PB   230  379

SONOMA  COUNTY  SOLID  WASTE  STABILIZATION
STUDY

EMCON  Associates
Prepared  for:

Environmental  Protection Agency

1974
                               DISTRIBUTED BY:
                               National Technical Information Service
                               U. S.  DEPARTMENT  OF  COMMERCE
                               5285 Port Royal Road, Springfield Va. 22151

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  BIBLIOGRAPHIC DATA
  SHEET
                    1. Report No.
EPA-SV-$30-65d
                                  PB   230   379
 4. Title and Subtitle
   Sonoma County  Solid  Waste  Stabilization  Study
                                    5- Report Date
                                    	1974
                                                                 6.
 7. Author(s)

   F.MCON Associates
                                    8- Performing Organization Kept.
                                      No.
 9. Performing Organization Name and Address
   EMCON Associates
   326  Commercial  Street
   San  Jose,  California
                                    10. Project/Task/Work Unit No.
                                    11. Contract/Grant No.

                                     G06-EC-00351
 12. Sponsoring Organisation Name and Address
   U.S.  Environmental  Protection  Agency
   Office of  Solid  Waste Management Programs
,'  Washington,  D.C.  20460
                                    13. Type of Report & Period
                                      Covered

                                      Interim
                                    14.
 15. Supplementary Notes
 16. Abstracts
   This  report documents  the  first  2 years of a  3-year  demonstration
   projected  sponsored  by EPA and  Sonoma County,  Calif.   The  purpose  of
   the  project is  twofold:   (1) to  investigate the stabilization  of solid
   waste in a sanitary  landfill by  analyzing  leachate,  gas,  temperature
   and  settlement  parameters,  and  (2)  to determine the  effect on  solid
   waste stabilization  of applying,  under various  operational modes,  exces
   water,  septic  tank pumpings, and recycled  leachate  in a  sanitary land-
   fill.   This report describes the investigation  of  the test site,
   construction,  instrumentation,  and  site operations  and discusses the
   data  produced  thus far through  extensive monitoring.   Tables and figure
   following  this  report  summarize  the  detailed  data  presented in  the
   appendi ces.
 17. Key Words and Document Analysis.  17a. Descriptors

   Landfill,  Leachate,  Septic  Tank,  Water
 17b. Identiflers/Open-Knded Terms
   Test  Cell,  Solid  WAste
       .TI Field/Group
                                   Reproduced by
                                    NATIONAL TECHNICAL
                                    INFORMATION SERVICE
                                    U S Department of Commerce
                                       Springfield VA 22151
*y Statement
19. Security Class (This
Report)
UNCLASSIFIED
20. Security Class (This
Page
UNCLASSIFIED
21. No. of Pages
%%•£>
22. Price
/4-sr>

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               NOTICE



THIS DOCUMENT HAS BEEN REPRODUCED PROM



THE BEST COPY FURNISHED US BY THE SPONSORING



AGENCY. ALTHOUGH IT IS  RECOGNIZED THAT CER-



TAIN PORTIONS ARE ILLEGIBLE,  IT IS BEING RE-



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AS MUCH INFORMATION AS POSSIBLE.

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               l\
     SOHOMA COUHTY SOLID «ASTE STABILIZATION STUDY
This interim report  (SW-65d)  describing  work performed
    for the Federal  solid waste  management program
      under demonstration grant  Nd.  G06-EC-00351
             to  Sonoma  County,  California
            was  written by  EMCON ASSOCIATES
    and is  reproduced  as received from the grantee
            U.S. ENVIRONMENTAL PROTECTION  AGENCY
                             1974
                               I

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Tliis report //j.v been reviewed by the U.S.  Environmental Protection
Agency and approved for publication. Approval docs not signify that
the contents necessarily reflect the views  and policies of the U.S.
Environmental Protection Agency, nor does mention of commercial
products constitute endorsement  or recommendation for use by the
U.S. Government.

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                         TABLE OF CONTENTS
                                                            PAGE

I.         INTRODUCTION                                        1

II.       GEOTECHNICAL INVESTIGATION                          3

III.      PROJECT CONSTRUCTION                                7

IV.       INSTRUMENTATION                                    13

V.         REFUSE COMPOSITIONAL ANALYSIS                      14

VI.       OPERATIONS AND MANAGEMENT                          17

VII.      MONITORING PROGRAM                                 19

VIII.      DISCUSSION                                         22

               REFUSE COMPOSITION                            22

               SAMPLING AND ANALYTICAL METHODS               23

               REFUSE STABILIZATION                          26

               GROUNDWATER ANALYSIS                          40

TABLES

          1.   Liquid Conditioning and Purpose of Cells       41
          2.   Refuse Moisture Content Summary                42
          3.   Refuse Composition Summary                     43
          4.   Composition of Refuse                          44
          5.   Solution Analysis                              45
          6.   Cell C Leachate - Electro-Conductivity/        46
                Parameter Ratios
          7.   Cell D Leachate - Electro-Conductivity/        48
                Parameters Ratios
          8.   Companion Thermister Comparison                50
          9.   Trace Metal Concentrations in Leachate-        51
                Cells A, B, & E
         10.   Trace Metal Concentrations in Leachate-        52
                Cell  C
         11.   Trace Metal Concentrations in Leachate-        53
                Cell D
                                                                  •	t	

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FIGURES
                                                   PAGE
     1 .
     2
     3
     4
     5
     6
     7
     8
     9
    10
    11
    12
    13
    14.

    15,

    16.
    17,
    18.
    19.
    20.
    21 .
    22.
    23.
    24.
    25.
    26.
    27.
    28.
    29.
    30.

    31 .

    32.
    33.
    34.

    35.

    36.
Locati on Map
Geologi c Map
Exploration Map
Field Density Test Location Map
Site  Plan (as Built)
Section  A-A, Site Plan
Section  B-B, Site Plan
Clay  Barrier
Typical  Instrumentation Location Plan
        Alkalinity vs. Time - Cells A-E
        Volatile Acids vs.  Time - Cells A-E
        B.O.D.  vs. Time - Cells A-E
        C.O.D.  vs. Time - Cells A-E
        Total Dissolved Solids vs.  Time - Cells
     of
     of
     of
     of
     of
     of
     of
     of
Plot
Plot
Plot
Plot
Plot
  A-E
Plot of
  A-E
Plot of
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
Plot
  B
        Electro-Conductivity vs.  Time - Cells
        Chloride vs. Time - Cells A-E
        Sulphate vs. Time - Cells A-E
        Phosphate vs. Time - Cells A-3
        Nitrate vs. Time - Cells A-E
     of Nitrogen-Ammonia vs. Time - Cells A-E
     of Nitrogen-Organic vs. Time - Cells A-E
        Sodium vs.  Time - Cells A-E
        Potassium vs. Time - Cells A-E
        Calcium vs. Time - Cells A-E
        Magnesium vs. Time - Cells A-E
        ph vs.  Time - Cel1s A-E
        Iron vs. Time - Cells A-E
        Fecal Coliform vs. Time - Cells A-E
        Fecal Streptococci vs.  Time - Cells A-E
        Cumulative  Leachate Production - Cells A,
        E
Plot of Cumulative  Water Distribution & Leachate
  Collection-Cell  C
Flui d Routing - Cel1
Fluid Routing - Cell
Plot of Temperature
  Cells A-E
Plot of Temperature
  Cell  A
Plot of Temperature
  Cell  B
Plot of Temperature
  Cell  E
plot of Temperature
  Cell  C
     °f Temperature
     of
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    and
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- All
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Cell
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rmi ster,
sters ,
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s
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ters
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9

                      ells  A-E
54
55
56
57
58
59
60
61
62
63
63
64
64
65

65

66
66
67
67
68
68
69
69
70
70
71
71
72
72
73

74

75
76
77

77

78

78

79

79

80
81

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APPENDICES                                                  PAGE
     A.   Field Exploration and Laboratory Testing            82
     B.   Test Cell  Construction Data                         93
     C.   Clay Barrier Construction Data                     102
     D.   Instrument Details                                 105
     E.   Refuse Compositional  Data                          112
     F.   Monitoring Schedules                                124
     G.   Analytical Methods and Procedures, etc.            131
     H.   Monitored  Data                                     157"
     I.   Test Cell  Refuse Placement History                 218
BIBLIOGRAPHY                                                 224

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                              PREFACE
     Sanitary  landfilling  involves  (1)  the placement of  refuse  In  a
manner which will not degrade the  1and-water-aIr environment of  the
disposal site,  (2) the compaction  of  the  refuse to  the smallest  prac-
tical volume,  (3) the daily covering  of the  refuse  with  a  layer  of
earth and  (k)  the performance of disposal operations without creating
nuisances  or hazards to the health  and  safety of the surrounding com-
munIty.
     Once  disposed of in a sanitary  landfill, the refuse presents  a
potential  source of pollution for  a  period of 10's  to  100's of  years.
The introduction of large quantities  of water into  the sanitary  fill
either by  acts of nature such as floods and  rising  groundwater  or  by
negligence of  man through  inadequate  grading, drainage,  or maintenance
of the earth cover can release pollutants from  the  decomposing  refuse
to contaminate the groundwater and  surface waters.
     The study discussed in this report was  conceived  to test the  hypo-
thesis that stabilization of refuse  in  a  sanitary landfill can  be  ac-
celerated  by the controlled application of water thereby reducing  the
period of  time during which the landfill  presents a potential source
of pollution and the risk that such  pollution might occur.
     The stabilization of household  refuse in a sanitary landfill  is
being investigated in five large-scale,  field test ce11s.   The refuse
in the test cells is subjected to  various moisture  conditions and  med-
iums  through the controlled application of excess water, septic  tank
pumpings and recycled leachate   The  stabilization  of  the  refuse is
measured by monitoring and analysis of  leachate, gas temperature and
settlement of  the sanitary landfill,,  In  addition,  the groundwater in
the vicinity of the test cells is  tested  periodically  to detect  any
significant change of groundwater  quality.
     This study is funded principally by  the Environmenta1'Protection
Agency under Demonstration Grant No.  G06-EC-00351  of the EPA Office of
                                 vi

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Solid Waste Management Programs.   Partial  funding of the 3 year de-
monstration project is provided by the County of Sonoma, Project Spon-
sor.

                         Project  Management

          Mr.  Donald B.  Head,  Director of  Public Works,  County of Son-
oma is Project Director.   All  project activities are directly supervised
by the Assistant Director of Public Works  for Sonoma County,  Mr. Duane
Butler.   Project Engineer assisting Mr.  Butler is Mr.  Johnny  Conaway.
          Emcon Associates,  Consultants  in Waste Management,  provides
technical direction and  input  to  the project, as well  as the  laboratory
testing  and analysis.   Their services are  under the direction of Pro-
ject  Manager,  Mr. John G. Pacey.   Dr. James Leckie of  Stanford Univer-
sity  provides  bio1ogica1-chemica1  consulting expertise through Emcon
Assoc i ates .

                            Acknow1edgmen ts

          Among those  who contributed significantly to the study were
the staff of the Environmental  Protection  Agency in Cincinnati, Ohio;
the State of California  Department of Public Health; the State of Calif-
ornia Department of Water Resources; the County of Sonoma Sanitation
Department; and students  of  Sonoma State College and Santa Rosa Com-
mun i ty College.
                                     vn

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                           I  - INTRODUCTION
     The investigation which forms the subject of this report was
authorized under a three-year demonstration grant project sponsored
by EPA and the County of Sonoma, California.  The purpose of the pro-
ject is twofoId:
     1..  To investigate the stabilization of refuse in a sanitary
         landfill by analyzing  leachate, gas, temperature and
         settlement parameters.
     2.  To determine the effect on refuse stabilization of applying,
         under various operational modes, excess water, septic tank
         pumpings and recycled  leachate to a sanitary  landfill.
     The stabilization of refuse is monitored in five  instrumented
field scale test cells.  Each test cell is subjected to a different
controlled moisture condition and/or liquid character.  The liquid
conditioning and purpose of each cell  are set forth in Table 1.
     This report documents the  site investigation, construction, in-
strumentation and site operations and  presents and discusses data gen-
erated during the initial two years of the three-year demonstration
g ran t p roj ect.
     The work completed to date was conducted jointly by the staffs
of Sonoma County Department of  Public  Works and Emcon Associates, the
County's consultant,  and includes the  following:
     1.  Geotechnical investigation of test site.
     2.  Construction and instrumentation of clay barrier.
     3.  Design and construction of five field scale refuse test cells
         and various  monitoring instruments and facilities  for distri-
         bution, collection and storage of leachate and water added to,
         or withdrawn from the  test cells.
     k.  Compositional analysis of refuse placed in the test cells.
     5.  Monitoring of refuse stabilization parameters, including
         leachate and gas composition, temperature and settlement.

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     6.  Monitoring of selected groundwater parameters to determine
         the effect of the project on the quality of the groundwater.
     7.  Development of leachate and gas sampling and analytical pro-
         cedures .
     During the first six months of the study, the geotechnical investi-
gation of the test cell area was accomplished, the test cells were con-
structed, refuse placed, and the cells were covered.  From that time
data has been collected on a scheduled basis concerning refuse settle-
ment, cell temperatures, gas composition and leachate composition, as
well as external parameters concerning groundwater quality.    Mean temp-
erature, rainfall, evaporation, storm runoff and quantity of liquid
added to and withdrawn from each demonstration test cell are also mon-
i tored.
     The first two years of the study were completed in accordance with
the methodology and scope of work set forth in the demonstration appli-
cation.  It is expected that the third year program will follow the same
pattern and that trends now becoming apparent will continue during the
forthcoming year.
     Discussion presented in this report follows the sequence  in which
the activities occurred, namely the first portions of the report de-
scribe the geotechnical investigation and construction activities follow-
ed by a discussion of instrumentation, compositional analysis of the  re-
fuse, pertinent operations and management procedures and the monitoring
program.  The main thrust of this report is a discussion of refuse stab-
ilization as measured by extensive monitored data.  Tables and figures
following the text of this report summarize the detailed data presented
in the append i ces.
     Readers wishing to examine closely the quantitative data will find
this information in the appendices following the main body of  this report

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           II - GEOTECHNICAL  INVESTIGATION - TEST CELL AREA
Scope of Work
     The initial work element for the demonstration grant was a geo-
technical Investigation of the test cell area located within the Cen-
tral Disposal Site in Sonoma County, California.  The purpose of the
investigation was (1) to determine the material types and conditions
underlying the test cell area, (2) to determine the suitability of the
site for the proposed use, and (3) to prepare appropriate recommend-
ations concerning the geotechnical aspects of the research program.
     The scope of work completed  in this investigation included a
surface and subsurface investigation, a review of geologic and engi-
neering data, laboratory testing of selected soil samples to determine
the pertinent physical and mechanical properties of the foundation
materials,  and the evaluation of this data to determine the suit-
ability of the area for the intended program.

S i te Descr i pt i on

     The Central Disposal Site is located in the southwestern portion
of Sonoma County, approximately *»5 road miles north of San Francisco,
California.  (See Figure 1)  The site consists of approximately kQQ
acres of sparsely-wooded grazing land in the well-rounded foothills
of the Northern Coast Range.   It is located well away from the path
of urbanization, within a relatively short travel distance of central
service areas.  An improved all-weather road leads to the large cen-
tral canyon.   This canyon will provide capacity for disposal of solid
waste generated in Sonoma County well beyond the year 2000.
     An area for the test cells was selected about midway up the cen-
tral canyon  in a relatively flat portion of the valley, just east of
the main drainage channel, (see Figure 2.).   A small  tributary drain-
age channel  passes through the test cell area bisecting it approxi-
mately in half, with three cells located to the north and two to the

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south of the tributary channel.
     Placement of sanitary fill at the Central Disposal Site commenced
in the main canyon just above  (north) the test cell area.  Landfilllng
will proceed up the canyon away from the test cells.  The test cell area
should therefore be available  for uninterrupted research activities for
many years to come.

Geology

     The Central Disposal  Site is underlain primarily by marine sedi-
ments of the Franciscan Formation, (see Geologic Map, Plate 2).  These
Jura-cretaceous rocks consist of sandy clayey shale with interbedded
sandstones and silicic chert beds.  Geologic structure in the Francis-
can Formation sediments is extremely complex reflecting a turbulent his-
tory of faulting, folding  and shearing.  The trend of this bedrock sys-
tem is generally northwest-southeast through the Northern Coast Ranges
of Callforn i a.
     The surface and near-surface deposits within the valley protions of
the site contain relatively thin deposits of poorly-consolidated sedi-
ments of younger Merced Formation.  The Merced Formation rocks are of
P1io-Pleistocene Age and consist essentially of gravelly sandstones with
interbeds  of sandy clay and silt.  The basal portion of the Merced For-
mation contains a zone of  we 1 1-indurated impervious volcanic tuff breccia
Sediments  of the Merced Formation have been deposited on an old erosion
surface (valley) of the underlying older Franciscan Formation.  The poor-
ly-consolidated sediments  of the Merced Formation are relatively undis-
turbed as  indicated by their near-horizontal attitude and uninterrupted
con t i nu i ty.

Subsurface Exploration

     Five  exploration trenches were excavated in the test cell area in or
der to examine foundation  soil types and conditions and thereby determine
the most suitable location for the cells from the standpoint of geology.

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The locations of the trenches are shown on Figure 3 and the  logs of
soils encountered  in the trenches are presented  in Appendix  A.   In gen'
eral, the materials encountered  in the excavation were comprised of
sandy and sllty clays and clayey sands.  Some gravel was encountered
in each trench and free water was observed in trench k.

Gi roundwater

     Sedimentary rocks of the Franciscan formation are considered to
be essentially barren of fresh water.  Locally,  however, these well-
consolidated rock units contain  small supplies of poor to fair quality
water which is used for domestic and stock water supply.  The more
successful low-yield wells tap water supplies in deeply-weathered or
high1y-fractured rock.  These marginal supplies  of poor quality water
do not constitute a protectable  resource.  Sediments of the  Merced
Formation contain groundwater of moderate to high quality in the more
pervious strata.   This water is  contained in beds of sand, lenses of
gravels and occasionally in lenses of permeable  volcanic rock.
     Groundwater was encountered in thin beds of clayey sand and gra-
vel just above the basal tuff breccia in each of the drill holes in
the canyon bottom areas.  This aquifer ranged in thickness from two
to ten feet and occurred from 15 to 25 feet below ground surface.
The groundwater encountered in this formation was confined by over-
lying clays of low permeability  and artesian pressure heads  ranged
from ten to nearly twenty feet in exploration drill holes.   Product-
ion capacities from wells in this thin stratum are estimated to be
marginal, but known hydraulic continuity between this aquifer and
major production  aquifers to the south established the absolute need
to prevent pollution of this aquifer by harmful   materials originating
i n the refuse f i1 I .
     In addition  to the subsurface groundwater,   at least one perennial
and two intermittent springs exist in the large  canyon at the upper
end of the Central  Disposal  Site.  The backhoe investigation in the
test cell area revealed little groundwater within twelve feet of the
ground surface.

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Laboratory Investigation

     Representative soil samples recovered from the exploration trenches
were tested in the laboratory to determine their physical and mech-
anical characteristics-  Test data are presented in Appendix A.  Based     *"
on the results of these laboratory tests, It was concluded that the
clay soils possess a permeability of less than one foot a year and soils   —
excavated for construction of the test ce1Js can be readily recompacted.

Conclus 5 ons
     Based on the results of the field and laboratory investigation,
we determined that the test cell area was suitable for the research
test cells.  It was decided that excavations for construction of the
test cells should terminate within the upper sandy clay and clayey sand
materials of low permeabi1ity„   Application of this criteria, tempered
by drainage considerations  and evaluation of the cut-and-fill material
balance, resulted in the siting of the test cells at the locations
shown on the plans.
     The nativ* soils in their existing state were considered generally
satisfactory for retaining  any leachate developed during excavation of
the test cells.  Occasional  lenses or layers of more previous water-
bearing soils were expected in the cell excavations.  Such areas were
to be over-excavated two feet and an impervious clay lining was to be
placed to restore the test  ceils to design grade,  Material generated
from excavation of the cells was considered suitable for construction of
the embankment portion of the test cells.  The resulting test cells
would thus be relatively impervious and capable of retaining leachate
and gas.

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                     I I I-PROJECT CONSTRUCTION

     Project construction generally proceeded as originally de-
signed and presented on the drawings which accompanied  the demon-
stration grant application.  However, some design modifications
were made during construction to meet changed conditions and  re-
flect additional decisions.  Final construction details are shown
on Figures 5, 6 and  7  "As Built" drawings.

CELL CONSTRUCT I ON

Excavat i on
     The test cells were excavated to design grade and  the material
removed was stockpiled adjacent to the cells.
     Some groundwater was encountered in  the excavation of Cells A
and E.  As a consequence, the subsurface  drains above Cell A  and E
and above Cells  B through D were installed prior to construction of
the embankment.
     After excavation  to design grade, the ground surface was  Inspect-
ed to determine  the presence of any pervious lenses within the cell
configuration.  A thin zone of pervious material was encountered in
Cells A and E.  This material was removed by ove r-excava 11 rvg  two
feet.  This area was then restored to design grade with a two-foot-
th5ck layer of compacted clay.

Embankment
     The  embankment areas of the test cells were first  stripped of
all surface organic matter.  The ground surface was then scarified
and compacted.  The stockpiled material  from cell excavation  was
utilized  as embankment fill and was placed in lifts of  six inch  un-
compacted thickness.  The lifts were moisture conditioned as  neces-
sary to achieve  proper compaction and compacted by numerous passes

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of a 5 x 5 sheepsfoot compactor drawn by a D-7 tractor and a Buffalo
Springfield steel wheeled compactor*
     Field density tests were taken during the placement operation to
determine the relative compaction of the embankment materials.  Results
of the field density tests and laboratory control curves are presented
In Append i x B.
     When the downhill embankment had been constructed to a level two
feet above the floor of the cell, trenches for the leachate collection
lines were excavated in the bottom of the cell and a trench was exca-
vated through the embankment for the leachate line discharging to the
collection tank.   Leachate collection lines were placed in the trenches
and backfilled.   The trench through the embankment was backfilled with
a  combination of native soil and 10% bentonite, by weight, in order to
assure an impervious backfill.  The embankments were then raised to de-
sign grade.   A shallow trench was excavated on the inside slope from
the top of the embankment to the base of the cell for installation of
th«* lysimeter and gas collection lines.

Leachate Collection System

     After the cells were excavated and graded and the embankments had
been constructed to an elevation two feet above the base of the cells,
trenches were excavated in the base of the cells and through the em-
bankments for placement of the leachate collection lines.  Pea gravel
was placed around the collection lines in Cell C and D.
     All collection tanks were positioned below the test cells with the
top of tank below the base of the test cells, thereby assuring positive
drainage of leachate into the collection facilities.
     In Cells A and E a single leachate collection line was installed
across the lower (west) side of the base as only a small quantity of
leachate was expected.   A full system of leachate collection lines was
installed in Cells B through D to collect the large quantities of leach-
ate expected from these cells.  Cell B was expected to develop a consid'
erable quantity of leachate only during the initial charging to field

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capacity.  Nevertheless, the quantity expected was such  that a  full
collection system was  installed.

Refuse

     Refuse was initially dumped at the edge of the cell and then
pushed into the cell and spread by a D-? dozer.  The dozer compacted
the refuse in a manner similar to the procedures that would be  used
in the normal sanitary landfill operation.
     All  incoming refuse was weighed.  Samples of the refuse were
obtained  for compositional  analyses in accordance with accepted stat-
istical sampling methods.  The samples were hand sorted  into approp-
riate waste categories in a covered work area within five miles of
the j ob site.

G r a n u1 a r  Materials

     Granular materials were used as backfill in the leachate collec-
tion trenches and for distribution material between the  distribution
lines and refuse in Cell C  and D.  Mechanical analyses of potentially
suitable  materials were performed prior to cell construction  (See
Appendix  B).  Concrete sand  and muck sand from Basalt were accepted
for the silty sand and concrete sand requirements.   Pea  Gravel was
substituted for the proposed fine soil backfill material on leachate
collection lines in Cells C and D and for material  placed between re-
fuse and  distribution lines in Cell D.  This substitution was made to
avoid the filtering action  that might occur when leachate passes
through f i ne so i1.

Cover Mate r i a 1
     Cover material generally consisted of the stockpiled sandy clay
material from cell excavation   The cover material was placed as a
two-foot capping over the refuse in Cells A, B and E.  A one-foot thick-
ness of permeable material was placed between the refuse and sandy clay

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cover in Cell C and D to facilitate distribution of water and leachate.
In Cell  C this one-foot of material consisted of a layer of fine si1ty
sand placed directly overlying the refuse.  A six-inch mound of concrete
sand was placed around the liquid distribution lines installed be-
tween the si I ty sand and cover material.  A 12-inch layer of pea gra-
vel (in  lieu of si1ty sand) was placed between the refuse and cover
material in Cell D to minimize any filtration of leachate.
     Tiie sandy clay was spread in one-foot lifts and compacted by num-
erous passes  of a D-7 dozer.   Two-inch-dIameter holes were augered
through  the cell cover at  intervals of 10  feet to permit measurement
of the in-place thickness of  cover material.   The cover thickness
measurements  for all cells are presented in Appendix 8.

Leachate Distribution System

     As  previously mentioned, a twelve-inch layer of pea gravel  was
placed over the refuse in Cell D in lieu of the originally planned fine
si1ty sand spreading medium.   Elimination  of  the spreading medium neces-
sitated  further changes in the distribution system for Cell D to assure
uniform  application of recycled leachate over the refuse.  The changes
consisted of the installation of two separate leachate distribution
systems  utilizing eight lines each with lines more closely spaced than
the originally planned eleven line system.  The decreased total  foot-
age in each system made necessary an increase in the size of the small
discharge holes to maintain planned distribution rates.  This had the
side benefit  of reducing the  potential  for plugging of the holes by  so-
lids in  the leachate.

Clay Barrier  Construction

     An  impervious  clay barrier was constructed across the lower end  of
the central canyon,  below  (south) of the test cells and central  disposal
areas, to block the subsurface escape of leachate and gases which might
emanate  from the sanitary  landfill and test cells.   See Figure 8 for  max-
imum cross section.

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     Native sandy clay soils were excavated to bedrock  in preparation
for construction of the barrier.  Conditions encountered  in the ex-
cavation were as originally estimated with the maximum  depth of ex-
cavation being 30 to 35 feet below the valley floor or  approximately
20 to 25 feet below the canyon creek channel.  The excavation was
inspected by Mr. Jack McCollough, the Engineering Geologist involved
in the original  investigation of the valley, and Mr. John Pacey,
Consulting Engineer for the construction phase of the grant project.
     A sump was excavated at the low point of excavation on the
downstream side of the barrier excavation and backfilled with granular
material.  A perforated pipe was installed in the sump  and extended to
the natural ground surface to permit future removal of  seepage waters
collected in the drainage blanket, if required.
     The barrier was constructed by backfilling the excavation with
sandy clay soil obtained from the excavation.  The fill material was
spread by a D-8 Caterpillar Tractor in relatively thin  lifts which
were moisture conditioned as necessary to permit achievement of the
required relative compaction and compacted by numerous  passes of a
5x5 Sheepsfoot roller drum pulled by a TD-24 tractor.  A sand drain-
age blanket was placed between the downstream face of the clay barrier
and natural ground.
     A moisture-density curve was developed in our laboratory to est-
ablish relative compaction parameters for the backfill  material in
accordance with ASTM Test Designation D698-70.  Field density tests
were performed periodically during the filling operation at random
locations.   Test methods utilized included both the sand cone method
(ASTM Test Designation D 1556) and the nuclear density  test method
(ASTM Test Designation D 2922-71).  The field density test results and
laboratory compaction curve are presented in Appendix C.
     The barrier was constructed up to a point slightly above the
stream channel elevation under the inspection and testing control of
Mr. James Cleary of Emcon Associates.   County personnel directed and
inspected the placement of additional  fill required to  raise the grade
up to the natural ground surface and to provide an aesthetically-
pleasing finish ground surface.   No tests were performed on this final
                                   1 1

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10 feet of fill, as this work was principally for aesthetic purposes
Nevertheless, precautions were taken by County Staff to assure that
the material was properly moisture conditioned and compacted.
                                      12

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                         IV - INSTRUMENTATION
     Stabilization of the refuse is monitored by instruments installed
in the test cells and by testing of leachate and gas samples withdrawn
from the cells at programmed intervals.  Instrumentation installed
for refuse stabilization data retrieval include gas probes, thermistors,
settlement monuments and leachate collection facilities.
     Evaporation, rainfall  and Cell runoff data necessary to evaluate
rainfall infiltration into the test cells, are recorded respectively
by an evaporimeter,  rain gauge and two flow meters.  Additional flow
meters connected at  appropriate locations in the collection, discharge
and distribution piping, record the daily application of water to Cell
C and makeup water applied to Cell D,  as well as the quantity of leach-
ate produced by Cells C and D.
     Instrumentation for obtaining groundwater samples and measuring
its quality include  observation wells  installed downh ill and uphill
of the test cells and up-valley of the clay barrier, and lysimeters
installed below each test cell.  Groundwater levels within and be-
neath the clay barrier are monitored by piezometers.
     Instrument locations and identification symbols used in recording
data developed are shown on Figure 9.   Detailed drawings of the in-
struments utilized are presented in Appendix D.
                                   13

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                 V - REFUSE COMPOSITIONAL ANALYSIS
     The composition and moisture content of refuse placed in the
test cells was determined by analyzing refuse samples selected by
statistical sampling methods.  The sampling schedule was derived
by use of Random Sample numbers, as noted and shown on Plate E-I .

Sample Procurement Procedure

     The weigh master marked the refuse trucks containing refuse to
be sampled as it left the scale.  Trucks marked for sampling were
directed by the traffic dispatcher to deposit its load of refuse
adjacent to the designated cell.  A front loader scooped 300 or more
pounds of refuse at random from this pile and loaded it into the bed
of a pickup truck.  The sample was then enclosed in a canvas tarp
and transported to the sorting center which was located about 5 miles
east in the county road maintenance yard at Cotati.
     The sample was removed from the truck, placed on a thick black
plastic ground cloth and sorted.  Forty-two part-time employees, prim-
arily students from Sonoma State College and Santa Rosa Community Col-
lege, were employed to sort the refuse samples.  Ten labelled 32-gal-
lon trash cans with plastic liners were positioned around the sample.
Two to six students classif5ed, segregated and deposited the material
in the trash cans.  Approximately 10. man-hours were required to sort
a sample.  The material was sorted into the following 10 categories:
     1.   Food Waste
     2.   Garden Waste
     3.   Paper
     k.   Plastics, Rubber, Leather
     5.   Text i les
6.
7.
8.
9.
0.
Wood
Metals
Glass
Ash , Rock ,
Fines



Di rt


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     After the sample was  sorted, all cans  in each  category were
weighed and  recorded.  The  total weight of  waste  In each  category  is
presented on Plates  E2-E6.

Sorting Guidelines

     1.  Synthetic material was classified  as a plastic.
     2.  F i ne s were  defined as any material  that  would pass through
         a 1" sieve.  No further classification was attempted.
     3.  Wood was wood material that had been processed at a mill,
         i.e., a 2x4 was classified as wood, but  a  tree limb or
         branch was  classified as garden waste.
     k.  Food wastes included:  bones, shells, feathers,  and fecal
         material.   Food wastes were scraped out  of their containers
         and the container  deposited into its appropriate category.
     5.  Labels were left on containers.

Moi s tu re De te rm inat ion

     Samples  of segregated  refuse are bulky, take a long  time to dry and
generate an obnoxious odor while drying.  Therefore, the  small capa-
city ovens of the Sonoma County Soils Lab were not adequate to handle
the large number of  samples obtained.  County staff therefore designed
and built two drying racks  that could hold  16-2 feet x k  feet X 6  inch
deep sheet metal trays.   The racks were enclosed  with sheet metal  and
heated by a propane-fired forced air heater.  This system maintained
a relatively  constant temperature of 105° F, drying most samples in
from 2 to 6 days.
     All samples were weighed before being placed in the  drier.  The
samples were  subsequently checked and their weights recorded every
morning and evening.   When two consecutive  recorded weights were
equal,  the sample was considered dry.
     Data was obtained  for two types of moisture  samples:
     1.  Total  Sample -  A sample was extracted from the sorting sample
         as  it  was loaded onto the pickup truck at the test cells.
         This sample contained a representative amount of all  constit-
         uents  and was  not sorted.
                                     15

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  These samples were dried separately and the data is reported
on Plates E7-E11 in the four left-hand columns.
Compos ite Sample - Samples of each of the ten constituents from
each sorted sample were obtained and sealed in plastic bags.
Four or more of these like category samples were combined for this
drying procedure.   In combining the samples only sequential sajn-
ples were used and the constituent samples of one cell were never
mixed with those of another.
  This data is reported on Plates E7-E11 in the ten right-hand
columns.   The samples from which the composite sample was gener-
ated are  listed under the appropriate grouping.
                                 16

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                         VI - OPERATIONS AND MANAGEMENT

        AUTOMATIC OPERATIONS

        Ligufd Collect ion and Distribution System
             Cell C and D distribution and collection systems are controlled
        by a central  timer  that activates twice daily at pre-set intervals.
        Four standard house service water meters measure the quantity of liq-
*""_      uids applied  to and discharged from the cells.  One meter measures
        the fresh water inflow to the Cell C distribution system.  One meter
*-"       is connected  to the leachate collection tank discharge line of Cell
        C and  records the quantity of leachate pumped from the collection
_       tank and disposed of in the adjacent main landfill.  A meter Is in-
        stalled in Cell D leachate return line and records the leachate re-
        cycled through Cell D.   The final meter is on the fresh water system
        for Cell D and records the make-up water that is added to maintain
        the desired quantity of liquid  recycled through Cell D.
             Cell A 6 E leachate is metered by a house service water meter
        and discharged to the main landfill with an electric pump.Cell B leach'
~~       ate is   discharged  to a collection tank and the quantity is measured
        with a graduated bucket.  The leachate is disposed of in the main
_       landfi 1 1 .

        Storm  Runoff  Collection and Monitor ing  System
             Storm runoff from Cell B and the combined runoff from Cells A
	       & E is collected in swales constructed in the cell embankments and
        discharged through  drainage inlets to collection tanks.  The collec-
        tion tanks discharge through Sparling low pressure line meters which
        record the runoff quantity.
  «

~       MONITORING AND  MANAGEMENT
             The site is inspected daily by disposal operation's personnel   to
        check  for any  vandal ism, theft or equipment malfunction.  An
                                           17

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office engineer visits the test cell site weekly for a detailed check
on all systems and to record the monitoring data.  His duties are:
     1)  Record all meter readings.
     2)  Check, retrieve and replace charts on the recording evapor-
         meter and rain gauge.
     3)  Test the discharge rates for Cell C and D distribution systems.
     k)  Check and test automatic timing system.
     5)  Record meter readings  on storm runoff metering devices.

MAINTENANCE
     Although the Cell design and construction minimized the main-
tenance functions, three basic operational maintenance funtions remain:
     1)  Since water service is not available at the site, water is
         hauled by truck to a 6,000 gallon storage tank that supplies
         the daily water for Cell 'C1  distribution and the makeup water
         for Cel1 D.
     2)  The distribution lines in Cells C & D have to be cleaned period-
         ically.
         Ce11 C - The clear plastic tubing, connecting the discharge
         manifold pipe to the small diameter distribution pipe have
         to be cleaned of algae periodically.
         Cel 1 D - The small diameter discharge holes In the distribution
         piping clog due to fungus growth caused by the leachate.
         These holes must be cleaned periodically.
     3)  The leachate generated from Cells A,B,C, E, and the adjacent
         sanitary landfill  is pumped into the sanitary landfill.  A
         22-foot deep, 6-inch diameter grave 1-packed well was drilled
         in the main landfill refuse and is presently accepting all
         excess leachate from this project.  This construction is of
         a temporary nature and has to be checked and serviced because
         of line breakage due to landfill equipment operations.
                                     18

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                      VI I  - MONITORING PROGRAM
GENERAL

     The monitoring program involves the collection of liquid and gas
samples for field and laboratory testing and retrieval of data from
instruments installed in and about the test cells and clay barrier.
     Monitoring activities are carried out jointly by the staffs of
Sonoma County Department of Public Works and Emcon Associates.  Rain-
fall, evaporation, storm runoff and refuse settlement, as well as the
metering of water and leachate flows into and out of Cells C and D
are monitored by Sonoma County Staff.   The staff of Emcon Associates
collects and tests samples of leachate, gas, Cell C input water, and
groundwater, and monitors lysimeters,  thermisters and groundwater
1 eve 1s.
     All monitored data is presented in Appendix H.

SAMPLING AND TESTING SCHEDULES

     Sampling and testing of leachate  and groundwater commenced in
December 1971.   In February 1972,  a formal schedule for frequency of
leachate,  gas and groundwater sampling and analysis was adopted.
     The initial and revised sampling  and testing schedules are pre-
sented in  Appendix F.

SAMPLE COLLECTION
Leachate, Groundwater, and Water Added to Cell  C and D

     Leachate samples are obtained at sampling  valves located in the
collection line just upstream from the !eachate col 1ection tank.  The
collection line discharges into the collection  tank  through a riser
                                   19

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which extends above the elevation of the sampling valve.   This arrange-
ment minimizes the exposure of the leachate to the atmosphere.
     The groundw»ter is sampled and tested to detect any contamination
by leachate escaping from the cells.  Groundwater samples are bailed
or pumped from the observation wells and periodically collected from
the Cell A subdrain outfall.  Samples of water added to Cell C are ob-
tained directly from the water distribution tank.  The exposure of the
groundwater samples to air during the bailing and collection process,
although not desirable, is not considered detrimental to detection of
contamination by leachate.
     All samples of leachate and water are field tested for pH , dis-
solved oxygen and electro-conductivity.   These tests require approxi-
mately 100 to 200 ml.  samples.  Samples  scheduled for laboratory test-
ing of parameters that deteriorate rapidly with time are treated with
a compatible preservative.  Samples are  stored on ice from the time
they are collected until they are delived to the laboratory.  Upon
arrival  at the laboratory the samples are refrigerated until tested.
Sampling and test procedures are discussed in detail in Appendix G.

Gas

     Gas is pumped from the gas probes using a battery-operated John-
son-Williams Model SSP Combustible Gas indicator.  Gas samples are
collected in gas sample tubes.  Sampling procedures and the gas analy-
sis test method are presented in Appendix G.

Lys i meters

     Lysimeters are sampled periodically by injecting compressed air
through one of two IM inch tubings connected to the lysimeter.  The
fluid sample is discharged' from the second \/k inch tubing and collect-
ed for testing.  Fluid collected is field tested for pH,  dissolved oxy-
gen and, when sufficient quantity is available, electro-conductivity.
                                     20

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Fluid Distribution andLeachate Production

     Flow meters, installed at appropriate locations in the d1str1 bution
and collection piping of Cells C and D, are read periodically to
determine the quantity of fluid entering and leaving the cells.
                                   21

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                       VI I I  - DISCUSSION

REFUSE COMPOSITION
     Refuse compositional analysis data Is presented in Appendix E
and is summarized in Table 2, Refuse Moisture Content Summary and
Table 3, Refuse Composition  Summary.  Both moisture and weight per-
centage figures for the various waste constituents are quite similar
for all cells.  The average  weight percentage of waste constituents
from all cells are compared  with similar compositional data for the
City of Berkeley, California*, the County of Santa Clara, California*
and a study by Dr. Pohland at the Georgia Institute of Technology,
in Table k.  The average values determined for the various waste
constituents in the Sonoma County study are reasonably similar to the
values developed for the City of Berkeley and the County of Santa
Clara.  Each of the California studies differ significantly from Dr.
Pohland's Georgia study in percentage of textiles, metals, glass and
food wastes.  Data from Dr.  Pohland's study is included as several of
his project objectives parallel objectives of this study.
     The Sonoma study developed a somewhat lower percentage by weight
of paper as compared to the  City of Berkeley, Santa Clara County and
Dr. Pohland's study figures.   Frequently, paper is reported in the
literature as comprising over k$ percent of the total waste.

REACTIVITY OF CELL CONSTRUCTION MATERIAL
     In order to establish the reactive character of the granular
material, 20 gram samples of material  were placed in distilled water
in 300 ml.  BOD bottles.   Four sample bottles were prepared for each
of the three granular materials.   A schedule was established to test
the water at time intervals of one week, six months, one year and two
years, respectively.   The tests include pH, alkalinity, Na, K, Ca,  Mg
and electrical conductivity determinations.
     Test results to date (Table  5) indicate that only insignificant
quantities  of dissolved  materials  are  contributed by the granular mater-
ials used in the test cells.  The  general  composition  of water in
* "Comprehensive Studies of Solid Waste Management, 1st and 2nd Annual
  Reports" ,  prepared by C. G,  Golueke and P.  H.  McGauhey, Public
  Health Service Pub 1 icat iion No.  2039, 1970.

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continual contact with the granular materials appears to be stable  in
each case except for pH.  No explanation  is offered for the increase
in pH, however, it is unlikely that the change in pH in the test solu-
tions would influence the composition of  the leachate materials.

SAMPLING AND ANALYTICAL METHODS

Gene ra1
     Experience with sampling procedures and analytical methods on
numerous samples of  leachate has necessitated changes  in both sampling
techniques and analytical methods.  The need for such  changes was gen-
erally anticipated,  but  it was not possible to specifically predict
them as leachate exhibits a complex and changing nature.
     The following general statements can be made about analytical met-
hods as related to leachate tests:
     1.  The analytical  philosophy should be one of attention to ac-
         curacy rather than precision.
     2.  The analysis  is made difficult by the danger  of interfer-
         ences due to  the high concentration of solutes and the chang-
         ing nature  of the leachate.
     3-  Colormetric methods are generally not applicable due to the
         complex nature  of the solution and the high background color
         of undiluted  leachate samples.
     *».  It is not possible to analyze for calcium and magnesium on
         undiluted leachate samples using the normal EDTA titrimetric
         technique due to masking of the end point by  background color.
     5.  On undiluted  leachate samples, it is necessary to use a po-
         tentiometric  titration technique for chloride utilizing an
         Ag/AgCl  electrode because of color interference.
     6.  The concentrations of most common constituents in leachate
         are generally very high and require dilution  prior to analyses

Total Suspended Solids
     Analytical measurement of total suspended solids  (TSS) in leachate
                                     23

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samples is subject to possible error because of the oxidation of re-
duced iron and manganese and the subsequent precipitation of ferric
hydroxide and manganese dioxide in the sample.  Depending upon the
sequence of sampling and the care of analyses, experience has shown
that an inordinate variation in measured total suspended solids (TSS)
results, (see tabulated data in Appendix H).
Our experience has shown that when proper care is taken to avoid the
formation of precipitate in the sample that TSS is generally low (<50ppm).
     Considering that great care must be taken at all points in the
handling of the sample to avoid introduction of oxygen prior to mea-
surement of TSS and also that the data are marginal in terms of inter-
pretive value, measurement of TSS in leachate is not recommended and
has been discontinued.

Colo r

     Quantitative measurement of color is useful only to the extent that
it measures the relative intensity of this parameter and may be cor-
relateable with other more meaningful measurements.  Since even slight
turbidity (suspended solids) causes  the apparent color to be notice-
ably higher than the true color, it  is necessary to remove suspended
material before true color can be approximated.   Removal of suspend-
ed solids is normally done by centrifugation.
     Measurement of color in leachate samples is somewhat complicated
by the fact that diffusion of oxygen into the leachate sample causes
the oxidation of reduced Fe and Mn solution species and, hence, the
precipitation of the hydroxide and dioxide, respectively.  The for-
mation of small, colloidal solids Interferes with the color measure-
ment, and due to the high concentration of reduced iron (and probably    •
Mn) in solution it is necessary to either ('i) prevent oxidation and
precipitation from occurring or (2)  allow complete oxidation and
precipitation to occur and remove the precipitate by centrifugation.
     The first procedure, preventing diffusion of oxygen into the
sample, requires care in handling of the sample at all points of trans-
fer prior to analysis.  The second procedure, is more time consuming
than the first and may still result  in very small colloidal particles

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 remaining  in solution despite centrifuga11 on.  Given  the  limited value
 of the color measurements  to begin with and  the handling  problems dis-
 cussed above, measurement  of color  in  leachate is not  recommended and
 has been discontinued.

 Eleet ro-Con duct i v i ty Rat i os
     Selection  of the degree of dilution  required for  various analytical
 tests is complicated by  the changing nature  of leachate as a function
 of time and site.  Since electro-conductivity  (EC)  is  essentially a
 measure of the  concentration of dissolved ions in solution, there is a
 strong possibility that  a  correlation  between  EC and  major ionic species
 can be made.  The correlation between  EC  and other  chemical parameters
 has therefore been investigated as a possible  aid in  predicting a pro-
 per dilution ratio.
     Results utilizing the data available indicate  the EC ratios may
 prove of value  in estimating dilution  requirements  for some parameters.
 Ratio data for  leachate  from Cells C and  D are presented  in Tables 6
 and 7.  Especially good correlation  is  found  between EC and alkalinity,
 chloride, BOD,  COD, Na and K.
     Somewhat greater scatter is seen  for the  data  on  calcium and mag-
 nesium.   The scatter in  data on sulfate is expected since SOj. is a re-
 active compound under reducing conditions and  hence should not be ex-
 pected to follow EC values consistently.
     Except for magnesium  snd sulfate  the EC ratios for the two cells
 are surprisingly close.   This indicates that,  at least for these few
 parameters, EC  ratios can  be used effectively  in estimating concentra-
 tions for dilution in the  laboratory.  This  may be  especially useful
 in cases where  spot samples are brought in for analysis with no prior
 information on  the leachate composition.
Gas Analyzer
     In  addition to its   use as & pump  to withdraw gat  samples from the
gas probes, the gas analyzer also registers  exp1osib I 1ity of the gas.
Although the value registered is not used to determine precise percent-
ages  of  gases present, the instrument  can be used to  detect the presence
of combustible gases.

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Therm!s te rs

      In order to establish that thermisters installed within the gas
probe conduits register temperature representative of the refuse at
that  location, thermisters were installed both inside and outside the
top gas probe in Cell B.  No appreciable difference in temperature
was registered by the thermisters.   The comparative data is presented
in Table 8.

