&EPA
United States . Solid Waste and
Environmental Protection . Emergency Response
Agency (5305W)
EPA630-R-97-026
NTIS: PB97-176911
April 1996
Best Demon strafed
Available Technology
(BOAT) Background
Document for Wood
Preserving Wastes:
F032, F034, and F035;
Final
U.S. EPA Headquarters Library s
.Mail code 3201
1200 Pennsylvania Avenue'
Washington DC 204pn
Printed on (taper that contains at lest 20 percent postconsumer fiber
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FINAL
BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BOAT)
BACKGROUND DOCUMENT
FOR
WOOD PRESERVING WASTES
F032, F034, AND F035
Michael Petruska
Chief, Waste Treatment Branch
Jose E. Labiosa
Project Manager
U.S. Environmental Protection Agency
Office of Solid Waste
401 M Street, S.W. (5302W) ..
Washington, O.C. 20460 .
April 15, 1996
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DISCLAIMER STATEMENT
The mention of commercial products or trade processes; their source or vendor; or their use in
connection with material reported herein should not be construed as either an actual or implied
endorsement of such products/services by the U.S Environmental Protection Agency.
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TABLE OF CONTENTS
•-.''.. • • • . . . - '' - Page
EXECUTIVE SUMMARY ..-...........;....:'. ix'
- * '' ' ."•••',
1.0 INTRODUCTION.... ...^ '.... 1-1 "
i •
1.1 Regulatory Background .....: 1-2-
.1.2 Summary - v. .,.-:-....:•.....;.- 1-4
1.3 Contents of This Document. . ., ;...'....-..-..'.. 1-7
2.0 LAND DISPOSAL RESTRICTIONS FOR F032, F034, AND F035 .2-1
2.1 Summary of Basis for Listing of Wood Preserving Wastes 2-1
2.2 Kev Points of Wood Preserving Waste Standards and How They Reflect.
• • ' LDR Goals . .',..'.,.. .....:... -.........".. 2-2 ,
3.0 DETAILED DESCRIPTION OF WOOD PRESERVING WASTESTREAMS ..:..... 3-1
3.1 Description of Wood PreservingLlndustry . ..'..,. 3-1
3.2 Raw Materials.. . .. •.. . . ".... .; ..3-2.
3.2.1 Pentachlorophenol (PCP) Preservatives . 3-3,
3.2.2 Creosote Preservatives " .......... 3-4 ^
3.2.3 Inorganic Preservatives 3-5 '
. , 3.3 Processes Generating Hazardous Waste Numbers F032. F034. and F035
-, •.......: :...... •..-.'.....-...•.,.. ...3-6
• 3.3.1 Conditioning Processes .. .......'.'... 3-6 . '
3.3.2 Typical Conditioning Processes Used Before Wood Preserving '
- ' :..'.,...................;.., : 3-9
3.4 Preservative Application Processes . '...:.'. 3-10
. 3.4.1 Pressure Treatment Processes :....... 3-11
3.4.2 Nonpressure Treatment Processes . ... .:,: 3-12
3.5 Wastestream Status Under Other Regulations :...'....... 3-14
•v '"^3.6 Wastestream Residuals ...,..: '........ '.'.. 3-15
3.6.1 Wastewaters •. .:........ ... . .' ., 3-15 -.
3.6.2 Process Sludges or Residuals ........ . • 3-17
. . 3.6.3 Treated Wood Drippage, Wash-Off Residuals, and Unused
, Preservative Formulations ...'......... 3-21 •
3.6.4 Cross-Contamination Residuals •.;-... 3-25
3.7 Quantities and Composition of the Wastestreams .....' 3-26
3.7.1 Quantity of Process Wastewater Generated by the Wood -
Preserving Industry ........ :. ... ... 3-26 x
3.7.2 Concentration of Constituents in Wood Preserving Process , ,
. . . Wastewaters . .. '. .- ='...-. :...'. 3-28 ,
3.7.3 Quantity of Process Sludges or Residuals Generated by the Wood
. . . Preserving Industry ,../... :. . 3^31
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3.7.4 Concentrations of Constituents in Wood. Preserving Process Sludge
or Residuals 3-32
I
3.7.5 Quantity of Drippage, Wash-Off, and Associated Residuals
Generated by the Wood Preserving Industry 3-36
3.7.6 Concentration of Constituents in Treated Wood Drippage, Wash-
' off Residuals, and Associated Residuals . ,: 3-38
3^8 Amenability of Wastes to Chemical Analysis . ... . . .v. 3-41
-3.8.1 Applicability of SW-846 Methods 3-41
3.8.2 Sample Preparation Issues '.. . 3-43
3.8.3 Addressing Potential Analytical Difficulties Determining PCDDs
and PCDFs in F032 Wood Preserving Wastes 3-44
; 3.9 Current Wood Preserving Waste Management Practices . 3-49
3.9.1 Reported Wastewater Management Practices ... .'•' 3-50
3.9.2 Reported Process Residuals Management Practices ........3-51
3.9.3 Reported Treated Wood Drippage Management Practices ... 3-51
4.0 BOAT TREATMENT STANDARDS FOR WOOD PRESERVING WASTES F032, F034,
ANDF035 ....'.... ..•....'.:' '. ' 4-1
4.1 Determination of BOAT Treatment Standards for F032. F034. and F035
; .,..._..: > ; 4-1
4.1.1 BOAT List Constituents Present in F032, F034, and F035 4-1
4.1.2 Regulated Constituents in F032, F034, and F035 '. .. 4-1
4.2 Identification of Best Demonstrated and Available Technologies (BOAT)
for Nonwastewaters . . ..'. , -. 4-3
4.2.1 Applicable Treatment Technologies for Nonwastewaters ..... 4-4
: 4.2.2 Demonstrated Treatment Technologies for Nonwastewaters . 4-10
4.3 Identification of Best Demonstration Available Technologies (BOAT) for
N' Wastewaters . . : 4-1 f
4:3.1 Demonstrated Technologies for Wastewaters 4-15
4.3.2 Identification of BOAT for Wastewaters , 4-15
4.4 Promulgation of Treatment Standards 4-17
4.4.1 Nonwastewaters ...;... 4-17
; 4.4.2 Wastewaters ..:..- • 4-18
4.5 Detailed Descriptions of Technologies Identified as BOAT . : 4-20
4.5.1 Slag Vitrification ,...'.'....'...:..! 4-20
, • - • 4.5.2 Stabilization/Solidification : -. 4-22
4.6 Detailed Description of Technologies Identified as BOAT for Wastewaters
' • ; . : . -4-24.
4.6:1. Biological Treatment 4-24
4.6.2 Chemically-Assisted Clarification 4-26
4.6.3 Steam Stripping . . . 4-28
4.7 ' Reuse. Reclamation, and Recycling Potential . .. ..4-29.
4.8 Pollution Prevention and Waste Minimization 4-30
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. • 4.8.1 Process Additions . .'. '. .'•...'. ....'. 4-30
4.8.2 v .Process Changes - 4-31-
4.8.3 Management Practices ,. ;• 4-32
4.8.4 Alternative Wood Preserving Formulations .....; 4-32
5.0 COMBUSTION TREATMENT STANDARD AS A COMPLIANCE ALTERNATIVE
FOR.DIOXIN/FURAN(D/F)INF032 .,./.... ,, -. ... 5-1
5.1 Combustion Treatment Standard Alternative ,....'. 5-1
5.2 Background . . .'. : ' , '.5-2
5.3 - Summary of Phase IV NODA for F032 ...'...:.. '. 5-4
5.4 Review of Major Comments on Phase IV NODA and Promulgation of a
. Modified Version of Suboption Three . . .". -: 5T5
5.5 Criteria and Procedures for Obtaining a Determination of Equivalent Treat-
ment that Mav Make a CMBST Treatment Standard Also Available for an
Incinerator Combusting F032 under a Part 265. Subpart O. Permit.. . 5:8
6.0 DEBRIS AND MEDIA CONTAMINATED WITH WOOD PRESERVING WASTES
. , •_[ ,'....• .; .;...-. : :....6rl
6.1 Land Disposal Restrictions Apply to Wood Preserving .. ., ... ....'.. 6-1
6.2 Major Comments on Soils and Debris to the Proposed Phase 4 Rulemaking
and EPA Notices oh the Available Data for Developing Treatment
Standards for Wood Preserving Wastes . 6-2
6.3 Overlap of Today's Treatment Standards and On-going Remedial'
Activities . . -. , 6-3
6.4 Regulation of PCDD and PCDF in F032 . .'..-! .6-4
6.5 UTS Limits and the Performance of Remedial Treatment Technologies 6-7
6.6 ' Potential Waivers or Variances from the Treatment Standards Promulgated
Today 6-13
7.0 REFERENCES .".. ......:......'..-..............." 7-1
8.0 ACKNOWLEDGEMENTS . '-...- 8-1
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LIST OF APPENDICES
Appendix A: Treatment Performance Data Base and Methodology for Identifying Universal
Treatment Standards for Constituents in Nonwastewater Forms of F032, F034,.
andF035 , , '' ' '.
' • ' '. *
Appendix B: Treatment Performance Data Base arid Methodology for Identifying Universal
Treatment Standards for Constituents in Wastewater Forms of F032, F034, and ;
• F035, .'..,..
Appendix C: Summary of Submitted and Other Available Treatment Performance Data for
Wood Preserving and Related Wastes
Appendix D: Comments Summary and Commentors to October 24, 1991, Advanced Notice of
Proposed Rulemakihg, Potential BOAT for Newly Listed Wastes From Wood
Preserving Operations
, Appendix E: Examples of Alternative Technologies Potentially Applicable for the Treatment of
Wood Preserving and Related Wastes
Appendix F: Federal Register Notices Concerning the Delisting of Petroleum Wastes for
Marathon Oil •
Appendix G: Guidance Memorandum: Assuring Protective Operation of Incinerators Burning ,
Dioxin-Listed Wastes .
• ' ••. •
1 i « \ '
Appendix H: OSWER Guidance for Obtaining Variances from the LDRs for Soil and Debris
s ' ' • '
Appendix I: Environmental Fact Sheet: EPA Issues Final Rules for Corrective Action '
Management Units and Temporary Units .. ,
Appendix J: 'Other Publications with Information Related to the Treatment of Wood Preserving
or Related Wastes .
Appendix K: Summary of Newly Submitted Data/Comments for Wastewater and
Nonwastewater Forms of- Wood Preserving Wastes F032, F034, F035
Appendix L: Overview of Data Cited by EPA for the Promulgation of Alternative Treatment
. Standard of CMBST
Appendix M: Expanded List of References Evaluated for Wood Preserving Wastes'
. iv
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4-3
4-4 ~
5-1
Compliance Treatment Alternative for Dioxin and Fiiran Constituents
inF032 Wastes , '.. . .... . /. . ..,:,.:
4-46
Proposed BOAT Treatment Standards for Wastewater Forms of F032,
F034, and F035, Wood Preserving Wastes . . ... > '..:.• -. 4-36 •
Compliance Treatment Alternative for Dioxin and Furan Constituents in .
F032Wastes '.....' .:. 5-6
VII
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LIST OE FIGURES
3-1.
•\
3-2
Flow Diagram of Pressure/Vacuum Treatment Processes
f ;•
Flow Diagram of Nonpressure Treatment Processes .. ..
3-89
3-90
Vlll
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LIST OF TABLES
ES-1, . Treatment Standards for Nonwastewater Forms of F032, F034, and
F035, Wood Preserving Wastes '. '...'..'.... xy
% i * * '
ES-2 . Treatment Standards for Wastewater Forms of F032, F034, and
• - • . F035, Wood Preserving Wastes xvii
ES-3 BDAT Treatment Standards for Wastewater Forms of F032, F034, ,
. and F035, Wood Preserving Wastes !....:.....,.,: . xix
1 , /
ES-4 * Compliance Treatment Alternative for Dioxin and Furan Constituents
inF032 Wastes -.. . .-.'•: ...,.,:...:." ' xxi
'1-1' _• Treatment Standards for Nonwastewater Forms of F032, F034, and
F035, Wood Preserving Wastes . . . .; : 1-9
1-2 Treatment Standards for Wastewater Forms of F032, F034, and
, F035, Wood Preserving Wastes .....: ' 1-11
1-3 Compliance Treatment Alternative for Dioxin and Furan Constituents
inF032 Wastes '. / .' '..... .' '..,.. 1-13
2-1 Constituents of Concern for Hazardous Waste Numbers F032, F034, and F034 2-4
3-1 -, Regional Distribution of Wood Preservation Facilities ....../......,.... 3-63
* f-~>," , ' s>~'
3-2 . Historical Constituents of Chlorinated Phenols ...'.. : . :. 3-64
-" • r '
3-3 Typical Compositions of Creosote, Coal Tar, and Petroleum Oil .......... .3-65
3-4 • Compositions of the Most Commonly Used Arsenate and Chromate
' .Preservatives • ... .^.; .. . • 3-66
' 3-5 Breakdown of Conditioning Methods by Preservative Type (RCRA 3007 .
Survey Data, 1984) ...... 3-67
3-6 Generation of Wood Preserving Wastes : , . . : 3-68
3-7 Concentrations of Listing Constituents and Other Significant Compounds
in Wood Preserving Wastewaters from Pentachlorophenol and/or Creosote
. Processes '. ... 3-69
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3-8 Concentrations of Listing Constituents and Other Significant Compounds
in .Wood Preserving Process Sludges or Residuals from Pentachlorophenol
Processes .......'.'.... 3-71
3-9 • Concentrations of Listing Constituents and Other Significant Compounds
in Wood Preserving Process Residuals from Creosote Wood Preserving
Processes .'...: V 3-74
'" * *
3-10 Concentrations of Listing Constituents in Wood Preserving Process
Residuals from Inorganic Wood Preserving Processes ... 3-76
i f
3-11 Concentrations of Listing Constituents and Other Significant
Compounds in Pentachlorophenol Preservative Solutions (Drippage) 3-77
' ' > ' * *
3-12 Creosote Composition, Percent 3-79
3-:13 Estimate of Constituent Concentrations of Total Metals, Inorganic-
treated Wood Drippage and Unused Preservative Formulations 3-80
3-14 Concentrations.of Polynuclear Aromatic Hydrocarbons (PAHs) in
Drippage from Wood Treated with Creosote 3-81
3-1.5 SW-846 Analytical Methods Applicable to Constituent Proposed
for Regulation in F032, F034, andF035 . . .'.'.. 3r82
3-16 , Analytical Methods Instrumentation 3-84
,' ' V . , . ' .
3-17 • , Reported Wastewater Management Practices in Use in 1984 at Surveyed
Wood Preserving Plants (RCRA 3007 Survey Data) ...'..: :..,... 3-85
3-18 Types of Wood Preserving Process Residuals Managed in 1984 at
Surveyed Wood Preserving Plants, by Preservative (RCRA 3007
Survey Data) :....... 3-86
3-19 Reported Management Practices for Wood Preserving Process Residuals,
by Preservative -.••••. '.....'. 3-87
3-20 . Reported Treated Wood Drippage Management Practices for Wood Preserving ,
Plants, by Preservative : 3-88
4-1 Constituents Proposed for Regulation in F032, F034, and F034 4-44
. \ ' • • . -
4-2 Proposed BDAT Treatment Standards for Nonwastewater Forms of F032,
F034, and F035, Wood Preserving Wastes ''.'.: 4-45
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EXECUTIVE SUMMARY
1 ' -1 '
. The U.S.'Environmental Protection Agency (EPA or the Agency).is promulgating Best -
Demonstrated Available Technology (BOAT) treatment standards for the regulation of listed
' * <" •
hazardous wastes identified in Title 40, Code of Federal Regulations. Section 261.32 (40 CFR v
26132) as F032, F034, and F035. These BD AT treatment standards are being promulgated in
accordance with the amendments to the Resource Conservation and Recovery Act (RCRA) of
1976 enacted by the Hazardous and Solid Waste Amendments (HSWA) of November 8,. 1984.
Compliance with these treatment standards is a prerequisite for land disposal, as defined in 40
• ' ' i
CFR Part 268. In 40 CFR 268.44, EPA supplies provisions that, if met, may justify granting a
variance from the applicable treatment standards/ In 40 CFR 268.6, EPA supplies provisions that,.
if met, may justify granting waste- and site-specific waivers from the applicable treatment
standards in 40 CFR 268.40. -'•'.. ' • . ''''..-
Hazardous Waste Numbers F032, F034, and F035 are generated during the application of
a preservative to wood to prevent .damage from weather, insects, and fungi. They are:
F032 -Wastewaters, process residuals/preservative drippage, and discarded spent
formulations from wood preserving processes at facilities that currently use or
. have previously used chlorophenolic formulations (except waste from processes .
that have complied with the cleaning or replacement procedures set forth in
§261.35 and do not resume or initiate use of chlorophenolic formulations). This
' listing does not include K001 bottom sediment sludge from the treatment of
wastewater from wood preserving processes that use creosote and/or
-•pentachlorophenol. . . . :
^034 - Wastewaters, process residuals, preservative drippage, and discarded spent
formulations from wood preserving processes that currently use creosote
formulations. This listing does not include K001 bottom sediment sludge from the
treatment of wastewater from wood preserving processes that use creosote and/or
pentachlorophenol. \.
•• • t '
F035 - Wastewaters, process residuals, preservative drippage, and discarded spent
formulations from wood preserving processes that currently use inorganic
preservatives containing arsenic and chromium. This listing does not include K001
bottom sediment sludge from the treatment of wastewater from wood preserving
processes that use creosote and/or pentachlorophenol.
ix •
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This background document provides the Agency's rationale and technical support for
developing BDAT treatment standards for F032, F034, and F035 under the Land Disposal
Restrictions (LDR) program. This document also provides waste characterization data that may:
serve as a basis for determining whether a variance from the applicable treatment standards is
' - \
warranted for a particular type of wood preserving waste thatmay be-more difficult to treat than
the wastes on which the promulgated treatment standards are based.
The treatment, standards promulgated for these wood preserving wastes are the same
universal treatment standards (UTS) that apply to the same regulated constituents in other
hazardous wastes listed in the 40 CFR 268.40. See Table ES-1 for a list of each regulated
constituent in F032, F034, and F035 and the Chemical Abstract Service.classification number
(CAS No.) of each hazardous constituent of concern, if available. Tables ES-2 and ES-3
summarize universal treatment standards (UTS) limits promulgated for all the specific hazardous
constituents regulated in F032, FQ34, and F035. The treatment performance data base and
methodology employed for identifying the nonwastewater universal treatment standards are found
in Appendix A. The treatment performance data base and methodology employed for identifying
the wastewater universal treatment standards are found in Appendix B.
It should be noted that the proposed rule and the BDAT Background Document for Wood
i ,
Preserving Wastes did have several typographical errors with regard to the numerical limits or the
constituents proposed in F032, F034, and F035. EPA issued a correction notice to the proposed
Phase IV rule (see 60 FR 546451) to clarify the typographical errors discovered in the proposed
treatment standards for wood, preserving wastes. For instance, EPA clarified that the treatment
standards for wastewater forms of 2,4-dimethylphenol and 2,3,4,5-tetrachlbro-phenol should have
appeared as 0.036 mg/1 and 0.030 mg/1, respectively. These are the levels being promulgated in
this final rule. The correction notice also acknowledged that in the .proposed Phase IV rule the
constituents and treatment standards that appeared in the regulatory tables were inconsistent with
the preamble language. In the correction notice, EPA directed commenters to the summary table
! . • ' . ^ . . .
in the preamble language rather than the regulatory tables. The correct standards are promulgated
today which can be found in the regulatory Table 268.40 revisions published in today's rule.N
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EPA is also noting today that the Proposed BDAT Background Document for Wood
.Preserving Wastes was.in error with regard to the proposed treatment standards for wastewater
forms of 2,4-dimethylphenol, 2,3,4,6- tetrachlorophenol, and pentachloro-di-benzofiirans. The
1 . i- • ••
background document had typographical errors in the proposed limits for 2,4-dimethylphenol,
2,3,4,6-tetrachloro- phenol, pentachlorophenol, pentachlordibenzofuran, and arsenic. These limits
were inconsistent with the UTS limits published in the Final Best Demonstrated Available
Technology fBDAT) Background Document for Universal Treatment Standards Volume B:
Universal Treatment Standards for Wastewater Forms of Listed Hazardous Wastes (July 1994).
i
EPA is thus promulgating the applicable UTS limits for these specific four constituents of concern
. • • • • ' ^- .
in this BDAT Background Document in accordance with those limits published in the UTS BOAT
Development Document (Volume B). . -
EPA is also promulgating a compliance treatment standard alternative of combustion ~
• s . • -
"CMBST" — in response to several commenters who asked EPA to consider adopting such an
alternative treatment standard for the regulation of Dioxin and Furan (D/F) constituents in F032.
Under this alternative compliance treatment standard, EPA is setting combustion as the treatment
standard for specific dioxin and furan (D/F) constituents in F032 that are treated via combustion
and thus, the monitoring of each regulated D/F constituent is not required as a prerequisite to land
disposal. Under this compliance treatment alternative, the specific UTS numerical limits of other
regulated organic and metal hazardous constituents in F032 must be met as a prerequisite to land
disposal. (See May 10, 1996 (61 F.R. 21418).) In addition, EPA is limiting the promulgated
* ' . • '
compliance treatment alternative standard to F0"*2 wastes that are combusted in interim status
combustion units regulated under 40 CFR Part 266 or in a Part B permitted combustion devices
operated under 40 CFR Part 264, Subpart 0. Therefore, residues arising from the combustion of
V " " ,
F032 and F024 in interim-status combustion units operated under 40 CFR Part 265 will have to"
meet applicable numerical limits for D/F prior to disposal unless the facility combusting F03 2
obtains from EPA a treatability variance of equivalent treatment pursuant to the 40 CFR 268.42
(b). The treatability variance application should emphasize to what extend the Part 265
incinerator has combustion controls that are equivalent to those prescribed by EPA to combustion
XI
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; Part 264 incinerators or Part 266 Boilers and Industrial Furnaces. See Section 5:0 for additional
discussion on this topic. .
•• There is some level of uncertainty regarding to what extent a given set of operating
combustion conditions or technological controls can provide F032 and F024, or any other waste,
with effective treatment as well as to what extent such technology, as practiced, is protective of
the human health and the environment. EPA currently relies on Omnibus permit authority
provisions under 40 CFR Parts 264 .and 266 to require studies that enable EPA to prescribe ad
hoc permit conditions that can minimize these uncertainties. One example of such Omnibus
permit, authority is the conduct of risk analyses to assess the potential for emitting specific
' ' ' • ' .
products of incomplete combustion into the air. Another example of such Omnibus permit
authority is an approved permit requiring additional operating conditions that have been
demonstrated to minimize the generation and emission of hazardous air pollutants. EPA currently
\ lacks such permit discretionary authority to readily expedite and address these kind of concerns in
units that operate under 40 CFR Part 265 permits. EPA believes, therefore, that the monitoring
of D/F in F032 and F024 being combusted in 40 CFR Part 265 interim status combustion units
must be required to ensure that F032 and F024 are destroyed prior to disposal unless the facility
operating the 265 incinerator obtains from EPA a treatability variance of equivalent treatment for
such combsution device. '.'.-..-
A universal treatment standard is a single concentration limit established for a specific
>'•*'. "' "*
constituent regardless of the waste matrix in which it is present, i.e., the same treatment standard
V ' -
applies to a particular constituent in each waste code in which it is. regulated. The Agency has
established two different sets of universal treatment standards: one for nonwastewater forms of
waste and one for wastewater forms of waste. These two sets differ in. the population of
regulated constituents and the individual universal treatment standards. A more detailed,
discussion concerning the determination of these treatment standards is provided in EPA's Final -
Best Demonstrated Available Technology (BD AT) Background Document for Universal
Standards. Volume A: Universal Standards for Nonwastewater Forms of Listed Hazardous ,
Wastes and EPA's Best Demonstrated Available Technology (BOAT) Background Document for
xu
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Universal Standards. Volume B: Universal Standards for Wastewater Forms of Listed Hazardous
Wastes. ' - - ,-.'.-
The universal treatment standards promulgated for each regulated organic constituent in
nonwastewater forms of F032 and F034 are based on incineration treatment performance data
that were used tq promulgate previous BOAT treatment standards The universal treatment
standards for wastewater forms of F032, F034, and F035 are based on treatment performance
*•' ' ' ' - , i
data from several sources, including the BDAT data base, 'the National Pollutant Discharge
* ?
Elimination System (NPDES) data base, the Water Engineering Research Laboratory ,(WERL)
data base, EPA-collected Wet Air Oxidation/ Powdered Activated Carbon (WAO/PACT®) data, -\
the EPA Office of Water's Engineering and Analysis Division (BAD) data base, industry-
submitted leachate treatment performance data, data in literature that were not already part of the
WERL data base, and data in literature submitted by industry (Advanced Notice of Proposed
Rulemaking (ANPR)) on the WAO and PACT® treatment processes. .
i • y
The Agency has treatment data on these wood preserving wastes, including data submitted
during the comment period for the Advanced Notice of Proposed Rulemaking of October 24,
. • • • ' • ' . /
1991: These data are presented in Appendix C. A summary of the comments received from the
ANPR is presented in Appendix D. Appendix E contains examples of alternative or emerging
technologies potentially applicable to the treatment of wood preserving or related waste streams.
Appendix F contains information on the thermal desorption of a petroleum refining waste
successfully removed from Subtitle C controls. Appendix G is the most recent memorandum
from Office of Solid Waste and Emergency Response (OS WER), "Assuring Protective Operation
of Incinerators Burning Dioxin-Listed Wastes." Appendix H contains the most recent OSWER
guidance on obtaining a variance from land disposal restrictions for soil and debris. Appendix I .
i . i
contains a summary of the final C AMU rule. Appendix J contains a list of additional references
that provide treatment information for hazardous waste. Appendix K is a summary of data
.submitted to EPA pursuant to the Phase 4 proposal for wood preserving wastes. Appendix Lisa
) • • .. • ' •
summary of data submitted to EPA pursuant to Phase 4' s Notice of Data Availability with regard
to the feasibility of setting a CMBST; treatment standard alternative for the regulation of D/F
'
x'
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constituents in F032. Appendix M is an expanded list of references evaluated for Wood
Preserving Wastes. . .. .
\ i . . . • •.
The Agency is prohibiting the land disposal of both nonwastewater and wastewater forms
of wood preserving hazardous wastes F032, F034, and F035. If these prohibited wood
preserving wastes meet the treatment standards promulgated today, the wastes can be land
disposed. These wood preserving wastes are currently managed in hazardous waste treatment,
1 storage, and disposal facilities subject to RCRA Subtitle C requirements. It is believed that these
wood preserving wastes are likely to be commingled with other wastes prior to treatment and
disposal. As a result, the Agency believes it would be appropriate to apply the universal treatment
' ' ' <••" "' •
standards to the hazardous constituents proposed for regulation in these wastes. EPA also is
. , promulgating a compliance treatment standard alternative of combustion —"CMBST" ~ in
response to several commenters who asked EPA to consider adopting such an alternative
;
standards for the regulation of Dioxin and Furan (D/F) constituents in F032.
Finally, the majority of the commenters raised concerns about the potential impact the
promulgated treatment standards may have on ongoing remediation activities at RCRA and
Superfund sites. Section 6.0 summarizes EPA responses to the major comments raised regarding
the management of contaminated media and debris under the land disposal restrictions.
xiv
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TABLE ES-1
REGULATED CONSTITUENTS FOR HAZARDOUS WASTE NUMBERS
F032, F034, and F035
' Constituent
Phenol
2,'4-Dimethylphenol
2,4,6-Trichlorophenol
2,3,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluorene
Indeno( 1 ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene ,
Arsenic •
Chromium,,
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxiris
Hexachlorodibenozo-p-dioxins
Tetrachlorodibenozofurans .
Pentachlorodibenzofurans
Hexachlorodibenzofurans
-CAS No.
- 108-95-2
105-67-9
'88-06-2
58-90-2
87-86-5
. 83-32-9
120-12-7
56-55-3
. 50-32-8
[a]
218-01:9
53-70-3
86-73-7 .
193-39-5
91-20-3
85-01-8
129-00-0
7440-38-2 \
7440-47-3 '
—
-
—
— .. . _
—
—
,,F032
X
X
X
X
X
X
X
X
X
x
. X '
x - ,.
x
X
x
X
X
X
X
x
X
X
x
x
X
F034
. -
"
X
X
x
X
X
X
x
X
X; ;
X
- X
X
x
X
«
• ;
,
.F035 .
,, s
' >
s
X
x
fc
t
Source: U.S. EPA, June 1995. , . , •
[a] this constituent is regulated as the sum of benzo(b)flu6ranthene (CAS No. 205-99-2) and
benzo(k) fluoranthene (CAS No. 207-08-9), since both of them coelute on gas chromatography.
xv
-------
TABLE ES-2
BDAT TREATMENT STANDARDS FOR NONWASTEWATER
FORMS OF F032, F034, AND F035, WOOD PRESERVING WASTES
Constituent ,
Phenol
2,4-Dimethylphenol
2,4,6-Trichiorophenol
2,3,4,6-Tetrachlofophenol
Pentachlorophenol •
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene*
Chrysene
Dibenz (a,h)anthracene
Fluorene
Indeno(l,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Arsenic
Chromium
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibehzo -p-dioxins
Tetrachlorodibenozfurans
Pentachlorodibenzofurans .-
Hexachlorodibenzofurans
F032 (rag/kg)
6.2
14.0
7.4
7.4
7.4
3.4
3.4
3.4
-3.4
6.8 (sum)
3.4
8.2
3.4
3.4
5.6
5.6
8.2
' ' 5.0 (mg/L TCLP)
0,86 (mg/L TCLP) ,
0.001 .
0.001
0.001
0.001
, 0.001
0.001
F034 (mg/kg)
*"
?
-
3.4 .
." 3.4
' 3.4 .
3.4
6.8 (sum) /''..
3.4
8.2
'3.4
3.4
5.6
5.6
8.2
5.0 (mg/L TCLP)
0.86 (mg/L TCLP)
. ' •
F035(mg/L) ,
'
/
'•
5.0 (TCLP)
0.86 (TCLP)
•
Source: U.S. EPA, June 1995. * Because benzo(b)fluoranthene and benzb(k)fluoranthene coelute on gas
chromatography columns, this constituent is regulated as a sum of the two compounds.
XVI
-------
TABLE ES-3
BDAT TREATMENT STANDARDS FOR WASTEWATER
FORMS OF F032, F034, AND F035, WOOD PRESERVING WASTES
Constituent
Phenol
2,4-DimethylphenoI '
2,4,6-Trichlorophenol '
2,3,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene '
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene* ,
Chrysehe
Dibenz (a,h)anthracene
Fluorene:
Indeno( 1 ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Arsenic >
Chromium -
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibenozo-p-dioxins
Tetrachlorodibenozofiirahs
Pentachlorodibenzofurans
Hexachlorodibenzofurans
F032(mg/L)
,. 0'039
0.036
' 0.035.
0.030
.0.089
0.059
0.059.
0.059
0.061
0. 11 (sum)
' 0.059
0.055
0.059 -
0.0055 .
... 0.059
! 0.059
0.067
1.4.
.2.77
0.000063
0.000063
0.000063
0.000035
0.000063
0.000063
F034 (mg/L)
'
0.059
0.059-
0.059
0.061
j! ' . .
0.11 (sum)
0.059
0.055
0.059
0.0055
0.059
•' 0.059
0.067
; 1.4 '
2.77 - -
-
v • •
- - •
• .
N
'
* F035 (mg/L)
,'
t ' •
•
. ^
\
• .
• 1.4
2.77
.
-
•x-
Source: U.S. EPA, June 1995.
^Because benzo(b)fluoranthene and benzo(k)fluoranth'ene coelute on gas chromatography
columns, these constituents are regulated as the sum these two compounds. •
xvii
-------
TABLE ES-4
COMPLIANCE TREATMENT ALTERNATIVE FOR DIOXIN AND FURAN
CONSTITUENTS IN F032 WASTES
. Constituent
Tetrachlorodibenzo-p-dioxiris
Pentachlorodibenzo-p-dioxins
Hexachlorodibenzo-p-dioxins
Tetracholbrodibenzo-p-furans
Pentachlorodibenzo-p-furans
Hexachlorodibenzo-p-furans
CAS Number
'
V
•
— -.
v""~™
•
Treatment Method*
CMBST
CMBST
CMBST,
CMBST
CMBST
CMBST
Compliance with this treatment method is limited only to combustion devices regulated under 40
CFR Parts 264, Subpart O, and 266. Also, any Part 265 incinerator who have obtained from EPA
a treatment equivalency pursuant to 40 CFR 268 42 (b).
xvm '
-------
1.0 INTRODUCTION
.> the U.S. Environmental Protection.Agency (EPA or the Agency) is promulgating Best
Demonstrated Available Technology (BD AT) treatment standards for the regulation of listed •
hazardous wastes identified in Title 40, Code of Federal Regulations. Section 261.32 (40 CFR
261.32) as F032, F034, and F035. These BDAT treatment standards are being promulgated in
accordance with the amendments to the Resource Conservation and Recovery Act (RCRA) of
1976 enacted by the Hazardous and Solid Waste Amendments (HSWA) of November 8, 1984.
Compliance with the proposed treatment standards is a prerequisite for land disposal, as defined in
.40 CFR Part 268. In 40 CFR 268.44, EPA supplies provisions, that, if met, may justify granting a
variance from the applicable treatment standards. In 40 CFR 268.6, EPA supplies provisions,
.that, if met,-may justify granting waste- and site-specific waivers from the applicable treatment
standards in 268.40. The BDAT treatment standards for these wastes are presented in Tables 1-1
and 1-2 of this document.
•' • " • ' ' "^ . t
Hazardous Wastes Numbers F032, F034, and F035 are generated during the application of
a preservative to wood to prevent damage from weather, insects, and fungi. These hazardous
wastes are defined as follows:
F032 - Wastewaters, process residuals, preservative drippage, and discarded spent
formulations from wood preserving processes at facilities that currently use or
have previously used chlorophenolic formulations .(except waste from processes
that have complied with the cleaning or replacement procedures set forth in
§261.35 and do not resume or initiate use of chlorophenolic formulations). This
listing does not include K001 bottom sediment sludge, from the treatment of
wastewater from wood preserving processes that use creosote and/or -
pentachlorophenol.
F034 - Wastewaters, process residuals, preservative drippage, and discarded spent
formulations from wood preserving processes that currently use creosote
formulations. This listing does not include K001 bottom sediment sludge from the
treatment of wastewater from wood preserving processes that use creosote and/or
pentachlorophenol . '•• '
1-1
-------
• ' F03S - Wastewaters, process residuals, preservative drippage, and discarded spent
formulations from wood preserving processes that currently use-inorganic
preservatives containing arsenic and chromium. This listing does not include KOOl
bottom sediment sludge from the treatment, of wastewater from wood preserving
processes that use creosote and/or pentachlorophenol.
•'•-.-• ' •','•''
This background document provides the Agency's rationale and technical support for
developing BD AT treatment, standards for F032, F034, and F035 under the Land Disposal (
Restrictions (LDR) program. This document also provides waste characterization data that may
serve as a basis for determining whether a variance from the applicable treatment standards is
warranted for a particular type of wood preserving waste that may be more difficult to treat than1
the wastes on which the promulgated treatment standards are based. '
• ' •
The Agency's legal authority and the petition process necessary for requesting a variance
from the treatment standards are summarized in EPA's Methodology for Developing BOAT
Treatment Standards. 1991. , .
' '• ' '
» •
1.1 Regulatory Background , •'•.''
Section 3001(e)(l) of RCRA requires EPA to determine whether to list as hazardous,
wastes containing chlorinated dioxins and chlorinated dibenzofurans. As part of this mandate, the
Agency initiated a listing investigation of dioxin-containing wastes from pentachlorophenol wood
preserving processes arid pentachlorophenate surface protection processes. Two other similar
wood preserving processes that use creosote and aqueous inorganic formulations containing
chromium or arsenic were also included in this investigation.
^ < i • - -
>" .'•••'
On December 30, 1988, EPA proposed four listings pertaining to wastes from wood
preserving and surface protection processes, as well as a set of standards for the management of
i
these wastes (53 FR 53282). The Agency finalized three generic hazardous waste listings for
wastes from wood preserving processes and promulgated standards for the management of these
wastes"on-drip pads (40 CFR.parts 264 and 265, Subpart W) on December 6, 1990 (55 FR
50450). .'••-' . .
''•''••-. ' '
'; 1-2 • .
-------
. HSWA amended RCRA to require EPA to promulgate treatment standards for a waste
within 6 months'after determining it is hazardous [3004(g)(4)]. The Agency did not meet this
statutory deadline for the wood preserving wastes, as well as other wastes identified or listed after
adoption of the HSWA amendments to RCRA in 1984. As a result, the Environmental Defense
Fund (EDF) filed a lawsuit against the Agency to force the Agency to comply with RCRA.. This
suit resulted in EPA and EDF signing a consent degree for adopting prohibitions and treatment
standards for newly identified and listed wastes. .This final rule meets requirements of the consent
degree to promulgate treatment standards for wood preserving wastes..
-. • • ' -. • \ " •
( . • i.
In the December 5, 1992, federal Register, EPA proposed to revise several elements of
the wood preserving hazardous waste regulations and requested comment on those issues. The
Agency proposed the following actions: (1) eliminate the F032 classification for certain wastes
i ' S .".'.-'
generated by past users of chlorophenolic formulations such that any wastewaters, drippage,
i f
process residuals, or spent preservatives are regulated as F034 wastes, F035 wastes, or wastes ,
exhibiting the Toxicity Characteristic (TC); (2) .narrow the scope of the wastewater listings
contained in the F032, F034, and F035 listings to include only those wastewaters that come in
contact with process contaminants; (3) require contingency plans and cleanup of storage yard
.drippage in response to incidental drippage in storage yards; (4) remove the requirement that new
1 ' *
drip pad coatings, sealers, or covers be impermeable; (5) add a requirement that new drip pads
have leak collection devices; (6) revise the requirement that all existing drip pad coatings, sealers,
or covers be impermeable to reflect data on the permeabilities of available coatings, sealers, or
covers; (7) require that drip pad surface materials be chemically resistant to the preservation being
used and that these surface materials be maintained free of cracks, gaps, corrosion, brother,
deterioration .that would increase their hydraulic conductivity above the 1 x 107 cms level and lead
to a potential for releases to the environment; (8) revise the requirement that drip pads be cleaned
weekly to a requirement that drip pads be cleaned in a manner and frequency such that the entire
surface of drip pads can be inspected weekly; (9) revise the schedule for upgrading existing drip
pads to allow 15 years for the incorporation of liners and leak detection systems; and (10) revise
the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
designation of hazardous substances to reflect the modifications in the listings. ' • '
. . i-3 •
-------
The Agency also requested comment as to whether the standards for new drip pads should
allow the.choice of either a highly impermeable surface (e^g., sealers, coatings, or covers for
concrete drip pads) or a liner with a leak detection and collection system.
. i
' . _ • '
These changes were finalized on Thursday, December 24, 1992.
'-..'' .
1.2 Summary
' * /
• ' ' < ' •
The Agency is prohibiting the land disposal of both nonwastewater and wastewater forms
of Hazardous Waste F032, F034, and F035 by applying the universal treatment standards to.each
hazardous constituent proposed for regulation in these wastes. These wood preserving wastes are
currently managed in hazardous waste treatment, storage, and disposal facilities subject to RCRA
Subtitle C requirements. It is believed that these .wood preserving wastes are likely to be
commingled prior to treatment and disposal. As a result, the Agency believes that it would be
appropriate to apply the universal treatment standards to the hazardous constituents proposed for
regulation in these wastes. EPA is also promulgating a compliance treatment standard alternative
of combustion — "CMBST"-in response to several commenters who asked EPA to consider
adopting such an alternative standard for the regulation of Dioxins and Furans (D/F) constituents
in F032. (See Section 5.0 for a general discussion of EPA's rationale and implementation
guidance.)
1 ' i • ' ' •
A universal standard is a single concentration l;mit established for a specific'constituent
regardless of the waste matrix in which it is present (i.e., the same treatment standard applies to a
particular constituent in each waste code in which it is regulated). The Agency has established
two different sets of universal treatment standards one for nonwastewater forms of waste and
one for wastewater forms of waste. These two sets differ in the population of regulated
constituents and the individual universal treatment standards. A more detailed discussion
concerning the determination of these treatment standards is provided in EPA's Proposed Best
Demonstrated Available Technology (BDAT) Background Document for Universal Standards.
. • .
Volume A: Universal Standards for Nonwastewater Forms of Listed Hazardous Wastes and
'"'"'. . *>
. ' ;' •.'•.'. 1-4 .,.•••'
-------
EPA's Proposed Best Demonstrated Available:Technology (BOAT): Background Document for.
Universal Standards. Volume B: Universal Standards for Wastewater Forms of Listed Hazardous
Wastes. . • • • - .'-"'.; ' .
* - ' . ,' '
The universal treatment standards promulgated for each regulated organic constituent in
nonwastewater forms of F032 and F034 are based on incineration treatment performance data
, ./
that were used to promulgate previous BOAT treatment standards. The universal treatment .
^ ' ' • *-
standards for wastewater forms of F032, F034, and F035 are based on treatment performance
data from several sources, including the BDAT data base, the National.Pollutant Discharge
Elimination System (NPDES) data base, the Water Engineering Research Laboratory (WERL)
data base, EPA-collected Wet Air Oxidation/Powdered Activated Carbon (WAO/PACT®) data,
the EPA Office of Water's Engineering and Analysis Division (EAD) data base, industry-
submitted leachate treatment performance data, data in literature that were not already part of the
WERL data base, and data in literature submitted by industry on the WAO and PACT® treatment
processes. ' ,
\ '
The Agency has treatment data on these wood preserving wastes, including data submitted
during the comment period following the Advance Notice of Proposed Rulemaking of October
24,1991. These data are presented in Appendix C.
Table 1-1 presents the promulgated BDAT treatment standards for nonwastewater forms
of F032V F034, and F035. Table 1-2 presents the promulgated BDAT treatment standards for ,
wastewater forms of these wastes. The standards shown on Tables 1-1 and 1-2 are numerically
equivalent to the universal treatment standards for those constituents. This action is taken in
accordance with the schedule established in the consent degree signed between the EPA and the
EOF. ' ' ' - ' • ' ' ' , ' . •.. ' '
• " • ' . * > '
Table Ir3 presents the promulgated compliance treatment alternative of combustion
(CMBST) for the regulation of specific dioxin and furan constituents in F032. Under this
.alternative compliance treatment standard, EPA is setting combustion as the treatment standard
. . ' 1-5
-------
for specific dioxin arid furan (D/F) constituents in F032 that are treated via combustion and thus,
the monitoring of each regulated D/F constituent is not required as a prerequisite to land disposal.
Under this compliance treatment alternative, the specific UTS numerical limits of other regulated
organic and metal hazardous constituents in F032 must be met as a prerequisite to land disposal.
(See May 10,1996 (61 FR 21418).) In addition, EPA is limiting the promulgated compliance
' . • "
treatment alternative standard to F032 wastes that are combusted in permitted interim status
combustion units regulated under 40 CFR Part 266 or in RCRA Part B permitted combustion
devices operated under 40 CFR Part 264, Subpart O unless the facility combusting F032 obtains
• „ • • "i f
from EPA a treatability variance of equivalent treatment pursuant to the 40 CFR 268.42 (b). The
treatability variance application should emphasize to what extend the Part 26S incinerator has
combustion controls that are equivalent to those prescribed by EPA to combustion Part 264
incinerators or Part 266 Boilers and Industrial Furnaces. See Section 6.0 for additional discussion
on this topic.
There is some level of uncertainty regarding to what extent a given set of operating
combustion conditions or technological controls can provide F032, or any other waste, with
effective treatment as well as to what extent such technology, as practiced, is protective of the
human health and the environment. EPA currently relies on Omnibus permit authority provisions
under 40 CFR Parts 264 and 266 to require studies that enable EPA to prescribe ad hoc permit
, conditions that can minimize these uncertainties. One example of such Omnibus permit authority
is the conduct of risk analyses to assess the potential for emitting specific products of incomplete
combustion into the air. Another example of such Omnibus pernvt authority is an approved
permit requiring additional operating conditions that have been demonstrated to minimize the
generation and emission of hazardous air pollutants. EPA currently lacks such permit
discretionary authority to readily expedite and address these kind of concerns in units that operate
i under 40 CFR Part 265 permits. EPA believes, therefore, that the monitoring of D/F in F032
'''••. / .
being combusted in 40 CFR Part 265 interim status combustion units must be required to ensure
that F032 are destroyed prior to disposal unless the facility operating the 265 incinerator obtains
from EPA a treatability variance of equivalent treatment for such combsution device.
,1-6
-------
1.3 Contents of This Document
•• > ^ •, " '
Section 2.0 of this document summarizes the promulgated BDAT standards, the basis for
listing wood preserving wastes as hazardous, and how the promulgated standards reflect the-goals
of the Land Disposal Restrictions program. Section 3.0 describes the industry and processes
generating Hazardous Waste Nos. F032, F034,' and F035, and presents data characterizing these
wastes. Existing waste management practices for these wastes also are described in Section 3.0.
Section 4.0 explains the methodology and rationale for selection of the proposed regulated
constituents, discusses the treatment technologies the Agency has designated as "applicable" and
"demonstrated" for these wastes, identifies BDAT for wastewater and nonwastewater forms of
"* " - ' -
these wastes, and presents the determination of the promulgated treatment standards for these
wastes. In addition, potential reuse and recycling, source reduction, pollution prevention, arid
waste minimization alternatives for these wastes are discussed in Section 4.0. EPA's rationale
for setting the alternative complaince treatment standard of combustion and how such standard
will be implemented can be found in Section 5.0. A summary of pertinent comments received
with regard to the potential impact today's treatment standards may have on remedial activities at
wood preserving sites can be found Section 6.0. References are liste, generally, in Section 7.0
Acknowledgements, are provided in Section 8.0. Tables,and figures are located at the end of each
section. - <, • ' . '
The treatment performance data base and methodology employed for identifying the
•f • ' • . ' " • • •
nonwastewater universal treatment standards are found in Appendix A. The treatment
performance data base and methodology employed for identifying the wastewater universal
. treatment standards are found in Appendix B.
, . The Agency has treatment data on these wood preserving wastes, including data submitted
during the'comment .period for the Advanced Notice of Proposed Rulemaking of October 24, ; -
1991. These data are presented in Appendix C. A summary of the comments received from this
ANPR is presented in Appendix D. Appendix E contains examples of alternative or emerging
technologies potentially applicable to. the treatment of wood preserving or related waste streams.
' > 'i ,t . '.-,'--..
' ^ .
I-?' • . ,
-------
Appendix F contains information on the thermal desorption of a petroleum refining waste
successfully removed from Subtitle C controls. Appendix G is the most recent memorandum
from Office of Solid Waste arid Emergency Response (OSWER), "Assuring Protective Operation
of Incinerators Burning Dioxin-Listed Wastes." Appendix H contains the most recent OSWER
guidance on obtaining a variance from land disposal restrictions for soil and debris. Appendix I
. contains a summary of the final CAMU rule. Appendix J contains a list of additional references
that provide treatment information for hazardous waste. Appendix K is a summary of data
' ' ^ i ' '
submitted to EPA pursuant to the Phase 4 proposal for wood preserving wastes. Appendix L is a
summary of data submitted to EPA pursuant to Phase 4* s Notice of Data Availability with regard
to the feasibility of setting a CMBST treatment standard alternative for the regulation of D/F
constituents in F032. Appendix Mis an expanded list of references evaluated for Wood
Preserving Wastes.
1-8
-------
TABLE 1-1
: TREATMENT STANDARDS FOR NONW ASTEW ATER
FORMS OF F032, F034, AND F035, WOOD PRESERVING WASTES
Constituent ;
' Phenol
2,4-Dimethylphenol
2,4,6-Trichlorophenol
2,3,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene
Anthracene '
Benz(a)anthracene ' .
Behzb(a)pyrene
Benzo(k)fluoranthene*
Chrysene
Dibeiizo(a,h)anthracene
Fluorene
Indeho(l ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Arsenic
Chromium .
fetrachlorodihenzo-p-dioxins ;
Pentachlorodibenzo-p-dioxins
Hexachiorodibenzo-p-dioxins
Tetrachlorodibenozfurans
Pentachlorodibenzofurans
Hexachlorodibenzofurans
F032 (mg/kg)
6.2
14.0
7.4
• 7.4 ' •
• 7.4
3.4
3.4,
, • 3.4.
, 3:4
6.8 (sum)
- 3.4
'8.2
3.4 .
.3.4,
' 5.6
5.6
. ' \ 8.2
5.0 (mg/L TCLP)
0.86 (mg/L TCLP)
0.001
0.001
0.001
.0.001
0.001
0.001 ,
F034 (mg/kg)
j
,
3.4
3.4
3.4
' 3.4 . .'
' 6.8 (sum)
3.4
• - 8.2
3.4. .
3.4
5.6
-, . ' , 5*. . '
8.2 .
5.6 (mgfL TCLP)
0.86 (mg^L TCLP)
/
. '
F035 (mg/L)
_
•
• . <
'
1
_
' 5,0 (TCLP)
0.86 (TCLP)
1
'
-
Source: U.S. EPA, June 1995. .
"'Because benzo(b)fluoranthene and benzo(k)fluoranthene coelute on gas chromatography columns, this constituent is
regulated as a sum of the two compounds. ' >
1-9
-------
TABLE 1-2
PROPOSED BOAT TREATMENT STANDARDS FOR WASTEWATER
FORMS OF F032, F034, AND F035, WOOD PRESERVING WASTES
Constituent
Phenol
2,4-Dimethylphenol
2,4,6-Trichlorophenol .
2,3 ,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene*
Chrysene
Dibenzo(a,h)anthracene ' . :
Fluprene v .
Indeno(l ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Arsenic
Chromium
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
>•
J>
Hexachlorodibenozo-p-dioxins
Tetrachlorodibenozofurans
Pentachlorodibenzofurans
Hexachlorodibenzorurans
F032 (mg/L)
0.039
0.036
- 0.035
0.035
0.089
0.059
0.059
0.059
' 0.061
.v 0.11 (sum)
0.059
-. 0.055 .
, 0.059
0.0055
0.059
0.059
• 0.067
1.4 .
2.77
0.000063
0.000063 •,
0.000063
• 0.000063
0.000063
0.000063
F034(mg/L)
.
0.059
0.059
• 0.059
0.061 . :
0.11 (sum)
0.059
0.055
' 0.059
0.0055
, 0.059
. 0.059
0.067
1.4
2.77
'
F035 (mg/L)
. ' ,
1.4
2.77
•
".
Source: U.S. EPA, June 1995. . • . ' .
'"Because benzo(b)fluoranthene and benzo(k)fluoranthene coelute on gas chromatography columns, this constituent is
regulated as a sum of the two compounds. '
1-1.0'
-------
,.-••'. • • :• TABLE 1-3 . ' '
COMPLIANCE TREATMENT ALTERNATIVE FOR DIOXIN AND FURAN
CONSTITUENTS IN F032 WASTES
Constituent ,
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibenzo-p-dioxins
Tetracholorodibenzo-p-furans
Pentachlorodibenzo-p-furans
Hexachlorodibenzo-p-furans
CAS Number
\ '
> ' '
— •• • "
— -
.
Treatment Method*
CMBST
CMBST
CMBST
CMBST
CMBST
CMBST ' .
Compliance with this treatment method is limited only to combustion devices regulated under 40
CFR Parts 264, Subpart O, and 266. Also, any Part 265 incinerator who have obtained from
EPA a treatment equivalency pursuant to 40 CFR 268.42 (b). •
.'1-11,
-------
2.0 LAND DISPOSAL RESTRICTIONS FOR F032, F034, AND F035
Section 3001(e)(2) of HSWA requires that EPA evaluate whether wastes from the wood
preserving industry should be listed as hazardous. HSWA directed EPA to study the production
and use of wood preservatives and determine whether these processes result in the generation of
hazardous waste according to the, criteria in 40 CFR 261.11. The Agency performed an extensive.
study of the wood preserving industry and made .the determination to list as hazardous the .
following three wastes associated with the production and use of wood preservatives: F032,
F034, and F035 (see the Background Document Supporting the Final Listing of Wastes from
Wood Preservation Processes. November, 1990, (EPA refers to this document as the Listing
Background Document)).
*
* ' '"
2.1 Summary of Basis for Listing of Wood Preserving Wastes
As presented in the Listing Background Document, the Agency determined that certain
residuals from the preservation of wood, listed as Hazardous Waste Numbers F032, F034, and
F035 wastes, typically contain constituents that, when mismanaged, pose a substantial present or
potential threat to human health and the environment due to their carcinogenic or toxic properties.
In addition, the Agency compiled evidence that these wastes contain toxic constituents that are
mobile and/or persistent in the environment and, therefore, are capable of reaching receptors in
harmful concentrations, the information that supports these findings is presented in this proposed
Background Document and the Listing Background Document; it is also available in the RCRA
Docket supporting the listing of wood preserving wastes. The Agency identified the following as
.constituents of concern in these wastes: pentachlorophenol, benz(a)anthracene, benzo(a)pyrene,
benzo(k)flupranthenei dibenz(a,h)anthracene, indeno(l,2,3-cd)pyrene, naphthalene,
tetrachlorodibenzo-p-dioxins, pentachlorodibenzo-p-dioxins, hexachlorodibenzo-p-dioxins,
tetrachlorodibenzofurans, pentachlorodibenzorurans, hexachlorodibenzofurans, arsenic, and
chromium. In addition to these constituents, the Agency has proposed the following additional
constituents for regulation in these wood preserving wastes: phenol, 2,4-dimethylphenol, 2,4,6-
trichlorophenol, 2,3,4,6-tetrachlorophenol, acenaphthene, anthracene, chrysene.-fluorene, *
* t , -
~s
2-1 ' •• • .
-------
phenanthrene, and pyrene. The reason for the addition of these compounds is provided in Section
4.1. Table 2-1 summarizes these constituents..
2.2 Kev Points of Wood Preserving Waste Standards and How They Reflect LDR Goals
, • ' s s '
The LDR program is designed to protect human health and the environment by prohibiting
the land disposal of RCRA hazardous wastes unless specific treatment standards are met.
In RCRA Section 3004(m), Congress directed the Agency to:
". .. promulgate ... levels or methods of treatment. .. which substantially
diminish the toxicity of the waste or ... the likelihood of migration of hazardous
constituents ... so that short-term and long-term threats to human.health and the J
environment are minimized." .
