Iron and Steel Foundries Manual Emission Testing : Cupola Baghouse, Waupaca Foundry, Tell City, Indiana


United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-017A
June 1999
AIR
   ©EPA

   Final Report - Volume I of II

   Iron and Steel Foundries Manual
   Emissions Testing of Cupola
   Baghouse at Waupaca Foundry in
   Tell City, Indiana
           'VSTsf

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             FINAL REPORT

      IRON AND STEEL FOUNDRIES
      MANUAL EMISSION TESTING
          CUPOLA BAGHOUSE
WAUPACA FOUNDRY, TELL CITY, INDIANA

             VOLUME I OF II
   REPORT TEXT AND APPENDICES A & B
         EPA Contract No. 68D70069
         Work Assignment No. 2-08

               Prepared for:

       Mr. Michael K. Ciolek (MD-19)
         Work Assignment Manager
           SMAG, EMC, OAQPS
     U.S. Environmental Protection Agency
      Research Triangle Park, NC 27711

                June 1999
            p:\iS28\fmrpt\waupaca\report

               Submitted by

 PACIFIC ENVIRONMENTAL SERVICES, INC.
        5001 S. Miami Blvd., Suite 300
           Post Office Box 12077
    Research Triangle Park, NC 27709-2077
             (919) 941-0333
            FAX (919) 941-0234

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                                   DISCLAIMER

      This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-08.  This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.

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                        TABLE OF CONTENTS


VOLUME 1                                                    Page

1.0   INTRODUCTION	1-1

2.0   SUMMARY OF TESTRESULTS 	2-1

     2.1   EMISSIONS TEST LOG	2-1
     2.2   PARTICIPATE MATTER AND METALS 	2-1
     2.3   DIOXINS AND FURANS	2-7
     2.4   SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS	2-14

3.0   PROCESS DESCRIPTION	3-1

     3.1   INTRODUCTION	3-1
     3.2   PROCESS DESCRIPTION	3-1
     3.3   SUMMARY OF PROCESS OPERATING DATA COLLECTED
          DURING SOURCE TEST	3-5

4.0   SAMPLING LOCATIONS	4-1

     4.1   CUPOLA BAGHOUSE INLET 	4-1
     4.2   CUPOLA BAGHOUSE OUTLET 	4-1

5.0   SAMPLING AND ANALYTICAL PROCEDURES	5-1

     5.1   LOCATION OF MEASUREMENT SITES AND
          SAMPLE/VELOCITY TRAVERSE POINTS 	5-1
     5.2   DETERMINATION OF STACK GAS VOLUMETRIC
          FLOW RATE	5-1
     5.3   DETERMINATION OF DRY MOLECULAR WEIGHT
          AND EMISSION CORRECTION FACTORS	5-1
     5.4   DETERMINATION OF STACK GAS MOISTURE CONTENT 	5-3
     5.5   DETERMINATION OF PARTICULATE MATTER
          AND METALS 	5-3
     5.6   DETERMINATION OF DIOXINS AND FURANS	5-7
     5.7   DETERMINATION OF SEMIVOLATILE ORGANIC
          HAZARDOUS AIR POLLUTANTS (SVOHAPS) 	5-7
                               in

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                     TABLE OF CONTENTS (Concluded)

6.0   QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) 	6-1

     6.1   CALIBRATION OF APPARATUS 	6-1
     6.2   ON-SITE MEASUREMENTS 	6-4
     6.3   LABORATORY ANALYSIS	6-6
     APPENDIX A - RAW FIELD DATA
     APPENDIX B - ANALYTICAL DATA - PARTICULATE MATTER
                 AND METALS

VOLUME 2

     APPENDIX C - ANALYTICAL DATA - DIOXINS/FURANS AND
                 SEMI-VOLATILE ORGANIC HAZARDOUS
                 AIR POLLUTANTS
     APPENDIX D - CALCULATIONS
     APPENDIX E - QA/QC DATA
     APPENDIX F - PARTICIPANTS
                               IV

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                               LIST OF TABLES
VOLUME 1                                                                  Page

Table 2.1     Emissions Test Log, The Waupaca Foundry - Tell City, Indiana	2-2
Table 2.2     Particulate/Metals Emissions Sampling and Flue Gas Parameters,
             Cupola Baghouse Inlet, The Waupaca Foundry - Tell City, Indiana	2-3
Table 2.3     Particulate Matter Concentrations and Emission Rates, Cupola
             Baghouse Inlet, The Waupaca Foundry - Tell City, Indiana	2-4
Table 2.4     Metals Concentrations and Emission Rates, Cupola Baghouse Inlet,
             The Waupaca Foundry - Tell City, Indiana	2-5
Table 2.5     Particulate/Metals Emissions Sampling and Exhaust Gas Parameters,
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-8
Table 2.6     Particulate Matter Concentrations and Emission Rates, Cupola Baghouse
             Outlet, The Waupaca Foundry - Tell City, Indiana	2-9
Table 2.7     Exhaust Gas Metals Concentrations and Emission Rates, Cupola
             Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-10
Table 2.8     Particulate Matter and Metals Removal Efficiencies, Cupola Baghouse,
             The Waupaca Foundry - Tell City, Indiana	,	2-12
Table 2.9     PCDDs/PCDFs Emissions Sampling and Exhaust Gas Parameters
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-13
Table 2.10    PCDDs/PCDFs Exhaust Gas Concentrations and Emission Rates,
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-15
Table 2.11    PCDDs/PCDFs Exhaust Gas Concentrations and 2378 Toxic Equivalent
             Stack Gas Concentrations Adjusted to 7 Percent Oxygen,
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-16
Table 2.12    SVOHAPs Emissions Sampling and Exhaust Gas Parameters
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-17
Table 2.13    SVOHAPs Exhaust Gas Concentrations and Emission Rates, Cupola
             Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-19
Table 2.14    SOVHAPs In-Stack Detection Limits (PPBVD), Cupola Baghouse
             Outlet, The Waupaca Foundry - Tell City, Indiana	2-26

Table 3.1     Typical Cupola Charge Materials  	3-4
Table 3.2     Summary of Cupola Charging During The Test Days	3-6
Table 3.3     Process Data During The Days of Cupola Testing  	3-8
Table 3.4     Periods When Cupola Was "On Relief During Testing	3-10
Table 3.5     Process Iron Chemistry at Cupola	3-11

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                            LIST OF TABLES (Concluded)
VOLUME 1
Table 5.1     Sources, Test Parameters, and Test Methods Summary,
             The Waupaca Foundry - Tell City, Indiana	5-2

Table 6.1     Summary of Temperature Sensor Calibration Data	6-2
Table 6.2     Summary of Pitot Tube Dimensional Data	6-3
Table 6.3     Summary of Dry Gas Meter and Orifice Calibration Data 	6-5
Table 6.4     Summary of EPA Methods 23 and 29 and SW-846 Method 0010
             Field Sampling QA/QC Data	6-9
Table 6.5     Summary of EPA Method 29 Analysis QC Data, Lab Control Spikes	6-10
Table 6.6     Summary of EPA Method 29 Analysis QC Data, Matrix Spikes
             (Post Digestion)	6-11
Table 6.7     Summary of EPA Method 29 Analysis QC Data, Duplicate Analyses	6-12
Table 6.8     Summary of EPA Method 29 Analysis QC Data, Serial Dilution	6-14
Table 6.9     Summary of EPA Method 29 Analysis QC Data, Method Blanks Results .6-16
Table 6.10    Summary of EPA Method 29 Analysis QC Data, Field Blanks Results ... 6-17
Table 6.11    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Lab Control Spikes 	6-18
Table 6.12    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Matrix Spikes (Pre-Digestion)	6-19
Table 6.13    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Method Blank 	6-20
Table 6.14    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Field and Reagent Blanks  	6-21
Table 6.15    Summary of EPA Method 23 Standards Recovery Efficiencies	6-22
Table 6.16    Summary of S W-846 Method 0010  Field and Laboratory
             Blanks Results	6-23
Table 6.17    Summary of S W-846 Method 0010  Surrogate Recovery Results	6-24
                                       VI

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                                LIST OF FIGURES
VOLUME 1                                                                  Page

Figure 1.1    Air Flow Schematic and Sampling Locations at The Waupaca Foundry -
             Tell City, Indiana	1-3
Figure 1.2    Key Personnel and Responsibility for Testing Program at The Waupaca
             Foundry - Tell City, Indiana,	1-4

Figure 3.1    Simplified Schematic of Cupola Gas Handling System 	3-2
Figure 3.2    Hourly Melting Rates During Cupola Testing	3-7
Figure 3.3    Blast Air Flow Rate Through Cupola 	3-9

Figure 4.1    Cupola Baghouse Inlet Sampling Location, Waupaca Foundry -
             Tell City, Indiana	4-2
Figure 4.2    Cupola Baghouse Inlet Traverse Point Location, The Waupaca Foundry -
             Tell City, Indiana	4-3
Figure 4.3    Cupola Baghouse Outlet Sampling Location, Waupaca Foundry -
             Tell City, Indiana	4-4
Figure 4.4    Cupola Baghouse Outlet Traverse Point Locations, The Waupaca Foundry -
             Tell City, Indiana	4-5

Figure 5.1    Sampling Train Schematic for EPA Method 29  	5-4
Figure 5.2    EPA Method 29 Recovery Scheme	5-5
Figure 5.3    Sample Preparation and Analysis Scheme for EPA Method 29	5-6
Figure 5.4    Sampling Train Schematic for EPA Method 23 and
             SW-846 Method 0010	5-8
                                       vn

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1.0 INTRODUCTION
The U.S. Environmental Protection Agency (EPA) Emission Standards Division
(BSD) is investigating iron and steel foundries to identify and quantify hazardous air
pollutants (HAPs) emitted from cupolas; electric arc furnaces; and pouring, cooling and
shakedown operations of sand mold casting processes. BSD had requested that EPA's
Emissions, Monitoring and Analysis Division (EMAD) conduct the required testing. EMAD
had issued a work assignment to Pacific Environmental Services, Inc. (PES) to plan and
conduct the air emissions test program to gather emissions data as specified in the BSD test
request. The planning and testing phase of the program was conducted through EPA Contract
No. 68D20162, Work Assignment No. 4-14. This test report was completed under EPA
Contract No. 68D70069, Work Assignment No. 2-08.

The EPA's BSD is investigating two types of control devices (baghouses and
scrubbers) as potential Maximum Achievable Control Technology (MACT) floor technology
for cupolas. Two facilities were selected by BSD as host facilities for the testing program.
One uses a baghouse for control of cupola emissions, and the other uses a wet scrubber for the
control of cupola emissions. The Waupaca Foundry, located in Tell City, Indiana, uses a
baghouse and was the subject of this test program. Results of tests on a wet scrubber at the
second facility were presented under a separate report.

Testing at the Waupaca Foundry was conducted by two EMAD contractors to address
the following BSD requirements: 1) characterize HAP emissions from cupolas that are
controlled by baghouses; 2) characterize uncontrolled HAP emissions from pouring, cooling,
and shakeout (PCS) processes; 3) determine baghouse performance in controlling HAP
emissions from cupolas; and 4) identify surrogates for estimating HAP emissions from the
subject foundry processes. PES conducted testing for requirements (1) and (3). Data
gathering for requirements (2) and (4) was conducted by the other contractor and is not a part
of this document.

The Waupaca Foundry was selected by the BSD as the host facility for this project.
This facility is a large job shop foundry that conducts melting and casting operations. EPA
deemed this facility to be representative of a large segment of the sand casting foundry
industry. It operates a relatively large cupola (50 standard tons per hour melting capacity) that
is controlled by a negative pressure baghouse. Ducts were available to measure emissions
from pouring, cooling, and shakeout sections of the casting lines. The new facility recently
began production and the modem design of the cupola baghouse was expected to be as
effective as any used in this type of application. Tests were conducted at the cupola baghouse
inlet and outlet. The sampling locations at the Waupaca Foundry are shown in Figure 1.1
PES performed particulate matter (PM) and metal HAPs testing at the cupola baghouse inlet

1-1

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and outlet and organic HAPs testing at the cupola baghouse outlet. The organic HAPs
consisted of poly chlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans
(PCDDs/PCDFs) and semi-volatile organic hazardous air pollutants (SVOHAPs).

       PES used three subcontractors for this effort: Deeco, Inc. (DEECO); Triangle
Laboratories, Inc. (TLI), and Atlantic Technical Services, Inc. (ATS). DEECO provided on-
site sampling support for the determination of PM and metal HAPs; TLI provided analytical
support for the analysis of HAPs; and ATS provided support for preparation of the site-
specific test plan (SSTP), quality assurance project plan (QAPP), and report documentation..

       The field testing program organization and major lines of communication are
presented in Figure 1.2.  The PES Project Manager communicated directly with the EPA
Work Assignment Manager and coordinated all of the on-site testing activities.
                                        1-2

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Outlet Test Location
  Inlet Test Location
  Heated Blast Air
Exhaust Stack
                              Exhaust Fan
                                Baghouse
                                 Mixer
                           Oil Heat Exchangers
                             Air-to-Air Heat
                               Exchangers
                          Combustion Chamber
                                Burners
                                 Settler
                                Off Gas
                                   I
   Cupola
                             Dry Injection
                            Blast Air from
                            Cupola Blower
                           Combustion Air

                           Solids Removed
Charge
  Figure 1.1 Air Flow Schematic and Sampling Locations at The Waupaca Foundry
           Tell City, Indiana
                                  1-3

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     GM Powertrain SMCO

      Kimberly Tremblay
        (812)547-0700
           PES
       QA/OC Officer

     Jeffrey L. Van Atten
       (703)471-8383
    Pretest Site
      Survey

       PES
SSTP/QAPP

   PES
                           Subcontractor

                               ATS
                         EPA/EMC
                   Work Assignment Manager

                      Micheal K. Ciolek
                        (919) 541-4921
                                                         PES
                                                    Program Manager

                                                     John Chehaske
                                                     (703)471-8383
                           PES
                       Project Manager

                      Franklin Meadows
                       (919)941-0333
 Field
Testing

 PES
                         Subcontractor

                           DEECO
Analyses

  PES
                                            EPA/ESP

                                          Jim Maysilles
                                          (919) 541-3265
                                                                        RTI

                                                                      JeffCobum
                                                                     (919)990-8603
  Report
Preparation

   PES
                        Subcontractor

                   Triangle Laboratories, Inc.
Figure 1.2 Key Personnel and Responsibility for Testing Program at the Waupaca Foundry - Tell City, Indiana

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2.0 SUMMARY OF RESULTS

This section provides test results summaries obtained from the Waupaca Foundry
testing. Included are results of the tests conducted for particulate matter/metals at the cupola
baghouse inlet and outlet, and SVOHAPs and PCDDs/PCDFs testing at the cupola baghouse
outlet. Although we have included averages, there were differences in
production rates and operating conditions.
2.1 EMISSIONS TEST LOG

Sampling at the cupola baghouse was conducted on September 9 and 10,1997. Table
2.1 summarizes the emissions test log. Presented are the run numbers, test dates, pollutants,
run times, and downtime for filter and port changes.
2.2 PARTICULATE MATTER AND METALS

2.2.1 Baghouse Inlet

Table 2.2 summarizes the particulate matter and metals emissions sampling and flue
gas parameters at the baghouse inlet. The total sampling time for each test run was 240
minutes. The average sample volume was 105.362 dry standard cubic feet (dscf) or 2.984 dry
standard cubic meters (dscm). The average flue gas temperature was 293 °F. The flue gas
contained 11.6 percent (%) carbon dioxide (CO2), 9.7% oxygen (O2), and 2.6% moisture. The
average flue gas volumetric flow rate was 52,700 actual cubic feet per minute (acfm) or
34,500 dry standard cubic feet per minute (dscfrn) or 976 dry standard cubic meters per minute
(dscmm).

Table 2.3 summarizes the flue gas particulate matter concentrations and emission rates
at the cupola baghouse inlet. The average concentration was 1.04 grains per dry standard
cubic foot (gr/dscf) or 2.39 grams per dry standard cubic meter (g/dscm). The concentrations
are also shown adjusted to 7% O2. The average mass emission rate was 323 pounds per hour
(Ib/hr) or 146 kilograms per hour (kg/hr).

Table 2.4 summarizes the flue gas metals concentrations and emission rates. The
blank correction procedures of EPA Method 29 were used to correct the samples for the back
half reagent blank only, because the analytical results for the front half reagent blank were
considered inappropriate for blank correction.. All of the target metals were found to be
present in all three samples. Average concentrations ranged from 2.89 micrograms per dry
standard cubic meter (ug/dscm) for beryllium to 247,458 |ig/dscm for zinc.

2-1

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               TABLE 2.1
          EMISSIONS TEST LOG
THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Baghouse Inlet

I-M29-1
I-M29-2
I-M29-3
Baghouse Outlet

O-M29-1
BO-23-1
BO-0010-1
O-M29-2
BO-23-2
BO-0010-2
O-M29-3
BO-23-3
BO-0010-3
Date

09/09/97
09/10/97
09/10/97

09/09/97
09/09/97
09/09/97
09/10/97
09/10/97
09/10/97
09/10/97
09/10/97
09/10/97
Pollutant

PM/Metals
PM/Metals
PM/Metals

PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
Run Time

1025-1501
0758-1233
1515-2021

1029-1503
1029-1501
1029-1503
0810-1315
0810-1315
0810-1315
1520-2021
1520-2008
1520-2008
Downtime,
Minutes

36
35
66

34
32
34
65
65
65
61
48
48
                  2-2

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                              TABLE 2.2

    PARTICULATE/METALS EMISSIONS SAMPLING AND FLUE GAS
              PARAMETERS - CUPOLA BAGHOUSE INLET
           THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm "
Sample Volume:
dscf
dscmc
Average Flue Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfmd
dscfm a
dscmm"
Isokinetic Sampling Ratio, %
I-M29-1
9/9/97
240.5
0.342

82.208
2.328
275
10.9
10.8
2.5

39,900
26,800
759
104.0
I-M29-2
9/10/97
240
0.481

115.471
3.270
301
9.5
11.6
2.8

58,900
38,200
1,080
102.7
I-M29-3
9/10/97
240
0.493

118.408
3.353
302
8.8
12.4
2.4

59,300
38,500
1,090
106.5
Average


0.439

105.362
2.984
293
9.7
11.6
2.6

52,700
34,500
976
104.4
8 Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
                                2-3

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                               TABLE 2.3

   PARTICULATE MATTER CONCENTRATIONS AND EMISSION RATES
                      CUPOLA BAGHOUSE INLET
            THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Clock Time, 24-hr clock
Concentration:
gr/dscfa
gr/dscf@7%O2b
g/dscm °
g/dscm @ 7% O2 d
Emission Rate:
lb/hre
kg/hrf
I-M29-1
9/9/97
1025-1501

0.622
0.863
1.42
1.97

143
64.8
I-M29-2
9/10/97
0758-1233

1.44
1.75
3.30
4.01

472
214
I-M29-3
9/10/97
1515-2021

1.07
1.22
2.45
2.80

354
160
Average



1.04
1.28
2.39
2.93

323
146
" Grains per dry standard cubic foot at 68° F (20° C) and 1 atm.
b Grains per dry standard cubic foot at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
" Grams per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Grams per dry standard cubic meter at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
0 Pounds per hour.
f Kilograms per hour.
                                  2-4

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               TABLE 2.4
METALS CONCENTRATIONS AND EMISSION RATES
         CUPOLA BAGHOUSE INLET
 THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Clock Time, 24-hr clock
Antimony (Sb)
ug/dscm "
Hg/dscm@7%O2b
lb/hrc
Arsenic (As)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Barium (Ba)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Beryllium (Be)
ug/dscm 8
ug/dscm @ 7% O2 b
lb/hrc
Cadmium (Cd)
ug/dscm a
ug/dscm @ 7% O2 "
lb/hrc
Chromium (Cr)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Colbalt (Co)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Lead (Pb)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
I-M29-1
9/9/97
1025-1501

376
521
0.0377

82.5
114
0.00828

623
864
0.0625

A 1.28
1.78
0.000128

606
840
0.0608

546
758
0.0548

14.7
20.4
0.00147

34,969
48,509
3.51
I-M29-2
9/10/97
0758-1233

428
520
0.0612

76.2
92.4
0.0109

878
1,066
0.126

4.68
5.68
0.000669

1,159
1,407
0.166

750
910
0.107

13.3
16.2
0.00190

61,200
74,296
8.75
I-M29-3
9/10/97
1515-2021

385
440
0.0555

93.6
107
0.0135

746
853
0.108

2.72
3.11
0.000392

898
1,028
0.130

609
696
0.0879

14.1
16.1
0.00204

44,131
50,487
6.37
Average



396
494
0.0515

84.1
105
0.0109

749
928
0.0986

2.89
3.52
0.000397

888
1,092
0.119

635
788
0.0833

14.0
17.6
0.00180

46,767
57,764
6.21
                 2-5

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                       TABLE 2.4 (Concluded)
          METALS CONCENTRATIONS AND EMISSION RATES
                     CUPOLA BAGHOUSE INLET
           THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Manganese (Mn)
ug/dscm *
ug/dscm @ 7% O2 b
lb/hrc
Mercury (Hg)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Nickel (Ni)
ug/dscm *
ug/dscm @ 7% O2 b
lb/hrc
Phosphorus (P)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Selenium (Se)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Silver (Ag)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Thallium (Tl)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Zinc (Zn)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
I-M29-1

36,557
50,713
3.67

20.5
28.4
0.00206

136
189
0.0137

801
1,111
0.0804

31.4
43.6
0.00315

6.02
8.36
0.000605

31.3
43.4
0.00314

168,832
234,209
16.9
I-M29-2

64,105
77,822
9.16

57.1
69.3
0.00816

138
167
0.0197

843
1,023
0.120

39.5
47.9
0.00564

16.9
20.6
0.00242

51.4
62.4
0.00735

342,274
415,511
48.9
I-M29-3

49,506
56,636
7.15

17.7
20.2
0.00255

149
171
0.0215

18,258
20,888
2.64

34.6
39.6
0.00499

5.94
6.79
0.000857

39.2
44.8
0.00565

231,268
264,578
33.4
Average

50,056
61,724
6.66

31.8
39.3
0.00426

141
176
0.0183

6,634
7,674
0.945

35.2
43.7
0.00460

9.63
11.9
0.00129

40.6
50.2
0.00538

247,458
304,766
33.1
* Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm, adjusted to 7% O2.
c Pounds per hour.
                              2-6

-------
2.2.2 Baghouse Outlet

Table 2.5 summarizes the paniculate matter and trace metals emissions sampling and
exhaust gas parameters at the baghouse outlet. The total sampling time for each test run was
240 minutes. The average sample volume was 120.781 dscf or 3.420 dscm. The average
exhaust gas temperature was 246°F. The exhaust gas contained 9.6 % CO2,11.6% O2, and 3.6
% moisture. The average exhaust gas volumetric flow rate was 60,900 acfm or 43,400 dscfhi
or l,230dscmm.

Table 2.6 summarizes the exhaust gas particulate matter concentrations and emission
rates at the baghouse outlet. The average concentration was 0.00124 gr/dscf or 0.00283
g/dscm. The concentrations are also shown adjusted to 7% 02. The average mass emission
rate was 0.393 Ib/hr or 0.178 kg/hr. The results presented for run
O-M29-2 use a negative filter catch weight. Both the filter and acetone rinse fractions were
low and at the limit of detection. There are no known reasons for the negative result. If a zero
had been used, the mass emission rate for the run would be 0.0897 Ib/hr.

Table 2.7 summarizes the exhaust gas metals concentrations and emission rates. The
blank correction procedures of EPA Method 29 were used to correct the samples for the back
half reagent blank only, because the analytical results for the front half reagent blank were
considered inappropriate for blank correction. All of the target metals, except beryllium,
cobalt, and thallium, were found to be present in all three samples. Metals that were not
detected in a sample have "ND" in place of any emissions calculations and were not included
in the total metals sum. Average concentrations ranged from 0.244 ug/dscm for silver to 115
ug/dscm for zinc.

2.2.3 Baghouse Performance

Table 2.8 summarizes the performance of the baghouse in controlling PM and total
HAP metals emissions. The removal efficiencies for PM and total HAP metals are based on
the inlet and outlet mass emission rates. The average removal efficiency for PM and total
HAP metals was 99.79% and 99.88%, respectively.
2.3 DIOXINS AND FURANS

Table 2.9 summarizes the PCDDs/PCDFs emissions sampling and exhaust gas
parameters at the baghouse outlet. The total sampling time for each run was 240 minutes.
The average sample volume was 145.249 dscf or 4.113 dscm. The average exhaust gas
temperature was 247°F. The flue gas contained 9.6% CO2,11.6% O2, and 2.8%
moisture. The average exhaust gas volumetric flow rate was 62,600 acfm or 44,800 dscfm or
l,270dscmm.

The EPA Method 23 sample extracts were first analyzed using a DB-5 capillary
column to determine the concentration of each isomer of PCDDs and PCDFs (tetra- through
octa-). Tetra-chlorinated dibenzofurans were detected in this analysis; therefore,

2-7

-------
                              TABLE 2.5

   PARTICULATE/METALS EMISSIONS SAMPLING AND EXHAUST GAS
             PARAMETERS - CUPOLA BAGHOUSE OUTLET
            THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm "
Sample Volume:
dscfb
dscmc
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfind
dscfin"
dscmme
Isokinetic Sampling Ratio, %
O-M29-1
9/9/97
240
0.378

90.633
2.566
231
12.7
8.8
5.5

45,000
32,100
908
103.1
O-M29-2
9/10/97
240
0.580

139.162
3.941
253
11.0
10.1
2.6

69,600
49,700
1,410
102.2
0-M29-3
9/10/97
240
0.552

132.547
3.753
254
11.0
10.0
2.8

68,200
48,500
1,370
99.7
Average


0.503

120.781
3.420
246
11.6
9.6
3.6

60,900
43,400
1,230
101.7
" Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
                               2-8

-------
                               TABLE 2.6

   PARTICULATE MATTER CONCENTRATIONS AND EMISSION RATES
                     CUPOLA BAGHOUSE OUTLET
            THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Clock Time, 24-hr clock
Concentration:
gr/dscfa
gr/dscf@7%O2b
g/dscm °
g/dscm @ 7% 02 d
Emission Rate:
lb/hre
kg/hrf
O-M29-1
9/9/97
1029-1503

0.00259
0.00441
0.00592
0.0101

0.711
0.323
O-M29-2
9/10/97
0810-1315

0.0000333
0.0000467
0.0000761
0.000107

0.0142
0.00642
O-M29-3
9/10/97
1520-2021

0.00109
0.00154
0.00250
0.00353

0.455
0.206
Average



0.00124
0.00200
0.00283
0.00457

0.393
0.178
" Grains per dry standard cubic foot at 68° F (20° C) and 1 atm.
b Grains per dry standard cubic foot at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
' Grams per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Grams per dry standard cubic meter at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
e Pounds per hour.
f Kilograms per hour.
                                 2-9

-------
                     TABLE 2.7
EXHAUST GAS METALS CONCENTRATIONS AND EMISSION RATES
              CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Clock Time, 24-hr clock
Antimony (Sb)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Arsenic (As)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Barium (Ba)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Beryllium (Be)
ug/dscm a
Hg/dscm@7%O2b
lb/hrc
Cadmium (Cd)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Chromium (Cr)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Colbalt(Co)
ug/dscm "
ug/dscm @ 7% 02 b
lb/hrc
Lead (Pb)
ug/dscm a
ug/dscm @ 7% O2 b
lb/hrc
O-M29-1
9/9/97
1029-1503

2.13
3.63
0.000256

0.355
0.605
0.0000427

25.3
43.1
0.00304

ND
ND
ND

14.3
24.4
0.00172

4.28
7.29
0.000514

ND
ND
ND

79.6
136
0.00956
O-M29-2
9/10/97
0810-1315

1.52
2.13
0.000283

0.348
0.488
0.0000647

16.5
23.1
0.00306

ND
ND
ND

0.731
1.03
0.000136

2.73
3.83
0.000508

ND
ND
ND

15.0
21.1
0.00279
O-M29-3
9/10/97
1520-2021

1.84
2.59
0.000334

0.408
0.574
0.0000740

18.3
25.7
0.00332

ND
ND
ND

2.82
3.98
0.000513

3.45
4.86
0.000626

ND
ND
ND

30.7
43.3
0.00558
Average



1.83
2.79
0.000291

0.370
0.556
0.0000605

20.0
30.6
0.00314

ND
ND
ND

5.96
9.80
0.000789

3.49
5.33
0.000549

ND
ND
ND

41.8
66.7
0.00598
                      2-10

-------
                        TABLE 2.7 (Concluded)
   EXHAUST GAS METALS CONCENTRATIONS AND EMISSION RATES
                    CUPOLA BAGHOUSE OUTLET
           THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Manganese (Mn)
Hg/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Mercury (Hg)
Hg/dscm *
Hg/dscm @ 7% O2 b
lb/hr°
Nickel (Ni)
Hg/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Phosphorus (P)
Hg/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Selenium (Se)
ug/dscm °
Hg/dscm @ 7% O2 b
lb/hrc
Silver (Ag)
Hg/dscm °
Hg/dscm @ 7% O2 b
lb/hrc
Thallium (Tl)
Hg/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Zinc (Zn)
Hg/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
O-M29-1

16.7
28.4
0.00200

101
172
0.0121

2.97
5.06
0.000356

39.6
67.5
0.00476

2.03
3.45
0.000243

0.144
0.246
0.0000173

ND
ND
ND

69.2
118
0.00831
O-M29-2

15.6
21.8
0.00289

46.2
64.9
0.00859

1.80
2.53
0.000335

24.9
34.9
0.00463

1.68
2.36
0.000312

0.0888
0.125
0.0000165

ND
ND
ND

72.4
102
0.0135
O-M29-3

29.5
41.5
0.00535

29.8
41.9
0.00541

2.21
3.11
0.000402

22.7
31.9
0.00412

1.62
2.28
0.000294

0.498
0.702
0.0000905

ND
ND
ND

203
286
0.0369
Average

20.6
30.6
0.00342

59.0
93.0
0.00871

2.33
3.57
0.000364

29.1
44.8
0.00450

1.77
2.70
0.000283

0.244
0.357
0.0000414

ND
ND
ND

115
169
0.0196
*   Micrograms per dry standard
b   Micrograms per dry standard
c   Pounds per hour.
ND Not Detected
cubic meter at 68° F (20° C) and 1 atm.
cubic meter at 68° F (20° C) and 1 atm, adjusted to 7% 02.
                              2-11

-------
                            TABLE 2.8

     PARTICULATE MATTER AND METALS REMOVAL EFFICIENCIES
                        CUPOLA BAGHOUSE
           THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Test Set No.
Date
PM Emission Rate, lb/hr:a
Inlet
Outlet
Removal Efficiency, %:
Total Metals Emission Rate, lb/hr:a
Inlet
Outlet
Removal Efficiency, %: b
M29-1
9/9/97

143
0.711
99.50

24.5
0.0430
99.82
M29-2
9/10/97

472
0.0142
99.997

67.5
0.0371
99.95
M29-3
9/10/97

354
0.455
99.87

50.0
0.0630
99.87
Average


323
0.393
99.79

47.3
0.0477
99.88
a Pounds per hour.
b Percent removal efficiencies are calculated using the emission rates (Ib/hr).
                             2-12

-------
                               TABLE 2.9

 PCDDS/PCDFS EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
                     CUPOLA BAGHOUSE OUTLET
            THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm a
Sample Volume:
dscf
dscmc
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfmd
dscfm "
dscmm e
fsokinetic Sampling Ratio, %
BO-23-1
9/9/97
240
0.486

116.671
3.304
230
12.7
8.8
3.4

49,400
36,000
1,020
98.9
BO-23-2
9/10/97
240
0.669

160.663
4.549
258
11.0
10.1
2.6

69,500
49,200
1,390
99.7
BO-23-3
9/10/97
240
0.660

158.414
4.486
254
11.0
10.0
2.4

68,800
49,100
1,390
98.5
Average


0.605

145.249
4.113
247
11.6
9.6
2.8

62,600
44,800
1,270
99.0
11 Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
                               2-13

-------
another aliquot of the sample was analyzed using a DB-225 capillary column to measure the
2,3,7,8 tetra-chloro dibenzofuran isomer (2378 TCDF).

Some PCDDs/PCDFs catch weights were reported as estimated maximum possible
values or EMPCs. Catch weights, concentrations, and emission rates based on EMPC values
were noted by enclosing them in brackets ({}). EMPC values were included in the three-run
averages and total PCDDs/PCDFs calculations. Averages or totals that were based on EMPC
values were also enclosed in brackets to indicate the values were estimated. The
PCDDs/PCDFs test results are presented in actual concentrations and mass emission rates,
concentrations adjusted to 7% O2, and concentrations adjusted to 7% O2 in 2378 TCDF toxic
equivalents.

Table 2.10 presents the PCDDs/PCDFs stack gas concentrations and emission rates.
The average concentration of total PCDDs was estimated to be {12.3} ng/dscm. The average
concentration of total PCDFs was estimated to be {111} ng/dscm. The average concentration
of total PCDDs/PCDFs was estimated to be {123} ng/dscm. These values corresponded to
average estimated emission rates of {992}, {8,764}, and {9,756} ng/hr, respectively.

Table 2.11 presents the PCDDs/PCDFs concentrations adjusted to 7% O2. The
average measured stack gas O2 concentration was 11.6%. The average adjusted concentration
of total PCDDs was estimated to be {17.7} ng/dscm @ 7% O2. The average adjusted
concentration of total PCDFs was estimated to be {162} ng/dscm @ 7% O2. The average
adjusted concentration of total PCDDs/PCDFs was {179} ng/dscm @ 7% O2. The
concentrations, adjusted to 7% O2, were also adjusted by each congeners respective Toxic
Equivalency Factor (TEF). The TEFs used were the international TEF values. The average
concentration for total PCDDs/PCDFs, adjusted for the 2378 TCDD TEFs, was estimated to
be {3.65} ng/dscm @ 7% O2.
2.4 SEMTVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS

The semivolatile organic hazardous air pollutants (SVOHAPs) were collected using a
SW-846 Method 0010 Modified Method 5 (MM5) sampling train. The MM5 sampling train
collects organic-laden particulate materials and semi-volatile organics species. This method
speciates and quantitates low concentrations of these semi-volatile organics with boiling
points above about 100°C.

Table 2.12 summarizes the SVOHAPs emissions sampling and exhaust gas parameters
at the cupola baghouse outlet. The total sampling time for each run was 240 minutes. The
average sample volume was 142.003 dscf or 4.021 dscm. The average exhaust gas
temperature was 249°F. The exhaust gas contained 9.6% C02,11.6% O2, and 2.9% moisture.
The average exhaust gas volumetric flow rate was 60,900 acfm or 43,400 dscfm or 1,230
dscmm.
2-14

-------
                               TABLE 2.10

  PCDDS/PCDFS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
                      CUPOLA BAGHOUSE OUTLET
             THE WAUPACA FOUNDRY - TELL CITY, INDIANA

CONGENER

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
1 23478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378PeCDF
23478 PeCDF
Total PeCDF
1 23478 HxCDF
1 23678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
1 2346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION "
ng/dscm, as measured
BO-23-1

0.0696
2.12
0.133
1.03
{0.0454}
0.0726
0.0969
0.848
0.115
0.203
{0.0333}
{4.23}

1.06
39.7
0.938
1.18
17.4
0.878
0.454
0.281
0.0303
4.54
0.294
0.0515
0.484
{0.0242}
{62.1}
{66.4}
BO-23-2

0.119
4.42
0.374
3.17
0.163
0.308
0.418
3.34
0.462
0.879
0.130
11.9

1.49
57.6
2.09
2.75
38.5
2.90
1.52
1.06
0.110
14.4
1.23
0.207
2.04
0.0901
113
125
BO-23-3

0.163
7.40
0.557
6.73
0.245
0.490
0.557
5.04
0.713
1.34
{0.127}
{20.6}

2.50
74.9
3.08
4.19
58.0
4.15
2.01
1.56
0.167
21.0
1.63
0.290
2.83
0.145
157
{178}
Average

0.117
4.65
0.355
3.64
{0.151}
0.290
0.357
3.08
0.430
0.807
{0.0967}
{12.3}

1.68
57.4
2.03
2.71
38.0
2.64
1.33
0.966
0.102
13.3
1.05
0.183
1.79
{0.0864}
{111}
{123}
EMISSION RATE b
Hg/hr
BO-23-1

4.26
130
8.14
62.9
{2.78}
4.44
5.92
51.8
7.03
12.4
{2.04}
{259}

64.8
2,424
57.4
72.2
1,066
53.7
27.8
17.2
1.85
278
17.9
3.15
29.6
{1.48}
{3,799}
{4,057}
BO-23-2

9.92
369
31.2
264
13.6
25.7
34.9
279
38.6
73.5
10.8
997

125
4,812
174
230
3,214
242
127
88.2
9.18
1,207
103
17.3
171
7.53
9,411
10,408
BO-23-3

13.6
617
46.5
561
20.4
40.9
46.5
420
59.5
112
{10.6}
{1,721}

208
6,246
257
349
4,833
346
167
130
13.9
1,755
136
24.2
236
12.1
13,082
{14,803}
Average

9.25
372
28.6
296
{12.3}
23.7
29.1
250
35.0
65.8
{7.82}
{992}

133
4,494
163
217
3,038
214
107
78.5
8.33
1,080
85.5
14.9
145
{7.03}
{8,764}
{9,756}
 8 Nanogram per dry standard cubic meter at 20°C and 1 atm.
 b Micrograms per hour.
{ } Estimated Maximum Possible Concentration. EMPC values are used as reported in totals and averages.
                                2-15

-------
                                           TABLE 2.11

PCDDS/PCDFS EXHAUST GAS CONCENTRATIONS AND 2378 TOXIC EQUIVALENT STACK
                GAS CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
                                 CUPOLA BAGHOUSE OUTLET
                      THE WAUPACA FOUNDRY - TELL CITY, INDIANA

CONGENER

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
1 2346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION
(ng/dscm, adjusted to 7% O2)
BO-23-1

0.119
3.61
0.227
1.75
{0.0773}
0.124
0.165
1.44
0.196
0.345
{0.0567}
{7.21}

1.80
67.5
1.60
2.01
29.7
1.50
0.773
0.480
0.0516
7.73
0.500
0.0877
0.825
{0.0412}
{106}
{113}
BO-23-2

0.167
6.20
0.525
4.44
0.228
0.432
0.586
4.69
0.648
1.23
0.182
16.8

2.10
80.9
2.93
3.86
54.0
4.07
2.13
1.48
0.154
20.3
1.73
0.290
2.87
0.127
158
175
BO-23-3

0.229
10.4
0.785
9.48
0.345
0.691
0.785
7.10
1.00
1.88
{0.179}
{29.1}

3.52
105
4.33
5.90
81.6
5.84
2.83
2.20
0.235
29.6
2.29
0.408
3.99
0.204
221
{250}
Average

0.171
6.75
0.512
5.23
{0.217}
0.415
0.512
4.41
0.616
1.15
{0.139}
{17.7}

2.47
84.6
2.95
3.92
55.1
3.80
1.91
1.39
0.147
19.2
1.51
0.262
2.56
{0.124}
{162}
{179}
2378-TCDD b
Toxic Equivalent
Factor

1.00

0.500

0.100
0.100
0.100

0.0100

0.00100


0.100

0.0500
0.500

0.100
0.100
0.100
0.100

0.0100
0.0100

0.00100


2378 TOXIC EQUIVALENCIES
(ng/dscm, adjusted to 7% O2)
BO-23-1

0.119

0.113

{0.00773}
0.0124
0.0165

0.00196

{5.67 E-05}
{0.271}

0.180

0.0799
1.01

0.150
0.0773
0.0480
0.00516

0.00500
0.000877

{4.12 E-05}
{1.55}
{1.82}
BO-23-2

0.167

0.262

0.0228
0.0432
0.0586

0.00648

0.000182
0.560

0.210

0.147
1.93

0.407
0.213
0.148
0.0154

0.0173
0.00290

0.000127
3.09
3.65
BO-23-3

0.229

0.392

0.0345
0.0691
0.0785

0.0100

{0.000179}
{0.814}

0.352

0.217
2.95

0.584
0.283
0.220
0.0235

0.0229
0.00408

0.000204
4.66
{5.47}
Average

0.171

0.256

{0.0217}
0.0415
0.0512

0.00616

{0.000139}
{0.548}

0.247

0.148
1.96

0.380
0.191
0.139
0.0147

0.0151
0.00262

{0.000124}
{3.10}
{3.65}
* Nanogram per dry standard cubic meter adjusted to 7 percent oxygen at 20°C and I atm.
b North Atlantic Treaty Organization, Committee on the challenges of Modem Society. Pilot study on International Information
  Exchange on Dioxins and Related Compounds: International Toxicity Equivalency Factor (I-TEF) Methods of Risk Assessment
  for Complex Mixtures of Dioxins and Related Compounds. Report No. 176, August 1988.
() Non Detectable - Results are below target analyte detection limits. ND values are used as zeroes (0) in totals and averages.
{ } Estimated Maximum Possible Concentration. EMPC values are used as reported in totals and averages.
                                               2-16

-------
                              TABLE 2.12

  SVOHAPS EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
                     CUPOLA BAGHOUSE OUTLET
           THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfin "
Sample Volume:
dscf
dscmc
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfin"
dscfm"
dscmrn0
Isokinetic Sampling Ratio, %
BO-0010-1
9/9/97
240
0.458

110.023
3.116
234
12.7
8.8
3.4

46,600
33,800
957
99.4
BO-0010-2
9/10/97
240
0.627

150.485
4.261
258
11.0
10.1
2.7

66,700
47,200
1,340
97.3
BO-0010-3
9/10/97
240
0.690

165.500
4.686
256
11.0
10.0
2.6

69,300
49,200
1,390
102.6
Average


0.592

142.003
4.021
249
11.6
9.6
2.9

60,900
43,400
1,230
99.7
" Dry standard cubic feet per minute at 68° F (20° C) and 1 atra.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
                               2-17

-------
The results of the semivolatile organic emissions are shown in Table 2.13. Analysis
was performed for 70 target compounds. Of these 70 target compounds, 50 were not detected.
In cases where a compound was not detected, the emission rate, and concentration, was
replaced with a "ND". If a compound was not detected in one of the three runs, a zero was
used in the three-run average for that compound and was not summed in any SVOHAPs totals.

Analysis for the SVOHAPs was performed using SW-846 Method 8270. The lower
quantitation limit for SW-846 Method 8270 for all but four compounds was 10 fig/sample.
The four compounds, 2,4-dinitrophenol, 4-nitrophenol, 4,6-dinitro-2-methylphenol and
pentachlorophenol, had quantitation limits of 25 jag/sample. Some samples had reported
values below the quantitation limit but above the detection limit. This was the case for 19 of
the 20 detected target compounds. Like the PCDDs/PCDFs, these values were reported as
estimates and all values and calculated results were enclosed by brackets ({}) to indicate that
the compound was detected but was below the quantitation limit. These estimated values
were used in the three-run averages and the resulting averages were also enclosed in brackets
to indicate the values were estimated.

Five compounds were detected in the run samples that were also detected in the
laboratory blank (sample ID SBLK 091497). Naphthalene, phenol, acetophenone,
di-n-butylphthalate, and bis(2-ethylhexyl)phthalate were detected in the laboratory blank, but
at amounts below the quantitation limit. TLI's case narrative advises that target analytes in the
laboratory blanks should not be considered as truly present in the native samples unless found
at five times the amount found in the blank. In the case of di-n-butylphthalate, all three run
samples had estimated amounts that were less than five times the blank and therefore should
not be considered truly present in the native samples. In the case of acetophenone, only the
first and third run's samples had estimated amount slightly higher than five times the
estimated lab blank value. In the case of bis(2-ethylhexyl)phthalate and phenol, all three run
samples had estimated catches that were more than five times the estimated lab blank value.
In the case of naphthalene, the first and third run samples estimated catches were 12.9 and
13.4 times, respectively, that of the estimated blank value, while the second run's estimated
catch was only three times the estimated blank value. The TLI's case narrative also advises
that "in the event that the amount of a target analyte found in the samples is twenty times the
amount found in the associated blank, the contribution from the blank can be considered
negligible." The estimated amounts of phenol in all samples and the estimated amount of
bis(2-ethylhexyl) phthalate in the third run's sample were all greater than 20 times the
estimated blank value. Refer to Table 6.16 in section 6.0 for a complete listing of all the
detected or estimated SW-846 Method 0010 field, method, and laboratory, blanks compared to
the average sample catch weights.
2-18

-------
                      TABLE 2.13
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
               CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Clock Time, 24-hr clock
Acenaphthene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Acenaphthylene
Concentration, ppbvd *
Emission Rate, Ib/hr b
Acetophenone
Concentration, ppbvd *
Emission Rate, Ib/hr b
4-Aminobiphenyl
Concentration, ppbvd "
Emission Rate, Ib/hr b
Aniline
Concentration, ppbvd "
Emission Rate, Ib/hr b
o-Anisidine
Concentration, ppbvd "
Emission Rate, Ib/hr b
Anthracene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Benzidine
Concentration, ppbvd *
Emission Rate, Ib/hr
Benzo(a)anthracene
Concentration, ppbvd a
Emission Rate, Ib/hr b
3enzo(b)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/hr b
BO-0010-1
9/9/97
1029-1503

ND
ND

{2.70E-02}
{2.19E-05}

1.79E+00
1.13E-03

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
BO-0010-2
9/10/97
0810-1315

ND
ND

ND
ND

6.54E-01
5.78E-04

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
BO-0010-3
9/10/97
1520-2008

ND
ND

{1.50E-02}
{1.77E-05}

1.09E+00
1.01E-03

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
Average



ND
ND

{1.40E-02}
{1.32E-05}

1.18E+00
9.07E-04

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
                       2-19

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
               CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Benzo(k)fluoranthene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Benzo(ghi)perylene
Concentration, ppbvd 8
Emission Rate, Ib/hr b
Benzo(a)pyrene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Benzo(e)pyrene
Concentration, ppbvd a
Emission Rate, Ib/hr b
Benzyl Chloride
Concentration, ppbvd a
Emission Rate, Ib/hr b
Biphenyl
Concentration, ppbvd *
Emission Rate, Ib/hr b
2-Chloroacetophenone
Concentration, ppbvd 8
Emission Rate, Ib/hr b
bis-(2-Chloroethyl)ether
Concentration, ppbvd a
Emission Rate, Ib/hr b
2-ChIoronaphthalene
Concentration, ppbvd a
Emission Rate, Ib/hr b
Chrysene
Concentration, ppbvd a
Emission Rate, Ib/hr b
Cumene
Concentration, ppbvd a
Emission Rate, Ib/hr b
BO-0010-1

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{2.62E-01}
{2.12E-04}

ND
ND

ND
ND

ND
ND

ND
ND

{1.39E-01}
{8.82E-05}
BO-0010-2

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.17E-02}
{1.33E-05}

ND
ND

ND
ND

ND
ND

ND
ND

{1.22E-02}
{1.08E-05}
BO-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{2.18E-01}
{2.57E-04}

ND
ND

ND
ND

ND
ND

ND
ND

{1.01E-01}
{9.28E-05}
Average

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.64E-01}
{1.61E-04}

ND
ND

ND
ND

ND
ND

ND
ND

{8.41E-02}
{6.39E-05}
                       2-20

-------
                  TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
               CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Dibenz(a,h)anthracene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Dibenzofuran
Concentration, ppbvd a
Emission Rate, Ib/hr b
1 ,2-Dibromo-3-chloropropane
Concentration, ppbvd a
Emission Rate, Ib/hr b
Di-n-butylphthalate
Concentration, ppbvd °
Emission Rate, Ib/hr b
1 ,4-DichIorobenzene
Concentration, ppbvd *
Emission Rate, Ib/hr
3,3'-Dichlorobenzidine
Concentration, ppbvd *
Emission Rate, Ib/hr
N,N-Diethylaniline
Concentration, ppbvd a
Emission Rate, Ib/hr b
3,3'-Dimethoxybenzidine
Concentration, ppbvd a
Emission Rate, Ib/hr b
Dimethylaminoazobenzene
Concentration, ppbvd "
Emission Rate, Ib/hr b
N,N-DimethylaniIine
Concentration, ppbvd "
Emission Rate, Ib/hr b
3,3'-Dimethylbenzidine
Concentration, ppbvd "
Emission Rate, Ib/hr b
BO-0010-1

ND
ND

{1.21E-01}
{1.07E-04}

ND
ND

{1.57E-01}
{2.30E-04}

{1.07E-01}
{8.29E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
BO-0010-2

ND
ND

ND
ND

ND
ND

{7.10E-02}
{1.45E-04}

{5.84E-02}
{6.31E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
BO-0010-3

ND
ND

{1.41E-01}
{1.82E-04}

ND
ND

{3.87E-02}
{8.26E-05}

{9.15E-02}
{1.03E-04}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
Average

ND
ND

{8.72E-02}
{9.62E-05}

ND
ND

{8.88E-02}
{1.52E-04}

{8.57E-02}
{8.30E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
                       2-21

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
              CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Dimethylphthalate
Concentration, ppbvd *
Emission Rate, Ib/hr b
4,6-Dinitro-2-methylphenol
Concentration, ppbvd a
Emission Rate, Ib/hr b
2,4-Dinitrophenol
Concentration, ppbvd "
Emission Rate, Ib/hr b
2,4-Dinitrotoluene
Concentration, ppbvd "
Emission Rate, Ib/hr b
bis(2-Ethylhexyl)phthalate
Concentration, ppbvd "
Emission Rate, Ib/hr b
Fluoranthene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Fluorene
Concentration, ppbvd *
Emission Rate, Ib/hr b
[iexachlorobenzene
Concentration, ppbvd "
Emission Rate, Ib/hr b
rlexachlorobutadiene
Concentration, ppbvd *
Emission Rate, Ib/hr
Hexachlorocyclopentadiene
Concentration, ppbvd a
Emission Rate, Ib/hr b
Hexachloroethane
Concentration, ppbvd 8
Emission Rate, Ib/hr
BO-0010-1

{1.44E-01}
{1.47E-04}

ND
ND

ND
ND

ND
ND

3.15E-01
6.48E-04

{2.10E-02}
{2.23E-05}

{3.99E-02}
{3.49E-05}

ND
ND

ND
ND

ND
ND

ND
ND
BO-0010-2

{7.62E-02}
{1.09E-04}

ND
ND

ND
ND

ND
ND

{8.64E-02}
{2.48E-04}

ND
ND

ND
ND

{1.07E-02}
{2.24E-05}

ND
ND

ND
ND

ND
ND
BO-0010-3

{4.28E-02}
{6.37E-05}

ND
ND

ND
ND

ND
ND

2.55E-01
7.62E-04

{2.77E-02}
{4.29E-05}

{3.52E-02}
{4.48E-05}

{1.03E-02}
{2.24E-05}

ND
°ND

ND
ND

ND
ND
Average

{8.78E-02}
{1.07E-04}

ND
ND

ND
ND

ND
ND

{2.19E-01}
{5.52E-04}

{2.43E-02}
{3.26E-05}

{2.51E-02}
{2.66E-05}

{6.99E-03}
{1.49E-05}

ND
ND

ND
ND

ND
ND
                       2-22

-------
                  TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
               CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Hydroquinone
Concentration, ppbvd "
Emission Rate, Ib/hr b
Indeno(l ,2,3-cd)pyrene
Concentration, ppbvd *
Emission Rate, Ib/hr b
Isophorone
Concentration, ppbvd "
Emission Rate, Ib/hr b
Methylene bis-chloroaniline
Concentration, ppbvd '
Emission Rate, Ib/hr b
4,4'-MethylenedianiIine
Concentration, ppbvd *
Emission Rate, Ib/hr b
2-Methylnaphthalene
Concentration, ppbvd *
Emission Rate, Ib/hr b
2-Methylphenol
Concentration, ppbvd *
Emission Rate, Ib/hr b
3/4-Methylphenol
Concentration, ppbvd "
Emission Rate, Ib/hr b
Naphthalene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Nitrobenzene
Concentration, ppbvd "
Emission Rate, Ib/hr b
4-Nitrobiphenyl
Concentration, ppbvd *
Emission Rate, Ib/hr b
BO-0010-1

{2.11E-01}
{1.22E-04}

ND
ND

ND
ND

ND
ND

ND
ND

{3.19E-01}
{2.39E-04}

ND
ND

ND
ND

1.25E+00
8.43E-04

ND
ND

ND
ND
BO-0010-2

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{5.20E-02}
{5.44E-05}

ND
ND

ND
ND

{2.13E-01}
{2.00E-04}

ND
ND

ND
ND
BO-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.92E-01}
{2.10E-04}

ND
ND

ND
ND

8.65E-01
8.50E-04

ND
ND

ND
ND
Average

{7.04E-02}
{4.08E-05}

ND
ND

ND
ND

ND
ND

ND
ND

{1.88E-01}
{1.68E-04}

ND
ND

ND
ND

{7.76E-01}
{6.31E-04}

ND
ND

ND
ND
                       2-23

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
               CUPOLA BAGHOUSE OUTLET
       THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
4-Nitrophenol
Concentration, ppbvd "
Emission Rate, Ib/hr b
n-Nitrosodimethylamine
Concentration, ppbvd a
Emission Rate, Ib/hr b
n-NitrosomorphoIine
Concentration, ppbvd "
Emission Rate, Ib/hr b
Pentachloronitrobenzene
Concentration, ppbvd *
Emission Rate, Ib/hr b
Pentachlorophenol
Concentration, ppbvd a
Emission Rate, Ib/hr b
Perylene
Concentration, ppbvd "
Emission Rate, Ib/hr b
Phenanthrene
Concentration, ppbvd a
Emission Rate, Ib/hr
Phenol
Concentration, ppbvd "
Emission Rate, Ib/hr b
1 ,4-Phenylenediamine
Concentration, ppbvd °
Emission Rate, Ib/hr b
Pyrene
Concentration, ppbvd *
Emission Rate, Ib/hr
o-Toluidine
Concentration, ppbvd "
Emission Rate, Ib/hr b
BO-0010-1

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.41E-01}
{1.32E-04}

1.29E+00
6.39E-04

ND
ND

ND
ND

ND
ND
BO-0010-2

ND
ND

ND
ND

ND
ND

ND
ND

{3.48E-02}
{6.80E-05}

ND
ND

{1.24E-02}
{1.62E-05}

{1.88E-01}
{1.30E-04}

ND
ND

ND
ND

ND
ND
BO-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

{4.78E-02}
{9.75E-05}

ND
ND

{1.63E-01}
{2.22E-04}

{4.74E-01}
{3.42E-04}

ND
ND

ND
ND

ND
ND
Average

ND
ND

ND
ND

ND
ND

ND
ND

{2.75E-02}
{5.52E-05}

ND
ND

{1.05E-01}
{1.23E-04}

{6.51E-01}
{3.70E-04}

ND
ND

ND
ND

ND
ND
                       2-24

-------
                         TABLE 2.13 (Concluded)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
                     CUPOLA BAGHOUSE OUTLET
           THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
1 ,2,4-Trichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/hr b
2,4,5-Trichlorophenol
Concentration, ppbvd 8
Emission Rate, Ib/hr b
2,4,6-TrichIorophenol
Concentration, ppbvd "
Emission Rate, Ib/hr b
a,a,a-Trichlorotoluene
Concentration, ppbvd a
Emission Rate, Ib/hr b
Irifluralin
Concentration, ppbvd *
Emission Rate, Ib/hr b
BO-0010-1

{1.23E-01}
{1.17E-04}

ND
ND

8.55E-01
8.88E-04

ND
ND

ND
ND
BO-0010-2

{1.24E-01}
{1.66E-04}

ND
ND

{6.09E-02}
{8.84E-05}

ND
ND

ND
ND
BO-0010-3

{1.40E-01}
{1.95E-04}

ND
ND

6.40E-01
9.68E-04

ND
ND

ND
ND
Average

{1.29E-01}
{1.59E-04}

ND
ND

{5.18E-01}
{6.48E-04}

ND
ND

ND
ND
   Parts per billion by volume.
   Pounds per hour.
ND Not Detectable - Results are below target analyte detection limit Values are counted as zero (0) in averages.
{ } Estimate - Analyte results are below the quantitation limit and above the detection limit. Values are counted in
   the averages.
                                 2-25

-------
               TABLE 2.14
SVOHAPS BV-STACK DETECTION LIMITS (PPBVD)
        CUPOLA BAGHOUSE OUTLET
THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
Date
Clock Time, 24-hr clock
Acenaphthene
Acenaphthylene
Acetophenone
4-Aminobiphenyl
Aniline
o-Anisidine
Anthracene
Benzidine
8enzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(ghi)perylene
Benzo(a)pyrene
Benzo(e)pyrene
Benzyl Chloride
Biphenyl
2-Chloroacetophenone
bis-(2-Chloroethyl)ether
2-Chloronaphthalene
Chrysene
Cumene
Dibenz(a,h)anthracene
Dibenzofuran
1 ,2-Dibromo-3-chloropropane
Di-n-butylphthalate
1 ,4-Dichlorobenzene
3 ,3 '-Dichlorobenzidine
M,N-Diethylaniline
3,3'-Dimethoxybenzidine
Dimethylaminoazobenzene
N,N-Dimethylaniline
3 ,3 '-Dimethylbenzidine
Dimethylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
BO-0010-1
09/09/97
1029-1503
1.55E-02
D
D
1.19E-02
2.49E-02
3.51E-02
1.08E-02
2.22E-02
1.35E-02
1.65E-02
1.59E-02
2.29E-02
1.84E-02
1.62E-02
1.04E-02
D
1.20E-02
3.83E-02
1.38E-02
1.45E-02
D
2.72E-02
D
2.84E-02
D
D
3.97E-02
1.45E-02
4.99E-02
3.39E-02
1.66E-02
2.80E-02
D
7.99E-02
1.46E-01
BO-0010-2
09/10/97
0810-1315
1.50E-02
9.15E-03
D
1.03E-02
2.06E-02
3.30E-02
9.82E-03
2.11E-02
1.31E-02
1.99E-02
1.95E-02
2.80E-02
2.24E-02
1.97E-02
8.92E-03
D
1.10E-02
3.24E-02
1.32E-02
1.41E-02
D
3.29E-02
9.06E-03
2.39E-02
D
D
3.84E-02
1.21E-02
4.81E-02
3.28E-02
1.49E-02
2.69E-02
D
7.64E-02
1.39E-01
BO-0010-3
09/10/97
1520-2008
9.65E-03
D
D
7.28E-03
1.43E-02
2.13E-02
6.62E-03
1.39E-02
8.54E-03
1.10E-02
1.06E-02
1.52E-02
1.22E-02
1.08E-02
6.08E-03
D
6.97E-03
2.23E-02
8.52E-03
9.22E-03
D
1.79E-02
D
1.63E-02
D
D
2.51E-02
8.25E-03
3.15E-02
2.14E-02
9.74E-03
1.77E-02
D
4.92E-02
9.09E-02
Average


1.34E-02
9.15E-03
NA
9.83E-03
1.99E-02
2.98E-02
9.09E-03
1.91E-02
1.17E-02
1.58E-02
1.53E-02
2.20E-02
1.76E-02
1.56E-02
8.46E-03
NA
9.97E-03
3.10E-02
1.18E-02
1.26E-02
NA
2.60E-02
NA
2.29E-02
NA
NA
3.44E-02
1.16E-02
4.32E-02
2.94E-02
1.37E-02
2.42E-02
NA
6.85E-02
1.25E-01
                2-26

-------
                     TABLE 2.14 (Concluded)

        SVOHAPSIN-STACK DETECTION LIMITS (PPBVD)
                  CUPOLA BAGHOUSE OUTLET
        THE WAUPACA FOUNDRY - TELL CITY, INDIANA
Run No.
2,4-Dinitrophenol
2,4-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hydroquinone
Indeno(l ,2,3-cd)pyrene
Isophorone
Methylene bis-chloroaniline
4,4'-Methylenedianiline
2-Methylnaphthalene
2-Methylphenol
3/4-Methylphenol
Naphthalene
Nitrobenzene
4-NitrobiphenyI
4-Nitrophenol
n-Nitrosodimethylamine
n-Nitrosomorpholine
Pentachloronitrobenzene
Pentachlorophenol
Perylene
Phenanthrene
Phenol
1 ,4-Phenylenediamine
Pyrene
o-Toluidine
1 ,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
a,a,a-Trichlorotoluene
Trifluralin
BO-0010-1
1.46E-01
3.52E-02
D
D
1.76E-02
1.69E-02
1.59E-02
2.41E-02
D
1.91E-02
1.28E-02
6.53E-02
5.02E-02
D
3.71E-02
3.28E-02
D
1.51E-02
2.67E-02
8.05E-02
8.23E-02
4.85E-02
4.03E-02
2.90E-02
1.84E-02
D
D
3.00E-02
1.18E-02
2.45E-02
D
2.66E-02
D
1.11E-02
2.26E-02
BO-0010-2
1.39E-01
3.38E-02
7.81E-03
1.22E-02
D
1.58E-02
1.51E-02
2.05E-02
3.54E-02
2.33E-02
1.18E-02
6.32E-02
4.87E-02
D
3.13E-02
3.03E-02
D
1.42E-02
3.11E-02
7.67E-02
6.93E-02
4.08E-02
3.61E-02
D
2.24E-02
D
D
2.77E-02
1.17E-02
2.05E-02
D
2.52E-02
D
1.01E-02
2.17E-02
BO-0010-3
9.09E-02
2.20E-02
D
D
D
1.02E-02
9.78E-03
1.39E-02
2.28E-02
1.27E-02
7.80E-03
4.15E-02
3.18E-02
D
2.14E-02
1.95E-02
D
9.17E-03
2.13E-02
5.02E-02
4.71E-02
2.78E-02
2.49E-02
D
1.22E-02
D
D
1.76E-02
7.61E-03
1.39E-02
D
1.64E-02
D
6.56E-03
1.41E-02
Average
1.25E-01
3.03E-02
7.81E-03
1.22E-02
1.76E-02
1.43E-02
1.36E-02
1.95E-02
2.91E-02
1.84E-02
1.08E-02
5.67E-02
4.36E-02
NA
2.99E-02
2.75E-02
NA
1.28E-02
2.64E-02
6.91E-02
6.63E-02
3.91E-02
3.37E-02
2.90E-02
1.76E-02
NA
NA
2.51E-02
1.04E-02
1.96E-02
NA
2.27E-02
NA
9.24E-03
1.95E-02
 D Detected; no detection limit provided; i.e. averages ignore D results.
NA Not applicable; used when all results are "D" or detected.
                                  2-27

-------
3.0 PROCESS AND CONTROL EQUIPMENT OPERATION
3.1 INTRODUCTION

The Waupaca foundry in Tell City, Indiana, is a completely new grey iron foundry that
started operation in February 1997. The foundry casts a diverse group of products, including
brake drums, shoes, rotors, calipers, and other parts. The plant operates one large cupola that
melts at a rate of about 60 tons/hr (tph), and operates four pouring lines. This section of the
test report provides a description of the cupola operation for iron melting, and the casting
operation, including pouring, cooling, and shake out.
3.2 PROCESS DESCRIPTION

3.2.1 Iron Melting in Cupolas

The Waupaca foundry in Tell City operates a large, water-cooled cupola that melts at a
rate of approximately 60 tph, with a blast rate of 10,000 to 15,000 standard cubic feet per
minute (scfm), which makes it a large cupola by U.S. industry standards. Figure 3.1 is a
simplified schematic of the cupola gas handling system and emission control equipment.

The cupola is charged with metal scrap, re-melt, coke, and limestone at the top of the
cupola, using one of two automated skip buckets. The level of metal within the cupola is
monitored, and the charge material in the skip bucket is dumped into the cupola when the
level of charge falls below a set level. The seal from the charge material and a draft on the
cupola prevent gases from escaping. If, for any reason, the charge material cannot be added to
the cupola within five minutes of the level falling below the set point, the cupola will
automatically go "off blast" until the appropriate charge level in the cupola can be achieved.

The blast air is preheated to about 1,000°F in the blast air recuperator and is
introduced into the bottom of the cupola through eight tuyeres. The blast is also enriched with
oxygen under certain melting conditions. The off gas from the cupola is removed at 250-
300 °F. The off-take duct is lined with refractory material and leads to a coarse grain separator
where heavy particles are removed. The separator is cooled with non-contact water.
3-1

-------
to
                                               (3) Ott heat exchangers
                                                                                     Exhaust Stack
                                    Combustion
                                    Chamber
                       CUPOLA
                                   Solids Removed
                                                 Combustion Air
Exhaust fan
                                Figure 3.1. Simplified Schematic of Cupola Gas Handling System

-------
After removal of the heavy particles, the gas enters a large combustion chamber where
combustion air is introduced and the carbon monoxide (CO) is burned. Two burners are used
when necessary to maintain the combustion temperature. The gas leaves the combustion
chamber at approximately 1650°F, and enters a dropout chamber where additional heavy
particles are removed. The hot gas then passes through an air-to-air heat exchanger (blast air
recuperator), followed by a series of three oil heat exchangers that are used to cool the air.
These oil heat exchangers are hot currently used for heat recovery. (Modifications may be
made in the future to recover and use the heat, such as for heating the building.)

The gas from the heat exchangers is injected with a dry mixture (mostly calcium
carbonate and magnesium oxide) in a venturi mixer that increases the gas velocity and
suspends the injected particles. Dry injection is used to improve pollutant removal in the
baghouse. During the source test, the dry powder injection was turned off to afford better
characterization of uncontrolled emissions and baghouse efficiency for hazardous air
pollutant (HAP) constituents. The gas is then sent to a 10 module, negative pressure baghouse
that uses a high temperature fabric designed to withstand temperatures of up to 320°F. The
temperature of the gas at this point is typically 280 to 290°F. A fan pulls the gas through the
system and discharges the cleaned gases through a stack.

The pressure drop across the baghouse is monitored, and when the pressure drop
increases to six inches of Water, individual bag house compartments are cycled off-line, the
bags are cleaned with a pulses of air, then the compartments are brought back on-line. The
baghouse uses plenum pulsing. During testing, each compartment was off line for
approximately eight minutes for cleaning, with cleaning pulses occurring approximately every
30 seconds during this interval.

The plant routinely monitors several parameters associated with the cupola, including
blast air and oxygen rate, and afterburner air addition rates, as well as temperature at various
points in the process. The combined air flow rate through the recuperator and the baghouse
system is not directly monitored, but can be estimated from the blast air, oxygen and
afterburner air addition rates. During testing, the combined flow rate of offgas was also
measured by the test crew at the final stack sampling location. The plant also records the
amount of each type of material added to the cupola by the automatic skip buckets for each
charge load. The composition of a typical charge is given in Table 3.1 and contains
approximately four tons of iron. The iron includes remelt from the foundry, steel scrap, and
pig iron.

3.2.2 Pouring. Cooling and Shakeout

The plant has four lines for pouring, cooling, and shakeout. Silica sand, bentonite, and
seacoal constitute the molding sand, which is recycled about 50 times prior to disposal in a
monofill. Resins and a catalyst are used to produce warmbox cores. Some of the company's
cast products use cores, and others do not. During the source test, cores were not being used
on any of the lines. The lines are all similar except that Line 4, which is designed to handle
larger molds, has an automatic pouring station and the other lines do not. Line 4 is typically
used for casting the larger size parts.

3-3

-------
TABLE 3.1
TYPICAL CUPOLA CHARGE MATERIALS
Material
Remelt from foundry6
Steel scrap6
Pig ironb
Silicon bricks
Blend bricks (Si, Mn, Cr)
Silicon carbide
Coke
Limestone
Typical range (Ibs/charge)"
3,500 to 4,500
3,200 to 4,000
600 to 1,400
70 to 105
260 to 300
210 to 250
500 to 900
280 to 300
a Typical range observed during the test days.
b Remelt, steel scrap, and gray iron bricks are the sources of iron and total 8,700 Ibs (4.35
tons) per charge.
Pouring emissions are not captured at any of the four pouring stations. Cooling
emissions are captured by hoods that cover the entire cooling line prior to shakeout. The
shakeout operation is totally enclosed and evacuated to capture the emissions. After shakeout,
the parts are transferred to a casting cooling house where they are placed on a metal "tree."
The parts then proceed to a "spinner house" and are shot blasted to remove residual sand. The
spinner house is also evacuated to the duct that removes emissions from shakeout. The
captured emissions from shakeout and cooling are sent to a baghouse for gas cleaning. There
are three baghouse systems; each system predominantly receives emissions vented from a
single line, but a few of the vents from a given line are routed to another line's baghouse
system. Consequently, controlled emissions represent contributions from multiple lines and
multiple processes.

The ductwork for the cooling lines are interconnected with either other cooling lines or
shakeout enclosure ductwork. Therefore, it is impossible to get a representative sample for
cooling emissions that could be attributed to an entire cooling line. The least amount of
interconnection was on Line 4, so it was selected for emissions testing. The first third of the
cooling section of Line 4 was ducted to a single vent that had a long, straight vertical section
before connecting with other ductwork. Ports were installed in this straight section of the
vent, so that the uncontrolled emissions from the first third (approximately 20-25 minutes) of
the cooling line could be measured. The shakeout enclosure ductwork has a short vertical rise,
then elbows to a horizontal section where it is tied to the vent from the spinner housing and
the last hood from the cooling line. Ports were installed in the short vertical duct from the
3-4

-------
shakeout enclosure approximately one foot above the roof of the enclosure prior to the point
where the ducts from the spinner house and the end of the cooling line join the shakeout
enclosure duct. This point represents uncontrolled emissions from the shakeout operations.
3.3 SUMMARY OF PROCESS OPERATING DATA COLLECTED DURING
SOURCE TEST

3.3.1 Process Operating Data for Cupola Melting Operations

Testing of the melting operations was conducted over a three-day period. Single test
runs were performed on September 8th and 9th, and two runs were performed on September
10th. During testing, process information was collected from the operating room's computer
control panel. Process information collected included cupola charging data, process
chemistry, gas flow rates, temperatures, baghouse pressure drop, and cupola stack opacity.

Table 3.2 and Figure 3.2 present metal charging rates for the cupola during the three
days of testing. Table 3.2 and Figure 3.2 show that the average metal production rate for
September 8th was higher than on the 9th or 10th. Table 3.2 and Figure 3.2 also show that
hourly production rates varied significantly within a given day.

Table 3.3 presents average gas flow rates and temperatures for several locations in the
cupola flue gas system on September 8th, 9th, and 10th. As can be seen from Table 3.3, the
average blast rate was lowest on September 9*, and the cupola typically operated with oxygen
addition on that day. On September 8th and 10th, the average blast rate was higher, and oxygen
addition was not used. The average baghouse pressure drop was lower on September 9th than
on September 8* or 10th, (2.8 inches of water versus 4.4 inches of water), and the average
opacity was higher on September 9th than September 10th (5.7% versus 2.8%).

Continuous records of blast air flow rates are presented in Figure 3.3. Blast air rates
were significantly reduced (i.e., the cupola was placed "on relief) for varying lengths of time
on September 9th and 10th. The specific times when the cupola was on relief are listed in
Table 3.4

Table 3.5 presents average process iron chemistry values (from cupola) for September
9th and 10th. Although process chemistry values were not recorded on September 8*, average
trace metal impurity levels were typical on all three days.

3.3.2 Process Operating Data for Pouring. Cooling and Shakeout Operations

Emissions from cooling (first third section) and shakeout were measured on
September 5,1997. Line 4 employs an automated molding machine. Testing was conducted
only when the entire mold line was filled with recently poured molds. During the day of the
source test of the cooling and shakeout operations, Line 4 was used to cast brake drums. Each
mold produced two brake drums, and used 189 pounds of poured metal. For the test day,
3-5

-------
                   TABLE 3.2
SUMMARY OF CUPOLA CHARGING DURING THE TEST DAYS
9/08/97
Time period




11:02-11:57
12:00-12:54
13:00-13:58
14:03-14:55
15:00-15:57




Average rate
(tons/hr)
Tons
charged




45
56
59
51
55




53.2
9/09/97
Time period

8:01-8:56
9:01-9:56
10:02-10:46
11:03-11:50
12:00-12:51
13:00-13:56
14:06-14:55





Average rate
(tons/hr)
Tons
charged

47
52
42
35
26
58
30





41.4
9/10/97
Time period
7:01-7:56
8:03-8:54
9:01-9:59
10:04-10:55
11:01-11:57
12:03-12:59
13:03-13:41
14:02-14:58
15:01-15:28
16:13-16:56
17:00-17:56
18:01-18:57
19:02-19:58
Average rate
(tons/hr)
Tons
charged
48
35
49
47
54
59
40
35
32
45
51
56
55
46.6
                     3-6

-------
|8-Sep  B9-Sep  Q10-Sep
                   Figure 3.2. Hourly Melting Rates During Cupola Testing

-------
                          TABLE 3.3
    PROCESS DATA DURING THE DAYS OF CUPOLA TESTING
Process Parameter
Average Value on Testing Date
September 8
September 9
September 10
Cupola process air flow information
Blast rate (scfin)
Oxygen addition (on/off)
Temperature in (F)
Temperature out (F)
14,794
off
1,156
330
9,131
on
1,067
232
13,665
off
1,101
297
Afterburner air flow information
Primary air (scfin)
Secondary air (scfrn)
Cooling air (scfin)
Temperature out (F)
5,271
5,893
2,794
1,717
2,764
2,823
2,300
1,639
4,969
5,476
2,792
1,668
Baghouse information
Temperature in (F)
Pressure drop (inches
H20)
Opacity (%)
297
4.4
Not Recorded
281
2.8
5.7*
299
4.4
2.8f
TAverage of opacity readouts recorded every 15 minutes; opacity readouts are
6-minute averages from KVB EPA-2 stack mounted opacity monitor
                             3-8

-------
OJ
I
J5,


2

I
5:

'5


I
CD
18000




16000




14000




12000




10000




 8000




 6000




 4000




 2000
                                                                                              .8-September



                                                                                              , 9-September



                                                                                               10-September
                         6:00  7:00  8:00  9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 0:00


                                                              Clock time (hours:minutes)
                                                    Figure 3.3. Blast Air Flow Rate Through Cupola

-------
                    TABLE 3.4
PERIODS WHEN CUPOLA WAS "ON RELIEF" DURING TESTING.
September 8
Continuous blast



September 9
10:54-11:09



September 10
13:51 - 14:04
14:11-14:28
15:27-16:03
16:06-16:08
                       3-10

-------
                                  TABLE 3.5
                  PROCESS IRON CHEMISTRY AT CUPOLA."
Element
ElCe
(Elemental Carbon Equivalents)
CalcC
(Calculated Carbon)
Si
Mn
P
S
Ni
Mo
Cr
Cu
Al
Ti
Sn
Mg
V
Pb
Concentration (%)
September 9
3.665
2.470
1.050
0.350
0.055
0.070
0.045
0.105
0.205
0.114
0.008
0.009
0.005
0.006
0.006
0.001
September 10
4.045
3.450
4.490
0.595
0.042
0.090
0.090
0.025
0.240
0.230
0.009
0.011
0.009
0.001
0.011
0.002
a The process chemistry values reported here are considered typical; the process chemistry
values were not specifically recorded on September 8, but were also considered typical.
                                     3-11

-------
249 molds per operating hour were produced. Each mold contains 1393 Ibs of green sand
(lake sand, sea coal, and bentonite), so the molds had a sand to metal ratio of 7.35:1.

       The properties of the molding sand measured during the test day are given in Table
3.6. A bonding agent was added to the sand in the amount of 38.1 pounds of bond per ton of
sand mulled.  The bonding agent is a dry mixture of coal, brittle asphalt, cellulose, bentonite,
starch, and cereal. The material safety data sheet for the product indicates no volatile
components, and no hazardous ingredients other than coal dust and crystalline quartz.
                                    TABLE 3.6
              TYPICAL RESULTS FROM GREEN SAND ANALYSIS
Property
Moisture (%)
Clay (%)
Loss on ignition (%, at 1800°F)
Volatile content (%, at 900 °F)
Value
3.5
8.7
7.8
4.0
                                       3-12

-------
4.0 SAMPLING LOCATIONS
Isokinetic source sampling was conducted at the inlet and outlet of the cupola
baghouse at the Waupaca Foundry. Descriptions of the sampling locations are presented
below, as well as schematic diagrams.
4.1 CUPOLA BAGHOUSE INLET

The cupola baghouse inlet measurement site was located in a 553/s-inch inside
diameter (ID) round, horizontal duct 50 feet (10.8 duct diameters) downstream of the nearest
flow disturbance (45° bend) and 23 feet 9!/2 inches (5.2 duct diameters) upstream of the
nearest flow disturbance (90° elbow). According to EPA Method 1 criteria this site required a
minimum of 12 sample traverse points, six along each of two perpendicular diameters. Figure
4.1 shows a simplified schematic of the baghouse inlet measurement site. Figure 4.2 shows
the sample traverse point locations. A check for the presence of non-parallel flow was
conducted as specified in Section 2.4 of EPA Method 1. The check confirmed the average
yaw angle for the horizontal port was 13.8 degrees, which is less than the Method 1
requirement of 20 degrees.
4.2 CUPOLA BAGHOUSE OUTLET

The baghouse outlet sampling location was located in a 92-inch ID round vertical stack
25 feet (3.3 stack diameters) downstream of the nearest flow disturbance (expansion joint) and
89 feet (11.6 stack diameters) upstream of the stack exit. According to EPA Method 1, this
location required 24 sample traverse points, 12 along each of two perpendicular diameters.
Six points were sampled, at each of four sample ports, located at 90°. Figure 4.3 shows a
simplified schematic of the baghouse outlet measurement site. Figure 4.4 shows the sample
traverse point locations.

PES checked for the presence of non-parallel flow in all four sampling ports during a
preliminary site visit and just prior to sampling. The average of the 24 sampling points yaw
angles was found to be 15.3 degrees, requiring no modifications for isokinetic sampling.
4-1

-------
                                                   Two Sample
                                                      Ports
                                                                     Section A - A
to
                                                                                                     To Baghouse
                                     Dry Injection
                                      Chamber
                                       Figure 4.1 Cupola Baghouse Inlet Sampling Location,
                                                 The Waupaca Foundry - Tell City, Indiana

-------
Two
Ports
                            Section A - A
              Traverse Point
                Number
  Distance from
Stack Wall, inches
1
2
3
4
5
6
2'/2
81/8
16%
39
47 '/4
527/s
       Figure 4.2  Cupola Baghouse Inlet Traverse Point Locations,
                  The Waupaca Foundry - Tell City, Indiana
                                 4-3

-------
Roof
Four Sample
Ports

>
|1
8
>
t
>.
2
_>


V

)'
f
k T
B
5'
f
^V
Section B - 1



o


A

J
I! < CEM


^
B

\
        Figure 4.3 Cupola Baghouse Outlet Sampling Location,
                 The Waupaca Foundry - Tell City, Indiana
                              4-4

-------
                      Section B - B
Traverse Point
Number
1
2
3
4
5
6
Distance from
Stack Wall, inches
!7/8
63/16
10?/8
16 V, 6
23
3213/.6
Figure 4.4 Cupola Baghouse Outlet Traverse Point Locations,
          The Waupaca Foundry - Tell City, Indiana
                          4-5

-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES
Table 5.1 summarizes the sources, test parameters, test methods, number of tests, and
net run times. Simultaneous, isokinetic, sampling was conducted at the cupola baghouse inlet
and outlet for PM/metals. Simultaneous with the PM/metals testing, additional isokinetic
sampling was conducted at the cupola baghouse outlet for PCDDs/PCDFs and SVOHAPs.
Brief descriptions of the methods used follow:
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS

EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
select the measurement sites and to establish velocity and sample traverse point locations.
The location of measurement sites and traverse points are discussed in Section 4.0.
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE

EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate
(Type S Pitot Tube)," was used to determine stack gas volumetric flow rate at the cupola
baghouse inlet and outlet. A Type S pitot tube, constructed according to Method 2 criteria and
having an assigned coefficient of 0.84 and connected to an inclined-vertical manometer was
used to measure velocity pressure. A calibrated Type K thermocouple attached directly to the
pitot tube was used to measure stack gas temperature. The average stack gas velocity was
calculated from the average square roots of the velocity pressure, average stack gas
temperature, stack gas molecular weight, and absolute stack pressure. The volumetric flow
rate is the product of velocity and the stack cross-sectional area.
5.3 DETERMINATION OF DRY MOLECULAR WEIGHT AND EMISSION
CORRECTION FACTORS

EPA Method 3B, "Gas Analysis for the Determination of Emission Rate Correction
Factor or Excess Air," was used to measure carbon dioxide and oxygen content of the stack
gases. Gas samples were extracted from the stack or duct simultaneous with the EPA Method
23 sample trains using the multi-point, integrated bag sampling technique. The bag contents
were analyzed on-site within four hours after sample collection using an Orsat® analyzer to
5-1

-------
                    TABLE 5.1
SOURCES, TEST PARAMETERS, AND TEST METHODS SUMMARY
      THE WAUPACA FOUNDRY - TELL CITY, INDIANA

Source
Cupola Baghouse Inlet



Cupola Baghouse Outlet






Parameter
Flow Rate
O2/C02
Moisture
PM/Metals
Flow Rate
O2/CO2
Moisture
PM/Metals
PCDDs/PCDFs
SVOHAPs
Test
Methods
EPA 1 & 2
EPA3B
EPA 4
EPA 29
EPA 1 & 2
EPA3B
EPA 4
EPA 29
EPA 23
SW-846 0010
No. of
Tests
3
3
3
3
3
3
3
3
3
3
Net Run Time,
Minutes
240
240
240
240
240
240
240
240
240
240
                       5-2

-------
determine percent concentrations of carbon dioxide and oxygen. The Orsat® analyzer had 0.1
percent subdivisions.
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT

EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine stack gas moisture content. The quantity of condensed water was determined
gravimetrically and then compared to the total volume of gas sampled to determine the
volume percent moisture content. The Method 4 procedure was conducted in conjunction the
EPA Methods 23 and 29 and SW-846 Method 0010 sampling runs. Condensed moisture was
determined by the difference in pre-test and post-test weights of the impingers, reagents, and
silica gel. Condensed moisture in the XAD® adsorbent trap from the SW-846 Method 0010
and EPA Method 23 sample trains was also determined gravimetrically and the results
included in the moisture content calculations.
5.5 DETERMINATION OF PARTICULATE MATTER AND METALS

EPA Method 29, "Determination of Metals Emissions From Stationary Sources," was
used to determine filterable particulate matter and metals at the cupola baghouse inlet and
outlet. The target metals included: antimony (Sb), arsenic (As), barium (Ba), beryllium (Be),
cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb), manganese (Mn), mercury (Hg), nickel
(Ni), phosphorus (P), selenium (Se), silver (Ag), thallium (Tl), and zinc (Zn). Multi-point
integrated samples were extracted isokinetically from the 12 traverse points at the inlet and 24
traverse points at the outlet as shown in Figures 4.2 and 4.4, respectively. At each traverse
point, sampling was performed for 10 minutes at the inlet and five minutes at the outlet for a
total run time of 240 minutes per test. At each location, readings were taken every five
minutes. The samples were extracted through a glass nozzle, a heated glass-lined probe, a
heated quartz fiber filter, two impingers containing an acidic hydrogen peroxide solution
(H2O2/HNO3), an empty impinger, and two impingers containing acidic potassium
permanganate (KMnO4). A schematic of the EPA Method 29 sampling train is shown in
Figure 5.1. The inlet sampling train was modified to allow for vertical sampling. A heated
Teflon® jumper was used between the probe exit and the heated filter. The nozzle was
attached to the probe using Teflon® or Teflon® coated unions and Teflon® or graphite ferrules.

The sample recovery scheme for metals is shown in Figure 5.2. Note that the optional
empty first impinger was not used.

The filter and acetone rinses of the probe and front half of the filter housing were
analyzed gravimetrically in the PES laboratory to determine filterable particulate matter.
Upon completion of the particulate matter analyses, the particulate fractions and aqueous
fractions were submitted to TLI for metals analyses. The sample preparation and analysis
scheme is shown in Figure 5.3. Metals other than Hg were analyzed by graphite furnace
5-3

-------
Glass Probe
   Tip
                  Figure 5.1 Sampling Train Schematic for EPA Method 29,

-------
Probe Untr
•nd Nozzle
RkwewHh
acetone
Brush finer
with nonmetaUc
(truth & rin««
with acetone
Check Iner to •••
If partial*!*
removed; tf not.
r*p*mt tMp above
Front H« of
Filer Homing
BnwhwKh
nonmataHc bru»h
•nd rtme with
acetone
  FIMr
 Fttar Support
 and Back HaV
ofFlMrHoutlng
                RblM on,
ramovamar      tknaawllh
from aupport      0.1N HNO3
with Teflon-
coated tweezers
and place In
petridlih
let Impfeigar
 (Empty at
 beginnhfl
  oftaal)
      I
  MMMfl
  knplngtr
  content*
 2nd ASrd
  Impkiger*
(HN03/H202)
                                            Meaeur*
                                            knpkiBor
                                            contents
                                                perticulate
                                                onto tiller
                        Seal petrl dl*h
                        with tip*
 Rlne* three
 lime* with
 0.1 N HNO3
 Rhie* three
 limaawKh
 0.1N HNO3
  4th Impbigcr
 (Empty)* 5th
•nd 6th Implngara
(Addlflwt KMnO4)
                                Maeiur*
                                lmplna*r
                                content*
                                                            Empty th*
                                                            content* Into
                                                            container.
                                                             Rfciea three
                                                             tlmeawlth
                                                             0.1N HNO3
                                            Empty th*
                                            content* into
                                            container
                                                                      Empty th*
                                                                      hnplngvrNo. 4
                                                                      content* Into
                                                                      container
                                                          Rlnaa three
                                                          time* wBh
                                                          0.1N HNO3
                FH
                (3)'
                  AR
                  (2)
     F
    (D
                                                                      Rime with
                                                                        100ml
                                                                      0.1 N HNO3
                                                                Empty the
                                                                Implngara
                                                                No*. S ft a
                                                               content* Into
                                                                 container
                                                                                    Rlna* three
                                                                                     time* with
                                                                                   permanganate
                                                                                    reagent, then
                                                                                     with water
                                                                                                                Lait bnplngw
                                                                                                                                                                  Weigh for
                                                                                                                                                                   moisture
                                                            Olicerd
                                                                                                   Remove any
                                                                                                   reildue with
                                                                                                    2Sml8N
                                                                                                   HCI eokjllon
                                                                                                       I	
                          BH
                          M)
                                   0.1 N HNO3
                                      (8A)
                                   KMn04
                                     (SB)
                               8NHCI
                                (SC)
• Number to perenlne*** bidlcat** container number
                                                           Figure 5.2 EPA Method 29 Recovery Scheme.

-------
                              Container 3
                           Add Probe RkiM
                             (Labeled FH)
    Container 2
Acetone Probf RklH
   (Labeled AR)
Container 1
   Filer
(Labeled F)
                                                Reduce la diyneee
                                                 In e teretf beaker
                                                Determine reeldue
                                                 weight In beaker
                                                 Solublttze reildue
                                                 wllh cone. HNO3
                         Determine filler
                        partleulate weight
      Container 4
(HN03AU02) knplnflen
     (UbeledBH)

    Implnger.lfuaad)
           I
                                                                                                                                              Container* 6A. SB, * 8C


AHquot taken
forCVAAS
forHganalyda
Anal. Fraction 2B



Dlgeatwffii «dd
and permanganata
al8SCfor2h
and analyze
forHgbyCVAAS

1
Acidify
remaining
eample to pH 2
with cone. HMOS
Anal. Fraction 2A
1
Reduce volume
toneardryneae
anddlgettwIOi
HN03 ft H202
1
                             Acidify to pH 2
                            with cone. HNO3
ON
                         DMde Into O.S g
                         aecOona & dlgeat
                         each ••ctlon with
                         cone. HF A HNO3
                            Reduce volume to
                            near drynaaa and
                             digest with HF
                             ft cone. HNO3
                                                  Fitter ft dilute
                                                 to known volume
                                                 Anal. Fraction 1
                                          _L
                                  Analyze by (CAP for
                                     target metala
                                   Anal. Fraction 1A
                Analyze for
             metala by GFAAS*
             Anal. Fraction 1A
                                    Remove 60 to 100 ml
                                        aliquot for Hg
                                      analyalabyCVAAS
                                    Analytical Fraction 1B
                                                                      Individually, three
                                                                   (operate digestion*
                                                                        and analyaes:
                                                                      dlgeat with add
                                                                    •nd permanganate
                                                                        •tesctor2h
                                                                         and analyze
                                                                      forHgbyCVAAS
                                                                   Analytical Fraction*
                                                                           3A. 3B. ft 3C
                                                  Analyze
                                                 by (CAP (or
                                              IS target metala
                                                                           Analyze by
                                                                             6FAAS
                                                                            for Metal*'
                                                                                                                DlgeetwRh add and
                                                                                                               permanganate ates C ki
                                                                                                                 a water bath for 2 h
                                       Analyze ajquol for
                                        Hg uabip CVAA8
                        •Analytli by AAS for metal* found el leu than 2 ug/ml ki dkjettata solution.
                        Vdaalred. Or analyze for (sen m»UI by AAS, IT doired.
                                         Figure 5.3 Sample Preparation and Analysis Scheme for EPA Method 29.

-------
atomic absorption spectroscopy (GFAAS) or inductively coupled argon plasma (ICP) emission
spectroscopy. Hg was analyzed by cold vapor atomic absorption spectroscopy (CVAAS).
5.6 DETERMINATION OF DIOXINS AND FURANS

EPA Method 23, "Determination of Polychlorinated Dibenzo-p-Dioxins and
Polychlorinated Dibenzofurans from Stationary Sources" was used to determine
PCDDs/PCDFs at the cupola baghouse outlet. The proposed rules amending EPA Method 23,
as published in the Federal Register, Volume 60, No. 104, May 31,1995, were incorporated.
The proposed changes correct existing errors in the method, eliminate the methylene chloride
rinse, and clarify the quality assurance requirements of the method. Samples were extracted
through a glass nozzle, a heated glass-lined probe, a pre-cleaned and heated glass fiber filter, a
water cooled condenser coil and an adsorbent trap containing approximately 40 grams of
XAD®-2 adsorbent resin. A schematic of the EPA Method 23 sampling train (which is the
identical to the SW-846 Method 0010 train) is shown in Figure 5.4. Multi-point integrated
samples were extracted isokinetically from the 24 traverse points shown in Figure 4.4. At
each traverse point, sampling was performed for 10 minutes, with pertinent readings taken
every five minutes, for a net run time of 240 minutes per test. TLI prepared the filters and
adsorbent traps, and performed the required analyses.
5.7 DETERMINATION OF SEMIVOLATILE ORGANIC HAZARDOUS AIR
POLLUTANTS (SVOHAPs)

Method SW-846 0010, "Modified Method 5 Sampling Train (MM5)," was used to
collect SVOHAPs at the cupola baghouse outlet. Multi-point, integrated samples were
extracted isokinetically from the 24 traverse points shown in Figure 4.4. At each traverse
point, sampling was performed for 10 minutes for a total run time of 240 minutes per test.
Readings were taken every five minutes. The SW-846 Method 0010 samples were extracted
through a glass nozzle, a heated glass-lined probe, a precleaned and heated glass fiber filter, a
water-cooled condenser coil and a adsorbent trap containing approximately 40 grams of
XAD®-2 adsorbent resin. A schematic of the SW-846 Method 0010 sampling train is shown
in Figure 5.4.

The SW-846 Method 0010 samples were extracted following the procedure of Method
3542, dated January, 1995. The extracts were analyzed in accordance with the guidelines of
Method 8270A by High Resolution Gas Chromatography/Low Resolution Mass Spectrometry.
The three sample fractions for each test run, i.e., front half extract, the back half extract
(XAD®-2 and back half rinse), and the condensate extract were combined for one analysis, per
test run. The samples were analyzed for the SW-846 Method 8270 polynuclear aromatic
hydrocarbon (PAH) and Clean Air Act (CCA) semivolatile compounds.
5-7

-------
oo
                                              Temperature
                                                 Sensor
                                    Slack
                       Button Hook
                         Nozzle
Nozzle     V
Heated Glass
   Liner
                                tn.  u ...      Condenser   XAD
                                Filter Holder         I       Trap
                                                                     Temperature
                                                                       Sensor
                      Gas
                     Flow
                           TypeS
                           Pilot Tube
                                        Inclined
                                      Manometer
                                  Gas
                                                 Orifice
                                          Manometer
                                      ..Sensors
                                        Empty 100 ml HPLC Water Empty Silica Gel
                                                                Vacuum
                                                                 Gauge
                           Figure 5.4  Sampling Train Schematic for EPA Method 23 and SW-846 Method 0010.

-------
6.0 QUALITY ASSURANCE/QUALITY CONTROL
PROCEDURES AND RESULTS
This section describes the specific QA/QC procedures employed by PES in performing
this series of tests. The procedures contained in the "Quality Assurance Handbook for Air
Pollution Measurement Systems, Volume III, Stationary Source Specific Methods,"
EPA/600/R-94/038c, and in the reference test methods served as the basis for performance for
all testing and related work activities in this project.
6.1 CALIBRATION OF APPARATUS

The preparation and calibration of source sampling equipment is essential in
maintaining data quality. Brief descriptions of the calibration procedures used by PES follow.

6.1.1 Barometers

PES used aneroid barometers which are calibrated against a station pressure value •
reported by a nearby National Weather Service Station corrected for elevation.

6.1.2 Temperature Sensors

Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in Section 3.4.2 of the Quality Assurance Handbook, Volume III, 1994.
Each temperature sensor was calibrated over the expected range of use against an ASTM 3C
or 3F thermometer. Table 6.1 summarizes the type of calibrations performed, the acceptable
levels of variance, and the results. Digital thermometers were calibrated using a thermocouple
simulator having a range of 0-2400 °F.

6.1.3 Pitot Tubes

Type S pitot tubes constructed to EPA Method 2 specifications were used. Pitot tubes
meeting these specifications are assigned to a baseline coefficient to 0.84 and need not be
calibrated. The dimensional criteria and results for each pitot tube used are summarized in
Table 6.2.
6-1

-------
                   TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
Temp.
Sensor
I.D.
5C


4B



4C



T5B



RMB-13





MB- 13





Usage
Stack Gas


Stack Gas



Stack Gas



Stack Gas



Meter Box
Inlet

Outlet


Meter Box
Inlet

Outlet


Temperature, °F
Reference
38
102
168
32
70
203
440
32
73
191
434
32
72
199
408
34
76
150
34
76
150
31
70
145
32
70
150
Sensor
38
101
169
31
72
204
438
34
71
190
430
32
71
201
412
35
76
149
35
75
151
32
70
147
31
70
151
Temperature
Difference
0.0%
0.2%
-0.2%
0.2%
-0.4%
-0.2%
0.2%
-0.4%
0.4%
0.2%
0.5%
0.0%
0.2%
-0.3%
-0.5%
1 °F
0°F
1 °F
1 °F
1 °F
1 °F
1 °F
0°F
2°F
-1 °F
0°F
1 °F
Tolerances
-------
               TABLE 6.2
SUMMARY OF PITOT TUBE DIMENSIONAL DATA
Measurement
«1
«2
PI
p2
Y
0
A
Z
w

D,
A/2D,
Criteria
<10°
<10°
<5°
<5°
-
-
-
s 0.125 in.
<. 0.03125
in.
0.1875" <;
D, * 0.375"
1.05D,*
A<; 1.50D,
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
5C
2.5
-2.5
1
1
2.5
0
1.013
0.044
0

0.370
1.37
Yes
0.84
5E
0
1
2
3
1
0
1.104
0.019
0

0.375
1.47
Yes
0.84
4B
2
1
0
1
0
1
0.947
0
0.017

0.375
1.26
Yes
0.84
4C
4
4
1
0
0
0
0.956
0
0

0.375
1.27
Yes
|_ 0.84
                 6-3
-------
6.1.4  Differential Pressure Gauges

       PES used Dwyer inclined/vertical manometers to measure differential pressures.  The
differential pressures measurements included velocity pressure, static pressure, and meter
orifice pressure. Manometers are selected with sufficient sensitivity to accurately measure
pressures over the entire range of expected values. Manometers are primary standards and
require no calibration.

6.1.5  Dry Gas Meters and Orifices

       The SW-846 Method 0010 and EPA Method 23 and 29 dry gas meters and orifices
were calibrated in accordance with Sections 5.3.1 and 5.3.2 of EPA Method 5. This procedure
involves direct comparison of the dry gas meter to a reference dry test meter.  The reference
dry test meter is calibrated annually using a wet test meter. Before its initial use in the field,
the metering system was calibrated over the entire range of operation as specified in EPA
Method 5.  After field use, the metering system was calibrated at a single intermediate setting
based on the previous field test. Acceptable tolerances for the initial and final dry gas meter
factors and orifice calibration factors are ± 0.05 and ± 0.20 from average, respectively. The
results for the gas meter and orifice used in this test program are summarized in Table 6.3.
6.2    ON-SITE MEASUREMENTS

       The on-site QA/QC activities include:

6.2.1  Measurement Sites

       Prior to sampling, the stack and inlet duct were checked dimensionally to determine
measurement site locations, location of velocity and sample test ports, inside stack/duct
dimensions, and sample traverse point locations. Inside stack/duct dimensions were checked
through both traverse axis to ensure uniformity of the stack/duct inside diameter. The inside
stack/duct dimensions, wall thickness, and sample port depths were measured to the nearest
1/16 inch.

6.2.2  Velocity Measurements

       All velocity measurement apparatus were assembled, leveled, zeroed, and leak-
checked prior to use and at the end of each determination. The static pressure was determined
at a single point near the center of the stack or duct cross-section.

6.2.3  Flue Gas Composition

       Integrated, multi-point, flue gas samples were collected in Tedlar® gas bags from the
baghouse inlet and outlet. Prior to use the bags were leak checked and purged with nitrogen to
ensure cleanliness. Prior to and after completion of each sampling run the entire sampling
                                         6-4
-------
                      TABLE 6.3
SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
Meter
No.
M5-3
M5-4
RMB-13
MB-13
Gamma
Pre-test
1.028
1.021
1.010
0.947
Post-test
1.060
1.049
0.994
0.945
% Diff.
3.1
2.7
-1.6
0.2
EPA Criteria
±5%
±5%
±5%
±5%
Orifice Coefficient
Average
1.591
1.662
1.884
1.762
Range
1.555-
1.621
1.653-
1.674
1.875-
1.894
1.760-
1.765
EPA Criteria
1.591 ±0.20
1.662 ± 0.20
1.884 ± 0.20
1.762 ± 0.20
                        6-5
-------
system was leak checked from the tip of the probe. The bag samples were analyzed on-site
using an Orsat® analyzer within four hours after sample collection, hi accordance with EPA
Method 3B. Prior to use the Orsat® analyzer was assembled and replenished with fresh
reagents and leak checked using the manufacturer's procedures.

6.2.4  Moisture

       The SW-846 Method 0010 and EPA Methods 23 and 29 sampling trains were used to
determine the flue gas moisture content.  During sampling, the exit gas of the last impinger
was maintained below 68 °F to ensure complete condensation of flue gas water vapor.  The
total moisture was determined gravimetrically using an electronic platform balance with 0.1
gram sensitivity.  The XAD® adsorbent modules from the EPA Method 23 and SW-846
Method 0010 sampling trains were also weighed and their weights included in the moisture
catch.

6.2.5  Method 23. Method 0010 and Method 29

       The field sampling QA/QC for EPA Methods 23 and 29 and SW-846 Method 0010
were similar.  Table 6.4 summarizes the critical measurements made and the EPA's
acceptability criteria. All pre- and post-test sample train leaks met the acceptance  criteria.
The isokinetic sampling rates deviated by no more than 6.5% thereby meeting each method
criteria of 90-110%.

       EPA Methods 23 and 29 and SW-846 Method 0010 field blanks were  collected near
each of the sampling locations to check for any sample contamination at the sites.  Sample
trains were assembled and pre- and post-test leak checks were conducted. The sample trains
were recovered in the same manner as the actual sample runs. Each field blank train was
subjected to a minimum of one leak check in the laboratory and three to five at the sampling
site, depending on the location.

       An acetone blank and quartz fiber filter were taken as control samples for the
particulate analysis and subsequent analysis for the target metals. Blanks were taken of the
metals absorbing and recovery reagents.
6.3    LABORATORY ANALYSES

6.3.1  Particulate Matter

       Particulate matter analysis consisted of front half acetone sample rinses and quartz
fiber filters.  Prior to the field testing program, the filters were tared in the PES (or DEECO)
laboratory, stored in petri dishes, and sealed with Teflon® tape. Several beakers were also
cleaned and tared for subsequent use in evaporating the acetone rinses. Upon receipt in the
PES laboratory, the acetone rinses were placed in the tared beakers and evaporated to dryness
at room temperature. The filters and beakers were desiccated and weighed to a constant
                                        6-6
-------
weight. All weighings were within the method requirements of 0.5 milligrams between two
consecutive weighings taken at least six hours apart.

6.3.2 EPA Method 29

       TLI analyzed the EPA Method 29 samples consisting of five stack gas samples, three
blank samples and reagent blanks to determine concentrations of antimony (Sb), arsenic (As),
barium (Ba), beryllium (Be), cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb),
manganese (Mn), mercury (Hg), nickel (Ni), phosphorus (P), selenium (Se), silver (Ag),
thallium (Tl), and zinc (Zn). All metals, except Hg and some Tl concentrations, were
determined by inductively coupled plasma emission spectroscopy (ICP). Thallium
concentrations for the back half samples and some front half samples (refer to the TLI case
narrative for an exact listing of the samples) were determined using graphite furnace atomic
absorption (GFAA). Specific TLI QA/QC activities for GFAA and ICP analyses consisted of:
laboratory control spikes, post-digestion matrix spikes of one sample set, duplicate analysis of
one sample set, serial dilution and analysis of one sample set, analysis of a method blank, and
analysis of field and reagent blanks.  Mercury was analyzed by cold vapor atomic absorption
spectroscopy (CVAAS).  Specific TLI QA/QC activities for CVAAS analyses consisted of
analysis of a method blank and analysis of field and reagent blanks.  The results of these
QA/QC activities are summarized in Tables 6.5 through 6.14. Complete QA/QC data are
contained in the TLI analytical report in Appendix C.

6.3.3 EPA Method 23 PCDDs/PCDFs

       Prior to the field testing program, TLI prepared PES' XAD®-2 adsorbent traps and
precleaned the glass fiber filters.  TLI's laboratory QA/QC program consisted of adding
isotopically labeled standards to each sample at various stages of the project to determine
recovery efficiencies. The following types of standards were used:

       Internal Standards were spiked in the TLI laboratory after the field sampling program
       and prior to sample extraction. Recovery efficiencies for these compounds were used
       in quantifying the actual PCDDs/PCDFs isomers measured in the samples.

       Surrogate Standards were spiked in the TLI laboratory on the XAD®-2 resin prior to
       the field sampling program. Recovery efficiencies for these surrogate compounds
       provided a measure of the sample collection efficiency and an indication of any
       analytical matrix effects.

       Alternate Standards were spiked in the TLI laboratory after the field sampling program
       and prior to sample extraction. Recovery of these compounds indicated the extraction
       efficiencies.

       Recovery Standards were added in the laboratory after extraction just prior to GC/MS
       analysis.
                                        6-7
-------
       Table 6.15 summarizes the recovery efficiencies for the various standards and the
respective quality control limits. In general, the recovery efficiencies for the XAD® blank,
field blank, and samples were all within the method QC limits. Refer to TLI's case narrative
for their discussion of any quality control anomalies.