Gas Samp I ing

     The initial gas samples obtained 12-8-71  were collected in large
evacuated sample bottles and are considered to be uncontaminated
samples.   These test results are therefore reliable.   Samples taken
between 1-3~72 and 3-14-72 were collected utilizing a flushing tech-
nique which resulted in collection of samples  contaminated with  at-
mospheric air.  Subsequent modification of the sampling technique to
include evacuation of the sample bottle have eliminated this problem.
Test  results commencing 3-28-72 are considered representative of the
gas produced in the refuse cells.
REFUSE STABILIZATION
Gene raI
     Sanitary landfilUng is now widely utilized for solid waste
disposal and careful planning and the application of sound engineering
principles to all facets of site selection, design, construction and
operation help insure that the environmental impact is minimal and,
in some cases, beneficial.  With increased use and public awareness
of this method of disposal, increased concern has also developed
with respect to the pollution potential of leachate, its possible
detrimental effects upon surface water and groundwater, and a reali-
zation that in some cases interception and treatment of this  liquid
may be necessary.
     In spite of satisfactory landfill design and operation,  leaching
                                   26

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can and frequently does occur.  This has been documented by  field ob-
servations and case histories which  indicate that  leachate production
is a most frequent problem  in geographical areas which have  relatively
high annual  rainfall.  Limited data  collected to date  indicate  that
some leachates are extremely high  in both organic  and  inorganic con-
stituents and provide potential sources of significant amount of pol-
lutants.
     Examination of the leachate problem reveals that even in landfills
containing only municipal refuse,  a  large number of variables interact
to produce an unpredictable quantity and quality of leachate.  A few
of the  relevant parameters  affecting leachate quantity and quality are:
annual   rainfall, runoff,  infiltration, mean annual air temperature,
waste composition, waste  density,  initial moisture content,  and depth
of landfill.  Additional  variables are macro and micro nutrients, and
toxic elements and compounds.
     Studies of leachate  composition indicate wide variation from site
to site and at any give site with  time.  Adding to the complexity of
the problem  is the fact that leachate flow rates frequently  vary widely
over time at any one site.
     This study has been  designed  to investigate the effect  of several
modes of operation upon the rate and extent of stabilization of muni-
cipal refuse in sanitary  landfills.  Five test cells have been construct-
ed and  subjected to the operational modes presented in Table 1.   The
modes of operation chosen for this study include:  (l)  addition of excess
water to the refuse after refuse emplacement, (2)  recircu1 ation of leach-
ate,  and (3)  addition of  septic tank pumpings to the landfill materials.
     The extent of refuse stabilization is being evaluated principally
by monitoring leachate composition.  Primary leachate composition
parameters  include BOD, COD, pH, alkalinity, volatile acids, phosphate
and forms of nitrogen.  In addition, electrical  conductivity, tempera-
ture  and various inorganic anions  and cations are being monitored to
define  leachate composition.  The  time response of these parameters
are presented in Figures  10 through 40.  Following is  a short discus-
sion   of the general  effect of seasonal  varietlon of rainfall  infil-
tration and temperature after which each test cell is  discussed sepa-
rately  with comparisons made to both the control cell  and to literature
if»f orma t i on .
                                     27

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Rat nfal 1  I nf11tratton
    The first rains of winter have relatively free access to the
refuse through  shrinkage cracks in the cell cover material.   Natural
swelling of the soil seals these cracks and thereafter the cover
material  is relatively impervious.  The infi1 atration water  influ-
ences the moisture content of the cells and,  hence the process of
refuse stabilization.  Rainfall records (Figure 30)  for the  study
site show that  very little precipitation occured duriing the first
winter (1971~72).  Consequently, very little  leachate developed as
a result of infiltration.  The second winter  (1972-73) however, was
a near-record year for the rainfall and leachate was developed in all
cells, indicating significant infiltration.  (Figure 30)
    Cell  D was  a fully saturated system prior to the heavy 1972-73
winter rains and has been monitored on a continuous  basis.  Prior to
the winter rains (before November  1972) the recycled leachate applied
to Cell D was approximately 6,000  to 8,000 gallons per week (Figure
33)-  The maximum quantity of recirculated leachate put through
the Icell  was approximately 37,000 gallons  per week (February and
March 1973).  Although there may be some differences in infiltration
rates between cells, it  is reasonable to sxpect that significant
infiltration occured in all test cells.  The  refuse in both Cells B
and E was wetted to field capacity, but the cells have responded  to
the infiltrated volume of rain water In different manners (Figure
30).  At the present time, it is not clear why the rate of leachate
production is so different between Cells B and E, but the differences
may be a combination of different  permeability of the cover layer
and differences  in the rate of stabilization  due to mode of oper-
ation.  Cell E  was originally seeded with  27,200 gallons of septic
tank pumpings and also received 7,^00 gallons of rainfall before  the
cell cover was  placed.  The cell gave early  indications of vigorous
anaerobic  biological activity.  Approximately ^1,000 gallons of
water were added to Cel'i B to bring it to field capacity before
the top cover was applied (Table  1).  When compared to control
                                     28

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 Cell A, both  Cells  B  and  E  show  considerably  more  leachate  produced.

 Temperature Effects
     Although  chemical  and  biological  processes  are  in  general  temp-
 erature dependent,  both as  to  rate  and  ultimate  equilibria,  it  is  not
 reasonable at  the present time to speculate on  the effect of  temper-
 ature on  leachate composition  other  than  in general  terms.  The  multi-
 plicity of chemical and biological  processes  occurring  within   a
 landfill  are  so complex as  to  preclude  any attempt at  rigorous  treat-
 ment.  On the  other hand, observation  indicates  real differences in
 cell temperatures with  time, depth  and  mode of  operation.
     In general, there  is an apparent  response  of  the  upper several
 feet of landfill to the ambient  air  temperature  while  the deeper mater-
 ials tend to  show a much  smaller thermal  response.   The  effect  of  the
 ambient air temperature is  significant  to the extent of  variation  of
 the ambient air temperature over an  annual seasonal  cycle.  The  sea-
 sonal variations for  this study  indicate  a range of  some 20°  C  over
 the year.   The thermal  response  of  Cells  A, B and  E  with depth  over
 one and one half seasonal cycles is  readily observed in  Figures
 35, 36 and 37.
     In contrast, Cells C and  D, which  receive  daily applications  of
 liquid, show  a pronounced thermal response over  the  whole depth  with
 the seasonal   cycle  (Figures 37 and  38).   This response  over the  whole
 depth of  the  cell reflects  the fact  that  the  temperature of the  ap-
 plied liquid  tended to approach  the  mean  ambient air temperature on
 the dates  of  application.

 Cell A -  Control Test Cell
     Cell A was constructed in accordance with normal  landfill  prac-
tice and covered after the cell was filled with  refuse with no  arti-
ficial  addition of moisture.  Cell A serves as a control against
which the other four cells are compared  in terms of  the effective-
ness of the operation procedures o/i refuse stabilization.

-------
Leachate and Gas Composi tlon;  The first significant quantity of
leachate was collected from Cell  A in October 1972.   During this per-
iod the first rainfall of the winter was recorded.   Prior to the rains
the soil cover exhibited  numerous random shrinkage  cracks.  Appar-
ently a considerable volume of storm water infiltrated Cell A (see
Figure 30)  before the clay cover  swelled, sealing the cracks.
     Compositional data for leachate samples from Cell A prior to
November 1972 indicate, in general, very low values  for the composi-
tional parameters when compared with leachate from  other test cells.
These low values prior to November 1972 may indicate that the initial
leachate samples were condensate  and, hence, did not carry the normal
load of dissolved and suspended materials found in  leachate.  The
volume of leachate collected prior to September 1972 also supports
this hypothesis  (Appendix H).
     In particular, highly solub1e e1ectrolytes such  as K, Na and Cl
were found  in low concentration until after heavy winter rains pro-
duced a significant quantity of leachate (Figure 30).  Parameters
showing marked increase after November 1972 are EC,  TDS , Ca, Mg, S.O.,
volatile acids and alkalinity.  The pH remains low  (pH 5) as expect-
ed because  of the high partial pressure of carbon dioxide.  As a con-
sequence of the  limited data little can be said about the activity
within Cell A prior to October 1972, when production of leachate
allowed consistent monitoring.  Settlement data, presented in Figure
41, indicate that little  settling occurred before the 1972-73 winter
rains.  In  fact, a settlement deflection occurred between September
and November 1972 commensurate with early heavy winter rains.  Ap-
parently, compaction within the cell occurred due to the  infiltrat-
ing mo i s ture .
     Although both phosphorus (P) and nitrogen (N)  levels are some-
what low in comparison to nutrient content In other  leachates, they
should be considered sufficient for biological activity.  Biodegrad-
ation of organic material is proceeding as evidenced by the  large
partial pressureof C02 and the increase in volatile acids.  Methane
                                   30

-------
has been measured  in  low concentration  (1% by volume),  indicating  the
presence of methanogenic organisms, even  though conditions  in  the  cell
are far from optimal.
     Trace metals  data  (Table 9)  indicate  that Cd,  if present,  is
consistently below  the  detection  limits for  the analytical  methods
used.  Since the  1962 U.S. Public Health  Service Drinking Water Stan-
dard is 0.01 ppm,  below the detection  limit  of the  analytical  method
employed, nothing  can be said concerning  Cd  as a potential  hazard
using the Drinking  Water Standards as  a reference point.  Cu has
been found (Table  9)  in the 0.1-0.2 ppm range which  is  an order of
magnitude below the USPHS Standards.   Zn,  Pb and Hg, however,  appear
to be consistently  present in the leachate in quantities above or
near the Drinking  Water Standards (USPHS  Standards:  Zn, 5 ppm, Pb,
50 ppb; Hg, 5 ppb).  An analysis of the potential for contamination
of groundwater by  these metals must take  into consideration the like-
ly reactions between the leachate and  the  soil through which the
leachate must pass  to enter the groundwater  aquifer  and potential  re-
moval mechanisms such as ion exchange, absorption and precipitation.

Cell B- Field Capacity  Test Cell
     Cell B is different from Cell A only  in the respect that  Al.OOO
gallons of water were added to bring the  cell up to  field capacity
before the cover material was placed.  No  additional management pro-
cedures have been  used  on Cell B.

Leachate and Gas Composition:  The initial addition  of moisture to Cell
B was intended to  bring the refuse moisture  content  to field capacity,
thus allowing any  subsequent addition  of water to generate  a propor-
tionate amount of  leachate.   The cumulative  record of leachate product-
ion for Cell  B (Figure  30)  shows the increase in leachate production re-
sulting from early winter rains (9/72-11/72).  The short duration of
increased leachate production suggests that  open cracks in  the soil
cover were apparently sealed due to swelling, once the cover material
was saturated with moisture.   Apparently,   infiltration was  significant
prior to the natural sealing of the cell cover material.
     Data on leachate composition must be   separated  into two time
                                         31

-------
periods.  The first Is the period from 12/71 to 1/72 immediately after
Cell B was brought to field capacity and the onset of the winter rains
In October 1972.  The second period covers the time interval start-
ing with the winter rains of 1972-73 (10/72 on).   Nothing signifi-
cant can be said about data developed during the  earlier period.
This first set of data are scattered and generally reflect concentra-
tions of components in leachates In the ranges reported in litera-
ture.
     Data on leachate composition for the second  time period reflect
real changes and can be explained In terms of volume flow-through
and biological activity within the cell.  Generally speaking, it can
be said that there continues to be anaerobic biodegradation within
the cell, but no significant activity of methanogenic organisms. Gas
composition (Figure 40) shows continued high C02  content with traces
of CH..  Consistent with the gas composition is the low pH, high al-
kalinity and volatile acids (Figures 26, 10 and 11, respectively).
Apparently conditions within the cell necessary to reduce sulfate to
sulfide in significant quantities have not developed, as is evidenced
by the continued high SO,  content (Figure 17).
     Trends from October 1972 on, for all parameters (except pH and
P) indicate a possible dilution mechanism acting  to lower concentra-
tions.  This is especially evident in trends for  TDS and EC, both
of which reflect decreasing concentrations with time (Figures 14 and
15).  Na, K, Ca, Mg and Cl, as well as volatile acids,  alkalinity,
BOD, COD, and organic nitrogen and ammonia (Figures 10  through 25)
all reflect decreases in concentration commensurate with increases
in total volume of leachate produced (Figure 30).
     Trace metals data (Table 9 show compositions  for Cell B similar
to those for Cell A.  Again, Zn, Pb and Hg tend to be at or above the
USPHS Standards, while Cu generally is below Ippm  (except on 1/3/72).
Cd has been detected only on 10/24/72 when the level was 0.19 ppm,
well above the accepted USPHS Drinking Water Standard.

Cell C - Continuous Flow -_ Through. Test Cell
     Water is applied to Cell C at a rate of approximately 800 gal-
lons per day.   The general  effects of this mode of operation are

                                   32

-------
 discussed  be 1ow.
 L each a t e and  Gas  Compo s i t i on:   General  time  responses  for  leachate
 composition  parameters  indicate  decreasing concentrations  for  all
 parameters  (except  pH).   This  general  decrease  reflects  the  basic
 flushing action of  the water added  to  the cell.   The  rate  of addition
                                              2
 of water to  Cell  C  was designed  to  0.4  gal/ft   -  day.   Figure  31 pre-
 sents  the  cumulative distribution and  collection  of  liquid  for  Cell
                                                     3
 C.  The slope of  the distribution curve  is 23.6 x  10   gal/month or
             2
 0.314  gal/ft  - day, slightly  under  the  design  capacity.   The  slope
 of the cumulative volume  collected  from  Cell  C  is  16.65  x  10   gal/ -
                    2
 month  or 0.22 gal/ft  -  day, an  average  loss  of about  3^%  which can
 be attributed basically  to evaportranspiration.
     The continuous steady application  of water to Cell  C  has  result-
 ed in  a moderation  of the  thermal response of  the  upper  layers  in the
 cell as is reflected in  Figure  38.   This thermal  response  is different
 for Cells A,  B and  E, and  more  closely  resembles  the  thermal response
 of Cell D, where  continuous recycle  of  liquid  also seems to  be  reflect-
 ed in  a stable temperature profile  through the  depth of  the cell (Fig-
 ures 35 - 39) .
     Data on  gas  composition,  BOD,  COD  and volatile acids  indicate
 vigorous biological  activity within  the  cell.   In  spite  of the  low
 pH (^5) methane is  being produced at an  increasing rate  (10%+ on 3/
 73).   These data  indicate  that either  the internal pH  is greater than
 the pH  recorded  for the  leachate in the collection system, or  there
 are pockets or volumes within  the cell having different  environmental
 conditions.   In either case, it  is apparent  that methanogenic organ-
 isms  are operating within  the  cell at an increasingly more efficient
 rate.
     The vigor of the biodegradation processes  is  reflected  in  the
 increasing percentage of NH. - Nitrogen  and  decreasing percentage
of organic nitrogen  (Figures 20  ana  21).  The strength of  the reducing
conditions  is reflected by the low  level of  NO- (Figure  19) and the
smooth  decrease on SO  (Figure )7).   Sulfate, a strong anionic elect-
rolyte  under oxidizing conditions, wou1d typica1 Iy follow  the same
trends  as  Cl   (Figure 16)  which generally functions as a  quasi-conser-
vative  material.   However, under appropriate reducing conditions,
                                     33

-------
sulfate is utilized as an electron acceptor and is reduced to sulfide
during bio-oxidation of organic matter.  The presence of CH.  and
decreasing SO, indicates strong reducing conditions.                   •
     Nutrient concentrations (P and N) indicate that  sufficient quan-
tities of nitrogen and phosphorus are available for biological growth.
It appears that the flushing action will continue to  remove nutrients*
from the cell and may eventually lead to nutrient limited biological
activity.
     The quantity of oxygen contained in the water added to Cell C
may eventually affect the general composition of the  leached liquid,
but at the present time it appears not to be exerting a strong in-
fluence.  There is the possibility that added water with substantial
0- con e'en t rat i on could be toxic to the anaerobic organisms present
in the landfill.   It is also likely that the oxygen would be con,sum-
ed rather rapidly as the water moves through the cell depth and,
hence, only the upper layer would be affected.   This  toxic behavior
of oxygen would be reflected in the gas composition,  generally caus-
ing a lower production of methane since molecular oxygen is known to
be extremely toxic to methanogenfc organisms.
     Concentratipns of dissolved materials and  electrolytes as reflect-
                                           *                            ,
ed by the gross measurement parameters TDS and  EC (Figures 1 k and 15)
show a rather smooth trend toward lower concentrations.  Specific
parameters such as Na, K, Ca, Mg and Cl reflect the same trends. The
decreasing concentrations are compatible with vigorous bio-degrada-
tion since inorganic salts and refractory organic solutes are ex-
pected end products of the bio-oxidation process and  should be easily
washed out.  The  early data (first 6 months of  data)  showing high
concentrations of electrolytes should reflect the flushing out of
                                                                      •
readily solubilized material leaving behind those materials requir-
ing biodegradation.
     Trace heavy  metals data (Tabla 10) indicate that, except for Cd,
all metals monitored are present in substantial quantities.  The con-
centrations of these metals are high but compatible with a  low
pK and the presence of dissolved organic solutes which can act as
chelates.   Except for Zn, no trends are apparent.  Zn concentrations
are decreasing with time, indicating a flushing action.  Zn,  Pb and

-------
Hg are all high when compared to USPHS Drinking Water Standards and
pose a potential pollutional hazard to groundwater and surface water
sources.  Recognition of the potential hazard is important.
     The rate of settling of Cell C (Figure *» 1) Is more rapid than the
rate of settling for Cell A, 6 and E.   Cell C has had continual through'
put of water and the data indicate accelerated compaction compared to
control Cel1 A.
     The presence of po1 yen lorinated byphenyls (PCB) was detected
on 3/2/72 at an 0.35 ppb level and O.AO ppb on 3/28/72.  However, none
has been detected in subsequent  analysis.  Since there is no exper-
ience to allow prediction of time-concentration response for PCB's un-
der the conditions present  in the test cell, further monitoring of
this parameter is justified at a reduced frequency.  It should be not-
ed that in the process of analyzing for PCB's, other chlorinated hydro-
carbons have been detected.   Specifically Lindane was found at the
0.06 ppb level on 12/28/71.   No  systematic appearance of chlorinated
hydrocarbon pesticides is evident and hence does not appear to be a
major concern.
     The concentration of fecal  coliform and feca1-streptococci (Fi-
gure 28 and 29) indicate a gradual die-off of these organisms in Cell
C.  It was expected that natural competition and inhibition processes
would cause a reduction in the active organism level.
Cell D - Continuous Leachate Recycle Test Cell
     Leachate is recycled and redistributed to Cell D at the rate of
about 1,000 gallons per day.  The time response of leachate and gas
composition are discussed below  for this mode of operation.

Leachate and Gas Composition;  The fluid routing for Cell D over the
test period is presented in  Figure 33-  It is evident that the volume
of recycled leachate has deviated by at least a factor of 10 during
the test to date.
     Infiltrated rainwater added to the volume of leachate developed
during the heavy winter rains of 1972-73 (Figure 32).  The daily
                                    -35

-------
volume of recycled leachate varied from a  ] ow of about 500 gal/day
(3500 gal/week) to a high of about 5,000 gal/day (37,000 gal/week).
                                                                2     *
The surface loading rates for these daily volumes are 0.2 gal/ft
                2
day and 2 gal/ft  - day, respectively.   Data on leachate composition
indicate surprisingly stable concentration conditions.
     Na, K, Ca and Mg show a leveling trend indicating that some
control mechanisms may be operating on  these alkali  and alkaline
earth metals.   These four metals, usually quite soluble (at low PH
values for Ca  and Mg), show no major response to changes in volume
during the period 10/72 to 3/73.   TDS and, to some extent EC, also
show a leveling trend commensurate with the data for Na, K, Ca, Mg,
as well as Cl  and alkalinity.
     Continuous recycling of leachate in Cell D has  moderated the
thermal response of the upper layers in the cell as  reflected in
Figure 39.
     Active anaerobic biological  activity is suggested by data on
gas composition, volatile acids and alkalinity.  The production of
CH. increased  sharply during the  summer of 1972 and  was about 26%
by volume on 9/72.  These data suggest  strongly that conditions with-
in the cell are somehow accommodating methanogenic organisms and the
pH measured in the collected leachate (pH 5 for Cell D) cannot nec-
essarily be used as a criteria for viability of the  pH-sensitive
methanogenic organisms.  The strong reducing conditions within the
cell are reflected in the absence of any substantial nitrate (Figure
19), in the apparent reduction of sulfate (Figure 17) and in the
continually high values for soluble reduced iron (Figure 27).  Both
NO, and SO, are utilized, sequentially, as electron  acceptors during
bio-oxidation  of organic material under strong reducing conditions.
The increasing percentage of ammonia compared to total nitrogen indi
cates a more complete degradation cf organic matter.  Substantial
quantities of  organic matter have apparently accumulated in the leach-
ate as is  reflected in the staole EOD  and COD measurements (Figures
12 and 13) .

-------
     The high values for organic and ammonia nitrogen and the concen-
tration of phosphate indicate that these nutrients are not limiting
to biological growth.  The reduction in phosphate concentration with
time may be  indicative of bio-utilization of phosphate.
     A balance of the major ions in solution can account for most of
the TDS but  the solution is sufficiently complex that it is doubtful
whether any  useful information can be gained by attempting a mass
balance on the measured ions and TDS.
     Heavy metals appear to be accumulating in the recycled leachate.
Inspection of values in Table II for Cu, Zn , Hg and Pb indicate a
rather steady concentration pattern with time.  Cd does not follow
this pattern within the detection limits of the technique used.  Cu
has accumulated to about 0.1 - 0.2 ppm levels, below the USPHS Drink-
ing Water Standards.  Zn ("20 ppm), Hg (* 10 ppb), and Pb (•'0.2-0.'*
ppm) all are substantially above the USPHS  Standards for these metals.
The high organic content and low pH of the  leachate solution are
compatible with the rather high levels of trace metals.
     The rate of settling of Cell D (Figure Al) is very similar to
the settling rate for Cell  C,  both of which have a continual  through-
put of water.  The settling indicates, compaction and is consistent with
the apparent biodegradation occurring in both Cells C and D.   The max-
imum settlement to  June  , 1973 has occurred in Cells  C and  D  with
a magnitude of between 3 and k inches, or about k percent of the refuse
th i ckness .
     Pol yen 1 orinated biphenyls were detected once on 3/28/72 at the
0.2 ppb level.  No subsequent  analysis showed any PCB's to be present.
Lindane, a chlorinated hydrocarbon pesticide, was detected at the 0.07
ppb level  on 1/18/72.   No subsequent analysis shows evidence for the
presence of pesticides.  Apparently most materials of this nature have
been either degraded or are being retained  within the cell and are not
in the leachate at detectable  levels.
     Data for fecal  coliform and fecnl  strep (Figures 28 and 29)  in-
dicate that there has been  a gradual, but steady kill-off of these or-
ganisms for all cells,  including Cells C and D.  The data confirm the
                                     37

-------
expected results of microbial competition and adaptation.  The only
surprising development is the fact that there is such little dif-
                                                                     *
ference between Cell E and Cells C and D.  Cell  E, seeded with septic
tank pumpings, might be expected to have substantially more fecal
organisms than leachates  from other cells.
                                        '                             «

Cell E - Biologically Seeded Test Cell
     Cell E has been seeded with septic tank pumpings (27,200 gal-
lons) to provide microbial seed material to accelerate biological
degradation processes, and also to bring moisture content up to
field capac I ty.
L e a c h a t e and  Gas Co m p o s i t i o n :  Only small volumes of teachate were
produced in Cell E prior  to October 1972.  However, much the same
as for Cells  A and B, Cell E has responded  to precipitation during
1972-73 winter by producing a considerable  quantity of leachate
(Figure 30).   The cumulative leachate volume (Figure 30) for Cell E
has a time response different from Cells A  and B.  It is not under-
stood at present why the  time response is so different.   Data for Cell
E shows a slow, smooth increase in leachate production during the
heavy winter  rains only tapering off after  the precipitation of Feb-
ruary, 1973-   The most plausible explanation for these data is that
the top soil  cover of Cell E has a higher permeability compared to
Cells A and B.  A higher  permeability would allow slow but contin-
uous infiltration of rainwater into the cell and would not neces-
sarily exhibit surface cracks.   The less permeable soil  with cracks
would allow an immediate  infiltration of rainfall, but once closed
by swelling,  it would be  relatively impervious.   The data can not be
explained by  other differences in Cell preparation or maintenance.  „
     The general trend of all parameters for Cell E  (except pH) ap-
pears to be toward increasing concentration.  initial pH values were
around 6 and  considered along with early gas composition and vola-  .
tile acid data, It is apparent that blodegration of organic matter
                                   38

-------
was accelerated due to the seeding with septic tank pump ings.  However,
it now appears that the early biological activity may have been at
the expense of easily decomposable material since data collected since
October  1972  indicate increasing volatile acids, alkalinity, BOD and
COD (Figures  10-13) with a corresponding decrease in pH  to about 5
(Figure  26).  The  increasing concentration of readily soluble salts
such as  Na, K, Ca, Mg, and Cl (Figures  16, 23-25) is reflected by
parallel increases in IDS and EC over time (Figures 1k and 15).  The
general  increase  in concentrations can  best be explained as a leach-
ing of readily solubilized materials made available by the early bio-
degradation of organic matter.  This explanation is supported by the
opposite response  to  infiltration  water in Cell B which, while brought
to field capacity  the same as Cell E, did not have the microbial seed
to accelerate the  biological processes.
     No  substantial change is evident in the gas composition which re-
mains with substantial percents of CO-  (90%+) and measurable CH, (2%+)
Although anaerobic, the cell environment apparently is not yet suf-
ficiently reducing to convert sulfate to sulfide as is evidenced by
increasing concentrations of SO^ (Figure 17).  Even though the rate
of production of  leachate is different  between Cell E and Cells A and
B, the rate of settlement for these three cells  is quite similar
(Figure  *» 1 ) .  Cell B was brought to field capacity prior to sealing,
whereas  Cell E was brought close to field capacity , Cell A was not
moisture conditioned but received relatively small quantities of rain-
water during construction of the cell.
     The P and N nutrient levels (Figures 18-2!) in Cell E leachate
indicate that neither nutrient can be considered limiting by normal
biological  requirements.   Although the  specific nutrient requirements
of the anaerobic microorganisms existing in the cell are unknown, It
is safe  to say that the nitrogen and phosphorus available  in the leach1
ate are at least an order of magnitude  above minimal requirements.
     Heavy metal  content of Cell E leachate (Table 9) follows the same
trend as for Cells A and B.   Cd is either just at or below the detect-
ion 1'mits of the  analytical  methods used and, when detected, is above
the USPHS Drinking Water Standards.   Cu is generally found at levels
                                        39

-------
below 0.2 ppm, while Zn,  Pb and Mg tend to be at or above the 1962
USPHS Standards.

GROUNDWATER ANALYSIS

     The purpose  of monitoring the quality of groundwater in close
proximity to the  test cells and down valley from the cells is to
maintain a check  on the effectiveness of the earth cells to pre-
vent leachate from contaminating the underlying groundwater.
     The data collected to date (Appendix H) indicate that the qual-
ity of the groundwaters taken from test wells 1 through k remain sta-
ble in terms of the parameters most likely to indicate pollution by
leachate.  The parameters most likely to indicate the presence of
leachate contamination are those relatively conservative parameters
(from the point of view of groundwater) such as Cl, Na, K, Ca, Mg,
SO. and alkalinity.  In addition,  gross measurements such as TDS and
EC are also valuable indicators of changes in composition.  The data
collected show no significant shifts in composition of the water in
any of the we 11s.
                                   1*0

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                                                TABLE 1

                                 LIQUID CONDITIONING AND PURPOSE OF CELLS
CELL
DESIGNATION
A
B
C
D
E
INITIAL
L I QU I D
CONDITIONING
None
Field ^
Capact ty
None
None
Field ^
Capacity
L I QU I D
USED
None
Water
None
None
Septic
Tank
Pump Ings
OPERATION
DAILY
L I QU I D
APPLICATION
gal /day
None
None
700±
(200-1000)**
1000±
(500-1000)**
None
L 1 QU 1 D
USED
None
None
Water
Reel rcu-
lated
Leachate
None
PURPOSE OF CELL
Control Cell
To determine the effect of high Initial
water content on refuse stabilization.
To determine the effect of continuous
water through flow on leachate character.
To determine the effect of continuous leachate
reel rculatlon on leachate character.
To determine the effect of high Initial
moisture content, using septic tank pump Ings,
on refuse stabilization.
*  Field capacity  is  the condition when a sufficient quantity of fluid has been added to the  refuse
   to cause a significant volume of leachate to be produced from the cell.
** Range of variation In dally application of fluid.

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                                  TABLE  2




                      REFUSE  MOISTURE  CONTENT  SUMMARY


ITEM
Food Waste
Garden Waste
Paper
Plastic, Rubber,
etc.
Textiles
Wood
Metals
Glass, Ceramic
Ash, Dirt, Rock
Ftnes
TOTAL
Random Sample
Combined Waste


A



LU
_1
cn
<
_i

<
<
Q
O
Z



41
MOISTUR

B
151
67
29
21
38
13
6
1
10
47
i»0
E CONTENT -
CELL
C
133
99
28
20
28
17
7
1
26
47
38
• * OF DRY

D
118
102
38
15
28
22
4
0
15
47
31
WEIGHT

E
122
91
36
20
25
18
4
1
13
51
33


Average of
All Cells
131
90
33
19
30
17
5
1
16
48
37
NOTE:  Samples oven dried at 105  Fahrenheit
                                           42

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         TABLE 3



REFUSE COMPOSITION SUMMARY
ITEM
Food Waste
Garden Waste
Paper
Plastic, Rubber,
etc.
Textiles
Wood
Metals
Glass, Ceramic
Ash, Rock, Dirt
Fines
TOTAL .
PERCENTAGE OF TOTAL WEIGHT

A
8.8
10.8
35.5
4.2
1.1
1.3
8.0
9.1
5.8
15.4
100.0
B
10.4
11.1
44.5
5.2
1.4
1.2
9.9
9.8
1.0
5.5
100.0
CELL
C
12.8
5.8
42.4
5.1
2.5
0.6
8.8
11.5
3.6
6.9
100.0
D
9.7
7.4
45-3
4.7
1.5
1.3
9.5
12.4
1.0
7.2
100.0
E
12.0
17.0
35.2
4.0
1.9
0.4
8.6
11.5
2.8
6.5
100.0
Average of
All Cells
10.7
10.4
40.6
4.6
*.?
1.0
9.0
10.9
2.8
8.3
100.0
              43

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                               TABLE  4
                        COMPOSITION  OF  REFUSE
^•s. SOURCE OF
^v REFUSE
ITEM ^v
Food Waste
Garden Waste
Paper
Plastic, Rubber,
Textiles
Wood
Metals
Glass, Ceramic
Ash, Dirt, Rock
Fines
TOTAL
WEIGHT PERCENTAGE
SONOMA COUNTY
TEST CELLS
CALIFORNIA
10.7
10. 4
40.6
4.6
1.7
1.0
9.0
10.9
2.8
8.3
100.0
SANTA CLARA
COUNTY (a)
CALIFORNIA
12.0
9.0
50.0
3.0
2.0
2.0
8.0
7.0
7.0
100.0
CITY OF
BERKELEY (b)
CALIFORNIA
25.1
44.5
2.2
1.1
-
8.7
11.3
7.1
100.0
•V;
DR. POHLAND
GA.INST. OF
TECH.- GEORGIA
25.0
0
50. Q
3.0
5.0
1.0
4.0
7-0
5.0
0
100.0
(a)   Estimated  breakdown  of  domestic  waste.   Assumes  a  per  capita
     production of  8  pounds  per  day of  which  44%  is domestic  refuse.
(b)   Refuse segregated  and weighed at Berkeley  Waste  Disposal  Site.
     Percentage figures are  average of  seven  loads  from districts
     established by income  level  and  type  of  dwelling unit.

 *   Reference:   "Co.nprehensive  Studies of Solid  Waste  Management"
                 First  and Second Annual Reports.   C. G.  Golueke 6
                 P. H.  McGauhey.  Public Health Service Pub.  No. 2039,  1970.

 **              "Landfill Stabilization with  Leachate Recycle"
                 Frederick G.  Pohland,  3rd Annual Environmental  Engineering
                 6  Science Conference,  March  5-6,  1973, Louisville,  KY.
                                           44

-------
    TABLE 5
SOLUTION ANALYSIS
     Sllty Sand
Determination - mg/I
Alkalinity
Calcium
Electrical Conductivity
Magnesium
Potassium
Sodium
pH
Time After Immersion
\ week
170
30
500
30
3-5
31
7.2
6 months
170
3*
500
23
1.85
32
7.7
1 year
168
48
600
29
17.0
34
8.8
2 years





    Concrete Sand
Determination - mg/i
Alkalinity
Calcium
Electrical Conductivity
Magnesium
Potassium
Sodium
PH
Time After Immersion
1 week
170
28
500
31
2.2
31
7.2
6 months
170
36
500
23
1.75
31.6
7.9
1 year
168
32
500
28
1.8
32
8.7
2 years







     Pea Gravel
Determination - mg/1
Alkalinity
Calcium
Electrical Conductivity
Magnesium
Potassium
Sod 1 urn
PH
Time After Immersion
) week
180
33
480
26
1.9
31
7.3
6 months
190
54
550
16
1.95
29.6
7.3
1 year
190
40
460
25
2.0
31
9.2
2 years








-------
              TABLE 6
           CELL C  LEACHATE
ELECTRO-CONDUCT!VITY/PARAMETER RAT I OS
DATE
1-18-72
2-15-72
3-2-72
3-14-72
3-28-72
14-11-72
4-25-72
5-9-72
5-23-72
6-6-72
6-20-72
7-11-72
7-25-72
8-8-72
8-23-72
9-7-72
9-20-72
10-11-72
10-24-72
11-8-72
11-21-72
11-30-72
17-19-72

PARAMETER
ALKALINITY
2.01
2.10
2.25
2.53
2.11
2.22
2-53
2.53
2.38
2.78
3.08
1.70
1 .89
2.61
2.69
1.76
1.97
3.01
3-33
3.65
2.56
3.41
2.84

BOD
0.45
0.42
0.37
0.44
0.44
0.44
0.55
0.52
0.41
0.56
0.54
0.42
0.71
0.54
0.66
0.60
0.66
0.57
0.70
0.38
0.38
0.54
0.38

CALCIUM
9.17
9.17
6.25
11.36
10.00
7.50
9.50
11.22
11.08
9.52
11.43
10.42
12.00
11.59
11.48
10.53
10.70
12.73
12.00
8.93
8.04
11.54
9.32

COD
0.33
0.28
0.31
0.41
0.33
0.32
0.39
0.41
0.40
0.49
0.39
0.32
0.43
0.41
0.41
0.37
0.40
0.42
0.43
0.32
0.28
0.43
0.34

CHLORIDE
9.17
9.82
9.09
11.79
a. 90
10.23
11.05
13.58
13.17
17.54
15.09
15.63
17.56
16.98
16.67
18.58
11.30
14.74
19.46
7.69
14.52
21.13
10.04

MAGNESIUM
14.47
22.00
18.18
30.49
22.22
20.00
21.11
27-50
44.32
45.45
40.00
34.09
37-50
28.63
36.08
37.97
41.22
36.36
40.00
30.12
14.06
41.10
-

POTASSIUM
-
-
11.83
-
-
10.75
-
14.67
-
17.86
-
15.63
18.95
15.87
-
17.65
-
21.54
20.00
14.71
16.67
22 . 22
17.50

SODIUM
-
-
10.53
-
-
12.86
-
13.75
-
18.18
-
15.76
15.38
19-21
-
19.23
-
16.67
12.68
14.71
13.64
18.75
16.67

SULPHATE
-
12.50
-
15.24
-
20.09
-
24.55
-
29.41
-
-
-
-
-
45.80
-

-
-
-
52.63
~

TDS
0.72
0.57
0.54
0.69
0.61
0.67
0.79
0.91
0.79
0.99
0.87
0.80
0.96
0.96
0.96
0.88
0.85
0.84
0.91
0.73
0.69
0.98
0.80


-------
              TABLE 6
           CELL C LEACHATE
ELECTRO-CONDUCT IVITY/PARAMETER RAT I OS
DATE
1-10-73
1-23-73
2-6-73
2-27-73
3-13-73
3-27-73
4-10-73
4-24-73
5-15-73
6-5-73
6-26-73

AVERAGE











PARAMETER
ALKALINITY
2.81
2.68
1.53
2.24
2.30
1.40
0.95
1.43
1.51
1.63
1.30

2.28











BOD
0.51
0.40
0.28
0.34
0.50
0.23
0.17
0.21
0.30
0.35
0.25

0.44











CALCIUM
9-95
8.75
6.04
6.06
7.93
5.18
3.12
4.87
4.93
5.76
5.69

8.93











COD
0.41
0.32
0.24
0.26
0.34
0.22
0.13
0.18
0.20
0.24
0.21

0.3k











CHLORIDE
18.97
19.09
5.51
8.15
18.59
7-51
7.32
6.44
7.48
7.06
12.35

12. Ik











MAGNESIUM
46.61
17-50
25.00
23.40
37.76
21.15
13.89
19.90
21.59
26.66
23.84

27.88











POTASSIUM
26,70
18.83
13-30
16.50
22.24
13.33
7.89
12.34
14.84
-
16.66

16.60











SODIUM
22.00
13.82
11.15
12.13
15.90
9.32
5.95
8.55
7.42
-
9.07

13.89











SULPHATE
-
-
-
-
30.72
-
-
-
33-93
-
32.54

29. 71*











TDS
0.88
0.81
0.55
0.61
0.79
0.48
0.30
0.41
0.46
0.56
0.49

0.75












-------
              TABLE 7

           CELL D LEACHATE
ELECTRO-CONDUCTIVITY/PARAMETER RATIOS
DATE
1-18-72
2-15-72
3-2-72
3-14-72
3-28-72
4-11-72
4-25-72
5-9-72
5-23-72
6-6-72
6-20-72
7-11-72
7-25-72
8-8-72
8-23-72
9-7-72
9-20-72
10-11-72
10-2*4-72
11-8-72
11-21-72
11-30-72
12-19-72
i
PARAMETER
ALKALINITY
3.93
2.i»7
1.88
2.02
1.98
2.02
1.91
2.27
2.18
2.24
2.83
2.0U
1.90
1.88
2.53
1.65
1.75
-
3. Mt
2.04
1.96
2.55
2.31

BOD
0.59
0.53
0.41
0.50
0.44
0.46
0.45
0.54
0.36
0.42
0.39
0.50
0.61
0.60
0.71
0.60
0.62
0.54
0.62
0.39
0.36
0.44
0.37

CALCIUM
7.69
8.46
6.43
10.00
7.69
11.11
9.00
12,50
9.38
7.22
10.62
9.85
10.59
10.07
10.86
9.42
9.79
9.99
11.23
7.52
6.25
8.86
6.95

COD
0.13
0.42
0.30
0.40
0.31
0.31
0.29
0.37
0.34
0.38
0.38
0.37
0.41
0.51
0.44
0.39
0.39
0.38
0.44
0.30
0.26
0.35
0.36

CHLORIDE
9.92
10.68
9.18
11.76
9.80
10.87
8.82
11.47
11.19
12.38
11.59
12.62
14.02
13.43
14.21
12.04
11.20
12.08
12.92
9.09
5.92
7.69
6.23

MAGNESIUM
21.43
22.00
18.00
26.67
20.00
16.67
16.36
25.00
33.89
30.95
30.36
26.00
22.87
28.43
28.41
26.26
25.69
24.65
30.51
17.86
14.29
20.69
-

POTASSIUM
13.19
-
12.16
-
-
13.75
-
17.19
-
17.10
-
16.25
18.07
18.59
-
17.57
-
18.67
19.38
13.16
12.33
17.39
16.70

SODIUM
12.24
-
10.00
-
-
11.63
-
12.25
-
13.68
-
14.77
15-89
14.36
-
14.64
-
14.58
15.35
10.99
11.25
13.64
11.50

SULPHATE
-
10.58
-
13.04 x
-
12.59
-
13-59
-
14.32
-
-
-
-
-
21.67
-
-
-
-
-
25.70
-

TDS
0.57
0.77
0.55
0.75
0.59
0.62
0.59
0.77
0.68
0.89
0.73
0.61
0.81
0.77
0.7k
0.69
0.69
0.72
0.91
0.59
0.52
0.69
0.65


-------
              TABLE  7
           CELL D LEACHATE
ELECTRO-CONDUCTIVITY/PARAMETER RATIOS
DATE
1-10-73
1-23-73
2-6-73
2-27-73
3-U-73
3-27-73
4-10-73
4-24-73
5-15-73
6-5-73
0-26-73

AVERAGE











PARAMETER
ALKALINITY
2.78
2.04
1.46
-
1.42
1.10
1.36
1.27.
1.06
1.43
1.27

2.03











BOO
0.47
0.33
0.37
0.33
0.34
0.28
0.25
0.25
0.30
0.38
0.36

0.44











CALCIUM
8.59
8.94
12.03
5.30
5-00
4.33
4.33
3.75
3.94
5.55
5-92

7-92











COO
0.41
0.28
0.21
0.23
0.24
0.20
0.21
0.21
0.19
0.26
0.26

0.32











CHLORIDE
10.43
8.10
5.98
5.71
5-30
4.35
5.38
5.17
3-31
3.83
4.89

9.16











MAGNESIUM
21.88
15.58
11.72
11.00
18.04
9-80
10.79
9.93
7.14
11.36
17.72

20.46











POTASSIUM
18.67
11.62
9.12
10.94
11.48
8.82
9.84
9.38
17-14
-
21.54

14.80











SODIUM
14.05
9.60
7.27
7.38
7.88
6.64
6.82
7.00
5.45
-
13.73

11.30











SULPHATE
-
-
-
-
15.91
-
-
-
15.19
-
21.79

16.44











TDS
0.72
0.52
0.40
0.43
0.41
0.34
0.35
0.35
0.31
0.40
0.38

0.61












-------
           TABLE  8
COMPANION THERMISTER COMPARISON
DATE
12-2-71
12-3-71
12-6-71
12-7-71
12-8-71
12-9-71
12-10-71
12-14-71
12-15-71
12-16-71
12-17-71
12-20-71
12-28-71
12-29-71
1-27-72
2-15-72
3-14-72
3-28-72
4-H-72
4-25-72
5-9-72
5-23-72
6-6-72
TEMPERATURE - ° C
Thermister Inside
Top Gas Probe
Cell B
22.2
21 .0
20.9
21.7
21.7
22.7
22.6
25.6
21.3
21.3
21.2
20.9
20.0
19-8
17.2
15.9
16.9
17.5
17.5
17.6
18.8
20.0
21.1
Thermister Outside
Top Gas Probe
Cell B
22.2
21.1
20.8
21.7
21.8
22.7
22.6
25-6
21.2
21 .1
21.0
20.9
20.1
20.1
16.7
15.6
16.8
17.4
17.4
17.5
18.7
20.0
21.1

-------
                             TABLE 9

             TRACE METAL CONCENTRATIONS IN LEACHATE

                         CELLS A, B & E
CELL A
Date
2-15-72
9-7-72
10-11-72
11-21-72
4-10-73
CELL B
1-3-72
10-24-72
3-13-73
CELL E
2-15-72
10-24-72
1-23-73
3-13-73
4-24-73
6-5-73
ELEMENT - mg/1
Cu
ND
ND
0.16
0.15
0.22

3.6
0.29
0.18

ND
0.12
0.10
0.19
0.32
0,10
Zn
2.1
0.23
0.58
9.0
3.0

140.0
62.0
10.8

ND
1.67
41.0
5.6
64.0
58.0
Cd
ND
ND
ND
ND
ND

ND
0.19
ND

-
0.09
ND
ND
0,05
0.05
Hg
0.0006
0.0065
0.0035
0.013
ND

0.006
0.0035
0.0044

0.0005
0.0145
0.0112
0.0044
ND
-
Pb
ND
0.16
0.12
0.44
1.81

3.0
0.95
0.33

ND
0.60
0.60
0.45
0.21
0.42
ND - Not detected
     No analysis made

-------
                             TABLE 10
             TRACE METAL CONCENTRATIONS  IN  LEACHATE
                             CELL C
DATE
3-2-72
4-11-72
5-9-72
6-6-72
7-11-72
7-25-72
8-8-72
9-7-72
10-11-72
10-24-72
11-8-72
11-21-72
2-6-73
2-27-73
3-13-73
3-27-73
4-10-73
4-24-73
5-15-73
6-26-73
ELEMENT - mg/1
Cu
0.6
NO
ND
0.15
0.15
0.18
0.13
0.07
0.08
0.06
0.11
0.1
0.06
0.06
0.05
0.06
0.08
0.05
0.04
0.02
Zn
42.0
30.0
30.0
22.0
13.0
10.0
9.5
7.5
6.5
7.5
8.5
8.0
4.6
4.5
4.3
2.8
3.5
3.8
2.5
0.6
Cd
NO
ND
ND
0.1
ND
ND
ND
ND
ND
0.05
0.06
0.04
ND
ND
ND
ND
0.05
0.05
0.05
<0.05
Hg
0.0014
0.0016
0.015
0.0102
0.0065
-
0.018
0.06
0.0065
-
0.0035
-
0.0166
0.0123
0.0007
-
0.0034
0.0078
0.0018
0.0002
Pb
ND
ND
ND
0.8
ND
0.1
0.2
0.22
0.15
0.35
0.15
0.17
ND
ND
0.1
-
0.1
0.1
ND
Tr.
ND - Not detected
     No analysis made

-------
                            TABLE 11
             TRACE METAL CONCENTRATIONS IN LEACHATE
                             CELL D
DATE
1-18-72
3-2-72
4-11-72
5-9-72
6-6-72
7-11-72
7-25-72
8-8-72
9-7-72
10-11-72
10-24-72
11-8-72
11-21-72
1-10-73
1-23-73
2-6-73
2-27-73
3-13-73
3-27-73
A- 10- 73
4-24-73
5-15-73
6-26-73
ELEMENT - mg/1
Cu
0.4
ND
ND
ND
0.1
0.15
0.16
0.14
0.15
0.25
0.1
0.35
0.32
0.29
0.08
0.11
0.12
0.09
0.12
0.08
0.06
0.04
0.08
Zn
95.0
40.0
40.0
30.0
30.0
28.0
28.0
-
21.5
29.5
28.5
27.5
25.0
21 .0
22.5
17.8
17.6
16.9
17.5
14.0
15.0
12.0
8.5
Cd
0.1
ND
ND
ND
0.13
ND
ND
ND
ND
ND
0.16
0.09
0.04
ND
ND
ND
ND
ND
ND
0.05
0.05
0.05
<-0.05
Hg
0.003
0.0058
0.0028
0.0066
0.0052
0.009
-
0.012
0.064
0.0055
-
0.0022
-
0.0086
0.0108
0.016
0.0123
0.0047
0.0016
0.0008
0.003
ND
0
Pb
2.0
ND
1.0
ND
0.5
0.18
0.35
0.64
0.36
0.59
0.47
0.32
0.37
0.43
0.40
0.23
0.46
0.24
-
0.1
0.5
ND
0.31
ND - Not detected
     No analysis made

-------
Tl K8-7U
         MENDOCINO  COUNTY

                 SONOMA
                                             V-'
                                             /  NAPA  COUNTY
                     COUNTY
                               CENTRAL
                               DISPOSAL
                               SITE
                                            O PETALUMA
         LEGEND
                 CENTRAL  SERVICE  AREA
                     LOCATION    MAP
                              54
                                                 FIGURE  1

-------
                           LEGEND
                            O~  Spring
                            f-»5 Landslide
                                Merced Formation
                            KJf Franciscan Formation
GEOLOGIC  MAP, CENTRAL  DISPOSAL SITE
                                             i    i

-------
            Trench   Location
EXPLORATION  MAP
                       FIGURE 3

-------
                                Original  Topography



                                Field Density Determination
FIELD  DENSITY  TEST  LOCATION  MAP

-------
as/1
                              Hott
                            • Obl
-------
-J"N
                                 I 1/2 " 01A. PV.C. PIPE  :
                                   1/2"  PERFORATED
                                     RVC. PIPE
                                  LOT
                      DISTRIBUTION  PIPE DETAIL
                          NO  SCAlE
                            CEU-'B-
                                                                                                      SETTLE WENT  MONUMENT
                                                                                                               DISTRIBUTION PIPE.
                                                             ^V;V°'%tV>ISTRI8UTION  MEDIUM
                                                             •.•''-'•>.y    Cell '£,• Sondy  Silt
                                                             " ""*? -"-^    Cell  D « Pea Grovel
                                                                                         CELL'C'a'D'  COVER DETAIL
                                                                                         *NO SCALE
                                                                                         2" DISTRIBUTION
                                                                                           MANIFOLD
                                                           .rn.i.ij..-.u.-.,.j»i.i..nji.
                                                                                                         CELL-0-
                                                                                        4"SUBDRAW
                                             2"PV.C.
                                                         DETAIL OF  LEACHATE COLLECTION  PIPE
                                                                NO SCALE
SECTION 'A-A'- TEST  CELL  SITE  PLAN  (AS BUILT)  |
                                                SCALE   IN  FEET
                                                                                                             COUNTY OF SONOMA
                                                                                                        DEPARTMENT OF PUBLIC  WORKS
                                                                                                          DONALD a HEAD,     DIRECTOR
                                                                                                        SECTION 'A-A1 , TEST  CELL SITE
                                                                                                         PLAN (AS  BUILT)
                                                                                                        JULY  1972    . SCALE AS SHOWN
                                                                                                           FIGURE   6

-------



1
.
•' - 1 .
i
l.obo CM. LtKfcrtt
I
i .



