United States
Environmental Protection
Agency
Environmental Monitoring
Systems Laboratory
Las Vegas NV 89114
Research and Development
EPA-600/S4-84-046  June 1984
Project Summary

Geothermal  Environmental
Impact  Assessment:
An  Approach  to  Groundwater
Impacts  from  Development,
Conversion,  and Waste Disposal

J. W. Hess, S. W. Wheatcraft, J. E. Edkins, R. L. Jacobson, and D. E. Zimmerman
  Groundwater  monitoring  for the
impacts  of geothermal  energy
development, conversion  and waste
disposal  is similar to groundwater
monitoring for other purposes, except
that additional information is needed
concerning the geothermal reservoir. In
the research described here, a six-step
methodology, including failure analysis
and computer-based contaminant
transport and geochemical models to
design groundwater monitoring plans,
was developed.  Failure data  analyses
indicate that production and  injection
wells have the highest probability of
failure and should be the focal points for
groundwater monitoring. Groundwater
monitoring techniques fall into  four
categories: 1)  monitoring  the
injection/production  well,  2)
monitoring in the  saturated  zone, 3)
monitoring in the unsaturated zone, and
4) monitoring on or above the ground
surface. Location  of the  monitoring
wells and the variables to  measure in
them may be determined with the aid of
computer contaminant transport and
geochemical  models.  POLUTE is  a
nondispersing contaminant transport
groundwater computer  model  that
enables the  user  to  locate  a
contaminant plume at any given time.
Prediction  of  resultant fluid
chemistries from a leaked geothermal
fluid may be essential to unambiguous
evaluation of geothermal fluid impact at
remote groundwater monitoring sites.
This can be accomplished through the
use of geochemical models.
  Illustrative examples were  run to
demonstrate the first four steps of the
six-step methodology. Results indicate
that the key to groundwater monitoring
is  the continuous measurement of
physical, and chemical characteristics
of injection fluids in the production and
injection wells.
  This report was submitted in fulfill-
ment of Grant No. R806457 by the
Desert Research Institute under the
sponsorship of the U.S. Environmental
Protection  Agency. This report covers
the period from April 17, 1979 to July
16, 1982 and work was completed as
of July 16, 1982.
  This Project Summary was developed
by EPA's  Environmental Monitoring
Systems Laboratory, Las Vegas, NV, to
announce key findings of the research
project that is fully documented in a
separate report of the same title (see
Project Report ordering information at
back).

Introduction
 The research described here used the
guidelines developed by Weiss,  Coffey,
and Williams (1979) as a base and refined
a six-step methodology to include failure
analysis and computer-based contami-
nanttransport and geochemical models.
This groundwater monitoring methodol-
ogy enables one to design a monitoring
plan to predict and detect changes in

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groundwater quality due to geothermal
development.

Methodology
  The variations in physical settings and
human  activities  at  or near potential
geothermal energy areas preclude one
monitoring plan that is applicable to the
release of geothermal fluid on the surface
as well as below the surface. Thus, the
monitoring method  developed  empha-
sizes groundwater impacts resulting from
the release of geothermal  fluid  into
groundwater from a production or injec-
tion well. Inherent in the methodology is
prediction of the possible impacts if a geo-
thermal fluid release should occur. The
methodology contains the following steps:
  1. Define baseline conditions, includ-
     ing   geology,  hydrology,   water
     quality, geothermal  system,  plant
     design,   existing  surface  and
     groundwater  usage,  and  other
     existing waste disposal systems.
  2. Perform  failure analysis: compare
    the site characteristics to the results
    of industry-wide failure analysis to
    predict the most likely mode of fluid
    release.

  3. Forecast aquifer conditions: predict
    travel times and chemical concen-
    trations in the geothermal reservoir
    and overlying aquifers through the
    use of solute transport and geochem-
    ical  models.  Predict  potential
    impacts, define limits of detection
    and use to design monitoring plan.
  4.  Select monitoring sites and tech-
     niques.

  5.  Design  monitoring  plan  and
     alternatives,  based on  the  above
     steps  and legal  and institutional
     constraints.

