United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-025A
July 1999
AIR
   Final Report - Volume I of II

   Iron and Steel Foundries
   Manual Emissions Testing
   Cupola Wet Scrubber
   General Motors Corp.

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                FINAL REPORT

         IRON AND STEEL FOUNDRIES
         MANUAL EMISSIONS TESTING
           CUPOLA WET SCRUBBER
GENERAL MOTORS CORP., SAGINAW, MICHIGAN

                VOLUME I OF II
       REPORT TEXT & APPENDICES A & B
            EPA Contract No. 68D70069
             Work Assignment No. 2-08

                  Prepared for:

           Mr. Michael K. Ciolek (MD-19)
             Work Assignment Manager
              SMAG, EMC, OAQPS
        U.S. Environmental Protection Agency
         Research Triangle Park, NC 27711

                   July 1999
                P:\i528\fmrpt\gm\gmfin.rep

                  Submitted by

    PACIFIC ENVIRONMENTAL SERVICES, INC.
           5001 S. Miami Blvd., Suite 300
              Post Office Box  12077
        Research Triangle Park, NC 27709-2077
                 (919)941-0333

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                                  DISCLAIMER

      This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-08.  This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.

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                        TABLE OF CONTENTS


VOLUME I                                                     Page

1.0   INTRODUCTION	1-1

2.0   SUMMARY OF RESULTS 	2-1

     2.1   EMISSIONS TEST LOG	2-1
     2.2   PARTICULATE MATTER AND METALS 	2-1
     2.3   DIOXINS AND FURANS	2-7
     2.4   SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS	2-14
     2.5   VOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS 	2-28

3.0   PROCESS DESCRIPTION	3-1

     3.1   INTRODUCTION	3-1
     3.2   PROCESS DESCRIPTION	3-1
     3.3   PROCESS AND CONTROL DEVICE MONITORING RESULTS 	3-8

4.0   SAMPLING LOCATIONS	4-1

     4.1   CUPOLA WET SCRUBBER INLET	4-1
     4.2   CUPOLA WET SCRUBBER OUTLET	4-1

5.0   SAMPLING AND ANALYTICAL PROCEDURES 	5-1

     5.1   LOCATION OF MEASUREMENT SITES AND
          SAMPLE/VELOCITY TRAVERSE POINTS 	5-1
     5.2   DETERMINATION OF STACK GAS VOLUMETRIC
          FLOW RATE	5-1
     5.3   DETERMINATION OF DRY MOLECULAR WEIGHT
          AND EMISSIONS CORRECTION FACTORS	 5-1
     5.4   DETERMINATION OF STACK GAS MOISTURE CONTENT 	5-2
     5.5   DETERMINATION OF PARTICULATE MATTER
          AND METALS	5-3
     5.6   DETERMINATION OF DIOXINS AND FURANS	5-3
     5.7   DETERMINATION OF SEMIVOLATILE ORGANIC
          HAZARDOUS AIR POLLUTANTS (SVOHAPS) 	5-8

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                     TABLE OF CONTENTS (Concluded)

     5.8   DETERMINATION OF VOLATILE ORGANIC HAZARDOUS AIR
          POLLUTANTS (VOHAPs)	5-8

6.0   QUALITY ASSURANCE/QUALITY CONTROL (QA/QC)  	6-1

     6.1   CALIBRATION OF APPARATUS 	6-1
     6.2   ON-SITE MEASUREMENTS 	6-4
     6.3   LABORATORY ANALYSIS	6-8
     APPENDIX A - RAW FIELD DATA
     APPENDIX B - ANALYTICAL DATA, PCDDs/PCDFs AND SVOHAPs

VOLUME II

     APPENDIX C - ANALYTICAL DATA, PARTICULATE MATTER AND METALS
     APPENDIX D - CALCULATIONS
     APPENDIX E - QA/QC DATA
     APPENDIX F - PARTICIPANTS

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                                 LIST OF TABLES
VOLUME I
Table 2.1     Emissions Test Log, General Motors Corporation - Saginaw, Michigan	2-2
Table 2.2     Particulate Matter/Metals Emissions Sampling and Flue Gas Parameters,
             Cupola Wet Scrubber Inlet, General Motors Corporation, Saginaw,
             Michigan 	2-3
Table 2.3     Particulate Matter Concentrations and Emission Rates, Cupola
             Wet Scrubber Inlet, General Motors Corporation - Saginaw, Michigan	2-4
Table 2.4     Metals Concentrations and Emission Rates, Cupola Wet Scrubber Inlet,
             General Motors Corporation - Saginaw, Michigan	2-5
Table 2.5     Particulate Matter/Metals Emissions Sampling and Exhaust Gas Parameters,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan 	2-8
Table 2.6     Particulate Matter Concentrations and Emission Rates, Cupola Wet
             Scrubber Outlet, General Motors Corporation - Saginaw, Michigan  	2-9
Table 2.7     Exhaust Gas Metals Concentrations and Emission Rates, Cupola Wet
             Scrubber Outlet, General Motors Corporation - Saginaw, Michigan  	2-10
Table 2.8     Particulate Matter and Metals Removal Efficiencies, Cupola Wet
             Scrubber, General Motors Corporation - Saginaw, Michigan	2-12
Table 2.9     PCDDs/PCDFs Emissions Sampling and Exhaust Gas Parameters,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan  	2-13
Table 2.10    PCDDs/PCDFs Exhaust Gas Concentrations and Emission Rates,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan  	2-15
Table 2.11    PCDDs/PCDFs Exhaust Gas Concentrations and 2378 Toxic Equivalent
             Stack Gas Concentrations Adjusted to 7 Percent Oxygen,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan 	2-16
Table 2.12    SVOHAPs Emissions Sampling and Exhaust Gas Parameters,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw
             Michigan 	2-17
Table 2.13    SVOHAPs Exhaust Gas Concentrations and Emission Rates, Cupola
             Wet Scrubber Outlet, General Motors Corporation - Saginaw, Michigan .... 2-19
Table 2.14    SVOHAPS Detection Limits, PPBVD, Cupola Wet Scrubber Outlet,
             General Motors Corporation - Saginaw, Michigan	 2-26

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                              LIST OF TABLES (Concluded)
VOLUME I
Table 3.1     Typical Cupola Charge Materials 	3-3
Table 3.2     Typical Results from Greens Sand Analysis	3-6
Table 3.3     Chemicals Used in Core Making and Mold Spraying	3-7
Table 3.4     Summary of Cupola Monitoring Results	3-9
Table 3.5     Summary of Cupola Charging During the Test Days 	3-10
Table 3.6     Summary of Number of Molds Poured on Line 4	3-14
Table 3.7     Summary of Metal Poured and Downtime for Line 4	3-15
Table 3.8     Line 4 Mold Counts During Testing Periods	3-16
Table 3.9     Mold Line 4 Production During Testing Periods	3-18

Table 5.1     Sources, Test Parameters, and Test Methods Summary,
             General Motors Corporation - Saginaw, Michigan	5-2

Table 6.1     Summary of Temperature Sensor Calibration Data	6-2
Table 6.2     Summary of Pitot Tube Dimensional Data	6-3
Table 6.3     Summary of Dry Gas Meter and Orifice Calibration Data 	6-5
Table 6.4     Summary of EPA Methods 23 and 29 and SW-846 Method 0010
             Field Sampling QA/QC Data	6-7
Table 6.5     Summary of EPA Method 29 Analysis QC Data, Lab Control Spikes	6-9
Table 6.6     Summary of EPA Method 29 Analysis QC Data, Matrix Spikes
             (Post Digestion)	6-10
Table 6.7     Summary of EPA Method 29 Analysis QC Data, Duplicate Analyses	6-11
Table 6.8     Summary of EPA Method 29 Analysis QC Data, Serial Dilution	6-12
Table 6.9     Summary of EPA Method 29 Analysis QC Data, Method Blanks Results ... 6-13
Table 6.10    Summary of EPA Method 29 Analysis QC Data, Field Blanks Results	6-14
Table 6.11    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Lab Control Spikes 	6-15
Table 6.12    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Matrix Spikes (Pre-Digestion)	6-16
Table 6.13    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Method Blank 	6-17
Table 6.14    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Field  and Reagent Blanks  	6-18
Table 6.15    Summary of EPA Method 23 Standards Recovery Efficiencies  	6-20
Table 6.16    SW-846 Method 0010 Field and Laboratory Blanks Results 	6-21
Table 6.17    SW-846 Method 0010 Surrogate Recovery Results 	6-22

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                                 LIST OF FIGURES


VOLUME I                                                                     Page

Figure 1.1     Key Personnel and Responsibility for Testing at GM - Saginaw, Michigan ... 1-3

Figure 3.1     Schematic of the Cupola Gas Handling System 	3-2
Figure 3.2     Schematic of Capture and Control System for Line 4	3-5
Figure 3.3     Hot Blast Temperature During Each Test Run   	3-11
Figure 3.4     Hot Blast Rate During the Test Runs	3-12

Figure 4.1     Cupola Wet Scrubber Inlet Sampling Location	4-2
Figure 4.2     Cupola Wet Scrubber Inlet Traverse Points Locations  	4-3
Figure 4.3     Cupola Wet Scrubber Outlet Sampling Location 	4-4
Figure 4.4     Cupola Wet Scrubber Outlet Traverse Point Locations	4-5

Figure 5.1     EPA Method 29 Sampling Train Schematic 	5-4
Figure 5.2     EPA Method 29 Sample Recovery Scheme	5-5
Figure 5.3     EPA Method 29 Sample Preparation and Analysis Scheme  	5-6
Figure 5.4     EPA Method 23 (PCDD/PCDF) and SW-846 Method 0010
             Sampling Train Schematic	5-7
Figure 5.5     Schematic of Direct Interface GC/MS Sampling System 	5-9

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                                 1.0  INTRODUCTION
       The U.S. Environmental Protection Agency (EPA) Emission Standards Division (BSD) is
investigating iron and steel foundries to identify and quantify hazardous air pollutants (HAPs)
emitted from cupolas; electric arc furnaces; and pouring, cooling and shakeout operations of sand
mold casting processes. BSD had requested that EPA's Emissions, Monitoring and Analysis
Division (EMAD) conduct the required testing. EMAD had issued a work assignment to Pacific
Environmental Services, Inc. (PES) to plan and conduct the air emissions test program to gather
emissions data as specified in the BSD test request. The planning and testing phase of the
program was conducted through EPA Contract No. 68D20162, Work Assignment No. 4-14.
This test report was completed under EPA Contract No. 68D70069, Work Assignment No. 2-08.

       The EPA's BSD is investigating two types of control devices  (baghouses and scrubbers)
as potential Maximum Achievable Control Technology (MACT) floor technology for cupolas.
Two facilities were selected by BSD as host facilities for the testing program. One uses a
baghouse for control of cupola emissions, and the other uses a wet scrubber for the control of
cupola emissions. General Motors  Corporation, Saginaw Metals Casting Operations (GMC),
located in Saginaw, Michigan, uses a wet scrubber and was the subject of this test program.
Results of tests on a baghouse at the second facility were presented under a separate report.

       Testing at GMC was conducted by two EMAD contractors to address the following BSD
requirements: 1) characterize HAP  emissions from cupolas that are controlled by wet scrubbers;
2) characterize uncontrolled HAP emissions from pouring, cooling, and shakeout (PCS)
processes; 3) determine wet scrubber performance in controlling HAP emissions from cupolas;
and 4) identify surrogates for estimating HAP emissions from the subject foundry processes.
PES conducted testing for requirements (1) and (3).  Data gathering for requirements (2) and (4)
was conducted by the other contractor and is not a part of this document.

       GMC was selected by the BSD as the host facility for this project. This facility is a large
foundry that conducts melting and casting operations.  EPA deemed this facility to be
representative of a large segment of the sand casting foundry industry. It operates a relatively
large cupola that is controlled by a wet scrubber. Tests were conducted at the cupola wet
scrubber inlet and outlet. PES performed particulate matter (PM) and metals (HAPs and non-
HAPs) testing at the cupola wet scrubber inlet and outlet, and organic HAPs  testing at the
scrubber outlet. The organic HAPs consisted of polychlorinated dibenzo-/?-dioxins and
polychlorinated dibenzofurans (PCDDs/PCDFs) and semi-volatile organic hazardous air
pollutants (SVOHAPs). Volatile organic hazardous air pollutants (VOHAPs) were measured by
direct interface gas chromatography/mass spectrometry (GC/MS) at the scrubber outlet.

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       PES used four subcontractors for this effort: Deeco, Inc. (DEECO); Emission
Monitoring, Inc. (EMI); Triangle Laboratories, Inc. (TLI); and Atlantic Technical Services, Inc.
(ATS). DEECO provided onsite sampling support for the determination of PM and metal HAPs;
EM provided onsite sampling and analysis by direct interface GC/MS for the determination of
VOHAPs; TLI provided analytical support for the analysis of HAPs; and ATS provided support
for preparation of the site-specific test plan (SSTP), quality assurance project plan (QAPP), and
report documentation.

       The field testing program organization and major lines of communication are presented in
Figure 1.1. The PES Project Manager communicated directly with the EPA Work Assignment
Manager and coordinated all of the on-site testing activities.

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    GMC

David F. Genske
(517)757-1455
                                              EPA/EMC
                                       Work Assignment Manager

                                           Michael K. Ciolek
                                            (919) 541-4921
 Jim Maysilles
(919)541-3265
                                           John Chehaske
                                           (703) 471-8383
                                            Dan Scheffel
                                           (513)398-2556
Wayne Westbrook
 (919) 941-0333

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                            2.0  SUMMARY OF RESULTS

       This section provides test results summaries obtained from GMC testing.  Included are
results of the tests conducted for particulate matter/metals at the cupola wet scrubber inlet and
outlet, and S VOHAPs and PCDDs/PCDFs testing at the cupola wet scrubber outlet.  Although
we have included averages, there were differences in production rates and operating conditions.
It should also be noted that the inlet sample location was located after the quench chamber.  The
quench chamber is the first stage of the particulate matter/metals control system.  A true removal
efficiency can not be determined based on the inlet sample loading.
2.1    EMISSIONS TEST LOG

       Sampling at the cupola wet scrubber was conducted on September 23,24, and 25,1997.
Table 2.1 summarizes the emissions test log. Presented are the run numbers, test dates,
pollutants, run times, and downtime for filter and port changes.
2.2    PARTICULATE MATTER AND METALS

2.2.1  Wet Scrubber Inlet

       Table 2.2 summarizes the particulate matter and metals emissions sampling and flue gas
parameters at the wet scrubber inlet. The total sampling time varies for each test run with an
average of 148 minutes.  The average sample volume was 97.591 dry standard cubic feet (dscf)
or 2.763 dry standard cubic meters (dscm). The average flue gas temperature was 131 °F. The
flue gas contained 9.8 percent (%) carbon dioxide (CO2), 12.3% oxygen (O2), and 16.6%
moisture.  The average flue gas volumetric flow rate was 82,300 actual cubic feet per minute
(acfm) or 57,400 dry standard cubic feet per minute (dscfin) or 1,630 dry standard cubic meters
per minute (dscmm).

       Table 2.3 summarizes the flue gas particulate matter concentrations and emission rates at
the cupola wet scrubber inlet. The average concentration was 0.363  grains per dry standard cubic
foot (gr/dscf) or 0.830 grams per dry standard cubic meter (g/dscm). The concentrations are also
shown adjusted to 7% O2. The average mass emission rate was 177 pounds per hour (Ib/hr) or
80.4 kilograms per hour (kg/hr).

       Table 2.4 summarizes the flue gas metals concentrations and emission rates.  The metals
concentrations shown by the reagent blank analysis for the acetone rinse, filters (3 inch and 4
inch), dilute nitric acid rinse, and metals absorbing solution (acidified hydrogen peroxide) were



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                   TABLE 2.1
              EMISSIONS TEST LOG
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Wet Scrubber Inlet

I-M29-1
I-M29-2
I-M29-3
I-M29-4
Wet Scrubber Outlet

O-M29-1
SO-23-1
SO-0010-1
O-M29-2
SO-23-2
SO-0010-2
O-M29-3
SO-23-3
SO-0010-3
O-M29-4
SO-23-4
SO-0010-4
Date

09/23/97
09/24/97
09/25/97
09/25/97

09/23/97
09/23/97
09/23/97
09/24/97
09/24/97
09/24/97
09/25/97
09/25/97
09/25/97
09/25/97
09/25/97
09/25/97
Pollutant

PM/Metals
PM/Metals
PM/Metals
PM/Metals

PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
PM/Metals
PCDDs/PCDFs
SVOHAPs
Run Time

1410-1841
0934-1343
0838-1149
1512-1845

1412-1846
1415-1846
1415-1847
0938-1347
0851-1347
0851-1400
0845-1145
0844-1321
0844-1321
1523-1843
1443-1918
1443-1919
Downtime,
Minutes

156
12
71
103

164
161
162
9
56
69
60
37
37
80
35
36

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                                   TABLE 2.2

     PARTICULATE MATTER/METALS EMISSIONS SAMPLING AND FLUE GAS
                 PARAMETERS, CUPOLA WET SCRUBBER INLET
           GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm "
Sample Volume:
dscf"
dscmc
Average Flue Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Flue Gas Volumetric Flow Rate:
acfind
dscfm a
dscmm d
Isokinetic Sampling Ratio, %
I-M29-1
9/23/97
115
0.517

59.458
1.684
125
12.3
8.9
14.0

82,000
60,200
1,700
102.3
I-M29-2
9/24/97
237.3
0.515

122.140
3.459
128
12.7
9.4
15.1

81,100
58,700
1,660
104.5
I-M29-3
9/25/97
120
0.881

105.757
2.995
133
12.2
10.0
17.7

82,900
56,100
1,590
102.0
I-M29-4
9/25/97
120
0.858

103.008
2.917
137
11.9
11.0
19.7

83,300
54,700
1,550
105.1
Average

148
0.693

97.591
2.763
131
12.3
9.8
16.6

82,300
57,400
1,630
103.5
' Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at flue gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.

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                                   TABLE 2.3

        PARTICULATE MATTER CONCENTRATIONS AND EMISSION RATES
                         CUPOLA WET SCRUBBER INLET
           GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Concentration:
gr/dscfa
gr/dscf@7%O2b
g/dscmc
g/dscm@7%O2d
Emission Rate:
lb/hre
kg/hrf
I-M29-1
9/23/97
1410-1841

0.269
0.434
0.615
0.994

138.6
62.9
I-M29-2
9/24/97
0934-1343

0.335
0.568
0.767
1.30

169
76.5
I-M29-3
9/25/97
0838-1149

0.387
0.618
0.885
1.41

186
84.4
I-M29-4
9/25/97
1512-1845

0.459
0.710
1.051
1.62

215
97.7
Average



0.363
0.583
0.830
1.33

177
80.4
• Grains per dry standard cubic foot at 68° F (20° C) and 1 atm.
b Grains per dry standard cubic foot at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
c Grams per dry standard cubic meter at 68° F (20° C) and 1 atm.
d Grams per dry standard cubic meter at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
e Pounds per hour.
f Kilograms per hour.

