REMEDIATION TECHNOLOGY ASSESSMENT REPORTS

           SUMMARY OF SELECTED DOCUMENTS
    This fact sheet identifies documents prepared by federal and state agencies to assist project
    managers in selecting and designing remediation technologies.  Remediation technologies are
    typically developed through successive testing from the laboratory to the field-scale, as illustrated
    in the timeline below.  When technologies have been  implemented  at full-scale,  technology
    assessment reports are prepared to document the use of the technologies at multiple sites. Design
    manuals are then prepared to provide technical guidance based on technology assessments and
    lessons learned.
                      TIMELINE FOR DEVELOPMENT OF REMEDIATIONTECHNOLOGIES
                 Early or small-scale
                 field demonstration
                Common use in
               full-scale cleanups;
              technology optimization
                 Design manuals
     Bench- or pilot-scale
    investigation; emerging
        technologies
  Large-scale field
demonstrations; early
 full-scale cleanups
Technology assessments
 based on multi-site use
    Member agencies of the Federal Remediation Technologies Roundtable (FRTR) are conducting an
    ongoing effort to document large-scale demonstration projects and full-scale cleanups in order to
    capture cost and performance data and other lessons learned. The FRTR works to promote cooperation
    among federal agencies in order to advance the use of remediation technologies for cleaning up hazardous
    waste sites. Primary members of the FRTR include the U.S. Departments of Defense, Energy, and
    Interior; the National Aeronautics and Space Administration; and the U.S. Environmental Protection
    Agency (EPA). Currently, the Web site (www.frtr.gov) has approximately 375 technology case studies
    available in a searchable format. As experience has been gained from applications of new technologies,
    federal agencies and states (through the Interstate Technology and Regulatory Council [ITRC]*) have
    been preparing broad technology assessments and design manuals based on these site-specific case
    studies. This fact sheet highlights some of these documents that may be among the most useful to
    project managers.

    WHAT INFORMATION DOES THE WEB SITE CONTAIN?
    The Remediation Technology Assessment Reports Web site (http://costperformance.org/remediation)
    contains documents that are based on practical field experience with either specific technologies
    (such as permeable reactive barriers) or, in a few instances, specific contaminants (such as arsenic).
    As of August 2005, the Web site included 68 remediation technology assessment reports. New
    documents are identified and added to the collection every year. The table on the next page lists the
    technologies and contaminants addressed by the documents in the compilation; documents addressing
    the technologies listed in bold are highlighted in this fact sheet.
      The ITRC is a state-led coalition of regulators, industry experts, citizen stakeholders, academicians, and federal partners
      that work together to achieve regulatory acceptance of environmental technologies. Additional information about the ITRC
      is available at www.itrcweb.org.
http://costperformance.org/remediation

-------
         TECHNOLOGIES AND CONTAMINANTS COVERED IN REMEDIATION TECHNOLOGY ASSESSMENT REPORT COMPILATION
           Air Sparging
           Arsenic
           Bioremediation
           Containment- Barrier Walls
           Containment - Caps
           Dense Nonaqueous-Phase
           Liquids
           Flushing
           In Situ Chemical Oxidation
           In Situ Thermal Treatment
           Incineration (on-site)
           In-Well Air Stripping
           Monitored Natural Attenuation
           Multi-Phase Extraction
           Permeable Reactive Barriers
           Phytoremediation
Soil Vapor Extraction
Soil Washing
Solidification/Stabilization
Thermal Desorption
Underground StorageTank
Sites/Fuel-Contaminated
Sites
For the technologies listed in bold above, the following documents are considered to be among the most useful for
project managers.

Am SPARGING
                            Cost and Performance Report: Multi-Site In Situ Air Sparging (Navy, April 2005)
                            The objective of the project discussed in this report was to implement the Air Sparging
                            Design Paradigm at a number of existing air sparging sites in order to determine whether the
                            Paradigm was effective for evaluating air distribution and whether other design guidelines
                            were valid. The Paradigm provides details on air sparging principles; site characterization;
                            pilot testing; system design, installation, and operation; and system monitoring.  Another
                            goal of the project was to modify the Paradigm as necessary based on results obtained
                            from 10 field sites.  Using the Paradigm to evaluate and design air sparging systems should
                            result in applications that are more cost-effective and have better performance.
                            In addition to the above-mentioned report, the U.S. Army Corps of Engineers (USACE) is
                            working on an update to its Engineer Manual on Air Sparging that will be posted on the
                            website when it is complete.
BIOREMEDIATION