^^WWSJpn | Stl 0< toll on Plel<6 ; Somplinj Tirtninol
) 44 ' DlilrlbutlM -—^ j ( L)niimtl«r,G«s,Thcrmisttr)
6'Concttll ft*' \ Svvict BM<- . 2%"7/L Ll"** \ft\ ' X
"•""^ 	 r- 	 -. 	 \ I .'••»",,*;. «,.»... X.-.1 ^7'4l-.»' i*n» « «.», 1 1..." 	 	 ^^ 	 — \
^^V4 iMclmu RdumLiiu -y\ V ~X-~ 	 r — "''•"'' "' ' " ••I 	 ^ X

X ""ult ^Gos and Th«rn,istff Probei ~J "\
Vs. /'Collwlioo Lim / ^ - ^^^
VX / 27. 	 > -* 	 	 	 S ^^
II2' .
; 1 ** Lyilmltri
; ' '8'
; i SECTION 'B-B'
I
^v
(^O
^ ^v
1



TEST CELL SITE PLAN (AS BUILT) ;

CELL 'd COMPONENTS ,

' i

6 1^ 20 3^^^^^«)
' SCALE IN FEET i
i - i

•4 »


300'
,Evoporimittf
\ ^^*. ^^v

Return Lint • " |
f,t

COUNTY OF SONOMA
DEfWRTMENT OF PUBLIC WORKS
DONALD B HEAD. DIRECTOR
TEST CELL SITE PUN
(AS BUILT)
j JULY.I972 SCALE, AS SHOWN
FIGURE 7
« «

-------
                                      12OO feet  to  Test  Cells
                     Top  of  Existing  Channel   Bank
                                                J
                           Piezometers
Sand
Drainage
Blanket
6 inch
Dia. CMP
Perforated
bottom 5 feet'
                                                Clay
                                                  7
Flow Line
 of Existing
 Channel
                                                                z
                                         7/|\V==/7|\\=='
                                                 Bedrock
Collection  Sump
backfilled  with Pea Gravel
    CLAY    BARRIER    CROSS   SECTION
                  Scale:  1inch  -  5 feet
                                61
                                                           FIGURE  8

-------
                                     Typical  Cell
\
\
\
\
1







f
,
s




r* ' 	 	 ~i
4 1
J_ _L
x 3
* *
5 2
_L _L





'
/
/








\
\
\
\
   Sampling Location  for
     Lysimeters,  Gas  Probes,
     and  Thermisters
                                  PLAN
                             Typical  Identification  Symbols

                                            2 feet - Cover Thickness
 Lysimeter  Located  at
2,4,8.8  feet Below
Cell  Bottom
                     C~Q,,
                       ~
Gas Probe  and Thermister
  Located  at  1  foot above Bottom(B),
  Middle(M). & 1 foot  below Top(T)
  of  Refuse.
                                SECTION
                                L EGEN D
              C-T    Cell 'C',  Top Probi
              C-4    Cell 'C',  Lysimeter 4 feet
                      below Cell  Bottom
                                            _L
                                              A
           Settlement  Plate
           Gas Probe & Thermister
           Lysimeter
           Sampling Location
TYPICAL   INSTRUMENTATION   LOCATION
                   SCALE :  1 men  =  20 feet
                                     62
                                                              FIGURE   9

-------
                                              1200  feet  to  Test  Cells
                             Top  of  Existing Channel  Bank
                                                        7
                                   Piezometers
         6  inch
         Dia.  CMP
         Perforated
         bottom 5
                                                                Flow Line
                                                                 of Existing
                                                                 Channel

         Sand
         Drainage \. '\V
         Blanket
         Collection  Sump
         backfilled  with Pea Gravel
TI  I (B - 71)
CLAY   BARRIER    CROSS   SECTION
              Scale:   1inch  - 5 feet

                           61
                                                                  FIGURE  8

-------
                                              Typical Cell
                                                          Y
                                                   J_

                                                          A
                                           PLAN
            Sampling Location  for
              Lysimeters,  Gas  Probes,
              and  Thermisters
                 Typical  Identification  Symbols

                                2 feet - Cover Thickness
          Lysimeter  Located at
           2,4,8.8 feet Below
           Cell  BoUom 	
                         Gas Probe and  T her mister
                           Located at   1 foot above  Bottom(B),
                           Middle(M), & 1  foot  below Top(T)
                           of Refuse.
                                         SECTION
                                         LEGEND
C-T
C-4
                             Cell 'C', Top  Probi
                             Cell f, Lysimeter 4 feet
                               below Cell  Bottom
_L
<=a
 y.
A
Settlement  Plate
Gas Probe & Thermister
Lysimeter
Sampling Location
         TYPICAL   INSTRUMENTATION   LOCATION
Tl 1(8 - 71)
                            SCALE :  1 men  =  2O feet.
                                              62
                                                                       FIGURE

-------
                                      (11,029)
  10,000 —
                                          1973
                                                         1974
                               TIME-MONTHS
                 ALKALINITY  OF LEACHATE
                                                      | FIGURE  10
  20,000—
  16,000 —
X
o>
E
I
v>
Q
O
O
>
I2.00C —
  8,000 —
  4,000 —
1971
                   1972
                                          1973

                               TIME-MONTHS
1974
       VOLATILE  ACID  CONCENTRATION OF  LEACHATE I  FIGURE n
                              63

-------
X
o>
E
l
o
   70.000—,
60,000 —
<  50,000-

UJ
O


UJ  40,000-
o


o
<

2
UJ


o
CD
   30000-
20,000-
    10,000-
          N1 D

          197!
           jT> IM I A ' M I J i J I A I S ' Qi N ' D
                    1972
                           J I F I M I A I M I J I J I A 1310 I NTO
                                     1973
J I F I M I A I M I J

   1974
                                  TIME-MONTHS
           BIOCHEMICAL  OXYGEN DEMAND  OF LEACHATE
                                                           FIGURE 12
E

I

O
UJ
o
UJ
to
X
o
<
o
UJ
X
o
   70,000—1
    60,000 —
   50,000 -
   40,000-
30,000 —
   20,000 —
 10,000-
               •(89,520)
N ' D| J

1971 '
                                                      I 01 N ID
                       1972                     1973

                                  TiME-MONTHS
                                                         J IFIMI A I Ml J

                                                             i974
             CHEMICAL  OXYGEN DEMAND OF LEACHATE    |  FIGURE 13
                                           64

-------
en
e
V)
Q


_J

O
CO


Q

LU
O
CO

CO
<
I-
o
40,000—




36,000—




32,000—




28,000-




24,000—




20,000—




I 6,000-




I 2,000—




 8,000—




 4,000-
          N1 D


          1971
I J I J I A IS I 01N!D J 'F IM'A 'MI J ' J I A1

 1972                      1973

            TIME-MONTHS
                                                     0 I N I D
                                          !MIA'M'

                                           1974
               TOTAL DISSOLVED SOLIDS IN LEACHATE
                                                             FIGURE  14
O
o
o
a:
o
LJ
UJ
    25,000—
E
o
£   20,000-

E
L:   15,000-
>
o
3
Q
    10,000-
 5,000 —
          N ' D

          1971
1 j' J'

 1972
                                            1973
                                       jl7]MlAl|*l J'

                                           1974
                                   TIME-MONTHS
               ELECTRO-CONDUCTIVITY OF  LEACHATE
                                                             FIGURE  15
                                65

-------
    2,500—
    2,000-
jj?   1,500—

I
LJ
Q


O   1,000—
_l
X
O
     500-^
         N ' D

         1971
                 1972
                              jIFIMI AIM!j'JI A IsIoIN1D
1973
J I FIMI AIM I J

    1974
                                TIME-MONTHS
            CHLORIDE  CONCENTRATION OF LEACHATE    FIGURE is
en
E
l
LU
    i,400—i
    1,200-
    1,000 —
800 —
£    600 —

13
CO
    400 —
     200 —
         NDJFMA MJ
                           s ' o N o
         1971
                 1972
1973
                                TIME-MONTHS
J I F I MI A IM' J I

    1974
            SULPHATE  CONCENTRATION OF LEACHATE      FIGURE 17
                                     65

-------
        (83.0)' -(79.2)
V.
o>

E
Q.

to
o
a
to
o
    50 —
                    1972
                      1973
                1974
                               TIME-MONTHS
          PHOSPHATE  CONCENTRATION OF LEACHATE   I  FIGURE is
o>
E

I
z
UJ
(S
o
a:
<
QL
            J'F'M'A'M'J'J'A's'O'N'D
   0.01
        1971
1972
1973
1974
                               TIME-MONTHS
          NITRATE-N  CONCENTRATION OF  LEACHATE     FIGURE 19
                          67

-------
E
i
Z
UJ
CD
O
cr.
z
O
    1,000—
    800—
600—
    400—
    200-
                                           1973
                                                    J I FTM1 A IMI J

                                                       1974
                               TIME-MONTHS
           AMMONIA-N  CONCENTRATION IN LEACHATE
                                                      FIGURE 20
    1,000—
UJ
C5
o
cr
h-

z

o

•z.
cc
o
    100-
1971
            J F M A M
                 1972
                                           I97o
J I-F 1 M I A I Ml J

    1974
                                TIME-MONTHS
           ORGANIC-N  CONCENTRATION OF  LEACHATE    FIGURE 21
                                   68

-------
V.
O>
E
Q
O
OT
1,600—


1,400-



1,200-



1,000-



800—



600-



400—


200-
N > D
1971
         J I F I M I A
                         I A I S I 0 I N I D
                      1972
                                         1973
                                                  JIplM IAIMI

                                                      1974
                                 TIME-MONTHS
             SODIUM  CONCENTRATION  OF  LEACHATE
                                                        FIGURE  22
    1,600—



    1,400—



    1,200—
OT
e   1,000—
CO
O
a.
     800—
     600—1
     400—
     200—
             \
1971
                      1972
                                    j 'F'M'A'M'J'J'A's^o'NIc
                                         1973
                                                  JIFI MIA I Ml J
                                                     1974
                                 TIME-MONTHS
            POTASSIUM  CONCENTRATION  OF  LEACHATE
                                                        FIGURE 23
                              69

-------
    3,000—1
                      1972
                                       1973
                                                jlF'MlA'Mljl
                                                   1974
                                TIME-MONTHS
            CALCIUM  CONCENTRATION  OF  LEACHATE
                                                      FIGURE 24
o>
E
cn
UJ
z
    1,400—1
    1,200—
    1,000-
     800—
600—
     400-
     200-
N ID
1971
                              ' K D
                      1972
j'FlM'A'M'J'-!
         1973
                                                    jFMA
                                                       1974
                                TIME-MONTHS
       MAGNESIUM  CONCENTRATION  OF LEACHATE
                                                           FIGURE 25
                                     70

-------
I
Q.
      7 —
      5—
         N1 D

         1971
          I FTMl
                  1972
1973
                                 TIME-MONTHS
                         pH  OF  LEACHATE
                                                  jIFIM'A'MI

                                                     1974
                                                        FIGURE 26
01
e
o
a:
1,100—




1,000




 90O




 800-




 70 C




 600 —




 500—




 400—




 300-




 200—




 100 —




  0
N I D

1971
                               A:
                      1972
                                         1973
                                 TIME-MONTHS
              IRON  CONCENTRATION OF LEACHATE
                 1974
                                                        FIGURE 27
                                 71

-------
E
O
O
Q_
S

I
^
or
o
o
o
<
o
     io6H
     I05H
     io4-
io3H
     I02H
     10 -
          \B
          \
          \
                    NOTE CURVES PLOTTED TO INDICATE TRENDS.
                        SEE APPENDIX H. FOR INDIVIDUAL TEST RESULTS.
         N ' D

         1971
             J I F I Ml ATM I jTjT A I S I 0 ' N I D
                  1972
                                 j IF IMI A'MI J ' j I A I s 'o I HMD
1973
                                                         IMI A 
-------
LLJ
UJ
5
UJ
X
o
g .	



6 —


4	



? —



0
         II
   4,000 —
   3,000 -
V)
z
o
-}  2,000

<
C5
   1,000 —
                    L09_
                      Ui
                                   RAINFALL--
                                       EVAPORATION
                                                           IJ
                                                                   i::
                                                 CELL "E"
                                     CELL "B
                                    "J~T"A"T"S  i
                                 1972
                                              OINlDJlFlMlAlMlJljlAlslOlNID
                                                       TIME-MONTHS
J I F
                                                                                                        T J
                    e


                   •6


                   : 4


                   -2


                   - 0


                   - 2


                   • 4


                   •6
                                                                                                                 — 4,000
                                                                                                                 — 3,000
                                                                                                                 -2,000
                                                                                                                 — 1,000
                                 CUMULATIVE LEACHATE PRODUCTION-CELLS  A, B  8  E
                                                                                                                     FIGURE 30

-------
    8OO-
    700 -I
    600-
 10
  O
  * 500
  CD
    400-
  3 300
  O
    200-
r-,   IOOH
O
c
m

OJ
WATER DISTRIBUTION
                                         LEACHATE COLLECTION
         ' A' S ' 0 rN rD  J rF ' M r A ' M ' J 'J'A'S'O'N'DJ'F'M'A'M'J'
1971
1972
1973
                                                 1974
                                    TIME-MONTHS

      CUMMULATIVE  WATER  DISTRIBUTION AND LEACHATE  COLLECTION - CELL"C"
                                                  i    i

-------
      V)
      UJ
      o
8-



6



4



2



0-



2



4 -



6
tn
      U.I

      Ui
      V)
      z
      o
         10,000 -
         8,000 -
         6,000 -
         4,000 -
         2,000 -
                                                                   ,V
                N  I D
                 1971
           J I F I  M I A
I M I  J  1 J
     1972
I A I  S  I 0 I N I  D
F I Ml A
\M I  J  I J
     1973
I A I  S  I 0 I N I  D ! J I  F
I M I  A
 1974
M !  J
                                                                                                              —10,000
                                                                                                              — 8,000
                                                                                                               - 6,000
                                                                                                                           — 4,000
                                                                                                               — 2,000
                                                               TIME-MONTHS
                                                        FLUID  ROUTING -CELL
                                                                    "C"
                                                                                           FIGURE 32

-------
UJ
UJ
UJ
x
o
o 	



O ~~



4.-


2 —



0--C


2 -


4-


6 —
  40,000
30,000 —
it
UJ
UJ
z
o
20,000 -
10,000 -
              LEACHATE AND WATER.

              DISTRIBUTED
                                         <>x/ J "*          | i-1'''"
                                         EVAPORATION	4j
                                                                                                                           -8


                                                                                                                           -6


                                                                                                                           -4


                                                                                                                           -2


                                                                                                                           -0


                                                                                                                           -2


                                                                                                                           -4


                                                                                                                           -6
                                                                                                                          —40,000
         N|D[J|F|M|A!M|J!J|A[S|O|N!D(J  I  F I  M I  A  I M TJ  [jlAlslolNlDjlF  I M I  A I M I  J
          1971  I                   1972                   I                    1973                   I         1974


                                                          TIME-MONTHS



                                                   FLUID ROUTING-CELL "D"
                                                                                                                             i— 30,000
                                                                                                                              -ao,ooo
                                                                                                                             —10,000
                                                                                                                                 FIGURE 33

-------
o
UJ
o:
UJ
Q.
UJ
     40-
     35-
     30—
     25—
     20 —
     15-
     10—
      5 —
              MEAN  AMBIENT AIR TEMPERATURE'1
         N1 D
         1971
J I F I Nil A I M I jl J I A I S I 0 ' N I D
          1972
1973
1974
                                 TIME-MONTHS
        MIDDLE THERMISTOR  TEMPERATURES- CELLS A-E"   FIGURE 34
UJ
tr
CC
U
Q.
     40—.
     35 —
     30-
     25—
     20-
     15-
     10 —
      5—
              MEAN AMBIENT AIR TEMPERATURE
              l FJ M1 A> M1 J ' J ' A1 S" O1 N'D J ' F MM^ ATMlj1 JT A 'S I Ql N ! D
        1971           1972                     1973
                                 TIME-MONTHS
                                                   1974
                                                     11*11
              THERMISTOR  TEMPERATURES - CELL A
                                                 FIGURE 35
                                 77

-------
cr
LLl
a.
2
UJ
     40—i
     35—
     30—
     25—
     20—
15—
     10—
     5-
              •MEAN AMBIENT AIR TEMPERATURE
N'DIdIFlMI AIM I J IJIAlSI O1NID]jlF'MlAlMlj'jl

1971 '           1972           '          1973

                        TIME-MONTHS
                                                     j I F i Ml A'

                                                         1974
                                                                    j I
                                                   HI-.II
             THERMISTOR  TEMPERATURES-CELL "B
                                                       FIGURE 36
o
QC
UJ
OL

5
UJ
     40—i
     35—
     30—
     25—
     20—
15-
     10-
              MEAN AMBIENT AIR TEMPERATURE
N'DJJ'F'M'A'M'j'j'A's'o'

1971 I           1972
                                             1973
                                                      j1FIMI AI

                                                         1974
                                 TIME-MONTHS
         THERMISTOR TEMPERATURES-CELL't"
                                                             FIGURE 37
                                     78

-------
u
e
 I
Ui
tr
£
ui
     40-1
     35-
     30-
25-
     20-
     15 -
     10-
              MEAN AMBIENT AIR TEMPERATURE'
1971
                 1972
                                             ljl J ' A ' S ' 0 ' N ' D| J 1 F ' M I AT||Tjl

                                              1973          I    1974
                                 TIME-MONTHS
            THERMISTOR TEMPERATURES-CELfC"        j  FIGURE 38
     40-1
     35-
u
o
I

IT
UI
Q.


UJ
     30-
     25 •
20-
15-
     10-
     5 -
              •MEAN AMBIENT AIR TEMPERATURE
N'D


1971
                 'j' j' A' S1 O1 N I D I J ' F I M U 1 tf j 171

                 1972          '          1973

                             TIME -MONTHS
                                                         ! D I J I F I M I A I M I J

                                                               1974
             THERMISTOH  TEMPERATimES - CEliL V      I  FIGURE 39
                               79

-------
     1001-1
CD
 I
V)
     80-
     60 -
     40-
     20-
SAMPLING LOCATIONS
 CELL V- MIDDLE PROBE
 CELL'S"-MIDDLE PROBE
 CELL V- BOTTOM PROBE
 CELLV-TOP PROBE
 CELL'S'- MIDDLE PROBE
           1971
             1972
M ! J I  J  I AIS I  0 I N I D I J  I F I *MA I M I J
    1973                  I    •    1974
                                                        TIME-MONTHS
                                                     GAS COMPOSITION
                                                                                                  FIGURE 40
                                                             »      I       I       I

-------
    I     I
            <    I    I     {
                                          I    II    I     II
   O-i
   .1 -
H
it,
LJ
z
ui
UJ
CO
   .4-
•n

i
r^i
rf
        ^AVERAGE VALUE OF 5 SETTLEMENT

        PLATES PER CELL.
N T D J TF MVTA MVI' J ' J ' A'S'O'N rD[ J rF rMTATM> J ' J ' A

1971 /          1972          '           1973

   I                       TIME- MONTHS
                                                          J 'F ' M1 A"M'

                                                              1974
         I
                      'AVERAGE  CELL SETTLEMENT

-------
               APPENDIX A






FIELD EXPLORATION AND LABORATORY TESTING

-------
ft I I8-7H
LOG OF EXPLORATORY BORING
GROUND SURFACE ELEVATION:
Tor-
vane

1.0
1.0



Liquid
limit

38
31




Plasticity
Index

21




Natural
Moftture
Content
Percent

12.8
15.6


15.7

Dry
Density
iWCu.Ft.






A
Penet-
ration

4.5+
4.5+



1
.c
1
2
4
6
8
10
12
FEET BORING NO. 1
Groond Water
Leveb
MM
••»
•^
•M
•M
•••
•••
•^
•Hi
•••
••H
^M
•••
•••
•en
•••
eBM
1
••••I
z
z
•MB*
•BIBB,
•••HI
••••
z

••)••
••••
••Me
•Ml
•MM
^MB
••••1
•IMP
••OT
DESCRIPTION
%
%
u
%
%>
m


(CD Yellow Brown Sandy CLAY
with roots to 8 inches;
dry, hard.
(Damp, very stiff to hard)
(SC) Yellow Orange Clayey SAND
with trace of fine gravel
@ 4.0'; moist, stiff.
(Firm)
(Mottled gray with gravel
to *s inch in lense; ve|y
moist)
(Blue-green, wet)
Bottom of Trench- 11.0 feet.
• ' ' " . • ':'
REMARKS: Trench excavated with Drott Backhoe. . ~"~ 	
X - Indicates bulk sample obtained from trench
* — Penetration by pocket penetrometer
Preceding page blank


                                                      83

-------
FE 1  (8-71 (
LOG OF EXPLORATORY BORING
GROUND SURFACE ELEVATION:
Tor-
vane

1.0
0.9 ."


Liquid
Limit
30


29
.-
Plasticity
Index
15


15
'-
Natural
Content
Percent
11.3


18.7

Dry
Density
Lbi./Oi.Pt.





*
Penet-
ration

4.5
3.5


1
£

2
4
6
8
10
12
REMARKS: -Trench excavated with Drott
FEET BORING NO. 2
jl
!
2
•*•



«••

—fee*
i
•••JM
MfteH
^••M
~
DESCRIPTION
VY
i//y
I
Yi
%
I

(CL) Medium Brown Sandy CLAY
with roots to 8 inches;
dry, hard.
(Damp, very stiff)
(Yellow brown with trace of
fine gravel; grading damp
to moist, stiff)
(Mottled orange and gray)

(lense gravel to V)
Bottom of Trench - 11.5 feet.
Backhoe. .
X - Indicates bulk sample obtained from trench
* - Penetration by pocket penetrometer
                                                                                  84

-------
FE 1  (8-71 (
LOG OF EXPLORATORY BORING
GROUND SURFACE ELEVATION:
Tor-
vane

0.4




0.8





Liquid
Limit












Plasticity
Index












Natural
Moitture
Content
Percent




19.9







Dry
Deniiry
Lbs./Cu.Ft.












is
Penet-
ration

4.5+




3.0





1
.E
f
1

2
4

6
8
10

12



FEET BORING NO. 3
£
"c *
5 —1
6




—i
_^








j
•^^•»
i •»
•n ii -
ii -
nil • i
L^
•^Mk



•«M—
— w"
^-H—
^Hi«e>
• •••
DESCRIPTION
/yy
///
f

7//
i
i
i
y/s
///




(CL) Medium Brown Sandy CLAY;
grass roots to 8"; dry^ hare
(Traces of fine gravel)
(Mottled orange; ^^*P»^f^y
stiff) ' * •" .
(Yellow brown, moist, stiff)
(More sand) - ^ j''
f
(Mottled orange and gray) ;


*' set -;
Bottom of Trench - 12.5 feet
t.
i.
(
V
REMARKS: Trench excavated with Drott Backhoe ^
X - Indicates bulk sample
* - Penetration by pocket
obtained from trench
penetrometer
                                                                        85

-------
FE 1  (8-71 (


R
I'.
LOG OF EXPLORATORY BORING
GROUND SURFACE ELEVATION:







Liquid
Limit



30


Plasticity
Index



17


Natural
Moisture
Content
Percent



18.3
20.2

Dry
Density
Lbs./Cu.Ft.






*
Penet-
ration






S
£
£
a

2
4
6
8
10

REMARKS:
Trench excavated with Drott
FEET BORING NO. 4
0
% *t
i-S



™-i
-_i




ft
JD
E
o



1
z



1
	
DESCRIPTION
w

%
w/
yy
%


(CL) Medium Brown Sandy CLAY with
roots to 8"; dry, hard.
(Damp, very stiff)
(Mottled orange; moist,
stiff)
(Very moist)
(Yellow brown; moist, stiff)
Bottom of Trench - 9.5 feet

Backhoe
X - Indicates bulk sample obtained from trench
" - Penetration by pocket penetrometer
                                                                                   86

-------
PE I (8-71 (
LOG OF EXPLORATORY BORING
GROUND SURFACE ELEVATION:
Tor-
vane

0.4

1.0+



Liquid
limit


" 39




Plottklty
Index


24



'
Natural
Moisture
Content
Percent


15.6

13.8


Dry
Demky
Ibt/Cu.lH.







Penet-
roHon

4.5+

4.5+



1
.E

2
4
6
8
10
12
REMARKS:
Trench excavated with Drott
FEET BORING NO. 5
Ground Water
levels
ena
^»
i
••^B*
•«•••
2
^•••BBHB
•^
en*)
••<
•••


••i
•M
•••
eMM
e^«
••e*
•••
••M
em
••N
evmi
••BBBB
»••••
•(••••>
E
•*••••
••Ml

•••BBB
!•••••
••»•»)
*•••>•
••••»
•IBBM
••*••
^^B
rfe^
••^B
••^B
!•••
m^m
DESCRIPTION
i
i
'/A
i

%
t


(CD Medium Brown Sandy CLAY
with roots to 8"; dry, hard
(Mottled orange; damp, very
stiff)
(Yellow brown mottled
orange; moist, stiff)
( Streaked 'gray)
(Trace of fine gravel)
Bottom of Trench - 11 . 0 feet
' •' '• >....• '
Backhoe
X - Indicates bulk sample obtained from trench
* - Penetration by pocket penetrometer
                                                          87

-------
MAJOR DIVISIONS
UNEO SOILS
1 > no. ZOO sieve size)
s|
I?
«» D
O.S
o*-
£
o
FINE GRAINED SOILS
(More than 1/2 of soil < no. 200 sieve size)
GRAVELS
(More than 1/2 of
coarse fraction >
no. 4 sieve site)
SANDS
(More thon 1/2 of
Coarse fraction <
no. 4 sieve size)
SILTS 8 CLAYS
LLX50
SjLTS a CLAYS
11)59
HIGHLY ORGANIC SOILS
SYMBOLS| TYPICAL SOIL DESCRIPTIONS
Qyy HJJBJ Well groded gravels or gravel-sand mixtures, little or no fines
PH
GP :•
0
r5
GM >l
s
ft
GC |
sw 1
SP
SM
SC ^
ML
CL ^
•*J
%3 Poorly groded gravels or gravel-sand mixtures, littlt or no fines
'•°J
SS
JH Silty gravels, gravel-sand-silt mixtures
^»
j< Clayey gravels, gravel-sand-clay mixtures
;'«1 Wtll groded sonds or gravelly sands, little or no fines
w
¥i
Poorly groded sands or gravelly sands, little or no fines
Silly sands, sand-sill mixtures
y
s/ Clayey sands, sand -clay mixtures
t
Inorganic silts and very fine sands, rock flour, silty or clayey
fine sands or clayey silts with slight plasticity
y\ Inorganic clays of low to, medium plasticity, gravelly clays,
y\ sandy clays, silly cloys, lean clays
OL ullllnt Organic silts and organic silty clays of low plasticity
MH
CH 1
OH 1
Pt |
1 Inorganic silts, micaceous or diotomaceous fine sandy or silty soils,
] elastic silts
ifi Inorganic clays of high plasticity, fat clays
2 Organic cloys of medium to higH plasticity, organic silty clays,
y organic silts
IS Peaf and other highly organic soils
Sc _ _.. _____ __ _ _ - _ _
          CLASSIFICATION  CHART
             (Unifind Sail Clossificotion Systam)
CLASSIFICATION
BOULDERS
COBBLES
GRAVEL
coarse
fine
SAND
coarse
medium
fine
SILT S CLAY
RANGE OF GRAIN SIZES
US Standard
Sieve Size
Above 12"
12" to 3"
3" to No. 4
3" to 3/4"
3/4" to No- 4
No. 4 to No. 200
No 4 to No 10
No 10 to No. 4O
No. 40 to No 200
Below No. 200
Gram Size
in Millimeters
Above 305
305 to 76.2
76.2 to 4.76
76.2 to 19 1
19.1 to 4.76
4.76 to 0.074
4.76 to 2 00
2. 00 to 0.42O
O420I00074
Below 0074
                        a
                        z
                                   CL
                                   ML80L
                                         CH
                                          -OH
                                           a
                                  JO 40  30  60 70

                                   LIQUID LIMIT
                                              eo  90 100
                              PLASTICITY  CHART
GRAIN SIZE  CHART

  METHOD OF SOIL CLASSIFICATION

-------
                      SUMMARY OF PERMEABILITY TESTS
TRENCH
  NO.
   DEPTH
    ft.
 DENSITY
   pcf
          PERMEABILITY
    @ 20 "C
    cm/sec
                                                          ft./year
  1

  4

  5
2.5-3.0

    5.5

    4.0
106.0

112.4

104.9
6.6 x 10'
2.3 x 10"
3.1 x 10'
0.066

0.23

0.31
                       SUMMARY OF SPECIFIC GRAVITY
TRENCH
NO.
1

DEPTH
ft.
2.5-3.0
4.5-5.0
SPECIFIC
GRAVITY
2.78
2.58
                               89

-------
                            PLASTICITY CHART
60
50
40
30
20
10

 7
 4
                                             CH
                             a
                            f
                   CL
                    'ML
          10     20     30      40      50     GO

                               LIQUID LIMIT (%)


                             PLASTICITY DATA
70
       80
90
                    100
KEY
SYMBOL
€
a
•
o
«
0
HOLE
NO
1

2

4
5
DEPTH
( f eel )
2.5-3.0
4.5-5.0
1.0-1.5
8.0-9.0
5.5
4.0
LIQUID
LIMIT
r )
38
31
30
29
30
39
PLASTICITY
INDEX
Ci)
21
14
15
15
17
24
UNIFIED
SOIL
CLASSI-
FICATION
SYMBOL
CL
SC
CL
CL
CL
CL
                                      90

-------
1
N








<^/_ GRADATION TEST RESULTS |
LL 38
PL 17
PI 21
JIAT W/C 12,8
CLASSIF. SYMB. c r_
SAMPLE NO. ]
DEPTH Ft 2.5-3.0
HOLE NO. 1
100












10
M
t
RCENT^
a.



31
17
14
15.6
sc
2
4.5-5-0
1
-
-
-
15.7
SC
3
10.0-10.5
1
HYDROMETER ANALYSIS
TIME READINGS
SKIN 7HR ISMIN 60MIN. I9MIM. 4MIN IMIN. ZC




































































































































„











1




















	 ff**@

















IE ^>b)ii
•^t;

5 3.0




1
" iti h -\ -i
^IgBU.U-l




M \ CH
















Q 8 8 8 888 885 o



t .• 5 — 5 -















|S 8
I* .0
















i1 	 "









) . T 	 P




y 1 . ._j















5 §8 ^
«T .01
CLAY (PLASTIC) TO SILT (HO* -PLASTIC)
O
30
15
15 .
,11.3
CL
1
1.0-1 .5
2
29
]k
15
18.7
CL
2
8. 0-9-0
2
U.S. STANDARD SERIES
IOO SO SO IS













•


^ S
/
S '

/


S
y^
•

S
f
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v

















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.14






•

. •
•
•
• yX
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M
9 f
PIAMETE



. '

.
_^
^
S^ ^~
S^S
^ *

f
s x
S s
s S
/ /
/
/






























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(T. .5
R: or Wk«T


* • '
^x^1
_x^"


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X '
/• v '
•" _, "
x



































W 1.
CLE IN M
-
-
'
19-9

1
6.0-7.0
3
SIEVE Al
S. '

... •^i^-
^*^~
^/
S"*^~
•~^-
/"


X
X








































9 ' •*.:
ILLIMETEf
jj+ *^*r
. ^*^ ^
_^^ -^
X











































m V
* 4
IS
\ SAMO
FIME
MEDIUM
COARSE
30
13
7
18.3
CL
1
5-5
4
-
-
-
20.2
CL,
2
9-0

1ALYSIS
CLEAR SQUARE
5/»" **" 1-1/2
z:
=s^














































iii
•• : *















































1
o
Z
1!















































| |
u ' s
39
15
2k
15.6
CL
1
4.0
5
-
«.
-
13.8
-
2
8.5
5
OPENINGS
j" s"«" a















































|l||
i.'1
7«
GRAVEL

FINE
[ COARSE














































|





|
III I
.2 " t2T 1















































0


o
u
J*
Itl
H
Z
Ul
u
a.





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KV\
o
se8
COBBLES

-------
                     COMPACTION TEST
   130
   125
 u
 ex
V)


UJ

o
cr
o
120
  115
  110
                                  \
                         10         15


                       MOISTURE CONTENT %
>-
I-

V)
CL

O
                      MOISTURE CONTENT
:ST
:ERO AIR
(IDS CURVE











V
\!





























































SAMPLE NO.
1
SAMPLE DEPTH
2.5' - 3.0'
SAMPLE DESCRIPTION
Brown Sandy
CLAY



SPECIFIC GRAVITY
2.78
TEST DESIGNATION
D1557-70
MAXIMUM DRY
DENSITY '( PCf)
123.5
OPTIMUM MOISTURE
CONTENT, %
12.0
20
T.%
:ERO AIR
)IDS CURVE









































































SAMPLE NO.
SAMPLE DEPTH
SAMPLE DESCRIPTION




SPECIFIC GRAVITY
TEST DESIGNATION
MAXIMUM DRY
DENSITY (PCf)
OPTIMUM MOISTURE
CONTENT, %
'^ &"7
                                                                   I 

-------
        APPENDIX B
TEST CELL CONSTRUCTION DATA
           93

-------
TABLE A































TEST
NO.


1
2
3
4
5
6
7
8

9
10
11
12
13
14
15
16
17
18

19



DATE
OF
TEST

1971
10-1
10-1
10-6
10-8
10-11
10-18
10-18
10-18

10-18
10-18
10-18
10-18
10-18
10-18
10-18
10-18
10-18
10-18

10-18
SUMMARY OF FIELD DENSITY TEST RESULTS
APPROX.
DEPTH
OF
FILL

(feet)

2.0
2.0
3.0
4.5
5.5
4.5
3.5
2.5

2.0
1.0
1.0
2.0
1.5
2.0
1.0
5.0
5.0
5.0

0.0


LOCATION



See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan

See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan
See Plot Plan

See Plot Plan
APPROX.
ELEVA-
TION

( (feet) )

297.0
297.0
298.0
299.5
300.5
300.5
301.5
302.5

303.0
304.0
304.0
303.0
277.5
277.0
278.0
275.5
275.0
276.5

278.0
FIELD

DRY
DENSITY
(pcf))

113.0
115.5
110.0
118.0
110.0
115.0
113.0
119.5

106.0
114.0
115.2
109.0
121.2
113.2
110.2
115.0
111.0
108.0

110.5

WATER
CONTENT
(%)

13.0
13.6
13.5
15.0
15.6
18.6
19.2
11.3

21.2
17.1
19.5
19.2
11.7
18.8
16.2
10.9
17.1
20.8

14.0
MAXIMUM
LAB
DRY
DENSITY
(pcf) I

114.0
114.0
114.0
114.0
114.0
114.0
114.0
114.0

114.0
114.0
114.0
114.0
114.0
114.0
114.0
114.0
114.0
114.0

114.0
RELA-
TIVE
COM-
PACTION

(%)

99.0
101.5
96.5
103.5
97.0
102.0
99.0
105.0

93.0
100.0
101.0
96.0
106.0
99.5
97.0
101.0
97.5
94.5

97.0


REMARKS



i


Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells B,C,D










i
Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells B,C,D
Cells A £ E
Cells A £ E
Cells A £ E
Cells A £ E
Cells A 6 E
Re-worked £
Accepted
Cells A £ E













94

-------
                         COMPACTION  TESt
    120
  '  115
z  110
UJ
o
 a:
 o
    105
    100
                                    \
                                       \
                                            ZERO AIR
                                           VOIDS  CURVE
                 10
                             15           20          25
                          MOISTURE CONTENT  - %
CO
z
a:
o
                                            ZERO AIR
                                           VOIDS CURVE
                          MOISTURE CONTENT
                                                                SAMPLE NO.
                                                               Stockoile
                                                               SAMPLE DEPTH
                                                            SAMPLE DESCRIPTION
                                                             Brown clayey
                                                              fine SAND
                                                              SPECIFIC GRAVITY
                                                               2.75 (est.)
                                                              TEST DESIGNATION
                                                               D 698-70
                                                               MAXIMUM DRY
                                                              DENSITY  '(DCf)

                                                                114.0
                                                             OPTIMUM MOISTURE
                                                                CONTENT, %

                                                                  16.3
                                                                SAMPLE NO-
                                                               SAMPLE DEPTH
                                                             SAMPLE DESCRIPTION
                                                             SPECIFIC GRAVITY
                                                              TEST DESIGNATION
                                                               MAXIMUM DRY
                                                               DENSITY  (PCf)
                                                             OPTIMUM MOISTURE
                                                                CONTENT, %
                                    95

-------
OTRDUL. . . 	 — 	 	 -— , 	 	 	 	
\
*









f
|| GRADATION TEST RESULTS 1
LL
PL
PI
NAT. W/C
CLASSIF. SYMB.
SAMPLE NO. Co§knSLB
DEPTH FT
HOLE NO. Kaiser





Cojjtr^le |

Basalt



.

luck Sand

Basalt
HYDROMETER ANALYSIS
TIME READINGS
25 HR 4SMIN 7HR.ISMIN 6OMIN. I9MIN. 4MIN IMIN. K
too



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S § 8 5]
37 .a
CLAY (PUSTic) T0SILT(NOi»-Pi.ASTic)
0
. .





Pea Gravel

Cell D
100





































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Ul
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70
90
WO
COBBLES

-------
                                                                         	iS'iiiS1*"
          \
             \
              \
               \
t*83-
                 2
                 2.
2.117
• -* —
1.67
  17        217
 X
2.33
                      -X —
                      2.50
                       X
                      2.25
                                                 2.00
  00       1.75        2.58       2.50
 X
2.83
          —X—
           1.92
            !*7        2*33        2*33       2^00
  *
 2.,58
                                           2.(83
                                            X
                                           2.|42

                                            I
                                                            2.67       2.
  •^
  |25
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  I
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/1.92
                            X
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                      X
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2X25        2*
                                  58
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2.5O
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  JC
 2.(00

  I

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 1.67\
                                                                          \
                                                                              \
                                                                               \
                                     CELL

                    COVER   THICKNESS   IN   FEET
Tl 1(8-71)
                             SCALE : *r inch = 1O feet
                                                                -77-

-------

\
\
\
\
\
\
\
1*90" 1*95 "2*45 ~T9"5 ~"


1*95 2*00 2^50 2?20
•
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1.i90 2.20 2.55 2:30
I
i
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X X X X
2.100 2.20 2.5O 2\9O
1
1
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1
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1.|75 2.OO 2.35 2>5
I
I
I
1

/1.45 1.85 2.3O 2.5O
.
.

/
/
'
,


CELL 'B'
COVER THICKNESS



SCALP 1 inch = 1O feet
\
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-------
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1
1
2*67 1.8.3 2,25 2^0
0?92 1.08 0.83 lfo8
1
| "" .
1 •
;" ' 1 "
1.A92 2^7 2^00 2^7
lijOO 1.17 1.25 O.92


2J42 2.17 2.00 2.17
:: X X X
0.183 1:OO 1.00 1.00
• '
2.JJ7 2.08 2.17 2.OQ

1433 1,17 1.08 1.17
1
1
1
• ' 1 . •":•.
X1.00 1.25 1.00 0.83
s • • • • '
. •
'
/
r - - •
CELL 'C'
COVER THICKNESS
LEGEND
2.25 Thickness of Soil Cover
X
1.00 Thickness of Sand Cover

SCALE: 1 inch s 1O feet

.'-.'.' . ."••/
• s
/
s
*X7 2-0€k
"b*B3 0^2
1
1
1
2£8 2|17
: ' ,.| ' ." -:.;.-•
1
1
2,33 2|25
0^12 1.|33
1
1
2 25 2.1 3 3
. ^j^ . - . •" '.j^'-v •. •
108 tjOO
" ' :' ;' : ' ., -
2.17 SjlOe
X X
1.17 1.108
- 'I- ; '•
' • • . 1 • • ••
1
1,92 2^)0
0.92 Q92\
• N •
\
\
- . . S "l-
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IN FEET




-97-

Tl  1W-71)

-------
TI KM-711














































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s
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1
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1
1*67
0*83
1
1
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LEGEND
2.42
X
1.00

,




192

1.00


1,92
1.08



1.67
X
0.92



1.00


2.00
X
O.83



1.92

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1.00







:OVER

Thickness

Thickness
SC





2gp 183_

O.92 1.08

•
2,25 2^7
0.92 1.00



175 . 132
X . X
1.O8 1.00



1.75 2-17
X X
1.17 1.00


1.67 2.00
x x
1.17 0.92



1.50 1.67


0.83 1.08


'



CELL 'D'
THICKNESS IN

of Soil Cover

of Pea Gravel Cover
ALE: 1 inch s 1O feet
'•'"• ,;'
/]

/
/
2}7 1.6*

0.92 1.,OO
, . , •
•
| tf~
2x°° ^P
1.17 1.|08 :
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1.92 1J58
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1.25 1.J08
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i*67 i£3
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1 75 1.,50
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1.25 1.108
1
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1.58 2.Jl7
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-------
                                                                 --X-
          \
             \
                ISi
                                          OO
              2.1
33
K
2.50
1.92
2X5(
2.33
83      1.
                                 X
                                2.67
                  2.
1.|75

 I

 I

 I


1.|67


 I

 I
              2.108

               I

               I
              2.|75
                 2^0      2^0       2^0
        X
        2.50
         X
         1.75
         2*33
         2X33
          I
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         2-H7  f ,
             iO'v-
              /1.83
                          -K -
                          1.67
                                    I

                                   J
                                                             v     !
                                                               \   >
                                                                s
                                                                 s
                                                                  \
                               CELL   'E1

                 COVER   THICKNESS  IN    FEET
                         SCALE: 1 inch ? v> feet
T( 1(8-71)

-------
          APPENDIX C
CLAY BARRIER CONSTRUCTION DATA
           102

-------
TABLE A




















SUMMARY OF FIELD DENSITY TEST RESULTS
TEST
NO.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
DATE
OF
TEST
1971
8/10
8/10
8/10
8/10
8/10
8/11
8/11
8/11
8/11
8/11
8/11
8/11
8/16
8/16
8/17
8/17
8/17
8/18
8/18
8/18
8/18
APPRQX.
. DEPTH
OF
FILL
(feet)
4.5
315
2.0
6.0
7.0
7.5
8.5
9.0
10.0
10.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
16.5
17.5
18.5
19.5
LOCATION
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
Barrier Core
APPROX.
ELEVA-
TION
( (feet) )
190.5
189.5
187.0
192.0
193.0
193,5
194.0
194.0
195.0
195.0
194.0
195.0
196.0
197.0
198.0
199.0
200.00
201.5
202.5
203.5
204.5
FIELD
DRY
DENSITY
(pcf))
118.7
114.0
113.2
113.7
111.5
114.2
117.2
117.7
122.2
119.5
120.0
118.0
119.7
117.0
119.2
117.2
121.2
118.0
113.7:
116.2
122.5:
WATER
CONTENT
(%)
16.4
15.8
17.4
15.1
16.4
15.5
15.6
16.4
15.3
15.5
15.0
15.6
15.7
15.4
15.7
16.4
15.4
16.2
17.4
19.3
15.')
MAXIMUM
LAB
DRY
DENSITY
(pcf) I
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
116.0
RELA-
TIVE
COM-
PACTION
(%l
103
99
98
99
97
99
101
102
105
103
104
102
103
101
103
101
105
102
•98
100
105
REMARKS

Re- worked f>
Accepted
• f f - i» •
11 ' 1!
II II
II 11




Sand Cone
Density
Test Method
.. !








MOTE: All field density determination by nuclear method except as noted.
• • ' • ••..'••.''




















103

-------
                          COMPACTION  TEST
0-iU
115
"S
ex
1
i 110
UJ
o
or
o
105


















































































-



































































































-












r












/
V

















/
f
















4
/

















/
/
.