Key provisions of the LDR program require that: (1) treatment standards are met prior to
land disposal, (2) treatment is not evaded by long-term storage, (3) actual treatment occurs rather
than dilution, (4) record keeping and tracking follow a waste from "cradle to grave" (i.e.,
generation to disposal), and (5) certification verifies thatthe specified treatment standards have
been met. , . v.
•' ' . ' •
The Agency is promulgating treatment standards for specific hazardous constituents in
both nonwastewater and wastewater forms of F032, F034, and F035 wastes as these treatment
.- • ' '-i '• -
.standards are expressed as the same universal treatment standard concentrations applicable to
each constituent of concern in.268.48 (see Phase IV proposal (60 FR 43654, August 22, 1995)).
The Agency's treatment standards promulgated for each constituent of concern in both
nonwastewater and wastewater forms of wood preserving wastes are presented in Table 2-1.
The Agency has determined that it is technically feasible to apply UTS to wood preserving
wastes, and thus, EPA is promulgating the. corresponding universal treatment standards that were
promulgated in the Phase II LDR. EPA believes that the promulgated treatment limits meet
• •* »*•
' ' ' ' •.-•'•/•' -2-2 ' . - -
-------
LDR's goal of minimizing threats to human health and the environment from land disposal. These
treatment limits are based on the treatment performance data representing treatment technologies
identified as "best" for wood preserving wastes. Since EPA is promulgating treatment limits for
each regulated hazardous constituent in F032, F034, and F035, other treatment technologies
capable of meeting treatment limits are not precluded except for those thatmay constitute
i
impermissible dilution. . .
For Dioxin and Furan constituents in nonwastewaters and wastewater forms of F032, EPA
is also promulgating an alternative compliance treatment standard of combustion (CMBST)
Facilities treating F032 via the alternative CMBST standard do not have to monitor the
concentrations of D/F constituents in CMBST residues, e.g. scrubber waters, as a prerequisite for
land disposal. However, other organic and metal constituents regulated in F032 must meet
applicable treatment limits prior to disposal. EPA is also limiting the availability of these
compliance alternative treatment standards to those CMBST devices operated in compliance with
regulatory requirements under 40 CFR Part 264, Subpart O, and Part 266. Thus, with residues
resulting from combustion in units regulated under 40 CFR Part 265 must meet applicable D/F
numerical limits prior to disposal. i
2-3
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- , •-•••- . , TABLE 2-1 '. . ..' .-.
CONSTITUENTS OF CONCERN FOR HAZARDOUS WASTE NUMBERS
F032, F034, and F035
Constituent
Phenol
2,4-Dimethylphenol
2,4,6-Trichlbrophenol
2,3,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene
Anthracene.
Benz(a)anthracene:
Benzo(a)pyrene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluprene
Inderio(l,2,3-cd)pyrene.
Naphthalene
Phenanthrene
Pyrene
Arsenic
Chromium f
Tetrachlbrodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibenozo-p-dioxins
Tetrachlorodibenozofurans
Pentachlorodibenzofurans
Hexachlorodibenzofurans
CAS No.
108-95-2
105-67-9
. 88-06-2
58-90-2
87-86-5
83-32-9
' 120-12-7
56-55-3
50-32-8
[a]
218-01-9
53-70-3
.86-73-7
193-39-5
91-20-3
85-01-8
129-00-0
7440-38-2
7440-47-3
—
—
' — ' ,
—
F032
• x; •
X
X
X
/X •'
X
X
X
.X ' ••
X
X
X
x
X
x
x
X
x
x
x
x. .
•' ;. X
X
X
X
. F034
'•
". . '
\
: x
x
: X-
X
X
X
• ' ' x ..
. • . ,;x .
X
x
x
x.
X
X
• .
• •'
•
-'.
' A
F035
• -
•i ' . ,
.„
'
X
• 'X-; '
.'
•
Source: U.S. EPA, June 1995. ,. <• . . .
[a] this constituent is regulated as the sum of benzo(b)fluoranthene (CAS No. 205-99-2) and
benzb(kyflupranthene (CAS No. 207-08-9), since both of them coelute on gas chromatography,
Note: X indicates that the constituent is promulgated for regulation in the individual wastestream.
2-4
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3.0 DETAILED DESCRIPTION OF WOOD PRESERVING WASTESTREAMS
• . ' ; ' • , , , ' I '
The following sections present a profile of the wood preserving industry and a description
of the raw materials used during wood preservation. Unless otherwise noted, the material cited in
this section is taken from the Background Document Supporting the Final Listing of Wastes from
. .Wood Preservation Processes, November, 1990(1).
N, ' ' . '
3.1 Description of Wood Preserving Industry .,
The American Wood Preservers Institute (AWPI) identified 588 plants that treated wood
products in 1987 (including 6 plants that were inactive in 1987). As of 1990, this number had
been reduced to 543 wood treating plants, consisting of 534 pressure treating plants and 9
nonpressure treating plants. Based on production reports for 431 plants and estimates of
i *
production for 112 non-reporting plants, the industry treated approximately 590 million cubic feet
of wood products in 1990 (10). In 1993, the number of active plants in the wood preservation
industry dropped to 471, of which only 2 are nonpressure treaters (1.1). The distribution of wood
preservers by region is depicted in Table 3-1.
" . - ' ' •'' - -s ' ' •
A wide variety of chemicals are used to preserve wood. The most commonly used ,
chemicals are pentachlorophenol, creosote, and inorganic arsenical and/or chromate salts. In
1973, AWPI reported that creosote and creosote solutions were used to treat approximately 51
> - ' - "
, percent of the total industry production, while pentachlorophenol and inorganic arsenicals
, /• . • -
accounted for 32 percent and 17 percent of the total production that year, respectively. However,
since the mid-1980s, there has been an upward trend in the overall percentage of wood treated
with inorganic arsenical and/or chromate salts. As of 1990, 88 percent of pressure-treating plants
used only one type of preservative: 76,4 percent treated with inorganic preservative only, almost
all contained arsenic; 7.7 percent treated with'creosote alone; and 3.6 percent used "-
pentachlorophenol. The remaining 12 percent used more than one type of preservative. In 1993,
, the distribution throughout the industry was 76 percent using inorganic preservatives, 9 percent
3-1
-------
using creosote preservatives, 4 percent using pentachlorophenol preservatives, and 11 percent
using a combination of preservatives.
3.2 Raw Materials , ,
Wood preservatives are used to delay wood deterioration and decay caused by wood-
destroying organisms such as insects, fungi, and marine borers. For example, surface
discoloration (sapstaining) that occurs during short-term wood storage can be adequately
controlled by applying a superficial application of the preservative, but for long-lasting .
effectiveness, deep and uniform penetration of preservative into wood is required. The deep
penetration is usually accomplished by forcing preservative into the wood under pressure. As
such, the term "pressure-treated" is often used as a synonym for "preserved."
'- " , v
V
Many different types of preservatives are used in the wood preserving industry. The
American Wood Preservers Association (AWPA) has been a primary force in the standardization
- ' s ' • ' i - - • . . •, ,
of specifications for wood preservatives and their application.to wood. According to AWPA, the
desirable characteristics of a wood preservative are:
. f • s
•••; It must be toxic to wood-destroying organisms.
- i S
• Its value as a preservative must be supported by field and/or service data.
• 'It must possess satisfactory physical and chemical properties which govern its
permanence under the conditions for which it is recommended for use.
It must be relatively free from objectionable qualities in handling and .use.
• It must be subject to satisfactory laboratory and plant control.
. • . . • i - r
• It must be available under provisions of current patents.
.' " ' i '
• It must be in actual commercial use.'
.•• For certain special uses, it may also need to be clean, colorless, odorless, paintable,
nonswelling, moisture-repelling, or possess a specific combination of these •
properties. ' • -
••'.-. ' ' 3-2 ' '. '' . '
-------
As stated earlier, the most commonly used chemicals to preserve wood are
pentachlorophenol, creosote, and inorganic arsenical and/or chromate salts (inorganics). In 1987,
^" '
the estimated consumption of pentachlorophenol, creosote, and inorganics used during wood .
preservation was 9-miIlion kilograms, 308-million liters, and 65-million kilograms, respectively.
Pentachlorophenol is usually used in an oil carrier for wood preservation and in a water soluble
form for surface treatment. Inorganics are always used in a water solution. Each of the three
major preservative types is discussed below. .
3.2.1 Pentachlorophenol (PCP) Preservatives
Pentachlorophenol is one of a group of synthetic organic compounds, called
chlorophenols, which are commercially manufactured by reacting chlorine with phenol.
Pentachlorophenol formulations are used primarily to treat poles, crossarms, lumber, timbers, and
fence posts. Pentachlorophenol is used in a wide variety of solvents, including heavy petroleum
(fuel oils) and creosote oils, light petroleum solvents such as butane, and volatile solvents such as
liquefied petroleum gas (LPG), alcohols, and methylene chloride. Standard petroleum oils
(AWPA P-9) are most frequently used in preparing the treating formulations. Pentachlorophenol
(using salts, such as sodium or potassium pentachlorophenate) may also be dispersed in water.
Data from a 1985 RCRA 3007 Survey of the wood preserving industry indicated that
approximately 89 percent of the plants treating with pentachlorophenol used organic solvents,
^ , , '
while 11 percent used pentachlorophenol in the salt form diluted in water. In 1987, industry
representative^ claimed that water-based pentachlorophenol was no longer used for pressure
treating wood. The practice had been attempted in the late 1970s and early 1980s due to the high
• j • u * ' •
cost of oil; however, because oil prices fell in the mid-1980s, water-based pentachlorophenol is
now rarely used for wood preservation.
. i . ' J
Pentachlorophenol formulations using petroleum solvents typically contain 5 percent total
pentachlorophenol; however, concentrations may range from 2 to 9 percent pentachlorophenol.
. Because pentachlorophenol has lower solubility in lighter petroleum solvents (such as kerosene,
mineral spirits, butane, and similar oils), auxiliary solvents (such as ether or alcohols) may be
'' • 3-3 • '
-------
•added to achieve a '5 percent concentration. Proprietary auxiliary solvents of undisclosed
compositions may also be used in some formulations. Waxes and resins may also be added to
pentachlorophenol formulations to prevent crystallization or "blooming" of the pentachlorophenol
on the wood surface as the solvent.evaporates. . - - . •" •
Water solutions of the sodium salts of pentachlorophenol (pentachlorophenates) are used
extensively in the control of sapstain in lumber. Chlorophenate formulations are produced by
dissolving chlorophenates in slightly alkaline (above pH 7) sodium hydroxide solution. Buffers
such as sodium tetraborate may be added to the formulations to maintain the alkaline condition.
Generally, these commercial concentrates are diluted 0,5 to 1. percent total pentachlorophenate
concentration and are applied directly to the wood by dipping or spraying.
' • ' . * . .•'.''*
<0.050 ppm (<50 ppb) TCDDs, <0.050 ppm (<50 ppb) PeGCDs, 1.55 ppmXl.550 ppb)
HxCDDs, and 94 ppm (94,000 ppb) HpCDDs. Covington and Burling (for the Penta Task Force)
and the American Wood Preservers Institute submitted additional data on PCP formulations in
their comments on the Phase 4 proposed rule. These data are summarized in Appendix K,. Table
3.2.2 Creosote Preservatives
Creosote generically refers to mixtures of relatively heavy residual oils obtained from the
- . . • •, . j - , . -, •
distillation of tar or crude petroleum. Creosote formulations are used primarily in treating
railroad ties, fence posts, lumber and timbers, crossarms, poles, and marine and fresh-water piling.
' ; ; 3-4 • " -.••"./.
-------
Although creosotes can be derived from a variety of tars, including wood-, petroleum-, and coal-
based tar derivatives, creosote formulations also include creosote solutions, in which creosote is
blended'with petroleum oils or crude coal tar, and creosotes fortified with insecticide additives
such as pentachlorophenol, arsenic trioxide, copper compounds, or malathion. The use of
insecticide-fortified creosote has been limited. : ...
i
The majority of creosote-based formulations consist of the pure coal tar creosotes. Pure
creosote is composed mainly of liquid and solid aromatic hydrocarbons, with 2 to .10 percent tar •
acids and tar bases. A typical creosote composition is given in Table 3-3. For comparison, the
polynuclear aromatic hydrocarbon concentrates of coal tar and petroleum oil are also presented in
this table. Creosote usually contains 1 to 3 percent water by volume, has a higher density than
water (the specific gravity of creosote is typically 1.1), and has a continuous boiling range
beginning at about 200 °C., Creosote blends consist of pure creosote blended with crude coal tar
or petroleum oil. The noncreosote components typically consist of 40 to 70 percent of the
' ' . i
treating solution. The creosote formulation used depends on the particular application involved
and on the local availability of additives. ' '
T
3.2.3 Inorganic Preservatives '• •
Inorganic preservatives consist of arsenical and chromate salts and fluorides dissolved in
water. Inorganic arsenical and/or chromate formulations are used primarily for the treatment of
'umber and timber for the building industry. According to a RCRA 3007 Survey conducted in
1985, the most commonly used inorganic preservatives include:
, \ • i , '
• Chromated Copper Arsenate (CCA); , . ,
Ammbniacal Copper Arsenate (ACA);
Acid Copper Chromate (ACC);
Chromated Zinc Chloride (CZC); and -
• Fluor-Chrome-Arsenate-Phenol (FCAP). ,
Three formulations of CCA (Types A, B, and C) are currently used at wood preserving plants.
The composition of the most frequently used formulation, CCA-C, is given along with the
compositions of other inorganic preservatives in Table 3-4. CCA accounts for the vast majority
I (
\ • . ' . ' '
.'• "3-5 • ' '•••••
-------
of inorganic preservative use (83 percent). Other inorganic preservatives used were ACA.
(9 percent), ACC (3 percent), CZC (3 percent), and FCAP and other inorganics (2 percent). For
treatment purposes, CCA is typically diluted in water'to 1 to 2 percent total. CCA concentration,
but treatment concentrations range from 0.9 to 8 percent total CCA in various treating solution.
Due to the'nature of these preservative mixtures, they are likely to undergo chemical changes
. when heated to high temperatures during treatment. Maximum acceptable temperatures range
froml20tol50°F.
i • ' i
\ ' • , ...
3.3 Processes Generating Hazardous Waste Numbers F032. F034. and F03S <
i '
Wood preserving consists of several processes. However, there are essentially only two
processes from which contaminated wastestreams are potentially created. These two processes,
conditioning (basically drying the wood) and preservative application, are discussed in detail -
below. Other sources of contamination, such as drippage during removal and storage after
preservative*application, are discussed in.Sections 3.3 and 3.4.
• '•' - ' *• • " • .
3.3.1 Conditioning Processes
f * . • • ' ,-- ' s " • '
, Wood preserving consists of the application of preservative chemicals to wood to protect
against decay and deterioration. Surface discoloration (sapstaining) can be adequately controlled
by applying a superficial coat of preservative, but for long-lasting effectiveness, deep and uniform
penetration of preservative into the wood is required. This type'of penetration can only be
achieved if the wood has been properly conditioned before the preservative is applied. However,
even with proper conditioning, only a limited number of wood species are amenable to wood
preservation (e.g., spruce and fir do not treat well). .
Seasoning and mechanical conditioning are the two most commonly used conditioning
methods. Seasoning reduces the moisture content of freshly-cut wood to a point where the
preservative can penetrate and be retained by the cells of the wood. Mechanical conditioning
consists of physically preparing the wood to improve the penetrability of the preservative, usually
•-.••• •' • -' 3-6 - •'-.'..-.
-------
by making holes or incisions along the wood surface. Untreated wood may undergo either one or
both of these conditioning methods before to preservative application.
Seasoning conditioning methods include: (1) steaming wood at elevated pressure in a
retort followed by application of a vacuum; (2) kiln drying; (3) heating wood in a preservative
.bath under reduced pressure in a retort (Boulton process); (4) heating unseasoned wood in a
solvent (vapor drying); and (5) drying wood in yards, at ambient temperatures (air seasoning).
Steam, Boulton, and vapor conditioning produce more process wastes (especially, wastewater).
than either air or kiln drying. All of these seasoning methods are described below.
(1) Steam Conditioning. Conventional steam conditioning (open steaming) is a process in
which unseasoned or partially seasoned wood is subjected to direct steam impingement at an ,
elevated pressure in a closed vessel or retort, thus vaporizing the water content of the wood. *
AWPA standards set the maximum permissible temperature at 118°C (244°F) and the duration of
the steaming cycle at no more than 20 hours. Immediately following steaming, a minimum
vacuum of 0:74 atm is applied for I.to 3 hours to pull the steam and vaporized wood water from
t ' '
the retort. Steam condensate that forms in the retort is removed through traps and is generally
conducted to oil/water separators for removal of free oils. The steam condensate may be further
treated before reuse or discharge off site:
' ' . ' * ' ' '
In closed steaming, a widely used variation of conventional steam conditioning, steam is
generated in situ by co'vering coils in the retort with water from a reservoir and heating the water
by passing process steam through the coils. The water is returned to the reservoir after oil
separation and is reused during the next steaming cycle. The volume of water in the storage tank
increases slightly after each cycle .because of the water removed from the wood. A small ,
blowdown from the storage tank is necessary to remove this excess water and to control the level
of wood sugars in the water. Because the steaming water may be reused, closed steaming
conditioning generates less wastewater than open steaming conditioning.
3-7
-------
Modified closed steaming is another variation of the steam conditioning process in which
steam condensate is allowed to accumulate in the retort during the steaming operation until it
covers the heating coils. Direct steaming is then discontinued, and the remaining steam required
.for the cycle is generated within the retort, by using the. heating coils. At the end of the steaming
cycle, the water in the cylinder is discarded after oil contaminants are removed.
I
; > - <
(2) Kiln Drying. Kiln drying is a batch-type process. Lumber or poles are placed in dry
kilns in which air is. either cross-circulated or circulated from one end to the other. Drying
temperatures and times vary with wood species and type of product. Drying temperatures
• • - (
ranging from 150-220°F have been used to dry poles. Pine lumber, which is commonly kiln-
dried, is dried at approximately 165 °F.
Kiln drying may produce wastewater in the form of condensate, which drains from the kiln
during the drying cycle. Kiln drying is also used, in some cases, to dry lumber after it is treated
with inorganic preservatives. Kiln drainage is also generated during the drying of treated lumber.
(3) Boulton Conditioning. Boulton conditioning consists of heating wood in a
- • , ' ' / *
preservative formulation in a pressure treating cylinder under vacuum conditions. The *
preservative, which has a boiling point higher than the boiling point of water, serves as a heat
transfer medium.' After the temperature in the treating cylinder is raised to operating temperature,
a vacuum is drawn and water vaporizes from the wood, passes through the preservative bath, and
Nv ' ' ' • '• "' • • • '
collects in a condenser. The condensate then may go^to an oil/water-separator and to any further „
treatment or recycling steps. -
.,.! _
- TheBoulton.conditioningcyclemayhayera:durationof48 hours-or-longerfqrlargepoles
=«.,."•""•* • ~ ' .._.'• • - - " "-•-^==ssa
"and pilings accounting for the lower daily production per retort compared to plants than steam-
* . •
condition. Boulton conditioning is usually limited to the application of creosote or nonwater-
based pentachlorophenpl formulations.
*3 "O
3-8
-------
(4) Vapor Conditioning. Vapor conditioning (vapor drying) consists of exposing wood in
a closed vessel to vapors from one of many organic chemicals that are immiscible with water and
have initial boiling points ranging from 212°F to 400°F (100°C to 204°C). Selected derivatives
of petroleum and coal tar, such as high-flash naphtha, or Stoddard solvent, are preferred; but
numerous chemicals, including blends, are also employed as drying agents in this process.
Vapors for drying are generated by boiling the chemical in an evaporator. The vapors are
• cdnducted to the retort containing the wood, where they condense on the wood, give up their
latent heat of vaporization, and cause the water in the wood to vaporize. The water vapor thus
produced, along with the excess organic vapor, is conducted from the vessel to a condenser and
then to a gravity-type separator. The water layer is discharged from the separator and the organic
chemical is returned to the evaporator for reuse. , . • .
At the end of the heating period, the flow of organic vapors to the vessel is stopped, and, a
vacuum is applied for 30 minutes to 2 hours to remove the excess vapor along with any additional
'water. Because the drying cylinder frequently serves as the pressure treatment cylinder, the wood
t ** * •
can be treated immediately after conditioning.
. ,' *
(5) Air Drying. Air drying consists of simply allowing wood to dry at ambient
temperatures in storage yards.
.., ,-
3.3.2 Typical Conditioning Processes Used Before Wood Preserving
Usually,,the selection of a particular conditioning method depends on-the species of wood
..tol>e treated and on the preservative to be used. According to the 3007 Survey, the majority of
plants treating with creosote and pe"htachlorophenol condition wood by air drying, kiln drying, or
steaming. (See Table 3-5!) Predictably, air drying, the simplest and least expensive method, has
the highest overall percentage of uses for both groups combined (approximately 38 percent). Kiln
drying and steaming are also used by pentachlorophenol and creosote treaters, with overall
3-9
-------
. percentages of 25 percent and 23'percent,.respectively. A smaller overall percentage (14 percent)
of pentachlorophenol and creosote treaters use the Boultbn conditioning method. , '
Plants treating with inorganics, however, almost exclusively use'kiln drying (52 percent)
or air drying (47 percent), because AWP A standards require wood treated with CCA or ACC to
- be cooled to 120°F or below before treatment to prevent fixation of the salts oh the wood
surface. Thus, any of the pressure conditioning methods would require an intermediate cooling
step, leading to inefficient use of pressure equipment. Further, most wood treated with inorganic.
; . ':-••'-.. . ..••• ; ' ' - • --' • -v
preservatives consists of lurhber and timbers, arid steaming would distort the size and shape of
these products. ;, - • .
After both pressure and nonpressure treatment, some unabsorbed preservative formulation
(drippage) will adhere to the treated wood surface.; Over time, this liquid will drip from the wood
or be washed offby precipitation. If the wood has been pressure-treated, excess preservatives
will also exude (bleed) slowly from the wood as it gradually returns to atmospheric pressure, a
phenomenon commonly called "kickback." Pressure- and nonpressure-treaied wood may
continue to bleed for long periods, even after the wood is shipped off site and installed for its
intended end use.
' ".•..,,, ' '' ' "
..3.4 Preservative Application Processes - ,, , •
/' s . -' -
After conditioning, preservatives may be applied by either pressure or nonpressure
processes. Pressure processes for applying wood preservatives employ a combination of air and
hydrostatic pressure and vacuum. Pressure treatment, carried out in batch processes known as
treatment cycles, is.accomplished by submerging wood in a preservative solution within a sealed
cylinder, or retort. Nonpressure .processes are usually carried out in open tanks, at ambient
pressure. Wood is immersed in the treating chemicals, which may be at ambient temperature or
above. . " " ','
3-10
-------
Many possible combinations of wood preserving processes, conditioning methods, and
preservative types are currently used in the wood preserving industry. AWPA sets standards
("Required Results of Treatment") for the industry, which depends on factors such as the
commodity (lumber, ties, poles, etc.); and the type of wood (Southern Pine, Douglas Fir, oak,
/ '
etc.). The "Required Results of Treatment" are stated in pounds of preservative per cubic foot of
wood. The selection of a particular wood preserving process depends on its ability to meet the
AWPA Standards. Each.rnajbr preserving process is discussed below: . v .
'- ' ; ' . •
3.4.1 Pressure Treatment Processes .
There are two basic types of pressure treatment processes, distinguished by the particular
sequence of application of vacuum and pressure. The first pressure method is referred to in the
industry as the "empty cell" process, It is used to obtain relatively deep penetration with limited
absorption of preservative, typically desired for products such as railway ties, poles, fence posts,
and construction lumber. The second pressure method, known as the ''full cell" process, results in
higher retention of preservative but in limited penetration compared to the empty cell process.
This type of penetration is particularly desirable for wood used in the marine environment. The
difference between the two processes can be viewed simply as whether the objective is to fill the
wood cells (full cell) or just to coat them (empty cell) with preservative. The distinguishing
process steps is an initial vacuum that is applied in full cell processes but not in empty cell
processes. There is no difference in the types of wastes generated by full cell and empty call
processes, although wood treated by the full cell process may drip more and has a greater
tendency to bleed than wood treated by the empty cell process. A flow diagram of typical
pressure treatment processes is presented in Figure 3-1.
•i • • ' - •
A.vacuum-only preservative process is also used in the wood preserving industry. This
process is simpler to control than the two pressure-vacuum process described above, but requires
more complex equipment than is generally used for other,processes. The vacuum-only process is
performed by enclosing wood in an airtight container, pulling an initial vacuum, and adding
preservative solution to atmospheric pressure. The preservative is driven into the wood by the
\
3-11 • ' • .
-------
pressure difference between the initial vacuum and the atmospheric pressure. A final vacuum may
be applied to control preservative retention and recover excess solution. -The vacuum-only
method is commonly used to treat window sashes with pentachlorophenol.
,. • ' /
* %~ «• * * " • \ » "
3.4.2 Nonpressure Treatment Processes ' . ••'..>
** * • * , '
. A limited quantity of wood is treated each year by nonpressure processes. Nonpressure
processes including brushing or spraying, dipping, soaking (steeping), and thermal applications.
The length of treatment and the concentration of the preservative are important factors in
nonpressure processes because the preservative is driven into the wood by diffusion. The
effectiveness of nonpressure processes depends heavily on the properties of the wood to be
treated and the moisture content. Figure 3-2 presents a flow diagram of typical nonpressure
treatment processes. . .
Brushing and Spraying. Brushing and spraying are the simplest of the nonpressure wood
treatment processes. These techniques can achieve good penetration through cut end-grain
surfaces, but result in only surface treatment along the grain of the wood. Creosote-based and
oil-based pentachlorophenol preservatives are generally applied by these methods, although
water-borne salts are applied in this manner to some degree. In the brushing and spraying
methods of preserving wood, the preservative is applied to the surface of the wood in a thick layer
and is allowed to soak in. Generally, two applications of preservatives are required. Brushing
and spraying are most effective when applied to end-grain surfaces because preservatives
penetrate much more readily in the direction of the grain. The preservative is usually mixed and
stored in tanks or drums, from which it is applied to the brush or sprayer. Brushing or spraying is
used for small volume applications, requires very little equipment, and results in quick,
inexpensive, and easy application of the preservative of to the wood.
\. ' -: •
Pipping. Dipping is generally used to treat structural forms of timber and consists of
immersing wood in a batch of preservative for a few seconds or a few minutes. Dipping is
essentially the same as spraying or brushing in terms of the types of preservatives used and
' * ' *
3-12
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conditioning requirements except that it generally uses more preservative and requires more,
equipment, namely, a dip tank of sufficient size. Dipping has the advantage of more adequately
treating the wood through further penetration due to the longer contact between the wood and
the preservative. . . > • .
Soaking (Steeping). Soaking at ambient temperature involves immersing wood in an
i
unheated oil solution (commonly a pentachlorophenol formulation) for periods ranging from 2
days to 1 week. The wood must be well-conditioned (dried) to achieve maximum absorption of
the preservative. The effectiveness of treating wood by soaking depends on the types of wood
and on the product being treated.
It is also possible to soak wood in water-based solutions for several days or even weeks at
ambient temperature (steeping). Occasionally, the preservative is heated somewhat to.attain more
rapid penetration. Both conditioned and unconditioned wood can be steeped; however,
conditioned wood attains the desired penetration of preservative much faster. Solution
concentrations generally range from 5 percent for conditioned timbers to 10 percent for
unseasoned timber. Kyanizing, a patented soaking process, uses preservatives of mercuric
chloride and was formerly used to preserve lumber, building timber, and poles.
' '
, • •• '
Thermal Process. The thermal process, or hot and cold bath process, involves immersing
seasoned wood in successive baths of hot and cool preservatives. Each stage typically takes 8 to
48 hours, depending on the ambient temperature and on the water content of the wood. The hot
baths expand the outer layers of the timbers and evaporate moisture through the surface of the ,
wood The cold bath causes the air and vapor in the outer shell of the wood to contract, thereby
forming a partial vacuum. Atmospheric pressure then forces the surrounding preservative into the
wood. .
. Creosote and pentachlorpphenbl formulations are generally used in the thermal process;
however, inorganic formulations have been used. Hot baths generally range from 210° to 220°F,
and cold baths are generally around 100°F. Treating times, actual temperatures, and preservative
' '3-13 ' ' • ' • - "
-------
I . "
• mixtures depend on the type of wood being treated. The thermal process is used primarily to treat
fence posts, lumber, and other forms of timber. It can be performed by using two separate tanks '.
or by changing.the temperature of the preservative solution in "one treating tank.
3.5 Wastestream Status Under Other Regulations - .
, Under the Clean Water Act (CWA), the discharge of pollutants into surface waters and
publicly-owned treatment works (POTWs) from wood preserving facilities is regulated under the
Timber Products Point Source Category, specifically 40 CFR 429, Subparts F and G. Subpart F
does not list specific constituents, but Subpart G includes effluent limitations and standards for
phenols, arsenic; and chromium (as well as COD, oil and grease, and pH). Phenols would include
.v , ' ' *~
the following constituents regulated in F032 Wood Preserving'Category: phenol, 2,4-
' Dimethylphenol, 2,4,6-Trichlorophenol, 2,3,4,6-tetrachlorophenol, and pentachlorophenol.
Arsenic and chromium are also regulated in F03 2, F034, and F03 5.
"" ' ' "x , • " •
Of the 25 constituents promulgated for Wood Preserving Wastes regulation under the
LDR program, 15 (phenol; 2,4-dimethylphenol; 2,4,6-trichlorophenol; pentachlorophenol;
anthracene; benz(a)anthracene, benzo(b)fluoranthene; benzo(k)fluoranthene; chrysehe;
dibenz(a,h)anthracene; indeno(l,2,3-cd)pyrene; naphthalene; phenanthrene; arsenic; and
chromium) are also regulated under the Emergency Planning and Community Right-to-Know Act
(EPCRA) Section 313 of the CERCLA. Under Section 313 (and also under the implementing , ',
regulations, 40 CFR Part 372, Subpart D),'facilities that manufacture, process, or otherwise use
these chemicals, and that meet certain other criteria, must report the releases and transfers of
these chemicals annually, on the Toxic Release Inventory (TRI) form R.
/ • -
Under the Clean Air Act (CAA), Section 112, National Emission Standards for Hazardous
Air Pollutants (NESHAPs) program (and the implementing regulations - 40 CFR Part 61), no
' (•,'.'.,'" • ' ' •. ' •••-',
Wood Preserving industry atmospheric emissions are currently regulated or scheduled for
regulation. There are also no specific regulations for Wood Preserving Industry atmospheric
emissions sources under CAA New Source Performance Standards (40 CFR Part 60). However,
' . : • •. 3-i4 . • .
-------
certain constituents found in Wood Preserving Wastes do have NESHAPs emissions limits from
• other sources. For instance, coke oven emissions are regulated under NESHAPs. Coke oven
emissions contain numerous polynuclear aromatic hydrocarbons (PAHs) that are also found in
Wood Preserving Wastes, such as naphthalene.
3.6 Wastestream Residuals .
1 "» .
This section describes the sources of wastes generated during wood preservation
processes. Source information is presented for each type of residual; first for residuals generated
during wood.preservation and then for residuals,resulting from cross-contamination. As shown in
Figures 3-1 and 3-2, the preservation of wood can result in the generation of the following
residuals: wastewaters,. process residuals, and treated wood drippage and Wash-off residuals
(including unused preservative formulations). These residuals are discussed below.
3.6.1 Wastewaters .
' - • • x
Wastewaters are generated at various points in both the pressure/vacuum and nonpressure
treatment processes. The sources of wood preserving wastewaters are described in detail below.
, , ' ," * . -
-'
Conditioning Wastewater. Conditioning is the process in which the natural moisture .
content of wood is removed to enable preservatives to adequately penetrate the wood. This may
.-* . .
be accomplished by air drying the untreated wood in storage yards for a period of months
(seasoning) or by kiln drying the untreated wood in controlled temperature and humidity kilns.
These conditioning methods may be used by pressure, vacuum, or nonpressure treaters. Air
drying does not produce contaminated wastewater unless surface protection (sapstain control)
( * '
with chlordphenolics is used before air drying.
Boultonizing, steam conditioning, and vapor drying are conditioning methods used by
pressure treaters. The wastewater produced by these conditioning methods consists.of the water
that is driven out of the wood. Steam conditioning also produces a considerable volume of steam
3-15
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condensate: The volume of wood conditioning water will vary according to wood type,
preservative formulation, conditioning method, etc. In general, 64 to 1,200 liters of water per.
cubic meter (0.5 to 9 gallons per cubic foot) of wood may be generated.
X
Although the preservative types do not specifically dictate the conditioning method used,
wood treated with inorganic arsenical and/or chromate salts is almost exclusively conditioned by
air or kiln drying. The use of conditioning methods that do not produce wastewater (and the
possibility of using condensate from vacuum systems and precipitation which falls in the treatment
area as makeup water for the inorganic salt preservative formulations) means that-inorganic
>x
processes can be operated with ho net generation of wastewater. However, arsenic and
. 'i ' • /•'•, . • . . ' . .
chromium may accumulate in wastewater and wastewater treatment residuals generated at plants
that treat with inorganic,salts along with pentachlorophenol or creosote.
Wastewater from Preservative Formulation Recovery and Regeneration. In addition to
. . . ; . . . _ f
the wastewater generated during conditioning, some water will accumulate in the
pentachlorophenol and creosote formulations used by both pressure and nonpressure treaters.
Periodic heat treatment or mechanical oil/water separation may be used to remove any -
accumulated moisture content.
• • . - ' * • '
, * -,. . , '•
Door Drippage and Spills.. Not all wastewater from pressure wood conditioning can be
effectively condensed and collected as an overhead from the pressure/vacuum retort or collected
by bottom drains from the retort. Steam or condensate may leak from door gaskets or drip from
the door as it is opened. Wastewater (and also preservative solution) may also spill out as the
door is opened. ^ '. ,.
i * - * - ,
' ' • ' • ' ~
Pole-Washer Wastewater. Excess surface preservative may be washed off with water
sprays either as the wood is removed from the treating retort or in another section of the plant
separate from the treating area. The use of pole-washers is more common in areas of the country
with little rainfall and for the small amount of wood treated by the Cellon® process
(pentachlorophenol in butane). . '
' • ' • • • • " ' • ''••'-' , "' ' •
. ' '•..-'. - • , .3-16 ' -.- •
-------
Precipitation That Accumulates in the Process Area. Wastewaters. managed by wood
preserving plants include precipitation falling in process areas contaminated with wood preserving
formulations. Runoff from the immediate process area (1/4- to Vi-acre adjacent to the process..
equipment) is currently included as a. process wastewater stream required to be collected and ,
treated by the effluent guidelines and standards promulgated in ,1981 under the CWA (46 FR
8260-8295).
Drying Kiln Condensate. Occasionally, wood treated with water solutions of inorganic
salts is kiln-dried after treatment: Kiln drying may produce some wastewater in the form of
condensate. If the kiln is used to dry wood treated with water solutions of inorganic salts, the
condensate may be contaminated with heavy metals. Condensate from this process constitutes .
contaminated wastewater.
t
Other Sources of Waste water. Other sources of wastewater that may,be present at some
plants are blowdpwn from wet air pollution control devices, drum rinsates, vehicle and equipment
washdown wastewater, and process area washdown.
3.6,2 Process Sludges or Residuals • ,
» i •'
Typical pressure treatment of wood is characterized by recycling preservatives from work,
storage, and mixing tanks to the pressure treating vessels. Nonpressure treatments involve the
repeated use of preservative in the treatment tank or the recycling of hot and cold formulations to
the mixing and work tanks. In both cases, fresh preservative solution is added to replace
consumptive loss. Preservative formulation lost with wastewater or through drippage into the
* '
s ,
door sumps is frequently collected and fed back into the process. The continual reuse of
preservative formulation leads to accumulations of sawdust, wood chips, sand, dirt, stones, tar,
and polymerized oils. This material comprises the bulk of wood preserving process sludges or
residuals and is collected in treating cylinders and tanks; in holding, work, storage, and mixing
tanks; in door sumps; and in filters and separators used to prepare preservative solutions for
reuse. Other process residuals are fugitive emissions (e.g., leaks and spills) and maintenance
3-17
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wastes that are typically managed by land disposal at the site of generation. These residuals are
described in detail below. ,/
, Treating Cylinder and Treating Tank Sediments. Sediments containing sawdust, wood
chips, sand, dirt, stones, tar, and emulsified and polymerized oils will accumulate in the bottom of
pressure treating cylinders and nonpressure tanks at wood preserving plants. Some treating
cylinders and tanks have bottom drains to recycle unused preservatives to work and storage tanks.
When this type of drain is used, sediments do not accumulate in the treating cylinders and tanks,
but are carried back to the mixing tanks. '
' v . , . - *
The frequency with which sediments are removed from treating vessels depends on the
preservative used, the production schedule, and how the wood is handled before treatment. A
pressure cylinder used to treat a high volume of wood with creosote may be cleaned out four or
.more times per year, while a cylinder used to treat a low volume of wood with organic salts may
^ •' ' '
go 5 years without cleaning. . . .
>.''••' ' /
The sediment layer that accumulates in the bottoms of the nonpressure treating tanks may
''.••. \ ' . • •
also need periodic dredging and removal, particularly for pentachlorophenol or creosote
processes, which do not use heat because of potential oil/water emulsion problems. - '
''.-•. • . . - ' s '
• ' ?
Treating cylinder sediments may be reduced in volume by cleaning the wood before
treatment and By storing wood during air seasoning on pallets or concrete pads instead of on open
ground. Also, kiln drying results in some surface dirt being retained in the kiln rather than in the
treating cylinder. , . . v>
• , ' . . . v ' '
Residuals from Holdings. Work. Storage. Mixing, or Other Tanks. Sediments similar in
composition to those generated in treating cylinders may be generated in holding, work, storage,
or mixing tanks at wood preserving plants.
3-18
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Pentachlorophenol tank sediments may be pumped out from the bottoms of tanks every
1 •'.-•••'
year or so, depending on plant conditions. These sediments often have a high water content .from
emulsified oils. Usable preservative may be. recovered form the sediments by mechanical oil/water
separation and/or thermal evaporation. Pentachlorophenol tank outlet lines may be several feet-
higher than the bottoms of the tanks to allow water emulsions and solid residuals to accumulate
without being returned to the process. -''_••' ,
' • • .• ' i . •
Creosote tank sediments also require periodic removal. Some heavy creosote tank
bottoms not suitable for a particular wood treatment application at one plant may be of the proper
grade for use at another plant. These/sediments have a high thermal recovery value and can be .
used as boiler fuel. Manufacturers of creosote may also regenerate these tank bottoms off site.
/ •
Inorganic arsenical/chromate processes generally do not generate tank sediments because
build-up of tarry residues or emulsions is not a problem, except in cases where wastewater from a
' * . '
Pentachlorophenol process is used as makeup water for the inorganic processes. Any entrained
insoluble matter.may be filtered from the treating solution before its return to work tanks.
Adjustment of pH is a means of resolubilizing precipitated preservative salts and will reduce the
quantity of process wastes requiring disposal. Inadequate control of the temperature of the
preservative solution may contribute to sediment formation; temperatures in excess of 140-150°F
.or temperatures below freezing are avoided for this reason. • . •
Residuals from Secondary Containment of Holding. Work. Storage. Mixing or Other
Tanks. The tank area of many wood preserving plants may be equipped with secondary
containment in the form of concrete or earthen berms around the concrete pads upon which the
x _ - '
^ t
tanks are installed. Drippage and spills (as well as windblown dirt and other debris) collect in
these units. *~
In addition, plants may have secondary collection systems for any stormwater runoff from
the "tank farm" secondary containment areas. Some plants require the manual operation of hoses
and pumps in the event of a major spill. In almost all cases, solid materials, such as dried
3-19
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formulation residues arid contaminated dirt and debris, are periodically shoveled from the
containment area and disposed. . * . • ,
Door or Treating Cylinder Sump Residuals. Most wood preserving plants have secondary
.containment for their treating cylinders in the form of concrete sumps either at the door opening
of the retort.or around the entire length of the retort. Sediments, windblown dirt, debris, as well
• • v '
as spills of preservative formulation, are collected in these sumps. Some treating cylinders may be
-x * • I
designed so that all sediments collect in these sumps, rather than, on the floor of the treating
cylinder itself. , ' .
"* ' ^
' . s • ~*
Some plants use sections of the containment sump area as conduits for wastewater or
preservative formulation collection and recycling. At some plants, recycling from the retort
containment sumps is automatic. > At other plants, manual operation of hoses is necessary to
collect wastewater or formulation from the top of the sump contents, to avoid recycling dirt,
debris, and other residuals. Often residuals, sediments, dirt, and debris must be shoveled from the
sumps by hand. . ,
Preservative Recycling/Regeneration Residuals. The recycling and regeneration of
preservative solutions used at wood preserving plants may require removal of entrained water and
i , • t ,
solid material. Filters or screens may be used in-line before returning solutions to the work tanks,
thus generating filtration residuals. Heat may be applied to creosote or pentachlorophenol
"solutions to break emulsions and evaporate entrained water, generating some portion of solid or
tarry material which cannot be returned. _•'..'
v
Drips and Spills from Leaking Process Equipment. Wood preserving plants are often old,
the processes are frequently run at elevated pressures, and the technology does not require great
precision and control. These factors may increase the probability of drips and spills from leaking
pipes, valves, and process equipment.,
3-20
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Maintenance Area and Shop Residuals. Processing equipment, trams and baskets for
holding wood during treatment, tanks, and vehicles contaminated with preservative formulation at
wood preserving plants are usually repaired1 on site in a maintenance shop area. Vehicles and
equipment may be hosed down over open ground or on pads before repair.
In the maintenance shop, degreasing solvents may be used on equipment before any repair,
thus becoming contaminated. Surface residues from equipment may also drip or be brushed onto
the shop floor, resulting in contaminated floor sweepings. '•<-".' ;
Other Sources of Process Sludges or Residuals. Maintenance and cleaning activities in the
process areas at wood preserving plants may generate process residuals. These residuals include
floor sweepings, empty drums and drum liners, and used gloves and other protective clothing.
3.6.3 Treated Wood Drippage, Wash-Off Residuals, and Unused Preservative
Formulations
*'••' ' ' ' . s .
Treated wood drippage and wash-off residuals are generated at various points in both the
pressure/vacuum and nonpressure treatment processes. The sources of treated wood drippage
and wash-off residuals from wood preserving are described below. .
Information about discarded unused preservative formulations is limited, but it is believed
r
to be similar to drippage in composition. Available data are presented in Section 3.4 for each type
"* * • ,
of waste. -No generation rates are available for discarded formulations, but they are believed to >e
generated when plants discontinue wood preserving operations. ,
Free Drippage from Treated Wood. After both pressure and nonpressure treatment, some
unabsorbed preservative formulation will adhere to the treated wood surface. Over time, this
liquid will drip from the wood or be washed offby precipitation. If the wood has been pressure-
treated, excess preservative will'also exude slowly from the wood as it gradually returns to
atmospheric pressure, a phenomenon commonly called "kickback.1' Preservative formulations
(especially pentachlorophenol and creosote formulations) may continue to exude ("bleed") from
. ' .- 3-21 - '
-------
pressure and nonpressure treated wood for long periods, even after the wood is shipped off site
" ' * *• L ' •'
and installed for its intended end use.
• - '*" "^
/ ~
sFree drippage from pressure-treated wood may be minimized by steaming the wood after
treatment to wash off adhering preservative or by applying a final vacuum on the wood before it is
removed from the retort; however, applying a final vacuum or steam cleaning to the treated'wood
while it is in the treatment cylinder may not always be possible. Certain types of preservative
formulation applications and certain types of wood preclude the use of vacuum, especially if a
•5 ' '.
maximum amount of formulation on the wood surface is desirable for water repellency during
•.... ..-.'• .'
storage or use (e.g., creosote applications to railroad ties or marine pilings). A final steam
cleaning may not be permitted by AWPA standards for certain woods in specified applications
(e.g., steaming of oak piles, poles treated with water-borne preservatives, and.lumber and timber
i.. • ' , • •
requiring protection from marine borers is not permitted). Final steaming may also render certain
treatment applications, (e.g., Cellon® process pentachlorophenol treatment) less effective.
Because a final steam cleaning and/or vacuum delay the next treatment cycle, and because final
steam cleaning and/or vacuums are energy-intensive, a plant may choose not to employ these
techniques. Finally, steam cleaning in the treating cylinder or tan is not possible for nonpressure
and vacuum treatment processes, nor is a final vacuum cycle position for nonpressure processes,
' - • /
In general, wood that has been treated by the empty cell process will have less free
drippage than the same wood treated with the same preservative formulation by the full cell
process.. THe'empty and full cell processes are'distinguished by an initial vacuum which is part df.
the full cell process, but not part of the empty cell process. The empty cell process is based on the >
principle that part of the preservative forced into the wood is expelled by entrapped air upon
' _ " . b
release of pressure at the conclusion of the treating cycle. In contrast, in the full cell process, air
is withdrawn from the wood by a vacuum drawn at the beginning of the treating cycle.
Preservative is then forced into the wood under pressure, as in the empty cell process. However,
1 • , '.'.-.
most of the preservative remains in the wood when the pressure is released, because there is no
i ' " '
entrapped air forcing the preservative out of the wood. A final vacuum may be applied at the end
3-22
-------
f
of either the empty or full cell process. Wood treated by the full cell will have a higher
preservative retention and, thus, may drip more than wood treated by the empty cell process. ,
The amount of free drippage from treated wood also depends on the type of formulation
used (viscosity), the degree of penetration into the wood (amount available for drippage), the type
of wood used (porosity and swelling capacity), the imperfections in the wood (splits and
knotholes), and the size of the,wood treated (relative surface area and relative proportion of end-
cuts). , -
Climatic conditions will also affect the amount of free drippage and the period of time
over which this drippage will occur. Warm climates, summer, and direct sunlight will favor
greater amounts of free drippage from creosote- or pentachlorophenol-treated wood. Cold
climates (especially freezing temperatures) and high humidity will prevent drying and fixation of
inorganic arsenical/chromate-treated wood, resulting in greater amounts of free drippage from
both inorganic arsenical/chromate-treated wood and creosote and pentachlorophenol-treated
wood until spring or the first warm day. As a result, large volumes of free drippage may be
generated over a short period of time.)
Management of free drippage varies from plant to plant and often depends on the
' production schedule a plant must meet. A plant producing near its capacity will remove wood
from the treating cylinder and transfer it to storage quickly. Thus, most free drippage and
kickback will occur in the treated wood storage yard. At a plant that does not need to maximize
its retort use, a charge may be allowed to drip in the retort for a extended period of tirrie. Other
plants have "drip pads" over which trams of freshly-treated wood are allowed to sit for 1 to 3
', ' -
days. Collected drippage may be routed to a sump and then reused in the treatment process, or
may be disposed. .
Several plants have "drip pad sludge" volumes. These volumes represent only sludge
accumulation at plants that collect a portion of their drippage; they do not represent the total
volume of excess preservative which drips from pressure-treated wood. Generally, collected
- , • .' . 3-23 ' -. '
-------
• drippage is reused in preservative processes, while sludges may be left in place indefinitely, or may
. be periodically dredged and hauled to ofFsite disposal in general or secure landfills. Eighty-six
percent of the plants'that responded to a 1985 RCRA 3007 questionnaire did not report managing
; ' . . •
treated wood drippage, although most generated this waste. Plants typically allowed treated
wood to drip on drip pads, along tram tracks, and in the wood storage yards.
' - . • ' . . i
Wash-Off of Excess Preservative Formulations from Treated Wood. Excess preservative
adhering to the surface of treated wood is undesirable because it prevents the clean use of the
-i . _ •
treated wood for construction purposes. AWPA standards specify that all treated wood should be
free of visible surface residue before sale to the customer. However, there is no known practice
by which wood preserving plants eliminate surface residues from wood treated with creosote or
pentachlorophenol in petroleum carriers before sale, other than to allow the wood to rest in the
open where precipitation washes off excess preservative. At most plants, washed-off preservative
V '"'-,.»
is disposed of oh open ground. At a few plants, both initial free drippage and treated wood
storage takes place over areas covered with asphalt or concrete, where drippage, kickback, and .
washed-off preservatives are collected and treated. A few plants are currently roofing their
concrete-covered treated wood storage yards to minimize the amount of washed-off preservative
that requires collection and treatment.
• ' • . i , • •
• ,• / •
Residues of excess formulation from treatments with nonpetroleum pentachlorophenol
formulations, known as "bloom," may appear on the surface of treated wood. Wood preserving
plants may wish off this surface residue with specially-installed sprays (often over open ground),
f. or may be able to take advantage of natural precipitation to perform this function in some climates
*" - \
or seasons. .
, Surface residues may. also form on^wood treated with arsenical arid/or chrbmate
formulations because complete fixation of all arsenical/chromate salts as insoluble complexes in .
the wood fiber is not possible. Some fraction of the water-borne arsenical/chromate salts remains
as free, powdery residues on the surface of-the wood, in the grain (especially along cuts), or in the
pores of the wood. Incomplete fixation is due in part to hydrostatic tension that keeps some of
• ' • 3-24 ^- . "" -'
-------
( » . t
the formulation as pockets or layers of free liquid, thus preventing the intimate contact of the
formulation with the wood fiber during drying. Further, wood may be overtreated with more
V _ ' •" '
inorganic salts than can be fixed in the wood fiber. Finally, impurities or imbalances in the
treating salts themselves may lead to the formation of residues of unfixed arsenic and chromium in
the pores and surfaces of the wood.
v • ' ' • >.
These surface residues of unfixed (i.e., soluble) arsenic and chromium may be washed
from treated wood with polewashers or other washing devices. A-final steam cleaning may also
be used to minimize surface residue. Alternatively, the residues may be washed off by
precipitation.
* •
3.6.4 Cross-Contamination Residuals ,
\
•- • . - * ' * , ' /
Because wastes generated at plants that previously used chlorophenolic preservatives and
wastes generated from creosote and inorganic wood preserving processes located within the same
plant as a chlorophenol process can be contaminated with pentachlorophenol and PCDDs and
s
PCDFs, these wastes are included in under Hazardous Waste No. F032. However, wastes,from
wood preserving processes at plants that do not resume the use of chlorophenolic preservatives
v .
will be excluded from the definition of F032, provided the generator meets the requirements of 40
CFR §261.35. • V
\
, ., ' - .?.-•'
ProcesS sludges and wastewater residuals accumulate gradually in wood preserving and
wastewater treatment equipment. Periodically (annually, semiannually, monthly, or perhaps less
frequently depending on the size and operating practices or a particular plant), the accumulated,
' i •
residuals are removed from the equipment and disposed. The Agency has determined that wood
preserving plants regularly change the preservatives used in a particular piece of process
equipment without removing accumulated materials.or cleaning the equipment. , .
* "..-•'' '' .
- EPA also believes that waste from inorganic and creosote processes, generated either from
equipment that has been previously used in pentachlorophenol process or at plants that have used
' '• ' • ' 3-25: •' ' •• ' •'
-------
. pentachlorophenol processes on the same site, is contaminated by the constituents of concern
from the pentachlorophenol processes. This potential for cross-contamination is documented by
the waste characterization data provided in the November 1990 Background Listing Document
for Wood Preserving Wastes (Final), Appendix D. These data show that constituents unique to
pentachlorophenol waste were identified in some creosote and inorganic wastes. This cross-
contamination is further documented by information collected by EPA through site visits and
surveys. Based on this information, EPA has concluded that the potential for cross-contamination
is significant and has, therefore, included in the F032 listing wastes from inorganic and creosote .
processes that may be cross-contaminated with chlorophenolic preservatives.
3.7 Quantities and Composition of the Wastestreams
The following section describes the quantities and concentration of contaminants in the
wastestreams produced from the wood preserving industry. Because the data are more readily .,
v , "•';,' '
, available by the type of waste, rather than by waste code, this section is divided into the following
three subsections: wastewaters, process sludges and residuals, and drippage/wash-off streams
However, the generation of wood preserving wastes is reported as wastewater and
nonwastewater forms for each wood preserving hazardous waste code of concern.
Based on the 1985 RCRA Section 3007 Survey, which was used as the primary source for
determining the quantities of waste generated, volume estimates have been calculated on a waste
code basis. To determine current \ nUimes for each waste code, wood preserving waste
generation rates from the survey were multiplied by the total volume of wood treated with each
preservative type scaled up from the 1994 Micklewright Report (1). Table 3-6 presents EPA's
estimates of the quantities of wood preserving wastes generated by waste code. .
•i • —''
3.7.1 Quantity of Process Wastewater Generated by the Wood Preserving Industry
The average process wastewater generation rate was 174 1/m3 of treated wood for, the 14
. plants supplying both production and wastewater generation information in response to the
- 3-26 ' .' . '
-------
RCRA 3007 Survey. In contrast, data collected by EPA's Office of Water indicated that for 47
surveyed plants in 1976, the average wastewater generation rate was 157 1/m3. Data collected in
the 1985 RCRA 3007 Survey were assumed to better represent current industry practices and ,
were used to estimate the rate at which process wastewater is produced during wood preserving
activities. .
All 28 plants that reported process'wastewater management in the RCRA 3007 Survey
treated wood-with pentachlorophenol, creosote, or both. Although plants treating with inorganic
preservatives generate process wastewater (condensate from vacuum systems and process area
runoff), these plants recycled these wastewaters back to the treating process. Therefore, based on
data from the questionnaires, attributing any net process wastewater generation to processes
using inorganic preservatives would not be accurate. .
The total quantity of process wastewater managed by the wood preserving industry in
1985 was estimated to include: process wastewater generation was associated with only 80
percent of the production of wood treated with creosote or pentachlorophenol because not all
plants treating wood with creosote or pentachlorophenol reported generating and managing
process wastewater. The remaining 20 percent ofproduction may be conditioned by kiln or air
V
drying processes that generate little wastewater. (However, plants that evaporate or reuse all of
' f
their process wastewater may also have failed to report managing any wastewater.) The total
1985 production of wood treated with pentachlorophenol or creosote was reported by AWPI to
be 3,394,000 m3. Eighty percent of the treated wood (2,715,200 m3) are associated with
wastewater generation: The total quantity of process wastewater managed by the wood.
preserving industry in 1984 has been estimated to be 4.72 x 10* liters.
