United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-025A
July 1999
AIR
Final Report - Volume I of II
Iron and Steel Foundries
Manual Emissions Testing
Cupola Wet Scrubber
General Motors Corp.
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FINAL REPORT
IRON AND STEEL FOUNDRIES
MANUAL EMISSIONS TESTING
CUPOLA WET SCRUBBER
GENERAL MOTORS CORP., SAGINAW, MICHIGAN
VOLUME I OF II
REPORT TEXT & APPENDICES A & B
EPA Contract No. 68D70069
Work Assignment No. 2-08
Prepared for:
Mr. Michael K. Ciolek (MD-19)
Work Assignment Manager
SMAG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
July 1999
P:\i528\fmrpt\gm\gmfin.rep
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919)941-0333
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DISCLAIMER
This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-08. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.
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TABLE OF CONTENTS
VOLUME I Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 PARTICULATE MATTER AND METALS 2-1
2.3 DIOXINS AND FURANS 2-7
2.4 SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS 2-14
2.5 VOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS 2-28
3.0 PROCESS DESCRIPTION 3-1
3.1 INTRODUCTION 3-1
3.2 PROCESS DESCRIPTION 3-1
3.3 PROCESS AND CONTROL DEVICE MONITORING RESULTS 3-8
4.0 SAMPLING LOCATIONS 4-1
4.1 CUPOLA WET SCRUBBER INLET 4-1
4.2 CUPOLA WET SCRUBBER OUTLET 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF DRY MOLECULAR WEIGHT
AND EMISSIONS CORRECTION FACTORS 5-1
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT 5-2
5.5 DETERMINATION OF PARTICULATE MATTER
AND METALS 5-3
5.6 DETERMINATION OF DIOXINS AND FURANS 5-3
5.7 DETERMINATION OF SEMIVOLATILE ORGANIC
HAZARDOUS AIR POLLUTANTS (SVOHAPS) 5-8
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TABLE OF CONTENTS (Concluded)
5.8 DETERMINATION OF VOLATILE ORGANIC HAZARDOUS AIR
POLLUTANTS (VOHAPs) 5-8
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) 6-1
6.1 CALIBRATION OF APPARATUS 6-1
6.2 ON-SITE MEASUREMENTS 6-4
6.3 LABORATORY ANALYSIS 6-8
APPENDIX A - RAW FIELD DATA
APPENDIX B - ANALYTICAL DATA, PCDDs/PCDFs AND SVOHAPs
VOLUME II
APPENDIX C - ANALYTICAL DATA, PARTICULATE MATTER AND METALS
APPENDIX D - CALCULATIONS
APPENDIX E - QA/QC DATA
APPENDIX F - PARTICIPANTS
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LIST OF TABLES
VOLUME I
Table 2.1 Emissions Test Log, General Motors Corporation - Saginaw, Michigan 2-2
Table 2.2 Particulate Matter/Metals Emissions Sampling and Flue Gas Parameters,
Cupola Wet Scrubber Inlet, General Motors Corporation, Saginaw,
Michigan 2-3
Table 2.3 Particulate Matter Concentrations and Emission Rates, Cupola
Wet Scrubber Inlet, General Motors Corporation - Saginaw, Michigan 2-4
Table 2.4 Metals Concentrations and Emission Rates, Cupola Wet Scrubber Inlet,
General Motors Corporation - Saginaw, Michigan 2-5
Table 2.5 Particulate Matter/Metals Emissions Sampling and Exhaust Gas Parameters,
Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
Michigan 2-8
Table 2.6 Particulate Matter Concentrations and Emission Rates, Cupola Wet
Scrubber Outlet, General Motors Corporation - Saginaw, Michigan 2-9
Table 2.7 Exhaust Gas Metals Concentrations and Emission Rates, Cupola Wet
Scrubber Outlet, General Motors Corporation - Saginaw, Michigan 2-10
Table 2.8 Particulate Matter and Metals Removal Efficiencies, Cupola Wet
Scrubber, General Motors Corporation - Saginaw, Michigan 2-12
Table 2.9 PCDDs/PCDFs Emissions Sampling and Exhaust Gas Parameters,
Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
Michigan 2-13
Table 2.10 PCDDs/PCDFs Exhaust Gas Concentrations and Emission Rates,
Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
Michigan 2-15
Table 2.11 PCDDs/PCDFs Exhaust Gas Concentrations and 2378 Toxic Equivalent
Stack Gas Concentrations Adjusted to 7 Percent Oxygen,
Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
Michigan 2-16
Table 2.12 SVOHAPs Emissions Sampling and Exhaust Gas Parameters,
Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw
Michigan 2-17
Table 2.13 SVOHAPs Exhaust Gas Concentrations and Emission Rates, Cupola
Wet Scrubber Outlet, General Motors Corporation - Saginaw, Michigan .... 2-19
Table 2.14 SVOHAPS Detection Limits, PPBVD, Cupola Wet Scrubber Outlet,
General Motors Corporation - Saginaw, Michigan 2-26
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LIST OF TABLES (Concluded)
VOLUME I
Table 3.1 Typical Cupola Charge Materials 3-3
Table 3.2 Typical Results from Greens Sand Analysis 3-6
Table 3.3 Chemicals Used in Core Making and Mold Spraying 3-7
Table 3.4 Summary of Cupola Monitoring Results 3-9
Table 3.5 Summary of Cupola Charging During the Test Days 3-10
Table 3.6 Summary of Number of Molds Poured on Line 4 3-14
Table 3.7 Summary of Metal Poured and Downtime for Line 4 3-15
Table 3.8 Line 4 Mold Counts During Testing Periods 3-16
Table 3.9 Mold Line 4 Production During Testing Periods 3-18
Table 5.1 Sources, Test Parameters, and Test Methods Summary,
General Motors Corporation - Saginaw, Michigan 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-2
Table 6.2 Summary of Pitot Tube Dimensional Data 6-3
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-5
Table 6.4 Summary of EPA Methods 23 and 29 and SW-846 Method 0010
Field Sampling QA/QC Data 6-7
Table 6.5 Summary of EPA Method 29 Analysis QC Data, Lab Control Spikes 6-9
Table 6.6 Summary of EPA Method 29 Analysis QC Data, Matrix Spikes
(Post Digestion) 6-10
Table 6.7 Summary of EPA Method 29 Analysis QC Data, Duplicate Analyses 6-11
Table 6.8 Summary of EPA Method 29 Analysis QC Data, Serial Dilution 6-12
Table 6.9 Summary of EPA Method 29 Analysis QC Data, Method Blanks Results ... 6-13
Table 6.10 Summary of EPA Method 29 Analysis QC Data, Field Blanks Results 6-14
Table 6.11 Summary of EPA Method 29 Analysis QC Data, Mercury Summary
Report - Lab Control Spikes 6-15
Table 6.12 Summary of EPA Method 29 Analysis QC Data, Mercury Summary
Report - Matrix Spikes (Pre-Digestion) 6-16
Table 6.13 Summary of EPA Method 29 Analysis QC Data, Mercury Summary
Report - Method Blank 6-17
Table 6.14 Summary of EPA Method 29 Analysis QC Data, Mercury Summary
Report - Field and Reagent Blanks 6-18
Table 6.15 Summary of EPA Method 23 Standards Recovery Efficiencies 6-20
Table 6.16 SW-846 Method 0010 Field and Laboratory Blanks Results 6-21
Table 6.17 SW-846 Method 0010 Surrogate Recovery Results 6-22
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LIST OF FIGURES
VOLUME I Page
Figure 1.1 Key Personnel and Responsibility for Testing at GM - Saginaw, Michigan ... 1-3
Figure 3.1 Schematic of the Cupola Gas Handling System 3-2
Figure 3.2 Schematic of Capture and Control System for Line 4 3-5
Figure 3.3 Hot Blast Temperature During Each Test Run 3-11
Figure 3.4 Hot Blast Rate During the Test Runs 3-12
Figure 4.1 Cupola Wet Scrubber Inlet Sampling Location 4-2
Figure 4.2 Cupola Wet Scrubber Inlet Traverse Points Locations 4-3
Figure 4.3 Cupola Wet Scrubber Outlet Sampling Location 4-4
Figure 4.4 Cupola Wet Scrubber Outlet Traverse Point Locations 4-5
Figure 5.1 EPA Method 29 Sampling Train Schematic 5-4
Figure 5.2 EPA Method 29 Sample Recovery Scheme 5-5
Figure 5.3 EPA Method 29 Sample Preparation and Analysis Scheme 5-6
Figure 5.4 EPA Method 23 (PCDD/PCDF) and SW-846 Method 0010
Sampling Train Schematic 5-7
Figure 5.5 Schematic of Direct Interface GC/MS Sampling System 5-9
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1.0 INTRODUCTION
The U.S. Environmental Protection Agency (EPA) Emission Standards Division (BSD) is
investigating iron and steel foundries to identify and quantify hazardous air pollutants (HAPs)
emitted from cupolas; electric arc furnaces; and pouring, cooling and shakeout operations of sand
mold casting processes. BSD had requested that EPA's Emissions, Monitoring and Analysis
Division (EMAD) conduct the required testing. EMAD had issued a work assignment to Pacific
Environmental Services, Inc. (PES) to plan and conduct the air emissions test program to gather
emissions data as specified in the BSD test request. The planning and testing phase of the
program was conducted through EPA Contract No. 68D20162, Work Assignment No. 4-14.
This test report was completed under EPA Contract No. 68D70069, Work Assignment No. 2-08.
The EPA's BSD is investigating two types of control devices (baghouses and scrubbers)
as potential Maximum Achievable Control Technology (MACT) floor technology for cupolas.
Two facilities were selected by BSD as host facilities for the testing program. One uses a
baghouse for control of cupola emissions, and the other uses a wet scrubber for the control of
cupola emissions. General Motors Corporation, Saginaw Metals Casting Operations (GMC),
located in Saginaw, Michigan, uses a wet scrubber and was the subject of this test program.
Results of tests on a baghouse at the second facility were presented under a separate report.
Testing at GMC was conducted by two EMAD contractors to address the following BSD
requirements: 1) characterize HAP emissions from cupolas that are controlled by wet scrubbers;
2) characterize uncontrolled HAP emissions from pouring, cooling, and shakeout (PCS)
processes; 3) determine wet scrubber performance in controlling HAP emissions from cupolas;
and 4) identify surrogates for estimating HAP emissions from the subject foundry processes.
PES conducted testing for requirements (1) and (3). Data gathering for requirements (2) and (4)
was conducted by the other contractor and is not a part of this document.
GMC was selected by the BSD as the host facility for this project. This facility is a large
foundry that conducts melting and casting operations. EPA deemed this facility to be
representative of a large segment of the sand casting foundry industry. It operates a relatively
large cupola that is controlled by a wet scrubber. Tests were conducted at the cupola wet
scrubber inlet and outlet. PES performed particulate matter (PM) and metals (HAPs and non-
HAPs) testing at the cupola wet scrubber inlet and outlet, and organic HAPs testing at the
scrubber outlet. The organic HAPs consisted of polychlorinated dibenzo-/?-dioxins and
polychlorinated dibenzofurans (PCDDs/PCDFs) and semi-volatile organic hazardous air
pollutants (SVOHAPs). Volatile organic hazardous air pollutants (VOHAPs) were measured by
direct interface gas chromatography/mass spectrometry (GC/MS) at the scrubber outlet.
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PES used four subcontractors for this effort: Deeco, Inc. (DEECO); Emission
Monitoring, Inc. (EMI); Triangle Laboratories, Inc. (TLI); and Atlantic Technical Services, Inc.
(ATS). DEECO provided onsite sampling support for the determination of PM and metal HAPs;
EM provided onsite sampling and analysis by direct interface GC/MS for the determination of
VOHAPs; TLI provided analytical support for the analysis of HAPs; and ATS provided support
for preparation of the site-specific test plan (SSTP), quality assurance project plan (QAPP), and
report documentation.
The field testing program organization and major lines of communication are presented in
Figure 1.1. The PES Project Manager communicated directly with the EPA Work Assignment
Manager and coordinated all of the on-site testing activities.
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GMC
David F. Genske
(517)757-1455
EPA/EMC
Work Assignment Manager
Michael K. Ciolek
(919) 541-4921
Jim Maysilles
(919)541-3265
John Chehaske
(703) 471-8383
Dan Scheffel
(513)398-2556
Wayne Westbrook
(919) 941-0333
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2.0 SUMMARY OF RESULTS
This section provides test results summaries obtained from GMC testing. Included are
results of the tests conducted for particulate matter/metals at the cupola wet scrubber inlet and
outlet, and S VOHAPs and PCDDs/PCDFs testing at the cupola wet scrubber outlet. Although
we have included averages, there were differences in production rates and operating conditions.
It should also be noted that the inlet sample location was located after the quench chamber. The
quench chamber is the first stage of the particulate matter/metals control system. A true removal
efficiency can not be determined based on the inlet sample loading.
2.1 EMISSIONS TEST LOG
Sampling at the cupola wet scrubber was conducted on September 23,24, and 25,1997.
Table 2.1 summarizes the emissions test log. Presented are the run numbers, test dates,
pollutants, run times, and downtime for filter and port changes.
2.2 PARTICULATE MATTER AND METALS
2.2.1 Wet Scrubber Inlet
Table 2.2 summarizes the particulate matter and metals emissions sampling and flue gas
parameters at the wet scrubber inlet. The total sampling time varies for each test run with an
average of 148 minutes. The average sample volume was 97.591 dry standard cubic feet (dscf)
or 2.763 dry standard cubic meters (dscm). The average flue gas temperature was 131 °F. The
flue gas contained 9.8 percent (%) carbon dioxide (CO2), 12.3% oxygen (O2), and 16.6%
moisture. The average flue gas volumetric flow rate was 82,300 actual cubic feet per minute
(acfm) or 57,400 dry standard cubic feet per minute (dscfin) or 1,630 dry standard cubic meters
per minute (dscmm).
Table 2.3 summarizes the flue gas particulate matter concentrations and emission rates at
the cupola wet scrubber inlet. The average concentration was 0.363 grains per dry standard cubic
foot (gr/dscf) or 0.830 grams per dry standard cubic meter (g/dscm). The concentrations are also
shown adjusted to 7% O2. The average mass emission rate was 177 pounds per hour (Ib/hr) or
80.4 kilograms per hour (kg/hr).
Table 2.4 summarizes the flue gas metals concentrations and emission rates. The metals
concentrations shown by the reagent blank analysis for the acetone rinse, filters (3 inch and 4
inch), dilute nitric acid rinse, and metals absorbing solution (acidified hydrogen peroxide) were
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TABLE 2.1
EMISSIONS TEST LOG
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Wet Scrubber Inlet
I-M29-1
I-M29-2
I-M29-3
I-M29-4
Wet Scrubber Outlet
O-M29-1
SO-23-1
SO-0010-1
O-M29-2
SO-23-2
SO-0010-2
O-M29-3
SO-23-3
SO-0010-3
O-M29-4
SO-23-4
SO-0010-4
Date
09/23/97
09/24/97
09/25/97
09/25/97
09/23/97
09/23/97
09/23/97
09/24/97
09/24/97
09/24/97
09/25/97
09/25/97
09/25/97
09/25/97
09/25/97
09/25/97
Pollutant
PM/Metals
PM/Metals
PM/Metals
PM/Metals
PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
Run Time
1410-1841
0934-1343
0838-1149
1512-1845
1412-1846
1415-1846
1415-1847
0938-1347
0851-1347
0851-1400
0845-1145
0844-1321
0844-1321
1523-1843
1443-1918
1443-1919
Downtime,
Minutes
156
12
71
103
164
161
162
9
56
69
60
37
37
80
35
36
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TABLE 2.2
PARTICULATE MATTER/METALS EMISSIONS SAMPLING AND FLUE GAS
PARAMETERS, CUPOLA WET SCRUBBER INLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm "
Sample Volume:
dscf"
dscmc
Average Flue Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfind
dscfm a
dscmm d
Isokinetic Sampling Ratio, %
I-M29-1
9/23/97
115
0.517
59.458
1.684
125
12.3
8.9
14.0
82,000
60,200
1,700
102.3
I-M29-2
9/24/97
237.3
0.515
122.140
3.459
128
12.7
9.4
15.1
81,100
58,700
1,660
104.5
I-M29-3
9/25/97
120
0.881
105.757
2.995
133
12.2
10.0
17.7
82,900
56,100
1,590
102.0
I-M29-4
9/25/97
120
0.858
103.008
2.917
137
11.9
11.0
19.7
83,300
54,700
1,550
105.1
Average
148
0.693
97.591
2.763
131
12.3
9.8
16.6
82,300
57,400
1,630
103.5
' Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at flue gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
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TABLE 2.3
PARTICULATE MATTER CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER INLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Concentration:
gr/dscfa
gr/dscf@7%O2b
g/dscmc
g/dscm@7%O2d
Emission Rate:
lb/hre
kg/hrf
I-M29-1
9/23/97
1410-1841
0.269
0.434
0.615
0.994
138.6
62.9
I-M29-2
9/24/97
0934-1343
0.335
0.568
0.767
1.30
169
76.5
I-M29-3
9/25/97
0838-1149
0.387
0.618
0.885
1.41
186
84.4
I-M29-4
9/25/97
1512-1845
0.459
0.710
1.051
1.62
215
97.7
Average
0.363
0.583
0.830
1.33
177
80.4
• Grains per dry standard cubic foot at 68° F (20° C) and 1 atm.
b Grains per dry standard cubic foot at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
c Grams per dry standard cubic meter at 68° F (20° C) and 1 atm.
d Grams per dry standard cubic meter at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
e Pounds per hour.
f Kilograms per hour.
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TABLE 2.4
METALS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER INLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
lun No.
Date
Clock Time, 24-hr clock
Antimony (Sb)
Hg/dscm "
^dscm @ 7% O2 b
lb/hrc
Arsenic (As)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Jarium (Ba)
(ig/dscm a
ug/dscm @ 7% O2 b
lb/hr°
Beryllium (Be)
ug/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Cadmium (Cd)
ug/dscm •
ug/dscm @ 7% O2 b
lb/hrc
Chromium (Cr)
Hg/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Cobalt (Co)
ug/dscm *
Ug/dscm @ 7% O2 b
lb/hrc
Lead (Pb)
Hg/dscm °
ug/dscm @ 7% O2 b
lb/hrc
I-M29-1
9/23/97
1410-1841
37.2
60.1
0.00838
15.6
25.2
0.00351
183
295
0.0411
ND
ND
ND
49.2
79.6
0.01110
281
454
0.0633
12.9
20.8
0.00291
5,682
9,184
1.281
I-M29-2
9/24/97
0934-1343
15.5
26.2
0.00340
23.6
39.9
0.00518
319
541
0.0701
0.688
1.17
0.000151
69.8
118
0.0153
294
498
0.0646
11.8
20.0
0.00260
3,824
6,482
0.840
I-M29-3
9/25/97
0838-1149
70.6
113
0.0148
21.5
34.3
0.00451
248
397
0.0522
ND
ND.
ND
78.1
125
0.0164
259
414
0.0544
10.6
16.9
0.00222
8,269
13,211
1.74
I-M29-4
9/25/97
1512-1845
85.3
132
0.0175
28.3
43.7
0.00579
340
525
0.0696
ND
ND
ND
63.1
97.4
0.01293
247
382
0.0507
11.2
17.4
0.00230
8,777
13,556
1.80
Average
52.1
82.7
0.01102
22.2
35.8
0.00475
272
439
0.0583
0.172
0.292
0.0000378
65.1
105
0.01394
270
437
0.0583
11.6
18.8
0.00251
6,638
10,608
1.414
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TABLE 2.4 (Concluded)
METALS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER INLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Manganese (Mn)
Hg/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Mercury (Hg)
ug/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Nickel (Ni)
ug/dscm1
ug/dscm @ 7% O2 b
lb/hrc
Phosphorus (P)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Selenium (Se)
|ig/dscm '
Ug/dscm @ 7% O2 b
lb/hrc
Silver (Ag)
|ig/dscm *
Ug/dscm @ 7% O2 b
lb/hrc
Thallium (Tl)
Ug/dscm '
Hg/dscm @ 7% O2 b
lb/hrc
Zinc (Zn)
|ig/dscm •
Hg/dscm @ 7% O2 b
lb/hrc
I-M29-1
36,405
58,840
8.21
4.75
7.68
0.001071
15.5
25.1
0.00350
243
393
0.0548
12.3
19.9
0.00277
6.35
10.3
0.00143
18.2
29.4
0.00410
45,858
74,119
10.34
I-M29-2
41,676
70,646
9.16
3.21
5.44
0.000705
13.2
22.3
0.00290
1,614
2,735
0.355
16.4
27.8
0.00360
7.85
13.3
0.00173
18.4
31.1
0.00404
47,631
80,740
10.47
I-M29-3
35,940
57,421
7.55
33.8
54.0
0.00710
15.2
24.3
0.00320
1,113
1,779
0.234
12.5
19.9
0.00262
10.2
16.3
0.00214
16.2
25.9
0.00340
64,566
103,157
13.57
I-M29-4
39,504
61,011
8.09
5.97
9.21
0.001222
11.6
17.9
0.00237
1,125
1,737
0.230
13.8
21.3
0.00282
6.17
9.53
0.001264
17.8
27.4
0.00364
85,608
132,217
17.5
Average
38,381
61,980
8.25
11.9
19.1
0.00252
13.9
22.4
0.00299
1,024
1,661
0.218
13.7
22.2
0.00295
7.64
12.3
0.00164
17.6
28.5
0.00379
60,916
97,558
12.98
• Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm, adjusted to 7% O2.
c Pounds per hour.
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used to blank correct the scrubber inlet metals concentrations. Blank corrections were made if
the blank target analyte was less than 10% of the sample concentration. Average concentrations
ranged from 0.172 micrograms per dry standard cubic meter (^g/dscm) for beryllium to 60,916
ug/dscm for zinc.
2.2.2 Wet Scrubber Outlet
Table 2.5 summarizes the particulate matter and trace metals emissions sampling and
exhaust gas parameters at the wet scrubber outlet. The total sampling time varies for each test
with an average of 148 minutes. The average sample volume was 113.671 dscf or 3.219 dscm.
The average exhaust gas temperature was 119°F. The exhaust gas contained 8.7 % CO2,13.4%
O2, and 12.0 % moisture. The average exhaust gas volumetric flow rate was 73,200 acfm or
58,000 dscfrn (1,640 dscmm).
Table 2.6 summarizes the exhaust gas particulate matter concentrations and emission
rates at the wet scrubber outlet. The average concentration was 0.00952 gr/dscf or 0.0218
g/dscm. The concentrations are also shown adjusted to 7% O2. The average mass emission rate
was 4.78 Ib/hr or 2.17 kg/hr.
Table 2.7 summarizes the exhaust gas metals concentrations and emission rates. The
metals concentrations shown by the field blank analysis were used to blank correct the scrubber
outlet multiple metals concentrations. Blank corrections were made if the blank target analyte
was less than 10% of the sample concentration. All of the target metals, except arsenic,
beryllium, cobalt, and nickel, were found to be present in all four samples. Metals that were not
detected in a sample have "ND" in place of any emissions calculations and were not included in
the total metals sum. Average concentrations ranged from 0.075 ug/dscm for beryllium to 1,919
jag/dscm for zinc.
2.2.3 Wet Scrubber Performance
Table 2.8 summarizes the performance of the wet scrubber in controlling PM and total
HAP metals emissions. The removal efficiencies for PM and total HAP metals are based on the
inlet and outlet mass emission rates. As noted previously, the inlet sampling location was
located after the quench chamber. The scrubber performance does not include the
particulate/metals removed by the quench chamber. As a result of the inlet sample location, the
particulate/metals removal efficiencies are biased low. The average removal efficiency for PM
and total HAP metals was 97.3% and 96.0%, respectively.
2.3 DIOXINS AND FURANS
Table 2.9 summarizes the PCDDs/PCDFs emissions sampling and exhaust gas
parameters at the wet scrubber outlet. The total sampling time was 110 minutes for the first run,
and 240 minutes for the additional three runs. The average sample volume was 161.244 dscf or
4.566 dscm. The average exhaust gas temperature was 119°F. The flue gas contained 8.7%
-------
TABLE 2.5
PARTICULATE MATTER/METALS EMISSIONS SAMPLING AND EXHAUST
GAS PARAMETERS CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm "
Sample Volume:
dscfb
dscmc
Average Exhaust Gas Temp,, °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfmd
dscfm1
dscmm8
Isokinetic Sampling Ratio, %
O-M29-1
9/23/97
110
0.692
76.163
2.157
125
16.7
4.0
13.0
80,200
62,800
1,780
95.4
O-M29-2
9/24/97
240
0.633
151.911
4.302
133
11.8
10.6
16.4
74,000
55,200
1,560
99.3
O-M29-3
9/25/97
120
0.946
113.491
3.214
109
12.5
9.7
9.2
68,700
56,600
1,600
97.8
O-M29-4
9/25/97
120
0.943
113.118
3.203
109
12.4
10.3
9.6
69,800
57,500
1,630
95.9
Average
148
. 0.803
113.671
3.219
119
13.4
8.7
12.0
73,200
58,000
1,640
97.1
* Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic meters per minute at 68° F (20° C) and 1 arm.
-------
TABLE 2.6
PARTICULATE MATTER CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Concentration:
gr/dscfa
gr/dscf@7%O2b
g/dscm c
g/dscm@7%O2d
Emission Rate:
lb/hre
ke/hrf
O-M29-1
9/23/97
1412-1846
0.0150
0.0497
0.0344
0.114
8.08
3.66
O-M29-2
9/24/97
0938-1347
0.0161
0.0246
0.0368
0.0562
7.61
3.45
0-M29-3
9/25/97
0845-1145
0.00352
0.00583
0.00806
0.0133
1.71
0.776
O-M29-4
9/25/97
1523-1843
0.00347
0.00567
0.00793
0.0130
1.71
0.775
Average
0.00952
0.0214
0.0218
0.0491
4.78
2.17
• Grains per dry standard cubic foot at 68° F (20° C) and 1 atm.
b Grains per dry standard cubic foot at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
c Grams per dry standard cubic meter at 68° F (20° C) and 1 atm.
d Grams per dry standard cubic meter at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
' Pounds per hour.
f Kilograms per hour.
-------
TABLE 2.7
EXHAUST GAS METALS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
*un No.
Date
Clock Time, 24-hr clock
Antimony (Sb)
ug/dscm '
ug/dscm @ 7% O2b
lb/hrc
Arsenic (As)
ug/dscm "
ug/dscm @ 7% O2b
lb/hrc
3arium (Ba)
ug/dscm "
ug/dscm @ 7% O2b
lb/hrc
Beryllium (Be)
ug/dscm *
Hg/dscm@7%O2b
lb/hrc
Cadmium (Cd)
ug/dscm *
ug/dscm @ 7% O2b
lb/hrc
Chromium (Cr)
Hg/dscm*
ug/dscm @ 7% O2b
lb/hrc
Cobalt (Co)
ug/dscm "
ug/dscm @ 7% O2b
lb/hrc
Lead (Pb)
ug/dscm '
ug/dscm @ 7% O2b
lb/hrc
O-M29-1
9/23/97
1412-1846
5.19
17.2
0.00122
2.72
8.99
0.000639
24.6
81.5
0.00579
0.158
0.522
0.0000371
3.96
13.1
0.000930
29.3
96.8
0.00688
ND
ND
ND
382
1,265
0.0899
O-M29-2
9/24/97
0938-1347
3.47
5.29
0.000716
1.61
2.45
0.000332
24.1
36.9
0.00499
0.144
0.220
0.0000298
5.37
8.21
0.00111
23.8
36.4
0.00492
1.33
2.04
0.000276
366
559
0.0756
O-M29-3
9/25/97
0845-1145
2.88
4.76
0.000610
ND
ND
ND
11.5
19.0
0.00244
ND
ND
ND
1.23
2.03
0.000260
8.46
14.0
0.00180
0.672
1.11
0.000143
141
234
0.0299
O-M29-4
9/25/97
1523-1843
2.61
4.27
0.000563
ND
ND
ND
7.52
12.3
0.00162
ND
ND
ND
0.659
1.08
0.000142
6.03
9.85
0.00130
ND
ND
ND
71.5
117
0.0154
Average
3.54
7.88
0.000778
1.51
3.56
0.000334
17.0
37.4
0.00371
0.075
0.185
0.0000167
2.80
6.10
0.000610
16.9
39.3
0.00372
1.16
2.69
0.000256
240
544
0.0527
-------
TABLE 2.7 (Concluded)
EXHAUST GAS METALS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
lun No.
Manganese (Mn)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Vlercury (Hg)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Nickel (Ni)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
'hosphorus (P)
Hg/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Selenium (Se)
ug/dscm "
(ig/dscm @ 7% O2 b
lb/hrc
Silver (Ag)
ug/dscm11
ug/dscm @ 7% O2 b
lb/hrc
Thallium (Tl)
ug/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Zinc (Zn)
ug/dscm '
Ug/dscm @ 7% O2 b
lb/hrc
O-M29-1
2,984
9,875
0.702
4.81
15.9
0.00113
4.57
15.1
0.00107
146
484
0.0344
2.89
9.56
0.000679
2.34
7.75
0.000551
1.99
6.58
0.000468
3,082
10,200
0.725
O-M29-2
2,510
3,834
0.518
4.98
7.61
0.00103
2.80
4.28
0.000579
15.0
22.9
0.00310
2.15
3.28
0.000444
1.83
2.80
0.000378
1.20
1.83
0.000247
2,953
4,511
0.610
O-M29-3
475
786
0.101
17.1
28.2
0.00362
1.99
3.29
0.000422
30.1
49.8
0.00639
1.57
2.61
0.000334
0.660
1.09
0.000140
0.380
0.628
0.0000805
862
1,426
0.183
O-M29-4
324
530
0.0698
5.61
9.17
0.00121
ND
ND
ND
18.5
30.3
0.00400
1.59
2.60
0.000343
0.562
0.919
0.000121
0.462
0.756
0.0000996
781
1,277
0.168
Average
1,573
3,756
0.348
8.12
15.2
0.00175
2.80
6.43
0.000618
52.4
147
0.0120
2.05
4.51
0.000450
1.35
3.14
0.000298
1.01
2.45
0.000224
1,919
4,353
0.421
' Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm, adjusted to 7% O2.
0 Pounds per hour.
-------
TABLE 2.8
PARTICULATE MATTER AND METALS REMOVAL EFFICIENCIES
CUPOLA WET SCRUBBER
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Test Set No.
Date
PM Emission Rate, lb/hr:a
Inlet
Outlet
Removal Efficiency, %: b
Total Metals Emission Rate, lb/hr:a
Inlet
Outlet
Removal Efficiency, %: b
M29-1
9/23/97
139
8.08
94.2
20.0
1.57
92.2
M29-2
9/24/97
169
7.61
95.5
21.0
1.22
94.2
M29-3
9/25/97
186
1.71
99.1
23.3
0.330
98.6
M29-4
9/25/97
215
1.71
99.2
27.8
0.263
99.1
Average
177
4.78
97.3
23.0
0.846
96.0
1 Pounds per hour.
b Percent removal efficiencies are calculated using the emission rates (Ib/hr).
-------
TABLE 2.9
PCDDS/PCDFS EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm '
Sample Volume:
dscf"
dscrn0
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfm"
dscfm*
dscmm'
Isokinetic Sampling Ratio, %
O-23-1
9/23/97
110
0.499
54.895
1.554
125
16.7
4.0
12.2
65,300
51,600
1,460
93.0
O-23-2
9/24/97
240
0.629
151.041
4.277
133
11.8
10.6
16.2
73,600
54,900
1,560
101.5
O-23-3
9/25/97
240
0.904
217.061
6.146
110
12.5
9.7
8.7
64,600
53,200
1,510
103.4
O-23-4
9/25/97
240
0.925
221.977
6.286
108
12.4
10.3
8.5
66,500
55,200
1,560
102.0
Average
208
0.739
161.244
4.566
119
13.4
8.7
11.4
67,500
53,700
1,520
100.0
" Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
0 Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
" Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
-------
CO2,13.4% O2, and 11.4% moisture. The average exhaust gas volumetric flow rate was 67,500
acfrn or 53,700 dscfin (1,520 dscmm).
The EPA Method 23 sample extracts were first analyzed using a DB-5 capillary column
to determine the concentration of each isomer of PCDDs and PCDFs (tetra- through octa-).
Tetra-chlorinated dibenzofurans were detected in this analysis; therefore, another aliquot of the
sample was analyzed using a DB-225 capillary column to measure the 2,3,7,8 tetra-chloro
dibenzofuran isomer (2378 TCDF).
Some PCDDs/PCDFs catch weights were reported as estimated maximum possible
concentration or EMPCs. Catch weights, concentrations, and emission rates based on EMPC
values were noted by enclosing them in brackets ({}). EMPC values were included in the four-
run averages and total PCDDs/PCDFs calculations. Averages or totals that were based on EMPC
values were also enclosed in brackets to indicate the values were estimated. The PCDDs/PCDFs
test results are presented in actual concentrations and mass emission rates, concentrations
adjusted to 7% O2, and concentrations adjusted to 7% O2 in 2378 TCDF toxic equivalents.
Table 2.10 presents the PCDDs/PCDFs stack gas concentrations and emission rates. The
average concentration of total PCDDs was estimated to be {1.68} ng/dscm. The average
concentration of total PCDFs was estimated to be {14.1} ng/dscm. The average concentration of
total PCDDs/PCDFs was estimated to be {15.8} ng/dscm. These values corresponded to average
estimated emission rates of {152}, {1,290}, and {1,442} ng/hr, respectively.
Table 2.11 presents the PCDDs/PCDFs concentrations adjusted to 7% O2. The average
measured stack gas O2 concentration was 13.4%. The average adjusted concentration of total
PCDDs was estimated to be {3.70} ng/dscm @ 7% O2. The average adjusted concentration of
total PCDFs was estimated to be {29.6} ng/dscm @ 7% O2. The average adjusted concentration
of total PCDDs/PCDFs was {33.3} ng/dscm @ 7% O2. The concentrations, adjusted to 7% O2,
were also adjusted by each congener's respective Toxic Equivalent Factor (TEF). The TEFs
used were the international TEF values. The average concentration for total PCDDs/PCDFs,
adjusted for the 2378 TCDD TEFs, was estimated to be {0.436} ng/dscm @ 7% O2.
2.4 SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS
The semivolatile organic hazardous air pollutants (SVOHAPs) were collected using a
SW-846 Method 0010 Modified Method 5 (MM5) sampling train. The MM5 sampling train
collects organic-laden particulate materials and semi-volatile organics species. This method
speciates and quantitates low concentrations of these semi-volatile organics with boiling points
above 100°C.
Table 2.12 summarizes the SVOHAPs emissions sampling and exhaust gas parameters at
the cupola wet scrubber outlet. The total sampling time was 110 minutes for Run 1 and 240
minutes for the additional three runs. The average sample volume was 162.319 dscf or 4.596
-------
TABLE 2.10
PCDDS/PCDFS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
CONGENER
DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total CDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total CDFs
Total CDDs + CDFs
CONCENTRATION "
ng/dscm, as measured
O-23-1
{0.0322}
1.74
0.045
0.540
0.0129
{0.0129}
0.0193
0.122
0.0129
0.0129
0.0193
{2.43}
0.46
12.3
0.232
0.244
3.92
0.103
0.0450
0.0322
(ND)
0.444
{0.0450}
(ND)
0.0257
{0.00643}
{16.7}
{19.1}
O-23-2
0.0491
1.54
0.0538
0.561
0.0164
0.0187
0.0257
0.257
{0.0281}
0.0327
{0.0210}
{2.42}
0.54
14.0
0.327
0.327
5.66
0.213
0.108
0.0608
{0.00935}
1.10
{0.0701}
{0.0117}
0.0234
0.00935
{20.8}
{23.2}
O-23-3
0.0212
0.667
0.0163
0.120
(ND)
(ND)
(ND)
0.0390
(ND)
(ND)
{0.00651}
{0.833}
0.293
8.33
0.106
0.0765
1.74
0.0293
0.0146
0.00813
(ND)
0.150
0.00651
(ND)
0.00651
{0.00488}
{10.2}
{11.1}
0-23-4
0.0191
0.732
0.0159
0.207
0.00318
0.00477
0.00636
0.0652
{0.00477}
0.00477
0.0127
{1.02}
0.207
6.84
0.0970
0.0827
1.80
0.0414
0.0175
0.00955
(ND)
0.191
0.0111
(ND)
0.0111
{0.00159}
{8.84}
{9.86}
Average
{0.0304}
1.17
0.033
0.357
0.00810
0.00909
0.0128
0.121
0.0114
0.0126
{0.0149}
{1.68}
0.38
10.4
0.190
0.183
3.28
0.0966
0.0462
0.0277
0.00234
0.471
{0.0332}
0.00292
0.0167
{0.00556}
{14.1}
{15.8}
EMISSION RATE b
jig/hr
O-23-1
{2.82}
152
3.94
47.3
1.13
1.13
1.69
10.7
1.13
1.13
1.69
{213}
41
1,076
20.3
21.4
344
9.02
3.94
2.82
(ND)
38.9
{3.94}
(ND)
2.25
{0.564}
{1,462}
{1,675}
O-23-2
4.58
144
5.02
52.4
1.53
1.75
2.40
24.0
{2.62}
3.05
{1.96}
{225}
50
1,309
30.5
30.5
528
19.9
10.0
5.67
{0.87}
103
{6.55}
{1.09}
2.18
0.87
{1,943}
{2,168}
O-23-3
1.91
60.3
1.47
10.9
(ND)
(ND)
(ND)
3.53
(ND)
(ND)
{0.589}
{75.3}
26.5
753
9.56
6.92
157
2.65
1.32
0.736
(ND)
13.5
0.589
(ND)
0.589
{0.441}
{925}
{1,001}
O-23-4 (Average
1.79
68.6
1.49
19.4
{0.298}
0.447
0.597
6.12
{0.447}
0.447
1.19
{95.8}.
19.4
641
9.10
7.76
169
3.88
1.64
0.895
(ND)
17.9
1.04
(ND)
1.04
{0.149}
{829}
{925}
{2.78}
106
2.98
32.5
{0.74}
0.83
1.17
11.1
{1.05}
1.16
{1.36}
{152}
34
945
17.4
16.7
299
8.85
4.24
2.53
{0.218}
43.2
{3.03}
{0.273}
1.52
{0.507}
{1,290}
{1,442}
" Nanogram per dry standard cubic meter at 20°C and 1 atm.
b Micrograms per hour.
(ND) Non Detectable - Results are below target analyte detection limits. ND values are used as zeroes (0) in totals and averages.
{ } Estimated Maximum Possible Concentration. EMPC values are used as reported in totals and averages.
-------
TABLE 2.11
PCDDS/PCDFS EXHAUST GAS CONCENTRATIONS AND 2378 TOXIC EQUIVALENT
STACK GAS CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
CONGENER
DIOXINS:
2378 TCDD
Total TCDD
I2378PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
1 2346789 OCDD
Total CDDs
FURANS:
2378 TCDF
Total TCDF
12378PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1 234678 HpCDF
1 234789 HpCDF
Total HpCDF
1 2346789 OCDF
Total CDFs
Total CDDs + CDFs
CONCENTRATION
(ng/dscm, adjusted to 7% O2)
O-23-1
(0.106)
5.75
0.149
1.79
0.0426
{0.0426}
0.0639
0.405
0.0426
0.0426
0.0639
(8.05)
1.53
40.7
0.766
0.809
13.0
0.341
0.149
0.106
(ND)
1.47
(0.149)
(ND)
0.0852
(0.0213)
(55.2)
(63.3)
O-23-2
0.0750
2.36
0.0821
0.857
0.0250
0.0286
0.0393
0.393
(0.0429)
0.0500
(0.0321)
(3.69)
0.82
21.4
0.500
0.500
8.64
0.325
0.164
0.0929
(0.0143)
1.68
(0.107)
(0.0179)
0.0357
0.0143
(31.8)
(35.5)
O-23-3
0.0350
1.10
0.0269
0.199
(ND)
(ND)
(ND)
0.0646
(ND)
(ND)
(0.0108)
(1.38)
0.48
13.8
0.175
0.127
2.88
0.0485
0.0242
0.0135
(ND)
0.248
0.0108
(ND)
0.0108
(0.00808)
(16.9)
(18.3)
O-23-4
0.0312
1.20
0.0260
0.338
0.00520
0.00780
0.0104
0.107
(0.00780)
0.00780
0.0208
(1.67)
0.34
11.2
0.159
0.135
2.94
0.0676
0.0286
0.0156
(ND)
0.312
0.0182
(ND)
0.0182
(0.00260)
(14.5)
(16.1)
Average
(0.0619)
2.60
0.0710
0.796
0.0182
(0.0193)
0.0284
0.242
(0.0233)
0.0335
(0.0319)
(3.70)
0.79
21.8
0.400
0.393
6.86
0.195
0.0915
0.0571
(0.00358)
0.927
(0.0713)
(0.00448)
0.0375
(0.0116)
(29.6)
(33.3)
2378-
TCDD*
Toxic
Equivalent
Factor
1.00
0.500
0.100
0.100
0.100
0.0100
0.00100
0.100
0.0500
0.500
0.100
0.100
0.100
0.100
0.0100
0.0100
0.00100
2378 TOXIC EQUIVALENT
(ng/dscm, adjusted to 7% O2)
O-23-1
(0.106)
0.0745
0.00426
(0.00426)
0.00639
0.000426
0.0000639
(0.196)
0.153
0.0383
0.405
0.0341
0.0149
0.0106
(ND)
(0.00149)
(ND)
(0.0000213)
(0.66)
(0.85)
O-23-2
0.0750
0.0411
0.00250
0.00286
0.00393
(0.000429)
(0.0000321)
(0.126)
0.082
0.0250
0.250
0.0325
0.0164
0.00929
(0.00143)
(0.00107)
(0.000179)
0.0000143
(0.418)
(0.544)
O-23-3
0.0350
0.0135
(ND)
(ND)
(ND)
(ND)
(0.0000108)
(0.0485)
0.048
0.00875
0.0633
0.00485
0.00242
0.00135
(ND)
0.000108
(ND)
(0.00000808)
(0.129)
(0.178)
O-23-4
0.0312
0.0130
0.000520
0.000780
0.00104
(0.0000780)
0.0000208
(0.0467)
0.034
0.00793
0.0676
0.00676
0.00286
0.00156
(ND)
0.000182
(ND)
(0.00000260)
(0.121)
(0.167)
Average
(0.0619)
0.0355
0.00182
(0.00198)
0.00284
(0.000233)
(0.0000319)
(0.104)
0.079
0.0200
0.196
0.0195
0.00915
0.00571
(0.000357)
(0.000713)
(0.0000446)
(0.0000116)
(0.331)
(0.436)
• Nanogram per dry standard cubic meter adjusted to 7 percent oxygen at 20°C and 1 atm.
b North Atlantic Treaty Organization, Committee on the challenges of Modern Society. Pilot study on International Information Exchange
on Dioxins and Related Compounds: International Toxicity Equivalency Factor (I-TEF) Methods of Risk Assessment for Complex
Mixtures of Dioxins and Related Compounds. Report No. 176, August 1988.
(ND) Non Detectable - Results are below target analyte detection limits. ND values are used as zeroes (0) in totals and averages.
{ } Estimated Maximum Possible Concentration. EMPC values are used as reported in totals and averages.
-------
TABLE 2.12
SVOHAPS EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfhi a
Sample Volume:
dscfb
dscmc
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Vloisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfhid
dscfm"
dscmm6
Isokinetic Sampling Ratio, %
O-0010-1
9/23/97
110
0.640
70.444
1.995
125
16.7
4.0
12.7
74,600
58,600
1,660
98.4
O-0010-2
9/24/97
240
0.636
152.632
4.322
135
11.8
10.6
16.6
76,400
56,600
1,600
101.2
O-0010-3
9/25/97
240
0.881
211.429
5.987
111
12.5
9.7
9.3
64,400
52,700
1,490
101.1
O-0010-4
9/25/97
240
0.895
214.771
6.082
111
12.4
10.3
9.2
65,600
53,700
1,520
100.8
Average
0.763
162.319
4.596
121
13.4
8.7
11.9
70,300
55,400
1,570
100.4
• Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
-------
dcsm. The average exhaust gas temperature was 121 °F. The exhaust gas contained 8.7% CO2,
13.4% O2, and 11.9% moisture. The average exhaust gas volumetric flow rate was 70,300 acfm
or 55,400 dscrm or 1,570 dscmm.
The results of the semivolatile organic emissions are shown in Table 2.13. Analysis was
performed for 70 target compounds. Of these 70 target compounds, 45 were not detected on any
of the four sample runs. In cases where a compound was not detected, the emission rate, and
concentration, was replaced with a "ND". If a compound was not detected in one of the four
runs, a zero was used in the four-run average for that compound and was not summed in any
SVOHAPs totals. Table 2.14 lists the target SVOHAPs detection limits. Compounds that were
detected are indicated with a "D".
Analysis for the SVOHAPs was performed using SW-846 Method 8270. The lower
quantitation limit for SW-846 Method 8270 for all but four compounds was 10 ug/sample. The
four compounds, 2,4-dinitrophenol, 4-nitrophenol, 4,6-dinitro-2-methylphenol and
pentachlorophenol, had quantitation limits of 25 jig/sample. Some samples had reported values
below the quantitation limit but above the detection limit. This was the case for 19 of the 25
detected target compounds. Like the PCDDs/PCDFs, these values were reported as estimates
and all values and calculated results were enclosed by brackets ({}) to indicate that the
compound was detected but was below the quantitation limit. These estimated values were used
in the four-run averages and the resulting averages were also enclosed in brackets to indicate the
values were estimated.
Three compounds were detected in the run samples that were also detected in the
laboratory blank. Naphthalene, acetophenone, 2-chloroacetophenone, di-n-butylphthalate, and
bis(2-ethylhexyl)phthalate were detected in the method blank, but at amounts below the
quantitation limit. TLFs case narrative advises that target analytes in the laboratory blanks
should not be considered as truly present in the native samples unless found at five times the
amount found in the blank. In the case of di-n-butylphthalate, all four run samples had estimated
amounts that were greater than five times the blank and therefore should be considered truly
present in the native samples. In the case of acetophenone, only the third run had an estimated
amount slightly higher than five times the estimated lab blank value. In the case of bis(2-
ethylhexyl) phthalate, all four run samples had estimated catches that were more than five times
the estimated lab blank value. In the case of naphthalene, all four run samples estimated catches
were more than five times that of the estimated blank value. In the case of 2-
chloroacetophenone, all four samples had values at non-detectable limits. The TLI's case
narrative also advises that "in the event that the amount of a target analyte found in the samples is
twenty times the amount found in the associated blank, the contribution from the blank can be
considered negligible." The estimated amount of bis(2-ethylhexyl) phthalate in the second and
third run's sample were greater than 20 times the estimated blank value. Refer to Table 6.16 in
Section 6.0 for'a complete listing of all the detected or estimated SW-846 Method 0010 field,
method, and laboratory blanks compared to the average sample catch weights.
-------
TABLE 2.13
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Acenaphthene
Concentration, ppbvd"
Emission Rate, lb/hrb
Acenaphthylene
Concentration, ppbvd'
Emission Rate, lb/hrb
Acetophenone
Concentration, ppbvd"
Emission Rate, lb/hrb
4-Aminobiphenyl
Concentration, ppbvd"
Emission Rate, lb/hrb
Aniline
Concentration, ppbvd "
Emission Rate, lb/hrb
o-Anisidine
Concentration, ppbvd'
Emission Rate, lb/hrb
Anthracene
Concentration, ppbvd"
Emission Rate, lb/hrb
Benzidine
Concentration, ppbvd"
Emission Rate, lb/hrb
Benzo(a)anthracene
Concentration, ppbvd"
Emission Rate, lb/hrb
Benzo(b)fluoranthene
Concentration, ppbvd °
Emission Rate, lb/hrb
O-0010-1
9/23/97
1415-1847
2.19E-02
3.08E-05
{6.33E-02}
{8.91E-05}
8.22E-01
9.01E-04
ND
ND
ND
ND
ND
ND
1.76E-02
2.86E-05
ND
ND
ND
ND
ND
ND
O-0010-2
9/24/97
0851-1400
ND
ND
2.31E-02
3.14E-05
4.14E-01
4.38E-04
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-3
9/25/97
0844-1321
2.45E-02
3.10E-05
{5.58E-02}
{7.05E-05}
4.53E-01
4.47E-04
ND
ND
{1.38E-02}
{1.05E-05}
ND
ND
7.66E-03
1.12E-05
ND
ND
ND
ND
ND
ND
O-0010-4
9/25/97
1443-1919
1.59E-02
2.05E-05
{2.82E-02}
{3.64E-05}
2.86E-01
2.87E-04
ND
ND
ND
ND
ND
ND
6.21E-03
9.26E-06
ND
ND
ND
ND
ND
ND
Average
1.56E-02
2.06E-05
{4.26E-02}
{5.68E-05}
4.94E-01
5.18E-04
ND
ND
{3.45E-03}
{2.64E-06}
ND
ND
7.87E-03
1.23E-05
ND
ND
ND
ND
ND
ND
-------
TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Benzo(k)fluoranthene
Concentration, ppbvd*
Emission Rate, lb/hrb
Benzo(ghi)perylene
Concentration, ppbvd*
Emission Rate, lb/hrb
3enzo(a)pyrene
Concentration, ppbvd*
Emission Rate, lb/hrb
Benzo(e)pyrene
Concentration, ppbvd*
Emission Rate, lb/hrb
Benzyl Chloride
Concentration, ppbvd'
Emission Rate, lb/hrb
Biphenyl
Concentration, ppbvd*
Emission Rate, lb/hrb
2-Chloroacetophenone
Concentration, ppbvd'
Emission Rate, lb/hrb
bis-(2-Chloroethyl)ether
Concentration, ppbvd "
Emission Rate, lb/hrb
2-Chloronaphthalene
Concentration, ppbvd"
Emission Rate, lb/hrb
Chrysene
Concentration, ppbvd*
Emission Rate, lb/hrb
Cumene
Concentration, ppbvd a
Emission Rate, Ib/hr b
O-0010-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.67E-01}
{2.34E-04}
ND
ND
ND
ND
ND
ND
{1.16E-02}
{2.42E-05}
ND
ND
O-0010-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{4.40E-02}
{5.98E-05}
ND
ND
ND
ND
ND
ND
ND
ND
{2.59E-02}
{2.75E-05}
0-0010-3
ND
ND
ND
ND
ND
ND
ND
ND
{7.20E-02}
{7.48E-05}
{1.33E-01}
{1.68E-04}
ND
ND
ND
ND
ND
ND
ND
ND
{5.21E-02}
{5.14E-05}
0-0010-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{6.41E-02}
{8.26E-05}
ND
ND
ND
ND
ND
ND
ND
ND
{1.48E-02}
{1.49E-05}
Average
ND
ND
ND
ND
ND
ND
ND
ND
{1.80E-02}
{1.87E-05}
{1.02E-01}
{1.36E-04}
ND
ND
ND
ND
ND
ND
{2.91E-03}
{6.05E-06}
{2.32E-02}
{2.34E-05}
-------
TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
!)ibenz(a,h)anthracene
Concentration, ppbvd'
Emission Rate, lb/hrb
Dibenzofuran
Concentration, ppbvd "
Emission Rate, lb/hrb
1 ,2-Dibromo-3-chloropropane
Concentration, ppbvd '
Emission Rate, lb/hrb
Di-n-butylphthalate
Concentration, ppbvd '
Emission Rate, lb/hrb
1 ,4-Dichlorobenzene
Concentration, ppbvd "
Emission Rate, lb/hrb
3,3'-Dichlorobenzidine
Concentration, ppbvd*
Emission Rate, lb/hrb
!^,N-Diethylaniline
Concentration, ppbvd'
Emission Rate, lb/hrb
3,3'-Dimethoxybenzidine
Concentration, ppbvd "
Emission Rate, lb/hrb
Dimethylaminoazobenzene .
Concentration, ppbvd "
Emission Rate, lb/hrb
N,N-Dimethylaniline
Concentration, ppbvd'
Emission Rate, lb/hrb
3 ,3 '-Dimethylbenzidine
Concentration, ppbvd'
Emission Rate, lb/hrb
O-0010-1
ND
ND
ND
ND
ND
ND
{4.15E-01}
{1.05E-03}
{5.99E-02}
{8.03E-05}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0-0010-2
ND
ND
ND
ND
ND
ND
{1.77E-01}
{4.33E-04}
{3.10E-02}
{4.02E-05}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-3
ND
ND
{5.95E-02}
{8.21E-05}
ND
ND
{1.25E-01}
{2.86E-04}
{3.50E-02}
{4.22E-05}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-4
ND
ND
{2.94E-02}
{4.13E-05}
ND
ND
{8.31E-02}
{1.93E-04}
{3.50E-02}
{4.30E-05}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
{2.22E-02}
{3.09E-05}
ND
ND
{2.00E-01}
{4.92E-04}
{4.02E-02}
{5.14E-05}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Dimethylphthalate
Concentration, ppbvd'
Emission Rate, lb/hrb
4,6-Dinitro-2-methylphenol
Concentration, ppbvd "
Emission Rate, lb/hrb
2,4-Dinitrophenol
Concentration, ppbvd "
Emission Rate, lb/hrb
2,4-Dinitrotoluene
Concentration, ppbvd1
Emission Rate, lb/hrb
bis(2-Ethylhexyl)phthalate
Concentration, ppbvd'
Emission Rate, lb/hrb
Fluoranthene
Concentration, ppbvd'
Emission Rate, lb/hrb
Fluorene
Concentration, ppbvd'
Emission Rate, lb/hrb
Hexachlorobenzene
Concentration, ppbvd'
Emission Rate, lb/hrb
Hexachlorobutadiene
Concentration, ppbvd'
Emission Rate, lb/hrb
Hexachlorocyclopentadiene
Concentration, ppbvd"
Emission Rate, lb/hrb
Hexachloroethane
Concentration, ppbvd '
Emission Rate, lb/hrb
O-0010-1
{1.55E-01}
{2.74E-04}
ND
ND
ND
ND
ND
ND
3.41E-01
1.22E-03
{5.72E-02}
{1.06E-04}
{6.82E-02}
{1.03E-04}
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-2
{5.42E-02}
{9.26E-05}
ND
ND
ND
ND
ND
ND
{2.89E-01}
{9.94E-04}
3.77E-02
6.72E-05
2.04E-02
2.99E-05
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-3
{4.61E-02}
{7.35E-05}
ND
ND
ND
ND
ND
ND
2.18E-01
6.99E-04
{1.71E-02}
{2.84E-05}
{3.21E-02}
{4.38E-05}
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-4
{2.91E-02}
{4.73E-05}
ND
ND
ND
ND
ND
ND
9.26E-02
3.02E-04
{1.78E-02}
{3.01E-05}
{1.83E-02}
{2.55E-05}
ND
ND
ND
ND
ND
ND
ND
ND
Average
{7.10E-02}
{1.22E-04}
ND
ND
ND
ND
ND
ND
{2.35E-01}
{8.03E-04}
{3.25E-02}
{5.78E-05}
{3.48E-02}
{5.06E-05}
ND
ND
ND
ND
ND
ND
ND
ND
-------
TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
lun No.
lydroquinone
Concentration, ppbvd'
Emission Rate, lb/hrb
ndeno(l,2,3-cd)pyrene
Concentration, ppbvd "
Emission Rate, lb/hrb
sophorone
Concentration, ppbvd'
Emission Rate, lb/hrb
VIethylene bis-chloroaniline
Concentration, ppbvd'
Emission Rate, lb/hrb
4,4'-Methylenedianiline
Concentration, ppbvd "
Emission Rate, lb/hrb
2-Methylnaphthalene
Concentration, ppbvd '
Emission Rate, lb/hrb
2-Methylphenol
Concentration, ppbvd'
Emission Rate, lb/hrb
3/4-Methylphenol
Concentration, ppbvd'
Emission Rate, lb/hrb
Naphthalene
Concentration, ppbvd'
Emission Rate, lb/hrb
Nitrobenzene
Concentration, ppbvd '
Emission Rate, lb/hrb
4-Nitrobiphenyl
Concentration, ppbvd'
Emission Rate, lb/hrb
O-0010-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{2.17E+00}
{2.81E-03}
ND
ND
ND
ND
2.35E+00
2.74E-03
ND
ND
ND
ND
O-0010-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{8.75E-01}
{1.10E-03}
ND
ND
ND
ND
{1.22E+00}
{1.38E-03}
ND
ND
ND
ND
O-0010-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{3.86E+00}
{4.51E-03}
8.03E-02
7.12E-05
ND
ND
2.89E+00
3.04E-03
ND
ND
ND
ND
O-0010-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.63E+00}
{1.93E-03}
2.56E-02
2.31E-05
3.62E-02
3.27E-05
1.42E+00
1.52E-03
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{2.13E+00}
{2.59E-03}
2.65E-02
2.36E-05
9.05E-03
8.18E-06
{1.97E+00}
{2.17E-03}
ND
ND
ND
ND
-------
TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
*un No.
4-Nitrophenol
Concentration, ppbvd '
Emission Rate, lb/hrb
n-Nitrosodimethylamine
Concentration, ppbvd *
Emission Rate, lb/hrb
n-Nitrosomorpholine
Concentration, ppbvd "
Emission Rate, lb/hrb
Jentachloronitrobenzene
Concentration, ppbvd *
Emission Rate, lb/hrb
'entachlorophenol
Concentration, ppbvd '
Emission Rate, lb/hrb
Perylene
Concentration, ppbvd '
Emission Rate, lb/hrb
Phenanthrene
Concentration, ppbvd "
Emission Rate, lb/hrb
Phenol
Concentration, ppbvd *
Emission Rate, lb/hrb
1 ,4-Phenylenediamine
Concentration, ppbvd "
Emission Rate, lb/hrb
Pyrene
Concentration, ppbvd "
Emission Rate, lb/hrb
o-Toluidine
Concentration, ppbvd *
Emission Rate, lb/hrb
O-0010-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.40E-01}
{2.28E-04}
8.42E-01
7.23E-04
ND
ND
7.04E-02
1.30E-04
ND
ND
O-0010-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{3.62E-02}
{5.69E-05}
{2.08E+00}
{1.72E-03}
ND
ND
4.57E-02
8.14E-05
ND
ND
0-0010-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{3.99E-02}
{5.84E-05}
{4.73E-01}
{3.66E-04}
ND
ND
2.09E-02
3.46E-05
ND
ND
O-0010-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{2.60E-02}
{3.87E-05}
{8.17E-01}
{6.43E-04}
ND
ND
1.92E-02
3.24E-05
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{6.05E-02}
{9.54E-05}
{1.05E+00}
{8.63E-04}
ND
ND
3.90E-02
6.95E-05
ND
ND
-------
TABLE 2.13 (Concluded)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
1 ,2,4-Trichlorobenzene
Concentration, ppbvd*
Emission Rate, Ib/hr b
2,4,5-Trichlorophenol
Concentration, ppbvd"
Emission Rate, Ib/hr b
2,4,6-Trichlorophenol
Concentration, ppbvd8
Emission Rate, Ib/hr b
a,a,a-Trichlorotoluene
Concentration, ppbvd*
Emission Rate, Ib/hr b
Trifluralin
Concentration, ppbvd"
Emission Rate. Ib/hr b
O-0010-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-2
ND
ND
ND
ND
{1.10E-02}
{1.91E-05}
ND
ND
ND
ND
O-0010-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
O-0010-4
{2.81E-02}
{4.26E-05}
ND
ND
ND
ND
ND
ND
ND
ND
Average
{7.03E-03}
{1.07E-05}
ND
ND
{2.75E-03}
{4.78E-06}
ND
ND
ND
ND
" Parts per billion by volume, dry basis.
b Pounds per hour.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{} Estimate - Analyte results are below the quantitation limit and above the detection limit. Values are counted in the averages.
-------
TABLE 2.14
SVOHAPS DETECTION LIMITS, PPBVD
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Acenaphthene
Acenaphthylene
Acetophenone
i-Aminobiphenyl
Aniline
o-Anisidine
Anthracene
ienzidine
3enzo(a)anthracene
3enzo(b)fluoranthene
3enzo(k)fluoranthene
3enzo(ghi)perylene
Benzo(a)pyrene
3enzo(e)pyrene
Benzyl Chloride
Biphenyl
2-Chloroacetophenone
bis-(2-Chloroethyl)ether
2-Chloronaphthalene
Chrysene
Cumene
Dibenz(a,h)anthracene
Dibenzofuran
1 ,2-Dibromo-3-chloropropane
Di-n-butylphthalate
1 ,4-Dichlorobenzene
3,3'-Dichlorobenzidine
^.N-Diethylaniline
3 ,3 '-Dimethoxybenzidine
Dimethylaminoazobenzene
!>J,N-Dimethylaniline
3,3'-Dimethylbenzidine
Dimethylphthalate
4,6-Dinitro-2-methylphenol
O-0010-1
9/23/97
1415-1847
D
D
D
2.92E-02
6.47E-02
8.91E-02
D
2.16E-02
1.27E-02
9.56E-03
9.56E-03
8.73E-03
l.OOE-02
8.60E-03
3.72E-02
D
2.73E-02
9.02E-02
3.19E-02
D
3.81E-02
1.04E-02
2.37E-02
7.24E-02
D
D
2.86E-02
4.12E-02
4.05E-02
3.80E-02
4.98E-02
2.33E-02
D
1.70E-01
O-0010-2
9/24/97
0851-1400
1.59E-02
D
D
1.22E-02
2.99E-02
4.16E-02
8.74E-03
7.85E-03
4.63E-03
3.31E-03
3.53E-03
3.22E-03
3.53E-03
3.09E-03
1.71E-02
D
1.26E-02
4.16E-02
1.47E-02
4.63E-03
D
3.80E-03
1.09E-02
3.37E-02
D
D
1.06E-02
1.90E-02
1.46E-02
1.38E-02
2.30E-02
8.39E-03
D
7.84E-02
0-0010-3
9/25/97
0844-1321
D
D
D
9.97E-03
D
3.20E-02
D
7.20E-03
4.22E-03
3.03E-03
3.18E-03
2.76E-03
3.18E-03
2.87E-03
D
D
9.88E-03
3.20E-02
1.09E-02
4.40E-03
D
3.32E-03
D
2.58E-02
D
D
9.52E-03
1.48E-02
1.33E-02
1.27E-02
1.79E-02
7.76E-03
D
5.90E-02
O-0010-4
9/25/97
1443-1919
D
D
D
8.18E-03
1.95E-02
2.76E-02
D
5.58E-03
3.29E-03
2.51E-03
2.66E-03
2.29E-03
2.66E-03
2.35E-03
1.12E-02
D
8.44E-03
2.74E-02
9.73E-03
3.29E-03
D
2.84E-03
D
2.21E-02
D
D
7.34E-03
1.27E-02
1.04E-02
9.83E-03
1.53E-02
5.96E-03
D
5.19E-02
Average
1.59E-02
D
D
1.49E-02
3.81E-02
4.76E-02
8.74E-03
1.06E-02
6.21E-03
4.60E-03
4.73E-03
4.25E-03
4.85E-03
4.23E-03
2.18E-02
D
1.46E-02
4.78E-02
1.68E-02
4.11E-03
3.81E-02
5.09E-03
1.73E-02
3.85E-02
D
D
1.40E-02
2.19E-02
1.97E-02
1.86E-02
2.65E-02
1.14E-02
D
8.99E-02
-------
TABLE 2.14 (Concluded)
SVOHAPS DETECTION LIMITS, PPBVD
CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
2,4-Dinitrophenol
2,4-Dinitrotoluene
bis(2-Ethylhexyl)phthalate
rluoranthene
Fluorene
lexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
lexachloroethane
tydroquinone
ndeno( 1 ,2,3 -cd)pyrene
Isophorone
Methylene bis-chloroaniline
4,4'-Methylenedianiline
2-Methylnaphthalene
2-Methylphenol
3/4-Methylphenol
Naphthalene
Nitrobenzene
4-Nitrobiphenyl
4-Nitrophenol
n-Nitrosodimethylamine
n-Nitrosomorpholine
Pentachloronitrobenzene
Pentachlorophenol
Perylene
Phenanthrene
Phenol
1 ,4-Phenylenediamine
Pyrene
o-Toluidine
1 ,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
a,a,a-Trichlorotoluene
Trifluralin
O-0010-1
2.46E-01
9.33E-02
D
D
D
4.19E-02
6.24E-02
6.68E-02
6.98E-02
8.32E-02
7.48E-03
3.84E-02
6.32E-02
4.87E-02
D
9.59E-02
8.48E-02
D
5.09E-02
6.42E-02
1.49E-01
2.43E-01
1.50E-01
1.56E-01
7.92E-02
9.56E-03
D
D
8.03E-02
D
5.85E-02
5.52E-02
7.39E-02
7.88E-02
3.95E-02
7.52E-02
O-0010-2
1.13E-01
4.31E-02
D
D
D
1.72E-02
2.90E-02
3.06E-02
3.22E-02
3.89E-02
2.68E-03
1.77E-02
2.29E-02
1.77E-02
D
4.43E-02
3.91E-02
D
2.35E-02
3.39E-02
6.84E-02
1.13E-01
6.90E-02
6.43E-02
3.25E-02
3.53E-03
D
D
3.76E-02
D
2.70E-02
2.55E-02
3.41E-02
D
1.82E-02
3.45E-02
O-0010-3
8.51E-02
3.24E-02
D
D
D
1.41E-02
2.23E-02
2.31E-02
2.48E-02
2.99E-02
2.35E-03
1.37E-02
2.09E-02
1.62E-02
D
D
4.24E-02
D
1.83E-02
2.79E-02
5.14E-02
8.62E-02
5.33E-02
5.27E-02
2.67E-02
3.03E-03
D
D
2.90E-02
D
2.10E-02
1.97E-02
2.56E-02
2.73E-02
1.42E-02
2.61E-02
O-0010-4
7.48E-02
2.84E-02
D
D
D
1.17E-02
1.93E-02
2.03E-02
2.12E-02
2.59E-02
2.04E-03
1.17E-02
1.61E-02
1.26E-02
D
D
3.62E-02
D
1.57E-02
2.31E-02
4.52E-02
7.42E-02
4.56E-02
4.37E-02
2.21E-02
2.51E-03
D
D
2.49E-02
D
1.81E-02
D
2.24E-02
2.40E-02
1.21E-02
2.29E-02
Average
1.30E-01
4.93E-02
D
D
D
2.12E-02
3.33E-02
3.52E-02
3.70E-02
4.45E-02
3.64E-03
2.04E-02
3.08E-02
2.38E-02
D
7.01E-02
5.06E-02
D
2.71E-02
3.73E-02
7.85E-02
1.29E-01
7.94E-02
7.92E-02
4.01E-02
4.66E-03
D
D
4.29E-02
D
3.12E-02
3.34E-02
3.90E-02
4.34E-02
2.10E-02
3.97E-02
"D" indicates that compound was detected.
-------
2.5 VOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS (VOHAPS)
The volatile organic hazardous air pollutants (VOHAPs) were measured using direct
interface gas chromatography/mass spectrometry at the inlet and outlet sampling locations of the
wet scrubber. Compounds of interest were those that had boiling points below 100° C.
Measurements taken at both locations did not show any target analytes to be in concentrations
above their respective analytical instrument detection limits. Table 2.15 lists the target analytes
and estimated detection limits.
-------
TABLE 2.15
GC/MS TARGET ANALYTES AND
ESTIMATED DETECTION LIMITS
Analyte
Chloromethane
Chloroethane
Methylene Chloride
1 , 1 -dichloroethane
c- 1 2-dichloroethene
1,1,1 -trichloroethane
1 ,2-dichloropropane
1 , 1 ,2-trichloroethane
Dibromochloromethane
Ethylbenzene
p-xylene
1 , 1 ,2,2-tetrachloroethane
Bromomethane
1 , 1 -dichloroethene
t- 1 ,2-dichloroethane
Methyl Ethyl Ketone
1 ,2-dichloroethane
Carbon tetrachloride
Trichloroethene
c- 1 ,2-dichloropropene
t- 1 ,2-chlhloropropene
2-hexanone
Chlorobenzene
Estimated Detection Limit
Parts per Billion (PPB)
50
50
10
25
25
25
25
25
25
10
30
10
50
25
25
500
50
10
25
25
25
500
10
-------
TABLE 2.15 (Concluded)
GC/MS TARGET ANALYTES AND
ESTIMATED DETECTION LIMITS
Analyte
m-xylene
p-xylene
Vinyl chloride
Carbon disulfide
Vinyl acetate
Chloroform
Benzene
Bromodichloromethane
Methyl iso-Butyl Ketone
Toluene
Tetrachloroethylene
Bromoform
Styrene
Estimated Detection Limit
Parts per Billion (PPB)
30
30
250
10
250
10
10'
10
1000
10
10
50
30
-------
3.0 PROCESS DESCRIPTION
3.1 INTRODUCTION
The GM Powertrain Group, part of the General Motors Corporation, operates a foundry in
Saginaw, Michigan named Saginaw Metal Casting Operations (SMCO), which casts grey iron
and aluminum. This foundry was constructed by GM in 1918 and is currently operating three
cupolas and two green sand lines for casting iron along with a melting furnace and one casting
line for aluminum to produce engine blocks for use in GM automobiles. The plant has about
2,000 employees. This section of the test report provides a description of the cupola operation
for iron melting and the casting operation, including pouring, cooling, and shakeout.
3.2 PROCESS DESCRIPTION
3.2.1 Iron Melting in Cupolas
There are three cupolas in operation ("B", "C", and "D"). Cupolas B and C are very
similar and are configured with an afterburner followed by a venturi scrubber (i.e., they burn
"dirty" gas). Cupola D burns the gas after removal of PM by the scrubber. Plant personnel
indicated that Cupolas B and C were more representative of the industry and pointed out that
cupolas configured like D are no longer constructed. Consequently, Cupola B was chosen for
testing, primarily because it had more modern and complete controls and instrumentation.
Cupola B has a diameter of 114 inches and melts at a rate of about 55 tons per hour (tph)
with a blast rate of 21,000 to 23,000 cubic feet per minute (cfm), which makes it among the
largest cupolas in use in the United States. The blast is enriched with O2 at a rate of about 4%.
Figure 3.1 is a simplified schematic of the cupola gas handling system and emission control
equipment.
The cupola is charged with metal scrap, briquettes made from metal shavings, coke, and
limestone at a point that is above the gas take-off. The composition of a typical charge is given
in Table 3.1 and includes six tons of iron. Very few emissions occur from charging because of
the below-charge gas take-off and the maintenance of negative pressure on the cupola. The off
gas from the cupola is removed at about 400 to 500° F and contains 12 to 14% carbon monoxide
(CO). This gas enters a large combustion chamber where the CO is burned at about 1500 to
1600°F. Some heavy and larger size particles settle out in the combustion chamber and are
removed at that point. The hot exhaust gases from the combustion chamber pass through two
recuperators that
-------
Quencher
tb
Off gas
Recuperator
Wet cap
Recuperator
Blast air
Solids
removed
Cooled gas
Scrubber water
CUPOLA
Heated
blast air
X Combustion CuP°fa
/ chamber blower
Solids removed
Venturi
scrubber
Exhaust stack
Cleaned
gas
o
Scrubber water
to wastewater treatment
Exhaust fan
-------
TABLE 3.1
TYPICAL CUPOLA CHARGE MATERIALS
Material
Remelt from foundry15
Steel scrapb
Gray iron bricksb> c
Silicon bricks
Blend bricks (Si, Mn, Cr)
Silicon carbide
Coke
Limestone
Typical range (lbs/charge)a
4,000 to 6,000
3,000 to 4,000
3,000
70 to 105
260 to 300
300
1,400 to 1,500
500
a Typical range observed during the test days.
b Remelt, steel scrap, and gray iron bricks are the sources of iron and total 12,000 Ibs (6 tons) per
charge.
c Gray iron bricks are a pressed material made from borings, shavings, etc.
are used to pre-heat the cupola's blast air to about 1100°F. There is also a cooler available for
additional temperature control as necessary.
From the recuperators, the gas passes through a quencher, which cools the gas and also
removes some of the entrained particulate matter. The gas then enters a venturi scrubber
(manufactured by Air Pollution Industries) that is operated at a pressure drop of about 40 inches
of water and a water flow rate of about 625 gallons per minute. A vacuum is maintained on the
system and the gas is moved by a 1200 hp exhaust fan following the scrubber. The cleaned gas is
exhausted through a stack. The wastewater from the scrubber is sent to a wastewater treatment
recycle system where polymers are added to assist in settling fine particles, and 99% of the water
is recycled to the scrubber (with a 1% blowdown to the city's wastewater treatment facility).
Particulate matter emissions from the scrubber are limited to 0.15 Ib per 1,000 Ib of gas by the
State.
The plant has instrumentation available to monitor several parameters associated with the
emission control system, including the pressure drop across the scrubber, the water flow rate,
electric current to the fan, and gas temperature. Temperature and blast rate for the cupola are
monitored routinely. In addition, an accurate measure of the melting rate (e.g., for use in
-------
normalizing mass emission rates by production rate) can be obtained from the charging data
sheets.
The plant buys scrap from other GM plants and controls the quality because scrap quality
directly affects the quality of the castings. However, plant personnel pointed out that it would be
difficult to have a parameter to measure scrap quality that could be used to make valid
comparisons among different foundries.
3.2.2 Pouring. Cooling and Shakeout
The two iron pouring lines are labeled Lines 3 and 4. Plant personnel indicated that Line
4 was the best candidate for testing because it is newer and the layout is more amenable to
sampling. A simplified schematic of the capture and control equipment for Line 4 is given in
Figure 3.2. The line has a capacity of 270 molds per hour with two engine blocks per mold.
Each horizontal mold contains 3,300 Ibs of green sand (lake sand, sea coal, and bentonite). The
typical properties that are measured and the range during the test days are given in Table 3.2.
The cores used in the molds include both hot box and cold box systems with phenol-
formaldehyde. For the 4-cylinder engine, 15.7 Ibs of hot box cores and 74.5 Ibs of cold box cores
are used for a total core weight of 90.2 Ibs per block or 180.4 Ibs per mold. For the 6-cylinder
engine, 17.9 Ibs of hot box cores and 95.2 Ibs of cold box cores are used for a total core weight of
113 Ibs per block or 226 Ibs per mold. The chemicals used to make the cores are summarized in
Table 3.3. The materials used for core dipping are primarily minerals, such as crystalline silica
(quartz), mica, aluminum silicate, along with graphite, clay and water.
The pouring station for Line 4 is automated and uses six ladles in a circular configuration.
A large, circular side draft hood evacuates the entire pouring area at a rate of about 50,000 cfrn.
During the testing, no significant visible emissions were observed escaping capture from the
pouring operation. The captured emissions are ducted overhead through the roof to the
atmosphere. During the test days, both 4- and 6-cylinder engine blocks were poured on Line 4.
The pouring weight of iron for the 4-cylinder block is 202.8 Ibs to produce a casting of 116.2 Ibs.
For the 6-cylinder block, the pouring weight is 250.4 Ibs and the casting weight is 149.2 Ibs.
The cooling line is enclosed and has a series of hoods throughout the line that evacuate
the enclosures at a rate of about 50,000 cfrn and send the emissions to a bank of pre-coated
cartridge filters to remove particulate matter. The cooling line is evacuated through three main
ducts that send the cooling emissions to three separate sets of cartridge filters. The residence
time of the cooling line is about 25 minutes.
The shakeout operation is totally enclosed in a small, evacuated building (roughly 40 by
60 feet). The room is evacuated at about 150,000 cfrn, and the captured emissions are sent to
three spray scrubbers that have 2 to 3 stages for cleaning.
-------
To atmosphere
(50,000 cfm)
To atmosphere
(150,000 cfm total)
A A A
U)
Circular side
draft hood
From mold
and core
preparation
Pre-c
cartridge
filters--"
To atmosphere
(150,000 cfm total)
A A A
(
1
••V--
i
*
i
7T\
;
S
i
•T-
Spray
scrubbers
T T
Shakeout
40 x 60 ft enclosure
To finishing
-------
TABLE 3.2
TYPICAL RESULTS FROM GREEN SAND ANALYSIS"
Property
Moisture (%)
Clay (%)
Comparability (%)
Green strength (psi)
Permeability (AFS units)
Loss on ignition (%)
Range
2.8 to 3.3
6.8 to 7.4
3.6 to 4.8
164 to 221
114 to 130
3.8 to 5.0
From analyses during the first shift of the test days.
-------
TABLE 3.3
CHEMICALS USED IN CORE MAKING AND MOLD SPRAYING"
Product
Acme
45MR1BS®
Acme 745LF®
Acme-flow 20 12®
Acme-flow
2052A®
Tribonol®
Function
Hot box catalyst
Phenolic resin for hot
box cores
Phenolic resin for cold
box cores
Isocyanate resin for cold
box Part 2
Mold spray
Chemical
Urea
Ammonium hydroxide
Ammonium nitrate
Water
Ammonium chloride
Siloxanes and silicones
Formaldehyde
Phenol
Formaldehyde
Phenol
Ethyl 3-ethoxypropionate
Heavy aromatic solvent naphtha
Diphenylmethane 4,4'-
Diisocyanate
Kerosene
Polymeric Diphenylmethane
Diisocyanate
Isocyanic acid,
methylenediphenylene ester
Heavy aromatic solvent naphtha
Zircon
Diethylene glycol polymer with 1-
chloro-2,3-epoxypropane
Percent
30 to 35
0.1 to 1
10 to 15
45 to 50
0.1 to 1
Ito5
Ito5
5 to 10
0.1 to 1
Ito5
5 to 10
10 to 30
10 to 30
5 to 10
30 to 50
Ito5
10 to 30
90
10
From the manufacturer's material safety data sheets (MSDS).
-------
3.3 PROCESS AND CONTROL DEVICE MONITORING RESULTS
3.3.1 Cupola B
During each test run, several parameters associated with the operation of the cupola and
the Venturi scrubber were monitored and recorded. For the cupola, these parameters included the
blast air flow rate, the relief stack flow rate, the hot blast temperature, oxygen feed pressure, and
the combustion chamber temperature. In addition, information was obtained on each time the
cupola was charged and the charge composition. Each time period was also recorded that the
blast was stopped (and the emission testing was also stopped).
The plant had instrumentation installed to monitor several parameters associated with the
Venturi scrubber, including the water flow rate to the scrubber, flow rate of makeup water, inlet
temperature, inlet pressure, pressure drop, and the pressure (vacuum) at the induced draft fan.
These parameters, with the exceptions noted below, were monitored and recorded during the test.
Before the sampling runs were begun, the process observers worked with the plant personnel to
determine if the instruments indicating venturi pressure drop and water flow rate to the scrubber
were showing correct readings. Calibration of the pressure drop instrumentation, completed
early on September 24, consisted of a direct manometer reading at the venturi followed by
adjustment of the pressure drop reading in the control room. Calibration of the water flow rate
reading could not be confirmed during the sampling campaign. After the testing was completed,
plant personnel confirmed that the instrument had been calibrated and that the water flow rate
was 625 gallons per minute.
Table 3.4 summarizes the major monitoring results for the cupola during each test run,
and Table 3.5 provides the cupola charging data for about 12 hours during each test day. The
blast air temperature and flow rate are plotted for the four test runs in Figures 3.3 and 3.4. The
blast air rate showed very little variability during the test; however, there were significant
differences in the temperature of the hot air blast, which averaged 464 to 488°F during Runs 1
and 2 and 364 to 366°F during Runs 3 and 4.
The pressure drop across the Venturi scrubber increased during each run. At the request
of EPA personnel, adjustments were made after the first test run to increase the scrubber pressure
and to maintain a range closer to the original design specifications. The pressure drop averaged
33, 35, 38, and 42 inches of water for Runs 1, 2, 3, and 4 respectively.
-------
TABLE 3.4
SUMMARY OF CUPOLA MONITORING RESULTS
Parameter
Blast flow rate (cfm)
Hot blast temperature (°F)
Oxygen (psig)
Combustion chamber
temperature (°F)
Melting rate (tons/hr)°
Time blast stopped (min)
Scrubber pressure drop (in. water)
Run
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
Average
21,400
22,100
21,900
21,800
488
464
366
364
30
49
50
59
Range
21,000-22,200
21,800-22,500
21,700-22,800
21,000-22,400
443 - 539
448 - 488
336 - 385
327 - 409
30
43-61
40-65
54-65
not available
1,557
1,518
1,608
38.8
41.7
45.4
43.5
156
6
29
15
33.4
35
38
42
1,401 - 1,669
1,276-1,633
1,495 - 1,670
-
-
-
-
-
~
-
-
33-35
32-37
36-40
40-42
Adjusted for the downtime when the blast was stopped (i.e., the downtime was subtracted from the operating time when
determining the melting rate).
-------
TABLE 3.5
SUMMARY OF CUPOLA CHARGING DURING THE TEST DAYS
9/23/97*
Time period
--
~
~
—
—
—
--
~
~
13:58-14:49
15:51-16:19
18:20-19:12
Average rate
(tons/hr)
Tons charged
~
~
~
—
—
~
~
~
—
48
30
24
38.8
9/24/97
Time period
6:00-7:05
7:13-8:02
8:25-9:14
9:19-10:09
10:14-11:05
11:14-12:05
12:10-13:02
13:20-14:03
14:08-15:12
15:17-16:08
16:21-17:10
17:17-18:18
Average rate
(tons/hr)
Tons charged
54
42
30
42
36
42
42
42
54
42
36
36
40.5
9/25/97
Time period
7:11-8:05
8:11-9:01
9:10-10:07
10:12-11:06
11:10-12:02
12:12-13:03
13:12-14:07
14:18-15:10
15:27-16:02
16:11-17:03
17:12-17:59
18:07-19:10
Average rate
(tons/hr)
Tons charged
42
36
42
42
36
42
42
48
30
42
42
42
40.6
* Run 1 on this day was a short test with 110 minutes of sampling between 14:10 and 18:41.
-------
300
0:00
RUN1
,RUN2
RUN 3
RUN 4
2:00 3:00
RUN TIME
-------
23.0
UJ
i
to
20.0
0:00
1:00
2:00 3:00
RUN TIME
4:00
5:00
6:00
-------
3.3.2 Mold Line 4
During the testing of Line 4, a record was kept of the rate at which the line moved (e.g.,
molds per hour) and pouring was observed to identify when broken molds were not poured and
the temperature of the molten iron when poured. Several observations were made of the time to
"light off after pouring, when the vapors escaping from the mold self-ignited. The first hole
ignited on average about 6 to 8 seconds after pouring, and all holes were lit 11 to 18 seconds
after pouring. During the testing of the scrubbers used on the shakeout operation, the pressure
drop across the scrubbers was recorded and ranged from 13.9 to 16.5 inches of water.
Table 3.6 provides a summary of the number and types of molds that were processed
during each test day from plant records, and Table 3.7 provides a summary of the quantity of iron
poured and the downtime during each hour of the testing days. Table 3.8 contains the mold
counts made by the process observers when testing was being performed. Table 3.9 provides an
estimate of the tons of iron poured per hour and the number of molds poured per hour during the
testing periods on Line 4.
During the testing days, the pouring temperature of the iron was maintained within a
narrow range of 2,743 °F to 2,818 °F. A typical analysis of the iron (from 9/25/97) showed
3.11% carbon, 0.13% sulfur, and 2.28% silicon.
-------
TABLE 3.6
SUMMARY OF NUMBER OF MOLDS POURED ON LINE 4
Hour
(first
shift)
1
2
3
4
5
6
7
8
9b
Number of molds poured"
9/22/97
4-cyl.
223
64
~
~
56
237
37
~
—
~
6-cyl.
--
126
220
185
36
--
46
217
106
—
9/23/97
4-cyl.
224
16
--
—
~
225
205
70
--
—
6-cyl.
—
165
214
208
217
~
—
76
108
--
9/24/97
4-cyl.
152
194
59
0
171
114
~
—
83
104
6-cyl.
—
~
—
~
~
98
195
Til
109
~
9/25/97
4-cyl.
180
235
155
—
~
48
202
176
—
~
6-cyl.
~
~
48
208
245
126
~
18
108
—
a Does not include broken molds that were not poured.
b The line usually shut down around 3 pm.
-------
TABLE 3.7
SUMMARY OF METAL POURED AND DOWNTIME FOR LINE 4
Hour
(first
shift)
1
2
3
4
5
6
7
8
9
Tons of metal poured8
9/22/97
45.2
44.5
55.1
46.3
20.4
48.1
19.0
54.3
26.5
~
9/23/97
45.4
44.6
53.6
52.1
54.3
45.6
41.6
33.2
27.0
—
9/24/97
30.8
39.3
12.0
0.0
34.7
47.7
48.8
56.8
44.1
21.1
9/25/97
36.5
47.7
43.5
52.1
61.3
41.3
41.0
40.2
27.0
—
Downtime (minutes)
9/22/97
8
17
11
15
40
7
42
12
0
~
9/23/97
10
20
12
14
12
10
14
26
0
—
9/24/97
26
17
47
60
22
13
17
10
17
1
9/25/97
20
8
15
14
6
21
15
17
0
—
Based on 202.8 Ibs per 4-cylinder engine block (405.6 Ibs per mold) and 250.4 Ibs per 6-
cyUnder engine block (500.8 Ibs per mold).
-------
TABLE 3.8
LINE 4 MOLD COUNTS DURING TESTING PERIODS
Date: 09/22/97
Time
1:41 pm
1 :42 pm
1 :45 pm
1:50 pm
2:00 pm
2:15 pm
2:20 pm
2:25 pm
2:30 pm
2:40 pm
2:45 pm
2:50 pm
2:53 pm
2:55 pm
3:00pm
Number of
molds"
0
5
14
21
40
57
21
21
22
28
22
21
17
3
16
Molds/hrb
0
300
280
252
240
228
252
252
264
168
264
252
340
90
192
Cumulative
molds/hr0
0
300
285
267
253
242
243
244
246
233
235
237
241
237
234
Comments
6-cylinder engine blocks; 8 broken
molds were not poured between 1 :30
and 3:00
Date: 9/23/97
Time
8:39 am
8:40 am
8:43 am
8:57 am
9:23 am
9:41 am
10:00 am
10:18am
10:30 am
10:42 am
10:54 am
11:02 am
ll:10am
Number of
molds8
0
5
14
54
93
69
64
73
32
49
44
35
34
Molds/hr"
0
300
280
231
215
230
202
243
160
245
220
263
255
Cumulative
molds/hr0
0
300
285
243
226
227
221
225
218
221
221
223
225
Comments
6-cylinder engine blocks; 26
6-cylinder molds not poured between
8:00 and 12:00
-------
TABLE 3.8
LINE 4 MOLD COUNTS DURING TESTING PERIODS (Concluded)
Date: 9/23/97
Time
11:42 am
12:01 pm
Number of
molds8
109
78
Molds/far"
204
246
Cumulative
molds/hr0
221
224
Comments
Switched to 4-cylinder blocks at
1 1 :45; 3 4-cylinder molds not poured
Date: 9/24/97
Time
11:03 am
11:06 am
11:08 am
ll:10am
11:35 am
11:51 am
12:04pm
Number of
molds8
0
12
9
9
94
68
44
Molds/hr"
0
240
270
270
226
255
203
Cumulative
molds/hrc
0
240
252
257
233
240
232
Comments
4-cylinder engine blocks; 5 molds
not poured
Date: 9/25/97
Time
8:57 am
9:17 am
9:30 am
9:48 am
9:58 am
10:15 am
10:26 am
10:41 am
10:57 am
11:25 am
11:32 am
Number of
molds8
0
68
41
72
42
52
38
59
64
118
29
Molds/hr"
0
204
189
240
252
184
207
236
240
253
249
Cumulative
molds/hr0
0
204
198
213
219
212
211
215
218
225
226
Comments
4-cylinder engine blocks; 3 molds
not poured
Switched to 6-cylinder at 9:30;
14 molds not poured
a Number of molds counted for the incremental time period.
b Rate based on the incremental time period.
c Cumulative rate based on number of molds from the start time; this is the most accurate
measure of the rate over the time period (i.e., the last bolded number in this column).
-------
TABLE 3.9
MOLD LINE 4 PRODUCTION DURING TESTING PERIODS
Date
9/22/97
9/23/97
9/24/97
9/25/97
Time Period
1:41- 3:00 pm
8:39 - 12:01 pm
1 1:03- 12:04 pm
8:57 -11:32 am
No. of molds poured
4-cylinder
—
75
231
106
6-cylinder
300
652
—
460
Molds/hr
poured
227
216
226
219
Tons/hr
poured8
56.9
53.0
45.8
53.0
Based on 405.6 Ibs for 4-cylinder molds and 500.8 Ibs for 6-cylinder molds.
-------
4.0 SAMPLING LOCATIONS
Isokinetic source sampling was conducted at the inlet and outlet of the cupola wet
scrubber at the GM-Saginaw SMCO facility. Descriptions of the sampling locations are
presented below, as well as schematic diagrams.
4.1 CUPOLA WET SCRUBBER INLET
The cupola wet scrubber inlet measurement site was located in a 661/4-inch inside
diameter (ID) round, vertical duct, 93% inches (1.4 duct diameters (d.d.)) downstream of the
nearest flow disturbance (90° bend) and 80 inches (1.2 d.d.) upstream of the nearest flow
disturbance. According to EPA Method 1 criteria, this site required 24 sample traverse points, 12
along each of two perpendicular diameters. Figure 4.1 shows a simplified schematic of the wet
scrubber inlet measurement site. Figure 4.2 shows the sample traverse point locations. A check
for the presence of non-parallel flow was conducted as specified in Section 2.4 of EPA
Method 1. The check confirmed the average yaw angle of 7.1 degrees, which is less than the
Method 1 requirement of 20 degrees based on the average. A quench (water) chamber was
located just upstream of the inlet sampling ports. It was attempted to locate sampling ports
before the quench chamber, but due to support beams and other ductwork, a suitable sampling
site was not accessible.
4.2 CUPOLA WET SCRUBBER OUTLET
The wet scrubber outlet sampling location was located in a 75-inch ID round, vertical
stack. Sampling ports were located along two separate planes to enable adequate access for the
multiple metals, semi-volatile organics and dioxin/furan sampling trains. The two sampling
ports utilized for the semi-volatile organics and dioxin/furan sampling trains were located close
to the rooftop. Sampling ports were located 639 inches (8.5 d.d.) downstream of a bend in the
duct and 273 inches (3.6 d.d.) upstream of the exhaust to atmosphere. The second set of
sampling ports was used to conduct the filterable particulate/multiple metals train. These ports
were located 672 inches (9.0 d.d.) downstream of a bend in the duct and 240 inches (3.2 d.d.)
upstream of the exhaust to atmosphere. Figure 4.3 is a schematic of the scrubber outlet sampling
locations. Figure 4.4 shows the sample traverse point locations. A check for the presence of
non-parallel
-------
Section A-A
93 1/4"
80"
k
Quench
Roof
Venturi
Spray
Nozzles
(Wet Scrubber
Figure 4.1 Cupola Wet Scrubber Inlet Sampling Location
-------
Circular Stack Method 1 Calculation Results
Date: 07/20/99 Time: 15:18:28
Facility: General Motors Corp.
Source ID: Scrub, inlet
Source Name: Cupola Wet Scrubber Inlet
Date: 09/21/97
Calculated By: F. Meadows
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 70 3/8 (inches)
Nipple Length: 41/8 (inches)
Distance from Upstream Disturbance: 80 even (inches)
Distance from Downstream Disturbance: 93 1/4 (inches)
Number of ports: 2 ports at 90 degrees
> v s^S-
CaliMIatett Vafciesf
4$
N v •• % o ••s^sj^
xw
^,;i
Inside Diameter: 66.2500
Upstream Duct Diameters: 1.20
Downstream Duct Diameters: 1.40
Mininum Traverse Points: 24
(inches)
1
2
3
4
5
6
7
8
9
10
11
12
!*«*« ,
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0.823
0.882
0.933
0.979
(tocft
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
338r
1 3/8
4 7/16
713/16
11 3/4
16 9/16
23 9/16
4211/16
4911/16
54 1/2
58 7/16
61 13/16
64 7/8
**,€tH^Jt3l %w"v.
jtltt ISnJS jt\ ^v
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
* ^rii^^K^jS
5 1/2
8 9/16
11 15/16
15 7/8
2011/16
2711/16
46 13/16
5313/16
58 5/8
62 9/16
6515/16
69 even
Figure 4.2 Cupola Wet Scrubber Inlet Traverse Point Locations
-------
33"
Roof
n
B
••MMH ^^^_
4 A
273"
Section B - B
240"
t
A and B = MM5 and M-23 Sampling Ports
C and D = M-29 Sampling Ports
639"
672"
Figure 4.3 Cupola Wet Scrubber Outlet Sampling Location
-------
Circular Stack Method 1 Calculation Results
Date: 07/20/99 Time: 15:21:16
Facility: General Motors Corp.
Source ID: Serb. Outlet
Source Name: Wet Scrubber Outlet
Date: 09/21/97
Calculated By: F. Meadows
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 79 1/4 (inches)
Nipple Length: 41/4 (inches)
Distance from Upstream Disturbance: 672 even (inches)
Distance from Downstream Disturbance: 240 even (inches)
Number of ports: 2 ports at 90 degrees
Inside Diameter: 75.0000
Upstream Duct Diameters: 8.96
Downstream Duct Diameters: 3.20
Mininum Traverse Points: 12
(inches)
0.021
75 even
1 9/16
4 1/4
513/16
0.067
75 even
5 even
4 1/4
9 1/4
0.118
75 even
8 7/8
4 1/4
13 1/8
0.177
75 even
13 1/4
4 1/4
17 1/2
0.250
75 even
18 3/4
4 1/4
23 even
0.356
75 even
2611/16
4 1/4
3015/16
0.644
75 even
48 5/16
4 1/4
52 9/16
0.750
75 even
56 1/4
4 1/4
60 1/2
0.823
75 even
61 3/4
4 1/4
66 even
10
0.882
75 even
66 1/8
4 1/4
70 3/8
11
0.933
75 even
70 even
4 1/4
74 1/4
12
0.979
75 even
73 7/16
4 1/4
7711/16
Figure 4.4 Cupola Wet Scrubber Outlet Traverse Point Locations
-------
flow was conducted as specified in Section 2.4 of EPA Method 1. The check indicated the
average yaw angle to be 7.7 degrees, which is less than the EPA Method 1 requirement of 20
degrees, based on the average.
-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES
Table 5.1 summarizes the sources, test parameters, test methods, number of tests, and net
run times. Simultaneous isokinetic sampling was conducted at the cupola wet scrubber inlet and
outlet for PM/metals. Sampling was also performed for VOHAPs at both the inlet and outlet
locations. Simultaneous with the PM/metals and VOHAPs testing, additional isokinetic
sampling was conducted at the cupola wet scrubber outlet for PCDDs/PCDFs and SVOHAPs.
Brief descriptions of the methods used follow.
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS
EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
select the measurement sites and to establish velocity and sample traverse point locations. The
location of measurement sites and traverse points are discussed in Section 4.0.
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE
EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S
Pitot Tube)," was used to determine stack gas volumetric flow rate at the cupola wet scrubber
inlet and outlet. A Type S pitot tube, constructed according to Method 2 criteria and having an
assigned coefficient of 0.84 and connected to an inclined-vertical manometer was used to
measure velocity pressure. A calibrated Type K thermocouple attached directly to the pitot tube
was used to measure stack gas temperature. The average stack gas velocity was calculated from
the average square roots of the velocity pressure, average stack gas temperature, stack gas
molecular weight, and absolute stack pressure. The volumetric flow rate is the product of
velocity and the stack cross-sectional area.
5.3 DETERMINATION OF DRY MOLECULAR WEIGHT AND EMISSION
CORRECTION FACTORS
EPA Method 3B, "Gas Analysis for the Determination of Emission Rate Correction
Factor or Excess Air," was used to measure carbon dioxide and oxygen content of the stack
gases. Gas samples were extracted from the stack or duct, simultaneous with the EPA Method
29 (scrubber inlet) or Method 23 (scrubber outlet) sample trains using the multi-point, integrated
bag sampling technique. The bag contents were analyzed on-site within four hours after sample
collection using an Orsat® analyzer to determine % concentrations of carbon dioxide and oxygen.
-------
TABLE 5.1
SOURCES, TEST PARAMETERS, AND TEST METHODS SUMMARY
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Source
Cupola Wet Scrubber
Inlet
Cupola Wet Scrubber
Outlet
Parameter
Flow Rate
02/C02*
Moisture
PM/Metals*(a)
Flow Rate
O2/CO2*
Moisture
PM/Metals*(a)
PCDDs/PCDFs
SVOHAPs
VOHAPs
Test
Methods
EPA 1 & 2
EPA3B
EPA 4
EPA 29
EPA 1 & 2
EPA3B
EPA 4
EPA 29
EPA 23
SW-8460010
On-site GC/MS
No. of
Tests
4
4
4
4
4
4
4
4
4
4
__b
Net Run Time,
Minutes
240
240
240
120
240
240
240
120
240
240
10-15/sample
'One integrated bag sample was collected for each 60 minutes of sampling time.
'"'Sample Runs I-M29-2 and O-M29-2 were run for 237 minutes; all other runs were approximately 120 minutes.
"''Several 10-15 minute GC/MS samples were collected during the periods of manual sampling.
The Orsat® analyzer had 0.1% subdivisions. One integrated bag sample was collected for each
60 minutes of sampling time at the wet scrubber inlet and outlet.
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT
EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine stack gas moisture content. The quantity of condensed water was determined
gravimetrically and then compared to the total volume of gas sampled to determine the volume
% moisture content. The Method 4 procedure was conducted in conjunction with the EPA
Methods 23 and 29 and SW-846 Method 0010 sampling runs. Condensed moisture was
determined by the difference in pre-test and post-test weights of the impingers, reagents, and
silica gel. Condensed moisture in the XAD® adsorbent trap from the SW-846 Method 0010 and
EPA Method 23 sample trains was also determined gravimetrically and the results included in
the moisture content calculations.
-------
5.5 DETERMINATION OF PARTICIPATE MATTER AND METALS
EPA Method 29, "Determination of Metals Emissions From Stationary Sources," was
used to determine filterable particulate matter and metals at the cupola wet scrubber inlet and
outlet. The target metals included: antimony (Sb), arsenic (As), barium (Ba), beryllium (Be),
cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb), manganese (Mn), mercury (Hg), nickel
(Ni), phosphorus (P), selenium (Se), silver (Ag), thallium (Tl), and zinc (Zn). Multi-point
integrated samples were extracted isokinetically from the 24 traverse points at the inlet and 24
traverse points at the outlet as shown in Figures 4.2 and 4.4, respectively. At each traverse point,
sampling was performed for five minutes at the inlet and five minutes at the outlet for a total run
time of 120 minutes per test. The samples were extracted through a glass nozzle, a heated glass-
lined probe, a heated quartz fiber filter, an empty impinger, two impingers containing an acidic
hydrogen peroxide solution (H2O2/HNO3), an empty impinger, and two impingers containing
acidic potassium permanganate (KMnO4). The final impinger contained silica gel. The nozzle
was attached to the probe using Teflon® or Teflon®-coated unions and Teflon® or graphite
ferrules. A schematic of the EPA Method 29 sampling train is shown in Figure 5.1. The sample
recovery scheme for metals is shown in Figure 5.2. >
The filter and acetone rinses of the probe and front half of the filter housing were
analyzed gravimetrically in the PES laboratory to determine filterable particulate matter. Upon
completion of the particulate matter analyses, the particulate fractions and aqueous fractions were
submitted to TLI for metals analyses. The sample preparation and analysis scheme is shown in
Figure 5.3. Metals other than Hg were analyzed by graphite furnace atomic absorption
spectroscopy (GFAAS) or inductively coupled argon plasma (ICP) emission spectroscopy.
Mercury was analyzed by cold vapor atomic absorption spectroscopy (CVAAS).
5.6 DETERMINATION OF DIOXINS AND FURANS
EPA Method 23, "Determination of Polychlorinated Dibenzo-p-Dioxins and
Polychlorinated Dibenzofurans from Stationary Sources" was used to determine PCDDs/PCDFs
at the cupola wet scrubber outlet. The proposed rules amending EPA Method 23, as published in
the Federal Register, Volume 60, No. 104, May 31,1995, were incorporated. The proposed
changes correct existing errors in the method, eliminate the methylene chloride rinse, and clarify
the quality assurance requirements of the method. Samples were extracted through a glass
nozzle, a heated glass-lined probe, a pre-cleaned and heated glass fiber filter, a water cooled
condenser coil and an adsorbent trap containing approximately 40 grams of XAD®-2 adsorbent
resin. A schematic of the EPA Method 23 sampling train (which is the identical to the SW-846
Method 0010 train) is shown in Figure 5.4. Multi-point integrated samples were extracted
isokinetically from the 24 traverse points shown in Figure 4.4. At each traverse point, sampling
was performed for 10 minutes, with pertinent readings taken every five minutes, for a net run
time of 240 minutes per test. TLI prepared the filters and adsorbent traps, and performed the
required analyses.
-------
Temperature
Sensor
Temperature
Sensor
Manometer
I N/ I N/ t
' 5%HUQ./ FmL, 4%KMnQ/ SIIL
Empty Em'pty 4%KMnQ/ silica
(Optional) 10% HjSQ lOyoHjSQ Gel
/Vacuum
Line
-------
tamaOk Bnah
«x) era wi* Aone
Itomtoe
bm« whh
O.INHNOJ
-------
OS
Cental
Acid Probi
(Labele
"•'3 Container 2 Cental
i Rinse Acetone Probe Rinse Fill
* FH) (Labeled AR) (Labelf
nert Container 4
sr (HN03/H202) Impingers
sd F) (Labeled BH)
(include condensate
impinger, if used)
I
Reduce to dryness Desiccate to Aliquot taken
in a tared beaker constant weight for CVAAS
Determine residue
for Hg analysis
Anal. Fraction 2B
weight in beaker Determine filter
' 1 ' paniculate weight
Solubilize residue
with cone. HN03
Divide into
Acidify to pH 2 sections A
with cone. HN03 ea(* sectio
• *»nnr- Up JL
Reduce volume to
near dryness and
digest with HF
Scone. HN03
Filter & dilute
to known volume
Anal. Fraction 1
' Digest with acid
and permanganate
at 95 C for2 h
and analyze
for Hg by CVAAS
0.5 g
digest
n with
HN03
Kemovesotoiourm Digest w
aliquot for Hg permanns
analysis by CVAAS a wa(e(
F I Analytical Fraction 1H
Analyze by (CAP for Analyze for
target metals metals by GFAAS*
Anal. Fraction 1A Anal. Fraction 1A
Acidify
remaining
sample to pH2
with cone. HNO3
Anal. Fraction 2A
Reduce volume
to neardryness
and digest with
HN03&H202
An alyze
by ICAP for
15 target metals
I
Analyze by
GFAAS
for Metals*
ith acid and
nate at 95 C in
bath for 2 h
Analyze aliquot for
Hg using CVAAS
Containers 5A, SB. & 5C
Individually, three
separate digestions
and analyses:
digest with acid
and permanganate
at 95 C for2h
and analyze
for Hg by CVAAS
Analytical Fractions
3A.3B.&3C
"Analysis by AAS for metals found at lei $ than 2 ug/mlin digastate solution,
if desired. Or analyze for each metal by AAS, if desired.
-------
Temperature
Sensor
Condenser
Button Hook
Nozzle
Stack
Wall
/
Heated Glass
Liner
Gas
Flow
Gas
Exit
Temperature
Sensor
TypeS vJ
PitotTube \
Inclned Recirculation
Manometer FumP
Temperature
Empty 100 ml HPLC Water Empty Silica Gel
Orifice
Inclined
Manometer
Vacuum
Pump
Vacuum
Line
-------
5.7 DETERMINATION OF SEMIVOLATILE ORGANIC HAZARDOUS AIR
POLLUTANTS (SVOHAPs)
Method SW-846 0010, "Modified Method 5 Sampling Train (MM5)," was used to collect
SVOHAPs at the cupola wet scrubber outlet. Multi-point, integrated samples were extracted
isokinetically from the 24 traverse points shown in Figure 4.4. At each traverse point, sampling
was performed for 10 minutes for a total run time of 240 minutes per test. Meter box readings
were recorded every five minutes. The SW-846 Method 0010 samples were extracted through a
glass nozzle, a heated glass-lined probe, a precleaned and heated glass fiber filter, a water-cooled
condenser coil and an adsorbent trap containing approximately 40 grams of XAD®-2 adsorbent
resin. A schematic of the SW-846 Method 0010 sampling train is shown in Figure 5.4.
The SW-846 Method 0010 samples were extracted following the procedure of Method
3542, dated January, 1995. The extracts were analyzed in accordance with the guidelines of
Method 8270A by High Resolution Gas Chromatography/Low Resolution Mass Spectrometry.
The three sample fractions for each test run, i.e., front half extract, the back half extract (XAD®-2
and back half rinse), and the condensate extract were combined for one analysis, per test run.
The samples were analyzed for the SW-846 Method 8270 polynuclear aromatic hydrocarbon
(PAH) and Clean Air Act (CCA) semivolatile compounds.
5.8 DETERMINATION OF VOLATILE ORGANIC HAZARDOUS AIR
POLLUTANTS (VOHAPS)
Direct interface gas chromatography/mass spectrometry (GC/MS) was used to determine
volatile organic hazardous air pollutant (VOHAP) concentrations at the inlet and outlet of the
cupola wet scrubber. A single point, constant rate sample was withdrawn from the individual gas
streams using a heated probe and sample line to prevent condensation. A conditioning unit was
used to protect the GC/MS from particulate matter and excess moisture. The gas
chromatography (GC) portion of the GC/MS separates the gaseous mixture of molecules by their
affinity for the analytical column's stationary and mobile phases. The mass spectrometer (MS)
portion of the GC/MS uniquely identifies each molecule by detecting individualized fragments.
Positive identification of target analytes is achieved by comparison of eluting analyte GC peak
retention times in the total ion chromatogram to those obtained from the calibration, and by
examining the mass spectral pattern.
Sample gas is introduced into the GC/MS via a pneumatic valve assembly or equivalent.
The internal standard mixture must be quantitatively co-added to every sample before injection.
Compounds are typically separated and detected in a 10- to 15-minute isothermal run. Effluent
samples are quantified by comparing analyte GC retention times and the corresponding
instrument response to the initial three-point calibration. Figure 5.5 is a schematic of the direct
interface GC/MS sampling system.
-------
Primary Particulate Filter
Heated Extractive Probe
Calibration
Assembly
A
Atmospheric vent
Sample
Conditioning
Box
Heated Sample
Transport Line
1
1
1
0
R
Analytical
Instumentation
Contains moisture
removal apparatus
Flow Meters
Calibration Gas and
Dilution Manifold
-------
Measurement of VOHAPs at the cupola wet scrubber inlet and outlet showed no
concentrations above analytical instrument detection limits for any of the target analytes. Control
spikes in the parts per billion (ppb) range showed recoveries of 100%, demonstrating the
integrity of the sampling system.
-------
6.0 QUALITY ASSURANCE/QUALITY CONTROL
PROCEDURES AND RESULTS
This section describes the specific QA/QC procedures employed by PES in performing
this series of tests. The procedures contained in the "Quality Assurance Handbook for Air
Pollution Measurement Systems, Volume III, Stationary Source Specific Methods," EPA/600/R-
94/03 8c, and in the reference test methods served as the basis for performance for all testing and
related work activities in this project.
6.1 CALIBRATION OF APPARATUS
The preparation and calibration of source sampling equipment is essential in maintaining
data quality. Brief descriptions of the calibration procedures used by PES follow.
6.1.1 Barometers
PES used aneroid barometers which are calibrated against a station pressure value
reported by a nearby National Weather Service Station corrected for elevation.
6.1.2 Temperature Sensors
Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in Section 3.4.2 of the Quality Assurance Handbook, Volume III, 1994.
Each temperature sensor was calibrated over the expected range of use against an ASTM 3C or
3F thermometer. Table 6.1 summarizes the type of calibrations performed, the acceptable levels
of variance, and the results. Digital thermometers were calibrated using a thermocouple
simulator having a range of 0-2400 °F.
6.1.3 Pitot Tubes
Type S pitot tubes constructed to EPA Method 2 specifications were used. Pitot tubes
meeting these specifications are assigned to a baseline coefficient to 0.84 and need not be
calibrated. The dimensional criteria and results for each pitot tube used are summarized in
Table 6.2.
-------
TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
Temp.
Sensor
I.D.
T6C
7C
8C
7B
RMB-13
MB-14
Usage
Stack Gas
Stack Gas
Stack Gas
Stack Gas
Meter Box
Inlet
Outlet
Meter Box
Inlet
Outlet
Temperature, °F
Reference
69
32
200
378
70
32
204
440
70
33
190
396
72
34
204
394
76
34
150
76
34
150
74
33
128
70
33
149
Sensor
70
31
203
375
71
33
202
437
70
33
188
395
73
35
201
391
76
35
149
75
35
151
75
34
129
71
34
150
Temperature
Difference
-0.2%
0.2%
-0.5%
0.4%
-0.2%
-0.2%
0.3%
0.3%
0.0%
0.0%
0.3%
0.1%
-0.2%
-0.2%
0.5%
0.4%
0
-0.2%
0.2%
0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
Tolerance
s
-------
TABLE 6.2
SUMMARY OF PITOT TUBE DIMENSIONAL DATA
Measurement
~1
«2
PI
P2
Y
0
A
Z
W
Dt
A/2D,
Criteria
<10°
<10°
<5°
<5°
-
-
-
<; 0.125 in.
<; 0.03125
m.
0.1875" *
Dt <, 0.375"
l.OSD.s
As 1.50D,
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
T6C
3
3
3
1
0
0
1.031
0
0
0.375
1.37
Yes
0.84
7C
0
1
0
1
2
1
0.98
0.03
0.017
0.375
1.31
Yes
0.84
8C
0
1
1
0
0
1
0.914
0
0.016
0.375
1.22
Yes
0.84
7B
1
0
1
0
0
1
0.947
0
0.165
0.375
1.26
Yes
0.84
-------
6.1.4 Differential Pressure Gauges
PES used Dwyer inclined/vertical manometers to measure differential pressures. The
differential pressures measurements included velocity pressure, static pressure, and meter orifice
pressure. Manometers are selected with sufficient sensitivity to accurately measure pressures
over the entire range of expected values. Manometers are primary standards and require no
calibration.
6.1.5 Dry Gas Meters and Orifices
The SW-846 Method 0010 and EPA Method 23 and 29 dry gas meters and orifices were
calibrated in accordance with Sections 5.3.1 and 5.3.2 of EPA Method 5. This procedure
involves direct comparison of the dry gas meter to a reference dry test meter. The reference dry
test meter is calibrated annually using a wet test meter. Before its initial use in the field, the
metering system was calibrated over the entire range of operation as specified in EPA Method 5.
After field use, the metering system was calibrated at a single intermediate setting based on the
previous field test. Acceptable tolerances for the initial and final dry gas meter factors and
orifice calibration factors are ± 0.05 and ± 0.20 from average, respectively. The results for the
gas meter and orifice used in this test program are summarized in Table 6.3.
6.2 ON-SITE MEASUREMENTS
The on-site QA/QC activities include:
6.2.1 Measurement Sites
Prior to sampling, the stack and inlet duct were checked dimensionally to determine
measurement site locations, location of velocity and sample test ports, inside stack/duct
dimensions, and sample traverse point locations. Inside stack/duct dimensions were checked
through both traverse axis to ensure uniformity of the stack/duct inside diameter. The inside
stack/duct dimensions, wall thickness, and sample port depths were measured to the nearest 1/8
inch.
6.2.2 Velocity Measurements
All velocity measurement apparatus were assembled, leveled, zeroed, and leak-checked
prior to use and at the end of each determination. The static pressure was determined at a single
point near the center of the stack or duct cross-section.
-------
TABLE 6.3
SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
Meter
No.
M5-10
M5-11
RMB-13
MB-14
Gamma
Pre-test
0.999
1.024
1.010
0.966
Post-test
1.016
1.027
0.990
0.982
% Diff.
1.7
0.3
-2.0
1.9
EPA Criteria
±5%
± 5% '
± 5%
±5%
Orifice Coefficient
Average
1.591
1.819
1.859
1.862
Range
1.532-1.640
1.798-1.926
1.800-1.925
1.756-1.923
EPA Criteria
1.591 ±0.20
1.819 ± 0.20
1.859 ± 0.20
1.862 ±0.20
-------
6.2.3 Flue Gas Composition
Integrated, multi-point, flue gas samples were collected in Tedlar® gas bags from the wet
scrubber inlet and outlet. Prior to use the bags were leak checked and purged with nitrogen to
ensure cleanliness. Prior to and after completion of each sampling run the entire sampling
system was leak checked from the tip of the probe. The bag samples were analyzed on-site using
an Orsat® analyzer within four hours after sample collection, in accordance with EPA Method
3B. Prior to use the Orsat® analyzer was assembled and replenished with fresh reagents and leak
checked using the manufacturer's procedures.
6.2.4 Moisture
The SW-846 Method 0010 and EPA Methods 23 and 29 sampling trains were used to
determine the flue gas moisture content. During sampling, the exit gas of the last impinger was
maintained below 68 °F to ensure complete condensation of flue gas water vapor. The total
moisture was determined gravimetrically using an electronic platform balance with 0.1 gram
sensitivity. The XAD® adsorbent modules from the EPA Method 23 and SW-846 Method 0010
sampling trains were also weighed and their weights included in the moisture catch.
6.2.5 Method 23. Method 0010 and Method 29
The field sampling QA/QC for EPA Methods 23 and 29 and SW-846 Method 0010 were
similar. Table 6.4 summarizes the critical measurements made and the EPA's acceptability
criteria. All pre- and post-test sample train leaks met the acceptance criteria. The isokinetic
sampling rates deviated by no more than 7.0% thereby meeting each method criteria of 90-110%.
EPA Methods 23 and 29 and SW-846 Method 0010 field blanks were collected near each
of the sampling locations to check for any sample contamination at the sites. Sample trains were
assembled and pre- and post-test leak checks were conducted. The sample trains were recovered
in the same manner as the actual sample runs. Each field blank train was subjected to a
minimum of one leak check in the laboratory and three to five leak checks at the sampling site,
depending on the location.
An acetone blank and quartz fiber filter were taken as control samples for the particulate
analysis and subsequent analysis for the target metals. Blanks were taken of the metals absorbing
and recovery reagents.
-------
TABLE 6.4
SUMMARY OF EPA METHODS 23 AND 29 AND SW-846 METHOD 0010 FIELD SAMPLING QA/QC DATA
Date
09/23/97
09/24/97
09/25/97
Site
Wet Scrubber
Inlet
Wet Scrubber
Outlet
Wet Scrubber
Inlet
Wet Scrubber
Outlet
Wet Scrubber
Inlet
Wet Scrubber
Outlet
Wet Scrubber
Outlet
Wet Scrubber
Outlet
Run No.
I-M29-1
O-M29-1
O-23-1
O-0010-1
I-M29-2
O-M29-2
O-23-2
O-0010-2
I-M29-3
I-M29-4
O-M29-3
O-M29-4
0-23-3
O-23-4
O-0010-3
O-0010-4
Pre-Test
Leak Rate
acfm
0.003 @ll"Hg
0.005 @ 12" Hg
0.003 @1 5" Hg
0.003 @ 15" Hg
0.006 @ll"Hg
0.002 @ll"Hg
0.002 @1 5" Hg
0.005 @1 5" Hg
0.014 @ 27" Hg
0.008 @ 15" Hg
0.002 @ 10" Hg
0.002 @ll"Hg
0.008 @ 15" Hg
0.005 @ 15" Hg
0.011@16"Hg
0.004 @ 15" Hg
Post-Test .
Leak Rate
acfm
0.006 @ 10" Hg
0.001 @ 7" Hg
0.003 @ 6" Hg
0.032 @ 7" Hg '
0.005 @ 22" Hg
0.001 @ 6" Hg
0.002 @ 10" Hg
0.002 @ 9" Hg
0.001 @ 12" Hg
0.002 @1 8" Hg
0.002 @ 15" Hg
0.002 @ 11" Hg
0.019 @ 17" Hg
0.002 @1 6" Hg
0.004 @ll"Hg
0.003 @ll"Hg
EPA
Criteria
acfm
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
Percent
Isokinetic
102.3
95.4
93.0
98.4
104.5
99.3
101.5
101.2
103.8
105.1
97.8
95.9
103.4
102.0
101.2
100.8
EPA
Criteria
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
-------
6.3 LABORATORY ANALYSES
6.3.1 Participate Matter
Particulate matter analysis consisted of front half acetone sample rinses and quartz fiber
filters. Prior to the field testing program, the filters were tared in the PES (or DEECO)
laboratory, stored in petri dishes, and sealed with Teflon® tape. Several beakers were also
cleaned and tared for subsequent use in evaporating the acetone rinses. Upon receipt in the PES
laboratory, the acetone rinses were placed in the tared beakers and evaporated to dryness at room
temperature. The filters and beakers were desiccated and weighed to a constant weight. All
weighings were within the method requirements of 0.5 milligrams between two consecutive
weighings taken at least six hours apart.
6.3.2 EPA Method 29
TLI analyzed the EPA Method 29 samples consisting of eight stack gas samples, two
blank samples and one reagent blank to determine concentrations of antimony (Sb), arsenic (As),
barium (Ba), beryllium (Be), cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb), manganese
(Mn), mercury (Hg), nickel (Ni), phosphorus (P), selenium (Se), silver (Ag), thallium (Tl), and
zinc (Zn). All metals, except Hg, Tl, As and Co concentrations, were determined by inductively
coupled plasma emission spectroscopy (ICP). Thallium concentrations for most of the back half
samples (refer to the TLI case narrative for an exact listing of the samples) were determined
using graphite furnace atomic absorption (GFAA). Arsenic and Co were also analyzed by
GFAA. Specific TLI QA/QC activities for GFAA and ICP analyses consisted of: laboratory
control spikes, post-digestion matrix spikes of one sample set, duplicate analysis of one sample
set, serial dilution and analysis of one sample set, analysis of a method blank, and analysis of
field and reagent blanks. Mercury was analyzed by cold vapor atomic absorption spectroscopy
(CVAAS). Specific TLI QA/QC activities for CVAAS analyses consisted of analysis of a
method blank and analysis of field and reagent blanks. The results of these QA/QC activities are
summarized in Tables 6.5 through 6.10 for metals other than Hg and in Tables 6.11 through 6.14
for Hg. Complete QA/QC data are contained in the TLI analytical report in Appendix C.
6.3.3 EPA Method 23 PCDDs/PCDFs
Prior to the field testing program, TLI prepared PES' XAD®-2 adsorbent traps and
precleaned the glass fiber filters. TLI's laboratory QA/QC program consisted of adding
isotopically labeled standards to each sample at various stages of the project to determine
recovery efficiencies. The following types of standards were used:
-------
TABLE 6.5
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
LAB CONTROL SPIKES (LCS)
Analyte
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Spike Amt
Aig/L"
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
LCS Recovery
88%
79%
91%
88%
91%
94%
91%
92%
90%
91%
91%
92%
91%
91%
92%
Recovery Limits
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
1 Micrograms per liter.
-------
TABLE 6.6
SUMMARY OF EPA METHOD 29
MATRIX SPIKES (POST
ANALYSIS QC DATA
DIGESTION)
Analyte
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Spike Amt /ug
50
50
50
50
50
25
50
50
50
1000
50
50
50
50/25
200
Percent Recovery*
Run No. M29-1-
FH
87%
82%
SL
65%
SL
92%
SL
SL
SL
83%
SL
SL
SL
SL
SL
Run No. M29-1-BH
76%
104%
96%
93%
97%
N/A
94%
94%
95%
86%
93%
90%
72%
93%
90%
Recovery
Limits
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
*SL = Spike Low, % Recovery is not considered valid when spike amount is less than 20% of recovered amount.
-------
TABLE 6.7
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
DUPLICATE ANALYSES
Analyte
Sample yug"
Duplicate /ug"
RPDb
RPD Limits
Run I-M29-2-FHc
AR
Asd
Ba
Be
Cd
Cod
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
25.2
82.4
1,170
2.37
231
46.7
1,020
140,800
55.7
5,560
22,300
54.4
60.0
63.7
160,700
24.7
N/A
1,190
2.34
227
N/A
1,010
149,500
55.2
5,550
23,800
59.1
58.7
63.2
172,100
2.00%
N/A
1.69%
1.27%
1.75%
N/A
0.985%
5.99%
0.902%
0.180%
6.51%
8.28%
2.19%
0.788%
6.85%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
Run I-M29-2-BH6
Ag
Asd
Ba
Be
Cd
Co"
Cr
Mn
Ni
P
Pb
Sb
Se
T1d
Zn
2.32
1.90
32.0
0.205
10.7
4.12
27.9
3,360
2.06
99.1
497
3.89
1.59
< 0.217
4,090
2.44
N/A
31.9
0.206
10.8
N/A
28.2
3,850
2.18
99.9
501
4.24
1.54
N/A
4,140
5.04%
N/A
0.313%
-------
TABLE 6.8
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
SERIAL DILUTION
Analyte
Sample /^g
Serial Dilution /uga
RPDb
RPD Limits
RunI-M29-l-FHc
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
10.8
28.2
406
< 0.100
82.8
31.3
502
61,300
37.5
476
9,560
66.5
25.1
30.8
77,200
12.3
27.3
424
< 0.500
97.0
40.7
574
62,400
44.9
530
9,610
74.4
23.5
39.5
78,200
13.0%
-------
TABLE 6.9
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
METHOD BLANK RESULTS
Analyte
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
7,n
Detection Limit
MS/La
1
7.5
2
1
1
1.5
2
2
3
30
2
4
3
5
12
MB 1 Recovered Amount
/LiZ/L*
-0.47
-0.30
-0.05
0.01
-0.37
0.70
0.92
0.12
-1.13
-12.45
0.20
-1.43
0.08
-2.46
5.47
The Method Blank is considered a "Pass" when the recovered amount is less than the detection limit.
a Micrograms per liter.
-------
TABLE 6.10
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
FIELD BLANKS RESULTS
Analyte
As
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Outlet Front Half, /zg"
0.129
< 0.750
13.0
< 0.100
< 0.100
0.640
7.06
1.54
4.03
5.19
0.237
3.89
4.07
0.720
10.2
Outlet Back Half, /^g"
0.128
< 0.750
0.366
< 0.100
< 0.100
< 0.150
0.737
4.69
< 0.300
4.35
1.08
0.550
< 0.300
0.610
6.78
' Micrograms.
-------
TABLE 6.11
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - LAB CONTROL SPIKES
Sample ID
LCSl
LCS 1 Dup
LCS2
LCS 2 Dup
Spike Amount
,"g/La
4.7
4.8
5.2
5.2
Recovery
95%
96%
103%
104%
Recovery Limits
80-120%
80-120%
80-120%
80-120%
1 Micrograms per liter.
-------
TABLE 6.12
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - MATRIX SPIKES (PRE-DIGESTION)
Sample ID
I-M29-1-H202BHMS
I-M29-1-H202BHMSD
O-M29-1-H202BHMS
O-M29-1-H202 BH MSD
O-M29-2-H202 BH MS
O-M29-2-H202 BH MSD
O-M29-4 H202 BH MS
O-M29-4-H202 BH MSD
Spike
Concentration
^g/L"
5
5
5
5
5
5
5
5
Recovery
97%
100%
81%
83%
104%
111%
108%
113%
Recovery Limits
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
1 Micrograms per liter.
-------
TABLE 6.13
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - METHOD BLANK
Sample ID
MB1
MB1 Dup
MB2
MB2 Dup
Detection Limit
A*g/La
0.200
0.200
0.200
0.200
Recovered Amount,
y"g/L"
0.023
0.005
0.018
0.010
The Method Blank is considered a "pass" when the recovered amount is less than the detection limit.
a Micrograms per liter.
-------
TABLE 6.14
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - FIELD AND REAGENT BLANKS
Sample ID
FH
FH - Dup
BH
BH- Duo
HNO,
HNO, - Dup
KMnO,
KMn(X - Dup
HC1
HC1 - Dup
Outlet Field Blank //g"
< 0.400
< 0.400
< 0.600
< 0.600
< 0.400
< 0.400
<1.60
<1.60
< 0.880
< 0.880
Reagent Blank //g"
< 0.400
< 0.400
< 0.600
< 0.600
<0.116
<0.116
<1.60
<1.60
< 0.920
< 0.920
Micrograms
-------
Internal Standards were spiked in the TLI laboratory after the field sampling program and
prior to sample extraction. Recovery efficiencies for these compounds were used in
quantifying the actual PCDDs/PCDFs isomers measured in the samples.
Surrogate Standards were spiked in the TLI laboratory on the XAD®-2 resin prior to the
field sampling program. Recovery efficiencies for these surrogate compounds provided a
measure of the sample collection efficiency and an indication of any analytical matrix
effects.
Alternate Standards were spiked in the TLI laboratory after the field sampling program
and prior to sample extraction. Recovery of these compounds indicated the extraction
efficiencies.
Recovery Standards were added in the laboratory after extraction just prior to GC/MS
analysis.
Table 6.15 summarizes the recovery efficiencies for the various standards and the
respective quality control limits. The recovery efficiencies for the XAD® blank, field blank, and
samples were all within the method QC limits. Refer to TLI's case narrative for their discussion
of any quality control anomalies.
6.3.4 SW-846 Method 0010
TLI analyzed the SW-846 Method 0010 samples following the procedures of
SW-846 Method 8270A Rev. 1 (7/92). Field blanks and laboratory blanks were used to check
for contamination. The blanks were processed in the same way the field samples were processed.
The results of the field and laboratory blanks are presented in Table 6.16. Also shown are the
average catch weights for the compounds presented. The significance of the blank values was
discussed in Section 2.
A five point initial calibration was performed using internal standards and instrument
response factors developed for the target analytes. Method 8720A procedures require the percent
standard deviations of the initial calibrations to be within 50% for most analytes and 30% for
some analytes. All internal standards were within the Method 8270A quality control criteria.
The XAD®-2 resins were spiked with surrogate standards prior to the field sampling. The
percent recoveries for the surrogate standards are presented in Table 6.17.
