5So
:. _ - '; /FINAL . / -; .- ; "_ , ...
AMENDMENTS TO THE
FINAL BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BDAT)
' BACKGROUND DOCUMENTS
FOR
WASTES FOR WHICH WASTEWATER TREATMENT
STANDARDS WERE DETERMINED BASED ON CbNCENTRAHONS
IN INONERATOR SCRUBBER WATER:
K015, K016, K018, K019, K020, K023,
K024, K028, K030, K048i K049, K050,
K051, K052, K087, K093, K094, U028,
U069, U088, U102, U107, AND U190
Richard Kinch '
Chief, Waste Treatment Branch
Anita Cununings
Project Manager
U.S. Environmental Protection Agency
Office of Solid Waste
2800 Crystal Drive
Arlington, Virginia 22202
June 1992
05
CM
NW/NW-054
0603-Ol.mj
US EPA Headquarters Library1
Room'2904, Maiicqde 3404 .
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TABLE OF CONTENTS
1.0 INTRODUCTION ..... . ..... . .................... ______ 1-1
2,0 AMENDMENT TO THE "APPLICABLE AND DEMONSTRATED
TREATMENT TECHNOLOGIES" SECTION OF THE FINAL BDAT
BACKGROUND DOCUMENTS FOR K015, K016, K018, K019, K020,
K023, K024, K028, K030', K048, K049, K050, K051, K052, K087, K093,
K094, U028, U069, U088, U102, U107, and U190: WASTEWATER
ORGANICS .... .......... . ...... .....; ...... . ....... ... 2-1
2.1 Applicable Treatment Technologies ....... ..... ....... ... 2-1
2.2 Demonstrated Treatment Technologies ____ . . . ---- ........ 2-7
3.0 AMENDMENT TO THE TREATMENT PERFORMANCE
DATABASE" SECTION OF THE FINAL BDAT BACKGROUND
DOCUMENTS FOR K015, K016, K018, K019, K020, K023, K024, K028,
K030, K048, K049, K050, K051, K052, K087, K093, K094, U028, U069,
U088, U102, U107, and U190: WASTEWATER ORGANICS ...... 3-1
.. . . 3.1 Sources, of Treatment Performance Data ..... ... ......... . . 3-2
3.1.1 BDAT Database ____ ...... ..... . . ..... . ....... 3-3
3.1.2 WAO/PACT Data . . . .......... . ...: ........ ..3-4
3.1.3 BAD Database-Promulgated Limits ..;..,......... 3-4
3.1.4 NPDES Database ............... . ...... . . '. . . . . . 3-5
3.1.5 WERL Database . ---- ....... . . . ........ ...... 3-5
3.1.6 Leachate treatment Performance Data . . ...... ...... 3-6
3.1.7 Other Sources . . ........ , ..... ................ 3-6
3.2 Treatment Performance Database ..;... ....... . ---- ..... 3T6
4.0 AMENDMENT TO THE "roENTIFICATION OF BEST
DEMONSTRATED AVAILABLE TECHNOLOGY (BDAT)" SECTION
OF THE FINAL BDAT BACKGROUND DOCUMENTS FOR K015,
K016, K018, K019, K020, K023, K024, K028, K030, K048, K049, K050, )
K051, K052, K087, K093, K094, U028, U069, U088, U102, U107, AND
U190: WASTEWATER ORGANICS ....... . ____ . ........... 4-1
. . - - ~ i ' '-''.
5.0 AMENDMENT TO THE "SELECTION OF REGULATED
CONSTITUENTS" SECTION OF THE FINAL BDAT BACKGROUND
DOCUMENTS FOR K018, K028, AND K030: WASTEWATER
ORGANICS .......... ....... . ...... ... . . . . . . ... ..... . . 5-1
5.1 BDAT List Constituent Deleted from Further \
Consideration for Regulation (Pentachloroethane) ......... . 5-2
5.2 BDAT List Constituents Selected for Regulation ---- . ...... 5-2
NW/NW-054 ' .
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TABLE OF CONTENTS (Continued)
Page
6.0 AMENDMENT TO THE."CALCU1ATION OF BDAT TREATMENT
STANDARDS" SECTION OF THE FINAL BDAT BACKGROUND
DOCUMENTS FOR K015, K016, K018, K019, K020, K023, K024, K028,
K030, K048, K049, K050, K051, K052, K087, K093, K094, U028, U069,
U088, U102, U107, AND U190: WASTEWATER ORGAN1CS .... 6-1
6.1 Accuracy Correction Factors ... 6-2
6.2 Variability Factors 6-3
63 Calculation of Revised BDAT Treatment Standards 6-4
7.0 ACKNOWLEDGEMENTS 7-1
8.0 , REFERENCES 8-1
Appendix A TREATMENT PERFORMANCE,DATA FOR
CONSTITUENTS REGULATED IN K015, K016, K018,
K019, K020, K023, K024, K028, K030, K048, K049, K050,
, K051, K052, K087, K093, K094, U028, U069, U088, U102,
U107, AND U190 , A-l
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LIST OF TABLES
List of Abbreviations and Acronyms ............. ....... ...... viii
1-1 Waste Code Definitions .... ............. ...... . .. ____ ....... 1-5
1-2 Revised BDAT Treatment Standards for Organic
Constituents in Wastewater Forms of: K015, K016, K018,
K019, KQ20, K023, K024, K028, K030, K048, K049, K050,
K051, K052, K087, K093, K094, U028, U069, U088, U102,
U107, and U190 ........ , . : ........... .... ... .......:, . 1-7
Ir3 ' ' Background Documents Which are Being Amended . ........... 1-19
* " " ~ *
5-1 Regulated Constituents for K015, K016, KQ18, K019, K020,
K023, K024, K028, K030, K048, K049, K050, K051, K052,
K087, K093, K094, U028, U069, U088, U102, U107, and
U190: Wastewater Organics ----- . . . ---- . ......... ......... 5-4
6-1 BDAT Treatment Standards for Organic Constituents
Regulated in K015, K016, K018, K019, K020, K023, K024,
K028, K030, K048, K049, K050, K051, K052, K087, K093, ,
K094, U028, U069, U088, U102, U107, and U190 ...:..,,.. ____ 6-5
6-2 VariabiHty Factors for Volatile Organics . ...... ........ . ..... 6-7
6-3 > Variability Factors for Semivolatile Organics ............... . . v 6-8
6-4 Determination of Accuracy Correction Factors for Volatile ,
Organics - EPA Data ... ............. . . . . . ......... ...... 6-9
6-5 Determination of Accuracy Correction Factors for . . ^
Semivolatile Organics - EPA Data . . ........ ........ ---- ... 6-10
6-6 c Determination of Accuracy Correction Factors for Volatile - '
Organics - Industry-Submitted (Dow) Leachate Data ----- . . ..... . 6-11
1 ' " -.''
6-7 Determination of Accuracy Correction Factors for Volatile
. Organics'- Industry-Submitted (CWM) Leachate Data .......... 6-12
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LIST OF TABLES (Continued)
Page
6-8 Determination of Accuracy Correction Factors for
Semivolatile Organics - Industry-Submitted (Dow) Leachate
Data 6-13
A-l Index for Appendix A . '.. .' A-2
A-2 Database Key ....:.. .........;... A-4
A-3 Key To Treatment Technologies A-5
A-4 Wastewater Treatment Performance Data for
Acenaphthalene ..; A-8
A-5 Wastewater Treatment Performance Data for Acenaphthene ...... A-10
A-6 Wastewater Treatment Performance Data for Anthracene . A-12
A-7 . Wastewater Treatment Performance Data for
- Benz(a)anthracene -. A-14
A-8 Wastewater Treatment Performance Data for Benzene ..:....... A-16
A-9 Wastewater Treatment Performance Data for
Benzo(a)pyrene '. A-19
A-10 Wastewater Treatment Performance Data for
Benzo(b)fluoranthene >. '-" A-21
A-ll Wastewater Treatment Performance Data for
Benzo(k)fluoranthene '. A-23
A-12 Wastewater Treatment Performance Data for bis(2- .
, Chloroethyl)ether ; A-25
A-13 ~ Wastewater Treatment Performance Data for bis(2-
Ethylhexyl)phthalate ......... A-27
A-14A Wastewater Treatment Performance Data for Carbon
Bisulfide .' '., A-29
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LIST OF TABLES (Continued)
A-14B , Industry-Submitted Leachate Treatment Performance Data '.
for Carbon Disulfide ............. ..... ...... ............ A-29
A-15 . Wastewater Treatment Performance Data for Chlorobenzene ...... A-31
A-16 , Wastewater Treatment Performance Data for Chloroethane ....... A-33
* i ' *
A- 17 Wastewater Treatment Performance Data for Chloroform ........ . A-35
' - _
A-18 . Wastewater Treatment Performance Data for Chloromethane ....... A-38
A-19 Wastewater Treatment Performance Data for Chrysene .......... A-40
i . '
A-20 , Wastewater Treatment Performance Data for ortho-Cresol ---- , . . A-42
A-21 Wastewater, Treatment Performance Data for meta/para-
Cresol . . ..... . . ---- . ...... ---- ---- . . . ---- ....... ------ . A-44
A-22 Wastewater Treatment Performance Data f or o-
Dichlorobenzene ..'...-. ........... ..'......... ......... . . A-46
A-23 Wastewater Treatment Performance Data for p-
Dichlorobenzene ........ ^ ....' ..... .............'.. ...... A-48
' - -,' x ' ' ,
A-24 Wastewater Treatment Performance Data for 1,1-
Dichloroethane . . ---- . . . . ........... ;....' ....... ....... A-50
; , - , ' . <:
A-25 Wastewater Treatment Performance Data for 1,2-
Dichloroethane ....... '. ..... ....... * ....... . . . ...... . ...... A-52
t
A-26 Wastewater Treatment Performance Data for 1,2-
Dichloroethene . ..... ."'. . ....... .... ........ ............. A-54
A-27 Wastewater Treatment Performance Data for Diethyl ซ
' , Phthalate . . ...... ........ . ..... :...... . . . .;. ......... . . A-56
A-28 .. Wastewater Treatment Performance Data for 2,4-
Dimethylphenol ......... 1 . ...... . . . ..... ;...... ..... ... A-58
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LIST OF TABLES (Continued)
\
Page
A-29 Wastewater Treatment Performance Data for Dimethyl
Phthalate ........ A-60
A-30 - Wastewater Treatment Performance Data for Di-n-butyl
Phthalate :.........;.. A-62
A-31 Wastewater Treatment Performance Data for Di-n-octyl
Phthalate . A-64
A-32 Wastewater Treatment Performance Data for Ethyl Benzene A-66
A-33 Wastewater Treatment Performance Data for Fhioranthene ... A-69
A-34 Wastewater Treatment Performance Data for Fluorene .......... A-71
A-35 Wastewater Treatment Performance Data for
Hexachlorobenzene A-73
A-36 .Wastewater Treatment Performance Data for
Hexachlorobutadiene ....:.. A-75
A-37 Wastewater Treatment Performance Data for
Hexachlorocyclopentadiene A-77
. A-38 . Wastewater Treatment Performance Data for
Hexachloroethane A-79
A-39 Wastewater Treatment Performance Data for Indeno(l,2,3-
cd)pyrene ..'. '..-...' A-81
A-40 Wastewater Treatment Performance Data for Naphthalene A-83
A-41 Wastewater Treatment Performance Data for Phenanthrene A-85
A-42A . Wastewater Treatment Performance Data for Phenol ... A-87
A-42B Industry-Submitted Leaichate Treatment Performance Data
for Phenol A-89
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LIST OF TABLES (Continued)
' . '' . , ' . ' . Page
A-43 Industry-Submitted Leachate Treatment Performance Data
for Phthalic Anhydride ......... .... ........... ..... ...... A-91
A-44 Wastewater Treatment Performance Data for Pyrene ............ A-93
i
A-45 Wastewater Treatment Performance Data for 1,2,4,5- . :
Tetrachlorobenzene ............ '. . . . ; ...... ....... ....... A-95
A-46 Wastewater Treatment Performance Data for 1,1,1,2- .
Tetrachloroethane ....... . ---- ---- . ---- .'...' ..... ......... A-97
A-47 Wastewater Treatment Performance Data for
Tetrachloroethane ...... ....... ---- .... ---- ..... ..... ; . . A-99
A-48 Wastewater Treatment Performance Data for '
Tetrachloroethylene . . '. . ........ _____ ..... ---- . ........ . . A-101
A-49 Wastewater Treatment Performance Data for Toluene .......... . A-104
A-50 Wastewater Treatment Performance Data for 1,2,4- ^ .
Trichlorobenzene ....". ....... . ....... ....... ..... ...... A-108
1 " .
A-51 Wastewater Treatment Performance Data for 1,1,1-
Trichloroethane ---- ......... ---- . . ..... ....... * ...... . A-110
A-52 . Wastewater Treatment Performance Data for 1,1,2-
Trichloroethane ... ............ ;..... ....... .' . . ......... . A-113
A-53 Wastewater Treatment Performance Data for 1,2-Xylene ........ A-115
A-54 Wastewater Treatment Performance Data for 13-Xylene . ....... A-116
A-SS Wastewater Treatment Performance Data for 1,4-Xylene . . ...... A-117
A-56 Wastewater Treatment Performance Data for Xylene . ........ . . A-118
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0603-Oljuj
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LIST OF ABBREVIATIONS AND ACRONYMS
Abbreviation/Acronym
AC
ACF
AFF
AirS
AL
AnFF
APCD
API
ART
AS
BOAT
BGAC
BT
CAC
CFR
ChOx
Chred
CWA
DAF
DNT
HAD
EPA
FIL
FR
FWPCA
Definition
Activated Carbon
Accuracy Correction Factor
Aerobic Fixed Film-
Air Stripping
Aerobic Lagoons
Anaerobic Fixed Film
Air Pollution Control Devices
American Petroleum Institute
Articles not part of WERL database
Activated Sludge Biological Treatment
Best Demonstrated Available Technology
Biological Granular Activated Carbon
Biological Treatment
Chemically Assisted Clarification
Code of Federal Regulations
\
Chemical Oxidation
Chemical Reduction
Clean Water Act
Dissolved Air Flotation
Dinitrotoluene
Engineering and Analysis Division __
Environmental Protection Agency
Filtration '
Federal Register - .
Federal Water Pollution Control Act
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VUl
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LIST OF ABBREVIATIONS AND ACRONYMS (Continued)
'^?ปs^
'}.'^-^f;-^'^^!if^^!^^^^/<^^fy^^^^:^^
GAC
HSWA
rro
LDR
Leachate
LL
NPDES
OCPSF
OER
OSW
PACTฎ
f- ป
RBC
RCRA
RO
SCOx \ ,
SExt
SS .- -. '-.>.
TCLP
.TF: ' ' ." . ';' , - -
Toe ;
TSS
UF
UV
;MiiiiP:;sii!ซ^^
Granular Activated Carbon
Hazardous and Solid Waste Amendments
Industrial Technology Division
Land Disposal Restrictions
Industry Submitted Leachate Data
Liquid-Liquid Extraction
National Pollutant Discharge Elimination
System .
Organic Chemicals, Plastics, and
Synthetic Fibers
Onsite Engineering Report
Office of Solid Waste .
Powdered Activated Carbon Addition to
Activated Sludge
Rotating Biological Contactor
Resource Conservation and Recovery Act
Reverse Osmosis
Super Critical Oxidation
Solvent Extraction
Steam Stripping
Toxicity Characteristic Leaching
Procedure
Trickling Filter
Total Organic Carbon
Total Suspended Solids
Ultrafiltration
*
'Ultraviolet Radiation -
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LIST OF ABBREVIATIONS AND ACRONYMS (Continued)
Abbreviation/Acronym
VF . . . . ' -
WAO
WERL
WOx
Definition ,
Variability Factor
Wet Air Oxidation
Water Engineering Research
Laboratory
Wet Air Oxidation
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1.0 INTRODUCTION.
The U.S. Environmental Protection Agency (EPA or Agency) is today
revising the best demonstrated available technology (BOAT) treatment standards for
organic constituents regulated in wastewater1 forms of the hazardous wastes listed as
K015, K016, K018, K019, K020, K023, K024, K028, K030, K048, K049, KOSO, K051,
K052, K087, K093, K094, U028, U069, U088, U102, U107, and U190. These hazardous
wastes, defined in Title 40, Code of Federal Regulations (40 CFR), Sections 26131,
26132, or 26133, are listed in Table 1-1 at the end of this section. This document
presents EPA's rationale and technical support for the revision of treatment standards
for organic constituents in the wastewater forms of the previously mentioned wastes. In
this document, the wastes identified by the aforementioned codes may also be referred to
as "the wastes of interest." . . '
'* ' -
BOAT treatment standards were established for the wastes of interest in
accordance with the amendments to the Resource Conservation and Recovery Act
(RCRA) of 1976, enacted by the Hazardous and Solid Waste Amendments (HSWA) of
November 8,1984. Treatment standards for the wastes of interest became effective on
1 *
various dates, none later, than May 8,1990. Since the effective dates, compliance with .
these BDAT treatment standards has been a prerequisite under 40 CFR Part 268 for
placement of the wastes in land disposal units. . .
'Wastewaters are defined as wastes containing less than 1% (weight basis)' total
suspended solids2.(TSS) and less than 1% (weight basis) total organic carbon (TOC).
Wastes not meeting this definition are classified as nonwastewaters and must comply with
the nonwastewater treatment standard. '
'The term "total suspended solids" (TSS) clarifies EPA's previously used terminology of
"total solids" and "filterable solids." Specifically, total suspended solids is measured by
Method 209C (total suspended solids dried at 103-105ฐC) in Standard Method for the
Examination of Water and JVastewater. Sixteenth Edition (1). .' " .
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The Agency's legal authority and promulgated methodology for establishing
treatment standards,, and the petition process necessary for requesting a variance from
the treatment standards, are summarized in EPA's Methodology for Developing BDAT ,
Treatment Standards (2\ If the individual concentrations of all of the regulated
constituents (organics, inorganics, and metals) in a waste, as generated, are lower than or
equal to their respective concentration-based treatment standards, then treatment of that
waste is not required prior to land disposal.
' ' ." .'"
The previously promulgated treatment standards for the organic
constituents regulated in wastewater forms of K015, K016, K018, K019, K020, K023,
K024, K028, K030, K048, K049, K050, K051, KOS2, K087, K093, K094, U028, U069,
U088, U102, U107, and U190 were determined based on constituent concentrations in
incinerator scrubber water. This methodology was. used for the following reasons:
EPA was not aware that wastewater forms of the waste, as
generated, existed; therefore, it was believed that the only
wastewater forms of the waste that might be generated would have
been derived from the treatment of the nonwastewater form of the
waste by incineration (i.e., scrubber water); and
Actual wastewater treatment performance data for treatment of the
wastes of interest or wastes judged to be similar were not readily
available. , .
.The Agency is revising the treatment standards for wastewater forms of the
wastes of interest and basing the treatment standards on available wastewater treatment
performance data rather than concentrations in incinerator scrubber water. This revision
is in accordance with the methodology established by the Agency in the Third Third
Final Rule (55 FR 22599). The Agency prefers to use appropriate wastewater treatment
performance data from well-designed and well-operated wastewater treatment units to
develop wastewater treatment standards whenever possible because they represent the
performance of actual wastewater treatment technologies; conversely, concentrations in
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0603-01-Bfj . . 1-2
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incinerator scrubber water represent a residual from treatment of nonwastewaters and do
not specifically reflect wastewater treatment.
The revised BDAT treatment standards for organic constituents-in
wastewater forms of the wastes of interest are based on wastewater treatment
performance data from several sources. These sources include the Best Demonstrated
" ' i
Available Technology (BDAT) database, wet air oxidation (WAO) and powdered
activated carbon addition to biological treatment (PACT9) data, the Industrial
Technology Division (TTD) (now the Engineering and Analysis Division (HAD))
i I - ' ' . '
database, the National Pollutant Discharge,Elimination System (NPDES) database, the -
Water Engineering Research Laboratory (WERL) database, industry submitted leachate
treatment performance data, data in literature that are not part of the WERL database,
and data in literature submitted by industry on the WAO and PACT9 treatment
processes. Details regarding the development of a wastewater database combining the
information in these sources are presented in EPA's Final Best Demonstrated Available
Technology (BDAT) Background Document for U and P Wastes and Multi-Source
Leachate (F039). Volume A: Wastewater Forms of Organic UJrnd P Wastes and Multi-
Source Leachate (F0391 For Which There are Concentration-Based Treatment
Standards (3). . . ,,
Two exceptions to these revisions include the treatment standard for benzal
chloride in wastewater forms of K015 and the treatment standard for pentachloroethane
in wastewater forms of K018, K028, and K030. The previously promulgated treatment
standard for benzal chloride in wastewater forms of K015 is not being revised. The ,
K015 treatment standard is based on benzal chloride concentrations in incinerator
scrubber water and will continue to be based on incinerator scrubber water data because
actual wastewater treatment performance data for benzal chloride are not available at
this time. During the development of the Third Third rule, a concentration-based
/ " t . * -
treatment standard for benzal chloride could not be established due to analytical .
difficulties; a technology-based treatment standard was then established for U017 (benzal
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chloride). However, because benzal chloride may be present m K015 m concentrations
above 88%, the Agency believes that it is necessary to establish a concentration-based
treatment standard for benzal chloride in wastewater forms of K015 to ensure that the
waste is substantially treated prior to land disposal. Also during the development of the
Third Third rule, the Agency determined that complications arise in the quantification of
pentachloroethane, a regulated constituent in K018, K028, and K030 (see 55 FR 22611).
As such, the Agency promulgated a method of treatment standard, rather than a
concentration-based treatment standard for this constituent. EPA is now removing
pentachloroethane from regulation in wastewater forms of K018, K028, and K030. The
Agency believes that the treatment of other regulated constituents in K018, K028, and
K030 will, in turn, provide treatment of pentachloroethane that is sufficiently protective
of human health and the environment.
The revised treatment standards promulgated today for the regulated
organic constituents in wastewater forms of K015, K016, K018, K019, K020, K023, K024,
K028, K030, K048, K049, K050, K051, K052i K087, K093, K094, UQ28, U069, UQ88,
U102, U107, and U19Q wastes are listed in Table 1-2. These treatment standards reflect
the total concentration of each organic constituent regulated in the wastewater forms of
the wastes of interest. The units used to report total constituent concentration are mg/L
(parts-per-million on a weight-by-volume basis):
Sections 2.0 through 6.0 of this document supplement discussions in the
background documents listed in Table 1-3 by discussing applicable and demonstrated
treatment technologies, wastewater treatment performance data, determination of the
revised BDAT, constituents selected for regulation, and calculation of the revised
treatment standards. Section 7-0 contains acknowledgements, and Section 8.0 lists .
references. Appendix A presents the wastewater treatment performance data, on a
constituent-by-constituent basis, that were used to determine the revised BDAT, and to
calculate the revised treatment standards promulgated in this regulation!
NRJ/NW-054
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1-4
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Table 1-1
Waste Code Definitions
i [
K015. Still bottoms from the distillation of benzal chloride.
K01J. Heavy ends or distillation residues from the production of carbon
tetrachloride.
K018. Heavy ends from the fractionation column in ethyl chloride production:
K019. Heavy ends from the distillation of ethylene dichloride in ethylene
dichloride production.
K020. Heavy ends from the distillation of vinyl chloride in vinyl chloride
monomer production.
K023. Distillation light ends from the production of phthalic anhydride from
naphthalene. . . . "
K024. Distillation bottoms from the production of phthalic anhydride from
naphthalene. '
K028. Spent catalyst from the hydrochlorination reactor in the production of
1,1,1-trichloroethane.
- , ' . \ ' ' ;-".'
KQ3Q. Column bottoms or heavy ends from the combined production of
trichloroethylene and perchloroethylene. ' ;
K04g. Dissolved air flotation (DAF) float from the petroleum refining industry.
K049. Slop soil emulsion solids from the petroleum refining industry.
K050. Heat exchanger bundle cleaning sludge from the petroleum refining
industry.
'
K051. API separator sludge from the petroleum refining industry.
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Table 1-1
(Continued)
KOS2. Tank bottoms (leaded) from the petroleum refining industry.
K087. Decanter tank tar sludge from coking operations.
> K093. Distillation light ends from the production of phtbalic anhydride from
ortho-xylene.
/
K094. Distillation bottoms from the production of phthalic anhydride from ortho-
xylene. . .
U codes representing discarded commercial chemical products, off-specification species,
container residue, and spill residue containing these constituents:
UQ28. bis(2-Ethylhexyl) Phthalate. , ;
/
U069. Dibutvl Phthalate.
U088. Diethyl Phthalate.
U102. Dimethyl Phthalate.
U107. Di-n-octyl Phthalate.
U190. Phthalic Anhydride.
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Table 1-2
' <
Revised BOAT Treatment Standards for Organic Constituents
Regulated in Wastewater Forms of K015, K016,
K018, K019, K020, K023, K024, K028, K030, K048,
K049, K050, K051, K052, K087, K093, K094, U028,
U069, U088, U102, U107, and U190
- ' : . -" . . KD15. ''.'
Maximum for Any Single Grab Sample
BOAT last Constituent
57. Anthracene . .
218. Benzal chloride
63, Benzo(b)fluoranthene
65. Benzo(k)fluoranthene
141. Fhenanthrene ' .
; 43. Toluene
Total Constituent Concentration
in Wastewaters (mg/L)
0.059
0.28*
0.055
0.059
OX)59 ,
0.080
K016
Maximum for Any Single Grab Sample
BDAT List Constituent
110. Hexachlorobenzene ' ' <
111. Hexachlorobutadiene .
112. Hexachlorocyclopentadiene .
113. Hexachloroethane '
42. Tetrachloroethene ..
Total Constituent Concentration
in Wastewaters (mg/L)
0.055
0.055
0.057
0.055
0.056
The trMtmeBt lUntkrd for benzat chloride in wปซewซter form* of K01S U ooc being tendtซd.
NRJ/NW-054
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" 1-7
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Table 1-2
(Continued)
K018
Maximum for Any Single Grab Sample
BDAT List Constituent
12. Chloroethane
15. Chloromethane . ' ,
22. 1,1-Dichloroethane
23. ,lฃ-Dichloroethane < .
110. Hexachlorobenzcne .
111. Hexachlorobutadiene
137. Pentachloroethane
45. 1,1,1-Trichloroethanc
113. Hexachloroethane
Total Constituent Concentration
in Wastewaters (mg/L)
0^7
0.19
0.059
o^i
0.055
0^55
NR
0.054
0.055
NR - Not Regulated.
NRJ/NW-054
0603-01 jnj
1-8
-------
Table 1-2
(Continued)
K019
. . - Maximum for Any Single Grab Sample \ .
BDAT List Constituent
68. bis(2-Chloroethyl)ether
9. Chlorobenzene . '
14. Chloroform - '
88. p-Dichlorobenzene
23. 1,2-Dichloroethane
109. Fluorene ' -
113. Hexachloroethane
121. Naphthalene . .
141. Phenanthrene '
148. 1^,4,5-Tetrachlorobenzene
42. Tetrachloroethene
150. lA4-Trichlorobenzene
45. 1,1,1-Trichloroethane
Total Constituent Concentration
in Wastewaters (mg/L) ,
0.033
OJOS7
0.046 ,
6.090
0^1 ' ;
0.059
0.055
0.059
O^J59
0.055
0.056
0.055
0.054
, KD20 .
Maximum for Any Single Grab Sample ,
BDAT List Constituent
23. 1,2-Dichloroethane
41. 1,1,^2-Tetrachloroethane
42, Tetrachloroethene
Total Constituent Concentration
in Wastewaters (mg/L) .
0-21
0.057
0.056
, K023
Maximum for Any Single Grab Sample .
BDAT List Constituent ]
220. Phthalic Anhydride (measured as phthalic acid)
Total Constituent Concentration
in Wastewaters (mg/L)
0.069
NRJ/NW-054
0603-01.nrj
'1-9
-------
Table 1-2
(Continued)
K024
Maximum for Any Single Grab Sample
BDAT List Constituent
220. Phthalic Anhydride (measured as pbthalic acid)
Total Constituent Concentration
in Wastewaters (mg/L)
0.069
... ' ' K028 ''' ' ; ' \ .. '
Maximum for Any Single Grab Sample
BDAT List Constituent
22. 1,1-Dichloroethane
25. trans-L>Dichloroethene
111. Hexachlorobutadiene
113. Hexachlorpetbane '.."
137. . Pentachloroethane
40. 1,1,1,2-Tetrachloroethane
41. 1,1,2,2-Tetrachloroethane .
42, Tetrachloroethene
45. 1,1,1-Trichloroethane
46. L.l^-Trichloroetnane
Total Constituent Concentration
in Wastewaters (mg/L)
0.059
0^)54
0.055
0^155
MR
0.057
0,057
0.056
0.054
0.054
NR - Not Regulated.
NRI/NW-054
MO
-------
Table 1-2
(Continued)
; , , ' K030
; '. . Maximum for Any Single Grab Sample '
BDAT List Constituent
87. o-Dichlorobenzene .
88. p-Dichlorobenzene
111. Hexachlorobutadiene
113. Hcxachloroethane
137. Pentachloroethane
148. 1^,44-Tetrachlorobenzene, .
