600282030
  SORBENT MATERIALS FOR CLEANUP  OF  HAZARDOUS  SPILLS
                        by
                   E.  C.  Herrick
                    D. Carstea
                   6.  Goldgraben

               The MITRE  Corporation
              McLean,  Virginia 22102
            EPA Contract No.  68-01-5051
                  Project Officer
                   Marshall Dick
Office of Environmental Engineering and Technology
       Office of Research and Development
             Washington, D. C.  20460
    MUNICIPAL ENVIRONMENTAL
        OFFICE OF RESEARCH  AND
       U.S.  ENVIRONMENTAL PROTECT!   AGENCY
              CINCINNATI, OHIO 452*68

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                                  ABSTRACT
     This report reviews the state-of-the-art of sorbent materials for
cleanup of hazardous liquid spills.  The pertinent characteristics of 90.
hazardous liquids and 28 sorbent materials are reported, and a matrix is
provided to indicate the tested and anticipated compatibilities between the
liquids and sorbents.  Some conclusions are drawn about the state-of-the-art
and the suitability of various sorbent types.  A comprehensive testing
program is recommended.

     This report was submitted in fulfillment of Contract No. 68-Q1-5Q51
by The MITRE Corporation under the sponsorship of the U.S. Environmental
Protection Agency.  This report covers the period March 10, 1980 to
June 2, 1980, and work was completed as of October 1981.
                                     IV

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                               ACKNOWLEDGMENTS
     The authors wish to acknowledge the helpful guidance and continuous sup-
port of Dr. I. Wilder, Mr. F. Freestone, Dr. J. Brugger, Dr. J. Lafornara and
Mr. L. McCarthy of the U.S. Environmental Protection Agency, Industrial Envi-
ronmental Research Laboratory, Oil & Hazardous Materials Spills Branch,
Edison, New Jersey, 08817.

     The administrative support provided during all facets of this endeavor by
Dr. L. Thomas and Dr. P. Clifford of The MITRE Corporation is greatly appreci-
ated.

     The authors are also indebted to the following persons for their techni-
cal contribution during the data collection and compilation of this document:
Ms. E. Goldberg and Dr. N. Zimmerman, formerly with The MITRE Corporation, and
Mr. H. Fawcett, P.E., consultant to The MITRE Corporation.

     Mr. J. King, formerly of The MITRE Corporation, was essential to the
formulation of this project.  His interest and technical advice during the
entire period of the project are gratefully and sincerely appreciated by the
authors.

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                                   CONTENTS

Foreword	iii
Abstract	iv
Tables	viii
Acknowledgments  ........................  	    v

     1.  Executive Summary 	    1
     2.  Introduction   	    3
              Background	    3
              Purpose   	    4
              Scope  ........  	    4
              Approach  	    4
              Limitations  	    5
     3.  Conclusions 	    6
     4.  Recommendations	    7
              Recommendations to EPA	    7
              Recommendations to the  Spill Response Teams   	    7
     5.  Hazardous Substances   	    9
              Selection  	    9
              Properties	   10
     6.  Sorbents	25
              Nature and Classification   	   25
              Characteristics   	   27
              Sorption of Hazardous Liquids   	   34

References	45
Appendices	48

     A.  List of Hazardous Liquids	48
     B.  Hazardous Substances Data Sheets  	   55
     C.  Sorbent Material Data  Sheets  	  155
                                     vii

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                                    TABLES
Number                                                                    Page

  1.      Description of Properties of Hazardous Liquids 	     11

  2.      Description of Classifications of Hazardous Liquids   	     12

  3.      Summary of Hazard Classifications and Properties of
          Hazardous Liquids  	     13

  4.      Summary of Hazard Classifications and Properties of
          Hazardous Liquids  	     19

  5.      Classification of Sorbent Materials  	     26

  6.      Description of Characteristics of Sorbent Materials   	     29

  7.      Selected Characteristics of Sorbent Materials  	     30

  8.      Compatibility of Hazardous Liquids and Selected Sorbent
          Materials	     35

  9.      Compatibility of Hazardous Liquids and Selected Sorbent
          Materials	     39
                                    viii

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                                   SECTION 1
                               EXECUTIVE SUMMARY
     The MITRE Corporation/Metrek Division has been helping the U.S. Environ-
mental Protection Agency (EPA) review the state-of-the-art of sorbent materi-
als for containing and cleaning spills of hazardous liquids.  This report sum-
marizes information for EPA and provides recommendations on the use of sorbent
materials for cleaning up hazardous liquid spills.  The report also provides
guidance to response teams that vary in sophistication from company cleanup
crews and fire departments to a combined Coast Guard/EPA task force.

     Because chemical spills may constitute a severe threat to human health
and the environment, EPA has identified 299 hazardous substances on the basis
of toxicity and likelihood of environmental discharge.  Of these chemicals, 90
are liquid under ambient conditions or are shipped in liquid formulations
(Appendix A).  These substances represent major potential spill problems and
are the central concern of this report.

     Information regarding the 90 hazardous liquids is presented to help pre-
dict the behavior of the spills, the hazards posed to public health, and the
potential interaction with various possible sorbent materials.  The informa-
tion listed for each chemical includes the Chemical Abstracts Service (CAS)
number, the solubility in water, viscosity, melting and boiling points, and
flash point, among others.

     Sorbent materials can be divided into three general classifications:
natural organic (e.g., straw, feathers), natural inorganic (e.g., clays, cal-
cium carbonate), and synthetic (e.g., polyurethane).  Each of these categories
differs from the other two tn terms of material, origin, cost, and effective-
ness.  The natural organic and inorganic sorbents are generally more readily
available and less expensive than the synthetic sorbents.  Although more
expensive, the synthetics tend to exhibit higher sorption capacity than their
natural counterparts.  Both natural and synthetic sorbents can be treated to
improve their versatility and sorption capacity.

     The criteria for sorbent selection in the event of a hazardous chemical
spill are safety, sorption capacity, cost, availability, and ease of applica-
tion, collection, and disposal.  The safety criterion refers to avoidance of
sorbent-liquid combinations that may result in explosion, fire, or generation
of toxic fumes.  Sorbents ate generally inert materials.  Thus, most combina-
tions of hazardous liquids and sorbent materials appear to be safe.  Sorption

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capacity, for which relatively few data are available, is the weight of liquid
sorbed per unit weight of sorbent.

     The interaction of two or more hazardous substances may occur either in
the same spill or as a result of the disposal at a single site of sorbents
from different spills.  Since these combinations may also be hazardous, unsafe
combinations of hazardous liquids are identified.

      Determining the compatibility between hazardous liquids and sorbent
materials is limited as a result of data gaps.  These limitations also exist
because available data are not generally substantiated by laboratory test
results, are extrapolated from oil spill cleanup operations, or are predicted
from physical and chemical characteristics of the liquids and sorbents.

     In spite of these limitations, the following conclusions have been drawn
regarding the use of sorbents, the criteria for their selection, and their
application in response to a hazardous liquid spill (see Section 3).  Sorbent
materials can be used to clean up spills on land and water.  To minimize the
environmental risk of a hazardous liquid spill, it is essential that quick
selection and application of the appropriate sorbent be made.

     Recommendations have been made to EPA and spill response teams (see
Section 4).  The recommendations to EPA involve establishing a comprehensive
testing program to determine which sorbents are suitable for containing and
cleaning up liquid spills on land and water.  Guidelines have been formulated
to determine the effectiveness and suitability of using each of 28 sorbents
with each of 90 hazardous liquids.  These include (1) testing substances from
each category of sorbents and hazardous liquids and extrapolating the results
to other substances  within the category; and (2) establishing a priority
range for test combinations of sorbents with hazardous liquids, from widely
available and low-cost natural sorbents, to less common, more costly ones.

     The recommendations to spill response teams involve selecting sorbents on
the basis of (1) response requirements to hazardous liquid spills, and (2)
factors related to their removal and disposal.  Factors to be considered in
responding to a liquid spill include safety, sorption capacity, retention
capacity, and relative affinity for water.  Considerations related to the
removal and disposal of sorbents include the ease of collecting the material,
the thoroughness of the clean-up, the means of removal, the ease of transport
to the disposal site, and the requirements for safe disposal of the material.

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                                  SECTION 2
                                 INTRODUCTION
     Background

     Spills of hazardous liquid substances represent a severe threat to
environmental quality.  These substances may pollute streams, contaminate
groundwater aquifers, run off into sanitary sewer systems and upset wastewater
treatment plants, or evaporate to become air pollution problems.  Dealing with
a spill largely depends on various uncontrollable conditions such as the
weather, spill site accessibility and availability of suitable equipment,
materials, and personnel.  The following are typical steps in responding to a
hazardous spill:  Assessment, containment, treatment, removal, disposal, and
monitoring.

     Spill assessment includes determination of such factors as the Identity
and quantity of the chemical(s) spilled, the location of the spill (e.g., on
land or water, or near population centers) and the hazardous properties of the
chemical(s) spilled.

     Containment and treatment of a hazardous liquid spill are designed to
prevent its dispersal in the environment and to reduce the hazard it may pose.
Various processes for containment and treatment have been described in a num-
ber of publications such as those prepared by the U.S. Environmental Protec-
tion Agency (EPA), the U.S. Department of Transportation (including the U.S.
Coast Guard), various state agencies, and commercial suppliers of spill
cleanup products and services (e.g., Akers et al., 1978; Arthur D. Little,
1974; Bauer et al., 1975; Michalovic et al., 1977; Pilie et al., 1975).

     Removal of the hazardous liquid and subsequent cleanup of the contami-
nated site are the most difficult steps.  In some cases, where the substratum
is impermeable and the liquid is not volatile or reactive, the liquid can be
pumped directly into a tank truck for transport to a disposal site.  Many
jurisdictions employ this technique, but, in many instances, the spilled
liquid needs to be contained and removed with the aid of sorbent materials.
Common, naturally occurring sorbent materials, such as straw, sawdust, bark,
sand, and ash, have been used to clean up liquid spills for many years.  Cer-
tain combinations of hazardous substances and sorbent materials are ineffec-
tive, however, and others are dangerous to cleanup personnel.  Consequently,
spill cleanup personnel need guidance concerning the selection of sorbents.
After removal, the hazardous substance can be disposed of or destroyed.  Dis-
posal of hazardous solid wastes (including hazardous liquid-sorbent

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combinations) is regulated by EPA under Subtitle C of the Resource Conserva-
tion and Recovery Act of 1976 [40 CFR 261.3 (c)(2)].

     Once the spill has been cleaned up, monitoring the site provides an indi-
cation of the extent to which cleanup has been completed.  Monitoring also
allows for the evaluation and assessment of environmental damage.

     Purpose

     The purpose of this report is to summarize information for EPA as well as
to provide recommendations concerning the use of sorbent materials for clean-
ing up hazardous liquid spills.  The report also provides guidance to response
teams varying in sophistication from a company cleanup crew to a combined
Coast Guard/EPA task force.  In addition, this report reviews the state-of-
the-art in sorbent materials used for hazardous liquid cleanup.  Character-
istics and classifications are presented for hazardous substances and common
sorbents selected by EPA, and indications are given of their compatibility.
Finally, the report identifies data gaps and research needs in the area of
hazardous liquid spill cleanup.
     The report presents data on 90 hazardous substances and various commerci-
ally available sorbents; it also develops a matrix for the suitability of
various sorbents for different hazardous chemical spills.

     Information presented on the hazardous chemicals includes their method of
selection for study in this report, and data on various properties useful in
characterizing the behavior and hazard of a liquid spill (e.g., physical and
chemical properties, and health and flammability hazard).  The selected pro-
perties are presented for each chemical in Appendix B.

     Data on various commercially available sorbent materials are presented in
Appendix C.  Included in the information gathered are physical characteristics
(e.g., density, degradability, sorption capacity, and retention capacity) and
product information (e.g., product name, generic name, and cost).  Although
information is presented on the three classifications of sorbents (natural,
mineral, and synthetic), emphasis is placed on those that are inexpensive and
readily available.

     Approach

     A four-step approach was used in this study:

     •  Identification and characterization of hazardous substances;

     •  Identification and characterization of sorbent materials;

     •  Identification of compatible liquid-sorbent combinations; and

     •  Identification of data gaps and research needs.

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     Hazardous substances were identified and characterized by selecting the
90 liquids from the EPA list of hazardous substances (EPA 1978b and EPA 1979a)
and conducting a literature search to obtain information on the physical and
chemical properties for each substance.

     The procedures for identifying and characterizing sorbent materials were
similar to those followed for hazardous substances.  Generally available
sorbent materials were identified from technical reports and the commercial
literature.  Sorbent-liquid compatibility (either proven or predicted) was
identified from the literature.

     Compatibilities of hazardous substances and sorbent materials were
derived from three sources:  (1) tested and tried combinations, (2) predicted
behavior based on functional groups, and (3) claims by manufacturers.  From
this information, a compatibility matrix was compiled indicating the safety of
the different sorbents for each hazardous liquid.  Finally, throughout this
report, data gaps are identified regarding hazardous materials, sorbents, and
their compatibility with each other.

     Limitations

     The numerous limitations of this study form the basis for the section on
recommendations for future study (Section 4).  Data gaps are identified
regarding both the characteristics of sorbents and the compatibility of the
sorbent-liquid combinations.  The data obtained are not generally substan-
tiated by laboratory test results.  In other instances, proprietary data have
been withheld from the public by manufacturers.  Although much field experi-
ence has been gained in hazardous liquid cleanup operations, results have not
been documented.  In addition, the time constraint involved in preparing this
document did not allow for direct communication with the sorbent industry.
Thus, the data presented are mainly taken from published literature.

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                                  SECTION 3
                                 CONCLUSIONS
     Response to a hazardous spill includes assessment, containment, treat-
ment, removal, transport, disposal, and monitoring.  Selection and application
of suitable sorbent materials are important factors in a spill response opera-
tion and should therefore be considered in the context of the overall response
to a spill.

     The following conclusions can be drawn regarding sorbent materials and
their application to hazardous liquid spill cleanup:

     •  Sorbents can be used to clean up spills on land and on the water sur-
        face (if the sorbents float and are hydrophobic).

     •  Criteria for selecting a sorbent include safety, sorption capacity,
        ease of application, collection, and disposal, as well as cost and
        availability.  The latter two vary with time and location.

     •  Quick selection and application of the appropriate sorbent material
        are essential to minimize the environmental risk of a hazardous liquid
        spill.

     •  The natural sorbents are generally more readily available than the
        synthetics, although availability varies with time and location.

     •  Synthetic sorbents are more costly than their natural counterparts,
        but they are more versatile and tend to exhibit higher sorption cap-
        acity.

     •  Special surface treatment of both natural and synthetic sorbents can
        improve their versatility and sorption capacity.

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                                  SECTION 4


                               RECOMMENDATIONS
     The recommendations resulting from this study are directed to EPA and to
those responsible for cleanup of hazardous liquid spills.

     Recommendations to EPA

     A comprehensive testing program should be undertaken to determine the
suitability of various sorbent materials for containment and cleanup of haz-
ardous liquids spilled on land and on water.  Thousands of measurements may be
necessary to determine the effectiveness and suitability of using each of the
28 sorbents with each of the 90 hazardous liquids.  The following guidelines
are therefore recommended for use in designing a practical test program:

     •  Substances from each category of sorbents and hazardous liquids should
        be tested and the results of the tests extrapolated to other sub-
        stances within the category (the categories are shown in Tables 3,
        6 and 7).

     •  The priority for test combinations of sorbents with hazardous liquids
        should range from:

        -  widely available, low-cost, natural sorbents with liquids produced
           in large amounts, to

        -  less common, more costly sorbents with liquids produced in small
           amounts or used primarily within the confines of a manufacturing or
           processing facility.

     •  Sorbent use on land spills should be evaluated before spills on water,
        since the former are more likely to occur.

     The product of this program should be a user's guide to the selection,
procurement, application, removal, and disposal of sorbent materials for the
containment, removal, and disposal of hazardous liquid spills.

     Recommendations to the Spill Response Teams

     The various available sorbents should be selected based on
(1) the requirements for response to a hazardous liquid spill, and
(2) the factors involved in the subsequent removal and disposal of the
sorbent-liquid mixture.
                                      7

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     The characteristics of the sorbent/hazardous liquid combinations that
should be considered in responding to a hazardous liquid spill are:

     -  safety of the sorbent/liquid combination (generation of toxic emis-
        sions or effluents, spattering, explosion, or fire)
     -  sorption capacity
     -  retention capacity
     -  relative affinity for water.

     Factors that should be considered in selecting a sorbent in relation to
the removal and disposal of the sorbent/liquid mixture include:

     -  ease of collecting the mixture
     -  thoroughness of cleanup to prevent potential secondary pollution of
        the site
     -  means of removal from the spill site
     -  ease of transport to the disposal site
     -  requirements for safe disposal of the mixture.

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                                  SECTION 5
                             HAZARDOUS SUBSTANCES
     The basis for selecting the 90 hazardous substances for study in this
report is discussed in this section.  In addition, specific properties that
would characterize the behavior of a hazardous substance are identified and
discussed.  These properties may be used by a spill team to select a sorbent
to clean up a particular hazardous chemical spill.

     Selection

     The 90 hazardous chemicals examined in this report were chosen from a
list of hazardous substances identified by the U.S. Environmental Protection
Agency (EPA) under Section 311(B)(2)(a) of the Federal Water Pollution Control
Act of 1972 as amended by the Clean Water Act of 1977.  The chemicals listed
by EPA were chosen on the basis of two criteria:  (1) toxicity and (2) likeli-
hood of release to the environment (EPA, 1978b).  The first criterion was
based primarily on a 96-hour LC5Q of no more than 500 milligrams per liter
(mg/1) for a test population of aquatic animals.  The second criterion was
based on factors such as history of previous spills and annual production in
excess of 2200 Gg (1 billion lb.).

     Those chemicals selected for study in this report were chosen  to satisfy
one of two additional criteria:  (1) the chemical is a liquid under ambient
conditions,* or (2) the chemical is shipped in liquid formulations.  Eighty
of the chemicals were selected from a list of 271, which appeared in the
Federal Register of March 13, 1978.  An additional 10 were chosen by EPA from
a supplementary list of 28 hazardous substances as identified in the Federal
Register of February 16, 1979.

     The hazardous liquids examined in this report are listed in Appendix A.
In the appendix, the chemicals are listed in alphabetical order with both
their CAS number and common synonyms.  In addition, the hazardous liquids are
identified by the principal functional group, which partly determines the
behavior and activity of the chemical substance.
*For the purpose of this report, ambient conditions are defined as between
 0°F and 100°F (-20°C and 40°C) at one atmosphere (760 mm Hg) pressure.

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     Properties

     For the purposes of this report, the properties of the hazardous liquids
that are of primary interest are those that can indicate the behavior of the
spill, the hazard it poses to public health and the environment, and the
interaction with various sorbent materials.  These properties are listed and
explained in Table 1, which also indicates the significance of the property
and the units of measurement.  For example, solubility in water is a property
that relates to the behavior of the liquid in the environment (Table 1).  This
property indicates two things:  (1) the likelihood of water as a dispersal
medium in the environment, and (2) the feasibility of diluting a land spill
with water.

     Classification schemes that categorize the behavior, the hazard, or both
for these 90 substances have been developed by various agencies or associa-
tions that deal with them.  EPA developed a classification of "Reportable
Quantities" (quantities that may be harmful), the discharge of which is a
violation of the Clean Water Act, Section 311(b)(3).  The U.S. Department of
Transportation and the National Fire Protection Association developed hazard
classifications individually.  Schemes devised by these various groups are
presented in Table 2.

     The appropriate hazard classification and chemical and physical proper-
ties for each of the 90 hazardous substances are presented in Appendix B.
These data are summarized in Tables 3 and 4.  Comparisons can be made within
or among functional groups of hazardous substances based on the data.  The
information presented in Appendix B is more complete than that in the summary
table; thus, the appendix should be consulted for additional information on a
particular hazardous substance.
                                      10

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                                                           TABLE  1

                                   DESCRIPTION OF HAZARDOUS  LIQUIDS  PROPERTIES
Property
Solubility In U}0
Paraiatenca
Specific gravity
Vl»co.tty
Surface tenalon
Melting end boiling point*
Vapor preeaure
Vapor denalty
Flaeh point
Auto Ignition temperature
Flamnablllty llailta
Utility Of Property
Behavior
X
(
X
X
X
X
X
X



Hatard






X
X
X
Interaction
X

X
X

X




Definition/ Explanation
Amount of aubatance that will dlaaolva in a unit volume of
water at a apecifled temperature (uaually around 2S°C);
reflecte likelihood of dlaperalon in water and faaalblllty
of diluting land aplll with water
Reflecta realatanca of the aubatanc* to degradation into
almpler component* by natural chemical and biochemical
reactione. The following retlng la uaedl 0-not parela-

Ratlo of the denaity of the aubatance to the denalty of
water: reflecta buoyancy in water; eubatancaa with a
value >1 will generelly alnk
Realatence to change of ton at a apecified temperature;
reflecta likelihood of running off, percolating into aoil,
end adhering to aorbent materiale
at a apecifled temperature; reflecta wetting ability, and
hence, likelihood of edherence to aorbant
Loweat and hlgheet tempereture* at which aubatance ia In
the liquid etate
Preaeura of the vapor in equilibrium with the liquid et
a apecified temperature; reflecta tendency to evaporate
Ratio of the denalty of the vapor to the denaity of air.
Reflecte buoyancy of the vapor in air; vapor riaea if
value <1
Minimum temperature at which aufficlent amount of liquid
haa vaporised to form an ignltlble mixture with the air
Temperature at which vapora will apontaneoualy ignite
Loweat and hlgheat concentration of vapor in air which
will aupport ingltion
Unite
Perta per million (ppm)
Qualitative rating
Nona
Centipolaaa
(dyne-aeconda/100 cm2)
Dynea/cm
°C
mm of Hg
None
°C
°C
Vol. X
NOTE;   The "X" Indicate* the utility of each property  in predicting th« physical behavior  (spreading,  percolation, evaporation) of the apilied liquid.
       the haiard (exploaion, fire, toxic fimee) it  poaea to the aurroundlng area, and  the character of  Interaction (degree  of aorptlon) with the
       aorbent Material.

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                    TABLE 2




DESCRIPTION OF HAZARDOUS LIQUID CLASSIFICATIONS
Claaeificatlon
DOT Hazard
HFPA- (National Fire
EPA Reportable Quantity
Significance
Claealflea aubatancea on the
followat
Claaalflcatlon
Combuetible liquid
Corroaiva Material
Flaaiaable liquid
Other regulated Material
Oxidizing material
Polaon A
Polaon 1
Ratea the health hazard, fla
effect) to 4 (aevere effect)
for aquatic organiana aa fol
Gate
X
A
1
C
D
baala of potential hazard and aaalgna a letter code aa
Abbreviation Definition
Comb. L. A liquid with a flaah point
between 100 - 200°F.
Cor. A liquid or aolid that cauaea
vlalble deatruetlon in human
ateel
P.L. A liquid with a flaah point below 100°F
ORH
Oxy. H A liquid or eolld that ylelda oxygen
readily upon reaction
Pole. A A gaa or liquid that la dangaroua to
life in email amount a
Pola. 1 A liquid or aolld that preaenta a health
hazard during tranaportatlon
nubility, and reactivity of aubatancea on a acale of 0 (no
aubatancea In terms of their lethal concent rat iona (LCjg)
Iowa:
gory Reportable Ouantltlea
1
10
100
1,000
5,000
Reference
U.S. Department of
Tranaportatlon. 1975

U.S. Environmental
Protection Agency, I960

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                                                                  TABLE  3




                                   SUMMARY OF HAZARD CLASSIFICATIONS  AND PROPERTIES  OF HAZARDOUS LIQUIDS
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HAZARDOUS LIQUIDS
Acetic acid
Acetic anhydride
Butyric acid
ACIDS 2,2-UIchloroproplonlc acid
and Formic acid
DERIVATIVES Maphthenic acid
Propionlc acid
Propionlc anhydride
ALCOHOLS Allyl elcohol
and Creaol*
PHENOLS Phenol
Acetaldehyde
ALDEHYDES Ac role In
end Crotonaldehyde
KETONES Formaldehyde
Furfural
EPOXIDES Propylene Oxide
1 HAZARD CLASSIFICATION


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Cor.
Cor.
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-
Cor.
Cor.
F.L.
Poia.R
Pote. a
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F.L.
F.L.
ORM
Coab.L
F.L.
NFPA HAZARD
RATING



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2
2
2
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3
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2
2
3
3
3
2
3
3
2
1
2

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2
2
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2
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2
2
3
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2
4
3
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PHYSICAL/CHEMICAL PROPERTIES

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1.6
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2.5
4.3
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3.7
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1.9
2.4
1.1
3.3
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VISCOSITY
(CENTIPOISES)

CP
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0.9
1.8
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18
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1.1
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20.8
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18
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30
20
50
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-
25
20
                                                                                                                            CONTINUED

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TABLE 3









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HAZARDOUS LIQUIDS
A*yl acetate
Butyl acetate
ESTERS n-Butyl phthalate
Methyl •ethacrylate
Pyrethrlna
Vinyl ecetate
Acetyl broalde
Acetyl chloride
Allyl chloride
Benzoyl chloride
Benzyl chloride
Carbon tetrachlorlde
HALOGEN Chlordane
COMPOUNDS Chlorobenzene
Chlorofor*
Cyenogen chloride
o-Dlclilorobenzene
Dlchloropropene -
dlchloropropane (D-D Blx)
2,2-Dlchloropropionlc acid
HAZARD CLASSIFICATION

M
g
a fc
a. p
?l
CD

c
D
B
D
C
C
D
D
C
C
B
D
X
t
D
A
B

D
n

ij
ij
a
3
3
b

r.L.
r.L.
-
r.L.
-
r.L.
Cor.
r.L.
r.L.
Cor.
Cor.
ORH
Coab.L
F.I.
ORH
Pole. A
ORH

Cor.
-
NFPA HAZARD
RATING



5
a
S
i
i
0
2
-
2
_
3
3
3
2
3
-
2
2
-
2

2
-

E

i
a
ri
3
3
1
3
-
3
_
3
3
2
2
0
-
3
0
-
2

3
-


P
g
2
a
0
0
0
2
-
2
_
2
1
1
1
0
-
0
0
-
0

0
~
PHYSICAL/CHEMICAL PROPERTIES

£
g
gr-t
|

s 1
u
fe
0.9
0.9
1.0
0.94
l.S
0.9
1.7
1.1
0.9
.2
.1
.6
.6
.1
.5
.2
.3

,2
.4


E ^

o
i9
>

4.5
4.0
9.6
3.S
• -
3.0
_
2.7
2.6
4.9
4.4
5.3
-
3.9
-
2.1
S.I

3.9
-




VISCOSITY
(CENTIPOISES)

CP
0.8
0.7
16. 5
-
-
-
_
-
0.3
-
-
1.0
_
0.8
0.6
-
1.3

-
-

°C
45
20
25
-
-
-
_
-
30
-
_
20
-
20
20
-
25

-
-
                                                     CONTINUED

-------
TABLE 3






I
p
8
O
i




















HAZARDOUS LIQUIDS
Hexechlorocyclopentadlene
HAlnrfH Phosgene (under preeeiire)
COMPOUNDS Polychlorlneted blphenyU
(con't) Trlchloroelhylene
Vinyl Idene chloride
Benzene
Cyclohexene
Ethylbeniene
HYDROCARBONS lnoprene
Styrene
Toluene
Xylene*
Acetone cyenohydrln
Acrylonltrlle
NITROGEN Aniline
COMPOUNDS Bentonltrlle
Butylanlne
DlethyUeilne
Uluetliylanlne
HAZARD CLASSIFICATION

3-
|&
2 y
S|
a
X
D
A
C
0
C
C
C
C
C
C
C
A
B
C
C
C
C
C
w

a
a
a
1
-
Pole. A
OHM
-
F.L.
F.L.
F.L.
F.I..
F.L.
F.L.
F.L.
Poie.B
F.L.
Poie.B
-
F.L.
F.L.
F.L.
NFPA HAZARD
RATING

I

/
0
1
-
*
I
2
2
1
2
2
2
2
2
4
4
3
-
2
2
3

E
ri

I
-
0
i
4
3
3
3
4
3
3
3
1
3
2
-
3
3
4


H
|
3
-
0
0
2
0
0
0
1
2
0
0
2
2
0
-
0
0
0
PHYSICAL/CHEMICAL PROPERTIES

C
u •
1} 00
M W
*** H
£3 v

1.7
1.4
1.2-1.5
1.5
1.3
0.9
0.8
0.9
0.7
0.9
0.9
0.9
0.9
o.a
1.0
1.0
0.7
0.7
0.7

g
IA •-*
a ,
a
% "
*
9.4
3.4
4.5
3.J
2. a
2.9
3.7
2.4
3.6
3.1
3.7
2.9
i.a
3.2
-
2.5
2.5
1.6



VISCOSITY
(CENTIPO1SES)
CP
-
-
0.6
-
0.65
0.7
0.7
-
-
0.6
0.6
_
-
10.2
1.2
-
0.4

°C
-
-
20
-
20
20
17
-
-
17
20
_
-
0
25
-
25

                                                          CONTINUED

-------
TABLE 3








i
§
§3
u
3
0




















HAZARDOUS LIQUIDS
Dlnltrotoluene*
NITROGEN Ethylenedtaailne
rJLvniiHDS Hydrogen cyanld.
COMPOUNDS HonoethyU»Jl»
(con t) mtrobeni.il.
Qulnoline
TriethylMlnc
Trleethylanlne
ORGANOMETALUC Tetr.«tnyl ,..d
COMPOUNDS '
Dlazlnon
Dlchlorvoa
Dlaulfoton
ORGAMOPHOS- Ethlon
PIIORUS Halathlon
COMPOUNDS Methyl parathlon
Hevlnphoa
Haled
Parathlon
Tetraethyl pyrophoiphate
HAZARD CLASSIFICATION

•1
SK
6
||
<
a
M
c
c
A
C
C
c
D
C
B









-

IA
jj
Q
I
3

*
-
-
PoIa.A
Pola.l
-
r.L.
r.L.
Pota.B
ORN
-
-
-
ORM
Pola.B
-
-
Pola.B
-
NFPA HAZARD
RATING



PJ
t*
a
2
J
4
3
-
2
2
3
_
-
-
-
-
4
-
-
4
-

P
3
3

*
1
2
4
4
2
-
3
4
2
.
-
-
-
-
1
-
-
1
-


E
£

3
3
0
2
0
0
-
0
0
3
_
-
-
-
-
2
-
-
2
-
PHYSICAL/CHEMICAL PROPERTIES

^
H
i 7
O I
U at
n B
u 3

1.5
0.9
0.7
0.8
1.2
1.1
o.a
0.7
1.7
1.1
1.4
1.1
1.2
1.2
1.3
1.3
2.0
1.3
-


E
V) r-t
o '
g 2

*
6.3
2.1
0.9
1.6
4.3
4.3
3.5
2.0
8.6
_
-
-
-
2.3
-
3.2
-
-
-




VISCOSITY
(CENTIPOISES)

CP
-
-
2.0
0.6
-
-
-
_
-
-
-
-
-
-
-
-
-
°C
-
-
20
17
-
-
-
_
-
-
-
-
-
-
-
-
-
                                                            CONTINUED

-------
TABLE 3


10
8
g
«
i




Ul

g
i
"
"

3
o
a









HAZARDOUS LIQUIDS
„...„.,„ Carbon dlaulf Ida
cZ™»* ~?7"» •* •«"
Methyl ner aptan
Hydrochlor c acid
(20X ao .)
Hydrofluor c acid
ACIDS <7M "° •>
Nitric acid
Phoa pho r i c acid
Sulfurlc acid
Antlnony pentachloride
Arsenic trichloride
Phoaphoroua uxychloride
HAI IDES Phoaphoroue trichloride
Sodlu* hypochlorite
(solution)
Sulfur •onochlorlde
Zinc chloride (aolution)
HAZARD CLASSIFICATION


y
UK
O S3
el
•<
a
D
C
B
D

D

C
D
C
C
D
D
D
B

C
D

14
^
1
B

F.L.
Cor.
F.L.
Cor.

