JENTAL PFJOTSCTJOM AGS'MC'Y
                           Office  of  Air Proarams
             4.11  W.' Chapel  Hill  Street,  Durham,  N.C.  27701
Office of Air Programs
Bureau of Stationary Sources  Pollution  Control
Division 'of Applied Technology
Emission Testing Branch
Combustion ฃ Incineration Section
                          Test No.  71-CI-01

                           Duke Power Company
                              Pelzer, S.C.
                          .February 2-4,1971
                  Author & Project Officer:   Jerome  J.  Rom
                                   John J,,*  McGinnity,  Acting  Chief
                                   Emission Testing  Branch

                                   Roger  T. Shigehara, Chief
                                   Combustion  &  Incineration  Section

-------
                               TABLE OF CONTENTS
                                                                      Page  No.
"I.  Introduction	       2

       Figure 1 - Schematic of Sampling Points	       3

       Table I - Summary of Results & Pollutants Sampled at
                 each point 	,	       4

       Table II - Average Boiler Operation During Tests	•	       5

       Table III - Ash Analysis			       6

       Table IV - Coal Analysis...	-.;...       7

  II.   Summary of Results....	•	       8

 III.   Process Description			.......       8

  IV.   Location of .Sampling "Points". 7.".....		   - -10

   V.  "Process .Operatton'T—r. ™rr... . /. .*.	      11

 •VI.  ..Sampliftg^ami-'ATi'alytical Procedures  		  —-~:12~-.

       A.  Moisture Determination	      12
       B.  Velocity Traverse	      "13
       C.  Particulate Sampling -  APCO Train  	      14
       D.  Particulate Sampling -  ASME Train  		      17
       E.  NO., Sampling	      17
             }\                              •    ' •                            .
       F.  Orsat Sampling...	.	•	      18

  Appendix

    A.  Particulate Results & Calculations  		:.	    A 1-8
    B.  N0v Emission Data	    B 1-3
          /\
    C.  Lab  Results.,		    C 1-2
    p.  Trip Report	'	    D 1-2
    E.  Duke Power Report...."	...-.-	.		    E 1-4

-------
INTRODUCTION



A cooperative test program was conducted by Duke Power and the



Emission Testing Branch personnel at the Lee Steam Station, Duke



Power Company, located in Pelzer, S.C..  The tests were conducted



February 2-4, 1971.  The purpose of the tests was to determine



emission levels from controlled power plants to assist in estab-



lishing new Federal Source Performance Standards.             .







Measurements of total particu'Iates and NO  were made at the outlet
                                         A


of the hot side precip-itatbr-(See Figure 1) by Source Testing



Section personnel .-_us-ing-.APCO methods.  Observations of visible



emissiฃHs--jiejre--a1s6 made~by a member of the Emission Testing Itean.ch.___







Total particulates were measured by Duke Power personnel using the



ASME Power Test Code 27 method at both the inlet and outlet of the



precipitator to determine the collection efficiency of the precipitator



and to compare the outlet results with those obtained by the APCO method.







Pertinent results are listed "in Tables I thru IV.  Complete results



are listed in the Appendix of this report.          -..-.•

-------
e^lM-Ej-J^.-^—g.- . 	 "- lima***
1

Boiler



Inlet
Point
••



X.
Inlet
Point
Test
A
•
-i
•


•ป
Fest
B



Hot Side
Precip.


Outlet Test
Point A
J,




/is.
Outlet Test
Point B


f

\


                 •  .Figure 1 - Schematic of "Sampling  Points
                   and Pollutants Sampled at each Point   :
Pollutant
Particulate
         , ^_ ^----_-
Parti oil ate"""^77"—-
NO..
.0
 6
 0
Outlet
   6
   6
  14
Method
 APCO
 ASf1ฃ-
 PDS
                                      -3-

-------
                                    TABLE 1
                              SUMMARY OF RESULTS
Run Number
'Date . .
' .Stack Flow Rate - SCFM'* 'dry
% Water Vapor - % Vol .
% C02 - Vol % dry
% 02 - Vol % dry
% Excess air @ sampling point
S00 Emissions - ppm dry
c.
•NO Emissions - pprri dry
s\ . -~ "~. -" " ^"*
Pa rti cu ] n tes -~APCO~Tra i iff"
., Pro5efr..Cyjr!^"n.eT & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
Ibs./hr.
GR/SCF* dry - ASME Train
"GR/CF P Stack Conditions
Ibs./hr.
Total Catch"- APCO Train
gr /SCF *dry
gr /CF @ Stack Conditions
Ibs./hr.
1A
2/2/71
107607
6.70
15.4
3.5
19.37


278**


.1745
.0737
160.9 "
.0387
.0168
40.9

.2002
.0846
1_84.7
IB
2/2/71
106757
6.20
15.4
3.5
19.37


246**


.2556
.1114
233.8
.0771
.0335
• 67.4

.2819
.1228
257.9
2A
2/3/71
115729
5.92
15.3
3.2
17.32
'
•
251**


.1600
.0679
158.7
.0753
.0327
83.3
-
.2116
.0897
209.8
26'
2/3/71
107088
5.17
15.3
3.2
17.32