6.3.4 SW-846 Method 0010

       TLI analyzed the SW-846 Method 0010 samples following the procedures of
SW-846 Method 8270A Rev. 1 (7/92). Field blanks and laboratory blanks were used to check
for contamination.  The blanks were processed in the same way the field samples were
processed.  The results of the field and laboratory blanks are presented in Table 6.16. Also
shown are the average catch weights for the compounds presented. The significance of the
blank values was discussed in Section 2.

       A five point initial calibration was performed using internal standards and instrument
response factors developed for the target analytes. Method 8720A procedures require the
percent standard deviations of the initial calibrations to be within 50% for most analytes and
30% for some analytes. All internal standards were within the Method 8270A quality control
criteria. The XAD®-2 resins were spiked with surrogate standards prior to the field sampling.
The percent recoveries for the surrogate standards are presented in Table 6.17. Refer to TLI's
case narrative for their explanation of the high terphenyl-d,4 recoveries.
                                         6-8
-------
                                         TABLE 6.4
        SUMMARY OF EPA METHODS 23 AND 29 AND SW-846 METHOD 0010 FIELD SAMPLING QA/QC DATA
Date
09/09/97

09/10/97



Site
Baghouse Inlet
Baghouse Outlet
Baghouse Inlet
Baghouse Outlet


Run No.
I-M29-1
O-M29-1
BO-23-1
BO-0010-1
I-M29-2
I-M29-3
O-M29-2
O-M29-3
BO-23-2
BO-23-3
BO-0010-2
BO-0010-3
Pre-Test
Leak Rate
acfm
0.002 @10"Hg
< 0.001 @1 1.5" Hg
0.002 @1 5" Hg
0.008 @1 5" Hg
0.003 @ll"Hg
0.008 @ 13" Hg
0.007 @ll"Hg
< 0.001 @ll"Hg
0.001 @ 15" Hg
0.005 @ 15" Hg
0.010 @ 15" Hg
0.004 @ 15"Hg
Post-Test
Leak Rate
acfm
0.015@6"Hg
< 0.001 @ 8.5" Hg
0.001 @ 8" Hg
0.003 @ 14" Hg
0.002 @1 7" Hg
0.002 @ 5" Hg
0.004 @ 8" Hg
0.002 @ 12" Hg
0.004 @ 15" Hg
0.007 @ 12" Hg
0.008 @ 15" Hg
0.003 @ 11" Hg
EPA
Criteria
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
Percent
Isokinetic
104.0
103.1
98.9
99.4
102.7
106.5
102.2
99.7
99.7
98.5
97.3
102.6
EPA
Criteria
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
a\
-------
                TABLE 6.5
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
           LAB CONTROL SPIKES
Analyte
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Spike Amt
%g/L
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
LCS Recovery
94%
99%
100%
96%
101%
99%
101%
100%
102%
103%
97%
102%
98%
100%
101%
ICP LCS Recovery^
86%
89%
93%
91%
92%
94%
94%
95%
91%
90%
93%
94%
89%
83%
96%
Recovery Limits
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
                  6-10
-------
                TABLE 6.6
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
      MATRIX SPIKES (POST-DIGESTION)

Analyte
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Spike Amt //g
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
Percent Recovery*
Run No. M29-1-FH
91%
90%
99%
91%
97%
93%
101%
SL
98%
0%
SL
90%
90%
47%
SL
Run No. M29-2-FH
74%
99%
93%
87%
91%
89%
92%
SL
97%
98%
SL
97%
91%
93%
SL

Recovery Limits
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
* SL = Spike Low, % Recovery is not considered valid when spike amount is less than 20%
of recovered amount.
                  6-11
-------
                TABLE 6.7
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
           DUPLICATE ANALYSES
Analyte
Sample //g
Duplicate //g
RPD
RPD Limits
Run I-M29-2-FH
As
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
5.05
2.96
27.2
0.148
29.9
0.510
15.4
1.260
5.14
42.0
1.490
10.6
1.88
0.310
8.480
5.05
3.36
27.4
0.148
29.9
0.499
15.5
1.250
5.20
42.5
1.490
10.7
1.83
NA*
8.510
0%
-------
            TABLE 6.7 (Concluded)

SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
           DUPLICATE ANALYSES
Analyte
Sample //g
Duplicate //g
RPD
RPD Limits
Run I-M29-2-BH
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
0.181
< 0.639
1.95
< 0.128
0.142
< 0.128
2.40
10.0
0.480
15.6
12.2
< 0.511
0.820
< 0.256
58.7
0.194
< 0.639
1.94
< 0.128
0.157
< 0.128
2.29
9.99
< 0.383
16.5
12.3
< 0.511
0.656
NA*
58.7
-------
                TABLE 6.8
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
             SERIAL DILUTION
Analyte
Sample yug
Serial Dilution /ug
RPD*
RPD Limits
RunI-M29-l-FH
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
1.06
0.744
5.15
< 0.100
286
< 0.100
4.14
158
5.04
10.6
191
2.37
0.856
< 0.200
1.140
1.12
<2.50
5.27
< 0.500
2.83
< 0.500
6.32
164
6.44
15.8
201
4.10
1.77
NA**
1.200
-------
            TABLE 6.8 (Concluded)

SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
             SERIAL DILUTION
Analyte
Sample //g
Serial Dilution //g
RPD*
RPD Limits
RunI-M29-l-BH
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
0.143
< 0.661
0.455
< 0.132
0.413
< 0.132
2.48
1.31
0.778
14.6
3.27
0.741
2.00
< 0.265
20.0
< 0.661
<3.31
<1.32
< 0.661
< 0.661
< 0.661
3.12
1.36
<1.98
19.9
3.12
<2.65
2.33
NA**
21 3
-------
                TABLE 6.9
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
         METHOD BLANK RESULTS
Analyte
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Detection
Limit
yUg/L
1
5
2
1
1
1
2
2
3
30
2
4
3
2
12
MB 1 Recovered
Amount ^g/L
0.01
0.21
0.13
0.30
-0.19
-0.08
0.23
0.80
0.77
3.21
-0.07
0.50
0.10
1.20
22.53
MB 2 Recovered
Amount Mg/L
-0.04
-1.68
-0.04
-0.81
-0.24
-0.53
0.07
2.84
-1.13
-13.83
1.67
-0.82
0.23
-5.52
9.79
The Method Blank is considered a "Pass" when the recovered amount is
less than the detection limit.
                  6-16
-------
                TABLE 6.10
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
          FIELD BLANKS RESULTS
Analyte
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Inlet Front
Half,/zg
7.23
3.26
50.3
< 0.100
172
3.55
32.9
34.4
19.0
125
597
5.37
4.47
< 0.500
166
Inlet Back
Half^g
0.485
< 0.500
0.357
< 0.100
4.07
< 0.100
1.89
1.21
1.07
6.98
18.9
0.594
1.01
0.490
16.8
Outlet Front
Half, MS
0.190
1.51
62.5
< 0.100
< 0.100
< 0.100
10.3
3.84
6.64
78.7
0.973
6.77
5.77
< 0.200
11.3
Outlet Back
Half,//g
< 0.100
< 0.500
0.244
< 0.100
0.185
< 0.100
0.430
0.971
< 0.300
4.57
2.11
< 0.400
1.22
< 0.200
12.0
                  6-17
-------
                 TABLE 6.11
 SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - LAB CONTROL SPIKES
Sample ID
LCSl
LCS 1 Dup
LCS2
LCS 2 Dup
LCS 3
LCS 3 Dup
LCS 5
LCS 5 Dup
LCS 6
LCS 6 Dup
Spike Amount
Mg/L
5
5
5
5
5
5
5
5
5
5
Recovery
100%
102%
102%
106%
93%
88%
1 1 1%
101%
91%
98%
Recovery Limits
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
                   6-18
-------
                     TABLE 6.12
      SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT -MATRIX SPIKES (PRE-DIGESTION)
Sample ID
I-M29-FHAR,BKL-5% 10%BHMS
I-M29-FHAR,BKL-5% 10% BH MSD
I-M29-l-5% 10% BH MS
I-M29-l-5% 10% BH MSD
I-M29-l-KMnO4MS
I-M29-l-KMnO4MSD
I-M29-2-5% 10% BH MS
I-M29-2-5% 10% BHMSD
I-M29-3-5% 10%BHMS
I-M29-3-5% 10% BHMSD
O-M29-l-5% 10% BH MS
O-M29-l-5% 10% BHMSD
O-M29-2-KMnO4 MS
O-M29-2-KMnO4 MSD
O-M29-3-KMnO4 MS
O-M29-3-KMnO4 MSD
REAGENT BLANK BH MS
REAGENT BLANK BH MSD
Spike
Concentration
Mg/L
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Recovery *
97%
92%
75%
80%
89%
87%
SL
SL
28%
16%
SL
SL
105%
112%
86%
84%
117%
102%
Recovery Limits
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
* SL = Spike Low, % Recovery is not considered valid when spike amount is less than
20% of recovered amount.
                        6-19
-------
               TABLE 6.13
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
 MERCURY SUMMARY REPORT - METHOD BLANK
Sample ID
MB1
MB1 Dup
MB2
MB2Dup
MBS
MBS Dup
MBS
MBS Dup
MB6
MB6 Dup
Detection Limit
Mg/L
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
Recovered Amount,
Mg/L
0.030
0.027
0.035
0.046
0.008
0.011
0.008
0.030
-0.003
0.000
                 6-20
-------
                   TABLE 6.14
    SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - FIELD AND REAGENT BLANKS
Sample ED
FH
FH - Dup
BH
BH- Dup
HNO3
HNO3 - Dup
KMnO4
KMnO4 - Dup
HC1
HC1 - Dup
Inlet Field Blank ^g
< 0.400
< 0.400
<1.20
<1.20
< 0.244
< 0.244
<1.05
<1.05
< 0.042
< 0.042
Outlet Field Blank yug
< 0.400
< 0.400
< 0.600
< 0.600
0.268
0.290
<1.02
<1.02
< 0.440
< 0.440
Reagent Blank /ug
< 0.400
< 0.400
<1.20
<1.20
< 0.120
< 0.120
NA*
NA*
< 0.400
< 0.400
* According to the analytical case narrative this sample arrived broken and could not be
analyzed.
                      6-21
-------
                                   TABLE 6.15

      SUMMARY OF EPA METHOD 23 STANDARDS RECOVERY EFFICIENCIES

FULL SCREEN
ANALYSIS
Internal Standards
2,3,7,8-TCDF
2,3,7,8-TCDD
1,2,3,7,8-PeCDF
1,2,3,7,8-PeCDD
1,2,3,6,7,8-HxCDF
1,2,3,6,7,8-HxCDD
1,2,3,4,6,7,8-
HpCDF
1,2,3,4,6,7,8-
HpCDD
1,2,3,4,6,7,8,9-
OCDD
Surrogate Standards
2,3,7,8-TCDD
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8,9-
HpCDF
Alternate Standards
1,2,3,7,8,9-HxCDF
2,3,4,6,7,8-HxCDF
CONFIRMATION
ANALYSIS
Internal Standards
2,3,7,8-TCDF
Percent Recovery
TLI
M23
Blank
48.2
46.3
40.6
43.9
62.2
63.5
51.7
59.8
55.1
94.1
105
96.1
94.8
87.0
53.6
61.4
*
M23
Field
Blank
1
51.0
51.0
40.5
45.1
71.2
68.0
66.7
81.0
82.4
101
106
96.4
111
108
70.2
69.5
*
M23
Field
Blank
2
53.6
56.0
44.1
47.4
72.2
86.0
58.1
68.8
67.4
94.3
106
94.1
81.7
101
68.2
73.1
*
Trip
Blank
49.6
50.4
39.8
43.3
62.6
72.7
57.4
67.0
67.5
94.6
104
98.0
83.8
87.8
61.8
63.3
48.9
BO-
23-1
52.4
47.3
44.9
49.3
62.3
71.4
43.0
51.8
48.2
95.5
102
104
84.6
96.7
62.2
66.3
48.9
BO-
23-2
60.1
48.4
48.5
47.3
58.7
64.8
58.8
72.8
70.5
94.9
100
103
90.7
116
69.5
63.8
48.4
BO-
23-3
64.4
47.0
43.5
43.3
57.3
73.9
66.2
79.4
77.0
99.2
111
102
88.7
113
70.8
66.5
46.3
QC Limits
40-130%
40-130%
40-130%
40-130%
40-130%
40-130%
25-130%
25-130%
25-130%
70-140%
70-140%
70-140%
70-140%
70-140%
40-130%
40-130%
40-130%
* Confirmation analysis was not necessary on these samples since no TCDF's were detected in the full screen
 analysis.
                                      6-22
-------
                             TABLE 6.16
SW-846 METHOD 0010 FIELD AND LABORATORY BLANKS RESULTS
Compound
Acetophenone
Di-n-butylphthalate
Dimethylphthalate
bis(2-Ethylhexyl)phthalate
2-Methylnaphthalene
Naphthalene
Phenol
Amount, micrograms*
Average
Catch
Weight**
22.5
{3.75}
{2.62}
{13.8}
{4.17}
{15.7}
{9.19}
Field
Blank
{5.09}
{3.06}
{3.19}
{8.95}
{0.36}
{1.84}
{1.44}
Method
Blank
{4.77}
{1.21}
ND
{1.11}
ND
{1.64}
{0.49}
Laboratory
Blank
{5.03}
{3.61}
ND
{0.95}
ND
{1.61}
{0.51}
*  Values in brackets { } are estimated values that were above the detection limit, but
   below the quantitation limit.
   ND = Compound was not detected.
** Average Catch Weight = Average sample amount from runs BO-0010-1, BO-0010-2,
   andBO-0010-3.
                                 6-23
-------
                             TABLE 6.17
         SW-846 METHOD 0010 SURROGATE RECOVERY RESULTS
Surrogate
Phenol-ds
Nitrobenzene-dj
1 ,3,5-Trichlorobenzene-d3
1 ,4-Dibromobenzene-d4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d,0
Pyrene-d,0
Terphenyl-dM
Percent Recovery
BO-
0010-1
80
76
74
82
83
110
101
117
149
BO-
0010-2
66
92
90
89
92
102
88
120
151
BO-
0010-3
58
77
74
81
88
81
86
114
146
Field
Blank
65
54
52
58
69
95
104
118
147
Method
0010
Blank
68
61
59
64
75
50
96
109
137
SBLK
091497*
70
61
46
72
65
93
94
103
130
Method
QC
Limits
20-120
20-120
20-120
20-120
20-120
20-120
20-120
20-120
20-120
* Laboratory Sample Blank
                               6-24
-------
  APPENDIX A




RAW FIELD DATA
-------
 Appendix A. 1




Raw Field Data




Baghouse Inlet
-------
        TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:


Date:
                         CJT\   -L^A.'.^
Sampling Location:
                  "TV> i^ T
Inside of Far Wall to Outside of Nipple:
                                      _/• /'

                                     >
Inside of Near Wall to Outside of Nipple (Nippie Langtn):
Stack I.D.:
              /
                                Stack 1.0.
                                                 dd
 Distance Uostream from Flow Disturbance (Distance A):


                 ^r//'jn&ef, Stack I.D. =



 Cateulatea By:
                                              /  ad
                                                                Schematic of


                                                              Sampling Location
Traverse
Point
Numoer
i
2
3
9
r
..<&^
O.<\£6






Length
(inches)
55:3?^




V.



/






Product of
Columns 2 & 3
(To nearest 1 /8")
2<4S?-
8.o8£"
/^. ^i
3fl.*r^
^7. ^^
r^ , s.r?






Nipple
Length
(inches)
3"
I



\



r




'-»*
' " -I;.
Traverse Point
Location
(Sum of Col. 4 & 5)
5-/i"
• / Va"
iq Va"
^"
SZ>V
<-f^"






                                                            •«•
                                                            *-•
                                                           . *

                                                           '-•'
-------
                 GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: 'NJci *J
Sampling Location:
Run #:
                            Date:   ^f-cr
                            Clock Time:   l.'oo
                                                                /MM
                	  Operators1,—
Barometric Pressure. inTHq:    M. £"5~      Static Pressure, in.
Moisture. %:    ,5"^      Molecular wt., nry-   3Q. cv   . Pitot Tube. Cp:.
Stack Dimension, in. Diameter or Side 1:     SiC-^.*      Side 2: •
Wet Bulb, °F:
    TravcrM
     Point
    Nurnbar
               V.tocny
                Haul
                n. H.,0
StACK

T«mo.
                               Dry Bulb, °F:.

                                        Md -
  ft  1,6,
        1-
            o.
                           303
            Md - 10.44 X

            Md -
                           (0.32X
                                                   %H,O
                                        .M« - Md xd • 	i— '• » )8'  .  "
                                                    100        ;00
 -..0.28x%N2)


 1 - 10.28 X    )



H.,0

                                                              - 18 (
                                                              °R(°F.460I
                                        p,. Pb * -!!L - (
                                                13.8
                                                            ) *
                                                                13.8
                                        P« -
                                                      in. Hg
                                        Vl - 85.48 x CO X


                                        V« - 85.48 x (


                                        Vt-
                                                              P3 x Ms
                                                                    i
                                                       n/i
                                         Qs • VaxAaxaOt/m
-------
Plant: VNkj
Sampling Location
                           y
                           4-
                                 FIELD DA IA SHEET
                            Sample Type: M^r^/6  Operator:
      Run NumberL-^— ~   Date:  in. Hg.
      Pretest Leak Check: Pilot: \/  Orsat: \/
    Pbar:
    CO2:
         Ps:
         O2:
                                                  •it.
                                                                10
                            Probe LengbYType:
                            Slack Diameter:
                                                                  PKot #:
                                                               As:
                                                                               Nozzle ID: TMPC I Thermocouple #:
                                                                               Assumed Bws:  &  FUter #:  \O( Q
                                                                               Meter Box #: //If-V Y: i, CfrlAH®:
                                                                               Post-Test Leak Rate:^Q ctyc(m @ &_ in. Hg.
                                                                               Post-Test Leak Check: Phot: Y   Orsat:
     Traverse
      Pofcit
     Numb*
      Time
      (mln)
Qockrvn*
 (24-hour
 dock)
                       Gas Mater
                       Reading
                        (Vm)«3
 Velocity
Head (Ap)
 ktH20
Oriice Pleasure Differential
    (AH) in H2O
 Desired
Actual
Stack
Temp.
 (Ts)
                  Temperature
                     °F
Probe  I  Filler
bnpinger
 Temp.
  °F
                                                                                                Dry Gas Meter Temp.
  Inlet
(Tmin°F)
  Outlet
(Tm out°F)
 Pump
Vacuum
fm.Hg)
                    O
                                               Y/7///y///////y///////^^
                                                  L_   I    -. _.   I  Ix>, j>.   I TN s    •-. ^wv    f ^.   a*.*ts£&> I  Gt^AD  i  j—
                                                    0.^3
                                                                                               5T
                                                                                                                1.5
                                                                                                                     JL^SL
                                                                                                              So
                                                                                                              ft/
                                                                                                                i.r
                                                                                      •2JTJL
                                                                                                               l.r
                                                    cs.ro
                                                                                              6-2-
                                                                                                              ft 2.
                                                                                                          3
f
                                       O.30
                                         .3V
                                              6,33
                                                                            tel
                                       0,55"
                               .06
                                   .S?
                                                                                        £-2-
                                                                                                   i.r
                                                                               ^33
                                                                                                        ft.?
                                       0.32-
                                                                                        63
                                         -3O
                                       6.3
                                       6. 3
                                       6-30
                                       0,32-
•&'
                                                                                              5.T
                                                                                                      5V
                                                                                              5V
                                                                     Ts=
-------
Plant:
Sampling Location
Run Number:    I
                                            FIELD DA IA SHEET
                                                        _ Operator:
 Pretest Leak Rate:
 Date:
• cfm<
    Sample Type:
    Pbar:
    C02:
                                                      O2:
                           —->in. Hg.
 Pretest Leak Check: Pilot:	Orsat:
    Probe Length/Type:  (^(C-^  Pilot #:
    Slack Diameter: ^T<^^" As:	
                                                                        Nozzle ID: 0. (9V Thermocouple »: 5Tf<--V Y: f.£>;y AH@:  /.gf 9
                                                                        Post-Test Leak Rate:  _   ,. cfm @ j—-m~Hg.
                                                                        Post-Test Leak Check: PKot:  	Dreat:	.
Traverse
 PoW
Number
SampKna
 Tbm
 Hn)
            Qockrim*
            (244iour
             dock)
   GaaMaUr
   Reading
    (Vm)n3
 V.looty
Head (Ap)
 lnH20
Oritoe Pleasure Differential
    (AH) in H2O
Desired  I  Actual
Stack
Temp.
 (Ts)
                           Temperature
                              °F
                          Probe
Impinger
 Temp.
  °F
Dry Gas Meter Temp.
  Inlet
(Tmln°F)
  Outlet
(Tm oul°F)
 Pump
Vacuum
(in. Hg)

             V70
                           Y/^&///&z^/MW/m^^
                                      21
                                                 0.
                                                               23?-
                                                                                STT
                                                                                                     s;
                                                                                                            x-o
                                                               339
                                    , S)
                                        6.30
                                                                      2.3V
                                                      £L
              5T
                    .fi a
                                   . Jo
            {.bo
                            - 31
                                  O/ 51
                                                0.3J
                                                                                                      12-0
                                                                                      62
                           is
                            0-31
                                                                                     $7-
                                                                                                    fls-
                                             6.35-
                                                 c.
                     ool.
                                                                                             f/
                                                                                               8s-
             hr
  rt
                                                 >. 75"
                           0.3V
                                                       . 31
                                 0. 3o
                                                                                                    13[
                                   -
                                                                                                      2^2
                                                                                     st
                                                                                     5V
                                             o-S;
                                                  -5 I7
                                                                                                   s?

                                                                                                         W  W
                                                                                                   •  y
                                                                                                       i<*m
-------
                        SAMPLE RECOVERY DATA
PLANT
DATE    3/t/y?

SAMPLE LOCATION

TRAIN PREPARER
                        Sample Box No.
                                               Run No.

                                               Job No. .
                                                                    -1
                                               Filter No.   /'£?7^
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                               /*?
                            Level Marked
                                               Sealed
                                                Sealed
Samples Stored and Locked

BACK HALF/MQISTTJRE
Container No.
Liquid Level Marked
                         -i -tit/ft \
                                                            Ksi+cH
                                                Sealed
    IMP. NO.
               CONTENTS
                           INITIAL VOL
                              (ml)
                                                   WEIGHT (grams)
                                         INITIAL
                                                      FINAL
                                                                   NET
                            too
                            I0o
                                      -7/6.7
                                                  -7
                             o
                                                                -H.I
                            1 00
                            lOQ
                                                   "76
                                                                   . 0
          TOTAL
                                                              (
-------
                                             FIELD DATA SHEET
Plant
Sampling Location
Run Number:
     \-~2-
                              'i r<
                     Date:
                                       Sample Type:
                                       Pbar.
                                       CO2:
                                               Operator:
                                 Nozzle ID:
                                                           Thermocouple #:
           10
         Ps:  -
         02:
Pretest Leak Rate: 0.003 elm @ |J^ in. Hg.
Pretest Leak Check: Pilot: J Great:
	+19 - S.fo
                                       Probe Length/Type:
                                       Slack Diameter: <~r
                                                                 Pilot *:
                                                                  Assumed Bws: 3  Filter #:
                                                                  Meter Box #: /uf-V Y: 1.Q2I  A
                                                                  Post-Test Leak Rate: o.    cfm
                                                                          i.Hg.
                                                              As:
                                                                  Post-Test Leak Check: Pilot: S Great:
T
 PoJnl
Numb**
     Sampling
      Tlnw
docfcTVn*
 (244io
 dock)
                       GaaMaUr
                       Reading
                        (Vm)«3
 Vctoctty
HMd (Ap)
 lnH2O
Oillc* Priaour* Oiftercnlial
    (AH) in H2O
Desired  I   Actual
Stack
Temp.
 as)
Temperature
                                                                        Pfobe
                                   Fitter
Impinger
 Temp.
  °F
Dry Gas Meter Temp.
                   (Tmin°F)
         Outlet
       (Tm out°F)
 Pump
Vacuum
f«.Hg)
 fU


                                                                                               •7?
       to
                                 o.Vl
                                                            23  /
       tr
                                                       O.VS
                                                    20 <}
                                                                                               B{
       10
                                             o.tyv
                                                            23Y
       or
                                                                               UG
     3CL
                                  6-f?
                                                                    r
       Ho
                                                                                             er

                                  /V
                                                                                                             fn
                                                                                                              to.r

                                                                307
                                                                                      sy
                                                                                 ©7
                                                                                                             c'V
                                                                                                       Ao
                                                                                                      80
                                                                                       sr
                                                                                                     91
                                              0.14
                        . ?-«
                                   go
                                           0.0)
                                                               305"
                                                                                                     flit
                                                                                                 -%—
                                              0.96"
                                                                                             *?/
                                                                        233
                                                                                                             8.5-
                         V3
                                                                                      ST
                                                                                                 /O
                                              0.93
                                                                                      r?-
      itr
                                6-71
                                 o-?3
                                                                                                     9?
                   i
                                             -'I
                                         ; l

                                                                             a
                                                                                              v/
-------
                                                                    Page
                                                                                         of
Plant Name:
Run Number:
                                                   Test Date:  __±dt^=33L-	
                                                   Operator:
TraVcne
 Point
Number
Sampling /dock Time
 Time, / (24-hour
 (min.) /  dock)
                Gas Meier
                 Reading
Velocity
leaJ^P,
in. IliO
Orifice Pres. Diffcrcalial
                               Desired
         Actual
 Slack
Temp. • F
  Probe
Temp./ Filler
 Temp* F
Impinger
 Temp.
 •F
Dry Gas Meier Temp.
                                          Inlel
                                                   UUllCl
 Pump
Vacuum
 In.Hg
 B £
                                                                         ftft
              /
                                              • 0.73
                                                      3/3
   r
                                                                                        88
        tSD
                                                                                            9-
                                                                                        88
[leO
               U : 13
                                0.^7/7
                                       O.'JO
                                        O.10
                       102.0?
                                                                  (oO
        1*0
                                               310
                                                                                         ?.
                         Si
                         (.o
                                              5/2,
                                                        SI
                      110.21
                                               J/3
                                                                rv
                                                        70
                                                            . r
                                                                                                 n.r
                                                      j/r
                                                                                           (f
                                                                                        to.
                      lX.37
                          (.0
                               (.6
                                 053
                                                 76
                                           U
              /(*'./*>
                      SCI.!

                                                                                          13
-------
                         SAMPLE RECOVERY DATA
PLANT W.^^* IX.J*.
r ™ -r T T
DATE V/./*7 Sample Box No. ' '
SAMPLE LOCATION ±**kt
Run No. J--/'foi 1"^.
Job No. S V/V. OQ3
Filter No. 1^/1
TRAIN PREPARER
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                                /*7
Samples Stored and Locked

BACK HALF/MOISTtrRE
Container No.
Liquid Level Marked
                             Liquid
                                  Marked
                                       10
                                                 Sealed
                                                 sealed
                                                 Sealed
    IMP. NO.
               CONTENTS
                           INITIAL VOL
                              (ml)
                                                    WEIGHT (grams)
                                         INITIAL
                                                       FINAL
                                                                    NET
                            too
                             too
                              b
                                               j
                             loo
                                                                 -    A
                            A90
           TOTAL
                                             : i,
-------
                                                                                   > b"
                                                                                                         032
                                        FIELD DATA SHEET
           (. Te-U
               lr.4-
Plant jWc
Sampling Location
Run Number:	3      Date:
X-CV^" SCcf^t. ~i /at /ft
Pretest Leak Rale: ft.flbp  elm i
Pretest Leak Check: Pilot:
                            Sample Type:
                            PbarfgjV
                            CO2:   |o
                    Ps:  -
                    02:
                        Operator:  A£>\>/M M
                                  Nozzle ID: CM ^2   Thermocouple if:
                                  Assumed Bws:  3  Filter #:   /Otl
                                                        10
                   in. Hg.    Probe Length/Type:
                                                             Pitot*:
                                   Slack Diameter:  ST.?V'  As:
                                  Meter Box #: Air-9 V: in3J,^H@:  l-Slfl
                                  Post-Test Leak Rate: Q_OC^ cfm @ ^_ in. Hg.
                                  Post-Test Leak Check: Pilot:  v^Orsat:
Traveree
 Pbht
Number
Sampling
 Tkra
 (mln)
OockTInM
 (244iour
 dock)
                       GuMator
                        RMdmg
                        (Vm)ft3
 Velocity
Hwd(Ap
 InHZO
Oillc* Pr«»sur* DiftartnbaJ
    (AH) n K2O
Desired  |   Actual
Stack
Temp.
                            Temperature
                               °F
                           Pioba
                Fitter
knpinger
 Temp.
  °F
Dry Gas Mater Temp.
  Inlet
(Tmin°F)
  Outlet
(Tm out°F)
 Pump
Vacuum
f«.Hg)
  D


                                         t>.
                                                                                            to
                                                                            71$ S
  1C
              6 1
                                                                         £33
                                                            100
       15":
 3D
                                                                                                    2-0
                                         O.&'b
                                           CD.
                                                                    2VV
                                                                            V3
                                         O.66
                                                                            v/?
                                                  o-SS
                                                            P33
                                         b.G'
                                           o.c/
                                                                        as?
                     OO
                                           0.93
                                                                        230
                                                                           Q.O
                            0.3-6
                                                            732
 75
85
                                                                            5ZP
                                                                                                           ?.&•
                             b.0\
                                                                                                   SL.o
                                                                                                          2.5"
 /CO
                                           o.lY
                                                                                                               P.O
( OS-
                            A. 63
                             0.6?
           AVm=
-------
                                                                  Page
                                                                                       of
Plant Name:
Run Number:
                       Jl  £-.!«
         o	-r_
                                                  Test Date:
                                           g>fa|tvOperator:
Tnvene
 Point
Number
Sampling
 Time,
 (min.)
 /
/
/
              dock Time
              (24-hour
                clock)
Gas Meter
 Reading
                            Velocity
                            lleid^P.)
                            in. IhO
Orifice Pros. Differential
   (£j|)ln.H2O
               Desired
         Actual
 Slack
Temp. • F
  Probe
Temp./ Filler
 Temp* F
Impingcr
 Temp.
 •F
Dry Gas Meter Temp.
                                         Inlet
                                                  UUllCl
 Pump
Vacuum
 In.llg
£_A.
              /
                                       .9 r
                                              738
                                                          6V
                                       0.9-^
                                                                                   3.5^"
       130
                                                                                         3-r
                               A 9?
       ;V6
                               o&ft
                                0.80
                                                                                               3.5^
       ivr   '
       /so
               9/V.arf
                                                                          63
                                                    305
                                                                vy
                                                                          8V
                                                                                               3-5
-£
                         . 8 y
                                o.&t
                                                          vr
                                                                                      #3
                                                                        3
                          . V3
                         ^.85
                                                   ' 255
                                                                      V5
                                                              £3
                                                                                           3.5
                                                                                              5-5
                                     o
                                                                                        3.5"
       (#•>
                               I./
                                        3(2
                     033.
                               0.03
                                                                f/
                                                                                     8?
                                             of
                                                                      f/
                                                    3/7-
                                                                               #3
                                                                                   y
                                             OM
                                              3IC,
                                                          y?
                                                                                      #3
                                             0.9,1
                                                                               03
                                                                     t
                                                                      10
                                            0&&
                                                               vg
                                                                         03
                                                                                               y
                                                                            10
                                                                               ga
                                                                      £1
                                                                        IE
                                                                                              3-ir
      £30
                                              Ft
                                —-  ^AJt)   OF
                                                                                                             I
-------
                        SAMPLE RECOVERY DATA
PLANT V/^pmuL H
DATE ^ I/O /1 7
SAMPLE LOCATION
'L*>J»Wi
7
Sample Box No.
/ / ^^L
Run No. J--/I7^9-?
Job No. Syrf.OOf
Filter No. \0l\
TRAIN PREPARER /^ A^.' //-.
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
Samples Stored and Locked

BACK HALF/MOTSTTTKF.
Container No.        "
Liquid Level Marked
             Liquid
          jrtfc* Level Marked
                          -3
                                                Sealed
                                 Sealed
                                 Sealed
    IMP. NO.
CONTENTS
                           INITIAL VOL
                              (ml)
                                                   WEIGHT (grams)
                                         INITIAL
                                       FINAL
                                                                   NET
                             too
                            190
                                                 1.C
                             0
                            100
                                    "73^.0
                                                                  O.T
                   fcklJ   (00
              WfiJ
          TOTAL
                                                  60-1
-------
Plant:
Sampling Location
Run Number:
                                              FIELD DA I A SHEET
                  6U/£)ate:
Sample Type:
Pbar:
C02:
                                                             Operator:
                                                         Ps: -U.2S'
10
02:  (0
Pretest Leak Rate: a.ooy cfm @ fg~\n. Hg.
Pretest Leak Check: Pilot: — .   Orsat: -
Probe Length/Type:
Slack Diameter:
                                                                   Pilot #:
                                                                As:
Nozzle ID: XHPC f  Thermocouple #:	
Assumed Bws:  Sfc Filter #:  «fl} RJC^&L
Meter Box #: M$"   Y: Lt2il.AH@:  L ^/ft
Post-Test Leak Rate:g>,co3 cfm @ l5jn Hg.
Post-Test Leak  Check: Pilot:  A/4 Great:
Trcv«r««
Ptoht
Number
•BUJ
T>lt»\'
61^4

























Sampling
Time
(mln)




























Qock Tim*
(24-hour
doc*)
9?
;^^l


l?.'2l






















GasMeUr
Reading
(VmjnS
^^4
?3LL3/

9r?l.ft7^
93^to
-------
                       SAMPLE RECOVERY DATA
PLANT

DATE
         VVCm
                       Sample Box No.
                                             Job No.
                                                           _v/y.
SAMPLE LOCATION

TRAIN PREPARER
                                             Filter No.
                       / /
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                           Liquid
                                Marked
                                              Sealed
                                              Sealed
Samples Stored and Locked

BACK HALF/MQISTTIKF
Container No.        	"X
                                                             SIX
Liquid Level Marked
                                              Sealed
    IMP. NO.
               CONTENTS
          TOTAL
                          INfTIAL VOL
                             (ml)
                            oo
                           ion
                            O
                           too
                            IOQ
                                                WEIGHT fgramsi
                                       INITIAL
                                     512.fi
                                                   FINAL
                                                7 ^.
                                                 7:13.0
                                                •7^.7
                                                                NET
                                                               o./
                                                              d.v
-------
                                            Pacific Environmental Services. Inc.
                                                Dry Molecular Weight Determination
Client/Proiect: Wr
Date/Time:
Sample Type:
Ambient Temo. :F
Run No.(s)

Run No.(s)
^^^—

Gas
•
CO,
o,'
CO"
",'
I" rw ' S'fn-oo
ilih?
C/t-flJ IJf-k .


Run 1
Actual
/ Orsat No.
Operator
Comments:
Site Location:
Run 2
Actual
to*
2I.+

/00.0
Net
//>,o
//.*-

7«.i.
Run 3
Actual




Net




C> —
/? &SJL

/Cw4->>_ X4

Average
Net
Volume
/o.Ct
7/2.

78,2-

Gas
•
CO,
o,'
CO"
Nf
Run 1
Actual
M
11.4

tOQ.0
Net
lo. f
/4?.<

78. fe
Run 2
Actual
/#.?
2/.S-

too.o
Net
/# ^
/
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
y Gb
t.^i

i-l<7o
Md= ^^ /y

Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
y<&0
1 36

zr.f7
Md= T-,0 > -J
Run No (s)
>/C

Gas
•
CO,
o,'
CO"
N,c
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md-
' 0] Net Volume is O, actual reading minus CO, actual reading.




" CO Net Volume is CO actual reading minus O, actual reading.




c N, Net Volume is 100 minus CO actual reading.
       IMVUKMaWttLMIMCta IMC.
-------
                                             Pacific Environmental Services. Inc.

                                                Dry Molecular Weight Determination
Client/Proiect: w
Date/Time:
Sample Type:
Ambient Temp. :F
Run No.(s)

Gas
•
CO,
+y
1o

Run 1
Actual
//.*•
20.4

/P'C, O
Net
If.T-
1,(p

7^,X
^ Orsat No
\0perator:
Comments:
Site Location:
Run 2
Actual
//. y
xeas

/^t?^
Net
^/ */
^ £/

4722-
Run 3
Actual




Net




&' Z.
tfL/Z&i.

ft+4^.0**. ^**
' S
Average
Net
Volume
//.3
^5-

-7f,1

Multiplier
0.44
0.32
0.28
0.28
*f/Cy*£
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
^77
3.oy

22.1%
PUM s *i* VN / *y
->°. 1 1
Run No (s)
^•-15

Gas
CO,
0,'
CO"
N,c
Run l_
Actual
ll.%
7.1.2-

fov.o
Net
//.S
1.1

7A«
Run 2
Actual
//S
2U

/ffff.o
Net
//S
?-Y

7a«
Run 3
Actual




Net




Average
Net
Volume
%
//£
^

7)8.8

Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
ot
Stack Gas. Md
(Ib/Mole)
sr/?
3,oi

22.0(0
Md= 3a2£
Run No (s)l   Gas
                          Run 1
                      Actual
              o,'
             CO"
                                Net
                              //.I
                                              Run 2
                                        Actual
2 /.I
                                       /oo.o
                                                   Net
          /2.o
                                                                Run 3
                                                            Actual
                                                                      Net
                                       Average
                                         Net
                                       Volume
                                                                                       Multiplier
                                                  0.44
0.32
                                                  0.28
                                                                                         0.28
       Molecutar Weight
             of
        Stack Gas. Md
          (Ib/Mole)
                                                                                                 2.7s7
^-O"2 Net Volume is Oj actual reaoing minus CO) actual reading.

 0 CO Net Volume is CO actual reading minus O, actual reading.

 c N, Net Volume is 100 minus CO actual reading.
                                                                                                                 ~
      f tNVUOMMTAL UIMGM WC.
-------
                                           Pacific Environmental Services. Inc.




                                               Dry Molecular Weight Determination
Client/Proiect: i,
Date/Time:
Sample Type:
Ambient Temp. :F
Run No.(s)

Run No.(s)

Run No (si
•^^••••••^••^M

Gas
•
CO,
o,'
CO"
N,'
y^/v^-^y
*//*/? 7
0r*»t P«a>'
7°

Run 1
Actual
l/'i
2l.o

/00.0
Net
'i(>i
U

71.0
W°0 ' Orsat No.
Operator:
Comments:
Site Location:
Run 2
Actual
//
Net
/3.o
%j

71.4
Net




Average
Net
Volume
1 1.0
q.o

7lo

Run 3
Actual




Net




Average
Net
Volume
/*/
*,$

7t.<{

Multiplier
0.44
0.32
0.28
0.28
Z.C
Molecular Weignt
of
Stack Gas. Md
(Ib/Mole)
4&2-
"5* 07

Z2.A2.
Md= 3>Q.l~l

Multiplier
0.44
0.32
0.28
0.28
Molecular Weignt
of
Stack Gas. Md
(Ib/Mole)
5729
2,0«

22.12.
Md= ^Of "2%

Multiplier
0.44
0.32
0.28
0.28
Molecular Weignt
of
Stack Gas. Md
(Ib/Mole)
&7(f
1.-7T-

t-f.lf
Md- '%Q Lf^
' O, Net Volume is 0, actual reading minus CO, actual reading.



6 CO Net Volume is CO actual reading minus O, actual reading.



c N] Net Volume is 100 minus CO actual reading.




      S8
      t IMVmOMieNTAL SWMCU IMC.
                                                                                                                           r-
-------
                                             Pacific Environmental Services, Inc.
                                                 Dry Molecular Weight Determination
Client/Proiea:
Date/Time:
Sample Type:
Ambient Temo. 'F
 Orsat No.
 Operator:
 Comments:
Site Location:
Run No.(s)
^

Gas
•
CO,
£>,0
Net
f2,0
%°

79.0
Run 2
Actual
/2.D
-LLo

i'QO.o
Net
{i.o
TO

-71.0
Run 3
Actual




Net




Average
Net
Volume
%
12.0
-------
 Appendix A.2




Raw Field Data




Baghouse Outlet
-------
        TRAVERSE POINT LOCATION FOR CIRCULAR DUG
Plant:
Data:
f—c\> /\ A /-y
Sampling Location:  (it* fj/^l
Inside of Far Wall to Outside of Nipple: _
Inside of Near Wall to Outside of Nipple (Nipple Length):  5. -
StackI.D.:    9/f "	_____
Distance Downstream from Flow Disturbance (Distance 8):
            2-5   5°°    inches / Stack I.D. =  z\    dd
 Distance Upstream from Flow Disturbance (Distance A):
 Calculated Bv:
    inches / Stack I.D. = ". c>
                                                 dd
  Schematic of
Sampling Location
Traverse
Point
Number
.•
i
^
>-
-
^
'•>

n
*'
.7^ „
M1
,-/$<)
,ez-3
y i*ez-
r fit
'^7?
LengtM
(inches)
^'?.'v






















Product of
Columns 2 & 3
(To nearest 1/8")
/.f
/. Z.
/O.?
/L2
23 O
2>^ ^
L£& £&2~
L1.G
->s<~?
91. I
ttV
°16,I
Nipple
Length
(inches)
\<"










J










/
Traverse Point
Location
(Sum of Col. 4 & 5)
S.4
9.^7
M.4
/
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Piam- |^,.^rf frTi,nrl ., Hate: 7-^-^7
c
F
E
P
c
\
fZ-lw
o^>
•A ft '
V
z°
3°
r
/.$•
2°
28°
33*
O
2;
38*
. 	 	
/t-;*«y-».

;CX«c<
»,Wf,,
£u>
£uo
£C
11
TIT
^ C-
i ••• „
Sampling Loc
Run #: Pr*
Barometric P
Moisture. %:
Stack Dimen;
Net Bulb. °F
Tr*v«rM
Point
Numtar
^^ /
2
3
-V
5
C
4^K '
^
5
*l
$
1. ^
... .-^ / /
iWC^^
1
3
^
5
c.
Uffr/A '
L
3
^
5 .
U

«
ration: Lsf)*l^' r>^H.±- Clock Time: /j/o
:/i'fwr^-w' nn»rarnre: T^f//3^
ressure. in. H
5?
q: X*?.3T5 static Pressure, in. H«O: . O-T
Molecular wt.. Drv: Pitot Tube. Cp: . *"/
sion. in. Diameter or Side
: - DrvE

Velocity
n. fUO
Stock
""•mo.
/-V is,
• / c^ Z- 5 2-
/A o ^ /*
.26
. ST.
.S3
./ 2i
t3
. il
.29
, 3 2
25?
zsz
-2-5C,
150
•235
2^?
^5y
25-f
. 3/ 2^^
./O
•/o
. //
.'&
./9
.2C;
. /^?
• 5*?
//
.(99
•^9
.0?


2-55
3-37
2<5?
-z5?
2^^
•Z.50
2,^2
T-35
1.C0
1~0(
?-<,£>
0-57

f»- 2^6
1- 72" Side 2- 	
tiilh.OC. __
Md - <0.44 x %CQ,) + (0.32 x %CX,) ••• (0.28 x %N2>
Md - (0.44 x ) * (0.32 X ) * (0.20 X )
Md - 2 f, 3 2-
% H,O % H..O
'00 10° , ^.
* " ' 100 "M
— ° ° °F 5'«'-^
^>
Pa - Pb * S'P' - ( ) * 	
13.8 13-8
P«- i.*} ,f_5 '". Hg
^- -
/ *s f^fl)
V« - 85.48 x Co x VS? x )| Pa x Ms
r
v«- zC,.*/^ (t/«
A«- V<<./
-------
                                      FIELD DA IA SHEET
'Own*
Plant:
Sampling Location
Run Number: /^/.-^.WyDate:
Pretest Leak Rate: ,/>Q5  elm @ /$  in. Hg.
Pretest Leak Check: Pilot:  -  Orsat:   —
Sample Type:
Pbar
CO2:
Operator:
                                                                           Nozzle ID:
                 Thermocouple il<:	
                 Filter #:
                                                 O2:
                                 Probe Length/Type:  6"'-5J   Pitot #:  —
Slack Diameter:
                                                         As:
                     Assumed Bws:. &
                     Meter Box
                     Post-Test Leak Rate: .
                       cfm @_5" in. Hg.
Post-Test Leak Check: Pitot:  — Orsat:  —
Traveree
Point
Number



























Sampling
Time
(mln)
0
to
Z-6
























dock Time
(244»our
dock)
/^Z-
tcs-z.
/~}0t
























Gas Malar
Reading
(Vm)B3
C,3/. LrO 6
G_s*.7
6^7, 746
























• Velocity
Head (Ap)
inH2O
Orif c« Preaaura Ditterential
(AH) in K2O
Desired
Actual
Stack
Tamp.
(Ts)
Tamperaturt
°F
Probe
y/////////////////////////////////
—
—
f^ s- "^~























;. f
/.?
























/• F
/•^
























2S/

























231
•2
-------
                        SAMPLE RECOVERY DATA
PLANT

DATE
                                Run No.
Sample Box No.
SAMPLE LOCATION
TRAIN PREPARER
                          ~?   Job No.

                                Filter
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
Samples Stored and Locked

BACK HALF/MOISTTIHF
Container No.        	
Liquid Level Marked
                                Sealed
Liquid
Level Marked
Sealed
Sealed
    IMP. NO-
CONTENTS
   INITIAL VOL
      (ml)
                                                  WEIGHT (gramsi
                                        INmAL
                                      FINAL
                                                                  NET
                            /fao
                                                  &8I.D
          TOTAL
-------
                                            FIELD DA I/? SHEET
 Plant:
Sampling Location
Run Number: roa^-O- T Date:
  O— f^a.q - \ocyr£^ VW'iS        " .
 Pretest Leak RaTeT;OOo3   cfm @ Ui> i
 Pretest Leak Check: Pilot: 
-------
                                              FIELD DA I A SHEET
Plant:
Sampling Locaion
Run Number
                  -l Date: °l ~
 o - ^*^ - i .I6       Post-Test Leak Check: PHot: o*Ki
                                                                                                                         -G.G4Q
                                                                                                                 ^9*
-------
                       SAMPLE RECOVERY DATA
PLANT
DATE
                FLJ
                                         Run No.
        <3/4/c7
SAMPLE LOCATION
TRAIN PREPARER
                   Sample Box No.   —     Job No. A

                         	 Filter No. .
SAMPLE RECOVERY PERSON   /*?
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                           Liquid
                 P'W»Mfr4*Levei Marked
                                          Sealed
                                             Sealed
Samples Stored and Locked

BACK HALF/MQISTTFRF
Container No.
Liquid Level Marked
                                             Sealed
IMP. NO.
              CONTENTS
                          INITIAL VOL
                            (ml)
                                                WEIGHT (grams)
                                      INFTIAL
                                                   FINAL
                                                               NET
                                                 77^.4
                          100
                                                5^7.5
                           / oo
                                    727.7
                                             /34/f
6,7
                          100
                                    73^.7
                                                           7-5
                                                868.6-
          TOTAL
-------
                                                                                                       o^f
                                             FIELD DATA SHEET
   Plant
         Date: q-(O-ICO .16~4
                               Assumed Bws:5.5% Filter #: 3O|£4O
                   7o         Meter Box »:M-5-3 Y: |.03fi AH@: 1.7^6
                  Pilot #: b -7?-Q7 Post-Test Leak Rate: .005 cfm @ Ji^ in. Hg.
               As: 4r^^l6     Post-Test Leak Check: Pilot: o-  . ..OS  ...ftft.
                                        5H-_LllK
                                                  V«
                                                                              q ,
                                                                                               "176
                                                                                                  5364
-------
                                                                  Page
                                                                                       of
 Plant Name:
 Run Number:
                                 Test Date:
                                 Operator:
                                                                 3_iiOji3_7
 Traverse
  Point
 Number
Sampling /dock Time
 Time,  / (24-hour
 (rain.)  /  dock)
Gas Meter
 Reading
          Velocity
          eaiitP.)
          in. IhO
                        Orifice Pres. Differential
               Desired
                                 Actual
 Stack
Temp. • F
  Probe
Temp. / Filter
 Temp." F
Itnpingcr
 Temp.
 •P
Dry Gas Meier Temp.
                                                                 Inlet
                                                                         UUllCl
 Pump
Vacuum
 In. llg
 IN/
 I35
                       .59
                               2S 5
                                             AST '253s
                        93
                                         81
                                         Ht>
                                         11
                                         •to
         HO  /
                                       ,.5**
                                                               87
         M5
                          ,0©
                              257
                                     2Sl'
                                                                         87
         1 50  /
                                       .49
         IS5-  /
                    . II
         I60   /
         445.PS
                                       .44
                              257°
                                                                 57
                       446.82
                          .05
               .365
                       . 365
                                                                         88
                                           3"
         no
                          .06
               ,584
                                                                 9<£-"
                                                                &&
                                                                                                          *;' :'»
         175
451.51
c7_a*b ——
                                       ,73
                                                                 W
                                                               88*
                                 . 10
                                       ,73
                             260*
                                                47
                                                                                 2"
         IBS   /
                          ,15*
                       U
W  1
  110   /
         .15*
                        M
                                                                lot
                                 -'7
                                              260
                                       I.Z4I
                                        .2.
                              Ibo
                                                       101
                                                                                                 "
                        #1.04
                                      0.95
                              260
                                     251
                                                                                       18
         210  /
                                                                                          "
              /
                                       0,80
                                          252°
                                                        105
         aao  /
                          .11
                      0.6O
                                     ZSl* 1 252°
              1
                               0,73
                       .73
                                                                         2"
         230  /
                               0,457
                                    2*2*1
                                                        /o
                                                                                 2"
                                                Vc?
         235   /
                          .Oi
               '.436
                               266"
                                                                 0
                                  95*
/ I3:i5
                        85.658
                          .05
               ,365
                                                  •/
                        j
                                                                                                 C
-------
                       SAMPLE RECOVERY DATA
PLANT 	

DATE  _1
                                                  No.  frfttf-
                       . Sample Box No.
                                              Run
                                              job NO.   <:
SAMPLE LOCATION
TRAIN PREPARER
                                              Filter No.
                                                         *?QJ
SAMPLE RECOVERY PERSON

COMMENTS        	
                              /"?   /tL», //L
                                  Lit
FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                            Liquid
                                Marked
                             •• k *L-
                                              Sealed


                                              Sealed

                                            &*2-
Samples Stored and Locked

BACK HALF/MOISTTJHF
Container No.
Liquid Level Marked
                                   0-
                                                    '
                                               Sealed
    IMP. NO.
               CONTENTS
                           INFTIAL VOL
                             (ml)
                                                 WEIGHT fgramsi
                                        INITIAL
                                                    FINAL
                                                                 NET
                            100
                                     I222i*.
                           LOO
                                                  £-71.*
                            -Cr
                           100
                            o
                                           '07.7
                                                     - 7
          TOTAL
-------
                                                    FIELD DATA SHEET
Plank
Sampling Location 3=foJvpnie £X£/.eifr
RunNumber:t*U°[-Q-3 Date: /^s^ Pitol »:5-?2-o9 Posl-Tesl Leak Rale: tOO^ cfm @l^w in. Hg
                                                    As: 46,16      Post-Test Leak Check: Pitol: Qk, Orsal:
TrevwM
 Point
Number
               Sampling
                 Thra
                 Nn)
      OocfcTlme
       (244tour
       docfc)
                     Gu Mater
                      Ftoadng
                      (Vm)ns
 Vetooty
HMd (Ap)
 lnH20
                                    Oilfca Pr«Mut» Oiftorcnttal
                                        (AH) in H2O
                                     Desired  I  Actual
Stack
Temp.
 (Ts)
                                                  Temperature
                                                    °F
                                                Probe "[" Filter
Impinger
 Temp.
 °F
                                                                                   Dry Gas Meier Temp.
                                                                                    Inlet
                                                                                  fJmin0F)
                             Ouflet
                           (Tm out°F)
 Pump
Vacuum
fw-Hg)
          W 1
           15'.3
                         Y/////////////////////////W
                 10
                                                                       536
                                                                            55°
                                                                                       0(5
                 15
                                ^ifi.
                           257°
                                                                                                  3"
                 AO
                           -15
                                           7,05
                   /.I
     ^5_
J3.
                                                                                     253'
                                                                                                  3"
^0_
                   503.^
                    32.
                                                                      25
                                                       ,56
                                                .56
                                                                                                      -2"
                 40
                                                                            3L
                 45
                            .05
                                            ,35
                    .35
                                                                     253
                 50
              511.8?
                                                     .41
                                                 5)'
                                                                                          86
                                                                ,28
                                                                .42.
                                                                            -M
                                                                                        0(2
                                                               as
                                                               .56
                                                                            4f
                                                                                        87
                  0
                                       •42.
                                                    -4Z
                                         ^47
9
                 15
eo
^
                            .11
                                            .77
                    '77
                                                      25°
K2.3.61
                                                        ,56
                                               •56
                                                            250
                              525.
                                               .56
£52*
255*
                                                  2.°
                                                                                                           *?
                                                                                                                      54
                                                                                                                      85
                              526,04
                            .06
                                             .56
                                                43
                                                                                         63
                                                                                   2."
                                            .08
                                               ,56
                                                                                 44"
                 Ito
               532,13
                                 .07
                                                              a
                                                                                                 m"
K>5
                    53 3,
                   ,42
                                                             253'
                 110
               535.8o
                                 ,06
           .42.
                                              .4Z
                                        553*
                                                                     a48"
                 US
                  , 66
                                                            253
                                                4*
                                                                                         83"
                            ,06
                                                   M
                          153!
                                                                    ^53'
                                                                                                  56*
                                                                                         80°
                                  , 3S
                                                                     253
                                                                                              ^
                 n  -
                                                             I.IQI
                                                                   54
                                                                                       i-  87.706
-------
Plant Name:
Run Number:
                                                                Page    2.   of

                                                 Test Date:  _9ll^±9:2_.....
                      O
                                                  j^fn Opera tor:
Traverse
 Point
Number
Sampling /dock Time
 Time,  /  (24-hour
 (mla.) 1   clock)
                      Gas Meter
                       Reading
 Velocity
I lead $P,)
 in. IhO
                     Orifice Pres. Diffcrcoiial
                                     Desired
                              Actual
 Stack
Temp. • F
  (T.)
   Probe
Temp. / Filler
 Temp* F
Impinger
 Temp.
 •F
Dry Gas Meter Temp.
                                                              Inlet
                                                                      Uullcl
 Pump
Vacuum
 In. llg
E  a
  135
                                      1,75
                              I.7.S
 ^53
252'
                 81
                 3"
      a?
      e?
      fi?
      67
      8?
      87
        HO  '
                553,5\
                                     1,7-T
                      557.Z3
                                                               43
                                                                                    ei
                                                                              ±1
        150  /
                                                               44
                                                                                        er
        155  /
                                1.51
                                              I.5
        160
                567.76*
                                                          Z52*' 251
                                                                     e
                                           r
                      570,'?^
                         .15
                                      1,05
                                                              93
                                           3"
        170
                         .15
                                      1,65
                              1. 1
 2.56*
                                                                                               "
        175  /
       576.51
                               •
                                -S8
                                                                                     80"
JL_i
        ,180
                                             255
                                                                                               "
        165
                563.38
                               .31
                      567^3,
                         .31
                                      2,17
                                    152
                                               1*
                                               96
        RS
                                                   253* 12$-)
        200
                5^5.66
                                                         25*° ' 258*
                                                             93
                                                    261
                                                   252
                                                                      8
                               ,30
                                      2, 1
                                                                      6
        215  /
                                      '•75
                                                   263
                                                                                    66
                                                                                    85
                               .2.2.
                                      I.5
                                                         2,50*1252
                         CJ J
        225  /
                613.37
                                                   «*»
        Z30  /
        .J6.fl
                               • SB
                                                                                     78
\
                                             ll
                                                        '534°
                                                                            6?
                               .to
                                                   254° '253°
                                                                            87
                                  7T
                                                                                   82
                                                             T
                                                    SW.O
-------
                        SAMPLE RECOVERY DATA
PLANT    w
-------
                        SAMPLE RECOVERY DATA
PLANT U/«~f~* r«.»J^
DATE <*A-/47 Sample Box No.
SAMPLE LOCATION Os¥\rt
Run No. ^ '
— - Job No. £
f^
Filter No. jO/
•<•» P'«:
?4W. oo •}
6f3.
TRAIN PREPARER /7 //— ,' AL
Samples Stored and Locked

BACK HALF/MOISTTJRF
Container No.
Liquid Level Marked
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                            Liquid
                         fiM4,Level Marked
                                Sealed
                                               Sealed
                                Sealed
   IMP. NO.
CONTENTS
                           INITIAL VOL
                             (ml)
                                                 WEIGHT (grams)
                                        INITIAL
                                      FINAL
                                                                 NET
                           /oo
                           too
                        ^52.7
                                                                o.o
                                       S5\.l
                           loo
                      12LM
                                                                o.o
                           100
                       7.17*
                                                                 . o
          TOTAL
-------
                                                FIELD  DATA SHEET
 Plant:
 Sampling Location   C-\jffrv-fiw
Pretest LeakRate: .
Pretest Leak Check: Phot:
         Date:
          cfm
                               -<\-°»1
    Sample Type:
    Pbar: ^.-5
    CO2:
                                                         Operator:
                                                          Ps:
                                                          O2:
                                                                                       Thermocouple
                                                                                       Filter #:
                                                            L.
                        V5_ in. Hg.
                     Orsat:
                               5_ in. H
                               t: t/
Probe LengtWType: 5"
Stack Diameter:  ^^
                               Pilot »:5*fc
                                                     As:
                                          Nozzle ID: .
                                          Assumed Bws:
                                          Meter Box #:
                         	J5Y:_UtyL_AH@:	,
               Post-Test Leak Rate: .001  cfm @ jT_ ii
               Post-Test Leak Check: PKot:  _ Orsat:
Trovers*
 Pokrt
Numtwr
Sampling
 time
 (irin)
       _2JL
        35
        4 0
        4-*
       3-5
       bO
CkKkTim*
 (24-hour
 dock)
                 04-
                        GMMelet
                         Reading
                                A
                           .   o
                        >D
^Vslooty
Head (Ap)
  inHZO
       Oi6c« Pressure Ditterential
           (AH) in H20
        Desired  I   Actual
Stack
Temp.
Temperature
   °F
                                                                             Probe
                                  AA.
                                   0.
                                        J2.
                                 vO.S
                                 .  0 tf
                                  os
                                                    .5
                                              ,5
                                             . $ s
                                        JS
                                                -5
                                                                4^-
                                                       444
                                                        iii.
                                                                       Mv
                                                                       V4d.
                                                                         74-7
                           L.UL
                                                        Jl
       To
       \\
                                      -Ai
                                             AA
       CPS
       \-LOi_
                                      v.O
                                       v 1  0
                                      J_o_
                                                       1,0
                                                    V.T-
                                                       v.i-
       \oo
                                        « V
                                        .\D
                                             \.f)
I1Q_
       OP
                         »V^-
                                                    -  0
                                                  _Li^
                                                                       -fc-
                                                      JuJ2_
                                                                       36
                                                                   Ti=_liO
                        //7/7
                                                              /rr\
-------
                                                                          Page
                                                                                                  of
 Plant Name:
   • *••**
 Run Number:
                 -3 3
                                     Test Date:
                                     Operator:
Tnverae
 Point
Number
Sampling /dock Time
 Time,  / (24-hour
 (rain.) /   clock)
Gas Meter
 Reading
 Velocity
llead^P.)
 In. IhO
Orifice Prcs. Oiffetential
    (All) la. 11,0
                 Desired
          Actual
 Stack
Temp.*F
  m
   Probe
Temp./ Filler
 Temp* F
Impinger
 Temp.
  a PC.O''
Dry Gas Meter Temp.
                                                               net
                                                        UUIICI
 Pump
Vacuum
 In.llg
                                    1'0
                                     \-o
                                                                       '
                                                                                                    JT
         Ho
                              o
                  \.o

                  Vh\1
                            • in
                                                                              V ~7
                                            \.\
                                             \. \
                                                        5*3
                                                                q i
                                                                _T
         VStr
                              U
                                                                              GO
                                                                          r/
                         (ofck) D
                             .  15
                  U
                  U,
                        O-it?
                             1,0 1
                                 ^
          1S
                                              ,6
W
  wo
         . ,04-
                  , <  3
                 T-M
                   Gs
                                           ,53
                                                                                         f
                  \WV
                                                    733
    4
                                                                                                   40
                                                                         Ml
                                                                                                    "b
                                    .0?
                   \vst
-------
09/09/97   10:19    O19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: A/A U P A C A .K ^ M M D *.Y
Sample Date: ^\^H> Filter No. (s): )3o- 2.3-1
Run No.: 8o-53-<
Job No
-: 5MIH.o^3
Sample Location: O /A£? (4 & u-5 & ^ UT uErr
Recovery Date: °\|^h'> XAD-2 Trap No.(s): 6ft-
l*-\

Sample Recovery Person: ^Y~{ P>£.
^Sii-Si^^
Impingers
Final wt.
Initial wt.
Netwt.
12 3
XAD-2 (knockout) (100 ml H2O) (100mlH2O)
Trap (untipped) (tipped)
— 55H . u >/T-.> ?6^.^
— <.(?«/• o >i<1.5 7/^ -5
— (rD.fc ~/.S "X 3
4
(knockout)
(untipped)
6633
5'^ . xl
H-l
:.' -'^ .':•:.- ;!^- •'.*'« •liT.-.v/Cirrs'is.'" ;*•*•' '*••
''•.'V^T!-':'-1-"'-*^'' ••*'i?.*-.i;-:^v^ri"--:.(:>
Silica gel
(untipped)
$i5^.^ g
•cOio.^ g
25*> g

Train System: M^.^^ x> 3 ~T@j\'f/ l~Tjyrt\L'- Hb.'S A -^
Probe:
7) ' /"/
Y ^ /(>g5
J

i • — ' / '
Filter: Color- ^ttjkA IA/O Loading- L/£i-fr
Impinger Contents: 0' Ty/>£ -^ ^^O
Silica Gel:
@GramsUsed- .^00 Color- '/. i>K < °/
a Spent - f |
^
Condensate Observed In Front Half: kl>>^iE^
fiftSifillftli!^
Filter Container No. T~
XAD Module Container No.: ^
Probe (FH)
Probe (FH)
& Back Half Rinse (Acetone) Container No.: ^
& Back Half Rinse (Toluene) Container No.: 1
Impinger Contents Container No.: / D
Impinger Rinse (Acetone/Mfl©t2) Container No.: 7

marked/sealed:.^
marked/sealed: ^£,
Liquid level — ^
marked/sealed:^
Liquid level -^
marked/sealed: ^
Liquid level ~~
marked/sealed: 1^_
Liquid level ~.
marked/sealed: Er^


-------
 Plant:
                     3 -  -Z_
Sampling Location _
Run NumberPn^v ^-   Date:  °\ -\ o -^ -j
Pretest Leak Rate: rp0\   cfm @ \S  in. Hg.
Pretest Leak Check: Pitot: // Orsat:  */*
                                                      FIELD DATA SHEET
                                                 Sample Type:  h 7 3     Operator:  (-, C
                                                 Pbar: Q-^S    Ps: -\-  ^f
                                                 C02:   l.Q     02:    1.5
                                                 Probe Lenglh/Type:  ^
                                                 Slack Diameter: Q[ 7
                                                                      Nozzle ID: .3<
                                                                      Assumed Bws:
                                                                      Meter Box #
                                                                                                  Thermocouple
                                                                                                  Fitter #:
                                                                     Pitot
                                                                  As:  flip. I
                                                                      Post-Test Leak Rate:   go*/ cfm @
                                                                      Post-Test Leak Check: Pitot:   iXbrsat:
                                                                                                              :  / . g-T?
                                                                                                                 in. Hg.
\4s«tf
Traverse
 Point
Number
   O
JL
    Sampling
     Time
     (mln)
        (0
       >S
       ro
       70
       7/
       \\0
dock Tim*
 (244iour
 dock)
                ^Ji_
            O^tQ
              \o-bv
                        Gas Meter
                        Reading
                         (Vm)na
                         .  4-
                      ion.
                             .0
                  AVm
                                              Velocity
                                             Head (Ap)
                                              inHZO
Orifice Pressure Differential
     (AH) in H2O
 Desired
Actual
Stack
Temp.
 (Ts)
                   Temperature
                      °F
Probe
FOtet
               Impinger
                Temp.
              Dry Gas Meter Temp.
  Inlet
(Tm in°F)
  Outlet
(Tm out°F)
 Pump
Vacuum
(in. Hg)
                                 Y//////////////////^^^
                                       »ot
                                     ,05
                                       , OS
                                       ./O
                                       .10
                                       Ml
                                       . 1
                                        , to
                                       —ux
                                        , 30
                                       , 1,0
                                           0
                                     ,2,3
                                                 /. 0
                                                \.
                                                 l.D
                                                   \S. S
                                                ±LJ1
                                                      -
                                                           . $
                                               /. O
                                                          1;  L
                                                          i J
                                                                  Pdo.
                                                       cut
                                                                  Tfc
                                                               M
                                                                          Ms
                                                                        Hi
                                                                                  2
-------
                                                                        Page
                                                                                               of
Plant Name:
Run Number:
                          - -L
                                                Test Dale:
                                                Operator:
Tnvcne
 Point
Number
Sampling
 Time,
 (min.)
 /
/
/
Clock Time
(24-hour
  dock)
Gas Meier
 Reading
 Velocity
Head (P.
 in. IhO
Orifke Pres. Differential
    (all)m.UsO
                Desired
          Actual
 Slack
Temp. • F
  ft)
   Probe
Temp./ Filler
 Temp." F
Impinger
 Temp.
Dry Gas Meier Temp.
                                             Inlet
                   UUIICl
 Pump
Vacuum
 In.llg
                             LL
                                                    .s
                                                                               I
                 \\\2>
                            .14-
                              1,5-
                                    \. 5
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                                                             is
                 \\\i
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                                                                        105
                          0.5 •
                                   7,3
                                     1-3
                                                             So
                 \\b>
                                   l.h
                                                                  5>
                                                                      1 0
                                                                               £
                                                   T>. I
        U,0
          \\\~b
                               . "i
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                                                                               Si
                                                                                                 J-T
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                            -
                                   102
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           0
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                                                                                                lo >
                                                                                                lo y
   .f

                                                                                                        A.
                                                          •>-S*\

-------
09/09/97   10:19    ZJ19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: \lbl\P A<-A . f~^
Sample Date: ^llkl^
Sample Location:
a/Vi)^V
Filter No. (s): 6ft -2-3-2^
Run No.: 60 -23 -Z
Job No.: S'-/(c/.c)()^
BA^ HOUSE "Dtfrz^r-
Recovery Date: *-j | |D | iT-
Sample Recovery Person: K-£
XAD-2 Trap No.(s): 6j&
- 2.3-^
- BE

Impingers XAD - 2
Trap
Final wt. —
Initial wt.
Net wt.
1
(knockout)
^"31%
H~)5-5
SP>.^

Train System: EPA ^e4llp
2 3
(100mlH20) (100mlH20)
(untipped) (tipped)
7%7/, / ~?o(.2-
^3.2. 1-C3.M
-2. 1 -^-2
4
(knockout) Silica gel
(untipped) (untipped)
^"77. 4> &&£ g
5^to .*? BS^-9 g
3. > 35. lo g

o( 23 /JTS-TAi
. ^,3^, ^
Probe: ~t Glfi^
Filter: Color- fj. b'bun>
Impinger Contents:
Silica' Gel: @Grams
C^Ar
Loading- L-'ArX,^



Used- 30-0 Color- H V^ % Spent- 50
Condensate Observed In Front Half: k 1 1> >0 E.
^•^^^^^^S^^^^^^i^i^t^^^^^^^^^^-
Filter Container No. I ^
XAD Module Container No.: i~
Probe (FH) & Back Half Rinse (Acetone) Container No.: I C
Probe -(FH) & Back Half Rinse (Toluene) Container No.: I U
Impinger Contents Container No.: I °\
Impinger Rinse (Acetone/M*6t2) Container No.:

^•^V!^^i'^-«ew,ivc%»v^r;'h«i»;^fr»:iHi*',^.^
^^SK^.'.-fS^^^SSSii^g^-
: -^- -i. .. !,.,,-.....*.;.;> :r.!i--,i •!••::*!•:.:.& ,t :. •»•;• '. f -,- tt. \-~-i r.i-1 -V -XT:
marked/sealed:^
marked/sealed.r^f
Liquid level ^
marked/sealed^—-
Liquid level
marked/sealed:E>
Liquid level r^
marked/sealed: V 6-
Liquid level ^
marked/sealed:


-------
                                                 FIELD DATA SHEET
Plant:	
Sampling Location
Run Number:
                        in  <=>*
Pretest Leak Rate:
Pretest Leak Check: Pitot:
                       DatB:<\~(rj-q-]
                        cfm @ \5 in. Hg.
                           Orsat: ^
                                           Sample Type: _
                                           Pbar
                                           CO2:
                                                                 Operator:
                                                                        Nozzle ID:
                                                                                          Thermocouple
                                              Ps:
                                              O2:
                                                                         Assumed Bws.jPS Filter #:
                                                                         Meter Box #: K*AJ3 Y: J.OiG_
                                                                                    —  -Li^       ™~
                              Probe Length/Type:
                              Slack Diameter:
                                                                       Pitot *:S E
                                                                    As:   \aty
                                       Head (Ap)
                                        inH2O
Oriice Pressure Drfterefibal
     (AH) in H20
 Desired
Actual
Stack
Temp.
 (Ts)
                    Temperature
                       °F
Probe
Rhef
                Temp.
                        Dry Gas Metar Temp.
  Inlet
(Tmin0?)
  Outlet
(Tm out°F)
 Pump
Vacuiun.
f"n.Hg)
        r
                                         JQ£_
                                       JL21.
        Ifc
        1 S"
                            .  It-
                                                               U
       •5 0
                                         _OJL
                                                                                                                   q)
               \5
                                         • b f-
                                                               .•f-3
        QO
               NbOO
                            Q 
                                                                ,4-3
                                                                      74-7
                                                                                                  fU
\toT
                                         • 03
                                                       33
                                                                                         ->$>-
                                                                                          \0o
\
                                          .63
                                                     .33
                                                  .33
                                                                                        5,53-
                                                                                                  4-1
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                                                                ,1)1
                                                                                               3-5
       To
                                                                                                        Iflr.
              vi o y
                             .(a
                                                    1. fa
                                                 t.e,
                                                                                                   qn
               \TOfe
                                                              01,
                                                                                     47
                                                                                                           7
                                                                                                    n
   "S
                                                    3,o
                                                                                                    "6
                                                                                                           fb
                                                                                        7-41
                                                                                                        Ito*.
                                         . 30
                                                                                                                          JX
                                                     -J.v
                                                              7,4-
                                                                                           lot
        \\0
                                                                                                   4$
                                                                                           IbS
                  v\
                                                                       3S(,
                                                                                                  U
                              . 708
                                                     SH
                                                       Ti-
                                                                                       Tm
-------
                                                                                 Page    ~L   of
   Plant Name:
   Run Number:
                                                      Test Date:
                                                      Operator:
   Traverse
    Point
   Number
Sampling
 Time,
 (m!n.)
 /
/
/
dock Time
(24-hour
  clock)
Gas Meier
 Reading
 Velocity
llead^P.)
 in. IhO
Orifice Pres. Differential
    (all)in.U20
                Desired
          Actual
 Slack
Temp. • F
  m
   Probe
Temp./ Filler
 Temp* F
Impinger
 Temp.
Dry Gas Meier Temp.
                                             Inlet
                                                      UUIICI
 Pump
Vacuum
 In.llg
      1
                                  >.<&
                                                    Mo
                                                                                                 -T
                                                      U
                                                   O-Sji
                                                              /
                                                                         T7
                                             V> fl.
                                       15
                                    l.fc
                                      l.t,
                                                                                  1
                                                                               |0t>
                                                                                   43
           I/O    /   Ifrifr
                                            I.I
                                                   750
                                                                 4*
                                                            lo 1
                                                              43
                                               3^
                                                                         IK,
                                                                          / 3

                                                                         ? 5 J
                                                                         41
                                                                                        in v_
                                                                                                           h
                                                                                                           i  /

                            . \5
                                       K
                                                                                  44
                                       \ a
                                                          "36\ / 56 b
-------
09/09/97   10:19    019199410234
                                           PES RTF NC
                                                                                ©003
                    METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
   Plant:  UlriuP&d
                                  O/lV
                                                            Run No.:
    Sample Date:  C[\  |o
                               Filter No.(s):    bc-23>-3
                                                               Job No.:
    Sample Location:
    Recovery Date:    )\
                              XAD-2 Trap No.(s):
                                                              5  -3
    Sample Recovery Person:

    Impingers
   Brian
           XAD -2
             Trap
                           1
                       (knockout)
(100mlH2O)
 (untipped)
(100mlH20)
   (tipped)
    4
(knockout)
(untipped)
Silica gel
(untipped)
         wt
                                               -2.0
    Initial wt.
                         -M
<<
KgfW.
•^...i.. ,.•....-...-.«.
                             1
^.^'V'-V'11'!^"'™^1*'"^1^"* X""*^'^*1''^^.'«V^v
                                         r.1 Vr';";'-'^?1''"^""'"' ~ ^.~*v-:-; ;••?•••'--•::•'•'-•••.•'••?"•; •'.-.-•™;-i>-:-.-.x'.".- ..•;.». .:=.s-.--»s»-«.'i'sl.«i'.'?'»1«"-
                                         S^^
    Train System:  SPA
    Probe:
    Filter: Color-
                                    Loading-
    Impinger Contents:
    Silica'Gel: ©Grams Used -
                                    Color -H.
                                                           Spent -  £
    Condensate Observed In Front Half:   fJo/\r&
    •-;:•:'•$. :-^-;.-.\--.F:::'e^-#&-^''--i-"i--!-^.#^^^
    S;:S'Stl^i^A^?^||g^^
    Filter Container No.
                                                             marked/sealed
    XAD Module Container No.;
                                                             marked/sealed
                                                                             v^T
Probe (FH) & Back Half Rinse (Acetone) Container No.:  / ?"
                                                                Liquid level   ' *~*,-
                                                                marked/sealedv^r
   Probe (FH) & Back Half Rinse (Toluene) Container No.
                                                      r T
                                                             Liquid level    7^
                                                             marked/sealed/^
Impinger Contents Container No.:
                                                                Liquid level    (V
                                                                marked/sealedtf^
Impinger Rinse (Acetone/Mc6<2) Container No.:
                                                                Liquid level
                                                                marked/sealed:
-------
                                              FIELD DA IA SHEET
Plant:
Sampling Location /"„*„/. o.J-<~\
Run Number: fc, - \
Pretest Leak Rate: /0^_?
Pretest Leak Check: Pitol:
Date: ^j-^-^7
_ cfm @ _^5 in. Hg.
•x" Orsat: i^
Sample Type: **, z_^>  Operator:
Pbar:  -z^.gg    Ps:	.—
CO2:     ->      O2:      '-7
Probe Length/Type: < '^
Stack Diameter:    ??'
                  Nozzle ID:  . •». Thermocouple #:
                  Assumed Bws: ,»f Filter #:
                  Meter Box #?"/ 3
£f_ Pilot #: c,&
 As: Hfe.2. ft *•
Y: }_Kt^


























Qockrime
(24-hour
dock)
^J-


•*= -2-


fl 3




















Gas Meter
Reading
(Vm)«3
r7r. ^-73


573-0^3


5Ti- 2^3




















Velocity
Head (Ap)
inH2O
Orifice Pressure Oifferential
(AH) in H20
Desired
Actual
Stack
Temp.
as)
Temperature
°F
Probe
//////ys/s/////yyy^
• 00^^

,6Q 5 'ifl

7jsP^
.aoC £-Pt*i




















Sf.» Mf

rs ;-f<;

%£**-+*$
'S.'^dt


































































































Fitter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin°F)
'///////////////A














































































Outlet
(Tm out°F)
Pump
Vacuum
(in.Hg)





















































                                                                 Ti=
                                 Tm=
-------
09/09/97   10:19    S19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: \A/AU PAcO F&WN
Sample Date: ^19^. Ill-
Aft-V
Filter No. (s): F6- n- \
Run No.:Fft-za,-
Job No.: *>H/^-^^3
Sample Location: &A-c;touwri E-r
Recovery Date: ^l 1$ n "9-
XAD-2 Trap No.(s): ^$> - 2. 5> - I
Sample Recovery Person: ^.V-- \lSEL

1
Impingers XAD - 2 (knockout)
Trap
Final wt. — V^.^
Initial wt. — M">515
Netwt ^ o.o
!?SfJI^^S}5^Sfif^SS8
2 3
(100mlH2O) (100mlH2O)
(untipped) (tipped)
lD3. -2, lZi>.L-{
l&.'i.-a. T-o.iA/
onn o.-o
SSSilSliSiSSiSiSS
4
(knockout) Silica gel
(untipped) (untipped)
5"^fo.^ iKM,^ g
5"7fe-.^ $?^V.^ q
^ -T7 6?. O g
^•^:vZ^^:&^3^:ii^&Xte
•^4^.^^^i2bj-rt<{v.-^-yy:s^:4*;'ii^Av?
Train System: Me^6o\ 2f> ~~r£AA
Probe: l' ^/AS^
Filter: Color- VW-f<
Loading - A^o N £-

Impinger Contents: ^feor
Silica'Gel: @Grams Used - 33? (J Color- P>\u
-------
                                              FIELD DATA SHEET
Plant
Sampling Location
Run Number: rX-?^3/«,^Date:  <>-;>-O -2-

•O& 7.





















(O

-------
09/09/97   10:19    Q19199410234
PES RTF NC
©003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA /v? -72.^
<
Plant: /A/A//#£# fou^ty-
Sample Date: V' ' A 7 Filter No.(s): /*"£,*- 2 B
/
Sample Location: /-vV^r /?(*«(< *,t '/e*r //fe, -
_
Run v\Ci..~f /g-^-^S
Job No.:<^$'5Vy«^6'3
^**!>i0o*«' 
i
Sample Recovery Person: (%/£&£ /&. £/*~f>

12 3
Impingers XAD-2 (knockout) (100mlH2O) (100mlH2O)
Trap (untipped) (tipped)
£inaTvft - 0-6 ^O-l -D.I
Initial wt. " ^~?(efi "foZ.y l&l.fy
Nef& - V7fr,^ 7»^S ^^T!^
4
(knockout) Silica gel
(untipped) (untipped)
0.D -01
£"??•£ 82o.^L
4frf.(t. $70,^

q
9
9

Train System: ^•Jpf\ P\<_<\-\c?c\ '23 / TbrAt-'
Probe: "^' Qla-55
/).0a
?


Filter: Color- Ui^^ Loading- Afo^^
Impinger Contents: CJ^A
Silica'Gel: ©Grams Used - ^>0 Color- M^li'l^ % Spent- &
Condensate Observed In Front Half: /t^KjZ/

Filter Container No. yi
XAD Module Container No.: 90
Probe (FH) & Back Half Rinse (Acetone) Container No.: j%?
Probe -(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.:
Impinger Rinse (Acetone/MeCI2) Container No.:

3Pi
•^-vixj
marked/sealed: ^C^.
marked/sealed £/^
Liquid level xv
marked/sealed axe
Liquid level
marked/sealed: ^*
Liquid level
marked/sealed:
Liquid level 	
marked/sealed:


-------
 Plant
 Sampling Location
 Run Number:
Date: 9-7-
 cfm @
                                               FIELD DATA SHEET
                                    Sample Type:  /ft - eo/o  Operator:

                                    CO2:    9      O2:    /
 Pretest Leak Rate: . OQg  elm @ £_ in. Hg.
 Pretest Leak Check: Pilot:   t/^Orsat:  ^
                             Probe Length/Type:
                             Stack Diameter:  <72/'
                                                              Pitot #:
                                                           As:
                                                          Nozzle ID:  .340 Thermocouple #:
                                                          Assumed Bws: >oG Filter #: £<9-oo /a —/
                                                          Meter Box #: ^ 2,  Y:. 9^7 AH@: /.g/
                                                          Post-Test Leak Rate: .^cy cfm @ Xj/ in. Hg.
                                                          Post-Test Leak Check: Pitot: i/ Orsat: —
Tr
 Ro«nl
NumtoM
Sampling
 Tkm
 (mln)
OockTm
 docfc)
Gas Meter
 Reading
 (Vm) n3
                Velocity
               HMd (Ap)
                InHZO
Oiftc* Pt«»aur« Diftetcntial
     (AH) in H2O
 Desired
Actual
         Stack
         Temp.
  Temperature
     °F
Piobe  |   FOtsr
knpinger
 Temp.
Dry Gas Meier Temp.
  Inlet
fJmin°F)
  Oudel
(Tm out°F)
 Pump
Vacuum
f«.Hg)


                                       •II
                                                                                                     T 9
       10
                                                                     253
                                                                      ZSC,
                                                  /•
                                                                                                     V?
       zo
                                           A3
                                                             2.5 7
                                                                                                           vo
                                       .zo
                                                    2,0
                                                           /. -5
                                                                                     60
                                                                                      5-7
       35
               67 5.
                         JTT.&
                      £-»*>. "I
                                                            2^7
                                                                                                   92-
                                                           .  5
                                                             23?
                                                              2*53
                                                           .262,
                                                 l.v
       00
       H LI  a
         69/. 2.3 2-
               .0?
                                            233
       65
                                        6,5
                                                    o.j
                                                          /.O
       05
       U-
                          . 2,
                                                                                     W
                                            1.1
                                                      •zyo
                                                   -2.S1
                                                                                                     ^-
                                       .1)
                                                    t, /
                                                                              C Z
                      111.7
                                 Jo
                                    1,0
                                  /• 0
                                                                                    It
       )Ot)
                TJ.O
                         ./J
                         I'f
                                                                                                  721,750
                                                                                                  C.77. /"Oi-
      104
               mfi.o
                                    /.I
                                                  257
                                                                   •7
       i/O
                TIN
                          . 11
                         /.I
                                                                     GO
                                                  'OO
                                       v\\
                                                                                                    4J-
      126
                                 .l
                                      ,03
                                                                                                                  tl'F
                                       • 0
                                                    GJ
                                                              IS/
                                                                  6?
      w/ *,.,<

-------
                                                                               Page    2,     of
Plant Name:
Run Number:
                                         Q
                                     Test Date:
                                     Operator:
                                                                                             i
Tnvene
 Point
Number
       Sampling /dock Time
        Time,  / (24-hour
        fmin.) /   clock)
Gas Meter
 Reading
 WOft*
                        73>.Z-
 Velocity
llead^P.)
 ilLlhO
Orifice Pres. Di/fercntiaJ
 Desired
                                           0.3
Actual
                                                  0.2
 Slack
Temp. • F
  m
                                  235
   Probe
Temp./ Filler
 Temp." F
                          Impinger
                          Temp.
                                                                             65
Dry Gas Meter Temp.
                                             Inlet
                                                   to/
                                                      UUIICl
 Pump
Vacuum
                                                                                                                 /£
                         0.6
                        753.JT
                                    • O
                        7^,6
                                            . 5
                                                                                 5
        2^5    '  '32*
                                    .03
                                        2.3 S
                                                   '*/
                        7C/.V
                                                          ^33
                                          0.3
                                                          z-i
                                                           /ot-
                            , V
                                                                 25*
                                                  0.3
                                                                                     lot
        230
                            . "1
                         **!>
                                                   '02,
                                    .03
                                                 6
                                    ttftl.
                               '^
                                                                     f*
                                                     _3


-------
09/09/97   10:19    ©19199410234
PES RTF NC
i)003
METHOD 23X3BDJQOF SAMPLE RECOVERY DATA

Plant: VUuPAtA . ^
Sample Date: ^iT^
Sample Location: Da £> ^> *•?(
Recovery Date: ' °l ll\<\>
aOo^-Y
Filter No.(s): 60 -Oo\o-\
=. CW&T-
XAD-2 Trap No.(s): Bo
Run No.: VS^-0(?(6-|
Job No.: 5MlM. 0&3

- tiTD 1 «3 -
Sample Recovery Person: R-M £> F_

1
Impingers XAD - 2 (knockout)
Trap
Final wt. — o 3D , ^
Initial wt. ~- HH-'J
Netwt. — " 5to.t>
V^:SSa-i'S?20'4^"^^.%i':fe?:.'V5 '^^"A -
^:^Moisture;Datass;v':r^A^::
2 3
(100mlH2O) (100mlH2O)
(untipped) (tipped)
IM^.S ^2-5,5
^H3.5 7ZS-I
^ ^ -/.&
.:-r..':4'j..ir .:£;••;..•.-_;. .::>-^'.-;'.....:^:,-.»;^i?tV-i:fr-:.;V1.<^'-*^;v';-;'-' "'
•^:^;':S^^^^^S'^^^^
4
(knockout) Silica gel
(untipped) (untipped)
C?2-2.-^ '•'iiip.o g
(j i"i . S &^°1>C1 q
2.<\ 2(*,\ g
i^l^^^sv^^
; ;Vi^;a;fe:^^
Train System: £PA MtTlAfcCi
Probe: u? ' (3 /ift5
Filter: Color- L'Qwt TAIS
Irnpinger Contents: t) ) ~T ft
» 2^ T/Z^IA/ / &ttV it

Loading - / ^MT
>t JT )-i7b
v / 1-^ 7) t i
> : N- 19 1 ImAL- M I rt
^


Silica'Gel: ©Grams Used - 36o Color- )4. h)u-» %Spent- ^0
Condensate Observed In Front Half: K) o wt.
•'vl -^r -;i^'^i-^^-:?' r -o^^K^^
v'^£££^7&^£^
Filter Container No. 1 \
XAD Module Container No.: \ ^
Probe (FH) & Back Half Rinse (Aootonc) Container No.: \"b
Probe (FH) & Back Half Rinse (T&luonc) Container No.: ) ^
Irnpinger Contents Container No.
Impinqer Rinse (Ac«*erre/MeCI2)
'5"
Container No.: 1 "

/1/7
marked/sealed: irz
marked/sealed: UlC
Liquid level
marked/sealed: £.1^
Liquid level
marked/sealed: j^_
Liquid level
marked/sealed: *-J^
Liquid level .
marked/sealed: ^1L

-
-------
    ling Location
Run Number: &0-ooio-2 Date:
Pretest Leak Rate: .0/0   cfm(
               . o/g   em    ^5" in. Hg.
Pretest Leak Check: Pilot:  •"" Great:	'
     FIELD DATA SHEET
Sample Type: M-oo'Q  Operator: T tf~
Pbar 29. tSg    Ps:	.2)
CO2:   7 .<3 ^gfe O2:
Probe Length/Tfpe: £'\
Stack Diameter: * f 2 *
   Pilot #:
                                                                                     /s -  /->.
Nozzle ID: .&?O  Thermocouple #:
AssumedBvw: .oV Filter #: ^G-GO/O-Z-
Meter Box #: /3  Y: .9V? AH@:  / P/<9
Post-Test Leak Rate:. A&<» cfm <&& in. Hg.
As:
                                                                               Post-Test Leak Check: Pitol: *XOreal: —
-------
                                                                              Page
Plant Name:
Run Number:
                                  - 7
                                                                Test Date:  __L/a±
                                                Operator:   77
Traverse
 Point
Number
          Sampling
           Time,
           (rain.)
 /
/
/
Clock Time
(24-hour
  dock)
Gas Meter
 Reading
 Velocity
HeadtP,)
 ia.IhO
Orifice Pres. Differential
                Desired
         Actual
 Stack
Temp. • F
  ft)
   Probe
Temp. / Filter
 Temp* F
Impinger
 Temp.
Dry Gas Meter Temp.
                                            Inlet
                                                      Uutict
 Pump
Vacuum
 In-llg
                         fW. 3
                                              /.
                                                                                  ?9
                                                                                        /O
                                    /JS
                                                                                                 *
                                                         £(*(/
                                                                                       IIL,
         2.VO   /
                                                                                     'no
                                        .  .J.-7I:
                                                                                                  /
                                                                                                 -/
                                                                                                               «f*'j
-------
09/09/97   10:19    ©19199410234
PES RTF NC
©003

METHOD 33*6
Plant: W/4l«PA<:A . Hi*
Sample Date: c// 'I oft 9-
Sample Location: t5Af)K(bi(<&E.
Recovery Date: 'Hjlo 1^3-
Sample Recovery Person: fO/.0&3

XAD-2 Trap No.(s): 6 C5 - 0> 1 0 - Z

^^^^l^^^iS^^iiSS^iaS^^j
1
Impingers XAD - 2 (knockout)
Trap
Final wt. — 55 L1. 5
Initial wt. — M^tS.M
Netwt. - *5 >52..T-
-D-> -l-^
^:=S^i=KKii1::=--;u;:~^Sta!^.?P;::i;TW®»n!r;t
;;:>f:^::Si^^^:im^*'2^i^i^
4
I (knockout) Silica gel
(untipped) (untipped)
o zo .~D 8- '•!& .7 g
u-i^ { C-l'i.z g
L^\ ^.5" g
:1SI5SiSI^
Train System: M fl\ S' T£A
;M / foOX iD= N/-'o / Tfcr/H^ "8>R,^ /» 
-------
                                 FIELD DATA SHEET
                            Sample Type: fi-c^sa   Operator:
                                               2 ?.
Plant   1^6..p*t^  ptHjir*^.'
Sampling Location  B*e^,*it
Run Number: ,80-00/0-3 Date: f - /o
Pretest Leak Rate: .00^  cfrn @ &  in. Hg.                    	
Pretest Leak Check: Pilot: _*^ Orsat:   —     Slack Diameter:  92"     As:
                                                                                 Nozzle ID:
    Pbar:
    CO2:		
    Probe Length/Type: 5' £/t<>  Pilot #:
                                                        02:
                                                                    Assumed Bws
                                                                    Meter Box #: /j
                                                                    Post-Test Leak Rate:
                                                                    Post-Test Leak Check: Pilot:
                                                                                           Thermocouple #: 70
                                                                                           Filter #: (*&-.O6jo- •?
                                                                                           Y: .W7  &H@:  frtf
                                                                                                 cfm @//  in. Hg.
TriVWM
 Pofrit
Number
Sampling
 Tiro
 (mln)
dock Time
 (24-hour
 doe*)
                       GasMetvr
                       RwcSng
                        (Vm)n3
 Vttodty
Head (Ap)
 inH2O
Oilloa Pre»sur« Diftertntial
    (AH) vi H20
 Desired
Actual
         Stack
         Temp.
  Temperature
     °F
                                       ////////////////////////,
Probe  I  Fitter
knpinger
 Temp.
  °F
Dry Gas Meter Temp.
  Inlet
(Tmin°F)
  Oudet
(Tm oul°F)
 Pump
Vacuum
(in-Hg)
                     ^3,3-28

                                                                   y////////&y/y///////////A
                                                 /
                                                         /.
       to
                               ./c
                                             /.c
                                                            262
                                                                                                        f-r
             .-5VO-
                                                   A*
                                                                              33
                                                                                                                7
       15
                                                                                  £6
                                                                              33
       •20
                f6fi
                                   /. 5
                                                                                 Z.3"
       3,5
                                          2,0
                      9-77.0
                               ./f
                                   Z.o
                                                                          2 Si.
                                                                    19
       -V5
                                                                            2-C.I
                                                                           A?
                                                                                                       
-------
                                                                                      Page    2— of
      Plant Name:
      Run Number:
                &O-OOI6- 3
                                                 Test Date:  __lz^i
                                                 Operator:

O^T*^
     Tnvene
      Point
     Number
       c,
Sampling
 Time,
 (rain.)
 /
/
/
Clock Time
(24-hour
  dock)
              /35
                     /
             ' /to    I
             i9S
              12*
  ^bS   i
              i•?
Orifice Prcs. Differential
    (£j|)in.U2O
                 Desired
                                    A J
                                    Af
                                                Z./
                                    /. 0
                                    / .0
                                    / o
                              1.0
                                                 1.0
                              I : 0
          Actual
                                     /-J
                                            /. 3
                                     A 9
                                            z.f
                                           2,1
                                            / f
                                                        /, O
                                     1.0
                                            I , 0
                                    /.o
 Slack
Temp. • F
  m
                                                    25$
   Probe
Temp./ Filler
 Temp* F
                                                           253
                                                           25
                                                           25"?
                                                           LSI
loipingcr
 Temp.
                                                               is
                                                                            Q
                                                              5-7
                                                                  5-3
                                                                                   •$"7
                                                                   v?
                                                                                   £?
                                                                         r-7
Dry Gas Meter Temp.
                                              Inlet
                                                                          77
                                                             /e>6
                                                                               /a
                                                                       99
                                                                                            /o /
                                                                       /OO
                   UUllCl
                                                                                   1C
                                                                       
-------
09/09/97   10:19
©19199410234
PES RTF NC
METHOD 23 GDD/ODF SAMPLE RECOVERY DATA

Plant: VM^uPAcA J-CHuv/O-R-Y
Sample Date: <-{ \ W \ <\ > Filter No.(s): BD - O-D i o - „
Sample Location: !9A<}K^ t/S E ^-"iT (.£T~
Recovery Date: £\ | \\ n^ XAD-2 Trap No.(s): BO -
Run No.: f^-ce.r -3
3 Job No
, ^/t/.^5

0 0 ID - ^

Sample Recovery Person: \cfc\ ^—

1 2 3
Impingers XAD-2 (knockout) (100mlH2O) (100mlH2O
Trap (untipped) (tipped)
Final wt. «• 53£.c "7fV. - 7^-i.f
Initial wt. - H^5v^ l-M^-4 >2-3.T
Netwt. - b5«(^ -M-4 -0.&

4
i (knockout)
(untipped)
b ^- 7
(s&:S^.^^^?f>,gp:^^gp|^:^
Silica gel
(untipped)
V'teZ g
6^1/j.O g
3H-5 g

Train System: G- PA M&rMo 0 D^^o /Ift-ft-iM (A1- K/-'Cs /TTr^: 9H-M a ^
Probe: v^ nwv\ • Loading- If^M
Impinger Contents: C\Q(\c


Silica'Gel: ©Grams Used - 300 Color- |{- b/u(- % Spent- b^>
Condensate Observed In Front Half: /OMFL
••-•••••••:-:\.f~:^^^'^-^Jr~-'**^'
-------
                                               FIELD DA IA SHEET
Plant:	
Sampling Location  d.,
Run Number:
                      \ o ++.1
- )
 Date:
- cfm
                            V y
Sample Type: A -ao/t>
Pbar:   -zq. 5"_5  Ps:
CO2:    3      O2:
                                                              Operator:
Nozzle ID:	
Assumed Bws
Meter Box #:  ,
                                                                               Thermocouple #:_
                                                                               Filter #:  /=g -/
Pretest Leak Rate:  .£/"2- cfm @ _/£_ in. Hg.
Pretest Leak Check: Pilot: /x^Orsat:  ^-
                                          Probe LengthH"ype:  $'cte.*s
                                          Slack Diameter:   f 2 /f
                                             As
                           Pilot
                          ' -U.;
                                                            56
                 Y:. 9*7 AH@:  /.
Post-Test Leak Rate: .0^- elm @ jC5^ in. Hg.
Post-Test Leak Check: Phot:      Orsal:
Ticv«rM
Point
NumtMi



























Sampling
Tlnw
(mln)
61$


























Qockrim*
(2*4iour
dock)
{^K&^K
*£-

U*Ki
C^ttf
**t
ir ^




















GasMeUr
Reading
(Vm)(t3
^VD. ?^0
*-^-

cy.t 03


63/. 2-?«?




















Vttocrty
Head (Ap)
lnH20
Oiif ca Praosur* Diltertnlwl
(AH) in H2O
Desited
Actual
Stack
Temp.
asj
Temperature
°F
Probe
FflM
Impinger
Temp.
°F
Dry Gas Meter Temp.
Met
(Tmin°F)
Outlet
(Tmout°F)
Pump
Vacuum
f«.Hfl)
y//////////////////////////^
n*1j

A.O


Xtf,




















. <9/
-------
09/09/97   10:19    ®19199410234
PES RTF NC
©003


CO 0
3LE RECOVERY DATA
Plant: WAuP^-A . ^oufjQfO-c1
Sample Date: °\ 1 & U"} Filter No.(s): P~fb - Odd - i
Run No.: FB>-aoi&-,
Job No.: ^H IM. 0^5
Sample Location: RA ^-UNU^f-r. T)KTt,£--r
Recovery Date: lC)|dhT XAD-2 Trap No.(s): p~6 - t>DlO- |
Sample Recovery Person: R^ 1 o£.

1 2
Impingers XAD-2 (knockout) (100mlH2O)
Trap (untipped)
Final wt. — MV\-b iM^sr
Initial wt. — M':H'& IM^.1?
Netwt. — C-& D.O
3
(100mlH2O) (ki
(tipped) (u
3-2-S.t (^
~YL^*\ (j
c. .0 c
4
lockout) Silica gel
ntipped) (untipped)
ft* B9^-^ g
^•"S ^^-^ g
^ -o o-o g

Train System: KHI6 -TfcAiO /D X I D
* IL. I ™ V J"^^ /"T*^.*- *
Probe: ^' Glaf??
Filter: Color- C\P^f^*^ Loading- JVDi vj* ^ % Spent - 2> . T?>
Condensate Observed In Front Half; J\J&^£

Filter Container No. i
XAD Module Container No.: o
Probe (FH) & Back Half Rinse (Acetone) Container No.: {g
Probe -(FH) & Back Half Rinse (Tolucne)-Contalner No.: —

Impinger Contents Container No.:

Impinger Rinse (A£elone/MeCI2) Container No.: — —

marked/sealed: <^.^-
marked/sealed: i2.^
Liquid level
marked/sealed: {LU-
Liquid level
marked/sealed: ~ 	
Liquid level
marked/seated:
Liquid level 	 	
marked/sealed:




-------
                                            Pacific Environmental Services, Inc.




                                               Dry Molecular Weight Determination
Client/Proiect: ^H^^ffCA -%WV.oo3 OrsatNo ^ "~ ^~
Date/Time:
^T?/T7 Operator: 
Sample Type:
Ambient Temp. 'F

Run No.(s)

Run No.(s)
V'lP

Run No.(s)
•^^H^HMM^BM*


Gas
•
CO,
o,'
CO"
N:'

Gas
CO,
0,'
CO"
N,'
Ort«x n *Y
70

Run i
Actual
sr.3
I0j iJ


Net
L/C

&$*


Comments:
Site Location: /3*B

Multiplier
0.44
0.32
0.28
0.28
Molecular Weigm
of
Stack Gas. Md
(Ib/Mole)
^22.
^.^

2/.9o
Md = 30 „ 2.

Multiplier
0.44
0.32
0.28
0.28
Molecular vveignt
of
Stack Gas. Md
(Ib/Mole)
Y.o?
^K*

V.S7
Md- ^jg T-7.11
*Oj Net Volume is O, actual reading minus CO, actual reading.




" CO Net Volume is CO actual reading minus O, actual reading.




' N, Net Volume is 100 minus CO actual reading.
                                                                                                                           8.7
     ICCMVIIIOMIMTAI.HIIVICUINC.
-------
                                            Pacific Environmental Services. Inc.




                                               Dry Molecular Weight Determination
Client/Proiect: W
f\3 Orsat No.
Operator:
Comments:
Site Location:
Run 2
Actual
1,1
2/Cr
— •
/00.0
Net
?-3
/2.2,
—
7£/
Run 3
Actual




Net




£>" ^
/? /*/<<<.

R^J+**~ o**

Average
Net
Volume
%?$
/2.3S
—
7jtf

Multiplier
0.44
0.32
0.28
0.28
&
Molecular weight
of
Stack Gas. Md
(Ib/Mole)
#^f
-£<$

v*
Md» 2^? . f 7
Run No.(s)


Gas
P
0,'
CO"
N,e

Run 1
Actual





Net





Run 2
Actual





Net





Run 3
Actual





Net




Average
Net
Volume
%
••i-^^^— ^— ••




Multiplier
0.44
0.32
0.28
0.28
Molecular weigm
of
Stack Gas. Md
(Ib/Mole)




Md =
Run No.(s)


Gas
•
CO,
o,'
CO"
N,c
Run 1
Actual

—


Net




Run 2
Actual




Net





Run 3
Actual





Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weiqnt
of
Stack Gas. Md
(Ib/Molel




Md*
*0, Net Volume is O, actual reading minus  CO, actual reading.




* CO Net Volume is CO actual reading minus O, actual reading.




c N, Net Volume is 100 minus CO actual reading.
     B INVIIIOIMMTM.IUMCU IMC.
-------
Client/Proiect:
Date/Time:
Sample Type:
Ambient Temp. 'F
                       _ _
                        /O
Pacific Environmental Services. Inc.
   Dry Molecular Weight Determination
                  Orsat No.           Q-
                  Operator:
                 Comments:
                 Site Location:
Run No.(s)

Gas
•
CO,
(f
/H

74. -o
Run 2
Actual
?.<<
2/2

/too

Net
t(t
ll.k

75,6
Run 3
Actual




Net




Average
Net
Volume
i^
//.*

?6.i

Multiplier
0.44
0.32
0.28
0.28
of
Stack Gas. Md
(Ib/Mole)




Md =
Run NO.IS)
0^

Gas
•
CO,
o,'
CO"
N:e

Run 1
Actual
/o.i.
2/,l

(fo.D

Net
/«2.
f/.O

7&.4

Run 2
Actual
M
2I.-L

/0°.0

Net
/o.y
/w

1&*

Run 3
Actual





Net




Average
Net
Volume
%
/O.^
/o.c(

fa*

Multiplier
0.44
0.32
0.28
0.28
of
Stack Gas. Md
(Ib/Mole)




Md =
Run No (s)

Gas
•
CO,
o,'
CO"
N,e
Run i
Actual
a. 1,
-U.O

»*+
Net
10. 1-
to,*

75.0

Run 2
Actual
/0.2-
*/.!-

(oO.O

Net
/0. i-
//,*

7$.%
Run 3
Actual





Net




Average
Net
Volume
/Air
/0.1

?f>1

Multiplier
0.44
0.32
0.28
0.28
Molecular Weiqnt
of
Stack Gas. Md
(Ib/Mole)
V??
3.V1

2.^01
Md" ?o.o7
'O] Net Volume is O, actual reading minus CO, actual reading.
8 CO Net Volume is CO actual reading minus O, actual reading.
c N, Net Volume w 100 minus CO actual reading.
                                                                                                                           (t.U
-------
                                             Pacific Environmental Services. Inc.
Client/Proiect:

Date/Time:

Sample Type:

Amoient Temo. 'F
                            Dry Molecular Weight Determination

                                          Orsat No.      	

