I I I I I oEPA Office of Environmental Engineering & Technology a siil fa te episode: 1976 August 16 to August 29,1976 EPA 600/ 1976.3 ------- astdfote episode: 1976 Widespread turbid air masses, sometimes referred to as "hazy blobs," are the most obvious characteristics of prolonged elevated pollution episodes. By using photographs taken from satellites, these large-scale pollution events, which may occur several times during a normal summer season, can be detected and tracked as they cross over land and ocean. A major episode occurred from August 16-29, 1976, over substantial portions of the North American continent and contiguous north Atlantic Ocean. As the blob developed and dissipated over a twelve- day period, it extended as far westward as Kansas, southward through much of the Mississippi River Valley out over the Gulf, northward to James Bay, Newfoundland and beyond, and eastward, far out over the ocean. The following pages document the development of this prolonged elevated pollution episode. The satellite photos taken at an altitude of about 25,000 miles show clouds and hazy air masses superimposed over the geographical features of the North American continent. Bright areas on the photographs indicate dense cloud cover, while ------- I I I I I I I I I I I I I I I bright streaks and fine-grained patterns are other cloud structures. Pollution-laden hazy air masses appear as amorphous milky areas on the photographs, such as the one extending from Ohio eastward past New Jersey out over the Atlantic on August 22. Care must be taken in interpreting these photographs to distinguish clouds from haze, as they are frequently intermingled—while over extended water areas the contrast is more pronounced. Standard weather map symbols are used to show the locations of high and low pressure systems and frontal systems on the SURFACE WEATHER & VISIBILITY display. Grey areas on this map delineate the area covered by haze as observed from the satellite. Colored areas indicate the regional extent of significantly degraded visibility as determined by airport observations. The PRIOR 3-DAY AIR PARCEL TRAJECTORIES display shows the paths followed by individual air parcels. The arrows can be thought of as the tracks of balloons simultaneously released into the air mass. The arrow shows the position of the air parcel at noon of the day indicated and its prior seventy- two hour track. Arrow length represents the distance covered, and therefore the average speed of the air parcel (wind speed). All trajectories are computed from upper air wind measurements at 600 meters (2,000 ft.) elevation above the local terrain. The SULFATE display shows 24-hour sulfate concentrations for those areas where monitoring data was available. Note that for August 22, no data was available for the majority of the region under the hazy blob—due to the twelve day cycle of most sulfate monitors. The OZONE display shows those areas where the maximum hourly value for ozone was above 80 parts per billion. Determining the full regional extent of elevated ozone concentrations is hampered by insufficient monitoring sites. ------- The twelve day episode began on August 16, as relatively clean air from the north moved in behind a frontal system that swept southward across the eastern United States. This air stagnated as a strong high pressure system developed over the central Mississippi and Ohio Valleys. Emissions from the many industrial and transportation sources (particularly, large power plants) were trapped in the stagnant air and were slowly transformed into harmful oxidants and sulfates. These formed the aerosols which were observed as haze from the satellite and were responsible for substantially reduced ground level visibility. After twelve days of "cooking" this polluted air mass moved off to the northeast as a new frontal system swept eastward over the continent. Measurements of sulfate concentrations within the turbid air mass were found to correspond closely with observations of areas of visibility reduction. Particulate sulfate 24-hour concentrations inside the blob were over 60 ug/m3, while in relatively unaffected "clear air" areas they ranged from 1.3 to 14 ug/m3. Maximum hourly ozone concentrations measured over 250 parts per billion. As observed from the satellite, the hazy air mass extended well beyond the maximum areas of ground level air quality degradation. The ability to perform analyses of these major prolonged elevated pollution episodes on a sub- continental scale is severely hampered by a lack of daily sulfate data. However, the use of satellite photographs enables us to interpret the available data in order to determine the full geographical extent and severity of these episodes which result from long range pollution transport. I I I I I I I I I I I I I I I ------- I I I I I I I 16 August 1976 • A fresh Canadian polar air mass has entered the United States... The first phases of stagnation are in progress. • Slight visibility degradation at ground level... Little evidence of hazy blob on the satellite images. • Moderately elevated sulfate and maximum ozone concentrations are found at the southern and western fringes of the high. ------- ----- i»r jf'^t ''&*''•'.•'* 'v.v, />/i^-:- w,;^'- 16 August 1976 I ?>,:•»! ' /*"; •• - • ------- I I I I I I I I I I I I I I I surface weather & visibility haze 5-mile visibility •< 3-mile visibility sulfate L- 1 10-20 pgm/M3 20-30 30-40 40-50 I > 50 single point observation/ j v NO OTHER \ DATA AVAILABLE/ prior three-day air parcel trajectories (at 600 Meters) ozone LJ> 80 PPB (areas where ozone peaked above 80 PPB, maximum hourly average) • 80 PPB ------- ------- I I I I I 22 August 1976 I I I I I I I I I I • The high has been stagnant for eight days... Air parcel trajectories indicate recirculation of the air mass over high SOa emission areas. • The hazy area on the satellite image stretches from Kansas to the east, far into the Atlantic... A sharp discontinuity in turbidity has formed aiong the front through the Great Lakes region. • Incomplete sulfate data shows very high values in Ohio and Pennsylvania (over 50 micrograms/ cubic meter)... This is coincident with a region of nearly stagnant air. Most ozone monitors within the hazy blob record greater than 80 PPB. Ground-level visibility drops below three miles over an extensive area. ------- 'SlKa^«^i ** ------- I I I I I I I I I I I I I I I surface weather & visibility LLJhaze •< 5-mile visibility •< 3-mile visibility sulfate D10-20 fjigmlM3 fl 30-40 /tgm/M3 EH 20-30 j*gm/M3 | 40-50 pgm/M3 single point observation I ^ NO OTHEH \ DATA AVAILABLE/ prior three-dqy air parcel trajectories (at 600Meters) ozone I | > 80 PPB (areas where ozone peaked above 80 PPB, maximum hourly average) K80PPB ------- ------- I I I I I I I I I I I I I I I 27 August 1976 • After twelve days, air parcel trajectories indicate the air mass is streaming northeast... A strong Pacific cold front begins to push the stagnant air mass eastward. A large-scale ducting situation is created, which transports the polluted air mass into Canada. • Haze now extends more than 700 miles into the Atlantic. • High sulfate and high ozone values continue to be recorded in the hazy area ahead of the front ,., There are still extensive areas of less than three-mile ground visibility. ------- i ir ' ------- I I I I I I I I I I I I I I I surface weather & visibility iH haze EH < 5-mile visibility I< 3-mile visibility sulfate n 10-20 pgm/M3 D 20-30 /igm/M3 u.8) single point observation ( ^~"M* ^ l30-40pgm/M3 Uo-5QMgm/M3 NO OTHER \ DATA AVAILABLE/ prior three-d^y air parcel trajectories (at 600Meters) ozone I—I > 80 PPB (areas where ozone peaked above 80 PPB, maximum hourly average) • < 80 PPB ------- ------- view from Whiteface Mountain New York State with clean air mass from the north two days later, after winds from Ohio ------- |