\



1















f-ZERO AIR
^OIDS CURVE
T
\

V
\















\
\

Ss?
^















\
\


















\
\


















\
\








                              10
                                          15
20
                            MOISTURE  CONTENT  %
co
Z
g
CE
O
                                             ZERO AIR
                                            VOIDS CURVE!
                           MOISTURE CONTENT
                                   104
                                                                  SAMPLE NO.
                                                                  Composite
                                                                 SAMPLE DEPTH
                                                                From Stockpile
                                                               SAMPLE DESCRIPTION
                                                               t Brgwn, Sandy
                                                               *"
                                                                SPECIFIC GRAVITY

                                                                   2.6'S (SSt.)
                                                                TEST DESIGNATION
                                                                 ASTM D698-70
                                                                 MAXIMUM DRY
                                                                 DENSITY '( PCf)

                                                                    116.0
                                                               OPTIMUM MOISTURE
                                                                  CONTENT, %

                                                                     14.5
                                                                  SAMPLE NO.
                                                                SAMPLE DEPTH
                                                               SAMPLE DESCRIPTION
        SPECIFIC GRAVITY
                                                               TEST DESIGNATION
                                                                 MAXIMUM DRY
                                                                 DENSITY  (PCf)
                                                               OPTIMUM MOISTURE
                                                                  CONTENT, %
                                    rnr

-------
            APPENDIX  D
INSTRUMENTATION  DETAIL  DRAWINGS
            105

-------

                 Thermister  wiring

             NO. 3  Rubber Stopper


            3/4 - inch   PVC  Coupling

          1/4-inch  Simplex Tubing
           3/4 - inch  PVC  Schedule 40 -*•
                            11B " Typ.
                          3/16"  Typ.
             3/4-inch PVC  End Cap-*-
                                             LL
                                        U	U
                                                       1/2"
                                                              36"-Stagger  Slots  at 2
                                                               inch  Intervals  around
                                                               Pipe  Circumference
 Notes:
1. If  thermister  is
 placed  inside probe,
 epoxy  thermister to
 tube wall or stopper.
2. Fabricate  holes  in
  Rubber  Stopper  for
  Tubing  and  Wiring  and
  seal  with  Epoxy.
                                 GAS    PROBE
                                       Full  Scale
II !(«-7l)
                                        1110

-------

          2 inch  Pip*


          2 inch  Coupling
                            SECTION A-A
I i
; j
rd Pipe Cap »f
Galvanized iron
Both CTnds •
i Galvanized Iron
Coupling -v
\
/T^I
-V \ T


*

••••MM





1 . jf



Variable
IA
3 I/'
baB *
                             ELEVATION
   n t«-
SETTLEMENT  PLATE  DETAIL
           Scale: 1 inch s 6 inches

                     107

-------
        Removable
        PVC  Cap
        Plug
p
1
fWfV* X-'i*1
crete Vi.
1
pervious
irbf ill .. n 	
nch PVC:
tedule 40 —
ed 2 inch
Schedule 40-
Detail )
rete Sand —
PVC Cap-



\


».':
/t
7
L
•-•i
. •

p

MM



k».
•>
V
V
to

. *
6'


• •
;V
»y
i
/
/
/
"/
•".••
•^

••/.
•


• • * *
*'/
L






4"


•_•
36
t-H
VJ
12
p

                                     Stagger 1/16 inch
                                     wide Stats
                                     around Pipe
                                     Circumference
                             36- Min.
                             Variable
SLOTTING DETAIL
Scale: linch: 2 inches
          INSTALLATION  DETAIL
            Scale: 1 inch = 1 foot


             OBSERVATION   WELL   DETAIL
Tl 111-71)
                                 108

-------
           Monitoring  Station
Alternate  Monitoring
  Station  Location
                                                               *-* w.
                                                               •    „ W
                                    PVC   Elbow  and  Riser
                                     with  Rubber  Stopper
     \+—PVC  Riser
              Coil 10 feet  of  Tubing
              and Cap  Ends
                                   Backfill  with  Moist
                                  Compacted impervious
                                  Soil

                                Backfill  with  Piezoseal
                                          2  inch Boring
                         1/4   inch QD. Polyethylene Tubing
                                              Lysi meter
            Variable
                                                                    4"  Compacted
                                                                    Impervious  Soil
                                                                    Variable
                                                                    6"Concrete Sand
            LYSIMETER   SAMPLING    SYSTEM
                            Scale: 1 inch = 1 foot
Tl 1(1-71)
                                             109

-------
    1  inch PVC Cap


Impervious Backfill — -*^^



1-inch PVC Schedule 40 — -



6 -inch Boring — •

Piezoseal — ^


1-1/2 -inch O.D. Porous
Tube and Reducer
Coupling (See Detail ) — **""
Concrete Sand — "•""*""

^*
£
^
y
/
/
$
/
-*.
7
'/
'/
I

';'i

;\j

r » '.
-^
*' *.






b

\
1






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/
/
y
/
y
u.
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/
/
V/////////A
•' :'
r •

'
i'

*'•'.




















4"







Variable



12"
6"
f

12"

12"
r
PIEZOMETER  INSTALLATION  DETAIL
           Scale : 1 inch = 1 foot
              1 ,0

-------
                         12"
                                         r—1-inch PVC  Schedule  40
i      11^—1-1/2-inch x  1  i
I      ' [     Reducer Coupling
                                                            inch pvc
                                                           ng
                                   . —
                                               1-1/2-inch  PVC Schedule 80
                                                Sleeve
                                              1 -1/2 - inch O.O. Norton
                                                porous Tube  P212O
                                              NO. 6  Rubber Stopper
               PIEZOMETER   TIP   DETAIL
Tl 1(1-71)
                             Scale :  1 inch s 2 inches
                                     m

-------
         APPENDIX E
REFUSE COMPOSITIONAL DATA
          112

-------
                    RANDOM SAMPLE ASSIGNMENT
   CELL NO. A
CELL NO. B
CELL NO. C
Cumulative
Weight
Tons
21
55
92
160
168
180
189
224
238
255
359
457
480
Sample
No.

A-21
A-55
A-92
A-160
A-168
A-180
A-189
A-224
A-238
A-255
A-359
A- 4 57
A-480
Cumulative
Weight
Tons
11
14
78
125
178
186
18?
255
265
336
365
370
439
495
Sample
No.

B-ll
B-14
B-78
B-125
B-178
B-186
B-187
B-255
B-265
B-336
B-365
B-370
B-439
B-495
Cumulative
Weight
Tons
56
118
142
159
176
178
254
261
262
39^
420
472
496
499
Sample
No.

C-56
C-118
C-142
C-159
C-176
C-178
C-254
C-261
C-262
C-394
C-420
C-472
C-496
C-499
  CELL NO. D
CELL NO. E
Cumulative
Weight
Tons
10
55
63
145
168
211
252
358
359
420
436
438
456
493
Sample
No.

D-10
D-55
D-63
D-145
D-168
D-211
D-252
D-358
D-359
D-420
D-436
D-438
D-456
D-493
NOTE:
Cumulative
Weight
Tons
80
86
87
105
157
250
259
276
295
338
362
407
432
495
mbers (500
Handbook
Sample
No.

E-80
E-86
E-87
E-105
E-157
E-250
E-259
E-276
E-295
E-338
E-362
E-407
E-432
E-495
unit sample)
of Tables for

















obtained fro
Mathematics
                         Chemical Rubber Co.  1970
                         18901 Cranwood Pkwy., Cleveland, Ohio 44128
                          113

-------
REFUSE COMPOSITION DATA
       CELL A
SAMPLE #
A21
A55
A92
AloO
A168
A180
A189
A224
A238
wt.
%
wt.
^_
wt.
wt.
wt.
_£
wt.
%
Wt7r~~-
wt.
'WK>

~*c
"wtT
food
waste
7.7
9^4
3§tB ]
3B.9 "
6.2
"29.T
~*50.2~
,7.1
121. 5
15.4
50.1
7.6
~~2l7C)
10.5
42.0
8.7
27.6
12.1
39. T~
5.5
J- i » ^
-i* .-a--;
garden
waste
3-5
"10.6 "
2 2
7TB
~l8Vf "
12.2
"5776-
191 ."4 "
32.8
99.5
0.1
0.1
2.2
~67o" "
r~o~
27.0
5.3
18.5
11.4
37.1
21.3
6T75
3.3
11.6"
1
paper
22.9
"70.3 ~
22.2
79.7
41.8
152.1
26.9
i25.3~"
_18J5_
106.7
•30 c,
-<--• -X
"98.5
41.9
136.2
49.3
1353" '
32.0
128.0
49.1
15673"
38.1
124.1
47.5
150.9
plastic
rubber,
etc.
5.1-
3.9
13-9
6.1
22.3
3.0
-1379"
"l6~.5
5.'!
16.5
4.5
14.7
4.4
"1276""
4.0
16.0
_j.o
4.5
14.5
"375™
11.3
38.3 j 4.1
335.9 f14-6

I
textil<
1.0
"375 '
1.4
5.0
177 ~
0.5_
0.8
4.7
1.5
4.5
1.8
5.9
1.1
2.4
9.5
0.9
3.0
1.1
3.5
0.8
2.6
0.9
3.0*"

7'"" "1" "T "" I """ j "
wood
0.5_j
0.9
3.0
" 3^4
0.7
" 373-
~o".5~
0.5
1.5
7.2
23.5
0.3
~0.8~
0.6
2.5
0,2
1.7
5.5
1.6
5.1
1,1

metal:
5.5
2T.O~~
-2or£
8.8
31.9
4.5
•21 .T
47io""
3.8
11.5
10.2
33.0
10.2
~2"8.0~
6.5
267o
„ 7-9 '
14.9
48.6
6.7
"21.2
7.6
27.0


glass,
ceramic
11.7
3"o7b "
^:f-
"3o!6~
8.5
~ ^Q Q
. 5.1
"29.0
6.7
20.2
9.4
30.6
8.7
24. 6~
12.3
49.5
9.9
31.5
10.3
'33.6
6.2"
'1975""
13.3
""46.9


ash.
Ib.o
"49T2- •
97i9~
_2..1_
6.0
"28."^
~26.0~
0.3
1.0
0.6
1.8
3.1
2.9
11.5
1.5
~4Tb" '
0.5
" O •
4.1
6.9
24.3


fines
24.4
~75TT5--
17.1
"BHT
|5.6
31.5
17.6 _
101.0 "
9.4
28.5
8.9
29.0
13.1
22.0
88.0
13.0
5.4
17.5
_ 2'7
19-9
70-5


TOTAL
100J6
30774"
T5*ry
36472"
^70-r
"573. r

1*303.2
32479'
"27478"

400. a
11573-
325 r?
jA | » &
-35470'



-------
REFUSE COMPOSITION DATA
      CELL B
SAMPLE #
Bll
B14
B78
B125
B178
B186
B187
B255
B265
B336
B365
B370
B439
B495
A _
wt.
-*_
wt.
*
wt.
J*__
wt.
J£_
wt.
*
wt.
%
wt.
*
wt.
•*
wt.
%
wt.
-*—
wt.
JL:-.
wt.
•*'
wt.
#
wt.
food
waste
9.3
37.5 "
12.4
"5573""
2.1
6.5
. 1-L
23.5
6.7
21.1
10.8
44.5
19.6
64.5
19.9
75.5
6.6
24.6
7.8
^8.0
9.9
31.4
13.2
~43T$
2,9
10.0
16.7
48.1
garden
waste
6.4
"26.0 "
15.4
"5875 ~
30.7
93.3
J4J_5_
107.0
12.0
38.1
10.7
44.0
0.7
2.4
0.7
2.5
9.3
34.8
23.0
82.2
2.7
"T.4~
^ 9.7
"32.2
0.0
0.0
. 0.0
0.0
paper
51.5
"208. 5 ~
40.6
180T5'
37.3
113.5
_36.i9-
114.5
47.6
150.5
42.1
173.4
1 38,7
127.4
48.4
183.1
41.6
156 . 2
43.6
156.1
44.3
"140~2~
37.4
124.0~
63.7
220.2
49.6
143.2
plastic
rubber,
etc.
3.7
15.0
5.1
22.5 '
5.6
"17.0
. JL7_
8.4
8.6
" 27.1
5.6
23.2
3.2
10.6
3.8
14.5
5.4
20.3
3.8
13.6
7.4
~23.2
5*9_
19. 6~
3.3
11.5
8.5
24. 5
textil<
1.0
~4.0
1.1
~5.6—
0.7
' 2TO
. °-5 _
1.5
0.7
2.1
0.9
3.8
1.4
4.5
1.3
4.9
2.8
10.T"
3.1
11.2.
2.5
*r:.r"
0.8
"275""
0.5
1.7
2.1
6.0
wood
0.1
0.5
1.5
~-5.5~
1.1
"373
2.7
8.5
0.1
0.3
1.7
7.1
0.4
1.4
1.9
7.4
0.6
2.4
0.2
0.8
0.9
~~5T7
1.3
—Kf
3.2
11.0
0.2
o~T
metal:
7.6
30.5
12.0
"5~5'
10.2
-^170"
— 7i£
21.7
9.0
2576 "
11.1
45.5
12.3
40.5
ID. 3
39. 6~
10.3
38.8
8.5
30.4
ll.l
IT. 3"
9.5
"31.6
7.2
25VO
11.8
34.1
glass,
ceramic
11.0
44.5"
7.3
"323"
5.8
"TT.T"
_TI§;
23.5
4.8
"15.2"
8J_
36.0
14.1
46.6
:9.3
35.1
13.7
51.3
8.3
2975
17.8
• 5&-.1-
16.5
' 54.?"
4.2
14.4
8.9
25.6
ash,
SSS-
1.4
5.5"
2.5
-TT.O-*
1.2
~5.r
_ 0.0
0.0
3.4
10.6"
0.6
2.5
0.3
0.9
P-9
3.5
1.0
3.8
0.0
0.1
0.2
~~°"^
0.0
" "oTo"
2.5
8.5
0.7
275
fines
8.0
32. 2 ~
2.1
" 575
5.4
T6.T
_ °^1
1.5
7.1
~22~7F "
7ji .
31.5
9.3
30.8
3.3
12.5
8.7
32.8
1-T
6.1
2.9
9.2
5.7
"19.0 '•'
12.5
43.0
1.5
"Tf.r"
• * # is #of wet weight.
TOTAL
100J6
404.5
"Tt4475
-30T.I
~31oTl
'316T2

411.5
~329T6

378". 6

37575
"50
"315T?
~*3§r.3
"345T3

288. e


-------
                                             REFUSE  COMPOSITION DATA
                                                     CELL  C
SAMPLE #
C56
C118
C142
C159
C176
C1J8
C254
C261
C262
C394
C420
C472
C496
C499
_± _
wt.
_*_
wt.
J-
wt.
A.,
wt.
J5_
wt.
*
wt.
j£_
wt.
*
wt.
%
wt.
• %
-Wt.
_£__
wt.
JL..
wt.
%
wt.
"#
tirt. .
food
waste
4.4
-2971 '
-IIJ*-
43.0
-20^ _
38.6
_U._i
40.5
-^H.
37.0
10.2
32.0
-JSui
45.6
18.8
82. 5
12.0
42.6
13.7
58.8
13.4
38.9
_1°^2_
257o
10.0
40.0
••12±g-
i:35.^
garden
waste
8.2
"54.2"
>^8_
14.5
0.3
0.6
_2^5_
86.6
«_°i2
0.1
. °-Z_
2.3
0^2.
2.8
2.8
12 0
1.7
6.1
6i.
28.9
11.2
32.8
.13*6-
37.5
3.8
15.1
1.5
3,9
paper
32.0
"211.5~
_3JL4.
.141.2
42.7
79.0"
_28_i:L
133.2
_50.2
157.3
^iLJ.
133.1
30.2
132.3
40.6
143.7
46.6
201.1
39.0
113.8
48.0
"132.0
55.5
221.8
48.8
"la&.O
plastic
rubber,
et£. ,'
3.2
" 21.1
_ -i7,
13.8
3.0
6.6
^ JL°_
13.6
. -_5.J_
14.3
_J-i
22.9
8.1
24.0
5.9
25.7
5.1
18.1
— *il'
18.5
6.4
18.6
5.2
14.3
4.1
16,5
5.4
' Ttt.-
textile
0.4
"2.5 "
_3-I_
17.7
1.1
2.0
.^J_
0.1
0.4
1.0
JL-7
24.0 .
2.^
7.5
5.4
23.8
2 JL .
9.5
2.1
9.2
2.5
7.4
1.1
"3.0
1.0
"~4.(T
0.9
Si;3
wood
0.2
" I-0
0.2
0.6
0.1
" O.l"
2.0
6.9
0.1
0.2
0.5
1.6
0.1
0.3
2.1
9.1
0.0
0.1
0.0
0.0
1.0
3.0
1.0
"^B^"
0.3
1.0
0.4
me tali
4.b
30.0
. A.7,
33.0
8.2
15.1
-JL5-
15.3
10.0
27.0~
_5-6
30.1
10.6
31.6
11.1
48.5
12.5
44.0
8.4
36.4
9.0
26.4
10.6
"^.o-
8.0
32.0
,7.o
18.1
glass,
ceramic
2.b
iO "
A1-^
49.7
16.7
31.0
-I.2 .JL
40.7
16.5
"44.5
_2-8
30.7
JJ.6
40.5
114.8
64.8
16.0
56.8
8.6
36.9
10.6
30.1
8.7
•T5.0-
9.3
37.2
10.4
""25", 9"
ash9
S?&'
32.9
2L^70~ "
-^•3^
4.9^
0.1
0.1
2.8
9.5
- °li_
" 0.2^
0.0
0.0
0.5
1.5
2.5
11.0
1.6
5.8
2.1
9.0 "
2.7
"E3-
0.2
"!-ZT5"
0.6
2.2
3.5
9.0
fines
11.3
"7*75"
17.5
66.1
6.3
"11 T
_ 5_.£
19.- 0
- 4<8-..
" 13.0~
4.0
12.6
_ 3.7
11.1
6.4
28.2
-l-»
27.5
- 1^5
32.4
4.7
13.8
1.4
" TV
7.4
29.5
8.3
2173"
TOTAL
lUUJb
"^^..B
17775
"lS4.§
"339". 2
"iToTs

313.5
~2987c

437.^

354.2
"^3172
"^9i"7g
"*275.t
"3997:

2587S
en
                                                           * % is ^of wet weight,
                                                                                   l?v'*

-------
REFUSE COMPOSITION DATA
       CELL D
SAMPLE
DIG
•ncc
iJJ J
D63

TsT Jl C.
DlHp

D168
D211
D2S2

B358
0359
D420


D43o
D438
D456
T\UQO
tJ"yj


i
±. -
wt.
%
Wt.
*
Wt.
*
Wt.
%
wt.
_£_
wt.
J6
wt.
*
wt.
*
wt.
*.
wt.
-*-_
wt.
iJL--
wt.
-1
wt.
*
wt.
food
waste
_ 8_L-4
25.l"
16_*2
50.2
12^1
54.7
_ 15^2
4O
11.2
40.6
11.7
36.3
1Q.3.
30.7
6.1
43.0
_9.o
29.6
7.7
24.6
_6.J^
16.0
_ Ji9_
36.7
6.4
18.6
X . . .

garden
waste
JL8_
" 23.4"
^7
0.5
11.7
49.9
0.7
2.0
5.8
21.0
. _7-_2_
24,5
I'Ll
42.6
3.7
25.8
1^.0
49.6
0.0
0.0
_28. 3_
74.1
2.3
9.5
2.9
. ».5r
>.

paper
_ 58^5 _.
"174.3
46^0 .
142.0
37.5
16076
_J9^2-
121.9
46.3
167.9
Jt3i2.
136.8
45.8
136.2
44.9
315.8
48. 1_
161.1
46.7
148.9
. 33^^_
87.7
54.7
"226.7
42.4
123.2


plastic
rubber,
etc.
4.2 _
~12.4 "
r- *±2
15.1
L 3.8
IT: 4
4.5
13.8
7.4
26.8
_ _4-0_
" 12.5
3.6
10.8
6.0
42.0
3^
11.5
5.4
17.1
_ 3*1.
8.1
-JL5L
28.4
3.3
9.2


textile
0.8
2.5"
1.8
5.4
1.4
'.T.8
1.8
5.5
1.3
4.7
0.3
1.0
OJ_
2.0
1.3
9.4
o±3
•i.i
4.2
13.2
0.9
2.4
2.5
10.4
1 	 2.7
7.8


wood
, 1.1
3.2
0.4
1.1
0.6
273
2.4
7.4
1.0
3.6
0.6
1.8
°il
0.8
1.4
9.8
Q±3 .
1.1
1.3
4.1
1.0
2.6
1.0
4.3
5.0
14.6


metals
7.7
23.1
[11.3
35.0
10.1
•53.3"
9.0
27.5
8.7
31.6
11.5
35.7
8.2
24.5
8.2
58.0
7_i2
26.0
10.6
33.6
_L3__
19.2
9.6
40.0
15.3
44.3


glass,
ceramic
10. 2_
30.4"
14.4
44.7
11.9
IEL^I
15.9
48.7
,11.6
42.1
10.3
32.1
10.8
32.3
13.5
95.0
10.9
36.1
13.0
41.4
. 13*6.
35.6
10.1
' 41.8
13.7
39.6


ash,
as-
0.4
1.3 "
0.0
0.0
1.1
~" 4.8~
1.1
3.5
2.1
7.6
0.2
0.5~
1.1
3.2
2.7
19.3
0.0
0.0
.0.0
0.0
_ 0.0 ,
0.0 '
0.7
3.l"
1.0
3.0


fines
0.9
r~ 2.6'
4.8
15.0
9.2
39.5
9.5
28.9
4.6
16.7
_ Si.* -
29.9
4.9
14.6
12.2
86.0
4.4
14.7
11.1
35.4
_6.-3
16.4
3.3
"13.7
7.3
21.2


TOTAL
10656
~29~8~..3

309.0

""W.S

"30575

362.6
"311.1

297.7

704.1

330.8

"31875
"262~7l
~414".6

290.5


             * % is %of wet weight.

-------
                                             REFUSE COMPOSITION. DATA
                                                     CELL E
SAMPLE
E80
E86

E87
El 05
El 57
E250

E259
E276


E295

E33
E362
!
E407
E.V;
#
A _
wt.
wt.
%
wt.
JL.
Wt.
wt.
wt.
%
wt.
%
wt.
%
wt,
%
wt.
wt.
%
_,.
1
— »•• *• — • (
food
waste
44.0
40.9
10.9
35.2
21.9
_ 14 .Ja.
57.5
"~39^4~
40.6
141.2
10.5
35.6
2.J:
7.0
6.8
23.5
_8.2_
24.0
12.7
Oq.7
,
1
garden
waste
31.2
-JL-5.
17.5
8.7
28.0
_46.6_
203.0
~"i7~7i
llTT
1.8
6.1
26.5
90.2
53.4
140.1
42.3
147.0
6.2
18.0
1.9
6.C
11, ol
"a =K" "**
paper
134.5
~155~.3 '
46.0
148.4
71.6
149.3
1327?"
20.8
72.4
33.4
113.5
27.8
72.8
28.2
98.1
38_.7_
40.7
127.4
-??/a2-
plastic
rubber,
etc.
4.4
15.0
~1~4
3.6
11.5
_ JL8_
8.0
"15 .~8~
" 74. 5~
4.9
17.1
3.7
12.5
5.4
14.0
3.4
11.8
5.7
16.6
4.4
13.8 1
_ _»sLjjr ..
textile
4.4
1.0
3.9
1.0
3.4
0.2 _
1.0
1.8
7.0
_i_.3_
4.4
4.2
14.6
2.4
~8~.2
1.3
3.5
1.6
5.6
3.5
10.2
1.1
3.5
4.8
f— — — '-
l6'-(
wood
0.6
1.9
0.0
0.1
0.5
1.5
" ~o7i~
1.0
4.0
~oT5~
0.6
2.0
0.4
1.2
1.0
2.5
0.3
1.0
0.0
"oa
0.0
0.1
-2.
glass,
ceramic
16.7
57.0
12.2
48.0
11.9
38.5
	 &\0
35.o'
_ 12.8
" 50.5"
~~32.l
9,5
33.1
10.7
36.4
2.8
7.4
9.2
32.0
17. 1_
49.7
18.3
57.3
IT O £5
I f fl
»» "^L^-'L^
3, -=* -=
•f 4 * JL. 1
ash,
" 47? "
2.6
10. C
0.6
2.0
_ 6_._4
28.0
0.6
2.5"
_13aO
43.2
4.9
17.0
0.6
2.2
0.2
0.5
0.8
^ 2.9
JX5
1.5'
0.6
2.0
3Tc \
fines
6.0 _
20.5
19.8
77.5
6.8
21.9
12.4
54.1
12.8 _
"50.8
28.2
4.7
16.2
0.0
0.0
0.0
0.0
0.0
0.0
5.4
15.8
9.1
28.4
	 ."5 * .™,,
JU Of 1 1
TOTAL
_iqpj&_
341 .-9
1?~7

322.9
""436li
" 395^6
"331.8

347.7

339". 8

261.9

347.6
~29l7l

313.3
~337~Q
a;.

-------
c
err
                       REFUSE MOISTURE CONTENT DATA  -  CELL A
sample
no.
21
55
92
160
168
180
224
238
255
359
457
480


total
ret wt.
12.25
13.70
11.55
25.52
8.6?
10.66
12.41







total
dry wt.
7.69
9.80
7.38
17.59
6.55
8.15
10.14




.-j


%
moist
59.3
39.8
56.5
45.1
32.4
30.8
22.4








43
tt
O®
S3
Bfi
OB
o
T*M
CO
o®
8§
total wet
weight £
total dry
weight #
Jfcnoistxire

















•












                            Coinpoait of saaqples*
*>
f*»>
OJ
o®
OQ
total wet
weieht J
total dry
weight #„
jSmoisture












-

















                             Conposit of samples,
       % are % of dry weight.

-------
                  REFUSE MOISTURE CONTENT DATA - CELL B
sample
no.
11
14
78
125
178
186
187
255
265
336
365
370
439
495
total
•JA-f* Tiff*
VO v V* w *
13.45
7.61
7.41
4.94
6.59
5.93
6.27
6.60
5.39
4.81
5.90
7.00
5.64
10 .88
total
dry wt.
9.89
6.14
5.19
4.04
5.11
3.94
3.88
4.29
4.19
2.93
4.87
3.98
5.03
7.96
moist
36.0
23.9
42.8
22.3
29.0
50.1
61.6
53.9
28.6
64.2
21.2
75.9
12.1
36.7


P
01
31
n
total wet
weight #
total dry
weight #
^moisture
food
waste
10.02
4.04
L48.0
gardei
waste
7.10
4.42
60.3
Composit of samples , J


So,
a
oa>
8§
total wet
weight: $
total dry
weight #
J&aoisture
Composit of

•p
01
o®
88
OB
O(3
01
total wet
weieht #
total dry
weight #
^moisture

13.88
5.22
L65.9

10.44
6.47
61.4
paper
7.34
5.82
26.1
rHa-ah-?^'
nbber
6.80
5.90
15.3
i-11, B-14,B-
11.86
8.78
35.1
8.93
6.92
29.1
textiLe
6.60
4.98
32.5
•78, B-
8.88
6.61
34.3
samples, B-I78, B-186, B-187,
10.92
4.58
138.4
6.84
3.79
80.5
9.98
8 .00
24.8
8.53
7.22
18.1
9.48
6.49
46.1
wood
7.04
6.56
7.3
•125
7.25
6.45
12.4
metal
9.33
8.95
4.3

11.14
10.28
8.H
:eranic
8.36
8.33
0.5

11.56
11.47
0.8
ash,
rock
5.89
5.79
1.7

8.54
7.45
14.6
fines1
8.19
5.69
43.9

11.54
8.00
L4.3
B-255, B-265
7.67
6.40
19.8
9.86
9.28
6.3
11.73
11.62
1.0
5.03
4.38
14.8
10.87
7.14
52.2
* % are % of dry weight.
                        CompOSit Of samples, B-336, B=365, B-370, B-439, B-495

-------
                         REFUSE MOISTURE  CONTENT - CELL C
sample
no.
56
118
142
159
176
178
254
261
262
394
420
472
496
499
total
»et wt.
6.63
8.75
7.63
5.05
6.46
11.73
8.31
6.48
6.28
11.73
7.90
5.69
6.20
4.98
total
dry wt.
4.63
5.59
6.44
3.92
4.94
5.32
6.78
5.89
4.69
8.10
5.31
4.84
5.23
3.55
%
moist
43.2
56.5
18.5
28.8
30.8
120.5
22.6
10.0
33.9
44.8
48.8
17.6
18.6
40.3

4*
to
O

OH B & O Ej o<3 w total wet weight # total dry weight # ^moisture 18.60 7.88 136.0 17.25 8.98 92.1 16.46 13.34 23.4 10.36 9.15 13.2 14.42 11.91 21.1 6.35 5.72 11.0 16.34 15.38 6.2 16.80 16.65 0.9 15.48 12.30 25.9 16.54 10.65 55.3 Composit Of samples, C-254, C-261, C-262, C-394, C-420, C-472, C-496, C-499. 4> T**> n O


-------
                  REFUSE MOISTURE CONTENT - CELL D
sample
no.
10
55
63
145
168
211
252
358
359
420
438
436
456
493
total
ret wt.
6.93
4.06
5.42
5.76
7.28
8.36
6.70
17.01
17.01
6.80
9.51
8.59
8.97
DAT.
total
dry wt.
5.47
2.94
4.26
4.94
5.90
4.82
5.29
12.44
12.44
5.77
8.28
6.59
6.90
i LOST
%
moist
26.7
38.1
27.2
16.6
23.4
73.4
26.7
36.7
36.7
17.9
14.9
30.4
30.0



•P
n
Q
0)
O
-------
r
r:-  tr;  rr
I
-ex
                                                                 cr  .r
                 REFUSE MOISTURE  CONTENT.DATA -  CELL E
sample
no.
80
86
97
105
157
250
259
276
•29 5
338
362
407
432
495
total
*et wt.
8.38
9.84
9.95
6.67
10.54
3.39
7.00
6.53
2.52
4.52
5.15
4.48
6.41
9.5*
total
dry wt.
7.21
8.10
8.55
6.15
7.62
2.05
4.50
4.59
2.02
3.44
4.35
3.27
5.34
5.09
•%
moist
16.2
21.5
16.4
8.5
38.3
65.4
55,6
42.3
24.8
31.4
18.4
37.0
20.0
68.2


•P
CD
O
OH
So
OS
oca
n
total wet
weieht #
total dry
weight #
^moisture
15.09
7.50
101.2
14.20
7.75
83.2
14.34
11.49
24.8
9.21
7.47
23.3
13.47
10.09
33.5
samples, E-250, E-259, E-276,
7.54
3.32
127.1
4.69
2.21
U2.2
4.37
3.28
33.2
4.28
3.50
22.3 '
M -
%
i
H

5.03
4.23
18.9
E-295,
2.60
2.13
22.1
metal
10.37
10.16
2.1
glass
:eranic
13.28
13.21
0.5
ash,
rock
9.15
8.59
6.5
fines
13.03
9.82
32.7
E-157
12.41
12.08
2.7
14.40
14.17
1.6
11.43
10.53
8.6
8.34
5.61
48.7
E-338, E-362, E-407
3.86
3.63
6.3
4.52
4.49
0.7
5.71
4.60
24.1
4.18
2.42
72.7
                       Compos it of samples, 15-432, E-495
* % are % of dry weight.

-------
     APPENDIX F
MONITORING SCHEDULES
     124

-------
                         SUMMARY  SAMPLING  SCHEDULE
             Initial  Frquency  of  Analysis  for Various Parameters

                                               I n i t i a 1  Frequency
  Parameter
  K

  Na

  Ca

  Mg

  Hg

  Pb

  Zn

  Cu

  Cd

  Cl

  PCB

  pH

  Alkalin!ty

  COD

  BOD

  IDS

  TSS

  Settleable Solids

  NIt rogen

       Ammon i a

       Organ S c - N

       Nitrate - N
Leach ate
*

*

semi -mon th 1 y**

semi -month 1 y**
sen i -mon th 1 y**
*

sem i -mon th 1 y

semi -month ly

semi -mon th 1 y

semi -mon th I y

sem f -month ly

sem i -mon th I y

sem i -mon th 1 y


semi -mon th 1 y

semi -mon th 1 y

sem i -mon th 1 y
G roundwater
*

*

mon th1y**

month 1y**
*

*

*

*

*

semi-month 1y**
*

semi-month 1y

semi-mon th J y

month Iy**

month 1y**

sem i-mon thly

none

none


monthly**

none

monthly**
Preceding page blank
                                   125

-------
Parameter


Total Phosphate

00

Color

Volatile Acids

Fecal Col 1 form

Fecal Streptococci
                     Leachate


                     semi-month 1y

                     semi-mon thly

                     semi-monthly

                     mon th1y***

                     semI-month 1y**

                     semi-monthly**
Groundwater


none

none

none

none

month 1y**

none
**
***
           Baseline data to be collected monthly at least for the first
           six months.  The frequency of analysis will then be reeval
           uated on the basis of the available data.
Frequency of analysis may change as the data are reviewed
Baseline date to be collected at least the first *) months
within subsequent analysis depending on development of pH
alkalinity and BOD data.
                                      126

-------
  b
  >
  V?

  b
  il
  L
  II
j
8*  •
  u
  y
   u
!   U
Cel1 Location

CelI A - Bottom

     A - Middle

     A - Top



Cel1 B - Bottom

     B - Middle

     B - Top



Cel1 C - Bottom

     C - Middle

     C - Top



Cel1 D - Bottom

     D - Middle

     D - Top



Cel 1 E - Bottom

     E - Middle

     E - Top
 SUMMARY SAMPLING SCHEDULE


 Frequency of Gas Analysis

Commencing February 15* 1972



      Sampling Frequency •

      Quarterly

      Monthly

      Quarterly



      Quarterly

      Monthly

      Quarterly



      Quarterly

      Monthly

      Quartly
      Monthly



      Quarterly

      Monthly

      Quarterly
            No gas samples can be withdrawn  from  these  probes  due  to  fluid
            Interference.  Attempts  in January  1972  to  remove  fluids  encount-
            ered  in these probes were unsuccessful.  Attempts  will  be made
            periodically to withdraw samples.
                                           127

-------
                            SUMMARY SAMPLING SCHEDULE
                     Frequency of AnalysIs for Various Parameters
Parameter

K
Na
Ca
Mg
Hg
Pb
Zn
Cu
PCI
pH
Alkalinity
COD
BOD
TDS
TSS
Settleable
Commenting February 15, 1972
i ""•"_,
Leachate , Gfoundwater
Cells A
6-week
6-week
6 -week
6 -week
6-week
6-week
6-week
6-week
6-week
6-week
6-week
6-week
6-week
6-week
6-week
C A 1 1 «l e - - - - -

, B ft € ^ells C * D
intervals
intervals
intervals
intervals
intervals
intervals
intervals
intervals
intervals
intervals
Intervals
intervals
intervals
intervals
intervals
monthly
monthly
semi-monthly
. semi-monthly
monthly
monthly
monthly
monthly
semi -monthly
quarterly
semi-monthly
semi-monthly
semi-monthly
semi-monthly
semi-monthly
semi-monthly
quarterly
Wells 1 thru *»
A & E Subdraln
Water Supply
Cell C
quarterly ^
. quarterly. ^
' quarterly "" - '
quarterly
quarterly
quarterly
quarterly
quarterly
quarterly
semi -annual ly
month ly
quarterly
quarterly
semi-annual ly
quarterly
quarterly
Nitrogen
  Ammon i a
  Organic N
  Nitrate N
Sulphate
Tot. Phosphate
DO
Color
Volatile Acids
Fecal coliform
                 6-week intervals
                 6-week intervals
                 6-week intervals
                 quarterly
                 6-week intervals
                 6-week intervals
                 6-week intervals
                 6-week intervals
                 quarterly
Elect.  Conductivity  6-week intervals
Fecal  Streptococci   semi-annually
semi-monthly
semi-monthly
semi-monthly
quarterly
semi-monthly
semi-monthly
semi-monthly
monthly
quarterly
semi-monthly
semi-annually
semi-annually

semi-annually
quarterly

monthly
semi-annually
monthly
semi"annually
^Initial test of Cell A leachate will include all parameters listed in
 December 1971 schedule In addition to those listed above,
                                    128

-------
                            SAMPLING SCHEDULE
                   Frequency of Fluid Sampljng & Analysis
                            Revised May, 1973
Parameter
                      Leachate
               Cells A, B 6 E
                                 Cells C & D
                  G roundwater
                  Wells 1  thru k*
                  A £ E Subdrain*
                  Water Supply
                    Cel 1 C
Alkalin!ty
B.O.D.
Cadmiurn
Ca1c i urn
C.O.D.
Chloride
Copper
               o-week Intervals
               6-week Intervals
               6-week i nterva1s
               6-week i n te rva1s
               6-week i nte rva1s
               6-week Intervals
3-week intervals
3-week intervals
6-week intervals
3-week intervals
3-week intervals
3-week i n te rva1s
6-week intervals
               6-week i n te rva1s
Dissolved Oxygen 6-week intervals 3~week intervals
Electri cal
Conductivity   6-week intervals  3-week intervals
Fecal Coliform semi-annually     semi-annua11y
Fecal Streptococci semi-annually semi-annually
Iron           6-week intervals  6-week intervals
Lead           6-week intervals  6-week intervals
Magnesium      6-week intervals  3-week intervals
Mercury        6-week intervals  6-week intervals
Nitrogen-Ammonia 6-week interva1s 3-week intervals
Nitrogen-Organic 6-week intervals 3-week intervals
Nitrogen-Nitrate 6-week intervals 3-week intervals
Phosphate-total ,
          as P 6-week intervals
P.C.B.
Potass i urn
Sodium
Sol 5 ds-Total
  DIssolved
               semi-annua11y
               6-week intervals
               6-week intervals
3-week i n te rva1s
semi-annual 1y
6-week intervals
6-week intervals
               6-week intervals  3-week intervals
                                 quarterly
                                 quarter ly
                                 quarterly
                                 6-week intervals
                                 6-week i nte rva1s
                                 3-week intervals
Sol ids-Settleable  	
Total Sulphide quarterly
Sulphate       quarterly
Volatile Acids 6-week intervals
Zinc           6-week intervals
pH             6-week intervals
quarterly
sem i-annua11y
quarterly
quarterly
quarterly
quarterly
quarterly
6-week intervals

6-week intervals
semi-annua11y
semi-annua1ly
quarterly
quarterly
quarterly
quarterly
semi-annually

semi-annually
(9nly if detected
 in eel 1 s)
quarterly
quarterly

quarterly
                  quarterly

                  quarterly
                  6-week intervals
*D.O.,  E.C.  6 pH to be run quarterly on Well  *» and A 6 E Subdrain.
                         129

-------
                       SAMPLING SCHEDULE
            Frequency of Gas SampHng6AnalysI
                       Revised May, 1973
Gas Probe Location
Cell  A - Middle
Cell  B - Middle
Cell  C - Bottom
CelID- Top
Cel1  E - Middle
Sampling Frequency
6-week Intervals
6-week intervals
6-week intervals
6-week intervals
6-week intervals
                           130

-------
                                            APPENDIX
 "".                               ANALYTICAL METHODS AND PROCEDURES

 w •      '                        FOR CHEMICAL ANALYSIS OF LEACHATE,


•L                                GROUNDWATER AND GAS  SAMPLES FROM

"4^                             SONOMA COUNTY CENTRAL DISPOSAL SITE


 j                                   SANITARY LANDFILL TEST CELLS
 i f
"w
 ^                                        December 1971

                                       Revised February 1972

-w                                      Revised June 1972

  »                                      Revised June 1973
                                          131

-------
                           TABLE OF CONTENTS



GENERAL

SAMPLING PROCEDURES AND PREANALYTICAL PREPARATION

     Sampling Procedures
     Sample Procurement
     Sample Preservation

ANALYTICAL METHODS AND PROCEDURES
     Detection Limits
     Alkalinity
     Biochemical Oxygen Demand
     Calcium and Magnesium
     Chemical Oxygen Demand
     Chloride
     Color
     Dissolved Oxygen
     Electro-Conductivity
     Fecal  Coliform
     Fecal  Streptococci
     Gas Analysis
     Heavy Metals
     Nitrogen
         Ammonia
         Organic Nitrogen
         Nitrate Nitrogen
       pH Measurement
       Phosphate (total)
       Polychlbrinated Btphenyls
       Sodium and Potassium
       Sulphate
       Settleable Solids
       Total Dissolved Solids
       Total Suspended Solids
       Volatile Acids

  BIBLIOGRAPHY
Page

133

133

133
134
134

135
135
 136
 1?6
 137
 137
 138
 138
 138
 140
 141
 142
 142
 143
 146
 146
 147
 147
 150
 152

 155
 155
  156
  156
 156
  156

  157
                                132

-------
                                 GENERAL








          Unless specifically noted, each analytical method is used to determine



the specific constituent in ail aqueous samples involved in this investigation.



The taking, handling, and preservation of samples prior to analysis will vary



according to the nature of the sample and constituent to be measured.  Pre-



analytlcal preparations may require acidification, dilution, addition of a



preservative,or filtration, to name some possibilities.



          The samples handled in this research project include a broad range



of concentrations and sample conditions.  The analytical problems encountered



Include predicting the proper dilution ratio when samples are too concentrated,



estimating sample volumes when low concentration of a given constituent is



expected, and changing analytical procedures or methods when interferences



occur.  It may sometimes be necessary to use several methods for the same



species, shifting the method to suit the special sample conditions.








            SAMPLING PROCEDURES AND PREANALYTICAL PREPARATION






Sampling Procedures



          In all cases and at all times taking and handling samples should be



done  In a manner which reduces to a minimum the possibilities for contamination



and at the same time reduces to a minimum the time between sampling and analysis.



The importance of conducting analysis as soon after sampling has been completed



cannot be overemphasized.



          Since there will  be a significant time interval (several  hours)



between sampling and analysis, the samples for certain time dependent tests



must be preserved in some manner to assure that the error due to chemical  and



biological change is held to a minimum.  The methods used in this investigation



are generally accepted and widely used (1, 2).

-------
Sample Procurement



          Samples, with the exception of those obtained for bacteriological



tests, are collected In all-glass bottles with caps haying plastic or foil



liners.  The glass sample bottles are prepared for use by rinsing in warm



dilute HC1 followed by a rinse with tap water.and several rinses in distilled



water.  When sufficient sample volume.is available, the bottle Is rinsed at



least once with the sample fluid before filling the bottle .to overflow capacity.



The samples are then prepared according to specific preanalytical procedures



described below.



        Samples taken for bacteriological tests are collected in 125 ml  plastic



bottles with plastic caps.  The bottles are prepared In the laboratory before-



hand by washing and sterilization as described In Standard Methods  (pg. 403).








Sample Preservation



          Depending upon the test series to be run, from one to four



samples are taken from each source for chemical analysis.  All samples are



stored on ice or under refrigeration at or below *» c until tested.  A pre-



servative, HgCl-f in a concentration of *tO mg/1 of sample is added to samples



to be tested for the following components:







     Alkalinity               Ammonla-N     Sulphate



     Chemical Oxygen Demand   Organic-N     Total Dissolved Solids



     Calcium                  Nitrate-N     Total Suspended Sol ids



     Magnesium                Phosphate     Settleable Solids



     Color                                  Volatile Acids
*  Hereinafter reference to Standard Methods indicates Reference 1
                                       134

-------
u
                  The detection limits listed below arc the minimum detection limit*
            valid for normal operating procedures in the laboratory.  This list is
            provided as a guide for the evaluation of th* analytical procedures.
• \ > . : 'V :- '';.. •'''! I'O ,? •?• .•.;.:•.? ,'
* Comoonent Detection
- vWtflfVI H*l 1 W ww-™^— ••— • •— -^ (
; - — • ^ -trtttfv.'.' ''^. • ••
i , •
W Cd 0.05
Cu 0.02
I , • .v.-.J i. •
-^ . Fe ^ - . • • ,•::,- ^0-v..-:-,^-,;--v-:
Hg ..:-.-.'W: JM5^7? .-.. • .,;,;
L K ' 0.1
*•* • . '• ••••.<:>•>& "s..>> ^o; •'.'-.-•• i .-•-; -1
1 Mig 0.05
.; ; Mn ' 0.1 . -^' •;•
^^^ .. A AC
' -Na •. .-.. . • -r. ;7.- "-:••;>?• •:&$*^wAf\u ,:ni';U
j l . . ". Pb . .'. ._ ,0.1
'\ 4 -' ' •"• ' '" • • .'"•. -; -": •:•' ' i;> \-; j w ;is 31*; ,V J S^ 7 • " '"' -, •'•
w Zn 0<01
•j r< •• ' •' ' alkalinity -.•••• -:- -"••'* -£\^ ^•.'u.-i--. •.-.•;
'•' W . ' , BOD '.'.,'• •''. ;.;-.«" rll ti>f-1fo^?v -V"- V!
Ca 1
' :• ' ; '.-"..' •-'. '}^^r:^^ B .•; VKV. s..>;; '' ,- ^.- •-
U COD '
J ' Color' ' • • " j,<-e^,r^ ,:••:••'.
\ Vf- ' Cl ^.HO'-!Jj;a ooa a.,TA>'.:-:
,! W<
Dissolved Oj v;-|.; v-. ^^P^^ ;-
:;-; '' , .Nitrogen - NH- 	 :'.!£•: ,.. 	 	 0^5 .i:-l-..i'L;-;-L.
J y j • .. * f .... .,., ' ;. .(
Nitrogen - Orgatilc ; 0.5
v Phosphate (as P) ^ 0.5
! -^ Solids - TS ^ 5
i • , . Solids - IDS ? 5
U Solids - TSS 5
. : Solids - Settleable 0.2
1 U s°j, ' :" 5
W <|
Volatile acids 50
Unit

mg/1
•" mg/ih '•'-•--v'--'- •••
• * . «
- -flig/Ttr.; .• !.'- ':'-: r
>H9/V ;
mg/1
"'•".•.•;.(' - , i
nig/1
•••••ing/iv' ^ ^- -..:-
ma/ 1
.-;:^^?j-!;:;v.l; 'KM
mg/1
"-" 'mg/t "'T': '
mg/i as CaCO^
, ^
mg/1
mg/1 '
color units
- m9/1
,!r,.mgt?tft.,,._
•|r- rtg/loas -»:•);:;-.;
»-T -- 	 »»Wy. ,^>j ..»,...- ^. . :,„.,., ,^,. ,, ...u,, -..
mg/1 as N
mg/1 as P
mg/1
mg/1
mg/1
' i' -. .'•!••
ml/I; •
mg/i
mjg/1
  U
                                             135

-------
                     ANALYTICAL METHODS AND PROCEDURES


 Alkalinity

           Alkalinity is determined by potent lometr I c titratlon using a pH of

 4.2 as the end point.  The general method described  In Standard Methods

 (page 52) is used*  A sample size of 50 or 100 ml Is used, depending on the

 alkalinity of the sample.  For samples of high alkalinity a 10 ml  sample Is

 diluted up to 50 or 100 ml and then titrated.