\ '
Of the 14 plants in the 1985 RCRA 3007 Survey that supplied information on their
wastewater generation rates, 6 treated with creosote only, 2 with pentachlorophenol only, and 6
with both creosote and pentachlorophenol. insufficient information was provided to calculate ,
separate wastewater generation rates for processes using pentachlorophenol and processes using
creosote formulations, particularly because plants treating with both preservatives typically
/'
' • ' .. 3-27 . .-'••" ' '
-------
combine the wastewaters for treatment and cannot attribute an individual flow to a specific
preservative. Further, the majority of available wastewater constituent data came from sources in
•\ i ^ " t
which the wastewaters from creosote and pentachlorophenol treating processes were , ;
commingled. Therefore, calculation of separate wastewater flow rates for pentachlorophenol
* i .-*
processes and for creosote processes was not considered to be meaningful, and the rates were
assumed to be the same. •'- " -
' • •
3.7.2 Concentration of Constituents in Wood Preserving Process Wastewaters
The constituents in wood preserving wastes, including process wastewaters, can be
divided into five groups: pentachlorophenol (PCP), polychlorinated dioxin and furari (PCDD and
** ' , ' '
PCDF), polynuclear aromatic hydrocarbon (PAH) constituents, phenolic constituents, and metal
constituents (specifically arsenic and chromium). Table 3-7 presents minimum, maximum, and ;
average detected concentrations for, the listing constituents and other significant compounds for
F032 and F034 wastewaters. The complete data set for all constituents found in the sampled
wood preserving wastes is provided in Appendix D of the Listing Background Document.
Process wastewater constituent concentrations have probably been underestimated
because many wastewater samples collected represent partially treated wastewater. These include
samples collected for the development of effluent guidelines, which were taken after preliminary
oil/water separation, as well as samples collected for the Georgia study (Case Number 110),
which were.taken from potentially stratified surface impoundments.
Pentachlorophenol. Concentrations of pentachlorophenol in wood preserving
wastewasters were available from the Development Document supporting the effluent guidelines
for wood preserving; from sampling performed by EPA's Office of Solid.Waste (OSW); from a
study of wood preserving surface impoundment wastes by the State of Georgia; and from data
obtained during RCRA site inspections. In all, data were available for samples of 25 different
wastewaters. Pentachlorophenol concentrations in wastewaters ranged from 0.01 .ppm to 300
ppfn and averaged 10 ppnr . . .'..'•-,
. - ; ' ' . • 3-28 '• ' ' - - .
-------
Polychlorinated Dioxins and Furans (PCDDs and PCDFsV Concentrations of PCDDs and
PCDFs in untreated wood preserving wastewaters were available from published studies
describing four sites in Canada and from a study undertaken as part of a CERCLA cleanup (Case
Number 93). Ranges and average concentrations for specific PCDD and PCDF homologs are
given in Table 3-7. ^
Other data quantifying wastewater concentrations of PCDDs and PCDFs were not used to
estimate typical dioxin concentrations because they are not considered to be representative. One
plant from which unused data were obtained is attempting to^use an aeration process to
biologically degrade the constituents of sludge and water contained in a large surface
impoundment. This process includes adding "dispersants" to the sludge/water mixture in an
attempt to force the constituents in the sludge into the wastewater and thus increase their
availability to micro-organisms. However, while increasing availability of sludge constituents,
PCDD and PCDF concentrations in water may also be increased. Further, the wastewater
samples are filtered before analysis. Thus, the data may not be representative of typical _•
wastewater concentrations of PCDDs and PCDFs in wood preserving wastewaters. ,, .
The PCDD and PCDF, concentrations in the wastewater from the Cellon® process at one
plant were also not used. -The concentrations of PCDDs and PCDFs in wastewaters at this plant
are several orders of magnitude greater than the concentrations measured in other wastewater
\ r
sources. A possible explanation for these higher concentrations is that butane, the carrier used in
the Cellon® process, is much more soluble in water than in petroleum oil, which is more
. i • '.
frequently used as the carrier for pentachlorophenol. Because a relatively small proportion of the
plants treating wood with pentachlorophenol use the Cellon® process, the PCDD and PCDF
concentrations in wastewater from the Cellon® process are not considered typical of
concentrations of these constituents in the wood preserving industry.
i
\ , ~ •
Polvnuclear Aromatic Hydrocarbons and Phenolics. Wastewater concentrations of PAHs
and phenolics in wood preserving wastewaters were available from the Development Document
supporting the effluent guidelines for wood preserving; from sampling performed by EPA's OSW;
." 3-29 • . -- • ' '
-------
and from a study of wood preserving surface impoundment wastes by the State of Georgia. EPA
: v. -. ' ' ,
believes these data can-represent F032/F034 untreated wastewater and wastewater treated in
preliminary oil/water separation. Ranges and average concentrations for specific PAHs and
. phenolics are provided in Table 3-7.
Metals. Wastewater concentrations or arsenic and chromium in wood preserving
wastewaters were available from the Development Document supporting the effluent guidelines
for wood preserving; from sampling performed by EPA. OSW; and from data,obtained during
RCRA site inspections (Appendix D of Background Listing Document). As shown in Table 3-7,
arsenic concentrations ranges from 0.003 mg/L to 30 mg/L and averaged 5 mg/L. Chromium
concentrations ranged from 0.004 to 10 rng/L and averaged 2 mg/L.
\ - .
As described, process wastewater generated while using inorganic preservatives is reused
as preservative makeup water, resulting in no net generation of wastewater,1 However,
i ,
wastewater generated while using creosote and/or pentachlorophenol preservatives may be ;
s • ' \ •
contaminated with arsenic and chromium due to cross-contamination at plants which use both "
organic and inorganic preservatives. The extent of this cross-contamination, and the associated
' /
concentration of arsenic and chromium in cross-contaminated wastewater, are quite variable.
Nevertheless, EPA concluded that concentrations of chromium and arsenic in these wastewater
forms supported the listing of F032, F034, and F035 as hazardous waste under RCRA. EPA is
not reopening this determination to review in today's final rule. , .
v.
• j- • •
V. ' .-
•••'.. . • "l . ' •
Three of the 11 wastewater samples analyzed for arsenic had concentrations greater than
5.0 mg/L and, thus, would be considered characteristically hazardous due to EP toxicity (40 CFR
261.24). These three samples represented wastewaters from treatment area surface runoff,
oil/water separator wastewater, and impoundment wastewater. . „ : '.
One of the 10 samples analyzed for chromium had a concentration greater than 5.0 mg/L, .
and, thus, would be considered characteristically hazardous due to EP toxicity (40 CFR 261.24).
This sample consisted of conditioning condensate from Boulton conditioning with creosote and
l • '
.'•••• 3-30 . • " ' ' .
-------
pentachlorophenol. However, the plant at which this sample was collected also treats with
chromated zinc chloride (C2C), which is assumed to be the source of the chromium in the .
1 » ' "
wastewater. . > ' . ,' - • . .
f / . •
3.7.3 Quantity of Process Sludges or Residuals Generated by the Wood Preserving
Industry . .
Data collected in the RCRA 3007 Survey were used.to estimate the rates at which process
sludges or residuals are produced during wood preserving activities. In contrast to the data
1 N . -
supplied to describe wastewaters, data describing process residuals were detailed enough for
calculation of separate statistics for residuals from each type of preservative. The average process
sludge or residual generation rates in liters per cubic meter (L/m3) were as follows:
Preservative . Average Generation Rate .
Creosote -1 , 0.542 L/m3 -
Pentachlorpphenol 0.845 L/m3
. Inorganics 0.051 L/m3
Fifteen percent of the plants responding to the RCRA 3007 questionnaires claimed to
, produce no residuals from their wood preserving operations. These plants accounted for
approximately 3 percent of the pentachlorophenol production, 4 percent of the creosote
production, and 5 percent of the inorganic production reported in the survey. However, many
survey respondents stated that, while there was residual buildup in the treating equipment, the
residuals had never been removed. Thus, for the purpose of this estimate, all wood preserving
operations were assumed'to generate process residuals. The total 1985 production rates, by
preservative (as reported by AWPI), were used to estimate the total quantity of process residuals
generated: /' .
' . Preservative L/m3 x m3/yr =. L/yr •
/ N • , "i
Pentachlorophenol 0.845 . 1,389,000 1,174,000
- Creosote .0.542 3,641,000 1,973^00
Inorganics '0.051' 9,549,000 487,000
/
3-31 . ' .
-------
. Because the listing definition ofFQ32 includes all wood preserving wastes generated -'at
plants that use chlorophenate preservative formulation, any process residuals from creosote
• *•
processes or inorganic processes at plants that also use pentachlorophenol would be classified as
F032. Similarly, process residuals from .inorganic processes at plants that also use creosote
would be classified as F034. The quantity of process residuals generated in each listing category
was estimated as follows: '..-•' . '.
Waste
Code
F032
F034
t
F035
Preservative
Pentachlorophenol
Creosote
Inorganics
TOTAL
'Creosote
Inorganics
TOTAL
Inorganics
L/m3 x
0.845
0.542
0.051 '
0.542
0.051
/ ,
0.051 .
mVyr =
/
1,389,000'
1,136,000 .
660,000 ••:
2,504,000 V
319,000
8,576,000
L/yr .
1,174,000
, 616,000 '
y - 34,000
\
1,824,000
1,357,000
16,000 ,
1,373,000
437,000
3.7.4 Concentrations of Constituents in Wood Preserving Process Sludge or Residuals
EPA has reviewed available characterization data on untreated and treated F032, F034,
^
• ' • -^
and F034 from documents supporting the listing of these .wastes as hazardous and additional data
gathered by EPA on F034/F035 during 1991 (EPA refers to these additional data as the EPA's
• ' ' '.
1991 F035 studies), EPA's 1991 F035 studies consist of four studies that characterize untreated
and treated wastewater and nonwastewater forms .of wastes believed to be as difficult to treat as
F035. .The first study consists of characterization studies of untreated F035 sludges, wastewater
collection sumps, wastewaters, and other filter residuals at three wood preserving facilities. J"he
second study involved collecting data on untreated and treated F035 wastes that were
commingled at a hazardous waste.treatment facility prior to their stabilization with lime and
cementitious agents. The third study describes an EPA in house stabilization treatability study of
' 3-32
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F035 using lime, fly ash, and cementitious agents. The fourth study is an EPA in house feasibility
study to selectively remove arsenic and chromium from a synthetic wastewater formulated to
simulate F03 5 wastewaters. . .
x i ' *
Other literature and documents reviewed included the EPA's Preliminary Data Summary
for the Wood Preserving Segment of the Timber Products Processing Point Source Category,
September 1991 (EPA 440/1-91/023), the 1986-1990 summary abstracts on the treatment of
F032, F034, and F035 contaminated soils at Supertund sites, other literature published on the
treatment of wood preserving and petroleum refining contaminated soils, and data included in
comments submitted in response to the Advanced Notice of Proposed Rulemaking of October 21,
1990 (ANPRM) and Phase 2. Additional data regarding the makeup of F032 wastes were
reviewed by EPA after the comment period for the Phase 4 proposed rule. These supplemental
data can be found in Appendix K (The Penta Task Force, comment PH4P-00032, 2/23/96;
American Wood Preservers Institute, comment PH4P-00039,11/20/95.) In addition, EPA
analyzed all available data on the treatment of other. RCRA wastes that are believed to be as
difficult to treat as F032, F034, and F035. Based on the analyses of these data, EPA believes that
it-is not necessary to subcategorize F032, F034, and F035 wastes beyond wastewaters and
nonwastewaters.
The constituents of concern in wood preserving < wastes, including process sludges or
residuals, can be divided into five groups: pentachlorophenol (PCP) constituents, polychlorinated
dioxin and fiiran (TCDD and PCDF) constituents, polynuclear aromatic hydrocarbon (PAH)
constituents, phenolic constituents, and metal constituents (specifically arsenic and chromium).
Minimum, maximum, and average detected concentrations for the listing constituents and other
significant compounds for process sludges or residuals from pentachlorophenol, creosote, and
inorganic wood preserving processes are presented in Tables 3-8, 3-9, and 3-10, respectively.
The complete data set for all of the constituents found in the sampled wood preserving wastes is
1 provided in Appendix D of the Background Listing Document.
3-33
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I
' Pentachlorophenol. Concentrations of pentachlorophenol in wood preserving process
sludges or residuals were available from sampling performed by EPA's OSW and from data '
obtained during RCRA site inspections. The sampled residuals, all derived from processes in
which pentachlorophenol was used, included pressure retort sediments and door sump sediments.
The concentrations of pentachlorophenol in process sludges or residuals ranged from 40 ppm
(0.004 percent) to 30,000 ppm (3 percent), and averaged 20,000 ppm (2 percent). ;
Two samples had concentrations much lower than the average concentration. One was a
sample of soil from the pit around a treating cylinder (40 ppm), and one was from a cylinder in.
which creosote, not pentachlorophenol, had been used for 2 to 4 months prior, to samplings.
' ' '
Excluding these samples, the concentration of pentachlorophenol in treating cylinder sludges
""" ' '' ' *'
ranged from 1.1 to 3.4 percent, and averaged.2.2 percent.
v ' ' " \ . -
Two samples of residuals from nonpressure processes had pentachlorophenol
"•• i - . ,*
concentrations of 2.0 percent and 1.1 percent - not significantly different from the overall average.
Therefore, concentrations of pentachlorophenol in residuals from pressure and nonpressure
processes are assumed to be the same. .
* s V
Polvchlorinated Dioxins and Furans fPCDDs arid PCDFsV Concentrations of PCDDs and
PCDFs in wood preserving process sludges or residuals were available from sampling performed
by EPA/OSW and from data obtained during RCRA site inspections. The sampled residuals, all
derived from'processes in which pentachlorophenol was used, included pressure retort sediments,
nonpressure treating tank sediments, work and storage tank sediments, and floor scrapings from a
treating cylinder shed. Not all samples were analyzed for all PCDD and PCDF homologs. • -• ' -
Ranges and average concentrations for specific PCDD and PCDF homologs are given in Table 3-
8. In addition, data on PCDD and PGDF concentrations were submitted by Covington and
Burling for the Penta Task Force. These data include samples of work tank solution, retort
'-' * ' • ~ > .
sludge, drip pad waste, oil-water separator sludge, and filter press cake. They are summarized in
Appendix K, Tables K-2 and K-6. >
3-34
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Polvnuclear Aromatic Hydrocarbons (PAHs) and Pheholics. - Concentrations of PAHs and
phenolics in wood preserving process sludges or residuals were.available from sampling
performed by EPA/OSW and from data obtained during RCRA site inspections. The sampled
residuals were divided into two groups- those derived from processes in which pentachlorophenol
was used (Table 3-8), and those derived from processes in which creosote was used (Table 3-9).
The pentachlorophenol process residuals included pressure retort, sediments, nonpressure treating
• i . '
tank sediments, storage tank sediments, and door sump sediments. The creosote process
residuals included pressure retort sediments and door sump sediments. Not all samples were
measured for all compounds. Compound by compound, the relative makeup of creosote waste
sediments did not differ greatly from the makeup of pentachlorophenol waste sediments at about
10 times the concentrations present in the pentachlorophenol waste sediments. Ranges and
average concentrations for specific PAHs and phenolics are provided in Tables 3-8 and 3-9.
Metals. Concentrations of arsenic and chromium in wood preserving process sludges or
residuals were available from sampling performed by EPA/OSW. The sampled residuals, all
derived from processes in which inorganic arsenical and/or chromate salts were used, included
treating cylinder residuals (ACA and CCA processes), and one residual from the recycle of
preservative solution (a CCA process). The absolute and relative.concentrations of arsenic,
chromium, and copper depended on the type of preservative used. Ammoniacal copper arsenate
(ACA) residuals had very low chromium concentrations (the formulation does not contain
chromium), but had higher copper concentrations than copper chromated arsenate (CCA)
. residuals. All four CCA process residuals were EP toxic for chromium, and both ACA process
residuals were EP toxic for arsenic. Ranges and average concentrations for specific metals are
*•* *
given in Table 3-10. . '
3-35
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3.7.5 Quantity of Drippage, Wash-Off, and Associated Residuals Generated by the Wood
Preserving Industry " < -
•-' - The volume of treated wood drippage and wash-off residuals generated by the wood . -
preserving industry has not been characterized well. It is uncertain how much drippage is
collected and reused and how much is simply allowed to drip along tram tracks and into wood
' ' ' _. • '
storage yards. However, the extensive soil contamination documented at wood preserving sites
t sampled as part of the listing effort and during RCRA and CERCLA site investigations
! . ' . " '
demonstrates that substantial quantities of treated wood drippage and wash-off are generated.
• /
*• Using information collected by EPA/OSW site inspections, three estimates of the amount
f • "* ^ *
of drippage generated by creosote wood preserving processes were made. The first estimate was
based on information supplied by a plant that reported the kickback drippage of 0.1-0.2 kg/tram
car, based on the amount of material that dripped in the first few hours after treatment. The
kickback rate is 0.018-0.035 kg/m3 of treated wood (0.02-0.03 1/m3). This rate is probably a low
.estimate, because the sampled plant uses an empty cell preservation process and pulls a final
vacuum on the treated wood - both are procedures that reduce drippage. Further, the experiment
lasted only a few hours; while it is expected that initial free drippage from kickback occurs over a
period of 2 to 3 days.
> * "' '• , ' -*
The second estimate was based on information supplied by another plant. This plant
reported that they collected 0.13 to 0.17 liters of kickback on its concrete drip pad for every cubic
meter of railroad ties treated. These estimates may be biased low depending on the production
schedule under which the plant was operating. -A plant producing-near its capacity generally
1 " '" .,
removes a charge from the treating cylinder and transfers it to storage quickly, therefore,
generating a larger volume of kickback in their concrete drip pad area. At plants operating on
slower schedules, a charge may be allowed to drip in the retort for an extended period, and an
'extra period of vacuum may be performed, thereby, generating a smaller volume of kickback.
3-36
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A third estimate involved the assumption that treated wood has a surface-to-volume ratio
of 4:1, that a kickback layer 5-mm (0.2 inches) thick, accumulates on the surface, and that 95
percent of the kickback are collected in the treating cylinder. Thus, the "free drippage" generated
is:
4-m2/m3x0.005mxl,OOOL/m3x5% =
Fourteen percent of the plants that returned RCRA 3007 questionnaires reported
. ;
managing drip pad sludges. The average rate for the eight plants supplying both production and
waste generation information was 0.0462 L/m3 of treated wood. Six of these eight plants were
licensees of one supplier of inorganic preservative chemicals. Each plant reported managing the
same volume of sludge. Thus, this waste generation rate may not be representative of the entire
wood preserving industry.
,i _ '
Very little data on the volume of drippage generated by wood preserving plants were
available. The limited data provided by commentors were not accompanied by sufficient
documentation of the conditions (e.g., temperature) under which the measurements were taken.
The drippage rates supplied by the commentors were multiplied by a factor of 10 to account for
the uncertainty in the available data, concern that there could be many situations in .which
drippage rates would be higher than indicated in the commentors' data, and theoretical estimates
of drippage that were considerably higher than those provided by commentors.
j ' . •
f ,
All wood preserving plants are assumed to produce treated wood drippage. The total
1987 productions estimated by AWPI, by preservative, were used to estimate the total quantity of
drippage generated: ' ' , ,
3-37 .
-------
Preservative >
Creosbte
Pentachlorophenol
Inorganics .
Drippage
Rate
(L/m3)x
1.12 " '
1.56
0.061
Annual
Production
(m3/yr)=
2,314,000 ..
1 1,080,000 v
10,530,000 V'
Annual Industry- Wide
Drippage Generation
. (L/yr)
' 2,592,000
1,685,000 .
642,000
If drip pad sludges are assumed to be generated at the rate reported in the RCRA 3007
questionnaire, the quantity of drip pad sludge produced by plants treating with pentachlorophenol,
creosote, and inorganic preservative formulations amounts to 50,000; 107,000; and 486,000 L/yr,
respectively. .
3.7.6 Concentration of Constituents in Treated Wood Drippage, Wash-off Residuals, and
Associated Residuals t '"•>.•'
The constituents of concern in wood preserving wastes, including treated wood drippage,
• ' i '
wash-off residuals,, and associated residuals, can be divided into five groups: pentachlorophenol
'. . • '•''•' -f
(PCP) constituents, chlorinated dioxin and furan (PCDD and PCDF) constituents, polynuclear
aromatic hydrocarbon (PAH) constituents, phenolic constituents, and metal constituents
(specifically arsenic and chromium). No analysis of preservative formulation was available as it
drips from treated wood However, in-use pentachlorophenol wood preserving formulations,
believed to be similar in composition to drippage, were sampled and analyzed. Table 3-11
presents minimum, maximum, and, average concentrations for the listing constituents and^other
. significant compounds detected in the samples of in-use formulations. Initial drippage and unused
preservative formulations from creosote-treated wood were assumed to have the same
, ~' , - \ t ' '
compositions as raw creosote. (See Table 3-12.) Initial drippage and unused preservative
formulations from wood treated with inorganic preservatives were assumed to have the same
compositions as unused preservative solutions, as specified by the AWPA (Table 3-13).
3-38
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Pentachlorophenol. Concentrations of pentachlorophenol in treated wood drippage were
assumed to be the same as pentachlorophenol concentrations in used (usable) treating solutions.
The concentrations of pentachlorophenol in treated wood drippage ranged from 10,000 ppm to
EPA's 50,000 ppm, and averaged 30,000 ppm. , ' ,
• i
i
Data were available from sampling performed by OSW and from RCRA site inspections
(Appendix D of the Background Listing Document). Preservative solutions from both pressure
and nonpressure processes were sampled. •
s • ,
. • ' •
Polvchlorinated Dioxins and Furans (PCDDs and PCDFsV Concentrations of PCDDs and
PCDFs in pentachlorophenol-treated wood drippage were assumed to be the same as
concentrations in used (but usable) pentachlorophenol treating solution and surface residue
i ' • ' ' ,
(bloom) on wood treated by the Cellon® process. Data were available from sampling performed
by OSW, from RCRA site inspections, and from a study performed by the State of California.
Ranges and average concentrations for specific PCDD and PCDF homolpgs are given in
Table 3-11.
Polvnuclear Aromatic Hydrocarbons and Phenolics. Concentrations of PAHs'and
phenolics in pentachlorophenol-treated wood drippage were assumed to be the same as ,
concentrations in used (usable) pentachlorophenol treating solutions. Data were available from .
sampling performed by EPA/OSW.
-* ' ' • ^ :
Initial free drippage from creosote-treated wood was assumed to have the same
composition as unused creosote (Table 3rl2) because analytical data describing drippage from
creosote-treated wood or in-use creosote solutions were limited. Literature sources provided
concentrations for 11 of the 15 PAH constituents of concern. Concentrations for the remaining
four compounds were estimated based on their proportions in creosote process residuals. (See
Table 3-9.) ;.',..' ' . .
3-39
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Data quantifying the concentrations of PAH constituents for drippage from creosote- _> ,
treated wood were available from one plant and are presented in Table 3-14. .However, these data
are not considered to be characteristic of drippage as it. is released to the environment. The data *
were obtained from samples of "kickback" deposits located in collection pipes and on the ground
adjacent to the plant's treatment cylinder. For most constituents, the measured PAH
concentrations were lower in these samples than the PAH concentrations in unused creosote
/ v . , -. .
(Table 3-12). Because these samples were not collected when drippage occurred, the more
volatile constituents may have vaporized during the residence time on the ground and in the
collection pipes. Vaporization is enhanced at elevated temperatures, under the sun/and with high
wind. In addition, treatment area runoff at the plant is routed to the treatment ponds via the same,
piping system that is used to collect the kickback; therefore, sortie constituents might have been
carried away in the runoff stream. . ;
Metals. Concentrations of metals in initial free drippage were assumed to be the same as
unused preservative solution, as specified in AWPA standards and specifications (Table 3-13),
because analytical data describing drippage from arsenical-treated wood or in-use.organic solution
\ " , , .
were not available. The specifications for the weight percent of metal oxides in CCA-C, AC A,
and ACC were used to estimate arsenic, chromium, and copper concentrations. Further, it was
assumed that CCA and ACC were used as 2.S percent solutions, and that AC A was used as a 3
percent solution. The concentrations of arsenic, chromium, and copper were weighted accordingv
to the productions using each salt-type reported in the RCRA 3007 questionnaires.
3-40
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3.8 Amenability of Wastes to Chemical Analysis
"S ' \
' . t
This section presents the recommended analytical methods for monitoring the regulated
constituents in these hazardous wastes. Several commenters expressed concerns that the
concentrations of PCDD and PCDF in F032 wood preserving wastes may hot be amenable to
. chemical analysis recommended in the Agency's Test Methods for Evaluating Solid Waste (SW-
846) (6). The commenters felt, therefore, that EPA.should withdraw the proposal for regulating
specific PCDD and PCDF constituents in F032. EPA has addressed specific comments raised by
these commenters in the document titled Phase 4 Response to Comments for Wood Preserving '
s ' \ .
Wastes! Given the limited information submitted by the Penta Task Force (Comment PH4P-
00032), EPA has concluded that the PCDD and PCDF constituents that EPA is promulgating as
regulated constituents in F032 can be routinely analyzed by the recommended analytical test
methods in SW-846. Also, EPA has revised Section 3.8 in today's background document to
enhance the discussion regarding the applicability of SW-846 test methods and preparation and
clean up procedures for the analysis of PCDD and PCDF in F032 wastes and, thus, how potential
analytical difficulties can be overcome. • ' ' '
, ' " ' • i •
i
3.8.1 Applicability of SW-846 Methods * .
, EPA methods for the analysis ofBDAT List constituents in nonwastewater and
wastewater forms of wastes are presented in the Agency's Test Methods for Evaluating Solid
Waste (SW-846) (6). Each BOAT List constituent to be regulated in wood preserving wastes is •'•
listed as a target analyte in at least one SW-846 method. Table 3-15 contains a list of the SW-846
methods applicable to each BDAT List constituent in wood preserving wastes. Table 3-16
#
contains a brief description of the instrumentation used in the determinative method.
The SW-846 manual is provided as a guidance document. With the exception of specific
applications where the use of SW-846 methods is mandated by federal regulations, the Office of
Solid Waste provides SW-846 as guidance in performing analyses under RCRA regulations, but
will accept "any appropriate method" that can provide data for "the analytes of concern, in the
-------
( matrix of concern, and the regulatory levels of concern "(17). Except for the preparation of,
TCLP leachates, the .analysis of BDAT List constituents in wood preserving wastes is not one of
i 'f
the applications where the use of SW-846 methods has been mandated by EPA. In order to
comply with the treatment standards for leachates, facilities must use the TCLP procedure in SW-
846 Method 1311 to prepare the leachate [see 40 CFR §268.7(a)]. Once the leachate has been •
prepared, .any appropriate determinative method may be used to analyze the leachate that results
from the application of Method 1311. x
i ' -
It should be noted that EPA may choose to enforce the treatment standards based on
those test methods recommended in the BDAT Background Document. If needed, EPA may
issue subsequent policy memoranda to authorized States, EPA Regions, and/or members of the
regulated community that describe equivalent test methods and may choose to use such equivalent
methods in enforcing these treatment standards.
Because SW-846 serves primarily as a guidance document and because the wastes
regulated under RCRA vary.so widely, the Agency has provided a discussion in Chapter Twp of
" -
SW-846 entitled "Choosing the Correct Procedure." Among other topics, Chapter Two-discusses
adjustments that may be made to the SW-846 methods to address the problems of "trace
analyses" versus "minor" and "major" analyses of different wastes and matrices. Chapter Two
also provides guidance on sample preparation and extraction techniques and describes several
approaches to the preparation and analysis of multiphase samples. For wastes such as F032, this
guidance maylje critical to the successful application of the methods. The following sections of
\ , ' • . ' ' -
this document provide additional information on the analyses of wood preserving wastes.
.'
' ' - *
The Agency is regulating benzo(k)fluoranthene in F032, F034, and F035 wastes as the
* ? -, ' • '
sum of both benzo(k)fluoranthene and benzo(b)fluoranthene, as these two stereoisomers cannot
. be chromatographically separated using methods such as Method 8100 or Method 8270 or other ..
gas chromatographic procedures. The regulation of these two constituents as a sum is being
finalized for both nonwastewater and wastewater forms of these wood preserving wastes.
3-42
-------
3.8.2 Sample Preparation Issues
Samples of wood preserving wastes will require various preparation, extraction or
digestion, clean-up, and determinative procedures. The sample preparation procedures are
described in the SW-846 extraction methods for organic constituents and the SW-846 digestion
methods.for inorganic constituents. The SW-846 3500 Series methods (3510, 3520, 3535, 3540,
3541, 3542, 3545, 3550, 3551, 3560, 3561, and 3580) describe solvents that may be employed
for extraction of organic constituents. The choice of solvent will depend on the constituent, the
sample matrix, and the extraction technique to be employed. Common solvents described in these
methods include methylene chloride, hexane, acetone, acetonitrile, and 2-propanol.
Method 3 500 and the individual 3 500 Series extraction methods describe common
interferences that may arise from solvents, reagents, glassware, and other sample processing
hardware. Method 3500 provides guidance on appropriate steps to eliminate or minimize
interferences from such sources. Additional interferences may be extracted from the sample
> i ' • "'
.matrix itself.
An additional potential problem relevant to the analysis of wood preserving wastes is that
of cross-contamination among samples. Because some constituents may be found in these wastes '
• «
at relatively high levels, there is an increased risk that the sample processing glassware and
equipment and even the analytical instrumentation may provide a means of transferring
**
constituents from one sample to another during the analysis. Such cross-contamination may be
minimized by a variety of laboratory housekeeping techniques designed to segregate samples
known or suspected to be highly contaminated from those that are less contaminated. None of
the techniques is extraordinary, but most require reasonable diligence and awareness of the ,
potential problems: Method 8280A provides guidance on laboratory glassware cleaning
procedures that are designed to minimize cross-contamination, solvent rinsing or prerextraction
procedures for glassware, and segregation of glassware used for extraction of different matrices.
3-43
-------
The standardized EPA quality control procedures described in SW-846 include the
preparation and analysis of method blanks. The results of such blank analyses should be used as
... • i
an indication of the potential for cross-contamination and the presence of interferences derived
from the sample processing steps. Analysts should consult Chapter Two, Method 3500, the
specific extraction method to be employed, Method 8000, and the specific determinative method
for additional information. The corresponding sample preparation, digestion, and determinative
procedures for the inorganic BOAT List constituents also contain information relevant to '
interferences with these analyses. ' ,
i - s
3.8.3 '' Addressing Potential Analytical Difficulties Determining PCDDs and PCDFs in F032
Wood Preserving Wastes
f. . * • • • • . ' '
The analysis of PCDDs and PCDFs is inherently more, complicated than the analyses for
most other compounds and more complicated than the analysis of any of the other BOAT List
constituents for wood preserving wastes. In many instances, the complications arise from the
very low levels at which these constituents may be regulated. However, for the F032 wood
preserving wastes, the proposed regulatory limit of 1 ug/kg (ppb) of total PCDDs and PCDFs
does not pose a challenge on the basis of sensitivity. Rather, the analysis of these constituents is
more complicated than that for other organics because of the number of preparation and clean-up
procedures that are routinely applied during the sample processing. As a result, many of the
' r ' ^ •
laboratories that perform PCDD/PCDF analyses tend to specialize in this area.
f ' - *
Although the treatment standards for wood preserving wastes are based on analyses that
employed SW-846 Method 8280 (September 1986), EPA is recommending that either Method
8280A or Method 8290 be used to comply with the treatment limits promulgated today. These
two analytical methods for PCDDs and PCDFs are provided in Test Methods for Evaluating Solid
Waste (SW-846). Method 8280A is a low resolution mass spectre-metric procedure designed to
achieve quantitative results for the PCDDs and PCDFs at levels of 1 ppb (ug/kg) in solid samples.
Method 8290 is a high resolution mass spectrometric procedure designed to achieve quantitative
results at levels of 10 ppt (parts per trillion, or ng/kg) in solid samples. Method 8290 was
" * . ' ' ,
, . - - 3-44
-------
promulgated in Update II to .the Third Edition of SW-846 in December 1994. Method 8280A
was proposed as part of Update III in July 1995, and will supersede Method 8280 upon
promulgation. Both methods can produce data that meet the data quality objectives for
compliance monitoring, however, the working ranges of the two methods do not overlap.
. ' ,. ' * ' \
Method 8280A differs greatly from its predecessor, Method 8280, and^many of the
differences are specifically designed to address the difficulties posed by matrices such as those
•, . \ '
associated with wood preserving wastes. Thus, analyses comparable to those that were
performed using Method 8280 will be able to be performed using Method 8280 A, and many of
the analytical difficulties may be eliminated through the use of the more recent version. While
Method 8280 A is presently a proposed, not promulgated, method, it is closely based on an
existing Superfund CLP method for these analytes and has been in wide use in commercial
laboratories since 1989. Therefore, it represents a well-established approach to these analyses.
EPA experts final promulgation of Method 8280A by early 1997. .
Methods 8280A and 8290 differ from the SW-846 methods for other organic constituents
in that these two methods are stand-alone procedures that address all the sample processing,
extraction, clean-up, and determinative steps in a single procedure. Thus, Methods 8280A and
8290 contain extraction procedures that address a wide variety of matrices, from aqueous samples
to waste oils. Both methods contain a series of clean-up procedures* including acid-base washing,
, V. . .
silica gel, alumina, and carbon column chromatographic procedures, that are designed to remove
interferences that may also be extracted from the sample. Both methods employ high resection
gas chromatography to separate the PCDDs and PCDFs from one another and both methods
employ mass spectrometers in the selected ion monitoring (SIM) mode to increase the ability of
the detector to differentiate the target analytes from possible interferences. Method 8280A
employs a quadrapole mass spectrometer to achieve unit mass (1 atomic mass unit [amu])
resolution. Method 8290 requires the use of a magnetic sector mass spectrometer to achieve
resolution of l/10,000th of an amu, and exploits the fact that the masses of different atoms are not
whole numbers, but differ in the third or fourth decimal place: • For example, although the mass of
hydrogen (H) is generally considered to be 1 amu, it is more precisely defined as 1.007825 amu.
3-45:
-------
While a low resolution mass spectrometer can distinguish between two compounds that differ in
mass by 1 amu, it would require a-high resolution instrument to determine if the difference was '
"- , '' f , .
due to the loss of a hydrogen atom from one ion or if the difference was due to the presence of
one atom of 13C instead of an atom of 12G. With regard to the analysis of PCDDs/PCDFs in wood
• / • • •>
preserving wastes, the use of a high resolution mass spectrometer allows the analyst to better
distinguish the target analytes from possible interferences, which may differ in mass from the
PCDDs/PCDFs by l/l,000th of an amu or less. , ' •
r
, As with the remainder of the SW-846 methods, Methods 8280A and 8290 are not
prescriptive procedures, but are provided as guidance. Thus, for some samples and matrices, it
may not be necessary to employ all the clean-up procedures described in the method in order to
achieve acceptable results. However, in the case of F032 wastes, it is highly likely that all the
i ' * ' ' „ - ' * ' * ' * ,
clean-up procedures will need to be employed. In addition, the analyst must employ professional
judgement and knowledge of the objectives of the analysis in choosing a specific course of action
for each sample. The analyst may need to consider the following aspects of the overall, analytical
' ' • -v .'
process. ' ' • . "
1 • Collecting a representative sample
' • •
• Low resolution mass spectrometiy vs. high resolution mass spectrometry
Sample size vs. method sensitivity • i
1 . ~ - /
s • ' • . '
EPA believes that thoughtful consideration of these aspects of the analytical process, combined
with careful application of the procedures described in the methods, will permit the analysis of
F032 wastes subject to regulation.
..-.•,,'• ' /
Collecting a Representaftive Sample ,
As with any environmental analysis, the sample results are only as good as the sample that
• - l ' • '
was collected. Sample collection procedures for F032 wastes should focus on the collection of a
representative sample. Chapter Nine of the SW-846 manual describes various approaches to
3-46 ' /•-....
-------
designing and conducting sampling. In addition, EPA has issued guidance on sample collection
' ! ' - I
procedures in documents such as "Guidance for the Sampling and Analysis of Municipal Waste
Combustion Ash for the Toxicity Characteristic"-(EPA530-R-95-036, June 1995) that have
relevance to the sampling of incinerator ash. As noted in Chapter Two of SW-846, multiphase
samples may require additional efforts. If samples of all phases can be collected, it may be '
advisable to analyze each phase separately. .
Mass Spectrometer Resolution •
As noted above, the principal difference between Methods 8280A and 8290 is the mass
resolving power of the mass spectrometer. The use of the high resolution instrument in Method
8290. allows the analyst to better distinguish between the target PCDDs/PGDFs and potential
interferences that are also extracted from the sample matrix. Therefore, Method 8290 would
appear at first to be the preferred approach to the analysis of F032 wastes. However, as written,
Method 8290 is designed to achieve much lower quantitation limits than Method 8280A, on the
order of 10 ppt in solids versus 1 ppb for Method 8280A. In addition, analyses for
PCDDs/PCDFs at sub-ppb levels require that the laboratory carefully control sources of
background contamination., A sample of F032 waste containing PCDDs/PCDFs near the
proposed 1 ppb limit could be viewed by some laboratories employing Method 8290 as
unacceptably "dirty" for a facility attempting to perform analyses iii the ppt range.
In addition, samples near the 1 ppb regulatory limit would be well above the calibration
range of Method 8290. Since Methods 8280A and 8290 employ forms of isotope dilution
quantitation, where the standards used for quantitation are added to the samples at the time of
extraction, extracts of samples above the calibration range cannot simply be diluted and
reanalyzed. A new sample aliquot must be extracted and analyzed in these instances.
The use of Method 8280 A lessens the potential problems of highly contaminated samples
for the laboratory, however, it may not be capable of separating the target PCDDs/PCDFs from
" all interferences.. One approach to the analysis of F032 wastes would be to employ Method
•> ' ,'-.'.• 3-47 • '. • ' •
-------
8280 A at first, and determine the approximate range of concentrations of the target *
PCDDs/PCDFs in the specific waste samples. If the target PCDDs/PCDFs cannot be detected by
Method 8280 A, then the more sensitive method, 8290, would be employed to analyze the samples
1 " " •'
J > ' ' '•
and ensure that the waste does not contain PCDDs/PCDFs above the regulatory limit of 1 ppb.
Sample Size versus Method Sensitivity
* . ^"" '"" """"""""'' • -r .t * t
• f ' ' '
: Another alternative would be to employ Method 8290, but adjust the size of the sample
that is extracted such that the method is less sensitive, so that samples near the regulatory limit
will fall within the calibration range of the method. - Such adjustments to sample sizes are allowed
within the flexibility inherent in SW-846; methods. ..'....
If the use of a smaller size sample is likely to raise issues of the representativeness of the
sample, a third alternative would be to extract a larger sample, but spike it with a larger aliquot of
the "internal standard solution" used for quantitation and increase the volume of the final extract.
by the same proportion. In other words, if 10 times as much internal standard solution is added to
. x , ' ' . " '
the sample prior to extraction, the final extract is concentrated to a 10 times larger volume, e.g.,
200 uL versus the 20, uL volume specified in the method. (
Extraction and Clean-up Procedures • ..-
' ' - - , •.•'..•'"•"-' • ' i
Both Methods 8280 A and 8290 contain a wide range of possible extraction and extract
clean-up procedures. Of particular relevance to the analysis of F032 waste are the procedures
described in these methods for the extraction of:
*. chemical waste samples, including:
* . ' •• x .
chemical sludges,
-•'.-- wet fuel oil, ' '
- still bottoms, and _ , .
- . • oils" - ' \ ' ' . •• /
*• ' " ' • '
• fly ash ","•'•
s • "',,'• - - ' -
. . - 3-48 • -
-------
These methods contain clean-up procedures that are applied to sample extracts to remove
potential interferences that may be extracted from the sample matrix. These clean-ups include:
• Acid/base washing, using concentrated sulfuric acid and potassium hydroxide
' solutions .
• Silica gel column chromatography combined with alumina column chromatography
; •'•.', Carbon column chromatography .
These clean-up procedures are well-established aspects of PCDD/PCDF analysis, and all three
should be applied to samples such as those from F032 wastes. •
Summary Recommendations Regarding Analytical Difficulties .
•\
. The choice of an analytical method will depend on generator knowledge of the waste
itself. This information should be conveyed to the laboratory prior to shipment of samples, so that
' the laboratory can take appropriate steps to segregate more highly contaminated samples and
choose the analytical technique that provides the appropriate data. Given this information and the
understanding that the goal of the analysis is to establish compliance with a regulatory limit of 1
ppb of PCDDs/PCDFs, EPA believes that either Method 8280A or Method 8290, with
modifications similar to those described above, should be adequate to monitor the analytes of
interest in F032 wastes subject to regulation. ,. '
-1 ' - <
^ ' • • . '
3.9 Current Wood Preserving Waste Management Practices , .
' .
This section presents currently reported waste management practices in use in the United
States for wood preservation wastes (1). .
3-49
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3.9.1 Reported Wastewater Management Practices
Thirty-three percent of the plants that responded to a 1985 RCRA 3007 Survey reported'
the generation and management of some process wastewater. Many plants did not describe the
process that generated the wastewater, but instead labeled it with the name of the treatment
process from which it was discharged (oil/water separator wastewater, filtration wastewater,
cooling tower blowdown, spray field wastewater, and the general "treated wastewater
' • *- ' ' ,/ !
discharge"). . .
The most frequently named process wastewater source was treating cylinder condensate.
Drip pad and process area wastewater, sludge/work tank water, drum washings, scrubber liquor
i f i • "*
from wet air pollution control devices, and pole wash waster were also named as sources of
wastewater.
/ ' ' ' . .
', *• *
Wastewater management practices in use in 1984 at the surveyed plants are summarized in
1 - i
Table 3-17. Sixty-three percent of the surveyed plants that reported managing wastewater
discharged their process wastewater to POTWs. Usually, this wastewater was pretreated by
oil/water separation in tanks. Teh percent of the plants also used some type of aeration process,
and 3 percent used activated carbon filtration as well. Thirteen percent of the plants reported
» • ' ' ' . •
storage or disposal of process wastewater in land-based units (e.g., land application, evaporation
ponds, and surface impoundments); , ,
,.-''• * . '
•'• '
Few inorganic-process wood preserving plants discharge wastewater. At these plants
zero discharge is achieved by reusing process wastewater and some contaminated precipitation.
Contaminated precipitation is also managed at these plants through soil percolation and
evaporation.
' . ' i
Additional information on wastewater management practices is contained in the
Preliminary Data Summary for the Wood Preserving Segment on the Timber Products Point
Source Category (14). - . . ;(
. 3-50
-------
3.9.2 Reported Process Residuals Management Practices
•S ' - .
f
. Ninety percent of the plants that returned their RCRA 3007 questionnaires reported
managing process residuals. vMany plants use more than one preservative. Fifty-one percent of
* - ' . . i
the plants generated residuals from processes using inorganic arsenical and/or chromate salts, 35
. percent from processes using pentachlorophenol, and 35 percent from processing using creosote.
The types of.residuals managed at these plants, by preservative, are listed in Table 3-18. Plants
using inorganic preservatives reported generating more of their process residuals as door sump
sediments and preservative recycling residues than did plants treating with pentachlorophenol or
creosote. In contrast, plants treated with the organic preservatives reported generating more of
their process residuals as treating cylinder sediments.
The number of plants generating process drips and spills is probably underestimated. The
exact source or quantity of drips and spills are rarely determined because they are potentially land-
disposed at the point at which they are released. In the 3007 Survey responses, reporting plants
probably included drips and spills generated from maintenance operations with reports of other
types of wastes.,
Reported process residual management practices are for the surveyed plants summarized
in Table 3-19. Most of the plants contract with waste removal services to transport and dispose
of their process residuals. Many plants reported that their wastes were treated as hazardous and
were disposed in secure landfills. Six plants that are licensees vf a supplier of inorganic
preservatives reported that their wastes were removed and disposed of by the chemical supplier.
3.9.3 Reported Treated Wood Drippage Management Practices
In 1987, AWPI surveyed the wood preserving industry. An extensive questionnaire was
/ .' , . ' .
sent to 570 wood preserving plants, and approximately 160 usable responses were returned to
AWPI. Selected results from this survey were provided to EPA in December 1987. In this
survey, AWPI collected information on the percentage of plants with surfaced or covered drip.
. - - 3-51
-------
pads and storage pads: The survey results provided by AWPI that pertain to the management of
' ''""•* • • • • . •
treated wood drippage at wood preserving plants are summarized in Table 3-20. .
i •
Drip pads are used to collect excess preservative that drips from the treated wood when it
•' • • • , ,' '
is first removed from the treating cylinder. Plants that do not have surfaced drips pads generally
/ • (,
allow excess preservatives to drip directly onto the ground. Most plants with surfaced drip pads
report reusing the collected drippage. AWPI did not report the management practices used by
plants that do not reuse collected drippage. Forty to 50 percent of the plants that use
pentachlorophenol and/or creosote have a surfaced drip pad, while 91 percent jof the plants that
s ' • ,
use inorganic preservatives have a surfaced drip pad. A larger percentage of the inorganic plants
have surfaced drip pads because they are generally newer than other wood preserving plants and
i •• • , . " i . /. • ' . .
are specifically designed for the recovery and reuse of preservative drippage.
Only 12 to 13 percent of the plants treated with pentachlorophenol arid/or creosote have
surfaced storage pads (i.e., long-term storage yards). Thirty-eight percent of plants treated with
inorganic preservatives have some surfaced storage area. The Agency concluded that
approximately 88 percent of pentachlorophenol arid creosote plants, and approximately 62
percent of inorganic plants, treated wood preservative drippings, and treated wood preservative
drippage, and treated wood precipitation wash-off.
'. -l
A few plants currently store surface-protected wood on concrete or asphalt ^pads with a
f ' - . • . .. ' i
system to collect excess surface preservative, which either drips from the wood or is washed'from
the surface by rain. The collected runoff may be used as makeup water (after filtration) for the .
; >. *"
preservative formulations or may be discharged to surface waters with other plant washwater. ,
3-52
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TABLE 3-1
REGIONAL DISTRIBUTION OF WOOD PRESERVATION FACILITIES
Region
Northeast
North Centra!
\
Southeast
South Central
. i "
Rocky Mountain
Pacific Coast
All Regions
- 1993
Number of Plants
.54
• 87
143
125
., 22
40
471
Source: Draft Capacity Background Document, March 8,1995.
3-53
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TABLE 3-2
HISTORICAL CONSTITUENTS OF CHLORINATED PHENOLS
j .. Constituent
Pentachlorophenol (%)
Tetrachlorophenol (%)
2,3,7,8-TCDD (ppb)
TCDDs (ppm)
PeCDDs (ppm)
\
HxCDDs(ppm)
HpCDDs(ppm)
OCDD (ppm)
TCDEs (ppm)
PeCDFs(ppm)
HxCDF (ppm).
HpCDFs (ppm)
OCDF(ppm)
. , Technical Grade
Pentachlorophenol
85-93 .
1.5-10.1
<0.03-<0.1
<0.03-18
<0.03-100 • "
<0.03-1,000
<0.03-1,000
0.6-3,600
<0.01-10
<0.03-40
<0.03-90 -
<0. 1-400'
<0. 1-300
Tetrachlorophenol
3.1-17
7.7-14
0.21-0.56 '.
. <0. 005-0.25
<0.03-1.4
<0.03-20
/ - 0.3-88
0.7-216
<0.02-ll'.l
<0.03-22.1
0.1-60
: 1-50
0.062-2.9. ,
Source: (1)
3-54
-------
TABLE 3-3
TYPICAL COMPOSITIONS OF CREOSOTE,
COAL TAR, AND PETROLEUM OIL ,
Major Components
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzofluorenes
Biphenyl
Carbazole
Chrysene " , '
Dibenz(a,h)anthracene
Dibenzofuran
Dimethylnaphthalenes
Fluoranthene
Fluorene
Methylanthracenes' ,
Y
Methylfluorenes
1 -Methylnaphthalene
2-Methylnaphthalene
Methylphenanthrenes
Naphthalene
Phenanthrene
Pyrene
Raw Creosote
/
Range
(Percent)
9-14.7
2-7
0:16-0.26
0.04-0.06
1.0-2.0
0.8-1.6
1.2-2.0
2.6-3.0
0.01-0.04
4.0-7.5
2.0-2.3 ,
0.5-10
7.3-10
3.9-4.0
.2.3-3.0 .
0.9rl2
1.2-12
.,3.0
1 1.3-18
16-21
1.0-8.5
- Average
(Percent)
10.9
4.5
0.26
0.06
' 1.5
1.1
1.6
. 2.8
0.04
.'5.5
2.15
6.9
8.8
3.9
- 2.7
4.9-
5.3
3.0 ,
7.4
. 18.1
5.5
. High
Temperature
Coal Tars
NDA
1.5
0.65
0.55 :
'NDA .
NDA
0.6
1.1
0.10
NDA
NDA
3.3 ,
NDA
NDA
NDA
NDA
' .NDA" '
NDA
10
• -5
2.1
A
TI ' •
Petroleum Oi!
(#2 Fuel Oil) ,
' 0.002-0.005
0.006
NDA
NDA
NDA .
NDA
/ NDA
0.0004
NDA
0.008
NDA
0.0003-0.0007
0.004-0,02
0.009-0.028
0.006-0.035
0.082
0.12
NDA
0.01-0.03
' . 0.03
0.0005-0.002
Source: (1)
3-55
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TABLE 3-4
COMPOSITIONS OF THE MOST COMMONLY USED ARSENATE AND GHROMATE
PRESERVATIVES
Preservative
'Chromated Copper-
Arsenate Type C
(CCA-C)
Ammoniacal
Copper Arsenate
(ACA); ..'
Acid Copper
Chromate(AZC);
Chromated Zinc
Chloride (CZC)
[Fluoro-Chrome-
Arsenate-Phenol
(FCAP)
pH Limit
1.6-3.0
' NDA
2.0-3.9
2.8-4.0
5.5-7.8
Dry- Weight Formulation Basis .
Arsenic
(AS205)
(%)
3.40
50.2
NDA
NDA,
25-
Copper
(Cup)
(%)
18.5
49.8
3L8
NDA
NDA
Chromium
(CrO,)
(%)
47.5
NDA
. 68.2 . -
, 20
37
'Zinc
(ZnO)
. (%)
NDA
NDA
NDA
80
NDA
t .
Concentration in
Typical Treating Solution
Arsenic
- (%)
0.55
1.14
NDA
NDA
0.33
Copper
.(%)
0.37
1.19
0.63
NDA,
NDA
Chromium
(%) ' •
" 0.62 .
' NDA
0.89
s 0.21
0.38
Zinc
(%)
NDA
NDA
NDA
1.29
NDA,
fl
; Source: (1)
3-56
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\
TABLE 3-5
BREAKDOWN OF CONDITIONING METHODS
BY PRESERVATIVE TYPE
(RCRA 3007 SURVEY DATA, 1984)
Conditioning Method
Air Drying (Seasoning) '
Kiln Drying
Steam Conditioning
Boulton Conditioning
Vapor Drying
TOTAL
i ...
Percent of Plants With
Creosote
• - ' 36
20
26 - .' •
16
2' ' . ' '
100
PCP
39
29
20
12
0 .
100
. Inorganics
47
52
1
.. 0
• 0
100
Source: (1)
3-57
-------
TABLE 3-6
GENERATION OF WOOD PRESERVING WASTES
• .Waste Type
Quantity Generated (Tons)
F032
Organic Nonwastewater
Inorganic Nonwastewater
Organic Wastewater
Inorganic Wastewater
Soil
Debris
10,400
2,200
26,800
140,800
,10,500
20
F034
Organic Nonwastewater
Inorganic Nonwastewater
Organic Wastewater
Inorganic Wastewater
Soil . . ,N .
Debris .
28,800
1,600
35,400
2,579,900
"9,400
3
F035
Organic Nonwastewater
Inorganic Nonwastewater
Organic Wastewater
Inorganic Wastewater
Soil
Debris
600
1,900
3,400.
9,800
2,700
.0
Total
Organic Nonwastewater
Inorganic Nonwastewater
Organic Wastewater
Inorganic Wastewater T
Soil
Debris
39,800
5,700
65,600
2,730,500
22,600
23
Source:. Draft Capacity Background Document, July 18,1995 (16).
3-58
-------
. . • '. ' • TABLE 3-7 - ''•'•,
CONCENTRATIONS OF LISTING CONSTITUENTS AND OTHER SIGNIFICANT
COMPOUNDS IN WOOD PRESERVING WASTEWATERS FROM ;
PENTACHLOROPHENOL AND/OR CREOSOTE PROCESSES
Compounds Selected As The,
Basis For Listing
-
, -i
Pentachlorophenol (1)
Benz(a)anthracene (1,2)
Benzo(a)pyrene (1,2)
Benzo(k)fluoranthene (2)
Dibenz(a,h)anthracene (1,2)
Indeno(l,2,3-c,d)pyrene (1,2)
Naphthalene (2)
Arsenic (1,2)
Chromium (1,2)
TCDDs (1)
PeCDFs (1)
HxCDDs (1)
HpCDDs(l)
TCDFs(l) J
PeCDFs (1).
HxCDFs(l)
HpCDFs(l)
Minimum
Detected
Concentration
(ppm)
0.01
0.03
0.007
0.02
0.1
0.006
0.1
0.003 ,
0.004
(ppb) '
0.001
6.008
0.03
0.009
0.0006 '
0.001
0.001
0.002
Maximum
Detected
. Concentration
(ppm)
300
10'
10
4
•• \
1
10
400 '
30
10
(ppb).
8
20
200
' 80
2
i
300
10
50
' Average
Detected
Concentration
(ppm)
10
- 3 .
3
1
6.5.
5 . •
50
5
2
(ppb)
.4
9
30
20
0.9
60
n
3
10
Number of
Data Points '
• 25
12
8
6
4
6
. 18
.11
10
5
5
' 8 -' ,
9
' 5\
5 - •
\
8
8
Source: (1) , . ' ''
NA - Not analyzed / ' " •
(1)-Listing Conistituent for F032 ,
(2) - Listing Constituent for F034
Note: All concentrations have been rounded to one significant figure.
3-59
-------
TABLE 3-7 (continued)
Other Compounds
Acenaphthene ( .
Acenapthylene
Anthracene (1,2)
Benzo(b)fluoranthene
Benzo(g,h,i)perylene .