                                          Operator:      	

                                          Comments:

                                         Site Location:
Run No.(s)
• ^

Gas
•
CO,
-------
                                            Pacific Environmental Services, Inc.
Client/Proiect:
Date/Time:
Sample Type:
Ambient Temo. JF
   //9/17
   /rJ*
        Dry Molecular Weight Determination
                      Orsat No.     	
                      Operator:     ___
                      Comments:
                     Site Location:
Run No.(s)

4W
1.20

22. /T-
Md= 3a/
-------
                APPENDIX B




ANALYTICAL DATA - PARTICIPATE MATTER/METALS
-------
          Appendix B.I




Analytical Data - Particulate Matter
-------
                   SAMPLE ANALYTICAL DATA FORM
Plant
Sample location _	
Relative humidity 	
Density of acetone (p.)
                     tt
                     -  T£T-L- £,/ry
                                            Run number T-
                    CUT>0L,A.  "B>nrfrHuuse   JX/LeT"
                                  0,78r£2~-
                                                            a/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
^
Liquid level marked
and/or container sealed
X
Acetone rinse container number
                                              w—l
 Acetone rinse volume
                     
Acettone blank residue concentration (Ca)
                                                        O.Q
 W
     ca vaw pa s
Date and time of wt      _
Date and time of wt 7/33/97
                                 /6>OO
                                 01 VQ
                                        Gross wt
                                        Gross wt
I HIS-?, 3
tins"?.?'
                                Average gross wt //fyjTT,
                                         Tare wt
                      Less acetone blank wt (W&)
     Weight of particulate in acetone rinse (m_)
                                 //
Filter(s) container number  ,  *{
Date and time of wt
Date and time of wt
mg/g
mg
mg
mg
mg
                                                        d,d
                                                             mg
                                                             mg
                                        Gross wt
                                        Gross wt
                                                     /79/, 6
                                                     /79 1, (
                            r   Average gross wt
                                         Tare wt
         Weight of particulate on filter(s) (mf)
          Weight of particulate in acetone rinse
                Total weight of particulate (n^)
                                                         ,
           mg
           mg
           mg
            Cf*-<—
                                                    mb.tf1
                                                    *?/37.
                                                            . »g
                                                            c«-«-
                                                            . »g
 Note;  In no case should a blank residue >0.01 mg/g or 0.001% of
 the weight of acetone used be subtracted from the  sample weight.

 Remarks
      Signature of analys^
      Signature of reviewer
                      PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                   SAMPLE ANALYTICAL DATA FORM
Plant
Sample location 	
Relative humidity 	
Density of acetone (p.)
                     O
                    -T£U.
c.rry
                                             Run number
                              BfrG-ttvuSG  3M L&J~~~
                                 0,
                                                             a/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
^
Liquid level marked
and/or container sealed
•-.
Acetone rinse container number
                                      &e**4j>\  U/-2—
Acetone rinse volume
                      
                                          STTO
 Acetone blank residue concentration (Ca)
 W
     ca Vaw
                                                        o.d
Date and time of wt
Date and time of wt

                                HoGl
                                010
                                        Gross wt /V£73/fV
                                        Gross wt
                                Average gross wt
                                         Tare wt
                      Less acetone blank wt (W_)
                                              tt
     Weight of particulate in acetone rinse (m_)
                                              a
                                                   /0a£V7.3
                                                         G<0
                                mg
                                mg
                                mg
                                mg
                                mg
                                mg
                                mg
Filter(s) container number */
Date and time of wt
                              "
                                                   / 0 /*?
                                /33s
 Date and time of wt   /?7
                                         Gross wt
                                         Gross wt
                                Average gross wt
                                         Tare wt
         Weight of particulate on filter (s) (m-)
          Weight of particulate in acetone rinse
                Total weight of particulate (m_)
                                                   S212, 8
                                                     6/6>.
                                mg
                                mg
                                mg
                                                    (ff-2>rO
                                                             mg
 Note;  In no case should a blank residue >0.01 mg/g or 0.001% of
 the weight of acetone used be subtracted from the sample weight.
 Remarks
      Signature of
      Signature of reviewer
                      PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                   SAMPLE ANALYTICAL DATA FORM
                   -  T^U-
Plant 	
Sample location
Relative humidity	
Density of acetone  (pa)
                                             Run number 3r
                            foifr-G-H-ttn£G
                                                             g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
X
Liquid level marked
and/or container sealed
*/ •
Acetone rinse container number 	
Acetone rinse volume  (V.,,.) 	
                       QlW  ««B*M^^»^"»"»l^"»^-M*"«
Acetbne blank residue concentration  (C&)

Wa s ca vaw Pa s  <  ''°  >
Date and time of  wt
Date and time of  wt
                                                               ml
                                                             mg/g
                                                        O.O mg
                                        Gross wt  /08I02'
                                        Gross wt
                                                              mg
                                                              mg
                                                              mg
                                                              mg
                                                              mg
                                                              mg
                                                             mg
                                 Average gross wt /0£~t03.
                                          Tare wt
                       Less acetone blank wt (W )
     Weight of particulate in acetone rinse (ma)
                             /'/
Filter(s) container number J£	_Z>^iJ2.?-3	
Date and time  of wt 11ll'fa 7    /6>30      Gross wt
Date and time  of wt ZJlfrfirTifa r^TtTtd (<" Gross wt
                                 Average gross wt
                                          Tare wt
         Weight  of particulate on filter (s) (mf)
          Weight of particulate in acetone rinse
                 Total weight of particulate (mn)
Note;   In no case should a blank residue >0.01 mg/g or 0.001% of
the weight of  acetone used be subtracted from the sample weight.
                                                                  CAV< .
                                                             ma
                                                         L2»g
Remarks
     Signature of anal;
     Signature of reviewer
                      PACIFIC ENVIRONMENTAL SERVICES. INC. -
-------
                   BLANK ANALYTICAL DATA FORM


Plant 	  W&-ViP>frC,* -  TtTU-
Sample location     c
Relative humidity 	.	
Liquid level narked and container sealed	k/-*-/
Density of acetone (pft)      •  0,7ft :T3- _ g/ml
Blank volume  (Va)  _ /•*£" _           ml
Date and time of wt 3-*3-*K7    -I4r*g~     Gross wtr7& %&£=!?   mg
Date and time of wt 3-*-*-»7    +M)      Gross wt    9fW> */   mg
                                  Average gross wt    ^fSyft .1   mg
                                           Tare wt    9^327,0  mg
                             Weight of blank (m^) _ /3,7  mg
 Note:   In no case should a blank residue greater  than 0.01 mg/g
 (or 0.001% of the blank weight) be subtracted  from the sample
 weight:
 Filters                     ¥" Filter number
 Date and time of wt 9/t97  /33>"' Gross wt _ &f3*<-f      mg
 Date and time of wt 9//7/97  70 /iT Gross wt _ £fAi*-f      rag
                             Average gross wt _ £/2, vc'mq
                                Difference wt          <
 Note;   Average difference must be less than ±5 mg or 2% of total
 sample weight whichever is greater.
 Remarks
      Signature of analy^
      Signature of reviewer
                                        ''w1..
                                        £:'•
                       PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                   BLANK ANALYTICAL DATA FORM
                   ~  T£U-
                    c.u?QLjr
Plant 	
Sample location  	
Relative humidity 	
Liquid level marked  and container sealed
Density of acetone (p  ) J	:	
Blank volume  (Vft) 	
Date and time  of wt
Date and time  of wt
                                          3>Jt-ET"
                                            ss wt
                                         cross wt
                                     age gross wt
                                          Tare wt
                              ight of blank (m K)
                                                             g/ml
                                                             _ ml
                                                             _ >*g
                                                             _ mg
                                                             	mg
                                                               mg
                                                              mg/g
Note;  In no case should a blank residue greater  than 0.01 mg/g
(or 0.001% of the blank weight) be subtracted from the sample
weight.
Filters
                             ''
Date and time of wt 9/W*?7
Date and time of wt 7//7/?7
                               Filter number
                                    Gross wt
                                    Gross wt
: ^-—- — ZTTTT
: 6/.f,7
: tilt 7
: 6(t,fr
: - Oj
mg
mg
mg
mg
mg
                            Average gross wt
                                     Tare wt
                               Difference wt
Note;  Average difference must be less than ±5 mg  or 2% of total
sample weight whichever is greater.
Remarks
     Signature of analyst   .^^.^^
                         ^""^^^
     Signature of reviewer
                      PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                   SAMPLE ANALYTICAL DATA  FORM
Plant
                                             Run number 0-
Sample location     CUPOLA
Relative humidity
Density of acetone  (pa)
                        »^^««
                                                             g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
^
Liquid level marked
and/or container sealed
/
Acetone rinse container number
Acetone rinse volume (V.
                        aw'
                                                               ml
Acetone blank residue concentration  (Ca)
                                      a
                                                   6.O
Wa = ca Vaw
              t = (  o   )  (
Date and time of wt 9-22-17
Date and time of wt f-
                                         Gross wt
                                         Gross wt /fa>//3.
                                Average  gross wt f/3
                                          Tare wt //3ffff,
                      Less acetone blank wt (W&)
     Weight of particulate in acetone rinse (m&)
Filter(s) container number      ^-^72-7 — /	
Date and time of wt
                                                        O> O
                     mg
                     mg
                     mg
                     mg
                     mg
                     mg
                     mg
                                f3>3£
 Date and time  of wt tight    10
Gross wt
Gross wt
                                 Average gross wt
                                          Tare wt
         Weight of particulate on filter (s) (mf)
          Weight of particulate in acetone rinse
                 Total weight of particulate (n^)
mg
mg
mg
mg
mg
mg
mg
Note;  In no case should a blank residue >0.01 mg/g or 0.001% of
the weight of  acetone used be subtracted from the sample weight.
 Remarks
     Signature  of analyst('"'
     Signature  of reviewer
                      PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                    SAMPLE ANALYTICAL DATA FORM
Plant.
                                              Run number  J-»i«3?-3-
Sample location 	
Relative humidity j	
Density of acetone  (p.)
                      ci
                    cu0f-/   'Bfy-f-tfauS-ls'
                                  0t~l$-£2-
                                                              a/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
"" .
Liquid level marked
and/or container sealed
"" '
Acetone rinse container number   &t,>\  fJo.   kf~ 6
Acetone rinse volume
                      
                                                                ml
Acetone blank residue concentration (C ]
                                                      O.d
 W
     ca Vaw "a
                                     (/
 Date and time of wt  9-
/.?
6,3
mg
mg
mg
mg
mg
mg
mg
 Note;  In no case should a blank residue >0.01 mg/g or 0.001% of
 the weight of acetone used be subtracted from the sample weight.

 Remarks
      Signature
      Signature of reviewer
                       PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                   SAMPLE ANALYTICAL DATA FORM
Plant
Sample location 	
Relative humidity    .
Density of acetone (p,)
                     cl
                                             Run number
                                                             g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
^ .
Liquid level marked
and/or container sealed
tx
Acetone rinse container number
                                                MA 7
Acetone rinse volume
                      
    /srv
Acetone blank residue concentration (C_)
                                       3
w.
     Ca vaw
                     mg/g
                     mg
Date and time of wt
Date and time of wt
                                         Gross wt
                                         Gross wt
                                Average  gross wt
                                          Tare wt
                       Less  acetone blank wt (W_)
                                               Cl
     Weight of particulate  in acetone rinse (m_)
                                               ct
 Filter (s) container number  	£
 Date and time of wt 9//6/97
                   _ mg
                   L. mg
                   _ »9
                   	 mg
                0,0  mg
                y» 0.01 mg/g or 0.001%  of
the weight of  acetone used be subtracted from the sample weight.
 Remarks
     Signature  of anal]
     Signature  of reviewer
                      PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                   BIANK ANALYTICAL DATA FORM
Plant 	
Sample location     c,uf>dt~*-   Bft~G-rtvu££
Relative humidity	
Liquid level marked and container sealed
Density of acetone (p_) '
                      **        ._
Blank volume (Vft)  	<_£	
Date and time of wt 9-vt3'Ji7	IbOQ    Gross wt /03S-(e>/, I   mg
Date and time of wt 9->3.-^7	0^0v   Gross wt /0£fi£fl. 3   mg
                                  Average gross wt /03>Jr&Q» 7   mg
                                           Tare wt  10 3 £ S1, ?-  mg
                             Weight of blank (Ja-jj) _	/«£" mg

                         mab       (        )
                   c& = VP! = T5o   >  (.7^>s —*	mg/g
Note;   In no case should a blank residue greater than  0.01 mg/g
 (or 0.001% of the blank weight) be subtracted from the sample
weight.
Filters                    3  Filter number
Date and time of wt 9//6/97  f^^^T' Gross wt
                                                         _;	mg
Date and time of wt 
-------
                   BLANK ANALYTICAL DATA FORM
Plant 	
      	1	
Sample location     c.u.P0t-rt-     &>to-6-ttouj(=-
Relative humidity
Liquid level marked and
Density of acetone (p)
a
Blank volume (V )
Date and time of wt 9-3
Date and time of wt  *J ma
7^t/SC,D
336, /
33 t/, -7
l,<4
mg
mg
mg
mg
mg
                             Average gross wt
                                      Tare wt
                                Difference wt
 Note;   Average difference must be less than ±5 mg or 2% of total
 sample weight whichever is greater.
 Remarks
      Signature of analy
      Signature of reviewer
                       PACIFIC ENVIRONMENTAL SERVICES. INC. •
-------
                                                METHOD S
                                               FINAL WEIGHT
Project Numbers    Slt'4.OO<-t
                                                    Item Weighed s
                                                                -  ffcj£TU*J£
Date
R.H. (%)
Temp. (°F)
                  "70
                                         TO
Std. Wt.
                             *OJt&
Analyst
                             •   r\
ID Number
Field Sample
   Number
                                1st
2nd
3rd
4th
5th
 Final
Wt. (g)
  Tare
Wt. (g)
Difference
   (mg)
            X-mtt-t
                                                         ///7S7.&
                   - 2.
                                                        /Of 720. 3
                                     /OJF/W.6
                                                        /Of: to*,
                                                                                                   . 7
                             101307,7
 uJ-1
                                                                                  -O./
             tg~t>. ooo . e)
-------
                                                   METHOD 5
                                                 TARE WEIGHT
Project Humbert  SV/«/.
                                                      Item Weighed s    2.S~0  r*\L
Date
                        /sroo
                       Qf/flQI
R.H.  (%)
                                          to
                                          10
                                                            70.
Std. Wt.
Analyst
ID Number
               Field Sample
                  Nunber
1st
2nd
3rd
4th
5th
 Final
Wt.  (9)
  Tare
Wt.  (q)
Difference
   (ng)
  kJ-f
                                101 6>S0.3
              /Cff&XO.b
              } 61 (,30,1
  ixf-Z.
                                /WSV7.I
                            . 1
  U/-3
                                             f
                                                9&J7.J.
                                        3017.S-
            o ~
  IA/-1
  IA/-8
  lAf-1
                                             . 7
              W&J.7
  kt-IO
                                               fo&ff.t

                              /Of J0*f. f
                                        /0&07.7
              (O&Of. S
                                                   6?
                                       fOcrtto. 0
                                                 SO ooo • 6
                                               f'ftW.O
              MA
                                IOOOOO. 0
      too ooo, o
      too ooo.o
                       f 00000.0
                   *&
                                             0
                                                               "&
                                                                ?l
                               ISVOOO, O
                                        ISO OOO. 0
               tsooot),0
               ISQooo.o
                    V-
                               (56 001,1
                                        Ittoot.Z
               ISO 003
-------
                                                METHOD 5
                                              FINAL HEIGHT
Project Numbers
                     . 00 «/  -
                                        Item Weighed i  3 * i  V"  Pi'/^ftcf
Date
          /33«SicWtv-
Temp. (°F)
                    70
                                                        ~76
Std. Wt.
Analyst
                                        r
ID Number
  Field Sample
     Number
                                1st
                   2nd
4th
5th
 Final
Wt. (g)
  Tare
Wt. (g)
Difference
   (mg)
                                                                                  WA7
                     -2.
  h/3-3
                                                                                     /. 3.
 A/3-V
~*g
                             536.
                          536.0
                                                                       33
     -/
                          1791.0 .  /79/,
            T-
                                                   (oil
 A/V-3
                                  333%
                                                              ion
                                                                 , 9
                                      J730.S"
             T-W21- FB
                                                   tots'
                                     6/9.7
                                                                       ttt.B
                                                                                               -0.1
                 S~CfO
                          4/99.9
                             I &O 0,O
                             $340. 0
                             £220.0
                f-ooa
                                  3 ooa. I
                300* s*
                                  3ooo.
                       *
-------
            Wife

>-:' '
-------
09/15/97 12:03   ©513 398 3342
          FES CINClMMAl'i  •»*-» UUKOAA
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     NO.:
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     DATE/TIME NAME  MASS
          AVERAGE
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                           NO.:
I.D. NO.:.
               DATE/TIME  NAME  MASS
                    AVERAGE
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     NO.: jo/to*  I.D. NO.:	

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              NO.:
                                      I.D. NO.:,

                                       ME   MASS
    #3.

    #4.
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                    AVERAGE
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           &&  fr  _
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                           . NO.:.
                        NAME  MASg
          AVERAGE
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                   AVERAGE
                  TARE MASS
-------
09/15/97 12:02   1*513 398 3342
                      FES CINCINNATI -»•»•» DURHAM
                   IflOUS/UUO
                      TARED FILTER LOG
    NO,;
           I.D. NO.:
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                          DATE/TIME  NAME  MASS
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         AVERAGE
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                               AVERAGE
                              TARFMASS
-------
09/15/97    12:02     ©513 398 3342
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DATE/TIME NAME MASS
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-------
09/15/97   12:02     ©513 398 3342
PES CINCINNATI    •»•»•»
•
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09/15/97  12:02  ©513 398 3342
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                              AVERAGE
                             TARE MASS  :
-------
                            FILTER WEIGHT LOG SIZE
                                                                                      T
                                                                                      ¥
Filter
 No.
/03d
Weight
  g.
Date/Time
m/d/24hr
           /30/
Inlls
Weight
  9-
                            OJM0
Date/Time
m/d/24hr
                                       &**
                                       QQ'l-
Intls

                                            AM
                                             640
                              6*0
Weight
  g.
Date/Time
m/d/24hr
Intls
Average
                                                o.fea&o
                                                                     0)
                                                                                             (0
                                                                                          • I
-------
 Filter
 No.
/o/r
 sot*
 ton
 lot?
                            FILTER WEIGHT LOG SIZE   II0
                                                                                       f
                                                                                       I
 Weight
   g.
       0*360
        Lilt)
01, lib
04111
       to .(0200
       o.brtl
        Date/Time
        m/d/24hr
Intls
                         **
                 ton
                 9*0
Weight
  g.
                      O.b
                      o.u>\\s
Date/Time
m/d/24hr
                              VIW
Intls
                                         o
Weight
  g.
Date/Time
m/d/24hr
Intls
                                                             640
Average
                                                                     0)
                                                                                             (0
-------
 Filter
  No.
100 f
too
loo
/oor
                              FILTER WEIGHT LOG SIZE
 tD/o
 till
Weight
  9
         .0 |oO
Date/Time
m/d/24hr
                   /f ^V
Intis
Weight
  g-
                      o .
Date/Time
m/d/24hr
                                          0\\1*
                                            \\\
                                          010%
                                  o 107
Intis
                                         A0
Weight
  g.
Date/Time
m/d/24hr
Intis
Average
                                                                     .6 12.6,
                                                                    o.
                                                                        0)
                                                                                                  10
                                                                                                . I
-------
                             FILTER WEIGHT LOG SIZE
                                                                                        T
 Filter
 No.
?•/**-
Weight
  9-
        .37 JO
       a. .179* 3/r/fr
Date/Time
m/d/24hr
Intls
Weight
              0.3353
                             0.
Date/Time
m/d/24hr
                                         /rVc-
                                         /rot
                                     9/7
Intls
                                              ft 4V)
Weight
Date/Time
m/d/24hr
Intls
Average
                                                                   O-3995
                                                                          Q.
                                                                       0)
                                                                                                (0
                                                                                                in
-------
                             FILTER WEIGHT LOG  SIZE
Filler
 No.
Weight
  g
      6.
Date/Time
m/d/24hr
InUs
Weight
  9-
                             t.Zll-O
                               3* O
Date/Time
m/d/24hr
                                         AT3
                                 /
-------
     Appendix B.2




Analytical Data - Metals
-------
                            CASE NARRATIVE
        Analysis of Samples for the Presence of Trace Metals
                           Method 29 April 1996 Rev.
             Client:
Pacific Environmental Services
             TLI Project Number:      43231

             Date:                     November 6,1997
                        This report should only be reproduced in full.
                    Any reproduction of this report requires permission from
                              Triangle Laboratories, Inc.
Rev. 25-Sep-96
                                            Triangle Laboratories, Inc.
                                 801 Cap/to/a Drive             P.O. Box 13485
                                 Durham, NC 27713-4411         Research Triangle Park, NC 27709-3485
                                 919-544-5729                 Fax #919-544-5491
-------
Triangle Laboratories, Inc.                                         November 6,1997
Case Narrative                                                 TLI Project #: 43231

Overview

Five train samples, three blank train samples and a DI water sample were analyzed for
silver (Ag), arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co),
chromium (Cr), manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), antimony (Sb),
selenium (Se), thallium (Tl), zinc (Zn), and mercury (Hg). For all analyses, the samples
and associated QC samples were prepared and analyzed following the guidelines of
Method 29 April 1996 Rev. Results reported relate only to the items tested.

OC Remarks

The release of this set of data by Triangle Laboratories, Inc. was authorized by the Quality
Control Chemist who has reviewed each sample data package individually following a
series of inspections/reviews. When applicable, general deviations from acceptable QC
requirements are identified below and comments are made on the effects of these
deviations upon the validity and reliability of the results. Specific QC issues associated
with this particular project are:

Sample Receipt:

Eight train samples (without the filters) were received at 5 °C on September 12,1997 in good
condition under project^ 43231. (The acetone rinse samples were temporarily put on hold and
then reentered into the system on September 23,1997) The components for the reagent blanks
were not received with the samples. The containers for inlet (FHAce and FHAR) and outlet
(FHAce and FHAR) blank were not marked "BLK" like the remaining blank containers.

One reagent blank sample (except the KMnO4 sample) was received without coolant on
September 15,1997 in good condition under project# 43243. The KMnO4 sample arrived
broken and the sample had leaked out, therefore, an analysis could not be performed for this
sample. The sample also arrived without a client chain-of-custody. The Acetone rinse for the
reagent blank was cancelled per the client's request.

Eight filter and acetone rinse samples and one reagent blank filter were received without
coolant on September 23,1997 under project^ 43350. All components that were received
on September 12,15, and 23,1997 were processed under project 43231. The
components for the inlet and outlet reagent blanks were combined  on order to make one
complete reagent blank train sample.  Only eight samples were reported in this data
package.

Sample Preparation:

Laboratory documentation of the sample preparation is included in the data package.
-------
Triangle Laboratories, Inc.                                        November 6,1997
Case Narrative                                               TLIProject*: 43231
Instrumentation:

Silver (Ag), arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co),
chromium (Cr), manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), antimony (Sb),
selenium (Se), and zinc (Zn) concentrations were determined by Inductively Coupled
Plasma Emission Spectroscopy (ICP). Thallium (Tl) concentrations for the  front half
samples I-M29-1 FH, I-M29-FIELD BLANK FH, O-M29-1 FH, O-M29-3 FH, I-M29-3
FH, and I-M29-2 FH were determined by Inductively Coupled Plasma Emission
Spectroscopy (ICP).

Thallium (Tl) concentrations for the back half samples and front half samples (except
samples I-M29-1 FH, I-M29-FIELD BLANK FH, O-M29-1 FH, O-M29-3 FH, I-M29-3
FH, and I-M29-2 FH) concentrations were analyzed by Graphite Furnace Atomic
Absorption (GFAA). Due to instrument failure, all samples could not be analyzed by
GFAA.

Mercury (Hg) concentrations were determined by Cold Vapor Atomic Absorption
(CVAA).

The linear range for the instrument TJA 61E Trace Analyzer was based on four standards
and a blank, which established a correlation coefficient value greater than or equal to
0.995.  A calibration curve, based on a blank and one standard, is established for each
analytical run, followed by a check high standard and an initial calibration verification
(ICV). The check high standard does not deviate from the calibration curve by more than
5%.  In addition, continuing calibration verifications (CCVs) are performed throughout
the analytical run.

A Reporting Detection Limit (RDL) is used instead of an Instrument Detection Limit
(IDL). The spectrometer and atomic absorption instruments can achieve low detection
limits between 0.2-8 ppb levels for many analytes. Triangle Labs is using RDL values of
1-10 times the DDL as detection limits for reporting purposes.

Data Review:

All analytes found in the method blank (MB) prepared on September 25-26,1997 are
detected at a level equal to or less than the respective Reporting Detection Limits (RDLs)
except for Zn. All analytes found in the method blank (MB) prepared on October 02-03,
1997 are detected at a level equal to or less than the respective Reporting Detection
Limits (RDLs) except for Mn. The following guidelines may be used to assess analyte
concentrations relative to the method blank: 1. Analyte quantitations should be considered
valid if the level of blank contamination is less than five percent of the level detected in the
field sample, 2. Analyte quantitations should be considered estimated if the
-------
Triangle Laboratories, Inc.                                         November 6,1997
Case Narrative                                                TLI Project #: 43231
analyte level in the sample is five to twenty times the level of the analyte in the blank, or 3.
Analytes whose level in a sample is the same as or less than five times the level detected in
the associated blank should be considered present likely due to laboratory contamination
and not native to the sample.  Please note that the concentrations for samples prepared on
September 25-26,1997 should be considered biased high for Zn. Also note that the
concentrations for samples prepared on October 02-03,1997 should e considered biased
high for Mn.

The client Ids did not match the Ids on the sample labels.  The sample labels were used to
identify the samples.

A sampling date was not supplied by the client for the reagent blank received on
September 15,1997, therefore, the sampling to analysis holding times cannot be
determined.  The sample was analyzed within 23 days of sample receipt at Triangle
Laboratories. Due to laboratory problems, samples I-M29-FHAR,BLK-5% 10% BH and
O-M29-FHAR,BLK-5% 10% BH were not analyzed within the 28 day sampling to
analysis holding tune for Hg.  All samples were analyzed within the six month sampling to
analysis holding time for all other requested analytes.

Due to a confusion in the laboratory, the sample preparation procedure deviated from the
method. The filter and acetone rinse samples (except I/O REAGENT BLANK FH) were
not prepared simultaneously with the HNO3 rinse samples on September 25-26,1997.
The filter and acetone rinse samples were prepared on October 02-03,1997. The samples
were analyzed separately and the concentrations from each analysis were added together
hi order to obtain a composited concentration for the front half samples. Only the
elements with concentrations greater than the RDL were added together. If one
concentration was below the RDL and one concentration was above the RDL, the
concentration above the RDL was used in the calculations. If both concentration for each
analysis from both preps were below the RDL, the concentration from the first analysis
was used in the calculations. The results  for the QC samples were not combined,
however, the individual results for the QC samples were included in the data package.

A duplicate analysis is  not reported for elements analyzed by GFAA. The GFAA
instrument analyzes two separate aliquots of the sample and averages the values for a final
result.  These two analyses agree within a RPD of 20% or a second run is done for that
sample. The ICP instrument analyzes one continuous aliquot three times and averages the
values for a final result. The ICP does not take two separate aliquots, therefore a DA is
performed.
-------
Triangle Laboratories, Inc.                                        November 6,1997
Case Narrative                                               TLI Project*: 43231
The post-digestion spike (PDS) for Tl for the sample I-M29-1 FH (prepared on October
02-03,1997) demonstrated a percent recovery outside the QC criteria of 85-125 percent,
which indicates significant matrix effects specific to this analyte in the native sample
matrix. The Method of Standard Additions (MSA) was performed on all of the samples
prepared on October 02-03-1997.  The MSA results are reported if the correlation
coefficient value is at least 0.995. Only samples I-M29-FHAR.BLK BH (prepared on
September 25-26,1997), O-M29-2 FH and O-M29-FEELD BLANK FH had passing
correlation coefficients. The remaining samples that were analyzed by GFAA
demonstrated significant matrix interferences during analysis and the results reported are
considered underestimated.

Due to instrument failure, all of the samples could not be analyzed by MSA for a second
time.  The initial results for all of the samples (except for the samples that had passing
MSAs and for samples I-M29-1  FH, I-M29-2 FH, and I-M29-3 FH) were taken from the
initial GFAA analysis. The samples I-M29-1 FH, I-M29-2 FH, and I-M29-3 FH were
reanalyzed by ICP and the Tl concentrations were taken from the reanalysis data.

The post-digestion spike (PDS) for P and Tl for samples I-M29-1 FH and I-M29-1 BH
demonstrated percent recoveries outside the QC criteria, which may indicate significant
matrix effects specific to these analytes in the native sample matrix.  Please note that these
samples should be considered biased low for these elements due to matrix interferences.

The post-digestion spike (PDS) for Ag for the sample I-M29-2 FH demonstrated a
percent recovery slightly outside the QC criteria, but does not indicate any significant
matrix effects specific to this analyte in the native sample matrix.

The pre-digestion spike (MS) and the pre-digestion spike duplicate (MSD) for Hg for the
sample I-M29-3-5% 10% BH demonstrated percent recoveries outside the QC criteria,
which may indicate significant matrix effects specific to this analyte in the native sample
matrix. Please note that this sample should be considered biased low for Hg due to matrix
interferences.

The recoveries for the post-digestion spike (PDS) are not reported for Mn, Pb, and Zn for
sample I-M29-1 FH and I-M29-2 FH. The spike concentrations added were insignificant
in comparison to the levels of these analytes present in the native sample.

The recoveries for the pre-digestion spike (MS) and the pre-digestion spike duplicate
(MSD) are not reported for Hg for samples I-M29-2-5% 10% BH and O-M29-l-5% 10%
BH.  The spike concentrations added were insignificant in comparison to the levels of this
analyte present in the native sample.
-------
Triangle Laboratories, Inc.                                         November 6,1997
Case Narrative                                                TLI Project #: 43231
QC requirements:

The duplicate analyses for analytes analyzed by GFAA cannot be considered valid
qualifiers if the concentrations of the analytes in the original and/or duplicate sample are
not at least five times the respective RDL. The RPDs for these analyses are indicated by
"
-------
Triangle Laboratories, Inc.                                         November 6,1997
Case Narrative                                                TLI Project #: 43231
By our interpretation, the analytical data in this project are valid based on the guidelines of
Method 29 April 1996 Rev. Any specific QC concerns or problems have been discussed in
the QC REMARKS section with emphasis on their effect on the data. Should Pacific
Environmental Services have any questions or comments regarding this data package,
please feel free to contact Project Scientist, Amy J. Boehm, at (919) 544-5729 ext.268.

For Triangle Laboratories, Inc.,

Report Preparation                             Quality Control
Linda F.Jones                                 -grfto*/aH •  & * II
Report Preparation Chemist                     Report Preparation Chemist
The total number of pages in this data package is:
-------
                     TRIANGLE LABORATORIES, INC.

                 LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American Association for Laboratory Accreditation.  Accredidation  pending.  Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(lncluding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department  of  Environmental  Management.  Expires December 31,
1997. Laboratory I.D. # 40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona,  Department of Health  Services.   Expires  May  26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department  of Pollution Control and Ecology.  Expires February 18,
1998. Pulp/paper, soil, water, and  Hazardous Waste for Dioxin/Furan; AOX/TOX.

State of California, Department of Health Services.  Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles.  Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut, Department of Health Services.  Recertification pending. Registration
# PH-0117.  Dioxin in drinking water.

Delaware Health and Social Services.  Expires  December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.

Florida Department of Health and Rehabilitative Services.  Expires June  30, 1998. Dioxin in
DW. Drinking Water ID HRS# 87424.  Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC)  and Volatiles (GC/MS)  in  Environmental Samples.   Environmental water  ID  HRS#
E87411.

Hawaii Department of Health. Expires March 1,  1998. Dioxin in drinking  water. "Accepted"
status for regulatory purposes .
Revised 10/28/97 RM
Printed 10/29/97                                  Triangle Laboratories, Inc.
Prmted 10/29/97                        ^ Capitola Drive            P.O. Box 13485
                                  Durham, NC 27713-4411        Research Triangle Park, NC 27709-3485
                                  919-544-5729                Fax #919-544-5491
-------
Idaho Department of Health and Welfare.  Expires November 30, 1997. Dioxin in drinking
water.

State of Kansas, Department of Health  and Environment.  Expires January  31,  1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste - E-1209.

Commonwealth  of Kentucky,  Department for Environmental  Protection.    Expires
December 31,1997. ID#90060. Dioxin in drinking water.

Maryland Department of Health and Mental Hygiene.   Expires  September 30,  1998.
Certification #235. Drinking water by Method 1613A.

State of Michigan, Department of Public Health.  Expires June  3, 1998. Drinking water by
Method  1613.

Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.

Montana Department of Health and Environmental Services.  Expires December 31, 1997.
 Dioxin in drinking water.

State of New Jersey, Department of Environmental Protection  and Energy.  Extended by
state. Temporary certificate until December 31,1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.

State of New Mexico, Environment Department.  Recertification pending. Dioxin in drinking
water.

New York State Department of Health.   Expires April  1, 1998.  ID  #11026. Environmental  :
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.

State of North Carolina, Department of Environment Health  and Natural  Resources
Expires August 31, 1999. Certificate # 37751.  Dioxin in drinking water.

State of North  Carolina, Department of Environment, Health,  and Natural Resources,
Division of Environmental Management.  Expires December 31, 1997.  Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.

North Dakota  State Department of Health  and Consolidated Laboratories.   Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993.  Dioxin in drinking water.    —
Revised 10/26/97 RM

Printed 10/29/97
-------
Oklahoma  Department of Environmental  Quality.   Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.

State of South Carolina, Department of Health and Environmental Control. Expires April 1,
1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.

State of Tennessee. Department of Environment and Conservation.  Expires  February 5,
1999. ID #02992.  Method 1613 Drinking water only.

U.S. Department of Agriculture Soil Permit.  Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.

U.S. Army Corps of Engineers.  Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USACE North Pacific Division Laboratory.

U.S. EPA Region V. Expires  November 14,1999.  Dioxin in drinking water.

U.S. EPA Region VIII, for the State of Wyoming.  Expires November 13,  1997. Dioxin in
drinking water.

State of Utah, Department of Health.  Expires December 31, 1997. Certificate Number E-166.
Certification  for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method  8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.

Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30,1998. ID # 00341. Dioxin in drinking water.

State  of Washington,  Department of Ecology.   Expires  September 11,  1998.  Lab
Accreditation Number  C067.  Scope  of  Accreditation  applies  to  water analyses  for
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.

State of Washington, Department of Health.  Expires April 30, 1998. Dioxin in drinking water.
 Lab I.D. 129

State of West Virginia, Department of Health. Expires December 31, 1997. Certificate  No.
9923(C). Dioxin in drinking water.
Revised 10/28/97 RM

Printed 10/29/97
                                                                              10
-------
State of Wisconsin,  Department  of Natural  Resources.  Expires August  31,  1998.
Laboratory  ID Number 999869530. Certification for the  following categories of Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement Agency (DEA).   Expires November  30, 1997.  Registration  number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources.  Expires October 31, 1998.  Registration  number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.

Food &  Drug  Administration (FDA)  Registration.  Expires June  1998.  ID  #"s  001500
1053481. Annual registration of drug establishment Annual registration of drug establishment

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration.  Expires May 30, 1999.
ID # 34D0705123.    Department of  Health  & Human  Services,  Health  Care  Financing
Administration.

U.S. EPA Large  Quantity  Hazardous Waste Generator.    No  expiration  date.   EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina Radioactive Materials License.  Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.

North Carolina General License for Radiation Protection.  No. expiration date. License No.
032-875-OG.  The general license applies only to radioactive material contained in  devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 10/28/97 RM

Printed 10/29/97
                                                                           11
-------
                                ABBREVIATIONS
BHssBackHaif
CCB — Continuing Calibration Blank
CCV ss Continuing Calibration Verification
CHECKHS = Check H5ga Standard
D = OUP = Analytical Duplicate (Prepared Duplicate)
DA = Duplicate Analysis
FH=B Front Half
FV = Enal Digestate Volume
ICB ss Imfjgl Calibranon Blank
ICV — Tpif^ai Calibranon Verification
ICS AB = Interxerencs Check Solution (Solution AB)
       I = Tnirial
       Soluiioa AB contains common interfbraas in addition to the anaiyte of interest.
 IDL ss Instrurrent Detecdoa ^rrgt
 L « Serial Dilution
 LCS = Laboratory Control Spike Sample
 MB = Method Blank
 MFV a Mercury Preparation Volume
 MS ss Pre-digestion Spike
 MSD = Pre-digestion Spike Duplicate
 N/A- Not Applicable "
 N/Av = Not Avaflabk
 N/V=s Not Valid
 PDS =s Post-digestion Spike
 %REC - Percent Recovery
 HDL = Reporting Detection TJrrrit
 RPD = Relative Percent DiSerence
 T = Analytical Triplicate (Prepared Triplicate; for Hg analysis by Method 7471 only)
 TV SB Total Sample Volume
 < s Aoalyte concentration in the sample is less man tfae respective RDL
                                                                               12
-------
                  STANDARD CONCENTRATIONS
                for the TJA 61E TRACE ANALYZER
Analyte
' 'Ag '
As
s- - All -
B
* ;: Ba ':
Be
< : Ca
Cd
J-" V--> (Jgx
Co
i- ;^.€r-
Cu
r.w*
K
E.-sai;.
Mg
i- ': =lMtt
Mo
fe;&Na
Ni
r --F
Pb
• • ?:Sfc:
Se
1 --Sn< ^
Sr
r^vTi ••:••
Tl
^v..:.:=i
Zn
Units
ppb-
ppb
^ppfc."
ppb
ppb '-
ppb
: ppb
ppb
" ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
' PPb
ppb
ppb
ppb
• ppfr
PPb
I ppb
PPb
?;ppb
ppb
HighStd
-'10Qfl?H
1000
-':, IQQOi'^
1000
O^10Q0-vS
L 1000
;. '1000^
1000
: -lOOKv"
1000
1000
1000
1000;' »
10000
1000^
1000
lootr-
1000
100QOW
1000
1000) x
1000
lOOO'V*
1000
•:•: -viewer- -,
1000
- 100044
1000
' IQOO^ft'
1000
ICV/CCV
:--v500- --
500
V^SOfc o>
500
^^:500-^-
500
.- 2 & 500!- ;^~-~
500
K>: 500
500
. " 500
500
500
5000
— 500
500
, 500
500
< n ^5000
500
- ; 500
500
- 500
500
500
500
t-;^'-500- :
500
>>x 500: - >
500
ICSAB
; 500
500
500000-
500
500
500
500000
500
x 500
500
500 .
500
200000
19000
500- -^
500000
500
500
5000
500
500
500
500 >
500
500 ;
650
500 ^;
500
. - SOGfe^r
500
RDL
- •; t
5
:^;5a •
7
A- \1 '
I
60
1
'- 3- -
1
•• - 2
2
.40
220
-,:1 ?
30
%,-•
2
300
3
V 30
2
^••'4-
3
- ft •
1
avfr
5
m^-:-
12
Wavelength
;< 3280
1890
P-C , 308r.?'T':.
2496
:^ ^493^-'^-^
3130
-" 13179^:.:'.:-
2265
V 4186
2286
«--':''267T
3247
;fe:^:2714- --.:
7664
Vi 6706
2790
s:- •^•057fr. -••
2020
3302
2316
2149
2203
2068
1960
1899
4215
kV.:-:-3349- -.•>
1908
B^-^292^-" -k
2062
Note: Use this reference page to review the raw data from the TJA 6IE Trace Analyzer.

This page includes the standard concentrations for the check high standard, initial calibration
verification (ICV), continuing calibration verification (CCV), and the interference check solution
(ICSAB). In addition the reporting detection limit (RDL) and wavelength are reported for each
analyte.
                                                      Revision Date: 15-Jul-96
                                                                      13
-------
             CALCULATIONS FOR AIR SAMPLES
      RESULT in ^g (Front Half) = fie/L * FV (mU * DF
                               1000 mL/L

     % RESULT in jig (Back Half & Impingers) = ug/L * TV (mD * FV f iriD * DF
                                            mL used * 1000 roL/L

            FV = final volume in mL
            TV = total volume in mL
            DF = Dilution Factor

The RESULTS for combined Front Half & Back Half samples use the same calculation as the
Back Half & impinger samples.

RESULTS FOR MERCURY (Hs):

      RESULT in jig (Front Half) = ng/L * (mL FV/mL aliquot) * MPV * DF

      RESULT in |ig (Back Half & Impingers) = tig/L * (mL TV/mL aliquot) * MPV * DF

             MPV = mercury preparation volume = 0.1 L

%REC (Percent Recovery) for MS/MSP He spikes:

      %REC = spike sample results - original sample results *  100
                   true spike sample results

NOTE: Original sample results less than the RDL are not used in emulations.

%REC (Percent Recovery) for PDS;

      %REC = Spike sample u.g/L cone. - original sample u.g/L cone. * 100
                         spike cone. (u,g/L)

%REC (Percent Recovery) for LCS/LCSD;

      %REC = Spike sample u.g/L cone. * 100
                   spike cone. Qig/L)
             RPD =  I  Result 2 - Result 1  I   * 1QQ
                    (Result 2 + Result l)/2                         Rev. 2-Oct-96
                                                                  14
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-FHAR.FELD BLANK FH
183-3-1B.184-23-4ABFH
Seotember 12.15.& 23. 1997
Sept. 25-26 & Oct. 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
' s Ahalvte
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















- '&onc, -,
s fttfLr
72.316
32.624
503.025
-51.180
1717.172
35.480
329.116
343.918
190.203
1251.931
5973.582
53.660
44.688
-6.404
1661.507
















- -rot
TbtelVot "
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















% mL^
-' Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















* / fflL - %
RnalVd.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















; Dilute
Factor %
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















, Tofaiug, <
; " Result ^
7.23
3.26
50.3
< 0.100
172
3.55
32.9
34.4
19.0
125
597
5.37
4.47
< 0.500
166
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at  11:03 AM
-------
Client:       Pacific Environmental Services
Project Number:         43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Preoared:
Date Analyzed:
Matrix:
I-M29-FHAR.BLKBH
183-3-1BCBH
Seotember 12. 1997
Seotember 25-26. 1997
October 07-08. 1997
Air

- *. '- Amlvb
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















' ^tbcfc -
, ' {jUi&V *
4.852
-5.449
3.570
0.154
40.727
-6.784
18.909
12.066
10.734
69.813
189.199
5.944
10.084
4.900
168.337
















- --cd.- -
- TotalVol.
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
















;: jTi.^"
, ^t^ed
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
















nC" -N
RnaSVoL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















•• DiftitiQiV
, Fsffiof'
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















' t&iijgf :;
* Restii o
0.485
< 0.500
0.357
< 0.100
4.07
< 0.100
1.89
1.21
1.07
6.98
18.9
0.594
1.01
0.490
16.8
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at   03:46 PM
                                                                              1r>
                                                                              o
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1-FH
183-3-2B.184-23-1AB FH
September 12.15.& 23. 1997
Sept. 25-26 & Oct. 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
- - , '•'«- ^
- Aaalvte ^
Ad
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















-- Concv N ;
VflWiy
139.780
1920.371
14490.889
29.813
14101.715
341.530
12730.326
850754.593
3173.256
18547.696
813675.023
8750.900
718.327
728.174
3929615
















' l "jfL^: *
. Total Vo£
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















; mL s ^
t. •* **"* + *•*• %
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















%% ^ITTL ^
Final Vd/
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















\ " DJlutiofi ,
: Factor l :
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















^ Totalug \
x Result' x :
14.0
192
1450
2.98
1410
34.2
1270
85100
317
1850
81400
875
71.8
72.8
393000
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at  11:03 AM
-------
Client:       Pacific Environmental Services
Project Number: 	43231	
 Sample Report
Client Sample ID:
TLI Samole ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1BH
183-3-2C BH
Sentember 12. 1997
Seotember 25-26. 1997
October 07-08. 1997
Air
: , ft ' i'*\- " ^
' ? 'Aaiiivte-^
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















^fC&rfc^
/VftiaTLy ~
1.084
-2.845
a441
0.143
3.120
-4.216
18.734
9.917
5.882
110.721
24.725
5.600
15.145
-0.500
151.166
















^;M, ,x?
^To&iVoL
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
















^ •vJtif '
1 ^Cused
310
310
310
310
310
310
310
310
310
310
310
310
310
310
310
















* V*4; s*
1 Riteivai
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















''«3s?£
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















'$W8& KJ
' ^>RMift ^!
0.143
< 0.661
0.455
< 0.132
0.413
< 0.132
2.48
1.31
0.778
14.6
3.27
0.741
2.00
< 0265
20.0
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at  03:46 PM
                                                                             13
-------
Client:       Pacific Environmental Services
Project Number;        43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1BHL
183-3-2C BH L
September 12. 1997
Seotember 25-26, 1997
October 07-08. 1997
Air
^Mv&V^*J
#"*«8i&'*:
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















^{CitfiW
0.155
-0.489
0.685
0.219
0.423
-1.161
4.711
2.062
1.933
30.067
4.713
1.112
3.517
N/A
32.230










,





;T^fci> £
^;T
100
100
100
100
100
100
100
100
100
100
100
100
100
N/A
100

















5
5
5
5
5
5
5
5
5
5
5
5
5
N/A
5
















^&p=us^ *y
.. -X l*v < l»^X- "• A
\-*vResuft-; s-¥
< 0.661
< 3.31
< 1.32
< 0.661
< 0.661
< 0.661
3.12
1.36
< 1.98
19.9
3.12
< 2.65
2.33
N/A
21.3
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at  03:46 PM
                                                                              19
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2-FH
183-3-3B.1 84-23-2 AB FH
September 12.15.& 23. 1997
Scot. 25-26 & Oct. 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
*• •. -x •
< •. \ "* v |
Anaivte- %:
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















; ,Oonc/- ';
{uoW
553.287
2493.252
28739.289
153.223
37924.683
434.914
24508.565
2095904.471
4497.640
27390.498
2001336.413
14014.141
1292.630
1679.875
11191035
















ml. -- ,v
Total Vol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A












•



'- .."fnL,- t?l
* Used :
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















-"«*.-
JFihatva
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















;\OMioa
"' Faetorv
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Tolal ug - s ^
s % Ftesuft ^ ^ -
55.3
249
2870
15.3
3790
43.5
2450
209600
450
2740
200100
1400
129
168
1119100
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at  11:03 AM
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2 BH
183-3-3C BH
September 12. 1997
September 25-26. 1997
October 07-08. 1997
Air
iSaalv^
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















f"}£&;
1.419
-4.446
15.256
0.105
1.109
-2.508
18.795
78.280
3.754
121.730
95.221
2.873
6.414
-0.400
459.381
















^TotatVof.
460
460
460
460
460
460
460
460
460
460
460
460
460
460
460
















Sl Used
360
360
360
360
360
360
360
360
360
360
360
360
360
360
360
















r*3£
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















; Factor "
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















', Totems ;-; i
0.181
< 0.639
1.95
< 0.128
0.142
< 0.128
2.40
10.0
0.480
15.6
122
< 0.511
0.820
< 0.256
58.7
















                                                                                    J./15"
                                                                                   /fr-5
                                                                                  o.sn
                                         L V
                                         C i )r

                                         '; • '•' ' £
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at   03:46 PM
                                                                            01
                                                                            »« J-
-------
Client:       Pacific Environmental Services
Project Number:         43231	
 Sample Report
Client Sample ID:
TLI Samole ID:
Date Received1
Date Prepared:
Date Analyzed*
Matrix:
I-M29-2BHDA
183-3-3C BH DA
September 12. 1997
Seotember 25-26, 1997
October 07-08. 1997
Air
;* ^y^CHj
~ "" AralvteNV-KJi
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















">£br«w, •
! :, iuo»D?>
1.515
-4.545
15.177
0.094
1.225
-1.929
17.896
78.199
2.658
129.406
96.231
3.852
5.137
N/A
459.230
















^ iSL*< \
i TetalVol
460
460
460
460
460
460
460
460
460
460
460
460
460
N/A
460
















, c'nt •
%*r Used ;,
360
360
360
360
360
360
360
360
360
360
360
360
360
N/A
360
















s " * iWL ^i
-:Rn^M,
100
100
100
100
100
100
100
100
100
100
100
100
100
N/A
100
















\,ttfcifedf *•
v Factor \,v
1
1
1
1
1
1
1
1
1
1
1
1
1
N/A
1
















K^f^jUjTt^
^ Jtesuft :^,
0.194
< 0.639
1.94
< 0.128
0.157
< 0.128
2.29
9.99
< 0.383
16.5
12.3
< 0.511
0.656
N/A
58.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at  03:46 PM
-------
Client:       Pacific Environmental Services
Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-3-FH
183-3-4B. 184-23-3 AB FH
September 12.15.& 23. 1997
Sept. 25-26 & Oct 2-3, 1997
October 7.8.23 & 29-30. 1997
Air
/ ^ ? :^ ' :
Anslvt& s
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Ccfoa
foo/U -
196.154
3144.309
25008.222
91.076
30130.599
472.671
20380.124
1658612.349
4995.930
612397.537
1479459.811
12947.981
1164.243
1308.620
7750554.077
















* ^*$fc/\
Total Vot^
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















s% - ml, ^ '
* Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















«rtL
Final Vd.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















, Oilutk*v:
F&etor ;
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















," tctaiug
Result
19.6
314
2500
9.11
3010
47.3
2040
165900
500
61200
147900
1290
116
131
775100
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham. North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at  11:03 AM
                                                                               23
-------
Client:       Pacific Environmental Services
Project Number:        43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received*
Date Prepared:
Date Analyzed:
Matrix:
I-M29-3BH
183-3-4C BH
September 12. 1997
September 25-26, 1997
October 07-08. 1997
Air
: ijk ;:*&*£ oi
\ x^Analvte- ^" ;
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















xv-c£hcC^V
^ .{UQ/lbs
2.964
•2.307
7.222
0.205
13.109
-2.251
13.070
640.411
1.556
131.117
483.027
4.079
4.593
-0.600
2403.785
















v^jx-v •. (JPt* % s*^ :
' "Total Voll;
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
















jf&^firiL*-
--""; ''' \i®i!i£^
240
240
240
240
240
240
240
240
240
240
240
240
240
240
240
















^...js •. py^ jf-f ^
" Final VdL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















-• J%t»xrr>,v
,-,' " F^ctor*^
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















V -^Kjft.-^
^"YlSestilt "X^
0.420
< 0.708
1.02
< 0.142
1.86
< 0.142
1.85
90.7
< 0.425
18.6
68.4
0.578
0.651
< 0.283
341
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   05-Nov-97  at  03:46 PM
                                                                              94
                                                                              ** ~
-------
Client:       Pacific Environmental Services
Project Number:          43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-FHAR.FIELD BLANK FH
183-3-5B.184-23-9AB FH
September 12.15.& 23. 1997
Sept. 25-26 & OcL 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
1 ^ % •• v:
^Analvt©
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















..Goncv - -:
* * Cu&L} =
1.896
15.110
624.604
-1.061
-6.678
-23.922
103.044
38.387
66.402
786.693
9.729
67.715
57.674
0.400
113.068
















:* nt>°.
TbtalVof:,
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















^trri^i
"Used ;
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















rnL ,
Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















; ^Dilution
• " Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















, Tbtelug s
Result
0.190
1.51
62.5
< 0.100
< 0.100
< 0.100
10.3
3.84
6.64
78.7
0.973
6.77
5.77
< 0.200
11.3
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at   11:03 AM
-------
Client:       Pacific Environmental Services
Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-FHAR.BLK BH
183-3-5BC BH
September 12. 1997
September 25-26. 1997
October 07-08. 1997
Air
^Af|P
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















>r*Socuf
^&oto'S
0.446
-2.903
2.443
-0.668
1.853
-1.064
4.299
9.713
-0.887
45.672
21.074
0.429
12.213
1.200
119.933
















v^iwt"':*
* 'total vor;;
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
















V(^fS>*
^Ufceet "
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
















^,v & ?
t-RniiW
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















* - <. DiuboR :
- *ftriSr'^
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















y^pfeo*^vi
^Fteajir!^
< 0.100
< 0.500
0.244
< 0.100
0.185
< 0.100
0.430
0.971
< 0.300
4.57
2.11
< 0.400
1.22
< 0.200
12.0
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   05-Nov-97  at  03:46 PM
                                                                             26
-------
 Client:       Pacific Environmental Services
 Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-1 FH
183-3-6B.184-23-6ABFH
September 12.1 5.& 23. 1997
Sect. 25-26 & Oct. 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
- Analvte^
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















" /Oona - :!
" (uo/iv X1
3.703
9.119
649.382
-1.231
366.037
-24.978
109.230
423.582
76.189
905.584
2030.900
54.727
52.014
-37.404
1624.963
















* ~" rat ^
1 Total Vof.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















i , rrt '
- * Used \
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















riiL.--'"
* Final Vol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















- Dilution
1 fiactor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















"fotafug '-
- % Result
0.370
0.912
64.9
< 0.100
36.6
< 0.100
10.9
42.4
7.62
90.6
203
5.47
5.20
< 0.500
162
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at   11:03 AM
-------
Client:       Pacific Environmental Services
Project Number:        43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-1-BH
183-3-6C BH
Seotemberl2.1997
September 25-26. 1997
October 07-08. 1997
Air
i^x- 0*- 5' ^ *>** ~?i
i-w^*^ ft»,A\<
\"*tfuiH* :*
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















^ Oona-*'*
\Totova:
350
350
350
350
350
350
350
350
350
350
350
350
350
350
350
















- ^.< .id'- --.
f«yjm~-'^'
- Used ^
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250












"



. % •• * 1- >%
^KH*-:
"RhsiVaL*
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















*st)iMliijnui*c
>V^ Factor^ •
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















l-^uaVC!
^;xfeaadt**«
< 0.140
< 0.700
0.429
< 0.140
0.147
< 0.140
1.08
1.00
< 0.420
12.1
2.35
< 0.560
< 0.420
< 0.280
16.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   05-Nov-97 at  03:46 PM
                                                                            23
-------
Client:       Pacific Environmental Services
Project Number:         43231	
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-2 FH
183-3-7B.184-23-7ABFH
September 12.15.& 23. 1997
Sept. 25-26 & Oct. 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
	 •; 	
% •* :
'• ^ : f
Analvte^ ;
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cona ,
*..
-------
Client:       Pacific Environmental Services
Project Number;	43231	
 Sample Report
Client Sample ED:
TLI Samcle ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-2-BH
183-3-7C BH
September 12. 1997
September 25-26, 1997
October 07-08. 1997
Air
•••••;••.;•••>• ^ •; : 	 l ' •; v; :•'•:•
,••> *vf ..w^ ^-.^o-^sa- :?•
£• 1 V ••??'' L ' « ^>
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















I^V^ncsLv
-"-{UQ/tV'i
0.932
-3.666
7.064
-0.844
0.894
-0.770
9.822
8.633
1.456
107.632
21.368
0.215
14.199
-0.600
154.895
















-^'-v-'rwfc "< »
x^*,l»«.
>Tota*Vol
360
360
360
360
360
360
360
360
360
360
360
360
360
360
360
















*V
-------
 Client:       Pacific Environmental Services
 Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-3 FH
183-3-8B.184-23-8ABFH
Seotember 12.15.& 23. 1997
Sept. 25-26 & Oct. 2-3. 1997
October 7.8.23 & 29-30. 1997
Air
* ,-.- ' s % --- :
'Analvte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Ti
Zn
















«• " Qoncv ,-" ;
4 "tooO ;
18.713
15.336
684.966
-1.286
106.184
-27.120
128.152
1091.099
77.154
708.075
1129.659
69.080
60.821
-37.498
7442.587
















:-' n£ ;
^ Total Vot
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















^,mL 3
Used -•
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















* rnL\
Final Voi
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















* Dilution x
' Ractor ^
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Jofafug %
Result
1.87
1.53
68.5
< 0.100
10.6
< 0.100
12.8
109
7.72
70.8
113
6.91
6.08
< 0.500
744
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  07-Nov-97  at  11:03 AM
                                                                         31
-------
Client:       Pacific Environmental Services
Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
0-M29-3.BH
183-3-8C BH
September 12. 1997
September 25-26, 1997
October 07-08. 1997
Air
•• .-A v%% -. ;• >-\ x-b ^ :
&\ ^A •• ?•*• •• ' ; ^:
•AS, *i x >i(. ^; \
s/"*riaM»- ^
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















^-VCBnc:s"<
^.-r^Df*
0.525
-3.138
3.658
-0.805
0.663
-1.302
8.300
16.366
8.018
111.483
24.246
-0.608
1.416
0.800
143.887
















^t*rt £*
1 ToteiWL^
370
370
370
370
370
370
370
370
370
370
370
370
370
370
370
















;^*^-f\ =
^ Uffeil%*
270
270
270
270
270
270
270
270
270
270
270
270
270
270
270
















H<$&V
rpihidv&
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















stai$bif^:
**;&&£^.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















r\T«fcrts-^fr:
% *Re&a^N<
< 0.137
< 0.685
0.501
< 0.137
< 0.137
< 0.137
1.14
254
1.10
15.3
3.32
< 0.548
< 0.411
< 0.274
19.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   05-Nov-97  at  03:46 PM
                                                                        32
-------
Client:       Pacific Environmental Services
Project Number:         43231	
 Sample Report
Client Sample ID:
TLI Sample ED:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
LO-M29-REAGENT BLANK FH
184-23-10AB.5.183-15-1B FH
September 15 & 23. 1997
October 02-06. 1997
October 07-08. 1997
Air
S?'" -.^ -,-^'c1"-;:
• x"* * "• -v? - '-A : '
:• . 5 Anaivtsr *
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















^'Iftfrnr* -••
•• A --..irfiQnCky^-
v ^i«?LV>*x%
3.105
33.470
1035.234
-55.530
-6.706
27.753
402.853
239.746
158.144
788.062
57.982
69.894
60.905
0.700
564.608
















•i 'y-. SV-S-A . -. '<"'*'
'^-Wfc^
TotalVol;-
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















4/% -.'•'• * ,•• '•''
> •* v 'JTif .. ''v^
$#t\ •:•!••* !*•.•?•• '•
Wtfesd^-
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A














.

.^eii:c^
« Rna1Vb£"
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















- ^Ffeeto**-'' -
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















^t<^ua^'s
>- .Result? -, ,\
0.311
3.35
104
< 0.100
< 0.100
2.78
40.3
24.0
15.8
78.8
5.80
6.99
6.09
< 0.200
56.5
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  03-Nov-97  at  04:56 PM
                                                                         33
-------
Client:       Pacific Environmental Services
Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Samole ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
REAGENT BLANK BH
183-15-1BD BH
September 15 & 23. 1997
October 02-06. 1997
October 07-08. 1997
Air
v»^ ^cw S. ^ 4|i )*$& x
', X-' '*t ? '^" "* '••
;?> AwMfr^
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















'^Cbfas^
V-&fua7L£cf
1.186
-4.801
4.324
-0.986
-1.092
-4.620
17.917
6.018
5.207
126.393
9.672
8.746
6.364
0.900
126.992
















:C::m^:
^T&alVof:*
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300
















v*-.> •-v-rf'^ * **
<* *#&.<"'
<,- --Ifeecl >--
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300














.

"i \"H£°s-t
/RnalVoif
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

















1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

















0.119
< 0.500
0.432
< 0.100
< 0.100
< 0.100
1.79
0.602
0.521
12.6
0.967
0.875
0.636
< 0.200
12.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   03-Nov-97  at  04:56 PM
                                                                       34
-------
Client:       Pacific Environmental Services
Project Number:         43231	
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
REAGENT BLANK DI H2O
183-15-1C
September 15 & 23. 1997
October 02-06. 1997
October 07-08. 1997
Air
'»$«<>•
^\, ^Analyb
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
TI
Zn
















\f$Cbrfe .N
\ /diafo* *"
0.571
7.872
3.212
-1.241
-0.896
-3.361
13.983
3.676
8.472
2.904
0.432
4.816
8.973
0.300
12.314
















;<* -Hi.; ;-'
^tbtalVoi;"
345
345
345
345
345
345
345
345
345
345
345
345
345
345
345
















mg£*f
--^Useei--"';
345
345
345
345
345
345
345
345
345
345
345
345
345
345
345














.

^H^rat^*'
- RriftYok
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















>Diut»fc./;
"" Factor C
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















^*p«9f;v
< -> Result^4
< 0.100
0.787
0.321
< 0.100
< 0.100
< 0.100
1.40
0.368
0.847
< 3.00
< 0.200
0.482
0.897
< 0.200
1.23
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544--5491
Printed:  03-Nov-97  at  04:56 PM
                                                                        35
-------
Client:       Pacific Environmental Services
Project Number:        43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2 FH
184-23-2AB FH
September 23. 1997
October 02-03, 1997
October 07.08.23 & 30. 1997
Air
•i:" - s ; :.""•. :
'- 'AnalvteK' i
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















,- ^Stonc" «•
- %Cuoiti%
50.281
12.318
142.334
15.175
188.129
42.981
121.771
10416.737
22.231
134.852
9932.204
69.541
127.382
167.678
55531.383
















'. ***** Si
- TetaWol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















% >*i.'f •.-•••
- -• 
'. Final VWL%
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dtupon..
- Factor
10
200
200
10
200
10
200
200
200
200
200
200
10
10
200
















,'T'pteitJS ^0
-" Result
50.3
246
2850
15.2
3760
43.0
2440
208300
445
2700
198600
1390
127
168
1110600
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  30-Oct-97  at  02:18PM
                                                                          36
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2FHL
184-23-2ABFHL
September 23. 1997
October 02-03. 1997
October 07.08.23 & 30. 1997
Air
• > -4 s % -s ,"' -:
"- AraMe ,. ^
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
71
Zn
















X "; Gbrta/
"," &S/UT"
8.408
6.008
29.303
3.464
39.491
9.450
24.930
2214.038
5.732
33.613
2068.697
15.781
25.069
35.641
12158.620
















. VatV-
* Total VoL -
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















' , CffL -
Used ;->
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A














.
*
^ / fit «\
"Final Vat*
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















"DMbn'
- -Fa^or5- -
50
1000
1000
50
1000
50
1000
1000
1000
1000
1000
1000
50
50
1000
















-", Tcte|ua%" \-
c " Result %
42.0
601
2930
17.3
3950
47.2
2490
221400
573
3360
206900
1580
125
178
1215900
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  30-Oct-97  at  02:18PM
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ID:
TLI Samole ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1 itt
183-3-2B FH
September 12. 1997
September 25-26. 1997
October 07-08. 1997
Air
U'^^v^
"' : Artahrtsr :':i
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
TI
Zn
















^OwcCf
*v>IWUK
10.576
7.435
51.465
0.333
28.573
-1.725
41.404
1584.477
50.418
105.556
1913.501
23.734
8.559
1.400
11375.923
















^*|NS£*
TotalVoL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















s»<* •^•i-d-vi-v-
Xs^vn*./- -
; - ..Used -y
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A














.

^vc;ntee
^Rr&IVdL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















-»pn5
-------
Client:       Pacific Environmental Services
Project Number;	43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed'
Matrix:
I-M29-1 FH L
183-3-2BFHL
September 12. 1997
September 25-26, 1997
October 07-08. 1997
Air
• " \ -5T ' - < * "'
^ ^ •> s< :
^ ^Anslvte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















- ;-$fcwQ
% %- Ita/iy^s
2.246
2.140
10.543
0.322
5.654
-1.100
12.646
327.553
12.882
31.588
402.233
8.209
3.531
N/A
2409.756
















i s ^ni'"-^
> \ t**« s ^ ^
* TetatVoU
N/A
M/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















^7t$^T;
v,iu&6d"^
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A














.

' ^*ni* - -"-
' \^ ,^' > - *
'Tsfirivfc -
100
100
100
100
100
100
100
100
100
100
100
100
100
N/A
100
















l\^irtl)R;-^
5
5
5
5
5
5
5
5
5
5
5
5
5
N/A
5
















^lpiP<& v:~
-^Result - *" -'
1.12
< 2.50
5.27
< 0.500
2.83
< 0.500
6.32
164
6.44
15.8
201
4.10
1.77
N/A
1200
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:'  05-Nov-97  at  03:46 PM
                                                                           39
-------
Client:       Pacific Environmental Services
Project Number:	43231	
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Preoared:
Date Analyzed:
Matrix:
I-M29-3FH
184-23-3AB FH
September 23. 1997
October 02-03. 1997
October 07.08.23 & 30. 1997
Air
;,5,.. o £ ^i ;
' % *Ar«alvte" :
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone."
^ fticjlV
18.897
15.679
124.801
9.108
150.528
47.267
101.748
8285.539
24.911
3054.165
7389.845
64.666
115.553
130.862
38710.043
















1 mL- *
* IbttfVaL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















' ,..njt V
.Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















S
-------
Client:       Pacific Environmental Services
Project Number:        43231	
 Sample Report
Client Sample ID:
TLI Sample ED:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-3FHDA
184-23-3ABFHDA
September 23. 1997
October 02-03, 1997
October 07.08.23 & 30. 1997
Air
-. s !
Analyte- *
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















s ':: "Oona-
^ &q/L> '' %
18.883
17.302
127.045
9.051
153.500
47.701
104.130
8429.759
25.631
3137.046
7544.282
68.209
116.150
139.193
39478.926
















^ ^^
* TctalVol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















//JN- -
^-Useet
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A














.

, ' !&"<
- Knat Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















';Epu8c>r> -
^Factor- "
10
200
200
10
200
10
200
200
200
200
200
200
10
10
200
















^TQtatag, \
^ % Re^ift
18.9
346
2540
9.05
3070
47.7
2080
168600
513
62700
150900
1360
116
139
789600
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   30-Oct-97  at  02:18PM
                                                                         41
-------
Client:       Pacific Environmental Services
Project Number: 	43231	
 Sample Report
Client Sample ED:
TLI Sample ED:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2FH
183-3-3B FH
September 12. 1997
September 25-26, 1997
October 07-08. 1997
Air
v s ^ / :
s :
" * Amlvte -.- -\
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















''•> GWKX
' 'ItBtfU -
50.476
29.564
272.481
1.477
298.885
5.101
154.455
12557.011
51.422
420.150
14895.593
105.889
18.809
3.100
1695.179
















taL '':•
* TotalVol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















% ^ *T»I
*<> ••>• vim ••
'tfcerf
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















^ «t ^
Rt^^VbL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















DMJor>
¥&%#"
1
1
1
1
1
1
1
1
1
1
1
1
1
1
50
















^TotefwsfV^
Fteift> s i
5.05
2.96
27.2
0.148
29.9
0.510
15.4
1260
5.14
42.0
1490
10.6
1.88
0.310
8480
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at  03:46 PM
                                                                           4^>
                                                                           £
-------
Client:       Pacific Environmental Services
Project Number:	    43231	
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2FHDA
183-3-3B FH DA
September 12. 1997
September 25-26, 1997
October 07-08. 1997
Air
s>^x^ V -
?• 2 ? £., ^ f "* 5A-
&x Analyter ;
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Y^od^
vs fubfliK^
50.490
33.608
273.639
1.475
298.801
4.991
155.185
12519.816
52.033
425.212
14905.329
106.854
18.289
N/A
1701.079
















's ••tw/l °
v.T&tei.Vbi*.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















yktcV
AMsteed ^
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A














.

e^^
•*4R»ifok
100
100
100
100
100
100
100
100
100
100
100
100
100
N/A
100
















: £iut»n', '-
^iRaetor^
1
1
1
1
1
1
1
1
1
1
1
1
1
N/A
50
















/\Totelpg^^ :
*-\>Re«ifc^V
5.05
3.36
27.4
0.148
29.9
0.499
15.5
1250
5.20
42.5
1490
10.7
1.83
N/A
8510
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  05-Nov-97  at   03:46 PM
-------
Client:      Pacific Environmental Services
Project Number: 43231	
QA:  Serial Dilution
Client Samole ID:
TLI Sample ID:
Date Preoared:
Date Analyzed:
Matrix:
I-M29-1 FH
1X3-3-2B FH
September 25-26. 1997
October 07-08. 1997
Air
I-M29-1 FHL
183-3-2BFHL
SeDtember 25-26. 1997
October 07-08, 1997
Air

\%*«£'*i"V:
>*£ Afiaivte &:
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Native Sample
OV ^fflidj*?*
"-"" -- #" -Result- -r
1.06
0.744
5.15
< 0.100
2.86
< 0.100
4.14
158
5.04
10.6
191
2.37
0.856
< 0.200
1140
















*V>*$'>
I^Cbria^l
2.246
2.140
10.543
0.322
5.654
-1.100
12.646
327.553
12.882
31.588
402.233
8.209
3.531
N/A
2409.756
















r
-------
Client:       Pacific Environmental Services
Project Number:  43231	
QA:  Serial Dilution
Client Sample ID:
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2FH
184-23-2ARFH
October 02-03. 1997
October 07.08.23 & 30, 1997
Air
I-M29-2FHL
184-23-2ABFHL
October 02-03. 1997
October 07,08,23 & 30. 1997
Air

;V>'^ '- *
:.L Analyte;^.
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Native Sample
- ?5 % ..Totglyg ^
- : Result;.''
50.3
246
2850
15.2
3760
43.0
2440
208300
445
2700
198600
1390
127
168
1110600
















Vs *tfk*!
Cona >
50.281
12.318
142.334
15.175
188.129
42.981
121.771
10416.737
22.231
134.852
9932.204
69.541
127.382
167.678
55531.383
















Serial Dilution
;-:^h^
	 ;••,•• Rest*"..
42.0
601
2930
17.3
3950
47.2
2490
221400
573
3360
206900
1580
125
178
1215900
















k t w vgPL: ,;,
-;: . ^Cona....'\
8.408
6.008
29.303
3.464
39.491
9.450
24.930
2214.038
5.732
33.613
2068.697
15.781
25.069
35.641
12158.620
















\, ;x \**
L*£;
: ^. ". ^. ". *.
-------
Client:      Pacific Environmental Services
Project Number: 43231         	
QA:  Serial Dilution
Client Sample ID:
TLI Sample ID'
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1 BH
183-3-2C BH
Setrtember 25-26. 1997
October 07-08. 1997
Air
I-M29-1RHL
183-3-2C BH L
September 25-26. 1997
October 07-08. 1997
Air

* •?•* V- v ""> * V--X ^
\ **f -f v A
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Native Sample
s'^O^l*esi&\V
0.143
< 0.661
0.455
< 0.132
0.413
< 0.132
2.48
1.31
0.778
14.6
3.27
0.741
200
< 0.265
20.0
















"^hhlL*," ?
'.. &.}W'g>> *
> >cor£r'*
1.084
-2.845
3.441
0.143
3.120
-4.216
18.734
9.917
5.882
110.721
24.725
5.600
15.145
-0.500
151.166
















Serial Dilution
^i^fcNp;;
*^"ResOt ^
< 0.661
< 3.31
< 1.32
< 0.661
< 0.661
< 0.661
3.12
1.36
< 1.98
19.9
3.12
< 2.65
233
N/A
21.3
















CU«*\^
^ Om" *
0.155
-0.489
0.685
0.219
0.423
-1.161
4.711
2.062
1.933
30.067
4.713
1.112
3517
N/A
32.230
















llsbfiMI --'
$P&* ;
^
-------
Client:          Pacific Environmental Services
Project Number;	43231	
QA: Duplicate
Client Sample ID:
TLI Sample ID:
Date Prepared*
Date Analyzed:
Matrix:
T-M2Q-2FH
183-3-3B FH
September 25-26. 1997
October 07-08. 1997
Air
I-M29-2FHDA
183-3-3B FH DA
September 25-26. 1997
October 07-08. 1997
Air

Uw '^ ^%J. * ' -. •>
VJSV * ' \ v.? V
*!•?* Agsdvte-^0*
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Sample
C\rwu0^
,:^ >*$**ft ~< ,
5.05
2.96
27.2
0.148
29.9
0.510
15.4
1260
5.14
42.0
1490
10.6
1.88
0.310
8480
















^'%t(;
"< Coril " i
50.476
29.564
272.481
1.477
298.885
5.101
154.455
12557.011
51.422
420.150
14895.593
105.889
18.809
3.100
1695.179
















Duplicate
^rFafeit^
^ S &U&"
505
3.36
27.4
0.148
29.9
0.499
15.5
1250
5.20
42.5
1490
10.7
1.83
N/A
8510
















> XM.>>
-*-" Condv, ..
50.490
33.608
273.639
1.475
298.801
4.991
155.185
12519.816
52.033
425.212
14905.329
106.854
18.289
N/A
1701.079
















x *X** *
;?;BPD;'
•.' \' > -
0.000%
-------
Client:          Pacific Environmental Services
Protect Number:	43231	
QA: Duplicate
Client Sample ID:
TLI Sample ID:
Date Prepared*
Date Analyzed'
Matrix:
T-M29-3 FH
184-23-3AB FH
October 02-03. 1997
October 07.08.23 & 30. 1997
Air
I-M29-3 FH DA
184-23-3AB FH DA
October 02-03. 1997
October 07.08.23 & 30. 1997
Air

'", "< ,\% --' o."
-< Analvfe "-
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Sample
,:^* -Tolafug
* " "^J&st*' -
18.9
314
2500
9.11
3010
47.3
2030
165700
498
61100
147800
1290
116
131
774200

















-*^ ug/Ls>:
^ toncS-i
18,897
15.679
124.801
9.108
150.528
47.267
101.748
8285.539
24.911
3054.165
7389.845
64.666
115.553
130.862
38710.043




.











Duplicate
^{Rjtaur
°"""x ^HeSl*'5"
18.9
346
2540
9.05
3070
47.7
2080
168600
513
62700
150900
1360
116
139
789600

















>",* ;«g&V" o
: V- Cone.- :-
18.883
17.302
127.045
9.051
153.500
47.701
104.130
8429.759
25.631
3137.046
7544.282
68.209
116.150
139.193
39478.926
















'vX v\,\ ^f
;j^pp^
- y^-'^V"
0.000%
-------
Client:          Pacific Environmental Services
Project Number:	43231	
QA: Duplicate
Client Sample ID:
TLI Sample ID:
Date Prepared:
Date Analvzed:
Matrix:
J-M29-2RH
m-v?rRH
September 25-26. 1997
ncroher 07-08. 1997
Air
I-M29-2BHDA
183-3-3CBHDA
September 25-26. 1997
October 07-08. 1997
Air

\ ; v?S*\ ^ s ^
, ^jtesaMs'^
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Sample
-Co-'TJ*"?^
" % ^iR&SUft*":
0.181
< 0.639
1.95
< 0.128
0.142
< 0.128
2.40
10.0
0.480
15.6
12.2
< 0.511
0.820
< 0.256
58.7
















! «*' Sf
i :Cooc. '- .:
1.419
-4.446
15.256
0.105
1.109
-2.508
18.795
78.280
3.754
121.730
95.221
2.873
6.414
-0.400
459381
















Duplicate
: '^ifctefcuj? ,:
"4 ft**
0.194
< 0.639
1.94
< 0.128
0.157
< 0.128
2.29
9.99
< 0.383
16.5
12.3
< 0.511
0.656
N/A
587
















^#ws$t --•£'
^VXJflWL *
1.515
-4.545
15.177
0.094
1.225
-1.929
17.896
78.199
2.658
129.406
96.231
3.852
5.137
N/A
459230
















*.'-f -f
Mll%,
-' \ A '
-------
Client:  Pacific Environmental Services
Project Number:       43231	
QA: Matrix Spikes (Post-Digestion)
Client Sample ID:
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1 FHPDS
183-3-2B FH PDS
September 25-26, 1997
October 07-08. 1997
Air






\ ff
5s '
rAffUvte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
71
Zn
















Post-Diqestion Spike
^ftecsbvfrecl
AirrmlnthM^
56.28
52.32
100.90
45.60
77.08
46.53
91.75
1619.02
99.32
106.60
1945.17
68.97
53.34
23.50
11470.90
















vt\»e *'*
'ArriountftKtfU
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
















* *%>
Recoweiv
91%
90%
99%
91%
97°/e
93%
101%
Spike Low
98%
0%
Spike Low
90%
90%
47%
Spike Low
















Post-Diqestion Spike Duplicate
s.i^eqoyered i
sAmour^(uo'U;































* Vx8pj
-------
Client:  Pacific Environmental Services
Project Number:	43231
QA: Matrix Spikes (Post-Digestion)
Client Sample ID:
TLI Sample ED:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2 FH PDS
184-23-2AB FH PDS
October 02-03, 1997
October 07,08,23 & 30, 1997
Air






51 %
'• •. -.
'^AnaiYte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Post-Diqestion Spike
; * jtepoteied \
Amc^tTuo/tV
87.50
61.65
188.76
58.87
233.79
87.37
167.82
10177.98
70.82
1115.16
9627.54
117.81
173.05
214.25
54164.58
















,.- ;Spik% V'
Amount fuo/D































s^**«
-Reeoveiv































v . ••
"-<-.:, --^r
^ RPD ^
•- %
—
_—
—
—
_—
—
—
_.
...
—
—
—
_.
—
—
—
—
—
—
...
—
—
—
...
—
—
...
_.
—
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:    30-Oct-97
at    02:18 PM
                                                                       51
-------
Client:  Pacific Environmental Services
Project Number:      43231
QA: Matrix Spikes (Post-Digestion)
Client Samole ID:
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1 BH PDS
183-3-2C BH PDS
Seotember 25-26, 1997
October 07-08, 1997
Air






< s' ' , N •• ,
- •? -^ '•• **"^s
: Anatvte
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
n
Zn
















Post-Diqestion Spike
^ fpB^$d;%
;A*noum&tfi*
46.67
42.67
52.75
46.90
52.22
45.78
65.84
59.62
53.36
108.02
73.37
51.92
57.09
22.20
343.12
















:-VSP*\;:
Amount ftiaflU
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
















V/%,' *
* Recovery
91°/<
85°/c
99%
94°/<
98°/c
92°/<
94°/<
99°/<
95°/<
-0%
97°/t
93°/c
847<
44°/£
96%
















Post-Digestion Spike Duplicate
VBsai»tef^\
^Amour^^uaU^































V;?^pike,^ x
Amount {udU































? ^^-" -%:
>,.f*.*% \--
'F^oveiv:































t^-^V
XW
^ v s - ••N--
N *• '•*•
„
	
	
	
«
	
_
__
	
	
	
	
	
	
—
_.
	
	
_.
»
	
	
„
	
	
	
„
	
	
_
	
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   05-Nov-97
at
03:48 PM
-------
Client:   Pacific Environmental Services
Project Number.    43231          	
QA: Method Blank
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43231 MB
September 25-26, 1997
October 07-08. 1997
N/A

: -. -. •• f V
.Anafrle*
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Method Blank
,^jB&3were&x ,
-^ounffurjiy
0.01
0.21
0.13
0.30
-0.19
-0.08
0.23
0.80
0.77
3.21
-0.07
0.50
0.10
1.20
22.53
















*•".>, i^ ... > v,^°^; \^*
- , UmiHuslV *^'/' '
1
5
2
1
1
1
2
2
3
30
2
4
3
2
12
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—

- ^assor,
: ^Faif
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Fail
—
—
—
—
_
—
—
—
—
—
—
—
—
—
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 2771
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: 05-Nov-97
at
03:48 PM
-------
Client:   Pacific Environmental Services
Project Number:   43231	
QA: ICP Method Blank
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43231 MB
October 02-03. 1997
October 07,0823 & 30. 1997
N/A

>V Sf-^vl

Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn

















^ffeoaMtiU
" Amount CCidfti
-0.04
-1.68
-0.04
-0.81
-0.24
-0.53
0.07
2.84
-1.13
-13.83
1.67
-0.82
0.23
-5.42
9.79
















Method Blank
'': S&dcAdft «:* • : d
- - llintftiaftJ " , 1 *
1
5
2
1
1
1
2
2
3
30
2
4
3
5
12
_
—
—
—
—
—
—
...
—
—
—
_
—
—
_
—

i ^;P^ock i
K^'W '
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Fail
Pass
Pass
Pass
Pass
Pass
Pass
Pass
—
—
—
—
—
—
—
—
—
—
—
—
—
—
„
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 2771
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  06-Nov-97
at
02:08 PM
                                                                     54
-------
Client:  Pacific Environmental Services
Project Number:      43231	
QA: Lab Control Spikes
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43231 LCS
September 25-26. 1997
October 07-08. 1997
N/A





j^^l
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
T!
Zn
















Lab Control Soike
^&&xM&^
"•* *;"^ S "*• *\ * ^ •. J» ^
'AftK^6us&>
46.92
49.55
50.04
47.96
50.47
49.51
50.38
50.22
50.80
1027.18
48.37
51.11
48.89
49.80
202.13
















fcyWte^
3taitxif*ttiBfU
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
















'•^t%Jr
Fiecwerr
94°/<
99°/<
100°/<
96°/c
101°/c
99°/c
101°X
100°/c
102°/<
103°/(
977<
102°/c
98°/c
100°/c
1017<














•

Lab Control Soike Duolicate
>v:ftec6p&^
^Arnc«jr(t{u^t>































*&$$$^$$;
,Amoun|{u«jfU































-s "*>£'••*<•;
-^^^A
imwveiy^































5<.> •• V ••' i ,-.-.\ °
'•JC'-V < < vXv^V
r RPD^'J
Jjiv^:
—
—
—
—
_
__
—
—
—
«..
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
_
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   05-Nov-97
at
03:48 PM
                                                                           55
-------
Client:  Pacific Environmental Services
Project Number;	43231	
QA: ICP Lab Control Spikes
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43231 LCS '
October 02-03, 1997
October 07.08.23 & 30. 1997
N/A





-V* V •
AnaJvte :
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
TI
Zn
















Lab Control Spike
, Recover©^ --.
% An^oxifltftiaty
43.16
44.64
46.44
45.27
45.89
46.96
46.87
47.66
45.34
904.63
46.69
47.00
44.37
41.73
192.40
















\ ,•&*», ,-;
^AmouftuiJqi'U
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
















;v:v%*- ^
Ftecoveiv
86°/c
89°/c
93°/<
91°/<
92°/c
94%
94°/<
95°/<
91°/<
90°/c
93°/c
94°/J
89°/; -SpjkSf 5\ *
/Amount («g/U































tfv%;.i
R^oveiy^































^j-^?'ir-
^ WgQ* -
•<•• ••
—
—
—
—
_
—
—
—
—
_
—
—
—
™
...
—
—
—
—
—
—
„
._
—
—
—
—
—
—
„
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:   30-Oct-97
at
02:18PM
                                                                          56
-------
Client:
Protect Number:
Pacific Environmental Services
                        43231
Sample Report
                                    Page 1 of 5
P^W? RffffP^Y^d*
Date Prepared:
Date Analyzed:
DATA FILE:
MatriK:
September 12.15 A 23. 1997
Sept.25-Oct.10. 1997
Sent. 30 & Oct. 1.6. 8 & 10. 1997
AB11. AB812. AB81S. AB8I6. & AB818
Air
                                                                                    ANIALVTP- Ho
                                                                                   uq/LRDL:  OJ2
                                                                                    Analysis Method:
                                                                                                       29
                                                                                    Insttument P EZaeman 5100
                                                                                    Spike Cone. faa/L)     5
                                                   CVAA ANALYTE SUMMARY REPORT
j^V-v *;/ ;- / s „- ^*$%&
tSB&BHrwjtefe "Vs- ^ - ^«1K*
I-M29-FHAR.FIELD BLANK FH
I-M29-FHAR.FIELD BLANK FH D
I-M29-FHAR,BLKS% 10% BH
l-M29-FHAR,BLK-5% 10% BH D
I-M29-BLK-BHARHNO3
I-M29-BLK-BHARHNO3D
l-M29-BLK-KMnO4
l-M29-BLK-KMnO4 D
l-M29-BLK-KMnO4-HCI
l-M29-BLK-KMnO4-HCI D
I-M29-1-FHAR FH
I-M29-1-FHAR FH D
I-M29-1-S%10%BH
l-M29-1-5% 10% BH D
I-M29-1-BHAR HNO3
I-M29-1-BHARHNO3D
l-M29-1-KMnO4
l-M29-1-KMn04 D
l-M29-1-KMnO4-Ha
l-M29-1-KMnO4-HCID
I-M29-2-FHAR FH
I-M29-2-FHAR FH D
l-M29-2-5% 10% BH
l-M29-2-5% 10% BH D
I-M29-2-BHAR HNO3
I-M29-2-8HAR HNO3 D
l-M29-2-KMn04
l-M29-2-KMnO4 D
I-M29-2-HCI
I-M29-2-HC) D
\\ \ ^v>*x ".v. ^t *• 5 % ^>j*^
V < \v^*V» N •%JX* \ t " * 4r
*msmps$ - '~> -x% -^_
183-3-1B.184-23-4AB
183^3-lB,184-23-4ABD
1 83-3-1 BC
183-3-1 BCD
183-3-1 D
183-3-1 DD
1 83-3-1 E
183-3-1 ED
1 83-3-1 EF
183-3-1EFD
183-3-28.184-23-1AB
183-3-28.184-23-1AB D
183-3-2C
183-3-2C D
183-3-2D
183-3-2D D
183^-2E
183-3-2E D
183-3-2F
183-3-2FD
183-3-3B.184-23-2AB
183-3-3B.184-23-2AB D
183-3-3CDX5
183-3-3CDX5D
183-3-3D
183-3-3DD
183-3-3E
183-3-3ED
183-3-3F
183-3-3FD
~&L\
oCONC
0.087
0.079
0.013
0.005
0.027
0.029
0.076
0.176
0.008
0.024
5569
5.153
3.766
4.031
0.070
0.073
0.698
0.730
0.067
0.064
9249
9.097
3.449
3.428
0.807
0.788
1.174
1.217
0.062
0.053
> SSiK
IV'
N/A
N/A
300
300
61
61
263
263
10.5
10.5
N/A
N/A
410
410
100
100
370
370
21
21
N/A
N/A
460
460
110
110
360
360
23
23
" «iN
^
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
^v
v&iciuej
5
5
5
5
S
5
S
5
5
5
5
5
S
5
5
5
5
S
5
5
5
5
5
5
5
5
5
5
5
5
'~i8L-
mm?
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
5
1
. 1
1
1
1
1
xx\T$i»*
4 RSSUO
< 0.400
< 0.400
< 150
< 150
< 0544
< 0544
< 1.0S
< 1.05
< 0.042
< 0.042
10.5
10.3
30.9
33.1
< 0.400
< 0.400
5.17
5.40
< 0.084
< 0.084
18.5
185
159
158
1.78
1.73
8.45
8.76
< 0.092
< 0.092
t\: x/**^
M> RESULT
< 0.400
< 1.20
< 0544
< 1.05
< 0.042
10.4
32.0
< 0.400
5.28
< 0.084
18.3
158
1.75
8.61
< 0.092
\t^\
^SPff-
_
—
_
—
_
-
-
-
_
—
-
—
_
—
-
«&REC*
	
-
_
_
-
-
-
-
_
_
_
—
-
—
-
-------
 olect Number:
Pacific Environmental Services
                   43231
Sample Report
                              Page 2 of 5
] e Recciy£(i-
Date Prepared:
Date Analyzed:
: TA FILE:
1 trix:
September }2 &. 15. 1997
Sect. 25-Oct 10. 1997
Sent. 30 AOctl.8 & 10. 1997
AB11. AB812. AB816. A AB818
Air
ANALYTE Hg
UoA. RDL: 02
Analysis Method*
29
Instrument p E Zeerjian 5100
Spike Cone. fug/O
5
                                           CVAA ANALYTE SUMMARY REPORT
b^S^ote^ . V*''«
WI29-3-FHARFH
/29-3-FHAR FH D
l-M29-3-5% 10% BH
Vl29-3-5% 10% BH D
I-M29-3-BHAR HNO3
I-M29-3-BHARHNO3D
V)29-3-KMnO4
l-M29-3-KMnO4 D
M29-3-HCI
M29-3-HCI D
O-M29-FHAR FH
•-M29-FHAR FH D
O-M29-FHAR.BLK-5% 10% BH
O-M29-FHAR,BLK-S% 10% BH D
I-M29-BLK-BHARHN05
0-M29-BLK-BHAR HNO3 0
)-M29-BLK-KMn04
)-M29-BLK-KMn04 D
O-M29-gf-HCI G!>,~K<£
VM29-"3-HCID * trnc'
O-M29-1-FHAR FH
O-M29-1-FHARFHD
>-M29-1-5%10%BH
O-M29-1-5%10%BHD
-J-M29-1-BHARHNO3
)-M29-1-BHARHNO3D
O-M29-1-KMnO4
O-M29-1-KMn04D
J-M29-1-HO
O-M29-1-HCID
. s •>• ^ % . -.Wi x-- ••- ••
WufiSvn '- - - " V
183-3<4B
183-3-4BD
183-3-4C
183-3-4CD
183-3-4D
183-3-4DO
183-3-4E
183-3-4ED
183-3-4F
183-3^tFD
183^-68
183-3-5BD
183-3-5BC
183-3-5BCD
183-3-5D
183-3-5DD
183-3-5E
183-3-5ED
183-3-5EF
183-3-5EF D
183-3-6B
183-3-6BD
1 83-3-6C DXS
183-3-6CDX5D
183-3-60
183-3-6DD
183-3-6E
183-3-6ED
183-3-6F
183-3-6FD
.^««t\
*txsw
0.060
0.049
7.919
7.987
0.143
0.141
0.726
0.601
0.097
0.125
0.043
0.054
0.003
0.005
0268
0290
0.043
0.062
0.011
0.035
0.284
0.076
7221
7.183
1.002
0.994
0.666
0.707
0.9*15
0208
-*ai
^ly-
N/A
N/A
340
340
100
100
393
393
21
21
N/A
N/A
150
150
50
50
255
255
110
110
N/A
N/A
350
350
99
99
375
375
24
24
***>
py,
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
-^w*>
&*KK*
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
S
5
5
5
%,J -. XJI&VA
F&JTQF
1
1
1
1
1
1
1
1
1
1
1
1
i
1
1
1
1
1
1
1
1
1
5
5
1
1
1
1
1
1
^ ^^btel.iigi
< 0.400
< 0.400
53.8
54.3
< 0.400
< 0.400
5.71
4.72
< 0.084
< 0.084
< 0.400
< 0.400
< 0.600
< 0.600
0268
0290
< 1.02
< 1.02
< 0.440
< 0.440
0.568
< 0.400
253
251
1.98
1.97
5.00
5.30
0.439
0.100
;?*<*«c -
•5 RESULT
_
< 0.400
_
54.1
_
<: 0.400
—
522
_
< 0.084
_
< 0.400
_
< 0.600
_
0579
..
< 1.02
< 0.440
.,
< 0.484
»»
252
w
1.98
M<
5.15
ta
0270
* *• - s
•^%%s &
"•!«£
_
-
_
-
_
-
•mm
-
^ „
-
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-
_
-
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-
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-
-
._
-
_
-
«.
-
mm
-
••
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^^
•^dte'
_
-
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-
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-
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-
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-
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-
.
-
M*
-
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-
-
^
-
—
-
_,
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^^
-
u.t
-
                                                                                        58
-------
Client:
Project Number;
Pacific Environmental Sendees
                      43231
Sample Report
                                  Page 3 of 5
Date Received*
Date Prepared:
Date Analyzed:
DATA FILE:
Matrix:
September 12 A }5. 1997
Sept. 25-OctlO. 1997
Sept, 30 & Octl.8 & 10. 1997
ABU. AB812. AB816. & AB818
Air
                                                                                ANAIYTF- Ha
                                                                                ua/LRDL-  0.2
                                                                                Analysis Method:
                                                                        29
                                                                                Instalment P E Zaeman 5100
                                                                                Soika Cone. fua/U	5
                                                CVM ANALYTE SUMMARY REPORT
, y— Y3-5% 10% BH D
O-M29-3-BHAR HNO3
O-M29-3-BHAR HNO3 D
O-M29-3-KMnO4
O-M29-3-KMnO4 D
O-M29-3-HCI
O-M29-3-HC! D
1.0-M29-REAGENT BLANK FH
1.O-M29-REAGENT BLANK FH D
REAGENT BLANK BH
REAGENT BLANK BHD
REAGENT BLANK HNO3
REAGENT BLANK HNO3 D
REAGENT BLANK HCI
REAGENT BLANK HOD
REAGENT BLANK DIH20
REAGENT BLANK Dl H2O D
^ : " > * 3? " " 'f ^
TtJ&MWD :" <*'
183-3-7B
183-3-7BD
183-3-7CDX5
183-3-7CDXSD
183-3-7D
183-3-7D D
183-3-7E
183-3-7ED
183-3-7F
183^-7FD
1 83-3-6 B
183-3-8BD
1833-8CDX2
183-3-8CDX2D
1 83-3-8 D
1 83-3-80 D
183-3-8E
183-3-8ED
183-3-6F
183-3-8FD
1 84-23-5,1 OAB.1 83-1 5-1 B
1 84-23-5,1 OAB.1 83-1 5-1 B D
183-1 5-1 BO
183-1 5-1 BOD
183-15-1B
183-15-1BD
183-15-1E
183-15-1ED
183-1 5-1 C
183-15-1CD
; '<**,,
cb«6
0.049
0.114
4.508
4.895
1.565
1.467
1.316
1.273
0.103
0.135
0.051
0.043
7.288
6.868
0.990
0.974
0.620
0.615
0.059
0.112
0.035
0.022
0.054
0.043
-0.003
•0.003
0.003
-0.005
0.005
0.008
<. a*--
>iy:
N/A
N/A
360
360
105
105
380
380
24
24
N/A
N/A
370
370
102
102
383
383
25
25
N/A
N/A
300
300
30
30
100
100
345
345
, **
" FV^
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
^V**i
M?
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
'^DiU^
FACTQF
1
1
5
5
1
1
1
1
1
1
1
1
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
>^piSi»
-'KESI&T
< 0.400
< 0.400
162
176
329
3.08
10.0
9.67
< 0.096
< 0.096
< 0.400
< 0.400
108
102
202
1.99
4.75
4.71
< 0.100
< 0.100
< 0.400
< 0.400
< 1.20
< 1.20
< 0.120
< 0.120
< 0.400
< 0.400
< 1.38
< 1.38
', , &&.-£
' aesufcT
< 0.400
169
3.18
9.84
< 0.096
< 0.400
105
ZOO
4.73
< 0.100
< 0.400
< 120
< 0.120
< 0.400
< 1.38
'-BP&
«~*
_
-
-
—
-
_
-
-
-
-
—
-
-
—
\ "•; 	 :
'^tfHBC'
-
-
_
-
-
-
-
—
_
-
—
-
-
—
-
                                                                                                59
-------
Client:
~' •eject Number;
Pacific Environmental Services
                     43231
Sample Report
                                  Page 4 of 5
I '•& RCC?iYfitf'
te Prepared:
Date Analyzed:
DATA FILE:
. trix:
September 12 & 15 1007
Scot. 25-OctlO. 1997
Set*. 30 & Oct. 1.8 A 10. 1997
AB11 AB812. AB816 &AB818
Air -
                                                                                AKIALYTF! Ha
                                                                                UQ/LRDL  0.2
                                                                                Analysis Method:
                                                                                                    29
                                                                                 Instniment P E Zaeman 5100
                                                                                 Soika Cone. (uo/U	S
                                                CVAA ANALYTE SUMMARY REPORT
: ^ 0 - , , - „ %V , f ' ' % , " "
UantSajnoteSi^t'' ; ~~''f' - "-
' V!29-FHAR,BKL-5% 10% BH MS
VI29-FHAR,BKL-S% 10% BH MSD
I-M29-1-5%10%BHMS
1 M29-1 -5% 10% BH MSD
..Ul29-1-KMn04MS
l-M29-1-KMn04MSD
v129-2-5% 10% BH MS
1/129-2-5% 10% BH MSD
!-M29-3-5% 10% BH MS
Ul29-3-5% 10% BH MSD
O-M29-1-5% 10% BH MS
O-M29-1-5% 10% BH MSD
•M29-2-KMnO4MS
O-M29-2-KMnO4 MSD
-M29-3-KMnO4MS
-M29-3-KMnO4 MSD
REAGENT BLANK BH MS
EAGENT BLANK BH MSD
l-M29-FHAR,BKL-5% 10% BH MS
l-M29-FHAR,BKL-5% 10% BH MSD
\/!29-1-5%10%BHMS
I-M29-1-S% 10% BH MSD
ri29-1-KMnO4MS
d29-1 -KMnO4 MSD
l-M29-2-5% 10% BH MS
t/129-2-5% 10% BH MSD
i-«!29-3-5%10%BHMS
l-M29-3-5% 10% BH MSD
•M29-1-5%10%BHMS
u-M29-1-5% 10% BH MSD
'•." ^ ^\ '' >-V' %< i ',-•••
%% % .g.% \ 
-------
 Client:
• Project Number:
Pacific Environmental Services
                       43231
 Sample Report
                                    Page 5of5
Date Received:
Dafe Prepared;
Date Analyzed:
DATA FILE:
Matrix:
September 12 & 15. 1997
Sept. 25-Oct.lO. 1997
Sent. 30 & Oct.1.8 & 10. 1997
AB11, AB812. AB816, & AB818
Air
ANALYTE- Hp
ug/L RDI • O 9
Analysis Method
29
Instrument P E Zeeman 5100
Seiko Cone. (uo/U
5
                                                    CVAA ANALYTE SUMMARY REPORT
bte&Mjfc^ w;-'^?
O-M29-2-KMnO4 MS
0-M29-2-KMnO4MSD
0-M29-3-KMnO4 MS
O-M29-3-KMnO4 MSD
REAGENT BLANK BH MS
REAGENT BLANK BH MSD
Method Blank
Method Blank D
LCS
LCSD
Method Blank
Method Blank D
LCS
LCSD
Method Blank
Method Blank D
LCS
LCSD
Method Blank
Method Blank D
LCS
LCSD
Method Blank
Method Blank D
LCS
LCSD
ItlSAtiV ' ?*^K
True Spike MS
True Spike MSD
True Spike MS
True Spike MSD
True Spike MS
True Spike MSD
43231 MB1
43231 MB1 D
43231 LCS1
43231 LCS1 D
43231 MB2
43231 MB2 D
43231 LCS2
43231 LCS2 D
43231 MBS
43231 MB3 D
43231 LCS3
43231 LCS3 D
43231 MBS
43231 MBS D
43231 LCS5
43231 LCS5 D
43231 MBS
43231 MB6D
43231 LCS6
43231 LCS6 D
r^g
5
5
5
5
5
5
0.030
0.027
4.979
5.117
0.035
0.046
5.076
5.280
0.008
0.011
4.646
4.400
0.008
0.030
5.526
5.053
•0.003
0.000
4.574
4.912
-;^
380
380
383
383
300
300
H
-
-
-
~
-
~
_
—
-
ii^ffii
N/A
N/A
N/A
N/A
N/A
N/A
_
-
-
-
-
_
-
-
-
-
*i$y
5
5
5
5
5
5
_
_
-
-
—
_
-
-
—
-
^™
1
1
1
1
1
1
-
-
—
_
-
_
-
-
-
-
lhSS
38.0
38.0
38.3
38.3
30.0
30.0
—
-
-
_
_
-
-
_
-
-
>*S8^
_
-
-
-
-
-
..
_
H
_
-
-
-
••
_.
-
-
-
-
-
_
~
..
-
_
-
-
xy -^
w
-
-
,_,
100%
102%
—
102%
106%
—
93%
88%
-
111%
101%
_
91%
98%
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                                         Printed:     OS-Nov-97   at   11:19 AM
                                                                                                       61
-------
                                                                                                /"»

                                                                                                i  9
                                                                                    t  i err i
                               ANALYTICAL REQUEST AND CHAIN OF CUSTODY
        PLANT:
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   ./i
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         SAMPLE IDENTIFICATION
                          "COLLECTION
          DATE  TIME
                     SAMPLE NAME
                                      NUMBER OF
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                                                 "7
                                                  "7
                                                  "7
                                                  7
                                                 7
                                                  7
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REtiNQUISHER'S NAME
                                      7-
           RECEIVER'S NA
                                 DATE/TIME
                  bATE/TIME
                                                                         SHIPPER'S NAME AND ID NUMBER
-------
            CT7
                              ANALYTICAL REQUEST AND CHAIN OF CUSTODY
       PLANT
       :  \ A/
         VV
-------
                                                       7
                       SAMPLE RECOVERY DATA
PLANT
DATE
                       Sample Box No.
                                              Run No.
                                              Job No.
SAMPLE LOCATION

TRAIN PREPARER
                                              Filter No.
                       / /  /TJJUH • fl
SAMPLE RECOVERY PERSON

COMMENTS       	
                                                        ;J  A*
FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter'
                            Liquid
                                Marked
                                              Sealed
                                              Sealed
Samples Stored and Locked

BACK HALF/MOTSTTIRF
Container No.        	3"
 Liquid Level Marked
                                              Sealed
    IMP. NO.
               CONTENTS
          'TOTAL
                          INITIAL VOL
                             (ml)
                            OO
                            ion
                            O
                         *•  100
                            103
                                                 WEIGHT (grams)
                                        INITIAL
                                      730-3.
                                      512,8
                                                    FINAL
                                                 r*/.
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                                                                 NET
                                                              -0.6
                                                               O./
-------
535E5
                            SAMPLE RECOVERY DATA
PLANT Wf-fv» 1
DATE lA/W
SAMPLE LOCATION
^V.«/i.
Sample Box No. *""
21/.Y
RunNo. -U n*1 ~ \
Job No. SiJ^-dOy
. Filter No. J<f
    TRAIN PREPARER
    SAMPLE RECOVERY PERSON     /*?
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter'
     Samples Stored and Locked

     BACK HALF/MQISTTIttK
     Container No.
     Liquid Level Marked
                                 Liquid
                                     Marked
                                Sealed
                                                    Sealed
                                                          U'J
                                Sealed
        IMP. NO.
CONTENTS
                           INITIAL VOL
                             (mi)
                                                       WEIGHT (grams)
                                             INITIAL
                                      FINAL
                                                                  NET
                                                                   -H.I
                                too
                                100
                                                                    n.o
               TOTAL
          *  *   ^ v   *
         »•«•+• 4^w **+ fv  *••
                                                                  bo
-------
                        SAMPLE RECOVERY DATA
PLANT    Ux^A. _ I  Ccr r«c.o '* ' /
Samples Stored and Locked

BACK HALF/MOTSTirRF
Container No.
 Liquid Level Marked
                                               Sealed
    IMP. NO.
               CONTENTS
                           INmAL VOL
                              (ml)
                                                  WEIGHT fgramsj
                                        INITIAL
                                                     FINAL
                                                                  NET
                           100
                            ioo
                             t>
                                             j
                            loo
                                                    6V.3
           TOTAL
 Descrrntion of Inrninffer r*atch;
                                                       .,,     6b
-------
                        SAMPLE RECOVERY DATA
PLANT W *.wp«zci h
DATE 41/0/n
SAMPLE LOCATION
iLrftJn.
7
\
Sample Box No.
i;/*
Run No. J--/725-?
Job No. S*V^.O>^
Filter No. 10 //
TRAIN PREPARER M A^.* //«
SAMPLE RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
Samples Stored and Locked

RACK HALF/MOLSTIJRfc
Container No.        "
Liquid Level Marked
                            Liquid
                        FH**Level Marked
                                Sealed
                                               Sealed
                                Sealed
    IMP. NO.
CONTENTS
                           INmAL VOL
                              (ml)
                                                  WEIGHT (gramsi
                                        INFTIAL
                                      FINAL
                                                                  NET
                             100
                                                                n.C
                             0
                            /Off
                                   "73^.0
                                                                 0-T
                            loo
          •TOTAL
                                                               D i
-------
                        SAMPLE RECOVERY DATA
PLANT W*.-^* r.**J~
i i
DATE 
-------
                       SAMPLE RECOVERY DATA
PLANT

DATE    *3/4/
            ..     FLJ
                                              Run No.
              c7
                       Sample Box No.    —      Job No. S
SAMPLE LOCATION
TRAIN PREPARER
                                              Filter No.
SAMPLE RECOVERY PERSON    /*?