270**

^j-
.1740
.0758
159.7
.1192
.0516
108.2

.2352
.1024
21.5.9
3A
2/4/71
111477
6.49
15.3
3.3
17.98"


' 252**

	 • „
.1441
.0610
137.7
.0535
.0231
53.9

.1639
.0594
156.6
3B
2/4/71
107824
4.97
15.3
3.3
17.9iT
!
1
j
247**

I
.1675
.0725 j
i
154.7 j
.1335 I
.0573
121.2
t
.1778
i
.0769
„ ' . \
164.3
**AVerage of all  samples  taken  during  the  run.
   * 70"F-,29.92 '"Hg

-------
                                     TABLE II
                       AVERAGE BOILER OPERATION DURING TESTS
                               Run No. 1	Run No.  2       Run  No.  3

Unit Load - MH                     108   .         108.5         108
Main Steam Temperature,ฐF          949            945            940
Main Steam Pressure, PSIG     —-  1272--   '      1260            1265
Soot Blowing    .       -_^.--=^___.r- --None  •- -       None            As Normal
Energy Input"-- -T06~BTU7H[t.  "     HOI5.2         1019.9         1015,2

-------
 TABLE III
ASH ANALYSIS

-------
   TABLE IV
COAL ANALYSIS

-------
 II.  SUMMARY OF RESULTS    .                 ...                    •
     Participate results ranged from 0.14 GR/SCF to 0.26 gr/SCF  by  the
     APCO method considering the catch  in the front portion of the  train
     only (from the nozzle up to and including the filter).  ASME results
     ranged from 0.04 GR/SCF to 0.13 GR/SCF.
     NO  emissions varied from an average of 246 ppm  to 278  ppm.
       A
     Visible emissions did not exceed 10% opacity.  Soot blowing had  no
      noticeable effect on"ttfe 'opacity of the plume.          '.  .      - -
HI.  PROCESS;••QESCRi-PTtON"     ~  ..•','     "     ,. \- '       . .  ...	  --
     The tests were conducted on  the emissions from Unit #1 at  the  Lee  Steam
     Station.  Unit ;^1 has a Combustion Engineering 750,000 lbs./hr., triple
     drum, natural circulation,  tangentially fired boiler.  This boiler produces
     the steam to drive a General Electric 90 MW hydrogen  cooled turbine  -
     generator.

-------
IV.  LOCATION OF SAMPLING  POINTS.
    The  two 9' X  12'  precipitator  outlet  ducts were  divided  into  45  equal
   areas for velocity traverses  and  particulate  sampling  by  the APCO method.
   The south duct was Tabled  "A" and  the  north duct  (nearest the  river)"B'.'
   Each  duct.had 5 equally spaced  sampling  ports along  the 1Z' length.   The
   9' width was divided into  9  equal  spaces thus forming  the 45 equal areas
   (Figure 3).

                          Top  View  of  Ducts
    9'
    SSL
1 ,

A
:"-""' '"- 	 ' ' ' ' '
B
C
D
E
F
G
H
I
fff „ - „ j^y
- • -
- • ~ • • •








	 	 n
LJ
'.. 12' .. _

V







n
LJ











Li
^i
-_






4— 28 3/4 ->

n
LJ
              14 3/8"
                1
- 3
                                    Figure  3
                                       10

-------
   The sampling  ports were approximately 28 ft. from a bend  in the duct.

   The precipitator  inlet ducts were divided into 10 equal areas for  the
   purposes of velocity traverses and participate sampling by the ASHE method,
   Precipitator  outlet ducts were divided into 15 equal areas (Figure 4)
   for the ASME  sampling.
     9'
    :&.
Precipitator Outlet Ducts
'•** . - -., , j , -. , , , „, 1^' , 	 . r.. 	 . ' V 1
Sปป " 	 1 c. 	 	 	 •'" 	 	 	 Fi
A .,_
B
_1_. CT -
~- — - •T**—^-.
• -•-" - • • •"
.-_ , -.__

n
—


_TT



_ ^n

^T"
-ป>-~— .
i*^*j "**• * --
j f - 	 if M 	 M 	 ]_ 	
J— ซ,J 1 J-™J1 ta— .1 -^-J l-ป*-i.
r^_ 28 3/4"4| .-...- 	 	
1 2 3 45
Figure 4 • "• ' ;:V"'. ' •-'•; -: '•<-". '•
    All  NO.  samples  were  taken  thru  port  #3  in  both  ducts  except  the samples
    for  run  number  2 at duct  B  which were taken thru  port  #4.
V.  PROCESS  OPERATION     .       -.'  ,   '  '  ' . ".'     ''-''••. v     /.', .^--      ':'.'.
    Pulverized  coal  is  tangentially  fired  into  a  triple  drum boiler  to
                    f                                 •
    producer steam.  The steam  produced  is  used  to drive  a  90 MW turbine-       )
    generator.   Normally the unit is operated so  as  to  produce  about 110 MW
    of electricity,  burning approximately  40 tons of pulverized coal  per hour.
                                    . 11

-------
     The gaseous emissions from the boiler are directed through a hot side
     precipitator to control participate emissions.  From the precipitator
     the gases exit through a stack.

     Soot is removed from the system by blowing steam when and where needed.

     Process operation was as normal during Runs Number 1 and 2 except that
     soot blowing was eliminated.  Run- Number 3 incorporated soot blowing as
     normal to see if any increase in emissions could be detected.