-------
TABLE 6.15
SUMMARY OF EPA METHOD 23 STANDARDS RECOVERY EFFICIENCIES
FULL SCREEN
ANALYSIS
Internal Standards
2,3,7,8-TCDF
2,3,7,8-TCDD
1,2,3,7,8-PeCDF
1,2,3,7,8-PeCDD
1,2,3,6,7,8-HxCDF
1,2,3,6,7,8-HxCDD
1,2,3,4,6,7,8-HpCDF
1,2,3,4,6,7,8-
HpCDD
1,2,3,4,6,7,8,9-
OCDD
Surrogate Standards
2,3,7,8-TCDD
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8,9-HpCDF
Alternate Standards
1,2,3,7,8,9-HxCDF
2,3,4,6,7,8-HxCDF
CONFIRMATION
ANALYSIS
Internal Standards
2,3,7,8-TCDF
Percent Recovery
TLI
M23
Blank
79.4
75.4
96.9
86.6
123
94.9
92.5
87.5
84.0
92.5
100
92.3
96.7
91.3
68.6
81.4
M23
1
57.6
86.4
93.5
109
110
102
80.5
99.6
99.7
85.8
97.7
88.3
94.3
98.3
79.9
91.8
M23
2
78.9
90.2
87.5
100
102
101
82.1
94.8
95.1
89.0
94.4
95.3
99.6
88.0
93.3
104
81.8
Trip
Blank
85.0
82.3
101
118
105
95.7
90.0
102
104
94.1
98.5
93.1
96.8
92.4
85.3
104
O-
23-1
89.8
85.5
78.8
83.7
111
94.1
61.3
95.0
63.5
93.7
95.6
92.0
98.9
101
101
112
95.4
O-
23-2
103
90.5
96.1
103
120
106
92.4
89.7
63.8
102
92.0
95.8
85.6
94.6
107
116
102
O-
23-3
45.9
58.6
77.7
84.8
62.8
61.3
47.5
70.9
89.2
85.9
80.7
88.1
97.6
97.2
49.2
48.9
58.9
0-
23-4
69.7
83.5
96.0
110
85.6
87.7
65.1
84.5
95.2
91.1
95.4
99.0
101
105
75.3
82.5
87.9
QC
Limits
40-130%
40-130%
40-130%
40-130%
40-130%
40-130%
25-130%
25-130%
25-130%
70-140%
70-140%
70-140%
70-140%
70-140%
40-130%
40-130%
40-130%
* Confirmation analysis was not necessary on these samples since no TCDF's were detected in the full screen analysis.
-------
TABLE 6.16
SW-846 METHOD 0010 FIELD AND LABORATORY BLANKS RESULTS
Compound
Acetophenone
Di-n-butylphthalate
2-Chloroacetophenone
bis(2-Ethylhexyl)phthalate
Naphthalene
Amount, micrograms*
Average
Catch
Weight**
13.12
{10.98}
ND
{20.56}
{52.80}
Field
Blank
3.78
3.41
{0.35}
21.61
5.85
Method
Blank
2.53
1.61
3.83
0.57
2.44
Laboratory
Blank
ND
29.02
{0.41}
1.19
ND
* Values in brackets { } are estimated values that were above the detection limit, but below the quantitation limit.
ND = Compound was not detected.
** Average Catch Weight = Average sample amount from runs O-0010-1, O-0010-2, O-0010-3 and O-0010-4.
-------
TABLE 6.17
SW-846 METHOD 0010 SURROGATE RECOVERY RESULTS
Surrogate
Phenol-d5
Nitrobenzene-d5
1 ,3,5-Trichlorobenzene-d3
1 ,4-Dibromobenzene-d4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d10
Pyrene-d,0
Terphenyl-dj^
Percent Recovery
O-
0010-1
77
76
80
82
82
103
103
82
91
O-
0010-2
79
68
63
81
78
108
93
81
90
O-
0010-3
77
72
68
82
84
110
98
87
94
O-
0010-4
75
63
58
71
81
119
91
79
86
Field
Blank
66
62
60
68
72
92
90
87
108
Method
0010
Blank
57
56
53
64
67
99
95
106
ND
Lab
Blank
69
74
63
74
72
91
92
97
ND
Method
QC
Limits
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
ND= None Detected.
-------
APPENDIX A
-------
Appendix A.I
Raw Field Data
-------
j asm tarn
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:
Data:
Sampling Location:
Inside of Far Wall to Outside of Nippie:
Inside of Near Wall to Outside of Nipple (Nipple Length): V fa
Stack I.D.: &6 '/V "
Distance Downstream from Flow Disturbance (Distance 8):
inches t Stack 1.0. = /. 4 dd
Distance Upstream from Flow Disturbance (Distance A):
*?3 >/ inches / Stack I.D. = / .V dd
Calculated By: /lt>D
Schematic of
Sampling Location
Traverse
Point
Number
• 1
2
3
V
r
*
7
^
^
10
II
a
Fracnon
of
Length
6.02J
rt.O
o.\n
& tfO
O^L
o. 6^/g
O.^/)
0.8*5
rrftto
to.^33
0.1^
Length
(inches)
(&.^
rnf*-vr
G>C.tt
a.^~
fa-it
0*.2'
5^423^' ^^
^ •• #/!*•"£/ %a
6l/.8$ei-v w i/^
Nipple
Length
(inches)
V^"
v{/?"
-------
3BC3 C3
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: & t\
Sampling Lo<
Run #: ?t-£
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travaraa
Point
Numbar
/? 1
3.
5
q
$
&
}
$
^
to
II
11
B \
2
1
(i
r
<£
7
$
'7
to
,•(
a
:ation: iv,Ve_f Clock Time: . v- ^
--4e-sf r-V4<- Operators- A^fo / ^ M
ressure, in. h
a
la: ^ ^ , 7 ¥ Static Pressure, in. HUO: - ft ?sr
Molecular wt.. Drv ^a>. V Pitot Tube, Cp: O ^
sion, in. Diameter or Side
** _' J /' It -».!-* | •
H: 0^ /y Side P- —
_
: - ' DrvBuiB.^h:
Valocity
Haad
in. H2O
J/L
1.3
I.l
| >/ ?,,
LZ
>*& 1.3
3,
^» /.T.
0 . '1C
ft.-\t/
r>. s)
tx:t#
D, >c
^.*x&
^SF -c, W
Stack ; (
"°7 6
/52J/ 'i
(V/7 i2.
/vy/^
/f/3/3
i v y/ <$"
/ /r /?
'vr/y
/ V(£ /.5
/ V ?/ 6
/VJ//6
r>W / .2
(To //V
/ J*"/ 7
|56/ /C-
lS«/ t
/.^/r
)V6/ /
IVe>/ /
Nif S~
NO/ C
ifc/ />'
^7/ /
f!./i// #>.
Md - (0.44 x SiCOj) + (0.32 X %V*Md - (0.44 x ) + (0.32 x ) -•• (0.28 x )
Md -
% H2O % HjO
TJ- °F- °R(°F^460)
Pa - Pb * S'P' -- ( ) +
13.0 13.0
Pa - In. Hg
flF-
— [ Ta ^R)
Va-«b.4«xCpx ^H x y psxM8
Va- ft/a
A.- ft2
Qa - VaxAaxOOa/m
Qa- x xOO
Qa • acfm
Pa ^HjO
-------
FIELD DA IA SHEET
Plant: ^
Sampling Location T^
Run Number:?&&&(• \ Date: ^-^ -"f?
Pretest Leak Rate: 3.QC3 cfm @ |l" in. Hg.
Pretest Leak Check: Pitot: ^ Orsat: S
Sample Type:
Pbar: ^ ? V'
CO2:
Operator:
'
Ps: -/
O2:
Nozzle ID:
Assumed
Pi-, I & >
o
Thermocouple #:
Probe Length/Type:
Stack Diameter:
Pitot #: £'-
Vfr"
As:
Meter Box #: ^-]< Y: f.rOVAH®: , #
Post-Test Leak Rate: Q^J, c*m @ &2_ '"•
Post-Test Leak Check: Pitot: V Orsat:
J77T
Traverse
Point
Number
Sampling
Time
(mln)
Qockrime
(24-hour
dock)
Gaa Meter
Reading
(Vmjtt3
Velocity
Head (Ap)
inH2O
Otitce Pressure Drtferential
(AH) in H2O
Desired I Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe Rltof
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
C«.Hg)
0
IV 'to
,5"
u
l.'l
v. v
^37
60
i^r- i--i
.5
V
o r
Si
it 6
3c)
J^i
Vo
(.0
^X
i -' i
r.c-r
6':
6
?&
i-i
39
.(3
2VZ
•fo
ro
, U
-m
7&C
Jo
16 X!
VVr. ^,6
/03
88
a,
&
oo
ft
32S"
ID
m
79
r?
7-
(00
^"5^,1 A
56
98
?i I/O
/.
1 3(0
AVrn-
-------
Plant: 6-'
FIELD DA IA SHEET
Zl Operator:
Sampling Location ~^|
Number: ^X Data:
o cctf
Pretest Leak Rate: &B&. cfm @ 11 in. Hg.
Pretest Leak Check: Pitot: \/ Orsat: ^
Sample Type:
Pbar: 33. 8 T
C02:
Nozzle ID: C- \
Ps:
O2:
Thermocouple #:
Filter #:
, D
Probe Length/Type:
Slack Diameter: £•£ '/••/
fi.to
237
LO
, ri
/.at
J .c'n
37
Go
&*•
r
f.o
l. i
/2V
. «i ft
1 (i
i.o
i.O
ei
If. oV
(.1
PC
ft
I-/
(•1
ft
I'.VV
J750. VX
0.18
.O
ft
nc
231
fti
i. l
i.1.
80
R ii
0.37
0.3^0
n 41
IM.
o .
61
AH=
-------
Page
of
Plant Name:
Run Number:
(rfv(
x
Test Date:
Operator:
Traverse
Point
Number
Sampling /dock Time
Time. / (24-hour
OniiU / clock)
Gas Meter
Reading
(U)ft'
Velocity
llead^P.)
in. IhO
Orifice Pros. Differential
Desired
Actual
Stuck
Temp. • F
Probe
Temp./ Filler
Temp.0 F
Impinger
Temp.
•F
Dry Gas Meter Temp.
Inlet
(Juliet
°F
Pump
Vacuum
In.llg
JSC /
io
HO
5" 3
33
bl
ivr
0-1]
i SI
o .
G.
/9
0 V3
0.
ixr
$0
o/
&
o.t'f
n
8-2.
i/
LO
1*1
/v
r
/U.'SS
13*5
9-X
/S"
ar
81
/x
\l~-c3
1.3
132
32,
//r
1.3
(71
/.**-
f-3'
So
/f
1,3
\.v
. ft
23?
576. •
60
1.2.
65"
1.3
'
-------
FIELD DA IA SHEET
Sampling Location IL'ef ^/,U-
?f'lllJ,9-3RunNumber: 2 Dato: ?/2>"
Pbar:
/*7 C02:
•IP"- n
77. /fl
n
.47 v^pciaiui. 1 in /n
Ps: -n,7f
02: /O
Assumed Bws: tES
Meter Box #: /*^>'-'f
Pretest Leak Rate: O.OW cfm @ ^2. m. Hg
Pretest Leak Check: Pitot: ^ Orsat:
Thermocouple »:
f Filter #:
Y:
fyf * ^^
Probe LengtWType: (,'
Slack Diameter:
.
Post-Test Leak Rale: .Qtt cfm @ [2. in. Hg.
Post-Test Leak Check: Pftot: ^ Orsat: *—
Tiav«ra«
Point
Nurnbai
An
i
.5"
n
Sampling
Ume
(rnln)
0
7
/O
Zo
5T
7c
,/r
lit)
Qockrinw
(244iour
dock)
GuMettr
Reading
stuw
'".»-'
Velocity
Kead (Ap)
lnH2O
Oiitc* Pr«ssui« Diftet«nlial
(AH) In H20
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
HIM
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin0F)
Outlet
(Tmout°F)
^&L
J&L.
_LP_
1.0
\.o
i.i
.32
3.
17J1
3.7?^
I.JS
I./IT
ion
2,1
7,1
•3.0
3. '
*?. ?
1-7
f.y
VL
u
1*70
m
lit
/^c
75"?
7.^
2ft,
277
-LC7
27-r
27V
171
16-s
_7fit
27<5
761
Z67
5T
5T7
ri
61
rv
it.
-74
79
71
$7
91
ri
6'C
£7
-71
77
76
77
7*
7/5
T'f
."JF
Pump
Vacuum
On Hg)
7
8"
/O
/O
If
/I
-------
FIELD DA IA SHEET
Plant: iy,
Sampling Location
Run Number: 1
n
~T!^K£
Date:
wtl^
yWfr
Sample
Pbar:
C02:
Type:
Zl/o
11
tf-2f
Ps:
O2:
Operator: /V» /*f^
— l?.7f
/o
Nozzle ID:
Thermocouple »:
Pretest Leak Rate: ,00? elm @ j£ in. Hg.
Pretest Leak Check: PHot: ^ Orsat: ^
Probe LengthHype.
Stack Diameter:
Pilot*:
As:
Assumed Bws: JJ[ Filler *:
Meter Box #: ftf-it Y: /,0y/ A>
Post-Test Leak Rate: ^OQ?, elm
Post-Test Leak Check: Pilot: ^
in. Hg.
Orsat:
AT'
Traverse
Point
Numbei
V
A/2
ffl
Sampling
Tim
(mln)
/o
ir
zo
55-
(00
Qockrima
(24-hour
dock)
76y.
GosMelar
Reading
(Vmjn3
772.
727.7^
•732.^6
71
77;. f*
, f ^
,¥3
^00, 70
Velocity
Head (Ap)
lnH2O
Oiica Pressura Differential
(AH) In H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
Ptob*
bnpinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmln0F)
Outlet
(Tmout°F)
^7r
.76
.77
_Lo
tT
J.^
/.I
.11
M
JiO
l.dT
Jo
J./76
9.7/G
1.01 r
r.i
-Z..7
10
I7C
f3i
n*
(Vf
/Ji
767
767
267
TV 7
-277
"20
7JO
761
•27?
?Tf
77?
771
5?
sz
11
55'
58
ri
rt
60
ev,
167
;or
Kf
1(6
107
t<>7
ho
(to
HO
(II
(61
/O?
ft
?7
fc
16
n
fr
fc
Tin=
Pump
Vacuum j^"^1
On.Hg)
•/o
rz
/r
a
/^
/X
13
-------
PARTICIPATE/ SAMPLE RECOVERY DATA SHEET
Client/Location:
Sampling Date(s):
RUN No.: £~MZ9~I Rec
Impingers:
Final Wt.
Initial Wt.
Net Weight
Description of I
Silica Gel Coloi
Filter I.D. No.:
Description of I
Probe Rinse Cont
Impinger Content
1
7S6.0
575. /
/ GO , /
overy Dat
2
70Z.C
//?,4
mpinger Contents:
* *
'articulate on Fill
ainer I.D.:
e: ?/2
3
7/2,2
7&J.8
224
-2
•J Recovered
4
tf/,7
+16.9
4-,t
Total Hois
CLEAR
ber: DKC
Percent Si
Filter Coi
?U/A/
5
7/5.7
7/.2.C
3. 1
By: £>h
6
GflJ
Gff.l
-2.3
sture = ,?/6r3
jent:
itainer I
20
.D.:
if
Silica Gel
J]t$
9tf.$
fro
grams
X
Sealed: f#N
Liauid Level
.3 Container:
Liquid Level
Marked/Sealed: TON
Marked/Sealed: (YJN
RUN No.:
Impingers:
Final Wt.
Initial Wt.
Net Weight
Recovery Date:
1 2 3
Recovered By: _
5 6
Silica Gel
1010. \
5 JSP
ffT./
7ff.3
5m
/5f7
8153
7/3,1
102.2-
7*7. £
ffA?
300.3
7*6.1
71 W
7ZS
£f5.5
6*t.S
3,0
?50,\
m,6
3/.S
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
grams
Percent Spent:
Filter Container I.D.:
Description of Particulate on Filter: F/lT£& WET & 8U)b/N
Probe Rinse Container I.D.:
Impinger Contents Container:
j=i_^ Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
RUN Ho.;l"/l/|2^.
Impingers:
Final Wt.'
Initial Wt.
Net Weight
Recovery Date:
123
Recovered By: _
5 6
Silica Gel
$51.6
739.1
236.5
352-2
$09,7
3.2.
2f.2
35.2
Xltt.7
--223
77.5
TT-^
Description of Impinger Contents:
Silica Gel Color:
Filter I.'D. No.:
Totalr Moisture = jtf'.O _
f SLIGHT ttw/COLD*
grams
Description of Particulate on Filter: HEW/
Probe Rinse Container I.D.:
Impinger Contents Container:
Percent Spent:
Filter Container I.D.:
_ Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
BLANKS: Probe rinse:
lapinger:
-------
PARTICULATE/ SAMPLE RECOVERY DATA SHEET
Client/Location:
RUN No.: X'MZ.9-^ Recovery Date:
1 2 3
Impingers:
Final Wt.
Initial Wt.
Net Weight
Sampling Date(s):
Recovered By: _
5 6
Silica Gel
005 A
173
1(0.0
710.3
.STf.f
'1*8. /
7/K3
2.9
03.0
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Total Moisture = *? S*Q. *? grams
Percent Spent:
Filter Container I.D.:
Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
RUN No.:
Impingers:
Recovery Date:
1 2 3
Recovered By: _
5 6
Silica Gel
Final Wt.
Initial Wt.
Net Weight
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Total Moisture =
grams
Percent Spent:
Filter Container I.D. :
Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt. '
Initial Wt.
Net Weight
123456 SilicaGel
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Total Moisture =
grams
Percent Spent:
Filter Container I.D.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
BLANKS: Probe rinse:
lapinger:
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
In
Pacific Environmental Services, Inc.
;.. Dry Molecular Weight Determination
Orsat No.
Operator
Comments:
Site Location:
Q-1-
Run 1
0,'
CO"
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md
Run No.(s)
^
Gas
•
CO,
o,'
CO"
N,'
Run 1
Actual
ft1/
20,6
Net
^
p-.i
Run 2
Actual
Vb
2.t.o
Net
$,&
(14
Run 3
Actual
Net
Average
Net
Volume
%
«K
&%
Multiplier
0.44
. 0.32
0.28
0.28
Molecular Weight
of
Slack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
Gas
•
CO,
o,'
CO"
N,c
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md»
* O, Net Volume is O, actual reading minus CO, actual reading.
* CO Net Volume is CO actual reading minus O, actual reading.
c N, Net Volume is 100 minus CO actual reading.
-------
Pacific Environmental Services. Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. 'F
Run No.(s)
v 2/1
Run No.(s)
/VP
Gas
CO,
<6
/&0.0
Net
M
/if
79. >
M I f • °£> > Great No.
Operator:
Comments:
Site Location:
Run 2
Actual
f.Y
^.fc
tM.O
Net
^,V
/?'/
7^2-
Run 3
Actual
Net
£/~ ^*
fi-J&i
S&tU/L/ <£^7
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
?,70
^2?
2/f<5?
Md= ^£j?
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
#^t
£<£/
2/<7b
Md= 2/9 /^*
A~^~''
te.07-
Run No.(s)
Gas
•
CO,
Oi§
CO"
N,e
Run 1
Actual
Net
Run 2
Actual
Net
Run3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md-
*O, Net Volume is O, actual reading minus CO, actual reading.
" CO Net Volume is CO actual reading minus O, actual reading.
c N, Net Volume is 100 minus CO actual reading.
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. 'F
Orsat No.
Operator:
Comments:
Site Location:
0-2.
Run No.(s)
\*fr
Gas
•
CO,
o,'
CO"
N,e
Run 1
Actual
16±
tod
Net
1^
11.4-
Run 2
Actual
/fc/
11.4
Net
/
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Run No.(s)
Run No.(s)
"j^£*^y
L*^ feJPW
Gas
•
CO,
Orsat No.
Operator.
Comments:
Site Location:
Run 2
Actual
1/.1-
V2.0
Net
||,V
'Ml
Run 3
Actual
Net
iJ ~~r~*
P 5tS*-Mj
1 '
////fr »
Average
Net
Volume
in
/A/
Gas
CO,
o,'
CO"
N,«
Rum
Actual
M.ft
Z2-.^
Net
(fij
^.»
Run 2
Actual
w
(/
Multiplier
0.44
0.32
0.28
0.28
9
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
<\
Run No.(s)
Gas
•
CO,
o,'
CO"
N,C
Run l
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Mi*
* O, Net Volume is Oj actual reading minus CO; actual reading.
" CO Net Voluma is CO actual reading minus Oj actual reading.
-------
Client/Location:
RUN No.:
PARTICULATE/ SAMPLE RECOVERY DATA SHEET
Sampling Date(s):
Recovered By:
Recovery Date:
6HR.
Impingers:
Final Wt.
Initial Wt.
Net Weight
1234 5 6 Silica Gel
57t, 0
575.6
04
£ff/,Z
6%0,£
0,+
732.2
732.3
0,5
62/.J
621, Z
O.I
743.1
1+5A
0.0
737. £
73 ?. £
0.0
Z29.0
K8.Z
0$
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Total Moisture =
grams
Percent Spent:
Filter Container I.D.:
Sealed:
Liquid Level Marked/Sealed:
Liquid Level Marked/Sealed:YN
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt.
Initial Wt.
Net Weight
1234 5 6 Silica Gel
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Total Moisture =
grams
Percent Spent:
Filter Container I.D.:
Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt. '
Initial Wt.
Net Weight
123456 SilicaGel
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Total Moisture =
grams
Percent Spent:
Filter Container I.D.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Sealeefi~Y~N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
BLANKS: Probe rinse:
lapinger:
-------
Appendix A.2
Raw Field Data
-------
Plant: & F\
Date:
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
r
- 9./- 17
Samohng Location:
Inside of Par Wall to Outside of Nippie:
Inside of Near Wall to Outsiee of Nipple *~
dd
Schematic of
Santpiing Location
larnpii
Traverse
Point
Numoer
I
Fracnon
of
Length
, 0\L
^ W^iwS).
3
9
$
c
0
«
1
\
, If*
,1-77
, *ro
,3»J-fe
, t>&
.1*0
i 8±*
^91
. fa
x ^11
Lengtn
(inches)
1^
1
,
\
T3T*
f
Proaua of
Columns 2 & 3
(To nearest 1 /8")
US"!
<-D
^^€5
\0,9-
\^.1
7C.T
Vy.3
rQ>.2«.
6J.-7
6c,,i
6R,°|
•73.4,
Nipple
Length
(inches)
4-.?5"
\
.X
Traverse Point
Location
(Sum of Col. 4 & 5)
S".tf
^r,p7
I 3- )
i -7--*
•^3. 0
3o,«)
r^.c
Co.r
GS-.^
^70,4-
7^-4
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Page
of
Client
Location
Prepared By Date Checked By Date Sheet Title
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: r,M Date: °l"^5 -91
c
f
I
1
c
\
0 «) PCW-*-
£ *<-
"<
.3 c<"
e> —
it, i«^
-T"'
o
^x \
* ^
/C^ £~ *-4^
I £^ £• ^-**
' • I £• ^*|11^'
Sampling Loc
^un#:_id
Barometric P
Moisture, %:
Stack Dimen
/Vet Bulb, °F
Point
Numbar
A /
1
--.3
. V
5
6.
7
g
^
to
11
11
V2> '
2-
7,
V
.5
U
7
fj
^
lO
ll
\1
:ation: ^,,^/< n^-hiA- Clock Time: yz.'?*/
\M^.^c,^J nnnratorS! 7nrf-y(5r,
ressure, in. H
ia: static Pressure, in. HoO: . /"7
Molecularwt , Drv Pitot Tube, Cp: - ^ .
sion, in. Diameter or Sick
: DrvE
Velocity
Haad
in. H2O
,7-j
,^ *y
.?z
,55
^5 2-
« 5^
.^1
.^
. V_5
,V^
•3S
'J,O
3-7
»3^
,V3
,^
'V 7
<$L
-SI
•H$
• ^13
•*{0
55
Oz
^p -
Stack
Tamp.
°F
'Tf
/3Z.
\}/J
*3^/
'11
J35
. i^
/3f
/&
• }?
i U
I3>J
137
'3>?
} bL
i&
•3$
;35
/3?
•35
>&J
t&j
>&3
l?>\
Ta-
J1: -7^ Side 2:
?ulh,°F-
Md - (0.44 x %CO2> + (0.32 X %O2> -t- (0.28 X%^)
Md - (0.44 x ) -t- (0.32 X ) + (0.28 X )
Md-
% H.O % HO
™ 100 100
Ma-
Ta- °F- 0R(°F-..460)
Pa - Pb + S-P' = ( ) +
13.8 13-8
Pa - In. Hg
VS? =
— I Ts(°R)
y i s x MO
Va- ft/a
A.- ft2
Qa- VaxAaxMa/m
Qa - x X00
Qa - acfrn
Pa %H,0
08^.= Qa x 17.847 x x (1 • =— )
91U yj 1IM
atd 100
O«std~
-------
Plant:
Sampling Location
Run Number: TU°|-O| Date:
Pretest Leak Rate: 0.QQ5 cfm
FIELD DA I A SHEET
Sample Type: |/X) •
Pbar:
C02:
Operator:
Ps: +\ . \
02: 10 %
Nozzle ID: .2 $5 Thermocouple it:
Assumed Bws: /TJ^ilter #: 3465
Meter Box *:W15-loY: O^AH®: /.S9/
Pretest Leak Check: Prtot:
Orsat:
in. Hg. Probe Length/Type:
Stack Diameter: 75
As:
Post-Test Leak Rate: g:{X>( c^m © _2l 'n-
Post-Test Leak Check: Pilot: v^Orsal: .
Travaree
Pobil
Number
Sampling
Time
(mln)
QockTime
(24-hour
dock)
Gas Meter
Reading
(Vm)ttS
Velocity
Head (Ap)
inH2O
Orifice Preuur* Drlfercntiat
(AH) in H20
Desired Actual
sired "J
7/7//
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filtw
Impinger
Temp.
°F
Dry Gas Meter Temp-
Inlet
(Tmin0F)
Outlet
(Tm out°F)
Pump
Vacuum
fm.Hg)
O
2.
10
15
-734
.73^
••73
73
1,0
50
li
?
20
24B*
43
30
£??»/?
L36.
Zto
4.
2S2*
232
'
35
0,51
i,53
^5/?a
i.
260
1.98
Zrs*
7?
5"
50
55
0,63
256
•101
255°
5''
304,^8
LB6
Z54*
8
70
L:
^5-5-°
75
,&(>
''
O
35
3m 7 36
• l.t,
i.
18
:te
73
?
252.
1. 8
82°
5"
"
3380^
0.2S
^2i
14:4^ iWcktoM
^/
- zm" m. /,gy is. /«s"
-------
. I , r 2,
:: Grt
Plant:
Sampling Location CpHpalfr 4B
Run Number: rTU°K?-2^ Date:
Pretest Leak Rate: ,002 cfm (
FIELD DA I A SHEET
Sample Type: W\ %tf Operator:
Pbar
'J
C02: J!_%_02:_LQ_7b
i|"in. Hg. Probe LengttVType: *7 '$
Nozzle ID:0.?55 Thermocouple
Assumed Bws: /7^Rlter #
Meter Box #:^s-to Y: ^11
Pretest Leak Check: Pitot:OK , Orsat: 6,
Stack Diameter: 15' As:
#: £•? -Z Post-Test Leak Rate: .flpf cfm @ ^ 'In. Hg.
Post-Test Leak Check: Pitot: Q^
-------
Page 2- of
Plant Name:
Run Number:
Test Date:
Operator:
Traverse
Point
Number
Sampling /dock Time
Time, / (24 hour
fmin.) / clock)
Gas Meier
Reading
Velocity
llead^P.)
iiLlhO
Orifke Pres. Differential
(£ll)in.U2O
Desired
Actual
Slack
Temp. • F
Probe
Temp./ Filter
Temp* F
Impingcr
Temp.
•F
Dry Oas Meter Temp.
Inlet
UUIICI
Pump
Vacuum
IlLllg
13.0 '
\
0.30
(9.81
fl
13-3
07
2,
130 '
1315'
9?
23/20
/31'
-78
"
3
'r
133
436,21
hJ
132
b
0,47
1,3
s
W5A
L32'
no
0.4
,323
,3
I3/
14
17 r
r-
7
iSS '
57,
OS'l
1,377
8
/
60,66
1,3??
MS /
OAl
*
£60 /
as73
205 /
,617
42
83°
"
210
5'
1.6
•fz
N
22P /
Jii
Ml
2sz_
Oil
IiZ.
2-36 / \^
<£>«?/
1.1*7
TSft
^5.876
-------
'^\Ql t^lCtoQ
f~* W\ O
Plant: Uf. I l> O
Sampling Location ^egpaN
Run Number: 0 - rVtt^ - 3 Date:
FIELD DA IA SHEET
A I
Sample Type: ^^9 Operator: Mot/one.
Pbar. ^Qt)O Ps: D-35
C02: l|% 02: [O%
Pretest Leak Rate:. QQ2- cfm @ ID "in. Hg.
Pretest Leak Check: Pilot: o^. Orsat: (9,«i
Probe LengbVType:
Stack Diameter: 75"
Pitot #: P-7'4
As:
Nozzle ID:^rQ^fflermocoup»e #: DloO-7
Assumed Bws: fo% Fdter #:
Meter Box #: W-IO Y: -W
Post-Test Leak Rate: >G&Z. cfm @/J_ in. Hg.
Post-Test Leak Check: Pitot: Q.'/t .Great:
0
-------
FIELD DA I A SHEET
Plant:
Sampling Location
Run NumberO-
Data: Cf-26~cl'7
cfm @ [\ _ in. Hg.
Sample Type:
Pbar: £.4 JO Ps:
C02:
Operator:
Q »35
11% O2: ( O%>
Nozzle ID: - 3 1 Q Thermocouple »
Assumed Bws: (£^fiHer #:
Meter Box *: n5 - K3 Y:
Pretest Leak Rate:
Pretest Leak Check: Pilot: O.K, Orsat: O.
Probe Length/Type: *J ^
Stack Diameter:
Ptot #: k-
As:
H@: /« 5i
Post-Test Leak Rate: 6MOZ cfm @ j/^in. Hg.
-------
PARTICULATE/SAMPLE RECOVERY DATA SHEET
Client/Location: r £3[ V^\ ~jn
-------
Client/Location
RUN
PARTICULATE/SAMPLE RECOVERY DATA SHEET
iQn; feS/GHrftGMtW Sampling Date(s): ^/Z^??
T* Recovery Date:
Impingers:
Final Wt,
Initial Wt.
Net Weight
Recovered By: _
5 6
O/7A
Silica Gel
isq.3
IO.B
1.4
I.
/.r
-.3
77?. 7
19.5
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Total Moisture = -t-O ni* T
grams
Percent Spent: 50
Filter Container I.D.:
Sealed: Y N
Liquid Level Harked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt.
Initial Wt.
Net Weight
123456 Silica Gel
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Total Moisture =
Percent Spent:
Filter Container I.D.:
grams
Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt. '
Initial Wt.
Net Weight
123456 SilicaGel
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Total Moisture =
Percent Spent:
Filter Container I.D.:
grams
Description of Particulate on Filter:
Probe Rinse Container I.D.:
Impinger Contents Container:
Sealed: Y N
Liquid Level Marked/Sealed: Y N
Liquid Level Marked/Sealed: Y N
BLANKS: Probe rinse:
Iipinger:
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Orsat No.
Operator
Comments:
Site Location: /
Run No.(s) Gas
Run 1
Actual
CO,
CO"
/C7V.0
Net
Run 2
Actual
to
-2XB
Net
Run3
Actual
Net
Average
Net
Volume
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md
Run No.(s)
°»
CO,
o,'
CO"
N,'
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
Gas
•
CO,
o,'
CO"
N,'
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md>
' Oj Net Volume is O, actual reading minus CO, actual reading.
" CO Net Volume is CO actual reading minus O, actual reading.
0 N, Net Volume is 100 minus CO actual reading.
-I—
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. 'F
-70 '
Orsat No.
Operator:
Comments:
Site Location:
Run No.(s)
*<«
mm
CO,
o,'
CO"
N,e
Run 1
Actual
toj
22.Y
/«
IZ.O
77.7
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
vC^?
3,%0,1> 772
Run 2
Actual
/o.fc
Net
Run 3
Actual
Net
Average
Net
Volume
"777
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md
* O, Net Volume is O, actual reading minus CO, actual reading.
0 CO Net Volume is CO actual reading minus O, actual reading.
c N, Net Volume is 100 minus CO actual reading.
2-
5 /0-Gr
-------
Pacific Environmental Services. Inc.
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
7*
Dry Molecular Weight Determination
Orsat No.
Operator. __
Comments:
Site Location:
Run 1
77 /
Run 2
Actual Net
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(IWMols)
Run No.(s)
Gas
CO,
o/
CO"
N,e
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md =
Run No.(s)
Gas
•
CO,
o,'
CO"
N,'
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md*
• Oj Net Volume is O, actual reading minus CO, actual reading.
" CO Net Volume is CO actual reading minus O, actual reading.
' N, Net Volume is 100 minus CO actual reading.
0'
fa^
W?
-------
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Orsat No.
Operator
Comments:
Site Location:
Run No.(s)| Gas
Run 1
CO,
0,'
CO"
N,c
Net
u
A
Run 2
Actual
Net
WA
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
11. 83
Md
Run No.(s) Gas
Run 1
Actual
CO,
0,'
CO"
N,c
Net
Run 2
Actual
17
Net
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
-L/-7E
Md
70,
Run No.(s)
Gas
•
CO,
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
'PA
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
10
/ MM
'
Orsat No.
Operator.
Comments:
Site Location:
Run 1
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
0.32
0.28
0.28
Run No.(s)
Run 1
Net
Run 2
Actual
10-
Net
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
Molecular Weight
o»
Stack Gas. Md
(Ib/Mole)
0,'
0.32
CO"
0.28
N,'
0.28
Md
Run 1
Net
Run 2
Actual
10-*)
Net
Run3
Actual
Net
Average
Net
Volume
Multiplier
0.44
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
0.32
0.28
0.28
Md
' O, Net Volume is 0, actual reading minus CO, actual reading.
" CO Net Volume is CO actual reading minus O, actual reading.
c N2 Net Volume is 100 minus CO actual reading.
-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Pacific Environmental Services, Inc.
Dry Molecular Weight Determination
Orsat No.
Operator:
Comments:
Site Location:
Run 1
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md
Run No.(s)
Gas
•
CO,
o,'
CO"
N,e
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mols)
Md =
Run No.(s)
Gas
•
CO,
o,*
CO"
N,«
Run 1
Actual
Net
Run 2
Actual
Net
Run 3
Actual
Net
Average
Net
Volume
%
Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
Md-
*O, Net Volume is O, actual reading minus CO, actual reading.
" CO Net Volume is CO actual reading minus O, actual reading.
* N, Net Volume is 100 minus CO actual reading.
-------
Gn
Plant
Sampling Location
-—t^Run Number: fe V* Date:
FIELD DA IA SHEET
Sample Type: jfV3_2l__ Operator:
Pbar 9*)."? 4- Ps: J- \. t
C02: ~ O2: l,Q
Nozzle ID: .2*3. Thermocouple #:
Assumed Bws: ) 1 Filter #: )*i ?^-
Meter Box #: g*.6>», Y: \.0lo
Pretest Leak Rate: »0o> cfm @ \J in. Hg.
Pretest Leak Check: Pilot: (/ Orsat: V>> A
Probe Length/Type:
Stack Diameter: "1
Pilot #:
As:
Post-Test Leak Rate: ,Q0 3 cfrn @ j£_ in. Hg.
Post-Test Leak Check: Pilot: ^ Orsat:
Traverse
Point
Number
Sampling
Time
(mln)
(24-hour
dock)
Gas Meter
Reading
(Vm)tt3
Velocity
Head (Ap)
'inH2O
Orifice Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filter
tmptnger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin°F)
Outlet
(Tmout°F)
Pump
Vacuum
(in.Hg)
y//////////////y//////////////////////^^^
O
\.o
1.0
is
IS
.01 t
feJ.
L 0
Sfi
S
\. 1
\\o-
"Mb
7-7
_t
10
JL
$7
S
40
3:55
1JJ
Wo
^00
A
(a
114-
SI
-o
i IS
(ob
_r
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•n
r /
to
a I
\0
sS
\IC,
£L
voo
VOJ
\ ^-
\r
\1
-------
09/09/97 10:19 ©19199410234
PES RTF NC
©003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant: C-aJi( - Sb4C^mMk)
Sample Date: QJZ?)^
Sample Location: B> &v~crdL
Recovery Date: n|^ 1 ' ^
Filter No.fs): *S^-t3-«
r\ / _rx^£-u.ftfte^ ( MTtfr
Run No.: 50> -25- 1
JobNo.:SHM.il3
XAD-2 Trap No.(s): ST 0 - £3 ~
Sample Recovery Person: K^~|£)E_
1
Impingers XAD-2 (knockout)
Trap
Final wt. — (^(o-3
Initial wt. — 4^,4-
Netwt. ~~ /5V- 6
2 3
(100mlH2O) (100mlH2O) (ki
(untipped) (tipped) (u
70^3 >/?.3 <
"7.03,^ ^iT-,1^ 5
• *A3 -a.ro
4
lockout) Silica gel
ntipped) (untipped)
5f5W ggO.-^ g
f y O Z^Mf^TA : g
/.^ 8^-^ • g
Train System: E^PPl fAsVfte
A Z3 /l>ox ^24 / TOTAL: A/.?
Probe: 1 hb?*> / CJter
Filter: Color - (Jret, / T,\n
Loading- (H^:^
Filter Container No. S^ " t-
XAD Module Container No.: ^
3V
"o - Z3V
Probe (FH) & Back Half Rinse (Acetone) Container No.: -2 3 -/
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.
It ut-f\4
Impinqer Rinse (Acetone/l\d«St2)
: S.-ZJ'/
Container No.:
marked/sealed:
marked/sealed: <-^
Liquid level
marked/sealed: ^/
Liquid level
marked/sealed: ^*<^
Liquid level
marked/sealed:
Liquid level \/
marked/sealed: ^
-------
FIELD DA I A SHEET
V
Plant: Cot<\ 9j «=>
Sampling Location
Run Numberf) VV>
^-s\V
^fo
>rv
'N'V
Ob-
Date:
x*f
a-^<\-^'
Sample
Pbar:_2
) C02:
Type: V
<1
\^^J
Ps:
02:
Operator
-T"l,
i?
i
OA
Pretest Leak Rate: -003- cfm @ j£ in. Hg.
Pretest Leak Check: Pilot: J/_ Orsat: rQ*
Probe Length/Type: _gj_
Stack Diameter:
Pilot #: 9 <-
As:
Nozzle ID: . IS 3- Thermocouple »:
AssumedBws:HFilter#:
Meter Box #:
Post-Test Leak Rate: $>-
->-s>-
-W-
If
-3-
Jlfe
95"
(bo
63
65
t-7
e-7
70
U
•is
jza
JT
fa
JT
*•/
-------
Page
of
Plant Name:
Run Number: .
b \W1
Test Date: _.
. Operator: _
\Vi
f
Traverse
Point
Number
Sampling /dock Time
Time, / (24-hour
(min.) / dock)
Gas Meier
Reading
Velocity
llead^P.)
in-lhO
Orifice Pres. Differential
(AH)in.H20
Desired
Actual
Stack
Temp. • F
Probe
Temp./ Filter
Temp" F
Impinger
Temp.
•F
Dry Gas Meter Temp.
net
UUIICt
Pump
Vacuum
In.llg
YK
\\ii-
.a
JT
\,0
l.o
l.o
jr
\-X\-L
Sy
7*
\<<>
\1J-a
4-0
\,
Sl-
is
sl
5-4,
V\0
7
fcl
VI
u
9;-
er
1S-7
Z.2-
'O
VCo
j
JO
a
10
i
XT*
T-Vi
4.
_Uc_
Ifc
rr
305.
v>
\1>V
/^
-------
09/09/97 10:19 ©19199410234
PES RTF NC
©003
/
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant: (^
A/I s^~~>
iYl-s.AC/j0.^a)
Sample Date: QlZ'JnJ-
Filter No.(s): S6-Z3-2,
Run No.: *So-*3-2
Job No.: ^5«/A/. ^^3
Sample Location: Y) i^MDita ^—^cr^D^f Ot. | ^CXo-H
~K)O i -5 ~3\5(0, u
- • »H o. z.
4
1 (knockout) Silica gel
(untipped) (untipped)
(^t>5v 6 8^&.?- 9
UjO^.2. ^>*y*D g
O £ ^ * 1 ••• M
^** 1& ^ v» / 9
Shl^SiliraiS^l^ll^iiS^
ii z^ / fe^ IB- M-5
/T^~r/)U If Li. L
Probe: ^' ^\0^>
Filter: Color- TAU
Loading - n&Au »v>
Impinger Contents: CJ<2ar-
Silica Gel:
@Grams Used - ^fx:
D Color - U . h^ % Spent - (^ b
Condensate Observed In Front Half: MO -^ >?^/3
Container No.:
marked/sealed: <-^
marked/sealed: ^
Liquid level ,
?>'^ marked/sealed: <:-^
Liquid level
marked/sealed: k<"
Liquid level
marked/sealed: <• — "
Liquid level ^
marked/sealed: N
-------
Plant: V-, V\
Sampling Location
Run Number:
FIELD DA IA SHEET
Operator: (j
Pretest Leak Rate: .
Date:
cfm
Sample Type:
Pbar:
CO2:
Ps:.
O2:
1.1
\S jn. Hg. Probe Length/Type:
Pretest Leak Check: Pitot: i/ Orsat:
Stack Diameter: IS
Pitot #:
As: 3p. Gfe
Nozzle ID: atfQ. Thermocouple #: jT£
Assumed Bws: jfe Filter #: £oa> 3
Y: I 0/fr AH@:
Meter Box #:
Post-Test Leak Rate: . Q|CJ cfm
Post-Test Leak Check: Phot:
tXO
in. Hg.
rsat:
Traverse
Point
Number
Sampling
Time
(mln)
dock Time
(24-hour
dock)
Gas Meter
Reading
(Vm)ft3
Velocity
Head (Ap)
inH20
Orifice Pressure Dittertntia)
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filter
Impinger
Temp.
Dry Gas Meter Temp.
Inlet
(Tm in°F)
Outet
(Tm out°F)
Pump
Vacuum
On. Hg)
y////////////////////////////////////////////////////////////,
Kft
los
6-S
JT
I? « 4-
se,
\5
•Z.-7
TO
to
110
7V
77
45
no
Wo
_3jL
IQ^
7-Sp
ro
7o
Z.
1-1
1.4.
3.4-
In 7
rj
71
l-r
/07
w/
S
55
3,4
IcO
2-
7)
(bo
LT
TJ-
rs JT
• V*-
*?/-
LS
1.2,
1.7X
/r
fS
j-f
, .3
/r
VO
\0\q
-SV
\\
f S"
IQQI
57
9$
76
\VO
VQI
af7
-------
Plant Name:
Run Number:
Page
Test Date: ft
Operator: C^c*
of
Pump
Vacuum
IlLllg
Traverse
Point
Number
Sampling /dock Time
Time, / (24-hour
(min.) / clock)
Gas Meier
Reading
Velocity
llead^P,)
in. IhO
Orifice Pres. Differential
(All) In. 11,0
Desired
Actual
Slack
Temp. • F
m
Probe
Temp./ Filter
Temp* F
Impinger
Temp.
•F
Dry Gas Meier Temp.
Inlet
UUIICI
o
1,0
&
'i.O
I ID
7-7
*
f/D
fe/
71
\01
70
17
/J-
\
4*9,1
-3-0
2 53 /
6V
3.3
3,3
\5° ' MM
3,3
lD
If
14-
2.4-
i
v SO
o-ft.
HO
Ml
***
40
L5"
3.5
II
\lo
\l A
/6
hi
\\
V.I
ll 2)
IU
tt
f o
n
10
\\\
,\
\r-
-------
09/09/97 10:19 ®19199410234
PES RTF NC
@003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant: ^Af — ^A&IVA
Sample Date: ^/to/^^-
u/
Filter No.(s): l3T)~2£-3
Run No.: SO -.2V =i
Job No.: SHH . 6b?>
/*""} x1*
Sample Location: *j C>^p©(a j^cru/lob^y— *Ovc*t,ET"~
Recovery Date: ' 9 /£$ / f ^
XAD-2 Trap No.(s): S»& - i3'3
Sample Recovery Person: M^- 1 v3>E-
siig^^
Impingers
Final wt.
Initial wt.
Netwt.
i'ggg^g
1
XAD-2 (knockout)
Trap
— 8>5»C>
"^ ^TSTo?
3^-^
2 3
(100mlH20) (100mlH20)
(untipped) (tipped)
l»^.0 7-/V. ^
"^Q-^. ^ ^l^.ly
- /A . 5" -* 3"* V
r.r£1r£^lri'2i'Hwi^i^'.->-":^':;i;s^»;'-rf;;;'v]^?&>w-,''
..;. i: -Vv%^;i;«-^yi^H^^'^*OSii^:3KXi^y;i,
•...."— . -• .•...••l-'_-.Tr«i ':• ••• •^'-•••^-.^ -.'Oi- .»^. ••'•-. .,".'?;CV';— «^c
4
(knockout) Silica gel
(untipped) (untipped)
* * \s^^ *j y
S*fcr.< Q£0*3> g
>. 2 ^?.z. g
f|S^^^J;!|^^":|i|g^
J;..l..^;.•:^f:^^.A:v.:^i•::•:^^.-^V^^:fy•^;'^•v:^x-•^.•".^;.^l>-.^•^.WSi?.V•J.HIWW•.•^.™;,-^^^
Train System: E?/X (^e^u
) 9 ^ / ^D si I ts ' AJ - <
«L X- P / 1 JO' ?v 1 1 3 • r N .3
h~ferAu: Wbrt
Probe: Cxi ^£v*~
Filter: Color- "T^^
Loading- N€cl^
^
Impinger Contents: C \-eat
Silica' Gel:
@GramsUsed- 3o6 Color- jlf. I?/A# % Spent- U6
Condensate Observed In Front Half JUndB
»;:•::•:•:• ;i™-:'.-,'i-:-.:i:'i:-.r«S','>-t,-;., i:/.^v-;i.v*.vv^Vi:-K'.;£."™^^«iV^i'v:JA^
Filter Container No. fSo - ^- 3 - 3
XAD Module Container No.: So ~ 2. ;>•"./
Probe (FH)
Probe (FH)
& Back Half Rinse (Acetone) Container No.:
& Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.
Impinger Rinse (Acetone/MfSSSj
£-2-3-3
Container No.:
marked/sealed:
marked/sealed:
-i _ j Liquid level ,
marked/sealed:
Liquid level
marked/sealed:
Liquid level ^
marked/sealed:
Liquid level
marked/sealed:
-------
Plant:
Sampling Location
Run Number:
Date:
Pretest Leak Rate: vOoS c(m @ \£_ In. Hg.
Pretest Leak Check: Pilot: J Orsat:
FIELD DA IA SHEET
Sample Type: X*\'V2? Operator:
Pbar: ^A.N Pa: T 19 3
C02: ID O2: | ~L,
Probe Length/Type: "g1'
Stack Diameter: ~\ 6
Nozzle ID:
Thermocouple
Assumed Bws: \p Filler f :
Meter Box
PHot #: ye,
As:
Post-Test Leak Rate: «Q£>;I ofm @ j^ In. Hg.
Post-Test Leak Check: PHot: J^jDrsat: /»
Traverse
Pbbit
Number
Sampling
Time
(mln)
Qock Time
(24-hour
dock)
Gas Meter
Reading
Velocity
Head (Ap)
inH2O
Oiice Piessui* DrftBrenhaJ
(AH) In H20
Desired I Actual
Stack
Temp.
(Ts)
Tempeiature
°F
Probei
Rlet
Impinger
Temp.
°F
Dry Gaa Meter Temp.
Inlet
(Tmin0F)
Outtel
(Tmout°F)
Pump
Vacuum
On.Hg)
4-
5
\o
Ins
3.1
3.1
3,-z.
11-2-
n
U 1
15-7
flfl
to
Co G,7
Co 60
60
feo
13
)o
a
1
Til-
60
40.
3.
3.5
13L
VO
QO
CoKJ
0..-J
2.4-
•2-.
I |
\\
t, T,
-------
of
Plant Name:
Run Number:
V>
Test Date:
Operator:
irv--<
Traverse
Point
Number
Sampling /dock Time
Time. / (24-hour
(min.) / clock)
Gas Meter
Reading
Velocity
Orifke Pres. Diffeieotial
Desired
Actual
Stack
Temp. • F
m
Probe
Temp./ Filler
Temp." F
Impinger
Temp.
Dry Gas Meter Temp.
Inlet
UullCI
Pump
Vacuum
liullg
0
z
'b. V
<<*•&
14-
, 4-0
3.3
toy
213 /
U
Uo
3,-f
( OV
/
toy
_£JL
O
It
f-
3,
1). 3
1 /t?
60 6)
qf-
Sf-
o-
3-5$, '
61
93
f 07
£&
\qS
IDl
to
y •>
14
\0
4-0
S
1.1
loyj
60 JY
- 1
Oi
li
len
*">
\\
&i
If-
H.
-Ms
Ak
JLL
Ik
-------
09/09/97 10:19
©19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant:
: C?M -
jOAW
Sample Date:
Filter No.(s): Sb-
Sample Location:
r.
Recovery Date: °( \fi\ °i\ |XAD-2 Trap No.(s): SO- 25"
Sample Recovery Person:
^;?"'vv:^*'':-;-"'i'v'~£'^??'^^~^':yi:;K^
^gr-^Sr?^^
Impingers
XAD-2
Trap
1
(knockout)
(100 ml H20)
(untipped)
(100mlH2O)
(tipped)
4
(knockout)
(untipped)
Silica gel
(untipped)
Final wt.
_g
Initial wt.
Netwt.
^^
A^^^
^3 / 6fr/ Kj -5 /
:?•
Train System:
Probe:
Filter: Color-
Loading - N\6 D ( UAA^
Impinger Contents:
Silica Gel: @Grams Used -
Color-
% Spent-
Condensate Observed In Front Half: M"D
g':sr
•Wfr-ttS;
K!^::
*?=ii^p®-
Filter Container No.
marked/sealed:
XAD Module Container No.:
marked/sealed:
Probe (FH) & Back Half Rinse (Acetone) Container No.: 5o-23-
Liquid level
marked/sealed:
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Liquid level
marked/sealed:
Impinger Contents Container No.: fv - 2-3 -
Liquid level
marked/sealed:
Impinger Rinse (Acetone/MeCI2) Container No.:
Liquid level
-------
FIELD DA IA SHEET
Plant: ^M
Sampling Location
Run
Pretest Leak Rate:
Pretest Leak Check: Pilot:
Dale: 7-23-7-7
cfm @ IS in. Hg.
Orsat:
Sample Type:
Pbar
CO2:
IV Ps:
02:
Probe Length/Type: 7'
Slack Diameter:
Operator:
/J
Nozzle ID: .
Thermocouple #:
Pilot #:
Assumed Bws: ,a(. Filter #: o^
Meter Box #: /-V Y: .?66 A
Post-Test Leak Rate: ^03^ cfm @ ^_ •"
75'/' As:
Post-Test Leak Check: PHot:
Orsat:
Traverse
Pobit
Number
Sampling
Time
(mln)
dockTima
(244iour
dock)
Gas Meter
Reading
Velocity
Head (Ap)
inH20
Oifice Pressure DHferenlial
(AH) in H2O
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Oter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin0F)
Outlet
(Tm out°F)
Pump
Vacuum
ftn.Hg)
0
O
tf/JS
y/////////////^^^^
/o
jjti...
AY
/
,7.7
255?
,*• 2-
7?
77
>>?:*»?%
20
•77
75-
7-5
Jo
/2-7
250
c
36
I.H
•2.30
SQ,
4-
35
, z.
/. 2.
66
67.
l.t.
/.S
•2.53
7C
55
. I*
z-SC
60
AC
TJ?
1
ScT
til
9-1,
_Zi_6_
/ .
TS
/..S
. "
tb
AJ
A-
Sy
/. 2.
0-7
-------
METHOD OOlcJifW SAMPLE RECOVERY DATA
f*
Plant: C^jij- V^f/JAW"
Sample Date: ^ (2? / *? ^
Sample Location: r) O^po
Recovery Date: ^) 1 £l 1 ^ 91
Filter No.(s): _S£> M/115' (
A /<^r,e_uA&^ T)UT^-
XAD-2 Trap No.(s): ^d - /^fc.f
Initial wt. — - M45*2)
!*tef wt «* A ^'5 (o
7z /. z 7^.2- ^
"::f--r';\-rJ.'^-;:"iJ',l.:.;a;%.-.«iSV'X.p:i>vS~'d /u YW
^f^^ ^-/Aw^M
Impinger Contents: Cj(Qo^
Silica' Gel: ©Grams Used - ^Dt> Color- I4^))1-L^ % Spent- VO
Condensate Observed In Front Half: jU>*J^
••::•:•?::.. f^-c-,»~-G4Z~-7&^
Filter Container No. £o-MM£ -*
XAD Module Container No.: ^
Probe (FH) & Back Half Rinse (Aa
/
-Mf '/
setene) Container No.: fa-hMt /
Probe -(FH) & Back Half Rinse CEofa*ne) Container No.: So-MM^-
Impinger Contents Container No.
Impinger Rinse (Aee*one/MeCI2)
: .^O-AA^-/
Container No.:
marked/sealed: <-/
marked/sealed: LX
Liquid level >•
^ marked/sealed:
Liquid level v
/ marked/sealed:
Liquid level S
marked/sealed:
Liquid level
marked/sealed:
-------
FIELD DA IA SHEET
Plant: £
Sampling Location
Run Number: o-
Pretest Leak Rate:
Pretest Leak Check: Pilot:
r. 2. Date: ?-
cfm
Sample Type:
Pbar: 3fr» 8S
CO2: °l
Operator:
Ps:
02:
ll
Nozzle ID: .230
Assumed Bws:
Meter Box #:
Thermocouple #: "7<1
Filter #: &—**/»?$'- 2.
Y:
<5_ in. Hg.
Orsat: —
Probe Length/Type:
Stack Diameter:
)' 6/eff Pilot #:
: / '•
As: J0. f» 8
Post-Test Leak Rate: foQz. cfm @ _?_ in. Hg.
Post-Test Leak Check: Phot:
Traverse
Point
Number
Sampling
Time
(mln)
aockFime
(24-hour
docfc)
Gas Meter
Reading
(Vm)«3
Velocity
Head (Ap)
inH2O
OriBce Presoure Differential
(AH) In H2O
Desired | Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe I Rltef
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin0F)
Outlet
(Tm out°F)
Pump
Vacuum
ftn- Hg)
O
O
///////////////////M^^
6
10
Wot
15
111 0
.31
/. V
62,
J^_
^
2-6
/2Z,
2=5
C-2-
/. 1
2.41
/.r
A -5
1*5
(tO
/. 5"
•70
?. t-
75
/.J
Cz.
t.
/,
CO
72-
62L
70
arc*
/. 2.
7f
to
1,2.
/o
/GO
31
1.1
1, <
ISO
3-?
A/
/I/
.TIL
Of
II
.31
M
ISO
00
7f
ITt.H
1.1
o-O
I'A
n
79
3"
/V-
ill
i2>0
•3-*
iii
= ,33.5
-------
Plant Name:
Run Number:
Page
Test Date: _JL_*
of
Operator: T/t
Traverse
Point
Number
Sampling / Clock Time
Time, / (24-hour
(min.) / clock)
Gas Meier
Reading
Velocity
Hcad^P.)
in. IhO
Orifke Prcj. Differential
(All) in. 1 1,0
Desired
Actual
Stack
Temp.«F
m
Probe
Temp./ Filler
Temp." F
Impinger
Temp.
Dry Oas Meter Temp.
Inlet
UUllCl
Pump
Vacuum
likllg
1 t z 15
38
1 i
. 3-7
M
16
3
J-5
S-G
.*!? *
/,£
O.O
38
93,
7?
2V
51
SY
9-1
1 £2.30
7
6,
35
1
Co
57
=h
.si
. 1
• 1
If
P3
*"&>
/.I
/•I
/•I
/. 7
CO
•He, 1 i 5 30
1.
^
i 2
9LT
2-24.
2*7, (
it
/.c
5-7
IZ.
7-5
SC
1 »H(sb
-------
METHOD
SAMPLE RECOVERY DATA
Plant:
Run
Sample Date: Q [ZM Hi-
No. (s):
- 2
Job No.:
Sample Location:
^^(ek
Recovery Date: l
>
XAD-2 Trap No.(s):
Sample Recovery Person:
V-V^V^j:^^^
^£g£-^;y&^
Impingers
XAD-2
Trap
(knockout)
(100mlH2O)
(untipped)
(100mlH2O)
(tipped)
4
(knockout)
(untipped)
Silica gel
(untipped)
Final wt.
Initial wt.
Netwt.
i" »••••*•.•-""'••"*' •«*-*vSj»~is**«* *— —'j***1* ••••*»• V-r-V-c'r':*«'***v^t'^'""7~*''"' 1 SliTAlii..''.'^"*;' •"«.•••.•••*»..•. ., •». .'';««.•-•• /.T***^*^*^".", *:• • > -"•" '"T -"it •;».—,- •••,••••— Vi'-'-^'1'.'.^.' .'•••^•^ "•*V"VtX*i"v*i-" »• ••rik*.'^'Si'XZ'»
..;,^^^^^;;^ 5^^;^^,:^ ^^
•:-i-"Z±r.vA-l?fr..^..*,-M%-J.:;;-*:y*:^
.
Train System:
Probe:
Filter: Color-
Loading -
Impinger Contents:
Silica'Gel: ©Grams Used -
Color - LA B U< % Spent -
Condensate Observed In Front Half:
Filter Container No So - MM ^ " 2—
marked/sealed:
XAD Module Container No.:
*4/l
-------
Plant:
Sampling Location
Run Number: &O-M.*?- 3 Date:
FIELD DA IA SHEET
Sample Type: AVH S Operator: T
Thermocouple #: 7C
Pbar: 2*7, I
CO2: if,
Ps: -f- . -7 Z,
02: /i
Pretest Leak Rate: JL
Pretest Leak Check: Phot:
in. Hg. Probe Length/Type: 7' 6f*>j Phot*:
Orsat:
Slack Diameter: "~7_T
As:
Nozzle ID:
Assumed Bws: r/o Filter #:
Meter Box #: /4 Y: >^^
Post-Test Leak Rate: ,oa^ cfm @ ^/_ in. Hg.
Post-Test Leak Check: PKot: —^"Orsat: —
Traverse
Poht
Numbef
Sampling
Time
(mln)
Gas Meter
Reading
Velocity
Head (Ap)
inHZO
Oifice Pressure Differential
(AH) in H20
Desired
Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe I Filtef
Impinger
Temp.
°F
Dry Gas Meter Temp.
Het
Outlet
(Tm out°F)
Pump
Vacuum
(in.Hg)
• .33
/•o
'5
Z. 5
2.
\\6
_LLL
2.^6
•2.39
Z-V2
31
"11
It
6 "I
7
J2_
1
3
5 3
.37
ILL
3.0
. --V7
-bo
6 "? 24
o
"7.5
7 s
,41-
CO
3,1
"76
/o
3-.
C2.
(•I
.35
*••
M
do
9
2.9
-\5
35
\ r
il 0
1,5
2,7
z.
HO
73
.31
t-o
73
,37
45
IK
/eo
hi
&tf*
?^J»»J,
. 5
i .5 2-
2-
-------
Page
of
Plant Name:
Run Number:
.SO -.*
Test Date:
Operator:
Traverse
Point
Number
Sampling
Time
(niin.)
ng /
, /
) /
dock Time
(24 hour
clock)
Gas Meter
Reading
Velocity
llcadfP,)
in. IliO
Orifice Pres. Differential
(£ll)in.U2O
Desired
Actual
Stack
Temp. • F
m
Probe
Temp./ Tiller
Temp* F
Impinger
Temp.
Dry Oas Meter Temp.
Inlet
(JUllCl
Pump
Vacuum
"L
\\lti
.32.
z.c.
2,6,
i/i
iHO 1
2.. (,
*•*
, /
Ho
£5
hd
$0
t
*<>
,1,6 1
3-V
3.V
Hi
SO
/O
,(,5 1 •* 00
1/
'~t6 1 ft It
3,3
75
"
-31
34
1*6 /
3.1
III
.35
2.-T
-S3
3*1
Hi
66
/J
J7
9
US
to
to
2-15
70
M
yz,
$
32.
Mr
IV
' ,30
-------
METHOD 00)0 SAMPLE RECOVERY DATA
Plant:
Run No.: So -
Sample Date:
Filter No. (s): So~/if#4-
Job No.:
Sample Location: S<.r~ky Ft
Impinger Contents: LJ\
Silica'Gel: @Grams Used -
Color - 1 1.
% Spent - <-*
Condensate Observed In Front Half:
Filter Container No. t>-0
marked/sealed:
XAD Module Container No.:
marked/sealed:
Probe (FH) & Back Half Rinse (AoaoB^Container
^^^
Liquid level
marked/sealed:
Probe (FH) & Back Half Rinse
Container No.:
Liquid level
marked/sealed:
Impinger Contents Container No.:
Liquid level
marked/sealed:
Impinger Rinse (>
eCI2) Container No.
Liquid level
-------
Plant: £
Sampling Location
Run Number: f,o -*•>?-
Pretest Leak Rale: ,&^
Data:
FIELD DA IA SHEET
Sample Type: ***\s Operator:
CO2: ,o O2: /-z_
(
Nozzle ID:. *>os Thermocouple »:. "?<-
Assumed Bws: .6V Filter #: go-/^^.^-^.'^
Meter Box #: «V Y: ?
Pretest Leak Check: Pftot:
@ ££. 'n- H
Orsat: —
Probe Length/Type: -)' Ci'oJ Pilot #: 1C Post-Test Leak Rate: /dp3 cfm @ y In. Hg
Slack Diameter: -7^
As:
Post-Test Leak Check: Pilot:
\
Traverse
POht
Number
Sampling
Time
(mln)
Qoch Tun*
(24-hour
dock)
Gas Meter
Reading
(Vm)«3
Velocity
Head (Ap)
lnH2O
Oiice Pteasur* DrtferenBal
(AH) In H2O
Desired | Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filer
Impingei
Temp.
Dry Gas Meter Temp.
Inlet
(Tmln0F)
Ouflrt
(Tmout°F)
Vacuum
(in. Hg)
/o
16
2.0
52/^5
-75
.3,5
JSI3
35
. 5
£41.5
*<((..«/
_A6.
SSI. 3
.13
.3-7
76
Y////////////777777WY77^^
S, I J,/ I / /Cr P^ife 235 '-£> Ql &7 I
-------
Page
of
Plant Name:
Run Number:
- Jv\w5-
Test Date: _.
Operator: _
-T74—
Traverse
Point
Number
Sampling /dock Time
Time, / (24-hour
(min.) / clock)
Gas Meter
Reading
Velocity
1 Icad^P.)
ialhO
Orifke Pres. Dirfeieotial
Desired
Actual
Slack
Temp. • F
m
Probe
Temp./ Filler
Temp* F
Impingcr
Temp.
•F
Dry Gas Meter Temp.
Inlet
UUllCl
Pump
Vacuum
iiullg
It-lit
.30
HI
2.32.
wo 1 n 33
'36
ifu
.'A
/ nsjjT
2.2-
1 1
.SYUo
In
I
^/
1 n £3
It
/75g
no i *
/i
f-7&r
if
' IS 13
/
.35-
Y*
/so '
n
z-f
X3
•
24 71
•2/0
3/2-
'
3.2-
"2-20 /
/o?
fe
i
left
$0
-725.1
, to
•3-3
/of
_*3L
$0
0
it-
i+
-------
METHOD 00/0
SAMPLE RECOVERY DATA
Plant:
Sample Date: Q \tf \ 9 ^
Filter No.(s):
Job No.
Sample Location:
Recovery Date:
XAD-2 Trap No.(s):
~ fl\ W B -
Sample Recovery Person: f\ 1C (vD C-
Irnpingers
XAD-2
Trap
(knockout)
(100 ml H2O)
(100mlH2O)
(tipped)^
4
(knockout)
(untippedl
Silica gel
(untipped)
Final wt.
Initial wt.
'6 -i^»^«']
Train System: &PA
/ 6"bK i 0'
^3.
Probe:
Filter: Color-
Loading -
Irnpinger Contents:
Silica Gel: ©Grams Used ^
Color -
% Spent -
Condensate Observed In Front Half:
?-?'".™V??'?5-:
Filter Container No. So- /kttA5'
marked/sealed: <. ?
XAD Module Container No.: $_o '
marked/sealed:
Probe (FH) & Back Half Rinse (AcstonsKontalner No
Liquid level
marked/sealed:
Probe -(FH) & Back Half Rinse
Container No.:
Liquid level
marked/sealed:
Impinger Contents Container No.:
Liquid level
marked/sealed:
Impinger Rinse (,
eCI2) Container No.:
Liquid level
-------
FIELD DA IA SHEET
Plant: 6^
Sampling Location A .it-t-
Run Number: fc^Ajli. Date: <7-z.i-%: 'VO\O Al
Post-Test Leak Rate: cfm
Post-Test Leak Check: Pilot:
@: \. fl &\
_ in. Hg.
Orsat:
Traversa
Point
Number
V
r
. >
i ^
•
Sampling
Time
(mln)
Clock Time
(24-hour
dock)
/
-Z-
'*)
/
2.
2>
Gas Meter
Reading
(Vm)«|3
^(VV^"
, Ob'b
.Ad L,
a
. 00 2>
> Op "^
^0^
Velocity
Head (Ap)
inH2O
Oifica Pressure Differential
(AH) in H2O
Desired | Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Wet
(Tmin°F)
Outlet
(Tm out°F)
Pump
Vacuum
fin. Hg)
y////////////////////////////////////////////////////////////,
P I*. V
^ n i
^"> /C,'k
/v>v)«//i/x
/
<0 n:tfa
/
1-^^Hl
15'>Hu
IA
5
AH-
-------
METHOD TXDIC
Plant: ^M — C^lMd
Sample Date: °[ \22 \ ^-V
>/iHH5- SAMPLE RECOVERY
!*>
Filter No.(s):r$^HA<^l=4.^t
f* S\
Sample Location: ^r>1>v^> ~Tfc*rtid
Probe:
>' k
^s
Filter: Color- ^ Charon
/ BD-X f^.
::^iV:'.Tv..:;.:k.%j\;.;;^v-^^^^r~>V-Tt;CH,tv;V:"'t
^#&j^$i&3i#&8S$l&^$
•:.^^.\••^'_•^•^•''^•r'•n.•^.•.»..:•.•.-^v',..t^^^ ^•..^V'-,i^is^^.P
4
lockout) Silica gel
ntipped) (untipped)
f5-G &(o%.i g
&J5 &U2.2. g
£TVO O . c> g
lif^;ip^;:^^iiP|?^SpS
;.:k^v^ii:ii;."!t,lvUi:;: yisbt' ao A
Loading - tOo 10^
Impinger Contents: CJLSA^I w> C WT^H/^E:
Silica' Gel:
@Grams
Used- 3c>0 Color -
Condensate Observed In Front Half: ^O^E
'vio OtAOsr % Spent - Ud/^c
-•;;•• •«»WWV:^.^>;;Tr^
:-:^:;^i£^<^
Filter Container No.
A'^/^ /
&Hf
XAD Module Container No.: /-V*?>/~ /M^
Probe (FH)
Probe -(FH)
& Back Half Rinse (Aeelane) Container No.: ^/- //A$
& Back Half Rinse (Toluene) Container No.: /v0/-^/e
Impinger Contents Container No.:
Impihqer Rinse (Acatene/MeCI2) Container No.:
marked/sealed: <*/
marked/sealed: LS
Liquid level j
marked/sealed: ^
Liquid level s
$ marked/sealed: */
Liquid level
marked/sealed:
Liquid level
marked/sealed:
£
-------
09/09/97 10:19 Q19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY
Plant: ^?M - ^/^//O/
Sample Date: ^pl / ?9~
Sample Location: \j {jUjftt
Recovery Date: *?/22j r 7"
u>
<~c>i ^2-2*
Ciltmr Mn fo\- CK, .? SJJJP I. &f
rmer INO.IS^. *&v^ t*y~\ ~^i>-
lA CcHtUi^ &RL&T-
DATA
.P6J- ^3
Run No.: f-ft- g^H ^
Job No.: SW. 06 3
XAD-2 Trap No.(s): <^^-=r23^»Vl£ F&i - -^3
Sample Recovery Person: <^V^ L»yEL
>_c< 1._. %•»*- r~', . -^
1
Impingers XAD - 2 (knockout)
Trap
Final wt. — VH >
Initial wt. -— */T*/-7-
Netwt. -— ffX 0
-"NioistureData; *('
2 3
(100mlH2O) (100mlH2O) (k
(untipped) (tipped) _[u
>o3.(p T-/ .^ ^ -
"^•^.iD "?•/?•.& ^
D. *3 (}-O
•^ilSt^^^^^^^iSBiHB^^^^i
Train System: Bv« f*\erlr|&ol
^^> / box I'D*, /y-fr
-. - -* * T ^T-"* • i
V
4
nockout) Silica gel
ntipped) (untipped)
5?V.£> 6Ta.^ 9
WO ^Qv.^ g
D,0 D.o g
- ...., • , ... >.,-r.-. -.-h,-..vv -. ... . s.,. ..^^^^.i^xj;/;.^!! r:;.;v;.»"-t-.
i^i" rvr:^^.':VX1*^r-'^!^^^
/To+aQ- O.Da
Probe: I-1 QloS£>
Filter: Color- Ha Charge Loading- /VJdfjF
Impinger Contents: Ah O£
Silica Gel: @Grams Used - 3^0 Color-^Oijv^/ % Spent- M^Mf
Condensate Observed In Front Half jvdur
^.•'•'••;:&^J-V-.y"&;f&ttr:'.;:--*^^
•'^m;:&^£^mmmMZ^^
Filter Container No. /' h (' ^ /
XAD Module Container No.: p fa /- Z 3
Probe (FH) & Back Half Rinse (Acetone) Container No.: f &(-1-s
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.:
Impinger Rinse (Acetone/Mglle)
Container No.:
marked/sealed:
-------
09/09/97 10:19 ©19199410234
PES RTF NC
@]003
METHOD
Plant: c?M- 3L^VvW
Sample Date: ^AvV
23 CDD/CDF SAMPLE RECOVERY DATA
yftj«~ A f
/ ltC"i f3jf**^
FilterNo.(s):^-23-2.
Run No.: F&~ 23- ^
I i_ ki V'Unt aO^L
uOD NO.: *J 7 ' '" .
' ^ C // X
Sample Location: J)£r^//£/- //Ww' — floor
Recovery Date: ' Q/l-k/'i 7
Sample Recovery Person:
1
Impingers XAD-2 (knock
Trap
Final wt. — i?£<.
Initial wt. ' ~ tf7«
Net wt. -
i^^^^^|g5^^^rp^;^±;::
. •;::?:-y-./-i-V«;iM.-.'.1S5«;.5. ..i.-vi'lfc •^.^••••\.:^- to.;.-* *
Train System: £/% A^
Probe: 7 ^ //L/rW
Filter: Color- MA ^
XAD-2 Trap No.(s): ^ - Z3~ "2-
£&^ v- ^^>x
liliiSiiii^ia^^llill
2 3
out) (100mlH2O) (100mlH2O)
(untipped) (tipped)
$ ~7&&.i/ ~7't3'<(^
f ~7z£.3 ~?2"$,(f,
tj> 21
*6jr^«J- -&U **•&?£,
Loading- A/ 4
4
(knockout) Silica gel
(untipped) (untipped)
<£&?. 7 ^ ^/> ^ g
fp&2-- 0 $&/. y g
g
*:.•;.••-:••. • :"•»• .. T/ ^•!'".1- ••'•w-r.v-: '••••. • •.-^- ^i-*'».-**;-^.'A£ rj»/*1' !';:«''/'•»•'»•
«.:5:;t^:'^f:^-^**w->vi^>\^Ti»vuiK:*K£5«K
l?^4^^^^^i.2^.>r^i ^- ^4(?
Silica Gel: @Grams Used -
2. t>o Color - /^e,y£^X % Spent - ^9
Condensate Observed In Front Half: 4/&\Ajzs
-»:-.•• rV'.'i --»"•'. ••.''•:':iJ—'V^vt'*i-^«^^fc:/i^>WA*« w'¥iC\%^^yf»Jt^^^^
Filter Container No. /^-- 2^3 - z-"
XAD Module Container No.: /£#- 1?-^
Probe (FH) & Back Half Rinse (Acetone) Container No.:/v?-27-
Probe-(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.: i'~/9-2- '" "^
Impinqer Rinse (Acetone/MeCI2) Container No.: /»- 2 ' ' ^
marked/sealed: l^x^
marked/sealed: ^
Liquid level >
^ marked/sealed: **/
Liquid level
marked/sealed:
Liquid level
marked/sealed:
Liquid level
marked/sealed:
-------
FIELD DA IA SHEET
Plant: £/n
Sampling Location
Run Number: fry m
Pretest Leak Rate:
Pretest Leak Check:
C /
*Va>*tS
7
Pilot:
,, o^U-4-
Date: ^-23-^7
cfm @ in. Hg.
Orsat:
Sample Type: ^ . V
Pbar. Z«?.7y Ps:
C02: O2 :
Probe Length/Type: */' >
Stack Diameter: ~7_5
Operator:
:/ Pitot #:
As:
Nozzle ID:
Assumed Bws: _
Meter Box »: /V
Post-Test Leak Rate:
cfm @ in. Hg.
Post-Test Leak Check: PHot: Orsat:
Thermocouple
Filter #:
Y:
Traverse
Point
Number
Sampling
Time
(mln)
£,
/o
IL.3
dock Time
(24-hour
dock)
I2,o2>
Gas Meter
Reading
(Vm)f|3
72MT-
30 ,0
3^ liO
(e/7, 7*0
Vetocity
Head (Ap)
inH2O
Otifica Pressure Drftertntial
(AH) in H2O
Desired
Actual
Stack
Temp.
fTs)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin0F)
OuHat
(Tm out°F)
Pump
Vacuum
(in.Hg).
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-• /
-------
Plant:
Date:
SAMPLE RECOVERY DATA
Run No.:
I Job No.:
Sample Box No.:
Sample Location:.
Sample Type:
Filter No.:
Sample Recovery Person:
Comments:
FRONT HALF
Acetone
Container No. L
Liquid
Level Marked:.
Filter
Container NO.L
Sealed:
Sealed:
Description of Rlter:
Samples Stored and Locked:
BACK HALF/MOISTURE
Container No.:
Sealed:
IMP. NO.
1
2
3
4
5
6
CONTENTS
P;r ^
p£ H^°
Zrfi
5-fce. Li
TOTAL
INITIAL
VOL (ml)
/(JO
/DO
b
ISO
WEIGHT (arams)
INITIAL
57f'6
lif -"A
Lj^.o
~7;$- ^
FINAL
fr%lb
73^
NET
^/
^7
fo7.7
-------
jaca a
K- 9,36
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Date: '7- 25"-^
Sampling Lo<
Run#: £«.i
\
\
i
\
\ ^
"V
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Trov«rM
Point
Number
/
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ressure, in. h
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la: Z-^f / Static Pressure, in. hUO: '^2^r ^
Molecular wt.. Drv: Pitot Tube, Cp: ^^ —
sion, in. Diameter or Side
: DrvE
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-------
APPENDIX B
ANALYTICAL DATA
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Page of
_| 3
Client
Location
j;
Prepared By
Date Checked By Date Sheet Title
FKJAU ^22.7
6*JL
1471 P
r
9-:
.8
to
M
18
\<\
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Page
of
Client
Location
Prepared By
Date Checked By Date Sheet Title
z
(g)
filkr
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Client
Location
Page of
3 3
Prepared By
Date Checked By Date Sheet Title
-------
CLIENT CHAIN OF CUSTODY
From: Pacific Environmental Services
5001 S. Miami Blvd. Suite 300
RTF, NC 27709
Project: Tell City,IN
>'
SAMPLER'S SIGNATURE
Contact: Frank Meadows
Phone: 919-941-0333
Fax: 919-941-0234
P.O.#:
(PES03/AJB)
If the data will be reported to a state agency, which one?.
Sample Name
Date
Time
Comp
Grab
Matrix
Sample Amt.
Analysis Wanted:
P/Q 03927/0700003270
Total Number of
Containers:
Remarks
6/Ar,
T
X
X
.50-23-3
•, ><•/»*/
»
X
Cti-tv&t*'**^
£'/Ar *#*,/
X
Relinquished By/Sign
Date/Time
Relinquished By/Sign.
Date/Time
Received By/Sign.
Relinquished By/Sign.
Date/Time
Recei^e¥By/Sign.
Relinquished By/Sign.
Date/Time
Received By/Sign.
Received for Laboratory By/Signature
Date/Time
Send Samples to: Triangle Laboratories, Inc.
Attn: Sample Custodian
SO11 capitola Drive
Da ham, NC 27713 USA
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
PLANT:
' ' '' 7 .' - S
>' :',H • ' "
PROJECT #:
, ,/
/ • 7 • <-'/,» •»
RECX)VERY
PERSON:
SAMPLE
TECHNIOAN:
SAMPLE IDENTIFICATION
COLLECTION
DATE TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
COMMENTS
(Typa of container,
special preparation.
special handling. «te.)
X
DATE/TIME
DATE/TIME '
REUNQUISHER'S SIGNATURE
RECEIVER'S SIGNATURE
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
PLANT:
PROJECT*:
RECOVERY
PERSON:
SAMPLE
TECHNICIAN: (•?.
SAMPLE IDENTIHCATION
COLLECTION
DATE TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
ANALYTICAL REQUEST
COMMENTS
(Typ« of contains,
•*•*& prepaiatton.
*>«clal handing, ate.)
- 00/0- /
f&-oo/o-l
X
X
So-M*-/
4*
)c
V
- 2-
X
•5
X
.-50- 13- 3
X
f ^dvCR^J
X
y
J?
ifofa
on^r-
REUNQUISHER'S NAME
DATE/TIME
REUNQmSHEfrS SIGNATURE
SHIPPER'S NAME AND ID NUMBER
RECEIVER'S NAME
DATE/TIME
-------
Appendix B.I
Analytical Data
-------
AIR QUALITY PREPARATION WORK ORDER FORM
TRIANGLE LABORATORIES, INC.
-1% "
TLI Project Number:
03927
Due Date:
Client/Company Nam
Project Manager:
Client MILES Code:
Quote.Number:
^
' ]£ Filters
31/z79.0 cm
4710.16cm
41/271 1 .0 cm
5712.5cm
Other
Filter Material:
Shio filter in:
A - A • ORDER INFORMATION
e: Kd£A-p£> SHv.Vex. fW^T/ifi Order Date: 9/
vlmft '
p£5<7f3
cmwt£>
Client Project #:
Client P.O. #:
RjSL
MATERIALS NEEDED
It- XAD traps PUFs
y^Ball and Socket
Socket and Socket
Screw cap
Other ftu/CW/tf
Sandwich PDF: yes
Ship PUFs in : jars
' t-A'T
no
sleeves
Quartz glass fiber other
one petri dish separate
petri dishes
Preparer:
# of Laboratory Blanks:
XAD Resin Batch #:
Pre-spike required:
Intended Analysis:
(Circle ail applicable) Other:
Spiker/Observer Initials:
Spiking Date:
Spiking Solution ID:
Volumn Spiked (uL):
Nominal Concentration:
Expiration Date:
PCDD/PCDF Surrogates
37CI<-2,3,7,8-TCDD _4
"C,2-2,3,4,7,8-PeCDF
13C,2-1,2.3,4,7,8-HxCDF
'3C,2-1,2,3,4,7,8-HxCDD
'3C,2-1,2,3,4,7,8,9-HpCDF
Ship to the Attention of
Mailing Address
Street Address
Phone Number
Special Instructions:
PVE PREPARATION INFORMATION
Date:
Supplier:
cO
HR-PCB
Dioxi
Organics
/
I
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ID:
P.O. Number:
TLI Project Number:
October 21,1997
Pacific Environmental Services
43432
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 05/08/97
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
-------
Triangle Laboratories, Inc. October 21,1997
Case Narrative 43432
Overview
Seven M23 samples were received from Pacific Environmental Services at 3 °C in good
condition on September 29, 1997 and were stored in a refrigerator at 4°C. The samples
and any associated QC samples were extracted and analyzed according to procedures
described in the Triangle Laboratories' Data User's Manual (Rev. 12/92-HK-2-AH-2/93).
Any particular difficulties encountered during the sample handling by Triangle
Laboratories will be discussed in the QC Remarks section below. Results reported relate
only to the items tested.
Quality Control Samples
A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples.
Quality Control Remarks
This release of this particular set of Pacific Environmental Services analytical data by
Triangle Laboratories was authorized by the Quality Control Chemist who has reviewed
each sample data package individually following a series of inspections/reviews. When
applicable, general deviations from acceptable QC requirements are identified below and
comments are made on the effect of these deviations upon the validity and reliability of the
results. Please consult Triangle Laboratories' Data User's Manual for further details.
Specific QC issues associated with this particular project are:
Sample Preparation Laboratory: None
Mass Spectrometry: None
Data Review: None
Other Comments: Any analytes found hi the TLI Blank are detected at a level equal to or
less than the Target Detection Limit. This level of contamination is acceptable as per TLI
guidelines.
Sample Calculations:
Analyte Concentration
The amount of any analyte is calculated using the following expression.
Amt(0)=
-------
Triangle Laboratories, Inc. October 21,1997
Case Narrative 43432
Where:
Amt (0) is the amount of a given analyte,
AO is the integrated current for the characteristic ions of the analyte,
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume (W = 1 for M23)
The amount is expressed hi nanograms (ng) or picograms (pg).
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
2 * 2.5 * (F * H) * Qp
DL(0)=
Ap*RRF(0) *W
Where:
DL(0) is the estimated detection limit for a target analyte,
2.5 is the minimum response required for a GC signal,
F is an empirical number that approximates the area to height ratio for a GC signal. This
number is 3.7 for both the DB-5 GC column and the DB-225 GC column,
-------
Triangle Laboratories, Inc. October 21,1997
Case Narrative 43432
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume
The detection limit is expressed in nanograms (ng) or picograms (pg).
Other sample calculations may be found in the Triangle Laboratories Data User's Manual.
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports,
as discussed in Triangle Laboratories' Method 23 Data User's Manual. Please note mat all
data qualifier flags are subjective and are applied as consistently as possible. Each flag has
been reviewed by two independent Chemists and the impact of the data qualifier flag on
the quality of the data discussed above. The most commonly used flags are:
A 'B* flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag will be used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories guidelines, a laboratory blank is acceptable if the tetra-
through hepta-CDD/CDF levels are all below the target detection limits (TDLS) or if the
contamination levels are less than 5% of the levels detected in the associated field samples.
If these conditions are satisfied or if the blank is unable to be reextracted, the
interpretation of the contamination levels relative to the samples should be as follows: 1)
analyte quantitations should be considered valid if the level of blank contamination is less
than five percent of the level detected in the field sample, 2) analyte quantitations should
be considered estimated if the analyte level in the sample is five to twenty times the level
of the analyte in the blank, or 3) analytes whose level in a sample is the same as or less
than five times the level detected in the associated blank should be considered present
likely due to laboratory contamination and not native to the sample.
An 'E' flag is used to indicate that an PCDF peak has eluted at the same time as the
associated diphenyl ether (DPE) and that the DPE peak intensity is ten percent or more of
the PCDF peak intensity. Total PCDF values are flagged 'E' if the total DPE contribution
to the total PCDF value is greater than ten percent. All PCDF peaks that are significantly
-------
Triangle Laboratories, Inc. October 21,1997
Case Narrative 43432
the isotopic abundance ratio. These EMPC values are most likely overestimated due to
the DPE contribution to the peak area.
An 'I' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences. Affected analytes may be overestimated or underestimated as a result of this
interference. A peak is flagged 'Q' only if it is affected by a QC ion deviation greater than
20% full scale as determined relative to the labeled standard against which it is
quantitated. Total PCDF/PCDF quantitations will be flagged 'Q' if the interferences affect
ten percent or more of the total PCDD/PCDF peak areas.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
A 'U* flag is used to indicate that a specific (2,3,7,8-substituted) isomer cannot be
resolved from a large, coeluting interferent GC peak. The specific isomer is reported as
not detected as a valid concentration/amount cannot be determined. The calculated
detection limit, therefore, should be considered an underestimated value.
A' V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
-------
Triangle Laboratories, Inc. October 21,1997
Case Narrative 43432
By our interpretation, the analytical data in this project are valid based on the guidelines
of EPA Method 23 (6/93) and Triangle Laboratories' Method 23 Data User's Manual.
Any specific QC concerns or problems have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Pacific
Environmental Services have any questions or comments regarding this data package,
please feel free to contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Report Preparation Quality Control
Vijay S. Chhabra
Report Preparation Chemist Report Preparation Chemist
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Certification pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX,
Volatiles, Pesticides, RGB's, BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management Expires December 31, 1997.
Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30, 1997.
Registration # PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 9/18/97 RM
-------
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires December
31, 1997. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1997.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires March 31, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31,1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.
State of New Mexico, Environment Department Certification pending. Dioxin in drinking
water.
New York State Department of Health. Expires June 30, 1997. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 9/18/97 RM
Printed 9/18/97
-------
Oklahoma Department of Environmental Quality. Expires October 31, 1997. Laboratory
#9612. Dioxin by 1613A. 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires June
30, 1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31,1997. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for Polychlorinated Dibenzo-
p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 9/18/97 RM
-------
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998.
Laboratory ID Number 999869530. Certification for the following categories of Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31,1997. Registration number NC-
PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 9/18/97 RM
Printed 9/18/97
-------
DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
: &M-
PROJECT *:
RECOVERY
PERSON:
SAMPLE
TECHNICIAN: (y.
_^_
, (.
SAMPLE IDENTIFICATION
COLLECTION
DATE TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
COMMENTS
(TypcofcontokMr.
pedal preparation.
•pedal handling. etc.)
- 00/0- /
X
K
ff?
5*0 - 33- 1
>c
So/VIS-
V
X
So-MM-'b
X
30- 13- 3
)C
f <^t3-u^lcc.
f.Y/^X/W,
'
K
T
V
ro
DATE/TIME
REUNQUISHER'S SIGNATURE
RECEIVER'S SIGNATURE
-------
7
CUENT CHAIN OF CUSTODY
SAMPLER'S SIGNATURE
P/Q 03927/0700003270
From: Pacific Environmental Services
5001 S. Miami Blvd. Suite 300
RTP, NC 27709
Project: Tull Ctty,1N
Contact: Frank Meadows
Phone: 919-941-0333
Fax: 919-941-0234
P.OJ:
(PES03 /AJB)
If the data will be reported to a state agency, which one?.
Sample Name
Date
Time
Comp
Grab
Matrix
Sample Amt.
Analysis Wanted:
Total Number of
Containers:
Remarks
X
X
So -
i
X
so- flf- y.
fl-23-*"
2
X
Relinquished. By/Sign.
Date/Time
Date/Time
Relinquished By/Sign.
Date/Time
Recei^eia By/Sign.
Reiinquilngcf By/Sign.
Date/Time
Received By/Sign.
ujleceived for Laboratory By/Signature
GO "' "
Date/Time
Send Samples to: Triangle Laboratories, Inc.
Attn: Sample Custodian
801 Capitola Drive
Durham, NC 27713 USA
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
PROJECT ,:
RECOVERY
PERSON:
SAMPLE
TECHNICIAN:
SAMPLE IDENTIFICATION
COLLECTION
DATE TIME
SAMPLE NAME
NUMBEROF
CONTAINERS
/
ANALYTICAL REQUEST
°°MMENTS
(TVP-oleontaJn.,.
SSS3S&
X
-------
19/09/97 10:19
U19199410234
PES RTF NC
31003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant: G^/v} - ^>
Sample Date: Wl M
Sample Location: C
Recovery Date: 7/Zl.i
^M)AUJ
\1- Cill»r MX i'.i\. Ctl "> 3 i_ 4. " ^
7 riller iNU.(a^. Ow* 6-5^ | ~»t x
CUf«U CchlX,^^- 2>U/TL&T-
)'} XAD-2 Trap No.(s): *^cV
.H-6J^ ^3
Run No.: Ste=^3=4~^
JobNa-r'S^W. 063
=-2^-^^ Fft»- 3-3
Sample Recovery Person: \V\ 1 r)EL
Impingers XAD-2 (kr
Trap
Final wt. — V
Initial wt. — *f i
Net wt —
S^S^SflifEiiSS
Train System: ESRt P\e
12 3
lockout) (100mlH2O) (100mlH2O)
(untipped) (tipped)
7^-? ^clG? ^t-Tk^
i^.'y. "^OS.ID *?/?•. s
. D /":. 0 (}-O
£?5i^^^S'DisiSC]H§8^
i^rticcl &?> / box I'D'. V-
4
(knockout) Silica gel
(untipped) (untipped)
5W-& 6?^,^ g
5^.0 ^^i..1^ g
1}.C* P» . c> g
•'•-T:;' •"-. ;-;:;T:j7r«-i • •• -\«{-*x:i"^'.i-.'v:a«::
K-^-Jti-A"- ; '-•'•'-' '~ •••'•' T " '-' ••Ki'Kf'Sir-.i-SV" »•— '-«.i
V .'.•'••.•iivr-n- •.V-^1iii^X._Tr.»i-cJ.':;:-~i: •';•..*"'-«' ^.I.VjJw: • •'-
^ / } C-A'7 C • I ' /-/ *7
Probe: ~V Qla^>
Filter Color- ^ Chfli
\\ e Loading - /\j ?? ivjF
Impinger Contents: Ah Gt*A*JC»f
Silica' Gel: ©Grams Used - 3fca Color - }\> (LHw > % Spent - \i^t^C
Condensate Observed In Front Half: jWiir
±r^liii?iS?;^Bi
i','.' v;" > RB c ova ra di'S ampl e^Wracti o nss~-
Filter Container No. /'* A /' 2- £
XAD Module Container No.; /' /? / - Z 3
Probe (FH) & Back Half
Probe -(FH)& Back Half
Rinse (Acetone) Container No.: f Af
Rinse (Toluene) Container No.:
Impinger Contents Container No.:
.^*
Impinger Rinse (Acetone/M5©£) Container No.:
^^SfiKISSS^^S
marked/sealed: <*/
marked/sealed: ~s
Liquid level
-2-3 marked/sealed: ^^
Liquid level
marked/sealed: \^
Liquid level
marked/sealed: %
Liquid level ,
marked/sealed: ^
15
-------
19/09.-97 10:19 ^19199410234
PES RTF NC
2)003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant: (— ,ji{ - SvAGiftMu)
Sample Date: ^|Z3l^>
Sample Location: p (C-uoolc
Recovery Date: ^1 |2*f p T
Sample Recovery Person: w~
^.>^-3:'^:i^^^^M^l^^r%M
1
Impingers XAD - 2 (knockout)
Trap
Final wt. (0A(*-3
Initial wt. — H3-H.4-
Netwt. ~~~ /5V. to
Filter No. (s): £.£.u Aft£{. ( 'aTttT
XAD-2 Trap No.(s): S: 0
Run No.: 56 2,-s-
JobNo.:^^.^
33-
i6E-
^SliWiSisitureL: iSalferl'H;^::
2 3
(100mlH2O) (100mlH2O)
(untipped) (tipped)
"TOx:7.^ ^/-?- 3
"7-^3.^? ^i?-.H
-/.3 -0.5*0
r;:fp|gi|:^|§|^g^y
4
(knockout) Silica gel
(untipped) (untipped)
^iW ^B^---Z g
6"^ y O J2H^**Oi ? g
' * * j £•'*(' g
Train System: §r(pP\ MfMrtte
\ zs /ix^x "^H
/ 7o-rAu : /6A?
Probe: 1 ' r» fc<5 / L/*v
Filter Color- <^r«?£ -2
Probe -(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.
Impinqer Rinse (Acetone/Ma&t2)
s.-zJV
Container No.:
SlBISIIgSlSi^
marked/sealed:
marked/sealed: -~s
Liquid level
^ -/ marked/sealed: >-/
Liquid level
marked/sealed: ^
-------
09/09/97 10:19 S19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant:
- fl C
Run No.:
-3 -
Sample Date:
Filter No.(s): "G6- 2.3-
Job No.:
Sample Location: ft ^Mptirt
r w
Recovery Date: ^ \l*{ \ ^
XAD-2 Trap No.(s): SC - £*>-
Sample Recovery Person:
1
•„.».•—•:_•.-,•- ^vrsv-^r^i^r^r-.;:;-.,--. ; '•^^•^•^f^^-^'-rf -*. irrW-^viV-- "
5fi •• -; *'-i*« «»-,•-•"• •• • • ••— ..- x^i-"- —"^ •' • • v^i -.%. .*• •••w .*.. "r*'4« •.v^*»«[^'•* » •,- X-
ia^^-y^^?^ ~ e--^sasafc^ggs^^g?^^
Impingers
XAD-2
Trap
1
(knockout)
(100mlH2O)
(untipped)
(100mlH2O)
(tipped)
4
(knockout)
(untipped)
Silica gel
(untipped)
Final wL
Initial wt.
Netwt.
0.2-
(•••• *'?•••.* •^.'.T»"w™t'~,'?r"'''r "."" **"*" '.tv .<"•?: &1-!—'-•".""• • r>" >••"•• •*?(taCX''r- -i
i^^
Train System:
Pfl~
I3) /
ID-
Probe:
Filter Color-
Loading -
iu
Impinqer Contents: C>i
Silica'Gel: @GramsUsed- .3ro Color- U fttu-e % Spent- U b
Condensate Observed In Front Half: MO iJ£
Filter Container No. SO - t^ - ^-^ marked/sealed: ^^
XAD Module Container No.: S V
marked/sealed:
Probe (FH) & Back Half Rinse (Acetone) Container No.:5o - 23
Liquid level
marked/sealed:
Probe-(FH) & Back Half Rinse (Toluene) Container No.
Liquid level
marked/sealed:
Impinqer Contents Container No.:
Liquid level
marked/sealed:
Impinqer Rinse (Acetone/MeCg) Container No.:
Liquid level
marked/sealed:
-------
19--09/97 10:19 O19199410234
PES RTF NC
METHOD 23 COD/CDF SAMPLE RECOVERY DATA
Plant:
Run No.:SO -
Sample Date: °1t6
Filter No.(s): •$?) - Z i -3
JobNo.rSHH.bbS
Sample Location
: *o
Recovery Date: ' ^ fc? / 9 >
XAD-2 Trap No.(s):
~ * 3 -3
Sample Recovery Person: MT- \ \jE-
Impingers
XAD-2
Trap
1
(knockout)
(100 ml HZO)
(untipped)
(100mlH20)
(tipped)
4
(knockout)
(untipped)
Silica gei
(untipped)
Final wt.
2.5
Initial wt.
. 3
Netwt —
-/a.5"
Train System: E?A
/
1>>;
Probe:
Filter Color-
Loading - r\
Impinger Contents: C
Silica Gel: @GramsUsed- 3o6 Color- ||. l?/^ % Spent- (id
Condensate Observed In Front Haft
Filter Container No.
marked/sealed:
XAD Modv!«9 Container No.:
marked/sealed:
Probe (FH) & Back Half Rinse (Acetone) Container No.:
Liquid level
marked/sealed:
Probe (FH) & Back Half Rinse (Toluene) Container No.
Liquid level
marked/sealed:
Impinger Contents Container No.: 5o -2-3-3
Liquid level
marked/sealed:
Impinger Rinse (Aceton
Container No.:
Liquid level
marked/sealed:
-------
09/09/97 10:19
S19199410234
PES RTF NC
©003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant: C,M - <
Sample Date: n/^5"
Sample Location:
5A6l*>AW
' Cl > Rlter No.(s): Sb-23-J
& C u*ob £
J^tiS!S^KS
Impingers XAD - 2
Trap
Final wt —
Initial wt. —
Netwt —
llpl^^ggppi^iall^lliai
12 3
(knockout) (100m»H2O) (100mlH2O]
(untipped) (tipped)
£,">\/5~" ^9D.^ ^?4, /
Ml^.T- ~j~ol.,1 "/'OU'-f'
-/Oi>.fi *W-3 -?-U?
":{^®|||^|§p:|^g§|
4
(knockout) Silica gel
(untipped) (untipped)
fclO.-l ^19.5 g
OcH-k .^r^r^.4/ g
^"•9 5t>'/ g
Train System: c*r/-
* ^A^^^K^ ,23 / 60^ M-5 /
-r^r^u- ^3(^.8
Probe: ~V £,Lfr56
Filter Color- ~~r~
A^ Loading- lA^D'W.
V\^
Impinger Contents: C^\^> Color- 'H- VD\VX£ % Spent- Uo
Condensate Observed In Front Half. M? N £•
^tf-rijs— ''•'•'"i*-:-';s™-***t*-"'' '•-'-^•»~^1>^vc^i^>^ssjvv»\i«^7^V*>«»^«i1SiiV-!<»i^.^(«'^^
-^i^iE^^;^^
Filter Container No. 5c - ^ > ' V^
XAD Module Container No.: £i> - 2 3 - V
Probe (FH) & Back Half Rinse (Acetone) Container No.: ^o-2-
Probe-(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.: fa " 23 - tf
Impinqer Rinse (Acetone/MeCI2) Container No.:
marked/sealed: «— '
marked/sealed:
Liquid level ^
5-/ marked/sealed:
Liquid level
marked/sealed:
Liquid level ^
marked/sealed:
Liquid level
marked/sealed:
19
-------
09/09/97 10:19 O19199410234
PES RTF NC
121003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
-•> + i
Plant: c?M- _>L>fVw Aw^
Sample Date: ^ M/V Filter No.(s): /=#- 23 -2.
/ '
Sample Location: _!>£>«.//£/- flvJ&J' — >locr
Recovery Date: ' 3/'1>k/4> 7 XAD-2 Trap No.(s): /"£ -
Run No.: ffr. 21- T-
JobNo.: Silt-***
-23- "2-
i *
Sample Recovery Person: £•&<£« v- <2£ /T^us
^^^rap^^^^^Maa^ffi^a^
1 2 3
Impingers XAD-2 (knockout) (100mlH2O) (100mlH2O
Trap (untipped) (tipped)
Final wt — i?£»$ ~76&.y_ -72.5/U.
Initial wt. ' — ^7^(f 17^.3 "7.2 3. £
Netwt -
^^—f-y-n:-^-; ..^Ui»it=.ViS}^jrf=^V»J«Pf.:»at'^'
\?;K f= •"-^•^:fe^vv^:5!S-5^J^¥SSS
4
i (knockout) Silica gel
(untipped) (untipped)
kv2. 7 <$£/, ^
^2.9 66/. y
9
q
9
SSIlSli^SfiiiSi^l^S^Si^Sffl
Train System: £PA fikd-d} 2- 3
Probe: 7^/4^U *6x J*J- ^6^, MT.^
Filter Color- N^ ^ Loading- A/ 4
Impinger Contents: "7^, -^ //i^?
Silica' Gel: @GramsUsed- 2.5i7 Color - &Le,/{jluA* % Spent - ^
Condensate Observed In Front Half: /^£no£/
^^s^%^^^?S^ipBZaMgSg^^^S3g^^
-•== i^'MtL^ifS^'^fSwSvi'^a'if.aSt^is-A •^llSPCOyaflBaSJMOTpleL^liaCupn.S?-?:^ '; ^v!S;: Siy -fesS^a1^ •r-rv^n'fe-'^'i^S
Filter Container No. /^- 13> ~~L-
XAD Module Container No.: /^^ ^.^ - "2^"
Probe (FH) & Back Half Rinse (Acetone) Container No.: /v?-??
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.: f/^-^- )1" ^
Impinqer Rinse (Acetone/MeCI2) Container No.: /^- ^ ? '
marked/sealed: L-x^
marked/sealed: ^
Liquid level y
•** marked/sealed: t^^
Liquid level
marked/sealed:
Liquid level
marked/sealed:
Liquid level
marked/sealed:
2(
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
SW.OO?
Page
Client
Location
ff
of
io»S
Prepared By Date Checked By Date Sheet Title
[70. Q
-23 -/
$0-
ft
/=:• V
3^2. a
t
st. C/?<*/o»«c
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Client
Location
Page
of
Prepared By Date Checked By Date Sheet Title
-216,
- 3
t>+UdkW.
z
.28-
&'
50-23-3
filkr
u»c,
22
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
Page of
3 3
Client
Location
Prepared By Date Checked By Date Sheet Title
f;fkr
23
-------
b
II
II
U
11
y
B
Custody Seal :
Chain of Custody :
Sample Tags :
Sample Tag Numbers:
SMO Forms :
Ice Chest
Absent
Present
Absent
Not Listed
N/A
Sample Seals:
Container. . . :
on Chain of Custody
ICE Temp
WliljtS IjABUKATUKlBS, IMC. -- LOU iH Kl
Absent
Intact
3.0 C
| TLI Project Number 43432 '
j Client: PES03 - Pacific Environmental Services
1
j *.
\
\ Date Received
j
| Carrier and Number
| 09/29/97
1 *** MZ^fodft k
| Book I)
1 II
1 "5 U
ft f ||
M&\
1 '.I " ' ' "
| TOM MCDONALD •) | 6 ||
JTLI Number Client Sample ID. Matrix)
jjmR/H:CPM ....Client COC ID * Location j
»i
U185-6-1A SO-
II so-
il
||l8S-6-lB SO-
li SO-J
||l85-6-lC SO-
II so-
il
||l85-6-lD SO-
ii so-
il
||l8S-6-lE SO-
II SO-
|
IJ18S-6-2A SO-
II SO-
II
II
||l8S-6-2B SO-
II SO-
||l8S-6-2C SO-
II SO-
|
II
||!85-6-2D SO-
lj j SO-
l|!85-6-2E SO-
II so-
||l8S-£-3A SO-
II so-
||l85-6-3B SO-
II SO-
||lB5-6-3C SO-
II SO-
||1BS-S-3D SO-
II SO-
To LAB
Date/Init
A ^
23-1 FILTER)
-------
-TRIANGLE LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY"
|| Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container. . . : Intact
U Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
|| ice Chest
ICE Temp 3.0 C
||TLI Number Client Sample ID Matrix)
jjmR/H-CPM Client ™c* ID.. ._• location
||l85-6-4A SO-I
U so-
il
II
||l85-6-4B SO-I
II SO-I
JJ185-6-4C SO-I
|| SO-I
||!85-6-4D SO-
II so-
23-4 y FILTER
23-4 rjJj^H*- C01
23-4 XAD
23-4 C01
23-4 ACE/TOLUENE
23-4 C01
23-4 CONDENSATE
23-4 C01
JJ18S-6-5A FB1-M23 FILTER
jl FB1-M23 C01
II
||l85-6-5B FB1-M23 XAD
I) FB1-M23 C01
||!85-6-5C FB1-M23 CONDENSATE
|| FB1-M23 C01
|i 185-6- 6A FB2-M23 FILTER
jj FB2-M23 C01
I
II
||l85-6-6B * FB2-M23 XAD
jl "i F82-M23 C01
II '
II
||!85-6-6C FB2-M23 ACE/TOLUENE
|| FB2-M23 C01
||l85-6-7A LAB BLANK M23 FILTER
U LAB BLANK M23 C01
||l85-6-7B LAB BLANK M23 XAD
II LAB BLANK M23 C01
||l85-6-7C | LAB BLANK M23 ACETONE
|| LAB BLANK M23 C01
To LAB
Date/lnit
xfv
lOA-W
-
II .
||l85-6-7D LAB BLANK M23 H20| \
|j LAB BLANK M23 C01 j
U Receiving Remarks:
1
II
|| Archive Remarks:
— |
«
TLI Project Number 43432 , | Book ||
Client: PES03 - Pacific Environmental Services j ||
1 IBS ||
Date Received j 09/29/97 | Bv^fk2g£> tJ^T*/*^^^-^336 II
i • '.; • i u
Carrier and Number | TOM MCDONALD , | 6 ||
To STORAGE |
Date/lnit
i jyC
\-*fl
J
/
} .
/""
r
/
1
<
V
J
\
>_
>-^fO
,
J_
To LAB
Date/lnit
To STORAGE
Date/lnit
To LAB
Date/lnit
To STORAGE
Date/lnit
i i
To LAB
Date/lnit
t
t
To STORAGE
Date/lnit
'
DISPOSED ||
Date/IniL ||
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
U
II
II
II
II
a
u
D
II
1
II
II
»Forro Revised 05/27/1997 -- Page 2 OF 3=
ro
-------
!vi == = = == = *TRI»- LABO. .IBS, _. -- L. -1 REC-.
0 Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container...: Intact
|| Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
TLI Project Number 43432 Book ||
Client: PES03 - Pacific Envi/ronmental Services ||
Date Received j 09/29/97 j By^p%^^/^7y?x^2 ^^9£ 1
U I I* • v ii
|| Ice Chest ICE Temp 3.0 C Carrier and Number | TOM MCDONALD '•, 6 ||
l|TLI Number Client Sample ID Matrix)
jjmR/H-CPM Client COC ID . ..* Location
n
U
Q18S-6-7E . LAB BLANK M23 TOLUENE
y LAB BLANK M23 C01
n
n
II
II i
II
D
II
II
j
u
II
II
n
u
II
n
n
n
n
n
n '
ii -
«i
u
ii
ii
n
u
n
.
n
u
To LAB
Date/Init
^
'
To STORAGE
Date/Init
)o>*o
jj^r
To LAB
Date/Init
To STORAGE
Date/Init
To LAB
Date/Init
-
To STORAGE |
Date/Init
•
To LAB
Date/Init
1
1
1
TO STORAGE
Date/Init
.
DISPOSED ||
Date/Init ||
n
II
n
II
II
.11
II
II
II
II
II
n
II
y
n
u
n
«"
u
• u
ii
u
n
D Receiving Remarks:
y
n
|| Archive Remarks:
=Forra Revised 05/27/1997 -- Page 3 OF 3=
ro
-------
TRIANGLS LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
-ADMINISTRATIVE INFORMATION ±J^>~r- ' - - A
TLI Proj#: 43432- Samples: 7 TurnAround. : -¥5" Day(s) |£L»^"
Prod Code: D23061 Matrix.: M23Train Hold Time..: 30 Day(s) / ..,,
DetectLim: 0.05 ng Type...: A Start Date.: lO/er^T?"1^ / "i^n?;
Recvd. . : 09/29/97 Ship By : 1Q/^2/^^^^\ 'Ofl
DWL Due Dt. : Ig^O-W*? ^4oL
I1
Analyte List.: tetra-octa PCDDs/PCDFs
Method : Method 23:Tetra-Octa (Tol Combined)
Client Proj..:
Client : Pacific Environmental Services (PES03)
P.O. No : Collect Dt/Tm: 09/22/97
Contact : Frank Meadows Phone : 919-941-0333
Proj . Mgr. . . < : Amy J. Boehm Fax : 919-941-0234
Sample Origin: NC
SPECIAL INSTRUCTIONS / QA REQUIREMENTS
Assoc Proj 1: 43433 Prespike Standard: USF-CS
Assoc Proj 2: 43452 Prespike Amount..: 4.0ng
Prep Project: 03927
---- ..... ----------------- REPORTING REQUIREMENTS
Reporting Format: Report Option II
See MILES for Instructions/Communications .
Completed by: Wl-.ljJ _ DATE: /C -'Z~97
Reviewed by: _ /)& _ DATE: fJ^JW ' (PMGT0197)
^-,
-------
TRIANGLE LABORATORIES OF RTP, INC.
PROJECT COMMUNlCATfON TRACKING FORM
page of
TL1 Project Number:
Use this form to record-all exchanges of information beNveen production units as well as personnel
handling -this project. Decisions, corrective actions and recommendations must also appear on this
tracking document. ..^
Comment / Decision / Resolution / Action / Observation
Triangle Laboratories, Inc
Til PROJECTS 03927
DATE 9/18/97 TLI BLANK
SPIKE 4.0ng USF-C & USF-S
SPIKE 100ug TERPHENYL-DU
SPIKER W^ PREP.
-------
Date: 10/10/97
Time: 07:26
TRIANGLE LABORATORIES, INC.
Met Lab MM5/PUF Observations
Project: 43432
PRDPERC V4.00
Page: 1
Sample
ft crd TLI_Number. .
000 TLI Blank
001
002
003
004
005
006
007
OOB
009
185-6-1A-D
1B5-6-2A-C
185-6-3A-C
1B5-6-4A-C
1BS-6-5A-B
185-6-6A-C
185-6-7A-C.E
TLI LCS
TLI LCSD
Cus
TLI
SO-
SO-
SO-
SO-
Blank \
-------
1
i 'reject: 43432
1 Solvent (s)/Acid(s) : iDCe^Sc
1 x>t Numbers: ^TZ.\\^[
| IS Spike: 40 M! cone: 0.1C
1 SS Spike: ui cone:
TRIANGLE LABORATORIES , INC. PAGE 1 OF 1
Dioxin Sample Preparation Tracking & Management Form '
Client: Pacific Environmental Services (PES03)
/ / Method: Method 23:Tetra-Octa
/ / Extraction Date: \fc / *t fi^r
ng/Ml 1 £-Kr" 1 L^fy~ 1
MS Spike: 0 M! cone: 0.0000 ng/fil 1 SH^l"? 1 ^233^31 |
1 ^CS Spike: 0 Ml cone: O.OOOOng/Ml 1 OVf-1 | 0<>\' •flfl*' \
| OPR Spike: 20 M! cone: _0.01 ng/jil | &-V /C^ Fi£ 1 IS / !i /S9" 1
. + + ... . I'D / c« /q'a. i to iCt Aa i
| I TLI / | GROSS | SAMPLE | (Q_ : _QQ | [Q : QO \
|S#.crd| SAMPLE / CLIENT | WEIGHT | SIZE | DJ nq/ul | &.0>ng/gl |
I | ID / SAMPLE ID | Before After | g / ml | t-\'D M! 1 H*Q (il 1
1 1 TLI Blank till -^-Q 1 1
|000 | TLI Blank | | 1^1 -1-^.D 1 1
1 | 185-6-1A-D
|001 | SO -I
| | 18S-6-2A-C
|002 | SO-t
\ 18S-6-3A-C
|u03 | SO-t'
\ 18S-6-4A-C
, 14 | SO-t
\«\T T
Ji^V 111 I 1
Ify \Q\ » 1 1 i 1 '^sv O 1 1
1 1 1 i 1 1 1
23-2 | | II 1)6 1 1
1 ' ' i ' 9x0 ' '
23-3 | | 1 ' 1 \)|3 1 I
1 ' ' i ' na ' '
23-4 | | 1 l I UO 1 1
\ 185-6-5A-B | | | j | --x-^ I I
IS | FB1-M23 | | 1 I I DO 1 1
(Tol Combined)
^_j_, .
<2k ;
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OSF-V** i
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^0 «i I
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|
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(>b !
ws !
| | 185-6-6A-C | | III 1 1 , \
16 | FB2-M23 | | 1 1 1 J3V^ ' 1 **1 J 1
| | 185-6-7A-C.E
17 | LAB BLANK
| | TLI LCS
1-08 | TLI
1 1 II -xn 1 1
M23 | | ill Dtj 1 1
LCS | | | 1 | ^^ | T>0 |
MS !
Ms !
| | TLI LCSD | | 1 » 1 -\ <--N ' «O ' to £ '
|009 | TLI LCSD | | ill U|j ' V^ b ' ' 1
Matrix :W£5
IChe
ISpi
1 '•
_/_/_! •
_/_/_! "
= 1 "
nq/ill 1 •
|Any
l
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 43432
Ext S#.crd and |
TLI Number |
\ 7 1 . 1 . 1 - 1 . 1 __ 1 n 1 f. 1 1
t Z- i 4/\ i b i ~> i U5 i 9" ' x i " i i
i$ jS&Pt''
TLI Blank | , 'f A*<«J \
001 |
185-6-1A-D |
002 |
185-6-2A-C |
003 |
185-6-3A-C |
004 |
185-6-4A-C |
005 |
185-6-5A-B |
006 |
185-6-6A-C |
007 |
185-6-7A-C.E |
008 |
TLI LCS |
009 |
TLI LCSD |
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
f i x
3
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....: .j LI....L.L.I...
i
i
i
i
i
i
1?
i i^ i
$d
I
\
ij
Enter the procedure number below into- the
Initial and date each sample for each num
# PROCEDURE DETAILS
7t) EXTRACTION ON^_ OF
C2» SPIKE AFTER EXTRACTION t^,*O
9 ADD TRIDECANE *°
ROTOVAP 40mL /
^f COMBINE
® DIVIDE / LIPID DETERMINATION 20*/80%
(j) SOLVENT EXCHANGE ^ ^
Q» CLEANUP /'DSP 26£,
(5} TRANSFER
10) ADDITIONAL CLEANUP Mod. DS
11) FINAL TRANSFER
li
1
1
1
1 \
^SSSE&BBSS?
box^at t
bered pro
(circle)
? SJSScKli
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P 260 /
1 I 1
1 i '
1 1 I
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1 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1
vV V1
\ 1 • 1
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1
1
/ 1
1
1
1
1
1
1
1
1
1
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1
1
1
1
' i
1
1
1
1
1
1
1
^
a^^ "V'
Vl Al
41..J-1L-
ie top of each column to si
cedure performed.
st / Jar / Sep Funnel / Ste
.x^-vB
BrynesJT
0% 5mL/20mL Other
225 / DSP 115
DSP 225 / DSP
^=,+==-.
jnify the
am Dist /
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
II 1
111 1
111 1
II 1
--— '-" \£J"+ +
, 'tf/to/tf ' '
step perfornnsd.
Cont LL / ASE / Waste Dilution
/ DSP 215 / DSP 267 / Other
US / DSP 215 /
DSP 267 / Other
Comments: tOl lt£/W. 3 3 <./ jfZ>/ / f
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 43432
Transfer From: DWLH5 To: DMS5
Initials.. Date
Released by: \J' Lfc J&_l LJ£L.131
. Sn -^
Accepted by:
Time. . .
/'/ **£
MILES.ID.
43432-
43432-
43432-
43432-
43432-
43432-
43432-
43432-
43432-
43432-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
TLI No Gust. Id.
TLI Blank
185-6-1A-D
185-6-2A-C
185-6-3A-C
185-6-4A-C
185-6-5A-B
185-6-6A-C
185-6-7A-C,
TLI LCS
TLI LCSD
TLI Blank
SO-I|I23-1
SO-1I23-2
SO-H23-3
SO-IJI23-4
FB1-M23
FB2-M23
LAB BLANK M23
TLI LCS
TLI LCSD
Additional comments or instructions:
-XfrCOC (Rev 11/01/94)--+
-------
PAGE I OF 1
I
| Method: Method 23:Tetra-Octa (Tol Combined)
| Required Detection Limit: 0.05 ng
TRIANGLE LABORATORIES, INC.
HR GC/HRMS ANALYSIS
|PROJECT: 43432
I
SAMPLE INFORMATION
1ST COLUMN
2ND COLUMN
RS Cone
20 All a 100.0 PG/jO.
1st.
1
1
|ooo
|001
1
|002
1
|003
1
|004
1
loos
1
|006
|007
1
(008
1
|009
1
1
1
1
I TLI / | GC/MS FILENAME. (CONFIRM | CONFIRM FILENAME (USF-R
crdl SAMPLE ID / CLIENT I COLUMN:U ' x) I ICOLOMllSGs lW~ IVOLOM
1 / SAMPLE ID | ||
| TLI Blank
\ \\<*-\ -xo ' V^>' '
1
1
1
1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 I
1
| Comments :
1
I
1
I
1
1
1
Type: A |
1
1
1
Spike File: SPX23704 I
1
Amt of Extract: 50% |
-REV 03/07/95 (PSTMF 6)- —
-------
.time _____ )
Ca-.._;TvL.
_NarL
luisT
^Q jf..
Signature
Date
Filename
Date*
Time*
Project^
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
o
2-3
^ ic-n-17
J/
\S
\J
\y
M-o
fe V
f-4
^_ i L
MtS
i£i
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u-/
a
IV
1
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Transcribed from chromatographic data
Dated initials required
ConCal Due:
ConCal Due:
srvr1/qa/forms/hrrunlog doc (02/05/97)
Page:
77
-------
Instrument ID Column Type Column ID Plot Name
^OS ^>^ "l-M-iTBinrf Tov
Ini. Vol. Acquisition QIC
~y A^>X v* — -- i -• / > A h v
Signature Date
Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Dale
Comments**
JJi
Jji
(A
iV
l
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s
to
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-Co—
M-O
21
M'
AM
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Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hrrunlog doc (02/05/97)
ConCal Due:
ConCal Due:
-------
. lun L
Instrument ID Column TVPB Column ID
VGTou^ "fc&^r "HSw^iiT*
Plot Name
TOv
Inl.Vol. Acquisition Q/Q
o*..0i-L_ Ej>Cu±i- MftfcfU^.
UUvX. ^ .=M^
Signature Date
Filename
tm^M^
U/?"* * U W V
u«*iv«r
^ 7^'L^C,
U'Z35
Date*
(0/10/1*
i '
lo/^/U
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/ '
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• Art
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Transcribed from chromalographic data
Dated Initials required
(02/05/97)
ConCalDue:
ConCal Due:
•/? /><>••)
-------
Triangle Labc 'es, Inc.
RUIIL ^
Instrument ID Column TVPB
Column ID
Plot Name
In). Vol.
3. &.!*(?
Acquisition
G/C
0 ftJ s
Signa
¥JL
mature
Date
Filename
Dale4
Time*
Projed #
Sample*
No.
Client Sample ID
Syr
332
Operator/Dale
Comments
'•'I
t/
TU
'G 7
66
(•/nj-O
5"
7
Tea
(cfiv/W-
T-o «>
Uvx
Uv. t
s. £
iv.f
1 (
Transcribed from chromatographlc data
Dated Initials required
(02/05/97)
A>
ConCalDue:
ConCal Due:
-------
mangle uauoratonca, Inc.
Run Log
Instrument ID Column Type Column ID Plot Name Ini. Vol.
~~7(~)~~5 f) ( 5^S ~7v i f£^ 1 ~T& ^— 9 • ® M £—
^^f^Q^y^t'
Acquisition
£ rC-14,5 ^.
^ ^^C^i^L4A--^^\^__^.
Signature
G/C
-- lO~3yf7
Date
Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments**
Al-D
2-
§0-10 -13-7J
M-o
* Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hrrunlog doc (02/05/97)
CO
00
ConCal Due:
ConCal Due:
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Type Column ID Plot Name Ini. Vol. Acquisition
"2OT" P/3 22.^" ~}?24>(&-f 77~7 X &i/r£ ^.(y^jf^Tr"
-i^'/L
Signature
QIC
K-t&iF—TjT*
Jo //"?•/ f*r>
Date
Filename
Date*
Time*
Project^
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
J
( tft
Ixv
t */ /y
7-**-
5.0
HMl-
VLC
\ VI-
\
1 -"UU.
6-t
V*
* Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hrrunlog doc (02/05/97)
CO
CO
ConCalDue: I
ConCal Due:
-------
R- •"' og
Instrument ID Column Type Column ID
V6X
Plot Name
TTf
In. Vol.
Acquisition
/ Signature
G/C
'
Date
Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
t
1.1.
C v
* Transcribed from chromatographic data
" Dated initials required
srvr1/qa/forms/hrrunlog.doc (02/05/97)
ConCal Due:
ConCal Due:
Page:
-------
Triangle Laboratories, Inc.
Run Log
Instrument IP Column Type Column ID Plot Name
Inj. Vol. Acquisition
X2-xlj2-
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 CapHola Drive P.O. Box 13485
Durham, NC 277134411 Research Triangle Park, NC 27709-3485
919444-5729 Fax # 919-544-5491
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43432
Method 23X Full Screen Analyses (DB-5)
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378- PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HXCDD 478
13C12-HpCDF 789
Other Standards
13C12- HxCDF 789
13C12-HXCDF 234
U973257
TLI Blank
ng
10/09/97
10/17/97
U
XAD
(0.004)
(0.005)
(0.008)
(0.007)
(0.007)
(0.008)
0.04
(0.003)
(0.003)
(0.003)
(0.004)
(0.003)
(0.004)
(0.004)
(0.005)
(0.006)
(0.008)
(0.004)
(0.005)
(0.007)
(0.008)
(0.003)
(0.003)
(0.004)
(0.005)
Percent Recovery
92.5
100
92.3
96.7
91.3
Percent Recovery
68.6
81.4
U973258
SO-23-1
ng
10/09/97
10/17/97
U
M2 3 TRAIN
£0.05}
0.07
0.02
{0.02}
0.03
0.02
0.03 B
2.4
0.36
0.38
0.16
0.07
0.05
(0.006)
{0.07}
(0.01)
{0.01}
2.7
0.84
0.19
0.02
19.1
6.1
0.69
0.04
Summary (% Rec)
93.7
95.6
92.0
98.9
101
Summary (% Rec)
101
112
S976909
SO-23-2
ng
10/09/97
10/23/97
S
M2 3 TRAIN
0.21
0.23
0.07
0.08
0.11
{0.12}
{0.09} B
6.6
1.4
1.4
0.91
0.46
0.26
{0.04}
{0.30}
{0.05}
0.04
6.6
2.4
1.1
0.14
60.0
24.2
4.7
0.10
102
92.0
95.8
85.6
94.6
107
116
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123
13C12-P6CDD 123
79.4
75.4
96.9
86.6
89.8
85.5
78.8
83.7
103
90.5
96.1
103
Page 1
10/24/97
U973260
SO-23-3
ng
10/09/97
10/17/97
U
M2 3TRAIN
0.13
0.10
(0.05)
(0.04)
(0.04)
(0.04)
{0.04} B
4.5
0.65
0.47
0.18
0.09
0.05
(0.03)
0.04
(0.05)
(0.03)
4.1
0.74
0.24
(0.04)
51.2
7
92
10
0
0.04
85.9
80.7
88.1
97.6
97.2
49.2
48.9
45.9
58.6
77.7
84.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:37 10/24/97
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43432
Method 23X Full Screen Analyses (DB-5)
Page 2
10/24/97
Data Pile
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
U973257
TLI Blank
ng
10/09/97
10/17/97
U
XAD
D973258
SO-23-1
ng
10/09/97
10/17/97
U
M23TRAIN
Internal Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 678 123 111
13C12-HXCDD 678 94.9 94.1
13C12-HpCDF 678 92.5 61.3
13C12-HpCDD 678 87.5 95.0
13C12-OCDD 84.0 63.5
S976909
SO-23-2
ng
10/09/97
10/23/97
S
M23TRAIN
120
106
92.4
89.7
63.8
U973260
SO-23-3
ng
10/09/97
10/17/97
U
M23TRAIN
62.8
61.3
47.5
70.9
89.2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:37 10/24/97
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Method 23X Full Screen Analyses
Data File
Sample. ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HXCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12- HxCDF 478
13C12-HXCDD 478
13C12-HpCDF 789
Other Standards
13C12- HxCDF 789
13C12-HXCDF 234
0973261
SO-23-4
ng
10/09/97
10/17/97
U
M2 3 TRAIN
0.12
0.10
{0.02}
0.03
0.04
{0.03}
0.08 B
4.1
0.61
0.52
0.26
0.11
0.06
(0.01)
0.07
(0.02)
(0.01)
4.6
1.3
0.41
0.03
43.0
11.3
1.2
0.07
Percent Recovery
91.1
95.4
99.0
101
105
Percent Recovery
75.3
82.5
U973262
FB1-M23
ng
10/09/97
10/17/97
U
M23TRAIN
(0.007)
(0.008)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
(0.009)
(0.007)
(0.007)
(0.008)
(0.006)
(0.007)
(0.008)
(0.01)
(0.01)
(0.01)
(0.007)
(0.008)
(0.01)
(0.01)
(0.009)
(0.007)
(0.007)
(0.01)
Summary ( % Rec )
85.8
97.7
88.3
94.3
98.3
Summary ( % Rec )
79.9
91.8
43432
(DB-5)
U973263
FB2-M23
ng
10/09/97
10/17/97
U
M23TRAIN
(0.006)
(0.008)
(0.01)
(0.009)
(0.009)
(0.01)
(0.01)
{0.03}
(0.007)
(0.006)
(0.007)
(0.005)
(0.006)
(0.007)
(0.008)
(0.01)
(0.01)
(0.006)
(0.008)
(0.01)
(0.01)
{0.03}
(0.006)
(0.006)
(0.009)
89.0
94.4
95.3
99.6
88.0
93.3
104
Page 3
10/24/97
U973264
LAB BLANK M23
ng
10/09/97
10/17/97
U
M2 3 TRAIN
(0.003)
(0.004)
(0.006)
(0.005)
(0.005)
(0.005)
0.01 B
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.004)
(0.004)
(0.004)
(0.003)
(0.004)
(0.005)
(0.005)
(0.003)
(0.003)
(0.003)
(0.004)
94.1
98.5
93.1
96.8
92.4
95.3
104
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123
13C12-PeCDD 123
69.7
83.5
96.0
110
57.6
86.4
93.5
109
78.9
90.2
87.5
100
85.0
82.3
101
118
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:37 10/24/97
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 43432
Method 23X Full Screen Analyses (DB-5)
Page 4
10/24/97
Data Pile
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Internal Standards
13C12-HXCDP 678
13C12-HXCDD 678
13C12-HpCDP 678
13C12-HpCDD 678
13C12-OCDD
D973261
SO-23-4
ng
10/09/97
10/17/97
U
M2 3 TRAIN
Percent
85.6
87.7
65.1
84.5
95.2
=f as as as a== ss as as
U973262
FB1-M23
ng
10/09/97
10/17/97
U
M2 3 TRAIN
Recovery Summary (% Rec)
110
102
80.5
99.6
99.7
U973263
FB2-M23
ng
10/09/97
10/17/97
U
M23TRAIN
102
101
82.1
94.8
95.1
U973264
LAB BLANK M23
ng
10/09/97
10/17/97
U
M23TRAIN
105
95.7
90.0
102
104
{Estimated Maximum Possible Concentration}, (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:37.10/24/97
13:37
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
X973636
SO-23-1
ng
10/09/97
10/18/97
X
M2 3 TRAIN
0.72
Method 23X (DB-225)
X973637
SO-23-2
ng
10/09/97
10/18/97
X
M23TRAIN
2.3
43432
X973638
SO-23-3
ng
10/09/97
10/18/97
X
M23TRAIN
1.8
Page 1
10/23/97
X973639
SO-23-4
ng
10/09/97
10/18/97
X
M2 3 TRAIN
1.3
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 95.4 102
58.9
87.9
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:4
:4B*p/2
-------
TRIANGLE LABORATORIES, INC. Page 2
Sample Result Summary for Project 43432 10/23/97
Method 23X (DB-225)
Data File X973680
Sample ID FB2-M23
Units ng
Extraction Date 10/09/97
Analysis Date 10/22/97
Instrument X
Matrix M23TRAIN
Extraction Type
Analytes
2378-TCDF (0.01)
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 81.8
(Detection Limit).