Biphenyl .
Chiysene
Fluoranthene
Fluorene
Lead
Phenanthrene + Anthracene
Phenol(2) .
Pyrene(2), ' .
: ' •
2,3,7,8-TCDD ' •
OCDD
OCDF
Minimum
Detected
Concentration
mg/L (ppm)
1
0.006
20
0.03
0.006 '
50 .
' 0.02
. 0.3
0.3
0.001
' 0.9
. 0.2
0.2
' (ppb)
; NA
0.02
0.03
. Maximum
Detected -
Concentration
mg/L (ppm)
300
.7
• . 400 ^
2
, 0.3 -
. 50
6
400
/ 200
0.3
600
- 300
300
(ppb)
NA
300
40 v
Average
Detected
Concentration
mg/L (ppm)
30
1
200 1
0.7 '
0.1
50 •'
0.9
' 30
20
. 0.1
50
50 .
30
(ppb)
«
. 50
10
Number of
Data Points
^
id
.11
2
'' ' 6
4
1
12.
14
11 . .
6
- ' 14
6
12
. ' .
0
11
6
Source: (1) . , . '
NA - Not analyzed. . '
(1) - Listing Constituent for F032.
(2) - Listing Constituent for F034V
s~ '
Note: All concentrations have been rounded to one significant figure.
3-60
-------
TABLE 3-8
CONCENTRATIONS OF LISTING CONSTITUENTS AND OTHER SIGNIFICANT
COMPOUNDS IN WOOD PRESERVING PROCESS SLUDGES OR
RESIDUALS FROM PENTACHLOROPHENOL PROCESSES
Compounds Selected As The
Basis For Listing
Pentachlorophenol . .
Benz(a)anthracene
Benzo(a)pyrene
Dibenz(a,h)anthracene
Indenb(l,2,3-c,d)pyrene '.
Arsenic (1) :
Chromium (1)
' »•
TCDDs "'. .
PeCDDs ' .
HxCDDs
HpCDDs
.TCDFs
PeCDFs '
HxCDFs
HpCDFs
Minimum
Detected
Concentration
(ppm) •
t
40
5
50 -
50
20
NA
NA
(ppb)
0.001
0.2
0.06
0.5 .
0.01
008
0.01
0.3
Maximum
Detected
Concentration
(ppm)
30,000
3,000
1,000 .
300
100
NA
• ~ NA
(ppb)
5 -
2
5,000
100,000
30
1,000
10,000.
20,000 '
Average
Detected
Concentration
(ppm)
20,000
900
500
200
70
• ••
«.
(ppb)
. . 3
1
2,000
30,000
20
500
3,000
4,000
Number of
Data Points
•'
g
, 4 " '
3
2
2 '
0-
0
2
2
9
10
4 '
'5 ,
7
7
Source: (1) ''
NA- Not analyzed. , - • ' '
U - Compound was analyzed for but not detected; value listed is the lowest detection limit reported.
(I) - This compound was not analyzed for but is included as a listing constituent because of the potential for cross-,
contamination.
'(2)- • "GC peak resolution was not sufficient to provide individual quantitation of benzo(b)fluoranthene and
benzo(k)fluoranthene. ' ; . .
(3) - • 2,3,7,8-TCDD was not detected in any of the three samples analyzed. The value listed is the lowest detection
limit value reported. . , •
Note: All concentrations have been rounded to one significant figure.
3-61
-------
TABLE 3-8 (cont.)
Other Compounds
2,4-Dimethylphenol
2,4,6-Trichlorophenol
. Acenaphthene
Acenapthylene
Benzo(b)fluoranthene (2)
Benzo(g,h,i)perylene. -
Chrysene
5 | .
Fluoranthene
Fluorene
Phenarithrene :
Phenol
Anthracene
Anthracene/Phenanthrene
Benzene .
Toluene
Naphthalene '
Pyrene '
2,3,7,8-TCDD ' • „ .
OCDD .-:
OCDF ,
Minimum
Detected
Concentration
(ppm)
10
30
40
30
100
40
10
-20
60
300
70
30
100
' 0.03
0.8
50
30
'(ppb)
<5(3)
1
0.2
Maximum
Detected
Concentration
(ppm)
200
30 '
"8,000 '-'
.' 400
2,000
300
3,000
10,000
8,000
30,000
500
- 7,000 .
100
. 0.03-
0.8
20,000
10,000
(ppb)
1
90,000
20,000
Average
, Detected
Concentration .
(ppm)'
80
30
2,000
. • 200
. 800
' 100
- 700
3,000
2,000
9,000
300
2,000 "
100 .
0.03
/
0.8
5,000
" .2,000
(ppb)
„
30,000
4,000
Number of
Data Points
-•
• ' 3
• ' 1
6
* 3
3
2 .
5 ;
6
6
,. 5 .
2
5
1
1
1
6
6
,'
'-• 3
10
7 •
3-62
-------
Source: (I) , -
NA - Not analyzed! . • '
U - Compound was analyzed for but not detected; value listed is the lowest detection limit reported.
(1) - This compound was not analyzed for but is included as a listing constituent because of the potential for cross-
contamination. . '
(2) - vGC peak resolution was not sufficient to provide individual quantitation of benzo(b)fluoranthene and
benzo(k)fluoranthene. .
(3) - 2,3,7,8-TCDD was not detected in any of the three samples analyzed. The value listed is the lowest detection
limit value reported. . • ' . '
. t\ '. • .
Note: Ail concentrations have been rounded to one significant figure.
3-63
-------
TABLE 3-9
CONCENTRATION OF LISTING CONSTITUENTS AND OTHER SIGNIFICANT
COMPOUNDS IN WOOD PRESERVING PROCESS RESIDUALS
FROM CREOSOTE WOOD PRESERVING PROCESSES
t
Compounds Selected As The
Basis For Listing ....
Benz(a)anthracene . '-.
Benzo(a)pyrehe
Benzo(k)fluoranthene (1)
Dibenz(a,h)anthracene
In,deno(l,2,3-c,d)pyrene
Naphthalene
%
Arsenic (2)
Chromium (2)
V
Other Compounds ,.
2,4-Dimethylphenol
2,4,6-Trichlorophenol
Acenapthene ;
-, Acenapthylene
Benzo(b)fluoranthene
Benzo{g,h,i)perylene
Chrysene
Fluoranthene
Fluorene
Phenanthrene
Phenol /
Anthracene
Anthracene/Phenanthrene
Minimum
Detected
Concentration-
• (Ppm)
.300
2,000
.2,000
' 100
100
700
NA - .
NA
(ppm)
300
50
' 500
800
2,000.
200
3,000
, 4,000
800 ..
s 40,000
. 800
' 20,000
5,000
Maximum
Detected
Concentration
(PPm)
8^000 .-
3,000
2,000' ,
700 .
. 300
60,000
NA ,
. NA
(ppm)
1,000
50
30,000
V
2,000
3,000
500
. 7,000
• 40,000
30,000
70,000
3,000
20,000
6,000
• Average
Detected
Concentration
(ppm)
4,000 .
2,'OOb
2,000 '
.400
, 200
40,000
•m-mi
•>.
(ppm)
600
1 50 "
20,000
1,000
2,000
300 .
,5,000' ,
20,000
10,000
/
50,000
2,000
20,000
" 5,000
Number of
Data Points
••• -^
4' ,
3 ' •
1
''3
3 ,
4
0
0 -
2
1
'.' ' • 5
> • 2
3
/3
3 .
5
4
•3 • '
— i
2
3
' •' 2
3-64
-------
TABLE 3.-9 (continued)
Compounds Selected As The
Basis For Listing
Benzene
*
Pyrene
Minimum
Detected
Concentration
0.007 ',.
2,000
Maximum
Detected
Concentration
0.007
30,000
• Average -
Detected .
Concentration
0.007
' 10,000
Number of
Data Points
1
5
Source: (1) . • • • . s
NA- - Not analyzed. , ' • ; . .,
U - Compound was analyzed for but not detected; value listed is the lowest detection limit reported.
(1) - GC peak resolution was not sufficient to provide individual quantitatiori of benzo(b)flubranthene and
benzo(k)fluoranthene. . \ '
(2) - This compound was not analyzed for but is included as a listing constituent because of the potential for cross-
contamination. .
All concentrations have been rounded to one significant figure. • .
3-65
-------
TABLE 3-10
CONCENTRATIONS OF LISTING CONSTITUENTS IN
WOOD PRESERVING PROCESS RESIDUALS FROM
INORGANIC WOOD PRESERVING PROCESSES
Compounds Selected, As
The
Basis For Listing
Arsenic ,
Chromium
Lead '
- Minimum
Detected
Concentration
(ppm)
5,000
70
j •
5
, Maximum
Detected
Concentration
: (ppm)
800,000
30,000 «
300
, Average
Detected
Concentration
(ppm)
-100,000
10,000
80
Number of
Data Points
•
7
" '-' 7
6
Source: (1)
All concentrations have been founded to one significant figure.
3^66
-------
TABLE 3-11
CONCENTRATIONS OF LISTING CONSTITUENTS AND OTHER SIGNIFICANT
COMPOUNDS IN PENTACHLOROPHENOL PRESERVATIVE SOLUTIONS
(DRIPPAGE)
Compounds Selected As The
Basis For Listing ,
i
Pentachlorophehol
Benz(a)anthracene
Benzo(a)pyrene
Dibenz(a,h)anthracene
Indeno(l,2,3-c,d)pyrene
Arsenic(l)
Chromium (1)
,
TCDDs
PeCDDs
HxCDDs
HpCDDs
TCDFs
PeCDFs; - ,
HxCDFs.
HpCDFs
Minimum
' Detected
'Concentration
(ppm)
- 10,000
•80
50
7
50 U
•NA
NA :. , ;
(ppb)
1
' 30
100
9,000
1
• 100
200
100
Maximum
Detected'
Concentration '
(ppm)
50,000 -
80 J
'so
7
50 U
NA' • .
NA. '
(ppb)
1
70
5,000
100,000
30
1,000
10,000
10,000 '
Average
Detected
Concentration
(ppm)
30,000
80
50 .-
• • :' -7 ' ' •
._ ' '
-— '
MB-flt
(ppb)
1
'50
2,000
. 4,000
20
400
3,000
5,000
Number of
Data Points
5 •'
1
1
1. ..
-.2
0
0
1
.2 '
8
8
.3
5
8.
8
Source: (1) ^ , _
NA- - Not analyzed. . ' • . .
U - Compound was analyzed for but not detected; value listed is the lowest detection limit reported,
(1) - , ' This compound was not analyzed for but is included as a listing constituent because of the potential for cross-
contamination. • >. \ ' . • '
All concentrations have been rounded to one significant figure. '
3-67
-------
TABLE 3-11 (continued)
Other Compounds
• _. '
2,4-Dimethylphenol
Acenaphthene
Aceriapthylene
Benzo(b)fluoranthene
Beiizo(g,h,i)perylene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Pyrene
Phenanthrene
Anthracene
: ,
2,3,7,8-TCDD
OCDD
OCDF "• '
Minimum
Detected
Concentration .
(ppm)
'40.
300
. 10
90
4
70
40
300
, 1,000
70
1,000
.300
(ppb)
2U
5,000
400
Maximum
, Detected
Concentration
(ppm)
40
. 500
10
90
4
' 70
400
1,000
7,000
300 ,
4,000
300
'(ppb) '
„
200,000
100,000
Average
Detected
Concentration
(ppm)
40
.400
10
90
C ' .
4
70
200
'700
'4,000
200
2,000
300
: (ppb)
•—
90,000
3,000
Number of
. Data Points-
1
3 -
j
I
1
. - 1 :
3
3
3
3 .
3
1
-
. '" '5 ' r
10
8
Source: (1) „.
NA- Not analyzed. •
U - Compound was analyzed for but riot detected; value listed is the lowest detection limit reported.
(1) - This compound was not analyzed for but is included as a listing constituent because of the potential for cross-
contamination. , .
Note: All concentrations have been rounded to one significant figure.
3-68
-------
TABLE 3-12
CREOSOTE COMPOSITION, PERCENT
Constituent <
Acenaphthene
Acenapthylene
Anthracene
Benz(a)anthracene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzo(b4-k)fluoranthene
Ghrysene
Dibenz(a,h)arithracene
Fluoranthene
Fluorehe
Indeno( 1,2,3 -c,d)pyrene
Naphthalene
' i
Phenanthrene
Pyrene ,
Raw Creosote '
A
9.0
__
2.0
_.
•«
j—
— —
3.0
— w
10.0
10.0
.„
3.0
21.0
8.5
B
14.7
«... •"
__
" __
_*,
_*
>
2.6
„ .
7.6
7.3 .
._
1:3
17.4
7.0
C
9.0
».
7.0
»
..
.- 4
• __
..
._
3.0,
9.0
„..
, 18.0
16.0
, .1:0 '
D
...
_ _
« y
0.16-0.26
__•
0.04-0.06
\
..
0.01-0.04
0.49-0.93
..
\
—
..
• —
Overall
Average A-D*
(Percent)
. 10.9-
0.54b
4.5
0.26
0.12b '
0.06 '
2.14b
2.8 .
. . 0.04
* 6.7
8.8
OJOb
'7.4
• 18.1
^ ^ 5.5
Source: (1) .
'Average is presented for calculation purposes.
'Estimated from creosote, characterization references supporting the proposed rule.
1-69
-------
TABLE 3-13
ESTIMATE OF CONSTITUENT CONCENTRATIONS OF TOTAL METALS,
INORGANIC-TREATED WOOD DRDPPAGE AND
UNUSED PRESERVATIVE FORMULATIONS
Constituent
Arsenic
Chromium
Copper
Average -Concentration (ppm)
5,500
- 6,172
' . 3,787
Source: (!)
3-70
-------
TABLE 3-14
CONCENTRATIONS OF POLYNUCLEAR AROMATIC HYDROCARBONS (PAHs)
IN DRIPPAGE FROM WOOD TREATED WITH CREOSOTE
Constituent^
Acenaphthene
Acenapthylene
.Anthracene
Benzo(g,h,i)perylene
• • .x*
Benzo(a)pyrene -
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrerie
Pyrene
... , Measured
Concentration
(ppm)
.5,265 .
'NA'" •• •'
175,000
. • • NA •"
733 '
2,590 . .
14,750
7,225
1,280
.28,750
12,100
•^ Estimated^
Concentration
(ppm)
, 109,000
' 5,400
•. (
45,000
1,200
600
28,000 •
i 67,000
88,000
74,000
181,000
55,000
Source: (1) .
NA - Not analyzed.
3-71
-------
TABLE 3-15
SW-846 ANALYTICAL METHODS APPLICABLE TO CONSTITUENTS
PROPOSED FOR REGULATION IN F032, F034, AND F03S
Constituent
Phenol '
2,4-Dimethylphenol , . /
2,4,6-Trichlorophenol
2,3,4,6-Tetrachiorophenol . ,
Pentachlorophenol
Acenaphthene ' •
Anthracene '
Benz(a)anthracene
Benzo(a)pyrene
BenzoC^fluoranthene1
Chrysene
Dibenz(a,h)anthracene
Fluorene
Indeno( 1 ,2,3 -c,d)pyrene
Naphthalene '
Phenanthrene • ;
.*
Pyrene -.- " •
Arsenic ,
Chromium \ •
Tetrachlbrodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
\
Hexachlorodibenzo-p-dioxins
SW-846 Method1
8270 . .
8270
8270
8270
8270
8270,8100
8270,8100
8270,8100
8270,8100
~ . 8270, 8100 ;
8270, 8100
8270,8100
8270, 8100
8270,8100
t 8270,8100
8270, 8100 • .
8270,8100
7060, 6010
7190,6010
8280, 8290
8280,8290
8280, 8290
'Because benzo(b)fluoranthene and benzo(k)fluoranthene coelute on gas chromatography columns, this constituent
. is regulated as a sum of these two compounds. ... • ' • •
3-72
-------
TABLE 3-15 (continued)
Constituent .
Tetrachlorodibenozfurans
Pentachlorodibenzofurans
Hexachlorodibenzofurans
SW-846 Method1
8280,8290
8280,8290
8280, 8290
3-73
-------
TABLE 3-16
ANALYTICAL METHODS
INSTRUMENTATION
MethodNumber
6010A :
7060 v
7190
8100
8270
8280
8290
Method Instrumentation
Inductively Coupled Plasma
• \ • ' •
Graphite Furnace Atomic Absorption Spectroscopy ' ,
Flame Atomic Absorption Spectroscopy
Gas Chromatography/Flame lonization Detector
Gas Chromatography/Mass Spectrometry
Gas Chromatography/Mass Spectrometry
High Resolution Gas Chromatography/Mass Spectrometry
Source: Test Methods for Evaluating Solid Waste, S W-846.
3-74
-------
TABLE 3-17
REPORTED WASTEWATER MANAGEMENT PRACTICES IN USE IN 1984
AT SURVEYED WOOD PRESERVING PLANTS (RCRA 3007 SURVEY DATA)
Management Practice
i t
Discharge to POTW
Discharge to Surface Water !
Reuse of all Process Wastewater
Removal by Waste Contractor ,
Storage/Disposal in Land-Based Units
Thermal Evaporation in a Tank
Management not Specified
Percent of Plants"
- . 63 • -
3 • ' ,
10
3
,13
'. • ,. 3-
3
98a
Source: (1)
"Does not add up to 100 percent due to rounding.
3-75
-------
TABLE 3-18
TYPES OF WOOD PRESERVING PROCESS RESIDUALS MANAGED IN 1984
AT SURVEYED WOOD PRESERVING PLANTS, BY PRESERVATIVE
(RCRA 3007 SURVEY DATA)
Type of Residual
Treating Cylinder and Treating
Tank Sediments
Holding, Work, Storage, Mixing
or Other Tank Sediments -
Door or Treating Cylinder -Sump
Sediments
Preservative Recycling/
Regeneration Residues
Drips and Spills
Maintenance Residuals "
F032
Pentachlorophenpl
Percent
i
• , 80
y
47.,
27
10.
• NR
•. . 3, '.
F034
Creosote
Percent
73
63 -
1 . ' - . A
. ' 37 .
10 .
' f NR.
NR
F035
Inorganics
Percent
57
45
50;
43
•' • 2.
2.
Source: (1) , •
NR-Not reported. -.-... ,
/ .
v ' • '
Note: Numbers shown are the percentages of plants using each preservative that generate each process residual. For
* example, 57 percent of plants that use inorganic preservatives reported managing treating cylinder and treating
tank sediments. • ,
Totals may exceed 100 percent because most plants generate more than one type of process residual.
'3-76.
-------
TABLE 3-19
REPORTED MANAGEMENT PRACTICES FOR WOOD PRESERVING
PROCESS RESIDUALS, BY PRESERVATIVE
Management Practice
Removal by Waste Contractor
Burning in Boiler/Wood Burner
Disposal in Landfill
Storage. in Tank of Container
Storage in Impoundment
Reclaimed for Reuse
Land Treatment
Management Not Specified
Land. Disposal in Place
Percent of Plants \
F032
Pentachlorophenol
- 70
3 "
13
r
3
7
0
s ' '
0
10
NRb A '
;
F034
Creosote
63
13
7 '
7
: 7- '• . •
0 :
3
• 3
' NRb
•F035 '
Inorganics
84s
0
1
/
5
0
2 :
0
2
'NRb
Source:.(l) . . ' ' .
MR - Not reported: . .
'Includes six plants whose waste is removed by their preservative chemical supplier: : , ,.
'Land disposal at the site of generation of drips, leaks, and spills is assumed to be the typical management practice at
most wood preserving plants. Respondents to the 3007 Survey, however, did not report this practice.
Note: Numbers shown are the percentages of plants using each preservative that use each process residual
management practice. For example, 70 percent of plants that use pentachlorophenol preservatives reported
that their process wastes are removed by a waste contractor. . .
Totals may. exceed 100 percent because some plants may use more than one management practice.
3-77
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TABLE 3-20
REPORTED TREATED WOOD DRDPPAGE MANAGEMENT PRACTICES FOR
WOOD PRESERVING PLANTS, BY PRESERVATIVE
- . - . . :
Number of Plants
Surveyed
Percent With Surfaced
Drip Pad
.
Percent Reusing
Drippage from Surfaced
Drip Pad
Percent With Surfaced
Storage Yard
Percent Allowing
Drippage in Storage
Yard Directly to
Ground1
Pentachlorophenol
Only, and Creosote,
and Pentachlorophenol
. 15
' ' 47 .
-
v'
1 . *
86 ,
13 .
. . - ' .
87 . :
Creosote
Only
'
' 25
,
.40
100.
12
88 ,
Inorganics
Only
.-
82
91
91 .
38
/
^
62
- Creosote,
Pentachlorp
„ phenol,
and
Inorganics
15 ..
73 * '
47
13
87 -
Source: (1) • •
'Calculated by difference (100 percent - percent with'surfaced storage yard).
3-78
-------
Figure 3-1
3-79 '
-------
Figure 3-2
3-80
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4.0 BDAT TREATMENT STANDARDS FOR WOOD PRESERVING
WASTES F032, F034, AND F035
4.1 Determination of BDAT Treatment Standards for F032. F034. and F035
This section presents the methodology and rationale for selection of constituents for
* >
regulation in nonwastewater and wastewater forms of wood preserving wastes. - Constituents^,
selected for regulation must satisfy the following EPA criteria:
(1) They must be on the BDAT List of constituents. Presence on the BDAT List
means that EPA-approved methods exist for analysis of the constituent in treated
waste matrices. ., / , •
(2) They must be present in. or be suspected of being present in. the untreated waste:
For example, analytical difficulties may prevent a constituent from being identified
in the untreated waste, but its identification in a treatment residual may lead the
Agency to conclude that it is present in the untreated waste.
4.1.1 BDAT List Constituents Present in F032, F034, and F035
For BDAT List Constituents present in F032, F034, and F035, see Tables 3^7, 3-8, 3-9, 3-
10, 3-11,3-13, and 3-14. . ,
• " . s
4.1.2 Regulated Constituents in F032, F034, and F035
.> , • -
Lists of the constituents regulated in each wood preserving waste code are presented in
Table 4-1. These constituents were selected based on waste composition data presented in the
wood preserving waste Listing Background Document from sampling and analysis of streams at
various wood preservers. Though benzo(k)fluoranthene and naphthalene were not constituents of
listing concern in F032, based on the characterization data available to the Agency, the Agency
' believes that these compounds also are present in F032. The Agency has based this decision on
the availability of various commercial grades of creosote formulations whose composition with
4-1
-------
respect to PAH compounds is variable (Table 3-12). The Agency also points out that any F034
or F035 cross-contaminated with F032 must be managed as F032. (See Section 3.6.4.)
-^ i
' . * v
Several BDAT List constituents detected in these wastes were not selected for regulation
because they were not present in concentrations of regulatory concern or because regulation of
another selected BDAT list constituent ensures treatment of the unselected constituent.
. Each category of PCDD and PCDF, HxCDD, HxCDF, PeCDD, PeCDF, TCDD, and
TCDF must achieve the promulgated treatment standards. The following acronyms and
,-',•-• - * i
definitions are used: PCDDs—all isomers of all chlorinated dibenzo-p-dioxins; PCDFs~alI
isomers of all chlorinated dibenzofurans; CDDs- and CDFs-isomers of tetra, penta-, and hexa, -
chlorodibenzo-p-dioxins and-dibenzofurans, respectively; and TCDDs and TCDFs~all isomers of
' " - -. ' '
the tetrachlorodibenzo-p-dioxins and -dibenzofurans, respectively. The prefixes T, Pe, and Hx
denote the tetra-, penta-, and hexa-chlorodioxins and -dibenzofuran congeners, respectively.
' • • ' • " >
The hepta- and beta-congeners and isomers of PCDD or PCDF were identified in F032 -
sludges, drippage, process residuals, or wastewaters in concentrations up to 40.0 ppm. However,
Vulcan, a manufacturer of pentachlorophenol (PCP) oils, has indicated that current PCP technical
grades must meet strict concentrations of dioxins and furans that may not exceed 2 ppm of the
hexa isomer and that the PCP technical grades do not contain any of the 2,3,7,8-TCDD.2 The
hepta-PCDD and hepta-PCDF were hazardous constituents for the listing of F032. Additional
data on the concentrations of PCDDs and PCDFs present in F032 were submitted to EPA3 and
are presented in Appendix K to this report.
Although the hepta-and octa-PCDD/PCDF constituents are also present in F032, EPA is
not regulating them. The hepta- and octa-PCDD and PDDF are not currently included on the list
See Appendix D of this Background Document. - • ,
3Comments submitted by the American Wood-Preservers Institute (PH4P-00039) and the Penta Task Force (PH4P-
00032). ' ." ,..'••-,'•
;; - • - . . 4;2- .;••-•• « - '' '-'.' .
-------
of'BDAT regulated constituents. In addition, the octa-isomers and congeners of PCDD and /
PDDF are not listed in Appendix VIII of the 40 CFR 261. EPA believes, however, that
regulation of other PCDD and PCDF hazardous constituents described above will effectively
control hepta-and octa-constituents.
As proposed, the Agency is promulgating treatment limits for benzo(k)fluoranthene as the
sum of benzo(f)fluoranthene and benzo(f)fluoranthene in both nonwastewater and wastewater
forms of F032 and F034. These compounds cannot be separated on a chromatographic column
during analysis; therefore, benzo(k)fluoranthene cannot be quantified as a separate compound.
The Agency is promulgating treatment limits for several PAH compounds identified in
F032 and F034 that were not part of the original listing for these wastes., The Agency has
information that suggests that various grades of commercial creosote vary in their composition of
^ PAH compounds. (See discussion in Section 3.6.4.) Therefore, the Agency believes that is
appropriated to regulate a more comprehensive list of PAH constituents for these wastes. The .
/• '
commenters to the Phase 4 proposed rule did not object to the expanded list of hazardous
( constituents. , .
4.2 Identification of Best Demonstrated and Available Technologies (BOAT) for
Nonwastewaters '." . .
' / ' •
Presented in the sections below are the Agency's determination of applicable and
demonstrated technologies and the best demonstrated available technology (BDAT) for treatment
of nonwastewater and wastewater forms of wood preserving wastes. However, other treatment
technologies capable of meeting concentration limits are not precluded except for those that may
constitute impermissible dilution.4 .=.'•'
4EPA's Office of Solid Waste, Washington DC, or the RCRA Policy Compendium can be
consulted for interpretation of those practices that may be prohibited from use pursuant to the
provisions in 40 CFR §268.3. ; . ' •
4-3
-------
In order to establish BDAT, the Agency first identifies which technologies are "applicable"
for treatment of the constituents of interest. An applicable technology is one that, in theory, can
treat the waste in question or a waste similar to the waste in question in terms of parameters that
affect treatment selection., Detailed descriptions of the technologies identified as applicable for
the treatment of listed hazardous wastes are provided in EPA's Final Treatment Technology
Background Document. Identifying treatment technologies as applicable for treating BDAT List
constituents is based on evaluation of current waste management practices, current literature
sources, field testing, data submitted by equipment manufacturers and industrial concerns, plus
engineering judgement of EPA technical staff personnel. / • . '•
' . % *
The Agency next determines which of the applicable technologies are "demonstrated" for
treatment of the wastes. EPA prefers to designate as demonstrated a technology, used in a full-
-. •. > ' • ' " ' ' •
scale operation for treatment of the waste of interest or a similar waste. Technologies that are
available only at pilot- or bench-scale operations may not be considered demonstrated
technologies, EPA may use, in limited circumstances, pilot- and bench-scale data in (1)
designating a technology as demonstrated and in (2) developing treatment limits. This would be
the case when EPA determines that the performance of pilot- or bench-scale technologies can be
' ' ' - ! - . .
optimized to a full-scale operation.
i" .•- • '
The Agency determines which of the demonstrated technologies is "best" by comparing
available treatment performance data from as many systems as possible for the constituents of v
interest, and determines whether this "best" demonstrated technology is also commercially
s
"available." If the "best" demonstrated technology is "available," then the technology is
determined to represent BDAT. * - • • <
4.2.1 Applicable Treatment Technologies for Nonwastewaters .
1 ' -a
This section presents the Agency's determination of: ' ... ,
' , , ' '
• Applicable technologies;
• * • • . .'....-' 4-4 '..•''"''
-------
Demonstrated technologies; and
Best Demonstrated Available Technology (BDAT)
for treatment of nohwastewater forms of F03 2, F03 4, and F03 5.
Because nonwastewater forms of these wood preserving wastes contain organic and metal
constituents at treatable concentrations, applicable treatment technologies include those that,
destroy or reduce the total amount of various organic compounds in the waste and reduce the
mobility of the metals in the treatment residual. The Agency has identified the following
technologies as being applicable for treatment of nonwastewater forms of these wood preserving
',-
• wastes: ' ' . ... '•'.''
• Critical fluid extraction;
• Alkaline dechlorinatiori;
• High-temperature thermal distillation; . .
• , Combustion (includes incineration and industrial boilers);
'\ , • .
* Biological treatment; .
• Solvent extraction;
•. Thermal desorption;
• Slag vitrification;
• Stabilization/solidification; and
Total recycle or reuse. ;
. • - • ' *
The concentration and type(s) of constituents present in the waste generally determine
which technology is most applicable. A brief discussion of each technology identified as ,
applicable for treatment of the constituents in nonwastewater forms of wood preserving wastes is
given below. , '. .
4-5'
-------
In addition to these, technologies, emerging technologies exist that could provide
treatment of wood preserving wastes and contaminated media. They include but are not limited
t ' , '
to: '.'-"..• • -; • . • ~
• Base-Catalyzed Dechlorination;
• Lewis Environmental Service's ENVTRO-CLEAN process;
, • Texaco Gasification Process; and
• Cashman Process. > •'',_'.
• Information on these and other potential treatment technologies is provided in Appendices
E and F. Other literature sources on the treatment of related wastestreams are referenced in
Appendix! . .
Critical Fluid Extraction. Critical fluid extraction is a separation and recovery technology
in which a solvent is brought to its critical state (a thermodynamically unique equilibrium state
between liquid and gas at high pressure and temperature) to extract organic constituents from a
waste. The solvents used are usually gaseous when at ambient conditions. In the extraction
procedure, the solvent is pressurized, thus converting it from a gas to a liquid. As a liquid, it
.dissolves the organic constituents and removes them from the waste matrix. After the extraction;
; the solvent is returned to its gaseous state; a small volume of extract remains that contains a high
concentration of organic constituents. This technology generates two residuals: a-treated waste , .
residual and an extract.
, ,. • • * i ' ' *
Alkaline Dechlorination. Alkaline dechlorination is a process that chemically alters
halogenated aromatic compounds. It replaces one or more of the halogens (i.e., chlorine) with an
aliphatic compound, resulting in a less.toxic compound. Its particular applicability is for the
' treatment of chlorinated dibenzodibxins and fiirans. ' ,
High-Temperature Thermal Distillation. High-temperature thermal distillation is a
\ ' ' ' >
separation and recovery technology that subjects wastes to indirect, electrically generated heat in
4-6
-------
an inert atmosphere. The process removes volatile hydrocarbon constituents from a waste; these
V •
constituents can subsequently be recovered in a reusable form by cooling the hydrocarbon-bearing
inert gases at high pressure. This process generates two residuals: a treated waste residual and
an extract. . . ' , .
' " • ^ ' "
Combustion. Combustion is a high-temperature thermal destruction technology in which
heat is transferred to a waste to destabilize chemical bonds and destroy hazardous organic
constituents. Combustion includes both incinerator and industrial boilers. Three combustion
•' ( • • . •
technologies are applicable for the treatment of organic constituents in nonwastewater forms of
these wood preserving wastes: liquid injection, rotary kiln, and fluidized bed.
In a liquid injection incinerator, liquid wastes are atomized and injected into the incinerator
where additional heat is supplied to destabilize chemical bonds in the presence of air or oxygen.
Once the chemical bonds are broken, these constituents react with oxygen to form carbon dioxide
and water vapor. Liquid injection is applicable to wastes with low viscosity values, small particle"
1
size, and low suspended solids content.
In a rotary kiln incinerator, solid and/or semi-solid wastes are fed into the higher end of a
sloping kiln. The rotation of the kiln mixes the waste with hot gases. Eventually, the waste
reaches its ignition temperature and is converted to gas and ash through volatilization and
combustion reactions. Ash is removed from the lower slope-end of the kiln. Combustion gases
from the kiln, containing volatilized and partially combusted waste constituents, enter an
afterburner, for further combustion to complete the destruction of the organic waste constituents.
In a fluidized-bed incinerator, solid and/or semi-solid wastes are injected into a fluidized
s
material (generally sand and/or incinerator ash) where they are heated to their ignition
• ' •*
temperature. In the incinerator, the waste is converted to gas and ash through volatilization and
combustion reactions. Heat energy from the combustion reaction is then transferred back to the
fluidized bed. The velocity of the combustion gases is reduced in a wider space above the bed,
4-7
-------
known as the freeboard, allowing larger ash and waste particles that were not combusted to fall
back into the bed. Ash is removed periodically during both operation and bed change-outs.
' • ' * • . . .
' - ' \' . • . ' • • > .
Offgases from combustion are fed into' a scrubber system for cooling and removal of any
entrained particles and acid gases. In general, with the exception of liquid injection incineration,
two.residuals are generated by the combustion process: ash and scrubber water. Because only
wastes with low or negligible solids content are amenable to liquid injection incineration, this
/ , * '
technology does not normally generate an ash residual, but does generate a scrubber water
residual. , .
' ,- • i • ) ...
( Biological Treatment. Biological treatment is a destruction technology that employs .
micro-organisms to degrade and mineralize biodegradable organic compounds and some inorganic
compounds, such as sulfides and cyanides. It can be broadly classified'into two classifications:
aerobic and anaerobic.. Aerobic biological treatment takes place in the presence of free oxygen,
and anaerobic biological treatment occurs in the absence of free oxygen. Anaerobic biological
treatment is typically done an anaerobic digester.
-'
The most common aerobic biological .treatment processes are activated sludge, aerated
lagoon, bioslurry reactor, trickling filter, and the rotating biological contactor .(RBC). The
activated sludge, aerated lagoon, and bioslurry reactor processes work by keeping the microbes in
suspension in water. The trickling filter and the RBC work by providing an inert medium, such as
rocks or specifically designed ceramic or plastic materials, to which the microbes are attached and
grow. Also, wastes containing biodegradable compounds can be mixed with a microbe and
nutrient-rich medium, such as manure, and composted. , - ,
i "•
- i * • , •
This technology generates two treatment residuals; a treated effluent and a waste
biosludge. Waste biosludge may be land disposed without further treatment if the concentrations
of its regulated constituents fall at or below their BDAT treatment standards.
4-8
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Solvent Extraction. Solvent extraction is a separation and recovery technology in which
hazardous organic constituents are removed from the waste due to greater solubility in the solvent
phase than in the waste phase. Wastes commonly treated by this technology have a broad range
of total organic content. Selection of an appropriate solvent is dependent on the relative
solubilities of the constituents to be removed and the other organic compounds in the waste.
Solvent extraction generates two residuals: a treated residual and an extract.
Thermal Desorption. Thermal desorption is a separation and recovery technology in
which heat is used to volatilize organic .constituents from wastes. Thermal desorption has been
defined as a thermal treatment that uses direct or indirect heat exchange to elevate the
temperature of a waste, thereby volatilizing the organic constituents. Thermal desorption differs
from thermal destruction (incineration) in the way in which the organic constituents are treated.
The objective of thermal desorption is to sufficiently elevate the temperature of the organic
constituents to effect a phase separation to a gaseous state without combustion; the objective of
incineration is to combust the organic constituents. Thermal desorption units function by creating
steam from the volatilization of the moisture in the waste from heating. The steam tends to strip
organic compounds from the waste and aids in the volatilization of organic compounds!
Generally, this technology generates two residuals: a treated waste residual and an extract.
Additional information is found in Appendix F.
Slag Vitrification. Slag vitrification is a treatment process that reduces the mobility of a
metal species, such as arsenic, by dissolving metals into a glass or glass-like matrix. The metals
become chemically bonded inside the matrix in many cases. For instance, arsenates are. converted:
to silicoarsenates. Other metals are converted into silicates. In all cases, metals are surrounded
by a glass .matrix that reduces the mobility of the metals, preventing their reintrpduction into the
environment. • - "* t ' •
' ' • . % . . .
Stabilization/Solidification. Stabilization/solidification is a treatment technology that
immobilizes hazardous constituents, i.e., metals in a waste. The basic principle of operation is
that the leachable metals in a waste are immobilized following the addition of stabilizing agents
,v - 4-9 ' ' '.''•••
-------
and possibly other chemicals. The stabilization agents form a lattice structure and/or chemical .
bonds that reduce the teachability of metals in the waste. Treatment is most effective when the
metal constituents in the waste are in the least soluble state. For example, hexavalent chromium is
much more soluble and, therefore, more difficult to immobilize than trivalent chromium.
Total Recycle or Reuse. Total recycle or reuse of a waste material within the same
• ••'.(-.•' * •
process or an external process eliminates the generation of a waste for treatment and disposal and
subsequently generates no treatment residuals.
'' s ' , . ' • •
4.2.2 Demonstrated Treatment Technologies for Nonwastewaters
Generally, demonstrated treatment technologies are those that have been demonstrated to
be effective in full-scale operation for treatment of the waste of interest or a similar waste.
- The Agency has determined that combustion provides substantial treatment of organic
constituents based on the reduction of all BDAT List organic constituents to nondetectable ,
k ' ,: '
concentrations. The Agency has also determined that slag vitrification provides substantial
treatment of arsenic, .based on the arsenic concentration in the toxicity characteristic leachate
procedure (TCLP) leachate; and stabilization/solidification provides substantial treatment for
chromium, based on the chromium concentration in the TCLP leachate. In addition to achieving ;
substantial treatment, incineration, slag vitrification, and stabilization/solidification are
.commercially available, meeting the second criterion of "availability." Therefore, combustion, .
slag vitrification, and stabilization/ solidification represent BDAT for nonwastewater forms of
F032, F034, and F035. . , :
'- _ '»
s
The Agency notes, however, that when it establishes concentration-based treatment
standards, the regulated community may use any other technologies to treat the waste to meet the
- . - f
.treatment standards except for those treatment practices that may constitute disposal or
'.".•' • ' ' " ' ' • >. . r '
iriipermissable dilution. Compliance with a concentration-based treatment standard requires only
that the effluent concentration be achieved; once achieved, the waste may be land disposed. The ,
.: ' . 4-10 ' , V;
-------
I •
waste need not be treated by the technology identified as BOAT; in fact, concentration-based
treatment standards provide flexibility in the choice of a treatment technology. Any treatment,
i h ' • , . .
including recycling or any combination of treatment technologies, unless prohibited (e.g.,
impermissible dilution) or unless defined as land disposal (e.g., land treatment), can be used to
achieve, these standards. .
\
4.3 Identification of Best Demonstration Available Technologies (BDAT) for
Wastewaters v ;
~ . • - ( •'
This section presents the Agency's determination of: . i
• Applicable technologies; ' .
• Demonstrated technologies; and
Best Demonstrated Available Technology (BDAT) :
for treatment of wastewater forms of F032, F034, and F035.
Applicable treatment technologies for organics in wastewater forms of wood preserving
wastes include those that destroy or reduce the total amount of various organic compounds in the
waste. The Agency has identified the following technologies as being applicable for treatment of
wastewater forms of these wood preserving wastes:.
'".''• : '
• Biological treatment (including aerobic fixed film, aerobic lagoon, activated
sludge, filtration, anaerobic fixed film, rotating biological contactor, sequential
batch reactor, and trickling filter technologies);
-. . • '
• Carbon adsorption (including activated carbon and granular activated carbon
' ' ' • ja
technologies);
• Chemical oxidation; •
• Chemical reduction; ., ."
* Chemically assisted clarification (including chemical precipitation technology);
••'.,.. . 4-11 . • ••'••'-'.
-------
• PACT® treatment (including powdered activated carbon addition to activated
sludge and biological granular activated carbon technologies);
• Reverse osmosis;
* Solvent extraction;
• Stripping treatment (including :steam stripping and air stripping technologies);
Total recycle or reuse; and : ,
I. /
• Wet air oxidation (including supercritical oxidation technology)..
The concentration and type(s) of waste constituents present in the wastewaters generally
determine which technology is most applicable. In most instances, combinations of two or more
of these wastewater treatment practices can be used for the purposes of achieving the treatment
limits established today. This is not an unexpected result, since combinations of these wastewater
treatment process allow the affected industry to optimize the overall performance of wastewater
< treatment trains and meet applicable effluent discharge limits under the National Pollutant
Discharge Elimination System (NPDES), A brief discussion of each technology identified as
applicable for the treatment of constituents in wastewater forms of wood preserving wastes is
givenbelow. , • . .,
*'."•' . ' » t t
Biological Treatment. Biological treatment is a destruction technology that employs
•<; micro-organisms to degrade and mineralize biodegradable organic compounds and some inorganic
compounds, such as sulfides and cyanides. It can be broadly classified into two classifications:
aerobic and anaerobic. Aerobic biological treatment takes place in the presence of free oxygen,
and anaerobic biological treatment occurs in the absence of free oxygen. Anaerobic biological
treatment is typically done an anaerobic digester. , '
i ' • * * ' ' •*
The most common aerobic biological treatment processes are activated sludge, aerated ,
- f ' . • • j» ' '
' lagoon, bioslurry reactor, trickling filter, and the RBC. The activated sludge, aerated lagoon, and
bioslurry reactor processes work by keeping the microbes in suspension in water. The trickling
filter and the RBC work by providing an inert'medium, such as rocks or specifically designed
ceramic or plastic materials, to which the microbes are attached and grow. Also, wastes
.*''''•< • / • y ' .'.''• '"• •'- - "•
" '• . ' ^ . '' •'- 4-12. ' . . • • ^ ' ~
-------
containing biodegradable compounds can be mixed with a microbe and nutrient-rich medium, such
as manure, and composted. ' • , .
This technology generates .two treatment residuals: a treated effluent and a waste
biosludge. Waste biosludge may be land disposed without further treatment if the concentrations
' • • . ' ' •. '
,of its regulated constituents fall at or below their BD AT treatment standards.
Carbon Adsorption. Carbon adsorption is a separation technology in which hazardous
organic constituents in wastewaters are selectively adsorbed onto activated carbon. This
technology generates two treatment residuals: a treated effluent and spent activated carbon.
Spent activated carbon is often reactivated, recycled, or incinerated.
Chemical Oxidation. Chemical oxidation is a destruction technology in which some
N. " *
dissolved organic compounds are chemically oxidized to yield carbon dioxide, water, salts, simple
organic acids, and sulfates. This technology generates one treatment residual: treated effluent.
Chemical Reduction. Chemical reduction is a technology that converts highly oxidized
metal ions, such as hexavalent chromium, to less highly oxidized states. This change in oxidation
state renders the metals more amenable to precipitation and stabilization.
J ' • '
,y ' * '
Chemically-Assisted Clarification. Chemically-assisted clarification, including chemical
precipitation, is t. separation technology in which the addition of chemicals during treatment
results in the formation of precipitates from the organic and inorganic constituents in the
wastewater. The solids formed are then separated from the wastewater by settling, clarification,
and/or polishing filtration. This technology generates two treatment residuals: treated
wastewater effluent and separated solid precipitate. The sqlid precipitate may be land disposed
.'.) •'..'''•
without further treatment if it meets the applicable BDAT treatment standards for regulated
constituents.
4-13-
-------
PACT® Treatment. PACT® treatment is a combination of carbon adsorption and ,;
biological treatment. It is a destruction technology in which hazardous organic constituents are
biodegraded and selectively adsorbed onto powdered activated carbon. This technology
generates two treatment residuals: a treated effluent and spent carbon/biosludgel Spent carbon is
often regenerated and recycled to the process or incinerated.
l- ' '
Reverse Osmosis. Reverse osmosis is a separation technology in which dissolved organics
(usually salts) are removed from a wastewater by filtering the wastewater through a
semiperrneable membrane at a pressure greater than the osmotic pressure caused by the dissolved
organic constituents. This technology generates two treatment residuals: the treated effluent and
' '•"",'' v ' -
the concentrated organic materials that do not pass through the membrane.
>""'•- .' • . • -'•
!'•'•». , ' •'"••'.
Solvent Extraction.. Solvent extraction is a separation and recovery technology in which
hazardous organic constituents are removed from a waste due to greater solubility in the solvent
phase than in the waste phase. Wastes commonly treated by this technology have a broad range
of total organic content. Selection of an appropriate solvent is dependent on the relative
solubilities of the constituents to be removed and the other organic compounds in the waste. ,
Solvent extraction generates two residuals: a treated residual and ah extract:
.,-.-. . ' '!"-' • • .' i " • ~ ' •
Stripping Treatment. Stripping treatment is a separation technology in which volatile
organic constituents in a liquid waste are physically transferred to a flowing gas or vapor. In
steam stripping, steam contacts the waste, strips it of volatile organic constituents, and carries
them to a condenser, where the mixture of organic vapors and steam is condensed and collected in
an accumulator tank. In air stripping, air contacts the waste and strips it of volatile organic
i ,
constituents. This technology generates one treatment residual, the treated effluent.
*•'*'. ~ ' ~>
•. .' • ' ' •* ~ ' '
Total Recycle or Reuse. Total recycle or reuse of a waste material within the same
' ,'' '
process or an external process eliminates the generation of a waste for treatment and disposal and
subsequently generates no treatment residuals.
4-14
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Wet Air Oxidation. Wet air oxidation is a destruction technology in which organic
constituents in wastes are oxidized at elevated temperatures and pressures in the presence of
\ - - •
dissolved oxygen. This technology is applicable for wastes comprised primarily of water and up
to 10 percent total organic constituents. Wet air oxidation generates one treatment residual:
treated effluent. The treated effluent may require further treatment for hazardous organic
constituents by carbon adsorption or PACT® treatment.
4.3.1 Demonstrated Technologies for Wastewaters " ' - '
Generally, demonstrated treatment technologies are those that have been demonstrated in
full-scale operation for treatment of the wastes of interest or a similar .waste. The Agency has
identified as applicable technologies that have been demonstrated on a full-scale operational basis
for wastewaters containing the constituents of concern or constituents similar to those of concern
in these wastes. . , ,
' • '....' ) . •
4.3.2 Identification of BOAT for Wastewaters
t v , 1 -
The procedure used to identify BDAT for the wastewater forms of F032, F034, and F035
follows the methodology described in EPA's Methodology for Developing BDAT Treatment
Standards. All applicable and demonstrated treatment technologies are identified for the regulated
constituents in the wastes of interest, and the treatment performance data are then examined to
identify the technologies thaj perform "best." The treatment performance data are evaluated to
determine: < .
Whether the data represent operation of a well-designed and well-operated
- treatment system; •.-'•"',
• .Whether sufficient analytical quality assurance/quality control measures were used
. , to ensure the accuracy of the data; and , '
• Whether the appropriate measure of performance was used to assess the
performance of the particular treatment technology.
. •' .' . ' ' ' 4-15". .• . ' " •
-------
The Agency then determines whether the best demonstrated technology is "available." To be
i ,
"available," a technology (1) must provide substantial treatment and (2) must be commercially
available. . _
., , The Agency determined the best demonstrated technology for each constituent in F032,
F034, and F035 by a thorough review of all of the treatment performance data available for each
constituent. The demonstrated technologies determined to be "best" for each constituent are all
commercially available. Therefore, the technologies selected as best and demonstrated for each
constituent are also considered to be available, and BDAT for that constituent.
V l • '.'• ..•'•. ' '"•••-. ._•';/
, 1
' The Agency notes, however, that when it establishes concentration-based treatment
standards, the regulated community may use any other technologies to treat the waste to meet the
.treatment standards except for those treatment practices that may constitute disposal or
impermissable dilution. Compliance with a concentration-based treatment standard requires only
that the effluent concentration be achieved; once achieved, the waste may be land disposed. The
waste need not be treated by the technology identified as BDAT; in fact, concentration-based
treatment standards provide flexibility in the choice of a treatment technology. In fact, EPA
points out that although the promulgated UTS limits are based on the performance of one or the
1 i ' . . ' '
combination of two or three treatment trains, existing wastewater treatment capabilities at wood
preserving sites can be optimized to meet the treatment limits promulgated today. This
determination is based on the available data on the performance of wastewater treatment practices
at wood preserving facilities that show that these facilities treat their wastewater via sequential
primary, secondary, and tertiary treatment processes in order to meet their effluent water
discharge limits under the National Pollutant Discharge Elimination System. EPA believes that
. these treatment infrastructures can be optimized to meet the UTS limits promulgated today via the
installation of a tertiary treatment process such as carbon adsorption. Specifically, see the
document entitled "Treatability of UTS Constituents in F032, F034, and F035 Wastewaters"
located in the docket for today's rulemaking and Appendix K to this report.
4-16
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4.4 Promulgation of Treatment Standards
•' _ m i~^~— j iii.ii— • i,
As proposed, the Agency is transferring universal treatment standards to the constituents
proposed for regulation in nonwastewater and wastewater forms of F032, F034, and F035. A
universal standard is a single concentration limit established for a specific constituent regardless of
the waste matrix in which it is present. Universal treatment standards are intended to be used to
/ . • • .
replace treatment standards in previously promulgated waste codes and as the treatment standards
for listed hazardous waste codes in the future.. Although several commentors objected to the
- f ' ' ' •
regulation of hexa-, tetra-, and penta-isomers of PCDD and PCDF in F032, as well as chromium
and arsenic in F034, EPA has determined that the regulation of these constituents.is warranted.
These constituents are toxic and they are present in F032 (D/F) and FQ34 (chromium and arsenic).
'' ' . - "
In response to public comments concerning the potential refusal of combustion device's
owner and operators to manage F032 wastes, some commentors asked EPA to promulgate an
alternative compliance treatment standard that allows combustion as the treatment standard for
D/F in F032, wastes. After evaluating the submitted data.characterization with regard to D/F
concentrations in F032, EPA proposed that such treatment compliance alternative is also available
fbrF032.
This section presents the universal treatment standards that were transferred to the
constituents proposed for regulation in nonwastewater and wastewater forms of F032, F034, and
F035, and the specific data used to determine these treatment standards. EPA is promulgating a ,
modified version of the proposed combustion alternative,treatment standard as explained in
Section 5.0 of this BDAT Background Document for Wood Preserving Wastes F032, F034, and
F035. . •',"•'"'.'.'
"•
' .a
4.4.1 Nonwastewaters ;
c
. The Agency is promulgating universal treatment standards for each constituent proposed
for regulation in nonwastewater forms of F032, F034, and F035. Universal treatment .standards
- '' -'- 4-17- . ' . '
-------
for .the organic constituents proposed for regulation in F032, F034, arid F035vwere based upon
- ' * '• « • \
combustion treatment performance data. Universal treatment standards for the inorganic
constituents proposed for regulation in F032, F034, and F035 were based upon slag vitrification
and stabilization/solidification treatment performance data. These data represent BDAT for .
wood preserving wastes: This is because incineration, slag vitrification, arid .
stabilization/solidification have also been identified as BDAT for wastes as difficult to treat as
wood preserving wastes, the Agency feels it is appropriate to transfer the universal treatment;
standards for nonwastewaters to the constituents proposed for regulation in nonwastewater forms
V. • " '."•'
of F032, F034, and F03 5. EPA believes that potential difficulties in treating hazardous
constituents in F032, F034, and F035 can be effectively reduced via appropriate pretreatment or
post-treatment technologies such that these wastes can meet the promulgated UTS limits:
.!>••.'' . .'. ' . "
• f ' .'*
I ' • ' - *
Table 4-2 presents the treatment standards promulgated for nonwastewater forms of wood
preserving waste by waste code. Details regarding the methodology used to develop these
nonwastewater universal treatment standards and the treatment standards database are presented
in Appendix A of this document. A more detailed discussion concerning the determination of
universal treatment standards is provided in EPA's Final Best Demonstrated Available. Technology
(BDAT) Background Document for Universal Standards. Volume A: Universal Standards for
Nonwastewater Forms of Listed Hazardous Wastes. . .
4.4.2 Wastewaters .
The Agency is promulgating universal treatment standards for regulated constituents in
wastewater forms of F032, F034, and F035, as proposed. Universal treatment standards in
' ' '"•*.''' .
wastewater forms of wastes are based on treatment performance data from several sources
including the BDAT data base, the NPDES data base, the WERL data base, EPA-collected
r . - I
WAO/PACT® data, the BAD data base, industry-submitted leachate treatment performance data,
data in literature that were not already part of the WERL, data base, and data in literature
submitted by industry on the WAO and PACT® treatment processes. Several commenters
expressed concerns that F032 wastewaters cannot be treated via biological treatment to meet
4-18
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limits that EPA proposed for the regulation of specific PCDD and PCDF in wastewater forms of
F032. EPA concurs with the cpmmenters that F032 wastewaters as generated may not be readily
amenable to biological treatment, Unlike the commenters, however, EPA believes that wood'
preserving facilities can optimize their existing wastewater treatment trains in order to meet the
UTS limits promulgated for PCDD and PCDF regulated in wastewater forms of F032. In fact,
EPA believes that: (1) pretreatment steps such as oil separation, pH adjustment, chemical
"v . • %
precipitation/clarification, arid equalization can manage the loading of deleterious pollutants to
biological treatment processes; (2) acclimatation of microorganisms to the concentrations of
pentachlorophenol, PCDD, PCDF, and metals in wastewaters; or (3) the addition of a carbon
adsorption polishing step can enable F032 wastewaters to meet the UTS limits promulgated today
for PCDD and PCDF in wastewater forms of F032. This determination is .based on EPA's
. y ' { ~* ' ' '
findings from the available data describing the characterization of. F032 wastewaters, the
performance of wastewater treatment practices at wood preserving facilities, the performance of
treatment practices on wastewaters as difficult to treat as F032 wastewaters, and the performance
of carbon adsorption as a polishing step of F032 wastewaters treated in bioreactors. EPA's
review of the available data can be found in the document titled: "Treatability of UTS
Constituents in F032, F034, and F035 Wastewaters" located in the docket for today's rulemaking.
-.