42. Tetrachlorocthene
ISO. lA4-Trichlorobcnzene
Total Constituent Concentration
in Wastewaters (mg/L)
0.088
OXJ90
0.055
- ' 0.055
. MR
0.055
0.056
0.055
MR -Not Regulated
NW/NW-054
0603-01 .ng
1-11
-------
Table 1-2
(Continued)
KQ48
'
Maximum for Any Single Grab Sample
BOAT List Constituent
4. Benzene
62. Benzo(a)pyrenc .
70. bis(2-Ethylhexyl)phthalate
80. Chrysene
98. Di-n-butyl PhthaJate
226. Ethyibenzene
109. Fluorene
121. Naphthalene . -
141. Phenanthrene , '
142. Phenol
145. Pyrene
43. Toluene
215.-217. Xylenes (total)
Total Constituent Concentration
in Wastewaters (mg/L)
044
' 0.061
OJ28
OX)59
OXป57
0.057
0.059
0.059
0.059
0.039
0.067
0.080
- 032
NRJ/NW-054
0603-01 .mj
1-12
-------
Table 1-2
(Continued)
' ' ' ' ' K049 . ' ;
,. Maximum for Any Single Grab Sample
BDAT List Constituent .
57. Anthracene
4. Benzene ,
62. Benzo(a)pyrene . '
70. bis(2-Ethylha{yl)phthalate
& Carbon Bisulfide - /
SO. Chrysene
96. 2,4-Dimethylphcnol
226. Ethylbenzene
121. Naphthalene
141. Phenanthrene * ' >
142. Phenol .
145. Pyrene
43. Toluene
215.-217. Xylenes (total)
Total Constituent Concentration
in Wastewaters (mg/L)
00159
0.14
0.061 .
0 2&
0.014
0.059
0.036 '
0.057
0.059.
OXJ59 ,
0.039
0.067
0.080
032
K050
' ' Maximum for Any Single Grab Sample
' \
BDAT List Constituent :
62. Benzo(a)pyrene . ' ,
142. Phenol
Total Constituent Concentration
in Wastewaters (mg/L)
, 0.061
6.039
NW/NW-054
0605-01 .orj .
1-13
-------
Table 1-2
(Continued)
KD51
Maximum for Any Single Grab Sample
BOAT Last Constituent ,
SZ Acenaphthene
57. Anthracene
59. Benz(a)anthracene
4. Benzene - -
62. Benzo(a)pyrene
70. bis(2-Ethyme^i)phthalate
80. Chrysene .
98. Di-n-butyl Phthalate
226. Ethylbenzene . ' . '
109. Fluorene
121. Naphthalene
141. Phenanthrene < .
142. Phenol
145. Pyrene .
43. Toluene
215.-217. Xylenes (total)
Total Constituent Concentration
in Wastewatcrs (mg/L)
0.059
0.059
0.059
0.14
O-OW
028
0.059
0.057
0.057
O^J59
0.059
0.059
0.039
0.067
0.080
- 032
0603-014ปj
M4
-------
Table 1-2
(Continued)
. K052
Maximum for Any Single Grab. Sample .
*
BDAT List Constituent
4. Benzene
62. Benzo(a)pyrene
81. o-Cresol
82. Crcsol (m- and p- isomers)
96. 2,4-DimethyIphenol
226. Ethylbenzene
121. Naphthalene
141. Fhenanthrene
142. Phenol
43. Toluene .
215.-217. Xylenes (total)
Total Constituent Concentration
in Wastewaters (mg/L)
0.14
0.061
0.11
0.77
6.036
0.057
0.059
6^59
0.039
0.080
032
NRI/NW-054
0603-014*$
1-15
-------
Table 1-2
(Continued)
- K087
Maximum for Any Single Grab Sample . -,'.'
BOAT List Constituent
51. Acenaphthalene
4. Benzene ' '
80. Chrysene
108. Fluoranthene ,
116. Indeno(L23-cd)pyrcne
121. Naphthalene
141. Phenanthrene
43. Toluene
2L5.-217. Xylenes (total)
K093
Total Constituent Concentration
'-' in Wastewaters (mg/L)
0.059
0.14
0.059
0.068
0.0055
0.059
0.059
OJ08Q
032
Maximum for Any Single Grab Sample . ,
- , / , f
BDAT List Constituent
220. Phthalic Anhydride (measured as phthalic add)
Total Constituent Concentration
in Wastewaters (mg/L) ,
0.069
K094
Maximum for Any Single Grab Sample
BDAT List Constituent
220. Phthalic Anhydride (measured as phthalic acid)
Total Constituent Concentration
in Wastewaters (mg/L)
0.069
NRJ/NW-054
0603-01-nrj
1-16
-------
Table 1-2
(Continued)
U028
Maximum for Any Single Grab Sample
BDAT List Constituent
Total Constituent Concentration
in Wastewaters (mg/L)
70. bis(2-Ethylhexyl)pbthalate
028
U069
Maximum for Any Single Grab Sample
BDAT List Constituent
Total Constituent Concentration
in Wastewaters (mg/L)
98. Di-n-butyl Phtbalate
0.057
U088
Maximum for Any Single Grab Sample
BDAT List Constituent
Total Constituent Concentration
in Wastewaters (mg/L)
92. Diethyl Phthalate
0.20
U102
Maximum for Any Single Grab Sample
BDAT List Constituent
Total Constituent Concentration
in Wastewaters (mg/L)
97. Dimethyl Phtbalate
0.047
NRJ/NW-054
0603-0l4ปj
1-17
-------
Table 1-2
(Continued)
U107 ' -
Maximum
for Any, Single Grab. Sample
BOAT List Constituent,
104. Di-n-octyl Phthalate
Total Constituent Concentration
in Wastewaters (rag/L)
0.017
U190
Maximum
for Any Single Grab Sample
BDAT List Constituent
220. Phthalic Anhydride (measured as phthalic acid)
Total Constituent Concentration
in Wastewaters (mg/L)
0.069
NKI/NW-OS4
0603-Oljnj
1-18
-------
Table 1-3
Background Documents Which Are Being Amended
Final Best Demonstrated Available Technology (BDAT) Background Document
for K015 (5) (hereinafter referred to as the Background Document for K015).
Final Best Demonstrated Available Technology (BDAT) Background
for K016. K018. K019. K020. and K030 (6) (hereinafter referred to as the
Background Document for K016, K018, K019, K020, and K030).
Final Best Demonstrated Available Technology (BDAT) Background Document
for Phthalate Wastes: K023. K024. K093. K094. U028. U069. U088. U1Q2. U107.
U190 (7) (hereinafter referred to as the Background Document for Phthalate '
Wastes). .
Final Best Demonstrated Available Technology (BDAT) Background Document
forK024 (8) (hereinafter referred to as the Background Document for K024).
Final Best Demonstrated Available Technology (BDAT) Background Document
for Wastes From the Production of 1.1.1-Trichloroethane: K028. K029. K095. and
K096 (9) (hereinafter referred to as the Background Document for K028). ;
\ . . . ' ,
Final Best Demonstrated Available Technology (BDAT) Background Document
for K048. K049. K050. K051. and K052 '(10) (hereinafter referred to as the
Background Document for K048, K049, K050, K051, and K052).
Final Best. Demonstrated Available Technology (BDAT) Background Document
forK087 (11) (hereinafter referred to as the Background Document for K087).
NRJ/NW-OS4
0603-01 joj . 1-19
-------
-------
2.0 AMENDMENT TO THE "APPLICABLE AND DEMONSTRATED
TREATMENT TECHNOLOGIES* SECTION OF THE FINAL BDAT
BACKGROUND DOCUMENTS FOR K015, K016, K018, K015), K020,
K023, K024, K028, K030, K048, K049, KOSO, K051, K052, K087, K093,
K094, U028, U069, U088, U102, U107, and U190: WASTEWATER
ORGANICS
This section supplements the discussion in Section 3.0 (Applicable and
Demonstrated Treatment Technologies) concerning the following documents:
Background Document for K015 (5);
Background Document for K016, K018, K019, K020, and K030 (6);
Background Document for Phthalate Wastes (7);
Background Document for K024 (8); ,
Background Document for K028, KQ29, K095, and K096 (9);
, * '' p ' '
Background Document for K048, K049, KOSO, K051, and K052 (10);
and ' . /''.'
. Background Document for K087 (11).
This section discusses the technologies that are applicable for the treatment
of organic constituents in wastewater forms of the wastes of interest and that can be
considered demonstrated for the purpose of establishing BDAT.
',-'"
2.1 Applicable Treatment Technologies
i _ '.">*'
To be considered apph'cable, a technology must theoretically be usable to.
N ' ป
treat the waste. Detailed descriptions of technologies that are applicable for treatment
NR//NW-054 '
0603-01 Jttj s ' - 2-1
-------
of listed hazardous wastes are provided in EPA's Treatment Technology Background
Document (4). . . ' -?
Since wastewater forms of the wastes of interest may contain organic
constituents at treatable concentrations, applicable treatment technologies include those
that destroy or reduce the total amount of organic compounds in the wastewater. The
Agency has identified the following treatment technologies as potentially applicable for
treatment of these wastes:
Biological treatment (including aerobic fixed film, aerobic lagoons,
activated sludge, anaerobic fixed film, rotating biological contactors,
sequential batch reactors, and trickling filter technologies);
i . . - ,. '
Carbon adsorption (including activated carbon and granular
' activated carbon technologies); .
Chemical oxidation;
Chemically assisted clarification (including chemical precipitation
technology);
" . r
Incineration (including fluidized-bed, rotary kiln, and liquid injection
incineration); N
* PACT* treatment (including powdered activated carbon addition to
. activated sludge and biological granular activated carbon
technologies); .
* \. ' .
Reverse osmosis; .
Solvent extraction (including liquid-liquid extraction technology);
Stripping treatment (including steam stripping and air stripping
technologies); and
Wet air oxidation (including supercritical oxidation technology).
WU/NW-054
0603-01 .m} 2-2
-------
Total recycle or reuse may also be applicable for certain wastes. These treatment
technologies were identified based on current waste treatment practices and engineering'
judgment. .
The concentrations and type(s) of constituents present in a waste generally
determine which technology is most applicable. For example, wet air oxidation, PACT*
treatment, biological treatment, and solvent extraction are applicable for treatment of
wastewaters containing a total organic carbon concentration up to 1% and is often used:
as a polishing step following primary treatment by biological treatment, solvent
extraction, or wet air oxidation. Typically, carbon adsorption is applicable for treatment
of wastewaters containing a total organic carbon concentration of less than 0.1%. Some
of the wastewaters that are the subject of this document may contain constituents that
.are too toxic to be treated effectively by biological treatment or PACT* treatment.
* l - '
Brief discussions of each of the technologies identified as applicable for the
treatment of organic constituents in wastewater forms of the wastes of interest are given
below:
" Biological Treatment , , "
Biological treatment is a destruction technology in which hazardous organic
constituents in wastewaters are biodegraded. This technology generates two treatment
residuals: a treated effluent and>a waste biosludge. Waste biosludge may be land
disposed without further treatment if it meets the applicable BDAT nonwastewater
treatment standards for regulated constituents.
\ . " .. . -
Carbon Adsorption
Carbon adsorption is a separation technology in which hazardous organic
constituents in wastewaters are selectively adsorbed onto activated carbon. This
NRJ/NW-QS4 .
060341*$ . 2-3 ,
-------
technology generates two treatment residuals: a treated effluent and spent activated
carbon. The spent activated carbon can be reactivated, recycled, or incinerated.
*
'Chemical Oxidation x
- 7
Chemical oxidation is a destruction technology in which inorganic cyanide,
some dissolved organic compounds, and sulfides are chemically oxidized to yield carbon
dioxide, water, salts, simple organic acids, and sulfates. This technology generates one
treatment residual: treated effluent. , '
Clarification
Chemically-assisted clarification, including chemical precipitation, is a
separation technology in which the addition of chemicals during treatment results in the
'
formation of precipitates from the organic or inorganic constituents in wastewater. The
solids formed are then separated from the wastewater by settling, clarification, and/or
i
polishing filtration. This technology generates two treatment residuals: treated
wastewater effluent and separated solid precipitate. The solid precipitate may be land
disposed without further treatment if it meets the applicable BDAT nonwastewater
treatment standards.
' . ' ' i
Incineration . . ' N
Incineration is a destruction technology in which heat is transferred to a
waste to destabilize chemical bonds and destroy organic constituents, In a fiuidized-bed
incinerator, waste is injected into the fiuidized-bed material (generally sand and/or
incinerator ash), where it is heated to its ignition temperature. Heat energy from the
combustion reactions is then transferred back to the fiuidized bed. Ash is removed
periodically during operation and during bed change-outs.
NRJ/NW-054
x 0603-01 .mj . 2-4
-------
In a rotary kiln incinerator, .wastes are fed into the elevated end of the
kiln. The rotation of the kiln causes the waste to mix with hot gases to heat the waste to
its ignition temperature. Combustion gases from the kiln enter an afterburner for
'- , -
complete destruction of organic waste constituents. Other wastes may also be injected
into the afterburner. Also, ash is removed from the lower end of the kiln.
, In a liquid injection incinerator, liquid wastes are atomized and injected
into the incinerator. In general, only wastes with low or negligible ash contents are
amenable to liquid injection incineration. Therefore, this technology does not generate
an ash residual. ; .
Combustion gases from the incinerators are fed to scrubber systems for
cooling and removal of entrained particulates and add gases, if present. In general, with
the exception of liquid injection incineration,.two residuals are generated by incineration
processes: ash and scrubber water.
' PACT* Treatment ;
i .
PACT* treatment is a combination of carbon adsorption and biological
treatment. It is a destruction technology in which hazardous organic constituents are
' ' ' i '
biodegraded and selectively adsorbed onto powdered activated carbon. This technology
generates two treatment residuals: a treated effluent and spent carbon/biosludge. The
spent carbon may be regenerated and recycled to the process or incinerated.
1 *
Reverse Osmosis
. t ' ' ' , !
' ' " f V ' "
Reverse osmosis is a separation technology in which dissolved organics ~
(usually salts) are removed from a wastewater by filtering the wastewater through a
semipermeable membrane at a pressure greater than the osmotic pressure caused by the
dissolved organic .constituents. This technology generates two residuals: the treated
^ '
NRJ/NW-054 .' ". '''', '.'.'
060341.00 i 2-5 : .
-------
effluent and the concentrated organic salt materials that do not pass through the
membrane. ,
Solvent Extraction
Solvent extraction is a separation technology in which hazardous organic
constituents are removed from a waste due to greater solubility in the solvent phase than
in the waste phase. This technology generates two residuals: a treated waste residual
and an extract The extract may be recycled or treated by incineration. .
Stripping Treatment
Stripping treatment is a separation technology in which volatile organic
constituents in a liquid waste are physically transferred to a flowing gas or vapor. In
steam stripping, steam contacts the waste, strips the volatile organics, and carries them to
a condenser where the mixture of organic vapors and steam is condensed and collected
in an accumulator tank. In air stripping, air contacts the waste and strips the volatile
j
organic constituents. Air stripping generates one treatment residual: treated effluent.
Emissions generated from air stripping may require further treatment .
Wet Air Oxidation '
i .
Wet air oxidation is a destruction technology in which hazardous organic
constituents in wastes are oxidized and destroyed under pressure at elevated
.temperatures in the presence of dissolved oxygen. This technology is applicable for
' '
wastes comprised primarily of water and containing a total organic carbon concentration
of iip to 10%. Wet air oxidation generates one treatment residual: treated, effluent
The treated effluent may require further treatment for hazardous organic constituents by
carbon adsorption or PACT* treatment Emissions from wet air oxidation may also
require further treatment,
.'"*-. '
NRJ/NW-054 s '
0603-0! jaj / . 2-6 , '
-------
2*2 Demonstrated Treatment Technologies : ~ *
/ -. . -
The performance data presented in Appendix A of this document include
i ^^
full-scale treatment performance data for all of these technologies. Therefore, all of the
technologies identified as applicable for the treatment of organic constituents in
wastewater forms of the wastes of interest have been "demonstrated" in full-scale
operation for treatment of wastewaters containing these constituents or constituents
determined to be similar. The Agency believes that all of these wastewater treatment
technologies deserved further consideration as potential Best Demonstrated Available
Technologies for the constituents in the wastes of interest
NRJ/NW-054
0603-Oljjfj 2-7.
-------
-------
3.0, AMENDMENT TO THE TREATMENT PERFORMANCE DATABASE"
SECTION OF THE FINAL BDAT BACKGROUND DOCUMENTS FOR
K015, K016, K018, K019, K020, K023, K024, K028, K030, K048, K049,
K050, K051, K052, K087, K093, K094, U028, U069, U088, U102, U107, and
U190: WASTEWATER ORGANICS
* ซ s ' * - ซ *
This section supplements the discussion in Section 4.0 (Treatment
Performance Database) of the following documents, unless stated otherwise:
* Background Document for K015 (5);
Background Document for K016, K018, K019, K020, and K030 (6);
s . ,
, Background Document for Phthalate Wastes (7);
Background Document for K024 (8);
Background Document for K028, K029, K095, and K096 (9);
Background Document for K048, K049, K050, K051, and K052 (10);
and . "' . '....
Background Document for K087 (11).
V * ' .
. Since the Agency does not have any treatment performance data for
organic constituents in wastewater forms of K015, K016, K018, K019, K020, K023, K024,
K028, K030, K048, K049, K050, K051, K052, K087, K093, K094, U028, U069, U088,
U102, U107, and U190, wastewater treatment performance data from several other data
sources.were examined. Details regarding the development of the wastewater treatment
performance database using these sources are presented in EPA's Final Best
Demonstrated Available Technology (BDAT) Background Document for U and P
Wastes and Multi-Source Leachate (FQ39), Volume A: Wastewater FormsLof Organic \ I
and P Wastes and Multi-Source Leachate (F039^ For Which There Are Concentration-
Based Treatment Standards (3). '- . ^ .
NRI/NW-QS4 . ,
0603-01.M3 ' . 3-1
-------
This section presents the wastewater treatment performance data available
to the Agency for each BDAT List organic constituent regulated in the wastes of interest.
Section 3.1 gives a brief description of each data source examined for applicable
wastewater treatment performance data. Section 32 discusses the wastewater treatment
performance data considered in determining BDAT. The actual treatment performance
data available to EPA for each constituent regulated in the wastes of interest are
presented on a constituent-by-constituent basis in the tables of Appendix A.
.
3.1 Sources of Treatment Performance Data
' ฐ '''","
The sources examined for applicable wastewater treatment performance
data included: . . ";
j /
The BDAT database;
WAO/PACT* data;
, s ' v
The HAD database;
v - * -
. The NPDES database;
*
The WERL database;
Industry submitted leachate treatment performance data;
, Data hi literature that were not already part of the WERL
database; and T
Data in literature submitted by industry on the WAO and PACTฎ -;
treatment processes.
i ' '
The treatment performance data from these sources were used to
determine BDAT for organic constituents in the wastewater forms of K015, K016, K018,
K019, K020, K023, K024, K028, K030, K048, K049, K050, KOS1, K052, K087, K093,
K094, U028, U069, U088, U102, U107, and U190.
NRJ/NW454
' .- 3-2
-------
3.1.1 BOAT Database
The BDAT database consists of treatment performance data collected to
establish treatment standards for wastes regulated in the First, Second, and Third Third
BDAT Land Disposal Restrictions rulemakings. '
Extensive sampling of incineration systems has been conducted under the
BDAT program. As part of these sampling efforts, incinerator scrubber water data were
collected to determine BDAT treatment standards for wastewater forms of various
hazardous wastes. As discussed in Section 1.0, however, the Agency prefers to use
appropriate wastewater treatment performance data from well-designed and well-
operated wastewater treatment units rather than constituent concentrations in scrubber
water to develop wastewater treatment standards. (This does not, however, preclude the
Agency from establishing treatment standards for wastes based on constituent
concentrations in incinerator scrubber waters on a case-by-case basis.) Therefore, only
'treatment performance data from the BDAT database that represent a specific
technology amenable to wastewater treatment, such as biological treatment or chemical
precipitation; were examined as potential treatment performance data for determination
of treatment standards for the constituents regulated in the wastes of interest.
BDAT wastewater treatment performance data were available for K103,
K104, and K062 from the First and Second Third groups of wastes. The wastewater
treatment technologies represented by the data for these waste codes include
liquid/liquid extraction, steam stripping, and activated carbon adsorption for organic
constituents.
' . , - " i --."
i . - > ,
Additionally, as part of the development of the final rule restricting the
I ป ' . , . N
land disposal of solvent wastes F001-F005, the Agency examined data from EAD
sampling episodes, which are presented in the F001-F005 background document (12).
- ' "
The technologies represented by the data for these waste codes include biological
/''
NRJ/NW-054 ' . - , .
0603-Ol.ng 3-3 .
-------
treatment, activated carbon adsorption, steam stripping, air stripping, and wet air
oxidation. The wastewater treatment performance data for constituents regulated in
F001-F005 were incorporated into the wastewater treatment database.
3.1.2 WAO/PACTData
For specific Third. Third U and P waste codes, a wastewater treatment test
was conducted using wet air oxidation (WAO) and PACT" treatment technologies. The
treatment performance data from this test were incorporated into the wastewater
treatment database.
i
3.13 EAD.Database-Promulgated Limits ,
/ - .
In response to the Federal Water Pollution Control Act (FWPCA) of 1972
and the Clean Water Act (CWA) of 1977, EPA promulgated regulations to reduce the
levels of pollutants in wastewaters discharged from industrial point sources using the
"Best Available Technology Economically Achievable." The responsibility for developing
and promulgating effluent limitations guidelines was assigned to the Industrial
Technology Division (ITD), how the Engineering and Analysis Division (EAD), within
EPA's Office of Water Regulations and Standards. To date, EPA has promulgated
' k.
effluent regulations for 27 industrial categories.
The treatment performance data used in promulgation efforts have been
summarized by category in specific effluent limitations guidelines and standards
development documents. The treatment performance data from the Final Development
Document for Effluent Limitations Guidelines and Standards for the Organic Chemicals,
Plastics, and Synthetic Fibers Point Source Category for BDAT list organic constituents
for which effluent limitations exist were incorporated into the wastewater treatment
database. -, . '
NRJ/NW-OS4 <
0603-01 .mj 3-4
-------
3.1.4 NPDES Database. . . ,
1 ' ' ' ' '
Under the dean Water Act, the discharge of pollutants into the waters of
the United States is prohibited unless a permit is issued by EPA or a state under the
National Pollutant Discharge Elimination System (NPDES). An NPDES permit
establishes effluent limitations for specific pollutants that a facility may discharge. The,
permit also establishes monitoring and reporting requirements for a facility to determine
whether the effluent limitations are being met The monitoring data submitted to the
' - \
Agency by facilities as part of the NPDES permit program is summarized in the NPDES
database. ... - -
The NPDES database was searched to identify facilities that have
monitoring data for 90 BDAT List constituents. Data from this search, representing
constituent concentrations in effluents from wastewater treatment, have been
incorporated into the wastewater treatment database. However, EPA was unable to
evaluate whether substantial treatment occurred because the corresponding influent
concentrations of the constituents were not available. Also, the treatment technologies
or treatment trains represented by the NPDES data were identified in some, but not all
cases. Therefore, NPDES data were used to calculate treatment standards only when
other data were unavailable. , ' , ,
3.1.5 WERL Database '
EPA's Risk Reduction Engineering Laboratory, which now includes the .
former Water Engineering Research Laboratory (WERL), has developed and is
continuing to expand a database on the treatability of chemicals in various types of
waters and wastewaters. This WERL database has been compiled from wastewater
treatment performance data available in literature.. The treatment performance data for
BDAT List constituents in this database were included in the wastewater treatment .
database. ' ' - - , '
NRI/NW-054
0603-014ttj ; . '. , 3*5
-------
3.1.6 Leachate Treatment Performance Data
Leachate treatment performance data were submitted to the Agency prior
to the proposal of the Third Third Land Disposal Restrictions rule. The data were
developed and compiled by a committee comprised of representatives of several major
domestic corporations. This leachate committee was formed in April 1989 following the
stay by the U.S. Court of Appeals, D.C. Circuit, of the Land Disposal Restrictions for the
First Third group of wastes as it applied to hazardous waste leachate. '(Waste
Management Inc. vs. EPA CADC, No. 88-1581, 8/9/88.)
The data submitted included waste characterization data and full- and
bench-scale treatment performance data for multi-source leachate. For those
constituents with little or no wastewater treatment performance data but for which
industry-submitted leachate treatment performance data were available and showed
substantial treatment, the Agency used the leachate treatment performance data as .the
basis for calculating concentration-based treatment standards. The leachate treatment
performance data that were used to recalculate BDAT treatment standards proposed in
the Third Third Final Rule have been included in the wastewater treatment database.
3.1J Other Sources
Other sources of wastewater treatment performance data for BDAT list
constituents include data in literature that were not already part of the WERL database
s
and data in literature submitted by industry on the WAO and PACT0 treatment
processes.
3.2 - Treatment Performance Database
All of the treatment performance data that were considered in the
development of the treatment standards for organic constituents in wastewater forms of
NW/NW-054 ' ^^
3-6 .
-------
the wastes of interest are summarized in the tables of Appendix A. (The data that were
used to calculate each of the revised BDAT treatment standards are shown in these
tables with an asterisk.) These1 data are discussed in greater detail in EPA's Final Best
Demonstrated Available TfechymTogy (BDAT) Background Document for I? and P
Wastes and Multi-Source Leachate (F039X Volume A: Wastewater Forms of Organic II
and P Wastes and Multi-Source Leachate (F039) For Which There Are Concentration-
Based Treatment Standards (3). '.'.-: '
s __
The discussions that precede each of the data tables in Appendix A present
any additional data that may have been considered in determining the final
concentration-based treatment standards. The Agency prefers, whenever possible, to use
appropriate wastewater treatment performance data from well-designed and well-
operated wastewater treatment units rather than data from incinerator scrubber water.
The wastewater treatment performance data in Appendix A were accumulated from
wastes tHat exhibited similar characteristics to the wastes of interest - in terms of
treatment performance and treatment selection. 'Furthermore, the Agency believes that
the wastewater treatment performance data presented in Appendix A represent the best
sources of treatment performance data for organic constituents in wastewater forms of
the wastes of interest. ..'.'
NSJ/NW-054
0603-01.arj . . , 3-7
-------
-------
4.0 AMENDMENT TO THE "IDENTIFICATION OF BEST
DEMONSTRATED AVAILABLE TECHNOLOGY (BDAT)" SECTION OF
THE FINAL BDAT BACKGROUND DOCUMENTS FOR KQ1S, K016,
K018, K019, K020, K023, K024, K028, K030, K048, K049, K050, K051,
K052, K087, K093, K094, U028, U069, U088, U102, U107, AND U190:
WASTEWATER ORGANICS
This section supplements the discussion in Section 5.0 (Identification of
Best Demonstrated and Available Technology (BDAT)) of the following documents:
Background Document for K015 (S); .
Background Document for K016, K018, K019, K020, and K030 (6);
, Background Document for Phthalate Wastes (7);
Background Document for KQ24 (8);
r * ,
Background Document for K028, JC029, K095, and K096 (9);
Background Document for K048, K049, KOSO, K051, andK052 (1Q);
' - - '' and ' ' . ..' .' ' '-.-'
Background Document for K087 (11).
1 '
The best demonstrated available technology (BDAT) is determined based
on a thorough review, of all the treatment performance data available to EPA for the
wastes of concern or wastes judged to be similar. The treatment performance data that
were evaluated for these wastes are presented in Appendix A. ''.
' ' ' .' ' -1
; As described in EPA's Methodology Document for Developing BDAT
* '
Treatment Standards (2), after all applicable and demonstrated treatment technologies
are identified for the wastes of interest, treatment performance data are examined to
NBJ/NW454 ;-"
0603-01.mj 4-1
-------
identify the technologies that perform "best." The treatment performance data are
evaluated to determine:
Whether the data represent operation of a well-designed and well-
operated treatment system;
Whether sufficient analytical quality assurance/quality control
measures were employed to ensure the accuracy of the data; and
Whether the appropriate measure of performance was used to assess
the performance of the particular treatment, technology.
The Agency then determines whether the best demonstrated technology is "available."
An available treatment technology is one that (1) is not a proprietary or patented
process that cannot be purchased or licensed from the proprietor (i.e., it must be
commercially available), and (2) substantially diminishes the toxicity of the waste or
substantially reduces the likelihood of migration of hazardous constituents from the
waste. ,
* ,
The Agency determines the "best" demonstrated technology for each
constituent by a thorough review of all the treatment performance data available for
each constituent. The best demonstrated technology selected for each constituent is
described in Appendix A, along with the presentation of treatment performance data.
To determine the best demonstrated technology for specific constituents in
wastewaters, a hierarchy was established to evaluate the data presented in Section 3.0.
These data came from a variety of sources as identified in Section 3.2. In general, the
Agency believes that data from the EAD and BDAT programs are superior data than
those from other sources. The EAD database, described in Section 3.13, is a
comprehensive source of wastewater treatment performance data and usually represents
longer term sampling with a greater number of sample sets than'the other wastewater
NRJ/NW-054
0603-OlJUJ 4-2
-------
treatment databases, and data generated as part of the BDAT program follow EPA
protocols for sampling and analysis procedures. .
. The following is an outline of the data source hierarchy used to determine
the best demonstrated technology for wastewater constituents included in this 'document.
All data used in determining BDAT for a constituent came from the highest level in the
hierarchy in which they were available for a particular constituent.
(1) HAD treatment performance data that were used to promulgate an
BAD effluent-based limitation standard. The data representing BAD
Option I were used in all cases (13).
(2) Agency-sponsored BDAT wastewater treatment test data.
(3) Industry-submitted multi-source leachate treatment performance
data, where the data showed substantial treatment.
t / ' '
(4) Other available treatment performance data. Evaluation of these
data were based on: .