VI.   SAMPLING AND ANALYTICAL.•PROCEDURES-        '                  '
     A.  flo-is-ture_Deterinination"           .          •               ~ซ—~~-  „.
         Per cent moisture in the stack gas was determined by pulling a
         measured volume of stack gas through a heated probe and into a
         preweighed midget impinger containing 15 mis. of water and  sitting
         in an ice bucket.  The per cent moisture was calculated from the
         gain in weight of the impinger due to the water collected,  and the
         volume of gas pulled through the impinger.  A schematic of  the
         moisture train is shown in r-'igure 5.
                                        12

-------
              Heated Probe
:ice Bath :
   Impfnger *
                                                               Rptcineter..
                           Figure 5 - Moisture Train
     8.   Velocity Traverse
         Velocity pressure  and  temperature measurements were  taken  in  the
         center of  each  of  the  45  areas  shown  fn  Figure 3  by  Source Test
         Section personnel.   The velocity  pressure was measured using  an
         S-type pi tot  tube  and  oil manometer,  and the temperature determined
         using a chromaJ.-alumel thermocouple connected to  a potentiometer.
         Velocity,;gressure  and  temperature measurements were made  at_the
         center of  each of  10 equal, areas in  each  inlet duct and the  center
         of  each  of the 15  equal  areas  (Figure  4)  in  the  outlet ducts by
         Duke  Power personnel.

         Velocity pressures were  measured using a  standard  pitot tube
         connected  to  an  oil manometer.  Temperatures were  measured using
         a thermocouple connected to a  potentiometer.
                                      13

-------
C.  Particulate Sampling -'APCO Train
    The APCO participate sampling  train (Figure  6)  consists  of a
    stainless steel  nozzle (l),an  Incoloy 825-10'  probe  (2), a cyclone
    (4), and a filter holder (5) in a heated  section  (6)  of  the sample
    box.  The filter holder contained a 2 1/4" glass  fiber filter (MSA
    1106 BH).  Beyond the filter was a modified  Greenburg-Smith impinger
    (8) containing 100 ml. H^O, a  second Greenburg-Smith  impinger not
    modified (9) containing 100 ml. H?0, a third impinger (10) of the
    modified Greenburg-Smith design left dry,  and  a fourth modified
    Greenburg-Smith  imp-inger -(11 )• containing  approximately 175 grams
    of accurately we_ighed_Jndieating silica gel.  The impingers are
   . JDijied-by_—glass  connectors  and are in the ice  bath section^?) of
    the sample box.          ,    ..   "        .

    The sample box is connected to the meter  box by an umbilical  cord (14),
    The umbilical cord has a thermometer (12)  and  check  valve (13) on the
    sample box end.   The thermometer indicates the temperature of the gas
    leaving the last impinger,  and the check  valve prevents  gas from
    backing up in the impingers thus forcing  water from  the  impingers into
   •the filter when  the system  is  turned off.                          ..
    The meter bo,* contains a vacuum gauge (15)  to measure the pressure
   "drop across the sampling train, an on-off valve (16)  and  a by-pass
    valve (18) to adjust the gas flow rate through the train.  Next is
                                14

-------
a leak!ess vacuum pump (17) to pull the gas through the train, a dry
gas meter (19) to measure the total amount of dry gas sampled, and
an orifice,(20) connected to an oil manometer (21) to indicate in-
stantaneous gas flow through the train.  The dry gas meter contains
inlet and outlet thermometers (12) to measure meter temperatures.

An S-type pitot tube (22) is attached to the probe.  This pitot
tube is connected across an oil manometer to continuously measure
velocity pressure while sampling.

A thermocouple was~~tape'd to th'e probe and connected to a potentio-
meter to ind-ica-te-stack temperature.
A velocity traverse was taken in each duct by positioning the pitot  .
and thermocouple in the center of each of the equal areas shown in
Figure 3.  The data from these traverses was used to determine the
nozzle size needed to sample isokinetically and at a rate of approxi-
mately 0.75 cfm.  The center of each of these equal areas was sampled
isokinetically for 3 minutes for a total of 135 minutes per each test
run.  Isokinetic flow was maintained using the nomograph described in
the test procedures.  Any deviation from the standard procedures are
explained in the Appendix.  Complete test procedures are available from
OAP upon request.      '                                         .
                            15

-------
Figure 6 -APCO  Participate Train

-------
 D.,  Particulate  Sampling  -ASME Train
     Velocity  traverses were  taken  in  both  the  precipitator  inlet
     and  outlet ducts  using a standard pitot  tube,  and  thermocouple  •
     and  potentiometer.  The  traverse  data  was  used to  select a  sampling
     nozzle  size  which would  permit isokinetic  sampling  at a rate of
     about 1 cfm  through the  meter. The same data  v/as  used  to determine
     the  isokinetic  sampling  rates  used in  each area.

     The  sampling train consisted of a nozzle,  a thimble holder  containing
     a  tared alundum thTmbleT probe, condenser,  dry gas  meter, and- ejector.
     The  temperaturerancr pressure at the meter  were monitored so that  the
            f"*9aT'sampled could be calculated-to standard condrbiens—
     Ten  equal  areas  were  sampled  in  the  precipitator  inlet  ducts  and
     15 equal  areas  (see Figure  4) were sampled  in  the precipitator out-
     let  ducts.                       .     .....           .....