The performance data on treatment processes for wastewaters as difficult to treat as wastewater
forms of F032 can be found in Appendix K. Because these standards reflect the performance of
$
numerous industrial wastewater treatment systems, the Agency believes it is appropriate to
. . N ' . ' •
transfer the universal treatment standards for wastewaters to the constituents proposed for
regulation in wastewater forms of F032, F034, F03" ,
Table 4-3 presents the proposed treatment standards promulgated for wastewater forms of
wood preserving waste by waste code. Details regarding the methodology used to develop these
wastewater universal treatment standards and the treatment performance data base are presented
in Appendix B of this document. A more detailed discussion concerning the determination of the
wastewater universal treatment standards is provided in EPA's Best Demonstrated Available
Technology (BOAT) Background Document for Universal Standards. Volume B: Universal
StandardsJbr Wastewater Forms of Listed Hazardous Wastes.
4-19
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4.5 Detailed Descriptions of Technologies Identified as BOAT
'' •• ."•-.*'•', *' - «
The detailed descriptions of treatment technologies that are presented in the following
subsections are summarized from information provided in EPA's Treatment Technology
Background Document. 1991. ' '
Of the technologies identified as applicable and demonstrated for treatment of wood
. preserving nonwastewaters, three were identified as BDAT for constituents proposed for
regulation in F032, F034, and F035. These technologies are as.follows:
. • Combustion (discussed in Section 5. Oof this report); .
', ,• Slag Vitrification; and
• Stabilization/Solidification.
i ' ' •> '
4.5.1 Slag Vitrification •.'""'
SJag vitrification is a treatment process that reduces the mobility of a metal species, such
as arsenic, by dissolving metals into a glass or glass-like matrix. The metals become chemically
bonded inside the matrix in many cases. For instance, arsenates are converted to silicoarsenates;
other metals are converted into silicates. In all cases, metals are surrounded by a glass matrix that
reduces the mobility of the metals, preventing their reintroduction into the environment
Treatment Applicability. Slag vitrification is applicable to nonwastewaters containing
arsenic or other characteristic toxic metal constituents that relatively nonvolatile at the
temperatures at which the process is operated. This technology is also applicable to many wastes
•*'"."
containing organbmetallic compounds, where the organic portion of the compound can be ;
completely oxidized at process-operating conditions. J ' .
4-20
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Treatment Process Parameters. In slag vitrification, finely ground slag from metal-refining
processes and waste are premixed and fed to the same type of furnace as that used for
glassmaking. The slag liquefies at the process temperatures (1100 to 12DO°C). The waste
constituents either dissolve in the melt or become suspended in the molten slag. Subsequent
cooling of the slag causes it to solidify, trapping the waste inside a glasslike matrix and reducing
the leachability of the waste.
Process Constraints. .Waste characteristics affecting the performance of slag vitrification
include the organic content of the waste, the concentrations of specific metal ions in the waste,
the concentration of compounds that interfere with the glassmaking process, and the moisture •
content of the waste.
At the process temperature, the organic content is combusted to carbon dioxide,1 water,
and other gaseous products. This liberates heat, reducing the external energy requirements for
this process. However, the presence of refractory organic compounds, such as halpgenated
organics, results in incomplete combustion and the deposition of components, such as chlorides,
that can affect the ability of the cooled matrix to achieve the desired reduction in mobility of
waste constituents. . . • • .
Metal oxides have solubility limits in glass matrices. Therefore, the amount of specific
metal oxides in the wastes will determine the amount of glass-forming material required to form a
satisfactory nonleachable slag.
Some common waste constituents, such as chlorides, fluorides, and sulfates, will interfere
with the vitrification process. To compensate for these interferences, higher levels of slag forming
'
materials have to be added. ,
•' • • \ ' . • . , , •
The moisture content of the waste and additives should be less than 5 percent free
moisture. Wastes with higher moisture content need to be dried before mixing with the slag-
4-21
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forming materials; otherwise, the final treated matrix will not have the desired characteristics to
reduce the teachability of the metals in the waste.
' -
4.5,2 Stabilization/Solidification '
' ' ' " -, ' ' x
Stabilization/solidification refers to a broad class of treatment processes that immobilize
hazardous constituents in a waste. Stabilization/solidification generally requires a chemical
reaction between the waste constituents and the treatment additives for effective treatment to
occur. ? s . . ,.. - -
• " , ' ^ '
.-'•..' . • . s
Treatment Applicability. This treatment is applicable to wastes containing teachable
metals that also have a high filterable solids content, low organic carbon (TOC) content, and low
1 •
oil and grease content. The most common wastes treated by this technology include residuals
generated from the treatment of electroplating wastes, combustion ash residuals, and .
characteristic TC-nietal wastes . ,
y
, Treatment Process Parameters. During treatment, teachable metals (e.gi, lead, chromium)
become immobilized in a lattice structure that develops in the waste following the addition of /
stabilization agents and, possibly, other chemicals. In some, cases, the teachable metals can form
chemical bonds within the treated waste matrix, further reducing potential teachability. Treatment
efficiency is improved if the metal constituents are in their least soluble form. For example,
because hexavalent chromium is more soluble than trivalent chromium, chemical reduction of any
hexavalent chromium in the waste should be done prior to adding the stabilization/solidification
reagents. The two principal treatment processes are cement-based and lime/pozzolan-based.
Portland cement is a mixture of the oxides of calcium, silica, aluminum, and iron. It is
: * "•-.''• 3 .
produced by the kiln burning of calcium and silica rich material at high (1400 to 1500°C)
temperature. When mixed with water, the mixture begins to set. In the process, a complex
matrix of interlacing, thin, densely packed silicate fibrils forms Metals constituents present in the
matrix, in their hydroxide arid carbonate forms, become incorporated in these interstices. •
'. • . ' 4-22 ' - '
-------
Pozzolan contains finely divided silica. Upon the addition of lime, it becomes
cementitious, producing a similar matrix as Portland cement when hydrated.
Process Constraints. Factors affecting the performance of stabilization include
concentration of fine particles, the level of oil and grease, the concentration of other organic
compounds, the amount of sulfate and chloride compounds, and the relative solubility of metal
compounds. ,
• ^ ,T . •
' i .
Very fine particles, eg., less than 74 ^m, will weaken the bonding within the treated
matrix due to coating of the waste particles Pretreatment to reduce the concentration of fine ,
particles or the addition of much larger amounts of treatment additives are required to achieve >
effective treatment. ,
The presence of oil and grease can result in the coating of the waste particles, weakening
the bonds between the waste and the treatment additives. Organic compounds can also interfere
with the formation of chemical bonds within the treated matrix and interfere with the formation.of
bonds between the waste and the treatment additives, which will decrease the resistance to
leaching. Pretreatment of the waste may be required if the TOC levels are high.
» p •""
Sulfate and chloride salts interfere with the chemical reactions within the treated matrix,
weakening bond formation and strength and prolonging the setting and curing time. Sulfate and
chloride salts may reduce the dimensional stability of the cured matrix, increasing the potential for
leaching. Pretreatment of the waste .may be required to reduce the concentration of sulfate and
chloride salts: .
/ *• • '
, The metal targeted for treatment should be in itsleast soluble state at the pH of the treated
matrix. For example, hexavalent chromium should be reduced to its trivalent form to achieve
optimum treatment efficiency. " ,
4-23
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4.6^ Detailed Description of Technologies identified as BOAT for Wastewaters
Of the technologies identified as applicable and demonstrated for treatment of wood
preserving wastewaters, three were identified as BDAT for the regulated constituents in F032,
F034, and F035. These technologies are as follows, each of which is described below:
•-•-•• Biological Treatment;
.• Chemically Assisted Clarification; and
• Steam Stripping. ,
4.6.1 Biological Treatment "*.'••
- •. i . '
i *
, • '" . . : -' •' .. . ' - .•
. The four most common biological treatment technologies are: '
Activated sludge;
Aerated lagoon;
Trickling filter; and
RBC.
These technologies are discussed below. . :
treatment Applicability. Biological treatment technologies are applicable to wastewaters
that contain biodegradable organics.
treatment Process Parameters. A typical activated sludge system includes an equalization
basin, a settling tank, an aeration basin, a clarifier, and a sludge recycle line. Wastewater enters
~ the system in the equalization basin, where it is homogenized to prevent process upsets. The
wastewater then enters a settling tank where settleable solids are removed. From the settling
tank, the wastewater is discharged to an aeration basin, where aerobic bacteria are maintained in
suspension. Mechanical or diffused aeration is used to supply oxygen to the aeration basin. The
wastewater containing the aerobic bacteria is continuously discharged from the aeration basin into ,
a clarifier. Jn the clarifier, the biomass is separated from the treated wastewater. This treated
'' . "
'".'•. • 4-24 ' .' - ' • ••.."''
-------
wastewater is discharged. A portion of the biomass is discharged. This portion may be
dewatered by sludge filtration or on sludge drying beds prior to discharge. The remainder of the
biomass is returned to the aeration basin, maintaining the bacterial population.
/ '.. - •
An aerated lagoon system is similar to an activated sludge system in that suspended ;
aerobic bacteria are used to degrade organic compounds in wastewater. An aerated lagoon,
however, initially contains a smaller population of micro-organisms than an activated sludge
system because there is no sludge recycle in an aerated lagoon. Therefore, water must remain in
the aerated, lagoon system longer to achieve similar effluent quality: The longer residence time,
however, provides more time for degradation of complex organic chemicals. Additionally,
process upsets due to feed variations are less likely in aerated lagoon than in activated sludge
systems due to the larger tank volumes and longer residence time used in aerated lagoon
treatment. The effluent from the aerated lagoon system can be discharged to a settling tank for
solids removal or the mechanical aerators used in the aerated lagoon may be shut down to allow
settling of solids in the treatment tank or pond The settled solids are often dewatered prior to
disposal. ,._'•,
• ' ~ - ' , - • (
A trickling filter system consists of an equalization basin, a settling tank, an filter, medium,
an influent wastewater distribution system, an under drain system, a clarifier, and a recirculation
*''-'.*''•
line. The wastewater enters the equalization basin where it is homogenized. The equalization ,
basin effluent is discharged to the settling tank where solids are removed. From the settling tank,
the wastewater is distributed over the filter medium with a rotating distribution arm or a fixed
distribution system. The filter medium consists of rocks or plastic rings with microorganisms
' \ - • ' ' i
attached to their surfaces. The wastewater forms on this layer as it flows down through the filter
medium. Oxygen reaches the micro-organisms through spaces in the media promoting aerobic .
biological decomposition. A biomass is produced that is separated from the wastewater in a
clarifier. . . '
1 . ' ' •'
A rotating biological contactor is a series of closely spaced, parallel disks made of
polystyrene, polyvinyl chloride, or similar materials. The disks are partly submerged in a tank
• ' ' ' ' •
- - ' . •' 4-25 . - • . •• ' . ' • •
-------
containing wastewater and rotated at an average rate of two to five revolutions per minute. The
disks are covered with a biomass that degrades dissolved organic*. As the disk rotates out of the
water, oxygen is available, promoting biological decomposition. A biomass is produced that
sloughs off the disk, The biomass is separated from the treated effluent in a clarifier.
' ' "•' • , -\ ;' .'.•'• V
Process Constraints. Several waste characteristics affect the performance of aerobic
biological treatments including ratio of biological oxygen demand (BOD) to TOC, concentration
of surfactants, and concentration of toxic constituents of the wastes. The wastes' ratio of BOD to
TOC content provides an estimation of the percentage of biodegradable organics in the waste. If
the percentage of biodegradable organics is low, aerobic biological treatment systems may not
effectively treat the waste. Surfactants can affect biological treatment performance by forming a
film on organic constituents, thereby establishing a barrier to oxygen transfer and effective
biodegradation. .; . i ...../'.
l • . '
A number of constituents and waste characteristics have been identified as potentially
toxic to the micro-organisms used in aerobic biological treatments. These include metals and oil
and grease, as well as high concentrations of total dissolved solids, ammonia, and phenols. . ,
Presence of these toxic constituents in a waste, therefore, may reduce the effectiveness of aerobic
biological treatment. However, microorganisms can be acclimated to handle higher -. '
concentrations of such pollutant loadings. If acclimation is not feasible, appropriate upstream -
treatment trains and holding tanks can be used effectively to reduce the loading of pollutants to
concentration ranges that can be handled by the microorganisms.
4.6.2 Chemically-Assisted Clarification
. • ' ' ' ' ' " •>' ' ' . • ' .
Chemically-assisted clarification includes chemical precipitation and sedimentation. .
-'
. ~ i ' "^
Treatment Applicability. Chemically-assisted clarification is applicable to the treatment of
wastewaters containing suspended solids, colloidal solids, or dissolved solids that are not removed
x ' ' i v
by simple sedimentation. .
V. _ ' ' • . ' ' ' '
. , " . .,'•'•• 4-26 •-...'. . '. • ' '- •" •
-------
Treatment Process Parameters. Coagulants are added to chemically-assisted clarifiers to
enhance liquid-solid separation, permitting solids denser than water to settle to the bottom and
materials less dense than water (including oil and grease) to flow to the surface. Various'"
coagulants and coagulant aids such as alum, ferric chloride, sodium sulfide, ferrous sulfide,
organic polymers, and sodium hydroxide are used depending on the specific waste material to be
removed. The coagulants are rapidly mixed with the wastewater and the colloidal particles
allowed to agglomerate into a large enough floe to be removed by clarification.
Clarifiers are designed to let the wastewater flow slowly and quiescently, providing an
adequate retention time to permit most solids more dense than water to settle to the bottom. The
settling solids form a sludge at the bottom of the clarifier and are usually pumped out.
continuously or intermittently. Oil and grease and other floating materials may be skimmed off -
the surface. *
/ ' '
Chemically-assisted clarification may be used alone or as part of a more complex
treatment process. It may also be used as: -., ,
\ ' . , ...
* * "' * > -"
• The first process applied to wastewater containing high levels of settleable
suspended solids. ' .
• The second stage of most biological treatment processes to remove the settleable
• _ materials, including micro-organisms, from the wastewater; the micro-organisms
can then be either recycled to the biological reactor or discharged to the plant's
sludge handling facilities. , ' -
• The final stage of most chemical precipitation (coagulation/, flocculation) processes
to remove the inorganic floes from the wastewater.
" • ~ . "i • ' ' '
.*
v * -•* ' '
Process Constraints: Waste characteristics affecting performance include chemical '
interactions, temperature, pH, solubility variances, and mixing effects.
4-27
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Many coagulation reactions occur very rapidly, during which some soluble kinetic
intermediates can be adsorbed on the colloidal surfaces. For these reasons, rapid and complete
dispersion of coagulants is necessary. Failure to provide adequate coagulant distribution may
cause localized pH or ion concentrations that can hinder the colloid destabilization to the point of
requiring more coagulant addition. ' ,
" , , • . * , *
' • -s
Adequate retention time and a quiescent flow rate favorably impact the efficiency of solids
i , - • . ' . .
settling within a clarifier. :
4.6.3 Steam Stripping . .
Steam stripping utilizes steam to volatilize organic constituents out of a wastestream.
, !. •
'. Treatment Applicability. Steam stripping is applicable to the treatment of wastes
containing volatile organics. Steam stripping is typically applicable when the waste contains less
than 1 percent volatile organics. ,
f \ .-"'"'• ' ' •
Treatment Process Parameters. The apparatuses required for steam stripping include a
boiler, a stripping column, a condenser, and a collection tank: The stripping column consists of
vertical columns filled with trays or packing. Liquid waste enters the top of the column. The
boiler, located at the bottom of the column, produces vapor that rises through the column and
meets the falling liquid. As the vapor and liquid come into contact at each equilibrium stage,
volatile constituents are removed from the liquid phase into the vapor phase. Equilibrium stages
X '
are produced by the trays or packing in the column. The steam containing volatile compounds
exits the top of the column and is condensed. The condensate is discharged to the collection tank,
and the noncondensed vapors are vented to an air pollutiqn control system or to the atmosphere.
The remaining liquid in the column is discharged to the boiler and recycled to the stripper
4-28
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Process Constraints. Waste characteristics affecting the performance of steam stripping
include the constituent boiling points, the concentration of suspended solids, the surface tension,
and the concentration of oil and grease.
If the boiling points of the lower volatile and higher volatile constituents in the waste are
similar, then the system may not treat the waste effectively. If the waste contains high
concentrations of suspended solids or oil and grease, the solids and/or oil and grease may clog the
column or coat heat transfer surfaces, inhibiting transfer of constituents from the liquid phase to
the vapor phase. These wastes may require filtration prior to steam stripping treatment. If a
waste has a high surface tension, it is more likely to foam. Defoaming compounds can be added
to the waste to prevent foaming. Packed columns also reduce foaming.
4.7 Reuse. Reclamation, and Recycling Potential • / ;
• \ ' . .
•EPA's progress in improving environmental quality through its media-specific pollution :
, ' i . ' •
control programs has been substantial. Over the past two decades, standard industrial practice for
pollution control concentrated to a large extent on "end of pipe" treatment or and disposal of
hazardous and nonhazardous wastes. However, EPA realizes that there are limits to the degree of
environmental improvement that can be achieved under these programs by emphasizing
management after pollutants have been generated. EPA believes that eliminating or reducing
' ' ,
discharges and/or emissions to the environment through the implementation of cost effective
source reduction and environmentally sound recycling practices can provide additional
>
environmental improvements. Reclamation processes that generate reusable wood and recover
i
wood preservative could be applicable to wood preserving wastes. For example, reclamation of
the constituents of phenolic or creosote formulations that have been applied to wood has recently
been attempted in field pilot studies. The process tested achieved up to a 98.7 percent efficiency
9 , - '
converting the treated wood to a usable wood fiber. The wood fiber and the recovered wood
preservative is potentially recyclable (12).
4-29
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4.8 Pollution Prevention and Waste Minimization
The three types of wood preserving processes (pentachlorophehol-, creosote-, and
aqueous-based) are generally similar enough that most pollution prevention/waste minimization
pollution prevention activities are applicable to all three processes. Specifically, each of the three
processes involve receiving untreated lumber, placing it in a treating cylinder/retort, filling the
retort with the preservative fluid, pressurizing the retort, releasing the pressure, applying vacuum,
draining, removing the treated lumber, and storing the lumber (8,9).
* • ' •:
'^ ' • '-
For aqueous-based processes (e.g., copper/chrome/arsenic formulations), modern wood
preservers typically recycle all aqueous wastes back to the processes, haying to dispose of only
contaminated, solids filtered from recycled process streams since the potential waste fluids can be .
flushed and cleaned with water, rather than the oil-based solvents that are present with
pentachlorophenol (PCP) and creosote-based systems. However, the following pollution
prevention alternatives are available to most wood preservers.
* f • . "
4.8.1 Process Additions , . .
' * ' ' •" ''*"*/
i .."'.' . -^ r
The following capital expenditures would not be required to produce quality treated
lumber. Their sole purpose is for pollution prevention: ,
• Enclose wood processing operations and drip pans - Building enclosures around all
operations prevents precipitation events from washing contaminants into the
• . • ' . • * ..
environment or adding to the load in wastewater collection systems.
• Install drip pans - Placing containment under and around sources of drips and spills
, allows the materials to be collected rather than drain into the environment. For
1 ' 3 ... .
aqueous-based systems, the collected drippage can usually be recycled with
. . minimal filtration? . . v ' .
• Automated lumber handling systems, including power rollers - Electronically
and/or remote controlled lumber handling removes the need for personnel to be in
- .. • %- 4-30 " ' • .' '
-------
the area of contaminated drips/spills, thereby preventing tracking of contaminants
throughout the operation. .
4 ' '
• Spill containment - Similar to drip pans, dedicated spill containment devices can be
designed to route spills to the appropriate treatment or recycle locations.
• ' Spill monitoring - Installing electronic monitors to detect spills (e.g., level sensors,
conductivity probes) will prevent their overflowing containment areas, and alert
. operators to possible process failures.
• Computer controlled processes - Computerized controls will minimize the need to
have operators walking in contaminated areas, and tracking contaminants.
1 " * ' ' .
4.8.2 Process Changes . ,
• • ' ' ' • •'• t •
The following changes in the wood preserving process involve capital expenses and are
i
intended to minimize the possibility of spillage. .
• Using higher pressures - The use of pressures in the range of 150-165 psi allow
more rapid penetration of the preservative chemicals into the wood, thereby
providing shorter cycle time and less chance for spills or leaks.
v ">."''"
• High volume pumps - Having pumps that can fill the retorts moire rapidly again
minimize the opportunity for leaks from the retorts because they shorten cycle
time. .
• Large volume vacuum pumps - At the end of the treatment cycle, vacuum is pulled
on the retort to remove excess treatment chemicals from the wood. If large
volume vacuum pumps are used, cycle time is reduced, again minimizing the
opportunity for leaks. ' .n
• Substitution of preservative formulations-While not yet popular, formulations N
* • ..
,. .' such as borates (water soluble and hence only applicable to inside locationsX
ammoniacal copper/quaternary ammonium (ACQ), copper naphthalate, zinc
••' • , ' •'•'..' 4-31 '. ' ' ' ; ' '' -
-------
naphthalate, and zinc sulfate are much less toxic and provide protection to the
lumber. k . ,
\ . - ' ,'.--' , .
4.8.3 Management Practices r t
\
The following activities are typically process changes that do not require significant capital
expenditure, but are operating costs/procedures that are designed to minimize the opportunity for
spills and excessive waste production, hopefully saving more money than the cost of implementing
these activities. ....'- .
. • , Using better quality lumber - Using a higher grade of lumber typically means less
waste. If lumber must be scrapped after treatment, disposal must be as a hazardous
waste, at extra cost. -
* . • , • ' "
• Cleaning lumber - If lumber is cleaned of dirt, debris, and chips prior to treating,
then the removed material will not have the opportunity to become contaminated
with the treating chemicals and not.result in additional hazardous wastes.
• _' -General housekeeping-If materials are stored neatly, away from property lines, in
areas where spills can be contained, and arranged for ease of inspection, then leaks
and breakage will be minimized. . . . -
1 " • ',,.-'
• . Cleaning wheels on fork lifts - Dedicating fork lifts to specific areas will prevent
tracking of contaminated materials. Cleaning wheels on a daily basis, or whenever
a fork lift leaves a contaminated area will also minimize tracking.
4.8.4 -Alternative Wood Preserving Formulations .
'. . • ' ' .-'••' i •
11 . • ' '
Alternatives to chfomated copper arsenate (CCA) include replacing CCA with
ammoniacal copper/quaternary ammonium compound (ACQ) as a wood preservative for
treatment of wood products. By using ACQ, arsenic and chromium are eliminated from the wood
preserving formulation use, which prevents the generation of hazardous wastes (13), !
4-32
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TABLE 4-1
CONSTITUENTS PROMULGATED FOR REGULATION IN F032, F034, and F035
Constituent
Phenol . .
2,4-DimethyIphenol '
2,4,6-Trichlorophenol
2,3,4,6-Tetrachlorophenol
/
Pentachlorophenol .
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluorene
Indeno(l,2,3-cd)pyrene .
Naphthalene
Phenanthrene
. \
Pyrene ' •, • •
Arsenic
Chromium
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibenozo-p-dioxins
Tetrachlorodibenozofurans
Pentachlorodibenzorurans
Hexachlorodibenzofurans
CAS No.
, 108-95-2
105-67-9
. 88-06-2
58-90-2
87-86-5
83-32-9
120-12-7
56-55-3
50-32-8
fal
218-01-9
53-79-3
86-73-7
193-39-5
91-20-3
85-01-8
129-00-0
7440-38-2
7440-47-3
™
«••
•.»
m~.m
• «
-~
F032
X
X
X
X
X .
X
X '
X
- 'X-
X
X
X
X
X
X
X
X
' - X
X
X
X '"
X
X
X
- X
F034
'• ' "
X
X
X .
X
X
X
X
X
'•-x • -
X
X
X
Y
X
F035
• \ - .
,
'
'
"
X
X
' "
Source: U.S. EPA, June 1995.
[a] this constituent is regulated as the sum or benzo(b)fluoranthene (CAS No. 205-99-2) arid benzo(k)fluorathene (CAS
No. 207-08-9),sincebothofthemcoeluteongaschromatography. . ' . .
Note: X indicates that the constituent is proposed for regulation in the individual wastestream.
4-33
-------
TABLE 4-2
PROPOSED BDAT TREATMENT STANDARDS FOR NONWASTEWATER
FORMS OF F032, F034, AND F035, WOOD PRESERVING WASTES
Constituent .
•Phenol
2,4-Dimethylphenol
2,4,6-Trichlorophenol
2,3,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene •
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene*
Chrysene
Dibenz(aji)anthracene
Fluorene
Indenb(l,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Arsenic
Chromium • . .
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibenzo-p-dioxins
Tetrachlorodibenozfurans
Pentachlorodibenzofurans
Hexachlorodibenzofurans
CAS No.
108-95-2
105-67-9
.88-06-2
58-90-2
87-86-5
83-32-9
120-12-7
-56-55-3
50-32-8
[a]
218-01-9
53-70-3
86-73-7
193-39-5
91-20-3
85-01-8
129-00-0
7440-38-2
7440-47-3
.—
_.*
--V
___
- • .«
'
F032(mg/kg) -
6.2 -
14.0
. 7.4
- 7.4
7.4 '
. 3.4
3:4 ' •
3.4
3.4
6.8 (sum)
3.4
8.2
3.4
3.4
5.6
5.6
8.2
5.0 (mg/L TCLP)
6.86 (mg/L TCLP)
0.001
0.001
o.oot
o.ooi ; •
0.001
0.001
F034(mg/kg)
. X 3.4 . '
" ' 3.4
3.4
34
v 6.8 (sum)
. 3.4
- : 8.2 .
3.4
3.4
. 5.6
5.6
8.2
5.0 (mg^ TCLP)'
0.86 (mg/L TCLP)
_
• - ^. *
F035(mg/L)
•-
- -
-
• .
5.0 (TCLP)
0.86 (TCLP)
j
Source: U.S. EPA, June 1995. .
[a] This constituent is regulated as the sum of benzo(b)fluoranthene (CAS No. 205-99-2) and benzo(k)fluoranthene
(CAS No. 207-08-9), since both of them coeiute on gas chromatography. " . .
4-34
-------
TABLE 4-3
PROPOSED BOAT TREATMENT STANDARDS FOR WASTEWATER
FORMS OF F032, F034, AND F03S, WOOD PRESERVING WASTES
Constituent
Phenol
2,4-Dimethylphenol '
2,4,6-TrichlorophenoI
/
2,3,4,6-Tetrachlorophenol
Pentachlorophenol
Acenaphthene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene*
Ghrysene . . ,
Dibenz(a4i)anthracene
Fluorene
Indeno(l,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Arsenic
.Chromium
Tetrachlorodibenzo-p-dioxins
Pentachlorodibenzo-p-dioxins
Hexachlorodibenozo-p-dioxins
Tetrachlorodibenozofurans
Pentachlorodibenzofurans
Hexachlorodibenzofiirans
F032 (mg/L)
0.039
0.036
0.035
0.030 :
0.089
0.059
0.059
0.059
0.061
0.11 (sum)
0.059
. 0.055
0.059
0.0055.
0.059
0.059
0.067
1.4
2.77
i
0.000063
0.000063
0.000063
0.000063
0.000035
0.000063
F034 (mg/L)
0.059
0.059
. 0.059
0.061
0.11 (sum)
0.059
0.055
.0.059
0.0055
0.059
0.059
0.067
1.4
2.77
'
•
-
F035 (mg/L)
j
• \
..i
,
1.4
- ' 2.77
•
Source: US. EPA, June 1995.
*Because benzo(b)fluoranthene and benzp(k)fluoranthene coelute on gas chromatography columns, this constituent is
regulated as a sum of the two compounds. ' ' < ' •
4-35'
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5.0 COMBUSTION TREATMENT STANDARD AS A COMPLIANCE ALTERNATIVE
FOR DIOXIN/FURAN (D/F) IN F032
'' • - ' . i '
5.1 Combustion .Treatment Standard Alternative ~
,1 ' ~ . , •
EPA has established an alternative combustion treatment standard for the regulation of
•*'"-* i. ' f -
PCDD and PCDF in nonwastewater and wastewater forms of F032. As explained in
*• • ... '.•""'
Section 5.2, the CMBST treatment standard alternative is defined in Table 1 of the 40 CFR
268.42. Also, see Table 5-1 which presents the alternative compliance treatment standard
codified today: Under this alternative compliance treatment standard monitoring of each
. regulated PCDD and PCDF constituent is not required as a prerequisite to land disposal if the .
v ' • - •/
specific PCDD and PCDF constituents in F032 are treated via combustion. Under this compliance
treatment alternative, the specific UTS numerical limits of other regulated organic and metal
hazardous constituents in F032 must also be met as a prerequisite to land disposal but those for
PCDD/PCDF need not be. Additionally, EPA is limiting the availability of the promulgated
compliance treatment alternative standard of CMBST to F032 wastes that are combusted in
*- ' ' i
combustion units regulated under 40 CFR Part 266 or in a permitted combustion device operated
under 40 CFR Part 264, Subpart O. Therefore, residues arising from the combustion of F032 in
units operated under 40 CFR Part 265, Subpart O will have to meet applicable numerical limits
for PCDD and PCDF constituents prior to disposal.. EPA believes, however, that Part 265,
/ ' '•..''.•
Subpart O incinerators capable of demonstrating to EPA that the combustion of PCDD and PCDF
i / , . ' • •
in nonwastewater and wastewater forms of F032 would be protective of human health and the
environment shall also be able to meet a CMBST treatment standard alternative. As such, EPA
has established in today's final rule criteria and procedures that should enable EPA to make,such
determination on an ad-hoc basis pursuant to regulations under 40 CFR 268.42 (b). Section 5.5
discusses the criteria and procedures that must be met and followed for the purpose of soliciting .
" ' * i t •
and obtaining from EPA a CMBST treatment alternative, for incinerators operating under a 265,
• • ' ^ t v • '
Subpart O, permit. ' - .
" ' . *- ' *
1 ' " "
Section 5:2 provides background information behind the proposed and promulgated
CMBST treatment alternative. Section 5.3 presents a summary of EPA's Phase 4 Notice of Data
5-1
-------
Availability (NODA) proposal for setting a CMBST treatment alternative for the regulation of
PCDD and PCDF constituents in nonwastewater and wastewater forms of F032. And finally,
Section 5.4 is a review of major comments on Phase IV NODA and EPA's rationale for
promulgating a modified CMBST treatment standard alternative for nonwastewater and
wastewater forms of F032. Since this alternative treatment standard is modeled after a similar
treatment standard EPA established for F024 in the Third Third rule (see 55 FR 22580-22581,
June 1,1990), EPA is also amending the standard for F024.
~~ • , . ' ' <-
- • i '
Although EPA determined in today's final rule that a compliance CMBST treatment
alternative is a feasible regulatory option for the regulation of PCDD and PCDF constituents in
F032 wastes, EPA was not persuaded by the commenters' arguments that PCDD and PCDF shall
be removed from the list of regulated constituents in F032, as EPA did in the promulgation of the
F024 treatment standard. Current data on F032 waste streams show that the concentrations of
PCDD and PCDF in F032 wastes may be, generally, within two to three orders of magnitude
higher than their applicable UTS limit and that the concentrations of the regulated PCDD and
PCDD in past remediation streams may reach concentrations of these constituents up to the ppm
range. These hazardous constituents are routinely identified as constituents of environmental
concern in clean up or remedial activities of wood preserving sites contaminated with PCP
chemicals. Further, all the regulated PCDD and PCDF constituents in F032 do support the listing
of F032 as a RCRA hazardous wastes. EPA is thus retaining the proposed list of regulated
PCDD and PCDF constituents in F032 wastes. EPA has also promulgated in today's rule .
treatment limits for these constituents
5.2 Background
Several members of the regulated community expressed concerns that EPA's proposal to .
regulate PCDD and PCDF constituents in F032 may result Jn problems finding treatment facilities
' • \ - .. '
willing to accept the waste. PCDD and PCDF are very controversial hazardous waste consti-
tuents that often trigger public opposition if documented at any concentrations regardless of the
actual risks presented. PCDD and PCDF monitoring also adds significantly to monitoring costs.
(See generally, 55 FR at 22580-81.) Commenters emphasized that owners and operators of
• • '5-2 . ' '• • • ' • •'
-------
combustion devices had informed them that their combustion facilities will hot accept F032 if
EPA requires the monitoring of PCDD and PCDF in combustion residues. _»- .* .
The American Wood Preservers Institute (AVVPI) and the Penta Task Force asked EPA to
consider establishing an alternative treatment standard that sets a method of treatment as an
V. -• *"
'alternative to the numerical limits for F032. Because combustion is the basis for the PCDD and
PCDF numerical limits, and because properly conducted combustion should effectively destroy
PCDD and PCDF constituents, today's rule establishes combustion as an optional method of
treatment for the regulation of specific PCDD and PCDD in nonwastewater and wastewater
forms of F032. (See 40 CFR Parts 268.42 (b), Table 1, CMBST, and the CMBST footnote.),
i \ ,
. i ' , "
If this method of treatment is used to treat F032 in certain specified combustion devices, there is
no need to monitor compliance with the PCDD and PCDF numerical limits established for PCDD
and PCDF constituents. However, other organic and metal constituents regulated in F032 will
.require monitoring prior to disposal. This approach is patterned after EPA's promulgation of a
similar treatment standard for F024, a group of several hazardous waste residues from the • „ '.
manufacture of chlorinated aliphatics, see 55 FR 22580-81 (June 1, 1990). See detailed
discussion of this proposal in the NODA published in the Federal Register of May 10,1996 (61
FR 21418). Also, this NODA is summarized below under Section 5.3. ;
In general, however, EPA agrees that providing a method of treatment as an alternative to
actual PCDD and PCDF measurement will be equally protective, and will assure availability of
effective treatment for these wastes. EPA is setting such treatment alternative pursuant to EPA's
authority under Section 3004 (m) of HSWA directing EPA to promulgate regulations specifying
, • " '
levels or methods of treatment that substantially diminish the tpxicity of the waste or substantially
i • . " ' *
reduce the mobility of hazardous constituents from the waste. The alternative, namely not
. providing the alternative treatment standard, leaves open the real possibility of these wastes being
refused treatment, an environmentally worse result. EPA is promulgating both levels and
methods of treatment based on the experience gained with F024 waste treatment, for which there
is a parallel treatment regime, has been satisfactory: these wastes are effectively treated by
combustion technology, and sufficient treatment capacity has remained available once EPA .
promulgated the alternative treatment standard which did not require analysis of PCDD and
PCDF in treatment residues. . ~
'• • ' . • • ';'.-"•• 5-3. ' ' .'•••.••'
-------
5.3 Summary of Phase IV NODA for F032
The Penta Task Force submitted data to show that the concentrations of PCDD and :
PCDF in F032 are substantially lower than those EPA reported in the F032 Listing Background
Document. These data consist of typical concentrations of PCDD and PCDF measured in
Pentachlofophenol commercial grades used by Wood Preserving facilities as well as in F032
t , ( '
wastes. See Appendix K for a summary of such data. The Penta Task Force and AWPA stated
their belief .that F032 should be regulated like F024. . .. "
Based on: (1) the new PCP and F032 characterization data; (2) available
characterization data on F024 wastes; (3) rotary kiln incineration treatment data on F024 wastes;
(4) combustion studies supporting the proposed maximum achievable control technology
(MACT) rule for incinerators, cement kilns, and light weight aggregate kilns combusting RCRA
hazardous wastes (61 FR 17358 (April 19, 1996)); and (5) other studies examining the potential
mechanisms behind the generation of PCDD and PCDF in combustion devices; EPA believes
that it is technically feasible to set CMBST as an alternative method of treatment for F032 wastes.
See Appendix K and Appendix L for a list of the consulted data and studies in support of the
development of the CMBST treatment standard alternative. Based on these studies, EPA
.believes further that well operated and well designed combustion practices that operate good
combustion practices can meet the treatment requirements sought by a compliance CMBST
treatment standard alternative. As such, EPA als-> requested comments on potential regulatory
controls on combustion devices to assure that PCDD and PCDF destruction fs conducted in well-
designed and well-operated combustion devices. EPA proposed three regulatory suboptions for
implementing a CMBST standard: .
. Suboption 1 — apply the existing F024 alternative combustion treatment standard to
F032 with applicable regulatory controls in 40 CFR Part 264 Subpart O, ;
265 Part Subpart O, or 266. . '
5-4
-------
Suboption 2 - revise the F024, and establish for F024 and F032, a CMBST standard
' alternative, that would have limited the combustion of F032 and F024 to RCRA
permitted or interim status facility whose combustion devices demonstrate their ability to
achieve a dioJcin toxicity equivalent (TEQ) air emission discharge limit of 0.2 ng/dscm.
Suboption 3 — revise the existing F024 combustion standard, namely CMBST, and
to establish an alternative combustion standard for F024 and F032 that limits the
combustion of F024 and F032 to RCRA permitted combustion devices under the
40 CFR 264 Subpart O.
/ "••'.'.
(See NODA as published in the Federal Register of May 10, 1996 (61 FR 21418).)
5.4 Review of Major Comments on Phase IV NODA and Promulgation of a Modified Version
of Suboption Three :
The majority of comment ers supported the proposed compliance alternative setting
CMBST as a method of treatment. In addition, the majority of commenters preferred suboption 1
(i.e., allow combustion in a RCRA interim status or permitted device) to ensure that combustion
is conducted in well-designed and well-operated devices, a significant number of commenters
also expressed concerns that adoption of suboption 3 may exclude the use of well designed and
well operated interim combustion devices operated under Part 266 rules applicable to boilers and
industrial furnaces.
' ' ' '•
The majority of commenters argued that it would be premature for the Agency to adopt
•- ,. • ' * '
suboption 2 whereby a PCDD and PCDF emission limit of 0.2 ng/dscm TEQ would be established
given that the Agency has only recently proposed such an emission standard for hazardous waste
burning incinerators, cement, and lightweight aggregate kilns under the maximum achievable
1 ••,'•! ' •
control technology (MACT) rule. See 61 FR 17358 (April 19, 1996).5 The Agency believes that
this concern is warranted given that EPA has received substantial comments on whether that
standard is appropriate for those devices and has not made a final decision as to an appropriate
standard.
Also available via Internet: "http:// www.epa.gov/epaoswer/ cmbust.htm".
l ' \
< ' • ' ' 5-5 ' . " ~
-------
The Agency believes that suboption 3 (i.e., allow combustion of F024 and F032 only in
RCRA-permitted devices), as proposed, was too restrictive. EPA agrees with the commenters
that well designed and well operated interim units operated under 266 also quality for the
proposed alternative CMBST compliance standard. Virtually all hazardous waste incinerators
have already been issued RCRA permits, and thus have demonstrated compliance with the
destruction and removal efficiency (DRE) performance standard that ensures destruction of toxic
. organics in the waste feed. In addition, although other RCRA-regulated boilers and industrial
furnaces (e.g., cement and lightweight aggregate kilns) have not yet been issued permits6, these
devices are subject to substantive interim status combustion controls. The controls limit carbon
monoxide or total hydrocarbon.levels in combustion gases, thus ensuring that the devices operate
under good combustion conditions, and can include explicit control of PCDD and PCDF under
specified conditions (see section 266.103 (c) (1)). Although these controls do not provide the
explicit demonstration of destruction of toxic organics in the waste feed that the DRE standard
provides, the Agency believes that they establish good combustion, and may, in some cases,
provide even better assurance of operations under good combustion conditions than the DRE
standard. For example, incinerators have often been .able to meet the DRE standard while
operating at higher carbon monoxide levels (an indicator of good combustion conditions) than
allowed under the interim status standards for boilers and industrial furnaces. .
• /
Accordingly, the Agency believes that it is not necessary to restrict burning to RCRA-
permitted devices because boilers and industrial furnaces operating under interim status are
required to operate under good combustion conditions which should ensure destruction of toxic
organic compounds in the waste feed..
The Agency acknowledges that ensuring that the combustion device operates under good
combustion conditions (i.e., either under a DRE standard or by limiting carbon monoxide and
total hydrocarbon levels in stack gas) may not necessarily ensure control of PCDD and PCDF
emissions. This is because PCDD and PCDF can be formed in the post-combustion zone of the
device—in the duct work and paniculate matter control devices that operate at temperatures
We note, however, that Ashgrove Cement in Chanute, KS, was recently issued a RCRA permit.
..' : / 5-6 . ' •'' '• ' '-' '
-------
above 350°F. However, under existing omnibus permit authority, permit writers can prescribe,
on a case-by-case basis, operating requirements that can ensure appropriate combustion
performance for the treatment of hazardous wastes (see 40 CFR 264.345 (a) and 266.102 (e)(2)).
This authority has been invoked frequently to justify controls on permitted hazardous waste
incinerators which controls are more stringent than those explicitly authorized by the regulations
in 40 CFR Part 264, Subpart O. EPA believes that these authorities can be used to minimize
threats to the human health and the environment that may arise from the combustion ofF032 and-
F024. ', • . . ' .•'•'''". '."..-"
EPA currently lacks similar Omnibus permit authorities for hazardous wastes that are
combusted in incinerators regulated under Part 265.345, Subpart O. Subpart in addition, unlike
the standards for interim status boilers and industrial furnaces, the interim status standards for
-^ ' '
hazardous waste incinerators do not contain controls on good combustion {i.e. CO or HC
controls), a DRE requirement, or explicit standards for PCDD and PCDF. EPA is concerned,
therefore, that the combustion of F032 and F024 in Part 265 incihefators may not consistently
achieve the treatment objectives sought by the alternative combustion compliance treatment
standard. (See also 265.352 (a), forbidding combustion of the acutely hazardous PCDD and
PCDF-contaming wastes in interim status hazardous waste incinerators.) As a result, EPA cannot
support the promulgation of suboption 1 for incinerators operated under Part 265, Subpart O.
5-7.
-------
5.5 . Criteria arid Procedures for Obtaining a Determination of Equivalent Treatment
that May Make a CMBST Treatment Standard Also Available for an Incinerator
Combusting F032 under a Part 265. Subpart Q. Permit
... -v •
Although EPA has determined that an incinerator operated under Part 265, Subpart 0, is
i
generally inadequate for qualifying for a CMBST treatment standard for D/F, EPA believes that
on an ad-hoc basis, a site-specific determination can be made pursuant to 268.42 (b) to extend the
availability of the CMBST treatment standard to incinerators operated under Part 265, Subpart O.
/ v • - >
In considering whether to extend the availability of a CMBST treatment standard to a facility
combusting F032 or F024 in a 265 incinerator, the Agency will seek to ensure that the incinerator
is operating under proper combustion conditions which may be shown by meeting requirements
under such provisions as 264.345 (a) and 266.102 (e)(2), '' '
The process for obtaining the availability of a CMBST treatment standard for a facility
currently combusting F032 or F024 in a Part 265 incinerator will require the accomplishment of
two steps, i One step is for the facility to demonstrate to a permit approving Official7 whether or
not the combustion of D/F in F032 (or F024, if applicable) at this facility (specify name and
location) operating an incinerator under Part 265, Subpart O (not applicable to interim status,
incinerator), satisfies applicable site-specific criteria showing the device performs as well as
.' . ' "
permitted incinerators or regulated BIFs with respect to combustion efficiency and PCDD/PCDF
control. This would normally require a showing that CO/HC levels are the same as those required
for Part 266 BIFs or Part 264 incinerators and that CDD controls are comparable as well. The
second step follows when an approving permit Official issues a written Cftification that such
demonstration satisfies applicable site-specific combustion criteria and the facility solicits from
EPA's Headquarters an equivalent treatment determination under 268.42(b) stating a
determination of equivalent treatment of a CMBST compliance treatment alternative is made
available to the applicant's facility burning F032 or F024: Once EPA Headquarters issues a
7 For the purpose of this rule, a permit approving Official shall be construed as the designated RCRA permit
state Official, if the State is authorized under RCRA to issue RCRA incineration permits (under the 40 CFR 264,
Subpart O; Part 265 Subpart O; and Part 266) at the State jurisdiction the facility's incinerator is located; or an EPA
Regional permit Official, when the State jurisdiction that the facility is located, lacks RCRA authority to issue RCRA
permits pursuant to equivalent regulations under 40 CFR Part 264, Subpart O; Part 265, Subpart O; and Part 266 . '
, '. ' ' ' 5-8. ' • ' ' . .'.'-.
-------
written determination of equivalent treatment, a facility operating a 265, Subpart O incinerator
will be able to meet LDR for F032 or F024 via the "CMBST" treatment standard alternative.
5-9
-------
TABLE 5-1
COMPLIANCE TREATMENT ALTERNATIVE FOR DIOXIN AND FURAN
CONSTITUENTS IN F032 WASTES
Constituent
Tetrachlorodibenzo-p-dioxins
Rentachlorodibenzo-p-dioxins
Hexachlorodibenzo-prdioxins
Tetracholorodibenzo-p-furans
Pentachlorodibenzo-p-furans
Hexachlorodibenzo-p-furans
CAS Number
• _
• . —
• ' ", '---.'
•
' '
Treatment Method*
CMBST
CMBST
CMBST
CMBST
CMBST
CMBST
Compliance with this treatment method is limited only to combustion devices regulated under 40
CFR Part 264 Subpart O and Part 266. Also, a Part 265 incinerator that have obtained from
EPA a treatment equivalency.pursuant to the 40 CFR 268.42 (b).
5-10
-------
6.0 DEBRIS AND MEDIA CONTAMINATED WITH WOOD PRESERVING WASTES
6.1 Land Disposal Restrictions Apply to Wood Preserving Wastes .
The promulgated treatment standards for wastewater and nonwastewater forms of F032,
• . . \.
F034, and F035 also apply to debris contaminated with these RCRA hazafdousVastes and
environmental media that contain these RGRA hazardous wastes (e.g., soils and groundwaters).
Therefore, cbntaminated debris and media that contain F032, F034, or F035 may have to meet the
treatment standards codified in 40 CFR Pan 268.40, as a prerequisite to land disposal unless
waivers from the treatment standard are obtained pursuant to appropriate regulations under
RCRA or CERCLA. (See Section 6.6 for a discussion of potential waivers or variances from the
•f . i
treatment standards promulgated today.) For all the regulated PCDD and PCDF constituents in
' " \ • , •
F032 wastes, debris contaminated with F032, and media that contain F032, EPA has promulgated
an alternative compliance treatment standard that specifies combustion as prescribed treatment
method of treatment. If the F032 stream is treated in accordance with such alternative
combustion treatment standard,- the monitoring of all the regulated PCDD and PCDF constituents
is not required as prerequisite to land disposal. (For a discussion of the promulgated treatment
standard compliance alternative of CMBST, see EPA's discussion in today's Phase IV preamble
and Chapter 5 in this document.) In addition, hazardous debris contaminated with F032, F034,
or F035 may be treated in accordance with the treatment alternative for hazardous debris in the 40
CFR Part 268.45, as a compliance alternative to the numerical limits promulgated today.
Section 6.2 summarizes major comments and EPA's responses regarding EPA's October
/
24, 1991, Advance Notice of Proposed Rulemaking (ANPR); the August 22, 1995, Phase IV
proposed rule; and the May 10, 1996, Notice of Data Availability (NOD A). Section 6.3
discusses the overlap between today's promulgated treatment standards and ongoing remedial
i
activities. Section 6.4 summarizes EPA's rationale for regulating PCDD and PCDF in F032 .
wastes, debris, as well as contaminated media. Section £.5 summarizes EPA's responses to
-• . * •x
comments regarding the proposed UTS and the performance of remediation treatment
technologies. And finally, Section 6.6 discusses the availability of potential waivers or variances
from the treatment standards promulgated today.
" 6-1-
-------
62 Major Comments on Soils and Debris to the Proposed Phase 4 Rulemaking and
EPA Notices on the Available Data for Developing Treatment Standards for
Wood Preserving Wastes
' Comments to EPA's October 24, 1991, ANPR; the August 22, 1995, Phase IV proposed
rule; and the May 10,1996, NOD A emphasized generally four major concerns* regarding the
development of treatment standards: (1) EPA's policy to apply treatment standards to wastes
from remedial activities and contaminated media should be abandoned; (2) EPA should defer
subjecting F032, F034, and F035 contaminated media to LDR to a schedule concurrent with
EPA's regulatory initiatives under the Hazardous Waste Identification Rule for contaminated
media, (3) EPA should forgo the regulation of PCDD and PCDF constituents in F032; and
(4) EPA should reconcile discrepancies for technology selection and treatment standard
development among the Land Disposal Restriction and other remediation programs under
CERCLA/SARA and RCRA/HSWA, namely the Superfund and the RCRA Corrective Action
programs, such that risk considerations are taken into account in the developed treatment
standard. In addition, other commenters argued that the proposed treatment standards for
PCDD and PCDF constituents are unachievable'by remediation technologies.
The above first, second, and fourth major concerns raised by the commenters are raised
often on every rule setting treatment standards for hazardous wastes under the land disposal
restrictions. EPA had already settled these issues in the final rule of Phase 2, as well as earlier
• , . } • "
rules/ EPA is hot reopening, therefore, such issues in today's rulemaking. (See, generally, 50 FR
at 47986-7 (September 19, 1994).) In addition, EPA believes that it will be illegal to adopt the
J i
commenters suggested options that EPA delays applying or exempts from the promulgated
treatment standards, any media or remedial waste contaminated with F032, F034, and F035.
The statue compels their prohibition from subsequent land disposal, like any other newly listed
hazardous wastes (RCRA Section 3004 (g) (4); see also Chem Waste Management vs. EPA. 869
8 For EPA's responses to other comments that are not addressed in this Chapter ..please consult Appendix K in '
this Final BOAT Background Document for Wood Preserving Wastes (F032, F034, and F035) and Phase 4 Response
to Comments Background Document. . . •
' • x *
' • •• .- 6-2' '•••'' . ' ' '
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F.2d, D.C. Cir. 1989). The land disposal restrictions, generally,, will apply to soils or debris which
are contaminated with newly listed wastes already 'prohibited from land disposal.
,63 Overlap of Today's Treatment Standards and On-goingjlemediai Activities
\ • • •. - ' i
Because media and debris contaminated with F032, F034, and F035 will carry wastes that
are now prohibited from land disposal; the contaminated media or debris may become subject to
the same land disposal restrictions applicable to these wastes. Compliance with the treatment
'*' ' v ' ' " f
standards may be required as a prerequisite for land disposal except for media or debris that are
managed in compliance with EPA approved waivers or variances (see Section 6.6 below) from the
^ •.. . ' • / .' • .- '
treatment standard. EPA notes, however, that land disposal restrictions only apply to
.'.'>'• • ' ' ' . .
contaminated debris and media that contain hazardous waste that will be "placed" after the
effective date of the applicable land disposal prohibition -- in the case of soil containing F032,
F034 or F035 that will be on the date the National Capacity Variance (NCV) (see below) expires..
It is important to note that not all contaminated media and debris managed during cleanups will "
contain hazardous waste or be restricted from land disposal. (See, for a general discussion of this
issues, 61 FR 18804-06, April 29,1996.)
EPA believes any disruption to on-going cleanups of F032, F034 and F035 media or
debris containing F032, F034 or F035 will be mitigated by the two year NCV. Under the NCV,
debris contaminated by F032, F034, or F035 and media containing F032, F034 or F035 may be ,
land disposed without treatment. The NCV does not, however, affect other minimum technical
requirements such as lining of surface impoundments and the lining of secure landfills, which
generally must be met as a prerequisite to land disposal. In addition, even after the NCV expires,
on-site remedies that have already been selected and prescribed in a Record of Decision (ROD)
under CERCLA's National Contingency Plan are not subject to newly promulgated regulations
(including the treatment standards for F032, F034, and F035 promulgated today) unless the ROD
' - • " ,s ".
.is modified or contaminated debris or media containing F032, F034 or F03S are managed (e.g.,
• > , j '•
land disposed) off the CERCLA site.9'10 In contrast, a ROD emphasizing the off-site treatment
Q , ' ' * '
.' Note, there is no similar exemption from new regulations for on-going remedies under the RCRA corrective
action program; land disposal of contaminated debris and media containing F032, F034 or F03S would have to
• . 6-3 ' ."':.-
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and disposal of CERCLA remedial soils and remedial wastes will have to comply with the
applicable treatment standards promulgated today. While EPA agrees with commenters that, .
i' ^
generally, application of land disposal restriction treatment standards developed for "generated
wastes" to remediation wastes and remedial process has a chilling effect on remediation and may
be inappropriate, EPA is addressing that issue for all remediation waste through a variety of other
initiatives, most notably, the Hazardous Waste Identification 'Rule for .Contaminated Media,
proposed April 26, 1996 (61 FR 18780). In the meantime, the existing construct of the land
disposal restriction program, including application of land disposal treatment standards to debris
contaminated with restricted waste and media containing restricted waste, will continue to apply.
6.4 Regulation of PCDD and PCDF in F032 Y,
• i '
The third major issue raised by the commenters is that by establishing treatment limits for
PCDD and PCDF in F032 wastes, EPA may disrupt ongoing remediation activities and
discourage voluntary clean ups. The commenters pointed out to the outcome of Solvent and . '
Dioxin rule as an example of an EPA LDR regulation that have discouraged, generally, the
remediation of media contaminated with dioxiri and furan bearing wastes. This is because
commercial treatment facilities often shy away from the management of hazardous wastes/soils
containing PCDD and PCDF whenever EPA requires that such constituents are monitored prior
to land disposal. Other commenters asked EPA to prescribe, instead, a treatment standard of
CMBST for F032 wastes (and F032 contaminated debris and media that contain F032) and to
• " (' •• • .
delete each one of the proposed PCDD and PCDF constituents from the list of regulated
constituents in F032, as EPA did for F024 in the Third Third rule ( See Third Third proposal, 54
FR 48450, November 22, 1989, and Third Third final rule, 55 FR 22580-81, June 1, 1990 (as
later amended by Phase 3, see 61 FR 15588, April 8, 1996)).
comply, as appropriate, with the FD32, F034 an
-------
, EPA acknowledges the industry's concerns that today's treatment standards may drive up
the demand for the combustion of hazardous soils and debris contaminated with,PCDD and
PCDF in F032. This is because combustion is the BOAT model technology supporting the
• ' ~' ' . ' ' - . ' ' ' ' '
numerical treatment limits promulgated for PCDD and PCDF and such treatment limits can be
achieved, generally, by combustion technologies. EPA also agrees that the treatment standard
may have a chilling effect on current or future voluntary clean up efforts by increasing the cost for
complying with the land disposal restrictions and discouraging remedies that call for ex-situ
treatment trains or offsite treatment and disposal. Based on the experience gained with
,- ^ • /
chlorinated aliphatic (F024) and acutely dioxin (F020-23, and F026 ) hazardous wastes, EPA is
also sensitive to concerns emphasizing that access to combustion capacity may be hindered if the
combustion residues are compelled to undergo the monitoring of PCDD and PCDF constituents
in F032 wastes. Normally, EPA does not change a treatment standard expressed as a
concentration limit to accommodate the demands of a recalcitrant industry. However, EPA has
determined today that the treatment of PCDD and PCDF in F032 (i.e. containing hazardous soils,
debris, and wastes) in combustion devices that are well designed and operated meets the legal
, criteria under 3004 (m) for establishing treatment standards that can be expressed as a prescribed
treatment method. EPA believes, further, that the combustion of these streams can be conducted
in a manner that is protective of the human health and the environment. EPA believes, therefore,
that is feasible to established a treatment standard expressed as Combustion and EPA has done so
in today's final rule. Therefore, EPA believes that the promulgated compliance treatment
standard alternative of combustion will address the commenters concern that F032 contaminated
media can be treated in offsite commercial combustion facilities . (See Chapter 5 in this Final
BDAT document for a discussion of EPA's rationale for setting the compliance treatment
. alternative of combustion.) - :
EPA also agrees with the commenters that the promulgated treatment standard for wood
preserving wastes may not always be appropriate or achievable by some debris or hazardous
media contaminated with F032, F034, and F035 Under such circumstances, EPA believes that
the treatability variance process under 268.44 (h) will be able, generally, to address these
concerns. Other potential waivers or variances allowed under CERCLA and RCRA may also be
6-5
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applicable and available. (See Section 6.6 for a discussion of potential waivers or variances from
the treatment standards.) . ! ' .