(a) The treatment technology for which data where available;
(b) Whether the data represented full-, pilot-, or bench-scale
treatment;
(c) The concentration of the constituent of interest in the
effluent from treatment;
. (d) The average concentration of the constituent of interest in
the effluent from treatment; and ' t '
' . - - '
(e) The removal efficiency of the treatment technology.
' ' \
Full-scale treatment performance data with an influent constituent .
concentration range greater than 100 ppb were preferred over .data .
. from pilot- or bench-scale operations, or from operations, with a low
(i.e., 0-100 ppb) influent constituent concentration range. If several .
sets of data met these criteria (i.e., full-scale available technologies
with high influent constituent concentrations), they were compared
by examination of their average effluent values and percent
NRJ/NW-OS4 . .
0603-01 JBJ 4-3
-------
removals to determine the data set(s) with the lowest effluent values
and the technology with the highest percent removal.
(5) ' If treatment performance data were not available from any of the
examined sources, data were transferred from a structurally similar
constituent. .
The applicable and demonstrated technologies identified in Sections 2.1
and 2.2 that were determined to be best for each constituent, as identified in
Appendix A, are all commercially, available. In addition, the treatment performance data
included in Appendix A show substantial treatment of each constituent by the
corresponding technologies selected as BDAT. Therefore, the best demonstrated
technology for each constituent is also considered to be "available," and is BDAT for that
t ' .'"*-'
constituent .
^ . V ' ....
In some cases, deviations from the above data source hierarchy were
necessary based on the data available for specific constituents. These deviations are
addressed in the relevant constituent discussions of Appendix A.
NKI/NW-054
060341.03 4-4
-------
5.0 AMENDMENT TO THE "SELECTION OF REGULATED
CONSTITUENTS" SECTION OF THE HNAL BDAT BACKGROUND
DOCUMENTS FOR K018, K028, AND K030: WASTEWATER
ORGANICS
This section supplements the discussion in Section 6.0 (Selection of
Regulated Constituents) in the following documents: . :
Background Document for K016, K018, K019, K020, and K030 (6);
and
Background Document for K028, K029, K095, and K096 (9).
As discussed in EPA's Methodology for Developing BDAT Treatment
Standards (2), constituents selected for regulation must satisfy the following criteria:
1. The constituent must be on the BDAT Tjst nf constituents.
Presence on the BDAT List means that EPA-approved methods
exist for analysis of the constituent in treated waste matrices. :
2. The constituent must be present in. or be suspected of being present
in, the untreated, waste. Analytical difficulties may prevent a
constituent from being identified in the untreated waste, but its
identification in a treatment residual may lead the Agency to
conclude that it is present in the untreated waste. .
From a group of constituents that are eligible for regulation because they
1 f ' '
meet the above criteria, EPA may select a subset of constituents that represents the
, , "' '
broader group. For example, from a group of constituents that react similarly to
treatment, the Agency may select for regulation those constituents that (1) are the most
difficult to treat, based on waste characteristics affecting treatment performance; (2) are
representative of other constituents in the waste, based on structural similarities; or (3)
are present in the untreated waste in the highest concentrations. Selecting a subset of
NRJ/NW-054
0603-ci .mj 5-1
-------
constituents for regulation is done to facilitate implementation of the compliance and
enforcement program.
The Agency acknowledges that in certain instances, compliance with the
BOAT treatment standards cannot be demonstrated due to analytical difficulties in the
analysis of certain wastes. In such instances, if the waste has been treated with a
''/
combustion BOAT process and an analytical sensitivity (i.e., detection limit) within an
order of magnitude of the treatment standard has been achieved, the Agency will
consider that compliance with the treatment standard for the respective constituents in
the waste has been demonstrated (14).
5.1 BOAT List Constituent Deleted from Further Consideration for Regulation
! r . '
(Pentachloroethane)
Initially, all organic constituents in the waste codes addressed in this
"
were considered by tne Agency tor regulation. However, during tne development ot tne
Third Third rule, pentachloroethane (a regulated constituent in K018, K028, and K030
which was originally included on the BDAT List of constituents) was removed from the
BDAT List of constituents due to analytical concerns. Therefore, the Agency is deleting
s- > ' .
pentachloroethane from further regulation in wastewater forms of K018, K028, and
K030.
5.2 BDAT List Constituents Selected for Regulation
j
.The Agency is revising the regulations for all of the organic constituents in
the wastewater forms of each waste selected for regulation during the First, Second, or
Third Third rules with the exceptions of pentachloroethane (discussed above) and benzal
chloride. As discussed in Section 1.0, the promulgated treatment standard for benzal
NRJ/NW-054 ;
, 5-2
-------
chloride in wastewater forms of K015 is not being revised. The constituents in the
wastes of concern selected for regulation are presented in Table 5-1;
NBI/NW454' -'.,
0603-01.nq 5-3
-------
Table 5-1
Regulated Constituents in
K015, K016, K018, K019, K020, K023
K024, K028, K030, K048, K049,
K050, K051, K052, K087, K093, K094,
U028, U069, U088, U102, U107, and
U190: Wastewater Organics
BDAT
List
Number
BDAT List
Constituent
Wastewater Forms of K015
57.
218.
63.
65.
141.
43.
AntlirqcCllG
Benzal Chloride
Benzo(b)Quoranthene
Benzo(k)fluoranthene
Phenanthrene
Toluene
Wastewater Forms of K018
12.
15.
22.
23.
110.
111.
45.
113.
Chloroetbane
Chioromethane
1,1-Dichloroethane
1,2-Dichloroethane *
Hexachlorobenzene
Hexachlorobutadiene
1,1,1-Trichloroethane
Hexachloroethane
Wastewater Forms of K020
23,
.41.
42,
1^-Dichloroethane
1,1,2^-Tetrachloroethane
Tetrachloroethene
BDAT
List
Number
BDAT List
Constituent '
Wastewater Forms of K016
110.
111.
112.
113.
42.
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Tetrachloroethene
Wastewater Forms of K019
68.
9.
14.
88.
23.
109.
113.
121.
141.
148.
42.
150.
45.
bis(2-Chloroeth)l)ether
Chlorobenzene
Chloroform .
p-Dichlorobenzene
1,2-Dichloroethane
Fluorene
Hexachloroethane
Naphthalene
Phenanthrene
1,2,4,5-Tetrachlorobenzene
Tetrachloroethene
1^,4-Trichlorobenzene
1,1,1-Trichloroethane
Wastewater Forms of E023
220.
Phthalic Anhydride (measured as '
phthalic acid)
NRJ/NW-054
0603-OIjq
5-4
-------
table 5-1
(Continued)
BDAT
List
Number
BDAT List
Constituent .
Wastewater Forms of K024
220.
-
. -
Phthalic Anhydride (measured as
phthalic acid)
f
. '
Wastewater Forms of K030 ' -
87.
88.
111.
113.
148.
42.
150.
o-Dichlorobenzene
p-Dichlorobenzene
Hexachlorobutadiene
Hexachloroethane
L2,4.5-Tetrachlorobenzene
Tetrachloroethene
1,2,4-Trichlorobenzene *
_
BDAT
List
Number
BDAT List
'' Constituent
Wastewater Forms of K028
22.
25.
111.
113.
40.
41.
42.
45.
46.
1,1-Dichldroethane
trans- 1^2-Dichlorocthene
Hexachlorobutadiene
Hexachloroethane '
l,l,lฃ-Tetrachlorpethane
l,L2,2-Tetrachloroethane
Tetrachloroethene :
1,1,1-Trichloroethane
l,L>Trichloroethane
Wastewater Forms of K048
4.
62.
70.
80.
, 98.
226.
109.
121.
141.
141
145.
43.
215-217.
Benzene
Benzo(a)pyrene
bis(2-EUiylhe]tyl) Phthalate
Chrysene
Di-n-butyl Phthalate
Ethylbenzene
Fluorene
Naphthalene
Phenanthrene
Phenol ' .
Pyrene
Toluene
Xylenes (total)
NRJ/NW-054
0603-01 .mj
5-5
-------
Table 5-1
(Continued)
BDAT
List
Number
BDAT List
Constituent
Wastewater Forms of K049
57.
4.
62.
. 70.
8.
80.
96.
226.
121.
141.
142.
, 145.
43.
215-217.
Anthracene
Benzene
Benzo(a)pyrene
bis(2-Ethyihexyi) Phthalate ,
Carbon Disulfide
Chrysene
2,4-Dimethylnhenol
Ethylbenzene
Naphthalene
Phenanthrene
Phenol
Pyrene
Toluene
Xylenes (total)
Wastewater Forms of K051
.52.
57.
59.
4..
62.
' 70.
80.
98.
226.
109.
121.
141.
142.
145.
43.
215-217.
, *
Acenaphthene
Anthracene -
Benz(a)anthracene
Benzene
Benzo(a)pyrene
bis(2-Ethylhetyl) Phthalate
Chrysene
Di-n-butyl Phthalate
Ethylbenzene
Fliibrene - " .
Naphthalene
Phenanthrene
Phenol. , -
Pyrene
Toluene
Xylenes (total)
BDAT
List
Number
-
62.
142.
-
'
BDAT List
Constituent
Wastewater Forms of K050
Benzo(a)pyrene
Phenol
<ป
t.
~
.'
Wastewater Forms of K052
4.
62.
81.
82.
96.
226.
121.
141.
142.
43.
215-217.
Benzene
Benzo(a)pyrene
o-Cresol
Cresol (m- and p-isomers)
2,4-Dimethylphenol
' Ethylbenzene
Naphthalene
Phenanthrene
Phenol
Toluene
Xylenes (total)
" *
NRJ/NW-054
0603-01 joj
5-6
-------
Table 5-1
(Continued)
BDAT
List
Number
BDAT List
Constituent
Wastewater Forms of K087
51.
4.
80.
108.
116.
121.
- 141.
43.
215-217.
Acenaphthalene
Benzene
Chrysene .
Fluoranthene
Indeno(l,23-cd)pyrene
Naphthalene ' , ,
Phenanthrene >
Toluene
Xylenes (total)
Wastewater Forms of K094
220.
Phthalic Anhydride (measured as
phthalic acid) ; '
Wastewater Forms of U069
98.
Di-n-butyl Phthalate
Wastewater Forms of U102
97.
Dimethyl Phthalate
Wastewater Forms of U190
220.
Phthalic Anhydride (measured as ,
phthalic acid) ,
BDAT
List
Number
BDAT List
Constituent
Wastewater Forms of K093
220.
Phthalic Anhydride (measured as
phthalic acid)
Wastewater Forms of U028
70.
bis(2-EthyIhexyl) Phthalate
Wastewater Forms of U088
92.
104.
Diethyi Phthalate
Wastewater Forms of U107
Di-n-octyl Phthalate
NRI/NW454
0603-Oi.BQ
5-7
-------
-------
6.0 AMENDMENT TO THE "CALCULATION OF BOAT TREATMENT
\ STANDARDS" SECTION OF THE FINAL BOAT BACKGROUND
DOCUMENTS FOR K01S, K016, K018, K019, K020, K023, K024, K028,
K030, K048, K049, K050, K051, K052, K087, K093, K094, U028, U069,
U088, U102, U107, AND U190: WASTEWATER ORGANICS
> i ''..'
' . . ' ' . .
This section supplements the discussion in Section 7.0 (Calculation of
BOAT Treatment Standards) of the following documents, unless stated otherwise:
i ' ' V. * ' ' '
Background Document for K015 (5);
Background Document for K016, K018, K019, K020, and K030 (6);
Background Document for Phthalate Waste (7);
Background Document for K024 (8);
Background Document for K028, K029, K095, and K096 (9);
, Background Document for K048, K049, K050, K051, and K052 (10);
and - . : ,
Background Document for K087 (11).
1 . > -
N ' '
The calculation of the revised treatment standards for each BDAT List
constituent regulated in the wastes of interest are shown in Table 6-1. The BDAT '
treatment standards were calculated by multiplying the average long-term effluent
concentration for each constituent by an accuracy correction factor (ACF) and a
variability factor (VF), if applicable. The long term effluent concentration Values are
* . '
those shown in the appropriate tables in Appendix A. The accuracy correction factors
and variability factors for each constituent were determined as described below.
NRI/NW-OS4
0603-01 jปq . 6-1
-------
6.1 Accuracy Correction Factors . '
Accuracy correction factors account for analytical interferences associated
with the chemical matrices of the samples. The accuracy correction factor is
incorporated into the determination of treatment standards by multiplying it (and a
variability factor when appropriate) by the constituent's detection limit An accuracy
correction factor was determined for each of the constituents by dividing 100 by the
matrix spike recovery (percent) for each constituent
The matrix spike recoveries are developed by analyzing a sample of a
treated waste for a constituent and then re-analyzing the sample after the addition of a
known amount of the same constituent (i.e., spike) to the sample. The matrix spike
recovery represents the total amount of constituent recovered after spiking, minus the
initial concentration of the constituent in the sample, and the result divided by the spike
concentration of. the constituent Duplicate matrix spikes were performed for some
BDAT List constituents. If a duplicate matrix spike was performed for a constituent, the
matrix spike recovery used for that constituent was the lower of the two values between
s
the first matrix spike and the duplicate spike., ,
i .. .
An accuracy correction factor of 1.00 was used when both the matrix spike
and duplicate matrix spike recoveries exceeded 100 percent, so that the data were not
adjusted to concentrations below the detection limits. Matrix spike values of less than 20
percent are not acceptable and were not used to correct detection limits, nor included in
calculating average matrix spike recoveries.
..,- ~ ป
BAD variability factors already contain accuracy correction measures.
. Therefore, to avoid over-correcting the data, accuracy correction factors were not used in
cases where HAD variability factors, were used. In cases where an HAD variability factor
was not used, an accuracy correction factor was determined as described above and
included in the treatment standard calculation. '
NW/NW-OS4
0603-01-mj . . 6-2
-------
As described above, matrix spike recovery data are routinely used in
determining accuracy correction factors; however, these data were not available for most
of the treatment performance data examined. Consequently, matrix spike data were
pooled from BDAT and leachate data sources. Leachate matrix spike data were used to
determine an accuracy correction factor in cases where leachate treatment performance
data were used to establish a treatment standard; BDAT matrix spike data were used in
all other cases. Where an accuracy correction factor was not available for a specific
constituent, an average accuracy correction factor was determined, as presented in
Tables 6-4 through 6-8.
62 Variability Factors
A variability factor accounts for the variability inherent in treatment system
performance, treatment residual collection, and analysis of the treated waste samples.
Variability factors are calculated as described in EPA's Methodology for Developing
BDAT Treatment Standards (2): '<.'
Original effluent data points were not always available. Therefore,
variability factors for some constituents were not calculated as described in Reference 2.
For example, effluent data hi the WERL database were presented as averages; since
actual effluent data points were not available, it was not possible to calculate a
variability factor specific to each of these constituents. - , .
The variability factor calculated during the EAD regulation effort was used
for those constituents for which a treatment standard was based on an EAD effluent
limitation (i.e., selected volatile and semivolatile organics). . \ .
One of two options was used for constituents where a variability factor was
unknown or could not be calculated:
NRJ/NW-054 '
0603-Ol.otj 6-3
-------
(1) Use of average variability factors that were generated from the
EAD variability factors and were specific to the type of constituent
under consideration. The average volatile organic variability factor
is an average of the volatile organic variability factors from EAD
data as presented in Table 6-2. The average semivolatile organic
variability factors are averages of the semivolatile organic variability
factors from EAD data as presented in Table 6-3. The procedure
for determination of these average variability factors was similar to
. the procedures used by EPA hi previous Land Disposal Restrictions
rulemakings to determine average accuracy correction factors.
(2) Use of a variability factor of 2.8 for constituents that were not
volatile or semivolatile organics. A variability factor of 2.8 was used
to calculate treatment standards for constituents for which the long-
' . . term average effluent concentration was based on detection limits
only. This variability factor has been used by EPA in past Land
Disposal Restrictions rulemakings where variability factors could not
be calculated. , ~
63 Calculation of Revised BDAT Treatment Standards
The calculation of .BDAT treatment standards involves three steps: .(1)
accuracy correction of the treatment performance data to account for analytical
interferences with the chemical make-up of the samples; (2) determination of a
variability factor, specific to each constituent, to correct for normal variations in the
performance of a treatment technology; and (3) calculation of the treatment standard,
which is equal to the average effluent concentration multiplied by the accuracy correc-
tion factor and the variability factor. .
NRJ/NW-054
0603-01 Jiij .6-4
-------
Table 6-1
CALCULATION OF BOAT TREATMENT STANDARDS FOR
ORGANIC CONSTITUENTS REGULATED IN WASTEWATER FORMS OF:
K015, K016, K018, K019, K020, K023, K024, K028, K030,
K048, K049, K050, K051, K052, K087, K093, K094, U028,
U069, UQ88, U102, U107, AND U190
BOAT
Li* .
. . Number
51.
52.
57.
59.
4.
62.
63.
65.
68.
' TO.
8.
9. '
12.
14.
15.
80.
81.
82.
87.
88.
. 22.
23.
25. ,
92.
96. ..
97.
98.
104.
.226.
108. '
109.
110.
111.
. BDATUat
Constituent!
Acewphthaleoe
Acenaphthene
Anthracene ' i
Benz(a)aiithnceoe
Benzene
Benzo(a)pyreiie '
Benzo(b){luorantheae
Benzo(k)fluonnthene
Bii(2-chlon>ethyl)ether
Bii(2-ethylbexyl)phthalate .
"
Carbon Diaulfide
Chiorobenzene . . ,
Chloroethane
Chloroform
Chloromethane
Chiyiene . .
o-Creaol ' ' -
m/p-Cre*ol \
o-Dichlorobenzene " - '"
p-Dichlorobenzene .
1,1-Dichloroethaite
1,2-DichloroethaAe
tnni-l,2-Dichlotoethene
Dietbyl Phthalate
2,4-Dimethylphenol
Dimethyl Phthalate -
Di-D-butyl Phthalate
Di-n-octy 1 Phthalate
Ethyl Unatmn
Fhioranthene
Fluorene .
Hexachlorobenzene '
HexacUorotnitadiene .
Long-Term
Average
Effluent ป
CoocmtntioQ
(ppm) x
0.010
0,010
0.010
0.010
0.010 :
0.0103
0.010
0.010
0.006
0.047
. s- \-
0.0050
0.010 .
0.050
0.0122
0.050
0.010
0.025
0.174
0.016
0.01633
0.010
0.0256
0.010
0.0425
0.010794
0.010 k
0.017606
0.0030
0.010
0.011533
0.010
0.010
0.010
Factor x
5.9
5.9
5.9
5.9
14
5.9
5J
5.9
5.5 '
$.9
2.8
5.7
53
3.7
3.8
5.9
4.4" '
4.4
. 5.5
5.5
5.9
t3.
S3
4.8
33
4.6
3 j
5J
5.7
5.9
. 5.9
5.5
5J
^
Accuracy
Correction
. : Factor "
NA
NA
NA
NA
NA
NA
NA
NA
NA
i r+f\-
1.0
NA
NA
NA
NA
NA
1 NA
NA
NA
. NA
NA
NA
NA
NA
- NA
NA
NA
NA
NA
* NA
NA .
NA
NA
BD AT Treatment
Standard
0.059
0.059 ^
0.059
0.059
0.14
0.061
0.055 .".
0.059
0.033
*
0.014 '
0.057
0.27
0.046
0.19
,0.059 .
0.11
0.77
0.088
0.090
0.059
0.21
0.054
OJO
0.036
0.047
0.057
0.017
1
0.057
0.068
0.059
0.055
x 0.055
NA - Not Applicable.
NRJ/NW-054
0603-01.taj
6-5
-------
I
^
BDAT
List
Number
112.
113.
116.
121.
141. ,
142.
220.
145.
148;
40.
41.
42.
43.
150.
45.
. 46.
- , '
*
i '
*
. BDATLut ,
Contthuentt
Hexachlorocyclopeotadiene
HexacbJoroethane
Indeao(l,2,3-ed)pyrene
Naphthalene
Pheninmreno
Phenol ' . '
Phthalic Anhydride x
Pyrene
1^,4,5-Tetrachlorobenzene .
1,1,1 ,2-TetrachIotoethane
1 ,1 ,2,2-Tettichloroethane
Tetttchknoethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-TricbJoroethuxi
1,1^-TricUoroeduae
Table 6-1
(Continued)
Long-Tenn
Avenge
Effluent
Concentration
(ppm) it
, 0.01026
0.010
* 0.0010
0.010
0.010
0.010
0.015
0.01133
0.010
0.010
0.010
0.0104
0.010
0.010
0.010
0.010
Variability
Factor x
5.5
5.5
V t
5.9
5.9
2.8
2.8
5.9
5J
5.7
5.7
5J
8.0
5.5
5.3
5.3
. .
Accuracy
Comction
Factor
NA
NA
NA
NA
NA
1.4
1.6
NA
NA
NA
NA
NNA
NA
NA
NA
NA
s
'
BDAT Treatment
Standard
(PPM)
0.057
0.055
0.0055
0.059
0.059
0.039
0.069
0.067
0.055
0.057
0^57
0.056
0.080
0.055
0.054
0.054
215.
Xyleoe* (total)
0.056
5.7
NA
052
NA-Not Applicable.
Note:
Due to apace conatratnti, variability ftcton were expreued here with only two ngmficant figures. For
vahiea, aee Tablet 6.2 and 6.3 of thi* document.
detailed
NRJ/NW-054
6-6
-------
Table 6-2
Variability Factors for Volatile Organics
Constituent ' HAD Variability Factor
Aoylonitrile 4.83045
Benzene . . 13.5252
Chloroethane '..''" 534808
Chloroform 3.71334
Chloromethane , 3.79125
1,1-Dichloroethane 5.88383
1,2-Dichloroethane 8.22387
1,1-Dichlorocthene 2.4723
trans-l^-Dichlorocthcne . 534808
Methylene Chloride ^ , 3A5915
Tetrachloroethylene . ' * 534808
Toluene 7.9506
W-TricMoroethane 534808
W-TricMoroethane 534808
Trichloroethylene 534808 .
Vinyl Chloride , 534808
~< Average Variability Factor (Volatile Organics) 5.7310
NRJ/NW-054 .
0603-01 .nrj ' .6-7
-------
Table 6-3
Variability Factors for Semivolatile Organics
Constituent
BAD Variability Factor
ACID EXTRACTABLES
2,4-Dimethylphenol .-.'.' 32565
2,4-Dinitro-o-cresol 115417
2,4-Dinitrophenol - . . , 2.45842
4-Nitrophenol . . v . 2.47783
Phenol 2.49705
f -
Average Variability Factor (Acid Extractable Semivolatiles) 4.4463
BASE/NEUTRAL EXTRACTABLES
Acenaphthalene 5.89125
Acenaphthene . . 5.89125
Anthracene - 5.89125
Benzo(a)anthracene , 5^9125
Benzo(a)pyrene . ' - ' 5.89125
Benzo(k)fluoranthene .5.89125
bis(2-Ethylhexyl) Phthalate 5.91768
' Chiysene . 5^9125
Diethyl Phthalate 4.75961
Dimethyl Phthalate 4.63833
/ Di-n-butyl Phthalate 3-23768
Fluoranthene . 5.89125
Fluorene 5.89125
Naphthalene 5^9125
Nitrobenzene 453045
Phenanthrene 5^9125
Pyrene 5.89125
Average Variability Factor (Base/Neutral Extractable Semivolatiles) 53340
NRJ/NW-054
0603-01 Ottj
6-8
-------
Table 6-4
\
Determination of Accuracy Correction Factors for
Volatile Organics - EPA Data
Percent Recovery
Volatile Organic ~ - Low
Constituent WAO A WAO B K103/K104 Value ACT*
n-Butanol .
Isobutanol
Methanol .
3-Chloropropionitrile
1,4-Dioxane
2-Ethoxyethanol
Ethyiene Oxide
Methacrylonitrile
Trichlorocthene
1,1-pichlordethene
Benzene
Chlorobenzene
Toluene
82 94
97 92
93 88
159 171
152 153
157 172
103 37
150 158
87 89
108 110
165 190
98 110
84 93
102 89
99 85
167 182
155 153
161 161
50 22
. 165 169
.87 88
120 120
110 120
88 90
87 90
. /
j
' i '
76 74
L
82
89
85
159
152
157
22
150
.87
108
76
88
87
12
1.1
12
W
1.0
LO
4.6
1.0
12
1.0
1ฃ
1.1
12
Average Percent Recovery = 103.23
I00%r
ACF for Volatile Organics - 100/100 = 1.0"
Notes:'. ' ' ^ > ' .- .. ...'''.', '" ' ' '
! - ' ' ' / -
. If Percent Recovery is less than 20%, that value is dropped from consideration.
If Percent Recovery is greater than 100%, then the recovery used is set at 100, to prevent adjustment of data
below detection limits.
*To determine an Accuracy Correction Factor (ACF), the average of the lowest values for each volatile
organic constituent is calculated. ACF = 100/avg. low value.
WAO A = Percent recovery data from the wet air oxidation test on waste mixture A.
WAO B = Percent recovery data from the wet air oxidation test on waste mixture B.
* ^-_ L
' " - - * *'
K103/K104 - Percent recovery data from the K103/K104 treatment performance test
NW/NW-054
0603-01 Jnj
6-9
-------
Table 6-5
Determination of Accuracy Correction Factors for
Semivolatile Organics - EPA Data
Percent Recovery
- ' ' : . '. - : LOW '
Semivolatile Organic Constituent - WAOA WAO B K103/K104 Value ACP
Acid Extractables
p-Chloro-m-cresol
2-Chlorophenol
Pentachlorophenol
4-Nitrophenol
Phenol
21 12
55 55
68 82
20 13
94 82
58
55
0
43
42
' \
21 26
21
55
68
20
21
4.8
1*
13
5.0
4.8
Average Percent Recovery 37
Acid Neutral Semivolatiles ACT = 100/37 = 2.7
Base Neutral Extractables
Acenaphthene
1,4-Dichlorobenzene
2,4-Dinitrotoiuene
N-Nitroso-di-n-propylamine
Pyrene
1,2,4-TricbJorobenzene
Nitrobenzene
Aniline
72 86
65 74
78 - 112
79 92
68 67
,73 87
'
79
52
69
51
84 s
61
.
i
115 116
91 97
72
52
69
51
67
61
115
91
14
1.9
15
2.0
- 1.5
1.6
1.0
1.1.
Base Neutral Extractable Semivolatilcs ACT - 100/723 - 138*
Notes: , v
If Percent Recovery is less than 20%, that value is dropped from consideration.
If Percent Recovery is greater, than 100%, then the recovery used is 100, to prevent adjustment of data below
detection limits. . . .
To determine an Accuracy Correction Factor (ACT), the average of the lowest values for each Semivolatile
organic constituent is .calculated. ACT = 100/avg. low value.
WAO A = Percent recovery data from the wet air oxidation 'test on waste mixture A.
WAO B = Percent recovery data from the wet air oxidation test on waste mixture B.
K103/K104 = Percent recovery data from the K103/K104 treatment performance test
NRJ/NW-054
0603-01 JHJ
6-10
-------
Table 6-6
Determination of Accuracy Correction Factors for
Volatile Organics - Industry-Submitted (Dow) Leachate Data
Percent Recovery
Volatile Matrix Matrix Spike Low . .
Constituent Spike Duplicate Value ACF*'
Methanol
Isobutyl Alcohol
n-Butyl Alcohol
1,1-Dichloroethene
Tridtloroethene . .
. Chlorobenzene ' ,
Toluene"
Benzene
100
101
105
130
94
98
100
94
100
101
99
132
94
96
100
94
100
101
99
130
94
96
100
94
j
1.0
1.0
1.01,
1.0
1.06
1.04
1.0
1.06
Volatile ACT -
' .
100/100 - 100"
Average
< Set At ,
, '
101.75
KKT
Notes:
If Percent Recovery is less than 20%, that value is dropped from consideration.
"if Percent Recovery is greater than 100%, then the recovery used is 100, to prevent adjustment of data:
below detection limits.
. ' . -i
To determine an Accuracy Correction Factor (ACF), the average of .the lowest values for each volatile
organic constituent is calculated. ACF = 100/avg. low value.
NRJ/NW-OS4
0603-01 .mj
6-11
-------
Table 6-7
Determination of Accuracy Correction Factors for
Volatile Organics - Industry-Submitted (CWM) Leachate Data
Volatile Constituent Percent Recovery ; ACS*
Acetone
n-Butyi Alcohol
Isobutyl Alcohol
Methyl Ethyl Ketone
Methanol
Methyl Isobutyl Ketone
99
112
112
99
112
99
1.01
IS)
10
1.01
1.0
1.01
Average Percent Recovery 105.5 *
Set At 100T
Volatile ACF - 100/100 = 1.00* '_..':
Notes: ' , ' " . . . : . . '
If Percent Recovery is .less than 20%, that value is dropped from consideration.
If Percent Recovery is greater than 100%, then the recovery used is 100, to prevent adjustment of data
below detection limits. " .
To determine an Accuracy Correction Factor (ACF), the average of the lowest values for each volatile
organic constituent is calculated. ACF = 100/avg. low value. . .
NRJ/NW-054
0603-01 jnj
6-12
-------
Table 6-8
I "S.