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                  TABLE 2.4
   METALS CONCENTRATIONS AND EMISSION RATES
          CUPOLA WET SCRUBBER INLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
lun No.
Date
Clock Time, 24-hr clock
Antimony (Sb)
Hg/dscm "
^dscm @ 7% O2 b
lb/hrc
Arsenic (As)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Jarium (Ba)
(ig/dscm a
ug/dscm @ 7% O2 b
lb/hr°
Beryllium (Be)
ug/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Cadmium (Cd)
ug/dscm •
ug/dscm @ 7% O2 b
lb/hrc
Chromium (Cr)
Hg/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Cobalt (Co)
ug/dscm *
Ug/dscm @ 7% O2 b
lb/hrc
Lead (Pb)
Hg/dscm °
ug/dscm @ 7% O2 b
lb/hrc
I-M29-1
9/23/97
1410-1841

37.2
60.1
0.00838

15.6
25.2
0.00351

183
295
0.0411

ND
ND
ND

49.2
79.6
0.01110

281
454
0.0633

12.9
20.8
0.00291

5,682
9,184
1.281
I-M29-2
9/24/97
0934-1343

15.5
26.2
0.00340

23.6
39.9
0.00518

319
541
0.0701

0.688
1.17
0.000151

69.8
118
0.0153

294
498
0.0646

11.8
20.0
0.00260

3,824
6,482
0.840
I-M29-3
9/25/97
0838-1149

70.6
113
0.0148

21.5
34.3
0.00451

248
397
0.0522

ND
ND.
ND

78.1
125
0.0164

259
414
0.0544

10.6
16.9
0.00222

8,269
13,211
1.74
I-M29-4
9/25/97
1512-1845

85.3
132
0.0175

28.3
43.7
0.00579

340
525
0.0696

ND
ND
ND

63.1
97.4
0.01293

247
382
0.0507

11.2
17.4
0.00230

8,777
13,556
1.80
Average



52.1
82.7
0.01102

22.2
35.8
0.00475

272
439
0.0583

0.172
0.292
0.0000378

65.1
105
0.01394

270
437
0.0583

11.6
18.8
0.00251

6,638
10,608
1.414

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                       TABLE 2.4 (Concluded)

         METALS CONCENTRATIONS AND EMISSION RATES
                  CUPOLA WET SCRUBBER INLET
      GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Manganese (Mn)
Hg/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Mercury (Hg)
ug/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Nickel (Ni)
ug/dscm1
ug/dscm @ 7% O2 b
lb/hrc
Phosphorus (P)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Selenium (Se)
|ig/dscm '
Ug/dscm @ 7% O2 b
lb/hrc
Silver (Ag)
|ig/dscm *
Ug/dscm @ 7% O2 b
lb/hrc
Thallium (Tl)
Ug/dscm '
Hg/dscm @ 7% O2 b
lb/hrc
Zinc (Zn)
|ig/dscm •
Hg/dscm @ 7% O2 b
lb/hrc
I-M29-1

36,405
58,840
8.21

4.75
7.68
0.001071

15.5
25.1
0.00350

243
393
0.0548

12.3
19.9
0.00277

6.35
10.3
0.00143

18.2
29.4
0.00410

45,858
74,119
10.34
I-M29-2

41,676
70,646
9.16

3.21
5.44
0.000705

13.2
22.3
0.00290

1,614
2,735
0.355

16.4
27.8
0.00360

7.85
13.3
0.00173

18.4
31.1
0.00404

47,631
80,740
10.47
I-M29-3

35,940
57,421
7.55

33.8
54.0
0.00710

15.2
24.3
0.00320

1,113
1,779
0.234

12.5
19.9
0.00262

10.2
16.3
0.00214

16.2
25.9
0.00340

64,566
103,157
13.57
I-M29-4

39,504
61,011
8.09

5.97
9.21
0.001222

11.6
17.9
0.00237

1,125
1,737
0.230

13.8
21.3
0.00282

6.17
9.53
0.001264

17.8
27.4
0.00364

85,608
132,217
17.5
Average

38,381
61,980
8.25

11.9
19.1
0.00252

13.9
22.4
0.00299

1,024
1,661
0.218

13.7
22.2
0.00295

7.64
12.3
0.00164

17.6
28.5
0.00379

60,916
97,558
12.98
• Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm, adjusted to 7% O2.
c Pounds per hour.

-------
used to blank correct the scrubber inlet metals concentrations. Blank corrections were made if
the blank target analyte was less than 10% of the sample concentration.  Average concentrations
ranged from 0.172 micrograms per dry standard cubic meter (^g/dscm) for beryllium to 60,916
ug/dscm for zinc.

2.2.2 Wet Scrubber Outlet

       Table 2.5 summarizes the particulate matter and trace metals emissions sampling and
exhaust gas parameters at the wet scrubber outlet.  The total sampling time varies for each test
with an average of 148 minutes.  The average sample volume was 113.671 dscf or 3.219 dscm.
The average exhaust gas temperature was 119°F. The exhaust gas contained 8.7 % CO2,13.4%
O2, and 12.0 % moisture.  The average exhaust gas volumetric flow rate was 73,200 acfm or
58,000 dscfrn (1,640 dscmm).

       Table 2.6 summarizes the exhaust gas particulate matter concentrations and emission
rates at the wet scrubber outlet.  The average concentration was 0.00952 gr/dscf or 0.0218
g/dscm. The concentrations are also shown adjusted to 7% O2. The average mass emission rate
was 4.78 Ib/hr or 2.17 kg/hr.

       Table 2.7 summarizes the exhaust gas metals concentrations and emission rates. The
metals concentrations shown by the field blank analysis were used to blank correct the scrubber
outlet multiple metals concentrations.  Blank corrections were made if the blank target analyte
was less than 10% of the sample concentration. All of the target metals, except arsenic,
beryllium, cobalt, and nickel, were found to  be present in all four samples.  Metals that were not
detected in a sample have "ND" in place of any emissions calculations and were not included in
the total metals sum. Average concentrations ranged from 0.075 ug/dscm for beryllium to 1,919
jag/dscm for zinc.

2.2.3 Wet Scrubber Performance

       Table 2.8 summarizes the performance of the wet scrubber in controlling PM and total
HAP metals emissions.  The removal efficiencies for PM and total HAP metals are based on the
inlet and outlet mass emission rates. As noted previously, the inlet sampling location was
located after the quench chamber. The scrubber performance does not  include the
particulate/metals removed by the quench chamber. As a result of the inlet sample location, the
particulate/metals removal efficiencies are biased low. The average removal efficiency for PM
and total HAP metals was 97.3% and 96.0%, respectively.
2.3    DIOXINS AND FURANS

       Table 2.9 summarizes the PCDDs/PCDFs emissions sampling and exhaust gas
parameters at the wet scrubber outlet.  The total sampling time was 110 minutes for the first run,
and 240 minutes for the additional three runs.  The average sample volume was 161.244 dscf or
4.566 dscm. The average exhaust gas temperature was 119°F.  The flue gas contained 8.7%



-------
                                   TABLE 2.5

     PARTICULATE MATTER/METALS EMISSIONS SAMPLING AND EXHAUST
              GAS PARAMETERS CUPOLA WET SCRUBBER OUTLET
           GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm "
Sample Volume:
dscfb
dscmc
Average Exhaust Gas Temp,, °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfmd
dscfm1
dscmm8
Isokinetic Sampling Ratio, %
O-M29-1
9/23/97
110
0.692

76.163
2.157
125
16.7
4.0
13.0

80,200
62,800
1,780
95.4
O-M29-2
9/24/97
240
0.633

151.911
4.302
133
11.8
10.6
16.4

74,000
55,200
1,560
99.3
O-M29-3
9/25/97
120
0.946

113.491
3.214
109
12.5
9.7
9.2

68,700
56,600
1,600
97.8
O-M29-4
9/25/97
120
0.943

113.118
3.203
109
12.4
10.3
9.6

69,800
57,500
1,630
95.9
Average

148
. 0.803

113.671
3.219
119
13.4
8.7
12.0

73,200
58,000
1,640
97.1
* Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic meters per minute at 68° F (20° C) and 1 arm.

-------
                                     TABLE 2.6

        PARTICULATE MATTER CONCENTRATIONS AND EMISSION RATES
                        CUPOLA WET SCRUBBER OUTLET
            GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Concentration:
gr/dscfa
gr/dscf@7%O2b
g/dscm c
g/dscm@7%O2d
Emission Rate:
lb/hre
ke/hrf
O-M29-1
9/23/97
1412-1846

0.0150
0.0497
0.0344
0.114

8.08
3.66
O-M29-2
9/24/97
0938-1347

0.0161
0.0246
0.0368
0.0562

7.61
3.45
0-M29-3
9/25/97
0845-1145

0.00352
0.00583
0.00806
0.0133

1.71
0.776
O-M29-4
9/25/97
1523-1843

0.00347
0.00567
0.00793
0.0130

1.71
0.775
Average



0.00952
0.0214
0.0218
0.0491

4.78
2.17
• Grains per dry standard cubic foot at 68° F (20° C) and 1 atm.
b Grains per dry standard cubic foot at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
c Grams per dry standard cubic meter at 68° F (20° C) and 1 atm.
d Grams per dry standard cubic meter at 68° F (20° C) and 1 atm adjusted to 7 percent O2.
' Pounds per hour.
f Kilograms per hour.

-------
                      TABLE 2.7
EXHAUST GAS METALS CONCENTRATIONS AND EMISSION RATES
            CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
*un No.
Date
Clock Time, 24-hr clock
Antimony (Sb)
ug/dscm '
ug/dscm @ 7% O2b
lb/hrc
Arsenic (As)
ug/dscm "
ug/dscm @ 7% O2b
lb/hrc
3arium (Ba)
ug/dscm "
ug/dscm @ 7% O2b
lb/hrc
Beryllium (Be)
ug/dscm *
Hg/dscm@7%O2b
lb/hrc
Cadmium (Cd)
ug/dscm *
ug/dscm @ 7% O2b
lb/hrc
Chromium (Cr)
Hg/dscm*
ug/dscm @ 7% O2b
lb/hrc
Cobalt (Co)
ug/dscm "
ug/dscm @ 7% O2b
lb/hrc
Lead (Pb)
ug/dscm '
ug/dscm @ 7% O2b
lb/hrc
O-M29-1
9/23/97
1412-1846

5.19
17.2
0.00122

2.72
8.99
0.000639

24.6
81.5
0.00579

0.158
0.522
0.0000371

3.96
13.1
0.000930

29.3
96.8
0.00688

ND
ND
ND

382
1,265
0.0899
O-M29-2
9/24/97
0938-1347

3.47
5.29
0.000716

1.61
2.45
0.000332

24.1
36.9
0.00499

0.144
0.220
0.0000298

5.37
8.21
0.00111

23.8
36.4
0.00492

1.33
2.04
0.000276

366
559
0.0756
O-M29-3
9/25/97
0845-1145

2.88
4.76
0.000610

ND
ND
ND

11.5
19.0
0.00244

ND
ND
ND

1.23
2.03
0.000260

8.46
14.0
0.00180

0.672
1.11
0.000143

141
234
0.0299
O-M29-4
9/25/97
1523-1843

2.61
4.27
0.000563

ND
ND
ND

7.52
12.3
0.00162

ND
ND
ND

0.659
1.08
0.000142

6.03
9.85
0.00130

ND
ND
ND

71.5
117
0.0154
Average



3.54
7.88
0.000778

1.51
3.56
0.000334

17.0
37.4
0.00371

0.075
0.185
0.0000167

2.80
6.10
0.000610

16.9
39.3
0.00372

1.16
2.69
0.000256

240
544
0.0527

-------
                       TABLE 2.7 (Concluded)

  EXHAUST GAS METALS CONCENTRATIONS AND EMISSION RATES
                 CUPOLA WET SCRUBBER OUTLET
      GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
lun No.
Manganese (Mn)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
Vlercury (Hg)
ug/dscm "
ug/dscm @ 7% O2 b
lb/hrc
Nickel (Ni)
ug/dscm "
Hg/dscm @ 7% O2 b
lb/hrc
'hosphorus (P)
Hg/dscm a
ug/dscm @ 7% O2 b
lb/hrc
Selenium (Se)
ug/dscm "
(ig/dscm @ 7% O2 b
lb/hrc
Silver (Ag)
ug/dscm11
ug/dscm @ 7% O2 b
lb/hrc
Thallium (Tl)
ug/dscm '
ug/dscm @ 7% O2 b
lb/hrc
Zinc (Zn)
ug/dscm '
Ug/dscm @ 7% O2 b
lb/hrc
O-M29-1

2,984
9,875
0.702

4.81
15.9
0.00113

4.57
15.1
0.00107

146
484
0.0344

2.89
9.56
0.000679

2.34
7.75
0.000551

1.99
6.58
0.000468

3,082
10,200
0.725
O-M29-2

2,510
3,834
0.518

4.98
7.61
0.00103

2.80
4.28
0.000579

15.0
22.9
0.00310

2.15
3.28
0.000444

1.83
2.80
0.000378

1.20
1.83
0.000247

2,953
4,511
0.610
O-M29-3

475
786
0.101

17.1
28.2
0.00362

1.99
3.29
0.000422

30.1
49.8
0.00639

1.57
2.61
0.000334

0.660
1.09
0.000140

0.380
0.628
0.0000805

862
1,426
0.183
O-M29-4

324
530
0.0698

5.61
9.17
0.00121

ND
ND
ND

18.5
30.3
0.00400

1.59
2.60
0.000343

0.562
0.919
0.000121

0.462
0.756
0.0000996

781
1,277
0.168
Average

1,573
3,756
0.348

8.12
15.2
0.00175

2.80
6.43
0.000618

52.4
147
0.0120

2.05
4.51
0.000450

1.35
3.14
0.000298

1.01
2.45
0.000224

1,919
4,353
0.421
' Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm.
b Micrograms per dry standard cubic meter at 68° F (20° C) and 1 atm, adjusted to 7% O2.
0 Pounds per hour.

-------
                               TABLE 2.8

       PARTICULATE MATTER AND METALS REMOVAL EFFICIENCIES
                        CUPOLA WET SCRUBBER
          GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Test Set No.
Date
PM Emission Rate, lb/hr:a
Inlet
Outlet
Removal Efficiency, %: b
Total Metals Emission Rate, lb/hr:a
Inlet
Outlet
Removal Efficiency, %: b
M29-1
9/23/97

139
8.08
94.2

20.0
1.57
92.2
M29-2
9/24/97

169
7.61
95.5

21.0
1.22
94.2
M29-3
9/25/97

186
1.71
99.1

23.3
0.330
98.6
M29-4
9/25/97

215
1.71
99.2

27.8
0.263
99.1
Average


177
4.78
97.3

23.0
0.846
96.0
1 Pounds per hour.
b Percent removal efficiencies are calculated using the emission rates (Ib/hr).

-------
                                   TABLE 2.9

     PCDDS/PCDFS EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
                       CUPOLA WET SCRUBBER OUTLET
           GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfm '
Sample Volume:
dscf"
dscrn0
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfm"
dscfm*
dscmm'
Isokinetic Sampling Ratio, %
O-23-1
9/23/97
110
0.499

54.895
1.554
125
16.7
4.0
12.2

65,300
51,600
1,460
93.0
O-23-2
9/24/97
240
0.629

151.041
4.277
133
11.8
10.6
16.2

73,600
54,900
1,560
101.5
O-23-3
9/25/97
240
0.904

217.061
6.146
110
12.5
9.7
8.7

64,600
53,200
1,510
103.4
O-23-4
9/25/97
240
0.925

221.977
6.286
108
12.4
10.3
8.5

66,500
55,200
1,560
102.0
Average

208
0.739

161.244
4.566
119
13.4
8.7
11.4

67,500
53,700
1,520
100.0
" Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
0 Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
" Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.

-------
CO2,13.4% O2, and 11.4% moisture. The average exhaust gas volumetric flow rate was 67,500
acfrn or 53,700 dscfin (1,520 dscmm).

       The EPA Method 23 sample extracts were first analyzed using a DB-5 capillary column
to determine the concentration of each isomer of PCDDs and PCDFs (tetra- through octa-).
Tetra-chlorinated dibenzofurans were detected in this analysis; therefore, another aliquot of the
sample was analyzed using a DB-225 capillary column to measure the 2,3,7,8 tetra-chloro
dibenzofuran isomer (2378 TCDF).

       Some PCDDs/PCDFs catch weights were reported as estimated maximum possible
concentration or EMPCs. Catch weights, concentrations, and emission rates based on EMPC
values were noted by enclosing them in brackets ({}). EMPC values were included in the four-
run averages and total PCDDs/PCDFs calculations. Averages or totals that were based  on EMPC
values were also enclosed in brackets to indicate the values were estimated.  The PCDDs/PCDFs
test results are presented in actual concentrations and mass emission rates, concentrations
adjusted to 7% O2, and concentrations adjusted to 7% O2 in 2378 TCDF toxic equivalents.

       Table 2.10 presents the PCDDs/PCDFs stack gas concentrations and emission rates. The
average concentration of total PCDDs was estimated to be {1.68} ng/dscm.  The average
concentration of total PCDFs was estimated to be {14.1} ng/dscm.  The average concentration of
total PCDDs/PCDFs was estimated to be {15.8} ng/dscm. These values corresponded to average
estimated emission rates of {152}, {1,290}, and {1,442} ng/hr, respectively.

       Table 2.11 presents the PCDDs/PCDFs concentrations adjusted to 7% O2. The average
measured stack gas O2 concentration was 13.4%. The average adjusted concentration of total
PCDDs was estimated to be {3.70} ng/dscm @ 7% O2.  The average adjusted concentration of
total PCDFs was estimated to be {29.6} ng/dscm @ 7% O2. The average adjusted concentration
of total PCDDs/PCDFs was {33.3} ng/dscm @ 7% O2.  The concentrations, adjusted to 7% O2,
were also adjusted by each congener's respective Toxic Equivalent Factor (TEF). The TEFs
used were the international TEF values. The average concentration for total PCDDs/PCDFs,
adjusted for the 2378 TCDD TEFs, was estimated to be {0.436} ng/dscm @ 7% O2.
2.4    SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS

       The semivolatile organic hazardous air pollutants (SVOHAPs) were collected using a
SW-846 Method 0010 Modified Method 5 (MM5) sampling train. The MM5 sampling train
collects organic-laden particulate materials and semi-volatile organics species. This method
speciates and quantitates low concentrations of these semi-volatile organics with boiling points
above 100°C.

       Table 2.12 summarizes the SVOHAPs emissions sampling and exhaust gas parameters at
the cupola wet scrubber outlet. The total sampling time was 110 minutes for Run 1 and 240
minutes for the additional three runs. The average sample volume was 162.319 dscf or 4.596

-------
                                       TABLE 2.10

       PCDDS/PCDFS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
                           CUPOLA WET SCRUBBER OUTLET
              GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN

CONGENER

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total CDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total CDFs
Total CDDs + CDFs
CONCENTRATION "
ng/dscm, as measured
O-23-1

{0.0322}
1.74
0.045
0.540
0.0129
{0.0129}
0.0193
0.122
0.0129
0.0129
0.0193
{2.43}

0.46
12.3
0.232
0.244
3.92
0.103
0.0450
0.0322
(ND)
0.444
{0.0450}
(ND)
0.0257
{0.00643}
{16.7}
{19.1}
O-23-2

0.0491
1.54
0.0538
0.561
0.0164
0.0187
0.0257
0.257
{0.0281}
0.0327
{0.0210}
{2.42}

0.54
14.0
0.327
0.327
5.66
0.213
0.108
0.0608
{0.00935}
1.10
{0.0701}
{0.0117}
0.0234
0.00935
{20.8}
{23.2}
O-23-3

0.0212
0.667
0.0163
0.120
(ND)
(ND)
(ND)
0.0390
(ND)
(ND)
{0.00651}
{0.833}

0.293
8.33
0.106
0.0765
1.74
0.0293
0.0146
0.00813
(ND)
0.150
0.00651
(ND)
0.00651
{0.00488}
{10.2}
{11.1}
0-23-4

0.0191
0.732
0.0159
0.207
0.00318
0.00477
0.00636
0.0652
{0.00477}
0.00477
0.0127
{1.02}

0.207
6.84
0.0970
0.0827
1.80
0.0414
0.0175
0.00955
(ND)
0.191
0.0111
(ND)
0.0111
{0.00159}
{8.84}
{9.86}
Average

{0.0304}
1.17
0.033
0.357
0.00810
0.00909
0.0128
0.121
0.0114
0.0126
{0.0149}
{1.68}

0.38
10.4
0.190
0.183
3.28
0.0966
0.0462
0.0277
0.00234
0.471
{0.0332}
0.00292
0.0167
{0.00556}
{14.1}
{15.8}
EMISSION RATE b
jig/hr
O-23-1

{2.82}
152
3.94
47.3
1.13
1.13
1.69
10.7
1.13
1.13
1.69
{213}

41
1,076
20.3
21.4
344
9.02
3.94
2.82
(ND)
38.9
{3.94}
(ND)
2.25
{0.564}
{1,462}
{1,675}
O-23-2

4.58
144
5.02
52.4
1.53
1.75
2.40
24.0
{2.62}
3.05
{1.96}
{225}

50
1,309
30.5
30.5
528
19.9
10.0
5.67
{0.87}
103
{6.55}
{1.09}
2.18
0.87
{1,943}
{2,168}
O-23-3

1.91
60.3
1.47
10.9
(ND)
(ND)
(ND)
3.53
(ND)
(ND)
{0.589}
{75.3}

26.5
753
9.56
6.92
157
2.65
1.32
0.736
(ND)
13.5
0.589
(ND)
0.589
{0.441}
{925}
{1,001}
O-23-4 (Average

1.79
68.6
1.49
19.4
{0.298}
0.447
0.597
6.12
{0.447}
0.447
1.19
{95.8}.