     Procedures  were  followed  as given in'Power  Test Code  27.

 E.   NO   Sampling
     Samples were  collected  in an  evacuated  flask of known volume
    •coDtaining  25*ml.  of  a  dilute solution  of I-L02 and t-L SO,.  The
	--—	~ ~"	*	* •  ~~     '                                      t
     pressure  and  temperature  of the  flask was measured before  and after
     sampling  so that the  sample volume could be adjusted  to standard
                                17

-------
    conditions.
    To analyze for NO  the solution was evaporated to dryness and treated
                     A
    with phenoldisulfonic acid reagent and ammonium hydroxide and measured
    colorimetrically.             '          '           •  •
F.   Orsat Sample                         .-'.'••
    Integrated samples for C02 and Op were collected in Tediar bags
    over the whole test period and analyzed using an orsat.
    All  APCO pro-cedu-res- ar-e- available upon request.
                                13

-------
Appendix A

-------
RF.PUUT NO.
                                                            PAGE
         PAGES
                               SOURCE  TESTING CALCULATION  FORMS
Test. No.____	
Name of Fi rni__J)jjke__Ppj//er_ -_Efilz&t,JL.JL,.
Location of Plant__p_eLze_rx.^_._jQ..	_
Type of Plant	Co
                                                               No,  Runs___3	
Control Equi prnent  Hot Side Precipitators .
Sampl i ng Poi nt  Locati ons	Qa.t].at_.D.acฑs,_fcQ!!.L-ฃne.ca.pjฑ5tQrs^
Po11utants Sampled '  Particulate,  SQg^  N0:<, Visible Emissions
Time of Participate Test':     •          .  •    ''
Run Mo.__	1	Date	2/2/2J	Be9in	lj_3.0__Pjv
Run No.	2	.  Datir__2;/^/-2.L_I	   Begin	_liOJLM—
R,u n No. 	  3    „...., •r^=~0a4e; _-:^g/4/71; j:.       Ceg i n	]j
                              PARTICULATE EMISSION DATA
Run No.
 P   barometric  pressure, "iig Absolute
 p   orifice  pressure drop, "H00
_. n?	   _.. ..   			  .<-.
 V,  volume  of  dry gas sampled @ meter
     conditions,  ft.3
Tm  Average  Gas  Meter Temperature,  ฐF
V       Volume of Dry Gas Sampled  @ Standard
  'std.   6'onditions,  ft.3
 V   Total  HJ3  collected, ml;,  Impingers
 w   & Silica! Gel.

•



>tandard
JPS
1A J IB
29.74
2L23
99.28'
64
00.28
52.0
29.74
2,13
99.74
65
2A j 2B
i
29.78129.78
2,50
102. 5^
"ซ 1
' ' 1
100.53T05-.6
140.0
140. 0
2J7
3A
"^R !
	 ! 	 ~"!
29.58 29.58 !
2.33 2.15 i
99, 09 |l 00. 00. 99.97
,?
52
102.55
1.18.0
62
100.88
147.6
55
— ..
102.18
112.7
       V61uv,:e  of""l'.'atc'r" Vapor  Collected
        ft.3 (3 Standard  Conditions*
                                                  7.20   6.64  '6.6.4
5.59  7.00.  5.34!
          i       j
    * 70 F, 29.92" Hg.-
                                         A-l

-------
PARTICULATil EMISSION DATA  (cont'd)
Run No.
i" "I
XM - % Moisture in the stack gas by volume
M. - Hole fraction of dry gas
% co2 • •
% Qy
- - , ...••.... ' . . . . .
% N2 '
M H , - Molecular weight. of dry stack gas
M W - Molecular weight of stack gas
 	 . ... — - — ,
PS - Stack Pressure-; '"tig .-"Absolute "
V - Stack^ Velocity @ stack ^conditions, fpm
.._ 	 ..,. _ */
A - Stack -Arear ]n,- •
Q - Stack Gns Volume @
s Standard Conditions, SCFM dry
T - Net Time of Test, m1n.
L>
0 - Sampling Nozzle Diameter, in.
/ '
%I - Percent isokinetic
m* . - Participate - probe, cyclone
and filter, nig.
m - Parti cu late - total, nig.
C - Parti cul ate - probe s cyclone,
an and filter, gr/SCF
C - Parti cul ate -'"total, gr/SCF
ao ••••.• -— 	 	 -
j C , - Parti cul ate - probe, cyclone, & f i i tet
[ gr/cf @ stack conditions
1
1A
6 . 70
0.93
15.4
3.5 .
81.1
30.6
29.72

679
15.97
29.23
2357.0
1555-5
107607
135
.375
; 96.91
1136.0
1303.7
. .1745 '
,'.
^002
.0737
IB
6.20 •
0.94
15.4
3.5
....... ,B.1J.
30.6
29.84

656
15.33.
29.23
2266.8
15552
106757
135
.377
96 '. 88
1668.7
1840.3
.2556
.2891
.1114
2A
5.92
0.94
15.3
3.2
	 .81. .5 	 	
30.6
29.84

638
•
29.27
2524.3
•~ -
"15552 j
1
115729
135
i
.375
94.89 •
1097.5
... .... , „ ,
1451.3
.1600 .
.2116
'.0679
             A~2

-------
PARTICULATE EMISSION DATA (cont'd)
Run No.