Determination of Accuracy Correction Factors for
Semivolatile Organics - Industry-Submitted (Dow) Leachate Data
Percent Recovery
Matrix Matrix Spike Low
Semivolatile Constituent Spike Duplicate Value . ACP
Acid Ffrtractables
Pentachlorophenol
Phenol
2-Chlorophenol
p-Chloro-m-cresol
4-Nitrophenol
L
' , V ' '
79
71
72
79
109
"*
83
74
73
84-
100
-
79
71
72
79
100
-
13
1.4
1.4
13
'10
Average
Acid Extractable Semivolatiies ACF - 100/802 - 125*
802
'Base Neutral
Extractables
12,4-Trichlorobenzene
Acenaphthene
2,4-Dinitrotoluene
Pyrene
N-Nitroso-n-propylamine
1,4-Dichlorobenzene
Base Neutral Extractable
80
81
84
87
60
74
.' ' ' : *
Semivolatiies ACF =
89 .-,
86
83
105
65
82
Average
100/773 - 129*
, *
80
81
83
87
60
74
773
' .
13
12
12
1.1
1.7
.1.4
1
Notes:. ' . , -_. ',., ,
If Percent Recovery is less than 20%, that value is dropped from consideration. .
If Percent Recovery is greater than 100%, then the recovery used is 100, to prevent adjustment of data below
detection limits. : .
To determine an Accuracy Correction Factor (ACF), the average of the lowest values for each Semivolatile
organic constituent is calculated. ACF - 100/avg. low value.
NRJ/NW-054
0603-Ol.fflj
6-13
-------
-------
7.0 ACKNOWLEDGEMENTS
' ' "* " . '
Technical support for the development of this background document was
provided for the United States Environmental Protection Agency, Office of Solid Waste,
by Radian Corporation under Contract No. 68-W9-0072. This document was prepared -
under the direction of Richard Kinch, Chief, Waste Treatment Branch; Larry
Rosengrant, Section Head, Treatment Technology Section; Angela Wilkes, Project
Officer; and Anita Cummings, Project Manager. Steve Silvennan served as EPA legal '
advisor. , , . s .
* * ^ *
/
. The following personnel from Radian Corporation who supported the
development of this document were: Thomas Ferguson, Program Manager; Mary
, ' r-
Willett, Project Director; and the Radian engineering team, Chrisanti Haretos, Kurt
Rindfusz, and Robert Shark. ; .
NRJ/NW-054
0603-01 .mj 7-1
-------
-------
8.0 REFERENCES
1. American Public Health Association, American Water Works Association,
and Water Pollution Control Federation. Standard Methods for
Examination of Water and Wastewater (Sixteenth Edition). Washington,
DC, 1985. x .-''"'
2. U.S. Environmental Protection'Agency, Office of Solid Waste. .
Methodology for Developing BDAT Treatment Standards. Washington,
DC, June 1989.
.3. U.S. Environmental Protection Agency, Office of Solid Wasted Final Best
Demonstrated Available Technology (BDAT) Background Document for U
and P Wastes and Multi-Source Leachate (FQ39V Volume A: Wastewater
Forms of Organic U and P Wastes and Multi-Source Leachate:JF039) for
which there are Concentration-Based Treatment Standards. Washington,
DC, 1990. .
4. U.S. Environmental Protection Agency, Office of Solid Waste. Treatment
' Technology Background Document. Washington, DC, June 1989.
^ 5. U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated Available Technology (BDAT) Background Document for
K015. Washington, DC, August 1988. ,
6. U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated.Available Technology (BDAT) Background Document for .
K016. K018. K019. K020. and K030. Washington, DC, August 1988.
7. U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
v Demonstrated Available Technology (BDAT) Background Document for
Phthalate Wastes. Washington, DC, May 1989.
8. U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated Available Technology (BDAT) Background Document for
K024. Washington, DC, August 1988.
9. U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated Available Technology (BDAT) Background Document for
Wastes from the Production of 1.1.1-Trichloroethane: K028. K029. K095.
and K096. Washington, DC, May 1989.
NW/NW-054
0603-01.nrj 8-1
-------
10.
11.
12.
13.
14.
U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated Available Technology (BDAT) Background Document for
K048. K049. K050. K051. and K052. Washington, DC, August 1988. -
U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated Available Technology (BDAT) Background Document for
K087. Washington, DC, August 1988.
U.S. Environmental Protection Agency, Office of Solid Waste. Final Best
Demonstrated Available Technology (BDAT) Background Document for
F001-F005 Spent Solvents. Volume 2. Washington, DC, 1986.
U.S. Environmental Protection Agency, Office of Water Regulations and
Standards. Development Document for Effluent Limitations Guidelines
New Source Performance Standards and Pretreatment Standards for the
Organic Chemicals and the Plastics and Synthetic Fibers Point Source
Category (Volumes I and II). Washington, DC, 1987.
U.S. Environmental Protection Agency. Federal Register (Volume 55).
U.S. Environmental Protection Agency. Washington, D.C.: June 1, 19901
p. 22541. . -
NRJ/NW-OS4
0603-01.nij
8-2
-------
Appendix A .
TREATMENT PERFORMANCE DATA
FOR CONSTITUENTS REGULATED IN
K015, K016, K018, K019, K020, K023, K024,
K028, K030, K048, K049, K050, K051,
K052, K087, K093, K094, U028, U069,
UQ88, U1Q2, U107, AND U190
BIO-40NW
A-l
-------
Table A-l
Index for Appendix A
Constituent
Acenaphthalene
Acenaphthene
Anthracene
A-7
A-9
A-ll
Benz(a)anthracene
Benzene
Benzo(a)pyrene
A-13
A-15
A-18
Benzo(b)fluoranthene
Benzo(k)fluoranthene
bis(2-Chloroethyl) Ether
A-20
A-22
A-24
bis(2-EthyIhexyl) Phthalate
Carbon Disulfide
Chlorobenzene
A-26
A-28
A-30
Chloroethane
Chloroform
Chloromethane
A-32
A-34
A-37
Chrysene ,
o-Cresol ;
Cresol (m- and p-isomers)
A-39
A-41
A43
o-Dichlorobenzene
p-Dichlorobenzene
1,1-Dichloroethane
A-45
A-47
A-49
1,2-Dichloroethane
trans-l^-Dichloroethene
Diethyl Phthalate
A-51
A-53
A-55
2,4-Dimethylphenol
Dimethyl Phthalate
Di-n-butyl Phthalate
A-57
A-59
A-61
Di-n-octyl Phthalate
Ethylbenzene
Fluoranthene
A-63
A-65
A-68
BICMONW
0322-OIJ>jg-2
A-2
-------
Table A-l (Continued)
Index for Appendix A
Constituent
Fluorene , .
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(l,23-cd) Pyrene
Naphthalene
Phenanthrene
Phenol
Phthalic Anhydride .
Pyrene
1,2,4,5-Tetrachlorobenzene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane . '
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1, 1^-Trichloroethane
Xylenes (total)
Page
A-70
A-72
A-74
A-76
, , A-78
A-80
A-82
A-84
A-86
A-90
A-92
A-94
A-96
A-98
A-100
A-103
A-107
A-109
A-112
A-114
BJO-40NW
0322-OI.bjgJ
A-3
-------
Table A-2
Database Key
Code
BDAT
BAD
NPDES
WAO
WERL
OCPSF
LEACHATE
Database
Best Demonstrated Available Technology
Engineering and Analysis Division (formerly ~
Industrial Technology Division)
National Pollutant Discharge Elimination System
Wet Air Oxidation
Water Engineering Research Laboratory
Organic Chemicals, Plastics, and Synthetic Fibers
Data Submitted by Industry
BKMQNW
Q322-OUปjs.4
A-4
-------
Table A-3
Key to Treatment Technologies
Code
AC
AFF
AL
API,
AS
AirS
, AnFF
BGAC
BT
CAC
ChOx
Chred
DAF
Fil
GAC
KPEG
LL
PACT
RBC
RO
SCQx
SExt
SS
Technology
Activated Carbon
Aerobic Fixed Film ,
Aerobic Lagoons . '
API Oil/Water Separator
Activated Sludge
Air Stripping '
Anaerobic Fixed Film !
Biological Granular Activated Carbon
Biological Treatment
Chemically Assisted Clarification
Chemical Oxidation .
Chemical Reduction /
Dissolved Air Flotation
Filtration .
Granular Activated Carbon ,
Dechlorination Using Alkoxide . . , .
Liquid-Liquid Extraction
Powdered Activated Carbon Addition to Activated Sludge
Rotating Biological Contactor
Reverse Osmosis
Super Critical Oxidation
Solvent Extraction
Steam Stripping
BKMONW
03224)1 .bjf.5
A-5
-------
Table A-3 (Continued)
Key to Treatment Technologies
ฃs<|e
TF
UF
UV
WQx
Technology
Trickling Filter
Ultrafiltration
Ultraviolet Radiation
Wet Air Oxidation
" + " - Indicates that the first process unit .is followed in the process train by the
second, i.e., AS + Fil - Activated Sludge followed by Filtration.
"__w + __" Indicates that the two units are used together, i.e., UFwPAC - . .
Ultrafiltration using Powdered Activated Carbon.
" [B]* - Indicates batch instead of continuous flow. .
BJG-WNW
0322-01 .fcjg .6
A-6
-------
Acenaohthalene. The data available for acenaphthalene were compiled
from the BAD and WERL databases. These data are presented in Table A-4.
Technologies for which treatment performance data are available include AL, AS,
AS+Fil, and BT. All of the treatment performance data represent full-scale studies.
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
\ ...''
. (1) The HAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by HAD include
, long-term sampling of several industries; therefore, the Agency
(./' believes these data are representative of the total organic chemical
. . _ ' industry and can adequately represent a wastewater of unknown
characteristics. .
(2) The BAD data were carefully screened prior to inclusion in the
OGPSF database. These data were used in determining
, .. promulgated BAD limit. _ "
, (3) A promulgated BAD limit represents data that have undergone
': further review, and have received acceptance by both EPA and
. 'industry.
BDAT for acenaphthalene is being revised to BT (biological treatment).
The revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 10 ppb and the BAD Option 1 variability factor. The
.calculation of the resulting BDAT treatment standard for acenaphthalene (0.059 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BIO-40NW
0322-01-bjg.7 A-7
-------
TABLEAU
-.
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ACENAPHTHALENE
TECHNOLOGY
TECHNOLOGY
SIZE -
FAaUTY
RANGE
DETECTION MFLUENT NO. OF
UMTT -, CONCENTRATION DATA
(ppb) (ppb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVERY REMOVAL
fit) Ok) REFERENCE
At
AS
AS+FU
BT
Fidt
Fid
Fid
fvB
1283
10
100-1000
100-1000
1000-10000-
101-1
3
13
3
IS
10.000
10.000
13.000
10.000
96.4 WERL-
07.9 WERL
99.67 WERL
EAD*
' Data UMd In dwmtoping raviMd Undard.
A-8
-------
Acenaphthene. The data available for acenaphthene were compiled from
the EAD and WERL databases, as well as WAO data from literature, these data are
presented in Table A-5. Technologies for .which treatment performance data are
available include AS, AS+Fil, CAC, BT, PACT*, TF, and WOx. The treatment
'" '
performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the EAD database were
used to determine the revised BDAT treatment standard for this constituent for the .
f ' ป
following reasons: . .
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency ,
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. .
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit. , ,
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. ,
BDAT for acenaphthene is being revised to BT (biological treatment).
The revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 10 ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for acenaphthene (0.059 ppm) is
' ' ' " '
described in Section 6.0 and is shown in Table 6-1. ;
BJO-40NW
0322-01-bjg.9 , . A-9
-------
' ". . _ ' TABLEAU . __ .
WASTEWATER TREATMENT PERFORMANCE DATA
FORACENAPHTHENE
DETECTION
TECHNOLOGY UMfT
TECHNOLOGY SIZE , FACILITY (ppb)
RANQE
INFLUENT.
CONCENTRATION
(ppb)
AVERAGE
NO. OF EFFLUENT
DATA CONCENTRATION RECOVERY REMOVAL
POINTS (ppb) At) (%) REFERENCE
AS
AS
AS
AS
AS
AS+FB
CAC
Ffl
BT
PACT
TF
WOx
WOxtBJ
Full
PwOt
Full
Full
Full
Full
Pilot
Full
Full
Full
97SB
204A
68
2018
68
6B
185B
T92E
1283
9738
1B
Zbnpra
236A
10
0-100
0*100
0*100
100-1000
100-1000
1000-10000
0-100
0-100
513-1516
0-100
7000000
> 1000000
8
7
3
13
3
8.
'4'
15
4
1
1
1200
10.000
1.000
laooo
13.000
10.000
2.000
10.000
4.000
6.000
500.000
2800.000
77
87
90
98.44
96.9
99.66
67
83
90
86
99.09
89.96
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
EAD*
WERL
WERL
WAO
WERL
1 Data u*ed hi developing revised ttandani
A-10
-------
Anthracene. The data available for anthracene were compiled from the
BAD and WERL databases. These data are presented hi Table A-6. Technologies for
which treatment performance data are available include AS, AS+Fil, BT, and TF. The
treatment performance data represent pilot- and full-scale studies.
, , v .
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
, believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. .
' t . -. , ;.'
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a -
promulgated EAD limit. ,
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
' ' industry. .
BDAT for anthracene is being revised to BT (biological treatment). The
revised BDAT treatment standard was calculated using the EAD median long-term
'.- '
average effluent value of 10 ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for anthracene (0.059 ppm) is
described in Section 6.0 and is shown in Table 6-1. .
BKMONW
0322-01 Jdf.Il'
A-ll
-------
TABLEAU ' v
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ANTHRACENE
*'
TECHNOLOGY
AS
AS
AS
AS+FD
FH
BT
TF
TECHNOLOGY
SIZE
Fun
Full
Pilot
Full
Full
FuH
Fun
DhlbdkGri
> UMTT
FACILITY (DDbl
6B
IB
8MA
68
782E
1283 10
IB .
RANGE
MFLUENT
CONCENTRATION
(rob)
100-1000
0-100
0-100
1000-10000
0-100
418443 ' .
100-1000
NO. OF;
DATA
POINTS
14
4
.
9
a'
16
6'
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
10.000
13.000
0.900
10.000
1.000
10.000
17.000
RECOVERY REMOVAL
(K) <%)
88.6 '
82
9TA
88.82
872
82.3
REFERENCE
WERL
WERL
WERL
WERL
WERL
EAD*
WERL
* Data used In developing revised ctandwd.
A-12
-------
Benz(a)anthraceng. Tie data available for benz(a)anthracene were
compiled from the BAD and WERL databases. TTiese data are presented in Table A-7.
Technologies for which treatment performance data are available include AS, AS+FQ,
and BT. The treatment performance data represent pilot- and full-scale studies.
' " 'i '
The treatment performance data available from the EAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. ' .
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD Uniit.
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. . ' ,.- '
BDAT for benz(a)anthracene is being revised to BT (biological
treatment). The revised BDAT treatment standard was calculated using the EAD
median long-term average effluent value of 10 ppb and the EAD Option 1 variability
factor. The calculation of the resulting BDAT treatment standard for benz(a)anthracene
(0.059 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJG-40NW
0322-01 Ajg. 13 A-13
-------
TABLE A-7
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZftANTHRACENE
TECHNOLOGY
TECHNOLOGY
SIZE
FACtUTY
RANGE
DETECTION WFLUENT NO. OF
UMIT CONCENTRATION DATA
fepb) . ftปM POINTS
AVERAGE
EFFLUENT
CONCENTRATION
tepbl
RECOVERY REMOVAL
(Kl fltt REFERENCE
AS
AS
AS
AS+FI
Fll
*BT
FuR
Pilot
Full
Full
FuU
Full
201B
204A
792E
12B3
10
0-100
0-100
100-1000
1000-10000
1000-10000
10414
1
.6
12
3 '
'4
15
1.000
0.600
10.000
56.000
3.000
10.000
98.3
97.S
V*
96.5
99.75
tUCttl
WCnL
WERL
WERL
WERL
WERL
EAD*
Data uted In davttoplng nwiMd ttwidwd.
A-14
-------
. Benzene. Hie data available for benzene were compiled from the HAD,
BDAT, and WERL databases, as well as PACT* data from literature. These data are
presented in Table A-8. Technologies for which treatment performance data are
available include ALป AL+AS, API+DAF+AS, AS, AS+Fil, AirS, AirS+GAC, GAC,
LLป LL+SS+AC, PACT* RO, SS, TF, TF+AS, and WQx. The treatment performance
data represent bench- and full-scale studies. '
i f . i ' ,
The treatment performance data available from the EAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit.
(3) '' A promulgated EAD Limit represents data that have undergone
further review, land have received acceptance by both EPA and
industry. :
BDAT for benzene is being revised to SS (steam stripping). The revised
BDAT treatment standard was calculated using the EAD median long-term average
effluent value of 10 ppb and the EAD Option 1 variability factor. The calculation of the
resulting BDAT treatment standard for benzene (0.14 ppm) is described in Section 6.0
and is shown in Table 6-1.
BKMONW . / . '
0322-oi.bjg.is ; . ; A-15
-------
TABLE A-8
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZENE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
, RANGE
DETECTION MFLUENT NO. OF
UMTT CONCENTRATION DATA
(ppb) (ppb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVERY REMOVAL
fit) fit) REFERENCE
AL
AL
AL
AL
AL+AS
API+QAF+AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS+FB
AirS
AlrS
AirS '
AirS
AirS
AlrS+GAC
Bwwh
Full
Full
Full
Full
FuH
Full
Bench
Full
FuH
Full
Fun
Full
Full
Bwwh
Full
Full
Full
Full
Bwwh
FuD
Full
Full
Full
Pilot
Full
FuU
Bwwh
Full
PDot
FuU
Not
Full
371 D
6B
IB
6B
233D
1482D
6B
2MB
2MB
1B
6B
1B
6B
6B
1B
6B
68
200B
68
234A
201B
18
206B
234A
6B
1328E
224B
322B
1362E
229A
1000-10000
100-1000
100-1000
100-1000
.10000-100000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
. 100-1000
JKMOOO
100000-1000000
1000-10000
1000-10000
1000-10000
. 0-100
0-100
10000-100000
100-1000
0-100
0-100
0-100
0-100
100000-1000000
10000-100000
100-1000
100-1000
1000-10000
100-1000
0-100
2
6
2
21
4
7
16
6
6 .
22
6
14
3
6
'8
27
3-
26
16
15
10
6
'22
1
10
3
19
60.000
10.000
10.000
10.000
13.000
3.700
10400
0.800
1.000
2.000
30.000
14)00
10.000
10.000
2.000
40.000
10.000
11.000
10.000
10.000
0.900
10.000
0.600
6.000
16.000
0200
0.700
20.000
6300.000
0.440
0.500
52.000
1.000
1.000
86
96.9
84.4
82.3
8946
99.63
99
81.7
99.55
86.7
85.6
96J
8947
89.09
894
89.71
89.6
87.8
89.97
89.63
81
64
89.73
87.4
.WERL
WERL
, WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
90
89.74
8947
86.7
89.09
904
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
A-16
-------
TABLE Aซ (Continued) . . > ^
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZENE
RANGE
, . DETECTION MFLUENT
TECHNOLOGY UMTT CONCENTRATION
TECHNOLOGY SIZE FAOUTY (Mb) tepfa)
QAC
, LL
LL
LL+SS ,
, LL+SS+AC
PACT
PACT
. PACT
PACT
RO
RO
RO
RO
RO
SS
88
88 '
"SS
SS
SS
88
SS
88
ป
WOx
WOx[B]
WOx[B]
Full
Full.
Full
Full
FuU
Bench .
Bench .
- Bench
Bench
Full
Full
Pilot
Pilot
Full
FuU
FuU
Fun
. Full
FuU
FuU
Fun
Fun
FuH
Fun
Full
Pilot
Full
Bench
Bench
2468
K104 5
K103 6
K103/K104 6
K103/K104 6
242E
200B
Zimpro
Zbnpfo
250B
250B
323B
2508
2508
. 0418 10
2680 10
1484 10
0415 10
68
6B
68
68
2518
1B
6B
250B
242E
1054E
1054E
1000-10000 -. r
4600420000
32000-61000
4WKV3?(10W
4WMKW0900
' 0-100
100-1000
290
29 '
1000-10000
0-100
MOO
100-1000
100-1000
22300-48100
34693-147212
yift-flflftftftifl
274000412000
^ 1000001000000
<' 100000-1000000
10000-100000
' 10000-100000
100-1000
0-100
' 10000-100000
1000-10000
1000-10000
1000-10000
100000-1000000
AVERAGE
NO. OF EFFLUENT ,
DATA CONCENTRATION RECOVERY REMOVAL
POINTS foob) fK) (X) REFERENCE
1
8
5
.g
4
12
1
1
1
4 .
10
13
3
.-.3
12
2
10
10
8
3
10.000
35600.000 76.0
3560.000 76.0
8400 76.0
19.000 78.0
6MO
0.700
1.000
5.000
140.000
3400
32400
80.000
87400
38400
10.000
44400
200.000
48.000
10.000
10.000
10.000
. . 1.000
. 10400
230.000
29.000
500.000
' IfllVMnfMA
8928
83
8944
89.7
83
, 8Z2
86.1
. 18
78
82.7
8944
9949
9947
99.99
884
874
9947
78
9944
63
82
WERL
BOAT
BOAT
BOAT
BOAT
WERL
WERL
WAO
WAO
WERL
WERL
WERL
WERL
WERL
EAD*
EAD*
< EAD*
BAD*
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
* Date used in developing revised ctandvd.
A-17
-------
Benzofatpvrene. The data available for benzo(a)pyrene were compiled
from the BAB and WERL databases. These data are presented in Table A-9.
Technologies for which treatment performance data are available include AS, GAC,
ChOx, GAC, BT, and TF. The treatment performance data represent bench-, pilot-, and
full-scale studies.
; The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit .
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry.
BDAT for benzo(a)pyrene is being revised to BT (biological treatment).
The revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 103 ppb and the BAD Option 1 variability factor. The
' " " % ,
calculation of the resulting BDAT treatment standard for benzo(a)pyrene (0.061 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BJO-40NW A 1C
-------
TABLE A*
WASTEWATER TREATMENT PERFORMANCE DATA
FORBENZOMPYRENE
TECHNOLOQY
TECHNOLOGY
SIZE
FACnJTY
RANGE
DETECTION INFLUENT NO. OF
UMTT . CONCENTRATION DATA
fopb) (ppb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVERY REMOVAL
(K) (K) REFERENCE
AS
AS
AS
AS
AS
CAC
ChOx(Oz)
Fll
.FII
QAC
*BT
Sed
TF
TF
TF
Full
Full
Full
Fun
Full
Pilot
Full
Pilot
PHot
Full
FuH
Full
Full
975E
37SE
375E
S75E
68
185B
1830
79SE
195D
196D
1893
163D
126E
376E
375E
10
0-100
0-100
0-100
0-100
100-1000
1000-10000
0-100
100-1000
0-100
1000-10000
10426
0-100
0-100
0-100
0-100
7
7
7
7
10
8
. 4
6
6
IS
7
7
0.027
0.028
0.016
86
88
87.4
86
10.000
20.000
1.000
\JBOO
10.000
20.000
10.300
4200
0.120
0.018
0X85
882
78
89.81
80
862
83.6
88
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
EAD*
WERL
WERL
WERL
WERL
1 Data UMd In developing revised standard.
A-19
-------
Benzofblfluoranthene. The treatment performance data available for
' ~^^^^^^"^^^^^^^^^^^"~^^^ N
benzo(b)fluoranthene were compiled from the NPDES and WERL databases and are
.presented in Table A-10. Technologies for which treatment performance data are
available include AS, BT, RO, and TF. The treatment performance data represent pildt-
and full-scale studies and the resulting effluent concentrations ranged from 0.001 ppb to
lOppb.,
/ 4 ^
The revised BDAT for benzo(b)fluoranthene is AS (activated sludge
biological treatment). AS was selected as BDAT because it represents full-scale data
with a high influent concentration range and a high removal efficiency. The revised
BDAT treatment standard for benzo(b)fluoranthene was calculated using the effluent
concentration of 10 ppb and the appropriate accuracy correction factor and the
variability factor. The calculation of the resulting BDAT treatment standard for
benzo(b)fluoranthene (0.055 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJCMONW
0322-01.bjj.20
A-20
-------
TABLE A-10
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZO(b)FLUORANTHENE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
RANGE
DETECTION. MFUIENT NO. OF
LIMIT CONCENTRATION DATA
fepfa) tepb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
RECOVERY, REMOVAL
(K> flB REFERENCE
*AS
AS
AS
AS
AS
BT
BT
RO
TF
TF
Full
FuH
Full
Fun
Full
FuU
FuU
Pilot
Full
Full
LA0066214
MDOOOOS^S
NY0000281
NYOOOOB81
10001627
MD0000345
KY0003S14
WVD004740
LA0065501
6B
375E
S75E
S7SE
375E
LA0038245
KY0002119
1634E
S7SE
37SE
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
16
1
9
9
. 1
1
1
1
6
10
7
7
7
7
38
1
7
7
10.000
10.000
MOO
4.844
10.111
IftOOO
10.000
10.000
10.000
10.000
O.OZ3
0.014
0.017
10.126
10400
0.001
0.033
0.017
96.4
88
97J
89.6
69
92.1
69.7
932
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL*
WERL
WERL
WERL
WERL
NPOES
NPDES
.WERL
WERL
WERL
1 Data uMd in developing rovtod tUndvd.
A-21
-------
The data available for benzo(k)fluoranthene were
compiled from the BAD and WERL databases. These data are presented in Table A-
11. Technologies for which treatment performance data are available include AS, 8T,
RO, and TF, and the treatment performance data represent pilot- and full-scale studies.
x ' ' t
The treatment performance data available from the BAD database were
used to determine the revised BOAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. 4
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit. ...
(3) . A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. , '
BOAT for benzo(k)fluoranthene is being revised to BT (biological
treatment). The revised BDAT treatment standard was calculated using the BAD
median long-term average effluent value of 10 ppb and the BAD Option 1 variability
factor. The calculation of the resulting BDAT treatment standard for
benzo(k)fluoranthene (0.059 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJCMONW , ,
0322-01 .bjg.22 A-ZZ
-------
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZOMFLUORANTHENE
1
DfcTECIiON'
^^ TECHNOLOGY , LIMIT
^^NOU
AS
AS .
AS
AS
*BT
RO
TF
TF
TOY SIZE
Full
Full
Fun
Full
Full
Pilot
Full
Full
FACILITY tob)
6B
375E
375E
375E
1293 10
1634E
375E
37SE
RANGE
MFLUENT
NO. OF
AVERAGE
EFFLUENT
CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
-------
BisfZ-chloroethvltether. The treatment performance data available for
1 " **' ' ' i.
bis(2-chloroethyl)ether were compiled from the NPDES and WERL databases and are
presented in Table 'A-12. Technologies for which treatment performance data are
available include AL, AS, BT, CAC, ChOx, and TF. The treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent concentrations
ranged from 1 ppb to 430 ppb. ;
The revised BDAT for bis(2-chloroethyl)ether is AS (activated sludge
biological treatment). AS was selected as BDAT because the data represent roll-scale
treatment performance with a high influent concentration and high removal efficiency.
Hie revised BDAT treatment standard for bis(2-chloroethyl)ether was calculated using
the effluent concentration of 6 ppb and the appropriate accuracy correction factor and
variability factor. The calculation of the resulting BDAT treatment standard for bis(2-
chloroethyl)ether (0.033 ppm) is described in Section 6.0 and is shown in Table 6-1.
BTO-40NW
jซ.24
A-24
-------
TABLE A-12
WASTEWATBt TREATMENT PERFORMANCE QATA
FORBBp-CHLOROETHYL)ETHER
TECHNOLOGY
i
. AL
AL
AS
AS
.AS
AS
AS
BT
BT
BT
BT
. BT
BT
CAC
ChOx
TF
TF
. UCIBC1IUN
TECHNOLOGY LIMIT
SIZE FACILITY fepb)
Pilot
Pilot
FuU
Pilot
FuU
PDot
Full.
FuU
Full
Full
Full
Full
Full
Pilot
Bench
Pilot
Pilot
LA0065501
PA0012777
.NY0107174 , ' '. (
MKXW0868
LA0066214
203A
203A
IB
240A ,
6B
203A
975B
KY0002119
LA0038245
PA0026247
PA0026689
MKJ029173
MI0029178
203A
975B
' 203A
240A
RANGE - AVERAGE
INFLUENT NO. OF EFFLUENT
CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
(bob) POINTS topb) J1U (%) REFERENCE
.
- fc
100-1000
100-1000
100-1000
0-100
1000-10000
.100-1000
1000-10000
100-1000
1000-10000
100-1000 .
0-100
t
6-
8
8 . .
1
15
. 11
11
11
9 ' '.
3
11
'
13
38
25
2
15
15
11
,11
" 6 '
10.000
3.014
25*75
2.750
10.000
102.000
78.000
, 13.000
29.000
430.000
80.000
6.000
1Z080
1&492
10^80
3L500
1JOQQ~
tjaao
114.000 :
6.000
132.000
65.000
29
46
98.8
67
73
79
99.87
. - -
.*
20
99.74
.8
32
NPDES
NPDES
NPOES
NPDES
NPDES
WERL
WERL
WERL
WERL
WERL .
WERL
WERL* .
NPOES. '
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL
WERL
' Data uซ6d in developing revised ctandard.
A-25
-------
Bisdrethvlhexynphthalate. The data available for bis(2-
ethylhexyl)phthalate were compiled from the BAD and WERL databases and literature
WAO and PACT* data. These data are presented in Table A-13. Technologies for
which treatment performance data are available include AL, AS, CAC, BT, PACT*, RO,
TF,.and WOx. The treatment performance data represent bench-, pilot-, and full-scale
studies. ...
The treatment performance data available from the BAD database were.
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: '*,,.-' ,
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit. . .
i . ''.'"'
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. . .