 Biochemical  Oxygen Demand (BOD)
                                                /
           The biochemical, oxygen demand (BOD) determination is conducted

 according to the procedure given in Standard Methods (page 489).  The direct

 pipetfng or dilution method js selected for preparing BOD samples  based upon

 the estimated ultimate 5-day BOD.

           For samples containing unknown BOD strengths it is necessary to

 prepare a range of dilutions so that the actual value will be bracketed.

 Generally three dilutions are required to assure adequate coverage of range.

 If the BOD can be reasonably estimated, the range of dilutions can be narrowed

 somewhat, but it Is usual 1y best to take a conservative approach.   The follow-

 ing table will aid in preparing dilutions:

                         ESTIMATED BOD DILUTONS*
                   0.05                     12,000 - 42,000
                   0.10                      6,000 - 20,000
                   0.20                      3,000 - 10,000
                   0.50                      1,200 -  4,200
                   1.0                         600 -  2,000
                   2.0                         300 -  1,000
                   5>0                         100 -    400
                   10.0                         60-    200
                   20.0                         30-100
                   50.0                         10 -     40
                  100.0                          5 -     20
                  300.0                          0 -      7
*  Modified and shortened from Sawyer R McCarty,  Chemistry for Sanitary
   Engineers, McG/aw-HilJ.  2nd ed..,  1967-
                                     136

-------
Calcium and Magnesium

          The concentrations of calcium and magnesium are determined by

complexometric titration with EDTA.  There Is the strong possibility of

Interference from dissolved heavy metals (e.g., Cu, Zn, Ni, Fe, Pb).  This

interference is overcome by complex ing the metals with cyanide.   Routine

addition of sodium cyanide solution is utilized to prevent potential metallic

Interference.  The procedure is described in Standard Methods (page 181).  When

sample volumes to not permit titration techniques, Atomic Absorption Spectro-

photometry (AAS)  should be used to conserve the sample volume for measurement

of other parameters.  The methods described in Standard Methods (page 211) and

elsewhere   can be used.  Where highly colored leachate samples are obtained

It may be necessary to analyze Ca and Mg by AAS to avoid color Interferences

with the EDTA method.



Chemical Oxygen Demand (COD)

          The dichromate reflux method, Standard Methods (page 495). has been

selected for the  chemical  oxygen demand (COD)  determination because It has

advantages over other oxldants in oxidizabi1ity, applicability to a wide

variety of samples, and ease of manipulation.

          The test Is performed with the following modifications:

      1.  Sample  and reagent volumes used are 20 ml  aliquot of sample, 10 ml

          of 0.5N K.Cr 0   and 30 ml  of H.SO.  containing Ag SO. .

      2.  The maximum COD  concentration which can be determined using the

          20 ml aliquot sample is 2000 mg/1;  for COD concentrations greater

          then 2000 mg/1,  smaller volumes of  sample diluted up to 20 ml  with

          distilled water  should be used.
* CAUTI ON;   Cyanide is a strong poison and great care should be exercised
            when handling.
                               137

-------
      3.  The standard ferrous ammonium sulfate tltrant should be approxi-

          mately 0.10N In concentration.  Frequent standardization Is required.

      k.  When the data  indicate a COO consistently below 500 mg/1, the normal

          procedure described in Standard Methods (page *»95) is to be employed.



Chloride

          Because of the interferences expected in leachate samples, the

method used for chloride analysis is the Mercuric Nitrate procedure.  It is ex-

pected that orthophosphate, sulfide, and sulfite ions will be in sufficient

concentrations so as to  interfere with the Argentometric titration technique.

The procedure as outlined in Standard Methods (page 97)  is used.  The presence

of sulfltes interferes.  If the presence is suspected, oxidize by treating

50 ml sample with 0.5 to 1.0 ml  of  30 percent H20».   This method Is  used for

both leachate and groundwater samples.

          Experience has indicated that potentiometric titration of Cl with

a Ag/AgCl electrode system is the best procedure when color interference is

too great to allow colorimetric determinations.  Discussions of potentiometric

titration techniques for Cl are readily available (12, 13)-Both methods are used

for chloride analysis depending on the color  interference.  The procedure  in
Standard Methods  (pg 377)  is used for potentiometric  titration of Cl.
Color
                                 <
          Color is measured according to the Platinum-Cobalt method described

in Standard Methods (page 160).



Dissolved Oxygen (DO)

          Most leachate samples are highly colored and it is therefore not

possible to use the Winkler Method of analysis.  A field oxygen probe is used

for in-situ measurement of oxygen in both leachate and groundwater samples.
                                       138

-------
                      Dissolved oxygen  is measured  In  the field using a  battery operated
 :           Yellow  Springs  Instrument Co., Model  51A Dissolved Oxygen Meter.  The  Instru-
•*   •                ••                                       •                        '
            ment  is equipped with a combination  temperature, oxygen probe.  Temperature
      *     can be  read to  0.3° C and dissolved  oxygen can  be read to 0.1 ppm.
 \                     Below is a detailed description  for use by field personnel who will
      »     be making the in-situ DO measurements:
                  1.  Calibration of DO meter.
K'                       -
                      a. Check the probe to assure  the membrane is not damaged.  Should
                         the membrane be damaged, it can be replaced following the pro-
rt                            .                               '..''-.
                         cedures outlined under  "Preparation for Operation" In the
                         Instruction manual.
J
                      b. Connect the probe cables to the instrument.  The oxygen-temperature
                         probes have two connectors of different sizes so they cannot be
it              -               '                                 ''•-'.
                         incorrectly attached to the Instrument.
                      c. With the instrument OFF check mechanical  zero of meter and adjust
                         if necessary with the screwdriver adjustment in the lower center
                         of the meter bezel.  Perform the adjustment with the instrument
                         In the position it will  be used.
 '   '                  d. Turn the selector switch to ZERO and adjust the meter to zero
«•                                  •
                         with ZERO adjustment knob.
                      e. Turn the selector switch to FULL SCALE and adjust the meter to the
                         full scale position (15  ppm on the meter).  If the meter cannot be
                  •       adjusted to full scale,  replace the batteries.  ' '
j                                       '..-'_'                  '
                      f. Set the selector switch  to CALIB Q£ with the probe in an envlron-
 '                        ment of 100 percent relative humidity.  This can be accomplished
                         by placing the probe in  the storage container partially filled
 •     *                  with water, taking care  that the membrane is not immersed.  Leave
                         the probe in this position for a period of 5 minutes to polarize
                         it before making further calibratIons or measurements.
!     •»               '
                      g. With the CALIB knob, set the meter pointer to the mark for the
                         local  altitude.
                                              139

-------
      2.  Measurement of Sample 00 Content.
          a.  Calibrate DO meter as outlined in calibration procedures.
          b.  Place the probe in the water sample at the measurement site. To
              induce a flow of water across the membrane, raise and lower the
              probe.
          c.  Turn the selector switch to TEMP and read the temperature from       ^
              the lower meter scale.  Record temperature.
          d.  Set the 02 SOLUBILITY FACTOR dial to the observed temperature,
              taking care to use the appropriate salinity index (each section
              of the bar on the 02 SOLUBILITY FACTOR dial represents 5,000 ppm
              chloride concentration.)  Previous analytical  data on chloride
              concentration should be used to estimate appropriate salinity
              Index setting.
          e.  Turn the switch to 02 and read the dissolved oxygen value In
              ppm directly from the meter dial.  RecordI dissolved oxygen value.
          f.  To perform a series of measurements in a short time at about the
              same temperature (within 5° C of calibration temperature), re-
 •;             calibration Is not required and performance will  not be degraded.
              To take readings, simply repeat steps b, c, d, and e.


Electro-Conductivity (EC)
          Electro conductivity is measured in the field using a battery operated
Beckman, Type RB3, Solu Bridge.  The instrument is equipped with three conduc-
tivity probe cells which provide a measurement range of from 50 to 200,000 micro-
mhos/cm.       .
          Below Is a detailed description for use by field personnel who will
be making the In-sltu E. C. measurements:
      1.  Check the battery by depressing the battery check switch and the
          ON-OFF button simultaneously.  The needle of the battery check meter
          should deflect to the right (positive) and come to rest In the green
          zone.
                                           140

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      2.  Set the manual temperature compensator to the solution temperature



          as measured by a thermometer or the reading from the 0.0. meter.



          Record the temperature of the sample.



      3.  Connect the two lead wires of the conductivity probe cell to the



          two Instrument terminals.  Either lead wire can be connected to



          either terminal.



      A.  Remove the protective end cap and Immerse the conductivity probe



          cell In the solution to be tested to a point at least one-half



          Inch above the cell air vent.  Move the cell up and down in the



          solution once or twice to insure removal of air bubbles from within




          the cell.



      5.  While depressing the ON-OFF button, rotate the main scale knob until



          the meter needle is opposite zero on the scale.  Release the button.



      6.  Read the scale value opposite the index mark on the main scale knob.



          Determine the electro-conductivity by applying the appropriate con-



          ductivity probe cell factor to the scale value.  Record electro



          conductivity.



      7.  Results can be checked by using another conductivity probe cell.  The



          probe that provides a reading nearest the middle range of the scale



          should be used.



      8.  Clean the probe before storing by rinsing with tap water several times.



          If this is not done, a film may build up on the probe.








Fecal Col I form



          The multiple tube dilution technique is used for the Fecal  Coliform



Test.  Lactose broth is used for the presumptive test.  The confirmed test



utilizes the boric acid lactose broth.  Details are given in Standard Methods



(page 669).   Data are reported as Most Probable Number (MPN) per 100 ml with a




95% confidence limit.



                                    141

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Fecal Streptococci
          The Multiple-Tube Technique is used for Fecal  Streptococci  analysis.
The Membrane Filter Technique could be used equally well.   The procedure used
for the presumptive test, confirmed test, and forvcomputing and recording the
MPN per 100 ml of the samples is given in Standard  Methods (page 689).


Gas Analysis
          Gas samples from the landfill  cells are collected in the field and
are analyzed in the laboratory using a gas chromatograph system for gas-liquid
partition chromatography.  The gases analyzed for are C^i CH. , N2, H_S, 0_.
          Sampling Procedure:  Gas samples are collected in the field in 250 ml
glass gas sampling tubes.  The principle is to draw the  gas sample into and
through the sample tube under a vacuum and to seal  the container when a repre-
sentative sample has been collected.  Procedure for collection of gas samples
is as follows:
      1.  Connect tubing from gas probe to gas sample tube inlet.
      2.  Connect the suction end of the field gas  analyzer to gas sample tube
          outlet.
      3.  Open stopcocks on both ends of gas sampling tube.
      U.  Switch on field gas analyzer and draw sample through gas sample tube
          into gas analyzer until parts per million reading remains fairly con-
          stant, but for not less than one minute.  (Pumping rate is approximately
          1400 ml/min.)
      5.  Close sample tube outlet stopcock.
      6.  Close sample tube  inlet stopcock.
      7-  Disconnect the gas sample tube outlet from the field gas analyzer.
      8.  Connect the hand vacuum pump to the gas sample tube outlet.
      9.  Open the stopcock at the outlet of the gas sample tube.
     10.  Pump with the hand vacuum pump for 20 repetitions (equal to approxi-
          mately 26" of Mercury pressure) to evacuate the sample tube.
                                       142

-------
               11.  Close the stopcock at the outlet of the gas sample tube.


L             12.  Reconnect and switch on the field gas analyzer.


               13.  Open the inlet stopcock, then the outlet stopcock of the gas sample

!j *                tube.


               14.  Continue pumping for 30 seconds.


*"•* «           15.  Close sample tube outlet stopcock.


  ,             16.  Close sample tube Inlet stopcock.
vJ
               17-  Disconnect gas sample tube from gas probe and field gas analyzer;

                    Care should be taken not to disturb either stopcock while trans-
-~
                    porting and handling the gas sample tube.  Record on the gas sample

 •                   tube the container number, sampling location, and date.
Connect to
Gas Probe -^

Gas Sample
Tube -7
O -^ ~^- -JE
'"' 4"V y~~^
L- Inlet
Stopcock

-Outlet
Stopcock

Gas
Analyzer

           Heavy Metals



                    All field samples require preanalytleal  treatment consisting of the


           addition of 5 ml  1:1  UNO* per liter of sample.  The acid is placed In the


           collecting container  prior to collection and the sample bottle Is filled to


           the top and capped.


                    Analysis for five heavy metals (Hg, Pb,  Zn, Cu, Cd) is done by


           Atomic Absorption Spectrophotometry.  Pb, Zn,  Cu, and Cd are run by the normal


           flame method as described In Standard Methods  (page
                    Mercury Is analyzed for by the flameless atomic absorption technique


           similar to that prescribed by EPA Methods (page 121).   Additional  information


           on this technique  is available (6, 7).  Details of the analytical  procedure


           are presented below:
          *  Hereinafter  reference  to  EPA  Methods  indicates  Reference  2.


                                             143

-------
                         Total Mercury Analysis

          The  following method for  the determination of Mercury  in  solution
employs a preanalytlcal acid oxidation procedure  followed by a simple
reduction aeration procedure to produce and  introduce elemental mercury
                                                •'•'•-:'•--•    :           '    .' •
ftfftif  Inte • fletfthrough »y»tem where the absorption at 253.7 nm  is measured
in a quartr-windowed cell.  This method applies to both groundwater and
                                       "':-..•••...;.     -  • •            ', .
leachate samples, although the sample volume may  have to be increased for  the
                                     •         • .-'•.-     ' '       '         ..
groundwater samples.
          The  range of the method may be varied through instrument and/or
recorder expansion.  Using a 25 ml  sample, a detection limit of l.Ojug Hg/1
can be maintained.  Concentrations  below this level should be reported as
<1.0.
             .     •  • •    -                               .             .
      1.  Acid Oxidation Procedure
          a.  Place a sample aliquot of 25 ml in  a 100 ml Erlenmeyer Flask.
               If necessary, a diluting solution is added to bring samples  up
              to a convenient volume.
          b.  Add 5 ml acid splution, 2 ml potassium persulfate solution and
              several  drops of potassium permanganate solution.  Cover or
              stopper the flasks and allow solutions to stand at least 2k
              hours at room temperature.                                    .
                                      . •          .                    .  .     .
          e.  Add several drops of  potassium permanganate solution.  DIge.s-
              tlon Is considered complete whin th« pink KMnO^ color remains
              at least one hour.  The sample is now ready for analysis.

      2.  Ana 1 y t i ca 1 P roced u re
          a.  Transfer the sample to the volItllization cell (see figure).
              Seal the volitilization cell.
          b.  Add 10 ml of reducing solution by syringe.  Several blanks
                               .     '      •                ••••'..        '
              are prepared by treating 25 ml altquots of dilution water
              exactly like the samples.
                                        144

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3.  Calibration
        Each and every time samples are run, at  least three standard
    mercury solutions (0.5, 1.0, 1.5>jg Hg) must be run to calibrate
    the system.
    a.  Add desired amount of standard mercury solution to the volatili-
        zation eel 1.
    b.  Add sufficient dilution water to give about 25 ml total volume.
    c.  Add 5 ml acid solution.
    d.  Seal the volatilization cell.
    e.  Add 5 ml of the reducing solution by syringe.

A.  Calculation
    a.  Determine the peak height of the unknown from the strip chart and
        read the mercury value from the standard curve.   The standard
        curve is prepared by plotting the peak height of standards versus
        the micrograms of Hg.
    b.  Calculate the mercury concentration in the sample by the following
        relationship:
                 jug Hg/1  = jug Hg In Aliquot x  . .100°	=	
                x~s  a    /-a  a       T      aliquot volume
5.  Reagents
    a.  Acid Solution.  2:1  by volume ratio of concentrated sulfuric
        acid,  H2S0lt,  and  nitric acid, HNO_.
    b.  Diluting Solution.   Add 1  ml  concentrated perchloric acid to one
        liter  distilled  water, and add a few KMnO.  crystals to just give
        a faint pink  color.
    c.  Potassium Permanganate Solution.  5% solution, w/v.  Dissolve-pt
        5 gm KMnO,  in 100 ml  distilled water.
    d.  Potassium Persulfate Solution.  5% solution,  w/v.   Dissolve
        5 gm «2S Og in 100 ml  distilled water.
    e.  Reducing Solution.   To 2 liters of distilled  water add 250 gm
        SnCl.,  150 gm NH  OH-HC1, 150  gm NaCl,  and 100  ml  of concentrated
        H2SV
                            145

-------
         f.  Stock Mercury Solution.   Dissolve 0.135^ gm of mercuric chloride
             in 75 ml  of distilled water.   Add 10 ml  of concentrated nitric
             acid and  adjust the volume to 100 ml.  1 ml  - 1  mg Hg
         g.  Standard  Mercury Solution.  Make the appropriate dilutions of the
             stock mercury solution to obtain a working standard containing
             0.1 jug per ml.  This working standard and the dilutions must be
             prepared  fresh daily.  The acidity of the working standard
             should be kept at about  0.15% nitric acid.  This acid should be
             added to  the flask as needed  before the  addition of the aliquot.

     6.  Apparatus
         a.  Atomic Absorption Spectrophotometer.  Any atomic absorption unit
             which is  capable of accommodating the cold vapor ceil.   Instru-
             ment settings recommended by the manufacturer should be followed.
         b.  Hg Hollow Cathode Lamp.
         c.  Recorder.  Any multi-range variable speed strip chart recorder
             compatible with the Uv detection system  in use.
         d.  Cold Vapor Absorption Cell.  Suitable cells may be constructed
             from standard spectrophotometric 10 cm cells having quartz end
             windows or may be constructed from plexiglass tubing making sure
             to use quartz end windows that are perpendicular to the line of
             light.  See Reference 1,  6, or 7 for exact details.
Nitrogen
         Ammonia.   The preliminary distillation method is used for ammonia
as described in Standard Methods (page 229).   The distillation method covers
the determination  of ammonia-nitrogen exclusive of total  Kjeldahl  nitrogen.
This method covers the range from about 1.0 to 25 mg/1 when the titrometric
end point is used.  Since most leachate samples will  contain NH -N in the
range 100-600 mg/1, it will  be necessary to use small  sample volumes (20-AOO ml)
and dilute with ammonia-free distilled water up to 500 ml.

-------
H
V                     Organic Nitrogen.  Organic Kjeldahl  nitrogen is defined as the
   k                                                           .
.  |            nitrogen converted to ammonia from nitrogen components of biological origin
u .                   .  ;
              such as amino acids, proteins and peptides, but may not include the nltro-
f    ,        genous compounds such as amines, nltro compounds, hydrazones, oxlmes, semt-
              carbazones and refractory tertiary amines.   Organic Kjeldahl  nitrogen Is
1 \ |                 •.•''•
U   ^        determined after distillation of free ammonia from the sample.  The method
              used Is described in the EPA Methods (page  149) and is similar except for minor
              details to the procedure detailed in Standard Methods (page 244).
'*; .                    Nitrate Nitrogen.  The Brucine Method employed for the measurement
              of nitrate nitrogen is described in EPA Methods (page 170).  This method is
^            based upon the reaction of the nitrate ion  with brucine sulfate  in a
j             13N H«SO.  solution at a temperature of 100° C.  The color of  the resulting
u
              complex is measured at 410 nm.  Temperature control  of the color reaction is
fj            extremely critical.  Details of the analytical procedure are  presented below:
                                          Brucine Method
^                     This method is applicable to the analysis In both groundwater and
.   •           leachate samples.   Modification can be made to remove or correct for
LJ                     ..                               .
              turbidity,  color,  salinity,  or dissolved  organic compounds in samples.  The
* '            range of the  method Is 0.1  to 2 mg/1  NO.-N.
«—                    .                          . •    3                                '
             '     '     Samples may be preserved for several  days by the addition of 40 mg/1
^            HgCl2 and  storage at 4°C.   Analysis should  not be delayed more than a week.
t                  I.   Points  to Note.
                       a.   Dissolved  organic  matter  will  cause  an  off  color  In
                           and  must be  compensated for  by additions  of all reagents  except
                           the  bruclne-sulfanllIc acid  reagent.  This  also applies to
                           natural color  present not due  to  dissolved  organlcs.
                       b.   The  effect of  salinity  is eliminated  by addition  of  sodium
                           chloride to  the  blanks, standards, and  samples.
                 Brucine Sulfate  Is  toxic;  reagent bottle should be marked with warning;

-------
    c.  Ferrous and ferric Iron and quadrivalent manganese give slight
        positive interference.  In concentrations less than 1  mg/1
        these are negligible.
    d.  All strong oxidizing or reducing agents interfere.  The presence
        of oxidizing agents may be determined by the addition  of ortho-
        tolidine reagent.
    e.  Uneven heating of the samples and standards during the reaction
        time will result In erratic values.   The necessity for absolute
        control of temperature during the critical  color development
        period cannot be too strongly emphasized.

2.  Analytical Procedure
    a.  Adjust the pH of the samples to approximately pH 7 with 1:3
        acedic acid and, if necessary, filter through a 0.5^/j pore
        size filter.
    b.  Set up the required number of matches tubes in the rack to
        handle reagent blank, standards and  samples.  It Is suggested that
        tubes be spaced evenly throughout the rack to allow for even flow
        of bath water between the tubes.  Even spacing of tubes should
        assist in achieving uniform heating  of all  tubes.
    c.  If It Is necessary to correct for color or dissolved organic
        matter which will cause color on heating,  a set of duplIcate
        tubes must be used to which all reagents except the brucine-
        sulfanilic acid has been added.
    d.  Pipette 10.0 ml or an aliquot of the samples diluted to 10.0 ml
        into the sample tubes.
    e.  If the samples have high dissolved solids,  add 2 ml of the 30
        percent sodium chloride solution to  the reagent blank, standards,
        and samples.  For groundwater samples, sodium chloride solution
        may be omitted.  Mix contents of tubes by swirling and place rack
        In cold water bath (0-10°C).
    f.  Pipette 10.0 ml of sulfuric acid solution into each tube and mix
        by swirling.  Allow tubes to come to thermal equilibrium In the
        cold bath.   Be sure that temperatures have equilibrated in all
        tubes before continuing.
                                 , (8

-------
    g.  Add 0.5 ml brucine-sulfani1ic acid reagent to each tube (ex-
        cept the  interference control tubes) and carefully mix by
        swirling, then place the rack of tubes in the boiling water bath
        for exactly 25 minutes.
        CAUTION:  Immersion of the tube rack into the bath should not
        decrease the temperature of the bath more than 1   to 2  C.  Flow
        of bath water between the tubes should not be restricted by
        crowding too many tubes into the rack, in order to keep this
        temperature decrease to an absolute minimum.   If color develop-
        ment in the standards reveals discrepancies in the procedure,
        the operator should repeat the procedure after reviewing the
        temperature control steps.
    h.  Remove rack of tubes from the hot water bath and immerse in
        the cold water bath and allow to reach thermal equilibrium
        (20-25° C.).
    i.  Dry tubes and read absorbance against the reagent blank at 410 nm.

3.  Calculation
    a.  Obtain a standard curve by plotting the absorbance of standards
        run by the above procedure  against mg NO,-N.   (The color reaction
        does not always follow Beer's law).
    b.  Subtract the absorbance of  the sample without the brucine-
        sulfanilic reagent from the absorbance of the sample containing
        brucine-sulfani1ic acid and read the absorbance in mg NO,-N.
        Convert mg per aliquot of sample to mg per leter.

A.  Reagents
    a.  Distilled water free of nitrite and nitrate is to be used  in
        preparation  of all reagents and standards.
    b.  Sodium chloride solution (300 g/1).  Dissolve 300 g NcCl  in
        distilled water and dilute  to 1.0 1.
    c.  Sulfuric acid solution.   Carefully add 500 ml  H SO.  (sp.  gr.  1.
        to 125 ml  distilled water.   Cool  and keep tightly stoppered to
        prevent absorption of atmospheric moisture.
                            149

-------
         d.  Brucine-sulfan!1Ic acid reagent.   Dissolve 1  g brucine sulfate
             UC23H26N2V2'H2SV7H2°] and 0>1  9 5u1fanilic acid
             (Nh^CgH^SO.H-^O)  In 70 ml hot distilled water.  Add 3 ml
             concentrated HC1,  cool, mix and dilute to 100 ml.   Store in a
             dark bottle at 5°C.   This solution  is stable  for several months;
             the pink color that  develope slowly does not  effect its usefulness.
             Mark bottle with warning:  CAUTION:  Brucine  Sulfate is toxic;
             take care to avoid Ingest ion.
         e.  Potassium nitrate stock solution (1 ml =0.1  mg NO.-N).  Dis-
             solve 0.7218 g anhydrous potassium  nitrate (KNO,)  in distilled
             water and dilute to  1  liter.
         f.  Potassium nitrate standard solution (1 ml  = 0.001  mg NO -N).
             Dilute 10.0 ml of the stock solution to I  liter.  This standard
             solution should be prepared fresh weekly.
         g.  Acetic acid  (1+3).  Dilute 1 vol. glacial  acetic acid (CH.COOH)
             with 3 volumes of distilled water.

     5.  Apparatus
         a.  Spectrophotometer or filter photometer suitable for measuring
             absorbance at 410 nm and capable of accommodating  25 mm diameter
             cells.
         b.  Sufficient number of 25 mm diameter matches tubes  for reagent
             blanks, standards, and samples.
         c.  Neoprene coated wire racks to hold  25 mm diameter  tubes.
         d.  Water bath suitable  for use at 100  C.  This bath should contain
             a stirring machanism so that all  tubes are at same temperature
             and should be of sufficient capacity to accept the required
             number of tubes without significant drop in temperature when
             the tubes are immersed.
         e.  Water bath suitable  for use at 10-15°C.

Measurement of pH
         pH Is measured in the field using a battery operated Beckman
Electromate pH Meter.  The instrument is equipped with a combination electrode
and normal operating procedures will assure a precision of ± 0.1 pH unit.

                                      150

-------
         The following is a detailed description of test procedures for use
by field personnel who will be making the In-sltu pH measurements.  It is
Important that explicit care be taken to assure as great an accuracy and pre-
cision as can be maintained since field measurements are unduly subject to
possible error.
     1.   Calibration of pH meter and electrode.
         a.   Check the battery power supply to assure adequate power.
         b.   Check to make sure that the pH meter Is in the proper operating
             mode.  Turn function switch to STANDBY, temperature compensation
             to the temperature of samples and buffers.
         c.   Be sure that the samples and buffers are at the same temperature
             before calibrating Instrument.
         d.   Rinse off electrode with distilled water and dry gently with
             soft tissue paper.
      • .  e.   Place the combination electrode into the buffer .solution  pH 7«
             Turn function switch to pH and after several minutes adjust the
             meter reading to the pH of the  buffer solution by using the
             "standardize" dial.
         f.   Turn function switch to STANDBY.   Remove combination electrode
             from buffer  solution, rinse with  distil led water, and dry.
         g.   Repeat e.  and f.  for buffer of  pH k.
    '*'   Measurement of Sample pH.
         a.   Use of the combination electrode  allows measurement of pH in
             small  beakers.   Use a clean 50  ml  or 100 ml  beaker.  Insert  the
             combination  electrode in sample.   The electrode must not  touch
             the sides  or bottom of the beaker.  Turn function switch  to pH.
             Slowly rotate the beaker several  times to insure good contact of
             sample and electrode When meter reading has stabilized, record  pH.
         b.   Turn function switch to STANDBY and remove electrode.  Rinse
             electrode  with  distilled water  and dry carefully with soft  tissue.

         c.   Repeat procedure  for  each sample.                •
                                  151

-------
     3.  Storage and care of combination electrode.
         a.  The salt solution  in the reference part of the electrode
             should be topped off occasionally to assure an adequate level             "
             Is maintained.
         b.  The rubber sleeve  should be kept over the fill hole except               «**
             when equilibrating pressure or filling with salt solution.
              •  .                               '::--- •":•'' :.'.-.          .   '•..      -:,sv, i
         c.  The electrode should be stored in a manner that keeps the             •<.  "
             electrode tip wet  at all times.
                                                ...        '           .          M
Phosphate - Total
         Digestion of Raw Sample;  The persulfate digestion method will be
used to prepare samples for analysis of total phosphate.  The method follows
        .'-"'"         '         .          '
the description in Standard Methods (page 526).  Additional information on
                                      .a
this digestion method can be found elsewhere0.
                                                           •  < '  '       .
         When necessary the sulfuric acid-nitric acid digestive method,
Standard Methods (page 525), will be used In lieu of the above.
         Analytical Method;  The ascorbic acfd-molybdate method described
In Standard Methods (page 532)  is applicable to the measurement of total               "
phosphate in the leachate samples.  Arsenates Interfere with the analysis
                                                                                       i
above 0.05 mg/1 arsenic.  This method for total phosphate  is adequate for
the full range of 0.03 to 2.0 mg/1 as P.
         When necessary the above specified analytical method will be replaced
by the vanadomolybdo-phosphorlc acid colorimetrlc method, Standard Methods
(page 527).
                                                                                       '
Polychlorinated Biphenyls (PCB)
         Since the chlorinated compounds are generally quite surface active,          *
most of the PCB is expected to  be on the suspended material.  The suspended
matter, after separation on a glass fiber disc, is extracted by agitation             *
in 1:1 acetone:aceton itrite.  Chlorinated pesticides are partitioned into
petroleum ether after the addition of a weak salt solution.  The extract  is
                                      152

-------
cleaned up on florist 1  before gas-liquid chromatography detection of the
chlorinated materials.
         This method is suitable for aqueous samples with or without large
amounts of suspended matter.  The detection limit is 10 nanograms per liter
of sample.  Therefore it is very important that extraordinary cleanliness be
maintained to avoid contamination.
                           Analytical  Method
         Samples containing 1  gm/1  or  more suspended matter must be filtered
(Section 1) and the filtrate and suspended matter analyzed separately as
discussed in Section 3  (water) and  Section 2 (sediment).  Samples having less
than 1  gm/1 suspended material can  be  analyzed as a whole sample according to
Section 3.
     '•  Filtration of  Heavily Sedimented Samples
         a.  Place a 7  cm.  Whatman  GF/B filter pad (or equivalent)  in a
             porcelain  Buchner funnel  and prewash with 50 ml  distilled petro-
             leum ether.   Discard the  washings.
         b.  Measure out 1  liter of homogeneous sample and filter using suction.
         c.  Transfer the  filtrate  to  a 2 liter separatory funnel and proceed
             according  to  Section 3-
         d.  Transfer the  filter pad to a 600  ml  beaker with clean  forceps
             and proceed according  to  Section  2.
     2-   Extraction Procedure  for Sediment Fraction
         a.  Add 100 ml  of  1:1  acetonitrile:acetone and 50 ml  distilled
             water to beaker containing the filter pads.  Allow contact for
             more than  2 hours with occasional  stirring.
         b.   After 2 hours  remove the  sediment  from the filter pad  by mas-
             cerating the  pad  with  two  clean glass stirring rods.
         c.   Allow the  sediment  to  settle and  decant  the clear supernatant
             using the  stirring  rods to hold back the glass filter  fibers.
             Decant into  1000  ml  of distilled  water in a 2 liter separatory funnel
                               153

-------
    d.  Repeat the partitioning with two additional  50 ml  portions of
        1:1 acetonItrile:acetone, each time allowing the sample to soak
        for more than one hour with occasional  swirling.  Decant the
        clear supernatant into the separatory funnel.   This should
        bring the total  volume up to 200 ml of  extractant.
    e.  Add 30 gm Na^SO.  and extract two times  with  150 ml  petroleum
        ether, each  time washing the petroleum  ether twice with 100 ml
        distilled water  which is added to the rest of  the  aqueous sample.
        (This is done to wash acetonitrile and  acetone out of the petroleum
        ether so they will  not interfere with the florisil  cleanup.)  If
        heavy emulsion occurs at this point, as it may with dirty samples,
        include the  emulsion with the aqueous phase  each time and par-
        tition a third time with 150 ml  petroleum ether.
    f.  Carry through with evaporation,  florisil  cleanup and detection
        as described fn  Section 3 for aqueous samples.

3.  Extraction Procedure for Aqueous Fraction
    a.  Add 150 ml of redistilled 15$ diethyl ether  in petroleum ether
        to the sample.   Shake vigorously for 3  minutes.  Settle for at
        least 10 minutes.
    b.  Draw off and save the aqueous phase.
    c.  Swirl the organic phase to dislodge water from the sides of the
        funnel.
    d.  Draw the organic phase into a clean 600 ml beaker.
    e.  Return the aqueous phase to the  separatory funnel  and repeat
        steps a-d with another 150 ml \5% ethyl ether  in petroleum ether,
    f.  Repeat steps a-d with 150 ml petroleum  ether (no ethyl  ether).
    g.  Prepare a large  funnel with a small cotton plug and 2 teaspoons
        of Na.SO..  Wash this with 50 ml petroleum ether.
    h.  Pour the sample  through Na2$0.  to dry it and catch the sample in
        a clean 600  ml  beaker.
    i.  Follow the sample with another 25 ml petroleum ether to wash the
        Na.SO. and catch this washing in the beaker  containing the sample.
                                  154

-------
         j.  Place the sample beaker  in a b5°C water bath and evaporate to          :
             about 25 ml volume  (about 2 hours).  This evaporation can also         j
             be accomplished in a K-D evaporator.                                   j
         k.  Prepare a 4-inch florisil column and prewash with 50 ml petroleum      !
             ether.  Discard the washing.
         I.  Follow the prewash with the sample.  Add 150 ml of 11 (V/V)
             ethyl ether in petroleum ether and then 150 ml of 20* (V/V)
             ethyl ether in petroleum ether.
         m.  Add  100 mtcroliters of distilled xylene to each elutriated volume.
         n.  Evaporate the collected volume to about 1 ml volume in a K-D
             evaporator.
         o.  Cool the evaporator under a cold water stream and wash down the
             large flask with the condensed solvent.
                                                                                    i
         p.  Reduce the sample down to an injectable quantity as rapidly as
             possible in a 45°C water bath.  Thoroughly mix the contents before     |
             GLC detection.                                                         1
                                                                                    f;
         q.  Initial detection is done by GLC using 3* OV-I and the Nicher-63       f
             electron capture detector.  Confirmation of positive amounts of
             chlorinated hydrocarbons  is first done on 3$ OV-17 using a Coulson
             electrolytic conductivity halide specific detector and then on
             5% OV-17 plus 2% QF-1 using a Dohrmann mlcro-coulometric chloride
             specific detector.

Sodium and Potassium
         The preferred method of analysis for sodium and potassium utllIzes
the flame photometer technique.  Standard analytical procedures are followed
as described in Standard Methods (page 317 and 283).
         Satisfactory results can also be achieved by Atomic AbsorbtIon
Spectrophotometry.

Sulphate
        Sulphate is determined by a gravimetric method utilizing precipitation
with barium as the barium sulphate solid. The filtered precipitate Is ignited
                               155

-------
at 800 C for I hour prior to cooling and weighing.  This method Is used for



both leachate and groundwater samples.  Care must be taken with leachate



samples to avoid error caused by precipitation of barium chloride during the



sulfate analysis.  The gravimetric method is described in detail in Standard



Methods (page 330-




Settleable Solids



         Settleable matter is determined according to the procedure given In



Standard Methods (page 539) using the Imhoff cone.                        '




Total Dissolved Solids (TDS)



         Total dissolved solids is determined according to the procedure



described in Standard Methods (page 290).  There may be a significant dissolved



organic fraction present in the leachate samples so that correspondence



between specific conductance and TDS may be different from thet of the ground-



water samples.




Total Suspended Solids (TSS)



         The analytical procedure employed for determining suspended solids



was originally described by Wycoff CO.   Suspended sol ids are determined by



leachate filtration through a glass fiber filter pad.  The initial  weight of



each-pad is determined before filtration.  Following filtration, the pads are



dried for one hour at 103°C and then weighed.  The glass pads are weighed



again after being ignited for 10 minutes at 600°C if the volatile fraction Is



to be determined.  The method utilized is described in  Standard Methods (page 537).




Volatile Acids



         Volatile acids (total  organic acids) is measured by the column-



partition chromatographic method as given in Standard Methods (page 577).



Special precaution should be exercised in maintaining the normality of the stan-



dard sodium hydroxide titrant by excluding CO* from the reagent bottle.
                                     15

-------
  APPENDIX H





MONITORED DATA
    157

-------

-------
                          TABLE  OF  CONTENTS
      TITLE
    PLATE WO.
   Thermister  Readings
   Gas Probe Readings
   Laboratory  Gas Analysis  -Cell  A  £  B
   Laboratory  Gas Analysis  -Cell  C  S  D
   Laboratory  Gas Analysis  -Cell  E
   Leachate Analysis -Cell  A
   Leachate Analysis -Cell  B
   Leachate Analysis -Cell  C
   Leachate Analysis -Cell  D
   Leachate Analysis -Cell  E
   Water Analysis - Water Added  to
            CelIs B & C
   Groundwater  Analysis -Well  1
   Groundwater  Analysis -Well  2
   Groundwater  Analysis -Well  3
   Groundwater  Analysis -Well  4
   Groundwater  Analysis - Original
            Geotechnical  Investigation
   Cel1 A 6 E  Subdrain
   Observation  Wells and Piezometers
   Cumulative  Leachate Production
   Cumulative  Leachate Production
   Lysimeter Samples - Field Analysis
   So 1ut i on Ana lysis
   Record of Rainfall, Evaporation  and
                            Runoff
   Settlement  Data
   Liquid Rout ing - Cell C
   Liquid Rout ing - Cell D
H-1A,  IB, 1C
H-2A,  2B
H-3A,  3B
H-JfA,  4B
H-5A,  5B
H-6A,  6B, 6C
H-7A,  7B, 7C
H-8A -8H
H-9A -9H
H-10A  -IOC
H-l 1A, 1 IB, 11C, 1 ID

H-12A  -12E
H-13A, 13B, 13C, 13D
H-UA, UB, 1*»C, 140
H-15A, 15B, 15C
H-16A

H-17A, 17B, 17C
H-18A
H-19A, 19B
H-20A  ( Discontinued)
H-21A
H-22A
H-23A - 23T

H-24A - 24D
H-25A - 25H
H-26A - 26H
Preceding page blank
                                   159

-------
THERMISTER READINGS
DATE TIME AIR
TEMP.
1971
11-8 PH 25.8
11-10 AM 24.5
PM 22.3
11-11 AM
11-12 AM
11-11 AM 9.1
PM
11-15 AM 9.8
11-16 AM 13.2
PM 21.it
11-17 AM 7.0
PM 20.3
11-18 AM 13.5
PM 20 . 1
11-19 AM 9.7
PM 17.5
11-22 AM 7.2
PM 17.5
11-23 AM 10.0
PM 12.0
11-214 AM 10.5
PM 10.0
11-29 AM
11-30 AM 6.1*
PM 21.0
12-1 AM 10.1
12-2 AM 7.5
PM 7.5
[ 12-3 AM 6.7
12-6 AM 15.0
PM 18.1
12-7 AM 12.5
12-8 PM 15.1*
12-9 AM 12.1
12-10 AM 15.0
CELL A
Temperature °C
Bot. Mid. Top

17.1
26.6 19.1
26.8 26.6
27.8 27.5
29.6 27.8
25.1 29.5 18.5
21*. 8 29.2 19.1
24.2 28.4 27.6
22.i* 28.1* 42.5
22.6 28.2 1*3.9
22.5 27.9 35.7
22.3 27.9 33.4
22.3 27.5 28.6
22.3 27.5 27.7
22.2 27.7 26.1
22.2 27.6 25.8
21.9 27.1 ,2i*.0
21.9 27.1 24.0
21.8 27.0 21*. 0
21.8 27.0 23.9
21.8 27.0 23.9
21.8 26.9 23.5
21.7 26.4 23.2
21.6 26.3 21.9
21.6 26.3 21.9
21.7 26.5 21.7
21.6 26.2 21.4
21.5 26.1 21.2
21.6 26.0 21.3
21.4 26.1 19.9
21.4 25.8 19.7
21.U 25.8 19.1
21.4 25.6 18.8
21.6 25.6 18.3
21.1* 25.5 17.8
CELL B
Temperature °C
Bot. Mid. Top













18.1
-
22.6 13.8
22.8 19. 4
22.1* 25.5
22.6 25.6
23.2 26.6
23.2 27.4
23.1* 28.9
23.4 29.1
23.9 34.4
24.1 35.1
24.2 35.2
24.4 35.5
24.7 35.7 20.6
24.6 35.7 22.2
24.5 35.6 21.0
25.7 34.8 19.7
25.7 34.7 20.9
25.9. 34.4 21.7
29.3 33.1 21.7
29.7 32. 9"" 22. 7
30.5 32.7 22.6
CELL C
Temperature ''c
Bot. Mid. Top




































CELL D
Temperature °C
Bot. Mid. Top




































CELL E ~~|
Temperature °C 1
Bot. Mid. Top







]


18.2
22.5
24.5
30.7
22.7
24.5
25.2
30.7 19.6
31.0 19.9
31.4
31.3 20.1
31.5 20.3
31.3 20.6
29.3 26.2
29.0 26,1
28.9 27.1
28.9 27.8
28.6 28.8
28.5 28.9
28.5 28.7 !
27.9 32.0 i
27.9 32.0
27.9 32.5
27.8 32.8
27.8 33.0
27.8 33.1
TIIERMISTER READINGS
                                                    PLATE  rf- 11
DATE TIME AIR
TEMP.
1971
12-13 AM 11.5
12-14 AM 11.7
12-15 AM 11.3
12-16 PM 14.1*
12-17 PM 14.3
12-20 PM 9.9
12-21 AM 6.6
12-28 PM
12-29 PM
12-30 AM
1972
1-11 AM
1-18 PM
1-27 AM
2-15 AM
3- Ht AM
3-28 AM
it- 1 1 AM
4-25 AM
5-9 AM
5-23 AM
6-6 AM
6-20 AM
7-11 AM
7-25 AM .
8-8 AM
8-23 AM
9-7 AM
9-20 AM
10-11 AM ,6-0
10-21* AM
i :l-8 AM' 21.0
l!-21 AM i;.C
CELL A
Temperature °C
Bot. M)d. Top

21.3 24.9 16.6
24.3 25.6 22.6
21.7 25.1 16.1
21.6 25.0 15-7
-
21.4 24.5 14.6
-
21-3 21.3 13.9
21.2 23.7 13.7
-

20.7 22.5 12.8
20.5 22.0 II. 1
20.8 21.7 13.8
19.7 20.6 17.4
19.0 19.5 15.4
18.6 18.5 15.4
18.4 18.3 16.1
18.2 18.! 16.9
18.2 18.1 18.2
18.1 18.2 20.0
18.1 18.5 21.5
18.1 18.5 23.4
18.2 19.) 24.6
18.5 '9-1* 25.6
18.7 19. S 25.9
18.9 20.4 26,0
19.0 20.4 26.6
20.7 -
19.5 21.3 24.9
The
19.5 20.6 16.7
19.4 20.4 14.3
CELL B
Temperature °C
Bot. Mid. Top

30.4 32.1 21.4
31.8 39.9 25.6
30.2 31-9 21.3
30.1 31.9 21.3
29.8 31.6 21.2
28.9 30.9 20.9
-
26.9 29.2 20.0
26.7 28.8 19.8
_

27.2 27.1 18.6
24.2 25-3 17-3
24.0 24.1 17.2
22.7 22.2 15.9
20.7 20.2 16.9
20.2 19.7 17.5
19.8 19.8 17.5
19.6 19.2 17.6
19.3 19.0 18.8
19.2 19.0 20.0
19.2 19.2 21.1
19.2 19.5 22.6
19.5 20.1 24.1
19.7 20.6 25.1
19.8 20.9 25.0
20.2 21.3 25.0
20.5 21.6 25.5
21.9 -
20.8 21.9 23.3
mister Connections
20.5 21.1 16.5
20.6 20.8 f -
CELL C
Temperature C
Bot. Mid. Top

31.6 22.6 -
32.5 25.4 20.2
30.1 23.7 24.2
29.7 24.7 21.1
29.3 25.4 20.0
28.3 26.2 17.3
-
26.6 26.1 14.6
26.4 26.0 14.5
26.3 25.8 14.4

24.5 25.0 11.5
23.8 20.3 10.7
22.9 16.8 10.7
20.6 13.5 10.6
18.5 14.0 14.3
18.2 15.6 14.7
18.1 15-7 15.1
17.0 15.7 15.4
17.2 16.9 16.7
17.9 18.4 18.5
18.7 19.9 19.6
19.4 20.4 21.7
20.2 22.3 22.4
21.1 23.6 22.6
21.7 23.3 23.0
21.9 23.6 23.2
22.4 24.1 25.5
24.0
22.4 21.7 20.7
shorted-out by ra
Shorted Oat
01 2 - 17.0
CELL D
Temperature °C
Bot. Mid. Top





11.3
16.1
17.7
19.5 21.2 23.2
19.5 22.1 24.3
19.5 22.5 22 4

19.9 16.4 15.2
15.9 15.1 13.7
15.7 14.0 14.5
12.4 11.5 10.8
17.0 13.9 14.3
16.5 15,9 16.0
17.0 16.3 17.6
16.6 16.6 17.0
17-4 18.1 ig.l
18.8 20.0 21.8
20.9 21.8 24.7
22.9 23.5 27.6
25.0 26.5 28.0
26.9 27.9 29.2
27.5 27.6 30.3
24.9 26.6 29.3
26.8 27.6 27.9
28.1
26.9 26.0 23.6
nwater .
25.2 21.5 16.8
22.5 13.2 14.6
CELL E
Temperature °C
Bot. Mid. Too

28.0 32.8 19.2
24.0 27.5 17.4
27.9 33.4 18.8
28.0 33.4 18.4
-
28.0 33.0 16.7
-
28.0 31.8 14.5
27.8 31.5 14.1
-

26.9 29.2 10.9
26.1 27.4 10.5
27.9 32.4 p.7
23.2 23.7 12.2
21.0 20.9 16.2
20.6 19,9 17.6
19.8 19.2 16, 7
19.3 18.8 !7.J
19.1 18.9 18.9
18.8 18.7 71 "
18.9 18.2 23.
18.9 19.5 <5,«
19.2 20.J 26.4
19.5 20.9 26.:'
19.7 21.4 27. i
19.8 21.6 27.0
20.2 22.1 27.5
22.4
20.5 22.5 23.0

20.6 21.1 20.6
20.5 20 o U.;< '

-------
                   THERMISTER READINGS
DATE TIME AIR
TEMP.
11-30 AH 6.0
12-15 AH 14.0
HO-73 AM 11.0
I-2J-73 AM 5.0
2-6-73 A« 11-5
2-27-73 AM 13-0
3-13-73 AM 11.5
3-27^73 AM 15.5
A- 10-73 AH 21.0 -
4-24-73 AM 22.0
5-15-73 AH 22.0
6-5-73 AM 20.0
6-26-73 AH 27.0
CELL A
Temperature C
Bot. Hid. Top
19.2 20.0 13.1
18.9 19.1 7.8
18.2 17.6 8.0
21.2 16.8 10.5
15.4*16.4 9.8
17.1 16.1 11.9
17.1 16.0 11.9
16.8 15.7 12.0
16.7 15-8 14.6
16.7 15.8 16.6
16.9 16.6 20.3
17.6 18.9 21). 8
17.6 18.3 26.8
CELL B
Temperature C
Bot. Hid. Top
20.3 20.3 16-.1
19.7 19.3 12.3
18.7 17.7 -
18.2 17.0 11.9
17.7 16.4 11.5
17.3 15.8 12.lt
15.9 15.7 12.7
16.7 15.5 12.6
16.6 15. 4 13.7
16.6 15.6 15.3
16.7 16.1 18.5
21.6 17.0 21.8
17.7 18.2 2ii.lt
CELL C
Temperature C '
Bot. Mid. TOD
20.4 13.0 11.6
22.7* 14. 4
17.7 9.5 7.2
16.3 9.0 8.6
16.8 16.7 12.6
10.3* l0-8* 10-3*
15-5 11.2 10.6
14.7 11.4 10.6
14.1 11.9 12.8
14.1 13.5 14.9
15.1 15.9 18.0
16.1 16.3 21.9
17.7 21.1 21.8
CELL »
Temperature C
Bot., Hid. TOD
21.1 17.8 13.7
19.3 15.2 8.7
13.1 13.0 9.1
15.8 12.5 II.)
14.7 12.3 10.6
14.2 12.7 12.2
14.1 15.1 12.3
12.1 13.2 12.0
14.) 13.3 13.5
14.4 14.2 15.0
15.1 16.4 18.1
16.4 18.9 24.2
18.1 21.8 23.8
CEIL E
Temperature C '
Bet. Hid. TOD
20.1 19.8 11.3
19.3 18.4 S.9
18.1 16.6 6.4
JZ.l 15. 5 S.2
16.9 15.2 9.4
16,6 15.0 11.9
16.5 15.1 11.6
16.4 15.1 12.1
16.5 15.2 15.7
16.4 15.5 17.4
16.7 16.3 21.9
17.2 17.6 26.2
17.9 19.1 28,3
Ojieit I enable Data
                                                  PLATE H-1C
                    -//A

-------
                                  CELL A
                              BH>ao*lMlity.-%
                              Boti Ij.  Tttc
                       Sues collected in the
                       co*busttt)i<) tonic v
                             per m*iH'«to
                                                                        • per million of
                                                                      ; readout- Units
                    * .
                                                                    Mate
L
                  (1) Ease* ,coH«tt»!t In the 9»« #rob«* were  teited for 4onc«ntc*tton Impart* p»r nil I ten of «*s*«»%J)»l« toxi« vapofs
                     prevent.  Osp4«atretlons «>(ce«d»i  lJi»tm«Wt re»do« 1 lnf» of lOTft K«rts per mlVTlon  end «re  therefore pot   '
                              i jJ^it. t.h^L.i.                                           r*                        -''
Ireludcd )jj*thl*  table.
2rc»n re-idty.gj with dilution vity«u.  tf*r«4*w) cx'los'bM
                                                 162
                                                                                      i
                                                                                       to«-IOi.
                                                                            > t y
                                                                                                                     PLAT6 H-2B

-------
                                       LABORATORY  GAS ANALYSIS
                                              CELLS A 6 B
PROBE
NO.
A-B



A-M



A-T

B-B



B-M



B-T



GAS
COMPONENTS
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Oloxld*
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nl trogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
DATE
12-8-71




30.0
12.4
57.6
0






46.4
8.6
45.0
0.