Cor.

oxy.M
Cor.
Cor.
Cor.
Pola.B
Cor.
Cor.
-

Cor.
-
NFPA HAZARD
RATING

i
0
1
2
2
3

-

3
2
3
3
3
3
3
-

2
-

|
1
s
3
4
0

-

0
0
0
0
0
0
0
-

1
-

t:
i
i
0
0
0

-

0
0
2
1
0
2
2
-

1
-
PHYSICAL/CHEMICAL PROPERTIES

£
b
!:
IS
g
1.3
1.8
0.9
1.1

1.2

1.5
1.9
1.8
2.3
2.2
1.7
1.6
1.0

1.7
3.0


E
W rH
« 8
I9

2.6
1.7
_

-

-
-
-
_
-
6.8
4.8
-

-
-



VISCOSITY
(CENTIPOISES)

CP
0.4
25.4

-

-
-
26.9
_
_
-
-
-

-
-

°C
20
20

-

-
-
15
_
-
-
-
-

-
-
                                                            CONTINUED

-------
                                                                        TABLE 3  (CONCLUDED)
u)
U
HAZARDOUS LIQUIDS
Aa»onlu*> hydroxide
™6* Nitrogen dioxide
' HAZABD CLASSIFICATION
EPA 8EPOMABLE
QUANTITY
C
c
(A
§
Cor.
Poll. A
NFTA HAZARD
RATING
HEALTH
3
FLAMMABILrn
0
I
a
PHYSICAL/CHEMICAL PROPERTIES
K
SPECIFIC 6SATO
WATER - I
0.9
1.5
VAPOK DENSITY
Alt - 1
1.6
VISCOSITY
(CENTIPOISES)
CP
-
°C
-
OO
                            'See  Individual data aheeta (or  propertlea of all iaoaera.
                            Notes:   Data Hated in thia table were compiled froai th« uourcea  liated in the text.
                                    Teblea 2 and 3 present  detailed deacriptione of the  properties end classifications Included  In thla table.

-------
                               TABLE A




SUMMARY OF HAZARD CLASSIFICATIONS AND PROPERTIES OF HAZARDOUS LIQUIDS





i
g
0
°
u
M
s
II
°















HAZARDOUS LIQUIDS
Acetic acid
Acetic anhydride
Butyric acid
ACIDS 2,2-Dlchloroproplontc acii
and Fomlc acid
DERIVATIVES Naphthenlc acid
Proplonlc acid
Proplonlc anhydride
ALCOHOLS Allyl alcohol
and Creaol*
PHENOLS Phenol
Acetaldehyde
ALDEHYDES Ac role in
and Crotonaldehyde
KETONES Formaldehyde
Furfural
EPOXIDES Propylene Oxide
PHYSICAL/CHEMICAL PROPERTIES
SURFACE
TENSION
(dynea/ca)


A/cm
27.8
21.7
26.8
-
37.6
-
26.7
-
25.8
-
40.9
_
-
-
58.2
43.5
-

°C
20
20
20
-
20
-
20
-
20
-
20
_
-
-
20
20
-
B
5f?

i!

16.7
-73
-5
-
8.4
30
-21
-45
-50
11
41
-124
-88
-76.5
-92
-36
-104
B
0
H~
3

118
140
164
185-190
101
233
141
168
96-97
191
182
21
53
104
20
162
35
B,

§
3

42.8
51.9
71.7
-
68.9
149
54.4
73.9
21.1
81.1
79
-37.8
-26.1
13
85
60
-37
|
|p
g~

«
465
190
450
-
601
-
513
-
378
599
715
175
235
232
-
316
449
' VAPOR
PRESSURE
(-> Hg)


-
11.4
S.I
0.43
-
42.4
46
4.5
1
25.6
-
0.53
92.3
288
30
1947
2.1
445

°C
20
25
20
-
25
38
25
26
25
-
20
25
25
20
25
25
20
Si
£ M
« |
§1

3-17
2.9-10.3
2.0-10.0
-
18-57
-
2.9 	
-
2.5-18
1.4 	
1.5 	
4-60
28-31
2.95-15.5
-
2.1-19.3
2.1-21.5

SOLUBILITY
IN WATER


PP«
•laclble
120,000
56,000
450,000
•laclble
2,010
•laclble
deconpoaca
•laclble
20,000
6,700
•laclble
400,000
181,000
550,000
8], 000
330,000

°C
-
25
25
25
-
25
-
-
-
-
25
-
25
20
-
20
30
8
K
M
*

_
-
i
-
0
-
0
1
1
-
2
0
0
0
-
0
0
                                                                                  CONTINUED

-------
                                                                      TABLE 4
N)
O




i
i
s
0
M
3
»


















HAZARDOUS LIQUIDS
Anyl acetate
Butyl acetate
ESTERS a-Butyl plithalete
Methyl •ethacryUte
Pyrethrlna

Vinyl acetate
Acetyl broeilde
Acetyl chloride
Allyl chloride
Benzoyl chloride
Benzyl chloride
Carbon tetrachlorlde
HALOGEN
COMPOUNDS Chlordane
Chlorobenzene
Chlorofora
Cyanogen chloride
o-Dichlorobenzene
Dlchloropropene -
dlchloropropane (D-D •!«)
2,2-Dlchloroproplonlc acid
PHYSICAL/CHEMICAL PROPERTIES
SURFACE
TENSION
(dyne
d/c«
-
-
33.4
-
-

23.9
26.7
-
_
26.8

-
33.6
27.1
-
26.8
28.9


• /»)
oc
-
-
20
-
-

20
14.8
-
-
20

-
20
20
-
20
20


g
&§
y
8
-78.5
-74
-
-48
0

-91
-96
-112
-135
-0.5
-39
-23

-
-45
-63
-6
-17
-80

"
g
2o


150
126
340
101
de-
coetpoaee
73
76
51
45
197
179
77

175
132
62
14
181
96

85-190
E
M
SG
o

25
22.2
157
10/0°C
-

-8
5
-31,7
73
67.2
none

,
28.9
_
_
66
16

""
|
P o
I S&
i
360
425
402
-
-

427
390
485
585
505
none

_
640
_
_
648
557

"
VAPOR
PRESSURE
(— Hg)
M
7.4
15
-
30
-

107.5
2
294,)
1
1.4
91.3

IxlO"5
12.1
200
40
_
40

-
"C
25
25
-
26
-

25
16
20
32
25
20

25
25
25
-38

19

-
i?
E «
If
I1
1.1-7.5
1.7-7.6
0.5 	
1.7-8.2
-

-
-
2.9-a.i
1.1 —
nonf la»-
•able
_
1.3-7.1

_
2.2-9.2
3.4-14.5

••

SOLUBILITY
IN WATER
ppn
2.000
7.00O
400
1,600
1

20,000
decoqpoaei!
decompoacB
1,000
deconpoaea
33
500

Inaoluble
488
2.000
2.500
naoluble
2,700

450,000
°C
20
20
25
20
-

25
-
25
25


_
25
25
25

20

25

8
1
M

-
1
2
1
-

1
1
_
-
2

_

(
_
2


-
                                                                                                                             CONTINUED

-------
TABLE 4





i
i
§
o
CJ
S
*
0



















HAZARDOUS LIQUIDS
Hexachlorocyclopentadlane

HALOGEN Phoagene
COMPOUNDS Polychloclnated blphenyla
(con't) (PCB's)
Trlchloroethylene
Vlnylidene chloride
Benzene
Cyc lohexane
HYDROCARBONS Ethyl benzene
laoprene
Styrene
Toluene
Xylene*
Acetone cyanohydrln
Acrylonitrlle
NITROGEN Aniline
COMPOUNDS Benzonltrlle
Bucylaaine
DletliylaalM
Dleethylanlne
PHYSICAL/CHEMICAL PROPERTIES

SURFACE
TENSION
(dynea/ca)
d/c.
-

-
-

29.5
-
28.8
25.5
29.2
-
32.1
28.5
28.9
_
_
42.9
39.1
19.7
16.4
-
°C
-

-
-

20
-
20
20
20
-
19
20
20
_
_
20
20
41
56
-

fi
2g
1"

9.6

-118
-

-73
-123
5.5
6.1
-95
-146
31
-95
-25
-19
-82
-6.2
12.8
-49
-50
-96

g
gg
ri~
S
239

8.2
325-366

87
32
80
81
136
34
146
111
144
95
77
184
191
78
55
7

B
go\
T

none

-
-

32
-10
-11.1
-20
IS
-65
32
4.4
32
73.9
0
70
75
12.2
-26
-7
1
3
P u
g~
g
M
none

-
-

410
456
560
245
432
493
490
480
465
688
481
615
-
312
312
400

VAPOR
PRESSURE
(— Hg)
_
-

1200
<1

100
500
94.9
98.1
9.6
20
6
28.4
-
..
113.8
0.67
1
72
247.1
1277
°C
-

20
25

31
20
25
25
25
-
25
25
-
_
25
25
24
20
25
20

K ~
§ B
E «
-i
|
JJ r4
S I
nonflaa-
•able
-
-

12.5-90
5.6-11.4
1.3-7.1
1.3-8.0
1.0-6.7
2.9 	
1.1-6.1
1.2-7.1
1.1-7
2.2-12.0
_
1.3 	

1.7-9.8
1.8 	
2.8-14.4



SOLUBILITY
IN WATER
PP"
-

deconpoaea
0.3-0.5

1,000
-
3,000
45
14
100
320
470
1)5
100,000
70,000
36,000
10,000
•Igclble
•laclble
237,000
°C
-

-
-

25
-
25
25
25
-
25
25
25
.
25
18
100
_
_
-


S
i
i

2

0
2

2
-
1
1
-
0
1
0
0
1
0

1
1
0
1
                                                      CONTINUED

-------
                                                                      TABLE  4
ro
to





1
g
u
S
0




















HAZARDOUS LIQUIDS
Dlnltrotoluene*
NITROGEN Ethylenedla.lne
Co£S Hydrogen cyanld.
(con't) Honoetl,yla.ln«
1 " Nitrobenzene
Qulnollna
Trlethylaaln*
TrlMethylaalna
ORCANOMETALLIC _ . , , .
COMPOUNDS Tetraethyl lead

Dlazlnon
Dlchlorvoa
Dlaulfoton
Ethlon
ORCANOPHOS- Halathlon
PHORUS Hethyl p.r.thlon
COMPOUNDS
Mevlnphoa

Haled
Pa rath Ion
Tetraethyl pycoptioophate
PHYSICAL/CHEMICAL PROPERTIES
SURFACE
TENSION
(dynea/ca)


d/c.
-
41.9
17
17.1
-
-

_
-
-
_
_
-

-

-
-
"


°C
-
20
28. 5
-4
-
-

.
-
.
_
.
-

-

-
-
"
g
*G
o o
y

71
8.5
-14
-80.6
6
-13
-US
-117
-117


-
-
-11
2.9
15-36

-

27
6
"
g
SG
u o
a

100
117
26
1?
211
218
90
3
decoK-
poaea
81/0.002
40/200
62/0.01
-
156
decon-
poaea
99-101/
0.03m
110/0.5
175
45- ISO/
5-10™
g
I
s2- ^
2

_
65.6
-18
87.8
-
-7
-
933

_
-
-
-
-51.9
46.1

-

54
112
-
I
|G
s
1
M
-
185
538
385
482
480
-
190
-

_
-
_
_
-
-

-

-
-
-
VAPOR
PRESSURE
(a- H|)


a. °C
_
13
264.4
1094
0.1
1
-
687
1

IxlO""1
1.2x10 *
I .SalO'1*
1.5x10"'
4x!0"5
0.97

2.9x10"

2xlO~1'
0.01
-
-
25
0
25
25
60
-
0
28

20
12
20
25
10
20

21

20
24
-
S|
M M
1
a I
£ ~
-
5.6-40.0
2.5-14.0
1.8 	
1.2 	
1.2-8.0
2.0-11.6
-

_
-
_
-
-
-

-

_
-
-

SOLUBILITY
IN WATER


PP«
2 JO
•laclble
•laclble
•lacible
1.900
60,000
55.000
475.000
30

40
10.0OO
2S
2
145
50

•laclble

500
20
•laclble

°C
22
20
25
20
30
25

25
20
_
20
25
25

-

_
_
-
8
1
M
s

_
0
2
0
-
-
1

_
-
_
1
0
1

1

_
1
1
                                                                                                                              CONTINUED

-------
                                                                         TABLE 4
to
OJ

.
1
§

s
it





g
§
b
0
O
3
1










HAZARDOUS LIQUIDS
smnm Carbon dlaulClde
rnMpniiMna Chloroaul Ionic acid
COMPOUNDS Methy, mftctftm
Hydrochloric acid
(20X aol.)
Hydrofluoric acid
.„-„„ (701 aol.)
ACIDS Nitric acid
Phosphoric ecld

SuHuric acid
Antimony pentachlorlde
Arsenic trichloride
INORGANIC Phosphorous oxychloride
HALIDES Phosphorous trichloride
Sodium hypochlorite
(solution)
Sulfur laonochlorlde
Zinc chloride (solution)
PHYSICAL/CHEMICAL PROPERTIES
SURFACE
TENSION
(dynes/ca)


d/c.
32.1
70

-

_
-

55.1
_
-
-
-

-
-

°0
20
20

-

_
-

20
-
-
-
~

-
-
B
..§
gt
d
2

-111
-80
-123
-62

-75

-42
4?. 3

10
2.8
-8.5
1.1
-112
57.5

-82
290
„
o


g

47
152
7
109

65

86
decon-
poaea
290
79/22m
131
107
76
-

138
732
g
°oi
Be.



-30
<0
-

-

_
-

-
_
-
_
-

118
-
f
(5 u
g"

p
S
90
-

-

-
-

-
-
-
-
-

239
-
VAPOR
PRESSURE
(— Kg)


an
400
1
760
1

400

7.1
-

3x10 "
1
1
28
100
-

10
100

°c
28
32
7
146

3

40
-

-
23
24
20
21
-

28
690
-1 a
Ef
i *

Sj g
2 -
1.3-50.0
3.9-21.8
-

-

-
-

-
-
- '
-
-

-
-

SOLUBILITY
IN WATER


PP«
2.200
decowpoaea
24.000
832,000

•laclble

•iacibla
•laclble

•iacible
deconpoaea
decoapoaea
deconpoaea
deconpoaea
293.000

decompoaea
4.3«106

°C
25
15
25

-

-
-

-
-
-
_
0

-
25
„
1




1
2

-

-
2

2
-
-
0
-

-
-
                                                                                                                               CONTINUED

-------
                                                              TABLE  4 (CONCLUDED)

U)
U

1
5





HAZARDOUS LIQUIDS
OTHER Aanonlua] hyrdoxide
Nitrogen dioxide
PHYSICAL/CHEMICAL PROPERTIES
SURFACE
TENSION
(dynea/c.)

d/co
-
"

°C
-
"
B
fi£
a

-77
-9.3
£
«*
ri
S

30
21

i^


-
"
1
Sg
H
M
-
~
VAPOR
PRESSURE
(aim H()

-
11.9
760

°C
20
21
S 3
.. «
a-
i *
v H
J ^
ri
16-25
-

SOLUBILITY
IN MATER

pp.
mtscllile
decunpoaea

°c
.
~
B
M
Ul
P


1
'
•Sac Individual  d«t« •heed for proper Cl«> at all laoaeri
Noteii  Data Hated in tbla table were  compiled fro» the eourcea  Hated in the text.
        Tablea  1 and 2 nrcaent detailed description, of the proper He. and claaalf Icatlona included  In thie table.

-------
                                  SECTION 6


                                   SORBENTS
     This section identifies and characterizes sorbent materials used for con-
taining and cleaning up hazardous liquids.  The nature and classification of
sorbents and sorbent characteristics are examined, and available data on the
sorbents are presented.

     Nature and Classification

     Sorbent materials are usually inert, nontoxic, solid substances that are
used to clean up hazardous liquid spills.  Four reasons exist for sorbent use:
to prevent spreading or~percolation of the liquid, to reduce rate of evapora-
tion, to condition for treatment, and to facilitate removal and safe disposal.

     Use of sorbent materials for containment and cleanup of hazardous liquids
has evolved from cleanup technology originally devised for oil spills.  Span-
ning a wide spectrum of forms and compositions, these sorbents can be grouped
into three classifications:  natural organic (natural), natural inorganic
(mineral), and synthetic.  The origin, composition, and representative sorbent
materials of each classification are presented in Table 5.  As can be seen,
the synthetic sorbents have the greatest diversity in material type because a
modification of either the natural or mineral sorbents is considered to be
synthetic.  In addition, numerous polymeric materials such as polyethylene or
polystyrene have also been used and are considered effective synthetic
sorbents.

     These three sorbent classes generally differ on availability and sorption
capacity.  The natural sorbents, both organic and inorganic, are generally
more readily available and less expensive than the synthetic ones.  The syn-
thetic sorbents are characterized by greater versatility and sorption cap-
acity.  For example, multipurpose gelling agent (MGA) (a mixture of four syn-
thetic polymers and a silica fluidizing agent) was developed to immobilize the
four most common types of hazardous liquids:  aqueous solutions, alcohols,
polar organic compounds, and nonpolar organic compounds (Michalovic et al.,
1975).  One common factor among the sorbent types is that organic sorbents
tend to have a greater sorption and retention capacity for organic rather than
inorganic liquids.

     Sorption of liquids occurs through one of two processes:  adsorption and
absorption.  In adsorption, a weak chemical bond is formed between the liquid
and the surface of the sorbent particles.  In absorption, the liquid is

                                     25

-------
                                                                   TABLE 5

                                                     CLASSIFICATION OF SORBENT MATERIALS
                          Class
                     Natural Organic
                        (Natural)
                    Natural Inorganic
                        (Mineral)
NJ
ON
 Synthetic
or Modified
  Natural
                          Origin
                    Animal or vegetable
                                                  Mineral
Synthetic polymeric
materials (e.g.
polyethylene, poly-
propylene, polysty-
rene, polyurethane),
animal or vegetable,
and mineral
                                                                                Common Materials
                        •  Straw,  sawdust,  bark,  peat,  rice hulls,
                           peanut  hulls,  bagasse, corn  cobs, cotton
                           waste,  wool waste,  feathers
                                            •  Sand, clays  (bentonlte, kaollnlte), fly
                                               ash, spent lime, calcium carbonate, dlato-
                                               maceous earth, perlite, vermlculIte, rock
                                               wool
Modified Organic:  Conwed (surface treated
cellulose), Sllkwlk (ground corn cobs),
Sorb-Oil (recycled flberboard)
Modified Inorganic:  Zorblte (formulated
perlite) Dlasorb (silica particles),
Absorbent 1012 (treated volcanic rock),
Flltrasorb (activated charcoal)
Organic/Inorganic:  Flberperl, Sorbent C
(mixtures of cellulose and perlite)
Foams:  Durable Conwed, Graboll, Spill
Control PEP

Mats:  Leomat, Qulck-Wlk, Tafmat, 3 M sheets
Strands:  Oil Snare, 3 M Fibres

Particles:  Imbiber Beads, Rubbermaid
Beground Rubber
Mixed Form:  Wlnkler Foams

Multipurpose Gelling Agent

-------
mechanically entrapped within the pores and interstices of the sorbent
material through capillary action.

     Sorbents may be used on land, where most spills occur, or on inland
waterways.*  Because contact between the liquid sorbent is easier to estab-
lish with spills on land than on water, land spills are more effectively
cleaned up by sorbents.  For spills on waterways, sorbents are most effective
when both the hazardous liquid and sorbent material float on the surface.
This rarely occurs because only 10 of the hazardous liquids examined in this
report float on water, although most of the sorbents float.**  More com-
monly, the hazardous liquid is dispersed in the water and does not float.  In
this case, the hydrophobic sorbents will sorb the hazardous liquid selec-
tively.  This type of spill is the most difficult to clean effectively.

     Characteristics

     Selection of the most appropriate sorbent for a given application is
governed by:

        Availability and cost
        Storage and transportation requirements
        Safety
        Sorption capacity
        Ease of use (i.e., application and removal)
        Disposal

Of these, the two most important in selecting a sorbent for a hazardous spill
are safety and sorption capacity.  These two and other characteristics are
discussed more fully below.

     Availability is an important consideration because of the need for a
quick response to spills of hazardous chemicals.  The availability of many of
the natural sorbents may be seasonal, especially if a large storage facility
is not available for keeping a stock of these lowest-cost sorbents.  Alterna-
tively, the synthetic sorbents can be readily obtained from the manufacturer
year-round, but for a higher cost.

     Some of the sorbents are bulky and require protection from weathering.
For these, storage may be an important consideration.  For example, sorbents
that are susceptible to weathering should be stored in a warehouse or in
weatherproof containers.

     Most sorbents are inert materials and do not usually cause safety prob-
lems in combination with hazardous liquids.  However, some sorbents may pre-
sent problems because of the combustibility of the sorbent or the reaction
 *The use of sorbents for containing hazardous liquid spills in open bays or
  oceans is not considered in this report.

**The few sorbents that are denser than water include untreated  cellulose
  and untreated minerals such as sand or clay.


                                     27

-------
between the sorbent and liquid, resulting in explosion or ignition of the
hazardous liquid.  An explosion or fire involving a hazardous liquid may
produce toxic fumes.

     Sorption capacity indicates the weight of liquid sorbed per unit weight
of sorbent.  This information allows assessment of the proper amount of sorb-
ent needed to contain the spill.  The sorbent capacity—either through adsorp-
tion or absorption—depends on certain qualities of the spilled liquid.  Vis-
cosity of the liquid is the most important variable in the sorption process
because it affects absorption and adsorption in different ways. Viscosity is
inversely proportional to temperature.  Generally, as viscosity increases,
absorption of the liquid into the interstices and capillaries of the sorbent
decreases.  Alternatively, high viscosity causes an increase in adsorption by
promoting adherence between both the liquid molecules and the liquid-sorbent
molecules.  Selection of a sorbent will be based partly on the ambient tem-
perature during use.

     The ease with which a sorbent can be applied and removed is an important
criterion that depends on the physical state of the sorbent material, the
extent of the spill, and the location of the spill (i.e., on land or water).
Sheets, pillows, pads, baths, and booms are deployed by hand; but chips,
granules, and other particles can be dispersed by mechanical blowers or
spreaders.  For spills orTwater, sorbents may be distributed by boats or air-
craft.  Removal of the sorbent-liquid combination is generally accomplished
manually, although mechanical means may aid in the collection of the sorbent.
For example, consolidated materials are picked up manually, whereas the col-
lection of loose sorbents is typically aided by skimming or vacuuming.

    If air emissions or leaching of hazardous substances can be controlled,
disposal of the contaminated sorbent material may be accomplished either
through incineration or landfill.  In some cases, treatment such as neutra-
lization may be necessary before disposal.

    Information useful for identifying and procuring sorbent materials is
presented in Table 6 along with characteristics for predicting performance.
The significance of selected sorbent characteristics, existing units of mea-
surement, and references are also presented in this table.  Most sorbent char-
acteristics, unlike those of hazardous liquids, have no units of measurement
and are generally expressed in qualitative terms.

     Data available on sorbent materials are presented in Appendix C and sum-
marized in Table 7.  The appendix contains more information than the summary
table and should be consulted for additional information on a sorbent.

     Sorbent materials can be divided by cost into three different groups.
First, the natural organic and inorganic sorbents are the least expensive,
with costs ranging between $0.01 and $0.02 per pound.  Second, treated min-
erals (a type of synthetic sorbent) have a cost range of $0.30 to $0.40 per
pound.  Third, the synthetic polymerics may vary in cost from $2.50 to $4.40
per pound.  The sorption capacity generally increases with the price, but not
as rapidly.  Thus, the least expensive sorbents are generally the most cost
effective.

                                      28

-------
N>
                                                                     TABLE 6




                                               DESCRIPTION OF CHARACTERISTICS OF SORBENT MATERIALS
CHARACTERISTICS
Brand or COMOD Nans
Generic MSBS or Description
Molecular Formula
form
Manufacture/Processor
Hataclal Coat
Penalty
Degrad ability
Flaaaublllty
Toxic Ity
Sorptlon Capacity
Retention Capacity
Affinity foi Water
SIGNIFICANCE
E.g.. Conwed, Dlaaorb, verailculite
Indicate* chemical and biological activity
I.g., 3x6' mate, 10-100 swah granule*
Contact information for Manufacturer or proceaaor
Coat per unit weight of aorbent material
Reflects ability to float
Suaceptlbility to natural chemical or biological degradation
Suaceptibility to combuatlon
Capability of harming living organlaM
Capability of aorblng a specified liquid
tendency to sorb water
UNITS

Structure/activity relationship


9/lb
g/V1, Ibe/ft3
Quality rating
Quality rating
Quality rating
Iba. llquld/lbs. material
Quality rating

-------
                                                                   TABLE 7


                                                SELECTED CHARACTERISTICS OF SORBENT MATERIALS
OJ
O
MATERIALS

feathers, wool
cellulose (straw,
sawdust, fasrk,
hulls, pest)
DESCRIPTION
DENSITY
(g/Ci.1)
DECRADABILITY, FLAMMAllLITy, TOXICITY
SORPTIVE CAPACITY
(Ibs subat/lb sorbent)
COST
(S/lb)
REFERENCE
NATURAL ORGANIC

strands, chips, powder

Conned
Sllkwlk
Sorb-Oil
trssted cellulose fiber
ground corn cob powder
recycled flberbosrd Mats, boons.
or chips

1.0

0.03
0.1*

high very high none
high very high none
TREATED ORGANIC
fslr high
high high none
high very high none
NATURAL MINERALS
cslclus) csrbonate
ash, ssnd
perllte
veralcullte

Absorbent 1012
white, slightly bsslc powder

expsnded and treated slllcste
glass grsnules
expsnded Magnesium silicate
grsnules



0.07

expsnded snd treated volcanic
rock granules
0.1
none none
none none
none none none
none none none



benzene: 12.6
phosplt. sctdi 5






pliosph. sctd: 6.5

0.01-0.02

1.36-4.40
0.11


0.01-0.02




(8)

(c)(d)(g)
(g)


(c)


(d)(g)
TREATED MINERALS
none none none
genersl: 5-7
0.33 1 (b)(g)

-------
TABLE 7
MATERIALS
Dlsorb
011-Dri
Zorbite
DESCRIPTION
silicate glaas foaai granules
crushed and expanded a»nt-
•orillonlte clay
expanded and treated ailicate
gloss granulea
OEMS ITY
0.04
0.48-0.56
0.14

Fiberperl
Sorbent C
•ixture of expanded perllte and
cellulose fiber
•Ixture of expanded perllte and
cellulose fiber
0.07
0.07
DEGRAOABIL1TY, FLAfMABlLITV. TOXICITT
none none very low
\
none none none
none none none
SORPT1VE CAPACITY
(Ibs aubst/lb sorbent)
acrylonltrlUl 10.2;
benzene: 10.6;
formaldehyde (37X): 8.6;
nitric acid (70%) i 20;
phenol (83Z): 15.5
phosphoric acid (85Z):
28; sulfurlc acid
(961): 19.2; toluene/
xylene:
acrylonltrllei 0.7;
bentene: 0.7;
formaldehyde (37%): 0.7;
nitric acid (70S): 2.2;
phenol (83Z): 1.2;
phosphoric acid (85%) :
2.0; aulfuric acid
(961) I 1.7; toluene/
xylene: 0.8

ORGANIC/MINERAL
low high none
low high none
POLYETHYLENE
Conwed-D
closed-cell, mechanically
modified foam pads
0.04
none low none


COST
(S/lb)

0.15


0.31

REFERENCE

(h)
(g)

(e)
(b)(g)


3.59 1 (g)
                                                           CONTINUED

-------
                                                             TABLE 7
MATERIALS

3H
Oil Hap
Oil Sn«r«
Quick-Wick

Grabol 1
Petro-Tr«p
Spill Control



Inbiber Beads
DESCRIPTION

polypropylene fiber In eheete,
booiia, granules
polypropylene fiber rope or mof
polypropylene atranda
treated polypropylene fiber
mala, rolla

treated polyurethane foaai
aheeca or booaa
polyurethane
polyurattiane foaai aheeta, pada,
booaa

and granulea

croaa-llnked copolyaer granulea
DENSITY
(g/c»3)

0.05
0.6-0.9
0.9
0.14
0.04

0.02





0.64
0.98
DECIDABILITY. FLAMMABILITY. TOX1CITY
POLYPROPYLENE
none fair none
\
none fair none
none fair none
none fair none
POLYURETHANE
none fair (gene re tea IICN none
on covbuetion)
none fair (generatea UCM none
on coafcuatlon)
none fair (generatea HCN none
on covbuatlon)

on conbuatlon)
CROSS-LINKED POLYMERS
very low none
SORPTIVE CAPACITY
(Iba aubat/lb aorbent)

b«nten«: 10.0
chlorofora: 17.8




general: 20
bensenei 18. B




general: up to 27
COST
(S/ll.)

2.10-4.40

2.50








2.65
REFEKENCE

(aXBX')
(b)
(b)(g)
(g)


U)
(g)



(a)(b)(g
OJ
rO
                                                                                                                               CONTINUED

-------
                                                                            TABLE  7 (CONCLUDED)
U>
U>
SOURCES!  (•)   Akera  et si., 1978.
          (b)   Arthur D. Little. 1974.
          (c)   Bauer  et ml., 1973.
          (d)   Diamond Shamrock Corp. 1979.
          (e)   Grefco, Inc.
          (()   Pill,  et •!.. 1975.
          (|)   Robertson,  1978.
          (h)   Temple et el.. 1978.
          (1)   3H Co., 1978.
                 1
                 HGA  Is composed of polyacrylainlde,  fumed  silica, polytertlary butyl etyrene, polycarboxyaethylcellulose, polyacrylonltrlle rubber.
MATKKIALS

Wlnkler Foaw
HUI.T1 -PURPOSE
GGLLING AGEHT (HGA)1

Activated Carbon
DESCRIPTION

•Ixture of polystyrene beads
with other materials
•Ixture of 4 polyserlc and 1
mineral poudei
DENSITY
(g/c.3)
DECRADA1ILITT, FLAMMABILITt, TOXICITY
SORPTIVE CAPACITY
(Ibs aubat/lb sorbeut)
COST
(S/lb)
REFERENCE
HIKED POLYMERS
0.02

none fair
\
very low



2.50
(g)
(f)
CARBON
varlea froH powder to granulea

very low none none
0.02-0.2
-
(a)(c)

-------
     Sorption of Hazardous Liquids

     Although experimental and field data are limited, the available informa-
tion on compatibilities of hazardous liquids and selected sorbent materials is
compiled in Tables 8 and 9.  Useful liquid-sorbent combinations are indicated
by a check (vO, and unsafe combinations are indicated by a cross (X).  In cas-
es where the sorption capacity is known, the check is replaced by the reported
value.

     The hazardous liquids presented in Table 8 are listed by their functional
chemical groups.  This arrangement permits ready comparison of data for the
liquids in a given functional category and extrapolation of the usefulness and
safety of the various untested combinations.  For example, data may exist for
a particular hazardous substance in combination with one or more sorbents.
This information may be useful in selecting a sorbent to be used in cleaning
up a spill involving another substance within the same functional group for
which data do not exist.  The safety and effectiveness of a selected but un-
tested sorbent should be determined  with a small amount of the spilled liquid
under controlled conditions before an actual cleanup operation is undertaken.