BDAT for bis(2-ethylhexyl)phthalate is being revised to BT (biological
% , *
treatment). The revised BDAT treatment standard was calculated using the BAD
median long-term average effluent value of 47.1 ppb and the BAD Option 1 variability
factor. The calculation of the resulting BDAT treatment standard for bis(2-
ethylhexyl)phthalate (0.28 ppm) is described in Section 6.0 and is shown in Table 6-1.
BKMONW
W22-Ol.lgf.2fi A-ZO
-------
TABLE A-13
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BBp-ETHYLHEXYL)PHTHALATE
TECHNOLOGY
TECHNOLOGY SIZE FACILITY
AL
AL
AL
"' ( **-
AS
AS .
AS
AS
AS ,
AS
AS
AS
AS
.AS '
AS
AS
AS
AS
' AS ,,
AS ;
AS' '
AS
AS
AS
AS
AS
AS
AS
CAC
BT.
PACT
PACT
RO
TF
TF
TF
TF
TF
TF '
TF
WOx
WOx
WOx[B]
PBot
Fun
Bench <
Pflot
Fun
Full
Full
POot
Pilot
Full
Bench
FuU
Pilot
, Full
Full
Fun
Full
Full
FuU
Full
Full
FuU
FuU
Full
Pilot >
Pilot
Full
Full
Bench
Full
Full
FuU
Pilot
Full
Bench ,
Bench
Full
Full
Pilot
Full
Full
Full v
Full
Pilot
Fun
Fun ,
Bencn
203A
.18
371D
203A
18
1B
IB
241 B
203A,
IB
2020
IB
241B
, IB
1B
1B
IB
IB
IB
6B
18
16
201B
1B
204A
. 240A
IB
1B .
/ 1050E
1B.
1B
.18
203A
948
9758
Zimpro
250B
IB
203A
1B ,
18
1B
18
240A
Zimpro
Zimpro
1054E
RANGE
DETECTION MFLUENT
LIMIT CONCENTRATION
foot! (ppb)
100-1000
100-1000
1000-10000
100-1000 ;
0-100
0-100 .
0-100
100-1000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
0-100
100-1000
' 0-100
, 0-100
0-100
1000-10000
0-100
100-1000
0-100
0-100
0-100
100-1000
100-1000 '
0-100
100-1000
0-100
0-100
100-1000
100-1000
10 . 11-11740
( 100-1000
861
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
2 4800
11 1800
1 0OOOM 000000
AVERAGE >
NO. OF EFFLUENT /
DATA CONCENTRATION RECOVERY REMOVAL
POINTS fepb) 06) (*) REFERENCE
11
6
11
6
- -4
4 ,
8
11
6.
3
4
6
6'
8
6
6
4 '
37
. '4
6
3
4
8
10
6''
6
8
6
3
6
11
33
1
'' 8
11
8
4
6 ' -
8
6
1
1
34.000
' ' 73.000
190.000 1
1 30.000
6.000
18.000
5.000 .
7.000
. 18.000
10.000
60.000
10.000
390.000
90.000
11.000
81.000
9.000
20.000
67.000
47XW)
11.000
40.000
6.000
16.000
11 XXX)
48.000
48.000
81.000
35*000
10.000
&000
180.000 ,
18.000 .
43.300
3.000
2.000
8.000
60.000
39.000
6.000
22.000
26.000
33.000
43.000
' 10X100
0.000
100X100
80
39
90.5
82
79
47
81
83.7
89
84
'77' /
66
'' 64'
89
64
/. 72
. 87
73
- 83
87.1
76
86
834
70
.79
73
. ' ' 63
> '' 39
" - , ' 91.2
81
88
.87
91.1
99.46
99.6
90
3
77
81
24
32
86
79
99.99
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
.WERL
WERL
WERL
WERL
WERL ' -
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BAD* :
WERL
WAO
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WERL
Data used in developing revised utandara.
A-27
-------
Carbon Bisulfide. The treatment performance data available for carbon
disulfide were compiled from the NPDES data for one facility and are presented in
Table A-14A. The revised BDAT treatment standard was based on the average effluent
concentration from this facility and leachate treatment performance data submitted by
industry (presented in Table A-14B). The technology for which data are available was
ซ _ . \ - .
BT with a resulting effluent concentration of 5 ppb.
The revised BDAT for carbon disulfide is BT (biological treatment). BT
was selected as BDAT because the data showed substantial treatment of carbon
disulfide. The revised BDAT treatment standard for carbon disulfide was calculated
using the effluent concentration of 5 ppb and the appropriate accuracy correction factor
and variability factor. The calculation of the resulting BDAT treatment standard for
carbon disulfide (0.014 ppm) is described in Section 6.0 and is shown in Table 6-1:
BIO-40NW
0322-01.bjj.28
A-28
-------
TABLE A-14A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CARBON D8ULFIDE
RANGE . AVERAOE
/ DETECTION MFLUENT NO. OF EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY'REMOVAL
TECHNOLOGY SIZE FACIUTY (ppb) (ppb) POINTS (ppb) (K) REfERENCE
BT EMELLE 6 10 16 80 LEACHATE
BT ' - BFI 5 260 1 5 . . 90.07 LEACHATE
A-29
-------
Chlorobenzene. The treatment performance data available for
chlorobenzene were compiled from the AVERL database, BDAT Solvents Rule data, and
PACT* and WAO data from literature. These data are presented in Table A-15.
Technologies for which treatment performance data are available include AFF, AL, AS,
AirS, BGAC, BT, GAC, PACT?, RO, SS, and WQx. The treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent concentrations
ranged from 0.250 ppb to 1,550,000 ppb. .
. The revised BDAT for chlorobenzene is BT (biological treatment). BT
was selected as BDAT because it is represented by full-scale data developed from BAD
sampling and was used as part of the BDAT Solvents Rule. Furthermore, the effluent
concentrations achievable by this technology are supported by similar effluent
concentrations from the AS and PACT* treatment performance data. The revised
BDAT treatment standard for chlorobenzene was calculated using the effluent
concentration of 10 ppb and the appropriate accuracy correction factor and variability
factor. The calculation of the resulting BDAT treatment standard for chlorobenzene
* ( '
(0.057 ppm) is described in Section 6.0 and is shown in Table < 6-1.
BKMONW
CQ22-01.bjg.30
A-30
-------
TABLE A-15
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHLOROBENZENE
A .' . " ' .'- ' .'.,..
TECHNOLOGY
AFF
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS .-
AS
AlrS
AlrS
BGAC
BT
BT
BT
BT
BT
BT+AC
QAC
GAC
ซ.
PACT
PACT
RO
RO
.RO
SS
WOx
WOx
TECHNOLOGY
SIZE
-
Bench
Bencn
Bench
Bench
Full
Full
Bench
Full
Full
Full
Btl***
nioi
Pilot
Full
Bench
Bench
Bench
Fun
Full
Full
Full
Full
Full
Full
Full
Full
Fun
Full
Bench
Btncn
Bench
Pilot
Full
Full
Full
Bench
Bench
i .'
LIMIT
FACILITY (POD)
601A
371O
200B
200B
975B :
6B .
200B
975B
975B
1B
206B
241B
975B
1328E
1328E
601A
P206
P248
P263
REF4
P202
P246
245B
245B
237A
1421 D
6B
200B
242E
Zimpre
323B
250B
2508
251B
Zimpre
Zimpre
RANGE
I WFLUENT
CONCENTRATION
(bob)
1
0-100
1000-10000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
1000-10000
10000-100000
0-100
' 929-49775
100040
443432
1900
79-429
10-7200
100-1000
1000-10000
1000-10000
0-100
1000-10000
100-1000
0-100
31
0-100
0-100
1000-10000
100-1000
6535000
792000- .
NO. OF
DATA
POINTS
9
12
6
4
8'
6
20
6
6
8
23
8
13
3
1
20
16
1
1
.1
4
11
1
1
10
1
1
AVERAGE
EFFLUENT
CONCENTRATION
-------
Chloroethane. The data available for ctiloroethane were compiled from
the BAD and WERL databases. These data are presented in Table A-16. Technologies
for which treatment performance data are available include AL, AS, PACT*, and SS,
with all of the treatment .performance data representing full-scale studies:
The treatment performance data available from the HAD database
were used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. ,
(2) The HAD data were carefully screened prior to inclusion in the
, OCPSF database. These data were used in determining a
promulgated BAD limit.
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry.
BDAT for chloroethane is being revised to SS (steam stripping). The
revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of SO ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for chloroethane (021 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BKMONW
0322-01 .bfr.32
-------
TABLE A-18
WASTEWATER TREATMENT PERFORMANCE DATA
FORCHLOROETHANE
DETECTION
TECHNOLOGY UMFT
TECHNOLOGY SIZE FACILITY (ppb)
RANGE
MFLUENT
CONCENTRATION
(ppb)
AVERAGE
NO. OF EFFLUENT
DATA CONCENTRATION RECOVERY REMOVAL
POINTS fepb) m (K) REFERENCE
AL
AS
AS
AS
PACT
SS
Aft
Full
FuH
FuU
Full
Fufl
Fun
Full
Full
Full
IB
IB
IB
68
6B
013
41ST
BB
88.76
GO
80
100-1000
100-1000
100-1000
100-1000
1000-10000
9047700
680-42000
10000-100000
10000-100000
6
5
5
4
3
14
15
2
18
260.000
250.000
640.000
80.000
63.000
80.000
60.000
80.000
80.000
30
0
0
87
86.8
88.88
88.78
WERL
WERL
WERL
WERL
WERL
EAD*
EAD*
WERL
WERL
1 Data UMd In developlna ravtod fUndvd.
A-33
-------
Chloroform. The data available for chloroform were compiled from the
HAD and WERL databases and WAO and PACT* data from literature. These data are
presented in Table A-17. Technologies for which treatment performance data are
available include AL, AS, AS+Fil, AirS, CAC, CAC+AirS, ChOx, GAC, PACT*, RO,
SS, TF, and WOx. The treatment performance data represent bench*, pilot-, and full-
scale data. . .
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: .
(1) The HAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
v "-*-'. ' '
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit.
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. ,
BDAT for chloroform is being revised to SS (steam stripping). The revised
BDAT treatment standard was calculated using the EAD median long-term average
effluent value of 12.2 ppb and the EAD Option 1 variability factor. The calculation of
the resulting BDAT treatment standard for chloroform (0.046 ppm) is described in
Section 6.0 and is shown in Table 6-1. ' ' ' . . . .
BJG-40 NW
0322-01 JggJ4 A-34
-------
TABLE A-17 .
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHLOROFORM
-9
TECHNOLOGY
AL
AL
AL
AL
AL
AL
AL
AS
, AS
AS
. AS'' ' '
AS
' AS
AS
-AS .
AS
AS
AS
AS
AS
AS
AS
AS
AS
f
AS
AS
AS
AS
AS
AS+Fil
AS+FB
AlrS
AirS .
AliS
AlrS
TECHNOLOOY
SEE
FuU
Full
Pilot
Full
Full
Full
Pliot
Full
Full
Fun :
FuP
Bench
FuU
Full
Full
Fun
Full
Full
Full
Full
FuH
Full
. Full
Pilot
Full
Fun
Pilot
FuU
Pilot
Full
Full
Full
Pilot
Full
Full
Bench '
Pilot
Pilot
Bofich
FACILITY
1607B
IB
203A
141A
1607B
1607B
203A
IB
6B
1B .
6B
2Q2D
234A
1B
375E
IB
975B
234A
234A
6B
23BA
1607B
1607B
206B
S75E
1587E
241 B
234A
203A
6B
201 B
234A
240A
6B
6B
1328E
369A
213B
1328E
RANGE
DETECTION MFLUENT
LIMfT CONCENTRATION
foDb) fppb)
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
0-100
100-1000
10000-100000
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100-1000
0-100
100-1000
1000-10000
100-1000
. 0-100
0-100
100-1000
0-100
100-1000
1000-10000 '
x 0-100
0-100
0-100
' 1000-10000
100-1000
100000-1000000
0-100
0-100
10000-100000
NO. OF
DATA
POINTS
8
6
14
2
3
14
3
.7
5'
3
6
7
6
3
3
3
2
20
7
5
14
27
28
14
3
14
5
1
5
AVERAGE
EFFLUENT
CONCENTRATION
tDPb)
9JOOO
26.000
, 53.000
16.000
10.000
130.000
31.000
20.000
30.000
6.000
10.000
200.000
1.200
. , 21.000
1400
68.000
2400
2JOO
OJOO
10.000
2.400
50.000
40.000
3.600
20.000
1400
1400
18.000
19400
' 38.000
1400
2400
10400
10400
16000.000
1.400
13.000
4400.000
*\
RECOVERY REMOVAL
fit) <%)
90.1
96.8
81
924
97.4
86
77
.80
77
86
97.7
99.43
61
62
75
51
934
72 .
. . 96.4
mz
46
86
964
97.4
'' .78
' ' ''ซ
85
' 84
'.-.. 87
98.7
83
65
' ' . -96
99.41
954 .
93.1
962
77
83
REFERENCE
WERL
WERL
WERL
WERL ;
WERL
WERL
WERL
WERL
WERL
WERL
nftHL ' -
WERL
, WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL .
WERL
WERL
A-35
-------
TABLE A-17 (Continued) ,
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHLOROFORM
TECHNOLOGY
TECHNOLOGY SIZE FAdUTY
AirS
AlrS
AliS
AitS
AJiS
AlrS
AirS
AirS
AlrS
CAC
CAC+AlrS
ChOx
ChOx
ChOx (Oz}
ChOx(Oz)
GAC
GAC
GAC
GAC
.GAC
PACT
PACT
PACT
RO
RO
RO
SCOx
ss
*SS
88
83
S3
SS
TF
TF
TF
WOx
WOx
PBot
Bench .
Bench
Bench
B6ftCn
Pilot
Bench
- . Bench
Pilot
PBot
Full
'. Bench
Bench
PPot
PUot
Full
Pilot
Full
Full
FuH
Bench
Bench
Bench'
Pilot
Full
FuB
PBot
Full
Full
Full
Full
Full
Full
Pilot
Full
PUot
B0noh
Bench
225B
17A
17A
17A
17A
2106
17A
132BE
4MB
203A
16330
640E
640E
331D
. 331 D
1264B
331D
245B
237A
245B
242E
Zfmpro
Zimpro
180A
2SOB
2SOB
65D
415T
813
6B
6B
2S1B
251B
24QA
1B
203A
Zimpro
Zimpro
RANGE
bfcJcvivN MFLUENT
LIMIT CONCENTRATION
(pob) fepb) .
0-100
0-100
1000-10000
0-100
100-1000
100-1000
; 100-1000
100-1000
1000-10000
100-1000
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
. 100-1000 '
. 100-1000
100-1000
0-100
1470
38
0-100
1000-10000
100-1000
100-1000
10 7330-1066000
10 28700400000
10000^p*1 000000
10000-100000
1000000 ;
' 100000-1000000
, v- 0-100
0-100
100-1000
4490000
2/uuuO
NO. OF
DATA
POINTS
''1 ' -
1
8
4
14
"25
2
1
(
15
14
15
2
.10
10
14
4 '
14
1
1
, AVERAGE
EFFLUENT
CONCENTRATION . RECOVERY REMOVAL
(ppb) (%) (K) REFERENCE
0.130
2.600
110.000
8900
4.200
14100
3.700
34.000
41.000
108.000
0200
7JOOO
9JBOO
46.000
2JOO
1Aป
. 1.000
10.000
10.000
10.000
80.000
IAOO
20.000
0.890
110.000
83.000
1.700
10.500
129200
10.000
120.000
0000-000
9600.000
11*00
14.000
102.000
3000.000
1000*000
98.8
8641
81.7
68
. 96.6
882
96.6
. 84
88
22
88
86
88
87
36
67 '
88.6
87.6
96.1
962
. 47
69.9
47
71
94.5
87
89.83
MM
88.86
99.99
96.4
89
88
24
99.9
99
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL :
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WEB^B^
WBJ^^B"
WEi^^^
WERL
BAD*
EADซ
WERL
WERL
WERL
,WERL
WERL
WERL
WERL
WAO
WAO
* Data used In developing revieed ttandard.
A-36
-------
Chloromethane. The data available for chloromethane were compiled
from the BAD, WERL, and NPDES databases. These data are presented in Table A-18.
Technologies for which treatment performance data are available include AS, AS+Fil,
BT, and SS. All of the treatment performance data represent full-scale studies.
. The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
, .' ' ", ' . . "
following reasons:. ''"'..'_. :
(1) The BAD data represent treatment performance data from the
. OCPSF sampling episodes. The data collected by HAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The HAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit
(3) A promulgated EAD limit represents data that have undergone.
further review, and have received acceptance by both EPA and
industry. ' , , .;. .
BDAT for chloromethane is being revised to SS (steam stripping). The
revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 50 ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for chloromethane (0.19 ppm) is
described in Section 6.0 and is shown in Table 6*1. ,
BKMONW
0322-01 .tjg.37 ; A-37
-------
TABLE A-18
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHLOROMETHANE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
DETECTION
LIMIT
(ppb),
RANGE
MFLUENT
CONCENTRATION
(ppbl -
AVERAGE
NO. OF EFFLUENT
DATA CONCENTRATION
POINTS (ppb)
RECOVERY REMOVAL
(%) (K) REFERENCE
AS
AS
AS
AS+RI
BT
BT
8T
BT
Sod+FQ
SS
SS
Fun
Full
Full
Full
Full
FuH
Full
Full
Full
Full
Full
Full
CTOOOM34
KY0003514
PA0011371
LA0004057
MA0006304
IL0001627
NY0202061
NY0075957
NY0006605
NJ002829V
MD0000345
KY0003603
WV0004740
OH0025461
8C0001180
LA0066214
LA0066435 .
LA0065501
TX0007439
1B
1B
KYOOOeilfl
LA003824S
PA0026689
WVOQ23116
PA0010502
725
6B
251B
100-1000
,100-1000
100-1000
0-100
60
9440-1290000
100000-1000000
10000-100000
5
1
9
22
21
9
29
13
15
2
1
1
1
2
40
IS
12
6
42
ซ
S
s
7
1
38
2
18
26
13
11
10
22.600
6.000
1.000
12.300
10.046.
9.333
20.769
6.400
10.000
10.000
10.000
21.700
6J74
11.788
6.500
10.000
110.000
11.000
91.000
50.000
10.000
10263
12.100
16.111
1.308
923.100
50.000
5.000
66
96.3
75
39
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL
WERL
99.96
99.99
WERL
WERL
EAD*
WERL
WERL
* Data used In developing reKraed ctandard.
A-38
-------
Ghrvsene. The data available for chrysene were compiled from the BAD
and WERL databases. These data are presented in Table A-19. Technologies for which
treatment performance data are available include AS, AS+Fil, and BT. The treatment
performance data represent pilot- and full-scale studies. ,
The treatment performance data available from the BAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown '
... characteristics. ,
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit .
(3) , A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry: - .
BDAT for chiysene is being revised to BT (biological treatment). The
revised BOAT treatment standard was calculated using the BAD median long-term
average effluent value of 10. ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for chiysene (0.059 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BIO-40NW
0322-01.ldg.39
A-39
-------
TABLE M9
WASTEWATER TREATMENT PERFORMANCE DATA
FORCHRYSENE
RANGE
DETECTION WFLUENT
TECHNOLOGY
AS
AS
AS
AS+FB
Fil
*,BT
TECHNOLOGY
SIZE
Pilot
Fun
Fun
Full
Full
Fun
LIMIT
FACILITY (bob)
204A
68
68 ;
68
782E
1283 10
CONCENTRATION
(ppb)
0-100
100-1000
100-1000
1000-10000
100-1000
. 10*77
NO. OF,
DATA
POINTS
8
4. '
11
a
4
15
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
1200
10.000
10.000
10.000
1.000
. 10.000
RECOVERY REMOVAL
(K) (K)
98.9 .
88
86.8
99.08
99.76
- - ' '
REFERENCE
WERL
WERL
WERL
WERL
WERL
EAD*
* Dซta u**d In developing ravted ซUndwd.
A-40
-------
ortho-Cresol. The treatment performance data available for ortho-cresol
were compiled from the WERL database and the BOAT Solvents Rule data. These data
are presented in Table A-20. Technologies for which data are available include Anff,
AnFFwGAC, BT, and RO. The treatment performance data represent bench-/ pilot-,
and fullrscale studies and the resulting effluent concentrations ranged from 14 jppb to
26,000 ppb. .'''-
, --.' ''"-, ' > '
The revised BDAT for ortho-cresdl is BT (biological treatment). Bf was
selected as BDAT because it represents full-scale data developed from EAD sampling
and was used as part of the BDAT Solvents Rule. The revised BDAT treatment
' . ' . * , /
standard for ortho-cresol was calculated using the effluent concentration of 25 ppb and
the appropriate accuracy correction factor and variability factor. The calculation of the
resulting BDAT treatment standard for ortho-cresol (0.11 ppm) is described in Section
\ _ .- _ .
6.0 and is shown in Table 6-1. '
BKMONW ,
0322-01 .bjg.41 , A-41
-------
TABLE A-20 -
WASTEWATER TREATMENT PERFORMANCE DATA
FORorthfrCRESOL
DETECHON
TECHNOLOGY - LIMIT
TECHNOLOQY SIZE FAaLfTY (ppb)
RANGE
NFLUENT
CONCENTRATION
tepb)
AVERAGE -
NO. OF EFFLUENT
DATA CONCENTRATION RECOVERY REMOVAL
POINTS (ppb) (K) (K) REFERENCE
AnFF
AnFF '
AnFFwGAC
BT
RO
Bซปh
Pilot
Pilot
Fun ,
Fun
230A
2480
REFS
2SOB
\ 00000~1000000
10000-100000
100000-1000000
18884538
100-1000
7800.000
25*000
14.000
78 WERL
65 WERL
08.7 WERL
BOAT*1
98.5 WERL
* EAO date presented In the BOAT Solvwito Ruto F001-F005 Buk0round Documtnl
* Date iปed in developing r*vi*ed ctendard.
A-42
-------
meta/para-Cresol. Currently, reliable analytical methods for the
separation and subsequent measurement of meta-cresol and para-cresol do not exist
Therefore, the Agency believes it is appropriate to measure and regulate both isomers
under one combined listing. The treatment performance data available for meta/para-
cresol were compiled from the WERL database and are presented in Table A-21.
t
Technologies for which treatment performance data are available include .
API+DAF+AS, AS, AnFF, RO, and SExt The treatment performance data represent
bench-, pilot*, and full-scale studies. The resulting effluent concentrations ranged from
72 ppb to 17,000 ppb.
1 ' " i " .
i " . .
The revised BDAT for meta/para-cresol is AS (activated sludge biological
treatment). AS was selected as BDAT because it, represents a demonstrated technology
with a high removal efficiency and was the BDAT chosen for ortho-cresol. The revised
BDAT treatment standard for meta/para-cresol was calculated using the effluent
.:.-'. - . , , v. . .. '
concentration of 174 ppb and the appropriate accuracy correction factor and variability
factor. The calculation of the resulting BDAT treatment standard for meta/para-cresol
. . j ~ '
(0.77 ppm) is described in Section 6.0 and is shown in Table 6-1.
BKMONW
0322-OI.bjg.43 A-43
-------
TABLE/MM :
WASTEWATER TREATMENT PERFORMANCE DATA
FORmtta/panfrCRESOL
TECHNOLOGY
TECHNOLOGY 8BE FACIUTY
DETECTION
UMfT
(ppb)
RANGE
INFLUENT
CONCENTRATION
tepb)
AVERAGE
NO. OF EFFLUENT
DATA CONCENTRATION RECOVERY REMOVAL
POINTS (ppb) OB <%) REFERENCE
APJ+DAF+AS
"AS
AnFF
RO
SExt
Full
PUot
Bench
Fid
Pilot
14820
241B
1062E
1000*10000
100-1000
10000^1000000
1000*10000
10OOOCH 000000
4
9
160.000
174.000
17000.000
72.000
9000.000
67
68
90.7
97.7
99.68
WERL
WERL"
WERL
WERL
WERL
' Data used In developing revised standard.
A-44
-------
o-Dichlorobenzene. The treatment performance data available for o-
dichlorobenzene were compiled from the WERL database, BDAT Solvents Rule data,
and WAO data from literature . These data are presented in Table A-22. Technologies
for which treatment performance data are available include AFF, AL, AS, AirS, BGAC,
BT, GAC, PACT*, RBC, RQ, and WOx. The treatment performance data represent
bench-, pilot-, and full-scale studies. The resulting effluent concentrations ranged from
0,09 ppb to 2,017,000 ppb.
s
The revised BDAT for o-dichlorobenzene is BT (biological treatment)., BT
was selected as BDAT because it represents full-scale data developed from HAD
sampling and was used as part of the BDAT Solvents Rule. Furthermore, the effluent
concentration achieved by this technology is similar to effluent concentrations reported
from the WERL activated sludge treatment performance data. The revised BDAT
- * ' f '
treatment standard for o-dichlorobenzene was calculated using the effluent concentration
of 16 ppb and the appropriate accuracy correction factor and variability factor. The
calculation of the resulting BDAT treatment standard for o-dichlorobenzene (0.088 ppm)
is described in Section 6.0 and is shown in Table 6-1.
BKMONW
0322-0l.bjg.4i . A-45
-------
TABLE A-22
WASTEWATER TREATMENT PERFORMANCE DATA
FORo-OCHlOROBENZENE .
* * ,
I '
TECHNOLOGY
AFF
AL
AL
AL
AS
AS '
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AiiS
AirS
BGAC
- BT
BT
BT
BT+AC
GAC
GAC
PACT
PACT
PACT
PACT
RBC
RO
RO
WOx
WOx
WOx
TECHNOLOGY
SIZE
. Bench
Pilot ;
Pilot
Bench
' Full
Fun
Pilot
PDot
Full
Full
Full
Full
Bench
Full
Fun
Bench
Pilot
Bench .
Full
Full
Bench
Bench
Pilot
Bench
Full
Full
Full
Full
Full
Full
Bench'
Bench
Full
Full
Pilot,
Pilot
Pilot
Bench
. Bench
Pilot
. . DETECTION
LIMIT
FACILITY (ppb)
S01A .
1920
x 1920
3710
1B
88 '
1920
1920
6B
1B
1B
68
200B -
IB
1587E
2020
241B
1050E
375E
68
1064E
1328E
222B
501A
P248
P202
P206
P246
' 245B ' . > "
14210
242E -.'
200B
68
68
1820
323B
180A
Zimpro
Zimpro
760
RANGE
MFLUENT
CONCENTRATION
(M>b)
0-100 ' .
100-1000
1000-10000
1000-10000
100-1000
1000-10000
1000-10000
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
100-1000
0-100
10000-100000
100-1000 .
100-1000
0-100
100-1000
100-1000
/ 10000-100000
0-100
0-100
7684801
1350-4387
2334333
768-3278
100-1000
0-100
0-100
100-1000
1000-10000
100-1000
,. 100-1000
0-100
0-100
590000
6530000
>1000000
NO. OF
DATA
POINTS
25
4 .
8
330
2
3
' 4
14
8
10
5
7
3
1
.8--
1
34
14
4
10
17
1
14
10
4
1
1
1
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
0.380
10.000
100.000
72.000
6.000
52.000
110.000
270.000
35.000
- 8-000
2.000
16.000
6.000
10.000
1200
80,000
25.000
1j600
5.000
10.000
8.000
6200.000
0.500
OJ10
896.000
16.000
68.000
176.000
10.000
0270
5.000
2JOO
88.000
64.000
10.000
11.000
0.090
150000.000
2017000.000
. 29000.000
RECOVER REMOVAL
(K) (%}
96
97.7
94.8
VTA
96
98.5
94.3
37
962
962
943
99.33
92.7
91.7
79
99.94
932
99.6
87
92*
86.4
74
83
96.8 _.
96 J
90
83
9ZS
98.5
90
97.7
70
92.5
74.6
69.1
98.7
REFERENCE
WERL -
WERL
WERL
WERL '
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BDA*Ub^
BD/j^^^B
BDA^^Ir
BOAT^T
WERL
WERL
WERL
WERL ."
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WERL
* EAD data presented in the BOAT Solvent* Rule F001-F005 Background Document
* Data u*ed In developing revised etendvd.
A-46
-------
p-Dichlorobenzene. The treatment performance data available for p-
dichlorobenzene were compiled from the WERL database and WAO data from
literature! These data are presented in Table A-23. Technologies for which treatment
performance data are available include AFF, AL, AS, AirS, BGAC, CAQ ChOx, GAC,
PACT*, RBC, RO, and TF. The treatment performance data represent bench-, pilot,
and full-scale studies. The resulting effluent concentrations ranged from 0.004 ppb to
3,600 ppb.
The revised BDAT for p-dichlorobenzene is AS (activated sludge biological
treatment). AS was selected as BDAT because it represents full-scale data with high
influent concentrations and high removal efficiencies. The revised BDAT treatment
standard for p-dichlorobenzene was calculated using an effluent concentration of 1633
ppb (which represents an average of the data presented for the activated sludge , . . ,
technology in the high influent concentration ranges) and the appropriate accuracy
correction factor and variability factor. The calculation of the resulting BDAT treatment
" '' ' ' . '
standard for p-dichlorobenzene (0.090 ppm) is described in Section 6.0 and is shown in
Table 6-1. .
BIO-WNW _
0322-OI.bjg.47 A-47
"
-------
TABLE A-23
WASTEWATER TREATMENT reRFORMANCE DATA
FORp-DICHLOROBENZENE ^^k
' RANGE AVERAGE .