         c:
Principles and Practices of Enhanced Anaerobic Bioremediation of Chlorinated
Solvents (Environmental SecurityTechnology Certification Program [ESTCP] and U.S.
Air Force, Navy, and Army, August 2004)
This report contains information that can help project managers (1) make more informed
decisions about enhanced bioremediation as a remedial alternative, (2) select specific
enhanced bioremediation approaches that are suitable for achieving cleanup goals, and (3)
track bioremediation cost and performance. Although this process has been shown to
enhance the destruction of chlorinated solvents in situ at certain sites, there are conditions
that may limit or even preclude its use.  The report can help project managers  identify
conditions under which the technology may not be successfully applied.
In addition to the above-mentioned report, the ITRC is working on a document addressing in
situ bioremediation of dense nonaqueous-phase liquids (DNAPL) that will be posted on the
website when it is complete.
IN SITU CHEMICAL OXIDATION
                            Technical and Regulatory Guidance for In Situ Chemical Oxidation of Contaminated
                            Soil and Groundwater-Second Edition (ITRC, January 2005)
                            This document outlines the technical and regulatory requirements associated with in situ chemical
                            oxidation.  The primary oxidants addressed are hydrogen peroxide, potassium and sodium
                            permanganate, sodium persulfate, and ozone. The document should prove useful to regulators,
                            stakeholders, consultants, and technology implementers. It is divided into sections that provide
                            a technology overview and discuss its applicability, remedial investigations, safety concerns,
                            regulatory concerns, injection design, monitoring, stakeholder concerns, and case studies.
            http://costperformance.org/remediation

-------
IN SITU THERMAL TREATMENT
                            In Situ Thermal Treatment of Chlorinated Solvents:  Fundamentals and Field
                            Applications (EPA, March 2004)
                            In situ thermal treatment technologies have proven to be effective in remediating source
                            zones contaminated with chlorinated solvents and are increasingly being used for that
                            purpose. This report provides an overview of the principles and science behind the technology;
                            its applicability and general engineering considerations; and applications of the technology
                            through site-specific examples and case studies. Specific technologies addressed include
                            steam-enhanced extraction, electrical resistive heating, and thermal  conductive heating.
                            In addition to the above-mentioned report, USACE is working on a design document for in
                            situ thermal treatment that will be posted on the website when it is complete.
MULTI-PHASE EXTRACTION (MPE)

                            Multi-Phase Extraction (USACE, June 1999)
                            This engineering manual provides practical guidance for evaluating the feasibility and
                            applicability of MPE for remediation of contaminated soil and groundwater and describes
                            design and operational considerations for MPE systems.  The document is primarily
                            intended to present USACE technical policy on the use of the technology and to help
                            prevent incorrect MPE application or MPE use in unfavorable settings.
PERMEABLE REACTIVE BARRIERS (PRB)
                            Capstone Report on the Application, Monitoring, and Performance of Permeable
                            Reactive Barriers for Ground-Water Remediation: Volumes I and II (EPA, August2003)
                            This report builds on work done in previous studies conducted by ESTCP. It evaluates the
                            long-term performance of zero-valent iron PRBs at several sites, including sites in Elizabeth
                            City, North Carolina,  and Denver Federal Center, Colorado. The evaluation focuses on
                            changes in iron reactivity and reaction zone permeability overtime. The parameters used
                            for the evaluation are trends in geochemistry (for example, pH and oxidation-reduction
                            potential); microbiological activity within and around the barriers; and surface precipitation
                            forming over time in  the barriers.  The report discusses how these parameters may be
                            evaluated to predict barrier longevity and performance over time. The evaluation will be
                            useful to project managers who are constructing remedial  designs and developing
                            performance-monitoring programs.

                            Permeable Reactive Barriers: Lessons Learned/New Directions (ITRC, February 2005)
                            This document updates previous guidance issued by the ITRC. The goal for this document
                            was to compile information on PRBs that has been generated over the  last 10 years of
                            technology development and research as well as to provide information on non-iron-based
                            reactive media that can be used in PRBs. The document also provides an update on a
                            developing technology related to PRBs in which source zone contamination is treated with
                            iron-based reactive media.