     As indicated by the numerous data gaps in the table, data on liquid-
sorbent combinations are generally not available.  In some cases, the avail-
able data are from extrapolations based on various properties of the hazardous
substances (e.g., viscosity, surface tension, and specific gravity).  Documen-
tation of sorption effectiveness for all categories of sorbent materials is
generally inadequate and particularly poor for the natural organic sorbents.

    For individual hazardous liquids, information deficiencies exist for
chlordane, dichloropropionic acid, methyl mercaptan, monoethylamine, naphthe-
nic acid, phosgene, propionic acid, pyrethrins, and most of the organophos-
phorous compounds.  Among the inorganic liquids, the principal data gaps are
for ammonium hydroxide, antimony pentachloride, arsenic trichloride, nitrogen
dioxide, sodium hypochlorite, sulfur monochloride, and zinc chloride.
                                     34

-------
                                                           TABLE 8*

                              COMPATIBILITY OF HAZARDOUS LIQUIDS AND SELECTED SORBENT MATERIALS
OJ










i
1
§
"

o
H
y
0









~~-~^_____^ SORBENT
~~~——--_^^^ MATERIALS
HAZARDOUS ~~~— ~— _^^
LIQUIDS ' -_^___^^

ACIDS
and
DERIVATIVES





ALCOHOLS
and
PHENOLS

ALDEHYDES
and
HE TONES


KPOX1DES
ESTERS






Acetic acid
Acetic anhydride
Butyric acid
2,2-Dlchloroproplonic acid
Foralc acid
Naplithenlc acid
Proplonlc acid
Pruplonic anhydride
Allyl alcohol
Creaol
Flienol

Acetaldehyde
Ac role In
Crotonaldehyde
Foruldehyde
Furfural
Prupylene oxide
Anyl acetate0
Butyl acetate
n- Butyl phthalate
Hethyl iKtliacrylate*
Pyrethrlna .
Vinyl acetate
f
ll

_°
-
-
-
_
-
-
-
_
_
_

_
-
-
-
-
-
_
-
-
-
-
-

3 •<

/**
/
•
-
j
/
/
J
/
/
/

/
/
/
/
*
/
/
/
/
/
-
'
A
1 CELLULOSE

-
-
/
-
_
-
-
-
_
J
/

-
-
-
Kr
-
-
/
/
-
^
-
'
.
tu
OU

ft
ft
/
-
/
/
/
-
/
/
J

/
/
-
X
/p
-
/p
/
-
l'
-
ft

IMIItERALS,
CALaUH
CARBONATE

_
-
.
-
_
-
-
-
/
..
_

_
-
-
-
-
-
_
-
-
-
-
-

h

/
/
/
-
/
/
j
-
_
/
/

/
_
.
/
*/
i
_
/
/
/
-
j

In
\
- .
131
-
-
_
-
-
-
10
13
IS

11
-
-
10
-
-
9
11
-
11
-
8
PERLITg AND
CELLULOSE, TREATED
FIBERPERL'
SORBCNT C»

_
-
-
-
-
-
-
-
_
_
_

-
~
-
-
-
-
.
-
-
-
-
-

POLYPROPYLENE
3M OIL
SORBENTh

J
J
/
-
/
-
-
J
/
,/
_

/
j
_
/
J
J
J
J
/
/
/
'
OIL SNARE1
QUICK -WICK-1

-
-
-
-
-
-
-
-
_
_
_

/
-
-
-
-
-
/
/
-
/
-
J
s
OTHEE
POLYOEFI1

-
-
-
-
-
-
-
-
-
J
-

-
-
-
-
-
-
/
•
-
/
-
/
         *References  for both Table 8 and Table 9 are found at  the end
         of  Table 9.

-------
                                                                  TABLE 8
ON












VI
§
0
O
8
0
Sj
i










SORBEHT
~ — -~. 	 MATERIALS
HAZARDOUS ' — 	 	
LIQUIDS • — - .^_^^

HALOGEN
COMPOUNDS
















HYDROCARBONS







Acatyl bnmld*
Ac«tyl chloride
Allyl chloride
Benzoyl chloride*
Benzyl chloride
Carbon tetrachloride
Chlordene
Cltlorobenzene
Chloroform
Cyanogen clilorid«
O'Uichlorobenzene
Dlchloropropene-
dlchloropropene (D-D Bllxture)
2,2-DJchloroproplanlc ecld
Mexechlorocyclopentedlene
Polychlorlneted blphenyl* (PC1'«)
Trlchloroethylene
Vinylloene chloride
Benzene*
Cyclohexene*
Ethylkenzene*
Iftaprene*
Styrene8
Toluene8
Xylene'
.
1
ZiK
§3

-
-
_
-
-
-
-
„
_
_
-
-
-
-
-
-
-
-

-
-
-
_
„
-

.§
B >
§s

/
/
/
/
/
/
j
J
/
/
/
/
/
-
-
/
/
'
x
/
/
/
/
/
'
^1
i
§
i

-
-
/
.
-
.
_
_
_
-
_
-
-
-
-
_
>
-
/
/
/
/
/
/
/
.
M
a u
§1
p g
o o

if
^
/
-
_
-
-
/p
/p
/
.
-
-
-
-
.
-
-
/
/
j
j
j
/p
/p

3s^
1^1
ail

.
-
_
/
/
-
.
_
_
_
_
-
-
-
-
_
-
-

-
_
.
_
_
-

a"
11
ii

-
-
_
-
/
/
_
/
/
_
/
-
-
-
-
/«
/
-
^
/
/
/
/
i
i

3a*
isl
SP3
\
-
-
.
-
-
19
-
12
12
_
.
-
-
-
-
10
13
-
11
7
9
-
9
11
11
PERLITH AND
CELLULOSE, TREATED
FIBERPERL'
SORBENT C»

-
-
_
-
-
-
-
_
_
-
-
-
-
-
-
-
-
-
6
-
-
-
-
_
-

POLYPROPYLENE
3M OIL
SORBENTh

/
/
/
/
/
/
/
/
IB
_
-
/
-
-
'
/
/
/
10
/
/
/
/
/
'
OIL SNARE
OUICK-UICKJ

-
-
/
-
-
-
_
_
/
-
-
-
-
-
-
-
-
-
/
/
/
^
/
/
'
(A
n>
E
1°
C o

-
-
/
/
-
-
-
_
/
/
-
-
-
-
-
/
-
-

-
/
J
J
J
/
                                                                                                                              CONTINUED

-------
TABLE 8















o
IB
8
u
1
o












• 	 ____^ 80R1ENT
" -— 	 MATERIALS
^^*~— ^^.^^
HAZARDOUS ~~~~ — -~^_^^
LIQUIDS ' ^_____^^
NITROGEN
COMPOUNDS














ORCANOMETALLIC
COMPOUNDS
ORGANOPHOSPHORUS
COMPOUNDS








Acetone cyanohydr.in
Acrylonltrlle
Aniline
Benionitrll*
Rutylanlne
DiethyUalne
Dijiethylailne
Dlnltrotoluene
Etltylenedlanlne
Hydrogen cyanide
MonoethylaBlne
Nit robencene
Qu incline
TrlethylaBlne
Trlaethylaiilne


Tetraethyl lead
Dlakinon
Dlchlorvoe
Dlaulfoton
Ethlon
Halathlon
Methyl parathion
Mevlnphoe
Naled
Patathloa
Tetraethyl pyrophoephate
*

«<
|p
53!

_
_
_
-
-
_
_
_
_
_
_*
„
_
-


-

.
_
_
_
.
_
_
_
-

B
• K
8 >
3§
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/


/
/
/
/
/
/
/
/
/
/
/

s
o
EJ
g

/
.
_
_
_
_
_
„
.
_
_
_
_
-


-

_
_
_
_
_
_
_
_
-

a
ou
3 ?
d
/
/
/
/
/
/
.
_
_
_
/
/
/
/
/


/

.
_
_
/
-
-
_
.
-

«" K
J £ ^
|§|
loa

_
_
_
.
_
_
„
_
/
_
-
_
_
-


-

_
_
_
_
_
_
„
_
-

w"
,J
gl
PC
/
/
/
_
/
J
.
_
/
/
/
/
„
/
/


J
/
/
/
/
J
/
/
/
/
-

•
ij n u
w9o
ipj_

10
1?
_
_
6
„
_
_
_
_
_
_
_.
-


-

.
„
_
_
_
_
_
_
-
PERLITE AND
CELLULOSE, TREATED

FIBERPERI.f
SORBENT Cg

_
=
„
,
_
.
_
_
_
_
_
_
_
-


-

_
.
_
_
_
-
_
_
-

POLYPROPYLENE

3M OIL
SORBENTh
/
/
/
/
/
/
/
_
/
_
/
/
/
_
/


/
/
/
/
/
/
_
/
/
j
/
OIL-SNARE
QUICK-WICK^

.
_
_
_
/
/
_
_
_
_
_
_
_
-


-
_
-
-
_
_
-
-
_
.
~
I/I
5
E
Ml
M >*
O ^

/
-
-
-
-
-
-
-
-
-
-
-
/
-


-
_
-
-
_
-
-
-
_
_
"
                                                           CONTINUED

-------
                                                                      TABLE 8 (CONCLUDED)
Co
00
CJ
H
O
M
g
O
I
^— ^_
HAZARDOUS
LIQUIDS
SULFUR
COMPOUNDS
ACIDS
INORGANIC
HAUDES
OTHER
SORBENT
-_ 	 MATERIALS
Carbon dlaulHda
Chloroaulfonlc acid
Methyl our cap tan
Hydrochloric acid
Hydrofluoric acid
Nitric acid
pho>|ihorlc acid
Su If uric acid
AntiMmy pentachloride
Araenlc trichloride
Phoaphoroua oxychloride
phoaphoroua trichloride
SodluM hypochlorlte (aolution)
Sulfur Monochloride
Zinc chloride (aolution)
AvaonliHi hydroxide
Nitrogen dioxide
REFERENCES
AHIHAL
MATERIALS*
-

-
-


CARBOR,
AcrrvATEB
J
\
J
/


CELLULOSEb '
;

-
-


aoatuco
•ISOT3T133
i

-
_


MINERALS,
CALCIUM
CARBONATE
-
>»v*
j
;
X
KIKERALS,
OTHER'
J
\
-
_
z.ee
MINERALS.
TKEATED
BAZORt
-
1*
20
26
19
» *
12
aa.bb
FERLITE AND
CEU.ULOSE, TREATED
FIBERPER1.'
SORBENT C«
-
-
'
-
X
POLYPROPYLENE
3M OIL
SORBENTh
?
]
"',
-
v.cc
OIL-SNARE
-
-
;
_
X
OTEER
POLYOEFINS
-
-
-
-
X

-------
                                                              TABLE  9


                                  COMPATIBILITY OF HAZARDOUS LIQUIDS  AND  SELECTED SORBENT MATERIALS
U>
vo










8
1
1
O
u
M
0











"" ^ — -— ~_^_^ SORBENT
~ ^"~"«— ^ _i 	 HATE RI ALS
HAZARDOUS "~ — • — — -^_^
LIQUIDS " ' — ^___^

ACIDS
and
DERIVATIVES





ALCOHOLS
•nd
PHENOLS
ALDEHYDES
and
KETONES


EPOXIDES
ESTERS





Ac. tic acid
Acetic anhydride
Butyric acid
2,2-Dlchloropropionlc meld
Foralc acid
Naphthenic acid
Proplonlc acid
Propionic anhydride
Allyl alcohol
Creaol
Phenol
Acataldchyde
Acrolein
CrotonaldeKyda
Formaldehyde
Furfural
Propylenc oxlda
A»yl acetate*
Butyl acetate
n-Butyl phthalate
Methyl aethacrylate*
Pyrethrlna
Vinyl acetate
POLYURETHANES

GRABOILk


_
-
-
_
_
-
-
.
_
-
_
_
_
_
-
-
.
-
-
-
_
-

PETRO-TRAP1


_
-
-
_
_
-
-
.
_
/
/
-
_
-
-
-
.
-
-
-
-
-
ssc
ABSORBENT*

\ "~
\^
-
.
_
.
-
-

/
-
.
_
_
.
-
-
/
/
-
/
_
/
. ^§g_
£|i3|
S n o S in


.
-
^
..
-
-
-
.
_
-
_
~
-
-
-
-
.
-
-
-
-
-
M O
Pg§g
E| B p 8

/
/
/
-
J
J
^
~
.
/
/
/
-
-
/
/
/
.
/
j
J
-
/

-------
TABLE 9








}3
g
o
i
o
s
&
°











	 — ---_
HAZARDOUS
LIQUIDS
HALOGEN
COMPOUNDS
















HYDROCARBONS






SORBENT
~~ MATERIALS
Acetyl broeilde
Acetyl chloride
Allyl chloride
Benxoyl chloride
Benzyl chloride
Carbon tetrachlorlde
Chlordane
Chlorobenzene
Chloroforei
Cyanogen chloride
Dlcliloropropene-
dlchloropropene (D-D Mixture)
2 ,2-Dichloroproplonlc ecld
Hexachlorocyclopentadiene
Phoegene
Polychlorlnated biphenyU (PCB'e)
Trlchloroethylene
Vlnylldene chloride
Beniene*
Cyclohexene*
Bthylbentene*
laoprene*
Styrene*
Toluene*
Xylene*

CRABOll>
..
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
14
-
-
-
-
-
-
POLYURE THANKS
PETRO-TRAP1
- \
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
19
_
-
-
-
_
-

ssc
ABSORBENT*
_
-
/
/
-
-
-
-
/
J
-
-
-
-
-
-
-
-
/
-
J
-
J
/
/
Ig,,
§3§Sa
_
-
-
-
/
/
-
/
/
-j
/
-
-
/
-
-
/
-
/
-
j
/
/
j
'
Kg
M O M H
S H dS
S S o <
.
-
-
-
J
•1
-
J
/
-J
-
-
-
-
-
/
/
-
J
J
J
/
/
/
'
                                                          CONTINUED

-------
TABLE 9










s
g
o
g
o
u
t_l

a












— — -^_ 	 SORBENT
• — 	 	 MATERIALS
HAZARDOUS — __^^
I QUIDS 	 	 ______^^
N1TROCEH
OOHPOUNDS













ORGANOMETALLIC
COMPOUNDS
ORCANOPHOSPIIORUS
COMPOUNDS








Acetone cyanohydrln
Acrylonltrlle
Aniline
Benzonlcrlle
Butylaailne
Dlethylailne
DlnethylaBlne
Dlnltrotoluene
Ethylenediaailne
Hydrogen cyanide
MonoethylMlne
Nitrobenzene
Qu Incline
Trlethylaalne
TrlBethylaalne

Tatraethyl lead
Dlazlnon
Dlchlorvoa
Diaulfoton
Kthlon
Malathlon
Methyl parathlon
Hevinphoa
Haled
Parathlon
Tetraethyl pyrophoaphate
POLYURETHANES

CRABOILk
_
-
_
-
-
-
-
-
-
-
-
-
-
-
-

-

-
-
-
_
-
-
-
_
-

PETRO-TRAPI
\
-
_
-
-
-
-
-
-
-
-
_
-
-
-

-

-
-
-
-
-
•*
-
_
-
ssc
ABSORBENT"
_
/
_
-
-
/
/
-
/
-
-
_
-
/
-

-

-
-
-
-
-
-
.-
_
-
el
K§^ H§
§§§Sa
_
-
_
-
-
-
-
-
-
-
-
_
-
-
-

-

-
-
-
-
-
~
-
-
-
gia
y*
Pn H
ft d S

j
j
j
-
j
/
-
~.
/
_
J
/
-
/
J

-
/
/
/
/
/
/
/
j
/
-
                                                        CONTINUED

-------
                                                      TABLE 9 (CONCLUDED)
NJ
8
s
fe
u
M
5
0




§
1
o

M
3
M
a



" ^_^_^ SORBEHT
HAZARDOUS " 	
LIQUIDS ' 	 -^____^
SULFUR
COMPOUNDS

ACIDS




INORGANIC
HAL I DCS





OTHER

Carbon dleulflde
Chloroaulfonlc acid
Methyl acrcaptan
Hydrochloric acid
Hydrofluoric acid
Nitric acid
Phoaphorlc acid
Sulfuric acid
AntlaKtny pantachlorlde
Araenlc trichloride
Plioaphoroua oxychlorlda
Phoaphoroua trichloride
Sodiua hypochlorlte (solution)
Sulfur Bonochlorlde
Zinc chloride
AMonliM hydroxide
Nitrogen dioxide
REFERENCES
POLYURETIIANES

CRABOIL*

-
-
.
-
-
-
-
.
.
-
-
-
_
-

-
X

PETRO-TRAF1

.
-
„
-
-
-
-
_
.
-
-
-
_
-
.
-
X

ssc
ABSORBENT11
\ -
_
-
.
-
~
-
-
.
-
-
-
-
_
-
.
-
v,x
^ «a
w BoHg
§"§Sa

_
-
.
.
_
-
-
.
-
-
-
-
_
-
-
-
V
M W
C|3g
^l§§
,,
/
*
.
-
~
-
J
.
_
.
-
-
_
-
/
-
r.dd

-------
                                               REFERENCES  FOR TABLES 8 AND 9
              aWool, feathers, leather shavings.
               Bark, hulls, peat moss, sawdust,  straw.
              Proprietary product of Conwed  Corporation.  Information la abstracted from company's advertising materials.
              d                                                                     \
               Ash, clays, perlite, sand,  vermlculite.
               Proprietary product of Diamond Shamrock  Corporation.
               Proprietary product of Grefco,  Inc.
              Proprietary product of Clean Hater,  Inc.
              ^Proprietary product of 3M Company.   Information Is abstracted from company's advertising materials.
               Proprietary product of Parker  Systems, Inc.
**            -"Proprietary product of Clark-Cutler-McDermott  Company.
              k
               Proprietary product of RBH  Cybernetics,  Ltd.
               Proprietary product of Best Textile  Company.
               Proprietary product of Sorbent Sciences  Corporation.
              "Proprietary product of Dow  Chemical  Company.
               "-" Indicates data was not  available and
               "/" represents compatible combinations as  found in the literature referenced.
              pConclusion based on experimental  data.
              "Numbers represent absorption capacity (mass of material sorbed  per unit  mass of  sorbent) ,
               based on experimental data.
              r"x" Represents Incompatible combinations.
              8Insoluble floater.
               Calcium carbonate should not be used on  concentrated  acids.
              UBocard C., P. Renault and J. Croquette,  1979.   "Cleaning  Products Used In Operations After the
               Amoco Cadiz Disaster", pp 163-167, in Proceedings  of  the  1979 Oil Spill  Conference. March  1979,
               Los Angeles, California.  API  Publication No.  4308, American Petroleum Institute,  Washington, D.C.
              VAkers,  C.  K.,  R.  J.  Pilie,  and  J. C.  Michalovlc, 1978. Guidelines for the Use of Chemicals in Removing
               Hazardous Substance Discharges.   Draft,  prepared under Contract No.  68-03-2093 for National
               Environmental Research Center,  U.S.  Environmental  Protection Agency,  Cincinnati, OH.

-------
                                REFERENCES FOR  TABLES  8 AND 9 (CONCLUDED)
 WSoden, J.E. and J.C. Johnson, 1978.   "Burial and Other High Potential Response Techniques for
  Spills of Hazardous Chemicals that Sink",  pp 202-207,  In Proceedings of 1978 National Conference
  on Control of Hazardous Material Spills, April 1978, Miami Beach,  FL.  Information Transfer,  Inc.,
  Rockville, MD.

 XBauer; W.H., D.N. Borton, and J.J. Bulloff.  1975.  Agents, Methods and Devices for Amelioration
  of Discharges of Hazardous Chemicals  on Water.  Report No. CG-D-38-76, U.S.  Coast Guard,
  Washington, D.C.

 'Conued Corporation, 1976.  Sorbents and Hazardous Materials Data Sheet, Form 615-056.  Conwed
  Corporation, St. Paul, MN.

 "pille, R.J., R.E. Baler, K.C. Ziegler.  R.P.  Leonard, J.G.  Mlchalovic, S.L.  Pek and D.H.  Bock,
  1975.  Methods to Treat,Control and Monitor  Spilled Hazardous  Materials.  EPA-670/2-75-OA2,
  National Environmental Research Center, U.S. Environmental Protection Agency, Cincinnati, OH.
aa                                            *^^
  Diamond Shamrock Corporation, 1979.   "Hazorb   Universal Absorbent for Hazardous  Substances"
  Technical Bulletin SP-LDS-4C, Diamond Shamrock Corporation, Cleveland, OH.

  Temple, R.E., W.T. Goodlng, P.F. Woe me r,  and G.F. Bennett, 1978.   "A New Universal Sorbent For
  Hazardous Spills", pp 382-383, in Proceedings of 1978  National Conference on Control of  Hazardous
  Material Spills, April 1978, Miami Beach.  FL.   Information Transfer,  Inc.,  Rockville, MD.

CC3M Company, 1978.  "3M Oil Sorbent and  Hazardous Liquid Materials",  Technical Bulletin No. 78-1.
  Occupational Health and Safety Products Division, 3M Company,  Saint  Paul, MN.

ddMichalovic, J.G., C.K. Akers, R.E. Baler,  and R.J. Pille,  1977.  Multipurpose Celling Agent
  and Ita Application to Spilled Hazardous Substances.   EPA-600/2-77-151, Industrial Environmental
  Research Laboratory, U.S. Environmental Protection Agency, Cincinnati, Oil.

  Andeslte of California,  Inc.,  1980.   "SAFESTEP Product  Bulletin and Specifications."  Andeslte
  of California,  Inc.,  Los Angeles,  CA.

-------
                                  REFERENCES
Akers, C.K., R.J. Pilic, and J.G. Michalovic, 1978.  Guidelines for the Use of
     Chemicals in Removing Hazardous Substance Discharges. U.S. Environmental
     Protection Agency, Industrial Waste Treatment Laboratory, Edison, New
     Jersey.

American Mutual Insurance Alliance, 1972.  Handbook of Organic Industrial Sol-
     vents.  Technical Guide No. 6, Fourth Edition.  American Mutual Insurance
     Alliance, Chicago, Illinois.

Arthur D. Little, Inc., 1974.  Response Methods Handbook.  Appendix A, Chemi-
     cal Hazardous Response Information System (CHRIS).  U.S. Coast Guard,
     Washington, DC.

Bauer, W.H., D.N. Borton and J.J. Buloff, 1975.  Agents, Methods, and Devices
     for Amelioration of Discharges of Hazardous Chemicals on Water.  U.S.
     Coast Guard, Washington, DC.

Bocard, C., P. Renault, and J. Croquette, 1979.  "Cleaning Products Used in
     Operations After the Amoco Cadiz Disaster."  Proceedings of the 1979 Oil
     Spill Conference,  pp. 163-167 March 1979.  Los Angeles, California.  API
     Publication No. 4308, American Petroleum Institute, Washington, DC.

Conwed Corporation, 1976.  "Sorbents and Hazardous Materials." Product Data
     Sheet.  The Chemical Rubber Company.  Conwed Corporation, Environmental
     Products Division, St. Paul, Minnesota.

Diamond Shamrock Corporation, no date.  Diasorb Sodium Silicate Material Data
     Sheet.  Diamond Shamrock Corporation, Soda Products Division, Cleveland,
     Ohio.

Diamond Shamrock Corporation, 1979.  "Hazorb™ Universal Absorbent for Hazard-
     ous Materials."  Technical Bulletin, Diamond Shamrock Corporation, Soda
     Products Division, Cleveland, Ohio.

Dorigan J., B. Fuller, and R. Duffy, 1976.  Scoring of Organic Air Pollutants:
     Chemistry, Production, and Toxicity of Selected Synthetic Organic Chemi-
     cals.  MTR-7248, The MITRE Corporation, McLean, Virginia.

Grefco, Inc., no date.  Data Sheet for Fiberpool.  Grefco, Inc., Los Angeles,
     California.

3M Company, 1978.  Oil Cleanup and Control News.  3M Company, Minneapolis,
     Minnesota.

                                      45

-------
Michalovic, J.G., C.K. Akers, R.E. Baler, and R.J. Pilie, 1977.  Multipurpose
     Gelling Agent and Its Application to Spilled Hazardous Substances.
     EPA-600/2-77-151, Industrial Environmental Research Laboratory, U.S.
     Environmental Protection Agency, Cincinnati, Ohio.

National Fire Protection Association, 1977.  National Fire Protection Guide on
     Hazardous Materials.  National Fire Protection Association, Washington,
     DC.

Pilie, R.J., R.E. Baier, R.C. Ziegler, R.P. Leonard, J.G. Michalovic, S.L. Lek
     and D.H. Book, 1975.  Methods to Treat, Control, and Monitor Spilled
     Hazardous Materials.  U.S. Environmental Protection Agency, National
     Environmental Research Center, Cincinnati, Ohio.

Rice University, 1977.  Research on Hazardous Substances in Support of Spill
     Prevention Regulations.  Report of Activities Data Sheets, Vol. V,
     Houston, Texas.

Robertson, L.A., 1978.  Selection Criteria and Laboratory Evaluation of Oil
     Spill Sorbents.  Canadian Department of Fisheries and the Environment,
     Montreal, Canada.

Sax, N.I., 1968.  Dangerdus Properties of Industrial Materials.  Third Edi-
     tion, Van Nostrand Reinhold Co., New York, New York.

Swanson, C.E., 1978.  Conwed Corp., St. Paul, Minnesota.  6 June.  Personal
     Communication.

Soden, J.E. and J.C. Johnson, 1978.  "Burial and Other High Potential Response
     Techniques for Spills of Hazardous Chemicals that Sink."  Proceedings of
     1978 National Conference on Control of Hazardous Material Spills,  pp.
     202-207.  April 1978, Miami Beach, Florida.  Information Transfer, Inc.,
     Rockville, MD.

Temple, R.E., W.T. Gooding, F.F. Woerner and G.F. Bennett, 1978.  "A New
     Universal Sorbent for Hazardous Spills."  Proceedings of the 1978
     Conference on Control of Hazardous Materials Spills.  Miami Beach,
     Florida.

The Chemical Rubber Company, 1972.  Handbook of Chemistry and Physics, 52nd
     Edition.  The Chemical Rubber Company, Cleveland, Ohio.

U.S. Department of Transportation, 1975.  Hazardous Materials Table and Com-
     munications Regulations.  Code of Federal Regulations, Vol. 49, Part 172,
     U.S. Department of Transportation, Washington, DC.

U.S. Environmental Protection Agency, 1977.  "Hazardous Substances Facts
     Sheets."  Criteria and Standards Division, Marine Activities Branch,
     Water and Hazardous Materials, U.S. Environmental Protection Agency,
     Washington, D.C.
                                     46

-------
U.S. Environmental Protection Agency, 1978a.  Data base, "Oil and Hazardous
     Materials-Technical Assistance Data System (OHM-TADS)."  U.S. Environ-
     mental Protection Agency.

U.S. Environmental Protection Agency, 1978b.  "Water Programs—Hazardous Sub-
     stances."  Federal Register Vol. 43, No. 49,  March .S. Environmental
     Protection Agency.

U.S. Environmental Protection Agency, 1979a.  "Water Programs—Hazardous Sub-
     stances."  Federal Register, Vol^ 44, No. 3, February 16, U.S. Environ-
     mental Protection Agency.

U.S. Environmental Protection Agency, 1979b.  "Water Programs: Determination
     of Reportable Quantities for Hazardous Substances."  Federal Register,
     Vol. 44, No. 169, August 29, U.S. Environmental Protection Agency.

Verschueron, K., 1977.  Handbook of Environmental Data on Organic Chemicals.
     Van Nostrand Reinhold Co., New York.

Windholz, M. (ed.), 1976.  The Merck Index, Ninth Edition.  Merck & Co.,
     Rahway, New Jersey.
                                     47

-------
-p-
00
                                                                 APPENDIX A



                                                          LIST OF HAZARDOUS LIQUIDS
                                       HAZARDOUS SUBSTANCE
Acetaldehyde


Acetic acid


Acetic acid butyl ester (See:  Butyl acetate)


Acetic acid ethylene ether (See:  Vinyl acetate)


Acetic aldehyde (See:  Acetaldehyde)


Acetic anhydride


Acetic oxide (See:  Acetic anhydride)


Acetone cyanohydrln


Acetyl bromide


Acetyl chloride


Acetyl oxide (See:  Acetic anhydride)


Acraldehyde (See:  Acroleln)


Acroleln


Acryaldehyde (See:  Acroleln)


Acrylic aldehyde (See:  Acroleln)


Aerylonltrlie


Allyl alcohol
                                                                                  CAS HO.
                                                                                  75-07-0
108-24-7





 75-86-5


506-96-7


 75-36-5








107-02-8
                                                                                 107-13-1


                                                                                 107-18-6
                                                                                 CHEMICAL GROUP
            Aldehydes and Ketones


            Organic Acids and Derivatives
Organic Acids and Derivatives






Nitrogen Compounds


Halogen Compounds


Halogen Compounds









Aldehydes and Ketones
            Nitrogen Compounds


            Alcohols and Phenols

-------
                                                   APPENDIX A
                    HAZARDOUS SUBSTANCE
Allyl chloride

Alpha hydroxylsobutyronltrlle (See:  Acetone cyanohydrin)

Amlnobenzene (See:  Aniline)

Amlnobutane (See:  Butylamine)

Amlnoethane (See:  Monoethylamlne)

Amlnophen (See:  Aniline)

Ammonium hydroxide

Amyl acetate (amylacetic ester)
        n-
        iao-
        sec-
        tert-
Anlllne
Aniline oil (See:  Aniline)

Antimony pentachloride

Aqua fortls (See Nitric acid)

Arochlor (See:  Polychlorinated Blphenyla)

Arsenic chloride (See:  Arsenic Trichloride)
                                                               CAS NO.
 107-05-1

      \
1336-21-6
 628-63-7
 123-92-2
 676-38-0
 625-16-1

  62-53-3
7647-18-9
                    CHEMICAL GROUP
Halogen Compounds
Inorganic Compounds:  Other
                                                                          Esters
Nitrogen Compounds
Inorganic Halides
                                                                                                               CONTINUED

-------
                                                                  APPENDIX A
Ui
O
                                      HAZARDOUS SUBSTANCE
Arsenic trichloride


Arsenious chloride (See:  Arsenic trichloride)


Arsenous chloride (See:  Arsenic trichloride)


Banana oil (See Amyl acetate)


Basudln (See:  Dlazlnon)


1-Benzazlne  (See:  Qulnollne)


Benzene
                  Benzene chloride (See:  Chlorobenzene)


                  Benzenecarbonyl chloride (See:  Benzoyl chloride)


                  1,2-Benzene dicarboxyllc acid, dlbutyl ester
                                          (See:  n-Butyl phthalate)


                  Benzol  (See:  Benzene)


                  Benzonitrlle


                  Benzo(b)pyridlne (See:  Qulnollne)


                  Benzoyl chloride


                  Benzyl chloride


                  Bleach  (See:  Sodium hypochlorlte)


                  Butanolc acid (See:  Butyric acid)
                                                                                 CAS NO.
                                                                               7784-34-1
                                                                                 71-43-2
                                                              100-47-0




                                                               98-88-4


                                                              100-44-7
                                                                                                   CHEMICAL GROUP
                                                                                            Inorganic Halides
Hydrocarbons
Nitrogen Compounds





Halogen Compounds


Halogen Compounds
                                                                                                                                CONTINUED

-------
                                                   APPENDIX  A
                    HAZARDOUS SUBSTANCE
1-Butanol- 3-methyl acetate

2-Butenal  (See:  Crotonaldehyde)

Butter of arsenic (See:  Arsenic trichloride)

Butter of zinc (See:   Zinc chloride)

Butyl acetate.
        n-
        iso-
        sec-
        tert-
Butylamlne,
        n-    (Aroinobutane)
        lao-  (2-Methyl-l-propanamlne)
        sec-  ((a)-2-Butanamlne)
        tert- (2-Methyl-2-propanamine)
n-Butyl phthalate
Butyric acid
        n-
        iso-

Carbollc acid (See:  Carbon Jlsulflde)

Carbon dlaulflde
Caroon tetrachlorlde
                                                               CAS NO.
123-86-4
110-19-0
105-46-4
540-88-5
109-73-9
 78-81-9
513-49-5
 75-64-9

 84-74-2
107-92-6
 79-31-2
 75-15-0

 56-23-5
                                                                                 CHEMICAL GROUP
                                                                          Esters
Nitrogen Compounds




Esters


Organic Acids and Derivatives'1




Sulfur Compounds

Halogen Compounds
                                                                                                                CONTINUED

-------
                                                                    APPENDIX A
Ul
                                       HAZARDOUS SUBSTANCE
Carbonyl chloride (See:  Phosgene)




Chlnolelne (See:  Qulnollne)




Chlordan (See:  Chlordane)




Chlordane




Chlorallylene (See:  Allyl chloride)




Chlorobenzene




Chloroform




Chloroforroyl chloride (See:  Phosgene)




Chloromethyl benzene (See:  Benzyl chloride)




3-Chloropropene (See:  Allyl chloride)




3-Chloropropylene (See:  Allyl chloride)




Chloroaulfonlc acid
                   Cinnamene  (See:   Styrene)




                   Cinnamol  (See:   Styrene)
                                                                                  CAS NO.
 57-74-9









108-90-7




 67-86-3
                                                                                7790-94-5
                                                                                 CHEMICAL GROUP
Halogen Compounds









Halogen Compounds




Halogen Compounds
                                                                                             Sulfur Compounds
                                                                                                                               CONTINUED

-------
                                                              APPENDIX A
U>
                                   HAZARDOUS SUBSTANCE
                Creaol  mixture (Cresylic acid)
        P-

Cro tona Xdehyd e

Cyanobenzene (See:  Benzontrlle)

Cyanoethylene (See:  Acrylonitrile)

Cyanogen chloride

Cyclohexane

Cyclohexanecarboxylic acid (See:  Napththenlc acid)

Dalapon (See:  2,2-Dlchloroproptonlc acid)

D-D mixture (See:  Dlchloropropene-Dlchloropropane)

DDVP (See:  Dlchlorvos)

1,2-IHaminoe thane (See:  Ethylenedlamlne)

Dlazlnon
                Olazltol (See:  Dlazlnon)

                Dibrom (See:  Naled)
                                                                               CAS NO.
1319-77-3

 108-39-^
  95-48-7
 106-A4-5

4170-30-3
                                                                              506-77-4

                                                                              110-82-7
                                                                              333-41-5
                                                                                                 CHEMICAL GROUP
                                                                          Alcohols and Phenols
                                                                                          Aldehydes and Ketones
             Halogen Compounds

             Hydrocarbons
             Organophosphorus Compounds
                                                                                                                                CONTINUED

-------
                                                                      APPENDIX A
Ui
                                           HAZARDOUS  SUBSTANCE
                       n-Dlbutyl phthalate  (See:   n-Butyl  phthalate

                       Dichlorobenzene
     o-
     p-  (solid)

1,1 Dlchloroethene (See;  .Vinylidene chloride)

1,1-Dlchloroethylene (See:  Vlnylldene chloride)

Dlchloropropane (aee mixture below)

Dlchloropropene (see mixture below)

Dichloropropene-Dlchloropropane mixture

2,2-Dlchloropropionlc acid

2,2-Dlchlorovlnyl dimethyl phosphate (See:  Dlchlorvos)

Dichlorvoa (DDVP)

Diethylamine

Dime thy lapiine

Dimethyl benzene (See:  Xylene)

Dimethyl parathlon (See:  Methyl parathlon)

Dlnltrotoluene
                                                               CAS NO.
25321-22-6

   95-50-1
  106-46-7
                                                                                     8003-19-8

                                                                                       75-99-0



                                                                                       62-73-7

                                                                                      109-89-7

                                                                                      124-40-3
                                                                                    25321-14-6
                                                                                                        CHEMICAL GROUP
                                                                           Halogen Compounds
              Halogen Compounds

              Organic Acids and Derivatives



              Organophosphorus Compounds

              Nitrogen Compounds

              Nitrogen Compounds
                                                                                                  Nitrogen Compounds
                                                                                                                               CONTINUED

-------
                                                                 APPENDIX A
ui
                                    HAZARDOUS SUBSTANCE
               Dlphosgene  (See:   Phosgene)




               Dlpofene  (See:  Dlazlnon)




               Disulfoton
Dl-Syston (See:  Dlaulfoton)




Dlthiocarbonlc anhydride (See:  Carbon disulflde)




DNT (See:  Dlnltrotoluene)




DNTP (See:  Parathlon)




Eplchlorohydrln




Etlianol (See;  Acetaldehyde)




Ethlon
               Ethylacetlc acid  (See:  Butyric acid)




               Ethyl aldehyde  (See:  Acetaldehyde)




               Ethylamine  (See:  Monoethylaraine)




               Ethyl benzene




               Ethylenediamlne




               Ethylene  dlbromlde




               Ethylene  dichloride