DETECTION WFLUENT NO. OF EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE FACILITY (POD) (bob) POINTS (ppb) (%) <%) REFERENCE
AFF
AL
AL
AL
AL ,
AS
AS
AS
AS
AS
AS
AS ..
AS ,
AS
AS
. AS
AS
AS
AS-' 'r
AS
AS
-*AS .
AS
AS
AlfS
BGAC .
CAC
, ChOx
QAC
QAC
PACT
PACT
PACT
RBC
RO
TF
TF
Bench
.PHot
Wlot
Pilot
Pilot
Full
Full .
Pilot
Full
pact
Pilot
Pilot
PBot
PBot
Full
Pilot, ^
Full
Full
Full
Pilot
Full
Full
Full
Fun
pflnCfi
BOnCn
Pilot
B*nch
Full
Full
Bench
Bench
Bench
Pilot
pilot
Pilot
Pilot
S01A
182D
203A
203A
1920
IB '
234A
241 B
875B
1820
631D
631D
240A
1820
234A
241B
2018
1B
1B
203A
234A
6B
875B
875B
, 1328E
801A
203A -.
875B
2453
1421D
976B
87SB
Zlmpro
1820
180A
240A
203A
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
100-1000
1000-10000
100-1000
0-100
0-100
. 100-1000
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
6-100 v .
100-1000
0-100
100-1000
10000-100000
0-100
0-100
0-100
100-1000
. 0-100
0-100
0-100
36.6
0-100
0-100
100-1000
0-100
27
.11
11
' ?
4
12
11
, 2
- 1 /
1
11
4 . -
'5
84
11
1
,
1
1 -1
11
11
0200
.10.000
31.000
liooo '
10.000
laooo
asoo
10.000
1&000
10.000
aoo4
QJ004 /
8.000
10.000
asoo
18.000
64X10
6.000
8.000
5.000
0.500
10.000
4.800
27.000 .
3600.000
0270
66.000
5.000
10.000
0200
5.000
6.000
0.015
10.000
0.670
16.000
58.000
86.1
88 '
67
87
80.5
76
81
80.7
. 88.63
80.5
88
88
83A
88
80
85.1
78
83.1
83
84.6
81.7
87
82.8
86.6
80
VIA
28
81.1
86
82
83.5
823
88.86
86
61
88 ,
38
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL*
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL*
WERL _
WER^^BK
WER^^^B
WERE^B^ .
WERL
WERL
. WERL
WERL
WERL
WERL
WAO
WERL
WERL
WERL
WERL
Data used In developing revteed itandard.
A-48
-------
1.1-Dichloroethane. The data available for 1,1-dichloroethane were
compiled from the HAD and WERL databases. These data are presented in Table A-
24. Technologies for which treatment performance data are available include AL, AS,
AirS, AirS+GAC, CAC, GAG, PACT*, RO, SS, and TF. The treatment performance
data represent bench-, pilot-, and full-scale studies. >
The treatment performance data available from the BAD database were
used to determine the revised BOAT treatment standard for this constituent for the
following reasons: .
(1) The HAD data represent treatment performance data from the
OCPSF sampling episodes. 'The data collected by HAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. s
(2) The HAD data were carefully screened prior to inclusion, in the
OCPSF database. These data were used in determining a
promulgated BAD limit. .
(3) .A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
. industry.
BDAT for 1,1-dichloroethane is being revised to SS (steam stripping). The
revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 10 ppb and the BAD Option 1 variability factor. Hie
calculation of the resulting BDAT treatment standard for 1,1-dichloroethane (0.059 ppm)
is described in* Section 6.0 and is shown in Table 6-1. .
BIO40NW
0322-01.bjg.49 A-49
-------
TABLE A-24
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1-aCHLOflOETHANE
RANGE . AVERAGE
DETECTION IMFLUENT N0.OF EFFLUENT
TECHNOLOGY UMTT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY _ SIZE FAdUTY , (ppfa) (ppb) POINTS fepbl. (X) fltt REFERENCE
AL
AL
AL
AS
AS
AUS
AUS
AlrS+GAC
CAC
' GAG
GAC .
PACT
RO
RO
RO
88
88
88
TF
TF
POot
Pilot
Full
Pilot
Plot
POot
PBot
, Full
Pilot
Bench
Full
Bench
Full
Full
Full
Full
Full
Full
Pilot
Pilot
203A
203A
.18
203A
240A
222B
1362E
229A
203A
1362E
. 1264B
Zimpro
250B
,2508
2508
913 10
2S1B
6B
240A
203A
100-1000
100-1000
0-100
100-1000
0-100
0-100
* 1000-10000
0-100
100-1000
.1000-10000
0-100
640
1000-10000
100-1000
0-100
3400-13900
10000-100000
1000-10000
0-100
100-1000
14
14.
2'
14
14
1
3
19
14
1.
^
14 :
10
2
.14
14
18.000
45.000
10.000
8.000
2.000
0.300
630.000
1.000
111.000
1.000
14XJO
1.000
64.000
64.000
3400
10.000
10.000
. 10.000
7.000
94.000
87
69
88
94.4
97.5
87.5
75
87.4
23
89.87
80
98.8
92.4
88
85.4
994)
894)
81.3
. 35
WERL
WERL
. WERL
WERL
WERL
WERL
WERL
WERL ,
WERL
WERL
WERL
WAO
WERL
WERL
WERL
. EAD*
WERL
WERL
WERL .
WERL
* Data uwd In dovsloping ravlMd standard.
A-50
-------
IJZ-Dichloroethane. The data available for 1,2-dichloroethane were
compiled from the HAD and WERL databases and WAO data from literature. These
data are presented in Table A-25. Technologies for which treatment performance data
are available include ALป AL+AS, AS, AS+Ffl," AirS, CAC, PACT*, RO, SS, TF, and
> . , -
WOx. The treatment performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the BAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: . .
(1) ,Ihe EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. '
(2) The HAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit. , - ,
(3) A promulgated HAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry.
BDAT for 1,2-dichloroethane is being revised to SS (steam stripping). The
'revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 25.6 ppb and .the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for 1,2-dichloroethane (0.21 ppm)
is described in Section 6.0 and is shown in Table 6-1.
BJO-40NW
0322-01.bjป .51
A-51
-------
TABLE A-25
WASTEWATER TREATMENT PERFORMANCE DATA
FORU-DICHLOROETHANE
TECHNOLOGY
TECHNOLOGY
SIZE
FACnJTY
RANGE
DETECTION MFLUENT NO. OF
LIMIT CONCENTRATION DATA
tepbl teobV POINTS
AVERAGE-
EFFLUENT
CONCENTRATION
RECOVER REMOVAL
(M (K)
REFERENCE
AL
AL
AL
AL+AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS+FU
AliS
AltS
CAC
PACT
RO
RO
RO
RO
SS
SS
SS
TF
TF
TF
WOx
WOx(B)
Pilot
Full
Pilot
Full
Pilot
Pilot
FuU
Fun
Pilot
Full
Fun
203A
IB
203A
233D
203A
241B
1B
8B
240A
6B
37SE
Full
FuU
FuH
Full
Full
Fuli
Pilot
Bench
FuU
FuU
Pilot
Full
Futt
FuU
Fun
Fun
Full
Pilot
Full
Pilot
Bench
Bench
1B
6B
6B
6B
,322B
203A
Zirnpro
2MB
323B
250B
415T
913
251B
SB
6B
240A
375E
203A
Zimpro
1054E
10
10
100-1000 14
1000-10000, 6
100-1000 * 14
1000-10000 21
. 100-1000 14
100-1000 3
1000-10000 , 8
100-1000 3
0-100 13
1000-10000 25
100-1000 7
10OOO^H 000000
10000-100000 6
100-1000 13
100-1000 12
' 10000-100000 3
100-1000 8
1000-10000 8
100-1000 . 14
,210 1
1000-10000
0-100
0-100 1
100-1000
233990043476000 15
172000427000 14
1000000 . 10
1000000 18
100000-1000000 2
0-100 13
100-1000 7
100-1000 14
6260000 '<- 1
1000000
15.000
10.000
45.000
8.000
22.000
140.000
4400.000
12.000
8.000
28.000
74:000
8700.000
1800.000
94:000
. 15.000
1200.000
55.000
189.000
109.000
tjOOO
380.000
13.000
32.000
43.000
56.100
79300
87.000
86.000
80.000
1ZOOO
45.000
93.000
13000.000
902
89.75
71
89.67
86
57
33
86.1
94.3
96.6
82
96.6
89
84
883
863
89
993
84
79
99.99
99.98
86
65
89 .
89.8
83.6
' Data used in devปlop!ng revised standard.
A-52
-------
trans-U-Dichloroethene. The data available for trans-l,2-dichloroethene
were compiled from the HAD and WERL databases. These data are presented in Table
A-26. Technologies for which treatment performance data are available include AS,
AS+Fil, AirS, GAC, RO, SS, and TF. The treatment performance data represent bench-
, pilot-, and full-scale studies. ..
The treatment performance data available from the EAD database were
used td determine the revised BOAT treatment standard for this constituent for the
'-.-
following reasons: - .'.-_'.
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit. "
(3) A promulgated EAD limit represents data that have undergone
further review,, and have received acceptance by both EPA and .
industry. ,.:.." "
BOAT for trans-l,2-dichloroethene is being revised to SS (steam
stripping). The revised BDAT treatment standard was calculated using the EAD median
long-term average effluent value of 10 ppb and the EAD Option 1 variability factor.
The calculation of the resulting BDAT treatment standard for trans-l,2-dichloroethene
(0.054 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJO-40NW
0322-01 .bjg.33 ' A-53
-------
TABLE A-26
WASTEWATER TREATMENT PERFORMANCE DATA
FOTTRANS-1^-DICHLOROETHYlฃNE
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
AS
AS
AS
AS+FU
AlrS '
AiiS
AlrS .
AlrS
AfrS
GAC
, RO
SS
ss
ss
6S
TF
FuB
Full
Full
Full
Bench
Pilot
Pilot
- Pilot '
Bench
Full
Full
Fun .
FuU
Full
Full
Full
1B
IB
1B
68 .
1328E
1362E
, 710
1363E
1328E
245B
250B
41 5T 10
913 10
6B
6B
. 1B
0-100.
0-100
0-100 '
100-1000
1000-10000
1000-10000
100-1000
100-1000
100000-1000000
100-1000
10000-100000 .
48SW3000 ~
14100-70300
10000-100000
10000-100000
0-100
NO. OF AVERAGE ^^
DATA . EFFLUENT RECOVER REMOVA REFERENCE
POINTS CONCENTRATION (*) (K)
(ppb)
3
4
5
3 - .
6
' 3 '
1
8
1
15
14
16
'2
8
7.000
3.000
8.000
76.000
1500.000
1.300
.6.000
5.000
' 17000.000
10.000
6000.000
14.100
10.000
14.000
10.000
1.000
' .. 88
93.5
71
81
80
99.9
98.1
952
84
92.5
64
' , %
99.9 .
100
97.9
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL '
WERL
WERL
WERL
ITD4.ซ
ITD-L*
WERL
WERL
WERL
* Data wad in developing proposed standard
A-54
-------
Diethvl Phthalate. The data available for diethyl phthalate were compiled
from the HAD and WERL databases and PACT* data from literature. These data are
presented in Table A-27. Technologies for which treatment performance data are
available include AS, BT, and PACT*. The treatment performance data represent
\
bench-, pilot-, and full-scale studies.
\ . .
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
. i
following reasons: ^ ,
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit, -
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
' industry. .
BDAT for diethyl phthalate is being revised to BT (biological treatment).
The revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 42.5 ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for diethyl phthalate (020 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BJO-40NW ,
0322-01 .bjj .55 . A-55
-------
TABLE ACT
WASTEWATER TREATMENT PERFORMANCE DATA
,. . FORDIETHYLPHTHALATE
RANGE AVERAGE .
DETECTION INFLUENT NO. OF EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE FACILITY teobV (ppb) POINTS (ppb) At,) (%) REFERENCE
AS
AS
AS '
AS
AS
*BT
PACT
Pilot
Full
Pilot
Full
Full
Full
BAMkk
DvJiWfl
204A
68 *
241B
1B
IB
48 10
Zknpro " .
0-100
1000-10000
100-1000
0-100
0-100
14-15000
88
' 8
38
11
4
3
33
1 ' '
1200
28,000
12.000
1XWO
3.000
23.500 .
1.000
07.4
Vt.J
B7.6
98.7
88
86.9
WERL
WERL
WERL
WERL
WERL
EAO*
WAD
' Data uปed in developing revived ctandvd.
A-56
-------
- 2.4-DimethvIphenol. The data available for 2,4-dimethylphenol were
compiled from the BAD and WERL databases, WAO data from literature, and EPA
WAO test data. These data are presented in Table A-28. Technologies for which
treatment performance data are available include AL, AS, AS+Fil, AnFF, AnFFwGAC,
BT, RBC, RO, TF, WQx, and WOx+PACI* The treatment performance data
represent bench-, pilot-, and full-scale studies. ,
' - - ' ' ' ' ฃ
The treatment performance data available from the BAD database were
used to determine the revised BOAT treatment standard for this constituent for the .
following reasons: '
(1) The HAD data represent treatment, performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. ,
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a .
promulgated BAD limit
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both BPA and
industry. s
BDAT for 2,4-dimethylphenpl is being revised to BT (biological treatment).
The revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 10.794 ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for 2,4-dimethyl phenol (0.036
ppm). is described in Section 6.0 and is shown in Table 6-1.
BJG-40NW
0322-01.bป.S7 A-57
-------
TABLE A-26
WASTEWATER TREATMENT PERFORMANCE DATA
FOR2.4-DIMETHYLPHENOL
".'', . RANGE AVERAGE
DETECTION WFLUENT NO. OF EFFLUENT * ' '
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE FACILITY (ppb) frpb) POINTS (ppb) f%) <%) REFERENCE
AL
AS
AS
AS
AS
AS+Fil
AnFF
AnFFwGAC
*BT
, RBC
RO
TF
WOx
WOx+PACT
WOx[B]
Pilot
Fun
Pilot
Full
Pilot
. Full
Pilot
Pilot
Full
Pilot
Full
Full
Bench
Pilot
Btnch
'192D .
6B
1820
68
204A
SB
235D
249D
1293 10
1820
250B
' .'IB
ZImpre
Zlmpro 39
236A
1000-10000
100-1000 '
. . , 1000-10000
10000-100000
0-100.
1000-10000
1001X10000
10000-100000
16216-73537
1000-10000
100-1000
0-100
6220000
630000-790000
> 1000000
7r
'
14
6
. 3
15
2
1
3
1
10.000
13.000
10.000
10.000
0.900
10.000
0.400
0.050
10.000
10.000
16.000
25.000
100.000
75.330
. 820.000
99.81
96.1
99.61
99.97
99.06
99.9
99.99
99.93
-
99.81
96.4
" 38"
99.99
99.99
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BAD*
< WERL
WERL
WERL
WAO
WAO
WERL
' Data uซed In developing rซviMd tankard
A-58
-------
Dimethyl Phthalate. The data available for dimethyl phthalate were
compiled from the EAD and WERL databases and PACT* and WAO data from
literature. These data are presented in Table A-29. Technologies for which treatment
performance data are available include AS, BT, PACT*, and WQx. The treatment
performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the EAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: ,'/'"
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. ; l ,
(2) The EAD data were carefully screened prior to inclusion in the
. OCPSF database. These data were used in determining a
promulgated EAD limit
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and .
industry.
BDAT for dimethyl phthalate is being proposed revised to BT (biological
treatment). The revised BDAT treatment standard was calculated using the EAD
median long-term average effluent value of 10 ppb and the EAD Option 1 variability
factor. The calculation'of the resulting BDAT treatment standard for dimethyl phthalate
(0.047 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJO-WNW .
0322-01.bjg.S9 A-59
-------
TABLE AW
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DIMETHYL PHTHALATE
TECHNOLOGY
TECHNOLOGY
AS
AS
AS
AS
AS
*BT
PACT
- WOx
SIZE
Fun -
Full
Pilot
Pilot
Full
Fun
Bench
FuD
FACILITY
IB
SB
241 B
804A
1B
046
Zimpre
Zimpio
RANGE
DETECTION MFLUENT
AVERAGE ,
NO. OF EFFLUENT
UMTT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
6>Pb)
-------
Di-n-butvl Phthalate. The data available for di-n-butyl phthalate were
compiled from the BAD and WERL databases. These data are presented in Table
A-30. Technologies for which treatment performance data are available include AL, AS,
CAC, ChOx, BT, and TF. The treatment performance data represent bench-, pilot-, and
full-scale studies.
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: ^
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics/ .'...-
\ \
* *
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were, used in determining a
promulgated EAD limit.. ' .
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
: industry.
BDAT for di-n-butyl phthalate is being revised to BT (biological
treatment). The revised BDAT treatment standard was calculated using the EAD
median long-term average effluent value of 17.606 ppb and the EAD Option 1 variability
factor. The calculation of the resulting BDAT treatment standard for di-n-butyl
phthalate (0.057 ppm) is described in Section 6.0 and is shown in Table 6-1.
' . > . '. . . .
BJO-40NW
0322-01 .bjg.6I A-61
-------
TABLE A-30
WASTCWATEH TREATMENT PERFORMANCE DATA
FORDMvBt/TYLPHTHALATE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
RANQE
DETECTION MFLJUENT NO. OF
UMfT CONCENTRATION DATA
(ppb) (pott POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVER REMOVAL
REFERENCE
AL
.AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
ChOx
*BT
TF
TF
TF
TF
Bench
Pflot
Pilot
Pilot
Full
FuH
Full
Full
Full
Full
Pilot
Pilot
Fuซ
Pilot
Bซnch
Full
Pilot
Bench
Full
Full
Full
Pilot
Pilot
871D
203A
203A
24QA
IB
8758
1B
2018
1B
IB
204A
203A
6B
241B
1050E
6B
203A
975B
948
IB
IB
203A
240A
10
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
194000
0-100
0-100
0-100
0-100
11
11
12
6
4
2
8
9
a
11
31
11
6
6
11
5
3
11
11
6.000
14.000
.44.000
8,000
4.000
3.000
6.000
3.000
5.000
10.000
2.700
7.000
13.000
17.000
2.400
30.000 ,
47.000
3.000
13.000
6.000
20.000
82.000
16.000
99.5
81
40
91.4
91.7
87
94.4
93.5
93.8
87
93.9
90.4
96.8
96
99.4
98.7
36
87
92.6
70
29
81
1 Data ueed In developing revised Undard.
A-62
-------
Di-n-octvl Phthalate. The treatment performance data available for di-ri-
octyl phthalate were compiled from the NPDES and WERL databases and are presented
in Table A-31. Technologies for which treatment performance data are available include
AL, AS, BT, ChOx, and PACT*. The treatment performance data represent bench-,
pilot-, and full-scale studies. The resulting effluent'concentrations ranged from 3 ppb to.
47,000ppb.
The revised BDAT for di-n-octyl phthalate is AS (activated sludge
biological treatment). AS was selected as BDAT because it represents full-scale
treatment with a high influent concentration and a high removal efficiency. The revised
BDAT treatment standard for di-n-octyl phthalate was calculated using the effluent
concentration of 3 ppb and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for di-n-octyl
phthalate (0.017 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJO-40NW
0322-01 .bJs-63 A-63
-------
TABLE A-31
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DktOCTYL PHTHAIATE
RANGE AVERAGE
DETECTION MFLUENT NO. Of EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE FACILITY fepb) fopb) POINTS 6>pb) (K) f%) REFERENCE
1
.
- AL
AS
AS
AS
BT
. ChOx
PACT
'
Bench
Full
Pilot
Full
FuH
Bench
Bencii
MA0005304
LA0065501
LA0066214
MS0001B70
OH0002445
WI0044636
NY0004138
OH0002445
371D
IB
204A
IB
LA0036245
975B
975B
i V
*
.'-
100CK10000
0-100
0-100
100-1000
1000-10000
1000-10000
21
1
6'
15
1
, ซ
1
'5 -
1
' " 8. '
8
1
38
0.810
WBW ,
10.000
10.000
110.000
8.717
47000.000
' 48.000
44100
48.000
12.000
4.BOO
8.000
9481
360.000 '
3.000
87.8
79
83
98.6
80
98.75
NPDES
nr Wi*9
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL :
WERL*
NPDES
WERL
WERL
* Data used In developing revised standard.
A-64
-------
Ethvlbenzene. The treatment performance data available for ethylbenzene
were compiled from the WERL database, BDAT Solvents Rule data, and PACT8 and
WAO data from literature. These data are presented in Table A-32. Technologies for
which treatment performance data are available include AL, AL + AS, AS, API 4- DAF
+ AS, AS + FU, Airs, Airs + GAC, BT, CAC, GAC, PACT* RO, SS, TF, and WQx.
The treatment performance data represent bench-, pilot-, and full-scale studies with
resulting effluent concentrations ranging from 0.100 ppb to 30,000 ppb.
1, ' p ' '
]
t The revised BDAT for ethylbenzene is BT (biological treatment). 'BT was
selected as BDAT because it represents full-scale data developed from HAD sampling
'and was used as part of the BDAT Solvents Rule. Furthermore, the effluent
concentration achieved by this technology is supported .by similar effluent concentrations
reported from the WERL activated sludge treatment performance data. The proposed
revised BDAT treatment standard for ethylbenzene was calculated using the effluent
concentration of 10 ppb and the appropriate accuracy correction factor and variability
factor. The calculation of the resulting BDAT treatment standard for ethylbenzene
(0.057 ppm) is described in Section 6.0 and is shown in Table 6-1. ' ..
BKMONW , .
0322-01.bป .65 A-65
-------
TABLE A-32
(
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ETHYL BENZENE
TECHNOLOGY
. AL
AL
AL
AL+AS
API+DAF+AS
AS
-''AS
AS ~
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY
SIZE
Pilot
Pilot
Fun *
FuO
FuO
Bench
FuO
Pilot
FuO
FuO
POot
FuO .
FuO
FuO
Bench
FuO
Fun
FuB
Futt
Fun ',-.-
Pilot
Fun
FuH
Fun
FuO
Fun
Fun
Fun
Pilot
Pilot
Fun'
FuO
FuO
Bonclt
FuO
Fun
FuO
Fun
FuO .
Bench
DETECTION
UMrr
FACtUTY (ppb)
203A
203A
18
233D
1482D
200B ,
201 B
206B .
68 '
238A
240A
68
234A
234A
202D
68
975B i
18
.9758 .
1B
2418
IB
IB
IB
IB
68
IB ,
975B
203A
REF2
IB
1B
1B
200B
6B
6B
68
18
6B
200B
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
100-1000
0-100
1000-10000 .
10000-100000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
. 0-100
0-100
10000-100000
1000-10000
1000-10000
0-100
100-1000
0-100
100-1000
0-100
0-100
0-100
0-100
1000-10000
0-100
0-100
100-1000
23500
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
10000-100000
100-1000
NO. OF
DATA
POINTS
14
14
4
21
4
6
16
20
3
3
14
24
4
6
4
5
3
5
4
5
3
3
14
6
6
3
- 4
9
7
15
29
. 4
7 "
12
AVERAGE
EFFLUENT
CONCENTRATION
(ppb) .,
12.000
27.000
10.000
4.000
3400
0.700
6.000
0200
10.000
0.500
1.000
10.000
0200
0200
80.000
10.000
8.000
9.000
10.000
3.000
5.000
5.000
1.000
1JOOO
5.000
25.000
3.000
8.000
6.000
366.000
.4.000
2.000
1.000
0.500
10.000
10.000
iaooo
8.000
10.000
0.600
RECOVER REMOVAL
<*) (K)
89
76
69
9923
99.98
90.89
924
99.76
982
972
98.4
94.4
99.14
9922
99.87
99.47
99.6
90.7
98.4
89
97.6
89
98.1
97.7
79
98.7
95.4
87
94.6
97JS
9926
99.17
99.5. .
97.9
. 98.9
97.4
89
99.97
99.5 _
REFERENCE
WERL
WERL
WERL .
WERL
WERL
WERL
WERL:
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL.
WERL
WERL
WERL
WERL
WERL
WERLdp^^
WEP^^HI
WERn^^F
WERL
WERL
WERL
WERL
BOAT*
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
# EAD Data presented In the BOAT Solvent* Rule F001-F005 Background Document
A-66
-------
TABLE A-32 (Continued}
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ETHYL BENZENE
RANGE AVERAGE
DETECTION MFLUENT NO. OF EFFLUENT
. , TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE , FACILITY (ppb) (ppb) POINTS (ppfa) (%) (%) REFERENCE
AS+Ffl .
AliS
AlfS
AirS+QAC
BT
' *BT.
BT
BT
BT
BT
*BT
BT
BT
BT ,
" *BT
BT
BT
, 'BT
CAC
GAC
PACT
PACT
PACT
^JJACT
^^BBO
^ ^^^Pto
^^^K>
ss .
TF
TF
TF
TF
UF
WOx
WOx
. WOx[B]
WOx[BJ
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
FuU
Bench
Bench
Bench
Bench
PDot
Pilot
Full
Pilot
Pilot,
Pilot
Full
Full
Pilot
Full
Full
Bench
Bench ,
.68-'
224B
69A
22BA
P211
P234
P221
P293
P238
P215
P242
P244
P257
P202
P230
P298
P251
P253
203A
1421 D
242E
ZImpra
2MB
Zbnpro '
' 180A
'" 2MB '
' 2SOB
REF2
240A
203A
1B
1B
. 250B
Zlmpre SO
242E
1054E
1054E
0-100
0-100
0-100
0-100
1292340000
1O4B50
10-140
2287-3565
ypQjyfliffl
. 564-4150
190553
606
63-3848
96-506
101*3040
22-230
1235-1360
10-144
100-1000
0-100
0-100
165
0-100
21
0-100
0-100
1000-10000 .
23500
0-100
- 100-1000
. 100-1000
0-100
100-1000
1900047000
1000-10000
100CV10000
" 100000-1000000
15
1
19
7
33
3
2
' 2 .
3
2 -'
1
27
20
15
16
3
- .'2
14
1
11
. 1 "'
5
14
14
'- 4
4
2
. -
10.000
0 JBOQ
0.300
1^00
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
12.000
10.000
. 10.000
10.000
10.000
10.000
73.000
0.100
6.000
1.000
0.400
5.000
0.020
5.000
170.000
208.000
.1.000
31.000
11.000
4.000
70.000
3550.000
21.000
500.000
30000.000
90
914
94.1
60
V
34
37
76
69.5
9957
76 ,
N 71
92ฃ
97
. 96.4
72
-K 90*
' 904
59
.'
99.65
94.6
97
WERL
WERL
WERL
WERL
BOAT**
BOAT*-
BOAT**
BOAT*4
BOAT**
BOAT**
BOAT**
BOAT**
BOAT*.
BOAT**
BOAT(M
BOAT**
BOAT**
BOAT**
WERL
WERL
WERL
WAO
WERL
WAO
.WERL
WERL
WERL
BOAT
"WERL
WERL
WERL
WERL
WERL
WAO
WERL
WERL
WERL
* EAD Data prevented In the BDAT Solvent* Rule F001-F005 Background Document
* Data used In developing revived standard.
A-67
-------
Fluoranthene. The data available for fluoranthene were compiled from the
BAD and WERL databases. These data are presented in Table A-33. Technologies for
which treatment performance data are available include AL, AS, AS+Fil, CAC, ChOx,
BT, PACT", RO, and TF. The treatment performance data represent bench-, pilot-, and
foil-scale studies. . .
* . ' '
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD. limit.
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry.
BDAT for fluoranthene is being revised to BT (biological treatment). The
revised BDAT treatment standard was calculated using the BAD median long-term
average .effluent value of 11.533 ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for fluoranthene (0.068 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BKMONW -
0322-01 .bfc.68 - A-O5
-------
' . TABLE A43
WASTEWATER TREATMENT PERFORMANCE DATA
. FORFLUORANTHENE
^M DETECTION
^H^ TECHNOLOGY UMTT
TECHNOLOGY SIZE FACILITY (ppb) -
AL
AL
AS
AS
AS ' '
AS
, AS
AS
AS
AS
'As+ni
CAC
CAC
ChOx(CQ :
Fil
Fa
Fil
Fil
*BT
- PACT
RO
TF v.
TF
TF
TF
.TF
Pflot
Pilot
Full
Full
Pilot
Full
Full
Pilot
Full
Pilot
FuN
Pflot
PUot
Full
PBot
Pilot
Full
Full
Full
Bench
PUot
Pilot
Full
Full
Full .
PUot
'
. 203A
203A
37SE
375E
204A
375E
68
240A
375E
203A
6B
185B
203A
1081 D
185B
577E
10610
782E
1283 10
87SB
1634E
203A
375E- ,
375E
- 1B
240A
RANGE - AVERAGE
WFLUENT NO. OF EFFLUENT
CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL , \
(ppb) POINTS toeb) 00 (K) REFERENCE
. 100-1000
100-1000 ,
0-100
0-100 .
0-100
0-100
1000-10000
0-100
6-100
100-1000
1000-10000 .
1000-10000
100-1000
. 0-100
100-1000
0-100
0-100
'1000-10000
888*141
0-100
0-100
100-1000,
0-100
0-100
0-100
0-100
11
ij
7 ,
7
8 '
1
14
.12
7
11
3
8
11
8. ' "'
4
15
11
7
7
4
11
' - i
38X100
23X100
0.041 ,
0.048
1.900
O038
12.000
8.000
0.029 '
, 6.000
16.000
170.000
13.000
a045
110.000
0.001
0.061
8.000
11.600
3.000
0.007
49.000
0.029
0.044
12.000
14.000
65
,78
86.1
83.3
83.9
84.1
88.25
81.8
86.8
852
89.69
83.7
88
44
35
89.82
42
89.58
77
88
S3
87.1
96.3
69
85
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
EAD*
'WERL
WERL
WERL
WcRL
WERL
WERL
WERL
In developing revised ctvuivd.