EPA disagrees, therefore, on the recommendation urging EPA to withdraw from the list of
hazardous constituents, all the PCDD and PCDF proposed for regulation in F032. First, all the
PCDD and PCDF are still regulated as UTS constituents in F032. These constituents are also
> . . ' •
toxic constituents supporting the listing of F032 as a hazardous waste under Subtitle C of RCRA.
Second, numerous RODs where wood preserving sites show PCP contaminants clearly show
instances where PCP, PNAs, PCDD, and PCDF constituents have also contaminated groundwater
bodies, surface waters, debris, and soils. Third, the concentrations of regulated PCDD and PCDF
found at some of these wood preserving sites have been determined to pose a potential risk to the
human health.and the environment warranting the adoption of clean up and corrective measures to
contain, source control, or permanently destroy the concentrations of PCDD and PCDF
contaminants pursuant to EPA's authorities under the Superfund and RCRA Corrective
programs. .
"i • \ . "
The experience gained at wood preserving sites is that in spite of the hydrophobicity
behavior of PCDD and PCDF, these constituents certainly can migrate.from soils and
contaminate surface waters and groundwaters. The migration of PCDD and PCDF has been .
attributed to the vertical and lateral displacement of Nonaqueous Phase Liquids arising from spills
\ -' • ; ..••"•- •
of PCP oils, creosote oils, and fuels at wood preserving sites practicing PCP formulations.
In addition to such organic liquids or mixtures to provide an advection migration vector for the
" • * * " '
transport of PCDD and PCDF, soluble fractions of these organic liquids or mixtures that may be
left untreated in soils can also enhance the solubility of PCDD and PCDF in water due to
cosolvent effects. This pervasive type of pollution has prompted EPA to impose the adoption of
remedies such as containment; the soil excavation and incineration of "hot spots""; and the pump
and treat of groundwater, surface waters, Dense Nonaqueous Phase Liquids, and Light
Nonaqueous Phase Liquids at several wood preserving facilities in order to protect the human
health and the environment. EPA believes, therefore, that forgoing the regulation of PCDD and
11 This BOAT model technology has also been used at Superfund's National Priority List (NPL) and non-NPL
sites to abate PCP, PNA, PCDD, and PCDF from soils and debris.
'.-' - ' 6-6 • •'•..'•.••
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PCDE in F032 will be contrary to the Congressional intent for enacting HSWA seeking to a
reduction of short- and long-term uncertainties associated with the land disposal of untreated
1 • .
hazardous wastes. In agreement with this 3004(m)'s legislative history and EPA's construct of
• . '
3004 (m) allowing the establihment of technology based treatment standards, EPA believes that
promulgation of treatment standards for the regulation of PCDD and PCDF in F032 are
warranted and legal. As a result, EPA is promulgating, therefore, the treatment standards for the
list of toxkrPCDD and PCDF constituents proposed for regulation in F032. •
6.5 UTS Limits and the Performance of Remedial Treatment Technologies . _
Another key concern raised by the commenters is whether or not the UTS limits
promulgated can be achieved by all remediation technologies being used at wood preserving
»
facilities. Also, commenters disputed whether some remediation treatment technologies
identified in the BDAT Background Document and the Phase 4 proposal were demonstrated or
' • • ' i , •
not for wood preserving wastes/contaminated media. In addition, commenters believed that none
of the remedial technologies reviewed by EPA can meet the UTS limits proposed for the
regulation of PCDD and PCDF in F032. - \
To support their views that the proposed UTS limits for PCDD and PCDF are generally
<• ' i
unachievable in soils using remediation technologies, the commenters cited disagreements among
limits for the targeted clean up goals in RODs reviewed by EPA and the proposed UTS limits;
other performance data for remedial technologies cited in the BDAT Background Document; the '•
opinion of authors from other literature cited by EPA on demonstrated technologies for the
treatment of soils/debris contaminated with RCRA hazardous wastes; and finally, several EPA
data bases describing the commercial status or performance of remedial technologies. The cited
EPA data bases include the Alternative Treatment Technology Information Center (ATTIC)
Online System and the Vendor Information System for Innovative Treatment Technologies
, (VISITT). Based on these data bases and the Presumptive Remedy guidance for wood preserving .
sites, the commenters urged EPA to set treatment limits that reflect the performance of remedial
i . • •
technologies being used to abate or contain pollutants in contaminated soils and debris at wood
. ' • v
preserving sites, rather than based on treatment data supporting the UTS limits.
I ' • ; ' s
. . . ' • '• 6-7' " • ' ' • ' .
-------
Under the land disposal restriction program, the selection and identification of one
treatment technology or various technologies as available, demonstrated, and best is driven by
EPA's criteria and methodology discussed in the October 23, 1991, document titled: "Final Best
Demonstrated Available Technology (BOAT) Background Document for Quality Assurance and
Quality Control Procedures and Methodology." The published criteria call for the establish-ment
of treatment standards which rely on the performance of technologies that can provide hazardous
.wastes with treatment levels that can substantially reduce the concentration of organics or the
mobility of metals prior to land disposal and that can substantially minimize short- and long-term
threats to the human health and the environment.
In order to implement this EPA technology based criteria, EPA compares the performance
from potentially applicable and demonstrated technologies and the treatment standard is ^
subsequently based on a technology or group of technologies that can perform "best." In order to
be denoted as "best", the technology must substantially reduce the concentration or mobility of
hazardous constituents being land disposed. As a result of these criteria, a technology selected as
"best" may result on treatment levels that may ensure the permanent destruction of organics or the
least mobile form of a metal. Based on these BD AT criteria, EPA has reviewed the available
data bases and those other studies/data suggested by the commenters and re-evaluted what
remediation technologies may qualify as "best." In examining the available data, EPA looked for
information that will help EPA determine the developmental stage or commercial status of such
technologies (e.g. full versus pilot, available, and demonstrated) and to identify performance data
V • J
on such technologies (e.g. is this treatment "best"). When data were not available specifically on
"~" . • / • ' ' .
soils contaminated with F032, F034, or F035, EPA considered data on the treatment of other
wastes, sludges, oils, or soils that are believed as difficult to treat as F032, F034, and F035. .
/ . • • . '
In an effort to obtain more recent information on the remedial technologies identified in
-, • ' '
the Proposed BOAT Background Document and the proposed Phase IV rule's preamble -
\
discussion seeking data on the performance of specific remedial technologies, EPA looked for the
information in the data bases/references cited by the commenters. EPA placed copies of the
consulted reports/references in the administrative or public docket of today's final rule. EPA also
summarized in Table 6.1 the type of information consulted and where EPA's findings or the
6-S ' - ' '.
-------
consulted documents can be found. For example, EPA findings with regard to the commercial
status of some remedial technologies can be found in Appendix K (see in particular Table K-6 for
EPA responses to comments emphasizing the developmental stage of specific remedial
• \\ •' . -
technologies). Another example is Appendix C which summarizes all the data reviewedjn
< support of the proposed rule including treatment data from field studies conducted on wastes as
difficult to treat as wood preserving wastes. '
- \ .' . . . •
The information described by these data bases consisted of electronically available reports
or vendor/technology profiles from ATTIC, CLU IN, the Internet, •and EPA guidance documents.
The data available in these documents, generally, were limited to enable EPA to conduct an
exhaustive or routine BDAT analyses regarding the treatment performance of the treatment'
technologies under review. EPA routinely examines data for the following:, (1) the availability of
quality assurance/quality control of data test method collection, analytical testing, validation and
reporting, (2) pair data points for untreated and treated waste streams, and (3) availability of
operational and design data on a given technology/test study. For instance, the vendors/EPA
, • <
reports often described reduction levels that the technology was capable of achieving in terms of
j/ . ....
percent level reductions, but no data were provided with regard to the influent concentration
ranges routinely managed by the technology., Other reports just provided anecdotal discussions
emphasizing whether a given remediation technology or set of remediation technologies were able
to meet or fail treatment standards promulgated today. . .
In Appendix C, EPA summarized the available performance data from field studies or the
published literature which reported the concentrations of organics or the mobility of metals
measured treated wastes/soils/wastewaters/remedial wastes believed as difficult to treat as F032,
F034, or F03S. These data appear to suggest that most remedial technologies would fail,
generally, the proposed limits. However, in Table C-5 a closed examination of the studies show
that deviations from the treatment standard may be up to two orders of magnitude higher than the
treatment standard promulgated for most of the technologies examined except for bioremediation.
Based on data: (1) in Appendix A through C; (2) Appendix F; (3) Appendix J; (4) Appendix K;
(5) Appendix L; (6) in the BDAT Background Document for Newly Listed Petroleum Refining
Wastes F037 and'F038; and (7) in the'Proposed BDAT Background Document for Hazardous
•\ ' . 6-9 ••/••'.•,
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Soils; EPA believes that energy and chemical intensive technologies often can yield generally one
of several out comes: (1) treat hazardous constituents in the soil/waste within the same or up to
two orders of magnitude higher than the UTS limits promulgated today; (2) treat the hazardous
constituents of concern in soils/wastes/ remedial wastes to a treatment level that represent a
reduction of at least 90% the total concentration of hazardous constituents in wastes or soils; or
(3) treat high concentrations of the constituents of concern in hazardous wastes/soils/remedial
wastes up to or below the UTS limit promulgated today. These findings are in full agreement
with EPA's findings in several EPA Superfund guidance documents published for the
• / • •
.management of remedial wastes and contaminated media at wood preserving sites (see citations of
Superfund documents in the fourth row in Table 6.1). These documents emphasize the need that
j '
combinations of various remedial technologies may be needed to meet targeted treatment
objectives. , ; •
Based on all the available information, EPA believes, therefore, that energy and chemical
intensive technologies such as thermal desorption, chemical dehalogenation, and critical
fluids/solvent extraction often can reduce the amount of hazardous constituents in soils and
debris prior to disposal within the context of an alternative treatability variance under the
40 CFR 268.44 (h) and normally, to the treatment limits for hazardous wastes of concern. The
\ . ' • • * . - '
ex-situ application of these technologies can be engineered to provide more contact between the
contaminants in soils or debris through better mixing or turbulence such that hazardous organics
of concern can be brought into contact with heat or chemical reagents and to subsequently
undergo further treatment prior to disposal. Likewise, for metals being treated via stabilization.
These technologies along with the appropriate'pretreatment of soils or debris can be optimized,
. generally, to overcome potential matrix interferences.from recalcitrant organic and metal.
constituents in soils and debris. For instance, thermal desorption has been optimized to meet the
UTS limits promulgated for organics at several Superfund and RCRA remedial sites within the
context of 268.44(h) and of 268.45. In addition, optimization of one thermal desorption unit had
allowed the delisting of F037 and F038 petroleum refining sludges from Subtitle C requirements.
In contrast, EPA has determined that alternative technology options that rely in design and
operational principles that are less chemical and energy intensive will perform worse than the '
BOAT model of other noncombustion technologies such as those emphasized above. One
>-.•'•• ' ' '
' ' . '•'•'' . 6-10 . • • . . ' .
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technology example is bioremediation. Bioremediation is a highly matrix dependant technology
and often will fail to meet UTS limits. One reason is the technology's inability to remove and to
,' 4- ' ' * ' f ^ '
destroy all the organic'constituents present in the matrix. Another reason is that the technology's
performance is also more sensitive to contaminant shock loadings in the soils or debris than other
technologies such as thermal desorption or incineration. Like the noncombustion technologies
discussed above, however, bioremediation may perform best if used as part of a treatment train
that include other physical/chemical technologies that substantially reduce the organic loadings in
soils. New advances on bio-augmentation research may also improve the long-term feasibility of
the technology.. Further, EPA's Presumptive Remedies document for wood preserving sites
emphasizes the need that bioremediated soils are managed in combination with containment
N ' •>' i ' '
controls in order to minimize the potential migration of residual organics from the disposal site.
/ " • • •
This document also emphasizes the need that the technology may have to comply with the .
provisions of a no-migration petition in order to be used for the remediation of soils that contain
i. , . • -' •
hazardous wastes prohibited from land disposal. ..
. %'
The UTS limits promulgated for organics and PCDD and PCDF regulated in nonwaste-
water forms of F032 wastes (including contaminated debris and soils that contain F032 waste) .
are based on the performance of (and are generally achievable by) combustion technologies. The
treatment limits promulgated for PCDD and PCDF constituents in honwastewater forms of F032
s ' \ •-
are based on the combustion of. solids, liquids, and soils with PCDD and PCDF bearing wastes,
namely the acutely hazardous wastes F020-F023 arid F026 (see 51 FR 1733, January 14, 1986).
EPA's existing technical guidance documents describing technological options for treating
contaminants found at wood preserving facilities often recommend incineration as a viable
i . ' .' '
technology for cleaning up "hot spots" of organics and PCDD and PCDF and other organic
contaminants. These guidance documents also emphasize that incineration is usually able to treat
below cleanup levels and LDR treatment limits. (See Presumptive Remedies for Soils. Sediments.
and Sludges at Wood Treater Sites. Directive 9200.5-1:62. NTIS #PB-95-9634lO: Technology
." ' » ; - '
Selection Guide for Wood Treater Sites. EPA 540-F-93-020 or Pub.9360.0-46FS; and
Contaminants and Remedial Options at Wood Preserving Sites. EPA/600/R-92/182.)
6-11
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EPA has determined that the following non-combustion technologies are also available
and demonstrated for wood preserving wastes/remedial streams: (1) thermal desorption, critical
fluid extraction/solvent extraction, and chemical dehalogenation for organic or chlorinated
organics in nonwastewater forms of F032 arid F034 and (2) stabilization and vitrification for
t \
metals in nonwastewater forms of F032, F034, and in F035. Available data on the performance
of these non-combustion technologies do not necessarily support the commenters' claim that
these remedial technologies will fail to meet the treatment limits promulgated today. Based on
•;..- / '
performance data available from the,treatment of PNA organics in .petroleum refining hazardous
wastes (see BDAT Background Document for F037 and F038 Petroleum Refining Wastes) by
thermal desorption and critical fluids/solvent extraction and from the treatment of organics, PCBs
and PCP oils, soils, and sludges treated by chemical dehalogenation (e.g. KPEG and NaPEG)
(see Appendix C), EPA believes that chemical dehalogenation (for PCDD, PCDF, and
V • . • ' • ' .
chlorinated organic constituents), critical fluid (CF-5 passes study for PNA) /solvent extraction.
(organics ), and thermal desorption (for organics and PCDD and PCDF constituents) generally
could be optimized to meet the UTS limits promulgated today for F032 and F034 and for
" , " i ' —• •
contaminated media within the context of 268.44 (h) . In situations where EPA determines that
the treatment standards are inappropriate for contaminated soils, EPA may allow the use of a ,
remedial technology that achieve, instead, a site-specific, risk-based cleanup levels, but may not
achieve the more stringent land disposal treatment standards. .(See, generally, LDR treatment
variance procedures under 40 CFR 268.44 (h) and for guidance on land disposal treatment
variances see, September 1990 implementation guidance documents ; OSWER 9347.3-06FS and
9347.3-06BFS, also known as LDR Guide # 6A and #6B, respectively and the January 8, 1997
EPA guidance memo, "Use of Site-Specific Land Disposal Restriction Treatability Variances
Under 40 CFR 268.44(h) During Cleanups." Each one is available in Appendix H .')|For the
purpose of today's rule, EPA does not find, however, that each one of these technologies should
be classified as best. For instance, the available performance data on thermal desorption show
that the technology can be optimized to yield sludges, and presumably soils, with concentrations
A
of organics well below the UTS treatment limits promulgated today.12 Although the soil, debris,
and sludges treated by thermal desorption may meet the treatment standards, residues from
12 See thermal desorption data in the.BDAT Background Document for F037 and F038 Petroleum Refining
Wastes and in the Marathon Oil Delisting Petition (see Federal Register Notice in Appendix F).
/ _. ' •
. ' • '• . 6-12 .' / :-.'"'
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thermal desorption such as PCP oils and carbon filters will have to undergo chemical
dehalogenation or combustion in order to meet the treatment standards promulgated for F032.
As explained above, .EPA has found that the feasibility of nonthermal treatment technologies for''
remediating contaminated debris or soil that contains F032 waste at wood preserving sites may
require the combined use of two or more of these technologies along with other chemical/physical
treatment for the purpose of meeting clean up levels or treatment objectives. This is, however, a
site-specific determination, and the ability of a treatment train to meet or fail UTS or a treatability
i ' . ' '
variance limit will be assessed through the findings of a feasibility study.
• ' '
". . i ^
6.6 Potential Waivers or Variances from the Treatment Standards Promulgated Today
EPA has always stated that there is a presumption treatment standards promulgated for
hazardous wastes prohibited from land disposal which may hot be appropriate for contaminated
soils. EPA believes, further, that such presumption can readily be verified and addressed through
treatability variance procedures promulgated in the 40 CFR Part 268.44 (a), (h), and (o). In fact,
it has been EPA experience under Superfund (Remedial and Removal) and the RCRA Corrective '
Action Programs that Part 268.44 (h) can address, generally, difficult to treat soil-matrices or
contaminated soils for which EPA has determined that the nationally applicable treatment
standards are inappropriate. In any case, a facility seeking such treatability variance compliance
alternative will be required to meet, generally, alternative treatment limits or a level of
performance that EPA believes fully satisfies 3004 (m) statutory directives.
• ~ • '. ,--,'' •
Two, other treatment alternatives available in the 40 CFR Part 268 can be found in:
(1) the 40 CFR Part 268.45 (Hazardous Debris Compliance Alternative) and (2) 40 CFR
Part 268.42 (b) (Alternative Treatment Methods). These treatment .alternative variances may
•'.••*•
.allow the establishment of other treatment limits or treatment methods, respectively.
...'«'"'. " . •"" ' • •
J t
Another compliance option that may waive treatment standards can be found in
the 40 CFR Subtitle S, Part 264.552 (Corrective Action Management Units). These .
Corrective Program regulations under Subtitle S may allow EPA to waive LDR requirements
under limited circumstances, allowing the disposal of treated or untreated soils in a Corrective
••• . ' . • 6-13' ;. ".': '
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Action Management Units (CAMU) (see 58 FR 8683 (February 16, 1993)). These CAMU
waivers are available for RCRA and Superfund soils contaminated with prohibited wastes.
However, EPA proposed to withdraw CAMU from the 40 CFR 264,, Subtitle S, once EPA
finalizes the proposed regulations for hazardous media under the proposed Hazardous Waste
' f
Identification Rule. Finally, petitioners who can meet the provisions of a no-migration
variance under the 40 CFR 268.6 are not required to treat. This other legal venue takes into
account site-specific characteristics of the land disposal practice under review and risks models
to assess whether hazardous constituents of concern will migrate or not from the disposal unit
as long as the hazardous constituents remain hazardous. As a result, a facility which is granted
' • ' -
a no-migration petition may land dispose of untreated hazardous wastes or contaminated media
at the land disposal unit for which EPA has approved the no-migration petition.
In addition, it should be emphasized that not all remedial activities may trigger the land
. ' ' s- f
disposal restrictions. For instance, facilities which re-consolidate hazardous wastes within an
area of contamination or which close the disposal unit as a landfill, also known as capping,
: generally would not trigger the land disposal restrictions. Similarly, facilities which remediate ,
prohibited wastes with in-situ treatment technologies would not trigger treatment standards
r except for remedial wastes that are routed to an ex-situ treatment unit and the collected and the
treated remedial wastes are subsequently land disposed on-site or off-site.
i '
Section 121(d)(4) provides that under certain circumstances the Administrator may waive
CERCLA remedial and removal responses from full compliance with Applicable or Relevant and
Appropriate Requirements ( ARARs) that have been determined by the Agency as being
practicable. The application of these statutory waivers to a removal or remedial action is .
described below: . : '
" -• v • .
*j • . •
.0 Interim measures:. Compliance with an ARAR is not necessary when the removal
action does not involve final clean up of a site and the final clean up will attain
!. the ARAR. N '
6 Compliance will result in greater risk to the human health and the environment:
6-14
-------
If the ARAR forces an action that wo'uld pose a greater risk to the human health
and the environment, the ARAR can be waived. .
o Technical impracticability: it is technically impracticable or impossible to meet
from an engineering stand point.
o .Equivalent standard of performance: Compliance with the ARAR is not necessary
if the removal/remedial action would achieve a standard of performance that is
x equivalent to that required by the ARAR.13 \
o Inconsistent application: An otherwise applicable or relevant and appropriate :
- * x ' ^- ' ' ' '
State requirement is not an ARAR and need not to be attained when that .
requirement is not consistently applied to hazardous waste sites or facilities
through out the State (CERCLA as well as non-CERCLA sites).
o Fund balancing: It is not a requirement of the removal or remedial program,
However, when complying with an ARAR requires an expenditure that
jeopardizes the Fund's ability to address other sites, the ARAR can be waived.14
' _
If needed, EPA may call these CERCLA authorities to waive ARARs that trigger land disposal
restrictions at Superfimd sites in the National Priority List (NPL) or at sites that undergo a
Removal Response. However, it has been EPA experience with NPL sites that the concerns
raised by the commenters can be addressed, generally, through the treatability variance process in
the 40 CFR 268.44 (h). \
13 However, a technology -based standard may not be replaced by a risk based analysis. See 1990 NCP (44 FR
8748). - '.''•'•• . . ' ' . -
14 See 55 FR 8750 (March 8, 1990).
6-15
-------
•_.,-• •' 7.0 .REFERENCES ' ;
1. U.S. Environmental Protection Agency. Office of Solid Waste. Background Document
Supporting the Final Listing of Wastes from Wood Preservation Processes. Washington, ;
D.C. November 1990.
2. U.S. Environmental Protection Agency, Office of Solid Waste. Final Treatment
.Technology Background Document. Washington, D.C., May 1990. ;,
3., 40 CFR Parts 261,266,268, and 271. , .
4. U.S. Environmental Protection Agency. Office of Solid Waste. Best Demonstrated
Available Technology (BDAT) Background Document for Universal Standards: Volume
A. Universal Standards for Nonwastewater Forms of Wastes. U.S. Environmental
Protection Agency, Washington, D.C. July 1994. .
5. U.S. Environmental Protection Agency. Office of Solid Waste. Best Demonstrated
Available Technology CBDAT) Background Document for Universal Standards: Volume
B. Universal Standards for Wastewater Forms of Wastes. U.S. Environmental Protection
, Agency, Washington, D.C. July 1994. (PB 94-170313 and PB 95-187225)
6. U.S. Environmental Protection Agency, Office of Solid Waste. SW-846 Test Methods for
Evaluating Solid Waste. 3rd Ed., Volume IB, Washington, D.C., U.S. Environmental'
Protection Agency. November 1986, (PB 88-239223) .
7. U.S. Environmental Protection Agency, Office of Solid Waste. Methodology for
Developing BDAT Standards. U.S. EnvironmentaLProtectioh Agency, Washington, D.C.,.
1991. (1989 version - PB 89-142301)
8. Waste Minimization Practices at Two CCA Wood-Treatment Plants, EPA/600/R-93/168,
August, 1993. ,
• : ' : • •• 7-1' ' : . . < '
-------
\ •
9. Guides to Pollution Prevention - Wood Preserving Industry, November, 1993. (PB 94-x
136298) .
10. Wood Preservation Statistics, 1990, James T. Micklewright, 1991.
11. Wood Preservation Statistics, 1993, James T. Micklewright, 1994.
. *
12. Portier, Ralph J., Darryl Hoover, Scott Miles, and Neil Emfinger. Recovery of Wood
Fiber From Treated Wood Products by Combined Physical. Chemical, and Biological
Approaches: FIELD PILOT STUDIES. Microterra, Inc. Boca Raton, FL.
f ' ' ' ' - •
13. Chen, Abraham, S.C., Evaluating AC A As An Alternative Wood Preservation System.
Prepared for U.S. Environmental Protection Agency, Risk Reduction Engineering
' ' * i "
Laboratory, Cincinnati, OH. January 1994. - . _
14. U.S. Environmental Protection Agency, Office of Water. Preliminary Data Summary for
the Wood Preserving Segment of the Timber Products Processing Point Source Category.
EPA 440/1-91/023, Washington, B.C. September 1991. ...
IS. ~ U.S. Environmental Protection Agency, Office of Solid Waste. Background Document ,
for Capacity Analysis for Land Disposal Restrictions, Phase IV - Issues Associated With
. Clean Water Act Treatment Equivalency, Treatment Standards for Wood Preserving -
> . • . - . • • '-'-.•'.
Wastes, Toxicity Characteristic Metal Wastes, and Mineral Processing Wastes.
Washington, D.C, March 8, 1995 draft. .
16. U.S. Environmental Protection Agency, Office of Solid Waste. Background Document .
for Capacity Analysis for Land Disposal Restrictions, Phase IV - Issues Associated With
,-.*-• '*• * ' • -
Clean Water Act Treatment Equivalency, Treatment Standards for Wood Preserving'
Wastes, Toxicity Characteristic Metal Wastes, and Mineral Processing Wastes.
Washington, D.C. July 18, 1995 draft.
7-2
-------
17. Barry Lesnik, Methods Section, EPA Office of Solid Waste, 1996 Pittsburgh Conference
« ' .. X
Presentation, Chicago, IL, March 1996. ,
7-3
-------
8.0 ACKNOWLEDGEMENTS
Radian Corporation and its contract team member, Versar, Inc., provided technical ,
support for the development of the proposed version of this document for the U.S. Environmental
Protection Agency, Office of Solid Waste under Contract Number 68-W3-0001. The proposed
version of this document was prepared under the direction of Richard Kinch, Chief, Waste .
Treatment Branch; Larry Rosengrant, Section Chief, Treatment Technology Section; and Carolyn
Cunningham and David Levy, Project Officers. Jose E. Labiosa served as EPA Project Manager.
" *- • ' J • ^
Steve Silverman served as EPA legal advisor. '.'.„•
• .- •' . • ' ;
the following personnel from Radian Corporation supported the development of this
"" V , . ,
document: Gayle Kline, Program Manager; William Sproat, Project Director; and the Versar
engineering team; Jerome Strauss, Associate Program Manager; Andrew Oravetz, Principal
InvestigatorAVork Assignment Manager, Stephen Schwartz, Amanjit Paintal, and Charles Peck.
In finalizing this document, Science Applications International Corporation provided
* s "
technical support to the U.S. Environmental Protection Agency, Office of Solid Waste, under
Contract No. 68-W4-0030. This final document was prepared under the direction of Michael
Petruska, Chief, Waste Treatment Branch, and Jose E. Labiosa, EPA Project Manager. SAIC
staff who supported the finalization of this document include Mary Wolfe, Project Manager,
Harry McCarty, Ph.D., Mario Gamboa, Kristy Allman, Kirsten Crockford, Kelly Mularie, and
Stephan Susta. .
-------
-------
- \. A
' Appendix A
Treatment Performance Data Base and
Methodology for Identifying Universal Treatment Standards
for Constituents in Nonwastewater Forms of
F032, F034, and F035
-------
\.
-------
TABLE OF CONTENTS
' - Page
A. 1 . . Methodology for Determining BOAT Universal Treatment Standards ...... A-l
A. 2 . Determination of Treatment Standards for Nonwastewater Forms of F03 2,
- • ; F034,andF035 .....,...- ..... :;. ,..".: .............. ...... A-2
'.A.2'.i: Phenols .• ..... -.-. ...... ' ....... -. .' . ..;.......,. ..... '..'.'...' A-2
•' '- '. A.2.2 PAHs .! ...... '. . ...... -... ......... ......... '....".' ..... '. . A-4
A.2.3 Dioxins and Furans : ...... . ...... ' ....................... '. . A-7
A.2.4 Metals . ____ :.':.:..... ..................... ' ........... ./. A-8
LIST OF TABLES ;
, ^ Page
A-l Determination of Universal Treatment Standards for Organic Constituents
(Nonwastewaters) .................. ..... ...... ......... . ..... A- 10
1 • ' ' ! '
A-2 Determination ofUniversal Treatment Standards for Metal Constituents
(Nonwastewaters) ....... ..... ......... ..... ........... ...... . A-I2
-------
-------
EPA is promulgating universal treatment standards (UST) for the regulation of specific
hazardous constituents in nonwastewater forms of F032, F034, and F035. This Appendix presents
the methodology for establishing nonwastewater universal standards. Section A. 1 presents the
methodology for determining nonwastewater Best Demonstrated Available Technology (BDAT)
Universal Treatment Standards. Section A.2 presents a cpnstituent-by-constituent discussion of the
determination of the universal standards for each regulated constituent.
1 "
A.I Methodology for Determining BDAT Universal Treatment Standards '
The performance data presented in Appendix A represent the universal standards data for the
constituents regulated in F032, F034, andF035. . .'
The Agency chose which treatment standards to transfer as the universal standard on a
constituent-by-constituent basis. Six factors were considered in selecting the "best" standard from
the available treatment standard performance data:
(1) Where possible, the Agency preferred performance data'(i.e., the matrix spike
recovery data, detection limit, and variability factor (according to Table 'A-1)) for the
same constituent.
• • •
(2) , The matrix spike recovery data were evaluated to determine whether acceptable
-recoveries were obtained according to EPA's quality assurance/quality control
guidelines. , .
(3) When performance data from the same constituent were unavailable, the Agency used
performance data from a constituent with similar composition and functional groups.
\ • ' t.
(4) When evaluating the matrix spike recovery data, the Agency preferred to use a matrix
spike recovery for a specific constituent instead of a value averaged over a group of
constituents (e.g., volatile organics). ' n
' - . . • *• • i ...
(5) The method detection limit was examined to determine if it could be met routinely by
. industry., , . • . [ ' • ~
2121V236\appendix..
A-i;
-------
(6) - The treatment standard corresponding to the "best" data was compared to the
detection limits used to calculate other treatment standards to determine if the
constituent could be treated to similar levels in similar waste codes.
A.2 Determination of Treatment Standards for Nonwastewater Forms of FQ32T F034. and
£035 - .. .-•-•'-. ' ' '
Treatment standard data for the constituents regulated in nonwastewater forms of F032, F034,
and F035 are presented in Table A-l and Table A-2. A constituent-by-constituent discussion of the
determination of the universal treatment standard for, each of these constituents is given below. A
more detailed discussion of the determination of the universal treatment standards is provided in
EP A's Final Best Demonstrated AVflflflble Technology (BPAT) Background Document for Universal
Standards for Nonwastewater Forms of Lise
(4).
A.2.1 Phenols
Phenol-
, The universal standard for phenol was determined to be 6.2 mg/kg, based upon the F039,
K083, and U188 treatment standard data. The Agency chose to use these data because they represent/
the transfer of an accuracy correction factor and detection limit from the same constituent as the
1 -
constituent of concern and the use of an actual matrix spike recovery. The Agency did not use the
K022 treatment standard data because the treatment standard was considered to be .an outlier
' ' ' i ' - • • '
compared to the magnitude of the detection limits from other incineration tests. The Agency believes
that a universal standard of 6.2 mg/kg may be reasonably achieved based on detection limits reported
for phenol in other waste codes. .
2I21\236\ippeodui - : .' ' . • . A-2
-------
2,4-Dichlorophennl: . .
*' * ' *
The universal standard for 2,4-dichlorophenol was determined to be 14 mg/kg, based upon
the F039 and U081 treatment standards, which represent the only concentration-based standards
.
promulgated to date for this constituent.- ... ;
2.4.6-Trichlorophenol: • - •;'.'..'..'
. The universal standard for 2,4,6-trichlorophenol was determined to be 7.4 mg/kg, based upon
the F039 treatment standard data. The Agency chose not to use the K105 data because it believes
that the K105 standard of 4.4 mg/kg is not reasonable for a universal standard based on other
incineration test detection limits. ^
' ' s
-' . - ' •,'•.'<•''' ' • ' • '
2.3.4.6-Tetrachlorophenol: '.,'••
The universal standard for 2,3,4,6-trichlbrophen61 was determined to be 7.4 mg/kg, based
upon,the F039 treatment standard,, which represents the only concentration-based standards
/
promulgated to date for this constituent
Pentachlorophenol:
' , The universal standard for pentachlorophenol was; determined to be 7.4 mg/kg, based upon
the F039^ K001, and U051 treatment standards, which represent the only concentration-based
standards promulgated to date for this constituent.
212U236\appendix' . A-3
-------
A.2.2 PAHs
Acenaphtheny; .
The universal standard for acenaphthene was determined to be 3.4 mg/kg, based upon the
K035 treatment standard data. .The Agency chose to use the K035 treatment standard data rather
than the F039 treatment standard data because the F039 treatment standard was promulgated
incorrectly as 4.0 mg/kg instead of 0.8 mg/kg. The Agency believes that a standard of 0.8 mg/kg may
not be reasonably achieved based on detection limits reported for acenaphthene in other incineration
' tests. •.. ' • . . '-;.'•_•
I • • _ •
Anthracene: , . •
The universal standard for anthracene was determined to be 3.4 mg/kg, based upon the KO15
and K035 treatment standard data. The universal standard for anthracene was not based upon,the
F039 treatment standard data because the F039 standard was promulgated incorrectly as 4.0 mg/kg
instead of 0.8 mg/kg. The Agency believes that a standard of 0.8 mg/kg may not be reasonably
achieved based on detection limits reported for anthracene in other incineration tests.
. ' '' Benz(a)aiithracene; ... • • _
* <" *• ' '
The treatment standard for benz(a)anthracene was determined to be 3.4 mg/kg, based upon
the K035 treatment standard. The Agency chose to use the K035 treatment standard data because
these data represent the use of an accuracy correction factor and detection limit from the same
constituent as the constituent of concern. The Agency believes that a treatment standard of 3.4
, s ' ' ^ "~
' L • ' "* ' ' '
mg/kg may be reasonably achieved based on detection limits reported for benz(a)anthracene in other
"*• '
waste codes." ; . .
212U236\ap|xsodix
A-4
-------
Benzofalpvrene: •
k .' • .
The treatment standard for benzo(a)pyrene was determined to be 3.4 mg/kg, based upon the
K035 and K06Q treatment standards. The Agency chose to use the K035 and K060 treatment
standard data because these data represent the use of both an accuracy correction factor and detection
limit from the same constituent as the constituent of concern. The Agency believes that a treatment
standard of 3.4 mg/kg may be reasonably achieved based on the detection limits reported for ^
benzo(a)pyrene in other waste codes. .
Benzo( k)flu o ran t hene: ... • ' .
The treatment standard for benzo(k)fluoranthene was determined to be.6.8 mg/kg, based upon
the F039 treatment standards for benzo(k)fluoranthene. This constituent is regulated as a Sum/2 to
account for analytical problems in distinguishing between the two compounds in nonwastewater
matrices. '
; . - Chrvsene: ' •.,•.<•'.'••.'•••
i • '"**".
The universal standard for chrysene was determined to be 3.4 mg/kg, based upon the K087
and K03 5 treatment standards data: The Agency chose to use the K087 and K03 5 treatment standard
data because these data represent the use of both an accuracy correction factor and detection limit
from the same constituent as the constituent of concern. The Agenc/ believes that a universal
standard of 3 4 mg/kg may be reasonably achieved based upon detection limits reported for chrysene
in other waste codes. .
/• ' ' ~ .
bibenzfa.h^anthraccne: "' \ • . .
• ^^»^^^„» . . v 3 • ,_
The treatment standard for dibenz(a,h)anthracene was determined to be 8:2 mg/kg, based
upon the F039 and U063 treatment standards. The Agency chose to.use the F039 and U063
^ ' '' ' * '
2121\236\ippeodix A-5 . ' ' • - ,
-------
treatment standard data because these data represent the use of an actual matrix spike recovery. The
Agency believes thtf'a treatment, standard of 8.2 mg/kg may be reasonably achieved based on
detection limits reported for dibenz(a,h)ahthracene in other waste codes.
Fluorene:
The universal treatment standard for fluorene was determined to be 3.4 mg/kg, based upon
the K035 treatment standard data. The Agency chose to use these data rather than the F039
treatment standard data. The F039 standard was promulgated incorrectly as 4.0 mg/kg instead of 0.8
mg/kg. The Agency believes that a standard .of 0.8 mg/kg may not be reasonably achieved based on
detection limits for fluorene from other incineration tests. .
Indeno( 1.2.3-cd)pyrene:
' •
The treatment standard for mdeno(l,2,3-cd)pyrehe was determined to be 3.4 mg/kg, based
upon the K035 and K087 treatment standards. The Agency chose to use the K035 and K087
/ . i
treatment standard data standard data because these data represent the use of both an accuracy
correction factor and detection limit from the same constituent. The Agency believes that a treatment
standard of 3.4 mg/kg may be reasonably achieved based on detection limits reported for
indeno(l,2,3-cd)pyrene in other waste codes.
>. ' " ' . •
The treatment standard for naphthalene was determined to be 5.6 mg/kg, based upon the
KOI9 treatment standard. The Agency chose to use the KOI9 treatment standard data because these
. u ' - ,3 • ' '
data represent the use of an accuracy correction factor and detection limit from the same constituent.
The Agency believes that a treatment standard of 5.6 mg/kg may be reasonably achieyed based on
detection limits reported for naphthalene in other waste codes..
A-6
-------
Pt^nanthrene: ~ • " . . ,
\
The universal standard for phenanthrene was determined to be 5.6 mg/kg, based upon the
KOI 9 treatment standard. The Agency chose to use these data because they represent the use of an
accuracy correction factor and detection limit from the same constituent as the constituent of concern.
The Agency chose a universal standard of 5.6 mg/kg to account for; regulatory flexibility based on
variations in treatment of this constituent. . .
Pyrene:
The universal standard for pyrene was determined to be 8.2 mg/kg,rbased upon the K035 and
F039 treatment standard data. The Agency chose to use these data because they represent the use
" " V
of an accuracy correction factor and detection limit from the same constituent as the constituent of
• ..„•'•"' "^ J .
concern: The Agency believes that transfer of data from K001 and U051, with a treatment standard
V, ' . " .
of 1.5 mg/kg, is not reasonable for a universal standard based on detection, limits from other
incineration tests. ',.-.'
A.2.3 Diouns and Furans
Tetrachlorodibenzo-p-dioiins:
* s. '
The universal standard for tetrachlorodibenzo-p-dioxins was determined to be 0.001 mg/kg,
based upon the F039 treatment standard, which represents only concentration-based standard
promulgated to date for this constituent.
Ajr
<,.„., «-,.Kr— . '
-------
Pentachlorodibenzo-p-dioxins: .
•• .' . , • ' • , ~- -'
; ,
The universal standard for pentachlorodibenzo-p-dioxins.was determined to be 0.001 mg/kg,.
, ' ' v _
based upon the F039 treatment standard, which represents only concentration-based standard
promulgated to date for this constituent. . ...
** ' • . " '.''*
Hexachlorodibenzo-p-dioiins: . • .
The universal standard for hexacnlorodibenzo-p-dioxins was determined to be 0.001 mg/kg,
based upon the F039 treatment standard, which represents only concentration-based standard
promulgated to date for this constituent.
' Tetrachlorodibenzofurans: • -•,•'. • ' '
The universal standard for tetrachlorodibenzofurans was determined to be 0.001 mg/kg, based
upon the F039 treatment standard, which represents only concentration-based standard promulgated
to date for this constituent.
.' > ' '
Pentachlorodibenzofurans:
The universal standard for pentachlorodibenzofurans was determined to be 0.001 mg/kg,
based upon the F039 treatment standard, which represents only concentration-based standard
promulgated.to date for this constituent. . ,'•,'._,'
Hexachlorodibenzofurans: • ..
I , - • • , . •
- -I I
The universal standard for hexachlorodibenzofurans was determined to be 0.001 mg/kg, based
upon the F03.9 treatment standard, which represents only concentration-based standard promulgated
to date for this constituent.
212n236\appendix . • A-8'
-------
A.2.4 Metals .'...- '
/ ' , •«
Arsenic:
The universal standard for arsenic was determined to be 5.0 mg/L in the TCLP extract based
upon the F034 treatment standard. The F039 treatment standard was established as equivalent to the
• .• '.',-'•'' • ' p
toxicity characteristic (TC) regulatory level for arsenic (D004). Table A-2 summarizes the
determination of universal standards for arsenic in honwastewater forms of wastes. The table
! ' '
includes the waste code, treatment performance data, and technology from which the universal
standard was transferred. - s
The Agency established BDAT for arsenic as slag vitrification. The universal standard was
not based upon K061-HTMR data because the Agency believes that this technology is not "best" for
treatment of arsenic in universal standards wastes. The available slag vitrification treatment standard
data (K031, K084, K101; Kl02, P010, P036, P038, and U136) show treatment to a leachate
concentration of 1.8 mg/L (using the Extraction Procedure (EP) toxicity test). The universal standard
based on this value would yield a standard of 5.6 mg/L using the EP toxicity test. Because the
characteristic level for arsenic of 5.0 mg/L in the toxicity characteristic leachate procedure (TCLP)
extract is similar in magnitude to.the standard calculated from slag vitrification, the Agency believes
that it is valid to default to the characteristic level for the universal standard for arsenic.
.'••,' • /
\ , ' . • .
. Chromium: " . • ' . .
V
EPA evaluated waste characterization and treatment performance data for chromium for
several sources, including data on the performance to high-temperature metal recovery (HTMR) and
stabilization technologies for treatment chromium. EPA selected the stabilization data to develop the
. - • ,•"*'.»•»',"
universal standard for chromium because these data represent treatment of chromium in difficult to
treat wastes, including stripping liquids, plating and palletizing operation wastes, and cleanout wastes
2I21V236\appendU
A-9
-------
from plating tanks. The Agency believes that these data represent effluent values that can be routinely
achieved by industry. • '
• ), ' . . ' ' •''...
Table A-2 summarizes,the determination of the universal standard for chromium in
• ' *.''*' J
nonwastewater forms of wastes. The table includes the waste code, treatment performance data, and
\ • \
technology from which the universal standard was transferred. The universal standard for chromium
was determined to be 0,86 mg/L in the TCLP extract based upon the treatment standard developed'
form the stabilization treatment performance data.
A-10
-------
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-------
-------
Appendix B - . • _
Treatment Performance Data Base and
Methodology for Identifying Universal Treatment Standards
for Constituents in Wastewater Forms of
F032, F034, and F034 ;
-------
-------
TABLE OF CONTENTS
, • Page
B.I Methodology for Determining Wastewater BOAT Universal Treatment Standards . . ."B-l
B.I.I Identification of Best Demonstrated Technologies and Treatment
Performance Data .: . B-2
. . x B. 1.2 Variability Factors : .. . . ': ..--. . ...'.:.. : B-4
B. 1.3 " Treatment Standard Calculation .'.......:,. •...'..'.'........... B-5
B.2 Determination of Treatment Standards for Wastewater Forms of F032r F034. and FQ35
(Phenols. PAHs. Dioxins and Furans. and Nfeitajs) ' B-5
,B.2.1 Phenols.... ,. .. . " ,.../: .... Br5
'. B.2.2 PAHs , . : '. . .:..;: .. :...'.....'...:.............'.... . . . B-8
B.2.3 Dioxins and Furans ; , - - - B-I2
' B.2r4 Metals ,.,...:. .,.-.-...;....'...,..•.... "B-14
-------
-------
LIST OF TABLES
• ' - Page
B-l Determination of-Univeral Treatment Standards for Organic and Metal
Constituents (Wastewater) . . . :. , . B-16 ,
B-2 Key to Data Sources for Wastewaters ' B-l 8
B-3 Key to Treatment Technologies '.....' B-19
B-4 Treatment Performance Data for Phenol in Wastewaters B-23
B-5 Treatment Performance Data for 2,4rDimethylphenol in Wastewaters .......... B-26
B-6 Treatment Performance Data for 2,4,6-Trichloropheriol in Wastewaters ......... B-27
B-7 . Treatment Performance Data for 2,3,4,6-Tetrachlorophenol in Wastewaters B-28
Br8 Treatment Performance Data for Pentachlorophenol in.Wastewaters . . B-29
B-9 Treatment Performance Data for Acenaphthene in Wastewaters B-32
B-10 Treatment Performance Data for Anthracene in Wastewaters B-3 3
B-11 Treatment Performance Data for Benz(a)anthracene in Wastewaters Br34
B-I2 Treatment Performance Data for Benzo(a)pyrene in Wastewaters B-3 5
B-l3 Treatment Performance Data for Benzo(b)fluoranthene in Wastewafers B-36
B-l4 Treatment Performance Data for Benzo(k)fluoranthene ini Wastewaters . . B-37
B-l5 Treatment Performance Data for Chrysene in Wastewaters B-38
B-16 Treatment Performance Data for Dibenz(a,h)anthracene in Wastewaters B-39
B-l7 Treatment Performance Data for Fluorene in Wastewaters , . B-40
B-18 Treatment Performance Data for Indeno(l,2,3-cd)pyrene Wastewaters . B-41
B-19 Treatment Performance Data for Naphthalene in Wastewaters ..... B-42.
. B-20 Treatment Performance Data for Phenanthrene in Wastewaters B-44
B-21 Treatment Performance Data for Pyrene in Wastewaters ,<................ 1 . B-45
B-22 Treatment Performance Data for Tetrachlorodibenzo-p-dioxins in
Wastewaters •....-..'... . :. . .'..- ..' :.. ..,.•;.. B-47
B-23 Treatment Performance Data for Pentachlorodibenzo-p-dioxins in
Wastewaters ... .V ...,.......:. B-48
B-24 " Treatment Performance Data for Hexachlorodibenzo-p-dioxins in
' Wastewaters .... ......'...:.... ' B-49
B-25 Treatment Performance Data for Tetrachlorodibenzofurans in Wastewaters .. . B-50
B-26 Treatment Performance Data for Pentachlorodibenzofiirans in Wastewaters ..... B-51
B-27 Treatment Performance Data for Hexachlorodibenzofurans in Wastewaters .... B-52
B-28 Treatment Performance Data for Arsenic in Wastewaters •. B-54
B-29 Treatment Performance Data for Chromium (Total) in Wastewaters : . ... B-55
B-30 Variability Factor Calculation for Base/NeutralExtractableSemivolatile
Organic Constituents .........,;... ., *....:......... '. B-58
B-31 Proposed BOAT Standards for F032, F034, and F03 5 (Wastewaters and
Nonwastewaters) '. • - - • B-59
-------
. EPA is promulgating universal -treatment standards to regulate specific hazardous constituents
in wastewater forms of F032; F034, and F035. This appendix presents the methodology for
establishing universal treatment standards for the constituents promulgated .for regulation in
'. ' ' '
wastewater forms of F032, F034, and F03 5 . Section 0. 1 presents the methodology for determining
the wastewater universal standards, Section B.2 presents a constituent-by-constituent discussion of
the determination of the universal standards for each regulated constituent. The data presented in this
Appendix are those that supported the development of univerai treatment standards. New data
submitted by industry during the public comment period for the Phase 4 proposed rule (60. FR 43654,
August 22, 1995) are presented in Appendix K and are discussed by the EPA in the document entitled
Treatabiliiy of Dioxin/Furan in F032 Wastewater.
B. 1 Methodology for Determining Wastewater BOAT Universal Treatment
the promulgated universal standards for regulated constituents in wastewater forms of F032,
F034, and F035 are based on treatment performance data from several sources, including the Best
Demonstrated Available Treatment (BOAT) performance data, the National Pollutant Discharge
. Elimination System (NPDES) data, the Water Engineering Research Laboratory (WERL).data, EPA-
coliected Wet Air Oxidation/Powdered Activated Carbon (WAO/PACT®) data, the Engmeeririg and
Analysis Division (EAD) data, industry-submitted leachate treatment performance data, data in
literature that were not already part of the WERL data, and data in literature submitted by industry
on the WAD and PACT® treatment process. This appendix presents the wastewater treatment
v / • " '
performance data and discusses use of the data to determine BDAT and to calculate the universal
treatment standards for the constituents proposed for regulation in wastewater forms of F032, F034,
andF035. Table B-l presents a summary of the data used. .
Table B-2 and Table B-3 are data source and treatment technology keys, respectively, for the
^t '
data tables presented in this appendix. Tables B-4 through B-29 in this appendix present the available.
wastewater treatment performance data for each constituent- regulated in F032, F.034, and F03 5 . The
212l\236\«ppead«
-------
data used to determine the universal treatment standards are indicated with a footnote. A discussion
. of the determination of the universal standards for each of the constituents regulated in F032. F034..
and F035 is presented in Section B.2. . • .
The'calculation of the universal treatment standards involved three steps. These were: (I)
identification of best demonstrated technologies and treatment performance data; (2) determination
of a variability factor specific to each constituent in a treatment performance data set to correct for
•'•.' . . -. -j
"normal variation in the performance of a particular technology, over time; and (3) calculation of the
, treatmentstandard, which is equal to the average effluent concentration multiplied by the variability.
factor. The universal standards and specific treatment performance data used to determine the-'
treatment standards for each regulated constituent in wastewater forms of F032, F034, and F035 are
» , -. . i
1 *
presented in Tables B-l and B-4 through B-29. : .
B.LI Identification of Best Demonstrated Technologies and Treatment Performance Data
To determine the best demonstrated technology for each BDAT List organic constituent, the
Agency examined the universal standards wastewater treatment performance data base., To determine
"best," a hierarchy was established to evaluate the wastewater treatment performance data. The
following outlines the methodology used to determine "best" for wastewater constituents that are
included in this document: " • : '
(1): For any prganics with EAD performance data and a promulgated HAD effluent
limitation, the EAD data were used to calc ilate the BOAT treatment standard for that
. constituent. The data representing EAD Option 1 were used in all cases (5).
.(2) For any constituent for which promulgated EAD standards (based on actual treatment
performance data) do not exist, data from an Agency-sponsored BDAT wastewater
treatment test were used to determine the BDAT treatment standard for that.
constituent (when it was available). •>• • . .
(3)
. • -3
For any constituent with industry-submitted leachate treatment performance data,
where the data showed substantial treatment and the data were considered better or
•• • .( ' , '. . -
2121\136\appendix •'«. • •. . B-2
-------
more representative of treatment perfqrmance'than Agency data, the Agency used the
" industry-submitted leachate data to calculate the BOAT concentration-based standard. •
(4) For any constituent without EAD data, BDAT wastewater treatment test data, or.
industry-submitted leachate treatment performance data showing substantial
treatment,' other available treatment performance data were evaluated to determine
BOAT and were used to calculate the BOAT concentration-base'd standard.
Considered in this evaluation were the treatment technology for which data were
available, whether the data represented a full-, pilot-, or bench-scale technology, the
. concentration of the constituent of interest in the influent to treatment, the average
concentration of the constituent of interest in the effluent from treatment, and the
removal efficiency of the treatment technology. Full-scale treatment data with an
influent concentration range greater than 100 ppb were preferred over pilot- or bench-
. scale data and preferred over data with a low (i.e., 0-100 ppb) influent concentration
range. If several sets of data met these criteria (i.e., full-scale available technologies
with high influent concentrations), they were.compared by examination of their
average effluent values and percent removals to determine the data set(s) which had
the lowest effluent values and the technology with the highest percent removal.
(5) For any constituent where treatment performance data were not available from any
of the examined sources, data were transferred for calculation of a BDAT treatment
standard from a similar constituent in a waste judged to be similar.
Details regarding the development of BDAT for the constituents proposed for regulation in
the wastewater forms of. F032, F034, and F035 are presented in the EPA's Proposed Best
* • , . ' ' r»
Demonstrated Available Technology (BDAT^ Background Document for Universal Standards.
* . ./ 'i
•Volume B: Univgrsjil Standards for Wastewater Forms of Listed. Hfl?ardous Wastes (5).
For most constituents proposed for regulation in F032, F034, and F035, the Agency ha<1
treatment performance data from the EAD (formerly. FTD) data base, the Agency believes that these
data represent the best demonstrated treatment performance for the following reasons:
EAD data are comprised of treatment performance data from Organic Chemical
Plastics and Synthetic Fiber (OCPSF) sampling episodes. These episodes included
long-term sampling episodes of several industries. The data are, therefore, a good
reflection of the treatment of organics in industrial wastewaters.
2!2U236\appendU
B-3
-------
. EAD data" were carefully screened prior to inclusion in the OCPSF data base and were
used in determining an EAJD promulgated limit ,
A promulgated EAD limit represents data that have undergone both EPA and industry
review and acceptance. • . : ' ' •
B.I.2 Variability Factors , '
A variability factor accounts for the variability inherent in the treatment system performance,
''treatment residual collection, and analysis of the treated waste samples. Variability factors are
calculated as described in EPA's Methodology for Developing BOAT Treatment Standards (7). :
Due to the nature of the data gathered from various data sources presented in this appendix,
variability factors for most of the constituents proposed for regulation in JF032, F034, and F035 are
.not calculated as described in Reference 7. In many cases, original effluent points were not available.