                                                                               CAS NO.
                                                                      \




                                                               298-04-4
                                                                               563-12-2
                                                               100-4 1-4




                                                               107-15-3
                                                                                                 CHEMICAL GROUP
                                                                                           Organophospliorus Compounds
Organophosphorus Compounds
Hydrocarbons




Nitrogen Compounds
                                                                                                                                CONTINUED

-------
                                               APPENDIX A
                    HAZARDOUS SUBSTANCE
                                                               CAS NO.
                                                                                  CHEMICAL  GROUP
Ethylene trichloride  (See:  Trichloroethylene)



Ethyl methylene  (See:  Ethlon)




Fluohydrlc acid  (See:  Hydrofluoric acid)




Formaldehyde




Formalin (See:   Formaldehyde)




Formic acid
Furalgrain (See:  Acrylonltrile)




2-Furaldehyde  (See:  Furfural)




Furfural
Glacial acetic acid  (See:  Acetic acid)




Hexachlorocyclopentadlene



Hexahydrobenzene (See:  Cyclohexane)




Hexahydrobenzolc acid (See:  Naphtheiilc acid)




Hydrochloric acid




Hydrocyanic acid (See:  Hydrogen cyanide)




Hydrofluoric acid
  50-00-0
  64-18-6
  98-01-1
  77-47-4
7647-01-0
7664-39-3
             Aldehydes and Ketonea
                                                                           Organic Acids and Derivatives
Aldehydes and Ketonea
Halogen Compounds
Inorganic Acids
Inorganic Acids
                                                                                                             CONTINUED

-------
APPENDIX A
HAZARDOUS SUBSTANCE
Hydrogen chloride (See: Hydrochloric acid)
Hydrogen cyanide
Hydroxybenzene (See: Phenol)
Hydroxy toluene (See: Cresol)
laoprene
Kyanol (See: Aniline)
Lead tetraethyl (See: Tetraethyl lead)
Leucol (See: Qulnollne)
Leucollne (See: Qulnollne)
Malathlon
Mercaptomethane (See: Methyl mercaptan)
Methacryllc acid methyl ester (See: Methyl methacrylate
Methanethlol (See: Methyl mercaptan)
Methanolc acid (See: Formic acid)
Methyl aldehyde (See: Formaldehyde)
Methylbenzene (See: Toluene)
CAS NO.
74-9Q-8
78-79-5
121-75-5
CHEMICAL CROUP
Nitrogen Compounds
Hydrocarbons
Organophosphorus Compounds
                                                            CONTINUED

-------
                                                                APPENDIX A
Ui
oo
                                       HAZARDOUS SUBSTANCE
2-Methyl-l,3-butatliene (See:  Isoprene)



2-Methyllactonltrile  (See:  Acetone cyanohydrln)


Methyl mercaptan


Methyl methacrylate


Methyl-2-methyl-2-propenoate (See:  Methyl methacrylate)


Methyl parathlon


Methyl aulfhydrate (See:  Methyl mercaptan)


Mevinphofl


Monochlorobenzene (See:  Chlorobenzene)


Honoethylamine


Muriatic acid (See:  Hydrochloric acid)


Naled


Naplithenlc acid


Nlalate (See:  Ethlon)


Nlran (See:  Parathlon)


Nitric acid
                                                               CAS NO.
  74-93-1


  80-62-6





 298-00-0





7786-34-7





  75-04-7





 300-76-5


1338-24-5









7697-37-2
                                                                                 CHEMICAL GROUP
Sulfur Compounds


Eaters






Organophoaphorus Compounds






Organophosphorus Compounds






Nitrogen Compounds






Organophosphorus Compounds


Organic Acids and Derivatives









Inorganic Acids
                                                                                                                               CONTINUED

-------
                                                                    APPENDIX A
VD
                                     HAZARDOUS SUBSTANCE
                 Nitrobenzene
Nitrobenzol (See:  Nitrobenzene)




Nitrogen dioxide




Nitrogen tetroxlde (See:  Nitrogen dioxide)




Nltrotoluene




Nltrox-80 (See:  Methyl parathlon)




Oil of Mlrbane (See:  Nitrobenzene)




Oil of Vitriol (See:  Sulfurlc acid)




Oleum (See:  Sulfurlc acid)




Orthophosphorlc acid (See:  Phosphoric acid)




Oxybenzene (See:  Phenol)




Parathlon
                 PCB  (See:  Polychlorlnated blphenyls)




                 Pentyl acetate  (See:  Amyl acetate)




                 Perchloromethane  (See:  Carbon tetrachlorlde)




                 Phenol
                                                                                CAS NO.
                                                                                 98-95-3
                                                                              10102-44-0
                                                                                 56-38-2
                                                               108-95-2
                                                                                                  CHEMICAL GROUP
                                                                                            Nitrogen Compounds
Inorganic Compounds:  Other
Organophosphorus Compounds
Alcohols and Phenols
                                                                                                                                CONTINUED

-------
                                                 APPENDIX A
                    HAZARDOUS SUBSTANCE
  CAS NO.
                                                                                 CHEMICAL GROUP
Phenylamine (See:  Aniline)

Phenyl cyanide (See:  Benzonitrile)

Phenylethane (See:  Ethylbenzene)

Phenylethylene (See:  Styrene)

Phenyl hydroxide (See:  Phenol)

Phenylmethane (See:  Toluene)

Phosdrln (See:  Mevlnphos)

Phosgene

Phosphoric acid

Phosphorodlthloate (See:  Ethlon)

Phosphorus chloride (See:  Phosphorus oxychlorlde or
                           Phosphorus trichloride)

Phosphorus oxychlorlde

Phosphorus trichloride

Pliosphoryl chloride (See:  Phosphorus oxychlorlde)

Phosphothldn (See:  Malathlon)
   75-44-5

 7664-38-2
10025-87-3

 7719-12-2
Halogen Compounds

Inorganic Aclda
Inorganic Hallde

Inorganic Hallde
                                                                                                            CONTINUED

-------
                                               APPENDIX A
                    HAZARDOUS SUBSTANCE
                                                               CAS NO.
                                                                                 CHEMICAL GROUP
Polychlorlnated biphenyls

Polychlorlnated dlphAnyla (See:  Polychlorlnated biphenyls)

Prioderm (See:  Halathlon)

Propanolc acid (See:  Proplonlc acid)

Propanolc anhydride (See:  Proplonlc anhydride)

Proparglte

2-Propenal (See:  Acroleln)

Propenenltrile (See:  Acrylonltrlle)

Propene oxide (See:  Propylene oxide)

2-Propen-l-ol (See:  Allyl alcohol)

Propionlc acid

Proplonlc anhydride

Propylene aldehyde  (See:  Crotonaldehyde)

Propylene oxide

Pyrethrlna

     I
    II
1336-36-3
  79-09-4

 123-62-6



  75-56-9
 121-21-1
 121-29-9
Halogen Compounds
Organic Acids and Derivatives

Organic Acids and Derivatives



Epoxldes



Esters
                                                                                                              CONTINUED

-------
                                                                      APPENDIX A
NJ
                                       HAZARDOUS SUBSTANCE
Pyromucic aldehyde (See:  Furfural)




Qulnoline




Sodium hypochlorite




Spectracide (See:  Dlazlnon)




Styrene




Styrol (See:  Styrene)




Styrolene (See:  Styrene




Sulfur chloride (See:  Sulfur monochlorlde)




Sulfurlc acid
                   Sulfur monochlorlde
                   Sulfurlc chlorohydrln (See:  Chlorosulfonlc acid)




                   TEL (See:  Tetraethyl lead)




                   TEPP (See:  Tetraethyl pyrophosphate)




                   Tetrachloromethane (See:  Carbon tetrachlorlde)




                   Tetraethyl lead




                   Tetraethyl pyrophoapliate
                                                                                  CAS NO.
                                                                                   91-22-5




                                                                                 7681-52-9









                                                                                  100-42-5
                                                                                 7664-93-9




                                                                                10025-67-9
                                                                78-00-2




                                                               107-49-3
                                                                                                     CHEMICAL GROUP
Nitrogen Compounds




Inorganic Halldes









Hydrocarbons
Inorganic Acids




Inorganic Halldes
Organometalllc Compounds




Organophosphorus Compounds
                                                                                                                               CONTINUED

-------
                                               APPENDIX A
                    HAZARDOUS SUBSTANCE
                                                               CAS NO.
                                                                                   CHEMICAL GROUP
TMA (See:  Trlmethylamlne)




Toluene
Toluol (See;  Toluene)




Toxichlor (See:  Chlordane)




TrIchloroe thylene




Trichloromethane (See:  Chloroform)




Trlethylamlne




Trlmethylamlne




Vapona (See:  Dlchlorvos)




Ventox (See:  Acrylonitrile)




Vidden D (See:  Dlchloropropene-Dlchloropropane)




Vinegar acid (See:   Acetic acid)




Vinyl acetate




Vlnylbenzene (See:   Styrene)




Vinyl carblnol (See:  Allyl alcohol)




Vinyl cyanide (See:  Acrylonltrlle)
108-88-3













 79-01-6









121-44-8




 77-50-3
108-05-4
Hydrocarbons














Halogen Compounds









Nitrogen Compounds




Nitrogen Compounds
            Esters
                                                                                                         CONTINUED

-------
                                        APPENDIX A  (CONCLUDED)
HAZARDOUS SUBSTANCE
Vlnylldene chloride
Xylene (mixed)
m-
o-
P-
Zlnc chloride

CAS NO.
75-35-4
1330-20-7
108-38-3
95-47-6
106-42-3
7646^85-7

CHEMICAL CROUP
Halogen Compounds
Hydrocarbons
Inorganic Hal ides

SOURCE:  U.S. Environmental Protection Agency, Water Programs.  Hazardous Substances.
         Federal Register, Vol. 43, No.  49,  March 13, 1978;  and Vol. 44, No. 34, Part IV,
         February 16, 1979.

Notes:   The chemical name underlined Is used In the reference documents and In this report.
         Synonyms for these chemicals are also Included with reference to the primary listing.
         CAS NO.
                     Chemical Abstract Series Number

-------
                                      APPENDIX B

                            HAZARDOUS SUBSTANCES DATA SHEETS
                                       IDENTIFICATION


•  NAME:  ACETALDEHYDE

•  SYNONYMS:  Ethanal, ethyl aldehyde, acetic aldehyde
                                                                      CAS  NO . :  75070
 •  MOLECULAR  FORMULA:
                                                •   STRUCTURAL  FORMULA:
                                                   CH,  -
                                                           H
                                PHYSICAL/CHEMICAL  PROPERTIES
•  SPECIFIC GRAVITY (water-1) :  0.8
                                                •   VAPOR DENSITY  (air-1) :  1.5
•  VISCOSITY  (centipoises) :  0.2 (? 2Q°C         •   SURFACE TENSION  (dynes /cm) :  -
•  MELTING POINT (°C) :  -123.5
•  FLASH POINT (°C) :   -37.8
                                                •  BOILING  POINT  (°C) :  21
                                               •   IGNITION TEMP.  (°C) :  175
•  VAPOR PRESSURE (mm Hg) :  92.3  @  25°C
                                               •   FLAMMABILITY  LIMITS:  4-60
                                                   (vol. 2 in air)
•  SOLUBILITY IN WATER (ppm) :  tniscible         •  PERSISTENCE  (0  to  2  rating):  0
                                  HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY CATEGORY:  C
•  NFPA HAZARD RATING:
                               HEALTH:   2      FLAMMABILITY:   4       REACTIVITY:   2
•  DOT HAZARD CLASS:  F.L.
                                            65

-------
                         HAZARDOUS SUBSTANCES DATA SHEET
                                      IDENTIFICATION


•  NAME:  ACETIC ACID                                             e  CAS NO. :  64197

•  SYNONYMS:  Ethanoic acid, glacial acetic acid,  vinegar acid, me thane carboxy lie  acid
   MOLECULAR FORMULA:  C H^O                   •  STRUCTURAL FORMULA:

                                                          0
                                                  CH3  -  C
                                                          OH
                               PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.6            •  VAPOR DENSITY  (air-1): 2.1
•  VISCOSITY (centipoises):  1.3 @ 18°C        •  SURFACE TENSION (dynes/cm):27.8 @
                                                                             20°C


•  MELTING POINT (°C):  16.7                   •  BOILING POINT (°C): 118
•  FLASH POINT (°C):  42.8                     •  IGNITION TEMP.  (°C): 465
•  VAPOR PRESSURE (mm Hg) :  11.4  @  20°C         •  FLAMMABILITY LIMITS: 3-17
                                                  (vol. Z in air)



•  SOLUBILITY IN WATER (ppm): alscible         •  PERSISTENCE (0 to 2 rating): -
                                  HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY CATEGORY:  C


•  NFPA HAZARD RATING:         HEALTH:   2      FLAMMABILITY:   2      REACTIVITY:  1




•  DOT HAZARD CLASS:   Cor.
                                          66

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                        HAZARDOUS SUBSTANCES DATA  SHEET
                       ••            IDENTIFICATION



•  NAME:   ACETIC  ANHYDRIDE


•  SYNONYMS:   Acetic  oxide,  acetyl oxide
                         CAS NO.:  108427
   MOLECULAR FORMULA:    CAHfi°3
   STRUCTURAL FORMULA:

            0
                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY  (water«l):   1.1       •  VAPOR DENSITY  (air-1):   3.5





•  VISCOSITY (centipoises):  0.9 9  18°C    •  SURFACE TENSION  (dynes/cm)::   23.7  @  20°C
•  MELTING POINT ( C):  -73
   BOILING POINT ( C):   140
•  FLASH POINT (°C):  53.9
•  IGNITION TEMP. (°C):  390
•  VAPOR PRESSURE (mm Hg) :  -5.1 @  25°C     •  FLAMMABILITY LIMITS:  2.9 - 10.3

                                              (Vol. I in air)




•  SOLUBILITY IN WATER  (PP=):  120,000     .  PERSISTENCE (0 to 2 rating):
                               a 9<;0r
                                HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY CATEGORY:  C
•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:  2    REACTIVITY:   1
•  DOT HAZARD CLASS:   Cor.
                                          67

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                         HAZAKDOUS SUBSTANCES DATA SHEET
                                    IDENTIFICATION'

•  NAME:  ACETONE CYANOHYDRIN                                    •  CAS NO.:  75865

•  SYNONYMS:   2-methyll*ctonitrile,  alpha-hydroxyisobutyronitrile
•  MOLECULAR FORMULA:  C,H?NO              .  STRUCTURAL FORMULA:
                                                      OH
                                                CH, - C - C*N
                                                  j   i
                                                      CH,
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (v«ter-l):  0.9        •  VAPOR DENSITY (air-1):  2.9



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):  -19                •  BOILING POINT (°C):  95
•  FLASHPOINT (°C):  73.9                 •  IGNITION TEMP. (°C):  687.8
•  VAPOR PRESSURE (mm Hg):                 •  FLAMMABILITY LIMITS:  2.2-12.0
                                              (Vol. Z in *ir)


•  SOLUBILITY IN WATER  (ppm):   100,000     •  PERSISTENCE  (0  to  2  rating):   1



                                HAZARD CLASSIFICATIONS

*  EPA  REPORTABLE QUANTITY CATEGORY:  A



•  NFPA HAZARD SATING:  4     HEALTH:  4    FLAMMABILITY:  1    REACTIVITY:  2



•  DOT HAZARD CLASS:  Pois.  B
                                          68

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                           HAZARDOUS SUBSTANCES  DATA SHEET
                       «            IDENTIFICATION

   NAME:   ACETYL BROMIDE                                         •   CAS  NO.:   506967

   SYNONYMS:
•  MOLECULAR FORMULA:   C-H-BrO            •   STRUCTURAL FORMULA:


                                                CH3 - C - Br
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  1.7        •  VAPOR DENSITY  (air-1):



•  VISCOSITY (ccntipoises):                •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):  -96                •  BOILING POINT  (°C):   76
•  FLASH POINT (°C):  <1                   •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (mm Hg):                 •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY d WATER (.ppnU:  Decomposes  •  PERSISTENCE  (0 to 2 rating):   1



                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY  CATEGORY:  D



•  HFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:



•  DOT HAZARD CLASS:  Cor.
                                          69

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                         HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION  .


•  NAME:  ACETYL CHLORIDE                                        •  CAS NO.:  79367


•  SYNONYMS:
•  MOLECULAR FORMDLA:  C.H-C10             •  STRUCTURAL FORMULA:
                                                      0
                                                      i

                                                CH3 - C - Cl
                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY (water-1):   1.1        •  VAPOR DENSITY (air-1):  2.7




•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):   26.7  @  14.8°C




•  MELTING POINT (°C):  -112               •  BOILING POINT (°C): 51
•  FLASHPOINT (°C): 5                     •  IGNITION TEMP. (°C): 390
•  VAPOR PRESSURE (mm Hg): 2 @ 16°C        •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)
•  SOLUBILITY IN WATER (ppm):   decomposes  •  PERSISTENCE (0 to 2 rating):
                                HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE QUANTITY CATEGORY:   D





•  NFPA HAZARD RATING:        HEALTH: 3     FLAMMABILITY: 3     REACTIVITY: 2





•  DOT HAZARD CLASS:  F.L.
                                         70

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                         HAZARDOUS  SUBSTANCES  DATA SHEET
                                      IDENTIFICATION


•  NAME:  ACROLEIN                                                 •   CAS NO.: 107028

•  SYNONYMS:  2-propenal,  acrylic  aldehyde, acrylaldehyde, acraldehyde
•  MOLECULAR FORMULA:  C.H^O                    •  STRUCTURAL FORMULA:


                                                             0
                                                             ||
                                                  CH2 •  CH - CH
                                PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY  (water*!):  0.84            •  VAPOR DENSITY  (air-1):  1.9




•  VISCOSITY  (centipoises):   -      .           •  SURFACE TENSION  (dynes/on):




.  MELTING POINT  (°C) :   -88                    «  BOILING POINT  (°C): 52.5




•  FLASH POINT  (°C):  -26.1                     •  IGNITION TEMP.  (°C):  235
•  VAPOR PRESSURE  (mm Hg):  288.2  @  25°C        •  FLAMMABILITY  LIMITS:  28-31
                                                  (vol. X in air)



•  SOLUBILITY IN WATER  (ppoO:  400,000          •  PERSISTENCE  (0  to  2  rating): 0
                               @ 25°C
                                  HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE QUANTITY CATEGORY:  X



•  NFPA HAZARD RATING:         HEALTH:   3     FLAMMABILITY:  3        REACTIVITY:




•  DOT HAZARD CLASS:  F.L.
                                        71

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                      HAZARDOUS SUBSTANCES DATA SHEET
                       »            IDEKTIFICATION

•  NAME:  ACRYLONITRILE                                          •  CAS NO.:  107131

•  SYNONYMS: Propeneitrile, vinyl cyanide, cyanoethylene, Fumigrain, Ventox



•  MOLECULAR FORMULA:  C^N               •  STRUCTURAL FORMULA:


                                                CH2 - CH - C » N




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1): 0.8         •  VAPOR DENSITY (air-1): i.s



•  VISCOSITY (ccntipoises):                •  SURFACE TENSION (dynes/cm):



•  MELTING POINT (°C):  -32                •  BOILING POINT (°C):  77.3
•  FLASHPOINT (°C):  0                    •  IGNITION TEMP. (°C):  481.1
•  VAPOR PRESSURE (am Hg) s  113.8 9 25°C   •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER  (ppi):" 70,000     •  PERSISTENCE (0 to 2 rating):   0
                                8 25°C

                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:  B
•  NFPA HAZARD RATING:        HEALTH: 4     FLAMMABILITY:  3    REACTIVITY:  2
•  DOT HAZARD CLASS:  F.L.
                                          72

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                           HAZARDOUS  SUBSTANCES DATA SHEET
                       «            IDENTIFICATION'



•  HAME:  ALLY! ALCOHOC                                          •   CAS  NO.:  107186



•  SYNONYMS:  2-propen-l-ol, l-propenal-3, vinyl carbinol
•  MOLECULAR FORMULA: C,H,0                •  STRUCTURAL FORMULA:
                       3 o



                                                CH2 • CH - CHrOH
                            PHYSICAL/CHEMICAL PROPERTIES



•  SPECIFIC GRAVITY  (water-1):  0.9        •  VAPOR DENSITY  (air-1): 2.0
•  VISCOSITY (eentipoises): 0.3 @ 30°C     •  SURFACE TENSION (dynes/cmj:  25.8 @ 20°C
•  MELTING POINT (°C):  -50                •  BOILING POINT (°C): 96-97
•  FLASHPOINT (°C):  21.1                 •  IGNITION TEMP. (°C):  378.3
•  VAPOR PRESSURE (mm Hg):  25.6 @ 25°C    •  FLAMMABILITY LIMITS:  2.5-18

                                              (Vol. I In air)





•  SOLUBILITY IN WATER (ppm):  miscible    •  PERSISTENCE (0 to 2 rating):   1





                                HAZARD CLASSIFICATIONS



•  EPA REPORTABLE QUANTITY  CATEGORY:   B






•  NFPA HAZARD RATING:        HEALTH:  3     FLAMMABILITY:  3     REACTIVITY:  l







•  DOT HAZARD CLASS:   F.L.
                                         73

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                         HAZARDOUS SUBSTANCES DATA SHEET
                       «           IDENTIFICATION

•  NAME:  ALLYL  CHLORIDE                                         •  CAS  NO.:   107051

•  SYNONYMS:   3-chloropropeae, 3-chloropropylene,  chlorallylene



•  MOLECULAR FORMULA:   ^Hj0-              •  STRUCTURAL FORMULA:


                                                CH2 - CH - CHr-Cl




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  0.9        •  VAPOR DENSITY  (air-1): 2.6
•  VISCOSITY (centipoises):  0.3 8 30°C    •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):  -134.5             •  BOILING POINT (°C):  45
•  FLASHPOINT (°C):  -31.7                •  IGNITION TEMP. (°C):  485
•  VAPOR PRESSURE (mm Hg): 294.3 @ 20°C    •  FLAMMABILITY LIMITS:  2.9-11.1
                                              (Vol. I In air)


•  SOLUBILITY IN WATER  (ppm):  3,000       •  PERSISTENCE (0 to 2 rating):
                               a 25°C


                                HAZARD CLASSIFICATIONS

 • EPA REPORTABLE QUANTITY CATEGORY:   C
•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY: 3     REACTIVITY: 1
•  DOT HAZARD CLASS:  F.L.
                                         74

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                           HAZARDOUS SUBSTANCES  DATA SHEET
                       «            IDENTIFICATION

•  NAME:  AMMONIUM HYDROXIDE                                      •   CAS  NO.:   1336216

•  SYNONYMS:



•  MOLECULAR FORMULA:   H,NO                 •  STRUCTURAL FORMULA:

                                                 NH,  - OH
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  0.9        •  VAPOR DENSITY  (air-1):



•  VISCOSITY (centipoiaes):                •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):  -77                •  BOILING POINT  (°C):  30 (282 solution)
•  FLASHPOINT (°C):                       •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (mm Hg):  11.9 6 20°C    •  FLAMMABILITY LIMITS:   16-25
                                              (Vol. 2 IB air)


•  SOLUBILITY IN WATER  (ppin):  miscible    •  PERSISTENCE (0 to 2 rating):  1


                                HAZARD CLASSIFICATIONS

 •  EPA  REPORTABLE QUANTITY  CATEGORY:   C
•  NTPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS: Cor.
                                        75

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                          HAZARDOUS  SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  NAME:  AMYL ACETATE-                                        '  •  CAS NO.:   628637

•  SYNONYMS:  Anylacetic ester  (iso-CAS No. 123922);  pear oil  (»ec -CAS No. 626380)-
              banana oil (tert-CAS No. 625161)


•  MOLECULAR FORMULA:  C7H14°2             •  STRUCTURAL FORMULA:
                                                    0
                                                    ii
                                              CH, - C
                                                3    \
                                                      °            '^
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (w«ter«l) :  0.9        •  VAPOR DENSITY  (air-1) :  4.5
•  VISCOSITY (centlpoi»«s) :  0.8 @ 45°C    •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):  -78.5              •  BOILING POINT (°C):  150



•  FLASH POINT (°C):  25                   •  IGNITION TEMP. (°C): 360



t  VAPOR PRESSURE (an Eg): 7:4 @ 25°C      •  FLAMMABILITY LIMITS:  1.1 -  7.5
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER Ippm):   2,000       •  PERSISTENCE  (0  to 2 rating):
                               9 20°C

                                HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE  QUANTITY CATEGORY:  C



•  NFPA HAZARD RATING:        HEALTH:  1    FLAMMABILITY:  3      REACTIVITY:  0




•  DOT HAZARD CLASS:  F.L.
                                         76

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                        HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

   KAME:  ANILINE      *                                           •   CAS  NO.:   62533

   SYNONYMS:    Aniline oil,  phenylamlne,  aminobenzene,  aminophen, kyanol
   MOLECULAR FORMULA:    C6H7N             •  STRUCTURAL FORMULA:
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):   1.0        •  VAPOR DENSITY  (air-1):  3.2
•  VISCOSITY (centipoises):   10.2  @  0°C    ,  SURFACE TENSION  (dynes/cm):   42.9  @  20°C
•  MELTING POIBT (°C):   -6.2               .  BOILING POINT  (°C):   184.4



•  FLASHPOINT (°C):     70                 •  IGNITION TEMP.  (°C):   615



•  VAPOR PRESSURE  (mm Hg):  0.67  @  25°C     •  FLAMMABILITY LIMITS:   1.3
                                              (Vol. Z in air)
•  SOLUBILITY IN WATER  (ppm):   36,000      •  PERSISTENCE  (0  to  2  rating):
                                e  is°c


                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:   C
•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:   2    REACTIVITY:   0
•  DOT HAZARD CLASS:  Pois. B
                                           77

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                          HAZARDOUS SUBSTANCES DATA SHEET
                       »            IDENTIFICATION

•  NAME:   ANTIMONY PEHTACHLORIDE                                «  CAS NO.:  7647189

•  SYNONYMS:



•  MOLECULAR FORMULA:   SbCl5              •  STRUCTURAL FORMULA:

                                                 C1x    , C1

                                                 Cl'  |  VC1
                                                     Cl

                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  2.3        •  VAPOR DENSITY (air-1):



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):
   MELTING POINT (°C):    2.8              •  BOILING POINT (°C):  79 
-------
                       HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION


•  HAME:   ARSENIC TRICHLORIDE                                   •  CAS NO.:  7784341


•  SYNONYMS:   Arsenic chloride,  arsenious chloride,  arsenous chloride,  butter of

               arsenic
•  MOLECULAR FORMULA:    AsClj             •  STRUCTURAL FORMULA:
                                                      Cl
                                                      i
                                                      As
                                                   Cl
                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY  (water-1):   2.2       •  VAPOR DENSITY  (air-1):






•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm )j
   MELTING POINT (°C):  -8.5               •  BOILING POINT (°C):  131.2
   FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg) :  M  @  24°C       »  FLAMMABILITY LDCTS:

                                              (Vol. t in air)




•  SOLUBILITY IN WATER  (ppm):  decomposes  •  PERSISTENCE  (0  to  2  rating):





                                HAZARD CLASSIFICATIONS



 •   EPA REPORTABtE QUANTITY  CATEGORY:   D






•  NFPA HAZARD RATING:        HEALTH:  3     FLAMMABILITY:  0    REACTIVITY:  0






•  DOT HAZARD CLASS:   ?°i«- B
                                         79
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                           HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  NAME:    BENZENE    *                                           •   CAS NO.:   71432

•  SYNONYMS:    Cyclohexatriene, benzol



•  MOLECULAR FORMULA:    CgH6              «  STRUCTURAL FORMULA:
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  0.9        •  VAPOR DENSITY  (alr-1):   2.8



•  VISCOSITY (centipoises):  0.65 (§ 20°C   •  SDRFACE TENSION  (dynes/cm):   28.8 @ 20°C



•  MELTING POINT (°C):  5.5                 «  BOILING POINT  (°C):   80.1



•  FLASH POINT (°C):   -11-1               •  IGNITION TEMP. (°C):   560



•  VAPOR PRESSURE (am Hg):   94.9 g 25°C   ,  FLAMMABILITY LIMITS:  1.3 - 7.1
                                              (Vol. 2 in air)


•  SOLUBILITY IN WATER (ppm):   3,000       •  PERSISTENCE  (0 to 2 rating):   1
                               « 25°C


                                HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE QUANTITY  CATEGORY:   C



•  NFPA HAZARD RATING:        HEALTH:   2   7LAMMABILITY:   3   REACTIVITY:   0




•  DOT HAZARD CLASS:    F-L-
                                         80