COMMENTS
                                  'J
                                                         / -
FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter'
                            Liquid
                                Marked
                           />
                                              Sealed
                                              Sealed
Samples Stored and Locked

BACK HALF/MOISTTJRE
Container No.        _
Liquid Level Marked
                                              Sealed
    IMP. NO.
               COffTENTS
                          INITIAL VOL
                             (ml)
                                                 WEIGHT (granui
                                       INHIAL
                                                    FINAL
                                                                 NET
                          100
                                                 517.5
                                     7^7.7
                                                                6,7
                           100
                                                  739,0.
                                                                7-S
                                                                JHU
          •TOTAL
                              0 \
                              •  'I-

-------
                        SAMPLE RECOVERY DATA
PLANT
                                               Run No.
DATE  _°L
                        Sample Box No.
                                              Job No.   
-------
                       SAMPLE RECOVERY DATA
         yv<
        Sample Box No.   —      Job No.
PLANT

DATE    .._	

SAMPLE LOCATION

TRAIN PREPARER	

SAMPLE RECOVERY PERSON

COMMENTS          fry*-*  iUt  At,*,) £'*«  ^
FRONT HALF
Acetone
Container No.     <

Filter
Container No.

Description of Filter
                               Run No.
                                                            007
                                             Filter No.   JO)
                                                  O~
             Liquid
             Level Marked
                                              Sealed
                                              Sealed
                                          fe
Samples Stored and Locked

BACK HALF/MOISTURE
Container No.
Liquid Level Marked
                               Sealed
   IMP. NO.
CONTENTS
                          INITIAL VOL
                           .  (ml)
                                                 WEIGHT (grams)
                                       INITIAL
                                     FINAL
                                                                 NET
                          100
                       710.0
                                                  776.0
                           too
                                               //.
                                                      . X.
                                                2.7
                           100
                                                O.H
                           loo
                                  730.3
          TOTAL
                                  A J
-------
PES, /nc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
«f\AkC~ tt*m u_Tt>Aj
Relinquished by: (Signature)
Relinquished by: (Signature)
^^/&Wt/~
RclinquUhedby:(Signalure)
^^^Jfc^?j(lt+*fo*^---
— ^^^£<*W>v(*4 ' ^«^*^»*»»"~»-«
ftLA*stt- m&frT>eMs. i>€*>
Field Sample
No.
l-M29-1-Filter
I-M29-1-FHAC8
I-M29-1-FHAR
I-M29-1-H2O2
I-M29-1-BHAH
I-M29-1-KMN04
I-M29-1-HCL
l-M29-2-Fflter
Dale
0/J1/97
9/J9L/97
9/i/97
9/.J/97
9/.S1/97
9/.J/97
ei$JB7
oilQjai
Date/Tune
Dale/Time
Date/Time
w*b?
i&fo
Dale/Time
?MT/
wr
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
^ U^^r
Received by^Sjgnaturc)
FZAijK. /Y\£»bOuJS - !>£*,
Received by: (Signature)
^^((,^1^2^
Analysis Required
EPA Method 5/ EPA Method 29
EPA Method S/ EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 51 EPA Method 29
Sampling Train
Particulate/MMUs
Particulate/MMtts
MMtls
MMUs
MMtls
MMUs
MMtls
•
Particulate/MMUs
i
Dale/Time
Date/Time
l(fr(f?-
I
Date/Time
y/^f? 1000
Date/Time
4fafa
*>%{*
Sample Description
4- Quartz Filter
Front Half
Acetone Rinse
Front Hall Acid Rinse
0.1NHNO3
5% HNO3 / 10% H2O2
Imping er-f Rinse
Blank Imp. Acid Rinse
0.1NHN03
4% KMnO4/10% H2S
Impinger+Rinse
8NHCI
4* Quartz Filter

Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
^t tf iY}^ *? ^ fAMto-ce^s.-

Comments
V // **-* f Ct ,3.A+wa£C'i-^

Comment! f
4(1 mz*( F~*£v%r a—/
f^ff Au^-r** /LLu^A^~
1 II fT*Jf*l*nv* '+*' ** w m*^~
Cammenti
Special Notes
M 29 Container #1
M 29 Container *2
. s~oo ^
M 29 Container f 3
M 29 Container #4
M 29 Container #5A
M 29 Container #5B
M 29 Container #5C
M 29 Container f\
tab
TU
TU
TU
TU
TU
TU
1
TU
TU
-------
PES, Inc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
l-M29-2-FHAce
I-M29-2-FHAH
(-M29-2-H2O2
I-M29-2-BHAR
I-M29-2-KMNO4
I-M29-2-HCL
I-M29-3- Filter
l-M29-3-FHAce
Date
9/^97
OIJ6J91
9,^7
9//JJ/97
9/UU97
9/1&JS7
9/I&JB7
9/10/97
Date/Time
Dale/Time
Date/Time
Date/Time
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method S/ EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method S/ EPA Method 29
EPA Method S/ EPA Method 29
Sampling Train
Particulale/MMUs
MMtls
MMUs
MMtls
MMtls
MMtls
Paruculate/MMfls
Particulate/MMUs
Date/Time
Date/Time
Date/Time
Date/Time
Sample Description
Front Hall
Acetone Rinse
Front Hall Acid Rinse
0.1NHNO3
5% HNO3 / 10% H2O2
Impinger* Rinse
Blank Imp. Acid Rinse
0.1NHNO3
4K KMn04/10% H2S
Impinger-f Rinse
8NHCI
4* Quartz filter
Front Hall
Acetone Rinse

Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container #2
500 nJL
M 29 Container #3
M 29 Container #A
M 29 Container #5A
M 29 Container *5B
M 29 Container * 5C
M 29 Container *t
M 29 Container *2
Lab
TU
TU
TU
TU
TU
TU
1
TU
TU
-------
PES, Inc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
I-M29-3-FHAR
I-M29-3-H202
I-M29-3-BHAR
l-M29-3-KMnO4
I-M29-3-HCL
l-M29-BLK-Filter
l-M29-BLK-FHAce
I-M28-BLK-FHAH
Date
aHtj/97
9//0/97
9110 107
9//H/97
BIJQJ97
°ldtf"
9//0/97
91 1 0/67
Date/Time
Dale/Time
Date/Time
Date/Time
Composite
or Crab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method S/ EPA Method 29
EPA Method S/ EPA Method 29
EPA Method 29
Sampling Train
MMUs
MMUs
MMUs
MMUs
MMUs
Particulate/MMtls
Field Blank
porticulate/MMUs
Field Blank
MMUs
Reid Blank


Date/Time
Dale/Time
Date/Time
Date /Time
Sample Description
Front Hall Acid Rinse
0.1NHNO3
5% HNO3 / 10% H2O2
Impinger+Rinse
Blank Imp. Add Rinse
0.1NHNO3
4% KMnO4/10% H2S
Impinger+Rinse
8NHCI
4' Quartz Filter
Front Half
Acetone Rinse
Front Half Add Rinse
0.1NHNO3
Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container *3
M 29 Container #4
M 29 Container #5A
M 29 Container *SB
M 29 Container #5C
M 29 Container *1
M 29 Container *2
M 29 Container #3
Lab
TU
TU
TU
TU
TU
TU
TU
TU
-------
PES, /nc
4700 Duko Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by. (Signature)
Field Sample
No.
I-M29-BLK-H2O2
I-M29-BLK-BHAR
l-M29-BLK-KMnO4
I-M29-BLK-HCL
'
'
'

Dale
9/1L/97
9//0/9T
B//ft/97
9//£/97
*
'
1
'
Date/Time
Date/Time
Date/Time
Date/Time
Composite
or Grab
Composite
Composite
Composite
Composite
*
1
1
'
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
,
.
'
i
Sampling Train
MMds
Reid Blank
MMUs
Reid Blank
MMds
Reid Blank
MMds
Reid Blank
,
1
i
•
Date/Time
Dale/Time
Date/Time
Dale/Time
Sample Description
5% HNO3 / 10% H2O2
lmpinger+ Rinse
Blank Imp. Acid Rinse
0.1NHNO3
4% KMn04/tO% H2S
Imping er-f Rinse
BNHCI
,
,
,
p

Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container #4
M 29 Container *5A
M 29 Container KB
M 29 Container *5C

,
,
.
Lab
TU
TU
1
TU
TU
1
,
1
1
1
01
-------
PES, Inc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
Relinquished by. (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
O-M29-1-Filter
O-M29-1-FHAce
O-M29-1-FHAR
O-M29-1-H202
O-M29-1-BHAH
0-M29-1-KMN04
O-M29-1-HCL
O-M29-2-Filt«r

Dale
9/JL/97
9/i/97
9/_i/97
9/JL/97
9/.1/97
9/_lf97
9/_i»7
8/^/97
Date/Time
Date/Time
Date/Time
Date/rime
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method S/ EPA Method 29
EPA Method 5/ EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 51 EPA Method 29
>
Sampling Train
Porticulate/MMUs
Pcuticulate/MMtis
MMUs
MMds
MMtts
MMUs
MMtfs
Particulate/MMBs
Dale/Time
Date/Time
Date /Time
Date/Time
Sample Description
3" Quartz Filter
Front Half
Acetone Rinse
Front Hall Acid Rinse
0.1NHNO3
5% HN03 / 10% H2O2
lmpinger+ Rinse
Blank Imp. Acid Rinse
0.1NHN03
4% KMn04/10% H2S
lmpinger+ Rinse
8NHCI
1
3' Quartz Filter

Date;
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container #1
M 29 Container #2
/V:T nJ.
M 29 Container #3
M 29 Container #4
M 29 Container *5A
M 29 Container #5B
M 29 Container #5C
M 29 Container ft
Lab
TU
TU
TU
TU
1
TU
TU
TU
TU
1
CD
-------
PES, fnc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquhhed by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
O-M29-2-FHAce
O-M2O-2-FHAR
O-M29-2-H2O2
O-M20-2-BHAR
O-M29-2-KMNO4
O-M29-2-HCL
O-M29-3-Fl!l«f
O-M29-3-FHAC*
Dale
O/^fi/97
OIISJ97
eilQjaj
9//ft/97
OIJSJB7
9/jt>/97
B//J&V97
a/lH/97
Dale/Time
Date/Time
Date/Time
Date/Time
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method S/ EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method S/ EPA Method 29
EPA Method SI EPA Method 29
Sampling Train
Parti cuIale/MMtis
MMUs
MMUs
MMUs
MMds
MMUs
Partculate/MMUs
Particulate/MMUs
Date/Time
Date/Time
Date/Time
Date/Time
Sample Description
Front Hall
Acetone Rinse
Front Half Acid Rinse
0.1NHNO3
S% HNO3 / 10% H2O2
Impinger+Rinse
Blank Imp. Acid Rinse
0.1N HNO3
4% KMnO4/10% H2S
Impinger+Rinse
8NHCI
3' Quartz Filter
Front Half
Acetone Rinse

Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container *2
ivo »JL
M 29 Container *3
M 29 Container #4
M 29 Container #5A
M 29 Container *5B
M 29 Container #SC
M 29 Container #1
M 29 Container «2
1 SO "A-
Lab
TU
TU
TU
TU
TU
1
TU
TU
TU
-I
-------
PES, /nc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquif bed by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
O-M29-3-FHAR
O-M29-3-H2O2
O-M29-3-BHAH
O-M29-3-KMn04
O-M29-3-HCL
O-M29-BLK-Rltar
O-M29-BLK-FHACB
0-M29-BLK-FHAR
Dale
8/1Q/97
BIIHJ97
9//»/97
9/^/97
9/JC/97
9ltSU*7
aiftja?
9//£/97
Dale/Time
Date/Time
Date/Time
Dale/Time
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method S/ EPA Method 29
EPA Method S/ EPA Method 29
EPA Method 29
Sampling Train
MMUs
MMds
MMUs
MMds
MMds
Particulate/MMUs
Held Bank
Particulate/MMtls
Reid Blank
MMUs
Held Blank
Dale/Time
Date/Time
Date/Time
Date/Time
Sample Description
Front Half Acid Rinse
0.1N HNO3
5% HNO3 / 10% H2O2
lmpinger+ Rinse
Blank Imp. Acid Rinse
0.1NHNO3
4% KMnCM/10% H2S
Impinger-i Rinse
8NHCI
3- Quartz Filter
Front Half
Acetone Rinse
Front Half Acid Rinse
0.1NHNO3

Date;
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
i
Comments
Special Notes
M 29 Container *3
M 29 Container *4
M 29 Container *5A
M 29 Container *5B
M 29 Container *SC
M 29 Container *1
M 29 Container #2
• £0 nJi
M 29 Container *3
Lab
TU
TU
TU
1
TU
TU
TU
1
TU
TU
-------
PES, Inc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca Foundry Plant Location: Tell City, Indiana
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
0-M29-BLK-H2O2
O-M29-BLK-BHAR
0-M29-BLK-KMnCM
O-M29-BLK-HCL
1
'
'
'
Date
9//O/97
9//a_/97
9/&L/97
9//gy97
*
1
*
'
Date/Time
Date/Time
Date/Time
Date/Time
Composite
or Crab
Composite
Composite
Composite
Composite
'
'
*
'
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
1
:
,
:
Sampling Train
MMUs
Held Blank
MMHs
Field Blank
MMfls
Reid Blank
MMUs
Field Blank
.
,
,
•


Date/Time
Date/Time
Dale/Time
Date/Time
Sample Description
5% HN03 / 10% H2O2
Impinger-f Rinse
Blank Imp. Acid Rinse
0.1NHNO3
4% KMnO4/10% H2S
Impinger+Rinse
8NHCI
,
,
,
'
Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl M5)
Project Name: S 414.003
Comments
Comments
Comment*
Comments
Special Notei
M 29 Container iM
M 29 Container #5A
M 29 Container #5B
M 29 Container *5C
1
f
,
1
Lab
TU
TU
TU
TU
1
,
*
I
1
CD
-------
PES, /nc
4700 Duko Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: Waupaca foundry Plant Location: Tell City, Indiana
Relinquished by. (Signature)
Relinquished by. (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
M29-Heagent Btonk-4' Filler
M29-Reagent Blank-3' Filter
M29-Reagent Blank-Acetone
M29-Reagent Blank-HNO3/H2O2
M29-Reagent Blank-O.IN HNO3
M29-Reagent Blank-KMnO4/H2SO4
M28-Reagent Blank-aN HCL
M29-Reagent Bank-DI H2O
Date
9//Q/97
9//0/97
9/./b/87
9IIQJ97
alto/a?
aiJCtfti
9//ff/97
9//&/B7
Date/Time
Date/Time
Date/Time
Date/Time
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by. (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method S/ EPA Method 29
EPA Method S/ EPA Method 29
EPA Method S/ EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
Sampling Train
Particulate/MMtts
Reagent Blank
Partculata/MMBs
Reagent Blank
Porticulate/MMBs
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
Date/Time
Date/Time
Dale/lime
Date/Time
Sample Description
4* Quartz Filter
3* Quartz alter
100 ml Acetone
250 ml 5% HNO
10% H202
160ml0.1NHNO3
500 ml 4% KMnO
10% H2SO4
100 ml 8N HO
330 ml 01 Water

Date:
Lab:
Train:
9/12/97
Triangle Labs
Method 29 (Incl MS)
Project Name: S 414.003
Comments
Comments
Comments
Comments
Special Notes
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                                            -.oo.jj.ic seals: Absent
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   ........• vi custody  :  Present
   Sample Tags        i  Absent
   Sample Tag Numbers:  Not Listed on Chain of Custody
   SHO  Forma          :  N/A
                                                    TLI Project Number   43231
                                                    Client; PES03  -  Pacific  Environmental Services

                                                                                                /
                                                         I  Book
                                                    Date Received
                    j 09/12/97   | By,
   Ice Chest
                                     ICE
Temp   5.0 C
Carrier and Number  \ MICHAEL MILBORNE

DTLI Number Client Sample ID. 	 , 	 Matrix) To LAB
QmR/H:CPM 	 Client COC ID 	 * Location 	 | Date/Init
01
	 	 — I
IJ183-3-1A I-M29-FHAC6 ACETONE RNS|
|| I-M29-BLK * METALS LAB j
»i
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\\lB3-3-lB I-M29-FHAR .IN HNO3 1
fl I-M2'9-BLK * METALS LAB j
n i
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||!83-3-lC I-M29-BLK-S% 10* KN03/H202J
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»|
1
D183-3-1D I-M29-BLK-BHAR .IN HNO3 1
1) I-M29-BLK * METALS LAB j
II 1
U 1
U183-3-1E I-M29-BLK-KMN04 KMn04 |
0 I-M29-BLK * METALS LAB |
II 1
II 1
1)183-3- IF I-M29-BLK-HCL SN KC1 1
j) I-M29-BLK • METALS LAB j
0 - ------ j
B1B3-3-2A I-M29-1-FHAC6 ACETONE RNS|
1) I-M29-1 * METAiS LAB j
[ ' 1
||lfl3-3-2B I-M29-1-FHAR .IN KN03 (
|| I-M29-1 « METALS LAB j
1 1
l|l83-3-2C I-M29-1-5V lot HN03/H202)
|| I-M29-1 * METALS LAB. j
II 1
1) 1
IJ183-3-2D I-M29-1-BHAR .1NHNO3|
|| I-M29-1 * METALS LAB j
II 1
|)l83-3-2B I-M29-1-KMN04 KMn04|
0 I-M29-1 • METALS LAB |
Bj
1
J1B3-3-2F I-M29-1-HCL 8N HC1 1
|| . I-M29-1 * METALS LAB |
II ..--... j
Q183-3-3A I-M29-2-FHAce ACETONE RNS|
B I-M29-2 * METALS LAB j
5 	 j
||l83-3-3B I-M29-2-FHAR '.IN HN03 1
|| I-M29-2 * METALS LAB |

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I)                      OTHER BLANKS.
I)  Archive Remarks:
11 " • ' •	         '        •'   .       '   Form Revised 05/27/1997 --  Page  1 OF  4  .   •-
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fl Chain of Custody : Present Container. . . : Intact
Q Sample Tags : Absent
B Sample Tag Numbers: Not Listed on Chain of Custody
fl SMO Forms : N/A
TLI Project Number 43231 | Book fl
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(183-3-3C I-M29-2-5* 10% HNO3/H2O2J
1 I-M29-2 * METALS LAB j
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0 1
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| I-M29-3 * METALS LAB |
B 1
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0 O-M29-BLK * METALS LAB j
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[183-3-5C 0-M29-BLK-5* 10% 'HN03/H2O2J
1 O-M29-BLK * METALS LAB |
B 1
J1B3-3-5D 0-M29-BLK-BHAR .IN HN03J
1 0-M29-BLK * METALS LAB j
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I                      THE SAMPLES FOR INLET (FHAce and FHAR) AND OUTLET (FHAce and FHAR) BLANKS HERB NOT MARKED BLK AS
0                      OTHER BLANKS.
|  Archive Remarks:
r                    '••	—	'	      •"     '  • 'Form Revised 05/27/1997 •• Page 2 OP 4	   .
    oo
-------
                                                                   u
|| Custody Seal :
|| Chain of Custody :
|| Sample Tags :
fl SMO Forms • :
Q Ice Chest
Absent
Present
Absent
N/A

Sample Seals: Absent
Container...: Intact

ICE Temp 5.0 C
TLI Project Number 43231
Client: PES03 - Pacific Environmenta.1 Services
Date Received j 09/12/97 j By ${$£# ' $%£
Carrier and Number j MICHAEL MILBORNB '
1 Book I)
1 B
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0 0-M29-BLK * METALS LAB
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01B3-3-5F 0-M29-BLK-HCL 8N HC1
fl 0-M29-BLK • METALS LAB
- 	 	 . ,_..,,. —
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|| O-M29-RUN1 • METALS LAB
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IJ183-3-6B 0-M29-1-FHAR .IN HN03
|| O-M29-RUN1 * METALS LAB
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B183-3-6C 0-M29-l-5% 10% HN03/H202
0 0-M29-RUN1 • METALS LAB
n
fllB3-3-6D O-M29-1-BHAR , .IN HNO3
II O-M29-RUN1 * METALS LAB
n
D1B3-3-6E O-M29-1-KMN04 KMH04
II O-M29-RUN1 * METALS LAB
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U183-3-6F O-M29-1-HCL BN HC1
B O-M29-RUN1 * METALS LAB*
n
fl!83-3-7A O-M29-2-FHACB ACETONE RNS
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||l83-3-7C O-M29-2-5% 10% HN03/H202
1) O-M29-RUN2 • METALS LAB
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R183-3-7D 0-M29-2-BHAR .IN HN03
D O-M29-RUN2 • METALS LAB
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J183-3-7B 0-M29-2-KMN04 XMn04
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                    THE SAMPLES FOR INLET (PHAce  and FHAR) AND OUTLET  (FHAce and FHAR) BLANKS HERE NOT MARKED BLK AS
                    OTHER BLANKS.
Archive Remarks:
                                                            =Form Revised 05/27/1997 -• Page 3 OF 4  i
    (XT
    CO
-------
                                               =TRIANGLE LABORATORIES, INC. --
  IJ   /
LOG IN RECORD/CHAIN OF CUSTODY'
(I Custody Seal : Absent Sample Seals: Absent
0 Chain of Custody : Present Container...: Intact
|| Sample Tags : Absent
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|| SMO Forms : N/A
TLI Project Number 43231 I Book U
Client: PES03 - Pacific Environmental Services | ,8
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|| Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Absent Container...: Intact
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B Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
TLI Project Number 43243 Book |j ;
Client: PES03 - Pacific Environmental Services 0
183 D
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Date Received | 09/15/97 | By/i/Wy*77^^*7/^xT>a3e || „
0 ••• 	 ••••' — ••• ' ' " I/ 5
|| Box NO COOLANT Carrier and Number | BILL DEWEE 15 0
||TLI Number 	 Client Sample ID 	 Matrix
||mR/H:CPM. 	 Client COC ID 	 * Location 	

H183-1S-1A Reagent Blank ACETONE RNS
|| METALS LAB
||1B3-15-1B Reagent Blank .IN HN03
|| METALS LAB
||1B3-15-1C Reagent Blank DI HATER
|| METALS LAB
||183-15-1D Reagent' Blank HNO3/H2O2
|| * METALS LAB
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0                      TLI843231.
\.  Archive Remarks:
                                                               =Form Revised 05/27/1997  --  Page  1 OF 1-
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                                                             LABORATORIES, me. -- LiOU IN Rfci-uicu/CHAI..  or CUSTuui=
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TLI Project Number 43350 , | Book |
Client: PES01 - Pacific Environmentals Serv. Inc. | fl
1 1 «4,fl
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Date Received j 09/23/97 | By <0fa&/yS~lS~}/rt***** '
U Box NO COOLANT Carrier and Number | FRANK MEADOWS | 23 ''fl
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jjmR/H:CPM. ' 	 Client COC ID 	 * Location 	 j Date/Init
II 1
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|| I-M29-1 METALS LAB j
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1)184-23-18 I-M29-1 FH Acetone Rinse)
U I-M29-1 METALS LAB j
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I) I-M29-2 METALS LAB j
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|| I-M29-3 METALS LAB j
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||!84-23-4A I-M29-FIELD BLANK Filter)
|| I-M29-FIELD BLANK METALS LAB j
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1)184-23-48 I-M29-FIELD BLANK FH Acetone Rinse)
0 I-M29-FIELD BLANK METALS LAB j
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                                                              •Form Revised  05/27/1997 --  Page 1 OF 2=
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Date Received |
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09/23/97
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|| O-M29-3 METALS LAB
||lB4-23-9A 0-M29-FIELD BLANK Filter
U O-M29-FIELD BLANK METALS LAB
0184-23-9B O-M29-FIELD BLANK FH Acetone Rinse
|| 0-M29-FIELD BLANK METALS LAB
,
||lB4-23-10A' 0-M29-REAGENT BLANK Filter
I) 0-M29-REAGBNT BLANK METALS LAB
IJ184-23-10B 0-M29-REAGENT BLANK FH Acetone Rinse
U 0-M29-REAGENT BLANK METALS LAB
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                                                              =Form Revised OS/27/1997  --  Page 2 OF 2«
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Prolecl II ^ S^),^ /
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Client Run/1 xiP - /7l-J?
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                                                                      Initials:	
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Client:
Date/lnt.:
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Analyles '
ICP - GFAA FI.AA CVAA
Triangle Laboratories of RTP
C91 91544-5729
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-------
                                                                                                     Anolyles
                                                                                          ICP
                                                                                                    CV,
3llenl:____PBS03
3ate/lnt.:
      Runll
                              Triangle Laboratories  of RTP
                                            (919)544-5729
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I & DM Posl dig. spk.
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Allquol A:  n  ml
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-------
                                                                                                     Analyles '
                                                                                          ICP  • GFAA   FLAA  CVAA
-llenl: Pdfj&, fo

Dote/lnt.: Ocfo^r    /W
                           Triangle  Laboratories of RTP
                                         (919)544-5729
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                                                                                                    CQNVH
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                        Reduce
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                                        \ label	
                                        i
                                        i
                                        i Volume
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               Allauol D: _^	mL
                                                                Inl

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                          FH & DM Serial dilution performed

                          __•	ml lo	ml FV •«•	uL Sc

                          Inlllals:	

                            nlr»'
-------
Project II H -^ 3
Client: KGS&3
Date/lnt.: JU^T/^
Client Run// ^0 - M-

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ICP - GPAA FLAA CVAA
Triangle Laboratories of RTP
(919)544-5729
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-------
Project „_
Client:
                                                              Anolyles  '
                                                     ICP ' &FAA   FLAA  CVAA
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Client Run,,
              Triangle Laboratories of RTP
                        (919)544-5729
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-------
Project I/.

Client:
                    ICP
                                                                       ' ncily '
                                                                 GFAA   FI.AA  CVAA
3ote/lnt.:
 :ilerit Runll
           riangle Laboratories  of RTP
                       (919)544-5729
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                                                   100 mis
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                          FH.& DH Serial dilution performed

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                          Initials:
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                            (Mo
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post digest spike on FH lor GFAA))

t & DH Post dig. spk.

      Lppb Onslrumenl spiked)
-------
Anolyles
Project It
Client:
Dote/lnt.
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Client Run// X^MA^'S

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-------
                                                                                               ICP  - GFAA   FLA/A  CVAA
X"
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Date/lnt.: '
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^ (919)544-5729



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-------
        •'•
Ancilyles
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Initials: '
• i »*-*! •-*•
-------
Project //.

Client:
                                                                                                     irjlyf
                                                                                        ICP • GPAA   FLAA  GVAA
Date/lnt.:
Client Run//
            Triangle Laboratories of RTP
                         (919)544-5729
                                                                    l-lg Implnger's |
                                                                       CONT ft
                                             CONT //
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                                                                   Volume 9 9^

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                                                                               Volume	I ' ml

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FH & DM Serial dilution performed

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Initials:
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    CD
    Qrjppb (Instrument spiked)
-------
Project

Cllenl:
                                                                                            Anal yles  '
                                                                                 ICP  • GFAA    FLAA  CVAA
Dale/lnt.:
                               Triangle Laboratories of RTP
                                            (919)544-5729
Client Run//
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                              J	,

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                          FH & DH Serial dllullon performed

                            .   ml lo	ml FV +	uL Sc

                          Initials:;	,

                          I nr-.io-
-------
'rojecl
                                                                                                       rjlyl
                                                                                         ICP  - GPAA   FI.AA  CVAA
Xrte/lnt.:
:ilent Runff
                                        Triangle Laboratories of RTP
                                                     (919)544-5729
                      CONTII
                        ©
                                                              CONf //
                                                                    I Hg Implngers |'

                                                          CONT/I.       CONT//        • CONT«
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-------
Project 11.

Client:
                                                              Anolyles  '
                                                     ICP - GFAA   FI.AA  CVAA
Date/lnt.:
              Triangle Laboratories of RTP
                        (919)544-5729
Silent Run//
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CONT

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Aliquot 0: j   ml
-------
'rojecr //.



:ilent:
ICP
                                                                               Anolyles '

                                                                           GPAA  PI.AA CVAA
)ate/lnt.:_
                               Triangle Laboratories of RTP

                                          (919)544-5729
;ilent Run//
            0"
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  ©
                                                                   CONU.
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-------
3roject «.

:ilenl:
                                                                                                     •  cjlyl"  '
                                                                                         ICP  • GfAA   TI.AA  C_yAA_
3ale/lnt.:
:ientRunl
Triangle Laboratories of  RTP
             (919)544-5729
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                        ©
                                                       |l-lg Implngers I
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-------
Analyles
3roject II
Client:
Date/In*.:



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Inlllals:
•% I-
-------
                                                             PAGE
                        INORGANICS SPIKE LOG
. DATE
PROJECT #

SAMPLE IDs
ANALYTE
                                     ORIGINAL
                                    STANDARD
ORIGINAL
STANDARD
 CONC.
 (PPM)
                                                      SPIKE
                                                      SAMPLE
                                                       (HL)
 FINAL
VOLUME
 (mL)
 SPIKE
SAMPLE
 (PPB)
INITIALS
WITNESS
                                   3-QB-3
                                    3-6 «-
                                          jTff
                                                               JLE
                                                                     JQS

               -(£5
                                                        fls/f
                                                              lose
   qa\forms\inospke.log (08/22/96)
                                                                              106
-------
                                                           PAGE
                       INORGANICS SPIKE LOG
- DATE
PROJECT #

SAMPLE IDs
ANALYTE
ORIGINAL
STANDARD
   #
ORIGINAL
STANDARD
 CONC.
 (PPM)
                                                    SPIKE
                                                    SAMPLE
 FINAL
VOLUME
 (mL)
 SPIKE
SAMPLE
 (PPB)
INITIALS
                                                                        WITNESS
                                  3-013-3
                                                           •-
                                                             M£-
                                  3-6 «-
                                        (SE.
                                                            JL6
                                                                  JQS

                                                                         s;
                                   3-OB-3
                                                      Gs/f
                                            lafa
                                                               /
                                  5-0)3-3
                                •X-

                                                                        *
                                                                        5F
                          P
                                 1066
                                  1000
   qa\forms\inospke.log (08/22/96)
                                                    10
-------
                                                  TCI jfc.
        * SEE SPIKE LOG
EXPdate

 2/1/98
 9/1/98
 2/1/98
 9/1/98
 2/1/98
 2/1/98
 9/1/98
'9/1/88
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 2/1/98
 9/1/98
 9/1/98
 8/1/98
 9/1/98
 9/1/98
 2/1/98
 8/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 8/1/98
Spiking Standard Preparation
Element Standard Orig. Std. Spike(uL) cone
ID ' (ppm)
19
\a
kl
0
J
fe
ia
5a
;a
:d
:o
:r
:u
:e
:e
t
t
wig
^9
An
do
Ja
la
«
»b
»b
8
n
n

n
n
2-115-4
3410-10
2-115-4
3-010-7
2-tlM
2-115-4
3410-10
3410-10
3412-7
3410-10
3410-10
3410-10
3410-10
3410-10
3-012-6
2-115-4
3412-5
341O-10
34104
3410-tO
3410-10
2-115-4
3410-9
3410-10
3410-10
3410-10
3410-10
3410-10
3410-10
3410-10
3410-10
3410-6
1000uL at OIB Spiking .
100
100
100
10000
100
100
100
100
10000
100
100
100
100
100
10000
1000
10000
100
10000
100
100
too
10000
too
too
100
too
too
too
too
100
1000
Fvd(100mL) (ppm)
5000
5000
5000
950
5000
5000
5000
5000
950
5000
5000
5000
5000
5000
9SO
5000
1500
5000
950
5000
5000
5000
1950
5000
5000
5000
5000
5000
5000
5000
5000
1500
5
S
5
95
S
S
5
5
95
S
5
S
5
5
95
50
150
5
95
S
S
S
195
5
5
S
5
S
S
S
5
IS
SPIKING
'ram Spiking Standard
Spiteful) cone
=Vd(tOOml)
1000
1000
1000
1000
1000
tooo
1000
1000
1000
1000
tooo
tooo
1000
1000
1000
. 1000
1000
1000
tooo
1000
1000
1000
1000
1000
tooo
tooo
tooo
1000
1000
1000
tooo
tooo
(ppb)
50
so
so
950
50
50
so
50
950
50
50
50
50
50
950
500
1500
50
950
50
50
SO
1950
50
50
50
SO
50
SO
50
50
ISO
combined
total



1000

1000

1000
2000
1000

2000

200
tandard gives the listed con'c. of me above elements.
••Spike separately
Bement  Orig Std
           (ppm)
Splke(uL)     cone
Fvol(100m    (ppb)
Au
Ca
U
P
Pd
Pt
S
Si
Sn
Sr
1000
1000
1000
tooo
tooo
1000
1000
10000
1000
tooo
140
30
70
100
160
300
350
350
20
S
1400
300
700
1000
1600
3000
3500
35000
200
SO
        Spiking Standard 3-013-3
        EXP: 11/26/97
        Spiked by:
        PredigesSon-

        Postdigestion-
                                                                                                           108
-------
         * SEE SPIKE LOG
EXPdate

 2/1/98
 9/1/98
 2/1/98
 9/1/98
 2/1/98
 2/1/98
 9/1/98
-"9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 2/1/98
 9/1/98
 9/1/98
 8/1/98
 9/1/98
 9/1/98
 2/1/98
 8/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 8/1/98
         Spiking Standard Preparation

3ement    Standard  Orig.Std.  SpikeKuL)       cone
             ID    •" (ppm)   Fvol(IOQmL)  ' (ppm)
jd '
:o •'••
tg
                                                 SPIKING
                                                 'ram Spiking Standard
                                                 5piKe(uL)       cone   combined
                                                                        total
n -•••...-.•;»•-••
           2-115-4
           3410-7
           2-115-4
          £2-115-4
          3-010-10
          3410-10
           3-012-7
          3410-10
          3-010-10
          3-010-10
          3-010-10.
          3-01 CM 
-------
                                                              PAGE 1 OF 3
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 43231
Transfer From: IWLM

Released by:
Accepted by:


MILES ID 	
43231- -000
43231- -001
43231- -002
43231- -003
43231- -004
43231- -005
43231- -006
43231- -007
43231- -008
43231- -009
43231- -010
43231- -Oil
43231- -012
43231- -013
43231- -014
43231- -015
43231- -016
43231- -017
43231- -018
43231- -019
43231- -020
43231- -021
43231- -022
43231- -023
43231- -024
43231- -025
43231- -026
43231- -027
43231- -028
43231- -029
Initials'; .

W&k


TLI No 	
TLI Blank
183-3-2B
183-3-2C
183-3-2D
183-3-2E
183-3-2F
184-23-1A
184-23-1B
183-3-3B
183-3-3C
183-3-3D
183-3-3E
183-3-3F
184-23-2A
184-23-2B
183-3-4B
183-3-4C
183-3-4D
183-3-4E
183-3-4F
184-23-3A
184-23-3B
183-3-1B
183-3-1C
183-3-1D
183-3-1E
183-3-1F
184-23-4A
184-23-4B
183-3-6B
To: IA I
Date 	 Time . . .

1 /^rftl Jf^^T


Gust .Id 	
TLI Method Blank
I-M29-1-FHAR
I-M29-l-5% 10%
I-M29-1-BHAR
I-M29-1-KMN04
I-M29-1-HCL
I-M29-1
I-M29-1
I-M29-2-FHAR
I-M29-2-5% 10%
I-M29-2-BHAR
I-M29-2-KMN04
I-M29-2-HCL
I-M29-2
I-M29-2
I-M29-3-FHAR
I-M29-3-5% 10%
I-M29-3-BHAR
I-M29-3-KMN04
I-M29-3-HCL
I-M29-3
I-M29-3
I-M29-FHAR
I-M29-BLK-5% 10%
I-M29-BLK-BHAR
I-M29-BLK-KMNO4
I-M29-BLK-HCL
I-M29-FIELD BLANK
I-M29-FIELD BLANK
O-M29-1-FHAR
	 Xf-rCOC (Rev 11/01/94)-- +
Additional  comments or instructions:
                                                               110
-------
                                                              PAGE 2  OF 3
h 	 	 1
TRIANGLE LABORATORIES, INC. '
Transfer Chain-of-Custody Form
Project 43231
Transfer From: IWLM

Released by:
Accepted by:


MILES. ID 	
43231- -030
43231- -031
43231- -032
43231- -033
43231- -034
43231- -035
43231- -037
43231- -038
43231- -039
43231- -040
43231- -041
43231- -042
43231- -043
43231- -044
43231- -045
43231- -046
43231- -047
43231- -048
43231- -049
43231- -050
43231- -051
43231- -052
43231- -053
43231- -054
43231- -055
43231- -056
43231- -057
43231- -058
43231- -059
43231- -060
Initials . .

MU\


TLI No 	
183-3-6C
183-3-6D
183-3-6E
183-3-6F
184-23-6A
184-23-6B
183-3-7B
183-3-7C
183-3-7D
183-3-7E
183-3-7F
184-23-7A
184-23-7B
183-3-8B
183-3-8C
183-3-8D
183-3-8E
183-3-8F
184-23-8A
184-23-8B
183-3-5B
183-3-5C
183-3-5D
183-3-5E
183-3-5F
184-23-9A
184-23-9B
183-15-1B
183-15-1C
183-15-1D
To: IA I
Date 	 Time . . .
Q cv £n -» ~\ f\
1 / c%~«. / 1 [ I i ^\_.x
\ltel<*r\ 1^:^


Gust. Id 	
0-M29-l-5% 10%
O-M29-1-BHAR
O-M29-1-KMN04
O-M29-1-HCL
O-M29-1
O-M29-1
0-M29-2-FHAR
0-M29-2-5% 10%
O-M29-2-BHAR
O-M29-2-KMN04
O-M29-2-HCL
O-M29-2
O-M29-2
0-M29-3-FHAR
O-M29-3-5% 10%
O-M29-3-BHAR
0-M29-3-KMN04
O-M29-3-HCL
O-M29-3
O-M29-3
O-M29-FHAR
0-M29-BLK-5% 10%
O-M29-BLK-BHAR
O-M29-BLK-KMN04
O-M29-BLK-HCL
0-M29-FIELD BLANK
O-M29-FIELD BLANK
Reagent Blank
Reagent Blank
Reagent Blank
	 Yfr-rOC (Rev 11/01/94)---
Additional  comments or instructions:
                                                              111
-------
                                                                   PAGE 3 OF 3
                         	+
                          TRIANGLE LABORATORIES, INC.
                         Transfer Chain-of-Custody Form
                                 Project 43231
                      Transfer  From: IWLM
               Accepted by:       Wft      *\ / TVf °C1    ^%  4T
           MILES .ID	  TLI No	  Cust. Id.
           43231-   -061     183-15-1E     Reagent Blank
           43231-   -062     184-23-5      I-M29-REAGENT BLANK
           43231-   -063     184-23-10A    O-M29-REAGENT BLANK
           43231-   -064     184-23-10B    0-M29-REAGENT BLANK
           43231-   -065     LCS           Lab Control Spike
., 				__	XfrCOC (Rev 11/01/94}-- +
  Additional comments or instructions:
                                                                    11:
-------
                                                                PAGE 1 OF 3
                        TRIANGLE LABORATORIES, INC.
                       Transfer Chain-of-Custody Form
                               Project 43231
Transfer  From: IWL
                                             To: IA I
Relea
Accej

MILES ID
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-

ised by
>ted by


-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
-012
-013
-014
-015
-016
-017
-018
-019
-020
-021
-022
-023
-024
-025
-026
-027
-028
-029

^**^IM..*.
-------
                                                              PAGE 2 OF 3
1 	 r
TRIANGLE LABORATORIES, INC.
Transfer Chain- of -Custody Form


Project
Transfer From: IWL


Released by:
. Initials . .

Accepted by: o£O

MILES ID
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-
43231-


-030
-031
-032
-033
-034
-035
-037
-038
-039
-040
-041
-042
-043
-044
-045
-046
-047
-048
-049
-050
-051
-052
-053
-054
-055
-056
-057
-058
-059
-060

TLI No 	
183-3-6C
183-3-6D
183-3-6E
183-3-6F
184-23-6A
184-23-6B
183-3-7B
183-3-7C
183-3-7D
183-3-7E
183-3-7F
184-23-7A
184-23-7B
183-3-8B
183-3-8C
183-3-8D
183-3-8E
183-3-8F
184-23-8A
184-23-8B
183-3-5B
183-3-5C
183-3-5D
183-3-5E
183-3-5F -
184-23-9A
184-23-9B
183-15-1B
183-15-1C
183-15-1D
43231
To: IA I
Date 	 Time . . .
J0j 3 /Q1 15: 60
10 /_lL/_22 f-.6D

Cust.Id 	
O-M29-l-5% 10%
0-M29-1-BSAR
0-M29-1-KMNO4
O-M29-1-HCL
O-M29-1
O-M29-1
0-M29-2-FHAR
0-M29-2-5% 10%
0-M29-2-BHAR
0-M29-2-KMNO4
0-M29-2-HCL
O-M29-2
O-M29-2
O-M29-3-FHAR
O-M29-3-5% 10%
O-M29-3-BHAR
O-M29-3-KMNO4
O-M29-3-HCL
O-M29-3
0-M29-3
O-M29-FHAR
0-M29-BLK-5% 10%
O-M29-BLK-BHAR
O-M29-BLK-KMN04
0-M29-BLK-HCL
0-M29-FIELD BLANK
0-M29-FIELD BLANK
Reagent Blank
Reagent Blank
Reagent Blank
	 yft-rnr (T?P»V 1 1 /m /QA^ --j.
Additional comments or instructions.:
                                                                 114
-------
                                                               PAGE 3 OF 3
Released by:

Accepted by:
    TRIANGLE LABORATORIES, INC.
   Transfer Chain-of-Custody Form
           Project 43231

Transfer  From:  IWL       To: IA I

       Initials..    Date	    Time...

                      iO/^/Vl    J3:00_

                                   JL:00
                             Stb
         MILES.ID.

         43231-
         43231-
         43231-
         43231-
         43231-
              TLI  No.
                    Gust.Id.
     -061
     -062
     -063
     -064
     -065
       183-15-1E
       184-23-5
       184-23-10A
       184-23-10B
       LCS
Reagent Blank
I-M29-REAGENT BLANK
0-M29-REAGENT BLANK
0-M29-REAGENT BLANK
Lab Control  Spike
Additional comments or instructions.:
                                                    -XfrCOC  (Rev 11/01/94)--+
                                                                   115
-------
"71
•ITS
-------
EXP data

 2/1/98
 9/1/98
 2/1/98
 9/1/98
 2/1/98
 2/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 2/1/98
 9/1/98
 9/1/98
 6/1/98
 9/1/98
 9/1/98
 2/1/98
 8/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 8/1/98
           SEE SPIKE LOG
Spiking Standard Preparation
3ement Standard Orig. Std. Spike(uL)
ID (ppm)
*g
*s
W
M
3
3a
3a
:a
Za.
M
Zo
:r
:u
:8
:e
C
c
uig
Ug
An
ulo
>Ja
la
>Ji
»b
Sb
Se
n
n
;
'.n
!n
2-115-4
3-O10-10
2-115-4
3-010-7
2-115-4
2-115-4
34)10-10
3-010-10
3-012-7
3-010-10
34)10-10
3-010-10
34)10-10
3-010-10
3-012-6
2-115-4
3-012-5
3-010-10
3-010-8
3-010-10
3-010-10
2-115-4
3-010-9
3-010-10
3-O10-10
34)10-10
3-010-10
3-010-10
3-010-10
3-010-10
3-010-10
3-010-6
100
100
100
10000
100
100
100
100
10000
100
100
100
100
100
10000
1000
10000
100
10000
100
100
100
10000
100
100
100
100
100
100
100
100
1OOO
Fvol(IOOmL)
5000
5000
5000
950
5000
5000
5000
5000
950
5000
5000
5000
5000
5000
950
5000
1500
5000
950
5000
5000
5000
1950
5000
5000
5000
5000
5000
5000
5000
5000
1500
cone
(ppm)
5
5
5
95
5-
5
5
5
95
5
5
5
5
5
95
SO
150
5
95
S I
5
5 {
195
S
5
5
5
5
5 I
S
5
15 I
SPIKING
'ram Spiking Standard
Spike(uL) cone
=Vol(100ml)
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
(ppb)
50
50
so
950
50
so
50
so
950
50
so
so
50
SO
950
500
1500
50
950
SO
SO
50
1950
SO
SO
SO
SO
50
50
30
SO
150
combined
total
1000

1000

1000
2000
1000

2000

200
••Spike separately
Bement   Orig Std
           (ppm)
Spike(uL)     cone
Fvol(100m     (ppb)
Au
Ce
Li
P
Pd
Pt
S
Si
Sn
Sr
1000
1000
1000
1000
1000
1000
1000
10000
1000
1000
140
30
70
100
160
300
350
350
20
5
1400
300
700
1000
1600
3000
3500
35000
200
50
         tOOOuL of tne SpiKing Standard gives the nstea cone, at tne above elements.
        Spiking Standard 3-013-4
        EXP: 11/26/97

        Spiked by:
        Predigestion-

        Postdigestion-
                                                                                                                          11
-------
-------
  * SEE SPIKE LOG
EXPtfati
2/1/98
9/V93
2/1 /98
9/1/98
2/1/98
2/1/98
9/1/98
•V/1/98
9/1/38
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
2/1/98
9/1/98 I
9/1 /sa
a/1/sa
9/1/98
9/1/98
2/1/98
8/1/98
9/1 /S8
9/1/98
II Spiking Standard Preparation •'
Dement 'standard Orig.Std. Spika(uU ecne
10 '"(ppm) Tvd(100mL) (ppm)
tf~"
\3

£
t

&•
P
P
fcd
to
P
F-
F« ~
po
<
<

«g
*.
.0
*i«
4a
Mi

9/1/98 JBb
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
8/1/98
5a
n
n
r
In
.n
• 2-115-4
3-010-10
2-115-4
3-010-7
2-115-4
2-115-4
3-OfO-IO
3-010-10
3-012-7
3-010-10
3410*10
-3-010-10
3410-10
3410-id
3412-8
2-115-4
3-01 2-5
3410-10
3-010-8
3-010-10
3-010-10
2-115-4
3-010-9
3-010-10
3410-10
3410-10
3410-10
3410-10
3410-10
341O-10
3410-10
3410-6
100
100
100
10000
100
too
100
too
10000
100
100
100
100
100
10000
1000
10000
100
10000
100
100
100
10000
too
too
too
too
100
100
100
100
1000
5000
5000
5000
950
5000
5000
5000
5000
950
5000
5000
5000
5000 •
5000 -
950
5000
1500
5000
950
SOOO
5000
SOOO
19SO
5000
5000
5000
SOOO
SOOO
•sooo
SOOO
SOOO
1SCO
5
s
s
as
5
5
s
5
35
5
5
5
5
" 5 I
' 95
50
150
5
95
5 1
5
S
195 !
5
S I
5
S
5
. s •
S
5
15
SPIKING
torn Spiking Standard
ipikefuL) eerie
=Vd(tOOml) (ppb)
1000 >
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
.-' 1000
1000
1000
1000 •
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
toco
1000
so
50
50
950
50
50
so
so
950
so
50
so
so
3d1
950
500
1500
50
950
50
SO
SO
1950
SO
50
SO
SO
50
SO
SO
SO
150
combined
total



1000




1000
f
1000
2000
1000

2000

200
••SpDc« icparatefy
Element OrigStd Spik«(uL) ccnc
(ppm) Fvol(100m (ppb)
Au
C«
U
P
Pd
Pt
S
SI
Sn
Sr
. 1000
1000
1000
1000
• 1000
1000
1000
10000
1000
1000
14O
30
70
100
160
300
350
350
20
5
1400
300
700
1000
1600
3000
3500
35000
200
50
lOOOuL at ma Spiking Standard gma me listed cone, of ma above dements.
Spiking Standard 3-013-3
EXP: 11/26/97

Spiked by:
                                                                                     119
-------
-------
        "  * SEE SPIKE LOG
  EXPdatt

   2/1/38
   9/V98
   2/1/S8
   9/t/sa
   2/1/98
   2/1/38
- ^9/1/98
 •9/1/98
  9/1/38
  9/1/98
  9/1/98
  9/1/98
  9/1/98
  9/1 /SB
  9/1/98
  2/1/S8
  9/1/98
  9/1/98
  8/1/98
  9/1/98
  9/1/98
  2/1/98
  a/t/sa
  9/1/98
  9/1/98
  9/1/98
  9/1/98
  9/1/38
'g/i/sa
 9/1/98
 9/1/98
 8/1/98
Spiking Standard Preparation ••
t Dement 'standard Orig. Std. Spike(uU ~eonc
10 •"(ppm) •Fvcl(1COmtO fppm)

















.






>b
>b
>•
n
n
'
P
&
• 2-115-4
3410-10
2-115-4
3410-7
2-115-4
2-115-4
34fO-tO
3410-10
3412-7
3410-10
3410-10
•3410-10
3410-10^
3410-10"
3-012-8
2-115-4
3-012-5
3410-10
3-010-8
3410-10
3410-10
2-115-1
3410-9
3410-10
3-010-10
3410-10
3410-10
3410-10
3-010-10
3410-10
3410-10
3-010-8
too
ICO
too
10000
too
too
100
too
1CCCO
too
too
100
ICO
too
tcoco
toco
tccco
too
tcoco
too
too
too
tccco
ICO
too
ICO
too
too
too
ICO
too
toco
5000
5000
5000
950
5000
5000
5000
5000 ~
950
scoo
5000
5000
5000 •
5000 ~
950
. SCOO
1500
5000
950
SOCO
50CO
SCGO
1950
5003
5000
5000
SOCO
5000
• 5000
5000
SOCO
1500
S
ISPIKING
(from SplUng Standard
EoikefuL) cone
fcvol(ICOml) fppb)
li icoo ;•
s 1 toco
s
93
S
s
s
5
95
S
5
5
5
" S
• 9S
SO
ISO
5
95
5
S
S i
19S 1
S I
s !
S |
s 1
s I
.5-1
5 t
II 1000
\ 1000
a icoo
I) toco
9 1000
1 toco
ll toco
H 1000
1 toco
1 1000
1} 1000
I toco
1CCO
.•• 1000
ICOO
toco
toco •
1 toco
1000
1000
1000
toco
toco
toco
toco
toco
toco
toco
5 | 1000
15 i
toco
50
so
so
950
50
so
so
so
950
so
so
so
so
so-
950
SCO
1SCO
so
950
50
SO
so
1950
SO
SO
SO
so
so
so
so
so
ISO
combined
total -



ICOO




1000

r
10CO
2COO
1CCQ

2000

200
"Spike separately
aement  Orig Std
           (pom)
Spike(uy    cone
FvddOCm
Au
C«
U
P
Pd
ft
S
SI
Sn
Sr
1000
1000
1000
toco
• toco -
toco
1000
10000
toco
1000
14Q
30
70
100
160
300
350
350
20
5
1JOO
330
TOO
1000
1800
30CQ
3SCO
35000
200
SO
         tOOCut ol tno Spiking Standard givsa ma listed cone, of trie above dements.
        Spiking Standard 3-013-3
        EXP: 11/26/97

        Spiked by:
        Predgeatfon-
        Postdlgestton-
                                                                                                              £.<•
                                                                                                             Til
                                                                                                              ''« '•
-------
Analysis Report
8
1
2
3
4
r
6
7
Sample Name
STD1-BLANK
ST03 w.
STD3 ~"
CHECK LO
icv/ccv 	 	
ICV/CCV
ICB/CCB
8.ICSA8
9
10
11
12
13
14-


16
17
18
19
20
21
22
23
24
25
26
27
28
30
31
32
33
34
35
36
37
38
39
40
41
42

44
45
46
47
48
49<
50
51
52
53
CHECK LO
CHECK 9972
185-4-1
185-4-1 0
ICV/CCV
ICD/CCG 	
rrn/rrn
ll/U/ HU
ICB/CCB
ICSAB
43231 MB
43231 LCS
183-3-1B
183-3-28
183-3-2B PDS
183-3-28 L
183-3-38
183-3-38 DA
183-3-48
183-3-5B
ICV/CCV
•flB/CCo
ICB/CC8
183-3-6B
183-3-7B
183-3-88
183-3-18/JOqvi^i-
183-3-2C
183-3-2C POS
183-3-2C L
183-3-3C
183-3-3C DA
183-3-4C
ICV/CCV
ICB/CCB

183-3-6C
183-3-7C
183-3-3C
43231 MB ^^
4323JJ£S*~""7*ir
nft-^ji-iflB *&**~
ICB/CCB
ICV/CCV
ICB/CCB
ICSAB
Suaaary
File
100797
100)97
. 100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
	 100707
IftATQI
1UU/ Tl
100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
100797
• 100797
100797
100797
100797
rt 100797
100797
100797
100797
100797
100797
100797
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100797
100797
100797^
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100797
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100797
100797
100797
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TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIflNSL?
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
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TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIflNGlZ
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
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TRIANGL2
TRIANGL2
TRIANGL2

TRIANGL2
TRIANGL2
JWfflSlT
TRIANGL2
TRIANGL2
TDT4NCI9
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
Date
10/07/97
10/07/97
10/07/97
10/07/97
in/m /Q7
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
1 A //\T Inl
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10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/yr
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
10/07/97
in/m/07
10/07/97
Ofl/«W
10/07/97
10/07/97
10/07/97
10/07 '97-
10/07/97
10/08/97
10/08/97
10/08/97
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02:08
02:13
02:17
02:22
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02:44
02:49
02:55
03:33
03:43
03:48
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04:31
04:37
05:09
05:14
05:19
05:23
05:28
05:33
05:37
05:42
05:47
05:51
05:57
1 06:04
06:19
06:24
06:29
06:34
06:38
06:43
06:48
06:52
06:57
07:02
07:06
07:12
07:17
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07:32
07:38
07:42
07:47
07 '51
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                             ,njL*3
                           Kh
2h6^- K>n(«o
-------
Analysis Rector t      Sumnary
               fled  10-08-97  07:01:24 AM     page 1
   Sample Name
File     Method   Date      Time  OpID  Type Mode
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
T
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77
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23
24
25
26
27
28
29
30
31
32
33
34
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37
38
39
.40
41
42
43
r
45
46
ICV/CCV
ICB/CCB
ICSA8
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STD3
ST03
CHECK LO
ICV/CCV
ICB/CCB
ICSA8
183-3-33 X50
183-5-58 X50 OA
183-3-56C
183-3-6C
183-3-7C
183-5-8C
43231 N8
43231 LCS

in/cc\h 	 	

ICV/CCV
ICB/CCB
184-23-iAB X200
184-23-2A6 X200
184-23-2A3 X200 L
184-23-5A8 <2GO
184-Z3-3A3 X200 OA
184-25-4A8
134-23-6A8
184-23-7no
184-23-3A8
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184-23-9A8
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183-15-iC
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100797
100797
100797
100797
100797
100797
100797
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100797
100797
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100797
100797
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100797
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TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
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10/08/97
10/08/97
10/08/97
10/08/97
10/08/97
10/03/97.
10/08/97
10/08/97
10/08/97
10/08/97
10/08/97
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10/08/97
10/08/97
10/08/97
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10/08/97
10/08/97
10/08/97
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10/08/97
10/08/97
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10/08/97
10/08/97

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10/08/97
10/08/97
10/08/97
10/08/97
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10/08/97
10/08/97
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                                                                                                          123
-------
AnaJvsis Reoori
I  Saraole Nane
                  Sunnarv
File
               Thu 10-25-97 02:55:54  ?N
                                 oaae I
Method   Date
                                               Tine  QpID Tvoe  Node
I
2
3
4
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17
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102397
102397
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102397
102397
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TRIANGL2
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10/23/97
10/23/97
10/73/07
10/23/97
10/73/97
10/73/97
10/23/97
lfl/?3/97
10/25/9?
10/73/97
10/23/97
lfi/23.'97
10/23/97
10/23/97
10/73/97
10/25/97
10/73/97
10/23/97
10/73/97
10/23/07
10/23/97
10/23/97
10/73/97
10/23/97
10/73/97
10/23/97
10/73/97
10/25/97
10/23/97
10/75/07
lft/7.7./07
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10/73/07
10/25/97
10/73/07
10/23/97
10/23/97
10/23/97
10/73/97
10/23/97
10/23/97
10/23/97
10/23/97
10/23/97
10/23/97
10/23/97
10/23/97
10/73/97
05
05
05
05
05
05
05
05
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06
06
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06
06
06
06
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06
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07
07
07
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08
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08
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08
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13
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14
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14
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SRB
SRB
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                                                                                    10
                                                                                                       124
-------
Ana mis Rennrt,      Sironarv             Ihu 10-23-97 02:53:34 PM     page 2




 8  Sanplfl Nane         File    Method   Date      Tine OpID Type Node






 54 ICSflB               102397   TRIAHGL? 10/23/97  14:42 SRB  Q    CONC
                                                                                                           125
-------
     finalvsis Rennet.
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                                                                                                                                  126
-------
                                                                                                            PAGE 1 OF 5
  Project: 43231
                               TRIANGLE LABORATORIES, INC.
                      Sample Preparation Tracking & Management Form
                                                       Client: Pacific Environmental Services (PES03)
  Method:
|  Solvent/Acids 0:  tWE)
                  Extraction Date:
                   Lot:
                                                            fiprmation
                                                            '
I       I
I       I   TLI        /
| Sample | SAMPLE ID   /     CLIENT
I ft  crd|            /     SAMPLE ID
                     | Sample  |Final
                     |Wgt //Vol|Volume|	/	/_
                     | g  /(ml/1  ml
|       | TLI Blank '
1 °°°    1  fttt. * r»
           * $
                     1
TLI Method Blank
                         1
                              i/Ol)
|       | 183-3-2B
|001    1
        I-M29-1-FHAR
        183-3-2C
1002
                     >xb
1003    '
l°°*
1005    '
        -M29-1-KMN04
|       | 184-23-1AQ
|006
             I-M29-1
|       | 184-23-1B
|007    |
             I-M29-1
                                                                     ^  M/l  1
                                                                     ^ '    1
|  Comments:
SOL   M\SL-\.
                                                                                                 -REV 07/26/93 (PSTMF 7) --»
                                                                                                              127
-------
                                                                                                                   PAGE 2 OF 5
  Project:  43231
                  TRIANGLE LABORATORIES,  INC.
         Sample Preparation Tracking & Management Form
                                             Client:  Pacific Environmental Services  (PESOS)
   .thod:
                                                       Sample Information
  Solvent/Acids 0:
     Extraction Date:
       Lot:   lilCfjQ
                                                   W,
       I    TLI          /
|S="ple|  SAMPLE ID    /    CLIENT       |Wgt
|ft  crd|              /     SAMPLE ID     |  g
                  POKl-IY          I   TJJ>
                  Volume |	/	/	I   7
                    ml   |           |
	I	/	/	|	/	/	|	/	/	|	/_
         184-23-2A&
1°
|       |  184-23-2B
1°      I
                  I       I
I-M29-2  |
                                                                       tf
                            I-M29-3-BHAR
                                    I  1&Pl
                                   TjjsT"
                           I-M29-3-KMNO4
                             I-M29-3-HCL
                                                                      fAS-
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|0
                                                                                                      -REV 07/26/93  [PSTMF 7)--
-------
                                                                                                                PAGE 3 OF 5
I
I  Project: 43231
                                                  TRIANGLE  LABORATORIES,  INC.
                                         Sample Preparation Tracking & Management Form
                                                                           Client: Pacific Environmental Services (PES03)
I
|  Method:
                    ^
                                                      Sample Information
                                    ExtractixmJJate:  S /3b/Qf
                                      Lot:
I       I
I       I   TLI         /
|Sample| SAMPLE ID    /     CLIENT
|#  crd|             /     SAMPLE ID
                                       I
                                       I
                                       |Wgt /Atol\ Volume |	/	/	|_
                                       |  g  /(mlj   ml  |         .  |
_y±_/	i	,
                          '-M29-BLK-HCL
                      I-M29-FIELD BLANK
                                                  (
-------
                                                                                                                  PAGE 4 OF 5
  Project: 43231
                                                   TRIANGLE LABORATORIES, INC.
                                          Sample Preparation Tracking & Management Form
                                                                             Client:  Pacific  Environmental Services (PES03)
  Solvent/Acids!) :
                                                      /Sample Information
                                                      ^*i -J&f  L*> /
                                     Extraction Date.:   { ifAl /7 /
                                       Lot:  l\%4t>
       1
       1   TLI
  -mple| SAMPLE  ID
    crd|
                           CLIENT
                          SAMPLE ID
|Wgt /Vol |olurae |
|  g  /Iml / ml   |
__4&_l _ / _ / _ 1 _ / _ / _ 1 _ / _ / _ 1 _ /   /   i
                           -M29-2-KMN04
                            0-M29-2-HCL
       |  184-23-7A
                                0-M29-2
                                                  i       i
                                             f   | /GO
         184-23-7B
1043
                                        1
                                0-M29-2 |
1044
|       | 184-23-8AJ
|       |  184-23-88
I   0    |
                                                  1       1
                                0-M29-3 |
|       |  183-3-5B
                             0-M29-FHAR
        183-3
                                    10*
  Comments :
                                                                                                      -REV 07/26/93 (PSTMF 7) —»
                                                                                                                  130
-------
                                                                PAGE 5 OF 5
TRIANGLE LABORATORIES, INC.
1 Sample Preparat
| Project: 43231
1 Method: \.\,> Extraction Date: ^
1 Solvent/Acids ()• fJMWf^W *>t: WTOM/ *?
J\ " ' ~
I | TLI / | Sample[_| Final
| Sample) SAMPLE ID / CLIENT |Wgt / Fol\ Volume
|tt crd| / SAMPLE ID | g / lnl/| ml
1 1 183-3-SD | £/ |
|053 | 0-M29-BLK-BHAR | /£ 1 //V)
| | 183-3-5E | ryS 1
|OS4 | 0-M29-BLK-KMN04 \/^ & 1 /r\/)
|055 | ^ 	 , O-M29-BLK-HCL | /{Z) I//"
| | 184-23-9A(i | tx |
|056 | k 0-M29-FIELD BLANK | >X- | '^
| | 184-23-9B | |
1 057 | 0-M29-FIELD BLANK | |
| | 183-lS-lB^ | ^/ \
|058 | "tf^*\ . Reagent Blank \S*-\ I)Q^
| | 183-15-1C | £ 'x' r l«t$
|059 | v>«<^ PW) ^ ^ '
1061 1 ^^ s |frTYM?Rea9ent Blank | ^/ * | JL y")
,x-<^IspZ-/5't l^T jr r-^ lir"
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1 1 184-23-5 | |\
1AC7 1 T M*5 Q TJPtf^PMT ttT &MV 1 J \ /
UO« | ly— _ i *K — -* A ~ N^; 3 — rCCi*wj£>Ti A OuAXMR. | £_ _ \ 'I/O
(v4->lj-9.toAjQO^/??-/^-jd UL»^> ^k #5-
| | 184-23-10A | ^
|063 | 0-M29-REAGENT BLANK | \J \ |J)C
	 * 	 / (
| | 184-23-10B | I 1 \
|064 | 0-M29-REAGENT BLANK iT^KJ 1 )
1 1 LCS1 | ..It |
|065 I/(V^II\ Lab Control Spike | [lift — 1 I&O
i (\ / r /:
1 Comments: i )00 -lftO$- 1 U 1 -^
1 ' &
1
ion Tracking & Management Form |
Client: Pacific Environmental Services (PESO 3) |
Sf ?frnation Tfe !
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i
                                                    -REV 07/26/93  (PSTMF 7)--.
                                                                  131
-------
                                                                                                           PAGE 1 OF 1
 Project: 43231
                                              TRIANGLE LABORATORIES, INC.
                                      Sample Preparation Tracking & Management Form
                                                                      Client: Pacific Environmental Services  (FES03)
       ,    n4oo
                .  UlfMjI^SOlJ
                                                   Samnle Information
V  :hod
Solvent/Acids 0
Extraction Date:
I       I   TLI        /
|Samnle| SAMPLE ID    /     CLIENT
|#   :rd|            /     SAMPLE ID
                                      Sample  |Final  |
                                    |Wgt / foii Volume | _
                                    I  g  / U J   ml

|       | TLI Blank.
                 <&
                      TLI Method Blank
                                             !
|       | LCS-i
| Of
                                             I       I
(._.  ...+
                    Lab Control Spike
       I/S3-3 -
                                             I       I
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                                                     I
                                               I      I
                                                /60 I
  Comments :
                                                                                                -REV 07/26/93 IPSTMF 7) --«
                                                                                                            132
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Project: 43231 Client: Pacific Environmental Services
i~\ 1 1 (O/~\ Sample Information 1 1 /"v
Method: J^ fJ Extraction Date: Q $0/3 ' I'M
Solvent/Acids { ) : -^rMX j ^5M- Lot ! \ \ *3\b } 3 1 1/)^ ^

1 i^W^I 1 ' 1 IfcAjfr^ 1 1 1
| TLI / | Sample (Final | ' Tf^7 ' ' 1
Sample | SAMPLE ID / CLIENT (Wgt / WoH Volume] 	 / 	 / 	 [ Y 1 	 | 	 / 	 / 	 | 	 / 	 / 	 | 	 / 	 /
# crd| / SAMPLE ID | g / \nl/| ml | | | | |
| TLI Blank-5" | £/ 1 \ ' ^ o\M ' ' '
000 ' mfi 5 n TLI Method Blank ' /o ' I&D ' ' ° ' ' '
065 1 1 A C
-------
                         MERCURY SPIKE LOG
                                                             PAGE
DATE
PROJECT #

SAMPLE IDs
ORIGINAL
  SPIKE .
CONC. (Hg)
STANDARD #
 WORKING
 STANDARD
 PREPARED
  FROM
 SPIKE
AMOUNT
  (mL)
 SPIKE
SAMPLE
 (PPB)
INITIALS
WITNESS
                                             r
                                                          B^
                                             i/
                                            5
       lfi-30- IGrfl-8
      lfZ.-30-JF
                                  V
                                          \/
       \ki-3s-HF
                        ]
         - 30-
         - 3o-/JG-

              LCSJ
                        0.
            LCSlD
                                   s/
                                                   V
                                  t
      433131  UlSO.
                        O.I
       V3-3- M CmS
                          Vr

                                                  M-
 qa\forms\hgspke.log (08/22/96)
                                                                134
-------
                                                                  PAGE
                              MERCURY SPIKE LOG
      DATE
PROJECT #

SAMPLE IDs
                         ORIGINAL
                          SPIKE
                         CONC. (Hg)
                                  STANDARD #
                                   WORKING
                                  STANDARD
                                  PREPARED
                                    FROM
                   SPIKE
                  AMOUNT
                   (mL)
 SPIKE
SAMPLE
 (PPB)
INITIALS
WITNESS
                              6' I
                pr
                  • 5-1 Afen
                  - ? -a E
                               \/
iOJ2^
                                                s
                                         S~
•^m^
                        oA
                                 1
                   3
                         o-i
                                5"
                                                         t

L4i
o-i
                m^
                                     3-011- 1,
                               S
                                                    5
            ISH- U - I A' M.J
                Z^ - lA
                                                  1
                                                                     s/
            ««*«
            0'.
                                 3-611-fe
                                                    5
                              4
                                                 ^
        qa\forms\hgspke.log (08/22/96)
                                                                                135
-------
                                                           PAGE-
                        MERCURY SPIKE LOG
DATE
PROJECT #

SAMPLE IDs
ORIGINAL
  SPIKE -
CONC. (Hg)
STANDARD #
 WORKING
 STANDARD
 PREPARED
  FROM
                                            SPIKE
                                           AMOUNT
                                             (mL)
 SPIKE
SAMPLE
 (PPB)
INITIALS
WITNESS
                       0.
                Ityi
                                  N
                                       -S
                                            w
                                           S"
               \1/
                                                  V
(°(ffl7
                               1-0/7-4
                                S"
                            5
                                   SF
                         /.
                                            /

      M-323/
                       ec
 qa\forms\hgspka.log (08/22/96)
                                                                          136
-------
Loc.  Concentration
  0
  1
  S
  4
  5
  &
  7
  a
  9
 10
 11
 is
 13
 14
 15
 16
 17
 13
 19
 S0
 SI
 S3
 S3
 S4
 S5
 S&
 39
50.0 ug/L
100.0 ug/L
     ID/Weight File: EB160.IDW

Solutions

Calib.  Blank / Diluent / ICB / CCB
Stock            |~(flO-lP
Stock / Recovery Stock j-
ICU=30ug/L   j'kO'^P
CCV=60ug/L
CHECK LO
43S31 MB
43S31 LCS
183-3-IB
183-3-SB
183-3-2B L
183-3-3B
183-3-4B
183-3-5B
183-3-&B
183-3-7B
183-3-8B
183-3-1BC
183-3-SC
183-3-SC L
183-3-3C
183-3-4C n
183-3-5B£
183-3-&C
183-3-7C
183-3-8C
Modifi er
                                                            137
-------
ElifHifll ;Ftle: TL. GEL
Print Datas Main+Suppl.
Prfnt: Calib. Curve
                                    Analyst: HOLSTE
                                    Peak Storage:  1 Repl. /Sample
INSTRUMENT: 4100  ZL
Wavelength: 276.8 Peak
Signal Type: Zeeman AA
Read Time: 5.0
Sample Replicates: 2
Standard Replicates: 2
                                    Technique: HGA            Version:  7.30
                                    Slit: 0.70 Low
                                    Signal Measurement: Peak  Area
                                    Read Delay: 0.0           BOC Time:  2

                                    Spike Replicates: Same as Sample
CALIBRATION:
Solutions

Calib. Blank
Standard 1
Standard 2
Standard 3
Reslope Std.
Samples

1 ID 1 Cone
1
ISTD BLK
ISTDl=25ug/L
ISTD2=50ug/L
ISTD3=100ug/L
!50ug/L





25.
50.
100.
50.







0
0
0
0



1
1
1
1
1
1
1



Locat ion

0
1
1
O
1


Vol ume

20
10
20
20
20
20
Di luent
Volume
5
15
5
5
5
5
Modifier
#1
5
5
5
5
5
5
#2






Diluent Location: 0
Modifier #1
Cal ibrat ion
Cal ibrat ion
Location: 39 Modi
fi
Units: ug/L Sam pi
Type: 'Nonlinear

e

er #2 Location:
Units: ug/L

Furnace Time/Temperature Program:
Step
1
2
3
A
5
Temp Ramp Hold
110 5 30
130 1 35
700 5 20
1600 0 5
2500 1 5
Gas FlowlRead
250 1
250 1
250 1
0 1 *
250 1
Gas Type
Norm
Norm
Norm
Norm
Norm






Injection Temp: 20 Pipette Speed: 85/4 Extraction System: On
SEQUENCE:
Step  fiction and Parameters
  1    Pipet diluent + modifier  1
  2    Run HGA steps 1 to End
                                   •+• spike + sample/std
CHECKS:
Recalibration Type:
Locations: None
                     Reslope
Cone, Above Calibration Action: Dilute  &  Reanalyze  After  1  Rep
Alternate Sample Volumes  (uL): 5,2,1
Run Alternate Volume Blanks:  Yes

If -/.RSD > 20.0      and Concentration  >  1.7       then  Retry 1
Check #RSD on: Samples +  Standards  + Spikes  +  QC  Samples
                                                                times
Recovery Measurements:
5  uL of 100 ug/L Standard at Location  2   Bives     25.0  ug/L
Measure Recovery on Samples:  10, 11,- 19,20
Add to QC Samples: Yes               % Recovery Limits:  75 to  125
                                                            138
-------
#1 ft/S I    QC Sample   I     Cone. Limits     IftfterIPeriodiclAt I Count As I
  f Loc.J       ID       I   Lower     Upper    ICalibl   Check  I End I  Sample  I
1  ~  4  ICV=30ug/L      27.0       33.0
a    0  ICB             -2.0       2.0
3    5  CCV=60ug/L      48.0       72.0         X       XX
4    0  CCB             -2.0       2.0          X       XX
Run Periodic QC Samples:  Every 10
Out of Limit Action: Reslope and Rerun Samples

Matrix Check Calculations:
'/• Difference for Dupls: No     Locations:
"A Recovery for Spike: No       Locations:         Cone:
                                                            139
-------
E\e.ment  File:  TL.GEL
Dat-e: 09/29/97
Data File:  EB160.DAT
Technique:  HGA
                        Element:  Tl
                        Time:  00:41
                        ID/Wt  File: EB160.IDW
                        Calib.  Type: Nonlinear
                                Wavelength:  £76.8
                                Slit: 0.70  L
                                Lamp Current:  0
                                Energy: 48
             f\f f\f i\f *v A* A* A/ A* A* A/ A* A/ A* A* A* A* A* Ar Ay A/ A* A* A/ A* A* *V A* A/ A» A* *V *V 'V A» A» A/ A* A/ A/ Af A» Af A* A* A* A* A# A/ A* Ar Af
                                                                              A* A/A/ A/A*
Tl
ID: STD BLK
Seq. No.:  00001
A/S Pos.:  0
Date: 09/£9/97
uL dispensed: 5 from  0,  5 from 39, £0  from 0
Replicate  1                             Time: 00:44
Peak  Area (ft-s): 0.001                   Peak Height  (ft):  0.007
Background Pk Area  (A-s): 0.001         Background Pk  Height (A): 0.006
Blank Corrected Pk  Area : 0.001         Background Pk  Height (ft): 0.005
Blank Corrected Pk  ftrea (A-s)s 0.000
Mean  Pk  Area  (A-s):
Auto—zero performed.
                    0.001
           SD: 0.0002
                RSD<%) :  41.09
A* *V\* *Vr *V A* *\* *W A* *W *\* *V *V *V*V *X/*\/*\* *\/*W *W*V A/*W A* *\^ *\/ Ay Ay A* A* A* A/ A* A* A* A* A* A* A* A* A* A* A/ «V A^ A* *\/A* A* A* A* A* A* A* A* A* A/ A* A/ A* A* A^ A* A* A* A* A* Av A/A* A^ A* A>
Tl
ID: STDl=25ug/L
Seq.  No.
ft/S Pos. :  1
Date:  09/£9/97
ul_ dispensed:  15  from 0,  5 from 39,  10 from 1
Replicate  1                             Time: (30:50
Peak  Area (A-s):  0.039                  Peak Height  (ft):  0.054
Background Pk  Area  (fl-s):  0.020         Background Pk  Height (ft):  0.030
Blank Corrected Pk  Area (A-s): 0.039

uL dispensed:  15  from 0,  5 from 39,  10 from 1
Replicate  £  (Peak  Stored)
Peak  Area (A-s):  0.038
Background Pk Area  (ft-s): 0.0££
Blank Corrected Pk  Area (A-s): 0.038
                                   Time:  00:53
                                   Peak Height (A): 0.053
                                   Background Pk Height  (A):  0.030
Mean  Pk Area  (A-s):
                    0.038
           SD: 0.0006
                RSDC/4) :  1. 50
Standard number  1  applied.   C25.OD
Correlation coefficient:  1.00000
                                   Slope:  0.0015
  # A* A* A* A* A* f\f A* A* A* A* A* A* A* A* A* A/ A* A* A/ *V A/ A* A* A* A/ A* A* A* A* A* A* A* A* A* A* A* A* A* A* Ay A/ A* A* A/ A* A/ A* A/ A/ A* A* A/ A* A* A* A* A* A* A* A* A* A* A* A* A* *\* A* *V A* A* A* A* A* A* A* A* A*
Tl
ID: STD£=50ug/L
Seq.  No.:  00003
A/S Pos.:  1
Date:  09/29/9:
uL  dispensed: 5  from  0,  5 from 39, £0 from 1
Replicate  1                             Time: 00:56
Peak  Area (A-s):  0.078                  Peak Height  (A):  0.106
Background Pk Area  (A-s): 0.04£         Background Pk  Height (A): 0.058
Blank Corrected  Pk  Area (A-s): 0.077
Concentration (ug/L  ):  50.5

uL  dispensed: 5  from  0,  5 from 39, £0 from 1
Replicate  £  (Peak  Stored)               Time: 00:59
Peak  Area (A-s):  0.076                  Peak Height  (A):  0.106
Background Pk Area  (ft-s): 0.04£         Background Pk  Height (A): 0.057
                                                                140
-------
Concentration  (ug/L  ): 49.4
  T

lean Cone   :  1.57
Tl
ID: STD3=100ug/L
Seq.  No.: 80004
fl/S Pos. : S
Date: 09/29/97
ul_ dispensed: 5  from 0, 5  from  39,  20 from 2
Replicate   1                            Time: 01:02
Peak firea  :  0.150         •         Peak Height (fl):  0.206
Background  Pk flrea  : 8.119
Blank Corrected  Pk  firea  :  8.158
Concentration 
                         *
                         
-------
Element File: TL.BEL
Date: 09/29/97
Data File: EB1&IZ). DAT
Technique: HGA
                       Element:  Tl
                       Time:  01:05
                       ID/Wt  File:  EB160. IDW
                       Calib.  Type: Nonlinear
                               Wavelength:  £76.8
                               Slit:  0.70 L
                               Lamp Current: 0
                               Energy:  53
Tl
ID:  ICV=30ug/L
Seq. No.: 00005
A/S Pos.
Date: 09/£9/9/
uL dispensed: 5  from 0,  5 from 39,  £0 from 4
Replicate   1                            Time: 01:03
Peak Area  :  0.048                 Peak Height  (A): 0.064
Background  Pk Area  : 0. 0£5        Background Pk Height   :  0.034
Blank Corrected  Pk  Area :"0.048
Concentration  (ug/L  ):  31.1

uL dispensed: 5  from  0,  5 from 39,  £0 from 4
Replicate   £  (Peak  Stored)
Peak Area  : 30.3
                                  Time:  01:11
                                  Peak Height (A): 0.067
                                  Background Pk Height (A): 0.038
Mean Cone   (ug/L  ):        30.7        SD: 0.61

QC sample  is  within  range £7.0 - 33.0
                                                          RSDC/4) : £.00


Tl
ID: ICB
Seq. No.: 00006
A/S Pos.: O
Date: 09/£9/97
uL dispensed:  5 from 0,  5 from 39,  £0 from 0
Replicate   1                            Time: 01:14
Peak Area  (A-s):  0.001
Background  Pk  Area (A-s):  0.003
Blank Corrected  Pk Area (A-s):  0.001
Concentration  (ug/L  ): 0.4
                                  Peak Height (A):  0.006
                                  Background Pk Height (A): 0.008
uL dispensed:  5  from  0,  5 from 39,  £0 from 0
Replicate   £  (Peak  Stored)
Peak Area  (A-s):  0.088
Background  Pk  Area  (A-s):  0.003
Blank Corrected  Pk  Area (A-s):  -0.000
Concentration  (ug/L  >: —0. £
                                  Time:  01:17
                                  Peak Height (A): 0.006
                                  Background Pk Height (A): 0.008
Mean Cone   (ug/L  ) :
                      0. 1
          SD: 0.39
               RSD(*) :  448.81
QC sample  is  within  range -£. ft - £. 0
                              f\ff\^f\^f\ff\ft^
Tl
ID: CHECK LO
Seq. No.: 00007
A/S Pos.: 6
Date: 09/£9/
-------
Pe^ak Area  (A-s) :  0.005                  Peak Height (A): 0.010
 background  Pk Area (A-s> : 0.007         Background Pk Height  (A):  0.007
 Mank Corrected  Pk Area  : 0.005
Concentration (ug/L  ): 3.1

 lean Cone   (ug/L  ):         3.5         SD:  0.&1                 RSD(*): 17.40
                                              *A*A* A* Av A*^^ A/ A* t\t A* A^'V^w ^a A/ ^W A* A*^^^w^^^U^*^**V*^A**V A* ^/ Av At A*^^ A*
 Tl     ID:  43231 MB           Seq.  No.:  00008    A/S Pos. : 7      Date: 09/29/97

uL dispensed:  5 from O, 5 from  39,  £0 from 7
 Replicate   1                            Time: 01:26
 "oak  Area  (A-s) : 0.002         '         Peak Height  (A):  0.007
Background Pk  Area  :  0.002
 Concentration   (ug/L  ): 1.3

uL dispensed:  5 from 0, 5 from  39,  20 from 7
 Replicate   2 (Peak Stored)              Time: 01:29
.:'eak  Area  (A-s): 0.002                  Peak Height  (A):  0.006
Background Pk  Area (A-s): 0.003        Background Pk Height  (A): 0.008
 Jlank Corrected Pk Area (A-s):  0.002
 Concentration   (ug/L  ): 1.2

lean  Cone   (ug/L  ):         1.2        SD: 0.03                 RSD(%): 2.54
•^ A* A* A* A* A* A/ A/ A* A/ A/ A* A* A* A/ A* A/ *V *V *V *\* *\/ *V A* A/ *\*
Tl     ID: 43231 LCS           Seq.  No.: 00809    A/S  Pos.:  8     Date: 09/29/97

aL dispensed: 5 from 0, 5 from  39,  20 from 8
Replicate  1                            Time: 01:32
 3eak  Area (A-s): 0.072                  Peak Height  (A):  0.094
 background Pk Area (A-s): 0.041         Background Pk Height (A): 0.051
Blank Corrected Pk Area  (A-s):  0.071
Concentration (ug/L  ): 46.8

uL dispensed: 5 from 0, 5 from  39,  20 from 8
Replicate  2 (Peak Stored)              Time: 01:35
 :-eak  Area (A-s): 0.081                  Peak Height  (A):  0.103
-Background Pk Area (A-s): 0.043        Background Pk Height (A): 0.055
Blank Corrected Pk Area  (A-s):  0.081
 Concentration (ug/L  ): 52.8

Mean  Cone  (ug/L  ):        49.8        SD: 4.23                 RSDO/O: 8.50
 fl     ID: 183-3-1B            Seq.  No.: 00010    A/S Pos.:  9      Date: 09/29/97

 jiL  dispensed: 5 from 0, 5  from  39,  20 from 9
 .Replicate  1                            Time: 01:37
 Peak Area (A-s): 0.801                  Peak Height  (A):  0.006
 iackground Pk Area  (A-s):  0.002        Background Pk  Height  (A): 0.006
 Jlank Corrected Pk  Area  (A-s):  0.001
 Concentration (ug/L ): 0.4
                                   »
 JiL  dispensed: 5 from 0, 5  from  39,  20 from 9
 Replicate  2 (Peak  Stored)              Time: 01:40
 Peak Area (A-s): 0.002                  Peak Height  (A):  0.008
                                                              143
-------
Blank Corrected  Pk  Area (A-s): 0. 80S
Concentration  (ug/L  ): 1.2

Mean Cone   (ug/L  ):         0.8        SD: 0. 57                 RSDC/t): 69.10
                                                                                 I
Tl    ID:  183-3-2B           Seq. No. : 00011     A/S Pos. :  10    Date: 09/29/97

uL dispensed:  5 from 0,  5 from 39, 20 from  10
Replicate   1                            Time: 01:43
Peak Area  :~ 0.002
Concentration  (ug/L  ):  1.4                                       Vidl
uL dispensed:  5 from 0,  5 from 39, 20  from  10
Replicate   2 (Peak . Stored)              Time: 01:46
Peak Area  (A-s): 0.005                  Peak Height (A): 0.010
Background  Pk  Area (A-s): 0.003         Background  Pk  Height (A): 0.006
Blank Corrected Pk Area  (A-s): 0.005
Concentration  (ug/L  ):  3.1

Mean Cone   (ug/L  ):        2.3         SD:  1. 19                 RSD <*> : 52.
                                        ~
-------
Mean Cone   (ug/L   ):        23.5        SD: 0.54                RSD<5t): 2.31

Recovery is
Tl    ID:  183-3-2B  L         Seq.  No.:  00014    ft/S Pos. s 11    Date: 09/29/97

uL dispensed: 5  from 0,  5 from 39,  20 from 11
Replicate   1                            Time: 02:01
Peak ftrea  (ft-s):  0.002                 Peak Height (ft): 0.006
Background  Pk ftrea  (fl-s): 0.004        Background Pk Height  (ft): 0.006
Blank Corrected  Pk  ftrea (fl-s):"0.001
Concentration  (ug/L  ): 0.8

uL dispensed: 5  from 0,  5 from 39,  20 from 11
Replicate   2  (Peak  Stored)             Time: 02:03
Peak flrea  (fl-s):  0.001                 Peak Height (ft): 0.007
Background  Pk flrea  (fl-s): 0.006        Background Pk Height  (ft): 0.006
Blank Corrected  Pk  ftrea (ft-s): 0.000
Concentration  (ug/L  ): 0.2

Mean Cone   (ug/L  ):        0.5        SD: 0. 42                 RSD(tf):  80.39
Tl     ID:  183-3-2B L         Seq.  No.: 00015    ft/S Pos.: 11     Date:  09/29/97

uL dispensed:  5 from 39,  5 from 2, 20 from 11
Replicate   1                            Time: 02:06
Peak  flrea  (fl-s): 0.037                 Peak Height  (ft): 0.063
Background Pk  flrea (fl-s): 0.024        Background Pk Height  (ft):  O.037
Blank Corrected Pk flrea  (fl-s): 0.037
Concentration  (ug/L  ): 23.9

uL dispensed:  5 from 39,  5 from 2, 20 from 11
Replicate   2  (Peak Stored)             Time: 02:09
Peak  flrea  (fl-s): 0.037                 Peak Height  (ft): 0.061
Background Pk  flrea (fl-s): 0.024        Background Pk Height  (ft):  0.034
Blank Corrected Pk ftrea  (ft-s): 0.037
Concentration  (ug/L  ): 24.1

Mean  Cone   (ug/L  ):       24.0        SD: 0.10                 RSDC/O: 0.41

Recovery  is 93. 8'/-


Tl     ID:  183-3-3B           Seq.  No.: 00016    fl/S Pos.: 12     Date:  09/29/97

uL dispensed:  5 from 0, 5 from 39, 20 from 12
Replicate   1                            Time: 02:12
Peak  ftrea  (fl-s): 0.008                 Peak Height  (ft): 0.013
Background Pk  flrea (ft-s): 0.012        Background Pk Height  (ft):  0.012
Blank Corrected Pk flrea  (fl-s): 0.007
Concentration  (ug/L  ): 4.6

uL dispensed:  5 from 0, 5 from 39, 20 from 12
Replicate   2  (Peak Stored)             Time: 02:15
Peak  flrea  (fl-s): 0.003                 Peak Height  (fl): 0.011
                                                                145
-------
Blank Corrected  Pk  ftrea -------
Blank Corrected  Pk Area (A-s): 0.801
Con-cent rat ion : 99. 14
       ID:  183-3-4B
Seq. No.: 000£0
         A/S Pos. : 13
                                    Date: 09/S9/97
uL dispensed:  5 from 0,  5 from 39, £0  from  13
Replicate  1                            Time:  0£:35
Peak Area (A-s) :  0.003        "         Peak Height (ft):  0.006
Background Pk  Area (A-s): 0.004         Background Pk Height : 0.006
Blank Corrected Pk Area  : 0.00£
Concentration   (ug/L  >:  1.5

uL dispensed:  5 from 0,  5 from 39, £0  from  13
Replicate  £ (Peak Stored)
Peak Area (A-s):  0.003
Background Pk Area (A-s): 0.003
Blank Corrected  Pk Area :  0.006
                                         Background Pk Height  (A):  0.005
Mean Cone  (ug/L  ):
                              1.6
           SD:  0. 15
                         RSDCX) :  9. 45
Tl
         ^ A* ^ ^^ A/ *\» A/^ A* A» A*
       ID:  183-3-5B
                        A/ A* A* A» A* A* A* A* A* A* ^^^^^A* A* A* A/ A/ A/ A* A* A/ A/ A* A* A/ A/ A* A/ A* A* A* A* A* A* A* A* A* A* A^^w A* A* A^^^A* A* A* A* A* Ay A> A* ^
Seq. No.:  000£1
         A/S Pos.:  14
                                    Date: 09/£9/97
uL  dispensed: 5 from 0, 5 from  39,  £0 from 14
Replicate  1                            Time: 8£:41
Peak  Area (A-s): 0.003                  Peak Height (A): 0.006
Background Pk Area  (A-s): 0.004        Background Pk Height  (A)
Blank Corrected Pk Area (A-s>:  0. 00£
Concentration (ug/L  ): 1.4

uL  dispensed: 5 from 0, 5 from  39,  £0 from 14
                                                                    0.006
Replicate  £ (Peak Stored)
Peak  Area (A-s): 0.801
Background Pk Area (A-s): 0.003
Blank Corrected Pk Area  (A-s): 0.001
Concentration (ug/L  ): 0.6
           Time:  0£:43
           Peak  Height (A): 0.005
           Background  Pk  Height (A)
                                                                    0.006
Mean  Cone  (ug/L  ):
                              1.0
           SD:  0.61
-------
Blank Corrected Pk ftrea  (ft-s) :  0
Concentration -------
WUIK-CIIUI CVUAUII  \'-iy/l_  / i   -*Jm UL


Meati Cone    : 0.005        Background Pk Height 
-------
Mean Cone  (ug/L  ):        -1.3        SD: 0. 02                RSD<*>:  1.60
                                 fi\ff\f^f\ff^f\f'\ff\tf\ff\f^f\ff\^^

Tl     ID:  183-3-2C L  **\     Seq. No.: 00029     fl/S Pos. : 20    Date:  09/29/97
uL dispensed: 5 from 39,  5 from 2, 20 from  20
Replicate  1                            Time:  03:27
Peak Area (fl-s) : 0.013                  Peak Height (fl) : 0.021
Background Pk ftrea  (ft-s) :  0.014        Background Pk Height  (ft): 0.014
Blank  Corrected Pk ftrea  (fl-s): 0.018
Concentration  (ug/L  ):  11.7

uL dispensed: 5 from 39,  5 from 2, 20 from  20
Replicate  2 (Peak Stored)             Time:  03:30
Peak Area (fl-s): 0.024                  Peak Height (ft): 0.021
Background Pk ftrea  (fl-s):  0.011        Background Pk Height  (ft) : 0.013
Blank  Corrected Pk flrea  (fl-s): 0.024
Concentration  (ug/L  ):  15. &

Mean Cone  (ug/L  ):        13.6        SD:  2.80                 RSDC/): 20.55

Recovery is 59.9V.    (outside of specified  limits)


Tl     ID: 1S3-3-2C L   Mfc   Seq. No.: 00030     fl/S Pos.: 2®     Date: 09/29/97
uL  dispensed: 5 from  39,  5 from 2, 20 from  20
Replicate  1                            Time:  03:33
Peak  flrea (fl-s): 0.019                  Peak Height (ft) : 0.023
Background Pk flrea  (fl-s): 0.013        Background Pk Height  (fl) :  0.013
Blank Corrected Pk  ftrea  (fl-s) s 0.019
Concentration (ug/L  ):  12.3

uL  dispensed: 5 from  39,  5 from 2, 20 from  20
Replicate  2 (Peak  Stored)              Time:  03:36
Peak  flrea (fl-s): 0.022                  Peak Height (ft): 0.019
Background Pk flrea  (fl-s): 0.013        Background Pk Height  (fl) :  0.014
Blank Corrected Pk  ftrea  (fl-s): 0.021
Concentration (ug/L  ):  13.7

Mean  Cone  *\**V^*'V
Tl     ID: CCY=60ug/L          Seq. No.: 00031     fl/S Pos.: 5     Date: 09/29/97

uL dispensed: 5 from 0,  5 from 39, 20 from 5
Replicate  1                            Time:  03:39
Peak  ftrea (fl-s): 0.044                  Peak Height (ft): 0.046
Background Pk flrea  (fl-s): 0.028        Background Pk Height  (ft): 0.026
Blank Corrected Pk ftrea  (fl— s) s 0.043                                  _
Concentration (ug/L  ) :  28. 2                                        Ottv*
                                                                              te.
uL  dispensed: 5 from  0,  5 from 39, 20 from  5
Replicate  £  (Peak Stored)              Time:  03:42
Peak  ftrea (fl-s): 0.043                  Peak Height (ft): 0.044
                                                                150
-------
Blank Corrected Pk Area : 0. 043
Concentration (ug/L  ): £7.9

Mean Cone  (ug/L  ):       SB. 1         SD:  0.17                 RSDC/O: 0.60

QC sample is out of range 48.0 -  72.0
                                   «'
Tl     ID:  CCB                Seq.  No. :  00032    A/S Pos. :  0     Date: 09/29/97

uL dispensed: 5 from 0, 5 from  39,  20 from 0
*\i f\f f\f f\f f\t f\f r\g f\f *\, *\f t\f f\f f\f *v *\» *V *\f *V *\» *V «V *V *Vr *\» *\* A/ A* *V A/ A/ 'V *W *V *V *\* *V A* »V *V *\» «V *V A/ *W *\» *\* A* A» *W *VW*W'W'\/A*'WV*\*'W*VWW*W«W'WVA*«W*V'\*'V'\*«V*W
Tl     ID:  CCV=60ug/L         Seq.  No. :  00033    ft/S Pos. :  5     Date: 09/29/97

uL dispensed: 5 from 0, 5 from  39,  £0 from 5
Replicate   1                            Time: 03:50
Peak ftrea  (ft-s) : 0.093                  Peak Height   :  0.088
Background Pk Area  :  0.092
Concentration  : 0.049        Background Pk Height (A):  0.049
Blank  Corrected Pk Area  (A-s):  0.091
Concentration  (ug/L  ): 59.3

Mean Cone   -------
Background Pk Area  (A-s): 0. 002         Background Pk Height   : 0.007
Blank Corrected  Pk Area  (A-s):  0.001
Concentration  (ug/L  ):  0.4

uL dispensed:  5  from  0,  5  from  39,  20 from 22
Replicate   2  (Peak Stored)              Time: 04:10
Peak Area  (A-s):  -0.002                 Peak Height  (A):  0.006
Background  Pk  Area (A-s):  0.000        Background Pk Height  (A): 0.006
Blank Corrected  Pk Area  (A-s):  -0.002
Concentration  (ug/L  ):  -1.5

Mean Cone   -------
Concentration   :  0.00£                  Peak Height  :  -0.001                 Peak Height (A): 0.005
Background Pk  Area  (A-s):  0.000        Background Pk Height (A): 0.005
Blank Corrected Pk  Area  (A-s):  -0.001
Concentration  (ug/L  ):  -0.8

uL dispensed:  5 from  0,  5  from  39,  £0 from £5
Replicate   £  (Peak  Stored)              Time: 04':£3
Peak Area  (A-s):  0.000                 Peak Height (A): 0.005
Background Pk  Area  -------
Replicate  £ (Peak Stored)
Peak ftrea (fl-s) : 0.088
Background Pk ftrea • (fl-s) : 0.049
Blank Corrected Pk flrea  (ft-s) : 0.088
Concentration -------
Autosanpler Loading Map
          File: TL.BEL
  Loc.  Concentration
    0
    1
    2
    4
    5
    6
    7
    a
    9
   10
   11
   12
   13
   14
   IS
   Ifr
   17
   13
   19
   20
   39
50.0 ug/L
100.0 ug/L
      ID/Weight File: EB165. IDW

Solutions

Calib. Blank  / Diluent / ICB / CCB
Stock l-tO-fcV7
Stock /  Recovery Stock
ICV=30ug/L
CCV=60ug/L
CHECK LO
43231 MB
,43231 LCS
184-23-IftB
184-23-2RB
184-23-2OB
184-23-30B
184-23-4ftB
184-23-6ftB
184-23-7OB
184-23-80B
184-23-9ftB
184-23-HZlflB
183-15-1C
                                                \
-------
.Element'File: TL. GEL
Date.: 10/07/97
'Data File: EB165. DflT
.Technique: HGfl
                       Element: Tl
                       Time: 05:56
                       iD/Wt File: EB165.IDW
                       Calib. Type:  Nonlinear
                              Wavelength: £76.8
                              Slit:  0.70 L
                              Lamp Current: 0
                              Energy: 53
 Tl
ID:  STD BLK
Seq. No. : 00001
fl/S Pos.: 0
Date:  10/07/97
 uL dispensed: 5 from 0, 5 from 39, £0  from  0
 Replicate  1                           Time:  05:58
 Peak Area (fl-s): -0.000                Peak Height (fl):  0.006
 Background Pk flrea (ft-s): 0.015        Background Pk Height  (ft): 0.011
 Blank Corrected Pk flrea (ft-s): 0.001
 Concentration  (ug/L  ): 0.6

 uL dispensed: 5 from 0, 5 from 39, £0  from  0
 Replicate  2 (Peak Stored)
 Peak flrea (fl-s): -0.002
 Background Pk flrea (fl-s): 0.002
 Blank Corrected Pk flrea  (fl-s): -0.001
 Concentration  (ug/L  ): -0.6
                                  Time:  06:01
                                  Peak  Height  (fl):  0.007
                                  Background Pk Height (fl): 0.007
 Mean Cone  (ug/L  ):

 fluto-zero performed.
                     -0.0
          SD: 0.87
               RSDC/O :  7113.54
           * *V *V A/ *\* *V *\»- A* *\* *\» *\* *\* *\* *V A* «\* A* *V *\/ A* *\* *
                                                              «\* *S* "\* A* *%*
 Tl
ID: STDl=25ug/L
Seq. No. : 00002
fl/S Pos. : 1
Date:  10/07/97
 uL dispensed: 15 from 0, 5 from  39,  10  from 1
 Replicate  1                            Time:  06:04
 Peak flrea (fl-s): 0.035                  Peak Height (fl):  0.062
 Background Pk flrea  (fl-s): 0.023         Background Pk Height (fl): 0.035
 Blank Corrected Pk flrea  (fl-s): 0.036
 Concentration (ug/L  ): £1.6

 uL dispensed: 15 from 8, 5 from  39,  10  from 1
 Replicate  2 (Peak Stored)
 Peak flrea (fl-s): 0.034
 Background Pk flrea (fl-s): 0.025
 Blank Corrected Pk flrea  (fl—s): 0.035
 Concentration (ug/L  ): £1.0
                                  Time:  06:07
                                  Peak Height (fl):  0.056
                                  Background Pk Height (fl) : 0.035
 Mean Cone  (ug/L  )
                     21.3
 Standard number 1 applied.   C25.
 Correlation coefficient:  1.000021
 Tl
          SD: 0.41
                                  Slope:  0.0014
                RSDC>4):  1.92
                                      *\f
ID: STD2=50ug/L
Seq. No. : 00003
fl/S Pos. : 1
Date:  10/07/97
 uL dispensed: 5 from 0, 5 from 39, .20  from  1
 Replicate  1                            Time:  06:10
 Peak flrea (fl-s): 0.072                  Peak Height (fl):  0.116
 Background Pk flrea  (fl-s): 0.045         Background Pk Height (fl): 0.072
 Blank Corrected Pk flrea (fl-s): 3.073
 Concentration (ug/L  ): 51.3
                                                                156
-------
Replicate  2  (Peak Stored)
Peak Area  (A—s): 0.072
Background Pk Area  (A-s): (3.044
Blank Corrected Pk Area  (A-s):  8.874
Concentration  (ug/L   ):  51.6
                                 Time: 86:13
                                 Peak Height  (A): 0.113
                                 Background Pk Height  (A): 0.070
Mean Cone   (ug/L   ):
                     51.5
Standard number 2 applied.   C58.0]
Correlation coefficient:  1.00008
          SD: 0.22
                                 Slope: 8.0014
                        RSDCX) : 0.42

Tl
ID:  STD3=100ug/L
Seq.  No.
00004
A/S Pos. :  2
Date: 10/07/97
uL dispensed: 5  from  0,  5 from 39,  28 from 2
Replicate   1                            Time: 86:16
Peak Area  (A-s):  0:134                 Peak Height (A): 0.218
Background  Pk Area  (A-s): 0.082        Background Pk Height (A): 0.134
Blank Corrected  Pk  Area  (A-s): 8.135
Concentration  (ug/L  ):  88.1

uL dispensed: 5  from  8,  5 from 39,  28 from 2
Replicate  2  (Peak  Stored)
Peak Area  (A-s):  8.137
Background Pk  Area  (A-s):  8.881
Blank Corrected Pk  Area (A-s):  8.138
Concentration  (ug/L  ): 98.8
                                 Time: 86:19
                                 Peak Height  (A):  8.215
                                 Background Pk  Height  (A)
                                    8. 129
Mean Cone   (ug/L   )
                     89.8
          SD: 1.36
                        RSDCX):  1.53
S-shaped  calibration curve detected.  2-coef.  equation used.
Standard  number  3 applied.   C188.8]
Correlation  coefficient:  8.99944       Slope: 8.8815
                                  Calibration - C:\Aft_U •
                        I. «4
                          a.a
                                   Concentration
                                                            157
-------
Element, File: TL. BEL
Date: 10/07/97
Data File: EB165. DftT
Technique: HGfl
                       Element: Tl
                       Time: 06:20
                       ID/Wt File:  EB165.IDW
                       Calib. Type:  Nonlinear
                                                            Wavelength: £76.8
                                                            Slit: 0.70 L
                                                            Lamp Current: 0
                                                            Energy: 53
Tl
ID: ICV=30ug/L
                              Seq.  No.:  00005
fl/S Pos.: 4
Date: 10/07/97
uL dispensed: 5  from  0,  5 from 39,  £0 from 4
Replicate  1                            Time: 06:£3
Peak flrea  (fl-s): 0.044                  Peak Height (fl) : 0.074
Background Pk ftrea  :  0.027        Background Pk Height  (ft): 0.04£
Blank Corrected  Pk  flrea  (fl-s):~0.045
Concentration (ug/L  ):  31. £

uL dispensed: 5  from  0,  5 from 39,  £0 from 4
Replicate  £  (Peak  Stored)              Time: 06:£&
Peak flrea  (fl-s): 0.043                  Peak Height (ft): 0.069
Background Pk ftrea  (fl-s):  0.028        Background Pk Height  (ft): 0.039
Blank Corrected  Pk  flrea  (fl-s): 0.044
Concentration (ug/L  ):  30. £
Mean Cone   (ug/L   ):        30.7        SD:  0.66

QC sample  is  within range £7.0 - 33.0
                                                          RSD<*> : £. 15
 * f\f A* ^f *\* *\* *V A* A* *\* *V *\* *\* *\* *V
Tl
ID: ICB
                              Seq.  No.:  00006
fl/S Pos. : 0
Date: 10/07/97
uL dispensed:  5  from  0,  5 from 39,  £0 from 0
Replicate   1                            Time: 06:£9
Peak flrea  (fl-s):  0.001                  Peak Height  (ft): 0.006
Background  Pk  flrea (fl-s): 0.004        Background Pk Height  (ft): 0.006
Blank Corrected  Pk flrea  (fl-s): 0.00£
Concentration  (ug/L  ):  1.5

uL dispensed:  5  from  0,  5 from 39,  £0 from 0
Replicate  £  (Peak Stored)
P'eak flrea  (fl-s): -0.001
Background Pk flrea  (fl-s):  0.004
Blank Corrected Pk flrea  (fl-s):  O.000
Concentration  (ug/L   ):  0. £

Mean Cone  (ug/L  ):         0. 9

QC sample  is within range  —£.0 -  £. 0
                                        Time: 06:3£
                                        Peak Height (fl): 0.006
                                        Background Pk Height  (fl): 0.006
                                 SD: 0.98
                                                                RSDCX):  114.92
                                          *»
Tl
ID: CHECK LO
                              Seq.  No.:  00007
fl/S Pos. : 6
Date: 10/07/9:
uL dispensed: 5  from  0,  5  from  39,  £0 from 6
Replicate   1                            Time: 06:35
Peak ftrea  (ft-s):  0.005             '     Peak Height (ft): 0.014
Background  Pk ftrea  (ft-s):  0.008        Background Pk Height  (fl): 0.011
Blank Corrected  Pk  flrea  (fl-s):  0.007
Concentration  (ug/L  ):  4.5

uL dispensed: 5  from  0,  5  from  39,  £0 from 6
                                                            158
-------
              \ i- cr can
     ftr^a  (fl-s): 0.007                  Peak Height  (fl) : 0.013
background Pk Area  (fl-s):  0.008        Background Pk Height   : 18.40
Tl    ID: 43231 MB            Seq.  No. : 00008    ft/S Pos. :  7      Date:  10/07/97

uL dispensed: 5 from  0,  5 from 39, 20 from 7
Replicate   1                   ..         Time: 06:40
Peak flrea  (fl-s) :  0.002                 Peak Height  (fl) :  0.006
Background  Pk flrea  (fl-s) : 0.003        Background Pk Height  (ft):  0.007
aiank Corrected Pk  flrea (fl-s) : 0.003
Concentration  (ug/L  ):  2.0

uL dispensed: 5 from  0,  5 from 39, 20 from 7
Replicate   2  (Peak  Stored)             Time: 06:43
Peak flrea  (fl-s) :  0.001                 Peak Height  (fl) :  0.007
Background  Pk flrea  (fl-s): 0.003        Background Pk Height  (fl) :  0.006
Blank Corrected Pk  flrea (fl-s): 0.002
Concentration  (ug/L  ):  1.3