The variability factor calculated during the EAD regulation.effort was used for those
constituents for which a treatment standard was based on an EAD effluent limitation (i.e., selected
volatile and semivolatile organic constituents). •-..•••'
- For constituents where a variability factor was unknown or could not be calculated, an
average variability factor was used. The average variability factors were generated from the EAD
variability factors and are specific to the'type of constituent under consideration (i.e., volatile organic
•or semivolatile organic). The average variability factor for semivolatile organics is the average of the
variability factors shown in Table B-l. Determination of these average variability factors is similar
to the procedure used by EPA in previous BOAT rulemakings to determine average accuracy
correction factors. - ' ,
2i2l\236\ap|«a
-------
For all constituents proposed for regulation in F032, F034, and F035, an EAD variability
factor was used in the determination of the treatment standard. In these cases, an accuracy correction
factor was not used because it would lead to'over-correcting the data.
B.l.3 Treatment Standard. Calculation ' ,•'•••
A constituent-by-constituent discussion of the determination of the universal treatment
standards for wastewaters is presented in Section B.2. ,
B.2 Determination of Treatment Standards for Wastewater Forms of F032T F034T and F035
(Phenols. PAHs. Diokins and Furans. and Metals^
Wastewater treatment performance data for the constituents regulated in F032, F034, and
'i . • .
F03S are presented in Tables B-4 through B-29. A constituent-by-constituent discussion of the data
used to calculate the universal treatment standards for each constituent regulated in wastewater forms
ofF032, F034, and F035 is given below. » . ''•'"..
B.2.1 Phenols
Phenol!
BDAT for phenol is biological treatment (BT). Biological treatment was selected as BOAT
for two reasons: (1) the industry-submitted leachate data for BT showed substantial treatment of
phenol and (2) the Agency believes that these data are representative of effluent values that can be
' ' '*''•{ \. '
routinely achieved by industry. The effluent concentration value reported for phenol in the industry-,
submitted leachate data is supported by the effluent concentration data from the EAD data base..
212U236\appendU .' . . .' B~5
-------
The universal standard for phenol was calculated using an effluent concentration of 10 u
and the appropriate .variability factor and accuracy correction factor. The calculation of the resulting
universal standard for phenoi in wastewaters is 0.039 mg/L (Table B-l).
2.4-Dimethylphenol: , , .
BOAT for 2,4-dimethylphenol is biological treatment (BT). The universal standard was.
calculated using the EAD median long-term average of 10.794 /zg/L and the HAD Option 1 variability
factor. The calculation ofthe resulting universal standard for 2,4-dimethylphenol in wastewaters is
0.036 mg/L (Table B-l). . . , , .
. 2.4.6-Trichlorophenol: '•''•-...
. . • , •• • . r ..
. ' '«'•'.
BOAT for 2,4,6-trichlorophenol is biological treatment (BT). Biological treatment was
\ ' ' - • . •
selected as BOAT for two reasons: (1) the industry-submitted leachate data for biological treatment
showed substantial treatment of 2,4,6-trichlorophenoi and (2) the Agency believes that these data are
representative of effluent values that can be routinely achieved by industry.
The universal standard for 2,4,6-trichlorophenol was calculated using an effluent
concentration of 10 ^g/L and the appropriate variability factor and accuracy correction factor! The
calculation ofthe resulting universal standard for 2,4,6-trichlorophenol in wastewaters is 0.035 mg/L
•(Table B-l). . , ; :
2.3.4.6-Tetrachlorophenol: , .
- , . (
. BOAT for 2,3,4,6-tetrachlorophenol is biological treatment (BT). Biological treatment
technologies include trickling filter systems (TF) and activated sludge biological treatment (AS).
212l\236\appendU •" . ^ , ' ' B~6
-------
• I .
' The universal standard for 2,3,4,6-tetrachlorophenol was calculated using its detection limit
of 6.8./ug/L and the appropriate variability factor and accuracy correction factor. The Agency used
the method detection limit because the effluent concentration of 2,3,4,6-tetrachlorophenol was below
the detection'level routinely achievable using EPA-approved methods. The calculation of the
\ '
resulting universal standard for 2,3,4,6-tetrachlorophenol in wastewaters is 0.030 mg/L (Table B-1).
• Pentachloropheno\' . • • •
BDAT for pentachlorophenol is filtration followed by granular activated carbon (Fil+GAC).
Fil+GAC was selected as BDAT because this technology represents treatment performance data with
a high influent concentration and a high removal efficiency. The effluent concentration achievable
by Fil+GAC is supported by the effluent concentration data from the biological treatment
technologies. . •
The universal standard for pentachlorophenol was calculated using an effluent concentration
of 20 /jtg/L and the appropriate variability factor and accuracy correction factor. The calculation of
the resulting universal standard for pentachlorophenol wastewaters is 0.089 mg/L (Table B-l).
"R 7
**"'
-------
B.2.2 PAHs / ,
" Acenaphthcng! / x - -
• • • •' . ' ' j - •
BOAT for acenaphthene is biological treatment (BT). The universal standard was calculated
* f ' ' - ' '
using.the EAD median long-term average of 10 ^g/L and the HAD Option 1 variability factor. The
•calculation of the.resulting universal standard for acenaphthene in wastewaters is 0.059 mg/L (Table
B-l): - . • ' -•'•'. •-.'•'• ;
Anthracene:
BOAT for anthracene is biological treatment (BT). The universal standard was calculated
using the EAD median long-term average of 10 Mg/L and the EAD Option"1 variability factor. The '
calculation of the resulting universal standard for anthracene in wastewaters is 0.059 mg/L (Table B-
.1). ''••••-._••'••''... '; . - '• -
Benz(a)anthracene:
BOAT for benz(a)anthracene was identified as biological treatment (BT). Biological
treatment was selected as BDAT because it represents treatment performance data from the EAD
data base. The BDAT treatment standard was calculated using the EAD median long-term average
of 10 ppb and the EAD variability factor for benz(a)anthracene. The determination of the resulting
BDAT treatment standard for benz(a)anthracene is .0.059 mg/L (Table B-l)v - ; ", -
B'8
-------
1 Benzo(a)pyreijg: • ,. ".
BOAT for benzo(a)pyrene was identified as biological treatment (BT). The biological
treatment was selected as BOAT because it represents treatment performance data from the EAD
data base. BOAT treatment standard was calculated using the EAD median long-term average of
10.3 ppb and the EAD variability factor for benzo(a)pyrene. The determination of the resulting ,
BOAT treatment standard for benzo(a)pyrene is 0.061 mg/L (Table B-l). . '
n*
*• I ' \
BenzoCbVfluoranthene and Benzofkifluoranthene: . '
* • - , - ' • '
The Agency's existing UTS limits for benzo(b)fluoranthene and benzo(k)fluoranthene were
promulgated as the sum of these two constituents in coking wastes, because, these two .constituents
may not be accurately quantified separately in wastewater forms of wastes. EPA proposed to adopt
; • __ ,
for benzo(k)fluoranthene in F032 and F034 the same UTS limit EPA is promulgating the treatment
*"• , ~ i *.
standard for the sum of benzo(b)fluoranthene and benzo(k)fluoranthene.
. BOAT for benzo(b)fluoranthene was identified as activated sludge biological treatment (AS).
Activated sludge was selected as BOAT because it represents full-scale data with a high influent
concentration range and a high removal efficiency. The concentration limit for benzo(b)fluoranthene
(O.OSS mg/L) was calculated using the effluent concentration of 10 ppb and the average of the EAD
variability factors for semivolatile constituents. BOAT for benzo(k)fluoranthene was identified as
. . ' • _/ .- • / _
BT. BT was selected as BDAT because it represents treatment performance data from the EAD data
base. The concentration limit for benzo(k)fluoranthene'(0.059 mg/L) was calculated using the EAD
' median long-term average of 10 ppb and the EAD variability factor for benzo(k)fluoranthene.
i ' .
, * * • - • • J
The treatment "standard promulgated for benzo(b)fluoranthene is the sum of
, i
benzb(b)fluoranthene and benzo(k)fluorarithene which was calculated as 0.11 mg/L '(based upon the
\ ' • •' •-'
2121\236\appcnd«
-------
sum of the individually-determined concentration limits for these constituents, and is shown in Table
Chrysene: ' , . ,
' '• - i " f ~ j - ' .
BDAT for chrysene was identified as biological treatment (BT)! BT was selected as BOAT
because it represents treatment performance data from .the HAD data base. The BOAT treatment
standard was calculated using the EAD median long-term average of 10 ppb and the EAD variability
factor for chrysene. the determination of the resulting BDAT treatment standard for chrysene is
0.059 mg/L (table -B-l.) • ^ '. •- ^ , .
. ' •. , .-' ' ' • f _
Dibenzfa.hlanthracene: . • . . . .
BOAT for dibenz(a,h)anthracene was identified as chemically-assisted clarification (CAC).
C AC was selected as BDAT because it represents a demonstrated technology with high influent
concentrations and a high removal efficiency. The BDAT treatment standard for
c ' '
dibenz(a,h)anthracene was calculated using an effluent concentration of 10 ppb and the average of
the EAD variability factors for semivolatile constituents. The determination of the resulting BDAT
treatment standard for dibenz(a,h)anthracene is 0.055 mg/L (Table B-l).
Fiuorene: , . . -
BDAT for fluorene is biological treatment (BT). The universal standard was calculated using
the EAD median long-term average of -10 Mg/L and the EAD Option 1 variability factor. The
calculation of the resulting universal standard for fluorene in wastewaters (0.059 mg/L) is shown in
Table B-l. . • - . " ' '• ., : , • ,
212U236\appendU , B-10
-------
Indenof 1.2.3-cd)pyrene: • ^ * •
s , ' . -
BOAT for indeno(l,2,3-cd)pyrene was identified as activated sludge biological treatment
(AS). Activated sludge was selected as BOAT because it represents full-scale treatment performance
with a high removal efficiency. The BDAT treatment standard for indenp(l,2,3-cd)pyrene was,
calculated using an effluent concentration of 1 ppb (which represents the detection limit for
indeno(l,2;3-cd)pyrene and the average of the HAD variability factors for semivolatile constituents.
The determination of the resulting BOAT treatment standard for indeno(l,2,3-cd) pyrehe (0:0055
mg/L) is shown in Table B-l.
1 • . e
Naphthalene: ' r
BDAT for naphthalene was identified as biological treatment (BT). Biological treatment was
selected as BDAT because it represents treatment performance data from the EAD data base. The
BDAT treatment standard was calculated using the EAD median long-term average of 10.0 ppb and
the EAD variability factor for naphthalene. The determination of the resulting BDAT treatment
standard for naphthalene (0.059 mg/L) is shown in Table B-l. r ;
Phenanthrene:
BDAT for phenanthrene is biological treatment (BT). The universal standard was calculated
using the EAD median long-term average of 10 ^g/L and the EAD Option 1 variability factor. The
calculation of the resulting universal standard for phenanthrene in wastewaters is 0.059 mg/L (Table
212n236\appendix .. B-ll
-------
Pyrene:
BOAT for pyrene is biological treatment (BT). The universal standard was calculated using
the EAD median 'long-term average of 1 1.33 /^g/L and the HAD Option 1 variability factor. . The,
calculation of the resulting universal standard for pyrene in wastewaters is 0.0(57 mg/L (Table B-l )
B.2.3 Dioxins and Furans - s
r < v * '
, • • Tetrachlorodibenzo-p-dioxins: ' . • • ' •
r • . .
' ' • ' - .'•'•' >
BOAT for tetrachlorodibenzq-p-dioxins is biological treatment (BT). Biological treatment
was selected as BDAT for two reasons: (1) the industry-submitted leachate data showed substantial
treatment of tetrachlorodibenzo-p-dioxins by a demonstrated treatment technology arid (2) the
Agency believes that these data are representative of effluent values that can be routinely achieved .
by industry. ' ' . .
*• " ' l ' '
The universal standard for tetrachlorodibenzo-p-dioxins was calculated using an effluent •
concentration of 0.0045 /zg/L and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting universal standard for tetrachlorodibenzo-p-dioxins in wastewaters
is 0.000063 mg/L (Table B-l). ..',..
'< ' . • •
\ ' ! • ' ' •
Pentachlorodibenzo-p-dioxins: . -' . ' .
Treatment performance data, were .transferred to pentachlorodibenzo-p-dioxins from a
constituent judged to be similar with respect to elemental composition and functional groups. The
' ' " v -
Agency believes that the tetrachlorodibenzo-p-dioxins are the most appropriate constituents, from
which to transfer performance data to pemachlorodibenzorp-dioxins. The transfer of treatment-.
performance data from this constituent results in a BDAT for pentachlorodibenzo-p-dioxins of
• , . ' . J • • ' ,
B-12
-------
biological treatment (BT): The universal standard for pentachlorodibenzo-p-dioxins wastewaters is
0.000063 mg/L (Table B-1). , : " .
•.. Hexachlorodihenzo-p-dioxins: . . .
Treatment performance data were transferred to hexachlorodibenzo-p-dioxins from a
constituent judged to be similar with respect to elemental composition and functional groups. The
Agency believes that the, tetrachlorodibenzo-p-dioxins are the most appropriate constituents from •'
which to transfer performance data to hexachlorodibenzo-p-dioxins. The transfer of treatment '
performance data from these constituents results in a BOAT for hexachlorodibenzo-p-dioxins of
biological treatment (BT). The universal standard for hexachlorodibenzo-p-dioxins wastewaters is
0,000063 mg/L (Table B-1). •
Tetrac h lo rod ibenzo fu ra ns: • ' • '
Treatment performance data were transferred ,tb tetrachlorodibenzofurans from a constituent ,
judged to be similar with respect to elemental composition and functional groups. The Agency
believes that the tetrachlorodibenzo-p-dioxins are the most appropriate constituents from which to
transfer performance data to tetrachlorodibenzofurans. The transfer of treatment performance data
from these constituents results in a BOAT for tetrachlorodibenzofurans of biological treatment (BT).
The universal standard for tetrachlorodibenzofurans wastewaters is 0.000063 mg/L (Table B-1).
Pentachlorodibenzofurans:
BOAT for pentachlorodibenzofurans is biological treatment (BT). Biological treatment was
t
selected as BOAT for two reasons:. (1) the industry-submitted leachate data showed substantial
treatment of pentachlorodibenzofurans by a demonstrated treatment technology and (2) the Agency
2121\236Vappendi*
B-13
-------
believes, that these data are representative of effluent values that.can be routinely achieved by
industry. • . • .',-'.'
\
the universal standard for pentachlorodibenzofurans was calculated using an effluent
concentration of 0.0025 7/g/L (the average of the biological treatment, effluent concentrations) and
the appropriate variability factor and accuracy correction factor. The calculation of the resulting
universal standard for pentachlorodtbenzpfurans in wastewaters is 0.000035 mg/L (Table B-l).
." ' • ' \
Hexachlorodibenzofurans: * ^
'••'.' ' ' ' ', ' ' < ' '.
' ! . ' ' ' " '
Treatment performance data, were transferred to hexachlorodibenzofurans from a constituent
i v . • , . ,
judged to be similar with respect to elemental composition and functional groups. The Agency
believes that the tetrachlorodibenzo-p-dtoxins are the most appropriate constituents from which to
" \ '
transfer performance data to hexachlorodibenzofurans. The transfer of treatment performance data
from these constituents results in a BOAT for hexachJorodibenzofurans of biological treatment (BT).
,The universal standard for hexachlorodibenzofurans wastewaters is 0.000063 rhg/L (Table B-30).
B.2.4 Metals v
'" • '
. ' • . Arsenic: * . . • . ' ' .
BOAT for arsenic is lime conditioning followed by sedimentation and filtration (L+Sed+Fil).
Lime conditioning followed by sedimentation and filtration was selected as BOAT because this
treatment train represents treatment performance data from the EAD-CMDB that showed substantial
treatment of arsenic and a lower effluent concentration value'than the other HAD data. The Agency
preferred, the use of the EAD data base rather than other data sources because the EAD data base
represents a comprehensive source of wastewater treatment performance data with longer-term
sampling and a greater number of sample sets than other wast'ewater treatment data bases...
2t2n236\appendU • ' '. ' B-14
-------
The universal standard for arsenic was calculated using the EAD mean long-term average of
340 /ug/L and the EAD-CMDB variability factor. The calculation of the resulting universal standard
for arsenic in wastewaters is 1.4 mg/L (Table B-l). .
Chromium (Total);
BOAT for chromium (total) is chemical precipitation followed by sedimentation (ChPt+Sed).
Although lime conditioning followed by sedimentation and filtration (L+Sed+Fil), lime conditioning
followed by sedimentation (L+Sed), arid sedimentation followed by 'filtration (Sed+Fil) data were
available from the EAD-CMDB, the Agency believes that the chemical precipitation followed by
sedimentation data from the EAD-MF data base are representative of effluent values that can be
• • • , ' • .' v. • '
, routinely achieved by industry. • . - . ^
The universal standard for chromium (total) was calculated using the EAD mean effluent
concentration of 572-Mg/L and -the EAD-MF variability factor. The calculation of the resulting
universal standard for chromium (total) in wastewaters is 2.77 mg/L (Table B-l).
212l\236\»ppendix .
B-15
-------
- , Table B-l
Determination of Universal Treatment Standards for Qrganic Constituents (Wastewaters)
Constituent Selected
For Regulation
BDAT
Treatment
Technology
Source of
Treatment
Performance .Data
Average
Effluent
Concentration '
(rng/L)
Accuracy
Correction
Factor
. 'PHENOLS
Phenol
2,4-Dimethvlphenol
2,4,6-Trichloropheriol
2,3.4,6-TetrachlorophenoI
Pentachlorophenol
BT - ;
BT
BT
TF+AS
Fil+GAC
LEACHATE
EAD-OCPSF '
LEACHATE'
WERL
WERL'.
O.OIO
0.011
<0.010 .
<0.0068
6.020
' 1.4
•
1.3
.
..
Variability
, Factor
. Universal
Treatment
Standard
(mg/L)
2.8-
3.3 '
2.8 .
4.4
4.4 -
0.039 '
0.036
0.035
0.030
0.089
1 . -. • , ,. • • . ' '
POL YNUCLEAR AROMATIC HYDROCARBONS (PAHS)
Acenaphthene '
Anthracene .
Benz(a)anthracene
Benzo(a)pvrene
Benzoib)lluoranthene •
Benzo(k)fluoranthene
Sum of • ' • .
benzo(b)tluoranthene and
berizo(k)fluoranthene
Chrvsene
2,4-Dimethvlphenol
' Fluorehe •
Indeno(l,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pvrene
BT
BT
BT
BT
'AS
BT
--
BT '
BT
- BT
AS
BT
- ' BT
BT
EAD-OCPSF
EAD-OCPSF
EAD-OCPSF
EAD-OCPSF
WERL
EAD-OCPSF
•
EAD-OCPSF
EAD-OCPSF
EAD-OCPSF
WERL
EAD-OCPSF
-. EAD-OCPSF
EAD-OCPSF '
0.010
0.010
0.010
' 0.010
,'.0.010
+
' . . - '
0.010
0.011
b.oio
0.0010
0.010 "
o.o'io
0.011
^
''" - *
f
-
1
^
'-
_
_
s>
_
„
.
.
.5.9
5.9
5.9
5.9
5.5
5.9 '
.- ' f.
5.9
. 3.3 • -
5.9
•t
' 5.5
5.9 . x
5.9 '
5.9
0.059 '
0.059
0.059
0.061 •
0.55"
. 0.59" .
. 0.11-
0.059
0.036
0.059 '
0.0055 .
0.059
0 059- .
' 0.067
2l2U236\appendi*
B-16
-------
Constituent Selected
For Regulation
BOAT
Treatment
Technology
Source of
Treatment
Performance Data
Average
Effluent
Concentration
(me/L)
Accuracy
Correction
Factor
Variability
Factor
Universal
Treatment
Standard
(me/L) 1
DIOXINS AND FURANS 1
Tetrachlorodibenzo-p-
dioxins
Pentachlorddibenzo-p-
dioxins
Hexachlorodibenzo-p-
dioxins
Tetrachlorodibenzdfurans
PentacUorbdibenzofurahs
Hexachlorodibenzofurans
BT ..
BT
"BT
•'.. BT
. BT '
•• BT
' LEACHATE
Transferred from ;
Tetrachlorodiben
zo-p-dioxin
Transferred from
Tetrachlorodiben
zo-p-dioxin
Transferred from
Tetrachlorodiben
zo-p-dioxin
LEACHATE
Transferred from
Tetrachlorodiben
zo-p-dioxin
0.0000045
0,0000045
' 0.0000045
0.0000045
0.0000025
0.0000045
5.0
" 5.0,
5.0
5.0
5.0-
5.0
2.8
V
2.8
2.8
' ' 2.8
' -. 2.8
2.8
*
. 0.000063
0.000063
0.000063
0.000063
I
0.000035 1
0,000063
< - Indicated a detection limit value., ' -' -
'Benzo(b)fluoranthene and benzo(k)fluoranthene are regulated as a sum under universal standards.
Source: (5) ' ' ',' , . • . ' .
Determination of Universal Treatment Standards for Metal Constituents (Wastewaters)
Constituent
Selected
For Regulation
Arsenic
Chromium (total) -
BOAT
Treatment
. Technology
. L+Sed+Fil
ChPt+Sed
Source of
Treatment
Performance
Data :
EAD-CMDB
EAD-MF
Average
Effluent
Concentration
(mg/L)
0.34 '
0.57.
. Accuracy
Correction
Factor
_
. -
s
Variability
Factor
4.1
4.9 '-
Universal
Treatment
Standard
(mg^)
• H
1.4 '. '
' • 2.77
Source: (5) '
' 212U236\appendui
B-17
-------
' . - Table B-2
Key to Data Sources for Wastewaters
. Code
BOAT
WAO
EAD
OCPSF
CMDB
MF
NPDES
WERL
LEACHATE
CMA
TSCD
ART
WAO (LIT) '
1 '
Data Base
Best Demonstrated Available.Technology , -
EPA Wet Air Oxidation/P ACT® Test Data .
_ .'
Engineering and Analysis Division
Organic Chemicals, Plastics, and Synthetic Fibers (EAD) " .
\
Combined Metals Database (EAD) ,
Metal Finishing (EAD) .
National Pollutant Discharge Elimination System
Water Engineering Research Laboratory
Leachate Treatment Performance Data Submitted by Industry
Data Submitted in Comments to the Proposed Rule by the Chemical
Manufacturers Association's Carbon Disulfide Task Force
Data Submitted by the California TSCD
Data from Published Articles
Wet Air Oxidation/P ACT® Data in Literature Submitted by
Industry
Source: (5)
< * indicates * detection limit value. . •• •
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike. ' . '
Source: (4)
B-18
-------
Table B-3
Key to Treatment Technologies
Code
AAS
AC
AFF
AL
API
AS
• AirS
AnFF
I ,
, . AnL
BGAC
' BT ' .
•-. CA.
CAC
Chem/Cond.
. ChOx
ChOx/Pt
ChPt
Chred
CN/Ox
COAG
DAF
EC
Technology
Activated Alumina Sorption :
Activated Carbon
. Aerobic Fixed Film ' .
Aerobic Lagoons • ' . . • -
API Oil/Water Separator
Activated Sludge
Air- Stripping ~ • . .
Anaerobic Fixed Film ' ' . '
Anaerobic Lagoons
Biological Granular Activated Carbon
Biological Treatment
Carbon Adsorption
Chemically Assisted Clarification
Chemical Conditioning
Chemical Oxidation [parentheses indicate the
oxidation chemical, i.e., ChOx(ozone)]
Chemical Oxidation/Precipitation
Che/nical Precipitation ,
Chemical Reduction
Cyanide Oxidation
Coagulation , •
t • T
Dissolved Air Flotation
Electrochemical Treatment
< - indicates a detection limit value. '
•Performance'data consist of the concentration in treated • waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.
Source: (4)
B-19
-------
Table B-3 (continued) •-.
Code
Fil
FLOAT
GAC
. Gr/Rem
.'E
KPEG
L
LL
Neut
.PACT®
RBC
RO
SBR
SCOx
Sed
SExt
- ss
TF
UF
uv ' •'
WOx
Technology
Filtration
Flotation .
Granular Activated Carbon . . '
Grease/Oil Removal
Ion Exchange. s . . . .
Dechlorination Using Alkoxide
)
Lime
Liquid-Liquid Extraction .
Neutralization ...
Powdered Activated Carbon Addition to
Activated Sludge '"
Rotating Biological Contactor
Reverse Osmosis "
Sequential Batch Reactor .
Super Critical Oxidation ;
Sedimentation
Solvent Extraction
Steam Stripping . .
Trickling Filter . •
Ultrafiltraiion
Ultraviolet Radiation
Wet Air Oxidation
< -/indicates a detection limit value. . \
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
'This number represents a constituent-specific matrix spike. , .
Source: (4)
B-20
-------
Table B-3. (continued)
- _ • i ' '
Addition codes included in tables of respective constituents: • . ; '
l- +- - Indicates that the first process unit is followed in the process train by the second, i.e., AS + Fil - Activated
. . Sludge followed by Filtration. • - , •
"Jw +_",-• Indicates that the two units are used together, i.e., UFwPAC - Ultrafiltration using Powdered Activated
Carbon. • ' . : .
"_[B]" - Indicates batch instead of continuous flow. ,
Source: (5) ....;'
< - indicates a detection limit value. - -
'Performance data consist of the,concentration in, treated waste, accuracy correction factor, and variability factor.
"This number represents a constituent-specific matrix spike. • . , .
Source:'- (4)
B-21
-------
PHENOLS
-------
Table B-4 '
Treatment Performance Data
for Phenol in Wastewaters
. Technology
AL'
AL
AL
AL ' .
API-DAF-AS
AS •
.AS
.AS
AS
AS'
AS
AS
.AS
AS
.AS
.AS • '
.AS
.AS - '
AS
AS.
.AS
AS
.AS
.AS
AS.
AS
'.AS
.AS
AS .
Technology
Scale
Pilot
Pilot
Full .
Pilot
Full
Full " -
Full
Bench
Full
Full
Pilot
Full
Full
. Full
Full
Full
Full
Full -
Scnch
Pilot
• Full
•Full '
Full
Pilot
Full
Full
Full
Full
' Full
Facility
203 A
203A
6B
192D
1482D
IB
IB
202D
6B
IB
203A
201B
v IB
6B
IB
IB
97JB
IB
1054E
240A
"68
1122E.
6B
* 241B
6B
975B
6B
IB
IB
Detection
Limit
fce/l)
NR
NR
. NR'
"-NR
NR
NR
NR
•NR
NR ,
NR
NR
NR'
NR
NR .
NR
NR
•NR
NR
NR
NR
. NR
NR
NR
NR
NR
NR
NR
NR •
NR
Range of
Influent
Concentrations
(Mt/L) .
100-1000
100-1000
100-1000
100-1000
100-1000 \
100-1000
o-ioo
100000-1000000
100-1000
100-1000
100-1000
100-1000
100-1000
10000-100000
100-1000 \ •
0-100
1000-10000
100-1000
1 100000-1000000 .
o-ioo -
100-1000
10000-100000
100-1000
'100-1000 •
1000-10000
100-1000
100-1000
100-1000
0-100
No. of
Data
Points
11
11
3
NR
4
5
6
NR
39
5
11
.31
6 .
3
6
3
NR
5
NR
11
7
NR
3
4
10
NR
if
6
6
Average
Effluent
Concentration
foB/U '
84.000
. 18.000 .
11.000
10.000
85.000
2.000
26.000
0.010
10.000
8.000
14.000
20.000
1. 000
10.000
61.000
1.000
6.6000
1.000
0.2SO
10.000 ,
15.000
400." 000
120.000
8.000
21.000
20.000
10.000
1.000
1.000
Recovery
CM
NR
NR
NR
NR -
NR
NR
NR
NR
NR
' NR
NR
NR
NR
NR
NR
NR
NR .
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR'
Removal
("/«)
33
86
90.8
98.99
89.5
'98.6
63
99.99
96.4
97.2 -
89
92.6
99.89
99.94
92.4
96.4
99.87
99.33
99.88
. 90
98
95.2
97.9
97.2
99.64.
87
96.3
99.44
98.3 .'
Reference
WERL
WERL
WERL .
'WERL
WERL'
WERL
WERL
WERL .
WERL
WERL I
WERL
WERL ' I
WERL •
WERL
WERL-
' WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL ' I
WERL' '
WERL ' 1
• WERL
'WERL
WERL '
WERL 11
< - indicates * detection limit value. ' .- ' .
•Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor. '
This number represents a constituent-specific matrix spike. •
Source: (4)
B-23
-------
Table B-4 (continued)
•==
II Technology
I AS
.AS
AS .
' .AS
AS
AS
.AS
il AS''
LAS'
AS
AS-Fil
1 ASt-Fil '
AnFF
KAnFF v
I .AnFF
1 :AnFF
AnFF
.AnFF
.AnFF-
AnFFw CAC
CAC
ChOx
CKOx
ChOx i
G.AC
G.AC .
O.AC
BT*' . .
BT
1 LL
—•••IMIIWIIIW^— •••••»•••
Technology
Scale
' .: Full
Pilot •
Full-'
Full
Pilot
Pilot
Full .,
Bench
Full
Full
Full
Full
Pilot
Pilot
Bench
Pilot
Pilot
Bench
Pilot
Pilot5
Pilot
Bench
. Bencb s
Bench
Bench
Full
Full
,' Full
Full
Full
Facility
6B
' 226B
975 B
68
204A " -
192D
6B
1054E
'6B '
IB
6B' -
. 6B
231 A
231 A
•230 A
231A
231A
230A
235D
249D
• 203A
975B
975B
975B
1054E
24SB
237A
DOW
1293
Kt04
* ' . \
Detection
Limit
tug/l^
MR
MR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
/NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR '-•
10
10 .
30
Range of
Influent
Concentrations
Gie/L) '
100-1000
100000-1000000
1000-10000
.100000-1000000
100-1000
100-1000
. . 1000-10000
10000-100000
,100000-1000000
100-1000
10000.100000
100-1000
1000000
' 1000000
100000-1000000
. 100000-1000000
100000.1000000
-1000000
100000-1000000
1000000
100-1000
100-1000
100-1000
looo-idooo ,
100-1000
100-1000'
1000-10000"
715-2500
698564-978672
150000-300000
. .\o. of
Data
Points
3
6
NR
2
8
NR
4
NR
13 .
6 •
.3 .
15
NR
NR
NR
NR
NR
NR
NR
NR
11
NR .
NR '
NR
NR
i
i
•• 3
15
- 5
Average
Effluent .
Concentration
kijj/L)
10.000
/ -
' 500.000
l'fiO.000
10.000
14.000
-, 10.000
56.000
1000.000
10.000
25.000
13.000
10.000
!
700.000.
30.000
10.000
10.000
70.000
1000.000
240.000
50.000
99.000
16.000
2-000
12-000
10.000
10.000
5.000
: . 10.000
10.000
165000.000
Recovery
(%)
NR .
NR
NR
NR
NR
NR
NR
'. NR.
NR
NR
>NR
' ' NR '.
NR
NR
• NR
NR
NR
NR .
NR
NR
NR
NR
NR
NR
NR
-NR '
NR
NR
N'R.
21
Removal
(%)
98.6
99.95
." 95
99.99
94.6
98"99
96.9
95'
99 99
94.4
99.98
98
99.98-
99.99
98.97
99.99
99.98
99.95
99.86
99.99
21
93.3
98.3
99.37
99
. 92.6
9989
99.32
" N'R ' .
NR
Reference
WERL
WERL
VVF.RL
WERL -
WERL
' -WERL
~WERL
WERL
. WERL
WERL
WERL
^
WERL
WERL.
WERL
WERL
WERL
WERL
/
WERL
WERL
WERL
WERL
WERL
WERL
• WERL'
WERL
WERL ' •
WERL
LEACHATE'
EAD-OCPSF
FID AT '
< - indicates a detection limit value. ' ' " ' '
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike. • . •
Source: (4)
B-24
-------
v Table B-4 (continued)
Technology
LL
LL-SS
'LL-SS+AC
PACT®
PACT*
PACT*
PACT® '
RBC
'RBC
RO '
SBR i
SBR
SBR
SBRwPACT®
SExt
SS
TF
TF
TF ' -.
TF
wo*
- WO* [BJ
WOX[B]
WOX fB|
Technology
Scale
Full
Full
Full
Bench
Bench
Full
Bench
Pilot
Pilot •
Full
Pilot
Pilot '
Bench
Bench
Pilot
Pilot
Pilot
Full
Pilot
Full
Bench
' Bench'.
• Bench -
Bench
Facility
' K103
K103/
• KI04
K103/
K104-
190E
975B
6B
975B
603 E
192D
250B
1433D '
227D
, 64D
64D
1082E
I082E
203A
IB
240A
IB
Zunpro
• 10S4E
1101O
236A
Detection
Limit
(MB/L)
30
30
30
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
. NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
Ran^e of
- Influent
Concentrations
fef/L)
. 1500000-3000000
150000-3000000
UOOOO-3000000
,. loooo-iooooo
1000-10000
. 1000-10000
1000-10000
100000-1000000
100-1000
1000-10000
ioooo- 100000
100000-1000000*
100000-1000000
100000-1000000
^1000000
100000-1000000 •
100-1000
100-1000
0-100
0-100
10000000- '
100000-1000000
> 1000000
' HOOOOOO
Mo. of
Data
Points
^
5
4
NR
NR
3
NR .
NR
NR
NR
16
1
NR
NR
NR
NR
11
6
10
6
1
NR
NR
1
Average
Effluent
Concentration
(ME/L) '
84000.000
2400.000
60.000
1.800
2.000
30.000
' 8.000
1700.000
10.000
120^000 .
1000.000
1000.000 .
3000.000
1000.000
210000.000
160.000
64.000
47,000
8.000
, 1.000
20000.000
27000.000
3600.000
3000.000
Recovery
(V»)
21
21
21
NR
NR
NR
NR
NR
. . NR
NR .
. NR
NR '
/
NR
' NR
NR
NR
NR •
NR
NR
NR
NR
NR
' NR
. '.NR
Removal
(%)
NR
NR
NR '
9999
99.96
. 98.6 .
99.85
99.6
98:99
' 93.6
97.7
99.81
99.63
99.88
95.4
24
49
82 .
91.3
98.2
99.8
. 97.3
' 99.92
- 99.97
I
Reference
BOAT I
BOAT.
BOAT
WERL
WERL
WERL
WERL •
WERL
WERL
WERL
WERL
WERL -. 1
WERL A
WERL ^
WERL '
WERL
WERL
WERL '
WERL
WERL .
WAD (LIT)
WERL
WERL '
WERL |J
'Data used in developing universal standard
NR = Not reported
The influent concentration was reported as between this range.
Source: (5)
< - indicates a detection limit value.
'Performance data consist of-the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.
Source: (4)
B-25
-------
Table B-5
"Treatment Performance Data •
for 2,4-DimethyIphenol in .Wastewaters •
Technology
-AL
.AS : .,
AS
.AS
-AS
AS-Fil
AnFF
AnFFwGAC
Bf1 ,
RBC
RO
*»
TF
WO,
WOX+PACT
WOxfB|
Technology
, Scale
' Pilot
Full
Pilot
Full
1
Pilot
Full
Pilot
Pilot
Full -
Pilot
Full
Full
Bench
Pilot
Bench
Facility
1920
6B
192D .
6B
204A
6B
235D
249D
1293
I92D
2JOB
.IB
Zimpro
Zimpro
236A
Detection
Limit
0*g/L)
NR
NR
NR
NR '
NR
NR
NR
NR
10
NR
NR
NR
NR
33
NR
Range of
Influent
Concentrations
fes/tr
" 1 000-10000
100-1000
1000-10000
10000-100000
0-100
1000-10000 '
\
1000-10000
10000-100000
16216-73537
1000-10000
100-1000
• o-ioo
8220000
530000-790000
> 1000000
.NO. or
Data
Points'
NR
7
NR
14
g
\ 3
NR
NR
15
NR .
NR
2
1
3 '
. 1
Average'
Effluent
Concentration
(ns/L)
10.000
13.000
10.000 .
10.000
. 0.900
10.000 ,
0.400 .
0.050
10.000 .
' 10.000
16.000;
25.000
, • • . 100.000
75:330
820.000
Removal
(%)
99.81
98.1
- '99.81
99.97
99.06
99.9
99.99
99.93
NR
9981
• 98.4
.38
99'.99
NR
99.99
Reference
WERL
WERL
WERL . '
WERL
WERL
WERL
WERL
WERL
EAD-OCPSF*
WERL
WERL
WERL
WAO(LIT)
WAO
WERL
'Data used in developing universal standard.
NR = Not reported -
Source: (5) ' -
<-indicates « detection limit value. ' .
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike. ' .
' Source: (4)
B-26
-------
Table B-6 •'
Treatment Performance Data
for 2,4,6-Trichlorophenol'in Wastewaters
Technology
NR
•NR
NR
NR
NR
NR
NR
NR
NR .'
NR
NR ,
AS
AS
BT
BT
BT •
BT
BT
RO
Technology
Size
NR
NR
NR
NR
NR
NR- '
NR
NR
'NR
NR
NR
Full
Full
NR
- Full
Full
Full
Full
Pilot
Facility
PA0033367
PA0036650
AR0038512
PA0008231
LA0065501
AR0038512
CT0001341
M10000868
. PA0008231
LA0066214
NJ0005134
• 375E
. 375E
DOW
PA0026247
LA003824J
NY0026042
MI0022276
180 A
Detection
LUntt
Source: (4)
•B-27
-------
- ; Table B-7 . -
Treatment Performance Data
for 2,3,4,6-Tetrachlprophenol in Wastewaters
. Technology '
AS'
AS'
AS'
AS1
'TP
TP
Technology '
Size
.Full
Full-
Full
Full
. Full
Full •>
Facility.
375E
' 375E
375E
375E
. 375E -
• 375E
Detection
Limit
' (MB/L) .
MR
NR
NR .
NR
NR
, NR
Range of .
Influent
Concentrations
- (M8/L)
0-100
0-100
. 0-100
(MOO
0-100
0-100
No. of
Data
Points
7
7-
7 -
7 ,
• 7 -
7 '
Avenge
Effluent .
Concentration
C"«/L) .
0;060
0.210
0.180
0.110-
0.100
0.060
*
Removal
{%)
,62
',16
5
' 15
'28 -
45 ; ' .
Reference
WERL'
WERL1 -
, WERL'
. WERL' .
WERL'. .
..WERL'
'Data used in developing universal standard.
NR = Not'reported
Source: (5) ' ' •
'< - indicates a detection limit value. . ' .
•Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.
Source: (4)
B-28 -'
-------
' ' • Table B-8
Treatment Performance Data
for Pentachlorophenol in Wastewaters
. Technology
NR
NR
NR
NR '.
MR
NR
NR
NR
NR
NR
NR
NR.
NR
NR
NR
NR
NR
AL
AL
AL
AS
-AS
.AS •
.AS
AS
AS - .
AS
.AS
AS
!
Technology
Size
NR
NR
NR ,
NR
NR
NR
, NR
NR
NR ,
NR
NR
NR '
NR
NR
NR'
NR
NR
Pilot
Pilot
. Pilot
Bench
' Pilot -
Pilot
Full ..'
Bench
Bench
Bench
Full
Pilot
Facility
LA0066214
'TX0001201
*
OH0058874
MS0044580
TX0001201
MOO 1 03349 ,
MW0049786
NJ0050750
LA0065501
OH0004961
CT0003751
WI0025739
WY0032590
PA0026S31
WY0032390
CT0001341
NY0001210
203A
203A
192D
.1050E
192D
240A
673B
. 1691A
202D
' 960E v
37JE.. '
204A
Detection
Limit
(ME/L)
NR '
NR
NR
• NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
' NR
NR
NR
' NR
NR
NR
NR
NR
NR
Range of
Influent
- Concentratloiu
(we/Li
NR
NR
NR
NR "
NR
NR
NR
NR
NR
NR
-NR .
NR
NR
NR
'NR
NR '
' NR
0-100
0-100
100.1000 .
100-1000
100-1000 .
0-100
1000-10000
100-1000
1000-10000
loooo-iooooo .. i
0-100
0-100
No. of
Data
Points
15
9 '
5
1
59
14 .
40
5
6
1
1
1
34
29
1
24
1
11
11
NR
5
NR •
9
29
NR
' NR
1 4
.'a
7
g-
Average
\ Effluent
Concentration
(MS/L)
.10.000
29:400'
7624.000
'• 3.000
41.900
3.700
3.148
18.775
5.000'
16200.000
10.000
40.000
1. 000
. 23103.400
1.000
64.600
0.010
57.000
20.000
10.000
2.800
70.000
20,000
3600.000
1.000
170:000
5400.000
0.620 '
••<• ' 6.300
Removal
(%)
NR
NR
,NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
32
76'''
98
99.3
86
-60
57
99.66
97.9 '
74
15
17- '
Reference
NPDES '
NPDES
NPDES
NPDES
NPDES
NPDES
' NPDES
NPDES '.
.•NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
. 'WERL
WERL
WERL
WERL
< - indicates a detection limit value. '
•Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.•
••Source: '(4)
B-29
-------
Table B-8 (continued)
r
1! Technology .
•».
AS .
AS
AS .
.AS
.AS
.AS
BT
BT
1ST '
C.AC ' .
COAG-Ssd-'-B :
T-Fil
Fit
IFtl+GAC"
GAC
'
RBC
RO '
TF
TF :
TF
TF ' .
TF
ITF ' '
TF , •
WOx
WOx [B|
(
I
Technology
Size
Full
Pilot
. Bench
Full
Bench
Bench
Full
Full
. Full
Full
Pilot
Full
Pilot
Pilot
Pilot •
- Pilot
Pilot
Pilot
Full
Full
Full
Pilot
Full
- Full-.
Bench
Bench .•
\
'Facility
s 375E
203.A
1691A
375E
40D
1691A
375E
PA0008800
PA0026247
LA0038245
203A' '
MI0024023
673B
673B ,
-673B
, 192D
180A
. 240A
' '. 375 E
IB
IB
203A
375E
M00023264
Zunpro •
236A
Detection
Limit
(W!/L)
NR
N'R
N'R
NR
NR
NR
! NR
.' NR
NR
NR
NR
NR
• NR
NR
.NR
NR
NR
NR
NR
NR
NR
NR.
NR
NR
• NR .
' NR
Range of
Influent
Concentrations •
tez/U
0-100
o-soo
10000-100000
0-100
10000-100000 ~
1000-10000
, ' 0-100
NR
NR
. NR
0-100
' NR
1000-10000
100-1000
.' 1000-10000
100-1000
0-100
0-100
0-100
too-iobo .
0-100
o-too
0-100
NR .
' 5000000' :
-•ibobooo
. No. of
Data
Points
7"
It
NR
7
30
NR
7
- 6
25 '
41
11
18
28
• 9
28
NR
NR
10
7
6
6
, 11 •
7
'10
1 .
1
Average
Effluent
Concentration
(ne/L) '
0.650
• ' 3.000
2.000
0.190
68.000
' 2.000
'. 0.410
585.200
28.600
44.624 .
50.000
20.444
3400.000
20.000
30.000
90.000
0.100
25,000
0.430
220.000
14.000 ..
82.000 '
, 0.500
1.MOO
135000.000
6000.000
Removal
(%)
14
- ' 96.4
99.98 .
63 .
99.66
99.94
39
.NR .
NR
- NR
40
NR
6
95.6
99.12
82
86 • .
39
6
35. .
69 ..
2 ' .
33
NR
97.3 .
99.88
Reference
\VERL
WERL '
WERL ' '
WERL
- WERL -
WERL
WERL
NPDES
NPDES
VPDES
WERL '
NPDES
WERL
WERL*
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL'
WERL
N'PDES
WAO(LIT)
WERL
' 'Data used in developing universal standard
NR'= Not reported '
Source: (5) .• .
< - indicates a detection limit value. "
"Performance data consist of (he concentration in treated waste, accuracy correction factor, and variability factor.
'This number represents a constituent-specific matrix spike. . . • ',
Source: (4)
B-30
-------
PAHs
-------
Table B-9
Treatment Performance Data
for Acenaphthene in Wastewaters
- Technology
AS
AS
.AS
AS
AS .
AS+Fil
CAC
Fil
'BT
PACT
TF " •
WO, '
WCMBI ' •
Technology
Scale '
Full
Pilot
' Full
Full
Full
Full '
Pilot
Full
Full
Bench
Full
Bench
Bench .
Facility
975B
. 204A .
6B
201 B
. 6B '
6B
195B
792E
1293
97iB
\B
Zimpro
236A
Detection
Limit
(A
-------
. Table B-10 .
Treatment Performance Data
for Anthracene in'Wastewaters
Techrtotoey
.AS
.AS
.AS .
AS^Fil
Fil
i •
BT
TF
.
Technology
Scale
Full
• Full
Pilot
Full.
Full
. Full
Full
Facility
6B
IB
204A
6B
. 792E
1293
IB
. Detection
Limit
' (M«/L)
NR
NR
. NR
NR
. NR '
10
NR
Range of
Influent
Concentrations
tez/L)
1004000
0-100
0400
100040000
0400
418-943 '
' 1004000
No. of
Date
Points
, 14
4 '
8 •
,
3
3
15
6
Average
Effluent
Concentration
tee/I)
10.000 . ;
13.000
6.900
10.000
1.000
10.000
17.000
Removal .
(%).
96.6
82
97.4
99.52
. 97.2
NR
92.3 '
*
- Reference
WERL
WERL
WERL
WERL
• WERL .
EAD-OCPSF1
WERL
'Data used in developing universal standard.
NR = Not reported
Source: (5)
< - indicates a detection limit value.
'Perfornwnce.daia consist of the concentration in treated waste, accuracy correction factor, and variability factor.
• This number represents a constituent-specific matrix spike.
Source: (4)
B-33
-------
Table B-ll
Treatment Performance Data
for Benz(a)ahthracene in Wastewaters
•
Technology .
AS~Fil
Fil
JQT*
Technology
Scale
. Full
Pilot '
Full
Full- •
Full
Full
Facilitv
201B
' 204A
68
6B
792E
1293
• >
Detection -
Limit
(MS/U
NR .
NR
NR
NR
.NR
to
Range of
Influent '
Concentrations
(wrt,)'.
• o-ioo
0-100
loo- 1000
' 1000-10000
1000-10000
10-614
•
NO. or
Data
~ Points
-1
8
12
3
4. '
15
i Average
Effluent •
Concentration
(ue/L)
1.000
0.600
10.000
56.000
3.000 .
10.000
1
Removal
(%)
/• 98.3
. 975
9?1
96.5
99.75
NR
Reference
WERL
WERL
WERL
- WERL
WERL
EAD' •
'Data used in developing univenal standard.
NR « Not reported
Source: (5)
< - indicate! a detection limit value. . •
"Performance data consist of the concentration in treated waste, accuracy correction factor,-and variability factor.
This number represent* a constituent-specific matrix spike. .. ' ^ .
Source: (4)
B-34
-------
Table B-12
Treatment Performance Data for Benzo(a)pyrene in Wastewaters
Technology
AS
AS
•AS
AS
AS
CAC
ChOx(ozone)
Fil
Fil
. GAC -
BP
Sed
TF
TF . ,
TF
Technology
Scale
Full
1
Full
Full
Full
Full
Pilot
Bench
Full
Pilot
. Pilot
Full
Bench '
Full
Full
Full ^
Facility
375E -
• 375E
1 375E'
375 E
6B
195B
1S3D
792E
195D.
. 195D
1293
153D
126E
375E
375E
Detection
Limit
' (MB/L)
MR
NR
NR .
• NR •
NR
NR
NR
NR
NR
NR
10
NR '
NR
NR .
NR
Range of
Influent
Concentrations
(ME/L>
0-100
o-ioo
0-100
O-IOO
100-1000
1000-10000
0-100
100-1000 •
, 0-100
1000-10000 •
10-t26
0-100
, 0-100
0-100
0-100
No. of
Date
Points
?'•
7
7 '
.. ' 7
10
8
NR
4
8
8
15
NR
NR
7
7
Average
Effluent
Concentra-
tion (MI/L)
0.027
0.028
0.016
0.021
. 10.000
20.000
1.000
1.000
10.000
20:000
. io.3oa
4.200
0.120'
0.016
0.035
Removal
(*/•)
86
88
97.4
86
95.2
98.2
76
- 99.81
50
98.2 .
NR
37
25
93.6
89
Reference
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL ,
WERL
EAD'
WERL
,WERL
'WERL
WERL
'Data used in developing proposed treatment standard
NR = Not repotted
. ' Source: (5) •
< - indicates a detection limit value. • • '
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
'This number represents a constituent-specific matrix spike. . • .
Source: (4)
B-35
-------
Table B-13^'
treatment Performance Data for Benzo(b)fluoranthene
"in Wastewaters
II Technology
1 NR
NR '
I NR
1 NR
NR
NR
II NR-
1 NR ' '
1 NR '
(I NR
1 AS' '
I .AS
1 AS
U ":
.AS
• BT
BT
RO
TF
Technology
Size
NR
NR
NR
NR
NR
NR
NR
NR
. NR
NR
Full ' .
Full
Full
Full
Full
' Full'
Full"
Pilot
Full
Full
Facility.
LA0066214
MD0000345
NY0000281
NY0000281
IL0001627
MD000034S
KY0003603
KY0003SI4
WV0004740
LA0065501
'6B
375E
375 E
' 375E
375 E . -.
LA0038245
KY0002119
1634E '
375E
375 £
Detection
Limit
(ne/L) >.
NR •
NR
NR
NR
NR
NR
NR
NR
. NR
NR
NR
NR
NR
NR
NR
NR ,
NR
- NR
NR
NR
Range of
Influent
Concentrations
(we/U
NR
NR
' NR
NR
NR
NR
•'NR
NR'
NR
NR
100-1000 '
0-100 .
0-100
0-100
.0-100
NR
0-100
0-100
0-100
"No. of
Data
Points
. 15
. 1
1
9-
9
I
I
I
' : l'
6
. 10
. 7
7 '
' 7
. 7
, 38
1
NR
• > 7
7
Average
Effluent
' Concentration
(MZ/L)
10.000
10.000
5.000
4.844
lo.iif
10.000
10.000
10.000
10.000
10.000 -
. • 10.000
0.023 •
'0.014
0.023
0.017.
' 10.126
10.000
0.001
0.033
0.017
Recover;
C%)
NR
NR
-. N'R
. NR
. NR . .
NR
NR
NR /
NR
'NR.
• NR
NR .
NR
NR
NR
NR
NR
NR
. NR
NR
Removal
("/«)
. NR .
NR
NR
NR
NR
NR
NR
NR-
NR
NR
95.4
: 88
97.8
89.6
89
NR
NR
92.1
. 89.7 •
' 93.2
Reference
NPDES
- NPDES
XPDES
NPDES'
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES >
WERL1 .
WERL
WERL
WERL
WERL
NPDES
S'PDES
. WERL
WERL '.
- WERL
'Data used in developing proposed treatment standard
NR = Not reported . -
Source: (5) . • • •
< - indicates a' detection limit value. ' • . .
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike. >
Source: (4)
B-36
-------
. • • ' Table B-14
Treatment Performance data for Benzo(k)fluoranthene
in Wastewaters
Technology
.AS •
AS
AS
AS
BT
RO
TF
TF
Technology
Size-
Full
Full
Full
Full
Full
Pilot
Full
Full
Facility
6B
375E
375E
375E '
1293 '
1634E
375E •
' 375E
Detection
Limit
, Og/L)
* N'R
NR
NR
NR
10
NR .
NR
NR
Range of
Influent
Concentrations
(M8/L)
100-1000
0-100
0-100
0-100
10-352
0-100
0-100
0-100 .
No. of
Data
Points
10
7
7
7
15
NR
' 7.
7
Average .
Effluent
Concentration
• (ue/L)
10.000
' 0.012.
0.010
0.013
10.000
0.00 1
0.015
0.014
Recovery
<%)
NR
NR
NR
NR
NR
NR:.
NR
NR
Removal
{%>
94.7 .
89
96.6
89
NR
94
90.6
90
Reference
WERL •
WERL
WERL
WERL
• EAD';
. WERL '
WERL
WERL
'Data used in developing proposed treatment standard
NR = Not reported - . ,
Source: (5)
< - indicates a detection1 limit value. . '
•Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.
Source: (4)
B-37
-------
Table B-15
.Treatment Performance Data for Chrysene
in Wastewaters
Technology
i
.AS
.AS
AS
AS'Fil .
Fil
sr
Technology
Size
: Pilot •
Full
Full ''
Full
Full"
Full
Facility
204A
68
68
. 6B
792E
. 1293
Detection
Limit
Cug/L)
NR
NR
NR
NR
NR
10
Range of
Influent .
Concentrations
(MC/L)
0-100
100-1000
100-1000
1000-10000
100-1000
10-67
No. of
Data
Points
- 8
4 .
' 11
3
4
• is'
Average
Effluent
Concentration
(ME/L)
1.200'
10.000
10.000
10.000
. i.boo
10.000
Recovery
(%)
NR
"- NR
- NR
-NR
NR
NR
Removal
• (%)
, 96.9
99
96.8
99.09
99.76
Reference
WERL
WERL
WERL'
WERL
- WERL
E.AD'
'Data used in developing proposed treatment standard
NR = Not reported •
Source: (5) ,
< - indicates a detection limit value. - '
/ 'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
'This number represents a constituent-specific matrix spike. ,
Source: (4)
B-38
-------
Table B-16
Treatment Performance Data for Dibenz(a,h)anthracene
in Wastewaters
\
Technology
NR
NR
BT
CAC'
Technology
Size
. NR
NR
Full
Pilot
Faculty
LA0066214
LA0065501
LA0038245
1958
Detection
Limit
NR
NR
NR
NR ..
• Range of
Influent
Concentrations
NR
NR
NR
100-1000
No. of
Data
Points
U
6
38
8
Average -,
Effluent .
Concentration
(Mt/L)
10.000
10.000
' ' 10.066
10.000
Recovery
' NR
.NR
NR
NR
Removal
NR
NR
NR
92.8
Reference
N'PDES
NPDES
NPDES
WERL« .
'Data used in developing proposed treatment standard
NR = Not reported . . .
Source: (5) ' • " .-
< - indicates a detection limit value. •
•Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
'This number represents a constituent-specific matrix spike.
Source: (4)
B-39
-------
, - Table B-17
Treatment Performance Data fpr(Fluorene in-Wastewater's
Technology
AL .
AS
AS
BT'
TF
v
Technology
Scale •
Full
Full •
Pilot ••
' Full
Full
FacUitv
6B -
6B
204A
1293
IB
Detectioo
. , Limit
. (MS/L)
." MR
NR .
NR
10
• NR'
Range or
Influent '
Concentrations
(W!/L)
100-1000 '
1000-10000-
• . o-ioo
.678-1873 "'
0-100.