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                         HAZARDOUS SUBSTANCES  DATA SHEET
                       »            IDENTIFICATION

•  NAME:     BENZONITRILE                                         •  CAS NO.:   100470

•  SYNONYMS:   Phenyl cyanide, cyanobenzene
•  MOLECULAR FORMULA:   C7H-N               •   STRUCTURAL  FORMULA:

                                                          C = N
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water«l):   1.0       •  VAPOR DENSITY  (air-1):
•  VISCOSITY (centipoises):  1.24 @ 25°C   •  SURFACE TENSION  (dynes/cm):   39.1 @ 20°C
•  MELTING POINT (°C):  12-8               •  BOILING POINT  (°C):  191
•  FLASH POINT (°C):  75                   • ' IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (am Hg):  1 @ 24.2°C     •   FLAMMABILITY  LIMITS:
                                               (Vol. Z in air)


•  SOLUBILITY IN WATER  (ppm):   10,000     •  PERSISTENCE  (0 to 2 rating):   1
                                e ioo°c


                                HAZARD CLASSIFICATIONS

 ,  'EPA REPORTABLE QUANTITY CATEGORY:  C



•  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:



•  DOT HAZARD CLASS:
                                         81
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                         HAZARDOUS SUBSTANCES  DATA SHEET
                       «            IDENTIFICATION

•  NAME:        BENZOYL-CHLORIDE                                '   •   CAS NO.:   98884

•  SYNONYMS:     Benzenecarbonyl  chloride
•  MOLECULAR FORMULA:    C H CIO           •  STRUCTURAL FORMULA:
                                                        0
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):   1.2        •  VAPOR DENSITY  (air-1):  4.9



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):
   MELTING POINT (°C):  -0.5               •  BOILING POINT.  (°C):   197
•  FLASHPOINT (°C):   73                  •  IGNITION TEMP. (°C):   585



•  VAPOR PRESSURE (mm Hg):   19 32.1°C    •  FLAMMABILITY LIMITS:
                                              (Vol. ^ in air)


•  SOLUBILITY IN HATER  (ppm):   decomposes  •  PERSISTENCE  (0 to  2 rating):


                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:   C



•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:  2    REACTIVITY:   1



•  DOT HAZARD CLASS:  Cor.-
                                         82
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                         HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  NAME:    BENZYL CHLORIDE                                       ,   CAS NO.:  100447

•  SYNONYMS:



•  MOLECULAR FORMULA:   ^f1             •   STRUCTURAL  FORMULA:


                                                          IH, - Cl
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (vater-1):  1.1        •  VAPOR DENSITY  (air-1):  4.4



•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/cm) :



•  MELTING POINT (°C):  -39                 •  BOILING POINT  (°C):   179



•  FLASH POINT (°C):   67.2                 *  IGNITION TEMP. (°C):   505
•  VAPOR PRESSURE (mm Hg):  1.4  @  25°C      •  FLAMMABILITY LIMITS:  1.1-
                                              (Vol. 2 in air)


•  SOLUBILITY IN WATER (ppm):   33  @ 25°C   •  PERSISTENCE  (0 to 2 rating):
                                HAZARD CLASSIFICATIONS
 •  EPA REPORTABLE QUANTITY CATEGORY:   B
•  NFPA HAZARD RATING:        HEALTH:   2    FLAMMABILITY:   2    REACTIVITY:   1
•  DOT HAZARD CLASS:   Cor.
                                         83
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                           HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  NAME:    BUTYL ACETATE                                      '   *  CAS NO.:  123864
                                                                        iso - 110190
•  SYNONYMS:   Acetic acid butyl ester                                  sec - 105464
                                                                       tert - 540895


•  MOLECULAR FORMULA:    cgHi2°2           *  STRDCTtJRAL FORMULA:
                                                      0
                                                      i
                                                CH3 - C




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):   0.9       •  VAPOR DENSITY  (air-1):   4.0
•  VISCOSITY (centipoises):  0.73 @ 20°C   •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):   -74               •  BOILING POINT  (°C):   126
•  FLASH POINT (°C):   22.2                •  IGNITION TEMP.  (°C):  425
•  VAPOR PRESSURE (ma Hg):   15  9 25°C      •  FLAMMABILITY LIMITS:  1.7 -  7.6
                                              (Vol. Z in air)


•  SOLUBILITY I» WATER  (ppm):   7,000      •  PERSISTENCE  (0 to 2 rating):  2
                                @ 20°C


                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY  CATEGORY:  D
•  NFPA HAZARD RATING:        HEALTH:  1     FLAMMABILITY:  3     REACTIVITY:   0
•  DOT HAZARD CLASS:
                                         84
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                        HAZARDOUS SUBSTANCES DATA SHEET
                                       IDENTIFICATION


 •   NAME:   N-BUTYL PHTHALATE                                       •  CAS NO.:  84-74-2

 •   SYNONYMS:  1,2-Benzenedicarboxylic acid, dibutyl ester, phthalic acid dibutyl ester,
              dibutyl-o-phthalate, DBF
    MOLECULAR FORMULA:  C,,H,-0,                 •   STRUCTURAL  FORMULA:
                        i 6 ^22 H
                                                      o
                                                    I-C-0(CH2)3CH3
                                PHYSICAL/CHEMICAL  PROPERTIES

•  SPECIFIC  GRAVITY  (water-1): d20 1.0465       •   VAPOR  DENSITY  (air-1):  9.6



•  VISCOSITY (centipoises):  16.47 @ ,25°C       •   SURFACE  TENSION (dynes/cm):  33.4
                                                                              @ 20°C


•  MELTING POINT  (°C):   -                      •   BOILING  POINT  (°C):  340



•  FLASH POINT  (°C):  157                       ,   IGNITION TEMP.  (°C) :  402
•  VAPOR PRESSURE  (mm Hg):  -                  •  FLAMMABILITY  LIMITS:  0-5  (lower limit
                                                  (vol. *  in  air)


•  SOLUBILITY IN WATER  (ppm) :  400 @ 25°C      •  PERSISTENCE (0  to  2  rating):  2
                                  HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY  CATEGORY:  B



•  NFPA HAZARD RATING:         HEALTH:   0     FLAMMABILITY:   1       REACTIVITY:  0



•  DOT HAZARD CLASS:  -
                                         85
-------
                            HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION

•  NAME:    BUTYLAMINE-                                          m  CAS NO.:  109379
                                                                        iso  -  78819
•  SYNONYMS:   1-aminobutane                                            sec  -  513495
                                                                        sec  -  13952846
                                                                       tert  -  75649

•  MOLECULAR FORMULA:   CBN             •  STRUCTURAL FORMULA:
                          4B11
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   0.7        •  VAPOR DENSITY  (air-1):   2.5
•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/en) :   19.7 @ 41°C
•  MELTING POINT (°C):    -49               •  BOILING POINT (°C):   78



•  FLASH POINT (°C):  12.2                 .  IGNITION TEMP. (°C):    312.2



•  VAPOR PRESSURE (mm Hg): 72 @ 20°C       •  FLAMMABILITY LIMITS:  1.7 -  9.8
                                              (Vol. I in *ir)


•  SOLUBILITY IN WATER (ppm):   miscible    •  PERSISTENCE  (0 to 2 rating):  1


                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTIT? CATEGORY:  C



•  NFPA HAZARD RATING:        HEALTH: 2     FLAMMABILITY:   3    REACTIVITY:   0



•  DOT HAZARD CLASS:  F.L.
                                        86
-------
                          HAZARDOUS SUBSTANCES DATA SHEET
                       «           IDENTIFICATION'

   NAME:   BtrmUC ACID*

   SYNONYMS:   Butanoic acid,  ethylacetic acid
                                                                  •   CAS  NO.:  107926
•  MOLECULAR FORMULA:     C4H8°2           •  STRUCTURAL FORMULA:
                                                                - C - OH
                                                                  I
                                                                  0
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1) :  1.0        •  VAPOR DENSITY  (air-1) :   3.0



•  VISCOSITY (centipoises) :  1-81 @ 15°C   •  SURFACE TENSION  ( dynes / cm ):   26.8 @ 20°C
•  MELTING POINT (°C) :   -5
                                              BOILING POINT  (°C) :   163.5
   FLASH POINT (°C) :   71.7
                                              IGNITION TEMP.  (°C) :   450
•  VAPOR PRESSURE (nan Eg):   0.43 @'20°C   *   FLAMMABILITY  LIMITS:   2.0-10.0
                                               (Vol. Z in air)


•  SOLUBILITY IN WATER  (ppm):   56,000      •  PERSISTENCE  (0  to  2 rating):   1
                                9 25°C

                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY  CATEGORY:   C
•  NFPA HAZARD RATING:        HEALTH:   2    FLAMMABILITY:   2    REACTIVITY:  0
•  DOT HAZARD CLASS:  c°r.
                                       87
-------
                            HAZARDOUS SUBSTANCES  DATA SHEET
                       »           IDENTIFICATION

•  NAME:    CARBON DISULFIDE                                   '  •  CAS NO.:  75150

•  SYNONYMS:   Carbon bisulfide,  dithiocarbonic anhydride
•  MOLECULAR FORMULA:   CS2                •  STRUCTURAL FORMULA:


                                                S - C • S
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.3         •  VAPOR DENSITY (air-1);  2.6



•  VISCOSITY (centipoises) t  0.36 @  20°C   •  SURFACE TENSION (dynes/cm)t   32.3  @  20°C
•  MELTING POINT (°C):   -111              •  BOILING POINT (°C):   46.5
•  FLASHPOINT (°C):  -30                  •  IGNITION TEMP. (°C):  90
•  VAPOR PRESSURE (mm Hg):  -400 @ 28°C     •  FLAMMABILITY LIMITS:  1.3 - 50.0
                                              (Vol. Z In air)


•  SOLUBILITY IN WATER  (ppm):  2,200       •  PERSISTENCE  (0  to  2 rating):   1
                               t 25°C

                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY  CATEGORY:  D


•  KFPA HAZARD RATING:        HEALTH:   2   FLAMMABILITY:  3    REACTIVITY:  0



•  DOT HAZARD CLASS:   F.L.
                                        88
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                            HAZARDOUS  SUBSTANCES  DATA SHEET
                                       IDENTIFICATION



 •   NAME:   CARBON TETRACHLORIDE


 •   SYNONYMS:  Tetrachloromethane, perchloromethane
                   •  CAS SO.: 56-23-5
 •  MOLECULAR FORMULA:  CC1.
•  STRUCTURAL FORMULA:
                                                          Cl
                                                          I
                                                       C1-C-C1
                                                          I
                                                          Cl
                                PHYSICAL/CHEMICAL  PROPERTIES


•  SPECIFIC  GRAVITY  (water-1) :  1.588           •   VAPOR  DENSITY (air-1):  5.3
•  VISCOSITY  (centipoises):  0.965 @.20°C
   MELTING POINT  (°C):  -23.0
•  FLASH POINT  (  C):  none
•  VAPOR PRESSURE  (mm Hg) :  91.3 (20°C)
•  SOLUBILITY IN WATER  (ppm):  500
•  SURFACE TENSION (dynes/cm): 26.8
                               20°C
•  BOILING POINT (°C):  76.74
•  IGNITION TEMP. (°C) : none
•  FLAMMABILITY LIMITS: Nonflammable

   (vol. Z in air)
•  PERSISTENCE (0 to 2 rating):  2
                                  HAZARD  CLASSIFICATIONS
 •   EPA REPORTABLE  QUANTITY  CATEGORY:  D
•  NFPA HAZARD RATING:         HEALTH:  3      FLAMMABILITY:  0        REACTIVITY:  0
•  DOT HAZARD CLASS:  ORM
                                        89
-------
                             HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  NAME:  CHLORDANE    »                                          •  CAS NO.:   57749

•  SYNONYMS:    Toxichlor,  cblordan




•  MOLECULAR FORMULA:    C,nB,ClB          •  STRUCTURAL FORMULA:         Q
                           10     8                       °    "a      a^     a

                                                      ii c-cu   ~        !' c~
a1-
   a      u          a

   aTnni
                                                                           (3O»
                            fgYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.6        •  VAPOR DENSITY  (air-1):




•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm) :
   MELTING POINT (°C):                     •  BOILING POINT (°C):   175
•  FLASH POINT (°C):                       •  IGNITION TEMP. (°C):




•  VAPOR PRESSURE (mm Hg): IrlO"5 at  25°C  •  FLAMMABILITY LIMITS:
                                              (Vol. 2 in air;



•  SOLUBILITY IN WATER  (ppm):   insoluble  •  PERSISTENCE  (0 to  2 rating):



                                HAZARD CLASSIFICATIONS


 •  EPA  REPORIABLE  QUANTITY CATEGORY:  X




•  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:




•  DOT HAZARD CLASS:   Comb. L.
                                       90
-------
                               HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION


    NAME:    CHLOROBENZENE                                         •  CAS NO.: 108907


    SYNONYMS:    Monochlorobenzen, benzen chloride
   MOLECULAR FORMULA:    C,H.C1             •  STRUCTURAL FORMULA:
                          0 J
                                                         Cl
                             PHYSICAL/CHEMICAL  PROPERTIES


•  SPECIFIC GRAVITY  (water-1):   1.1        •   VAPOR DENSITY (air-1):   3.9
•  VISCOSITY  (centipoises):  0.8 @ 20°C    •  SURFACE TENSION  (dynes/cm):.  33.53 <3 20°C
•  MELTING POINT  (°C):   -45               •  BOILING POINT  (°C):   13-2
•  FLASHPOINT  (°C):    28.9                •  IGNITION TEMP.  (°C):   640
•  VAPOR PRESSURE (am Hg):  12.1  @  25°C     •   FLAMMABILITY LIMITS:   1.3  - 7.1

                                               (Vol. Z in air)




•  SOLUBILITY IN WATER (pptt):   488 
-------
                            HAZARDOUS  SUBSTANCES DATA SHEET
                       «           IDENTIFICATION  -

•  SAME:    CHLOROFORM"                                          •  CAS NO.:  67663

•  SYNONYMS:  Trichloromethane
•  MOLECULAR FORMULA:     CHC1,             •  STRUCTURAL FORMULA:
                                                     Cl
                                                      I
                                                Cl - CH
                                                      I
                                                     Cl


                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.5        •  VAPOR DENSITY (air-1):
•  VISCOSITY (centipoi»es):   0.6  @  20  C    •  SURFACE TENSION (dynes/cm):   27.1 @ 20°C
•  MELTING POINT (°C):   -63                •  BOILING POINT (°C):  62
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg):  -200  9  25°C     •  FLAMMABILITY LIMITS:
                                              (Vol. 2 in air)


•  SOLUBILITY IN WATER  (ppm):   2,000      •  PERSISTENCE  (0 to 2 rating):   1
                                
-------
                             HAZABDOUS SUBSTANCES DATA SHEET
                                    IDENTIFICATION

   NAME:    CHLOROSULFONIC ACID                                   •  CAS NO.:   7790945

   SYNONYMS:   Sulfuric chlorohydrin
•  MOLECULAR FORMULA:    ClHOjS            •   STRUCTURAL  FORMULA:

                                                   0       OH
                                                     * S '
                                                   o *   x ci
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water«l):   1.8       •  VAPOR DENSITY  (air-1):



•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/on):
•  MELTING POINT (°C):  -80                •  BOILING POINT  (°C):   151.5
•  FLASH POINT (°C):                       •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (mm Eg) :    1  
-------
                             HAZARDOUS SUBSTANCES  DATA SHEET
                       •            IDENTIFICATION

•  NAME:    CRESOL    *                                           •   CAS NO.:   1319773

•  SYNONYMS:   Cresylic acid (a- CAS  No.  108394); hydroxytoluene (o- CAS No. 95487)
               p- CAS No.  106445


•  MOLECULAR FORMULA:   CjHgO             •  STRUCTURAL FORMULA:

                                                        ,OH


                                                   \  )
                                                        ;CH3      (m-Cresol)
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.1 (o-)    •  VAPOR DENSITY  (air-1):  3.7 (o-)
                                1.0 (m- or p-)


•  VISCOSITY (centipoises):   20.8 @ 20°C  •  SURFACE TENSION  (dynes/cm):
                          31 (o-)                                    191 (o-)
                          11 (a-)
                          35 (p-)
•  MELTING POINT (°C):    11 (a-)           •  BOILING POINT  (°C):   202 (a- and p-)
                       81.1 (o-)                                      598.9 (o-)
•  FLASH POINT (°C):   94.4 (a- and p-)   .  •. IGNITION TEMP.  (°C):   558.9 (m- and p-)


                                                                     1.4 @ 148.9 (o-)
•  VAPOR PRESSURE (IBB Hg):                 •  FLAMMABILITT  LIMITS:   1.1 8 150 (a- and p-
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER  (ppm):   20,000     •  PERSISTENCE40 to 2 rating):
                                HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY CATEGORY:   C
•  HFPA HAZARD RATING:        HEALTH:   3   FLAMMABILITY:   2    REACTIVITY:  0 (o-)
                                        3                   1                 0 (m- and
                                                                                 P-)

•  DOT HAZARD CLASS:    Pois.  B
                                          94
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                           HAZARDOUS SUBSTANCES DATA SHEET
                                       IDENTIFICATION


 •   NAME:  CROTONALDEHYDE                                           •  CAS SO.:  4170-30-3


 •   SYNONYMS: trans-2-butenal, crotonic aldehyde,  S-oethylacrolein,  propylene  aldehyde
   MOLECULAR FORMULA:   C^HgO                   •  STRUCTURAL  FORMULA:

                                                            0
                                                             II
                                                   CH=CH " CHCH
                                PHYSICAL/CHEMICAL  PROPERTIES


 •  SPECIFIC  GRAVITY  (water-1):  0.8531           •   VAPOR  DENSITY  (air-1): 2.41
   VISCOSITY  (centipoises):  -       .           •   SURFACE  TENSION (dynes/cm):
•  MELTING POINT  (°C):   -76.5                  .  BOILING  POINT (°C):  104
•  FLASH POINT  (°C):  13  (open  cup)             •   IGNITION TEMP.  (°C):  232
•  VAPOR PRESSURE  (mm Hg):   30  @ 20°C          •  FLAMMABILITY  LIMITS:  2.95-15.5
                                                  (vol.  Z in  air)



•  SOLUBILITY IN WATER  (ppm): 181,000          •  PERSISTENCE (0  to  2  rating):  0
                              @ 20°C
                                  HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY CATEGORY:  B
•  NFPA HAZARD RATING:         HEALTH:  3      FLAMMABILITY:  3        REACTIVITY:  2
•  DOT HAZARD CLASS:  F.L.
                                         95
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                               HAZARDOUS SUBSTANCES  DATA SHEET
                       •            IDENTIFICATION

•  NAME:    CYANOGEN  CHLORIDE                                  '   •  CAS NO.:  506774

•  SYNONYMS:



•  MOLECULAR FORMULA:    CC1N              •  STRUCTURAL FORMULA:



                                                     Cl - C « N



                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  1.2        •  VAPOR DENSITY (air-1):   2.1



•  VISCOSITY (centipolses):                •  SURFACE TENSION (dynes/cm) :



•  MELTING POINT (°C):  -6                 •  BOILING POINT (°C):  13.8
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (am Hg):  40 9 -37.5°C   •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)
•  SOLUBILITY IN WATER  (ppm):   2,500      •  PERSISTENCE  (0  to  2  rating):
                                9 25°C


                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY CATEGORY:  A
•  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:    p°is. A
                                         96
-------
                              HAZARDOUS  SUBSTANCES DATA SHEET
                       *            IDENTIFICATION




•  NAME:    CYCLOHEXANE-                                           •  CAS NO.:   110827




•  SYNONYMS:   Hexahydrobenzene,  hexamethylene,  hexaaaphthene
•  MOLECULAR FORMULA:     C£H,,            •   STRUCTURAL FORMULA:
                           o L±
                            PHYSICAL/CHEMICAL  PROPERTIES




   SPECIFIC GRAVITY  (water*!):   0.8       •   VAPOR DENSITY  (air-1):   2.9
   VISCOSITY (centipoises):  0.7 @ 20°C    •  SURFACE TENSION  (dynes/cm):   25.5 @ 20°C
•  HELTING POIHT (°C):   6.1               •  BOILING POINT  (°C):  81








•  FLASH POINT (°C):    -20                •  IGNITION TEMP.  (°C):   245








•  VAPOR PRESSURE (mm Hg):  98.1 (? 25°C    ,  FLAMKABILITY LIMITS:   1.3 -  R.n

                                              (Vol. Z in air)






•  SOLUBILITY IN WATER  (ppm):   45 9 25°C  •  PERSISTENCE  (0 to 2 rating):  1







                                HAZARD CLASSIFICATIONS




•  EPA REPORTABLE QUANTITY CATEGORY:  C









•  NFPA HAZARD RATING:        HEALTH:   1   FLAMMABILITY:  3   REACTIVITY:  0









•  DOT HAZARD CLASS:  F.L.
                                        97
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                         HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION


•  SAME:    DIAZINON   *                                           •   CAS NO.:   333415

•  SYNONYMS:   Dipofene,  diazitol,  Basudin,  Spectracide

                                                                     CH3


•  MOLECULAR FORMULA:  C12H21N203PS        •  STRUCTURAL FORMULA:  //C N
                                                         CH3      N     CH       OC2H5
                                                            \     I     H       /
                                                              CH-C     C-O-P
                                                            /      •*  /•       a N
                                                         CH3         N         S OC2H5



                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.1        •  VAPOR DENSITY (air-1):
•  VISCOSITY (eeatipoises):                •  SURFACE TENSION  (dynes/cm):




•  MELTING POINT (°C):                     •  BOILING POINT  (°C):  83  @ 0-002 mm Hg
   FLASH POINT (°C):                       •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (am Hg):  1*10~  9  20°C   ,   FLAMMABILITY LIMITS:
                                               (Vol. I in air)


•  SOLUBILITY IN WATER  (ppm):   40 I?  25°C   •   PERSISTENCE (0 to 2 rating):



                                HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE QUANTITY CATEGORY:  X



•  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:        REACTIVITY:




•  DOT HAZARD CLASS:  ORM
                                         98
-------
                          HAZARDOUS SUBSTANCES  DATA  SHEET
                                       IDENTIFICATION





•  NAME:  0-DICHLOROBENZENE                                        .   CAS  NO. :  95-50-1




•  SYNONYMS:  o-dichlorobenzol
   MOLECULAR FORMULA:  CgH^a^                 •  STRUCTURAL FORMULA:
                               PHYSICAL/CHEMICAL PROPERTIES
  •                                  - — -       ._


                                      7fl

•  SPECIFIC GRAVITY  (wacer-1):  1.309 -=7- °C    •  VAPOR DENSITY  (air-1):   5.07

                                       4
•  VISCOSITY (centipoises):  1.324 9 25°C      •  SURFACE TENSION  (dynes/cm):   26.84

                                                                                20°C






•  MELTING POINT (°C):  -17.03                 •  BOILING POINT  (°C):   180.5
•  FLASH POINT (°C):   66 (closed cup)          •  IGNITION TEMP.  (°C):   648









•  VAPOR PRESSURE (mm Hg) :  -                  •  FLAMMABILITY  LIMITS:  2.2-9.2

                                                  (vol. Z in air)






•  SOLUBILITY IN WATER  (ppm):  insoluble       •  PERSISTENCE  (0  to  2  rating):  2







                                  HAZARD CLASSIFICATIONS





 •   EPA REPORTABLE QUANTITY  CATEGORY:   B








•  NFPA HAZARD RATING:         HEALTH:  2       FLAMMABILITY: 2         REACTIVITY: 0








•  DOT HAZARD CLASS:    ORM
                                        99
-------
                           HAZARDOUS SUBSTANCES DATA SHEET
                                       ID ENTITI CATION'
 •  NAME:  DICHLOROPROPENE-DICHLOROPROPANE MIXTURE
                                    •   CAS  SO.:  8003-19-8
 •  SYNONYMS:  D-D mixture, Vidden D, Ent 8,420 (*l,3-Dichloro-l-propene + 1,2-
              Dichloropropane mixture).
 •  MOLECULAR  FORMULA:
     C3HifCl2
                                                •  STRUCTURAL FORMULA:
                   C1CH2-CH  •  CHC1   (1)
                                                  CH3-CHC1-CH2C1   (2)
                                PHYSICAL/CHEMICAL PROPERTIES
   SPECIFIC GRAVITY  (water-1):
         1.233 (1)
         1.158 (2)

   VISCOSITY  (centipoisas):   -
   MELTING POINT  (°C) :    -70°C (1)
                          -80°C (2)
•  FLASH POINT  (°C):  35 (1) (open cup)
                    16.1 (2) (open cup)
                •  VAPOR DENSITY  (air-1) :

                        3.83  (1)
                        3.90  (2)

                •  SURFACE TENSION  (dynes /cai):
                                                                     28.9 @ 20C  (2)
                •  BOILING POINT  (°C):   108°  (1)
                                         96.4°  (2)
                •  IGNITION TEMP.  (°C) :  557  (2)
•  VAPOR PRESSURE  (mn Eg):  40 @ 19.4°C (2)      •  FLAMMABILITY LIMITS:  5.3-14.5  (1)
                                                   (vol.  I in air)       3.4-14.5Z (2)


•  SOLUBILITY IN WATER  (ppm):   si.  s.  (1)      •  PERSISTENCE (0 eo 2 rating): -
                                2.700 9 20°C (2)
                                   HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:   D
•  S7PA HAZARD RATING:
•  DOT HAZARD  CLASS:  Cor.
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY:  0
*Sote:  According to Chen Abstracts, "DD" is the mixture of these two isomers.  According
        to the Merck Index (9th Ed.), "DD" is the mixture of two dichloropropene isomers.
        According to the Condensed Chemical Dictionary (8th Ed.), "DD" is the mixture of
        three dichloropropene isomers and related Cj chlorinated compounds.
                                         100
-------
                            HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION

•  NAME:    2,2-DICHLOKDPROPIONIC ACID                           •  CAS NO.:   75990

•  SYNONYMS:   Dalapon
   MOLECULAR FORMULA:   C-H^Cl-O,           •  STRUCTURAL FORMULA:


                                                CH, - C - C*
                                                  3   i     ^nn
                                                      Cl    OH
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.4        •  VAPOR DENSITY  (air-1):



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):
   MELTING POINT (°C):                     •  BOILING POINT (°C):  185 -  190
   FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (am Hg):  •               •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)
•  SOLUBILITY DJ WATER  (ppm):   450,000    •  PERSISTENCE (0 to 2 rating):
                                9 25°C


                                HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE QUANTITY CATEGORY:  D
•  NJTA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:
                                        101
-------
                           HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION

•  NAME:   DICHLORVOS  *                                          •  CAS NO.:  62737

•  SYNONYMS:  2,2-Dichlorovinyl dimethyl phosphate, Vapona



•  MOLECULAR FORMULA:  C^CljO^P          •  STRUCTURAL FORMULA:

                                                CH5Ox?
                                                    ,t - 0 - CH - CC1,
                                                CH^O                   •



                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.4        •  VAPOR DENSITY (air-1):



«  VISCOSITY (ceatipoises):                •  SURFACE TENSION (dynes/cm):



•  MELTING POINT (°C):                     •  BOILING POINT (°C): 140  @ 200 mm Eg



•  FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg): 3-2 * 10        •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)
   SOLUBILITY IN WATER (ppm):   10,000 @    •  PERSISTENCE  (0 to 2 rating):
                               20°C


                                HAZARD CLASSIFICATIONS

   EPA REPORTABLE QUANTITY  CATEGORY:   A
•  HFPA HAZARD RATING:        HEALTH:       PLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:
                                       102
-------
                          HAZARDOUS SUBSTANCES DATA SHEET
                       »           IDENTIFICATION

   NAME:    DIETHYLAMINE                                         •  CAS NO.:  109897

   SYNONYMS:
   MOLECULAR FORMULA:     C4HnN           •  STRUCTURAL FORMULA:

                                                       NH
                            PHYSICAL/CHEMICAL PROPERTIES

   SPECIFIC GRAVITY (water-1):   0.7        •  VAPOR DENSITY  (air-I):   2.5
   VISCOSITY (centipoises):  0.35  9  25°C    •  SURFACE TENSION (dynes/cm):   16.4  Q  56°C
   MELTING POINT (°C):   -50                •  BOILING POINT (°C):  55
•  FLASH POINT (°C):   -26                  ,  IGNITION TEMP. (°C):   312.2



•  VAPOR PRESSURE (nn Hg):  247.1 9  25°C    •  FLAMMABILITY LIMITS:   1.8 -
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER  (ppm):" miscible   •  PERSISTENCE (0 to 2 rating):   0


                                HAZARD CLASSIFICATIONS
 •  T£PA REPORIABLE QUANTITY  CATEGORY:   C



•  NFPA HAZARD RATING:        HEALTH:   2    FLAMMABILITY:  3    REACTIVITY:  0



•  DOT HAZARD CLASS:  F.L.
                                        103
-------
                           HAZARDOUS  SUBSTANCES DATA SHEET
                       •            IDENTIFICATION

•  NAME:      DIMETHYLAMINE                                      •  CAS NO.:   124403

•  SYNONYMS:



•  MOLECULAR FORMULA:    C^N              •  STRUCTURAL FORMULA:


                                                    NH

                                                         3


                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  0.7         •  VAPOR DENSITY (air-1):   1.6