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713 Printed: 23-40 10/23/97
-------
TLI Project: 43432
Client Sample: TLI Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973257
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
XAD
TLI Blank
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
II
10/09/97
10/17/97
n/a
U973257
GG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
A*rfp& ; v * *'£%y ;
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
U,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
U,3,7,8-PeCDF
2,3,4,7,8-PeCDF
U,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
lWalr'^\ f^w;
Total TCDD
Total PeODD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
^;-!|>>B^i^
ND
ND
ND
ND
ND
ND
0.04
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
\*?SlV**SS;'?
ND
ND
ND
ND
ND
ND
ND
ND
XiM*e^if l^^^^l^f:-^!^;
0.004
0.005
0.008
0.007
0.007
0.008
0.90 36:26
0.003
0.003
0.003
0.004
0.003
0.004
0.004
0.005
0.006
0.008
'^^^:\m^^:^'y^f^ > «^*^£;; 7vifc£^
0.004
0.005
0.007
0.008
0.003
0.003
0.004
0.005
Page 1 Of 2
X237_PSRvlOOl LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:00 10/21/97
-------
w
,- .", -t - A - .
TLI Project:
Client Sample:
43432
TLI Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973257
Internal Standards
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C.2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
3.2
3.0
3.9
3.5
4.9
3.8
3.7
3.5
6.7
79.4
75.4
96.9
86.6
123
94.9
92.5
87.5
84.0
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.77
0.80
1.43
1.50
0.50
1.26
0.42
1.02
0.77
21:32
22:27
26:16
27:28
30:14
30:59
33:01
33:53
36:26
SuiTogatfl Standards
-------
Initial
Date..
Data Review By:
Calculated Noise Area:
2.59
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of U973257B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
0.65-0.
DC
DC
NL
SN
0
0:00
18:55
Peaks
0
RO 0
.86
.55
0.65-0.
DC
DC
NL
SN
4
0:00
21:03
21:32
21:53
22:06
22:27
Peaks
RO 0
0
0
RO 3
0
RO 0
.93
.72
.77
.46
.71
.99
89
14
21
0
89
1
45
7,668
10
81
33
7,829
0.813-1.106
.56
.17
.00
0.
0.
000
878
0.954-1.046
.82
.19 18.91
.75 3,328.24
.73
.38 33.71
.93 18.99
.25
0.
26.28 0.
4,340.51 1.
1.
47.67 1.
19.17 1.
000
978
000 13C12-2378-TCDF ISO
016
026
043
TCDD
320-322
320-322
37C1-TCDD
328
0.65-0.
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
0
0:00
19:15
20:45
21:31
22:22
22:30
22:47
23:28
Peaks
RO 1
RO 1
RO 4
RO 1
RO 0
RO 0
RO 1
0
.18
.32
.96
.11
.52
.26
.63
.75
nhsww i * wwf / AV»W f WA AWIVV — ~~™
89
2
0
0
6
1
6
1
3
0
.42
.94
.94
.99
.93
.55
.19
.93
.00
0.848-1.061
0.
0.
0.
0.
0.
1.
1.
1.
000
857
924
958
996
002
015
045
0.911-1.089
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
0:00
20:43
22:28
22:48
22:53
22:58
23:03
23:11
23:18
23:22
23:28
23:38
23:46
23:51
23:59
24:11
0
23
5,076
13
8
13
7
13
16
5
17
10
6
10
11
6
.97
.95 23.95
.57 5,076.57
.46 13.46
.86
.40 13.40
.92
.02 13.02
.16 16.16
.52
.39 17.39
.26
.77
.42
.27 11.27
.45
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
923
001 37C1-TCDD SDR1
016
019
023
027
033
038
041
045
053
059
062
068
077
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:00 10/21/97
-------
Page No.
10/21/97
Listing of O973257B.dbf
Hatched GC Peaks / Ratio / Ret. Tim*
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area. Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
8
NL
SN
SN
SN
SN
SN
5
NL
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
7
24:14
Peaks
0:00
21:00
22:14
22:27
22:53
23:02
23:08
23:41
23:51
23:58
24:12
Peaks
0:00
24:06
25:17
25:43
26:14
27:18
27:27
Peaks
0:00
25:19
25:52
26:16
26:35
26:50
27:05
27:26
27:36
27:48
28:03
Peaks
0.
RO
5,
5
185
.36
.22
65-0.89
1.
99
0.88
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
4.
1.
0.
0.
1.
82 6,
80 5,
95
63
21
04
42
54
50
12.
, __
32-1.78
1.
1.
3.
0.
1.
0.
0.
33
21
92
81
95
45
18
3
36
952
811
137
16
8
46
21
24
15
984
.54
.73 17.21
.75 3,134.57
.53 2.588.02
.39 73.82
.99
.99
.41 27.26
.61
.44
.74
.81
0.
19.52
3,818.18
3,223.51
77.62
26.22
1.
079
911-1.089
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
000
935
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
019
026
030
055
062
068
078
7
4
11
5
12
2
0
0
.75
.56
.65
.81
.55
.55
.94
.00
32-1.78
0.
1.
2.
1.
1.
8.
1.
0.
0.
1.
0.
97
68
12
43 7,
72
63
48 7,
52
55
04
69
14.
2
117
15
371
88
9
170
23
22
23
9
818
.11
.04 73.34
.38
.87 4.337.08
.99 56.33
.08
.47 4,283.39
.90 14.53
.60 13.74
.64 14.37
.38
.51
0.
0.
43.70
3,034.79
32.66
2,887.08
28.03
25.14
13.78
906-1.077
0.
0.
0.
0.
0.
1.
1.
000
918
963
979
999
039
045
848-1.152
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
000
964
985
000 13C12-P«CDF 123 IS2
012
022
031 13C12-PeCDF 234 SUR2
044
051
058
068
PeCDD
356-358
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
0:00
25:29
26:16
26:36
26:46
28:07
1.
RO
RO
RO
RO
RO
32-1.78
1.
0.
1.
1.
2.
0.
61
26
94
18
11
67
2
2
5
2
2
1
.51
.42
.97
.88
.70
.45
0.921-1.025
0.
0.
0.
0.
0.
1.
000
928
956
968
975
024
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page No.
10/21/97
Listing of U973257B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Coropound.Name.. ID.. Flags.
356-358
13C12-PeCDD
368-370
368-370
HXCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
DC WH 28:13
DC WH 28:19
DC WH 28:29
0 Peaks
DC NL 0:00
DC SN 25:20
DC SN 25:56
DC SN 26:16
DC SN 26:37
DC SN 27:06
DC SN 27:13
27:28
27:38
DC SN 27:51
27:59
28:14
DC SN 28:22
DC SN 28:29
4 Peaks
DC NL 0:00
DC SN 30:47
0 Peaks
DC NL 0:00
30:07
30:14
30:21
30:26
30:28
30:46
31:30
7 Peaks
DC NL 0:00
DC SN 30:02
DC SN 30:08
DC SN 30:14
DC SN 30:46
DC SN 30:53
DC WH 31:31
0 Peaks
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
0.
RO
RO
2.08
1.18
0.55
32-1.78
1.27
1.54
1.42
0.92
3.95
1.84
1
1
1
2
0
1
2
2
.43
.50 3
.49
.33
.83
.04
.71
.31
4
05-1.43
1
1
.21
.02
1.
3.
0.
0.
2.
3.
2.
7.
2.
6.
2.
,610.
407.
17.
24.
22.
12.
19.
56
49
99
00
04
20
40
81
86
83
92
79 2,168.94
88 244.22
93
35 14.80
08 13.42
57
53
0.
1,441.85
163.66
17.93
12.89
1.027
1.031
1.037
855-1.145
0.000
0.922
0.944
0.956
0.969
0.987
0
1
1
1
1
1
1
1
.991
.000 13C12-P*CDD 123
.006
.014
.019
.028
.033
.037
IS3
,065.10
8.
9.
0.
78
12
00
43-0.59
0
0
0
0
1
0
0
0
.54
.52 4
.50 5
.51
.16
.89
.51 3
.50 2
85.
,902.
,452.
61.
32.
42.
,387.
.685.
95
39 1,675.31
11 1,811.01
72 20.89
80 25.27
78 25.29
59 1,150.74
45 898.85
0.
0.
3,227.08
3,641.10
40.83
21.72
28.33
2,236.85
1,786.60
958-1.051
0
1
.000
.018 234678-HxCDF
AN
868-1.132
0
0
1
1
1
1
1
1
.000
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.004
.007
.008
.018 13C12-HXCDF 234
.042 13C12 -HXCDF 789
SOR3
IS4
ALT2
ALT1
16,564.84
.___ KluH*M . Uu**n« 1 u.^*v%v\ -B.1 1 ,_^».
1.
RO
RO
RO
RO
05-1.43
1
1
1
1
1
1
1
.17
.45
.96
.78
.72
.36
.15
5.
1.
6.
5.
4.
3.
3.
0.
68
05
63
64
82
82
21
00
0.
952-1.015
0
0
0
0
0
0
1
.000
.969
.973
.976
.993
.997 123478-HxCDD
.017
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:00 10/21/97
-------
Page No.
10/21/97
Listing of 0973257B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HPCDD
436-438
436-438
OCDP
442-444
1.05-1.43
DC NL 0:00 1.25
DC SN 30:20 RO 0.91
30:53 1.26 3
30:59 1.26 3
31:11 RO 2.25
31:17 1.22 4
31:27. RO 2.89
31:32 RO 0.96
DC SN 31:37 RO 6.88
6 Peaks 11
0.88-1.20
DC NL 0:00 1.16
DC SN 33:01 1.14
DC SN 33:21 RO 1.50
DC SN 33:37 RO 2.30
DC SN 33:50 RO 0.73
DC SN 33:55 RO 2.89
0 Peaks
0.37-0.51
DC NL 0:00 RO 0.59
33:01 0.42 3
33:12 RO 0.57
33:25 RO 0.55
34:14 0.41 2
4 Peaks 6
0.88-1.20
DC NL 0:00 RO 0.85
DC SN 33:17 1.14
DC SN 33:53 RO 0.78
DC WH 34:14 1.13
0 Peaks
0.88-1.20
DC NL 0:00 RO 0.85
DC SN 33:17 1.13
33:53 1.02 3
34:04 0.88
2 Peaks 3
0.76-1.02
DC NL 0:00 0.90
DC SN 32:59 RO 0.38
5.70
16.91
,174.01
,660.40
57.48
,011.35
31.79
101.45
18.66
,036.48
7.87
17.17
11.22
4.04
3.37
1.31
0.00
18.78
,536.24
88.57
58.77
,850.98
,534.56
3.83
14.41
14.26
7.42
0.00
9.81
12.93
.220.59
152.18
,372.77
LJnpnn / fy
nft^uu i \JG
6.75
6.39
0.968-1.032
0.000
0.979
1,768.08 1,405.93 0.997 13C12-HXCDD 478
2,038.93 1,621.47 1.000 13C12-HXCDD 678
57.69 25.66 1.006
2,204.68 1,806.67 1.010 13C12-HXCDD 789
41.00 14.19 1.015
56.16 58.77 1.018
1.020
0.996-1.043
0.000
1.000 1234678-HpCDF
1.010
1.018
1.025
1.027
0.939-1.121
0.000
1,050.52 2.485.72 1.000 13C12-HpCDF 678
35.25 61.51 1.006
22.50 40.81 1.012
822.48 2,028.50 1.037 13C12-HpCDF 789
0.977-1.005
0.000
0.982
1.000 1234678-HpCDD
1.010
0.971-1.029
0.000
0.982
1,623.47 1,597.12 1.000 13C12-HpCDD 678
71.32 80.86 1.005
0.890-1.110
0.000
0.905
SUR4
IS5
RS2
AN
IS6
SDKS
AN
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:00 10/21/97
-------
Pago No.
10/21/97
Listing of U973257B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
1
NL
1
35:17
35:26
35:42
35:43
36:32
36:58
37:09
37:20
37:39
37:45
38:36
38:45
Peaks
0:00
36:26
36:36
36:53
Peak
0:00
36:26
Peak
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
0.
RO
1
1
3
2
0
0
0
2
1
0
1
0
.21
.00
.72
.02
.82
.40
.68
.10
.81
.89
.16
.58
76-1.02
0
0
0
1
.86
.90
.84
.84
76-1.02
0
0
.70
.77
7.65
5.61
1.02
0.83
15.04
.04
.61
.91
.57
.80
.95
.76
0.00
7.59
26.40
3.90
3.57
26.40
3.53
5,141.90
5,141.90
0.968
0.973
0.980
0.980
1.003 OCDF
.015
.020
.025
.033
.036
.059
AN
1.064
0.890-1.110
12.50
13.90
0.000
1.000 OCDD
1.005
1.012
AN
2,243.66
0.995-1.005
0.000
2,898.24 1.000 13C12-OCDD
IS8
Column Description.
•Why Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (ram:33)
Rat.l -Ratio of M/M+2 Ions
OK -RO'Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
HH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
'llatU973257 #1-1024 Acq:17-OCT-1997 15t44i3S OC EI+ Voltage SIR 70S SOiB«t3362
303.9016 Ps2 BSUB(aS6,30,-3.0) PO3(9,5,3t 0.10*, 13448. 0,1. OOX,F,V) ExptEPCUSS
•RIAKOLB LABS TextiTil BLANK TLIit43432
100* A9.21E4
18(00 19:00 20:00 21:00 22:00 23:00
Plla:U9732S7 11-1024 Acgtl7-OCT-1997 15:44:35 OC BI+ Voltage SIS 70S Xoinai3922
305.8987 ft2 BSOB(256,30,-3.0) PKD(9, 5,3,0.10%, 15688. 0,1.00\,P,T) Exp:EPCUS2
TRIASOLB LABS TmxttTLI BLANK TLH43432
18:00 19:00 20:00 21:00 22:00 23tOO
fllmtU9732S7 tl-1024 Acqtl7-OCT-1997 15:44:35 OC EI+ Voltaffa SIR 70S tfoisat482
315.9419 fi2 BSVB(256,30,-3.0) PXHI9,5,3,0.101,1928.0,1.00f,P,T) Exp:EPCUS2
TRZAOOLS LABS TfXt*TLI BLANK TLX#43432
IOCS
80:
601
40:
oj
A3
IS7
18(00 15(00 20(00 21(00 22(00 23(00
Pll»iU973257 tl-1024 Acq:17-OCT-1997 15t44t35 OC EH- Voltayt SIR 70S Nola»:516
317.9389 Fl2 B3UB(256,30,-3.0) PKD(9,5,3,0.10*,2064.0,1.00*,P,T) Exp:EPCU33
TRIASOLX LABS fncttTLI BLANK TLH43432
1005
80:
40:
20:
0.
A4
J4E7
18:00 19:00 20:00 21(00 22(00
Pilu:U973257 tl-1024 Aoqtl7-OCT-1997 15t44>35 OC EH- Voltagt SIR 70S
330.9792 P:2 Exp:EPCU32
TRIANOLS LABS TextlTLI BLANK 7LIH43432
23*00
1009
00:
60:
40:
20:
0.
17:48 18(22 18:46
24 tOO
Time
24 tOO
oso
Via*
IBS
9E6
7S6
4E6
2S6
.OEO
24100
24(00
18,00 19:00 20:00 21:00 22(00
Pll»tU973257 tl-1024 Acqt 17-OCT-1997 !Si44,35 OC EH- Voltagm SIR 70S
375.8364 P:2 SxptBPCUS2
TRXANOLg LABS TaxtlTLI BLANK TLXt43432
1003
80:
60:
40:
20:
o:
23 tOO
24 tOO
ass
2S6
.7E6
.1X6
.6X6
.0X0
Time
.1X7
.9X6
.6X6
.4X6
.2X6
.0X0
Tim»
..3.SE4
18'37 T5 igta aogi "I" 23,04 - f-.«
t^^^M^^L^^ r'
18(00
-.7.1X3
19100
20:00
21 tOO
22100
23 tOO
. oso
Tlm«
-------
Plle*U973257 #1-1024 Acq*17-OCT-1997 15*44*35 OC EI+ Voltage SIR 70S
319.8965 P*2 BSUB(256,30.-3.0) PXD(7, 5,3,0.10X, 3244.0,1. 00*,F,T) Exp,EPCUS2
TRIASOLS LABS TexttTLI BLANK TLIJ43432
20tOO 21(00 32:00 23*00
Pll»*U973257 *1-1024 Aoq*17-OCT-1997 15t44s35 OC BI+ Voltage SIR 70S Soil*:687
321.8936 P*2 BSOB(2S6,30,-3.0) PXO(7,5,3t0.10\,2748.0,1.00*,P,T) Exp:EPCUS2
TSIASOLS LABS TfXttTLI BLASK TLH43432
2004 AJ.08E5
20,00 21iOO 22tOO 23tOO
Pll»:U973257 91-1024 Acqtl7-OCT-1997 15:44:35 OC ZI+ Voltage SIR 70S Noli*il992
331.9368 P:2 B3U3(256,30,-3.0) PKH(7,5,3, 0.10\, 7968. 0,1. 00*,P,T) SxptBPCU32
TRIANOLE LABS Tmxt:TLI BUHK TLI»43432
.1.4E4
24100
24100
1003
00:
so.
40.
20:
A3.13B7
\A2.59B7
20,00 21,00 22,00 23,00
Fll»tU973257 11-1024 JLcytn-OCT-1997 15,44:35 OC BI+ Voltag* SIS 70S SOll»t998
333.9338 Pt2 BSVB(256,30,-3.0) PXD(7,5,3,0.10*,3992.0f1.00*,P,T) Sxp,SPOJ33
TRUUtOLB LABS TmxttTLI BLUR TLXf43432
loan
24 tOO
20(00 22(00 22(00 23(00
Plle*U973257 11-1024 Acq*17-CCT-1997 15*44*35 OC XI* Voltage SIS 70S No±*e*48S
327.8847 P*2 BSOB(256,30,-3.0) PKD<7,5,3, 0.10*, 1940.0,1.00*,P,T) Xxp,EPCUS2
TRIANOLE LABS TextlTLI BLASK TLI143432
24*00
100*
so:
ffo:
40:
20.
0.
AS
08B7
20<00 21(OO 22(00 23tOO
F11»,US73257 tl-1024 Acqtl7-CCT-1997 15,44,35 OC Sl-f Voltagt SIS 70S
330.9792 P,2 Sxp,SPCU32
TSIASOL8 LABS TmxttTLI BLUOT TLH43432
19*21 19i45_ 2.0*07 20*33 20*51 21*23 21*48 22*23 22*50
100J
00:
60:
40:
20:
o.
24100
20*00
21*00
22*00
23*00
24*00
-6.2B6
-4.9S6
.3.7E6
.2.SSS
.1.2E6
.0.050
Tin*
A3.B3B/
1,
22B7
\
7.7B6
S.1SS
4.6E6
3.1B6
1.5E6
O.OSO
Tim*
.1.0S7
.8.2ES
.6.2S6
.4.1X6
.2.1S6
.0.0*0
.1.0X7
.8.2X6
.6.2X6
.4.1X6
.2.1X6
.0.0X0
Tim*
-------
'Iloi0973257 #1-1024 Acqtl7-OCT-1997 15:44:35 OC EH- Voltago SIR 70S NolB»t2210
\39.8S97 Ft2 BSUB(2S6,30,-3.0) PKD(7,5,3,0.10^,8840.0,1.00*,F,T) ExptEPCUS2
TRXANOLE LABS ToxtiTLI BLANK 713*43432
100H
24100 25tOO 26tOO 27:00 28s00
Pilot0973257 #1-1024 Acqt17-OCT-1997 15i44i35 OC EH- Voltage SIR 70S Nol*o:1663
341.8S67 Ft2 BSUB(25S,30,-3.0) PKD(7,5,3,0.10*,6652.0,1.00*,P,T) BacptSPCns2
TRIANOLX LABS ToxttTLZ BLANK TLI943432
100* A7 3S4
24100 25 0 26tOO 27*00 28tOO
Fll*t09732S7 91-1024 A&jt 17-CCT-1997 15t44i3S OC Eli- Voltagt SIS 70S Nolm»t641
351.9000 Ft3 BSUB(256,3Q,-3.0) PKD(7,5,3,0.101,3564. 0,1. 00*,P,T) ErpiEPCUS2
TRIANOLS LABS ToxtiTLI BLANK TLIf43432
ion
80.
SO.
40:
20.
14.34E7
24.100 25100 26tOO 27iOO 28tOO
Fil»iU973257 tl-1024 A.CXJ: 17-OCT-1997 15t44t3S OC SI+ Voltagu SIS 70S Nolt»t6S8
353.8970 ft2 B3UB(256,30,-3.0) PKD(7,5,3,0.10*,2632.0,1.00*,P,T)
TRIASQIiB LABS TmxtiTLX BLANK TLIS43432
100%
Pll»iU973257 91-1024 Aegil7-OCT-1997 15t44i35 OC BI+ Voltayt SIR 70S
330.9792 Ft2 S*ptSPCUS2
TRIASOLS LABS ToxttTLI BLANK TLX#43432
40:
20.
o:
.1.0X7
.7.6X6
'.5.0X6
.2.5S6
0.0X0
A3.03E7 A3. 89X7
I 1
11 11
24tOO 25(00 26:00 27(00 28\00
-8.5X6
.6.8X6
'-.5.1X6
-.3.4X6
-.1.7X6
0.0X0
Tlaa
37t31
28t03
-9.8S6
-.7.8X6
.5.986
.3.9X6
-.2.0X6
24t00 25tOO 26tOO 27:00
F11»:U973257 91-1024 Acytl7-OCT-1997 15:44:35 OC Eli- Voltage SIR 70S
409.7974 Ft2 Exp:EPCUS2
TRIASOLX LABS TmxtiTLX BLANK TLX943432
100H (
24:52 25(11
SO.
40.
20:
0.
28tOO
0.0X0
Tim*
24100
25\00'
26:00
27:OO'
-3.3X4
.2.6X4
'-.2.0X4
-.1.3X4
-.6.6X3
28:00
LO. 0X0
Wa.
-------
'llatQ973257 tl-1024 AcqiU-OCT-1997 15,44,35 OC SI* Voltage SIR 70S SoiS»t777
55.8546 Pi2 BSUB(256,30,-3.0) PKD(S,5,3,0.OS\,3108.0,1.00*,P,T) ExptEPCUSl
TRIAKOLS LABS ToxtlTLI BLANK TLI143432
100* A3. 5E4
26iOO 27:00 28'tOO
Fllu,U973257 91-1024 Aatjtl7-OCT-1997 15i44t35 OC SI* Voltaffm SIR 703 Noie»,482
357.BS16 Pt2 BSVB(2S6,30,-3.0) PKD(5,5,3,O.OS\, 1928.0,1.00\,P,T) ExpiEPCUS2
TRIANOLB LABS TtatttTLI BLUOC TLXI43432
100*A5.61E4
36,00 37 tOO 20100
Pil»tU973257 01-1024 Aeqtl7-OCT-1997 15144,35 OC Sit- Voltafff SIR 703 Nod.f»,618
367.8949 fi2 BMUB(2Sf,30,-3.0) PXD(5,5,3,0.05\.2472.0,1.00*,PtT) Exp,EPCVS2
TRULXOLB LABS TwctiTLI BLABX TLXI43432
10A A2.J.7S7
80.
60.
40.
20.
36,00 27,00 28,00
Pilm,U973257 01-1024 Aaqtl7-OCT-1997 15,44,35 OC SI* Voltaffm SIR 70S Nols»,492
369.8919 Pt2 BSOB(256,30,-3.0) PKD(5,S,3,O.OS\,1968.0,1.00*,P,T) Sxp,EPCUS2
TRIASOLS LABS TuxttTLI BLASK TLI143432
200JI A1.44S7
80.
60.
40.
20:
26,00 27,00
Fllf,0973257 #1-1024 Acq,17-OCT-1997 15,44,35 OC SI* Voltajr* SIR 70S
330.9792 Ft2 Exp,BPCVS2
TRXASOLX LABS TuxttTLI BLAOC TLIf43432
25,36 . 26,0826,19
' yV^vVvx^~'WvWVV\ '
soJ
60.
40.
20.
0.
28100
.6.5X6
.5.2X6
.3.9X6
.2.6E6
.1.3X6
0.0X0
36,00
27tOO
4.4E6
3.6E6
2.7X6
1.BE6
8.9S5
.O.OSO
Time
.9.7S6
.7.8X6
.5.8S6
.3.9X6
.1.9X6
28100
0.0X0
-------
Pllf:ff973357 #1-404 Acq:17-OCT-1997 15:44i3S QC EH- Voltage SIR 703 NOlBa:3400
373.8208 P:3 BSVB(256, 30,-3.0) PKD(7,5,3,0.10*,9600.0,1.00*,F,T) ExpiEPCUS2
TRIASOLS LABS ToxttTLX BLANK TLI043432
IOCS
so:
29:00 30:00 31:00
Fll«iU973257 #1-404 Aaq:17-OCT-1997 15:44:35 OC EI+ Voltaffa SIR 70S Nolsa:lS8B
375.8178 P:3 B3VB(256,30,-3.0) PKD(7,5,3,0.101,7953.0,1.00X,P,T) Exp:BPCUS2
TRIASOLB LABS TrnxttTLI BLANK TLI043432
100% A4.33E4
so:
sol
40:
201
29:00 30:00 31iOO
Pi.l»:U973257 91-404 Aaqt 17-OCT-1997 15:44:35 OC SH- Voltago SIR 70S Noll*: 15100
383.8639 Pi3 BSUB(3S6,30,-3.0) PKD(7,5,3,0.10*, 60400.0,1. 00*,P,T) Bxp:EPCUS3
TRIANOLX LABS TvcttTLI BLANK TLI*43432
100H Al. 8.1X7
32:00
A2.45E4
.3.4S4
12.7S4
.2.0B4
.1.3S4
.6. 7S3
32:00
00:
60-
401
aoj
A1.15S7
A8.99BS
0. OSO
Time
.6.1E6
.4.8E6
.3.6S6
13.4S6
''.1.2E6
39100 30:00 31:00
Pll»:U973257 #1-404 Aaqt17-OCT-1997 15:44:35 OC ST* Voltaff* SIR 70S Noia»:27876
385.8610 P:3 B3US(2S6,30,-3.0) PXD(7.5,3,0.10*,111504.0,1.00*,P,T) S3Cp:BPCU32
aLX LABS TtactlTLI BLANK TLI*43432
1003C
32100
0.050
Tima
A3.S4B7
ft n
M A2.24E7
A A1.79B7
A
V A
7 V v. ; V / V
.1.2E7
.9.7B6
.7.3E6
.4.9ES
.3.4E6
29:00 30:00 31:00
Pll»iU973257 01-404 Acytl7-OCT-1997 15:44:35 OC BH- Voltage SIR 70S
392.9760 P:3 Exp:EPCUS2
TRIANOLE LABS TvxtlTLI BLANK TLZ#43432
29:05 29:19 29:35 29:54 30:0730:18 30:43
32:00
ao:
#o:
40:
20:
o:
31:06 31:22
31:39
_5.4E6
14.3ES
13.2B6
.2.1B6
.1.1S6
~r
25(00 30iOO 31>00
Pll»:U973257 01-404 Acq:17-OCT-1997 15:44:35 OC ET+ VoltafiT* SIR 703
445.7555 P:3 Exp:BPCUS3
TRIANOLS LABS TfXt:TLI BLANK TLI043432
100H .....
29:24 10.1* 30:19 30:46 I I 31«17
32:00
tO.OBO
Tiom
29:00
30:00
31:00
32:00
-------
'li«*V973357 91-404 Acq: 17-OCT-1S97 15*44*35 OC EZ+ VOltaffB SIR 70S NoiS0,1531
389.8156 P:3 BSVB(256,30,-3.0) PKD(7,5,3, 0.10*, 6124.0,1.00X,F,T) Exp:EPCU32
'RIANOLE LABS TuxttTLI BLANK TLH43432
100H A5.81S4
29:36 29*48 30,00 30*12 30*24 30*36 30:48 31*00 31*12 31*24
Pil»*U973257 11-404 Aag*17-OCT-1997 15*44*35 OC EH- Voltagm SIR 70S Noil*: 1310
391.8127 P:3 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,5240.0,1.00*,P,T) ExptSPCVS2
TRIANGLE LABS TmxttTLI BLANK TLH43432
6S4
29*36 29i48 30*00 30*12 30*24 30*36 30:48 31*00 31*12 31*24
Fll»*U973257 tl-404 Acq, 17-OCT-1997 15*44*35 OC ZT+ Voltago SIS 703 Noie»:1586
401.8558 P:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,6344.0,1.00*,P,T) Exp:SPCU32
LABS TfXttTI,! BLANK 7LIt43432
100H i3.a*B7 A2.30S7
31:36
31:36
80.
60.
40.
20.
41.77.
29,36 29*48 30*00 30*12 30,24 30*36 30*48 31*00 31*12 31*24 31*36
Pil*:U973257 #1-404 Acq*17-OCT-1997 15,44*35 OC EH- Voltay» SIR 70S Soi*»*1264
403.8529 P,3 BSVB(256,30,-3.0) PKD(7,5,3,0.10*e505t.O,1.00*,P,T) Sxp,XPCU32
TRIANGLE LABS T*Xt:TLX BLANK TLIt43432
1001
80.
60.
40.
20.
A1.62E7
A1.81S7
A1.41E1
29*36 29,48 30*00 30*12 30*24 30*36 30*48 31*00
Pile:U973257 #1-404 Acq:17-OCT-1997 15*44*35 QC XI* Voltagm SIR 70S
392.9760 P,3 BxptBPCUS2
TRIANGLE LABS TmxtiTLI BLANK TLH43432
100X29(35 39,45 29{54^ 30*07 30*18 30,37
31124
31*36
Time
7.5S6
6.0E6
4.5X6
3.0X6
1.5X6
0. 0X0
.6.3E6
.5.0X6
.3.8X6
.2.SE6
.1.3E6
,0.050
Time
so:
eo:
40.
20.
0.
®Z^^^
.5.3X6
".4.2X6
.3.2X6
.2.1X6
-1.1X6
29*36 29*48
30,00
30,12 30,24 30*36 30,48
31,00 31*12
31,24
31,36
0.0X0
Tim,
-------
•lla:U973257 #1-596 Acqtl7-OCT-1997 15(44(35 OC BH- Voltage SIR 70S Noino:2117
407.7818 Pi4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*,846B.O,1.00X,J?,T) ExptEPCUS2
•SIANGLE LABS TfUCtsTLI BLANK TLI«43432
100H A9.J.4E4
33tOO 33t12 33i24 33>36 33(48 34:00 34il2 34:24
Pilu:U9732S7 91-596 Acy: 17-OCT-1997 15t44t35 OC BH- Voltaff* SIB 709 Hole*11820
409.7789 Pi4 BSUB(2S6,30,~3.0) PKD(7,S,3, 0.10\,7280.0,1.00*,P,T) ExplSPCUS2
TRIANGLE LABS TmxttTLI BLANK TLI#43432
loon
33»00 33s 12 33:24 33:36 33:48 34:00 34.112 34:24
Pllm:U9732S7 *l-596 Acq:17-OCT-1997 15:44:35 GC SH- Voltagt SIS 70S Koita:3867
417.8253 P*4 BSUB(256,30,-3.0) PKD(7,5,3,0.10^,15468.0,1.00\,P,T) Exp:BPCU32
TRIANOLB LABS TfXttTLI BLANK TLHf43432
lOOSt A1.05E7
34:36
34:36
so:
fffl:
40:
20:
OJ
A8.22S6
33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24
Pil»:U973257 tl-596 Acgi 17-OCT-1997 15:44:35 OC BH- Voltag* SIR 70S Nola»:6S22
419.8220 Pi4 B3UB(2S6,30,-3.0) PXD(7,5,3,0.10*,26088.0,1.00*,J*,T) SxptSPCUS2
TRIANOLE LABS TvctlTLI BLANK TLI*43432
100H A2.49B7
so:
60:
40:
20:
A2.03E7
33:00 33:12 33:24 33:36 33:48 34:00 34:12
Pll»:U9732S7 tl-596 Acq:17-OCT-1997 15:44:35 OC SH- Voltagt SIR 70S
430.9729 Pi4 Exp:SPCUS2
TRIANQLB LABS TtXttTLI BLANK TLI#43432
100*
80:
60:
40.
20:
a:
34:24
33(00 33(12 33(24 33(3ff 33(40 34(00 34(12
Pil»:U9732S7 01-596 Acq: 17-OCT-1997 15(44(35 OC BH- VoJtagr* SIR 70S
479.7165 Pi4 Bxp:BPCV32
TRIANOLB LABS TextiTLI BLANK TLI043432
33143
so:
sol
40:
20:
0.
34:24
34:22
32:57
33:1
33t21.
33132
34113
33100
33112
33:24
33:36
33(48
34:00
34(13
34.24
34:36
34136
34:36
34(4
34:36
.3.8E6
.3.1S6
.2.3E6
•.1.5B6
'•.7.6BS
-.o.oso
Tim*
9.1B6
.7.3E6
5.5E6
3.7B6
1.8E6
0. OBO
Time
.2.7B6
.2.2B6
.1.6B6
.1.1B6
.S.SBS
.0.0X0
Tin*
.3.3B4
.3.024
.2.324
.1.524
.7.523
O.OSO
Tim*
-------
FHOSUS73257 91-596 Acqt17-OCT-1997 15:44:35 OC EH- VolCago SIR 70S NOISO1973
423.7766 Pt4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,3892.0,1.00*,P,T) Exp:EPCUS2
TRIANQLB LABS TaxtlTLI BLANK TLI943432
icon
33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06
?!!•: 17973 257 91-596 Acqt 17-OCT-1997 15:44:35 OC BH- Volt ay • SIS 70S Noia»:1147
425.7737 P:4 BSOB(2S6,30,-3.0) PKD(7,5,3,0.10\r4588.0,1.00\,PfT) Exp:EPCUS2
TSXANOLS LABS TfXtlTLI BLANK TLI943432
lOOn A9.34E4
O.OEO
'34': 12 ' '34\ 18 ' '34\24 tiaa
33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06
Pil9iO9732S7 91-596 Acyt17-OCT-1997 15:44:35 OC Elf Volta£T« SIS 70S Sois»:2499
435.8169 P:4 B3UB(256,30,-3.0) PKD(7,5,3,0.10\,9996.0,1.00\,P,T) Exp:EPCU32
TRIANQLE LABS T*Xt:TLI BLANK TU943432
lOOn Al.f2S7
so:
eo:
401
20.
O.OEO
34': 12 34:18 34:24 Tima
S.8E6
4.7B6
3.5E6
2.3B6
1.2B6
0.050
33112 33118 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06
P±l»tU973257 91-596 Acq: 17-OCT-1397 15:44:35 OC ET* Voltagt SIR 703 Hoist:2957
437.8140 Pi4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,11828.0,1.00*,P,T) Bxp:EPCVS2
TRIANQLB LIBS TmxtiTLI BLANK TLH43432
100H A1.60K7
80.
60.
40.
20.
'34*112 ' '34*118 ' '34124 Tim*
rS.6E6
.4.SB6
.3.4B6
.2.2E6
.1.1B6
0.050
33:12 33tl8 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06 34:12 34:18 34,24 Tim*
Filet0973257 91-596 Acq: 17-OCT-1997 15:44:35 OC EH- Yoltaff* SIR 70S
430.9729 Pi 4 Bxp:SPCU32
TRIANOLX LABS T*Xt:TLX BLANK TLI943432
.2.2S6
.1.6E6
.1.1X6
.5.4B5
80.
60.
40.
20.
o.oso
33i12 33:18 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06 34:12 34:18 34:24 Tim»
-------
>il»tV9732S7 ti-$9* Acqtl7-OCT-19Sl i5,44>35 OC EI+ Voltag» SIR iOS Noise,1598
\41.7428 P,4 BSUB(256,30,-3.0) PKD(7,S,3,0.10X,6392.0,1.00*,P,T) ExptEPCUS2
•RIANQLB LABS TaxttTLI BLANK TLIV43432
33(00 34(00 35tOO 36tOO 37iOO 36tOO
'llmtU9732S7 *l-596 Acqil7-OCT-1997 15i44i3S OC SI> Voltage SIR 70S Nola«:1777
443.7399 Pt4 BSVB(256,30,-3.0) PKD(7,3,3,0.10*,7108.0,1.00*,F,T) ExpsEPCUS2
TRIANOLE LABS TexttTLI BLANK TLX*43432
39 tOO
33100 34»00 3StOO 36tOO 37iOO 38:00
filmtU973257 fl-596 Acqil7-OCT-1997 15t44i35 OC EH- Voltage SIS 70S
430.9729 fi4 ExpiEfCV32
TRIANOLE LABS TfXttTLI BLANK TLX#43432 •
100H 32tS6 33,30 34l03
'J ' " 37,26 38,13
39 tOO
3St47
33(00 34>00 35(00 36iOO 37,00 38tOO
Pll»t09732S7 tl-596 Aeyil7-OCT-1997 15,44,35 OC Bl+ Voltage SIR 70S
513.6775 Pi4 BxpiSSCUS2
TRIABOLB LABS TexttTLI BLANK TLI*43432
39100
-2.7B6
.2.SS6
.2.2P.6
.1.9S6
.1.6S6
.1.4B6
.1.1S6
.8.235
IS.SBS
.2.7B5
O.OEO
Tim
33 tOO
-------
'110IU973257 91-596 Acq: 17-OCT-19S7 15,44,35 GC EI+ Voltagf SIR 70S NO1B»,175S
457.7377 Pit BSUB(256,30, -3.0) PKD(7,5,3, 0.10%, 7036.0,1.00*,P,T) Exp,BKUS2
TRIAKOLS LABS TlXtlTLI BLANK TLI#43432
100H JL1.48B5
80.
60.
40.
20.
36tl8 36,24 36:30 36,36 36,42 36,48
Pll»,V973257 #1-596 Acqt17-OCT-1997 15,44,35 OC SX+ Voltafff SIR 70S Solm»,2036
459.7348 F,4 BSUB(256,30,-3.0) PKD(7,5,3, 0.101,8144.0,1.OOX,P,T) ExpiXPCUS2
TRIAHOLB LASS TfXttTLI BLANK TLI#43432
100H 11.',
80.
60.
40.
20.
36,18 36,24 36,30 36,36 36,42 36,48
Pll»tU973257 fl-596 JLcqt 17-OCT-1997 15,44,35 OC BX+ Voltagf SIR 70S Soltm,829
469.7779 ft4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,3316.0,1.00*,P,T) Exp,SPCUS2
TXIUMLX LABS TmxtlTLI BLANK TLI*43432
100H A2.2.4X7
36,18 36*24 36,30 36,36 36,42 ..36,48
Pll»,U973257 §1-596 Acqtl7-OCT-1997 15,44,35 OC KT* Voltay* SIR 70S Soim»,1188
472.7750 P,4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,4752.0,1.00*,P,T) Bxp,EPCVS2
TRIANQLX LABS TfXttTLI BLANK TLI*43432
10OH A2.90S7
36,18 36,24 36,30 36,36 36,42
Pil»lU9732S7 91-596 Ac
-------
CD
CC
Peak Locate Examination:17-OCT-1997:15:43 File:U973257
-------
File:U973257 #1-596 Acq:17-OCT-1997 15:44:35 GC EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:TLI BLANK TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A1.25E5
OJ
'0 36iOO 37iOO 38iOO
File:U973257 #1-596 Acq:17-OCT-1997 15:44:35 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:TLI BLANK TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A1.39E5
80 j
60j
40 j
20 j
OJ
39:00
5.
\sAd*}u^J\^ikfy^^
13
;2
35:00 36:00 37:00 38:00
File:U973257 #1-596 Acq:17-OCT-1997 15:44:35 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:TLI BLANK TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36;26
801
60 j
401
20 j
OJ
0
39:00
35:00
36:00
s
13
L2
Ll
LO
37:00
38:00
39:00
5E4
4E4
3E4
2E4
1E4
,OEO
Time
.3E6
.1E6
.8E6
.5E6
.3E6
.OEO
-------
r-r
TLI Project: 43432
Client Sample: SO-23-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973258
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-1A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
Anafytes %" -^" ^ J'^ 75
2,3,1,S~TCDD
1,2,3,1, 8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
^'i^c^^^^^i
EMPC
0.07
0.02
EMPC
0.03
0.02
0.03
2.4
0.36
0.38
0.16
0.07
0.05
ND 0.006
EMPC
ND 0.01
EMPC
*$**?-;
0.05
0.02
0.07
0.01
XV;;ife*fc
1.68
1.23
1.32
1.08
0.88
0.74
1.47
1.54
1.32
1.36
1.27
- '?
-------
TLI Project: 43432
Client Sample: SO-23-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973258
Internal Standards
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
nCl4-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13Cl2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
13Ci2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Typ* A) \V
13C12-i,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards •, .?; :;
13C,2-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt {ng} 'V
"• ••
3.6
3.4
3.2
3.3
4.4
3.8
2.5
3.8
5.1
Amf^Wf-^
3.7
3.8
3.7
4.0
4.0
Mft|OT%C^
4.0
4.5
v- \ '\ '•• ,1*1
* "; v %7$regvg
....•; ':.':..<...':.. •:.
89.8
85.5
78.8
83.7
111
94.1
61.3
95.0
63.5
f£ '^fl&SKS&ve
93.7
95.6
92.0
98.9
101
X ? *° i% -. •. s- '••••• v>
101
112
5i\SS$
nv QC Limits ^
-.
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
^x^Ci,tn»it» >^
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
;• •- \f -A "• -•'"• ""-. s %>
i5i;;||QC?;l«lRiite:.^.rJ
40%-130%
40%-130%
"r^A^ ^
Ratio
f
0.77
0.82
1.51
1.44
0.51
1.21
0.38
1.04
0.87
*tori*
1.48
0.51
1.22
0.38
* s Ratio:
0.50
0.50
;;Ratfe
0.81
1.20
RT ^ x Flaas^
% s
21:32
22:28
26:16
27:28
30:14
30:59
33:01
33:54
36:26 •
^^m^$'&*&^
22:29
27:05
30:08
30:54
34:14
.^r-ST^-- PiS[S;>
31:30
30:46
> * m->V;Fteas-
22:15
31:17
Data Reviewer.
Vc-
Page 2 of 2
10/23/97
X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:13 10/23/97
-------
Initial
3ate. .
Data Review By:
\i
Calculated Noise Area:
5.22
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
10/23/97
Compound/
M_Z QC.Log Omit Why
Listing of U973258B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
TO
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
D
0.65-0.89
DC NL 0:00
17:41
18:14
18:28
18:54
19:16
19:48
20:11
20:36
20:44
21:01
21:20
21:34
22:08
22:24
22:40
23:41
16 Peaks
RO 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
40
75
74
72
75
75
75
75
77
77
75
74
74
74
75
83
79
2,
1,
1,
8,
5,
5,
4,
4,
1,
2,
2,
6,
2,
1,
51,
6
553
584
121
898
706
505
401
028
875
601
245
391
499
477
249
151
292
.51
.72
.24
.96
.98
.43
.12
.39
.35
.96
.20
.63
.04
.99
.95
.33
.02
.31
1,091
675
470
3,822
2,445
2.355
1,885
1,750
818
1,118
953
2,712
1,065
634
116
66
.14
.10
.34
.61
.54
.78
.53
.79
.32
.99
.39
.86
.03
.25
.81
.77
1,462
909
651
5.076
3,260
3.149
2,515
2,277
1,057
1,482
1,292
3,678
1,434
843
132
84
0.65-0.39
DC NL 0:00
DC WL 20:09
21:00
21:32
DC SN 22:16
DC SN 22:32
DC WH 22:42
DC WH 22:45
DC WH 23:36
DC WH 23:46
2 Peaks
RO 2.
0.
0.
0.
RO 0.
RO 1.
RO 3.
RO 1.
RO 0.
RO 3.
29
78
79
77
64
79
15
03
47
88
9,
10,
3
83
56
962
14
12
5
6
24
4
018
mr*n
.22
.29
.08
.59
.11
.83
.10
.09
.44
.25
.67
0 /
0.65-0.89
DC NL 0:00
19:10
19:40
20:04
20:59
21:20
21:49
D CO 22:14
RO 2.
0.
0.
0.
0.
0.
0.
0.
03
77
79
77
78
78
72
73
1,
1,
2
588
803
400
142
662
315
346
.14
.49
.32
.85
.44
.34
.08
.90
24
4,331
.74
.81
31
5,630
0.
.58
.14
.62
.37
.89
.34
.86
.56
.64
.21
.24
.18
.96
.70
.52
.25
0.
.34
.78
813-1.106
0.000
0.821
0.847
0.858
0.878
0.895
0.920
0.937
0.957
0.963
0.976
0.991
1.002 2378-TCDF AH
1.028
1.040
1.053
1.100
954-1.046
0.000
0.936
0.975
1.000 13C12-2378-TCDF ISO
1.034
1.046
1.054
1.057
1.096
1.104
tV*TMl ITrtl 1 /M*re • — •_ — —
689
353
174
502
289
132
.88
.66
.31
.09
.49
.21
898
449
226
640
372
182
0.
.61
.66
.54
.35
.85
.87
848-1.061
0.000
0.853
0.875
0.893
0.934
0.950
0.971
0.990
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:13 10/23/97
-------
Page No.
10/23/97
Listing of U973258B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TM
AN
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
WH
12
ML
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
7
NL
SN
SN
6
NL
SN
SN
SN
22:21
22:28
22:41
22:54
23:10
23:24
23:33
23:41
23:58
Peaks
0:00
19:09
19:23
19:32
19:42
20:45
21:00
22:29
22:44
22:50
23:00
23:20
23:30
23:48
23:51
23:52
23:56
24:05
Peaks
0:00
22:15
22:28
22:53
23:20
23:29
23:48
23:56
24:10
Peaks
0:00
23:59
24:25
24:34
24:46
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
0
0
0
0
0
1
0
0
5
.76
.59
.73
.80
.91
.82
.74
.74
.28
6
1
6
a
998.00
121.60
134.83
201.94
54.85
3.66
5.51
49.68
1.19
,473.42
2.04
9.01
4.47
34.09
35.09
,154.25
7.41
,698.67
13.01
14.27
190.30
33.98
35.88
2.39
2.92
2.56
11.49
12.00
.140.36
430
52
56
89
28
21
1,154
6,698
13
14
190
33
35
.00
.90
.79
.57
.26
.12
.25
.67
.01
.27
.30
.98
.88
65-0.89
2
0
0
0
1
1
1
1
0
.56
.81 7
.82 7
.94
.09
.84
.25
.07
.53
15
32-1.78
1
1
4
1
2
.45
.58 1
.10
.92
.11
1.68
,980.42
,569.82
182.13
28.74
30.16
31.84
11.89
16.25
,823.11
TV nn /
L \-LJU 1
4.65
,467.60
4.79
4.51
26.19
3,580
3,418
96
17
31
22
.03
.87
.73
.71
.34
.45
568.00
89.70
78.04
112.37
30.99
28.56
0.
0.
4,400.39
4,150.95
102.90
16.24
17.04
17.99
0.995
1.000 2378-TCDD AN
1.010
1.019
1.031
1.042
1.048
1.054
1.067
911-1.089
0.000
0.852
0.863
0.869
0.877
0.924
0.935
1.001 37C1-TCDD SUR1
1.012
1.016
1.024
1.039
1.046
1.059
1.062
1.062
1.065
1.072
911-1.089
0.000
0.990 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.019
1.039
1.045
1.059
1.065
1.076
P&C DP F*o 1 1 ows —
898
.62
0.
568.98
906-1.077
0.000
0.913
0.930
0.935
0.943
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Caroina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page No.
10/23/97
Listing of U973258B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
A
M
340-342
13C12-P6CDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
DC SN 24:52
25:09
25:19
25:30
25:45
25:58
26:12
26:17
26:28
26:37
27 : 06
27:15
27:35
DC SN 27:42
DC SN 28:00
28:09
14 Peaks
DC NL 0:00
25:19
DC SN 25:53
26:16
26:36
DC SN 26:46
27:05
DC SN 27:25
DC SN 27:41
DC SN 28:08
4 Peaks
DC NL 0:00
25:28
26:00
26:17
26:26
26:39
26:50
26:56
27:09
27:18
27:29
27:39
27:59
DC WH 28:12
12 Peaks
DC NL 0:00
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
1
RO
3.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
99
53
53 3,
58
51
61 1,
38
47
58
49
54
50
28
41
02
49
11,
3.49
744.06
638.16
790.08
397.26
196.37
276.00
678.00
534.92
670.53
741.14
574.00
80.83
15.61
11.38
59.02
847.97
450
2,198
483
239
737
160
404
327
401
449
344
49
35
.23
.98
.91
.12
.82
.00
.00
.30
.61
.02
.77
.13
.36
293
1,439
306
158
458
116
274
207
268
292
229
38
23
.32-1.78
1.
1.
1.
1.
1.
0.
1.
0.
4.
0.
08
50
66
51 6,
23
54
48 6,
55
40
50
13,
1.83
126.98
30.07
879.94
86.19
9.30
377 . 82
18.52
15.63
15.89
470.93
t**f*no I
.32-1.78
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
30
92
70
53
49
50
46
50
39
05
68
96
84
95
1,
2.43
485.32
60.81
368.66
97.67
281.41
55.30
103.50
107.42
51.66
94.24
46.51
45.65
2.70
798.15
76
4,137
52
3,803
.23
.36
.39
.77
50
2,742
42
2,574
.83
.18
.17
.14
.55
.00
.00
.62
.92
.12
.23
.26
.66
0.
.75
.58
.53
.05
0.947
0.957
0.964
0.971
0.980
0.989
0.997
1.001 12378-PeCDF
1.008
1.013
1.032 23478-PeCDF
1.037
1.050
1.055
1.066
1.072
848-1.152
0.000
0.964
0.985
1.000 13C12-PeCDF
1.013
1.019
1.031 13C12-PeCDF
1.044
1.054
1.071
AN
AN
123 IS2
234 SUR2
295
38
223
58
168
32
62
62
31
59
35
32
.00
.28
.06
.47
.91
.85
.08
.45
.40
.13
.80
.85
321
22
145
39
112
22
41
44
29
35
18
17
.32-1.78
1.
07
1.32
0.
.84
.53
.60
.20
.50
.45
.42
.97
.92
.11
.24
.90
0.
921-1.025
0.000
0.927
0.947
0.957
0.962
0.970
0.977
0.981
0.988
0.994
1.001 12378-PeCDD
1.007
1.019
1.027
855-1.145
0.000
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:1 3 10/23/97
-------
Page No. 4
10/23/97
Compound/
M_Z.... QC.tog Omit Why
Listing of U973258B.dbf
Matched GC Peaks / Ratio / Ret. Time
. RT. OK Ratio Total.Area Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
K
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
K
DC SN 26:17
DC SN 26:25
DC SN 26:47
27:28
27:38
DC SN 27:58
DC SN 28:11
DC SN 28:19
DC SN 28:28
2 Peaks
1
1
1
1
1
1
RO 7
1
1
.71
.38
.42
.44 4
.44
.38
.43
.32
.57
4
1.05-1.43
DC NL 0:00
29:06
29:15
29:25
29:34
29:45
DC SN 29:56
30:08
30:14
30:22
30:34
30:46
DC SN 31:31
31:36
11 Peaks
1
1
1
1
1
RO 1
1
1
1
1
1
1
RO 1
RO 1
.11
.25
.23
.16
.39
.01
.25
.32
.36
.42
.41
.27
.47
.53
1
8.48
6.77
2.35
,005.78
420.09
27.02
8.03
24.22
17.31
,425.87
11.73
159.87
537.06
66.70
76.45
34.94
6.11
334.38
189.25
41.57
88.22
107.22
8.29
21.24
,656.90
2,361
248
.06
.08
1,644
172
.72
.01
0.
0.
0.
1.
1.
1.
1.
1.
1.
957
962
975
000 13C12-PeCDD 123
006
018
026
031
036
I S3
88
296
35
44
19
190
109
24
51
59
14
.97
.33
.79
.43
.34
.17
.06
.36
.62
.94
.47
70
240
30
32
19
144
80
17
36
47
9
0.43-0.59
DC NL 0:00
30:08
30:14
30:46
31:30
4 Peaks
RO 0
0
0
0
0
.41
.51 6
.51 7
.50 6
.50 5
25
KW«M. 1
1.05-1.43
DC NL 0:00
29:39
30:08
DC SN 30:14
30:22
DC SN 30:32
DC SN 30:40
DC SN 30:46
30:55
31:00
DC SN 31:04
RO 0
1
1
RO 0
RO 1
1
1
RO 1
1
RO 0
RO 2
.62
.05
.24
.87
.44
.30
.40
.60
.23
.93
.49
88.26
,342.46
,074.93
,744.22
,717.46
,879.07
3.32
49.79
129.21
7.57
84.96
14.90
3.00
8.04
21.35
25.27
1.55
2,136
2,377
2,261
1,906
.79
.66
.64
.91
4,205
4,697
4,482
3,810
0.
.90
.73
.91
.02
.11
.21
.19
.21
958-1.051
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
.60 1.
.28
.48
0.
.67
.27
.58
.55
1.
1.
1.
000
963
967
973
978
984
990
997 123478-HxCDF
000 123678-HxCDF
004
Oil
018 234678-HxCDF
042 123789-HxCDF
045
AN
AN
AN
AN
868-1.132
0.
0.
1.
1.
1.
000
997 13C12-HXCDF 478
000 13C12-HXCDF 678
018 13C12-HXCDF 234
042 13C12-HXCDF 789
SUR3
IS4
ALT2
ALT1
25
71
54
11
13
.48
.49
.66
.76
.99
24
57
37
9
14
0.
.31
.72
.93
.59
.98
952-1.015
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
957
973
976
980
985
990
993
998 123478-HxCDD
001 123678-HxCDD
003
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:13 10/23/97
-------
Page No.
10/23/97
Listing of 0973258B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
M
K
K
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
MX
M
424-426
13C12-HpCDD
436-438
31:18 1.32
6 Peaks
1.05-1.43
DC NL 0:00 RO 0.68
DC SN 30:21 1.21
30:54 1.22 4
30:59 1.21 5
31:08 1.07
31:17 1.20 5
31:33 1.28
31:35 RO 0.70
DC SN 31:37 RO 4.61
6 Peaks 15
0.88-1.20
DC NL 0:00 RO 1.48
33:02 RO 1.22
33:16 1.02
33:23 0.94
DC SN 34:15 RO 0.77
DC SN 34:22 RO 1.77
DC WH 34:38 RO 1.62
3 Peaks
0.37-0.51
DC NL 0:00 RO 0.65
33:01 0.38 3
33:13 RO 1.20
34:14 0.38 3
DC SN 34:26 RO 0.09
3 Peaks 6
0.88-1.20
DC NL 0:00 RO 1.24
33:17 RO 0.83
DC SN 33:31 RO 1.84
33:54 1.08
DC WH 34:11 RO 2.95
DC WH 34:15 RO 1.40
DC WH 34:21 RO 2.76
2 Peaks
0.88-1.20
DC NL 0:00 1.20
DC SN 33:17 1.09
33:54 1.04 5
34:16 RO 1.43
44.49 25.29
355.07
3.65
24.85
,662.16 2,562.36
,253.10 2,878.93
109.84 56.67
,802.06 3,160.17
44.18 24.79
24.84 13.75
25.92
,896.18
HxCDD / HpCDF Follows ~**
5.41
86.70 51.70
23.50 11.84
20.19 9.79
13.16
4.57
2.88
130.39
14.73
,390.65 938.25
27.85 23.29
,017.10 834.73
20.98
,435.60
3.00
17.18 8.76
1.69
24.80 12.90
1.67
7.06
1.94
41.98
12.35
19.21
,057.51 2,582.80
51.88 36.32
19.20 1.010 123789-HXCDD
0.968-1.032
0.000
0.980
2,099.80 0.997 13C12-HXCDD 478
2,374.17 1.000 13C12-HXCDD 678
53.17 1.005
2,641.89 1.010 13C12-HXCDD 789
19.39 1.018
19.58 1.019
1.020
0.996-1.043
0.000
42.50 1.001 1234678-HpCDF
11.66 1.008
10.40 1.011
1.037 1234789-HpCDF
1.041
1.049
0.939-1.121
0.000
2,452.40 1.000 13C12-HpCDF 678
19.34 1.006
2,182.37 1.037 13C12-HpCDF 789
1.043
0.977-1.005
0.000
10.50 0.982
0.989
11.90 1.000 1234678-HpCDD
1.008
1.010
1.013
0.971-1.029
0.000
0.982
2,474.71 1.000 13C12-HpCDD 678
25.43 1.011
AN
SUR4
IS5
RS2
AN
AN
IS6
SUR5
AN
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:13 10/23/97
-------
Page No. 6 Listing of U973258B.dbf
10/23/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name. . ID.. Flags.
436-438 2 Peaks 5,109.39
Above: !$>CDD / Octa-CDD and CDF Follows
OCDF 0.76-1.02 0.890-1.110
442-444 DC NL 0:00 0.91 5.82 0.000
DC SN 34:43 RO 0.27 2.68 0.953
DC SN 34:49 RO 1.36 6.50 0.956
DC SN 36:20 RO 1.03 2.85 0.997
MK 36:33 RO 0.73 11.66 5.49 7.51 1.003 OCDF AN
DC SN 36:50 RO 1.92 3.12 1.011
DC SN 36:57 RO 1.18 4.27 1.014
DC SN 37:49 RO 2.46 2.06 1.038
DC SN 37:54 RO 1.33 1.25 1.040
DC SN 38:11 RO 1.51 4.69 1.048
442-444 1 Peak 11.66
OCDD 0.76-1.02 0.890-1.110
458-460 DC NL 0:00 RO 1.86 2.38 0.000
MK 36:27 0.88 22.80 10.70 12.10 1.000 OCDD AN
DC SN 36:36 RO 0.37 0.85 1.005
DC SN 36:38 RO 0.34 0.81 1.005
DC SN 36:40 RO 0.36 4.03 1.006
458-460 1 Peak 22.80
13C12-OCDD 0.76-1.02 0.995-1.005
470-472 DC NL 0:00 0.95 1.97 0.000
36:26 0.87 5,622.50 2,617.42 3,005.08 1.000 13C12-OCDD IS8
DC WH 36:52 RO 1.81 36.19 1.012
470-472 1 Peak 5,622.50
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
. .RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Feak Deleted
OK -RO=Ratio Outside Limits
-------
Plla, 0973258 #1-1024 Acgt 17-OCT-1997 15*30*11 OC SI+ Voltage SIR
319.8965 P,2 BSUB(256r 30, -3.0) PXD(7, 5, 3,0. 101,4920. 0,1.001,P,T)
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327.8847 7*2 BSUB (256, 30 f -3.0) PXO(7, 5.3,0. 101,4088. 0,1.001,P,T)
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330.9792 Pt2 Sxp:BPCVS2
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409.7974 Pl2 ExpiSPCUS2
TRIASOLB LABS TtactiSO-H23-l TLI#43432
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355.8S46 Pl2 BSUB(256,30,-3.0) PXD(5, 5,3,0. 05*,2964. 0,1. 00*,P,T) ExpiSPCUS2
TRIANGLE LABS T«3CttSO-M23-l TLI843432
1009
80.
60.
40.
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0
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A1.69E6
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1 I JL3.83E5 T "A. / I A A*3.1377
369.8919 P:2 BSOB(256,30,-3.0) Pn>(S,5,3,0.05*,1508.Q,1.00*,?,T) ExpiBPCVS2
TRIAttOLB LABS TfXttSO-IOS-l TLI043432
1009
80_
60.
40.
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A1.64S7
/ ]A1.72S6 _
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330.9792 Pi 2 SxptSPCUS2
TRIASQLS LABS T»xttSO-M23-l TLI043432
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80.
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25t32 25t48 26t02 26:29 26i45 ni.nt 27*27 27tSl in, no
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373.8208 Pl3 BSVB(256,30,-3.0) PKD(7,5,3,0.10X,12344.0,1.00\,B,T) ExptEPCUSl
TRIANGLE LABS TexttSO-H23-l TLI#43432
1009
80:
60:
40:
20:
A2.96E6
A1.90E6
AA5.99ES
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29*00 30*00 31»00
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32*00 Wm»
Pil»tU97325B #1-404 Acqi 17 -OCT- 1997 15.30.11 OC EH- Voltage SIR 70S Nola»i2779
375.8178 Pt3 BSUB(256,30,-3.0) PXD(7,S.3,0.10*,11116.0,1.00*,F,T) BxptBPCUS2
TRIANGLE LABS Te3CttSO-M23-l TLI#43432
1009
80:
60:
40:
20.
A2.41E6
A
1 \ A1.44E6
A7 09 J h
A / 1 A3.20E5 /\A ai...*1^"
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25 » 00 30.00 ' 31.00
_8.UBS
-6.5E5
-.4.9E5
13.255
'.1.6ES
• O.OEO
32*00 Time
PlletU97325a #1-404 Acqi 17 -OCT- 1997 16t30tll OC EH- Voltage SIR 70S Solmetl4906
383.8639 Pt3 BSOB(256,30,-3.0) PKD(7,5,3, 0.10X,59624.0,1.00*,P,T) ExptSPCVS2
TRIANGLE LABS TextiSO-lO3-l TLIK43432
1003
80:
60:
40:
20:
A2.38E7 A2.26E7
A II
A ft I
1 V V I V /
29.00 30*00 ' 31.00
91E7
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.0.455
.5. 755
.5.055
13.455
11.755
32*00 Tinw
Pll»tU9732S8 #1-404 Acqtl7-OCT-1997 16t30tll OC EH- Voltage SIR 70S Hoiaei36735
385.8610 P:3 B3VB(256,30,-3.0) PKD(7,5,3,0.10*, 146940.0,1.00X,P,T) BxptBPCUS2
TRIANGLE LABS Te3ftiSO-H23-l TLI»43432
1009
80:
60:
40:
20:
A4.70S7 A4 48S7
I
y V V / I j
29\00 30.00 31.00
PiletU9732S8 #1-404 Acqi 17-OCT-1997 15.30*11 OC Eli- Voltage SIR 70S
392.9760 Pt3 B*ptSPCUS2
TRIANGLE LABS Te3ttiSO-H23-l TLH43432
10091
80.
60.
40.
20.
0.
-1.6B7
0157
1
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Ll.357
19.055
15.555
13.355
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29.13 29.25 29*44 30*11 30J33 30»5<32/M 31.1931*30 31.57
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29.00 30*00 ' 31.00
P119IU973258 #1-404 Acqt 17-OCT-1997 16t30tll OC EI+ Voltage SIR 70S
445.7555 Pt3 ExpiSPCVS2
TRIANGLE LABS Texti3O-M23-l TLI#43432
lOOJj
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60.
40.
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0.
-2.355
11.955
Ll.455
19.355
14.555
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32.00 ^2.9*4
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29*00 30.00 ' 31.00 ^
L2.354
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11.254
15.853
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-------
'il«iU97335B ti-404 Xcqil7-6cr-1997 16i30:ll vn// \*sS*Z: ~ w^yV \ys__
A3.53ES
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80.
60.
40.
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29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24
Pil»,U97325B tl-404 Acq: 17-OCT-1997 16:30:11 OC EH- Voltagt SIS 70S Noia»:1477
403.8539 Pi3 BSUB(256,30,-3.0) PKD(7,5,3,0.10X,5908.0,1.00X,P,T) ExptEPCUSS
TRIAHOLE LABS TncttSO-tO3-l TLHt43432
100* A2.37E7 A3.64E7
31:36
80.
60.
40.
30.
A3.10.
29:36 29:48 30*00 30*12 30:24 30:36 30:48 31:00
Pll»iU973358 tl-404 Acyil7-OCT-1997 16:30:11 OC EH- Voltag* SIS 70S
393.9760 Pi 3 SxptSPCUS3
TRIANOLf LABS T*xt:SO-H23-l 911*43433
lOOh
31:12 31:24
31:36
.3.5E5
'.3. OSS
.1.5E5
.9.9S4
.4.9E4
O.OEO
Time
Tim*
1.1B7
8.7E6
6.SB6
4.3E6
3.2E6
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7.1E6
5.3E6
3.6E6
1.8E6
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60.
40.
30.
0.
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29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36
.2.3E6
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.1.4S6
.9.3S5
.4.6E5
O.OEO
Time
-------
FlletU97325B #1-596 Acy: 17-OCT-1997 15(30(11 CC EH- Voltage
SIS 70S Noiaotl96S
407.7818 Pt4 BSUB(256,30,-3.0) PXD{7,5,3,0.10*,7860.0r1.00*,P,T) ExpiEPCUS2
TRIANOLE LABS Text t SO-M23-1 1X1*43432
iota
aoj
60:
40:
20:
72ES
\ A1.18E5
V_^y\/A^^_ ^ ^^
33(00 33 (12 33(24 33:35 33(48 34(00
FiletU9732S8 tl-596 Acqil7-OCt-1997 15(30(11 OC EH- Voltage
1.4ES
A6. 71E4
AA3.96E4 A2.97S4
.1.1BS
.B.3S4
.5.5S4
.2.8E4
'O. OEO
34(12 34(24 34(35 Time
SIR 70S Noise t 1324
409.7789 Pt4 B3U3(256,30, -3.0) PXD(7,5,3f0.10*,5296.0,1.00*,P,T) Exp:EPCU32
TRIASOLE LABS Text:SO-K23-l 1XZ*43432
IOCS
so:
60:
40:
20:
a4.(fS5
l\
1 \ A1.04S5
/ \ r\ f\
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33(00 33(12 33(24 33(35 33(48 34(00
PlletU9732S8 tl-596 Acqt 17-OCT-1997 15(30(11 OC 2T+ Voltage
-1.3E5
A8.74E4
?.57S4_yr/^\A2^24£4 A1.41S4 ^
.1.1S5
_8.1E4
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_2.7B4
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'34il2' ' '34(24' ' '34(35' ' ' ' Tiu»
SIR 70S Soifet3300
417.8253 Pl4 BSUB(2S6,30, -3.0) PXD(7,5,3,0.10*,13200.0,1.00*,g.T) BxptEPCOS2
TRIANGLE LABS Text i SO-H23-1 1X1*43432
100S
SO:
50:
40:
20:
A9.38S6
I
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/ I
J V
33.00 33*: 12 33:24 33(35 33(48 34(00
Pil»:U973258 tl-596 Acqt 17 -OCT- 1997 15(30(11 OC BI+ Voltage
..3.5E6
A8.35E6
:
-
.2.855
12.125
•.1.4B6
.6.9BS
34(12 34(24 34(35 Time
SIR 70S Holme t 5114
419.8220 Pi4 BSUB(256,30,-3.0) PXD(7,S,3r0.10*,20456.0,1.00*,P,T) BxptBPOJS2
TRIANOLB LABS Text:3O-H23-l 1X1*43432
1004
aoj
60:
40:
20-.
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A2.4SE7
R
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/ \
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33(00 33(12 33(24 33(35 33(48 34(00
FlletU9732SB tl-596 Acyt 17-OCT-1997 15(30(11 OC 2T+ Voltage
430.9729 Pt4 BxptSPCVSl
TRIANOLB LABS TmxttSO-H23-l 1X7*43432
IOCS
30:
60:
40.
20.
0.
33lai 33(54
-.^VA jfc^ A^«w* Jv*»v >^«% yVXV A A & ^»A ^« *As+S "\ *^ AA
^***~^*Tll*J^^f'^S~\fS v'X/V/\>i/<-^__/\/^/> \/~"*' \^VV^
'33(00 33(12 33(24 33(35 ' '33(48' ' '34(00
PiletU9732S8 tl-596 Acy: 17-OCT-1997 15(30(11 OC EI+ Voltage
479.7165 7(4 Brp:BPCUS2
TRIANQLB LABS T*xt:SO-H23-l 1X1*43432
1009
80.
50.
40.
20.
0.
1
33 liO A i *
* A 33 1 27 H *3Q • A 1 1 A A
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33(00 33(12 33(24 33(35 33(48 34(00
^9.0*6
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15.425
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34(12 34(24 34(35 Time
SIR 70S
/^-^/ V\/\/ -""V/Vv/Ny V/V^/^' N
-1.225
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34(12 34(24 34(35 Time
SIR 70S
34ilO , r2.8*4
A
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15.523
0.020
34(12 34(24' ' '34(35' ' ' ' Tin*
-------
P11«*097325B #1-595 Acq,17-(7,S,3,0.10*,2940.0,1.00\,P,T) EXp,BPCUS2
TRIANOLB LABS T«rt»SO-M23-l TLU43432
1009k A1.28ES
33:12 33*18 33*24 33*30 33*36 33*42 33*48 33*54 34*00 34*06 34*12
Pllm*U973258 #1-596 Acy:17-OCT-1997 16*30*11 OC ET+ Voltage SIR 70S Nolso:3365
435.8169 P:4 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10*,13460.0,1.00*,P,T) Exp:BPCU32
TRIANGLE LABS Tucti3O-K23-l TLU43432
A2-SBE7
so:
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40.
20:
A1.23E5
A3.28S3 A1.S7B4
0.050
'34', 24 Timo
-S.1E4
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.2.1B4
.1.0E4
,0.050
eo:
6
-------
PilatU9732$8 #1-596 Aaqi 17-OCT-1997 16i30tll OC EH- Voltaffo SIR 70S Noist:1390
441.7428 Pl4 BSUB(256,30,-3.0) PKD(7,5,3,0.10X,5560.0,1.00\,P,T) ExptSPCUS2
TRIANGLE LABS T0JCt:SO-M23-l TLI#43432
33(00 34/00 35(00 3ff«00 37(00 30(00 35(00
Fll»:U9732S8 #1-596 Acqt 17-OCT-1997 16t30>ll OC EH- Voltag* SIR 70S Noil*11519
443.7399 Pt4 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,6076.0.1.00*,P,T) Exp:EPCUS2
TRIANGLE LABS T»3ftiSO~H23-l TLX143432
Tim*
33(00 34>00 35(00 36:00 37(00 30(00
Pll»iU973258 #1-596 Aaqt 17-OCT-1997 16i30tll OC Elf Voltafo SIR 70S
430.9729 Pt4 Exp:EPCUS2'
TRIANGLE LABS T*Xt:SO-K23-l TLI943432
100H 33(31 35(00
. I 33iS4 I.I , 36il3
90l
sol
70\
6ol
sol
40.
30J
201
101
39:00
Timm
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33tOO 34:00 35tOO 36:00 37:00 38;00
P11»:U9732S8 #1-596 Acqtl7-OCT-1997 16:30:11 OC Sit Voltaya SIR 70S
513.6775 Pi4 Sxp:SPCUS2
TRIANOLE LABS T»Xt:3O-U23-l fLI#43432
39100
Tim*
IOCS
30-
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70.
601
50J
40.
30.
20.
10.
0:
37
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33:38
33119
34:27
35t5.
96:51
40
39108
38109
38(50
33100
34100
35*00
36:00
37(00
30(00
39100
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.9.6X3
.6.4X3
.3.2X3
.0.0X0
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-------
'11«,U97325B #1-596 Acgil7-6fflP-lJJ7 16i30ill OS El* Voltage SIR 703 Nbis»tll70
57.7377 Pt4 BSUB(2S6,30,-3.0) PE3(7,5,3, 0.10*, 4680.0,1.OOX,P,T) ExptEPCUS2
TRIANGLE LASS TextiSO-H23-l TLI043432
100* ALICES
36il8 36i24 36t30 36t36 36t42 36i48
'11»:U973258 01-596 Aeqtl7-OCT-1997 16t30tll OC BH- Voltafff SIR 70S NolB»,631
459.7348 Pt4 BSUB(2S6,30,-3.0) PKD(7, 5,3.0.10\,2524.0,1.00\,P,T) Exp:EPCUS2
TRIANGLE LABS TfXtiSO-H23-l TLIX43432
1009k Al.fSES
80.
60.
40.
20.
36tl8 36,24 36i30 36t36 36:42 <.36t49
fil»tU97325B 01-596 Acq:17-OCT-1997 16i30tll OC SH- Volt ago SIR 70S Nolaet479
469.7779 f>4 BSOB(2S6,30,-3.0) PKD<7,S,3,0.10*,1916.0,1.00*,P,T) BatptBPCUS2
TRIAKOLB liABS TfXttSO-M23-l 71,1*43432
100H A2.62B7
80.
60.
40.
20.
361 IB 36t24 36,30 36,36 36,42 36,46
Pil»tU973258 01-596 Acytl7-OCT-1997 16,30,11 OC BI+ Voltafff SIR 70S BoimatSOS
471.7750 Pt4 BSUB(256,30,-3.0) PXD(7,5,3.0.10*,202Q.O,1.00*,f.T) Exp,EPCUS2
TRIANOLE LASS T*xt,SO-H23-l TZiI*43432
100H A3.01S7
80.
60.
40.
20.
36,18 36,24 36t30 36,36 36,42
Pll»,U973258 01-596 Acqi 17-OCT-1997 16,30,11 OC BH- Voltagm SIR 70S
430.9729 fi4 B*piBPCUS2
TRIANGLE LABS T9XttSO-H23-l TLI043432
'36,48
10(9
80.
60.
40.
20.
36,23
36142
36,18
36:24
36,36
36142
•:36],48
36,54
36154
36:54
36:54
36153
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.4.7E4
.3.8S4
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.1.9B4
.9.4E3
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'.5. OB6
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.1.7E6
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-9.7E6
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-------
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Peak Locate Examination:17-OCT-1997:16:28 File:U973258
-------
File:U973258 ttl-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A4.30E6
80 j
60 j
40J
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22:00 23:00 24:00
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A5.68E6
22:00 23100 24iOO
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 22:1522;28
80 j
60 j
40 J
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-------
File:U973258 #1-1024 Acq: 17-OCT-1997 16:30:11 GC EI+ Voltage SIR
319.8965 F:2 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text : TRIANGLE LABORATORIES,
100%
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File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EH- Voltage SIR
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES,
100%
80 j
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File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES,
100% 22:15 22; 28
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22:00
23:00
24:00
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4.5E6
3.0E6
1.5E6
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Time
r-
-------
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
80 j
60 j
40 J
20 j
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16,
25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
80 J
60J
40 j
20J
28:00 28:12
7
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File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 26;16 27-05
80 j
60 j
40 J
20J
_7
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25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12
27:24 27:36 27:48 28:00 28:12
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Time
OO
-------
05
oo
File;U973258 #1-1024 Acq;17-OCT-1997 16;30ill GC EI+ Voltage SIR 703
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A4.04E6
80-
60J
40J
201
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25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36
File:U973258 f1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A2.74E6
80J
60 J
40J
20J
2748
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28!66 ' 28!l2
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File:U973258 ttl-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 26;16 27:05
601
40 j
20 j
27:48 28:00 28:12
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25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28
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-------
File:U973258 #1-404 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i i i i i i i i iii
30154 31:00 31:06 31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06
File:U973258 #1-404 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 31;35
100%
80J
601
40J
20J
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31:36
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5.8E4
4.4E4
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File:U973258 #1-404 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 31j30
80 j
60 J
40 j
20 j
30:54 31:00 31:06 31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06
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-------
File:U973258 #1-404 Acq:17-OCT-1997 16:30
389.8156 F:3 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text
lOOi A1.34E5
80J
601
40 j
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:TRIANGLE LABORATORIES, INC.
OJ
30:36 30:48 31:00
File:U973258 #1-404 Acq:17-OCT-1997 16:30
391.8127 F:3 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text
100% A1.47E5
31:12 31:24 31:36
11 GC EI+ Voltage SIR 70S
: TRIANGLE LABORATORIES, INC.
31:48
30:36 30:48 31:00
File:U973258 #1-404 Acg:17-OCT-1997 16:30
401.8558 F:3 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text
1002s. 30:59
30:54
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31:12 31:24 31:36
ill GC EI+ Voltage SIR 70S
.TRIANGLE LABORATORIES, INC.
31:17
31:48
30:36
30:48
31:00
31:12
31:24
31:36
31:48
32
7.2E4
L5.8E4
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32
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-------
CM
cn
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS2
Sample Text :SO-M23-1 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
100%
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40j
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33:16
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File:U973258 #1-596 Acq: 17 -OCT- 19 97 16:30:11 GC EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS2
Sample Text :SO-M23-1 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
100%
•
80j
60 J
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File:U973258 #1-596 Acq: 17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS2
Sample Text :SO-M23-1 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
100%
80 J
60 j
40J
20J
0:
34:14
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-------
File:U973258 #1-596 Acq:17-OCT-1997 16:30
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLItt43432 File Text
100% A5.17E5
80 j
60 J
40 j
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:11 GC EI+ Voltage SIR 70S—
•
:TRIANGLE LABORATORIES, INC.
_1.5E5
L1.2E5
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32:24 32:36 32:48 33:00 33:12 33:24
File:U973258 #1-596 Acq:17-OCT-1997 16:30:
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:
100% A4 25E5
80 j
60J
40 j
20 j
OJ
33:36 33:48 34:00 34:12
11 GC EI+ Voltage SIR 70S
TRIANGLE LABORATORIES, INC.
34:24 34:36 34:48 Time
1.5E5
L1.2E5
L8.9E4
L5.9E4
L3.OE4
O.OEO
32:24 32:36 32:48 33:00 33:12 33:24
File:U973258 #1-596 Acq:17-OCT-1997 16:30:
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:
100% 33;01
80 j
60 j
40 J
201
OJ
33:36 33:48 34:00 34:12
11 GC EI+ Voltage SIR 70S
TRIANGLE LABORATORIES, INC.
34:14
34:24 34:36 34:48 Time
3.5E6
L2.8E6
L2.1E6
L1.4E6
L7.0E5
.32:24 32:36 32:48 33:00 33:12 33:24
-------
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% A1.29E5
80 J
60J
40.:
20J
33:00 34:00 35:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% A1.19E5
80J
60J
40 J
20J
0
36:00
33:00 34:00 35:00
File:U973258 #1-596 Acq: 17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text : TRIANGLE LABORATORIES, INC,
100% 33,- 54
80 J
60J
40 j
36:00
OJ
5.9E4
4.7E4
3.5E4
2.3E4
1.2E4
O.OEO
Time
6.4E4
5.1E4
3.8E4
2.6E4
.1.3E4
.O.OEO
Time
33:00
34:00
35:00
36:00
.8.9E6
.7.1E6
.5.4E6
.3.6E6
.1.8E6
.O.OEO
-------
in
File:U973258 ttl-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100*
80J A8.76E4
60 j
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33:00 34:00 35:00
File:U973258 tl-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100&
80j A1.05E5
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File:U973258 #1-596 Acg:17-OCT-1997 16:30:11 GC EH- Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 33.54
80J
60J
40J
20 j
0
36:00
36:00
.5.9E4
.4.7E4
.3 . 5E4
.2.3E4
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Time
.6.4E4
.5. 1E4
.3.8E4
.2. 6E4
.1.3E4
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Time
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34:00
35:00
36:00
.8.9E6
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5.4E6
.3.6E6
.1.8E6
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-------
CD
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EH- Voltage SIR 70S
441.7428 F:4 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36:33
36:00 37:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% 36:33
36:00 37100
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-l TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% 36;26
80 j
60 j
20j
OJ
O.OEO
Time
36:00
37:00
O.OEO
Time
8.4E6
6.7E6
5.0E6
3.3E6
1.7E6
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-------
File;U973258 #1-596 Acq;17-OCT-1997 16;30;11 GC EH- Voltage SIR 70S
441.7428 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% A5.49E4
80 j
60 j
40J
20 j
36:00 37:00
File:U973258 #1-596 Acq: 17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% A7.51E4
36:00 37:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% 36;26
80 j
60 j
40J
20 j
36:00
37:00
.3.7E4
.3.0E4
.2.2E4
1.5E4
.7.4E3
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Time
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Time
8.4E6
.6.7E6
.5.0E6
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.1.7E6
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-------
File:U973258 #1-596 Acq:17-OCT-1997 16:30
457.7377 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text
100% A1.Q7E5
:11 GC EI+ Voltage SIR 70S
:TRIANGLE LABORATORIES, INC.
37:00 38:00
GC EI+ Voltage SIR 70S
0
36:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30
459.7348 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% A1.21E5
80 J
60 j
40 j
20J
37:00 38:00
GC EI+ Voltage SIR 70S
36:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-1 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36;26
80 j
60 J
40 J
20 J
OJ
39:00
39:00
.O.OEO
Time
6.0E4
L4.8E4
L3.6E4
L2.4E4
L1.2E4
O.OEO
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_8.4E6
L6.7E6
L5.0E6
L3.3E6
L1.7E6
36:00
37:00
38:00
39:00
E.O.OEO
-------
TLI Project:
Client Sample
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
^^#*-JE£
43432
: SO-23-1
Saginaw, MI
M23TRAIN
185-6-1A-D
1.000
n/a
DB-225
es^> ,^51^r ,:t :^v
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973636
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/18/97
Dilution Factor: n/a
Blank File: U973257
Analyst: WK
Spike File: SPC2NF04
ICal: XF24087
ConCal: X973633
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
Analyse _:t' /^7,-r : Att^Ctt^lt **r , "$&*&-' ^; ^i*%?;^V^*ki^:
2,3,7,8-TCDF
Internal Startdaitl
13Cl2-2,3,7,8-TCDF
Recovery Stancfan
-% ,;, ^v^'^Ari
* ^*v>' "
0.72
si C«rf^%^»ec<^f^Llmtts
3.8 95.4 40%-130%
^v * <** %?l *$ '^-^
t v*v"' s ^y. •• ,,,;^xx^ c " ? \
0.81 24:33
'» ^v^f^\^^ ?:m&}
0.81 24:32
- ^«atlaJ^^^S^^s
13C,2-1,2,3,4-TCDD
0.85 23:20
Data Reviewer.
10/23/97
Page 1 of 1
C2NFJ>SR vIOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:34 10/23/97
-------
Data Review By:
Initial Date...
_\U_, s,^
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of X973636B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total. Area... Area.Peak.1.. Area. Peak. 2.. Rel.RT Compound. Name.. ID.. Flags.
TCDF
304-306 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
304-306
13C12-TCDF
316-318 DC
DC
0.65-0.89
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
24
0:00
19:46
19:59
20:02
20:47
20:55
21:04
21:14
21:22
21:30
21:40
21:49
21:59
22:08
22:15
22:31
22:37
22:45
23:01
23:08
23:16
23:32
23:46
23:57
24:25
24:33
24:48
25:09
25:18
25:41
26:14
26:34
26:44
26:47
26:52
26:57
27:01
27:07
Peaks
0
0
0
0
0
0
0
0
RO 1
0
0
0
0
0
RO 2
0
0
RO 1
0
RO 0
0
0
0
0
0
0
0
0
0
RO 1
0
0
0
0
RO 0
RO 2
0
0
.70
.88
.78
.84
.81
.78
.80
.79
.20
.79
.78
.77
.82
.77
.77
.88
.68
.22
.82
.95
.80
.80
.80
.80
.73
.81
.80
.81
.80
.04
.82
.81
.74
.75
.95
.08
.84
.65
1,
2,
1,
2,
1,
1,
1,
3,
1.
2,
1,
1,
1,
1,
1,
1,
1,
1.
1,
34,
18.97
726.96
6.73
16.96
571.89
470.27
126.51
549.13
29.81
097.19
646.18
746.28
844.10
090.97
5.58
199.30
490.17
20.73
705.74
267.71
555.01
651.14
200.92
203.24
066.83
157.80
038.14
938.20
785.89
5.54
789.84
5.38
4.69
6.17
7.49
4.14
9.04
106.01
919.41
809
1,153
643
942
683
483
723
325
1,733
474
1,027
602
767
142
689
735
89
536
449
517
461
420
791
355
.44
.29
.09
.10
.08
.64
.37
.00
.01
.33
.79
.04
.88
.99
.42
.20
.41
.12
.75
.91
.91
.59
.16
.86
917
1,418
827
1,184
866
613
922
421
2,111
616
1,171
888
937
151
865
915
111
667
617
639
576
517
994
433
0.65-0.89
NL
WL
0:00
19:56
RO 0
RO 1
.63
.21
15.59
12.92
0.798-1.112
.52
.60
.18
.41
.05
.55
.81
.28
.09
.64
.51
.13
.86
.25
.59
.94
.51
.12
.08
.89
.23
.61
.73
.98
0.000
0.806
0.815
0.817
0.847
0.853
0.859
0.865
0.871
0.876
0.883
0.889
0.896
0.902
0.907
0.918
0.922
0.927
0.938
0.943
0.948
0.959
0.969
0.976
0.995
1.001 2378-TCDF
1.011
1.025
1.031
1.047
1.069
1.083
1.090
1.092
1.095
1.099
1.101
1.105
0.959-1.041
0.000
0.813
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
Page No. 2 Listing of X973636B.dbf
10/21/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC WL 20:46 RO 1.04 10.35 0.846
DC ML 22:48 RO 0.57 5.08 0.929
DC WL 22:53 RO 0.54 8.14 0.933
DC WL 23:00 RO 0.62 40.66 0.938
DC WL 23:14 RO 1.16 58.29 0.947
24:32 0.81 6,657.81 2,987.98 3,669.83 1.000 13C12-2378-TCDF ISO
DC WH 26:58 0.65 67.57 1.099
316-318 1 Peak 6,657.81
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.89 0.913-1.087
332-334 DC NL 0:00 RO 2.23 7.26 0.000
DC SN 21:51 RO 0.28 9.63 0.950
DC SN 22:37 RO 1.06 6.28 0.983
DC SN 22:44 RO 2.05 1.40 0.988
23:00 0.79 4,515.84 1,995.41 2,520.43 1.000 13C12-2378-TCDD 131
23:20 0.85 5,011.54 2,301.28 2,710.26 1.014 13C12-1234-TCDD RSI
DC SN 23:58 RO 1.18 8.27 1.042
DC SN 24:05 0.72 71.30 1.047
DC SN 24:34 RO 0.61 4.34 1.068
DC SN 24:45 RO 0.56 7.31 1.076
DC WH 25:12 0.70 11.36 1.096
DC WH 25:18 RO 1.00 8.07 1.100
DC WH 25:22 RO 9.79 1.42 1.103
DC WH 25:27 RO 1.50 8.16 1.107
DC WH 25:55 RO 1.79 3.91 1.127
DC WH 26:01 RO 4.50 2.96 1.131
DC WH 26:08 0.66 26.47 1.136
DC WH 26:12 RO 0.60 13.29 1.139
332-334 2 Peaks 9,527.38
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
'1I»:X973636 91-803 Acqi 1B-OCT-1997 14:45:51
-------
'1101X973636 91-BO3 AcqtlB-OCT-1997 14:45:51 OC EH- VOJ-Cayo SIR Autospac SOlB»i22BB
319.8965 BSUB(256,30,-3.0) PKD(5,3,1,0.10*,9152.0,0.00*,P,P) XjCptXCONP_TT
Saapla Text:SO-M23-l TLI#43432 Pllu TfJCt: JWZAITOLE LABS
100H
80.
21:00 22:00 23:00 24:00 25:00 26:00
PlletX973636 #1-803 Acy: 18-OCT-1997 14:45:51 OC EH- Voltage SIR AutoSpac Holeet2407
321.8936 BSV3(256,30,-3.0) PXO(5,3.1f0.10*,9628.0,0.00*,P,P) XxptXCONP_TT
Saoplt TexttSO-M23-l TUK43432 Pile Text: TRIANGLE LABS
1009
00.
60.
40.
20.
A2.24E6
A1.77E6
1.08E
A1.
A1.29S6
60.
40.
20.
A3.87B6
A2.2SE6
A1.19S6
A2.90B6
A9.12E5
SliOO 22:00 23:00 24:00 25:00
Sil»tX97363S #1-803 Acy: 1B-OCT-1997 14t45<51 OC ET+ Voltay* SIR AutoSpuc Soim»iSB46
327.8847 BSUB(256,30,-3.0) PXD(5,3,1,0.10*,23384.0,0.00*,P,P) Exp:KOllP_TT
Sanpl* TfXt:SO-M23-l TLI143432 film TfXti TRIAKOLS LABS
lOOIf A4.22S7
80.
60.
26:00
40.
20.
AS.03B6
JL9.3BE6
A
21JOO 22:00 23:00 24:00 25:00
Pile :X973 636 il-803 Aeqtl8-OCT-1997 14:45t51 OC XH- Voltage SIR AutoSpoc Noi*»:4563
331.9368 BSOB(256,30,-3.0) PKO(S,3,1,0.10\,182S2.0,0.00*,P,F) Exp:XCOKP_TT
T*Xt:SO-H23-l TLI*43432 Pile Text! TRIABQLB LABS
26 tOO
BO:
eo:
40:
20:
21:00 22tOO 23:00 24:00 25:00
PiletX973636 fl-003 *cq:18-Ocr-1997 14:45:51 OC XI* Voltage SIR AutoSp»c Hoit«t2050
333.9338 BSUB(256,30, -3.0) PXD(S.3,1,Q.10\,B3QO.O,0.00*,P,F) X*ptXCOSP_TT
Saaplf TvrttSO-H23-l TLX#43432 Pile TMctt TRUUtOLf LABS
26:00
BO:
so:
40.
20.
0.
31 tOO
22100
23100
24100
25100
26:00
-1.SB6
.1.2S6
'.B.7S5
.5.ass
.2.9ES
0.080
Tim*
.1.9S6
'.1.5X6
".1.2X6
'.7.7X5
.3.9X5
10.020
Tim*
.1.1*7
.B.BX6
.6.6X6
'.4.4X6
.2.2X6
0.0X0
-.5.7X6
.4.6X6
.3.4X6
.2.3X6
.1.1X6
0.0X0
MUM
.6.8X6
'.5.4X6
.4.1X6
J.7X6
.1.4X6
0.0X0
Tim
-------
FllmiX973636 #1-803 Acqi 18-OCT-1997
303.9016 Exp:XCOKP_TT
Saapla Taxt,SO-M23-l TLI#43432 Pile
20,00 21,00 22,00
Pilo:X973636 #1-803 Acy,lB-OCT-1997
315.9419 ExptXCONFjer
Soaplm Taxt,SO-M23-l TLI#43432 Film
100*
80:
60:
40:
20:
o:
20,00 21,00 22,00
Pila,X973636 #1-803 Aay,18-OCT-1997
319.8965 BxptXCOSP TV
Saaplm Taxt:SO-H23-l TLHM3432 Film
100* 20/35
looa
ao:
60:
40:
20:
20:47
2159
14,45,51 OC EH- Voltage SIR AutoSpac
Taxtt TRIANGLE LABS
II ,23,32 "I18
flA 24/25 A
uuLjiiyi
26:14
A
23/00 24/00 25/00
14/45/51 OC EH- Voltays SIR AutoSpac
26:00
27:00
Ttuctt TRIAKOLB LABS
24,32
23,00 24,00 25,00
14,45,51 OC EH- Voltaga SIR AutoSpac
Taxt: TRIAHOLE LABS
26:00
2TiOO
ao:
60:
40:
20:
0J
21/10
22/37
20/00 21/00 22/00
Pll»:X973636 #1-803 AcyilB-OCT-1997
331.9368 Exp:XCONP_TT
Saapl* Tuct:SO-U23-l TLI#43432 Film
100*
80:
60:
40:
20:
23,00 24,00 25,00
14,45,51 OC EH- Voltaga SIR AutoSpac
Taxt, TRIAKOLB LABS
26:00
27io
20,00 21,00 22,00
Film,X973f36 #1-803 Acq,18-OCT-1997
292.9825 Bxp,XCONF_TT
Saapla Taxt:SO-M23-l TLH43432 Film
2700
ao:
60:
40:
20:
o.
23,00 24,00 25/00 26:00
14,45,51 OC BI+ Voltaga SIR AutoSpac
Taxt, TRIANGLE LABS
_ 23/45 24,19 24,50 26,1726,45
20,00 21,00 22:00
Film,X973636 #1-803 Acy,18-OCT-1997
330.9792 Bxp,XCOSF_TT
Saapla Ta3tt,SO-H23-l TLI#43432 Film
100»
ao:
60:
40:
20:
o:
30,23
23,00 24,00 25,00
14,45,51 OC Eli- Voltaga SIR AutoSpac
Taxt: TRIANOLE LABS
23,21 24,08 IA.A*-,*.,*
26: 00
27:00
.3.6E6
.2.9E6
.2.1B6
.1.4E6
.7.2ES
O.OEO
Tima
6.7S6
.5.4E6
.4.0B6
.2.7B6
.1.3S6
O.OEO
Tima
1.5B6
.1.2E6
.8.BBS
•.S.9B5
.2.9B5
O.OEO
Timm
5.7B6
.4.6B6
.3.4E6
.2.3B6
.1.1E6
O.OEO
Tima
-1.3EB
ll.OBB
'-.7.7E7
.5.2B7
.2.6B7
10. 010
Tima
^6,17 26,47 27/20
,.1.2*8
.9.6E7
.7.2B7
.4.827
.2.457
20(00
21(00
2200
23/00
24(00
25/00
26,00
27 1 00
O.OEO
Tima
-------
Peak Locate Examination:18-OCT-1997:14:45 File:X973636
-------
TO Project: 43432
Client Sample: SO-23-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976909
Client Project:
Sample Matrix:
TLIBD:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-2A-C
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst:
09/29/97
10/09/97
10/23/97
n/a
U973257
GO
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976907
n/a
n/a
n/a
Unaiyik:^^^:?;
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3.6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4,7,8-HxCDF
1,2,3.6.7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3.4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2.3.4,6,7,8,9-OCDF
^TOtalS \?,;1 *?¥?*" :^,VX
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
r^^^Wti^lBgJ-l
0.21
0.23
0.07
0.08
0.11
EMPC
EMPC
6.6
1.4
1.4
0.91
0.46
0.26
EMPC
EMPC
EMPC
0.04
Vv^UatflH^
6.6
2.4
1.1
0.14
60.0
24.2
4.7
0.10
SI^Ut^ViMRC--
0.12
0.09
0.04
0.30
0.05
gj^ber*^^»c \
13
8 3.6
6 1.1
1 0.26
13 60.3
15
11 4.7
1 0.51
vc; "\tlRatfc ,s
0.68
1.54
1.28
1.26
1.18
0.82
1.45
1.40
1.26
1.27
1.25
0.98
,^:\ ,0^^""^
7^?^
21:33
26:06
29:20
29:25
29:42
20:47
24:59
25:44
28:35
28:41
29:12
34:49
%\>;x:^f
^agsV
FR
B_
^PR
vFtogsx;f
—
Page 1 of2
X237.PSR v2.00. LARS & 10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:29 10/24/97
-------
^|^V^g^^
•S^^elsfe:
.*. •*&&••*
TLl Project: 43432
Client Sample: SO-23-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S976909
F&temaJ Standard v ^ - ,t. An
^| /_ | % %"• *• s | •• "• ..
13C,2-2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
l3C12-1.2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
l3C,2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
^^a&Ispp* fry pe Afc ^ An
37CU-2,3,7,8-TCDD
13Ci2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-U,3,4,7,8-HxCDD
l3C,2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A) An
13C12-U,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
^c^ry^taadirttee^ ri: 'V V;>*
I3CI2-1A3,4-TCDD
l3C,2-l,2,3,7,8,9-HxCDD
it/Otgj!^^^ ^"2
™ * >'-^s '"• *
4.1
3.6
3.8
4.1
4.8
4.3
3.7
3.6
5.1
tt^ti^^g
4.1
3.7
3.8
3.4
3.8
it'^/ifV'
4.3
4.6
i^v'^4;f
^Rprni
."". *" *^t
103
90.5
96.1
103
120
106
92.4
89.7
63.8
/*F f»frvW^!
102
92.0
95.8
85.6
94.6
^R6C^
107
116
If^bj
ery'^cymits
% -. 7* •;
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
Irsr^C^lml^
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
Vk •• ^ •> "• %
40%-130%
40%-130%
||^x ;*' - ^
<- - %, Ratio?-. -,.
0.76
0.80
1.47
1.53
0.52
1.19
0.43
0.99
0.91
\ _ \ f
1.53
0.51
1.25
0.41
^ o ffetfifr , *
...AN v ...:•... .
0.51
0.52
"•^Ratio f -'
0.81
1.20
*fff- - ,,-
•.-: •. *••• ss
20:44
21:32
24:58
26:05
28:41
29:24
31:23
32:14
34:43
>tfl^-%
21:33
25:43
28:35
29:19
32:34
VRTKf
29:55
29:12
^FTP^
21:20
29:41
Flags
•*?
f^k
—
"* ' V. ^ "• %
Rag* ;
Data Reviewer.
10/24/97
Page 2 of 2
X237JSR vZOO, LARS & 10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:29 10/24/97
-------
Initial
....Date.
Data Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/23/97
Listing of S976909B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306
N
D
304-306
13C12-TCDP
316-318
316-318
TCDD
320-322
DC NL 0:00
17:21
17:51
13:05
18:29
18:49
19:19
19:37
19:57
• 20:18
20:34
20:47
21:02
21:14
21:27
21:43
22:01
D SN 22:16
DC WH 22:54
16 Peaks
DC NL 0:00
20:17
20:44
2 Peaks
DC NL 0:00
18:44
19:10
19:30
20:15
20:32
20:58
21:20
21:26
21:33
21:43
21:54
22:08
0.65-0.89
RO 1.45
0.80 1
0.80 1
0.82
0.81 6
0.82 3
0.81 3
0.80 2
0.84 2
0.82 1
0.82 1
0.82 3
RO 1.14
0.81 1
0.80 1
RO 0.96
RO 0.91
RO 1 . 68
0.67
31
0.65-0.89
RO 2 . 63
RO 0.59
0.76 1
1
w™
0.65-0.89
0.73
0.77
0.83
0.73
0.79
0.80
0.82
0.69
0.83
0.68
0.87
0.73
0.80
2.37
,985.05
.022.23
588.58
,142.53
,951.40
,253.75
,733.29
,991.29
,510.30
,207.88
,460.28
9.88
,433.00
.060.16
141.21
16.60
2.25
34.12
,507.43
1.77
9.08
,670.99
.680.07
rppTvp / ny*
IX. Ur / l\*
3.19
464.71
243.13
127.66
460.67
267.81
119.68
140.59
228.91
73.15
51.92
119.67
29.00
883.80
453.46
264.81
2,751.22
1,777.89
1,456.94
1,213.42
1,364.20
682.53
543.15
1,557.61
6.37
641.22
471.92
76.75
8.52
3.95
721.14
202.38
110.22
53.79
203.31
119.28
53.86
57.26
103.57
29.70
24.14
50.31
12.87
0.
1,101.25
568.77
323.77
3,391.31
2,173.51
1,796.81
1,519.87
1,627.09
827.77
664.73
1.902.67
5.58
791.78
588.24
79.78
9.38
0.
6.72
949.85
0.
262.33
132.91
73.87
257.36
148.53
65.82
83.33
125.34
43.45
27.78
69.36
16.13
828-1.098
0.000
0.837
0.861
0.872
0.891
0.908
0.932
0.946
0.962
0.979
0.992
1.002 2378-TCDF AN
1.014
1.024
1.035
1.047
1.062
1.074
1.105
952-1.048
0.000
0.978
1.000 13C12-2378-TCDF ISO
862-1.057
0.000
0.870
0.890
0.906
0.940
0.954
0.974
0.991
0.995
1.001 2378-TCDD AN
1.009
1.017
1.028
Triangle Laboratories, inc.® Analytical Services Division
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:24 10/23/97
-------
Page No.
10/23/97
Listing of S976909B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total .Area... Area. Peak. 1.. Area. Peak. 2.. Rel.RT Compound. Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
D
A
22:37
13 Peaks
DC NL 0:00
DC WL 18:43
DC WL 19:04
DC WL 19:11
DC WL 19:18
20:03
20:18
20:30
20:47
DC SN 20:57
21:33
21:43
21:51
22:00
22:43
DC SN 22:49
9 Peaks
DC NL 0:00
DC WL 18:55
DC WL 19:10
DC SN 19:43
20:16
21:20
21:32
21:53
DC SN 22:09
DC SN 22:15
DC SN 22:37
DC SN 22:51
DC SN 22:53
4 Peaks
DC NL 0:00
D SN 22:44
22:53
D SN 23:08
23:35
23:56
24:05
24:15
24:30
24:42
24:56
0.89
2
1
1
0.65-0.89
RO 1.19
RO 4.20
RO 1.95
RO 1.38
RO 1.39
0.81 1
0.80 1
0.74
RO 1.65
RO 3.79
0.67
0.79
0.66
2
1.32-1.78
RO 0.80
RO 2.03
1.58 1
RO 0.83
1.44
1.55
1.50 2
1.49
1.44
1.53
1.59
22.91
.349.81
0.31
4.72
7.19
8.56
0.60
350.21
4.64
2.43
2.75
1.10
,019.56
1.96
1.70
60.62
2.30
0.69
,446.17
0.48
0.44
2.35
1.84
7.77
,233.72
,190.18
21.80
0.41
0.60
1.55
0.75
1.23
,453.47
wnn /
L\,IJLJ f
0.33
3.29
,182.44
14.77
26.94
681.11
,867.11
704.25
349.28
724.11
174.30
10.77
350.21
4.64
2.43
2.75
1,019.56
1.96
1.70
60.62
2.30
6.10
553.95
529.88
9.25
724.07
15.90
413.73
1,721.02
421 . 67
206.28
437.60
107.00
12.14
0.
0.
4.39
679.77
660.30
12.55
0.
458.37
11.04
267.38
1,146.09
282.58
143.00
286.51
67.30
1.050
907-1.093
0.000
0.869
0.885
0.891
0.896
0.931
0.943
0.952
0.965
0.973
1.001 37C1-TCDD SUR1
1.009
1.015
1.022
1.055
1.060
907-1.093
0.000
0.878
0.890
0.916
0.941
0.991 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.016
1.029
1.033
1.050
1.061
1.063
909-1.076
0.000
0.911
0.917
0.927
0.945
0.959
0.965
0.971
0.981
0.989
0.999
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:24 10/23/97
-------
Page No.
10/23/97
Listing of S976909B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
M
D
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
M
356-358
13C12-PeCDD
368-370
24:59
25:09
25:18
D SN 25:32
25:44
25:52
26:11
DC SN 26:36
26:43
15 Peaks
DC ML 0:00
DC SN 23:01
DC SN 23:44
24:05
24:58
25:16
25:43
DC SN 26:32
DC SN 26:42
4 Peaks
DC NX, 0:00
24:13
DC SN 24:27
24:43
24:59
25:08
25:19
25:35
25:47
25:55
26:06
26:14
DC SN 26:24
26:35
DC WH 26:48
11 Peaks
DC NL 0:00
DC SN 24:41
DC SN 24:56
DC SN 25:04
DC SN 25:36
DC SN 25:48
26:05
26:14
RO
RO
1.
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
1.45
1.50
1.51
0.80
1.40
1.65
1.49
0.49
1.58
32-1.78
1.09
1.00
1.86
1.55
1.47
0.74
1.53
1.20
0.42
32-1.78
1.45
1.08
0.04
1.38
1.62
1.58
1.62
1.36
1.51
1.02
1.54
1.86
1.00
1.61
4.25
32-1.78
1.09
4.06
3.11
2.33
1.06
1.35
1.53
1.53
526.00
367.13
469.27
2.94
534.91
368.08
40.96
1.61
45.09
9,060.98
0.39
1.30
2.37
14.48
1,343.24
7.49
1,198.20
0.81
1.83
2.563.41
311
220
282
312
229
24
27
8
799
4
724
.00
.33
.15
.00
.11
.50
.59
.81
.83
.55
.67
215.
146.
187.
222.
138.
16.
17.
5.
543.
6.
473.
00
80
12
91
97
46
50
0.
67
41
13
53
1.
1.
1.
1.
1.
1.
1.
1.
1.
001 12378-PeCDF
007
013
023
031 23478-PeCDF
036
049
065
070
AN
AN
840-1.160
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
922
951
965
000 13C12-PeCDF
012
030 13C12-PeCDF
063
069
123 IS2
234 SUR2
0.54
259.23
1.40
30.24
168.45
70.22
118.90
88.40
51.28
23.02
58.13
28.84
0.56
24.45
0.61
921.16
157
17
104
43
73
50
30
13
35
21
15
.57
.56
.14
.02
.50
.90
.81
.99
.22
.09
.10
145.
12.
64.
27.
45.
37.
20.
13.
22.
11.
9.
0.
90
68
31
20
40
50
47
71
91
31
35
923-1.026
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
928
937
948
958
964
971
981
988
994
001 12378-PeCDD
006
012
019
027
AN
0.847-1.153
0.41
1.35
1.17
1.40
1.25
1.41
806.89
77.43
487
46
.35
.80
319.
30.
54
63
0.
0.
0.
0.
0.
0.
1.
1.
000
946
956
961
981
989
000 13C12-P6CDD
006
123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
Page No.
10/23/97
Listing of S976909B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
2
NL
12
NL
SN
SN
SN
SN
SN
SN
5
NL
SN
SN
SN
SN
SN
26:36
Peaks
0:00
27:36
27:45
27:54
28:03
28:13
28:35
28:41
28:48
29:00
29:12
29:55
30:00
Peaks
0:00
27:35
27:44
28:35
28:41
29:01
29:12
29:23
29:38
29:55
30:09
30:23
Peaks
0:00
27:59
28:08
28:14
28:24
28:29
28:35
28:48
28:57
29:16
29:20
29:25
29:42
RO
1.
RO
0.
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
0.46
05-1.43
1.19
1.42
1.34
1.27
1.26
1.38
1.26
1.27
1.26
1.25
1.25
0.98
1.28
43-0.59
1.74
0.37
0.77
0.51
0.52
0.17
0.52
0.14
0.44
0.51
0.58
1.46
05-1.43
0.60
0.64
1.23
0.42
1.10
0.42
1.10
1.24
0.78
0.73
1.28
1.26
1.18
0
384
DerfT
r&*.U
3
163
584
78
94
33
312
203
45
93
91
11
18
1,729
0
1
4
1,035
1,127
1
1,009
0
1
812
1
1
3,989
Hvf™Ti
too~v
0
0
37
0
0
0
76
69
5
0
13
18
25
.90
.32
.26
.15
.98
.00
.29
.03
.14
.49
.19
.38
.66
.31
.93
.55
.53
.27
.68
.31
.29
.10
.48
.33
.76
.31
.31
.09
.07
.54
.54
.82
.42
.65
.25
.30
.43
.20
.72
.08
.98
.75
HxCDF Follows
95.83
334.47
43.61
52.51
19.16
173.72
113.76
25.20
51.79
50.95
6.26
10.64
2.38
348.88
384.21
346.56
273.37
Follows
20.87
39.94
38.37
2.88
7.34
10.59
13.92
1.020
0.956-1.052
0.000
67.32 0.962
250.51 0.967
34.39 0.973
41.78 0.978
13.87 0.984
138.42 0.997 123478-HXCDF
89.73 1.000 123678-HXCDF
19.99 1.004
41.59 1.011
40.71 1.018 234678-HXCDF
6.42 1.043 123789-HXCDF
8.29 1.046
AN
AN
AN
AN
0.861-1.139
0.000
0.962
3.10 0.967
686.43 0.997 13C12-HXCDF 478 SOR3
743.08 1.000 13C12-HXCDF 678 IS4
1.012
662.92
538.94
1.018 13C12-HXCDF 234 ALT2
1.024
.033
1.043 13C12-KXCDF 789 ALT1
1.051
1.059
0.951-1.015
0.000
0.952
16.95 0.957
0.960
0.966
0.969
36.36 0.972
31.06 0.980
3.70 0.985
0.995
5.74 0.998 123478-HxCDD
8.39 1.001 123678-HxCOD
11.83 1.010 123789-HxCDD
AN
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:24 10/23/97
-------
Page No.
10/23/97
Listing of S976909B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
M
408-410
13C12-HPCDF
418-420
418-420
HpCDD
424-426
424-426
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
WH
WH
7
NL
WL
SN
SN
SN
SN
4
NL
SN
SN
SN
WH
WH
4
NL
SN
SN
2
NL
SN
SN
WH
WH
2
29:49
29:53
30:01
Peaks
0:00
28:14
28:48
29:12
29:19
29:24
29:41
29:55
30:02
30:09
Peaks
0:00
31:23
31:36
31:43
32:22
32:24
32:36
32:44
32:54
33:03
Peaks
0:00
31:23
32:08
32:34
32:46
Peaks
0:00
31:39
31:53
32:00
32:14
32:29
32:36
Peaks
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
0.
RO
RO
RO
RO
RO
0
0
0
.43
.24
.67
0.40
0.27
0.11
246.56
05-1.43
0
1
0
0
1
1
1
1
1
0
.79
.27
.75
.67
.25
.19
.20
.64
.95
.37
ltW«M..
88-1.20
3
1
0
0
2
6
1
1
7
7
.42
.23
.93
.84
.13
.30
.67
.77
.48
.90
0.40
0.68
3.76 2.08
0.65
690.11 382.85
828.75 450.31
782.11 427.38
0.63
0.94
0.42
2,304.73
Uvf^nn 1 U«<"*TO7 17/tl 1 m*re
0.49
73.24 44.30
22.64 10.92
12.30 6.27
0.98
0.67
9.98 8.17
2.04
0.55
0.61
118.16
37-0.51
0
0
1
0
3
.78
.43
.00
.41
.12
0.39
640.83 192.53
1.31
467.44 136.01
1.18
1,108.27
tin/Tit? 1 UnffV) T?«1 1 ni*te
88-1.20
1
1
2
0
0
1
4
.05
.08
.82
.71
.77
.55
.19
0.45
21.22 11.00
1.00
1.26
17.93 9.14
0.67
0.63
39.15
0.
2.77
307.26
378.44
354.73
0.
35.90
11.72
7.50
4.89
0.
448.30
331.43
1.
1.
1.
014
016
021
966-1.034
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
960
980
993
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
018
022
026
SUR4
IS5
RS2
995-1.044
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
000 1234678-HpCDF
007
Oil
031
032
039 1234789-HpCDF
043
048
053
AN
AN
936-1.127
0.
1.
1.
1.
1.
000
000 13C12-HpCDF 678
024
038 13C12-HpCDF 789
044
IS6
SUR5
0.977-1.006
10.22
11.94
0.
0.
0.
0.
1.
1.
1.
000
982
989
993
000 1234678-HpCDD
008
Oil
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive* Durham, North Carolina27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:24 10/23/97
-------
Page Mo.
10/23 '97
Listing of S976909B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z ---- QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HpCDD
436-438
436-438
OCDF
442-444
M
442-444
OCDD
458-460
M
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
1
NL
SN
WH
1
0:00
31:38
31:56
32:05
32:14
32:27
32:40
Peak
0:00
31:36
32:05
32:55
33:07
33:15
33:31
33:42
33:52
34:02
34:21
34:25
34:30
34:42
34:49
34:59
35:34
35:45
35:57
Peak
0:00
34:44
35:06
35:15
Peak
0:00
34:43
34:53
35:16
Peak
0.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
0.
RO
RO
88-1.20
1.
1.
0.
0.
0.
2.
0.
39
35
63
87
99
09
77
- Above:
0
2
0
1
571
1
1
571
.47
.02
.75
.61
.53
.14
.10
.53
HpCDD /
76-1.02
1.
10.
0.
2.
5.
0.
0.
0.
4.
0.
0.
3.
1.
2.
0.
0.
3.
2.
0.
67
00
30
13
88
66
43
16
78
61
92
61
64
68
98
27
86
97
60
0
0
0
0
0
0
0
0
0
1
1
.34
.21
.87
.72
.15
.57
.91
.40
.17
.34
.59
0.62
0
.53
0.7C
3
0
0
0
1
3
.91
.40
.68
.70
.13
.91
76-1.02
0.
1.
1.
0.
91
23
70
61
0
.42
6.29
0
0
6
.38
.53
.29
76-1.02
0.
0.
1.
1.
83
91
17
32
0
517
1
1
517
.42
.94
.95
.70
.94
284.61
0.969-1.031
0.000
0.981
0.991
0.995
286.92 1.000 13C12-HpCDD 678 IS7
1.007
1.013
Follows
1.94
4.11
0.885-1.115
0.000
0.910
0.924
0.948
0.954
0.958
0.965
1.97
0.971
0.976
0.980
0.989
0.991
0.994
.000
.003 OCDF
.008
.024
.030
AN
246.14
1.036
0.885-1.115
0.000
3.33 1.000 OCDD
1.011
1.015
0.995-1.005
0.000
271.80 1.000 13C12-OCDD
1.005
1.016
AN
IS8
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:24 10/23/97
-------
Page No.
10/23/97
Listing of S976909B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File ,3976909 tl-848 Aoq,23-OCT-1997 17,16,18 EH- Voltage SIR 70S Soiae>968
303.9016 Fi2 BSUB(256,30,-3.0) fXD(9, 5,5,0.05%, 3872.0,1.00\,F,T) ExptEPCUS
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TRIANGLE LABS Text:SO-H23-2 TLIt 43432
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TRIASGLX LABS Text:SO-H23-3 TLIt 43433
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TRIANGLE LABS Text,SO-H23-2 TLIt 43432
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rlle:S976909 tl-848 Acq,23-OCT-1997 17:16,18 EI+ Voltage SIS 70S Noise: 12 3
341.8567 t,2 BSOB(256, 30, -3.0) PKD(7,5,3,0.05\,492.0,1.00\,F,T) Exp:EPCUS
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351.9000 F:2 SSUB(256,30, -3 .0) PXD(7,5,3,0.05\t488.0,1.00\rr,T) XxptXPCOS
TRIANGLE LABS Text,SO-M23-2 TLIt 43432
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353.8970 T,2 B3UB(256, 30, -3.0) PKD(7, 5, 3,0. 051,440. 0,1.00\,T,T) XxpiXfCUS
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369.8919 T>2 BSOB(2S6, 30, -3.0) PKD(7,5,3,0 .05\,452.0,1.00\,F,T) XxpiEPCUS
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389.8156 r,3 BSUB(256,30,-3.0) PXD(7,5, 3, 0.051,600 .0,1. 00*,r,T) ExpsEPCOS
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391.8127 T,3 BSUB(256,30,-3.0) PKD(7, 5, 3, 0.051,1008. 0,1.00\,F,T) ExpiEPCUS
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401.8558 Ti3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,444.0,1.00\,r,T) ExpiEPCUS
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403.0529 Fi3 BSUB(256,30,-3.0) PXD(7,5,3,O.OS\,560.0,1.00*,F,T) ExpiEPCUS
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393.9760 Fi3 ExpiEPCUS
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F±le:S976909 tl-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S Soiso:408
407.7818 F:4 SSOB(256,30,-3.0) PXD(7,5,3,0.05\,1632.0,1.00\,F,T) Exp:EPCOS
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TRIANGLE LABS Text, SO-M23-2 TLIt 43432
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File:S976909 tl-403 Aeq:33-OCT-1997 17:16:18 EH- Voltage SIR 70S Soiae:105
417.8253 F:4 BSUB(256,30,-3.0) PXD(7,5,3,0. 051,420. 0,1.00\,F,T) Exp:EPCUS
TRIANGLE LABS T*xt,SO-M23-2 TLIt 43432
1001
80:
60:
40:
20:
o:
A1.93E6
A
M A1.36E6
1 t\
A
/I \
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3l':34 31:36 3l':48 33:00 33:13 33:34 33:36
r±le:S976909 tl-403 Aoq:23-OCT-1997 17:16:18 EH- Voltage SIR 70S Oolae:136
419.8220 F:4 BSOB(256,30,-3.0) PKD(7,5, 3,0. 051,544. 0,1.00\,F,T) ExptEPCUS
TRIANGLE LABS Text:SO-H33-3 TLIt 43433
1001
80:
60:
40:
30:
o:
A4.4BE6
A
f 1 A3. 31X6
A
/
/ 1 A
/ V J \
31:24 31:36 31:48 32:00 32\12 32:24 32:36
File:S976909 tl-403 Acq: 33 -OCX- 1997 17:16:18 EH- Voltage SIR 70S
430.9739 F:4 ExptEPCUS
TRIANGLE LASS Text:SO-M23-2 TLIt 43432
1001
80:
60:
40:
20:
0:
31'34 31'42 31t54 32:10 32:19 . « 3*r?JL
31:34 3l':36 3l':48 32:00 32': 12 32\24 32\36
fil«, 3976909 tl-403 Acq: 23 -OCX- 1997 17:16:18 EI+ Voltage SIR 70S
479.7165 F:4 ExptEPCUS
TRIANGLE LABS TextiSO-M23-2 TLIt 43433
100S
80:
60:
40:
20:
ol
1
1 A
A M 31:54
1.8E5
'.1.4X5
.1.1X5
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32l: 4 9 33:00 Time
-1.6E5
-.1.3X5
-.9.4X4
''.6.3E4
\
-.3.1X4
O.OEO
32 1 48' ' ' 33 1 00 ' Time
8.6X5
.6.9X5
.5.2X5
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.1.7X5
0.0X0
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-1.9X6
.1.5E6
.1.1X6
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32:48 33:00 Tlao
32:4 6 f^33 '03r-3' 9ES
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13.3E6
_1 . 7E6
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.8.8X3
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0.0X0
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-------
rileiS976909 #1-403 Acq: 23-OCT-1997 17:16:18 EI+ Voltage SIS 70S NOiaeillS
423.7766 F:4 BSUB(256, 30, -3.0) PKD(7, 5, 3,0. 051,460 .0, 1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text: SO-M23-2 TLIt 43432
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31
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F±la: 3976909 §1-403 Acq:23-OCT-1997 17:16:18 EH- Voltage SIS 70S KoiaeillO
425.7737 F,4 BSUB(256,30, -3.0) PKD(7,5,3,0.05\,440.0,1.00\,F,T) ExptEPCUS
TRIANGLE LABS Text,SO-M23-2 TLIt 43432
1001
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31
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File, 3976909 §1-403 Acqt23-OCT-1997 17:16:18 EH- Voltage SIS 70S Soiae,159
435.8169 F:4 BSUB(256r30,-3.0) PXD( 7,5, 3,0.05\,636 .0,1.00*, F,T) Exp:EPCOS
TRIANGLE LABS Taxt:SO-M23-2 TLIt 43432
1001
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40.
20:
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31
30 31,36
A2.85E6
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0.0X0
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File ,3976909 §1-403 Acq:23-OCT-1997 17:16:18 Eli- Voltage SIS 70S Noise, 115
437.8140 F:4 BSUB(256, 30, -3.0) PKD(7,5,3,0.05\,460 .0,1.00\,F,T) ExpiEPCUS
TRIANGLE LABS Text:SO-M33-3 TLIt 43432
1003
80.
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0
31
30 31,36
A2.87E6
A
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TilatS976909 §1-403 Aoqt33-OCT-1997 17:16:18 EI+ Voltage SIS 70S
430.9729 F,4 XzpiXPCUS
TRIANGLE LABS Text, SO-M23-2 TLIt 43432
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-------
31:00 33tOO 33,00 34,00 35:00
F±le:S976909 tl-403 Acq,23-OCT-1997 17:16:19 XI+ Voltage SIB 70S Noiae:92
443.7399 Ft4 3303(356,30, -3.0) tXD(7,5r3,0.05\,368.0,l.OO\,F,T) ExptSPCUS
TRIANGLE LABS Text:SO-M23-2 TLIt 43432
riletS976909 tl-403 Acq,23-OCT-1997 17,16,18 EH- Voltage SIS 70S NoiaetlSO
441.7438 Ti4 BSOB(256,30,-3.0) PXD(7,S,3,0.05%,600.0,1.00\,f,T) ExpiSPCUS
TRIANGLE LABS Text,SO-H23-2 TLIt 43433
31:00 32tOO 33,00 34tOO
TilutS976909 tl-403 Acq:23-OCT-J.997 17tl6tl8 XH- VoltMgt SIS 70S
430.9729 Ti4 ExptEPCUS
TRIANGLE LABS Text:SO-M23-2 TLIt 43432
35:00
1001
90^
80.
701
601
501
401
301
201
101
0.
31:13
31,54 32,19,
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33,93
33157
34,45
35,28
31,00 32,00 33,00 34,00
File:S976909 tl-403 Acq:23-OCT-lS97 17,16,18 XH- Voltage SIX 70S
513.6775 r,4 XxpiEPCUS
TRIANGLE LABS Text:SO-M23-2 TLIt 43432
35,00
,.3.0X6
2. 7X6
2.4X6
2.1X6
1. 8X6
1.5X6
1.2X6
8.9X5
6. OXS
3.0X5
0.0X0
Time
31100
32,00
33,00
34,00
35,00
-------
FileiSS7690S #1-403 Acqt 13-OCT-1991 17H6,18 EH- Voltage SIR 70S Noise1102
457.7377 T,4 BSOS(256,30, -3.0) Pn>f7,5,3,0.05\,408.0,1.00\,r,T) XxpiEPCUS
TRIANGLE LABS TaxttSO-H23-2 TLIt 43433
100\ A4.27E4
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A5.61X3
34.35 34142 34:48 34s54 35,00
PilotS976909 #1-403 Acqt23-OCT-1997 17tl6tl8 EH- Voltage SIS 70S Noise> 110
459.7348 T>4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,440.0,1.00\,F,T) XxptEPCUS
TRIANGLE LABS TextiSO-M23-2 TLIt 43433
1004 R4.26E4
35:06
20.
34136 34t42 34:48 34,54 35:00
Tile:3976909 tl-403 Acqt23-OCT-1997 17tl6>18 EI+ Voltage SIR 70S Noiae:97
469.7779 Fi4 BSUB(256,30r-3.0) PXD(7,5,3,0.05\,3B8.0r1.00\rTrT) EipiEPCUS
TRIANGLE LABS Text.:SO-M23-2 TLIt 43433
1001 A2.46E6
80.
60.
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20.
35 i 06
34,36 34:42 34,48 34,54 35:00
F±10,3976909 tl-403 Acq,23-OCT-1997 17,16:18 Eli- Voltage SIR 70S Noise: 117
471.7750 r>4 BSOB(256,30,-3.0) PKD(7,5,3,0.051,468.0,1.00\r,T) ExpiEPCUS
TRIANGLE LABS Text:SO-M23-2 TLIt 43433
100* A2.72E6
35 > 06
34:36 34,42 34:48 34:54 35,00
File,3976909 tl-403 Acq,23-OCT-1997 17:16,18 EI+ Voltage SIR 70S
430.9729 r,4 ExptSPCUS
TRIANGLE LABS Text,SO-H23-2 TLIt 43432
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35,06
34i36
34,42
34:48
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35112
35112
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35,12
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0.0X0
Time
-------
File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
80 J
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305.8987 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
80 j
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40 j
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23:00
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File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
10 or
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File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS
Sample Text :SO-M23-2 TLI# 43432 File Text :SO-M23-2 TLI#_ 43432
100%
80 J
60 J
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22:35
23:08 23:35
23:00 24:00 25:00
File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
80 j
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26:00
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351.9000 F:2 ExprEPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
26:00
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24:00
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339.8597 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
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File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
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351.9000 F:2 Exp:EPCUS
Sample Text :SO-M23-2 TLI# 43432 File Text .-SO-M23-2 TLI# 43432
100% 24;58
80J
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-------
File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% A3.11E6
80 j
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341.8567 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
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351.9000 F:2 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% 24;58
80 J
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355.8546 F:2
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Sample Text:
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File:S976909 #1-445 Acq:23-OCT-1997 17:16
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Sample Text .-SO-M23-2 TLIt 43432 File Text
100%
80J
60 j
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18 EI+ Voltage SIR 70S
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29:30 29:36 29:42 29:48
File:S976909 #1-445 Acq:23-OCT-1997 17:16
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Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
80 J
60 J
40 J
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File:S976909 #1-445 Acq:23-OCT-1997 17:16
383.8639 F:3 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text
100%
80 J
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29:54 30:00 30
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-------
File:S976909 #1-403
Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text :SO-M23-2
100%
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Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text -.SO-M23-2
100% A3.59E5
80 j
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40 J
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0:
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File:S976909 #1-403
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Acq:23-OCT~1997 17:16:18 E2> Voltage SIR 70S
417.8253 F:4 Exp : EPCUS
Sample Text : SO-M23-2
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43432 File Text :SO-M23-2 TLItt 43432
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-------
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 El-f Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% A6.40E4
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File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% A4.19E4
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File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
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-------
File:S976909 #1-403 Acq: 23-OCT-1997
423.7766 F:4 Exp:EPCUS
Sample Text :SO-M23-2 TLI# 43432 File
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Text:SO-M23-2 TLI# 43432
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File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS
Sample Text :SO-M23-2 TLI# 43432 File Text :SO-M23-2 TLI# 43432
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-------
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
441.7428 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% A1.94E4
80 j
60 j
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File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
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File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EH- Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% 34;43
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-------
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100% A4.11E4
80 j
60 j
40J
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33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
lOOi A3.33E4
80 j
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35:24 35:36 35:48
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:48
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
lOOi 34;43
80J
60 J
40J
20 j
OJ
.2.5E4
.2.0E4
.1.5E4
.9.8E3
.4.9E3
.O.OEO
Time
.2.0E4
1.6E4
.1.2E4
.8.0E3
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33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
35:12
35:24 35:36 35:48
.9.6E5
.7.7E5
.5.7E5
.3.8E5
.1.9E5
.O.OEO
Time
-------
TLI Project: 43432
Client Sample: SO-23-2
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973637
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-2A-C
1.000
n/a
DB-225
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/18/97
Dilution Factor: n/a
Blank File: U973257
Analyst: WK
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
XF24087
X973633
n/a
n/a
n/a
2,3,7,8-TCDF
2.3
0.81
24:34
a$^^ ^T
13C12-2,3,7,8-TCDF
4.1
102
40%-130%
0.81
24:32
13C,2-1,2,3,4-TCDD
0.77
23:19
Data Reviewer
10/23/97
Page 1 of 1
C2NF.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:35 10/23/97
-------
Initial
Date..
Data Review By:
NJCxo^^
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of X973637B.dbf
Matched GC Peaks / Ratio
/ Ret. Tina
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306
304-306
13C12-TCDF
316-318
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
25
0:00
19:46
19:53
20:02
20:14
20:24
20:47
20:55
21:03
21:14
21:21
21:30
21:39
21:49
21:59
22:06
22:14
22:20
22:31
22:36
22:44
23:00
23:07
23:15
23:31
23:46
23:57
24:25
24:34
24:48
25:07
25:17
25:55
26:14
26:23
26:58
27:06
27:21
27:33
Peaks
0.
0.
RO 3.
RO 1.
RO 0.
RO 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RO 0.
RO 1.
0.
RO 0.
RO 3.