  6.  Implement  monitoring  plan  and
     modify as experience dictates.
  Failure data  analysis indicates that
production and injection wells have the
highest probability of failure and should
be  the  focal  points  for groundwater
monitoring. Additional years of operating
experience  using currently  developed
technologies  are needed  to estimate
failure rates  confidently. Groundwater
monitoring  techniques  fall  into four
                                   2
categories:   1)   monitoring  the
injection/production well, 2) monitoring
in the saturated zone, 3) monitoring in the
unsaturated zone, and 4) monitoring  on
or above the ground surface.
  Monitoring the  injection/production
wells can  best be accomplished  by
borehole geophysics and measurements
of annulus fluid properties. Techniques
include  acoustic borehole televiewers,
flow meters,  cement logs, conductivity
probes,  temperature  probes,  and
pressure gauges.
  Monitoring  in   the  saturated  and
unsaturated zones generally will involve
the  use of  monitoring wells  in which
chemical and physical  measurements
can be made, water samples collected, or
borehole geophysics run. Location of the
monitoring   wells   and  variables  to
measure in them may bedetermined with
the  aid of  computer  contaminant
transport and geochemical models.
  POLLUTE  is   a  nondispersing
contaminant  transport  groundwater
computer model that can be applied to an
anisotropic aquifer  which is bounded by
impermeable  and/or  equal  potential
boundaries.  The   location  distribution
coupled with the  isochron distribution
output  from POLLUTE enables the user
to locate a contaminant plume  at a given
time. The well flow distribution enables
the user to determine,  under a given
scenario, what will be contaminated, how
much contaminant  will be intercepted,
and how long it will take for the well to
become contaminated.
  Advective  contaminant transport
models  (which  ignore dispersion)  are
normally  adequate  for  purposes  of
designing  geothermal  monitoring
networks.   POLLUTE,   the  model
developed for this  study, is specifically
designed to  be  of maximum usefulness
and minimum cost to run and intercept
for monitoring network design. Use of an
advective  model   such   as  POLLUTE
eliminates the need for large amounts of
hydrologic data and permits optimization
of the geothermal monitoring network.
  Care must be taken to understand that
the  model will  not  predict exact arrival
times  of  contaminants  at  discharge
areas.  The  arrival   times  predicted  by
POLLUTE  will  be  equivalent  to  the
breakthrough of the 50% contaminant
concentration. This  is not seen  as a great
disadvantage, since advective-dispersion
models  are probably  inaccurate even
when  dispersivity   values  have been
measured.
  For any given geothermal system, there
are  five  possible  geochemical
mechanisms by which leaked geothermal
fluid chemistries might be altered. Four of
the five  mechanisms  are related  to
solution  and  precipitation   reactions
resulting from 1) aqueous redox potential
changes,  2) temperature  changes,  3)
pressure  change effect  on  dissolved
gases, and 4) exposure  of fluids to new
mineral   assemblages.  The fifth
mechanism  involves cation  exchange
reactions.  Prediction of resultant fluid
chemistries   may  be essential  to
unambiguous evaluation of geothermal
fluid  impact   at   remote  groundwater
monitoring sites.
  Computerized  geochemical  modeling
methods  are   recommended  for
application  to geothermal monitoring
problems when   used  by experienced
personnel on a site-specific basis. Steps
should include  1) selection  and field
supervision of essential  baseline data
collection directed to modeling needs, 2)
determination  of the degree  of  model
sophistication required  and selection of
appropriate geochemical program types
based on prior field data  evaluation  for
the Known Geothermal Resource Area
(KGRA) in question, and 3) interpretation
of  results,  including  selection  of
diagnostic remote monitoring  parame-
ters  and  identification  of information
gaps  requiring  further evaluation.
Because adequate redox information was
generally lacking in the analyses taken
from the literature, more effort should be
made  to  quantify  this  parameter  in
geothermal  fluids.  Redox information
should be  evaluated and comparisons
made between a number  of direct and
indirect methods. Redox  information is
important to studies involving corrosion
of plant facilities  as well as to impacts on
nonthermal  environments. It  is very
important to measure comparable data at
all sites at a given KGRA for both thermal
and nonthermal waters.
  Monitoring on  or above the surface
includes  tests on surface equipment,
surface water measurements,  surface
geophysics and remote  sensing. Surface
geochemistry techniques such as radon
and  mercury  detectors may  have
monitoring applications.
  Three   illustrative  examples  are
presented to demonstrate the six-step
methodology.  The  methodology was
applied to the  Raft River KGRA in Idaho
and to hypothetical examples of leakage
from a lagoon and  contaminant plume
tracking and interception. The results of
these examples  indicate that the key to
groundwater  monitoring  is to measure
physical  and  chemical characteristics
continuously on production and injection

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wells.  As  an example,  a change in
annulus pressure may indicate leakage
through the injection tubing and would be
the first indication of a leak into a ground-
water  system.  At  most sites,  the
immediate  groundwater   systems  are
already  naturally affected  by  the
geothermal  fluid.  This   makes  early
detection of the  geothermal fluid more
difficult in monitoring wells. Monitoring
wells can be used to assess the impact of
a leak, that is, to determine if there is a
detectable change in water quality.
J. W. Hess, S. W. Wheatcraft, J. E. Edkins. R. L Jacobson. D. E, Zimmerman, are
  with Water Resources Center, Desert Research Institute, University of Nevada
  System, Las Vegas, NV 89109.
Leslie Dunn is the EPA Project Officer (see below).
The complete report, entitled "Geothermal Environmental Impact Assessment:
  An Approach to Groundwater Impacts from Development, Conversion, and
  Waste Disposal," (Order No. PB 84-198 639; Cost: $23.50, subject to change)
  will be available only from:
        National Technical Information Service
        5285 Port Royal Road
        Springfield,  VA 22161
        Telephone: 703-487-4650
The EPA Project Officer can be contacted at:
        Environmental Monitoring Systems Laboratory
        U.S. Environmental Protection Agency
        Las Vegas, NV 89114
                                                                              U.S. GOVERNMENT PRINTING OFFICE; 1984 — 759-015/7731

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