%M - % Moisture in the stack gas by volume
M, - Mole fraction of dry gas
% co2
a n
* ?
% N? :
M H , - Molecular weight .of dry stack gas
M W - Molecular weight of stack gas
APs - Velocity Head of stack gas, In. HO
T - Stack Temperature, F
[ZD^~y460)~ _ 	 -~- ••-- -- ;
^ PS - Stack Pressurer-'Hg-^Abstrlute -
V --.Stack -yelo-e-vty (3 stack conditions, fpm
^ •'--._*.. 	 ^ 	
' A - Stack Area, in.- '.
Q - Stack Gas Volume @ *
Standard Conditions, SCFM
T. - Met Time of Test, m1n.
V
0 - Sampling Nozzle Diameter, in.
%! - Percent isokinetic
nu - - Particulate - probe, cyclone
and filter, mg.
m - Particulate - total, mg.
w
C - Particulate - probe, cyclone,
an and filter, gr/SCF . ' - .
| C -.Particulate - total ,' or/SCF
ao
1 C ,. - Particular - probe, cyclone, & filter
gr/cf @ stack conditions.

2B
_ 5.17
0.95
15.3
3.2
81.5
30.6
29.97

• 67(1
15.49
29.27
2275.0
15552
1070S8
135
.375
99 . 58
1159.0
1566.1
.l"740~----.
.2352 '•
.0758

3A
6.49 •
0.94
15.3
- 3.3
_ai.4__
30.6
29.84

6R2
16.49
29.07
2435.5 ""
15552
111477
135
.375
94.10
944.0
1073.8
.. .1441-
.1639
.0610

3B
' 4.97
0,95
15.3
3.3
81.4.....
30.6
•29.97

670
- 15.65
29.07
—2306 r4 ,
• 15552 !
107824
135
.372 |
97.50
.
1111.7
1179.5'
.1675
.1778-
.0725
            A-3

-------
                        rr-.x\ ILULM ; i:
Run No.
C, (   - Parti cu 1 ate,.. tota.L, gr/cf	
 a"     0 stack cond.

C    - Particulate,  probs, cyc!onef
 c:W     and filler, Ib/hr.
C    - Participate - total, Ib/hr.
% EA - % Exccs5 air G>
       saropl ing point
 '70ฐF.  29.92" Kg.
                                                1A
.084f
      IB
      2A
2B    3A
3B
d22^-^?^^2^  -0694  -075-
160.233.8 158.}
                                               JMJL25.Z-.Sf
19.37
            159.7  137.7
            154.1\
                                     A-4 ••-;

-------
                               PARTI GUIATE  CALCULATIONS
1.  Volume of c!ry gas sampled  at  standard  conditions  •-  70ฐF,  29.92"

                                                  '
     mstd  a  17.7 X  v?R  -I-   P
     : •  .  .     .      md  B
                                   /
                   (Tra * 460)             '




 2.   Volume of water vapor  at  70ฐF  & 29.92"  Hg,  Ft.3
     wgas- ซ 0.0474  X  V   =  Ft.3
                      Vs
 3.   % moisture  ih  stack  gas   	•-- -.




     *N  ป  100  X  V.  " '. •-——-^- -—
           ;_....,..„__._„^






          mstd    wgas  .
4.  Mole  fraction  of  dr,-  gas





• ,'."'• H  ป    100  ".._?M   .V':-r'   .  .  >:


.;  .  d        100




   • '    .•  . pf



5..  Avernna molecular v.'ilnht  of dry  stack  gas
                                                     X  fcV
                                         A-5

-------
     3,   Molecular weight of stack gas
   '•r'   -M.W.' ป M.U.j X Hd -5- 18  (1  - Md)
%"-'  7.   Stack velocity @ s-tack conditions,  fpm



                                         '       "
                                                  1/2  ซ
fpm
     8.   Stack gas volume @ standard conditions* SCFM
              0.123XVsXAsXMdXPs
                   (T  + 460)
  .• '9.   Per cent isokinotie
         %I .
            = 1032 X (le + 460)  X  V,
                                   rrt
                                   II!
    10.   Pavtlculato - p?'c;J;e9 cyclona,  S filter, gr/SCF
         C.5n = 0.0154 X Mf  = gr/SCF
          ail




          ,', .  '^.:;;-'^-     ..  m std.,  .
                                            A-6

-------
11... Particulate total, gr/SCF

 r



•- -  Cao  = 0.0154 X l-\t  •= gr/SCF



                      m std.
12.  Participate - probe, cyclone & filter,
     gr/CF at stack conditions
     r    - 17.7 X C   X P 'X M.  ซ Gr/CF
     Vt  "         '••'       •  a
                  (T  + 460)
13.  Participate - total, gr/CF @ stack conditions
     Cau
14.  Particulate - probe, cyclone, & filter, Ib/hr.
     Caw  = 0.00857 X Can X Qs  = Ib/hr.
15.  Particulato - total, Ib/hr.
                    XCaoX V=l b/hr.
                                     A-7