Mean Cone   (ug/L   ):         1.6        SD: 0.51                 RSDC/O: 31.03
                                           *\* »\* *\/ A* *\* *V A* *\/ *\/ *
Tl     ID:  43231  LCS          Seq. No.: 08009    fl/S  Pos.:  8     Date: 10/07/97

uL dispensed:  5  from 0,  5 from 39, 20 from 8
Replicate   1                            Time: 06:46
Peak  flrea  (fl-s): 0.065                 Peak Height  (fl) :  0.097
Background Pk  flrea (fl-s): 0.040        Background Pk Height (fl) :  0.058
Blank Corrected  Pk flrea  (fl-s): 0.066
Concentration  (ug/L  ) :  46. 1

uL dispensed:  5  from 0,  5 from 39, 20 from 8
Replicate   2  (Peak Stored)             Time: 06:49
Peak  flrea  (fl-s): 0.064                 Peak Height  (fl) :  0.098
Background Pk  flrea (fl-s): 0.040        Background Pk Height (fl) :  0.058
Blank Corrected  Pk flrea  (fl-s): 0.065
Concentration  (ug/L  ):  45.2

Mean  Cone   (ug/L  ):       45.6        SD: 0.60                 RSDC>O : 1.32
                                   ff^f\f^f^t^f^f^
Tl     ID:  184-23-lflB         Seq. No. : 00010    fl/S  Pos. :  9     Date: 10/07/97

uL dispensed:  5 from 0,  5 from 39, 20 from 9
Replicate   1                            Time: 06:52
Peak  flrea  (fl-s):  0.004                 Peak Height  (fl) :  0.008
Background Pk  flrea (fl-s): 0.639   .     Background Pk Height (fl) :  0.287
Blank Corrected Pk flrea (fl-s): 0.005
Concentration  (ug/L  ):  3.5

uL dispensed:  5 from 0,  5 from 39, 20 from 9
Replicate   2  (Peak Stored)             Time: 86:55
Peak  flrea  (fl-s):  0.003                 Peak Height  (fl) :  0.889
                                                           159
-------
      -o unu i- r\ 1-11
Blank Corrected Pk Area   :  0.004
Concentration   : 0. 5b9
Blank Corrected Pk  Area  :~ 0.006
Concentration   :  1.042        Background Pk Height (A): 0.415
Blank Corrected Pk  Area   :  0.006
Concentration  (ug/L ): 3.7

Mean Cone   (ug/L  ):         4.1        SD: 0.46                 RSDCX):  11.21
Tl     ID:  184-23-2AB  PDS      Seq.  No. :  00012    A/S Pos. : 10    Date:  10/07/9
uL dispensed:  5  from  39,  5 from 2,  £0 from 10
Replicate   1                            Time:  07:04
Peak Area  (A-s):  0.005                  Peak Height (A): 0.011
Background  Pk  Area  (A-s):  1.043        Background Pk Height  (A): 0.421
Blank Corrected  Pk  Area  (A-s):  0.007
Concentration  (ug/L  ):  4.5

uL dispensed:  5  from  39,  5 from £,  £0 from 10
Replicate   2  (Peak  Stored)              Time:  07:07
Peak Area  (A-s):  0.007                  Peak Height (A): 0.009
Background  Pk  Area  (A-s):  0.973        Background Pk Height  (A): 0.404
Blank Corrected  Pk  Area  (A-s):  0.008
Concentration  (ug/L  ) :  5. 6

Mean Cone   (ug/L ):         5.0        SD: 0.73                RSD(K):  14.38

Recovery  is 3.9%    (outside of specified limits)


Tl    ID:  184-23-2AB  L        Seq.  No.: 00013    A/S Pos.: 11    Date:  10/07/97

uL dispensed:  5  from  0,  5 from  39,  20 from 11
Replicate   1                            Time:  07:09
Peak Area  (A-s):  0.002                  Peak Height (A): 0.008
Background  Pk  Area  (A-s):  0.268        Background Pk Height  (A): 0.139
Blank Corrected  Pk  Area  (A-s):  0.004
Concentration  (ug/L  ):  £.5

uL dispensed:  5  from  0,  5 from  39,  £0 from 11
Replicate   £  (Peak  Stored)              Time:  07:12
Peak Area  (A-s):  0.001                  Peak Height (A): 0.011
                                                            160
-------
                                        i^c\\_ r\ h
Blank Cprrected Pk ftrea  :  1.9

uL dispensed:  5  from  0,  5 from 39,  20 from 11
Replicate  2  (Peak Stored)
Peak flrea  (fl-s) : 0.005
Background Pk flrea  (fl-s): 0.259
Blank Corrected Pk flrea  (fl-s) : 0.006
Concentration  (ug/L   ):  4.3
                                        Time: 07:18
                                        Peak Height (A): 0.012
                                        Background Pk Height  (fl) : 0.148
Mean Cone   (ug/L  ):
                            3.1
                                        SD: 1.74
                                                                RSDCX): 5&. 01

Tl
       ID:  184-23-2flB L
                             Seq.  No.:  00015
                                                 fl/S Pos.: 11
                                                                 Date:  10/07/97
uL dispensed:  5  from  39,  5  from  2,  20 from 11
Replicate   1                            Time:  07:21
Peak flrea  (fl-s):  0.005                  Peak Height (fl) :  0.016
Background  Pk  flrea  (fl-5> : 0.288         Background Pk Height (fl)
Blank Corrected  Pk  flrea (fl-s): 0.006
Concentration  (ug/L  ):  4.2

uL dispensed:  5  from  39,  5  from  2,  20 from 11
                                                                  0.158
Replicate  2  (Peak Stored)
Peak flrea  (fl-s): 0.006
Background Pk flrea  (fl-s): 0.306
Blank Corrected Pk flrea  (fl-s) : 0.007
Concentration  (ug/L   ):  5.1
                                        Time: 07:24
                                        Peak Height (fl) : 0.014
                                        Background Pk Height (fl)
                                                                  0.168
Mean Cone   (ug/L   ):         4.7        SD: 0.58

Recovery is 6.1%     (outside of specified limits)
                                                                RSD(X):  12.52
Tl
       ID:  184-23-3flB
                             Seq.  No.:  00016
                                                 fl/S Pos.: 12
                                                                 Date:  10/07/97
uL dispensed:  5 from 0,  5 from 39,  20 from 12
Replicate   1                            Time: 07:27
Peak  flrea  (fl-s): 0.015                 Peak Height (ft): 8.024
Background  Pk  flrea (fl-s): 1.116   .     Background Pk Height  (fl) : 0.484
Blank Corrected Pk flrea (fl-s): 0.016
Concentration  (ug/L  ): 10.8

uL dispensed:  5 from 0,  5 from 39,  20 from 12
Replicate   2  (Peak Stored)              Time: 07:29
Peak  flrea  (fl-s): 0.013                 Peak Height (fl) : 0.020
                                                           161
-------
oacKgrouna KK urea  SH— s; :  10. v*-j        oai-nyr u«-unj m ric o.yn\,  \n/ .  v. ^j,_»i
Blank Corrected Pk  Area (fl-s):  0.014
Concentration  : 9.4

Mean Cone   :  9.61
Tl    ID: CCV=60ug/L         Seq.  No. :  00017    A/S Pos. : 5     Date:  10/07/97

uL dispensed: 5  from 0,  5 from 39,  £0 from 5
Replicate   1                            Time: 07:32
Peak Area  (fl-s) :  0.073                 Peak Height  (ft): 0.184
Background  Pk Area (fl-s): 0.053        Background Pk Height  (A):  0.113
Blank Corrected  Pk Area (A-s) : 0.079
Concentration  :  55. &

uL dispensed: 5  from 0,  5 from 39,  £0 from 5
Replicate   £  (Peak Stored)             Time: 07:35
Peak Area  (A-s) :  0.086                 Peak Height  (ft): 0.182
Background  Pk flrea (fl-s) : 0.053        Background Pk Height  (A):  0.106
Blank Corrected  Pk Area  : 0.087
Concentration  (ug/L  ):  61.4

Mean Cone    :  -0.000                Peak Height  (ft): 0.007
Background Pk  flrea : 2.2

uL dispensed:  5 from 0,  5 from 39,  20 from 13



                                                            162
-------
        e  t.  \ r- «s «a n OVUIBU/              i » MIC • v ( • -r(
Peak Anea  (A-s): -0.0191                 Peak Height (A): 0.006
Background Pk Area  (A-s> :  0.065        Background Pk Height (A): 0.051
Blank Corrected Pk Area  
-------
Blank Corrected Pk Area  (A-s):  0.003
Concentration  (ug/L   ):  1.9

Mean Cone   (ug/L  ):         1.3        SD: 0. 92                RSDOC): 71.03

Tl    ID:  184-23-9AB          Seq.  No. : 00023    A/S Pos. : 17    Date:  10/07/97

uL dispensed: 5  from  0,  5 from 39,  £0 from 17
Replicate   1                            Time: 08:07
Peak Area  (A-s) :  0.001                  Peak Height (A): 0.007
Background Pk Area   : 0.002        Background Pk Height   : 0.006
Blank Corrected  Pk  Area :~ 0.002
Concentration  (ug/L  ):  1.2

uL dispensed: 5  from  0,  5 from 39,  20 from 17
Replicate   2  (Peak  Stored)              Time: 08:10
Peak Area  (A-s) :  -0.002                Peak Height (A): 0.007
Background Pk Area  (A-s): 0.004        Background Pk Height  (A): 0.006
Blank Corrected  Pk  Area (A-s): -0.001
Concentration  (ug/L  ):  -0.4

Mean Cone   (ug/L  ):         0.4        SD: 1.10                 RSD(K):  272.77
                             * *\* *V *\* A* *
Tl     ID:  184-23-10AB 5      Seq.  No. : 00024    A/S Pos. : 18    Date:  10/07/97

uL dispensed:  5 from 0,  5 from 39, 20 from 18
Replicate   1                            Time: 08:12
Peak  Area  (A-s): 0.001                 Peak Height  (A): 0.006
Background Pk  Area (A-s): 0.095        Background Pk Height  (A): 0.069
Blank Corrected Pk Area (A-s): 0.002
Concentration  (ug/L  ): 1.6

uL dispensed:  5 from 0,  5 from 39, 20 from 18
Replicate   2  (Peak Stored)              Time: 08:15
Peak  Area  (A-s): 0.003                 Peak Height  (A): 0.007
Background Pk  Area (A-s): 0.089        Background Pk Height  (A): 0.064
Blank Corrected Pk Area (A-s): 0.004
Concentration  (ug/L  ): 2.6

Mean  Cone   (ug/L  ):        2.1        SD: 0. 73                RSDC/O: 34.37
Tl     ID:  184-23-10AB 5      Seq. No.: 00025    A/S Pos.: 18    Date:  10/07/97

uL  dispensed:  5 from 0,  5 from 39, 20 from 18
Replicate   1                            Time: 08:18
Peak  Area  (A-s):  0.000                 Peak Height  (A): 0.006
Background Pk  Area (A-s): 0.088        Background Pk Height  (A): 0.065
Blank Corrected Pk Area (A-s): 0.002
Concentration  (ug/L  ) :  1. 1

uL  dispensed:  5 from 0,  5 from 39, 20 from 18
Replicate   2  (Peak Stored)              Time: 08:21
Peak  Area  (A-s):  -0.001                Peak Height  (A): 0.006
Background Pk  Area (A-s): 0.086        Background Pk Height  (A): 0.072
Blank Corrected Pk Area (A-s): 0.000
                                                             164
-------
           ion \ug/i_  > : 10. c
   c    *
Mean Cone   (ug/L  ):        0.7        SD: 0.67                 RSDCX):  103.21

^^^r^^^^ «^^^«^«^^^^^^f ^^ ^^«^*^^f j^^^j^j^f^ j^f^^^^^^^^*^ ^^A? ^V^tf ^v^*A*^v AfAr Af^v^^^v A«*\*'^'V^'^^tf ^w^tf ^w^^^v^v 'W Ar A#^W^V^*^tf ^^^^ A*^^ A*^v*V^tf A*^v^^tf '^'^^^^' *
Tl     ID:  183-15-1C           Seq.  No.: 000£6    fl/S Pos. :  19    Date: 10/07/97

uL dispensed: 5 from 0, 5 from  39,  £0 from 19
Replicate   1                            Time: 08:24
Peak Area  (fl-s): -0.001                 Peak Height  (fl) s 0.007
Background Pk flrea  (ft-s) : 0.003        Background Pk Height (ft): 0.008
Blank  Corrected Pk ftrea  : 0.001
Concentration (ug/L ):  0.5

Mean  Cone  (ug/L  ):         0.9        SD: 0.65                 RSDC/O:  69.38
*\* *V *\» *V *V *\* *V A* *it *\* A* f\f *\* *V *V *V *\* *\* *\* 'Vr *\* *\* *\/ *\* *
Tl     ID: CCV=60ug/L          Seq.  No.: 000£8     fl/S  Pos. :  5     Date:  10/07/97

uL dispensed: 5 from 0, 5  from 39,  £0 from 5
Replicate  1                            Time: 08:36
Peak  flrea (fl-s) : 0.085                  Peak Height  (fl) :  0.156
Background Pk flrea  (fl-s):  0.048        Background Pk Height (fl) : 0.089
Blank Corrected Pk flrea  (fl-s): 0.086
Concentration  (ug/L  ): 60.8

uL dispensed: 5 from 0, 5  from 39, .£0 from 5
Replicate  £ (Peak Stored)              Time: 08:39
Peak  flrea (fl-s): 0.075                  Peak Height  (fl) :  0.136
Background Pk flrea  (fl-s):  0.044        Background Pk Height (fl) : 0.078
Blank Corrected Pk ftrea  (ft-s): 0.076
Concentration  (ug/L  ): 53.7
                                                              165
-------
QC sample is within range 48.0 - 72.0
Tl    ID: CCB                Seq. No.: 00029    A/S Pos. : 0     Date:  10/07/97

uL dispensed: 5 from 0, 5 from 39, 20 from  0
Replicate  1                           Time: 08:42
Peak Area   : -0.001                Peak Height  (ft):  0.006
Background Pk Area  (A-s) : 0.002        Background Pk Height  (A):  0.005
Blank Corrected Pk  Area -------
Element*. Files TL_MSA. GEL      Element:  Tl                   Wavelength: £76.8
Date: 10/07/97                Time:  09:01                   Slit: 0.70 L
Data File: EB1&5. DAT          ID/Wt  File: EB1&5. IDW         Lamp Current: 0
Technique: HGA                Calib.  Type: Meth.  of Add.    Energy: 53
Tl    ID: AUTO ZERO           Seq.  No. :  00031    A/S Pos. : 0     Date: 10/07/97

uL dispensed:  10  from  0,  5  from  39,  10 from 0
Replicate   1                            Time: 09:03
Peak Area  (A-s) :  0.000                 Peak Height (A): 0.005
Background  Pk Area  -------
ui_ aispensea: o rrom »i"3,  i<0 rrom e,  iw ri-om -y
Replicate  1             .               Time: 09:21
Peak Area  (A-s): 0.004                  Peak Height (A): 0.009
Background Pk Area  100 is not allowed.  No calibration has occurred.
Tl    ID:  184-23-1AB          Seq. No. : 80832    A/S Pos. : 9     Date:  10/07/97
Concentration  (ug/L   ):
Tl    ID: AUTO  ZERO           Seq.  No. :  00035    A/S Pos. : 0     Date:  10/07/9"/

uL dispensed: 10 from  0,  5 from 39,  10  from 0
Replicate   1                            Time: 09:27
Peak Area   : 0.001                 Peak Height (A): 0.007
Background  Pk Area  -------
     Hrea  m— s; : 10. we:
Background Pk ftrea  (ft-s):  0.632
Blank Corrected Pk ftrea (fl-s): 0.002
                                             neigng  VH/ :  ««.
                                        Background Pk Height  (ft):  0. 266
uL dispensed: 5  from  39,  10 from 1, 10 from  10
Replicate  2  (Peak  Stored)              Time: 09:41
Peak ftrea  (ft-s) : 0.003                 Peak  Height   :  0.010
Background Pk flrea   :  0.661        Background Pk  Height  (ft):  0. 284
Blank Corrected  Pk  ftrea (ft-s): 0.003

Mean Pk ftrea  (ft-s):      0.003         SD: 0.0006               RSD(%): 22.68

Tl    ID: ODD 2  100ug/L      Seq. No. : 00038    fl/S Pos. :  10    Date: 10/07/97

uL dispensed: 5  from  39,  10 from 2, 10 from  10
Replicate  1                            Time: 09:44
Peak ftrea  (ft-s): 0.004                 Peak  Height  (ft):  0.010
Background Pk ftrea  (ft-s) :  0.664        Background Pk  Height  (ft):  0.280
Blank Corrected  Pk  ftrea (ft-s): 0.004

uL dispensed: 5  from  39,  10 from 2, 10 from  10
Replicate  2  (Peak  Stored)              Time: 09:47
Peak ftrea  (fl-s): 0.001                 Peak  Height  (ft):  0.008
Background Pk ftrea  (ft-s):  0.662        Background Pk  Height  (ft):  0.279
Blank Corrected  Pk  ftrea (ft-s): 0.001
Mean Pk flrea  (fl-s):
0.003
                                         SD:  0.0017
Expansion  ) 100 is not allowed. No calibration  has  occurred.
Tl     ID:  184-23-2flB         Seq. No. :  00036     fl/S Pos. :  10
                                                                 RSDC/O: 63.99
                                                                  Date: 10/07/97
Concentration (ug/L  ):
        *\* «V A* «V *\» A/ *V *\* 
-------
uL dispensed:  10  from 0, 5 from  39,  10 front 12
Replicate  2  (Peak Stored)              Time:  09:58
Peak Area  (fl-s):  0.007                  Peak Height (fl) :  0.012
Background Pk  flrea  (fl-s): 0.575         Background Pk Height (ft): 0.278
Blank Corrected Pk flrea  : 0.007

Mean Pk Area  :  0.007                  Peak Height (fl> :  0.012
Background Pk  flrea  : 0.574         Background Pk Height (fl): 0.277
Blank Corrected Pk flrea  : 0.007

uL dispensed:  5 from 39, 10  from 1,  10 from 12
Replicate  2  (Peak Stored)              Time:  10:04
Peak flrea  : 46.60

Tl    ID: flDD  2 100ug/L       Seq.  No. : 00042    fl/S Pos. : 12    Date: 10/07/9

uL dispensed:  5 from 39, 10  from 2,  10 from 12
Replicate  1                            Time:  10:07
Peak flrea  (fl-s):  0.003                  Peak Height (fl):  0.010
Background Pk  flrea  (fl-s): 0.342         Background Pk Height (fl): 0.194
Blank Corrected Pk flrea  (fl-s): 0.003

uL dispensed:  5 from 39, 10  from 2,  10 from 12
Replicate  2  (Peak Stored)              Time:  10:10
Peak flrea  (fl-s):  0.002                  Peak Height (fl):  0.010
Background Pk  flrea  (fl-s): 0.323         Background Pk Height (fl): 0.198
Blank Corrected Pk flrea  (fl-s): 0.002

Mean Pk flrea  (fl-s):      0.002          SD: 0.0007              RSD(5O: 32.76

Standard abs.  & cone, values are not in the same order.
Tl    ID:  184-23-3flB          Seq.  No.: 00040    fl/S Pos.: 12    Date: H3/07/S
Concentration  (ug/L   ):
Tl     ID:  ftUTO ZERO          Seq.  No.: 00043    fl/S Pos.: 0     Date: 10/07/97

uL dispensed:  10 from 0,  5  from  39,  10 from 0
Replicate   1                            Time: 10:13
Peak flrea  (fl-s):  -0.001            _     Peak Height (fl):  0.007
Background Pk  flrea (fl-s): 0.001    '     Background Pk Height (fl): 0.005
Blank  Corrected Pk ftrea  (fl-s): -0.001

uL dispensed:  10 from 0,  5  from  39,  10 from 0
Replicate   2  (Peak Stored)              Time: 10:16
Peak flrea  (fl-s):  -0.000                 Peak Height (fl):  0.005
                                                          170
-------
Blank Cprrected Pk Area   : 0.004         Background Pk Height (A): 0.005
Blank Corrected Pk  Area   : 0.010         Background Pk Height (A): 0.013
Blank Corrected Pk  Area  (A-s): 0.011

uL dispensed:  5 from 39,  10 from 1,  10  from 13
Replicate   2  (Peak  Stored)              Time: 10:27
Peak Area  (A-s):  0.009                 Peak Height (A): 0.019
Background  Pk  Area  (A-s): 0.009         Background Pk Height (A): 0.013
Blank Corrected Pk  Area  (A-s): 0.010

Mean Pk Area  (A-s):       0.011          SD: 0.0010              RSDCX): 9.49

Tl    ID:  ADD  2 100ug/L       Seq.  No.:  00046    A/S Pos.: 13    Date: 10/07/97

uL dispensed:  5 from 39,  10 from 2,  10  from 13
Replicate   1                            Time: 10:30
Peak Area  (A-s):  0.018                 Peak Height (A): 0.026
Background  Pk  Area  (A-s): 0.016         Background Pk Height (A): 0.021
Blank Corrected Pk  Area  (A-s): 0.018

uL dispensed:  5 from 39,  10 from 2,  10  from 13
Replicate   2  (Peak  Stored)              Time: 10:33
Peak Area  (A-s):  0.016                 Peak Height (A): 0. 026
Background  Pk  Area  (A-s): 0.016         Background Pk Height (A): 0.021
Blank Corrected Pk  Area  (A-s): 0.017

Mean Pk Area  (A-s):       0.018          SD: 0.0009              RSDCX): 4.98  .

The standard additions calibration curve may not be linear.
Tl    ID:  184-23-4AB          Seq.  No. :  00044    A/S Pos. : 13    Date: 10/07/97
                                                          171
-------
Correlation coefficient:  0.96016
                                        Slope:  0.0002
                        "Pisplau Calibration - Ci
Tl
      ID: AUTO ZERO
Seq.  No. : 00847
                   A/S Pos. : 0
Date: 10/07/97
uL dispensed:  10 from 0,  5  from  39,  10
Replicate  1
Peak Area  (A-s): -0.001
Background Pk  Area  (A-s): 0.002
Blank Corrected Pk  Area  (A-s): -0.001

uL dispensed:  10 from 0,  5  from  39,  10
Replicate  2  (Peak  Stored)
Peak Area  (A-s): -0.001
Background Pk  Area  (A-s): 0.001
Blank Corrected Pk  Area  (A-s): -0.000
                                        from 0
                                        Time: 10:36
                                        Peak Height (A) : 0.005
                                        Background Pk Height  (A): 0.005
                                        from 0
                                        Time: 10:39
                                        Peak Height (A): 0.006
                                        Background Pk Height  (A): 0.004
Mean Pk  Area (A-s):

Auto—zero  performed.
                         -0.000
          SD: 0.0001
                                   RSD C/.):  20.56
              *\»*V *V *V *\* *V *\* A» *W 'V *\» A* A* A*
Tl
      ID:  184-23-6AB
Seq. No.: 00048
                   A/S Pos. :  14
Date: 10/07/97
uL dispensed: 10 from 0, 5  from  39,  10
Replicate   1
Peak Area  (A-s): -0.001            .
Background  Pk Area  (A-s): 0.002
Blank Corrected Pk  Area  (A-s): -0.000

uL dispensed: 10 from 0, 5  from  39,  10
Replicate   2  (Peak  Stored)
Peak Area  (A-s): -0.003
Background  Pk Area  (A-s): 0.004
Blank Corrected Pk  Area  (A-s): -0.002
                                        from 14
                                        Time: 10:42
                                        Peak Height (A): 0.007
                                        Background Pk Height  (A): 0.008
                                        from 14
                                        Time:  10:45
                                        Peak Height (A): 0.005
                                        Background Pk Height  (A): 0.006
                                                           172
-------
Tl    ID: ODD 1 50 ug/L      Seq.  No.:  00049    A/S Pos. :  14    Date: 10/07/97

uL dispensed: 5 from 39,  10  from  1,  10 from 14
Replicate  1                            Time: 10:48
Peak Area  : 0.008                  Peak Height (A): 0.013
Background Pk Area  
-------
                                   Calibration -
                        1.0ft.,
                          3.3
                                   Concentration
                                             100.0
                                   '\f^^
Tl
ID: ftUTO ZERO
                              Seq. No.:  00051
                                                  ft/S Pos.: 0
Date:  10/07/97
uL dispensed:  10 from 0, 5 from 39,  10
Replicate   1
Peak flrea  (A-s): -0.001
Background  Pk  Area (A-s): -0.000
Blank  Corrected Pk Area  (A-s): 0.001

uL dispensed:  10 from 0, 5 from 39,  10
Replicate   2  (Peak Stored)
Peak Area  (A-s): -0.001
Background  Pk  ftrea (fl-s): 0.000
Blank  Corrected Pk ftrea  (ft-s)s 0.000
                                  from 0
                                  Time: 11:00
                                  Peak Height  (ft):  0.005
                                  Background Pk Height  (ft): 0.006
                                  from 0
                                  Time: 11:03
                                  Peak Height  (A): 0.007
                                  Background Pk Height  (A): 0.005
Mean Pk  Area (A-s):

Auto-zero  performed.


Tl     ID:  18A-23-7fiB
                          0.000
                                  SD: 0.0003
                                                                  RSDC/O :  104.79
                                       *^ *V^ *W*\**%* *\*'\»^w^**^ ^* *V*W*\/*V*V*^*\**%/*\* *\* *^*VV*N**X* *\* *\* ^»*V*V ^*^**\^*W^^ A* ^,

                              Seq. No.:  00052    ft/S Pos.: 15     Date: 10/07/97
uL dispensed:  10 from 0,  5 from 39,  10
Replicate   1
Peak ftrea  (ft-s): -0.001
Background  Pk  ftrea (ft-s): 0.002
Blank Corrected Pk ftrea (ft-s) s -0.000

uL dispensed:  10 from 0,  5 from 394  10
Replicate   2.  (Peak Stored)
Peak ftrea  (ft-s): -0.001
Background  Pk  ftrea (fl-s> : 0.002
Blank Corrected Pk flrea (fl-s) : -0.000

Mean Pk  ftrea  (ft-s):     -0.000

Tl    ID: ODD  1 50 ug/L      Seq. No.:
                                  from 15
                                  Time:  11:05
                                  Peak Height  (ft): 0.007
                                  Background Pk Height  (ft):
                                                                    0.005
                                         from 15
                                         Time:  11:08
                                         Peak Height (ft): 0.006
                                         Background Pk Height  (ft):  0.009
                                         SD:  0.0002               RSDC/): 121.22

                                         00053    ft/S Pos.: 15     Date: 10/07/97
                                                               174
-------
uL dispensed: 5 from 39,  10 from  1,
Replicate  1
Peak Area  (A-s): 0.006
Background Pk Area  (A-s): 0.010
Blank Corrected Pk  Area  : 0.006

uL dispensed: 5 from 39,  10 from  1,  10
Replicate  £  (Peak  Stored)
Peak Area  (A-s): 0.007
Background Pk Area  : 0. 0®9
Blank Corrected Pk  Area  
-------
Tl .    ID: AUTO  ZERO           Seq.  No.: 00055    A/S Pos. : 0     Date:  10/07/97

uL dispensed: 10  from 0,  5 from 39,  10 from 0
Replicate   1                            Time: 11:23
Peak Area  (A-s) :  -0.002                Peak Height (A): 0. 006
Background  Pk Area  (A-s): 0.0(92        Background Pk Height (A): 0.036
Blank Corrected Pk Area (A-s) :  -0.001

uL dispensed: 10  from 0,  5 from 39,  10 from 0
Replicate   2  (Peak Stored)             Time: 11:26
Peak Area  (A-s):  -0.002                Peak Height (A): 0.004
Background  Pk Area  (A-s): 0.002        Background Pk Height (A): 0.003
Blank Corrected Pk Area (A-s):  -0.001

Mean Pk Area  (A-s):      -0.001          SD: 0.0001               RSD<%):  5.89

Auto-zero  performed.
ArAfAtA* A* A* A* A* A* A* A» A* A* A»
Tl    ID:  184-23-8AB         Seq.  No.: 00056    A/S Pos.: 16     Date:  10/07/97

uL dispensed: 10 from 0,  5 from 39,  10 from 16
Replicate   1                            Time: 11:29
Peak Area  (A-s): 0.000                 Peak Height (A): 0.005
Background Pk Area (A-s): 0.002        Background Pk Height  (A):  0.006
Blank Corrected Pk Area (A-s): 0.002

uL dispensed: 10 from 0,  5 from 39,  10 from 16
Replicate  2  (Peak Stored)             Time: 11:32
Peak Area  (A-s): -0.001                Peak Height (A): 0.005
Background Pk Area (A-s): 8.005        Background Pk Height  (A):  0.006
Blank Corrected Pk Area (A-s): 0.001

Mean Pk Area  (A-s):      0.002         SD: 0.0010               RSD<*>: 61.55

Tl    ID:  ADD 1 50 ug/L      Seq.  No.: 00057    A/S Pos.: 16     Date:  10/07/9

uL dispensed: 5 from 39,  113 from 1,  10 from 16
Replicate   1                            Time: 11:35
Peak Area  (A-s): 0.009                 Peak Height (A): 0.015
Background Pk Area (A-s): 0.011        Background Pk Height  (A):  0.012
Blank Corrected Pk Area (A-s): 0.011

uL dispensed: 5 from 39,  18 from 1,  10 from 16
Replicate  2  (Peak Stored)             Time: 11:38
Peak Area  (A-s): 0.010                 Peak Height (A): 0.019
Background Pk Area (A-s): 0.012        Background Pk Height  (A):  0.011
Blank Corrected Pk Area (A-s): 0.012

Mean Pk Area  (A-s):      0.011         SD: 0.0001               RSDC/C): 1.11

Tl    ID:  ADD 2 100ug/L      Seq.  NO.: 00058    A/S Pos.: 16     Date:  10/07/9

uL dispensed: 5 from 39,  10 from 2,  10 from 16
Replicate   1                            Time: 11:41
Peak Area  (A-s): 0.022                 Peak Height (A): 0.030
Background  Pk Area (A-s): 0.019        Background Pk Height  (A):  0.020
Blank Corrected Pk Area (A-s): 0. 024
                                                          176
-------
ui_ aispensea: D  rrom  J»~s,  no rr-oro c,
Replicate  2  (Peak  Stored)
 'eak Area  (A-s):  0.022
 Background Pk Area  (A-s): 0.819
Blank Corrected  Pk  Area (A-s) : 0.024
                                        rr-um  AO
                                        Time:  11:44
                                        Peak  Height  (A):  0.029
                                        Background Pk  Height  (A):  0.020
 lean Pk Area  (A-s) :
                          0.024
          SD: 0.0003
The standard additions calibration curve may not  be  linear.
 '1    ID:  184-23-8AB         Seq. No. : 00056    A/S  Pos. :  16
                                                                 RSDC/O:  1.40
                                                                  Date: 10/07/97
Concentration  :  7.5

Correlation coefficient: 0.98768
                                        Slope: 0.0002
                                   Calibration -
                         e.ex-*-,
                                   C«ncentr otlon
                                                   1B0.9
                 *\* A* A* «V *\* «\* -------
uL dispensed:  10  from 0, 5  from 39,  10 from 17
Replicate  1                            Time:  11:52
Peak Area  (A-s):  -0.001                 Peak Height (A):  0.005
Background Pk  Area  (A-s): 0.004        Background Pk Height (A): 0.007
Blank Corrected Pk  Area  :  -0.001

uL dispensed:  10  from 0, 5  from 39,  10 from 17
Replicate  2  (Peak  Stored)              Time:  11:55
Peak Area  :  0.005
Background Pk  Area  (A-s): 0.004        Background Pk Height (A): 0.006
Blank Corrected Pk  Area  (A-s):  -0.000

Mean Pk Area  (A-s):     -0.001.         SD: 0.0001              RSDCX):  13.61

Tl    ID: ADD  1 50  ug/L       Seq.  No. : 00061     A/S Pos. : 17    Date: 10/07/97

uL dispensed:  5 from  39,  10 from 1,  10 from 17
Replicate  1                            Time:  11:58
Peak Area  (A-s):  0.806                  Peak Height (A):  0.012
Background Pk  Area  (A-s): 0.010        Background Pk Height (A): 0.011
Blank Corrected Pk  Area  (A-s):  0.007

uL dispensed:  5 from  39,  10 from 1,  10 from 17
Replicate  2  (Peak  Stored)              Time:  12:01
Peak Area  (A-s):  0.807                  Peak Height (A):  0.014
Background Pk  Area  (A-s): 0.009        Background Pk Height (A): 0.010
Blank Corrected Pk  Area  (A-s):  0.008

Mean Pk Area  (A-s):      0.008         SD: 0.0306              RSDC/O:  3.17

Tl    ID:  ADD  2 l(30ug/L       Seq.  No.: 00062    A/S Pos.: 17    Date: 10/07/97

uL dispensed:  5 from  39,  10 from 2,  10 from 17
Replicate  1                            Time:  12:04
Peak Area  (A-s):  0.016                  Peak Height (A):  0.026
Background Pk  Area  
-------
                        "JDiselay Calibration *

                                                   -*.»»»*
                          3-0
                                   Conc«ntrotl«n
                                                   10B.D
Tl    ID: flUTO  ZERO
                              Seq.  No.:  00063
         fl/S Pos. : 0
                Date:  10/07/97
uL dispensed:  10 from  0,  5  from 39,  10 from 0
Replicate  1                            Time: 12:10
Peak ftrea  (fi-s): -0.000                 Peak Height : 0.000        Background Pk Height  (ft): 0.00fe
Blank Corrected Pk  ftrea  :  0.000

uL dispensed:  10 from  0,  5  from 39,  10 from 0
Replicate  S  (Peak  Stored)              Time: 12:13
Peak flrea  (ft-s): -0.001                 Peak Height (ft): 0.005
Background Pk  ftrea  (fl-s): 0.001        Background Pk Height  (ft): 0.005
Blank Corrected Pk  ftrea  (ft-s):  0.000
Mean Pk flrea  (fl-s):

fluto—zero performed.


Tl    ID: 184-£3-10flB  5
                          0.000
5D: 0.0003
               RSD(X):  113.96
                              Seq.  No.
00064
fl/S Pos. : 18
                                                                 Date:  10/07/97
uL dispensed:  10 from  0,  5  from  39,  10 from 18
Replicate  1                            Time: 12:16
Peak ftrea  (ft-s): 0.000                 Peak Height (ft): 0.007
Background Pk  flrea  (ft-s): 0.002         Background Pk Height  (ft): 0.006
Blank Corrected Pk  flrea  (fl-s): 0.001

uL dispensed:  10 from  0,  5  from  39,  10 from 18
Replicate  S  (Peak  Stored)              Time: 12:19
Peak flrea  (fl-s): -0.001                 Peak Height (ft)5 0.007
Background Pk  flrea  (ft-s): 0.002         Background Pk Height  (ft) : 0.007
Blank Corrected Pk  flrea  (fl-s): -0.001

Mean Pk flrea  (fl-s):      -0.000          SD:  0.0010              RSDC/O:  1147.58

Tl    ID: flDD  1 50  ug/L       Seq.  No.: 00065    fl/S Pos.: 18    Date: 10/07/97
                                                             179
-------
                           f  iiwui
              «j  i r u in o 7
Replicate   1
Peak Area  (A-s) : 0.013
Background  Pk Area (A-s) :  0.013
Blank Corrected  Pk Area  
-------
Tl •   ID: AUTO ZERO           Seq.  No. :  00067    A/S Pos. : 0     Date: 10/07/97

jiL dispensed: 10  from 0,  5  from 39,  10 from 0
Replicate   1                            Time: 12:34
"Seak Area   :  0.001

JiL dispensed: 10  from 0,  5  from 39,  10 from 0
Replicate   £  (Peak Stored)              Time: 12:37
Peak Area  (A-s) :  0.001                  Peak Height (A): 0.005
Background  Pk Area  (A-s): 0.001        Background Pk Height (A): 0.005
Blank Corrected Pk Area  (A-s):  0.001

Mean Pk Area  (A-s):       0.001          SD: 0. 0004              RSD(S): 36.79

Auto-zero  performed.
Tl     ID:  183-15-1C          Seq.  No. :  00068    ft/S Pos. : 19    Date: 10/07/97

uL dispensed:  10 from  0,  5 from 39,  10 from 19
Replicate   1                            Time: 1£:40
Peak Area  (A-s): -0.001                 Peak Height (A): 0.005
Background Pk  Area (A-s): 0.000        Background Pk Height  (A): 0.006
Blank  Corrected  Pk Area  (A-s):  -0.001

uL dispensed:  10 from  0,  5 from 39,  10 from 19
Replicate   2  (Peak Stored)             Time: 12:42
Peak Area  (A-s): -0.001                 Peak Height (ft): 0.007
Background Pk  Area (ft-s) : 0.000        Background Pk Height  (A): 0.004
Blank  Corrected  Pk Area  (A-s):  -0.001

Mean Pk  Area  (A-s):     -0.001          SD: 0.0004              RSDCX): 32.23

Tl     ID:  ADD  1  50 ug/L       Seq.  No.:  00069    ft/S Pos.: 19    Date: 10/07/97

uL dispensed:  5  from 39,  1C from 1,  10 from 19
Replicate   1                            Time: 12:45
Peak Area  (A-s): 0.005                 Peak Height (ft): 0.013
Background Pk  ftrea (ft-s): 0.006        Background Pk Height  (ft): 0.010
Blank  Corrected  Pk Area  (fl-s) :  0.004

uL dispensed:  5  from 39,  10 from 1,  10 from 19
Replicate   2  (Peak Stored)             Time: 12:48
Peak Area  (A-s): 0.004                 Peak Height (A): 0.012
Background Pk  Area (A-s): 0.006        Background Pk Height  (A): 0.010
Blank  Corrected  Pk Area  (A-s):  0.004

Mean Pk  Area  (A-s):      0.004          SD: 0.0003              RSD(*): 6.56

Tl     ID:  ADD  2  100ug/L       Seq.  No. :  00070    A/S Pos. : 19    Date: 10/07/97

uL dispensed:  5  from 39,  10 from 2,  10 from 19
Replicate   1                            Time: 12:51
Peak Area  (A-s): 0.013                 Peak Height (ft): 0.021
Background Pk  ftrea (fl-s): 0.010        Background Pk Height  (fl) : 0.015
Blank  Corrected  Pk ftrea  (A-s):  0.012
                                                               181
-------
uu dispensed: D  rrom  J^,  iw rrom c,  i\o Trora 1-3
Replicate  2  (Peak  Stored)              Time: 12:54
Peak Area  (A-s):  0.013                 Peak Height  (A):  0.023
Background Pk Area  (A-s):  0.011        Background Pk Height  (A):  0.016
Blank Corrected  Pk  Area :  0.013
Mean Pk Area   :  4.59


                Date:  10/07/91
Concentration  : -0.002                Peak Height   :  0.007
Background  Pk  Area -------
Replicate  1                            Time: 13:03
Peak Area (fl-s): -0.000                 Peak Height (ft) : 0.006
Background Pk flrea  (fl-s): 0.002        Background Pk Height (ft): 0.006
Blank Corrected Pk  ftrea  
-------
M Display Calibration - Ci
0.01*,
                                       184
-------
Tl .   ID: AUTO ZERO           Seq.  No.:  00075    fi/S Pos. :  0     Date: 10/08/97

uL dispensed: 10  from 0,  5  from  39,  10 from 0
Replicate   1                            Time: 00:39
Peak Area  -------
ui_ ui*penseu: u  rram o?,  it>  i r-ura c.,  xv i r-um j
Replicate  2  (Peak Stored)              Time:  01:00
Peak Area  (A-s): 0.002                  Peak Height :  0.007
Background Pk Area  (A-s):  0.240        Background Pk Height (A): 0.133
Blank Corrected  Pk Area  (A-s):  0.003

Mean Pk Area  (A-s):       0.002          SD: 0.0006              RSDC/O : 24.79

Standard abs. &  cone, values  are not in the same order.
Tl    ID:  1S4-23-1AB          Seq.  No.: 0007&     A/S Pos. :  9     Date: 10/08/(
Concentration  (ug/L   ):
Tl    ID: AUTO  ZERO           Seq.  No. :  00079    A/S Pos. : 0     Date:  10/08/97

uL dispensed:  10 from  0,  5 from 39,  10 from 0
Replicate   1       •                     Time: 01:03
Peak Area  (A-s):  -0.000                 Peak Height (A): 0.006
Background  Pk Area (A-s): 0.002        Background Pk Height (A): 0.007
Blank Corrected Pk Area  (A-s):  0.000

uL dispensed:  10 from  0,  5 from 39,  10 from 0
Replicate   2  (Peak Stored)              Time: 01:06
Peak Area  (A-s):  -0.001                 Peak Height (A): 0.006
Background  Pk  Area (A-s): 0.000        Background Pk Height (A): 0.005
Blank Corrected Pk Area  (A-s):  -0.000

Mean Pk  Area  (A-s):       0.000         SD: 0.0004              RSDC/.): 771.8,

Auto-zero  performed.


Tl    ID:  184-23-2AB         Seq.  No. :  00080    A/S Pos. : 10    Date:  18/08/W

uL dispensed:  10 from  0,  5 from 39,  10 from 10
Replicate   1                            Time: 01:08
Peak Area  (A-s):  0.003                 Peak Height (A): 0.011
Background  Pk  Area (fl-s): 0.513        Background Pk Height (A): 0.228
Blank Corrected Pk Area  (A-s):  0.004

uL dispensed:  10 from  0,  5 from 39,  10 from 10
Replicate   2  (Peak Stored)              Time: 01:11
Peak Area  (A-s):  0.002                 Peak Height (A): 0.008
Background  Pk  Area (A-s): 0.510        Background Pk Height (A): 0.240
Blank Corrected Pk Area  (A-s):  0.003

Mean Pk  Area  (A-s):       0.003         SD: 0.0008              RSDCX): 24.54

Tl    ID:  ADD  1 50 ug/L       Seq.  No. :  00081    A/S Pos. : 10    Date:  10/08/< '

uL dispensed:  5 from 39,  10 from 1,  10 from 10
Replicate   1                       .     Time: 01:14
Peak Area  (A-s):  0.003                 Peak Height (A): 0.009
Background  Pk  Area (A-s): 0.521        Background Pk Height (A): 0.243
Blank Corrected Pk Area  (A-s):  0.004

uL dispensed:  5 from 39,  10 from 1,  10 from 10
Replicate   2  (Peak Stored)             Time: 01:17
                                                               186
-------
 Peak  Area (A-s) :  0.0O3                 Peak Height  (m : w.
 Background Pk Area : 0.004

.Mean  Pk Area (A-s):      0.004         SD: 0.0001               RSDCX):  1.97

 Tl     ID: ADD 2 100ug/L      Seq. No.: 00082    A/S Pos.:  10    Date:  10/08/97

 uL  dispensed: 5 from 39, 10 from £,  10 from 10
 Replicate  1                           Time:  01:20
 Peak  Area : 0.005                 Peak Height  : 0.009
 Background Pk Area : 0.528        Background Pk Height  : 0.242
 Blank Corrected Pk Area (A-s):.0.006

 uL  dispensed: 5 from 39, 10 from 2,  10 from 10
 Replicate  2 (Peak Stored)             Time:  01:23
 Peak  Area (A-s): 0.003                 Peak Height  (A): 0.008
 Background Pk Area (A-s): 0.523        Background Pk Height  (A): 0.246
 Blank Corrected Pk Area  (A-s): 0.004

 Mean  Pk Area (A-s):      0.005         SD: 0.0014               RSDCX):  29.94

 Expansion >100 is not allowed. No calibration has occurred.
 Tl     ID: 184-23-2AB         Seq. No.: 00080    A/S Pos.:  10    Date:  10/08/97
 Concentration  (ug/L   )
 Tl    ID: AUTO ZERO           Seq.  No. :  00083    A/S Pos. :  0     Date: 10/08/97

 uL dispensed: 10 from  0,  5  from  39,  10  from  0
 Replicate  1                            Time: 01:26
 Peak Area (A-s): 0.000                 Peak  Height (A):  0.005
 Background Pk Area  (A-s): 0.001         Background Pk Height (A): 0.006
 Blank Corrected Pk Area  (A-s): 0.001

 uL dispensed: 10 from  0,  5  from  39,  10  from  0
 Replicate  2  (Peak Stored)              Time: 01:29
 Peak Area (A-s): -0.002                 Peak  Height (A):  0.003
 Background Pk Area  (A-s): 0.003         Background Pk Height (A): 0.004
 Blank Corrected Pk Area  (A-s): -0.001

 Mean Pk Area  (A-s):      -0.000          SD: 0.0016              RSDC/O: 850.62

 Auto-zero performed.


 Tl    ID: 184-23-3AB          Seq.  No. :  00084    A/S Pos. :  12    Date: 10/08/97

 uL dispensed: 10 from  0,  5  from  39,  10  from  12
 Replicate  1                            Time: 01:32
 Peak Area (A-s): 0.006                 Peak  Height (A):  0.011
 Background Pk Area  (A-s): 0.437    .     Background Pk Height (A): 0.262
 Blank Corrected Pk Area  (A-s): 0.007

 uL dispensed: 10 from  0,  5  from  39,  10  from  12
 Replicate  2  (Peak Stored)              Time: 01:34
 Peak Area (A-s): 0.004                 Peak  Height (A):  0.010
 Background Pk Area  (A-s): 0.423         Background Pk Height (A): 0.232
                                                              187
-------
              u t- t\ n r «r  : 0. A13        Background Pk Height (A): 0.183
Blank Corrected Pk  Area   s  0.005

uL dispensed: 5 from 39,  10  from  1,  10 from 12
Replicate   2   : 0. 00&                  Peak Height (A):  0.009
Background  Pk Area  (A-s) : 0.431        Background Pk Height (A): 0.200
Blank Corrected Pk  Area  (A-s) s  0.007
Mean Pk Area  (A-s):       0.006         SD: 0.0018

Tl     ID:  ADD  2  100ug/L       Seq.  No.: 00086    A/S Pos.: 12
                                                                RSDCX): 30.79

                                                                 Date: 10/08/97
uL dispensed:  5  from  39,  10  from 2,  10 from 12
Replicate   1                            Time: 01:43
Peak Area  (A-s):  0.003                  Peak Height (A): 0.009
Background  Pk  Area  (A-s):  0.442        Background Pk Height (A): 0.200
Blank Corrected  Pk  Area  (A-s) s  0.004

uL dispensed:  5  from  39,  10  from 2,  10 from 12
Replicate   2  (Peak  Stored)              Time: 01:46
Peak Area  (A-s):  0.006                  Peak Height (A): 0.012
Background  Pk  Area  (A-s):  0.429        Background Pk Height (A): 0.194
Blank Corrected  Pk  Area  (A-s):  0. 007
Mean Pk Area  (A-s):
                         0.005
                                        SD: 0.0018
Standard abs. & cone, values  are  not  in  the  same  order.
Tl    ID: 184-23-3AB          Seq.  No. : 00084   A/S Pos.
                                                           12
                                                                RSDC/): 32.93


                                                                 Date:  10/08/97
Concentration  (ug/L  ):
Tl
      ID: AUTO ZERO
                              Seq.  No.:  00087
                                                 A/S Pos.: 0
                                                                 Date:  10/08/9-?
uL dispensed:  10 from  0,  5 from 39,  10 from 0
Replicate   1                            Time: 01:49
Peak Area  (A-s):  -0.001                 Peak Height (A): 0.005
Background  Pk  Area  (A-s):  0.002        Background Pk Height (A): 0.006
Blank Corrected  Pk  Area  (A-s):  -0.000

uL dispensed:  10 from  0,  5 from 39,  10 from 0
Replicate   2  (Peak  Stored)              Time: 01:52
Peak Area  (A-s):  -0.000            .     Peak Height (A): 0.005
Background  Pk  Area  (A-s):  0.002        Background Pk Height (A): 0.005
Blank Corrected  Pk  Area  (A-s):  0.001
Mean Pk Area  (A-s):

Auto— zero performed.
                         0.000
                                        SD: 0.0010
                                                                RSD(tt): 336.56
                                                             183
-------
Tl ,   IB: 184-23-4AB          Seq.  No. :  00088    A/S Pos. :  13    Date: 10/08/97

uL dispensed:  10 from 0, 5  from  39,  10  from 13
Replicate  1                            Time: 01:55
Peak Area : 0.000

uL dispensed:  10 from 0, 5  from  39,  10  from 13
Replicate  2  (Peak  Stored)              Time: 01:58
Peak Area : -0.001                 Peak Height (A):  0.006
Background Pk  Area  -------
                                   Calibration - CiXfift
                        I.O*.
                          -0.1
                                   Concentr o-tlon
                                                   tOB.O
                                                    »\/'\*A*'W^A*A*A*'\*A/'\*A*n*A*'\*'\*'Vn^^'\/A*»VA*'VA*«\* A* A/A*
Tl
ID: AUTO ZERO
Seq. No.: 00091
                                                  A/S Pos. :  0
Date: 10/08/9;
uL dispensed:  10 from 0,  5 from 39,  10  from  0
Replicate   1                             Time:  02:13
Peak Area  (A-s): 0.001                  Peak  Height (A): 0.006
Background  Pk  Area -------
uL dispensed: 5 from  39,  1U» Trora i,
Replicate  1
Deak flrea  :  0.014        Background Pk Height  (fl> :  0.015
Blank Corrected  Pk flrea (fl-s) :  0.015

Mean Pk flrea  : 4.46

Tl    ID: flDD 2  100ug/L      Seq.  No.: 00094    fl/S Pos. :  14     Date: 10/03/97

uL dispensed: 5  from  39,  10 from 2,  10 from 14
Replicate  1                            Time: 02:30
Peak flrea   : 0.028                  Peak Height   :  0.027

uL dispensed: 5  from  39,  10 from 2,  10 from 14
Replicate  2  (Peak Stored)              Time: 02:33
Peak flrea   :  0.022        Background Pk Height  -------
Tic,   ID: AUTO ZERO           Seq.  No.!  00095    A/S Pos. :  0     Date: 10/08/9"7

uL dispensed: 10 from 0, 5  from  39,  10  froni 0
Replicate   1                            Time: 02:36
Peak Area  (A-s): -0.001                 Peak Height (ft): 0.006
Background  Pk Area  : 0.005
Blank Corrected Pk Area  -------
 uL dispensed: 5 from 39, 10 from  £,  lifl rrom is
 Replicate  2 (Peak Stored)              Time: 02:56
 Peak Area (A-s): 0.024                  Peak Height (A): 0.032
 Background Pk Area  (A-s): 0.020         Background Pk Height  (ft):  0.022
•Blank Corrected Pk Area  (A-s): 0.025

 Mean Pk flrea (A-s):      0.027          SD: 0.0032               RSD(K)s 11.85

 Tl     ID: 184-23-7flB          Seq.  No.: 00096    A/S Pos.:  15    Date:  10/08/97

 Concentration  (ug/L  ):  0. 1

 Correlation coefficient: 0.999J2        Slope: 0.0003
                                   Calibration - Crtftft
                         1.0*
                                           Meth. fcf Add.
                                           C«rr. £•«?„s
                                           Sl»»«i C.JJJ3
                                    Concentration
                                                    100.0
                     » *\* A* *W *\* *V
 Tl
      ID: AUTO  ZERO
Seq. No. : 00099
         A/S Pos. :  0
Date: 10/08/97
 uL dispensed:  10  from  0,  5  from 39,  10 from 0
 Replicate  1                            Time: 02:59
 Peak Area  (A-s):  -0.001                 Peak Height  :  0.005
 Background Pk  Area  (A-s): 0.001        Background Pk Height  (A):  0.005
 Blank Corrected Pk  Area  (A-s):  0.000

 uL dispensed:  10  from  0,  5  from 39,  10 from 0
 Replicate  2  (Peak  Stored)              Time: 03:02
 Peak Area  (A-s):  -0.001                 Peak Height  (A):  0.006
 Background Pk  Area  (A-s): 0.001        Background Pk Height  (A):  0.006
 Blank Corrected Pk  Area  (A-s):  0.000
 Mean Pk Area  (A-s):

 Auto—zero performed.
                          0. 000
SD: 0.0001
                              A* *V*W A* A* *\**V*V ^* *V*\» *\»
Tl    ID: 184-23-8AB         Seq.  No. : 00100    A/S Pos. :  16

uL dispensed:  10  from  0,  5  from 39,  10 from 16
                                   RSD<*): 58.54
                                                                   Date: 10/08/97
                                                                193
-------
Tli   ID: AUTO ZERO         Seq. No.: 00101    ft/S Pos. :  0     Date:  10/08/97




uL dispensed:  10 from 0, 5 from 39, 10 from 0
                                                             194
-------
            Report    Table: HA451
Ned 10-08-97 01:07:.12 Art     page  1
Table Maine:  HA451            -Autosampler Type: TYPE TJA
Sample Positions:  ISO/192    QC Positions:  13/19      ft Sets:  2
Rinse Station location  is rack -1, pos.  -1.
                                              SPos Left  Analyses/Pos
— Racks —
'£**"-
Rack ft Type
1
2
3
4.
5
Aux. (I) Rack
Sample (16")
Saiaple (16inn)
Sample (16fflffl)
Sample (16mm)
Usage
STD/QC/8LANK
Samples
Samples
Samples .
Samples
13
"6
48
48
43
10
1
1
1
1
— Sample Sets —

Set»  Type      Prepare?   Description
      Method    SPos  Rack? -StartPos
1
2
Setft
Normal No 43430
Normal No C4323?^
Preparation Info —
Uptake Uptake82 Final
TRIANGL2 2 2 1
TRIAN6L2 40 2 3
Oil. Factor
No Samples Prepared.
Rack
Pos
1
2
3
4
5
6
(7..
Rack
Pos
1
2
3
4
5
6
7
8
9
10
11
12
13
14
31
ROM
1
1
1
1
1
1
.19
82
Ron
1
1
1
1








2
2

Col
1
2
3
4
5
6
Not

Col
1
2
3
4
5
6
7
8
9
10
11
12
1
2

Sample Name
STD3
STD1-BIANK
ICSA8
ICV/CCV
CHECK 10
IC8/CC8
Used)

Sample Name
185-4-1
185-4-1 0
43231 MB
43231 LCS
183-3-18
183-3-28
183-3-28 POS
183-3-28 L
183-3-38
183-3-38 OA
183-3-48
183-3-5B
183-3-68
183-3-78

Set 8
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-


Set ft
1
1
2
2
2
2
2
2
2
2
2
2
2
2

BUsed
2
1
3
6
1
6
•

8Used
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-

Type
Standard |-Gl-\\>
Standard \-"Vv>
OC Standard »*G* r
OC Standard \-Gh2.
OC Standard
QC Standard


Type
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample -
Sample
                                                                                       (KvCtA
                                                                                                 195
-------
iAutoSarap.lerk Report Table: HA451
Wed 10-08-97 01:0*7:12 AN
Rack 12
Pos
15
16
17
18
19
20
21
22
23"
24
25
26
27
28
29
30
3d
32
33
34
35
36
37
33
39
40
41
42
(43.
Rack
Pos
(I-
Rack
Pos
(1..
Rack
Pos
(1..
ROM
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
..48
33
ROM
.48
1)4
ROM
.48
IS
ROM
.48
Col
3
4
Sample Name
183-3-88
183-3-1BC •
•^""183-3-20
6
7
8
9
10
11
12
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
4
5
6
183-3-2C PDS
183-3-2C L
183-3-3C
183-3-3C DA
183-3-4C
183-3-58C
183-3-6C
183-3-7C
183-3-8C
43231 MB
43231 LCS
184-23-1AB X50
184-23-2AB
184-23-2A8 PDS
184-23-2A8 L
184-23-3A8
184-23-3A8 DA
184-23-4A8
184-23-6A8
184-23-7AB
184-23-3AB
184-23-9A3
184-23-10A8.5
183-15-1C
183-15-18C
Set
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
S'lUsed
-NA-
-HA-
-HA-
-NA-
-NA-
-NA- .
-HA-
-NA-
-NA-
-HA-
-NA-
-HA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
Type
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Saaple
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Not Used)

Col
Not

Col
Not

Col
Not

Sasiple Name
Used)

Sample Name
Used)

Sample Name
Used)

Set


Set


Set


8 tUsed
»

8 HUsed


«t tUsed


Type


Type


Type

page 2
                196
-------
"Standardization Rot.               '  .   Tue 10-07-97 02:13^04 AH    page 1



Method:  TRIANGL2    Standard: STD1-BLANK
Elen
Avge
SDev
%RSD
81
1)2
13
'Elei
Avge
SDev
WSO
81
82
1)3
Elen
Avge
SDev
IRSD
111
«2
83
Elen
Avge
SOev
*RSD
ttl
02
13

Elen
Avge
SDev
iRSO
111
12
83
AQ3280
-.0001
.0002
" 238^,.
.0001
-.0001
-.0002
Cd2?65
-.0001
.0001
69.80
-.0001
-.0000
-.0001
LV6707
.0748
.0005
.6568
.0743
.0752
.0750
2203-1
.0008
.0003
38.95
.0012
.0006
.0006

Ti3349
.0001
.0001
115.6
-.0000
.0001
.0002
A13082
.0029
.0000
.9540
.0029
.0029
.0029
Ce4186
-.0000
.0001
467.4
-.0002
-.0000
.0001
HQ2790
.0001
.0001
87.43
.0000
.0001
.0001
2203-2
.0002
.0001
64.63
.0001
.0003
.0002

T11908
-.0006
.0000
6.633
-.0006
-.0005
-.0006
AS1890
-.0003
. .0001
"18.26
-.0004
-.0003
-.0003
Co2286
-.0001
.0000
31.64
-.0002
-.0001
-.0001
Mn2576
.0000
.0000
22.13
.0000
.0000
.0000
Sb2063
.0003
.0001
48.42
.0003
.0001
.0004

V.2924
-.0005
.0000
3.104
-.0005
-.0004
-.0005
B 2496
.0387
.0010
2.698
.0378
.0398
.0384
Cr2677
-.0001
.0001
59.00
-.0002
-.0001
-.0001
Mo2020
.0000
.0000
131.4
.0000
.0001
.0000
1960-1
-.0059
.0011
18.09
-.0047
-.0068
-.0062
ft
Zn2062
-.0000
.0000
143.6
-.0001
.0000
-.0000
8a4934
.0006
.0000
2.019
.0006
.0006
.OOS6
CU3247
.0028
.0000
1.242
.0028
.0028
.0028 "
Na3302
.0025
.0019
77.25
.0040
.0031
.0003
1960-2
.0021
.0001
6.774
.0023
.0021
.0020

512381
.0515
.0039
7.564
.0497
.0559
.0487
8e3130
.0002
.0000
.8331
.0002
.0002
.0002
Fe2714
.0000
.0000
59.72
.0000
.0001
.0001
Ni2316
-.0017
.0002
9.837
-.0019
-.0017
-.0015
Snl899
-.0004
.0000
6.482
-.0004
-.0004
-.0005








Ca3179
.0005
.0000
2.589
.0005
.0005
.0005
KJ664
4.044
.029
.7063
•
'4.011
4.063
4.057
P.2149
-.0010
.0000
4.876
-.0010
-.0010
-.0009
SN215
.0003
.0000
8.453
.0003
.0003
.0003








                                                                                                197
-------
Standardization Rot.
Method: TRIAN6L2   - Standard: STD3
Tue  10-07-97 02:1*7M6 AN    page 1
Elen
Avge
SDev
IRSD
81
82
83
Elen
Avge
SDev
IRSD
81
82
83
Elen
Avge
SDev
IRSD
81
82
83
Elen
Avge
SDev
IRSD
81
82
83

Elen
Avge
SDev
IRSD
81
82
83
Ag3280
.3982
.0019 -
' .4764
s^ee--
.4003
.3976
.3967
Cd2265
.9160
.0033
.3602
.9126
.9162
.9192
L16707
15.96
.08
.4845
15.99
16.03
15.88
2203-1
.1775
.0008
.4299
.1784
.1770
.1771

Ti3349
1.100
.002
.1470
1.098
1.100
1.101
A13082
.0180
.0003
1.461
.0183
.0179
.0178
Ce4186
.1104
.0002
.1649
.1102
.1106
.1105
Hg2790
.0200
.0000
.2240
.0200
.0200
.0199
2203-2
.0883
.0005
.5841
.0879
.0881
.0889

T11908
.0306
.0010
3.264
.0295
.0309
.0314
AS1890
.0517
.0000
' .0740
.0517
.0517
.0518
C02286
.1037
.0003
.2513
.1034
.1037
.1039
Hn2576
.1273
.0004
.2832
.1269
.1274
.1276
SD2068
.1192
.0003
.2448
.1195
.1189
.1192

V.2924
.0379
.0001
.1783
.0379
.0379
.0380
8.2496
.1964
.0009
.4663
.1974
.1962
.1956
Cr2677
.1453
.0005
.3350
.1448
.1453
.1453
1102020
.0774
.0004
.5870
.0769
.0775
.0778
1960-1
.2668
.0016
.6023
.2685
.2667
.2653
*
Zn2062
.0979
.0005
.4822
.0975
.0979
.0985
B34934
.2895
.0002
.0636
.2897
.2896
.2894 '
CU3247
.1778
.0012
.6508
.1791
.1775
.1768 '
Ha3302
.2309
.0023
1.015
.2336
.2300
.2292
1960-2
.1586
.0011
.7097
.1573
.1594
.1591

Si2881
.4769
.0026
.5433
.4798
.4758
.4750
Be3130
.2558
.0009
.3704
.2548
.2559
.2567
Fe2714
.0041
.0000
.6543
.0041
.0041
.0042
N12316
.3443
.0014
.4059
.3434
.3437
.3459
Snl899
.0055
.0001
1.018
.0054
.0055
.0054








Ca3179
.0223
.0001
.2756
.0222
.0223
.0223
K.7664
23.31
.05
.2268
•23.34
23.34
23.25
P.2149
.0215
.0000
.0620
.0216
.0216
.0215
Sr4215
.8209
.0008
.0980
.8216
.8209
.8200








                                                                                           193
-------
'Analysis Report      Averages
                              Wed 10-08-97 00:54:.19 AH     page 1
 Method: IRIANGL2   Sample Name: STD3                  Operator: DM
 Run Tine: 10/07/97 02:17           Filename:  100797
 Node: CONC         Type:  Q        Corr. Factor:        1.00000
 Lab 10.:           Cust.  Sipl. ID.: -          Cust. 10.: 43430
 Eleos
 Units
 Avge
 SDev
Ag3280   A13082   Asl890   8J496    Ba4934   8e3130
ppb      ppb      ppb      ppb      ppb      ppb
 998.6    1000.    1004.    983.8    1004:    '1004.
5.093    13.27    2.708    4.027     .7248    2.818
.51      1.327    .2699    74094     .0722    .2808
Eleos
Units
Avge
SDev
tRSD
Elens
Units
Avge
SDev
tRSO
Elens
Units
Avge
SDev
tRSD
Eleos
Units
Avge
SDev
tRSD
Elens
Units
Avge
SDev
tRSD
Ca3179
ppb
1005.
2.647
.2633
Fe2714
PPb
1007.
3.941
.3916
Na3302
ppB
9.983
.0904
.9058
1960-1
ppb
1005.
5.134
.5109
Ti3349
PPb
1003.
1.978
.1972
Cd2265
ppb
1007.
2.874
.2856
X.7664
ppn
9.972
.0194
.1945
N12316
ppb
1006.
2.089
.2078
1960-2
ppb
1006.
1.384
.1377
T11908
ppb
1035.
10.62
1.026
Ce4186
PPb
1007.
1.356 -
.1346
Li6707.
ppb
996.5
1.972
.1979
P.2149
ppb
1004.
5.599
.5577
Pb2203
PPb
1006.
4.736
.471
V_2924
ppb
1004.
1.491
.1484
C02286
PPb
1006.
2.088
.2076
Hg2790
PPb
1003.
4.795
.4782
2203-1
ppb
1000.
2.234
.2233
Sel960
ppb
1005.
2.551
.2537
2n2062
PPb
1010.
6.095
.6038
Cr2677
ppb
1006.
1.181
.1174
Hn2576
PPb
1005.
2.251
.224
2203-2
ppb
1008.
8.047
.798
Snl899
ppb
988.2
7.927
.8022
•Si2881
PPb
9993.
53.58
.5362
CU3247
ppb
1002.
4.399
.4389
M02020
ppb
1011.
.7379
.073
Sb2068
PP°
1007.
2.929
.2909
Sr4215
ppb
999.5
1.155
.1156





                                                                                                           199
-------
.Analysis Report      Averages
                               Bed 10-08-97 00:54U9 AH     page  3
•Method: TRIAHGL2   Sample Hane: ICV/CCV                Operator: DKH
 Run Tine:  10/07/97 02:27           Filename: 100797
 Node:  CONC        Type: 0  _.     Corr.  Factor:        1.00000
 Lab ID.:           Cust. Sipl. 10.:           Cust. ID.: 43430
 Elens
 Units
 Avge
 SDev
 Eleias
 Units
 ftvge
 SDev
 Elems
 Units
 Avge
 SOev
 *RSD
 Elans
 Units
 Avge
 SDev
 Ca3179
 ppb
 Q.7980
 .2426
 30.4

 Fe2714
 ppb
 Q5.346
 4.673
 87.4

 Na3302.
 ppo
 0.1
  815
'14.8

 1960-1
 PPb
  2.036
 1.709
 83.95

 Ti3349
 PPb
 0.8199
 .1822
Cd2265
ppb
Q.8192
.1844
22.51

KJ664
ppm
0.0269,
.0131/
48^6

N12316
PPb
Q.8937
.1957
21.9

1960-2
ppb
 .4676
.9612
205.6

T11908
ppb
016.97
6.494
38.27
AS 1890
PPb
Q1.289
2.213
171.7
Ce4186
ppb
1.301
.8208
63.07 j
LJ0W7
JW>
Q.8153
.1781
21.85
P.2149
ppb
02.009
1.555
77.37
Pb2203
PPb
Q-.3140
1.748
556.7
V.2924
PPb
01.628
IV7A
B.2496
ppb
-86.48
1.231
l'.423
C02286
ppb /
0.9241
j&n
/2B.84
«g2790
ppb
02.238
1.294
57.81
2203-1
ppb
.6948
1.936
278.7
Sel960
ppb
0.9899
1.088
109.9
Zn2062
ppb
0.7629
JIM
Ba4934
ppb
0.7875-
.1798
22. 83/
if2677
^ppb
0.7586
.0791
10.43
Hn2576
PPb
0.8254
.214
25.93
2203-2
PPb
-.8176
1.748
213.8
Snl899
ppb
012.36
14.35
116.2
•Si2881
ppb
0-262.4
4 032
Be3130
ppb >
Q.00
/2313
28.27
Cu3247
ppb
0.4245
.4021
94.73
M02020
ppb
02.291
.4794
20.93
Sb2063
ppb
04.500
1.519
33.75
Sr4215
ppb
0.7994
.1952
24.42




                            9.684     41.54    1.537
                                                                                                           200
-------
 Analysis.Report      Averages
.   Red 10-08-97 00:54:.l9 AH    page 4
 Hethod:  TRIANGL2   Sample Naue: ICV/CCV               Operator: DKH
 Run Time:  10/07/97 02:34          Filenane: 100797
 rtode:  CONC        Type: Q        Corr.  Factor:        1.00000
.Lab ID.:          .Oust. Sipl. ID.:           Cust. ID.:  43430
Elens
Units
Avge
SDev
*RSO
Elems
Units
Avge .
SDev
*RSD
Eleois
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
IRSD
Eleros
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
*RSD
Ag3280
ppb
496.3
2.087
.4205
Ca3179
ppb
498.6
1.326
.266
Fe2714
ppb
491.0
6.234
1.27
Na3302
ppm
4.913
.1562
3.179
1960-1
PPb
502.1
4.361
.8685
T13349
ppb
496.1
.8619
.1737
A13082
ppb
506.3
12.97
2.561
Cd2265
ppb
500.0
2.456
.4912
K.7664
PPB
4.882
.0418
.856
Ni2316
ppb
498.1
1.359
.2728
1960-2
ppb
501.2
3.123
.6231
T11908
ppb
505.6
12.56
2.484
AS1890
ppb
499.2
1.552
.3109
Ce4186
ppb
496.2
1.302
.2623
116707
PPb'
485.4
4.274
.8306
P_2149
ppb
496.3
1.814
.3655
Pb2203
ppb
498.4
.0888
.0178
V.2924
PPb
497.1
.992
.1996
8.2496
ppb
400.6
1.528
.3815
C02286
ppb
495.5
1.84
.3714
Ng2790
ppb
498.6
4.04
.8103
2203-1
ppb
497.1
2.469
.4968
Sel960
PPb
501.5
3.126
.6233
Zn2062
ppb
498.8
3.135
.6285
8a4934
ppb
496.7-
.763
.1536
Cr2677
PPb
497.0
1.958
.3941
Mn2576
PPb
497.0
1.61
.324
2203-2
ppb
499.0
1.107
.2217
Snl899
PPb
Q9516.
40.35
.4241
•Si2881
ppb
Q-33.54
8.421
25.11
Be3130
PPb
492.4
2.514
.5106
CU3247
ppb
500.4
4.565
.9122
M02020
ppb
498.3
.9754
.1958
Sb2068
PPb
494.7
2.296
.464
Sr4215
ppb
494.4
.287
.0581





                                                                                                        201
-------
.Analysis .Report      Averages
Wed 10-08-97 00:54:19 AM     page 5
-Method:  TRIANGL2   Sample Name:  IC8/CC8               Operator: DKH
 Run  Time: 10/07/97 02:44          Filename:  100797
 Mode:  COHC         Type: Q        Corr. Factor:        1.00000  _
 Lab  ID\:  _        Cust. Siapl. ID.:           Cust. ID.: 43430
Eleras
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
*RSD
Eleins
Units
Avge
SDev
%RSD
Elenis
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
«SO
Eleras
Units
Avge
SDev
iRSD
Ag3280
ppb
.3155
.257
81.48
Ca3179
ppb
-.5314
.8154
153.4
Fe2714
ppb
-.2569
3.027
1178
Na3302
ppin
.0681
.0584
85.75
1960-1
PPb
1.853
.6234
33.65
Ti3349
ppb
.1101
.0354
32.15
A13082
PPb
6.615
3.268
49.41
Cd2265
PPb
.0224
.1327
591.6
K.7664
PPffl
.0065
.0102
156.5
Ni2316
ppb
.1093
.095
86.92
1960-2
ppb
-2.055
1.978
96.21
T11908
ppb
3.916
2.667
68.12
AS1890
ppb
.0904
.4241
469.1
Ce4186
ppb
.6182
1.838
297.3
Li6707
ppb
.1007
.0087
8.674
PJ149
ppb
3.447
1.654
47.97
Pb2203
ppb
-.9054
.8238
90.99
VJ924
ppb
.8993
.1791
19.91
8J496
ppb
-128.7
.7183
.5582
C02286
ppb
.1822
.1334
73.23
MQ2790
ppb
.0826
1.801
2179
2203-1
PPb
.1017
.8925
877.6
Sel960
ppb
-.7540
1.504
199.5
Zn2062
PPb
.0529
.3174
600.1
Ba4934
ppb
.0616-
.0346
56.23
Cr2677
ppb
.1414
.2856
201.9
Mn2576
ppb
.0901
.0456
50.61
2203-2
ppb
-1.408
.8182
58.1
Snl899
ppb
-.3666
17.63
4808
•Si2881
ppb
0-371.0
1.75
.4718
8e3130
PPb
'.1053
.034
32.28
CU3247
PPb
-.5736
.4538
79.12
M02020
PPb
.4445
.5671
127.6
Sb2063
PPb
1.411
1.881
133.4
Sr4215
ppb
.0781
.0372
47.63





                                                                                                          202
-------
•Analysis Report     Averages
Wed 10-08-97 00:54:19 AH     page 6
Method: TRIANGL2   Sanple Nane: ICSA8                 Operator: OKH
Run Tine: 10/07/97 02:49          Filename: 100797
Node: CONC        Type: Q        Coir. Factor:        1.00000
Lab ID.:          CustrSapl.  10.:            Cust. 10.: 43430
Eleros
Units
Avge
SOev
*RSO
Eleas
Units
Avge
SDev
*RSD
Eleos
Units
Avge
SDev
*RSO
Eleos
Units
Avge
SOev
%RSO
Elens
Units
Avge
SDev
«SD
Eleos
Units
Avge
SDev
*RSD
Ag3280
ppb
534.1
1.677
.314
C33179
ppb
447300.
1055
.2359
Fe2714
ppb
172500.
191.8
.1112
Na3302
ppm
5.430
.1276
2.349
1960-1
ppb
543.7
10.11
1.859
Ti3349
ppb
496.1
.7835
.1579
A13082
ppb
497500.
4766
.9579 '
Cd2265
ppb
477.5
1.155
.2418
K_7664
ppm
025.18
.058
.2302
NJ2316
ppb
459.3
.8184
.1782
1960-2
ppb
521.9
8.784
1.683
T11908
ppb
516.6
9.949
1.926
AS1890
ppb
519.1
2.114
.4072
Ce4186
ppb
500.4
.7313
.1461
Li6707
ppb
622.1
1.361
.2188
P.2149
ppb
546.1
3.243
.5939
Pb2203
ppb
487.3
4.779
.9808
V.2924
ppb
492.6
1.416
.2875
B.2496
ppb
402.2
1.583
-;3935
C02286
ppb
471.1
1.108
-.2352
Hg2790
ppb
525200
1135
.2162
2203-1
ppb
501.7
2.574
.5129
Sel960
ppb
529.1
3.846
.7269
Zn2062
ppb
450.2
3.577
.7946
Ba4934
ppb
515. *
1.099
.2134
Cr2677
ppb
478.5
2.127
.4446
Mn2576
ppb
. 459.1
1.384
.3015
2203-2
ppb
480.0
8.179
1.704
Snl899
ppb
Q9884.
30.75
.3111
.Si2331
PPb
0206.5
19.32
9.354
Be3130
ppb
485.7
1.786
.3677
CU3247
ppb
' 537.6
4.405
.8194
NQ2020
ppb
498.4
2.587
.5192
Sb2068
ppb
508.0
6.555
1.29
Sr4215
ppb
508.0
.4383
.0864





                                                                                                         203
-------
:Analysis Report      Averages
Wed 10-08-97 00:54:19 AH    page 11
 Method: TRIANGL2  Sample Name: ICV/CCV          .      Operator: OKH
 Run Time: 10/07/97 03:54           Filenaue: 100797
 Mode: CONC        Type: Q         Corr. Factor:        1.00000
 Lab 10.:          -Cust. Srnpl. ID.:           Cust. ID.:  43430
El eras
Units
Avge
SOev
%RSD
Elems
Units
Avge
SOev
*RSD
El eras
Units
Avge
SOev
;RSD
Elems
Units
Avge
SOev
*RSD
Elens
Units
Avge
SOev
*RSD
Elems
Units
Avge
SDev
USD
Ag3280
ppb
497.8
3.045
.6117
C33179
ppb
497.9
1.714 -
.3442
Fe2714
ppb
496.1
3.232
.6515
Na3302
PP»
4.890
.0603
1.232
1960-1
PPb
502.6
3.822
.7604
Ti3349
ppb
497.9
.8951
.1798
A13082
ppb
523.1
10.84
2-. 073
Cd2265
ppb
504.1
2.036
.4039
K.7664
ppiB
4.879
.0395
.8093
Ni2316
ppb
503.5
1.796
.3567
1960-2
PPb
507.0
.8046
.1587
T11908
ppb
499.4
18.76
3.756
AS1890
ppb
503.0
2.449
.4869
Ce4186
ppb
496.8
.5736
.1155
U6707
ppb
480.5
3.567
.7423
P.2149
ppb
507.9
4.647
.915
Pb2203
PPb
500.4
.8995
.1798
VJ924
ppb
498.2
1.183
.2375
8.2496
ppb
313.3
1.095
.3496
C02286
ppb
495.4
1.303 .
.263
Hg2790
ppb
500.3
1.462
.2922
2203-1
ppb
491.5
3.873
.7879
Sel960
ppb
505.5
.8226
.1627
Zn2062
ppb
500.4
3.693
.7379
8a4934
PPb
495.3
.7605
.1535
Cr2677
ppb
499.4
1.438
.2879
Hn2576
PPb
497.4
1.525
.3065
2203-2
ppb
504.8,
2.595
.5141
Snl899
PPb
Q9385.
22.85
.2435
.Si2881
ppb
Q-286.4
4.778
1.663
8e3130
ppb
491.4
2.016
.4103
CU3247
ppb
498.9
3.769
.7556
M02020
ppb
496.7
2.627
.5289
Sb2068
ppb
492.7
1.115
.2263
Sr4215
ppb
494.2
.2477
.0501





                                                                                                          204
-------
<>palysis Report      Averages
Wed 10-08-97 00:5*4:19 AH    page 12
Method: TRIAHGL2   Sample  Name: IC8/CCB               Operator:  DKH
Run Tine:  10/07/9704:13           Filenane: 100797
Hode: CONC         Type: Q        Corr.  Factor:        1.00000
Lab 10.:            Cust. Sipl. ID.:  -        Cust. ID.:  43430
Eleos
Units
Avge
SDev
*RSO

[lens
Units
Avge
SOev
*RSD

Elems
Units
Avge
SDev
*RSD

Elems
Units
Avge
SDev
iRSD

Elems
Units
Avge
SDev
*RSD
Ag3280
ppb
.0352
.2306
654.4
Ca3179
ppb
-2.315
.2333
10.08
Fe2714
ppb
.4665
1.432
307
Na3302
ppra
.0136
.0449
329.4
/
1960/
PPb/
2/538
1/019
«0.14
\i3349
PPks^
.0476
.0625
131.2
A13082
ppb
34.98
4.163
11.9
Cd2265
ppb
-.0260
.0367
141.5
KJ664
ppB
.0302
.0086
23.46
Ni2316/
ppb /
.3/71
.mi
/111. 3
1960-2
ppb
-1.377
2.188
158.8
T11908
PPb
"Tlii.
-------
-Analysis.  Report      Averages
                               Ned 10-08-97 00:54:19 AH     page 13
Method: TRIANGL2   Sample Nane:  ICB/CC8                Operator:  DKH
Run  Time:  10/07/97 04:19           Filenaae:  100797
Mode: CONC  _     Type: Q         Corr.  Factor:        1.00000
Lab  ID.:           Cust. Soph  ID.:           Cust. ID.: 43430
El eras
Units
Avge
SDev
%RSO

Elems
Units
Avge
SDev
*RSD

El eras
Units
Avge
SDev
*RSD

Elems
Units
Avge
SDev
iRSO

Elems
Units
Avge
SDev
%RSD
Ag3280
ppb
 .1153
.3559
308.6
A1308
ppb
 35.78
3.024
8.4-52
ppb
 -.7492
1.582
211.1
                          ppb
                           -208.7
                          .9138
                          .4379
                                   Cr2677   Cu3247
                                   ppb      ppb
                                    .1302    -1.267
                                   .1114    .1472
                                   85.5     11.61
         C64186
         ppb
          -.4512
         .5508
         122.1
                                   Mn2576   No2020
                                   ppb      ppb
                                    .0309    .1208
                                   .018     .3677
                                   58.21    304.4
                 Mg2790
                 ppb
                  2.520
                 .8062
                 32
                                   2203-2   Sb2068
                                   PPb      ppb
                                    -3.434   -.0020
                                   .9822    1.274
                                   28.6     64910
         P.2149
         ppb
          6.483
         3.62
         55.34
         2203-1
         ppb
          1.209
         1.094
         90.48
         1960-2
         PPb
          -2.974
         2.35
         79.02
                          Snl899
                          ppb
                          Q33.02
                          9.284
                          28.11
Pb2203
ppb
 -1.
.5263
27.88
                          Sel960
                          ppb
                           -1.021
                          .0971
                          9.513
Ca3179   Cd2265
ppb      ppb
 -3.147   -.1175
.6507    .1615
20.68    137.4

Fe2714   K.7664
ppb      ppio
 2.283    .0175
.6559    .0108
28.72    61.5

Na3302   Ni23
ppn      ppb
 .0545    yC0893
.0629    /276
115.4   /366.8
101V/
Elems
Units
Avge
SDev
*RSD
Ti3J49
ppb \
-.0190
.066
348.2
T11908
smb ._
Q5.048
2.915
57.75
V.2924
ppb -
1.557
.3821
24.54
Zn2062
— PP»
.1679
.1562
93.01
.SJ2881
~~PPi>
Q-628.5
.091
.0145
                                                                                                               206
-------
"halysisJSport      Averages       •      Wed  10-08-97 00:5*4:19  AM    page 14
nethod:  TRIAHGL2   Saaple Naae:  IC8/CCB               Operator:  DKH
 iun Tine:  10/07/97 04:31          Filename:  100797
riode: CONC        Type: Q        Corr. Factor:        1.00000
Lab ID.:           Cust. Snpl. ID.:           Cust. ID.: 43430
Elems
Inits
*vge
SOev
IRSD
Elenis
Units
4vge
SOev
$RSD
Elems
Units
Avge
SOev
*RSD
Elems
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
%RSD
El ens
Units
Avge
SDev
*RSD
Ag3280
ppb
.1661
.1269
76.43
Ca3179
ppb
-4.096
.5473
13.36
Fe2714
ppbi
3.309
3.475
105
Na3302
ppni
.0360
.1033
302.3
1960-1
ppb
2.833
1.608
56.76
Ti3349
ppb
-.0126
.061
482.6
A13082
ppb
40.81
2.658
6.514
Cd2265
ppb
-.0758
.018
23.78
KJ664
ppoi
.0201
.012
59.67
Ni2316
ppb
-.0023
.6983
29790
1960-2
ppb
-.9544
1.044
109.4
T11908
ppb
3.302
2.898
87.78
AS1390
ppb
1.251
.9621
76.89
CB4186
ppb
.1982
.5162
260.5
Li6707
ppb
.0755
.0337
44.56
PJ149
ppb
3.424
1.303
38.06
Pb2203
ppb
-.9020
.276
30.6
V.2924
ppb
1.671
.386
23.09
8.2496
ppb
-211.7
1.69
.7981
C02286
ppb
.0802
.3625
451.9
Mg2790
ppb
.5514
3.487
632.4
2203-1
ppb
.8929
1.807
202.4
Sel960
ppb
.3063
.9219
300.5
Zn2062
ppb
.1510
.3774
249.9
Ba4934
ppb
-.Oltt
.0428
370.3
Cr2677
ppb
.1499
.3166
211.2
Mn2576
ppb
.0024
.0446
1849
2203-2
ppb
-1.798
.9609
53.44
Snl899
ppb
Q13.43
14.7
109.1
.Si2881
ppb
Q-651.2
1.713
.2631
8e3130
ppb
-.2269
.016
7.059
CU3247
ppb
-1.328
.129
9.711
H02020
ppb
-.5559
.2651
47.68
Sb2068
ppb
.3855
1.052
272.9
Sr4215
PPb
-.0077
.0227
294.2





                                                                                                             207
-------
Analysis' Report      Averages
Sed 10-08-97 00:54:19 Ail    page 15
Method:  TRIAN6L2   Sample Name: ICSA8                 Operator:  DXH
Run Time:  10/07/97 04:37          Filename:  100797
Node:  CONC        Type: Q        Corr.  Factor:        1.00000
Lab 10.:          Cust. Sapl.  10.:           Cust. 10.: 43430
Elems
Units
Avge '
SOev
IRSD
Elems
Units
Avge
SOev
IRSO
Elems
Units
Avge
SOev
*RSD
Eleus
Units
Avge
SOev
*RSD
Elems
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
*RSO
Ag3280
ppb
531.9
1.237
.2325
Ca3179
ppb
448500.
1338
.2983
Fe2714
ppb
172700.
245.2
.142
Na3302
ppg
5.589
.0987
1.766
1960-1
ppb
537.0
7.339
1.367
Ti3349
ppb
499.6
.3489
.0698
A13082
ppb
501000.
3412
.6809
Cd2265
ppb
480.7
1.042
.2168
K.7664
PPB
025.34
.1569
.6191
Hi2316
ppb
462.5
1.248
.2699
1960-2
ppb
527.6
7.309
1.385
T11908
PPb
503.0
23.13
4.598
AS1890
ppb
522.8
4.091
.7826
Ce4186
ppb"
504.2
1.044
.2071
Li6707
ppb
625.0
3.643
.5823
P.2149
ppb
545.5
12.9
2.365
Pb2203
ppb
488.3
1.6
.3277
V.2924
ppb
493.6
1.132
.2294
8J496
ppb
324.4
3.635
1.121 _.
C02286
ppb
470.5
1.251
.2659
Hg2790
ppb
527500.
598.2
.1134
2203-1
ppb
491.5
5.464
1.116
SS1960
ppb
530.7
2.762
.5203
Zn2062
ppb
446.6
3.533
.7911
834934
ppb
518.5-
1.233
.2378
Cr2677
ppb
480.2
2.242
.467
Hn2576
ppb
459.9
1.24
.2696
2203-2
ppb
486.6
5.071
1.042
Snl899
ppb
Q9712.
111.3
1.146
.Si288i
ppb
Q-63.97
5.421
8.475
8e3130
ppb
482.5
1.742
.361
Cu3247
ppb
542.6
3.815
.7031
M02020
ppb
496.5
4.086
.8231
Sb2068
ppb
510.1
3.386
.6637
Sr4215
ppb
512.5
.9922
.1936





                                                                                                              208
-------
Analysis  Report      Averages
Bed 10-08-97 00:59:04 AN     page 1
Method: TRIANGL2   Sample Name:  43231 MB              Operator:  DKH
Run Tine:  10/07/97 05:09          Filenaue:  100797
Mode: CONC        Type: S        Corr. Factor:        1.00000
Lab ID.:           Cust. Snipl. 10.:           Cust. ID.: 43231
El ems
Units
Avge
SDev
tRSD
Co2286 Asl890 6a4934 Be3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-.0840 L.2054 L.1336 1.3012 L-.1924 1.0129
.0786 1.789 .023 .0141 .036 .1976
93.54 870.9 17.21 4.686 18.73 1535
Elems
Units
Avga
SOev
%RSD
Cr2677
ppb
L.2336
.2472
105.8
Mn2576
ppb
L.8014
.057
7.111
IU2316
PPb"
L.7729
.5292
68.46
P.2149
ppb
L3.209
1.384
43.14
Pb2203
ppb
L-.0667
.3606
540.9
Sb2068
ppb
L.4985
.7593
152.3
El 80S
Units
Avge
SOev
%RSD
Sel960
ppb
L.0967
2.06
2129
T11908
ppb
L3.807
1.589
41.72
Zn2062
ppb
22.53
.2129
.9451
                                                                                                    209
-------
:Analysis  Report  •    Averages
                               Bed 10-08*97 00:59:04 AH     page 2
 Method:  TRIAN6L2   Sample Name:  43231 LCS              Operator:  OKH
 Run Tine:  10/07/97 05:14           Filename: 100797
 Node:  CONC        Type: S         Corr. Factor:        1.00000
 Lab ID.:           Oust. Sapl.  ID.:            Cust. ID.: 43231
Eleois
Units
Avge
SDev
IRSD
C02286
ppb
49.51
.4746
.9586
AS1890
ppb
49.55
1.37
2.766
Ba4934
ppb
50.04
.0505
.101
Be3130
ppb
47.96
.0718
.1496
Cd2265
ppb
50.41
.2798
.5543
Ag3280
ppb
46.92
.4211
.8974
 Eleins
 Units
 Avge
 SDev
 IRSD
Cr2677   Mn2576
ppb      ppb
 50.38    50.22
.5406    .1382
1.073    .2751
N12516
PPb'
 50.80
.9832
1.936
P_2149
ppb
 1027.
9.016
.8777
Pb2203   Sb2068
ppb      ppb
 48.37    51.11
.2561    .9948
.5295    1.947
Elems
Units
Avge
SDev
%RSO
Sel960
ppb
48.39
.8738
1.787
T11908
ppb
54.98
.8596
1.563
Zn2062
ppb
202.1
.9752
.4825
                                                                                                       210
-------
Analysis  Report      Averages
Wed 10-08-97 00:59:04  AN     page 3
Method:  TRIANGL2   Sample Name: 183-3-18              Operator: DKH
Run Tine:  10/07/97 05:19          Filenaae:  100797
Mode:  CONC         Type:  S        Corr. Factor:        1.00000
Lab ID.:           Cust.  Snpl. ID.:           Cust. ID.:  43231
Elems
Units
Avge
SDev
*RSD
Co2286
ppb
L-1.503
.2874
19.12
AS1890
ppb
L2.984
1.066
35.71
Ba4934
ppb
4.282
.0153
.3576
8e3130
ppb
L.2732
.0461
16.9
Cd2265
ppb
25.20
.185
.7342
Ag3280
ppb
5.430
.3719
6.85
Elems
Units
Avge
SDev
IRSD
Cr2677 Mn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
9.808 7.089 9.264 L19.49 134.9 6.088
.3586 .0144 .4954 4.19 1.735 1.037
3.657 .2033 5.348 21.5 1.286 17.04
Eleas
Units
Avge
SDev
%RSD
Sel960
ppb
3.900
2.003
51.35
T11908
ppb
L-.5224
1.752
335.5
Zn2062
Ppb
42.38
.3113
.7356
                                                                                                      211
-------
analysis Report      Averages
Wed 10-08-97 00:59:04 AH    page 4
Method:  TRIANGL2   Sample Name: 183-3-2B              Operator: DKH
Run Time:  10/07/97 05:23          Filename:  100797
Mode:  CONC        Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. Srapl. ID.:           Cust. ID.: 43231
Eleias
Units
Avge
SDev
IRSD
C02286 AS1890 8a4934 8e3130 M2265 Ag3280
ppb ppb ppb ppb ppb ppb
1-1.725 7.435 51.46 L.3328 28.57 10.58
.43 1.497 .0976 .0402 .2591 .6289
24.92 20.13 .1896 12.08 .9066 5.946
Eleras
Units
Avge
SDev
USD
Cr2677
PPb
41.40
2.048
4.946
Mn2576
ppb
1584.
8.431
.5321
Ni2316
PPb"
50.42
1.657
3.287
PJ149
ppb
105.6
5.198
4.924
Pb2203
ppb .
1914.
12.68
.6o25
Sb2068
ppb
23.73
3.3
13.9
Eleois
Units
Avge
SDev
*RSD
Sel960 T11908 Zn2062
ppb ppb ppb
8.559 L-2.244 11380.
1.332 2.784 110.3
15.56 124.1 .9692
                                                                                                       212
-------
••Analysis Report      Averages
Ned 10-08-9? 00:59:04 AM    page 5
Method: TRIANGL2   Sample Nane:  183-3-28 PDS           Operator: DKH
 ton  Time: 10/07/97 05:28           Filename: 100797
 lode: COHC         Type: S         Corr. Factor:        1.00000
Lab  ID.:           Cust. Snpl. ID.:           Cust.  ID.: 43231
Elens
Units
4vge
SDev
%RSD
Co2286
ppb
46.53
.3865
.8308
Asl890
ppb
52.32
1.785 •
3.411
8a4934
ppb
100.9
.3536
.3505
8e3130
ppb
45.60
.1294
.2837
Cd2265
ppb
77.08
.5125
.6649
Ag3280
PPb
56.28
.5567
.9892
Elens
Units
Avge
SOev
%R5D
Cr2677
ppb
91.75
1.525
1.662
Hn2576
ppb
1619.
5.874
.3628
Ni2316
ppb'
99.32
1.766
1.778
P.2149
PPb
106.6
12.33
11.56
Pb2203
ppb
1945.
7.356
.4039
Sb2063
ppb
68.97
1.48
2.145
Elems
Units
Avge
SDev
USD
Sel960 T11908 2n2062
ppb ppb ppb
53.34 46.28 11470.
.2419 2.999 98.47
.4534 6.479 .3534
                                                                                                         213
-------
: Analysis Report      Averages            fled 10-08-97 00:59:04 AN     page 6
 Method:  TRIAN6L2   Sample Name:  183-3-28 I             Operator: DKH
 Run Time:  10/07/97 05:33           Filenaoe: 100797
 Mode:  CONC        Type: S         Corr. Factor:        1.00000
 Lab ID.:          Cust. Smpl. ID.:           Cust. ID.:  43231
Elems
Units
Avge
SDev
4RSD
Co2286 Asl890 8a4934 8e3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-1.100 L2.140 10.54 L.3221 5.654 2.246
.1214 1.787 .063 .0306 .161 .3491
11.03 83.51 .598 9.491 2.846 15.54
 Elens     Cr2677   Mn2576   Ni2316   PJ149   Pb2203   Sb2068
 Units     ppb     ppb      ppb'      ppb      ppb      ppb
 Avge       12.65    327.6    12.88    31.59    402.2    8.209
 SDev      .3954    .7695    .337     8.045    2.606    1.123
 IRSD      3.127    .2349    2.616    25.47    .6479    13.68
Elens
Units
Avge
SDev
%RSD
Sel960
ppb
3.531
1.877
53.16
T11908
ppb
13.416
2.182
63.87
Zn2062
PPb
2410.
3.5r>3
.3556
                                                                                                          214
-------
-.Analysis Report      Averages
Wed 10-08-97 00:59:04 AM    page 7
 Method:  TRIAN6L2   Sample Name: 183-3-3B              Operator: DKH
 Run Tine:  10/07/97 05:37          Filenaie:  100797
 Mode:  CONC        Type: S        Corr. Factor:        1.00000
 Lab ID.:          Cust. Smpl.  ID.:            Cust.  ID.: 43231
Eleias
Units
Avge
SDev
%RSD
Co2286 Asl890 8a4934 Be3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
5.101 29.56 272.5 1.477 298.9, 50.48
.1027 1.621 .1511 .0157 .7584 .4574
2.014 5.483 .0555 1.065 .2537 .9062
Elems
Units
Avge
SDev
%RSD
Cr2677
ppb
154.5
1.403
.9083
Mn2576
ppb
12560.
18.43
.1468
N12316
ppb-
51.42
1.221
2.375
P.2149
ppb
420.2
8.107
1.929
PD2203
ppb
14900.
8.949
.0601
Sb2068
ppb
105.9
2.9
2.739
El ems
Units
Avge
SDev
%RSD
Sel960
ppb
18.31
1.038
5.516
T11908
ppb
14.67
.9247
6.302
Zn2062
ppb
H72520.
206.2
.2843
                                                                                                         215
-------
Analysis Report      Averages
Ned 10-08-97 00:59:04 AM
page 8
Method:  TRIANGL2   Sample Name:  183-3-38 DA           Operator:  DKH
Run Tine:  10/07/97 05:42           Filename:  100797
Mode:  CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. Smpl.  ID.:            Cust.  ID.: 43231
El ens
Units
Avge
SDev
*RSD
C02286
ppb
4.991
.3913
7.84
Asl390
ppb
33.61
2.12
6.307
8a4934
ppb
273.6
.2217
.081
8e3130
ppb
1.475
.0297
2.015
Cd2265
ppb
298.8
1.402
.4691
Ag3280
ppb
50.49
.2812
.5569
El eras
Units
Avge
SDev
*RSD
Cr2677
ppb
155.2
1.801
1.16
Hn2576
ppb
12520.
56.51
.4514
Ni2316
PPb"
52.03
.4253
.8174
P.2149
ppb
425.2
2.365
.5562
Pb2203
ppb
14910.
58.42
.3919
Sb2068
ppb
106.9
1.539
1.44
Eleios
Units
Avge
SDev
%RSD
Sel960
ppb
18.29
1.813
9.938
111908
ppb
13.08
3.168
24.21
Zn2062
ppb
H71960.
469.5
.6525
                                                                                                       216
-------
•'Analysis  Report      Averages
Ned 10-08-97  00:59:04 AM     page 9
Method: TRIANGL2   Sample  Name: 183-3-48               Operator: DKH
Run Time:  10/07/97 05:47           Filenaue:  100797
Mode: CONC         Type: S        Corr.  Factor:        1.00000
Lab ID.:           Cust. Stipl. ID.:           Cust. ID.: 43231
Hems
Units
Avge
SDev
USD
C02286
ppb
L-1.676
.4468
26.66
AS1890
ppb
8.563
1.731
20.22
8a4934
ppb
48.03
.2026
.4218
Be3130
ppb
L.4056
.0434
10.69
Cd2265
ppb
25.08
.1776
.7083
Ag3280
ppb
7.181
.3424
4.768
El ems
Units
Avge
SDev
*RSD
Cr2677
ppb
30.49
1.071
3.514
Mn2576
ppb
1505.
5.021
.3338
Ni2316
ppb'
13.72
.9878
7.201
P.2149
ppb
1565.
1.35
.0863
P62203
ppb
1491.
4.75
.3186
Sb2068
ppb
14.70
2.254
15.33
El ems
Units
Avge
SDev
%RSD
Sel960
ppo
8.715
1.429
16.4
T11908
PPb
L-1.443
4.736
328.2
Zn2062
ppb
3545.
72.11
.3439
                                                                                                          217
-------
.Analysis- Report      Averages
                                        Bed 10-08-97 00:59:04 AM    page 10
Method: TRIANGL2   Sample  Name: 183-3-58              Operator: DKH
Run Time: 10/07/97 05:51           Filename:  100797
Mode: CONC         Type: S        Corr. Factor:        1.00000
Lab ID.:           Cust. Snpl.  ID.:           Cust.  ID.: 43231
El ems
Units
Avge
SDev
IRSD
Co2286 Asl890 Ba4934 8e3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-2.223 L4.119 2.195 L.2215 L-.1931 L.4694
.4794 1.927 .0116 .0272 .0138 .1325
21.57 46.79 .53 12.29 7.125 28.24
Elems
Units
Avge
SDev
SRSO
Cr2677 Mn2576 Ni2316 PJ149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
10.44 11.41 6.462 113.13 9.729 7.605
.9226 2.011 1.026 4.668 3.117 2.898
8.84 17.63 15.87 35.57 32.04 38.11
Elems
Units
Avge
SDev
SRSD
                   TH903   Zn2062
           ppb      ppb      ppb
           6.198   Ll.619    61.34
           2.272    i.43     12.74
           36.65    88.36    20.78
                                                                                                          21S
-------
Analysis Report     Averages
Ned 10-08-97 00:59:04 AM    page 11
 Method: TRIAN6L2   Sample Naae:  ICV/CCV               Operator: OKH
 Run  Tine: 10/07/97 05:57           Filename: 100797
 Mode: CONC        Type: 0         Corr. Factor:        1.00000
 Lab  ID.:          Cust. Snpl. ID.:           Cust.  ID.: 43231
El ems
Units
Avge
SDev
%RSD
Elems
Units
Avge
SOev
*RSD
Elems
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
*RSD
Ag3280
ppb
500.1
1.768
.3536
Ca3179
ppb
496.2
1.349
.2717
Fe27l4
ppb
504.5
2.803
.5557
Na3302
ppm
4.790
.0763
1.593
1960-1
ppb
494.3
5.34
1.08
H3349
ppb
500.4
.8618
.1722
A13082
ppb
549.8
11.63
2.116
Cd2265
ppb
506.5
2.453
.4844
X_7664
ppoi
4.770
.0039
.0827
Nil'316
ppb
508.6
1.098
.2159
1960-2
ppb
'SOO.3
2.733
.5556
111903
ppb
501.9
15.59
3.106
AS1890
ppb
503.0
2.658
.5284
C64186
ppb'
502.0
.2835
.0565
Li6707
ppb
471.3
1.514
.3212
P.2H9
ppb
506.4
4.205
.8303
Pb2203
ppb
492.7
.3996
.1826
VJ924
ppb
498.5
1.359
.2727
8.2496
ppb
1126.
289.1
25.63
C02286
ppb
491.1
1.704
.3469
Mg2790
ppb
494.2
n -ino
i.iOO
.4629
2203-1
ppb
477.5
13.53
2.835
Sel960
ppb
493.6
1.65
.331
Zn2062
ppb
495.1
1.921
.3879
8a4934
ppb
499.6
.8604
.1722
Cr2677
ppb
508.3
3.19
.6276
Mn2576
ppb
494.5
1.959
.3962
2203-2
pob
500.3
5.416
1.083
Snl899
ppb
Q9060.
42.96
.4741
Si288l
ppb
Q134400.
14970
11.14
8e3130
ppb
488.5
2.648
.542
Cu3247
ppb
499.3
3.39
.679
«o2020
ppb
495.0
3.113
.629
Sb2Co3
ppb
497.?
2.355
.4729
5r4215
PPb
498.4
.4037
.081





                                                                                                         219
-------
•Analysis Report      Averages
Bed 10-08-97  00:59:04 AH    page 12
Method: TRIANGL2   Sample Name: IC8/CC8                Operator: DKH
Run Time: 10/07/97 06:04           Filename:  100797
Mode: CONC         Type:  9        Corr. Factor:         1.00000
Lab 10.:           Cust.  Srnpl. ID.:            Cust.  10.: 43231
Eleios
Units
Avge
SDev
$RSD
Ag3280
ppb
.5385
.2869
53.28
A13082
ppb
Q57.04
2.91
5.101
AS1890
ppb
1.689
.6228
36.87
8_2496
ppb
1103.
345.8
31.34
8a4934
PPb
.2200
.1405
63.37
8e313C
ppb
.5654
.1555
27.49
 Elerns     Ca3179   Cd2265   Ce4186 _Co22fl6—frf^TJ—Cu3247
 Units     ppb      ppb      ppF     ppb      ppb      ppb
 Avge       -4.869   -.3955   -.7971   -.9458  Q5.127    Q-2.216
 SDev      .1377    .0709    .4798    .3115    .6631    .4563>
 %RSD      2.828    17.94    60.19    32.93    13.03
EleiBS
Units
Avge
SDev
SRSD
Fe2714
ppb
14.13
5.622
39.73
KJ664
ppm
.0282
.0217
77.04
U6707
ppb
.3119
.092
29.51
MQ2790
ppb
i.657/
1.6K
>T56
mut
ufi
' .1839
.1417
77.08
1102020
ppb
.6380
.4317
67.67
El ems
Units
Avge
SDev
IRSO
Ha3302 Ni2316 P.21/9 2203-1 2203-2 Sb2068
ppm ppb MTO ppo ppb poo
.0078 Q3. 213/5. 152 4.331 -5.130 Q4.165
.0636 .587 / 3.26 8.018 3.177 1.559
816.7 18.2i 63.27 166 61.33 37.44
El ems
Units
Avge
SDev
SRSD
1960-1
ppb /
11.58
1.8/S
15/56
/1 960- 2
ppb
-.6711
1.67S
250.1
PD2203
ppb
-1.346
.617
33.42-—
5el?60
ODD
Q3.457
1.174
•ToT'O
Snl399
ppb
g-iG5.i
28.36
27.47
Sr4215
ppb
f\fi^ f
.tLlj
.135
"59.36
Elems
Units
Avge
SDev
$RSD
TJ3349
ppo
.1627
.0632
41.92
T11903
ppb
3.96'}
2.724
68.62
V.2924
ppb
32.349
.2512
10.7
Zfi2062
ppb
1.139
.2836
24.89
Si2351
ppb
Q93760.
11540
12.3
                                                                                                  220
-------
'.Analysis Report      Averages
Wed 10-08-97 00:59:04 AM    page 13
 Method:  TRIANGL2    Sample  Name:  ICB/CC8                 Operator: DKH
 Run Tine:  10/07/97  06:19           Filename:  100797
 Mode:  CONC         Type: Q         Corr.  Factor:         1,00000
 Lab ID.:           Cust. Smpl.  10.:            Cust.  ID.:  43231
Eleits
Units
Avge
SDev
%RSD
Elens
Units
Avge
SOe'v
*RSD
Elems
Units •
Avge
SOev
',RSO
Eleins
Units
Avge
SDev
*RSO
Elens
Units
Avge
SDev
SRSD
Elains
Units
Avge
SDev
*RSD
Ag3280
ppb
-.5317
1.738
326.9
Ca3179
ppb
.5761
.8656
150.2
Fe2714
ppb
5.114
2.113
41.32
Ha3302
ppffl
-.2286
.5526
241.7
1960-1
ppb
4.529
2'. 188
48.31
Ti3349
ppb
.1194
.1123
94.47
A13082
ppb
-.5762
8.903
1545
Cd2265
ppb
.7945
.2941
57.01
KJ664
ppffl
,0601
.0243
40.42 .
Ni2316
ppb
2.343
.1125
4.802
1960-2
ppb
.9633
3.235
334.1
T11908
ppb
Q10.44
1.68
16.09
As 1890
ppb
4.251
.9086
21.37
Ca4136
Ppb'
2.189
1.289
58.91
U6707
ppD
.1608
.0506
31.45
P.2149
ppb
11.40
3.328
29.21
Pb2203
ppb
'l.225
1.312
107.1
V.2924
ppb
Q2.990
.698
23.34
8_2496
ppb
1531.
342.2
22.36
Co2236
Ppb
.2052
.2702 '
131.6
flg2790
ppb
2.086
2.249
107.8
2203-1
ppb
-.3249
3.728
1148
Sel960
ppb
2.154
2.015
93.56
Zn2062
ppb
.6097
.3819
62.65
834934
ppb
.0309.
.0293
94.81
Cr2677
ppo
1.853
.518
27.96
«n2576
ppo
-.0044
.0257
580.7
2205-2
PPb
1.999
3.531
176.7
Snl899
ppb
Q-21.31
17.37
81.52
5i2381
ppb
Q24/30.
9419
38
BeJloO
ppb
.0217
.0526
242.4
CU3247
ppb
Q-2.841
.6563
22.4
H02020
ppb
.1754
.•1378
249.6
3b2065
ppb
1.673
.3552
21.17
Sr4215
PPb
.0393
.0211
54.56