A-69
-------
Fluorene. The data available for fluorene were compiled from the EAD
and WERL databases. These data are presented in Table A-34. Technologies for which
treatment performance data are available include AL, AS, BT, and TF and the treatment
performance data represent pilot- and full-scale studies.
The treatment performance data available from the EAD database were
' used to determine the revised BDAT treatment standard for this constituent for the .
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit.
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry.
BDAT for fluorene is being revised to BT (biological treatment). The
revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 10 ppb and the EAD Option 1 variability factor. The
s
calculation of the resulting BDAT treatment standard for fluorene (0.059 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BKMONW
0322-01 .bjg-TO . A-/U;
-------
TABLEA-34
WASTEWATER TREATMENT PERFORMANCE DATA
FORFLUORENE
TECHNOLOGY
TECHNOLOGY
SIZE
FACJUTY
' ' ' RANGE
DETECTION MFUUENT NO. OF
LIMIT CONCENTRATION DATA
fepb) (ppb) POINTS
, AVERAGE .
EFFLUENT
CONCENTRATION
(PPbl
RECOVER REMOVAL
REFERENCE
AS
AS
BT
TF
Full
Full
Pilot
FuH
Full
68
68
1283
IB
10
100-1000
1000-10000
. 0-100
678-1813
0-100
.9
13
6 '
15
4
.10.000
10.000
0.700
10.000
20.000
94.1
99.17
9B2
54
WERL
WERL
WERL
EAD*
WERL
' Data used In developing revived tandard.
A-71
-------
Hexachlorobenzene. The treatment performance data available for
hexachlorobenzene were compiled from the WERL database. These data are presented
in Table A-35. Technologies for which treatment performance data are available include
AS, AS+Fil, and GAG The treatment performance data represent full-scale studies.
The resulting effluent concentrations ranged from 0.01 ppb to 20 ppb..
The revised BOAT for hexachlorobenzene is AS+FiL (activated sludge
followed by filtration). AS+Fil was selected as BDAT because it represents full-scale
data with a high influent concentration and a high removal efficiency. The proposed
revised BDAT treatment standard for hexachlorobenzene was calculated using die
effluent concentration of 10 ppb and the appropriate accuracy correction factor and
variability factor. The calculation of the resulting BDAT treatment standard for
hexachlorobenzene (0.055 ppm) is described in Section 6.0 and is shown in Table 6-1.
BJO-40NW
0322-01-bjj.72
A-72
-------
' TABLE A-3S
f ปPT*^ite 9 ซM0
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOROBENZENE
TECHNOLOGY
TECHNOLOGY
SgE
FACmTY
RANGE
DETECTION MFLUENT NO. OF
UMfT CONCENTRATION DATA
(ppb) ' (ppb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVER REMOVAL
(K) (K)
REFERENCE
AS
AS
AS+Fil
GAC
Fun
Full
Full
Full
375E
375E
6B
237A
0-100
0-100
100-1000
0-100
7
7
14
1
OA10
0.010
10400
20.000
83
84.4
86.7
WERL
WERL
WERL'
WERL
* Data used in developing ravind standard.
A-73
-------
Hexachlorobutadiene. The treatment performance data available for
hexachlorobutadiene were compiled from the WERL database. These data are
presented in Table A-36. Technologies for which treatment performance data are
available include AS, AS+Fil, and GAC. The treatment performance data represent
pilot-scale and full-scale studies. The resulting effluent concentrations ranged from
10 ppb to 20 ppb.
The revised BDAT for hexachlorobutadiene is AS+Fil (activated sludge
followed by filtration). AS+Fil .was selected as BDAT because it represents full-scale
data with a high influent concentration and a high removal efficiency. The revised
BDAT treatment standard for hexachlorobutadiene was calculated using the effluent
concentration of 10 ppb and the appropriate accuracy correction factor and variability
factor. The calculation of the resulting BDAT treatment standard for
hexachlorobutadiene (0.055 ppm) is described in Section 6.0 and is shown'in Table 6-1.
BJCMONW . .
0322-01 .%.74 ' A-74
-------
TABLE A-96
WASTEWATER TREATMENT PERFORMANCE DATA
FORHEXACMLOROBUTADIENE
RANGE . AVERAGE
DETECTION WFLUENT NO. OF EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE FACtLTTY (ppb) (ppb) POINTS (ppb) flM fltt REFERENCE
AS
AS+Ftt '
AS+Fil
QAC
PHot
Full
Full
FuO
241 B
6B
68
237A
100-1000
100-1000
1000-10000 '
100-1000
11
2
14
1
18.000
10.000
10.000
20.000 '
862
92.8
99.6
62
WERL
WERL*
WERL*
WERL
* Date uซซd In developing revised ttandwd.
A-75
-------
Hexachlorocvciopentadiene. The treatment performance data available for
hexachlorocyclopentadiene were compiled from the NPDES database and WAO data
from literature. These data are presented in Table A-37. Technologies .for which
treatment performance data are available include bench-scale and full-scale studies. The
effluent concentrations of all the data documented ranged from 02 ppb to 15,000 ppb.
The revised BDAT for hexachlorocyclopentadiene is BT (biological
treatment). BT was selected as BDAT because it represents full-scale treatment
performance. The proposed revised BDAT treatment standard for
hexachlorocyclopentadiene was calculated using the effluent concentration of 10263 ppb
and the appropriate accuracy correction factor and variability factor. The calculation of
the resulting BDAT treatment standard for hexachlorocyclopentadiene (0.057 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BJCMONW
Q32241.tw.76
A-76
-------
TABLE/UP
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOflOCYCLOPENTADIENE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
RANGE
DETECnON MFLUENT NO. OF
LIMIT CONCENTRATION DATA
(ppb> (ppb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
_topb)
RECOVER REMOVAL
(%) (*)
REFERENCE
*BT
WOx
FuH
Bonon
LA006SS01
LA0066214
NY0107174
LA003824S
Zimpro
>10000000
6 '
1
IS
24
as
i
10.000
0.200
10.000
14)00
10^63
15000.000
99.8
NPDES
NPDES
NPDES
NPDES
NPDES*
WAO
' Data mod in developing revteod itondwd.
A-77
-------
Hexachloroethane. The treatment performance data available for -
hexachloroethane were compiled from the WERL database. These data are presented in
Table A-38. Technologies for which treatment performance data are available include
AS and AS+Fil. Data are available from pilot and full-scale studies. The resulting
effluent concentration for both studies was 10 ppb.
The revised BDAT for hexachloroethane is AS+FiL (activated sludge
followed by filtration). AS+Fil was selected as BDAT because it represents full-scale
treatment performance with a high removal efficiency. The proposed revised BDAT
treatment standard for hexachloroethane was calculated using the effluent concentration
of 10 ppb and the appropriate accuracy correction factor and variability factor. The
calculation of the resulting BDAT treatment standard for hexachloroethane (0.055 ppm)
is described in Section 6.0 and is shown in Table 6-1.
BKMONW
0322-OI.bjg.78 . A-78
-------
TABLE A-36
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOROETHANE
RANGE AVERAGE
DETECTION MFLUENT , NO. OF EFFLUENT .
TECHNOLOGY UM(T CONCENTRATION DATA CONCENTRATION RECOVER REMOVAL
TECHNOLOGY SIZE FACILITY (ppb) fopb) POINTS , tepbl (K) fX>) REFERENCE
AS ,
AS+FH
PHot
FuD
241B
68
100-1000
100-1000
It
14
10.000
10.000
87.1
83.8
WERL
WERL*
' Data usod in developing revised standard.
A-79
-------
' IndenofLZJ-cdlpwene. The treatment performance data available for
indeno(l,2,3-cd)pyrene were compiled from the NPDES and WERL databases. These .
data are presented in Table A-39. Technologies for which treatment performance data
are available include AS, BT, chlorination, and TF. All of the treatment performance
data represent full-scale studies. The resulting effluent concentrations ranged from
0.009 ppb to 28 ppb.
The revised BDAT for indeno(l,2ป3-cd)pyrene is AS (activated sludge-
biological treatment). AS was selected as BDAT because it represents full-scale
treatment performance with a high removal efficiency. The revised BDAT treatment
standard for indeno(l,2,3-cd)pyrene was calculated using an effluent concentration of 1
ppb (which represents the detection limit for indeno(l,2,3-cd)pyrene) and the
appropriate accuracy correction factor and variability factor. The calculation of the
resulting BDAT treatment standard for indeno(l,3,3-cd)pyrene (0.0055 ppm) is described
in Section 6.0 and is shown in Table 6-1.
BKWONW
.0322-01.bjf.80 A-OU
-------
TABLEAU
WASTEWATER TREATMENT PERFORMANCE DATA
FORWDENO(1A*00 In developing rwlMO tanovd.
A-81
-------
Naphthalene. The data available for naphthalene were compiled from the
BAD and WERL databases as well as WAO data from literature. These data are
presented in Table A-40. Technologies for which treatment performance data are-
available include AL> AS, AirS, CAC, ChOx, BT, PACT*, RBC, RO, TF, and WQx. The
. \ ' 'a - , -
treatment performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the BAD database were
used to determine the revised 8DAT treatment standard for this constituent for the
following reasons:
(1) The BAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by HAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. .
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit.
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both BPA and
industry. -
BDAT for naphthalene is being revised to BT (biological treatment). The
revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 10 ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for naphthalene (0.059 ppm) is
described in Section 6.6 and is shown in Table 6-1. .
B10-40KW
0322-01.bjg.82
A-82
-------
TABLEA-40
WASTEWATER TREATMENT PERFORMANCE DATA
FOR NAPHTHALENE
* .
TECHNOLOGY
TECHNOLOGY SIZE FACILITY
AL
AL
AL
AL
AL
AL+AL
AS
. AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
j^^fcAS
^^^fes
^^HirS
^^XAC
ChOx
*BT
PACT
, RBC
RO
TF
TF
TF
WOx
Pilot
Bench
Pilot
Pilot
Pilot
Full
Full
Full
Bench
Pilot
Pilot
Full
Pilot.
Bench
Pilot
Pilot
Full
Full
Full
Full
Pilot
Fun .
Full
Full
Pilot
j Bench
Pilot
Bench
Full
Bench
Pilot
Pilot
Pilot
Full
Pilot
Full
192D
371 D
192D
203A
203A
2330
201B
6B
1050E
* 241B
241B
. 975B
204A
2020
. 203A
240A
1B
IB
66
6B
192D
1B
6B
68
192D
1328E
203A
. 975B
1293
Zimpro
1920
180A
240A
1B
203A
Zimpro
RANGE
DETECTION WFLUENT
UMIT CONCENTRATION
(ppb) , (ppb)
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
' ' 0-100
1000-10000
. 100-1000
100-1000
0-100
100-1000
10000-100000
100-1000
0-100
. 0-100
1000-10000
100-1000
100-1000
10000-100000
100-1000
0-100
10 11227-37145
191
0-100
0-100
. v 100-1000
0-100
100-1000
6 1200
AVERAGE
NO. OF EFFLUENT '
DATA CONCENTRATION RECOVER REMOVAL
POINTS (ppb) (K) <*) REFERENCE
)
11
11
21
11
2
5
11
5
8
11
12
' 5 '
5
14
13
4
7
3
5
11
15
1
11
6
11
1
10.000
23.000
25.000
13.000
36.000
16.000
5.000
14.000 ,
2.000
8.900
10.000
1.000
0.700
10.000
4.000
6.000
9.000
10.000
10.000
10.000
10.000
3.000
10:000
10.000
' . 25.000 ' '
6200.000
79.000
2.000
10.000 A
1.000,
10.000
0.020 -
14.000
3.000
74.000
210.000
62
97.7
96.5
88
67
96.3
69
95.9
99.5
97.9
93
99.17
99.09
99.86
96 &
95
86
95.4
99.95
99
82
91.9
99.56
96
96.5
74
27
' *B
99J
82
80
86
69
32.
WERL
WERL
WERL
WERL
WERL : .
WERL
N WERL
WERL,
WERL
WERL . .
WERL
WERL '
-WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
EADซ
WAO
WERL
WERL
WERL
WERL .
, WERL
WAO
Data used in developing revteed ซUndard.
A-83
-------
Phenanthrene. The data available for phenanthrene were compiled from
the HAD and WERL databases. These data are presented in Table A-41. Technologies
for which treatment performance data are available include AL, AS, AS+Fil, CAC, BT,
PACT*, and TF. The treatment performance data represent bench-, pilot-, and full-scale
studies.
The treatment performance data available from the HAD database were
used to determine the revised BOAT treatment standard for this constituent for the .
following reasons:
(1) The HAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The BAD data were carefully screened prior to inclusion in the
. OCPSF database. These data were used in determining a "'
promulgated BAD limit. . ,
(3) A promulgated HAD limit represents data that have undergone .
further review, and have received acceptance by both EPA and '
industry. '.,'.'
BDAT for phenanthrene is being revised to BT (biological treatment).
The revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 10 ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for phenanthrene (0.059 ppm) is;
described in Section 6.0 and is shown in Table 6-1. . .
BJO^ONW
0322-01.bjj.M
-------
TABLE A-41
WASTEWATER TREATMENT PERFORMANCE DATA
FORPHENANTHRENE ,
TECHNOLOGY
TECHNOLOGY
SEE
FACOJTY
RANGE
DETECTION MFLUENT .NO. OF
LIMIT CONCENTRATION DATA
(bob) tob) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
foot)
RECOVERY REMOVAL
(%> ป)
REFERENCE
AL
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS+FU
CAC
Fll
ปBT
PACT
TF
TF
TF
Full
Pilot
Pilot
Pilot
Pilot
Full
Pilot
FuU
.BCflOn
Bench
FuU
Pilot
Full
Full
Full
Pilot
Pilot
FuU
6B
203A
203A
S71D
204A
240A
68
203A
18
1060E
68
203A
782E
1293
68
240A
203A
IB
10
100-1000
MOO
0-100
100-1000
0-100 .
0-100
1000-10000
0-100
0-100
100-1000
100-1000
1000-10000
0-100
0-100
20354711
100-1000
0-100
0-100
100-1000
6
11
11
8
12
14
11
4'
5
8
11
4
15
10
10
11
6
10.000
40.000
16.000
18.000
1.100
6.000
10.000
4.000
18.000
10.000
8.000
17.000
24.000
10.000
10.000
25.000
8.000
51.000
17.000
82.9
58
83
88.5
83
88.7
86.8
82
862
88.5
88.8
75
85
864
80
46
813
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL.
WERL
WERL
BAD*
WERL
WERL
WERL
WERL
Data used in developing revised ttandard.
A-85
-------
Phenol. Treatment performance data for phenol were compiled from the
HAD, BOAT, and WERL databases as well as WAO data from literature. These data
are presented in Table A-42A In addition, leachate treatment performance data was
submitted by industry and are presented in Table A-42B. Technologies for which
treatment performance data are available include AL, API+DAF+AS, AS, ChOx, GAC,
BT, LL, LL+SS, LL+SS+AC, PACT*, RBC, RO, SBR, SS, TF, WOx, AS+Fil, and
Anff. The treatment performance data represent bench-, pilot-, and full-scale studies.
' ' . '
The revised BDAT for phenol is BT (biological treatment). BTwas
selected as BDAT because it resulted in substantial treatment of phenol. The revised
BOAT, treatment standard for phenol was calculated using the effluent concentration of
10 ppb and the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for phenol (0.039 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BJO-40NW . -,
0322-01.bjg.86 . . . ' A-OO
-------
TABLE A-I2A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR PHENOL
^Br RANGE AVERAGE
DETECTION MFLUENT NO.OF EFFLUENT
TECHNOLOGY UMfT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SIZE FACILITY (ppb) toott POINTS feoW (%> OU REFERENCE
AL
AL
AL
AL
API+DAF+AS
AS
AS
AS
AS
AS , .
AS
AS
, AS
AS
' AS
AS
AS
AS
AS
AS
AS
AS
'AS
AS
^jc
^L^H
^^^F
AS
AS
AS
AS
AS
AS
AS
. AS
AS
AS ,
. AS
AS
AS+Fn
AS+FU
, Pilot
Pilot
Full
Wot
Full
Full
FuH
Bvnch
Full
Fun
Pilot
Fun
FuD
Full
Full
Fun
Fun
Fun
Bench
Pilot
Full
FuU
Full
Pilot
Full
Full
Full
Full
FuN
Full
Pilot
Fun
FuU
PPot
Pilot
Full
Bench
Full
Full
Full
FuU
203A
203A
68
192D
1482D
18
IB
2020
68
18'. ' <
203A
2018
1B
. 88
18 '
18
9758
18
1054E
240A
68 .
1122E
68
2418 .
68
975B
68
IB
IB
68
2268
9758 <
68
204A
192D
68
1054E
68
IB
' 68
68
100-1000
100-1000
100-1000
.100-1000
100-1000
100-1000
0-100
1 OOOOCH 000000
100-1000
100-1000
100-1000
100-1000
100-1000
10000-100000
100-1000
0-100
1000-10000
.100-1000
1 OOOOCH 000000
0-100
100-1000
10000-100000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
0-100
100-1000
1 0OOOCH 000000
1000-10000
100000-1000000
100-1000
100-1000
1000-10000
10000-100000
100000-1000000
100-1000
10000-100000
100-1000
11
11
3
4
8
6
' 39 '
6
11
31
6
3
6 .
3
. 8
11
7
/*
' '4
10
-
: 11
' 6
6
3
e i
'2
.0
4
i
13
6
3
18 .
,84.000
18.000
,11.000
10.000
.68.000
2.000
26.000 .
0.010
10.000
8.000
14.000 -.
20.000
1400
iaooo ,
81400
1400
MOO
1400
0.250
10.000
18.000
' 4000.000
120.000
8.000
21400
20400
iaooo
1400
1400 ,
10.000
, 800.000
160.000
10.000
14.000
10400 -
56.000 .
1000.000
10.000
25400
iaooo
10.000
33
86
904
9649
89.5
984
63
. 9949
96.4
97.2
89
92.6
89.89
99.94
92.4
96.4
99.87
99.33
99.88
90
96
952
974
97J2
99.64 '
67
96.3
99.44
96.3
96.6
99.95
f w*
99.99
94.6
9649
964
' 95
99.99
94.4
9948
98
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL -
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL .
WERL
WERL
WERL
WERL
WERL
WERL
A-87
-------
TABLE A-42A (Continued)
WASTEWATBR TREATMENT PERFORMANCE DATA
FOR PHENOL
RANGE
, : OETECTiON MFLUENT
TECHNOLOGY LIMIT CONCENTRATION
TECHNOLOGY SIZE _FACnJTY (ppb) (ppb)
AVERAGE
NO. OF 'EFFLUENT
DATA CONCENTRATION RECOVERY REMOVAL
POINTS (ppb) fltt ซtt REFERENCE
AnFF
AnFF
AnFF
AnFF
AnFF
' AnFF
AnFF
AnFFwQAC
. CAC
ChOx
ChOx
ChOx
GAC
GAC
GAC
*BT
UL
LL
LL+SS
LL+SS+AC
PACT
PACT
PACT
PACT
BBC
RBC
RO
SBR
SBR
SBR
SBRwPACT
SExt
ss
TF
TF
TF
TF
WOx
WOx[BJ
WOx[B]
. WOx IB]
Pilot :
Pilot
Bench
Pilot
Pilot
. Bench '
Pilot
Pilot .
PHot
Bench
BOflCn
Bench
Bench
Full
Full
Full
FuU
FuU
Full
Full
Bench
Bench
Full
Bench
Pilot
Pilot
FuU
Pilot
Pilot
Bench
Bench
Pilot
Pilot
Pilot
Full
Pilot
Full
Bench
Bench
Bench
Bench .
231A
231A
230A .
231A
231A
230A
. 235O
249D
203A
975B
975B ' ' -
975B
1064E
245B
237A
1293 10
K104 30^
K103 30
K103/K104 30
K103/K104 30
190E
975B
6B
975B
603E
192D
250B
1433D
2270
640
640
10B2E
1082E
- 203A
18
24QA
1B
Zimpro
1054E
1101D
236A
1000000
1000000
100000-1000000
100000-1000000
100000*1000000
. > 1000000
100000-1 000000
1000000
100-1000
100-1000
100-1000
1000-10000
100*1000
100-1000
1000-10000
698564-978672
150000400000
15000004000000
1500004000000
1500004000000
10000*100000
> 1000-10000
1000-10000
1000-10000
100000*1000000
100-1000
1000-10000
10000-100000 '
100000^1000000
10000^1000000
100000-1 000000
>1 000000
100000-1000000
100-1000
100-1000
0-100
0-100
10000000
1 0000^p*1 000000
> 1000000'
"" > 1000000
11
1
1
IB
6
5
s
4
3
16
1
11
6
10
6
1
1
700.000
30.000
10.000
10.000
70.000
1000.000
240.000
- 80.000
80*000
16.000
2400
1ZOOO
10.000
10400
6400
10.000
165000.000 21
84000.000 21
2400400 21
. 60.000 21
1400
2400
30400
6400
1700.000
10.000
120400
1000.000
1000.000
3000.000
1000.000
210000.000
160.000
64.000
47400
8.000
1400
OQQQQ 000
27000.000
3600.000
3000.000
69.88
9949
9847
9649
9948
9945
99.86
99.99
21
634
964
,8947
99
92.6
9949.
' . ,
9949
9946
984
9945
994
9649
934
97.7
99.81
99.63
8948
95.4
24
49
82
914
66.2
994
874
99.92
9947
WERL
. WERL
WERL
; WERL
WERL
WERL
WERL
.WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL '.'
BAD*
BOAT
BOAT
BOAT
BOAT
WERL
WERL
WERL
WEBIB^
W^B^B
WoB^PP
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
' WAO
WERL
WERL
WERL
' Data used in developing reviaed etendanl.
A-88
-------
WDUSTRY-SUBMTrTED LEACHATE TREATMENT PERFORMANCE
DATA FOR PHENOL
' . . DETECTION
TECHNOLOGY UMTT'
TECHNOLOGY SIZE FACILITY (ppb)
RANGE
MFLUENT
CONCENTRATION
(ppb)
AVERAGE
NO. OF EFFLUENT
DATA CONCENTRATION RECOVERY REMOVAL
POINTS (ppb) (%) (%) REFERENCE
DOW
10
71*2900
10.000
96.32 LEACHATE
A-89
-------
Phthalic Anhydride. No wastewater treatment performance data are
available for phthalic anhydride from any of the examined sources. However, leachate
treatment performance data representing biological treatment were submitted by industry
and are presented in Table A-43.
The revised BDAT for phthalic anhydride is BT (biological treatment). BT
'S " .''''.
was selected because it showed substantial treatment of phthalic anhydride and showed
average leachate effluent values greater than that of PACTฎ. The revised BDAT
treatment standard for phthalic anhydride was calculated using the effluent concentration
of 15 ppb and the appropriate accuracy correction factor and variability factor. The
calculation of the resulting BDAT treatment standard for phthalic anhydride (0.069 ppm)
is described in Section 6.0 and is shown in Table 6-1. ;
W
-------
TABLE A-43
MDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR PHTHAUC ANHYDRIDE
RANGE AVERAGE
DETECTION MFLUENT 'NO. OF EFFLUENT
TECHNOLOGY . UMfT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SIZE FACILITY fppb) tepb) POINTS (ppbl (%) fit,) REFERENCE
BT
Boneh
CWM
3
15.000
89.94 LEACHATE
A-91
-------
Pyrene. The data available for pyrene were compiled from the HAD and
WERL databases as well as WAO data from literature. These data are presented in
Table A-44. Technologies for which treatment performance data are available include
ALป AS, AS+FQ, CAC, ChOx, GAC, BT, TF, and WQx. The treatment performance
data represent bench-, pilot-, and full-scale studies. '',
The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: , . :
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit. .
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. . .
BDAT for pyrene is being revised to BT (biological treatment). The
revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 1133 ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for pyrene (0.067 ppm) is
described in Section 6.0 and is shown in Table 6-1.
BIO-WNW
0322-01 .bjg.92
-------
TABLE A-44 .
WASTEWATER TREATMENT PERFORMANCE DATA
FORPYRENE
RANGE AVERAGE
' DETECTION INFLUENT NO. OF EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SgE ^ FACILITY (ppb) (ppb) POINTS (ppb)' M) (*) REFERENCE
AL , Bปnch 3710 100-1000 11 15.000 07 WERL
AL Pilot 203A " 100-1000 11 36.000 65 WERL
AL Pilot 203A 100-1000 11 25.000 76 WERL
AS Pilot 203A . 100-1000 .11 S.OOO - 05.2 WERL
AS- Fun 1B 0-100 1 . 6.000 , 80 WERL
AS , Pilot 204A 0-100 8 2.000 . 03.3 WERL
AS Pilot 204A 0-100 12 10.000 00 WERL
AS Full 08 100-1000 14 10.000 09 WERL
AS+FU Full 0B 1000-10000 3 10.000 09.48 WERL
CAC Pilot 105B 1000-10000 0 110.000 . 04.5 WERL
CAC Pilot 203A 100-1000 11 12.000 . 08 WERL
ChOx(CS) -. Full 1081D " 0-100 0.018 , 00 WERL
Rl Pilot 105B 100-1000 8 80.000 27 .WERL
Fli Pilot 877E 0-100 , 0.001 00.08 WERL
Fil Full 1081D 0-100 , ' 0.045 40 WERL
Fป Full : 702E 1000-10000 4 6.000 09.5 WERL
QAC . , Pilot 105D .' 0-100 0 10.000, 70 WERL
*BT Full ' 1203 10 641-1438 15 ' 10.300 EAD*
TF Pilot 203A 100-1000 11 48.000 64 WERL
TF : Pilot 240A . 0-100 10 17.000 , 03 WERL
WOx Bench Zimpro 600000 1 260.000 09J5 WAO ,
uปed in devjoplng rซviปซd ttandmrd.
A-93
-------
1.2.4.5-Tetrachlorobeitzene. The treatment performance data available for ~
1,2,4,5-tetrachlorObehzene were compiled from the NPDES database and .are presented
in Table A-4S. Influent values were not available for the NPDES data and the NPDES
average effluent value was below the compound detection limit of 1.5 ppb. Therefore, it
t
.cannot be determined if this data represents treatment
\ : . .' ' -
i Treatment performance data were therefore transferred to this constituent
from the constituent judged to be most similar in elemental composition and functional
groups within the structure of the chemical. The constituent judged to be most similar to
1,2,4,5-tetrachlorobenzene (and used to transfer treatment performance data) was
hexachlorobenzene. The treatment performance data for hexachlorobenzene is
presented in Table A-36.. The resulting BDAT for 1,2,4,5-tetrachlorobenzene is AS+Fil
(activated sludge followed by filtration) and the BDAT treatment standard is 0.055 ppm
as described in Section 6.0 and shown in Table 6-1. - .
BIO-40NW
0322-01 .bjg.94
A-94
-------
TABlEA-45
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1 A4,5-TETRACHLOROBEN2ENE
RANGE . AVERAGE
DETECTION WFLUENT NO.OF EFFLUENT .
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SEE FACIUTY (rob) ^Jppb) POINTS (ppb)
-------
. 1.1.1.2-TetrachIoroethane. The 'treatment performance data available for
1,1,1^-tetrachloroethane were compiled from WAO data from literature and are
presented in Table A-46. The technology for which data were available was bench-scale
-PACT*. , . ' ', ' ' / ' ' -.-''
The revised BOAT for 1,1,1,2-Tetrachloroethane is PACT* (powdered
activated carbon treatment). PACT* was selected as BDAT because it represents data
with a high removal efficiency and the lowest achievable.effluent. The revised BDAT
treatment standard for 1,1,1,2-tetrachloroethane was calculated using the effluent
concentration of 10 ppb and the appropriate accuracy correction factor and variability
factor. The calculation of the resulting BDAT treatment standard for 1,1ป1,2-
tetrachloroethane (0.057 ppm) is described in Section 6.0 and is shown in Table" 6-1.
BJO-40NW
0322-01Jbjg.96
A-96
-------
: TABLEAU
\
WASTEWATER -mEATMEhTT PERFORMANCE DATA
FOR 1.1,1,2-TETRACHLOROETHANE
RANGE AVERAGE
DETECTION MFLUENT NO. OF EFFUJENT . _
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SIZE FACILITY teobl fepbl POINTS - tppb) fit) ซ%) REFERENCE
'PACT
Bench
Zimpro
10.000
72
WAO*
* Data usซd in developing proposed revteed ซtandvd.
A-97
-------
1.1.2.2-Tetrachloroethane. The treatment performance data available for
1,1,2,2-tetrachloroethane were compiled from the WERL and NPDES databases and are
presented in Table A-47. Technologies for which treatment performance data are
available include AS, AirS, BT, and GAG The treatment performance data represent
bench-, pilot-, and full-scale studies. The resulting effluent concentrations ranged from
0.0005 ppb to 11,000 ppb.
The revised BDAT for 1,1,2,2-tetrachloroethane is GAC (granular
activated carbon). GAC was selected as BDAT because of its full-scale treatment
performance with high influent concentrations and a high removal efficiency. The
revised BDAT treatment standard for 1,1,2,2-tetrachloroethane was calculated using the
effluent concentration of 10 ppb and the appropriate accuracy correction factor and
variability factor. The calculation of the resulting BDAT treatment standard for 1,1,2,2-
tetrachloroethane (0.057 ppm) is described in Section 6.0 and is shown in Table 6-1.