19.4
641
9.10
7.76
169
3.88
1.64
0.895
(ND)
17.9
1.04
(ND)
1.04
{0.149}
{829}
{925}

{2.78}
106
2.98
32.5
{0.74}
0.83
1.17
11.1
{1.05}
1.16
{1.36}
{152}

34
945
17.4
16.7
299
8.85
4.24
2.53
{0.218}
43.2
{3.03}
{0.273}
1.52
{0.507}
{1,290}
{1,442}
 " Nanogram per dry standard cubic meter at 20°C and 1 atm.
 b Micrograms per hour.
(ND) Non Detectable - Results are below target analyte detection limits. ND values are used as zeroes (0) in totals and averages.
{ } Estimated Maximum Possible Concentration. EMPC values are used as reported in totals and averages.

-------
                                        TABLE 2.11

  PCDDS/PCDFS EXHAUST GAS CONCENTRATIONS AND 2378 TOXIC EQUIVALENT
         STACK GAS CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
                           CUPOLA WET SCRUBBER OUTLET
             GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN


CONGENER


DIOXINS:
2378 TCDD
Total TCDD
I2378PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
1 2346789 OCDD
Total CDDs
FURANS:
2378 TCDF
Total TCDF
12378PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1 234678 HpCDF
1 234789 HpCDF
Total HpCDF
1 2346789 OCDF
Total CDFs
Total CDDs + CDFs
CONCENTRATION

(ng/dscm, adjusted to 7% O2)

O-23-1

(0.106)
5.75
0.149
1.79
0.0426
{0.0426}
0.0639
0.405
0.0426
0.0426
0.0639
(8.05)

1.53
40.7
0.766
0.809
13.0
0.341
0.149
0.106
(ND)
1.47
(0.149)
(ND)
0.0852
(0.0213)
(55.2)
(63.3)
O-23-2

0.0750
2.36
0.0821
0.857
0.0250
0.0286
0.0393
0.393
(0.0429)
0.0500
(0.0321)
(3.69)

0.82
21.4
0.500
0.500
8.64
0.325
0.164
0.0929
(0.0143)
1.68
(0.107)
(0.0179)
0.0357
0.0143
(31.8)
(35.5)
O-23-3

0.0350
1.10
0.0269
0.199
(ND)
(ND)
(ND)
0.0646
(ND)
(ND)
(0.0108)
(1.38)

0.48
13.8
0.175
0.127
2.88
0.0485
0.0242
0.0135
(ND)
0.248
0.0108
(ND)
0.0108
(0.00808)
(16.9)
(18.3)
O-23-4

0.0312
1.20
0.0260
0.338
0.00520
0.00780
0.0104
0.107
(0.00780)
0.00780
0.0208
(1.67)

0.34
11.2
0.159
0.135
2.94
0.0676
0.0286
0.0156
(ND)
0.312
0.0182
(ND)
0.0182
(0.00260)
(14.5)
(16.1)
Average

(0.0619)
2.60
0.0710
0.796
0.0182
(0.0193)
0.0284
0.242
(0.0233)
0.0335
(0.0319)
(3.70)

0.79
21.8
0.400
0.393
6.86
0.195
0.0915
0.0571
(0.00358)
0.927
(0.0713)
(0.00448)
0.0375
(0.0116)
(29.6)
(33.3)
2378-
TCDD*
Toxic
Equivalent
Factor

1.00

0.500

0.100
0.100
0.100

0.0100

0.00100


0.100

0.0500
0.500

0.100
0.100
0.100
0.100

0.0100
0.0100

0.00100


2378 TOXIC EQUIVALENT

(ng/dscm, adjusted to 7% O2)

O-23-1

(0.106)

0.0745

0.00426
(0.00426)
0.00639

0.000426

0.0000639
(0.196)

0.153

0.0383
0.405

0.0341
0.0149
0.0106
(ND)

(0.00149)
(ND)

(0.0000213)
(0.66)
(0.85)
O-23-2

0.0750

0.0411

0.00250
0.00286
0.00393

(0.000429)

(0.0000321)
(0.126)

0.082

0.0250
0.250

0.0325
0.0164
0.00929
(0.00143)

(0.00107)
(0.000179)

0.0000143
(0.418)
(0.544)
O-23-3

0.0350

0.0135

(ND)
(ND)
(ND)

(ND)

(0.0000108)
(0.0485)

0.048

0.00875
0.0633

0.00485
0.00242
0.00135
(ND)

0.000108
(ND)

(0.00000808)
(0.129)
(0.178)
O-23-4

0.0312

0.0130

0.000520
0.000780
0.00104

(0.0000780)

0.0000208
(0.0467)

0.034

0.00793
0.0676

0.00676
0.00286
0.00156
(ND)

0.000182
(ND)

(0.00000260)
(0.121)
(0.167)
Average

(0.0619)

0.0355

0.00182
(0.00198)
0.00284

(0.000233)

(0.0000319)
(0.104)

0.079

0.0200
0.196

0.0195
0.00915
0.00571
(0.000357)

(0.000713)
(0.0000446)

(0.0000116)
(0.331)
(0.436)
• Nanogram per dry standard cubic meter adjusted to 7 percent oxygen at 20°C and 1 atm.
b North Atlantic Treaty Organization, Committee on the challenges of Modern Society. Pilot study on International Information Exchange
  on Dioxins and Related Compounds:  International Toxicity Equivalency Factor (I-TEF) Methods of Risk Assessment for Complex
  Mixtures of Dioxins and Related Compounds. Report No. 176, August 1988.
(ND) Non Detectable - Results are below target analyte detection limits.  ND values are used as zeroes (0) in totals and averages.
{ } Estimated Maximum Possible Concentration. EMPC values are used as reported in totals and averages.

-------
                                   TABLE 2.12

       SVOHAPS EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
                        CUPOLA WET SCRUBBER OUTLET
           GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Total Sampling Time, min
Average Sampling Rate, dscfhi a
Sample Volume:
dscfb
dscmc
Average Exhaust Gas Temp., °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Vloisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfhid
dscfm"
dscmm6
Isokinetic Sampling Ratio, %
O-0010-1
9/23/97
110
0.640

70.444
1.995
125
16.7
4.0
12.7

74,600
58,600
1,660
98.4
O-0010-2
9/24/97
240
0.636

152.632
4.322
135
11.8
10.6
16.6

76,400
56,600
1,600
101.2
O-0010-3
9/25/97
240
0.881

211.429
5.987
111
12.5
9.7
9.3

64,400
52,700
1,490
101.1
O-0010-4
9/25/97
240
0.895

214.771
6.082
111
12.4
10.3
9.2

65,600
53,700
1,520
100.8
Average


0.763

162.319
4.596
121
13.4
8.7
11.9

70,300
55,400
1,570
100.4
• Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.

-------
dcsm. The average exhaust gas temperature was 121  °F. The exhaust gas contained 8.7% CO2,
13.4% O2, and 11.9% moisture. The average exhaust gas volumetric flow rate was 70,300 acfm
or 55,400 dscrm or 1,570 dscmm.

      The results of the semivolatile organic emissions are shown in Table 2.13.  Analysis was
performed for 70 target compounds. Of these 70 target compounds, 45 were not detected on any
of the four sample runs. In cases where a compound was not detected, the emission rate, and
concentration, was replaced with a "ND". If a compound was not detected in one of the four
runs, a zero was used in the four-run average for that compound and was not summed in any
SVOHAPs totals. Table 2.14 lists the target SVOHAPs detection limits.  Compounds that were
detected are indicated with a "D".

      Analysis for the SVOHAPs was performed using SW-846 Method 8270. The lower
quantitation limit for SW-846 Method 8270 for all but four compounds was 10 ug/sample. The
four compounds, 2,4-dinitrophenol, 4-nitrophenol, 4,6-dinitro-2-methylphenol and
pentachlorophenol, had quantitation limits of 25 jig/sample. Some samples had reported values
below the quantitation limit but above the detection limit.  This was the case for 19 of the 25
detected target compounds. Like the PCDDs/PCDFs, these values were reported as estimates
and all values and calculated results were enclosed by brackets ({}) to indicate that the
compound was detected but was below the  quantitation limit. These estimated values were used
in the four-run averages and the resulting averages were also enclosed in brackets to indicate the
values were estimated.

      Three compounds were detected in the run samples that were also detected in the
laboratory blank. Naphthalene, acetophenone, 2-chloroacetophenone, di-n-butylphthalate, and
bis(2-ethylhexyl)phthalate were detected in the method blank, but at amounts below the
quantitation limit. TLFs case narrative advises that target analytes in the laboratory blanks
should not be considered as truly present in the native samples unless found at five times the
amount found in the blank. In the case of di-n-butylphthalate, all four run samples had estimated
amounts that were greater than five times the blank and therefore should be considered truly
present in the native samples.  In the case of acetophenone, only  the third run had an estimated
amount slightly higher than five times the estimated lab blank value. In the case of bis(2-
ethylhexyl) phthalate, all four run samples had estimated catches that were more than five times
the estimated lab blank value.  In the case of naphthalene, all four run samples estimated catches
were more than five times that of the estimated blank value. In the case of 2-
chloroacetophenone, all four samples had values at non-detectable limits. The TLI's case
narrative also advises that "in the event that the amount of a target analyte found in the  samples is
twenty times the amount found in the associated blank, the contribution from the blank can be
considered negligible." The estimated amount of bis(2-ethylhexyl) phthalate in the second and
third run's sample were greater than 20 times the estimated blank value. Refer to Table 6.16 in
Section 6.0 for'a complete listing of all the detected or estimated SW-846 Method 0010 field,
method, and laboratory blanks compared to the average sample catch weights.

-------
                     TABLE 2.13
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
            CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Acenaphthene
Concentration, ppbvd"
Emission Rate, lb/hrb
Acenaphthylene
Concentration, ppbvd'
Emission Rate, lb/hrb
Acetophenone
Concentration, ppbvd"
Emission Rate, lb/hrb
4-Aminobiphenyl
Concentration, ppbvd"
Emission Rate, lb/hrb
Aniline
Concentration, ppbvd "
Emission Rate, lb/hrb
o-Anisidine
Concentration, ppbvd'
Emission Rate, lb/hrb
Anthracene
Concentration, ppbvd"
Emission Rate, lb/hrb
Benzidine
Concentration, ppbvd"
Emission Rate, lb/hrb
Benzo(a)anthracene
Concentration, ppbvd"
Emission Rate, lb/hrb
Benzo(b)fluoranthene
Concentration, ppbvd °
Emission Rate, lb/hrb
O-0010-1
9/23/97
1415-1847

2.19E-02
3.08E-05

{6.33E-02}
{8.91E-05}

8.22E-01
9.01E-04

ND
ND

ND
ND

ND
ND

1.76E-02
2.86E-05

ND
ND

ND
ND

ND
ND
O-0010-2
9/24/97
0851-1400

ND
ND

2.31E-02
3.14E-05

4.14E-01
4.38E-04

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-3
9/25/97
0844-1321

2.45E-02
3.10E-05

{5.58E-02}
{7.05E-05}

4.53E-01
4.47E-04

ND
ND

{1.38E-02}
{1.05E-05}

ND
ND

7.66E-03
1.12E-05

ND
ND

ND
ND

ND
ND
O-0010-4
9/25/97
1443-1919

1.59E-02
2.05E-05

{2.82E-02}
{3.64E-05}

2.86E-01
2.87E-04

ND
ND

ND
ND

ND
ND

6.21E-03
9.26E-06

ND
ND

ND
ND

ND
ND
Average



1.56E-02
2.06E-05

{4.26E-02}
{5.68E-05}

4.94E-01
5.18E-04

ND
ND

{3.45E-03}
{2.64E-06}

ND
ND

7.87E-03
1.23E-05

ND
ND

ND
ND

ND
ND

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
             CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Benzo(k)fluoranthene
Concentration, ppbvd*
Emission Rate, lb/hrb
Benzo(ghi)perylene
Concentration, ppbvd*
Emission Rate, lb/hrb
3enzo(a)pyrene
Concentration, ppbvd*
Emission Rate, lb/hrb
Benzo(e)pyrene
Concentration, ppbvd*
Emission Rate, lb/hrb
Benzyl Chloride
Concentration, ppbvd'
Emission Rate, lb/hrb
Biphenyl
Concentration, ppbvd*
Emission Rate, lb/hrb
2-Chloroacetophenone
Concentration, ppbvd'
Emission Rate, lb/hrb
bis-(2-Chloroethyl)ether
Concentration, ppbvd "
Emission Rate, lb/hrb
2-Chloronaphthalene
Concentration, ppbvd"
Emission Rate, lb/hrb
Chrysene
Concentration, ppbvd*
Emission Rate, lb/hrb
Cumene
Concentration, ppbvd a
Emission Rate, Ib/hr b
O-0010-1

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.67E-01}
{2.34E-04}

ND
ND

ND
ND

ND
ND

{1.16E-02}
{2.42E-05}

ND
ND
O-0010-2

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{4.40E-02}
{5.98E-05}

ND
ND

ND
ND

ND
ND

ND
ND

{2.59E-02}
{2.75E-05}
0-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

{7.20E-02}
{7.48E-05}

{1.33E-01}
{1.68E-04}

ND
ND

ND
ND

ND
ND

ND
ND

{5.21E-02}
{5.14E-05}
0-0010-4

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{6.41E-02}
{8.26E-05}

ND
ND

ND
ND

ND
ND

ND
ND

{1.48E-02}
{1.49E-05}
Average

ND
ND

ND
ND

ND
ND

ND
ND

{1.80E-02}
{1.87E-05}

{1.02E-01}
{1.36E-04}

ND
ND

ND
ND

ND
ND

{2.91E-03}
{6.05E-06}

{2.32E-02}
{2.34E-05}

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
             CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
!)ibenz(a,h)anthracene
Concentration, ppbvd'
Emission Rate, lb/hrb
Dibenzofuran
Concentration, ppbvd "
Emission Rate, lb/hrb
1 ,2-Dibromo-3-chloropropane
Concentration, ppbvd '
Emission Rate, lb/hrb
Di-n-butylphthalate
Concentration, ppbvd '
Emission Rate, lb/hrb
1 ,4-Dichlorobenzene
Concentration, ppbvd "
Emission Rate, lb/hrb
3,3'-Dichlorobenzidine
Concentration, ppbvd*
Emission Rate, lb/hrb
!^,N-Diethylaniline
Concentration, ppbvd'
Emission Rate, lb/hrb
3,3'-Dimethoxybenzidine
Concentration, ppbvd "
Emission Rate, lb/hrb
Dimethylaminoazobenzene .
Concentration, ppbvd "
Emission Rate, lb/hrb
N,N-Dimethylaniline
Concentration, ppbvd'
Emission Rate, lb/hrb
3 ,3 '-Dimethylbenzidine
Concentration, ppbvd'
Emission Rate, lb/hrb
O-0010-1

ND
ND

ND
ND

ND
ND

{4.15E-01}
{1.05E-03}

{5.99E-02}
{8.03E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
0-0010-2

ND
ND

ND
ND

ND
ND

{1.77E-01}
{4.33E-04}

{3.10E-02}
{4.02E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-3

ND
ND

{5.95E-02}
{8.21E-05}

ND
ND

{1.25E-01}
{2.86E-04}

{3.50E-02}
{4.22E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-4

ND
ND

{2.94E-02}
{4.13E-05}

ND
ND

{8.31E-02}
{1.93E-04}

{3.50E-02}
{4.30E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
Average

ND
ND

{2.22E-02}
{3.09E-05}

ND
ND

{2.00E-01}
{4.92E-04}

{4.02E-02}
{5.14E-05}

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
             CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Dimethylphthalate
Concentration, ppbvd'
Emission Rate, lb/hrb
4,6-Dinitro-2-methylphenol
Concentration, ppbvd "
Emission Rate, lb/hrb
2,4-Dinitrophenol
Concentration, ppbvd "
Emission Rate, lb/hrb
2,4-Dinitrotoluene
Concentration, ppbvd1
Emission Rate, lb/hrb
bis(2-Ethylhexyl)phthalate
Concentration, ppbvd'
Emission Rate, lb/hrb
Fluoranthene
Concentration, ppbvd'
Emission Rate, lb/hrb
Fluorene
Concentration, ppbvd'
Emission Rate, lb/hrb
Hexachlorobenzene
Concentration, ppbvd'
Emission Rate, lb/hrb
Hexachlorobutadiene
Concentration, ppbvd'
Emission Rate, lb/hrb
Hexachlorocyclopentadiene
Concentration, ppbvd"
Emission Rate, lb/hrb
Hexachloroethane
Concentration, ppbvd '
Emission Rate, lb/hrb
O-0010-1

{1.55E-01}
{2.74E-04}

ND
ND

ND
ND

ND
ND

3.41E-01
1.22E-03

{5.72E-02}
{1.06E-04}

{6.82E-02}
{1.03E-04}

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-2

{5.42E-02}
{9.26E-05}

ND
ND

ND
ND

ND
ND

{2.89E-01}
{9.94E-04}

3.77E-02
6.72E-05

2.04E-02
2.99E-05

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-3

{4.61E-02}
{7.35E-05}

ND
ND

ND
ND

ND
ND

2.18E-01
6.99E-04

{1.71E-02}
{2.84E-05}

{3.21E-02}
{4.38E-05}

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-4

{2.91E-02}
{4.73E-05}

ND
ND

ND
ND

ND
ND

9.26E-02
3.02E-04

{1.78E-02}
{3.01E-05}

{1.83E-02}
{2.55E-05}

ND
ND

ND
ND

ND
ND

ND
ND
Average

{7.10E-02}
{1.22E-04}

ND
ND

ND
ND

ND
ND

{2.35E-01}
{8.03E-04}

{3.25E-02}
{5.78E-05}

{3.48E-02}
{5.06E-05}

ND
ND

ND
ND

ND
ND

ND
ND

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
             CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
lun No.
lydroquinone
Concentration, ppbvd'
Emission Rate, lb/hrb
ndeno(l,2,3-cd)pyrene
Concentration, ppbvd "
Emission Rate, lb/hrb
sophorone
Concentration, ppbvd'
Emission Rate, lb/hrb
VIethylene bis-chloroaniline
Concentration, ppbvd'
Emission Rate, lb/hrb
4,4'-Methylenedianiline
Concentration, ppbvd "
Emission Rate, lb/hrb
2-Methylnaphthalene
Concentration, ppbvd '
Emission Rate, lb/hrb
2-Methylphenol
Concentration, ppbvd'
Emission Rate, lb/hrb
3/4-Methylphenol
Concentration, ppbvd'
Emission Rate, lb/hrb
Naphthalene
Concentration, ppbvd'
Emission Rate, lb/hrb
Nitrobenzene
Concentration, ppbvd '
Emission Rate, lb/hrb
4-Nitrobiphenyl
Concentration, ppbvd'
Emission Rate, lb/hrb
O-0010-1