1-3-72
45.4
13.7
40.9
0
58.0
8.5
33.5
0
38.3
8.0
53.7
0.




71.0
7-0
22.0
0




1-18-72














54.6
10.8
34.6
0




1-27-7
65.3
4.6
30.1
0


















2-15-72










81.3
4.2
14.5
0.0
68.8
7.1
24.1
0.0
59.4
6.6
34.0
0.0
3-2-72
75.8
1.4
22.7
O.I


















3-14-72




76.5
2.1
21.3
0.1






92.9
1.5
5.6
0.0




4-25-72




75.2
0.4
24.4
Tr






94.1
0.6
5.3
Tr




5-23-72










95.0
0.4
4.6
Tr
89.8
1 .0
9.2
Tr
73.8
0.3
25.9
Tr
-20-72
69.7
0.4 '
29.9
Tr
70.5
0.5
29.0
Tr
M.5
1.9
56.6
Tr












7-25-72




68.7
0.5
30.8
Tr






82.9
1,2
15.9
Tr




 * - Flrtt  latter Indicates call; second  letter Indicates bottom, middle or top probe.
                                                                                            PLATE H-3A
                                      LABORATORY GAS  ANALYSIS
                                             CELLS A 6  B
PROBE
NO.
A-B



A-M



A-T


B-B


B-M



B-T



GAS
COMPONENTS
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
N 1 trogen
Methane
Carbon Dioxide
Oxygen
Ni trogen
Methane
Carbon Dioxide
Oxygen
N 1 1 rogen
Methane
Carbon Dioxide
Oxygen
N 1 1 rogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
DATE
8-23-72




66.0
1.2
32.8
Tr






81.8
0.9
17.3
Tr




9-20-72




65.3
0.8
33.9
Tr






81.7
0.4
17.8
O.I




10-24-7




66.4
0.6
33.0
Tr






74.3
0.9
24.7
O.I




1 1-2 1-72




69.7
0.4
29.9
Tr






79.1
0.6
20.1
0.2




12-19-72




71.6
0.4
27.9
O.I






78.7
0.7
20.3
0.3




1-23-73




70.9
0.5
28.4
0.2














2-27-73




73-4
1.0
25.2
0.4






78.6
0.6
20.3
0.5




3-27-73




73-7
0.4
25-5
0.4






73.6
0.7
25-1
0.6





6-5-73




77.4
0.3
21.8
0.5






76.9
0.8
21.1
1.2














































_



* - First latter Indicates cell; second  letter Indicates bottom, middle or top probe.
                                                                                           PLATE  H-3B

-------
                                      LABORATORY  GAS ANALYSIS
                                              CELLS C &  D
PROBE
NO.
C-B



C-H



C-T



0-B



0-M



D-T



GAS
COMPONENTS
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
N i t rogen
Methane
DATE
-11-72
64.9
7.4
27.7
0
79.6
3-8
16.6
0
67.4
6.9
25.7
0
62.8
8.3
28.9
0




70.9
6.1
23.0
0
1-18-72




61.8
9.3
28.9
Tr
















I-27-7J
68.7
7.0
24. 3
Tr




68.7
7.3
24.0
Tr








83.9
3.3
12.8
Tr
2-15-7
72.9
6.5
20.6
0.0
82.6
3.9
13-5
0.0
76.8
5.1
18.1
0.0








92.9
,'•*
"5.*
0.0-
3'2'72
75.7
5.6
18.7
Tr.




SOiO
3.8
16.2
Tr.








96.7
. 0.2
"•" 3-1
ff.o--
3-14-72




87". T
3.1
9-8
Tr














" —

3-28-7!




















98. 5
0.1
• 1.4
0.0
-25-72
97.8
0.4
1.7
• a.r
















98.1
0.1
1.8
Tr
5-23-72
99.8
Tr
O.I
O.I




















6-20-72
98.8
0.2
0.9
O.I
















98.9
Tr
I.I
Tr
7-25-72
99.4
Tr
0.1
0.5
















94.4
0.1
2.2
3.4
* - First letter  Indicates cell;  second letter Indicates bottom, middle or  top  probe.
                                                                                            PLATE H-'iA
                                      LABORATORY GAS  ANALYSIS
                                              CELLS C S D
PROBE
NO.
C-B



C-M



C-T


D-B



D-M



D-T



GAS
COMPONENTS
Carbon Dioxide
Oxygen
Ni t rogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
N i t rogen
Methane
Carbon Dioxide
Oxygen
Ni trogen
Methane
Carbon Dioxide
Oxygen
NI trogen
Methane
DATE
8-23-72
98.2
Tr
0.2
1.6















79-1
Tr
1.0
19.9
9-11-72



















71.6
0.4
1.2
26.8
D-ll-72
96.4
Tr
0.1
3-5



















10-24-7
96.0
Tr
0.2
3.8







80. 0
O.I
0.6
19.3








1 1-21-72
94.9
Tr
0.3
4.8



















12-19-72
92.7
O.I
0.4
6.8



















1-23-73
90.1
Tr.
0.2
9.7



















-27-73
89.3
0.1
0.3
10.3



















3-27-73
89.1
Tr
0.2
10.7



















6-5-73
90.0
Tr
0.3
9.6


















1-
























* - First  letter Indicates cell; second  letter Indicates bottom, middle or top probe.
                                                  164

-------
                                        LABORATORY, SAS  ANALYSIS
                                       i                 E      o  •'"
PROBE
NO.
E-B

E-M
E-T









GAS
COMPONENTS
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
N 1 1 rogen
Methane
Carbon Dioxide
Oxygen
N 1 1 rogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
Carbon Dioxide
Oxygen
Nitrogen
Methane
0 DATE
2-8-71


65.5
2.5
0.2







•£


1-3-72
52.2
9.2
36.6
2.0
1.9.6
12.3
37 ".5"
0.6-
61.1.
7.5
30.8
-OJ


-

,«' •-
,'"'- "7 "
:i ~

1-18-72
65'. 7 -
7.7
2*7* "
2.2
68.3
7-3
23" i 	
62. 8 <•••
3.5
33.1
. 0.6.-;
O
O


'~',
^
'8 c
Lil

2-15-72
'V" "? ''


63.1
6.8



V ~




.?
rv
	 „„.„„„„

3-2-72
± 72.8"
5.4
2.9
	 	
' 57-7
3-2
38.3
* 0.7
:..: -v '•'
-.' 3
o o
•i -i
. .T :"
£i '
•-' O
_ -.
' Sg S

3-l*-72



"b.8
1.9



,; -,..

^
;•;, ;-•

" ••?
C)'" O
k °"
*•» W
w..,.,™,..™,..

*-25-7!


88.1
0.2



*• -.0 . C
•'.s




r?.
s . :,
& a f

6-20-73
86.2
0.7
10.2
2.9
77.6
2.3
18.1
2.0
52. *
0.8
1.6.2
_g.te'-
f.





;; '-



-25-72


79.6
1.3
16.8
2.3



.::, . .;.-.. •'







'*, •;.
"
8-23-72

';- |
81.6
0.2
15.7
2.5

- ,, '



|!



S .i


9-20-72


80. 1
0.5
17.1
2.3


r ;
-* :•



;
. ; 	 i

                                                                                                                        J
                                                                                                                        J

                                                                                                                          t
                                                                                                                        •  |
                                                                                                                        J
                                                                                                                        J


                                                                                                                        J
* - First Tetter Indicates cell;  second  letter  Indicates bottom, middle or top probe.
                                                                                                 PLATE  H-SA
                                                    .J5AS».A!l»U_S.IS.,-.,.  _.
                                             o  -•> CiLL E      o   a,
ft









PRCBE
NO.
E-B


E-M


:E-T









' : CAS
COMPONENTS
Ccrbon Dicxic'c
Oxygen
lCJ°l~"
Qfrbon Dioxide
Oxygen
K!trc-;tn
Msths.-a .

Oxygen
lift rogen
Katha-.e - '
Ccr;on Dioxide
Oxyccn
Hi t rogcn
Mcthsne
Cerbcn 'Dioxide
!!i trcgcn
Corbcn D.loxide
Oxygen
N'it re: en
Hc.he.-.i

10-21.-72



75-3
0.3
22.0
r..,2,lt...










' ° "" 6 o o DA?E v S - " •" •-" ;^ -• ° ,; ;: '
H-21-72

;- ^*

83.0
0.2
lit. 7
.4,1..





- 	 •
"
'^'
^
-"•* •*"
12-19-72

" :" ;>
0
90.2
0.2
7.5
--- 2^1-



	 	 	 •




it
• I ";
<. --.. ..<
2-27-7
.....
.'" ~
V
O.I
3.3
	 t,r7_



	 ,





3 ,,
— f
3-27-7



93-5
0.1
it.it
— *»«-



„ 	 _



S r
X .^
,^J '-
•> -j- c
* o «.
!._:..:
1.-24-73

'V
o
•" .
93.0
0.1
"..5
	 4.4--
,,
.-- .-





? 1
'"I
'.*
liJl
brS-73

;... ;-, -

91.9
0.2
• 's.». '
•;-*-.-5-









!. ..: ;.
-"'


, •-:. -;



„..,...„.



------





; "
,.:.'....:1

















..-< -V-


,
;


,,, . '
f




~ •





















 ,- First  IcUcr  ir.dtcotcs cell;
                                sccorH letter iind:IMattes top, middle or .bottcri probr.
                                           165
PLATE  H-5B

-------
                         LEACHATE  ANALYSIS

                              CELL A
SAMPLE DATE
COMPONENT *
Alkalinity (CaCOj)
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dl ssol ved Oxygen ppm
Fleet. Cond. u mhos/ cm
Fecal Coli. MPN/IOO ml
Fecal Strep. MPN/IOO ml
Iron
Lead
Magnesium
Mercury
Nitrogen * Anroonli
Nitrogen - Organic
Nltrcfgen - Nitrate
.Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, nl/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
12-15-71






























5.1
12-21-71








1.4
285















> • •




4.8
.'i-3-72






























4.7
2-15-72
240


44
16200
5*
28
— 0.2
1.6
500



<0.5
. 2.6
0/0006
4.5
15.6
0'. 0
2,0

4.8
80
724
60

28
17.0
48
2. 1
5.0
9-7-72
1 300
2250
0
20
3260
56
30
-cO.08
4.6
1000
"3
«3

0.16
17
0.006!
0
3
0
0

6.6
128
724
70
«= O.I
20
28.5
430
0.23
5.0
*   Units  In tng/1 unless noted.
**  Temperature of sample when tested for DO,  EC and pH.
                                                              Plate H-6A
                            LEACHATE ANALYSIS
                                 CELL A
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/ cm
Facal Coll. MPN/IOO ml
.Fecal Strep. MPN/IOO ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic'
Nitrogen - Nitrate'
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
SoHds -T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
10-11-72
1370
2850
0
48
3&30
58
28
0.16
I.*
800
<3
<3
22.5
0.12
18
0.0035
3
14
0.10
<0.1

6.1
161
820
42


16.0

0.58
4.7
11-21-72
2160
16,200
•tO. OJ
93«
22.440
390
350
0.15
0.1
5250
<3
9.4.
750
0.44
590
0.013
81
8J
0.0
1.4

130
300
11,800
200


10.0
10,000
9.0
4.7
11-30-72








0.4
7000










0





250
7.0


4.8
1-10-73
3920
19,200
<0.1
1082
20,300
490
125
0.44
0.8
7250
<3
«3
1050
0.55
760
0.0100
48
42
0.90
2.8

148
338
14,080
98


10.0
12,700
5-5
4.8
2-27-73
2310
12,700
<0.05
440
17,600
424
75
0.06
0.4
5000


945
1.29
608
0.0120
66
29
0.40
1.4

120
288
10,700
14


.12.0
9400
3.2
5-4
*   Units in mg/1  unless  noted.
**  Temperature of sample when  tested for DO, EC and pH.
                                                                                                                                                                 Plate  H-6B

-------
                              LTACHATr. ANALYSIS
                                   CELL A

cor.ro«i:NT •'
Alkal ini ty
B.0.0.
Cadmium
Cal c i utn
C.O.D.
Chlor ide
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond . u mhos/cm
Fecal Coli . KPN/ 100 ml
Fecal Strep. KPN/100 ml
Iron
Leud
Magnes 'mm
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sod i um
Sol ids - T.D.S.
Solids - T.S.S.
Sol ids - Settle, ml/1
Sulphate
Temperature' (°C)
Volatile Acids
Zinc
PH

3-13-73




















0





108





3-27-73































SAMPLE DAT
ii-10-73
2835
17,500
< 0.05
858
18,300
MO
1)50
0.22
0.6
!<750


850
1.81
5"i8
0
55
17

1.6

115
272
11,020
16


20.0
9900
3-0
11.9


































































*•   Units in mg/1  unless noted.
**  Temperature of soraple when tested for DO, EC am! pH.
                                                                hate H-6C

-------
                      LEACHATE  ANALYSIS

                            CELL B
SAMPLE DATE
COMPONENT *
Alkalinity (CaCO )
B.O.D.
Cadmium
Ca 1 c i urn
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potass ium
Sodium
Sol ids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
12-7-71
0
13,500

320
15,933
) ,l»75
1 ,600

1 .4

^4,000
^•2,400


320



66
0.029



15,970
421





4.4
12-10-71
0
15,300

200
17,920
998
2,000

<:0.5

9.3 xlO5
2.1 xlO7


550



58
0.084
0


25 ,028
496





4.2
12-15-71






























4.5
12-21-71








1 . 1
14,500




















4.3
12-28-71
972
32,400

1 ,681
42,600
1 ,800
2,500

0.8
12 ,000
300
1.5 xlO5


924

0.25
170
2.5
0
0


29,663
148
<0. 1


6, 360

4. 2
Units in mg/1  unless  noted.
Temperature of sample when  tested  for  DO,  EC and pH.
                                                           Piste !'- /A
                   LEACHATE ANALYSIS
                        CELL B
SAMPLE DATE
COMPONENT *
Alka) inity
8.0. D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect, Cond. u mhos/cm

Fecal Col i. MPN/100 ml
Fgcal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P,.C.B. ppb
Potassium
Sod i urn
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volati le Acids
Zinc
p!)
1-3-72
2360
28,350
<0.25
2950
41,000
1725

3.6
2.4


<: 3.0
2.1 x lO1*

3.0
815
0.006
226
20
14
83

1500
1325
42,270
368
^.0.1

14.0
10,800
140
it. 2
1-7-72








7.4 ,
14,000
t

















12.5


4.4
10-24-72
6880
45,000
0.19
1640
58,450
2000
950
0.29
0.5
20,000

6.0 '
2400
408
: 0-95
8)6
0.0035
780
5?0 .'
0.4
5.0
0
1560
1550
29,000
1800

980
19.0
17,500
62
5-0
11-30-72




61,700



0.2
10,000

<: 3.0
230






0







1070
6.0


5.3
1-23-73
5880
40,000
•^0.1
1323
51,400
498
650
0.20
0.3
9500

<3.0
360
425
0.35
344
0.0136
560
388
0
o.a

1180
1072
24,520
124


9.0
14,400
24
5.'*

-------
                              LEACHATE  ANALYSIS

                                   CELL B
SAMPLE DATE
COMPONENT * ,
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. HPN/100 m\
Iron
Cead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature** (°C)
Volatile Acids
Zinc
PH
3-13-73
4725 •
22,800
•*0.05
1130
32,200
1320
275
0.18
0.8
4500
«3.0
93.0
348
0.33
378
.0044
480
250
0.1
4.2
0
940
816
17,480
36
-
1036
13.0
10,100
10.8
5-2-
































































































































*   Units in mg/1 unless noted.
**  Temperature of sample when, tested for DO, EC and pH.
                                                                Plate  H-7C

-------
                           LEACHATE ANALYSIS

                                CELL C
SAMPLE DATE ,
COMPONENT *
Temperature** (°C)
Alkalinity (CaCO?)
B.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. jj mhos/cm
Fecal Coll. MPN/IOO ml
Fecal Strep.HPN/100 ml
Lead
Magnesium
Mercury
Nitrogen - Armor i a
Nitrogen - Organic
Nitrogen - Nitrate
Nitrogen - Nitrite
Phosphate-Total, as P

P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sulphate
12-15-71






























4.3

12-21-71









1.4
11,200




*














4-7

12-28-71

* 0
»5.900

1041
27.300
750

1300
0.8
9500
230,000
4,300,000
•
1070

0.33
310
4.3

0.38
n ***
u


15,400
323
<0.1


5.1

1.-3-72
11.0
4900
22,500
< 0.25
1700 .
26,750

2.15
1225
1.0

4
15.000
< 2.0
725
0.0012
304
186
4.25

3.26


445
820
16,890
260
<0.1
11,520 .
28
5.1

1-7-72
11.0








0.5
1 1 ,400



















5.4

* Units in mg/1 unless noted
**Temperature of  sample when tested
    ***0etected .06 ppb Lindane.
for 00,  EC and pH.
                                                                  Plate  H-8A
                                                                                                                                     r-     r
                                                                                                                      r
                                                                                          LEACHATE  ANALYSIS

                                                                                               CELL C

COMPONENT *
Temperature (°C)
Alkalinity (CaCOjJ
B.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. ji mhos/cm
Fecal Coll; MPN/IOO ml
Fecal Strep.MPN/100 ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate '
Nitrogen - Nitrite .
Phosphate -Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T^D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sul pbate
SAMPLE DATE .
1-18-72
8.5
5480
2 It, 600

1200
33.500
700

1200
'•7
1 1 ,000
3
400

760

240
17«
3.24
0.030
9-8



15,190
128
<0.l


5.1

2-15-72
19.0
5240
26,400

1200
39,400
750

1120
0.5
11,000



500

550
432
3.8

34.0



19.336
182



5.1
880
3-2-72
16.5
41(50
27,000
<0.l
1600
32,620
700
0.6
iioo
1.0
10,000


<0.5
550
0,0014
800
400
3.10

41.7
0.35
845
950
18,444
88

io.too
42
5.1

3-14-72
21.0
4940
28,200

IIOO
30,500
500

1060
0.3
12,500
3
43,000

410

570
280
4.2

36



18,025
325

-------
                          LEACHATE ANALYSIS

                                CELL C
SAMPLE DATE
COMPONENT *
Alkalinity (CaCO )
B.O.D.
Cadmium
Calc ium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cr?
Fecal Coli. MPN/100 ml
Feca! Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sod i urn
Sol ids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature ' (°C)
Volatile Acids
Zinc
PH
4- 1 1-72
4,050
20 ,400
«=:0. 1
1 ,200
27,948
880
1 ,700
<:0.25
0.9
9,000
cl .0
400
0.015
592
312
2.40
40.6

750
800
1 1 ,980
, 356
< 0. 1
448
. 19'5
9,700
30
5. 1
5-23-72
4, 100
23,700

880
24 ,600
740
400

0.4
9,750
6
43,000


220

656
240
3.6
41 .9
0


12,330
-v84
0.5

19.0
8,720

5. I
6-6-72
3 ,600
18,000
0. 1
1 ,050
20,276
570
350
0. 15
0.2
10,000
92
1 ,600,000

0.8
220
0.0102
632
800
1 .8
40. 3

560
550
10,080
58
0.6
340
20.0
7,730
22
4.9
"*  -Units in »g/V  unless  noted.
 **  Temperature of sample when  tested for DO, EC and pH.
                                                               Plate  H-8C
                           LEACHATE ANALYSIS
                                CELL C
SAMPLE DATE
COMPONENT *
Alkal ini ty
B.0.0.
Cadm i urn
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. .Cond. jj mhos/cm
Fecal Co) i. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
PH
6-20-72
2600
! 4,700

700
20,720
530
350

0.8
8000




200

i(16
50*
it. 60
36.3



9180
48


19.0


5-0
7-11-72
4400
17,960
<0.1
720
23,490
480

0.15
0.7
7500


140
•CO. 10
220
0.0065
351
90
0.04
24.0

480
476
9324
52


22.0
7270
13
5.1
7-25-72
3800
10,100
^0.1
600
16,630
4)0

0.18
0.0
72CO


120
0,10
192

303
69
0.05
16.4

380
468
7470
69


21.5

10
5-0
8-8-72
2800
13,600
<: 0.05
630
17,910
430

0.13
0.4
7300
<3
3
130
0.20
255
0.018
341
89
0.04
23-0

460
380
7642
206


20.5
5910
9.5
5.2
8-23-72
2600
10,540

610
17,170
420
150

0.4
7000




194

338
79

26.0



7268
178


22.0


5.0
*   Units in mg/l  unless noted.
**  Temperature of sample when tested for  DO,  EC  and  pH.
                                                                                                                                                                 Plate H-8B

-------
LEACHATE ANALYSIS
     CELL C

COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Sleet. Cond. u mhos/cm
Fecal Col 1. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature " (°C)
Volatile Acids
Zinc
PH
_ _._)

9-7-72
3400
10,000
<0.05
570
18,320
323
275
0.07
0.2
6000
6
<3
115
0.22
158
0.060
306
68
0.5
17-0
0
340
312
6800
88
co.l
131
21.5
6060
7.5
5.0


9-20-72
3100
9200

570
15,130
540
225

1.2
6100




148

282
64
0.5
18.0



7160
78


22.5


4.9

SAMPLE DAT
10-11-72
1860
9900
<0.05
440
13,430
380
175
0.08
0.0
5600
3
9.3
150
0.15
154
0.0065
283
71
0.2
16.4

260
336
6630
120


18.0
5280
6.5
4.9

E
10-24-72
2160
10,350
0.05
600
16,780
370
240
0.06 .
0.4
7200


154
0.35
180

330
150
0.4
12.0

360
568
7950
50


22.0
6240
7.5
4.8


11-8-72
1370
13,000
0.06
560
15,660
650
150
0.11
0.2
5000
<3
4.0
170
0.15
166
0.0035
294
67
0.10
13.0

340
340
6860
320


20.0
5940
8.5
4.9
:
Units in mg/! vnlcss noted.
Tenp^raturt of sample whei.
                ?^ and p.i.
                                                                                                                               LEACHATE  ANALYSIS

                                                                                                                                    CELL C
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Sol ids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Ac ids
Zinc
pK
11-21-72
1760
1 1 ,800
0.04
561
16,320
310
225
0.10
0.2
4500


160
0.17
320

301
63
0
2.4

270
330
6500
900


18.0
5700
8.0
5-2
11-30-72
1760
11,100
0.05
520
13,900
284
175
0.07
0.2
6000
4
3
163
0
146
0.0038
265
60
0.17
3-2
0
270
320
6160
132
0
114
15.0
5520
3 .3
4.9
12-19-72
1940
14,550
<0.1
601
16,510
558
175
0.10
0.2
5600





t ft
28I~
51
0.10
2.2

320
336
7040
16


15.0

3.5
5.0
1-10-73
I960
10,800
t 0.1
553
13,300
290
125
0.05
0.3
5500
6.1
*3
148
0.19
118
0.0102
224
39
0.26
1.6

206
250
6260
72


15.0
5500
5-0
4.9
1-23-73
1568
10,600
•^0.1
480
13,000
220
75
0.05.
0.4
4200


185
0.20
240
0.0150
242
60
0.34
2.4

223
304
5180
34


14.0

6.0
5.1
                                                                                                             for  DO,  ;£  inc  ph

-------
                            LEACHATE ANALYSIS
                                 CELL C
	
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.0.0,
Chloride
Color (f,oJ.or, Units)
Copper ;
DlssQ|yed .Oxygep vppro.
E)ee*.,CCBd. ,u mhos/cm
FecjaJ, Cp,i|,, rlPN/lOQjl
Fe**} --^F^MC;^
" ' }ffl&& ;" <^l"9pB?ftM L b
Nlfpijflen -^Nitrate
Phpsp^hafe-Total , as P
''•p'SviiPP!'. i "., .•;;. ;i ;•
Potassium
So^um,,,,

Sot|dS - T.S.S.
So)l|dj.,,- Se|ttle. ml/1
Sulpiwt*

T^lratttre f°C)
VoUtlle Acids . .. . .
Zinc
pH 	 	

.2^6-73 '
1890
10,500
,!,:
i •
0.30L
• 3. '6
j i>*
' l44M
4600^

56 '
""
118;

15^5 '
4200
4.3
4.T
E 	
3*-27-73,
1575
9400
<0.05
; 425 "
10,100
293
; 100
''0.06
! 0.4
'; 2260
; -"it!
.!!?•-'
i 173
?00
104
?"l

176
,
o552
•ffi
f
1 i;6§
•1 ""23^
i 454ib

34

!
_^ »•
- lfe5— • -

2.8"
4.'9

4-10-73
1575
9000
<0.05
48b
11,200
205
75
!0.08 ~
: °.-3
1500 ?'°
ifiS
•f-"t
'jji0^8
ef ••'•'••
Dissolved OXygeri ppm'
Eh
Fes
£t :. ' Cohd'; ' u' (nhos/'tm
i
* • -
Fecpl ' i't rep: HPttf 100 '-ml
Ire
Le,
Ka<
He
Ni
Ml
NI

Ph
£<••''•' ••'•
jisSi.^;:'^
ries fiirn
Airy " c " "" "'-''" ' 'V-'J
t^;9 ^ rcj • ~»» . ,:^ •.
rogen * Ammonia "-
r"dgen * 6r"ganic ' '
rdgen'-'fJiWaie0 "'

spnate-fotal, as P
P.jt.B. ppb
Pokassium " '
Sojdium '
Sojllds - T.flis.
ScflVds - T.S.S.
sdllds - Settle, ml/1
SijlRhate
• ** n
Temperature- (PC) ^.~
Volatile Acids
Z|nc
p«

4-24-73
136$
9100

-------
                             LEACHATE ANALYSIS


                                  CELL D
SAMPLE DATE
COMPONENT *
"Temperature"" (°C)
Alkalinity (CaC03)
8.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. )i mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. HPN/IOO ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Nitrogen - Nitrite
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids -T.S.S.
Solids - Settle. ml/I
Volatile Acids
Zinc
pH.
Sulphate 	
1-7-72
13.0








0.8
7800


















4.6

1-11-72
8.0








1.1
12,000




















1-18-72
9.0
3050
20.400
0.1
1560
89,520
1300
0.4
1210
1.0
12,000
3-0
29,000,000
.2.0
560
0.003
19*
210
4.70
0.080
79.2
0***
910
980
21,010
238
£0.1
8850
95
4.6

2-15-72
18.5
4450
20,850

1300 .
26,300
550

1030
0.4
11,000



500

350
270
3.1

41.2



14,196
122



5.0
1040
3-2-72
16.5
4800
22,050
•CO.)
1400
29,800
440
0.25
980
1.1
9000


<0.5
500
0.0058
408
182
1.90

25
0
7"»0
900
16,252
32

8690
40
5.1

 * Units In mg/1 unless noted
**Temperature of Sample when tested
           ***Detected

for DO, EC and pH.
                                                           .07 ppb Lindane.
                                                                    Plate  H-9A
                                                                                             LEACHATE ANALYSIS


                                                                                                  CELL D

COMPONENT *
ft*,O V
Temperature ( C)
Alkalinity (CaG03)
8.0.0.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. p mhos/cm
Fecal Coli. HPN/IOO ml
Fecal Strep. HPN/IOO ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Nitrogen - Nitrite
Phosphate -Total, as P
P.C.B. ppb
Potassium ,
Sodium .
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sulphate
SAMPLE OATE
3-14-72
19.5
5950
24,000

1200
30,300
270

1020
O.I
12,000
3
23,000

450

378
306
3-0

40



15,994
88
0.15
8430

5.1
920
3-28-72
' 17.5
sow
22,800

1300
31,900
520

1020
0.4
10.000
<. 3
43,000

500

360 '
209
3.80

36.0
0.20


16,948
50
0.4
10,190

5.1

4-11-72
17.0
4950
21,750
< O.I
900
32.330
1700
<0.25
920
0.6
10,000
<3
2000
1.0
600
0.0028 >"
423
207
3-60

17-8

727
860
16,132
228
<0.1
8,300
40

/q*
4-25-72
. 20.0
4700
19,800

1000
30,700
900

1020
0.5
9000
<3
430,000

550

500
236
4.22

22.1
0


15,240
58
<0.1
10,200

5.2

5-9-72
19.0
55QO
23.100
<0.1
1000
33,640
600
<0.2
1090
0.2
12,500
6
<3
<1.0
500
0.0066
580
264
2.38
,
28.7

727
1020
16,110
409
<0.1
10,900
30
5-2
q20
* Units in mg/1 unless noted
**Temperature of sample when tested for DO, EC,  and pH.
                                                                                                                                                                         Plate H-9B

-------
                           LEACHATE ANALYSIS

                                CELL D
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Ca 1 c 1 urn
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 m!
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
PhospKate-Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.O.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
5-23-72
5600
33,600

1300
36, 040
1090
360

0.1
12,200
< 3
21*0


360

720
332
3-1
32.0
0


17,970
40
0.)

18.5
11,400

5-2
6-6-72
5800
30 , 600
0.13
1800
34,524
1050
350
0.10
0.2
13,000
9.2
2300

0.5
420
0.0052
880
864
'3.0
27.7

760
950
14,610
50
O.C
908
20.0
11,300
30
5.1
6-20-72
4500
33.000

1200
33,040
1100
400

0.2
12,750




420

592
440
6.34
28.1



17,450
34


21.0


5-2
7-11-72
6500
25,950
<0.1
1320
35,060
1030

0.15
0.4
13,000


180
0.18
500
0.0090
560
142
0.16
12.4

800
880
21,220
75


23.5
10,750
28
5.2
7-25-72
7900
24,400
0.1
1416
36,400
1070

0.16
0.0
15,000


185
0.35
656

612
151



830
944
18,460
97


23.5

28
4.9
*   Units In mg/1 unless noted.
**  Temperature of sample when  (Sestet for DO, EC and pH.
                                                                Plate N-9C
                               LEACHATE  ANALYSIS

                                    CELL D
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Ca 1 c 1 urn
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
8-8-72
7700
24,300
* 0.1
1440
28,610
1080

0.14
0.3
14,500
3
C3
175
0.64
510
0.012
570
149
0.08
10.0

780
1010
18,740
420


23.5
12,750

5.3
8-23-72
6000
21,550

1400
34,320
1070
250

0.4
15,200




535

638
156
2.6
23.0



20,540
264


25.0


5.1
9-7-72
7900
21 ,800
<0.l
1380
33,660
1080
250
0.15
0.1
13,000
9.2
<3
165
0.36
495
0.064
604
16!
0.2
16.0
0
740
888
18,900
480
*0.05
600
25.0
12,500
21-5
5.1
9-20-72
8000
22,500

1430
35,550
1250
290

0.8
14,000




545

596
167
0.2
15.0



20,200
102


22.0


5.0
10-11-72
3430
25,800
<: 0.1
1402
36,700
1159
290
0.25
0.0
14,000
-=3
<3
208
0.59
568
.0055
702
190
0
8.0

750
960
19,540
370


18.0
13,600
29.5
5-1
*   Units in mg/1 unless noted.
**  Temperature of sample when tested for DO, EC and pH.
                                                                                                                                                                     Plate H-9D

-------
                              LEACHATE ANALYSIS
                                '   CELL D
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Ca 1 c 1 urn
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
fecal Coli. MPN/IOO ml
recal Strep. MPN/IOO ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sod ium
Solids • T.D.S.
Sclids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
! pH
10-211-72
4500
25,200
0.16
l}80
34,840
1200
370
0.10
O.k
15,500


185
0.47
508

630
180
0.1
4.0

800
1010
17,000
80


23.0
12,600
28.5
5.0
11-8-72
4900
25,800
0.09
1330
33,260
1100
375
0.35
0.2
10,000
< 3
< 3
185
0.32
560
0.0022
556
146
0.0
11.0

760
910
17,000
600


20.5
11,200
27.5
5.!
11-21-72
4600
25,200
0.04
1440
34,340
1520
225
0.32
0.05
9000


180
0.37
630

561
137
0.0
3.0

730
800
17,400
600


17.0
12,400
25.0
5.2
11-30-72
4700
27,250
0.05
1354
34,300
1560
260
0.11
0.15
12,000
<3
3
200
0.55
580
0.0045
580
134
0.05
4.4
0
690
880
17,380
412
0
467
14.0
12,800
11.5
5.2
12-19-72
4214
26,200
* 0.1
1402
27,250
1565
275
0.07
0.2
9750






522
101
0.4
1.8

584
848
14,980
90


13.0

21.5
5-2
*   Units  in rng/1  unless  noted.
**  Temperature  of samp 1-5 vher •_est«'
~r, and
                                                                                      LEACHATE ANALYSIS
                                                                                           CELL  D
SAMPLE DATE
COMPONENT *
Alkal inity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/IOO ml
Fecal Strep. MPN/IOO ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volati le Acids
Zinc
PH
1-10-73
4410
26,100
<0.1
1426
30,100
1174
150
0.29
0.4
12,250
6
3
200
0.43
560
0.0086
474
95
0.50
8.0

656
872
16,900
72


12.0
11,800
21.0
5.1
1-23-73
4214
25,700
<0.1
962
31,200
1062
100
0.08
0.2
8,600


230
0.40
552
0.0108
513
119
0.08
8.0

740
896
16,440
22


13.0

22.5
5.3
2-6-73
4620
18,200
^0.1
561
31,600
1129
75
0.11
0.7***
6750
<3-0
3.0
212
0.23
576
0.0160
498
107
0.18
5.6

740
928
16,720
28


13-0
12,200
17.8
4.8
2-27-73
1680
21,400
<0.05
1322
29,800
1225
175
0.12
0.4
7000


300
0.46
636
0.0123
500
128
0.36
2.2

640
948
16,360
66


13.0

17.6
5-5
3-13-73
4935
20,800
*0.05
1400
29,700
1320
150
0.09
0.5
7000


255
0.24
388
0.0047
480
90
O.I
1.8
0
610
888
16,880
72

440
14.0
12,100
16.9
5.0
Un i".3  i I*, rig/1  unless noted .
Ter ;"•"; •: lure of sorp1^ v:hen ;
                                                                                          .i:i.J for DO,  U.
                                                                                                                                                                          Plate   H-5F

-------
                              LEACHATE ANALYSIS

                                   CELL D
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium.
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecat Coli. MPN/100 ml
j Fecal .Strep. MPN/100 ml
VIS0'--
Lead,,
Magnesium
; ifcwy
Nitrogen - Ammonia
Nitrogen - Organic .
Nitrogen - ,N I tra te
Pj*«h*H-Tot,l,, as,P
Potassium
Sod, t.um .
SoMds - T.D.S.
Solids - T.S.S.
Solid* - Settle, ml/1
Sulphate
^>___- — • Aw tQ(*\
Volatile Acids
Z'nc
pH
3-27-73
5460
21,400
•ffl.05
1386
29,500
1380
ISO
0.12
0.3
6000


248

612

516
90
0.24
6.8
680
904
17,680
50


14.0

17-5
5.3
4-10-73
4410
24,200
*0.05
1386,
29,100
1115
100
0.08
0.3
6000


275
<0.1
556
0.0008
519
61 j

1,4 _•
6)0 :
880
17,280
52
- ;

17.0 j
12,300
14.0 •!
5.3 „.
4-24-73
4935
24,100
*0.05
1600
28,500
1160
125
0.06
0.8 '
6060


290
0.5ft j
604 ''
0.0030 \
563G '
77 i
0.48 - i
; 3,*,- i
640 i
856, !
16,970
68


17.0

15.0
5.4
5-15-73
4515
16,100
<0.05
1218
24,450
1450

0.04
0.5-
4800


240 •
o i
672 i
0 i
290 j
34 \
iJ2 ;
<^s •
280
880 .
15,600
32

316
18.7
9900
12.0
*•*-
6-5-73
4200
15.800
<0.05
1080
22,700
1565

0.10
0.4
6000

• ;
215 ;
9 ;
528

,,543. I
74 ;
0:.3" - ':
2.4 '•


14^00,



'9.5

7.6
S.5
*   Units In mg/I unless noted.
**  Tenperature of sample when tested for 00, EC and pH.
                                                                Plate H-9C
                               LEACHATE ANALYSIS

                                    CELL D
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D. :
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strepl MPN/100 ml
iron
Lead
W'-JCK; ~ ^
Magnesium
Mercury
!LOi.'
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-total, as f
f.C.t. ppb
Potassium
Sodium
Solids - T.O.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Sine ;
P* - ••• . ;
6-26-73
4410
15.500
<0.05
946
21,600
114S

0.08
0.40
5600
20 ;6
7.0
203
0:31
316
551
68
1.60
4.'."4;

260
408
14,600


257
24;5
95*0
8,5
'**'.'..


































































































,.:.