                                                                                                       991
                                                                                                       ^, M» JL
-------
"•Analysis Report      Averages
Bed 10-08-97 00:59:04 AM    page 14
 Method:  TRIANGL2   Sample Name: 183-3-6B              Operator: DKH
 Run  Time: 10/07/97 06:24           Filename:  100797
 Mode: CONC         Type: S         Corr. Factor:        1.00000
 Lab  ID.:           Cust. Sgpl. ID.:           Cust. ID.:  43231
El eras
Units
Avge
SDev
%RSD
Co2286 AS1890 Ba4934 8e3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-1.806 L4.283 8.844 1.1416 16.44 L.8027
.3095 .36 .0277 .0244 .0362 .5466
17.14 8.406 .3137 17.22 .2201 68.1
Eleiss
Units
Avge
SDev
IRSD
Cr2677
ppb
9.845
.7486
7.604
Mn2576
ppb
29.62
.0633
.2138
Ni2316
PPb"
11.50
.16
1.391
P.2149
ppb
L25.81
2.254
8.734
Pb2203
ppb
241.7
1.067
.4413
Sb2068
ppb
L3.938
1.543
39.19
El eras
Units
Avge
SDev
$RSD
Sel960
ppb
3.725
1.336
49.3
T11908
ppb
L.1661
.2842
171.1
Zn2062
ppb
92.84
.5221
.5624
                                                                                                 222
-------
Ana-lysis Report      Averages            Med  10-08-97 00:59:04 AN    page IS
Method:  TRIANGL2   Sample Mane:  183-3-7B              Operator:  DXH
Run Tine:  10/07/97 06:29          Filename:  100797
Node:  CONC        Type: S        Corr. Factor:        1.00000
Lab 10.:          Cost. Sipl.  ID.:            Cust.  10.: 43231
Eleios
Units
Avge
SDev
IRSD
Co2286 AS1890 8a4934 8e3130 Cd226S Ag3280
ppb ppb ppb ppb ppb ppb
L-2.318 5.244 7.222 L.1385 19.51 L.6510
.2215 1.829 .0532 .0252 .0542 .3015
9.553 34.88 .7369 18.16 .2777 46.31
Eleins
Units
Avge
SDev
*RSO
Cr2677
ppb
10.33
.815
7.89
Hn2576
ppb
56.90
.3025
.5317
Ni2316
PPb'
12.71
.6915
5.44
P.2149
ppb
30.66
4.756
15.51
Pb2203
ppb
167.8
.525
.3129
Sb2068
ppb
4.323
1.924
44.5
Eleros
Units
Avge
SDev
%R3D
Sel960 T11908 Zn2062
ppb ppb ppb
4.249 Li. 378 155.9
1.721 .741 1.698
40.51 53.77 1.09
                                                                                                   223
-------
. Analysis fteport     Averages
Bed 10-08-97 00:59:04 AN    page 16
 Method: TRIAN6L2   Sample Name:  183-3-88              Operator:  DKH
 Run Time: 10/07/97 06:34          Filename:  100797
 Mode: CONC        Type: S        Corr. Factor:        1.00000
 Lab 10.:          Cust. Sipl.  10.:            Cust. 10.: 43231
Elens
Units
Avge
SDev
?;RSO
C02286 Asl890 8a4934 Be3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-3.729 5.202 12.50 L.1025 3.949 9.942
.3914 .2739 .1446 .0193 .1164 .1831
10.5 5.265 1.157 18.84 2.948 1.842
Elents
Units
Avge
SDev
%RSD
Cr2677
ppb
20.67
.5764
2.789
Mn2576
ppb
170.9
1.392
.3148
Ni2316
PPb'
12.18
.2914
2.593
PJ149
ppb
L28.32
10.4
36.71
Pb2203
ppb
186.0
2.226
1.196
Sb2063
ppb
8.237
2.066
25.08
Elems
Units
Avge
SOev
$RSD
Sel960
ppb
8.440
.5147
6.099
111908
ppb
L-1.782
.6325
35.5
Zn2062
ppb
1600.
22.71
1.419
                                                                                                   224
-------
"Analysis (Sport      Averages
Ned 10-08-97 00:59:04 AH    page 17
 Method: TRIANGL2   Sample  Name: 183-3-18C             Operator: DKH
 Run  Tine:  10/07/97 06:38          Filename:  100797
 Mode: CONC         Type: S        Corr.  Factor:        1.00000
 Lab  ID.:           Cust. Smpl. ID.:           Cust. ID.: 43231
Elems
Units
Avge
SDev
*RSD
C02286
ppb
L-6.784
1.356
19.99
AslSSO
ppb
L-5.449
3.78
69.37
Ba4934
ppb
3.570
.0803
2.249
Be3130
ppb
L.1541
.0252
16.36
Cd2265
ppb
40.73
1.03
2.528
Ag32SO
PPb
4.852
.1807
3.725
Eleins
Units
Avge
SOev
iRSD
Cr2677
PPb
18.91
4.946
26.16
Hn2576
ppb
12.07
.1103
.9141
N12316
ppb'
10.73
4.136
38.53
P.2149
ppb
69.81
16.94
24.27
Pb2203
ppb
189.2
.1989
.1051
Sb2063
ppb
5.944
5.273
88.7
Elems
Units
Avge
SDev
%RSD
Sel960
ppb
10.08
3.405
33.76
T11908
ppb
L-11.90
2.273
19.14
Zn2062
ppb
168.3
3.07
1.824
                                                                                                      225
-------
•Analysis Report      Averages
Ned 10-08-97 00:59:04 AM    page 18
 Method:  TRIANGL2   Sample Name:  183-3-2C               Operator:  DKH
 Run Time:  10/07/97 06:43           Filename:  100797
 Mode:  CONC          Type:  S         Corr.  Factor:         1.00000
 Lab ID.:            Cust.  Sinpl. 10.:            Cust.  10.:  43231
Eleins
Units
Avge
SDev
IRSD
Eleras
Units
Avge
SDev
*RSD
Hems
Units
Avge
SDev
%RSD
Co2286
ppb
L-4.216
.5978
14.18
Cr2677
ppb
18.73
1.465
7.822
Sel960
ppb
15.14
2.63
17.37
Asl890
ppb
L-2.845
1.803
63.37
Mn2576
ppb
9.917
.081
.8172
T11908
Ppb
L-9.613
3.033
31.56
Ba4934
ppb
3.441
.0877
2.548
N12316
ppb'
5.882
1.84
31.29
Zn2062
ppb
151.2
2.213
1.464
Be3130
PPb
L.1431
.0226
15.81
P.2149
ppb
110. 7
9.969
9.003





Cd2265
ppb
3.120
.3987
12.78
Pb2203
ppb
24.72
1.227
4.964





Ag3280
ppb
1.084
.291
26.83
Sb2068
ppb
5.600
3.057
54.59





-------
         Rft'port      Averages
Ned 10-08-97 00:59:04  AM   page 19
Method:  TRIANGL2   Sample Name:  183-3-2C PDS          Operator:  DKH
Run Time:  10/07/97 06:48          Filename: 100797
Mode:  CONC        Type: S        Corr. Factor:        1.00000
Lab ID.:          Cust. Smpl.  ID.:            Cust.  ID.: 43231
Elems
Units
Avgs
SDev
IRSD
Elems
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
*,RSD
C02286
ppb
45.78
.5609
1.225
Cr2677
ppb
65.84
1.093
1.66
Sel960
ppb
57.09
1.199
2.101
AS1890
ppb
42.67
1.859
4.357
Mn2576
ppb
59.62
.2415
.4051
T11908
ppb
44.99
2.69
5.979
8a4934
ppb
52.75
.1318
.25
Ni2316
ppb"
53.36
.3677
.689
Zn2062
ppb
343.1
3.282
.9565
Be3130
ppb
46.90
.3142
.6698
P_2149
ppb
108.0
4.079
3.776





Cd2265
ppb
52.22
.427
.8177
Pb2203
ppb
73.37
1.074
1.463





Ag3280
ppb
46.67
.2279
.4883
Sb2068
ppb
51.92
2.589
4.986





                                                                                                      227
-------
.Analysis Report      Averages             Wed 10-08-97  00:59:04 AN    page 20
Method: TRIAN6L2   Sample  Name: 183-3-2C L             Operator: DKH
Run Time: 10/07/97 06:52          Filename:  100797
Node: COHC         Type: S        Corr. Factor:         1.00000
Lab 10.:           Cust. Sipl.  ID.:            Cust.  ID.: 43231
Eleros
Units
Avge
SDev
*RSD
Co2286 As 18% 8a4934 Be3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-1.161 L-.4891 L.6851 L.2191 L.4233 L.1553
.3492 .848 .0436 .0352 .0472 .4149
30.08 173.4 6.369 16.08 11.14 267.2
Eleras
Units
Avge
SDev
%RSD
Cr2677 Mn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb- ppb ppb ppb
4.711 2.062 LI. 933 30.07 4.713 LI. 112
.4529 .022 .3797 4.359 1.025 .986
9.613 1.067 19.64 14.5 21.76 38.64
 Elems     5el960   T11908   Zn2062
 Units     ppb      ppb      ppb
 Avge       3.517   1.1127    32.23
 SOev      .9451    2.654    .2552
 SRSD      26.37    2356     .7917
                                                                                                         22S
-------
Analysis  Report       Averages
Wed 10-08-97 00:59:04 AH    page 21
Method: TRIANGL2   Sample  Name: 183-3-3C               Operator: DKH
Run Tine:  10/07/97 06:57            Filename: 100797
lode: CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. S«pl.  10.:            Cust.  ID.: 43231
Eleois
Units
Avge
SOev
*RSD
Eleois
Units
Avge
SOev
%RSD
Elens
Units
Avge
SOev
%RSD
Co2286
ppb
1-2.508
.8657
34.51
Cr2677
ppb
18.80
1.792
9.535
Sel960
PPb
6.414
.8551
13.33
AS1890
ppb
1-4.446
2.354
52.95
Mn2576
ppb
78.28
.4926
.6293
T11908
PPb
1-6.124
2.299
37.54
8a4934
ppb
15.26
.0256
.1676
NJ2316
ppb'
3.754
1.2
31.98
Zn2062
ppb
459.4
5.811
1.265
8e3130
ppb
L.1054
.0473
44.9
PJ149
ppb
121.7
4.906
4.03





Cd2265
ppb
1.109
.2281
20.56
Pb2203
ppb
95.22
1.243
1.305





Ag3280
ppb
1.419
.561
39.53
Sb2063
ppb
L2.873
3.743
130.3





-------
"•Analysis' Report      Averages
Wed 10-08-97  00:59:04 AM    page 22
Method: TRIANGL2   Sample  Name: 183-3-3C DA            Operator:  DKH
Run Time: 10/07/97 07:02          Filename:  100797
Mode: CONC         Type: S        Corr. Factor:        1.00000
Lab ID.:           Cust. Sipl. ID.:           Cust. 10.: 43231
Elems
Units
Avge
SDev
*RSD
C02286 AS1890 8a4934 8e3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-1.929 L-4.54S 15.18 L.0945 1.225 1.515
.5267 .4272 .0288 .0361 .3143 .4331
27.3 9.401 .1901 38.24 25.66 28.58
Elems
Units
Avge
SDev
%RSO
Cr2677
ppb
17.90
.847
4.733'
Mn2576
ppb
78.20
.272
.3478
Ni2316
ppb-
12.658
.695
26.14
P.2149
ppb
129.4
3.099
2.394
Pb2203
ppb
96.23
1.145
1.19
Sb2068
ppb
L3.852
.6
15.57
Elems
Units
Avge
SDev
SRSD
Sel960
PPb
5.137
.999
19.45
T11908
ppb
L-7.383
2.553
32.44
Zn2062
ppb
459.2
3.201
.6971
                                                                                                 230
-------
'Analysis Report     Averages
Wed 10-08-97 00:59:04 AM    page 23
Method: TRIANGL2   Sample Name: 183-3-4C               Operator: OKH
Run Time: 10/07/97 07:06           Filename: 100797
Mode: CONC        Type: S         Corr.  Factor:        1.00000
Lab ID.:          Cust. Snpl. ID.:           Cust.  ID.:  43231
[lens
Units
Avge
SDev
IRSD
Co2286 Asl890 Ba4934 8e3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb
L-2.251 L-2.307 7.222 L.2053 13.11 2.964
.5416 .263 .1023 .03 .169 .414
24.06 11.4 1.417 14.63 1.289 13.97
Elems
Units
Avge
SOev
*RSD
Cr2677 Mn2576 Hi2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
13.07 640.4 LI. 556 131.1 483.0 4.079
.3783 3.483 .4508 8.039 6.131 3.553
6.72 .5439 28.97 6.131 1.269 87.1
El ens
Units
Avge
SOev
tRSD
Sel960
ppb
4.593
1.21
26.35
T11908
ppb
L-4.718
3.003
63.64
Zn2062
ppb
2404.
27.57
1.147
                                                                                                  231
-------
Analysis Report      Averages
10-08-97  00:59:04 AM    page 24
Method:  TRIANGL2   Sample Name: ICV/CCV               Operator:  DKH
Run Time:  10/07/97 07:12          Filename:  100797
Hode:  CONC         Type: 0        Corr.  Factor:        1.00000
Lab 10.:          Cust. Smpl.  10.:            Cust.  10.: 43231
Eleios
Units
Avge
SDev
IRSO
[lens
Units
Avge
SOev
*RSD
Elens
Units
Avge
SOev
°<;RSD
Elects
Units
Avge
SOev
*RSO
Elems
Units
Avge
SDev
4RSO
Elems
Units
Avge
SDev
%RSD
Ag3280
ppb
498.0
2.278
.4574
Ca3179
Ppb
500.5
1.068
.2133
Fe2714
ppb
492.0
11.67
2.372
Na3302
ppffl
4.711
.1239
2.631
1960-1
ppb
488.5
1.767
.3613
H3349
ppb
495.1
1.004
.2027
A13082
ppb
522.4
10.14
1.942
Cd2265
ppb
499.5
1.732
.3467
K_7664
ppro
4.736
.0482
1.018
Ni2316
opb
498.4
1.254
.2516
1960-2
ppb
494.2
2.397
.5861
T11908
ppb
503.5
1.788
.3552
Asl390
ppb
499.4
1.46
.2923
Ce41S6
ppb"
493.0
3.176
.6443
Li6707
ppb
464.2
5.36
1.155
P.2149
ppb
501.6
3.926
.7827
Pb2203
ppb
496.2
2.997
.6035
V.2924
ppb
496.5
.9821
.1978
B.2496
ppb
3099.
361.8
11.67
C02286
ppb
493.8
1.317
.2667
Hg2790
ppb
497.2
2.444
.4915
2203-1
Ppb
488.5
1.726
.3534
Sel960
ppb
492.3
2.519
.5115
Zn2062
ppb
496.6
3.39
.6826
Ba4934
ppb
489.6
.6792
.1387
Cr2677
ppb
500.1
1.846
.369
Mn2576
ppb
496.0
1.26?
.2553
2203-2
ppb
500.1
4.653
.93U
Snl899
ODD
Q9392.
48.24
.5136
Si2881
ppb
017090.
245.4
1.424
Be3130
ppb
490.7
2.24
.4565
Cu3247
ppb
492.5
3.788
.769
Mo2020
ppb
493.6
1.95
.3952
Sb2068
bob
488.?
1.181
.2416
Sr42l5
ppb
491.5
.1941
.0395





                                                                                                  232
-------
'•Analysis  Report      ftverages
Wed 10-08-97 00:59:04 AN    page 25
 Method:  TRIANGL2   Sauple Name: IC8/CCB               Operator: DKH
 Run Time: 10/07/97 07:17           Filename: 100797
 Mode:  CONC         Type:  Q        Corr.  Factor:        1.00000
 Lab 10.:           Cust.  Sipl. 10.:           Cust. 10.:  43231
Eleras
Units
Avge
SDev
%RSO
Eleras
Units
Avge
SDev
IRSD
Elems
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
4RSD
cleus
Units
Avgs
SDev
*RSD
tieros
Units
Avge
SDev
%RSD
Ag3280
ppb
.5632
.4598
81.64
Ca3179
ppb
-2.486
.4173
16.79
Fe2714
ppb
.8134 .
4.334
532.8
Na3302
ppm
.0185
.0943
510.3
1960-1
ppb
4.275
.3584
20.08
Ti3349
ppb
.4956
.1189
24
A13082
ppb
36.66
4.451
12.14
Cd2265
ppb
.2293
.2363
103.1
KJ664
ppiB
.0607
.0181
29.75
Ni2316
ppD
.9271
.4753
51.27
1960-2
opb
-.4360
1.606
363.4
T11903
ppb
Q7.715
4.843
62.78
AS 1890
PPb
1.069
1
93.54
Ce4186
ppb-
-.0852
.527
618.3
Li6707
PPb
.5874
.1166
19.85
P.2149
PPb
6.954
3.465
49.83
Pb2203
ppb
-.5180
.9348
130.5
V.2924
opb
1.815
.1197
6.593
B.2496
ppb
2589.
228.7
8.835
Co2236
ppb
.1817
.0916
50.41
Mg2790
ppb
1.017
1.452
142.3
2203-1
ppb
1.120
3.329
297.3
Sel960
ppD
1.133
.91
30.34
2n2062
opo
.7824
.0212
2.713
Ba4934
ppb
.42^8
.1381
32.13
Cr2677
PPb
1.091
.03^7
3.641
Mn25-6
ppb
.5471
.146
26.69
2203-2
ppo
-1 .336
1.426
106.3
Snl399
ppb
Q1S.73
7.422
39. o2
Si286l
opb
012830.
730.1
5.692
6e3130
ppb
.7008
.1876
26.77
Cu3247
PPb
-.9285
.3665
39.47
flo2020
ppb
1.502
.4715
31.39
5b2C63
ppb
3.275
1.41
43.06
Sf4215
opb
.4860
.1582
32 . 55





                                                                                                  233
-------
'Analysis' Report      Averages
                               Wed 10-08-97 00:59:04 AM    page 26
 Method:  TRIANGL2   Sample Name: 183-3-5BC             Operator: DKH
 Run  Time:  10/07/97 07:23           Filenaue:  100797
 Mode:  CONC         Type: S         Corr.  Factor:         1.00000
 Lab  ID.:          Oust. Sipl. ID.:            Cust.  ID.: 43231
 Elens
 Units
 Avge
 SDev
 $RSD

 Elents
 Units
 Avge
 SDev
 $RSD

 Eleios
 Units
 Avge
 SDev
 SRSD
Co2286
ppb
L-1.457
.4882
33.51
Cr2677   Hn2576
ppb      ppb
 5.442    9.5CT4
.5392
9.908  /.3263
                 JK2316
               /ppb-
         T11908    Zn2062
         ppb      ppb
 12.77   1-2.601    114.6
 .7102    .5646    .9378
                                   Cd2265   Ag3280
                                   ppb      ppb
                                    1.687.   L.8616
                                   .2192    .5426
                                   13       62.97
Sb2068
ppb
LI.901
1.328
69.85
Se
                                                                                                       234
-------
1 Analysis Report      Averages
                               Wed  10-08-97 00:59:04 AM   page 27
 Method:  TRIANGL2   Sample Name:  183-3-6C               Operator: DXH
 Run Time:  10/07/97 07:27           Filename: 100797
 Mode:  CONC        Type: S         Corr.  Factor:        1.00000
 Lab ID.:          Cust. Sipl. ID.:           Cust. ID.: 43231
El ems
Units
Avge
SDev
%RSD
Co2286
Ppb
L-1.526
.4706
30.84
As 1890 "
ppb
L-3.844
.889
23.12
~Ba4934
ppb
3.043
.0476
1.566
Be3130
ppb
L.2005
.045
22.45X
Cd2265
PPb >
L.8JJ&S
.x-f395
15.7
AjjSttO
xtfpb
L.8136
.4068
50
El eras
Units
Avge
SDev
%RSD
Cr2677
ppb
8.543
.4332
5.071
«n2576
ppb
7.011
.0662 /
.9436/
Ni2316>
PPb/
1/3612
/:5791
160.3
"PJ2149
ppb
91.00
1.274
1.401
Pb2203
ppb
15.54
.8226
5.294
Sb2068
PPb
LI. 250
1.429
114.3
 El eras
 Units
 Avgs
 SDev
 %RSD
Sel960
PPb
 3.292
1.635
49.65
 ppb
[L-2.546
^^JAT" —

 17.56
Zn2062
PPb
                                                                                                        235
-------
Analysis  Report      Averages
                              Wed 10-08-97 00:59:04 AH    page 28
Method:  TRIANGL2   Sample Name:  183-5-7C              Operator: DKH
Run Time:  10/07/97 07:32          Filenane:  100797
Node:  CONC         Type: S        Corr. Factor:        1.00000
Lab 10.:           Cust. Sipl.  10.:            Cust.  10.: 43231
Elens
Units
Avge
SDev
IRSD
Co2286
PPb _
L-1.108
.506
45.66
AS1890
_ppb 	 •
1-3.723
1.631
43.82
Ba4934
^*r~~*"
-PPD
7.064
.061
.8632
J&&KT
ppb
L.1714
.0323
18.85
•"U32265
ppb
L.783?
.318^*
40xSf
AQ3280
ppb >
M70
<4752
40.62
Eleins
Units
Avge
SOev
%RSD
Cr2677
ppb
10.57
.6398 '
6.054
Mn2576
PPb
8.516
.1143
1.342 >
N12316
ppb'
l.SMK
J&l
M21.2
P 2JW1
/p|b
113.3
3.448
3.044
Pb2203
ppb
21.08
.7887
3.74
Sb2068
ppb
L3.022
3.133
103.7
                                                                                                             -\
Elems
Units
Avge
SDev
Sel960   U1908
ppb    /ppb
 14.3    L-4.576
         .6368
475    13.92
                                                                                                       23B
-------
'Analysis Report      Averages
Ned 10-08-97 00:59:04 AM    page 29
 Method:  TRIANGL2   Sample Name:  183-3-8C               Operator:  DKH
 Run Time:  10/07/97 07:38           Filename:  100797
 Mode:  CONC        Type: S         Corr.  Factor:        1.00000
 Lab ID.:          Cust. Srapl. ID.:           Cust. ID.: 43231
 [leas
 Units
 Avge
 SDev
 *RSD

 Eleras
 Units
 Avge
 SDev
 *RSD

 Elems
 Units
 Avge
 SDev
 °.RSD
C02286
PPb
L-1.817
^Ivvv
38.89
Cr2677
PPb
9.054
.5541
6.12
Sel960
PPb/
3/20
/96
5.27
AS1890
ppb

1.642
40.76
Mn2576
PPb
16.10
.1184
.735/
/11908
ppb
L-6.378
.3194
5.008
Ba4934
Pfib — *"
3.645
.084
2.304
Ni2316
PPb' /'
7,4i6
X7708
10.39
Zn2062
ppb
140.1
2.001
1.428
8e313j).
•"ppb
L.1906
.039
20.47
R^-2149
Xppb
110.3
1.194
1.083





    Pb2203
    ppb
     23.83
    1.196
    5.021
 T7658
.5403
70.56

Sb2068
ppb
LI.887
1.519
80.52
                                                                                                        231
-------
Analysis'Report     Averages
     Wed 10-08-97 00:59:04 AH    page  30
Method:  TRIANGL2  Sample Name:  43231  MB
Run Time: 10/07/97 07:42           Filename:  100797
Mode: CONC        Type: S         Corr.  Factor:
Lab ID.:          Oust. Sopl. ID.
Eleis     Co2286   Asl890
Units     ppb      ppb
Avge      L-.7094  L-1.691
SDev      .2122    .7641
*RSO      29.92    45.2
                 Operator: DKH

                  1.00000
                    43231
 0078
3.756
         Ag3280
ppb      ppb
L-.3305  L.2580
.3004    .0152
90.9     5.899
                                            Pb2203
                                            ppb
                                             2.021
                                            .8474
                                            41.94
                                                                                                         238
-------
'Analysis Report      Averages
                              Wed 10-08-97 00:59:04 AN    page 31
Hethod: TRIAN6L2   Sample Name: 43231 LCS             Operator:  DKH
Run Time: 10/07/97 07:47          Filename:  100797
Node: CONC         Type: S        Corr.  Factor:        1.00000
Lab ID.:           Cust. Sapl.  ID.:            Cust.  ID.: 43231
El ems
Units
Avge
SDev
IRSD
C02286 AS1890 8a4934 Be3130 Cd2265 Ag3280
ppb ppb ppb ppb ppb ppb/"
46,18 44.02 46.31 44.62 46.76 /43.15
.5436 .6175 .0547 .1791 .08^X^.223
1.177 1.403 .1181 .4014 ^Hll .5168
                                                                                                r\
El eras
Units
Avge
SOev
IRSO
Cr2677
ppb
47.61
.4845
1.018
Nn2576
PPb
47.38
.1828
.38S8/
Ni2316
PPb' /
4#fo
X2643
.5886
B/Z149
'PPb
903.1
5.482
.6071
Pb2203
ppb
45.36
.5191
1.132
Sb2068
ppb
46.84
1.144
2.442
 Elems
 Units
 Avge
 SDev
 *RSD
Sel960  /T11908
ppb  / ppb
    89    49.42
  509    2.208
 .017
Zn2062
PPb
 189.3
1.914^
 .011
                                                                                                          239
-------
Analysis Report      Averages
                               Bed 10-08-97 00:59:04 Ad    page 32
Hathod: TRIANGL2   Sample Name: 184-23-1A8             Operator: DKH
Run Tine: 10/07/97 07:52           Filenaue: 100797
Node:  CONC         Type: S         Corr. Factor:        1.00000
Lab 10.:           Cost. Sipl. 10.:            Cust.  ID.:  43231
Elens
Units
Avge
SDev
%RSD

El ems
Units
Avge
SDev
*RSD

Elens
Units
Avge
SDev
*RSO
Co2236
ppb
 220.5
3.464
1.571
Asf
ppb
 1146.
7.119
.6212
Cr2677   Hn2576
ppb      ppb
 9376.   H119800.,
26.18    1600
.2792    1
         /
Sel960/T11908
ppb  /  ppb
   ».9    365.8
PPb
 12090.
23.41
.1937
         Ni2316
          '1975.
         .7151
         .0362
SS3T30
ppb
7.474
.5287 >
7. OK
s
PJ149
ppb
14070.
18.81
.1337
Cd2265
PPb /
2»£
^.54
.1549
Pb2203
ppb
H515300.
3877
.7524
Ag«280
ppb
104.3
2.228
2.136
Sb2068
PPb
6628.
16.15
.2437
                                                                                                             240
-------
Analysis Report      Averages
                                          Wed  10-08-97  00:59:04 AH    page 33
Method: TRIAN6L2   Sample Name:  ICB/CCB               Operator: DXH
Run Time: 10/07/97 10:36           Filename:  100797
Mode: COHC         Type: 0         Corr.  Factor:         1.00000
Lab ID.:           Cust. Sipl. 10.:            Cust.  ID.:  43231
Elems
Units
Avge
SOev
*RSD

Elems
Units
Avge
SOev
%RSD

El eras
Units
Avge
SOev
*RSO
Ag3280   A13082
ppb      ppb"
 -.0062  059.41
.1122    1.81
1811     3.047

Ca3179   Cd2265
ppb      ppb
 -3.314   -.0176
,266     .1117
8.028    633.6
                            Asl890   8.2496
         8a4934
          tfr
                                     27.91
                  CU3247
         ppb      ppb
          .1885    -.2727
         .1585    .1278
         34.08    46.85
          Fe2714
          ppb
           -3.106
          9.028   yo02
         K 7664  ,116707
          ~    /   .
         ppra  /•   ppb
                   .1566
                  .0024
290.6.'  4.07
                            1.547
                   NJ2316
                   ppb
            .0409    2.079
           .0453    .3544
           110.9    17.05
                            ?b2203
                            ppb
                            0-2.166
Hg2790   Mn2576   Mo2020
ppb      ppb      ppb
 -.1193   -.0542   -.6430
1.226    .0354    .0585
1028     65.4     9.0jr~
                                     575.5
                                    SnlS99   S.-4215
                                    ppb     ppb
                                    Q81.00     .0037
                                            .0125
                                    9.497^   IT?
Elems
Units
Avge
SDev
*RSD
          H3349   T11908
          ppb      ppb
           -.0439   4.802
          .1148    .1333
          261.4    2.775
                  V.2924
                  ppb
                   .4958
                  .0568
                  11.46
Zn2062
PPb
 7.076
.225
3.18
Si2881
PPb
Q-57S.7
2.038
.354
                                                                                                               241
-------
 Analysis. Report      Averages
Wed 10-08-97 00:59:04 AH    page 34
 Method:  TRIAN6L2   Sample  Name: ICV/CCV               Operator: DKH
'Run  Tine: 10/08/97 00:37           Filename: 100797
 Node:  CONC         Type: Q        Corr.  Factor:        1.00000
 Lab  ID.:           Cust. Smpl. ID.:           Cust. ID.:  43231
Elems
Units
Avge
SDev
*RSD
Eleins
Units
Avge
SOev
IRSD
Eleias
Units
Avge
SDev
*RSD
El eras
Units
Avge
SDev
SRSD
Elems
Units
Avge
SDev
*RSD
Eleras
Units
Avge
SDev
SRSD
Ag3280
ppb
487.2
2.254
.4628
Ca3179
ppb
505.1
3.893
.7706
Fe2714
ppb
494.4
15.34
3.103
Na3302
ppiB
Q4.108
.0994
2.42
1960-1
ppb
445.1
1.342
.3016
Ti3349
ppb
515.2
1.203
.2334
A13082
ppb
0669.4
11.67
1.743
Cd2265
ppb
504.7
2.822
.5592
KJ664
ppm
Q4.393
.0173
.4043
(U2316
ppb
498.1
2.722
.5465
1960-2
ppb
480.7
4.53
.9423
T 11903
ppb
499.0
11.63
2.332
Asl890
ppb
487.8
1.722
.353
Ce4186
ppb"
498.5
1.957
.3925
Li6707
ppb
9448.3
3.613
.3058
P.2149
opt)
477.5
3.S26
.8013
Pb2203
ppb
500.7
3.405
.6801
V_2924
ppb
485.3
1.753
.3609
B_2496
ppb
281.0
2.616
.9308
Co2286
ppb
481.9
2.348
.591
Plg2790
pDD
495.6
5.718
1.154
2203-1
ppo
480.1
2.576
.5366
Sel960
ppb
468.9
2.6
.5545
Zn2062
ppb
472.4
4.312
1.019
8a4934
ppb
501,?
1.313
.2616
Cr2677
ppb
502.3
3.181
.6333
Hn257c
ppb
497.0
2.233
.-5502
2205-2
ppo
511.1
5.641
1.104
Snl899
ppb
Q9309.
68.76
.7387
Si2881
ppb
Q-467 .6
1.7
.3635
Be3130
ppb
457.8
2.689
.5873
Cu3247
PPb
493.8
3.596
.721
1102020
ppb
495.6
2.781
.5654
3b2068
ppo
487.4
2.899
.5949
Sr4215
ppb
516.2
1.045
.2024





                                                                                                           242
-------
ftnjlysis Report      Averages
Hed 10-08-97 00:59:04 AH    page 35
Method: TRIAN6L2   Sample Name: ICB/CC8               Operator:  DKH
 jn Tine: 10/08/97 00:42          Filename:  100797
 Jde: CONC        Type: Q        Corr. Factor:        1.00000
Lab ID.:          Cust. Smpl.  ID.:            Cust. ID.: 43231
tlems
Units
/ge
-Dev
*RSD
leras
Units
*vge
Dev
«RSO
lens
.nits
Avge
Dev
RSO
-'leas
nits
Hvge
SDev
:RSO
El ems
nits
vge
SDev
"-RSO
clems
Units
vge
.Dev
*RSD
Ag3280
ppb
.3916
.2666
68.08
Ca3179
ppb
-7.189
.6779
9.43
Fe2714
ppb
5.411
2.229
41.2
Na3302
ppm
-.0370
.0605
163.3
1960-1
ppb
-6.508
.8738
13.43
Ti3349
ppb
.4906
.0553
11.26
A13082
ppb
Q182.6
7.268
3.979
Cd2265
ppb
.3826
.1892
49.45
K_7664
ppm
-.0233
.0145
62.28
Ni2316
ppD
-.1446
.6003
415.3
1960-2
ppb
3.181
1.012
31.33
111908
ppb
Q9.320
4.261
45.72
AS1890
ppb
-1.629
2.214
136
C64186
ppb-
.2814
.8087
287.4'
Li6707
ppb
.5986
.0413
6.903
P.2149
pob
-5.639
1.584
28.08
?b2203
ppb
.6493
.3022
46.55
V.2924
ppb
Q4.559
.4512
9.897
8.2496
ppb
-221.3
.3662
.1655
C02286
ppb
-.0945
.1859
196.8
Mg2790
ppb
1.866
.6428
34.45
2203-1
ppb
4.249
1.159
27.29
Sel960
ppb
-.0454
.4245
934
Zh2Q62
ppb
1.345
.2023
15.04
Ba4934
ppb
.4201
.0557
13.27
Cr2677
ppb
.5804
.3297
56.8
Mn2576
ppb
.5211
.0456
8.742
2203-2
ODD
-1.1*3
1.027
89.52
Snl8
-------
(*?)aly,slstReport      Averages
Wed 10-08-97 00:59:04 AH    page  36
Method:  TRIANGL2   Sample Name:  ICSA8                  Operator: DKH
Run Time:  10/08/97 00:47          Filename: 100797
Mode:  CONC        Type: Q        Corr. Factor:         1.00000
Lab ID.:           Cust. Sropl.  10.:            Cust.  ID.: 43231
El eras
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
*RSD
Elens
Units
Avge
SOev
USD
Elems
Units
Avge
SDev
SREO
Elens
Units
Avge
SDev
*RSD
Ag32SO
ppb
528.1
1.92
.3636
Ca3179
ppb
462200.
944.6
.2044
Fe2714
ppb
175500.
208.4
.1188
Na3302
ppiB
4.689
.066
1.407
1960-1
pob
495.8
5.425
1.094
Ti3349
PPb
516.2
.5002
.0969
A13082
ppb
497300.
3913
.7868
Cd2265
ppb
482.4
.8757
.1815
K_7664
ppi»
Q23.40
.0206
.088
Ni2316
ppb
461.5
1.79
.3879
1960-2
ppb
509.0
4.32
.947
T11908
PPB
516.0
16.55
3.207
ASJS90
ppb
515.6
2.538
.4922
Ce4186
ppb-
505.6
1.849
.3658
Li6707
ppb
588.0
1.016
.1728
P_2149
ppb
499.3
7.667
1* * f
.300
Pb2203
PPb
491.3
2.908
.5919
V_2924
ppb
485.0
1.39
.2866
BJ496
ppb
313.4
.6637
.2118
C02286
ppb
461.2
.978
.2121
Hg2790
ppb
527200.
761.9
.1445
2203-L
PPb
498.8
5.345
1.072
Sel960
ppb
504.6
1.604
.3173
Zn2062
ppb
428.6
3.987
.9303
8a4934
ppb
524,2
1.87
.3568
Cr2677
ppb
486.7
1.406
.2888
Mn2576
ppb
463.7
1.351
.2913
2203-2
oob
'487.6
6.914
1.418
Snl899
ppb
Q9775.
54.97
.5624
Si2381
ppb
Q-172.7
4.416
2.557
Be3130
ppb
458.3
1.521
.3319
Cu3247
ppb
540.7
3.726
.6891
M02020
ppb
493.2
2.742
.5504
Sb2068
ppb
510.8
4.903
.9609
SN215
ppb
531.1
1.389
.2615





                                                                                                            244
-------
  AutoSapf'er Report   Table: HA452
   Red  10-08-97 02:10:19 AH     page 1
  fable Name: HA452            Autosanpler Type:  TYPE TJA
. Sample Positions:  170/192    QC Positions: 13/19      It  Sets: 1
  Rinse Station location  is  rack -1, DOS. -1.
                                                 *Pos Left  Analyses/Pos
— Racks —
'Hack ft Type
1
2
3
4
5
Aux. (I) Rack
Sample (16nn)
Sample (16mm)
Sample (16m)
Sample (16mm)
Usage
STD/OC/8LANK
Samples
Samples
Samples
Samples
13
,26
48
48
48
10
1
1
1
1
  — Sample Sets —

  Sett  Type      Prepare?  Description

     1   Normal      No      43231

  — Preparation Info —

  Sett  Uptake    Uptake«2    Final
         Method    «Pos  Rack!  StartPos

         TRIAN6L2    22     2      1
Oil.Factor
  No Samples Prepared.

  Rack HI

  Pos  Row  Col   Sample Name
Set It  aused
                Type
1
2
3
4
5
6
(7..
1
1
1
1
1
1
.19
1
2
3
4
5
6
Not
STD3
STD1-BLANK
ICSA8
CHECK LO
ICV/CCV
ICB/CCB
Used)
-NA-
-NA-
-NA-
-NA-
-NA-
-HA-

2
1
2
1
4
4

Standard 1'
Standard
OC Standard
QC Standard
QC Standard
QC Standard

                                                                  -c,\- \
  Rack 112
  Pos  Row  Col   Sample Naae
Set i  «Used     Type
I
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
I
1
1
1
I
1
1
1
1
1
1
1
2
2
2
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
183-3-38 X50
183-3-38 X50 DA ]
183-3-58C
183-3-6C
183-3-7C
183-3-8C
43231 MB
43231 LCS
184-23-1A8
184-23-2A8
184-23-2AB
184-23-3A8
184-23-3AB
184-23-4A8
184-23-6AB

1

1

]
xso
XSO ]
XSO L
XSO
XSO DA
XSO
XSO
I -NA- Sample
-NA- Sample
1 -NA- Sample
-NA- Sample
1 -NA- Sample
-NA- Sample
[ -NA- Sample
-NA- Sampl.e
-NA- Sample
-NA- Sample
-NA- Sample
-NA- Sample
-NA- Sample
-NA- Sample
-NA- Sample
                                                                                                       245
-------
.,AutoSat»pler Report   Table:  HA452         Hed 10-08-97 02:10:19 AN     page 2
 «>      >
  Rack 12
*
  Pos  Row  Col   Sample Name            Set 8  (Used    Type
16
17
18
19
20
21
22
(23.
2
2
2
2
2
2
2
..48
4 184-23-7AB XSO
5 184-23-8A8 XSO
6 184-23-9AB XSO
7 184-23-10AB.5 XSO
8 183-15-1C
9 laS-lS-lBj?1*^,,^.,,^,^
10 ( empty )
Not Used)
I
1
1
1
1
t 1
1

-NA-
-NA-
-NA-
-NA-
-NA-
-NA-...
-NA-

Saaple
Sample
Sample
Sample
Sample
Saaple
-NA-

  Rack 83

  Pos  RON   Col   Sample Name           Set 8  lUsed     Type

  (1...48    Hot Used)

  Rack «4

  Pos  RON   Col   Sample Name           Set 8  8Used     Type

  (1...48    Not Used)

  Rack 85

  Pos  RON   Col   Sample Name           Set i  ttUsed     Type

  (1...48    Not Used)
                                                                                                     246
-------
Analysis Report      Averages
Hed 10-08-97 07:03:45 AN     page  4
Method: TRIANGL2   Sample Name:  STD1-BLANK              Operator:
Run Tine: 10/08/97 02:11           Filenane:  100797
Mode: IR           Type: X         Corr.  Factor:         1.00000
Lab ID.:           Oust. Snpl.  ID.:             Cust.  ID.:
Elens     Ag3280   A13082   As1890   B.2496   Ba4934   8e3130
Units     count    count    count    count     count     count
Avge       0        .00575   -.0004   .0037    .00062   .00085
SDev      .00011   .00009   .00006   .00018   .00001   .00002
tRSO      18087.5  1.71474  15.4235  5.05971   1.86892  2.9699

Eleus     Ca3179   Cd2265   Ce4186   Co2286   Cr2677   Cu3247
Units     count    count    count    count     count     count
Avge       .00033   -.00009  -.00005  -.00016   -.0001   .00229
SDev      .00001   .00019   .00009   .00003   .00005   .00004
*RSD      5.19045  209.65   184.618  22.4583   50.3011  1.84165

Elems     Fe2714   K.7664   Li6707   Mg2790   Hn2576   Ho2020
Units     count    count    count    count     count     count
Avge       .00005   3.89015  .07635   .00013    .00003   .00006
SDev      .00003   .02683   .00034   .0001     0        .00004
*RSD      57.6222  .6897    .44804   77.3615   11.5067  74.4291

Eleus     Na3302   Ni2316   P.2149   2203-1   2203-2   Sb2068
Units     count    count    count    count     count     count
Avge       .00104   -.00168  -.00093  .00173    .00004   .00073
SDev      .00226   .00018   .00003   .00048   .00016   .00022
*RSD      216.865  10.7239  3.77577  28.1234   384.12   30.9777

Eleras     1960-1   1960-2   Snl899   Sr4215   Ti3349   T11908
Units     count    count    count    count     count     count
Avge       -.00648  .00232   -.0004   .00033    .00016   -.00034
SDev      .00038   .00034   .00013   .00001   .00011   .00007
*RSO      5.86225  14.9219  33.245   5.3312   72.6622  22.7504

Elems     V_2924   Zn2062   Si2881
Units     count    count    count
Avge       -.00032  .00008   .01863
SOev      .00002   .00003   .00002
*RSD      7.08465  42.1786  .15691
                                                                                                         247
-------
( Analysis Report      Averages
Ned 10-08-97 07:03:45 AH     page 5
  Method:  TRIAN6L2   Sample  Name: STD3                   Operator:
  Run Tiie: 10/08/97 02:16          Filename: 100797
  Hode:  IR        .   Type: X        Corr. Factor:        1.00000
  Lab ID.:           Oust. Sopl.  ID.:            Cust. ID.:
  Elens     Ag3280   A13082    Asl890   8.2496   Ba4934   Be3130
  Units     count    count    count    count    count    count
  Avge       .38497   .02043    .05097   .16505   .2893.7   .23431
  SOev      .0015    .00034    .00013   .00019   .00036   .00102
  tRSD      .39163   1.67379   .26263   .11973   .12707   .43841

  Elens     Ca3179   Cd2265    Ce4186   Co2286   Cr2677   Cu3247
  Units     count    count    count    count    count    count
  Avge       .02224   .92028   .11079   .10035   .14505   .17642
  SDev      .00008   .00407    .00011   .00035   .00044   .00115
  IRSD      .36079   .44328    .10096   .34883   .30798   .65246

  Elens     Fe2714   KJ664    Li6707   Hg2790   Mn2576   Mo2020
  Units     count    count    count    count    count    count
  Avge       .00408   21.8268  14.981   .01976   .12633   .07576
  SDev      .00002   .02927    .03249   .00001   .00044   .0004
  IRSD      .72347   .13412    .2169    .08686   .35048   .53452

  Eleis     Na3302   Ni2316    PJ149   2203-1   2203-2   Sb2068
  Units     count    count    count    count    count    count
  Avge       .19977   .3416     .02126   .16974   .08997   .11321
  SDev      .00347   .00095    .0002    .00103   .00037   .00035
  *RSD      1.74049  .27985    .96336   .6079    .4169    .31007

  Elesis     1960-1   1960-2    Snl899   Sr4215   H3349   T11908
  Units     count    count    count    count    count    count
  Avge       .24882   .15605   .10968   .83545   1.11886  .03102
  SDev      .00183   .00038    .00038   .00054   .00186   .00081
  *RSD      .73765   .24925    .35463   .06528   .16681   2.62214

  Elens     VJ924   Zn2062    Si2881   Pb2203   Sel960
  Units     count    count    count
  Avge       .03661   .09328   .46311
  SDev      .00009   .00065    .0027
  *RSD      .24992   .69981    .58429
                                                                                                           248
-------
Analysis  Report      Averages
Wed 10-08-97 07:03:45 AH     page 6
Method:  TRIANGL2   Saaple Name:  STD3                  Operator:  DKH
Run Tiae:  10/08/97 02:21          Filename: 100797
Node:  CONC        Type: 0        Corr. Factor:        1.00000
Lab ID.:           Cust. Sipl.  ID.:            Cust. ID.: 43231
[leas
Units
Avge
SOev
tRSD
Eleins
Units
Avge
SOev
tRSD
Elens
Units
Avge
SDev
IRSO
Elems
Units
Avge
SDev
tRSD
Elens
Units
Avge
SDev
tRSD
Elens
Units
Avge
SDev
tRSD
Ag3280
PPb
999.7
3.694
.3695
Ca3179
ppb
1003.
4.529
.4516
Fe2714
PPb
997.5
• 10.97
1.1
Ha3302
ppffl
9.832
.1523
1.549
1960-1
ppb
1006.
3.246
.3227
V.2924
PPb
1003.
3.042
.3034
A13082
ppb
993.9
22.08
2.221
Cd2265
ppb
1003.
3.344
.3335
KJ664
PP»
9.993
.0422
.4221
Ni2316
ppb
1003.
2.648
.264
1960-2
ppb
1006.
3.149
.313
Zn2062
ppb
1007.
7.998
.7942
Asl890
ppb
1000.
1.654
.1653
Ce4186
ppb"
1003.
1.126
.1123
Li6707
ppb
998.7
5.033
.5039
P.2149
ppb
1009.
9.913
.9826
Snl899
PPb
1003.
2.994
.2985
S12881
ppb
10010.
56.74
.5668
8.2496
ppb
1002.
2.889
.2885
Co2286
ppb
1006.
4.499
.4474
Mg2790
PPb
1001.
2.48
.2478
2203-1
PPb
1004.
1.374
.1369
Sr4215
ppb
999.2
.7262
.0727
Pb2203
ppb
1001.
5.384
.5381
Ba4934
PPb
1002.
1.711
.1708
Cr2677
PPb
1003.
4.471
.4459
Hn2576
PPb
1003.
3.55
.3541
2203-2
PPb
999.0
8.544
.8553
Ti3349
PPb
1001.
1.892
.1891
Sel960
PPb
1006.
1.368
.136
Be3130
ppb
1003.
5.617
.5601
Cu3247
ppb
999.9
6.198
.6199
M02020
ppb
1007.
3.101
.308
Sb2068
ppb
1010.
3.96
.3922
T11908
ppb
1022.
9.04
.8842





                                                                                                 249
-------
t Analysis Report      Averages
Ned 10-08-97 07:03:45 AH
page
  Method: TRIANGL2   Sample  Name: ICV/CCV               Operator: 0KB
  Run Tine: 10/08/97  02:30           Filename: 100797
  node: CONC         Type: Q        Core.  Factor:        1,00000
  Lab ID.:           Cust. Snpl. ID.:  .         Cust. ID.:  43231
Eleins
Units
Avge
SDev
USD
Eleas
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
IRSD
Elens
Units
Avge
SDev
IRSD
Elens
Units
Avge
SDev
IRSO
El ems
Units
Avge
SDev
«SD
Ag3280
ppb
506.6
2.069
.4084
Ca3179
ppb
509.4
1.249
.2451
Fe2714
PPb
499.8
5.532
1.107
Na3302
PPa
4.978
.0322
.6475
1960-1
PPb
513.1
1.586
.3091
Ti3349
ppb
503.1
.819
.1628
A13082
ppb
486.5
14.52
2.985
Cd2265
ppb
506.5
1.425
.2814
K.7664
ppm
4.906
.0102
.2079
Ni2316
ppb
504.9
1.326
.2626
1960-2
ppb
513.0
2.484
.4843
T11908
ppb
509.9
9.537
1.87
AS1890
ppb
510.4
3.431
.6722
Ce4186
ppb-
501.5
2.827
.5637
Li6707
PPb
487.2
2.955
.6065
P.2149
ppb
510.7
2.84
.5561
Pb2203
PPb
505.3
.7743
.1532
V.2924
ppb
506.1
1.137
.2245
8,2496
ppb
500.3
.4603
.092
Co2286
ppb
506.8
1.968
.3884
Mg2790
ppb
504.8
1.273
.2521
2203-1
ppb
505.2
2.572
.509
Sel960
PPb
513.0
2.144
.4179
Zn2062
PPb
508.5
3.839
.7549
834934
ppb
503,2
1.02
.2027
Cr2677
ppb
504.7
2.504
.4961
«n2576
ppb
504.7
1.411
.2796
2203-2
ppb
505.4
2.418
.4785
Snl899
ppb
506.3
1.696
.3349
S12831
ppb
0285.1
1.762
.6179
8e3130
ppb
506.9
2.192
.4324
CU3247
ppb
505.9
3.263
.6449
H02020
PPb
505.8
1.662
.3286
Sb2068
PPb
525.7
3.273
.6226
Sr4215
ppb
502.4
.6403
.1274





                                                                                                   250
-------
Analysis Report      Averages
Ned 10-08-97 07:03:45 AN     page 9
Method:  TRIANGL2   Sample Nane: ICB/CCB               Operator: DKH
Run Tine:  10/08/97 02:36          Filenaie:  100797
Hode:  CONC        Type: Q         Corr.  Factor:        1.00000
Lab ID.:          Cust. Sipl. ID.:           Cust. ID.:  43231
Elens
Units
Avge
SOev
USD
Elens
Units
Avge
SOev
%RSD
Eleis
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
tRSD
Elens
Units
Avge
SDev
tRSD
Elens
Units
Avge
SDev
tRSD
Ag3280
ppb
.5272
.5009
95
Ca3179
ppb
1.373
.426
31.03
Fe2714
ppb
-2.411
9.886
410.1
Na3302
ppra
.0391
.1478
377.6
1960-1
ppb
1.869
1.721
92.09
H3349
ppb
.4260
.0588
13.79
A13082
ppb
-19.13
8.006
41.86
Cd2265
ppb
.4632
.1585
34.23
K.7664
PPn
.0333
.0201
60.48
1)12316
ppb
.8217
.5218
63.5
1960-2
PPb
-3.037
.3126
10.29
T11908
PPb
2.965
3.467
116.9
AS1890
ppb
1.761
.2552
14.49
Ce4186
ppb'
1.727
.8644
50.06
116707
ppb
.4562
.0671
14.72
P.2149
ppb
2.982
1.86
62.36
Pb2203
ppb
-1.007
.8433
83.75
V.2924
ppb
.4220
.1185
28.08
8.2496
ppb
.0299
.4995
1673
C02286
ppb
.6189
.1793
28.97
Mg2790
ppb
-1.801
2.625
145.7
2203-1
ppb
-3.283
2.134
65
Sel960
ppb
-1.403
.478
34.07
Zn2062
ppb
-.5546
.1114
20.09
8a4934
ppb
.3951
.1296
32.8
Cr2677
ppb
.4277
.3855
90.14
Mn2576
ppb
.3929
.0796
20.27
2203-2
ppb
.1296
2.242
1730
Snl899
ppb
.5508
.7697
139.8
S12881
ppb
.8372
1.813
216.6
8e3130
ppb
.1292
.1933
149.5
CU3247
ppb
.3246
.3636
112
1102020
ppb
.8313
.227
27.3
Sb2068
ppb
.8309
1.405
169.1
Sr4215
ppb
.4123
.1
24.25





                                                                                                  251
-------
. Analysis Report      Averages
Wed 10-08-97  07:03:45 AH    page 10
  Method:  TRIANGL2   Sample Name: ICSA8                 Operator: DKH
  Run  Tine: 10/08/97 02:41           Filenane: 100797
  Node:  CONC         Type: 0         Corr.  Factor:        1.00000
  Lab  ID.:           Cust. S»pl. ID.:            Cust. ID.:  43231
Eleos
Units
Avge
SDev
IRSD
Eleas
Units
Avge
SDev
IRSO
Eleos
Units
Avge
SDev
%RSD
Eleins
Units
Avge
SOev
%RSD
Eleos
Units
Avge
SDev
IRSD
Elens
Units
Avge
SDev
IRSD
Ag3280
ppb
541.8
1.609
.297
Ca3179
ppb
454100.
2209
.4865
Fe2714
ppb
177600.
514.5
.2897
Na3302
PPB
5.527
.1759
3.183
1960-1
ppb
551.8
7.606
1.378
Ti3349
ppb
500.6
1.02
.2038
A13082
ppb
509500.
4246
.8334
Cd2265
ppb
477.5
2.125
.4451
K.7664
PPffl
Q25.60
.1305
.51
Ni2316
ppb
460.9
1.687
.3659
1960-2
ppb
532.9
10.46
1.963
T11908
ppb
511.6
8.779
1.716
Asl890
ppb
531.8
3.326
.6254
Ce4186
ppb"
502.3
2.045
.4072
Li6707
ppb
633.7
4.073
.6426
P.2149
ppb
533.4
.7771
.1457
Pb2203
ppb
494.4
3.804
.7695
V.2924
ppb
499.3
2.159
.4324
B.2496
ppb
526.6
1.098
.2085
C02286
ppb
479.3
1.418
.2959
Mg2790
ppb
533100.
742.1
.1392
2203-1
PPb
517.8
3.61
.6971
Sel960
PPb
539.2
4.675
.867
Zn2062
ppb
455.7
4.122
.9045
834934
ppb
519,8.
1.855
.3569
Cr2677
ppb
484.2
2.484
.513
Hn2576
ppb
465.3
1.645
.3531
2203-2
ppb
482.7
7.505
1.555
Snl399
ppb
519.4
5.933
1.142
S12S81
ppb
Q561.2
.1655
.0295
Be3130
ppb
501.4
2.35
.4686
CU3247
ppb
541.8
4.08
.7532
H02020
ppb
503.6
3.171
.6297
SD2068
ppb
541.0
4.554
.8419
Sr4215
ppb
514.1
1.336
.2598





                                                                                                     252
-------
Analysis Report      Averages
                               Ned 10-08-97 07:03:45 AH    page 11
Method:  TRIANGL2   Sanple Kane:  183-3-3B XSO           Operator: OKH
Run Tiee:  10/08/97 03:13           filename: 100797
Hode: CONC        Type: S         Corr. Factor:        1.00000
Lab ID.:          Cost. Snpl. ID.:           Cust.  ID.:  43231
Elens
Units
Avge
SDev
*RSD
Ag3280
ppb
1.044
.1188
11.38
Asl890
ppb
L2.S03
1.52
60.73
Ba4934
ppb
5.520
.0374
.6779
Be3130
ppb
L-.4856
.1021
21.03
Cd2265
ppb
5.922
.0996
1.682
C02286
ppb
1.1913
.2462
128.8
Eleras
Units
Avge
SDev
IRSD
Cr2677 Mn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
3.314 275.1 LI. 425 L9.324 314.2 L-.7330
.3705 .8535 .2619 6.96 1.483 2.275
11.18 .3103 18.37 74.64 .4721 310.3
Elens
Units
Avge
SDev
*RSD
Sel960
ppb
L-.2995
.8252
275.5
T11908   Zn2062
ppb      ppb
L-4.121   1695.
4.451    9.086
108      .536
                                                                                                       253
-------
Analysts Report      Averages
Hed 10-08-97 07:03:45 AH   page 12
Method: TRIAN6L2   Sainple Name: 183-3-3B X50 DA       Operator:  DKH
Run Tine: 10/08/97 03:17          Filenaae: 100797
Node:  CONC        Type: S        Corr. Factor:        1.00000
Lab 10.:          Cust. Snpl.  ID.:            Cust.  ID.: 43231
Eleos
Units
Avge
SOev
*RSD
Ag3280 AS1890 8a4934 Be3130 Cd226S Co2286
ppb ppb ppb ppb ppb ppb
L.9757 LI. 265 5.506 L-.5472 6.065 L.1159
.1277 1.499 .0169 .0853 .1137 .472
13.09 118.5 .3076 15.59 1.874 407.4
Elems
Units
Avge
SDev
%RSD
Cr2677
ppb
3.396
.0287
.8445
Hn2576
ppb
275.2
.1284
.0466
N12316
Ppb"
LI. 512
.1862
12.32
P.2149
ppb
110.16
2.719
26.75
Pb2203
ppb
312.5
1.139
.3645
S52068
ppb
L.3145
.9085
288.9
El ens
Units
Avge
SDev
IRSD
Sel960
ppb
L.6587
1.008
153
T11908
ppb
L-.5729
2.393
417.6
Zn2062
ppb
1701.
6.754
.397
                                                                                                      254
-------
Analysis Report      Averages
led 10-08-97 07:03:45 AH    page 13
Method:  TRIANGL2   Sanple Naue:  183-3-SBC             Operator: DKH
Run Tiae:  10/08/97 03:22          Filename:  100797
Node:  CONC        Type: S        Corr. Factor:        1.00000
Lab ID.:          Cust. Snpl.  ID.:            Cust. ID.: 43231
Elens
Units
Avge
SDev
«SD
Ag3280 As 1890 8a4934 8e3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.4457 L-2.903 2.443 L-.6678 1.853 L-1.064
.551 1.387 .0193 .0861 .0232 .2394
123.6 47.79 .7908 12.9 1.253 22.49
Eleins
Units
Avge
SDev
IRSD
Cr2677 Mn2576 Hi2316 P.2149 Pb2203 Sb2068
ppb ppb ppb* ppb ppb ppb
4.299 9.713 L-.8869 45.67 21.07 L.4292
.2999 .0352 .291 2.697 .4124 1.948
6.977 .3625 32.81 5.906 1.957 453.9
El BUS
Units
Avge
SDev
%RSD
Sel960
PPb
12.21
1.489
12.19
T11908
ppb
1-9.163
2.242
24.46
Zn2062
ppb
119.9
.933
.778
                                                                                                       255
-------
.Analysie Report      Averages
Ned 10-08-97 07:03:45 AH    page  14
 Method:  TRIANGL2   Sanple Name:  183-3-6C              Operator: DKH
 Run Tine:  10/08/97 03:27           Filenane: 100797
 Node: COHC        Type: S         Corr. Factor:        1.00000
 Lab ID.:          Cust. Supl.  ID.:            Cust.  10.: 43231
Eless
Units
Avge
SDev
*RSD
Ag3280 Asl890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.7462 L-3.814 3.063 L-.7413 1.053 L-1.179
.6181 1.747 .0374 .0963 .0361 .4345
82.84 45.8 1.222 12.99 3.427 36.84
Elems
Units
Avge
SOev
tRSD
Cr2677 Mn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb* ppb ppb ppb
7.699 7.149 L.2620 86.70 16.76 LI. 291
.3404 .0241 .6199 3.035 1.009 2.165
4.421 .337 236.6 3.5 6.02 167.8
Elems
Units
Avge
SOev
IRSD
Sel960 T11908 2n2062
ppb ppb ppb
L.7528 L-10.08 119.2
1.169 2.541 1.505
155.3 25.21 1.263
                                                                                                 256
-------
Analysis Report      Averages
Ned 10-08-97 07:03:45 AH    page 15
Method:  TRIANGL2   Sanple Nane: 183-3-7C              Operator: DKH
Run Tine: 10/08/97 03:31          Filenane:  100797
Mode: CQNC        Type: S        Corr. Factor:        1.00000
Lab ID.:          Cust. Srapl. ID.:           Cust. ID.: 43231
Elens
Units
Avge
SOev
*RSD
Ag3280 Asl890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.9317 1-3.666 7.064 L-.8442 L.8941 L-.7697
.2618 .6801 .0692 .0566 .2032 .4057
28.1 18.55 .9797 6.709 22.72 52.72
Elens
Units
Avge
SDev
*RSD
Cr2677 Nn2576 Ni2316 PJ149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
9.822 8.633 LI. 456 107.6 21.37 L.2146
.783 .1202 .6213 6.923 .6768 2.654
7.972 1.393 42.68 6.432 3.168 1237
Elens
Units
Avge
SDev
mo
Sel960
ppb
14.20
1.198
8.437
T11908
ppb
L-7.985
1.925
24.11
Zn2062
ppb
154.9
1.426
.9203
                                                                                               257
-------
. Analysis  Report      Averages
tied 10-08-97  07:03:45 AH    page  16
  Method: TRIANGL2   Sample Name: 183-3-8C               Operator: DKH
  Run Tine:  10/08/97 03:36          Filename:  100797
  Hode: CONC         Type: S        Corr.  Factor:        1.00000
  Lab ID.:           Gust. Sinpl. ID.:           Cust. ID.: 43231
El ens
Units
Avge
SDev
*RSD
Ag3280 Asl890 Ba4934 8e3130 Cd226S Co2286
ppb ppb ppb ppb ppb ppb
L.5251 L-3.138 3.658 L-.8049 L.6621 L-1.302
.5607 1.168 .0731 .0684 .0519 .6143
106.8 37.21 1.997 8.494 7.839 47.17
Elens
Units
Avge
SDev
%RSD
Cr2677 Mn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
8.300 16.37 8.018 111.5 24.25 L-.6075
.5082 .1623 1.394 .1818 1.223 1.192
6.124 .9914 17.39 .163 5.044 196.3
El ems
Units
Avge
SDev
%RSD
Sel960
ppb
LI. 416
.7877
55.65
T11908
ppb
1-9.210
2.172
23.58
Zn2062
PPb
143.9
1.707
1.186
                                                                                                  258
-------
Analysis Report      Averages
Ned 10-08-97 07:03:45 AH    page  17
Method:  TRIANGL2   Sanpie Nane:  43231 MB              Operator:  DKH
Run Tine:  10/08/97 03:41           Filenane:  100797
Node:  CONC        Type: S         Corr. Factor:        1.00000
Lab ID.:          Oust. Sapl.  ID.:           Cust. ID.: 43231
Elens
Units
Avge
SDev
*RSD
Ag3280 AS1890 Ba4934 Be3130 Cd226S Co2286
ppb ppb ppb ppb ppb ppb
L-.0396 L-1.678 L-.0358 L-.8093 L-.244.3 L-.5261
.1657 2.249 .0228 .0378 .0286 .1993
419 134 63.59 4.668 11.71 37.89
Elens
Units
Avge
SDev
*RSD
Cr2677
Ppb
L.0685
.1353
197.5
Hn2576
ppb
2.844
.0327
1.149
H12316
ppb-
L-1.131
.8425
74.48
P.2149
ppb
1-13.83
5.068
36.64
Pb2203
ppb
LI. 672
1.382
82.69
Sb2068
PPb
L-.8198
.1904
23.23
Eleos
Units
Avge
SOev
%RSD
Sel960
ppb
L.2343
1.519
648.4
TH908
PPb
L-5.424
3.046
56.16
Zn2062
ppb
9.791
.3881
3.964
                                                                                                259
-------
Analysis Report      Averages
Red 10-08-97 07:03:45 AH    page  18
Method:  TRIAN6L2   Saaple  Name: 43231 LCS             Operator:  DKH
Run Tine:  10/08/97 03:45          Filename:  100797
Node:  CONC        Type: S        Corr. Factor:        1.00000
Lab ID.:          Cust. Sipl. ID.:            Oust. ID.: 43231
Elens
Units
Avge
SDev
IRSO
Ag3280 As 1890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
43.16 44.64 46.44 45.27 45.89 46.96
.5728 2.289 .0724 .212 .1659 .7293
1.327 5.129 .1559 .4684 .3616 1.553
Elens
Units
Avge
SDev
IRSD
Cr2677 Hn2576 Hi2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
46.87 47.66 45.34 904.6 46.69 47.00
.5382 .2079 .9026 4.625 .419 2.523
1.148 .4362 1.991 .5112 .8974 5.368
Elens
Units
Avge
SDev
IRSO
Sel960
ppb
44.37
1.676
3.777
T11908
ppb
41.73
5.652
13.54
Zn2062
ppb
192.4
1.968
1.023
                                                                                                     260
-------
Analvsis fteoort.     Averaoes
                              Ued 10-22-97 03:23:25 PH    page SO
Method: TRIANG12   Sanole Nw>:  184-23-IA8 X50         Operator: OKH
Run TiiB: 10/08/97 03:SO           filename: 100797
Mnrtp-  COW        Type: s         Corr. Factor:        1.00000
l.ah Ff>.:          i:nsf. Snnl.  ID.:           Cust. fO.:  43231
FlRRS
llni ts
Avae
SOev
tRSO
Aa3?80
ppb
2.106
.2924
13.88
A* 1890
ppb
29.07
1.681
5.781
Ra4934
PPb
281.0
.5952
.2118
8e?l30
ppb
I -.4995
.0279
5.586
M2265
ppb
271:5
1.224
.4507
Cr2677
ppb
244.8
1.562
.638
El ens
Units
Avge
SDev
4RSD
Mn2576
ppb
15900.
48.69
.3063
N12316
ppb
56.60
.2706
.4782
Sb2068
PPb"
163.0
3.625
2.224
Pb2203
ppb
15620.
40.79
.2611
S61960
ppb
14.83
.8455
5.703
P.2149
PPb
356.3
9.271
2.602
llni ts
Avap
PPb
HVI.',RO.
505.5
.70Ss
                                                                                                    261
-------
•Analysis Report      Averages
             Ned 10-22-97 03:23:25 PH    page  51
 ItRt.M:  TRTANG1.2   Sannle Naie: 184-23-2AB X50         Operator: DKH
 Run Tine:  10/08/97 03:55           Filenane:  100797
 Mode:  COHC         Tvp«: S         Corr.  Factor:         1.00000
 Lab 10.:          Ciist. Snipl. ID.:            Cust.  10.:  43231
 iinirs
 HVOP
 Sfmv
 tHSf

 Hems
 Unit.?
 Avge
 SOev
 iRSO

 El eras
 Units
 Avae
 SOev
 SRSD
Ao3?RO
ppb
3. 97ft
2115
S.32
Hn257h
ppb
H37240.
9S.42
.2563
Zn2062
ppb
HI 79200.
958.6
.5349
As 1890
onh
51.li
.4.VS
.RSI 2
Hi 2316
ppb
91.50
.12R6
.1406





ppb      ppb
 560.7    2.29^
1.436    .0471
         Pb2203
         ppb
          38770.
         134.)
         .3458
Sb2068
ppb
 286.0
3.869
1.353
ppb
 737:2
1.865
.25?<»

Sel%0
ppb
 21.79
3.714
17.04
Cr2677
ppb
 477.8
1.329
.2782

P.2149
ppb
 584.0
6.085
1.042
                                                                                                      262
-------
• Analysis Report      Averages
Wed 10-08-97 07:03:45 AH    page 23
 Method:  TRIANGL2   Sample Name: ICV/CCV               Operator: DKH
 Run Tine:  10/08/97 04:14          Filename: 100797
 Mode:  CONC         Type: 0        Corr.  Factor:        1.00000
 Lab ID.:          Cust. Sipl.  ID.:           Cust. ID.: 43231
Elens
Units
Avge
SOev
IRSD
eiems
Units
Avge
SOev
*RSD
Elens
Units
Avge
SOev
*RSD
Eleas
Units
Avge
SOev
USD
El ems
Units
Avge
SDev
*RSD
Elems
Units
Avge
SDev
tRSD
Ag3280
ppb
517.9
4.507
.8703
Ca3179
ppb
513.9
1.302
.2534
Fe2714
ppb
514.6
6.603
1.283
N33302
PP»
5.187
.204
3.932
1960-1
PPb
523.3
6.133
1.172
Ti3349
PPb
501.5
.5115
.102
A13082
ppb
460.7
18.55 .
4.026
Cd2265
ppb
505.6
.883
.1746
KJ664
ppm
5.130
.0308
.5996
Ni2316
ppb
504.0
1.02
.2023
1960-2
PPb
517.6
.7649
.1478
T11908
PPb
514.0
14.4
2.801
AS1890
ppb
517.2
1.425
.2756
Ce4186
PPb'
501.8
.6708
.1337
Li6707
PPb
496.9
3.029
.6096
P.2149
ppb
518.3
3.507
.6766
Pb2203
PPb
509.2
1.529
.3003
V.2924
PPb
513.0
.6666
.1299
8.2496
ppb
506.6
1.399
.2762
C02286
ppb
516.4
1.013
.1961
«g2790
PPb
510.8
6.294
1.232
2203-1
PPb
515.5
5.643
1.095
Sel960
PPb
519.5
1.557
.2997
Zn2062
ppb
520.2
1.145
.2202
8a4934
PPb
505.5
1.147
.2269
Cr2677
PPb
509.7
1.124
.2204
Mn2576
PPb
507.2
1.056
.2081
2203-2
PPb
506.0
4.409
.8714
Snl899
PPb
509.7
1.421
.2789
512881
PPb
Q4031.
40.92
1.015
Be3130
ppb
520.7
1.784
.3427
CU3247
ppb
506.5
4.846
.9567
M02020
PPb
510.8
.8218
.1609
Sb2068
ppb
488.5
6.627
1.356
Sr4215
PPb
500.8
.6648
.1327





                                                                                                     263
-------
.Analysis Report      Averages
Wed 10-08-97 07:03:45 AN    page 24
 Method: TRIANGL2   Sample  Name: ICB/CC8               Operator: OKH
 Run  Time: 10/08/97 04:21           Filename: 100797
 Mode: CONC         Type: Q        Corr.  Factor:        1.00000.
 Lab  ID.:           Cust. Snpl. ID.:           Cust. ID.:  43231
Eleas
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
*RSD
El ems
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
IRSD
Elens
Units
Avge
SDev
IRSD
Ag3280
ppb
.3128
.3591
114.8
Ca3179
ppb
3.224
.5812
18.03
Fe2714
ppb
-1.564
4.462
285.3
Na3302
ppm
.0201
.0566
281
1960-1
ppb
1.335
4.77
357.3
Ti3349
ppb
.2912
.0837
28.74
A13082
ppb
Q-55.57
10.97
19.74
Cd2265
ppb
.3109
.0926
29.8
K.7664
ppro
.0383
.026
67.84
N12316
ppb
.7390
.4273
57.82
1960-2
ppb
-3.378
1.336
39.55
T11908
ppb
1.979
.7565
38.24
As 18<50
ppb
2.068
1.174
56.77
Ce4186
PPb"
-.4351
.9053
208.1
Li6707
ppb
.3578
.0314
8.78
P.2149
ppb
.8917
7.335
822.6
Pb2203
ppb
-.3417
1.369
400.8
V.2924
ppb
-.2019
.3413
169
8.2496
ppb
-2.761
1.116
40.43
Co2286
ppb
.5022
.031
6.182
Hg2790
ppb
-2.137
.3262
15.26
2203-1
ppb
-1.575
3.249
206.4
Sel960
ppb
-1.809
2.419
133.7
Zn2062
ppb
1.549
.3892
25.14
Ba4934
ppb
.2773.
.0693
24.98
Cr2677
PPb
-.0139
.2684
1932
Mn2576
ppb
.5610
.1751
31.21
2203-2
ppb
.2739
.4365
159.4
Snl899
PPb
.6920
.957
138.3
Si2881
ppb
9.747
3.493
35.83
Be3130
ppb
-.5910
.188
31.81
Cu3247
ppb
.8741
.4261
48.74
N02020
pob
.0916
.2306
251.6
Sb2068
PPb
2.822
1.423
50.44
Sr4215
ppb
.2953
.0741
25.1





                                                                                                       264
-------
.Analysis Report      Averages            Ned 10-08-97 07:03:45 AH    page 25
 Method:  TRIAN6L2   Saiple Name:  1B4-23-1A8 X200        Operator: DKH
 Run Tine:  10/08/97 04:26           Filenaae: 100797
 Node:  CONC         Type: S         Corr. Factor:        1.00000
 Lab ID.:           Cust. Supl.  ID.:           Oust. ID.:  43231
Elens
Units
Avge
SOev
*RSD
Ag3280 Asl890 8a4934 Be3130 Cd2265 C02286
ppb ppb ppb ppb ppb ppb
L.7194 9.565 72.20 L-.7956 70.37 1.860
.3148 1.313 .4395 .084 .3039" .2726
43.75 13.73 .6087 10.56 .4319 14.66
Eleus
Units
Avge
SOev
*RSD
Cr2677 Nn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb- ppb ppb ppb
63.44 4246. 15.61 92.21 4059. 43.64
.2711 9.774 .2253 7.586 11.67 1.385
.4274 .2302 1.443 8.227 .2875 3.174
 Elens     Sel960   T11908   Zn2062
 Units     ppb      ppb      ppb
 Avge      L2.392   LI.165    19590.
 SDev      2.038    1.445    133.7
 *RSD      85.17    124      .6826
                                                                                                      265
-------
Analysis Report      Averages             Ned 10-08-97 07:03:45 AN   page 26
Method: TRIANGL2   Sample Naae: 184-23-2A8 X200       Operator:  DKH
Run Tine:  10/08/97 04:31          Filename:  100797
Hode: CONC        Type: S        Corr. Factor:        1.00000
Lab ID.:          Oust. Sopl.  ID.:            Cust.  ID.: 43231
Elens
Units
Avge
SDev
tRSD
Ag3280 Asl890 8a4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.9297 15.16 143.3 L-.1602 191,9 2.426
.1652 .9641 .5275 .0517 .7189 .2134
17.77 6.36 .3681 32.31 .3747 8.795
Eleins
Units
Avge
SDev
*RSD
Cr2677 Mn2576 Hi2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
123.1 10530. 24.49 150.6 10050. 73.48
.3161 25.72 .4927 .7415 25.17 1.203
.2568 .2441 2.012 .4922 .2503 1.637
El ens
Units
Avge
SDev
mo
Sel960 T11908 Zn2062
ppb ppb ppb
4.951 7.234 56240.
1.055 2.025 399.3
21.32 28 .7099
                                                                                                      266
-------
Analysis Report      Averages             Wed  10-08-97 07:03:45 AH    page 27
Method: TRIANGL2   Saople Naie: 184-23-2AB X200 L      Operator: DKH
 tun Tine: 10/08/97 04:36           Filename:  100797
.lode: COHC         Type: S         Corr.  Factor:        1.00000
Lab 10.:           Cust. Sopl. ID.:           Cust.  ID.: 43231
Eleis
Units
ivge
JDev
*RSD
Ag3280 Asl890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.1229 6.008 29.30 L-.8341 39.4? L.4516
.2684 .4912 .0327 .0684 .1391 .3627
218.3 8.176 .1116 8.202 .3522 80.31
ileis
Units
^vge
!Dev
*RSD
Cr2677
ppb
24.93
.4886
1.96
Mn2576
ppb
2214.
7.977
.3603
Ni2316
ppb-
5.732
.7371
12.86
P.2149
ppb
33.61
1.725
5.133
Pb2203
ppb
2069.
6.866
.3319
Sb2068
ppb
15.78
.6887
4.364
 ilens     Sel960   111908   Zn2062
Units     ppb      ppb     ppb
Avge      1.4343   LI.873    12160.
 iOev      1.085    .7286   79.66
 JRSD      249.5    38.9    .6551
                                                                                                        267
-------
•Analysis Report      Averages            Ned 10-08-97 07:03:45 AM    page 28
 Method: TRIANGL2   Sample Name: 184-23-3AB X200        Operator: DKH
 Run  Tine: 10/08/97 04:40          Filenane: 100797
 Node: COHC         Type: S         Corr. Factor:        1.00000
 Lab  ID.:           Cust. Sipl. ID.:           Cust.  ID.:  43231
Elens
Units
Avge
SDev
IRSD
Ag3280 Asl890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.6353 15.68 124.8 L-.5840 150.5 2.487
.2422 1.31 .4022 .0355 .8995 .4445
38.12 8.355 .3223 6.079 .5975. 17.87
Elems
Units
Avge
SDev
*RSD
Cr2677
ppb
101.7
.9317
.9157
Hn2576
ppb
8286.
40.56
.4895
Ni2316
ppb'
24.91
.4901
1.967
P.2149
ppb
3054.
10.03
.3284
Pb2203
ppb
7390.
47.67
.6451
Sb2068
ppb
64.67
1.253
1.937
Elens
Units
Avge
SDev
*RSD
Sel960
PPb
4.709
1.534
32.57
T11908
PPb
5.921
1.674
28.27
Zn2062
ppb
38710.
381.9
.9866
                                                                                                       268
-------
, Analysis Report       Averages
Ned 10-08-97 07:03:45 AH    page 29
 Method: TRIANGL2   Sanple  Nane:  184-23-3A8 X200 PA     Operator: DXH
 Run Tine:  10/08/97 04:47            Filenaue: 100797
 Mode: CONC         Type: S         Corr. Factor:        1.00000
 Lab ID.:           Cust. Sipl.  ID.:           Cust. ID.: 43231
Elens
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
IRSD
Elens
Units
Avge
SDev
*RSD
Ag3280
ppb
L.8864
.1601
18.06
Cr2677
ppb
104.1
.6927
.6653
Sel960
ppb
6.213
.2846
4.581
AS1890
Ppb
17.30
1.648
9.526
Hn2576
ppb
8430.
47.33
.5615
T11908
ppb
L3.271
2.775
84.85
8a4934
ppb
127.0
.3263
.2569
N12316
ppb'
25.63
.4261
1.662
Zn2062
PPb
39480.
440.8
1.117
8e3130
ppb
L-.5885
.0714
12.14
PJ149
ppb
3137.
4.917
.1567





Cd2265
ppb
153,5
.7414
.483
Pb2203
ppb
7544.
51
.676





Co2286
ppb
3.318
.4442
13.38
SD2068
ppb
68.21
1.216
1.783





-------
> Analysis  Report      Averages
Ned 10-08-97 07:03:45 AN    page 30
 Method: TRIANGL2   Sample Nane: 184-23-4AB            Operator:  DKH
 Run Tine:  10/08/97 05:01          Filenaae:  100797
 Node:  CONC         Type: S        Corr. Factor:        1.00000
 Lab ID.:           Cust. Sopl. ID.:            Cust.  ID.: 43231
Eleas
Units
Avge
SDev
IRSD
Ag3280
ppb
66.89
.7716
1.154
AS1890
ppb
32.62
2.77
8.49
Ba4934
ppb
498.7
.9166
.1838
8e3130
ppb
L-51.18
.1834
.3584
Cd2265
ppb
1692,
8.242
.4871
C02286
ppb
35.48
1.033
2.911
Eleos
Units
Avge
SDev
USD
Cr2677
ppb
319.3
1.052
.3295
Nn2576
ppb
336.8
.8933
.2652
Ni2316
ppb'
180.9
.5335
.2948
P.2149
ppb
1252.
6.946
.5549
Pb2203
ppb
5839.
46.04
.7885
Sb2068
ppb
47.57
2.725
5.728
Eleus
Units
Avge
SDev
*RSD
Sel960
ppb
40.79
2.281
5.593
T11908
ppb
L-6.404
3.978
62.11
Zn2062
ppb
1619.
12.64
.7807
                                                                                                          270
-------
•Analysis Report      Averages
                               Med 10-08-97 07:03:45 AH    page 31
 Method:  TRIANGL2   Sample Nane:  184-23-6AB            Operator: DXK
 Run Tine:  10/08/97 05:14           Filename: 100797
 Mode:  CONC        Type: S         Core. Factor:         1.00000
 Lab ID.:          Cust. Snpl.  ID.:           Cust.  ID.:  43231
Eleois
Units
Avge
SOev
*RSD
Ag3280
PPb
3.703
.417
11.26
As 1890
ppb
9.119
.6883
7.548
834934
PPb
640.5
2.817
.4398
Be 3 130
ppb
1-1.231
.1135
9.22
Cd2265
PPb
349,6
3.283
.9392
C02286
ppb
1-24.98
1.177
4.713
Eleois
Units
Avge
SDev
%RSD
Cr2677
ppb
99.38
1.763
1.774
Mn2576
ppb
394.0
2.922
.7416
Ni2316
ppb"
64.69
1.515
2.343
PJ149
PPb
905.6
13.26
1.465
Pb2203
PPb
1789.
21.76
1.216
Sb2068
PPb
54.73
7.679
14.03
 Elenis
 Units
 Avge
 SDev
 IRSD
Sel960
PPb
 48.29
1.461
3.026
T11908   2n2062
PPb      ppb
1-37.40   1532.
4.864    27.83
13       1.816
                                                                                                          271
-------
•Analysis  Report      Averages
Med 10-08-97 07:03:45 AN    page 32
 Method: TRIANGL2   Sample Name: 184-23-7A8             Operator: DKH
 Run  Tine:  10/08/97 05:22           Filename: 100797
 Node: CONC         Type: S         Corr. Factor:        1.00000
 Lab  10.:           Cust. Sipl. ID.:           Oust. ID.:  43231
Eleus
Units
Avge
SDev
tRSD
Ag3280 Asl890 Ba4934 8e3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
3.501 8.426 635.8 1-1.212 9.254 L-25.88
.4752 1.632 3.038 .0923 .506 1.322
13.57 19.37 .4779 7.616 5.468 5.111
Eleos
Units
Avge
SDev
IRSO
Cr2677 Nn2576 Ni2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
93.83 550.6 58.20 810.3 404.0 55.62
2.26 4.139 2.158 10.63 2.931 4.187
2.409 .7518 3.708 1.312 .7254 7.528
El eras
Units
Avge
SOev
tRSD
Sel960 111908 Zn2062
ppb ppb ppb
48.53 L-36.83 2495.
2.15 6.274 43.83
4.43 17.04 1.757
                                                                                                         272
-------
Analysis Report     Averages
                               Ned 10-08-97 07:03:45 AN    page 33
Method:  TR1ANGL2   Sample Name: 184-23-8A8             Operator: DKH
Run Tine:  10/08/97 05:32           Filename: 100797
Node:  CONC        Type: S         Corr. Factor:        1.00000
lab ID.:          Cust. Sspl. ID.:           Cust. ID.:  43231
Eleos
Units
Avge
SDev
IRSD
Ag3280
ppb
8.771
.7565
8.625
Asl890
ppb
10.13
4.634
45.73
Ba4934
ppb
672.5
3.113
.4629
Be3130
ppb
L-1.286
.0941
7.317
Cd2265
ppb
102.2
1.213
1.186
Co2286
ppb
L-27.12
1.247
4.598
Eleras
Units
Avge
SDev
*RSD
Cr2677
ppb
107.5
2.244
2.088
Mn2576
ppb
920.2
5.867
.6375
N12316
PPb"
64.98
2.023
3.114
PJ149
ppb
708.1
11.84
1.672
Pb2203
ppb
943.6
7.653
.811
Sb2068
ppb
60.84
5.1
8.383
Eleras
Units
Avge
SDev
USD
Sel960
ppb
 52.38
4.894
9.342
T11908   Zn2062
ppb      ppb
L-37.50   5842.
4.205    86.33
11.21    1.478
                                                                                                      273
-------
Analysis'Report      Averages
Ned 10-08-97 07:03:45 All    page 34
Hethod:  TRIANGL2   Sample Name:  ICV/CCV               Operator: OKH
Run Tine:  10/08/97 05:40           Filename: 100797
Node:  CONC        Type: Q         Corr. Factor:        1.00000
Lab ID.:          Oust. Sopi.  ID.:            Cust.  ID.: 43231
Elems
Units
Avge
SDev
IRSO
Elens
Units
Avge
SDev
%RSD
Eleras
Units
Avge
SDev
%RSD
El eras
Units
Avge
SDev
%RSD
Eleos
Units
Avge
SDev
IRSD
Eleos
Units
Avge
SDev
IRSD
Ag3280
ppb
512.8
2.075
.4045
Ca3179
ppb
508.1
4.888
.9622
Fe2714
ppb
505.5
13.94
2.758
Na3302
ppra
5.139
.0783
1.524
1960-1
PPb
522.6
4.038
.7726
T13349
ppb
495.1
1.193
.2411
A13082
ppb
Q434.7
17.43
4.01
Cd2265
ppb
497.1
3.6
.7242
K.7664
ppffl
5.094
.0235
.4614
N12316
ppb
498.7
2.831
.5677
1960-2
ppb
508.1
3.688
.7257
TH908
ppb
506.0
13.35
2.639
As 1890
ppb
512.8
2.122
.4139
Ce4186
ppb'
496.9
2.988
.6012
LJ6707
ppb
495.0
2.076
.4194
P.2149
ppb
513.5
5.308
1.034
Pb2203
ppb
495.4
3.945
.7963
V.2924
ppb
512.4
2.89
.564
8.2496
ppb
3610.
425
11.77
Co2286
ppb
514.0
3.626
.7054
Mg2790
ppb
505.7
5.241
1.036
2203-1
ppb.
512.1
5.822
1.137
Sel960
ppb
513.0
2.916
.5684
Zn2062
ppb
511.0
7.061
1.382
8a4934
ppb
504,0
2.289
.4542
Cr2677
ppb
507.4
4.47
.881
Mn2576
ppb
505.0
2.909
.576
2203-2
ppb
487.1
7.439
1.527
Snl899
ppb
503.3
4.294
.8532
S12881
ppb
059310.
3810
6.423
8e3130
ppb
525.4
3.864
.7354
Cu3247
ppb
504.9
4.972
.9848
No2020
ppb
506.5
3.03
.5982
Sb2068
ppb
485.8
6.261
1.289
Sr4215
ppb
500.4
1.525
.3048





                                                                                                    274
-------
.Analysis Report      Averages
Ned 10-08-97 07:03:45 AN    page 37
 Method:  TRIANGL2   Sample Name:  ICB/CC8                Operator:  DKH
 Run Time: 10/08/97 06:06          Filenane: 100797
 Node:  CONC         Type: Q        Corr. Factor:        1.00000
 Lab ID.:           Cust. Snpl. ID.:            Cust. ID.:  43231
Elens
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
USD
Elens
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
Elens
Units
Avge
SDev
USD
Elens
Units
Avge
SDev
USD
Ag3280
ppb
.2309
.5822
252.1
Ca3179
ppb
.3246
1.112
342.5
Fe2714
ppb
-.8432
9.396
1114
Na3302
ppin
.0906
.0971
107.2
1960-1
ppb
5.736
2.575
44.89
Ti3349
ppb
-.1543
.1032
66.87
A13082
ppb
Q-53.89
8.679
16.11
Cd2265
ppb
.7877
.0724
9.186
KJ664
ppn
.0036
.0403
1114
N12316
ppb
-.1408
.1854
131.7
1960-2
ppb
-1.977
.6189
31.3
T11908
ppb
-.8034
.9901
123.2
AS1890
ppb
2.654
2.048
77.17
Ce4186
PPb"
.6887
1.897
275.5
Li6707
ppb
-.1073
.0846
78.76
P.2149
ppb
3.792
7.114
187.6
Pb2203
ppb
-.0061
2.035
33330
V.2924
ppb
-.9228
.6983
75.67
B.2496
ppb
2256.
158.8
7.037
C02286
ppb
-.2525
.6182
244.8
Hg2790
ppb
-3.960
3.642
91.99
2203-1
ppb
-.8636
3.54
409.9
Sel960
PPb
.5911
.6391
108.1
2n2062
PPb
-.3258
.1348
41.38
8a4934
ppb
-.0779
.0367
47.14
Cr2677
ppb
.0688
.5652
821.5
Mn2576
ppb
-.0765
.0157
20.56
2203-2
ppb
.4220
1.571
372.2
Snl899
ppb
-1.153
.2231
19.34
S12881
ppb
06815.
1692
24.82
8e3130
ppb
-.9839
.0908
9.226
Cu3247
ppb
.0251
.1111
443.5
1402020
ppb
-.7988
.1386
17.35
Sb2063
ppb
-1.775
2.381
134.2
Sr4215
ppb
-.0681
.0303
44.45





                                                                                                     2-75
-------
'Analysis Report      Averages
Hed 10-08-97 07:03:45 AH    page 38
 Method: TRIANGL2   Sample Naae:  184-23-9A8             Operator: DKH
 Run  Time: 10/08/97 06:11           Filename: 100797
 Mode: COHC         Type: S         Corr. Factor:        1.00000
 Lab  ID.:           Cust. Snpl. ID.:           Cust. ID.:  43231
Elegs
Units
Avge
SDev
USD
Ag3280
ppb
1.896
.4018
21.19
Asl890
ppb
15.11
3.117
20.63
Ba4934
ppb
622.4
2.207
.3546
863130
ppb
L-1.061
.0619
5.83
Cd2265
ppb
L-6.618
.3033
4.542
C02286
ppb
L-23.92
.6385
2.669
Eleas
Units
Avge
SDev
%RSD
Cr2677 Nn2576 Hi2316 P.2149 Pb2203 Sb2068
ppb ppb ppb' ppb ppb ppb
92.61 26.98 59.94 786.7 L-.9452 60.11
1.197 .2808 .6297 7.513 .5112 5.605
1.293 1.041 1.05 .955 54.08 9.325
Eless
Units
Avge
SDev
*RSD
Sel960
ppb
51.48
1.433
2.785
T11908
ppb
L-41.02
2.863
6.979
Zn2062
ppb
51.73
1.489
2.878
                                                                                                       276
-------
Analysis'Report      Averages
Hed 10-08-97 07:03:45  AH     page 39
Method: TRIANGL2   Sample Naae:  184-23-10AB.5          Operator: DKH
Run Tine: 10/08/97 06:20           Filenaae:  100797
Mods: COHC         Type: S         Corr.  Factor:        1.00000
Lab ID.:           Cust. Snpl. ID.:            Cust.  ID.: 43231
Elees
Units
Avge
SOev
*RSD
Ag3280 As 1890 Ba4934 8e3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
3.105 33.47 1035. L-55.53 L-6.7Q6 27.75
.707 5.345 5.434 .4368 .161 1.328
22.77 15.97 .5249 .7866 2.401 4.786
Eleos
Units
Avge
SDev
IRSD
Cr2677
PPb
402.9
5.14
1.276
Hn2576
ppb
239.7
1.855
.7739
N12316
ppb"
158.1
1.882
1.19
PJ149
ppb
788.1
13.88
1.761
Pb2203
ppb
57.98
2.485
4.287
Sb2068
ppb
69.89
6.015
8.607
El ems
Units
Avge
SDev
%RSD
Sel960 T11908 Zn2062
ppb ppb ppb
60.90 1-15.12 564.6
1.602 9.699 11.02
2.631 64.13 1.952
                                                                                                           2-71
-------
•Analysis Report      Averages
Wed 10-08-97 07:03:45 AH   page 40
 Method:  TRIANGL2   Sample Nane:  183-1S-1C             Operator:  DKH
 Run Tine:  10/08/97 06:25          Filename: 100797
 Node:  CONC        Type: S        Corr. Factor:        1.00000
 Lab ID.:          Cust. Sapl.  ID.:            Cust. ID.: 43231
Elens
Units
Avge
SDev
IRSD
Ag3280 AS1890 8a4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L.5711 7.872 3.212 L-1.241 L-.8955 L-3.361
.3791 3.012 .0806 .0341 .1938 .2172
66.38 38.26 2.509 2.746 21.64 6.464
Eleas
Units
Avge
SDev
IRSD
Cr2677
ppb
13.98
1.376
9.837
Hn2576
ppb
3.676
.031
.8445
Ni2316
PPb'
8.472
.8*048
9.499
P.2149
ppb
L2.904
4.614
158.9
Pb2203
PPb
L.4317
1.306
302.6
Sb2068
ppb
4.816
2.022
41.99
[less
Units
Avge
SDev
%RSD
Sel960 T11908 Zn2062
ppb ppb ppb
8.973 1-10.79 12.31
1.557 2.52 .3826
17.35 23.36 3.107
                                                                                                        273
-------
••Analysis Report      Averages
                                Ned  10-08-97 07:03:45 AH    page 41
 Method: TRIANGL2   Sample  Nane:  ICV/CCV                Operator: DKH
 Run Tine: 10/08/97 06:29           Filename:  100797
 Node:  CONC         Type: 0         Corr. Factor:        1.00000
 Lab ID.:           Cust. Snpl.  ID.:           Oust.  ID.: 43231
 El ems
 Units
 Avge
 SOev
 USD

 Eleos
 Units
 Avge
 SDev
 USD

 El ems
 Units
 Avge
 SDev
 USD

 Eleras
 Units
 Avge
 SDev
 USD

 Elenis
 Units
 Avge
 SDev
 USD

 Elems
 Units
 Avge
 SDev
 USD
Ag3280   A13082
ppb      ppb
0341*9
         AS1890
         ppb
         8348.8
         C42265
         ppb
         0332.3
         287.8
         86.59
Ca3179
ppb
0390.3
321.7
82.42
         Ce4186
         ppb-
          324.6
         280.8
         86.5
                           C02286
                           ppb
                           0335.6
                           290
                           86.4
                  Li6707
                  ppb
                  0327.7
                  282.1
                  86.08
K.7664
ppm
03.664
2.417
65.97
         Ni2316
         ppb
         0333.5
         285.7
         85.67
Fe2714
ppb
0256.3
247.9
96.69

Na3302
ppm
03.351
3.109
92.78

1960-1
ppb
 320.5
271.6
84.74
                  Pb2203
                  PPb
                  0316.8
                  277
                  87.41
                  2203-1
                  PPb
                   301.5
                  276
                  91.56

                  Sel960
                  ppb
                  0331.0
                  286.9
                  86.66

H3349   T11908   V.2924
ppb  . '   ppb      ppb
0328.6   0342.4   0340 .J^
284.^4 - Mfcr— 78O
86.56    85.24    84.79
         8e3130
         PPb
         0345.4
         301.9
         87.41

         CU3247
 
-------
"Analysis Report      Averages
Red 10-08-97 07:03:45 AH    page 42
 Method:  TRIAN6L2   Sample  Name: 183-15-lB/W-z^ju.  Operator: OKH
 Run Time:  10/08/97 06:34           Filename: 100797
 Mode: CONC        Type: S        Corr.  Factor:        1.00000
 Lab ID.:           Oust. Sspl. ID.:           Cust. ID.:  43231
El ens
Units
Avge
SDev
IRSD
Ag3280 AS1890 Ba4934 8e3130 Cd226S Co2286
ppb ppb ppb ppb ppb ppb
1.186 1-4.801 4.324 L-.9855 L-1.092 L-4.620
.6274 4.186 .0528 .1946 1.363 3.53
52.91 87.2 1.221 19.74 124.8 76.41
Eleins
Units
Avge
SDev
%RSD
Cr2677
PPb
17.92
2.965
16.55
Nn2576
PPb
6.018
.2937
4.881
Ni2316
PPb'
5.207
3.437
66.01
P.2149
ppb
126.4
33.78
26.72
Pb2203
ppb
9.672
2.535
26.21
Sb2068
ppb
8.746
9.177
104.9
Eletos
Units
Avge
SDev
%RSD
Sel960
ppb
6.364
.3434
5.396
T11908
ppb
L-11.77
1.767
15.01
Zn2062
ppb
127.0
4.356
3.43
                                                                                                           230
-------
> Analysis Report      Averages
Ned 10-08-97 07:03:45 AN    page 43
 Method: TRIANGL2   Sample Name: ICV/CCV                Operator:  DKH
 Run Tiie: 10/08/97 06:39           Filename: 100797
 Node: CONC         Type: Q         Corr. Factor:         1.00000
 Lab ID.:           Cust. Srapl. ID.:            Cust.  ID.:  43231
Elens
Units
Avge
SOev
USD
Elens
Units
Avge
SOev
IRSD
Elens
Units
Avge
SOev
*RSD
Elens
Units
Avge
SDev
IRSD
Eleas
Units
Avge
SDev
%RSD
Elens
Units
Avge
SDev
*RSD
Ag3280
ppb
516.3
1.698
.329
Ca3179
ppb
509.7
.9727
.1908
Fe2714
ppb
507.8
4.159
.819
Na3302
ppn
5.205
.1597
3.068
1960-1
ppb
526.9
.8198
.1556
Ti3349
Ppb
497.7
.839
.1686
A13082
ppb
Q432.2
9.11
2.108
Cd2265
ppb
508.3
1.252
.2464
K.7664
ppra
5.204
.0272
.5225
Ni2316
ppb
507.5
1.15
.2267
1960-2
ppb
511.1
.6881
.1346
T11908
ppb
513.5
3.944
.7681
AS1890
ppb
518.4
1.35
.2605
Ce4186
Ppb'
504.2
1.592
.3157
U6707
PPb
497.5
4.19
.8423
P.2149
PPb
522.2
6.02
1.153
Pb2203
ppb
503.3
2.774
.5513
V_2924
PPb
515.0
1.022
.1985
B.2496
ppb
4301.
431.4 .
10.03
C02286
ppb
516.5
1.185
.2294
Hg2790
ppb
506.2
5.785
1.143
2203-1
ppb
508.0
5.345
1.052
Sel960
ppb
516.4
.2838
.055
Zn2062
ppb
514.6
3.424
.6655
8a4934
ppb
509.3
1.147
.2252
Cr2677
ppb
511.4
1.083
.2117
Nn2576
ppb
509.9
1.03
.202
2203-2
ppb
500.9
6.825
1.363
Snl899
ppb
506.0
.7443
.1471
Si2881
PPb
044760.
1116
2.493
Be3130
PPb
526.6
1.61
.3057
CU3247
ppb
502.9
2.779
.5526
M02020
ppb
508.2
2.182
.4294
Sb2068
ppb
494.3
5.041
1.02
Sr4215
ppb
502.4
.6572
.1308





-------
~> Analysis Report      Averages
Ned 10-08-97 07:03:45 AH    page 45
  Method: TRIANGL2   Sasple Nans: ICB/CC8               Operator: DXH
  Run Tine:  10/08/97 06:50          Filename:  100797
  Node:  CONC         Type: Q         Corr.  Factor:        1.00000
  Lab ID.:           Oust. Snpl. ID.:           Cust. ID.:  43231
Elems
Units
Avge
SOev
*RSD
Elents
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
$RSD
Elems
Units
Avge
SDev
%RSD
Elems
Units
Avge
SDev
IRSD
Elems
Units
Avge
SDev
WSD
Ag3280
ppb
.1747
.2575
147.4
Ca3179
ppb
1.500
.9785
65.23
Fe2714
PPb
-1.281
6.35
495.6
Na3302
ppm
.0537
.1344
250.4
1960-1
ppb
5.207
2.845
54.64
Ti3349
PPb
-.0724
.1862
257.3
A13082
ppb
Q-74.49
6.276
8.426
Cd2265
ppb
-.2270
.2033
89.54
K.7664
ppn
.0347
.0401
115.5
Ni2316
ppb
.9256
.476
51.42
1960-2
ppb
-3.632
.2124
5.847
T11908
ppb
-1.171
1.804
154
AS1890
ppb
3.113
2.751
88.39
Ce4186
ppb'
-.2441
1.225
501.8
Li6707
ppb
.0343
.0697
203.3
P.2149
PPb
.6120
5.274
861.8
Pb2203
ppb
-1.706
.8566
50.21
V.2924
ppb
-.6510
.6563
100.8
8.2496
ppb
2950.
355.5
12.05
C02286
ppb
-.3791
.6709
177
Ng2790
ppb
-4.398
4.759
108.2
2203-1
ppb
-2.038
3.557
174.5
Sel960
ppb
-.6889
1.058
153.6
Zn2062
ppb
-.8326
.4831
58.02
8a4934
ppb
-.0343
.0694
202.6
Cr2677
ppb
.7813
.8068
103.3
Hn2576
ppb
-.0473
.0454
95.89
2203-2
ppb
-1.540
.5084
33.01
Snl899
ppb
-1.529
2.38
155.6
512881
ppb
Q21830.
2473
11.33
8e3130
ppb
Q-1.163
.0684
5.885
CU3247
ppb
.1096
.0587
53.58
PI02020
ppb
-.4506
.2341
51.95
Sb2068
ppb
.8408
3.233
384.6
Sr4215
ppb
.0044
.033
742.7





                                                                                                          282
-------
* Analysis Report     Averages
led 10-08-97 07:03:45 AM    page 46
 Method: TRIAN6L2   Sample Name:  ICSA8                  Operator: OKH
 Run Tine: 10/08/97  06:56          Filename: 100797
 Node: CONC         Type: Q        Corr. Factor:        1.00000
 Lab ID.:           Cust. Smpl.  ID.:            Cust.  ID.: 43231
El ems
Units
Avge
SOev
IRSD
El eras
Units
Avge
SOev
*RSD
El ems
Units
Avge
SOev
iRSD
Elems
Units
Avge
SOev
iRSD
Elems
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
IRSD
Ag3280
ppb
547.0
2.838
.5189
Ca3179
ppb
449600.
5123
1.14
Fe2714
ppb
176900.
1634
.9233
Na3302
ppm
5.784
.1398
2.417
1960-1
ppb
577.0
7.764
1.346
TJ3349
ppb
494.5
3.804
.7693
A13082
ppb
512400.
3670
.7162
Cd2265
ppb
475.8
4.729
.9937
K.7664
PP«
026.31
.0473
.1799
Ni2316
ppb
461.1
5.119
1.11
1960-2
ppb
537.7
10.31
1.917
T11908
ppb
513.6
10.16
1.978
As 1890
ppb
534.7
6.726
1.258
Ce4186
ppb"
504.4
2.094
.4152
U6707
ppb
643.9
1.593
.2474
P.2149
ppb
542.1
22.66
4.181
Pb2203
ppb
489.5
9.074
1.854
V.2924
ppb
506.1
4.613
.9115
BJ496
ppb
3894.
413.9
10.63
C02286
ppb
485.6
4.986
1.027
Mg2790
ppb
535100.
3859
.7211
2203-1
ppb
517.7
5.393
1.042
Sel960
ppb
550.8
5.076
.9217
Zn2062
ppb
457.1
8.895
1.946
B34934
ppb
519,4
2.639
.508
Cr2677
ppb
485.3
6.809
1.403
Mn2576
PPb
466.0
4.417
.948
2203-2
ppb
475.4
14.69
3.09
Snl899
PPb
524. 2
6.615
1.262
Si2881
ppb
Q17280.
2659
15.39
Be3130
PPb
513.4
5.181
1.009
Cu3247
PPb
544.4
3.367
.6184
M02020
PPb
504.6
4.097
.812
Sb2068
PPb
542.9
8.218
1.514
Sr4215
ppb
513.3
2.351
.555





                                                                                                     233
-------
AiitoS*i&nler Rfinnrt    Table: HA466
Thi! 10-??-0? 01:?«:38 PI*
naa?
Table Naeie: HA466           Autosamoler Type:  TYPE  TJA
Sanmle Positions:  161/112    QC Positions:  13/1°      I Sets: 4
Rinse Station location  is  rack -I. DOS.  -I.
— Rack? —
Rack 9 Type

Usage
1 Aux. Ill Rack STO/GC /BLANK
2 Samole
3 Sanple
4 Samole
5 Samole
I16mra) Sanmles
(16nn) Sanples
(16nn) Samoles
116mm) Sanples


itPos Left Analyses/Pos
13 10
17 1
48 I
48 1
48 1





— Safflole Sat,* —
5et.lt Type
i normal
? Nnr«Ml
A iinrnal
•I Nnrna 1
— Prijoarario
SptJ l.lntake
Preoare? Oescriotion
Ho i.\478
Hn i.W
Ho ».J53o
. II" 4J?.\I
n info — -
UntakeH? Final Oil. Fa
Method KPos Rack* StartPos
TRIAH6L2 II
TRTfttWI." \
[RIAHiiL2 11
TPTAHGL2 (>

rtor
? 1
? !?
2 15
•? 96


No Saraole1: Preoareil
Rack HI
Pos Row Col
1 I
2 1 2
3 1 5
4 1 4
"5 1 5
* 1 A
17.. !9 Hot
Rart- If?
?ns finn i:ol
! 1
•? 1 9
.> I <
4 1 4
5 I 5
f, 1 6
7 I 7
8 ) 8
o I <)
10 1 10
11 1 11
12 1 12

SaiDole Nane Set t
STD3 -NA-
ST01-BLAHIf -HA-
ICSA8 -HA-
CHFCK 1.0 -HA-
iCV/CCV -NA-
ICR/^CB -HA-
Used i

Saniole rtane Set II
1.5478 rtB
d.^47fl LOR
1S5-5?-!
185-57-1 D
185-52-2
185-52-2 HS
185-52-2 HSO
185-52-2 PDS
185-52-2 L
185-52-3
185-52-4
CHECK 997? 2

DUsed Type
? Standard
1 Standard
3 QC Standard
1 QC Standard
5 QC Standard
5 or Standard


HUsed Type
-NA- Saeols
-HA- SauDle
-MA- Sanole
-HA- Saiole
-HA- SanoTe
-NA- Saaole
-NA- Sanole
-NA- Saiole
-NA- Saiole
-NA- Sanple
-NA- Saiple
-NA- Sasole


1-65-^

I-IP^'M
i-^a-tp
















                                                                                                  234
-------
f       <•'
• AutoSamler Reoort   Table: HA4fei>
 Rack 8°
 Pos  ROM  Col    Sanole Nane
   Thu 10-23-97 01:29-58 PH
              oane 2
Set 8  ((Used
Type
rj
14
15
16
17
18
19
20
21
22
23
24
25
26 •
27
28
?9
JO
';\
W.
Park
vn.
2
2
i
1
I
2
2
2
2
2
2
2
3
3
3
3
5
,\
5
4fi
I*
Kfl.
I
•)
3
4
5
6
7
8
9
10
11
12
1
2
5
4
5
A
7
Nnt

rol
187-68-1
187-68-1 f
4353b MB
43536 ICS
186-11-1
186-11-1 D
186-11-2
186-11-2 MS
186-11-2 MSO
186-11-2 POS .
186-11-2 L
186-11-3
186-11-4
184-23-1A8 XIO
184-23-2A8 XIO
I84-23-2AB XIO POS
184-23-2A8 XIO 1.
IS4-23-3AR VI 0
184-73-5AB XtO OA
iKRd!