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{2.17E+00}
{2.81E-03}

ND
ND

ND
ND

2.35E+00
2.74E-03

ND
ND

ND
ND
O-0010-2

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{8.75E-01}
{1.10E-03}

ND
ND

ND
ND

{1.22E+00}
{1.38E-03}

ND
ND

ND
ND
O-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{3.86E+00}
{4.51E-03}

8.03E-02
7.12E-05

ND
ND

2.89E+00
3.04E-03

ND
ND

ND
ND
O-0010-4

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.63E+00}
{1.93E-03}

2.56E-02
2.31E-05

3.62E-02
3.27E-05

1.42E+00
1.52E-03

ND
ND

ND
ND
Average

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{2.13E+00}
{2.59E-03}

2.65E-02
2.36E-05

9.05E-03
8.18E-06

{1.97E+00}
{2.17E-03}

ND
ND

ND
ND

-------
                 TABLE 2.13 (Continued)
SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
             CUPOLA WET SCRUBBER OUTLET
   GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
*un No.
4-Nitrophenol
Concentration, ppbvd '
Emission Rate, lb/hrb
n-Nitrosodimethylamine
Concentration, ppbvd *
Emission Rate, lb/hrb
n-Nitrosomorpholine
Concentration, ppbvd "
Emission Rate, lb/hrb
Jentachloronitrobenzene
Concentration, ppbvd *
Emission Rate, lb/hrb
'entachlorophenol
Concentration, ppbvd '
Emission Rate, lb/hrb
Perylene
Concentration, ppbvd '
Emission Rate, lb/hrb
Phenanthrene
Concentration, ppbvd "
Emission Rate, lb/hrb
Phenol
Concentration, ppbvd *
Emission Rate, lb/hrb
1 ,4-Phenylenediamine
Concentration, ppbvd "
Emission Rate, lb/hrb
Pyrene
Concentration, ppbvd "
Emission Rate, lb/hrb
o-Toluidine
Concentration, ppbvd *
Emission Rate, lb/hrb
O-0010-1

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{1.40E-01}
{2.28E-04}

8.42E-01
7.23E-04

ND
ND

7.04E-02
1.30E-04

ND
ND
O-0010-2

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{3.62E-02}
{5.69E-05}

{2.08E+00}
{1.72E-03}

ND
ND

4.57E-02
8.14E-05

ND
ND
0-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{3.99E-02}
{5.84E-05}

{4.73E-01}
{3.66E-04}

ND
ND

2.09E-02
3.46E-05

ND
ND
O-0010-4

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{2.60E-02}
{3.87E-05}

{8.17E-01}
{6.43E-04}

ND
ND

1.92E-02
3.24E-05

ND
ND
Average

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND

{6.05E-02}
{9.54E-05}

{1.05E+00}
{8.63E-04}

ND
ND

3.90E-02
6.95E-05

ND
ND

-------
                            TABLE 2.13 (Concluded)

     SVOHAPS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
                      CUPOLA WET SCRUBBER OUTLET
         GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
1 ,2,4-Trichlorobenzene
Concentration, ppbvd*
Emission Rate, Ib/hr b
2,4,5-Trichlorophenol
Concentration, ppbvd"
Emission Rate, Ib/hr b
2,4,6-Trichlorophenol
Concentration, ppbvd8
Emission Rate, Ib/hr b
a,a,a-Trichlorotoluene
Concentration, ppbvd*
Emission Rate, Ib/hr b
Trifluralin
Concentration, ppbvd"
Emission Rate. Ib/hr b
O-0010-1

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-2

ND
ND

ND
ND

{1.10E-02}
{1.91E-05}

ND
ND

ND
ND
O-0010-3

ND
ND

ND
ND

ND
ND

ND
ND

ND
ND
O-0010-4

{2.81E-02}
{4.26E-05}

ND
ND

ND
ND

ND
ND

ND
ND
Average

{7.03E-03}
{1.07E-05}

ND
ND

{2.75E-03}
{4.78E-06}

ND
ND

ND
ND
"   Parts per billion by volume, dry basis.
b   Pounds per hour.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{}  Estimate - Analyte results are below the quantitation limit and above the detection limit. Values are counted in the averages.

-------
                  TABLE 2.14
        SVOHAPS DETECTION LIMITS, PPBVD
          CUPOLA WET SCRUBBER OUTLET
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
Date
Clock Time, 24-hr clock
Acenaphthene
Acenaphthylene
Acetophenone
i-Aminobiphenyl
Aniline
o-Anisidine
Anthracene
ienzidine
3enzo(a)anthracene
3enzo(b)fluoranthene
3enzo(k)fluoranthene
3enzo(ghi)perylene
Benzo(a)pyrene
3enzo(e)pyrene
Benzyl Chloride
Biphenyl
2-Chloroacetophenone
bis-(2-Chloroethyl)ether
2-Chloronaphthalene
Chrysene
Cumene
Dibenz(a,h)anthracene
Dibenzofuran
1 ,2-Dibromo-3-chloropropane
Di-n-butylphthalate
1 ,4-Dichlorobenzene
3,3'-Dichlorobenzidine
^.N-Diethylaniline
3 ,3 '-Dimethoxybenzidine
Dimethylaminoazobenzene
!>J,N-Dimethylaniline
3,3'-Dimethylbenzidine
Dimethylphthalate
4,6-Dinitro-2-methylphenol
O-0010-1
9/23/97
1415-1847
D
D
D
2.92E-02
6.47E-02
8.91E-02
D
2.16E-02
1.27E-02
9.56E-03
9.56E-03
8.73E-03
l.OOE-02
8.60E-03
3.72E-02
D
2.73E-02
9.02E-02
3.19E-02
D
3.81E-02
1.04E-02
2.37E-02
7.24E-02
D
D
2.86E-02
4.12E-02
4.05E-02
3.80E-02
4.98E-02
2.33E-02
D
1.70E-01
O-0010-2
9/24/97
0851-1400
1.59E-02
D
D
1.22E-02
2.99E-02
4.16E-02
8.74E-03
7.85E-03
4.63E-03
3.31E-03
3.53E-03
3.22E-03
3.53E-03
3.09E-03
1.71E-02
D
1.26E-02
4.16E-02
1.47E-02
4.63E-03
D
3.80E-03
1.09E-02
3.37E-02
D
D
1.06E-02
1.90E-02
1.46E-02
1.38E-02
2.30E-02
8.39E-03
D
7.84E-02
0-0010-3
9/25/97
0844-1321
D
D
D
9.97E-03
D
3.20E-02
D
7.20E-03
4.22E-03
3.03E-03
3.18E-03
2.76E-03
3.18E-03
2.87E-03
D
D
9.88E-03
3.20E-02
1.09E-02
4.40E-03
D
3.32E-03
D
2.58E-02
D
D
9.52E-03
1.48E-02
1.33E-02
1.27E-02
1.79E-02
7.76E-03
D
5.90E-02
O-0010-4
9/25/97
1443-1919
D
D
D
8.18E-03
1.95E-02
2.76E-02
D
5.58E-03
3.29E-03
2.51E-03
2.66E-03
2.29E-03
2.66E-03
2.35E-03
1.12E-02
D
8.44E-03
2.74E-02
9.73E-03
3.29E-03
D
2.84E-03
D
2.21E-02
D
D
7.34E-03
1.27E-02
1.04E-02
9.83E-03
1.53E-02
5.96E-03
D
5.19E-02
Average


1.59E-02
D
D
1.49E-02
3.81E-02
4.76E-02
8.74E-03
1.06E-02
6.21E-03
4.60E-03
4.73E-03
4.25E-03
4.85E-03
4.23E-03
2.18E-02
D
1.46E-02
4.78E-02
1.68E-02
4.11E-03
3.81E-02
5.09E-03
1.73E-02
3.85E-02
D
D
1.40E-02
2.19E-02
1.97E-02
1.86E-02
2.65E-02
1.14E-02
D
8.99E-02

-------
                        TABLE 2.14 (Concluded)
                 SVOHAPS DETECTION LIMITS, PPBVD
                   CUPOLA WET SCRUBBER OUTLET
        GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
Run No.
2,4-Dinitrophenol
2,4-Dinitrotoluene
bis(2-Ethylhexyl)phthalate
rluoranthene
Fluorene
lexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
lexachloroethane
tydroquinone
ndeno( 1 ,2,3 -cd)pyrene
Isophorone
Methylene bis-chloroaniline
4,4'-Methylenedianiline
2-Methylnaphthalene
2-Methylphenol
3/4-Methylphenol
Naphthalene
Nitrobenzene
4-Nitrobiphenyl
4-Nitrophenol
n-Nitrosodimethylamine
n-Nitrosomorpholine
Pentachloronitrobenzene
Pentachlorophenol
Perylene
Phenanthrene
Phenol
1 ,4-Phenylenediamine
Pyrene
o-Toluidine
1 ,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
a,a,a-Trichlorotoluene
Trifluralin
O-0010-1
2.46E-01
9.33E-02
D
D
D
4.19E-02
6.24E-02
6.68E-02
6.98E-02
8.32E-02
7.48E-03
3.84E-02
6.32E-02
4.87E-02
D
9.59E-02
8.48E-02
D
5.09E-02
6.42E-02
1.49E-01
2.43E-01
1.50E-01
1.56E-01
7.92E-02
9.56E-03
D
D
8.03E-02
D
5.85E-02
5.52E-02
7.39E-02
7.88E-02
3.95E-02
7.52E-02
O-0010-2
1.13E-01
4.31E-02
D
D
D
1.72E-02
2.90E-02
3.06E-02
3.22E-02
3.89E-02
2.68E-03
1.77E-02
2.29E-02
1.77E-02
D
4.43E-02
3.91E-02
D
2.35E-02
3.39E-02
6.84E-02
1.13E-01
6.90E-02
6.43E-02
3.25E-02
3.53E-03
D
D
3.76E-02
D
2.70E-02
2.55E-02
3.41E-02
D
1.82E-02
3.45E-02
O-0010-3
8.51E-02
3.24E-02
D
D
D
1.41E-02
2.23E-02
2.31E-02
2.48E-02
2.99E-02
2.35E-03
1.37E-02
2.09E-02
1.62E-02
D
D
4.24E-02
D
1.83E-02
2.79E-02
5.14E-02
8.62E-02
5.33E-02
5.27E-02
2.67E-02
3.03E-03
D
D
2.90E-02
D
2.10E-02
1.97E-02
2.56E-02
2.73E-02
1.42E-02
2.61E-02
O-0010-4
7.48E-02
2.84E-02
D
D
D
1.17E-02
1.93E-02
2.03E-02
2.12E-02
2.59E-02
2.04E-03
1.17E-02
1.61E-02
1.26E-02
D
D
3.62E-02
D
1.57E-02
2.31E-02
4.52E-02
7.42E-02
4.56E-02
4.37E-02
2.21E-02
2.51E-03
D
D
2.49E-02
D
1.81E-02
D
2.24E-02
2.40E-02
1.21E-02
2.29E-02
Average
1.30E-01
4.93E-02
D
D
D
2.12E-02
3.33E-02
3.52E-02
3.70E-02
4.45E-02
3.64E-03
2.04E-02
3.08E-02
2.38E-02
D
7.01E-02
5.06E-02
D
2.71E-02
3.73E-02
7.85E-02
1.29E-01
7.94E-02
7.92E-02
4.01E-02
4.66E-03
D
D
4.29E-02
D
3.12E-02
3.34E-02
3.90E-02
4.34E-02
2.10E-02
3.97E-02
"D" indicates that compound was detected.

-------
2.5   VOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS (VOHAPS)

      The volatile organic hazardous air pollutants (VOHAPs) were measured using direct
interface gas chromatography/mass spectrometry at the inlet and outlet sampling locations of the
wet scrubber.  Compounds of interest were those that had boiling points below 100° C.
Measurements taken at both locations did not show any target analytes to be in concentrations
above their respective analytical instrument detection limits.  Table 2.15 lists the target analytes
and estimated detection limits.

-------
        TABLE 2.15
GC/MS TARGET ANALYTES AND
ESTIMATED DETECTION LIMITS
Analyte
Chloromethane
Chloroethane
Methylene Chloride
1 , 1 -dichloroethane
c- 1 2-dichloroethene
1,1,1 -trichloroethane
1 ,2-dichloropropane
1 , 1 ,2-trichloroethane
Dibromochloromethane
Ethylbenzene
p-xylene
1 , 1 ,2,2-tetrachloroethane
Bromomethane
1 , 1 -dichloroethene
t- 1 ,2-dichloroethane
Methyl Ethyl Ketone
1 ,2-dichloroethane
Carbon tetrachloride
Trichloroethene
c- 1 ,2-dichloropropene
t- 1 ,2-chlhloropropene
2-hexanone
Chlorobenzene
Estimated Detection Limit
Parts per Billion (PPB)
50
50
10
25
25
25
25
25
25
10
30
10
50
25
25
500
50
10
25
25
25
500
10

-------
    TABLE 2.15 (Concluded)
GC/MS TARGET ANALYTES AND
ESTIMATED DETECTION LIMITS
Analyte
m-xylene
p-xylene
Vinyl chloride
Carbon disulfide
Vinyl acetate
Chloroform
Benzene
Bromodichloromethane
Methyl iso-Butyl Ketone
Toluene
Tetrachloroethylene
Bromoform
Styrene
Estimated Detection Limit
Parts per Billion (PPB)
30
30
250
10
250
10
10'
10
1000
10
10
50
30

-------
                            3.0  PROCESS DESCRIPTION
3.1    INTRODUCTION

       The GM Powertrain Group, part of the General Motors Corporation, operates a foundry in
Saginaw, Michigan named Saginaw Metal Casting Operations (SMCO), which casts grey iron
and aluminum. This foundry was constructed by GM in 1918 and is currently operating three
cupolas and two green sand lines for casting iron along with a melting furnace and one casting
line for aluminum to produce engine blocks for use in GM automobiles. The plant has about
2,000 employees. This section of the test report provides a description of the cupola operation
for iron melting and the casting operation, including pouring, cooling, and shakeout.
3.2    PROCESS DESCRIPTION

3.2.1  Iron Melting in Cupolas

       There are three cupolas in operation ("B", "C", and "D"). Cupolas B and C are very
similar and are configured with an afterburner followed by a venturi scrubber (i.e., they burn
"dirty" gas).  Cupola D burns the gas after removal of PM by the scrubber. Plant personnel
indicated that Cupolas B and C were more representative of the industry and pointed out that
cupolas configured like D are no longer constructed. Consequently, Cupola B was chosen for
testing, primarily because it had more modern and complete controls and instrumentation.

       Cupola B has a diameter of 114 inches and melts at a rate of about 55 tons per hour (tph)
with a blast rate of 21,000 to 23,000 cubic feet per minute (cfm), which makes it among the
largest cupolas in use in the United States. The blast is enriched with O2 at a rate of about 4%.
Figure 3.1 is a simplified schematic of the cupola gas handling system and emission control
equipment.

       The cupola is charged with metal scrap, briquettes made from metal shavings, coke, and
limestone at  a point that is above the gas take-off. The composition of a typical charge is given
in Table 3.1  and includes six tons of iron.  Very few emissions occur from charging because of
the below-charge gas take-off and the maintenance of negative pressure  on the cupola.  The off
gas from the cupola is removed at about 400 to 500° F and contains 12 to 14% carbon monoxide
(CO).  This gas enters a large combustion chamber where the CO is burned at about 1500 to
1600°F.  Some heavy and larger size particles settle out in the combustion chamber and are
removed at that point. The hot exhaust gases from the combustion chamber pass through two
recuperators that

-------
                                                                      Quencher
tb
                                                Off gas
                               Recuperator

                            Wet cap
                                                               Recuperator
                                                                   Blast air
                                                                      Solids
                                                                      removed
                                                                                 Cooled gas
                                                                                   Scrubber water
                          CUPOLA
  Heated
  blast air
         X  Combustion  CuP°fa
       /    chamber     blower
Solids removed
                                      Venturi
                                      scrubber
                                                                Exhaust stack
                                                                                            Cleaned
                                                                                            gas
                                                                                                         o
                                                                                 Scrubber water
                                                                                 to wastewater treatment
                                                                                                       Exhaust fan

-------
                                      TABLE 3.1
                     TYPICAL CUPOLA CHARGE MATERIALS
Material
Remelt from foundry15
Steel scrapb
Gray iron bricksb> c
Silicon bricks
Blend bricks (Si, Mn, Cr)
Silicon carbide
Coke
Limestone
Typical range (lbs/charge)a
4,000 to 6,000
3,000 to 4,000
3,000
70 to 105
260 to 300
300
1,400 to 1,500
500
a Typical range observed during the test days.
b Remelt, steel scrap, and gray iron bricks are the sources of iron and total 12,000 Ibs (6 tons) per
  charge.
c Gray iron bricks are a pressed material made from borings, shavings, etc.

are used to pre-heat the cupola's blast air to about 1100°F. There is also a cooler available for
additional temperature control as necessary.

       From the recuperators, the gas passes through a quencher, which cools the gas and also
removes some of the entrained particulate matter.  The gas then enters a venturi scrubber
(manufactured by Air Pollution Industries) that is operated at a pressure drop of about 40 inches
of water and a water flow rate of about 625 gallons per minute. A vacuum is maintained on the
system and the gas is moved by a 1200 hp exhaust fan following the scrubber. The cleaned gas is
exhausted through  a stack. The wastewater from the scrubber  is sent to a wastewater treatment
recycle system where polymers are added to assist in settling fine particles, and 99% of the water
is recycled to the scrubber (with a  1% blowdown to the city's wastewater treatment facility).
Particulate matter emissions from the scrubber are limited to 0.15 Ib per 1,000 Ib of gas by the
State.

       The plant has instrumentation available to  monitor several parameters associated with the
emission control system, including the pressure drop across the scrubber, the water flow rate,
electric current to the fan, and gas  temperature.  Temperature and blast rate for the cupola are
monitored routinely. In addition, an accurate measure of the melting rate (e.g., for use in

-------
normalizing mass emission rates by production rate) can be obtained from the charging data
sheets.

       The plant buys scrap from other GM plants and controls the quality because scrap quality
directly affects the quality of the castings. However, plant personnel pointed out that it would be
difficult to have a parameter to measure scrap quality that could be used to make valid
comparisons among different foundries.

3.2.2  Pouring. Cooling and Shakeout

       The two iron pouring lines are labeled Lines 3 and 4.  Plant personnel indicated that Line
4 was the best candidate for testing because it is newer and the layout is more amenable to
sampling. A simplified schematic of the capture and control equipment for Line 4 is given in
Figure 3.2. The line has a capacity of 270 molds per hour with two engine blocks per mold.
Each horizontal mold contains 3,300 Ibs of green sand (lake sand, sea coal, and bentonite). The
typical properties that are measured and the range during the test days are given in Table 3.2.