*Units in mg/1 unVess noted. •
**  Temperature of sample when tested for 00, EC and pH.
                                                                Plate  H-9H
                                                                                                     r    I
                                                                   L        f

-------
                          LEACHATE ANALYSIS

                                CELL E
SAMPLE DATE
COMPONENT *
Alkalinity (CaCOj)
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Llect. Cond. u mhos/cm
recal Coll. MPN/100 ml
Fecal Strep. MPN/100 ml
1 ron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sod i urn
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
PH
12-15-71






























6.5
12-2l-7'l








2.l|
3,200




















6-5
1-1-72
704
1.730
<0.25
200
1,986
210

0.45
1.6

9
400

<2.0
150
0.004
11.6
350
1 .0
0.35

24
115
2,948
60
<0.l

13.0
480
0.15
5.8
1-1 1-72








0.8
2,200










0






8.0



i-iq-7^
626
1 ,020

170
1 ,430
170
450

1.6
2,000
240
24,000


ICO

4.40
55c
0.87
2.3



2,186
10.0
0. 1

8.0


6.2
*   Units  in mg/1 unless noted.
**  Temperature of sample when tested  for DO, EC and pH.
                                                              Plate  H-IOA
                             LEACHATE ANALYSIS

                                CELL  E
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Eltct. Cond. u mhos/cm
Fecal Col !. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
2-15-72
620
1(80

130
216
102
1)20
<0.2
1.1
UOO



•<0.5
100
0.0005
6.1
13.2
0.6
2.6

8. it
71
1212
54

0.0 .
18.0
552
<0.1
5.7
3-2-7Z


<0.1




























3-14-72
550



2580
300
600

6.6







5.6
27.0
0.8
3.0

' 25
120
2800
2*0
1
0.0
22.5
430

6;5
10-211-72
3720
16,300
0.09
1060
24,450
750
liltO
0.12
0.6
7000
6.1
2k, 000
453
0.60
736
0.0)1(5
220
HO
0.3
3-0
0
3*0
361.
13,200
940

300
20.0

1.67
' 5.2 .
11-30-72
30W
25.250
0.06
1080 '
33,300
950
375
0.08
O.k
9000 	
"3
<3
483
0.32
544
0.0050
382
132
0
3.2

610
656
15, 400
1(20

456
6.5
1 1 ,800
6.5
4.9 -
*   Units in mg/1  unless  noted.
**  Temperature of sample when  tested for 00, EC and pH.
                                                                                                                                                                Plate H-IOB

-------
                             LEACHATE ANALYSIS

                                  CELL £
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Col i . MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature * (°C)
Volatile Acids
Zinc
pH
1-23-73
4700
33,200
•iO.I
1360
1(1,700
823
175
0.1
0.3
9000
^3.0
3.0
370
0.60
536
0.0)12
602
248
0
6.4

1040
880
18,420
60


8.0
13.900
41.0
5.1
3-13-73
11,025
40,000
.to. 05
1844
58,100
1565
"•25
0.19
0.6
9500
< 3.0
< 3.0
478
0.45
676
0.0044
690
35
0
5.6
0
1400
1110
26,680
164

958
14.0
18,100
56.4
4.8
4-24-73
8910
50,500
<0.05
2160
51,900
1760
375
0.32
0.6
8000
3.0
<3.0
520
0.21
896
0
895
483
0.40
10.0

1430
12)6
31,680
80


17.0
19,200
64.0
5.2
6-5-73
5250
42,800
*0.05
2600
62,000
1565

0.10
0.4
20,000


525
0.42
896

946
531
0
16.0

1320
1264
30,000



19.0

58
5.2
6-26-73
8925
47,300
<0.05
2605
65,600
1830

0.10
0.20
9800
< 3.0
<3-0
500
0.73
956
0
946
560
0.48
3.6

1470
1344
35.240


1106
29.0
19,560
61
5.3
*   Units in m$/l unless noted.
**  Temperature of sample when tested for  DO,  EC and pH.
                                                               Plate  HMCC

-------
     WATER  ANALV5IS
WATER ADDED TO  CELL  C
SAMPLE DATE
COMPONENT *
Alkal ini ty (CaCO )
3
B.O.D.
Cadmium
Ca !c ium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
CJect. Cond. u mhos/cm
recal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
1 ron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total , as P
P.C.B. ppb
Potassium
Sod i urn
Sol ids - T.D.S.
Solids - T.S.S.
Sol ids - Settle, ml/1
Sulphate
Temperature (°C)
Volati ie Acids
Zinc
.
pri
12-28-71
0.0

1 .0

36
850
73
5

7.6
750
<3
---


36

0. 1
0. 00
0.10

0


502
1 .0
N 1 L


432

7. 2

3-2-72









8.8
650

















15.0


•7.8

_3- 14-22









9.2
700

















18.0


7-6

4-1 1-72









8.9
750

















14.0




4-25-72
304

3.0
'j   : - dfld  pH .
    WATER ANALYSIS
WRIER ADDED TO rrr.T. c
SAMPLE DATE
COMPONENT *
Alkal ini ty
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Col i. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Sol Ids - Settle, ml/1
Sulphate
Temperature " (°C)
Volati le Acids
Zinc
pH

5-9-72








9.8
600

















19.0


7.5
.
5-23-72








7.0
750

















21.0


7.7

6-6-72








7.2
675




















7.8

6-20-72








7.0
900

















19-0


7.9

7-11-72








7.3
800

















214.0


7.9

                                                                                                                 i:d for C,"

-------
                           WATER ANALYSIS

                         WATER ADDED  TO CELL C
















oj>
~~"












. SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
PH
7-25-72
330
0
0
22
12
57

0.07
6.4
800


0.5
0.15
16
0.0102



- — _.
7.9
152
536
<0.5

32
23.5
0
0.09
7.3
8-8-72








7.4
800















19.5


7.8
9-7-72








7.0
825















2J.S


7.9
10-11-72








8.0
800















16.0

'1
8.0
11-8-72








9.4
950















14.5

' •
8.0
*   Units In mg/1 unless noted.                .
**  Temperature of sample when tested for DO, EC and pH.
                                                                PIateH-lie
                             WATER ANALYSIS

                          WATER  ADDED TO  CELL  C
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/ cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium ,
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
PH
11-30-72
30*
'2
0
43
2
56
4
0.04
9.0
850
<3
4
0.3
0
11
0.0105
0
0
0.23

0
5.7
132
440


25
10

0.03
8.0
1-10-73








9.4
700

















9


7.6
2-6-73








8.6
650

















12.5


7.4
3-27-73
292

0
28
0
50

0.06
8.8
800


0.20
0
29
0





8.7
124
480
0

38
14.0

0.07
7.7
'6-26-73
286

p
26
4.0
49

•o
6.3
980
<3-0
C3-0
0.2
0
17
0.0002
0
0
0.56


8.5
24
1040


97
30.1

0.06
7.9S
*   Units -in mg/1 unless noted.
**  Temperature of sample when tested for DO, EC and pH.
                                                                                                                                                                     Plate   H-11D

-------
                          GROUNDVATER ANALYSIS

                                 WELL 1
SAMPLE DATE
COMPONENT *
Temperature (°C)
Alkalinity (CaCOj)
B.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. p mhos/cm
Fecal Coll . MPN/100 ml
Fecal Strep. MPN/100 ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Kltrogen - Nitrate
Nitrogen - Nitrite
Phosphate -Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Sol ids - Settle, ml/1
Volatile Acids
Zinc
PH
Sul phate
1-3-72
15.0






8.3



















7-3
1-18-72
11.0
202
31
<0.05
78
8.58

<0.2
60
6.8
750
15

<0.5
40
0.0003
0.160

o-30
0.013

0
2.35
96.0
636



0.9
7-3
3-2-72
15.5
88
3
<0.1
10
120

<0.2
27
5.8
260
2400

<0.5
43
0 .0004
0 .084

1.07



3.15
50
716



1.2
7-1
.0..2
3-14-72
23.0
184





60
5.4
400













508




7-3
3-28-72
15.5
124





53
6.4
430













452




7.1
* Units in mg/1 unless
**Tempera tu re of samp 1e
noted
 when tested  for  DO,  EC, and pH.
                                                                   Plate H-12A
                                                                                                                                        r:
                           GROUNDWATER ANALYSIS

                             '    'WELL 1  '
SAMPLE DATE
COMPONENT *
Temperature (°C)
Alkalinity (CaCO,)
B.0.0.
Cadmium
Ca 1 c i um
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Col 1. MPN/100 ml
Fecal Strep.MPN/100 ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Kltrogen - Nitrate
Nitrogen - Nitrite
Phosphate -tota 1 , as P
P.C.B. ppb
Potassium

Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sulphate
4-M-72
17.5
121
2
. <.0.1
11
16

< 0.25
58.5
'5.8
400
23

< 1.0
45
0 . 0050
0

0.74



3.1-

64.8
486



0.1


4-25-72
16.0
122






60
6.5
410-














.470




7.1

5-9-72
20.0
136
2
<:o.l
12
23

<0.2
51
4.0
450
460

<1.0
20
0.0047
0.149

0.50




5-9
75
296



O.I
.7-4

5-23-72
18.0
134






54
4.3
450














482




7-3

6-6-72
17.0
. 132



38


62
4.2
475
4




0.096

0.12
•-•-—-.- 	



4.9
78
272




7.0

 *  Units  in  mg/1  unless
**Tempe?tature of  sample
noted
when tested
            for. DO, EC, and pH.
                                                                    Plate H-12B

-------
                         GROUNDWATER ANALYSIS

                                WELL 1
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/IOO ml
Fecal Strep. MPN/IOO ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
7-11-72








2.9
520

















22.5


7-3
7-25-72
200

0
19



<0.02
A. 2
525


0
0
6
0.0075




0
2.4
78




22.0

40.05
7.4
8-8-72








4.2
500

















21.0


7.3
9-7-72
160

0
10
3
59

0
8.3
500


4.9
0
17
0.0047





2.0
98
366


19
22.0

0.08
7.2
10-11-72








4.8
530

















19.0


7.2
*   Units in mg/1 unless noted.
**  Temperature of sample when tested for DO, EC and pH.
                                                                Plate«-12C
                           GROUNDWATER ANALYSIS

                                  WELL 1
SAMPLE DATE
COMPONENT *
Alkal in! ty
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coli. MPN/IOO ml
Fecal Strep. MPN/IOO ml
Iron
Lead
Magnes lum
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature' " (°C)
Volatile Acids
Zinc
pH
11-8-72








4.8
500

















19.0


7.3
11-30-72
140
"2
0
16
2
108

0.05
6.3
600
150
460
12.9
0
12
0
0

0.95


1.5
70
560


73
15.0

O.i»
7.4
12-19-72




















0










1-10-73








9.2
850

















13.0


7.2
2-6-73








7.4
320

















12.5


6.9
*   Units in mg/l unless noted.
**  Temperature of sample when tested for DO, EC and pH.
                                                                                                                                                                    Plate H-120

-------
                             GROUNDWATER ANALYSIS

                                   WELL 1

COMPONENT *
Alkal inity
B.O.D.
Cadmium
Calcium
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen pptn
Elect. Cond. xi mhos/cm
Fecal Col i. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnes ium
Mercury
Mitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Sol ids - T.D.S.
Solids - T.S.S.
Sol ids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
PH


3-13-73
98

0
14
3
73

0.08
12.2
380


28
0
18
0





2.9
59
600


72
14.5

0.11
7.1


6-26-73
130

0
\t>
9.6
50

0.06
2.6
675
<3.0
4.0
27
0
19
0.0004
0.1
'•3
0.8


4.0
73
960


30
35.0

0.76
7.15

SAMPLE DAT
































-




































































*   Units in mg/1 unless noted.
**  Temperature of sample when  tested  for  DO,  EC .and  pH,
tor L>"   "  a:
                                                                 Plat;  H-'2E

-------
                          GROUNOWATER ANALYSIS

                                 WELL 2
SAMPLE DATE
COMPONENT *
Alkalinity (CaCO )
B.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect.Cond. ^i mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Lead
Magnes ium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Nitrogen - Nitrite
Phosphate (total)
P.C.B. ppb
Potassium
Sodium
Soljos - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH '
Sulfate
1-18-72
158
1
<0.05
8.3
0

2.0
25
5.2
400
3

•CO. 5
40
.0004
.016

.38
.003


2.12
38
1372



0.8
7.15

3-14-72
!42
2
0.1
21
5-6

.01
26
6.3
340
< 3

<1 .0
21
.0009
.096

0.1



11
27
286



0.3
7.2 '

3-28-72
132

•'




31
4.7
350













218




7.0

4-11-72
132
1
< 0.1
11
11.0

< 0. 25
19.7
6.6
320
< 3

< 1.0
30
.00019
0.0





1.4
26.2
272



< 0. 1


4-.2S-72
140






33
6-1
320







0.0





208




7.|

* Units in mg/l unless noted
                                                                   Plate  H-13A
                          GROUNDWATER ANALYSIS

                                 WELL 2

COMPONENT *
Temperature"" (°C)
Alkalinity (CaCO.)
B.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Conii. p mhos/cm
Fecal Coll. MPN/10'0 ml
Fecal Strep- MPN/100 ml
Lead
Magnes ium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Kitrogen - Nitrate
Nitrogen - Hi trl te
Phosphate -Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.O.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
PH
Sulphate

5-9-72
! t . '•>
U6

4 0.1
21
12

< 0.2
23
6.0
330
7

< 1.0
30
0.0062
0.112

0.09



I.I.
30
198



. O.I
7-3


5-23-72
20.0
136






21
3-8
360













228




7-1

SAMPLE DATE
6-6-72
19.0
130
9
0.12
'•5
22

'0.2
30
7-5
1130
*- 3

0.15
29
0.0057
0.160

0.05



2.1
2S.5
158



0.14
7.0


7-11-72
iy.o








4.5
360


















7.0


.7-25-72
2J.U








6.2
400










0







7.6

 * Unit'  in iiKj/1  un)i;ss
** Temperature of sample
noted
 when tested for DO,
                                                                                                                                                EC and pK.
                                                                                                                                                                       Plate  M-I3B

-------
                             GROUNDWATER ANALYSIS

                                   WELL 2
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.O.D,
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Fleet. Cond. u mhos/cm
. ecal Coll. HPN/100 ml
Fecal Strep. HPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature** (°C)
Volatile Acids
Zinc
pH
8-8-72








6.1
360

















20.0


7.3
9-7-72
155

0
20
0
20

0
5.0
380


0.4
0
24
0.0025





1.45
44
212


10
22.5

0.08 -
7-'
10-11-72








4.2
370

















18.5


7.0
11-8-72








5.2
450

















19.5


7-3
11-30-72
150
*1
0
58
1
?o

0.03
7.*
360
<3
4.0
0.7
0
16
0.0060
0
0
0.25


0.7
38
238


8
14.0

0.04
7.4
*   Units in rog/1 unless noted.
**  Temperature of sample when tested for DO, EC and pH.
                                                                Plate H-13C
                         BROUNOWATER ANALYSIS

                                WELL 2
SAMPLE DATE
COMPONENT *
Alkalinity
B.O.D.
Cadmium
Calcium
C.0.0.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cond. u mhos/cm
Fecal Coll. MPN/100 ml
Fecal Strep. MPN/100 ml
Iron
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.O.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature** (°C)
Volatile Acids
Zinc
pH
12-19-72




















0.2










1-10-73.








5.6
360

















12.0


7.2
2-6-73








6.4
310

















12.0


6.7
3-13-73
134

0
32
1
48

0.05
11.5
450


0-3
0
15
.0080





1.0
28
160


10
15.0

0.04
7-3
6-26-73
155

0
19
10.4
18

0
6.4
260
3.0
4600
1.6
0
22
0.0004
0.3
1.1
0.64


1.4
34
840


8
35.6

0.16
7.1
*   Units in mg/1 unless noted.
**  Temperature of sample when tested for DO, EC and pH.
                                                                                                                                                                     Plate H-13D

-------
                                GROUNDV/ATER ANALYSIS
                                       WELL 3
                                                                                                        GROUNDVIATER ANALYSIS

                                                                                                               WELL 3
CO
-•J
SAMPLE DATE
COMPONENT *
Temperature (°C)
Alkalinity (CaCO )
B.O.D.
Cadmium
Calcium
C.O.D.
Color (Color Uni ts)
Copper
Chloride
Dissolved Oxygen ppm
Elect. Cond. p nihos/cm
Fecal Col i. MPN/IOO ir.l
Fecal Strep.MPN/100 ml
Lead
Kagnes ium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Hitrogen - Nitrite
Phosphate -Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.O.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volat i le Acids
Zinc
pH
Sul phate
1-18-72
12.0
118
9
< 0,05
40
0

< 0.2
13
6.0
350
4

<0.5
30
0.0004
0.016

2.25
0.003

0
1.88
14.5
276



0.3
7.1*

3-2-72
15.0
78
2
<• 0.1
26
126

<0.2
10
6.6
250
930

<0.5
20
0-0012
0.048

2.00



1.9
14.0
304



.05
7-2
17.2
3-14-72
20.5
116






43
5.0
330













108




7.2

3-28-72
16.0
112






24
6.8
320













214




7.1

4-11-72
17-0
118
2
< 0.1
21
5

< 0.25
13-3
6.4
300
< 3

< 1.0
17
0 .0015
0.04

2.19



1.7
13.5
672



< 0.1


     * Units  in mg/1  unless
    ** Temperature of  sample
SAMPLE DATE
COMPONENT * .
Temperature ( C)
Alkalinity (CaCO )
B.O.D.
^adm i urn
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect .Cond. p mhos/cm
Fecal Col i . MPN/100 ml
Fecal Strep .MPN/100 ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Nitrogen - Nitrite
Phosphate-Total , as P
P.C.B. ppb
Potassium
Sod i urn
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sulphate 	 	
4-25-72
16.0
122





31
6.3
320













202




7.2
5-9-72
19.5
146
2
< 0.1
24
331

<0.2
13
7.2
300
460

< 1.0
20
0.0048
0.088

1-52



1.5
15
366



0.1
7.3
5-23-72
19.0
106





12
3-9
300













214



'
7-1
6-6-72
18.0
102
5
0.15
2.)
38

0.25
19
6.2
300
43

0.20
&
0.0027
0

2.60



2.6
13.8
278



0.22
7.2
7-11-72
22.5






6.2
310


















7.1
noted
,when  tested  for  DO, EC, and pH.
                                                                         Plate   H-14 A
                                                                              t*
 *  Units in mg/1 unless noted
** Temperature of sample when tested for 00, EC, and prt.
                                                                                                                                                  Plate  H-146

-------
                         GRDtJNDWATER ANALYSIS

                                HELL 3
SAMPLE DATE
COMPONENT * . . ..
Alkalinity
B.0.0.
Cadmium
Calcium
C.6.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
fleet. Cond. u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Iroq
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature (°C)
Volatile Acids
Zinc
pH
7-25-72








6.2
400










0






22.0


7.5
8-8-72







V
6,7,
300%


. ;

.•,
" ' *











20.0


7.4
9-7-72
120



15
22.0

0.06
7-1
10- 1 1-7.2







•ft
M
}M


*)
c
f i
V -Jit











19.0


7.2
11-8-72








5.0
350

















20.0


7.2
*   Units in mg/1 unless noted.
**  Temperature of sample when  tested  for  DO,  EC  a.n.d  pH.
                                                                 Plate  H-14C
                           GROUNDWATER  ANALYSIS

                                 WELL 3
SAMPLE DATE
COMPONENT *
Alkalinity
B.0.0.
Cadmium
ta lei ura
C.O.D.
Chloride
Color (Color Units)
Copper
Dissolved Oxygen ppm
Elect. Cone), u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
1 ren
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen r Organic
Nitrogen - Nitrate
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Sulphate
Temperature'" (°C)
Volatile Acids
Zinc
PH
11-30-72
110
•<1
0
50
1
2 If

0.03
7.6
300
23.0
93-0
0.4
0
15
0.8051
0
0
4.50


0.5
20
210


18
14.0

0.04
7.2
12-19-72




















0










1-10-73








7.4
350

















12.0


7.2
2-6-73








*•?
360

















12.0


6.7
3-13-73
150

0
ltd
0
29

0.05
11.2
350


0.2
0
25
0





0.8
32
160


27
15.0

0.07
7.3
*   Units in mg/1 unless noted.
**  Temperature of sample when tested for 00, EC and pH.
                                                                 Plate  H-14D

-------
                                    ANALYSES
                                                                  i,j9f*J H-tiC

                                                               ?•((
         Oxygen   ppm

              "ihos/cm
      Cot '
                                             3-38-72 >
              HbMMOO
     flen " Organi
         e -Total, as P
I Solids - T.S.S.
         :  Acids
 3-5
••-tr.-r-

..6,8-
                                        I ••;•»-


                                        6,,7.
:*.*
 Zinc


par—

| Sulphate


 * Units in.mg/1 unless noted*       f.,.BO  er  and DH
** Temperature of sample when tested for DO, EC, and pH
I


1
r

1

i

j
1 1

T
T
V.L
m \


M




1
4-J

12.0
106

10

0.05
200
o
1.2
27
5-5
300
<»3

< 0.5
300
1.0006
3.163)0
e o
0.08
0.010

0
2.10
13-0
2*
0
n.oi'i
30
0012
1 .23*00
J-Q
0.30

] S8 '
i °
r*s
i »*5
t 262
; ;»

: ,-A-'..r.
|l8.0 I
il» ;1
«
I ' M

i :'t
1
J
24 :•
4.3R
300* "8<4
n-a
0
rg
#rd
<1'0
m
**t
S'8

S3
i
] " '
,,,

! 2i*<--
11 ':-'
i.
i .1
i
i



<




B




.









L
f
J
1.0
'22

2 "i
- , : 1
0. r 1
20 ^
"
0.25
16.7
5-9
3db*5»lt
<"3«
o 1
< Ut»?
35
1.0033
0^0
*'*
O.'O?

Jj
5
l.¥
16.&
1)04
^ :^
.
•
3-v; •.!
17














,







«
L
u
!
.0
132
1
! j

1
1

28 1
.8 1
:so 1

I

1
1

1
1
1

1
. 1

2>(8

J
1
                                                                      Plate  H-IJA
                                                                                                      -POUHDVATEP ANALYSIS


                                                                                                             V.'tLL '•
COMPONENT ^ 1 S-9'72 I 5-"'72 I
Temperature"" (°C) 1
[Alkalinity (CaCOj) J
B.O.D.
1 Cadmium 1

I Calcium 1

1C. 0.0. 1
I Color (Color Units) 1
1 Copper 1
=_=— — -r—
19-0
11(0
2 1
>• n 1 1
^ U . 1 1
2? 1
1
12 1

< 0.2
7S
Chloride 1 " 1
1 1 5 0 1
1 Dissolved Oxygen ppm 1
1 Elect. Cond. p mhos/cm 1 j
1 Fecal Coli. MPN/100 ml 1
Fecal Strep.MPN/100 ml

1 LCad

JKagnesium |
1 Mercury
1 Nitrogen - Ammonia
I Nitrogen -, Organic
I Nitrogen - Nitrate
I Nitrogen - Nitrite
1 Phosphate-Total, as P
JP.C.B. ppb
j Potassium
I Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sulphate 	 	
V 1

«£ 1.0 '


0.027
0.112
0.16



1 1-9
1 24
j 202
1



I 0.2
1 6.6

J 	
"^ 	
18.0
120







15 I
• l(.0
300







6-6-72 1 7-11-^ >"-72
=BB»B»=l^==i===^^^S^^^^
1
"'
0.18
_ A 1
21.0


2.8 I . i
^1 1
3

0,59
22
3.Z
310
< 3 1
O'^ft
.at

90
0.009*.
0.20*
0.3S

1
;


256





Z.i
ta
32*



..
1 1 °~y*
6.7 | 6Jf




5.5 1
240







i '








19.0 1


1





4.0 1
400 1


1

1
i




0 1





1 1

6.9 7'3 !
| 1 	 1

                                                                                                       * Units  in mg/1  unless noted
                                                                                                       ** Temperature of sample when  tested  for DO,  EC  an*pH.
                                                                                                                                                                            Plate H-15B

-------
                                                                                r 7i     t
                        GftOUNOMATER ANALYSIS

                              4IEU *
SAMPLE DATE
COMPONENT *
Alkalinity
0.0.0.
CadMlwp
Calclu*
C.0.0.
Chloride
Color (Color Unit*)
Cooper
Dissolved Oxygen pp»
CUetv Cond. n *tos/o»
Fecal Colt. HPN/IOO stl
focal Strap. HPN/IOO ml
Iron
Lead '
MagnesltM
Narcury
nitrogen - Avwnla
•Itrogen - Organic
Nitrogen - Nitrate
Phosphate-Total, a* P
P.C.I, ppb
Potass tun
Sod tup
Solids - T.D.S.
Solids - T.S.S.
Solids -Settle, ml /I
Sulphate
Temperature** (°C)
Volatile Acids
Zinc
PH
8-8-72








«.o
310

















18.0


6.6
»-J-72
'J5

0
32
0
to

0
5.0
-,-;fOO


1.1
0
is
0.0037





1.40
21
186


18
22.0

0.04
6.6
M-15-72
130
0
/O.I
26
0
22

0.02
.-».*.'
•' ^ •:
«3.0 i
•3.0
1.8
0
I7.S
0.00*8
0
0
O.I

0
1.16
28
288
23

73
16.0

0.06
6.9
3-27-73
too

0
32
1
13

0.06
5.6
. "•'•'••HO ..• .';


1,65
0
21
0.0*16





1.2
. 17.5
280


35
17.5

0.05
6.4
































Units In mg/1 unless noted.
Temperature of sample when tested for DO,  EC and pH.
                                                           Plate H-15C

-------
                            WATER  ANALYSIS   REPORT
   PH. 1419) 368-3329

  EDISON WAY AT I t TH AVENUE
                      WATER. WASTE WATER AND AIR POLLUTION

                                    CHEMISTS AND ENGINEERS
      P. O. BOX 2266
  MENLO PARK. CALIF. 94O2S
                                          ESTABLISHED 1927
                               LABORATORY FACILITIES FOR ALL
                                "STANDARD METHODS" TESTS
REPORT TO •   Terratech,  Inc.
          •   193 E.  Gish Road
          .   San Jose, California
95112
SOURCE OF , DATE c /I c DATE , /o ,- _
SAMPLE HammeJ. REC'D D/^D REPORTED o/*//.u
ANIONS
Nitrate (NO.)
Chloride (Cl)
Sulphate (SO,)
Bicarbonate (HCOj )
Carbonate (CO3 )
Phosphate (PO« )
MILLIGRAMS
2.8
38.
11.
181.
0.0
0.1
Total Equivalents Per Million
CATIONS
Sodium (No)
Potassium (K)
Calcium (Ca)
Magnesium (Mg)


MILLIGRAMS

20.
0.40
24.
25.

Total Equivalents Per Million
EQUIVALENTS
0.04
1.07
0.23
3.00
0.00
0.00
4.34



0.87
0.01
1.20
2.06

4.14.
DETERMINATION
Phenolphtholein AlkalinityfCaCOa )
Methyl Orange Alkalinity (CaCOj )
Total Hardness (CaCOj)
Calcium Hardness (CaCOj)
Magnesium Hardness (CaCOj)
Total Solids - Calculated
Total Solids - Evaporation
Loss On Ignition
Total Fixed Residue




Sp. Cond. - Micromhos 25°C
MILLIGRAMS
PER LITER
0.0
148
164
60
104
233
245






346
DETERMINATION
Silica (SiO. )
Iron (Fe)
Manganese (Mn)
Boron (B)
Fluoride (F)








Hyd. Ion Cone. (pH)
MILLIGRAMS
PER LITER
20
0.77
0.03
0.1
0.33





t,'


7.24
      THIS IS AN APPROVED COMMERCIAL WATER LABORATORY DESIGNATED BY THE STATE OF CALIFORNIA DEPARTMENT OF PUBLIC HEALTH
COMMENTS.
             ORIGINAL GEOTECHNICAL INVESTIGATION
                                                       Reported by
FORM c »/««
                                                                                  PLATE   H-16A
                                                    191

-------
                                    GROUNDWATER ANALYSIS

                                     CELL ACE SUBDRAIN
                           GROUNDWATER ANALYSIS

                            CELL A  S  E SUBDRAIN
f\5  '  -..







f

t-1
t


.,
""•


1 .
1 •














SAMPLE DATE
COMPONENT *
Temperature (°C)
Alkalinity (CaCO^)
B.O.D. r <
Cadmium
Calcium
C.o.o.
Color (Color Units)
Copper
IJHlorlde ^ ' $'
Dissolved Oxygerf ppnt •
Eliftt.Cond. a mhos/cm '

pVcat Coli .MPN/100 ml
F«ca{ Strep. MPN^l 00 mi-
lead^
Magne,slun , :
i ' :
Mercur» i ; , : ,.
Nitrogen - Ammonia ;
Nitrogen - Organic' -
KUrogen - Nitrate
Nitrogen - Nitrite
Phosphate-Total, as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, ml/1
Volatile Acids
Zinc
pH
Sulphate
12-8-7,1 ,
I
. 116 ;
0

.10
it
5

'23
, 1

I * 4
' ^ . ^
t

22

' '
!'"•" '







216




5-6

1-7-72
15.0




\ t ( *
;


2." 4
2.1(00

i.l




< »



1,*

''•»




'.1
j
i










5.8

2-15.-72
.16.5 :
* ^ • '
.' ' ' •
i


'


**
%*

2.1




i
i















•

' • '

' '






5.5

3- t4 -72
17.5



t





11
3














3
10









!
i
j







S-1*

3-28-72
16.0 i
1







4.9
300



i

i























[ '•
j







5.5

          * Units in mg/1 unless
          ** Temperature of  sampl
noted
e when tested for DO, EC, and pH.
SAMPLE DATE
COMPONENT *
Temperature (°C)
Alkalinity (CaCO )
8.0.0.
Cadm i urn
Calcium
C.O.D.
Color (Color Units)
Copper
Chloride
Dissolved Oxygen ppm
Elect.Cond. ^u mhos/cm
Fecal Coli. MPN/100 ml
Fecal Strep. MPN/100 ml
Lead
Magnesium
Mercury
Nitrogen - Ammonia
Nitrogen - Organic
Nitrogen - Nitrate
Nitrogen - Nitrite
Phosphate -Total , as P
P.C.B. ppb
Potassium
Sodium
Solids - T.D.S.
Solids - T.S.S.
Solids - Settle, mi/1
Volatile Acids
Zinc
pH
Sulphate
it-25-72
17-0



•


5-3
350

















5-5
5-23-72
17.0






*.9
350

















5.7
6-6-72







7.4
340

















5.9
6-20-72
18.5






5.2
320

















6.7
7-11-72
20.5






5.5
350

















5.7
                                                                             Plate H-17A
* Units in mg/1 unless
**Temperature of sample
noted
when  tested for DO, EC, and pH.
                                                                                                                                                                                 Plate H-17B

-------
                            GROUNOWATER ANALYSIS
                                               SAMPLE DATE
tOHPONEHT f
                          9-7-7=
                                    lli-30-72
                                                l-10r73
                                               3-27-73;
        -T—

Alkallnltyt
fe.O.D.    1
Cadmium   j
JC^IcluiiH ; *
•chiorrW
Dto&fcd
WMB-W
Mercury
Nitrogen
Nitrogen
 i—TT~A3
Nitrogen
 roMMnu
 **»&•
 V«>ellle
                 100 ml
          >r Un i 0
                                              ra
                                                     3-1
                                                     5'3
                                        16
                                                  150  i

                                                    0  :
                                                  AS  :
                                                    i  :
                                                   18  •
                                                      |
                                                  0.06;
                                                      i
                                                  6.0  j
                                                  Ii20  i
                                                             0.13
                                                               0
                                                              13
          e44*»
                                                             1.1 f
                                                             30 j
                                                             220 !
                                                             1*1
                                     ...SJL.L..
 *   Units  In mg/1 unless noted.
 ** Temperature of
                                                    PH.
                                                               Plate H-17C

-------
OOSfftVATION WELLS AMD PIEZOMETERS



                         tat

DATE
MI-72
3-t-72
V.lfc.T*
™1™/*
l-»l-72
4-11-72
V2S-72
$-9-72
MS-72
(W-7I
**»•!»*
f»2*-72
W-7I
>Wi
«»-H-n
iH-li
ll-JO-Tt
I«-1»-7J
1-10-71
«^-73
9-U:7J
I-I7-7J
**IO-73
S-15-73
«-»-73

1
4.5
t.O
S.7
f.5
5.7
5.7
S.I
5.7
«.o
-
«.1
4.1
(.4
t.t
5.9

*.7
M
2.1

1.7
l.«
3.9
MEI
2 "
7.0
1.0
7.2
7-1
7.J
7.*
7.5
7.*
S.1
-
.1
.2
.1
.3
.»

».2
3.J
3.1
-
3.*
4.2
7.*
.IS
3
1.5
7.0
4.5
«.J
4.2
4.*
(.4
$.«
7i7 ,
-
*.k
9.1
9.7 •
*.9
*.7

3.1
2.%
3-«
-
3.a
3.1


k
18.5
19.0
11.5
11.7
11.9
11.9
19.0
19.1
19.3

I9.»
19.5



I7.«



14.1




1
10.0

*.<

J.4


a.3
2.4
-
2.2



1.1



O.I


0.7

2
1.0

1.4

1.7


1.S
i.9
- •
1.9



••>



0.0


0.0
HEI»
3
HOM

J*

4.0


A3
2.4
• •
2.1



1.1



0.9


0.5
«TE»S
4












.










5























4






















                                             PLATE   HH8A

-------
                    CUMULATIVE LEACHATE PRODUCTION
Dete
12-7-71
12-15-71
12-19-71
12-28-71
1-3-72
1-11-72
1- 1 8-72
2- 15-72
3-2-72
3-14-72
3-2R-72
4- 11 -72
4-25-72
9-7-72
10- 15-72
10- 1 7-72
10-18-72
10-19-72
10-20-72
10-21-72
10-24-72
1 1-8-72
1 1-27-72
12-6-72
12- 1 1-72
12-18-72
12-21-72
(1)
Ce! 1 A - Ga' Ions

Tr
Tr
T r
Tr
Tr
Tr
0. 3
0. 3
0.3
0. 3
0. 3
0. 3
0.8
30.8
50. 8
--
80.8
80.8
80.8
81.8
81.8
81 .8
81 .8
81 .8
81 .8
84.3
(2)
Cell R - Gallons
830
833
834
837
838
83?
838
838
838
838
838
838
838

89?
958
1018
10&3
1093
1153
1 164
1 164
1 164
1 164
1 1 6 •'-
1 164
1 164.5
(3)
Cell E - Gs ) lens

Tr
0 . 1
0 . 1
0. 3
0.7
0.9
1 .9
2 . 1
2 .2
2 .2
2 .2
2 .2
-
-
17.2
-
22 .2
22.2
22.2
23.7
46.2
71 .2
81.2
?C .2
116.2
116.7
(!)  An estimated  1710  gallons of rainwater  added  to  Cell  A during
    cons t rue 11 on.
(2)  An estimated  7268  gallons of rainwater  and  34,000  gallons of
    additional water  added to Cell B to obtain  field capacity.
(3)  An estimated  7420  gallons of rainwater  and  27,000  aallons of
    septic tank  pumpings  added to Cell E during construction.
                                                            PLATE H-19A
                                                                                                             CUMULATIVE LEACHATE PRODUCTION
bete
12-26-72
1-4-73
1-1 1-73
1-18-73
1-26-73
2-1-73
2-8-73
2-15-73
2-22-73
3-1-73
3-8-73
3- 15-73
3-22-73
3-29-73
't-5-73
14-12-73
4-19-73
4-26-73
5-3-73
5-10-73
5-17-73
5-24-73
5-31-73
6-7-73
6-14-73
6-21-73
6-28-73
(1)
Cell A - Ga' Ions
8(4.3
114.3
1 114.3
119.3
135. 3
140.3
140. 3
140.3
145.8
145. 6
145.8
145.8
145.8
145.8
145.8
145.8
145. C
146.0
146.0
146.C
146.0
146.5
146.5
146.5
146.5
146.5
146.5
(2)
Cell B - Gallons
1164.5
1164.5
1 164.5
1 164.5
1 165
1 165
1 165
1 165
1170.5
1170. 5
1)70. 5
1170.5
1 170.5
1 170.5
1 170.5
1170.5
1 170.5
1171.0
1171-0
1171.0
1171.0
1171.0
1171.0
1171-0
1171.0
1171.0
1171.0
(3)
Cell E - Gallons
146.7
241.7
341.7
459-7
590.2
782.2
980.2
1171.2
1352-7
1490. 7
1632.7
1753.7
1775-7
1874.7
1959.7
204 1 . 7
2120.7
2189 .2
2253.2
2314.2
2368.2
2417.7
2465.7
2414.7
2464.7
2505.7
2548.7
                                                                                                                                                     PLATE H-19B

-------
                              LYSIMETER  SAMPLE FIELD ANALYSIS
IO
Lys imeter
Location
Cell A -
4 feet below
bottom of Cell





Cell A -
8 feet below
bottom of Cell





Cell E -
8 feet below
bottom of Cell






Date

1-18-72
2-15-72
3-14-72
5-23-72
6-20-72
9-20-72
12-19-72
4-10-73
1-18-72
2-15-72
3-14-72
5-23-72
6-20-72
9-20-72
12-19-72
4-10-73
12-15-71
1-18-72
2-15-72
3-14-72
5-23-72
6-20-72
9-20-72
12-19-72
4-10-73
Vo I ume
ml
200
30
30
70
50
30
50
blocked
400
200
50
240
250
400
150
0
50
300
35
• 50
35
50
30
50
blocked
PH

5.6
7.1
7.1
6.5
8.4
5.9
6.5

5.7 ;
7.0
7.4
6.S i
7.3 -
6.4 i
6.8 ;
'
7.4
6.6
7.4 '
6.9
7.1
8.3
7.2
7.0

D.O."
ppm
5.0
8.4
7.8
9.0
-
9-0
-

1.3
9.3

ioio
912
9.6
10.2

5:9
8.7
8.0
10.4
-
8.9
-

E.C.
p mhos/en
380
-
-
-
-
-
- is-:;

310
_
_
ito
275
300

290
-
-
-
-
- **

           Water samples are collected from lysimc-ters by displacing the sample with
           air from a  pressurized tank.   This procedure thoroughly aerates  the sample.
           Insufficient quantity for D.O. or E.C. tests.
                                                                          PI,HeH-71A

-------
SOLUTION ANALYSIS
    SUty Sand

Determination - mg/1
AfkaHnlty
Calcium
Electrical Conductivity
Magnesium
Potassium
• ! i i ' : : : ; i ;
SIQfl 1 Uin • ' '
f., - > : • . .-.-I
* i •' i-i • r : : i :
Time After Immersion
t week
170™ 	
30
500"""
30
3.5
i i
31
! i 7.2T
;•!... -j ...'•:' ' . ' '• ': I : '•• '• i
•"I •. J ; • i • i .... p
f
•'! T •[ -.- ;-"Y -•-':• •'V':;--


"nifr
Alkalinity
Calcium
Electrical Conductivity
Magnesium ^
Potassium
Sodium
PH

6 months
~~^
; 500
23
~~ 1.85


i i ConcrSete ;34nd?;Sirl
! , ^ ! jo: i o ; o o : o
1 year
168
600
29
17.0
8.8
2 years
: . ." ::; i. "** i
. .1 -. ^. ; ^ - * U \ |
is ;~ J2|(

170
28
500
31
2.2
31
7.2
_6 mohtjhf

170
36
500
23
1.75.
31.6
7.9
; ] year
- ^™ .. ^..
168 ;
32
soa
28
1.8
32
8.7
_J_VWrsj !
' - •"- •."' j •». '
                 1 1  I :  i
i .."'':
• ; 1 '...:••: ;
! I •! ' ; ; ; ; ij's
(A^a >£»' f^tfn*! n ^ t* 'f'TM*! "«> '• tn/T-/'! 	 Jr*-~
jUetfirini no t ion - -"»yr * ? .
AlkLlfnlty
3f£l«ic tr lea I CpnditctlV-liy
-I • 1 • '. i i ! i ! 1 |
Magnesium
C i- i • • : ' ';
"; Potassium
-'* . i ' i • ' T j
|pH] ,„;.,, = .. ;,,is:.;J,,L|,,L
'....-' 	 :... .'.. ; 	 •. ...... .,-.,. :....i. ;._l_i


• •
— 14-
1

i
i
1
j
!
i
isb
i
P

i i
] .L
i i
18C
|33
iJo/
!« ^
L
si?

Fa
s

L



,
9
*i
0
0
3

(C|r

j

I
i
i



~ *

ajv<

1
ft


i
j

AJ
W
i
|
j'
t "

m





k.



fie! After
sntHs '

'$0 I
1! 1"^
116 ,
-li-AcL :
2^1
JAl ,
i ;
i i : 	


• Immersion
41 VW^f
T
»9,0
- 40
! ,460,
i
25
.0-
31
j , \ • i
I a- n* ! -E. j m * n .
! ; i

"

1
v








s ^ ^ ' '
,* ye0r^s -
" ] < . -;

> - > i
i' '^
' .. •-
l - • " '
H * - - -i —

                                Plate H-22A

-------
                    RAINFALL. EVAPORATION AND RUNOFF
NOV.
1971
,
2
3
4
5
6
7
8
9
10
11
12
13
\k
15
16
17
18
19
20
21
22
23
2k
25
26
27
28
29
30

TOTALS
RAIN-
FALL











0.29
0.25


O.OS












0.96


1.52
EVAP.
































RUNOFF
CELLS A * E
METER
READING








"























TOTAL
GALLONS








™*

"





















CELL B
METER
READING
































TOTAL
GALLONS
































REMARKS
No Evaporation <
runoff, data was
for this month.

Evaporation reported In Inches
                                                                   PLATE H-23A
                                                                                                                         RAINFALL, EVAPORATION AND RUNOFF
DEC.
1971
1
2
3
V
5
6
7
8
9
»0
II
12
I)
1*
IS
It
»7
18
19
20
21
22
23
24
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL

0.50
0.32


0.2*


0.27
0.09
0.01

0-77.

0.05






0.51
0.22
0.06


' -.77

0.03



-------
                    RAINFALL,  EVAPORATION AND RUNOFF
JAN.
1972
1
2
3
!)
5
6
7
8
9
10
ri
12
13
\k
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL



















o. 13
0.09
o. n

0.25
0.28
0.01
0.58
0.03



1.1(8
CVAP.



















,












RUNOFF
CELLS A s E
METER
READING
































TOTAL
GALLONS
































CELL B
METER
READING
































TOTAL
GALLONS
































REMARKS
No evaporat i on c
runoff data was
for this non th .
Evaporation reported  in  Inches
                                                                  PLATE H-23C
                                                                                                                       RAINFALL, EVAPORATION AND  RUNOFF

FEE
1972
	 1
2
3
_5
6
8
	 9
	 10
1]
12
'3
I';
'5
16
17
18
19
20
21
22
23
^k
25
26
27
28
29
30

TOTALS

RAIN-
FALL
0. 50
0.81)

_]_. 30



- ---



0.39
0.02
0.03



0.08
0. 15


3.31



- - -


-- -—-



















CELLS A
METER
READING


	
— - - —


















RUNG
S. E
TOTAL
GALLONS


- —
	


















FF
CELL
C.ETEK
READING


	 ._




















6
TOTAL
GALLONS
--

- --- --
	

	
















Fvaporation reported  in  Inches
                                                                                                                                                              REMARKS

                                                                                                                                                                 No  evaporation  or
                                                                                                                                                                 runoff data was  tak
                                                                                                                                                                 for  this  month.
                                                                                                                                                                      PLATE H-23D

-------
                    RAINFALL, EVAPORATION AND RUNOFF
                                                                                                                          RAINKALL,  EVAPORATION AND RUNOFF
MARCH
1972
1
2
3
M
5
6
7
8
9
10
11
12
13
11)
15
16
17
18
19
20
21
22
23
2A
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL

0. 10
0.08






0.05














0.25






0.48
EVAP.
.160
.128
.032
.077
.077
.192
.077
. 160
.0614
.128
.128
.077
.06>t
.128
. 128
. 192
.061.
.077
.077
.064
.064
.077
.077
.077
.064
.288
. 160
.064
.064
. 160
.064
3.253
RUNOFF
CELLS A S E
METER
READING
732























732







TOTAL
GALLONS
























0






0
CELL B
METER
READING
420























420







TOTAL
GALLONS
























0






0
REMARKS
Evaporation and ru
meters were operat
as of March 1st.
Runoff meter read!
a re the initial re
after testing.
Evaporation reported in Inches
                                                                    PLATE  H-23 E
APRIL
1972
1
2
3
;,
5
6
7
_ 8
9
	 10
(I
12
13
U;
15
16
17
18
IS
20
21
22
23
24
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL




0. 15
0. 15

	
JU5JL
0. 26









T.22








1.36
EVAP.
.064
. 128
.077
. 192
.077
. 128
.064
. 160
. 160
_.iil
-------
                    RAINFALL, EVAPORATION AND RUNOFF
MAY
1972
1
2
3
i)
5
6
7
8
9
10
11
12 '•
13
14 >
15 '
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
rOTALS
RAIN-
FALL































0.00
EVAP.
*
*
*
*
*
*
*
*
*
.128
.256
.288
L?88
.25$
,128
.128
.166"
. 160 '
.192
.128
.160
.077T
.224
.077
.128
.077
.064
• 064
.256
.160
.160
3. 559
RUNOFF
CELLS A £ E
METER
READING
732









r !

(•

•: '

















TOTAL
GALLONS
0






























0
CELL B,
METER
READING
549



























j



TOTAL
GALLONS
0






























0
REMARKS
* Evaporation gage was
beinq repaired and
was not available for
recording on these
dates.
Evaporation reported in Inches
                                                                    PLATE H-23G
RAINFALL, EVAPORATION AND RUNOFF
JUNE"
1972
1
2
3
4
5
6
8
9
10
; 11
12
'3
!4
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

TOTALS
RAIN-
FALL








.19

-.- 	



















0.19
EVAP.
. 192
. 160
.128
.128
.352
.160
h . 160
. 160
.064
^.128
-256
^288:
.224
.256
.256
.224
-•131;
. 128
.192
.077
.128
.128
.256
. 160
.077
. 160
.128
.077
.256

5.287
RUNOFF
CELLS A - i E
METER
READING








732
















732


TOTAL
5ALLONS







0


















0

0
CELL B 	
METER
READING








549

	 ..

