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/on):
•  MELTING POINT (°C):   -96                •  BOILING POINT (°C):   7.4
•  FLASHPOINT (°C):   -7                   •  IGNITION TEMP. (°C):  400



•  VAPOR PRESSURE (am Hg):  1277 @ 20°C    •  FLAMMABILITY LIMITS:  2.8 -  14.4
                                              (Vol. % in air)


•  SOLUBILITY IN WATER (ppm):  "237,000     •  PERSISTENCE  (o to 2 rating):  1



                                HAZARD CLASSIFICATIOSS

 •  EPA REPORTABLE QUANTITY CATEGORY:   C



•  NFPA HAZARD RATING:        HEALTH:  3     FLAMMABILITY:  4    REACTIVITY:  0



•  DOT HAZARD CLASS:   F.L.
                                        104
-------
                           HAZARDOUS  SUBSTANCES  DATA SHEET
                                       IDENTIFICATION
•  NAME:  DINITROTOLUENE

•  SYNONYMS:  OUT
                                                                   .  CAS NO.:  25321-14-6
•  MOLECULAR FORMULA:   C7H6N20,t        N02     •   STRUCTURAL  FORMULA:
                                                                NO,
                                             (2,4-DNT)
                    (Commercial DNT is a 80/20 mixture of 2,4- and 2,6-DNT)
                               PHYSICAL/CHEMICAL  PROPERTIES   (2)

•  SPECIFIC GRAVITY  (water-1):  1.28(1)         •   VAPOR DENSITY  (air=l):  6.27
•  VISCOSITY  (cencipoises):  -
•  MELTING POINT (°C): 66(1)
•  FLASH POINT ( C):  207
•  VAPOR PRESSURE (mm Eg):  -
•  SURFACE TENSION (dynes/cm): -
•  BOILING POINT (°C): 300
•  IGNITION TEMP. (°C) :  -
•  FLAMMABILITY LIMITS:
   (vol. Z in air)
•  SOLUBILITY IN WATER  (ppm):  220 @ 22°C       •   PERSISTENCE  (0  Co  2  rating):  -
                                  HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY  CATEGORY:  C
•  NFPA HAZARD RATING:         HEALTH:   2      FLAMMABILITY:   1       REACTIVITY: 3
•  DOT HAZARD CLASS: -
                                       105
-------
                        HAZARDOUS  SUBSTANCES DATA SHEET
                       »           IDENTIFICATION


•  NAME:  DISULFOTON   -                                          •  CAS  NO.;  298044

•  SYNONYMS:    Di-syston




•  MOLECULAR FORMULA:   CgH^O^Sj         •  STRUCTURAL FORMULA:

                                                CH3 - CH2 - O  S
                                                             \ II
                                                              T - S - CH2CH2 - S
                                                             x
                                                CH3 - CH2 - O


                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY (water-1):  1.1         •  VAPOR DENSITY  (air-1):




•  VISCOSITY (centipolsea):                •  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):                     •  BOILING POINT (°C):   62  @  0.01 mm Hg
•  FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg): 1.8 x 10~4      •  FLAMMABILITY LIMITS:
                           @ 20°C             (Vol. t in air)



•  SOLUBILITY IN WATER (ppm):   25          •  PERSISTENCE (0 to 2 rating):



                                HAZARD CLASSIFICATIONS


 •   EPA  REPORTABLE QUANTITY  CATEGORY:   A




•  NFPA HAZARD RATING:        HEALTH:    -   FLAMMABILITY:       REACTIVITY:




•  DOT HAZARD CLASS:
                                         106
-------
                          HAZARDOUS SUBSTANCES DATA SHEET
                                    IDENTIFICATION


•  NAME:    ETHION     *                                          •   CAS  NO.:   563122

•  SYNONYMS:    Nialate,  ethyl methylene phosphorodithioate
•  MOLECULAR FORMULA:    CgH^O^S^        •  STRUCTURAL FORMULA:
                                                      s
                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY  (water-1):  1.2         •  VAPOR DENSITY  (air-1):




•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):   -13                •  BOILING POINT  (°C):
•  FLASH POINT (°C):                       •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (ma Hg):1.5 x  10"6 9  25°C»  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)



•  SOLUBILITY IN WATER  (ppm):  2 @ 20°C   •  PERSISTENCE  (0 to 2 rating):  1
                                HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY  CATEGORY:  A
•  SFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:
                                       107
-------
                               HAZARDOUS SUBSTANCES DATA SHEET
                       •           IDENTIFICATION



•  SAME:  ETHYLBENZENE *                                          c  CAS HO.:  100414


•  SYNONYMS:   Phenylethaae
•  MOLECULAR FORMULA:   C0H...               •  STRUCTURAL FORMULA:
                         o  lU
                            PHYSICAL/CHEMICAL PROPERTIES



•  SPECIFIC GRAVITY (water-1):  0.9         •  VAPOR DENSITY  (air-1):  3.7






•  VISCOSITY (centipoises):  0.7 @ 17°C     •  SURFACE TENSION (dynes/cm)^  29.2  9  20°C
•  MELTING POINT (°C):   -95                •  BOILING POINT (°C):  136
•  FLASHPOINT (°C):  15                    •  IGNITION TEMP. (°C>: 432.2
•  VAPOR PRESSURE (am Hg): 9.6 8  25 C      •  FLAMMABILITY LIMITS:  1.0 - 6.7

                                              (Vol. t in «ir)




•  SOLUBILITY IN WATER  (ppm): ~  14 @  25°C  •  PERSISTENCE  (0 to 2 rating) :





                                HAZARD CLASSIFICATIONS



•  EPA REPORTABLE QUANTITY CATEGORY:  C






•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:  3    REACTIVITY:  0






•  DOT HAZARD CLASS: F.L.
                                         108
-------
                            HAZARDOUS SUBSTANCES DATA SHEET
                       -            IDENTIFICATION  .

•  SAME:   ETHYLENEDIAMINE                                       •  CAS NO.:   107153

•  SYNONYMS:   1,2-diaminoethane



•  MOLECULAR FORMULA:     C2H8N2           *  STRUCTURAL FORMULA:

                                                H2N - CH2 - CH2 - NH2




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  0.9         •  VAPOR DENSITY (air-1):   2.1



•  VISCOSITY (centipoiaes):                •  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):   8.5                •  BOILING POINT (°C):   116.5
•  FLASH POINT (°C):   65.6                 •  IGNITION TEMP. (°C): 385
•  VAPOR PRESSURE (mm Hg): 13.04 9  25°C     •  FLAMMABILITY LIMITS:
                                              (Vol. I in air)


•  SOLUBILITY IN WATER (ppm):  miscible    •  PERSISTENCE (0 Co 2 rating):


                                HAZARD CLASSIFICATIONS

•  EPA  REPORTABLE QUANTITY CATEGORY:  C



•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:  2    REACTIVITY:  0



•  DOT HAZARD CLASS:
                                       109
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                               HAZARDOUS SUBSTANCES DATA SHEET
                                   IDENTIFICATION

•  NAME:   FORMALDEHYDE                                          •   CAS  NO.:   50000

•  SYNONYMS:    Formic  aldehyde,  methanal,  formalin
•  MOLECULAR FORMULA:     CHjO             •  STRUCTURAL FORMULA:
                                                    0
                                                    i
                                                H - C - H
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.0        •  VAPOR DENSITY  (air-1):   1.1



•  VISCOSITY (cencipoises):                •  SURFACE TENSION  (dynes/cm):  58.2 @ 20°C



•  MELTING POINT (°C):   -92                •  BOILING POINT  (°C):   19.5



•  FLASH POINT (°C):  85  (37Z solution with •  IGNITION TEMP. (°C):
                      0.5 methyl  alcohol)


•  VAPOR PRESSURE (am Hg): 1946.7 9 25°C   •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER (ppm):   550,000     •  PERSISTENCE (0 to 2 rating):
                                HAZARD CLASSIFICATIONS
 •  EPA REPORTABLE QUANTITY CATEGORY:   C
•  NFPA HAZARD RATING:        HEALTH:   2    FLAMMABILITY:   2    REACTIVITY:  0 (solution)
                                        2                    40 (gas)


•  DOT HAZARD CLASS:    0*"
                                       110
-------
                            HAZARDOUS SUBSTANCES DATA SHEET
                                       IDENTIFICATION


•  SAME:  FORMIC ACID                                              •  CAS NO.:   64186

•  SYNONYMS:  Methanoic acid




•  MOLECULAR  FORMULA:  CH202                    •   STRUCTURAL  FORMULA:


                                                      0 - CH - OH
                               PHYSICAL/CHEMICAL  PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  1.2             •   VAPOR  DENSITY  (air-1):   1.6
•  VISCOSITY  (cencipoises):  18 @ 20°C          •   SURFACE  TENSION  (dynes/cm):  37.6  @
                                                                               20°C


•  MELTING POINT  (°C):  8.4                     ,   BOILING  POINT  (°C) :  101
•  FLASH POINT (°C):  68.9                      •   IGNITION TEMP.  (°C):   601.1



•  VAPOR PRESSURE (mm Hg) :  42.4  @ 25°C         •   FLAMMABILITY LIMITS:    18-57
                                                   (vol.  Z in air)


•  SOLUBILITY IN WATER  (ppm):  niscible         •   PERSISTENCE  (0  Co  2  rating):  0
                                  HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:   D



•  NFPA HAZARD RATING:         HEALTH:  3        FLAMMABILITY:   2        REACTIVITY:  0



•  DOT HAZARD CLASS:  Cor.
                                       Ill
-------
                        HAZARDOUS SUBSTANCES  DATA SHEET
                       «           IDENTIFICATION

•  NAME:   FURFURAL    «                                           «   CAS  NO.:   98011

•  SYNONYMS:    2-furaldehyde,  pyromucic aldehyde
•  MOLECULAR FORMULA:     C5H4°2           *  STRUCTURAL FORMULA:
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.2        •  VAPOR DENSITY  (air«l):   3.3
•  VISCOSITY (centipoises):  1.5  8  25°C     •  SURFACE TENSION ( dynes / cnj) :  43.5  I? 20°C
•  MELTING POINT (°C):    -36               •  BOILING POINT (°C):   162
•  FLASHPOINT (°C):   60                   •  IGNITION TEMP. (°C):   315.6
•  VAPOR PRESSURE (am Eg):  2.1  fl  25°C      •  ^LAMMABILITY LIMITS:  2.1-19.3
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER  (ppm):   83,000     •  PERSISTENCE  (0 to 2 rating) :0
                                9 20SC

                                HAZARD CLASSIFICATIONS
 •  EPA REPORTABLE QUANTITY CATEGORY:   C



•  NFPA HAZARD RATING:        HEALTH:   1    FLAMMABILITY:   2    REACTIVITY:    1



•  DOT HAZARD CLASS:    Comb. L.
                                        112
-------
                          HAZARDOUS SUBSTANCES DATA SHEET
                                       IDENTIFICATION'

•   NAME:  HEXACHLOROCYCLOPENTADIENE                                •  CAS N0.= 77-47-4

•   SYNONYMS: Perchlorocycylopentadiene, C-56, 1,3-cyclopentadiene,  1,2,3,4,5,5-hexa-
             chloro-
•  MOLECULAR FORMULA:   CsClg                    •   STRUCTURAL  FORMULA:
                                                           Cl
                                                               ,C1
                                                               Cl
                               PHYSICAL/CHEMICAL  PROPERTIES

•  SPECIFIC GRAVITY  (water-1): 1.717            •   VAPOR DENSITY  (air-1):  9.42



•  VISCOSITY  (centipoises): -       .           •   SURFACE  TENSION  (dynes/cm): -



•  MELTING POINT (°C):  9.6                      •   BOILING  POINT  (°C):  239



•  FLASH POINT (°C):  none                       •   IGNITION TEMP.  (°C): none
•  VAPOR PRESSURE (mm Hg): -                   •   FLAMMABILITY LIMITS:  Nonflanmable
                                                   (vol.  Z  in air)


•  SOLUBILITY IN WATER (ppm): -                •   PERSISTENCE (0  to  2 racing):  2
                                  HAZARD CLASSIFICATIONS


•  EPA REPORTABLE QUANTITY CATEGORY:  X


•  NFPA HAZARD RATING:         HEALTH:  -      FLAMMABILITY:   -      REACTIVITY:  _



•  DOT HAZARD CLASS: -
                                       113
-------
                               HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  NAME:   HYDROCHLORIC ACID                                     •  CAS NO.:  7647010

•  SYNONYMS:   Hydrogen chloride, muriatic acid



•  MOLECULAR FORMULA:    HC1               •  STRUCTURAL FORMULA:


                                                 H+  Cl~




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1): 1.1  (202    •  VAPOR DENSITY  (air-1):
                               solution)


•  VISCOSITY (eentipoises): 25.4 (3 20°C    •  SURFACE TENSION (dynes/cm   : 70 0 20°C
•  MELTING POINT (°C):  -115  (202          •  BOILING POINT (°C):  -35  (202  solution,
                        solution, -62)                                  108.6)


•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (am Hg):  1 @ 145.8      •  FLAMMABILITY LIMITS:
                                              (Vol. 2 in air)


•  SOLUBILITY IN WATER (ppm):   832,000     ,  PERSISTENCE (0 to 2 rating):  2
                               
-------
                                 HAZARDOUS SUBSTANCES DATA SHEET
                       »            IDENTIFICATION

•  NAME:   HYDROFLUORIC*ACID                                      •  CAS NO.:   764393

•  SYNONYMS:     Fluohydric acid



•  MOLECULAR FORMULA:       HF             •  STRUCTURAL FORMULA:

                                                  +
                                                H   F




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  0.96 (702  •  VAPOR DENSITY  (air-1):
                                solution,
                                1.2)

•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm) :>
   MELTING POINT (°C):  -83.6 (70Z         •  BOILING POINT  (°C):   19.5 (70% solution,
                        solution,  -75)                                    65)


   FLASH POINT (°C):                       •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (mm Hg): 400 @ 2.5°C     •  FLAMMABILITY  LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IH WATER (ppa):  miscible    •  PERSISTENCE (0 to 2 rating):



                                HAZARD CLASSIFICATIONS

•   EPA  REPORTABLE QUANTITY CATEGORY:   D



•  NFPA HAZARD BATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:



•  DOT HAZARD CLASS:  Cor.
                                        115
-------
                            HAZARDOUS SUBSTANCES  DATA SHEET
                       «            IDENTIFICATION

•  KAME:   HYDROGEN  CYAHIDE                                    '   e  CAS NO.:   74908

«  SYNONYMS:   Hydrocyanic acid



•  MOLECULAR FORMULA:    HCN               •  STRUCTURAL FORMULA:


                                                HC s N




                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1): 0.7 as      •  VAPOR DENSITY (air-1):   0.9
                               liquid


e  VISCOSITY (c«ntipoia«a):                •  SURFACE TENSION (dynes/on):
•  MELTING POINT (°C):  -14                •  BOILING POINT (°C):  25.6
•  FLASH POIHT (°C):   -18                 •  IGNITION TEMP. (°C):  537.8
,  VAPOR PRESSURE (an Hg): 264.4 3 0°C     •  *"»»M"W LIMITS:  5.6 - 40.0
                                              (Vol. X in air)


•  SOLUBILITY IN WATER (ppn):  "miscible    •  PERSISTENCE  (0 to 2 racing):



                                HAZARD CLASSIFICATIONS


•  EPA REPORTABLE QUANTITY CATEGORY:  A


•  NFPA HAZARD RATING:        HEALTH:   4   FUMMABILITY:  4   * REACTIVITY:   2


                     Pols. A  (5Z or more hydrocyanic acid)
•  DOT HAZARD CLASS: Pols. B  (less than 51 hydrocyanic acid)
                                        116
-------
                          HAZARDOUS SUBSTANCES DATA  SHEET
                                    IDENTIFICATION
 •  NAME:   ISOPRENE

 •  SYNONYMS:    2-methyl-l,3-butadlene
                                       CAS NO.:  78795
•  MOLECULAR FORMULA:
                            C5H8
             •   STRUCTURAL  FORMULA:
                        CH,
                                                CH, » C - CH- CH,
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  0.7        •  VAPOR DENSITY  (air-1): 2.35
•  VISCOSITY (centipoises):
             •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):   -146
             •  BOILING POINT ( C):  34
•  FLASH POINT (°C):   -65
             •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (mm Hg): 493 @ 20°C
                FLAMMABILITY LIMITS:  2.9
                (Vol. Z in air)
•  SOLUBILITY IN WATER (ppm):   100         •  PERSISTENCE (0 to 2 rating):   0


                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY  CATEGORY:  C
•  NFFA HAZARD RATING:
HEALTH:   2   FLAMMABILltY:   4   REACTIVITY:   1
•  DOT HAZARD CLASS:  F-L-
                                       117
-------
                          HAZARDOUS  SUBSTANCES DATA SHEET
                                    IDENTIFICATION
•  NAME:    MALATHION -

e  SYNONYMS:     Phosphothion
                                   •  CAS NO.:   121755
•  MOLECULAR FORMULA:   CinH.aO,PS,
                         L\J i.y o  Z
                STRUCTURAL FORMULA:
                                  s
                                  II
                                                                P-S-CH-C- OCH2CHj

                                                                       CH, - C - OCH2CH3
                                                                            II
                                                                            O
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (wacer-1):   1.2       •  VAPOR DENSITY  (air-1):   2.3
•  VISCOSITY (centipoises):
             •  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):   2.9
             •  BOILING POINT ( C): 156
•  FLASH POINT (°C):    -53.9
             •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (am Hg):  4 x 10~5 ?  30°C •  FLAMMABILITY LIMITS:
                                              (Vol. I in air)


•  SOLUBILITY IK WATER (PP»): "145 8 25°C  •  PERSISTENCE  (0 to 2 rating):  0
                                HAZARD CLASSIFICATIONS
 •  EPA REPORTABLE QUANTITY CATEGORY:   A
•  KFPA HAZARD RATING:
HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:    ORM
                                          118
-------
                           HAZARDOUS SUBSTANCES DATA SHEET
                       »           IDENTIFICATION

•  NAME:   METHYL MERCATTAN                                      •   CAS  NO.:   74931

•  SYNONYMS:     Methanethiol,  mercaptomethane,  methyl sulfhydrate,  thiomethyl  alcohol
•  MOLECULAR FORMCLA:    CH4S               •  STRUCTURAL FORMULA:


                                                  CH3 - S - H
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):   0.9        •  VAPOR DENSITY  (air-1):   1.7



•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT (°C):   -123               •  BOILING POINT (°C):  6.8
•  FLASH POINT (°C):   <0                   •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (aa Hg) :  760  <§  6.8°C     •  FLAMMABILITY LIMITS:  3.9 - 21.8
                                              (Vol. I in air)


•  SOLUBILITY IN WATER (ppm) :  24,000      •  PERSISTENCE (0 to 2 rating):
                               9. 15°C


                                HAZARD CLASSIFICATIONS

»  EPA  REPORTABLE QUANTITY  CATEGORY:  B



•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:  4    REACTIVITY:   °
•  DOT HAZARD CLASS:
                                       119
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                             HAZARDOUS SUBSTANCES DATA SHEET
                       •            IDENTIFICATION

•  NAME:   METHYL METHXCRYLATE                                   •  CAS NO.:  80626

•  StNONYMS:    Methacrylic acid methyl ester,  methyl-2-methyl-2-propenate
•  MOLECULAR FORMULA:     C5H8°2
   STRUCTURAL FORMULA:

           CH, 0
           I  3 II
     CH2-C-C-0-CH3
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   0.94       •  VAPOR DENSITY (air-I):   3.45
•  VISCOSITY (centipoises):
•  SURFACE TENSION (dynes/cm):
•  MELTING POINT ( C):    -48
•  BOILING POINT ( C) :   101
•  FLASH POINT (°C) :   10  9 0°C
•  IGNITION TEMP. ( C):
•  VAPOR PRESSURE (mm Hg) :   30 @  25.5 C    •  FLAMMABILITY LIMITS:  1.7 - 8.2
                                              (Vol. I in air)


•  SOLUBILITY IN WATER (ppm) : " 1.600       •  PERSISTENCE (0 to 2 rating.) :  1
                               3 20°C


                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:  D
•  KF7A HAZARD RATING:        HEALTH:   2    FLAMMABILITY:   3    REACTIVITY:   2
•  DOT HAZARD CLASS:  F-L-
                                         120
-------
                           HAZARDOUS  SUBSTANCES  DATA SHEET
                       «            IDENTIFICATION
       :   METHYL PARATHION                                       •   CAS  NO.:   298000
   SYNONYMS:   Nitrox-80
   MOLECULAR FORMULA:     CaHlr.NO,PS       •  STRUCTURAL FORMULA:
                             1   i                  nrn
                                                    OCH3
                                                S - P - 0
                                                    OCH3
                            PHYSICAL/CHEMICAL PROPERTIES
•  SPECIFIC GRAVITY  (water-1):  1.3        •  VAPOR DENSITY  (air-1):


•  VISCOSITY (ceatipolses):                •  SURFACE TENSION  (dynes/ca):
   MELTIMG POINT (°C):  35 -  36            •  BOILING POINT  (°C):  decomposes
   FLASH POINT (°C) :    46.1  (open  cup)     •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (na Hg):  -0.97  @  20°C    •  FLAMMABILITY LIMITS:
                                              (Vol. I in air)

•  SOLUBILITY IN WATER (ppm):  "50 @ 25°C   •  PERSISTENCE  (0 to 2 rating):  1
                                HAZARD CLASSIFICATION'S
•   EPA  REPORTABLE  QUANTITY  CATEGORY:   B
•  NFPA HAZARD RATING:        HEALTH:  4    FLAMMABILITY:  1    REACTIVITY:   2  (solid)
                                       4                   32  (Xylene
                                                                              solution)
•  DOT HAZARD CLASS:    Pois. B
                                        121
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                           HAZARDOUS SUBSTANCES DATA SHEET
                       •>           IDENTIFICATION

•  NAME:    MEVINPHOS  *                                          •  CAS NO.:  7786347

•  SYNONYMS:   Phosdrin
•  MOLECULAR FORMULA:   C7H.-0,P           •  STRUCTURAL FORMULA:
                                                CH n °       H   °
                                                  3\||       |    U
                                                     P-0-C-C-C-O-CH.
                                                    '        I

                                                GH~3°         «a

                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.25       •  VAPOR DENSITY  (air-1):   3.2
•  VISCOSITY (centipoisea):                •  SURFACE TENSION (dynes/on):



•  MELTING POINT (°C):                     •  BOILING POINT (°C):  99  -  103  <§  0.03 mm Hg



•  FLASH POINT (°C):   49                   •  IGNITION TEMP. (°C):



•  VAPOR PRESSURE (mm Hg):  2.9 x  10"3  @    .  FLAMMABILITY LIMITS:
                            21°C               (Vol. 2 in air)


•  SOLUBILITY IN WATER (ppm):   miacible    •  PERSISTENCE  (0 Co 2 rating):   1



                                HAZARD CLASSIFICATIONS

•  EPA  REPORTABLE QUANTITY  CATEGORY:   X


•  KFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:



•  DOT HAZARD CLASS:
                                         122
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                           HAZARDOUS  SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

 •  SAME:   MONOETHYLAMfNE                                         •   CAS  HO.:  75047

 •  SYNONYMS:   Ethylamine, aainoethane



 «  MOLECULAR FORMULA:   CN              «  STRUCTURAL FORMULA:
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1) :  0.8        •  VAPOR DENSITY  (air-1) :   1.6



•  VISCOSITY (centipolses) :                •  SURFACE TENSION (dynes/on):



•  MELTING POINT (°C) :   -80.6             •  BOILING POINT  (°C) :   16.6
   FLASH POINT (°C):   <21.1                •  IGNITION TEMP. (°C):  385
•  VAPOR PRESSURE (mm Eg):  1094.2  @  25°C   •  FLAMMABILITY LIMITS: 2.5 - 14.0
                                              (Vol. I In air)


•  SOLUBILITY IN WATER (ppm):   miscible    •  PERSISTENCE (0  Co 2 racing):   0


                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY  CATEGORY:   C


•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY: 4     REACTIVITY:  0



•  DOT HAZARD CUSS:  F-L-
                                        123
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                          HAZARDOUS SUBSTANCES DATA SHEET
                        »            IDENTIFICATION

 •  KAME:   HALED      «                                       '   •  CAS NO.:  300765

 •  SYNONYMS:   Dibroa



 •  MOLECULAR. FORMULA:  C^Br.Cl^P       •  STRUCTURAL FORMULA:

                                                 _,.  0       Br  Br.
                                                 C*3°\ II       I    I
                                                       P-0-C-C-C1

	*?''       H   Cl

                             PHYSICAL/CHEMICAL PROPERTIES

 •  SPECIFIC GRAVITY (water-!):  1.95       •  VAPOR DENSITY (air-1):



 «  VISCOSITY (centipol»e«):                •  SURFACE TENSION (dynes/cm):
 e  MELTING POINT (°C):    27                 •  BOILING POINT (°C):  110  (0.5 mm Hg)
 •  FLASH POINT (°C):  54                    •  IGNITION TEMP. (°C):
 •  VAPOR PRESSURE (am Hg): 2 x 10""4 (3  20°C •  FLAMMABILITY LIMITS:
                                               (Vol. X In «ir)
 •  SOLUBILITY IN WATER (ppm):  ' 500         •  PERSISTENCE (0 to 2 rating):
                                 HAZARD CLASSIFICATIONS
 •  EPA REPORTABLE QUANTITY CATEGORY:  A
 •  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
 •  DOT HAZARD CLASS:
                                         124
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                            HAZARDOUS SUBSTANCES DATA  SHEET
                                    IDENTIFICATION

 •   NAME:   NAPHTHENIC ACID*                                       •  CAS NO.: 1338245

 •   SYNONYMS:   Cyclohexanecarborylic acid, hexahydrobenzoic acid
 •  MOLECULAR FORMULA:
*contains other sacuraced fatty acids
             •  STRUCTURAL FORMULA:

                      0-C-OH
                             PHYSICAL/CHEMICAL PROPERTIES

 •  SPECIFIC GRAVITY (water-1):   1.03       •  VAPOR DENSITY (air-1):
•  VISCOSITY  (centipoises):
             •  SURFACE TENSION (dynes/cm):
•  MELTING POINT  (  C):   30
             •  BOILING POINT ( C):  233
 •   FLASH POINT  (  C):  149
             •  IGNITION TEMP. (°C):
 •  VAPOR PRESSURE  (mm Hg):  46 @ 38 C
             •  FLAMMABILITY LIMITS:
                (Vol. Z in air)
 •   SOLUBILITY  IS WATER  (ppm):   2,010        •   PERSISTENCE  (0  to  2  rating):
                                8. 25°C
                                HAZARD CLASSIFICATIONS

    EPA REPORTABLE QUANTITY CATEGORY:  B
 •  NFPA HAZARD RATING:
HEALTH:       FLAMMABILITY:       REACTIVITY:
 •   DOT  HAZARD  CLASS:
                                       125
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                          HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

•  KAME:   NITRIC ACID -                                           «   CAS  NO.-.  7697372

<>  SYNONYMS:   Aqua fortis



•  MOLECULAR FORMDLA:    HN03              •  STRDCTURAL FORMULA:



                                                 H+ NoJ



                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  1.5        •  VAPOR DENSITY  (air-1):



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm) :
•  MELTING POINT (°C):   -42                •  BOILING POINT (°C):   86
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (am Hg):  7.1 @  20°C      •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER (ppm):   miscible    •  PERSISTENCE (0 Co 2 rating):



                                HAZARD CLASSIFICATIONS


 •  EPA REPORTABLE QUANTITY CATEGORY:   C


•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:  0    REACTIVITY:  0



•  DOT HAZARD CLASS:  Oxy. M
                                        126
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                        HAZARDOUS SUBSTANCES  DATA SHEET
                       »            IDENTIFICATION



   HAME:    NITROBENZENE                                       '   •   CAS  NO.:  98953



   SYNONYMS:     Nitrobenzol,  oil of mirbane
   MOLECULAR FORMULA:      C,H,NO          •  STRUCTURAL FORMULA:
                            o  5   2
                                                       NO,
                            PHYSICAL/CHEMICAL PROPERTIES



•  SPECIFIC GRAVITY  (water-1):   1.2        •  VAPOR DENSITY  (air-1):  4.3






•  VISCOSITY (centipoises):2.03  @  20°C     •  SURFACE TENSION (dynes/cm):  43.9 9  20°C
•  MELTING POINT (°C):   6                  •  BOILING POINT (°C): 211
•  FLASHPOINT (°C):  87.8                 •  IGNITION TEMP. (°C):  482.2







•  VAPOR PRESSURE (mm Hg): 0-.284 8 25°C    •  FLAMMABILITY LIMITS:  1.8 -

                                              (Vol. I in air)





•  SOLUBILITY IN WATER  (ppm):   1,900      •  PERSISTENCE  (0 to  2 racing):   2

                                9  20°C




                                HAZARD CLASSIFICATIONS



 •   EPA REPORTABLE QUANTITY CATEGORY:   C






•  HFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:  2    REACTIVITY:   0







•  DOT HAZARD CLASS:  ?o±s. B
                                       127
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                            HAZARDOUS SUBSTANCES DATA SHEET
                                   IDENTIFICATION

   NAME:   NITROGEN DIOXIDE                                      «  CAS  NO.: 10102440

   SYNONYMS:  Nitrogen  tetroxlde
   MOLECULAR FORMULA:    NO, =s N^        •  STRUCTURAL FORMULA:

                                                0 • N - 0
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water«l):  1.45       •  VAPOR DENSITY (air-1):  1.59



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):



•  MELTING POINT (°C):  -9.3               .  BOILING POINT (°C):   21.3
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg):  760 8 21°C     e  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER (ppm):   decomposes  •  PERSISTENCE (0 to  2 rating):



                                HAZARD CLASSIFICATIONS

•  EPA IMPORTABLE QUANTITY CATEGORY:  C



•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:   °   REACTIVITY:  0



•  DOT HAZARD CLASS:   p0ia. A
                                      128
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                            HAZARDOUS SUBSTANCES DATA  SHEET
                       «            IDENTIFICATION

•  NAME:      PARATHION1                                           •   CAS  NO.:  56382

•  SYNONYMS:    DNT?. Niran



•  MOLECULAR FORMULA:  C.nHn/NO.PS         •  STRUCTURAL FORMULA:
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.3        •  VAPOR DENSITY  (air«l):



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):



•  MELTING POINT (°C):  6                  •  BOILING POINT  (°C): 375
•  FLASH POINT (°C):   132                 •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg):  0.03 9 24°C    •  FLAMMABILITY LIMITS:
                                              (Vol. 2 in air)


•  SOLUBILITY IN WATER (ppm):   20          .  PERSISTENCE (0 to 2 racing):   1



                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY CATEGORY:  TL



•  NFPA HAZARD SATING:        HEALTH:  4    FLAMMABILITY:  1    REACTIVITY:  2



•  DOT HAZARD CLASS:  Pois.  B
                                       129
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                           HAZARDOUS SUBSTANCES DATA SHEET
                                   IDENTIFICATION
•  NAME:   PHENOL                                                •  CAS NO.:  108952

•  SYNONYMS:   Carbolic acid,  phenyl hydroxide, hydroxybenzene, oxybenzene
•  MOLECULAR FORMULA:     C6H6°            *  STRUCTURAL FORMULA:

                                                      OH
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.1         •  VAPOR DENSITY (air-1):  3.2



•  VISCOSITY (centipoises):  3.49  9  50°C    •  SURFACE TENSION (dynes/cm): 40.9 9 20°C



•  MELTING POINT (°C):  41                 .  BOILING POINT (°C): 182



•  FLASHPOINT (°C):   79                   •  IGNITION TEMP. (°C): 715
•  VAPOR PRESSURE (mm Hg): 0.530  9 25°C     •  FLAMMABILITY LIMITS:  1.5 -
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER (ppm):  6,700       •  PERSISTENCE  (0 to 2 racing):   2
                               9 25°C


                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:  C
•  NFPA HAZARD RATING:        HEALTH: 3     FLAMMABILITY:  2    REACTIVITY:   0
•  DOT HAZARD CLASS:  Pois. B
                                       130
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                           HAZARDOUS SUBSTANCES DATA SHEET
                       «           IDENTIFICATION

   NAME:   PHOSGENE    *                                         •  CAS  NO.:  75445

   SYNONYMS:      Diphosgene, carbonyl chloride, chloroform?! chloride
•  MOLECULAR FORMULA:   CC120              ,  STRUCTURAL FORMULA:
                                                    0
                                                    II
                                                    C
                                                   /  \
                                                Cl     Cl

                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   1.4        •  VAPOR DENSITY  (air-1):  3.4
•  VISCOSITY (cencipoises):                •  SURFACE TENSION (dynes/cm):
   MELTING POINT (°C):  -118                •  BOILING POINT (°C):  8.2
   FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (am Hg):  -1200  @ 20°C   •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER  (PP»):   decomposes •  PERSISTENCE (0  Co  2  rating):   0


                                HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY CATEGORY:  D


•  NFPA HAZARD RATING:        HEALTH: 4     FLAMMABILITY:  0    REACTIVITY:  Q



•  DOT HAZARD CLASS: Pois. A
                                       131
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                            HAZARDOUS SUBSTANCES DATA SHEET
                       «            IDENTIFICATION


•  NAME:   PHOSPHORIC XCID                                       •  CAS NO.:   7664382


e  SYNONYMS:
   MOLECULAR FORMULA:    H3°4P              •  STRUCTURAL FORMULA:

                                                        OH

                                                   HO - P - 0
                                                        t
                                                        OH
                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY (water-1):   1.9        •  VAPOR DENSITY (air-1):





•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/on):





•  MELTING POINT (°C):   42.3               •  BOILING POINT (°C): decomposes at  213
•  FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg) :                 •  FLAMMABILITY LIMITS:
                                              (Vol. 2 in air)




•  SOLUBILITY IN WATER (ppn):   miscible    •  PERSISTENCE (0  to 2 rating):   2





                                HAZARD CLASSIFICATIONS
 •   EPA REPORTABLE  QUANTITY  CATEGORY:  D




•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:  0    REACTIVITY:   0





•  DOT HAZARD CLASS:  Cor.
                                        132
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                           HAZARDOUS SUBSTANCES DATA SHEET
                       »           IDENTIFICATION
•  SAME:   PHOSPHORUS OXYCELORIDE                                 •   CAS  NO.:  10025873
•  SYNONYMS:     Phosphoryl chloride, phosphorus chloride
   MOLECULAR FORMULA:     C1,OP            •  STRUCTURAL FORMULA:
                                                             Cl
                                                    0  -  P  -  Cl
                                                          XC1
                            PHYSICAL/CHEMICAL PROPERTIES
•  SPECIFIC GRAVITY  (water-1):   1.7       •  VAPOR DENSITY  (air-1):   6.8


•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):


•  MELTING POINT (°C):   1.25               •  BOILING POINT  (°C):   107
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (nan Hg):  • 28  @ 20°C    •  FLAMMABILITY LIMITS:
                                              (Vol. 2 in air)

•  SOLUBILITY IN WATER (ppm):  decomposes  •  PERSISTENCE (0 Co 2 rating):

                                HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY  CATEGORY:   D


•  NFPA HAZARD RATTJJG:        HEALTH:  3    7LAMMABILITY:  0    REACTIVITY:   2


•  DOT HAZARD CLASS:  Cor.
                                        133
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                          HAZARDOUS SUBSTANCES DATA SHEET
                                   IDENTIFICATION

•  NAME:  PHOSPHORUS TRICHLORIDE                                  •   CAS  NO.: 7719122

•  SYNONYMS:  Phosphorus chloride



•  MOLECULAR FORMULA:  CljP                ,  STRUCTURAL FORMULA:

                                                   Cl    Cl

                                                     V

                                                       Cl


                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water»l) :  1.6        •  VAPOR DENSITY  (air-1) :  4:8



•  VISCOSITY (centipoises) :                •  SURFACE TENSION (dynes/cm) :
   MELTING POINT (°C) :  -112               ,  BOILING POINT (°C) :  76
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg): 100 8 21°C      •   FLAMMABILITY LIMITS:
                                               (Vol. ^ in air)


•  SOLUBILITY IN WATER (ppm):   decomposes  •  PERSISTENCE  (0  to  2  rating):   0



                                HAZARD CLASSIFICATIONS
 •  EPA REPORTABLE QUANTITY CATEGORY:  D
•  NFPA HAZARD RATING:        HEALTH:  3  '  FLAMMABILITY:   0   REACTIVITY:  2
   DOT HAZARD CLASS:  Cor.
                                        134
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                       HAZARDOUS SUBSTANCES DATA SHEET
                       «           IDENTIFICATION



•  NAME:  POLYCHLORINA5ED BIPHENYLS



•  SYNONYMS:  PCS, aroclor, polychlorinated biphenyls
                                      CAS NO.: 1336363
•  MOLECULAR FORMULA:   C,,H Cl,.
                         12 a  XO—a
                                           •  STRUCTURAL FORMULA:
                                                                        X " Cl or H
                            PHYSICAL/CHEMICAL PROPERTIES



   SPECIFIC GRAVITY (vater-1):  1.2-1.5    •  VAPOR DENSITY (air-1):
•  VISCOSITY (centipoises):
                SURFACE TENSION (dynes/cm):
•  MELTING POINT ( C):
             •  BOILING POINT ( C): 325-366
•  FLASH POINT (°C):
             •  IGNITION TEMP. (°C);
•  VAPOR PRESSURE (mm Hg): 
-------
                           HAZARDOUS SUBSTANCES DATA  SHEET
                                      IDENTIFICATION
•  NAME: PROPIONIC ACID

•  SYNONYMS:





•  MOLECULAR FORMULA:  C3Hs02
                   e  CAS NO.:  79094
•  STRUCTURAL FORMULA:

               0

   CH3  -  CH2  -  C  - OH
                               PHYSICAL/CHEMICAL PROPERTIES

   SPECIFIC GRAVITY (water-!):  1.0            •  VAPOR DENSITY (air-1):  2.5
•  VISCOSITY (centipoises):  1.1 9  2Q°C
•  MELTING POINT (°C):  -21
•  FLASH POINT ( C):  54.4
•  VAPOR PRESSURE (mm Hg):  4.5  <§ 25  C
e  SURFACE TENSION (dynes/cm): 26.7
                               20°C
•  BOILING POINT (°C): 141
   IGNITION TEMP. (°C) :  512.8
c  FLAMMABILITY LIMITS:  2.9
   (vol. X in air)
•  SOLUBILITY IN WATER (ppm):  niscible        •  PERSISTENCE  (0 to 2 rating):  0
                                  HAZARD CLASSIFICATIONS
 •   EPA REPORTABLE QUANTITY  CATEGORY:  D
•  NFPA HAZARD RATING:         HEALTH:  2      FLAMMABILITY:  2        REACTIVITY:   0
•  DOT HAZARD CLASS:  Cor.
                                        136
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                        HAZARDOUS  SUBSTANCES DATA SHEET
                       «            IDENTIFICATION



•  NAME:  PROPIONIC ANHYDRIDE                                    •  CAS  NO.:  123626



•  SYNONYMS:   Propanoic anhydride, mechylacecic anhydride
•  MOLECULAR FORMULA:   C,H,nO,            •  STRUCTURAL FORMULA:     o
                         o xu j                                      /.
                                                       CH, - CH, - C'
                                                         J     i
                            PHYSICAL/CHEMICAL PROPERTIES



•  SPECIFIC GRAVITY  (water-1):  1.0        •  VAPOR DENSITY  (air-1):  4.5
•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/en);
•  MELTING POINT (°C):  -45                •  BOILING POINT (°C):  168
•  FLASH POINT (°C):   73.9                •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (nm Hg) : 1 
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                           HAZARDOUS SUBSTANCES DATA SHEET
                                      IDENTIFICATION

•  NAME:  PROPYLENE OXIDE                                         •  CAS NO.:  75-56-9
•  SYNONYMS:  Propane  oxide,  1 , 2-epoxypropane



•  MOLECULAR FORMULA:   C3E^O                  •  STRUCTURAL FORMULA:

                                                      A
                               PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1) :  0.831           •  VAPOS DENSITY  (air-1) : 2.00
«  VISCOSITY (centipoises): 0.327  9 20°C        e  SURFACE TENSION  (dynes/cm):
   MELTING POINT (°q):  -104                   •  BOILING POINT  (°C):  35



   FLASH POINT (°C):  -37 (open Clip)            .  IGNITION TEMP.  (°C):  4*
•  VAPOR PRESSURE (mm Hg):  4.45 @ 20°C        •  FLAMMABILITY LIMITS:  2.1-21.5
                                                  (vol. 2 in air)


•  SOLUBILITY IN WATER (ppm):  330,000 @ 30°C  .  PERSISTENCE (0 to 2 rating): 0
                                  HAZARD CLASSIFICATIONS
 •   EPA REPORTABLE QUANTITY  CATEGORY:  D
•  NFPA HAZARD RATING:         HEALTH:  2      FLAMMABILITY:  4       REACTIVITY:  2
•  DOT HAZARD CLASS:
                                         138
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                          HAZARDOUS  SUBSTANCES DATA SHEET
                       «            IDENTIFICATION

   NAME:   PYRETHRINS  «                                           •  CAS NO.: 121299
                                                                           (Pyrethrin I)
   SYNONYMS:   Pyrethrin  I, Pyrethrin  II                                      121211
                                                                           (Pyrethrin II)


   MOLECULAR FORMULA:     C21H28°3           *  STRUCTURAL FORMULA:
                           and                    H r ctr^  ^x~\_, CM-jCH — me* — CM,
                                                   V
                         C22H28°5            "*
                                                                           (Pyrethrin  I)
                             PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  1.5         •   VAPOR DENSITY (air-1):



•  VISCOSITY (centipoises):                 •   SURFACE  TENSION (dynes/cm):



•  MELTING POINT  (°C):  0                   9   BOILING  POINT (°C):   decomposes
•  FLASH POINT  (°C):                       •   IGNITION TEMP.  (°C):
•  VAPOR PRESSURE  (mm Hg}:  •              •   FLAMMABILITY  LIMITS:
                                               (Vol.  Z  in air)


•  SOLUBILITY IN WATER (ppm):  1           •   PERSISTENCE (0 to 2 rating):
                                HAZARD CLASSIFICATIONS
•  EPA  REPORTABLE  QUANTITY CATEGORY:   C
•  HFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:        REACTIVITY:
•  DOT HAZARD CLASS:
                                         139
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                       HAZARDOUS SUBSTANCES DATA SHEET
                       •»           IDENTIFICATION

•  SAME:  QUINOLINE    «                                           •  CAS  NO.: 91225

c  SYNONYMS:  1-benzazine, benzo(b)pyridine, leuocoline, chinoleine, leucol
•  MOLECULAR FORMULA:  r „ «               •  STRUCTORAL FORMULA:
                       C9
                       r „ «
                       CH7N
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1): 1.1         •  VAPOR DENSITY  (air-1): 4.5



•  VISCOSITY (ceatipoisea):  0.6 @ 17°C    e  SURFACE TENSION  (dynes/cm):  17 @ 28.5°C
•  MELTING POINT (°C):   -15               •  BOILING POINT  (°C):  237.7
•  FLASHPOINT (°C):                       •  IGNITION TEMP.  (°C):  480
•  VAPOR PRESSURE (nan Hg): 1 8 59.7        •  FLAMMABILITY LIMITS:  1.2 -
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER (ppm):  60,000      •  PERSISTENCE  (0 to 2 racing):  0
                               @ 25°C


                                HAZARD CLASSIFICATIONS

 •  EPA  REPORTABLE QUANTITY  CATEGORY:   C



•  NF?A HAZARD RATING:        HEALTH:   2   FLAMMABILITY:   1   REACTIVITY:   0



•  DOT HAZARD CLASS:
                                        140
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                          HAZARDOUS  SUBSTANCES  DATA SHEET
                       •            IDENTIFICATION

   HAME:    SODIUM HYPOCHLORITE                                   •  CAS NO.:  7681529
                                                                              10022705
   SYNONYMS:  Bleach
•  MOLECULAR FORMULA:   NaCIO              •  STRUCTURAL FORMULA:

      (usually in solution;                        Ha - 0
      dihydrate is solid)                              i
                                                       Cl
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):   1.0       •  VAPOR DENSITY  (air-1):




•  VISCOSITY (cencipoises):                •  SURFACE TENSION  (dynes/cm):
   MELTING POINT (°C):  57.5 (dihydrate)   •  BOILING POINT (°C):
   FLASHPOINT (°C):                       •  IGNITION TEMP.  (°C):
•  VAPOR PRESSURE (mm Eg):                 •  FLAMMABILITY LIMITS:
                                              (Vol. X in air)


•  SOLUBILITY IN WATER  (ppm):  293.000    *  PERSISTENCE (0 to 2 rating):
                                @ 06C


                                HAZARD CLASSIFICATIONS
•   EPA  REPORTABLE  QUANTITY  CATEGORY:   B
•  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:
                                        141
-------
                         HAZARDOUS SUBSTANCES DATA SHEET
                                   IDENTIFICATION
e  HAKE:   STYRENE                                               «  CAS NO.:  100425

•  SYNONYMS:   Vinylbenzene, phenylethylene, styrol, styrolene, cinnamene, cinnamol
•  MOLECULAR FORMULA:    CgHg              •  STRUCTURAL FORMULA:
                                                   pH » CH2
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  0.9        •  VAPOR DENSITY (air-l): 3.5



•  VISCOSITY (eentipoisea):                •  SURFACE TENSION (dynes/on):  32.1 @ 19°C
   MELTING POINT (°C):   31                •  BOILING POINT (°C):  146
•  FLASH POINT (°C):   32                  •  IGNITION TEMP. (°C):  490
•  VAPOR PRESSURE (aim Hg): 6.05 9 25°C     •  FLAMMABILITY LIMITS:  1.1 - 6.1
                                              (Vol. Z In air)


•  SOLUBILITY IN WATER (PP»):   320 @ 25°C  •  PERSISTENCE (0 to 2 rating) :   1



                                HAZARD CLASSIFICATIONS
    ERA  REPORTABLE QUANTITY  CATEGORY:  C
•  NFPA HAZARD RATING:        HEALTH:   2   FLAMMABILITY:   3   REACTIVITY:    2
•  DOT HAZARD CLASS:    F-L-
                                       142
-------
                             HAZARDOUS SUBSTANCES DATA SHEET
                       »            IDENTIFICATION



•  NAME:   SULFURIC ACID                                         •  CAS NO.:  7664937



•  SYNONYMS:   Oil of vitriol, oleum






•  MOLECULAR FORMULA:   H2°4S              •  STRUCTURAL FORMULA:

                                                     0
                                                     it

                                                HO - S - OH
                                                     g

                                                     0




                            PHYSICAL/CHEMICAL PROPERTIES



•  SPECIFIC GRAVITY  (water-1):  1.8        •  VAPOR DENSITY  (air-1):






•  VISCOSITY (centlpoises):  26.9 I? 15     •  SURFACE TENSION (dynes/cm);  55.1 @ 20°C
   MELTING POINT <°C):  10                 •  BOILING POINT (°C):  290
   FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
                                  -
•  VAPOR PRESSURE (mm Hg):  3 x 10         •  FLAMMABILITY LIMITS:

                                              (Vol. I in air)




•  SOLUBILITY IN WATER (ppm):  miscible    •  PERSISTENCE.^ to 2 rating):  2





                                HAZARD CLASSIFICATIONS



•  EPA  REPORTABLE QUANTITY  CATEGORY:  C
•  NFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:   0   REACTIVITY:   2
•  DOT HAZARD CLASS:   Cor.
                                         143
-------
                           HAZARDOUS  SUBSTANCES  DATA SHEET
                       •            IDENTIFICATION

•  NAME:     SULFUR MONOCHLORIDE                                 •  CAS NO-: 12771083

•  SYNONYMS:  Sulfur chloride
•  MOLECULAR FORMULA:     ci  S              •  STRUCTURAL FORMULA:

                                                  Cl - S - S - Cl
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  1.7        •  VAPOR DENSITY (air-1):



•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):  -82                •  BOILING POINT (°C):  138
•  FLASHPOINT (°C):   118                 •  IGNITION TEMP. (°C):  239



•  VAPOR PRESSURE (mm Hg):   10 (3 27.5°C   •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)


•  SOLUBILITY IN WATER (ppm):   decomposes  •  PERSISTENCE (0 to 2 racing):



                                HAZARD CLASSIFICATIONS

*  EPA  REPORTABLE QUANTITY CATEGORY:   C



•  NFPA HAZARD RATING:        HEALTH!  2    FLAMMABILITY:  1    REACTIVITY:  1



•  DOT HAZARD CLASS:   Cor.
                                        144
-------
                          HAZARDOUS SUBSTANCES DATA SHEET
                       »           IDEKTIFICATION   .

•  NAME:   TETRAETHYL BEAD                                       •  CAS NO.: 78002

•  SYNONYMS:  Lead  tetraetnyl, TEL
•  MOLECULAR FORMULA:  CgH^Pb             •  STRUCTURAL FORMULA:


                                                C2H5N  /C2H5

                                                _ _  S  \ _ _
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1):  1.7        •  VAPOR DENSITY  (air-1):  8.6



•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/cm):
•  MELTING POINT <°C):  -137               •  BOILING POINT  (°C): decomposes above 230
•  FLASHPOINT (°C):  93.3                 •  IGNITION TEMP.  (°C):
   VAPOR PRESSURE (am Hg):  1 @ 28.4°C     •  FLAMMABILITY LIMITS:
                                              (Vol. Z In air)


   SOLUBILITY IN WATER  (PP«)'   30 @ 25°C  •  PERSISTENCE  (0 to 2 rating):   1
                                HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE QUANTITY CATEGORY:   B





•  KFPA HAZARD RATING:        HEALTH:  3    FLAMMABILITY:   2   REACTIVITY:   3



•  DOT HAZARD CLASS:  Pois. B
                                        145
-------
                              HAZARDOUS SUBSTANCES DATA SHEET
                       »            IDENTIFICATION

«  NAME:    TETRAETHYL'PYROPHOSPHATE                             •  CAS NO,;  107493

e  SYNONYMS:   TEPP



•  MOLECULAR FORMULA:   C8H10°7P2          *  STKDCTOTAL FORMULA:
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1) :             •  VAPOR DENSITY (air-1) :



•  VISCOSITY (cent±pois«s) :                e  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):                     •  BOILING POINT (°C):
•  FLASHPOINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (MB Hg):                 •  FLAMMABILITT LIMITS:
                                              (Volo % in air)


e  SOLUBILITY IN WAXES (ppm):   miscible    •  PERSISTENCE (0 to 2 rating):   1



                                HAZARD CLASSIFICATIONS


 •   EPA REPORTABLE QUANTITY  CATEGORY:   C



•  HFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:



•  DOT HAZARD CLASS:
                                        146
-------
                             HAZARDOUS SUBSTANCES DATA SHEET
                       *           IDENTIFICATION

•  SAME:  TOLUENE      •                                          •  CAS  NO.:  108883

•  SYNONYMS:   Toluol, methylbenzene, phenylaethane
•  MOLECULAR FORMULA:  C?Hg                •  STRUCTURAL FORMULA:
                                                     CH3
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):  0.9        •  VAPOR. DENSITY  (air-1):  3.1
•  VISCOSITY (centipoises):  0.6 @ 17°C    •  SURFACE TENSION (dynes/cm):  28.5 9 20°C
•  MELTING POINT (°C):  -95                •  BOILING POINT (°C):  110.6
•  FLASH POINT (°C):  4.4                  •  IGNITION TEMP. (°C):  480
•  VAPOR PRESSURE (mm Hg):  28.4 <§ 25°C    •  FLAMMABILITY LIMITS:  1.2 - 7.1
                                              (Vol. Z ia air)


•  SOLUBILITY IN WATER (ppm):   470 @ 25°C  •  PERSISTENCE  (0 to 2 rating):   0
                                HAZARD CLASSIFICATIONS

 •   EPA REPORTABLE QUANTITY CATEGORY:   C



•- NFPA HAZARD RATING:        HEALTH:   2   FLAMMABILITY:.  3   REACTIVITY:   0



•  DOT HAZARD CLASS:   F.L_
                                      147
-------
                            HAZARDOUS SUBSTANCES DATA SHEET
                                      IDENTIFICATION

•  NAME:  TRICHLORDETHYLENE

•  SYNONYMS:   Ethylene  trichloride, trichloroethene
                   •  CAS NO.;  79-01-6
•  MOLECULAR FORMULA:   C2HC13
•  STRUCTURAL FORMULA:


   C12C « CHC1
                               PHYSICAL/CHEMICAL PROPERTIES
•  SPECIFIC GRAVITY  (water-1):  1.466



•  VISCOSITY (centipoises):  0.566 £.20°C



•  MELTING POINT (°C):  -73



•  FLASH POINT  (°C):  32

        ignites with difficulty

•  VAPOR PRESSURE  (mm Hg):  100 @ 31.4°C
•  VAPOR DENSITY (air-1): 4.53
•  SURFACE TENSION (dynes/cm): 29.5
                               20°C
•  BOILING POINT (°C):   87.2
•  IGNITION TEMP. (°C): 410
•  FLAMMABILITY LIMITS: 12.5-90
   (vol. Z in air)
c  SOLUBILITY IN MATER (ppm):  1000 9 25 C     •  PERSISTENCE  (0 to 2 rating):  2
                                  HAZARD CLASSIFICATIONS

•  EPA REPORTABLE QUANTITY CATEGORY:  C



•  NFPA HAZARD RATING:         HEALTH:  1      FLAMMABILITY:'  1       REACTIVITY:  0



•  DOT HAZARD CLASS:  ORM
                                         148
-------
                          HAZARDOUS  SUBSTANCES DATA SHEET
                       »           IDENTIFICATION


•  NAME:    TRIETHYLAMINE                                      '  •  CAS NO.:  121448


•  SYNONYMS:





•  MOLECULAR FORMULA:   C,B.. ,N             •  STRUCTURAL FORMULA:
                         6                              r  B
                                                       /C2H5

                                              C2H5-\CH






                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY  (water-1): 0.8         •  VAPOR DENSITY (air-1):  3.5





•  VISCOSITY (centipoises):                •  SURFACE TENSION  (dynes/cm):  17.3 9 -4°C
   MELTING POINT (°C):   -115              •  BOILING POINT (°C): 90
•  FLASH POINT (°C):   -7                  •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg):  •               •  FLAMMABILITY LIMITS:  1.2 - 8.0

                                              (Vol. Z In air)




•  SOLUBILITY HI WATER  (ppm):   55,000     *  PERSISTENCE  (0 to 2 rating):
                                9 20°C



                                HAZARD CLASSIFICATIONS



•  EPA REPORTABLE QUANTITY CATEGORY:  D
•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:  3    REACTIVITY:  0
•  DOT HAZARD CLASS:  F-L-
                                       149
-------
                            HAZARDOUS SUBSTANCES DATA SHEET
                                   IDENTIFICATION
c  NAME:   TRIMETHYLAMINE


c  SYNONYMS:   TMA
                      •  CAS NO.:  75503
•  MOLECULAR FORMULA:    C3H9N
   STRUCTURAL FORMULA:

            CH-
                                                 CH- - N - CH3
                            PHYSICAL/CHEMICAL PROPERTIES


•  SPECIFIC GRAVITY (water-1):  0.7        •  VAPOR DENSITY  (air-1):  2.0
c  VISCOSITY (centipolses):
•  SURFACE TENSION (dynes/cm) :
e  MELTING POINT (°C):  -117.2
•  BOILING POINT (C):  2.9
•  FLASH POINT (°C):
•  IGNITION TEMP. (°C):  190
•  VAPOR PRESSURE (mm Hg):  687 9 0°C
   SOLUBILITY IN WATER (ppm):  435,000
                              8 30°C
                                           •  FUMMABILITY LIMITS: 2.0 - 11.6
                                              (Vol. Z in air)
•  PERSISTENCE  (0  to  2  rating):
                                HAZARD CLASSIFICATIONS
 •   EPA  REPORTABLE QUANTITY CATEGOEY:  C
•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:  *    REACTIVITY:   0
•  DOT HAZARD CLASS:   F.L.
                                          150
-------
                             HAZARDOUS SUBSTANCES DATA SHEET
                                    IDENTIFICATION
•  NAME:  viNYL ACETATE

•  SYNONYMS:   Acetic acid ethylene ether
                                                                     CAS  NO-:  108054
   MOLECULAR FORMULA:   C.H,0.
                         4 6 f.
                                           •   STRUCTURAL FORMULA:
                                                     0
                                                     i
                                               CH. - C - 0 - CH •  CH-
                            PHYSICAL/CHEMICAL PROPERTIES

   SPECIFIC GRAVITY  (water-l) :  0.9        •  VAPOR DENSITY  (air-1) :   3.0
•  VISCOSITY (centipoises) :
                                              SURFACE TENSION  (dynes/cm):  23.9 9 20°C
•  MELTING POINT (°C) :   -92.8
                                           •  BOILING POINT  (C) :   73
•  FLASHPOINT (°C):    -8
                                              IGNITION TEMP. (°C):  426.7
•  VAPOR PRESSURE (am Hg>:   107.5  8  2S°C   •  FLAMMABILITY LIMITS:
                                              (Vol. Z in air)
   SOLUBILITY IN WATER (ppm) :   20,000      .  PERSISTENCE- (0 to 2 rating):   1
                               @ 25°C
                                HAZARD CLASSIFICATIONS
•  EPA REPORTABLE QUANTITY CATEGORY:  C
   NFPA HAZARD RATING:
                              HEALTH:   2   FLAMMABILITY:   3   REACTIVITY:   2
•  DOT HAZARD CLASS:   F.L.
                                        151
-------
                               HAZARDOUS SUBSTANCES DATA SHEET
                                      IDENTIFICATION


•  NAME:  VINYLIDENE CHLORIDE

•  SYNONYMS: 1,1-Dichloroechylene, 1,1-dichloroethene
                   •  CAS NO.:   75-35-4
•  MOLECULAR FORMULA:
                                               •  STRUCTURAL FORMULA:
                                                     CH2 - CC12
                               PHYSICAL/CHEMICAL PROPERTIES
•  SPECIFIC GRAVITY (water-1): 1.25
   VAPOR DENSITY (air»l):  3.34
e  VISCOSITY (centipoises): -
   MELTING POINT (°C): -122.5
•  FLASH POINT ( C): -10  (open cup)
c  SURFACE TENSION (dynes/cm): -
•  BOILING POINT (°C):  31.9
•  IGNITION TEMP. (°C):  458
•  VAPOR PRESSURE (mm Hg): 500 9 20°C
•  FLAMMA3ILITY LIMITS:  5.6-11.4
   (vol. Z in air)
•  SOLUBILITY IN WATER  (ppm) :  V. si. sol.     •  PERSISTENCE  (0  to 2 racing):  -



                                  HAZARD CLASSIFICATIONS

 •  EPA REPORTABLE  QUANTITY  CATEGORY:  D



•  NFPA HAZARD RATING:         HEALTH: 2       FLAMMABILITY:  4       REACTIVITY:  2



•  DOT HAZARD CLASS: -
                                        152
-------
                        HAZARDOUS  SUBSTANCES DATA SHEET
                                    IDENTIFICATION

•  NAME:     XYLENE                                               •  CAS NO.: 1330207
                                                                              (mixed)
•  SYNONYMS:   DJmethylbenzene                                                108383  (m-)
               Xylol                                                          95476  (o-)
                                                                              106423  (p-)

•  MOLECULAR FORMULA:   C8H10               •  STRUCTURAL FORMULA:
                                                (ortho)   CH3
                             PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY  (water-1): 0.86 - 0.88  •  VAPOR DENSITY (a±r-l):3.7  (o-, m-, p-)



•  VISCOSITY  (centipolses):  0.62 <§ 20°C    •  SURFACE TENSION (dynes/cm): 28.9 @ 20°C
•  MELTING POINT  (°C):   -25  (o-)           •   BOILING POINT (°C):  144 (o-);  139 (m-);
                         -47  (m-)                                  130 (p-)
                           13 (p-)

•  FLASH POINT  (°C):  32.2  (o-)              •   IGNITION TEMP.  (°C):  465 (o-)
                      28.9  (m-)                                      530 (m-)
                      27.2  (p-)                                      530 (p-)

•  VAPOR PRESSURE  (mm Hg):                  •   FLAMMABILITY LIMITS:   1.1  - 7  (m-,  p-)
                                               (Vol.  Z in air)


•  SOLUBILITY IN WATER (ppffl):  175. @ 25°C   •   PERSISTENCE (0 to 2 rating):  0
                                HAZARD CLASSIFICATIONS
 •  EPA  REPORTABLE  QUANTITY  CATEGORY:   C
•  NFPA HAZARD RATING:        HEALTH:  2    FLAMMABILITY:   3     REACTIVITY: o
•  DOT HAZARD CLASS:  F.L.
                                       153
-------
                        HAZARDOUS SUBSTANCES  DATA SHEET
                                   IDENTIFICATION


•  SAME:    ZINC CHLORIDE  (solid,  often  shipped  in  solution)     •  CAS NO-:  7646857

•  SYNONYMS: Butter of zinc
•  MOLECULAR FORMULA:    Cl,Zn             •  STRUCTURAL FORMULA:

                                                      Cl

                                                  Zn
                            PHYSICAL/CHEMICAL PROPERTIES

•  SPECIFIC GRAVITY (water-1):   2.97       •  VAPOR DENSITY  (air-1):




•  VISCOSITY (centipoises):                •  SURFACE TENSION (dynes/cm):
•  MELTING POINT (°C):   290                •  BOILING POINT (°C):   732
•  FLASH POINT (°C):                       •  IGNITION TEMP. (°C):
•  VAPOR PRESSURE (mm Hg):  100  @ 610°C     •  FLAMMABILITY LIMITS:
                                              (Vol. I in air)