       The cores used in the molds include both hot box and cold box systems with phenol-
formaldehyde. For the 4-cylinder engine, 15.7 Ibs of hot box cores  and 74.5 Ibs of cold box cores
are used for a total core weight of 90.2 Ibs per block or 180.4 Ibs per mold. For the 6-cylinder
engine, 17.9 Ibs of hot box cores and 95.2 Ibs of cold box cores are used for a total core weight of
113 Ibs per block or 226 Ibs per mold.  The chemicals used to make the cores are summarized in
Table 3.3. The materials used for core dipping are primarily minerals, such as crystalline silica
(quartz), mica, aluminum silicate, along with graphite, clay and water.

       The pouring station for Line 4 is automated and uses six ladles in a circular configuration.
A large, circular side draft hood evacuates the entire pouring area at a rate of about 50,000 cfrn.
During the testing, no significant visible emissions were observed escaping capture from the
pouring operation. The captured  emissions are ducted overhead through the roof to the
atmosphere. During the test days, both 4- and 6-cylinder engine blocks were poured on Line 4.
The pouring weight of iron for the 4-cylinder block is 202.8 Ibs to produce a casting of 116.2 Ibs.
For the 6-cylinder block, the pouring weight is 250.4 Ibs and the casting weight is 149.2 Ibs.

       The cooling line is enclosed and has a series of hoods throughout the line that evacuate
the enclosures at a rate of about 50,000 cfrn and send the emissions to a bank of pre-coated
cartridge filters to remove particulate matter.  The cooling line is evacuated through three main
ducts that send the cooling emissions to three separate sets of cartridge filters.  The residence
time of the cooling line is about 25 minutes.

       The shakeout operation is totally enclosed in a small, evacuated building (roughly 40 by
60 feet). The room is evacuated at about 150,000 cfrn, and the captured emissions are sent to
three spray scrubbers that have 2  to 3 stages for cleaning.

-------
                                       To atmosphere
                                       (50,000 cfm)
                              To atmosphere
                             (150,000 cfm total)
                                                           A   A  A
U)
Circular side
draft hood	
                      From mold
                      and core
                      preparation
                                                 Pre-c
                                                 cartridge
                                                 filters--"
To atmosphere
(150,000 cfm total)
                                                    A     A     A
(

1
••V--






i
*
i
7T\






;
S
i
•T-




Spray
scrubbers
T   T
                                                       Shakeout
                                                    40 x 60 ft enclosure
                                                                       To finishing

-------
                              TABLE 3.2
            TYPICAL RESULTS FROM GREEN SAND ANALYSIS"
Property
Moisture (%)
Clay (%)
Comparability (%)
Green strength (psi)
Permeability (AFS units)
Loss on ignition (%)
Range
2.8 to 3.3
6.8 to 7.4
3.6 to 4.8
164 to 221
114 to 130
3.8 to 5.0
From analyses during the first shift of the test days.

-------
                               TABLE 3.3
        CHEMICALS USED IN CORE MAKING AND MOLD SPRAYING"
Product
Acme
45MR1BS®
Acme 745LF®
Acme-flow 20 12®
Acme-flow
2052A®
Tribonol®
Function
Hot box catalyst
Phenolic resin for hot
box cores
Phenolic resin for cold
box cores
Isocyanate resin for cold
box Part 2
Mold spray
Chemical
Urea
Ammonium hydroxide
Ammonium nitrate
Water
Ammonium chloride
Siloxanes and silicones
Formaldehyde
Phenol
Formaldehyde
Phenol
Ethyl 3-ethoxypropionate
Heavy aromatic solvent naphtha
Diphenylmethane 4,4'-
Diisocyanate
Kerosene
Polymeric Diphenylmethane
Diisocyanate
Isocyanic acid,
methylenediphenylene ester
Heavy aromatic solvent naphtha
Zircon
Diethylene glycol polymer with 1-
chloro-2,3-epoxypropane
Percent
30 to 35
0.1 to 1
10 to 15
45 to 50
0.1 to 1
Ito5
Ito5
5 to 10
0.1 to 1
Ito5
5 to 10
10 to 30
10 to 30
5 to 10
30 to 50
Ito5
10 to 30
90
10
From the manufacturer's material safety data sheets (MSDS).

-------
3.3    PROCESS AND CONTROL DEVICE MONITORING RESULTS

3.3.1  Cupola B

       During each test run, several parameters associated with the operation of the cupola and
the Venturi scrubber were monitored and recorded.  For the cupola, these parameters included the
blast air flow rate, the relief stack flow rate, the hot blast temperature, oxygen feed pressure, and
the combustion chamber temperature. In addition, information was obtained on each time the
cupola was charged and the charge composition. Each time period was also recorded that the
blast was stopped (and the emission testing was also stopped).

       The plant had instrumentation installed to monitor several parameters associated with the
Venturi scrubber, including the water flow rate to the scrubber, flow rate of makeup water, inlet
temperature, inlet pressure, pressure drop, and the pressure (vacuum) at the induced draft fan.
These parameters, with the exceptions noted below, were monitored and recorded during the test.
Before the sampling runs were begun, the process observers worked with the plant personnel to
determine if the instruments indicating venturi pressure drop and water flow rate to the scrubber
were showing correct readings. Calibration of the pressure drop instrumentation, completed
early on September 24, consisted of a direct manometer reading at the venturi followed by
adjustment of the pressure drop reading in the control room. Calibration of the water flow rate
reading could not be confirmed during the sampling campaign. After the testing was completed,
plant personnel confirmed that the instrument had been calibrated and that the water flow rate
was 625 gallons per minute.

       Table 3.4 summarizes the major monitoring results for the cupola during each test run,
and Table 3.5 provides the cupola charging data for about 12 hours  during each test day.  The
blast air temperature and flow rate are plotted for the four test runs in Figures 3.3 and 3.4. The
blast air rate showed very  little variability during the test; however, there were significant
differences in the temperature of the hot air blast, which averaged 464 to 488°F during Runs 1
and 2 and 364 to 366°F during Runs 3 and 4.

       The pressure drop  across the Venturi scrubber increased during each run. At the request
of EPA personnel, adjustments were made after the first test run to increase the scrubber pressure
and to maintain a range closer to the original design specifications.  The pressure drop averaged
33, 35, 38, and 42 inches of water for Runs 1, 2, 3, and 4 respectively.

-------
                                     TABLE 3.4
                SUMMARY OF CUPOLA MONITORING RESULTS
Parameter
Blast flow rate (cfm)
Hot blast temperature (°F)
Oxygen (psig)
Combustion chamber
temperature (°F)
Melting rate (tons/hr)°
Time blast stopped (min)
Scrubber pressure drop (in. water)
Run
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
Average
21,400
22,100
21,900
21,800
488
464
366
364
30
49
50
59
Range
21,000-22,200
21,800-22,500
21,700-22,800
21,000-22,400
443 - 539
448 - 488
336 - 385
327 - 409
30
43-61
40-65
54-65
not available
1,557
1,518
1,608
38.8
41.7
45.4
43.5
156
6
29
15
33.4
35
38
42
1,401 - 1,669
1,276-1,633
1,495 - 1,670
-
-
-
-
-
~
-
-
33-35
32-37
36-40
40-42
Adjusted for the downtime when the blast was stopped (i.e., the downtime was subtracted from the operating time when
determining the melting rate).

-------
                               TABLE 3.5
         SUMMARY OF CUPOLA CHARGING DURING THE TEST DAYS
9/23/97*
Time period
--
~
~
—
—
—
--
~
~
13:58-14:49
15:51-16:19
18:20-19:12
Average rate
(tons/hr)
Tons charged
~
~
~
—
—
~
~
~
—
48
30
24
38.8
9/24/97
Time period
6:00-7:05
7:13-8:02
8:25-9:14
9:19-10:09
10:14-11:05
11:14-12:05
12:10-13:02
13:20-14:03
14:08-15:12
15:17-16:08
16:21-17:10
17:17-18:18
Average rate
(tons/hr)
Tons charged
54
42
30
42
36
42
42
42
54
42
36
36
40.5
9/25/97
Time period
7:11-8:05
8:11-9:01
9:10-10:07
10:12-11:06
11:10-12:02
12:12-13:03
13:12-14:07
14:18-15:10
15:27-16:02
16:11-17:03
17:12-17:59
18:07-19:10
Average rate
(tons/hr)
Tons charged
42
36
42
42
36
42
42
48
30
42
42
42
40.6
* Run 1 on this day was a short test with 110 minutes of sampling between 14:10 and 18:41.

-------
300
  0:00
                                                           RUN1
                                                           ,RUN2
                                                           RUN 3
                                                           RUN 4
2:00      3:00
RUN TIME

-------
         23.0
UJ
i


to
         20.0
            0:00
1:00
2:00          3:00



        RUN TIME
4:00
5:00
6:00

-------
3.3.2  Mold Line 4

       During the testing of Line 4, a record was kept of the rate at which the line moved (e.g.,
molds per hour) and pouring was observed to identify when broken molds were not poured and
the temperature of the molten iron when poured. Several observations were made of the time to
"light off after pouring, when the vapors escaping from the mold self-ignited. The first hole
ignited on average about 6 to 8 seconds after pouring, and all holes were lit 11 to 18 seconds
after pouring. During the testing of the scrubbers used on the shakeout operation, the pressure
drop across the scrubbers was recorded and ranged from 13.9 to 16.5 inches of water.

       Table 3.6 provides a summary of the number and types of molds that were processed
during each test day from plant records, and Table 3.7 provides a summary  of the quantity of iron
poured and the downtime during each hour of the testing days.  Table 3.8 contains the mold
counts made by the process observers when testing was being performed. Table 3.9 provides an
estimate of the tons of iron poured per hour and the number of molds poured per hour during the
testing periods on Line 4.

       During the testing days, the pouring temperature of the iron was maintained within a
narrow range of 2,743 °F to 2,818 °F. A typical analysis of the iron (from  9/25/97) showed
3.11% carbon, 0.13% sulfur, and 2.28% silicon.

-------
                                 TABLE 3.6
            SUMMARY OF NUMBER OF MOLDS POURED ON LINE 4
Hour
(first
shift)
1
2
3
4
5
6
7
8
9b

Number of molds poured"
9/22/97
4-cyl.
223
64
~
~
56
237
37
~
—
~
6-cyl.
--
126
220
185
36
--
46
217
106
—
9/23/97
4-cyl.
224
16
--
—
~
225
205
70
--
—
6-cyl.
—
165
214
208
217
~
—
76
108
--
9/24/97
4-cyl.
152
194
59
0
171
114
~
—
83
104
6-cyl.
—
~
—
~
~
98
195
Til
109
~
9/25/97
4-cyl.
180
235
155
—
~
48
202
176
—
~
6-cyl.
~
~
48
208
245
126
~
18
108
—
a Does not include broken molds that were not poured.
b The line usually shut down around 3 pm.

-------
                                TABLE 3.7
        SUMMARY OF METAL POURED AND DOWNTIME FOR LINE 4
Hour
(first
shift)
1
2
3
4
5
6
7
8
9

Tons of metal poured8
9/22/97
45.2
44.5
55.1
46.3
20.4
48.1
19.0
54.3
26.5
~
9/23/97
45.4
44.6
53.6
52.1
54.3
45.6
41.6
33.2
27.0
—
9/24/97
30.8
39.3
12.0
0.0
34.7
47.7
48.8
56.8
44.1
21.1
9/25/97
36.5
47.7
43.5
52.1
61.3
41.3
41.0
40.2
27.0
—
Downtime (minutes)
9/22/97
8
17
11
15
40
7
42
12
0
~
9/23/97
10
20
12
14
12
10
14
26
0
—
9/24/97
26
17
47
60
22
13
17
10
17
1
9/25/97
20
8
15
14
6
21
15
17
0
—
Based on 202.8 Ibs per 4-cylinder engine block (405.6 Ibs per mold) and 250.4 Ibs per 6-
cyUnder engine block (500.8 Ibs per mold).

-------
                TABLE 3.8
LINE 4 MOLD COUNTS DURING TESTING PERIODS
Date: 09/22/97
Time
1:41 pm
1 :42 pm
1 :45 pm
1:50 pm
2:00 pm
2:15 pm
2:20 pm
2:25 pm
2:30 pm
2:40 pm
2:45 pm
2:50 pm
2:53 pm
2:55 pm
3:00pm
Number of
molds"
0
5
14
21
40
57
21
21
22
28
22
21
17
3
16
Molds/hrb
0
300
280
252
240
228
252
252
264
168
264
252
340
90
192
Cumulative
molds/hr0
0
300
285
267
253
242
243
244
246
233
235
237
241
237
234
Comments
6-cylinder engine blocks; 8 broken
molds were not poured between 1 :30
and 3:00
Date: 9/23/97
Time
8:39 am
8:40 am
8:43 am
8:57 am
9:23 am
9:41 am
10:00 am
10:18am
10:30 am
10:42 am
10:54 am
11:02 am
ll:10am
Number of
molds8
0
5
14
54
93
69
64
73
32
49
44
35
34
Molds/hr"
0
300
280
231
215
230
202
243
160
245
220
263
255
Cumulative
molds/hr0
0
300
285
243
226
227
221
225
218
221
221
223
225
Comments
6-cylinder engine blocks; 26
6-cylinder molds not poured between
8:00 and 12:00

-------
                                  TABLE 3.8
         LINE 4 MOLD COUNTS DURING TESTING PERIODS (Concluded)
Date: 9/23/97
Time
11:42 am
12:01 pm
Number of
molds8
109
78
Molds/far"
204
246
Cumulative
molds/hr0
221
224
Comments
Switched to 4-cylinder blocks at
1 1 :45; 3 4-cylinder molds not poured
Date: 9/24/97
Time
11:03 am
11:06 am
11:08 am
ll:10am
11:35 am
11:51 am
12:04pm
Number of
molds8
0
12
9
9
94
68
44
Molds/hr"
0
240
270
270
226
255
203
Cumulative
molds/hrc
0
240
252
257
233
240
232
Comments
4-cylinder engine blocks; 5 molds
not poured
Date: 9/25/97
Time
8:57 am
9:17 am
9:30 am
9:48 am
9:58 am
10:15 am
10:26 am
10:41 am
10:57 am
11:25 am
11:32 am
Number of
molds8
0
68
41
72
42
52
38
59
64
118
29
Molds/hr"
0
204
189
240
252
184
207
236
240
253
249
Cumulative
molds/hr0
0
204
198
213
219
212
211
215
218
225
226
Comments
4-cylinder engine blocks; 3 molds
not poured
Switched to 6-cylinder at 9:30;
14 molds not poured
a Number of molds counted for the incremental time period.
b Rate based on the incremental time period.
c Cumulative rate based on number of molds from the start time; this is the most accurate
measure of the rate over the time period (i.e., the last bolded number in this column).

-------
                                TABLE 3.9
          MOLD LINE 4 PRODUCTION DURING TESTING PERIODS
Date
9/22/97
9/23/97
9/24/97
9/25/97
Time Period
1:41- 3:00 pm
8:39 - 12:01 pm
1 1:03- 12:04 pm
8:57 -11:32 am
No. of molds poured
4-cylinder
—
75
231
106
6-cylinder
300
652
—
460
Molds/hr
poured
227
216
226
219
Tons/hr
poured8
56.9
53.0
45.8
53.0
Based on 405.6 Ibs for 4-cylinder molds and 500.8 Ibs for 6-cylinder molds.

-------
                            4.0 SAMPLING LOCATIONS
       Isokinetic source sampling was conducted at the inlet and outlet of the cupola wet
scrubber at the GM-Saginaw SMCO facility.  Descriptions of the sampling locations are
presented below, as well as schematic diagrams.
4.1    CUPOLA WET SCRUBBER INLET

       The cupola wet scrubber inlet measurement site was located in a 661/4-inch inside
diameter (ID) round, vertical duct, 93% inches (1.4 duct diameters (d.d.)) downstream of the
nearest flow disturbance (90° bend) and 80 inches (1.2 d.d.) upstream of the nearest flow
disturbance. According to EPA Method 1 criteria, this site required 24 sample traverse points, 12
along each of two perpendicular diameters. Figure 4.1 shows a simplified schematic of the wet
scrubber inlet measurement site.  Figure 4.2 shows the sample traverse point locations. A check
for the presence of non-parallel flow was conducted as specified in Section 2.4 of EPA
Method 1. The check confirmed the average yaw angle of 7.1  degrees, which is less than the
Method 1 requirement of 20 degrees based on the average. A quench (water) chamber was
located just upstream of the inlet sampling ports. It was attempted to locate sampling ports
before the quench chamber, but due to support beams and other ductwork, a suitable sampling
site was not accessible.
4.2    CUPOLA WET SCRUBBER OUTLET

       The wet scrubber outlet sampling location was located in a 75-inch ID round, vertical
stack.  Sampling ports were located along two separate planes to enable adequate access for the
multiple metals, semi-volatile organics and dioxin/furan sampling trains.  The two sampling
ports utilized for the semi-volatile organics and dioxin/furan sampling trains were located close
to the rooftop.  Sampling ports were located 639 inches (8.5 d.d.) downstream of a bend in the
duct and 273 inches (3.6 d.d.) upstream of the exhaust to atmosphere.  The second set of
sampling ports was used to conduct the filterable particulate/multiple metals train. These ports
were located 672 inches (9.0 d.d.) downstream of a bend in the duct and 240 inches (3.2 d.d.)
upstream of the exhaust to atmosphere.  Figure 4.3 is a schematic of the scrubber outlet sampling
locations. Figure 4.4 shows the sample traverse point locations. A check for the presence of
non-parallel

-------
                                   Section A-A
93 1/4"
  80"
                          k
                 Quench
Roof
                   Venturi
                    Spray
                   Nozzles
                (Wet Scrubber
              Figure 4.1 Cupola Wet Scrubber Inlet Sampling Location

-------
               Circular Stack Method 1 Calculation Results
                           Date: 07/20/99     Time: 15:18:28
      Facility:  General Motors Corp.
    Source ID:  Scrub, inlet
Source Name:  Cupola Wet Scrubber Inlet
        Date:  09/21/97
Calculated By:  F. Meadows
                        Traverse Point Type:  Sample - M5
           Inside of far wall to outside of nipple:    70 3/8      (inches)
                              Nipple Length:     41/8      (inches)
           Distance from Upstream Disturbance:    80 even    (inches)
        Distance from Downstream Disturbance:    93 1/4      (inches)
                           Number of ports:  2 ports at 90 degrees
> v s^S-
CaliMIatett Vafciesf
4$
N v •• % o ••s^sj^
xw
^,;i
                            Inside Diameter:   66.2500
                    Upstream Duct Diameters:   1.20
                 Downstream Duct Diameters:   1.40
                    Mininum Traverse Points:  24
(inches)

1
2
3
4
5
6
7
8
9
10
11
12
!*«*« ,
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0.823
0.882
0.933
0.979
(tocft
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
66 1/4
338r
1 3/8
4 7/16
713/16
11 3/4
16 9/16
23 9/16
4211/16
4911/16
54 1/2
58 7/16
61 13/16
64 7/8
**,€tH^Jt3l %w"v.
jtltt ISnJS jt\ ^v
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
4 1/8
* ^rii^^K^jS
5 1/2
8 9/16
11 15/16
15 7/8
2011/16
2711/16
46 13/16
5313/16
58 5/8
62 9/16
6515/16
69 even
              Figure 4.2  Cupola Wet Scrubber Inlet Traverse Point Locations


-------
             33"
Roof
       n
       B
                                       ••MMH      ^^^_
                                        4        A
                                          273"
                                                                    Section B - B
                                                   240"
                                                 t
                                                         A and B = MM5 and M-23 Sampling Ports
                                                         C and D = M-29 Sampling Ports
                                           639"
                                                   672"
               Figure 4.3 Cupola Wet Scrubber Outlet Sampling Location

-------
                Circular Stack Method 1 Calculation Results
                            Date: 07/20/99     Time: 15:21:16
      Facility:  General Motors Corp.
    Source ID:  Serb. Outlet
Source Name:  Wet Scrubber Outlet
         Date:  09/21/97
Calculated By:  F. Meadows
                         Traverse Point Type:  Sample - M5
            Inside of far wall to outside of nipple:     79 1/4     (inches)
                              Nipple Length:      41/4     (inches)
           Distance from Upstream Disturbance:    672 even    (inches)
         Distance from Downstream Disturbance:    240 even    (inches)
                            Number of ports:  2 ports at 90 degrees
                             Inside Diameter:   75.0000
                     Upstream Duct Diameters:   8.96
                  Downstream Duct Diameters:   3.20
                     Mininum Traverse Points:   12
                                       (inches)
                0.021
             75 even
              1 9/16
              4 1/4
                   513/16
                0.067
             75 even
              5 even
              4  1/4
                   9  1/4
                0.118
             75 even
              8  7/8
              4 1/4
                   13  1/8
                0.177
             75 even
              13 1/4
              4 1/4
                   17 1/2
                0.250
             75 even
              18 3/4
              4  1/4
                  23 even
                0.356
             75 even
             2611/16
              4  1/4
                  3015/16
                0.644
             75 even
             48 5/16
              4  1/4
                  52 9/16
                0.750
             75 even
              56 1/4
              4  1/4
                   60 1/2
                0.823
             75 even
              61  3/4
              4  1/4
                  66 even
    10
0.882
75 even
66  1/8
4 1/4
 70 3/8
    11
0.933
75 even
70 even
4 1/4
 74 1/4
    12
0.979
75 even
73 7/16
4 1/4
7711/16
               Figure 4.4 Cupola Wet Scrubber Outlet Traverse Point Locations


-------
flow was conducted as specified in Section 2.4 of EPA Method 1. The check indicated the
average yaw angle to be 7.7 degrees, which is less than the EPA Method 1 requirement of 20
degrees, based on the average.