66
80
00
01
60
34
79
77
78
78
72
76
79
78
78
76
80
61
75
77
81
79
73
79
79
82
77
80
81
81
78
78
76
78
91
23
80
43
24
21
8,495
62
73
39
148
13,320
7,752
8,644
7,099
169
4,675
6,195
2,341
15,202
4,162
78
43
7,726
5,226
104
6,044
1,175
5,631
5,798
707
4,023
3,633
4,152
3,185
2,895
6,382
11
3,455
19
17
391
4
7
138,322
.56
.70
.55
.76
.58
.95
.82
.27
.06
.25
.50
.95
.78
.81
.73
.71
.00
.40
.96
.59
.58
.28
.93
.71
.13
.60
.08
.01
.48
.56
.64
.38
.19
.95
.52
.75
.69
.30
.01
.07
3,766
5.869
3,377
3.782
3,117
2.021
2.728
1,023
6,682
1,800
3,314
2.281
2.664
494
2,485
2,553
317
1,750
1,611
1,852
.87
.09
.05
.61
.04
.87
.44
.23
.46
.26
.63
.35
.57
.50
.71
.03
.89
.34
.11
.31
1,428.29
1,270
2,788
1,517
173
.67
.82
.73
.82
4,
7,
4,
4,
3,
2,
3,
1,
8,
2,
4,
2,
3,
3,
3,
2,
2,
2,
1,
1,
3,
1,
0.65-0.89
DC
NL
0:00
0.
77
19
.98
0.
728.83
451.73
375.22
861.45
982.21
654.08
467.34
318.58
520.27
362.45
412.33
945.24
379.71
681.43
146.00
245.10
389.71
272.74
021.90
300.17
757.27
624.97
593.56
938.22
217.87
0.
798-1.112
0.000
0.806
0.810
0.817
0.825
0.832
0.847
0.853
0.858
0.865
0.870
0.876
0.882
0.889
0.896
0.901
0.906
0.910
0.918
0.921
0.927
0.938
0.942
0.948
0.959
0.969
0.976
0.995
1.001 2378-TCDP
1.011
1.024
1.031
1.056
1.069
1.075
1.099
1.105
1.115
1.123
959-1.041
0.000
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:5AlO/21/97
-------
Page No.
10/21/97
Listing of X973637B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
316-318
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
WL
SN
SN
SN
WH
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
WH
WH
2
21:04
22:59
23:14
23:20
23:37
24:32
24:45
25:16
26:59
Peak
0:00
21:03
22:00
23:00
23:19
23:32
23:37
24:05
24:15
24:39
24:42
24:45
24:59
25:25
26:03
26:11
26:24
26:41
Peaks
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
2
1
0
1
1
0
0
0
1
.38
.18
.26
.04
.19
.81
.20
.21
.19
65-0.89
1
2
1
0
0
1
0
0
0
4
0
2
0
8
0
1
2
1
.63
.41
.09
.80
.77
.00
.53
.59
.59
.03
.49
.22
.80
.21
.50
.64
.46
.38
4.53
29.06
11.98
8.16
5.20
7,632.04 3,415.57
6.34
10.44
70.78
7,632.04
Above: TCDF / TCDD Follows -
4,216.47
0.859
0.937
0.947
0.951
0.963
1.000 13C12-2378-TCDF ISO
1.009
1.030
1.100
7.59
4.80
6.58
5,214.85 2,316.60
5,391.44 2,347.91
30.64
3.31
53.79
3.56
2.57
8.32
6.85
7.32
2.19
7.65
' 6.99
3.56
6.00
10,606.29
0.913-1.087
0.000
0.915
0.957
2,898.25 1.000 13C12-2378-TCDD IS1
3,043.53 1.014 13C12-1234-TCDD RSI
1.023
1.027
1.047
1.054
1.072
1.074
1.076 .
1.086
1.105
1.133
1.138
1.148
1.160
Column Description "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio outside Limits
Rel.RT-Relative Retention Time
*** End of Report ***
WL-Below Retention Time Window
WH-Above Retention Tim* Window
SN-Below Signal to Noise Level
-------
FllatX973637 #1-003 Acq: 18-OCT-1SS7 15*37*41 OC EH- Voltage SIX AUtOSpec Ooiee:4274
303.9016 BSUB(256,30,-3.0) PKD(5,3,1,0.10*,17096.0,0.00\,F,P) Exp:XCOBP_TT
Sample TaxttSO-H23-2 TLIif43432 Pile Text* TRIJUmLE LABS
100* A5.87S7
BO.
20100 31*00 22:00 23:00 24iOO 2SiOO 26tOO 27:00
file: 1973 637 #1-003 AaqtlB-OCT-1997 15:37:41 OC EI+ Voltage SIR AutoSpec Nolae:6504
305.8987 BSUB(256,30,-3.0) PXO(5,3,1,0.10*,26016.0,O.OOX,F,P)
Saaplf T*xt:SO-K23-2 TLI*43432 Pllf Tuttt TRUWQLB LAB3
IOOH JL7.4SE7
20:00 21:00 22:00 23:00 24*00 25*00 26:00 27*00
Film 1X973637 #1-803 ley: 18-OCT-1997 15:37:41 OC EH- Voltage SIR XutoSptc Holm*:4359
315.9419 B3UB(256,30,-3.0) PXD(5,3,1,0.10*, 17436.0,0.00*,F,P) Sq?»XCOHP_TT
Saoplu T»Xt:3O-IO3-2 TLIK43432 Film Tmxt: TRIUSUKS tABS
100JC A3.42E7
BO.
60.
40.
20.
20:00 21:00 22:00 23:00 24*00 25*00 26*00 27*00
Pile :X973 637 #1-003 Aag*18-OCT-1997 15*37*41 OC KT+ Voltage SIR JLutoSpec Soi*e:S629
317.9389 BSUB(25f,30,-3.0) PXD(5,3,1,0.10*,22516.0,0.00*,P,P) BtptXCOBFJTV
Staple TextiSO-H23-2 TLX143432 Pile Text* TRaOOLS UBS
A4.22S7
BO:
eo:
40.
20.
o:
20(00 21<00 22(00 23(00 24(00 25(00 2tf»00
Pilu:XS73637 #1-003 JL.c
-------
Pile,X973S37 #1-903 Acqil9-
-------
Pll»*X973637 #1-003 Aaq*18-OCT-1997 15:37:41 OC EH- Voltago SIR AutoSpac
303.9016 Exp*XCONP_TT
Saapla Toxt:SO-M23-2 TLIt43432 Filo Taxtt TRIASBLE LABS
20(00 21<00 22:00 23:00 24:00 25:00
P11»:XS73637 #1-003 AeqilB-OCT-1997 15:37:41 OC EH- Voltayt SIR AutoSpfc
315.9419 SxptXCOSP TV
Sanpl* T*Xt:SO-H23-2 TLH43432 Pile Text: TRIABOLE LABS
iota
sol
60:
40:
20.
20*00 21>00 22 tOO 23tOO 24:00 25:00
Pilf 1X973637 * 1-803 AcqtlB-OCr-1997 15 1 37 t 41 OC SH- Voltage SIS AutoSpec
319.8965 S*piKOHf_Tr
Saoplf Text:SO-K23-2 TLH43432 Film Ttxtt TRIMK3LE LABS
100* 20(34
80:
60:
40:
20:
•i-
OJ
26:00
27(00
21(10
21(51
23:18
24(00
20(00 21(00 22(00 23(00 24(00 25:00
Pil»*X973637 #1-003 AcytlB-OCT-1997 15*37*41 OC El* Voltage SIS AutoSpea
331.9368 SxptXCONP_TT
TextiSO-K23-2 TLIf43432 Pile Text: TSIABOLX LABS
100* 23,19
so:
ffflj
40:
20:
26*00
27100
oj
20(00 21(00 22(00 23(00 24(00 25(00
Pile*X973637 #1-003 ActjtlS-OCT-1997 15(37(41 OC EH- Voltage SIS
292.9825 ExptXCONP_TT
Staple TexttSO-K23-2 TLIf43432 Pile Text* TRIAHOLE LABS
1003^ ^0(24 31(03 21*36 _^^JV1^-12314g. 24(22 ,24(54 75(25
80:
60:
40:
20:
8.2X6
6.6X6
.4.9X6
3.3X6
.1.6X6
.0.0X0
Time
.2.2E6
.1.6S6
.1.1S6
.5.425
0.050
Tim*
.6.3E6
'-.5.0E6
'-3.8B6
.2.5E6
.1.3E6
27(00
26*16 26*49 27*20
O.OEO
Time
.9.3X7
.6.9X7
.4.6X7
-.2.3X7
20*00 21(00 22(00 23(00 24(00 25(00 26:00
PileiX973637 #1-003 Actjil8-OCT-1997 15(37(41 OC SI* Voltage SIS AutoSpeo
330.9793 XxptXCOSPJTT
Staple Text:SO-M23-2 TLH43432 Pile Text* TRIANGLE LABS
lOOH ^jOjOy 20(50 21(50 33*36 23*58 ^24,39 25(27 36*11
27:00
0.0X0
Time
00:
40:
20:
o:
20(00
21(00
22(00
23(00
.1.1X8
.8.6X7
.6.5X7
-.4.3X7
.2.2X7
0.0X0
24(00
25(00
2f(00
27(00
-------
Peak Locate Examination:18-OCT-1997:15:37 File:X973637
Experiment:XCONF_TT Function:! Reference:PFK
-U
-------
% "*
TLI Project: 43432
Client Sample: SO-23-3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973260
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-3A-C
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
"", \ "\ vv ^^^^ £$',* ^ J <^
•AfWww'9' % % ^ ^ s s \ '•>• % % %--
* s % V
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
total* : ,:x*;/ , " ^
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
&£i£j%X$i&
^•w^mjfc.
>' v>. * ^¥^.*"T
0.13
0.10
ND
ND
ND
ND
EMPC
4.5
0.65
0.47
0.18
0.09
0.05
ND
0.04
ND
ND
5 &rafe-$|t
4.1
0.74
0.24
ND
512
10.7
0.92
0.04
V^ic^fc^Wi^ ^V-3^ii*£ttiv'% 0 " -• * ->"s > W z w?V ^^^B^- '"•"' ^\iii ^%
% s
-------
TLI Project: 43432
Client Sample: SO-23-3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973260
Internal Standards* , - ? "\ An
13C12-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C.2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13Ci2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C.2-l,2,3,4,6,7,8-HpCDD
I3C.2-1,2,3,4,6,7,8,9-OCDD
£^*t*^r^$,{!yp*A)^ An
37CU-2,3,7.8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13C12-l,2,3,4,7,8-HxCDD
l3C.2-l,2,3,4,7,8,9-HpCDF
Alternate Standards
0.73
0.78
1.45
1.41
0.50
1.14
0.42
0.96
0.84
[tette'"^
1.46
0.53
1.25
0.43
^aitio
0.51
0.52
iteitia - " '-
0.80
1.17
RT - Flags
21:36
22:32
26:18
27:30
30:15
30:59
33:03
33:54
36:26
;\8r>; BMJ$;\
22:32
27:07
30:09
30:55
34:16
lf^vj?lags\
31:31
30:47
rwr:*?^j*tas*.
22:17
31:18
Data Reviewer.
Page 2 of 2
10/23/97
X237_J>SR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:14 10/23/97
-------
Initial
Date.
Data Review By:
Calculated Noise Area: 7.22
The Total Area Cor each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of O973260B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
H
M
DC NL
IS
DC NL
DC WL
DC WL
DC WL
DC SN
DC SN
DC SN
DC SN
DC SN
DC WH
1
DC NL
0:00
17:44
18:17
18:33
18:57
19:19
19:52
20:15
20:41
21:05
21:23
21:39
22:11
22:26
22:43
23:44
Peaks
0:00
18:49
18:56
19:00
21:05
21:36
21:54
22:20
22:24
22:26
22:56
Peak
0:00
19:15
19:43
20:08
21:03
21:22
21:52
22:24
0.
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
65-0.89
1.34
0.71
0.75
0.74
0.73
0.74
0.74
0.78
0.74
0.74
0.76
0.74
0.73
0
0
1
.79
.97
.21
9
2,831
1,243
577
7,721
4,752
3,941
2,728
3,085
1,796
1,312
3,061
1,218
696
76
38
35,081
.27
.28 1,179.33
.82 532.84
.11 246.22
.50 3,265.44
.79 2,019.10
.26 1,672.04
.83 1,191.72
.78 1,315.78
.14 765.67
.02 567.37
.36 1,305.04
.59 513.33
.24 308.03
.84 42.24
.30 26.17
.86
65-0.89
1
1
0
0
0
0
1
0
0
1
1
.15
.21
.78
.40
.49
.73
.22
.44
.30
.45
.01
nv-
65-0.89
1
0
0
0
0
0
0
0
.07
.75
.74
.72
.72
.74
.69
.80
8
3
7
8
15
2,536
.04
.63
.62
.80
.15
.01 1,071.86
0.813-1.106
0.000
1,651.95 0.821
710.98 0.846
330.89 0.859
4,456.06 0.877
2,733.69 0.894
2,269.22 0.920
1,537.11 0.938
1,770.00 0.958
1,030.47 0.976
744.65 0.990
1,756.32 1.002 2378-TCDF AN
705.26 1.027
388.21
43.41
21.64
0.
1,464.15
7.27
5
2
8
9
2,536
iv% s TCu
5
723
414
156
632
295
171
507
.45
.09
.99
.13
.01
B 1 IfVnn T7/\l 1 ruia —
.77
.32 310.56
.15 176.78
.31 65.35
.93 264.91
.00 125.00
.36 69.74
.00 225.00
0.
412.76
237.37
90.96
368.02
170.00
101.62
282.00
1.
1.
1.
039
052
099
954-1.046
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
871
877
880
976
000 13C12-2378-TCDF ISO
014
034
037
039
062
848-1.061
0.
0.
0.
0.
0.
0.
0.
0.
000
854
875
893
934
948
970
994
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:17 10/21/97
-------
Page No.
10/21/97
Listing of U973260B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why .-RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
H
K
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
SN
SN
WH
WH
11
22:32
22:43
22:57
23:12
23:22
23:44
24:08
24:13
Peaks
0.
0.
0.
RO 0.
0.
0.
0.
RO 2.
87
74
84
52
86
80
66
42
99
62
124
26
5
26
3
3
3,212
.00 46.10
.31 26.52
.14 56.79
.80 11.66
.87
.20
.28
.49
.32
52.90 1
35.79 1
67.35 1
22.22 1
1
1
1
1
.000 2378-TCDD AN
.008
.018
.030
.037
.053
.071
.075
0.911-1.089
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
0:00
19:36
19:45
19:53
20:02
20:14
20:15
20:21
20:30
20:48
21:04
21:12
21:18
21:36
21:39
22:32
23:03
23:12
23:21
23:34
23:45
23:51
24:06
24:09
Peaks
4
12
9
3
1
.82
.91
.23
.66
.74
1.29
1
3
.26
.49
3.77
411
7
6
3
5
1
2,095
49
3
8
8
5
12
4
3
2.556
.94 411.94
.18
.18
.72
.80
.10
.49 2,095.49
.33 49.33
.85
.68
.06
.75
.25
.14
.04
.76
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
SN
SN
SN
SN
SN
3
0:00
19:23
19:29
22:17
22:32
22:55
23:18
23:25
23:28
23:57
24:06
Peaks
RO 2.
RO 3.
RO 3.
0.
0.
0.
RO 0.
RO 4.
RO 1.
RO 0.
RO 0.
24
37
21
80
78
88
49
02
17
46
25
6
2
3
3,973
2,582
86
6
4
13
8
6
6,642
.53
.50
.56
.84 1,767.61
.73 1,128.21
.42 40.33
.23
.60
.52
.78
.69
.99
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
.000
.870
.876
.882
.889
.898
.899
.903
.910
.923
.935
.941
.945
.959
.961
.000 37C1-TCDD SOR1
.023
.030
.036
.046
.054
.058
.070
.072
0.911-1.089
0
0
0
2,206.23 0
1,454.52 1
46.09 1
1
1
1
1
1
.000
.860
.865
.989 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.017
.034
.039
.041
.063
.070
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:17 10/21/97
-------
Page No.
10/21/97
Listing of U973260B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why .-RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
K
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
K
K
374-376
13C12-HXCDF
384-386
25:30
DC SN 25:45
26:02
26:19
26:28
26:40
26:52
26:58
27:11
27:20
27:30
27:40
28:02
DC WH 28:22
DC WH 28:28
DC WH 28:39
12 Peaks
DC NL 0:00
DC SN 25:35
DC SN 26:19
DC SN 27:21
27:30
27:40
DC SN 28:02
DC SN 28:12
2 Peaks
DC NL 0:00
29:07
29:17
29:26
29:35
DC SN 29:45
30:09
30:15
30:23
30:35
30:47
DC SN 30:53
9 Peaks
DC NL 0:00
30:09
30:15
30:47
31:31
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
1.
RO
RO
RO
RO
0.
0.91
0.22
1.47
1.29
1.51
1.51
0.95
1.30
1.61
1.78
1.63
1.89
1.68
1.65
1.91
0.67
32-1.78
1.60
4.46
1.68
1.79
1.41
1.82
1.36
2.12
05-1.43
0.92
1.35
1.14
1.34
1.15
1.48
1.24
1.23
1.64
1.07
1.25
0.35
43-0.59
0.50
0.53
0.50
0.52
0.51
346.44
12.80
43.00
207.37
86.05
169.49
27.24
63.34
78.52
38.38
68.47
36.80
31.57
5.41
3.65
5.77
1,196.67
7.98
3.90
6.89
6.68
2,022.65
198.11
23.24
14.74
2,220.76
210
25
126
51
101
16
38
48
24
42
27
19
1,182
141
.58
.57
.05
.80
.87
.56
.50
.48
.55
.41
.24
.80
.19
.32
231
17
97
34
67
17
29
30
13
26
14
11
840
77
.06
.43
.80
.25
.62
.42
.54
.04
.83
.06
.43
.77
0.
.46
.69
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
927
936
947
957
962
970
977
981
988
994
000 12378-PeCDD
006
019
032
035
042
AN
855-1.145
0.
0.
0.
0.
1.
1.
1.
1.
000
930
957
995
000 13C12-PeCDD 123
006
019
025
IS3
/*no •Bol l .&•„•*•
8.35
65.54
210.58
32.20
33.99
10.21
103.82
64.46
13.22
24.63
28.79
1.41
577.23
37
112
18
18
57
35
'9
12
15
.68
.30
.41
.18
.53
.60
.70
.71
.98
27
98
13
15
46
28
5
11
12
0.
.86
.28
.79
.81
.29
.86
.90
.92
.81
958-1.051
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
963
968
973
978
983
997 123478-HXCDF
000 123678-HxCDF
004
Oil
018 234678-HxCDF
021
AN
AN
AN
0.868-1.132
24.69
1,607.85
1,872.93
1,372.74
1,300.14
559
623
469
437
.51
.88
.24
.48
1,048
1,249
903
862
.34
.05
.50
.66
0.
0.
1.
1.
1.
000
997 13C12-HXCDF 478
000 13C12-HXCDF 678
018 13C12-HXCDF 234
042 13C12-HXCDF 789
SUR3
134
ALT2
ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:1710/21/97
-------
Page No.
10/21/97
Listing of U973260B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
4 Peaks
6,153.66
HxCDD
390-392
K
X
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
MX
408-410
13C12-HpCDP
418-420
418-420
HpCDD
424-426
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
WH
WH
WH
3
NL
WL
SN
SN
4
NL
SN
SN
1
NL
SN
2
NL
SN
SN
WH
0:00
29:40
30:09
30:22
30:56
31:00
31:11
31:19
31:36
31:41
31:47
Peaks
0:00
29:45
30:55
30:59
31:11
31:18
31:29
31:36
Peaks
0:00
33:03
33:16
34:16
Peak
0:00
33:03
33:21
34:16
Peaks
0:00
33:18
33:54
34:08
1.
RO
RO
RO
RO
RO
1.
RO
RO
RO
0.
RO
RO
0.
RO
RO
0.
RO
RO
RO
RO
05-1.43
0.64
1.39
1.12
1.34
1.17
0.94
0.69
1.35
1.09
0.34
2.93
05-1.43
1.43
0.31
1.25
1.14
1.23
1.17
0.47
0.19
88-1.20
1.11
1.04
1.70
1.23
37-0.51
0.84
0.42
0.73
0.43
88-1.20
1.33
0.76
0.62
0.59
ax^u
4
20
45
28
10
8
2
14
3
1
1
94
8
1
1,398
1,597
11
2,707
24
15
.46
.51 11.94
.98 24.29
.27 16.20
.94
.96
.17
.71
.64
.84
.37
.76
.61
.39
.49 775.88
.71 852.68
.60
.98 1,461.46
.26 13.43
.75
0.
8.57
21.69
12.07
0.
622.61
745.03
1,246.52
28.51
952-1.015
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
958
973
980
998 123478-HXCDD
001 123678-HxCDD
006
Oil 123789-HXCDO
020
023
026
AN
AN
AN
968-1.032
0.
0.
0.
1.
1.
1.
1.
1.
000
960
998 13C12-HXCDD 478
000 13C12-HXCDD 678
006
010 13C12-HXCDO 789
016
020
SOR4
IS5
RS2
5,728.44
5
16
8
6
16
9
1,226
18
1,053
2,280
HpCDi
3
13
8
1
.58
.84 8.59
.34
.81
.84
.88
.83 363.96
.53
.28 314.82
.11
.81
.61
.89
.79
0.
8.25
0.
862.87
738.46
0.
996-1.043
0.
1.
1.
1.
000
000 1234678-HpCDP
007
037 1234789-HpCDF
AN
AN
939-1.121
0.
1.
1.
1.
000
000 13C12-HpCDF 678
009
037 13C12-HpCDF 789
IS6
SUR5
977-1.005
0.
0.
1.
1.
000
982
000 1234678-HpCDD
007
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:17 10/21/97
-------
Page No.
10/21/97
Listing of U973260B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Nam*.. ID.. Flags.
424-426
0 Peaks
0.00
13C12-HpCDD 0.88-1.20
436-438 DC NL 0:00 RO 1.30 9.85
33:54 0.96 1.763.70
DC SN 34:24 RO 2.18 5.30
436-438 1 Peak 1,763.70
863.44
0.971-1.029
0.000
900.26 1.000 13C12-HpCDD 678 IS7
1.015
OCDP
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
1
NL
WH
WH
1
0:00
33:34
36:07
37:14
37:17
37:27
37:32
37:38
37:51
37:54
38:49
39:17
39:40
39:49
39:55
Peaks
0:00
36:27
36:47
36:58
Peak
0:00
36:26
36:49
36:58
Peak
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
RO
RO
0
RO
RO
.76-1.02
1
2
1
3
1
0
0
1
0
0
2
0
1
1
1
.01
.16
.09
.08
.55
.63
.72
.16
.15
.32
.96
.74
.01
.37
.89
.76-1.02
0
0
3
0
.97
.63
.39
.99
.76-1.02
0
0
1
0
.97
.84
.49
.43
Above: HpCDD / Octa-CDD and CDF Follows
8.20
2.76
6.58
2.46
2.14
5.80
8.96
5.52
2.14
3.27
1.68
11.09
16.74
2.31
2.46
0.00
6.02
19.35
0.83
4.10
19.35
6.52
3,686.48
26.52
18.56
3,686.48
0.890-1.110
0.000
0.921
.991
.022
.023
.028
.030
.033
.039
.040
.065
.078
.089
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.093
1.096
0.890-1.110
0.000
9.11 14.50 1.000 OCDD AN
1.010
1.015
0.995-1.005
0.000
1,678.82 2.007.66 1.000 13C12-OCDD IS8
1.011
1.015
Column Description "Why Code Description QC Log Desc.
H_2 -Nominal Ion Mass(as)
..RT. -Retention Time (nm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
HL-Below Retention Time Window
MH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
OGT
18*00 19*00 20*00 21*00 22*00 23*00
Fil*:U973260 tl-1024 Aeqil7-OCT-1997 18*41*01 OC SI* Voltage SIB 705 Koit»i2622
305.8987 Fl2 BSUB(256,30,-3.0) PKD(9,S,3,0.10\,10488.0,1.00\,F,T) ExptEPCUS2
TRIAKOLE LABS T*XtlSO-K23-3 TLIt43432
ion
so:
18*00 19*00 20,00 21,00 22,00 23,00
Pil*>U973260 tl-1024 Acqt 17-OCT-1997 18,41,01 OC EJ+ Voltage SIR 70S Koie*:2616
315.9419 Fl2 BSVB(256,30,-3.0) PKD(9,S,3,0.10\f 10464.0,1. OO\,P,T) ExptEPCUS2
TRIAKOLE LABS TfxttSO-tS23-3 TLH43432
A1.07E7
•liftU973260 tl-1024 Aoqi17-OCT-1997 18*41*01 OC EH- Voltage SIR 70S Noil*t3503
03.9016 Pt2 BSOB(256,30,-3.0) PKD(9,5,3,0.10*, 14012.0, 1. 00*,P,T) ExptEPCUS2
•RXAKOLE LABS TfJCt: SO-1123-3 TLIt43432
LOOJf A3.2.7*7
80:
eol
401
aol
A.1.31B7
i.32^7-rff -•*»•
/^V/VAA A
A
.4.2E6
-3.4B6
.2.5E6
-1.7B6
.8.4X5
24*00
0. OBO
Hoe
24*00
80.
60:
40:
20:
0.
.0. OEO
Time
,2.0B6
-1.6E6
.1.2E6
.7.9E5
.4. OSS
18*00 19*00 20*00 21*00 22,00 23*00
Fll»tV973260 tl-1024 Acqtl7-OCT-1997 18*41*01 OC El* Voltage SIR 70S Noie»i2268
317.9389 Pl2 BSVB(2S6,30,-3.0) PKD(9,5,3,0.10\,9072.0,1.00*,F,T) SxpiEPCffS2
TRIAKOLE LABS TvetiSO-lO3-3 TLIt43432
IOCS
eol
eol
40:
20:
24*00
0.020
Time
-2.7E6
-2.2E6
.1.6116
.i.ise
.5.4E5
18*00 19,00 20,00 21,00 22,00
Fil»tU973260 tl-1024 Actjt 17-OCT-1997 18,41,01 OC EI+ Voltage SIR 70S
330.9792 Pt2 ExptEPCUS2
TRIAKOLE LABS Text>SO-H23-3 TLXt43432
100*
23*00
24*00
O.OFO
Time
lf^*^w^^
23,53
18,00 19,00 20*00 21*00 22*00
Fll»tU973260 tl-1024 Acy:17-OCT-1997 18*41*01 OC EI+ Voltage SIR 70S
375.8364 Ft2 Exp:EPCUS2
TRIANBLE LABS Taxti3O-t!23-3 TLIt43432
21 f 45
19155
23*00
24«00
IOCS
80:
60.
40:
20:
0.
_8.9S7
17.2B7
-.5.4E7
.3.6E7
.1.8E7
Lo. 050
Tim*
4.8S4
"47
ISiOO
19*00
20 »00
21*00
22*00
23*00
0.050
-------
Pll»iU973260 91-1024 Acqt 17-OCT-1997 18*41*01 OC EH- Voltag« SIR 70S Soi8»tl742
319.8965 Pt2 BSVB(256,30,-3.0) PXD(7, 5, 3,0.10*, 6968.0,1. 00*,P,t) ExpiEPCUS2
TRIAHQLB LABS TEPCUS2
TRIANGLE LABS T*XttSO-H23-3 TLI943432
ion
80:
60:
40.
20:
I
I A3.68S6
\ A
"T6 \ Al-?9B6
\ \ \ A1.02E6 A
\ / I A9.10S5 I \ UL-89B6 ». l\ A6.73ES
I V I V .A ./ IPV A /T VA Af-«- _ .
.7.025
.5.6ES
.4.2E5
.2.025
.1.425
0.020
20*00 21>0o' '22*00 23*00 ' ' 24*00 Mm*
Pllf>U973260 91-1024 Aeqil7-OCT-1997 10*41*01 OC EH- Voltagu SIR 70S Sol f»i 4140
331.9368 Fi2 B3VB(256,30,-3.0) PXD(7,5,3,0.10*,16560.0,1.00*,P,T) SxptEPCUS2
TRIANQLB LABS TmxttSO-H23-3 9LI943432
ion\
80:
60:
40.
20.
A1.77S7
n
ft
I \A1.13E7
A
/ V7 v
.3.6X6
.2.9E6
.2.2S6
'•.1.SE6
17.325
• 0. 020
'20*00' ' ' '21«00' ' ' ' '22*00 23*00 24*00' Tim*
Pil»tO973260 91-1024 Acqt 17-OCT-1997 10*41*01 OC 2J+ Voltagt SIR 70S Nolt»tl846
333.9338 Pt2 B3UB(256,30,-3.0) PXD(7,5,3,0.10X,73a4.0,1.00*,P,T) EXptSPCUS2
TRIANGLE LABS TvttiSO-H23-3 TUt 43432
ion
80:
60:
40:
20:
o:
A2.21S7
ft
IUl.<5B7
r A
/ U V
-4.6E6
'-.3.7S6
'-.2.8X6
'-.1.8X6
15.225
• o.oxo
'20*00 21*00 22*00' ' ' ' '23*00 24*00' «a»
P110IU973260 91-1024 Acqt 17 -OCT- 19 97 10*41*01 OC EH- Voltagt SIR 70S Noit»i2409
327.8847 Pi2 B3UB(256,30,-3.0) PXD(7,5,3,0.10*,9636.0,1.00*,P,T) ExptSPCUSS
TRIANQLB LABS T»xttSO-H23-3 VLI943432
100*
80.
60.
40:
20.
o:
A2.10B7
A4.12S6
/V I V
-4.4S6
.3.525
.2. 725
.1.025
.8.025
0.020
'20*00 ' 21*00 22*00 23*00 24*0o' Timt
Pll»t0973260 91-1024 Acqi 17-OCT-1997 10*41*01 OC XH- Voltag* SIR 70S
330.9792 Pt2 XxpiXPCU32
TRIAmtiX LABS T«tC»SO-J€23-3 TLI943432
100*
00:
60:
40:
20.
o.
^l^t^---^^^^
_7.«27
'
.6.1X7
.4.6X7
.3.027
.1.527
O.OXO
20*00 21*00 ^22»0o' ^ ' '23«00' ' ' " "" 24\00 Tiou
-------
Pll»tU9732SO tl-1024 Acqil7-OCT-1997 18(41,01 OC El* Voltage SIR 70S Woise*1843
339.8597 Pi2 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,7372.0,1.00*,P,T) Sxp:EPCUS2
TSIASOLE LABS TucttSO-M23-3 TLI043432
100*
ao:
60:
40:
20:
o:
A5.11E6
•JWA J\ A A "AT
.4.6E6
.3.6B6
.2.7B6
.1.8SS
.9. IBS
O.OBO
24*00 25*00 2«,00 27,00 ' '28,00 ' Time
Pll«tU973260 01-1024 Aaqil7-OCT-1997 18,41,01 OC SI* Voltaga SIS 70S Nois*i2130
341.8567 Pi2 BSV3(256,30,-3.0) PXO(7, 5,3,0. 10*,8520. 0,1. 00*,P,T) BxptBPCUSS
TRIANGLE LABS T»xti3O-M23-3 TLI043432
ion
80:
60:
40:
20:
o:
Al 33S7
A
/I A A « *A A2.08E6 A1.91E6
l\ J\l lA-jswA /AAA /v/v
-2.8B6
'•.2.2B6
.1.7B6
-1.1B6
.5.6B5
O.OBO
24*00 25*00 2*»00 27*00 ' ' 28*00 ' Tia»
Pll»iO973260 01-1024 Aaqt 17-OCT-1997 18,41*01 OC EI+ Voltage SIR 70S So±mm*1223
351.9000 Pt2 BSVB(256,30,-3.0) PSD(7f 5,3,0. 10*,4892. 0,1. 00*,P,T) BxptSPCUS2
TSIASOLE LABS T»xt t 3O-M23-3 TLI043432
100*
•
80:
60:
40:
20:
A2.QOE7
n A1.57B7
Jl
1
/I / V
_5.fiBff
.4.4E6
.3.3BS
-2.2S6
.1.1E6
'•O.OBO
24*00 25*00 26iOo' ' ' ' 27,00 ' ' 28,00 ' ' Time
FllutU973260 01-1024 Acqt 17-OCT-1997 18*41*01 OC BI+ Voltage SIR 70S Soln»t2113
353.8970 P*2 BSVB(256,30,-3.0) PSD(7,5,3,0.10Xr8452.0,1.00*,P,T) BxpiBPCVS2
TRIANGLE LABS TvtttSO-M23~3 TU043432
loot
so:
60:
40:
20-
a-
A1.3857
I "'f'*7
ft
/I ; V
-3.8B6
'-3.1B6
.2.3E6
.1.5E6
'•.7. TBS
O.OSO
24,00 25,00 26tOO 27,00 28,00 Tim»
PilftO973260 01-1024 Aaqtl7-OCf-1997 18,41,01 OC SI* Voltage 3IR 70S
330.9792 7(2 BxpiEPCUS2
TRIASQLB LABS T»XtiSO-H23-3 TLX043432
ion
80.
60.
40.
20.
0
~^^*»*l^fl^v*v^^^
~^^-VV^^~^^~-W*^AS^*>^*^^^^ ^VAV^AV'
C7.9B7
.6.3B7
-4.7B7
•-3.2B7
.1.6B7
'• o. oso
24*00 25*00 ' ' 26tOO 27,00 ' ' ' '28*00 ' ' Tlae
PllftU973260 01-1024 Aeyt 17-OCT-1S97 18,41,01 OC SI+ Voltage 3IR 70S
409.7974 Pt2 ExptEPCUS2
TRIANGLE LABS Tuxt I SO-H23-3 TLI043432
ion
80.
60.
40.
20.
0.
24*37 2tf,00 "
1 1 25*45 1 1 26t48 27il9 27t44
JT4.01 1 . I 25,35i «'« I , j, * 1 28,24
IH A".'2fi lul JU . «»^I LJUL , A. lA /W/LnH.*7M L ,1 1« 1 - i
"\v\jW VV*VvA"r y>"^ ^nVA/^NA-wflrv/v '^/' v>'''AJ1 Vv\p^\/\V/ \y/ " V ruiA/NV VJIVT*^''Vv UV^
5.824
'-.4.7E4
.3.524
.2.3E4
11.224
• o. oso
24,00 25,OO 29,00 27\00 ' ' ' 2e'tOo' ' ' ' rime
-------
F1101U97326O 91-1O24 Acqt 17-OCT-1997 10*4.1*01 QC SI* Voltage SIS 703 NolB*t2359
355.8546 ft 2 BSUB(256,30,-3.0) PXD(5,5,3,0.05*,9436.0,1.00*,?,T) ExpiEPCUS2
TRIABGLB LABS Text t SO-U23-3 TLIJ43432
10091
801
60.
401
20.
A2.11E6
A A1.26E6
/ I
A Al 02X6
A '
1 Ime ia~* \ A4.85E5
\ P'i8*5 I A A4.24ES
II 9 cc B I I i\ I A3 85E5 l\ f\ A3 . 72E5
.4.8ES
.3 . 8E5
.2.9ES
.1.9E5
.9.5E4
O.OSO
26tOO 37*00 ' ' ' 30*00 Tiaa
Plle>U973260 #1-1024 Acqtl7-OC7-1997 18t41t01 OC BZ+ Voltage SIR 703 Noia«il799
357.8516 Pi2 BSUB(256,30,-3.0) PKD(5,5,3.0.0S\,7196.0,1.00\,P,T) BxpiEPCUS2
TRIAKOLS LABS Text t SO-H23-3 TLIf 43432
10C»
801
60.
401
201
A3. 31X6
A
fl
1 A9.7BXS
\ A A6.76E5
\ A3. 50X5 l\ A
\ A / f3-*3*5 \ A3.00E5 A2.61E5
\ /\ A1.74X5 \ \ /N / \ .. /\A1.38X5 A A. A1.10BS
J \. JX_ JuvJ.^y W v_y \_> — rV^JTt^C /V.JV- . s^ ^
.5.7X5
.4.6X5
.3.4X5
.2.3X5
26tOO 37*00 ' 30*00 ' ' ' Mm*
PH0IU97326O §1-1024 Acqtl7-OCT-1997 10(41*01 OC Xlf Voltage SIR 70S Holm ft 2454
367.8949 Pi2 BSOB(256,30,-3.0) PXD(5,5,3,0.05*,9B16.0,1.00\,P,T) E*ptXPCVS2
TRIASOLS LABS Text t SO-M33-3 TLH43432
looa
00J
601
401
201
O
A1.18B7
L '
/ r^r
-3.8X6
.3.1X6
-2.3E6
'.1.5X6
.7.6X5
' O.OSO
26*00 27 tOO 30*00 Time
Fil»iO973260 §1-1024 Acq:17-OCT-1997 10*41*01 OC EH- Voltage SIR 703 Noise 1 1537
369.8919 P:2 BSUB(256,30,-3.0) PXD(S,S,3,0.05*,6148.0,1.00X,P,T) ExptEPCUSS
TRIASOLE LABS TfXt : SO-M23-3 TLH43432
IOCS
801
60.
401
20.
0
A8.40X6
i
I
/ U7.77S5
/ vy\
-2.6X6
.2.1E6
.1.6X6
.1.0X6
.5.2X5
0. OSO
26\00 37*00 30*00 ' ' ' Tlttf
PllmiU973260 §1-1024 Acqtl7-OCT-1997 10*41*01 OC XI-f Voltage SIR 70S
330.9792 Vi2 KxptZPCUSS
TRIANOU LABS Text 1 3O-M23-3 TLI§43432
ion
80.
60.
40.
20.
0.
35*57 26*45 37*41
V^X-vvrvs^^ -Vv^N^v^^— ^^V-^AA/^^^^^^^^^
r7.9X7
.6.3X7
.4.7X7
.3.2X7
'.1.6X7
O.OSO
26tOO 37*00 30*00 Time
-------
P±letU973260 #1-403 Aaqtl7-OCT-1997 10(41(01 SC EH- Voltage SIR 70S Soiao:230B
373.8208 Pi3 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,9232.0,1.00*,P,T) Exp:BPCUS2
TRIANGLE LABS Text:SO-M23-3 TLH43432
100*
sol
so:
40:
20.
A1.12E6
|
J
A3. 7755^ A5.7555
AjL. /ill „,„,
j vy v~/v_/v^-^ . / \f v-«t. .rv_r*v_ . - - - —, -
.3.755
.3.055
.2.255
.1.555
.7.454
O.OEO
25(00 30(00 ' 31(00 32(00 Tim*
PlletU973260 91-403 Acqtl7-OCT-1997 18 : 41 1 01 OC EH- Voltage SIR 70S Noiee:2506
375.8178 P*3 BSUB(2S6,30f-3.0) PXD(7,5.3.0.10\,10024.0,1.00*,P.T) BxptEPCUS2
TRIANGLE LABS TexttSO-M23-3 TLH43432
10«
00J
sol
40:
20:
A5.0355
|
J I A4.63E5
A2.79BS: A
A ] A1.5055 A A 3gss
J \ 1 \ -v A /I I*?'90B4 A1.28B5
f \J V_X>_y \^ ^ -/ \JV^— -S~*L- _A-Vn - --ntft j, ,-.-, _ -
.3.155
.2.555
.1.555
.1.355
_ff.354
O.OBO
29 tOO • • • • 30l0o ' ' 31(00 32(00 Time
PiletU973260 §1-403 Acqt 17 -OCT- 1997 10(41(01 OC EH- Voltage SIR 70S Noiaet4114
383.8639 Pt3 BSUB(256,30,-3.0) PXD(7,5,3,0.10X.16456.0,1.00*,P,T) Exp:EPCUS2
TRIANGLE LABS TextiSO-M23-3 TLIf 43432
lOOJj
00:
so:
40:
20:
AS.24S6
\ 1 A4.69S6 A4.37S6
fl A
U \
y Y v y v / v
-2.2E6
li.ass
-.1.3E6
L0.555
14.555
25(00 30(00 31(00 32(00 Time
Pile:U973260 #1-403 Acqt 17 -OCT- 1997 18(41(01 OC SH- Voltage SIR 70S SoiaetB232
385.8610 Pt3 BSUB(256,30,-3.0) PXD<7,5,3,0.10*,32928.0, 1.00*,P,T) Exp:BPCUS2
TRIANGLE LABS T»XttSO-M23-3 TLH43432
100*
80:
sol
40:
201
A1.2557
fl 11 A5.035ff A0.«Sff
A A
y
/ V V y V / v
..4.3E6
.3.455
.2.655
.1.75*
.8.SBS
25(00 30(00 31(00 32(00 Time
Pile:U973260 tl-403 Acq: 17 -OCT- 19 97 10(41(01 OC EH- Voltage SIR 70S
392.9760 Pt3 BxptBPCUS2
TRIANGLE LABS TextiSO-M23-3 TLH43432
IOOS
aoj
sol
401
201
01
31j04 ,, nf 31 1 SO
-
3.657
12.557
12.257
.1.457
.7.255
0.050
25(00 30(00 ' ' ' 31(00 ' 32(00 Time
PlletU973260 §1-403 Acqt 17 -OCT- 1997 10(41(01 OC 5X+ Voltage SIR 70S
445.7555 Pt3 ExptEPCU32
TRIANGLE LABS Text i SO-H23-3 TLIf 43432
ion
80.
SO.
40.
20.
0.
^ArMAAA^AAM^A^^
_4.354
E.3.554
.2.654
.1.754
.0.753
O.OSO
25(00 30(00 31(00 ' ' 32(00 Time
-------
'110IU973260 fl-403 Aoqs 17-OCT-1997 18:41:01 OC SI* voltage SIR 70S Noise:1235
389.8156 Pt3 BSUB(256,30, -3.0) PKD(7,5,3, 0.10\,4940.0,1.00*.P,T) Exp:EPOJS2
TRIANGLE LABS TexttSO-M23-3 TUf43432
1009
25(39 25(48 30(00 30:12 30(24 30(39 30(48 31(00 31(12
PilmiU973260 91-403 Acqt 17-OCT-1997 18(41(01 OC ST+ Voltage SIR 703 Noiae:1923
391.8127 Pi3 BSOB(256,30,-3.0) PXD(7,5,3,0.1OX,7692.0,1.00*,P,T) ExpiEPCUS2
TRIANGLE LABS T*Xt:SO-M23-3 TLI943432
100H A2.J.7B5
31:24 31(39
25(39 25(48 30(00 30(12 30(24 30(39 30(48 31(00 31(12" 31(24
Pile:U973260 91-403 Acqil7-OCT-1997 18(41(01 OC 5J+ Voltage SIR 70S Boise: 2537
401.8558 Pi3 BSOB(2S6,30,-3.0) PXD(7,S, 3, 0.10\f 10148.0,1.00\tP,T) S*piEPCU32
TRIANOLB LABS Text:SO-U23-3 TLX943432
IOC* A1.46B7
80.
60.
40.
20.
31(3tf
25(39 25(48 30(00 30(12 30(24 30(39 30:48 31:00 31(12 31:24
Pil»tV973260 91-403 Aeqt 17-OCT-1997 18(41(01 OC EH- Voltage SIR 70S Noioetl769
403.8529 Pi3 BSUB(2S6,30,-3.0) PXD(7.5,3,0.10*,7076.0,1.00*,P,T) Exp:EPCUS2
TRIAmLS LABS Text:SO-M23-3 TLH43432
100H A1.2SB7
31(39
80.
60.
40.
20.
A7.45E6
25(39 25(48 30(00 30(12 30(24 30(39 30(48 31(00
File:0973260 91-403 Aaqi 17-OCT-1997 18(41(01 OC KT* Voltage SIR 703
392.9760 Pt3 Bxp:SPCUS2
TRIANGLE LABS Text:SO-M23-3 TU943432
100H 31:04
80.
60.
40.
20.
0.
31(f12 ' 31(24 31(39
25(39 ' '25(48' ' '30(do' ' '30(12' ' '30(24' ' '30(39 ' '30\48 ' 's'l'tOO ' '31(12' ' '31(24'
31(39
.050
time
.4.559
13.559
.2.559
12.059
.5.855
0.050
Tine
,.4.259
.3.459
.2.559
.1.759
.8.455
0.050
Tim*
_3.957
.2.557
12.257
.1.457
.7.259
0.050
Tim
-------
•Ila*a973260 #1-596 Acq: 17-OCT-1997 18:41:01 QC Bit Voltago SIR 70S NolBf*1463
107.7818 P*4 BSUB(256,30,-3.0) PKD(7,S,3,0.10*,5852.0,1.00*,P,T) Exp*EPCUS2
TRIANGLE LABS T«XtiSO-M23-3 TLI#43432
100H A1.43S5
33*00 33i13 33*24 33:36 33,48 34*00 34tl2 34t24
Pll»*U973260 #1-596 Aaq*17-OCT-1997 18*41*01 OC ST+ Voltoff* SIR 70S SOie»*1327
409.7789 Ft4 BSUB(256,30,-3.0) PXD(7, 5,3,0.10*, 5308.0,1.00X,P,T) ExptEPCUSS
TRIASOLB LABS T«xt*SO-M23-3 TLI043432
lOOtl A1.01ES
33'tOO 33*12 33*24 33i36 33/48 34tOO 34tl2 34t24
Pll«tU973260 il-596 Acq: 17-OCT-1997 18:41:01 OC BX+ VolCag* SIR 70S Nols«t2868
417.8253 P:4 BSOB(2S6,30f-3.0) PXD(7,S,3,0.10*,11472.0,1.00*,P,T) Exp:BPCUS2
TRIANOLB LABS ToxtiSO-M23-3 TLHt43432
34:36
34:36
ion
BO:
60.
40:
20:
A3.64ES
A3.15S6
33:00 33*12 33i24 33:36 33:48 34:00 34tl2 34:24
PllmtU973260 *l-596 Aeytl7-OCT-1997 18t41t01 OC SI* VolCajr* SIR 70S Soimmt3430
419.8220 P:4 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,13720.0,1.00\,P,T) Exp:EPCU32
TRIANOLB LABS T»xt:SO-H23-3 TLI*43432
ion
ao:
fol
40:
20:
A8.S3E6
A7.38S6
33:00 33:12 33:24 33:36 33:48
Pll»tV973260 tl-596 Acytl7-OCT-1997 18i41i01 OC SIf
430.9729 Pt4 Exp:EPCUS2
TRIANOLB LABS T*xt:SO-M23-3 TLI*43432
100H
40:
20:
o:
34:00 34:12
SIR 70S
34*24
33*00 33*12 33*24 33*36 33*48 34*00 34*12
Pll*tU973260 01-596 JLcy:17-OCT-1997 18*41*01 QC EH- VolCag. SIR 70S
479.7165 P*4 Exp:BPCUS2
TRIANOLB LABS TucttSO-M23-3 TLIt43432
ion
80:
60:
40:
20:
0.
34*24
34*20
33*04
33*42
33*23
33*53
34*11
33*00
33*12
33:24
33*36
33*48
34*00
34*12
34*24
34*36
34*36
34*37
34*36
1.2E6
9.3S5
.6.9S5
.4.6B5
.2.3E5
O.OEO
Tin*
2.9B6
2.3E6
1.7E6
.1.2S6
,5.8E5
.O.OEO
Time
.2.7E7
.2.1E7
.1.6B7
.1.1S7
.5.3S6
O.OBO
Tim
5.4E4
4.3S4
3.3E4
2.2E4
1.1S4
O.OEO
Tim
-------
'110:U97326O #1-596 Acg:17-OCT-1997 18:41:01 OC El* Voltage SIS 70S SolB»tl246
423.7766 Fit BSUB(256,30, -3.0) PKD(7, 5,3, 0.10X, 4984.0,1.OOX,P,T) Exp:EPCUS2
TRIASOLE LABS TuctiSO-M23-3 TLIS43432
100H A6.94E4 A4.53E4
so:
33:12 33'tlB 33't24 33(30 33i36 33:42 33:48 33:54 34:00 34:06 34:12 34:18
P±lftU973260 fl-596 Aaytl7-OCT-1997 18:41:01 QC EH- Voltafff SIS JOB Nola»:934
425.7737 P:4 BSUB(256,30,-3.0) PXD(7,S,3,0.10*,3736.0,1.00X,P,T) Exp:EPCUS2
TRIANOLB LABS T»Xt:SO-H23-3 TLH43432
100* A7.32X4
O.OEO
'34\24 Tima
33:12 33.18 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34i06 34:12
F±lu:U973260 *1-S96 Acy: 17-OC7-1997 18:41:01 QC SH- Voltiff» SIR 70S Ko±t»t314S
435.8169 P:4 BSUB(256,30,-3.0) PKD{7,5,3,0.10*, 12580.0,1.00*,P,T) BxpiEPCU32
TRIANGLE LABS Tuxt:3O-K23-3 TLIJ43432
100* AB.63E6
80.
60.
40.
20.
0.OSO
'34'tia ' '34\24 Tia*
.2.4E6
.1.8B6
.1.2X6
'.6.1S5
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33.12 33(18 33.24 33.30 33:36 33:42 33(48 33.54 34.00 34:06 34:12
Pll»:V973260 91-596 Actji 17-OCT-1997 18(41(01 OC ST+ Voltag* SIR 70S Noit»:2417
437.8140 Pi4 BSUB(256,30,-3.0) PKD(7,S,3,0.10\,966B.O,1.00\,P,T) Exp:EPCUS2
TRIANGLE LABS T»Xt:SO-tt23-3 TLX943432
100\
80.
«o:
40.
20.
A9.00S6
34:18 34:24 Tifflo
3.1E6
'.2.5E6
'.1.9E6
.1.3X6
'.6.3SS
33/11 33»ltf
33.12 33.18 33i24 33.30 33«3ff 33.42 33.48 33.54 34.00 34.Of 34.12 34.18
P±1»:U973260 91-S96 Acq:17-OCT-1997 18(41(01 OC EH- Voltage SIR 70S
430.9729 Pi4 gxp:SPCU32
TRIAmLE LABS T»Xt:SO-N23-3 TLI043432
IOCS
80.
60.
40.
20.
o:
O.OEO
34i24 Tim*
.2.7X7
.2.1X7
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.1.1X7
.5.3X6
'33(12 ' '33llB ' '33(24 ' 33(30 ' 33(3* ' 33(« ' '33(48 ' 33(54 ' 34(00
0. 0£0
-------
'ilatU973260 #1-596 Acqi 17-OCT-1997 18i41t01 OC EH- Voltage SIR 70S Noia0i2067
41.7438 Pt4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10%, 8268. 0,1.00\,P,T) BxptEPCOS2
TXIANOLB LABS TextISO-K23-3 TLI«43432
100H
33*00 34(00 3SJOO 36tOO
PllttU973260 01-596 Acqtl7-OCT-1997 18t41tOl QC BH-
443.7399 Pt4 BSVB(256,30,-3.0) PXD(7,5,3,0.10*,8132
TRIANOLE LABS T«xtjSO-M23-3 TLI1t43432
lOCSt
37tOO 38tOO
Voltage SIR 70S Nole»t2033
0,1.00\,P,T) SxptSPCUS2
39100
33>00 3<»00 35>00
P110tU973260 fl-596 Aeytl7-OCT-1997 IB141101 OC EH-
430.9729 Ft4 ExptBPCUSS
TRIANOLS LABS T9XttSO-H23-3 TLI943432
10OH
37tOO 38(00
Voltaym SIR 70S
39 tOO
.0. OBO
rlma
33(00 34,00 35,00 36,00
Pll»t0973260 fl-596 Aaqtl7-OCT-1997 18(41(01 OC EI+
513.6775 Pi4 ExptEPCU32
TRIANQLB LABS TuctiSO-H23-3 TLIt43432
100H
37,00 38,00
Voltajr* SIR 70S
37 06
39:00
33 tOO
34100
35(00
3f(00
37(00
30(00
39(00
-------
'H»lU9733SO 91-596 Acqi 17-OCT-1S97 18:41:01 IK EH- VOltaff SIR 70S NOlao:14Sl
457.7377 Pt4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,5924.0,1.00*,P,T) Sxp:EPCffS2
TRIANOLE LABS T*xt:SO-M23-3 TLI943432
100* A1.26E5
80.
60.
40.
30.
36,18 36:24 36i30 36:36 36:42 36:48
Pil»iV973260 *l-596 Aaqtl7-OCT-1997 18:41:01 OC EI+ Voltafft SIR 70S Noiimtl531
459.7348 Pi4 BSUB(256,30,-3.0) PKD(7,5,3,0.10X,6124.0,l.OO\,f.T) XsptSPCUS2
UiaLS LIBS Toxt:SO-M23-3 TLI043432
100* A1.J7SS
36:18 36:24 36:30 36:36 36:42 • -36:48
PiluiV973260 91-596 Ac
-------
Peak Locate Examination:17-OCT-1997:18:40 File:U973260
Experiment:EPCUS2 Function:2 Reference:PFK
-------
File
303.
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:U973260 #1-1024 Acq: 17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
9419 F:2 Exp:EPCUS2
le Text:SO-M23-3 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
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-------
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS2
Sample Text-.SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%
80 J
60 J
40 J
20 J
21:00 22:00 23:00
File:U973260 #1-1024 Acq: 17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS2
Sample Text-.SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%
80 J
60 J
40 J
20 J
21:00 22:00 23:00
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% 22;17
60J
40 J
20J
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22:32
4.5E5
3.6E5
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.6.0E5
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21:00
22:00
23:00
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-------
File:U973260 #1-1024 Acq;17-OCT-1997 18:41:01 6C EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
CO
cc
21:00 22:00 23:00
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
80J
60J
40J
20J
A2.25E6
80 j
60 j
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21:00 22:00 23:00
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EH- Voltage SIR 70S
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 22;17
80 J
60 j
40 j
20 j
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22:32
4.5E5
3.6E5
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23:00
3.7E6
2.9E6
2.2E6
1.5E6
7.3E5
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-------
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%
80 J
601
40 J
20 j
21:00 22:00 23:00
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%
80 J
60 J
40 J
20J
21:00 22:00 23:00
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EH- Voltage SIR 70S
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% 22;17
80 J
60 J
40 J
20J
OJ
22:32
.4.5E5
.3.6E5
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.1.8E5
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21:00
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23:00
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-------
File;U973260 #1-1024 Acq;17-OCT-1997
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File
100%
80 j
60 j
40J
20J
18:41:01 GC EI+ Voltage SIR 703
Text:TRIANGLE LABORATORIES, INC.
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25:48 26:00 26:12 26:24
File:U973260 #1-1024 Acq:17-OCT-1997
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File
100%
80 j
60 J
40 j
20J
OJ
26:36 26:48 27:00 27:12 27:24 27:36 27:48
18:41:01 GC EI+ Voltage SIR 70S
Text:TRIANGLE LABORATORIES, INC.
25:48 26:00 26:12 26:24
File:U973260 #1-1024 Acq:17-OCT-1997
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File
oo% 26
80 J
60J
40 J
20 J
OJ
26:36 26:48 27:00 27:12 27:24
18:41:01 GC EI+ Voltage SIR 70S
Text:TRIANGLE LABORATORIES, INC.
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-------
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES,
100% A3.67E6
80 J
60 J
40 j
20J
70S
INC.
0.
25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES,
100% A2.44E6
80 j
60 j
40 J
20 J
27:24
70S
INC.
27:36 27:48
25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 26;
27:07
80j
60J
40 J
20 j
27:36 27:48
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25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48
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Time
-------
File:U973260 #1-403 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 29:07
29100 30100 31:00
File:U973260 #1-403 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 29;07
3200
29:00 30:00 31:00
File:U973260 #1-403 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
32:00
20 j
0
29OO
sooo
31: OO
32 00
O.OEO
Time
O.OEO
Time
2.5E4
2.0E4
1.5E4
1.0E4
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-------
GO
:01 GC fil+ Voltage SIR 70S
:TRIANGLE LABORATORIES, INC,
File:U973260 #1-596 Acq:17-OCT-1997 18:41
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text
100% A8.59E4
80J
60J
40 J
20 j
OJ
33:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text
100%. A8.25E4
80J
60 J
40J
20J
34:00
:01 GC EI+ Voltage SIR 70S
;TRIANGLE LABORATORIES, INC,
OJ
33:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41;
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:
100% 33j03
34:00
01 GC EI+ Voltage SIR 70S
TRIANGLE LABORATORIES, INC,
34:16
35:00
35:00
4.9E4
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Time
5.2E4
4.1E4
3 . 1E4
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Time
33:00
34:00
35:00
.1.2E6
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.7.0E5
.4.7E5
.2.3E5
.O.OEO
-------
File;U973260 #1-596 Acq;17-OCT-1997 18;Alt01 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text;TRIANGLE LABORATORIES, INC.
100& 33:1833:
32:33 _„ i |y, 1 34:16
34:08 A 34;37 34:59
8CL
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33:00 34100 35:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100* ,,..,0 33:54
33:00 34:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
lOOi 33;54
80 j
60J
40J
20J
OJ
35:00
O.OEO
Time
33:00
34:00
35:00
.O.OEO
Time
3.1E6
2.4E6
1.8E6
.1.2E6
.6.1E5
.O.OEO
Time
CD
-------
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
457.7377 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES,
100% A9.11E4
80 J
60J
40 j
20J
35:00 36:00 37:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
459.7348 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES,
70S
INC.
38:00
70S
INC.
100%,
80J
60 J
40J
20J
A1.45E5
35:00 36:00 37:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-3 TLI#43432 File Text:TRIANGLE LABORATORIES,
100% 36:26
80J
60 J
40 j
20J
38:00
70S
INC.
5.4E4
4.3E4
3.2E4
2.2E4
1.1E4
O.OEO
Time
6.8E4
.5.5E4
.4.1E4
.2.7E4
1.4E4
.O.OEO
Time
35:00
36:00
37:00
38:00
5.4E6
4.3E6
3.3E6
2.2E6
1.1E6
O.OEO
Time
-------
TLI Project: 43432
Client Sample: SO-23-3
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973638
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
&**I**\C^
Saginaw, MI
M23TRAIN
185-6-3A-C
1.000
n/a
DB-225
Xv$* ^j^$|i
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
IJSi^^fl^r
09/29/97
10/09/97
10/18/97
n/a
U973257
WK
> ^mto*Str;}
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
if*fi*fe^V$
SPC2NF04
XF24087
X973633
n/a
n/a
n/a
fe ^*&*& '
2,3,7,8-TCDF
1.8
0.79 24:34 _
Internal Standard; ^ -
l3C12-2,3,7,8-TCDF
2.4
58.9 40%-130%
0.83 24:32
13C12-1,2,3,4-TCDD
0.81 23:19
Data Reviewer
10/23/97
Page 1 of 1
C2NF.PSR vlOa LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:35 10/23/97
-------
Initial
Date...
Data Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of X973638B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID., nags.
TCDF
304-306 DC NL 0:00
19:46
20:04
20:47
20:56
21:03
21:14
21:31
21:40
21:49
21:59
22:06
22:31
22:36
22:43
23:00
23:06
23:16
23:32
23:45
23:57
24:25
24:34
24:49
25:09
25:18
26:14
26:41
26:45
26:50
27:07
304-306 30 Peaks
13C12-TCDP
316-318 DC NL 0:00
DC WL 19:39
DC WL 21:09
DC WL 23:16
DC WL 23:21
24:32
24:45
DC WH 26:57
316-318 2 Peaks
0.65-0.89
RO 0.57
0.77
RO 1.42
0.78
0.77
0.81
0.88
0.78
0.76
0.69
0.79
0.79
0.83
0.70
RO 1.39
0.77
0.67
0.79
0.75
0.86
0.79
0.86
0.79
0.83
0.75
0.79
0.83
0.82
RO 1.99
0.66
RO 3.76
0.65-0.89
RO 0 . 60
RO 0.32
RO 2.00
RO 0.96
RO 0.97
0.83
RO 0.33
RO 1.91
0.798-1.112
14.27
1,661.40
9.10
2.612.58
1.488.78
1.672.95
1.355.79
833.10
1.173.28
402.29
2.854.09
680.65
1.485.58
915.03
7.29
1.214.31
200.26
821.83
1,049.31
126.58
549.02
538.17
718.21
442.56
379.69
994.30
415.57
7.79
2.89
5.76
11.81
24.630.02
723.10
7.29
1.145.05
649.22
750.51
636.30
366.13
504.75
164.27
1,256.38
300.19
675 . 67
375.48
5.71
526.40
80.14
361.63
448.33
58.66
242 . 40
249.06
316.28
200.83
162.93
438.01
188.51
3.50
3.25
2.28
25.06
938.30
5.14
1,467.53
839.56
922.44
719.49
466.97
668.53
238.02
1,597.71
380.46
809.91
539.60
4.12
687.91
120.12
460.20
600.98
67.92
306.62
289.11
401.93
241.73
216.76
556.29
227.06
4.29
1.63
3.48
6.67
0.000
0.806
0.818
0.847
0.853
0.858
0.865
0.877
0.883
0.889
0.896
0.901
0.918
0.921
0.926
0.938
0.942
0.948
0.959
0.968
0.976
0.995
1.001 2378-TCDP AN
1.012
1.025
1.031
1.069
1.088
1.090
1.094
1.105
0.959-1.041
12.67
3.93
7.65
5.86
3.96
1,648.32
4.30
15.03
1,652.62
746.51
1.87
901.81
5.68
0.000
0.801
0.862
0.948
0.952
1.000 13C12-2378-TCDP ISO
1.009
1.099
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:54 10/21/97
-------
Page No.
10/21/97
Listing of X973638B.
-------
Fil»tX97363B #1-903 icqtlB-OCr-1997 16*30*40 X S* Voltaga
303.9016 BSUB(2S6,30,-3.0) PKD(S,3,1.0.10\.12423.0,0.00*,P,F)
Sajnplo ToxtiSO-M23-3 TLI*43432 Pilt Tsortr TRZWH3LB L3UB3
100* A1.J.5E7
Auto^pae Soisa*3107
30'tOO 21*00 2atOO 23tOO 24100 25 tOO 26tOO
P11»*Z973638 #1-803 Acg(10-OCT-1957 lf(30(48 OC SI* Voltag* SIR AutoSpao
305.8987 B3UB(256,30,-3.0) PKD{5,3,l,0.10*,21688.0,0.00*rP,F) SxptXCONP_TT
Sanpl* ToxttSO-K23-3 TLIX43432 gilt Ttocti TXUUmS LABS
1009C A.1.47E7
aitoo 22*00 23*00 24*00 25*00 26*00
Pil»*Z973638 tl-803 JLcqt 18-OCT-1997 1ft 30*40 OC JET* Volt ay • SIR JiutoSpoc Soim»*2757
315.9419 BSOB(2S6.30,-3.0) fXD(S,3,l,0.10*.11028.0.O.OO*,P.P) BxptZCONP_TV
Sonplf raxtiSO-M23-3 TLH43432 Pll» Tuctl THIAHOLB UBS
27<00
27JOO
Pil»tI97363B 91-803 Acq*18-OCT-1997 16*30*48 OC SZ+ Voltag* SIR AutoSJ)»c Kblm»*4626
317.9389 BSUB(256,30,-3.0) PKD(S,3,1,0.10^,18504.0,0.00\,P,P) SxpiKONP_TT
Saopl* T»XttSO-H23-3 TLIV43432 Film TfXtt TRIABOUB
Fil»tX973€38 91-803 Acqt 18-OCT-1997 16*30*48 OC SX+ Voltage SIR JLutoSpmo
375.8364 SxptKONP_TT
Saaplf Tmxti30-H23-3 TLH43432 Pil» ttott* BUIBOU IABS
IOC*
.O.OSO
Time
10.050
rlao
009
00J
60.
40.
20.
A7.47S6
11
20»00 21>00 22(00 23iOO 24tOO 25*00 26*00 27*00
.1.8S6
.1.4S6
.1.1S6
.7. OSS
.3.525
Tim*
oca
ao.
60.
40.
20.
JL9.02S6
11
20<00 21 It 00 22(00 22(00 24*00 25(00 26tOO 27(00
.2.0S6
.1.6S6
.1.2S6
.7. 8SS
.3.9S5
Tim*
20*00
21*00
22(00
23(00
24(00
25(00
2«(00
27(00
-------
'ii»tX97363B wi-aoa Acq:iu-ocT-i997 16:30:48 ac EI+ voltage SIR Autospec noisa:i7Oi
319.89SS BSUB(256,30,-3.0) PXD(5,3,1,0.10*,6804.0,0.00*,P,P) ExpiXCOKP__TT
Saapla TaxtlSO-M23-3 TLI043432 Pila TfXtt TRIMBLE LASS
icon
21tOO 22100 23tOO 24:00 25:00
Flit 1X973638 #1-003 AcqtlB-OCT-1997 16i30t48 OC XX+ Voltag* SIR JLutoSpoc So±s»:1813
321.8936 BSOB(256,30.-3.0) PXD(5.3,1,0.10*,7252.0,0.00*,P,P) Xxp:XCOSP_TT
Saoplm r«xt*5O-JC23-3 TLIf43432 Pll» ItorCs TRUOOLB LABS
100K
80.
26100
21tOO 22s00 23tOO 24tOO 25tOO
Silm*X973638 #1-003 t.cqtia-OCT-1997 16t30t48 OC JET* VolCagr* SIX AutoSpmc Soim»t4903
327.8847 BSUB(256,30,-3.0) PKD(5,3,1, 0.10*, 19612.0,0.00*,P,f) ixp»ZCC»P_rT
T«Zt
-------
Pile:X973638 #1-003 Acys 18-OCT-1997 16,30,48 OC EH- Voltage SIR AutoSpec
303.9016 ExpiXCONP TV
Sample TexttSO-M23-3 TLI#43432 Pile Text, TRIANOLB LABS
iota
so:
60:
40:
20:
20(47
1 ^l59
1 i | M(M
I II H I ft Jl i 23>°°
II III II 1 A A ll l\ l\ fl* A 24(34 "A18
20(00 21(00 22(00 23(00 24(00 25(00
Pil»iI97363B #1-003 Acgd0-OCT-1557 16,30,48 OC EH- Voltage SIR AutoSpec
315.5415 BxptKONPjrT
Sample Text,SO-M23-3 TLI*43432 Pile Text, TRIASOLS LABS
ion
00:
50:
4flJ
20:
24<32
. . J V .
20(00 21(00 22(00 23(00 24,00 25(00
Pile ,197363 8 #1-003 Ac
-------
Peak Locate Examination:18-OCT-1997:16:30 File:X973638
-------
jt?.5..4.'..?.....*&*. "Sac1-!.... ?*&^..^ v --^
TLI Project: 43432
Client Sample: SO-23-4
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973261
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-4A-C
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
JfoaJ^V^^'T!*'*"
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6.7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
$ ,
0.12
0.10
EMPC
0.03
0.04
EMPC
0.08
Pg^^ei%'^^ ; J^ft*^
0.74
1.49
0.02
1.26
1.22
0.03
0.80
*" "• ""• ^ ft**E*':'£ *•*
^ •. -rl t"^ s s s
22:30
27:31
31:00
31:18
36:27
^ ^%V:
B_
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
4.1
0.61
0.52
0^6
0.11
0.06
ND
0.07
ND
ND
0.01
0.02
0.01
0.74
1.46
1.50
1.22
1.19
1.27
1.05
21:38
26:19
27:07
30:09
30:16
30:47
33:03
totals :
% .-.V.
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
4.6
1.3
0.41
0.03
43.0
11.3
1.2
0.07
13
9
5
1
15
14
10
1
2.1
0.43
0.05
11.3
Page 1 of 2
X237.PSR V2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:14 10/23/97
-------
,; ;' ,;V ? ^^F^e-^S^^^i^, , ; x;;V£ ;£ ,^/f
TLI Project:
Client Sample:
Internal Standards, ,
13C,2-2,3,7,8-TCDF
13Cr.-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-1,2,3,4,6,7,8-HPCDF
13Cr- 1,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
37Cl4-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
l3C,2-l,2,3,4,7,8-HxCI>D
13Cl2-l,2,3,4,7,8,9-HpCDF
Ait0rnat9 Standards p
> 1 .-!(,
13C,2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards ,
13C,2-1,2,3.4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
43432
SO-23-4
Amfc {ngj \,
2.8
3.3
3.8
4.4
3.4
3.5
2.6
3.4
7.6
fyp&"A>-; Affli Cl^v"
3.6
3.8
4.0
4.1
4.2
y^^^AnirCii^
3.0
3.3
-.^ •• \ •••.•.•. •• s*
< * XXrt-f ss ^ •. ^A--^.\-.O -.5 '*.-.
Method 23
;^ %^/ \% Recowwy A- &C Limits-
69.7
83.5
96.0
110
85.6
87.7
65.1
84.5
95.2
0^^
91.1
95.4
99.0
101
105
ttif&RscoS
75.3
82.5
^£%?*%*
4Q%-130%
4Q%-13Q%
4Q%-130%
4Q%-130%
40%-130%
4Q%-130%
25%-l3Q%
25%-l3Q%
25%-l3Q%
»^||f^tt»tlfe
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
i^tc^^iife:
40%-130%
40%-130%
f^|CC ,^^-
PCDD/PCDF Analysis (a)
Analysis
v .Ratio,
0.75
0.79
1.49
1.45
0.51
1.22
0.42
1.03
0.85
\Y^&*teFr-
1.55
0.51
1.19
0.42
5?rBa8oC^
0.52
0.51
?>t:RattoV'
0.78
1.20
File:
-- irr
21:35
22:30
26:18
27:30
30:15
31:00
33:02
33:54
36:26
A81^
22:32
27:06
30:09
30:54
34:15
; ^-X^fTf^
31:31
30:47
'* \(BT 5
22:16
31:18
U973261
„- o Flags
—
;>,fW»^
—
^fla^
—
rf;^» "
Data Reviewer.
Page 2 of2
10/23/97
X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:14 10/23/97
-------
Initial
Date...
Data Review By:
Calculated Noise Area: 4.66
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of U973261B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
M
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
M
DC NL 0:00
17:43
18:15
18:31
18:57
19:18
19:51
20:14
20:39
21:04
21:22
21:38
22:10
22:26
22:42
23:43
15 Peaks
DC NL 0:00
DC WL 18:50
DC WL 18:57
21:35
22:08
DC WH 22:50
2 Peaks
DC NL 0:00
19:13
19:42
20:07
21:02
21:24
21:52
22:17
22:24
22:30
22:43
22:56
23:13
0.65-0.89
RO 1.53
0.73
0.72
0.68
0.74
0.74
0.76
0.75
0.70
0.73
0.74
0.74
0.78
0.78
0.72
0.73
0.65-0.89
RO 1 . 42
RO 3 . 49
RO 1.95
0.75
RO 0.43
RO 0.45
.__ _____ AHr
0.65-0.89
RO 1.00
0.75
0.79
0.73
0.73
0.75
0.79
0.81
0.66
0.74
0.75
0.78
0.81
9.04
4,217.43
1,838.77
982.99
10,891.24
6,806.53
5,162.02
4,093.17
4,560.00
2,215.57
1,738.07
4,754.83
1,752.93
1,116.57
187.32
97.84
50,415.28
7.12
3.58
5.56
4,350.31
29.70
22.14
4,380.01
wa • TVTO7 /
7VW ! l>\rVr /
6.46
1,430.78
781.91
307.44
1,033.81
517.00
274.43
336.15
505.18
155.26
107.31
181.17
66.26
1,785.67
772.23
397.93
4,617.98
2,891.33
2,224.15
1,748.84
1,880.00
934.04
739.48
2,023.95
766.91
491.02
78.21
41.23
1,867.59
12.92
612.34
345.72
129.51
436.04
221 . 00
121 . 05
150.93
200.74
66.13
46.04
79.46
29.72
0.
2,431.76
1,066.54
585.06
6,273.26
3,915.20
2,937.87
2,344.33
2,680.00
1,281.53
998.59
2,730.88
986.02
625.55
109.11
56.61
0.
2,482.72
30.27
0.
818.44
436.19
177.93
597.77
296.00
153.38
185.22
304.44
89.13
61.27
101.71
36.54
813-1.106
0.000
0.821
0.846
0.858
0.878
0.894
0.920
0.937
0.957
0.976
0.990
1.002 2378-TCDF AN
1.027
1.039
1.052
1.099
954-1.046
0.000
0.873
0.878
1.000 13C12-2378-TCDF ISO
1.025
1.058
848-1.061
0.000
0.854
0.876
0.894
0.935
0.951
0.972
0.990
0.996
1.000 2378-TCDD AN
1.010
1.019
1.032
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Page No.
10/21/97
Listing of O973261B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WH
13
ML
ML
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
KL
SN
SN
SN
4
NL
SN
23:44
23:54
Peaks
0:00
19:11
19:20
19:36
19:44
20:46
20:59
21:08
21:34
21:46
21:50
22:02
22:32
22:45
22:47
22:50
23:02
23:13
23:22
23:27
23:35
23:42
23:45
23:48
23:53
24:02
24:13
24:18
Peaks
0:00
22:16
22:30
22:55
23:13
23:16
23:42
24:00
Peaks
0:00
24:01
24:18
0.84 42.27 19.28
RO 0.40 4.18
5,738.97
5.42
10.98
3.13
20.57
18.75
411.21 411.21
11.46
2.23
8.59
2.42
6.12
1.84
3,570.97 3,570.97
3.94
4.54
4.44
89.32 89.32
5.43
11.78
8.65
6.49
9.81
1.50
4.35
6.83
2.81
5.58
3.64
4,071.50
0.65-0.89
RO 2.73 4.87
0.78 4,488.34 1,970.01
0.79 4,154.02 1,838.72
0.69 89.02 36.37
0.70 36.43 14.96
RO 1.92 17.68
RO 1.22 15.33
RO 4.96 5.89
8,767.81
1.32-1.78
RO 1.00 6.15
1.51 2,163.54 1,302.44
RO 1.05 16.37
22.99 1.055
1.062
0.911-1.089
0.000
0.853
0.859
0.871
0.877
0.923
0.933
0.939
0.959
0.967
0.970
0.979
1.001 37C1-TCDD SDR
1.011
1.013
1.015
1.024
1.032
1.039
1.042
1.048
1.053
1.056
1.058
1.061
1.068
1.076
1 . 080
0.911-1.089
0.000
2,518.33 0.990 13C12-1234-TCDD RSI
2,315.30 1.000 13C12-2378-TCDD IS1
52.65 1.019
21.47 1.032
1.034
1.053
1.067
0.906-1.077
0.000
861.10 0.913
0.924
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Page No.
10/21/97
Listing of U973261B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Name.. ID.. Flags.
A
M
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
DC SN 24:24
DC SN 24:34
24:47
DC SN 24:54
25:10
25:20
25:32
25:42
25:59
26:12
26:19
26:30
26:38
DC SN 26:54
27:07
27:17
27:36
28:10
DC WH 28:21
15 Peaks
DC NL 0:00
25:19
DC SN 25:54
26:18
DC SN 26:28
26:38
27:06
DC SN 27:20
DC SN 27:26
DC SN 27:31
DC SN 28:06
4 Peaks
DC NL 0:00
25:29
26:02
26:18
26:28
26:40
26:51
26:58
27:10
27:19
27:31
27:40
DC SN 27:50
28:02
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
1
5
1
3
1
1
1
1
1
1
1
1
1
0
1
1
1
1
1
.66
.34
.58
.25
.50 1
.49 4
.59 1
.56
.47 1
.50
.46
.54
.60
.52
.50
.46
.61
.29
.17
14
28.37
4.46
58.76
9.00
,093.16
,822.60
,107.39
536.44
,342.12
330.00
803.00
625.42
733.24
12.83
695.59
530.94
88.45
62.12
13.05
,992.77
35.
655.
2,888.
679.
326.
798.
198.
476.
379.
451.
417.
314.
54.
37.
98
13
73
96
58
24
00
00
66
36
56
85
55
76
22
438
1,933
427
209
543
132
327
245
281
278
216
33
29
32-1.78
0
0
0
1
4
1
1
1
1
0
1
.85
.96
.95
.49 4
.13
.06
.55 4
.41
.72
.90
.07
9
ftU.»M. '
3.22
46.85
20.55
,711.36
12.75
37.49
,361.63
28.51
18.25
18.46
15.30
,157.33
n«/>«nn /
32-1.78
1
1
1
1
1
1
1
1
1
1
1
1
2
1
.36
.26
.58
.49
.65
.54
.74
.43
.48
.10
.49
.36
.85
.83
7.16
662.61
75.49
411.65
129.07
287.74
57.67
104.00
129.67
52.89
106.91
61.62
5.89
41.11
28.
2,818.
22.
2,653.
48
45
79
12
29
1,892
21
1,708
.78
.03
.87
.43
.86
.88
.00
.00
.76
.88
.03
.09
.90
.28
0.
.59
.91
.53
.51
0.928
0.934
0.942
0.947
0.957
0.963
0.971
0.977
0.988
0.996
1.001 12378-PeCDF
1.008
1.013
1.023
1.031 23478-PeCDF
1.037
1.049
1.071
1.078
848-1.152
0.000
0.963
0.985
1.000 13C12-PeCDP
1.006
1.013
1.030 13C12-PeCDP
1.039
1.043
1.046
1.068
AN
AN
123 IS2
234 SUR2
402.
46.
246.
80.
174.
36.
61.
77.
32.
64.
35.
29.
76
20
51
31
34
65
14
38
15
01
53
55
318
29
165
48
113
21
42
52
29
42
26
16
0.
.43
.29
.14
.76
.40
.02
.86
.29
.33
.90
.09
.12
921-1.025
0.000
0.927
0.947
0.956
0.962
0.970
0.976
0.981
0.988
0.993
1.001 12378-PeCDD
1.006
1.012
1.019
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Page No.
10/21/97
Listing of U973261B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT compound.Name.. ID.. Flags.
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
A
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
DC SN 28:07
DC WH 28:15
12 Peaks
DC NL 0:00
DC SN 26:19
DC SN 26:39
DC SN 26:50
DC SN 27:15
27:30
27:39
DC SN 27:50
DC SN 28:06
DC SN 28:14
2 Peaks
DC NL 0:00
29:07
29:16
29:26
29:35
DC SN 29:46
30:09
30:16
30:22
30:35
30:47
31:36
10 Peaks
DC NL 0:00
30:09
30:15
30:27
30:47
31:31
5 Peaks
DC NL 0:00
29:41
DC SN 29:46
30:09
DC SN 30:16
30:22
RO 1 . 80
RO 0.67
2
1.32-1.78
1.53
1.53
RO 5.61
RO 2.15
RO 2.17
1.45 2
1.43
RO 0.93
RO 1.22
RO 3.93
3
1.05-1.43
RO 1.50
1.17
1.31
1.30
1.28
1.42
1.22
1.19
1.16
1.33
1.27
1.34
1
0.43-0.59
0.50
0.51 3
0.51 3
RO 0.75
0.51 2
0.52 2
11
1W~.~
1.05-1.43
RO 0.81
1.29
RO 1.78
1.15
RO 1.71
1.09
7.22
3.60
,120.43
4.70
6.97
1.84
2.96
3.24
,950.88
322.08
12.49
12.96
5.84
,272.96
10.08
145.01
424.79
53.75
60.36
18.55
249.31
133.93
28.91
60.83
64.93
14.25
,236.07
20.11
,062.15
,175.81
27.63
,880.40
,475.69
,621.68
3.74
43.87
2.28
116.14
4.12
79.73
1.746.08
189.57
78.09
240.83
30.37
33.83
136.84
72.78
15.50
34.74
36.27
8.15
1,037.43
1,069.26
13.71
971.03
841.83
24.71
62.07
41.62
0.
1,204.80
132.51
0.
66.92
183.96
23.38
26.53
112.47
61.15
13.41
26.09
28.66
6.10
0.
2,024.72
2,106.55
18.30
1,909.37
1,633.86
0.!
19.16
54.07
38.11
1.022
1.027
855-1.145
0.000
0.957
0.969
0.976
0.991
1.000 13C12-POCDD 123
1.005
1.012
1.022
1.027
958-1.051
0.000
0.963
0.967
0.973
0.978
0.984
0.997 123478-HXCDF
1.001 123678-HXCDF
1.004
1.011
1.018 234678-HXCDF
1.045
868-1.132
0.000
0.997 13C12 -HXCDF 473
1.000 13C12-HXCDF 678
1.007
1.018 13C12-HXCDF 234
1.042 13C12-HXCDF 789
952-1.015
0.000
0.958
0.960
0.973
0.976
0.980
IS3
AN
AN
AN
SDR3
IS4
ALT2
ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Plle*U973261 #1-1024 Acqil7-OCT-1997 19*38*42 QC EI+ Voltage SIR 70S NOiae*3913
303.9016 P*2 BSUB(2S6,30,-3.0) PXD{9,5,3,0.10*,15652.0,1.00*,P,T) BxptEPCOS2
TRIANGLE LABS TexCiSO-M23-4 TLI#43432
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315.9419 P*2 BSUB(2S6,30,-3.0) PKD(9,5, 3,0. 10*, 11420.0, 1. 00*,P,T) Exp:BPCUS2
TRIANGLE LABS TextiSO-M23-4 TLI#43432
100*
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317.9389 Pt2 BSUB(256,30,-3.0) PKD(9,S,3,0.10*,8048.0, 1.00*,P,T) BxpiBPCUSS
TRIANGLE LABS TextiSO-H23-4 TLI#43432
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PiletU973261 #1-1024 Acytl7-OCT-1997 15*38,42 OC BI+ Voltage SIR 70S
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TRIANGLE LABS TextsSO-M23-4 TLI#43432
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TRXASOLE LABS TextlSO-H23-4 VLI#43432
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333.9338 Pt2 BSUB (256, 30. -3 . 0) PKD(7,S,3,0.10\,S496.0,1.00*,P,T) E3CpiEPCUS2
TRIAHOLB LABS TexttSO-M23-4 TLIM432
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TRIAKOLS LABS TexttSO-M23-4 TLI043432
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TRIANGLE LABS Text :SO-H23-4 TLI843432
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TRIANQLE LABS TtacttSO-103-4 TLIt43433
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TRIANGLE LABS T»xt , SO-M23-4 TLIt43432
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330.9792 Pt 2
A1.89E7
I A1.71E7
ft (1
'
/I /I
'2S»00 2ff«00 27«00'
#1-1024 Acyi 17-OCT-1997 19t38t42 OC EI+ Voltage SIR 70S
BxpiBPCUS2
^5.6E6
.4.4E6
.3.3B6
.2.2B6
.1.1S6
O.OSO
'20*00' ' ' ' ria*
TRIANGLE LABS Taxt:SO-M23-4 TLIt 43432
100S
00.
60.
40.
20:
o:
^t/^»l^f/**'
24*00
Pllt»U973261
409.7974 P,2
31^^^4*^25,22^^ 26,45 37,30
^^Atft** *^ ^~^^^"*^^\*^T***"*Tr^p~"'TV^\j.. . ~^' m^^^^**^^
25,00 26', 00 ' ' ' 27,00'
tl-1024 Acg,17-OCr-1997 19,38,43 OC BI+ Voltago SIR 70S
ExptSPCU32
!^" ,. «,Mia* r*'**7
•^\t^28,07 . Xv^. .
^^^-*>Y^V^ v~v/
.3.7B7
.2.8B7
.1.8X7
.9.2B6
O.OBO
20*00 ' ' Tims
TRIANQLB LABS TvKiSO-H33-4 TLIt 43 432
1001
00.
60.
40.
20.
0.
241 08
i
A HiA^
VwVM
24*00
35l46h 26[i9 37,06
j^l^^^
25,00 26'tOO 27<00
,_ff.OB4
20*03
1
a7ifVftl «""«
Jl Jl flB|L& IF .»
\^W^WH^
.4.SE4
.3.6X4
.2.4B4
.1.2X4
'• o.oso
20*00 Tino
-------
Flla>U9/3161 91-1024 Acqtl7-OCT-1997 19t3Bi42 OC EI+ Voltage SIS 70S SOiB»t205B
355.8546 Pi2 BSUB(256,30, -3.0) PXD(5, 5,3, 0.051,8232 .0,1. 001,P,T) ExpiEPCUS2
TRIAKOLB LABS Toxt:SO-«23-4 TLI#43432
1003
80.
so:
40.
20:
A4.03B6
A
J A2.47E6
A
I 1 1 A1.74B6
A
1 1 U0.0325 I \ A7.74BS A6 40S5
I \ A4.62BS \ A 1 \ A A^ aass f\A3.SSB5 A2.96BS
1 V /\ J \J\ J VyvVJc^v y\w/\- yv
.1. OS5
.0.325
.6.2E5
.4. IBS
.2.125
0.020
26\00 27(00 ' 20(00 Time
P110IU973261 #1-1024 Acqtl7-OCT-1997 19t38t42 OC BX+ Voltagf SIR 70S Noll»tl520
357.05157(2 BSBB(256, 30, -3.0) PJO)(5, 5,3, 0.051, 6080. 0,1. 001,P,T) Exp,BPCVS2
TRIANGLE LABS T*Xt:SO-M23-4 TLI#43432
1003
ao:
so:
to:
20:
A3.18E6
A
ft
I 1 A1.6SE6
\ \ \
A «•"**
A
11 l\ ggss \ AS.23BS
I \ A2.93BS I f >f* I \ "^f*5 A^A^A^A Al.tfl25
/ V /v j^^ / \J V y \ /~~r v_«/ V«X\_ x V XX _ -^N
.7.725
.6. IBS
'.4.6E5
.3.125
.1.525
0.020
25(00 27(00 20(00 ' ' ' Timo
Pile,O973261 #1-1024 Acyt 17-OCT-1997 19i38i42 OC EX+ Voltagt SIR 70S Solm»il419
367.8949 7(2 BSUB(2S6, 30, -3.0) PKD(5, 5, 3, 0.051,5676. 0,1. 001,P,T) Exp,EPCVS2
TRIANQLS LABS T*xt,SO-IU3-4 TLI#43432
1003
80.
60.
40.
20.
0.
JU.75S7
|
/ lll.502ff
1 *S^
..5.4E6
'.4.3E6
.3.225
.2.22$
.1.125
0. OBO
25(00 27(00 20(00 ' ' ' Tim»
P110IU973261 #1-1024 Acgi 17-OCT-1997 19i38i42 OC BI+ Voltafff SIR 70S Nola»>930
369.8919 Pi2 BSUB(256, 30, -3.0) PXD(S, 5, 3, 0.051,3720. 0,1. 001,P,T) Exp,EPCU32
TRIASOLB LABS T*xt,SO-U23-4 TLI#43432
10031
ao:
60.
40.
20^
0
A1.20E7
1
/ \L1.33E6
J WX
3.02ff
.3.025
.2.325
L1.525
.7.525
O.OBO
26tOO ' 27(00 20(00 ' ' ' TlttLf
Pll»iU973261 #1-1024 Actjil7-OCT-1997 19t38i42 OC EH- Voltmgf SIR 70S
330.9792 7(2 SxptSPCUS2
TRIASOL* LABS T*xt,SO-H23-4 TLI#43432
100S
00.
to.
40.
20.
0.
^w« J^v^v^SC?' 26t4S 27tl4 21*30 -~*.J\^ 28i26
^~vs~~v~vv-'-/~~^ ^^^^AXv^Ar-^
-4.527
3.727
2.027
1.027
9.2*6
o.oso
26(00 27>00 ' ' ' 20(00 ' ' ' Tia»
-------
PlletU973261
#1-404 Acq:17-OCT-1997 19s38t42 GC EI+ Voltage SIR 70S Holeat33S5
373.8208 Pt3 BSOB(2S6,30, -3.0) PXD(7,5,3,0.10*,13460.0,1.00*,P,T) ExpiBPCUS2
TRIANGLE LABS TejctiSO-023-4 TLI843432
100k
80:
so:
40:
20:
A2.4
J
A7.81ES
A
/\y
25(00
PlleiU973261
375.8178 Pt3
1E6
\
\ A1.37E6
A
1 «.j«s 00
PlleiO973261
385.8610 Pi3
A1.04B7
A I
V
J V
30(00
r3.7B6
A9.71B6
\ A8.42E6
rt
V y V J V
''.3.0ES
'.2.2B6
.1.5E6
.7.4ES
O.OEO
31(00 32(00 time
#1-404 Acqtl7-OC7-1997 19t38t42 OC EH- Volt*ff» SIS 70S Solm»t6723
BSUB(256,30,-3.0) PXD(7,5,3,0.10\,26892.0,1.00\,P,r) BxpiEPCUS2
TRIANGLE LABS TexttSO-IO3-4 TLI#43432
IOCS
80:
so:
4ol
20.:
o-
*2-02B7 A1.91S7 C7-3S6
25(00
Plleta973261
392.9760 Pt3
A
f\
\
J V
30(00
A1.63E7
A
A
V 7V / L
.S.8E6
.4.4S6
.2.9E6
.1.SB6
O.OSO
31(00 32(00 Time
#1-404 Acqil7-OC7-1997 15(30(42 OC BH- Voltage SIR 70S
ExpiEPCU32
TRIANGLE LABS TextiSO-M23-4 TLU43432
IOCS
80.
SO.
40.
20.
0.
29 1 07
IS~\S******#(
29\00
PlleiU9732Sl
445.7555 Pi 3
^j^r^^^^^L 30;10
30(00
31(37 r2.3S7
30(31 30(53 31'06 31,27 Av^
.1.8X7
.1.4B7
.9.1ES
.4.5E6
O.OSO
31(00 32(00 Time
#1-404 Acqil7-OCT-1997 19i38t42 OC EH- Voltage SIR 70S
BxptEPCUS2
TRIANGLE LABS T*XtiSO-M23-4 TLZX43432
100S
80.
SO.
40.
20.
0.
30il2 " 5.2S4
29tS4 \
1 II
29il6 i A 1 III
lit 4. . A > 129:42,1 A J , ArtJ'L
rJ^V^W^
25(00
\W\^^s*JP->S*)JV*riVJVV\/-i M
30(00
30(40 31(44
jo, 33 ao'37 lA*» * 1 31t05 31!18 llU 31(55
\tf3vs23 , ii UvK Jl AA* JUU iA IA kflin . »
^wOwAA^VvM1 ^^J^^Nv/v^(^wA^l(l^^^
I.4.2B4
.3.1S4
.2.1E4
.1.0E4
O.OSO
31(00 ' ' ' 32(00 Tin*
-------
'11»*U973261 91-404 Acqi 17-OCT-1937 19*38*42 SC BI+ Voltage SIR 703 NoiSO:1034
363.8156 P*3 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*, 413f. 0,1. 00\,P,T) ExptEPCUSS
TRIANGLE LABS T*xtsSO-H23-4 TLM43432
100H A6.21B5
29*36 39148 30,00 30113 30*24 30*36 30:48 31tOO 31:12 31*24 31*36
Pllf*U973261 #1-404 Atsq*17-OCT-1997 19i38t43 OC ST+ Voltage SIR 70S Hoio»:1287
391.8127 Pi3 BSVB(256,30,-3.0) PKD(7,S,3,0.10*, 5148.0,1.00*,P,T) Bxp:EPCUS2
TRIANOLB LABS TextiSO-K23-4 TLI143432
100H A5.41ES
29:36 ' '29:48 30*00 30tl2 30*34 30>36 30t4B SltOO 31H3 3lt24 31i36
P110I0973261 01-404 JLc
-------
Pllet0973261 Kl-596 Acgtl7-OCT-1997 19:38t42 QC BI+
407.7818 Ps 4 BSOB(256,30, -3.0) PKD(7,5,3,0.10*,6000.
TRIANQLS LABS TexttSO-M23-4 TLI#43432
10031 A5.76E5
so:
60:
40:
20.
Pile
409.
TRIA.
ao:
60:
40:
20:
Pile
417.
TRIA
ion
80:
60:
40:
20:
o:
Pile
419.
TRIA
lOOJi
eol
60.
4ol
20^
o-
Pile
430.
TRIA
ion
80.
60.
40.
20.
0
Pllt
479.
nuj
ion
80.
60.
40.
20.
0
33'tOo' ' 33112' ' 33\24~ ' ' 33»3ff' ' 33i48
10973261 01-596 Aagtl7-OCT-1997 19t38t42 OC BI+
7789 Pi4 BSOB(256,30,-3.0) ?KD(7.5,3,0.10*,2796.
VOLE LABS Texti3O-K23-4 TLI843432
A2.80B5
A
/ L A6.88E4
' 33'tOo' ' 33': 12' ' 33:24' ' 33*: 36 33\48
10973261 §1-596 Aegtl7-OCT-1997 19:38:42 OC EH-
8253 Pi4 BSOB(256,30,-3.0) PXD(7,5,3,0.10*,8716.
HOLE LABS Te3cttSO-H23-4 TLI143432
A6.21S6
A
A
Voltage SIR
0,1.00*,P,T)
SM^UJM
34 tOO
Voltage SIR
0,1.00*,P,T)
\9.27E3
34:00
Voltage SIR
0,1.00f,P,T)
70S Noise: 1500
ExptSPCOS2
1.2B5
... A5-/OS4 A3.73S4
~ /^-A A^V-Sy^V^^-v/^ ^^x
34:12 34t24 34\36
70S Soieet699
BxplEPCOSa
A3.27B4 U.95E4
34:12 34:24 34:36
70S Solmet2179
SxptSPCOS2
AS.70B6
A:,
33iOO 3 3': 12 33:24 33>36 33:48 34': 00 34:12 34:24 34:36
IO973261 *1-S96 Acgtl7-OCT-1997 19:38:42 OC EH- Voltage SIR 70S Soimei3439
8220 Pi4 BSOB(256I30.-3.0) PKD(7, 5,3, 0.10*, 13756. 0,1. 00*,P,r) BxptBPCUS2
HOLE LABS TexttSO-K23-4 TLIK43432
A1.47S7
A
/V
33<00 33:12 33:24 33:36 33t48
,0973261 tl-596 Acqtl7-OCT-1997 19:38:42 OC EX+
9729 Pt 4 SxpiBPCOSa
MOLE LABS TextiSO-H23-4 TLI»43432
33:00 33': 12 33:24 '33:36 '33:48
10973261 91-596 Ac/ 1 *^ * *— ' ^*"
34:12 34:24 34:36
.9.5E4
.7.1S4
.4.7S4
.2.4B4
.O.OEO
Time
.LOSS
.8.0E4
.6.0E4
.4.0E4
.2.0E4
.O.OEO
Time
.2.3B6
.1.8E6
.1.4B6
-.9.1SS
•.4.6E5
'•O.OEO
Time
S.8E6
.4.6E6
.3.SE6
.2.3E6
.1.2E6
O.OEO
Time
C1.1E7
.8.6E6
.6.5S6
.4.3B6
.2.2E6
O.OEO
Time
3.6S4
.2.9B4
.2.2B4
.1.SS4
.7.3B3
O.OEO
Time
-------
fiJL«iUS73261 #1-596 Acijt 17-OCT-1SS7 19:38:42 OC EH- Voltage SIS 70S KoiS»:742
423.7766 Pt4 BSOB(256,30,-3.0) Pn}(7,5,3,0.10X,2968.0,1.00*,P,T) BxptEPCUS2
TRIANGLE LABS TncttSO-O23-4 TLI143432
IOOH A1.07BS
33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06 34:12 34(18
Pil»iff973261 tl-596 Acy: 17-OCT-1997 19:38:42 OC EH- Voltaff* SIR 70S Noil*:691
425.7737 Pi4 BSOS(256,30,-3.0) PXD(7,S,3,0.10*,2764.0,1.00*,P.T) BxptBPCUS2
TRIANOLB LABS Tvct:SO-M23-4 TKCt43432
100* A1.23B5
80.
60.
40.
20.
A8.66B4
A4.34S4
.4.4E4
.3.5E4
'.2.6E4
.1.8B4
.8.8E3
O.OBO
34:24 Via»
33:12 33:18 33:24 33:30 33:36 33:42 33:48 33(54 34:00 34:06 34:12 34:18
Fll»:0973261 tl-596 Acytl7-OCT-1997 19:38:42 OC EH- Voltaff* SIR 70S Boim*t2647
435.8169 Pi4 BSOB(256,30,-3.0) PXD(7,5,3r0.10»l, 10588.0,1.00»l,P,T) Bxp:BPCUS2
TRIANOLB LABS T»Xt:3O-M23-4 TLI043432
10091 A1.3.2E7
so:
eo:
40:
20.
O.OBO
'34': 2 4 Tim*
.4.8B6
.3.8B6
.2.9B6
-1.9S6
.9.SS5
O.OBO
33:12 33:18 33:24 33:30 33:36 33*42 33:48 33:54 34:00 34:06
Fll»:U973261 tl-596 Acyt17-OCT-1997 19:38:42 OC SX+ Voltaym SIR 70S Soit»»2239
437.8140 Pt4 BSOB(256,3O,-3.0) PXD(7,5,3,0.10*,8956. 0,1.00*,P,T) B*ptBPCUS2
TRIANGLE LABS TfXt:SO-M23-4 TU«43432
34:12 34\13 34\24. fim»
ion
80.
60.
40.
20.
0.
"ft"
A
/ 1
J V_
-4.5S6
.3.6B6
'.2.7S6
'.1.SS6
.8.9S5
.O.OBO
33:12 33: 18 33': 24 33:30 33136 33142 33:48 33:54 34<6o' 34*: 06 34(12 34(10 34(24 rim«
Pil*:U973261 tl-596 Acqt 17-OCT-1997 19t38i42 OC EH- Voltage SIR 70S
430.9729 Pt4 BxptSPCUS2
TRIANGLE LABS T*xt:3O-M23-4 TLIt 43432
1009
00.
60.
40.
20.
0.
33:12
34(13
33(12 33(10' ' '33(24 33(30 ' '33(3tf ' '33(42 ' '33(40 ' 33(54 ' '34(00 ' 34(05 ' '34(12 ' '34(10
-1.1*7
.8.6X6
.6.5S6
.4.3B6
.2.2*6
O.OBO
34 2 4 Tlm»
-------
'11010973261 H-596 Acqtl7-OCT-199l 19:38:42 OC EH- Voltage SIR 70S NOis0>1430
441.7438 Pt4 BSUB(2S6,30,-3.0) P1H>(7,5,3,0.10*,5720.0.1.00*,P,T) E3CptEPCUS2
TRIANOLE LABS TWCCISO-U23-4 TLI043432
100H
33'iOO 34tOO 35'tOO 36'tOO 37:00 38*00 39'tOO
Pll»:ff973261 #1-596 Acqt 17-OCT-1S97 19t38i42 OC EH- Voltafff SIR 70S Ko±a»:1440
443.7399 Pi4 BSUB(236,30,-3.0) PXD(7,3,3, 0.10\,S760.0,1.00*,P,T) ExptEPCUSl
TRIANOLE LABS TfXtiSO-K23-4 TLX#43432
100H
Tlaa
33100 34:00 35iOO 36:00 37:00
Pllmiff973261 01-596 Acy: 17-OCT-1997 19:38:42 OC EH- Voltag» SIR 70S
430.9729 Pi4 SxptBPCUS2
TRXANOLE LABS T»xt!3O-K23-4 TLI043432
10031
38:00
39 tOO
lima
901
801
35>10 (I |l.
.1.9B7
.7B7
5E7
33:00 34:00 35:00 36:00 37:00 38:00
Pll»:U973261 01-596 Acgtl7-OCT-1997 19:38:42 OC EH- Voltay» SIR 70S
513.6775 Pt4 Exp:BPCU32
TRIANOLE LABS T»xt:SO-H23-4 TLH43432
39 tOO
OEO
Maw
33:00
34:00
35100
36:00
37:00
38100
39:00
-------
Page No.
10/21/97
Listing of 09732618.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.
Flags.
13C12-HpCDD
436-438
436-438
OCDF
442-444
0.88-1.20
0.971-1.029
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:00
33:54
34:05
34:25
Peak
0:00
33:27
33:38
35:10
35:53
36:34
36:49
37:33
37:43
37:54
38:01
39:19
39:19
39:27
Peaks
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
1
0
6
.18
.03
.31
.59
UK,
76-1.02
0
0
0
1
0
0
0
0
1
0
1
0
1
0
.99
.66
.46
.36
.86
.46
.97
.70
.95
.58
.39
.93
.36
.55
9.77
2,610.01 1,321.34 1,288.67
9.44
2.84
2,610.01
Above: HpCDD / Octa-CDO and CDF Follows —
0.000
1.000 13C12-HpCDD 678 IS7
1.005
1.015
5.74
7.60
3.99
4.71
3.81
7.69
11.34
3.21
2.84
2.51
4.50
1.54
1.06
5.35 1.083
0.00
0.890-1.110
0.000
0.918
0.923
0.965
0.985
1.004 OCDF
.011
.031
.035
.040
.043
.079
.079
AN
OCDD
458-460
458-460
0.76-1.02
DC HL 0:00 1.01 4.50
36:27 0.80 55.20
DC SN 36:40 RO 0.38 2.06
1 Peak 55.20
24.50
0.890-1.110
0.000
30.70 1.000 OCDD
1.006
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.10 2.95
36:26 0.85 4,889.16
DC WH 36:53 1.02 27.89
470-472 1 Peak 4,889.16
2,253.07
0.995-1.005
0.000
2,636.09 1.000 13C12-OCDD
1.012
IS8
Column Description 'Why Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
HH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Fil»,0973261 #1-596 Acqtl7-OOt-i997 19:38,41 X BI+ Voltage SIR 70S Jtoia«»1131
457.7377 Pt4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10^,4524. 0,1. OOf,F,T) BxptEFCUS2
TRIANGLE LASS T*XttSO-M23-4 TLI143432
100H A2.JJ7E5
36118 36', 24 36', 30 36,36 36,42 36,48
Pil»iU973261 tl-596 Acytl7-OCT-1997 19,38:42 X EH- Voltage SIS 70S Kolm»tlll9
459.7348 Pt4 BSUB(256,30,-3.0) PXD(7.S,3,0.10*,447f.Oe1.00*,P,T) Exp,EPCV32
TRIANGLE LABS TuxttSO-H23-4 TLI*43432 • •
lOCA
36,18 36,24 36,30 36,36 36,42 .36,48
Fil*,U973261 tl-596 Aagt 17-OCT-1997 19,38,42 OC BI+ Voltag* 3IR 703 Nolle,855
469.7779 Pi4 B3UB(256,30,-3.0) PXD(7,5,3,0.10*,3420.0,1.00X,F,T) Exp,EPCUS2
TRIANGLE LABS TtXti3O-M23-4 TLH43432
100H A2.25E7
4E7
36,18 36,24 36,30 36,36 36,42 36,48
Pll»,U973261 tl-596 Acq, 17-OCT-1997 19t38t42 OC EH- Voltag* SIR 70S Nolt«,782
471.7750 Pt4 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,3128.0.1.00*,P,T) Exp,EPCUS2
TRIANGLE LABS T»Xt,SO-H23-4 TLI*43432
100* A2.(
80.
60.
40.
20:
36,18 36,24 36,30 36,36 36,42
Fill, 0973261 tl-596 Acqt 17-OCT-1997 19,38,42 OC XL* Voltag* SIR 70S
430.9729 Pi4 2xp,EPCU32
TRIANGLE LABS TvtttSO-H23-4 TLI143432
3-OOH 36,42
801
60.
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-------
Peak Locate Examination:17-OCT-1997:19:37 File:U973261
Experiment:EPCUS2 Function:2 Reference:PFK
CO
-------
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS2
Sample Text;SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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19:00 20:00 21:00
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EH- Voltage SIR 70S
315.9419 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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-------
File:U973261 ttl-1024 Acq: 17-OCT
319.8965 F:2 Exp:EPCUS2
Sample Text :SO-M23-4 TLI#43432
100%
21:00
File:U973261 #1-1024 Acq:17-OCT
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432
100%
1997 19:38:42 GC EI+ Voltage SIR 70S
File Text : TRIANGLE LABORATORIES, INC.
22:00 23:00
1997 19:38:42 GC EI+ Voltage SIR 70S
File Text:TRIANGLE LABORATORIES, INC,
24:00
21:00
File:U973261 #1-1024 Acq:17-OCT
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432
100%
80 j
60 j
401
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22:00 23:00
•1997 19:38:42 GC EI+ Voltage SIR 70S
File Text:TRIANGLE LABORATORIES, INC.
22'1622:30
24:00
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23:00
24:00
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O.OEO
-------
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23r4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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-------
File:U973261 tfl-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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341.8567 F:2 Exp:EPCUS2
Sample Text :SO-M23-4 TLI#43432 File Text-.TRIANGLE LABORATORIES, INC.
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351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-404 Acq;17-OCT-1997 19:38;42 GC EI+ Voltage SIR 70S—
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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-------
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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Time
O
-------
File:U973261 #1-404 Acq:17-OCT-1997 13:38:42 GC EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
80 j
60 j
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File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC El* Voltage SIR 70S
401.8558 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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Time
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-------
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
80J
60 j
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30:36 30:48 31:00 31:12 31:24 31:36
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 33:17
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60 j
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File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 34;15
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Time
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-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:
100% A2.81E5
42 GC EI+ Voltage SIR 70S
TRIANGLE LABORATORIES, INC,
33:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text
100% A2.67E5
34:00
:42 GC EI+ Voltage SIR 70S
:TRIANGLE LABORATORIES, INC.
35:00
33:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text
100%, 33; 02
80 j
60 J
40J
20 J
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34:00
:42 GC EI+ Voltage SIR 70S
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34:15
35:00
33:00
34:00
35:00
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6.9E4
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2.3E4
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1.8E6
1.4E6
9.2E5
4.6E5
O.OEO
Time
CD
-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EH- Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%, A1.Q1E5
33:00 34:00 35:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
80^
60 j
40 j
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33:00 34:00 35:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EH- Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100% 33 54
80 J
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35:00
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Time
O
-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
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File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EH- Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%
80J
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33:00 34:00 35:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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80 j
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-------
File:U973261 #1-596 Acq: 17-OCT-l
457.7377 F:4 Exp:EPCUS2
Sample Text:SO-M23-4 TLI#43432
100% A2.
80 j
60 J
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:U973261 #1-596 Acq: 17-OCT-1997 19:38:42 GC El-f Voltage SIR 70S
7348 F:4 Exp:EPCUS2
le Text:SO-M23-4 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
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:U973261 #1-596 Acq: 17 -OCT- 19 97 19:38:42 GC EI+ Voltage SIR 70S
7779 F:4 Exp:EPCUS2
le Text:SO-M23-4 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
36:26
11
35100 36loO 37JOO 3s!oO 39loO
8.9E4
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_3.6E4
_1.8E4
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_6.9E4
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_2.3E4
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7.1E6
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-------
TLI Project: 43432
Client Sample: SO-23-4
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973639
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-4A-C
1.000
n/a
DB-225
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/18/97
Dilution Factor: n/a
Blank File: U973257
Analyst: BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
XF24087
X973633
n/a
n/a
n/a
2,3,7,8-TCDF
1.3
0.78 24:33
»C12-2,3,7,8-TCDF
3.5
87.9 40%-130%
0.79 24:32
Recovery Stantiarrf
13C12-1,2,3,4-TCDD
0.81 23:19
Data Reviewer.
10/23/97
Page 1 of 1
C2NFJ>SR vlOO. LARS «. 10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:35 10/23/97
-------
Initial
Date...
Data Review By:
\j (_. _lD/JLl/_L_ Calculated Noise
Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of X973639B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Ral.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC NL 0:00
19:46
19:53
20:04
20:12
20:17
20:24
20:47
20:55
21:03
21:14
21:20
21:30
21:39
21:48
21:58
22:07
22:31
22:36
22:44
22:52
23:00
23:07
23:15
23:31
23:46
23:57
24:24
24:33
24:48
25:08
25:17
25:33
25:40
26:13
27:07
304-306 35 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 19:35
DC ML 22:29
DC WL 22:39
0.65-0.89
RO 1.33
0.79
RO 2.93
RO 0.57
0.70
0.67
0.81
0.78
0.79
0.79
0.79
RO 0.63
0.79
0.78
0.79
0.77
0.75
0.78
0.79
RO 0.90
0.80
0.79
0.77
0.79
0.78
0.77
0.77
0.79
0.78
0.75
0.77
0.79
RO 1 . 27
0.86
0.78
RO 0.43
0.65-0.89
0.66
RO 0.59
RO 1 . 62
RO 0.56
0.798-1.112
11.15
7,257.49
75.07
57.12
20.30
62.05
102.11
10,340.25
6,091.61
7,180.72
5,508.93
99.86
3,661.54
4,925.04
1,924.21
11,238.99
2,985.97
5,724.63
3,924.73
82.80
90.26
4,116.99
747.45
3,663.88
3,889.24
448.24
2,567.26
2,301.89
2,387.65
2,018.92
1,711.85
3,476.71
15.15
6.21
1,588.19
105.17
100,398.48
3,197.52
124.33
24.85
8.36
24.92
45.84
4,536.10
2,682.27
3,169.05
2,438.33
43.44
1,614.56
2,157.04
849.86
4,904.51
1,277.81
2,511.50
1,726.42
41.95
40.18
1,818.00
324.58
1 , 619 . 04
1,709.35
194.47
1,115.13
1,018.31
1,049.80
868.41
743.93
1,538.69
10.90
2.88
693.66
45.75
4,059.97
42.41
43.39
11.94
37.13
56.27
5,804.15
3,409.34
4,011.67
3,070.60
69.11
2.046.98
2,768.00
1,074.35
6,334.48
1,708.16
3,213.13
2,198.31
46.78
50.08
2,298.99
422.87
2,044.84
2,179.89
253.77
1,452.13
1,283.58
1,337.85
1,150.51
967.92
1,938.02
8.56
3.33
894.53
106.41
0.000
0.806
0.810
0.818
0.823
0.827
0.832
0.847
0.853
0.858
0.865
0.870
0.876
0.882
0.889
0.895
0.901
0.918
0.921
0.927
0.932
0.938
0.942
0.948
0.959
0.969
0.976
0.995
1.001 2378-TCDF
1.011
1.024
1.031
1.041
1.046
1.069
1.105
0.959-1.041
17.59
6.30
13.58
6.76
0.000
0.798
0.916
0.923
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:55 10/21/97
-------
Page No. 2 Listing of X973639B.dbf
10/21/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC WL 22:58 RO 0.57 39.97 0.936
24:06 RO 0.62 7.68 3.34 5.35 0.982
24:32 0.79 7,730.05 3,406.82 4,323.23 1.000 13C12-2378-TCDF ISO
25:05 0.88 2.72 1.27 1.45 1.022
25:15 RO 0.60 28.71 12.49 20.73 1.029
DC WH 26:57 0.68 91.52 1.099
316-318 4 Peaks 7,769.16
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.89 0.913-1.087
332-334
DC
DC
DC
DC
DC
DC
DC
ML
WH
WH
WH
WH
WH
WH
0:00
21:49
23:00
23:19
24:06
25:17
25:29
25:40
25:52
26:25
26:35
RO
RO
RO
RO
RO
RO
RO
RO
RO
3.
0.
0.
0.
0.
1.
2.
0.
0.
2.
2.
11
94
76
81
92
07
38
45
99
66
15
5
30
5,175
6,318
70
5
5
7
14
2
5
.20
.87
.20
.95
.99
.91
.36
.08
.05
.74
.54
16.38
2,240.34
2,837.37
36.73
17.44
2,934.86
3,481.58
40.11
0.
0.
1.
1.
000
949
000
014
1.048
1.
1.
1.
1.
1.
1.
099
108
116
125
149
156
13C12-2378-TCDD IS1
1.014 13C12-1234-TCDD RSI
332-334 4 Peaks 11,596.01
Column Description "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
'lletX973639 71-803 Acqt1B-OCT-iSyl 17:20:10 OC EH- Volt ago SIR AUtoSpea Noise:4194
303.9016 BSUB(256,30,-3.0) PKD(S,3,1, 0.10*, 16776.0, 0. 00*,P,P) ExptZCOKP_TT
Saaplo TexttSO-H23-3 TLH43432 Pile Text: TSIAKOLS LABS
iO» A4.54E7
so:
20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00
File: 1973639 #1-803 Acq:18-OCT-1997 17:20:10 OC EH- Voltage SIS AutoSpec Ooimet31SO
305.8987 BSVB(256,30,-3.0) PKD(5,3,1, 0.10*,12600.0, 0.00*,P,P) SxptXCOSPjn
Sample Text:SO-U23-3 TLI*43432 Pile Text: TRIAHOLE LABS
A5.BOE7
A6.33E7
80.
60.
40.
20.
.1057
A1.45B7
A1.94E7
AJL1.15E7 A
MA/VV
1B.9SB6
20'sOO 21:00 22:00 23:00 24'tOO 25*00 26:00 27:00
Pll»:X973639 f 1-803 Acqi 18-OCT-1997 17:20:10 OC BH- Voltagf SIX AutoSp»C Soim»t3S12
315.9419 BSVB(256,30,-3.0) PXD(5,3,1, 0.10*, 14048.0, 0.00*,P,P) Bxp:XCOllP_TT
Sanplf TmxtiSO-M23-3 TLI143432 Pile TfXt: TRIANOLB LABS
100* A3.41E7
so:
SOL
40:
20:
20:00 21100 22:00 23:00 24:00 25:00 26:00 27:00
Pll»tX973639 #1-803 Acy: 18-OCT-1997 17:20:10 OC EH- Voltage SIR AutoSp»c Boi**s5286
317.9389 BSV3(256,30,-3.0) PKD(S,3,1, 0.10*,21144.0, 0.00*,P,P) Bxp:XCONP_TT
Sample Text:SO-H23-3 mf43432 Pile Text: TRUOH3LB LABS
10091 A4.32E7
BO:
so:
40.
20:
20:00 21100 22:00 23:00 24tOO 25:00 26:00
Plle:X973639 #1-803 Acgt 18-OCT-1S97 17:20:10 OC EH- Voltage SIR AutoSpec
375.8364 Exp:ICOHP_TT
Sample Text:3O-U23-3 TLX143432 Pile Text: TRXANQLX LABS
100JI
27:00
20:00
21100
22 tOO
23:00
24 > 00
25100
26100
27:00
O.OSO
Time
-1.7B7
.1.3E7
-1.0E7
.6.7E6
.3.4E6
0. OBO
rime
..7.6B6
'.6.1E6
'.4.6B6
.3.1S6
.1.SB6
O.OEO
Time
-9.7E6
.7.8B6
.5.8E6
.3.9B6
.1.9B6
O.OSO
Time
-------
PilotX973S39 #1-303 Acqt 1B-XT-1S97 17tSOtlO X BT* Voltage SIS AutoSpec NoisetSlSB
319.8965 BSVB(256,30,-3.0) tKD(5,3,l,0.10*,12672.0,O.OOX,F,P) BxptKOHPJUT
Sample TuKtSO-K23-3 ZLX143432 Pile Text: TRIANQLS LABS
100*
21(00 22(00 23(00 24(00 25(00 26iOO
FlleiX973639 11-803 Ac
-------
Flle,X973639 #1-803 Acq: 18-OCT-1997 17,20,10 QC El* Voltage
303.9016 ExpiXCONF TT
Saofle Text,SO-M23-3 TLH43432 file Textt TRIASQLB LABS
ion
80:
60:
40:
20:
o:
20*47
. 21*58
t ft
\\ K , 22*31
A ft 21*30 ( •"• 23,00
SIR AutoSpec
II 11 A/\A h lAT.A IOTA X
20*00 ' ' ' 21*00 ' ' ' 22*00 ' ' ' 23*00 ' ' ' 24*00 '
File,X973639 #1-803 Acq: 18 -OCT- 1997 17*20*10 OC EH- Voltage
315.9419 XxpiXCOKF TT
Sample TextiSO-023-3 TLI043432 f±le Textt TRIA1OLB LABS
ion
80:
601
40:
20:
o:
"
1
1
20*00 21*00 22*00 23*00 24*00
File,X973639 #1-803 Acq: 18-OCT- 1997 17*20*10 OC EH- Voltage
319.8965 Exp,XCONF_TT
Sample TextiSO-K23-3 TLI#43432 File Textt TRIABOLB LABS
ion
80:
60:
40:
20:
20,34
21,09
T
l\ A A A "n37 2/A15 24,07
]l l\ /\ A/\ AxvA>A/V . AL
20*00 21*00 22*00 23>OO 24*00
Pile iX973 639 01-803 Acq: 18-OCT- 1997 17*20*10 OC EH- Voltage
331.9368 ExptXCOKP TT
Sample Text,SO-IO3-3 TLX043432 File Text, TRIANOLE LABS
ion
so:
60:
40:
20:
OJ
23,15
23.00 J
/III
20*00 21(00 22*00 23, OO 24*00
Plle:X973639 #1-803 Acqtia-OCT-1997 17*20*10 OC EH- Voltage
292.9825 Exp,XCOKF_TT
Sample Text:SO-M23-3 TLI043432 File Textt TRIANGLE LABS
1009
sol
60-.
40:
20:
OJ
20*04 20*43 ^J&iOA^ 23139^24,10
25,00 '
SIR AutoSpec
1"
.
25*00
SIR AutoSpec
^^
25*00 '
SIR AutoSpec
25*00
3IR AutoSpec
24,52 25,22
-
26:13
A
.1.4X7
.1.1X7
.8.2X6
.5.5E6
.2.7X6
0.0X0
26\00 ' 27*00 Time
.7.7X6
.6.1X6
.4.6X6
.3.1X6
.1.5X6
0.0X0
26,00 ' ' ' 27*00 ' ' Time
-.3.5X6
.2.8X6
.2.1X6
.1.4X6
.7.0X5
0.0X0
26tOO ' ' ' 27*00 ' ' Time
-7.1X6
.5. 7X6
.4.3X6
.2.9X6
.1.4X6
O.OEO
26tOO 27*00 Time
25*54 ^^^r-9'3*7
20*00 21*00 22*00 23*00 24*00
Pile 1X973 639 #1-803 Acqt 18-OCT- 1997 17,20,10 QC XT* Voltage
330.9792 XxpiXCOHF_TT
Saaple Text,SO-H23-3 TLI#43432 File Textt TRIANOLX LABS
ion
80.
60.
40.
20.
0.
20,20 20,57 ^. 32,4223110 n, M 24,0ff
20*00 ' 21*00 22*00 23*00 ' 24*00
25*00
SIR AutoSpec
.7.4X7
'•.5.5X7
'•.3.7X7
.1.8X7
0.0X0
26 tOO 27 tOO Time
^ 24,59 25,3426,02 27,21^8.4X7
25*00 '
-.6.7X7
'•.5.0X7
.3.4X7
.1.7X7
a. axo
26\00 ' ' 27*00 ' ' Time
-------
Peak Locate Examination:18-OCT-1997:17:19 File:X973639
Experiment:XCONF_TT Function:! Reference:PFK
-------
< :>?l \ i^fff^*; ^o^x*3*
TLI Project: 43432
Client Sample: FB1-M23
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973262
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-5A-B
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
***^-*r&r^
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
U,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals " ^ -,\, { ,^--^;]
•. \ *• •• \ v f ^v,S- stkrf v. •>
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Awt |ngJ ;
\f •>•• ^-M^W-"*
ND
ND
ND
ND
ND
ND
ND
ND
0.007
0.008
0.01
0.01
0.01
0.01
0.01
0.009
0.007
0.007
0.008
0.006
0.007
0.008
0.01
0.01
0.01
N«rat>«i^ &. I*IP<* 4 >x? - ^ '"r> vx* >X " s ^: ^teggiA ,
^^^W• %%s^->"-. s f •• <. y S "• ~~ <••$'.•.•.•'•' f
-------
TLI Project:
Client Sample:
43432
FB1-M23
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973262
Mental Standards ,„ t \
13Cl2-2,3,7,8-TCDF
l3C12-2,3,7,8-TO>D
13C12-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13CI2-l,2,3,4,6,7,8-HpCDF
13C,2-1.2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
^. ^»''.*i»^ ~J ^t *»V
Surrogap stat^aitfd^ {Ty
37Cl*-2,3,7,8-TCDD
l3C12-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
»C,2-l,2,3,4,7,8-HxCDD
13C12-l,2,3,4,7,8,9-HpCDF
Alternate Standards * fy - A Wfe?;-\W0|^ %
3.4
3.9
3.5
3.8
3.9
R&-^^\$ii^
3.2
3.7
\;'^;5^^^^
^ -- -VJtRtBtw*
57.6
86.4
93.5
109
110
102
80.5
99.6
99.7
^ ** *^^*-i %
-<%v '^•^^BCd-ye;
85.8
97.7
88.3
94.3
98.3
79.9
91.8
;"^>^J
ry\5-QCL%lt» ,;
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
•••.!'. A>^ i^f {» % N •&.*
^ ^tSQ^IWilK- - ^N
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
ryvvo^l»is>V
40%-130%
40%-130%
^^ -%^^
nRaBa
0.80
0.76
1.46
1.54
0.51
1.24
0.42
1.01
0.85
•;Ni*,»*t ^ *
> *W*^X
1.53
0.51
1^4
0.43
'••• patioli
0.49
0.52
"RkW
0.80
1.21
?;c^8t^
21:36
22:31
26:18
27:29
30:15
30:59
33:02
33:54
36:27
**Ut^5»t^f*% ^
x^^^*V
22:32
27:06
30:09
30:54
34:15
iftS**^
31:31
30:47
"*'\**Wi83$
22:17
31:18
;5^s/
__
__
—
^*N^tn^%S •>S"-
*v*|r^%;4
—
?t\8^|
—
^Ssr^
Data Reviewer.
Page 2 of2
10/21/97
X237.PSR xiOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Initial
. .Data..
Data Review By:
Calculated Noise Area:
2.37
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
10/21/97
Compound/
M_Z QC.Log Omit Why
Listing of U973262B.dbf
Matched GC Peaks / Ratio
/ Ret. Tine
.RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
WL
ML
WL
WL
SN
SN
SN
SN
WH
WH
WH
WH
WH
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
0:00
18:27
18:41
19:02
19:18
19:53
20:04
20:13
21:57
22:24
22:32
Peaks
0:00
18:50
19:10
19:40
20:14
20:51
21:03
21:36
21:51
22:09
22:40
23:00
23:13
23:56
24:06
Peak
0:00
19:17
19:31
21:15
21:20
21:30
21:35
22:04
22:09
0.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0
0
0
1
0
0
1
0
2
0
2
.91
.35
.79
.18
.79
.82
.73
.78
.88
.75
.14
3.33
1.33
1.
10.
11
60
7.73
11.
1.
8.
1.
4.
2.
0.
23
65
76
38
25
14
00
65-0.89
0
3
1
0
0
1
1
0
0
0
6
0
0
2
0
.82
.83
.21
.90
.64
.32
.21
.80 2
.52
.26
.46
.28
.40
.56
.28
2
M !«»•_. .
3.
1.
2.
2.
22.
2.
14.
.517.
12.
8.
4.
7.
3.
6.
5.
.517.
Htf+rva
65-0.89
1
3
0
0
2
0
1
2
0
.93
.47
.96
.58
.66
.28
.17
.15
.44
i.
0.
0.
0.
0.
0.
3.
2.
1.
14
65
34
21
64
28
00
83 1.123.19
80
99
81
75
56
04
36
83
/
-------
Page No. 2
10/21/97
Compound/
M_Z.... QC.Log Omit Why
Listing of U973262B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
DC
DC
DC
SN
SN
SN
0
23:16
23:25
23:33
Peaks
RO
RO
1
1
0
.26
.66
.88
2
1
2
0
.04
.31
.40
.00
1.
1.
1.
033
040
046
0.911-1.089
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
ML
WL
SN
SN
SN
SN
SN
SN
3
0:00
20:19
20:48
21:03
22:32
22:49
22:57
23:03
23:03
23:11
23:16
23:29
23:34
23:40
23:48
23:55
23:59
24:06
Peak
0:00
19:09
19:23
21:02
22:17
22:31
22:54
23:16
23:21
23:27
23:40
23:56
Peaks
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
1
8
2
2,439
5
1
1
4
7
10
1
3
7
4
4
4
2
2,439
.86
.17
.31
.61
.26 2,439.26
.86
.70
.92
.68
.80
.88
.32
.38
.38
.04
.99
.49
.22
.26
.65-0.89
1
0
0
2
0
0
0
0
1
1
0
1
.96
.62
.37
.21
.80
.76
.55
.86
.25
.53
.39
.01
3
5
1
10
3,143
3,012
60
12
10
9
9
11
6,216
.52
.86
.31
.64
.12 1,392.24
.10 1,304.89
.87 26.48
.51
.90
.77
.03
.91
.09
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
902
924
935
001 37C1-TCDD SOR1
013
019
024
024
030
033
043
047
051
057
062
065
070
0.911-1.089
0.
0.
0.
0.
1,750.88 0.
1,707.21 1.
48.11 1.
1.
1.
1.
1.
1.
000
850
861
934
990 13C12-1234-TCDD RSI
000 13C12-2378-TCOD IS1
017
033
037
041
051
063
KVuuvn . mf*T\r\ / n**s*no w*»t "I «».«»
PoCDF
340-342
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
0:00
24:14
24:26
25:21
25:58
26:53
27:29
27:36
1
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
0
0
1
0
2
1
0
2
.88
.21
.09
.96
.42
.01
.28
.99
w i i\*vu f fv^uc c wi j. wwa
•^ 2
1
3
12
1
2
0
1
.09
.05
.77
.16
.40
.58
.72
.96
0.906-1.077
0.
0.
0.
0.
0.
1.
1.
1.
000
921
929
964
987
022
045
049
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Page No.
10/21/97
Listing of O973262B.dbf
Hatched GC Peaks / Ratio /
Rat. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Hi
fama.. ID.. Flags.
340-342
13C12-P8CDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
WH
0
NL°
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
SN
SN
SN
SN
SN
2
ML
SN
SN
SN
28:10
28:23
Peaks
0:00
25:10
25:20
25:54
26:18
26:29
26:38
27:06
27:32
Peaks
0:00
25:21
25:29
25:45
25:51
26:17
26:40
26:51
26:55
27:34
Peaks
0:00
26:29
26:50
27:06
27:15
27:29
27:39
27:49
28:03
28:23
28:31
Peaks
0:00
28:59
29:05
29:09
RO
RO
1
1
.19
.20
2
4
.39
.31
1
1
.071
.079
0.00
1.
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
32-1.78
1
0
1
1
1
2
1
1
1
.13
.90
.39
.26
.46
.08
.38
.53
.26
32-1.78
1
0
0
0
3
1
2
1
0
0
.76
.83
.70
.90
.32
.38
.55
.53
.71
.42
1
1
56
16
3,215
20
35
3,047
11
6,355
.78
.83
.91 33.12
.75
.49 1,905.76
.63
.75 20.75
.45 1,843.61
.27
.60
0.848-1.152
0
0
23.79 0
0
1,309.73 1
1
15.00 1
1,203.84 1
1
.000
.957
.963
.985
.000 1
.007
.013
.030 1
.047
2
2
3
2
0
7
3
2
1
1
0
.18
.12
.92
.12
.97
.22
.52
.93
.51
.66
.00
32-1.78
1
1
2
2
0
1
1
2
3
2
1
.61
.24
.36
.82
.87
.54
.47
.62
.48
.65
.47
*!..»_ .