SanDle Name
?
n
5
3
5
3
3
3
3
3
3
3
3
4
4
4
4
4
4


Set it
-NA-
-HA-
-Hft-
-HA-
-HA-
-NA- "
-HA-
-HA-
-HA-
-HA-
-HA-
-NA-
-HA-
-NA-
-MA-
-NA-
-HA-
-HA-
-flA-


ttUsed
Satsole
SantDle
Sanole
Sample
Saiole
Saaole
Sample
Sanole
Sample
SaiBDle
Sanole
Sanole
Samole
Samole
Sanole
Samole
Sanole
Saraole
Samole


Tyoe
  •I   .4ft   Nnt IKjP.rli

  Rark 84

  Pos  RON  Col   Sanols  Name

  * I...48   Not Used)

  Rack «5

  Pos  RON  Col   Samole  Name

  II...48   Mot Used)
Set it  KUsed
Tvoe
Set I  XUsed
Type
                                                                                                  285
-------
Standardization Rot.
Thu  10-25-97 05:12:19  AM     paae I
Hethod: TRlftH6L2     Standard: STDI-BIANI1'
f-lein
Avae
SDev
«SP
HI
»?
»S
Flpnt
Avge
SOev
SRSO
11
82
85
El em
Avae
SOev
%RSO
81
«?
85
FlPin
Avae
Sfipv
•5RSO
tt!
«•?
itj.
El era
Avgp
SOev
».RSO
111
82
113
Ag5280
-.0001
.0004
362.7
.0001
.0001
- 0005
Cd?W
-.0003
.0001
38.50
-.0004
-.0002
-.0003
U6707
.1412
.0010
.7015
.1483
.1503
.I486
770.S- 1
0008
.OOOR
lOh.2
001 <•
0009
-.0001
11334"
-.0000
.0005
787.1
-.0003
.0000
.0002
A 1 3082
.002?
.0000
.2999
0025
.0025
.0025
Ce4186
-.0002
.0001
37.20
-.0003
-.0002
-.0002
Mg2790
-.0000
.0001
504.7
- 0002
.0001
.0000
7203-2
-.0001
.000?
J^.S
- . oon?
0001
.0001
T 11908
-.0004
.0001
19.22
-.0005
-.0003
-.0004
As 1890
-.0003
0000
13.71
-.0003
-.0002
-.0003
C02286
- 0002
.0001
44'. 61
-.0003
-.0001
-.0001
Hn2576
.0000
.0000
86.62
0000
.0000
.0000
Sh?06fl
0003
.ooft«;
158 2
- Mm
i)00<)
.000?
VJ994
-J)004
.0000
8.260
-.0005
-.0004
-.0004
6 J496
.0001
.0001
64.94
.0000
.0001
.0002
Cr2677
-.0001
.0001
57.78
-.0002
-.0001
-.0001
Ho2020
.0000
.0001
177.0-
-.0000
0001
0000
I9AO-1
- 0043
.0005
10 55
-.'1047
-.0058
-.0044
Zn?0b2
-.0000
.0001
156.1
-.0001
.0000
-.0000
834934
.0000
.0000
53.64
0000
.0001
.0001
r:»3?47
.0024
.0000
.o536
.0024
.0024
.0024
Na3302
.0027
.0058
142.5
.0048
.0050
- 0017
I960-?
0015
.0006
io.78
. OOIM
00 1 8
.001 °
S12881
.0221
.0004
1.931
.0225
.0221
.0217
8e5130
.0002
.0000
1.422
.0002
.0002
.0002
Fe2714
.0000
.0000
368.2
-.0000
.0000
.0000
N12316
-.0016
.0001
3.309
-.0017
-.0016
-.0016
Snl89o
- 0003
.0001
?<».55
-.000?
-.0004
-.0004







Ca3179
.0006
.0000
4.980
.0005
.0006
.0006
K.7664
7.539
.046
.6274
7.30°
7.392
7.315
P.2149
-"0008
.0001
15.47
-.0007
-.000?
-.0009
Sr4215
.0001
.OOOC'
29.14
.000!
0001
.000!







                                                                                          286
-------
.  Standardization Rot.                     Thu 10-23-97 05:12:19 AH     paae ?
   IntStd  1         234567
   Node    *Counts   Ti»e      NOTUSEO   NOTUSED   NOTUSED   NOTUSED   NOTUSED
   Eles)    y
   Wavlen  371.030   --        --        --        --        --        -•
   Avge    236811    15000
   SOev    5390.643  .OOOOOOC1  -
   SRSD    ?.276352  .0000000  --

   »!      231267    15000
   82      237131    15000
   tt.s      2470^4    15000
                                                                                                     237
-------
       i-ation  Rot.



Mp.thnd- TRlANfil.?    Standard:  ST03
Thu  10-23-97 05:17:06 AM
oaae 1
El em
Avge
SDev
IRSD
11
12
15
Elei
ftwge
SOev
iFSO
II
4?
»,'
*•"'.*!«
AVOP
sfifitf
^HSf<
41
»?
»3
Flan
Avge
SDev
ttSD
81
82
»3
flem
Avgp
SOev
»fiSI'
1!
r
43
Ag5280
.4108
.0006
.1362
.4115
.4107
.4103
Cd2265
1.091
.005
.4772
MR*
1.0%
1 09"
1167(17
14. ?S
•>o
1 . .Ufl
14.11
u.y>
14.76
2203-1
.2078
.0005
.2306
.2082
.2080
.2075
T i 3349
!.?Q6
.005
.•7477
1 ?0.i
1 . 9C,R
1 ,'Oh
A 13082
.0177
.0001
.3146
.0177
.0176
.0176
C64186
.1183
.000?
.1608
.MR)
.1183
.1185
«n?7%
. fl W
000?
.7?fto
.0221
.0224
.0223
2203-2
.0183
.0007
.7432
.0975
.0988
.0985
H1908
.0334
0006
1.*5ft
.Wfi
.0.5 '.ft
i>53h
AS 1890
.0520
.0001
.2072
.0521
.0520
.0519
C02286
.1195
.0006
.5024
.1190
1202
.1194
Nn?S7o
.I4AO
0006
.114?
.1462
.1475
.1469
Sb2068
.1215
.0003
.2893
.1214
.1219
.1213
V_?924
.0415
.0001
..si SO
"Ul.i
.041A
.0415
8.2496
.1615
.0009
.5307
.1606
.1619
.1621
Cr2677
.1684
.0008
.4485
.1677
.169?
.1684
Ho2020
.081H
0007
?^q?
.0816
.0820
.0819
l%0-)
.2666
.0010
.3748
.2677
.2665
.2657
in2062
.125?
.0011
.R474
l?40
.1261
.1754
634934
.2846
.0001
.0363
.2848
.2846
.2846
CU3247
.1699
.0004
.2404
.170?
.1694
.W
Na3302
.7056
.004.',
2. "7^
2105
.2042
.2021
1^60-2
1598
.0008
.5188
.158"
.1601
.1604
Si288l
.477h
.0005
.1014
4782
.4774
.4773
8e3130
.2958
.0014
.4699
.2944
.2971
.2960
Fe2714
.0048
.0001
1.065
.0047
.0048
.004fl
Hv?3l6
.3874
.OOlo
.7671
3865
.3885
.3871
Snl899
.1264
.000°
.6798
.1256
.1274
.1263







Ca3l?9
.0277
.0001
.5285
.0276
.0279
.0277
K_7664
24.70
.2?
.8800
24.9?
24.48
24. AO
P. 2 149
.0234
0005
?.03I
.0221
.023"
.0233
Sr4215
.8633
.0008
.0912
.8636
.8640
.8625







                                                                                      288
-------
Standardization Rot.                     Thu 10-23-°7 05:17:06 AH     oaae
 FntSM  I         2         3         4        5         o         7
 Node     *Counts   Time      NOTUSED   MOTUSED   HOTUSEfi   NOTUSEfi    MOPISEO
 Eleffl     r
 Wavien  571.030   —
 Ovge     242234    iSOOfl
         ?401.778  .nooonoo   --
                  .0000000   --
 «1      244501    15000
 «2     239717    15000
 «3     242484    15000
                                                                                              239
-------
Analysis Reoori
QC Standard
Method:  TRIANGL2   Sasole Name: 3TD5
Run Tine:  10/23/07 05:17:11
Thu 10-23-97 05:21:54 AN     page I

            Ooerator: SR8
Hode: CONC   Corr. Factor:  1
Flera
Dm ts
Svgp.
srmv
tfisn
m
»2
»3
Errors
Value
Range
Elem
Units
Avge
SOev
*RSO
HI
»?
»3
Frrors
•i* I ne
Ranop
Heat
Uni t.c
M'JOP,
Sfmv
*RSn
11
12
13
Errors
Value
Range
Elen
Units
Avge
SOev
IRSO
II
«'•
»S
Frrnr*
Vain?.
Ag3280
DDh
095.1
•?.fl
2810
99fl.'>
092.7
994.5
QC Pass
1000.
5.000
Cd2265
ppb
993.6
3.8
.3851
990.9
qgj.o
998.0
QC. Pass
1000.
S.flflf-
M*>?07
nnh
997 b
Ih. \
1.0.58
986.4
tOlo.
989.Q
QC Pass
1000.
5.000
2203-1
ODD
994. A
8.. 5
.838H
Wl.l
Qflfl.n
1004
NnOHFO.

A13082
DDb
990.4
A. A
6330
907.7
<587.3
986.4
OC Pass
1000.
5.000
Ce4186
ppb
995.1
4.0
.4026
$90.7
0950
998.5
QC. Pas?
1000
s.nno
Mg2790
nnh
097 ?
4.\
.4301
995.0
093.7
1002.
QC Pass
1000.
5.000
2203-2
ppb
996.7
6.7
.6601
096.0
989.9
1003.
MOrHECK

AS 1 890
DDb
998.1
Q
.0942
997.3
997.9
999.2
QC Pass
100ft.
5.000
C02286
DDb
995.4
3.4
.3368
092.7
014.4
090. i
OH P3?<5
1000.
S.OflO
Mn257o
nnh
••W5 . S
2.7
.2704
991.0
993.2
996.3
QC Pass
1000.
5.000
Sb2068
ppb
991.8
5.1
.5156
086.8
00) .s
997 0
or Pass
1000
6.2496
pnb
1005.
5.
.3007
1004.
1002.
1008.
QC Pass
1000.
5.000
Cr2677
ppb
095.0
3.1
.3118
092.8
°93.7
098.0
flO Pas?
1000.
i.noo
Ho20?0
nnh
096.0
4.1
.4162
994.0
004.4
1001.
QC Pass
1000.
5.000
1960-1
ppb
996.6
8.0
.8020
088.1
997.0
1004
NOCHECK

834034
DDb
096.7
1.3
.1341
006.1
098.2
995.7
QC Pass
IQOfl.
5.000
CU3247
ppb
906.6
2.2
.2201
008.8
OOA.h
094.4
QC Pass
1000.
s.ooo
Ha3302
nn»
0 840
.035
.3571
9.881
0.318
9.821
QC Pass
10.00
5.000
1960-2
ppb
996.6
6.6
.6654
1001.
9fl
-------
.Analysis Report
            OC  Standard
                      Thu 10-23-97 05:21:54 AM     page ?
  Range
                    5.000
                                       5.000
                                       5.000
El era
Units
Avge
SDev
SRSD
Snl899
ppb
995.8
5.1
.3085
Sr4215
ppb
992.1
1.3
.1274
Ti3349
ppb
993.8
2.1
.2103
T11908
PPb
1016.
5.
.4806
V_2924
ppb
995.5
2.3
.2303
Zn2062
ppb
997.6
5.9
.5953
S12881
PPb
9951.
22.
.2193
993.0
995.3
999.1
  81
  82
  83
  Frrnrs  Of-
  value   1000
  Ranap   S.Ortft

  IntSM  I
  Hnde    *0onnt.«
  Elera    Y
  Wavlen  371.030
  Avae    241873
990.7
993.2
992.3

QC
1000.
5.000
          Trme
          15000
994.3
995.5

QC Pas?
1000.
5.000
1010.
1020.
1018.

QC Pass
1000.
5.000
993.0
996.3
997.4

QC Pass
1000.
5.000
994.3
994.0
1004

QC Pass
1000.
5.000
9974.
9930.
9947.

OC Pas?
10000.
                    1        5         o         7
                    NDTDSEP   HOTUSED   HOTDSEO   NOTUSEP
  SOPV    3779.456  .OOOOnOO   --
  iRSO    1.562579  .0000000   --
  81      239018
  82      246159
  83      240442
          15000
          15000
          15000
                                                                                                    291
-------
Analvsis  Recoct
                    QC Standard
Thu 10-25-97 05:51:26  AM     cage 1
Method: TRIANGL2   Sauole  Nane: ICV/CCV
Run Tine: 10/23/97 05:26:45
CoiDBP.nt.:
Mode: CflNC   Corr. Factor- I
                                                    Operator: SRB
Elein
Uni t«
4vqp,
Sfipw
tfisr.
tti
12
IS
F.rrors
Valup
Range
Elfin
Units
Avge
SOev
SRSO
Jl
»9
43
Frrnr*
'In I us
Hangp
Hsu
lim r«
avoB
Sfipw
wso
HI
»2
83
Errors
Value
Range
Eleni
Units
Avge
SOev
iRSn
Jl
IP
«.'.
frrnr*
'/ante
HQ3280
nnh
105.0
•?.o
.3948
498.1
405.5
494.'?
QC Pass
500.0
10.00
Cd2265
ppb
499.8
.0
.1887
408.7
500. \
500.4
Qf Pass
500.0
.0.. V.
1 I.h7fi7
nob
482 S
fl.fi
1.315
472.6
480.1
485.0
QC Pass
500.0
10.00
2203-1
opb
501.5
6.9
1.384
507.3
49.VR
503.3
NnruFr.K

A 15082
nnh
182.6
l.o
.2010
483.3
482.9
481.5
QC Pass
500.0
10.00
Ce4186
ppb
496.2
2.o
.5881
495.2
493.0
490.5
NOCHFfK


H07700
onh
407 1)
4.?
.3448
495.3
493.0
501.8
QC Pass
500.0
10.00
2203-2
ppb
498.4
6.6
1.331
501.6
4°0.7
5u? 7
NOCHFOr

Asl890
r>nb
502.7
1.3
.2618
5fl?.o
501.3
S03.9
QC Pass
500.0
10.00
Co2286
ppb
490.5
1.0
.2033
498.3
500.2
409.9
QC Pass
500.0
10 00
rtn257h
nob
408.4
1.0
.2056
497.2
499.1
408.8
QC Pass
500.0
10.00
Sb2068
ppb
495.3
.7
.1330
495.4
495.8
404. 1
QC Pass
500.0
8.2496
opb
500.3
2.7
.5324
497.3
502.1
501.6
NOCHECK


Cr2677
ppb
499.8
.g
.1836
498.3
500,6
500 0
Qf Pas?
500.0
10.00
M02020
Dr-h
407 6
.7
.1502
496.8
498.3
497. A
QC Pass
500.0
10.00
1960-1
ppb
504.8
4.2
.8374
507.2
400.0
507.3
MOCHFCK

8a4934
ODh
496.0
1.6
.3247
495.3
498.5
496.8
QC Pass
500.0
10.00
Cu3247
ppb
492.6
1.1
.2196
402.4
403.7
491.6
QC Pass
500.')
10.00
Ha3302
DflB
4 700
.20?
4.215
5.020
4.642
4.708
OC Pass
5.000
10.00
1060-2
ppb
497.2
8.1
1.621
503.9
488.3
400.4
NOCHFCK

Be3150
ODD
499.0
_7
.1396
498.3
499.6
499.2
OC Pass
500.0
10.00
Fe2714
ppb
505.2
6.2
1.218
408.1
508.3
508.8
QC Pass
500.0
jo. oo
Ni23l6
noh
501 0
1.8
.3620
500.3
409.7
503.1
OC Pass
500.0
10.00
Pb2203
ppb
400.4
6.6
1.327
503.5
401.7
502.0
OC Pass
500.0
C33179
DDb
490.9
1.0
.1994
498.1
499.8
499.8
QC Pass
500.0
10.00
X.7664
ppn
4.748
.097
2.052
4 636
4.R03
4.306
Qf Pas?
5.000
10.00
P_2140
DBh
400.8
2.8
.5549
407.0
503.0
498.6
QC Pass
500.0
10.00
Sel960
ppb
400.7
6.7
1.348
505.0
492.2
502.0
OC Pas?
500.0
                                                                                                 292
-------
Analvsis Reoort
OC Standard
Thu 10-23-97  05:31:26 AH     oaoe ?
 Range
        10.00
                 10.00
10.00
El en
Units
Avge
SOev
%RSP
HI
82
«3
Firrnr*
Value
fianoP
inr.St.1
Mode
ties
Wav I en
Avge
SOev
SRSO
HI
«2
83
Snl899
ppb
495.4
1.0
.2080
494.2
496. |
495.9
00 Pas«
500.0
10.00
1
*i*ount.s
Y
371.031'
241394
3588.702
1.486655
237275
243844
243064
Sr4215
ppb
494.0
1.4
.2900
492.8
495.6
493.7
Of Pass
500.0
10.00
•>
Tine
--
--
15000
.0000000
.0000000
15000
15000
isoor-
TJ3349
ppb
495.2
l.l
.214
-------
         Recoct.
                    Of; Standard
                       Thu  10-23-97  05:36:15 AH
                                         oaae  1
Hpthnd: TRIANGI.2   Sannle Nairn:  ICR/CCR
Run Time: 10/23/97 05:31:31
Consent:
Mode: CONC   Corr. Factor: 1
                                                     Operator: SRB
Elen
Unifcr-
Avge
SOev
%RSD
Ag3280
DDD
.9030
.7566
83.78
_8lvW
ppb
2.453
6.365
259.4
As. 1890
ppb
-.0439
1.8488
4212.
f) ?i9h
PDb
8.734
1.929
22.08
RadQ.sJ
ppb
.0301
.0378
125.8
_Je3J.3p_
DDb
-.0055
.0543
987.0
                                                                    Ca3179
 81
 02
 85
        .7556
       01.722
        .2310
 Frrors  OC Pass
 Vain*   .0000
 Sange   I. 000
9.798
-.9939
-1.444

Of; Pass
.0000
50.00
1.061
-2.178
.9858
 Mr.i ts   onh
 81
 8?
 85
trrnrs
ftanqp.
 Flsin    ?9ft.\
 Hni r.s   opb
         L16707
         ppb
         .2576
         .1170
         45.41
         QC Pass
         .onoo
         1 . 000
HI
8?
85

Frrors  OC Pass   OC
Value   .0000     .0000
Range   1.000     3.000

Elen
Uni ts
Avge
SOew
 SOev
 tRSD

 tl
 82
 83
 Errors  NOCHECX   NOCHECK   OC  Pass    NOCHECK   NOCHECK   OC Pass   OC Pass
 Value                       .0000                         .0000     .0000
                                                                                                          294
-------
Analysis Report.
            QC Standard
                      Thu  10-23-97 05:36:13 AH
                                         page 2
 fianoe
                    i.OOO
                                       2.000
                                        3.000
Flfiffi
Units
AVOP
SOev
SRSD
Sntflii
nob
-.6974
1.5935
228.5
Sr42l5
pt)b
.0328
.0272
83.03
Ti3349
ppb
.ni»4
0802
702.3
T 11908
ppb
010. Ifl
4.15
40.8!
VJ924
ppb
.397?
.1084
27.28
7.n2062
ppb
.2472
.1436
58.0"
812881
ppb
29.00
5.22
18.00
 *2
 83
.4910
-2.508
-.0751
 Errors  QC Pass
 Value   .0000
 fianae   13.00
.0586
.0043
.0355

QC Pass
.0000
1.000
.0714
-.0797
.0426

QC Pass
.0000
8.000
014.%
08.120
Q7.456

 QC Fail
 .0000
 5.000
.4412
.2738
.4766

QC Pass
.0000
2.000
.2709
.0933
.3776
 IntStd  1         2         3
 Mode    tfoiints   Tine      NOTUSEP
 El en    Y
 DUvlen  371.030   -
 Avge    ?2477<)    1SOOO
 SOev    ?341.1?a  .0000000   --
 tRSfi    ! 041523  .0000000   —
23.28
30.21
53.50
                                                 QC Pass   QC Pass
                                                 .0000     .0000
                                                 12.00     120.0
                              4567
                              NOriJSED   NOTIJSEO   NOTUSED   NOTUSEf'
 8'
 V'
 t?
                   ISOOO
                                                                                                        295
-------
Analysis Report      QC Standard

Method:  TRIAN6L2   Sample  Naie: ICB/CCB
Run Tine:  10/23/97 05:37:37
Consent:
Hode: CONC  Corr. Factor: I
Thu 10-23-<>7 05:42:19  AH     page 1

            Operator: SRB
R38
linm
Suns
Sfifiv
•SiRSri
91
»2
13
Errors
Value
Range
El em
Units
Avge
SOev
IRSD
HI
»•>
4.5
Frrnr*.
Ya | MR
Rangp
!-l?n)
'ini rs
*VO«
Sfie»
tRSf)
HI
1?
»3
Errors
Value
Range
E)e»
Uni ts
Avge
SBev
SRSO
HI
!•>
43
trrnrs
7.1 1 ue
Ag3280
pnh
1507
. 43ft.t
?90 . «»
.At^o
0880
-.?5?9
OC Pass
.0000
1. 000
Cd2265
ppb
.1092
.0804
73.60
. 0997
.1930
0340
Qf Pass
.0000
i . nnn
1 ih/07
nnh
A 140
.051*
16.41
.2820
.3735
.286*
OC Pass
.0000
1. 000
2203-1
ppb
.S74S
3.617
A27.S
4 047
- A47J
-•> '7o
MnrHFflK

A 13082
DDD
4.<'14
.fl?4
16.77
4.470
4.399
5.865
OC Pass
.0000
50.00
Ce418h
ppb
^612?
2.516
411.0
-? ?h7
1.7 (A
.? . 39 1
Of Pass
0000
3.000
dfl-.'79i'i
onh
S ortO
5.7?^
102.2
-.9574
8.156
0.401
OC Pass
.0000
30.00
2203-2
ppb
.4M?fl
1.403
?9fl>
-1 02h
.A7<"
l.'Sh
MnfHECK

AS 1890
nnh
1.424
1.09?
76.66
.2400
1.642
2.391
OC Pass
.0000
5.000
C02286
ppb
!4570
.2725
59.63
.1468
.5665
.6577
Of: Pas<
.0000
1.000
rtn?S7h
nnb
.107?
.ftO?7
j.497
.!0°4
.1080
.104?
OC Pass
.0000
2.000
Sb?068
ppb
.8371
1.932
232.'
-.103°
- 4538
3.054
ilC Pass
0000
8.2496
nnb
4.036
.508
12.58
3.465
4.210
4.435
HOCHECK


Cr2677
ppb
.4543
.3563
78.41
.0504
.5fl»o
.7236
QO Pass
.0000
•? . iinn
H02020
nnn
- i)l31
.4898
3739.
.3785
-.5623
.1447
QC Pass
.0000
2.000
1960-1
ppb
-1.029
1.934
188.9
.6933
-.(W
•3.122
NflCHECK

834934
nnn
.1154
.0848
73:41
.0231
.1335
.1897
QC Pass
.0000
•2.000
CU3247
ppb
.3250
.2275
69. °5
.2100
.1781
.5868
Or Pass
.0000
?.iW'
Ha5302
DP»
014?
.144°
1018.
.1534
.0252
-.1358
OC Pass
.0000
300.0
l°-<0-2
ppb
1.980
.620
31.16
1.78"
1 . 403
? o83
HOCHECK

8e3l30
pob
.OOQo
.0103
1189.
.0128
-.0056
-.0045
OC Pass
.0000
1.000
Fe2714
ppb
11.68
5.81
40.75
5.412
16.80
12.75
OC Pass
0000
40. 10
Mi23lo
onh
4814
.8236
171.1
-.1343
.1616
1.4)7
OC Pass
.0000
3.000
Pb2203
ppb
-.5054
.3224
63.79
.8631
.2374
4155
QC Pass
. 0000
Ca3179
DDb
.4210
•J.066
252.7
-.7535
1.326
.6929
OC Pass
.0000
60.00
K.7664
ppn
.1355
.0203
15.01
.1217
.158°
.1259
QC- Pass
OOiiO
??0.''
P.2140
nnh
-1.857
4.051
218.2
-5.068
2.695
-3.197
QC Pass
.0000
30.00
Sel960
ppb
.9838
.3818
38.81
1 424
.7768
. 750?
QC Pass
.0000
                                                                                                          296
-------
Analysis Report      QC Standard
                                 Thu 10-23-97 05:42:l<» AH
                                                    pace ?
 Range
                    4.000
                                        2.000
                                        3.000
El en
Units
Avge
SOev
4HSD
Snl899
ppb
-.6483
1.3390
206.5
SN215
ppb
.0477
.0419
87.76
H3349
ppb
.138?
.1569
1)3.6
T11908
ppb
4.590
2.597
56.58
V_2924
PPb
.5555
.3886
6
                              3
 Hnde    *finnnfcs
 Hem    r
 Wavlfin  .571.030
 Avge    222717
          Tin»?
           15000
                    4         S         6          7
                    NOTUSEf'   HOTIISEP   NOTIISEP    NQTUSEf'
 SOflV    3002.896  .OOOOQOfi  --
 *RSD    1.348303  .0000000  --

 »1      220558    15000
 82      221446    15000
 83      226146    15000
                                                                                                                      007
-------
         Rennrt
Of: Standard
Thu 10-23-07 05:47:05 AM
oaae I
Method: TRIANSI.2   Sanole Na»e:  ICSAR
Run lime:  10/23/97 05:42:23
Coninent:
Mode: CONC   Corr. Factor:  1
                                  Operator: SRS
Elein
Units
Avge
SOev
IRSO
HI
*2
13
Errors
Vain*
Range
F'iPn
IIPUS
(WOP
^I'lfiV
•JHSn
41
V
»3
Error?
Value
Range
Elen
Uni N
Avge
SflP.V
^PSO
ill
«?
m
>rror<-
'^
nnh
4^.3
1 •>
•-•"ii*,
4^8 1
lfts.°
466.2
QC Pass
500.0
20.00
L16707
DDb
53<>.0
3.?
.6008
54? s
558.5
S.Nf.. 1
unOHErX


?70.\-i
DDb
53*. 8
12.9
2.395
531.6
551.4
527.3
HOCHECK

A 13082
ppb
519600.
5308.
1.022
525600.
517700.
515500.
QC Pass
500000.
20.00
Cpliflh
onb
48P.?
^.i>
. A?S?
•W2.0
486.0
189.4
HOCHECK


Hg2790
pob
546600.
2558.
.4680
S49SOO.
544700.
S45500.
Of: PHSS
SOOono.
?0 00
7703--?
opb
45?."
<».7
2.138
457.4
442. <)
461.3
NflCHECK

AS1890
DDb
518.4
2.0
.3826
519.9
516.2
5I?.2
OC Pass
500.0
20.00
Cn??86
nnh
4M.I
!.?
.'66'
465.4
463.0
465.7
OC Pass
500.0
20.00
Nn2576
pph
451.4
l.«
.4101
4S.M
44<».7
4SI.?
Or Pass
SOO "
20.00
Sh?06R
opb
506.2
3.2
.6304
506.5
502.8
509.1
OC Pass
500.0
B_2496
DDb
516.0
3.1
.6060
518.8
512.6
516.6
NOCHECK


r.rWl
nnb
47^. 1
1.!
.'3.^
478.2
476.0
476. ^
OC Pass
500.0
20.00
1102020
POb
4%. 8
l.«
.3786
498.4
494.8
407.J
QC Pass
snn.o
20.00
I
556.1
556.3
521.6
NOCHECX

8a4934
pob
506.3
3.3
.6436
510.1
504.5
504.4
QC Pass
500.0
20.00
CII324T
opb
508. 9
A.I
!.'S4
51e.l
506. J
504.1
OC Pass
500.0
20.00
Ha3302
PDA
5.02<»
.132
2.610
5.175
4.994
4.9)8
Qf: Pass
5.0
453.4
452.0
455.7
OC Pass
500.0
20.00
Pb2203
pob
481.5
2.2
.4564
482. 1
479.0
483.3
QC Pass
500.0
Ca3l70
DDb
472900.
1345.
.2844
474400.
471700.
472700.
OC Pass
500000.
20.00
K.76M
oora
22. *9
I?
.54^
022.82
22.67
22.58
OC Pass
19.00
20.00
P.2149
onb
482.5
20.5
4.248
481.3
462.7
505.6
QC Pass
500.0
20.00
Sel%0
PPb
521.7
4.7
.8988
525.2
523.6
516.4
OC Pass
500.0
-------
.Analysis  Rennet
 OC Standard
   Thu 10-23-97 05:47:05 AH
                     pace 2
  Sanne
         20.00
                   20.00
                   20.00
Hen
Units
Avge
SDev
4RSD
81
82
83
Errnrs
Value
Range
IntStd
Mode
Elan
Havien
Avge
SfiPM
*RSO
Snt8°9
oph
49fl. 7
i.o
.7251
502.6
495.5
498.0
QC Pass
500.0
20.00
,
*Cnnnts
Y
571.030
203737
fits. |3Po
. 1000
                                                                                                                  299
-------
         fienort      ftveranes            Thii 10-25-97 02:50:12 PM     oaoe 1
Nfithnd:  IRIANGI?   Sanole \\w.  184-?5-lAfl V10         Operator:
finn line:  10/23/<>7  13:47           Filenaae:  102317
MnriP:  ("OMr        IVOR: S         Cnrr. Factor:        1.00000
Uh ffJ.:          Oust. Siol. ID.:           Cust. 10.: 43251
Flems
Units
Avge
SOev
*RSO
fla.wao
nob
12.4
6.018
C02286
ppb
34.15
1.33
3.095
Sel%0
ppb
70.98
1.68
2.367
T 11908
PPb
72.8?
ft. 487
8.909
                                                                                                          300
-------
"Analysis Report      Averages             Thu 10-23-97 02:50:12 PH     page 2
Method: TRIANGL2   Sauole Kane: IR4-23-2A8  X10         Operator:  SRB
Run Tine: 10/23/97 13:52           Filename:  102397
Node: CONC         Tyoe: S         Corr.  Factor:        1.00000
Lab ID.:           Oust. Saol. 10.:            Cust.  ID.: 43231
FlRBlS
Units     opb
AVOP       Srt.;.
          .387
RfiJl30
opb
IS. 17
.0752
.4954
Co2?8£
oob
42.98
.6077
1.4)4
sumo
ppb
127.4
1.792
1.407
T 11908
ppb
167:7"
5.o
5.34
                                                                                                         301
-------
•analysis Report.     Averages            Thu 10-23-97 02:50:12 PM     page 3
Method: TRIAH6L2  Sample Hane:  184-23-2AB X10 POS    Operator:  SRB
Run  Tine:  10/23/97 13:57           FilenaBe: 102397
Mode: CONC        Tyoe: S         Corr. Factor:         1.00000
Lab  ID.:          Cust. Snl. ID.:            Cust.  ID.: 43231
Hems
Units
AVCIR
SDev
*RSn
Ag3280
onb
H7.50
.2254
.?57h
BBS 130
opb
58.87
.1733
.2944
C02286
DDb
9 '
.7723
.884
Sel%0
DDb
175.1
1.258
.7271
Tll"08
PPb
214:?
8.937
4.171
                                                                                               302
-------
         Renort      Averaaes             Thu 10-23-97  02:50:12 PH     page 4
Method:  TRTANGL?   Sanple Nane: 184-23-2AB \10  L       Qoerator: SRB
Run Time: 10/23/97 14:02          Filenane:  102397
Node:  COHC        Tyoe: S        Corr. Factor:         1.00000
Lab ID.:          Cust. Smol.  10.:            Cust.  ID.: 43231
El ens
Units
Avge
SDev
%RSD
Ag3280
opb
8.408
.3713
4.416
8e3130
opb
3.464
.0213
.6149
Co2286
ppb
9.450
.1277
1.352
Sel960
ppb
25.07
1.595
6.363
T11908
ppb
35.64'
4.383
12.3
                                                                                                 303
-------
Analysis  Report.      Averages             Thu 10-23-97 02-50:12 PM     cage 5
Hethnd:  TRIAH6L?   Sanple  Na»fi: 184-23-3AB XIO         Operator: SR6
Run Tine:  10/23/97 14:08          Filename:  102397
Hod*:  r.m?         Tyoe: S        Corr.  Factor:        1.00000
Ub ID.:          Cust. Snol.  ID.:           Oust. 10.:  43231
Elfli*
Uni ts
Avge
SDev
IRSD
Aq3280
opb
18.90
.4456
2.358
BR3130
ppb
9.108
.0112
.1231
Co2286
ppb
47.27
.4996
1.057
SeWO
ppb
115.6
2.65
2.293
TIJ908
ppb
130!*
7.523
5.740
                                                                                               304
-------
Analysis Reoort      Averages             Thu 10-23-97 02:50:12 PM     page 6
Method: TRIANGL2   Sanole Name: 184-73-3AB X10 DA      Ooerator:  SR8
Run Time: 10/23/97  14:13           Filenane: 102397
Mode:  CflNf:         Tvoe: S         Corr. Factor:         1.00000
Lab (0.:           Cust. Saol.  10.:            Cust. ID.:  43231
F.lP.me     Ao3?80   Rp.3130   Co??8*   Sel9fiO   111908
Units     nnh      ooh     pnb      opb      ppb
HVOP       Ifl.flB    9.051    47.70    llfi.l    139.?
                   .0407     (,765    I  19|    4.259
                   .4494    1.418    I.07S    3.0*
                                                                                                    305
-------
analysis Reoort      Averages
Thu 10-25-<»7 02:50:12 PH
page 7
Method: TRIANGL2   SaiiDle Nane: ICV/CCV                Operator: SRB
Run Tine:  10/23/97 14:18           Filenane: 102397
Node: CONC         Type: 0         Corr. Factor:        1.00000
Lab ID.:           Cust. Snpl.  ID.:            Cust. ID.: 43231
Flea?
units
AVQR
SDev
iRRf>
Kleins
Mni r.«
AVOP,
Shpw
•5 HSU
FlBUS
Units
AVQP.
SDev
tRSO
El ens
Units
Avge
Sfiev
liRSD
FlPB?
iini r.s
fivgp
Sfiev
tRSft
KlP.ms
Hin N
AVOP.
Sfipy
*Rsn
Ag3280
ppb
503.1
3.32
.66
C3.il 79
nnh
uSbO «
^07 . 4
/» . A
Ffi?7U
ORh
OW.O
804.5
80.6"
Ma3302
pom
4.965
.51
10.27
1960-1
opb
SO,v-3
l?.o.i
•'..^87
m$49
nph
Sui I
h.ll13
1 . >78
A13082
ppb
0567.9
65.94
11. At
01226S
nnh
511.0
A 097
1.1*2
K.7664
opi
4.548
.1051
2.311
Mi2316
npb
510.1
3.816
.748
I960-?
opb
514.7
o 312
l.80«
FIIQ08
nnh
500 ^
a. a??
1.76?
As 1 8<>0
ppb
512.8
6.248
1.218
Ce4-186
PDb
507.0
a. tsi
l.oOS
116707
ppb
469.7
5.841
.8179
P.2149
PDb
0573.7
104.9
18.29
Pb2?03
DDb
0^77.0
50.74
3.794
V_29?4
pnb
505.. \
I..U8
?0o8
R_2496
ppb
610.5
12.97
?. l?5
Co228h
nnh
505.5
•>.4H
. 4905
Ha'^^O
ppb
0937.5
737.1
78.6?
2203-1
pnb
665.6
143.6
21.57
SeH60
nob
511. 1
10.12
1.070
;n?062
nnb
01247.
l?54
100.5
Ba4934
ppb
502 '.\
1.408
.2805
Cr26/7
pob
510.2
4.R24
.9456
Mn2576
DDb
064v. 3
260.3
41.47
2203-2
DDb
532.7
9.081
1.705
Snl8°o
opb
405.:?
23.44
4.734
Si 2881
nnh
139148.
l?fl.n
4.o85
8e3130
ppb
506.o
1.346
.2655
r:n3247
onb
506.6
A.???
1.228
Ho20?0
ppb
504.6
.:,.017
.7763
Sb2068
Dnb
505.4
4.52
.8942
SM?!*
DDb
500.1)
1.306
.2613





-------
       s Repnrr.
Thti 10-73-97 0?:50:12 PM     page  8
Method: TRIANGI.2   Saaole Hane:  IC8/CCB                 Operator: SR8
Run Tine:  10/23/97 14:24          Filenane:  102397
Mode: CONC         Type: Q        Corr.  Factor:         1.00000
l.ab ID.:           r.ust. Suol.  ID.:            Cust.  ID.: 43231
F.IRIB?
Vni ts
HVQR
SDev
SRSf!
lini I*
MVOP
Slip"
FISH)-?
Units
Avge
iflSD

El ens
Units
Avge
SOev
Units
Auofi
.SOev
Hey/feu..
.9285
.221
23.8
Ca3179
DDb
Q7ft3. I
353.5
174.1
F*r/l4
nnb
UV% 7
179 A
15*. 2
Na.«0?
ODD
.2454
.1572
64.08
1960-1
pob
-1.787
I.7fl8
100 /
nw6
onfi
/.04<>
/4.ft72
/ I53.'x-
-BlOUOi 	 HS-18W-
ppb ppb
Q74.76
40.46
54.11
Cd2265
pob
02.463
5.935
15". 7
i 7fto4
npm
0438
.1)771
1?*.?
Hi?3l*
DDb
1.682
2.293
136.3 y
196/2
DO/
/.326I
/7.63
806.3
TH908
oot>
Q*. 377
?.'>7jU—
*4fM
3.028
2.429
80.22
Oe4186
onb
05.986
4.681
70.19
Hh7fl7
nnh
8018
QA?
H3.I /
p 9 v(«
POO
JB2.65
/'I. 22
167.1
Pb2203
PPb
04.054
.5562
13.72
V_79?4
ppb
1 . 94C
-Ti505
103.5
• u>'r.K/ •
ppb
53.81
10.4
19.33
Co2286
DDb
01.418
803
V.A4
nov?9/
nnb/
fl/b I 5
Aw.\
loo
7203-1
DDb
3.052
3.577
117.2
Sel960
DDb
-.8126
1.75
215.4
7n2062
ppb
JJ44V7 _
747
167.6
DdiHJ^ -
ppb
1.973
3.112
157.8
Cr?677
DDb .
07.44JT
3. y\
m.i
Hn257o
pnb
y93.05
160. n
171 5
2703-?
DDb
1.554
1.201
26.37
Snl899
DDb
9.120
13.6
149.1
S17881
opb
a ma1?
268.6
24.82
1 Boaiw 	 ^
ppb j
.6367 /
.6716 /
105.5 /
\jjR\)( 4 /
/^pb
05.365
o.898
178.6
iio2020
DDb
1 487
1.18
70.35
Sb2068
pob
04.814
1.814
37.68
Sr4215
PPb
01.469
2.377
161.8


	 	 	 •


                                                                                                          307
-------
Analvsis fleoort      Averaaes
Ihii 10-23-97 02:50:12 PM     page 9
Nflt.hod:  TRlHNGl.?   Sample Name:  FCB/CCft                Operator: SRfi
Rim rime:  10/23/97  U:37           filename: 102397
Mode:  CONr         fvoe: 0         Corr. Factor:        1.00000
lab 10.:          Cust. Snol. ID.:           Cust. ID.:  43231
ElfiBS
Units
Avge
SDev
4RSO
El ems
Units
Avge
SOev
SRSO
Flea?
Units
HVQP
SDev
MSP
f IfiBS
lini r.
nnni
I4?J
.?/4s
192 A
1960-1
opb
1.782
2.798
15.7
Ti3349
ppb
-.0375
.1032
275.3
A 13082
ppb
43.83
3.268
7.455
Cd2265
pob
.0835
.2364
283
K.7664
opn
-.1330
.0685
51. S
N123I6
pn*>
?9|(i
7474
'56. ft
I960-1?
ppb
-.0562
1.641
2921
111908
pob
1.390
3.249
233.7
ft-51890
ppb
.0183
.2873
1566
C64-186
ppb
-1.043
2.254
216.1
H6707
ppb
-.0438
.1492
305. fl
P >U4
nnb
-1.5HO
I 3? 4
.W.8<
Pb2203
Dpb
.737Q
1.157
156.8
V.2924
PDb
.4379
.381
87
8_"496
ppb
19.21
1.032
5.374
C02286
PDb
-.4362
.2649
60.72
Ha2790
ppb
-.0074
3.584
48610
22W-I
opb
3.347
3.74S
III 9
Set 960
ppb
.551°
1.245
?23.9
Zn2062
DDb
5.658
.3572
6.313
8*49.34
ppb
-.0100
.0866
863.1
Cr2677
onh
.0423
.3302
781.2
Hn2576
DOb
. 1?30
0502
40. R)
??OJ-?
onb
-.5649
A. 503
620
Snl899
ppb
-.2662
.5858
219.3
S12881
DDb
80.77
6.595
8.166
BBS 130
ppb
.23K-
.0245
10.58
CU3247
nob
.1351
.1037
76.73
Ho202f'
opb
. !686
.1867
110.7
Sb20h8
ooh
-1 13
1 .\.\6
II 75
Sr4215
ppb
.0011
.0411
3584





                                                                                                    303
-------
Analysis  Reoort
Averaaes
Thu 10-23-97 02:50:12 PH    page  10
Method:  TRIANGL2   Sanple Haae: ICSAB                 Operator:  SR8
Run fine:  10/23/97 14:4?           Filename:  102397
Mode:  CONC        Type:  Q        Corr. Factor-        1.00000
Ub rn.:           Cust.  SBDI. ID.:            Ciist. ID.:  43231
n?»s
Urn N
Avqfl
Sfmv
-*Hsr>
Flems
Units
Avge
SOev
%RSn
El ems
Units
Avge
SOfiv
«SD
F)p.m<;
Units
HVQP
•SIJ8V
*«-?
nnr>
5.il.7
II s?
I US
III 90S
opb
502.5
16.41
3.266
As 1 890
noh
519.8
6.R81
1.324
C.R41R6
ppb
489.8
3.428
.7
116707
DDb
582.5
33.65
5.777
P_?14" •
opb
49R.A
28.6ft
S.751
Pb??0.3
nnh
4fll..i
•4.4?7
9305
V ?9?4
ppb
489.2
3.043
.6222
R .7496
!>nh
540.5
4.63
.8566
ro2?86
ppb
459.7
4.27
.9289
Mg2790
pnb
545000.
3762
.6902
7203-1
onb
504.0
1. 3.. S3
?.644
Se I ^hO
DDh
528.7
i.M?
.3?38
Zn206?
DDb
423.7
7.391
1.744
B34934
Dpb
509.3
7.651
.5204
Cr2677
opb
473.5
4.85
1.024
Mn2576
PDb
438.1
3.381
.7718
7203-7
DDb
469.3
11.84
7.S19
S'nlS'}'}
nob
474. /
4.471
93 M
Si?R8)
DDb
5650.
23.98
.4244
Be3l30
pob
485.4
4.253
.8763
Cu3247
ppb
519.9
6.066
1.167
H02020
PDb
494.7
2.868
.5797
Sb2068
DDb
505.0
10.08
1.995
Sr4?l5
nob
502.0
1.770
.2445





                                                                                                      303
-------
        flp.nort   f?Dl?: IM470
Fhu 10-30-97  07:lbi47  AH     pans I
  Nan?: Hfl470            Aytwuoler lyoe:  fVPE  TJA
   Positions- (5S/19?    QC Positions: 13/19      » Sat?:  5
?. Station location i? racfc -1.  oos. -1.
                                            »Pos Uft  AnalV53?/Pof.
I
?
3
4
S
—
SP.t,
1
?•
.)
4
S
...
*tl
Hn >
«.,
1
7
3
4
S
6
17..
Rank
Pn<
1
'/
\
1
S
>.
7
H
<»
10
11
AMU i
Satin IP
.Sanolfi
Sa«m|p.
Saaole
Sannle Set
ivoe
Nonal
Hnrnal
Normal
Noraal
Normal

Mnt.'ke
;unnip.c MTP
RON Col
I
7
4
5
6
.14 Not
V
RON i':n I
1
•i
"\
l
S
f.
7
. 8
Q
10
II
U ftack
IIM»B>
1 16991
(Una)
Il6nil
B ...
Prp.nare?
No
(In
No
No
MO
n Tnfn ---
i.ior..i!fp»-'

Sannls Na
STfi3
Sini-BI.AN
ir:SA8
CHECK LO
ICV/CCV
1CB/CC8
Used)

S.innls Na
t.A-7fl
ifn-:>.^-?6
187-32-1
187-37-1
«.to30 Bfi
*3J3o (.CS
187-fc-l
I87-A-1 0
187-4-2
STO/OC/BLAHK
Saaoles
Saenles
Sannlp-;
Sanoles

Oescrintion
43603
4323!
43*>30
4.^1^
I.U4I

Final I'it f:

se Sst »
.-NA-
> -MA-
-NA-
-NA-
-NA-
-NA-


RP. Set t
1
i
ft x'.'oo 2
B X20" P')S ?
XI 00 1
VI Oft Pfl ' 1
*n i
48 1
48 1

Method »Pos R
TRIANi5l.2 4
TRIANSI.? ?
TRIANiil.2 11
fPIANfil.2 1 1
TRlAHftl.? 11

rtor

p)p
-MA- S.iBnl/>
-HA- SPHO'P
-MA- Saoole
-NA- Saaole
-NA- Sasoie
-llfl- Sa»Dle
-HA- Saiole
-NA- Saiole
-NA- Saiole






JckK StartPos
't 1
1 *
2 ?
2 if
2 >
-------
Antn3anplp.r Rennet   Table: HA470




Rack 9?




Pns  ROD  Col    Saaols Nane
       IO-30-«7 07:IAi47 AH     woe  ?
 II  ..«8   Not Used)




 Rack »4




 Pos  ROM  i:nl   Saaole  Nans




 iI...48   Not Usedl




 Rank I1*




 Pns  PON  cnl   SanDle  Hans




 11.. iJi   Hnf Used)
Set. «  8llsp.fi
Tvoe
!•>.
13
14
IS
Ih
|7
IH
I'J
•?o
?l
'>?
73
V«
?5
26
'7
28
29
30
31
32
33
.<«
XK
3ft
•:?
/.h
Xu
Uii
H,r,
««
1 ' 12-
? I
'' ?
? .X
? i
9 *
'' ft
•/ 7
•> 8
? °
? 10
2 II
? 1?
.X 1
3 ?
3 3
3 4
3 S
3 ft
.X ?
.x ft
> 9
A in
1 (i
.-. r/
4 1
• •>
•i •.
IK flnf
I.'.
KOM i':o I
187-ft-2 MS
187-6-2 HSP
(87-ft-? PfiS
If 7 -6-? l.
l87-ft-3
I87-A-4
1XMSR nft
d.^l^H I.CS
tfl^-iJO-l
[fift-Qft., [|
1 86-90-?
1 86-00-7 MS
186-90-? MSI)
1 QJLvOl)— 0 DHQ
1 HO " r"'^
186-90-? 1.
186-90-3
186-90-4
43641 M8
43641 I.US
187-17-1
187-17-1 0
I87-I7-?
I8V-I7-? MS
187-17--' HSf'
I87-I/-7 i/DS
187-1 7--J 1
I8M/-A
IM'-'-17-<
IKRrt.

».nl. Na.fi
3
3
3
3
3
3
4
i
4
4
4
4
4
4
4
4
4
5
S
s
S
<•
S
s
5
5
S
s


Set it
-MA-
-NH-
-MA-
-H«-
-MA-
-Hfl-
-HH-
-HA-
-NA-
-Hfl-
-HA-
-HA-
-IIA-
-HA-
-HA-
-MA-
-HA-
-HH-
-HA-
-Hn-
-M«-
-NH-
-MH-
-N«-
-Htt-
-»H-
-HA-
-iio-


BHseil
Saanlfl
Sannli? •
siapift
Sample
Saw 16
Saanl?
S.imnta
saBinIs
S.mnte
Sanol?
Saiolfl
Sanole
saanle
Saiiolp
Sannle
Saople
Sainle
Sanol"
Sanole
SSBplP
Dannie
Sannlp
sannle
Sa.nnlP
Sannle
S.9.Df>l ?
^Aynl 6
S?nple


1 lyoe
Set I  tnsed
Fvne
Set I
fvne
                                                                                                        311
-------
                      Fhii 10-30-97 Ot:36i39
                                                                 oaoe  1
in (n.
         p: STC'3                   Operator:
01:08          Filenanp,:  103097
Tvnp' 0         Oorr. Factor:        1.00000
am. -Saol. m :           I'nst.  ID.: 43603
, FlPine
1 Hni ts
u HWOP
SOfiv
' *Rsn
Flems
; Unit*
^ Avoe
Rfipv
tRsn
( 1 p«<5
Units
< AvoB
V SIlP'J
•sisii
/ •
^ !• 1 'I*!'
i!ni"»
/ ' HV1f>
1 SI'S''
~,lt?.\!
r •
1 Flprne
^ Units
HUOP
' SflP.U
; 4RSO
r Elems
' Uni ts
^ Avqe
, „ SOp.v
; tRSD
Aa3?Rf>
onh
1007.
3.0hS
.3043
033170
ppb
1004.
A. 3°
6363
FP.77U
onh •
Hll.V
HI in
•30) S
l4.VV.lf'
r»ni£
•' -iVM
': •' ,',f.
1 Ml

lOfn-l
oob
IOIV?.
S l/fi
.SIAft
Ti334<»
pob
1000.0
3.144
.3144
AUOR?
nnb
qos.o
11.69
1.174
Cd?265
.ppb
1002.
r.95?
2946
K 1M
nnn
« SAO
.IS-JI
i ic;
N) >".\r.
nrn
|IM'|4
i 30?
r.?HS

IPMI-^
oob
1000.
J3. 7«
4.579
T 1 1908
ppb
1004.
13.71
1.366
Asia1"!
oob
1003.
4.141
.413
Ce4186
Rob
998.7
?.932
.2936
UA70/
onh
9>>3."
lfl.M3
1 m
V 7| 1<*
piih
|(H|8
I/I n 7
1 .<«'.

Pb''?(i3
or.n
1006
'24.54
7.44
V.2924
pob
1003.
?.*<»
.2b81
B_?4«6
opb
1007.
2.629
.-7A1I
C02286
pnh
1004.
3.°
.3885
Ma'W
onh
100'?.
l.W
»7fi«
•<'"'A- 1
nnh
1 IK'S .
3 OSh
iflA?

SPI9AO
oob
IrtOJ.
?8.hft
7.863
Zn2062
pob
1008.
3.83<»
.3807
8a*93H
opb
000 (
3.2R5
.3?fi7
Cr2677
pob
lOOh.
3.83S
.3814
Hn?57A
nnb
100.5
3.40?
.?39?
?3ft3-5
nnh
ions.
5V>--'
3 74S

SntflW
opb
1003.
5.028
.5011
Si2881
oob
10020.
43.08
.4301
8*3130
opb
.1005.
2.562
.2551
Cu3247
nnb
1002.
3.041
.3033
Mn?0?0
nnb
tons.
1.307
.13
Sttfl'lhfi
nnh
<»*"» e.
s ^
.V?'''

<5rd-'1S
oob
000 (i
2.51/
.251°





                                                                                                    312
-------
          flenort
                      Aweranes
                                 Thu  10-30-97 06:36i39 AH     oaoe 3
HRthod: TRTANfiL?    Sa«pl«  Haw:  ICV/CCV                 Operator: OKH
Run fiae:  10/30/97  01:20            Filenase: 103097
Mode: MM          Typp.: 0         Corr.  Factor:        1.00000
Lab II).:            P.iist. S«o.l.  10..:      '   - Cust.  ID.:  4360.3
FlPB?     Ao3280    A13082
Units     nnb      onb      pob
«VOP        S«v>  A     490.A     504
SIIP.U      h rtHS    21.44     57?
tCW      I  ->ll     4 371     1.13
                           RJ496   8*4934    Be3130
                           ppb      nnh      ppb
                            49*. I     502^0"     498.1
                           11.12    5.951     8.485
                           •>.?il     1.18*     (.705
                                                                                      ".  3  -
f I fin*.
llm r.c
41MB
pnh     .pnh
 SOti S    495J
I •. «     IM.IJH
•"' ns;    "> osi
                             nnh
pnh

II "H
•> •>*,<<
nf)h      ppb
 498.9    504 3
II  A     o 1170
•>..v»c.     I ftdl
(•' I P»«
Hm I*
           opb

           A7  78
                    K  •;
                    OPS
                  cob      onb       nob
                   4H9.8    49?  I     498  ?
                  II 7S    28 43     10.09
                  ?.4      5.77r.     -?.0?J
                   nob
                    400  A
                   H.?48
                   I.A5?
rtwgp,
SOsv
tfiSD
                             P.2I49   2203-1   2203-2   Sb2068
          nnw       pph      nnb       ppb      pnh      poh
            5106    496.6    491.0    4974    4946     495.5
          .181'    10.07     16.81     18.8S    18.17    9.837
          3.548    2.028     3.423    3.79     3.673    1.985
                             9.7.W
                    I9AO-?   Ph??fi3    Spi9nfl   Snlfl00
           onb      nnh      nnb      nnh      opb      nnb
            489  8     18fl  A    495.5     tiSa.fi    498.rt    498.A
           21.5?    I? '/6    13.54    11.1?    8 796    6.816
                                               I.76A    1.3*7
!-'|P.»=      ii.s.vJ1'   III90H   V  '/si'
tlni f.«;     nnh       nnh       nph       nnh      pob
MIMA        4«ft  ft    4HJ  II   49-V  1     4^..i    S016.
SIIBV      h..'.«S     AA  If.     (0.J9     I?  9K    |I2.1
"Hsi;       I  ''Mr.     r. 85      ?.OH      ? n|?    2 ?35
                                                                                                                313
                                                                                                                                       I ~\
-------
             ftpnnrt
                                       •   fhn 10-30-97 0*-.tt;.3o AN     paop 4
Nflthnrt:  fKIAMHl.'J   Sasnle Mane: ICfi/Cf:B
Run Tina: IO/3f>/97 OI.-74           Filp.nJtn*: |ft30°7
Node: i:OHC     —  Type: 0         Corr. factor:
I ah If..-
                                                           OpBMtor:  fiKH

                                                            1.00000
;    llni ts
\-   Avgs
    Sfmv
L
    (1 P.»<*
i    Hni r.<5
;    BVOP
    SlIRV
    t I P.B«
    Uni r«
    )•' I P«C
    nni ts
    HfilDS
    Unit?
    llni r.s
          Aq3280    A1308?   As1890   B_2496   8a4934   8e3t30
          npb       pnb      nph      neb      nob      nnb
                     -18.88   -.8837   2.295    -.348? J^.0419
                                     3 U
    SIIP.V
                            nnh      ono      nnh
                            0-10.79  Q-l.hOfl
                            IS 07    I.10|
                            I.W ,'
                            Pb2203   Se|960   Snl899   Sr42IS
          nph   /   nnh      nnb      pnh      nnb      poh
                     .3069    -I.H4    .1508    -.3396   -.1163
          f>. M      7.394    1.409    .5844    1.6.35    .1798
              .3     780.1    I2(i.5    129.6    481.5    154 6
                                         144.3     310.4
                                                                                                            314
-------
         fieonrt      Avenges
                                Thu 10-30-97 Oft:36i39 AM     D.W.  S
Hprhn    1.038
         fip.5130
opb      opb
 -.1773   -.063?
.0824    .0512
64.71    40.47
         C42265   Ceil86   Co2286   Cr2677    Cu3247
pnh      pnb      nnb      nph      pph       ppb
 -.2855   -.0974   -1.576   -5120    -.7432     1488
         .9311    7.063    .5358     .6873     .7?34
         237.1    130.9    104.7     9?.48     486.1
Flpmc
Hni t*
Awflo
Sfiftv
W*l.
MM*
Mm ' e
,i-»n*
::fis.-
'"*
FIMC
llni ts
AVQP
Sfmv
susr.
fleis
Uni ts
Avge
Sfiev
twso
FP.77U K 7664
nnh nnn
-13.85 .OS9S
Irt 48 JiAhl
'S '" «' A(
MAA.I-- rn.'-lr.
n^fii n^^
-l!-'l • ••'•lul
•••I"1. I !>3»
I«S •' ||0 4
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nnn oph
- . ROflo ? . HO
I.321* .<>549
164.? 30.48
Ti3349 TH908
pnh opb
-I. Oil 2.195
1.209 S.7?
II1*. 6 260.7
1 i6707
nnb
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'* p
P -Mrt
onn
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•i H-)'j
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81.08
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-.1878
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- 068 >
0/J>7
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•'•Jft5-'
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- I83/
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Snl*o«
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-.107?
1.19
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nnb
7.441
17.14
230.3
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nnh
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.9J35
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-.0775
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59.23





                                                                                                            315
-------
             Rppnrt
                                 Ihn 10-30-97 06.-36i.39 AH
                                                                         paae 6
J    rtnthiuJ:  IRIANKI.2   Sasnle Nasm: ICSAB                   Ooentor: DKH
L   Bun HUP.:  10/30/07  QI:3S           Filenaup: 1030°?
    Rmj8-_f:ilNi:         Ivpp.r 0         Corr.  Factor:         1.00000
'    I ah n-  :            foist.  SBP.I. IP •.            Cust.  H>.:  43603
    Unit*
    IHSIl
           RO.V.'HO   I
           nnh      nnh      oph
            v/» «»    M«3nO   Mil S
           •i  ftofi    e)'\
HPIDS
Uni r.
-------
       « HRonrt       flveraoes         .   Ihu lO-3ft-*»7  iifc:3ij;.39 AN     oaqfi
      i: rpfntlM?    Situnlp Hane:  •<*••  Si" I  .'.'l'J'.r          Oop.r?tor:  OKH
ftun  (IBP-  |u/Ail/<)7  0|:S3           Kilfinaiie: 103097
Mndu- rfiiir          Tvw  S         I'iorr.  Facfr:         1.00000
l.iti  Hi  •            rriist  Sanl. [fi •            i':nst..  10
                    A^IW   Ra40?4   Rp.3130   Cd2?65    Co2286
iinir.«      nnh      nnh      ppb      nob      pph       opb
AVOP       3  303     12.3?    149.3   L8??ft    I«8.T    L236
Sfifiw       .VM4     1.908    .7       .OOfcft    1.932     .1868
SfiSfl       18  (^     IS do    .4918
Flans      f:r?A77   Hn257A   Ni?3l6   P_2149   Pb2203    S52068
ilni !:fl
                                                                                                                    017
-------
J   Analysis Report.      Averages          .   Ihu 10-30-97 06:36^39 AH    cage 10
;'   MPthnrt- rRTANr,!.?   Sasnlfi  Nan?.: 4JT \i I  X10Q PftJy^
                      01:57          Filenaae: I05u<»7
                      Fvne: S        Corr.  Factor:   _     1.00000
    ..in ffi.:           fiiist. Sanl.  10.:            Ctisr..  in.:  43605
  r
  L

i "ini r.s
I
L «>'09
Sllfi"
j tHSP
flfiBS
,' Units
1 nvgfl
Sfmw
, *HSO
' F|PII<;
.Units
' AWOP
SOev
tfi^n
HU '. ni»
onh
JS A.\
• tr-S.'
i ai
i':r2i>77
nnh
167.8
4.SM
?.7I8
SRI%0
oph
S.VA*
7(12?
I..XOO

oob
ft) AS
I 8'?'.'
•> 9SS
MnW*
pnh
" 10180
MS. 1
2.01S
TIIOOP
nob
SA.sa
5.54<>
«.R06

OPb
I8R.3
1 *h
879S
Mi?jlh
nnh
?« 82
?.!'!
3
7n?06?
opb
S4IHt».
IS42
?.R4a

nnh' onb
SO..U 233 :ff
•J8.V4 5.004
1 W •'.-!<
P 214** Cb2?0.i
nnb oph
1115. %28.
IA ?s tas.f)
I so? I.SI4
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pnh
I.WC
16^
1.???

non
50. 9S
1 . 4V7
?.aoi-
Sb2068
nnb
117.8
l.8<»0
1.612





                                                                                                                 31S
-------
unajucic. pgnnrr      ftverin«s         .   Thu 10-50-17 Oo:4u^23 flfi    oa«ie
Hptho<1-  TPIftMftl?   SpBrde Haw:  fCV/C^V               Owrator: OKH
fiiin Tina:  10/30/97 0?:15           FHenMe: 10309?
ilnde-  
FlPB«
ilni r.s
HVOP
S()P.'.'
Wh
HW
Mr.' re
rfVflr
SI'S"
•!>S"
FI.M
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(IVOP
si»ev
tBSfj
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Units
Avge
Sfip.v
do3?ai? A 13082
nob nnb
5071 491 fi
A 8/h 7.??1
I.35S- 1.17
ra3l7<» Cd2265
nnb nnb
SO).? ' 497 9
A. 904 8.731
1 J77 I 754
tf>l\l K ?AM
onh ooffl
MS S -) 7ft?
14 ? 151
••• /M A is^t
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nndi nni
j A > / j«jg 14
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<-. 'i! 1 ln|
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nnn nnb
573.1 497 f,
•,^.3« ?5 41
S.04I 5.I5H
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pnh nnb
499 i) 480 1
7.089 ?7.58
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nob
500.9
5.001
" . 998S
064186
nnb
511 3
13. A7
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1 1^707
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507 . ?
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•i.033
V.2924
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503.5
fl.373
B ?496
pob
495.8
9 755
1.968
C02286
pnb
501 8
8.6?°
1 72
HOW
onb
•)00. I
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•'•'(!.<- 1
nnh
V* *. ('
•-!•) ||J
l •'!>
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50' 9
?l 01
4.l«3
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nnb
494.8
9.59
8^-1934
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50?. P
5. <»3I
».m
Cr2677
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504.3
7.903
I.5b7
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onr.
49ft.1;
S.098
'•*"•
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nnr-
Son <>
1-) OS
J 58*
Sn!fl«°
nob
49°. 3
6 85ft
1.373
Si 2881
oob
5126.
56.14
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50?.?
8.052
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C«3247
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508.4
7.08»
1. 314
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nnp
50.1 4
8. .5*?
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Sb?ftwi
nnh
195 I
a .yi
1 *22
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c.317
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                  5.746    1.663     1.138    1.015
                                                                                                             319
-------
  flnalv<1s Rennrt
                     Thll 10-30-97 06:40:23 AN     MOB 4
•  Mflthmt- IRInNiil?
{ Run HBP-  io/JD/97
  BO
-------
       c Hepnrt
                                       .   Ihu 10-30-97 Ot:40;?3  «H     pane 5
Mpthnd: fRTANGl?   Sa»nl* Ha»p.: ICR/CC*                Operator: DKH
Bun fine: IO/30/<»7 02:25           Filename: 103097
Mndfi: CONC         Tyne: 0         f.nrr. Factor:        1.00000
l.ab m.!           niist. Sunl. 10.: .          Cnst. ID.: 43231
f IP1B5
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AUQP
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tHSf'

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                                                                                                                                       r i
                                                                                                                        321
-------
             ftpnnrf
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                                           Thii  U>-30-°7
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                                            MOP  6
f"  rtBthnrt; l'KiflHhi.->   Sannlfl M.«e: [CR/CCR                 Operator:  OKH
^  Run  TIBP-  Hi/30/07 07:46           Filename: IOJO<>7
   node:  i;UMf:         Fyne: 0         Corr. Factor:         1.00000
,  I  ah  in :            f:n<;t  
                     npto      nnh      nnh
                        (III IS
                      rt14'-'
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                                     IIS.o     
-------
Ihu 10-30-97 Oh:40^?3 ««     oage 7
       TPfrtHfil?  SPBOlp HPBP- fCSft»_
Kim liiBfi- lfi/31'1/97 ft?- SI          FilsiMBR-  103097
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awgfi
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units
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tnrt . Factor:
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541.3
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1 114
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                                                                     323
-------
 ID/Weight File:  AB811,IDW
Sample Volume: 100 ml
   Loc.
Sample ID
                      Analyst: RICHARDS
                      Nominal Weight:  1.0 g
Weight
Dilution
0
1
2
3
4
5
6
7

8
9
10
11
12
13
14
15
16
17
18
19
20


22
23
24
25
26
27
23
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45

46
47
48
49
50
51
52
53
STD BLK
STDl=0.2ug/L v
STD2=0,5ug/L \
ST03=1.0ug/L N. o ,5^ -7 «\ha
STD4=2.0ug/L S *>-vl° c l
STD5=5.0ug/L /
STD6=10.0ug/L .
TrVrA nun/1 n _.r^ r^ Cj Hi

rr>o  tt&.
183-3-10 0X10 ^^^. re-(r*ja t|sop-? i^-
183-3-10 DDX10 '
183-3-1E
183-3^f-lE D ^'^S^ST «c
183-3-2B
183-3-28 D
183-3-20
183-3-2D D
                                                       (0(1/97
L
                                                             324
-------
Loc.       Sample ID        Weight      Dilution
CA
J*T
55
56"
57
58
59
60
61
62
63

64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
8?
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
, *7 ^ . r^ 1 & C^ O 1 1. £) / C*™^
CCoZ ^fS»/T"7 "u^-
183-3-2E ^To^^fpT'
183-3-2E D '
183-3-3C
183-3-3C DX5
183-3-3C DDX5
183-3-3C MSX5
183-3-3C MSDX5 ^
1OTTOC . 1 _ Oil*/'? 7
lo-5~o™^r v •<• b &-V)f±\p "I***

183-3-2F D r *
CCV3=6.0ug/L 	 3-Ot$— 
-------
  Loc.        Sample ID

I 110     183-3-6B
  111     183-3-6B D
.'  112     CCV3=6.0ug/L
  113     CCB3
"  114     183-3-60
,  115     183-3-60 D
  116     183-3-6E
L 117     183-3-6E D
  118     183-3-6F
'  119     183-3-6F D
i  120     183-3-78
  121     183-3-7B D   .
'  122     183-3-7C
I  123     183-3-7C DX5
~ 124     183-3-7C 00X5
-  125     CCV4=6.0ug/L
I  126     CC84
  127     183-3-70
, .128     183-3-70 0
  129     183-3-7E
  130     133-3-7E D
  131     183-3-7E MS
'  132     1S3-3-7E MSO
L 133     183-3-7F
  134     L83-3-7F 0
•  135     183-3-8B
  136     183-3-88 0
  137     CCV5=6.0ug/L
  138     CC85
  139     183-3-8C
;  140     183-3-8C 0X5
  141     183-3-8C DDX5
'  142     183-3-80
i  143     183-3-80 D
  144     183-3-SE
.  145     183-3-8E D
  146     183-3-8F
  147     183-3-8F D
  148     CCV6-6.0ug/L_
  149     CCB6
     Weight
Dilution
To lc
                                                      326
-------
Element File: HG_.MEL
Element: Hg2
Print Data: Main+Suppl.
Print: Calib. Curve
Remarks:
 STANDARDS= 3-018-7
 QC= 3-018-8
     Analyst:  RICHARDS
     Peak Storage:  None
INSTRUMENT: 5100
Wavelength: 253.7 Peak
Signal Type: AA
Read Time: 30.0
Sample Replicates: 1
Standard Replicates: 1
     Technique:  MRS           Version: 7.01
     Slit:  0.7  Low
     Signal Measurement:  Peak Height (5)
     Read Delay: 1.0          BOC Time: 2
FLAME:
Flame Type: Air
Oxidant Flow: 10.0 L/min
     Flame Sensor:  On
     Fuel Flow:  2.0 L/min
CALIBRATION:
Solutions
Calib. Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Standard 6
Calibration
Calibration
t c TH
i o 1 U
!STD
!STD
!STD
!3TO
!STD
iSTO
Units:
Type:
ID
D 1 V
BLK
1
2
3
4
5
6
ug/L
Linear
Cone !
0.200J
0.500!
1.000!
2 . 000 !
5.000J
lo.ooo;
Sample Units:








ug/L

QC:
Matrix Check Calculations:
% Difference for Dupls: No
% Recovery for Spike: No
Locations:
Locations:
Cone:
                                                                                327
-------
  Element  File:  HG_.MEL
  Date:  09/30/97
  Data  File:  AB811.DAT
  Technique:  MHS
  Remark 1: STANDARDS= 3-018-7
  Remark 2: QC=  3-018-8
                       Element:  Hg2
                       Time:  09:27
                       ID/Wt  File: AB811.IDW
                       Calib.  Type:  Linear
                              Wavelength:  253.7
                              Slit:  0.7  L
                              Lamp Current: 0
                              Energy:  72
  Hg2
ID:  STD BLK
Seq. No.:  00003    A/S Pos.:  —    Date:  09/30/97
  Replicate   1
'  Peak  Area  (A-s):  0.002
  Blank Corrected Pk Height  (A): -0.001
  Concentration (ug/L  ):. -0.026

;  Auto-zero  performed.
                                 Time:  09:28
                                 Peak  Height  (A):  -0.001
  Hg2    ID:  STDl=0.2ug/L
                       Seq.  No.:  00004     A/S  Pos.: —    Date: 09/30/97
  Replicate  I
  Peak  Area (A-s):  0.148
  Blank Corrected Pk Height (A):  0.006
  Concentration (ug/L  ):  0.160

  standard'number 1 applied.   |'0.200]
  Correlation coefficient:  1.00000
                                 Time:  09:29
                                 Peak  Height  (A):  0.006
                                 Slope:  0.0281
  Hg2   ID:  STD2=0.5ug/L
                       Seq.  No.:  00005
                   A/S Pos.:  —
  Sample abs.  is greater than that  of  the  largest  standard.
  Replicate  1                           Time:  09:31
  Peak Area (A-s):  0.403 '               Peak  Height  (A):  0,016
•Blank Corrected Pk Height (A):  0.016
  Concentration (ug/L  ):  0.579
  Standard number 2 applied.   [0.500]
  Correlation coefficient:  0.99265
                                 Slope:  0.0320
Date: 09/30/9'
  Hg2   10:  3T03=1.0ug/L
                       Seq.  No.:  00006
                   A/S Pos.:  —
  Sample abs.  is greater than  that  of  the  largest standard.
  Replicate  1                           Time:  09:32
  Peak  Area (A-s):  0.915                Peak Height  (A): 0.037
  Blank Corrected Pk Height (A):  0.037
  Concentration (ug/L  ):  1.164
  Standard number 3 applied.   [1-000]
  Correlation coefficient:  0.99169
                                 Slope:  0.0362
Date: 09/30/97
  Hg2   ID:  STD4=2.0ug/L
                       Seq.  No.:  00007
                   A/S Pos.:  —
  Sample abs.  is greater than that  of  the  largest standard.
 "Replicate  1          .                Time: 09:33
  Peak  Area (A-s):  1.749                Peak Height  (A): 0.070
Date:  09/30/9^
                                                                          328
-------
Blank Corrected Pk Height (A):  0.070
Concentration (ug/L  ):  1.941

Standard number 4 applied.   [2.000]
Correlation coefficient: 0.99832       Slope:  0.0354
Hg2   ID: STD5=5.0ug/L       Seq.  No.:  00008    A/S  Pos.:  —    Date: 09/30/97

Sample abs. is greater than that of the largest  standard.
Replicate  1                        ••  Time: 09:35
Peak Area (A-s): 4.656                 Peak Height (A):  0.189
Blank Corrected Pk Height (A): 0.189
Concentration (ug/L  ): 5.331

Standard number 5 applied.  [5.000]
Correlation coefficient: 0.99922       Slope:  0.0373
Hg2   ID: STDfa=10.0ug/L      Seq.  No.:  00009    A/S  Pos.:  —    Date: 09/30/9^

Sample abs. is greater than that of the largest standard.
Replicate  1                           Time: 09:36
Peak Area (A-s): 9.123                 Peak Height  (A):  0.370
Blank Corrected Pk Height (A): 0.370
Concentration (ug/L  ): 9.902

Standard number 6 applied.  [10.000]
Correlation coefficient: 0.99982       Slope: 0.0371
                                                                                 329
-------
•Element File: HG_.MEL       Element: Hg2
 Date: 09/30/97              Time: 09:36
 Data File:  A8811.DAT        ID/Wt File: AB811.IDW
 Technique:  MHS              Calib. Type: Linear
 Remark 1:  STANDARDS= 3-018-7
 Remark 2:  QC= 3-018-8
Wavelength: 253.7
Slit: 0.7 L
Lamp Current:  0
Energy: 72
         Hi  Display Calibration - C:\m_USER\flfl,FILES\ELEHEHT\HG..HEL
         0.3701
                                              Linear
                                              Corn. Coef.: 8.99982
                                              Slope;  Q.Q371	
                                    Concentration
             18.
                                                                     330
-------
Element File: HG..MEL        Element:  Hg2                  Wavelength:  253.7
Date: 09/30/97               Time:  09:38                   Slit:  0.7 L
Data File: AB811.DAT         ID/Wt  File: AB811.IDW         Lamp Current:  0
Technique: MHS               Calib. Type: Linear           Energy:  72
Remark 1: STANDARDS= 3-018-7
Remark 2: QC= 3-018-8


Hg2   ID: ICV=4.0ug/L        Seq. No.: 00010    A/S Pos.: —    Date: 09/30/97

Replicate  1                           Time: 09:39
Peak Area (A-s): 3.815                 Peak Height (A): 0.157
Blank Corrected Pk Height (A): 0.157
Concentration (ug/L  ):. 4.229


Hg2   ID: ICB                Seq. No.: 00011    A/S Pos.: —    Date: 09/30/97

Replicate  1                           Time: 09:41
Peak Area (A-s): 0.015                 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L  ): 0.014


Hg2   ID: CHECK. LO           Seq. No.: 00012    A/S Pos.: --    Date: 09/30/97

Replicate  1                           Time: 09:42
Peak Area (A-s): 0.194                 Peak Height (A): 0.008
Blank Corrected Pk Height (A): 0.008
Concentration (ug/L  ): 0.208


Hg2   ID: 43159A MB3         Seq. No.: 00013    A/S Pos.: —    Date: 09/30/97

Replicate  1                           Time: 09:46
Peak Area (A-s): 0.009                 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L  ): 0.014


Hg2   ID: 43159A MB3 D       Seq. No.: 00014    A/S Pos.: —    Date: 09/30/97

Replicate  L                           Time: 09:47
Peak Area (A-s): 0.018                 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L  ): 0.038


Hg2   ID: 43159A LCS3        Seq. No.: 00015    A/S Pos.: —    Date: 09/30/9"

Replicate  f   -*.	                 Time: 09:48
Peak Area (A-s): sTzsT^—~->^_        Peak Height (A): 0.132
Blank Corrected Pk Height (A)
Concentration (ug/L  '): 3.574
Hg2   ID: 43159A LCS3
Seq. No.:  00016
Date: 09/30/97
                                                                             331
-------
 Hg2    ID:  182-30-15B  D        Seq.  No.:  00031    A/S Pos.:  —     Date:  09/30/97

Replicate   1                            Time: 10:40
 Peak  Area  ('A-s):  0.017                  Peak  Height (A):  0.001
 31ank Corrected Pk Height  (A):  0.001
 /oncentration (ug/L  ):  0.024


 ig2    ID:  182-30-15C          Seq.  No.:  00032    A/S Pos.:  --     Date:  09/30/97

 Replicate   1                            Time: 10:42
 'eak  Area  (A-s):  0.022                  Peak  Height (A):  0.001
 Jlank Corrected Pk Height  (A):  0.001
 Concentration (ug/L  ):-0.035


~Hg2    ID:  182-30-15C  D        Seq.  No.:  00033    A/S Pos.:  --     Date:  09/30/97

 leplicate   1                            Time: 10:43
 r^eak  Area  (A-s):  0.045                  Peak  Height (A):  0.002
 Blank Corrected Pk Height  (A):  0.002
 oncentration (.ug/L  ):  0.057


'"g2    ID:  CCV2=6.0ug/L        Seq.  No.:  00034    A/S Pos.:  —     Date:  09/30/9T

"Replicate   1                            Time: 10:44
.Peak  Area  (A-s):  4.570                  Peak  Height (A):  0.191
  lank Corrected Pk Height  (A):  0.191
 Concentration (ug/L  ):  5.150


  32    ID:  CCB2               Seq.  No.:  00035    A/3 Pos.:  —     Date:  09/30/97

 •"splicate   1                            Time: 10:45
 , =ak  Area  (A-s):  0.035                  Peak  Height (A):  0.001
 Blank Corrected Pk Height  (.A):  0.001
 r.oncentration (ug/L  ):  0.038


 Hg2    ID:  43231 MB1     '     Seq.  No.:  00036    A/3 Pos.:  —     Date:  09/30/97

  ;plicate   1                            Time: 10:46
 Peak  Area  (A-s):  0.028                  Peak  Height (A):  0.001
 "lank Corrected Pk Height  (A):  0.001
  Micentration (ug/L  ):  0.030


 I |2    ID:  43231 MB1 D        Seq.  No.:  00037    A/S Pos.:  —     Date:  09/30/97

 Replicate   1                            Time: 10:47
 f :ak  Area  (A-s):  0.025                  Peak  Height (A):  0.001
 L.ank Corrected Pk Height  (A):  0.001
 Concentration (ug/L  ):  0.027
 hg2   ID:  43231 LCS1
Seq.  No.: 00038    A/S Pos.:  —    Date:  09/30/97
                                                                              332
-------
Replicate  1
Peak Area (A-s): 4.465
Blank Corrected Pk Height (A): 0.184
Concentration (ug/L  ): 4.979
                                 Time:  10:49
                                 Peak Height  (A):  0.184
Hg2   ID: 43231 LCS1 D
                       Seq. No.: 00039     A/S  Pos.: —    Date: 09/30/97
Replicate  1
Peak Area (A-s): 4.564
Blank Corrected Pk Height (A): 0.190
Concentration (ug/L  ): 5.117
                                 Time:  10:50
                                 Peak Height  (A):  0.190
Hg2   ID: 183-3-2C
                       Seq.  No.:  00040     A/S  Pos.:  —    Date: 09/30/97
Replicate  1
Peak Area (A-s): 3.332
Blank Corrected Pk Height (A): 0.140
Concentration (ug/L   ): 3.766
                                 Time:  10:51
                                 Peak Height  (A):  0.140
Hg2   ID: 183-3-2C D
                       Seq.  No.:  00041
Replicate   1
Peak Area (A-s): 3.501
Blank Corrected Pk Height (A): 0.149
Concentration (ug/L   ): 4.031
                   A/S Pos.:  —
                                 Time:  10:52
                                 Peak Height (A):  0.149
Date: 09/30/9:
Hg2    ID: 183-3-2C MS
                       Seq.  No.:  00042     A/S Pos.:  —     Date:  09/30/97
Replicate  1
Peak Area (A-s): 6.787
Blank Corrected Pk Height (A): 0.283
Concentration (ug/L   ): 7.640
                                 Time:  10:53
                                 Peak Height (A):  0.283
Hg2    ID: 183-3-2C MSD
                       Seq.  No.:  00043     A/S  Pos.:  —    Date:  09/30/9:
Replicate  1
Peak Area  (A-s): 6.895
Blank Corrected Pk Height (A): 0.292
Concentration (ug/L   ): 7.890
                                 Time:  10:54
                                 Peak Height  (A):  0.292
Hg2
ID:  183-3-1B
Seq.  No.:  00044     A/S Pos.:  —    Date:  09/30/97
Replicate  1
Peak Area (A-s): 0.076
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L   ): 0.087
                                 Time:  10:56
                                 Peak Height  (A):  0.003
Hg2    ID:  183-3-1B D
                       Seq.  No.:  00045     A/S  Pos.:  —    Date: 09/30/97
 Replicate   1
 Peak Area  (A-s): 0.072
 Blank Corrected Pk Height (A): 0.003
                                 Time:  10:57
                                 Peak Height  (A):  0.003
                                                                                       r 1
-------
  Concentration (ug/L  ): 0.079
  Hg2   ID: CCVl=6.0ug/L
                      Seq.  No.:  00046     A/S  Pos.: --     Date: 09/30/97
!  Replicate  1
  Peak Area (A-s): 4.458
  Blank Corrected Pk Height (A): 0.188
r  Concentration (ug/L  ): 5.068
                                 Time:  10:58
                                 Peak Height  (A):  0.188
  Hg2   ID: CCB1
                      Seq.  No.:  00047
  Replicate  1
  Peak Area (A-s): 0.050 •
  Blank Corrected Pk Height (A): 0.002
  Concentration (ug/L   ): 0.054
                                A/S Pos.:  --
                                 Time:  10:59
                                 Peak Height  (A):  0.002
                                   Date:  09/30/97
  Hg2    ID: 183-3-1C
                       Seq.  No.:  00048
                                A./S Pos.:  —
  Replicate   1
  Peak Area  (A-s): 0.039
  Blank Corrected Pk Height (A): 0.002
  Concentration (ug/L   ): 0.043
                                 Time:  11:01
                                 Peak Height  (A):  0.002
                                   Date:  09/30/9'
  Hg2
ID:  183-3-1C  D
             Seq.  No.: 00049
  Replicate   1
  Peak Area  (A-s): 0.030
  Blank Corrected Pk Height (A): 0.002
  Concentration  (ug/L   ): 0.043
                   A/S Pos.: --
                                 Time:  11:02
                                 Peak Height  (A):  0.00^
Date: 09/30/97
  Hg2
ID:  183-3-1D
             Seq.  No.: 00050    A/S Pos.:  —    Date:  09/30/9:
  Sample abs.  is greater than that of the largest standard.
  Replicate  1                           Time: 11:03
  Peak Area  (A-s): 48.733                Peak Height (A): 1.915
  Blank Corrected Pk Height (A): 1.915
  Concentration (ug/L   ): 51.677
  Hg2
ID:  183-3-1D
   Replicate   1
   Peak Area  (A-s): 0.089
   Blank Corrected Pk Height
   Concentration  (ug/L   ): 0
                         0.004
                  No.:  00051
                   A/S
Date:  09/30/9'
                                 Time:  11:11
                                 Peak Height  (A):  0.004
         ID:  183-3-10
Seq. No.: 00052
                                A/S Pos.:  ~
                                                         Date: 09/30/9~
  Replicate   1
 r ''eak Area  ( A-
   Jlank Corn
      ted
 0.083
Pk Height (A):  0.003
                                 Time:  11:13
                                 Peak  Height  (A):  0.003
 ^"Concentration (ug/L   ): 0.087
                                                                                334
-------
Hg2   ID: 183-3-1E
                       Seq.  No.:  00053     A/S  Pos.:  —     Date:  09/30/9'
Replicate  1
Peak Area (A-s): 0.062
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L  ): 0.076
                                 Time:  11:15
                                 Peak  Height  (A):  0.003
Hg2   ID: 183-3/-1E D
Seq.  No.: 00054
Replicate  1
Peak Area (A-s): 0.164
Blank Corrected Pk Height (A): 0.007
Concentration (ug/L   ):. 0.176
                                          A/S  Pos.:  —
                                 Time:  11:17
                                 Peak  Height  (A):  0.007
                                   Date:  09/30/97
Hd2
ID:  1S3-3-2B
Seq.  No.:  00055
Replicate   1
Peak Area (A-s): 0.066
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L   ): 0.079
                   A/S Pos.:  —
                                 Time:  11:19
                                 Peak  Height  (A):  0.003
Date:  09/30/9T
Hg2
ID: 183-3-2B D
Seq. No.: 00056
                   A/3 Pos.: —
Replicate   1
Peak Area (A-s): 0.078
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L   ): 0.087
                                 Time:  11:20
                                 Peak  Height  (A
                           0.003
Date: 09/30/9'
      ID: 183-3-2D
                       Seq.  No.:  00057
                   A/S Pos.:  —
Replicate  1
Peak Area (A-s): 0.066
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L   ): 0.070
                                 Time:  11:21
                                 Peak Height  (A):  0.003
                                   Date: 09/30/9^
Hg2   ID: 183-3-2D D
                       Seq.  No.:  00058     A/S  Pos.:  —
Replicate  1
Peak Area (A-s): 0.068
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L   ): 0.073
                                 Time:  11:23
                                 Peak Height  (A):  0.003
                                   Date:  09/30/9:
Hg2   ID: CCV2=6.0ug/L
                       Seq.  No.:  00059
Replicate  1
Peak Area (A-s): 4.952
Blank Corrected Pk Height (A): 0.207
Concentration (ug/L  ): 5.575
                   A/S Pos.:  —
                                 Time:  11:24
                                 Peak Height  (A):  0.207
                                   Date:  09/30/97
Hg2   ID: CCB2
                       Seq.  No.:  00060
                   A/S Pos.:  ™
                                   Date:  09/30/9'
                                                                               335
-------
Replicate  1
Peak  Area (A-s):  0.034
1  lanK Corrected Pk Height  (A):  0.001
u  oncentration (ug/L  .):  0.038
                                        Time: 11:26
                                        Peak Height  (A):  0.001
  g2
       ID:  183-3-2E
Seq. No.: 00061    A/S Pos.: —    Date:  09/30/91
fReplicate   1
  eak  Area  (A-s):  0.029
vlank Corrected  Pk  Height  (A):  0.002
Concentration  (ug/L  ):  0.043
                                        Time:  11:28
                                        Peak  Height (A):  0.002
 Hg2   ID: 183-3-2E D

L eplicate  1
 Peak Area (A-s):  0.432
,Rlank Corrected Pk Height (A):  0.018
  oncentration (ug/L  ):  0.474
                              Seq.  No.:  00062     A/S  Pos.:  —    Date: 09/30/97
                                        Time: 11:29
                                        Peak Height  (A):  0.018
       ID: 183-3-3C
                              Seq.  No.:  00063
                   A/S Pos.: --
 Sample abs. is greater than that of the largest  standard.
t~eplicate  1                           Time:  11:31
1  eak Area (A-s): 20.651                Peak Height (A):  0.866
"Blank Corrected Pk Height (A):  0.866
.Concentration (ug/L  ): 23.376
                Date:  09/30/9
 Hg2
       ID:  183-3-3C DX5
Seq. No.: 00064
  eplicate  1
 Peak Area (A-s): 3.156
 •"lank Corrected Pk Height (A):  0.128
  oncentration (ug/L  ):  3.449
A/S Pos.: —
                                        Time:  11:48
                                        Peak Height  (A):  0.128
Date:  09/30/9'
  32   ID: 183-3-3C /5DX5 t>     Seq.  No.:  00065     A/S Pos.:  —    Date: 09/30/9'

 Replicate  1               I0"           Time:  11:49
  =ak Area (A-s):  3.110                 Peak Height (A):  0.127
  lank Corrected Pk Height  (A):  0.127
 Concentration (ug/L  ): 3.428
 Hg2
       ID:  183-3-3C MSX5
Seq. No.: 00066    A/S Pos.: —    Date:  09/30/97
 ! splicate  1
 . ^ak Area (A-s):  4.140
 Blank Corrected Pk Height (A):  0.168
 ! sncentration (ug/L  ):  4.538
                                        Time: 11:51
                                        Peak Height  (A): 0.168
 ,u-g2   ID: 183-3-3C MSDX5

 Replicate  1
 Peak Area (A-s):  4.486
                              Seq.  No.:  00067.   A/S Pos.: —    Date: 09/30/97

                                        Time: 11:53
                                        Peak Height (A): 0.186
                                                                                336
-------
Blank Corrected Pk Height (A): 0.186
Concentration (ug/L  ): 5.011
Hg2   ID: 183-3-2F
                       Seq.  No.:  00068    A/S  Pos.: —     Date: 09/30/9:
Replicate  1
Peak Area (A-s): 0.781
Blank Corrected Pk Height (A): 0.033
Concentration (ug/L   ): 0.891
                                 Time:  11:57
                                 Peak Height  (A):  0.033
Hg2
ID: 183-3-2F D
Seq.  No.: 00069    A/S Pos.:  —     Date:  09/30/97
Replicate  1
Peak Area (A-s): 0.424
Blank Corrected Pk Height (A): 0.018
Concentration (ug/L  ): 0.479
                                 Time:  11:58
                                 Peak Height  (A):  0.018
                                                                                             r l
Hg2   ID: CCV3=6.0ug/L
                       Seq.  No.:  00070 .   A/S  Pos.: --
Replicate  1
Peak Area (A-s): 5.005
Blank Corrected Pk Height (A): 0.212
Concentration  (ug/L   ): 5.710
                                 Time:  12:00
                                 Peak Height  (A):  0.212
                                   Date:  09/30/9'
Hg2
ID: CCB3
Seq. No.: 00071    A/S Pos.:  —
Replicate   1
Peak Area  (A-s): 0.040
Blank Corrected Pk Height (A): 0.002
Concentration  (ug/L   ): 0.049
                                 Time:  12:02
                                 Peak Height (A):  0.002
                Date: 09/30/9'
Hg2
ID: 183-3-3B
Seq. No.: 00072    A/S Pos..:  —
Replicate  1
Peak Area (A-s): 0.098
Blank Corrected Pk Height (A): 0.004
Concentration  (ug/L   ): 0.106
                                 Time:  12:04
                                 Peak Height  (A):  0.004
                Date: 09/30/9^
Hg2
ID: 183-3-3B D
Seq.  No.: 00073
Replicate   1
Peak Area (A-s): 0.069
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L   ): 0.076
A/S Pos.:  —
                                 Time:  12:05
                                 Peak Height  (A):  0.003
Date: 09/30/9:
Hg2
ID: 183-3-3D
Seq.  No.: 00074    A/S Pos.:  —
Replicate   1
Peak Area  (A-s): 0.707
Blank Corrected Pk Height (A): 0.030
Concentration .(ug/L   ): 0.807
                                 Time:  12:06
                                 Peak Height  (A): 0.030
                Date:  09/30/97
                                                                              337
                                                                                       i—i
-------
  Hg2   ID:  183-3-30 D
                             Seq.  No.: 00075    A/S Pos.:  --    Date:  09/30/97
'u Replicate  1
  Peak Area (A-s): 0.715
'  Blank Corrected Pk Height (A): 0.029
L Concentration (ug/L  ): 0.788
                                       Time: 12:07
                                       Peak Height (A): 0.029
Hg2
        ID:  183-3-3E
'Seq. No.: 00076    A/S Pos.: —    Date: 09/30/97
  Replicate  1
  Peak Area (A-s): 0.161
  Blank Corrected Pk Height (A): 0.007
  Concentration (.ug/L  ):-0.187
                                       Time: 12:09
                                       Peak Height (A): 0.007
  Hg2   ID: 183-3-3E D
                             Seq. No.: 00077
                   A/S Pos.: —
Date: 09/30/9"
  Replicate  I
  Peak Area (A-s): 0.431
  .Blank Corrected Pk Height (A): 0.018
  Concentration (ug/L   ): 0.487
                                       Time: 12:10
                                       Peak Height (A): 0.018
  Hg2   ID: 183-3-3F
                             Seq. No.: 00078    A/S Pos.: --    Date:  09/30/9'
  Replicate  1
  Peak Area (A-s): 0.169
  Blank Corrected Pk Height (A): 0.007
  Concentration (ug/L   ): 0.181
                                       Time: 12:12
                                       Peak Height (A): 0.007
  Hg2   ID: 183-3-3F D
                             Seq. No..: 00079    A/S Pos.: --    Date:  09/30/97
  Replicate  i
  Peak Area (A-s): 0.351
  Blank Corrected Pk Height (A): 0.014
  Concentration (ug/L  ): 0.387
                                       Time: 12:13
                                       Peak Height (A): 0.014
  Hg2   ID: CCV4=6.0ug/L
                             Seq. No.: 00080    A/S Pos.: —    Date:  09/30/97
  Replicate  1
  Peak Area (A-s): 5.137
  Slank Corrected Pk Height (A): 0.216
  Concentration (ug/L   ): 5.818
                                       Time: 12:14
                                       Peak Height (A): 0.216
        ID: CCB4
                             Seq. No.: 00081    A/S Pos.: —
  Replicate  1
  3eak Area (A-s): 0.045
  -31ank Corrected Pk Height (A): 0.002
  Concentration (ug/L  ): 0.049
                                       Time: 12:15
                                       Peak Height (A): 0.002
                                   Date: 09/30/97  !
  Hg2   ID: 43231 MB2
 r ^
 I
                             Seq. No.: 00082    A/3 Pos.:  --    Date:  09/30/9-
                                                                                338
-------
Replicate  1
Peak Area (A-s): 0.032
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L  ): 0.035
                                       Time: 13:06
                                       Peak Height (A): 0.001
Hg2    ID: 43231 MB2 D
                             Seq. No.: 00083    A/S Pos.: —    Date: 09/30/9
Replicate   1
Peak Area  (A-s): 0.046
Blank Corrected Pk Height (A): 0.002
Concentration  (ug/L   ): 0.046
                                       Time: 13:07
                                       Peak Height (A;.- 0.002
Hg2    ID: 43231  LCS2
Replicate   1
Peak Area  (A-s): 4.566
Blank Corrected Pk  Height  (A):  0.188
.Concentration  (ug/L  ): 5.076
                             Seq. No.: 00084    A/S Pos.: —    Date: 09/30/9T

                                       Time: 13:08
                                       Peak Height (A): 0.188
Hg2   ID: 43231 LCS2 D
                        >vvHntt
                       Seq .  No.:  00085
Replicate   1
Peak  Area  (A-s): 4.726
Blank Corrected Pk  Height  (A):  0.196
Concentration  (ug/L  ): 5.280
                                                A/S Pos.: —
                                        Time: 13:09
                                        Peak Height (A): 0.196
                                                                Date: 09/30/9
Hg2
ID:  183-3-4B
                              Seq.  No.:  00086    A/3 Pos.: --
 Replicate   1
 Peak  Area  (A-s):  0.053
 Blank Corrected Pk  Height  (A):  0.002
 Concentration  (ug/L  ): 0.060
                                        Time: 13:10
                                        Peak Height (A): 0.002
                                                                Date: 09/30/97
Hg2    ID:  183-3-4B  D
                             Seq. No.: 00087    A/S Pos.: --    Date: 09/30/97
 Replicate   1
 Peak  Area  (A-s):  0.037
 Blank Corrected  Pk  Height  (A):  0.002
 Concentration  (ug/L  ): 0.049
                                       Time: 13:11
                                       Peak Height (A): 0.002
Hg2   ID: 183-3-4C
                       Seq.  No.:  00088
                                                A/S Pos.: --
 Replicate   1
 Peak  Area  (A-s):  7.193
 Blank Corrected  Pk  Height  (A):  0.293
 Concentration  (ug/L  ):  7.919
                                        Time: 13:12
                                        Peak Height (A): 0.293
                                                                Date: 09/30/97
Hg2
       ID:  183-3-4C  D
                       Seq.  No.:  00089     A/S Pos.: —    Date: 09/30/97
Replicate   1
Peak Area  (A-s):  7.081
Blank Corrected Pk Height (A): 0.296
                                        Time: 13:14
                                        Peak Height (A): 0.296
-------
L Concentration (ug/L  ): 7.987


I. Hg2   ID: 183-3-4C MSX2      Seq. No.: 00090    A/S Pos.:  —    Date:  09/30/97

I  Replicate  1                           Time: 13:23
  Peak Area (A-s): 4.143                 Peak Height (A):  0.174
1 Blank Corrected Pk Height (A): 0.174
  Concentration (ug/L  ): 4.689

L-
  Hg2   ID: 183-3-4C MSDX2     Seq. No.: 00091    A/S Pos.:  —    Date:  09/30/97

• Replicate  1                           Time: 13:24
" Peak Area (A-s): 3.969 .                Peak Height (A):  0.162
,• Blank Corrected Pk Height (A): 0.162
  Concentration (ug/L  ): 4.383


  Hg2   ID: CCVl=6.0ug/L       Seq. No.: 00092    A/S Pos.:  --    Date:  09/30/97

  Replicate  1                           Time: 13:25
 ' Peak Area (A-s): 5.289                 Peak Height (A):  0.221
 , Blank Corrected Pk Height (A): 0.221
  Concentration (ug/L  ): 5.970


 " Hg2   ID: CCB1               Seq. No.: 00093    A/S Pos.:  --    Date:  09/30/97

  Replicate  1                           Time: 13:26
 - Peak Area (A-s): 0.061                 Peak Height (A):  0.002
  Blank Corrected Pk Height (A): 0.002
  Concentration (ug/L  ): 0.065
 \.