-------
16....  % excess  air at campling point
     % EA
           =  '100  X
             0.266  X % 11  - % 0   =  %
                                                                                ' r'  ^ ?•  * "^

-------
Appendix B

-------
                                NOV  EMISSION  DATA
                                  A
Run No.
.Date •
nig N0? '
Tc - Flask Temperature, ฐF
V.,- - Flask Volume, liters
P. - Initial Flask Vacuum, "Hg.
' X
P.- Final Flask Vacuum, "Hg.
ppm NO?
2A
2/2/71
0.925
.60
2.043
25
0
279.0
3A
2/2/71
1.065
•
60
2.061
25
0
318.5
4A
2/2/71
0.785
60
2.046
25
0
236.5
._ ,
2/2/71
0.810
55
,
2.095
25
b
236.0
2.8
2/2/71
0.915
55
2.096
... ., u...
26"
0-
256.2
	 . — „„—


... . ,.. ,_. _ j

. .-


                             (iy-M60)
                               \
ppm N0"
           Vf  X  (P.  -  Pf)
                                      B-l

-------
                                 NOV  EMISSION DATA
                                   A
	 -: - - 	 - 	 •• - •
Run Mo.
.Date
mg N0?

I* - Flask Temperature', ฐF
Vf - Flask Volume, liters
Pi - Initial Flask Vacuum, "Hg.
Pf- Final Flask Vacuum, "Hg.

ppซi NC^ .

5A_
2/3/71
0.940

50
2.095
25
0

271. 2_j

. 6A
2/3/71
0 900

50
2.059
25
0

_2&L2_

	 7A 	
2/3/71
0 750

50
2.079
25
0

_mj_

__3B____
2/3/71

L
__




	

48 	
2/3/71
0.865

50.
2.097
25
0

-,-, •• - , -
._Z4.9^3

--. rL ,. .. j
J_B_____
2/3/71
0 990

50
2.061
25
0

.zaa_4__
                          "X   (T^  +  460)
ppm NO9=
Vf  X  (P.
                        Pf)
                                    B-2

-------
                                     )v  EMISSION DATA
                                     A -
Run No.
.
.Date
mg NQ?
Tr - Flask Temperature, F
V,: - Flask Volume, liters

P. - Initial Flask Vacuum, "Hg.
Pf- Final Flask Vacuum, "Hg. •

ppm HO,
8A
2/4/71
0.900
45
2.073

25
0

9W.Q
9A
2/4/71
™ — — •"—
0.840
45
2.065

25
0

?/n q
	
10A
2/4/71
_
	






68
2/4/71
0.865
45
2.071

25
0
u

?5n n
7B
2/4/71
0.865
40
2.103

25
0
i.
?A? R
T









                            X'  (T.-+  460)
                                  '
. ..ppm
             Vf  X   (P. (- Pf)
                                           B-3

-------
Appendix C

-------
9  3
                                   • •    ''"*"" ฃ$
                          ^.•,
_33Y,A.
                                 , I
                                                                         (
                                                                                         T
                                                          • iฃ. ,f*iซ7
                                                              /

                                           -    ป
                           -'i  ^MJ^I, 4..,.•
                                          __.^
                                       	(1,9.^
                                                                        s-/
                                                               0,

-------
                          •        /
-•:.
                                             •r—
             C-2

-------
Appendix D

-------
f  _	,„	•   		_.
j      >
                s   February 23^ 1971
                                 ENVIRGIIMEN7AL  PROTCCTlOiJ AGENCY

                                  Air Pollution Control  Office
        Reply to                                            -
         Atin o-i3? ' Source Testing SaGt1onป  DA,  BAG

         Subject: -Soyrca Testing of Duke- Pc-.Jsr Plant,  GraenvWe, SปC,

              Tos  John L. McG1nn1ty0 Chief,  Engr.  Br.,DAB BAG

                   THROUGH:  James 0, Dealyc  Chief,, Source Testing Section

                   1.  Source test personnel  visited the lea  Steam Station0 Duko  '
                   Power Company 8 February  1  through 4  to tsst unit- no, 1.  The?
                   following goverruTant  personnel wora  Involved?

                       Hark Hooper                    Ray Hob ley
                       M1ke SlavlnsJcy                 Allan Riley
                       Jerry Rom                -      Stan Blacker DAQEO
                       Bill GHmley                   Jawes Ko'ily
                       Ed McCarlcy         '                              •'••••
                       Gone Riley         _
                       Bob Martin         --— -        -                           ^

                   2.  Duke Povfl&r-sflf,ip1ed-3irriu1t:dneous1y with Af>CO using tho AS"ฃ   •
                         i  Personnel Involved  in testing from Duks Power aro listed
                       wr— -*"'"                                    ...     ^~_--  ._

                       Bob Carpenter                       •             -:
                       Jim Snyder                     , .           .'.....       .  _.-
                       T\A ^ v> -? r- ,-\ p. ,r> V •* ป.-,-J- #ป
                       Evsrctta Yelton                         .       •            .
                       Jim Hards on              '                        •     ,
                       Mlltcn K-j-Itilit                                            .   .'
                       David Martin
                       CoO. Hu.-nphrios
                       Bill Kino
                       V .  . p . • i * 5 ; r ! i :ซ•
                   38  The tosts worn obsnrva-J  by  ths foil •:;•., -Ing visitors 2/2

                       Earl Povmrs ป Se C,  Pollution Contract
                       Otto Pearson - S. Co  Pollution Contract        .    '  '
                       Ed Galloway - C1nti.  Gas and Electric
                       Dick Thorsel'S - EEI       .
                                              0-1

-------
 Pago 2 - John U McSinnity

	Yh3 tests-wars  ofosarvod by the following  visitors 2/3.