2
4
2
1
0
2,054
218
12
7
6
4
2,273
*»— r^rv
05-1.43
1
.50
1.18
RO
RO
2.22
0.39
2
1
1
0
.09
.31
.42
.56
.67
.64 1,247.07
.86 130.12
.98
.57
.40
.45
.50
.84
.66
.10
.99
0.921-1.025
0
0
0
0
0
0
0
0
0
1
.000
.922
.927
.937
.941
.956
.970
.977
.979
.003
0.855-1.145
0
0
0
0
0
807 . 57 1
88.74 1
1
1
1
1
.000
.964
.976
.986
.992
.000 i:
.006
.012
.021
.033
.038
0.958-1.051
0
0
0
0
.000
.958
.961
.964
000 13C12-PeCDF 123 IS2
007
013
030 13C12-PeCDF 234 SDR2
000 13C12-PeCDD 123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Page No.
10/21/97
Listing of U973262B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
4
NL
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
SN
SN
SN
5
29:15
29:22
29:26
29:34
29:43
29:47
29:56
30:03
30:09
30:16
30:47
31:17
31:29
Peaks
0:00
30:09
30:15
30:47
30:57
31:31
Peaks
0:00
29:39
29:59
30:12
30:24
31:19
31:32
31:40
Peaks
0:00
30:10
30:22
30:54
30:59
31:09
31:18
31:29
31:32
31:39
31:45
Peaks
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
2
1
1
0
0
1
2
0
1
2
0
0
1
.75
.21
.38
.70
.55
.55
.19
.51
.07
.05
.96
.58
.21
1
1
1
0
2
0
2
1
5
2
4
1
1
0
.59
.57
.45
.83
.19
.65
.98
.08
.13
.22
.10
.03
.06
.00
43-0.59
0
0
0
0
0
0
.22
.51
.51
.52
.77
.49
11
2,165
2,517
1,979
8
1.623
.72
.97 727.27
.24 849.00
.95 676.70
.62
.54 533.41
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
967
971
973
977
982
985
990
993
997 123478-HxCDF
001 123678-HxCDF
018 234678-HxCDF
034
041 123789-HxCDF
AN
AN
AN
AN
0.868-1.132
0.
1,438.70 0.
1,668.24 1.
1,303.25 1.
1.
1,090.13 1.
000
997 13C12-HXCDF 478
000 13C12-HXCDF 678
018 13C12-HXCDF 234
023
042 13C12-HXCDF 789
SUR3
IS4
ALT2
ALT1
8,286.70
1.
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
05-1.43
0
0
0
1
1
2
1
0
.76
.92
.51
.48
.68
.21
.03
.69
f w. fw*tus i «MvwA/is f W*A wna
1
1
0
4
2
1
3
0
0
.63
.25
.70
.97
.28
.05
.22
.92
.00
05-1.43
1
1
1
1
1
1
1
0
1
0
1
.09
.40
.69
.24
.24
.58
.21
.40
.08
.87
.64
3
3
7
1,721
2,035
34
2,080
8
34
11
11
5,906
.56
.07
.32
.79 954.16
.52 1.126.67
.88 24.61
.58 1,140.65
.13
.17 17.74
.00
.58
.94
0.952-1.015
0.
0.
0.
0.
0.
1.
1.
1.
000
957
968
975
981
Oil 123789-HxCDD
018
022
AN
0.968-1.032
0.
0.
0.
767.63 0.
908.85 1.
15.57 1.
939.93 1.
1.
16.43 1.
1.
1.
000
974
980
997 13C12 -HxCDD 478
000 13C12-HXCDD 678
005
010 13C12-HXCDD 789
016
018
022
025
SUR4
IS5
RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:41 10/21/97
-------
Page No.
10/21/97
Listing of U973262B.dbf
Matched
-------
Page No.
10/21/97
Listing of U973262B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
0
NL
1
36:24
36:44
37:00
37:06
37:39
38:03
38:23
38:30
38:58
39:09
Peaks
0:00
36:17
36:31
36:48
Peaks
0:00
36:27
Peak
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
0.
RO
1.
0.
1.
1.
4.
0.
1.
0.
0.
0.
78
24
59
13
05
37
10
61
86
70
76-1.02
1.
1.
0.
0.
11
03
17
66
76-1.02
1.
0.
05
85
3.27
1.40
3.65
4.18
1.46
1.23
3.55
4.25
6.00
3.16
0.00
2.21
1.76
1.57
2.72
0.00
1.95
3,166.63
3,166.63
0.999
008
,015
,018
,033
.044
.053
.056
069
1,457.83
1.074
0.890-1.110
0.000
0.995
1.002
1.010
0.995-1.005
0.000
1,708.80 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Tima (nm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*•* End of Report ***
WL-Below Retention Tima Window
HH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:U973262 #1-1024 Acg* 17-OCT-1997 20i33s28 OC EH- Voltage SIR 70S Noise: 853
303.9016 F:2 BSVB(256,30,-3.0) PKB(9, 5,3,0.10\,3412.0,1.00\,P,T) ExptEPCVS2
TRIASOLB LABS Text:PBl-H23 TLI943432
18'tOO IS'tOO 20*00 21iOO 22:00 23:00
P±le*U973262 #1-1024 Acqt17-OCT-1997 20:33:28 OC EH- Voltage SIR 70S Soime*939
305.8987 Pi2 BSVB(256,30,-3.0) PXD(9,5,3,0.10*,3756.0,1.00*fP,T) ExptEPCUS2
TRIANQLX LABS Text:PB1-X23 TLX943432
IOCS
801
18:00 19:00 20:00 21*00 22*00 23*00
PileiU973262 91-1024 Aog* 17-OCT-1997 20*33*28 OC XI* Voltage SIR 70S Hoife:707
315.9419 P:2 BSVB (256,30,-3.0) PXD(9, 5,3,0.10*,2828.0,1.00*,P,T) Exp:EPCUS2
TRIAHQLX LABS Text:PB1-K23 TLI943432
lOOSi
0.
0.
0.
0.
0.
rlle*U973262 91-1024 Acq* 17-OCT-1997 20*33*28 OC XI* Voltage SIR 70S Kolmet865
317.9389 P:2 B3UB(256,30,-3.0) PXD(9,5,3,0.10*,3460.0,1.00*,P,T) Sxp:EPCU32
TRIAHOLX LABS Text:PBl-H23 TLI943432
lOOh
24 tOO
Al.
'l8:00 ' ' ' 19*00 ' ' ' 20*00 ' ' ' 21*: 00
2B7
••
V ,
22:00 '23*00 24*00
-2.1X6-
.1.7X6
.1.3X6
.8.4X5
.4.2X5
0.0X0
Time
X1.4QE7
A
1
H
18<00 15(00 20(00 21(00 22(00 23:00 24*00
.2.6B6
'.2.1S6
.1.5X6
-.1.0X6
-.5.2X5
'• o. oxo
Time
Plle:U973262 91-1024 Acy* 17-OCT-1997 20*33*28 OC EH- Voltage SIR 70S
330.9792 P*2 Exp:BPCUS2
TRIAHOLB LABS Text:PB1-K23 TLX143432
IOC
ffi1^^^
601
401
201
01
21*35
22*22 22*52
23*52
-1.5X7
.1.2X7
-9.1B6
.6.1X6
.3. OSS
18:00 19*00 20*00 21*00 22*00
Plle:U973262 91-1024 Acq* 17-OCT-1997 20*33*28 OC SH- Voltage SIR 70S
375.8364 P*2 Sxp*SPCUS2
TRIAHOLB LABS TexCtFB1-M23 TLI943432
100H
23*00
24*00
.0.0X0
Time
801
601
401
201
0.
22*33 22*58
18*13
20*20
23149
23*351
10(00
19*00
20*00
21:00
22*00
23 tOO
24*00
-2.7X4
.2.1X4
.1.6X4
.1.1X4
.5.3X3
0.0X0
Time
-------
Plle*a973262 01-1024 Acqtl7-OCT-1997 20*33:28 OC Elf Voltage SIS 70S Noise:705
319.8965 P*3 BSOB(256,30,-3.0) PKD(7,5,3,0.10\,2820.0,1.00*,P,T) Exp:EPCUS2
TRIANOLX LABS TexttPBl-M23 TLI043432
lOOS
/'
-------
PilaiU973262 #1-1024 Acqtl7-OCT-1997 20t33t28 QC EI+ Voltage SIR 703 Ko±amt636
339.8597 P*2 BSUB(256, 30,-3.0) PXD(7,5,3,0.10*,2544.0,1.00*,P,T) ExpiBPCUS2
TRIANOLB LABS ToxtiFBl-M33 TLIK43432
24*00 25*00 26:00 27*00 20*00
PlleiU973262 91-1024 Aaqil7-OCT-1997 20*33*2* OC EH- Voltage SIR 70S Noil*1719
341.8567 Pt2 BSUB(2S6,30,-3.0) WtDf7,5,3,0.10*,207tf.O,1.00%,F,S1; SxpiEPCffS2
TRIAHOLB LABS Text t PB1-H23 TLI043432
ion
00:
24:00 25(00 26iOO 27*00 20(00
Pil»:U973262 01-1024 Aaj: 17-OCT-1997 20*33*2* OC JET* Voltage SIR 70S Boime*541
351.9000 Pt2 BSUB(256,30,-3.0) PKD<7,5,3,0.1091,2164.0,1.00t,P,T) Exp:BPCUS2
TRUOfOLE LABS Text > PB1-M23 TLX043432
iom
sol
60:
40:
20:
0.050
Timu
A3.24S4
A1.47S4 I A1.68E4
oj
C5.786
.4.SS6
.3.4E6
'.2.3SS
'.1.1S6
O.OSO
24:00 25*00 26tOO 27*00 20*00
Pil»:U973262 01-1024 Aoqt17-OCT-1997 20*33*2* OC BI+ Voltage SIR 70S Holme:481
353.8970 Pt2 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,1324.0,1.00*,P,T) SxptXPCOS2
TRIANOLS LABS Text >PB1-H23 TLI043432
1009
80:
ffOj
401
20.
0:
A.1.20E7
-3.9B6
-3.1B6
.2.4S6
.1.6S6
.7. 8S5
24iOO 25*00 26tOO 27*00
Pil»:U9732S2 91-1024 Acqtl7-OCT-1997 20*33*2* OC 5X4- Voltafff SIR 70S
330.9792 Pl2 Sxp:EPCUS2
TRIANQLE LABS Text:PB1-M23 TLXX43432
00:
60:
40:
20.
o:
28100
.O.OSO
Tlm»
-1.3S7
-1.0S7
_7. 7S6
-5.2S6
-2.6S6
24*00 25*00 26iOO 27*00
Pll»:U9732S2 §1-1024 Acqtl7-CCT-1997 20i33i2* OC XT* Voltage SIR 70S
409.7974 Pi2 fxp:XPCU32
TRIAKOLS LABS Text:PB1-M23 TLIt43432
25:26
28 tOO
O.OSO
Tlam
24100
25100
26 tOO
27*00
-------
'110IU9732S2 91-1024 Acqt17-OCT-1997 2QI33S2B OC EI+ VOltaga SIR 70S NO18»:696
355.8546 Pt3 BSUB(256,30,-3.0) PKD(5,5,3.0.0S*,2784.0,1.00*,P,T) ExptEPCUS2
TRIANGLE LABS TuxttPBl-U23 TLX#43432
loo*
26tOO 27tOO 28tOO
Pll»iU973262 #1-1024 Aaqt 17-OCT-1997 20t33t28 PBl-H23 TLX143432
100H A8 OSES
80.
60.
40.
20.
0.
8.B7E5
26iOO 27iOO
Pil»tU973262 tl-1024 Acqil7-OCT-1997 20:33t28 OC SIf Voltage SIR 70S
330.9792 Ft2 BxptEPCU32
TRIANOLB LABS Tuct:PBl-H23 TLX«43432
^^^^\* ^^^ Af^ ^k A ^JT AA /V*v AA * ?** •
80.
60.
40.
20.
0.
28:00
26:00
28100
.3.8E6
.3.0B6
.2.3S6
.1.5S6
.7.5S5
O.OEO
Time
2.4E6
.1.9B6
.1.4E6
'.9.6S5
4.8E5
O.OEO
1.3S7
'.1.087
".7.7S6
'.S.1S6
"2.6S6
'.O.OEO
Time
-------
Pile:V9732€2 #1-405 Aey:17-OCT-1997 20:33:28 OC Eli- Voltage SIR 70S Nolse:953
373.8208 Pi3 BSUB(256,30, -3.0) PXD(7,5,3,0.10X,3812.0,1.00*,P,T) Exp:BPCU32
TRIANOLE LABS T«Xt:FBl-M23 TLI943432
100*
29100 30:00 31:00
Pile:U973262 91-405 Aeg:17-OCT-1997 20:33:28 OC SH- Voltage SIR 703 Holse:636
375.0178 P:3 BSUB (256,30,-3.0) PKD(7,5,3,0.10*,2S44.0,1.00\,P,T) Exp:EPCUS2
TRIAKOLB LABS Text:PBl-M23 TLI943432
100*
A6.77S6
29:00 30:00 31:00
File:U973262 91-405 Jicqi 17-OCT-1997 20:33:28 OC EI+ Voltaff* SIS 703 Noit»tl978
383.8639 P:3 BSUB(256,30,-3.0) PKD(7,S,3,0.im,7912.0,1.00*,P,T) Bxp:EPCU32
TRIAKOLS LABS TfXt:PB1-M23 TLI*43432
IOCS
80:
sol
40:
aol
o.
32:00
32:00
J&.33B6
29100 30:00 31:00
Pil»tU9732S2 91-405 Icqt 17-OCT-1997 20:33:28 OC SH- Voltagf SIR 70S Soim91Sl
385.8610 F:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,36604.0,1.00*,P,T) Exp:EPCU32
TRIANOLB LABS TfXtiFBl-H23 TLI943432
32 tOO
8S6
3S6
7S6
1S6
6S5
.OBO
Tim*
1009
80:
sol
40:
20:
o:
7X7
A1.30S7
A1.09B7
29:00 30:00 31:00
Pil»iU973262 91-405 lcq:17-OCT-1997 20:33:28 OC SH- Voltmff* 3IR 70S
392.9760 F:3 Exp:EPCUS2
TRIANGLE IAB3 T»Xt iFB1-M23 TLI943432
32:00
ion
80:
60:
40:
20:
o.
29t07 ' 39tSO ' 30'*3 A 11, 75 31,^* r
J^^r^M^^^^^^
a9'38 39tSO
30'17
29:00 30:00 31:00
P11»:U973262 91-405 Acy:17-OCT-1997 20:33:28 OC JET* Voltage SIR 703
445.7555 P:3 Exp:EPCUS2
TRIAKOLS LABS Text:PB1-K23 TLI943432
100*
32:00
7B6
6B6
4S6
3B6
IBS
.OBO
Time
.8B6
.4E6
.1S6
.7B6
.436
.OBO
Time
29:00
30:00
31:00
32:00
-------
-------
Fil»sU973262 #1-596 Acqsl7-OCT-lS97 20t33i28 OC El* Voltaya SIX 70S Noisai789
407.7818 Fit BSUB(256,30,-3.0) PJO3(7, 5,3, 0.10*, 3156. 0,1.00*,P,T) Xxp,EPCUS2
•RIANOLB LABS Text IPB1-M23 TLI943432
loan
33', 00 33112 33:24 33,36 33,48 34,00 34,12 34,24
Pil»iU973262 91-596 Acqsl7-OCT-1997 20,33,28 OC BH- Voltage SZH 705 Nolle,622
409.7789 P,4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*,2488.0,1.00*,P,T) XxptBPCUS2
TRIANGLE LABS T*xC,PBl-H23 TLI943432
100H A1.21B4
33,00 33,12 33,24 33,36 33,48 34,00 34,12 34,24
Pll»,U973262 »l-59€ Acqil7-OCT-1997 20,33,28 OC SZ> Voltaffu SIS 703 Nol*»,1702
417.8253 Fi4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*, 6808.0,1.00*,P,T) Kxp,BPCUS2
TRIANGLE LABS TfXt,FB1-K23 TLH43432
34,36
34,36
ion
sol
fol
40:
20:
A4.72E6
A4.18E6
33,00 33,12 33,24 33,36 33,48 34,00 34,12 34,24
Pll»,U973262 91-596 Acq,17-OCT-1997 20,33,28 OC BX+ Voltmfff SIR 70S Nolm»i2280
419.8230 Pi4 B3UB(2S6,30,-3.0) PKD(7,5,3,0.10*,9120.0,1.00*,P,T) Xxp,BPCUS2 "'
TRIANQLE LABS T»xC tPB1-H23 TLHf43432
100H
80:
60:
40:
20:
A9.66S6
33,00 33,12 33,24 33,36 33,48 34,00 34,12
Pll»,U973262 f 1-596 Aogtl7-OCT-1997 20,33,28 OC SXf Voltagm SUt 70S
430.9729 Pi4 Exp,BPCUS2
TRIANGLE LABS T*xC:PBl-M23 TLH43432
33151
34,24
1003
flOJ
ffflj
40:
20:
OJ
32,59
33112
33,24
33,00 33tl2 33,24 33,36 33,48 34,00 34,12
Pllf,U973262 91-596 Acq,17-OCT-1997 20,33,28 OC Sit- Volt»g» SIR 70S
479.7165 Pi4 Bxp,SPCVS2
TRIANOLS LABS T*xClPBl-lt23 TLH43432
loan
34,24
80:
60:
4 a:
20:
0:
33/13
32(50
33,26
33141
34,20
33(00
33(12
33,24'
33,36
33,48
34i60'
34112
34,36
34,36
34,36
34,40
i i I i i
34,36
.0. OBO
Tim»
1.8B6
1.4E6
.1.1S6
7.2*5
3.6B5
.0.050
Tim*
.4.2E6
.3.4B6
.2.5S6
.1.7B6
.8.5BS
.0.0X0
Tin*
4.1S6
.3.3X6
'•.2.5X6
11.7X6
:8.3X5
0.0X0
-3.0B4
.2.4X4
.1.8X4
.1.2X4
.6.1X3
0.0X0
Mm*
-------
fil»:U9732S2 M-5S6 Acq: 17-OCf-i997 20,33,28 OC BT* Voltage SIR 70S tbis»tS51
433.7766 Fit BSUB(256,30,-3.0) PKD(7, 5,3,0.10\,2204.0,1.00*,Z,T) BxpiXPCOS2
THZANOLE LABS TfXt,PBl-M23 TLI1t43432
A2.J.7E4
A1.24E4
33il2 33'tlB 33:24 33,30 33,36 33,42 33:48 33:54 34:00 34:06
Pll»,U973262 #1-596 Acq,17-OCT-1997 20:33:28 OC XX+ Voltagt SIR 703 Solm»:416
425.7737 Ft4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*,1664.0,1.00*,P,T) X3tp,XPCVS2
TRIANOLB LABS TfXttPBl-M23 TLX#43432
lOOSt
80.
34:12 34:18 34:24 Tia»
.6.2E3
.4.9S3
33:12 33:18 33:24 33:30 33:36 33l42 33:48 33:54 34:00 34:06 34:12
P11»:U973262 «l-596 Atojt 17-OCT-1997 20:33:28 OC BH- Voltage SIR 70S So±au:1744
435.8169 Fi4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,6976.0,1.00*,P,T) BxptSPCUS2
TRUUfOLB LABS T»Xt:PBl-M23 TLIV43432
lOOH A9.55S6
80.
60.
40.
30.
LO.OEO
'34lie ' 34124 Mae
.3.7S6
.2.9E6
J.2S6
.1.5S6
.7.3B5
O.OBO
33:12 33:18 33:24 33,30 33:36 33,42 33,48 33,54 34,00 34,06 34:13
P11»:U973262 fl-5S6 Acy:17-OCT-1997 20,33,28 QC EH- Voltafff SIS 70S Hoia»ti619
437.8140 Pit B3UB(256,30,-3.0) PKD(7,5,3,0.10*,6476.0,1.00\,P,T) Xxp,XPCOS2
TRIANOLB LABS T»xt:PBl-M23 TLIS43432
A9.47S6
80.
60.
40.
20.
34:18 34.124 Man
.3.SE6
.2.8B6
.2.1E6
.1.4E6
'.7.0B5
33:12 33:18 33:24 33:30 33:36 33:42 33:48
Pil»iO973362 tl-596 Acqt 17-OCT-1997 20:33:28 OC EH-
430.9729 Pi 4 Sxp:SPCU32
TRIANGLX LABS T«urC>FBl-M33 TLIt43432
lOOSi 33tl2 33,111 33t24 it, in . . 33t51
O.OBO
33:54 34:00
SIR 70S
34:06 34:13 34x10 34:24 Tim*
80.
60.
40.
30.
0.
33:18
33:30..
34:08
34,21
.3.2B6
.2.4X6
.1.6X6
.8. OSS
0.0X0
33:12 33:18 33:24 33:30 33:36 33:42 33t4B 33:54 34:00 34:06 34:12 34:18 34^24 Timu
-------
'±10:0973262 #1-596 Acq: 17-OCT-19S7 20:33:28 OC EH- Voltaffa SIR 70S Nolaa:728
441.7438 Pi4 BSUB(256,30,-3.0) PXB(7,5,3,0.10X,2912.0,1.00*,P,T) ExptEPCUS2
TRIANGLE LABS ToxttFBl-M23 TLI*43432
100*
A2.99E4 A2.41B4
33*00 34:00 35.00 36:00 37:00 36:00
Pll»tO973262 #1-596 Acqt 17-OCT-1997 20:33:28 OC SH- Voltaym SIR 70S Nola»:770
443.7399 Pt4 BSUB(2S6,30,-3.0) PKD(7,S,3,0.10X,30BO.O,1.00*tP,T) ExptEPCU32
TRIANOLE LASS TutttPBl-lOS TLH43432
A2.29E4
A2.19E4
A1.0SE4
.S8E
39100
33tOO 34:00 35:00 36:00 37:00 38:00
Pll»:U973262 #1-596 Acq: 17-OC7-1997 20:33:28 OC Eli- Voltage SIR 70S
430.9729 Pt4 Exp:EPCUS2
TRIANGLE LABS TmxttPBl-M23 TLIt43432
35f44 ig,n 37tl4
39 tOO
33lOO 34:00 35:00 36tOO 37': 00
Pll»tU973262 #1-596 Acq: 17-OCT-1997 20:33:28 OC EH- Voltaff* SIR 70S
513.677S Pt4 ExptSPCUS2
TRIANOLE LABS Tf3rttPBl-M23 TLH43432
33:00
39 tOO
33 tOO
34:00
35:00
36:00
37:00
38:00
39 tOO
-------
?ila:l}373262 91-596 Acq: 17-OCT-1997 20:33:28 OC EH- Voltay a SIR 70S Soia»>649
457.7377 P*4 BSVB(256,30,-3.0) PXD(7,5,3,0.10*,2596.0,1.00X,P,T) E3cp*BPCUS2
TRIANGLE LABS Tf3CtiPBl-M23 TLI043432
100H A3.30E4
36:18 36*24 36*30 36*36 36*42 36i4B
Pll»*U973262 tl-596 Acytl7-OCT-1997 20t33t2B OC EH- Voltage SIS 70S Noise,583
4S9.7348 Pt4 B3UB(2S6,30,-3.0) PXD(7,5,3,0.10*,2332.0,1.00*,P,T) Exp,EPCUS2
TRIAHOLB LABS T»Xt,FBl-H23 TLZ#43432
100H A4.46B4
36tlB 3fi24 36t30 36t36 36i42 36i4B
Pil»>U973262 f 1-596 Acytl7-OCT-1997 20l33t28 OC EH- Voltafff SIX 703 Noim»t539
469.7779 Pt4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,2156.0,1.00*,F,r) SxptEPCUSS
TRIANOLB LABS T*3tt tPB1-M23 TLIt43432
100H A1.46S7
.'.*'
36tl8 36,24 36i30 36t36 36*42 -36t48
P±lftO973262 tl-596 Actjt 17-OCT-1997 20t33t28 OC BI+ Voltagf SIR 70S Soimmi'515 .
471.7750 Pl4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,2060.0,1.00*,P,T) SxptBPCU32
TBIAKOLS LABS Tnct tPB1-H23 TLI#43432
100H A1.J1S7
BO!
60.
40.
20.
36,18 36,24 36,30 36,36 36,42
Pil»iU973262 tl-596 Acqil7-OCT-1997 20i33t28 OC SH- Voltagm SIR 70S
430.9729 Pi4 SxpiBPCUS2
TRIAKOUS LABS T»xtiPBl-M23 TLIt43432
36*20
36l48
36*54
BO.
60.
40.
20.
0.
36*18
'36*24
'36*30
'36*36
36*42
'36\4B
36,54
36,54
36*54
36*53
i I i
36,54
.0.050
Tim*
.4.7S6
.3.'7Bg
.3.8S6
.1.9E6
.9.3X5
.O.OSO
Vim*
S.5S6
.4.4E6
.3.3B6
.2.2B6
.1.1E6
O.OSO
r4.4S6
.3.5BS
.2. TBS
.l.BSS
.8. BBS
O.OSO
tta*
-------
Peak Locate Examination:17-OCT-1997:20:32 File:U973262
-------
File:U973262 ttl-596 Acq:17-OCT-1997 20:33:28 GC EH- Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:PBl-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100i.34f45
36:27
80J
60J
40J
20J
35:39 36:00
29
38:21
35:00 36:00 37:00
File:U973262 #1-596 Acq:17-OCT-1997 20:33:28 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:FBl-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
10 0*
35:26 36:2(7 36:48
34:44 ----- . I
60 j
40 j
20 j
38:00
38:17
35:00 36:00 37:00
File:U973262 #1-596 Acg:17-OCT-1997 20:33:28 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:FBl-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36;27
80J
60 j
40J
20J
38:00
_2 . 9E4
_2.3E4
_1.8E4
_1.2E4
_5.9E3
O.OEO
Time
.2. 6E4
2. 1E4
.1.6E4
1. 1E4
.5.3E3
.O.OEO
Time
35:00
36:00
37:00
38:00
4.7E6
3.7E6
2.8E6
1.9E6
9.3E5
.O.OEO
-------
.. > '« ^ .. '"f \
s
™>; * \/. T > «/-jv *""•;'««
* "*T**»*-&*J6;
"^ ,\,^ 0 v\^^«W«*f*
TLI Project:
Client Sample
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
43432
: FB2-M23
Saginaw, MI
M23TRAIN
185-6-6A-C
1.000
n/a
DB-5
> *^>5^\ v ^ - -5S ^ * "^^^fe-
% A* Xvi f. A\. V, •, _. ^^ VX5S&
• Fri^rjrnnrri^rt fai Qp
K^l^a^ij«Miine^»ai\*3^
$£&•'$$& K<* ^ " "$>" \ ""x"-' ' " ;
^^f^^^ V55'*"* ' ,' \-^^ ov'\M...*i.*..*....\.r.
Method 23 PCDD/PCDF Analysis (a)
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/17/97
Dilution Factor: n/a
Blank File: U973257
Analyst: BB
Analysis File: U973263
Spike File: SPX23704
ICal: UF59167
ConCal: U973252
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
AhaJytes v "* \ \*
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
U,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
,,- , -- ; -, ^ ^ '^'-^^4jn
^ *^ % .. % ,vJ^ . ....... s »% «
ND
ND
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
j^T-i '^"l&V ^\^JsMNM§
"••? , fV. ,^^**v» ^ i»^ •., '• < &?
0.006
0.008
0.01
0.009
0.009
0.01
0.01
0.03
0.007
0.006
0.007
0.005
0.006
0.007
0.008
0.01
0.01
tf^^^^f^jipC;^^!^, "xs-l-^feHte " -
v^ % ff£ \"':. ' '' •.%?• •• ™. * ° .?^% **^
Totals ^ , j^ps ^V*IM'^Y^ *
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
EMPC
ND
ND
ND
0.006
0.008
0.01
0.01
0.03
0.006
0.006
0.009
Page 1 Of 2
X2I7.PSR V2.00, LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
x »sV*1 v ***ur^?l
TLI Project: 43432
Client Sample: FB2-M23
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973263
Internist Standards ••''••
13C,2-2,3,7,8-TCDF
13Ci2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
% %Amf» CBS&^S
3.2
3.6
3.5
4.0
4.1
4.0
3.3
3.8
7.6
r'v%R»c«v»fv
78.9
90.2
87.5
100
102
101
82.1
94.8
95.1
->;acum|S^
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
\ Ratio*
0.78
0.79
1.48
1.44
0.50
1.18
0.43
1.01
0.90
JBT: ,-; flags. ,>;
21:32
22:27
26:16
27:27
30:14
30:58
33:01
33:53
36:26
$«rr<*g^Sta^ante^
37Cl.-2,3,7,8-TCDD
1JCir2,3A7,8-PeCDF
'3C,2-l,2,3,4,7,8-HxCDF
I3C,2-l,2,3,4,7,8-HxCDD
t3C,2-l,2,3,4,7,8,9-HpCDF
3.6
3.8
3.8
4.0
3.5
89.0
94.4
95.3
99.6
88.0
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
1.53
0.51
1.21
0.41
22:28
27:05
30:07
30:53
34:14
^Mtei^S&rida^^^^
13C,2-l,2,3,7,8,9-HxCDF
13C.2-2,3A6,7,8-HxCDF
Recovery Standards i: ,\r;
13C12-1,2,3,4-TCDD
'3C,2-l,2,3,7,8,9-HxCDD
3.7
4.2
* "V- % ^V s -X Ms >
*% •• •••••>•• •* s*** •• ~-\
93.3
104
w *••"•••' '* V *fyk : :: ""> "~ •!"
•.fjf... jf\ \ %V %^.
40%-130%
40%-130%
V>' ^5|f£
0.49
0.50
!;, Ratio--' \;
\
0.83
1.18
31:30
30:46
^RT^f^lagsV
22:13
31:16
Data Reviewer
Page 2 of 2
10/23/97
X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Initial
---- Date. . .
Data Review By:
.
•
n 't •
J_i_/ _ / _
Calculated Noise Area:
2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/23/97
Listing of O973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
K
DC
DC
DC
304-306
13C12-TCDF
316-318 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
316-318
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
WL
ML
WL
WL
WL
WL
SN
SN
SN
SN
WH
WH
WH
1
0:00
17:40
17:46
18:11
18:51
19:28
19:46
20:11
20:26
20:39
20:46
21:03
21:34
22:05
23:10
23:39
Peak
0:00
17:55
19:14
19:43
19:55
20:09
20:31
21:32
21:48
22:06
22:19
22:27
23:00
23:15
23:48
Peak
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0
0
0
1
0
0
0
0
0
0
0
.79
.72
.14
.17
.87
.75
.87
.60
.76
.44
.24
0.22
0
.94
0.47
0
0
.27
.87
2
5
0
2
18
3
16
9
3
2
1
3
21
8
0
3
21
.76
.36
.37
.57
.24
.60
.70
.06
.70
.71
.38
.47
.47
.74
.74
.82
.47
65-0.89
1
1
1
0
1
0
0
0
0
0
1
1
1
0
0
.06
.01
.94
.29
.36
.67
.48
.78
.81
.96
.31
.45
.51
.44
.78
lV»/r
1
3
1
1
2
46
4
3,180
7
22
7
7
6
3
4
3,180
tTA . TTff
.38
.01
.66
.17
.05
.27
.14
.34
.09
.37
.54
.49
.57
.54
.70
.34
p /
0.813-1.106
0.000
0.820
0.825
0.844
0.875
0.904
0.918
0.937
0.949
0.959
0.964
0.978
11.44
12.13
.002 2378-TCDF
.026
.076
AN
1,391.79
1.098
0.954-1.046
0.000
0.832
0.893
0.916
0.925
0.936
0.953
1,788.55 1.000 13C12-2378-TCDF ISO
1.012
1.026
1.036
1.043
1.068
1.080
1.105
TCDD Follows
TCDD
320-322
0.65-0.89
DC NL 0:00 RO 0.99
DC SN 19:36 RO 7.53
DC SN 21:59 0.89
DC SN 22:10 RO 0.93
1.43
0.53
1.55
5.50
0.848-1.061
0.000
0.873
0.979
0.987
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page No.
10/23/97
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
DC
DC
DC
DC
SN
SN
SN
WH
0
22:30
22:51
22:58
23:56
Peaks
RO
RO
RO
RO
0
1
0
1
.56
.42
.44
.80
5
1
0
1
0
.31
.47
.71
.54
.00
1.
1.
1.
1.
002
018
023
066
0.911-1.089
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
ML
WL
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
HL
SN
SN
SN
SN
SN
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
19:12
19:54
20:43
22:28
22:51
22:59
23:12
23:19
23:26
23:33
23:56
24:11
Peaks
0:00
19:31
20:56
22:13
22:27
22:51
22:59
23:08
23:37
23:46
24:03
24:15
Peaks
0:00
23:48
23:57
24:29
25:06
25:16
25:30
25:40
25:46
26:09
26:17
26:30
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
• 2
2
0
2
0
54
.435
7
5
5
2
6
6
4
2
,489
.76
.18
.92
.32 54.32
.30 2,435.30
.18
.77
.43
.54
.43
.69
.86
.72
.62
65-0.89
2
1
1
0
0
1
0
0
1
0
0
0
.49
.35
.44
.83 2
.79 2
.07
.63
.79
.24
.53
.58
.38
5
32-1.78
0
0
0
1
2
1
1
3
0
0
3
2
.84
.64
.95
.25
.62
.02
.38
.30
.57
.66
.09
.85
1
2
14
,898
,900
48
12
8
4
7
6
6
.45
.50
.96
.12 1,311.33
.22 1,277.31
.78 29.44
.18
.84
.46
.01
.76
.02
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
855
886
923
001 37C1-TCDD SUR1
018
024
033
039
044
049
066
077
0.911-1.089
0.
0.
0.
1,586.79 0.
1,622.91 1.
27.56 1.
1.
1.
1.
1.
1.
1.
000
869
932
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
018
024
030
052
059
071
080
,847.12
TCDD / PftCDF Poll ows — —
i
i
5
1
3
12
6
1
0
1
1
1
.04
.65
.28
.74
.42
.17
.20
.63
.99
.55
.89
.56
0.906-1.077
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
906
912
932
956
962
971
977
981
996
001 12378-PeCDF AN
009
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:43 10/23/97
-------
Page No.
10/23/97
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
ML
SN
SN
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
SN
SN
26:44
26:50
27:04
27:15
27:27
27:47
27:57
28:01
28:12
28:32
28:45
Peaks
0:00
25:17
25:52
26:16
26:36
27:05
27:20
28:07
Peaks
0:00
25:35
26:17
26:21
26:31
26:40
26:43
27:10
27:22
27:54
28:05
28:27
Peaks
0:00
25:31
25:42
26:24
26:34
27:14
27:27
27:38
27:52
28:00
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
1.
1.
1.
11.
1.
0.
0.
39
25
55
18
11
22
18
19
48
91
58
0
0
4
1
1
1
1
0
0
1
1
0
.74
.66
.08
.17
.37
.53
.74
.41
.77
.41
.65
.00
32-1.78
1.
1.
2.
1.
0.
1.
2.
1.
00
65
20
48
98
53
86
73
32-1.78
1.
1.
0.
0.
0.
4.
1.
0.
1.
0.
0.
0.
10
33
67
55
64
86
34
99
46
97
68
53
1
63
13
2,774
22
2.540
3
11
5,378
.30
.39 39.48
.80
.19 1.654.48
.57
.82 1.534.67
.29
.37
.40
1
1
1
1
1
1
1
1
1
1
1
'
.018
.022
.030 23478-PeCDF AN
.037
.045
.058
.064
.067
.074
.086
.095
0.848-1.152
0
23.91 0
0
1,119.71 1
1
1,006.15 1
1
1
.000
.963
.985
.000 13C12-PeCDF 123 IS2
.013
.031 13C12-PeCDF 234 SUR2
.041
.070
PoCDF / PfeCDD Follows —
i
i
2
1
2
1
1
1
1
1
0
1
0
.28
.61
.52
.27
.07
.45
.59
.63
.18
.04
.89
.17
.00
32-1.78
0.
2.
1.
2.
1.
0.
1.
1.
1.
0.
74
47
46
19
31
63
44
59
25
91
0
0
1
2
2
1
1.744
175
4
4
.97
.97
.99
.88
.53
.23
.52 1.030.41
.78 107.86
.87
.98
0.921-1.025
0
0
0
0
0
0
0
0
0
1
1
1
.000
.932
.957
.960
.966
.971
.973
.990
.997
.016
.023
.036
0.855-1.145
0
0
0
0
0
0
714.11 1
67.92 1
1
1
.000
.930
.936
.962
.968
.992
.000 13C12-PeCDD 123 IS3
.007
.015
.020
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:43 10/23/97
-------
Page No. 4
10/23/97
Compound/
M_2.... QC.Log Omit Why
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
WH
WH
WH
0
NL
SN
SN
SN
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
28:16
28:34
Peaks
0:00
29:15
29:34
30:41
30:47
30:53
31:37
31:57
32:02
32:08
Peaks
0:00
29:05
29:13
30:07
30:14
30:23
30:35
30:46
31:01
31:30
31:40
31:44
31:57
Peaks
0:00
29:31
29:33
29:37
29:47
30:08
30:14
30:36
30:45
30:54
31:17
31:28
31:33
Peaks
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
0
.00
.67
05-1.43
0
0
0
1
1
1
0
5
0
0
.97
.81
.51
.25
.11
.17
.57
.19
.92
.89
8
4
.19
.13
1
1
.030
.041
1,920.30
2
3
0
1
6
2
0
0
0
1
0
.33
.63
.74
.89
.52
.47
.58
.36
.87
.12
.00
43-0.59
1
0
0
0
0
0
0
0
3
0
0
2
7
.51
.50
.51
.51
.50
.30
.09
.50
.73
.49
.53
.05
.14
05-1.43
1
0
1
0
0
1
0
0
1
0
1
3
0
.20
.56
.41
.62
.55
.25
.92
.82
.02
.62
.65
.54
.70
3
10
25
2,283
2.459
20
7
2,359
6
1,997
17
8
1
9,099
.16
.55
.56
.17 769.43
.91 817.06
.76
.79
.53 790.89
.90
.36 656.52
.78
.71
.19
.97
0.958-1.051
0
0
0
1
1
1
1
1
1
1
.000
.967
.978
.015
.018 234678-HxCDF
.021
.046
.057
.060
.063
AN
0.868-1.132
0
0
0
1,513.74 0
1,642.85 1
1
1
1,568.64 1
1
1,340.84 1
1
1
1
.000
.962
.966
.996 13C12-HXCDF 478
.000 13C12-HJCCDF 678
.005
.012
.018 13C12-HXCDF 234
.026
.042 13C12-HXCDF 789
.047
.050
.057
SOR3
IS4
ALT2
ALT1
1
0
1
1
1
3
3
0
3
1
2
0
0
0
.80
.69
.06
.30
.28
.76
.05
.65
.56
.81
.80
.63
.96
.00
0.952-1.015
0
0
0
0
0
0
0
0
0
0
1
1
1
.000
.953
.954
.956
.962
.973
.976
.988
.993
.998 123478-HXCDD
.010 123789-HxCDD
.016
.019
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page Ho. 5
10/23/97
Compound/
H_Z.... QC.Log Omit Why
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
3
NL
WL
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
2
NL
SN
SN
SN
WH
0
NL
SN
SN
SN
0:00
30:20
30:39
30:53
30:58
31:05
31:16
31:23
31:35
31:39
31:48
Peaks
0:00
32:50
32:58
33:03
33:11
33:14
33:22
34:23
34:41
Peaks
0:00
33:01
34:14
34:28
34:35
Peaks
0:00
33:11
33:54
34:00
34:13
Peaks
0:00
33:16
33:53
34:03
34:14
1.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
0.
RO
RO
RO
RO
0.
RO
RO
RO
RO
05-1.43
1.
0.
2.
1.
1.
1.
1.
1.
0.
1.
1.
16
94
03
21
18
94
18
65
39
76
19
88-1.20
1.
2.
5.
1.
1.
4.
1.
0.
3.
35
04
02
05
39
94
72
92
76
2.
10.
0.
1,900.
2,128.
28.
2,191.
18.
13.
14.
10.
6,220.
64
57
67
63 1,040.31
10 1,153.87
94
63 1,188.48
41
26
94
48
36
0.968-1.032
0.
0.
0.
860.32 0.
974.23 1.
1.
1,003.15 1.
1.
1.
1.
1.
000
980
990
997 13C12-HXCDD 478
000 13C12-HXCDD 678
004
010 13C12-HXCDD 789
013
020
022
027
SUR4
IS5
RS2
2.
1.
1.
4.
2.
0.
1.
2.
1.
0.
06
04
08
52
02
67
90
46
47
00
37-0.51
0.
0.
0.
0.
0.
47
43
41
52
14
11.
1,715.
1,333.
13.
9.
3,048.
u»*^nc
88-1.20
1.
0.
0.
1.
16.
15
61
33
22
17
1.
2.
1.
1.
0.
0.
15
36 513.44
53 389.61
15
13
89
40
22
14
04
24
00
88-1.20
1.
1.
1.
6.
0.
25
22
01
04
59
5.
8.
1,907.
6.
12.
47
24
82 956.89
55
63
0.996-1.043
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
994
998
001 1234678-HpCDF
005
007
Oil
041
050
AN
0.939-1.121
0.
1.201.92 1.
943.92 1.
1.
1.
000
000 13C12-HpCDF 678
037 13C12-HpCDF 789
044
047
IS6
SUR5
0.977-1.005
0.
0.
1.
1.
1.
000
979
000 1234678-HpCDD
003
010
AN
0.971-1.029
0.
0.
950.93 1.
1.
1.
000
982
000 13C12-HpCDD 678
005
010
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:43 10/23/97
-------
Page No.
10/23/97
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
436-438
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
34:19
Peak
0:00
32:54
33:18
33:32
33:43
34:07
34:43
35:09
35:15
35:31
35:56
36:28
36:58
37:07
37:51
37:57
38:51
39:12
39:23
Peaks
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
.20
76-1.02
1
0
0
1
0
4
0
1
0
0
1
0
0
0
1
0
0
0
1
.09
.24
.28
.67
.83
.23
.15
.00
.97
.85
.32
.67
.19
.64
.30
.66
.42
.78
.51
11.75 1.013
1,907.82
Above: HpCDD / Octa-CDD and CDP Follows
2.12
1.23
1.36
0.45
2.16
0.59
0.55
1.52
0.69
4.08
2.55
3.57
1.87
4.61
2.68
3.89
2.89
3.24 1.076
3.33 1.081
0.00
0.890-1.110
0.000
0.903
0.914
0.920
0.925
0.936
0.953
0.965
0.968
0.975
0.986
.001
.015
.019
.039
.042
.066
OCDD
458-460
458-460
0.76-1.02
DC NL 0:00 0.82
DC SN 36:33 0.96
DC SN 36:50 RO 0.70
0 Peaks
1.98
2.31
1.85
0.00
0.890-1.110
0.000
1.003
1.011
13C12-OCDD
470-472
470-472
DC
DC
DC
NL
WH
WH
1
0:00
36:26
36:45
36:51
Peak
0.
RO
RO
76-1.02
0.
0.
0.
1.
88
90
31
85
1
3,182
10
10
3,182
.99
.05
.89
.41
.05
0.995-1.005
0.000
1,508.40 1,673.65 1.000 13C12-OCDD
1.009
1.011
IS8
Column Description "Why Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*** End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below signal to Noise Level
-------
File
303.
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IU9732S3 #1-1024 Ac?: 17-OCT-1997 21 1 17 1 12 QC EH- Voltage SIR 70S Noiaet608
9016 Pi2 BSU3(256,30,-3.0) PKD(9,5,3, 0.10*, 2432.0, 1.00*,F,T) BxpiB?CUS2
VOLE LABS Text:FB2-M23 TLIV43432
A8.47E4
A1.14B5
lac VIVA A1.72S4 ft A3.80E4
11 * /*• • y T£WA I t| k
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tU9732S3 #1-1024 Acy: 17-OCT-1997 21(17(12 OC BI+ Voltage SIR 70S Noise t 771
8987 Pi2 BSUB(256,30,-3.0) PXD(9,5,3, 0.10*, 30B4.0, 1.00*,?,T) SxptEPCUS2
HOLS LABS TmrttPB2-M23 TLHf43432 X/
A9.77E4 JL6.54E4 (1
If 'Til J Tr\ ili "'jnr*
ft) A1.45E4 Jfil jjiyj 1 ftljll M I l|J \ lit F 1. If JJJ ' •*V'
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10(00 ' 19(00 20(00 ' 21(00 ' 22(00 ' 23(00 ' 24(00
10973363 fl-1024 AO9(17-OCT-1557 21>17(12 OC BX* Voltage SIR 705 lft>i««t*ltf
5<15 Pi2 BSUB(25Sf30,-3.0) tXD(9,5,3,0.10*,1664.0,1.00\,P,T) ExpiEPCUS2
SOLS LASS TexttPB2-M23 TLH43432
A1.39S7
1
10(00 19(00 20(00 21(00 22(00 23(00 24(00
:U9732S3 fl-1024 Acq>17-OCT-1997 21(17(12 OC BI+ Voltage SIR 70S Kol*et38a
9389 Pt2 BSUB(256,30,-3.0) PKD(9, 5,3,0.10*, 1552.0, 1.00*,P,r) BxptBPCUS2
SOLS LABS TmxtiPB2-M23 TLH43432
Al. 9S7
T ' *1
10(00 19 t 00 20(00 ' 21(00 ' ' 22(00 ' ' ' 23(00 ' ' ' 24(00
IU9732S3 01-1024 Acqtl7-OCT-1997 21(17(12 OC Slf Voltafff SIR 70S
9792 P:2 SxptSPCUSa '••
HOLS LABS TexttPB2-M23 TLI043432
UJ(iS^*^-^k^^
10(00 19(00 20(00 21(00 ' ' 22(00 23(00 24(00
,0973263 tl-1024 Acqt 17-OCT-1997 21(17(12 OC SZ* Voltag. SIJl 70S
03(4 P(2 SxptSPCUSa
HOLS LABS Text:PB2-H23 TLH43432
IB i 20 1 22(03 32>36
Ar*AU._AA-, >.^./» .. JJJ3t3f IT. .i »,......, A-..» *^"" *L *• ^. - •* 3 •> ^JfA^r.n, ^ fy.JU .^^Jtx^jjj J> ' . j - M
_2.0£4
.1.CE4
.1.2JB4
_0.1£3
_4.1E3
Time
-2.3S4
.1.954
.1.4£4
.9.3X3
Time
^.7S6
.2.2SS
.1.6S6
.1.125
.5.455
.0.050
Time
3.3S6
-2.SE6
.2. OSS
-1.3B6
.6.5S5
.0.0X0
Time
7.9S6
.S.3ES
'•-4.BS6
.3.2SS
-.1.6S6
io.OEO
Tim
3.424
.2.754
L2.154
.1.454
.S.9S3
o.oxo
10*00 19 tOO 20(00 21(00 ' 22(00 23(00 ' 24(00 Tlae
-------
PlletU973263 01-1024 Acqt 17-OCT-1997 21(17(12 OC EI+ Voltage SIX 70S Soiset399
319.8965 Pi2 BSUB(2S6,30,-3.0) PXD (7, 5, 3, 0.10%, 1596.0,1. 00%, P,T) ExptEPCUS2
TRIANQLS LABS TextiPB2-M33 TLI043432
i00* , »J-=..'Vf-7
00:
60:
40:
20.
kA1.30B4 A2.BBB4 '
|| «•«»« U.03fe4 |
k\4 i ""rlil 1 IAr5'l°7B3| 11 Illm'*1'iffl"
/%l»v^[/wlW WWW I/WV %Jkjb«
20(OO 21(00 ' 22(00 23(00
PiletU973263 $1-1024 Acytl7-OCT-1997 21(17(12 OC EH- Voltage SIS 70S Soieei404
331.8936 Pt2 BSUB(2S6,30,-3.0) P1O}(7,S,3, 0.10*, 1616.0,1.00*,P,T) BxpiBPCUS2
TRIANQLB LABS TexttPB2-H23 TLI043433
1003
80.
60:
40:
r '
N-
<•"> ^
_^S£.-7^=- ^,-'-/ 9.0E3
f \-\l\ fyf**"
111 11
1 i iln IA M
^Mi^k
.7.2E3 '
.5.4B3
.3.683
.1.053
34 1 00 Time
A1.46E4
i ., ,__. I A4.13S4
A1.42E4 A1.3SX4 \ ,,
jJly^vJ^XX^
'20iOO 21(00 22(00 ' 23(00
Pil»iO973263 01-1034 Acqtl7-OCT-1997 21(17(12 OC BI+ Voltage SIX 70S Sbl««(10J8
331.9368 Pt3 BSUB(256,30, -3.0) PKD(7, 5,3,0.10*, 4072. 0,1. 00*,F,T) gxptSPCU32
TRIAKOLS LABS TextiFB2-M23 TLI043432
ion
00:
60:
40:
20:
o:
A1.31S7
i ft
A fl
1 U V
20(00 ' ' ' ' '21(00 22(00 23(00'
PlletVS73363 01-1034 Acqt 17-OCT-1997 21(17(12 OC XI+ Voltage SIX 70S So±mei411
333.9338 Pi3 BSUB(2S6,30,-3.0) PXD(7, 5,3,0. 10*. 1644. 0,1. 00*,P,T) gxptgPCOS2
TRIANOLB LABS Text:FB2-M23 TLI043432
IOCS
80:
60:
40:
so:
0-
"'f*7/!
fl
/ \l \
' 20(00' ' ' '21iOo' ' ' ' 22 tOO 23(00
PlletV973263 01-1024 Acyt 17-OCT-1997 21(17(12 OC EI+ Voltage SIS 70S Soieet382
327.8847 Pi3 BSTJB(256,30, -3.0) PXD(7, 5,3, 0.10*, 1528. 0,1. 00*,P,T) BxptBPCUS2
TRIANQLS LABS Text I PB3-K33 TLI043433
ion
80:
tfoj
40J
20:
o_:
A3.44E7
fl
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20(00 21(00 '22(00 23(0o'
PiletU973263 01-1024 Acqt 17-OCT-1997 21(17(12 OC EH- Voltage SIM 70S
330.9792 Pi 2 XxptBPCUS2
TRIAKQLX LABS TextlPB2-M33 TLI043432
100J
00.
60.
40.
20.
0.
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'•.1.4E4
Ll.154
17.1S3
'-3.6E3
24 (00 Tine
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-3.7B6
.2.2E6
.1.6B6
'•.1.1S6
Is.SBS
' O.OBO
24 1 00 Time
3.3E6
.3.7B6
-.2.0E6
.1.3E6
'•.6. 7E5
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24 ( 00 Time
-5. IBS
.4.1B6
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' 34 tOO' rio»
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20(00 21(00 22(00 23(00
-7.1B6
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IU973263 #1-1024 Acqi 17-OCT-19S7 21(17(12 OC EH- Voltage SIR 703 Kolaei315
0597 Fl2 BSUB(256,30,-3.0) PXD(7,S,3,0.10*,1260.0,1.00*,F,T) Exp:EPCUS2
HOLE LABS Text,FB2-H23. TLI#43432
1
J
2<
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85
iro
J
ji 1 AS . 29X4 * « o « 04
mo A fvA 1 1 A3 60E4 \ \ * yijs*
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1 1 MJlAl lid" 9OVA K I II A1.0fK4
IIOO' ' ' ' 25(00 2ff(00 ' ' ' '27(00 20(00'
'973263 #1-1024 Acqil7-OCT-1997 21(17(12 OC EH- Voltage SIR 703 Holme, 376
67 Fi2 BSUB(256,30,-3.0) PKD(7,5,3f 0.10*, 1504. 0, 1.00\,P,T) BxpiXPCUS2
LX LABS Text!FB2-M23 TLI#43432
\A7.26S4
\ |
ill *1-"Z4 A1.60X4
\^J^^
J^h\
OOB4
iLu.
24(00 25(00 2*(00 27(00 20(00
117973263 #1-1024 Aetjil7-OCT-1997 21(17(12 OC EI+ Voltage SIR 703 Nolte,397
9000 P:2 BSUB(256,30,-3.0) PXD(7, 5,3,0.10*, 1588. 0,1. 00*,P,T) Exp:EPCU32
HOLS LABS TexttFB2-U23 TLI#43432
A1.6SX7
j| A1.53S7
i
J V J Vj
24(00 25(00 2tf(00 27(00 20(00'
IU973263 #1-1024 Aeqtl7-OCT-1997 21(17(12 OC XI* Voltage SIR 708 Holmes 396
8970 Ft2 BSUB(2S6,30,-3.0) PXD(7, 5,3,0. 10*,1S84. 0,1. 00*,P,T) XxptXPCUS2
NOLX LABS Text:PB2-K23 TLI#43432
A1 I3*7 A1.01B7
J V J L.
24(00' ' 25(00 ' 2*100 27(00 20(00
:U973263 #1-1024 Acqil7-OCT-1997 21(17(12 OC JSJ+ Voltage SIR 70S
9792 Fi2 ExptEPCU32
HOLE LABS TexttPB2-H23 TL1#43432
**^&>^
24(00' 25(00 2ff(00 27(00 ' ' 20(00
:U973263 #1-1024 Acqtl7-OCT-1997 21(17(12 OC XH- Voltage SIR 70S
7974 fi2 Sxp,EPCUS2
SOLB LABS TexttPB2-ia3 TLI#43432
27(02 i
LjMi^^^Mj^J^^^
24(00 25(00 2«(00 27(00 20(00
.1.3B4
.9.8E3
.6.5E3
.3.3B3
.O.OEO
Time
.2.1X4
-1.6E4
.1.2E4
J .0.253
.4.US3
O.OEO
Time
-.4.7X6
.3.8X6
'-.2.8X6
.1.9X6
'•.9.4X5
-.0.0X0
Time
3.0X6
'.2.4E6
.1.8E6
.1.2B6
le.iss
-S.2S6
.5.0X6
.3.7X6
.2.5X6
.1.2X6
.0.0X0
Time
-2.6X4
.2.1X4
.1.5X4
.1.0X4
.5.1X3
O.OEO
Time
-------
\PilfiU973263 #1-1034 Xcytl7-6&f-19S7 2lsl7tl2 OS Elf Voltage SIR 70S Jtoig«(3flfl
355.8546 Pt2 BSUB(256,30,-3.0) PKD ( 5,5, 3, 0.05%, 1552. 0,1. 00%,*, t) BxptEPCUS2
TRIANGLE LABS TfJCt t PB2-K23 TLI043432
10091
80.
SO.
40.
20.
12.77E4
A1.53B4 fl ,|| ' I
• fl 1 II II 1
.1.1S4
.8.6E3
.6.SB3
^ J JW.88K3 1 I Ml A1'!8E4 1 "'\6S3 61S3 \*-3S3
\lil *i 1 11 I 1 / \j( 1 II 1 IIIL n /111 A •*7-*^fl3ll 1 jJI "A it
v lj\M J\I\M^V^ 'vMw ]\^^^^
26tOO 27(00 ' 28(00 Tioa
Pil*tU973263 91-1024 JLGqii,7-OCT-1997 21: 17 1 12 QC EH- Voltaffu SIR 703 Sole»t353
357.8516 Pi2 BSUB(256r30,-3.0) PKD(5, 5,3,0. 05\, 1412. 0,1. 00\,P,T) BxptEPCUSS
TRIANQLB LABS Tfltt t PB2-H23 TLI043432
100k
80.
60.
40.
20.
Aiifs"
1
I A1.41E4
1 \L6 94B3^S4 A1-0a4 \A1.98B4 I jl A-, gos4 A1.S7B4 JL7.95B3 ^-35B4
/ CC^A7\A^^iA^^JvAA^/^^vLAAv^^
.3.3B4
-2.7B4
-2.0B4
'.1.3E4
.6.6S3
' 0. OBO
2ff(00 ' 27(00 ' 28(00 ' ' ' Tim
Pil»iU973263 01-1024 Jicqil7-OCT-1997 21(17(12 OC Elf VolCag* SIR 703 Solmmi296
367.8949 Pl2 B3UB(256,30,-3.0) PltD(5, 5, 3,0.05*, 1184. 0,1. 00\,P,T) BxptEPCOS2
TRIUKOiB LABS TfXt t PB2-M23 TLI043432
100*
80.
60.
40.
20.
0.
Jil 03B7
ft
/ IU.OSB*
y v/v
-3.1B6
'.2.5BS
-1.9E6
'.1.2B6
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O.OBO
26tOO 27(00 ' 28(00 ' ' ' Tia»
Pil»tU973263 01-1024 Acqtl7-OCT-1997 21(17(12 OC BJ+ Voltagm SIR 70S Nola»:401
369.8919 Pi2 B3UB(256,30,-3.0) PXD(S,5,3,0.05*,1604.0,1.00*,P,T) BXptBPCUS2
TRIANOLB LABS TfXt,PB2-H23 KI043432
100]
00.
60.
40.
20.
0
A7.14Bff
ft
1
/ iff. 75B5
/ vvv
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O.OSO
26tOO 27(00 28(00 ' ' ' Wn*
Pll»tU973263 01-1024 Acqill-OCT-1997 21(17(12 OC El* Voltage SIR 703
330.9792 Pi2 XxpiSPCUS2
TRIUiaLB LABS Tmjrt t PB2-IO3 9LX943432
ion
80.
60.
40.
20.
0.
25*30 26 1 14 26i27 26t47 27 09 27t26 37 so f.3S6
"/^\^r^S^yA/^^
.5. OBt
.3.7B6
.2.5B6
.1.2E6
O.OSO
26iOO ' " 27(00 "" 28(00 ' ^^ " Tin*
-------
Pil»:a973263 #1-404 Acg: 17-OCT-1997 21:17:12 OC BI> Voltage SIR 703 Kofs»:643
373.8208 P:3 BSOB(256,30,-3.0) PXD(7,S,3,0.10*,2S72.0,1.00\,P,T) ExptBPCUS2
TRIANGLE LABS T*xt:PB2-M23 m#43432
29:00 30:00 31:00
Pll»:0973263 91-404 Aetj: 17-OCT-1997 21:17:12 OC EI+ Voltage SIS 70S Holm*1667
375.8178 F:3 BSU3(256,30,-3.0) PXD(7,5,3,0.10*,2668.0,1.00*,P,T) Exp,BPCVS2
TRIANQLE UBS Text:PB2-M23 TLHH3432
29:00 30:00 31:00
Pll»,0973263 tl-404 Jkegi 17-OCT-1997 21:17:12 OC EH- Voltaff SIS 703 SOlam:1579
383.8639 P:3 B3UB(2S6,30,-3.0) PKD(7,5,3,0.101,6316.0,1.00*,?,T) ExpiEPCUS2
TRULNOLB ZJLS3 VfXt:PS2-M23 TLI*43432
32lOO
Tla»
33:00
loot
80L
601
40J.
20:
o:
3LB.17S6
A6.57B6
-2.9E6
'•J2.3B6
.1.BE6
.1.2E6
'•.5.9S5
0.0X0
29,00 30:00 31:00
Pll»tV973263 il-404 Acytl7-OCT-1997 21*17:12 OC EH- Voltage SIS 70S Hoimm:1044
385.8610 P:3 BSUB(256,30,-3.0) PKD(7,S,3,0.10\,4176.0,1.00*,P,T) Bxp:BPCUS2
TKUSOIJC LABS T*xt:PB2-H23 TLIH3432
32:00
Tia»
io a
80:
60:
40:
20:
JU.64B7
I
S7
A1.34X7
5.6X6
.4.4E6
.3.3B6
.2.2S6
0.020
00 30:00 31:00
PllftV973263 *1-404 Hag: 17-OCT-1997 21:17:12 OC BI+ Voltaym SIR 70S
392.9760 P:3 Exp>EPCUS2
TRIANGLE LABS ftaO:: PB2-H23 TLHH3432
1001
80:
60:
40:
20:
0.
32:00
Time
.3.4E6
-.2.7S6
'-.2.1X6
.1.4E6
.6.9X5
0.0X0
29:00 30:00
P11»:V973263 «1-404 Acq:17-OCT-1997 21:17:12 OC
445.7555 P:3 Exp,BPCU32
TSIAOOLS LABS Text,PB2-H23 TLH43432
30,36
30:15
31:00
Voltage SIS 70S
32100
Tlffl*
29,00
30:00
31:00
32:00
-------
'ile,09733S3 #1-40* Xcg:17-6a-1997 21*17*13 Og gT+ Voltage SIX 70S Soiae,i90
89.8156 Pi3 BSUB(2S6,30,-3.0) PXD(7,St3,0.10\,1960.0,1.00X.P,T) Bxp*BPCUS2
TRIAIKILS LABS TexttPB2-H23 TLItf43432
29*36 29*48 30'tOO 30*12 30*24 30i36 30*48 31': 00 31,12 31t24 31i36
rlle*U973263 01-404 Acg* 17-OCT-1997 111 17112 OC ET+ Voltage SIS 70S Solse:408
391.8127 Pi3 BSOB(256,30,-3.0) PXD(7,5,3,0.10*,1632.0,1.00*,P,T) ExpsEPCVS2
TRIANOLB LABS T*3CtiPB2-H23 TLX«43432
ion
80.
29',36 29*48 30*00 30*12 30*24 30*36 30*48 31*00
Plle*U973263 01-404 Actj:17-OCT-1997 21*17,12 OC BT+ Voltage SIR 70S Noiee:709
401.8558 F*3 BSOB(2S6,30.-3.0) PXD(7,S,3,0.10\,2836.0,1.00\,F,T) Exp:EPCUS2
TRIANOLS LABS Tmxt*PB2-H23 TLH43432
100ft A1.15B7 A1.19S7
80.
60.
40.
20.
31i24 31:36
29:36 29*48 30*00 30*12 30*24 30*36 30*48 31*00 31:12 31*24
Pll»:U973263 tl-404 Aeq* 17-OCT-1997 21*17*12 OC SI* Voltage SIR 70S Boia»:610
403.8529 P*3 B3UB(2S6,30,-3.0) PXD(7.5,3.0.10\,2440.0,1.00*,P,T) Exp*EPCUS2
TRIUKILS LABS T*JceiPB2-M23 TLH43432
IOOH A9.74S6 JH.OOE7
31*36
80.
60.
40.
20.
0.
A8.60SI
31,12 31*24
31*36
Tina
.4.2S6
.3.4E6
-2.SE6
.i.Tse
.0.525
O.OEO
Time
-3.SS6
.2.8S6
.2.1S6
.1.4B6
.7.0ES
O.OEO
29*36 29*48 30*00 30*12 30*24 30*36 30*48 31*00
Pil»,U973263 tl-404 Aey* 17-OCT-1997 21*17,12 OC EH- Voltage SIR 70S
392.9760 t*3 Bxp:BPCUS2
TRIANGLE LABS TextlPB2-M23 TLH43432
ao-^^f1^^^^^
rime
60.
40.
20.
0.
.2.7X6
'.2.1S6
.1.4E6
'.6.9S5
29*36 29*48 30*00 30,12 30*24
30*36 30*48
31*00
31*12 31*24
.0.050
31,36
Time
-------
Pll«:U973263 #1-596 Acq>17-OCT-1997 21tl7tl2 OC EH- Voltage SIR 70S Soia«t682
407.7818 F:4 BSUB1256, 30, -3.0) PXD(7,5,3,0.10*,2728.0,1.00*,P,T) Exp:EPCUS2
TRIANGLE LABS Tfxt:PB2-M23 TLI#43432
33'tOO 33(12 33:34 33:36 33s 48 34:00 34:12 34:24 34:36
Fllf:U973263 *l-596 Aaq>17-OCT-1997 21:17:12 OC ET+ Voltage SIS 70S Soia«t504
409.7789 P>4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,2016.0,1.00*,P,T) Exp:EPCU32
TRIANGLE LABS TfXt:FB2-M23 TU143432
33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24
Fil»:V973263 01-596 Acqi17-OCT-1997 21:17:12 OC SI* Voltage SIR 703 Solsa:178S
417.8253 Pi4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,7140.0,1.00*,P,T) SxptSPCUS2
TRIANQLB LASS TmxtIPB2-H23 TLIf43432
100* AS. 13X6
10(8
80J
601
40l
20.
A2.27S4
A1.28E4
A2.28S4
A2.20E4
34:36
80.
60l
40.
20.
A3.90E6
33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24
Fll»:U973263 §1-596 Acq: 17-OCT-1997 21:17:12 OC SI* Voltage SIR 70S Hoim*:3789
419.8220 P:4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*, 1S156.0,1.00\,P,T) Rrp:SPCUS2
TRIANOLS LABS TmxttPB2-H23 TLII43432
34:36
IOCS
SO:
SO:
40:
20.
A1.20S7
A9.44E6
33:00 33(12 33(24 33:36 33(48 34(00 34(12
Fll»:U973263 91-596 Acq: 17-OCT-1997 21(17(12 OC EH- Voltage SIR 70S
430.9729 Pt 4 Exp:BPCUS2
TRIAKOLE LABS TfxttPB2-M23 JXXf43432
10« 33,01 33tao 33(40 33/50
80:
60:
40:
20:
o:
34:24
34:24
34:36
33(00 33<17 33:24 33:36 33(40 34(00 34:12
Pll»:U973263 *1-S96 Acq: 17-OCT-1997 21il7:12 OC EH- Voltage SIR 70S
479.7165 Pi 4 Exp:EPCUS2
TRIAHOLS LABS Text:FB2-M23 TLH43432
33(21
33:16 I
34:24
34:36
100)
80:
60:
40:
20:
o:
34132
33(35
33129
34103
8.5B3
6.8E3
5.123
3.4S3
1.7S3
O.OEO
Tlmt
2. OSS
1.6E6
1.2E6
.7.9ES
.3.9S5
.0.050
Maw
.4.5B6
.3.6S6
2.7E6
.1.8S6
.9.0X5
0.050
Tim
S3:
34:14 3«r23i
34(43
2.0E6
1.6X6
1.2X6
,8.1X5
.4.0X5
.0.0X0
Tim*
.2.6X4
.2.1X4
.1.6X4
.1.0X4
.5.2X3
.0.0X0
33(00
33112
33124
33:3t
33(40
34(00
34(12
34(24
34:36
-------
'H0:US73253 91-536 Acqt 17-OCT-19S7 21,17:13 {7,5,3,0.10*,1308.0.1.00*,P,T) Bxp,EPCVS2
TRIANBLB LABS T«xt,PB2-M23 TLI943432
10M A1.78E4
O.OEO
'34\ 24 Tima
80.
60.
40.
20.
A1.84B4
O.OEO
33 1 12 33tl8 33,24 33,30 33,36 33:42 33i48 33:54 34:00 34t06
P11*,U973263 91-596 *aqtl7-OCT-1997 21,17,12 OC KL+ Voltaff* SIR 70S Noiga,1682
435.8169 Ptt B3UB(256,30,-3.0) PO>(7,5,3,0.10*,6728.0,1.00*,P,T) Sxp:SPCVS2
TRIUIQLB LABS T»Xt , PB2-H23 TLIf 43432
20A A9.57E6
so:
60.
40.
20.
34*12 34*18 34,24 Time
-3.5B6
'.2.8E6
-.2.1E6
.1.4S6
.7.OSS
33.12 33*18 33«24 33*30 33(3* 33<42 33*48 33*54 34*00 34tO*
,0973263 91-596 Aay: 17-OCT-1997 21:17:12 OC EH- Voltage SIR 70S Koieo,1341
437.8140 P:4 BSUB(256,30,-3.0) PXD(7,S,3,0.10X,5364.0,1.00*eP,T) Sxp:SPCUS2
TRUWQLE LABS Text, PB2-M23 TLI943432
100* A3.S1S6
ao:
60.
40.
20.
O.OEO
0
34:12 34:18 34:24 Time
-3.4E6
_2. 7E6
.2.0E6
-1.4E6
-6. ass
33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54 34:00
Pil»,0373263 91-596 Acq: 17-OCT-1997 21:17:13 OC ST+ Voltage SIR 70S
430.9729 P:4 Exp:SPCUS2
TRIAHOLS LABS Tmxt IPB2-K23 TLX943432
0.050
34-106 34:12 ' 34*18 ' 34(24 Tia»
ion
80.
60.
40.
20.
0.
33*a°33t24
33i33 33:40
33:50
34:06
33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54 34:00 34:06 34:12 34:18
.2.0BS
.1.636
.1.2X6
.8. IBS
-4.OSS
O.OEO
-------
'U»tU9732t3 ti-596 Acq:l7-OCT-199} 21:17:i2 OC SI* Voltag* SIR 70S Noise,
-------
Pil»tU973263 il-596 Acq,17-
-------
Peak Locate Examination:17-OCT-1997:21:15 File:U973263
Experiment:EPCUS2 Function:2 Reference:PFK
-------
File:U973263 #1-596 Acq:17-OCT-1997 21:17:12 GC EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:FB2-M23 TLItt43432 File Text : TRIANGLE LABORATORIES, INC.
1004 . 37:37
80 j
60
20J
35:21
38:04
36:00 37:00
File:U973263 #1-596 Acq:17-OCT-1997 21:17:12 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:FB2-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100* 35:44 36:26 ^ n
__ ,_ I A -JC.KO 37:20
80J , 35:33
60 j
40 j
20J
38:00
38:02
36:00 37:00
File:U973263 #1-596 Acq:17-OCT-1997 21:17:12 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:FB2-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36;26
80J
60 J
40 J
20J
38:00
.2.5E4
.2.0E4
.1.5E4
.9.9E3
.4.9E3
.O.OEO
Time
2.8E4
2.2E4
1.7E4
1.1E4
5.6E3
O.OEO
Time
36:00
37:00
38:00
.4.9E6
.3.9E6
.2.9E6
.1.9E6
.9.7E5
.O.OEO
-------
TLI Project: 43432
Client Sample: FB2-M23
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973680
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-6A-C
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/22/97
n/a
U973257
GG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
XF24087
X973676
n/a
n/a
n/a
2,3,7,8-TCDF
ND
0.01
OC Lteitta
13C12-2,3,7,8-TCDF
3.3
81.8
40%-130%
0.79
24:18 _
13C12-1,2,3,4-TCDD
0.82
23:07
Data Reviewer.
10/23/97
Page 1 of 1
CZNF.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:32.10/23/97
-------
Data Review By:
Initial
\ \ C
XI ^
...Date.,
Calculated Noise Area:
9.99
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/23/97
Listing of X973680B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. R«1.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
1
NL
WL
WL
WL
SN
WH
WH
WH
1
NL
SN
SN
WH
WH
WH
WH
WH
WH
0:00
20:52
24:34
24:40
Peak
0:00
22:20
22:47
23:03
24:18
24:35
25:44
26:42
26:46
Peak
0:00
20:52
22:49
23:07
23:24
23:53
24:44
24:56
24:59
25:09
25:25
25:33
25:51
0.
RO
0.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0.
0.
0.
0.
65
93
70
69
65-0.89
0.
2.
2.
1.
0.
0.
0.
0.
1.
54
85
62
09
79
26
54
76
19
65-0.89
2.
1.
0.
0.
0.
0.
5.
0.
3.
0.
0.
0.
0.
12
36
79
82
67
48
03
67
17
87
30
57
90
17.53
9.01
16.64 6.87
6.48
16.64
23.26
10.12
14.73
64.53
7,789.42 3,430.53
10.83
9.95
63.12
14.02
7,789.42
Above: TCDF / TCDD Follows -
0.800-1.112
0.000
0.859
9.77 1.011
1.015
0.959-1.041
0.000
0.919
0.938
0.949
4,358.89 1.000 13C12-2378-TCDF ISO
1.012
1.059
1.099
1.102
332-334
4 Peaks
8.30
6.99
5,739.59 2,541.14
6,840.77 3,089.24
15.31 6.14
53.88 23.44
5.26
4.68
10.02
2.90
4.11
7.33
21.05
12,649.55
0.912-1.088
0.000
0.915
3,198.45 1.000 13C12-2378-TCDD IS1
3,751.53 1.013 13C12-1234-TCDD RSI
9.17 1.026
49.27 1.047
1.084
1.093
1.095
1.102
1.114
1.120
1.133
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
Page No.
10/23/97
Listing of X973680B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description.
"Why- Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Tim* (mn:ss)
Rat.l -Ratio of H/H+2 Ions
OK -RO=Ratio Outside Limits
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
FiJ.e,X973680 tl-803 Acq,22-OCT-1997 14t44t32 GC EH- Voltage SIR AutoSpec Noia»,J464
303.9016 BSUB(256,30,-3.0) PKD(5, 3,1,0.10\, 13856.0,0.00\,F,F) ExpiXCONT_TT
Sample Text:FB2-H23 TLH43432 OJ.e Texts TRIANGLE LABS
20»00 ill 00 Mi 00 23'tOO 24(00 25iOO iff 100
Flle,X973680 tl-803 Acqi22-OCT-1997 14,44,32 GC EH- Voltage SIS AutoSpmc Hti±a«i5301
305.8987 BSOS(356,30,-3.0) PKD(S,3,1,0.101,21304.0,0.00\,r,F) ExptXCOHT_TT
Sample T»xttFB2-H23 TLH43432 Tile Tart. TSIAXGLB LABS
1004 A1.23X5
0.0X0
27100 Time
20100 21100 22100 23,00 24:00 25.00 26tOO
F±letX973680 fl-803 Acqt22-OCT-1997 14t44i32 GC EI+ Voltage SIR AutoSpec SoifetS059
315.9419 BSOB(256,30,-3.0) P1O>(5,3,1,0.101,20236.0,0.00\,r,F) ElptXCOKr_TT
Sample TexttFB2-H23 TLH43432 rile Textt TRIANGLE LABS
1004 A3.43X7
80.
60.
401
30.
27100
-B.OE6
.6.4E6
•-4.8S6
.3.2X6
'.1.6X6
20,00 21,00 22,00 23,00 24,00 25,00 26,00
rile,X973680 tl-803 Acqi22-OCT-1997 14,44,32 GC EH- Voltage SIR AutoSpec Noise,9385
317.9389 BSUB(256,30,-3.0) PKD(S,3,1,0.10\,37540.0,0.00\,r,r) ExpiXCOHT_TT
Sample T»xt,FB2-H23 TLH43432 rile Tazti TRIANGLE LABS
1004 A4.36E7
80.
60.
40.
20.
27100
0.0X0
Time
-1.0X7
'.8.2X6
.6.1X6
.4.1X6
'.2.0X6
20,00 21,00 22,00 23,00 24,00 25,00
rileiX973680 tl-803 Acq,22-OCT-1997 14,44,32 GC XII- Voltage SIR AutoSpec
375.8364 XxptXCOar_TS
Sample Texttn2-H23 TLH43432 rile Text, TRIANGLE LABS
100\19,41 21,34
26100
.0.0X0
27,00 rime
201 00
21100
22,00
23,00
24,00
25100
26100
27 tOO
-------
Fll*,X973680 fl-803 Aoq:23-OCT-1997 14:44:3? SC EI+ VoJLtMff* SIS AutoSp*a S6if*»16B2
313.8965 BSU3(2S6,30,-3.0) PXD(S,3,1,0.10\,6728.0,0.00\,T,T) ExptXCONT IT
Samplm Taxt.,TB2-M23 TLH43432 ril* Tkztt TRIANGLE LABS
100*
21t00 32tOO 23100 24,00 25,00
Fil* 1X973680 H-803 Acq:22-OCT-1997 14:44:32 SC EH- Voltaga SIS AutoSpac Noia*,2006
321.8936 BSUB(256,30,-3.0) fXD(5,3,1,0.10\,8024.0,O.QO\,T,r) SzpiXCO»r_TT
Stmpl* T*xt,n2-H23 TLH43432 ril* Tmrti TRIANGLE LABS
1001
26,00
21,00 22:00 23,00 24,00 25,00
Til*:X973680 H-803 Acq:22-OCT-1997 14:44,32 GC EI+ Voltagw SIX AutoSpoc Noil*:6271
327.8847 BSUB(256,30,-3.0) HD(5,3,l,0.10\,25084.0,0.00\rT,r) ExptXCONF_TT
Sample T*xt:TB2-M23 XLIf43432 r±lm Tart.- TRIANGLE LABS
100* AS.22X7
80.
eo:
40.
20:
26,00
21,00 22>00 23:00 24:00 25,00
rilmtX973680 41-803 Acq:22-OCT-1997 14:44:32 SC EI+ Voltag* SIS AutoSpfo Noll*:4964
331.9368 BSOB(256,30,-3.0) H3>(5t3,l,0.10\, 19856.0,0.00\,T,f) Exp:XCONT_TT
Stmpl* T»xttfB2-M23 TLH43432 Til* T*xt, TXIANSLE LABS
100* A3.09X7
26:00
so:
50:
40:
20:
A2.54E7
21,00 22,00 23:00 24,00 25,00
rll*,X9736aO H-803 Aoq:22-OCT-1997 14:44:32 SC XI + Voltmy* SIS AutoSpmc Nolf*:2344
333.9338 BSUB(256,30,-3.0) PfD(S,3,l,0.10\,9376.0,0.00\,F,T) Ejcp:XCONT_TT
Stmpl* T*zt:rB2-M23 TLH43432 ril* T*rt» TRIANGLE LABS
100* A3.75X7
26:00
80.
60.
40.
20.
A3.20X7
21100
22,00
23100
24:00
25:00
26100
-1.3X7
J..1X7
.7.9X6
.5.3X6
.2.6X6
.0.0X0
Tim*
-7.9X6
.6.4X6
.4.8X6
.3.2X6
.1.6X6
0.0X0
Tim*
.1.0X7
.8.0X6
.6.0X6
.4.0X6
'-2.0X6
0.0X0
Tim*
-------
Tilm
303.
Samp
1001
80:
60:
40:
20:
0
Tilm
315.
Samp
1001
eo:
60:
40:
20:
Tllo
319.
Samp
1001
80:
60:
40:
20:
0
Tilm
331.
Samp
1001
80:
60:
40:
20:
Tilm
292.
Samp
1004
00:
eo:
40:
20:
o-
Tilm
330.
Samp
1004
80:
60:
40:
20:
0:
1X973680 fl-803 Acq,22-OCT-1997 14*44*32 CC EH- Voltagm SIS AutoSpmc
9016 Exp,XCONT_TT
1m Tmxt,TB2-H23 TLIf43432 Tile Text* TSIAOGLX LABS
20,38 21,47
1 I 1 22,19 24,19 25,02
J^!^^
20,00 21,00 22*00 23*00 24*00 25*00 26,00 27,00
,X973680 fl-803 Acq:22-OCT-1997 14*44*32 GC EH- Voltagm SIS AutoSpmo
9419 XxpiXCONT_TT
1m Tmxt,TB2-M23 TLIf 43432 Tilm Texts XXIABGLX LABS
24*10
11
20*00 21*00 22*00 23*00 24*00 25*00 25100 27100
1X973680 #1-803 Aoq,22-OCT-1997 14*44*32 GC EH- Voltagm SIS AutoSpmo
8965 XxptXCONr TT
1m Tmxt,TB2-M23 TLIf 43432 Tilm Text* TSUOKLX LABS
24,21 35 41
21,07 It I 25(58
\Jk£^
20*00 21*00 22*00 23*00 24*00 25*00 25*00 27*00
,X973680 f 1-803 Acq,22-OCT-1997 14*44*32 GC EI+ Voltagm SIS AutoSpmc
9368 Xxp,XCOHr_TT
1m Tmxt,TB2-H23 TLIf 43432 Tilm Text* TMIABGLE LABS
23,07
T
111
20 lob 21*00 22 lob 23*00 24*00 25*00 iff 1 00 27lo0
,X973680 fl-803 Acq,22-OCT-1997 14*44*32 GC EH- Voltagm SIS AutoSpmo
9825 X3Cp,XCOHT_TT
1m Tmxt,TB2-M23 TLIf43432 Tilm Text* TXIARGLE LABS
20,13 20f49 21,30 M.I-732..4*,,. ,, 24,14 ^^^L?^ 35*42 25*152(y,4j
20 lob ' ' ' 21 lob ' ' 22*00 ' ' 23 lob ' ' ' 24*00 ' ' ' 25*00 ' ' ' 26*00 ' ' ' 27*00
1X973680 #1-803 Acq,22-OCT-1997 14*44*32 CC EH- Voltagm SIS AutoSpmo
9792 Exp,XCOlTT_TT
1m Tmxt,TB2-H23 TLH43432 Tilm Text* TRIAHGLX LABS
19$43., 2.0*15 20*47 21*41 22*10 33,41 23,35 24t20 25,0025,27 26,17
20*00 21*00 22*00 23lob 24lob 25100 25*00 27lob
_S.2r4
.7.4E4
.5.5X4
'.3 . 7X4
.1 . BE4
0.0X0
Timm
-8.0X6
.6.4X6
'-.4.8X6
13.2X6
.1.6X6
Timm
r.6.4E4
1.5.1X4
.3.8X4
'•o.oxo
Timm
-8.0X6
-.6.4X6
.4.8X6
.3.2X6
.1.6X6
Timm
-1.5X8
.1.2X8
.9.2X7
.6.2X7
.3.1X7
0.0X0
Tlmm
-1.9X8
.1.5X8
.1.2X8
.7.7X7
.3.9X7
0.0X0
-------
TLI Project: 43432
Client Sample: LAB BLANK M23
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973264
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-7A-CE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst*
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
'AnaTyt**^ '^4^8fe '*
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
U,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3.4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
,tatate^ : ° xV^^lr -
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
*< £%&.&&$:
ND
ND
ND
ND
ND
ND
0.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
*nte&%jfj$
ND
ND
ND
ND
ND
ND
ND
ND
*A* S'aiPC ^ %Kft%a^%4^l^^^
0.003
0.004
0.006
0.005
0.005
0.005
0.84 36:25 B_
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.004
0.004
0.004
^^^^;j;pim ^ ^^^^///^iSSIS^^J
0.003
0.004
0.005
0.005
0.003
0.003
0.003
0.004
Page 1 of2
X237JPSR rZOX LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
TLI Project: 43432
Client Sample: LAB BLANK M23
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U973264
Interr^ Standards ^%""-> ,^lf:Ai
I3C,2-2,3,7,8-TCDF
13C.2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-1.2,3,7,8-PeCDD
l3Cl2-l,2,3,6,7,8-HxCDF
l3Ci2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Surix>gate Standards (TyiJe^i Ar
"CU^SJ-S-TCDD
l3C,2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
^tw^^pawxisCfyiP^r^
13d2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards *%'V^| f
13Ci2-l,2,3.4-TCDD
13C.2-l,2,3,7,8,9-HxCDD
nfc jtng$^|
3.4
3.3
4.0
4.7
4.2
3.8
3.6
4.1
8.3
M» /*»*&• ' *'*>*?
IjU A»^5>> s ?%
3.8
3.9
3.7
3.9
3.7
. ** ^s^\^&
&*&$&*&
3.8
4.2
" '' ^^1
H»ittmy
85.0
82.3
101
118
105
95.7
90.0
102
104
|j|$* H^csoveiy
94.1
98.5
93.1
96.8
92.4
95.3
104
H^S?-:^
.;•":.•• OO l»ltll{ts
- , -^ %
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
*• "" ^l^*^1 t t^MtSf*J>
•> *u(l^ t^tf-HlmiiT'
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QC Limits
40%-130%
40%-130%
' *.* ^\\"'"
& ?'*&n*3$>
0.75
0.80
1.46
1.50
0.50
1.24
0.42
1.01
0.85
Vf ^ 8*P?&
1.44
0.50
124
0.42
^|l|tit^!
0.51
0.50
^i^iwhiy;;
0.79
1.22
; *w
21:31
22:27
26:16
27:28
30:13
30:58
33:01
33:53
36:25
x^%?1
22:28
27:04
30:07
30:53
34:14
£Sf&?
31:30
30:45
vMK
22:13
31:16
I§S*8^1
^
_B^^-«.
^«l_^
—
gFtag^^
—
gflagsjf
—
Data Reviewer
Page 2 of 2
10/21/97
X237.PSRy2.Oa LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:4210/21/97
-------
Initial^
Data Review By:
. .Date. .
alculated Noise Area:
1.20
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
10/21/97
Listing of U973264B.dbf
Matched OC Peaks / Ratio
/ Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
HH
0
NL
HL
SN
SN
SN
SN
SN
HH
HH
HH
HH
HH
HH
HH
1
NL
SN
SN
SN
SN
SN
0:00
17:38
18:55
20:15
20:19
20:52
20:59
21:21
21:34
22:06
22:22
23:02
23:42
24:02
Peaks
0:00
20:09
20:37
21:01
21:31
22:05
22:12
22:26
22:38
22:53
23:09
23:23
23:38
23:54
24:15
Peak
0:00
19:10
19:57
20:23
20:38
21:30
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
65-0.89
0.
1.
0.
0.
1.
0.
0.
0.
1.
0.
1.
1.
0.
4.
88
71
38
32
75
44
35
14
12
99
25
94
55
68
1
4
2
1
0
2
3
1
10
4
4
1
2
0
0
.47
.04
.28
.95
.78
.60
.95
.01
.67
.00
.73
.96
.99
.50
.00
65-0.89
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
2.
0.
2.
86
60
30
73
75
52
58
57
37
51
58
82
24
58
68
1
28
3
21
3,821
14
9
9
3
5
6
3
3
3
1
3,821
.71
.87
.65
.21
.99
.78
.45
.24
.13
.13
.32
.17
.08
.43
.15
.99
D *
65-0.89
0.
2.
2.
2.
1.
3.
96
96
34
48
28
48
1
0
1
1
1
1
.40
.85
.04
.29
.13
.96
1.642.76
0.813-1.106
0.000
0.820
0.879
0.941
0.944
0.970
0.975
0.992
1.002 2378-TCDF AN
1.027
1.040
1.070
1.101
1.117
0.954-1.046
0.000
0.936
0.958
0.977
2,179.23 1.000 13C12-2378-TCDF ISO
1.026
1.032
1.043
1.052
1.064
1.076
1.087
1.098
1.111
1.127
TCDD Follows
0.848-1.061
0.000
0.854
0.889
0.908
0.919
0.958
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
265
-------
Pag* No.
10/21/97
Listing of U973264B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Kame.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
DC
DC
DC
DC
SN
SN
SN
SN
0
22:00
22:30
23:14
23:25
Peaks
RO
RO
RO
RO
0
0
1
0
.48
.29
.04
.41
1
3
1
1
0
.24
.33
.19
.61
.00
0.
1.
1.
1.
980
002
035
043
0.911-1.089
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
20:42
22:28
22:46
23:05
23:15
23:26
23:27
23:38
23:54
24:01
24:07
24:15
Peak
0:00
20:55
21:29
21:50
22:13
22:27
22:38
22:52
23:20
23:27
23:53
23:57
24:11
Peaks
0:00
23:51
24:00
24:59
25:06
25:11
25:17
25:42
26:11
26:19
26:43
0.
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
2
2
0
6
.622
2
4
2
2
1
6
4
2
2
2
,622
.77
.98
.50 2,622.50
.22
.18
.15
.45
.96
.04
.06
.35
.20
.45
.50
65-0.89
1
1
1
0
0
0
0
0
0
0
0
0
0
.25
.19
.14
.86
.79 3
.80 2
.57
.94
.66
.52
.17
.35
.72
6
*!».«••_ .
32-1.78
0
0
2
1
1
1
0
0
3
1
0
.99
.95
.09
.17
.83
.26
.14
.22
.54
.66
.18
1
15
2
3
.236
.953
15
58
9
3
4
3
7
.43
.72
.85
.68
.15 1,428.45
.50 1,311.21
.33
.96 31.28
.52
.75
.53
.79
.05
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
922
001 37C1-TCDD SOR1
014
028
036
044
045
053
065
070
074
080
0.911-1.089
0.
0.
0.
0.
1,807.70 0.
1,642.29 1.
1.
33.31 1.
1.
1.
1.
1.
1.
000
932
957
973
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
008
019
039
045
064
067
077
.248.61
TCDD / P^CPP PoUows ™—
i
2
2
1
0
0
0
0
1
4
0
.15
.17
.01
.23
.61
.87
.81
.66
.56
.15
.18
0.906-1.077
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
908
914
951
956
959
963
978
997
002 12378-PeCDF AN
017
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
266
-------
Page No.
10/21/97
Listing of U973264B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-FeCDD
368-370
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
27:03
27:45
27:49
28:17
28:33
Peaks
0:00
25:17
25:51
26:16
26:37
27:04
27:29
27:36
28:09
28:40
Peaks
0:00
26:17
26:29
26:33
27:05
27:26
27:36
27:48
27:55
28:29
Peaks
0:00
25:42
25:53
26:07
26:15
26:38
27:28
27:37
27:55
28:05
28:17
28:23
28:34
Peaks
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
0.
0.
0.
1.
0.
71
93
94
49
19
2
0
1
2
0
0
.58
.63
.04
.59
.35
.00
32-1.78
0.
1.
1.
1.
0.
1.
0.
0.
2.
0.
97
55
38
46
85
44
75
93
02
46
1
55
18
3,564
27
3,407
7
11
15
0
.09
.90 33.98
.62
.87 2,117.73
.47 16.70
.15 2,013.27
.16
.01
.61
.90
1
1
1
1
1
.030 23478- PeCDF
.056
.059
.077
.087
AN
0.848-1.152
0
21.92 0
0
1,447.14 1
19.61 1
1,393.88 1
1
1
1
1
.000
.963
.984
.000 13C12-PeCDF 123
.013
.030 13C12-PeCDF 234
.046
.051
.072
.091
IS2
SOR2
7,055.39
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
32-1.78
1.
2.
0.
0.
1.
3.
0.
1.
1.
3.
10
94
63
53
89
15
73
21
88
10
rw i f^^isf i f m»w c~ w**w**«
1
3
0
0
2
0
1
1
2
1
0
.27
.93
.86
.79
.32
.66
.05
.88
.55
.96
.00
32-1.78
1.
4.
2.
2.
1.
1.
1.
1.
0.
1.
0.
1.
1.
09
02
54
08
72
73
50
58
22
46
61
18
18
1
1
0
0
4
2
2,292
227
1
5
2
3
4
2.520
.23
.22
.61
.99
.41
.27
.92 1,374.35
.91 139.61
.09
.22
.93
.37
.03
.83
0.921-1.025
0
0
0
0
0
0
1
1
1
1
.000
.957
.964
.967
.986
.999 12378-PeCDD
.005
.012
.016
.037
AN
0.855-1.145
0
0
0
0
0
0
918.57 1
88.30 1
1
1
1
1
1
.000
.936
.942
.951
.956
.970
.000 13C12-PeCDD 123
.005
.016
.022
.030
.033
.040
IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
. Printed: 20:43 10/21/97
-------
Page No.
10/21/97
Listing of 0973264B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT compound.Name.. ID.. Flags.
HxCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SK
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
0:00
29:01
29:13
30:08
30:13
30:24
30:29
30:45
30:59
31:05
31:11
31:16
31:19
31:26
31:38
31:55
Peaks
0:00
29:14
30:07
30:13
30:45
30:54
30:56
31:10
31:15
31:18
31:30
Peaks
0:00
29:38
29:43
29:50
29:54
30:13
30:40
30:45
30:56
31:16
31:29
Peaks
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
05-1.43
1
2
0
2
0
0
1
0
0
0
0
2
0
1
0
1
.08
.76
.85
.57
.69
.94
.64
.82
.69
.57
.73
.19
.83
.32
.67
.40
2
0
1
2
1
1
0
4
1
0
0
1
0
1
1
1
0
.25
.47
.61
.44
.82
.10
.49
.25
.34
.36
.52
.19
.89
.30
.23
.25
.00
43-0.59
0
0
0
0
0
0
0
1
0
1
0
.41
.67
.50
.50
.50
.28
.26
.02
.83
.07
.51
15
17
2,848
3,141
2,931
10
4
5
3
4
2,529
.46
.32
.05 952.23
.70 1,052.43
.27 974.64
.75
.80
.39
.44
.88
.35 852.20
0.958-1.051
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
.000
.960
.967
.997 123478-HXCDP
.000 123678-HxCDP
.006
.009
.018 234678-HxCDF
.025
.029
.032
.035
.036
.040
.047
.056
AN
AN
AN
0.868-1.132
0
0
1,895.82 0
2,089.27 1
1,956.63 1
1
1
1
1
1
1,677.15 1
.000
.967
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.018 13C12-HXCDF 234
.023
.024
.031
.034
.036
.042 13C12-HXCDF 789
SOR3
IS4
ALT2
ALT1
11,450.37
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
05-1.43
1
0
0
0
2
0
0
1
1
0
1
.20
.89
.71
.88
.25
.79
.64
.98
.39
.33
.04
RAW W / CWMrW *i W**WW» — ~
1
1
0
0
0
4
2
2
1
0
2
0
.74
.03
.54
.81
.36
.91
.35
.91
.96
.96
.84
.00
0.952-1.015
0
0
0
0
0
0
0
0
0
1
1
.000
.957
.960
.963
.966
.976
.990
.993
.999 123478-HxCDD
.010 123789-HxCDD
.017
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
2H8
-------
Pag* No.
10/21/97
Listing of U973264B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
3
NL
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
SN
2
NL
SN
SN
SN
WH
WH
0
NL
SN
SN
SN
SN
1
0:00
30:20
30:53
30:58
31:06
31:16
31:25
31:30
31:48
Peaks
0:00
32:59
33:39
34:01
34:09
34:31
34:36
Peaks
0:00
33:01
33:11
33:39
33:53
34:14
Peaks
0:00
33:17
33:26
33:53
34:11
34:14
Peaks
0:00
33:17
33:53
34:04
34:21
34:28
Peak
1.
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
0.
RO
RO
RO
RO
0.
RO
RO
RO
RO
05-1.43
0
1
1
1
1
1
3
9
2
.96
.15
.24
.24
.42
.22
.12
.68
.14
88-1.20
1
5
1
0
3
1
1
.47
.24
.35
.95
.30
.32
.06
2
13
2,172
2,502
17
2,717
5
5
6
7,392
.31
.68
.90
.01
.48
.47
.04
.51
.54
.38
UwfTm / u_.
fGv^UU J nf
i
3
2
4
2
2
3
0
.73
.18
.98
.15
.00
.71
.83
.00
37-0.51
0
0
0
0
0
0
.35
.42
.44
.58
.43
.42
*!•..»». .
6
2,331
27
13
4
1,903
4,234
U«. *•*•*'
88-1.20
0
0
5
1
3
1
.90
.79
.15
.44
.75
.09
1
4
0
3
1
5
0
.45
.46
.17
.55
.15
.15
.61
/ut*
np
.52
.18
.55
.96
.08
.74
.00
88-1.20
1
0
1
0
1
3
.11
.73
.01
.39
.41
.64
6
9
2,548
17
7
5
2,548
.45
.38
.37
.30
.55
.04
.37
0.968-1.032
0.
0.
1.202.44 970.46 0.
1,385.89 1.116.12 1.
1.
1,491.50 1,225.97 1.
1.
1.
1.
000
980
997 13C12-HXCDD 478
000 13C12-HXCDD 678
004
010 13C12-HXCDD 789
015
017
027
SUR4
IS5
RS2
0.996-1.043
0.
0.
1.
1.
1.
1.
1.
000
999
019
030
034
045
048
0.939-1.121
0.
690.68 1.640.78 1.
1.
1.
1.
566.96 1,336.19 1.
f*nn W/O 1 nt>>a
000
000 13C12-HpCDP 678
005
019
026
037 13C12-HpCDP 789
IS6
SDR5
0.977-1.005
0.
0.
0.
1.
1.
1.
000
982
987
000 1234678-HpCDD
009
010
AN
0.971-1.029
0.
0.
1,283.11 1,265.26 1.
1.
1.
1.
000
982
000 13C12-HpCDD 678
005
014
017
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page No.
10/21/97
Listing of U973264B.dbf
Hatched OC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
OCDF
442-444
442-444
OCDD
458-460
MK
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
1
0:00
32:39
32:48
33:30
33:38
34:14
34:37
34:47
35:02
36:02
36:17
39:07
39:14
39:26
39:32
39:40
Peaks
0:00
36:17
36:25
36:45
Peak
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
76-1.02
1.
0.
1.
1.
4.
0.
1.
5.
1.
0.
3.
3.
0.
0.
1.
0.
14
79
31
59
25
73
13
48
14
98
78
31
84
64
25
20
76-1.02
0.
0.
0.
0.
91
44
84
39
Above: HpCDD / Octa-CDD and CDF Follows
2.66
2.94
1.93
1.51
0.45
3.06
1.68
0.91
2.21
3.62
1.12
0.96
4.48
1.97
1.74
1.15
0.00
1.97
2.72
7.07
1.17
7.07
0.390-1.110
0.000
0.897
0.901
0.920
0.924
0.940
0.951
0.955
0.962
0.989
0.996
.074
.077
.083
.086
3.22
1.089
0.890-1.110
0.000
0.996
3.85 1.000 OCDD
1.009
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.15 1.74
36:25 0.85 4,321.34
DC WH 36:37 RO 0.58 25.76
DC WH 36:54 RO 0.27 6.56
470-472 1 Peak 4.321.34
0.995-1.005
0.000
1,988.45 2,332.89 1.000 13C12-OCDD
1.005
1.013
IS8
Column Description 'Why* Cod* Description QC Log D«»c.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO»Ratio Outside Limits
Rel. RT-Relative Retention Time
*«* End of Report ***
WL-Below Retention Time Window
WH-Abovo Retention Time Window
SN-Below Signal to Noise Level
-------
P1101U973264 #1-1024 Acqi 17-OCT-1997 22(01(31 0C *1> Voltage SIS 70S Noim»t347
303.9016 Pi2 BSOB(256,30,-3.0) SXD(9,5.3,0.10\,1388.0,1.00\,P,T) ExpiBPCUS2
TSIASOLE LABS VlXtiLAB BLANK M23 TLH43432
10091 A6.;
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Pll*tff973264 91-1024 Acqtl7-OCT-1997 22(02(31 OC EH- Voltag* SIS 70S Bolm»i388
305.8987 P>2 BSOB(256,30,-3.0) PXD(9,5,3,0.10*,1552.0,1.00*,P,T) XxptSPCUS2
TRIANOLE LABS TtOtttLAB BLANK JC23 TLI*43432
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Pil»iU973264 01-1024 Aaqt 17-OCT-1997 22(02(31 OC *X+ Voltmgu SIS 70S Nairnft397
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330.9792 Pl2 fXp,SPCU32
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-------
PilfiU973264 #1-1024 Acgt 17-OCT-1997 22(01(31 OC XI* Voltafft SIS 70S No±t»l382
319.8965 Pt2 BSUB (256, 30, -3.0) PKD(7,5,3,0.10*,1528.0,1.00*,P,T) XxpiXPCUS2
TRIASOLX LABS Tact t LAB BLANK M23 TLIt43432
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IU973264 tl-1024 Acytl7-OCT-1997 22(01(31 OC SI+ Voltaff* SIR 70S Nolm»t393
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tOJLX LABS Tact t LAB BLANK M23 TLIt43432
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331.9368 Pi2 BSUB (256, 30, -3.0) PKD(7, 5, 3,0. 101,2028. 0,1. 00\,P,T) XxpiXPCUS2
TRIASOLX LABS Tact: LAB BLANK JC23 TLIt43432
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-------
Pil»tU973264 #1-1024 Aeq,17-669-1997 21,01,31 X BT» Volfcag* SIR 703 Noise:3B5
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367.8949 Pt2 BSUB(256,30,-3.0) PKD(5,S,3,O.OS*,1500.0,1.00*,P,T) ExptSPCU32
TRIANOLX LABS TfXtiLAB BLANK M23 TLIf43432
100* 11.37*7
80.
60.
40.
20.
.40S6
.4. OSS
.3.2S6
'.2.4S6
".1.6X6
.0.125
.0.020
26,00 27*00 20*00
Pll»tU973264 tl-1024 Aeq*17-OCT-1997 22*01*31 OS 21* Voltage SIR 70S Nols»i343
369.8919 Pi2 BSUB(256.30,-3.0) PKD(5,5,3,0.05*,1372.0,1.00*,P,T) XxpiXPCVS2
TRIANOLE LABS TextiLAB BLANK H23 TLH43432
100H AS.J.9B6
80.
60.
40.
20.
0.
18.0325
.A. -
.2.7X6
'.2.1X6
r.1.6X6
.1.125
.5.425
10.020
26tOO 27tOO
Pil»tU973264 91-1024 Aoqt 17-OCT-1997 22t01l31 OC XX* Voltafff SIR 70S
330.9792 Pi2 SxpiSPCU32
TRIANOLX LABS TiJCtlLAB BLANK M23 TU*43432
28100
Tlmu
iocs
so:
so.
to:
20:
o:
> ™ti? 2S,*3 3S>" 36t22 ",11 27t24 37,53 ^0.11 30,30
^My-as^^
2SiOO
27100
28(00
.3.9X6
.3.1X6
.2.3X6
'.1.6X6
.7.025
.0.020
Mm
-------
P110IU973264 #1-105 Acg: 17-OCT-1997 32:01t31 OC SI* Voltag* SIS 703 Soimtt586
373.8208 Pt3 BSUB1256,30,-3.0) tXD(7,5,3,0.10*,2344.0,1.0a*,P,T) Exp:SPCUS2
TRIANBLE LABS TiXCtLAB BLANK K23 TLI143432
29100 30tOO 31i00
Fll»:U973264 91-405 Hegi 17-OCV-1997 32:01:31 OC XI* Voltag* SIR 703 Noil*1541
375.8178 Pt3 B3OB(256,30,-3.0) PXD(7,5,3,0.10*,2164.0,1.00*,PrT) XxptXPCUS2
TRIANOLX LABS TtocttLAB BLANK K23 TLZI43432
100* A2. 6X4
29 i 00 30:00 31(00
Pil»tU973264 §1-405 Aegtl7-OCT-1997 22t01s31 OC XI* Voltmyt SIR 70S Holme: 2 609
383.8639 Pt3 BSUB(256,30,-3.0) PXD(7,5.3,0.10*,10436.0,1.00*,F,T) XxptSPCUS2
TRXJUOOLX LABS TfXtiLAB BLANK H23 TLIf 43432
lOOt
80.
60:
to:
20.
A2.80X4
A2.35X4
A8.91S3
.1.4S4
-1.1X4
"'.8.5X3
.5. 7S3
-2.8E3
0.0X0
32100
32100
IOCS
80:
60:
40:
20:
o:
A9.7SSS
A8.S2S6
Tim*
.3.6X6
.2.9X6
.2.2X6
.1.4X6
.7.2X5
0.0X0
29tOO 30i00 31tOO
Pll»tU973264 tl-405 JLcgt 17-OCT-1997 22:01:31 OC KH- VolCffft SIR 70S So±*»:6290
385.8610 Pi3 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,25160.0,1.0O*,r,T) X*piXPCOS2
TRIANOLX LABS TmxttLAB BLANK H23 TLM43432
100H A2.09X7 U..96X7
32100
80:
60:
40:
20:
A1.6BS7
29tOO 30(00 31(00
P110:U973264 tl-405 Acy: 17-OCT-1997 22(01(31 OC SI* Voltmgf SIR 70S
392.9760 P:3 SxptSPCUSS
TRIAHOLS LABS TfxttLAB BLANK H23 TLI043432
o°f'ia
32100
ao:
60:
40:
20:
o:
29:3729:48
lOtt
1:14
31,47
7.SS6
6.0X6
4.5X6
3.0X6
1.5X6
0.0X0
Tlm«
2.3X6
.1.8X6
1.4X6
.9.2X5
.4.6X5
.0.0X0
29:00 30:00 31:00
Pll«lU973264 tl-405 Aoyt 17-OCT-1997 22:01:31 OC XI* Voltmgm SIR 70S
445.7555 P:3 XxptXPCUS2
TRIANQLX LABS TmxCtLAB BLANK H23 TLH43432
lOOtt
32:00
80.
30:50
29105
29141
61
40.
20.
0.
29 tOO
29125
29,S3
30>15
30»0«
30«37
31»17
30tOO
103
31100
lit 33
31:58
32100
.2.7X4
.2.2X4
.1.6X4
.1.1X4
.5. 4X3
.0.0X0
ria»
-------
fJ.lmtV973at4 91-405 Acq:17-3 BSUB(256,30, -3.0) PXD(7,5,3,0.10*,1892.0,1.00*,P,T) XxptBPCUS2
TRIANGLE LABS T«UCt I LAB BLANK H23 TLI943432
100H
29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36
Pll»:U973264 91-405 Aoqt 17-OCT-1997 22:01:31 OC JET* Voltmfff SIR 703 Noi**:394
391.8127 fl3 B3UB(256,30,-3.0) PXD(7,5,3,0.10\,1576.0,1.00*,P,T) Bxp:XPCUS2
TRIANOLS LASS TfXtiULB BLANK 1123 TLH43432
A2.02X4
29:36 29:48 30:00 30:12 30:24 30t36 30:48 31:00 31:12 31:24
Pllm:U973264 91-405 Jicqi 17-OCT-1997 22:01:31 OC MX* Voltmfff SIR 703 No±*»:641
401.8558 fi3 B3UB(256,30,-3.0) PKD(7,5,3,0.101.2564.0,1.00X,P,T) ExptSPCUS2
TRUUfOLX LABS TutlLAB BLANK H23 TLH43432
100H ., ,„„ JL1.49S7
80.
60.
40.
20.
A1.51S4
31:36
80.
60.
40.
20:
A1.39B7
29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24
P±1»:U973264 91-405 Acq:17-OCT-1997 22:01:31 OC JX+ Voltmgm SIR 703 Soim»t669
403.8529 ft3 BSUB(256, 30, -3. 0) PKD(7,5,3,0.10\,2676.0,1.00*,P,T) Sxp:SPCU32
TRIANQLX UUB3 TfXttlAB BLANK X23 TLX943432
100H A1.23E7
31:36
80.
60.
40.
20.
0.
A1.12S7
29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00
Pll»:U973264 91-405 Acq: 17-OCT-1997 22:01:31 OC U* Volt*g» SIR 70S
392.9760 P:3 fxp:SPCVS2
TRIAKOLX IAB3 Text:LAB BLANK H23 TLX943432
31112
31:24
31:36
.1.3X4
.1.124
.7.9X3
.5.3X3
.2.6X3
0.0X0
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.3.2X6
.2.1X6
.1.1X6
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29,36
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30:12
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.2.3X6
'.1.8X6
'.1.4X6
.9.2X5
.4.6X5
0.0X0
31:36
Tim*
-------
Pil»*U973264 #1-596 Acy* 17-OCT-1997 22t01i31 QC Eli' Voltag* SIX 70S Koim»:623
407.7019 Pt4 BSUB(2S6,30,-3.0) PO>(7,5,3,0.10*,2492.0,1.00\,P,T) Xxp*XtOJS2
TRIAHOLB LABS Text * LAB BLANK M23 tLX*43432
100H M.18X4
33'tOO 33*12 33t24 33t36 33t48 34tOO 34il2 34t24
P110IU973264 91-596 *c
-------
SileiU9732S4 #1-596 Acqs 17-OCT-1S97 22(0.1(31 QC BI+ voltage SIX 70S NOiaeut
423.7766 Pi4 BSUB(256,30,-3.0) PKD(7,5.3,0.10*,1444.0,1.00\,P,T) BxptEPCUtt
TRIANGLE LABS Text tLAB BLANK H23 TLIH43432
IOOH
33:12 33(10 33(24 33*30 33't36 33(42 33*48 33(54 34.00 34 i Off
Fll»tU973264 91-596 Acqt 17-OCT-1997 22(01(31 QC XT* Voltage SIR 70S Noimet401
425.7737 Pi4 B3UB(256,30,-3.0) PKD(7,5,3,0.10*,1604.0,1.00X,P,T) XxptXPCUS2
TRIANQLX LABS Text,LAB BLANK H23 TLI943432
100H A3.69X4
33(12 33(10 ' 33(24 33(30 33(3tf 33(42 33(40 33(54 34(00
FlletU973264 91-596 Aagi17-OCT-1997 22(01(31 OC XT* Voltage SIR 70S Noieeil694
435.8169 Pi4 BSOB(256,30,-3.0) PKD(7,5,3,0.10*,6776.0,1.00*,P,T) XxptXPCU32
LABS Text:LAB BLANK H23 TLI943432
41.20X7
0X4 ,.1.3X4
-1.0X4
.7.5X3
.5.2X3
.2.6X3
34(12 34(10 34(24 Time
00:
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40.
20.
O.OEO
34(12 ' 34(10 ' 34(24 Tim*
-4.5S6
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.9.OSS
.O.OEO
33(12 33(10 33(24 33(30 33»3tf 33(42 33(40 33(54 34(00
Pll»tU973264 tl-596 Aaqil7-OCT-1997 22(01(31 OC EH- Voltmgm SIR 70S Nolf»ilS28
437.8140 Pi4 BSDB(256,30,-3.0) PXD(7,5,3,0.10*,6112.0,1.00*,P,T) ExptEPCtTS2
TRXANOLX LABS Text I LAB BLANK H23 TLIf 43432
100H Al.2.7X7
00.
60.
40.
20J
0.
34(12 34(10 34(24 Time
-4.5S6
.3.6X6
,.2.7*6
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.8.9X5
33(12 33(10 33(24 33(30 33(3* 33(42 33(40 33(54 34(00 ' 34(6*
Pil»tU973264 91-596 Actjtl7-OCT-1997 22(01(31 OC JET* Voltuye SIR 70S ;'
430.9729 Pi4 E*ptSPCUS2
TRIANOLX LABS TexttLAB BLANK JQ3 T1J*43432
0.0X0
IOCS
801
eo:
40.
20.
0.
33151
34103
34(12 34(10 34(24 Time
.1.4X6
.1.1X6
-0.1X5
_5.4X5
.2.7X5
0.0X0
33(12 33(10 33(24 33(30 33»3tf 33f42 33(40 33(54 34(00 34.Off 34.13 ' 34(10 ' 34(24 Tin*
-------
Fil»:U973264 tl-596 Acqil7-OCT-1997 22t01t31 QC EH- VoJtajr* SIR 70S Solf»t804
441.7428 Pit BSOB(256,30,-3.0) PKD(7,5,3, 0.10X,3216.0,1.00*,F,T) Exp:EPCVS2
TXXAHOLS LABS TexttLAB BLANK K23 VLIt43432
33:00 34:00 35:00 36'tOO 37:00 38,00
P11»:U973264 tl-596 Aagil7-OCT-1997 22:01:31 OC KC+ Voltaff* SIS 70S Sol*ft705
443.7399 P:4 BSUB(256,30,-3.0) fXD(7f 5,3,0.10\,2820.0,1.00\,P,T) Exp:EPCU32
TRUUtOLS LABS TUXttL&B BLANK H23 TLH43432
100*
39:00
-.0.0*0
Via*
33iOO 34tOO 35iOO 36:00 37:00 38:00
Pll»:U973264 tl-596 Acqil7-OCT-1997 22:01:31 OC Kf Voltmffu SIX 70S
430.9729 Pi4 *xpi*PCUS2
TSUUKIL* LABS TfXtiLAB BLANK H23 TLI143432
39,00
33:00 34:00 35:00 36:00 37:00 38:00
Pll»:U973264 tl-596 Acq:17-OCT-1997 22:01:31 OC JET* Voltaga SIR 70S
513.6775 Ft4 XxptXPCVS2
TRIAOOL* LABS TfXttLAB BLANK M23 TLHH3432
39:00
33100
34100
35:00
36:00
37:00
38100
39100
-------
AS
361 IB 36*24 36*30 36*36 36*42 36*48
Pll»*a973264 il-596 Aaq*17-OCT-1997 22t01t31 OC XH- Voltfgt SIR 703 Holm»:513
459.7348 P*4 B3UB(256,30,-3.O} PgD(7,5,3,0.lO*,2052.0,1.00X,P,T) SxptBPCUSS
TRIANOLS LAJUT TfXttLAB BLUf H23 TLHf43432
loan
80.
60.
40.
20.
36tl8 36t24 36i30 36t36 36t42 3Si48
Pll»iU973264 tl-596 JLcqi 17-CCT-1997 22t01t31 OC JET* Voltagu 3IR 703 Nolm»tS28
469.7779 Pl4 BSVB(256,30,-3.0) PXD(7,5,3,0.10\,2112.0,1.00\,P,T) gxptKPCUS2
TRUUX3LX LABS TfXttlAB BLUf U23 TLX143432
100H A1.99X7
91-596 Acqt 17-tiCf-lHi>'7 22*01*31 OC SH- VOJitag* SIS 70S NOlt«t469
457.7377 Pit BSUB(256,30,-3.0) PXD(7,5,3,0,10*,1876.0,1.00\,P,r) Exp:EPCOS2
TRIAKOLS LABS Tact:LAB BLAOC K23 TLI*43432
IOOH A4.31B4
80.
60.
40.
30.
A1.42S4
36110 36t24 36t30 36:36 36:42 -36148
PilttU973264 tl-596 Acqi 17-OCT-1997 22:01:31 OC SX+ Voltmgt SIS 70S Soim»t459
471.7750 Pl4 B3UB(2S6,30,-3.0) PXD(7,5e3f0.10*,1836.0r1.00*,P,T) SxpigPCUS2
TSUUIOLM LJLB3 TfXttLAB BUHT JQ3 TLII43432
100H 12.3.3X7
36:18 36:24 36:30 36:36 36:42
Pllu:U973264 tl-596 JLcqt 17-CCT-1997 22:01:31 OC SH- Voltagm SIX 703
430.9729 Pt4 Bxp:BPCUS2
LABS Text tLAB BLAMf M23 TLX*43432
36t42
36:54
A7.33S3
36:54
36:54
80.
60.
40.
20.
0.
36:25
36*32
36*47
36*50
-1.4E4
.1.2S4
'.8. 753
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O.OSO
Tlmm
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36*18
36*24
36*30
36*36
36*42
0.0X0
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7.5B6
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Vim*
.1.4X6
.1.1X6
.8.1X5
.5.4X5
.2.7X5
.0.0X0
Tim*
-------
Peak Locate Examination:17-OCT-1997:21:59 File:U973264
-------
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36;25
80 J
60 J
40 J
20J
_5.5E3
7E4
2E4
6E4
35124 35I36
36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EH- Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
36:26
100%
80 J
60 j
40 J
20J
3723
35-30
54
OEO
Time
7E4
2E4
6E4
_5.4E3
35I24 35136 35148 36166
36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
OEO
Time
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
36:25
A
l{
35l24 35\36 35\48 36166 36li2 36124 3el36 36\48 37166 37li2 37l24 37136 37148 38166
6.6E6
.5.3E6
_3.9E6
_2.6E6
L1.3E6
:O.OEO
Time
-------
File;U973264 #1-596 Acq;17-OCT-1997 22:01:31 GC El+ Voltage SIR 703
457.7377 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A3.22E4
60J
40J
20J
35:24 35:36 35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% A3.85E4
80.:
60 J
40 j
20J
2 . 7E4
L2.2E4
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L1.1E4
_5.5E3
O.OEO
Time
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L2.2E4
Ll.6E4
L1.1E4
L5.4E3
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35:24 35:36 35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100% 36:25 6.6E6
80J A L5.3E6
60J I L3.9E6
40J I 1 L2.6E6
20J / I L1.3E6
35:24 35:36 35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36
37:48 38:00
LO.OEO
Time
00
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491
-------
3ate: 10/18/97
TRIANGLE LABORATORIES, INC.
Continuing Calibration Cor X973633
Analysis Date : 10/18/97
Operator : WK
Init Calibration.: XF24087
ICal Date : 04/08/97
Analysis Time : 10:55
Method : C2NF
Instrument..: X
Std.Cone : 5.00
GC Column...: DB-225
Analyte Summary
Name
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
RF Ratio
RT
ICal Delta
RT Rel. RT RF RF %D
1&2 Lo/High
1.079 0.77 19:36 24:34 1.0007 0.967 0.112 11.6%
27:18
1.079 0.77 0.967 0.112 11.6%
1.265 0.75 20:25 23:01 1.0000 1.095 0.170 15.5%
26:21
1.265 0.75 1.095 0.170 15.5%
Other Standard Sumnary
Name RF Ratio
1&2
37C1-TCDD 1.062
ICal Delta
RT RT Ral. RT RF RF %D
Lo/High
21:01 23:02 1.0007 1.018 0.044 4.3%
25:01
Internal Standard Sumnary
Name RF Ratio
1&2
13C12-2378-TCDF 1.495 0.80
13C12-2378-TCDD 1.011 0.79
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
23:33 24:33 1.0000 1.392 0.103 7.4%
25:33
21:01 23:01 1.0000 1.105 -0.094 -8.5%
25:01
Recovery Standard Summary
Name RF Ratio
1&2
13C12-1234-TCDD 1.000 0.81
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
23:19 1.0130 1.000 0.000 0.0%
Page
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:50 10/18/97
-------
Dace: 10/22/97
TRIANGLE LABORATORIES. INC.
Continuing Calibration for X973676
Analysis Date : 10/22/97
Operator : GG
Init Calibration.: XF24087
ICal Date : 04/08/97
Analysis Time....: 11:06
Analyte Summary
Name
2378-TCDP
TOTAL TCDF
2378-TCDD
TOTAL TCDD
RF Ratio
RT
Method : C2NF
Instrument.. : X
Std.Conc : 5.00
GC Column...: DB-225
ICal Delta
RT Rel. RT RF RF %D
1&2 Lo/High
1.002 0.78 19:26 24:19 1.0014 0.967 0.035 3.6%
27:00
1.002 0.78 0.967 0.035 3.6%
1.038 0.69 20:14 22:49 1.0000 1.095 -0.057 -5.2%
26:05
1.038 0.69 1.095 -0.057 -5.2%
Other Standard Summary
Name RF Ratio
1&2
37C1-TCDD 1.001
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
20:49 22:49 1.0000 1.018 -0.017 -1.7%
24:49
Internal Standard Sumnary
Name RF Ratio
1&2
13C12-2378-TCDF 1.228 0.77
13C12-2378-TCDD 0.975 0.78
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
23:17 24:17 1.0000 1.392 -0.164 -11.8%
25:17
20:49 22:49 1.0000 1.105 -0.130 -11.8%
24:49
Recovery Standard Summary
Name RF Ratio
1&2
13C12-1234-TCDD 1.000 0.79
ICal Delta
RT RT Rel. RT RF RF %O
Lo/High
23:06 1.0124 1.000 0.000 0.0%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:58 10/22/97
-------
Date: 10/17/97
TRIAKSLE LABORATORIES OF RTF, INC.
Continuing Calibration for U973252
Init Calibration.
ICal Date
Analyte Summary
Name
• GG
Tn at rumen t -
: UF59167
• 09/17/9?
RF
Std.Conc
. : O
ICal
Ratio
1&2
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378 -PeCDD
TOTAL PeCDD
123478-HXCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HXCDD
123678-HxCDD
0.000
0.000
0.000
0.000
0.000
0.000
1.159
1.159
1.022
1.022
1.206
1.267
1.237
1.390
1.390
1.083
1.399
1.070
1.037
1.147
0.721
0.839
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
74
74
67
67
53
51
52
61
61
23
25
24
24
RT
Lo/High
1:37
15:37
2:32
16:32
8:37
16:37
9:32
17:32
12:37
19:37
14:32
20:32
17:35
23:55
19:06
23:55
23:51
28:21
25:21
28:13
28:58
31:47
RT Rel. RT
RF
2
2
.585
.303
0.892
21:38 1.0008
22:32 1.0000
26:20 1.0006
27:08 1.0310
27:31 1.0000
30:10 0.9972
30:16 1.0006
30:48 1.0182
31:32 1.0424
1.24
1.
1.
26
25
29:31
31:27
Page
30:56 0.9978
31:01 1.0005
1
1
0
0
1
1
1
1
1
1
1
1
1
1
1
1
.770
.250
.000
.077
.077
.210
.210
.109
.138
.124
.382
.382
.212
.541
.267
1.207
1
0
1
.307
.857
.071
50.
00
Delta
RF
-2
-2
-0
-1
-0
0
0
0
-0
-0
0
0
0
0
0
-0
-0
-0
-0
-0
-0
-0
.585
.303
.892
.770
.250
.000
.082
.082
.188
.188
.097
.129
.113
.008
.008
.129
.142
.197
.170
.160
.136
.232
%D
100.
100.
100.
100.
100.
100.
7.
7.
-15.
-15.
8.
11.
10.
0.
0.
-10.
-9.
-15.
-14.
-12.
-15.
-21.
0%
0%
0%
o*
0%
0%
6%
6%
6%
6%
8%
4*
0%
6%
6%
6%
2%
6%
1%
2%
9%
6%
....
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
Dace: 10/17/97
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
TRIANGLE LABORATORIES OF RTF, INC.
Continuing Calibration for O973252
0.906 1.20 31:19 1.0102 1.042
0.822 1.23 0.990
1.348 1.02 32:54 33:03 1.0005 1.467
34:27
1.141 1.00 34:16 1.0373 1.241
1.245 1.01 1.354
0.957 1.03 33:09 33:55 1.0000 1.012
34:05
0.957
1.427
1.039
1.03
0.89
0.84
32:27
40:27
32:27
40:27
36:34
36:27
1.0032
1.0000
Other Standard Summary
Name
37C1-TCDD
13C12-PeCDF
13C12-HXCDF
13C12-HXCDF
13C12-HXCDF
13C12 -HxCDD
13C12 -HpCDF
234
478
234
789
478
789
Internal Standard
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF
13C12-PeCDD
13C12-HXCDF
13C12 -HxCDD
123
123
678
678
RF
0.927
0.992
0.921
0.863
0.807
0.913
0.904
Ratio
1&2
1.55
0.52
0.52
0.52
1.21
0.42
RT
Lo/High
20:32
24:32
22:19
30:19
31:02
37:02
RT
22:33
27:08
30:09
30:47
31:31
30:55
34:15
Rel. RT
1.0007
1.0310
0.9967
1.0176
1.0419
0.9973
1.0368
Summary
RF
1.128
1.074
0.963
0.448
1.070
0.949
Ratio
1&2
0.78
0.82
1.49
1.46
0.52
1.19
RT
Lo/High
20:37
22:37
20:32
24:32
22:19
30:19
23:31
31:31
26:15
34:15
30:00
32:00
RT
21:37
22:32
26:19
27:31
30:15
31:00
Rel. RT
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.
1.
1.
012
308
077
ICal
RF
0.
0.
0.
0.
0.
0.
0.
944
970
974
941
886
897
883
ICal
RF
1.
1.
1.
0.
1.
0.
390
109
094
600
102
962
-0
-0
-0
-0
-0
-0
-0
0
-0
.137
.168
.119
.100
.109
.055
.055
.119
.038
-13.1%
-17.0%
-8.1%
-8.0%
-8.1%
-5.4%
-5.4%
9.1%
-3.6%
Delta
-0
0
-0
-0
-0
0
0
RF
.017
.022
.053
.078
.079
.016
.021
%D
-1.8%
2.2%
-5.5%
-8.2%
-9.0%
1.8%
2.4%
Delta
-0
-0
-0
-0
-0
-0
RF
.262
.035
.131
.152
.032
.013
%D
-18.9%
-3.1%
-11.9%
-25.3%
-2.9%
-1.3%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1
-------
Data: 10/17/97 TRIANGLE LABORATORIES OF RTF, INC.
Continuing Calibration for U973252
13C12-HpCDF 678 0.835 0.43 31:02 33:02 1.0000 0.953 -0.118 -12.4%
37:02
32:55 33:55 1.0000 0.918 -0.085 -9.3%
34:55
36:17 36:27 1.0000 0.763 -0.138 -18.0%
36:37
13C12-H&CDD 678 0.833 1.01
13C12-OCDD 0.625 0.85
Recovery Standard Sunsnary
Name RF Ratio
RT
1*2 Lo/Hign
13C12-1234-TCDD 1.000 0.80
13C12-HXCDD 789 1.000 1.18
ICal Delta
RT Rel. RT RF RF %D
22:18 0.9896 1.000 0.000 0.0%
31:18 1.0097 1.000 0.000 0.0%
QC Front End Check:
1.1102
Page
Trianglo Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
ite: '10/23/97
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976907
.
lit Calibration.:
lal Date
lalyte Summary
ime
Total MCDF
>tal MCDD
Total DCDF
>tal DCDD
Total TriCDF
Jtal TriCDD
2378-TCDF
JTAL TCDF
3378-TCDD
JTAL TCDD
•"2378-PeCDF
_J478-PeCDF
""JTAL PeCDF
_2378-PeCDD
"•JTAL PeCDD
^..23478 -HxCDF
" 73678 -HxCDF
^34678-HxCDF
23789 -HxCDF
lOTAL HxCDF
23478-HxCDD
123678-HxCDD
•^ w/ «^
GO
Instrument .
SF56117
Ofi/10/
-------
Date: ,10/23/97
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standard
Name
37C1-TCDD
13C12-PeCDF
13C12-HXCDF
13C12-HxCDF
13C12-HXCDF
13C12- HxCDD
13C12- HpCDF
234
478
234
789
478
789
1
0
1
1
1
0
0
1
1
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976907
.025 1.22 29:43 1.0102 1.091
.995 1.24 1.059
.489 1.02 31:15 31:25 1.0005 1.543
32:46
.148 1.10 32:36 1.0382 1.184
.319 1.06 1.363
.999 1.05 31:30 32:15 1.0005 1.068
32:25
.999
.728
.049
1.05
0.91
0.86
30:44
38:44
30:44
38:44
34:51
34:44
1
1
.0034
.0000
Summary
0
0
0
0
0
0
0
RF
.929
.988
.940
.860
.789
.940
.792
Ratio
162
1.59
0.51
0.52
0.52
1.21
0.41
RT
Lo/High
19:34
23:34
21:00
29:00
29:24
35:24
RT
21:35
25:44
28:36
29:13
29:56
29:20
32:36
Rel. RT
1
1
0
1
1
0
1
.0008
.0293
.9965
.0180
.0430
.9972
.0382
Internal Standard Summary
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF
13C12-PeCDD
13C12-HXCDF
13C12- HxCDD
123
123
678
678
1
1
1
0
1
1
RF
.378
.047
.060
.617
.418
.036
Ratio
162
0.71
0.80
1.50
1.52
0.52
1.19
RT
Lo/High
19:47
21:47
19:34
23:34
21:00
29:00
22:06
30:06
24:42
32:42
28:25
30:25
RT
20:47
21:34
25:00
26:06
28:42
29:25
Rel. RT
1
1
1
1
1
1
.0000
.0000
.0000
.0000
.0000
.0000
1.068
1.493
1.105
ICal
RF
0.843
0.970
0.959
0.926
0.805
0.973
0.771
ICal
RF
1.318
1.066
1.133
0.635
1.204
0.995
-0.066
-0.064
-0.054
-0.036
-0.044
-0.069
-0.069
0.235
-0.056
Delta
RF
0.086
0.018
-0.019
-0.066
-0.016
-0.033
0.021
Delta
RF
0.060
-0.019
-0.073
-0.018
0.214
0.041
-6.0%
-6.0%
-3.5%
-3.0%
-3.2%
-6.5%
-6.5%
15.8%
-5.1%
%D
10.2%
1.9%
-2.0%
-7.2%
-2.0%
-3.4%
2.7%
%D
4.6%
-1.8%
-6.5%
-2.9%
17.8%
4.1%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:06 10/23/97
-------
Date: 10/23/97 TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976907
13C12-HpCDF 678 0.960 0.44 29:24 31:24 1.0000 0.887 0.073 8.3%
35:24
31:14 32:14 1.0000 0.815 0.032 3.9%
33:14
34:34 34:44 1.0000 0.519 -0.129 -24.9%
34:54
13C12-HpCDD 678 0.847 1.01
13C12-OCDD 0.390 0.93
Recovery Standard Summary
Name RF Ratio
RT
ICal Delta
RT Rel. RT RF RF
%D
162 Lo/High
13C12-1234-TCDD 1.000 0.86
13C12-HXCDD 789 1.000 1.23
21:22 0.9907 1.000 0.000 0.0%
29:42 1.0096 1.000 0.000 0.0%
QC Front End Check:
1.9799
Page 3
.Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:0610/23/97
-------
TRIANGLE LABORATORIES, INC.