No. of
Data
Points
3
13
8
15'
4 •
- .Average .
Effluent
Concentrations
(MJS/L)
10.000
10.000
0.700
: 10.000
20.000
Removal
(%) '
94.1
99.17
98.2
NR
. 54 '
.Reference
WERL
WERL '•
WERL
EAD-OCPSF*
• "WERL
'Data used in developing universal standard.
NR = Not reported
Source: (5) •' •
< - indicates a detection limit value. '
'Performance data consist of the concentration in treated' waste, accuracy correction factor, and variability factor.
'This number represents a constituent-specific matrix spike.
Source: (4)
B-40
-------
• , Table B-1.8
Treatment Performance Data for Indeno( 1,2,3-cdjpyrene
'in Wastewaters •
Technoloer
NR •
NR .
AS1
AS'
AS'
AS'
BT '..
ChOx(CI)
Fil
TF
TF
' Technology
Size
NR
N'R
Full
Full
Full
. Full
'Full
Full
Full
Full
Full
Faculty
LA0065501
LA0066214
375 E
• 37SE
375E
375E
LA0038245
108 ID -
1081D
37SE
375 E
Detection
Limit \
bte/L)
NR
NR
NR
NR
NR
NR
NR
NR
NR
. NR ^
NR
Range of
. Influent
Concentrations
0*8/L>
NR
NR
0-100
0-100
0-100
0-100
NR
0-100
0-100
•0-100
0-100
No. of
Data
Points
6
15
7
7
•7 •
7
38
NR
NR
7
7
Average .
Effluent
Concentration
(utiL)
10.000
28.000
0.013
0.011
0.017
0.015
10.097
, 0.009
. 0.027
0.012 •'
0.019
Recovery
(%)
NR
NR
NR
NR
NR
NR
\
NR -
NR
NR
' NR '
'NR
Removal
(%)
NR
NR
92.8
97'
84
86
NR
.67
59
92.5
1 89
Reference
NPDES .
NPDES
WERL*
'WERL'
WERL'
1 WERL'
NPDES
WERL
' WERL
WERL
WERL
•'Data used in developing proposed treatment standard
N'R = Not reported '
Source: (5)
< - indicates i detection limit value. . • " > ' • ' ,
•Performance data consist of the concentration in treated, waste', accuracy correction factor, and variability factor.
• This number represents a constituent-specific matrix spike.
Source: (4)
B-41
-------
Table B-19
Treatment-Performance Data
for Naphthalene in Wastewaters
Technology
AL
AL ,'
.AL
AL
AL
•AL-AL
.AS
.AS '
AS -
.AS
" .AS
/
AS
.AS
.AS
.AS
.AS
.AS
.AS '
.AS ' . '
.AS
.AS , >
AS
,AS
.AS
AS '
AirS
BT
CAC
ChOx
Technology
'- Size
Pilot
Bench
Pilot
Pilot
Pilot
i Full i
•Full
Full *
Bench
Pilot
Pilot
Full
Pilot '
Bench'
Pilot
Pilot
Full ' .
Full
Full'-
Full '
- Pilot
Full
:Full
' Full i
Pilot
, Bench
Full
Pilot
Bench
N.
Facility
I92D
371D
192D
203A
203A
233D
201B
6B
• 1050E
241 B
241B
975B
204A
202D
203A
240A
IB
IB
6B '
- 6B
192D
. IB
- 68
6B
192D
1328E
1293
203A
975B
Detection
Limit
. (u*fU
• 'MR r
NR
NR
NR
NR
NR '
NR'
NR
NR .
NR
NR. •'
NR
NR
"• NR
NR
NR
NR
NR
NR
V
NR
NR
NR
NR
NR
.NR
NR
.10
' NR
NR
Range of
'influent
Concentrations
fca/L)
0-100
100-1000
100-1000
100-1000
100-1000 .
' 100-1000
0-100
100-1000
100-1000
100-1000
100-1000
too- 1000
0-100
1000-10000
100-1000-
100-1000 .
0-100
100-1000
10000-100000
100-1000
0-100
o-ioo ' •
• 1000-10000 .
1 1 00^1 000
100-1000
10000-100000
• 11227-37145
'100-1000
0-100
No. of
Data
Points
SR
NR
NR
11
11
21
11
2'
5
11
5
NR
8
NR
11
12
5 :
5 ' '
* 14 '
' 13
- NR
4
7
3
NR
5
• 1 J • -
11
NR
Average
Effluent
. Concentration
fez/L)
1 0.000
23.000
25.000
x 13.000
• . 36.000
16.000
5.000
14.0"00
2.000
8.900
10.000 '
1.000
0.700
10.000
4.000
6.000
9.000
10.000
10.000
10.000
10.000
3.000
10.000
• 10.000 .
25.000 .
6200,000
10.000
79.000
2.000
Removal
• (%)
82
97.7
96.5
88''
• 67
98.3
89
95.9 k
99.5
97.9
93
99.17
99.09
99.86
96.3
95
86
95.4
99.95
99
82 •
919
9956
96
96.5
74
NR
. "27 , •'
88
Reference
WERL
WERL
WERL
' WERL
WERL .
WERL
WERL
WERL
WERL
WERL .'
WERL
.WERL
WERL
WERL
WERL .
WERL
WERL
WERL
WERL
WERL
WERL-
WERL
' WERL
WERL
WERL
• WERL
, E.AD1
WERL
.WERL
< • indicates a detection limit value.
'Performance data consist of the concentration in treated waste,
'This number represents a constituent-specific matrix spike.
accuracy correction factor, and variability factor.
Source: (4)
B-42
-------
Table B-19 (continued)
Technology
PACT*
RBC . .
RO
TF
TF
TF
WOx
Technology
Sfcte .
Bench
Pilot
Pilot
Pilot
Full
Pilot
Full
Facility
Zimpro
192D '
180A
240A
IB
203A
ZlfllpTO
Detection
Limit.
(Ma^L)
' NR
NR
NR
NR
NR .
NR
6
Range of
Influent
Concentrations
^ufl/L)
191
0-100
0-100
100-1000
0-100
i
too- 1000
1200 >
\o.of ,
Data
Potato
1
NR
NR
11
6
11
- I
Average
Effluent
Concentration
(ws/L)
1.000
\
10.000
0.020
14.000
3.00
74.000 .
210.000
Removal
(%)
99.9
82
80
88
89
32
NR
Reference
WAO
WERL
WERL
WERL
WERL .
WERL
WAO"
•Data used in developing proposed treatment standard
NR = Not reported
Source: (5) • -, .
< - indicates a detection limit value. . ' , •'
'Performance-data consist of the concentration in treated', waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.
Source: (4)
B-43
-------
Table B-20
Treatment Performance Data
for Phenanthrene in Wastewaters
Technology
' AL
.AL
AL
AL
AS
AS
. .AS'
.AS
AS
.AS
AS
AS-Fil '
CAC
Fi!
BP •
PACT*
•TF
TF
TF '
Technology
.Scale
Full
Pilot
Pilot
Bench
i Pilot
Pilot
Full
Pilot'
. Full
Bench . '
Bench
Full'
Pilot
Full
Full
Full ..
Pilot
Pilot
Full
Facility
6B
203 A
203A
371 D
204A
•• 240A .
6B
• 203A
IB
202D. '
1050E
6B
203A-
792E
1293
6B
240A
203A
IB
Detection
Limit
(ne/L)
NR
N'R.
• NR
NR
NR
NR '
NR
NR
NR
NR
NR
NR
NR
NR
v 10 '
NR
NR
NR
. NR •
Range of
Influent
Concentrations
O^g/L)
100-1000
: 0-100
0-100
100-1000
0-100
0-100
1000-10000
0-100
0-100
100-1000
100-1000
1000-10000
•0-100
0-100
2035-471 K '
100-1000
' 0-100.
0-100
100-1000
No. of
Data
Points
^
'• 11
11
NR
8
. 12
'14
11
4
NR
5
. 3
11
4
15
10
10
I ,
.11
- 6
•Average
Effluent
Concentration
(A
-------
Tablei B-21
Treatment Performance Data
for Pyrene in Wastewaters
Technology
AL'
AL"
AL
AS
AS
.AS
AS
AS
AS+Fi!
CAC
CAC ".
ChOx(Cl)
f»
Fil
Fil
Fil
GAC
BT . '
TF •' ,
TF-
WOX
technology
Scale
' Bench
Pilot
Pilot
Pilot
Full
Pilot
Pilot
Full
Full
Pilot
, Pilot
Full
Pilot
Pilot
' Full
Full
Pilot .
.Full
t
Pilot:
. Pilot
. Bench •.
Facility
'• 371D
203A
203A
203A
IB
204A
.204A
'6B
' 6B
195B
203A
108 ID
19SB
577E
1081D
792E
i
195D
1293
203A
240A
Zunpro
. Detection
Limit
(ttefL)
NR
NR
NR
NR
NR
NR
NR
NR
• NR
NR
NR
NR
NR
. NR
NR
NR
NR
10
NR
NR
NR.
Range of
Influent
• ^Concentrations '
C^e/U
too- 1000
100-1000
100-1000
100-1000
25-
o.ioo
0-100
100-1000. '
1000-10000
looo-ioboo -
100-1000
0-100
100-1000
0-100
0-100
1000-10000
0-100
641-1438
100-1000
0-100
500000
No. of
Data
Points
H .
11 '
11
11
I
8
12
14
3
8
U
NR
8
NR
NR
4
6
13
U
10
I
Average
EIEuent
Concentration
(ME/L)
; 15.000
36,000
25.000
5.000
. 5.000
2.000
10.000
10.000
16.000
110.000
12.000
0.018
80.000
0.001
0.045
6.000
/ 10.000
10.300
48.000
17.000
260.000
Removal
(%)
. 97
65 •
76 .
95.2 '
80
- 93.3. .
90
. 99
99.48
" .94.5
88
60 '
27
99.96
40
99.5
79
NR
54
83
99.95
Reference
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
•WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
EAD-
OCPSP
WERL
,WERL
WAO
(LIT) .
'Data used in developing universal standard.
NR = Not repotted
Source: '(5) '
< - indicates « detection limit value. . - ' ,
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
l>»i_ ' _ ^i—'_ *__ _ ^^ ..:,_ *. *£.~ *.—:.. :U._ '
This number represents a constituent-specific matrix spike.
'Source: (4)
B-45
-------
DIOXINS AND FURANS
-------
Table B-22 ; , .
Treatment Performance Data
for Tetrachlorodibenzo-p-dioxins in Wastewaters
Technology
.AS
AS
Bf
BT
GAC
KPEO (B)
KPEG(B)
Technology
Size
. Full
Full •
NR
Bench
' Full
Bench
Bench
Facility •
253B
233B
CWM
CWM
. 245B
244B
244B '
Detection
Limit
(ntfL)
NR
NR
NR
NR '
NR
NR
NR
Range of .
Influent '
Concentrations
fcz/L)
0.00014 .
0.00004
0.0021-0.0039
-0.0176
0-100
28
400
No. of
Data
Potato
1
I
3
3
NR
1
• 1
Average
Effluent
Concentration
Gjf/L)
0.00012
0.00001
0.00500
0.00400
0,00087
' 0.65000
0.37000
Removal
(%)
14
75
NR
78.79
93.6
'97.7 '
99.91
Reference
'WERL
WERL
. LEACHATE' '
LEACHATE'
WERL
WERL
- WERL
'Data used in developing universal standard.
NR = Not reported ' •
Source: (5)
, <-'indicates a detection limit value. ' v .
'•' •performance data consist of the concentration in treated waste, accuracy correction factor,- and variability factor.
This number represents a constituent-specific matrix spike. ^
Source: (4) ;'
B-47 '
-------
Table.B-23 . .
Treatment Performance Data ',
for Pentachlorodibenzo-p-dibxins in Wastewaters
Technology
KPEG(B)
.
Technology
Size
Bench
.Facility
244B
Detection
Limit
0<«/L) .
' NR
Range of
Influent
* 'Concentration*
(MZ/L)
500
No. of
Data
Points
1
Average
Effluent
Concentration
(MK/t)
0.36000
Removal
' (%>
99.93
Reference
WERL
NR - Not reported
Source: (5)
< - indicates a detection limit value.
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability, factor.
This number represents a constituent-specific matrix spike. ' . . .
. Source: (4)
B-48
-------
Table B:24
Treatment Performance Data '
for Hexachlorodibenzo-p-dioxins in Wastewaters
Technology
KPEG(B)
Technology
Size
Bench
Facility
244B
Detection
Limit
(M«/L>-
NR
Ranee of
Influent
Concentrations
< (ME/U -
3000
No. of
Data
Points
I '
Average -
Effluent
Concentration
(^e/L)
2.10000
•
Removal
(%)
99.93
• Reference
WERL
NR - Not reported
Source: (5)
< - indicates * detection limit value, -
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike.
Source: (4)
B-49
-------
Table B-25 ; , •
Treatment Performance Data
'for Tetrachlorodibenzofurans in Wastewaters
f •
Technology
KPEO (B)
Technology
.Bench
Facility
244B
Detection
.Limit -
OuZ/L)
, NR
Range of
Influent
Concentrations
toe/U
. 145
No. of
Data
Poinb
t
Average
Effluent
Concentration
0.35000
Removal
99.76
Reference
WERL
NR = Not reported ,
Source: (5)
< - indicates a detection limit value. ' -
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents « constituent-specific matrix spike. .
Source: (4)
B-50
-------
Table B-26
- , Treatment Performance Data
for.Pentachlorodibenzofurans in Wastewaters
Technology
BT
BP
KPEO(B)
Technology
Size
N'R
Bench
- Bench
Facility'
CWM .
CWM
2448
Detection
Limit
•NR
NR '
' ' NR
Range of
Influent
Concentrations
- 6.0001-0.0027
-0.0118
SOO
No. of
Data
Points
3
3
t
' Average •
Effluent
Concentration
0.002
0.003
• 0.71000
V . ,
Removal
NR
77.68"
99.91
Reference •
LEACHATE1 '
LEACHATE1
WERL
'Data used in developing universal standard.
SR = Not reported
Source: (5) • . ' .
< - indicates a detection limit vtlue. _ '
'Performance data consiit of the concentration in .treated waste/accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike. • •
Source: -(4)
B-51
-------
" ;_ Table B-27.
Treatment Performance Data
for-Hexachlorodibenzofurans in Wastewaters
.Technoloey
KPEG(B)
. Technoloey
Size '
i Bench
Facility
244B
Detection
Limit
.' (*s/L)
NR
' Range of
Influent
Concentrations
0
-------
METALS
-------
Table B-28
Treatment Performance Data
for Arsenic in Wastewaters
'Technology
AL-
AS
AS
AS
.AS
.AS '
.AS
AS
.AS
AS
AS
AS
AS .. .
CAC
CAC (B)
CAC (B)
Chred/Pt+Se
d+Fil •
' L^-Sed -
L*Sed-t-Fti' .
TF • ' •
Technology
Size
Full
Full'
Full"
- Full
Full
Full .
Full •
. Full
• Full
Full
Full
Full
Full
Full
Bench
Bench
Full
Full
. Full
Full
Facility
IB
234A
234A
234A
234A
234A . .
• 201B
IB '
IB
IB
IB
IB .
975 B
. 393A
6388
638B
K062
I
NR ,
NR
. IB
Detection
Limit
twe/L)
- NR
NR
NR
NR
NR
. NR
• NR
NR
NR
NR
NR
NR
NR
NR
NR
' " NR
NR
, NR
NR
NR
Range of
Influent.
Concentrations
(j^K/L)
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
. 0-100 '
0-100
• 0-100,
0-100
100-1000
0-100
0-100'
. - 100-1000'
< 1 00-3000
4200
4200
- • o-ioo
No. of
' Data
Points
4
7 .
•r .
7
•7 '•"
. 7
. 6
6
6
6
• 6
5
NR
NR
r
i
a
NR
NR
6
Average
Effluent
Concentration
(utfL)
• 8.000
3.000 -
6.000 .
6.000
1.000
• 1.000
4.000
4.000
2.000
2.000
3.000
2.000-
83.000
6.300
8.000 '
2.000 .
180.000
510.000
340.000 •
32.000
Removal
(%)
' 0.00
50.00 •
40.00
50.00
'75.00
. 89.00
50.00
• 50.00 .
50.00 '
50.00.
0.00 •.
33.00
• 27.00 •'
34.00
67.00
99.69
NR
NR
NR
0.00
!
Reference
WERL
WERL
WERL '
WERL
•• WERL '
WERL
WERL •
• WERL . '
WERL
' WERL
' WERL
WERL
WERL
WERL
• WERL . •
WERL
BOAT.
EAD-CMDB
EAD-CMDB1
WERL
'Data used in developing universal standard.
The influent concentration was repotted as between this range.
NR = Not reported' •
Source: (5) - , "
< - indicates a detection limit value, ' , •
'Performance daw consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represents a constituent-specific matrix spike. •' . • ' " _.
Source: (4)
B-54
-------
Table B-29
Treatment Performance Data
for Chromium (Total) in Wastewaters
Technology
AL ,
.AS.. .
.AS
.AS
.AS
AS
AS
AS
AS
.AS
AS
.AS
.AS
AS
AS
AS
AS
AS
AS- '•-
AS
'AS.
AS '
AS
AS
AS ' "
AS .
AS
. AS
AS
Technology
Size
Full
Full
Full .
Full
Full
.Full
Full
Full
Full
Full
Full
Full
\
Full-
Full
Full
• Full
Full
Full
Full
Full
• Full
Full
Full
Full
Full
Full -
Full
Full
Full
Facility
18
234A
IB
167E
IB
IB
234A
IB
167E
-IB
243A
IB
IB
IB
IB
234A
IB
IB
198E
234A
234A •
IB
IB
243A
IB
IB
IB
IB.
167E
Detection
Limit
(ne/L)
NR
NR
NR •
NR
'' NR
NR '
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR •
NR
NR
NR
NR
~'NR
NR
NR
NR
NR
NR .
NR
NR
NR
Ran«e of
Influent
Concentration*
(ut/L)
100-10000
0-100
0-100
0-100
0-100
o-ioo
0-100 "'
0-100
0.100
0-100
0-100
0-100 •
0-100 .
0-100
0-100
0-100
0-100
0-100
0-100 :
0-100
100-1000
100-1000
100-1000
100*1000
1000-10000
100-1000 .
. 100-1000
100-1000
100-1000
* No. of
• Data
Points
6
. '7 ,
6
NR .
'_ 6
7
7
6
NR
6
NR
6
6
6
6
7
6
6
33
7
7
• 6
6
- NR
6
6
6 -'
6
NR
Average
Effluent
Concentration
(MB/L) .
- 130.000
• 7.000
29,000
9.000
/5.000
22.000
16.000
/
6.000
3.000 >
12.000
12.000
36,000
35.000
6.000
11.000
'34.000
36.000
24.000
40.000
3.000
14.000
16.000
40.000
28.000
.- 62.000 .
59.000
19.000
38.000
6.000
Recovery
(%)
NR
NR
NR
NR
NR
NR
NR
• .NR'
NR
NR
NR
N'R
NR
NR
NR
NR
NR
NR
NR i
NR
NR
NR
NR
NR
NR
NR
• NR
NR
'NR '
Removal
<%)
89.00
84.00
' 64.00
72.00
90.90
69.00
82.00
85.00
96.10
76.00
83.00
62.00 '
65.00
89.00
78.00
. 58.00
64.00
70.00
79100
94.60 .
89.00
87.00 .
76.00
. 77.00
95'60
86.00
89.00
' 84.00
98.50 "
Reference •
WERL
WERL
WERL
WERL
WERL
.WERL
WERL
WERL
WERL
WERL
WERL
WERL Jj
•WERL ^
• WERL
WERL
WERL
' WERL
WERL
. WERL'
WERL
WERL
WERL
WERL
•WERL
WERL
WERL .
WERL
WERL
WERL II
< - indicates a detection limit value.
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
"This number represents a constituent-specific matrix spike. ' ' •
Source: (4)
B-55
-------
Tabled B-29' (continued)
|| Technology
IAS
AS / .
.AS
.AS
AS
AS •'
AS
..AS
AS. ' .
AS .
AS
AS •'
••AS -
AS ' •
L
L
CAC
CAC(B)
ChO*Pt(B)
ChPt
ChPt(B)
ChPt(B)
ChPt+Fii (B).
ChPt-Fil (B)
IChPt+Sed"
Chred/Pt*
Sed+Fil
Chred/Pt+
, SedfFil
. Fil.
L.Sed
Technology
Size
Full-
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Fullx-
Full '
Full
Full
Full
Full
Bench
Bench
Full
Pilot
Pilot
Pilot .
Pilot
Full .
Ful!
Full •
Pilot
Full
Facility
IB
' . 167E
IB
1294B
IB
'IB
IB
IB'
IB
201B
234A
IB
is
IB
IB
IB
393A
638B
248A
24SB
254B
254B .
254B
- 254B
NR
•K062 .
K062
254B
NR
Detection
Limit
toe/L)
. NR
NR
NR
' NR
NR
NR
NR
NR
NR
NR
NR
NR
' NR
1 NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
- so
. NR
NR
NR
NR
Range of
Influent
Concentrations
fee/L) ' "
' 1 00-1000
100-1000
100-1000
1000-10000 "
100-1000.
1000-10000
100-1000 '
1000-10000
100-1000
100-1000-
loo-iooo
100-1000
100-1000
100-1000
lOO-'lOOO
100-1000
' 100-1000
100-1000*
1000-10000"
10000.100000'
100.1000
10000-100000
10000-100000
100-1000
0~-35400
70-917000 -
6000-7000000
100-1000
i 00- 11 6000
No. of
Data
Points
6
NR
6
3
6
6
6
96
6
35
"7
7
6
6
- 6'
6
NR
f
f
1 •
16
14s
14
16
38
9
11 '
14
NR
Average . '
. Effluent
Concentration
(M8/L)
16.000
12.000 ' •
48,000
390.000
26.000
110.000
52.000
ff
140.000
19.000
51.000
20.000
46.000
28.000
35.000
50.000.
19.000
40.000 •
. 50.000
0.500
- . 34.000
77.000
170.000
47.000
75.000
572.000 -
57.000
135.000
39.000 -
84.000
Recovery
(%)
NR*
NR
NR
NR
NR
; NR
NR
NR
: NR •
NR
NR
"NR
NR
NR
NR '
NR
NR
NR
NR .
NR
NR
NR
NR
NR
NR
NR
68.0
NR
NR
' Removal
(*/.)
90.00 '
' 92.30
' 88.00
, 64.00
80.000
• 97.40 -
82.000 '
90.00
83.00 .
77.00
82.00
89.00
93.50
68.00
54.00 .
88.00
i •
>• 94:10
62.00
' 74.00
99.95
76.00
99.66
- 99.91
77.00
NR
NR ,
•• NR
• • •
90.20
NR
' Reference
WERL
. WERL
WERL
WERL
WERL
WERL
WERL
.WERL
. WERL
WERL
.. WERL
^ WERL
. WERL '
WERL
WERL
WERL
WERL •
WERL
^WERL
WERL
' WERL .
WERL
WERL .
' WERL
E.AD-MP'1 '
BOAT
'BOAT
WERL •
'EAD-CNfDB
< - indicate* a detection limit value. • . ' ' '
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
'This number represent* a constituent-specific matrix spike.
Source: (4)
B-56
-------
Table B-29 (continued)
. Technology'
L-Sed-Fil
PACT* '
Sed
Sed^Fil .
TF
TF
TF
TF
TF
TF . ,
TF
Technology
Size
Full
Pilot .
Pilot -
Full .
Full
Full
Full
Full
Full
Full
Full
Facility,
N'R
1294B
1294B
NR
• IB
IB
IB
IB
IB
, IB
IB
Detection
Limit
Cue/L)
' NR
x
NR
NR
,NR
NR'
,NR
'NR
NR
NR
NR
NR
Range of
Influent
Concentrations
(ME/L>
2800-9150
1000-10000
. 1000-10000
100-116000 '
100-1000
100-1000
o-too
100-1000
100-1000
100-1000
' 0-100
No. of
Data
Points
NR
3
3
NR
6
6
6
6 -
6 .
6'
6 .
Average
Effluent.
Concentration
(MR/L)
70.000
320.000
1100.000
80.000
57.000
34.000
15.000
92.000 '
180.000
44.000
17.000
Recovery
(%)
NR
N'R '
NR
NR
NR
NR
NR
NR
NR
NR
NR
•Removal
(%)"
NR
71.00
66.00
NR
56.00
69,00 \
67.00
23,00
25.00
71.00
48^00
Reference
- EAD-CMDB
WERL
WERL
EAD-CMDB
WERL
WERL
WERL
WERL
. WERL
WERL
WERL
. 'Data used in developing universal standard
The influent concentration was reported as between this range.
NR± Not reported
Source: (5) » *
< 7 indicates a detection limit value.
•Performance data consin of the concentration in treated waste, accuracy correction factor, and variability factor.
This number.represents a constituent-specific matrix spike. ' ' ' - ' .
Source: (4)
B-57
-------
Table B-3.0 ' , , ;
Variability Factor Calculation for Base/Neutral
Extractable Semivolatile Organic Constituents
' SemivolatUcs
Acenaphthalene , :•
Acenaphthene
Anthracene , , » ' .
Benz(a)anthracene
Benzo(a)pyrene
•Benzo(k)fluoranthene . . •
bis(2-Ethylhexyl)phthalate
Chrysene
Diethyl phthalate
Dimethyl phthalate .
Di-n-butyl phthalate i • •
Fluoranthene
Fluorene
Naphthalene
Nitrobenzene - • ;
Phenanthreiie -' .
Pyrene ,
. AVERAGE =
BAD Variability Factor
. ' 5.89125 ' , '
5.89125
- 5.89125
-.- 5.89125 .
5.89125
5.89125 •
"5.91768
5.89125 > • • .
4.75961
,'4.63833
3.23768
5.89125
5.89125 , . •:
5.89125 '
.4.83045 - .
5.89125 ' s
. 5.89125 '
5.5340 '
Semivolatiles VF = 5.5340
Source: (5)
'< - indicates a detection limit value. . . ' . ,
'Performance data consist of the concentration in treated waste, accuracy correction factor, and variability factor.
This number represent! » constituent-specific matrix spike. '
Source: (4)
B-58
-------
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-------
APPENDIX C
SUMMARY OF SUBMITTED AND OTHER AVAILABLE TREATMENT
PERFORMANCE DATA FOR WOOD PRESERVING AND
RELATED WASTES
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-------
~ APPENDIX D •
• " , - --
COMMENTS SUMMARY AND COMMENTORS
' .-'- TO OCTOBER 24,1991
ADVANCED NOTICE OF PROPOSED RULEMAKING,
POTENTIAL BDAT FOR NEWLY LISTED WASTES
FROM WOOD PRESERVING OPERATIONS
-------
-------
MEMORANDUM
TO
FROM:
DATE:
SUBJECT:
JoseLabiosa
Josefina Castellanos
June 30, 1992
cer ' file 25254.117.1
^
24, 1991
y of Public Comments to the Advance Notice Published on October
The propose of this
is to summarize the public comments related to Section V
A "Potential BOAT for Newly Listed Wastes from Wood Preserving Operations (F032,
F034, and F035)" of the Advance Notice of Proposed Rulemaking published on October
24,1991. the following six commenters addressed wood preserving wastes issues: ,
Vu
Industries
Beazer East, Inc. •
American Wood Preserving Instinite -
HWTC
Janes Granain Brown Foundation* Inc. -
The main issues addressed by the commenters were the following:
* LDRs for F032 and F034 wastewaters should be no lower that the values
F032/F034 nonwastewater BDAT levels should be both risk based and
consistent with K001.U051, and F039 standards.
* Thee is no need to include additional treatment standards for lower than
pema-chlorophenols in BDAT F032 wastes. ^ : ;
i •
., Regulating dioxins in F032 will create the same problem as with F021 and
F027. Nobody accepts these wastes for treatmenL Therefore, the generator
will have to store them indefinitely. .' • • •
Instead of regulating dioxins in F032, dioxin
• should be regulated.1
For all organics in the wastewater forms of F032, F034, and F035, the use
of F039wastewater seems appropriate.
EPA should transfer the BDAT nvaonent standards for K001 and U0521 to
F032 and F034'listed wastewaters and nonwastewatersr
6B50 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD. VIRGINIA 22151 • TELEPHONE: (703) 750-3000
-------
BDAT standards for F035 sBbuld be based on stabilization and chemical
: data from other inorganic waste codes. Specifically, EXXM, D007,
ucauucni
and K062 wastewaters are good alternatives to transfer to F03S
wastewaters. K061 based on HTMR is not a good option.
i " •
For the F035 nonwastewaters, BOAT based on vitrification is not a good
alternative given the capacity problems already in existence.
Transfer of all organic and inorganic standards associated with F034 and
F035 wastewateis and nonwastewaters to F032 is not warranted unless
there is a showing that the facility generating F032 wastes has previously
llSCQ fliTSCOlC&iS OT CT
The removal of pentachlorophenpl and pentachlorophenol associated wastes
from die acutely hazardous listing would rfwiiMt»- the current stalemate
regarding the um»M*nt and disposal of rgnTa?hlCTT?phe*K'l<=Pm*"T"tig waste
It is not appropriate to apply F032 listing to media .containing PCP even if
the plant does not use currently PCP.
EPA's interpretarion of "waste piles" is confusing (e.g., existing waste piles
for plants that no longer use PCP comply with the RCRA interim stams
standards and the LDRs.) The Agency could at a mitrimmn provide the
. regulated community with the opportunity to obtain RCRA interim status for
management of preservative-containing contaminated media at some of the
plants by extending the deadline for filing Part A Permit Application
pursuant to 40 CFR 270.10(e)(2)
The LDRS for F032, F034, and F035 should be applied only when such
wastes are managed .outside the remediation site or outside the extended
SltC** ' "
A variety of innovative technologies could be use in Ueu of incineration to
treat wood preserving wastes. By establishing concentration limits for
F032 based on incineration, the regulatory community is robbed of its
flexibility in choosing innovative technologies. .
The Agency should establish two separate programs to address treatment
standards for wood preserving wastes. One for the process waste and
another one for the contaminated media at sites with contamination
associated with past activities.
The Agency has failed to consider the large volumes of media that are, and
will be, generated by remedial activities at inactive and operating wood
preserving plants. >
It is inappropriate to assume that only the wood preserving industry
members are going to be affected by the LDRs for the newly listed wood
preserving wastes. The community involve in remediation activities should
"also be considered. .
-------
• Bioremedianon and biological treatment may prove to be extremely good
choices for treatment ofconominated soil with wood preserving wastes.
• Treatment methodologies for other arsenic- or chroimum-containing wastes
are not directly transferable to wood preserving wastes meeting the F035
•IStHQfp uCSCZIDQCRDtf ' ' '
TTlP (inqmiiefU $$& in<;{|t^as data snhmilied by the L^juimgr
was.
-------
-------
Summary Comments on the Advance Notice of Proposed Rulemaking
dated October 24, 1991
June 26,1992
6850 VERSAR CENTER * P.O. BOX 1549 • SPRINGRELD, VIRGINIA 22151 • TELEPHONE: (703) 75*3000
-------
-------
•Wter
CSP-00013 Koppers Industrie
Stephen Smith—Env. Program Manager
(412)227-2677
Koppers owns and operates thirteen wood preserving plants throughout the United
Preservatives used at each plant include pentachlorophenol, creosote, and CCA.
Koppers generates the newly listed wastes F032, F034,and F035.
Koppers states that LDRs for F032 and P034 wastewaters should be no lower than
what can be achieved by use of biological treatment. The industry standard for wastewater
treatment at wood preserving plant using pentachlorophenol and/or creosote, according to
Koppers, is to provide primary oil water separation, usually involving polymer addition,
secondary biological treatment, and discharge to a POTWin accordance with apretreatment
permit Some plants are not near POTW sewers and either evaporate wastewater or surface
discharge in accordance with discharge permits. ^
Ifniiii^rs presents
-------
Saapli Oiti
to y*tir
Specific Conductanct
ph •
PenUcMoropiitnol
Chttical Oiyqtn DMiad
To t*l Organic Carton
Oil and SriaM
ftrtinic
Chrotiua
Phenol
IPE ' ,
CMondt
Col i fort
FEATHER RIVES PUKT
ACTIVATED SUOSE HASTE HATER TREATHEBT SUHHMY
Oil HATER SEPARATOR EFR1OT - ACT. SL. UfUOT
Ftft
C
, ttS
0
ug/L
•9/L
•9/L
•9/L
•9/L
ftntltr.cm
Fluroanthtnt
PyriM
•9/L
«9''L
•9/L
•9/L
Arotitic Compounds
Napthilene '. uq/L
Acenighthylene ug/L
AcenapiithiRi ug/L
Fluorcnc ' uj/l
ug/L
ug/L
uq/L
ug/L
ug/L
uj/L
ug/L
ug/L
ug/L
ug/L
ui/L
uq/L
6PH
6PM
SPH
SPH
6PH
«SD
ChryiCM
B«nio(b)fluorjnthene
3tn:o(k)f1uoranthiac
Btnioljlpyren*
Dibenzti.hli.Uhricent
Indeno i J,e,3-cdIpyrene
FUN HMk II
Flo. Vetk 12 • '
FUv «*€*• 13
Flo. U«n H
Average Flo«
Toui Flo*
1-9-91
13.9
1703
11.58
75
1640
496.
11
'. —
' 0.11
47.4
—
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13000
2500
SOOO
1800
5200
700
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280
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97
100
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2.4
5.8
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2-6-91
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55
0.017
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—
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29000
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10000
3700
12000
1800
4500
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610
550
240
200
SOO
2000
800
SOO
.(
9
6
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4
3-13-91
—
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590
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0.017
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—
_ —
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:T
25000
2500
7000
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6600
790
3000
SOOO
370
370
130
61
120
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760
3100
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71
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250
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420000
47000
36000
38000
110000
14000
45000
16000
5300
5100
1800
1000
1800
600
SOO
570
4
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7
7-16-91
27.8
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16000
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230
73
67
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22
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6
3
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8-1-91
30.1
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0.0057
0.01
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— '
32000
SOOO
10000
2200
6600
820
3100
1400
SOO
500
130
72
120
200
80
50
3.7
3.7
3.9
2.8
9-19-91
29.8
714
8.89
31
1580
501
14
0.007
0.01
—
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23000
1300
2500
1700
4700
730
1900
880
300
270
110
46
82
50
27
23
2.8
3.5
4.5
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10-2-91
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568
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. 1400
433
22
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70.2
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21000
500
1000
350
740
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270
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40
SO
11
6.2
10
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26.49
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572,40
43.40
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6801.00
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5277.00
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1990.6J|
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2907.00 .
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269.30
152.27
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336.00
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4.77
4.65
4.39
4 6 8.9 3.73 5 5 4 3.5 3.8
0.005350 0.012699 0.012842 0.005926 0.009140 0.007164 0.005374 0.005(10 0.005572
O.fll
-------
Date
FEATHER IIVB) PUUTT
ACT-NATO SJJKE HASTE HATES
ACTIVATE] SL106E EFFUOT
0 1-10-91
— \^<~X*? -J
4-4-91
^» *• B*tir
Jpicific Conductance
jfh ' ' •'
Fpfittacaloropnmol
DiMical Oxygen Dtund
fatal Organic Carbon
Oil aad 6re*ie
Arienic
ChroilM .
Phenol
JPE
Chloride
Colifori
FHk
C
uS
0
og/L
•g/L
ig/L
•g/L '
•g/L
•g/L -
•g/L
ug/L
•g/L
•g/L
" —
21.4
597
4.99
42
449
189
3
0.01
OJH
. —
— '
—
•—
—
23.5
.431
7.18
49
114
49.5
3.9
0.0097
0.01
. '— .-'
—
—
. — '
— -
21.9
449
7.44
5.3
84.8
33.2
5
0.012
0.01
— '
—
i ' — ,
—
• —
24.8
402
7.31
9.3
455
44.2
8.4
0.015
0.01
—
— •
•. — •
. —
— •
25
844
4.3
4.4
124
54
3.3
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0.01
. ' —
—
—
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. .—
28
838
7.34
4.2
98.4
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29.9
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7.24
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28.1
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7.42
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84.8
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—
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— .
—
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29.2
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7.45
3.3
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20.7
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—
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^^
. 28
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3.2
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5
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—
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25.98
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7.25
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52.74
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0.01
0.00
0.00
0.00
. o.oo
WE
Polynucifir Aroutic Compound! ' ' , ' . • . '
Napthalene
AciMphtftyleM
Acenapathene
Huorent
Phenanthrene
Anthracene
Flurjanthene
pw
BenTlu) anthracene
Chryim
Ienzo(b)fluorantfaene
BcRJolkJfliurantaenf
Benzol aJpyrine
DtbentU,h)antliracine
Beniotg,h,i)pirylfne
!ndc
-------
P»qt I
8310
Acenachthyime
Aeenaphthcnc
Phtnanthrene
AnttMCtne .
Fluoranthtnt
Pyrent
BenroU) inttirtctnt
Chrystnt
Sinzo(a,Mantliracfnt
BtnzotohUptryltnt
Intend l,2,3-cd)pyr0»
B310 SURHBATIS
2-Fluowbiphenyl
Benzo(e)pyrtne
, . ' Siaury af analytical teultr
2Wtt-H91 C«t«tr:'topptri IndurfriM Inc Job MMI H91-03-124
Jrtitl -
WL
uq/L
ug/L
uq/L
uo/L
uq/l
U9/L
uq/L
™ W »
uq/L
uq/L
uq/L
uq/L
uq/L
UQ/L
"^ ,
uq/L
uq/L
uq/L
Sa^lts
124-003
19-MB-1991
DfUBiT
417
83600
16000
<1980
10400
14200
4540
7400
5600
1130
1450
493
294.
401
381
'257 -
226
I Rccovtry Matrix, Int.
1 Rtttw
try Matrix Int.
' ' . '
124-004
19-AUB-1991
EFFUWT
•f
<6.00
<1.9B
<1.9B
<1.9B
0.242
1.51
<0*495
2.22
2.12
0.390
1. 11
0.821
0.067
0.604
1.03
0.236
0.214
84.7
48.4
124-005
19-W-1991
OIL/HATER SPERATOR
9.87
13100
1790
1940
450
508
125
164
144
15.0
17.9
8.08
3.35
6.81
7.24
1.33
1.13
Matrix Int.
Matrix Int.
124-006
19-OUB-1991
COOLINBMA1B
• J
<6.00
O.02
<2.02
<2.02
<0.202
<0.505
(•*«•
-------
CSP-00019 Vulcan Chemicals! .••'..:
Thomas A. Robinson
Vulcan Chemical is the sole UJS. producer of pentachlorophenol.
Vulcan does not believe dial the transf erring of all organic and inorganic standards
associated with F034 and F035 wastewaters and npnwastewaters to F032 is warranted
unless there is a-showing that the facility generating F032 wastes had previously used
arsenicals or creosote preservatives. While it is not uncommon for a facility to have^used'
both creosote and pentachlorophenol, often such facilities have not used die arsenicals and
waste standards relative to F035 should not automatically apply to all facilities generating
F032. The same would apply to F034 creosote wastes. Unless there is a showing that the
facility used creosote formulations for the preservation of wood products, the facility
should not be automatically subject to BOAT standards for F034.
> . . . -
Vulcan does not believe that it is necessary that additional treatment standards for •
lower than penta-chlorophenols be included in BOAT for F032 wastes. If the penta is
either destroyed or removed to the required level, the lower chlorophenols will also be
*•.'•,'
destroyed or removed to the same or greater degree.
Vulcan states that the manufacture of pentachlorophenol already has .strict
limitations of die hexachlorodioxin content and current product generaUycxmtains less dun
2 ppm of the hexa isomer. Additionally, technical grade pentachlorophenol does not
contain any of the 23,7,8 TCDD. Accordingly, it is not necessary or appropriate to
• establish BOAT standards for the chlorinated dioxins or furans found in F032 wastes.
Related to the EPA's request of ideas about regulating F032 and lessening delays in
treatment and disposal, Vulcan states that this problem arise^from the failure of EPA to
remove pentachlorophenol wastes, F021, and FQ27, from the acutely hazardous category.
There are not commercial incinerators in the US which are permitted for the
destruction of dioxins or dioxin-comaining substances. Vulcan must ship its
pentachlorophenol associated wastes to Finland for destruction by incineration. The
removal of pentachlorophenol and pentachlorophenol associated wastes from the acutely
hazardous listing, based on the presence of trace levels of hexachlorodioxin, would
eliminate the current stalemate regarding the treatment and disposal of pentachlorophenol-
containing waste materials. >. '
«.«».<«.•. <+„«.. S^L.™*™ „„ . TH^o^^
-------
CSP-00020 Beazer East, Jnc •
Robert G. Hamilton — VP and General Manger Env. Services.
/, ' '
EPA's technical corrections to the wood preserving new listed wastes stated for the
first time thai if a cleanup operation is conducted at a closed plant that used preservatives
covered by these newly listed wastes, and this cleanup takes place after the effective date of
the wood preserving new listed wastes, the preservative-containing media removed from
• , / v * .
the site would be'regulated as hazardous wastes and subject to the LDRs. It is Beazar's
East understanding mat EPA construes the F032 listing to apply to media containing PGP
even if the plant does not currently use PCP. Thus, it appears that Beazer East may not be
able to continue with many of the investigations and cleanups at formerly operated or
currently operating plants because it might not be able to meet mandated schedules to
manage the preservative-containing media in accordance with the RCRA management
standards.
According to the commenter, another problem.arises in that the Agency often
construes soil piles as ."waste piles" that must not only have RCRA interim status but also .
must comply with the applicable RCRA interim status standards and with the LDRs. Given
the Agency's confusing interpretation of the F032 listing and the fact that this interpretation
was not clear from the listings preamble, it was, and still is, impossible for Beazer East to
ensure that existing waste piles for plants that no longer use PCP comply with the RCRA
interim status standards and the LDRs. The Agency could, at a minimum, provide the
*
regulated community with the opportunity to obtain RCRA interim status for management
of preservative-containing contaminated media at some of the plants by extending the
deadline for filing Part A Permit Applications pursuant to 40 CFR 270.10(e)(2).
. . • ' '- ' /
Another flaw in EPA's approach to establishing LDRs, in Beazer East's opinion, is
reflected in the inability of the regulated community to manage certain wastestreams in
accordance with LDRs. Beazer East retains some form,of environmental liability for
wastes that currently are classified as EPA hazardous waste No. F032 or will be classified
as such once the wastes are actively managed As you are aware, wastes designated as
F032 may contain some form, of dioxin. In light of Beazer Easts's experiences with
managing F021 and F027, which also are generated, by the wood preserving industry and
may contain some form of dioxin, Beazer East believes that it will be forced to indefinitely
store such wastetTmtil such time as: (1) the treatment industry reverses its current position
6850 VEflSAR CENTIR • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151 • TELEPHONE: (7031 750-3000
-------
and decides to accept these wastes for-off-rite treatment; or (2) EPA allows the on-site
management of such wastes without triggering the LDRs. . ,
Beazer East would only generate the newly listed wood preserving wastes in the
process of conducting T^mfajiqti^p activities. However, to the extent that the LDRs for
F032, F034, and/or F035 process wastes would be transferred to media containing F032,
F034, and/or F035, Beazer East recommends mat LDRs only apply when such wastes are
rnafftgcd outside of the remediation site or outside the *»i»»*H*fl remediation site. - ,
Regarding to soils and gronndwaters impacted with wood preserving wastes,
Beazer Bfl-^r considers ***** a variety of innovative technologies could be utilized in lieu of
incineration. Applicable f**hiy^p>gifs ip^lwte the following:
Soil Groondwater
Ex Situ bibremediaiion Activated carbon adsorption
In Situ bioremcdiation In Situ biaremediation
CJlCOQlCSl .CXfittCtlOO
Glycolatt Dechlorination Chemical oxidation
Ex Sim stabilization • . Fixed-film bioJogia
. In Situ stabilization ' Membaane ultrafilcanon
' - ' Thermal treatment UltravioIetfOxidation .
. In Sim vitrification " ' ".-
''. '
Soil washing/flushing ...
Wet air oxidation • • '
>..'•'. . ' . ' ~
By establishing concentration limits for F032 based on incineration, the regulatory
rnfrrniuntTy 4tivf> terfinolngieg. .
. Beazer East believes that the treatment standard determination' process should be
revised. The Agency should establish two separate programs to address treatment
standards. The protocol in current use could be continued por pmees^ waste treatment
standards. A separate program must be develop to address treatment of contaminated
media at sites with contamination associated with past activities. The Agency has clearly
recognized in other programs that occasions arise "where new sources of potential
environmental impact must be handled in a manner different from the management of
ongoing processes. -
8 :'"'••
6850 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151 • TELEPHONE:
(703)750.3000
-------
In dealing with capacity, the Agency has failed to include die large volumes of
media that are, and will be, generated by remedial activities at inactive and operating wood
preserving plants. EPA has suggested thai recycling may be selected as BOAT for
wastewaters. However, fieazer East's experience has shown that groundwater cannot in
most cases be recycled, Therefore, any initiative to establish recycling as the BOAT for
inorganic wastewaters from wood preserving facilities should clearly exclude groundwaters
from its purview. Thus, treatment capacity for *mjM''i?d groundwater remains an issue.
Related tn the financial gains of the wood
ntig industry,
that it is inappropriate for EPA to assume that wood preserving industry members alone
will be subject to the LDRs for the newly listed wood preserving wastes, including media
containing such wastes, there are, in fact, many other entities that are directly impacted.
Beazer East recommends mat EPA assess the impact of its approach on all entities affected.
. From the type of information that die Agency is «*»'""£ (e.g., financial status of the
wood preserving industry, drip pad use,- and removal information), it appears that EPA is
again only focusing on the impact of the LDRs on the active wood preserving industry and
not on the regulated community actively involved in remediation of media. Beazer East
recommends that before establishing LDRs, EPA undertake an extensive of the regulatory
and economical impacts that the LDRs will have on the regulated community who are, or
will be, involved in remediation activities. •',""..' , ..
In summary, then, Beazer East believes that EPA's current approach to
1 i
implementing LDRs suffers from serious flaws, particularly as it provides obstructions and
disincentives to remediate rites in a timely and cost-effective manner.
Note: The comment attaches me following documentation:
(1) A Technology Overview of Existing and Emerging Environmental Solutions
? ' v ' i
for Wood Treating Chemicals. (Memo indicating results of the evaluation of 28 RODs
dealing with wood preserving wastes.) " ' , • .
(2) Pilot Scale Demonstration Study Engineered Biodegradarion System Appendix
to Feasibility Study Nashua, New Hampshire. (Document details design, operation and
results of a pilot ex-situ bioremediation test.)
S " . . •
. (3) A lifS&ture review of land-based bioremediation case studies.
6850.VEHSAR CENTER • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151,* TELEPHONE: (703) 750-3000
-------
Versar*
:Tn
INC.
CSP-OOQ27 American Wonri
Michael diaries
(703) 893-4005
The American Wood Pieservm Institute (A WPI) believes that bioremedian'on and
biological treatment may prove to be extremely useful treatment technologies for soils
contaminated by wood-preserving wastes. In A WPI view, biorexnedian'on appears to offer
solid promise for the remediation of creosote-contaminated media (e.g., soils and
groundwater). According ID them, recent bench- and pilot-scale testing programs Have
demonstrated that biological treatment "effectively removed toxic organic compounds from
creosote wastewater." Additionally, at least foot wood-preserving facilities on the
Superfund National Priorities List are undergoing bioremediation tests under the SITE
program to remove benzene, creosote, pehtachlorophenol, polycyclic. aromatic
hydrocarbons (PAHs), and other contaminants from soils.. A WPI encourages EPA to
continue these efforts. " • • ' ' '
' In regard to F035 wastes, A WPI believes mat treatment methodologies for other
arsenic- or chromium-containing wastes are not directly transferable to wood-preserving
wastes meeting the F035 listing description. Moreover, CCA, AZCA, ACC, and CZC are
chemically distinct and not compatible with each other. Separate concentration-based
treatment standards should be promulgated for each preservative. The Center for
Hazardous Materials Research in Pittsburgh is developing a technology to recover cuppa,
chromium, and arsenic from P035 wastes. The work is about to enter the pilot-plant stage,
and EPA should adopt BDAT rules that would be consistent with the use of such a new
technology. (No details about this new technology are presented in the comment.)
Related to F034 wastes, AWPI believes that EPA should transfer the BDAT
' • • j '* '
treatment standard for KOOI and UOS1 to F034 listed wastewaters and nonwastewaters.
The standards for the organic constituents were established based upon incineration. .The
constituent-based standards also should be used to delist the wastes when attained.
AWPI suggest that the BDAT standards for P032 listed wastes be adapted from the
existing standards for KOOI and U051 wastes. The BDAT standards for KOOI and U051
are achievable with current technology and they apply to the same constituents of concern
that caused EPA.to list creosote and pentachlorophenol as hazardous in 1990.
10
6850 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 2215t • TELEPHONE: (703)750.3000
-------
ING* ' • .
AWPI whishcs to point out that the Agency is proposing to revise the existing
listing regulations for F032 wastes that would omit from the listing description certain
wastes generated by former users of chlorophenoHc formulations. The exclusion for
i
former chlorophenolic users would apply as long as they were able to demonstrate
compliance with the deletion standard for F032 wastes in the current regulations. The
December 5 NPRM makes it clear that former chlorophenolic users who switched to
creosote or an inorganic arsenical preservative would be required to manage their wastes as
characteristically toxic, F034, or F035 wastes.
The Agency stales that it is. considering the use of in-process recycling of F035
wastewaters as the BDAT for inorganic arsenicals. AWPI strongly supports this
detc
11 " .
6650 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151 • TELEPHONE: (703) 750-3000
-------
Versar*
INC.
CSP-00033 HWTC
Richard C. Fortuna
For die metal standards in F035, the HWTC urges EPA to set BDAT on the basis
of stabilization and chemical treatment ^nta from other inorganic waste codes. Since F035
are wastewaters, the wastewater data for D004, D007, and K062 are more appropriate for
technology transfer for F035 wastewaors than data on KD61 based on HTMR.
For the ndnwastewater forms of F035, the HWTC opposes the use of vitrification
data. A capacity crises already exists with the upcoming capacity extension expiration for
wastewaters* , -
For all organics in wastewater forms of F032, F034, and F035 wastes, die HWTC
supports the use of F039 wastewater standard. However, for the nonwastewater forms of
these wastes the HWTC urges EPA to set BDAT in accordance with the EQMI analysis of
i .
the HWTC PQLVMDL Study on Combustion Residuals. The EQMI analysis is presented
in a report titled: "Multisouxce Combustion Residuals- An Analytical Evaluation of
Concentration Based Treatment Standards for the Land Disposal Restriction Program" and
submitted as, an aiinr.hinpntto the UHIII HTML • - •
1 '
According to the commenter, the report is designed to assist the HWTC by
providing rationale and supporting documentation for developing concentration based
treatment standards for a specific short list of constituents in combustion residuals. The
residuals are derived from muhisonrce hazardous waste combustion units. The report
presents Table 1 and Table 2 which are attached to this summary. Table 1 lists the F039
constituents and existing BDAT standards that are "well behaved and acceptable" based on
HWTC data and Table 2 shows data on the analytically problematic BDAT constituents.
HWTC considers that Table 2 supports why EPA should not set BDAT standards for the
problematic BDAT constituents. .
The HWTC is against setting dioxin treatment standards for F032 waste. As was
the case with F024, treatment companies will not accept F032 wastes due to the difficulty
of analyzing dioxins. Instead, EPA should establish treatment standards based on the
following dioxin precursors, using data from the EQMI report. .
hexachlorob
1,2,4-trichlorobenzene .
1,2,4,5-tetrachlorobenzene
12 ' ' - ..
6850 VERSAR CENTER * P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151 • TELEPHONE: (703) 750-3000
-------
. These constituents are dioxin=pfB£ursors and can serve as suitable .surrogate
compounds as in F024. The EQMI report, recommends BOAT standards that can be set
for these dioxin precursors. ' , .
'.,-'.' 13 ' •
6850 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151 • TELEPHONE: (703) 750-3000
-------
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-------
INC.
> .
CSP-00067 James Graham Brown Foundation. Inc.
Damel Fergusson—President . .
Among the assets mat the Foundation inherited were three former wood preserving
plants. The Foundation does not operate them, but has partial responsibility for site
ion portions of these;
The Foundation has considerable experience in die treatment of soils contaminated
with wood preserving chemicals through its successful completion of site remediation
activities at the Live Oak, Florida NPL site. This site was a former wood preserving plant
where prepared bed bioremediation systems were used to treat creosote WHmn »*mt™ soils..
The broadest use of bioremediation in the CERCLA program, has involved
treatment of wood preserving contaminated soils. A large portion of these soils were
contaminated as a result of dnppage of spent preservatives prior to the enactment of RCRA.
These soils meet, the definition of F032 and F034. The principal contaminants associated
with F032 and F034 wastes are polynnclear aromatic hydrocarbons and chlorinated
' ' - '
phenolics. These constituents can be readily degraded so that the treated soils have little or
no mobile constituents remaining in the Ifwhiblf fraction. EPA has determined in various
ROD's that the treated residues are protective of human health and the environment Little
i ' . ' • .
or no Icachable fraction remained.
The Foundation encourages EPA to consider the use of prepared bed
bioremediation systems as BDAT for creosote and pentachlorophenol contaminated soils in
lieu of establishing concentration based BDAT limits. However, if EPA considers it
necessary to establish concentration based limits, the Foundation encourages EPA to
consider selecting these limits on the basis of the teachable extract resulting from the TOP
test or an equivalent test using bioremedianon as BDAT.
/ • • ' .
A large number of F032 and F034 wastes are associated with contaminated soils
(such as soils containing dnppage related to a drip track), therefore, the Foundation
encourages EPA to clearly distinguish between the process waste and the contaminated
cni]c i
Note: The comments has "three attachments:
(1) Summary of Bioremediation activities at the Live Oak, Florida NPL Site,
(2) Summary of Solid Phase Bioremediation Data, and
(3)The influence of Soil Composition on Bioremediation of PAH Contaminated
Soils. •• '
. ,
6850 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD VIRGINIA 22151 * TELEPHONE: (703) 750-3000
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APPENDIX E ,
EXAMPLES OF ALTERNATIVE TECHNOLOGIES POTENTIALLY
APPLICABLE FOR THE TREATMENT OF WOOD PRESERVING
AND RELATED WASTES
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