          Alex Covo'll - Ccrft'iStlcn gr^ln-:
          Ch;;ck Bldkosel't  ป C' run was conducted o'yring scot blowing.
          g* . CiJai  C.i'^a  tcucuiiicJ fvt1?;] 'cii;: piant wi'll  ba ur>x?d in
          calculating  excess a1rป  The bag sample  dcita obtained was
         . Inconsistent and appeared to be lev;.

      50  Duks Pov/e?* peruonra'! sampled 15 equal areas  1n each duct
      using the ASME insthod*  Thay also sampled the 1n'!ot to the prs
      c1p1t.5tor as '=;::]] as tho c'itlet. '
                                    .'•

      6.  D^ta Cf>t:vij";^d by both test groups K-U copied and ojcchancjad.
      Ccr^ploto rtfsuKn will b.i axchangod c.i ;;con as the analytical
      report Is rovlos-d  and t!:n ncccssav"' d.ifcn calcu'!atad0
      Source Tsiit Tecini
                 s~                              .

      eet   Mark Hooper  	                    •             •
            Mike Slavlnsky                         Mle:  71 OAK
                                 D-2

-------
Appendix

-------
                        DUKE PovniTf; COMPANY
   i  ,
                                Pcfrn'.a BOII.PIMO
                     433 SOUTH CHUKCH ST.T;E;:T, G:u,.-u.oTTi!, N. C.


A. C Trnao                                                              p O- Sox si TO
v>cs Putoiotirt                                                                 no:!o>


  February 26, 1971     ..                   .                           ...
  Mr. Mark H. Hooper
  APCO EPA                                '                              .    •
  411 West Chapel Hill Street
  Durham, North Carolina  27701

  Subject:                   Lee Steam  Station
                             Unit No. 1
                             Electrostatic  Precipitator
                             Joint  Emission Test
                             Duke Power - 'APCO
                             February 1-5,  1971   .

  Dear Mr. Hooper:            ----- ..;.~ ._ . --

  Enclosed you will find— two— cop ieja. of  our  tabulation of  data and reaulta
  from the subject test.  At your earliest  convenience, would you please
  send us copi'eff" oฃ^our~re3ults."~  This is  in accordance  with the agreements
  which we made ptto-y-tb the teat.         .                            _^,_

  After we receive your results, we will send you a  copy  of  our teat report
  which will include a coupariaion  of your  results and ours..

  We call your attention particularly to Item 12 , "Coal Analysis, As Fired,"
  in our tabulation.  This was requested by your Mr.  James Kelly.  When he
  was at Lee on February 5, 1971, we gave him coal samples from the test,
  but he indicated that he did not  have the equipment to. check the samples
  for BTU , aah? moisture, and sulfur.                  . •.

  One unusual aad unexpected condition  that we had during the test van <:ao
  sulfur content of the coal. .It ran from  1.90  to 2.092.  This uaa an
  abnormal condition because our sulfur generally runs frota  about .0.5 to
  1.5%.   V7e do not believe that this had any effect  on' the performance of
  this hot precipitator because ash conductivity varies 30 slightly with
  sulfur in the 700ฐ F range.
     )' truly yours,
  A. C. Thies, Vice President
  Production and Operation

  RRC:vr  -
  Enclosures                           E-l

-------
       LF '-STEAK STATION, USIT HO. 1
       JO'^T "EMISSION TEST
       DUKE POWER AND APCO
                                TABULATION 0? DATA AND RESULTS
                                    (BY DUKE POWER COMPANY)
n
i
ro
            I.
            2.
            3.
            4.
            5.
           .6'.
           ' 1.
            8.
            9,
           10.
           11,
           12.
V
           13.
           1.4,
Date
Run   •
Unit Load
Steam Flow
Main Stearu Teraperauure
Main Steaa Pressure
Reheat S tears Temperature
C02           .  :'
C'2
'Condenser ABP
Baroraeter
Coal Ane.lyais,  As l-'isred
     BTU
     Ash
     Moisture '.
     Sulphur
Precipitate.: Efficiency
'     A Side
   ,  3 Side
     Average
Precipitator Gas Flow-
A.  At Duct Conditions
    A__Sj.dc_
       Inlet
       Outlet '
       Average
  .v B Side
       Inlet  '
      .Outlet
       Average
    A & B Total
B.  At Contract Conditions
    A Side
       Inlet
       Outlet;
       Average
2-2-71
•'• ''• 1
; KM ' 108
M-Lbซs/Hr ' 795
V| ft , ..949
^s;ic 1272
l|?iT : 951
'!'••.?• . 15.3
1 '% . , • '3,50
"kg ! '. ' 0.78
- "Kg j| ' 29.72