Initial Calibration Summary for SF56117
Date: 06/10/97
Instrument :
Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378 -TCDD
TOTAL TCDD
12378 -PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789 -HxCDF
TOTAL HxCDF
123478 -HxCDD
123678 -HxCDD
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HxCDF 478
13C12 -HxCDF 234
13C12-HXCDF 789
13C12-HXCDD 478
13C12- HpCDF 789
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123
s
'/ *•*-,
f -«•
RF
2.
1.
0.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
087
625
687
326
082
933
251
251
191
191
111
115
113
256
256
215
574
247
105
285
953
133
091
059
543
184
363
068
068
493
105
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
0.
0.
0.
0.
0.
0.
0.
843
970
959
926
805
973
771
0
0
0
0
0
0
0
RF
1.
1.
1.
318
066
133
0
0
0
SD
.000
.000
.000
.000
.000
.000
.116
.116
.231
.231
.082
.061
.069
.113
.113
.064
.099
.069
.060
.062
.067
.070
.067
.067
.103
.100
.095
.089
.089
.131
.066
SD
.038
.030
.042
.021
.044
.027
.049
SD
.065
.020
.051
%RSD
0%
0%
0%
0%
0%
0%
9%
9%
19%
19%
7%
5%
6%
9%
9%
5%
6%
6%
5%
5%
7%
6%
6%
6%
7%
8%
7%
8%
8%
9%
6%
%RSD
5%
3%
4%
2%
5%
3%
6%
%RSD
5%
2%
5%
Page
RT
8:15
8:42
10:38
11:09
13 : 59
14:03
19:43
20:36
24:12
24:59
25:22
27:55
28:01
28:32
29:15
28:41
28:46
29:03
30:45
31:57
31:37
34:09
34:03
RT
20:36
24:58
27:55
28:32
29:15
28:40
31:57
RT
19:43
20:34
24:11
1
RT/LO
0:01
0:34
6:43
7:34
10:43
12:34
15:43
16:34
20:11
21:21
24:01
24:45
26:45
27:36
30:02
30:02
RT/LO
18:34
22:11
28:45
RT/LO
18:43
18:34
20:11
RT/HI
13:43
14:
14:
15:
34
43
34
17:43
18:
23:
24:
28:
29:
32:
32:
34:
35:
38:
38:
34
43
34
11
21
01
45
45
36
02
02
RT/HI
22:
26:
34:
34
11
45
RT/HI
20:
22:
28:
43
34
11
Ratlol Ratio2
2.
2.
5.
1.
1.
1.
0.
0.
0.
0.
1.
1.
1.
1.
1.
931
827
965
609
025
064
799
799
772
772
552
470
509
526
526
1.247
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
260
243
246
249
265
251
233
249
034
080
053
993
993
876
902
Ratiol Ratio2
1.
0.
0.
0.
1.
0.
470
518
517
519
241
424
Ratiol Ratio2
0.
0.
1.
734
802
447
N
1
1
1
1
1
1
5
5
5
5
5
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
5
S
5
5
5
S
5
5
5
S
5
5
N
5
5
5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:49 06/10/97
-------
TRIANGLE LABORATORIES, INC. Date: 06/10/97
Initial Calibration Summary for SFS6117
13C12-PeCDD 123 0.635 0.082 13% 25:21 21:21 29:21 1.461 5
13C12-HXCDF 678 1.204 0.073 6% 28:01 24:01 32:01 0.522 5
13C12-HxCDD 678 0.995 0.017 2% 28:45 27:45 29:45 1.240 5
13C12-HpCDF 678 0.887 0.046 5% 30:45 28:45 34:45 0.429 5
13C12-HpCDD 678 0.815 0.077 9ft 31:36 30:36 32:36 1.019 5
13C12-OCDD 0.519 0.080 15% 34:02 32:02 36:02 0.866 5
Recovery Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 N
13C12-1234-TCDD 1.000 0.000 0% 20:21 0.811 5
13C12-HXCDD 789 1.000 0.000 0% 29:02 1.231 5
*** End of Report •**
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 09:49 06/10/97
3hone: (919) 544-5729 • Fax: (919) 544-5491
-------
TRIANGLE LABORATORIES OF RTP, INC.
Initial Calibration Summary for UF59167
Date: 09/17/97
Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDP
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-P*CDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HxCDD
123678-HxCDD
123789-HXCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Oth*r Standards
37C1-TCDD
13C12-P«CDF 234
13C12-HXCDF 478
13C12-HXCDF 234
13C12 -HxCDF 789
13C12-HXCDD 478
13C12-HpCDF 789
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12-P*CDF 123
u
RF
2
2
0
1
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
0
1
1
1
1
1
1
1
.585
.303
.892
.770
.250
.000
.077
.077
.210
.210
.109
.138
.124
.382
.382
.212
.541
.267
.207
.307
.857
.071
.042
.990
.467
.241
.354
.012
.012
.308
.077
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
0
0
0
0
0
0
0
.944
.970
.974
.941
.886
.897
.883
0
0
0
0
0
0
0
RF
1
1
1
.390
.109
.094
0
0
0
SD
.566
.263
.121
.150
.000
.000
.056
.056
.179
.179
.022
.080
.040
.159
.159
.049
.067
.111
.061
.069
.045
.039
.020
.032
.037
.084
.051
.044
.044
.078
.039
SD
.015
.043
.026
.046
.036
.023
.031
SD
.117
.027
.045
%RSD
22%
11%
14%
8%
0%
100%
5%
5%
15%
15%
2%
7%
4%
12%
12%
4%
4%
9%
5%
5%
5%
4%
2%
3%
3%
7%
4%
4%
4%
6%
4%
%RSD
2%
4%
3%
5%
4%
3%
4%
%RSD
8%
2%
4%
Pag*
RT
9:04
9:40
12:12
12:53
11:49
23:33
24:20
27:49
28:33
28:55
31:27
31:33
32:03
32:47
RT/LO
3:32
4:20
10:32
11:20
14:32
16:20
19:32
20:20
23:48
24:54
27:32
RT/HI
17:32
18:20
18:32
19:20
21:32
22:20
27:32
28:20
31:48
32:54
35:32
Ratiol Ratio2
3
2
6
1
0
0
0
0
0
1
1
1
.578*
.804
.782
.518
.237*
.752
.752
.738
.738
.480
.470
.474
1.548
1
1
1
1
1
.548
.293
.256
.271
.260
1.268
32:10
32:15
32:33
34:14
35:29
35:06
37:59
37:50
RT
24:20
28:32
31:26
32:02
32:46
32:09
35:28
RT
23:32
24:20
27:48
1
28:14
30:14
31:05
33:50
33:50
RT/LO
22:20
25:48
32:14
RT/LO
22:32
22:20
23:48
36:14
38:14
39:05
41:50
41:50
RT/HI
26:20
29:48
38:14
RT/HI
24:32
26:20
31:48
1
1
1
1
1
0
1
1
1
0
0
.272
.236
.258
.254
.045
.993
.020
.031
.031
.899
.839
Ratiol Ratio2
1
0
0
0
1
0
.421
.514
.511
.515
.197
.427
Ratiol Ratio2
0
0
1
.746
.805
.441
N
5
5
5
5
2
0
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
N
5
5
5
5
5
5
5
N
5
5
5
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:02 09/17/97
-------
TRIANGLE LABORATORIES OF RTF, INC. Date: 09/17/97
Initial Calibration Sumnary for j*?59167
13C12-PeCDD 123 0.600 0.047 8% 28:54 24:54 32:54 1.424 5
13C12-HXCDP 678 1.102 0.047 4% 31:32 27:32 35:32 0.520 5
13C12-HXCDD 678 0.962 0.014 1% 32:14 31:14 33:14 1.207 5
13C12-HpCDP 678 0.953 0.050 5% 34:14 32:14 38:14 0.420 5
13C12-HpCDD 678 0.918 0.029 3% 35:05 34:05 36:05 1.030 5
13C12-OCDD 0.763 0.065 9* 37:50 35:50 39:50 0.856 5
Recovery Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 N
13C12-1234-TCDD 1.000 0.000 0* 24:08 0.820 5
13C12-HXCDD 789 1.000 0.000 0* 32:32 1.210 5
*** End of Report ***
Page 2
Trianglo Laboratories, Inc.® Analytical Services Division
n01 Caprtola Drive • Durham, North Carolina 27713 Printed-14-02 09/17/97
-------
TRIANGLE LABORATORIES, INC.
Initial Calibraeion Sumnary Cor XF24087
Date: 04/09/97
Analysis Dace : 04/08/97
Instrument : X
Method : C2NF
GC Column...: DB-225
Analycas
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
RF SO %RSD
0.967 0.044 5%
0.967 0.044 5%
1.095 0.097 9%
1.095 0.097 9%
RT RT/LO RT/HI Raciol RaCio2 N
21:49 14:49 25:49 0.779
0.779
20:37 16:36 24:36 0.793
0.793
10
10
10
10
Other Standards
37C1-TCDD
RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 N
1.018 0.047 5% 20:37 18:36 22:36 10
Internal Standards RF SD %RSD RT RT/LO RT/HI Ratiol
13C12-2378-TCDF 1.392 0.071 5% 21:49 20:49 22:49 0.787
13C12-2378-TCDD 1.105 0.037 3% 20:36 18:36 22:36 0.783
Ratio2
N
10
10
Recovery Standards RF SO %RSD
13C12-1234-TCDD 1.000 0.000 0%
*** End of Report ***
RT RT/LO RT/HI Ratiol Ratio2 N
20:50 0.796 10
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 02:46 04/09/97
-------
Appendix B.2
Analytical Data
-------
- Vr
CASE NARRATIVE
Analysis of Samples for the Presence of
Semivolatile Analytes by
High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
METHOD 8270A Rev. 1 (7/92)
Date:
November 13,1997
Client ID
Pacific Environmental Services
TLI Project Number : 43433
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
-------
TRIANGLE LABORATORIES, INC. November 13,1997
CASE NARRATIVE 43433
Objective: Analysis of six MM5 train samples for Method 8270 polynuclear aromatic
hydrocarbon (PAH) and Clean Air Act (CAA) semivolatile compounds.
Method:
Six MM5 train samples were received by Triangle Laboratories, Inc. on ice at 3°C on September
29,1997. Although a condensate was listed on the client chain-of-custody (COC) for sample SO-
MM5-1, no condensate was received for that sample. In addition, the Lab Blank sample was not
listed on the client COC. The samples were stored in a cooler at 4°C prior to extraction. The
XAD traps used for sampling were pre-spiked with 100 micrograms (ug) of terphenyl-dn prior to
sampling. Prior to extraction, the XAD, filter, and rinses were spiked with 100 ug of phenol-ds,
2,4,6-tribromophenol, l,4-dibromobenzene-d4, and pyrene-dio. These portions of the MM5 trains
were Soxhlet extracted with methylene chloride for 16 hours. The impinger condensates, when
present, were spiked with 100 ug of the surrogate standards anthracene-dlO, 2-fluorobiphenyl,
nitrobenzene-ds and l.S.S-trichlorobenzene-da before being extracted with methylene chloride
using a separatory funnel. The extracts were combined and brought to a final volume of 1.0 mL
for the semivolatile analysis. The analysis is based on the guidelines of Method 8270A Rev. 1
(7/92). The results reported relate only to the items tested.
The internal standards, l,4-dichlorobenzene-d4, naphthalene-dg, acenaphthene-dio, phenanthrene-
dio, chrysene-di2, and perylene-dja, were added to the extracts such that the final internal standard
concentration was 40 ug/mL immediately prior to analysis by GC/MS.
The GC/MS analysis conditions are listed below:
GC Conditions:
Column: J&W DB5-625, 30m x .32mm x lum
Program: 35C, ramp at 12C/min to 285C, hold for 2 min.
ramp at 8.5C/min to 315 C, hold for 6.5 min.
Carrier Gas: Helium
MS Conditions:
Instrument: HP MSD, Chemsystem and Target data systems
Scan: 35-550 amu at 1.67 scan/sec
Interface: Capillary, Injector: 250C, Detector: 275C
Report:
Enclosed with the case narrative are the sample identification index, project summary sheets,
client and TLI chain of custody sheets, wet laboratory extraction information sheets, GC/MS
tracking forms, and analytical run logs. The sample identification index correlates the client
sample name, TLI sample number and the analytical file name for the each sample. The project
summary sheets list the amounts of analytes detected in gray and list the estimated detection limits
in parentheses for analytes which were not detected.
-------
TRIANGLE LABORATORIES, INC. November 13,1997
CASE NARRATIVE 43433
The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target analytes. The quantitation report header lists the TLI project number, analysis
method, instrument sample file name, and client sample name. The client project number, TLI
sample number, calibration file, dilution factor, and date received, extracted, and analyzed are also
listed in the quantitation report header. The response factors used for all calculations are from the
continuing calibration listed in the header. All initial and continuing calibration data are located in
the back of the data package. The amount reported for each target analyte detected in the
samples is reported in total ug. The retention time (RT) will be listed for all internal standards
and analytes which are detected. If a target analyte is not detected, it will be flagged with a "U"
and a detection limit will be listed. Estimated detection limits are calculated using an area of
10,000 for all analytes which were not found in the samples. The estimated detection limits
reported are the average detection limits achievable over time on an instrument type. The actual
detection limit for a given compound on a given day may vary from the estimate reported. The
quantitation limit for all analytes is half of the low point of the initial calibration adjusted for
dilution when appropriate. Below this point the calibration cannot be considered to be linear.
Any amounts reported at a level below the quantitation limit will be flagged with a "J" and should
be considered estimated. If a target analyte is found at a level exceeding the upper calibration
limit, it will be flagged with an "E" and should also be considered estimated. Any analytes flagged
with a "B" on the sample topsheets were detected in the associated laboratory blank. All target
analytes are quantitated against the internal standard preceding them on the target analyte list.
Surrogate standards are quantitated against the internal standard with the matching internal
standard reference number. For example, phenol-ds has 1 in the IS Ref column and would be
quantitated against the internal standard which has IS1 listed in the flag column. If an internal
standard area is above or below the quality control limits as defined by the continuing calibration,
it will be flagged with "High" or "Low" in the flag column.
Immediately following the quantitation report are two pages which comprise the total ion chro-
matograms. Labeled internal and surrogate standards present in the sample have their identifica-
tions and retention time printed above their peak on the chromatogram. The chromatogram is
followed by the interim report. On the interim report a $ is indicative of a surrogate standard and
a * represents an internal standard. The interim report from the instrument is followed by the
target spectra of detected compounds. Four spectral plots are included for each compound: a raw
spectrum of the peak, a background subtracted version of the same spectrum, a library spectrum
of the compound, and a plot showing the percent difference between the library spectrum and the
background subtracted spectrum. Extracted ion current profiles are plotted on the right-hand side
of the page showing the quantitation mass and one or two other prominent ions known to be
present in target compound as they appear in the sample peak.
Results:
All samples were extracted outside the fourteen day sampling to extraction holding time. All
samples and blanks were analyzed within the extraction to analysis holding time.
Please note that several target analytes were found at levels below the quantitation limit in the
laboratory blank. These analytes should not be considered truly present in the native samples
-------
TRIANGLE LABORATORIES, INC. November 13,1997
CASE NARRATIVE 43433
is twenty times the level in the blank, the blank contribution can be considered statistically
insignificant.
The internal standard area for perylene-d!2 was outside Method 8270 quality control limits in
samples SO-MM5-2-17 and SO-MM5-4-51. These internal standards were flagged with "IS
High" and the amounts quantitated against them should be considered estimated.
Each sample was processed twice, once against the calibrations containing the PAH compounds
and once against the calibrations containing CAA compounds. Therefore, each sample reported
contains topsheets and interim reports for both the PAH and CAA analyses as well as a chroma-
togram and spectra for all analytes. Please note that the surrogate standards have been reported
from the PAH analyses only.
All surrogate standard percent recoveries were within in-house quality control limits as defined by
the following 95 percent confidence intervals:
Surrogate Standards Mean 95% confidence interval
l,3,5-trichlorobenzene-d3 55 22.19 - 87.75
l,4-dibromobenzene-d4 69 34.65 - 103.19
2,4,6-tribromophenol 78 32.43 - 123.81
2-fluorobiphenyl 77 37.70 - 115.87
anthracene-dio 77 37.45 - 116.75
nitrobenzene-ds 68 30.52 - 105.65
phenol-ds 70 28.39 - 112.40
pyrene-dio 80 33.65 - 126.15
terphenyl-d14 77 18.86 - 135.64
Sample Calculations:
Response Factor, RF = Area analyte x Amt Is
Area IS x Amt analyte in the ccal
Amount ug = Area analyte x Amt IS x DF
Area IS x RF
Where:
Amt IS = amount of internal standard = 40 ug
Amt analyte in the ccal = amount of analyte in the continuing calibration = 50 ug
-------
TRIANGLE LABORATORIES, INC. November 13,1997
CASE NARRATIVE 43433
The data reported has been judged to be valid and in compliance with the guidelines of Method
8270A Rev. 1 (7/92) except as noted above. Should you have any questions about this project,
please feel free to contact our Project Scientist, Amy Boehm, at (919) 544-5729, extension 268.
For Triangle Laboratories, Inc.,
Report Preparation: Quality Control:
Sarah A. Hubbard
Report Preparation Chemist Report Preparation Chemist
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accredidation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(lncluding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management. Expires December 31,
1997. Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 1S,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles. Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Recertification pending. Registration
# PH-0117. Dioxin in drinking water.
V *
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 10/28/97 RM
Printed 10/29/97 oni . ., , Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 2TZ09-3485
-------
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Heajth and Environment. Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste -E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31, 1997. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires June 3, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31, 1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.
State of New Mexico, Environment Department. Recertification pending. Dioxin in drinking
water.
New York State Department of Health. Expires April 1, 1998. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water. •—
Revised 10/28/97 RM
Printed 10/29/97
-------
Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires April 1,
1998. Certificate number #99040001 -(drinking water). Expires August 31, 1999. Certificate '
number #99040002 (other parameters). Dioxin/Furans, SNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit. Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockbourne Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington,' Department of Ecology. Expires September 11, 1998. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
10/28/97 RM
PrintBd 10/29/97
-------
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998.
Laboratory ID Number 999869530. Certification for the following categories of Organics:
Purgeable, Base/Neutral, Acid, RGBs, and Dioxin. Expires November 14, 1999. .Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1998. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 10/28/97 RM
-------
Triangle Laboratories of RTF
Sample Identification Index for Project: 43433
ClientTd:
SO-MM5-1-8
SO-MM5-2-17
SO-MM5-3-37
SO-MM5-4-51
FBI-MM5-1
LAB BLANK-MM5-28
SBLK101497
185-7-2A-C,E
185-7-3A-F
185-7-4A-F
185-7-5A-E
185-7-1A-D
185-7-6A-C
SBLK101497
YP788
YP789
YP790
YP791
YP775
YP774
YP773
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Proj_Sumv4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 43433
Client ID:
ilename :
.11 Id :
Matrix :
Jnits :
SO-MM5-1-8
YP788
185-7-2A-QE
MM5
ug
SO-MM5-2-1
7
YP789
185-7-3A-F
MM5
«g
SO-MM5-3-3
7
YP790
185-7-4A-F
MM5
"g
SO-MM5-4-5
1
YP791
185-7-5A-E
MM5
"g
FBI-MM5-1
*
YP775
185-7-1A-D
MM5
"g
Naphthalene J/L"'!lxcJE&S,L *Kt ' Y-;'V•£1pM 7^ j^f ?,!2.14; f 1 &;*&*'' (0-25)
tenaphthene , C aiS (0.44) "/,'*""'4*4* X,- "-^\^2; (0.42)
Fluorene ,V * ^^ A%,,, JUl*$&' _ \,\\ 1$3 J"" " ^5^7 (0.41)
nhenanthrene 'ss\ ,„„" 2.07 / s si^^slllS, -^f" " 1*77 ' %/,T ,1^7 "I-""' &&.
imthracene '\ ; \9M (0.28) **„ , 0^4 /'*\%W»% (0.31)
Fluoranthene s { " "-" ' &M ' ,," t47 0*8& s 1 * &91. (0.29)
>yrene ,\ , lift A/,%,1^ % 1.05 0.9$ (0.26)
Jenzo(a)anthracene (0.24) (0.19) (0.24) (0.19) (0.30)
Chrysene , 0.22 (0.19) (0.25) (0.19) (0.30)
Jenzo(b)fluoranthene (0.20) (0.15) (0.19) (0.16) (0.24)
Benzo(k)fluoranthene (0.20) (0.16) (0.20) (0.17) (0.23)
T3enzo(e)pyrene (0.18) (0.14) (0.18) (0.15) (0.22)
Jenzo(a)pyrene (0.21) (0.16) (0.20) (0.17) (0.25)
Perylene (0.20) (0.16) (0.19) (0.16) (0.23)
ndeno(l,2/3-cd)pyrene (0.18) (0.14) (0.17) (0.15) (0.22)
Jibenz(a,h)anthracene (0.24) (0.19) (0.23) (0.20) (0.29)
Benzo(g,h,i)perylene (0.20) (0.16) (0.19) (0.16) (0.24)
( )-Estimated Detection Limit Page 1
Triangle Laboratories of RTF, Inc Savar v3.5
-------
Triangle Laboratories of RTF
Project Summary for Project 43433
Client ID: LAB BLANK- SBLK101497
MM5-28
Filename :
TLJId :
Matrix :
Units :
YP774
185-7-6A-C
MM5
ug
YP773
SBLK101497
XAD
ug
Naphthalene (0.29) ,-„ ^
2-Methylnaphthalene (0.47) (0.43)
2-Chloronaphthalene (0.43) (0.44)
Acenaphthylene (0.27) (0.27)
Acenaphthene (0.45) (0.45)
Fluorene (0.44) (0.45)
Phenanthrene (0.32) (0.29)
Anthracene (0.33) (030)
Fluoranthene (031) (0.29)
Pyrene (031) (0.28)
Benzo(a)anthracene (037) (032)
Chrysene (037) (033)
Benzo(b)fluoranthene (0.36) (030)
Benzo(k)fluoranthene (0.34) (0.29)
Benzo(e)pyrene (0.33) (0.28)
Benzo(a)pyrene (0.37) (031)
Perylene (034) (0.28)
Indeno(l,23-cd)pyrene (0.32) (0.27)
Dibenz(a,h)anthracene (0.43) (0.36)
Benzo(g,h,i)perylene (0.35) (0.29)
( )-Estimated Detection Limit Page 2
Triangle Laboratories of RTF, Inc. Savar v3.5
801 Capitals Drive • Durham, North Carolina 27713 Printed: 1721:40 11/13/97
-------
Triangle Laboratories of RTF
Project Summary for Project 43433
Client ID:
Filename :
mid :
Matrix :
Units :
h-Nitrosodimethylamine
Cumene
Phenol
Aniline
Benzyl Chloride
1 .4-Dichlorobenzene
SO-MM5-1-8
YP788
185-7-2A-C,E
MM5
ug
(1.49)
(0.38)
yvvvy
(0.50)
(0.39)
x"" ' ''"' Q»7J
SO-MM5-2-1
7
YP789
185-7-3A-F
MM5
ug
__(1^0)
:^* ?ifc&
(050)
(0.39)
< ~ ss, ' " 0J12
SO-MM5-3-3
7
YP790
185-7-4A-F
MM5
ug
_Jl-59)
>'^!tio* '
,%lj" "-" -V?"2i27.
' s'% ie3&
SO-MM5-4-5
1
YP791
185-7-5A-E
MM5
ug
_O39)v
'^;7:f;ym44 r;-
(0.46)
(0.36)
...Xv.....1-.., ....-.•• i-SO « :
FBI-MM5-1
"
YP775
185-7-1A-D
MM5
ug
(1-44)
(039)
(052)
(0.40)
i % % ;% 5 0^43
2-Methylphenol (0.86)
Acetophenone ,,„" " SJ£
n-Nitrosomorpholine (1-44)
o-Toluidine (0.52)
Hexachloroethane (1-37)
l,2-Dibromo-3-chloropropane (1-42)
N,N-Diethylaniline (0.51)
bis- (2-Chloroethyl) ether (1.07)
3/4-Methylphenol (0.76)
Nitrobenzene (0.52)
N,N-Dimethylaniline (0.50)
Isophorone (0.44)
o-Anisidine (0.91)
1,4-Phenylenediamine (0.72)
1,2,4-Trichlorobenzene (0.83)
Hexachlorobutadiene (1.35)
a,a,a-Trichlorotoluene (0.64)
Hydroquinone (0.76)
2-Chloroacetophenone - (0.35)
Hexachlorocyclopentadiene (1-51)
2,4,6-Trichlorophenol (1.29)
2,4,5-Trichlorophenol (1.21)
Biphenyl " 2.13
Dimethylphthalate ,, %M
4-Nitrophenol • (1.72)
2,4-Dinitrotoluene (1-41)
Dibenzofuran (0.33)
4/6-Dinitro-2-methylphenol (2.80)
Trifluralin (2.09)
(0.86)
(0.82)
(1.44)
(0.52)
(1.37)
(1.43)
(0.51)
(1.07)
(0.76)
(052)
(0.50)
(0.44)
(0.92)
(0.73)
(0.83)
(1.36)
(0.64)
(0.77)
(0.35)
(1.50)
(1.21)
(154)
(0.56)
(1.46)
(1.52)
(0.55)
(1.14)
(0.81)
(0.56)
(054)
(0.47)
(0.98)
(0.78)
(0.89)
(1.45)
(0.69)
(0.82)
(0.38)
(1.57)
(1.34)
(1.26)
(1.34)
(0.49)
(1-27)
(1.32)
(0.48)
(0.99)
6.99
(0.49)
(0.47)
(0-41)
(0.86)
(0.68)
(1.71)
(1.41)
(0.33)
(2.79)
(2.08)
, 2.2$
(1.78)
(1.47)
(1.27)
(0.60)
(0.72)
(0.33)
(1.40)
(1-20)
(1.12)
2.50
145
(1.59)
(131)
(2.91)
(2.18)
(2.60)
(1.94)
(1-44)
(0.52)
(1.35)
(1.43)
(0.49)
(1.11)
(0.83)
(0.52)
(0.53)
(0.44)
(0.95)
(0.69)
(0.80)
(1.37)
(0.65)
(0.71)
(0.35)
(1.34)
(1.22)
(1.06)
(0.33)
"""332
(1.79)
(1.38)
(0.30)
(3.05)
(2.22)
( )-Estimated Detection Limit Page 1
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:49:03 11/13/97
-------
Triangle Laboratories of RTP
Project Summary for Project 43433
Client ID: SO-MM5-1-8 SO-MM5-2-1 SOMM5-3-3 SO-MM5-4-5 FBI-MM5-1
771
Filename :
TLJId :
Matrix :
Units :
YF788
185-7-2A-C,E
MM5
«g
YP789
185-7-3A-F
MM5
«g
YP790
185-7-4A-F
MM5
"g
YP791
185-7-5A-E
MM5
ug
YP775
185-7-1A-D
MM5
«g
2,4-Dinitrophenol (3.75) (3.73) (3.90) (3.48) (4.70)
Di-n-butylphthalate %x^\^ !x &$& %\,\ ^•-'"^%.$&' 'I^x x -''4=67, -"V^"**^ SJ^" i'\^"^ s^£ii?
J I "• "• "• "• f f w •.*.•.:::•.•. f f -.-• f ~. •• -.-.-. f f. ~. : -..--.-..v-..-
Hexachlorobenzene (0.99) (0.88) (1.00) (0.84) (0.88)
4-Aminobiphenyl (0.41) (0.37) (0.42) (035) (038)
Pentachlorophenol (1.75) (156) (1.77) (1.49) (1.68)
Pentachloronitrobenzene (3.83) (3.41) (3.87) (3.26) (3.55)
4-Nitrobiphenyl (1.06) (0.94) (1.07) (0.90) (0.96)
Benzidine (0.33) (0.26) (0.33) (0.26) (0.44)
4,4'-Methylenedianiline (0.80) (0.63) (0.80) (0.63) (1.02)
Dimethylaminoazobenzene (0.71) (0.56) (0.71) (0.56) (0.88)
33'-Dimethylbenzidine (0.41) (0.32) (0.41) (0.32) (0.55)
33'-Dimethoxybenzidine (0.82) (0.64) (0.81) (0.64) (1.13)
33'-Dichlorobenzidine (0.60) (0.48) (0.60) (0.47) (0.74)
Methylenebis-chloroaniline (1.40) (1.10) (1.39) (1.09) (1.68)
bis(2-Ethylhexyl)phthalateJ\;:/ Ipfr , ; ^••203? i ^ .'
( )-Estimated Detection Limit Page 2
Triangle Laboratories of RTF, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 12:49:03 '"
-------
Triangle Laboratories of RTF
Project Summary for Project 43433
Client ID: LAB BLANK- SBLK101497
MM5-28
Filename: YP774 YP773
Olid : 185-7-6A-C SBLK101497
Matrix : MM5 XAD
Units : ug ug
n-Nitrosodimethylamine (1.50) (1.41)
Cumene (0.41) (039)
Phenol (0.66) (0.63)
Aniline (0.54) (051)
Benzyl Chloride (0.41) (0.39)
1,4-Dichlorobenzene (0.67) (0.63)
2-Methylphenol (0.86) (0.81)
Acetophenone (0.61) c, \% V'„ 2&&
n-Nitrosomorpholine (1.49) (1.41)
D-Toluidine (0.54) (0.51)
Hexachloroethane (1.41) (1.33)
l,2-Dibromo-3-chloropropane (1.48) (1-40)
N,N-Diethylaniline (0.51) (0.48)
bis- (2-Chloroethyl) ether (1.15) (1.08)
3/4-Methylphenol (0.99) (0.89)
Nitrobenzene (0.62) (0.56)
N,N-Dimethylaniline (0.63) (0.57)
Isophorone (0.52) (0.47)
o-Anisidine (1.13) (1.02)
1,4-Phenylenediamine (0.82) (0.74)
1,2,4-Trichlorobenzene (0.95) (0.86)
Hexachlorobutadiene (1.63) (1.47)
a,a,a-Trichlorotoluene (0.77) (0.70)
Hydroquinone (0.85) (0.77)
2-Chloroacetophenone - (0.41) ^ 3.83
Hexachlorocyclopentadiene (1-44) (1-46)
2,4,6-Trichlorophenol (1.31) (1.33)
2,4,5-Trichlorophenol (1.14) (1.15)
Biphenyl (0.36) (0.36)
Dimethylphthalate s , " 144 (0.42)
4-Nitrophenol • (1.93) (1.96)
2,4-Dinitrotoluene (1.48) (1.50)
Dibenzofuran (0.32) (0.32)
l,6-Dinitro-2-methylphenol (3.27) (3.32)
Trifluralin (239) (2.42)
( )-Estimated Detection Limit Page 3
Triangle Laboratories of RTF, Inc Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 12:4943(41 /13/97
-------
Triangle Laboratories of RTF
Proj ect Summary for Proj ect 43433
Client ID: LAB BLANK- SBLK101497
MM5-28
Filename :
TLJId :
Matrix :
Units :
2,4-Dinitrophenol
YP774
185-7-6A-C
MM5
ug
(5.05)
YP773
SBLK101497
XAD
ug
(5.12)
Di-n-butylphthalate -
Hexachlorobenzene (0.96) (0.87)
4-Aminobiphenyl (0.41) (0.37)
Pentachlorophenol (1.82) (1.66)
Pentachloronitrobenzene (3.84) (3.50)
4-Nitrobiphenyl (1.04) (0.95)
Benzidine (0.54) (0.47)
4,4'-Methylenedianiline (1.26) (1.11)
Dimethylaminoazobenzene (1.08) (0.95)
3,3'-Dimethylbenzidine (0.67) (0.59)
3,3'-Dimethoxybenzidine (1.39) (1.22)
33'-Dichlorobenzidine (0.91) (0.80)
Methylene bis-chloroaniline (2.06) (1.81)
bis(2-Ethylhexyl)phthalate \/ && I.."'""" QS7
( )-Estimated Detection Limit Page 4
Triangle Laboratories of RTF, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 12:49:03 11/13/97
-------
CLIENT CHAIN OF CUSTODY
SAMPLER'S SIGNATURE
P/Q 03927/0700003270
From: Pacific Environmental Services
5001S. Miami Blvd. Suite 300
RTF, NC 27709
. Project: Tull Citji/iN
Contact: Frank Meadows
Phone: 919-941-0333
Fax: 919-941-0234
P.O.tf:
(PES03/AJB)
If the data will be reported to a state agency, which one?.
Relinquished. By/Sign.
Analysis Wanted:
Total Number of
Containers:
Relinquished By/Sign.
Received for
Date/Time
y/Sign.
Relinqui^e^ By/Sign.
Date/Time
Received By/Sign.
Date/Time
Send Samples to: Triangle Laboratories, Inc.
Attn: Sample Custodian
801 Capitola Drive
Durham, NC 27713 USA
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
oo
PROJECT,:
RECOVERY
PERSON:
If.
/fa
SAMPLE
TECHNICIAN:
SAMPLE IDENTIFICATION
COLLECTION
DATE TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
ANALYTICAL REQUEST
—
SSTSS3
U
gEUNqus^En ^VME-
0£7£/6»A-
"^ RgCETVErf&NAME
D'ATE/TIM
HTURE
SHIPPER'S NAME AND ID NUMBER
bATE/f IME
-------
METHOD -PCIC
Plant G^M-£A6|Ato
Sample Date: °[ \22 \ °Pr
Sample Location: ^>E|
Recovery Date: ^t\22_ \\\"
ji*«f SAMPLE RECOVERY DATA
U)
F£?l- MO"1?
Filter No.(s):-$^-f|^«^=^•lfl'
t TVofsr B CvcDy\^
1 ^
\ XAD 2 Tran No (sV S li v-l
Run No.:J3-5«*f*tf5=e>^
t Job No.:*S*{M.Dii3>
HAW2 -Pfti- nn-
Sample Recovery Person: *^- ' OuL.
,.- ;\F*:.^-::^~r£t^r' ;>'''..>.5>--y. ^JJ'-V f"."" "i'i'J
Impingers
Final wt.
Initial wt.
Netwt
XAD-2
Trap
—
—
—
1
(knockout)
•y^1^
V"^.^
OD
^^Iiiiipiisturei'i3^tife:v 1^^;-
2 3
(100mlH2O) (100mlH2O)
(untipped) ^tipped)
Jn(~^ f~j "^^ — TJ
'^i it ^^1 —A // ^^
"^l*?^ "?-2(»*>
C7.D /O.iv
.•:.^i\-j*/s-r':.:; .- \.~'-1,'«.. .r^VK7s.:v-.v.{*> VV-» -C.1^; v.V- *'
:•% ^•^•^b?':^;S^r '^^'^i>
4
(knockout) Silica gel
(untipped) (untipped)
C? /5"- C t^(^ ^ . 2^ 9
0?t5»^b ^loZ.2. g
(f^-.f) Q.O g
P^^SM^
Train System: fe^ft ^V^tS ^
Probe:
">' k
h**
Filter: Color- K/0 (JVcrA*
Impinger Contents:
Silica Gel:
©Grams
>T>N^ "T^irto / BDX
Loading - Wo ur
I^X A>-IC5 / te./£. tfOtr
— lJ \ t. ~\ S*
C . 1 K' I [UK. is- r-
\ (uC\i^.l '^D Vw. l<>\WO->t
Used- 3oO Color -^c Cuiuior % Spent - K}^,J*
Condensate Observed In Front Half vWf
':v^¥"M;^^^^^S^^^^r^^m^^^SvS^
Filter Container No. ¥&!- foftS
XAD Module Container No.: f^fel- fifa£
Probe (FH)
& Back. Half Rinse (Acetone) Container No.: f-&{- /
Probe '(FH) & Back Half Rinse (Toluene) Container No.: rfij-
Impinger Contents Container No.:
Impmqer Rinse (Acetone/MeCI2)
Container No.:
-^v^lt^-ffe^^SifeS'
marked/sealed: ^-^
marked/sealed: >^
Liquid level j
ci/-i$ marked/sealed: ^
Liquid level ;
fyfy marked/sealed:
-------
fW
r*
METHOD O-OieyW SAMPLE RECOVERY DATA
Plant: C^fij- S/-l6,/^AuT Run No.: So • (vjrwc- 1
Sample Date: c\ \W \ '? } Filter No.(s): _S£ Aim - / Job No.: S-i ,M uctf
Sample Location: f) O^pol^ cl_. ,rpwnS££ .\ML£~\ —
Recovery Date: ^IM \ uf ?• XAD-2 Trap No.(s): St> mr* *i - 1
Sample Recovery Person: >**f^r ^V^-IO1 —
•^:fe:- ":r'"^h^fe^:^^?^iv.v/:St.?^"'v "^Svvrr^ Md istuirei. Datasjir.' £".:;•• -^•••-'^ j— :.^^j-2^:'v T.V^-^^-r^^^i;;-
1234
Impingers XAD-2 (knockout) (100mlH2O) (100mlH2O) (knockout) Silica gel
Trap (untipped) (tipped) (untipped) (untipped)
'SrrgTwt. — llk.l 7^ O- 7 /^- /5". 2. g
Initial wt. -*- ^5^ >\>-H ~>l^-5 U/>2. p. ^S.S g
luwfwt. «^ ^7/'V 7>/.Z 7^.2- 6/^K:5^iii^SSLffiW:B^
Train System: &r(\ CT\i>VnDA T^C> r A\m^ / BfcV J^T^^ ^V r?^ _>,? ^
Probe: I-' ^Uv^ / ^-'^*r
Filter: Color- (_^re^ /"Oi" Loading- i\1frf/urvN
Impinger Contents: (f.| ft-^
Silica Gel: ©Grams Used - ^CD Color- !l V!-L'S< % Spent- VO
Condensate Observed In Front Half: X^xt
.»;-.- . • . ._ • • • I'ir.-.atiT''- » i - '.••-»»^*t|>».i*'i'd^ur.W'.i*!*>T-1Ai .:j"v.j^",'*"t-'« ~"£:.:-.t'*t"'~t>^^-'i*t'^\.***-*'-«<'^'-?'~^>'':-^^^
• ' T*:.*' TIL; ^r^rir-ii^-;^:.^;^; • .; ]^ R^cpvered: S^ ni pli£1- ractj oriss-- ^f : -; v;:v • v ; :^^j;-;_f v^":^:^^^
Filter Container No. Sb- itfMfj - 1 marked/sealed: ^
XAD Module Container No.: Sd-fa/bS'/ marked/sealed: ^
p\<-~\\ -Te-tK..^ Liquid level ^
Probe (FH) & Back Half Rinse (Acetone) Container No.: ."> » /
-------
METHOD *>*
Plant: G^ M - C-,SQ6
Sample Date: -] JZM I^T-
Sampie Location: r) O*-0<.
1
Recovery Date: 'Q |
Sample Recovery Person: k£
( 0 SAMPLE RECOVERY DATA
^) NJQ"oO
Filter No.(s): SO - -O^S - 2
si*. C,c,ruJk-k~ ^.^
Run No.: Sfc - rA^ - a
Job No.: "SHIM .ot)b
l^t
XAD-2 Trap No.(s): ?'**&:\'S-?x* ••'••••ii^'J':"V-'V-r'.;->'':"'- v'is;';v _••;••?•.' ^ •,':-:-"".--
.^•!>::^J:^^^ Dates::"?/.:- -->.v
1
Impingers XAD - 2 (knockout)
Trap
Final wt. - — /D^D.fe
Initial wt. V ^S"^
Netwt. fcl^l
2 3
(1QOmlH2O) (100mlH2O;
(untipped) [tipped)
'^O.T. ^(.^
~J\t\,oi ~'}2I -*>
^D^> °>~)~
'^pfggl^lp^^f^g
4
(knockout) Silica gel
(untipped) (untipped)
6>/^5" &\2.*> g
Lf'^-C £{£>:!.£. g
a^ 3*0.*^ g
!^^&7£^s:-l^
Train System: £- K!
• (C ("l^ul ^V^?,2
Probe: "? ' (Jj,^>*-> .' C_ le^r
Filter: Color- C^reoj /~fAN
^ Loading- ^UHl-'uv
YY^
Impinger Contents: C~Aea>r
Silica' Gel: @Grams Used - 3o
o Color- MBl\At % Spent- ^
Condensate Observed In Front Half. fOz>w ^
:.VT^rf^:;.:^??vfcik%:-^^3^^
Filter Container No. .^0 - Mh^> ' ^*
XAD Module Container No.: 5i? - itifa$ ' 2-
V
Proba (FH) & Back Half Rinse (Acetone) Container No.: >->-/•
Probe '(FH) & Back Half Rinse (Toluene) Container No.:5<5-j!|
Impinger Contents Container No.
Impinger Rinse (Acetone/MeCI2)
5 ^ - AA/ - ^ i
Container No.:
?^-j7^s^"^^"^.s~!^''-'y^s^v'^^»-
marked/sealed:
marked/sealed:
Liquid level
^-^ marked/sealed: ^
Liquid level
*4^ marked/sealed:
Liquid level . /
2> marked/sealed:
Liquid level
marked/sealed:
?1
-------
METHOD
SAMPLE RECOVERY DATA
/I
Plant: LZ?
>JU~ ^rtLA
'
^
Sample Date: ^faffo
Run No.: <5b -/f/i£- 2
Filter No.(s): So-ftA^' ^
Job No.: 5yy/oo S
Sample Location: Sc^^c^ D^±<*sf
Recovery Date: ^p-S/v 3-
XAD-2 Trap No.(s): 5b -/^/^- ^
Sample Recovery Person: ft/' / P&
, si*.-^*:::tt£s^f'&^?^-^'*!^ >:*••*<: •?.
; w..;.-^-- .i.^-^--^ ••.?i-/.u \-y;.>->">;-~>- -is t-7~:-> ;••.-••••••••..»:(••.•
Impingers
Final wt.
Initial wt.
Netwt
XAD'- 2
Trap
— -
- — .
1
(knockout)
/C3/.V
^3(0.0
535"-?-
y^Moislttilra
2
(100mlH2O)
(untipped)
L-M^i ^
"•M^-l
-UM->
Sa^^?^?s^|^:4
3 4 . -
(100mlH20) (knockogt)
(tipped) (untippedt
0^.3.^ 'vjLZ.Z
•^•Z5.Go Iol3.>
- b? I • 6 J - 5
SS?fSSS
Silica gel
(untipped)
"V"* -*
/T5'V. c*i g
Cfrt>£.O g
^6: - 6 g
u;"5iSlSi5KS^SfSii'S^
Train System: £ PA- M M.^T/oo it? / &'
Probe:
1V £\a<>
•5
Filter: Color- /Atf
Impinger Contents:
Silica Gel:
@Grams
CJ\ # F , ivo-r j^
^ Color -
') V,IVM % Spent- ^>
G
Condensate Observed In Front Half. f° 5 •**£-
"V'. .:.,'.vi~^i '':':-v.:;;
••^Vt'-^.'ti'.ili
Filter Container No.
P?5'';:=s:r->"' •^"'.^'O'ei',
.;-^ifV^;^, .'.v jj- •>*•'
5-5) ^/^/
XAD Module Container No.: &0
MeC
Probe (FH) & Back Half Rinse (A
H^O,
Probe -(FH) & Back Half Rinse £6
c o ve ra d: Szini p
yti.^ 'J
-•/i/f^ 3
|:Sr^^cj^*^^^^^^SSf^
leiFractians^^f-nS-i'v^y^
aeoafi^ Container No.:^>t? -/v*>-?
tifuiiniii) Container No.: S^-/*/%/-3
Impinger Contents Container No.: "Tv ~ l'^f^^-3
Impinqer Rinse (Aefflinac/MeCI2)
Container No.:
wASCWft •- ^c'SftT.'.rsr-'." •
'$. t-5;:T:ntS'"
-------
METHOD DO/0
SAMPLE RECOVERY DATA
Plant:
RunNo.rSD
Sample Date:
Filter No.(s):5V
Job No.:
Sample Location: p>
Recovery Date:
XAD-2 Trap No.(s):
Sample Recovery Person:
Impingers
XAD-2
Trap
1
(knockout)
(100mlH2O)
£ (untipped)
(100mlH2O)
(tipped)£-
4
(knockout)
(untipped)
Silica gel
(untipped)
Final wt.
Initial wt.
Net\wt.
Train System:
o / B^x i Q.' M- I ts / 7bT*6
. 8
Probe:
Filter: Color -
Loading -
Impinger Contents:
Silica'Gel: @Grams Used -
Color -
% Spent -
Condensate Observed In Front Half:
Filter Container No.
marked/sealed:
XAD Module Container No.: 5o "
marked/sealed:
Probe (FH) & Back Half Rinse (AsetocaK^ontainer No
Liquid level
marked/sealed:
Probe (FH) & Back Half Rinse Gfeiueae) Container No.:
Liquid level
marked/sealed:
Impinger Contents CQntainer No.:
a\9"
Liquid level
marked/sealed:
ci-^
Impinger Rinse (Acmane/MeC12) Container No.:
Liquid level
-------
Custody. Seal : Absent Sample Seals: Absent
Chain of Custody : Present Container. . . : Intact
Sample Tags : Absent ,
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A
Ice Chest ICE Temp 3.0 C
|TLI Number Client Sample ID Matrix)
jmR/H-CPM. Client COC ID * Location \
II
TLI Project Number 43433 j Book j|
Client: PES03 - Pacific Environmental Services j <£
1 18S(i
f' 1 1
Date Received j 09/29/97 j *vj%^ ^ forffa*
i g i
Carrier and Number | TOM MCDONALD | 7
'TO LAB'
^ate/Infit
\S~^s
I185-7-1A FBI-MM5-1 FILTERj^^Jc
I FBI MMS * COI K^X/
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| FBI-MMS * COI
|!8S-7-lC FBI-MMS-3 FH/RINSE
| FBI-MMS * • COI
»|
(18S-7-1D FBI-MM5-4 BH/RINSE
B • FBI-MMS * COI
u
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(18S-7-2A j SO-MM5-1-8 FILTER
H . SO-MM5-1 * COI
H
H185-7-2B SO-MM5-1-9 . XAD
|| SO-MM5-1 * COI
||
||!85-7-2C SO-MM5-1-10 FH/RINSE
|| I ! SO-MMS-1 * CO!
||l85-7-2E SO-MM5-1-.12 BH/RINSE
I) SO-MMS-1 * COI
H '
II
||!85-7-3A SO-MM5-2-17 FILTER
H SO-MM5-2 * COI
||!8S-7-3B SO-MM5-2-1B XAD
|| ' SO-MM5-2 * COI
•
8185-7-3C SO-MM5-2-19 FH/RINSE
|| SO-MM5-2 * COI
u
|l85-7-3D SO-MM5-2-20 CONDENSATE BOTTLE A
IJ SO-MMS-2 * COI
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B185-7-3E SO-MMS-2-21 CONDENSATE BOTTLE B
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Date/Init
ffafak.
To LAB
Date/Init
'
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£7 t*l
-------
RIANGLB LABORATORIES. INC. •- LOG IN RECORD/CHAIM OF CUSTODY*
H Custody Seal : Absent Sample Seals: Absent
fl Chain of Custody t Present Container. . . : Intact
D Sample Tags : Absent
U Sample Tag Numbers: Not Listed on Chain of Custody
H SMO Forms : N/A
TLI Project Number 43433 | Book JJ
Client: PES03 - Pacific Environmental Services j j
1 "S^
Date Received j 09/29/97 | ^Jj^^^^/ WJySt4&&~^~fage
n "• i • / i
I) Ice Chest ICE Temp 3.0 C Carrier and Number | TOM MCDONALD | 7
HTLI Number Client Sample ID Matrix] To L
jjmR/H'CPM Client COC ID * Location j Date
II 1 j->
AB | To STORAGE) To LAB
/Init | Date/Init | Date/Init
fll8S-7-4A SO-MMS-3-37 FILTER A) ^f-/ / \ ^*X-jr \
jj , so-MMB-3 • * coi \y&7e/ffl\&'rttfiki
II 1 7 J ' Jr
||l8S-7-4B SO-MM5-3-38 FILTER B| f \
D SO-MM5-3 * COI III
n i '
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H185-7-4C SO-MM5-3-39 XAD|
I) SO-MMS-3 * COI j
1
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1) ' SO-MM5-3 * COI j
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fl!85-7-4E SO-MMS-3-41 CONDENSATE|
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(I SO-MM5-3 * COI ' |
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||l85-7-5A SO-MM5-4-51 , FILTER)
1) SO-MM5-4 * COI j
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1)185-7-58 SO-MM5-4-52 XAD|
H ' SO-MM5-4' * COI |
n i i
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H18S-7-5C SO-MM5-4-S3 , FH/RINSE|
1) SO-MM5-4 • COI j
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H185-7-5D SO-MMS-4-54 CONDENSATE|
|j SO-MM5-4 * COI j j
n I
II 1
H185-7-5E SO-MM5-4-55 BH/RINSE|
H SO-MM5-4 * COI |
II 1
II 1
fll85-7-6A LAB BLANK-MM5-28 FILTER)
D NOT ON COC * COI |
Ri
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1)185-7-68 LAB BLANK-MM5-30 CH2CL2/CH3OH|
fl NOT ON COC * COI |
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H NOT ON coc * coi | feV \£S) /£//V/T?
To STORAGE
Date/Init
To LAB
Date/Init
To STORAGE
Date/Init
•
To LAB
Date/Init
1
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To STORAGE
Date/Init
'
'
DISPOSED
Date/Init
i
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jj Receiving Remarks: COC LIST A CONDENSATE FOR SO-MM5-1 BUT A CONDENSATE' WAS NOT RECEIVED. • -•
II ' ' 1
1 ' f
| Archive Remarks:
-------
PAGE 1 OF 1
I
| Project: 43433
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Client: Pacific Environmental Services (PES03)'
I Method:
Sample Information
Extraction Date: (Q__/'_/^J
II II
| | TLI / | Sample | Final
|Sample| SAMPLE ID / CLIENT |Wgt / Vo:
|* crd| / SAMPLE ID | g / ml | ml
£•
VA*>
1*1*31
A0t/32li£/J!L/£2l.{a/uty43l / / l_/_/__l
I | TLI Blank |
|000 | SBLK |
| | 18S-7-1A-D
1001 |
FBI-MM5-1
| | 18S-7-2A-C.E
1002 |
so-MMs-i-8
vrki
\\I\IM\
| | 185-7-3A-F
1003 |
SO-MM5-2-17
| | 185-7-4A-F
(004 |
SO-MM5-3-37 |
185-7-5A-E
|OOS
SO-MM5-4-51
| | 185-7-6A-C
1006 |
LAB BLANK-MM5-28
| | TLI LCS
|007 |
| | TLI LCSD
1008 |
ii
ii
i
Comments: O
txn
I
-REV 07/26/93 (PSTMF 7)--*
-------
70MM5.TXT OWL SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
21 '97 8270 MM5 PROJECT (IMPINGER INCLUDED)
SOP # STEP DESCRIPTION .
OV i-118 Prep .glassware for soxhlet extraction.-
OVfu-111 K/D front half and back'half rinses to' 1 ml.
OWL-118 Place filter and XAD into MeCl2 presoxed thimble. tf lo/Wl
0* ,-118 Add concentrated FH and BH rinses to thimble.
DLJ-128 Spike lOOOul Spike X @ 100 ug/ml into all samples.
DSP-128 Spike lOOOul BN QC CHECK @ 100 ug/ml into LCS/LCSD.
D! '.-128 Spike lOOOul A QC CHECK @ 100 ug/ml into LCS/LCSD.
0! j-118 Soxhlet extract 16 hours with CH2C12. .
OWL-111 K/D down impinger rinses, if any. 4 JIN*
OT~j-118 Pour impinger water in separatory . funnel, ^measure and
record pH and volume. A "7&V I°/16]17 V'~l
OWL-118 'Add concentrated impinger-rinses to the water. A/T .
D.^P-128 Spike lOOOul Spike W @ 100 ug/ml into all samples. \\\\/^[^f
NOTE: LCS/LCSD does not have a water fraction.
OwL-118 Extract 3 X 60 mL MeCl2. JArf' /«?//<5/^7
OWL-111 Filter the sox and impinger extracts through Na2S04 .1 |Y1I^-fov
0 [,-111 K/D the to 10 mL, l '
O..L-111 N2 to 1 ml.
OWL-111 Transfer to 1/2 cjram vial with 2 X 0.5 mL of CH2C12 rinses.
0 L-lli N2 to 1 mL.
Relinquish to LRGC/MS for analysis.
/ / S7 * ~y
-------
Dates 10/16/97 TRIANGLE LABORATORIES, INC. PRDPERC v4.00
Times 15s35 , . Wet Lab Extraction and Observations Page: 1 ^^
Projects 43433 OO
Sample Init. NaOH Adj. H2SO4 Adj.
ft crd Tt,I_Number.. Customer. Sample. Id pH. . . mL. . pH.l. mL. . . pH.2. Appearance. Color Odor... Vol. Entered.By Date Time S
000 TLI Blank SBLK 7.00 n/a n/a n/a n/a HPLC WATER COLORLESS NONE 620 SYKOROVA 10/16/97 15:34:47 F
003 185-7-3A-F SO-JM5-2-17 7.00 1.5 12.00 0.4 2.00 CLEAR WATER COLORLESS NONE 620 SYKOROVA 10/16/97 15:34:47 F
004 185-7-4A-F SO-WB-3-37 7.00 1.0 12.00 0.3 2.00 CLEAR WATER COLORLESS NONE 530 SYKOROVA 10/16/97 15:34:47 F
005 185-7-5A-E SO-MM5-4-51 7.00 0.8 12.00 0.2 2.00 CLEAR WATER COLORLESS NONE 420 SYKOROVA 10/16/97 15:34:48 F
006 185-7-6A-C LAB BLANK-MM5-28 7.00 1.5 12.00 0.5 2.00 CLEAR WATER COLORLESS NONE 440 SYKOROVA 10/16/97 15:34:48 F
-------
Date: 10/14/3?
Time I 18:28'
Sample
# crd TLI_Number.. Customer.Sample.Id
000 TLI Blank SBLK
001 185-7-1A-D FBI-MM5-1
002 185-7-2A-C.E SO-MME-1-8
003 1B5-7-3A-F SO-MM5-2-17
004 18S-7-4A-F SO-MM5-3-37
005 185-7-5A-E SO-MM5-4-51
006 185-7-6A-C LAB BLANK-MM5-28
007 TLI LCS TLI LCS
008 TLI LCSD TLI LCSD
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/POF Observations
Project: 43433
PRDPERC V4.00
Page: 1
F.
No
1
1
1
2
1
1
XAD
Color
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
Filter
WHITE
BROWN
BROWN
BROWN
LGHT BROWN
WHITE
Glass Wool PUF
WHITE
WHITE
WHITE
WHITE
WHITE
. . Odor . . .
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
Air
.. Q.No. Entered. By ...
P1039 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
LIVENGOOD
P1035 LIVENGOOD
P1035 LIVENGOOD
Date.... Time..
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
10/14 18:25 F
. S
CD
-------
>»
AV^^ -Cv>
PES03-Paciflc Environmental Services
FBI-MM5-2
Pr-o.j ©ot. : 4-3-4.33
iea-7--, B
Triangle Lator?
TLI PROJECT* Oj '•'
DATE 9/18/97
SPIKE 4.0ng USF
SPIKE lOOug TERP.-.X""
SPIKER \A/^ PRE.-.'.
PACIFIC ENV.
PES03-Pacif1c Environmental Services
SO-MM5-1-8
: 4-3-4-33
• \
DATE 9.r-.
-------
Services
r-^nq-Pacific Environmental Services
SO-MM5-2-18
Pr-ojeot.: 4-34-33
185—7—3B
TLI PROTv'* 03927
DATE 9/1* ^7
SPIKE 4.ong USF-C *
SPIKE 100ilg TERPHENY'. 014
SPIKER_J/VU_ PREP.
PACIFIC ENV.
PES03-Pacific EnvirofWentaT Services
SO-MM5-3-37
Rr-ojoot- : 4-3-4-33
1 85— 7 —4-A
PES03-Pacific Environmental Servtces
SO-MM6-3-38
R r- o © o t. : 4- 3 4- 3 3
PES03-Pacific Environmental Services
SO-MM5-3-39 ' "
Rr-cijeot: 4-34-33
-------
— s B
? Laboratories, Inc.
TLI PROJECTS 03927
DATE 9/18/97
SPIKE 4.0ng USF-C & USF-S
SPIKE 100ug TERPHENYL-D14
SPIKER 1/t*] PEEP.
PACIFIC ENV.
'J
PES03-Paclfic Environmental
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 43433
Transfer From: OWLS5 To: OMSSV
Initials. . Date Time
Released by:
Accepted by:
MILES.ID.
43433-
43433-
43433-
43433-
43433-
43433-
43433-
43433-
43433-
-000
-001
-002
-003
-004
-005
-006
-007
-008
TLI No,
Cust.Id.
TLI Blank
185-7-1A-D
185-7-2A-C,E
185-7-3A-F
185-7-4A-F
185-7-5A-E
185-7-6A-C
TLI LCS
TLI LCSD
SBLK
FBI-MM5-1
SO-MM5-1-8
SO-MM5-2-17
SO-MM5-3-37
SO-MM5-4-51
LAB BLANK-MM5-28
TLI LCS
TLI LCSD
. iditional comments or instructions:
-XfrCOC (Rev 11/01/94)--+
-------
SEMIVOLATILE GC/MS TRACKING FORM
TL-RTP Project #:
MATRIX^MMS) PUF Water Soil Other
METHOD: (^27(1) 625 CLP
ANALYTELIST: Table 2 TCLP 625 CLPfCA;
AP
CB/CP Other
CAfl / 736Z/5W
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Triangle Laboratories, Inc.
Run Log
Standards
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Triangle Laboratories, Inc.
Run Log
; Standards
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Signature
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*** Dated Signature/Initials Required
-------
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Run Log
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Standards
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Analyte
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Signature
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*'•.," " , ' «
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Project Number: 43433
Sample File: YP788
Client Project: £#gittaw;MI ,* \ x , ,
fFUE ID* li8ffiW?*'2A,-C!yB- "^'i ^ %4-^ ** '
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Naphthalene-d
Naphthalenev
2-Methylnaphthalenc /
Acenaphthene-d
2-Chloronaphthalene /"
Acenaphthylene •/
Acenaphthene
Fluorene--''
Phenanthrene-d
10
Phenanthrene •/
Anthracene y
FIuoranthene\/
Chrysene-d
Pyrene v/
Benzo(a)anthracene ^/
Chrysene v
Perylene-d /
12 /
Benzo(b)fluoranthene • /
Benzo(k)fluoranthene •/
Benzo(e)pyrene <-/ /
Benzo(a)pyrene v/
Perylene -./
Indeno(l ,2,3-cd)pyrene v'
D ibe nz(a, h) an thracene \J
Ben2»(g,h,i)perylene y/
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25.56
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0.28 J
0.94 J
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2.07 J
0.26 J
0.96 J
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1.18 J
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14.24
16.41
16.12
16.48
17.56
19.54
19.59
19.70
22.09
25-27
22.57
25.29
29.39
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-^ Sample ID: SO-MM5-1-8
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0.20 10
0.20 10
0.18 10
0.21 10
0.20 10
0.18 10
0.24 10
0.20 10
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: QuantiUtion Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below QuantiUtion Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.5
Printed: 09:55 11/13/1997
-------
^.J&'^-j 4-r£*<
^ ^ ^ . :
v s ,•> -•. ^ •; ••'
Project Number. 43433
Sample File: YP788
Method 8270A MM5
Sample ID: SO-MM5-1-8
• •. '• \f^ * ..&-F-*'- * ^-^ i *;r* - -. ^ 5 ^ "-
-^:..^.%.^:..''- 1- >-•:*> ^^ -^^v^^^^
Dilution Factor 1.00
Nitrobenzene-d
1,3,5-Trichlorobenzene-d
1,4-Dibromobenzene-d
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-dio
Terphenyl-d
77.36
76.47
80.13
82.46
82.30
102.84
102.73
82.46
90.89
9.45
11.29
11.98
12.86
15.00
18.06
19.66
22.53
22.90
1
2
2
1
3
3
4
5
5
77
76
80
82
82
103
103
82
91
Reviewed by.
DwcH /
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
I
Project Number 43433
Sample File: YP788
Method 8270A MM5
Sample ID: SO-MM5-1-8
Client Project Sagihaw, MI i
plUE IDt IS&T-^^J;^;^:
* " „ - - N^^-xv /
>-Toluidine -J
Hexachloroethane \i
1 ,2-Dibromo-3-chloropropanev
N,N-Diethylaniline /
Naphthalene-d
^M-MethylphenolV^
Nitrobenzene *J
N,N-Dimethylaniline V
sophorone •-•
o-Anisidine ^/
. ,4-Phenylenediamine>/
. ,2,4-Trichlorobenzene^
Hexachlorobutadiene-\/^
i,a,a-Trichlorotoluene v
Hydroquinone *
::; f*x -ViBSifiW
•>»*§, .^^
' ,-^- <; ^<~&t&>Yzt(£e
:---»i" \^^^?
Dilution
^-'r-v> \^^^^^«
v^;\i^^4j
IS
u
u
6.57 }
U
U
U
0.73 ]
U
8.19 BJ
U
U
U
U
U
IS
U
u
u
u
u
u
u
u
u
u
£v*£ tatiw*. ^;;;^f »«sa*asii
% .I". -. ^ s T \ ->f^ ~ s A ^O > ^ s v ^ «^ v v% '•••• s -X^X--
taetefc Wl*»8*>4^ ^^^K
i^g^^e^i^
Factor: 1.00
bt*3." ^ * ^ "x^-8^^ ' ' ;-C "Sftfeft ¥< 1^^ -' xX4^
;v; ^ ^^'^ '*t tk>*&* ?;SS^
1 10.21
1.49
0.38
9.47
0.50
1.07
0.39
10.25
0.86
10.98
1.44
0.52
1.37
1.42
0.51
2 12.76
0.76
0.52
0.50
0.44
0.91
0.72
0.83
1.35
0.64
0.76
l^8l^!i
£&^v£:':s
i^l--vVo- V,
V^-' >•;, \
^^"vv^y.
•^fStflB^^^lt -^
k^6*% "!
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Del. Limit: Detection Limit; Quan. Limit: Quantisation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
lione: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.5
Printed: 12:42 11/13/1997
-------
\ 5 ' : s s , ***°&'> ^s' I-4 -
, \ *s " "t~ ;'^-V^: '* -
Project Numben 43433
Sample File: YP788
Client Pro] ect Sagiitaw, MI ;-
mJP:1^7^^^;^
^ -A ^ $ ^ ^ ^ •• ,. X o^ ^
>.O' ^ %A N*A!i ? ^^ \ %> %* sv s% ^
%\»* ^»k. «>»'1' »* « *'»<«•». * fk
^ Pacific Bnvirqnmenial S
« ^ , f -.-. -. ' 4 •* fe ,', ••
v^.* ^^J |TiV^J;>j^
^vic«s^ ,^;k^ -'4fMl
' ' ^^ , ^SS ^ 'v '^X>.^%5
Method
4vi^ "\ "
^v% ^^. s %
*s^*"*Cf, /
\ -^v '\
8270AMlVf5
Sample ID: SO-MM5-1-8
^ 5^-^^i^w^
y^ f|*^!^|6 E^&ff^jy&
Dilution Facton
&*&&'-" ^ "'^f^- •^--^,^
S^r^fe-^ss
1.00
nnw^SI
'SH^^J
A ^ v ^^ "-X--. -. J f '•• *•*••• •> •.
ji ,^^j -!1 \' ' % ^ ^ ^ •• ^ %^ ^ s
awaiyw ^ >< __ ^^ ^v*. ^ ^ f ..
"'- ?^vj%i,^;%^
2-Chloroacetophenonc \^
Acenaphthene-d /
Hexachloroqrclopentadiene \/
2,4,6-Trichlorophenol v
2,4,5-Trichlorophenol >/
Biphenyl v/
Dimethylphthalate-/
2,4-Dinitrophenol v
4-Nicrophenol'/
2,4-Dinitrotoluene-M'
Dibenzofurany
4,6-Dinitro-2-methylphcnol^
Trifluralinv
Phcnanthrene-d
10
Di-n-butylphthalate-Y
Hexachlorobenzene \/
4-Aminobiphenyl \/'
Pentachlorophenol v
Pentachloronitrobenzene-/
4-Nitrobiphenyl v
Chrysene-d
Benzidine v^
4,4'-Methylenedianiline -^
Dimethylaminoazobenzene v
3,3'-Dimethylbenzidine ,],
S.S'-Dimethoxybenzidine^/
•'?f^ ••• '•'' -^ o A * ^ •• •• J« %^ A*%'t ••
% ^v. --C • A*"icijiiiA.?..;
U
IS 3
U
U
U
2.13 J
2.49 J
U
U
U
U
U
U
IS 4
9.59 BJ
U
U
U
U
U
IS 5
U
U
U
U
U
•x* •F\'^\ •••• % -. ^ •••• ^ * •& /? f -~ *••' %•>**• f v%x-. v
v^D^V ^ % *••%'"'' >f^Al>: T j|s 1 1<^% ' ^ f * •? %
"^* '' ^'' # * ^ **»B* A SX- ij*
..*. ~.L*.-L..^.. ^'^..'^.\-.^"^.
0.35
16.41
1.51
1.29
1.21
15.21
15.84
3.75
1.72
1.41
0.33
2.80
2.09
19.54
20.77
0.99
0.41
1.75
3.83
1.06
25.27
0.33
0.80
0.71
0.41
0.82
* -. Xs%s -t^ ' ' :
•/^-U**^*"' T<4^*^*-'' :
Sg'MiWwt JUtlOU :
f ""^S 'S " % %• S •.
<* ^tt« ^ •
10
10
10
10
10
10
25
25
10
10
25
10
10
10
10
25
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limib Quantitation Limit
IS: Internal Standard; U: Undetected; B
: Present In Blank; ): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544^5729 • Fax: (919) 544-5491
Savarv3.5
-------
Li
Project Numben 43433
Sample File: YP788
Method 8270A MM5
Sample ID: SO-MM5-1-8
Dilution Factor 1.00
i,3'-Dichlorobenzidine -^
Mcthylene bis-chloroaniline •
>is(2- E thylhexyl) p hthalate /
U
U
11.05 B
25.34
0.60
1.40
10
10
10
Reviewed by
Date H / !?>/ ^7
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
"01 Capitola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
Data ,1;ile: /chen/Y.i/10-23-97.b/YP788.d
Date * 23-OCT-1997 13:33
Instrument : Y.I
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected (uL> : 1.0
Page 9
of RTF, Inc.
Column diameter : 0,32
/chem/Y.i/10-23-97.b/YP788.d (Part 1 of 2)
0.0
11 12
Time
-------
Data fii le: /chem/Y.i/10-23-97.b/YP788.d
Date { 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-HH5-1-8
Column phase : DB-5
Volume Injected (uL> : 1.0
Triangle
of RTF, Inc.
Column diameter : 0.32
Page 10
in
5.2-.
5.0-i
4.8-i
4.6-^
4.4-j
4.2-j
4.0-.
3.2-i
^•»-
H
I
/chem/Y.i/10-23-97.b/YP788.d (Part 2 of 2)
20
23
24
25
26
27 28
Time (min.)
29
30
31
32
33
34
-------
Data File: /chem/Y.i/10-23-97.b/YP788.d
Report Date: 23-Oct-1997 14:54
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Oil Factor
Integrator
Sample Type:
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QTJANTITATION REPORT
/chem/Y.i/10-23-97.b/YP788.d
43433
23-OCT-1997 13:33 Autotune Date: 22-Oct-97 09:14:0
DD Inst ID: Y.i
SO-MM5-1-8
185-7-2A-C,E
/chem/Y.i/10-23-97.b/cclist.m
23-Oct-1997 14:39 target
23-OCT-1997 09:12 Cal File: YP783.d
4
1.000 Target Version: Target 2.20
HP RTE Compound Sublist: pah.sub
AIR
CONCENTRATIONS
Compound*
* 1 1,4-Dichlorobenzene-d4
* 2 Naphthalene-dS
* 3 Aeenaphthene-dlO
• 4 Phenanthrene-dlO
• 5 Chry««ne-dl2
* 6 Perylene-dl2
$ 7 2-Fluorophenol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 !<2-Diehlorobenzene-d4
$ 11 Nitrobenzene-d5
$ 12 l,3,5-Trichlorobenzene-d3
$ 13 l,4-Dibromobenzene-d4
$ 14 2-Fluorobiphenyl
$ 15 2,4,6-Tribromophenol
$ 16 Anthcacene-dlO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
42 Naphthalene
46 2-Methylnaphthalene
50 2-Chloronaphthalene
56 Acenaphthylene
58 Acenaphthene
65 Fluorene
73 Phenanthrene
74 Anthracene
77 Fluoranthene
78 Pyrene
83 Benzola)anthracene
84 Chrytene
86 Benzo(b)fluoranthene
QUANT SIO
MASS
152.00
136.00
164.00
188.00
240.00
264.00
Compound
99.00
Compound
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
244.00
128.00
142.00
162 .00
152.00
154.00
166.00
178.00
178.00
202.00
•59 D no
24u . uu
228.00 3
252.00
OS-COLUMN
RT (REL RT)
10.214(1.000)
12.763(1.000)
16.411(1.000)
19.537(1.000)
25.271(1.000)
29.393(1.000)
Not Detected.
9.452(0.925)
Not Detected.
Not Detected.
11.290(0.885)
11.976(0.938)
12.863(1.259)
14.997(0.914)
18.064(1.101)
19.659(1.006)
22.531(0.892)
22.898(0.906)
12.806(1.003)
14.237(1.116)
16.117(0.982)
16.476(1.004)
17.561(1.070)
19.587(1.003)
19.702(1,008)
22.567(OTSS3L1*'"
-^'l-. °ittt nirn
RESPONSE
458159
1487169
860099
1322472
1531806
2077760
1489537
1071904
989049
878330
2198028
658947
3644235
3713702
2843543
938092
630000
30926
6399
23520
69913
, 8455
[ "Tn^OJ—
l» y s \ " ^—>
59151
A f1^ O|a •
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
77.37
76.49
80.01
82.46
82.27
102.67
102.71
82.49
90.84
24.92
25.55
0.81
0.28
0.94
2.07
0.26
1.18
0.05
FINAL
( ug)
77.37
76.49
80.01
82.46
82.27
102.67
102.71
82.49
90.84
24.92
25.55
O.SKa)
0.28UQ)
0.94 (a)
2. 07 (a)
0.26UQ)
1.18UQ,
O.Ugfxl
-^1
Data Review:
Date: U
-------
Data File: /chem/Y.i/10-23-97 .b/YP788.d Page 2
Report Date: 23-Oct-1997 14:54
CONCENTRATIONS _ —
QUART SIQ OH-COLOMN FINAL
Compound* MASS RT (RKL RT) KBSPOHSK ( ng) ( ug)
87 Benzo (k) f luor»nthene 252.00 2frr»»tflT3TB1 2m 0.04 O.Otd
88 Benzo(e)pyrene Compound Hot Detected.
89 Benzo(»)pyrene 252.00 29.>81UiB«0) 57*? B7TI 0". 11 («
90 Perylene 252.00 2^-r+*Hl.UUfr) -5246 n.ii>- e • 18 (j
91 Ind»no(l,2,3-cd)pyr»n» Compound Hot D«t«et«d.
92 Dlb«nz(*,h)anthraocn* Compound Hot D«taetad.
93 B«nzo(g,h,i)p«ryl»n« Compound Hot 0«t«ot«d.
QC Flag Legend
a - Target compound detected but, guantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP788.d
Report Date: 23-Oct-1997 15:01
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Snip Info
Hisc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
REPORT
SEMI-VOLATILE QUANTITATION
/chem/Y.i/10-23-97.b/CAA/YP788.d
43433
23-OCT-97 13:33 Autotune Date:
DD Inst ID: Y.i
SO-MM5-1-8
185-7-2A-C/E
22-Oct-97 09:14:0
/chem/Y.i/10-23-97.b/tlicaa.m
23-Oct-1997 10:51
23-OCT-97
4
1.000
HP RTE
09:56
Sample Type: mm5
Cal File: YP784.d
Target Version: Target 2.20
Compound Sublist: CAAl.sub
CONCENTRATIONS
Compound*
* 1 1,4 Dichlorob*nz«n*-d4
* 2 N»phth»l«n«-d8
* 3 Ac«n»phth«n«-dlO
* 4 Ph«n»nthr«n«-dlO
* 5 Chry«*n«-dl2
* 6 P»ryl«n«-dl2
$ 7 2-Fluoroph«nol
$ 8 Phanol-d5
$ 9 2-Chloroph«nol-d4
$ 10 1,2-Dichlorob*nz«n*-d4
$ 11 Hitrob«nz«n«-dS
$ 12 l,3,5-Trichlorob.nz«n«-d3
$ 13 l,4-Dibromob«iz*n*-d4
$ 14 2-Fluorobiph«nyl
$ 15 2,4,6-Tribromoph«nol
$ IS Anthr»c«n«-dlO
$ 17 Pyr«n«-dld
$ 18 T«rph«nyl-dl4
20 n-NitroBodim«thylamin*
21 Cumana
23 Ph»nol
24 Anilin.
27 bi«-(2-Chloro«thyl)«th.r
26 Banzyl Chloride
29 l,4-Dichlorob»nz«n«
31 2-M«thylph«nol
32 3/4-ltethylphanol
33 Ac«toph«non«
34 n-Nitro«omorpholin«
35 o-Toluidin.
36 R«xachloro«thana
QUANT SIO
MASS
152
136
164
188
240
264
.00
.00
.00
.00
.00
.00
Compound
99
.00
Compound
Compound
82
185
240
172
329
188
212
244
74
94
gl
91
146
10(
105
106
.00
.00
.00
.00
.80
.00
.00
.00
.00
. 00
.00
n n
. u u
. 00
.00
.00
. 00
. 00
.00
.00
.00
Compound
10
12
16
19
25
29
Not
9
Mot
Mot
11
11
12
14
18
19
22
22
4
9
10
10
Xfl
Mot
RT (RBL RT)
.214(1.
.763(1.
.411(1.
.537(1.
.271(1.
.393(1.
000)
000)
000)
000)
000)
000)
ON-COLUKM
RESPONSE
458159
1487166
860099
1322472
1531806
2077760
(
40.
40.
40.
40.
40.
40.
ng)
00
00
00
00
00
00
FINAL
( ug)
D«t«ot«d.
.452(0.
925)
1489537
87.
77
87.77
D«t«ot«d.
D«t«ct«d.
.290(0.
.976(0.
.863(1.
.997(0.
.064(1.
.659(1.
.531(0.
.898(0.
-Ill 10
.474(0.
787 (JK
_20(l (0
.250(1.
.983(1.
yf t (1
885)
938)
259)
914)
101)
006)
892)
906)
aci>
928)
»aa>
004)
075)
O7*»
1071904
989049
878330
2198028
658947
364423S
3713698
2843543
?9«RC
98543
11151
138901
etjAi
D«t«ct«d.
71.
71.
81.
87.
115.
103.
77.
92.
A
6.
0.
8.
79
32
60
10
29
60
64
15
47
57
22
72
19
71.79
71.32
81.60
87.10
115.29
103.60
77.64
92.15
A 42.
6.57
0,72
0.72
8.19
PP
»PP
Data Review:
Date: id 1
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP788.d
Report Date: 23-Oct-1997 15:01
Page 2
CONCENTRATIONS
Compound*
37 Nitrob.nz.n.
38 H,N-Dim.thyluilin.
39 l,2-Dibromo-3-chloroprop»n.
40 I.ophoron.
41 o-Anisidin.
42 1,4-Ph.nyl.n.diamin.
43 1,2,4-Trichlorob.nz.n.
44 N«phth»l.n.
46 H.x»chlorobut»di.n.
47 N,N-Di.thyl»nilin.
48 af a, a-Trichlorotolu.n.
49 Hydroquinon.
51 2-Chloroac.toph«non.
52 H.xachlorooyclop.ntadi.n.
53 2,4,6-Trichloroph.no!
54 2,4,5-Trichloroph.no!
60 Biph.nyl
61 Dim.thylphthalat.
62 2,4-Dinitroph.nol
63 4-Nitroph.nol
64 2,4-Dinitrotolu.n.
65 Dib.nzofuran
66 Di-n-butylphthalat.
67 4,6-Dinitro-2-m.thylph.no!
68 Trifluralin
69 H*x»chlorob«nz*n*
70 4-Aminobiph»nyl
71 P«nt»chloroph«nol
72 P«ntachloronitrob«nz«n«
73 4-Nitrobiph«nyl
74 Banzidin*
75 4,4'-M»thyl«n«dianilin«
77 Dim«thylamlnoazobttnz«n«
78 3,3'-Dim«thylb«nzidin«
80 3,3'-Dim«thoxyb«nzidin»
81 3,3'-Dichlorob«nzidin«
82 M«thyl«n« bi«-ohloroanilin«
83 bi»(2-Bthylh«xyl)phthal»t*
QUANT SIO ON-COLUMN
MASS RT (RBZi RT) RSSPONSK ( ng)
Compound Not D«t*ct*d.
03 00 1,1 , noi (0. 935) ^fi?° n "*!
Compound Not D«t«etad.
180.00 13-.C34 (OiDSO) 5097 — Or4J
128.00 12.806(1.003) 938092 26.80
Compound Not D«t«ot*d.
Compound Not D«t«ct«d.
154.00 15.205(0.927) 62543 2.13
163.00 15.837(0.965) 60060 2.49
Compound Not D.t.ct.d.
n«-00 -l.fi ^c I? ti. niai ^ 19*5 n •»•»
149.00 20.773(1.063) 448996 9.59
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
149.00 25.336(1.003) 404215 11.04
FINAL
( ug)
^> f* P •*& *T
'F9^C(U
°'i0 .} F^ '•>
0.49
26.80
30i57— \ urf1 A /!/-
f-\ /fr(r
0.04 —1 '
ff 13v- p J,frtf
2.13
2.49
' 1~2*-\ P P SZ0^
0.92'
9.59 .
a*tf-
y
3 aj ^ p CL. c^^U-
11.04
-------
Data File: /che»/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected (uL> : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
Scan 1215 (12.806 min) of YP788.d
.
5.0-i
4.0-;
s j
•*™l
£2.0-i
^ 1.0-i
Oft-
•
i
•• .... ll -II --• - ll
i
1 ,,
.g T^ T i i • | i • • • | i i i • | i i i • | i . . • | • . i . | ... | .... | ... ,....,..,,,,
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
.
5.0-j
4.0-!
3 * =
£2.0-1
1.0-!
0.0-
Scan 1215 (12.806 min) of YP788.d (Subtracted)
1
. ,,'.,, ,,, . ,. |l
1 .
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
42 Naphthalene (PBM Reference Spectrum)
•
.
8.0-;
•
ro * •
< .
3 4.0-
XX "
>- "
2.0-
0 0—
ii .Hi iin. . i . i
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Scan 1215 (12.806 min) of YP788.d (2 DIFFERENCE)
100-
504
25i
S -25-;
"*-50-j
-75-1
-100-
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Mass 128.00
5.5^
5.0-i
4.5-j
4.0-j
3.5-j
S3.0-!
32.5-i
3_2.0-i
1.5-1
i.o-i
0.5-1
0 0-
ro
CM
T-H
J\j
~*A
*
LL
12.4 12.6 12.8 13.0" 13.2
Time (min.)
Mass 129.00
__. /s
6.0-5
5.0^
4.0:
? :
£ * •
"2.0-;
1.0-
0/\
5\
ro
CM
i
^<|A
s[
CM
•r-l
L
A^v,
.0 i i i i i | i i i i i i i | i i i | i i
12.4 12.6 12.8 13.0 13.2
Time (min.)
Mass 127.00
"
7.0-j
:
6.0-
•
5.0-
I4«H
^<
-3.0-5
2.0-;
.
1.0-;
0 0-
a*
ll
ro
S.
SM
1
A, J
12.4 12.6 12.8 13.0 13.2
Time (min.)
-------
Data File: /chew/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected (uL) : 1.0
46 2-Methylnaphthalene
Page 12
Column diameter : 0.32
Scan 1415 (14.237 win) of YP788.d
3.5-1
3.0-1
2.5-j
o * :
XX * •
="•1.0-:
o.s-i
OrtJ
J.L j..i 1 i,^.^L _
40 80 120
160 200 240 280 320 360
Mass/Charee
Scan 1415 (14.237 min) of YP788.d (Subtracted)
7 KJ
•J + -J ,
3.0-i
^ 2.5-j
o * :
-*1*5"
>-1.0-i
0.5-i
. Ill J,L -I.
.g t i i i , . i i | .
40 80 120
160 200 240 280 320 360
Mass/Charee
8.0-j
•
M * '
3 4.0-
XX
>- -
2.0-
On—
46 2-Meth
,1 III. nk ,J . , .
40 80 120
ulnaphthalene (PBM Reference Spectrum)
160 200 240 280 320 360
Mass/Charee
Scan 1415 (14.237 min) of YP788.d (Z DIFFERENCE)
100-
75-j
50-j
25-E
20-
o
3l»6-i
*~ 1 1-
'•
0.8:
0.4:
0 0-
I ro
\ ^
3
-
5
;
U^i/V
13.8 14.0 14.2 14.4 "14.6
Time (min.)
Mass 141.00
3.0-1
2.8-i
2.5-j
2.2-j
2.0-i
£1.8-:
< - ;
^1.2-j
0.8-i
0.5-j
0.2-1
.
13.8 14.0 14.
™
^^
*
1
I I | , 1, I | ! .
2 14.4 14.6
Time (roin.)
-------
Data File: /chew/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected : 1.0
56 Acenaphthylene
Page 14
Column diameter : 0.32
Scan 1677 (16.117 min) of YP788.d
6.0-j
5.0-1
^4.0-i
x :
1-°i
0.0J
. ......ill . , ., JiL 1... ., ,ih .
i . ..L. . ...illiifl
40 60 80 100 120 140 160 180 200
Mass/Charee
6.0-j
5 0-
iJ * V .
_4.0-j
Ss.o-i
X •
i.o-i
0.0-
Scan 1677 (16.117 nin) of YP78
8.d (Subtracted)
Ii
1 1
.1 . .llij., ......
| i i | i i l | l l i | l i l | i i i f •! ••!""( >| •!• |. 1 | i i i | i i
40 60 80 100 120 140 160 180 200
Mass/Charee
8.0:
^6 Oj
ff)
<•>
34.0-
5_
2.0-
-
0.0-
56 flcenaphthylene (PBM Reference SF
J
i ll
J ijl ., i. ,i ,|l
>ectruw)
40 60 80 100 120 140 160 180 200
Mass/Charee
Scan 1677 (16.117 min) of YP788.d (2 DIFFERENCE)
100-
75-j
50-j
25-j
**" :
«-25-j
"*-50-j
-754
100 :
"
i
i ,,U ...J.L.
I..I.....A
<\
40 60 80 100 120 140 160 180 200
Mass/Charee
Mass 152.00
1.6-i
1 4-^
i2-
.-.1.0-
|°*8"
0.4-j
0.2-!
0.0-
I
•
Li
W
JV\
i i i 1 i i i 1 i i i 1 'i r>i' | i i i"|'
15.8 16.0 16.2 ISA 16.6
Time (min.)
Mass 151.00
3.6-j
•
3.2-i
2.8-i
2.4^
**. '•
S * :
31-6-:
0.8^
0.4:
.
Of»-
ri
1 ^Q
n ^
i
J
"
* \
rH 1
A KiA
ALA /\ J 1 "i
^/V-uAvW^^Jf W^rvJ 1 *
15.8 16.0 16.2 16.4 16.6
Time (min.)
Mass 153.00
7.0q
6.0-j
5 0-
J. V
,-.4.0-1
< ;
1 S -I
1 3 *•
i 7 a
^3 0- J I 1 1 '11
-*1 i Ak
? CM » / i »
*•* «
1.0-
o o-
V U
1 1 V i / 1 . i ,i J hJ p u
v V W U m \! 1
B. , . .n . W, I! llWfJl , ,fll
15.8 16.0 16.2 16.4 16.6
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected *» ;
s-l.OH
o.s-i
0 0-
1 1 1
i l
1, H
111
IlllJIIIll, 111
40 80 120 160 200 240 280 320
Mass/Charge
360 400 440 480 520
58 ftcenaphthene (PBM Reference Spectrum)
8.0-
^6.0-
0
34.0-
,_
2.0-
0.0-
. ,
40 80 120 160 200 240 280 320
Mass/Charee
Scan 1727 (16.476 min) of YP788.d
100-g
75H
50-j
'25-i
Jt 0-|
3-25-i
*"-50-i
-75-!
100 =
1
"
j,i,v,i, , Jiii k <
1
360 400 440 480 520
(2 DIFFERENCE)
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Mass 154.00
5.5-|
5.0-j
4.5-j
4.0-j
^3.5-j
fftf n:-
S •
3 2.5-;
^~ 2»0~
1.5-i
i.o-i
n ^"^ VO
II * iCl
a -.
f
l
s „
al S
I ^ J %
\ ^ 7 § ^
lit J 1s* ^s
u 1 1 11 1 1 1 ' i '"' '
0.5-iilJ 1 liMlil.Ai/IU
0.0-3
n\ i\ mini inniivrnMyviiif
16.0 16.2 16.4 16.6 16.8
Time (min.)
Mass 153.00
4.8-;
4.4-
4.0-i
3.6-
3.2-
^2.8-i
ro
^2.4-;
32.0-i
^1.6-
0*8^
0.4-
l~rS
1 ^^
1 * °°
S r^ ft "^ l°2n
3 S Jig
7 a Pjp3
1 111 I 11 g
fl IJ 1 7 1 a
f I / I*^H ll II III
1 1 I 1 1 1 4ll rlnl 1 1 U Mr U
, u , n/1
y In ill
1(111 III) /Will 11 Flu 1 1 llr 1
16.0 16.2 16.4 16.6 16.8
Time (win.)
Mass 152.00
1 6-
* «
1.4-
1.2-
-1.0:
<*"
|0.8,
^0.6-j
0.4^
0.2:
0.0-
I-^T^'
3
"
8
"°*
?^ . »«.
1^5 ii a ^
11 In TH 7 ' "^
u L.JluV^Ai
16.0 16.2 16.4 16.6 16.8
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MH5-1-8
Column phase : DB-5
Volume Injected (uL) : 1.0
65 Fluorene
Page 16
Column diameter : 0.32
2.4-.
2.0-i
^1.6-i
Si.2-
S0<9j
.O-1
4
.
1.4-i
1
^ 1.0-
o0.8-i
-0.6-i
^0.4-i
0.2-;
f\ ft '
y.u
i
•
8.0-
6 0-
s * :
c^
^4.0-
>. :
2.0-
0 0-
t
100-
75-
50-
25-
£ 0-
S-25-
**-50-
-75-
IU4
[" r"i'^"
10
vl lli.uii
" ' ' '
(0
\ 1 .1
1 • '
to
>il jbiSiU
40
Scan 1878 (17.561 win) of YP788.d
I y 1 III
lUlluL ill lu. Ll 1 L .tL U 1 1.. > ...A • i .1. 1 L ,
80 120 160 200 240 280 320 3
Mass/Charee
Scan 1878 (17.561 win) of YP788.d (Subtracted)
|j.ll.,,,|L l.,lli 111 ,1 nil ,1 in ll ,
80 120 160 200 240 280 320 3
Mass/Charee
65 Fluorene (PBM Reference Spectrum)
1
-
1 1
LJ,, , 1 Jl
80 120 160 200 240 280 320 3
Mass/Charee
Scan 1878 (17.561 win) of YP788.d (2 DIFFERENCE)
l.J^ Ml r^S ' 5n
A "V ^l\ '•Tn k. '
17.2 17.4 17.6 17.8 18.<
Time (min.)
Mass 165.00
OD p«r
in r£"l
•^ ',
.' |[\
1 [1J S
^ H^ ™}\ ^
"• 131 ^1 *"*
JH Hi t;j '
i i} \ i j ft
VAAV^^^r!* ftlJ-i-^O'V*
'"I*'1 I1'* (' " * 1 " *" 1
17.2 17.4 17.6 17.8 18.(
Time
Mass 167.00
[~3
s
J
B S 55 £ II ^
^ S/l\] ( V
1. 1 mjju M / wL-LJ' r ]V|
1[ »| 1 if 1\*I V r 1 T
17.2 17.4 17.6 17.8 18.C
Time
-------
Data File: /chem/Y.i/'10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected : 1,0
73 Phenanthrene
Page 17
Column diameter : 0.32
Scan 2160 (19.587 min) of YP788.d
4.0-^
3.5-j
3.0-j
£2.0-=
»- 1.0-j
0.5-j
n n-3
1
ji.JLuiiulU..i..^^....jLi..
V.V | i i i | i i i | i i i | i
40 80 120 160
*
200 240 280 320 360 400 440
Mass/Charge
Scan 2160 (19.587 min) of YP788.d (Subtracted)
4.0-
3.5-1
3.0-j
-.2.5-i
£2.0-j
3 1.5-:
*- 1.0-1
0.5-j
0.0-3
i i
... .... 1 I.I IK ..... ,11.
1 ' 1' • 1 1 1 1 | ' » «• | '
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
8.0-
xx 6.0-
to
<^
*4-0'
5_
2.0:
o.o:
73 Phena
•ithrene (PBM Reference Spectrum)
, . . . 1 | 1 1 • | • • • | . • • | • • . | • . • | • • . | • •
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 2160 (19.587 min) of YP788.d (Z DIFFERENCE)
100-
75::
504
25^
S£ 0-1
« -25-'
-50-j
-75 -i
•••§••» m '•« "* • •*••* ••• •*• * -V * *
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
Mass 178.00
4.0-3
3.6-i
•
3.2-i
2.8-i
S2-0^
^1.6-j
1.2:
0.8-
0.4-i
rt 0-
l~w
u
L
1 1 s
i
\\A
\ *. A /xJ-1 , JLXV ^ A- IW-jLvWWxA^^^v
19.2 19.4 19.6 19.8" 20.0
Time (min.)
Mass 179.00
7.0-
6.0-
5.0-
xx 4.0-
<_>
x3.0-
1^^^.
s
1
-
ON
T-l
1
U n Ai
:::i i J II M
1 1 ill M IJ '"nlM \
H IIIRJl n li 1 raV ill In if I ll
A A. I 111 ill II III iFlllll Fill I II
19.2 19.4 19.6 19.8 20.0
Time (min.)
Mass 176.00
8.0T
7.0-:
6.0J
5.0-j
XX '.
ro .
3 j
*-3'°1
2.0-
1.0-=
0 0-
R
s
§
ii *
5 j
I 1 A 11 A
i A | ji M WM I An A 111
"*v • - 1 • * • 1 - • • 1 • . • J . 1 . 1 .
19.2 19.4 19.6 19.8 20.0
-------
'Data File: /chem/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected (uL> : 1.0
74 flnthracene
Page 18
Column diameter : 0.32
Scan 2176 (19.702 min) of YP788.d
:
1.2:
1.0-;
r°*8i
'x * •
^0.4^
0.2:
Oft-
«v
4
•
i
III
ilulMitf.^.'
1, , 1 i .
0 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
4.0:
^3.0-
<
32.0-
X
"1.0-
0 0-
Scan 2176 (1<
Illllllll , .1,
J.702 min) of YP788.d (Subtracted)
, 1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
74 flnthracene (PBM Reference Spectrum)
8.0-
ro
Trl 4 fi-
XX
*~2.0-
0 0-
. . . J 1 . . J J
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 2176 (19.702 min) of YP788.d (2 DIFFERENCE)
100-q
75-j
50-i
25-i
T* •
»-25-i
**-50-i
-75-i
I " I
, 1 h
JjlijiJiLiI] j , , i,k lil i
1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 178.00
4.0-1
3.6-i
-
3.2-i
2*H
-2.4-i
•*
!*-H
1*2"
0.8-.
0.4^
19
S
1 3
S
o
1 ^-"
J 1 '
.2 19.4 19.6 19.8 26.0 20.2
Time (min.)
Mass 176.00
8.0T
'-
7.0-i
6.0^
5 0*~
XX '.
^4.0-i
X ;
o#0~
.
2.0-:
•
l.O-j
0.0-
r~So
1 "^
s
CM
O
fx.
OS
•r*
\ \ 1 1
rt. rt
-------
Data File: /chem/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB-5
Volume Injected (uL) : 1.0
77 Fluoranthene
Page 11
Column diameter : 0.32
Scan 2508 (22.086 «in) of YP788.d
d
4.0-j
3.5-i
3.0-i
32.5-i
I2-°1
-1.5-i
0.5-i
0.0-3
It
J
KlUjJUub...! L ..,..„....
i, ,- •
\ i i | i i i ( ... , ... | i i i |
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2508 (22.086 min) of YP788.d (Subtracted)
4.0-=
3.5-i
3A
#o-
32.0-j
•21.5-
*~1.0-
0.5-
0.0-3
II
.
il
, a\ ..if
1 1
. n ,L Juli ..L. . li L j .,. ii —
• • • i • • • i • • • i • • • i • • • i
40 80 120 160 200 240 280 320 360 400
Mass/Charse
8.0-J
;
ff) * •
<
34.0:
>- '•
2.0-
0.0:
77 Fluoranthene (
x
t -
I (" i I T | II 17
PDM Reference Spectrum)
• • i i • i • i i i i i •• i i i . i i
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2508 (22.086 min) of YP788.d (Z DIFFERENCE)
100 -3
:
75 -j
so-i
25 -i
£
-------
Data File: /chen/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-HH5-1-8
Column phase : BB-5
Volume Injected .
2.0-
0.0-
,,->!., i « i
I ' • • i • i | i i i | ... 7
. . .j ...... .g ... | .,.,.,
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2575 (22.567 min) of YP788.d (2 DIFFERENCE)
100-
754
50-j
254
£
-------
Data File: /chen/Y.i/10-23-97.b/YP788.d
Date : 23-OCT-1997 13:33
Instrument : Y.i
Sample ID : SO-HM5-1-8
Column phase : DB-5
Volume Injected -0.5-
0.2-
_. ..i. . JU
40 80 120 160 200
«in) of YP788.d
•
ll
1
lJ|l
240 280 320 360 400
Mass/Charee
Scan 2955 (25.293 min) of YP788.d (Subtracted)
8.0-1
7.0-j
g 0-:
* :
-5.0-i
ro j
33.0-1
*"2.0-!
1.0-j
0.0-3
1
1.1 I [1, 1,1,1 .1 ll.il! l,lj 1... 1.1 I
40 80 120 160 200
il
| II 1 , . |
240 280 320 360 400
Mass/Charee
84 Chrysene (PBM Reference Spectrum)
8.0-J
xx 6.0-
ro
I4-0'
«_ :
2.0-
^
. . . i,
I
40 80 120 160 200 240 280 320 360 400
Mass/Charee
100-
75-j
50-j
25-j
fc o-f
5-25-1
** :
-50H
-75-!
Scan 2955 (25.293 min) of YP
'
1 1
ill jl. Jl llj.- * :
0.6-
04-
***
0.2-
his
1 liT *
K
uiHl J *
1
m
1
i
ii i
I i
I
1 11 (1
25.0 25.2 25.4 25.6 25.8
Time (min.)
Mass 226.00
1.0-3
0.9-
0.8-
0.7-!
^0.6-
5°
o0.5-
•^0.4-
^0.3-
0.2^
o.i-i
0.0J
5
1
i n
— ^u
R
S
ro
*
25.0 25.2 25.4 25.6 25.8
Time (min.)
Mass 229.00
1.4-
1.2-j
1.0-
ro *
xO.6-
>-
0.4-
0 2-
0 0-
1— ro
1 S
ro
CNJ
in
Of
J?
•
r
Lo
r
Ml
i ii ii
i
m
111
III
25.0 25.2 25.4 25.6 25.8
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CftfVYP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB.5-625
Volume Injected (uL) : 1.0
23 Phenol
Page 14
Column diameter : 0.32
Scan 748 (9.474 win) of YP788.d
7.0-j
6.0-
5.0-j
34.0-;
33'0'
^2.0-
1.0-
Ofi-
»u
i
111 ii > I J i
Jill h|l(i|j, ill i|l.i,,!n. 1
40 60 80
•
i 1
..l|.,i. ,.f . , . ji . v , Ik
100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 748 (9.474 min) of YP788.d (Subtracted)
7.0-
6.0-i
5.0-i
34.0-1
33.0-;
^2.0-i
i.o-i
0.0J
1 II J 1 ,
III i.lli .lit i. lii l
1 i i | i i ] i i
1
J , . 1
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
8.0-
-6.0-
s
^4.0-
XX
*~2.0-
II 1
J. lllj .J.
40 60 80
23 Phenol (PBM Reference Spectrum)
100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 748 (9.474 min) of YP788.d (2 DIFFERENCE)
100-
75-
50-
25-
£ 0-
S-25-
**-50-
-75-
i.l... ..,.11 i.l !•. -i iL . . , .t . . .. .. hi
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 94.00
7.0-
6.0-
5.0-:
-4.0-;
o
3 3.0-
5-
2.0-
1A
.0-
0 0-
9.00 9.20 9.40
— •*
o£
t f l l i | r i 1
9.60 9.80
Time (min.)
Mass 65.00
4.0-
3.6-;
3.2-i
2.8-j
2 4-
fc*" .
"^
Sl.6-i
*"l.2-i
•
0.8-;
0.4-.
0.0-
9
£
?
1
w^rW 1
.00 9.20 9.40 9.60 9.80
Time (min.)
Mass 66.00
4.8-
4.4-
4.0-
3.6-
3.2-
-2.8-
|2.4-
32.0-
=-1.6-
1.2-
0.8-
0.4-
0 0-
ft ^
1
^
U , .A.,
9.00 9.20 9.40 9.60 9.80
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CflA/YP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB.5-625
Volume Injected (uL> : 1.0
29 1,4-Dichlorobenzene
Page 18
Column diameter : 0.32
Scan 857 (10.250 min) of YP788.d
8.0-
xx 6.0-
?4 0-
XX * •
-
1
>- Jjl 1 1
2.0H, . LI II
0.0-
i
ill In i hi III i
i
10 80 120 160 200 240 280 320 31
Mass/Charee
1
V) 400 440 480 520
Scan 857 (10.250 min) of YP788.d (Subtracted)
7.0-:
6.0-j
5 0-
<•>* V .
XS 4 rt-
ro ^*v
XX
>-2.0-
1.0-
0 0-
1 1
1 1
40 80 120 160 200 240 280 320 3
Mass/Charee
8.0:
xx 6.0-
ro
^
^4.0-
XX
>-
2.o:
29 1
|
SO 400 440 480 520
,4-Dichlorobenzene (PBM Reference Spectrum)
*
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charee
100-
75-i
50-i
25-1
£ 4,0~
^ \
2.0:
1.0:
0 0-
1 c3
a
1
^
.
i
|
II
i \
s
a*
•
L
\ II
9.80 10.00 10.20 10.40 10.60
Time (min.)
Mass 148.00
3.6-d
3.2:
2.8:
2.4:
-.2 Oj
S * :
XX "
0.8:
0.4:
•
0 0-
i^- 1 ui
a Jo
* II «H 1 t I
o -^r
•<-< LO
1 °*
j 1
n
1 Jl
I
I III
1 1 ' '
9.80 10.00 10.20 10.40 10.60
Time (min.)
Mass 113.00
•
8*°1
7.0^
6.0-i
xxS.O^
S :-
X •
^3.0-i
2.0-i
i.o-i
0.0-
113
u •
a
IVJ
s
*
a
Jl III /i
1 1 ' * ' i ' ' '
U)
a*
\ ?
l|n A f
. i * 1 1 1 < 1 1 1
9.80 10.00 10.20 10.40 10.60
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/Cf)A/YP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-HM5-1-8
Column phase : DB.5-625
Volume Injected (uL> : 1.0
33 flcetophenone
Page 21
Column diameter : 0.32
7.0-j
6.0-j
5.0-J
XX
£4.0-!
33.0-J
XX .
=-2.0-1
i.o-i
1
40
7.0-j
6.0-j
^5.0-j
S4*°"i
33.0-i
>-2.0-:
1.0-i
J
40
•
8.0-J
^4.0-
XX H
>- I
2.0-
0.0:
1
40
100-
75-j
50-1
25-j
£ oi
** :
-50-:
-75-1
U-<
40
Scan 960 (10.983 ruin) of YP788.d
•W
_ilH.ll . . i
80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 960 (10.983 min) of YP788.d (Subtracted)
in ii
ii>. 11
l
80 120 160 200 240 280 320 360 400 440
Mass/Charee
.ji J
33 flcetophenone (PBM Reference Spectrum)
'
80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 960 (10.983 min) of YP788.d (2 DIFFERENCE)
M— f L ,
80 120 160 200 240 280 320 360 400 440
Mass/Charee
Mass 105.00
1.2-j
-
1.0-j
'
0.8:
XX
in
S0.6-
X
XX
* "
09_
«c
0.0-
\
d
N\
JVli/
I1 1 1 1 1 1 1
ro
§^
o
fo
ICO
! ^
^ ,
1 h
A ft
i i/HuILi
5
^
i/
, i i i f r r r | i
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 77.00
1.0-^
0.9-;
0.8-
0.7-;
^0.6-
o0.5-
-o^-i
*"o.3-i
0.2-
A J
I~S
^ P
8 B
O |
" 4
K)
s
O
*"*
ft
I.
*"* J 1
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 120.00
1.6-^
1.4-
:
!«2~
~ i.o-l
<*
!°-81
^0.6-j
0.4-^
•
0.2-
0 0-
.
J
1
,-i
-
ffi
s
7
g
e I-
-------
Data File: /chem/Y.i/10-23-97.b/CAfl/YP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB.5-625
Volume Injected : 1.0
60 Biphenyl
Page 36
Column diameter * 0.32
-
3.5-j
3.0-j
^2.5-j
o * :
0.5-!
.
ii
• »i| p|inpii
40 60
3.5-j
3.0-i
2rr •
**~
1 1.5-1
^i.o-i
0.5^
Ort-
•
ll,
,.
40 60
8.0-
:
£5
^>
-34.0-
XX
""2.0-
1 ll 1
40 60
100-
75-i
50-i
25 -i
£ _ _uyr i .. i
80 100 120 140
160 180 200 220 240 260 280
Mass/Charee
Mass 154.00
3.6H
3.2:
2.8:
2.4:
XX
0.8:
0.4:
0.0:
-if>
CM
ID
5
i
A, M i Ail A* *Mi /AuA/
14.8 15.0 15.2 15.4- 15.6
Time (min.)
Mass 152.00
6.0-
5.0:
~4.0-
<^
33.0-
*".2.0:
1.0-
1 *
a
4
\ \ CSJll
si
1
A *
I / V I AT
rs ... , .1 .i ...r. r. .v^s*/.v\/.
14.8 15.0 15.2 15.4 15.6
Time (min.)
1.2-
•
1.0-j
0.8-
*^
J ;
•^jO.6-
:0.4-
0.2-
0 0-
Mass 155.00
1
I
CM 1 1
CM
.
!3 1
I i
• 1
in ll 1
"
II |1
uA A A Al^ili » f Uf
14.8 15.0 15.2 15.4 15.6
Time (min.)
-------
Data File: A*em/Y.i/10-23-97.b/OWYP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB.5-625
Volume Injected (uL> : 1.0
61 Dimethylphthalate
Page 37
Column diameter : 0.32
3.2-!
2.8-j
2.4-j
52.0-i
^ois-i
0.4-:
Ort J
Scan 1638 (15.837 min) of YP788.d
i i 1
i hi J i j ,i il
lUlilMiiiliiUMn iLlii
^ V iitiiiiiiiii
40 80 120 16
,T. J . . ^ i , ! .
0 200 240 280 320 360 400 440 480
Mass/Charge
Scan 1638 (15.837 min) of YP788.d (Subtracted)
3.2-|
2.8-.
$2.0-!
|wj
*"0.8-j
0.4-;
0 0-
I i 1
A .,^li \ , 1.JJK .111.
.... J . . I I .
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
61 Dimethylphthalate (PBM Reference Spectrum)
8.0-
~6.0-
PO
§4.0-
>. ;
.i..li,.,
1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1638 (15.837 nin) of YP788.d (Z DIFFERENCE)
100 -:
75-i
50-1
254
•*• •
» -25-:
"-50-J
-754
100 :
•
j
^-^L^.^.-.JV.J-.I- * . . k i .
T
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 163.00
3.2:
2.8-
2.4-
SlV
***
»-i.2:
0.8:
0.4^
0.0-
1
dUta
^^"^
ro
GO
*
a
T*
iS
ft '
fvf^nuJ \jr TX, fj*.
«II«IJ"'«II>II>I«I«"
15.4 15.6 15.8 16.0 -16.2
Time (min.)
Mass 194.00
1.8-3
1.6-:
1.4:
1.2-
ffil 0_
< *
o ;
^0.6^
,
0.4-51
0.2-1
0 0 /
15.4 15.6 15.
rf>
oo
in
3
T-l
\s>
T
il
11
[fii
3 16.0 16.2
Time (min.)
4.0-;
3.6^
3.24
2.84"
^24-:
32.04
x =
^1.6-
1 2-
Mass 164.00'
\n *5
a
1 1
III L
H j 1 1 n i
°*8il Wl J \l\lr
PS.
*J9
1 It J *^
In U Ji i
ill M \t
Illf
15.4 15.6 15.8 16.0 16.2
Tine (win.)
-------
'Data File: /chem/Y.i/10-23-97.b/Cfl(VYP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB.5-625
Volume Injected : 1.0
66 Di-n-butylphthalate
Paee 41
Column diameter : 0.32
Scan 2325 (20.773 min) of YP788.d
2.4-3
2.0:
•
^1.6:
£ ;
x ;
•-0.8-
5- ;
0.4:
...III.. .1.^.1,. .!._.. Jl... . .J. -^
V*V 1 . i i 1 i i i 1 i • • 1 i i. I . • • I .
40 60 80 100 120 140
-
160 180 200 220 240 260 280
Mass/Charee
Scan 2325 (20.773 min) of YP788.d (Subtracted)
2.4-3
2.0-j
_1.6:
£l.2-i
~0.8-
>•
0.4-
0 0-
.1 .... , ,. .1. ...
40 60 80 100 120 140
| . 1 1 , 1 , 1 | I I 1 , I l| 1 | | 1 I | I , | | ,
160 180 200 220 240 260 280
Mass/Charee
66 Di-n-butylphthalate (PBM Reference Spectrum)
•
-
8.0-_
~6.0-]
<
§4.0^
,_ ;
2.0-
o.o:
1 1 .. ..II i. 1. I IL L
| . 1 I , I , I ( . . , , I , , | . . 1 | .
1 1 '
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 2325 (20.773 min) of YP788.d (Z DIFFERENCE)
100-
75-j
50 -j
25H
Q- 0~
u~ :
~-50-^
-75-i
100-
"r "
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 149.00
2.4-^
2.2-1
2.0-
1.8-i
*
in •
o 1 2"
•Sl.O-
*"0.8-
0.6-
0 4-^
v.t
0.2-
li
"~R
a
i
20.4 20.6 20.8 21.0 21.2
Time (min.)
Mass 150.00
2.0-
1.8-i
1.6-
1.4-
-1.2-
O 1 ft-
^a1*0
^0.8-
>- :
0.6:
0.4:
0.2-i
AAn/tfW/lrtAAiWY
— TO
fc
*
CM
^Vw1f^«^ NiiAf^P
^U i i | i i i | i i i | i i i | i i i | i
20.4 20.6 20.8 21.0 21.2
Time (min.)
Mass 104.00
1.0-j
0.9^
0.8-
0.7-
.jO.6-
o0.5-
X
^0.4-
'"o.s-
0.2-
0.1-
0.0-
|~fc
1 ^*
M«W
nJKftttf
20.4 20.6 20.8 21.0 21.2
Time (min.)
-------
Data File: /che«/Y.i/10-23-97.b/CAfl/YP788.d
Date : 23-OCT-97 13:33
Instrument : Y.i
Sample ID : SO-MM5-1-8
Column phase : DB.5-625
Volume Injected : 1.0
83 bis(2-Ethylhexul)phthalate
Page 48
Column diameter : 0.32
Scan 2961 (25.336 win) of YP788.d
1.4-3
1.2-j
1.0-f
£0.8-1
o
^0.6-
XX
0.2-j
0.0-:
4
ll ll
U i .JU .1. ... LrL i
0 80 120
•
1 ^ J - ||-
160 200 240 280 320 360 400
Mass/Charee
Scan 2961 (25.336 min) of YP788.d (Subtracted)
1.4-d
1.2-i
1 0-
J-.v .
£0.8-
< :
o
^0.4-i
0.2-i
0 0-
II J
1 1 Jl .......
i
40 80 120 160 200 240 280 320 360 400
Mass/Charee
8.0-i
~6.0:
34-°~
;_
2.o:
o.o-
83 bis(2-Ethy
1
|
1 l.f.l. J
. . T , 1 1 1 f 1 1
IhexyDphthalate (PBM Reference Spectrum)
\
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2961 (25.336 min) of YP788.d (2 DIFFERENCE)
100-:
75-=
50-i
251
Jt 0-1
S-25-1
"*-50-j
-75-j
-100-
'r"'T Vv -••"«-- -
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Mass 149.00
1.4-3
•
1.2-i
1.0-j
u)Q.Q-.
§0.6^
0.4^
:
0.2^
!
1
'•
':
-^^^l^-^f^
25.0 25.2 25.4 25:6 25.8
Time (min.)
Mass 167.00
•
3.6-i
3.2-;
2.8-j
2j "
.4-
^2.0-
3l.6i
0.8-;
0.4-f
0.0^
I— MD
1 ffy
II «
CM
1
1 1
.A.. ^1\ .
i*r, f'/'n ***?( i >i v^ f^».rti ff-
25.0 25.2 25.4 25.6 25.8
Time (min.)
-------
, - *v, v-^ vx *v ^v? -V-
, -. ^"% ,; - ,, *^4 f' f, ->-, p&i
" '< ' * 'X s «. s v. ', " •. v. •. -x^ <. /: v JF«
' V. i % vt ^ JV S •* S %
V f
Project Number 43433
Sample File: YP789
aiefttF^lecfe^iftMMI'';"; *
TO ID: ISSf'^-E-' j ^ J^^^V ^
i-'\' ' : '
^^&^^i
likstW*
S!-^ ;i - ]
Method 8270AMM5
Sample ID: SO-MM5-2rl7
'^J^I^^C^
" s ^r*^*.—'' i H'_t_^_;^ j ^VSf^i
- - |?at^4«3|l3?2Eea ; 10
Dilution Factor:
t^rf'r-* ""' %sv
W?, %t ,
f&Wff * ^
1.00
^»&9$««$ya
';,,,, ^*rV":
X.VK " ' ^ ,, ^
**YrajB\
% s •> ' \
* •• « v ;
^^ ** C" •? "" •? x *•
\---x\\$x-r\ ,;
' % '^ ^ ^ ^ -. ^^ %!| ^ s ^ V"^^
•. ''/..'.:•. .£ '%S •• '"• ^ $ ' ., -."^ ,"•
Naphthalenc-d
Naphthalene
2-Methylnaphdialene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)an thracene
Chrysene
Perylene-d
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e) pyrene
Benzo(a) pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
D ibe nz(a, h) an thracene
Benzo(g,h,i) perylene
? '„ " ^ ?*•!,.-• sv 5- ^^ 5
IS 2
28.20 B
22.37
IS 3
U
0.64 ]
U
0.61 }
IS 4
1.16 ]
U
1.37 ]
IS 5
1.66 ]
U
U
IS 6 High
U
U
U
U
U
U
U
U
'F; -V^
12.75
12.80
14.23
16.41
16.12
17.55
19.54
19.59
22.09
25.26
22.56
29.40
^\T«g- v^^
0.43
0.44
0.28
0.19
0.19
0.15
0.16
0.14
0.16
0.16
0.14
0.19
0.16
""•if -.^ 1 ^ ^V*- % •. ""
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
Savar v3.5
Printed: 17-70 11/13/1997
-------
Project Numben 43433
Sample File: YP789
Method 8270A MM5
Sample ID: SO-MM5-2-17
xSrirx. '•••• ^W^W
LIU***f «H %f, % 4 •ss* vv o
•j" ~
^.,,^-S ^^-^^-K- ^ -•.!• • %-
Qient
£ XtM. -CJL^ AW*?^* MT^AV«. -LV v"« •. 'vT \ ^v% \"-5.%^^x •>«
-- ,v< ' x^^j^V^^ti's '-H^x^u^
\ - -.5 •,;,,", cc.*x ^X'SA ,^\ \ ?'>iv-^i5'- x ,'
^ .. - \ - -t o "• * -" v*^ "^ ^ - i, > .% ' ^
Dilution Factor: 1.00
: ,"-^s ,^'7^ : ^ - -> '^
Phenol-d
s
Nitrobenzene-d
s
1 ,3.5-Trichlorobenzcne-d
3
1 ,4-Dibromobcnzene-d
4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
' 10
Terphenyl-d
St'Ve:
78.58
68.08
63.30
80.78
77.96
107.83
92.58
80.73
90.28
ilv'^/P
9.45
11.29
11.97
12.86
15.00
18.06
19.65
22.53
22.90
f'KS!
i
2
2
1
3
3
4
5
5
,Vt -^ ; ' ;
79
68
63
81
78
108
93
81
90
Reviewed by.
Date I/ /
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
I
A •• •• . •»
^fliL^IiSH
**{' *'V*SV%S-
^''tr '*;
Project Number 43433
Sample File: YP789
Method 8270A MM5
Sample ID: SO-MM5-2rl7
Clien
^MI;, -^feX
1
Dilution Factor: 1.00
r1"* -"• .'.' ;-fesl 'Sf^^KJ^^SSS^i^I^W
1 ,4-Dichlorobenzene-d
n-Nitrosodimethylamine
Cumene
Phenol
Aniline
bis-(2-Chloroediyl)ether
Benzyl Chloride
1 ,4-Dichlorobenzene
2-Mediylphenol
Acetophenone
n-Nitrosomorpholine
j-Toluidine
Hexachloroethane
1 ,2-Dibromo-3-chloropropane
N,N-Diethylaniltne
Naphthalene-d
3/4-Methylphenol
Nitrobenzene
N,N-Dimediylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlo robutadiene
:i,a,a-Trichlorotoluene
Hydroquinone
IS 1 10.22
U
0.56 } 8.71
35.15 9.48
U
U
U
0.82 ] 10.24
U
8.93 BJ 10.99
U
U
U
U
U
IS 2 12.75
U
U
U
U
U
U
U
U
U
U
1.50
0.50
1.07
0.39
0.86
1.44
0.52
1.37
1.43
0.51
0.76
0.52
0.50
0.44
0.92
0.73
0.83
1.36
0.64
0.77
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
Project Number 43433
Sample File: YP789
Method 8270A MM5
Sample ID: SO-MM5-2rl7
Client Project; Sqgfattr JtfE ,\ 'tl-
', ^ - -^\VS
A 1 " "^ * " , ^"V^' A " ",
(flUtt^JLYtCt1 ff v •. s \" ^ "~ *$fi ^ *• ^
/x-*-1 >^\\ - -:\
2-Chloroacetophenone
Acenaphthene-d
Hexachlorocyclopentadienc
2,4,6-TrichlorophenoI
2,4,5-Trichlorophenol
Biphenyl
D ime diylp h thalate
2,4-Dinitrophenol
4-Nitrophenol
2,4-Dinitro toluene
Dibenzofuran
4,6-Dinitro-2-methylphenol
Trifluralin
Phenanchrene-d
10
Di-n-butylphthalate
Hexachloro benzene
4- Ami nobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Benzldine
4,4'-Methylenedianiline
Dimethylaminoazo benzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
'•••.'• *v ^^..L^r^ W** *yf*»?ifj? s;
Dilution Factor: 1.00
i ' "iU *x ^i?rAr^ ""'- " »«r^- "
»0+Q wPE^ _,^ "• -• *r*«^l*4'' •• % !; % s »v 3^ jv <§;''
^^-::..\: ^;— i."v-,5
u
IS 3 16.41
U
0.39 J 14.80
U
1.22 J 15.20
1.89 J 15.84
U
U
U
U
U
U
IS 4 19.54
8.83 BJ 20.77
U
U
U
U
U
IS 5 25-26
U
U
U
U
U
V '; ' ':»*^V\
•.•.-•* V V-;;
^ '"^'r\*frT*»&. " "-" ^^ ;
'^~ y^ *<^*1S Jwtwtlt'' ^ "•"
!>?- ^i4\riv>
0.35
1.50
1.21
3.73
1.71
1.41
0.33
2.79
2.08
0.88
0.37
1.56
3.41
0.94
0.26
0.63
0.56
0.32
0.64
"-*-••* Vi^"'tT *H
•.v:..;"\, -. VjJl*****A- -JWwSwJt? :
^14'*^* v% 1
10
10
10
10
10
10
25
25
10
10
25
10
10
10
10
25
10
10
10
10
10
10
10
NA- Not Applicable; DeL Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 « Fax: (919) 544-5491
Savar v3.5
-------
Project Number: 43433 Method 8270A MM5
Sample File: YP789 Sample ID: SOMMS-2^17
Client Project: Sagina
Dilution Factor: 1.00
3,3'-Dichlorobenzidine U 0.48 10
Methylene bis-chloroaniline U 1.10 10
bis(2-Ethylhexyl)phthalate 20.27 B 2533 10
Reviewed by S=>aMr Date II / O
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 12:42 11/13/1997
-------
Data, file: /chem/Y.i/10-23-97.b/YP789.d
Date •: 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-HM5-2-17
Column phase : DB-5
Volume Injected : 1.0
triangle UbwWI*
$ RTF* too.
Column diameter : 0.32
Page 9
1.1-
/chei»/Y.i/10-23-97.b/YP789.d (Part 1 of 2)
11 12
Tine (min.>
13
14 15
17
i
18
-------
Data Rile: /chen/Y.i/10-23-97.b/YP789.d
Date } 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-HM5-2-17
Column phase : DB-5
Volume Injected (uL> : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0.32
Page 10
CO
1.1-
1.0-
0.9-
0.8-
0.7-
0.5-
0.2-
0.1-
0.0
/chem/Y.i/10-23-97.b/YP789.d (Part 2 of 2)
IT)
CM
20 21 22 23 24
25
27 28
_Time (min.)
29
30
31
32
33
34
-------
.Data File: /chem/Y.i/10-23-97.b/YP789.d
Report Date: 23-Oct-1997 15:26
Page 1
Data file
Lab. Id.
Inj Date
Operator
Sxnp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-23-97.b/YP789.d
43433
23-OCT-97 14:21 Autotune Date: 22-0ct-97
DD Inst ID: Y.i
SO-MM5-2-17
185-7-3A-F
09:14:0
/chem/Y.i/10-23-97.b/cclist.m
23-Oct-1997 15:22 target
23-OCT-1997
5
1.000
HP RTE
09:12
Sample Type: AIR
Cal File: YP783.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
Compounds
* 1 l,4-Dichlorobanzana-d4
* 2 Naphthal»ne-d8
* 3 Acanaphthana-dlO
* 4 Phenanthrana-dlO
* 5 Chryaene-dl2
* S P*rylana-dl2
$ 7 2-Fluorophanol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 1,2-Dichlorobanzana-d4
$ 11 Nitrobanzana-d5
$ 12 1.3,5-Trichlorobanzana-d3
$ 13 l,4-Dibromobanzana-d4
$ 14 2-Fluorobiphonyl
$ 15 2,4,6-Tribromophanol
$ 16 Anthraeana-dlO
$ 17 Pyrana-dlO
$ IB Tarphanyl-dl4
42 Naphthalene
46 2-Methyln.phehalene
50 2-Chloronaphthalane
56 Aeenaphthylena
58 Acanaphthana
£5 Pluorana
73 Phananthrana
74 Anthracene
77 Fluoranthana
78 Pyrane
83 Banzo(a)anthracene
84 Chrysene
86 Banzo(b)fluoranthena
QUANT SIO
MASS
152.00
136.00
164.00
188.00
240.00
264.00
112.00
99.00
132.00
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
244.00
128.00
142.00
162 . 00
152.00
154.00
166.00
178.00
178.00
202.00
202.00
228.00
228.00
252.00
ON-COLOMN
RT (REL RT)
10.216(1.000)
12.754(1.000)
16.411(1.000)
19.535(1.000)
25.261(1.000)
29.404(1.000)
8.089(0.792)
9.446(0.925)
10.216(1.000)
Hot Detected .
11.286(0.885)
11.973(0.939)
12.861(1.259)
15.000(0.914)
18.056(1.100)
19.651(1.006)
22.528(0.892)
22.896(0.906)
12.804(1.004)
14.232(1.116)
15.303 io.gaa>- —
16.116(0.982)
16.476(1.004)
^7^ 5 5 1 (i_B*M—
19.586(1.003)
19.694(1.008)
22.088(1.131)
22.564(0.893)
25.239(0.999)
2a-.aaau.663) —
la^tnm OCA\
RESPONSE
457778
1474295
864321
1484212
1946041
2631565
937
1511762
467
946009
774522
859747
2092326
694334
3685890
4618603
3588450
1051943
546689
24704
7625
43994
6508
53366
106043
5824
1911 ~~
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
0.07
78.59
0.03
68.10
63.20
80.78
77.94
107.65
92.56
80.75
90.23
28.19
22.36
T75T
0.64
0.34
iT7T — •*
1.16
0.18
1.37
1.66
«-ii
— OTIS —
FINAL
( ug)
0.07(aQR)
78.59
0.03UQR)
68.10
63.20
80.78
77.94
107.65
92.56
80.75
90.23
28.19
22.36
l.Ji(aU)-
0.64UQ) .
0.34UQ) .
• ««TT»0)"^
1.16U)
0.18 (a)
1.37 (a)
1.66UQ)
n 11 '-? — ^
Data Review:
Dats: 1.112.|^7
-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Report Date: 23-Oct-1997 15:26
Page 2
Compound*
QUANT SXG
MASS
RT (RKL RT)
CONCENTRATIONS
ON-COLTMN FINAL
RKSPONSB ( ng) ( ug)
87 Benzo(k)fluoranthene
88 Benzo(e)pyrene
89 Benzo (•)pyrene
90 Perylene
91 Indeno(1,2,3-ed)pyrene
92 Dibenz(m,h)anthracene
93 Benzo(g,h,i)perylene
QC Flag Legend
252.00
252.00
252.00
252.00
M til (n ig«) «;
14 o.oi
2A.AM-H
L.8B1) K
Lg fl 02
•\
"-
Compound Hot Detected.
Compound Not Detected.
Compound Not Detected.
a - Target compound detected but, guantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
R - Spike/Surrogate failed recovery limits.
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP789.d
Report Date: 23-Oct-1997 15:28
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
REPORT
SEMI-VOLATILE QUANTITATION
/chem/Y.i/10-23-97.b/CAA/YP789.d
43433
23-OCT-97 14:21 Autotune Date:
DD Inst ID: Y.i
SO-MM5-2-17
185-7-3A-F
22-Oct-97 09:14:0
/chem/Y.i/10-23-97.b/tlicaa.m
23-Oct-1997 10:51
23-OCT-97
5
1.000
HP RTE
09:56
Sample Type: mm5
Cal File: YP784.d
Target Version: Target 2.20
Compound Sublist: CAAl.sub
CONCENTRATIONS
Compound*
* 1 1,4 Dichlorob.nz.n.-d4
* 2 N»phth»l«n»-d8
* 3 Ac.n»phth.n.-dlO
* 4 Ph«n»nthr«n«-dlO
* 5 Chry««n«-dl2
* 6 P«ryl»n«-dl2
$ 7 2-Fluoroph«nol
$ 8 Ph«nol-dS
$ 9 2-Chloroph«nol-d4
$ 10 l,2-Dichlorob.nz.n.-d4
$ 11 Nitrob.nz.n.-d5
$ 12 l,3,5-Trichlorob.nz»n»-d3
$ 13 l,4-Dibromob.nz.n.-d4
$ 14 2-Fluorobiph.nyl
$ 15 2,4,6-Tribromoph.no!
$ 16 Anthr»c.n.-dlO
$ 17 Pyr.n.-dlO
$ 18 T.rph.nyl-dli
20 n-Nitro»odim.thyl»min.
21 Cum.n.
23 Ph.no1
24 Anilin*
27 bi.-(2-Chloro.thyl).th.r
28 Benzyl Chloride
29 1,4-Dichlorob.nz.n.
31 2-M.thylph.no1
32 3/4-M«thylph.no1
33 Ac.toph.non.
34 n-NitroBomorpholin*
35 o-Toluidin.
36 H.xachloro.than.
QUANT SIO
MASS
152
136
164
188
240
264
112
99
132
82
185
240
172
329
188
212
244
105
94
63
01
y i
146
106
108
.LUC
105
56
IOC
.00
.00
.00
.00
.00
.00
.00
.00
.00
Compound
.00
.00
.00
.00
.80
.00
.00
.00
. 00
.00
.00
Compound
.00
nn
. uu
.00
.00
nn
. uu
.00
. 00
. 00
Compound
10
12
16
19
25
29
8
9
10
Not
11
11
12
15
18
19
22
22
8
9
Not
^
10
10
Not
RT (RBI. RT)
.216(1
.754(1
.411(1
.535(1
.261(1
.404(1
.089(0
.446(0
.216(1
D.t.c
.286(0
.973(0
.861(1
.000(0
.056(1
.651(1
.528(0
.896(0
.713(0
.475(0
.000)
.000)
.000)
.000)
.000)
.000)
.792)
.925)
.000)
t.d.