549


TOTAL
GALLONS





._.
0

	

















0

0
REMARKS
                                                                                                      Fvaporation reported in Inches
                                                                                                                                                                          PLATE H-23 H

-------
                    RAINFALL, EVAPORATION AND RUNOFF
JULY
1972
1
2
3
!)
5
6
7
8
9
10
II
12
U
14
IS
li
17
IJ
19
20
21
22
23
24
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL































0.00
EVAP.
• 397
.160
.192
.192
.192
.077
.1(0
.160
.320
.800
.197
-51J
.768
.896
.576
.320
.224
.256
.128
.128
.1(0
.160
.064
.192
.160
.192
.320
.192
.160
.128
.224
9.111
1 RUNOFF
CELLS A S E
METER
READING
732































TOTAL
GALLONS
0






























0
CELL B
METER
READING
549































TOTAL
GALLONS
0






























0
REMARKS '
fvaporatlon reported In Inches
                                                                   PLATE H-23  I
                                                                                                                          RAINFALL.  EVAPORATION AMD  RUNOFF
AUG.
1972
1
2
3
4
5
6
7
8
9
10
II
12
13
!
-------
                    RAINFALL, EVAPORATION AND  RUNOFF
SEPT.
1972
1
2
3
ii
5
6
7
8
9
10
11
12
13
ill
15
16
17
18
19
20
21
22
23
2
-------
                    RAINFALL, EVAPORATION AND RUNOFF
NOV.
1972
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

TOTALS
RAIN-
FALL


1.33
0.01


0.56


0.70
0.34

1 .06

2.09
0.27

0.04
0. 14












6.54
EVAP.
.064
.077
.032
.000
.064
.064
.064
.288
.128
.128
.224
. 192
. 160
. 160
.192
.288
.288
.256
.128
.224
.096
. 192
.192
.128
.064
.064
.320
.224
. 160
.064

4.525
RUNOFF
CELLS A S E
METER
READING
2221


4889


6183
6670


8350

nooo

23600
25790










25800


25800


TOTAL
GALLONS



2668


1249
532


1680

4650

10600
2190










10


0

23579
CELL B
METER
READING
5087


6500


74J8
7588


8240

10050

15S6Q
16320










16380


16380


TOTAL
GALLONS



1413


938
ISO


652

1810

5510
760










60


0

11293
REMARKS

Evaporation reported in Inches
                                                                    PLATE  H-23 M
                                                                                                                          RAINFALL,  EVAPORATION AND RUNOFF
DEC.
1972
	 	 1 	
2
3
'4
	 5
6
8
0
10
II
U

• 14
15
IS
	 17
18
13
20
21
22
23
24
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL
	
0.24

0^32
0.56

	
' 0.03
0.50
1.83
, 0. 15
0.05
1.06


0.12
0.10




0.10



5.06
EVAP.
_-_P12_
.000
.032
.288
. 256
.192
.320
.416
.320
-J2D...
L1&
. 128
.000
.096
.096
.000
_ .032
.000
.000
.000
.256
.032
.352
.864
. 160
.064
.480
.352
.288
.736
6.432
RUNOFF
CELLS A s E
METER
READING
25800

25800
27410

-- - --

.. ZB79Q


36000
41460


41490



41490

41490




TOTAL
GALLONS
	 _0_

0
1610

, 	

lisa




7210
5460


30



0

0



15690
CELL B
METER
READING
16380

16380
16910

-US 40




19280
218S-H


21880



21880

21880




TOTAL
GALLONS
.___0 	

0
530

;-. 630


i
!
! •*»
1 ...2*00

0



0

0



5500
REMARKS
* Meter failed dur
this period at ri
Meter repaired.
I
i
i
                                                                                                      rvaporat ton  reported  in  Inches
                                                                                                                                                                          PLATE  H-23 N

-------
                    RAINFALL, EVAPORATION  AND  RUNOFF
JAN.
1973
1
2
3
4
5
6
7
8
9
10
11
12
13
!4
'5
16
17
18
19
20
21
22
23
24
25
26 1
27
28
29
30
31
TOTALS
RAIN-
FALL







1 .20
1 .03
0. 22
3.07
__U1_

0.10
2.17

1.81

0.50



0.21)
0.16



0.69
0.08
0.16
14. 16
CI/AP.
.800
.224
-352
.288
.2't'i
.256
.000
.032
.061*
.064
.032
,000
.064
.192
.096
.224
. 160
.224
.416
.224
.128
. 128
. 128
.064
.288
.256
.288
.288
. 128
. 160
.244
6.036
RUNOFF
CELLS A S E
METER
READING



41490



45870
50940
51830
71700
91800


91810
106250

1 19800
1 19800


12)890
121890
121890
122610
122610


124500
126380
126940

TOTAL
GALLONS



0



4380
5070
890
19870
20100


10
14440

13550
0


2090
0
0
720
0


1890
1880
560
85450
CELL B
METER
READING



21880



24080
26340
26780
36540
45790


45920
51960

57630
57630


58060
58060
58060
58270
58270


58560
59100
59170

TOTAL
GALLONS



0



2200
2260
440
9760
9250


130
6040

5670
0


A
430
0
0
*
210
A
0


290
540
70*
37290
REMARKS
* Cell "B" runoff
metering device rr
function. Result
questionable till
2/17/73.
Evaporation  reported  in  Inches
                                                                 PLATE H-23 0
                                                                                                                     RAINFALL, EVAPORATION AND  RUNOFT
                                                                                                  evaporation  reported  in Inches
FEB .
1973
!
2
_ 3_
...L
_...Z - -
8
-5 _
__,0
1 1
' "
-£-•
15
16
l?
18
19
20
21
22
23
2k
25
26
27
28
29
30

TOTALS
RAIN-
FALL
QJi
0 . 4_0_
1 .04
0.35
0.32
0 .Ok
0.06
0.86
a.Z9
0.0 5-
0.22
0.59
0 . 86

0.01





0.76
0.01
0.96
1 .04
0.03



8.54
rvAF.
.,.28_8_
_., 132
...22 ',
. 320
. 192
.128
.192.
. 160
. 160
.096
	 22_4
.096
. 128
.288
.288
.288
.288
.381.
.256
.1(16
.5l| 4
.256
.288
1 .381*
.320
.22't
.096
.224



6.944
RUNOFF
CELLS A S E
METER
READING
_ 126940
126950
1 36560
143150
143 _l?0
160860
160860

LJ60860

163423

.172760




TOTAL
GALLONS
0
1 0
9610
6590
40
1 7670
0


0

2563


9337



1*5820
CELL B
METER
READING
59170
-19170
62350
61)990
64990
71790
71 790

71860

73530


7.868C



TOTAL
GALLONS
0
0
3 1 80
261(0
0
6800
•jcrx
o""


70

1670


5150




19510
                                                                                                                                                            REMARKS

                                                                                                                                                             Ce1 I  "B"  runof f
                                                                                                                                                             metering  device
                                                                                                                                                             malfunction.  Results
                                                                                                                                                             questionable,  till
                                                                                                                                                             2/17/73
                                                                                                                                                                    PLATE H-23P

-------
                    RAINFALL, EVAPORATION AND RUNOFF
MARCH
1973
1
2
3
'i
5
6
7
8
9
10
II
12
'3
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL
0.0k

0.86
0.01

0.47

0.38

0. 18








0.56

0.32








0.58

3.40
EVAP.
.288
.352
.064
.192
.224
.256
.288
-320
.288
.096
.384
.576
.800
.736
.288
.256
.416
.120
.064
.416
.384
.384
.544
.224
.256
.288
.544
.640
.448
.032
.448
10.816
RUNOFF
1 CELLS A & I
METER
READING
176440
176440





183210






183210






184780






184780



TOTAL
GALLONS
3680
0





6770






0






1570






0


12020
CELL B
METER
READING
81030
81030





86130






86300






87710






87710



TOTAL
GALLONS
2350
0





5100






170






1410






0


9030
REMARKS
Fvaporation reported in Inches
                                                                    PLATE  H-23Q
                     RAINFALL, EVAPORATION AND RUNOFF
APRI L
1973
1
2
3
4
5
6
	 I.....
8
9
	 to
11
12
M;
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

TOTALS
RAIN-
FALL



	
0.19

















0. 19
F.VAP.*
, 	 .516
t. 153
.800
. 800
.5J2
.485
_._60£
. ..._: 6_I?
.672
_,J6J
	 .32S.
.480
.320
.38<<
.480
.192
.640
.640
.640
.961
1 .280
.640
.640
.608
.576
.224
.288
.320
.352
.640

17.674
RUNOFF
CELLS A S E
METER
READING




1 85780

185780


185780
185780
185780





18780



185680


TOTAL
GALLONS




1000
0



0
0
0





0




0

1000
CELL B
METER
READING




884!,:

68440






88440





88440




88440


TOTAL
GALLONS




730
0



0
0

0





0




0

730
REMARKS
'•'Evaporation  reported  in  Inches
                                                                     PLATE  H-23

-------
                    RAINFALL, EVAPORATION AND RUNOFF
MAY
1973
1
2
3
4
5
6
7
8
•3
10
11
12
13
U
'5
16
17
18
19
20
21
22
23
21)
25
26
27
28
29
30
31
TOTALS
RAIN-
FALL























0.07
0.01






0.08
EVAP.
. 320
.320
.38l(
.M2
.kitB
.5ltU
.736
.832
.412
1 . 152
. 800
48n
.q?6
.5l;4
.54A
.54'
.ye*
_ .^81
.416
.54*
.48C
.44E
-32C
.256
.60S
.832
.928
.92£
.480
.480
.44!
17.30'
RUNOFF
CELLS A 5 E
METER
READING
185780

1 85780






185780






185780





185780









TOTAL
GALLONS
0

0






0






0





0








0
CELL B
METER
READING
88440

88440






88440






88440





88440









TOTAL
GALLONS
0

0






0






0





0








0
REMARKS

Evaporation reported in Inches
                                                                    PLATE  H-23 S
                                                                                                                          RAINFALL,  EVAPORATION  AND  RUNOFr
JUNE
1973
	 I
2
3
'(
5
6
	 Z_
8
9
!0
1)
12
'3
!':
1C
16
17
18
19
20
21
22
23
2k
25
26
27
28
29
30

PJTALS
RAIN-
FALL
















TVAP,
_-_5_li
.480
.608
.480
. 384
1.217
_!_._! 5_3
1 .856
.961
_^?6l(
^.^8.6.4
.928
.-86k
. 896
.832
.512
1.12)
1.153
1 .249]
1.217
1.376
.576
.480
.896
1 .21(9
1 .661.
1.217
.61(0
.704
.704

27.657
RUNOFF
CELLS A S E
METER
READING
1 85780
185780
185780




185780




TOTAL
GALLONS
0
0

0




0



0
CELL 8
METER
READING
881(1)0
8J440
881. 1,0






881(1(0




TOTAL
GALLONS
0
__0


0







0


0
RE
Evaporation reported in Inches
                                                                                                                                                                  REMARKS
                                                                                                                                                                          PLATE  H-23T

-------
                                     SETTLEMENT DATA
CELL-
MONUMENT
A-l
A-2
A-3
A-4
A-5
B-l
B-2
B-3
B-4
B-5
C-l
C-2
C-3
C-4
C-5
D-l
D-2
D-3
D-4
D-5
E-l
E-2
E-3
i E"'1
E-5
DATE
1 1-16-71
280.89
280.34
280.36
280.76
280.59




















1 1-22-71
280.47
279.91
279.83
280.15
279.98




















11-23-71
280.57
280.09
279.98
280.30
280.20




















12-6-71
280.45
279.95
279.81
280.08
279.96
307.28
307.10
306.99
306.43
307.1 1















12-10-71




















281 .27
281.14
281.15
280.70
280.85
12-14-71










307.93
307.85
307.79
307.79
307.53










O
CO
                                                                             PLATE;
                                                                                                                                            SETTLEMENT DATA
CELL-
MONUMENT
A-l
A-2
A- 3
A-4
A-5
B-l
B-2
B-3
B-it
B-5
C-l
C-2
C-3
C-4
C-5
D-l
D-2
D-3
D-4
D-5
E-l
E-2
E-3
E-'t
E-5
DATE
12-21-71
280.52
279. 94
279.88
280.23
280.03
307. 15
306.92
306.69
306.20
306.87










280.90
280.73
280.72
280.35
280.60
12-28-71















306.97
307.21
306.82
305.91
306. 16





12-30-71
280.39
279.95
279.82
280.09
280. 1 1
306.95
306. 7*
306.148
305.94
306.61
307.47
307. 44
307.26
307.40
107. 13
306.55
306.77
306.27
305.55
305.59
280.70
280.57
280.47
280.20
280.34
1-7-72
280.52
280.03
279.92
280.23
260. 1 1
306.97
306.75
306. 52
306.03
306.67
307.44
307.38
307. 19
307-33
307.06
306.51
306.76
306.27
305.57
305.64
280.94
280.83
280.76
280.47
280.70
1-14-72
280.52
280.03
279.92
280. 23
2?G . 1 1
306.97
306.75
306.51
306.02
306.66
.307.42
307.36
307.18
307.31
307.04
306. <(9
306.74
306.24
305-55
305.61
280.93
280.74
280.75
280.47
280.68
1-24-72
280.51
280.02
279.91
280. 22
280. 10
306.96
306.73
306.49
306. 01
306.65
307.40
307.34
307. 15
307.29
307.02
306.45
306.71
306.20
305.51
305.58
280.91
280.72
280.73
280.45
280.67
                                                                                                                                                                                    PLATE  H-2!)B

-------
                                   SETTLEMENT QATA
CEU-
MONUHEKT
A- 1 -;
A-2
A-3
A-4
A-5
Z- 1 •' .}
; 6'2: ;
: B-3 ... 5
B-4 1
•j fc--S:'j
C-2 !
t-r
C-41 1
P5,f
; b-i |
0-2 ":
i0'3 i
D-4 '
• "'
E-l
"E-2" '
• ^'>£>-3 ' '
	 pi(,
/-I.S ;

1-31-72
280.51
280.00
279.91
280.22
280.10
306.95
306.72
306.50
306.01
306.65
307-40
307;. 34
307.14
307.28
307.01
306.45
306.70
306 . 1 9
305.55
305.56
280.91
280.71
280.73
280.45
280.67

2-14-72
280.50
280.01
279.91
280.22
280. 10
Wss;:
306.72:
:306.4g.
!306.00;
1306.64
!307.38i
J307.3ll
J307-12
i 307. 26:
S307.00J
i
1306.42
f 306. 68
^306.17
*305-48i
JSOS.S1!
280.90
280.70
280.72
-- 280.44
280.67
DAT
3-2-72
280.52
280.03
279.91
280.23
280. 10
306.35
306. .72
306 J-48
306.4)0
306.63-
307Jj37
307. |3f
307^:11-
307^25
306 ;%9
306 J4 1
306168-
306.16
305 ,48
305.;53
280.91
280 .-71
280,72
280.45
280.67
E
3*31-72
280.49
280.01
279.90
280.22
280.09
306.93
306.71
306.47
30 5 -.99
306.62
307.35
307.28
307.09
J07.22
306.96
306.39
366.66
306 . 1 3
305. 45
305.51
2*0 . 89
280.6?
280.70
280.43
'280.65

4-28-72
280.50
280.02
279.91
' 280.22
280. 10
306.93,
306.71
306 . 46:
305.98,
306.61
3 07.33 =
', 307.06
S 307.21
'. 306. g J.
306.37..
i 306.65
306.11
; 305.43
305.49
2«0.89
280.68
280.71
'' 280.44
280,65

6-1-72
280.50
280.02
279.89
280.21
280. 10
306,. 9 3
306!. 70
306!. 46
- 3B5.98
306.6!
307;. 32
-307.24
. 3P7.05
307:. 19
3*6.90
;• 306>36
306.64
306. 11
: J05.42
305.48
280.88
280.65
280.71
280.44^
280.64
ro
O
                                                                           PLATE H-24 C
                                                                                                                                        SETTLEMENT DATA
CELL-
MONUMENT
A-l
; A-2 ' '
A-3
A-4
A-5
G-l
E-2 .
6-3 ...
B-4
B-5 :
c-' ;
C-2 .
C-3
04 ;
; c-5
D-l
0-2
, D-3
0-4
0-5 :
E-)
E-2
JE-3
	 E-4
• :v. E-5 ; •

8-17-72
280.48
280.01
279.89
280.21
280.09
306.89
306.67
306.41
305.95
306.57
307.28
307. 19
3§6 ..98
307.14
.306.84
306.31 '
306.59
3Q6.03
305.36
305,39
280.86
280.61
280.67
280.42
2,80.61

JO- 13-72
280.48
279.99
279.88
280.20
280.08
306.88
306.66 i
306.40 :
305.94 '
306.56" <
307.25 .
307.15.
306.95 :
307. 11 '
306:80 ^
306^28 ;
306. 56 -
305-99
305.33
305.36
280.85
280.60
280.66
280.41- -
280,60
DAT
1 1-20-72
280.46
279.98
279-86
280. 18
280.06
'- 306.86
306.64
306.40
305.93
•306'. 55
307.23
307. 12
306.93
307.10
: 306.77
'"'306.26
306.54
305.97
305.31
305.33
280.83
280.58
280.65
- -280.39
28ff.58
E
1-3-73
280.46
279.97
279.86
280. 18
280.06
306.86
306.64
306.39
305.93
306.55
307.23
307.11
306.91
307.08
306.76
306.25
306.53
305.95
305-30
305.31
280.82
280.57 ;
280.64
280.39
280.58

4-4-73
280.45
279.97
279-86
280. 17
280.06
306.85
306.63
306. 38
305.92
306.54
307.22
307- 10
306.90
307-07
306.75
306.24
306.51
305-94
305.29
305.29
280.81
280.56
280.63
280.37
280.57

7-3-73
280.45
279.96
279.85
280. 17
280.06
306.84
306.63
306.37
305.92
306,53
307.21
307.09
306.89
307.07
306.74
306.24
306.50
305.92
305.28
305.24
280.80
280.54
280.62
280.37
280.56
                                                                                                                                                                                PLATE H-24 6

-------
                                                                       •r;:
                     FLUID ROUTING CELL  "C"
                                                                                                         FLUID ROUT IMG CELL "C"

Date
1971
12-30

12-31

1972


1-*

1-5

1-7

1-10

l-ll

1-12

1-13

1-1*

1-17

i-i a

1-19

1-20

1-21

1-2*

1-25

1-26

Leae
Start

5.8

6.5


7.8

7.9

7.9

8.5

8.6

a.a

8.8

9.0

9.0

9.*

9,5

9.6

10. 1

12.*

28.*

33.2

*0.3

hate Cc
End
(In)
s







































llectl
Total
(In)







































-
Leachate This .Sheet

Leachate Prior Sheet
Total Leachate
pn
Total
(Gal)
2000*







































2000

0
2000
Distribution
Start
(In)

68.1

73.5


73.5

73.5

73.3

73.2

73.5

68.0

73.5

73.5

T3.5

7*. 3

72.7

72.fr

73.2

83.5

73.8

72.3

73.3

End
(In)


I.P

1.0


1.0

1.0

1.0

1.0

1.0

1.0

1.0

1.0

1.0

1.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0
Total
(in)


67.1

72.5


72.5

78.5

72.3

72 . 2

72.5

67.0

72.5

72.5

72.5

73 . 3

72.7

72.6

73.2

83.5

73.8

72.3

73.3
?n!sr^eiion
Distribution
Prior Sheet
Total Distribution
Total
(Gal
1*933*

803.2

868.*


868.*

868.*

865.*

865.*

868.*

802.5

868.*

868.*

868.*

877.*

870.5

869.0

876.2

999.5

883.*

865.*

877.*
31*67

0
31*67
Fluid
Ret. In
Refuse
12933










































*8,000 gallons  applied  by  water  truck  during refuse placement.
 6,993 "gallons  applied  by  2.27"total  rainfall during refuse
 placement operation.
                                                       PLATE H-25A

Date

1972
1-27

1-28

'-31

2-1

2-2

2-3

2-*

2-7

2-8

2-9

2-10

2-11

2-12

2-13

2-1*

2-15

2-16

2-17

2-18

2-19

L»e
Start
(In)

*9.*

60.6

39.5

9.*

19.5

31.1

W-j-Z

3*. 8

11.0

22.8

3*.0

35.1

*5.6

.25. 'I

39.3

53.1

1*.*

3*. 3

58.3

32.*

hate Ce
End
(In)



1.0

1.0







-1 .*

2.0





2*.l

22.7

1.0





I.*





6.0



llectl
Total
(In)



59.6

38.5







*0.8

32.8





9-9

12.*

**.6





51.7





52.3



Leachate This Sheet
Leachate Prior Sheet
.Total Leachate
an
Total
(Gal)



713.*

*60.8







*88.*

392.6





118.5

271.7

533.9





618.8





626.0



*22*
2000
622*
Distribution
Start
Mn).

72.8

7*.J

72.5

73-0

71.5

00.0

00.0

71.*

72.2

72.*

72.5

72.9

1.0

1.0

72.5

72.*

72.2

72.5

72.5

72.4

En*
(»*J

'
o.a

o.a

6.7

0.0

o.o

0.0

0.0

o.a

1.0

1.5

1 .6

1.0

1.0

1.0-

I.*

1.2

i.a

1.07

I . *v

1.0
Total
(In)
*." "

72.8

7*. 3

65.8

73-0

71.5

00.0

00.0

71.*

71.2

70.9

70.9

71.9

00.0

60.0

71 •?

71.2

71.2

71.5

71.1

71.6
?n?srSn1e'eiX")
Distribution
Prior She.*£
Total Distribution
Total
(Gal


871.*

889.3

787.6

873.8

855.9

000.0

000.0

as*. 7

852.3

8*8.7

8*8.7

860.6

900.0

900.0

855.9

852.3

852.3

855. 9

851.1

857. 1
13668
31*67
*5135
Fluid
Ret. In
Refuse



29625

3005*







32082

31690





3*127

3*70*

35031





35268





. 37202





PLATE H-25

-------
FLUID ROUTING CELL  "C"

Date

1972
2-20

2-2!

2-22

2-23

2-24

2-25

2-26,

2-27

2-28

2-29

3-1

3-2

3-3

3-4

3-5

3-6

3-7

3-8

3-9

3-10

3-1 1
Leac
Start
(In)

60. 3

33.2

62.2

31.1

67.5

24.0

5*. 7

30.3

64.5

48.2

37.8

42.9

44. 1

45.5

40.7

42.3

45.0

44.3

47-9

46.8

49. 1
hate Collection
End
(In)

5.0



1 .0



1 .0



4.0



6.0

1 .6

5.0

6.0

6.0

5.0

5.0

5.0

5.0

6.0

5.0

5.0

5. 1
Total
(In)

55.3



61.2



66.5



50.7



58.5

47.2

32.8

36.9

38.1

40.5

35-7

37.3

40.0

38.3

42.9

41.8

44. 1
Leachate This Sheet

Leachate Prior Sheet
Total Leachate
Total
(Gal)

661 .9



732.6



796.0



606.9



700.2

564.9

392.6

441 .7

456. 1

484.8

427.3

446.5

478.8

458.5

513.5

500.3

527.9
9191

6224
15415
D i s t r i but i on
Start
(In)

72.8

72.5

73.2

72.8

72.3

72.9

72.3

72.5

72.3

74.5

72.5

72.5

72.7

72.7

72.7

72.9

72.6

72.8

72.9

72.9

72.8
End
(In)


1 .0

1 .0

4.3

13.3

28.2

1 .0

1 .0

3.0

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0

2.0

1 .0

1 .0

1 .0

1 .0

Total
(In)


71.8

71 .5

68.9

59.5

44. 1

71 .9

71 .3

69.5

71.3

73.5

71 .5

71 .5

71 .7

71 .7

71-7

70.9

71 .6

71.8

71.9

71.9

D i s t ribut i on
This SKeet
Distribution
Prior Sh«Pt
Total Distribution
Total
(Gal


859.4

855.9

824.7

712.2

527.9

860.6

853.5

831 .9

853.5

679.8

855-9

855.9

858.2

858.2

858.2

848.7

857. 1

359.4

860.6

860.6

16632

45135
61767
Fluid
Ret. In
Refuse

38249



39231



39972



40754



41739

42028

42515

42929

43329

43702

44133

44545

44915

45313

45659

46020

46352




                                   PLATE  H-25 C
                                                                                     FLUID ROUTING CELL  "C"
Date
1972
3-12
3- 13
3-14
3- 15
3-16
Leachate Collection
Start
(In)
46.6
45.3
49.6
51.4
61.7
End
(In)
5. 0
4.0
5 .0
5.0
6.4
Total
(In)
41.6
41.3
44. 6
46 . 4
55. 3
Leachate This Sheet
Leachate Prior Sheet
Total Leachate
Total
(Gal)
497.9
494. 4
533.9
555.4
661.9
2743
15415
18158
Distribution
Start
(In)
72.9
72.9
73.0
73.0
1 . 0
End
(In)
1 .0
1 .0
1 .0
' 0
Total
(In)
71.8
71.9
71.9
7? .0
72 . 0
Distribution
This Sheet
Distribution
Prior Sheet
Total Distribution
Total
(Gal]
859.4
860.6
860.6
861 . 8
861 . 8
4304
61767
66071
Fluid
Ret . 1 n
Refuse
46714
47080
47407 i
47714
479 1 3


                                                                                                                        PLATE H-25  D

-------
FLUID ROUTING  CELL "C"


Date

3-16-72

3-17-72

3-24-72

3-26-72

3-28-72

3-30-72

4-1-72

4-5-72

4-7-72

4-10-72

4-11-72

4-14-72

4-21-72

4-28-72

5-8-72

5-1 1-72

5-17-72

5-23-72

5-31-72

6-9-72
Leachate Collection

Meter
Read i ng
000

362

3822

51 18

6293

7350

8475

1 1193

12556

14592

15391

17734

22072

27102

33540

35191

39010

42251

46622

52567
Leachate This Sheet
Leachate Prior Sheet

Total Leachate
Total Gallons
Leachate
Generated

362

3460

1296

1175

1057

1125

2718

1363

2036

799

2343

4338

5030

6438

1651

3819

3241

4371

5945

52567
18158

70725
Distribution

Meter
Reading
000

1233

6771

8366

9881

1 1810

13412

16692

19264

21901

23438

26352

33368

40303

49330

51477

56302

60010

64931

71820
Distribution
This Sheet
Distribution
Prior Sheet
Total
Distribution
Total Gallons

Distributed

1233

5538

1595

1515

1929

1602

3280

2572

2637

1537

2914

7016

6935

9027

2147

4825

3708

4921

6889

71820
66071

137891
Fluid
Retained
in
Refuse

48784

50862

51161

51501

52373

52850

53412

54621

55222

55960

56531

59209

61 114

63703

64199

65205

65672

66222

67166





                               Plate  H-25 E
                                                                                           FLUID  ROUTING CELL "C"


Dale


6-16-72

6-23-72

6-29-72

7-3-72

7-10-72

7-18-72

7-25-72

8-1-72

8-9-72

8-14-72

8-22-72

8-30-72

9-5-72

9-18-72

9-27-72

10-3-72

10-10-72

10-19-72

1 1-7-72

1 1-16-72
Leachate Collection

Meter
Read i ng

56288

59299

60956

63070

66970

71700

76070

80164

84360

87394

92050

94164

94164

101230

106400

1 10395

1 14430

122560

135080

140590
Leachate This Sheet
Leachate Prior Sheet

Total Leachate
Total Gal Ions
Leachate
Generated
3721

301 1

1657

2114

3900

4730

4370

4094

4196

3034

4656

2114

(3300)*

7066

5170

3995

4035

8130

12520

5510

91323
70725

162048
D i str i but ion

Meter
Reading

75667

78685

80052

83760

89020

95270

100766

106140

1 1 1880

1 15860

12 1623

126490

130740

140100

146490

151020

155790

161580

173450

178370
Distribution
This Sheet
Distribution
Prior Sheet
Total
Distribution
Total Gallons

Distributed
3847

3018

1367

3708

5260

6250

5496

5374

5740

3980

5763

4867

4250

9360

6390

4530

4770

5790

1 1870

4920

106550
137891

244441
Fluid
.''etai'ned
in
Refuse
67292

67299

67009

67603

69963

71483

72609

73889

75433

76379

77486

80239

81 189

83483

84703

85238

85973

83633

82983

82393





                                                                     Collection  line broke and  leachate generation data  durina this
                                                                     period was  lost.   E.stimate  ^3?-0 gallons.

                                                                                                                          Plate  H-25  F

-------
                                  FLUID ROUTING CELL  "C"
                                                                                                                                       FLUID ROUTING  CELL  "C"
no-  -
_J . .-;

CO
;o.:

Date:


11-27-72

12-6-72

12-1 1-72

12-18-72

12-26-72

1-4-73.'

1-1U73;

1-18- 7$
;
l-2tr;73J
i ;
2-I--7J:

2 - 8>-7 3 >i
;.•
'2-V.5-.75li
: T
2-2,2-jjl
I;
3-1-7J1
|.
3-8,73;;
't
3-15-7?

3-22-7J
3-25-7:3
i
4-5-73
*,
4-12-73
... L«achate Collection

Meter
Reading

147780

: 153130

156050

157880

160990

166040

170620

175410

180095

183170

186460

189450

192160

193790

195650

200460

204130
207690

210990

215170
Leaehate This Sheet
Leachate Prior Sheet

Total Leachate
Total Gallons
Leachate
Generated
7190

5350

2920

1830

3110

', 5050
• -, -
"< 4580:

4790'

; 4685
f-
• 3075
• ) \ •-•-_•:
! 3290
i i
j 2990

| 2710
i i
j 1636
1
i 1860
i
1 4810

• 3670
1
; 3560
'
' 3300

: 4180

74580
162048

236628
Distribution

Meter
Reading

185920

; 191030

192770

192770

196410

202900

: 208500

f 212950

: 217930

220800
1 -' :.> ' .'
5 224740
* 4 "
i 22.792»
,J ' '-
i 22,9680

| 231390

I 234110
: '.. • •
I 240040

•• 245020
250740

255940

' 261150
Distribution
This Sheet
Distribution
Prior Sheet
Total
Distribution
Tota } . Ga 1 1 ons

Distributed
7550

5110 -

•• 1 740

0

3640
t
j 6490
j
! 5600
i '•'','..-
1 4450

4980

2870

3940

31.80

1 760
• • ' ••
i 1710
' v':
i 2720

5930
1 • ''
j 4980
i 5720
1 • "• .
; 5200
1 '
! 5210
! ' • .,
82780
244441

327221
Fluid
f-.etoincd
. *in
Refuse
82753

82513

•81333

79503

80033

8147J
<
' 82493

: 82253

82548

•: 82343

8299
-------
                       FLUID ROUTING CELL"D"

Date'

*
1971
12-30

12-31

^?^3

1-4

1-5

1-7

1-10

1-11

1-12

1-13

1-14

1-15

1-17

1-18

1-19

1-20

1-21

1-24

1-25

1-26
Leachate Collection
Start
(In)

70.0

5.6

27:5

27.6

27.9

28.5

28.8

30.0

31.8

40.0

48.8

58.8

26.2

34.4

49.7

73.4

23.4

69 .l 9

12.3

17,4
•End
(In)























1.3







1.0

1.0

I • 0

1.0

1.0
Total
(In)























56.5







72.4

22.4

68.9

11.3

16.4
Leachate This Sheet
Leachate Prior Sheet
Total Leachate
Total
(Gal)
1500*






















679.7







866.6

268.1

824.7

135.3

196.3
4471
0
4*71
Distribution
Start
(In)

56.6

70.6

73.8

73.3

72.2

73.3

72.5

72.0

72.0

72.0

71.0

56.*

71.5

71.1

71.2

71.2

76.2

69.4

62.3

70.9
?it.tri
End
(In)


0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

1.0

1.0

1.0

9.3

Total
(In)


56.6

70.6

73.8

73.3

72.2

73.3

72.5

72.0

72.0

72.0

71.0

56.4

71.5

71.1

71.2

70.7

75.2

68.4

53.0

lut ion
hee't
pi s t r J but ton
Prior 5nc0t
Total Distribution
Total
(Gal)
8063*

682.2

851.8

889.5

883.5

871.*

883.5

87*.*

868.4

868.4

868.4

856.3

675.9

867.2

857-3

858.7

852.6

906.9

824.9

639.2

239*8
0
23948
Fluid
Ret. In
Refuse
6563






















15281







17678

18262

1834*

1903*

19*77



*8,063 gallons of rain water added during refuse placement.
 1,500: gal Ions of teachate generated durlno refuse placement.
                                                        PLATE  H-26 A
                                                                                                            FLUID ROUTING CELL"D"
                                                                                                                                                r       r

0»t«

1972

1-27

1-28

l-3t

2-1

2-2

2-3

2-*

2-7

2-8

2-9

2-10

2-11

2-12

2-13

2-1*

2-15

2-16

2-17

2-18

2-19
Leachat* Collection
Start
(In)


27-3

33.*

81.5

16.5

22 . *

*2.8

*2.0

81.*

16.5

20.6

fcl.6

*7.6

*8.2

*7.5

31.8

*0.6

39.2

*2.6

*2.6

43.3
End
(In)


1-0

1.0

2-0

1.0

1.0

1.0

1.0

2.0

1.0

1.0

2.0

1.0

1.0

1.0

1.0

1.0

1.0

1-5

1.0

1-0
Total
(In)


26.3

32.*

79.5

15.5

21.*

*1.8

*I.O

79.*

15.5

19-6

39-6

*6.6

47.2

*6.5

30.8

39.6

38.2

*l.l

*1.6

*2,3
Leachate This Sheet
Leachate Prior Sheet
Total Leachate
Total
(Sal)


31*. 8

387.8

951.6

185.5

256.2

500.3

490,7

950 . *

185.5

23*. 6

.474.0

557.8

56*. 9

556.6

368.7

474.0

45713

492.0

497.9

506.3
1*07
4*71
13878
Distribution
Start
(In)


72.5

70.7

72.5

70.5

71.6

*5.l

*3. 1

72.3

71.*

72.9

72.8

70.2

65.3

62.*

73.0

73.1

72.1

71.1

71.2

72.6
?n?srs
End
(In)

0.0

10.9

0.0

0.0

0.0

0.0

0.0

0.0

12.3

2.0

II. 0

1*.8

15.3

13.5

22.0

19.3

23.3

19.7

21.1

19.0

Total
(In)

70.9

61.6

70.7

72.5

70.5

71.6

45.1

*3.l

60.0

69.*

61.9

58,0

5*. 9

51.8

*0.*

53.7

49.8

52.*

50.0

52.2

but Ion
leet
Prlor's-See?"
Total Distribution
Total
(Gal)

855.1

7*2.9

852.6

875.0

850.9

86*. 1

5**. 3

520.2

72*. 1

837.6

747.1

700.0

662.6

(25.2

487.6

648.1

601.0

632.*

603.5

630.0

1*00*
239*8
37952
Fluid
Ret. In
Refuse


20017

20372

20273

20963

21557

21921

21975

215*5

22083

22686

229S9L

23102

2JI99

23268

23387

23561

23705

238*5

23951

2*07*



                                                                                                                                              PLATE H-26

-------
FLUID ROUTING CELL"D"

Date

1972

2-20

2-21

2-22

2-23

2-2*

2-25

2-26

2-27

2-28

2-29

3-1

3-2

3-3

3-4

3-5

3-6

3-7

3-8

3-9

3-10

Leachate Collection
Start
(In)


41.3

37.5

33.7

37.8

52.1)

«. 7

58.9

50.9

55.3

62.3

60. 5

60.8

60.8

66.5

59.9

61,0

64.5

60.7

59.7

60.7

End
(In)


1 .0

1 .0

1 .0

2 .0

11.8

2.0

1 .0

1 .0

2.0

1 .0

2.0

2 .0

3.0

2.0

2.0

2 .0

1 .0

2.0

3.0

2 .0

Total
(In)


itO. 3

36.5

32.7

35.8

ItO. 6

44.7

57.9

49.9

53.3

61.3

58.5

58.8

57.8

64.5

57-9

59.0

63.5

58.7

56.7

58.7

Leachate This Sheet
Leachate Prior Sheet
Total Leachate
Total
(Gal)


482.4

436.9

331 .4

428.5

485.9

535. 1

693.1

597.3

638.0

733.8

700.2

703.8

691 .9

772.1

690.7

706.2

760. 1

702.6

678.7

702.6

12531
13878
26409
D i s t ri but i on
Start
(In)


72.5

72.9

72.3

81.0

72.7

72.3

72.3

72.5

72.3

72. 1

72.8

72.6

72.8

72.9

72.9

72.9

73.0

72.9

72.8

73.0

Dl s tri
This S
End
(In)

21.4

23.1)

28.2

31.6

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0

1.0

0.0

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0

1 .0
Tota!
(In)

51.2

49. 1

1)4.7

40. 7

80.0

71.7

71.3

71.3

71.5

71.3

71.1

71 .8

71.6

72.8

71.9

71 .9

71.9

72.0

71 .9

71.8

72.0
ju t i on
heet
Dlstr i but Ion
Prior Sheet
Total D i s t r i but i on
Total
(Gal)

617.9

592.6

539.5

49 i .2

965.5

865.3

860.5

860.5

862.9

860. 5

858. 1

866.5

864. 1

878.6

867.8

867.8

867.8

868.9

867.8

866.5'

868.9
17059
37952
5501 1
Fluid
Ret . In
Refuse


242 10

24365

24514

24576

25056

25386

25553

25817

26042

26168

26326

26489

26661

26768

26945

27106

27214

27380

27569

27733




                                  PLATE H-26
                                                                                     FLUID ROUTING CELL"D'

Date

1972
3-1 1

3-12

3-13

3- H

3-15



Leachate Collection
Start
(In)

58.lt

55.0

54.8

61.1

59.6

Leach
p ump i
End
(In)

1 .0

i .0

1 .0

1 . 0

1 . 0

ite ad
i g ope i
Total
(In)

57.1*

514.0

53.8

60.1

58.6

us t me n
a t i on
Leachate This Sheet
Leachate Prior Sheet
Total Leachate
Total
(Gal)

687. 1

61)6.')

643.9

715. M

70 1 . 1)

t for
1506.5
"i905
26409
3131"!
Distribution
Start
(In)

73.0

72.9

73 .0

72 .9

73. 0



End
(In)


1 0

1 . 0

1 . 1

i . 0

i . 0


Total
(In)


72 . 0

71.9

72 .0

71.9

72 . 0


?i s t r i but i on
his Sheet
0 1 s t r i but i on
Prior Sheet
Tota 1 Distribution
Total
(Gal)


868.9

867. 8

868 . Q

867.8

868.9


Ii3li3
5501 1
5935
-------
FLUID ROUTING CELL "D"

Date


3-15-72

3-16-72

3-17-72

•3-24-72

3-26-72

3-28-72

3-30-72

4-1-72

4-5-72

4-7-72

4-10-72

4-11-72

4-14-72

4-21-72

4-28-72

5-8-72

5-11-72

5-17-72

5-23-72
Leachate Collection
Meter
Read 1 ng

1
000

889

1673

6917

8390

9921

1 1643

13352

17395

19574

22051

23133

26420

33072

42378

52260

5*547

59062

63282
Leachate
This Sheet
Leachate
Prior Sheet
Total Leachate
Total Gal.
Leachate
Generated
(1-3)
2

889

673

5117

1290

1301

1403

1392

3765

1774

2264

833

3120

6652

8928

9882

2287

4302

3882

59754

31314
91068
Distribution (Leachate & Fresh Water)
Fresh Water Added
Meter
Reading

3
000

1000

1800

7100

8620

10240

11960

13630

17800

19787

22300

23300

26420

33450

42378

52260

54760

59400

63800
Gallons
Added
(3-D
4

1 1 1

127

183

230

319

317

278

405

213

249

167

0

378

0

0

213

338

518

Distribution
This Sheet
Distribution
Prior Sheet
Total Distribution
Total
Distribution
(4+2)
5

1000

800

5300

1520

1620

1720

1670

4170

1987

2513

1000

3120

7030

8928

9882

2500

4640

4400

63800

59354
123154
Fluid
P.eta i ned
in
Refuse
(4+6)
6

28151

28278

28461

28691

29010

29327

29605

30010

30223

30472

30639

30639

31017

31017

31017

31230

31568

32086




                                        PLATE  H-26  E
                                                                                                      FLUID ROUTING  CELL "D"

Date



5-31-72

6-9-72

6-16-72

6-23-72

6-29-72

7-3-72

7-10-72

7-18-72

7-25-72

8-1-72

8-9-72

8-14-72

8-22-72

8-30-72

9-5-72

9-18-72

9-27-72

10-3-72

Leachate Collection
Meter
Read i ng

1

69953

78027

83347

89513

95122

99470

10
6
32583

32956

33526

34081

34589

34739

34919

35422

35622

35892

36039

36371

36527

37058

37353

38593

39283

40344

42383



                                                                                                                                              PLATE H-26 F

-------
                        FLUID ROUTING CELL "0"

Date


10-10-72

10-19-72

11-7-72

1 1-16-72

11-27-72

12-6-72

12-1 1-72

12-18-72

12-26-72

1-4-7}

1-11-73

1-18-73

1-26-73

2-1-73

2-8-73

2-15-73

2-22-73

3-1-73

3-8-73
Leachate Collection
Meter
Reading

1
181961

193070

209710

227890

249750

262910

268450

27*020

293550

314290

329580

357350

392160

418640

450770

484430

518560

551560

584850
Leachate
This Sheet
Leachate
Prior Sheet
Total Leachate
Total Gal.
Leachate
Generated
(1-3)
2

9070

16640

15340

21860

13160

7940*

5570

19530

20740

15290

27770

34810

26480

32130

33660

34130

33000

33290

400410

200971
601381
Distribution (Leachate i Fresh Water)
Fresh Water Added
Meter
Read i ng

3
184000

193070

212550

227890

249750

262910

268450

274020

293550

314290

329580

357350

392160

418640

450770

484430

518560

551560

584850
Gallons
Added
(3-D
J»

0

2840

0

0

0

-2400*

0

0

0

0

0

0

0

0

0

0

0

0

Distribution
This Sheet
Distribution
Prior Sheet
Total Distribution
Total
Distribution
(4+2)
5

9070

19480

15340

21860

13160

5540

5570

19530

20740

15290 .

27770

34810

26480

32130

33660

34130

33000

33290

400850

243354
644204
Fluid
Retained
in
Refuse
(4+6)
6

42383

45223

45223

45223

45223

42823

42823

42823

42823

42823

42823

42823

42823

42823

42823

42823

42823

42823




* 2,400 gallons  leachate  lost  on Dec.  9, 1972, due  to  frozen
  leachate return  line.
                                                           PLATE H-26G
                                                                                                                 FLUID ROUTING CELL "D"


Date


3-15-73

3-22-73

3-29-73

4-5-73

4-12-73

"1-19-73

4-26-73

5-3-73

5-10-73

5-17-73

5-24-73

5-31-73

6-7-73

6-14-73

6-21-73

6-28-73

7-5-73

7-12-73

Leachate Collection
HP ter
Read i ng
1

6 15420

61(1600

664900

684020

697580

706120

712727

718603

724792

729941

734398

740773

747340

755397

762J86

768552 .

774599

781260

Leachate
This Sheet
Leachate
Prior Sheet
Total Leachate
Total Gal.
Leachate
Generated
(1-3)
2
30570

26)80

23300.

19120

13560

8540

6607

5643

5882

4991

4028

6193

6000

7257

6571

5402

5949

5300

3890
19493

601381
796364
Distribution (Leachate 5 Fresh Water)
Fresh Wate' Added
Meter
Read i ng
3

615420

641600

664900

684020

697580

706120

712960

718910

724950-

730370

734580-

741340

748140

755815

763150

768650

775960

781890

Gal Ions
Added
(3-D
it
0

0

0

0

0

-400 *

233

307

158

429

182

567

800

418

764

98

1361

630

490
Distribution
This Sheet
Distribution
Prior Sheet
Total Distribution

Total
Distribution
(4*2)
5
30570

26180

26180

19120

13560

8540

6840

5950

6040

5420

4210

6760

6800

7675

7335

5500

7310

5930

4380
201420

644204
845624
Fluid
Reta 1 ned
i n
Refuse
(4+6)
6
42823

42823

42823

42823

42823

42423

42656

42963

43121

43550

43732

44299

45099

45517

46281

46379

47740

48370

48860




*  400 gallons  leachate lost" due  to equipment failure.
                                                           PLATE H-26 H

-------
           APPENDIX  I
Test Cell Rffuse Plactment History
                    218

-------
                     TEST CELL REFUSE PLACEMENT HISTORY
                                   CELL A
  DATE
                       EVENT
ADDED LIQUII  RAINFALL
ll/ 5/71
11/12/71
11/13/71
11/15/71
11/15/71
11/16/71
11/17/71
11/22/71
Started Placing Refuse
Rain
Rain
Finished Placing Refuse (530.35 Tons)
Started Placing Cell Cover
Rain
Cell Cover in Place
Shot Initial  Settlement Elevation
             0.29"
             0.25"
             0.02"
          Compacted Refuse  ,
          Density 1064  #/ydJ
                                    219

-------
                     TEST CELL REFUSE  PLACEMENT HISTORY
                                   CELL B
  DATE
                           EVENT
ADDED LIQUID
                                                                 RAINFALL
11/16/71
11/19/71
11/24/71
11/29/71
12/ 1/71
12/ 2/71
12/ 3/71
12/ 6/71
12/ 6/71
12/ 7/71

12/ 8/71
12/ 9/71
12/10/71
12/10/71
Started Placing Refuse
Switched Refuse Placement to Cell E
Resumed Refuse Placement
Rain
Finished Placing Refuse (524.23 Tons)
Rain
Rain
Rain
Add Water from Water Truck
Add Water from Water Truck (69.25" in tank D as run
                            off from Cell B.
                            69.25" = 829 gallons)
Started Placing Cell Cover
Rain
Rain
Cell Cover in Place
          Compacted Refuse  ~
          Density  1052 #/ydJ
               0.96"

               0.50"
               0.32"
               0.24"
 20,000  gal.
 14,000  gal*
               0.27"
               0.09"
          *14,000 gallons should be reduced by 829 gallons to
           determine total  moisture added to cell
                                        220

-------
TEST CELL REFUSE PLACEMENT HISTORY




              CELL C
*

4







i •







-


DATE
Wi/fi
12/( 2^1
12/ 3/71
12/3/71
12/j 6/21 (
1. ••'"-""
124 6^1.
12/ 7/71
12/ 9/71
12/10/71
12/11/71
12/13/71
12/13/71
12/13/71
12/13/71
12/15/71
121/17/71
12/21/71
1^/21/71
12/21/71
i

EVENT
Started Placing Refuse
Rain
Rain
Switched Refuse Placement to Cell E
Rain
Resumed Placing Refuse
; *V. . L ' ' •• ; •:-.- '•' ' ., • : • „. '
Add Water from Water Truck (2,000 gal ran through
the cell and out the
tank)
Rain
Rain
Rain
Rain
Add Water from Water Truck
Finished Placing Refuse (521.72 tons)
Began Placing Muck Sand
Rain
Started Placing Distribution System
Started Placing Cell Cover
Cell Cover 1n Place
405 gal. Leachate pumped from bottom tank and
discarded
Compacted Refuse •>
Density 1064 #/ydJ
*4,000 gallons should be reduced by 2,000 gallons
to determine total, moisture added to cell.
\DDED LIQUID






4,000*




4,000 gal.






- 405 gal.


RAINFALL

0.50"
0.32"

0.24"


0.27"
0.09"
0,03"
,0.77":



0.05"






                 221

-------
                     TEST CELL REFUSE PLACEMENT HISTORY
                                   CELLO
  DATE
                      EVENT
ADDEDLIQUIE
RAINFALL
12/13/71
12/15/71
12/22/71
12/23/71
12/23/71
12/24/71
12/27/71

12/28/71
12/29/71
12/29/71
12/29/71
12/30/71
Started Placing Refuse
Rain
Rain
Rain
Finished Placing Refuse (530.97 Tons)
Rain
Rain - Leachate Collection Tank at bottom of Cell D
       was full and overflowing.  Leachate held for
       recycl1 ng.   Estimated vol uae, 1,500 gal.
Pea Gravel Placed for Distribution System
Rain
Distribution System Installed
Started Placing Cell Cover
Cell Cover In Place
          Compacted Refuse  -
          Density  1065 I/yd3
 - 1,500
  0.05"
  0.51"
  0.22"

  0,06"
  1.77"
              0.03"
                                          222

-------
TEST CELL REFUSE PLACEMENT HISTORY
              CELL E
DATE
1 1/15/71
11/16/71
1 1/16/71
1 1/16/71
1 1/17/71
1 1/S8/71
1 1/19/71
1 1/22/71
1 1/22/71
11/23/71
1 1/24/71
1 1/29/71
11/30/71
12/1/71
12/2/71
12/2/71
12/3/71
12/3/71
12/3/71
12/6/71
12/6/71
12/6/71
12/7/71
12/8/71
12/9/71
12/10/71
12/10/71
12/10/71
12/1 1/71
12/1 1/71
12/12/71

EVENT
Started Placing Refuse
Ra! n
Septic Pump i ngs
Switched Refuse Placement to Cell B (@Ton
180,2
Septic Pump ings
Septic Pump ings
Septic Pump ings
Resumed Refuse Placement
Septic Pump ings
Septic Pump ings
Switched Refuse Placement to Cell B(@ Ton
Ra in
Septic Pump ings
Septic Pump ings
Septic Pump ings
Ra i n
Rai n
Resumed Refuse Placement
Septic Pump ings
Ra i n
Septic Pump ings
Finished Placing Refuse (521.93 Tons)
Septic Pump ings
Septic P ump ings
Rain
Ra i n
Sept ic Pump ings
Started Placing Cell Cover
Ra i n
Septic Pump ings
Ce 1 1 Cover in Pi ace
Refuse Density 1047 #/yd^
<\DDED LIQUID


1 ,000 gal
)
1 ,000 Gal
800 Gal
2,200 Gal

2,200 Gal
1 ,000 Gal


2,200 Gal
2,600 gal
1 ,000 gal



1 ,000 gal

2,000 gal

3,800 gal
2, 100 gal


3,300 gal


1 ,000 gal


RAINFALL

0.02"









0.96"



0.50"
0.32"


0.24"




0.27"
0.09"


0.03"



                  223

-------
                                 BIBLIOGRAPHY
 1.   Standard methods for the examination of water and wastewater.   13th ed.
       New York, American Public Health Association,  1971.   874  p.

 2.   U.S.  Environmental Protection Agency.   Methods for chemical analysis
       of  water and wastes.   Water Pollution Control  Research  Series.   Washington,
       U.S. Government Printing Office, 1971.  312 p.

 3.   Steiner, R. L., and A.  A.  Fungaroli, eds.   Analytical  procedures  for
       chemical pollutants.   2d ed.   Publication SWUE-12.   Philadelphia,
       Drexel University, 1970.   27 p.

 4.   Wyckoff, B. M.  Rapid solids determination using glass fiber filters.
       Water & Sewage Works, 111(6) -.277-280, June 1964.

*5.   Mancy, K. H.,  and T. Jaffe.  Analysis of dissolved oxygen in natural and
       wastewaters.  Public Health Service Publication 999-WP-37.  1966.

 6.   Hatch, W. R.,  and W. L. Ott.  Determination of sub-microgram quantities
       of  mercury by atomic absorption  spectrophotometry.   Analytical  Chemistry,
       40(14):2,085-2,087, Dec.  1968.

*7.   Brandenberger, H., and H.  Bader.  The determination of nanogram levels of
       mercury in solution by a flameless atomic absorption technique.   Atomic
       Absorption Newsletter, 6:101, 1967.

*8.   Menzel, D. W., and N. Corwin.  The measurement of total phosphorus in
       seawater based on the liberation of organically bound fractions by
       persulfate oxidation.  Limnology and Oceanography,  10:28, 1965.

 9.   Sawyer, C. N., and P. L. McCarty.   Chemistry for sanitary engineers.
       2d ed.  New York, McGraww-Hill,  1967.  518 p.

10.   Fishman, M. J., and S. C.  Downs.  Methods for analysis of selected metals
       in water by atomic absorption.  U.S. Geological Survey, Water Supply
       Paper 1540-C.  Washington, U.S.  Government Printing  Office, 1966.  45  p.

11.   Mancy, K. H.  Instrumental analysis for water pollution control.   Ann
       Arbor, Mich., Ann Arbor Science Publications,  1971.   343  p.

12.   Skoog, D. A., and D. M. West.  Fundamentals of analytic chemistry.  2d ed.
       New York, Holt, Rinehart, and Winston, 1969.

13.   Lingane, J. J.  Electroanalytical chemistry.  2d ed.   New York, Interscience
       Publishers, Inc., 1958.   669 p.
     *A11 references except those marked with an asterisk have been verified
by the Office of Solid Waste Management Programs.

                                                                        Va959
                                   224

-------