' *
BTU/Lb: ' ! 11605
% j , ; • 16.22 -
• % 1. 5.36
% ;;.f -1.93
%•
,•
: . 99.21
' ' 98.52
98.37
2-3-71
2
108.5 ,
793
945
1260
940
15.3
'3.50
0.68
29.80


11979
15,65
. 4.84
1.90
98.48
97.53
98.00
2-4-71
3
103
790
940
1256
935
15.3
•3.50
0,68
29.55


11690
15.10
6.75
2.09
98 . 88
97.44
98.16

• Average
108.2
'- 792.7
. 944,6
i 1266
! ' 942
' 15.3
3.50
0.71
; 29.69
t
I
i 11758
15,65
5.65
, 1.97
93.86
97.83
98.35
                                       AFGi
                                                                  271,771
                                                                  239,047
                                                                  230,409

                                                                  241,963
                                                                  236,481
                                                                  239,222
                                                                  519,631
                                                                  277,703
                                                                  297-,798
                                                                  287,751
                                                                 257,386
                                                                 299,032
                                                                 278,209

                                                                 243,454
                                                                 242,741
                                                                 243,098
                                                                 522,307
                                                                 262,924
                                                                 308,099
                                                                 285,508
253,809
273,100
263,455

242,352
242,806
242,579
506,034
260,104
282,506
271,305
260,989
287,060
274,024

242,590
240,675
<•*}-, C."i*>
ฃ -4 J. 3 O .^ J '
515,651
266,910
296,134
281,521

-------
                                          TABULATION OF DATA AND RESULTS  (cont'd)
n
i
Co
                                                   \\  T
                                                   Oj,
                                                 In. E?0
             Inlet
             Outlet
     i '•      Average
   '  '     A & S  Total
 15.  Duct Temperature
     ;    A Inlet
     ';    B Inlet              -  '
    •  i  •  Average

    .  •    A Outlet
          B Outlet             .. ..  '
          Average
 16.  Temperature Drop
          Across Precipitator
.17.  Duct Pressure
          A Inlet .             '                '
          B Inlet        .             '
         , Average

          A Outlet
          B Outlet
          Average
 13.  Duct Loadings  (Not for Efficiency Cal.)   •
          At Duct Conditions       •  .   .   GRAINS/ACF
     A.   Leaving Stack
       .'' A Side
          B Side          •
          Average
     B,   At Precipitator Outlet
        •  A Side
          3 Side
               Average
               At Precipitator Inlet
               A Side
               B Side
               Average
                                                       \
248,005
244,134
"' 246,070
533,321
•• . 679.3
'i 676.2
;| 677.3
, j 669. 2
'' '667.7
• J663.5
249,151
250,056 •
249,604
531,112
630.0
677.9
673.9
. 663.4
669.3
668.8
249,720
252,178 -.
250,949 i '
522,254
676.0 ;
669.9 .
672.9
' 664.3
660,6
662,5 -
248,959
248,739
248,374
530,395
673,4
674.7
676.6
667.3
665.9
666.6
   9.3
0.0245
0.0478
0.0362

0.0168
0.0335
0..0252

2.0840
2.1203
2.1022
10,1
0,0475
0,0750
0.0613

0.0327
0.0516
0.0422

2,1518
2.1060
2.1289
10.4
           0.0332
           0.0322
           0.0577

           0.0231
           0.0573
           0.0402

           2.0121
           2.2261
           2.1191'
                            10.0
-6.72
-6.47
-6.60
-6. S3
-6.70 '
-6,79
-6,48
-6,47
- ' -6.43
-6.33
-6.61 '
" '-6.72
-6.67
' -6.62
, -6.65
-7.01
-6. S3
'-6.92
-6.62
-6.52
-6.58
- -6.91
-6.71
-6. 31
                                                                                                     0.0351
                                                                                                     0,0633
                                                                                                     0.0517
           0.0242
           0.0475
           0.0358

           2.0826
           2.1508
           2.1167

-------
20,

21.

22,
             Dust Loadings (For -Efficiency Caic.)
                 ; ac 32ฐ? and 29.92 "Kg
             A.  'At Prccipitator Outlet
                 iA1 Side                  :
                 ;5 Side
                 Average
             B.  .At Precipitator Inlet
                 A Side
               '  B Bide
                 Average
             Energy Input   ,             -
             Emission Rate

             Outside Ambient Tarnoerature
• I"
K ' "
	 	 'y "•

;T:..

ATION 0? DATA AND RESULTS (cont'd) -
GRAINS /,CF
; . ; * .
VJ 4
1 ! 1
• ' ' i '
: i j

•••
1C6 BTU/Hr.
Lbs/10ฐ BTU<
"ฐF- '

0.0418 0.0813
0.0832 ' ' 0.1286
0.0625 . '. 0.1050 -

;5:j2S80 5.3439
J5J6253 5.2035
I5J4567 •• 5.2737
l6l5. 2 1019.9
i '* ป
). 11056 - 0.18524
: 35 30 - -

0.0577
0.1440
0.1009

5.1567 •'
5.6296
5.3918
1015.2
0.17175
32
. N. T • . '
V . T
<-
i
•
0.0669
.0.1186
0.0395

5.2629
5.4852
5.3741
1016.8
0.155S5
32.3
                                                                                                              i   *
        2/22/71
        RRC/vr
\

-------