 ' Hg2   ID: 183-3-4D           Seq. No.: 00094    A/S Pos.:  —    Date:  09/30/97

 ' Replicate  1                           Time: 13:30
 . Peak Area (A-s): 0.139                 Peak Height (A):  0.005
  31ank Corrected Pk Height (A): 0.005
  Joncentration (ug/L  ): 0.143


  1g2   ID: 183-3-4D D         Seq. No.: 00095    A/S Pos.:  --    Date:  09/30/97

 ' Replicate  1                           Time: 13:31
 i >eak Area (A-s): 0.128                 Peak Height (A):  0.005
 vBlank Corrected Pk Height (A): 0.005
 Concentration (ug/L  ): 0.141
  Hg2
ID:  183-3-4E
Seq. No.: 00096    A/S Pos,
 Replicate  1
 ^Peak Area (A-s): 0.668
 rRlank Corrected Pk Height (A): 0.027
 !  :oncentration (ug/L  ): 0.726
                                 Time:  13:32
                                 Peak Height  (A): 0.027
Date: 09/30/97
                                                                                  340
-------
Hg2   ID: 183-3-4E D
                       Seq.  No.: 00097    A/S Pos.: --    Date: 09/30/97
Replicate  1
Peak Area (A-s): 0.553
Blank Corrected Pk Height (A): 0.022
Concentration (ug/L  ): 0.601
                                 Time:  13:33
                                 Peak Height  (A): 0.022
Hg2   ID: 183-3-4F
                       Seq.  No.:  00098    A/S Pos.: —    Date: 09/30/91
Replicate  1
Peak Area (A-s): 0.093
Blank Corrected Pk Height (A): 0.004
Concentration (ug/L  ):. 0.097
                                 Time:  13:34
                                 Peak  Height  (A): 0.004
                                                                                      r '•
Hg2   ID: 183-3-4F D
                       Seq.  No.:  00099    A/S Pos.: —    Date: 09/30/9'
Replicate  1
Peak Area (A-s): 0.121
Blank Corrected Pk Height (A): 0.005
Concentration (ug/L   ): 0.125
                                 Time:  13:35
                                 Peak Height  (A): 0.005
Hg2   ID: 183-3-5B
                       Seq.  No.:  00100     A/S Pos.:—    Date: 09/30/9!
Replicate   1
Peak Area  (A-s): 0.034
Blank Corrected Pk Height (A): 0.002
Concentration  (ug/L   ): 0.043
                                 Time:  13:37
                                 Peak  Height  (A): 0.002
Hg2   ID: 183-3-5B D
                       Seq.  No.:  00101
                   A/S Pos.:  --
Replicate   1
Peak Area  (A-s): 0.042
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L   ): 0.054
                                 Time:  13:38
                                 Peak Height  (A): 0.002
Date: 09/30/9'
Hg2   ID: 183-3-5C
                       Seq.  No.:  00102    A/3 Pos.: ~    Date: 09/30/97
Replicate  1
Peak Area (A-s): 0.165
Blank Corrected Pk Height (A): 0.007
Concentration  (ug/L   ): 0.187
                                 Time:  13:39
                                 Peak Height  (A): 0.007
Hg2
ID:  183-3-5C D
Seq. No.:  00103    A/S  Pos.:  —    Date: 09/30/9'
Replicate   1
Peak Area  (A-s): 0.163
Blank Corrected Pk Height (A): 0.006
Concentration  (ug/L   ): 0.171
                                 Time:  13:40
                                 Peak Height  (A): 0.006
Hg2    ID: CCV2=6.0ug/L
                       Seq.  No.:  00104     A/S Pos.: —    Date: 09/30/97
                                                                                341
-------
 Replicate  1
 Peak Area  (A-s):  5.296
 Blank Corrected Pk  Height  (A): 0.221
 Concentration  (ug/L  ): 5.970
                                       Time: 13:41
                                       Peak Height (A): 0.221
 Hg2    ID: CCB2               Seq. No.: 00105     A/S  Pos.: —     Date: 09/30/97

, Replicate   1                           Time:  13:42
: Peak  Area (A-s):  0.042                 Peak Height  (A):  0.002
- Blank Corrected Pk  Height  (A): 0.002  ~
 Concentration  (ug/L  ):  0.043


 Hg2    ID: 183-3-5D     -     Seq. No.: 00106     A/S  Pos.: —     Date: 09/30/97

•, Replicate   1                           Time:  13:43
'Peak  Area (A-s):  0.251                 Peak Height  (A):  0.010
, Blank Corrected Pk  Height  (A): 0.010
  :oncentration  (ug/L  ):  0.268


 [' \g2    ID: 183-3-5D  D         Seq. No.: 00107     A/S  Pos.: --     Date: 09/30/9'
 i
 Replicate   i                           Time:  13:45
 '-""eak  Area (A-s):  0.267                 Peak Height  (A):  0.011
 | Uank Corrected Pk  Height  (A): 0.011
 ^Concentration  (ug/L  ):  0.290


 '.,g2    ID: 183-3-5E           Seq. No.: 00108     A/S  Pos.: —     Date: 09/30/97

  leplicate   1                           rime:  13:46
 v 'eak  Area (A-s):  0.040                 Peak Height  (A):  0.002
 Blank Corrected Pk  Height  (A): 0.002  .
 • Concentration  (ug/L  ):  0.043,


 ,Hg2    ID: 183-3-5E  D         Seq. No.: 00109     A/S  Pos.: —     Date: 09/30/97

 -.,eplicate   1                           Time:  13:47
 Peak  Area (A-s):  0.050                 Peak Height  (A):  0.002
 '  lank Corrected Pk  Height  (A): 0.002
   Dncentration  (ug/L  ):  0.062

 t ~*
 ',  g2    ID: 183-3-6C           Seq. No.: 00110     A/S  Pos.: —     Date: 09/30/97
 L
 Sample abs. is greater  than  that of the  largest  standard.             'imi'"^,«"4-v\ v.
 1  splicate   1                           Time:  13:48
 i,3ak  Area (A-s):  36.891                Peak Height  (A):  1.483
 Blank Corrected Pk  Height  (A): 1.483
 '  bncentration  (ug/L  ):  40.013
f>72   ID: 183-3-6C DX5

Keplicate  1
Peak Area (A-s): 6.469
r1
L
                               Seq. No.:  00111     A/S  Pos.: —    Date: 09/30/97

                                         Time:  13:57
                                         Peak Height (A):  0.268
                                                                                 342
-------
Blank Corrected Pk Height (A): 0.268
Concentration (ug/L  ): 7.221
Hg2
      ID: 183-3-6C
Replicate  1
Peak Area (A-s): 6.584
Blank Corrected Pk Height (A): 0.266
Concentration (ug/L  ): 7.183
Seq.  No.:  00112    A/S Pos.:  —    Date:  09/30/97
                                       Time:  13:58
                                       Peak Height (A): 0.266
Hg2
      ID: 183-3-6C MSX5
Seq. No.:  00113    A/S Pos.:  —    Date:  09/30/97
Replicate  1
Peak Area (A-s): 7.506
Blank Corrected Pk Height (A): 0.310
Concentration (ug/L  ): 8.355
                                       Time:  14:04
                                       Peak Height (A): 0.310
Hg2   ID: 183-3-6C MSDX5
                             Seq. No.:  00114    A/S Pos.: --    Date:  09/30/9:
Replicate  1
Peak Area (A-s): 7.662
Blank Corrected Pk Height (A): 0.313
Concentration (ug/L   ): 8.436
                                       Time:  14:05
                                       Peak Height (A): 0.313
Hg2    ID: 183-3-6B
                             Seq. No.:  00115
                   A/S Pos.:  —
Replicate   1
Peak Area (A-s): 0.263
Blank Corrected Pk Height (A): 0.011
Concentration (ug/L   ): 0.284
                                       Time: 14:07
                                       Peak Height (A): 0.011
Date: 09/30/9:
Hg2
      ID: 183-3-6B D
Seq. No.:  00116    A/S Pos.: --    Date:  09/30/9'
Replicate  1
Peak Area (A-s): 0.070
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L  ): 0.076
                                       Time:  14:08
                                       Peak Height (A): 0.003
Hg2    ID: CCV3=6.0ug/L
                             Seq. No.:  00117    A/S Pos.: --    Date:  09/30/97
Replicate  1
Peak Area (A-s): 5.322
Blank Corrected Pk Height (A): 0.225
Concentration (ug/L   ): 6.065
                                       Time:  14:10
                                       Peak Height (A): 0.225
Hg2
       ID: CCB3
Seq. No.:  00118    A/S Pos.: --
Replicate   1
Peak Area  (A-s): 0.046
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L   ): 0.046
                                       Time:  14:11
                                       Peak Height (A): 0.002
Date: 09/30/97
                                                                                343
-------
(.Hg2    ID:  183-3-6D            Seq.  No.:  00119    A/S Pos.:  —    Date:  09/30/97

v  Replicate   1                           Time: 14:13
  Peak Area  (A-s):  0.899                 Peak Height (A):  0.037
;• Blank Corrected Pk  Height (A):  0.037
,  Concentration (ug/L  ):  1.002


  Hg2    ID:  183-3-6D  D         Seq.  No.:  00120    A/S Pos.:  —    Date:  09/30/97

  Replicate   1                         '  Time: 14:14
'  Peak Area  (A-s):  0.895                 Peak Height (A):  0.037
1  Blank Corrected Pk  Height (A):  0.037
  Concentration (ug/L  ):. 0.994
{
\
^Hg2    ID:  183-3-6E            Seq.  No.:  00121    A/S Pos.:  —    Date:  09/30/97

  Replicate   1                           Time: 14:15
-Peak Area  (A-s):  0.612                 Peak Height (A):  0.025
  Blank Corrected Pk  Height (A):  0.025
I Concentration (ug/L  ):  0.666
i

( 'Hg2    ID:  183-3-6E  0         Seq.  No.:  00122    A/S Pos.:  —    Date:  09/30/9~

 """Replicate   1                           Time: 14:16
 , Peak Area  (A-s):  0.634                 Peak Height (A):  0.026
; Blank Corrected Pk  Height (A):  0.026
  concentration (ug/L  ):  0.707


 ^ig2    ID:  133-3-6F            Seq.  No.:  00123    A/S Pos.:  —    Date:  09/30/9"

 rReplicate   1                           Time: 14:17
 i 'eak. Area  (A-s):  0.822                 Peak Height (A):  0.034
 "Blank Corrected Pk  Height (A):  0.034
 Concentration (ug/L  ):  0.915


  Hg2    ID:  183-3-6F  D         Seq.  No.:  00124    A/S Pos.:  —    Date:  09/30/97
 ' .\
 , eplicate   1                           Time: 14:19
  Peak Area  (A-s):  0.184                 Peak Height (A):  0.008
 :"lank Corrected Pk  Height (A):  0.008
   oncentration (ug/L  ):  0.208


  f g2    ID:  183-3-76            Seq.  No.:  00125    A/S Pos.:  —    Date:  09/30/97

  Replicate   1                           Time,- 14:21
  [ eak Area  (A-s):  0.035                 Peak Height (A):  0.002
  ^Jlank Corrected Pk  Height (A):  0.002
  Concentration (ug/L  ):  0.049
  r y

  Wg2    ID:  183-3-7B  D         Seq.  No.:  00126    A/S Pos.:  —     Date:  09/30/9"

  r
  L
344
-------
 Replicate  1
-Peak Area (A-s):  0.105
 Blank Corrected Pk Height  (A):  0.004
 Concentration (ug/L  ):  0.114
          Time:  14:22
          Peak Height (A): 0.004
 Hg2   ID:  183-3-7C           Seq.  No.:  00127     A/S  Pos.:  —     Date:  09/30/97

 Sample abs.  is greater than that of the largest  standard.
 Replicate   1                           Time:  14:23
 Peak Area  (A-s):  25.807             ''"Peak Height  (A):  1.047
 Blank Corrected Pk Height (A):  1.047
 Concentration (ug/L  ): 28.255


 Hg2   ID:  183-3-7C 0X5       Seq.  No.:  00128     A/S  Pos.:  --     Date:  09/30/9

 Replicate   1                           Time:  14:39
 Peak Area  (A-s):  4.042                 Peak Height  (A):  0.167
 Blank Corrected Pk Height (A):  0.167
 Concentration (ug/L  ): 4.508


 Hg2   ID:  183-3-7C 1/0X5 D    Seq.  No.:  00129     A/S  Pos.:  —     Date:  09/30/9
                            ^•n-fWfct
 Replicate   1                           Time:  14:41
 Peak Area  (A-s):  4.452                 Peak Height  (A):  O.ISi
 Blank Corrected Pk Height (A):  0.181
 Concentration (ug/L  ): 4.895


 Hg2   ID:  CCV4=6.0ug/L       Seq.  No.:  00130     A/S  Pos.:  --     Date:  09/30/9

 Replicate   1   "                        Time:  14:43
 Peak Area  (A-s):  5.514                 Peak Height  (A):  0.235
 Blank Corrected Pk Height (A):  0.235
 Concentration (ug/L  ): 6.354


 Hg2   ID:  CC84               Seq.  No.:  00131     A/S  Pos.:  --     Date:  09/30/9

 Replicate   1                           Time:  14:44
 Peak Area  (A-s):  0.049                 Peak Height  (A):  0.002
 Blank Corrected Pk Height (A):  0.002
 Concentration (ug/L  ): 0.054


 Hg2   ID:  183-3-70           Seq.  No.:  00132     A/S  Pos.:  —     Date:  09/30/9

 Replicate   1                           Time:  14:45
 Peak Area  (A-s):  1.397                 PeaR Height  (A):  0.058
 Blank Corrected Pk Height (A):  0.058
 Concentration (ug/L  ): 1.565
 Hg2   ID: 183-3-7D D

 Replicate  1
 Peak Area (A-s): 1.336
Seq. No.:  00133    A/S Pos.:  —    Date:  09/30/97

          Time: 14:46
          Peak Height (A):  0.054
-------
L Blank  Corrected  Pk  Height (A):  0.054
  Concentration  (ug/L  ):  1.467
  Hg2    ID:  183-3-7E            Seq.  No.:  00134     A/S Pos.:  —    Date:  09/30/97
r  '
  Replicate   1                           Time:  14:47
L  Peak  Area  (A-s'):  1.157                  Peak Height (A):  0.049
,  Blank Corrected Pk  Height (A):  0.049
i  Concentration (ug/L  ):  1.316
i_                                     "' * .

'  Hg2    ID:  183-3-7E  D         Seq.  No.:  00135     A/S Pos.:  —    Date:  09/30/97

  Replicate   1           .                Time:  14:49
,-  ^eak  Area  (A-s):  1.133                  Peak Height (A):  0.047
,  31ank Corrected Pk  Height (A):  0.047
~Concentration (ug/L  ):  1.273


- rlg2    ID:  183-3-7E  MS        Seq.  No.:  00136     A/S Pos.:  --    Date:  09/30/97

'  Replicate   1                           Time:  14:50
I  >eak  Area  (A-s):  5.826                  Peak Height (A):  0.243
  Blank Corrected Pk  Height (A):  0.243
•Concentration (ug/L  ):  6.555


rHg2    ID:  183-3-7E  MSD        Seq.  No.:  00137     A/S Pos.:  —    Date:  09/30/97
/
'-replicate   1                           Time:  14:51
  Peak  Area  (A-s):  6.085                  Peak Height (A):  0.255
 f :iank Corrected Pk  Height (A):  0.255
 .Concentration ('ug/L  ):  6.874

 r •             '    ~        ~~        ~
  g2    ID:  183-3-7F            Seq.  No.:  00133     A/'S Pos.:  —    Date:  09/30/9'
 V,
 ,Replicate   1                           Time:  14:57
  eak  Area  (A-s):  0.092                  Peak Height (A):  0.004
 ^lank Corrected Pk  Height (A):  0.004
  Concentration (ug/L  ):  0.103
  ; "\

  Hg2    ID:  183-3-7F  D         Seq.  No.:  00139     A/S Pos.:  —    Date:  09/30/97

   aplicate   1                           Time:  14:58
  "Peak  Area  (A-s):  0.132                  Peak Height (A):  0.005
  (Blank Corrected Pk  Height (A):  0.005
   Dncentration (ug/L  ):  0.135
   "32   ID: 183-3-8B
Seq.  No.: 00140    A/S Pos.:  —    Date:  09/30/9:
  Replicate  1
  P-?ak Area (A-s):  0.036
  ! Lank Corrected Pk Height (A):  0.002
  concentration (ug/L  ):  0.051

  f1
  L
          Time:  14:59
          Peak Height (A):  0.002
-------
Hg2   ID: 183-3-88 D
                       Seq.  No.:  00141     A/S  Pos.:  —     Date:  09/30/97
Replicate  1
Peak Area (A-s): 0.032
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L  ): 0.043
                                 Time:  15:01
                                 Peak Height  (A):
                           0.002
Hg2   ID: CCV5=6.0ug/L
                       Seq.  No.:  00142     A/S  Pos.:  --     Date:  09/30/97
Replicate  1
Peak Area (A-s): 5.657.
Blank Corrected Pk Height (A): 0.238
Concentration (ug/L   ):. 6.414
                                 Time:  15:02
                                 Peak Height  (A):  0.238
Hg2   ID: CCB5
                       Seq.  No.:  00143    A/S  Pos.:  --
Replicate   1
Peak Area (A-s): 0.034
Blank Corrected Pk Height (A): 0.001
Concentration  (ug/L   ): 0.032
                                 Time:  15:04
                                 Peak Height  (A):  0.001
                                   Date: 09/30/9'
Hg2
ID:  183-3-8C
Seq. No.: 00144    A/S Pos.
                Date: 09/30/9
Sample abs.  is greater than that of the  largest standard.
Replicate  1                           Time: 15:06
Peak Area  (A-s):  25.797                Peak Height (A): 1.064
Blank Corrected Pk Height (A): 1.064
Concentration (ug/L   ): 28.715
Hg2
ID:  183-3-8C DX5
Seq. No.: 00145
A/S Pos,
Date: 09/30/9'
Replicate   1
Peak Area  (A-s): 2.095
Blank Corrected  Pk Height (A): O.OS6
Concentration  (ug/L   ): 2.318
                                 Time:  15:15
                                 Peak  Height  (A):  0.086
Hg2    ID:  183-3-8C 0DX5 C>    Seq. No.: 00146    A/S Pos.: —    Date: 09/30/9"

Replicate   1                           Time: 15:17
Peak Area  (A-s): 2.171                 Peak Height (A): 0.090
Blank  Corrected  Pk Height (A): 0.090
Concentration  (ug/L   ): 2.420
Hg2
ID: 183-3-80
Seq. No.: 00147   ' A/S Pos.:  ~
                Date: 09/30/9'
Replicate   1
Peak Area  (A-s):  0.939
Blank Corrected  Pk  Height (A): 0.038
Concentration  (ug/L  ): 1.037
                                 Time:  15:18
                                 Peak  Height  (A):  0.038
                                                                                                r i
-------
L
, .Hg2    ID:  183-3-8D D
                             Seq.  No.:  00148    A/S Pos.;  --     Date:  09/30/9'
  Replicate   1
  Peak  Area  (A-s):  0.959
  Blank Corrected Pk Height (A):  0.040
  Concentration (ug/L  ):  1.069
                                       Time: 15:19
                                       Peak Height (A):  0.040
  Hg2   ID:  183-3-8E
                             Seq.  No.:  00149    A/S Pos.:  —     Date:  09/30/97
  Replicate  1
  Peak  Area (A-s):  0.591
  Blank Corrected Pk Height (A):  0.024
  Concentration (ug/L  ):.0.639
                                       Time: 15:21
                                       Peak Height (A):  0.024
  Hg2   ID:  183-3-8E D
                             Seq.  No.:  00150
  Replicate  1
  Peak Area (A-s):  0.568
 .Blank Corrected Pk Height (A):  0.023
  Concentration (ug/L  ): 0.620
                   A/S Pos.:  —
                                       Time: 15:22
                                       Peak Height (A):  0.023
                Date:  09/30/9'
  Hg2   ID:  183-3-8F
                             Seq,.  No.: 00151
  Replicate  1
  -Peak Area (A-s): 0.144
  Blank Corrected Pk Height (A): 0.006
  Concentration (ug/L  ): 0.168
                   A/S Pos.:  --
                                       Time: 15:23
                                       Peak Height (A):  0.006
                Date:  09/30/9:
Hg2
        ID:  183-3-8F 0
Seq. No.: 00152
A/S Pos.:  —
'  Replicate  1
  Peak Area (A-s):  0.082
  Blank Corrected Pk Height (A):  0.004
'-Concentration (ug/L  ):  0.100
                                       Time: 15:24
                                       Peak Height (A):  0.004
Date: 09/30/97
,  Hg2   ID:  CCV6=6.0ug/L
                             Seq.  No.:  00153    A/S Pos.:  —     Date:  09/30/9
^  Sample abs.  is greater than that of the largest standard.
  Replicate  1                           Time:  15:26
'  Peak Area (A-s): 25.910                Peak Height (A):  1.066
u  'Blank Corrected Pk Height (A):  1.066
  Concentration (ug/L  ): 28.780
 -Hg2   ID:  CCV6=6.0ug/L
                             Seq.  No.:  00154
                   A/S Pos.:  —
1  Replicate  1
--Peak Area (A-s):  8.743
  Blank Corrected Pk Height (A):  0.372
['Concentration (ug/L  ): 10.047
                                       Time:  15:28
                                       Peak Height (A):  0.372
                Date:  09/30/9'
L
                                                                                  348
-------
Hg2   ID: CCB6
Seq.  No.:  00155    A/S Pos.: —    Date: 09/30/91
Replicate  1
Peak Area (A-s):  0.050
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L  ): 0.060
          Time:  15:30
          Peak Height  (A): 0.002
                                                                                  349
                                                                                           r i
-------
  ID/Weight File: A6812,IDW
r . Sample Volume: 100 mL
    LOG.
Sample  ID
                     Analyst: RICHARDS
                     Nominal Weight: 1.0 g
                                       -U
Weight
Dilution
\ x o
1 1
2
< 3
1 4
^ 5
6
| 7
I 8
9
10
11
12
r 13
14
" 15
16
r
, 17
!-- 18
19
' ' 20
21
22
r . 23
24
25
26
27
v 28
29
' ' 30
31
( 33
34
35
36
f v
37
38
39
'-' 40
41
^ 42
43
I 44
; 45
46
r 47
L' 48
49
r - 50
51
~ 52
p 53
L
STD BLK
STDl=0.2ug/L >.
STD2=0.5ug/L ^-^ O, - I
STD3=1.0ug/L / "*
ST04=2.0ug/L /
STD5=5.0ug/ /
STD6=10.0ug/L ' ~

ICV-4.0Ug/L — 	 •* ^
ECB
CHECK LO
43159A MB4
43159A MB4 D
43159A LCS4
43159A LCS4 D
182-30-7E
182-30-7E D
182-30-7E MS

182-30-7E MSD
182-30-9E
182-30-9E D -<
CCVl=6.0uq/L 	 -
CCB1
43233B MB
43233B MB D
43233 LCS
43233 LCS D
133-5-1
183-5-1 D
183-5-1 MS
183-5-1 MSD
TCLP BLK.
TCLP BLK D
CCB1
43231 MB3
43231 MB3 D
43231 LCS3

43231 LCS3 D
183-3-1D
183-3-1D D
183-3-2E
183-3-2E D
183-3-2E MS
183-3-2E MSD
(XV1 =6.0ua/L
CCB1 ~~" i~
183-3-2F
183-3-2F D
183-3-3E
183-3-3E D
183-3-3F
183-3-3F D
183-3-1EF
183-3-1EF D

                                                          •/'A?
                                                    |o/'/V7
                                                                      350
-------
Loc.        Sample ID

 54     183-3-5EF
 55     183-3-5EF D
 56     CCV2=6.0ug/L
 57     CCB2
 58     183-3-6F
 59     183-3-6F D
 60     183-3-8C
 61     183-3-8C DX2
 62     183-3-8C DOX2
 63     183-3-8D
 64     183-3-8D D
 65     183-3-8E
 66     183-3-8E 0
 67     183-3-8E MS
 68     183-3-8E MSO
 69     CCV3=6.0ug/L
 70     CC83
 71     183-3-8F
 72     183-3-8F 0
 73     CCV4=6.0ug/L
 74     CCB4
Weight
Dilution
                       "/'/V
  3-ocy-z.
                                                                     351
-------
  Element File:  HG..MEL
 .Element:  Hg2
  Print  Data: Main+Suppl.
  Print: Calib.  Curve
  Remarks:
 , STANDARDS= 3-019-1
   QC= 3-019-2
                                   Analyst: RICHARDS
                                   Peak Storage: None
  INSTRUMENT:  5100
  Wavelength:  253.7 Peak
  Signal Type: AA
  Read Time:  30.0
  Sample Replicates:  1
  Standard Replicates:  1
                                  Technique: MHS           Version:  7.01
                                  Slit:  0.7  Low
                                  Signal Measurement: Peak Height (5)
                                  Read Delay:  1.0          BOC Time: 2
' TLAME:
\  Flame Type: Air
*  Oxidant Flow:  10.0 L/min
                                   Flame  Sensor: On
                                   Fuel  Flow:  2.0  L/min
CALIBRATION:
 Solutions

Calib. Blank
Standard 1
Standard 2
Standard 3
Standard 4
                       ID
                JSTO BLK
                ISTD i
                !STD 2
                JSTD 3
                ISTD 4
    Calibration Units:  ug/L
    Calibration Type:  Linear
                                Cone
                                   0.200!
                                   0.500!
                                   1.000!
                                   2.000!
                                    Sample Units: ug/L
QC:
Matrix Check Calculations:
% Difference for Dupls: No
% Recovery for Spike: No
                                  Locations:
                                  Locations:
                                                 Cone:
 L
 L
                                                                         352
-------
Element File: HG .MEL        Element: Hg2                  Wavelength:  253.7
Date: 10/01/97  ~            Time: 09:25                   Slit: 0.7 L
Data File: AB812.DAT         ID/Wt File: AB812.IDW         Lamp Current:  0
Technique: MHS               Calib. Type: Linear           Energy: 72
Remark 1: STANDARDS= 3-019-1
Remark 2: QC= 3-019-2


Hg2   ID: STD BLK            Seq. No.: 00003    A/S Pos.: --    Date: 10/01/97
                                    \ «
Replicate  1                           Time: 09:27
Peak Area (A-s): -0.004                Peak Height (A): -0.001
Blank Corrected Pk Height (A): -0.001

Auto-zero performed.


Hg2   ID: STDl=0.2ug/L       Seq. No.: 00004    A/S Pos.: —    Date: 10/01/9"7

Replicate  1                           Time: 09:28
Peak Area (A-s): 0.162                 Peak Height (A): 0.007
Blank Corrected Pk Height (A): 0.007

Standard number 1 applied.  [0.200]
Correlation coefficient: 1.00000       Slope: 0.0331


Hg2   ID: ST02=0.5ug/L       Seq. No.: 00005    A/S Pos.: ~    Date: 10/01/97

Sample abs. is greater than that of the largest standard.
Replicate  1                           Time: 09:29
Peak Area (A-s): 0.407                 Peak Height (A): 0.017
Blank Corrected Pk Height (A): 0.017
Concentration (ug/L  ): 0.503

Standard number 2 applied.  [0.500]
Correlation coefficient: 0.99999       Slope: 0.0333


Hg2   ID: STD3=1.0ug/L       Seq. No.: 00006    A/S Pos.: —    Date: 10/01/97

Sample abs. is greater than that of the largest standard.
Replicate  1                           Time: 09:30
Peak Area (A-s): 0.854                 Peak Height (A): 0.036
Blank Corrected Pk Height (A): 0.036
Concentration (ug/L  ): 1.085

Standard number 3 applied.  [1.000]
Correlation coefficient: 0.99780       Slope: 0.0355
 Hg2    ID:  STD4=2.0ug/L
Seq.  No.:  00007    A/S Pos.:  ~    Date:  10/01/97
Sample  abs.  is greater than that of the largest standard.
Replicate   1                          Time: 09:32
Peak  Area  (A-s):  1.759                 Peak Height (A): 0.075
Blank Corrected  Pk  Height  (A): 0.075
Concentration  (ug/L  ):  2.101
-------
bcandard  number 4 applied.  [2.000]
Correlation coefficient: 0.99899
                                       Slope:  0.0369
Hg2   ID: STD5=5.0ug/
                             Seq. No.: 00008    A/S Pos.: —    Date:  10/01/97
)  ample  abs.  is  greater than that of the largest standard.
Replicate   1                          Time: 09:33
Peak  Area  (A-s):  4.364                 Peak Height (A): 0.188
!  lank Corrected Pk  Height (A): 0.188
Concentration  (ug/L  ): 5.095
  tandard  number  5  applied.  [5.000]
  orrelation coefficient: 0.99983
                                       Slope:  0.0375
y;  g2    ID:  ST06=10.0ug/L
                             Seq. No.: 00009    A/S Pos.:  —     Date: 10/01/97
.Sample  abs.  is  greater than that of the largest standard.
1  eplicate  1                          Time: 09:34
-. eak  Area (A-s):  8.781                 Peak Height (A): 0.375
 Blank Corrected Pk Height  (A): 0.375
  oncentration (ug/L  ):  10.011
 Standard number 6 applied.   [LO.OOO]
'Correlation coefficient:  0.99996
                                       Slope:  0.0375
                                                                       354
-------
Element File: HG_.MEL
Date:  10/01/97
Data File: AB812.DAT
Technique: MHS
Remark 1: STANDARDS= 3-019-1
Remark 2: QC= 3-019-2
Element: Hg2
Time:  09:35
ID/Wt  File: AB812.IDW
Calib.  Type: Linear
Wavelength:  253.7
Slit: 0.7 L
Lamp Current: 0
Energy: 72
         H| Display Calibration - C;\flfl,USER\flflJILES\ELEHEHT\HS,.HEL
         0.375n
              1.8
                                              Linear
                                              Corn. Coef.:  B.99996
                                              Slope; 0.0375	
         Concentration
             1B.B8B
                                                                 355
-------
 .Element  File:  HG_.MEL        Element:  Hg2                   Wavelength:  253.7
  ate:  10/01/97               Time:  09:37                    Slit: 0.7  L
 -~ata  File:  AB812.DAT          ID/Wt  File: AB812.IDW          Lamp Current:  0
 Technique:  MHS               Calib.  Type:  Linear            Energy:  72
 '^emark 1:  STANOARDS=  3-019-1
 ' amark 2:  QC=  3-019-2


 . g2    ID:  ICV=4.0ug/L        Seq. No.: 00010    A/S  Pos.:  —    Date: 10/01/97

 .Replicate   1                            Time:  09:37
 , 'eak  Area  (A-s):  3.529                 Peak Height  (A):  0.152
 '-lank Corrected Pk Height (A):  0.152
 Concentration  (ug/L  ):- 4.052
 \                                 «,^,«,~^<-^^,«,^.^^~^,«~~^~~~~^.~~«^~^^~~^~^~^^^,~^~~^^^,,

 ^Hg2    ID:  ICB                 Seq. No.: 00011    A/S  Pos.:  —    Date: 10/01/9~

  (eplicate   1                            Time:  09:41
 'Peak  Area  (A-s):  -0.001                Peak Height  (A):  0.000
 rBlank Corrected Pk Height (A):  0.000
  Concentration  (ug/L  ): 0.005


 ( Ig2    ID:  CHECK LO           Seq. No.: 00012    A/S  Pos.:  —    Date: 10/01/97

 Replicate   1                            Time:  09:42
 r^eak  Area  (A-s):  0.155                 Peak Height  (A):  0.006
 i Uank Corrected Pk Height (A):  0.006
 Concentration  (ug/L  ): 0.163
 ( >~~~~.._~~~~~M~~,»~~~~~M~~~~M,>,~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ra~~~~M~^~~~,.

 v.lg2    ID:  43159A MB4          Seq. No.: 00013    A/S  Pos.:  —    Date: 10/01/97

 '' teplicate   1                            Time:  09:43
 u 'eak  Area  (A-s):  -0.001                Peak Height  (A):  0.000
 ' Blank Corrected Pk Height (A):  0.000
 - Concentration  (ug/L  ): 0.003


 , Hg2    ID:  43159A MB4  D       Seq. No.: 00014    A/S  Pos.:  --    Date: 10/01/9^

 ; Replicate   1                            Time:  09:44
 Peak  Area  (A-s):  -0.004                Peak Height  (A):  -0.000
 I Slank Corrected Pk Height (A):  -0.000
; Concentration  (ug/L  ): -0.005


 I Hg2    ID:  43159A LCS4        Seq. No.: 00015    A/S  Pos.:  —    Date: 10/01/97

 Replicate   1                            Time:  09:45
( =>eak  Area  (A-s):  3.808                 Peak Height  (A):  0.164
^~3lank Corrected Pk Height (A):  0.164
 Concentration  (ug/L  ): 4.365
 ~Hg2    ID:  43159A LCS4 D
Seq. No.:  00016    A/S Pos.:  —
r
L
Date: 10/01/97

         356
-------
Hg2   ID: 183-5-1 MS
                       Seq.  No.:  00031     A/S  Pos.: —    Date: 10/01/97
Replicate  1
Peak Area (A-s): 3.985
Blank Corrected Pk Height (A): 0.174
Concentration (ug/L  ): 4.632
                                 Time:  10:10
                                 Peak  Height  (A):  0.174
Hg2   ID: 183-5-1 USD
                       Seq.  No.:  00032    A/S  Pos.: —    Date: 10/01/97
Replicate  1
Peak Area (A-s): 3.870
Blank Corrected Pk Height (A): 0.166
Concentration (ug/L  ):- 4.421
                                 Time:  10:11
                                 Peak Height  (A):  0.166
                                                                n
Hg2   ID: TCLP BLK
                       Seq.  No.:  00033    A/S  Pos.: --    Date: 10/01/97
Replicate   1
Peak Area (A-s): 0.022
Blank Corrected Pk Height (A): 0.001
Concentration  (ug/L  ): 0.029
                                 Time:  10:12
                                 Peak Height  (A):  0.001
Hg2   ID: TCLP BLK D
                       Seq.  No.:  00034    A/S  Pos.: —    Date: 10/01/97
Replicate   I
Peak Area  (A-s): 0.046
Blank Corrected Pk Height (A): 0.002
Concentration  (ug/L   ): 0.051
                                 Time:  10:13
                                 Peak Height  (A):  0.002
Hg2   ID: CCVl=6.0ug/L
                       Seq.  No.:  00035    A/S  Pos.: --    Date: 10/01/97
Replicate   1
Peak Area  (A-s): 5.244
Blank Corrected Pk Height (A): 0.227
Concentration  (ug/L  ): 6.042
                                 Time:  10:14
                                 Peak Height  (A):  0.227
Hg2
ID:  CCB1
Seq. No.: 00036    A/S Pos.:  --     Date:  10/01/97
Replicate   1
Peak Area  (A-s): 0.018
Blank Corrected Pk Height (A): 0.001
Concentration  (ug/L  ): 0.024
                                 Time:  10:15
                                 Peak  Height  (A): 0.001
Hg2
ID:  43231 MB3
Seq. No.: 00037    A/S Pos.:  —     Date:  10/01/97
Replicate   1
Peak Area  (A-s): 0.009
Blank Corrected Pk Height (A): 0.000
Concentration  (ug/L  ): 0.008
                                 Time:  10:16
                                 Peak Height  (A): 0.000
Hg2   ID: 43231 MB3 D
                       Seq.  No.:  00038     A/S Pos.: —
                                   Date:  10/01/97

                                       357
-------
t
 Replicate  1
, Peak Area (A-s): 0.008
  Jlank Corrected Pk Height (A): 0.000
-Concentration (ug/L  ): 0.011
                                Time:  10:17
                                Peak Height  (A): 0.000
L Ig2   ID: 43231 LCS3         Seq. No.: 00039    A/S Pos.: —    Date: 10/01/97

'  Replicate  1                           Time: 10:18
      Area (A-s): 3.968                 Peak Height (A): 0.174
       Corrected Pk Height (A): 0.174"
.  Concentration (ug/L   ): 4.646


  Hg2   ID: 43231 LCS3  D .      Seq. No.: 00040    A/S Pos.: —    Date: 10/01/97

_ teplicate  1                           Time: 10:19
  Peak Area (A-s): 3.809                 Peak Height (A): 0.165
; Hank Corrected Pk Height (A): 0.165
  Concentration (ug/L   ): 4.400

r
  \g2   ID: 183-3-1D           Seq. No.: 00041    A/S Pos.: ~    Date: 10/01/9^

  Replicate  1                           Time: 10:20
( >eak Area (A-s): 0.031                 Peak Height (A): 0.001
;_ 31ank Corrected Pk Height (A): 0.001
  Concentration (ug/L   ): 0.027
r >•

  Hg2   ID: 183-3-1D D         Seq. No.: 00042    A/S Pos.: —    Date: 10/01/97

  teplicate  1                           Time: 10:21
^eak Area (A-s): 0.028                 Peak Height (A): 0.001
  Blank Corrected Pk Height (A): 0.001
  Concentration (ug/L   ): 0.029
 *•                                                                      ~~~~~~~~-

 - Mg2   ID: 183-3-2E           Seq. No.: 00043    A/S Pos.: —    Date: 10/01/97

 s Replicate  1                           Time: 10:22
{ Reak Area (A-s): 0.620                 Peak Height (A): 0.026
 l Hank Corrected Pk Height (A): 0.026
 --concentration (ug/L   ): 0.698


[_ !g2   ID: 183-3-2E 0         Seq. No.: 00044    A/S Pos.: —    Date: 10/01/97

/-Replicate  1                           Time: 10:24
 ( "eak Area (A-s): 0.652                 Peak Height (A): 0.027
 'Blank Corrected Pk Height (A): 0.027
  Concentration (ug/L   ): 0.730
  Hg2
ID:  183-3-2E MS
Seq.  No.:  00045    A/S Pos.:  —     Date:  10/01/97
 Jeplicate   1
 Peak  Area  (A-s):  4.515
 ^lank Corrected  Pk  Height  (A): 0.194
                                 Time:  10:25
                                 Peak Height  (A):  0.194
                                                                        358
-------
Concentration (ug/L  ): 5.183
Hg2   ID: 183-3-2E USD
Seq. No.: 00046    A/S Pos.: —    Date:  10/01/97
Replicate  1
Peak Area (A-s): 4.456
Blank Corrected Pk Height (A): 0.190
Concentration (ug/L  ): 5.076
          Time: 10:26
          Peak Height (A): 0.190
Hg2   ID: CCVl=6.0ug/L
Seq. No.: 00047    A/S Pos.: —    Date:  10/01/97
Replicate  1
Peak Area (A-s): 5.079 .
Blank Corrected Pk Height (A): 0.219
Concentration (ug/L  ): 5.828
          Time: 10:27
          Peak Height (A): 0.219
Hg2   ID: CCB1
Seq. No.: 00048    A/S Pos.: —    Date:  10/01/9'
Replicate  1
Peak Area (A-s): 0.033
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L  ): 0.037
          Time: 10:28
          Peak Height (A): 0.001
Hg2    ID: 183-3-2F
Seq. No.: 00049
Replicate   1
Peak Area (A-s): 0.065
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L  ): 0.067
A/S Pos.: —
          Time: 10:29
          Peak Height (A): 0.003
Date:  10/01/97
Hg2   ID: 183-3-2F D
Seq. No.: 00050    A/S Pos.: —    Date:  10/01/97
Replicate  1
Peak Area (A-s): 0.055
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L  ): 0.064
          Time: 10:30
          Peak Height (A):
        0.002
Hg2    ID: 183-3-3E
Seq. No.: 00051    A/S Pos.: —    Date:  10/01/97
Replicate  1
Peak Area (A-s): 1.023
Blank Corrected Pk Height (A): 0.044
Concentration (ug/L  ): 1.174
          Time: 10:31
          Peak Height (A): 0.044
Hg2    ID: 183-3-3E D

Replicate  1
Peak Area (A-s): 1.080
Blank  Corrected Pk Height (A):
Concentration (ug/L  ): 1.217
Seq. No.: 00052    A/S Pos.: --    Date:  10/01/9'
  0.046
          Time: 10:33
          Peak Height (A): 0.046
                                                                     359
                                                                                            n
-------
.
Hg2
       ID: 183-3-3F
                              Seq. No.: 00053    A/S Pos.: —    Date:  10/01/97
 Replicate  1
 Peak Area (A-s): 0.049
 Blank Corrected Pk Height (A): 0.002
 Concentration (ug/L  ): 0.062
                                        Time: 10:34
                                        Peak Height (A): 0.002
       ID: 183-3-3F D
                              Seq. No.: 00054    A/S Pos.: —    Date: 10/01/97
, Replicate   1
• =eak Area  (A-s): 0.047
 31ank Corrected Pk Height (A): 0.002
 Concentration  (ug/L   ):. 0.053
                                        Time: 10:35
                                        Peak Height (A): 0.002
ID:  183-3-1EF
                             Seq. No.: 00055
                                                 A/S Pos.: —
  teplicate   1
"Peak Area  (A-s):  0.008
,  Blank Corrected Pk Height (A): 0.000
  Concentration  (ug/L   ): 0.008
                                        Time: 10:38
                                        Peak Height (A): 0.000
                                                                 Date: 10/01/9
ig2
ID: 183-3-1EF D
                             Seq. No.: 00056
                                                 A/S Pos.: --
  Replicate   1
r^eak  Area  (A-s):  0.023
  Uank Corrected Pk  Height (A): 0.001
""Concentration  (ug/L  ): 0.024
                                        Time: 10:39
                                        Peak Height (A): 0.001
                                                                 Date: 10/01/9
,ig2
        ID:  183-3-5EF
                              Seq. No.: 00057    A/S Pos.: —    Date: 10/01/97
; teplicate   1
:_ 'eak Area  (A-s):  0.012
  Blank Corrected Pk  Height (A): 0.000
^ Concentration  (ug/L  ): 0.011
                                         Time: 10:40
                                         Peak Height (A): 0.000
Hg2
        ID:  183-3-5EF D
                              Seq. No.: 00058    A/S Pos.: —    Date: 10/01/97
  ,
-------
Replicate  1
Peak Area (A-s): 0.016
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L  ): 0.011
                                 Time:  10:44
                                 Peak Height (A):  0.000
Hg2   ID: 183-3-6F           Seq. No.: 00061    A/S Pos.: —    Date: 10/01/97

Replicate  1                          • Time: 10:46
Peak Area (A-s): 0.023                 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001 "
Concentration (ug/L   ): 0.027


Hg2   ID: 183-3-6F D'  -      Seq. No.: 00062    A/S Pos.: —    Date: 10/01/97

Replicate  1                           Time: 10:47
Peak Area (A-s): 0.022                 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L   ): 0.024


Hg2   ID: 183-3-8C           Seq. No.: 00063    A/S Pos.: —    Date: 10/01/97

Sample abs. is greater than that of the  largest standard.            tc\«L V    Seq. No.: 00065    A/S Pos.: —    Date: 10/01/97
                           *&it-4Wte
Replicate  1                           Time: 11:01
Peak Area (A-s): 6.070                 Peak Height (A): 0.258
Blank Corrected Pk Height (A): 0.258
Concentration (ug/L   ): 6.868


Hg2   ID: 183-3-8D           Seq. No.: 00066    A/S Pos.: —    Date: 10/01/97

Replicate  1                           Time: 11:02
Peak Area (A-s): 0.886                 Peak Height (A): 0.037
Blank Corrected Pk Height (A): 0.037
Concentration (ug/L   ): 0.990
                                                                                       r ^

                                                                                       V -/
Hg2
ID: 183-3-8D D
 Replicate   1
 Peak Area (A-s):  0.856
Seq. No.: 00067    A/S Pos.: —    Date: 10/01/97

          Time: 11:04
          Peak Height (A): 0.037
-------
- 31ank Corrected  Pk Height  (A): 0.037
 Concentration  (ug/L   ): 0.974
L.
 Hg2
ID: 183-3-8E
                             Seq.  No.: 00068    A/S Pos.:  --    Date:  10/01/97
I  Replicate   1
  Peak  Area  (A-s):  0.539
,  Blank Corrected Pk  Height  (A):  0.023
j  Concentration  (ug/L  ): 0.620
                                 Time:  11:05
                                 Peak Height (A):  0.023
  Hg2    ID:  183-3-8E  D
                       Seq.  No.: 00069    A/S Pos.:  —    Date:  10/01/97
  Replicate  1
•  •Peak  Area (A-s):  0.544
\  31ank Corrected Pk  Height  (A):  0.023
"Concentration (ug/L  ):  0.615
                                 Time:  11:06
                                 Peak Height (A):  0.023
-vlg2    ID:  183-3-8E  MS
                       Seq.  No.
                                       00070
A/S Pos.: —
  Replicate  1
  >eak  Area (A-s):  4.298
  Blank Corrected Pk  Height  (A):  0.184
  Concentration (ug/L  ):  4.902
                                 Time:  11:07
                                 Peak Height (A):  0.184
Date: 10/01/9'
Hg2
        ID:  183-3-8E USD
                       Seq. No.: 00071    A/S Pos.:  —    Date:  10/01/97
  ••teplicate  1
  Peak  Area (A-s):  4.180
  Jlank Corrected Pk  Height  (A):  0.181
  '.oncentration (ug/L  ):  4.830
                                 Time:  11:08
                                 Peak Height (A):  0.181
  Ig2    ID:  CCV3=6.0ug/L
                       Seq.  No.: 00072
                                                A/S Pos.:  —
 , Replicate  1
 1 'eak  Area (A-s):  0.038
 < Jlank Corrected Pk  Height  (A):  0.002
  Concentration (ug/L  ):  0.043
                                 Time:  11:09
                                 Peak Height  (A):  0.002
                Date: 10/01/9
  Hg2    ID:  CCV3=6.0ug/L
                       Seq.  No.: 00073    A/S  Pos.:  —     Date:  10/01/97
  leplicate  1
 "~Peak  Area (A-s):  4.570
 .Blank Corrected Pk  Height  (A):  0.194
 1 oncentration (ug/L  ):  5.162
                                 Time:  11:11
                                 Peak Height  (A):  0.194
 ( ,g2    ID:  CCB3
                       Seq.  No.:  00074
                                                A/S  Pos.:  —
  Replicate  1
 r"eak  Area (A-s):  0.017
 !  lank Corrected Pk  Height  (A):  0.001
 ""Concentration (ug/L  ):  0.019
                                 Time:  11:12
                                 Peak Height  (A):  0.001
                Date: 10/01/97
                                                                          362
-------
Hg2   ID: 183-3-8F
Seq. No.: 00075    A/S Pos.: --    Date: 10/01/97
Replicate  1
Peak Area (A-s): 0.048
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L  ): 0.059
          Time: 11:13
          Peak Height (A): 0.002
Hg2   ID: 183-3-8F D
Seq. No.: 00076    A/S Pos.: —    Date: 10/01/97
Replicate  1
Peak Area (A-s): 0.103
Blank Corrected Pk Height (A): 0.004
Concentration (ug/L  ):• 0.112
          Time: 11:14
          Peak Height (A): 0.004
Hg2   ID: CCV4=6.0ug/L
Seq. No.: 00077    A/S Pos.: --    Date: 10/01/9
Replicate  1
Peak Area (A-s): 4.850
Blank Corrected Pk Height (A): 0.207
Concentration (ug/L   ): 5.507
          Time: 11:15
          Peak Height (A): 0.207

Hg2   ID: CC84
Seq. No.: 00078    A/S Pos.: —    Date: 10/Oi/?-
Replicate   1
Peak Area (ft-s): 0.01S
Blank Corrected Pk Height t'AJ: 0.001
Concentration (ug/L   ): O.Olfr
           Time:  ii:io   .
           Peak Height (A.); 0.001
-------
\ ID/Weight File: AB815.IDW
  Sample Volume:  100 mL
 •'
 i   Loc.       Sample ID

      0     STD BLK
 (     1     STDl=0.2ug/L
 I     2     STD2=0.5ug/L
      3     STD3=1.0ug/L
      4     STD4=2.0ug/L
 !     5     STD5=5.0ug/L
 ^    6     STD6=10.0ug/L
      7     ICV=4.0ug/L
 I     8     ICB
      9     CHECK
     10     43231 MB
     11     43231 MB3. D
 L   12     43231 LCS
     13     43231 LCS
 f    14     184-23-1AB
 '    15     184-23-1A6 D
     16     184-23-1AB
 ;    17     184-23-1AB HSD
     18     184-23-2AB
     19     184-23-2AB D
     20     CCVl=6.0ug/L
     21     CCB1
 |_   22     184-23-3AB
     23     184-23-3AB D
 / -   24     184-23-4AB
     25     184-23-4A8 D
     26     184-23-6AB
     27     184-23-6AB D
     28     184-23-7AB
     29     184-23-7AB D
     30     184-23-8AB
 '    31     184-23-8AB D
     32     CCV2=6.0ug/L
     33     CCB2
     34     184-23-9AB
     35     184-23-9AB D
     36     CCV3=6.0ug/L
     37     CCB3
     Analyst: RICHARDS
     Nominal Weight: 1.0 g
                  -H
Weight
Dilution
3-02,0-1    (o
       1-02,0-2^
 I
 L
                                                          364
-------
Element File: HG_.MEL
Element: Hg2
Print Data: Main+Suppl
Print: Calib. Curve
Remarks:
 STANDARDS= 3-020-1
 QC= 3-020-2
     Analyst:  RICHARDS
     Peak Storage:  None
INSTRUMENT: 5100
Wavelength: 253.7 Peak
Signal Type: AA
Read Time: 30.0
Sample Replicates: 1
Standard Replicates: 1
     Technique:  MHS           Version:  7.01
     Slit:  0.7 Low
     Signal Measurement:  Peak Height  (5)
     Read Delay:  1.0         60C  Time: 2
FLAME:
Flame Type: Air
Oxidant Flow: 10.0 L/min
     Flame Sensor:  On
     Fuel Flow:  2.0 L/min
CALIBRATION:
Solutions
ft « 1 -i W Q 1 -?a « L/
(-.aiiD, clank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Standard 6
Calibration
Calibration
i
•
i
i
i oxr**
i b 1 U
ISTD
ISTD
ISTD
!STD
;STD
ISTD
Units
Type:
ID
D 1 I/
fcjLK
1
2
w
4
5
6
: ug/L
Linear
Cone I
i
_ _ _ i
i
0.2001
o.sooi
1.000!
2.000J
5.000J
10.000!
Sample Units:









ug/-L

QC:
Matrix Check Calculations:
% Difference for Dupls: No
% Recovery for Spike: No
Locations:
Locations:
Cone:
                                                        365
-------
'Element File:  HG_.MEL        Element: Hg2                  Wavelength: 253.7
,-Oate:  10/06/97               Time: 12:47                   Slit: 0.7 L
< fata File:  AB815.DAT         ID/Wt File: AB815.IDW         Lamp Current: O
-technique: 'MHS               Calib. Type: Linear           Energy: 71
 Remark 1: STANDARDS= 3-020-1
( '.emark 2: QC=  3-020-2


f'1g2   ID: STD BLK            Seq. No.: 00003    A/S Pos. :  —    Date: 10/06/97

 Replicate  1                           Time: 12:48
, Peak Area (A-s): -0.000                Peak Height (A): 0.000
I  lank Corrected Pk Height (A): 0.000
 Concentration (ug/L  ): 0.003

! iuto-zero performed.
i

f'g2   ID: STDl=0.2ug/L       Seq. No.: 00004    A/S Pos.:  --    Date: 10/06/97

""Replicate  1                           Time: 12:49
;Peak Area (A-s): 0.123                 Peak Height (A): 0.005
I  lank Corrected Pk Height (A): O.OO5
 Concentration (ug/L  ): 0.121

i ;tandard number 1 applied.  [0.200]
L orrelation coefficient: l.OOOOO       Slope: 0.0231

 ~-,.        ,~.
'  g2   ID: STD2=0.5ug/L       Seq. No.: 00005    A/S Pos.:  --    Date: 10/06/97
i.

Cample abs. is greater than that of  the  largest standard.
\  eplicate  1                           Time: 12:51
^,-eak Area (A-s): 0.335                 Peak Height (A): O.013
 Blank Corrected Pk Height (A): 0.013
'  oncentration (ug/L  ): 0.565

 Standard number 2 applied.  [O.500]
/Correlation coefficient: 0.99473       Slope: 0.0257


,Hg2   ID: STD3=1.0ug/L       Seq. No.: 00006    A/S Pos.:  --    Date: 10/O6/97

 Cample abs. is greater than that of the largest standard.
 Replicate  1                           Time: 12:52
  eak Area (A-s): 0.708                 Peak Height (A): 0.028
,_ lank Corrected Pk Height (A): 0.028
 Concentration (ug/L  ): 1.073

;  tandard number 3 applied.  [1.000]-
"Correlation coefficient: 0.99763       Slope: 0.0272
^         ~        ,         .,    ~,  ..   ,      ,~~~~    ,~~,      .  ,  .      ,  ,«,«.  ,  _,

v,g2   ID: STD4=2.0ug/L       Seq.  No.: 00007    A/S Pos.: --    Date: 10/06/97

I ample abs. is greater than that of the largest standard.
|_eplicate  1                           Time: 12:53
 Peak Area (A-s): 1.570                 Peak Height (A): 0.063
                                                           366
-------
'Blank Corrected  Pk  Height  (A):  0.063
 Concentration (ug/L  ):  2.321
                                                                              r i
 Standard number  4 applied.   [2.00O]
 Correlation coefficient: 0.99425       Slope:  0.0306

 ~~~^^~~~~~~~~~~~~^^^^~^^~~~~~~~~~~~~~~~~~~~~~^~^~^^^^~~~~^~^~~^~,v,~~~~~~~~~~~~..' ~\

 Hg2   ID:  STD5=5.0ug/L      Seq.  No.:  00008    A/S Pos.:  —     Date:  10/06/9V

 Sample abs.  is greater than that of  the largest  standard.                     f'
 Replicate  1                  -.-.       Time: 12:54                            ^_
 Peak Area (A-s): 4.273                 Peak Height  (A):  0.179
 Blank Corrected  Pk  Height  (A):  0.179                                          n
 Concentration (ug/L  ):  5.851
                                                                              V j

 Standard number  5 applied.   [5.000]                                            ^
 Correlation coefficient: 0.99610       Slope:  0.0350
 Hg2   ID:  STD6=10.Oug/L      Seq.  No.:  00009    A/S  Pos.:  --     Date:  10/O6/9"
                                                                              \
 Sample abs.  is greater than that of  the largest standard.
 Replicate   1                           Time: 12:55
 Peak Area  (A-s):  8.685                 Peak Height  (A):  0.365
 Blank Corrected Pk Height (A):  0.365
 Concentration (ug/L  ): 10.425

 Standard number 6 applied.   [10.0OO]
 Correlation coefficient:  0.99891       Slope:  0.0362
                                                         367
-------
  Element  File: HG_.MEL
,-Date:  10/06/97
I  Data  File:  AB815.DAT
^-Technique:  MHS
  Remark 1: STANDARDS= 3-020-1
1  Remark 2: QC= 3-020-2
                  Element: Hg2
                  Time: 12:56
                  ID/Wt File: AB815.IDW
                  Calib. Type: Linear
Wavelength: 253.7
Slit: 0.7 L
Lamp Current: 0
Energy: 71
r-
         H
Display Calibration - C; WjSER\flflJ I LES\ELEHEHT\HG..HEL
          0.365-
                                           Lineap
                                           COPP.  Coef.:  B.99B91
                                           Slope: 0.0362
                                 Concentration
                                                 18.
                                                         368
-------
Element  File:  HG_.MEL
Date:  10/06/97
Data  File: AB815.DAT
Technique: MHS
Remark 1: STANDARDS= 3-020-1
Remark 2: QC=  3-020-2
                       Element: Hg2
                       Time:  12:57
                       ID/Wt  File: AB815.IDW
                       Calib.  Type: Linear
                              Wavelength:  253.7
                              Slit:  0.7 L
                              Lamp Current:  0
                              Energy:  71
Hg2    ID:  ICV=4.0ug/L
                       Seq.  No.:  00010    A/S  Pos.:  --    Date:  10/06/9^
Replicate   1
Peak Area  (A-s):  3.724
Blank Corrected  Pk Height (A): 0.158
Concentration  (ug/L   ): 4.374
                                 Time:  12:58
                                 Peak Height  (A):  0.158
Hg2
ID: ICB
Seq. No.: 00011
                                          A/S  Pos,
                                                         Date:  10/06/9'
Replicate   1
Peak Area  (A-s):  0.008
Blank  Corrected  Pk  Height  (A): O.OOO
Concentration  (ug/L  ): 0.011
Hg2
ID: CHECK LO
     Nc
Replicate   i
Peak Area  (A-s):  0.093
Blank  Corrected  Pk  Height  (A): 0.004
Concentration  (ug/L  ): O.O97
                                 Time:  13:00
                                 Peak Height  (A): 0.000
                                 000.12    A/£  Pos.:  --    Dste:  10/06/9

                                 Time: 13:02
                                 Peal*  Hei an t  f A ): 0. OO4
•Hg:
ID:  43231 MB£
                       Seq.  Nc. :  0001;
Peplicats   1
Peak Area  (A-si:  0.009
Slank  Corrected  Pk  Height  (A): O.OOO
Concentration  (ug/L  ): 0.000
                   A/S Pos.:  —
                                                         Date:  lO/06/9~
                                 Time:  13:03
                                 Peak Height  (A): 0.000
Hg2
ID:  43231 MBZ D
                       Seq.  No.:  00014
Replicate   1
Peak Area  (A-s):  0.005
Blank  Corrected  Pk  Height (A): O.OOO
Concentration  (ug/L  ): 0.006
                   A/S Pos.:  —
                                                         Date:  10/06/9"?,
                                 Time:  13:04
                                 Peak Height  (A): O.OOO
Hg2
ID:  43231 LCS
Seq. No.: 00015
 Replicate   i
 Peak Area  (A-s):  3.826
 Blank  Corrected  Pk  Height (A): O.172
 Concentration  (ug/L  ): 4.748
                                          A/S  Pos.: --
                                                         Date: 10/06/9~
                                 Time:  13:05
                                 Peak Height  (A): 0.172
Hg2
ID: 43231 LCSi D
                       Seq.  No.:  00016
                                          A/S  Pos.: --
                                   Date:  10/06/97
                                                          369
-------
I  Replicate  1
  Peak  Area (A-s):  4.141
("Blank Corrected  Pk  Height  (A): 0.178
j  Concentration  (ug/L  ):  4.928
                                         Time:  13:06
                                         Peak Height  (A): 0.178
 Hg2
        ID:  184-23-1AB
                              Seq. No.: 00017
  Replicate   1
  Peak  Area  (A-s):  4.484
v_Blank  Corrected  Pk  Height  (A):. 0.191
  Concentration  (ug/L  ):  5.269
                   A/S Pos.:  —
                                   Date: 10/06/97
                                         Time:  13:07
                                         Peak Height  (A): 0.191
  Hg2    ID:  184-23-1AB  D
                               Seq.  No.:  00018
  Replicate   1
  Peak  Area  (A-s):  4.343
  Blank Corrected  Pk  Height  (A): O.186
  Concentration  (ug/L  ):  5.153
                                                 A/S Pos.: --
                                   Date: 10/06/97
                                         Time:  13:08
                                         Peak Height  (A): 0.186
i Hg2    ID:  184-23-1AB MS
Seq. No.:  OO019
                                                  A/S  Pos. : --
                                                                  Date:  10/06/9^
  Replicate  1
  Peak  Area (A-s):  8.967
  Blank Corrected Pk Height  (A):  0.383
  Concentration (ug/L  ):  10.592
                                         Time:  13:09
                                         Peak Height  (A):  0.383
I Hg2
ID:
134
-23-1ABMSDX2
Seq.
No. :
00020
A/S
Pos . : --
Date :
10/O6/9-
  Replicate  1
  Peak  Area (A-s):  4.728
  Blank Corrected Pk Height  (A):
  Concentration (ug/L  ):  5.561
                                 0.201
                                         Time:  13:18
                                         Peak Height (A):  0.201
  Hg2
        ID:  184-23-1ABMSDX2
Seq. No.:  OO021
  Replicate  1
  Peak  Area (A-s):  4.121
  Hank Corrected Pk  Height  (A): 0.177
  Concentration (ug/L  ):  4.881
                                                 A/S Pos.: --
                                   Date: 10/O6/9T'
                                         Time:  13:19
                                         Peak Height (A): 0.177
        ID:  184-23-2AB
                               Seq.  No.:  00022
  Replicate  1
 < 'eak Area (A-s):  7.587
 i Jlank Corrected Pk Height (A):  0.33S
  Concentration (ug/L  ):  9.249
                                                 A/S Pos.: --
                                         Time:  13:21
                                         Peak Height  (A): 0.335
                                   Date: 10/06/97
 "Hg2
        ID:  184-23-2AB  D
                              Seq. No.: O0023
 \ leplicate  1
 L..>eak  Area (A-s):  7.506
  Blank Corrected Pk  Height  (A): 0.329
                   A/S Pos.:  —
                                         Time:  13:22
                                         Peak  Height  (A): 0.329
                                                          370
                                   Date: 10/06/97
-------
Concentration (ug/L  ): 9.097
Hg2   ID: CCVl=6.0ug/L
                       Seq.  No.:  00024
Replicate  1
Peak Area (A-s):  5.358
Blank Corrected Pk Height (A): 0.230
Concentration (ug/L  ): 6.357
                   A/S Pos.:  --
                                 Time:  13:22
                                 Peak Height (A):  0.230
                         Date:  10/06/9,
                                                                       r i-
Hg2
ID: CCB1
Seq.  No.:  00025    A/S Pos.:  —    Date:  10/06/97,
Replicate  1
Peak Area (A-s): 0.053
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L  ): 6.047
                                 Time:  13:23
                                 Peak Height (A):  O.002
Hgi
ID: 184-23-3AB
Seq. No.:  00026
Replicate  1
Peak Area (A-s): 5.790
Blank Corrected Pk Height (A): 0.251
Concentration (ug/L  ): 6.931
         A/S Pos.: --    Date: 10/06/9"
                                 Time:  13:24
                                 Peak Height (A):  O.251
Hg2
ID: 184-23-3AB D
Seq. No.: 00027
Replicate  1
Peak Area (A-s): 5.473
Blank Corrected Pk Height (A): 0.234
Concentration (ug/L  ): 6.479
         A/S Pos.:  --
                                 Time: 13:26
                                 Peak Height (A):  0.234
                Date: 10/06/9''
Hg2   ID: 184-23-4AB
                       Seq. No.:  00028
Replicate  1
Peak Area (A-s): 0.021
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L  ): 0.014
                   A/S Pos.:  --
                                 Time:  13:30
                                 Peak Height (A):  0.001
                         Date: !O/06/97r
Hg2
ID: 184-23-4AB D
Seq. No.
Replicate  1
Peak Area (A-s): 0.016
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L  ): 0.011
00029
A/S Pos.:  --
                                 Time:  13:31
                                 Peak Height (A):  0.000
Date: 1O/06/9?
Hg2
ID: 184-23-6AB
Seq. No.:  0003O
Replicate  1
Peak Area (A-s): O.O80
Blank Corrected Pk Height (A): O.003
Concentration (ug/L  ): 0.092
A/S Pos.: --
                                 Time:  13:32
                                 Peak Height (A):  O.OO3
                         Date: 10/06/97 r
-------
Hg2
ID:  184-23-6AB D
Seq. No.: OO031
A/S Pos.:  —
Date: 10/06/97
; splicate  1
v eak Area (A-s): 0.078
Blank Corrected Pk Height (A): 0.003
i Dncentration (ug/L  ): 0.083
                                 Time: 13:33
                                 Peak Height (A):  0.003
 '32
ID: 184-23-7AB
Seq. No.: 00032
A/S Pos.:  —
Date: 10/06/97
Replicate  1
Peak Area (A-s): 0.034
I lank Corrected Pk Height (A): 0.001
Loncentration (ug/L  ): 0.033
                                 Time: 13:34
                                 Peak Height (A):  0.001
1.32
ID: 184-23-7AB D
Seq. No.: OO033
A/S Pos.:  --
Date: 10/06/9-*
"splicate   1
I sak Area (A-s): 0.032
blank Corrected Pk Height (A): 0.002
ppncentration  (ug/L   ): 0.042
                                 Time: 13:35
                                 Peak Height (A):  0.002
Hg2   ID: 184-23-8AB
                       Seq.  No.:  OO034
[_eplicate   1
Peak Area  (A-s): 0.041
.^lank Corrected  Pk Height (A): 0,001
 oncentration  (ug/L   ): 0.036
                   A/S Pos.: --
                                 Time: 13:36
                                 Peak Height (A): 0.001
                Date: 10/06/97
      ID: 184-23-8AB D
                       Seq.  No.: 00035
                   A/S Pos.:  --
Replicate   1
| eak Area  (A-s): 0.041
 lank Corrected  Pk Height (A): 0.001
Concentration  (ug/L   ): 0.036
                                 Time: 13:37
                                 Peak Height (A): 0.001
                Date: 10/06/97
      ID: CCV2 = 6.0ug/L
                       Seq.  No.:  00036
J eplicate   1
-,-eak Area  (A-s): 5.261
Blank Corrected Pk Height (A): 0.229
[ oncentration  (ug/L   ): 6.329
                   A/S Pos.:  --
                                 Time: 13:38
                                 Peak Height (A):  0.229
                Date: 10/06/97
:"g2
ID: CCB2
Seq. No.: OO037    A/S Pos.: --
Replicate   1
Peak Area (A-s): 0.029
[  lank Corrected Pk Height (A): 0.001
Concentration  (ug/L   ): 0.025
                Date: 10/06/9:
                                 Time: 13:39
                                 Peak Height (A):  0.001
r
L.92
ID: 184-23-9AB
Seq. No.: OO038    A/S Pos.: --    Date: 10/06/97
L
                                                      372
-------
 Replicate  1
 Peak Area (A-s): 0.018
•Blank Corrected Pk Height (A): 0.000
 Concentration (ug/L  ):  O.006
                                 Time:  13:40
                                 Peak Height  (A): 0.000
 Hg2
ID:  184-23-9AB  D
Seq. No.: 00039
A/S Pos.:  --
                Date:  10/06/97
 Replicate  1
 Peak Area (A-s): 0.012
 Blank Corrected Pk Height (A): Q.OOO
 Concentration (ug/L  ): 0.003
                                 Time:  13:40
                                 Peak Height  (A): O.OOO
                                                                              n
 Hg2   ID: CCV3=6.0ug/L
                       Seq.  No.:  00040
 Replicate  1
 Peak Area (A-s): 5.205
 Blank Corrected Pk Height (A): 0.219
 Concentration (ug/L  ): 6.046
                   A/S Pos.:  --
                Date:  10/06/97-'
                                 Time:  13:41
                                 Peak Height  (A):  0.219
 Hg2
ID: CCB3
Seq. No.:  00041
 Replicate  1
 Peak Area (A-s): 0.034
 Blank Corrected Pk Height (A): O.OO2
 Concentration (ug/L  ): 0.042
A/S Pos.:  --
                Date:  10/06/9T
                                 Time:  13:42
                                 Peak Height  (A):  0.002
                                                            373
-------
i D/Weight File: A8816.IDW
-oample Volume: 100 mL
                                     Analyst: RICHARDS
                                     Nominal Weight:  1.0 g
 .  Loc,
     O
     1
     2
     3
     4
     5
     6
     7
    - a
     9
    10
    11
    12
    13
    14
    15
    16
    17
    IS
    19
    2O
    21
    22
    23
    24
    25
    26
    27
    28
    29
    3O
    31
    32
    33
    34
    35
    36
    37
    38
    39
    4O
    41
    42
    43
    44
    45
    46
    47
    48
    49
    50
    51
    52
    53
L
   Sample ID

STD BLK
STDl=0.2ug/L
                                Weight
                                   Dilution
           STD3=1.0ug/L
           STD4=2.0ug/L
           STD5=5.0ug/L
           STD6=10.0ug/L
           ICV=4.0ug/L
           ICB
           CHECK l_o£^ „.
           43231 MB4
           43231 MB^l D
           43231 LCS4
           43231.LCS4 D
 184-25-5^10^8
 1 S3- 15-10 •$.*'
' 183- 15- IF D* '«(<-/«•»
 183-15- l4c MS"1"^
 183-1 5- 11
 CCVl=6.0ug/L
 CCB1
 133-L5-1C
 183-15-10 D
 183-15-18
 183-15-18 0
 133- 15- IE
 183-15-1E D
 CCV2=6.0ug/L
 CCB2
 43271  MB!
 43271  MB1 D
 43271  LCS1
 43271  LCS1
 183-43-1AB
 183-43-1AB D
 183-43-1C
 183-43-1C D
 183-43- 1C MS
 183-43-1C MSD
 CCVl=6.0ug/L
 CCB1
 183-43-10
 183-43-1D D
 183-43-1E
 183-43-1E D
 183-43-1F
 183-43-1F D
 183-43-2AB
 183-43-2AB D
 183-43-3A8
 183-43-3AB D
 CCV2=6.0ug/L
 CCB2
                          •*•
                                                           374
-------
Loc.       Sample ID         Weight        Dilution
 54     IS3-43-2D
 55     183-43-2D D
 56     183-43-2E                  -
 57 .     183-43-2E D
 58   ^~183-43-2C
 59     183-43-2C D
 60     1S3-43-2C MS
 61     183-43-2C MSD        ...
 62     183-43-2F
 63     183-43-2F D             -^-02.0 -V- *&-  <°AA?
 64     CCV3 = 6.0ug/L	S  ^     ^         ' '
 65     CC83
 66     183-43-4BC
 67     183-43-4BC D
 68     183-43-30
 69     183-43-30*
 70     1S3-43-3E
 71     183-43-3E D
 72     183-4.3-3F
 73     133-43-3F D
 74     183-43-4A6
 75     1S3-43-4A8 D
 76     CCV4=6.0ug/L
 77     CCB4
 78     183-43-40
 79     183-43-40 D
 80     183-43-3C
 81     183-43-3C D
 82     133-43-3C MS
 83     133-43-3C MSD
 84     183-43-4E
 85     183-43-4E D
 86     L33-43-4F  •>         />•
 87     183-45-4F D i To ^ *"l »
 33     CCV5=6.0ug/L	
 89     CCB5
                                                         375
-------
  Element Fil-e:  HG_.MEL
  Element:  Hg2
  Print Data:  Main+Suppl.
  Print: Calib.  Curve
  Remarks:  .
   STANDARDS=  "3-020-3
  -QC= 3
     Analyst: RICHARDS
     Peak Storage: None
             10
f  INSTRUMENT:  5100
{_ Wavelength:  253.7 Peak
  Signal Type:  AA
r  Read Time:  3O.O
J  Sample Replicates:  1
u  Standard Replicates:  L
     Technique:  MHS           Version: 7.01
     Slit: 0.7 Low
     Signal Measurement:  Peak Height (5)
     Read Delay: 1.0          BOC Time: 2-
  FLAME:
 -Flame Type:  Air
  Oxidant Flow:  10.0 L/min
     Flame.Sensor:  On
     Fuel Flow:  2.0 L/min
  CALIBRATION:
Solutions ! ID
i
i
^ a 1 1 D . 6 JL a n K jblD 8 L ft
Standard 1 | STD 1
Standard 2 \ STD 2
Standard 3 ; STD 3
Standard 4 |STD 4
Standard 5 j STD 5
Standard 6 !STD 6
Calibration Units: ug/L
Calibration Type: Linear
Cone
— __.-._ —
0 . 200
0 . 500
1 . 000
2 . 000
5 . 000
10.000
Sample

} Units: ug/L
  1C:
 "Matrix Check  Calculations:
 <%  Difference  for  Dupls:  No
 ' ;  Recovery  for  Spike:  No
Locations:
Locations:
Cone;
  L
                                376
-------
element  File: HG_.MEL
Date:  10/08/97
Data File: AB816.DAT
Technique: MHS
Remark 1: STANDARDS- 3-020-3
Remark 2: QC= 3-020-4
                       Element:  Hg2
                       Time:  09:47
                       ID/Wt  File: AB816.IDW
                       Calib.  Type:  Linear
                              Wavelength:  253.7r,
                              Slit: 0.7  L
                              Lamp Current:  O
                              Energy:  71
Hg2
ID: Seq.  00001
Seq. No.:  00001
A/S Pos.:  --
Date: 10/08/ 7
Replicate  1
Peak Area  (A-s): -0.026
Blank Corrected Pk Height (A): -0.001
Concentration (ug/L  ): -0.061

Auto-zero  performed.
                                 Time:  09:47
                                 Peak  Height  (A):
                           -0.001
Hg2   ID: Seq. 00002
                       Seq.  No.:  00002
Replicate   1
Peak Area  (A-s): 0.036
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L  ): 0.074

Auto-zero  performed.
                   A/S Pos.:  --
                Date:  10/08/<
                                 Time:  09:49
                                 Peak Height  (A): 0.002
Hg2
ID:  STD BLK
Seq. No.:  00003
Replicate   1
Peak Area (A-s): -0.000
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L  ): -0.009

Auto-zero performed.
A/S Pos.:  --
Date: 1O/08/9
                                 Time:  09:52
                                 Peak Height  (A): -0.000
Hg2   ID: STDl=0.2ug/L
                       Seq.  No.: OO004
                   A/S  Pos.:  —
                Date:  10/08/9'
Sample abs. is greater than that of the largest standard.
Replicate  1                           Time:  09:54
Peak Area (A-s): 0.166                 Peak Height (A):  0.003
Blank Corrected Pk Height (A): 0.008
Concentration (ug/L  ): 0.330
Standard number 1 applied.   [0.200]
Correlation coefficient:  1.00000
                                Slope: 0.0381
Hg2   ID: STD2=0.5ug/L
                      Seq. No.: OOOO5    A/S PCS.: --    Date: 10/08/97rA
Replicate  1
Peak Area (A-s): -0.005
Blank Corrected Pk Height (A):  0.000
Concentration (ug/L  ): 0.000
                                Time: 09:55
                                Peak Height (A): 0.000
                                                             377
-------
  Hg2   ID: STD2=0.5ug/L
                       Seq.  No.:  00006
                   A/S Pos.:  —
                Date: 10/O8/97
  Sample abs. is greater than that of the largest standard.
  Replicate  1                           Time:  10:01
  Peak Area (A-s): 0.449                 Peak Height  (A):  0.019
  Blank Corrected Pk Height (A): 0.019
  Concentration (ug/L  ): 0.511
  Standard number 2 applied.  [0.500]
  Correlation coefficient: 0.99984
                                 Slope:  O.0388
  Hg2   ID: 3TD3=1.Oug/L
                       Seq.  No. :  00007
                   A/S Pos.:  --
  Sample abs. is greater than that of the largest standard.
  Replicate  1                           Time:  10:02
  Peak Area (A-s): 0.830                 Peak Height (A):  0.035
  Blank Corrected Pk Height (A): 0.035
  Concentration (ug/L  ): 0.912
  Standard number 3 applied.  [1-000]
, .Correlation coefficient: 0.99693
                                 Slope:  0.0362
                Date: 10/08/97
  Hg2
ID:  STD4r2.Oug/L
Seq. No.:  00008
A/S Pos.:  --
  Samole abs. is greater than that of the largest standard.
  Replicate  1                           Time:  10:03
  Peak Area (A-s): 1.682                 Peak Height  (A):  O.O72
  Blank Corrected Pk Height (A): 0.072
  Concentration (ug/L  '): 1.991
  Standard number 4 applied.   [2.00O]
- Correlation coefficient: 0.99946
                                 Slope: 0.0361
Date: 1O/08/9"
  Hg2
ID:  STD5=5.Oug/L
Seq.  No.: 00009
A/S Pos.:  --
  Sample abs. is greater than that of the largest  standard.
  Replicate  1                           Time:  10:05
  Peak Area (A-s): 4.249                 Peak Height  (A):  0.187
  Blank Corrected Pk Height (A):  0.187
  Concentration (ug/L  ): 5.171
  Standard number 5 applied.   [5.00O]
  Correlation coefficient:  0.99977
                                 Slope: 0.0371
Date: 10/08/97
  Hg2   ID:  STD6=10.Oug/L      Seq.  No.:  00010    A/S  Pos.: —

  Sample abs.  is greater than that of  the largest standard.
,  Replicate  1
:  Peak Area (A-s): 8.594
^-Blank Corrected Pk Height (A):  0.371
  Concentration (ug/L  ):  10.005
r
[_Standard number 6 applied.   [10.000]
  Correlation coefficient:  0.99995
                                 Time: 10:06
                                 Peak Height (A): 0.371
                                 Slope: 0.0371
                                                         Date: 10/08/97
                                                               378
-------
 Element File:  HG_.MEL        Element: Hg2
. Date: 10/08/97               Time: 10:06
 Data File:  A8816.DAT         ID/Wt File: AB816.IDW
 Technique:  MHS               Calib. Type: Linear
 Remark 1: STANDARDS= 3-020-3
 Remark 2: QC=  3-020-4
                    Wavelength: 253.7
                    Slit: 0.7 L
                    Lamp Current: O
                    Energy: 71
         H| Display Calibration - C:\m.USER\ftflJILES\ELEMEHT\H6_.HEL
         8.371n
            0
            *
JS5
                                          Linear
                                          Corn, Coef.:  B.99995
                                          Slope; 0.0371	
                                 Concentration
                     18.
                                                           379
-------
  Hg2    ID:  ICV=4.0ug/L
                              Seq.  No.:  00011
                   A/S Pos.:  —
                                   Date: 10/08/97
 Replicate   1
L-Peak Area  (A-s):  -3.457
 Blank Corrected  Pk Height  (A): 0.151
[ Concentration (ug/L   ): 4.078
                                        Time:  10:09
                                        Peak Height  (A):  0.151
  Hg2
       ID: ICB
Seq. No.: 00012
  Replicate  1
  Peak  Area (A-s):  0.008
  alank Corrected Pk  Height  (A):  0.000
  Concentration (ug/L  ): 0.005
                   A/S Pos.: --
                Date: 10/08/97
                                        Time:  10:10
                                        Peak Height (A):  0.000
  Hg2
       ID: CHECK LO
Seq. No,
 Replicate  1
 Peak Area (A-s):  0.173
 Blank Corrected Pk Height  (A):  0.007
 Concentration (ug./L  ):  0.200
          00013
A/S Pos.:  —
Date: 10/08/97
                                         Time:  10:12
                                         Peak Height  (A): O.OO7
 Hg2
        ID:  43231
Sea. No.: 00014
                   A/S Pos.:  --
                Date: 10/08/97
  Replicate  1
  Peak  Area (A-s):  0.014
  Blank Corrected Pk  Height  (A): 0.000
  Concentration (ug/L  ): O.OO8
                                        Time:  1O:13
                                        Peak Height  (A):  0.000
        ID:  43231  MB? D
                              Seq.  No.:  00015
 Replicate  1
 3eak Area (A-s):  0.016
 Jlank Corrected Pk Height  (A):
 Concentration (ug/L  ):  0.030
                                0.001
                   A/S Pos.:  --
                                   Date: 1O/08/97
                                        Time: 1O:14
                                        Peak Height (A): 0.001
 ~Hg2    ID:  43231  LCS/
                    •
Seq. No.: 00016    A/S Pos.:  --
                                                                Date:  1O/08/97
 j Jeplicate   1
 i-"eak  Area  (A-s): 4.642
 Blank Corrected  Pk Height (A): 0.205
 I :oncentration  (ug/L   ): 5.526
                                        Time:  10:16
                                        Peak Height  (A): 0.205
  '92
       ID:  43231  LCS4*  D
                    ^Sf \\-A-VlCC
 Replicate   1
,°eak  Area  (A-s):  4.397
i 'lank Corrected  Pk  Height (A): 0.188
^concentration (ug/L  ): 5.053
Seq. No.:  00017
                   A/S Pos.:  --
                Date:  1O/O8/97
                                        Time: 10:17
                                        Peak Height (A): 0.188
  -g2    ID:  184-2^-5^
Seq. No.: 00018
                                                A/S Pos.: --
                                   Date:  10/08/97
                                                              330
-------
-Re01"icate  1
 Peak Area (A-s):  0.024
•Blank Corrected Pk Height (A):  0.001
 Concentration (ug/L  ):  0.035
                                       Time: 10:18
                                       Peak Height (A): 0.001
Hg2
       ID:  134-22-5710AB,
                       Seq.  No.:  00019
 Replicate  1
 Peak Area (A-s):  0.019
 Blank Corrected Pk Height (A):- 0.001
 Concentration (ug/L  ):  0.022
                   A/S Pos.: —
                         Date:  10/O8/9'
                                       Time: 10:19
                                       Peak Height (A):  0.001
Hg2
       ID:  1 83 -lfc-
                       Seq.  No.:  00020
 Replicate  1
 Peak Area (A-s):  0.051
 Blank Corrected Pk Height (A):  0.002
 Concentration (ug/L  ):  0.054
                   A/S Pos.: --
                         Date:  10/08/9/-
                                       Time: 10:20
                                       Peak Height (A):  0.002
 Hg2
ID: 183-15-lK»
                             Seq. No,
 Replicate  1
 Peak Area (A-s):  0.035
 Blank Corrected Pk Height (A):  0.002
 Concentration (ug/L  ):  0.043
          OO021
         A/S Pos.:  --
                                                          Date:  10/03/97
                                       Time: 10:21
                                       Peak Height (A):  0.002
Hg2
       ID:  183-15-lV'MS
Seq. No,
 Replicate  1
 Peak Area (A-s):  4/723
 Blank Corrected.Pk Height (A):  0.217
 Concentration (ug/L  ):  5.842
00022
                                          A/S Pos.:  --
                                                          Date:  10/08/97^.
                                       Time: 10:22
                                       Peak Height (A):  0.217
 Hg2
ID: 183-15-
                    MSD
                       Seq.  No.:  OO023
 Replicate  1
 Peak Area (A-s):  4.373
 Blank Corrected Pk  Height  (A):
 Concentration (ug/L  ):  5.105
                               0.190
                   A/S Pos.:  --
                                       Time:  10:23
                                       Peak Height (A):  0.190
                         Date:  10/08/97
 Hg2
      ID: CCVl=6.0ug/L
Seq. No.: 00024
         A/S Pos.:  --
 Replicate  1
 Peak Area (A-s):  5.210
 Blank Corrected Pk  Height  (A): 0.234
 Concentration (ug/L  ):  6.298
                                       Time:  10:24
                                       Peak Height (A):  0.234
                                                          Date:  1O/08/97
 Hg2
      ID: CCB1
Seq. No.: OOO25
         A/S  Pos.:  --
 Replicate  1
 Peak  Area (A-s):  0.016
 Blank Corrected Pk  Height  (A): 0.001
                                       Time:  1O:25
                                       Peak Height (A):  0.001
                                                         Date: 1O/08/97'
                                                              381
-------
 Concentration  (ug/L   ): 0.019
r
 Hg2
       ID: 183-15-1C
Seq. No.: 00026
 Replicate   1
(Peak  Area  (A-s): 0.000
• Blank Corrected  Pk Height (A): 0.000
 Concentration  (ug/L   ): 0.005
A/S Pos.:  —
                                        Time: 10:26
                                        Peak Height (A): 0.000
Date: 10/08/97
L
 Hg2
        ID: 183-15-1C D
Seq. No.: 00027
  Replicate   1
  Peak  Area  (A-s):  0.007
  Blank Corrected  Pk" Height (A): 0.000
  Concentration  (ug/L   ): 0.008
A/S Pos.:  —
                                        Time: 10:27
                                        Peak Height (A): 0.000
Date: 10/08/97
, Hg2    ID: 183-15-1B
                              Seq. No.: 00028
^Replicate   1
  Peak  Area  (A-s):  -0.007
;  Blank Corrected  Pk Height (A): -0.000
I  Concentration  (ug/L   .) : -0.003
                   A/S Pos..: --
                Date: 1O/08/97
                                        Time: 10:23
                                        Peak Height (A): -O.OOO
  Hg2
       ID: 183-15-1B D
Seq. No.:  00029
r  Replicate   1
i  Peak  Area  (A-s):  -O.002
  Blank  Corrected  Pk Height (A): -O.OOO
  Concentration  (ug/L   ): -0.003
A/S Pos.:  --
Date: 10/08/97
                                        Time: 10:29
                                        Peak Height (A-):
                           -O.OOO
 Hg2    ID:  183-15-1E
                              Seq. No.:  00030
                   A/S Pos.:  —
                Date:  10/08/97
  Replicate   1
  Peak Area  (A-s): -0.009
i  31ank Corrected Pk Height (A): 0.000
  Concentration  (ug/L   ): 0.003
                                        Time: 10:30
                                        Peak Height (A):  O.OOO
        ID: 183-15-1E D
                              Seq.  No.:  00031
 Replicate   1
' ^eak Area  (A-s): -0.016
; Blank Corrected Pk Height (A): -0.000
 Concentration  (ug/L   ): -0.005
                   A/S Pos.:  —
                Date:  10/08/97
                                        Time: 10:31
                                        Peak Height (A)
                           -0.000
 Hg2   ID: CCV2=6.Oug/L
                              Seq.  No.:  OOO32
I  Replicate  i
Weak Area (A-s): 4.569
 Blank Corrected Pk Height (A): 0.201
{ Concentration  (ug/L  ): 5.404
                   A/S Pos.:  —
                Date:  10/08/97
                                        Time:  1O:33
                                        Peak Height (A):  0.201
                                                                382
-------
Hg2
ID: CC82
Seq. No.: 00033    A/S Pos.: --    Date:  10/08/S
Replicate  1
Peak Area (A-s): -0.006
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L  ): 0.000
                                 Time:  10:34
                                 Peak Height (A):  0.000
Hg2
ID:  43271 MB1
Seq. No.: 00034
Replicate  1
Peak Area (A-s): -0.007
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L  ): -0.003
         A/S Pos.:  --
                Date:  10/08,
                                 Time:  10:35
                                 Peak Height (A):
                           -0.000
Hgi
ID:  43271 MB1  D
Seq. No.: 00035    A/S Pos.: —    Date:  10/08/9'
Replicate  1
Peak Area (A-s): -0.014
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L  ): -0.011
                                 Time:  10:36
                                 Peak  Height (A):
                           -0.000
Hg2
ID: 43271 LCS1
 Seq. No.: 00036
Replicata  1
Peak Area (A-s): 4.426
Blank Corrected Pk Height (A): 0.192
Concentration (ug/L  ): 5.175
         A/S Pos.:  --
                                 Time:  10:37
                                 Peak  Height (A):  0.192
                Date:  10/08/
Hg2   ID: 43271 LCS1
                       Seq.  No.:  00037
Replicate  1
Peak Area (A-s): 4.192
Blank Corrected Pk Height (A): 0.182
Concentration (ug/L  ): 4.913
                   A/S Pos.:  --
                                 Time:  10:38
                                 Peak Height (A):  0.182
                         Date:  1O/Q8/9T
                                                                      r '
Hg2
ID:  183-45-1AB
Seq. No,
Replicate  1
Peak Area (A-s): 0.033
Blank Corrected Pk Height (A):  0.001
Concentration (ug/L  ):  0.035
00038
A/S Pos.:  —
                                 Time:  10:39
                                 Peak Height  (A): 0.001
Date:
Hg2
ID:  183-43-1AB  D
Seq. No.:  OO039
Replicate  1
Peak Area (A-s): 0.017
Blank Corrected Pk Height (A):  0.001
Concentration (ug/L  ):  0.030
         A/S Pos.:  --
                                 Time:  10:41
                                 Peak Height  (A): 0.001
                Date:  1O/08/9;
Hg2   ID: 183-43-1C
                       Seq. No.: 00040
                   A/S Pos.:  --
                         Date:  10/08/9:
                         38*
-------
f
  ID/Weight File: AB818.IDW
 •Sample Volume:"100 ml_
Loc.
  i
             « Sample ID
"o-
1
,2
V
4
5
6
- 7
8
9
10
11
12
13
14
15
16
17
18 '
19
20
21
22
23
24
25
26
27
28
29
3O
31
32
33
34
35
36
37
33
39
40
41
42
43
44
45
46
47
48
.49
50
51
52
53
STD BLK
STDl=0.2ug/L x.
STD2=0.5ug/L
STD3=1.0ug/L
STD4=2.0ug/L
STD5=5.0ug/L /
STD6=10.0ug/L
ICV = 4.0ug/l 	 ~-
ICB
CHECK LO *o«>y
43271 MB-f -*"***
43271 MB-k D
43271 LCSB
43271 LCSJi D
133-43-8A3
183-43-3AB D
133-43-8C
183-43-8C D
133-43-SC MS
<• 1S3-43-8C MSD
CCVl=6.0ug/L _
CC81
183-43-8D
183-43-80 D
183-43-8E
183-43-8E D
183-43-8F
183-43-8F D
183-43-9AB
183-43-9AB D
1S3-43-9C
' 183-43-9C D
CCV2-6.0ug/l 	
CC82
183-43-90
133-43-9D D
183-43-96
183-43-9E D
183-43-9F
183-43-9F D
183-43-10A8
183-43- 10AB D
183- 43 -IOC
183-43-10C D
CCV3=6.0ug/L _
CCB3
183-43- 10D
183-43-10D D
183-43-10E
183-43-10E D
183-43-10F
183-43-1QF D
183-43-11C
183-43-11C D
                                Analyst: RICHARDS
                                Nominal Weight:  1.0 g
Weight
Dilution
                                3-02,0- 7
                               •V.OT.O-
                                3-
                                                             384
-------
Loc,
Sample 'ID
Weight
Dilution
 54     1Q3-43-11C MS
 55     18*3-43-110 MSD
'56     CCV4=6.0ug/L  -
 57     CCB4
 5'3     183-43-11A6
 39,     183-43-11A8 D
 60     CCV5=6.0ug/L
 61     CC85
 62     43231 MB.
 63     43231 MB!
 64     43231
 65     43231
 66     183-3-1BC
 67     183-3-1BC D
 68     183-3-18C MS
 69     183-3-1BC MSD
 70     183-3-58C
 71     183-3-5BC D
 72     CCV6=6.0ug/L
 73     CCB6
                                                               385
-------
 Element File: HG_,MEL
 Element: Hg.2
 Print Data: Main+Suppl
 Print: Cali^. Curve
 Remarks:
 STANDARDS^ 3-020-7
 QC= 3-020-8
     Analyst: RICHARDS
     Peak Storage: None
 INSTRUMENT:  5100
 Wavelength:  253.7  Peak
 Signal  Type:" AA
 Read  Time: 30.0
 Sample  Replicates:  1
 Standard Replicates:  1
     Technique: MHS
     Slit: 0.7 Low
     Signal Measurement:
     Read Delay: 1.0
           Version: 7.01

      Peak Height (5)
           80C Time: 2
 FLAME:
 Flame  Type: Air
 Oxidant Flow:  1O.O  L/min
     Flame Sensor: On
     Fuel Flow: 2.0 L/min
'CALIBRATION:
Solutions ! ID
i
i
caiio. Blank , biD 8L!\
Standard 1 !STD 1
Standard 2 |STD 2
Standard 3 ! STD 3
Standard 4 • | STD 4
Standard 5 | STD 5
Standard 6 |STD 6
Calibration Units: ug/L
Calibration Type: Linear
Cone •
0 . 200
0 . 500
1 . 000
2 . 000
5 . 000
10.00O
Sample

i Units: ug/L
QC:
 "latrix Check Calculations:
"% Difference for  Dupls:  No
% Recovery  for  Spike:  No
Locations:
Locations:
Cone.
                          •**.
                                                                 336
•L
-------
Element File: HG_.M£L
Date:  10/10/97
Data File: AB818.DAT
Technique: ffHS
Remark 1:. STANDARDS= 3-020-7
Remark 2: QC= 3-O20-3
Element: -Hg2
Time: 13:51
ID/Wt File: AB818.IDW
Calib. Type: Linear
                    Wavelength:- 253.7
                    Slit: 0.7 L
                    Lamp Current: 0
                    Energy: 71
     . ID: STD 8LK
Seq. No.: OOOO3
Replicate  1
Peak Area (A-s): -0.004
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L.  ): -0.005

Auto-zero performed.
         A/S Pos.:  —
Date:  10/LO/9T
Time: 13:52
Peak Height (A):
                           -0.000
Hg2   ID: STDl=0.2ug/L
Seq. No.:  O0004
         A/S Pos.:  --
Replicate  L
Peak Area (A-s):  0.156
Blank Corrected Pk Height (A): 0.006
Concent-ration (ug/L  ): O.171

Standard number 1 applied.  CO.200]
Correlation coefficient: 1.00000
          Time: 13:53
          Peak Height (A): O.OO6
          Slope: 0.03
Date:  10/10/97
Hg2   ID: STD2=0.5ug/L
Seq. No.:  00005
         A/S Pos.:  --
Date:  10/10/97,,
Sample abs.  i-s greater than that of the largest standard.
Replicate  1                           Time:  13:54
Peak Area (A-s): 0.434                 Peak Height (A):  0.018
Blank Corrected Pk Height (A):  O.O18
Concentration fug/L  ):  0.566
Standard number 2 applied.   [0.500]
Correlation coefficient:  O.99467
          Slope: 0.0358

Hg2   ID: STD3=1.0ug/L
Seq.  No.:  OOOO6
         A/S Pos.:  --
Sample abs. is greater than that of the largest standard.
Replicate  1                           Time:  13:55
Peak Area (A-s): O.S53                 Peak Height (A):  0.035
Blank Corrected Pk Height (A):  0.035
Concentration (ug/L  ;.-  0.989

Standard number 3 applied.   [1.000J
Correlation coefficient:  0.99923       Slope:  0.0355
Date: 10/10/97
Hg2   ID: STD4=2.Oug/L
Seq. No.:  00007
         A/S Pos.:  —
Sample abs. is greater than that of  the largest  standard.
Replicate  1                           Time:  13:56
=eak. Area (A-s):  1.762                 Peak  Height  (A):  0.075
Date: 10/10/97  '
                                                                387
-------
     .
 Blank Corrected  Pk Height  (A):  0.075
 Concentration  (ug/L '  ): 2..100

 Standard  number  4 applied.   [2.000]
 Correlation 'coefficient: 0.99926       Slope: 0.0369
- Hg2 :.  ID:  STD5 = 5.0ug/L        Seq.  No.: 00008    A/S Pos. : —    Date: 10/10/97

f Sample  abs.  is greater  than  that of  the  largest standard,
L_ Replicate   1                  "        Time: 13:57
 Peak Area  (A-s):  4.368                 Peak Height (A): 0.187
i Blank  Corrected  Pk-Height '(A ): 0.187      .
 Concentration  (ug/L   ): 5.063

f Standard number  5 applied.   [5.000.]
I Correlation  coefficient: 0.99989       Slope: 0.0372
\.                                                              -

• Ig2    ID:  STD6=10.0ug/L       Seq.  No.: 00009    A/S Pos.: —    Date: 10/10/97
I
w
 Sample  abs.  is greater  than  that of  the  largest standard.
.' leplicate   1                          Time: 13:59
' 3eak Area  (A-s):  8.575                 Peak Height (A): 0.378
 'Blank Corrected  Pk Height (A): 0.378
 .Concentration  (ug/L   ): 10.154

 Standard number  6 applied.   [10.00O]
 Correlation  coefficient: 0.99994       Slope: 0.0377
                                                               388
-------
element File: HG_.MEL    "-   Element:  Hg2
Date: 10/10/97               Time:  13:59
Data File: A8818.0AT         ID/Wt  File: A8S18.IDW
Technique: MHS               Calib.  Type:  Linear
Remark 1: STANDARDS^ 3-020-7         .    "  -
Remark 2: QC= 3-020-8
Wavelength: 253.7 '
Slit: 0.7 L
Lamp Current: 0
Energy: 71       —r
        H| Display Calibration - C:\fiflJSER\fifiJILES\ELEMEHT\HG_.MEL
                                         Corp. Coef.: 0.99994
                                         Slope; 8,8377
                                Concentration
  1B.
                          '*.
                         .» '
                          •x
-------
 .Element File: HG_.MEL
f 5ate: 10/10/97
LJata File: AB818.DAT
 Teqbnique: MHS
("Remark 1: STANDARDS= 3-020-7
 Remark 2: QC= 3-020-8
                              Element: Hg2
                              Time: 14:01
                              ID/Wt File: A8S13.IDW
                              Calib._Type: Linear
                                                     Wavelength: 253.7
                                                     Slit:  0.7 L
                                                     Lamp Current: 0
                                                     Energy:  71
f
       ID: ICV=4.0ug/L
                            No
rReplicate  1  -
: 3eak Area (A-s): .3,624
' Jlank Corrected Pk Height (A): O.158
 Concentration (ug/L-  ): 4.204
00010    A/S Pos.:  --

Time: 14:02
Peak Height (A):  0.158
                                                                 Date: 10/10/97
 Hg:
ID: ICB
                              Seq. No.: 00011
 Replicate  1
"Peak Area (A-s): '0.023
 alank Corrected Pk Height (A): 0.001
 :oncentration (ug/L  ): 0.035
         A/S Pos.:  —
 Date:  1O/10/97
                                 Time: 14:03
                                 Peak Height (A):  0.001
!  192
ID: CHECK LO
                              Seq. No.: 00012
         A/5 Pos.:  --
 Date:  10/10/97
 Replicate  L
;^eak Area (A-s): 0.188
1  ilank Corrected Pk Height (A): 0.008
 Concentration (ug/L  ): O.200
                                 Time: 14:05
                                 Peak Height (A):  O.OOS
 .92
ID: 43271 MB3
                              Seq. No.:  00013
•  .eplicate  1
L eak Area (A-s): 0.000
 Blank Corrected Pk Height (A):  0.000
Concentration (ug/L  ):  0.000
         A/S Pos.:  --
 Date: 10/10/97
                                 Time: 14:10
                                 Peak Height (A):  0.000
       ID:  43271 MBS D
                       Seq.  No.:  00014
 .-^eplicate  1
 Peak Area (A-s): 0.010
  lank Corrected Pk Height (A):  0.000
  oncentration (ug/L  ):  0.008
                                                 A/S Pos.:  --
                         Date:  10/10/9:
                                 Time:  14:11
                                 Peak Height (A):  0.000
       ID:  43271 LCS3
                       Seq.  No-.:  00015
                                                 A/S Pos.:  --
                         Date:  10/10/97
  eplicate
  eak Area (A-s): 5.031
 Wlank Corrected Pk Height (A):  0.234
 Concentration (ug/L  ):  6.198
                                 Time;  14:12
                                 Peak Height (A):  0.234
 Hg2
ID:  43271 LCS3 D
                              Seq.  No.: 00016
         A/S Pos.:  --
 Date: 10/10/97

339
-------
 Replicate  1
 Peak Area (A-s~): 3.869
'Blank Corrected Pk-Height (A):
 Concentration (ug/L  ): 4.529
                               0.171
                                       Time: 15:04
                                       Peak Height (A):  0.171
 Hg2   ID: CCV4=6.0ug/L
                             Seq.  No.:  00061
 Replicate  1
 Peak Area (A.-s): 4.236
 Blank Corrected Pk Height (A): 0.189
 Concentration (ug/L  ): 5.024
                   A/S Pos.
                         Date: 10/10/97^
                                       Time: 15:06
                                       Peak Height
                      (A): 0.189
 Hg2
      ID: CC84
Seq. No.: 00062    A/S Pos.: --    Date: 10/10/97
 Replicate  1
 Peak Area (A-s): 0.011
 Blank Corrected Pk Height (A): 0.001
 Concentration (ug/L   ): 0.019
                                       Time: 15:07
                                       Peak Height (A):  O.OO1
 Hg2
      ID: 183-43-11AB
Seq. No.
 Replicate  1
 Peak Area (A-s): -0.004
 Blank Corrected Pk Height (A): 0,000
 Concentration (ug/L   ): 0.000
0006:
A/S Pos.:  --    Date: 10/10/97,
                                       Time:  15:03
                                       Peak Height (A):  O.OOO
 Hg;
      ID: 133-43-11AB D
Seq. No.: 00064
 Replicate   1
 Peak Area (A-s): -0.004
 Blank Corrected Pk Height (A): 0.001
 Concentration (ug/L  ): 0.016
         A/S Pos.:  --
                Date: 10/10/97
                                       Time:  15:11
                                       Peak Height (A):  0.001
 Hg2   ID: CCV5=6.0ug/L
                             Seq.  No.:  00065
Replicate  1
Peak Area (A-s):  4.880   "'.*
Blank Corrected Pk Height (A):  0.208
Concentration (ug/L  ):  5.527
                   A/S
             Pos.
                Date: 10/10/97
                                        Time: 15:12
                                        Peak Height (A):  0.208
 Hg2
      ID: CCB5
Seq. No.:  00066
 Replicate  1
 Peak Area (A-s): 0.007
 Blank Corrected Pk Height (A):
 Concentration (ug/L  ): 0.011
                               0.000
         A/S Pos.:  --
                Date: 10/10/97
                                       Time:  15:12
                                       Peak Height  (A):  O.OOO
 Hg2   ID: 43231 MB$«*».v<
-------
'f
J  .Concentration (ug/L  ):  -0,003
L
Hg
         ID: 43251 MSJ D
              1
                       Seq.  No.:  00063
   Peak Area (A-s): 0.000
   8 1 a n'k Co r r ec ted P K Height ( A ) :  0, 000
   Concentration (ug./L  ):  0.000
                   A/3 Pos.:  —
                                        Time: 15:14
                                        Peak Height (A): O.OOO
                                   Date:  10/10/97
   HQ;
ID:  43231 LCS$
Seq. No.: 00069
 f  Replicate  1
 i  Peak Area (A-s): 3..900
   Blank Corrected Pk Height (A): O.172
 C  Concentration (ug/L   ):  4.574
                   A/S Pos.: —
                                        Time: 15:15
                                        Peak Height (A): 0.172
                                                                Date: 10/10/97
Hg
         ID: 43231 LCS$ D
                       Seq.  No.:  00070
  "Replicate  1
  f Peak Area (A-s): 4.077
  i Slank Corrected Pk Height (A): 0.1S5
  - JoncentVation (ug/L  ):  4.912
                   A/S Pos.:  --
                                        Time: 15:'16
                                        Peak Height (A): 0.185
                                   Date:  10/10/97
         ID: 1S3-3-1BC
                             Seq. No,
          00071
                   A/S Pos.:  --
                                                          Date:  10/10/97
  r?eplic3te  i
  I  eak Area (A-s): 0.017
  "Blank Corrected Pk Height (A;: 0.001
   Concentration (ug/L  ):  0.013
                                        Time: 15:17
                                        Peak Height (A): 0.001
   Hg2
      ID:  183-3-1BC D
 3plicate   1
Peak Area  (A-s): 0.002
Plank Corrected Pk Height-.,
( jncentration (ug/L  ): 0.
Seq. No.: 00072
                                :  O.OOO
                   A/S Pos.:  —
                                          Time:  15:18
                                          Peak Height (A):  O.OOO
                                                          Date:  10/10/97
         ID:  183-3-1BC MS
                             Seq. No.: 00073
   RepLicate  1
   F; ,ak  Area (A-s):  4.103
   E_ ank Corrected Pk Height (A):  0.182
   Concentration (ug/L  ):  4.827
                   A/S Pos.:  —
                                       Time: 15:20
                                       Peak Height (A): 0.132
                                   Date:  10/10/97
   Hg2
      ID: 183-3-18C MSD
Seq. No.:  00074
   R  olicate  1
   pLak  Area (A-s):  3.914
   31ank Corrected Pk^Height (A):  0.174
   ^l icentration (ug/L   ):  4.619
                   A/S  Pos,
                                                         Date:  10/1O/97
                                       Time: 15:20
                                       Peak Height (A): 0.174
-------
Hg2   ID: 183-3-5BC
                       Seq.  No.:  00075
Replicate  If.
Peak^Area (A-s): 0.007
Blank'Corrected Pk Height (A):  0.000
Concentration (ug/L  ):  0.003
                   A/S Pos.:  —
                                 Time:  15:22
                                 Peak Height  (A-): 0.000
                         Date: "10/10/9"
      ID: 183-3-5BC D
                       Seq.  No.:  00076
Replicate  1
Peak Area ('A-s): 0.002
Blank Corrected Pk Height (A):  0.000
Concentration (ug/L  ):  0.005
                   A/S Pos.:  --
                                 Time:  15:22
                                 Peak Height tA): 0.000
                         Date:  10/10/S
Hg2
ID:  CCV6=6.0ug/L
Sea.  No.:  00077
         A/S Pos.:  --
                Date:  10/10/97
Replicate  1
Peak Area (A-s): 5.364
Blank Corrected Pk Height (A):  0.232
Concentration (ug/L  ):  6.150
                                 Time:  15:23
                                 Peak Height  (A): 0.232
      ID: CCB6
                       Sec
     No.
0007S
A/S Pos.:  --
Date: 10/1O/O
Replicate  1
Peak Area (A-s): 0.009
Blank Corrected Pk Height (A):  0.000
Concentration (ug/L  ):  O.OOS
                                 Time:  15:25
                                 Peak Height  (A): 0.000
                                                                             r 1
                                                               392
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-99-017A
2.
4. TITLE AND SUBTITLE
Final Report - Iron and Steel Foundries Manual Emissions Testing of Cupola Baghouse at
Waupaca Foundry in Tell City, Indiana
Volume I of II
7. AUTHOR(S)
Franklin Meadows
Daniel F. Scheffel
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
June 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-70069
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating iron and steel foundries to identify and quantify hazardous air pollutants
(HAPs) emitted from cupolas; electric arc furnaces; and pouring, cooling and shakedown operations of sand mold casting processes. The Waupaca
Foundry in Tell City, Indiana was selected by the EPA as the host facility at which to 1) characterize HAP emissions from cupolas that are controlled by
baghouses, and 2) assess baghouse performance in controlling HAP emissions from cupolas. The Waupaca Foundry was selected because EPA
deemed this facility to be representative of a large segment of the sand casting foundry industry. Waupaca Foundry operates a large cupola (SO standard
tons per hour melting capacity) that is controlled by a negative pressure baghouse. The new facility recently began production and the modern design of
the cupola baghouse was expected to be as effective as any used in this type of application.
This report presents the results of a manual emissions testing program to characterize emissions from a cupola and assess the performance of the
baghouse in controlling HAP emissions. Testing was conducted at the cupola baghouse inlet and outlet to determine air emissions of particulate
matter (PM) and metal HAPs; and at the cupola baghouse outlet to determine organic HAPs consisting of dibenzo-p-dioxins and polychlorinated
dibenzodurans (PCDDs/PCDFs), and semi-volatile organic hazardous air pollutnats (SVOHAPs). The data may be used by the EPA as potential
Maximum Achievable Control Technology (MACT) floor technology for cupolas.
During the testing program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission control system
operating parameters, and prepared Section 3.0, Process and Control Equipment operation, of this report.
This volume (Volume I) is comprised of 569 pages and consists of the report text, and Appendices: A (Raw field Data), and B (Analytical Data -
Particulate Matter and Metals).
1 7. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTIONS
Baghouse
Cupola
Dioxins/Furans
Emission Measurements
Hazardous Air Pollutants
Metals
Particulate Matter
Semi-volatile Organic Hazardous
Pollutants
18. DISTRIBUTION STATEMENT
Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
I
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group

21. NO. OF PAGES
1,066
22. PRICE
-------