.885)
.939)
.259)
.914)
.100)
.006)
.892)
.906)
.853)
.927)
ON-COLDMN
RES PONS B
457778
1474295
864321
1484212
1946041
2631565
937
1511762
467
946009
774522
859747
2092326
694334
3687417
4618603
3588450
14645
526594
(
40
40
40
40
40
40
0
89
0
63
56
79
82
120
93
76
91
0
35
ng)
.00
.00
.00
.00
.00
.00
.07
.15
.02
.91
.34
.94
.51
.88
.40
.00
.54
.55
.14
FINAL
(
0
89
0
63
56
79
82
120
93
76
91
0
35
ug)
.07
.15
.02
.91
.34
.94
.51
.88
.40
.00
.54
.55
.14
D.t.c t*d.
,781 (tt
.244(1
.986(1
357)
.003)
.075)
5171
12592
151270
.
0
8
D.t.ct.d.
57
.82
.93
a
0
8
c.,
/
.82
'"V
.93
Data Review:
Dats: n
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP789.d
Report Date: 23-Oct-1997 15:28
Page 2
CONCENTRATIONS
Compound*
37 Nitrobenzene
38 N, It-Dime thy laniline
39 1, 2-Dibromo-3-chloropropane
4 0 Isophoron.
41 o-Anicidine
42 1,4-Phanyl.nediamine
43 1,2,4-Trichlorob.nz.n.
44 Naphthalene
46 Hexachlorobutadi.ne
47 N,N-Di.thylanilin.
48 a, a, a-Trichlorotoluene
49 Hydroquinon.
51 2-Chloroacetophenone
52 Hexaohlorocyclopentadiene
53 2,4.6-Trichlorophenol
54 2,4,5-Trichloroph.no!
£0 Biphenyl
61 Dimethylphthalate
62 2,4-Dinitrophenol
S3 4-Nitroph«nol
£4 2,4-Dinitrotoluene
€5 Dibenzofuran
66 Di-n-butylphthalate
67 4,6-Dinitro-2-m.thylph.nol
68 Trifluralin
69 Hexachlorobenzene
70 4-Aminobiphenyl
71 Pentachlorophenol
72 Pentachloronitrobenzene
73 4-Nitrobiph.nyl
74 Benzidine
75 4,4'-Methylenedianiline
77 Dim«thylaminoazob«nz«n«
78 3,3'-Dim»thylb«nzidin«
80 3,3'-Dim«thoxyb«nzidin«
81 3,3'-Dichlorob«nzidin«
82 Mathylcn* bi»-chloroanilin»
83 bi.(2-Ethylh«xyl)phthalat«
QUANT SIS ON- COLUMN
MASS RT (RSL RT) RBSPONSB ( ng)
Compound Not Detected.
Compound Not Detected.
180.00 ll.aJMO.99i) W7W2 — 1.23
128.00 12.804(1.004) 1051943 30.32
Compound Not Detected.
Compound Not Detected.
196.00 14.799(0.902) 3068 0.39
196.00 14.799(0.902) 3068 atK
154.00 15.202(0.926) 35873 1.21
163.00 15.835(0.965) 45791 1.89
1R4 nn 1.C 716(1.020) IQB-? n 1^
165.00 Id 099 (1.984) '0361 Lib
149.00 20.769(1.063) 464077 8.83
198.00 17,731(1.080) «" n •"»
Compound Not Detected.
283.80 19.016(0.973) .. m£S s^-aa
169.00 •"».], flijtn^ftM 3TO7 OTM
Compound Not Detected.
Compound Not Detected.
152.00 20.105(3 "5.9 o.aa
212.00 23 . 877 (0 i»43) TH 0.02
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
149.00 25.333(1.003) 941724 20.26
FINAL
( ug)
-•••V y. pJ^LfT"
_^^ -fp^
S-PJ*
30.32
•\ PM+
- ™'
0.39 j
1.21
1.89
\
1*" \ PP -fc'w
I'll/
8.83
0 ly/ '
, .,\
i-"> \
n ?s \ ff D 9~£lA
(rr2S^ ] V rJyu
J-"s y
HJ-.UJ /
20.26
-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Date : 23-KT-97 14:21
Instrument : Y.i
Sample ID ; SO-MM5-2-17
Column phase : DB-5
Volume Injected '•
o3.0-
x •
^2*°~
1.0-i
.
•
8.0:
~6.0-
tf>
<
^4.0-
>- I
2.0-
0 0-
100-
75i
50-:
25-1
£ H
= -25-:
^-504
-75-f
f ,« » J
tO 80 120
Scan
. /^ -,, ./
40 80 120
1 t ^ • I
40 80 120
Scan
V » *t» Wl "" *T ** "•
40 80 12C
Scan 1214 (12.804 min) of YP789.d
-
160 200 240 280 320 360 400 440
Mass/Charee
1214 (12.804 min) of YP789.d (Subtracted)
160 200 240 280 320 360 400 440
Mass/Charee
42 Naphthalene (PBM Reference Spectrum)
%
160 200 240 280 320 360 400 440
Mass/Charee
L214 (12.804 nin) of YP789.d w«w \\tfJ \y *\_
12.4 12.6 12.8 13.0 13.2
Tine (min.)
Mass 127.00
^A^vAN
12.4 12.6 12.8 13.0 13.2
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB-5
Volume Injected (uL> : 1.0
46 2-Methylnaphthalene
Page 12
Column diameter : 0.32
Scan 1413 (14.232 min) of YP789.d
3.2-3
2.8-^
2.4-j
s2*°i
3i.2-i
=~0.8-i
0.4-i
0.0-3
. ll (I., i 1 .III III Ilil .ilill - .- .It.. - . 1
40 60 80 100
*
120 140 160 180 200
Mass/Charee
Scan 1413 (14.232 min)
3.2-
2.8-f
2A\
£l.6-i
1-1 '•
"- 0.8-i
0.4-;
ft ft-
1 II. . .ll.. ,1 .1.. ..1 1 1
U.U | i i i | i i • | i i i | i •
40 60 80 100
of YP789.d (Subtracted)
120 140 160 180 200
Mass/Charee
46 2-Methulnaphthalene (PBM Reference Spectrum)
.
8.0:
S6*0^
0 •
34.0-
J_
2.0-1
^
ll II 1 ll. II ll,, 1.1 . 1
40 60 80 100
120 140 160 180 200
Mass/Charee
Scan 1413 (14.232 min) of YP789.d (Z DIFFERENCE)
100-:
75-j
50-j
25-j
£ 0-!
S-25-j
**-5o4
-75-j
— iflfl-
•II ' !•" | •!»"• I*1 -Mil • ••*•"• -'•
40 60 80 100
120 140 160 180 200
Mass/Charee
Mass 142.00
3.2-]
-
2.8-
2.4-J
s2-°i
ol.6-
•3 :
^1.2-
0.8-
0.4:
0 0-
1
•g
^
T-l
o
1
1
13.8 14.0 14.2 14.4 "14.6
Time (min.)
Mass 141.00
2.8JJ
2.5-j
2.2-i
2.0-i
1O •
.8-
Lf) 1 ^~
sx !
s-l.OH
0.8-i
0.2-=
0.0^
Ho
5
II ?
__
3
;
\j. i/ Vi
1 'r i 1 i T i i i i
13.8 14.0 14.2 14.4 14.6
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB-5
Volume Injected
£3.0-:
-2.0-
1.0-i
0.0
Scan 1675 (16.116 win) of YP789.d
Jjlll, liLlrjIllLLllllllin.^!.!.....!!,. ,,,,1,1 lll.l
1 III)
p., . ll..|.iii|llll|ll.l.i.... . ..,.,. .
40 60 80 100 120 140
Mass/Charge
160
180 200
Scan 1675 (16.116 min) of YP789.d (Subtracted)
5.0-1
4.0-i
» I
^2.0^
l.Or
0.0-
i
40
Ik .nllll . li
^^^~^^^^T 1 I
60 80 100 120 140
Mass/Charge
160
180
200
56 ftcenaphthylene (PBM Reference Spectrum)
8.0-
2.0-
0.0-
40
60
80
100 120 140
Mass/Charge
160
180
200
lOOq
Scan 1675 (16.116 win) of YP789.d (2 DIFFERENCE)
«-25-
"-50,
-75-
40 60 80 100 120 140 160 180
Mass/Charge
200
220
220
220
., . .1. .1.11. ..Jll. .,11 ....III... •.»•
1 . . 1. . ,
L
220
Mass 152.00
15.80 16.00 16.20 16;40 16.60
Time (min.)
Mass 151.00
15.80 16.00 16.20 16.40 16.60
Time (min.)
Mass 153.00
15.80 16.00 16.20 16.40 16.6(
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Bate : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-HM5-2-17
Column phase : DB-5
Volume Injected : 1.0
65 Fluorene
Page 16
Column diameter : 0.32
1.2-
1.0-i
-
0.8-j
|o.6-i
*•
0.2-
8*0~
xx 6.0-
ro
O|
^f 4 0"*
XX
>- "
2.0-
100-
75-
50-
25-
£ o-
"-50-
-75-
*,«•
f i1^11"
10
,l ^
10
. I J
40
J „
40
Scan 1874 (17.551 min) of YP789.d
1 1
i
i.,LJ , Ln . L i i J.
80 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 1874 (17.551 min) of YP789.d (Subtracted)
1
i 1 I
80 120 160 200 240 280 320 360 400 440
Mass/Charge
65 Fluorene (PBM Reference Spectrum)
' '\ ' \
80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 1874 (17.551 min) of YP789.d (Z DIFFERENCE)
i
Lr-,-...TL.^ l .... 1 ... I . i . .
80 120 160 200 240 280 320 360 400 440
Mass/Charee
2.2-
2.0-j
1.8-i
1.6-i
1.4-i
51.2-!
o '
x ^* ~
^o.s-;
0.6-i
0.4-;
0.2-:
ft 0 '
v.u
2.8-j
2.5-1
2.2^
2. OH
1Q •
.8-
^15-
s^ -L + sJ .
3J1.2-:
^1.0-j
0.8-j
0.5-i
0.2-;
2.5-1
2.2^
2.0-
1.8-j
xx 1.5-
i1^
X '•
0.8-i
0.5-
0.2-
*v
Mass 166.00
^?
^-t;
•
-------
Data File: /chen/Y.i/10-23-97.b/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB-5
Volume Injected (uL) : 1.0
73 Phenanthrene
Page 17
Column diameter : 0.32
2.4-i
2.0-:
-1.6-i
I1-2"
0.
0.4:
0.0-
2.4-j
2.0-i
0.4-i
0.0-
8.0:
xx 6.0-
0.0-
100-
75-j
50-i
25-i
S-25-j
-75-i
-100-^r
Scan 2156 (19.586 rain) of YP789.d
jl.l.lllll.,.1 |J.I|i l.[lil.liil| ill[41. n..[i.if, [il.i[l.i ^iil,..!.!. .jM.!..!!!,,,.^!..
I I
. i. t\\\\\\\ li.iiin.iL . .in . i. ..
r ^ I i |f . , , , , - r y
40 60 80 100 120 140 160 180 200 220
Mass/Charge
Scan 2156 (19.586 min) of YP789.d (Subtracted)
•+•
-t-
J»-
40 60 80 100 120 140 160 180 200 220
Mass/Charee
73 Phenanthrene (PBM Reference Spectrum)
.,
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Scan 2156 (19.586 min) of YP789.d (2 DIFFERENCE)
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Mass 178.00
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 179.00
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 176.00
19.20 19.40 19.60 19.80 20.00
-------
Data Filet /chem/Y.i/10-23-97.b/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB-5
Volume Injected (uL) : 1.0
77 Fluoranthene
Page 19
Column diameter : 0.32
Scan 2503 (22.088 min) of YP789.d
a
3.54
3.0-1
2.5-!
xx ;
Sl.SJ
0.5-j
ll 1
.
iJJJuLli,a,u,l,. i
L. ... i i . *
11 ' i ' ' ' i ' ' f i ' ' ' i ' ' '
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 2503 (22.088 min) of YP789.d (Subtracted)
3.5-j
3«0~
^2.5-j
o :
-21-5":
5— 1 ft —
' :
1
i
...Uli.il.iL . , i..,..L
ii. i i . i
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
77 Fluoranthene (PBM Reference Spectrum)
8.0:
•
g6*0'
I4-0:
>.
2.0:
•
0.0-
i ' 1
i \\ 1
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 2503 (22.088 min) of YP789.d (2 DIFFERENCE)
100-g
75-j
50-1
25-1
«-25:
**-5o4
-75-1
-100-
I
i Jl L
>l» L. J • i L.f it i*** ». u,t i* .1 L, . i k . i ., « . 1. >b. I'lir* ' ' *• • i i
i
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 202.00
6.0-j
5.54
5.04
4.5-1
4.0-!
?S
32.5-i
>-2.0-j
1.51
1.0-1
0.5-j
0.0-
§
a
i'
J
i • • i \ * * '
21.60 21.80 22.00 22.20 22.40
Time (min.)
Mass 101.00
1.1-i
i.o-i
•
0.9-i
0.8-^
^0.7-1
O * :
30.5-:
0.3-j
0.2-j
°'11
0 0-
co n
8.
S
i 1
j
i i
1 lA
, 1, A / " V J
rfV SI
21.60 21.80 22.00 22.20 22.40
Time (min.)
Mass 100.00
3 2-
•3 + £.
2.8-
2.4-;
~2.0-
J*
|1.6-
0.8-
0 4-
v.t
0 0-
i
\
2 1
CM
J 1 II
„ . A A AA/ \AA I VW*^*-V* f^fr
21.60 21.80 22.00 22.20 22.40
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB-5
Volume Injected (uL> : 1.0
78 Pyrene
Page 20
Column diameter : 0.32
6.0-:
5.0-!
4.0-i
XX
23.0^
:^
1.0-
L
.0 1 '
40
5.0-i
4.0-i
XX I
1.0-j
n n-
uL^i
y.u— i i
40
8.0:
£5 * •
>*» "
>- ".
2.0-
"PVtJ
80
Scan 2569 (22
L^J-fUj
.564 min) of YP789.d
Jil. • i L
120 160 200 240 280 320 360 400
Mass/Charee
Scan 2569 (22.564 mi
1 ' T '"^
80
40
100-
75-
50-
25-
{£ 0-
3-25-
"*-50-
-75-
-100-
.Bi..»
40
80
n) of YP789.d (Subtracted)
'J -i • — .. . i.
120 160 200 240 280 320 360 400
Mass/Charee
78 Pyrene (P
BM Reference Spectrum)
120 160 200 240 280 320 360 400
Mass/Charee
Scan 2569 (22.564 win) of YP789.d (Z DIFFERENCE)
80
120 160 200 240 280 320 360 400
Mass/Charee
6.0-
5.5-j
5.0-i
4.5-i
4.0-i
=-2.0-=
1.5-j
1.0-j
0.5-1
0.0J
1.0-i
0.9^
^0.7-
?0.6-
30.5^
^0.4-
0.3-1
0.2-i
"i
!
I
3.2-i
2.8-
2.4-
|1.6-
0.8-
0.4-
0 0-
/
Mass 202
.00
~*
Si
^
•
L.A^
VY'ir'rv1T''u^TT ! r'l-f-VT i-T-]-f
22.20 22.40 22.60 22.80 23.00
Time (min.)
Mass 101
\k
sl
.00
?i
CM
CO
GO
8S
MIWM
22.20 22.40 22.60 22.80 23.00
Time (min.)
Mass 100
j
J
V^jw\Aw~M|/^yVf
.00
—CO
&
a
§
LJl,
22.20 22.40 22.60 22.80 23.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected (uL> : 1.0
21 Cumene
Page 13
Column diameter : 0.32
Scan 641 (8.713 min) of YP789.d
2.0-j
1.8-j
1.5-i
Si!o-i
3o.8-|
^0.5-j
0.2-!
.u
| ,
III 1
40
1.8-j
1.5-j
1.2-j
?1.0-=
f o.8-i
>-0.5-i
0.2-i
.v-" i
40
,ll
||
1 .1
III II
1
1, 1 1 III
1 ill
1 1 1 1 Illj , ,
I |
1
Mil
•
II ,
60 80 100 120
Mass/Charee
1,
III
Sc
i i. [|
an 641 (8.713 min) of YP789.d
ll
,,
1 II
1
. 1 1
60 80 100 i:
Il ,
>0
1
i| 1.
140 160 180
(Subtracted)
i . i i
140 160 180
Mass/Charee
21 Cumene (PBM Reference
8.0-
^.6.0-
ro
^
-34.0-
XX
>-
2.0-
Ort- »
1 . 1
40
|§
'
.. .1 . .Ill 1
|
i
60 80 100 120
Spectrum)
140 160 180
Mass/Charee
Scan 641 (8.713 min) of YP789.d
100-q
75H
50-1
25-i
. I
"-25-J
-50-
-75 -i
Ml
40
1 1 ll
1.
1
,
[
,. k
60 80 100 120
(2 DIFFERENCE)
.* i i i
140 160 180
Mass/Charee
Mass 105.00
9.0-:
s.o-i
:
7.0H
6.0-j
mS.O-i
o ;
£ ' :
=~3.0-i
2.0-i
o'll
—TO
*
CO
• i * \ * ' * i ' * ' i
8.4 8.6 8.8 7.0 9.2
Time (min.)
Mass 120.00
4.4-q
4.0-i
3.6-
3.2-;
2.8-i
2 *
3^]
1.2-
0.8-1
0.4-
0 0-
TH
CO
1
1
1
1
i
n
II III
I
fl
n
8.4 8.6 8.8 9.0 9.2
Time (min.)
Mass 77.00
1.6-
1.4-
1.2-i
xvl.O-i
r ;
•^0.8-
"* - ,j
0.4-i
\
\ ro
1 I ^
"
\ k
o 2-4 \ i A u IL« k 1 1 k i
T \fi Jt A.1I I I n ITI fv 1 II J 1
8.4 8.6 8.8 9.0 9.2
Time (rain.)
-------
Data File: /cheni/Y.i/10-23-97.b/Cflft/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected (uL) : 1.0
23 Phenol
Page 14
Column diameter : 0.32
Scan 748 (9.475 min) of YP789.d
3.54]
3.0-j
2.5-j
£2.04
3 :
^1.0-1
0.5-j
i
1
I
iil,i.,.i.i.l ,iill,...,.,.
40 60 80
*
•
J - *
100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 748 (9.475 min) of YP789.d (Subtracted)
3 5-^
3.0-j
2.5-i
g2.0;
gi.5H
>-1.0-;
0.5-
0 0-3
J
i
.. ,,!.!. .lllL,.,. .
V.U • • | . i . | i .
40 60 80
I1 - '
100 120 140 160 180 200 220 240 260 280
Mass/Charee
•
8.0-
£6'°:
§4.0-1
;_
2.0-
0 0-
I |
iilLjji, .1 ..
40 60 80
23 Phenol (PBM Reference Spectrum)
100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 748 (9.475 min) of YP789.d (2 DIFFERENCE)
100-
754.
504
25-:
£ Q~-
S-25-j
"*-5o4
-75-:
-100 :
.ii.-..,.....,.......il........ ..L. ...i . . . „.. .
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 94.00
3.6-1
3.2-i
2.8-;
•
2.4-;
in 2.0-
o
xi.6-;
*"1.2-:
0.8-
0.4-j
0 0-
i
!^
0%
J
9.00 9.20 9.40 9.60 9.80
Time (min.)
Mass 65.00
i.o|
0.9-j
0.8-j
0.7-J
^0.6-J
If)
00.5-!
X :
-0.4-i
%.3-J
0.2-i
0.1-J
A.AJ
r>-
.J(
.U-^i — i — r— i — [— i — i — i | i i — r— | — i i i — |— i — i— i-
9.00 9.20 9.40 9.60 9.80
Time (min.)
Mass 66.00
•
1.2;
.
1.0;
~0.8-
in ;
o
30.6;
^
0.4-
0.2;
.
0 0-
'
,- *,o.
9.00 9.20 9.40 9.60 9.80
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CAfl/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected : 1.0
29 1,4-Dichlorobenrene
Page 17
Column diameter : 0.32
Scan 856 (10.244 min> of YP789.d
50 75 100 125 150 175 200 225 250 275 300
Mass/Charge
Scan 856 <10.244 rain) of YP789.d (Subtracted)
7.0-
6.0-
5.0-
4.0-
§3.0-
^2.0-
1.0-
0.0-
II
I
50 75 100 125 150 175 200 225 250 275 300
Hass/Charge
29 1,4-Dichlorobenzene (PBM Reference Spectrum)
8.0-
2.0-j
0.0-
50 75 100 125 150 175 200 225 250 275 300
Hass/Charge
100-
75-i
SO-j
251
Jt 0^
S-25-
"-50^
-75-
-100
Scan 856 (10.244 roin) of YP789.d (2 DIFFERENCE)
,1,1
50 75 100 125 150 175 200 225 250 275 300
Hass/Charge
Hass 146.00
7.0-
6.0-
5.0-
fo4.0-
33.0-
2.0-
1.0-
0.0-
9.80 10.00 10.20 10.40 -10.60
Time (min.)
Mass 148.00
9.80 10.00 10.20 10.40 10.60
Tine (min.)
Mass 113.00
8.0-i
7.0-i
6.0-j
5.0-i
2.0-
1.0-j
0
o
r-t
i
'Oj.. JI^Q.UA
9.80 10.00 10.20 10.40 10.60
Time (min.)
-------
Data File: /chem/Y. i/10-23-97.b/Cftft/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected : 1.0
33 flcetophenone
Page 20
Column diameter : 0.32
8.0-j
7.04
;
6.0-:
£4.0-=
Ss.o-i
>- -
2*0"
1.0-j
0.0-3
1
II
ll,
T '
40
8.0-=
7.0-=
6. Or
£4.0-!
rH :
•5 3. OH
^2.0-j
1.0-j
0 fl-
,,nJ
V»V | '
40
8.0-
36'0;
|4.0:
>.
2.0-
•
,i J
40
100-
75-
50-
25-
u. 0-
**-
S-25-
"-50-
-75-
....i
40
Scan 960 (10.986 Bin) of YP789.d
h i II. ,i.r... I.J.
...I. ,,l. . . ,
.
...I 1
60 80 100 120 140 160 180 200
Mass/Charee
Scan 960 (10.986 n
1
I. , ii. ..LI.. . i,j. |ll . L, n|. „ .. j
in) of YP789.d (Subtracted)
1
1 ..] ,
i i i . i i -p r '""| i .. | ... | ... | ...,...,.
60 80 100 120 140 160 180 200
Mass/Charee
33 flcetophenone (PBM Reference Spectrum)
[
,
60 80 100 120 140 160 180 200
Mass/Charee
Scan 960 (10.986 min) of YP789.d (Z DIFFERENCE)
, • ,- k ,- •-
i
1 '
60 80 100 120 140 160 180 200
Mass/Charee
Mass 105.00
1.2-J
1.0-
0.8-
XX
<
3 0.6-
X
"0.4-
OO_
*£
0.0-
§ «
o °o
*
1 S
I
0 11 •»
ro II II ^^
s II ll *^
sl - 3
fl s
1 s
H s
J r
1(11
't i
^tn /]
•n
M
—TO
ro
.
' '
^
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 77.00
1.0-1
;
0.9-:
0.8-i
0.7-;
•
** 0.6--
So 5-^
^X A A '
V0.4-
^0.3-;
0.2H
0.1-i
rs
1 CM I — TO
1 • e^
1 ^j J ro
ft _4*
s
o IJ
en Jl'
O» Jl
5 ^
S ' /I , *l
* A ll - •
si fcf
i
i
A
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 120.00
2.2-
2.0-
1.8-
1 6-
X*U
^1'4"
|l£
^0.8-
0.6-
0.4-
0.2-
0.0-
^ |~S
* P 53
o
CTv '
CO 1 I
S i S
' I
^
vA ll 1
s
ULIi
.3?
|h
In,
ft
ON
^
M ,
10.60 10.80 11.00 11.20 11.40
Time (win.)
-------
Data File: /chen/Y.i/10-23-97.b/Cfifl/'YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected -0.4-i
0.2-;
1
5
Scan 1492 (14,
1 1 1
III
i
i i
,11
ikUJij
D 75 100 125 150
799 min) of YP789.d
•
i -H -
175 200 225 250 275 300 325
Mass/Charee
Scan 1492 (14.799 min) of YP789.d (Subtracted)
2.0-:
1.8H
1.5H
ro * :
20.B-.
"0.5-i
0.2-.
1
1 1 1
1
II . Ill 1
50 75 100 125 150
175 200 225 250 275 300 325
Mass/Charee
53 2,4,6-Trichlorophenol (PBM Reference Spectrum)
-1
8.0-
tfi '
£.
£4.0:
5.
2.0:
^ 1i .1
1
i L
I
i,
!""« • 1 .11 Ill
50 75 100 125 150
4
i
175 200 225 250 275 300 325
Mass/Charee
Scan 1492 (14.799 min) of YP789.d (2 DIFFERENCE)
100-g
75 1
50-q
2H
(4. 0 —
i =
"-50-!
-75 -i
1
•f
. ,.U> .4 •„• LU • J
50 75 100 125 150
I | ii
175 200 225 250 275 300 325
Mass/Charee
Mass 196.00
2.0-i
1.8-
1.6-i
1.4-
-.1.2-:
^1.0-i
^0.8-j
0.6-
0.4-;
0.2-
0.0^
r8-
*-«
• i i i i i i i
14.4 14.6 14.8 15.0- 15.2
Time (min.)
Mass 198.00
2.4-H
2.2-
2.0-
1 fi-
1.6-
-^1.4-
ol.2-i
^51.0-
>-O.B-.
0.6-
0.4-
0.2-
0 0-
1 ,
A
1
in. . . .
"S
II
14.4 14.6 14.8 15.0 15.2
Time (ruin.)
Mass 200.00
1 1-^
i.o4
Od-3
* :
0.8^:
0.7-=
§0.5^
^0.44
0.3-=
0.2-:
0.1-=
0 0-
~Ss
^
14.4 14.6 14.8 15.0 15.2
Time (min.)
-------
Data File: /che»/Y.i/10-23-97.b/Cflfl/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sanple ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected (uL> : 1.0
60 Biphenul
Page 35
Column diameter : 0.32
Scan 1548 (15.202 min) of YP789.d
6.0-:
5.0-i
^4.0-i
i3*°^
X
~2.0-
1 0-
0>
-
1
, 1
40 60 80 100 120 140 160 180 200
Mass/Charee
Scan 1548 (15.202 min) of YP789.d (Subtracted)
2.0-
1.8--
1.5-1
~1.2-i
?1*0-^
sH *
S0.8-;
*-0.5-!
0.2-j
.
II L 1
1 i I ,i ... R i . 1 1. , . 1 1
II 1
40 60 80 100 120 140 160 180 200
Mass/Charee
60 Biphenyl (PBM Reference Spectrum)
8.0:
~6.0^
<°
I4-0:
>• '.
2.0-
0.0-
i i 1
.... |l. .11, ,,l .. ., , ,, . .,1
40 60 80 100 120 140 160 180 200
Mass/Charee
Scan 1548 (15.202 «in) of YP789.d (2 DIFFERENCE)
100-
75-
50-
25-
£ °"
X
-50-
-75-
-100-
.,!
1-
... .- .,f, i. i ...... ..L..,.. .k_r. _•.-., i,. . _.J... J. .!„.._ i.i 1 .
40 60 80 100 120 140 160 180 200
Mass/Charee
Mass 154.00
2.0-;
1.8-^
1.6-i
1.4-i
1 2~
5 * •
ol.OJ
^ :
-0.8^
0.6^
0.4-i
0.2-:
0 0-
R
|a
-«r
§ s
a
I A '
A^li (l. i
kt\ 1/UvvtJW
14.80 15.00 15.20 15.40" 15.
Time (min.)
Mass 152.00
1.2-3
:
:
l.Or
0.9-:
0.8-;
^.0.7-i
go.6^
3o.5-i
0.3^
0.2-=
0.1^
l~00
1 °^
1 Lf)
I
II
ll
J
^1 a"
All 11
1 f
V
60
, r
14.80 15.00 15.20 15.40 15.60
Time (min.)
Mass 155.00
1.1-1
1.0-j
0.9-=
0.8^
0.7-=
?0 6^
^5 * •
30.5^
0.3-E
0.2-j
o.i-:
0 0-
P
\ '
fl!
CM
0
CM
*
1 in
n ^
Jl
, 1 1
I 1 /
,.Miifl..W.VUI.
14.80 15.00 15.20 15.40 15.
Time (min.)
^
»
0
*
n
r+
60
-------
Data File: /chem/Y.i/10-23-97.b/Cflfl/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected (uL) : 1.0
1 Dimethylphthalate
Page 36
Column diameter : 0.32
Scan 1636 (15.835 min) of YP789.d
7.0-
6.0-j
5.0-j
54.0-j
I3-0-;
*^ '.
^2.0-j
1.0-j
Ort-i
„
iuu,
.
1
1 J
^Lu.iLM,
i
.^i • i i » . ... w L i
40 80 120 160 200 240 280 320 360 4<
Mass/Charee
1^ L
)0 440 480
Scan 1636 (15.835 min) of YP789.d (Subtracted)
4.0-i
.-.3.0-j
^2.0-
v :
*~1.0-
0.0-
,A.,,4
1
.1... i i. . - l.L i
L I
ii i j i ii | i i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
61 Dimethylphthalate (PBM Reference Spectrum)
8.0-
-6.0-1
I4*0:
;_
2.0-
0 0-
, J
\A i, .„
*
i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1636 (15.835 min) of YP789.d « DIFFERENCE)
100-
75-
50-
25-
J£ 0-
S-25-
"*-50-
-75-
100
^sr
i""1"*" t"" L
1
L L L
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 163.00
H
3.6-!
3.2-j
2.8-1
xx2*4^
|2.0^
Sl.6-j
*"1 9-
1»2-
0.8:
0.4H
0 0-
j
a*
1
lA I
ii j<
1 1 *~*
\A~ L i A *
^vv** y w *-i_ u/ HJ^ xw Hwx-'1
15.40 15.60 15.80 16.00 -16.20
Time (min.)
Mass 194.00
2.0-j
1.8-j
1.6-1
^'2\
S0|8j
0.6^
0<4j
0.2H
0 0-
"yM
o.o ^i i iM i 1 1 1 1 |l JMi [N 1 1 ifH'I
15.40 15.60 15.80 16.00 16.20
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/OWYP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MM5-2-17
Column phase : DB.5-625
Volume Injected : 1.0
66 Di-n-butylphthalate
Page 41
Column diameter : 0.32
Scan 2320 (20.769 min) of YP789.d
2.4-;
2.0-i
1 f>-
P * :
3 :
>• *
0 4-
v»*» .
0.0-
1
ill . lL • .,il. . i.- 1
•
rl''1!'''!'''^''!'''!'''!'''!
40 80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 2320 (20.769 min) of YP789.d (Subtracted)
2 A —
.4-;
2.0-
~1.6-
«
ol.2-
*
~0.8-
0.4-
.,.,.» , t .
.V | • • i | i . i | i i
40 80 120
160 200 240 280 320 360 400 440
Mass/Charee
66 Di-n-butylphthalate - :
0 8J
v*u .
0.5-!
0.2^
-^ ..L
VA
a
i. ..
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 150.00
2.4H
2.24
2.04
1.8-i
1.64
^1.4-j
ol.2-
^H ;
^o.s4
0.64
0.4-;
0.24
0.0"
—ON
^^
rt
0
-------
Data File: /chem/Y.i/10-23-97.b/Cflft/YP789.d
Date : 23-OCT-97 14:21
Instrument : Y.i
Sample ID : SO-MH5-2-17
Column phase : DB.5-625
Volume Injected : 1.0
83 bis(2-Ethalhexyl)phthalate
Page 50
Column diameter : 0.32
Scan 2953 (25.333 win) of YP789.d
3.2-
2.8'
2.4'
Sl.6
-1.2
0.4
0.0
Wrl-
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
Scan 2953 (25.333 rain) of YP789.d (Subtracted)
3.2
2.8
2.4
iH
.21.2
"-0.8
0.4
0.0
4U
H»-
i.
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
83 bis(2-Ethylhexul>phthalate (PBM Reference Spectrum)
8.0'
-6.0
§4.0
^2.0-
50
75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
100-
75 -I
50-j
251
: °1
'-50-i
-75-i
Scan 2953 (25.333 min) of YP789.d « DIFFERENCE)
>r "T
-100 1
50
75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
3.2-
2.8-
2.4-
0.8-
0.4-
0.0-
Mass 149.00
25.0 25.2 25.4 25-.6 25.8
Time (min.)
Mass 167.00
25.0 25.2 25.4 25.6 25.8
Time (min.)
-------
% * "^V^ £ % '% xx "^ * *
' J- k t* ^>^S)> % * ^ '.v s\-X*"S'> ^
A - ^ $*r*^' /">** < E
s •: •.-.%••% •• v.
Project Numben 43433
Sample File: YP790
Oteat Projects Sagfriaw^ MI ^* $V«
|1J ID: laWHfcNT* , -:J-: :J -C^ ^C
Vs '^i5 ^. S* % ^^ '. \,
%- *,*
\^pl^E«^ye^:^
x^.tli^j|^*^iS^|
V^§St^%Ra|^e10l|;i
Dilution Factor:
Seimces
jfc#9Sf .'
$UIBWN\
1.00
•'•V'^i'l-V:^^-'!
Method 8270A MM5
Sample ID: SO-MM5-3-37
^^ ': '.Y^i;3fffi
Naphthalene-d
Naphthalene
2-Mediylnaphthalene
Acenaphthene-d
2-Chloronaphthalenc
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
to
Phenamhrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-d
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i) perylene
•.*• "\ '' \ •. f \ s? % \
IS 2
92.27 B
136.69
IS 3
U
2.14 ]
0.94 ]
1.33 J
IS 4
1.77 J
0.34 J
0.86 J
IS 5
1.05 J
U
U
IS 6
U
U
U
U
U
U
U
U
N % ' "•
12.76
12.81
14.24
16.42
16.12
16.49
17.57
19.54
19.59
19.70
22.09
25.28
22.57
29.40
y^i&*&> v:;^f;jQtt^flia|
10
10
0.44 10
10
10
10
10
10
10
10
0.24 10
0.25 10
0.19 10
0.20 10
0.18 10
0.20 10
0.19 10
0.17 10
0.23 10
0.19 10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 09:55 11/13/1997
-------
Project Number: 43433
Sample File: YP790
Method 8270A MM5
Sample ID: SO-MM5-3-37
Dilution Factor. 1.00
\'' -, .., %- C- :',"*&&.'"-*
Phenol-d
5
Nitrobenzene-d
5
1 ,3,5-Trichlorobenzene-d
1 ,4-Dibromobenzene-d
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
7 10
Terphenyl-d
77.47
71.82
68.00
81.64
83.52
110.40
98.43
87.02
94.18
f*^:
9.46
11.30
11.98
12.86
15-00
18.07
19-66
22.53
22.90
».:yp%
1
2
2
1
3
3
4
5
5
"^ •> ^v. s^^ x ^ \ %^% s :
77
72
68
82
84
110
98
87
94
Reviewed by.
Date
/°l~?
NA- Not Applicable; Det Limih Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 09:55 11/13/1997
-------
v^ •• ' f f ^ ^>. £ ^
^ •••••• ^ ^>'- -, ' v£. *V" "vs*'X-.
•" -. X j. ^.J x* *%"\^ •• xs1- ••< -^
.: '..i v^^vaK ^ ..v..?.*
Project Number: 43433
Sample File: YP790
Method 8270 A MM5
Sample ID: SO-MM5-3r37
> \ •? i '..
<* "X "•
*• "• \ ^ \
1 ,4-Dichlorobenzene-d
n-Nitrosodimethylamine
Cumene
Phenol
Aniline
bis-(2-Chloroethyl)ether
Benzyl Chloride
1 ,4-Dichlorobenzene
2-Mediylphenol
Acetophenone
n-Nitrosomorpholine
o-Toluidine
Hexachloroethane
1 ,2-Dibromo-3-chloropropane
N,N-Diethylaniline
Naphthalene-d
3/4- Methy Iphenol
Nitrobenzene
N,N-Dimethylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlorobutadiene
a,a,a-Trichlorotoluene
Hydroquinone
I ^*fkf 7xi^^5^i^^^;^f
Dilution Factor: 1.00
•. -. f <. -. A -.y s % "? s ft^.v. -*v •.
* ** ss % % •• ^ •f- "-^ % ? A^JjJj^WtotlsJ ^ % 'rf*^nvtfi?'':' % •.'' '^''^ " v Jv* "" % x **
s% % . , X" XA%% . %. . "" C" ^ ' v% <4%'''' / "iS 'vs 'xNs'V^% ^ ''''i. ^% ^ -.
% \ •:., v^.^5 %^^^^ ^^. •. ' •. $•'&* •,•••• •C**™ •. '*^- '• $s
"• f- "" ^ *^%J "" "V ^"^ "^-f f 2"' f % ^ '\ * \ "*^ j "" "^
IS 1 10.22
U
1.56 J 8.71
11.09 9.48
0.32 J 9.56
U
2.27 J 10.20
1.28 J 10.25
2.16 J 10.66
13.55 B 10.99
U
U
U
U
U
IS 2 12.76
U
U
U
U
U
U
U
U
U
U
•,•.-, f '. v. % >*r . v. -.
\ ' •> "• •" %*•*•>• s' s
vX v •.*<• "" "* ^ '•^"•'- S / §
_. ^o^ % ^ s . r
%rv& nrfltntTT •*** '" ''•
% *^ •• / . ..
1.59
1.14
1.54
0.56
1.46
1-52
0.55
0.81
0.56
0.54
0.47
0.98
0.78
0.89
1.45
0.69
0.82
't|^|^> |
E|^|^::i
^\ v^^v <• % ^ %x •* ' "*
^^ft3^!
iO"' ""X •. . ^v :
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed 12:43 11/13/1997
-------
I
If Pacif&i
', '" *V, f' - '$ A - "*t- •• -* ,V" V "• O
».. -, '"V- i - * S$: v"\ v"-. ~5
„•. •. ,< , s .. , < ^> ^- ->X »'•%'•
, ' '}, V , x» % •• - >s
Project Number: 43433
Sample File: YP790
Method 8270A MM5
Sample ID: SO-MM5-3-37
CUeftfcPr^cfc^g^avt', MI 4< ^*
1
Dilution Factor: 1.00
f"* ' v ':';' -V:.V.
Z-Chloroacetophenonc
Acenaphthene-d
Hexachloroqfclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Biphenyl
Dimediylphthalate
2,4-Dinitrophenol
4-Nitrophenol
2,4-Dinitro toluene
Dibenzofuran
4,6-Dinitro-2-methylphenol
Trifluralin
Phenanthrene-d
10
Di-n-butylphthalate
Hexachloro benzene
4-Aminobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Bcnzidine
4,4'-Methylenedianiline
Dimediylaminoazo benzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
/;o^A*^0^^ lw ; ':^
u
IS 3 16.42
U
U
U
5.10 ] 15-21
2.23 ] 15.84
U
U
U
2.49 ] 16.85
U
U
IS 4 19.54
8.67 ft] 20.77
U
U
U
U
U
IS 5 25.28
U
U
U
U
U
H^ti
0.38
1.57
1.34
1.26
3.90
1.78
1.47
2.91
2.18
1.00
0.42
1.77
3.87
1.07
0.33
0.80
0.71
0.41
0.81
fft?^
10
10
10
10
10
10
25
25
10
10
25
10
10
10
10
25
10
10
10
10
10
10
10
NA- Not Applicable; Del Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:43 11/13/1997
-------
^
Project Number: 43433
Sample File: YP790
Method 8270A MM5
Sample ID: SO-MM5-3-37
Client Project: Sagitta%MI
r ' ' ^ ?'- ''-^
V'Days^c*e^::0$^M ;, x
; \l?ate^r^ted*l^J4^7\ ^
- Response File:
|/^K 3;
^P5^^J^
s ^,-:f
Dilution Factor: 1.00
&8*lyf«!:., x „ " ^ ^,-"\'\C\'%-\ -. % ^ % %
3,3'-Dichlorobenzidine
Methylene bis-chloro aniline
bis(2-Ethylhexyl)phthalate
A-moattt ;-•
-, ,,Vs
Tf$- -k.
21.21
••'•••••^
^t'Hi
V ^s"
U
U
B
&^ -5 " - '•- 0
r> ^^^ Sv- w \ i" „' „ ' <• s " ,
^W^" X^ ^ \ "•• v' ' '',' ^
^ * k^i-vv x ' :.* ,^'- -.^
25.34
s v •• \% > X
. s^ •••••. s ^ •••> •••• y .
^ftiawiA^y^vo
^ % ^ ;C ?_;\; ^
0.60
1.39
QU«t.UmU
*\ vO*#
•• •• ^% -. AS s ;
> X1»g ^ :
10
10
10
Reviewed by.
Date
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544r5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:43 11/13/1997
-------
Data file: /chem/Y.l/10-23-97.b/YP790.d
Date.: 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-HM5-3-37
Column phase : DB-5
Volume Injected
-------
Data,file: /chem/Y.i/10-23-97,b/YP790.d
Date .: 23-XT-97 15:09
Instrument : Y.i
Sample ID : 50-1*15-3-37
Column phase : DB-5
Volume Injected : 1.0
Page 10
Triangle
o
o
Column diameter : 0.32
6.0-
5.8-
5.6
5.4-
5.2-
s.o
4.8-
4.6-
4.4
4.2-
4.0-
3.8
3.6
2.4
2.2-
2.0-
1.8-
1.6-
1.4-
1.2-
1.0-
0.8-
0.2-
e.o
/chem/Y.i/10-23-97.b/YP790.d (Part 2 of 2)
I
fc
+
f~\
R
in
CM
CM
T-t
7
20
21
22
23
24
25
27 28
Time (min.)
29
30
31
32
T '
33
^ i '
34
-------
Data File: /chem/Y.i/10-23-97.b/YP790.d
Report Date: 24-Oct-1997 06:54
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-23-97.b/YP790.d
43433
23-OCT-97 15:09 Autotune Date: 22-Oct-97
DD Inst ID: Y.i
SO-MM5-3-37
185-7-4A-F
09:14:0
/chem/Y.i/10-23-97.b/cclist.m
24-Oct-1997 06:51 target
23-OCT-1997
6
1.000
HP RTE
09:12
Sample Type: AIR
Cal File: YP783.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
Compounds
* 1 l,4-Dichlorob«nz«n«-d«
• 2 Naphthal«n«-d8
* 3 Ac«naphth«n«-dlO
* 4 Ph«n»nthr«n«-dlO
* 5 Chry««n»-dl2
• 6 P«ryl»n»-dl2
$ 7 2-Fluoroph«nol
$ 8 Phanol-dS
$ 9 2-Chloroph«nol-d4
$ 10 l,2-Dichlorob«nz«n«-d4
$ 11 Nitrob»nz«n»-dS
$ 12 l,3,5-Trichlorob«nz«n»-d3
$ 13 l,4-Dibromob*nz«n*-d4
$ 14 2-Fluorobiph«nyl
$ 15 2,4,6-Tribromophanol
$ IS Anthrac«n«-dlO
$ 17 Pyr«n«-dlO
$ 18 T«rph«nyl-dl4
42 Naphthal«n«
46 2-M»thylnaphthal«n«
50 2-Chloronaphthal*n«
56 Ac«naphthyl«n«
58 Ac»naphth»n»
65 Fluor«n«
73 Ph«nanthr*n«
74 AntAracan*
77 Fluoranthvn*
78 Pyr*n*
83 Banzo(a) anthraon*
84 Chry««n«
86 B«nzo(b)fluoranth*n*
QUANT SIO
MASS
152.00
136.00
164.00
188.00
240.00
264.00
112.00
99.00
Compound
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
244.00
128.00
142.00
i £? no
IDA . uu
152.00
154.00
166.00
178.00
178.00
202.00
30 a on
**O • UU
•*•) g ft ft
*jfcQ • Uu
252.00
ON-COLDMN
RT (RBL RT)
10.218(1.000)
12.763(1.000)
16.421(1.000)
19.537(1.000)
25.275(1.000)
29.403(1.000)
7.316(0.716)
9.456(0.925)
Mot D*t*ct«d.
Hot D«c»ot»d.
11.296(0.885)
11.976(0.938)
12.864(1.259)
15.003(0.914)
18.066(1.100)
19.660(1.006)
22.532(0.891)
22.899(0.906)
12.807(1.003)
14.241(1.116)
16.119(0.982)
16.486(1.004)
17.568(1.070)
19.588(1.003)
19.703(1.008)
RBSPONSK
4303S4
1386516
827130
1306920
1533975
2125148
47891
1401072
938553
782541
816885
2145031
£80319
3450884
3924533
2950812
3236554
3141382
79028
20453
32030
59246
10776
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
3.77
77.48
71.84
67.90
81.65
83.49
110.22
98.42
87.05
94.13
92.23
136.64
2.14
0.94
1.33
1.77
0.34
FINAL
( ug)
3.77UQR)
77.48
71.84
67.90
81.65
83.49
110.22
98.42
87.05
94.13
92.23
136.64
2.14UQ)
0.94UQ)
1.33U)
1.77U)
0.34U)
-trot D.c.at*?'471^ laK-ef
22.568(0.893)
2*r*an) W5>
*- ~ •* ^
52969
l.OS
f
l.OS(aQ)
0..03UOV
Data Review:
Date:
-------
Data File: /chem/Y.i/10-23-97 .b/YP790.d
Report Date: 24-Oct-1997 06:54
Page 2
Compound*
QUANT 310
MASS
CONCENTRATIONS
OH-COZiQMH FINAL
KT (R1L RT) RESPOHSI ( ng) ( ug)
87 Benzo(k)£luoranthene
88 Benzole) pyrenei
89 Benzo(a)pyrene
90 Perylene
91 Indeno(1,2,3-cd)pyrene
92 Dibenz (a,h) anthracene
93 Benzo (g,h, i) perylene
QC Flag Legend
252.00
252.00
252.00
252.00
(8.9CO)
MK3
0.83
».83U)
29.258 (0.94
Uai I
THJJ/
CampouaA Hot D»t«ot»d.
Conpovmd Hot D*t*ot*d.
Compound Hot Detected.
a - Target compound detected but, quant ita ted amount
Below Limit Of Quantitation(BLOQ) .
Q - Qualifier signal failed the ratio test.
R - Spike/Surrogate failed recovery limits.
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP790.d
Report Date: 24-Oct-1997 07:04
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
REPORT
SEMI-VOLATILE QUANTITATION
/chem/Y.i/10-23-97.b/CAA/YP790.d
43433
23-OCT-97 15:09 Autotune Date:
DD Inst ID: Y.i
SO-MM5-3-37
185-7-4A-F
22-Oct-97 09:14:0
/chem/Y.i/10-23-97.b/tlicaa.m
23-Oct-1997 10:51
23-OCT-97
6
1.000
HP RTE
09:56
Sample Type: xmn5
Cal File: YP784.d
Target Version: Target 2.20
Compound Sublist: CAAl.sub
CONCENTRATIONS
Compounds
* 11,* Dichlorobenzene-d4
» 2 N»phth»lene-d8
* 3 Acen»phthene-dlO
* 4 Phenanthrene-dlO
* 5 Chry«ene-dl2
* 6 Perylene-dl2
$ 7 2-?luorophenol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 l,2-Dichlorobenzene-d4
$ 11 Nitrobenzene-dS
$ 12 l,3,S-Trichlcrobenzene-d3
$ 13 l,4-Dibromobenzene-d4
$ 14 2-Pluorobiphenyl
$ IS 2,4,6-Tribromophenol
$ 16 Anthraeene-dIO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
20 n-Nitrosodimethylaunine
21 Cumene
23 Phenol
24 Aniline
27 bi«-(2-Chloroethyl>ether
28 Benzyl Chloride
29 1,4-Dichlorobenzene
31 2-Hethylphenol
32 3/4-Methylphenol
33 Acetophenone
34 n-Nitroiomorpholine
35 o-Toluidine
36 Hexachloroethane
QUANT SIQ
MASS
152.00
136.00
164.00
188.00
240.00
264.00
112.00
99.00
Compound
Compound
82.00
185.00
240.00
172.00
329.80
188.00
212.00
244.00
1 A. O ft
1 % * U U
105.00
94.00
93.00
63.00
91.00
146.00
108.00
108.00
105.00
56.00
infi.oo
ON-COLOMN
RT (REL RT)
10.218(1.000)
12.763(1.000)
16.421(1.000)
19.537(1.000)
25.275(1.000)
29.403(1.000)
7.316(0.716)
9.456(0.925)
Not Detected.
Not Detected.
11.296(0.885)
11.976(0.938)
12.864(1.259)
15.003 (0.914)
18.066(1.100)
19.660(1.006)
22.532(0.891)
22.899(0.906)
8.715(0.853)
9.477(0.927)
9.562(0.936)
9.719 fP.9Sll
10.204(0.999)
10.247(1.003)
10.660(1.043)
10.960(0.859)
10.989(1.075)
11 rufd iii)
IB. iT4 fl.»7el
RESPONSE
430354
1386516
827130
1306920
1533975
2125148
47891
1401072
938553
782541
816885
2145031
680319
3450884
3924533
2950812
38470
156252
6042
____Z5*0— —
54497
18385
23778
1?2.1P -
215752
lift
am 01
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
4.05
87.89
67.42
60.53
80.79
88.39
123.77
99.27
81.93
95.50
1.56
11.09
0.32
2.27
1.27
2.16
13.54
*.«j — -
FINAL
( ug)
4.05
87.89
67.42
60.53
80.79
88.39
123.77
99.27
81.93
95.50
1.56
11.09
0.32
0739
2.27
1.27
2.16
13.54
a. 19
Compound Not Detected.
Data Review:
Date:
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP790.d
Report Date: 24-Oct-1997 07:04
Page 2
Compounds
QUANT SIO
MASS
RT (RKL RT)
CONCKNTRATIONS
ON-COLOMN FINAL
RKSPONSS ( ng) ( ug)
13 (47(n qsn) 15044
12.807(1.003) 3236554
Not Detected.
•La I->Q/I -.BKI 14503
99.20
IT nf«n nnn) 3tnf7t
30.23-
37 Nitrobenzene 77.00 11.333(9.889) 8.7035 3.10
38 N,H-Dimethylaniline 120.00 JJUMB (0 .882) 05919 9,83
39 l,2-Dibromo-3-chloropropane Compound Hot Detected.
40 laophorone 82.00 .IT i QH4 (0.941) lUSbb U.S1-
41 o-Anieidine Compoun'd Hot Detected.
42 1,4-Phenylenediamine 108.00 IS.C1T(1.867) m tT.Oi
43 1,2,4-Trichlorobenzene 180.00
44 Naphthalene 128.00
46 Hexachlorobutadiene Compound
47 H,N-Diethylaniline 134.00
48 a,a,a-Trichlorotoluene 159.00
49 Hydroquinone 110.00 13. 5ti II
51 2-Chloroacetophenone 105.00 13.9^6(1
52 Hexachlorocyclopentadiene Compound Hot Detected.
53 2,4,6-Trichlorophenol 196.00
54 2,4,5-Trichlorophenol 19£.00
£0 Biphenyl 154.00
£1 Dimethylphthalate 163.00
£2 2,4-Dinitrophenol 184.00
£3 4-Hitrophenol 139.00
£4 2,4-Dinitrotoluene 165.00 1_» ..ain{i n->.»\ 1134-9 l.CD-
65 Dibenzofuran 168.00 16.846(1.026) 72118 2.49
66 Di-n-butylphthalate 149.00 20.769(1.063) 401230 8.£7
£7 4,£-Dinitro-2-methylphenol 198.00 17 . S9» (1. 8T1) T?n O.U9
£8 Trifluralin Compound Not Detected.
£9 Hex&chlorobenzene 283.80
70 4-Aminobiphenyl 169.00
71 Pentachlorophenol Compound
72 Pentachloronitrobenzene Compound
73 4-Nitrobiphenyl 152.00
74 Benzidine 184.00 T7 117 (n. 9"M 1-
75 4,4'-Methylenedianiline Compound Not Detected.
77 Dimethylaminoazobenzene 120.00 12.9»t (0.90(i)
78 3,3'-DimethyIbenxidine 212.00 23.914 (B.94£)-
80 3,3'-Dimethoxybenzidine Compound Hot Detected.
81 3,3'-Dichlorobenzidine Compound Not Detected.
82 Methylene bie-chloroaniline 231.00 -85 , 3£1 10 . 9»») 1OA4 U.1H
83 bi«(2-Bthylhexyl)phthalate 149.00 25.340(1.003) 776924 21.20
011(8.
19
19
Hot Detected.
Hot Detected.
""?.'"'•'11 .ft""*?
TSK-
99.20
MHr-23 \P
15.212(0.926)
15.838(0.964)
IS E8BI1 810)
ta.cT7 ri .ai3l
143847
51622
1S99
5.09
2.22
0.14
l.tij
V.2b
5.09
2.22
1.37 —
2.49
8. £7
SPP
21.20
-------
Data Filet /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected (uL> : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
Scan 1214 (12.807 min> of YP790.d
2.0|
1.8-j
1.5-1
£ * j
loia-l
"0.54
0.2-i
I J * . 1
40 80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 1214 (12.807 min) of YP790.d (Subtracted)
2.0-1
1.8-:
1.5-!
xxl.2-1
Sl.O-i
So.8-i
="0.54
0.2-1
0 0-
, 1 J , . J
40 80 120 160 200 240 280 320 360 400 440
Mass/Charee
:
8.0-j
6 0-
s * :
34.0-
._ :
2.0-
..... 1
42 Naphthalene (PBM Reference Spectrum)
.
40 80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 1214 (12.807 min) of YP790.d (2 DIFFERENCE)
100-
75-i
504
25i
l.2g]
~-5o4
-754
40 80 120 160 200 240 280 320 360 400 440
Mass/Charee
Mass 128.00
2.0-3
1.8-j
•
1.6-i
1.4-i
31.2-j
ol.O-i
^O.B-j
0.6H
0.4^
0.2-i
0 0
11
a
I
Jli
12.4 12.6 12.8 13.0 13.2
Time (min.)
Mass 129.00
2.2-3
2.0-j
1.8-i
1.6-
1A —
**f-
s •
3*1
0.6-:
0.4-i
0.2-:
(I
i
12.4 12.6 12.8 13.0 13.2
Time (min.)
Mass 127.00
9 fl
^.o <
2.5-i
2.2-i
2.0-
_1.8-
?1.5-i
o * :
31'2'
0.8^
0.5-
0.2-
0 0-
«_JV 1
1
J ., ,
12.4 12.6 12.8 13.0 13.2
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected : 1.0
46 2-Methylnaphthalene
Page 12
Column diameter : 0.32
1.8-j
1.5-j
^1.2-j
«J) A A J
|0[gj
=-0.5-1
0.2-i
0.0-3
Scan 1414 (14.241 min) of YP790.d
| i i i | . r i | i i i | .. ,...,.. . | , , , |
40 60 80 100 120 140 160 180
Mass/Charee
Scan 1414 (14.241 min) of YP790.d (Subtracted)
1.8-j
1.5-j
^1.2-j
|o.8-
0.2-
0.0-
| i i i | I I •• •• | I — I i | i , ,...,. i i | i , i |
40 60 80 100 120 140 160 180
Mass/Charee
46 2-Methylnaphthalene (PBM Reference Spectrum)
.
8.0^
xx 6.0-
fO
|4.0-
;_
2.0-
0.0-
.
ll II 1 ll, II li, i.l . i I
1 ' ' ' 1 ' ' 1 ' ' ' 1 ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' I
40 60 80 100 120 140 160 180
Mass/Charge
Scan 1414 (14.241 min) of YP790.d (Z DIFFERENCE)
100-
75-
50-
25-
5-25-
**-50-
-75-
-100-
40 60 80 100 120 140 160 180
Mass/Charee
Mass 142.00
1.8-i
1.6-j
•1.4-1
1.2-.
o -
3 0.8r
^0.6-;
•
0.4-j
0.2^
0.0-
I
i | • >> | i i i
s
3
CM
*
3
*-i
i
1
1
II
1
1
•i .''Mi
. -r r , , ^ p | i i
13.8 14.0 14.2 14.4 14.6
Time (min.)
16
I.*-:
1.2-
1.0-
So.8-
»-i
X
^0.6-
0.4-
0.2-
0 0-
Mass 141.00
Is
V
CM
3*
I
.
1.
13.8 14.0 14.2 14.4 14.6
Time (min.)
-------
Data File: /chero/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected : 1.0
56 ftcenaphthylene
Page 14
Column diameter : 0.32
6.0-;
5.0-i
1.0-1
0.0
Scan 1675 (16.119 min) of YP790.d
I
f%
40
JJA
t^UjLi^
^
6.0-:
5.0-i
;2.o-
i.o-
0.0
40
8.0:
§4.0-
*"2.0-
40
100-:
75 -I
50-j
251
£ H
"-50^
-75H
-100-^-r
40
•^
60 80 100 120 140 160 180 200
Hass/Charee
Scan 1675 (16.119 min) of YP790.d (Subtracted)
iJll
i
60
Illll. ...h.
| IM ii ,iiii|>
I
80
100 120
Mass/Charge
140
160
180
56 flcenaphthylene
-------
Data File: /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected
-------
Data File: /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected (uL> : 1.0
65 Fluorene
Page 16
Column diameter : 0.32
1.8-1
1.5-j
1.2-j
XX •
o * :
XX -
=-0.5-;
0.24
Scan 1871
ilkiiMuladJyJilJ
•> (17.568 min) of YP790
liiLkLj
.d
, , L L
40 80 120 160 200 240 280 320 360 400
Mass/Charge
1.6-i
1.4-1
1.2-j
i0*8"
3o.6-
^0.4-
0.2-
Scan 1876 (17.E
IU.I.lll, ll. ,,,ll Jl.,lU J
68 min) of YP790.d (Subtracted)
LlL
.11 i.
40 80 120 160 200 240 280 320 360 400
Mass/Charge
8.0:
-6.0:
?4.0-
XX H
>- -
2.0-
0 0—
65 Fluor
1 1 ll. ,, .
ene (PBM Reference Spectrum)
40 80 120 160 200 240 280 320 360 400
Mass/Charee
100-
75-
50-
25-
£ 0-
«-25-
**-50-
-75-
Scan 1876 (17.568 min) of YP790.d (2 DIFFERENCE)
40 80 120 160 200 240 280 320 360 400
Mass/Charge
2.8-
2.5-j
2.2-j
2.0-j
1.8-j
51.54
^1.0-j
0.8-j
0.54
0.2-j
Mass 166.00
3
in
te
i »•
yj
17.20 17.40 17.60 17.80 18.00
Time (min.)
3.6-;
3.2^
2.8-;
2.4-j
?2.0-j
O
^i.2-i
0.87
0.4:
Mass 165.00
I
roiv. •»
""i ps? J
\r^J^
I—
t-t
P
r
-------
Data File: /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected : 1.0
73 Phenanthrene
Page 17
Column diameter : 0.32
Scan 2156 (19.588 min) of YP790.d
3.2-i
2.8-i
2.4-:
?2*°1
Ili-l
*"0.8-
0.4-;
O.O-3
1 1 1 Jl I 1
|j 111 HIM LiiiiLUk jJdi ll \ 1* kit I.L It. 11 ifilkLl.ii, la. ,. ,
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
Scan 2156 (19.588 min) of YP790.d (Subtracted)
3.2-3
2.8-i
2.4-!
~2.0-i
Si.6-i
•2 1.2-:
^O.S-i
0.4^
0.0-
,,tiN(t,v,...., )........,....,....,.,...>
rrr-r p r-r. , .... ( . . , , t , , , , ^ . , , , , , , . , ( , , , , (
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
73 Phenanthrene (PBM Reference Spectrum)
.
8.0:
•
KJ * J
<
^x4.0-^
5. ;
2.0-
0 0-
1
-
. . , J J . II J
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
Scan 2156 (19.588 min) of YP790.d (Z DIFFERENCE)
1003
75-j
50-j
2M
£
1 •<-•
1
ro
*
IT\
1 ? -
I o*
h §
l/U^wfi
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 179.00
6.0-;
5.0-
4.0-
ro
33*°1
"2.0^
i.o-i
0.0-
Is
•
rt— m c3
1 S' 1
II ^ I
s* fl ll 1
1 .7* 1 II II
1 1 IA i )l IH
In n 1 \ nil
M 111 1 «1 ill 1
i ,, JL j| | 1 Iff 1
\wWlii i f
n f i if iiifl i
i n i i iiii *
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 176.00
7.0-
6.0-:
5.0^
^4 Oj
<° * •
0
7 fl '
^ :
2 0-
*
1.0-"
—CO
CO
1 Cft
1"
1
1
^ 5
r^ S
• 7
1 1 1
i 1
, I i ... it.J N.L
ooW]WHfpJn" W.if, I,il I'll
19.20 19.40 19.60 19.80 20.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected (uL) : 1.0
74 flnthracene
Page 18
Column diameter : 0.32
Scan 2172 (19.703 min) of YP790.d
1.4-
1.2-i
1.0-
?0.8-
30.6-
^0.4-
0.2-
0.0-3
i
Li
1 1 .. 1 1 1
1 i i 1 III hll it > 1, l,i, I ,i i I . „ .
ll J 1, ill 11 111,1,1, llllllili L Ilillill 1,1 III lll,l,,il ii bnll 1 , 1 1,1 1 Ull hllil.li ,1 1 , 1 1
Illlll III ill 1
i 1
40 60 80 100 120 140 160 180 200 220
Mass/Charge
Scan 2172 (19.703 min) of YP790.d (Subtracted)
3
6 0-
(J* V ,
5.0-i
j
? * :
3 0~
x * •
^ 2 0-^
*~i-°i
0.0-3
ii
I 1 II I 1 ] 1 , 1 III
I 111 ill 1 1 . ill III .1 . , 1 1 II
1
1 1 1
T • • • i • i • • i • • i • • • i • • i ... i ... i ... i
40 60 80 100 120 140 160 180 200 220
Mass/Charge
74 Anthracene (PDM Reference Spectrum)
8.0-J
S6'°~
I4-0:
5. :
2.0-
0.0-
|
. ,
. , .. J J . .. ,11 Jill
i . i . | . . i ,..,,. i ,,...,. i , | • . i ,...,... |
40 60 80 100 120 140 160 180 200 220
Mass/Charge
Scan 2172 (19.703 min) of YP790.d (Z DIFFERENCE)
1UQ"
75-i
50-i
25-=
£ H
~-50i
-754
*
i ii
.. II. ,i L,, iii] .1 LI 1.1 i ,. .1 ..,n, i i. 1 n,i
I 1
40 60 80 100 120 140 160 180 200 220
Mass/Chdrjfff
Mass 178.00
3.2-i
2.8^
-
2.4-j
^2.0:
r :
SL6-
x :
XX
>.1.2-i
0.8-i
0.4-
0 0-
w.w . . • ) ... | ... | ... | . . . ,
19.40 19.60 19.80 20.00 20. 2(
Time (min.)
Mass 176.00
7.0H
*
"
6.0-i
5.0^
'.
&*'°--
ro
^ :
33-^
>-
2.0-
•:
l.o-i
Ort-
1— §g
1 10
1 9^
1 *"*
1
II
3 i
3 o
1 ,
1
/ K
i / iHk J( h\\i
HNW i nm¥[
^y-^— i — i — i — | — i — i — i — [ — i — i — i — | — i — i — i — | — i — i — i — j
19.40 19.60 19.80 20.00 20.2(
Time (min.)
Mass 179.00
6.0:
5.0-
4.0-j
? :
3 3.0:
XX
"2.0-
1.0-
0 0-
r§
1^-HjO CNJ
II ^* II
II ^^ LI 1!
s j 11
11 il' 1 il
llil A 1 1
n "11
iiA ffli/LJ 1 I Hf
i Ii ill Y r
Iii 'Ml i 1
19.20 19.40 19.60 19.80 20.00.
-------
'Data File: /chemA.i/10-23-97.bAP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected (uL> : 1.0
77 Fluoranthene
Page 11
Colunn diameter : 0.32
Scan 2503 (22.085 min) of YP790.d
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
Scan 2503 (22.085 min) of YP790.d (Subtracted)
2.4-1
2.0-i
0.0-
14
^4
uiii.,t ,
fO+
-+-
-+-
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
77 Fluoranthene (PBM Reference Spectrum)
8.0-
g'.H
2.0-
0.0-
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
100-
75-i
50^
25^
: 0-
'-25-i
'-50-
-75-
Scan 2503 (22.085 min) of YP790.d (Z DIFFERENCE)
-100 J-r
..illli... ..kt.
h. ll.4.k i... A . i _ .u
.L -. I. .,-IH .. ;.«•>•
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
Mass 202.00
0.0
21.6 21.8 22.0 22.2
Time (min.)
Mass 101.00
21.6 21.8 22.0 22.2 22.4
Time (min.)
Mass 100.00
0.0
21.6 21.8 22.0 22.2 22.4
Time (nin.)
-------
Da,ta File: /chem/Y.i/10-23-97.b/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB-5
Volume Injected (uL> : 1.0
78 Pyrene
Page 19
Column diameter : 0.32
Scan 2570 (22.568 min) of YP790.d
3.2-
2.8-
2.44
32.0-i
£ 1.6-j
-2l.2-
*-0.8^
0.4-
1
11
,
jiLjIL*.
40 80 120
2.8-i
2.4-1
~2*°i
|l.2-J
^0.8-1
0.4-;
o.o-i
J
Scan 2570
,.,
^iu^.
40 80 120
UL*J^
,
160 200
*
1), ,. . tl . ... I. , ,
240 280 320 360 400
Mass/Charge
(22.568 min) of YP790.d (Subtracted)
lHi|Mi,i/. . :
2.0:
o.o:
I
- • M
i i . . i . • . i i •
40 80 120
.
' l ' ' ' i
160 200 240 280 320 360 400
Mass/Charge
Scan 2570 (22.568 min)
100 -g
754
504
25-1
£ \n
—CO
S
CM
e\i
i
I
t.
KMA **J \ *.
i T i i i i r ' ' ' i • • ' i j ' ' i '
22.20 22.40 22.60 22.80 23.00
Time (min.)
Mass 101.00
8.0-
7.0-
6.0-i
P55-°-
n
E
3
7
i s
k :n \\\
O , A J| 1 i nil i
S4'°I ,11 1
>- 3.0-3 flj
2.0-i /T'U
1 \s\\\ \
n
iMj IN li nUI 1 A
n mm w ^
22.20 22.40 22.60 22.80 23.00
Time (min.)
Mass 100.00
2.8-1
2.5-i
2.2-j
2.0-i
1.8-1
^v
o * I
0.8-i
0.5^
0.2-;
0.0-^
rs
o <^
1 CM
1
I <^
s.
a
I
fl
J
if\tf\{^r*M 1 VAIU,/, AJ*/I V«,'
22.20 22.40 22.60 22.80 23.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/Cfifl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected : 1.0
21 Cumene
Page 13
Column diameter : 0.32
Scan 641 (8.715 min) of YP790.d
2.4-1
2.0-j
1.6-
l1^
-0.8-;
0.4-j
0.0:
^1
III, ll.ll
i .
.1
11
1
llmll
)
•
1,1
!• I1
1,, . ,
1 1,-
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Scan 641 (8.715 min) of YP790.d (Subtracted)
2.4-1
2.0-
•
1.6-j
-0.8-j
*~
0.4:
0.0^
.1
, III
, i
1 i 1
l.n
4.,!
III , 1
1 'l
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
21 Cumene (PBM Reference Spectrum)
8.0-
xv 6.0-
rf>
§4.0-j
>_ ;
2.0-
•
On-
,1 1,1
Hi. .. .1.1 ...in.
i
.1,
. . .
40 50 60 70 80 90 100 110 U
1
JO 130 140 150
Mass/Charee
Scan 641 (8.715 min) of
1001
75-j
504
25-j
*j_ f\ '
= -254
"*-50-^
-754
100 =
1
i . i II . ..1,1,
YP790.d (2 DIFFERENCE)
1 ti *
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charge
Mass 105.00
2.4H
2.24
2.o4
1.8-i
1.6-j
.^1.4-
<01.2-.
^*1 0-
^o.s-i
0.6-;
0.4-i
0.0^
/uA JUAAA/
, 'iT'i | °l"V>i"'|
8.4 8.6 8.8 9".0 9.2
Time (min.)
Mass 120.00
1.0-j
0.94
0.8-i
0.7-i
f^. '.
ro.e-
o •
-S 0.5-
•*»x !
>-0.4H
0.34
0.2-
O.l4
0 0-
B
K
00
1'
A,
8.4 8.6 8.8 9.0 9.2
Time (min.)
Mass 77.00
2.07)
.
1.8-"
1.6-
1.4--
^1.2-j
gi.o-i
*0.8r
^0.6:
0.4-;
0.2-i
0 0-
1
t
1
\
I
\ s
\ 1
1 ft 1 I
VtV ... 1 ....... 1 ... 1 ... I
8.4 8.6 8.8 9.0 9.2
Time (min.)
-------
Data File: /chen/Y.i/10-23-97.b/CflA/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected (uL> : 1.0
23 Phenol
Page 14
Column diameter : 0.32
Scan 748 (9.477 min) of YP790.d
1.2-ij
i.o-i
^0.8-j
£0.6:
3 :
-0.4-
>- ;
0 2-
V*fc _
0.0-
I
1
tUwJu
|
•
n , ,1 r , I,
, , | , , , , | ....,..,. | .,..,.... | . . ..,....,. . • • )
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
Scan 748 (9.477 min) of YP790.d (Subtracted)
1.2-d
1.0-;
^0.8:
So.6^
T-I * ;
X
-0.4:
0.2:
0.0-
i
Liiij i ,
I
i
,J ,• , L
, . f : , : : f , . , , f : . , , , ... . | . . ..,,,,,,,...,. . • • )
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
23 Phenol (PBM Reference Spectrum)
8.0:
xx 6.0-
ro
<>
34.0-
NX
2.o:
, 1
i J,,| J
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
100-
75-i
so-;
25-i
£
-------
Data File: /chem/Y.i/10-23-97.b/CAfl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected
-------
Data File: /chem/Y.i/10-23-97.b/Cftfl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-HM5-3-37
Column phase : DB.5-625
Volume Injected (uL> : 1.0
28 Benzyl Chloride
Page 17
Column diameter : 0.32
Scan 850
1.6-3
1.4--
1.2-i
xxl.OH
^0.8-i
^0.4-i
0.2-;
..III, ,M. ,.,
40 50
60
I'.M'll'
70
(10.204 min) of YP790.
•
80 90 100 110
Mass/Charge
d
120
1
130 140 150
Scan 850 (10.204 min) of YP790.d (Subtracted)
1.6-a
1.4-i
1.2-
1 0-
go.8-
*0.6-
="0.4-
0.2-
..hi 1.
.1 . ...i,
40 50 60
.. .,1
70
'/ .' V
80 90 100 110
Mass/Charee
1
120
130 140 150
28 Benzyl Chloride (PBM Reference Spectrum)
„
8.0-
j
~6.0-
_x4.0-
._
2.0-
On—
,l . ..I
J,
40 50 60
70
I
80 90 100 110
Mass/Charee
,
120
,|
130 140 150
Scan 850 (10.204 min) of YP790.d
40 50 60
. . , ill
70
i
80 90 100 110
Mass/Charee
1
120
. . .
130 140 150
1
Mass 91.00
6.0-=
5.5-i
5.0-j
4.5-i
4.0-:
53.0-=
TH :
^2.5^
*~2 0-
1.5-1
1 0-
0 5-=
0 0-
i
I
2
•
•
I
* i I
LA t\ A I A A
J WLAJVVMAJI/V
9.80 10.00 10.20 10.40' 10.60
Time (min.)
Mass 126.00
7.0-
6.0-
5.0-
^4.0-
O
-3.0-
2.0-
1.0-
I§
$>
|ilb f
« 1 1 1 * i f 1 1
9.80 10.00 10.20 10.40 10.60
Time (min.)
Mass 65.00
.8-s
2 5-
2.2~-
2.0-E
1.8-6
51'5!
3^2-i
*" ^•" :
0.8-E
0.5-=
0.2^
0 0-
a
o
T-l
1 1
nil Jl
AA, AA/I h &
•Www r \P\ i V ^^itMifJ
9.80 10.00 10.20 10.40 10.60
Time (min.)
-------
Data File: /chen/Y.i/10-23-97.b/Cfifl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected (uL) : 1.0
29 1,4-Dichlorobenzene
Page 18
Column diameter : 0.32
1.8-:
1.54
1.2-j
p i.o-j
XX I
>.0.5-j
fl O j
0.0J
,\
Scan 856 (10.247 min) of YP790.d
1
1
*
1
Wl 11 i II i 1
, ,,,1,, 1 1 111 Lnl.i , , lll.ll. , ,
if II 1 1 f 1 1 M | 1 I | I I I I | I I I I | 1 1 .. | ..,.,...,,,.
|
i
40 50 60 70 80 90 100 110 120 130 140 150
1.0-|
0.8-1
Q0.6-
o
£0.4-
>_
0.2-
Mass/Charee
Scan 856 (10.247 win) of YP790.d (Subtracted)
|
40 50 60 70 80 90 100 110 120 130 140 150
8.0-j
~6 0^
? * -
V<4.0:
*** "
>.
2.0-
0.0-
|.
1 '
Mass/Charee
29 1,4-Dichlorobenzene (PBM Reference Spectrum)
.1
.,, i i, ., l|l, ,. . 1
|
40 50 60 70 80 90 100 110 120 130 140 150
100-
75-=
™
504
™
25-:
Jt
-------
Data File: /chem/Y.i/10-23-97.b/Cflfl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected : 1.0
31 2-Methylphenol
Page 19
Column diameter : 0.32
Scan 914 (10.660 min) of YP790.d
1.4-^
1.2-i
i.o-i
XX •
^0.8-:
S0.6-:
0.2-i
0.0-3
1.4-1
1.2-i
1.0-i
go.a-
?0.6-
0.2-
0.0-
Jl 1 i II
il ll |,,l III I.I III 1 llpi Mi II II 1
ii I 1 , III
40 50 60 70 80 90 100 110 120 130
Mass/Charee
Scan 914 (10.660 min) of YP790.d (Subtract
, ., ,|l ,. ,1 ; i. ,
ed)
1 , , III
40 50 60 70 80 90 100 110 120 130
Mass/Charee
8.0-i
-.6.0-
tf>
*~2.0-i
0.0:
100-
754
50-^
25i
~-504
-754
-100-
31 2-Methylphenol (PBM Reference Spectr
• 'I'l'l' -I'l'i i •!• 'i . -
urn)
40 50 60 70 80 90 100 110 120 130
Mass/Charee
Scan 914 (10.660 nin) of YP790.d (Z DIFFERENCE)
"
•| ' ' i|ni" • '•• i| |ii" ' ' '
, ., in
40 50 60 70 80 90 100 110 120 130
Mass/Charee
Mass 108.00
1.4-
1.2-i
1.0-
?0.8^
~o.6-i
0.4:
0.2:
o.o-
K
S
o
TH
1
Jj 1
VJJ
VD
* ^^.
*
S
A
A M
).20 10.40 10.60 10.80 11.00
Time (min.)
Mass 77.00
5.0-!
4.5H
4.0r
3.5-i
-3.0-i
^25-
1.5-j
i.o-i
0.5-j
0.0J
1
r*
I 2
1
H 5 § i
fl
if 111
Uli^Juw
5.20 10.40 10.60 10.80 11.00
Time (min.)
3.6-i
3.2:
2.8-i
2.4-i
5° 2.0:
^ 1.2-i
0.8^
0.4-
0.0-
1
Mass 90.00
GO
TH
1
11 lh \
1(1 1
III
11
0.20 10.40 10.60 10.80 11.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP790.d
Date : 23-XT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected - * :
0.2:
0.0-
J,l.
40
1.2:
1.0:
^0.8-i
£0.6:
^^
x :
>- * ;
0.2:
Oci-
i
il I,
.U ' | '
40
.
•
8.0^
ro6*0^
^x 4 0~
XX
>-
2.0:
rt rt-
.il .,
40
100-a
75-i
50-j
254
«£ 0-
e-254
-754
-1f>0-
40
.
K,
. . . |
Scan 960 (10.989 min) of YP790.d
1- ^i,!,.^!,! .,.(. .}.
l... ... ..1. ... .
50 60 70 80 90 100 110 120 130
1
Mass/Charee
Scan 960 (10.989 min) of YP790.d (Subtracted)
1
i •- •• i-
i.. . ,.i i
i
1.
50 60 70 80 90 100 110 120 130
5<
l
Mass/Charee
33 ficetophenone (PBM Reference Spectrum)
1 • I'i'v i i i1!1
.
(
D 60 70 80 90 100 110 120 130
Mass/Charee
Scan 960 (10.989 rain) of YP790.d (% DIFFERENCE)
-
., li
1
50 60 70 80 90 100 110 120 130
Mass/Charee
140 150
140 150
140 150
140 150
Mass 105.00
1.4-1
1.2^
1.0-i
S0.8^
<->
S°-6~
0 4-
V»*T
Oo
.2-
0 0-
OO
s* I
S3
jj
S '
^ 1
1 in ll II
A rH [1 11
I'
WWu (f
10.60 10.80 11.00 11.20 11.40
Time (rain.)
Mass 77.00
1.0-j
0.9-1
0.8^
0.7-i
^0.6-1
£o.5-^
-0.4-!
s- :
0.3^
•
0.1-1
i
*
s
^~i
& •
0* (1 ^r
3-w
vo D 1 zT*.
ON Jl I T^^H
VO ,^
S A '
. Am
—TO
in
CJ
*
|
1
I)
1 1
1 1
j 1 1
All
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 120.00
3.6-:
3.2^
2.8-
'.
2.4-
S * ~-
^1.6-
XX
>"1.2-
0.8^
0.4-i
0 0-
H »H
g 3
» y^ 1
^ 0% $^i
k 5 4
j [3
! Ml
A Lv WL
/« H y J K^I/ r it u/i y w ,
10.60 10.80 11.00 11.20 11.40
Time (min.)
-------
Data File: /chemA.i/10-23-97.b/CAfl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected (uL) : 1.0
60 Biphenyl
Page 36
Column diameter : 0.32
8.0-i
7.0-=
6.0-1
xx 5.0-=
S4.0-J
33.0-i
^2.0-1
1.0-i
0.0-3
i, k
1 JllJll
40 60
iJiUi
80
Scan 1549 (15.212 min) of YP790.d
j i. j. L .
1^ r'i "1 i i i | i i i | i i i | i r
100 120 140 160 180 200 220 240
Mass/Charee
Scan 1549 (15.212 min) of YP790.d (Subtracted)
8.0-3
7.0-j
6.0-j
S3.0-J
^2.0-j
i.o-i
Oft-
1
1,
, id ,
.V | i i | i •
40 60
8.0:
xx 6.0-
S
34-°:
.,_
2.0-
.
1 1
40 60
1
i i.li i
80
,
80
I..I 1L.I. 1 III i . . 1
1 i
100 120 140 160 180 200 220 240
Mass/Charee
60 Biphenyl (PBM Reference Spectrum)
|
. . , , . .,1
1
100 120 140 160 180 200 220 240
Mass/Charee
Scan 1549 (15.212 min) of YP790.d (Z DIFFERENCE)
lOOi
-
75-.
504
254
S-25-j
~-5o4
-754
-100-
.,.
1
1 ...Ill ,„..
40 60
1
i,r -
80
L. .»~... ._. ._..-.. ._~ ....J,.. i ...
100 120 140 160 180 200 220 240
Mass/Charee
Mass 154
8.0-i
"
7.0-i
6.0-;
:
5.0--
XX '
^4.0-i
x :
2.0-;
1.0-i
0.0-:
|
,
s\ . -J
14.80 15.00 15.
.00
ra
a
1
1
®
So
• *
Itfp
.
-~ xVx -/
"V'l t V
»H^
|l(ln /
w
' 1 '
20 15.40" 15.60
Time (min.)
Mass 152
6.0-
5.0-
xx 4.0-
s
^3.0-
XX
^2.0-
1 0-
Jt « V
.00
CM
s.l
-1 s
«U i | i — rn — [— i — n —
14.80 15.00 15.
i i
s
f\
1
W
r"r
20 15.40 15.60
Time (min.)
Mass 155
6.0-j
5.5-!
5.0-=
4.5-i
4.0-1
S3.0-i
^*? $ ''
^ * 1
1.54
1.0-1
0.54
0.0-=
.00
CVJ
. r~. . _ -A ^ffJa
14.80 15.00 15
a*
t
t
I Jl J
f~s
la
1 ^H
1
\
1
L
20 15.40 15.60
Time (min.)
-------
IJata File: /chem/Y.i/10-23-97.b/Cflfl/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sainple ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected • *°1
i.o-i
0.0-:
1
ill i, i y k k 11
li M JJiuiLii U>l4ipviiP
i
lUi .,L . 1 . . 1 1 1 . • V ' '
Pl ' I ' ' ' i * • ' F ' • ' i ' * ' i ' ' ' I ' ' ' i • ' ' i ' •
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
-,
5.0-i
:
4*0~"
|3.0-i
£2.0-;
>• •
l.O-i
0.0-
Scan 163
.
.
S (15.838 min) of YP790.d (Subtracted)
1
i H -;• • J i • f If" • V * • f
r r ' ' i ' ' ' I h ' ' r ' ' ' I n r ' I ' ' ' I ' ' ' I ' ' ' I ' '
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
61 Dimethalphthalate (PBM Reference Spectrum)
8 —
.0-
xx 6.0-
ro * •
I4-0:
>_
2.0-
0 0-
, , il 1 1 , il
H
i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1636 (15.838 min) of YP790.d (Z DIFFERENCE)
100-
75-j
504
25-=
«- o-^
3_25j
~_50j
-75-:
-100-
1
_ t ^ L ._ .. J L
i |
i
• • I i*
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 163.00
2.8-j
2.5-|
2.2-j
^1.8-j
51-5"!
^< 1 2-
^i'.o-j
0.8-j
0.54
~.
II "^
CM
O^
.
15.40 15.60 15.80 16.00 '16.20
Time (min.)
Mass 194.00
1.1-
1.0-j
0.9-
0.8-j
0.7-
XX :
5° 0.6-
o
30.5-
^0.4-1
0.3-
0.2-!
0.1-!
iR
P
1
nl i_^
15.40 15.60 15.
I 1 S
f II ^
i
J.
30 16.00 16.20
Time (min.)
4.0-i
3.6-i
3ri '
.2-
2.8-i
2 4j
§2^
'x :
^1.6-
1.2-i
0.8-i
0.4-i
o o-
Mass 164.00
1 l~SR
GO
n ^
II '*""'
A I
S
ft III llntn-
1 fl
III
1
II
i Id i
UN
I
. . ,i,
1 \Mn ,
Mil
11 1
111 1 1ll. . 1 VI 1 11
15.40 15.60 15.80 16.00 16.20
-------
Hata File: /chem/Y.i/10-23-97.b/CfiA/YP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected : 1.0
65 Dibenzofuran
Page 41
Column diameter : 0.32
3.5-j
3-°i
2.5-i
1 2.0-i
S1-5"!
s-l.O-j
0.5-j
Scan 1776 (16.846 min) of YP790.d
Jill, lllllJil I.I i.illlllinlliililJ, l.n. i,ill,,.l,,.i,l,in.,, ,,ll,l,l i.,, ill. ,I,J|I
UmlllJ
i
40 60 80 100 120 140 160 180 200
Mass/Charee
3.5-j
3.0-j
2.5-j
32.0-j
Sig-:
x -1*3 •
^•^ z
^i.o-j
0.5-;
Scan 1776 (16.846 win) of YP790.d (Subt
.1 i . J. ihl.. iin . ,i ill . ,. llil , , li . ill
-acted!
i ..i
40 60 80 100 120 140 160 180 200
Mass/Charge
8.0:
~6.0-
ro
^4.0-
*w*
>-
2.0-
0 0
65 Dibenzofuran (PBM Reference Spectrum)
i - • ii- ii I. .'•« ii. .ill-
40 60 80 100 120 140 160 180 200
Mass/Charee
100-
75-j
504
25-^
5£ 0-j
3 -25-!
~-5o4
-75-!
Scan 1776 (16.846 min) of YP790.d (Z DIP
FERENCI
.
I)
,
40 60 80 100 120 140 160 180 200
Mass/Charee
4.4-
4.0-i
3.6-i
3.2-i
2.8-i
52.4-1
S2.0^
:i.^
1.2-;
0.8-^
0.4-:
Mass 168.00
1
\o
iH — -JJ
•«•
CO
.
VO
in ^
If)
.
\o
^-4
1
I O
1 m &
n ID •
55 R
3* • ^.fc
"*' A -^*
i4 fl , S
vL^ifV ^v/WAA
,0-t i i i | i • i | i i • | i i i | i i
16.40 16.60 16.80 17.00 "17.20
Time (min.)
1.6-!
1.4-i
1.2:
1.0-
*"»
l°-8i
^0.67
0.4^
0.2:
0 0-
Mass 139.00
— *s>
3
*
S. S oo ^ 2 5
*2 vo **" 1 1 i P^ JJ
•tH ,_^ * 1 1 ' ' j ^Tl
r\^°/i h Ji
16.40 16.60 16.80 17.00 17.20
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CtWYP790.d
Date : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected (uL) : 1.0
66 Di-n-butylphthalate
Page 42
Column diameter : 0.32
Scan 2320 (20.769 min) of YP790.d
2.0-f
1.8-^
1.5-1
£1.2-1
Sl.O-j
~0.84
"•0.5-j
0.24
0 0-^
,ll .,,.,...1 ... l
40 60 80 100 120 140
160 180 200 220 240 260 280 300
Mass/Charee
Scan 2320 (20.769 min) of YP790.d (Subtracted)
2.0-1
1.8-1
1 5-=
XX 1*2^
ol.O-=
^0.8-!
^0.5-=
0.2-i
0 0-^
.1 ... I . l
40 60 80 100 120 140
160 180 200 220 240 260 280 300
Mass/Charee
8.0-J
xx 6.0-
ro
<
§4.0-
5_
2.0-;
66 Di-n-butylphtha
,1 . Jl i i. , I, i. ..
40 60 80 100 120 140
late (PBM Reference Spectrum)
| i
160 180 200 220 240 260 280 300
Mass/Charee
Scan 2320 (20.769 nin) of YP790.d (2 DIFFERENCE)
100 -:
75 -j
504
25-j
fc
-------
Data File: /chem/Y.i/10-23-97.b/CfiA/YP790.d
"We : 23-OCT-97 15:09
Instrument : Y.i
Sample ID : SO-MM5-3-37
Column phase : DB.5-625
Volume Injected : 1.0
83 bis(2-Ethu.lhexyl)phthalate
Page 51
Column diameter : 0.32
Scan 2955 (25.340 rain) of YP790.d
j
2.8-i
2*4~
2.0-:
S1'6!
31.2-!
x** „
0.4-i
II J 1
.11 J .in .. I t. . .
L . i.
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Scan 2955 (25.340 min) of YP790.d (Subtracted)
20-
.0 .
2 4-
^»~ i
2.0-
gl.6-
^1.2-
XX
>-0.8-
0.4-
Ofi-
1, 1 .
H l.l.i
40 80 120
I
160 200 240 280 320 360 400
Mass/Charee
8.0-J
~6.0-
ro
|>
34.0-
>-
2.0-
0.0-
83 bis(2-Eth«
1
I
I..1 ,1
, . T , . , 1 f 1 1
jlhexyDphthalate (PBM Reference Spectrum)
-
i • ' • i • • • i | ... | ... | ...
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Scan 2955 (25.340 min) of YP790.d (Z DIFFERENCE)
100 -:
75 -i
50-i
25-i
s-25-=
>x :
-50-=
-754
-100-
-
'T"1~T
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Mass 149.00
3.0-d
2.8-=
2.5-j
2.2-j
2.0-j
s1*8!
Ili-j
>-i.o-=
0.8-j
0.5-i
0.2-=
. T^-~-
25.00 25.20 25.40 25.60 25.30
Time (min.)
Mass 167.00
7.0-i
6.0-
5.0-
^4.0-:
•rH :
X
-3.0-
2.0-
1.0-
0.0-
n*
Is
/ I
-P* VV • <" •"V ^-ft- f-r* -*«•«— A~
n i TT i i | i i i | i r1 r f1' ' ' 1
25.00 25.20 25.40 25.60 25.80
Time (min.)
-------
1 ,***'.*** , V •"
- - < ;- ^ ~r ^ ;, ^~p
s4» <,, *'- «$• t- &•
Project Number 43433
Sample File: YP791
V*»X^*^^ %i**\ s ^ ^v.-^
Dilution Factor:
•,
* ? •.- •, '
tit|M^
1.00
^•^^•5Sa4ii*:Ci
Method 8270A MM5
Sample ID: SO-MM5-4r51
*•*»..' •'•'Vpjvj^yg
Naphthalene-d
Naphthalene
2-Methylnaphthalene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrenc-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-d ^
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
^MJ^S
IS 2
45.94 B
58.46
IS 3
U
1.10 ]
0.62 ]
0.77 ]
IS 4
1.17 ]
0.28 ]
0.91 ]
IS 5
0.98 ]
U
U
IS 6 High
U
U
U
U
U
U
U
U
•? <: •/ ![ \
12.76
12.81
14.24
16.42
16.13
16.49
17.57
19.54
19.59
19.70
22.10
25.28
22.58
29.40
" " "JEto&IjaiJilA r 'i^^vVQtt^tti.IJiBit i
% *'% -.*l:8t ^ *% v * * ^^ % \ ^ &8S -^c ''•
10
10
0.40 10
10
10
10
10
10
10
10
0.19 10
0.19 10
0.16 10
0.17 10
0.15 10
0.17 10
0.16 10
0.15 10
0.20 10
0.16 10
NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
L
Project Number: 43433
Sample File: YP791
Method 8270A MM5
Sample ID: SO-MM5-4-51
> MI
I Dilution Factor.
1.00
h.s v< *sY-^ -.*, >%»"i.v\
•> ^ \v ;- ..^ "
?hcnol-d
5
Nitrobenzene-d
5
1 ,3, 5-Trichlorobenzene-d
3
1 ,4-Dibromobenzene-d
4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
Terphenyl-d
H3^§ ^x^«^^f>^f
>\ i0/,^ , ? f^. ^^yst^rk »s^ ,
\ w. > \ \ -^. Xs •- «. %<• ^^ •:•. BPEPB .-. -xxx ^^ . > •> \ < s\
ft. X- jp 5 ^ *• ^-- f V A^I-T «\*W^f ^ ^"- '.f-. ^^*\ s -.1 ^X v %
74.76
63.35
57.85
70.52
80.59
118.77
90.99
78.62
86.10
ll*^
•^ ^. \% i"--- %
^ ^-- ;ix>
9.45
11.29
11.98
12.87
15.01
18.07
19.66
22.54
22.90
^ivsjj*-^
-. y- 's x s%>> . . •*>.•• ' •• •• ^^
"\<- -*',«":?: - ^ Y-
^^% vw«% •.-'•.V.V s^.\
1
2
2
1
3
3
4
5
5
^¥x?o^iKig,^i
..-. * -.x^ ^ «4 %55 v- ^ •• ^ •
-\ o-: ^--rr*- x ," - =
^ % s.jX^-.issS.j. •. : ; -, \ ; \\ :
75
63
58
71
81
119
91
79
86
Reviewed by.
Date l\_/ '3 /T7
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
Savar v3.5
-------
* % % ^
- ~ -* - ,'„ , Y*, *'.;,';
Project Number 43433
Sample File: YP791
aientPrOje<±Saginaw;MI :
**JI Jliu*t XoJy'f ^viA.***?- "" "• ^ s^^"
- -*^V^t^J -'%£F * V\'^x'vo-V^l
- ^F^ci^J^^ioi»m^t-al^|vi:c«s t x ^ ?«
%s f f •. H-^
^If^^l^K", -^ :v --
Method 8270A MM5
Sample ID: SO-MM5-4r51
^ ^ v^KSSK'^H
:|t'v^;
3P;';
Dilution Factor 1.00
toa!yt*' "' '^fe&s*^
1 ,4-Dichlorobenzene-d
n-N i trosodimethylamine
Cumene
Phenol
Aniline
bis-(2-Chloroethyl)ether
Benzyl Chloride
1 ,4-Dichlorobenzene
2-Mediylphenol
Acecophenone
n-Nitrosomorpholine
o-Toluidine
Hexachloroethane
1 ,2-Dibromo-3-chloropropane
N,N-Diethylaniline
Naphthalene-d
8
3/4-Methylphenol
Nitrobenzene
N,N-Dimethylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlorobutadiene
a,a,a-Trichlorotoluene
Hydroquinone
IS 1 10.22
U
0.45 J 8.71
19.44 9.48
U
U
U
1.30 J 10.25
0.70 J 10.67
8.68 BJ 10.99
U
U
U
U
U
IS 2 12.76
0.99 J 10.97
U
U
U
U
U
1.29 J 12.64
U
U
U
1.39
0.46
0.99
0.36
1.34
0.49
1.27
1.32
0.48
0.49
0.47
0.41
0.86
0.68
1.27
0.60
0.72
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; ): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
SavarvS.5
-------
Project Number: 43433
Sample File: YP791
Method 8270A MM5
Sample ID: SO-MM5-4r51
^gfe^;^l)^^
1
riyfe ,', f.fe^?1
J-Chloroacetophenone
Acenaphthene-d
rlexachlorocyclopentadiene
-2,4,6-Trichlorophenol
2,4,5-TrichIorophenol
Jiphenyl
Oimethylphthalate
2,4-Dinicrophenol
i-Nitrophenol
2,4-Dinitrocoluene
Dibenzofuran
4,6-Dinitro-2-methylphenol
Trifluralin
Phenanthrene-d
10
Di-n-butylphthalace
Hexachlorobenzene
i-Aminobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Benzidine
4,4'-Methylenedianiline
Dimediylaminoazo benzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
Dilution Factor. 1.00
*^^^f^'^'V3
U
IS 3 16.42
U
U
U
2.50 } 15.22
1.43 ] 15-84
U
U
U
1.25 ] 16.85
U
U
IS 4 19.54
5.85 BJ 20.78
U
U
U
U
U
IS 5 25.28
U
U
U
U
U
"Suff
0.33
1.40
1.20
1.12
3.48
1.59
1.31
2.60
1.94
0.84
0.35
1.49
3.26
0.90
0.26
0.63
0.56
0.32
0.64
10
10
10
10
10
10
25
25
10
10
25
10
10
10
10
25
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated* Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
*
5~ -*\\\, •»">,. s s C
1 - ^ ?% v vS\
Project Number 43433
Sample File: YP791
Method 8270A MM5
Sample ID: SO-MM5-4r51
Dilution Facton 1.00
Amlyte
3,3'-Dichlorobenzidine
Methylene bis-chloroaniline
bis(2-Ethylhexyl)phthalate
9.14
U
U
BJ
0.47
1.09
25.34
10
10
10
Reviewed by.
Date U /
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
Savar v3.5
Printed-12:43 11/13/1997
-------
Data.filet /chem/Y.i/10-23-97.b/YP791.d
Date •: 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-HM5-4-51
Column phase : D6-5
Volume Injected (uL) : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0.32
Page 9
/chem/Y.i/10-23-97.b/YP791.d (Part 1 of 2)
• p
A ^f
3 0)
Q
10
11 12
Time (min.)
13
14
15
16
17
18
-------
Data, filet /chem/Y.i/10-23-97.b/YP791.d
Date •: 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Report Date: 24-Oct-1997 06:58
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-23-97.b/YP791.d
43433
23-OCT-97 16:00 Autotune Date: 22-Oct-97
DD Inst ID: Y.i
SO-MM5-4-51
185-7-5A-E
09:14:0
/chem/Y.i/10-23-97.b/cclist.m
24-Oct-1997 06:51 target
23-OCT-1997 09:12
7
1.000
HP RTE
Sample Type: AIR
Cal File: YP783.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
Compound*
* 1 l,4-Dichlorobenzene-d4
• 2 Naphthalene-dS
* 3 Acenaphthene-dlO
* 4 Phenanthrene-dlO
* 5 Chry«ene-dl2
* 6 Perylene-dl2
$ 7 2-Fluorophenol
$ 8 Phenol-d5
$ 9 2-Chlorophenol-d4
$ 10 l,2-Dichlorobenzene-d4
$ 11 Nitrobenzene-dS
$ 12 l,3,5-Trichlorobenzene-d3
$ 13 l,4-Dibromobenz«ne-d4
$ 14 2-?luorobiphenyl
$ 15 2,4,6-Tribromoph.no!
$ 16 Anthracene-dIO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
42 Naphthalene
46 2-Methylnaphthalene
SO 2-Chloronaphthalene
56 Acenaphthylene
58 Acenaphthene
65 Fluorene
73 Phenanthrene
74 Anthracene
77 Fluoranthene
78 Pyrene
83 Benzo(a)anthracene
84 Chrysene
86 Benzo(b)fluoranthene
QUANT SIO
MASS
152.00
136.00
164.00
188.00
240.00
264.00
112.00
99.00
Compound
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
244.00
128.00
142.00
ic? fin
iDei • UU
152.00
154.00
166.00
178.00
178.00
Compound
202.00
228 .00
228. 00
252.00
ON-COLOHN
RT (RKL RT>
10.217(1.000)
12.762(1.000)
16.420(1.000)
19.543(1.000)
25.276(1.000)
29.405(1.000)
7.316(0.716)
9.455(0.925)
Hot Detected.
Not Detected.
11.295(0.885)
11.982(0.939)
12.870(1.260)
15.009(0.914)
18.072(1.101)
19.659(1.006)
22.535(0.892)
22.903(0.906)
12.813(1.004)
14.240(1.116)
16.132(0.982)
16.492(1.004)
17.574(1.070)
19.594(1.003)
19.702(1.00.8)
t»rt?"j?L!.2.<3.&
22.579(0.893)
AA *p M f M IT* \
RESPONSE
494079
1584565
926997
1555065
1960428
2515943
32064
1552200
946163
760854
810046
2319718
820242
3795484
4531145
3447432
1841526
1535484
45451
14989
20802
46422
10564
4~7t>T\
63327
-S*T-»
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
2.20
74.76
63.37
57.76
70.52
80.56
118.57
90.97
78.64
86.05
45.92
58.44
1.10
0.62
0.77
1.17
0.28
0.98
0.01
FINAL
( ug)
2.20UQR)
74.76
63.37
57.76
70.52
80.56
118.57
90.97
78.64
86.05
45.92
58.44
u. it t«u)
0.62U)
0.77(a)
1.17 (a)
0.28UQ)
0.98UQ)
o.oi r»oi
Data Review
Date: ,,)i
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Report Date: 24-Oct-1997 06:58
Page 2
Compound*
QUANT SIQ
MASS
RT (RE. RT)
CONCENTRATIONS
OH-COLUMN FINAL
RBSPONSB ( ng) ( ug)
87 Benzo (k) fluoranthene
88 Benzo(e)pyrene
89 Benzola)pyrene
90 Perylene
91 Indeno(l,2,3-ad)pyrene
92 Dili«nz(»,h) «nthr»o«n»
93 B»nzo(g,h,i)p«ryl«n«
QC Flag Legend
252.00
252.00
252.00
252.00
276.00
32.S42
Compound Hot Detected
Compound Not Detected
a - Target compound detected but, guantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
R - Spike/Surrogate failed recovery limits.
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP791.d
Report Date: 24-Oct-1997 07:09
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Snip Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
REPORT
SEMI-VOLATILE QUANTITATION
/chem/Y.i/10-23-97.b/CAA/YP791.d
43433
23-OCT-97 16:00 Autotune Date:
DD Inst ID: Y.i
SO-MM5-4-51
185-7-5A-E
22-Oct-97 09:14:0
/chem/Y.i/10-23-97.b/tlicaa.m
23-Oct-1997 10:51
23-OCT-97
7
1.000
HP RTE
09:56
Sample Type: mm5
Cal File: YP784.d
Target Version: Target 2.20
Compound Sublist: CAAl.sub
CONCENTRATIONS
Compound*
• 1 It4 Dichlorobenzene-d4
* 2 Haphth«lene-d8
* 3 Acenaphthene-dlO
* 4 Fhenanthrene-dlO
* 5 Chry*ene-dl2
• £ Perylene-dl2
$ 7 2-Fluorophenol
$ 8 Phenol-45
$ 9 2-Chlorophenol-d4
$ 10 l,2-Dichlorobenzene-d4
$ 11 Hitrobenzene-dS
$ 12 l,3,5-Trichlorobenzene-d3
$ 13 l,4-Dibroiuobenzene-d4
$ 14 2-Pluorobiphenyl
$ IS 2,4,6-Tribromophenol
$ 16 Anthracene-dIO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
20 n-Hitroiodimethylamine
21 Cumene
23 Phenol
24 Aniline
27 bis-(2-Chloroethyl)ether
28 Benzyl chloride
29 1,4-Dichlorobenzene
31 2-Methylphenol
32 3/4-Methylphenol
33 Acetophenone
34 n-HitroBomorpholine
35 o-Toluidine
36 Hexachloroethane
QUANT SIO
MASS
152.00
136.00
164
188
240
264
112
99
.00
.00
.00
.00
.00
.00
Compound
Compound
82
185
240
172
329
188
212
244
105
94
91
146
108
108
105
5C
.00
.00
.00
.00
.80
.00
.00
.00
. 00
.00
.00
Compound
Compound
. 00
.00
.00
.00
.00
. 00
.00
Compound
10
12
16
19
25
29
7
9
Hot
Hot
11
11
12
15
18
19
22
22
8
9
Hot
Hot
10
10
10
10
Hot
RT (RBL RT)
.217(1.000)
.762(1.000)
.420(1
.543(1
.276(1
.405(1
.316(0
.455(0
.000)
.000)
.000)
.000)
.716)
.925)
ON-COLUMH
RESPONSE ( ng)
494079 40.00
1584565 40.00
926997
1555065
1960428
2515943
32064
1552200
40
40
40
40
2
84
.00
.00
.00
.00
.36
.81
FINAL
( ug)
2
84
.36
.81
Detected.
Detected.
.295(0
.982(0
.870(1
.009(0
.072(1
.659(1
.535(0
.903(0
.715(0
.476(0
.885)
.939)
.260)
.914)
.101)
.006)
.892)
.906)
.853)
.927)
946163
760854
810046
2319718
820242
3795484
4531145
3447432
12845
314379
59
51
69
85
133
91
74
87
0
19
.47
.49
.78
.29
.15
.76
.01
.30
.45
.44
59
51
69
85
133
91
74
87
0
19
.47
.49
.78
.29
.15
.76
.01
.30
.45
.44
Detected.
Detected.
.253(1
.667(1
.966(0
.988(1
.004)
.044)
.859)
.075)
21408
8765
13944
158759
1
0
0
8
.29
.69
.98
.68
1
0
0
8
.29
.69
.98
.68
Detected.
Data Review:
Date:
-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP791.d
Report Date: 24-Oct-1997 07:09
Page 2
CONCENTRATIONS
Compound*
37 Nitrob.nz.n.
38 N,N-Dim.thylanilin.
39 l,2-Dibromo-3-chloropropan*
40 Isophoron*
41 o-Ani«idin.
42 1,4-Ph.nyl.n.diamin.
43 1,2,4-Trichlorob.nz.n.
44 N»phth»l.n.
46 H.xachlorobutadi.n.
47 N,N-Di.thylanilin.
48 »,»,a-Trichlorotolu.n.
49 Hydroquinon.
51 2-Chloroac.toph.non.
52 H«xachlorocyclop.ntadi.n«
53 2,4,6-Trichloroph.no!
54 2,4,5-Trichloroph.no!
SO Biph.nyl
61 Dim.thylphth.alat.
62 2,4-Dinitroph.nol
63 4-Hitroph.nol
£4 2,4-Dinitrotolu.n.
65 Dib.nzofuran
66 Di-n-butylphthalat.
£7 4,6-Dinitro-2-m.thylph.nol
68 Trifluralin
69 H«xaehlorob.nz.n.
70 4-Aminobiph.nyl
71 Pvntachloroph.no!
72 P.ntachloronitrob.nz.n.
73 4-Nitrobiph.nyl
74 B«nzidin»
75 4,4*-M«thyl«n«dianilin«
77 Dim*thylaminoazob*nz*n*
78 3,3'-Dim«thylb«nzidin«
80 3,3'-Dim*thoxyb«nzidin«
81 3,3'-Dichlorob.nzidin.
82 M«thyl«n« bi»-chloro«nilin»
83 bi«(2-Sthylh«xyl)phthal»t»
QUANT SIO
MASS
77.00
Compound
Compound
Compound
108.00
180.00
128.00
Compound
134.00
159.00
110.00
105.00
Compound
196.00
196.00
154.00
163.00
184.00
139.00
165.00
168.00
149.00
198.00
Compound
Compound
Compound
Compound
152.00
184.00
Compound
120.00
212.00
244.00
Compound
Compound
149.00
Hot
Hot
Hot
12
12
Hot
13,
Not
IS
15
yt
If.
16
20
Hot
Hot
Hot
Hot
Hot
2*
25.
Hot
Hot
25
RT (RKL RT)
D.t.ct.d.
D.t.ct.d.
D.t.ct.d.
.641(0.990)
.813(1.004)
D.t.ct.d.
cn * f1 i W
D.t.ct.d.
.218(0.927)
.844(0.965)
if¥?(1 m*»
.853(1.026)
.776(1.063)
D.t.ct.d.
D.t.ct.d.
D.t.ct.d.
D.t.ct.d.
D.t.ct.d.
-2*0 (0,91'"
D.t.et.d.
D.t.ct.d.
.341(1.003)
ON- COLUMN FINAL
RESPONSE ( ng) ( ug)
16551
1841526
inif
79149
37203
n?n —
40497
321779
"Tie
-5-95 —
428009
<1.U4 J.U4"
1.28 1.28
49.39 49.39
4 A 4 4 1 O 4 ^
Q 07 0-r07
2.50 2.50
1.43 1.43
l-r81 1 frl
1.24 1.24
5.84 5.84
o.oi"" e-f-ei
9 . 14 9 . 14
f1
fPj8ftl^
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : D6-5
Volume Injected (uL> : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
Scan 1215 (12.813 min) of YP791.d
1.0-
0.8-i
XX
gO.6-
3 0.4-
0.2-
0.0-
*
. |[ .11 i|.. .. .,1 III.
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
.
1.0-:
0.8J
vo 0.6-
o :
3 0.4:
0.2:
.
0.0-
Scan 1215 (12.81:
i
5 min) of YP791.d (Subtracted)
i
, il .11 HI. . J III .
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
42 Naphthalene (PBM Reference Spectrum)
•
8.0:
•
^ 6.0-
fO
3 4.0-
XX
^2.0:
•
o.oJ
^
l! Hi II. ,1 ill
II 11 Jll Illl 1 II. Ill
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
Scan 1215 (12.813 min) of YP791.d (2 DIFFERENCE)
100-3
75-i
50-i
25-i
fc
JH
GO
CM
12.4 12.6 12.8 13.0 13.2
Time (min.)
Mass 129.00
a
1.1-
1.0-j
0.9-j
0.8-
0.7-
gO.6-
3°*5"
^0.4-1
0.3:
0.2,
0.1-
A
**V s\ — ^_JJ
t-^o
8
CM
T-l
^\ ^ , Lr^^, ^ ^j-sXV^v
12.4 12.6 12.8 13.0 13.2
Time (min.)
Mass 127.00
1.4:
1 2-
A»fc-
1 0-
|0.8-
-0.6-
>-
0.4:
0 2-
'.
0 0-
^VVr r _J
— fO
«o
CM
T-(
i~i ^j ~T-~I - i~ <~
12.4 12.6 12.8 13.0 13.2
Time (min.)
-------
Data File: /chen/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected : 1.0
46 2-Methy.lnaphthalene
Page 12
Column diameter : 0.32
Scan 1414 (14.240 min) of YP791.d
.
8.0-
^6.0-J
Ul
S4.0:
X
XX
"2.0-|
.„ i .,.•!. hi,,, u
40 60 80 100
. ,.,!
•
120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 1414 (14.240 min) of YP791.d (Subtracted)
8.0^
6.0-J
34.0-
X
XX
"2.0-
.1. i , .,1. nl „. ..i. .. .
#V |- r » i | i i- r [— i i T j i i
40 60 80 100
120 140 160 180 200 220 240 260 280
Mass/Charee
46 2-Methylnaphthalene (PBM Reference Spectrum)
8.0-
£•>
£_
34.0^
5.
2.0-
0 0-
,ii 1 1 ll, II Ih i,l , i
40 60 80 100
Scan 1414 (14
100-:
75-i
50 -i
25-5
!_2°j
"-50-;
-754
40 60 80 100
120 140 160 180 200 220 240 260 280
Mass/Charee
.240 min) of YP791.d (2 DIFFERENCE)
1 " ""•
120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 142.00
9.0-d
8.0-j
7.0^
6.0-:
555.0-i
^4.0-1
XX •
>- 3.0-1
2.0-f
1.0-j
0.0-^
|T§
1*
?
1 3
J
II
TV' M-
13.8 14.0 14.2 14.4 '14.6
Time (min.)
Mass 141.00
7.0-;
6.0-;
5.0-
^4.0-i
^3.0^
2.0-
1.0-
0 0-
1 •*
n °i
3
1
"^
*"*
{'
Jl. Jl,
u SJt r
13.8 14.0 14.2 14.4 14.6
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MH5-4-51
Column phase : DB-5
Volume Injected (uL) : 1.0
56 Acenaphthylene
Page 14
Column diameter : 0.32
Scan 1677 (16.132 rnin) of YP791.d
3.5-j
3.0-^
2.5-1
0.5-
0.0-
,i Lh
40
3.2
2.8
2.4
S1.6
-1.2
0.4
0.0
8.0-
rd
2.0-
0.0
40
lOOri
'-25H
'-50-j
-75-i
iii.jii.l[l.i.Jii
60
80
100 120
Mass/Charge
140
160
180
Scan 1677 (16.132 rain) of YP791.d (Subtracted)
40 60 80 100 120 140
Mass/Charge
160
180
56 flcenaphthylene (PBM Reference Spectrum)
60
100 120 140
Hass/Charge
160
180
Scan 1677 (16.132 min) of YP791.d (Z DIFFERENCE)
40 60 80 100 120 140 160 180
Hass/Charge
200
.. ,1. ,b lllll ..... -..]... .1. ,..!.
1 ,
1
1,
1 -t .
200
„, ,,l. .1)1, ,„,,, 1
1
200
1. ..J ...III ..J 1... .1 ll.
1 ,1 . ,r. 1 ...
200
Mass 152.00
in*
15.80 16.00 16.20 16.'40 16.60
Time (min.)
Mass 151.00
R
15.80 16.00 16.20 16.40 16.60
Time (min.)
Mass 153.00
15.80 16.00 16.20 16.40 16.60
Time (min.)
-------
Data File: /chen/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected
i ) S
ffiiss aS
li * li * * i | ^
V V V (fiV
^ UA N U
JL MMHla
W Kw V-m N ^ ^
16.00 16.20 16.40 16.60 16.80
Time (min.)
Mass 152.00
2.2-i
2.0-i
1 8-
1.6-i
1.4-j
pl.2-j
o :
^ o.s-i
0.6-i
0.4^
0.2-;
0 0-
•
Jg
*
. ^_Q
II ^7ll
L1"^* l^1 ^Jj] ' "^
(fiv A vfUj;
JWM^Wia
^jLiiP1 iy>^i-j^\
16.00 16.20 16.40 16.60 16.80
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected J.h.L.-r.,4..v,a.^
50 75 100 125 150 175 200 225 250 275 300 325 350
Hass/Charge
100-
75-j
50-j
25-!
Scan 1877 (17.574 min) of YP791.d (2 DIFFERENCE)
'-25^
'-50-j
-75-i
-100-Vr-r
J 11 M^HUI, j.lli .1. .jLi.Jl ,, I jUjilllJil j .1 11, ,
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Mass 166.00
2.8-
2.5-
2.2-
2.0-
3 1.2-1
0.8-:
0.5-^
0.0-
&
17.20
17.40 17.60
Time (rain.)
17.80 18.00
Mass 165.00
3.2-
2.8-
2.4-
2.0-
0.8:
0.4:
0.0-
17.20 17.40 17.60 17.80 18.00
Time (min.)
Mass 167.00
17.20 17.40 17.60 17.80 18.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected (uL> : 1.0
73 Phenanthrene
Page 17
Column diameter : 0.32
Scan 2157 (19.594 min) of YP791.d
2.8-3
2.4-!
2.0-i
31.6-;
^1-2-i
^0.8-;
0.4-i
[I I! Mill 1 1 II 1
ill. iLlLilllllLIIJu j. i.uiJ.>i,.ji,,iL ,, , . ]l iul .„. i. ...
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 2157 (19.594 min) of YP791.d (Subtracted)
2.8n
2.4-
2.0-1
£
Sl.2-
^0.8-
0.4-
0 0-
I
, .1 . ii i,.. „, . J . t
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
73 Phenanthrene (PBM Reference Spectrum)
•
8.0-j
-6.0-
f!
|4.0-
>-
2.0-
i
. ,. , J J . . .1 J
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 2157 (19.594 min) of YP791.d (Z DIFFERENCE)
100-
75-
50-
25-
fc 0-
e-25-
*t
-50-
-75-
,. J .,...,.11 „!.!.,. . *\1 .t t* ' "'t ..*«!*
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Mass 178.00
2.8-j
2.5-1
2.2-i
2.0-1
^1.8-j
?1.5-j
|l.2-i
^1.0-j
. 0.8-1
0.5^
0 2^
v.t .
0 0-
^
U)
1 a
CM
e
*
a
s1 S
i \ _j .
Illl s
VsA^VvVJk/^LllVMV^
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 179.00
6.0^
5.5-!
5.0-
4.5-i
4.0-
...S.S-i
S 3.o|
l °°
"*
1 'K i
I ^
^ i i
i
32.5| 1
>-2.0-=
1.5-;
i.o-i
0.5-j
A
k .1 H , j n\
l^Afl/NAJ
ipwy
• 1 M
IB /I J
111/, 1
v a II nftl N 'TJ
• ^ 1 M ' 1 ftll
1 ifl
H ui
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 176.00
4.8-=
4.4-E
4.0-^
3 6-
w* w .
3.2^
^2*4-
2 2*0 -^
^i]6j
Ifs
P
ii •<-*
J'
^
^£
i1 g.
i i o^A
11 • r ^-*ji
1 . | , J L ' r 1
n 111 finilll
If 1111 r 1 1| 'ii 1
19.20 19.40 19.60 19.80 20.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected (uL> : 1.0
74 flnthracene
Page 18
Column diameter : 0.32
Scan 2172 (19.702 min) of YP791.d
1.8-3
1.5-1
1.2-1
31.0-j
^0.8-;
^0.5-;
0.2-i
0.0-^
•
•
ll 1 1 1
III 1 1 In 1 1 1 1 1 1 1 III
ii iiilill i|illiil|li|ji!ililh4^ .ill, , i
iii|ii/]iii|iii]jii|iii^iiiryir^i|iii|i- * :
0.2:
0 0-
Scan 2172 (19.702 min) of YP791.d (Subtr
. ..Hull ,1, 1 ,,. .. .1 ..i 1. Jl 1 II, n
acted)
. i i
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
74 Anthracene (PBM Reference Spectrum)
8.0:
~6.0-
to
<
34*°:
5_
2.0-
fc
• 1
1 ..1 • - 1 -III
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 2172 (19.702 min) of YP791.d (2 DIFFERENCE)
100-q
75 -i
50-1
25-i
£ o-l
S-25-:
*« :
-50-j
-75-i
. . „ .1 ,. lll,.|ll ^ , ., 1 . 1 .,„! 1 1 II. . II .. 1 ,
1
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 178.00
a
2.8-.
2.5-j
2.2-j
2.0H
1.8-1
|l.5j
,x 1»'"-
>- 1.0-1
0.8-;
0.5-j
0.2-1
0 0-
f~s
1 ^
la
8
***"+
1 CF* \Q **f
If) 1 fi. O
Ko. ON .
i ai s^1
^^wvJwXJA^^
19.40 19.60 19.80 20.00
Time (min.)
Mass 176.00
4.8-1
4.4-J
4.0H
3.6-
3.2-i
P;2.8-i
o2.4r
^i\6\
1.2-=
0.8-!
0.4-i
Ort-
n§
n *
i
1 1 1 1 1
MI i
II Ml llillll 11 111
T-l
•
.j^ CM
Se ^°
& S
•j §/
I I 1 [S*M i
,1. JLIi '/yl ii
fffli nrn 1 ill
II 1 1 il 1 1 ft 1 Hi 1 rllfl
19.40 19.60 19.80 20.00 20.2C
Time (min.)
Mass 179.00
6.0-1
5.5-
5.0-=
4.5-=
4.0-j
Ss.o-i
32.54
^2.0-i
1.5-j
1.0-:
If)
rs i ?
1 "• 1 i 1
II ^ III J if
J
.1 , rt
J ll ... . ] 1
MNtU
:-:if,f,:;,!,
1 111 Jl I
1 9
111 111
n (If
19.20 19.40 19.60 19.80 20.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : D8-5
Volume Injected (uL) : 1.0
77 Fluoranthene
Page 11
Column diameter : 0.32
5.0-
4.0-i
-30-^
^ *
|2.o
^
i.O:
On»
.v
5.0:
4.0-
3 0-
5 * :
o
^2.0-
XX
"l.O-
Ofi-
.v
•
8.0:
ro * •
§4.0:
>. :
2.0:
100-;
75-j
50 -i
25 -i
<4- ftJ
<4- '
**-50-
-75-:
-1 rift »
I
i. ,
UJ
r i j -t \v}
50 7
I
JL Jj
j . f . n
50 7
i, i i , ,n, ,
50 7
I
1 L
ill -Jl. .Mill
50 5
Scan 2504 (22.095 min) of YP791.d
I
l^l|lll.|l|L|YJbj..J[l|.rrl,1. i|...i.^.Yi|.l|l^. . ;• -,| I ' J ' I \
5 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 2504 (22.095 min) of YP791.d (Subtracted)
1
,
VV if V 1 VVr"l r f 1 1 ' •'( 'IV 'If- r VI I ' i * I \
5 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
77 Fluoranthene (PBM Reference Spectrum)
.
,,!,, ,,,,,, ,,,,,1 ,,,,,, ,,
5 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 2504 (22.095 min) of YP791.d (Z DIFFERENCE)
.
IftiU *i i di 1 j nV- ,-- , , . j t A «•*— . • 1 i k .
1 ' JI
'5 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
3.2:
2.8:
2.4:
^2.0-
Sl.6-
^1«2-
0.8-
0.4-
On '
21
9.0-
8*°i
7.0-:
6.0J
-5.0^
o
34-°~
^3.0-
2.0-j
;
o'o1
y.u
21
4.8-i
4.4-j
4 0-
2 CJ
o.o .
3.2--
Q2.8-
S2.4^
3 2.0^
^ ;
1.6-:
0.8-i
0.4^
v»v
21
Mass 202.00
«
*
CM
CM
1
J
MvV\ Vl Aft AM
.60 21.80 22.00 22.20" 22.40
Time (min.)
Mass 101.00
i
I
II
III
j -
,i || |
!| I Jl| I
J j 1| V
f^jw' Y nj|
.60 21.80 22.00 22.20 22.40
Time (min.)
Mass 100.00
i
1
fl
I
-
1
a
CVJ 1 \
.x-^rv^^^x A-f-A***
.60 21.80 22.00 22.20 22.40
Time (min.)
-------
fiata File: /chem/Y.i/10-23-97.b/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB-5
Volume Injected : 1.0
78 Pyrene
Page 19
Column diameter : 0.32
3.2-;
2.8-;
2.4-;
xx2.o-;
Si.e-;
XX 1+Z~
>"0 8-
. • •
0.4-:
0.0-3
ll
ill
40
3.2-
2.8-i
2.4-^
2.0-=
•^
^1.6-
XX -^*^ -
"-o.s-i
0.4-i
«\.i
lT-1Mm
40
8.0:
~ 6.0-
m •
<
34.0-5
>- "
2.0:
0 0-
V.W | i
40
100-g
75-j
50-1
25i
S"25]
-50-
-75-E
40
Scan 2571 (22.579 win) of YP791.d
J
b 1 Jjil 1 i 1
•
i
• I
1
U i
>• 1, 1 ........ ,l> . L . ,
•T l"l"1 1 "i 'i t ' ' ' 1 ' ' • 1 • • ' 1 ' '
80 120 160 200 240 280 320 360 400
Mass/Charee
Scan 2571 (22.579 min) of YP791.d (Subtracted)
ill 1 JL,|..|...I| till. . . i. ... .1
.1.1 , 1 . ,,i , , , ,1. i.
* ' ' I * ' ' T ' ' ' 1 ' ' ' 1 ' ' ' ' '
80 120 160 200 240 280 320 360 400
Mass/Charee
78 Pyrene (P
- • ' J
BM Reference Spectrum)
80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2571 (22.579 min) of YP791.d (Z DIFFERENCE)
ll '
80 120 160 200 240 280 320 360 400
Mass/Charge
Mass 202.00
3.2-1
;
2.8-
2.4:
|~£
a
^2-4
? ]A
*» 1.6-1
•rH HI
•2 j]
*• * ~
0.8:
0.4:
:
i*»
0
1 °*
1
11
^AAJk^AAAA/f VAA A
22.20 22.40 22.60 22.80 23.00
Time (min.)
Mass 101.00
9 O-i
^*v .
8.0-i
7>0j
6.0-i
•^50-
S * ':
J4.0-
2.0-
1.0-j
kit ^
1 II CM ^
1 i
Jlltl
1
1
111
IT 11
fill
7
J
\rtwyiu.
\m vrnv v w
111 FlfVr 1 1 I\V
.0 i i | i i i | i i i i i • i | • • i | i
22.20 22.40 22.60 22.80 23.00
Time (min.)
3n
.2:
2.8:
2.4-
^2.0-
XX
0.8-
0 4-
v.t
0.0^
Mass 100
At «.j yi i/
.00
— m
to
•
i
8
1
1
\
J
Jb^oi\A/T7r . Y^ffMfri.1, U*/
22.20 22.40 22.60 22.80 23.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CAfl/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL) : 1.0
21 Cumene
Pace 13
Column diameter : 0.32
1.4-j
1.2-j
I0'8-!
^0.6-i
XX
=-0.4-:
0.2-=
0 0 '
,
ill
50
1.4-i
1.2-;
1.0-i
o * :
30.6-
>• 0 4-
:
0.2-;
n rt-i
I,
N
III
u»y • i
50
8.0:
~6.0-^
p> * •
<
^4.0-
XX
2.0:
0 0-
,L
|
II |
y
.1
1
Ihi
ll
Scan 641 (8.715 min) of YP791.d
1
i 1
k II 1 ,
75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
Scan 641 (8.715 min) of YP791.d (Subtracted)
V
1
1 1 i
..Illl I
i
. i ,
75 100 125 150 175 200 225 250 275 300 325
.... Jl
Mass/Charee
21 Cumene (PBM Reference Spectrum)
Jl
50 75 100 125 150 175 200 225 250 275 300 325
100-q
:
75-j
50-j
251
S-25-1
"-50-!
-75 -!
-100-
1
l*'l.fJ
Mass/Charee
Scan 641 (8.715 min) of YP791.d (2 DIFFERENCE)
...I
•Y--r' '
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
Mass 105.00
7.0-
6.0-
5.0-
^
g4.0-
-3.0-
>-
2.0-
1.0-
0.0-
I ^
1 °°
1
I
1
; il i \\ II d I\J
fxj JIU M M It ft
1 1 1 | 1 i 1 j ii i|ii ill IT i
8.4 8.6 8.8 9;0 9.2
Time (min.)
Mass 120.00
2.2-^
2.0-1
1.8-i
1 fi-
:
~ :
£> -
XX
0.6H
0.2-i
Oci-
•r-4
»•
i
1
1
1
l
III
I l
i n
ii n
8.4 8.6 8.8 9.0 9.2
Time (min.)
Mass 77.00
1.4:
1.2":
1.0-
XX
i°*8"
X
^0.6-
0.4-
|
I
I
\
\
1
s
? J
i A /^
0.2-/ 1 A .j. (\ . il L i
o o ' i 1 1 f¥ IM ! 'i \ 1 1 i iY \WJ X|
8.4 8.6 8.8 9.0 9.2
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CIWYP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected : 1.0
23 Phenol
Page 14
Column diameter : 0.32
2.0-1
-0.8-1
0.4-1
Ort-
.U-i
2.0-1
1.6-
|l.2-
3 0.8-
0.4-
LL
Scan 748 (9.476 min) of YP791.d
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Sc
1 1
II ,1,1 I n, ,
:an 748 (9.476 min) of YP791.d (Subtracted)
.. . .. L
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
8.0-1
g6'°-
34.0:
2.0-
0 0-
Kill,.,
23 Phenol (PBM Reference Spectrum)
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
100-
75-=
50-j
254
£ o-:
**-50-j
-754
Scan 748 (9.476 min) of YP791.d (Z DIFFERENCE)
.U.....JL...1 J..J.. .. . - ... 1.
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
2.2^
2.0^
1.8-i
1.6-i
1.4^
i * ~:
0.6H
0.4-i
0.2-j
Mass 94
.00
r-
'
9.00 9.20 9.40 9.60 9.80
Time (min.)
7.0-
6.0-1
5.0-
54.0:
o
^3.0-
2.0-
1.0-1
Mass 65
.00
-<3-
*
V.^.t/\* — , , — J \f
9.00 9.20 9.40 9.60 9.80
Time (min.)
8.0^
7.0-
6.0^
^5.0-1
2.0-:
i.o-;
0 0-
Mass 66
.00
9.00 9.20 9.40 9.60 9.80
Time (min.)
-------
•Data File: /chem/Y.i/10-23-97.b/CflfVYP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL) : 1.0
29 1,4-Dichlorobenzene
Page 16
Column diameter : 0.32
Scan 857 (10.253 win) of YP791.d
1.8-j
1.5-1
1.2-j
Si.o-i
30.8-j
XX
J
.11
I
>. o 5- ill j|
°:*PJL LI
o.o-3
•illllllijiil Ilil 1
i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 857 (10.253 win) of YP791.d (Subtracted)
1.2-=
1.0-i
80.6-i
x :
>lo.4-j
•
0.2-i
0.0-
+
, i
i
. 1 ..r, 1 1, ,
i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
29 1,4-Dichlorobenzene (PBM Reference Spectrum)
8.0-j
•
? * '
<
-------
Data File: /chem/Y.i/10-23-97.b/Cflfl/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL> : 1.0
31 2-Hethylphenol
Page 17
Column diameter : 0.32
8.0-:
7.0-1
6.0-j
S55*H
*3.o-i
1::
I I I
4
U.U | i i
40
5.0-;
4.0-;
fo3.0-
o
£2.0-
"~1.0-
0 A-
, h
40
8.0-^
Z * "
2.0-
Oft-
• i
80
|j
i
80
,L
40
100-
75-;
50 -j
25-
£ Or
« -25-!