-------
                5.0 SAMPLING AND ANALYTICAL PROCEDURES
      Table 5.1 summarizes the sources, test parameters, test methods, number of tests, and net
run times.  Simultaneous isokinetic sampling was conducted at the cupola wet scrubber inlet and
outlet for PM/metals. Sampling was also performed for VOHAPs at both the inlet and outlet
locations.  Simultaneous with the PM/metals and VOHAPs testing, additional isokinetic
sampling was conducted at the cupola wet scrubber outlet for PCDDs/PCDFs and SVOHAPs.
Brief descriptions of the methods used follow.
5.1    LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
      TRAVERSE POINTS

      EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
select the measurement sites and to establish velocity and sample traverse point locations. The
location of measurement sites and traverse points are discussed in Section 4.0.
5.2   DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE

      EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S
Pitot Tube)," was used to determine stack gas volumetric flow rate at the cupola wet scrubber
inlet and outlet.  A Type S pitot tube, constructed according to Method 2 criteria and having an
assigned coefficient of 0.84 and connected to an inclined-vertical manometer was used to
measure velocity pressure. A calibrated Type K thermocouple attached directly to the pitot tube
was used to measure stack gas temperature. The average stack gas velocity was calculated from
the average square roots of the velocity pressure, average stack gas temperature, stack gas
molecular weight, and absolute stack pressure.  The volumetric flow rate is the product of
velocity and the stack cross-sectional area.
5.3    DETERMINATION OF DRY MOLECULAR WEIGHT AND EMISSION
       CORRECTION FACTORS

       EPA Method 3B, "Gas Analysis for the Determination of Emission Rate Correction
Factor or Excess Air," was used to measure carbon dioxide and oxygen content of the stack
gases.  Gas samples were extracted from the stack or duct, simultaneous with the EPA Method
29 (scrubber inlet) or Method 23 (scrubber outlet) sample trains using the multi-point, integrated
bag sampling technique. The bag contents were analyzed on-site within four hours after sample
collection using an Orsat® analyzer to determine % concentrations of carbon dioxide and oxygen.


-------
                                     TABLE 5.1

        SOURCES, TEST PARAMETERS, AND TEST METHODS SUMMARY
           GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN

Source
Cupola Wet Scrubber
Inlet


Cupola Wet Scrubber
Outlet






Parameter
Flow Rate
02/C02*
Moisture
PM/Metals*(a)
Flow Rate
O2/CO2*
Moisture
PM/Metals*(a)
PCDDs/PCDFs
SVOHAPs
VOHAPs
Test
Methods
EPA 1 & 2
EPA3B
EPA 4
EPA 29
EPA 1 & 2
EPA3B
EPA 4
EPA 29
EPA 23
SW-8460010
On-site GC/MS
No. of
Tests
4
4
4
4
4
4
4
4
4
4
__b
Net Run Time,
Minutes
240
240
240
120
240
240
240
120
240
240
10-15/sample
'One integrated bag sample was collected for each 60 minutes of sampling time.
'"'Sample Runs I-M29-2 and O-M29-2 were run for 237 minutes; all other runs were approximately 120 minutes.
"''Several 10-15 minute GC/MS samples were collected during the periods of manual sampling.

The Orsat® analyzer had 0.1% subdivisions. One integrated bag sample was collected for each
60 minutes of sampling time at the wet scrubber inlet and outlet.
5.4    DETERMINATION OF STACK GAS MOISTURE CONTENT

       EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine stack gas moisture content.  The quantity of condensed water was determined
gravimetrically and then compared to the total volume of gas sampled to determine the volume
% moisture content. The Method 4 procedure was conducted in conjunction with the EPA
Methods 23 and 29 and SW-846 Method 0010 sampling runs.  Condensed moisture was
determined by the difference in pre-test and post-test weights of the impingers, reagents, and
silica gel. Condensed moisture in the XAD® adsorbent trap from the SW-846 Method 0010 and
EPA Method 23 sample trains was also determined gravimetrically and the results included in
the moisture content calculations.

-------
5.5    DETERMINATION OF PARTICIPATE MATTER AND METALS

       EPA Method 29, "Determination of Metals Emissions From Stationary Sources," was
used to determine filterable particulate matter and metals at the cupola wet scrubber inlet and
outlet.  The target metals included: antimony (Sb), arsenic (As), barium (Ba), beryllium (Be),
cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb), manganese (Mn), mercury (Hg), nickel
(Ni), phosphorus (P), selenium (Se), silver (Ag), thallium (Tl), and zinc (Zn). Multi-point
integrated samples were extracted isokinetically from the 24 traverse points at the inlet and 24
traverse points at the outlet as shown in Figures 4.2 and 4.4, respectively. At each traverse point,
sampling was performed for five minutes at the inlet and five minutes at the outlet for a total run
time of 120 minutes per test. The samples were extracted through a glass nozzle, a heated glass-
lined probe, a heated quartz fiber filter, an empty impinger, two impingers containing an acidic
hydrogen peroxide solution (H2O2/HNO3), an empty impinger, and two impingers containing
acidic potassium permanganate (KMnO4). The final impinger contained silica gel.  The nozzle
was attached to the probe using Teflon® or Teflon®-coated unions and Teflon® or graphite
ferrules. A schematic of the EPA Method 29  sampling train is shown in Figure 5.1. The sample
recovery scheme for metals is shown in Figure 5.2.         >

       The filter and acetone rinses of the probe and front half of the filter housing were
analyzed gravimetrically in the PES laboratory to determine filterable particulate matter. Upon
completion of the particulate matter analyses, the particulate fractions and aqueous fractions were
submitted to TLI for metals analyses. The sample preparation and analysis scheme is shown in
Figure 5.3.  Metals other than Hg were analyzed by graphite furnace atomic absorption
spectroscopy (GFAAS) or inductively coupled argon plasma (ICP) emission spectroscopy.
Mercury was analyzed by cold vapor atomic absorption spectroscopy (CVAAS).
5.6    DETERMINATION OF DIOXINS AND FURANS

       EPA Method 23, "Determination of Polychlorinated Dibenzo-p-Dioxins and
Polychlorinated Dibenzofurans from Stationary Sources" was used to determine PCDDs/PCDFs
at the cupola wet scrubber outlet. The proposed rules amending EPA Method 23, as published in
the Federal Register, Volume 60, No. 104, May 31,1995, were incorporated. The proposed
changes correct existing errors in the method, eliminate the methylene chloride rinse, and clarify
the quality assurance requirements of the method. Samples were extracted through a glass
nozzle, a heated glass-lined probe, a pre-cleaned and heated glass fiber filter, a water cooled
condenser coil and an adsorbent trap containing approximately 40 grams of XAD®-2 adsorbent
resin. A schematic of the EPA Method 23 sampling train (which is the identical to the SW-846
Method 0010 train) is shown in Figure 5.4. Multi-point integrated samples were extracted
isokinetically from the 24 traverse points shown in Figure 4.4. At each traverse point, sampling
was performed for 10 minutes, with pertinent readings taken every five minutes, for a net run
time of 240 minutes per test.  TLI prepared the filters and adsorbent traps, and performed the
required analyses.

-------
      Temperature
        Sensor
                                         Temperature
                                           Sensor
Manometer
I      N/      I      N/      t
'       5%HUQ./    FmL,   4%KMnQ/    SIIL
 Empty               Em'pty   4%KMnQ/   silica
(Optional)   10% HjSQ             lOyoHjSQ     Gel
/Vacuum
  Line

-------
 tamaOk Bnah
«x) era wi* Aone
  Itomtoe
  bm« whh
  O.INHNOJ

-------
OS
Cental
Acid Probi
(Labele
"•'3 Container 2 Cental
i Rinse Acetone Probe Rinse Fill
* FH) (Labeled AR) (Labelf
nert Container 4
sr (HN03/H202) Impingers
sd F) (Labeled BH)
(include condensate
impinger, if used)
I

Reduce to dryness Desiccate to Aliquot taken
in a tared beaker constant weight for CVAAS

Determine residue 	 	 	
for Hg analysis
Anal. Fraction 2B
weight in beaker Determine filter
' 	 1 	 ' paniculate weight
Solubilize residue
with cone. HN03


Divide into
Acidify to pH 2 sections A
with cone. HN03 ea(* sectio
	 • 	 *»nnr- Up JL



Reduce volume to
near dryness and
digest with HF
Scone. HN03



Filter & dilute
to known volume
Anal. Fraction 1

	 ' Digest with acid
and permanganate
at 95 C for2 h
and analyze
for Hg by CVAAS
0.5 g
digest
n with
HN03


Kemovesotoiourm Digest w
aliquot for Hg permanns
analysis by CVAAS a wa(e(
F I Analytical Fraction 1H
Analyze by (CAP for Analyze for
target metals metals by GFAAS*
Anal. Fraction 1A Anal. Fraction 1A
Acidify
remaining
sample to pH2
with cone. HNO3
Anal. Fraction 2A

Reduce volume
to neardryness
and digest with
HN03&H202

An alyze
by ICAP for
15 target metals
I
Analyze by
GFAAS
for Metals*

ith acid and
nate at 95 C in
bath for 2 h

Analyze aliquot for
Hg using CVAAS
Containers 5A, SB. & 5C
Individually, three
separate digestions
and analyses:
digest with acid
and permanganate
at 95 C for2h
and analyze
for Hg by CVAAS
Analytical Fractions
3A.3B.&3C

                "Analysis by AAS for metals found at lei $ than 2 ug/mlin digastate solution,
                if desired. Or analyze for each metal by AAS, if desired.

-------
                          Temperature
                             Sensor
                                                 Condenser
  Button Hook
    Nozzle
Stack
Wall
 /
  Heated Glass
      Liner
Gas
Flow
 Gas
 Exit
                                                                              Temperature
                                                                                 Sensor
      TypeS  vJ
     PitotTube \
                    Inclned     Recirculation
                   Manometer     FumP
                               Temperature
                                 Empty  100 ml HPLC Water Empty  Silica Gel
                  Orifice
            Inclined
           Manometer
                                                   Vacuum
                                                    Pump
                                                                             Vacuum
                                                                              Line

-------
5.7   DETERMINATION OF SEMIVOLATILE ORGANIC HAZARDOUS AIR
      POLLUTANTS (SVOHAPs)

      Method SW-846 0010, "Modified Method 5 Sampling Train (MM5)," was used to collect
SVOHAPs at the cupola wet scrubber outlet. Multi-point, integrated samples were extracted
isokinetically from the 24 traverse points shown in Figure 4.4. At each traverse point, sampling
was performed for 10 minutes for a total run time of 240 minutes per test. Meter box readings
were recorded every five minutes. The SW-846 Method 0010 samples were extracted through a
glass nozzle, a heated glass-lined probe, a precleaned and heated glass fiber filter, a water-cooled
condenser coil and an adsorbent trap containing approximately 40 grams of XAD®-2 adsorbent
resin. A schematic of the SW-846 Method 0010 sampling train is shown in Figure 5.4.

      The SW-846 Method 0010 samples were extracted following the procedure of Method
3542, dated January, 1995.  The extracts were analyzed in accordance with the guidelines of
Method 8270A by High Resolution Gas Chromatography/Low Resolution Mass Spectrometry.
The three sample fractions for each test run, i.e., front half extract, the back half extract (XAD®-2
and back half rinse), and the condensate extract were combined for one analysis, per test run.
The samples were analyzed  for the SW-846 Method 8270 polynuclear aromatic hydrocarbon
(PAH) and Clean Air Act (CCA) semivolatile compounds.
5.8   DETERMINATION OF VOLATILE ORGANIC HAZARDOUS AIR
      POLLUTANTS (VOHAPS)

      Direct interface gas chromatography/mass spectrometry (GC/MS) was used to determine
volatile organic hazardous air pollutant (VOHAP) concentrations at the inlet and outlet of the
cupola wet scrubber. A single point, constant rate sample was withdrawn from the individual gas
streams using a heated probe and sample line to prevent condensation. A conditioning unit was
used to protect the GC/MS from particulate matter and excess moisture.  The gas
chromatography (GC) portion of the GC/MS separates the gaseous mixture of molecules by their
affinity for the analytical column's stationary and mobile phases.  The mass spectrometer (MS)
portion of the GC/MS uniquely identifies each molecule by detecting individualized fragments.
Positive identification of target analytes is achieved by comparison of eluting analyte GC peak
retention times in the total ion chromatogram to those obtained from the calibration, and by
examining the mass spectral pattern.

      Sample gas is introduced into the GC/MS via a pneumatic valve assembly or equivalent.
The internal standard mixture must be quantitatively co-added to every sample before injection.
Compounds are typically separated and detected in a 10- to 15-minute isothermal run.  Effluent
samples are quantified by comparing analyte GC retention times and the corresponding
instrument response to the initial three-point calibration. Figure 5.5 is a schematic of the direct
interface GC/MS sampling system.

-------
                               Primary Particulate Filter
Heated Extractive Probe
                        Calibration
                        Assembly
                            A
                                                                          Atmospheric vent
  Sample
Conditioning
    Box
                                         Heated Sample
                                          Transport Line
1
1
1
0

R
                         Analytical
                       Instumentation
                                                                       Contains moisture
                                                                       removal apparatus
                                                            Flow Meters
                                           Calibration Gas and
                                             Dilution Manifold

-------
       Measurement of VOHAPs at the cupola wet scrubber inlet and outlet showed no
concentrations above analytical instrument detection limits for any of the target analytes. Control
spikes in the parts per billion (ppb) range showed recoveries of 100%, demonstrating the
integrity of the sampling system.

-------
                 6.0 QUALITY ASSURANCE/QUALITY CONTROL
                           PROCEDURES AND RESULTS
       This section describes the specific QA/QC procedures employed by PES in performing
this series of tests. The procedures contained in the "Quality Assurance Handbook for Air
Pollution Measurement Systems, Volume III, Stationary Source Specific Methods," EPA/600/R-
94/03 8c, and in the reference test methods served as the basis for performance for all testing and
related work activities in this project.
6.1    CALIBRATION OF APPARATUS

       The preparation and calibration of source sampling equipment is essential in maintaining
data quality.  Brief descriptions of the calibration procedures used by PES follow.

6.1.1   Barometers

       PES used aneroid barometers which are calibrated against a station pressure value
reported by a nearby National Weather Service Station corrected for elevation.

6.1.2   Temperature Sensors

       Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in Section 3.4.2 of the Quality Assurance Handbook, Volume III, 1994.
Each temperature sensor was calibrated over the expected range of use against an ASTM 3C or
3F thermometer. Table  6.1 summarizes  the type of calibrations performed, the acceptable levels
of variance, and the results. Digital thermometers were calibrated using a thermocouple
simulator having a range of 0-2400 °F.

6.1.3   Pitot Tubes

       Type S pitot tubes constructed to EPA Method 2 specifications were used. Pitot tubes
meeting these specifications are assigned to a baseline coefficient to 0.84 and need not be
calibrated. The dimensional criteria and results for each pitot tube used are summarized in
Table 6.2.

-------
                   TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
Temp.
Sensor
I.D.
T6C



7C



8C



7B



RMB-13





MB-14





Usage
Stack Gas



Stack Gas



Stack Gas



Stack Gas



Meter Box
Inlet

Outlet


Meter Box
Inlet

Outlet


Temperature, °F
Reference
69
32
200
378
70
32
204
440
70
33
190
396
72
34
204
394
76
34
150
76
34
150
74
33
128
70
33
149
Sensor
70
31
203
375
71
33
202
437
70
33
188
395
73
35
201
391
76
35
149
75
35
151
75
34
129
71
34
150
Temperature
Difference
-0.2%
0.2%
-0.5%
0.4%
-0.2%
-0.2%
0.3%
0.3%
0.0%
0.0%
0.3%
0.1%
-0.2%
-0.2%
0.5%
0.4%
0
-0.2%
0.2%
0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
-0.2%
Tolerance
s

-------
               TABLE 6.2
SUMMARY OF PITOT TUBE DIMENSIONAL DATA
Measurement
~1
«2
PI
P2
Y
0
A
Z
W

Dt
A/2D,
Criteria
<10°
<10°
<5°
<5°
-
-
-
<; 0.125 in.
<; 0.03125
m.
0.1875" *
Dt <, 0.375"
l.OSD.s
As 1.50D,
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
T6C
3
3
3
1
0
0
1.031
0
0

0.375
1.37
Yes
0.84
7C
0
1
0
1
2
1
0.98
0.03
0.017

0.375
1.31
Yes
0.84
8C
0
1
1
0
0
1
0.914
0
0.016

0.375
1.22
Yes
0.84
7B
1
0
1
0
0
1
0.947
0
0.165

0.375
1.26
Yes
0.84

-------
6.1.4   Differential Pressure Gauges

       PES used Dwyer inclined/vertical manometers to measure differential pressures.  The
differential pressures measurements included velocity pressure, static pressure, and meter orifice
pressure. Manometers are selected with sufficient sensitivity to accurately measure pressures
over the entire range of expected values.  Manometers are primary standards and require no
calibration.

6.1.5   Dry Gas Meters and Orifices

       The SW-846 Method 0010 and EPA Method 23 and 29 dry gas meters and orifices were
calibrated in accordance  with Sections 5.3.1 and 5.3.2 of EPA Method 5. This procedure
involves direct comparison of the dry gas meter to a reference dry test meter. The reference dry
test meter is calibrated annually using a wet test meter.  Before its initial use in the field, the
metering system was calibrated over the entire range of operation as specified in EPA Method 5.
After field use, the metering system was calibrated at a single intermediate setting based on the
previous field test. Acceptable tolerances for the initial and final dry gas meter factors and
orifice calibration factors are ± 0.05 and ± 0.20 from average, respectively.  The results for the
gas meter and orifice used in this test program are summarized in Table 6.3.
6.2    ON-SITE MEASUREMENTS

       The on-site QA/QC activities include:

6.2.1   Measurement Sites

       Prior to sampling, the stack and inlet duct were checked dimensionally to determine
measurement site locations, location of velocity and sample test ports, inside stack/duct
dimensions, and sample traverse point locations. Inside stack/duct dimensions were checked
through both traverse axis to ensure uniformity of the stack/duct inside diameter. The inside
stack/duct dimensions, wall thickness, and sample port depths were measured to the nearest 1/8
inch.