                            Permeable Reactive  Barrier Technologies  for Contaminant Remediation (EPA,
                            September 1998)
                            This issue paper contains information on PRB-treatable contaminants; treatment reaction
                            mechanisms; feasibility studies for PRB implementation; site characterization; and PRB
                            design, emplacement, and monitoring for both compliance and performance as well as
                            summaries of several field applications. It also includes a summary of significant findings
                            of PRB research through 1997 and scoping calculations used to estimate the amount of
                            reactive media required.
             http://costperformance.org/remediation

-------
SOIL VAPOR EXTRACTION (SVE)
                           Engineering and Design - Soil Vapor Extraction and Bioventing (USAGE, June 2002)
                           This engineering manual provides practical guidance for design and operation of SVE and
                           bioventing (BV) systems. It addresses all aspects of the engineering of SVE and BV
                           systems, including site characterization, technology selection, bench- and pilot-scale testing,
                           design, installation, operation, and closure.
MONITORED NATURAL ATTENUATION (MNA)
                            Technical Protocol for Implementing Intrinsic Remediation with Long-Term Monitoring
                            for Natural Attenuation of Fuel Contamination Dissolved in Groundwater (U.S. Air
                            Force, March 1999)
                            This document presents a technical protocol for data collection and analysis in support
                            of MNA with long-term monitoring for restoration of groundwater contaminated with
                            fuel  hydrocarbons.  It describes  the processes associated with MNA, the site
                            characterization activities that may be performed to support evaluation of the MNA
                            option, MNA modeling using analytical or numerical solute fate and transport models,
                            and the post-modeling activities that  should be completed to ensure successful support
                            and verification of MNA.
                            Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground
                            Water (EPA, September 1998)
                            This document presents a technical protocol for data collection and analysis to evaluate
                            MNA through biological processes for remediating groundwater contaminated with
                            mixtures of fuels and chlorinated aliphatic hydrocarbons. It identifies parameters that
                            are useful for evaluating natural attenuation of chlorinated solvents (chlorinated aliphatic
                            hydrocarbons and/or fuel hydrocarbons) and provides recommendations for analyzing
                            and interpreting the data collected during the site characterization process. It also
                            provides suggestions for integrating MNA into a remedial approach that includes an
                            active remedy.
DENSE NONAQUEOUS-PHASE LIQUIDS
                            Strategies for Monitoring the Performance ofDNAPL Source Zone Remedies (ITRC,
                            August 2004)
                            The purpose of this report is to serve as a tool to educate regulators and stakeholders
                            about performance monitoring of various in situ technologies for treating DNAPLs. The
                            document discusses issues  related to DNAPLs, including the challenges of accurately
                            characterizing DNAPL sites, health and safety issues, and regulatory concerns. The
                            document also describes methods for quantifying the performance of a treatment technology
                            and ways to evaluate the efficiency and effectiveness of a remedial action in attaining
                            remediation objectives. Case studies are presented that highlight the various performance
                            assessment approaches used in recent DNAPL source zone treatment projects as well as
                            the remedial goals and objectives, performance monitoring and verification activities, and
                            lessons learned.
             http://costperformance.org/remediation

-------
UNDERGROUND STORAGE TANK SITES/FUEL-CONTAMINATED SITES
                          How to Evaluate Alternative Cleanup Technologies for Underground Storage Tank
                          Sites: A Guide for Corrective Action Plan Reviewers (EPA, May 2004)
                          The purpose of this manual is to provide guidance for reviewing corrective action plans that
                          propose alternative cleanup technologies for the remediation of leaking underground storage
                          tank sites. The manual does not advocate the use of one technology over another; rather,
                          it focuses on appropriate technology use with consideration of site-specific conditions and
                          the nature and extent of contamination. A chapter discussing MNA as a technology alternative
                          is included in the  manual.
CONTAINMENT - BARRIER WALLS
                          Evaluation of Subsurface Engineered Barriers at Waste Sites (EPA, August 1998)
                          The objective of the study discussed in this report was to address the performance of
                          subsurface engineered barriers installed throughout the United States over the previous 20
                          years to remediate hazardous waste sites and facilities. The study focused on vertical
                          barriers; evaluation of caps was a secondary objective. The overall approach to the study
                          was to assemble existing performance monitoring results from a number of sites and examine
                          those results in light of remedial objectives and factors that may influence barrier performance.
                          The factors considered included barrier design, construction quality assurance and quality
                          control; types of monitoring programs; and operation and maintenance efforts. Although the
                          report was published in 1998, the information it contains is still relevant and useful for
                          construction of subsurface engineered barriers.
   How do I submit new reports or provide feedback?
   To propose adding new reports to the compilation  or to provide feedback on existing reports,
   please contact Martha Otto of EPA's Office of Superfund Remediation and Technology Innovation
   at (703) 603-8853 or otto.martha@epa.gov.
           http://costperformance.org/remediation

-------
                         Solid Waste and
                         Emergency Response
                         (5102G)
National Service Center for
Environmental Publications
P.O. Box 42419
Cincinnati, OH 45242

Official Business
Penalty for Private Use $300
EPA542-F-05-006
August 2005
www.epa.gov
www.frtr.gov
           900Z
       S}U9lUnOOQ
           jo
           sjjoday
       )U3LUSS3SSV
        A6O|OUl|331
d/qeipunoy

-------