"-50-
-75-
-1ftft-
rr
40
80
h
f
80
Scan 915 (10.667 min) of YP791.d
III i II
120 160 200 240 280 320 360 400 440 480
Mass/Charee
J^.
Scan 915 (10.667 min) of YP791.d (Subtracted)
1 1
120 160 200 240 280 320 360 400 440 480
Mass/Charge
31 2-Methalphenol (PBM Reference Spectrum) •
120 160 200 240 280 320 360 400 440 480
Mass/Charee
c
r
Scan 915 (10.667 Bin) of YP791.d (Z DIFFERENCE)
t ' ' '
120 160 200 240 280 320 360 400 440 480
Mass/Charee
6.0-
5.0-
-4.0-
5°
3 3.0-
XX
^2.0-
1.0-
M
Hi
ass 101
i
3.00
u
1
\\
—*a
*.
o
"
1), I
10.20 10.40 10.60 10.80 il.OO
Time (min.)
5.0-
4.5H
4.0-
3.5-
-3.0-
i2^
^2.0-
*"i.s-i
1.0-i
0.5-
Mass 77.00
• §«
|j vjl
I
10.20 10.40 10.60 10.80 11.00
Time (min.)
4.8-
4.4-^
4.0-
3.6-;
3.2-:
-2.8-
g2.4-
>-1.6-
1.2-i
0.8-
0.4-
0 0-
Mass 90.00
CVJ
Lg
bint lii
J
10.20 10.40 10.60 10.80 11.00
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/CAft/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL) : 1.0
32 3/4-Methy.lphenol
Page 18
Column diameter : 0.32
3.2-
2.8-i
2.4-=
~2.0-f
Si. 6-:
3l.2-j
0.4-i
,
2 8J
*.» v .
2.4-j
^2.0-:
?1 6^
^H •
Srf* A*^ •
*-0.8-i
0.4-j
•
•
8.0-
~6 0-
P5 * •
2 . . •
34.0-
._
2.0-
• V
100-
75-
50-
25-
«4- 0-
<^
S-25-
^-50-
-75-
inrt
i
i I
ILkuLuj
* * * * * * ^
40 80
Sea
J
(Lk4^
\ ' ' ' I ' ^
40 80
-UJ
T '
40 80
Scar
J J-|Lj •_ ,_ _,
r T> \
40 80
Scan 957 (10.966 min) of YP791.d
J ,
120 160 200 240 280 320 360 400
Mass/Charee
n 957 (10.966 min) of YP791.d (Subtracted)
..1.
120 160 200 240 280 320 360 400
Mass/Charee
!2 3/4-Methylphenol (PBM Reference Spectrum)
120 160 200 240 280 320 360 400
Mass/Charee
i 957 (10.966 min) of YP791.d (2 DIFFERENCE)
i . 1 i
120 160 200 240 280 320 360 400
Mass/Charee
:
6.0-!
5.0-;
•
ro '.
33.0-;
*•« ^:
2.0-
1A
*o~
V»V
3.6H
.
3.2-i
:
2.4^
,
52.0-
s
31.6-
"1.2-i
*
0.8-^
0.4-i
OA
.u
:
1.8--
1.6-i
1.4-j
1.2-i
^i.o-j
"><0 8-^
>_ i
0.6-:
0.4-:
0.2^
0.0-
Mass 108.00
'
I
»
i Ml!!1^
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 107.00
IPO
ff^
s
/\«^A A *AlV^ AA*J
i I i i i I 'i 'TTI T T»r i '|lqF
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 79.00
(1
ll
GO II
« 1
O II
I j'
111
" 1
^ 1 III J 1 I II
a I , I
I'AJI I ll U 1 lu
10.60 10.80 11.00 11.20 11.40
Time (min.)
-------
Data Filej /chem/Y.i/10-23-97.b/ClWYP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected : 1.0
33 flcetophenone
Page 19
Column diameter : 0.32
•
8.0:
.
6.0-
o . •
£ * •
*~2 0:
\
,
40
8.0-
xx6-°"
|j4.0-
X
*~2.0-
,
.
ll,
40
8.0-
~ 6.0-
ro
o :
34.0-
^.
2.0-
fl 0-
40
100-q
75-
50 -.
25-
rt '
(4-
s-25-
"-so-i
-75-
.
40
MM
nl
80 i;
..-.jj
LU..J
Scan 960 (10.988 min) of YP791.d
I
>0 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 960 (10.988 min) of YP791.d (Subtracted)
so i:
i
80 L
.
20 160 200 240 280 320 360 400 440 480
Mass/Charge
33 ftcetophenone (PBM Reference Spectrum)
20 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 960 (10.988 min) of YP791.d « DIFFERENCE)
* a-m m * -
r
i
["'
80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 105.00
1.2-1
1.14
1.0-=
0.9H
0.8H
£0.7-;
^0.51
0.3-i
ft OJ
o.i-i
i
J
1
•I
III
If
I~-QO 1— -flP
\m iS
fl * n *
o K o
11 ^H II v-4
S
1 II PO IH
] GO | iHro i
• h ^K ft
S 1 i ^ ll
^
*
JrUlAi/Ul/
10.60 10.80 11.00 11.20 11.40
Time (rain.)
Mass 77.00
9.0-
8.0-;
7.0-i
6.0^
55.0:
o '
34.0-
^ :
3.0-
2.0-
1.0-
0
J1
I §.
i
o
1
1
S II fl>
o fl ^IM
1 'r*r1
ft /I1?
I M
tf Nl i) li i/ l\i
*
*~*
1 i
HI t
s
ll /
(Ji — nJ/ UJ/ 1 Uf i i — a/
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 120.00
2.2J
2.0-;
10 •
.OJ
1.6-^
1.4-
n.2-
31.0:
A Q-
0.6-
0.4-;
0.2-
0 0-
m
*
S
,,,A
S5
I •
S ft ^
°* II
ro TH II
o ' $ 1
, J ^1
11 1 5^
7i'
M ll 1 1 fl I
I
lUIIN
S
10.60 10.80 11.00 11.20 11.40
Time (min.)
-------
flata File: /che«/Y.i/10-23-97.b/CAft/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL) : 1.0
43 1,2,4-Trichlorobenzene
Page 25
Column diameter : 0.32
Scan 1191 (12.641 nin) of YP791.d
7.0-d
> + v «
6.0-1
5 0-^
iJ.V .
p4.0-|
3 ^ o-
_>< * :
5-2.0--
i.o-i
0.0J
i i
Ii i|Llk Jl
40 60
*
, J
I ' I
80 100
Ihl
1 .1.1. J
II,
1 '
120 140
i i | i i i | i • i | i
160 180 200
Mass/Charee
Scan 1191 (12.641 min) of YP791.d (Subtracted)
60-
*V .
5.0-i
^4.0-;
s3*°i
X
5-2*0"
i.o-i
0.0-
nil, .L...1L j|
40 60
1
.„,
1 ' * ' 1
80 100
ll 1
' '. '
.1 .
1 1 ' ' i
120 140
11
• • I > i i | • i > I i
160 180 200
Mass/Charee
43 1,2,
8.0:
£n * •
I4'0:
>_
2.0:
I
,, ..ll.M ., ,11
*U~ | i i i | i i
40 60
4-Trichlorobenrene (PBM Reference Spectrum)
1,. ,
80 100
1. T . J
120 140
.1
160 180 200
Mass/Charee
Scan 1191 (12.641 win) of YP791.d (Z
100-g
75 -i
50-i
•
25-i
s-25J
~-50-i
-754
-100-
, J.I.. ...,l,..,.JL.^r
40 60
-
1.
U. i
J
80 100
-I
... J... .a
1 ... ...,.
I
120 140
DIFFERENCE)
. r
160 180 200
Mass/Charee
Mass 180.00
1.0-:
:
0.9^
;
0.8-:
0.7-i
xxO.6-1
?" :
0.3-i
0.2-i
O.lT
0 0-
— «H
cJ
rH
8
3
a
i
1
.
I i\
12.2 12.4 12.6 12.8 '13.0
Time (min.)
Mass 145.00
3.6-j
3.2-!
2.8-i
2.4-;
^2.0-
^516-
0.8^
0.4-
0.0-
1
, . | 13
1
1 j|
i 111
II 1 fl III
SH I 11 II 1
Ml
l
11 '
iifl
j^ '
I
11 U i i
12.2 12.4 12.6 12.8 13.0
Time (min.)
Mass 109.00
8.0-1 1
7 0~
6.0-:
.
00
5.0- 1 3 II
^, J a
O 4»vT| | II (SI
"S< "1 i / II S
^3.0-j
2.0-
1.0-
1 ft J «
I r I 1 1 r \n 1 'r
,Ai., Mlu Uftl \![dl
ftJiMljWiV Vkfv r1 r u wv
n iifw N"*li— J ' u '^LJ
00; , ,,II, ,, ,, 1,,,
12.2 12.4 12.6 12.8 13.0
Time (min.)
-------
'Data File: /chem/Y.i/10-23-97.b/Cftfl/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-HM5-4-51
Column phase : DB.5-625
Volume Injected (uL> : 1.0
60 Biphenyl
Page 33
Column diameter : 0.32
4.0-j
3.0-
1 :
|2.0-
*~1.0-
0.0-
i
.Ii]
1 1 . 1
Scan 1550 (15.218 min) of YP791.d
*
ll 1
II 1 1 1 Jl
50 75 100 125 150 175 200 225 250 275 300 325 350
4.0:
^3.0:
|2.0^
XX
"i.o-
A fl-
j
V»V ii ii
50
8.0-
S)6*0"^
£
^4.0-;
>_
2.0-
§
1,
50
100-:
75 -j
50 -I
25i
5-25-1
**-50-j
-75-i
-1ftrt-
50
Mass/Charee
Scan 1550 (15.218 min) of YP791.d (Subtracted)
I
' {•!• V Ir/'ll'i 7
75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
60 Biphenyl (PBM Reference Spectrum)
'
,„,,.., I,,-,,,,,
75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 1550 (15.218 min) of YP791.d (Z DIFFERENCE)
•
|
1 I
75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Mass 154.00
4.4-!
4.0-i
3.6-!
3.2-!
2.8-i
|2.ji
«**• *
^1.6-i
1.2-i
ft gj
0.4-i
c3
a
en
o "J
if) **
*"* '
.' ft » F
. A JK../V, JWV/
14.8 15.0 15.2 15.4 - 15.6
Time (min.)
Mass 152.00
7.0n
6.0-
5.0-
^4.0-
o
33.0-
j.
2.0-
1.0-
0.0-
1
in
•rH
.
n
,J
CM 1 ?
If) J 1 •
*HI 1 If)
nil 1 f
m A. /
/ A AJ
^ I VvrM \rAV W
1 | f l l rT"T | * I T-| T1 I | I I
14.80 15.00 15.20 15.40 15.60
Time (min.)
Mass 155.00
3.0^
2.8-
2.5-1
2.2-1
2.0-i
p * i
S 1.2-i
0.8-
0.5-
0.2-
0 0-
CM
S
*
lf>
*-< 1
i
K
ft
CO II
§
i 7
» I 1
s ft
1 JL JL J I
. »i. j-w. jWWwlL/ W
14.8 15.0 15.2 15.4 15.6
Time (min.)
-------
•Data File: /chem/Y.i/10-23-97.b/Cftft/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL> : 1.0
61 Dimethylphthalate
Page 34
Column diameter : 0.32
Scan 1637 (15.844 min) of YP791.d
:
2.0-
1.8-
1.5-i
S1-0-!
-0.8-
1
i
.
.
-o.5i.il I .1 1 1 il 11,1
0.2-i
0.0-3
1 iw^whU
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 1637 (15.844 min) of YP791.d (Subtracted)
2.0-f
1.8-1
1.5-1
Sl.O-l
3 0.8-1
"0.5-j
0.2-j
,
.1. 1...I . .1 ill- 1.1.
iilllL 1,1 i
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
•
8.0:
-6.0-
<° -
|4.0:
>.
2.0-
0.0-
61 Dimethylphtha
I ! 1 4 j
late (PBM Reference Spectrum)
I 1
1 i • • • • i • • • • i • • • • i • • ' • i ' ' • • i • • ' ' i • • • • i •
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 1637 (15.844 rain) of YP791.d (Z DIFFERENCE)
100-
75-
50-
25-
<*. o-
5-25-
*>t
-50-
-75-
100
....... -lr- •!«•' — «-• i-,-I..J.Jjl.Vr. U 1 .if. -0.8-l
0.6-;
0.4-:
0.2-I
n rt :
W# v
f?5
*
^
»
AA
xjixy^
t yr
s.
II m
i J
'VUJ
1
i. 1
*"* r
i i
I . J\J H
V if ^f^Y"^ Vl—J1>vvJ'
[ -I r"r | . • , | . . . , . i T i . .
15.40 15.60 15.80 16.00 16.20
Time (min.)
Mass 194.00
1.4:
•
1.2:
1.0:
SO 8^
o
3 0.6:
0.4-
o.2:
OA
.V
1
O
a
5.40 15.60 15. (
to
CO
§'"
.
r-l
^
1?
30 16.00 16.20
Time (min.)
Mass 164.00
5.0-|
4.5-ji
4.0-j
3.5-1
:
^3.0-:
rO
<
S2.5-:
1.5-j
2-i
5
T li
I
j ii
\\
\\ \
III
i.o-li \ | fy^
0.5| JM
o o V \\ 'i''i | i i i [
^.
GO
a*
i
i
1 00
k ^
iHiM I
1™
15.40 15.60 15.80 16.00 16.20
Time (min.)
-------
Data File: /chem/Y.i/10-23-97.b/Cftfl/YP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected : 1.0
65 Dibenzofuran
Page 38
Column diameter : 0.32
2.0:
1.6:
:1.2:
^0.8:
0.4-
0.0-
8.0-
!4.0-
0.0-
100-
75-1
50-j
25-i
5£ 0-!
»-25-l
"-50-I
-75-i
-100-
Scan 1777 (16.853 min> of YP791.d
I
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Scan 1777 (16.853 min) of YP791.d (Subtracted)
r^
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
65 Dibenzofuran (PBM Reference Spectrum)
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Scan 1777 (16.853 min) of YP791.d (2 DIFFERENCE)
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Mass 168.00
16.40 16.60 16.80 17.00 17.20
Time (min.)
Mass 139.00
16.40 16.60 16.80 17.00 17.20
Time (min.)
-------
Oata File: /chen/Y.i/10-23-97.b/CftlVYP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL) : 1.0
66 Di-n-butylphthalate
Page 39
Column diameter : 0.32
Scan 2321 (20.776 win) of YP791.d
1.8-:
1.5-^
1.2-j
£1.0-!
^ =
30.8-:
^o.s-i
0.2-1
.
.JiiiA...,,..,.,. i ...A.L.. ..„.
50 75 100 125 1!
•
50 175 200 225 250 275 300 325 350
Mass/Charee
Scan 2321 (20.776 min) of YP791.d (Subtracted)
1.8-3
I
1.5-j
1 9-
*. + £. -
Sl.O-j
|0.8-|
^o.s-i
°*2i
0.0-=
• i
, , | / , 1 , f , , , , , 1 , , 1 1 , , , /
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
:
8.0-^
-
x, 6.0-
ro
< J
§4.0-5
>-
2.0:
0.0-
66 Di-n-butylp
J I/1 1 f ' \ J-
hthalate (PBM Reference Spectrum)
| i
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Scan 2321 (20.776 win) of YP791.d (2 DIFFERENCE)
100-:
75i
50-j
254
«4- 0™
t»- :
S-25i
-50-:
-754
100 :
r--,r - ...--.-
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Mass 149.00
1.8-j
1.6-i
1.4^
;
1.2:
-10^
?* ' :
^0.8:
>-0.6-^
0 4-
v.*t t
0.2:
J-JS
§
I
. J U. ..
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 150.00
1.4-j
1.2-
•
i.O:
"~"0 8-
< * •
o
TH
0 4-
v»*t
0.2-
Oh-
. ^Q
1 o*
j
I j . n j . 1 ** J
L>J
1
i
\ . i A A ..I
ill/'VAil An/^ift/y ijMJ MUiiM^rt^iJ
Vw Uw/VV 1 I nW/VT/rVVn/
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 104.00
8.0-j
7.0-i
:
6.0-;
^s.oi
<° :
24.0-
T-l ^*v .
X ;
^3.0-i
2.0-i
1 0-
-l.V H
0 0-
n=
^
-
j
A * ,n
f ..... 1
WmjAifcW Ujittnl^l,iiik
V 'YlWl Inilnml
. , . J.u! . .If. .IMiii J 1
20.40 20.60 20.80 21.00 21.20
Time (win.)
-------
* Data File: /chem/Y.i/10-23-97.b/Cfl(VYP791.d
Date : 23-OCT-97 16:00
Instrument : Y.i
Sample ID : SO-MM5-4-51
Column phase : DB.5-625
Volume Injected (uL> : 1.0
83 bis(2-Ethylhexyl)phthalate
Page 47
Column diameter : 0.32
Scan 2954 (25.341 min) of YP791.d
1.6-J
1.4-1
1.2-j
l.O-'
LO
^o.s-i
So.e-i
"-0.4-i
0.2-i
i i
lil^i,.-. .
•
. I ..
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Scan 2954 (25.341 min) of YP791.d (Subtracted)
1.6-a
1.4-i
1.2-i
1 0-
go^
30.6-:
>-o.4-;
0.2-j
0.0-3
• •-;
1 • • T 1 • • ' 1 • '
V T T-T-1 -
1 ' • ' 1 • ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' 1 ' '
40 80 120 160 200 240 280 320 360 400
Mass/Charee
83 bis(2-Ethylhexyl)phthalate (PBM Reference Spectrum)
.
8.0-^
~ 6.0^
34-°~
>- '.
2.0-
I I . . 1, I 1 . .
1
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Scan 2954 (25.341 min) of YP791.d (2 DIFFERENCE)
100-:
75-=
504
254
fc
-------
, ' •-•-;. :,vt!4Xlf
Project Number: 43433
Sample File: YP775
Client Pi»|€^St]giA*rti-.MI -"'5;
"". \ f "• . . v \ ""
-. : : {-. -._£. v. "v.
,->: : "" ^J^|t^t>Vf%, ^
ll A -.-s-, v^ ':-\«r^ v o. ^
; >\'$&J"Vi\ ^'"•••.^.C }\
Wrt&^Vv*
1 s ••- \ '•'•'•.*'
. .A v ^\ . -s /•"•
v- ""^ v ^'^ o\^l$-A:
;-"->-/ ,i- -^%;^
!x^x ^ ^j^^l^
ISt^;;
\^~- *"*• ?<$ s %s> '
^^'^-.^ ^ S >X i
Method 8270A MM5
Sample ID: FBI-MM5-1
\ V * -"f; *' -Oa& Eecftlved.: i
' V *• "• "^1. 1 "^ ""t ^lL%ik \
Dilution Factor:
«BBW;*^V*"
11^7^ ^ *?
idis^4 ^1
1.00
•••• -.-. %%^. >,>•"«*
' •. sx , •fv.tto^ %iy
^^fv;i
*•**' '-.v^r:;>;>
Naphthalene-d
8
Naphthalene
2-Mediylnaphthalene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Andiracene
Fluoranthene
Chrysene-d
' 12
Pyrene
Benzo(a) anthracene
Chrysene
Perylene-d
' 12
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
-•"^IfllfSS
IS 2
5.85 BJ
0.52 ]
IS 3
U
U
U
U
IS 4
0.13 ]
U
U
IS 5
U
U
U
IS 6
U
U
U
U
U
U
U
U
p:.'.;:tw
12.77
12.81
14.25
16.42
19.54
19.59
25.28
29.41
*u^v,/y;
0.40
0.25
0.42
0.41
0.31
0.29
0.26
0.30
0.30
0.24
0.23
0.22
0.25
0.23
0.22
0.29
0.24
i^?j
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 09:53 11/13/1997^
-------
Project Number 43433
Sample File: YP775
Method 8270A MM 5
Sample ID: FBI-MM5-1
Dilution Factor: 1.00
Phenol-d
Nitrobenzene-d
1,3,5-Trichlorobenzene-d
1,4-Dibromobenzene-d
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
to
Pyrene-d
Terphenyl-d
66.16
61.74
60.34
68.04
71.51
92.50
90.07
86.70
107.63
9.45
11.30
11.98
12.87
15.01
18.07
19.66
22.54
22.90
1
2
2
1
3
3
4
5
5
66
62
60
68
72
92
90
87
108
Reviewed by.
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv33
Printed: 0953 11/13/1997
-------
S % s •• ' ^^ O N ^ ? ^1
! , •.^^ XN'^t v s '•»'$$?'' ••'
Project Number: 43433
Sample File: YP775
Client Proj ech Saginaw, MI
' ^> >;*T>i
^ ; ^H?%^7 ^ ^ <•' •&.\ "•' ' - '•<«$'#' \s< ^\ 4*
^*^^ld^li£uS; ^''^'
f^^^^£S!^f * "]<«
*^ *• y^ *• ^ '% ^ yfe*''
i •• ^J% VH ^&;
Method
Sample ID:
Resjwmse File
^f:'; f f
i^s^i
8270A MM5
FBI-MM5-1
sYEjTlV:. I
* % ^ V 's^
Dilution Factor: 1.00
, - ^-^ £ ,vS«^~~vt*i^
„ v ^£6?t*v%$s
1 ,4-Dichlorobenzene-d
n-Nitrosodimediylamine
Cumene
Phenol
Aniline
bis-(2-Chloroethyl)ether
Benzyl Chloride
1 ,4-Dichlorobenzene
2-Mediylphenol
Acetophenone
n-Nitrosomorpholine
o-Toluidine
Hexachlo methane
1 ,2-Dibromo-3-chloropropane
N.N-Diethylaniline
Naphthalene-d
3/4- Methylphenol
Nitrobenzene
N,N-Dimethylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlorobutadiene
a,a,a-Trichlorotoluene
Hydroquinone
f\> *^^$^^*™*JgZ£t'*^ •."•£•'££, x;u; '•-^•^i
:SS^^^x5$^"fe\ v ^^
IS 1 10.22
U
U
3.22 J 9.47
U
U
U
0.43 J 10.26
U
3.78 BJ 10.99
U
U
U
U
U
IS 2 12.77
U
U
U
U
U
U
U
U
U
U
1.44
0.39
0.52
1.11
0.40
0.82
1.44
0.52
1.35
1.43
0.49
0.83
0.52
0.53
0.44
0.95
0.69
0.80
1.37
0.65
0.71
fffii
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:42 11/13/1997
-------
- , %" Y-"% ^ <•
1 > - -,i-^*^"" -v.
'reject Number: 43433
Sample File: YP775
nientProjecfc Sagirtaw,MI
bu ID: 18&t7-lA-0 r *^> * s^\
1 -,,-•• - ^ -v
-i.% ,
1
\cV^ci&^^*o»«t|iil^t Sewiw
•. •. ^f^- ^^X- X ^v. X %v ••"'' •••••*' % ^.
^
Dilution Factor 1.00
,^^f||:;:^^'/-
Method 8270A MM5
Sample ID: FBI-MM5-1
\ \\u^Ri%iti«e>^S^^P37tV^
CV-N. / ^;^ ^:w\-^,- , i
% %•. f"CSf»^ %%^* <.« $ % *\.\ *'^*m *v ^ N»^ '•
- ^ - r\"-« * ,* \s ,SS*^^VV^ i
r^r>'-^^S
.-Chloroacctophenone
Acenaphthene-d
•lexachlorocyclopentadiene
~,4,6-Trichlorophenol
2,4,5-TrichIorophenol
liphenyl
Dimediylphthalate
1,4-Dinitrophenol
1-Nitrophenol
2,4-Dinitro toluene
Dibenzoruran
i,6-Dinicro-2-methylphenol
Trifluralin
'henanthrene-d
10
Di-n-butylphthalate
Hexachlo ro benzene
i-Amtnobiphenyl
Pen tachlo ro phe nol
'entachloronitrobenzene
i-Nitrobiphenyl
Chrysene-d
ienzidine
4,4'-Methylenedianiline
Dimediylaminoazobenzene
l,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
§i^^g^f^
U
IS 3 16.42
U
U
U
U
3.32 J 15.84
U
U
U
U
U
U
IS 4 19.54
3.41 BJ 20.78
U
U
U
U
U
IS 5 25.28
U
U
U
U
U
0.35 10
1.34 10
1.22 10
1.06 10
0.33 10
10
4.70 25
1.79 25
1.38 10
0.30 10
3.05 25
2.22 10
10
0.88 10
0.38 10
1.68 25
3.55 10
0.96 10
0.44 10
1.02 10
0.88 10
0.55 10
1.13 10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; J: Estimated- Below Quantitation
Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
"01 Capitola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:42 11/13/1997
-------
Project Number: 43433
Sample File: YP775
Method 8270A MM5
Sample ID: FBI-MM5-1
aient Project: Sagirtaw, MI
Dilution Factor: 1.00
^^^ttTTv.^ -
JJ-V ' t^ *< Sl " '";<-
"• <• -.v. •• --^ * ^ %5 v
3,3'-Dichlorobenzidine
Methylcne bis-chloroanilinc
bis(2-Ethy!hexyl)phthalate
U
U
21.61 B
0.74
1.68
25.36
10
10
10
Reviewed by.
Date ll
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:42 11/13/1997
-------
Data, file: /chem/Y.i/10-22-97.b/YP775.d
Date-: 22-OCT-97 19:06
Instrument : Y.i
Sample ID : FBI-HH5-1
Column phase : DB-5
Volume Injected (uL) : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0.32
Page 9 CO
CD
f
. . r-
/chem/Y.i/10-22-97.b/YP775.d (Part 1 of 2)
6.6-i
6.4-i
6.2-;
5.8-i
5.6-;
5.4-j
5.2-i
5.0-!
4.8-i
4.4-i
4.2-!
4.0-i
3.8-1
3f *
.(>-.
xx _ . !
— ;
0 -
£V
O Q)
BB
QQ
-------
Data f,ile: /chem/Y.i/10-22-97.b/YP775.d
Date < 22-OCT-97 19:06
Instrument : Y,i
Sample ID : FBI-H15-1
Column phase : DB-5
Volume Injected
-------
Data File: /chem/Y.i/10-22-97,b/YP775.d
Report Date: 23-Oct-1997 11:43
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type:
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-22-97.b/YP775.d
43433
22-OCT-97 19:06 Autotune Date: 22-Oct-97 09:14:0
DD Inst ID: Y.i
FBI-MM5-1
185-7-1A-D
/chem/Y.i/10-22-97.b/cclist.m
23-Oct-1997 11:29 target
22-OCT-1997 11:59 Cal File: YP766.d
13
1.000 Target Version: Target 2.20
HP RTE Compound Sublist: pah.sub
AIR
CONCENTRATIONS
Compound*
* 1 l,4-Dichlorobenzene-d4
* 2 Naphthalene-d8
* 3 Acenaphthene-dlO
* 4 Phenanthrene-dlO
• 5 Chzyiene-dl2
* 6 Pezylene-dl2
$ 7 2-71uorophenol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 I*2-Dichlorobenzene-d4
$ 11 Nitrobenzene-d5
$ 12 l,3,5-Trichlorobenzene-d3
$ 13 l,4-Dibromobenzene-d4
$ 14 2-Pluorobiphenyl
$ 15 2.4,6-Tribromophenol
$ IS Anthracene-dIO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
42 Naphthalene
46 2-Methylnaphthalene
50 2-Chloronaphthalene
56 Acenaphthylene
58 Acenaphthena
65 rluorene
73 Phenanthrene
74 Antbr»c«n«
77 Tluoranth«n«
78 Pyr«n«
83 Banzo(«)anthrmc*n*
84 Chry««n«
86 B«nzo(b)fluoranth*n«
QUANT SIQ
MASS RT (REL RT)
152.00 10.220(1.000)
136.00 12.767(1.000)
164.00 16.419(1.000)
188.00 19.543(1.000)
240.00 25.280(1.000)
264.00 29.409(1.000)
Compound Hot Detected.
99.00 9.453(0.925)
Compound Hot Detected.
Compound Hot Detected.
82.00 11.300(0.885)
185.00 11.983(0.939)
239.80 12.867(1.259)
172.00 15.010(0.914)
329.80 18.070(1.101)
188.00 19.665(1.006)
212.00 22.537(0.891)
244.00 22.902(0.906)
128.00 12.810(1.003)
142.00 14.247(1.116)
Compound Not Detected.
152.00 16^98(0.999)
Compound Not Detected.
178.00 19.593(1.003)
202.00 22it90 (0 .0331
Compound Hot Detected.
Compound Hot Detected.
Compound Not Detected.
ON- COLUMN
RESPONSE
451015
1574677
905865
1341363
1210767
1760521
1265141
921129
810054
748761
2003232
569785
3183532
3154323
2534736
241772
13020
fill
4478
14 OS
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
66.17
61.73
60.34
68.06
71.52
92.51
90.05
86.70
107.67
5.85
0.52
9.J7
0.13
"0.04
FINAL
( ug>
66.17
61.73
60.34
68.06
71.52
92.51
90.05
86.70
107.67
5. 85 (a)
0.52(a)
0 - 17 ( afl) x
0.13(aQ)
Qly
O.IUlaU/
Data Review:
Date:
-------
Data File: /chem/Y.i/10-22-97.b/YP775.d
Report Date: 23-Oct-1997 11:43
Page 2
Compound*
QUANT SIO
MASS
XT (RE. RT)
COHCCHTRKrXOHS
OH-COLOMH FINAL
RESPONSE ( ng) ( ug)
87 Benzo (k) f luoruthene
88 Benzo (•) pyrene
89 B«nzo (a) pyr«n«
90 P«ryl«n«
91 Ind«no(l,2,3-od)pyr*n*
92 Dib«nz(«,h)»nthr»c«n«
93 B«nio(g,h,i)p«ryl»n«
QC Flag Legend
Compound Hot D«t«ot»d.
Coapound Hot Detected.
252.00 29^*fl*4*T*O
252.00
5925
Hot D«t«ot*d.
Conpound Hot Detected.
Coapound Hot Detected.
a - Target compound detected but, guantitated amount
Below Limit Of Quantitation(BLOQ) .
Q - Qualifier signal failed the ratio test.
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP775.d
Report Date: 23-Oct-1997 09:07
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
REPORT
SEMI-VOLATILE QUANTITATION
/chem/Y.i/10-22-97.b/CAA/YP775.d
43433
22-OCT-97 19:06 Autotune Date:
DD Inst ID: Y.i
FBI-MM5-1
185-7-1A-D
22-Oct-97 09:14:0
Sample Type: mm5
/chem/Y.i/10-22-97.b/tlicaa.m
23-Oct-1997 08:05 target
22-OCT-1997 15:55 Cal File: YP771.d
13
1.000 Target Version: Target 2.20
HP RTE Compound Sublist: CAAl.sub
CONCENTRATIONS
Compound!
* 1 1,4 Dichlorobenzene-d4
* 2 Naphthalene-d8
* 3 Acenaphthene-dlO
• 4 Phenanthrene-dlO
* 5 Chzy*ene-dl2
• 6 Perylene-dl2
$ 7 2-Pluorophenol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 l,2-Dichlorobenzene-d4
$ 11 Nitrobenzane-d5
$ 12 l,3,S-Trichlorobenzene-d3
$ 13 !<4-Dibromobenzene-d4
$ 14 2-Fluorobiphenyl
$ 15 2,4,6-Tribromophenol
$ 16 Anthracene-dIO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
20 n-Nitroaodimethylamine
21 Cumene
23 Phenol
24 Aniline
27 bia-(2-Chloroethyl)ether
28 Benzyl Chloride
29 1,4-Dichlorobenzene
31 2-Methylphenol
32 3/4-Methylphenol
33 Acetophenone
34 n-Nitroaomorpholine
35 o-Toluidina
36 Haxachloroathana
QUANT SIO
MASS RT (REL RT)
152.00 10.220(1.000)
136.00 12.767(1.000)
164.00 16.419(1.000)
188.00 19.543(1.000)
240.00 25.280(1.000)
264.00 29.409(1.000)
Compound Hot Detected.
99.00 9.453(0.925)
Compound Hot Detected.
Compound Hot Detected.
82.00 11.300(0.885)
185.00 11.983(0.939)
240.00 12.867(1.259)
172.00 15.010(0.914)
329.80 18.070(1.101)
188.00 19.665(1.006)
212.00 22.537(0.891)
244.00 22.902(0.906)
74.00 t.73tfn ut62)
Compound Hot Detected.
94.00 9.475(0.927)
Compound Hot Detected.
146.00 10.255(1.003)
108.00 11.370 (8.891)
105.00 10.986(1.075)
Compound Hot Detected.
ON- COLUMN
RESPONSE
451015
1574677
905865
1341363
1210767
1760521
1265141
921132
810054
748761
2003232
569785
3183532
3154323
2534736
22711
50400
6664
~2Tt
64637
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
71.18
60.26
63.16
68.70
71.13
103.80
84.31
77.62
100.38
3.27 .
3.21
0.42
1 0.01
3.77
FINAL
( ug)
71.18
60.26
63.16
68.70
71.13
103.80
84.31
77.62
100.38
1 17- f D
3.21
0.42
0.01
3.77
~? F
Data Review:
Date:
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP775.d
Report Date: 23-Oct-1997 09:07
Page 2
Compounds
QUANT SIO
MASS
RT (REL RT)
CONCBNTRATIONS
ON-COLUMN FINAL
RESPONSE ( ng) ( ug)
37 Nitrobenzene Compound Not Detected.
38 N,N-Dimethylanilina 120.00 Ili3»7 10 . 882) I5T5 OrO* -O.08
39 l,2-Dibromo-3-chloropropane Compound Not Detected.
40 Icophorone 82.00 11.393(0.8911 mflS Q-A9 n.AI,
41 o-Ani«idine Compound Not Detected.
42 1,4-Phenylenediamine Compound Not Detected.
43 1,2,4-Trichlorobenzene Compound Not Detected.
44 Naphthalene 128.00 12.810(1.003) 241772 6.61 6.61
46 Hexachlorobutadiene Compound Not Detected.
47 N,H-Diethylaniline 134.00 12_.J67 (1.2491 136919 s.ett 6. fin f=-
48 a,a,a-Trichlorotoluene Compound Not Detected.
49 Hydroquinone 110.00
51 2-Chloroacetophenone 105.00 13,»SS(1.03ir
52 Hexachlorocyclopentadiene Compound Not Detected.
53 2,4, 6-Trichlorophenol Compound Not Detected.
54 2,4,5-Trichlorophenol Compound Not Detected.
60 Biphenyl 154.00 IS . M3 (0 .01«) STSS 0.09 0.88
61 Dimethylphthalate 163.00 15.842(0.965) 86325 3.31 3.31
62 2,4-Dinitrophenol Compound Not Detected.
63 4-Nitrophenol 139.00 M1613 (1.013) 1479 81*6 *-.2f~
64 2,4-Dinitrotoluene 165.00 1^411C1 """? 119891 • 16.J8 16^38
65 Dibenzofuran Compound Not Detected.
66 Di-n-butylphthalate 149.00 20.776(1.063) 175808 3.41 3.41
67 4, 6-Dinitro-2-methylph.no! 198.00 1&-J63 (1.1881 3«W 9-r«2 B-rW
68 Trifluralin Compound Not Detected.
69 Hexaehlorobenzene Compound Not Detected.
70 4-Aainobiphenyl Compound Not Detected.
71 Pentachlorophenol Compound Not Detected.
72 Pentachloronitrobenzene Compound Not Detected.
73 4-Nitrobiphenyl Compound Not Detected.
74 Benzidine 184.00 22.537(0.8911 31568,
75 4,4'-Hethylenedianiline Compound Not Detected.
77 Dim.thylaminoazob.nz.il. 120.00 23-r902 (0.89O— 488*5 3.Si 3 .52.
78 3,3'-Dimethylb.nzidin. Compound Not Detected.
80 3,3'-Dimethoxybenzidine Compound Not Detected.
81 3,3' -Dichlorobenzidine Compound Not Detected.
82 Methylene bia-chloroaniline Compound Not Detected.
83 bi«(2-Kthylh.xyl)phthalat. 149.00 25.359(1.003) 617438 21.61 21.61
f P ACCtJ-
-------
Data File: /chem/Y.i/10-22-97.b/YP775.d
Date : 22-OCT-97 19:06
Instrument : Y.i
Sample ID : FBI-MH5-1
Column phase : DB-5
Volume Injected : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
Scan 1218 (12.810 min) of YP775.d
1.4-i
1.2-i
i.o-i
£>0.8-i
^0.6-i
XX
0.2-i
..I...I. il. ll .. Mill ..... . . .1
...
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
1 A-
l.*f .
1.2-i
1.0-i
£0. 8-
30.6-i
^0.4-
0.2-
0.0-
Scan 1218 (12.810 min) of YP775.d (Subtracted)
1 .1 i, • i ,-• i •
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
42 Naphthalene (PBM Reference Spectrum)
•
8.0:
s6'1
3 4.0:
>.
2.0-
0.0-
,.
i' i' -i'l I'i'i • • •
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Scan 1218 (12.810 min) of YP775.d (Z DIFFERENCE)
100-:
75":
50-j
25-!
. i
«£ .
s-25-i
**-50-j
-754
100-
'•' '' ' '''I' ' 'I'1'1 1' ' '
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Mass 128.00
1.4:
1.2-
1.0-
|o.8:
So.6-
>.
0.4-
0.2:
0 0-
!S
CJ
7
A
L
OO
*
a
12.40 12.60 12.80 13.00 13.20
Time (min.)
Mass 129.00
1.6-j
1.4:
1.2-i
1.0-
XX
o0.8-i
X
XX .
^0.6-
0.4:
0.2:
0 0-
1 JH
a
II i-4
,
8
^ 1
y
A
1. ,
12.40 12.60 12.80 13.00 13.20
Time (min.)
Mass 127.00
1.8-i
1.6-
1.4-
XX •
ri.o^
o
£0.8-
^0.6-i
0.4-;
0.2^
0 0-
|~?
I a*
O
ro
OJ 1
"
,
A
1 1
1
A
/v A , lly^ »
12.40 12.60 12.80 13.00 13.20
Time (min.)
-------
Data File: /che»/Y.i/10-22-97.b/YP775.d
Date : 22-OCT-97 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB-5
Volume Injected of YP775.d
8.0-
2.0-
4
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charge
Scan 1420 (14.247 min) of YP775.d (Subtracted)
8.0-
6.0-
0.0-
-MW,
k
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charge
46 2-Methylnaphthalene (PBM Reference Spectrum)
8.0-
|4.0-
""2.0-
0.0-
ll,,,,,!!,,,',,!!.,,!',!!!',,,,,',!.
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charge
100
75
50
25
£ 0
«-25
~-50
-75
-100
Scan 1420 (14.247 min) of YP775.d (Z DIFFERENCE)
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charge
Mass 142.00
9.0
8.0
7.0
6.0
3^.0:
2.0-i
1.0-
0.0
13.80 14.00 14.20 14.40 14.60
Time (min.)
9.0r
8.0-i
7.0-i
6.0-!
S4.0^
2-°1
l.Or
Mass 141.00
0.0^
13.80 14.00 14.20 14.40 14.60
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/YP775.d
Date : 22-OCT-97 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB-5
Volume Injected (uL> : 1.0
73 Phenanthrene
Page 15
Column diameter : 0.32
Scan 2171 (19.593 min) of YP775.d
.
8.0-|
:
fn * •
34-°-
*"2.0:
ll
III ill i ill III 1 him ih i ii 1 1 ii
juu, — i I" 'i — P-H1 — i" 1 i1 "i 1 — i ' I ' 'I 'i1 i 1 I i~^ i 1
I I
ll
' ' I
40 60 80 100 120 140 160 180
Mass/Charee
-
3.2-i
2 8-
fc.O .
2J -
.4-
fo2.0-|
S1.6-!
^o'.a-i
0»4-i
Scan 2171 (19.593 min) of YP775.d (Subtracte
1 i
i ii i
ll
, ill llllll 1 ll , ,1 .1 1,
d)
,
,,
40 60 80 100 120 140 160 180
Mass/Charge
73 Phenanthrene (PBM Reference Spectrum)
8.0:
6 0-
P> '
<
34.0-
j.
2.0-
0 0-
i
,
. , , ,,l ,ll . Ill .
40 60 80 100 120 140 160 180
Mass/Charee
100-
75 -1
50-i
25-i
s-25-i
~-5o4
-75-i
Scan 2171 (19.593 min) of YP775.d (Z DIFFERD
1
n 1 1 i
.. ll Jl, ,,lll ,|| 1, 1 k 1 i, 1
ICE)
-i
40 60 80 100 120 140 160 180
Mass/Charee
200
200
200
200
Mass 178.00
2.8-j
2.5-1
2.2-i
2.0-j
fo1*^
i ID
n *
r
3*1 ||^
^i!o-j
0.8--
0.5-1
0.2-!
0 0-
i .
lv_l
1 1
1 II
11
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 179.00
1.8:
1.6-
1.4-
"
1.2:
-1.0-^
2 :
3°*8"
^0.6:
0.4:
0.2:
•
0 0-
ro
in
*~* II
i |||
1 1 1
1 | HI
|
|| |
11 111 1
|| 1 1 1] |
III III
III 1 1 1 II III
19.20 19.40 19.60 19.80 20.00
Time (min.)
Mass 176.00
1.4-
1.2-
1.0-|
^0 j
<° * :
'xO.6-
^ * :
o.4:
0.2-j
0 0-
~s?
r-t
1
1
ft
II
19.20 19.40 19.60 19.80 20.00
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/CfWYP775.d
Date : 22-OCT-1997 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB.5-625
Volume Injected _
2.0-
0.0-
1 , I
ill Jlh ,1,1 .
I . 1 1 1 1 . , 1 . .
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 749 (9.475 nin> of YP775.d (Z DIFFERENCE)
100-
:
75-j
50-i
£2°j
S-25-:
*< -
-50-E
-75-j
100 :
-ir''(r'"n" '"' r -'*' '"
1
. ill .. 1 . \— M . 1
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 94.00
3.6H
•
3.2-j
2.8-i
2.4-i
g2.0-j
2ii
0 8-
v*o t
0.4T
0.0-
j
i ' • • i * • • i •
~R
•*
ON
IY * +
9.00 9.20 9.40 9.60 9.80
Time (min.)
Mass 65.00
1.2-j
1.1-i
1.0-
0.9-j
0.8-j
^06-
20.5-
»- 0.4-1
0.3-
0.2-
0.1-
1— -4f)
1 •&
5
A A M n 1
Li k ** rt A
9.00 9.20 9.40 9.60 9.80
Time (min.)
Mass 66.00
3.6-3
3.2-1
2.8-i
!
2.4-;
52.0-j
S^j
;
0.8-^
-
0.4^
0.0-
r^.
II ^
1 f
i
. )t . . 4 ...,«.,
9.00 9.20 9.40 9.60 9.80
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/Cfifl/YP775.d
Date : 22-OCT-1997 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB.5-625
Volume Injected : 1.0
29 1,4-Dichlorobenzene
Page 9
Column diameter : 0.32
Scan 859 (10.255 min) of YP775.d
6.0-^
5.0-i
xx4.0-i
I3'°i
1.0-j
0.0J
4
illlllllnfl
10 80 120
1 1
160 200 240 280 320 360 400
Mass/Charge
4.0:
.3.0-
ro
S2 0-
x *w
XX
"1.0-
0.0-
t
Scan 859 (
111
tO 80 120
10.255 min) of YP775.d (Subtracted)
1 1
160 200 240 280 320 360 400
Mass/Charge
29 1,4-Dichlorobenzene (PBM Reference Spectrum)
-
8.0:
3 4.0-
^2.0-J
0.0-
„ ,..!,. 1,..
40 80 120
*
160 200 240 280 320 360 400
Mass/Charee
100-q
75-^
50-=
251
S-25-!
"*-50r
-75-:
-100-
Scan 859 (10.255 min) of YP775.d « DIFFERENCE)
L , ,|i l| I
1 f
40 80 120 160 200 240 280 320 360 400
Mass/Charee
Mass 146.00
4.4-i
4.0-;
3.6-i
3«2i
1.2-i
0.4-!
0.0-3
9
118
^
J
.80 10.00 10.20 10.40 10.60
Time (min.)
Mass 148.00
2.8-j
2.5-i
2.2-!
2.0-j
1.8-1
5s 1.5-1
O -
x 1*2~
x-l.Or
0.8H
0.5H
0.2-:
0.0J
c
'
.80 10.00 10.20 10.40 10.60
Time (min.)
8.0-i
7.0-i
6.0-i
5 0-:
<° :
XX
2.0-:
-
0.0-:
c
Mass 113.00
§
,,,,,... .P. .i^... .4
1.80 10.00 10.20 10.40 10.60
Time (min.)
-------
Data File: /che»/Y.i/10-22-97.b/CflA/YP775.d
Date : 22-OCT-1997 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB.5-625
Volume Injected
,
40 50 60 70 80 90 100 110 120
Mass/Charee
100-:
75 -j
50-i
25-
t. f\^
<£ ^
3-25-i
*4
-50-j
-75-
Scan 962 (10.986 min) of YP775.d (Z DIFFERENCE)
.1. , ,i 1
40 50 60 70 80 90 100 110 120
Mass/Charee
1.4:
l.O:
go.8-:
306^
>• ' :
0.4:
0.2:
0 0-
Mass 105.00
fo
^0 [o
'o *H .
A Sx ^^
A • li ^
s ft * ;
AjtHAl
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 77.00
1
1.1-:
i.o-i
0.9^
0.8-!
•^ :
^0.6^
^o'Ji
0.3^
0.2-i
0.1-j
I
r**- II
a
^* I
i
i
I
|
-
°^
- s
S '
0* |
,,n,/ui
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 120.00
Q 0-
o.v .
7.0^
6.0-j
5.0-j
fo :
^< * :
^3 0-
*"2'0j
1.0-=
0 0-
^?
»
. s
r*^ ^^
ro
CO
*
o
1
1
II <5
1 "^ '-'
i ^
1 ^H 1
.1 1 1 flu
10.60 10.80 11.00 11.20 11.40
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/QWYP775.d
Date : 22-OCT-1997 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB.5-625
Volume Injected (uL> : 1.0
61 Dimethylphthalate
Page 22
Column diameter : 0.32
Scan 1644 (15.842 min) of YP775.d
5.0-d
4.0:
^3.0-
o :
32*°J
*~1 0-
, ,1
lLl.ll.-ii
'
1 ,
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1644 (15.842 min) of YP775.d (Subtracted)
5.0H
4.0-
g3.0:
§2.0:
~ :
1.0-
0 0-
I
-iAl i
1 ,
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
61 Dimethylphthalate (PBM Reference Spectrum)
J
8.0:
xv 6.0-
ro
j_
•$ 4.0:
>_
2.0-
0 0-
, L ii , ,i
.
1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1644 (15.842 win) of YP775.d (2 DIFFERENCE)
100-
75-i
50-i
25-
fc 0-
S-25-
"-50-
-75-
r*—^ L- ^ r*. •- . ^ L .f . .. r • L i • i i * .
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 163.00
d
4.Q-.
4.4-.
4.0^
3.6-;
7 2-=
w*fc .
52.8-i
I2-4"!
*" 1 C. -
l.b-
1.2-i
0 8-^
V.Q .
0.4-1
0 0-
I "*
11 ^~*
»**
f\. r-*
15.40 15.60 15.80 16.00 16.20
Time (min.)
2.4-
2.2-j
2.0-=
1.8-=
1.6-^
^1.4-j
^1.2-:
3 i.o^
=-0.8-!
0.6-!
0.4^
0.2-!
0 0-
Mass 194
.00
oo
in
'H
1
1
I
. . . 1 . ...
15.40 15.60 15.80 16.00 16.20
Time (min.)
4J —
*^—
4.0-i
3.6-
3.2-f
2.8^
<^ .
32.0-!
>-i.6-i
0.8-;
0.4-i
Mass 164.00
I— CJ
1 s
I
1 i
1 ll
a
i ii ii
y
15.40 15.60 15.80 16.00 16.20
Time (min.)
-------
Data File: A*en/^. i/10-22-97.b/Cflfl/YP775.d
Date : 22-OCT-1997 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB.5-625
Volume Injected : 1.0
66 Di-n-butylphthalate
Page 25
Column diameter : 0.32
Scan 2337 (20.776 min) of YP775.d
8.0-
6.0:
^
34.0-
X
XX
"2.0-
0 0-
.jltl. jl,lLi..l,ULl_jJ.^lJj_Jl li. i
•
i i i
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
Scan 2337 (20.776 min) of YP775.d (Subtracted)
8.0-
.
6.0:
34.0-
-X.
"2.0-
0 0-
L .1 .. i.
• ---.- . . i
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charge
8.0:
-.6.0-
ro •
3 4.0-
XX
*~2.0:
66 Di-n-butylphthalate
.
•.I.. ,...ll i i. i li i..
(PBM Reference Spectrum)
1 II
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
Scan 2337 (20.776 min) of YP775.d (2 DIFFERENCE)
100-
•
75-
50-i
251
£ H
»-25-:
"*-50-j
-75-1
100 :
i
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charge
Mass 149.00
9.0-d
8.0-i
7.0-!
6.0-i
-~5.0-
|4.0-|
=-3.0^
2 0-
fc*" .
i.o-:
0.0^
ips
Is
j
u. ......
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 150.00
9.0^
8.0-;
7.0-^
6.0-i
N>5.0-:
o -
^4.0-
XX
2.0-i
1.0-f
0 0-
•
I
At ,
A H i/
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 104.00
6.04
5.5-j
5.0-1
4.5-
4.0-i
p;3.5-
o3.0-
32.5-
*-2.0-
1.5|
i.o-IL J
0.5|U 1 |
~o8
§
L 1 1
11 iiu
20.40 20.60 20.80 21.00 21.20
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP775.d
Date : 22-OCT-1997 19:06
Instrument : Y.i
Sample ID : FBI-MM5-1
Column phase : DB.5-625
Volume Injected (uL) : 1.0
83 bis(2-Ethylhexyl)phthalate
Page 29
Column diameter : 0.32
:
2.0-1
1.8-i
1.5-i
£1.2-=
< :
I 0*"
*o.e-i
*-0.5-j
0.2-j
0.0J
1
1
.«, , •)!
Scan 2979 (25.359 min) of YP775.d
II
..JI-L -1- • 1. • .-
i i
40 60 80 100 120 140 160 180 200 220 240 260 280
2.0-j
i a-=
* :
1C "
•51
£l.2-i
Sl.O-i
*0.8H
^0.5-j
0 2-=
V*£. •
0.0-3
.
.
1
Mass/Charee
Scan 2979 (25.359 min) of YP775.d (Subtracted)
11 ,
i i i i | i i i | i i i i i i i | i ., ... ,...,...,...,...,...,
40 60 80 100 120 140 160 180 200 220 240 260 280
8.0-j
~6.0-
g i
J4.0-
>-
2.0-
0 0-
|
1 i
Mass/Charee
83 bis(2-Ethylhexyl)phthalate (PBM Reference Spectrum)
ll
. . JL 1, i. ll .. .
•
1
40 60 80 100 120 140 160 180 200 220 240 260 280
100-
75-j
50-j
254
sr o4
3-25-j
-754
Mass/Charee
Scan 2979 (25.359 min) of YP775.d (Z DIFFERENCE)
-
-v -i if - •-• •• •"
40
60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 149.00
2.2-
2*°-i
1.8-j
1.6-j
1.4-j
£1.2-1
Sl.O-
•2 :
0.6-!
0.4-j
0.2H
0.0^
-i— ~*t— < J-
~~LO
3
CM
U ,—
. . 1 1 . 1 1 1 1 1 1 . . . 1 . . , , .
25.00 25.20 25.40 25.60 25.80
Time (min.)
Mass 167.00
6.0-
5.5J
5.0-
4.5-j
4.0-i
x>. 3.5-
^3.0-:
32.5-
1.5-
1.0-
0.5-
0.0-
J-£
i '°-
sa
1
A. f f ., V M. - /• r
25.00 25.20 25.40 25.60 25.80
Time (min.)
-------
.V^ ?\C'v' ~" "< V&V *" ' t
Project Number 43433
Sample File: YP774
Method 8270A MM5
Sample ID: LAB BLANK-MM5-28
Client Project: Sagittaw^ MI ' '^'
" ' * ^
" '' V >* ,*',.* *V^ *«' \% ^' \X
Naphthalene-d
Naphthalene
2-Mcthylnaphthalene
Acenaphthene-d
2-Chloronaphthalene
Accnaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)anthracene
Chrysene
Pcrylene-d
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
: *: Dati Received: 09/29/97 .
;° '/^^^l&^
Dilution Factor: 1.00
IS 2 12.76
U
U
IS 3 16.42
U
U
U
U
IS 4 19.55
U
U
U
IS 5 25.28
U
U
U
IS 6 29.40
U
U
U
U
U
U
U
U
;>\;^^M(K»ifelita:
ijx* ^''""" v^
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
Savarv3.5
Printed: 09:53 11/13/1997
-------
I
Project Number 43433
Sample File: YP774
Method 8270A MM5
Sample ID: LAB BLANK-MM5-28
Clien
NlDt
w, MI
i-^XiST \ V .""*• \ "• •• ' . -. \ S\s.. -Xs •• x*s •» v* % •?^'.xv^s ^ % "^\t^
J^J&fati^lMMX;; ' ;_ -:«r _ v,\"-:» ^f
I
Dilution Factor: 1.00
s ^ ' V ' -'' \ C^ % '* % ^-.^ s "%% ' "
Sitttto04ie SttaiiftSiiijf, ^ \ v % •* ^ % 'f* -A
- " ^ ; / -...5...
Phenol-d
5
Nitrobenzene-d
5
1 ,3i5-Trichlorobenzene-d
3
1 ,4-Dibromobenzene-d
4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
' 10
f %J. ^ ^ \
feSHS.-.
69.13
74.18
62.82
74.39
71.68
91.27
91.72
97.11
* % "" ' RT -
5 ' «V* * 4 •• *
, *. - \
','-. *$.-. 5
9.45
11.29
11.98
12.87
15-01
18.07
19.66
22.54
^XSBfcC^
1
2
2
1
3
3
4
5
•&t^\ ' » -%'%K!3C% v :
% ^ % \ * ^ % < •, s ,\\ ;
69
74
63
74
72
91
92
97
Reviewed by.
Date 11 /
NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544r5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 09:53 11/13/1997
-------
- , V //;:<;,/ x, " l^itV C
% <• \ *• .. ' % - W* ^ :|L*$. s^sr ^ 1^^->^|^
T^-?^^l!*;w*II?:t5o^^'7^\^*^
,vV:iy °^Vs4Vv^
^;^fx^i§8S>^
!lAT^g|f^ I i
v %VxS?!^'"^ \%\>vW \>Nv% ^ %
Method 8270A MM5
Dafeleceived: 0^29/97
; 'P^^fi^ei 48m$5
Sample ID: LAB
> , ,^f^R^^HW«
"^ "^•%^?* * -.''^ •• '"*
'/.'^'J^.V ^
BLANK-MM5^28
s^feYFra,:^ - I
5' ^4-V •• **s ''''^' -^" '
1 5t^ ^SM, i
Dilution Factor: 1.00
ArialyW \ , , -" < .. ,\ ;* ^-; \* - ™:\ ^7^
,;- s "\-" ^ ^ ^ ;% ° Kft^UiS
1 ,4-Dichlorobenzene-d
n-Nitrosodimethylamine
Cumene
Phenol
Aniline
bis-(2-Chloroethyl)ether
BenTyl Chloride
1 ,4-Dichlorobenzene
2-Mediylphenol
Acetophenone
n-Nitrosomorpholine
o-Toluidine
Hexachloroethane
1 ,2-Dibromo-3-chloropropanc
N,N-Diethylaniline
Naphthalene-d
3/4-Methylphenol
Nitrobenzene
N,N-Dimethylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlorobutadiene
a,a,a-Trichlorotoluene
Hydroquinone
..^ f. jfit+.t'^^l'\-w' *f£f AJ^' % ^ ""•'•" 'J *** s/ j>**y •,
fjlf ^•y^jl fxi v |* • . y iyujT^rM*" ^ "• •* v \"3f^
-------
I
5.-5J -.-. «* vv./^ V^™
^ ;->- * >,(^ s •. .* .:'?.3tt.\'._.?.\.-.
Pfcciifcl
Rjr||^rUal JSemces, ^>v^^>^Xv|?^\^M§^v,f f&i
•* \v% * %^ ^ •• x -* v vy>».'S. x^ \^ >•: *>. iS-^>^j *&.'•£.•?...' ^ ' :
Project Number: 43433
Sample File: YP774
Method 8270A MM5
Sample ID: LAB BLANK-MM5-28
Client Project: Sagirta>
[IU ID: l£5-7-6A«€^ ;?
" " '%t|?
1
' •• •• ••^•^
p* ^ ^ ^^^
2-Chloroacetophenone
Acenaphthene-d
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Biphenyl
Dimediylphthalace
2,4-Dinitrophenol
4-Nitrophenol
2,4-Dinitrotoluene
DibenzoFuran
4,6-Dinitro-2-methylphenol
Trifluralin
Phenanthrene-d
10
Di-n-butylphthalate
Hexachloro benzene
4-Arninobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Benzidine
4,4'-Methylenedianiline
Dimediylaminoazo benzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
'^Ml-/-\ fe, DklK««6lvea 1&&19SF - ; V " *!
•*' "--r f % •* .. ''^t J1- <• ^i? t X*.S s^ •- "" % <
^;;g^v v^^l^j^W^ VS- \
}>,; /4, &r* ^ -- P^ jygpBj^d'? "J&fi&t^ , : ;^ ; x x ;
Dilution Facton 1.00
: ^ ', '-£\ rAJ^a^^ ^MAd^—^'^RT' f^- -^0A
';^^%^; ^ - v^v .^.;..*. % V ^..^
U
IS 3 16.42
U
U
U
U
1.14 J 15-84
U
U
U
U
U
U
IS 4 19.55
29.02 B 20.78
U
U
u
u
u
IS 5 25.28
U
U
U
U
U
ieSp^nseiPIiei"
^t'Llvtx^
"*^:5§™*o >'4$R
tiMt^ ^---^C
a^:.xsN»/:lxC
0.41
1.44
1.31
1.14
0.36
5.05
1.93
1.48
0.32
3.27
2.39
0.96
0.41
1.82
3.84
1.04
0.54
1.26
1.08
0.67
1.39
&m^y?N
^^Y
^^^>x
i««a*I^wlt ]
\..:.^i... : 1
10
10
10
10
10
10
25
25
10
10
25
10
10
10
10
25
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
Savarv3.5
-------
Project Number 43433
Sample File: YP774
Method 8270A MM5
Sample ID: LAB BLANK-MM5-28
Dilution Factor: 1.00
3,3'-Dichlorobenzidine
Methylenc bis-chloroanilinc
bis(2-Ethylhexyl)phthalate
U
U
1.19 BJ
0.91
2.06
25.35
10
10
10
Reviewed by.
^ClU" Date »l
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:41 11/13/1997
-------
Data,file: /chem/Y.i/10-22-97.b/YP774.d
Date •: 22-OCT-97 18:18
Instrument : Y.i
Sample ID : LftB BLANK-MH5-28
Column phase : DB-5
Volume Injected : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter ; 0,32
Page 9
^
-±.00
/chem/Y. i/10-22-97.b/YP774.d (Part 1 of 2)
4.0:
3.8:
3.6:
3.4:
3.2:
3.0:
2.8:
2.6:
2.4:
"
2.2-
XX
\O
32.0:
>< .
^i.s-;
1.6:
1.4:
1.2:
l.O:
0.8:
0.6:
0.4:
0.2:
f
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^
JLl ^
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1 g U
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'
,
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1
C
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g
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b =
s '
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i
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5 6 7 8 9 10 11 12 13 14 15 16 1
Time
-------
Data File: /chem/Y.i/10-22-97.b/YP774.d
Date :• 22'OCT-97 18:18
Instriment : Y.i
Sample ID : LAB BLANK-MM5-28
Column phase : DB-5
Volume Injected (uL) : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0.32
Page 10
00
4.0-
3.8:
3.6:
3.4:
3.2:
3.0:
2.8:
2.6:
2.4:
2.2-
XX •
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1.6:
1.4:
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0.6:
0.4:
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•
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.
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21 22
XX
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XX
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23 24 5
/chem/Y.i/10-22-97.b/YP774.d (Part 2 of 2)
3 ff)
CM §
• »
g g
CVJ CM
^j T"j
(0 •— i
CJ ft
1 1
'
'
1
1 A ILjL ^L^^- -n H— V-JW-^, ^^_,,.Jv.irJK_urni..-l „,
L ^^^^^J^^^^JW-~^KA**-~*~^'^ •«v«-m«v«A5 26 27 28 29 30 31 32 33 34 35
-------
Data File: /chem/Y.i/10-22-97.b/YP774.d
Report Date: 23-Oct-1997 11:38
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Hisc Info
Comment
Method
Heth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-22-97.b/YP774.d
43433
22-OCT-97 18:18 Autotune Date: 22-Oct-97
DD Inst ID: Y.i
LAB BLANK-MH5-28 •
185-7-6A-C
09:14:0
/chem/Y.i/10-22-97.b/cclist .m
23-Oct-1997 11:29 target
22-OCT-1997
12
1.000
HP RTE
11:59
Sample Type: AIR
Cal File: YP766.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
Compounds
* 1 l,4-Dichlorobenzan«-d4
* 3 Naphthalene-d8
* 3 Acenaphthene-dlO
* 4 Phenanthrane-dlO
* 5 Chry«ene-dl2
* 6 Perylene-dl2
$ 7 2-Pluorophenol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 l,2-Dichlorobenzene-d4
$ 11 Nitrobenzene-d5
$ 12 l,3,5-Trichlorobenzene-d3
$ 13 l,4-Dibromobenzene-d4
$ 14 2-71uorobiphenyl
$ 15 2,4,6-Tribromoph.no!
$ 16 Anthracene-dIO
$ 17 Pyrene-dlO
$ 18 Tarph«nyl-dl4
42 Naphthalene
46 2-Hethylnaphthalene
50 2-Chloronaphthalene
56 Acenaphthylene
58 Xcenaphthene
£5 Fluorene
73 Phenanthrena
74 Anthracene
77 Fluoranthene
78 Pyrene
83 Benzo(a)anthracene
84 Chryaene
86 Benzo(b)tluoranthane
QUANT SIQ
MASS RT (RBL RT)
152.00 10.224(1.000)
136.00 12.762(1.000)
164.00 16.421(1.000)
188.00 19.549(1.000)
240.00 25.276(1.000)
264.00 29.403(1.000)
Compound Not Detected.
99.00 9.451(0.924)
Compound Not Detected.
Compound Not Detected.
82.00 11.294(0.885)
185.00 11.982(0.939)
239.80 12.869(1.259)
172.00 15.010(0.914)
329.80 18.066(1.100)
188.00 19.663(1.006)
212.00 22.539(0.892)
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
ON-COLDMN FINAL
RESPONSE ( ng) ( ug)
433631 40.00
1322956 40.00
842411 40.00
1241220 40.00
985400 40.00
1189592 40.00
1270989 69.14 69.14
929888 74.18 74.18
708495 62.82 62.82
787094 74.42 74.42
1867470 71.70 71.70
522817 91.27 91.27
2999871 91.70 91.70
2875514 97.12 97.12
2336 U.US U.US lag)
*•)??*#.£
Data Review
Date:
-------
Data File: /chexn/Y.i/10-22-97 .b/YP774.d
Report Date: 23-Oct-1997 11:38
Page 2
Compounds
Q0ANT SIS
MASS
BT (MEL RT>
CONCBRKATXONS
OH-COLUMN FINAL
RBSPONS1 ( ng) ( ug)
87 Benzo(k)fluoranthene
88 Benzo(•)pyrene
89 Benzo(a)pyrene
90 Perylene
91 Indeno(l,2,3-cd)pyrene
92 Oibcnz («,h) anthraocn*
93 B*nzo(g,h>l)paryl*n«
QC Flag Legend
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Hot
Hot
Not
Hot
Hot
Hot
Hot
D«t«ot«d.
D*t*et«d.
Detected.
Detected.
Detected.
Detected.
Detected.
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP774.d
Report Date: 23-Oct-1997 09:04
Page 1
TRIANGLE LABORATORIES, INC.
REPORT
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type:
22-Oct-97 09:14:0
SEMI-VOLATILE QUANTITATION
/chem/Y.i/10-22-97.b/CAA/YP774.d
43433
22-OCT-97 18:18 Autotune Date:
DD Inst ID: Y.i
LAB BLANK-MM5-28 '
185-7-6A-C
/chem/Y.i/10-22-97.b/tlicaa.m
23-Oct-1997 08:05 target
22-OCT-1997 15:55 Cal File: YP771.d
12
1.000 Target Version: Target 2.20
HP RTE Compound Sublist: CAAl.sub
mm5
CONCENTRATIONS
Compound*
* 1 lf4 Dichlorobenzene-d4
• 2 Naphthalene-dS
* 3 Aeenaphthene-dlO
• 4 Phenanthrene-dlO
* 5 Chry«ene-dl2
* 6 Perylene-dl2
$ 7 2-Pluorophenol
$ 8 Phenol-d5
$ 9 2-Chloroph«nol-d4
$ 10 l,2-Dichlorobenzene-d4
$ 11 Nitrobenzene-d5
$ 12 l,3,S-Trichlorob«nzen«-d3
$ 13 l,4-Dibromob«nz«ne-d4
$ 14 2-Pluorobiphenyl
$ 15 2,4,6-Tribromophenol
$ 16 Anthracene-dIO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
20 n-Nitroeodimethylamine
21 Cumene
23 Phenol
24 Aniline
27 bis-(2-Chloroethyl)ether
28 Benzyl Chloride
29 1,4-Diehlorobenzene
31 2-Methylphenol
32 3/4-Methylphenol
33 Acetophenone
34 n-Nitroeomorpholine
35 o-Toluidine
3 6 Hexaehloroethane
QUANT SIO
MASS
152
136
164
188
240
2S4
99
82
185
240
172
329
188
212
74
94
.00
.00
.00
.00
.00
.00
Compound
.00
Compound
Compound
.00
.00
.00
.00
.80
.00
.00
Compound
.00
Compound
.00
Compound
Compound
Compound
Compound
Compound
Compound
Compound
56*00
Compound
Compound
10.
12.
16.
19.
25.
29.
Not
9.
Not
Not
11.
11.
12.
15.
IB.
19.
22.
Not
4.
Not
Not
Not
Not
Not
Not
Not
Not
Not
Not
RT (RBL RT)
224(1.000)
762(1.000)
421(1.000)
549(1.000)
276(1.000)
403(1.000)
Detected.
451(0.924)
Detected.
Detected.
294(0.885)
982(0.939)
869(1.259)
010(0.914)
066(1.100)
663(1.006)
539(0.892)
Detected.
it* (n *«3)
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
ON-COLUMN
RKSPONSB
433631
1322956
842411
1241220
985400
1189592
1270989
929888
708495
786727
1867470
522817
2999871
2875514
138'j''
(
40
40
40
40
40
40
74
72
65
75
71
102
85
86
3.
ng)
.00
.00
.00
.00
.00
.00
.38
.41
.75
.08
.31
.41
.85
.94
T&7
FINAL
( ug)
74.38
72.41
65.75
75.08
71.31
102.41
85.85
86.94
3.07
Data Review:
Date:
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP774.d
Report Date: 23-Oct-1997 09:04
Page 2
Compounds
QUANT SXQ
MASS
RT (RKt RT)
CONCENTRATIONS
ON-COLUMN FINAL
RZSPONSC ( ng) ( ug)
37 Nitrobenzene
38 N.H-Dimethylaniline
39 l,2-Dibromo-3-chloropropane
40 laophorone
41 o-Anisidine
42 1,4-Phenylenedianine
43 1,2,4-Trichlorobenzene
44 Naphthalene
46 Hexachlorobutadiene
47 N,N-Diethylaniline
48 a,a,a-Trichlorotoluene
49 Hydroquinone
51 2-Chloroacetophenone
52 Hexaehloroeyclopentadiene
53 2,4,6-Trichlorophenol
54 2,4,5-Trichlorophenol
SO Biphenyl
£1 Dimethylphthalate
62 2,4-Dinitrophenol
S3 4-Nitrophenol
£4 2,4-Dinitrotoluene
65 Dibenzofuran
£6 Di-n-butylphthalate
£7 4,£-Dinitro-2-methylphenol
£8 Trifluralin
£9 H«xaohlorob»nz«n«
70 4-Aminobiph«nyl
71 P«nt»ohloroph«nol
72 P*ntachloronxtrob*nz«n«
73 4-Hitrobiph«nyl
74 B«nzidin«
75 4,4'-M«thyl«n«dianilin«
77 Dim«ehylaminoazob*nz«n*
78 3,3'-Dim*thylb«nzidina
SO 3, 3' -Dim*thoxyb«nzidin«
81 3,3'-Dichlorob«nzidin«
82 M«thyl«n« bi«-chloroanilin«
83 bi« (2-Bthylh«xyl)phthalat«
Compound Hot
Compound Hot
Compound Hot
Compound Not
Compound Hot
Compound Not
Compound Hot
Compound Hot
Compound Hot
Compound Not
Compound Hot
110.00 13-:
Compound Hot
Compound Hot
Compound Hot
Compound Hot
154.00 IS,
163.00 15.
Compound Hot
139.00 16-
165.00 16-,
Compound Hot
149.00 20.
Compound Not
Compound Not
Compound Hot
Compound Hot
Compound Not
Compound Not
Compound Not
184.00 22-
Compound Not
Compound Not
Compound Not
Compound Not
Compound Not
Compound Not
149.00 25.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
520(1.OtO)
-5W
0.04
Detected.
Detected.
Detected.
Detected.
839(0.965)
Detected.
BR1 (1 . U71?)
Detected.
785(1.063)
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
355(1.003)
27547
5S7
1.13 1.13
1384286
29.02 29.02
27619
1.18 1.18
-------
Data File: /chen/Y.i/10-22-97.b/CfWYP774.d
Date : 22-OCT-1997 18:18
Instrument : Y.i
Sample IB : LAB BLANK-MM5-28
Column phase : DB.5-625
Volume Injected _
2.0:
61 Dimethylphthalate (PBM Reference Spectrum)
%
i 11 > 1
•" •'!• "II.. .. 1. -• J.I.
40 50 60 70 80 90 100 110 120 130 140 150 160
Mass/Charee
Scan 1665 (15.839 min) of YP774.d (Z DIFFERENCE)
100-
75-4
50-j
25-j
<+. :
S-254
X :
-50-j
-75-i
40 50 60 70 80 90 100 110 120 130 140 150 160
Mass/Charee
Mass 163.00
1.6-5
•
1.4-i
1.2:
;
31'0"
00.8:
•2 :
>-0.6-
0.4:
0.2:
0 0-
A
•s
*
in
A
15.4 15.6 15.8 16.0 16.2
Time (min.)
Mass 194.00
700-^
'•
600-j
500:
400-j
•
^300:
200-i
100-i
S
B
15.4 15.6 15.8 16.0 16.2
Time (min.)
Mass 164.00
j
1 4-
A«t
1.2-
1.0-
< *
o
^50.6:
0.4-
0.2-
0 0-
~M
GO
in
15.4 15.6 15.8 16.0 16.2
Time (min.)
-------
Data File: /cliem/Y.i/10-22-97.b/Cftfl/YP774.d
Date : 22-OCT-1997 18:18
Instrument : Y.i
Sample ID : LftB BLflNK-MM5-28
Column phase : DB.5-625
Volume Injected : 1.0
66 Di-n-butylphthalate
Page 13
Column diameter : 0.32
Scan 2362 (20.785 min) of YP774.d
7.0H
6.0-i
5.0-j
£4*°1
XX * j
1.0^
i
.1. i. • & .. n . .
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
Scan 2362 (20.785 min) of YP774.d (Subtracted)
7 0-
f * V .
6.0-1
5.0-j
^4.0-J
o :
33-°1
i.o-i
0 0 ''
'", f .", 1 , -|l'| , ,', , 'l , , f; , i , .
40 60 80 100 120 140
*-i — r— r — i r i — i — i i i — I , . ' , — , — . . , — i—
160 180 200 220 240 260
Mass/Charee
66 Di-n-butylphthalate (PBM Reference Spectrum)
.
8.0:
•
fO * '
§4.0:
3_ :
2.0:
0 0-
1 ,.,11 |. ,L 1 l|. L. (
40 60 80 100 120 140
| |
160 180 200 220 240 260
Mass/Charee
Scan 2362 (20.785 min) of YP774.d (2 DIFFERENCE)
100-q
75-j
50-j
251
t <>-•
5-25-j
"*-50-j
-75-.
-100-
••i r - — — - • — r- •.- -
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
Mass 149.00
7.0-i
6.0-;
5.0:
|4.0:
-3.0:
>- ;
2.0-;
1.0-;
0 0-
It— Hf)
"
II O
II "^
1 LI
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 150.00
6.0:
5.0:
^4.0-
<^
33'°:
>• ;
2.0-
i.o-
^^
o
20.40 20.60 20.80 21.00 21.20
Time (min.)
Mass 104.00
3.2-
2.8-
2.4:
2 *
.0-
J*
Sl.6-
XX
>-1.2-
0.8-
0.4-
l~fc
1 s*
]
I
. >, ,1 t ,i , , A, . t ,N» , , , ,t. , . l
20.40 20.60 20.80 21.00 21.20
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/C(WYP774.d
Date : 22-OCT-1997 18:18
Instrument : Y.i
Sample ID : LAB BLANK-MM5-28
Column phase : DB.5-625
Volume Injected : 1.0
83 bis(2-Ethylhexyl)phthalate
Page 15
Column diameter : 0.32
Scan 3005 (25.355 min) of YP774.d
0.0
.0 "'P i I"'| i"f'l' |"l i1 l"|"i 'i'l | i i1* | i"l i |'i'i i'| i i' i | i"i i | i i i"| i i i | i i i (
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
Scan 3005 (25.355 min> of YP774.d (Subtracted)
8.0-
0.0-
I
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
83 bis(2-Ethulhexyl)phthalate (PBM Reference Spectrum)
8.0-
0.0
-+-
Jt-
I
40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charge
100-
75-i
50-i
25i
t H
3-25-i
-75-i
-100-
Scan 3005 (25.355 min) of YP774.d (2 DIFFERENCE)
ir ,„ ,.l
40
60 80 100 120 140 160 180 200 220
_ Mass/Charge _
240 260 280
Mass 149.00
25.00 25.20 25.40 25.60 25.80
Time (min.)
Mass 167.00
3.2-
2.8-
2.4-
2.0-
f<>
S1*6"
0.8:
0.4-
0.0-
n
25.00 25.20 25.40 25.60 25.80
Time (min.)
-------
[> - , ^**v£*\L'''*^ * ;,'s
^ . ,^ ~y,y,, ^ ^5,
Project Number. 43433
Sample File: YP773
Client Proiecfe Sai&riaii^' MI-^ **
TPTf "J 1T\» ^JL-TtT ^tr *^V*t^ Jtrfyy^" •• •' '""* •'•> •x>v-*'¥v" ""..
Jt .TifrT j fir t YTnr n rtfc^- rUr 'Jt'*r^ff sX ' C"1^* 5O1. ^* Su% '•
s > "* -^ "•%•••••% ^%/^% \\-. X v
. ^i$gX$iJiib2*$
:* ,\-f" ; ^^^ifeived*^/ ^*- '^v '" - --^ " '->
" "^ ^DS®ffi^feilfM^I ^ ; ^
;^^^WSSS8^*^^;sV^
•" % ^ s f v f" ^"^^^ ^ ^ % ^. :
Method 8270AXAP
Sample ID: SBLK101497
^•Resd^ri^ F^^S^'T'^H- =
J-* ^^ Afl **»*? >^*d^^^* ^
if'^|"^*V^^§\^!.
Dilution Factor: 1.00
te^-' •'•''«;WM?^'?t^?f^^^^®'0^^!
Naphthalene-d
Naphthalene
2-Mediylnaphthalene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-d
7 12
Benzo(b) fluoran diene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
IS 2 12.76
2.44 ] 12.81
U
IS 3 16.43
U
U
U
U
IS 4 19.55
U
U .
U
IS 5 25.28
U
U
U
IS 6 29.41
U
U
U
U
U
U
U
U
10
0.43 10
0.44 10
0.27 10
0.45 " 10
0.45 10
0.29 10
0.30 10
0.29 10
0.28 10
0.32 10
0.33 10
0.30 10
0.29 10
0.28 10
0.31 10
0.28 10
0.27 10
0.36 10
0.29 10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantttation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantttation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 09:47 11/13/1997
-------
I
* ' v^V ^s
% % s •, g^. i.V \
'reject Number: 43433
Sample File: YP773
Method 8270A XAD
Sample ID: SBLK101497
Dilution Factor: 1.00
\ \ s "• \ "• v. , -. ^ •. t <• %
1 v ^ ' ^ -"'^ '
' " ' s '
'henol-d
i
Nitrobenzene-d
i
,3>5-Trichlorobenzene-d
3
» ,4-Dibromobenzene-d
4
2-Fluorobiphenyl
,4,6-Tribromophenol
Anthracene-d
to
"yrene-d
' 10
*'o,%
C^^k ^ % ' v ''"
56.67
56.00
53.36
64.21
67.25
99.19
95.10
105.84
-X
"" s ssO^ ^
9.45
11.30
11.98
12.87
15.01
18.07
19-67
22.54
% ^ .^\x%%
"• ^v" •.
1
2
2
1
3
3
4
5
^ C*** "* N %S % '•
...?.$..?..?. \.% :
57
56
53
64
67
99
95
106
Reviewed by.
Date II
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitatton Limit
IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
"01 Capitola Drive • Durham, North Carolina 27713
hone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.5
-------
Project Number 43433
Sample File: YP773
Method 8270A XA-D
Sample ID: SBLK101497
LjLieUt JrrQTeCC SnXgluttl^- SflL .••••.•..' ••••. •.•.;.•,•.
Tff TT%» &KT V"ttVtAOfT $ ' " ~~ •• K & v Vs.
I IJI JlL/; OoJUiXAUa.*;?/ :.-..- , ^ „ «** *:
4 «\ v-. o h - " '%:? v"ff ""9
&nftlyffe •> „ % V ^ ^ Tv
1 ,4-Dichlorobenzene-d
n-Nitrosodimethylamine
Cumene
Phenol
Aniline
bis-(2-Ch!oroethyl)ether
Benzyl Chloride
1 ,4-Dichlorobcnzene
2-MediyIphenol
Acetophenone
n-Nitrosomorpholine
o-Toluidine
Hcxachloroethanc
1 ,2-Dibromo-3-chloropropane
N,N-Diethylaniline
Naphthalene-d
3/4-Methylphenol
Nitrobenzene
N,N-Dimethylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlorobutadiene
a,a,a-Trichlorotolucne
Hydroquinone
, <;^^^^|iyzc4'^10^i^
Dilution Factor: 1.00
.^ifrff.^^tltf S jPJ^TTT"? % % f ^ s S^t •* % s
IS 1 10.22
U
U
u
u
u
u
u
u
2.53 J 11.00
U
U
U
U
U
IS 2 12.76
U
U
U
U
U
U
U
U
U
U
\ '"¥'* ' '*£ X ^ ^ %-u ' j-
•. ^ ^ s ^ V ' ^ j. ^ <•*• \XJ% •^v~ Vff '"''
^ £ •• J^ v yX ^ ^ x^«.% *-V*^ ^-X% N*'
\ ^^^,^^ % N% *-^%^
^ ^ ^V«« 1^;^"^
1.41
0.39
0.63
0.51
1.08
0.39
0.63
0.81
1.41
0.51
1.33
1.40
0.48
0.89
0.56
0.57
0.47
1.02
0.74
0.86
1.47
0.70
0.77
MjMv. \> x :
f^, •. v\
oC^: *!
^% \x ^ \:
Kt^ K»n10llTi
% "t ' V°i
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
NA- Not Applicable; DeL Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-3729 • Fax: (919) 544-5491
Savar v3.5
Printed: 12:41 11/13/1997
-------
. %% x " rs ' ," ..-. v " v-
1 ^ -
F -"' , * " v%-
Project Number: 43433
Sample File: YP773
pnilD:SB^101$S7i
* %%\
I
v.^ ^**^ x£ ^j^-\^ ' ' v ^v s vi£i3$\<£,£% T ^C"\x. ™*rs ^^^.H-."1 ^v^x.1^
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Method 8270AXA-D
Sample ID: SBLK101497
- x l -'^ ^\v^dte"^tfasadfe^Wl4/^CAT^
•>":** ^^':';vmtl^aj^dtlO/^^ '-^ \:
". "• % s *• f *.\yj^ s ^\^\v ' &^ O*-?«% ^ *• f f ^
Dilution Facton 1.00
Response F|I<
> * <\^« % ^*%
^^/y
^^ *" ^ ^ ' ^x 1 ~" V
!:'£^*"^ i
1
2-Chloroacetophenone
Acenaphthene-d
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Biphenyl
Dimethylphthalace
2,4-Dinitrophenol
4-Nitrophenol
2,4-Dinitrotoluene
Dibenzofuran
4,6-Dinitro-2-methylphenol
Trifluralin
Phcnanthrene-d
10
Di-n-butylphthalate
Hexachlorobenzene
4-Aminobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Benzidine
4,4'-Methylenedianiline
Dimethylaminoazo benzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
• ...^^A^j;,^^ :RT '^
3.83 J 13.86
IS 3 16.43
U
U
U
U
U
U
U
U
U
U
U
IS 4 19.55
1.61 J 20.78
U
U
U
U
U
IS 5 25.28
U
U
U
U
U
^5-fc ":;:;
1.46
1.33
1.15
0.36
0.42
5-12
1.96
1.50
0.32
3.32
2.42
0.87
0.37
1.66
3.50
0.95
0.47
1.11
0.95
0.59
1.22
^f*j
10
10
10
10
10
10
25
25
10
10
25
10
10
10
10
25
10
10
10
10
10
10
10
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544o729 • Pax (919) 544-5491
Savarv3.5
-------
^v.v% ^-. Jw •. ^ x £.. s ' '^ ^ ^\< ^
^% ^>\f -^X OV-> ^ ,-},, «> , ^5,
Project Number 43433
Sample File: YP773
Method 8270 A XAD
Sample ID: SBLK101497
Dilution Factor: 1.00
3,3'-Dichlorobenzidine
Methylene bis-chloroaniline
bis(2-Ethylhexyl)phthalate
U
U
0.57 J
0.80
1.81
25.35
10
10
10
Reviewed by.
Date \U 15 I
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.5
-------
Data ,F,ile: /chem/Y.i/10-22-97.b/'YP773.d
Date t 22-OCT-97 17:30
Instrument ; Y.i
Sample ID : SBLK 101497
Column phase : D6-5
Volume Injected : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0.32
Page 9
4.6-i
4.4-i
4.2:
4.0:
3.8:
3.6-i
3.4-i
3.2-i
3.0-i
2.8:
2.6:
XX
-2.2-i
2.0-i
•
1.8:
1.6-i
1.4-i
1.2:
1.0:
0.8:
0.6-i
0.4-i
0.2:
a
/chem/Y. i/10-22-97.b/YP773.d
ro
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xx c
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9 10 11 12
Time (min.)
1
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10
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13 14 15 16 17 18 19
-------
Data file: /chem/Y.i/10-22-97.b/YP773.d
Date J 22-OCT-97 17:30
Instrument : Y.i
Sample ID : SBLK 101497
Column phase : DB-5
Volume Injected (uL) : 1.0
Triangle Laboratories
of RTP, Inc.
Column diameter : 0.32
Page 10
00
03
4.6:
4.4:
4.2:
4.0:
3.8:
3.6:
3.4:
3.2:
3.0:
2.8:
2.6:
XX
^2.4-;
-2.2:
2.0:
o •
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1.4:
1.2:
1.0:
0.8-i
0.6:
0.4:
0.2:
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1
L^L_ JL
/'chem/Y.i/10-22-97.b/YP773.d (Part 2 of 2)
1
8*
o
1
-------
Data File: /chem/Y.i/10-22-97.b/YP773.d
Report Date: 23-Oct-1997 11:34
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-22-97.b/YP773.d
43433
22-OCT-97 17:30 Autotune Date: 22-Oct-97 09:14:0
DD Inst ID: Y.i
SBLK 101497
/chem/Y.i/10-22-97.b/cclist.m
23-Oct-1997 11:29 target
22-OCT-1997
11
1.000
HP RTE
11:59
Sample Type: AIR
Cal File: YP766.d
Target Version: Target 2.20
Compound Sublist: pah.sub
Compound*
QUANT SIS
MASS
RT (RBI. RT)
CONCENTRATIONS
ON-COLOMN FINAL
RESPONSE ( ng) ( ug)
• 1 l,4-Dtchlorob«nl«n«-d4
* 2 N«phth«l«n«-d8
* 3 Ac«naphth«n«-dlO
* 4 Ph«n*nthr»n«-dlO
• 5 Chry«»n«-dl2
* £ P«ryl«n«-dl2
$ 7 2-Fluoroph«nol
$ 8 Phanol-dS
$ 9 2-Chloroph«nol-d4
$ 10 l,2-Dichlorob«nz«n«-d4
$ 11 Nitrob«nz«n«-d5
$ 12 l,3,S-Trichlorob«nz«n«-d3
$ 13 l,4-Dibromob«nz«n«-d4
$ 14 2-Pluorobiph*nyl
$ 15 2,4,6-Tribromoph»nol
$ 1C Anthr»o«n«-dlO
$ 17 Pyr»n«-dlO
$ 18 T«rph«nyl-dl4
42 N»phth»l«n«
46 2-M«thyln»phth»l.n«
50 2-Chloron»phth»l«n«
56 Ac«n«phthyl»n«
58 Ao*naphth«n*
65 Fluor«n«
73 Ph«n«nthr«n»
74 Anthr»c»n«
77 Fluor«nth»n«
78 Pyr«n«
63 Bttnzo (•) uithrac^n*
84 Chry»»n»
86 Banzo(b)fluoranth«n«
152.00
136.00
164.00
188.00
240.00
264.00
Compound
99.00
Compound
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
Compound
128.00
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compound
10.
12.
16.
19.
25.
29.
Not
9.
Not
Hot
11.
11.
12.
15.
18.
19.
22.
Hot
12.
Hot
Hot
Not
Hot
Hot
Hot
Hot
Not
Not
Hot
Hot
Hot
223(1.000)
764(1.000)
426(1.000)
546(1.000)
280(1.000)
408(1.000)
D«t«ct«d.
450(0.924)
D«t«ot«d.
D«t«ct*d.
301(0.885)
983(0.939)
870(1.259)
006(0.914)
071(1.100)
668(1.006)
540(0.892)
D«t«ot«d.
806(1.003)
Detected.
D»t«ct«d.
D«t«ot«d.
D«t»ct«d.
Dataetad.
D*t*ct*d.
D*t*ct«d.
D«t«ot«d.
D«t«ot«d.
Dctcetad.
D«t«ot«d.
D«t«ct«d.
459693
1467052
830491
1360406
1120374
1424942
1104585
778357
667324
720176
1727131
560160
3408997
3563308
93907
40.
40.
40.
40.
40.
40.
56.
55.
53.
64.
67.
99.
95.
105.
2.
00
00
00
00
00
00
68
99
35
23
26
20
07
85
44
56.68
55.99
53.35
64.23
67.26
99.20
95.07
105.85
2.44U)
Data Review.
Date'. «i
-------
Data File: /chem/Y.i/10-22-97.b/YP773.d
Report Date: 23-Oct-1997 11:34
Page 2
Compounds
QUANT SXO
MASS
RT (XKL RT)
ON-COttMH FINAL
RXSPOHSB ( ng) ( ug)
87 Banzo (k)fluoranth«n«
88 B«nzo (•)pyr«n»
89 B*nzo(a)pyr«n«
90 P«ryl«n«
91 Ind«no(l,2,3-od)pyr»n»
92 Dlbcnz(a,b)anthracene
93 B«nzo(g,h,i)p«ryl«n»
QC Flag Legend
Compound Hot D«t«ct«d.
Compound Not D«t«ot»d.
252.00 2!T7«13(i.flOO)
252.00 73. .Ti (1,8811)
-3419-
OilB-
Compound Rot D«t«ot«d.
Compound Hot D*t*ot>d.
Compound Rot D«t«ot«d.
a - Target compo\ind detected but, guantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP773.d
Report Date: 23-Oct-1997 09:00
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Oil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-22-97.b/CAA/YP773.d
43433
22-OCT-97 17:30 Autotune Date: 22-Oct-97
DD Inst ID: Y.i
SBLK 101497
09:14:0
/chem/Y.i/10-22-97.b/tlicaa.m
23-Oct-1997 08:05 target
22-OCT-1997 15:55
11
1.000
HP RTE
Sample Type: xnm5
Cal File: YP771.d
Target Version: Target 2.20
Compound Sublist: CAAl.sub
CONCENTRATIONS
Compounds
• 1 If4 Dichlorob«nz»n«-d4
* 2 N»phth»l»n«-d8
* 3 Ac«naphth«n»-dlO
* 4 Ph«n»nthr«n»-dlO
* 5 Chry»«n«-dl2
* 6 P«ryl«n«-dl2
$ 7 2-Pluoroph«nol
$ 8 Phanol-dS
$ 9 2-Chloroph«nol-d4
$ 10 l,2-Dichlorob«nz»n»-d4
$ 11 Nitrob«nz«n«-dS
$ 12 l,3,5-Trichlorob«nz«n«-d3
$ 13 l,4-Dibromob»nz»n«-d4
$ 14 2-Pluorobiphvnyl
$ 15 2,4,6-Tribromoph*nol
$ 16 Anthr»o»n«-dlO
$ 17 Pyr«n«-dlO
$ 18 T*rph«nyl-dl4
20 n-Nitro«odim*thylamin*
21 Cuman*
23 Phanol
24 Anilin*
27 bi«-(2-Chloro«thyl)»th»r
28 Banzyl Chlorid*
29 l,4-Dichlorob«nz«n«
31 2-M«thylph«nol
32 3/4-M*thylph«nol
33 Ac»toph«non»
34 n-Nitro«omorpholin«
35 o-Toluidina
36 H»x»chloro«than«
QUANT SIO
MASS
152
136
164
188
240
264
99
82
185
240
172
329
188
212
14
94
.00
.00
.00
.00
.00
.00
Compound
.00
Compound
Compound
.00
.00
.00
.00
.80
.00
.00
Compound
.00
Compound
.00
Compound
Compound
Compound
Compound
Compound
Compound
105.00
10
12
16
19
25
29
Hot
9
Hot
Hot
11
11
12
15
18
19
22
Hot
Mot
Not
Mot
Not
Not
Hot
Not
10
RT (RRL RT)
.223(1.000)
.764(1.000)
.426(1.000)
.546(1.000)
.280(1.000)
.408(1.000)
Detected.
.450(0.924)
Detected.
Detected.
.301(0.885)
.983(0.939)
.870(1.259)
.006(0.914)
.071(1.100)
.668(1.006)
.540(0.892)
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
Detected.
.995(1.076)
ON-COLDMN
RESPONSE
459693
1467052
830491
1360406
1120374
1424942
1104585
778357
667324
720423
1727131
560160
3408997
3563308
4B3H
44151
(
40.
40.
40.
40.
40.
40.
60.
54.
55.
64.
66.
111.
89.
94.
ITT
2.
ng)
00
00
00
00
00
00
98
66
85
85
89
30
01
76
70
53
FINAL
( ug)
60.98
54.66
55.85
64.85
66.89
111.30
89.01
94.76
U. JO"
2.53
56.00 11.265LL-1O21 •**•>•* n ->c O- IB
Compound
Compound
Not
Hot
Detected.
Detected.
Data Review:
Date:
-------
Data File: /chem/Y.i/10-22-97.b/CAA/YP773.d
Report Date: 23-Oct-1997 09:00
Page 2
QUANT SIO
Compound* MASS KT (RKL RT)
37 Nitrobenzene Compound Not Detected.
38 N,N-Dimethylaniline Compound Hot Detected.
39 l,2-Dibromo-3-chloropropane Compound Hot Detected.
40 laophorone Compound Hot Detected.
41 o-Aniaidine Compound Hot Detected.
42 1,4-Phenylenediamine Compound Not Detected.
43 1,2,4-Trichlorobenzene Compound Not Detected.
44 Naphthalene 128.00 12.806(1.003)
46 Hexachlorobutadiene Compound Hot Detected.
47 N,N-Diethylaniline 134.00 12.764(1.24JO_
48 a,a,a-Trichlorotoluene Compound Hot Detected.
49 Hydroquinone 110.00 'LSaffd """>
51 2-Chloroaoetophenone 105.00 13.863(1.086)
52 Hexachlorocyclopentadiene Compound Hot Detected.
53 2,4,6-Trichlorophenol Compound Not Detected.
54 2,4,5-Trichlorophenol Compound Not Detected.
£0 Biphenyl 154.00 15.HOC id.»14)—
£1 Dimethylphthalate Compound Hot Detected.
£2 2,4-Dinitrophenol Compound Not Detected.
£3 4-Nitrophenol Compound Not Detected.
£4 2,4-Dinitrotoluene 165.00 M.418 (1.800)
£5 Dibenzofuran Compound Not Detected.
£6 Di-n-butylphthalate 149.00 20.781(1.063)
£7 4, 6-Dinitro-2-methylphenol Compound Not Detected.
£8 Triflurilin Compound Not Detected.
£9 Bexachlorobenzene Compound Not Detected.
70 4-Aminobiphenyl Compound Not Detected.
71 Pentachlorophenol Compound Not Detected.
72 Fentachloronitrobenzene Compound Hot Detected.
73 4-Nitrobiphenyl Compound Not Detected.
74 Benzidine 184.00 ia_c^o fn B92)
75 4,4'-Methylenedimniline Compound Not Detected.
77 Dimethylaminoazobenzene Compound Not Detected.
78 3,3'-Dimethylbenzidine Compound Hot Detected.
80 3,3'-Dimetboxybenzidine Compound Not Detected.
81 3,3'-Dichlorobenzidine Compound Not Detected.
82 Methylene bie-chloroaniline Compound Not Detected.
83 bi«(2-Ethylhexyl)phthalat» 149.00 25.352(1.003)
CONCXMTKXTIONS
OH-COLDMH
RESPONSE ( ng) ( ug)
93907
mi«
2.75
-S.90
2.75
-9r»ff
_3ia9-
-fl.lT.
103008
•>•»"•"
3.83
.0.98
3.83
-0.90-
83913
1.60
1.60
33199_
l.St
15147
0.57
0.57
-------
Data File: /chem/Y.i/10-22-97.b/YP773.d
Date : 22-OCT-97 17:30
Instrument : Y.i
Sample ID : SDLK 101497
Column phase : DB-5
Volume Injected — "
1.0-
JLJ *.. 1 .1
•
1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Scan 1237 (12.806 win) of YP773.d (Subtracted)
5.0-;
4.0-;
^H
X9 0-
xx t»V
1.0-
. ,1. .1 1. . J
i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
42 Naphthalene (PBM Reference Spectrum)
8.0-
|6-°-
3 4.0-
XX
>-
2.0-
.nt. 1 1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1237 (12.806 min) of YP773.d « DIFFERENCE)
100 -:
75-i
50 -j
254
£ 04
»-25i
-50-=
-754
..,.,, p . .T ...
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 128.00
5.5|
5.04
4.54
;
4.0-j
3.54
?3.0-=
^ :
^2.5^
^2.04
1.54
i.o4
0.5-i
0.0J
in
£*
i
i
1]
J 1
j
i V ^ j
S4
u..
12.40 12.60 12.80 13.00" 13.20
Time (min.)
5.54
5.04
4.5r
4.04.
~*'^.
^3.04
'H O K '
>-2.o4.
1.54
i.o4
0.54"
0 0-
Mass 129.00
i^^n
1 *
\ i
. j
^ IN
1
1
I
1
12.40 12.60 12.80 13.00 13.20
Time (min.)
Mass 127.00
7.0-i
6.0-
5.0-
^ :
< '.
o
33.0-
s- :
2.0-
1.0-
o o-
t^.
ro
CVJ
»H
,
"s
CM
12.40 12.60 12.80 13.00 13.20
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/Cftfl/YP773.d
Date : 22-OCT-1997 17:30
Instrument : Y.i
Sample ID : SBLK 101497
Column phase : DB.5-625
Volume Injected -
2.0-
On—
,ll,,
•u i
40
100-
75-i
504
254
fc 0-1
S-25-1
"-504
-75-1
-1AO-
J
.]
", Vi > !|1
Scan 982 (10
.995 nin) of YP773.d
60 80 100 120 140 160 180 200
Mass/Charee
Scan 9E
1 , "I , 'l
2 (10.995 mi
• I. i
n> of YP773.d (Subtracted)
60 80 100 120 140 160 180 200
Mass/Charee
33
Acetophenonc
• (PBM
Reference Spectrum)
60 80 100 120 140 160 180 200
Mass/Charee
Scan 982 (10.995 min> of YP773.d
ro
CO
»
s
1
1 p
.00
-»
S
ll
1
W.W^ • | ... | ... | ........ | .
10.6 10.8 11.0 11.2 11.4
Time (min.)
3.2-;
2.8-j
2.4-;
2.0-
*^i
Sl.6^
X
:i.2-
0.8:
0.4:
Ort-
Mass 77.
i
. .A ni 1
00
1
o
iH
uw.
1
10.6 10.8 11.0 11.2 11.4
Time (min.)
6.0-j
5.5-j
5.0-1
4.5-^
4.0-i
R'-SI
o3.0-i
X 0 C :
<— 2.0-
*• 2.0-j
1.5-1
i.o-i
0.54
0 0-=
Mass 120
hw
1
1
u li il
.00
•*.
s
il 1
10.6 10.8 11.0 11.2 11.4
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/Cflft/YP773.d
Date : 22-OCT-1997 17:30
Instrument : Y.i
Sample ID : SBLK 101497
Column phase : DB.5-625
Volume Injected : 1.0
51 2-Chloroacetophenone
Page 12
Column diameter : 0.32
Scan 1386 (13.863 min) of YP773.d
e.o-i
5.0-i
s4-0^
i3-°i
~2.- *
1.0-
0 0-
.1. .
1
1 i
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charee
51 2-Chloroacetophenone (PBM Reference Spectrum)
8.0-J
:
P>
^x4.0-
>_
2.0-
0.0-
%
..1 . 1 . ..il .1, .1
1 , 1 , , i 1 . . . , 1 i i i | i I i , . , l . , l i i i | i i
1 1 1 1 1 1 ,....,.... , ... 1 1 1 1 1 1 1 ....,,
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charge
Scan 1386 (13.863 min) of YP773.d (Z DIFFERENCE)
100 -q
75 -i
so -i
25-i
S-25-;
~-50-i
-75 -i
40 50 60 70 80 90 100 110 120 130 140 150 160 170
Mass/Charee
Mass 105.00
6.0-;
5.0-
^4.0-;
S3.0J
X * •
*••> ft
2.0-
1ft-
.w
0.0-
p3
II -rH
gj
CM1"";
(1 ^
II /\'A 1
S
2
'
Jv. /VW ^^ *\^ .. ,
13.40 13.60 13.80 14.00 14.20
Time (min.)
Mass 77.00
3.2-
2.8-
2.4-
^2.0-
<^
sx
>-1.2-j
0.8-i
0.4-j
0.0-
h-*-O
fs
1
0^
*
Iro
s7
t._
*-*
ro
8
^1
A A
I U\ R/UAA
u K V*w »/ vvjv\
T ''it11' i™i | i' '
13.40 13.60 13.80 14.00 14.20
Time (min.)
Mass 51.00
2.0-i
1.8-j
1.6H
1.4-^
~12^
Sl.O-i
•^0.8-i
^
0.6^
0.4-i
0.2^
— ^o
°^
53
1
?5
"•".S
(1 ^k
11 *|/l
fO
.
•V
Jl "
LA AA. ,
A 1 \i A i y i y y ij*fl w \jjy f\i
13.40 13.60 13.80 14.00 14.20
Time (min.)
-------
Data File: /che«/Y.i/10-22-97.b/CfilVYP773.d
Date : 22-OCT-1997 17:30
Instrument : Y.i
Sample ID : SBLK 101497
Column phase : DB.5-625
Volume Injected : 1.0
66 Di-n-butylphthalate
Page 15
Column diameter : 0.32
Scan 2361 (20.781 min) of YP773.d
4.0-
3.0-
XX
•*
32.0-
XX
0 0~
•
1 ill . Illl 1. . .1. . . H
40 60 80 100 120 140
| i.. i
160 180 200 220
Mass/Charee
Scan 2361 (20.781 min) of YP773.d (Subtracted)
4.0-i
3.0-i
5
<
S2.0-
X
XX
>.
1.0-
0 0-
i III , .il i. .1. . . il
40 60 80 100 120 140
i —i f-i r-*-
160 180 200 220
Mass/Charee
66 Di-n-butylphthalate (PBM Reference Spectrum)
•
8.0-
xx 6.0-
r-o * •
XX
2*°~
0.0-
i! . ,n i i. i ii h.
1 . 1 1 1 1 . 1 , . . . 1 1 . . , I . 1 1 1
•
1 i
. | . i • | . . , | i . . |
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Scan 2361 (20.781 min) of YP773.d (Z DIFFERENCE)
100-
75-
50-
25-
£ 0-
S-25-
"-50-
-75-
"
- .-,- .-. .- ~... — r-
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Mass 149.00
4.4-^
4.0-i
3.6-i
3.2-;
2.8-;
?2.4-i
XX
>.1.6-i
1.2-j
0.8-i
0.4-:
0 0-
l
~00
*
a
' * • *
20.4 20.6 20.8 21.CT 21.2
Time (min.)
Mass 150.00
4.4-q
4.0-
3.6-
3.2-
2.8-
£2.4-
^2.0-
^•61
1.2-i
0.8-
0.4-i
H
CO
o
CJ
20.4 20.6 20.8 21.0 21.2
Time (min.)
Mass 104.00
2.0-i
1.8-i
1.6-j
•
1.4-i
S * ^
x * '•
,,.0.8-
0.6-i
0.4-i
0.2-i
0 0-
1
, , r,r JU,
•^r
»
S
1,
,-,... JU . .
20.4 20.6 20.8 21.0 21.2
Time (min.)
-------
Data File: /chem/Y.i/10-22-97.b/CflA/YP773.d
Date : 22-OCT-1997 17:30
Instrument : Y.i
Sample ID : SBLK 101497
Column phase : DB.5-625
Volume Injected \
dj|
l*||
T
1 \
^ A/1 I Hi A
25.00 25.20 25.40 25.60 25.80
Time (min.)
Mass 167.00
1.6-
1.4-
1.2-
XX
IV)
So.8-
X
^0.6-
0.4-;
0 ?-
0 0—
1 LO
1 ro
•OT in
r
i j
I
in U i
25.00 25.20 25.40 25.60 25.80
Time (min.)
-------
Triangle Laboratories of RTF, Inc.
Continuing Calibration Curve
CCAL File: YP766
ICAL File: ICALYO22
Date of Analysis :10/22/97 Analyte List: 8270A
-, % '•''S \ \ ** ^ v. *•
Naphthalene-d8
Naphthalene
2-Methylnaphthalene
Acenaphthene-d 10
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d 10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-dl2
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-dl2
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno( l,23-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
i^sVstaj^a^ ^
*^\0^1V4
I
I
C
I
C
I
I
C
£$R'
1.050
0.638
1.105
1.777
1.063
1.082
1.021
0.967
1.030
1.293
1.106
1.086
0.932
0.977
1.013
0.909
0.989
1.038
0.787
0.963
RSMEAN
1.031
0.675
1.098
1.799
1.054
1.079
1.033
0.990
1.064
1.278
1.098
1.080
1.003
1.002
1.048
0.946
1.004
1.075
0.823
0.974
"SsST'^^
-1.8
5.5
-0.6
1.2
-0.9
-0.3
1.2
2.3
3.2
-1.2
-0.7
-0.6
7.1
2.5
33
3.9
15
3.4
4.4
1.1
Surrogate ' flag = * Kf SO JBlMJ&tt' ]'*& \ . ,
Phenol-d5
Nitrobenzene-d5
l,3,5-Trichlorobenzene-d3
l,4-Dibromobenzene-d4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d 10
Pyrene-dlO
Terphenyl-dl4
.s
s
s
s
s
s
s
s
s
1.696
0.379
0.341
0.976
1.237
0.272
1.054
1.202
0.778
1.664
0386
0.348
0.943
1.230
0.276
1.063
1.214
0.782
-1.9
1.8
2.0
-35
-0.6
1.4
0.8
1.0
05
Approved by:.
Date U / IJ> m
*- Fails QC Criteria for %D;« - Rf leas than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.5
-------
Triangle Laboratories of RTF, Inc.
Continuing Calibration Curve
CCALFile:YP783
ICAL File: ICALYO22
Date of Analysis :10/23/97 Analyte List: 8270A
\M Ivi '^ -v "-;:
1 , y ^^ ,
Naphthalene-d8
Naphthalene
2-Methylnaphthalene
Acenaphthene-dlO
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-dlO
Phenanthrene
Anthracene
Fluoranthene
Chrysene-dl2
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-dl2
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Sarrogate
Phenol-d5
Nitrobenzene-d5
l,3,5-Trichlorobenzene-d3
l,4-Dibromobenzene-d4
2-Fluorobiphenyl
2,4/6-Tribromophenol
Anthracene-dIO
Pyrene-dlO
Terphenyl-dl4
"iHtat '
^ «*
I
I
C
I
c
I
I
c
flag
,S
S
s
s
s
s
s
s
s
RF50
V
1.012
0.663
1.088
1.784
1.051
1.163
1.022
' 0.969
1.051
1.313
1.094
1.062
0.983
0.962
1.049
0.922
0.979
1.078
0.810
0.979
RF50
1.681
0.377
0.332
0.930
1.242
0.298
1.073
1.176
0.817
£&£&*&•' $
>>f.\. .?..>.. ; **••
1.031
0.675
1.098
1.799
1.054
1.079
1.033
0.990
1.064
1.278
1.098
1.080
1.003
1.002
1.048
0.946
1.004
1.075
0.823
0.974
RFMEAN
1.664
0.386
0.348
0.943
1.230
0.276
1.063
1.214
0.782
K%0 - --;F^ - A-^i ? " v ^-% -r r v * , ^fe:t$?: ,v^i
»^. '^.. ''*SS.. ^ss ^ s" ^^ X ' ' ' ** s *%^ * '"^S S^** "** * - x VI
1.8
1.8
0.9
0.8
0.3
-7.8
1.1
2.1
1.2
-2.7
0.4
1.7
2.0
4.0
-0.1
2.5
2.5
-0.3
1.6
-0.5
1 %B - ** < , : ^ \
-1.0
2.3
4.6
1.4
-1.0
-8.0
-0.9
3.1
-4.5
Approved by:.
.Date_ii_/_il/22_
*• Fails QC Criteria for %D;« - Rf leas than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
Triangle Laboratories of RTF, Inc.
Initial Calibration Curve
ICAL File: ICALYO22
RF20 YP767
RF120 YP764
Date of Analysis
RFSO YP766
RF160 YP763
-.10/22/97
Analyte List: 8270A
RFSO YP765
Analyte , , %\\^ ••"'
•> * *
Naphthalene-d8
Naphthalene
2-Methylnaphthalene
Acenaphthene-dlO
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-dlO
Phenanthrene
Anthracene
Fluoranthene
Chrysene-dl2
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-dl2
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l,23-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
I Surrogate
Phenol-d5
Nitrobenzene-d5
l,3,5-Trichlorobenzene-d3
l,4-Dibromobenzene-d4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-dlO
Pyrene-dlO
Terphenyl-dl4
1 flag *
I
I
C
I
C
I
I
C
flag
S
's
S
S
S
S
S
S
S
*t$fcp
1.076
0.683
1.201
1.781
1.093
1.094
1.025
1.013
1.038
1.308
1.149
1.136
1.044
1.048
1.117
0.985
1.041
1.076
0.836
1.003
KF2D
1.646
0.372
0.379
0.958
1.282
0.265
1.089
1.278
0.804
S&
1.050
0.638
1.105
1.777
1.063
1.082
1.021
0.967
1.030
1.293
1.106
1.086
0.932
0.977
1.013
0.909
0.989
1.038
0.787
0.963
RFSO
1.696
0.379
0.341
0.976
1.237
0.272
1.054
1.202
0.778
*$g
1.019
0.671
1.034
1.742
1.019
1.028
1.022
0.996
1.036
1317
1.093
1.100
1.005
0.998
1.020
0.943
0.996
1.059
0.804
0.963
RFSO
1.692
0.374
0.333
0.954
1.192
0.273
1.025
1.224
0.795
v s <•---'•
0.946
0.682
1.091
1.911
1.041
1.122
1.079
0.985
1.118
1.210
1.024
1.040
1.000
0.938
1.015
0.917
0.956
1.081
0.827
0.959
RF120
1.622
0.387
0.325
0.885
1.240
0.291
1.116
1.171
0.754
m^MEA^r ^itscK-y-^^;^^^^
1.063
0.699
1.057
1.785
1.053
1.071
1.019
0.988
1.096
1.264
1.119
1.036
1.035
1.048
1.077
0.977
1.038
1.120
0.858
0.982
RF160
1.666
0.418
0.360
0.941
1.201
0.280
1.031
1.197
0.779
1.031
0.675
1.098
1.799
1.054
1.079
1.033
0.990
1.064
1.278
1.098
1.080
1.003
1.002
1.048
0.946
1.004
1.075
0.823
0.974
Mean
1.664
0.386
0.348
0.943
1.230
0.276
1.063
1.214
0.782
5.1
3.4
5.8
3.6
2.6
3.2
2.5
1.7
3.8
3.4
4.2
3.9
4.4
4.7
4.5
3.6
3.6
2.8
3.4
1.9
%fc$& ,
1.9
4.8
6.3
3.7
2.9
3.6
3.7
3.3
2.5
Approved by:.
.DateJi_/_i3_/fLl
*- Fails QC Criteria for %RSD; « - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544.5729 • Fax: (919) 544-5491
Savar v3.5
-------
Triangle Laboratories of RTF, Inc.
Continuing Calibration Curve
1 CCAL File: YP771 Date of Analysis :10/22/97
CAL File: ICALYO22
Analyte List: 8270A
•
JA»aJyfe , -'; r ^ > , $*S:s;
.,4 Dichlorobenzene-d4 I
n-Nitrosodimethylamine
Cumene
'henol C
Aniline
bis-(2-Chloroethyl)ether
Jenzyl Chloride
1,4-Dichlorobenzene C
2-Methylphenol
\cetophenone
i-Nitrosomorpholine
o-Toluidine
Hexachloroethane
L,2-Dibromo-3-chloropropane
vJ,N-Diethylaniline
Naphthalene-d8 I
1 /4-Methylphenol
Nitrobenzene
N,N-Dimethylaniline
Tsophorone
)-Anisidine
x,4-Phenylenediamine
1,2,4-Trichlorobenzene
iexachlorobutadiene C
i,a,a-Trichlorotoluene
Hydroquinone
*!-Chloroacetophenone
Vcenaphthene-dlO I
Hexachlorocyclopentadiene . P
7.,4,6-Trichlorophenol C
!,4/5-Trichlorophenol
3iphenyl
Dimethylphthalate
!,4-DinitrophenoI P
l-Nitrophenol P
2,4-Dinitrotoluene
Oibenzofuran
l,6-Dinitro-2-methylphenol
;';JH* *
0.616
2.248
1.390
1.695
0.802
2.226
1.384
1.076
1.517
0.618
1.709
0.655
0.622
1.816
0.306
0.488
0.482
0.582
0.267
0.368
0.318
0.186
0.391
0.356
0.733
0.330
0.363
0.418
1.337
1.149
0.094
0.246
0.321
1.486
0.145
A •« •* •• $f
0.600
2.203
1.330
1.676
0.797
2.193
1.325
1.029
1.442
0.597
1.651
0.629
0.610
1.707
0.312
0.477
0.474
0.576
0.260
0.357
0.318
0.183
0.386
0.357
0.719
0.336
0.351
0.396
1.296
1.090
0.121
0.260
0325
1.495
0.175
^m >>%r^'- ^^;^SJV?^^?^
-2.7
-2.0
-4.5
-1.1
-0.6
-1.5
-4.5
-4.6
-5.2
-3.5
-3.5
-4.1
-2.0
-6.4
1.9
-2.3
-1.7
-1.0
-2.7
-3.1
0.0
-1.6
-1.3
0.3
-1.9
1.8
-3.4
-5.6
-3.2
-5.4
22.3
5.4
1.2
0.6
17.1
*- Fails QC Criteria for %D; « - Rf less than minimum QC RF; »- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc
"01 Capitola Drive • Durham, North Carolina 27713
•hone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
-------
Triangle Laboratories of RTF, Inc.
Continuing Calibration Curve
CCAL File: YP771 Date of Analysis -.10/22/97 Analyte List: 8270A
ICAL File: ICALYO22
^rte ; ^
Trifluralin
E&tf^' *B$5o I^MEAMT *
^•^ *W|J.-> i^., ., •. v£ f ••
0.199
0.211
^1.;^!';; *'* iy:,\ \^^*Y,vj
5.7
Phenanthrene-dlO I
Di-n-butylphthalate 1.537 1.432 -7.3
Hexachlorobenzene 0.337 0.299 -12.7
4-Aminobiphenyl 0.791 0.736 -7.5
Pentachlorophenol C 0.177 0.178 0.6
Pentachloronitrobenzene 0.084 0.079 -6.3
4-Nitrobiphenyl 0310 0.281 -10.3
Chrysene-dl2 I
Benzidine 0.758 0.766 1.0
4,4'-Methylenedianiline 0323 0.321 -0.6
Dimethylaminoazobenzene 0.375 0.370 -1.4
33'-Dimethylbenzidine 0.605 0.568 -6.5
33'-Dimethoxybenzidine 0.293 0.282 -3.9
33'-Dichlorobenzidine 0.444 0.434 -2.3
Methylene bis-chloroaniline 0.197 0.185 -6.5
bis(2-Ethylhexyl)phthalate 0.944 0.946 0.2
Approved by: ._^>{4-VC Date 'v / '.
•- Fails QC Criteria for %D;« - Rf ICM than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 O 1 O
-------
Triangle Laboratories of RTF, Inc.
Continuing Calibration Curve
ICCAL File: YP784
ICAL File: ICALYO22
Date of Analysis -.10/23/97 Analyte List: 8270A
%W\^..^ ?'$$£**]£$
1,4 Dichlorobenzene-d4 I
n-Nitrosodimethylamine
Cumene
Phenol C
Aniline
bis-(2-Chloroethyl)ether
Benzyl Chloride
1,4-Dichlorobenzene C
2-Methylphenol
Acetophenone
n-Nitrosomorpholine
o-Toluidine
Hexachloroethane
l,2-Dibromo-3-chloropropane
N,N-Diethylaniline
Naphthalene-d8 I
3/4-Methylphenol
Nitrobenzene
N,N-Dimethylaniline
Isophorone
o-Anisidine
1,4-PhenyIenediamine
1,2,4-Trichlorobenzene
Hexachlorobutadiene C
a,a,a-Trichlorotoluene
Hydroquinone
2-Chloroacetophenone
Acenaphthene-dlO I
Hexachlorocyclopentadiene - P
2,4,6-Trichlorophenol C
2,4,5-Tri'chlorophenol
Biphenyl
Dimethylphthalate
2,4-Dinitrophenol P
4-Nitrophenol P
2,4-Dinitrotoluene
Dibenzofuran
l,6-Dinitro-2-methylphenol
' 1*'ts •.
0.584
2.289
1.309
1.742
0.814
2.230
1.337
1.021
1.480
0.605
1.665
0.637
0.613
1.702
0.356
0.518
0.538
0.616
0.294
0.372
0.325
0.199
0.421
0.353
0.766
0.308
0.360
0.384
1.364
1.121
0.124
0.271
0.329
1.400
0.166
jMJJAN'-'W
0.600
2.203
1.330
1.676
0.797
2.193
1.325
1.029
1.442
0.597
1.651
0.629
0.610
1.707
0.312
0.477
0.474
0.576
0.260
0.357
0.318
0.183
0.386
0.357
0.719
0.336
0.351
0.396
1.296
1.090
0.121
0.260
0.325
1.495
0.175
\-$ySt£K^fy'$;f" " * s^V \ , « -v* ^J"""^ - ^"Vi|^\- ^1
» ..v ^ v ^ •*•.•. "•s^."xv<% *»*^^^^X^" " V^>-^-xr-|
2.7
-3.9
1.6
-3.9
-2.1
-1.7
-0.9
0.8
-2.6
-1.3
-0.8
-1.3
-0.5
0.3
-14.1
-8.6
-135
-6.9
-13.1
-4.2
-2.2
-8.7
-9.1
1.1
-6.5
8.3
-2.6
3.0
-5.2
-2.8
-2.5
-4.2
-1.2
6.4
5.1
*- Fails QC Criteria for %D;« - Rf lesa than minimum QC RF; »- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc
301 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
Savar v3.5
-------
Triangle Laboratories of RTF, Inc.
Continuing Calibration Curve
CCALFile:YP784 Date of Analysis :10/23/97 Analyte List: 8270A
ICALFile:ICALYO22
Trifluralin 0.222 0.211 -5.2
Phenanthrene-dlO I
Di-n-butylphthalate 1.416 1.432 1.1
Hexachlorobenzene 0307 0.299 -2.7
4-Aminobiphenyl 0.735 0.736 0.1
Pentachlorophenol C 0.173 0.178 2.8
Pentachloronitrobenzene 0.079 0.079 0.0
4-Nitrobiphenyl 0.286 0.281 -1.8
Chrysene-dl2 I
Benzidine 0.792 0.766 -3.4
4,4'-Methylenedianiline 0.325 0.321 -1.2
Dimethylaminoazobenzene 0.366 0.370 1.1
3,3'-Dimethylbenzidine 0.643 0.568 -13.2
3,3'-Dimethoxybenzidine 0.320 0.282 -135
3,3'-Dichlorobenzidme 0.432 0.434 0.5
Methylene bis-chloroaniline 0.187 0.185 -1.1
bis(2-Ethylhexyl)phthalate 0.955 0.946 -1.0
Approved by: ~*& Date _JL/_!i/!2_
*- Fails QC Criteria for %D;« - Rf lea* than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713
-------
Triangle Laboratories of RTF, Inc.
Initial Calibration Curve
TCAL File: ICALYO22 Date of Analysis -.10/22/97
P20 YP772 RF50 YP771
RF120 YP769 RF160 YP768
Analyte List: 8270A
RF80 YP770
.
Ana^ V ;;^^%g;
,4 Dichlorobenzene-d4 I
n-Nitrosodimethylamine
Cumene
henol C
4lniline
bis-(2-Chloroethyl)ether
enzyl Chloride
,4-Dichlorobenzene C
2-Methylphenol
\cetophenone
-Nitrosomorpholine
o-Toluidine
Hexachloroethane
,2-Dibromo-3-chloropropane
. J,N-Diethylaniline
Naphthalene-d8 I
/4-Methylphenol
litrobenzene
N,N-Dimethylaniline
T".ophorone
-Anisidine
1,4-Phenylenediamine
1,2,4-Trichlorobenzene
texachlorobutadiene C
_,a,a-Trichlorotoluene
Hydroquinone
-Chloroacetophenone
.cenaphthene-dlO I
Hexachlorocyclopentadiene - P
°,4,6-Trichlorophenol C
,4,5-Trichlorophenol
oiphenyl
Dimethylphthalate
,4-Dinitrophenol P
.-Nitrophenol P
2,4-Dinitrotoluene
"Hbenzofuran
,6-Dinitro-2-methylphenol
?\F^
0.550
2.256
1.287
1.645
0.821
2.203
1.383
0.963
1.499
0.610
1.668
0.629
0.619
1.703
0.317
0.480
0.480
0.559
0.269
0.358
0.338
0.188
0.375
0.363
0.713
0.292
0.326
0.365
1.278
1.059
0.281
1.508
Rfso
0.616
2.248
1.390
1.695
0.802
2.226
1.384
1.076
1.517
0.618
1.709
0.655
0.622
1.816
0306
0.488
0.482
0.582
0.267
0368
0318
0.186
0391
0356
0.733
0.330
0.363
0.418
1.337
1.149
0.094
0.246
0.321
1.486
0.145
*JH*;
0593
2.078
1.278
1.642
0.758
2.159
1.292
1.005
1.389
0579
1597
0.615
0.599
1.615
0.317
0.479
0.468
0.574
0.247
0.355
0.315
0.181
0.390
0358
0.676
0.344
0.334
0378
1.215
1.037
0.105
0.240
0317
1.483
0.159
OK*
0.620
2.195
1366
1.714
0.772
2.139
1.274
1.062
1.454
0.601
1.712
0.621
0.609
1.701
0.295
0.469
0.473
0.565
0.257
0348
0.306
0.178
0.369
0.341
0.696
0.363
0364
0.409
1.341
1.116
0.130
0.263
0.341
1.478
0.186
|»fcj
0.621
2.238
1329
1.686
0.832
2.237
1.294
1.040
1.352
0.579
1.569
0.623
0.599
1.700
0.325
0.471
0.468
0.601
0.260
0.354
0.313
0.182
0.404
0.368
0.779
0.353
0.371
0.409
1.311
1.088
0.155
0.291
0.363
1.522
0.207
rfEAN
0.600
2.203
1.330
1.676
0.797
2.193
1.325
1.029
1.442
0597
1.651
0.629
0.610
1.707
0312
0.477
0.474
0.576
0.260
0.357
0.318
0.183
0386
0.357
0.719
0.336
0.351
0.396
1.296
1.090
0.121
0.260
0.325
1.495
0.175
^^M;\Sr^l
5.1
33
3.7
1.9
3.9
1.9
4.0
4.4
4.9
3.0
4.0
2.5
1.8
4.2
3.8
1.6
1.4
2.8
3.4
2.1
3.8
2.2
3.6
2.9
5.5
8.2
5.7
5.7
4.0
4.1
22.5
8.8
9.4
1.2
15.9
*- Fails QC Criteria for %RSD;« - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc
""!! Capitola Drive • Durham, North Carolina 27713
lone: (919) 544-5729 • Fax: (919) 544-5491
Savar v35
-------
Triangle Laboratories of RTF, Inc.
Initial Calibration Curve
ICAL File: ICALYO22
RF20 YP772
RF120 YP769
Date of Analysis -.10/22/97
RF50 YP771
RF160 YP768
Analyte List: 8270A
RF80 YP770
£aalyfceA> \ > ->-" .4- ^ fj> ^v^|t
•. x % ^.^..^...^X.^l^.'i.. ^< Y^.l:s^K
, % JtfSO /.
Trifluralin
Phenanthrene-dlO
Di-n-butylphthalate
Hexachlorobenzene
4-Aminobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-dl2
Benzidine
4,4'-Methylenedianiline
Dimethylaminoazobenzene
S/S'-Dimethylbenzidine
33'-Dimethoxybenzidine
33'-Dichlorobenzidine
Methylene bis-chloroaniline
bis(2-Ethylhexyl)phthalate
0.163 0.199 0.210 0235 0.249 0.211 15.8
1.290 1537 1388 1371 1575 1.432 8.4
0.291 0.337 0.285 0.285 0.297 0.299 73
0.711 0.791 0.727 0.709 0.743 0.736 4.6
0.177 0.172 0.174 0.187 0.178 35
0.072 0.084 0.079 0.078 0.082 0.079 6.0
0.199 0.310 0.284 0.292 0.317 0.281 16.9
0.662 0.758 0.747 0.768 0.894 0.766 10.9
0.258 0.323 0.316 0.323 0386 0.321 14.2
0316 0.375 0.375 0.377 0-408 0.370 9.0
0.472 0.605 0.573 0.522 0.670 0.568 13.4
0.211 0.293 0.295 0.289 0321 0.282 14.8
0.412 0.444 0.422 0.414 0.481 0.434 6.6
0.164 0.197 0.186 0.177 0.200 0.185 8.1
0.844 0.944 0.957 0.938 1.046 0.946 7.6
Approved by:.
Date li in /?7
*- Fails QC Criteria for %RSD; « - Rf less than minimum QC RF; »• RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.5
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-99-025
2.
4. TITLE AND SUBTITLE
Final Report - Volume I of II, Iron and Steel Foundries Manual Emissions Testing, Cupola Wet
Scrubber - General Motors Corp., Saginaw, Michigan
7. AUTHOR(S)
Franklin Meadows
Daniel F. Scheffel
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
1 2. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
July 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-70069
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating iron and steel foundries to identify and quantify hazardous air pollutants
(HAPs) emitted from cupolas; electric arc furnaces; and pouring, cooling and shakedown operations of sand mold casting processes. General Motors
Corporation, Saginaw Casting Operations (GMC), Saginaw, Michigan was selected by the EPA as the host facility at which to 1) characterize HAP
emissions from cupolas that are controlled by wet scrubbers, and 2) assess wet scrubber performance in controlling HAP emissions from cupolas. GMC
was selected because EPA deemed this facility to be representative of a large segment of the sand casting foundry industry and GMC operates a relatively
large cupola that is controlled by a wet scrubber.
This report presents the results of a manual emissions testing program to characterize emissions from a cupola and assess the performance of the wet
scrubber in controlling HAP emissions. Testing was conducted at the cupola wet scrubber inlet and outlet to determine air emissions of paniculate
matter (PM) and metal HAPs; and at the cupola wet scrubber outlet to determine organic HAPs consisting of dibenzo-p-dioxins and polychlorinated
dibenzodurans (PCDDs/PCDFs) and semi-volatile organic hazardous air pollutnats (SVOHAPs), and volatile organic hazardous air pollutants (VOHAPs)
The data may be used by the EPA as potential Maximum Achievable Control Technology (MACT) floor technology for cupolas.
During the testing program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission control system
operating parameters, and prepared Section 3.0, Process and Control Equipment operation, of this report.
This volume (Volume I) is comprised of 688 pages and consists of the report text, and Appendices: A (Raw Field Data) and B (Analytical Data -
PCDFs/PCDDs and SVOHAPs).
17. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTIONS
Cupola
Dioxins/Furans
Emission Measurements
Hazardous Air Pollutants
Metals
Particulate Matter
Semi-Volatile Organic Hazardous
Air Pollutants
Volatile Organic Hazardous Air
Pollutants
Wet Scrubber
18. DISTRIBUTION STATEMENT
Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
1,159
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
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