6.2.2   Velocity Measurements

       All velocity measurement apparatus were assembled, leveled, zeroed, and leak-checked
prior to use and at the end of each determination. The static pressure was determined at a single
point near the center of the stack or duct cross-section.

-------
                      TABLE 6.3
SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
Meter
No.
M5-10
M5-11
RMB-13
MB-14
Gamma
Pre-test
0.999
1.024
1.010
0.966
Post-test
1.016
1.027
0.990
0.982
% Diff.
1.7
0.3
-2.0
1.9
EPA Criteria
±5%
± 5% '
± 5%
±5%
Orifice Coefficient
Average
1.591
1.819
1.859
1.862
Range
1.532-1.640
1.798-1.926
1.800-1.925
1.756-1.923
EPA Criteria
1.591 ±0.20
1.819 ± 0.20
1.859 ± 0.20
1.862 ±0.20

-------
6.2.3  Flue Gas Composition

       Integrated, multi-point, flue gas samples were collected in Tedlar® gas bags from the wet
scrubber inlet and outlet. Prior to use the bags were leak checked and purged with nitrogen to
ensure cleanliness. Prior to and after completion of each sampling run the entire sampling
system was leak checked from the tip of the probe. The bag samples were analyzed on-site using
an Orsat® analyzer within four hours after sample collection, in accordance with EPA Method
3B.  Prior to use the Orsat® analyzer was assembled and replenished with fresh reagents and leak
checked using the manufacturer's procedures.

6.2.4  Moisture

       The SW-846 Method 0010 and EPA Methods 23 and 29 sampling trains were used to
determine the flue gas moisture content. During sampling, the exit gas of the last impinger was
maintained below 68 °F to ensure complete condensation of flue gas water vapor.  The total
moisture was determined gravimetrically using an electronic platform balance with 0.1 gram
sensitivity.  The XAD® adsorbent modules from the EPA Method 23 and SW-846 Method 0010
sampling trains were also weighed and their weights included in the moisture catch.

6.2.5  Method 23. Method 0010 and Method 29

       The field sampling QA/QC for EPA Methods 23 and 29 and SW-846 Method 0010 were
similar. Table 6.4 summarizes the critical measurements made and the EPA's acceptability
criteria. All pre- and post-test sample train leaks met the acceptance criteria. The isokinetic
sampling rates deviated by no more than 7.0% thereby meeting each method criteria of 90-110%.

       EPA Methods 23 and 29 and SW-846 Method 0010 field blanks were collected near each
of the sampling locations to check for any sample contamination at the sites. Sample trains were
assembled and pre- and post-test leak checks were conducted.  The sample trains were recovered
in the same manner as the actual  sample runs.  Each field blank train was subjected to a
minimum of one leak check in the laboratory and three to five leak checks at the sampling site,
depending on the location.

       An acetone blank and quartz fiber filter were taken as control samples for the particulate
analysis and subsequent analysis for the target metals.  Blanks were taken of the metals absorbing
and recovery reagents.

-------
                                         TABLE 6.4
       SUMMARY OF EPA METHODS 23 AND 29 AND SW-846 METHOD 0010 FIELD SAMPLING QA/QC DATA
Date
09/23/97
09/24/97
09/25/97
Site
Wet Scrubber
Inlet
Wet Scrubber
Outlet
Wet Scrubber
Inlet
Wet Scrubber
Outlet
Wet Scrubber
Inlet
Wet Scrubber
Outlet
Wet Scrubber
Outlet
Wet Scrubber
Outlet
Run No.
I-M29-1
O-M29-1
O-23-1
O-0010-1
I-M29-2
O-M29-2
O-23-2
O-0010-2
I-M29-3
I-M29-4
O-M29-3
O-M29-4
0-23-3
O-23-4
O-0010-3
O-0010-4
Pre-Test
Leak Rate
acfm
0.003 @ll"Hg
0.005 @ 12" Hg
0.003 @1 5" Hg
0.003 @ 15" Hg
0.006 @ll"Hg
0.002 @ll"Hg
0.002 @1 5" Hg
0.005 @1 5" Hg
0.014 @ 27" Hg
0.008 @ 15" Hg
0.002 @ 10" Hg
0.002 @ll"Hg
0.008 @ 15" Hg
0.005 @ 15" Hg
0.011@16"Hg
0.004 @ 15" Hg
Post-Test .
Leak Rate
acfm
0.006 @ 10" Hg
0.001 @ 7" Hg
0.003 @ 6" Hg
0.032 @ 7" Hg '
0.005 @ 22" Hg
0.001 @ 6" Hg
0.002 @ 10" Hg
0.002 @ 9" Hg
0.001 @ 12" Hg
0.002 @1 8" Hg
0.002 @ 15" Hg
0.002 @ 11" Hg
0.019 @ 17" Hg
0.002 @1 6" Hg
0.004 @ll"Hg
0.003 @ll"Hg
EPA
Criteria
acfm
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
Percent
Isokinetic
102.3
95.4
93.0
98.4
104.5
99.3
101.5
101.2
103.8
105.1
97.8
95.9
103.4
102.0
101.2
100.8
EPA
Criteria
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%

-------
6.3    LABORATORY ANALYSES

6.3.1  Participate Matter

       Particulate matter analysis consisted of front half acetone sample rinses and quartz fiber
filters. Prior to the field testing program, the filters were tared in the PES (or DEECO)
laboratory, stored in petri dishes, and sealed with Teflon® tape. Several beakers were also
cleaned and tared for subsequent use in evaporating the acetone rinses. Upon receipt in the PES
laboratory, the acetone rinses were placed in the tared beakers and evaporated to dryness at room
temperature. The filters and beakers were desiccated and weighed to a constant weight. All
weighings were within the method requirements of 0.5 milligrams between two consecutive
weighings taken at least six hours apart.

6.3.2  EPA Method 29

       TLI analyzed the EPA Method 29 samples consisting of eight stack gas samples, two
blank samples and one reagent blank to determine concentrations of antimony (Sb), arsenic (As),
barium (Ba), beryllium (Be), cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb), manganese
(Mn), mercury (Hg), nickel (Ni), phosphorus (P), selenium (Se), silver (Ag), thallium (Tl), and
zinc (Zn). All metals, except Hg, Tl, As and Co concentrations, were determined by inductively
coupled plasma emission spectroscopy (ICP). Thallium concentrations for most of the back half
samples (refer to  the TLI case narrative for an exact listing of the samples) were determined
using graphite furnace  atomic absorption (GFAA). Arsenic and Co were also analyzed by
GFAA. Specific  TLI QA/QC activities for GFAA and ICP analyses consisted of:  laboratory
control spikes, post-digestion matrix spikes of one sample set, duplicate analysis of one sample
set, serial dilution and analysis of one sample set, analysis of a method blank, and analysis of
field and reagent  blanks. Mercury was analyzed by cold vapor atomic absorption spectroscopy
(CVAAS). Specific TLI QA/QC activities for CVAAS analyses consisted of analysis of a
method blank and analysis of field and reagent blanks. The results of these QA/QC activities are
summarized in Tables 6.5 through 6.10 for metals other than Hg and in Tables 6.11 through 6.14
for Hg. Complete QA/QC data are contained  in the TLI analytical report in Appendix C.

6.3.3  EPA Method 23 PCDDs/PCDFs

       Prior to the field testing program, TLI prepared PES' XAD®-2 adsorbent traps and
precleaned the glass fiber filters. TLI's laboratory QA/QC program consisted of adding
isotopically labeled standards to each sample at various stages of the project to determine
recovery efficiencies. The following types of standards were used:

-------
                 TABLE 6.5

SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
         LAB CONTROL SPIKES (LCS)
Analyte
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Spike Amt
Aig/L"
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
LCS Recovery
88%
79%
91%
88%
91%
94%
91%
92%
90%
91%
91%
92%
91%
91%
92%
Recovery Limits
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
80-120%
 1 Micrograms per liter.

-------
                            TABLE 6.6

        SUMMARY OF EPA METHOD 29
                MATRIX SPIKES (POST
ANALYSIS QC DATA
DIGESTION)

Analyte
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Spike Amt /ug
50
50
50
50
50
25
50
50
50
1000
50
50
50
50/25
200
Percent Recovery*
Run No. M29-1-
FH
87%
82%
SL
65%
SL
92%
SL
SL
SL
83%
SL
SL
SL
SL
SL
Run No. M29-1-BH
76%
104%
96%
93%
97%
N/A
94%
94%
95%
86%
93%
90%
72%
93%
90%

Recovery
Limits
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
*SL =  Spike Low, % Recovery is not considered valid when spike amount is less than 20% of recovered amount.

-------
                                 TABLE 6.7

         SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
                         DUPLICATE ANALYSES
Analyte
Sample yug"
Duplicate /ug"
RPDb
RPD Limits
Run I-M29-2-FHc
AR
Asd
Ba
Be
Cd
Cod
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
25.2
82.4
1,170
2.37
231
46.7
1,020
140,800
55.7
5,560
22,300
54.4
60.0
63.7
160,700
24.7
N/A
1,190
2.34
227
N/A
1,010
149,500
55.2
5,550
23,800
59.1
58.7
63.2
172,100
2.00%
N/A
1.69%
1.27%
1.75%
N/A
0.985%
5.99%
0.902%
0.180%
6.51%
8.28%
2.19%
0.788%
6.85%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
± 20%
Run I-M29-2-BH6
Ag
Asd
Ba
Be
Cd
Co"
Cr
Mn
Ni
P
Pb
Sb
Se
T1d
Zn
2.32
1.90
32.0
0.205
10.7
4.12
27.9
3,360
2.06
99.1
497
3.89
1.59
< 0.217
4,090
2.44
N/A
31.9
0.206
10.8
N/A
28.2
3,850
2.18
99.9
501
4.24
1.54
N/A
4,140
5.04%
N/A
0.313%

-------
                                       TABLE 6.8

                SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
                                  SERIAL DILUTION
Analyte
Sample /^g
Serial Dilution /uga
RPDb
RPD Limits
RunI-M29-l-FHc
Ag
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
10.8
28.2
406
< 0.100
82.8
31.3
502
61,300
37.5
476
9,560
66.5
25.1
30.8
77,200
12.3
27.3
424
< 0.500
97.0
40.7
574
62,400
44.9
530
9,610
74.4
23.5
39.5
78,200
13.0%

-------
                       TABLE 6.9

  SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
              METHOD BLANK RESULTS
Analyte
Ae
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
7,n
Detection Limit
MS/La
1
7.5
2
1
1
1.5
2
2
3
30
2
4
3
5
12
MB 1 Recovered Amount
/LiZ/L*
-0.47
-0.30
-0.05
0.01
-0.37
0.70
0.92
0.12
-1.13
-12.45
0.20
-1.43
0.08
-2.46
5.47
The Method Blank is considered a "Pass" when the recovered amount is less than the detection limit.
a Micrograms per liter.

-------
                 TABLE 6.10
SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
           FIELD BLANKS RESULTS
Analyte
As
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Outlet Front Half, /zg"
0.129
< 0.750
13.0
< 0.100
< 0.100
0.640
7.06
1.54
4.03
5.19
0.237
3.89
4.07
0.720
10.2
Outlet Back Half, /^g"
0.128
< 0.750
0.366
< 0.100
< 0.100
< 0.150
0.737
4.69
< 0.300
4.35
1.08
0.550
< 0.300
0.610
6.78
 ' Micrograms.

-------
                    TABLE 6.11
   SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
 MERCURY SUMMARY REPORT - LAB CONTROL SPIKES
Sample ID
LCSl
LCS 1 Dup
LCS2
LCS 2 Dup
Spike Amount
,"g/La
4.7
4.8
5.2
5.2
Recovery
95%
96%
103%
104%
Recovery Limits
80-120%
80-120%
80-120%
80-120%
1 Micrograms per liter.

-------
                             TABLE 6.12

           SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
     MERCURY SUMMARY REPORT - MATRIX SPIKES (PRE-DIGESTION)
Sample ID
I-M29-1-H202BHMS
I-M29-1-H202BHMSD
O-M29-1-H202BHMS
O-M29-1-H202 BH MSD
O-M29-2-H202 BH MS
O-M29-2-H202 BH MSD
O-M29-4 H202 BH MS
O-M29-4-H202 BH MSD
Spike
Concentration
^g/L"
5
5
5
5
5
5
5
5
Recovery
97%
100%
81%
83%
104%
111%
108%
113%
Recovery Limits
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
75-125%
1 Micrograms per liter.

-------
                        TABLE 6.13

    SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
     MERCURY SUMMARY REPORT - METHOD BLANK
Sample ID
MB1
MB1 Dup
MB2
MB2 Dup
Detection Limit
A*g/La
0.200
0.200
0.200
0.200
Recovered Amount,
y"g/L"
0.023
0.005
0.018
0.010
The Method Blank is considered a "pass" when the recovered amount is less than the detection limit.
a Micrograms per liter.

-------
                     TABLE 6.14
     SUMMARY OF EPA METHOD 29 ANALYSIS QC DATA
MERCURY SUMMARY REPORT - FIELD AND REAGENT BLANKS
Sample ID
FH
FH - Dup
BH
BH- Duo
HNO,
HNO, - Dup
KMnO,
KMn(X - Dup
HC1
HC1 - Dup
Outlet Field Blank //g"
< 0.400
< 0.400
< 0.600
< 0.600
< 0.400
< 0.400
<1.60
<1.60
< 0.880
< 0.880
Reagent Blank //g"
< 0.400
< 0.400
< 0.600
< 0.600
<0.116
<0.116
<1.60
<1.60
< 0.920
< 0.920
  Micrograms

-------
       Internal Standards were spiked in the TLI laboratory after the field sampling program and
       prior to sample extraction. Recovery efficiencies for these compounds were used in
       quantifying the actual PCDDs/PCDFs isomers measured in the samples.

       Surrogate Standards were spiked in the TLI laboratory on the XAD®-2 resin prior to the
       field sampling program. Recovery efficiencies for these surrogate compounds provided a
       measure of the sample collection efficiency and an indication of any analytical matrix
       effects.

       Alternate Standards were spiked in the TLI laboratory after the field sampling program
       and prior to sample extraction. Recovery of these compounds indicated the extraction
       efficiencies.

       Recovery Standards were added in the laboratory after extraction just prior to GC/MS
       analysis.

       Table 6.15 summarizes the recovery efficiencies for the various standards and the
respective quality control limits. The recovery efficiencies for the XAD® blank, field blank, and
samples were all within the method QC limits. Refer to TLI's case narrative for their discussion
of any quality control anomalies.

6.3.4 SW-846 Method 0010

       TLI analyzed the SW-846 Method 0010 samples following the procedures of
SW-846 Method 8270A Rev. 1 (7/92). Field blanks and laboratory blanks were used to check
for contamination. The blanks were processed in the same way the field samples were processed.
The results of the field and laboratory blanks are presented in Table 6.16.  Also shown are the
average catch weights for the compounds presented.  The significance of the blank values was
discussed in Section 2.

       A five point initial calibration was performed using internal standards and instrument
response factors developed for the target analytes.  Method 8720A procedures require the percent
standard  deviations of the initial calibrations to be within 50% for most analytes and 30% for
some analytes. All internal standards were within the Method 8270A quality control criteria.
The XAD®-2 resins were spiked with surrogate standards prior to the field sampling. The
percent recoveries for the surrogate standards are presented in Table  6.17.

-------
                                  TABLE 6.15




    SUMMARY OF EPA METHOD 23 STANDARDS RECOVERY EFFICIENCIES

FULL SCREEN
ANALYSIS
Internal Standards
2,3,7,8-TCDF
2,3,7,8-TCDD
1,2,3,7,8-PeCDF
1,2,3,7,8-PeCDD
1,2,3,6,7,8-HxCDF
1,2,3,6,7,8-HxCDD
1,2,3,4,6,7,8-HpCDF
1,2,3,4,6,7,8-
HpCDD
1,2,3,4,6,7,8,9-
OCDD
Surrogate Standards
2,3,7,8-TCDD
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8,9-HpCDF

Alternate Standards
1,2,3,7,8,9-HxCDF
2,3,4,6,7,8-HxCDF
CONFIRMATION
ANALYSIS
Internal Standards
2,3,7,8-TCDF
Percent Recovery
TLI
M23
Blank
79.4
75.4
96.9
86.6
123
94.9
92.5
87.5
84.0
92.5
100
92.3
96.7
91.3
68.6
81.4

M23
1
57.6
86.4
93.5
109
110
102
80.5
99.6
99.7
85.8
97.7
88.3
94.3
98.3
79.9
91.8

M23
2
78.9
90.2
87.5
100
102
101
82.1
94.8
95.1
89.0
94.4
95.3
99.6
88.0
93.3
104
81.8
Trip
Blank
85.0
82.3
101
118
105
95.7
90.0
102
104
94.1
98.5
93.1
96.8
92.4
85.3
104

O-
23-1
89.8
85.5
78.8
83.7
111
94.1
61.3
95.0
63.5
93.7
95.6
92.0
98.9
101
101
112
95.4
O-
23-2
103
90.5
96.1
103
120
106
92.4
89.7
63.8
102
92.0
95.8
85.6
94.6
107
116
102
O-
23-3
45.9
58.6
77.7
84.8
62.8
61.3
47.5
70.9
89.2
85.9
80.7
88.1
97.6
97.2
49.2
48.9
58.9
0-
23-4
69.7
83.5
96.0
110
85.6
87.7
65.1
84.5
95.2
91.1
95.4
99.0
101
105
75.3
82.5
87.9
QC
Limits
40-130%
40-130%
40-130%
40-130%
40-130%
40-130%
25-130%
25-130%
25-130%
70-140%
70-140%
70-140%
70-140%
70-140%
40-130%
40-130%
40-130%
* Confirmation analysis was not necessary on these samples since no TCDF's were detected in the full screen analysis.

-------
                                        TABLE 6.16
       SW-846 METHOD 0010 FIELD AND LABORATORY BLANKS RESULTS
Compound
Acetophenone
Di-n-butylphthalate
2-Chloroacetophenone
bis(2-Ethylhexyl)phthalate
Naphthalene
Amount, micrograms*
Average
Catch
Weight**
13.12
{10.98}
ND
{20.56}
{52.80}
Field
Blank
3.78
3.41
{0.35}
21.61
5.85
Method
Blank
2.53
1.61
3.83
0.57
2.44
Laboratory
Blank
ND
29.02
{0.41}
1.19
ND
*  Values in brackets { } are estimated values that were above the detection limit, but below the quantitation limit.
   ND = Compound was not detected.
** Average Catch Weight = Average sample amount from runs O-0010-1, O-0010-2, O-0010-3 and O-0010-4.

-------
                             TABLE 6.17
          SW-846 METHOD 0010 SURROGATE RECOVERY RESULTS
Surrogate
Phenol-d5
Nitrobenzene-d5
1 ,3,5-Trichlorobenzene-d3
1 ,4-Dibromobenzene-d4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d10
Pyrene-d,0
Terphenyl-dj^
Percent Recovery
O-
0010-1
77
76
80
82
82
103
103
82
91
O-
0010-2
79
68
63
81
78
108
93
81
90
O-
0010-3
77
72
68
82
84
110
98
87
94
O-
0010-4
75
63
58
71
81
119
91
79
86
Field
Blank
66
62
60
68
72
92
90
87
108
Method
0010
Blank
57
56
53
64
67
99
95
106
ND
Lab
Blank
69
74
63
74
72
91
92
97
ND
Method
QC
Limits
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
20-120%
ND= None Detected.