•  SOLUBILITY IN WATER (PP"):   4,320,000    ,  PERSISTENCE  (0  to  2  rating):
                               9 25°C


                                HAZARD CLASSIFICATIONS


•  EPA REPORTABLE QUANTITY  CATEGORY:  D
•  NFPA HAZARD RATING:        HEALTH:       FLAMMABILITY:       REACTIVITY:
•  DOT HAZARD CLASS:
                                       154
-------
                                     APPENDIX C

                            SORBENT MATERIAL DATA SHEETS
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   Absorbent 1012

•  CHEMICAL NAME OR DESCRIPTION:    expanded volcanic rock., created to repel water


•  MOLECULAR FORMULA:
•  FORM:    granules, packed in 25 Ib.  bags




                                      PROCUREMENT              • ,

•  MANUFACTURER/PROCESSOR:   Colloid Chemicals Co.,  P.O.  Box 861,  Brockton,  MA 02403


•  MATERIAL COST ($/LB):  0.33 (a)



                                       PROPERTIES

•  DENSITY (LBS/FT3):   6.5 (a)             ; (g/on3):   0.1

•  DEGRADABILITY:   none                    •  FLAMMABILITY:   none

•  TOXICITY:   none

•  SORPTION CAPACITY (L3S/LB):   5-7 (b)

•  RETENTION CAPACITY:  good (b)             •  AFFINITY FOR WATER:  low (b)
                                       REFERENCES
   (a)  Robertson,  1978
   (b)  Arthur D. Little,  1974
                                         155
-------
                             SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:    ash
•  CHEMICAL NAME OR DESCRIPTION:   inert  residue of  coal combustion

•  MOLECULAR FORMULA:
•  FORM:    powder
                                      PROCUREMENT
•  MANUFACTURER/PROCESSOR:   many  throughout the U.S.
•  MATERIAL COST ($/LB):    0.01
•  DENSITY aBS/FTJ):
•  DEGRADA3ILITY:   none
•  TOXICITY:
0  SORPTION CAPACITY (LBS/LB):
•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/an):
 c  FLAMMABILITY:   none
 •  AFFINITY FOR WATER:
                                       REFERENCES
                                          156
-------
                           SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:    calcium carbonate,  limestone
•  CHEMICAL NAME OR DESCRIPTION:   calcium  carbonate

•  MOLECULAR FORMULA:     Ca CO,
•  FORM:    powder
                                      PROCUREMENT
•  MANUFACTURER/PROCESSOR:   "any  throughout  the U.S.

•  MATERIAL COST ($/LB):     0.01-0.02  (a)
•  DENSITY (LBS/FT3):
•  DEGRADABILITY:  none
•  TOXICITY:
•  SORPTION CAPACITY (LBS/LB):
•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/cm >:
 •  FLAMMABILITY:   none
 •  AFFINITY FOR WATER:
   (a) Bauer et ml., 1975
                                       REFERENCES
                                         157
-------
                               SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   cellulose, vegetable  fiber  (e.g.,  straw,  sawdust,  bark,
                           peanut  hulls,  corn  cobs,  peat moss)
•  CHEMICAL NAME OR DESCRIPTION:     cellulose
•  MOLECULAR FORMULA:




•  FORK:   strands,  powder,  chips



                                      PROCUREMENT              -,  .

•  MANUFACTURER/PROCESSOR:  many  throughout  the U.S.'


•  MATERIAL COST ($/LB):   (straw)  .01-.02  (a)



                                       PROPERTIES

•  DENSITY (LBS/FT3);  (straw)  62  (a)       ;  (g/cm3): 0.99

•  DEGKADABILITY:    high                    •  FLAMMABILITY:  very high

•  TOXICITY:  none

•  SORPTION CAPACITY (LBS/LB):

•  RETENTION CAPACITY:                      •  AFFINITY FOR WATER:  variable



                                       REFERENCES

   (a) Robertson, 1978
                                            158
-------
                            SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:    Conwed

•  CHEMICAL NAME OR DESCRIPTION:  cellulose fiber treated to  repel water


•  MOLECULAR FORMULA:




•  FORM:    sheets,  pads,  sweeps,  strips,  pillows,  rugs



                                      PROCUREMENT              - ,

•  MANUFACTURER/PROCESSOR:   Conwed Corp.,  332 Minnesota St.,  St.  Paul,  MN  55101


•  MATERIAL COST ($/LB):   1.36-4.40 (a)



                                       PROPERTIES

•  DENSITY (LBS/FT3):   3.2 (b)             5 (g/cm3):    0.05

•  DEGRADABILITY:   biodegradable,           •  FLAMMABILITY:    high
                    sensitive to CV (b)
•  TOXICITY:

•  SORPTION CAPACITY (LBS/LB):  benzene: 12.6  (d);  phosphoric  acid (85Z):  5  (c)

•  RETENTION CAPACITY:                       •  AFFINITY FOR WATER:  low
                                       REFERENCES
   (a)  Swanson,  1978
   (b)  Robertson,  1978
   (c)  Diamond Shamrock  Corp.
   (d)  Bauer  et  al..  1975
                                          159
-------
                               SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:     Conwed-D
•  CHEMICAL NAME OR DESCRIPTION:  closed-cell polyethylene  foam, mechanically modified  to
                                  increase  sorption
•  MOLECULAR FORMULA:        r~, _-,  i
•  FORM:     pads,  21 x 21 x 1/4"
                                      PROCUREMENT              :,
•  MANUFACTURER/PROCESSOR:   Cowed Corp.,  332 Minnesota St., St. Paul, MN   55101
•  MATERIAL COST ($/LB):    3.59  (a)
•  DENSITY (LBS/FT3):   2.3  (b)
•  DEGRADABILITY:   none
•  TOXICITY:    none
•  SORPTION CAPACITY (LBS/LB):
•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/an):  0.04
 •  FLAMMABILITY:   low
 •  AFFINITY FOR WATER:  very low
   (a)  Swansea,  1978
   (b)  Robertson,  1978
                                       REFERENCES
                                         160
-------
                                SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   Diasorb, Universal Sorbent Material (USM)

•  CHEMICAL NAME OR DESCRIPTION:   silicate glass foam
•  MOLECULAR FORMULA:   Si02
•  FORM:   granules, 8-200 mesh
                                      PROCUREMENT              -,

«  MANUFACTURER/PROCESSOR:  Diamond Shamrock Corp., Soda Products Division,
                            1100 Superior Ave., Cleveland, OH  44114

•  MATERIAL COST ($/LB):
                                       PROPERTIES

•  DENSITY (LBS/FT3):   2.2 (a)            ; (g/=m ): 0.04

•  DEGRADABILITY:  none                     •  FLAMMABILITY:   none

•  TOXICITY:   LC5Q(inhalation)  >2.32 mg/1 (b);  LD5Q (oral) >15,380 ing/kg (b)

•  SORPTION CAPACITY (LBS/LB):   (b)   acrylonitrile: 10.2; benzene: 10.6; formaldehyde (37Z):
   8.6;  nitric acid (70Z):  20;  phenol (832):  15.5; phosphonic acid (85Z):  28;
   sulfuric acid (96Z):  19.2;                •  AFFINITY FOR WATER:   falr
   toluene/xylene:  11.2


                                       REFERENCES
   (a) Diamond Shamrock Corp., 1976.
   (b) Temple et al.,  1978
                                         161
-------
                               SORBENT MATERIAL DATA  SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   Fiberperl

e  CHEMICAL NAME OR DESCRIPTION: mixture  of  expanded  perlite and  cellulose  fiber,
                                 treated  to  repel water

•  MOLECULAR FORMULA:
•  FORM:  particles packed in 18-Ib. bags



                                      PROCUREMENT              -,

•  MANUFACTURER/PROCESSOR:  Grefco Inc., 630 Shatto Place, Los Angeles, CA  90005


•  MATERIAL COST ($/LB):    0.31 (a)



                                       PROPERTIES

•  DENSITY (LBS/FT3):  4.5 (a)              ; (g/cm3):   0.07

•  DEGRADABILITY:  low                      •  FLAMMABILITY:  high

•  TOXICITY:   none

•  SORPTION CAPACITY (LBS/LB): • perchloroethylene:  8 (b);  phosphoric acid (85Z):  very
                                poor (b)
•  RETENTION CAPACITY:                       •  AFFINITY FOR WATER: very Xow
                                       REFERENCES
  (a)  Grefco,  Inc.                      	
  (b)  Diamond  Shamrock Corp., 1979.
                                         162
-------
                               SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:  Graboil
•  CHEMICAL NAME OR DESCRIPTION:  polyurethane foam treated to  repel  water

                              0       0
                              fl
•  MOLECULAR FORMULA:
•  FORM:   sheets,  batts,  booms
                                      PROCUREMENT              - ,

•  MANUFACTURER/PROCESSOR:   EBH Cybernetics,  Ltd.,  P.O.  Box 4205,  Postal  Station A
                             Victoria,  B.C., Canada

•  MATERIAL COST ($/LB):
                                       PROPERTIES
•  DENSITY (LBS/FT3):   1.2 (a)

•  DEGRADABILITY:  none

•  TOXICITY:

•  SORPTION CAPACITY (LBS/LB):    20  (b)

•  RETENTION CAPACITY:
;  (g/cm ):  Q.02

 •  FLAMMABILITY:  fair, generates hydrogen
                '  cyanide upon combustion
 •  AFFINITY FOR WATER:   low
   (a)  Robertson,  1978
   (b)  Arthur  D. Little,  1974
                                       REFERENCES
                                        163
-------
                           SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION



•  BRAND OR COMMON NAME:   Ground Rubber




•  CHEMICAL NAME OR DESCRIPTION:   ground cured scrap rubber






•  MOLECULAR FORMULA:
•  FORM:   particles
                                      PROCUREMENT
•  MANUFACTURER/PROCESSOR:   Rubbermaid  Co.
•  MATERIAL COST ($/LB):   0.15  (a)
•  DENSITY (LBS/FTJ):




•  DEGRADABILITY:   low




•  TOXICITY:    none




•  SORPTION CAPACITY (LBS/LB);




•  RETENTION CAPACITY:
                                       PROPERTIES
J  (g/cm >:



 •  FLAMMABILITY:   high
 •  AFFINITY FOR WATER:    very low
   (a)  Robertson,  1978
                                       REFERENCES
                                         164
-------
                              SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:    Imbiber Beads

•  CHEMICAL NAME OR DESCRIPTION:   cross-linked allylstyrene and tertiary butyl
                                   copolymers (a)

•  MOLECULAR FORMULA:
•  FORM:  granules packed in polyolefin fiber bags



                                      PROCUREMENT              -,

•  MANUFACTURER/PROCESSOR:   Dow Chemical Co., 2030 Dow Center, Midland, MI  48460


•  MATERIAL COST (5/LB):    2.65 (b)



                                       PROPERTIES

•  DENSITY (LBS/FT3): 61.3 (b);  40 (c)      ;  (g/cm3): 0.98 (b); 0.64 (c)

•  DEGRADABILITY:   very low                ,  FLAMMABILITY:

•  TOXICITY:    none

•  SORPTION CAPACITY (LBS/L3) :  •   up  to 27 (c)

•  RETENTION CAPACITY:   very high (a)       •  AFFINITY FOR WATER:     very low (a)
                                       REFERENCES
   (a) Akers  et  al.,  1978               	
   (b) Robertson,  1978
   (c) Arthur D. Little, 1974
                                         165
-------
                                SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:  3M Oil Sorbent

•  CHEMICAL NAME OR DESCRIPTION:  polypropylene (b)  or polyethylene (c)  fiber
•  MOLECULAR FORMULA:  -[CHCH3CH2-]
•  FORM:  sheets,  pads,  pillows,  rolls,  sweeps, boons,  granules



                                      PROCUREMENT              -,

•  MANUFACTURER/PROCESSOR:    3M  Company,  3M Center, St. Paul, MN   S5101


»  MATERIAL COST ($/LB): 2.30-4.40  (a)



                                       PROPERTIES

•  DENSITY (LBS/FT3):    3-4  (c)            ; (g/cm ) :   0.05-0.06

•  DEGRADABILITY:  none                      •  FLAMMABILITY:  fair

•  TOXICITY:   none

•  SORPTION CAPACITY (LBS/LB) : benzenes 10.0  (b) ; chloroform: 17.8 (b)

•  RETENTION CAPACITY:                      •  AFFINITY FOR WATER:  very  low (b)
                                       REFERENCES
   (a) 3M Company, 1978                 	
   (b) Akers et al., 1978
   (c) Robertson, 1978
                                         166
-------
                               SORBENT MATERIAL  DATA SHEET
                                     IDENTIFICATION

t  BRAND OR COMMON NAME:   Multipurpose Gelling Agent (MGA)  (302 Imbiber Beads,  30Z Hycar
                           1422, 252 Carbopol 934,  52 Gelgard M, 10Z Cabosil)
•  CHEMICAL NAME OR DESCRIPTION:


e  MOLECULAR FORMULA:
•  FORM:    powder



                                      PROCUREMENT              -,

•  MANUFACTURER/PROCESSOR:   Calspan Corporation,  Buffalo,  NT  14221


•  MATERIAL COST (?/LB):     2.50 (a)



                                       PROPERTIES

•  DENSITY (LBS/FT3):                      ; (g/ca3):

•  DEGRADABILITY:  sensitive to moisture    .  FLAMMABILITY:

•  TOXICITY:

•  SORPTION CAPACITY (LBS/L3):

•  RETENTION CAPACITY:                      •  AFFINITY FOR WATER:
                                       REFERENCES

   (a)  Pilie et *!..  1975
                                         167
-------
                                 SORBENT MATERIAL DATA SHEET
                                      IDENTIFICATION

 •  BRAND OR COMMON NAME:   Oil-Dri

 •  CHEMICAL NAME OR DESCRIPTION:  crushed calcined montmorillonite clay


 •  MOLECULAR FORMULA:    Al2Si4010(OH)2  • xH20




 •  FORM:  granules,  powder



                                       PROCUREMENT              •,

 •  MANUFACTURER/PROCESSOR:    Oil-Dri Manufacturing Co., 520 N. Michigan Ave.,
                              Chicago, IL

 •  MATERIAL COST ($/LB):   0.35



                                        PROPERTIES

 •  DENSITY (LBS/FT3):  30-35              .  ;  (g/cm3):  0.48-0.56

 •  DEGRADABILITY:   none                     •  FLAMMA3ILITY:   none

 •  TOXICITY:  none

 •  SORPTION CAPACITY (LBS/LB): acrylonitrile: 0.7; benzene: 0,7; formaldehyde  (37Z): 0.7;
     aitric  aei- (732): 2.2, phenol  (83Z): 1.2;
     phosphoric  acid (85Z): 2.0              •  AFFINITY FOR WATER:
     •ulfurlc acid  (962): 1.7
	toluene/xylene; 0.8	

                                        REFERENCES

    (a) Temple et al., 1978
                                         168
-------
                                     SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION



•  BRAND OR COMMON NAME:  Oil Mop




•  CHEMICAL NAME OR DESCRIPTION:    polypropylene fiber






•  MOLECULAR FORMULA:      -[CHCHjCH^] Q
•  FORM:    mops,  rope
                                      PROCUREMENT              ;,




•  MANUFACTURER/PROCESSOR:    Oil  Mop,  Inc.,  P.O.  Box P,  Belle  Chasse, LA   70037






•  MATERIAL COST ($/LB):
•  DENSITY (LBS/FT ):    38-57  (a)



•  DEGRADABILITY:   none




•  TOXICITY:    none



•  SORPTION CAPACITY (LBS/LB):




•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/cm ):   0.6-0.9




 •  FLAMMABILITY:   fair
 •  AFFINITY FOR WATER:  very low
   (a) Arthur D. Little,  1974
                                       REFERENCES
                                        169
-------
                                  SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION


•  BRAND OR COMMON NAME:    Oil Snare


•  CHEMICAL NAME OR DESCRIPTION:    polypropylene




•  MOLECULAR FORMULA:      -[CHCE-CH.-]
                            u    32 Jn






•  FORM:    strands
                                      PROCUREMENT              •,


•  MANUFACTURER/PPJOCESSOR:   Parker Systems,  Inc.,  P.O.  Bor 1652,  Norfolk,  VA  23501




•  MATERIAL COST ($/LB):     2.50






                                       PROPERTIES
•  DENSITY (LBS/FT3):  9  (a);  3.2  (b)       ; (g/cm3):   0.14  (a);  0.05  (b)


•  DEGRADABILITY:      none                 •  FLAMMABILITY:    fair


•  TOXICITY:   none


•  SOBPTION CAPACITY (LBS/LB):


•  RETENTION CAPACITY:                      «  AFFINITY FOR WATER:   very low
                                       REFERENCES
   (a)  Robertson,  1978                 	

   (b)  Arthur D. Little,  1974
                                        170
-------
                             SORBENT MATERIAL  DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:   perlite
•  CHEMICAL NAME OR DESCRIPTION:   silica -  volcanic  rock,  crushed  and  heated  to  increase
                                   polarity  and frequently  treated  with a  silicone  to
                                   repel water
•  MOLECULAR FORMULA:   SiO,
•  FORM:   granules
                                      PROCUREMENT      •        -,

•  MANUFACTURER/PROCESSOR: Grefco,  Inc.,  630 Shatto Place, Los Angeles, CA  90005
   MATERIAL COST ($/LB):
•  DENSITY (LBS/FT ):

•  DEGRADABILITY:    none

•  TOXICITY:    none

•  SORPTION CAPACITY (LBS/LB):

•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/cn ):

 •  FLAMMABILITY:   none
 •  AFFINITY FOR WATER:   low
                                       REFERENCES
                                       171
-------
                          SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:  Petro-Trap
•  CHEMICAL NAME OR DESCRIPTION:  polyurethane

                             0      0
                          _   "      »_
•  MOLECULAR FORMULA:   ~"pRQCNHR'NHCjJ-
•  FORM:    pad*  enclosed  in fiberglass membrane
                                      PROCUREMENT              •,


•  MANUFACTURER/PROCESSOR:     Best Textile Co., P.O. Box 157, Westport, MA
•  MATERIAL COST ($/LB):   7.00-12.50/4 ft. section
•  DENSITY (LBS/FTJ):


•  DEGRADABILITY:


•  TOXICITY:


•  SORPTION CAPACITY (LBS/LB):


•  RETENTION CAPACITY:
     PROPERTIES


          ;  (g/cm ) :


          • FLAMMABILITY:





benzene:  18.S (a)


          • AFFINITY FOR WATER:
                                       REFERENCES
   (a) Bauer  et  al.,  1975
                                        172
-------
                               SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   polypropylene

•  CHEMICAL NAME OR DESCRIPTION:     polypropylene
•  MOLECULAR FORMULA:
•  FORM:   sheets,  strands,  powder
                                      PROCUREMENT              -,

•  MANUFACTURER/PROCESSOR:  Dow Chemical  Co.       Phillips Petroleum Co., Plastics Div.
                            2030 Dow Center        P.O. Box 792
                            Midland,  MI   48460     Pasadena, TX   77501
•  MATERIAL COST (S/LB): 0.24 - 0.29
                                       PROPERTIES

•  DENSITY (LBS/FT3):                      ; (g/cm3):

•  DEGRADABILITY: less  resistant  to  chemical*  FLAMMABILITY:   fair
     attack than cross-linked  polymers  such  as  polyurethane
•  TOXICITY:  none

•  SORPTION CAPACITY (LBS/LB):

•  RETENTION CAPACITY:                       •  AFFINITY FOR WATER:  very poor
                                       REFERENCES
                                         173
-------
                          SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
«  BRAND OR COMMON NAME:  polyurethane
•  CHEMICAL NAME OR DESCRIPTION:  polyurethane


•  MOLECULAR FORMULA:
                              0      0
                              II      II
•  FORM:     all forms,  la open-celled,  closed-cell, end non-porous structure
                                      PROCUREMENT

   MANUJACTURER/PMCESSOR:  BASF Wyendotte Corp.
                            Industrial Chemicals Group
                            Wyandotte, MI  48192
   MATERIAL COST (5/LB):
                                                         B.F. Goodrich Chemical Co.
                                                         6100 Oak Tree Blvd.
                                                         Cleveland, OH  44131
•  DENSITY (LBS/FT ):  variable

•  DEGRADABILITY: none

e  TOXICITY:

e  SORPTION CAPACITY (LBS/LB):

•  RETENTION CAPACITY:
                                       PROPERTIES
                                           ; (g/cmJ):

                                            •  FLAMMABILITY:  fair, generates HCK upon
                                                              combustion
                                            e  AFFINITY FOR WATER:  low
                                       REFERENCES
                                         174
-------
                          SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION



•  BRAND OR COMMON NAME:   Quik-Wick




•  CHEMICAL NAME OR DESCRIPTION:   polypropylene fiber,  treated






•  MOLECULAR FORMULA:   -[CHCH.CH.-]
•  FORM:  nats,  pillows,  rolls
                                      PROCUREMENT              -,



•  MANUFACTURER/PROCESSOR:    Clark-Cutler-McDennott  Co.,  1  Fisher  St.,  Franklin, MA   02038
   MATERIAL COST ($/LB):
                                       PROPERTIES
•  DENSITY (LBS/FT-*):   2.8  (a)




•  DEGRADABILITY:  none




•  TOXICITY:   none




•  SORPTION CAPACITY (LBS/LB):  •




•  RETENTION CAPACITY:
;  (g/cm ):  0.04




 •  FLAMMABILITY:  fair
    AFFINITY  FOR WATER:   very low
   (a)  Robertson,  1978
                                       REFERENCES
                                          175
-------
                          SORBENT MATERIAL DATA SHEET
                                      IDEKTIFICATION

 •  BRAND OR COMMON NAME:   SAFESTEP

 •  CHEMICAL NAME OR DESCRIPTION: mixture of volcanic ash and perlite


 •  MOLECULAR FORMULA:
 •  FORM:  powder,   Size No.  1  -  no  more  than  10.6% by weight retained by a 325 mesh screen
                   Size No.  2  -  no  more  than  10Z by weight plus 3Z by weight of binding
	agents retained by a -100 +200 mesh screen	

                                       PROCUREMENT

 •  MANUFACTURER/PROCESSOR:   Andesite of  California, Inc.
                              PO Box 37157
                              Los Angeles,  California  90037
 t  MATERIAL COST ($/LB):
                                        PROPERTIES

 •  DENSITY (LBS/FT3):   137-150              ;  (g/cm3):

 •  DEGRADABILITY:    none                     0  FLAMMABILITY:  non-flammable

 •  TOX1CITY:     non-toxic

 •  SORPTIOS CAPACITY (LBS/LB):   5

 •  RETENTION  CAPACITY:  very  high            •  AFFINITY FOR WATER:  0.297 g/g



                                        REFERENCES


                 Andesite  of California,  Inc.,  1980
                                          176
-------
                           SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   SSC Absorbent DS, SP, SS,  ST
•  CHEMICAL NAME OR DESCRIPTION:    treated polyurethane

                             0      0
                             It      »t
•  MOLECULAR FORMULA:   -{OROCNHR'NHcJ-
•  FORM:   disposable sorbent granules (DS),  sorbent pillows (S?), sorbent sheets (SS),
           sorbent towels (ST)
                                      PROCUREMENT              - ,

•  MANUFACTURER/PROCESSOR:  Sorbent Sciences Corp.. 1269 East Edna Place, Covina, CA  91724


•  MATERIAL COST (S/L3):
                                       PROPERTIES

•  DENSITY (LBS/FT3):  1.7 (b)              ; (g/cm3)'.  0.27

•  DEGRADABILITY:   very low                •  FLAMMABILITY:  fair,  generates HCN on
                                                              combustion
•  TDXIC1TY:

•  SORPTION CAPACITY (LBS/LB):    40-60 (b)

•  RETENTION CAPACITY:                      •  AFFINITY FOR WATER:  low (a)
                                       REFERENCES
   (a)  Akers et al.,  1978              	
   (b)  Arthur D.  Little,  1974
                                        177
-------
                            SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION



•  BRAND OR COMMON NAME:   Slikwlk




•  CHEMICAL NAME OR DESCRIPTION:  cellulose-ground  corn  cobs






•  MOLECULAR FORMULA:
•  FORM:  particles  packed  In 37-lb. polyethylene bags
                                      PROCUREMENT              - ,



•  MANUFACTURER/PROCESSOR:   Slickbar,  Inc., P.O. Box 139, Southport, CT  06490
•  MATERIAL COST ($/LB):
•  DENSITY (LBS/FT ):   8.8  (a)




•  DEGRADABILITY: high




•  TOXICITY:   none




•  SORPTION CAPACITY (LBS/LB):




•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/cm):  0.14




 •  FLAMMABILITY:   high
 •  AFFINITY FOR WATER:
   (a)  Robertson,  1978
                                       REFERENCES
                                         178
-------
                               SORBENT MATERIAL DATA  SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:  Sorbent C

•  CHEMICAL NAME OR DESCRIPTION:    mixture of expanded perlice and cellulose fiber,
                                    created Co repel  water

•  MOLECULAR FORMULA:
•  FORM:  fluffy particles



                                      PROCUREMENT              - ,

•  MANUFACTURER/PROCESSQR:   Clean Water  Inc., P.O.  Box  1002,  Toms  River,  NJ  08753


•  MATERIAL COST ($/LB):



                                       PROPERTIES

•  DENSITY (LBS/FT3):   4.5  (a)             ; (g/cm3):   0.07

•  DEGRADABILITY:   low  (b)                  •  FLAMMABILITY:  high

•  TOXICITY:   none

•  SORPTION CAPACITY (LBS/LB):    8-10  (b)

•  RETENTION CAPACITY:   high (b)            •  AFFINITY FOR WATER:   very low (b)
                                       REFERENCES
  (a) Robertson, 1978
  (b) Arthur D. Little, 1974
                                       179
-------
                       SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION
•  BRAND OR COMMON NAME:   Sorb-Oil
•  CHEMICAL NAME OR DESCRIPTION:   recycled fiberboard

•  MOLECULAR FORMULA:


•  FORM:   oats,  chips,  swabs,  booms
                                      PROCUREMENT              -,
•  MANUFACTURER/PROCESSOR:   Innova Corp., 444 NE Ravenna Blvd., Seattle, WA  98115

•  MATERIAL COST ($/LB):
•  DENSITY (LBS/TT ):
•  DEGRADABIHTY:  high
•  TOXICITY:    none
•  SORPTION CAPACITY (L3S/LB):
•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/cm ):
 •  FLAMMABILITY:  very high
 •  AFFINITY FOR WATER:   high
                                       REFERENCES
                                          180
-------
                            SORBENT MATERIAL DATA SHEET
                                     IDENTIFICATION


•  BRAND OR COMMON NAME:   Spill Control PEP


•  CHEMICAL NAME OR DESCRIPTION:    polyurethane foam

                            0      0
                            tt      If

•  MOLECULAR FORMULA:  -{pROCNHR'NHC}-
•  FORM:  sheets,  pads,  pillows,  strips,  booms
                                      PROCUREMENT              -,


•  MAXUFACTURER/PP.OCESSOR:  Spill Control Co.,  828  North Grand Ave.,  Covina,  CA  91724
•  MATERIAL COST (S/LB):
•  DENSITY (LBS/FTJ):


•  DEGRADABILITY:   none


•  TOXICITY:


•  SORPTIOS CAPACITY (LBS/LB):


•  RETENTION CAPACITY:
PROPERTIES


    5 (s/cm3):


     •  FLAMMABILITY:   falri  generates  HCN on

                        combustion
     •  AFFINITY FOR WATER:
                                       REFERENCES
                                        181
-------
                                 SORBENT MATERIAL DATA SHEET
   BRAND OR COMMON NAME:
                                     IDENTIFICATION

                             vermieulite
•  CHEMICAL NAME OR DESCRIPTION:  clay  mineral,  crushed  and heated  to  increase porosity
                                  and treated to improve sorption

•  MOLECULAR FORMULA:    Mg3Si4010(OH)2  •  x  HjO
•  FORM:    granules  packed  in bags
   MANUFACTURER/PROCESSOR:
•  MATERIAL COST ($/LB):
                                      PROCUREMENT
                                       PROPERTIES
                                           ;  (g/cm ):  0.07

                                            •  FLAMMABILITY: none
•  DENSITY (LBS/FT3):   4.5  (b)

•  DEGRADABILITY: none

•  TOXICITY:   none

•  SORPTION CAPACITY (LBS/LB):  perchloroethylene:  3.5  (a);  phosphoric  acid (85Z):  6.5 (a)

•  RETENTION CAPACITY:                      •  AFFINITY FOR WATER:
                                       REFERENCES
   (a) Diamond Shamrock Corp., 1979.
   (b) Robertson,  1978
                                        182
-------
                                SORBENT MATERIAL DATA  SHEET
                                     IDENTIFICATION

•  BRAND OR COMMON NAME:   Winkler Foam

•  CHEMICAL NAME OR DESCRIPTION:  mixture of  polystyrene beads  and  polyurethane  chips  or
                                  rubber fibers

•  MOLECULAR FORMULA:
•  FORM:  mixture of  beads  and chips  or fibers
•  MANUFACTURER/PROCESSOR:
•  MATERIAL COST ($/LB):
                                      PROCUREMENT
•  DENSITY (LBS/FT ):  1.5  (a)

•  DEGRADABILITY:  none

•  TOXICITY:

•  SORPTIOS CAPACITY (LBS/LB):

•  RETENTION CAPACITY:
                                       PROPERTIES
;  (g/cm ):   0.02

 •  FLAMMASILITY:   fair
 •  AFFINITY FOR WATER:   very low
   (a)  Robertson,  1978
                                       REFERENCES
                                         183
-------
                                 SORBENT MATERIAL  DATA SHEET
                                     IDENTIFICATION



•  BRAND OR COMMON NAME:   Zorbite




•  CHEMICAL NAME OR DESCRIPTION:  expanded and  treated silicate glass






•  MOLECULAR FORMULA:
•  FORM:  granules
                                      PROCUREMENT
•  MANUFACTURER/PROCESSOR: Spill Control Co., 828 North Grand Ave., Covina, CA  91724






c  MATERIAL COST (S/LB):
                                       PROPERTIES
   DENSITY (LBS/FT1): 9  (a)




   DEGRADABILITY: none



   TOXICITY:  none




   SORPTION CAPACITY (LBS/LB):




   RETENTION CAPACITY:
;  (g/cm ):   0.14



 •  FLAMMABILITY:   none
                                            •  AFFINITY FOR WATER:
                                       REFERENCES
   (a) Robertson,  1978
                                         184
-------
                                     TECHNICAL REPORT DATA
                             (Please read Instructions on the reverse before completing)
 1. REPORT NO.
                               2.
                                                              3. RECIPIENT'S ACCESSION>NO.
4. TITLE AND SUBTITLE

      Sorbent Materials  for Cleanup  of Hazardous Spills
                                                              5. REPORT DATE
                                                              6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

      E.  C.  Herrick,  D.  Carstea, G.  Goldgraben
              8. PERFORMING ORGANIZATION REPORT NO.

               MTR80W194
9. PERFORMING ORGANIZATION NAME AND ADDRESS

      The MITRE Corporation
      1820 Dolley Madison Blvd.
      McLean, VA   22102
                                                              10. PROGRAM ELEMENT NO.
              11. CONTRACT/GRANT NO.
                68-01-5051
12. SPONSORING AGENCY NAME AND ADDRESS
     Municipal Environmental Research  Laboratory
     Office of Research & Development
     Environmental Protection Agency
     Cincinnati, OH     45268
              13. TYPE OF REPORT AND PERIOD COVERED
                Final         	
              14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES

      Project Officer - Marshall Dick
16. ABSTRACT

      This report reviews the state-of-the-art of. sorbent materials  for cleanup  of
 hazardous  liquid spills.   The pertinent characteristics of 90 hazardous liquids
 and  a matrix is provided to indicate the tested  and anticipated  compatibilities
 between the liquids  and sorbents.   Some conclusions are drawn about the state-of-
 the-art and the suitability of various sorbent  types.   A comprehensive testing
 program is recommended.
17.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                   DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c.  COSATI Field/Group
 Sorbents
 Compatibility
  Cleanup of hazardous
    liquid spills
      11/G
18. DISTRIBUTION STATEMENT
                                                19. SECURITY CLASS (ThisReport)
                            21. NO. OF PAGES

                                 193
                                                20. SECURITY CLASS (This page)
                            22. PRICE
EPA Form 2220-1 (9-73)
                                            185
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