BIG-40NW - A OQ
0322-01 *jj.98 A-&B
-------
TABLE A-47
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1 A2.TETRACHLOR06THANE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
DETECTION
LIMIT
REFERENCE
NY0007M6
NJOQ28291
LA0066214
LA0065501
NJ0030392*
9
2
13
15
- 6
4
1J60
1.000
NPDES
AS
AS
AlfS
AirS
BT
*GAC
Full
Pilot
Pilot
Full
Fun
1B
1363E
710
LA003824S
2458
0-100
100*1000
100-1000
1000-10000
5.000
5.000
0.006
11000.000
3.000
4.600
41.000
&313
10.000
04.5
83.5
88
85.5
88.1
NPDES
NPDES
NPDES
WERL
WERL
WERL
WERL
NPDES
WERL*
* Data MM In developing r*vlซซd standard.,
A-99
-------
Tetrachloroethene. The data available for tetrachloroethylene were :
compiled from the BAD and WERL databases, BOAT Solvents Rule data, and PACT*
data from literature. These data are presented in Table A-48. Technologies for which
treatment performance data are available include AL, AS, AS+Fil, Airs, AnFF, BT,
CAC+AirS, ChOX, Chred, GAC, PACT*, RO, SS, TF, and WOx. The treatment
1 ' . \
performance data represent bench-, pilot-, and full-scale studies. -
* ' r '* *
. The treatment performance data available from the HAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
'''"'. ''.''.'
(1) The HAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by HAD include
long-term sampling of several industries; therefore, the Agency
' believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. , ' -,
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit. . .
(3) A promulgated BAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry. .
BDAT for tetrachloroethene is being revised to SS (steam stripping). The
revised BDAT treatment standard was.calculated using the BAD median long-term
average effluent value of 10.4 ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for tetrachloroethylene (0.056 ,
ppm) is described in Section 6.0 and is shown in Table 6-1.
BKHONW A inn
0322-01 Jqg.100 , A-1UU
-------
TABLEAU
WASTEWATER TREATMENT PERFORMANCE DATA
FOHTETRACHlJOROETHYLENE
TECHNOLOGY
At
AS
AS
AS
. AS - .
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
-
'
AhS
AlrS
AbS
.AliS
AltS
AiiS
AirS
AlrS .
AirS
AlrS
AirS
AtrS
AnFF
TECHNOLOGY
SEE
Futl
Fun
Full
Full,
Full
Fun
Full
Full
Fun
Full
Full
Full
Fun
Full
PBot
FuU
Full
Full .
Full
Full <
Full
Full
Fun
Full
Fun
FuU
Pilot
Pilot
Fun
Pilot
Pilot
Pilot '
Full
Pilot
Pilot
Pilot
Pilot
Full
Fun
PBot
Bam-h
UVIIbl 1
DETECTION
LIMIT
FACILITY fepb)
IB '
18
18
18
238A
1S87E ''
234A
238A
1B ' ,
234A
1B
IB
18
1B
2418
IB
2018
18
IB
IB
234A
IB
IB
18
68
6B ,
2218
71D
2238
222B '
2178
2078
69A
2208
2088
1363E
2148 .
1042E
3228
1362E
724D
RANGE
MFLUENT
CONCENTRATION
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
100-1000 .
1000-10000
0-100
0-100 *
100-1000
100-1000
0-100
0-100
0-100
100-1000
10000-100000
100-1000
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000 .
100-1006
1000-10000
10000-100000 :
NO. OF
DATA
POINTS
e
3
5
4
3
- 3
4.
6
5
8 '"
6
8
6 ' -
22
4
6 '
.
6
8
4
3
16
1
1
1
1
1
1
1
1
1
9
8 .
AVERAGE
EFFLUENT
CONCENTRATION
10.000
10.000
2.000
.000
2.100
0.870
22.000
1.600
1.000
. 3JOO
8,000
8.000
22.000
28.000
, 11.000
440.000
' 8.000
6.000
48.000
26.000
0.600
, 6.000
14.000
100.000
230.000
11.000
' asm
0.200
. OJBOO
. . 0.200
QJ30Q
.0300
OMO
0400
0^00
; o^oo
0.800
0.500
1.200
5.000
4.400
RECOVERY REMOVAL
(%) ซ)
' '80
'63
97.5
85
87
97.8
48
87
86
96.7
75
86.7
' 45
71
85J
65
89.8
93
79
78
95.9
65
74
83
99.04
97.7
964
96.7
99.43
94.3
99.73
98.3
96.4
ป 96.76
99.17
97.1
99.31
99.71
99.75
99.74
9949
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL '
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
A-101
-------
TABLE A-48 (Continued) :
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TETRACHLOROETHYLENE
TECHNOLOGY
BT
BT.
BT
CAC+AifS
ChOx
ChOx
Chred
GAC
OAC
GAC
PACT
PACT
PACT
RO
RO
ss
ss
ss
. TF
TF
TF
TF
TF
TF
UVfB]
WOx
WOx
RANGE
, DETECTION MFLUENT
TECHNOLOGY LIMIT CONCENTRATION
SIZE FACILITY to*) ftปW
Futt
Fun
Fun
Full
Pilot
Pilot
Bench
FuH
Futt
Fun
Bench
Bench
Bench
Pilot
Pilot
FuH
FUJI
Fun
Fun .
Full
Full
Fun
Futt
Full .
Bench
Pilot
P22S
P260
REF4
1633D
2026A
2D26A
t - \
1264B
245B
237A
242E
Zirnpio
Zimpro
323B
180A
813 10
2518
68
IB
IB
IB
IB
1B
1B
1138E
REF10
78D
8841800
110-1746
62
0-100
0-100
0-100
250
0-100
1000-10000 .
100-1000
100-1000
304
136
0-100
. 0-100
10600-241000
1000-10000
10000-100000
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
41000
1000000
NO. OF
DATA
POINTS
18
12
1
. '7
4
'4
1
1
1
, 1
1
14
10
2
8
. 8
3
4
6
6
1
1
AVERAGE ^^
EFFLUENT
CONCENTRATION RECOVERY REMOVAL
(ODb) (K) . IK) REFERENCE
47.000
10.000
7.300
0.100
2.000
1.700
8.000
1.000
10.000
10.000
10.000
1.000
10.000
30.000
0250 ,
16.400
10.000
10.000
12.000
26.000
16.000
1.000
6.000
&000
7.500
x 1000.000
800.000
89
86
64
852
89.13
86.3
. 82.6 .
89.7
83
68
81
8929
88.85
> 81
83
84
86.8
82.7
84.3
85
89.88
BDAT1
BDAT1
BDAT1
WERL
WERL
WERL
ART
WERL
WERL
WERL
WERL
WAO
WAO
WERL
WERL
EAD*
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WEfiL^^
WEB^B
BD/^^V
WER^
# EAD data presented In the BOAT Solvent* Rule FOOI-f 005 Background Document
* Data uted In developing revised standard.
A-102
-------
Toluene. The data available for toluene were compiled from the HAD and
WERL databases, BDAT Solvents Rule data, WAO and PACT* data from literature,
and EPA WAO test data. These data are presented in table A-49. Technologies for
which treatment performance data are available include AL, AL+AS, API+DAF+AS,
AS, AS+Ffl, AirS, AirS+GAC, BT, BT+AC, GAC, PACT* RO, SS, SS+AC, TF,
WOx+PACI*, and WOx. The treatment performance data represent bench-, pilot-, and
full-scale studies.
, The treatment performance data available from the BAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
(1) The HAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
: industry and can adequately represent a wastewater of unknown
characteristics. . '
(2) The HAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated HAD limit.
(3) . A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and !
industry.. - .
BDAT for toluene is being revised to SS (steam stripping). The revised
BDAT treatment standard was calculated using the EAD median long-term average
effluent value of 10 ppb and the EAD Option 1 variability factor. The calculation of the
resulting BDAT treatment standard for toluene (0.080 ppm) is described in Section 6.0
and is shown in Table 6-1.
BJO-WNW
0322-6l.bjs.103 , . A-103
-------
Table A-49
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
RANGE
DETECTION MFLUENT
TECHNOLOGY LIMIT CONCENTRATION
TECHNOLOGY SIZE FACILITY (ppb) (ppb)
AL
AL
AL
AL+AS
API+DAF+AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS .
AS
AS
AS
AS
AS
AS
AS '
AS
AS
AS
AS
AS
AS
AS
AS
, AS
AS
AS
AS
AS
I
Full
Bench
Full
Fun
FuU
Bench
Full
, Full
Fun
.Fun
Bench
Full
Full
FuH
Full
Full
Fun
Full
Full
Pilot
FuU
FuU
FuH
FuH
Full
Full
FuH
.. Full
Full
Full
FuU
FuU
FuH
FuH
Full
Full
Full
Full
Pilot
68
371D
18
2330
1482D
JUUfcf*
4PUB0
68 ' '
6B . ' '
9758
68
2008
6B
18
68
68
9758
68
9758
68
2268
68
68
1B
9758
18
234A
IB
1587E
2018
IB
18
234A
18
IB
238A
68
18
IB
2418
t
100-1000
1000-10000
100-1000
1000-10000
10000-100000
10000-100000
10000-100000
1000-10000
1000-10000
. 10000-100000 .
100-1000
1000-10000
1000-10000
1000-10000
1000-10000
1000-10000
1000-10000.
100-1000
1000-10000
1 0OOOW 000000
100-1000
100-1000
0-100
100-1000
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
AVERAGE .. ^F
NO. OF EFFLUENT . , .
. DATA CONCENTRATION RECOVERY REMOVAL
POINTS (PDb) (%) <%) REFERENCE
3
6
21
4
3
3
3
10
' 24 '
6
15
3
,
7
33
7
14
4
5
6
4 ' .
' 32 ' ,
8
4
4
5
3
3
5
4 .
8
10.000
80.000
32.000
4.000
11400
10.000
73.000
10.000 .
12.000
76400
0400
10.000
, 9400
10.000
24.000
800-000
10.000
23.000
20.000
300.000
. 10.000
10400
4400
7400
4400
0.700
. 3400
0.100
87.000
12.000
1400
0200
4.000
2400
6200
10400
2.000
4400
4400
862
87
86.1
88.85
99.93
6948
9944
. 99.57
89.68
8940
- 994
/' 89.73
9941
99.88
86.76
964
894
86
894
9945
974
974
88
8644 -
89.48
97.1 .
804
89
, *
864
86 .
862
86.4
874
. 82.7
84.4
87.1
86
864
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL "
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
.WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WEBB^Bk
WE^^^B
WEnRlBW .
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
A-104
-------
Table A-49 Continued
\ ,
WASTEWATER TREATMENT PERFORMANCE DATA
FORTOLUENE
RANGE
, , DETECTION ' MFLUENT
TECHNOLOGY . LIMIT CONCENTRATION
TECHNOLOGY SIZE FACILITY (ppb) (ppb)
AVERAGE
NO. OF EFFLUENT
DATA CONCENTRATION 'RECOVERY REMOVAL '
POINTS (ppb) (K) <%j REFERENCE
AS
AS
AS.
. AS
AS
-'AS
AS
AS
AS
AS
AS
AS
AS
. AS + FU
AlrS
AlrS
AlrS
AlrS
AlrS
.AlrS '
AlrS
AlrS
*3AC
BT
Bt
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
FuU
Full
FuU
Full
Full
Full
Full
Full
Pilot
Full
Full '
Full .
Pilot
Fun'
Full
Pilot
Bench
FuH
Full
Pilot
Fun
Fun
Full
Full
Full
Full
Full
Fun
Full
Fun
, Fun
Full
Full
Full
Full
Full
FuH
Full
FuU
FuU
234A
IB
IB
IB
1B
234A
18
18
206B
1B
234A
1B
REF2
68
3SS2&
1362E
1328E
69A
322B
224B
3228
322B
229A .
P206
P211
P202
P244
P210
P223
P217
P234
P242
P221
P206
P240
P246
P251
P253
P257
P265
0-100 ;
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
, 100-1000
100-1000
100-1000
' flSOQO
10000-100000 '
100-1000 .
0-100
1000CMOOOOO
0-100
0-100
0-100
1000-10000
10000-100000
0-100
83447475
11544000
60-155
1109
135-5806 . ' '
90465
1200-1533
10423
140440
22700
77-12938
1584046060
66430
1730-12900
3775040000.
8
e
6 '
8
6
8
20
6
6
6
' 3
24
3
5
8
1
'6
3
19
10
7
20
1
2
3
3
'32' -
2
3
14
1
9
3 ' "
3
27
3
0200
3.000
' 20X00 .
1X00
1X00
0200
2X00
56.000 .
0.600
10.000
0200 *
31X00 :
. 23467.000
10.000
0X60 ;
1.700
- ' 2800.000
0X40
,2X00
0X00
34.000
114.000
5 1.000
1491.000
10.000
10.000
10X00
10.000
10.000 - :
73X00
21X00
10X00
10.000
10.000
; 10.000 :
630.000
10.000
103.000
12X00
10.000 ;
96X
. 94
89
97.3
874
97.7
96.3
93.8
99.76
964
99X
95.4
99X6
99.77
9&3
92.4
97
97.4
96X
99.18
99.33
., . *
' -
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BDAT*
WERL
WERL
WERL
WERL
WERL '
WERL
WERL
WERL
WERL
WERL
BDAT*
BOAT*
BDAT*
BOAT*
BDAT*
BOAT*
BDAT*'" '
Pljpl* Ir - .
BOAT*
BOAT*
BDAT*
BOAT*
BOAT*
BDAT*
BDAT*
BDAT*
BDAT*
BOAT*
* EAD data presented in the BOAT Solvent* Rule F001-F005 Background Document.
A-105
-------
Table A-49 Continued
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
TECHNOLOGY
BT
BT
BT
BT
BT+AC
QAC
QAC
.QAC
PACT
PACT
PACT
PACT
RO
RO
RO
ss
ss
ss
ss
ss
ss
SS+AC '
TF
TF
TF
TF
TF
TF
UF
WOx
WOx
WOx
WOx.
WOx
WOx
WOx
WOx + PACT
WOx ID]
WOx[b]
WOx p>]
W0x[b]
TECHNOLOGY
SIZE
Fun
Fufl
FuU
Fun
Fun
PIW
Fufl
Pilot
BWICtl
Bwicit
Otnoh
Bench
.FuH
PBot
Fun
Fun
Fun
POot -
Fufl
. Fun
Fun
FuU
Fun
Fun
FuU
,- Fun
Pilot
f-
Bench
Bench
Pilot
Fufl
FuU
Pilot
Pilot (
Bench
Bench
Bench
Bench
FACIUTY
P286
P21B
' P230
REF4
P246
435B
245B
REF7 .
200B
242E
Zimpro
Zimpro
2SOB
250B
2508
04152
68
68
04151
REF4
P246
P297
6B
IB
1B
1B
1B
18
2508
REF10
Zimpro
Zimpro
Zimpro
Zimpro
242E .
78D
Zimpro
780
78D
1054E
1054E
RANGE
DETECTION MFLUENT
LIMIT CONCENTRATION -
-------
1.2.4-Trichlorobenzcng. The treatment performance data available for
1,2,4-trichlorobenzene were compiled from the WERL database and are presented in
Table A-50. Technologies for which treatment performance data are available include
AFF, AS, BGAC, GAC, PACT* RO, and TF. The treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent concentrations
ranged from 0.02 ppb to 89 ppb.
. * - ' ;
The revised BDAT for 1,2,4-trichlorobenzene is PACT* (powdered '
activated carbon treatment). PACT* was selected as BDAT because this technology
represents full-scale treatment with a high influent concentration and a high removal
efficiency. The revised BDAT treatment standard for 1,2,4-trichlorobenzene was
calculated using the effluent concentration of 10 ppb and the appropriate accuracy
correction factor and variability factor. The calculation of the resulting BDAT treatment
standard for 1,2,4-trichlorobenzene (0.055 ppm) is described in Section 6.0 and is shown
in Table 6-1.
BIO-WNW *,ซ,
0322-01 J>jg.l07 Arl07
-------
Table A-50X
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1A+TOCHLOROBENZENE
RANGE AVERAGE ^^
. DETECTION MFLUENT NO. OF EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SIZE FACILITY fopb)
-------
. 1.1.1-Trichloroethahe. The data available for 1,1,1-trichloroethane were
compiled from the BAD and WERL databases, BDAT Solvents Rule data, and WAO
data from literature. These data are presented in Table A-51. Technologies for which
treatment performance data are available include AL, AS, AirS, BT, GAC, PACT*, RO,
SS, TF, and WOx. The treatment performance data represent bench-, pilot-, and full-
scale studies. ' .
^.
The treatment performance data available from the BAD database were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons:
i ' . '
' ' ' ' i .
' ' !
(1) The BAD data represent treatment performance data from the
, OCPSF sampling episodes. The data collected by BAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. .
(2) The BAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated BAD limit.
(3) A promulgated BAD limit represents data that have undergone .
further review, and have received acceptance by both BPA and
industry.
, ' V. ' ^ '
BDAT for 1,1,1-trichloroethane is being revised to SS (steam stripping).
The revised BDAT treatment standard was calculated using the BAD median long-term
average effluent value of 10 ppb and the BAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for 1,1,1-trichloroethane* (0.054
ppm) is described in Section 6.0 and is shown in Table 6-1.
BJO-40NW
O322-Ol.igg.109 . . A-109
-------
Table A-51
WASTEWATCT TREATMENT PERFORMANCE DATA
/ '.
RANGE AVERAGE
DETECTION MFLUENT NO. OF .EFFLUENT
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SIZE FACILITY (rob) topbV POINTS (ppbl (K) fltt
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
. AS
AS
AS
AS
AS
. AS
AS
AS
AS
AS
AS
' AS
AS
AS
AS
AS
FuU
Fun
Full
Full >
Full
Full
Full
Full
Full
Full
Full
Full
Full
FuH
Pilot .
Full
Full
' Full
Full
Full
Fun
, Fun
Full
Full
Full.
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Bench
Pilot
Pilot
IB
201 B
IB
234A
. 1B
1B
1B
1B
1B
6B
. 375E
1B
, 975B
234A .
206B
1B
1B
1B
1B
1B
. 234A
238A
234A
IB
236A
1567E
IB
375E
1B
1B
1B
241B
1B
1B
234A
. 2Q2D .
REF6
REF2
0-100 5 10.000
0-100
0-100000
1000-10000
1000-10000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
100-1000 ,
0-100
100-1000 a
100-1000
100-1000
0-100
0-100
100-1000
21.000
10.000
1200
850.000
9.000
10.000
10.000
12.000
10.000
14)00
124100
44)00
14)00
0 0200
64.000
5.000
30.000
6.000
28.000
0-100 - 1.300
0-100 3 ' 2200
0-100 1200
0-100 . , 3 24)00
0-100 3 2.900
100-1000 0270
. 100-1000 8 1004100
0-100 7 1.000
0-100 3 7.000
0-100 3 8.000
0-100 . 3 ZOOO
100-1000 . 8 84100
0-100 6 * 1.000
0-100 3 '44100
0-100 . 1200
100000-1000000 1600.000
237' ' .1 . 23.000
150000 8 486834100
90
79
89
9948
87
84
84
. 81
90
982
92.3
87
98.1
97.6
99.77
89
962
39
96
942
76
- 85
. 78
962
77
99.73
70
922
83 .
84
962
972
98.4
88
88
96.6
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WER^hv
WE^^^B
WER^^F
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BOAT*
BOAT*
* EAD data presented in the BOAT Solvent* Rule F001-F005 Background Document
A-110
-------
Table A-51 Continued
WASTEWATEH TREATMENT PERFORMANCE DATA
FOR 1,1,1-THCHLOROETHANE
RANOE
DETECTION INFLUENT
TECHNOLOGY LIMIT CONCENTRATION
TECHNOLOOY SIZE FACILITY (ppb) (ppb)
AVERAGE , .
NO. Of EFFLUENT '
DATA CONCENTRATION RECOVERY REMOVAL
POINTS (ppb) (K) mi REFERENCED
AirS
AirS
AirS
AirS
AirS
. AirS
AirS
AirS
AirS
AirS
AirS
AirS
BT'
GAC ,
GAC
GAC
GAC
PACT
PACT
PACT
RO
RO
RO
ซ.
TF
TF
TF
TF
UV[B]
WOx
WOx
WOx
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Full
Pilot
FuN
Bench
Fun
Full
Pilot
Bench ,
Bench
Bench
Pilot
Full
Pilot
Fun -
FuH
Full
Pilot
Full
Full
Full
Full
DWICfl
FuU
, fun
211B
207B
812E
, 222B '
812E
211B
1382E
812E
217B
205E
1344E
2186
P240
1362E
1264B
1264B
612E
, 242E
Zimpro
Zimpro ,
180A
2508
323B
2506
6B '' '
913 10
REF2 ,
1 37SE -
IB
1B
1B
1138E
REFtO
Zimpro 50
a486. '
0-100
0-100
1000-10000
100-1000
0-100
100-1000
1000-10000 '
100-1000
0-100
100-1000
100-1000
0-100
10415
10-100
0-100
100-1000
100-1000
100-1000
4970
405
0-100
100-1000.
0-100
100-1000
10000-100000
11900-35000
150000
0-100
0-100
100-1000
0-100
0-100
370000
6900-9600
100000-1000000
1
1
1
. . 1
3
1 >
1
3
*
^
,1
1
1
14
S
7
5
- 6
5
1
2
1.000
0.500
48.000
1.100
3.000
1.700
130.000
12.000
0.300
7.000
, 0.200
0.500
10.000
1.000 '
1.000
1.000
1.000
25.000
1.000
25.000
0.050
36.000
2JOQO
10.000
10.000
10.000
463.000
1.000
2.000
2.000
5.000
30.000
1000.000
.
400.000
96.8
87.5
.85.8
99.75
92.9
99.5
97.8
88 '
97
96.8
99.96
96.7
99.99
96.6 '
99.35
. 99.05
93.8
99.9
93J
98.2
95.6
.. 97.8
83.8
99.94
SO
82.6
96.3
922
40
" /
99.96
WERL
WERL
WERL
WERL
WERL
tftfCBt
went*
WERL
WERL
WERL
WERL
WERL
WERL
BOAT*
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WERL
WERL
WERL
WERL
WERL
EAD*
BOAT*
WERL
WERL
WERL
WERL
WERL
BOAT*
.WAO
WERL
# EAD data presented in thป BOAT Solvent* Rule F001-F005 Background Document
1 Data u>ed in developing revived etandeid.
A-lll
-------
Ll-2-TrichIoroethane. The data available for 1,1,2-trichloroethane were
compiled from the EAD and WERL databases and PACT* data from literature. These
data are presented in Table A-52. Technologies for which treatment performance data
are available include AS, PACT*, SS, and WQx. The treatment performance data
represent bench-, pilot-, and full-scale studies. .
The treatment performance data available from the EAD database, were
used to determine the revised BDAT treatment standard for this constituent for the
following reasons: '.-.
(1) The EAD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by EAD include
long-term sampling of several industries; therefore, the Agency
believes these data are representative of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics. .
(2) The EAD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining a
promulgated EAD limit. ,
(3) A promulgated EAD limit represents data that have undergone
further review, and have received acceptance by both EPA and
industry.
BDAT for 1,1,2-trichloroethane is being revised to SS (steam stripping).
The revised BDAT treatment standard was calculated using the EAD median long-term
average effluent value of 10 ppb and the EAD Option 1 variability factor. The
calculation of the resulting BDAT treatment standard for 1,1,2-trichloroethane (0.054
ppm) is described in Section 6.0 and is shown in Table 6-1.
BJO-40NW
0322-OU>aj.ll2
A-112
-------
Table A-52
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1 ^-TWCHLOROETHANE
'
UBIBWIlUr
TECHNOLOGY .' LMIT
.TECHNOLOGY 821 FACfUTY tob)
AS
AS';
AS
AS
AS
PACT
PACT
PACT
SCOx
ss
*8S
SS
SS
ss
SS
WOK
Fun
Pilot
Fun
Fud
Pilot
B0non
Btncn
Bwtch
Pilot
Fun
FuH
Fun
Fun
Fun
Fun
Full
68
206B
68
1B
2418
242E >
190E
Zfcnpio ' :
860
813 10
41 5T 10 '
88 '. :
68 ' -.
2518
2518
242E
RANGE
4 MFUIENT
OONCENTRATK
(ppb)
100-1000
100-1000
0-100
0-100
100-1000
0-100 ,
1000-10000
80
10000^1000000
4ifr26400
77^-14500
10000-100000
1000-10000
1000-10000
1000*10000
10000-100000
AVERAGE
NO. OF EFFLUENT
IN DATA CONCENTRATION RECOVERY REMOVAL
POINTS topb) , (%) m REFERENCE
3 '
20
3
3
. 8 .
1
14
18
2
8
10
10
--
' 18.000
28.000
104100
8.000
110.000
84100
4200
64)00
36.000
11^00
104100
10.000
, 10.000
10.000
5.000
30.000
97.1 .
n
80
88 '
84,
83
80.68
83
99.98
99.96
99.85
99.87
99.91
99411
WERL
WERL
WERL
WERL
WERL '
WERL
WERL
WAO
WERL
BAD*
EAD* '
WERL
WERL
WERL
WERL
WERL
1 Data wad In developing nvtod standard.
A-113
-------
Xylenes. Hie revised BDAT treatment standard for xylenes was
determined using the combined data of all three isbmers. The treatment performance
data available for xylenes were compiled from the NPDES and WERL database, BDAT
Solvents Rule data, and WAO and PACT* data from literature. These data are
presented in Tables A-53, A-54, A-55, and A-56. Technologies for which treatment
performance data are available include AS, AirS, FACT*, RO, GAC, and WOx. The
treatment performance data represent bench-, pilot-, and full-scale studies. The resulting
effluent concentrations ranged from 0.1 ppb to 20,000 ppb, with a detection limit
established at 0.5 ppb.
. i
The revised BDAT for xylenes is WOx (wet air oxidation). WOx was
selected as BOAT because the WOx and RO data were the only full-scale data available
.at the higher concentration ranges. Further examination of the available data revealed
that RO was not able to achieve the low effluent concentrations observed with the use of
WOx technology. The revised BDAT treatment standard for xylenes was calculated
using the average effluent concentrations of all data available from WOx full-scale
studies. This effluent concentration was determined to be 56 ppb. The resulting BDAT
' treatment standard for xylenes is 032 ppm as shown in Table 6-1.
BIO-40NW
032241.ljg.114
A-114
-------
TABLE A-53
WASTEWATER TREATMENT PERFORMANCE DATA
FOR1,2-XYlฃNE
T6CHNOLOOY
TECHNOLOGY
SIZE
FACILITY
RANGE
DETECTION WFLUENT NO. OF
LIMIT CONCENTRATION DATA
(ppb) (ppb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVERY REMOVAL
(%) (K)
REFERENCE
AS
AS
AlrS
PACT
PACT
RO
WOx
Full
B*nch
Pilot
NY0183628
15B7E
BtflCfi
Full
Full
224B
242E
Zbnpro
242E
0-100
100-1000
0-100
0-100 '
T*
10000-100000
10000-100000
15
1
196.330.
0.100
0400
0.500
8.000
8.000
300.000
79.000
98.6
992
93
93.7
94
97*
99,92
NPDES
WERL
WERL
WERL
WERL
WAO
WERL
WERL*
' Dซtซ u*ซd In devetoplna raviMd ซtandvd.
'
A-115
-------
TABLE A-84
WASTTEWATER TREATMENT PERFORMANCE DATA
FOR1.34CYLENE
TECHNOLOGY
TECHNOLOGY
SIZE
JACIUTY
RANGE
DETECTION MFLUENT NO. OF
LIMIT CONCENTRATION DATA
fepbl topb) POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
RECOVERY REMOVAL
Pt) (K)
REFERENCE
AS
AbS
GAG
PACT
PACT
WOK
FuH
Pilot
Fun
Bench
Bench
Full
NY0183628
1587E
224B
1421D
242E
Zbnpro
0-100
0-100
0-100
0-100
83 _
10000-100000
0.100
0.500
0.130
10,000
10.000
33.000
66.3
72
20'
70
70
99.7
NPDES
WERL
WERL
WERL
WAO
WERL*
* Date UMd in developing rcviMd ซUndwd.
-l 16
-------
'_-, TABLE AHป _
WASTEWATER TREATMENT WERFORMANE DATA
FOR1.4-XYLENE
W-
DETECTION
TECHNOLOGY , UMfT
TECHNOLOGY SIZE FACMTY (ppbl
RANGE AVERAGE
MFIJUENT NO. OF EFFLUENT
CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
tepM POINTS tepb) flt) M} REFERENCE
AbS
. QAC
,
POol
Fun
NY0183628
224B
1421D
/
3 ,
0-100 1
0-100
196.330
0.800
0.040
M
37
NPOES
WERL
WERL
A-117
-------
TABLE A-ซ
WASTEWATER TREATMENT PERFORMANCE DATA
FORXYLENE
. , RANGE ' AVERAGE
DETECTION MFLUENT, NO. OF EFFLUENT '
TECHNOLOGY LIMIT CONCENTRATION DATA CONCENTRATION RECOVERY REMOVAL
TECHNOLOGY SIZE FACtUTY teob) Jpptt POINTS (ppblflQ (%) REFERENCE
GAC
WOx
WOx
PBot
PBot
REF7
REF10
2mpro
140
21200
8385000
0.100
800.000
BOAT 9
BOAT*
98.8 WAO
# EAD data prwentod in the BOAT Solvปrrtป Rule F001-F005 BaeKgreund DoeummL
A-118
------- |