-------
  APPENDIX A





-------
  Appendix A.I




 Raw Field Data





-------
j asm tarn
               TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
       Plant:
       Data:


       Sampling Location:
       Inside of Far Wall to Outside of Nippie:	
       Inside of Near Wall to Outside of Nipple (Nipple Length):  V fa
       Stack I.D.:    &6 '/V "	
       Distance Downstream from Flow Disturbance (Distance 8):
                                inches t Stack 1.0. =  /. 4   dd
       Distance Upstream from Flow Disturbance (Distance A):
                       *?3 >/   inches / Stack I.D. =  / .V  dd
       Calculated By: /lt>D	
  Schematic of
Sampling Location
Traverse
Point
Number
• 1
2
3
V
r
*
7
^
^
10
II
a
Fracnon
of
Length
6.02J
rt.O

o.\n & tfO O^L o. 6^/g O.^/) 0.8*5 rrftto to.^33 0.1^ Length (inches) (&.^ rnf*-vr G>C.tt a.^~ fa-it 0*.2' 5^423^' ^^ ^ •• #/!*•"£/ %a 6l/.8$ei-v w i/^ Nipple Length (inches) V^" v{/?"


-------
3BC3 C3
                    GAS VELOCITY AND VOLUMETRIC FLOW RATE
      Plant: & t\
Sampling Lo<
Run #: ?t-£
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travaraa
Point
Numbar
/? 1
3.
5
q
$
&
}
$
^
to
II
11
B \
2
1
(i
r
<£
7
$
'7
to
,•(
a


:ation: iv,Ve_f Clock Time: . v- ^
--4e-sf r-V4<- Operators- A^fo / ^ M
ressure, in. h
a
la: ^ ^ , 7 ¥ Static Pressure, in. HUO: - ft ?sr
Molecular wt.. Drv ^a>. V Pitot Tube, Cp: O ^
sion, in. Diameter or Side
** _' J /' It -».!-* | 	 •
H: 0^ /y Side P- —
_
: - ' DrvBuiB.^h:

Valocity
Haad
in. H2O
J/L
1.3
I.l
| >/ ?,,
LZ
>*& 1.3
3,
^» /.T.
0 . '1C
ft.-\t/
r>. s)
tx:t#
D, >c
^.*x&

^SF -c, W
Stack ; (
"°7 6
/52J/ 'i
(V/7 i2.
/vy/^
/f/3/3
i v y/ <$"
/ /r /?
'vr/y
/ V(£ /.5
/ V ?/ 6
/VJ//6
r>W / .2
(To //V
/ J*"/ 7
|56/ /C-
lS«/ t
/.^/r
)V6/ /
IVe>/ /
Nif S~
NO/ C
ifc/ />'
^7/ /

f!./i// #>.
Md - (0.44 x SiCOj) + (0.32 X %V*Md - (0.44 x ) + (0.32 x ) -•• (0.28 x )
Md -
% H2O % HjO
TJ- °F- °R(°F^460)
Pa - Pb * S'P' -- ( ) + 	
13.0 13.0
Pa - In. Hg
flF-
— [ Ta ^R)
Va-«b.4«xCpx ^H x y psxM8

Va- ft/a
A.- ft2
Qa - VaxAaxOOa/m
Qa- x xOO
Qa • acfm
Pa ^HjO


-------
                                                 FIELD  DA IA SHEET
 Plant: ^
Sampling Location   T^
Run Number:?&&&(• \  Date: ^-^ -"f?
Pretest Leak Rate: 3.QC3  cfm @ |l" in. Hg.
Pretest Leak Check: Pitot:  ^ Orsat:  S
                              Sample Type:
                              Pbar:  ^  ? V'
                              CO2:
                                                           Operator:
                                                          '
                                                             Ps:  -/
                                                             O2:
                                                             Nozzle ID:
                                                             Assumed
                                                                                                          Pi-,  I & >
                                                                                                            o
                                                                                                        Thermocouple #:
                              Probe Length/Type:
                              Stack Diameter:
                                                                        Pitot #: £'-
                                                         Vfr"
                                                                     As:
                                                             Meter Box #: ^-]<  Y: f.rOVAH®:   , #
                                                             Post-Test Leak Rate: Q^J, c*m @ &2_ '"•
                                                             Post-Test Leak Check: Pitot:  V Orsat:
                                                                                                                                     J77T
Traverse
 Point
Number
Sampling
 Time
 (mln)
Qockrime
 (24-hour
 dock)
Gaa Meter
 Reading
 (Vmjtt3
                                        Velocity
                                       Head (Ap)
                                        inH2O
Otitce Pressure Drtferential
     (AH) in H2O
 Desired   I   Actual
Stack
Temp.
 (Ts)
  Temperature
      °F
Probe     Rltof
Impinger
 Temp.
  °F
Dry Gas Meter Temp.
  Inlet
(Tm in°F)
  Outlet
(Tm out°F)
 Pump
Vacuum
C«.Hg)
        0
        IV 'to
        ,5"
        u
                                              l.'l
                                               v. v
                                                              ^37
                                                                                                 60
                                                                                                                                 i^r-  i--i
   .5
                                                          V
                                                                                           o r
                             Si
                                                                                                 it 6
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                                                             J^i
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                                                                                                                        r.c-r
                                                                                                6':
   6
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                             39
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                                                                          2VZ
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                                                                                                                           ro
                           , U
                                                                       -m
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       16 X!
                       VVr. ^,6
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                                                                                                   88
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                                                                                                         oo
                                                              ft
                                                                         32S"
   ID
                                                                 m
                                                                                                   79
                                                                                                r?
                                                                                                                    7-
       (00
                ^"5^,1 A
                                                                                  56
                                                                                                        98
              ?i I/O
                   /.
      1 3(0
                   AVrn-

-------
           Plant:  6-'
         FIELD DA IA SHEET
                  Zl    Operator:
Sampling Location   ~^|
    Number:   ^X     Data:
               o cctf
Pretest Leak Rate: &B&.  cfm @  11  in. Hg.
Pretest Leak Check: Pitot:  \/  Orsat:   ^
                                    Sample Type:
                                    Pbar: 33. 8 T
                                    C02:
                                                                                  Nozzle ID: C- \
                                                                    Ps:
                                                                    O2:
                                                                                                   Thermocouple #:
                                                                                                   Filter #:
                                                                   ,  D
                                    Probe Length/Type:
                                    Slack Diameter:  £•£ '/••/
                                                          fi.to
                                                                             237
                 LO
                    , ri
                                                          /.at
     J .c'n
                                                              37
                                                                                           Go
                                                                                                  &*•
             r
                              f.o
                                                          l. i
                                                                   /2V
                                    . «i ft
                                                    1 (i
                                               i.o
                                                    i.O
                                                                                                  ei
                       If. oV
                              (.1
                                                                              PC
                                                                                                                   ft
                                              I-/

                                                    (•1
                                                                                           ft
                       I'.VV
                               J750. VX
                             0.18
                                                          .O
                                                                                           ft

                  nc
                                                                             231
                                                                                                 fti
                                              i. l
                                                         i.1.
                                                                                            80
           R ii
                             0.37
                                               0.3^0
                                              n 41
                                                             IM.
                                                          o .
                                                                                             61
                                                             AH=

-------
                                                                       Page
                                                                                               of
Plant Name:
Run Number:
               (rfv(
               x
                                     Test Date:
                                     Operator:
Traverse
 Point
Number
Sampling /dock Time
 Time.  /  (24-hour
 OniiU /   clock)
 Gas Meter
 Reading
  (U)ft'
 Velocity
llead^P.)
 in. IhO
Orifice Pros. Differential
 Desired
Actual
        Stuck
      Temp. • F
   Probe
Temp./ Filler
 Temp.0 F
Impinger
 Temp.
  •F
Dry Gas Meter Temp.
                                             Inlet
                                                      (Juliet
                                                          °F
 Pump
Vacuum
 In.llg
        JSC    /
   io
 HO
5" 3
                         33
                                    bl
        ivr
                                  0-1]
                                                   i SI
                                  o .
                                  G.
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                                                    $0
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                                                                                    8-2.
                                                                                                 i/
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                                 13*5
                                                           9-X
                                                              /S"
                                           ar
                                                                            81
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                \l~-c3
                           1.3
                                 132
                                                           32,
                                                              //r
                                                 1.3
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                                         /.**-
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                                                                     /f
                                  1,3
                                          \.v
                           .  ft
                                                         23?
                       576. •
                                                                     60
                                  1.2.
                                                                     65"
                                  1.3
                                                              '

-------
                                               FIELD DA IA SHEET
Sampling Location IL'ef ^/,U-
?f'lllJ,9-3RunNumber: 2 Dato: ?/2>"
Pbar:
/*7 C02:
•IP"- n
77. /fl
n
.47 v^pciaiui. 1 in /n
Ps: -n,7f
02: /O
Assumed Bws: tES
Meter Box #: /*^>'-'f
Pretest Leak Rate: O.OW  cfm @ ^2. m. Hg
Pretest Leak Check: Pitot:  ^  Orsat:
                                                                                                    Thermocouple »:
                                                                                                    f Filter #:
                                                                                                    Y:
                                                                                                                          fyf * ^^
                                          Probe LengtWType: (,'
                                          Slack Diameter:
                                                                                                           .
                                                                             Post-Test Leak Rale: .Qtt  cfm @ [2. in. Hg.
                                                                             Post-Test Leak Check: Pftot: ^  Orsat: *—
Tiav«ra«
 Point
Nurnbai
 An
   i
   .5"
   n
Sampling
 Ume
 (rnln)
   0
         7
        /O

        Zo
         5T
         7c
  ,/r
         lit)
            Qockrinw
             (244iour
              dock)
GuMettr
 Reading
                       stuw
                           '".»-'
 Velocity
Kead (Ap)
 lnH2O
        Oiitc* Pr«ssui« Diftet«nlial
            (AH) In H20
                         Desired
                   Actual
Stack
Temp.
 (Ts)
  Temperature
     °F
Probe
HIM
Impinger
 Temp.
  °F
              Dry Gas Meter Temp.
  Inlet
(Tmin0F)
  Outlet
(Tmout°F)
^&L
                                        J&L.
                                        _LP_
                                          1.0
                                          \.o
                                          i.i
                                         .32
                                            3.
                                             17J1
                                                   3.7?^
                                                   I.JS
                                                   I./IT
                          ion
                                                     2,1
                                                      7,1
                                                      •3.0
                                   3. '
                                   *?. ?
                                                      1-7
                                   f.y
                                   VL
                      u
                                                                    1*70
                                                                      m
                                                                      lit
                                                                     /^c
                                                                             75"?
                                                                       7.^
                                                                             2ft,
                                                                       277
                                                                                      -LC7
                                                                                    27-r
                                                                               27V
                                                                               171
                                                                                    16-s
                                                                              _7fit
                                                                                27<5
                                                                               761
                                                                                     Z67
                                                                                        5T
                                                                      5T7
                                                                                        ri
                                                                                        61
                                                                                            rv
                                                     it.
                                                               -74
                                                                                                      79
                                                                                                     71
                                                                             $7
                                                                                                     91
                                                                                    ri
                                                                                                            6'C
                                                                                                        £7
                                                                                                            -71
                                                                       77
                                                                                                            76
                                                                                                            77
                                                                                                           7*
                                                                                                           7/5
                                                                                                            T'f
                                                            ."JF
 Pump
Vacuum
On Hg)
                                                                                                               7
                                                                                             8"
                                                                                            /O
                                                                                             /O
                                                                                             If
                                                                                            /I

-------
                                                FIELD DA IA SHEET
Plant: iy,
Sampling Location
Run Number: 1
n
~T!^K£
Date:

wtl^
yWfr
Sample
Pbar:
C02:
Type:
Zl/o
11
tf-2f
Ps:
O2:
Operator: /V» /*f^
— l?.7f
/o
                                                                              Nozzle ID:
                                                                                                      Thermocouple »:
 Pretest Leak Rate:  ,00? elm @ j£ in. Hg.
 Pretest Leak Check: PHot: ^  Orsat:   ^
    Probe LengthHype.
    Stack Diameter:
                                                                Pilot*:
                                                             As:
                                                            Assumed Bws: JJ[	Filler *:	
                                                            Meter Box #:  ftf-it Y: /,0y/  A>
                                                            Post-Test Leak Rate: ^OQ?, elm
                                                            Post-Test Leak Check: Pilot:  ^
                                                                                                       in. Hg.
                                                                                                   Orsat:
                                                                                                     AT'
Traverse
 Point
Numbei
   V
 A/2
  ffl
Sampling
 Tim
 (mln)
        /o
        ir
        zo
         55-
         (00
Qockrima
 (24-hour
 dock)
76y.
GosMelar
 Reading
 (Vmjn3
                         772.
                         727.7^
                         •732.^6
                               71
                          77;. f*
                             , f ^
                              ,¥3
                         ^00, 70
 Velocity
Head (Ap)
 lnH2O
                         Oiica Pressura Differential
                              (AH) In H2O
                          Desired
                    Actual
Stack
Temp.
 (Ts)
                                        Temperature
Ptob*
bnpinger
 Temp.
  °F
                       Dry Gas Meter Temp.
  Inlet
(Tmln0F)
  Outlet
(Tmout°F)
                ^7r
                 .76
                 .77
_Lo
tT
J.^
                                         /.I
                                    .11
                                   M
JiO
 l.dT
                                    Jo
                                              J./76
                                             9.7/G
                                             1.01 r
                                                 r.i
                                               -Z..7
                                                       10
                                                                 I7C
                                                                       f3i
                                                                      n*
                                                         (Vf
                                                                /Ji
                                                                        767
                                                      767
                                                                         267
                                                                        TV 7
                                                                        -277
                                                                 "20
                                                                              7JO
                                                                 761
                                                                                 •27?
                                                ?Tf
                                                                                77?
                                                                                771
                                                                                  5?
                                                                                  sz
                                                                                  11
                                                                                  55'
                                                                                         58
                                                                                         ri
                                                                      rt
                                                                      60
                                                                                  ev,
                                                                                          167
                                                                              ;or
                                                                                          Kf
                                                                              1(6
                                                                                         107
                                                                                         t<>7
                                                                                                       ho
                                                                                                      (to
                                                                              HO
                                                                             (II
                                                                (61
                                                                              /O?
                                                                                                 ft
                                                                                                               ?7
                                                                        fc
                                                                        16
                                                                                                 n
                                                                                                         fr
                                                                        fc
                                                                                                   Tin=
 Pump
Vacuum j^"^1
On.Hg)
                                                                                             •/o
                                                                                              rz
                                                                                              /r

                                                                                             a
                                                                                              /^
                                                                               /X
                                                                                              13

-------
                       PARTICIPATE/ SAMPLE RECOVERY DATA SHEET
Client/Location:
                                             Sampling Date(s):
RUN No.: £~MZ9~I Rec
Impingers:
Final Wt.
Initial Wt.
Net Weight
Description of I
Silica Gel Coloi
Filter I.D. No.:
Description of I
Probe Rinse Cont
Impinger Content
1
7S6.0
575. /
/ GO , /
overy Dat
2
70Z.C


//?,4
mpinger Contents:
* *



'articulate on Fill
ainer I.D.:
e: ?/2
3
7/2,2
7&J.8
224
-2
•J Recovered
4
tf/,7
+16.9
4-,t
Total Hois
CLEAR


ber: DKC
Percent Si
Filter Coi
?U/A/
5
7/5.7
7/.2.C
3. 1
By: £>h
6
GflJ
Gff.l
-2.3
sture = ,?/6r3

jent:
itainer I

20
.D.:
if
Silica Gel
J]t$
9tf.$
fro
grams

X

Sealed: f#N
Liauid Level
.3 Container:
Liquid Level
Marked/Sealed: TON
Marked/Sealed: (YJN
RUN No.:
  Impingers:

  Final Wt.

  Initial Wt.

  Net Weight
 Recovery Date:
1      2        3
Recovered By: _
     5        6
                                                                  Silica Gel
1010. \
5 JSP
ffT./
7ff.3
5m
/5f7
8153
7/3,1
102.2-
7*7. £
ffA?
300.3
7*6.1
71 W
7ZS
£f5.5
6*t.S
3,0
?50,\
m,6
3/.S
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
                                                                      grams
                                        Percent Spent:
                	     Filter Container I.D.:
Description of  Particulate on Filter:  F/lT£& WET & 8U)b/N
Probe Rinse Container I.D.: 	
Impinger Contents Container: 	
                                            	j=i_^   	  Sealed:  Y N
                                             Liquid Level Marked/Sealed:  Y N
                                             Liquid Level Marked/Sealed:  Y N
RUN Ho.;l"/l/|2^.
  Impingers:

  Final Wt.'

  Initial  Wt.

  Net Weight
                     Recovery Date:
                    123
                             Recovered By: _
                                 5        6
                                                                  Silica Gel
               $51.6
                        739.1
                        236.5
                                 352-2
                                         $09,7
                3.2.
                                         2f.2
                               35.2
          Xltt.7
          --223
77.5
                          TT-^
Description of Impinger Contents:
Silica Gel Color: 	
Filter I.'D. No.: 	
                                        Totalr Moisture  =   jtf'.O _
                                            f SLIGHT ttw/COLD*
                                                                      grams
Description of Particulate on Filter:  HEW/
Probe Rinse Container I.D.:  	
Impinger Contents Container:	
                                         Percent Spent:
                                         Filter Container  I.D.:
                                                             _  Sealed: Y N
                                             Liquid Level Marked/Sealed: Y N
                                             Liquid Level Marked/Sealed: Y N
BLANKS:  Probe  rinse:
                                  lapinger:

-------
                       PARTICULATE/ SAMPLE RECOVERY DATA SHEET
Client/Location:
RUN No.: X'MZ.9-^  Recovery Date:
                   1       2        3
Impingers:

Final Wt.

Initial Wt.

Net Weight
             Sampling Date(s):

                Recovered By: _
                    5        6
                                                                   Silica Gel
                 005 A
                        173
                        1(0.0
710.3
                                 .STf.f
                                         '1*8. /
                 7/K3
                                                           2.9
03.0
Description of Impinger Contents:
Silica Gel Color:  	
Filter I.D. No.:   	
Description of Particulate on Filter:
Probe Rinse Container I.D.: 	
Impinger Contents  Container: 	
                                         Total Moisture =   *? S*Q. *?    grams
                                         Percent Spent:
                                         Filter Container I.D.:
                                             	  Sealed:  Y N
                                              Liquid Level Marked/Sealed:  Y N
                                              Liquid Level Marked/Sealed:  Y N
RUN No.:
  Impingers:
                     Recovery Date:  	
                    1        2        3
                Recovered By: _
                     5        6
Silica Gel
Final Wt.
Initial Wt.
Net Weight





















Description of Impinger  Contents:
Silica Gel Color: 	
Filter I.D. No.: 	
Description of Particulate  on  Filter:
Probe Rinse Container I.D.: 	
Impinger Contents Container: 	
                                         Total Moisture =
                                                                       grams
                                         Percent Spent: 	
                                         Filter Container I.D. :
                                                                 Sealed: Y N
                                              Liquid Level Marked/Sealed: Y N
                                              Liquid Level Marked/Sealed: Y N
RUN No.:
                     Recovery Date:
                Recovered By:
Impingers:
Final Wt. '
Initial Wt.
Net Weight
123456 SilicaGel





















 Description of Impinger Contents:
 Silica Gel Color: 	
 Filter I.D. No.:
                                         Total Moisture =
                                                                       grams
                                         Percent Spent: 	
                                         Filter Container  I.D.:
 Description of Particulate on Filter:
 Probe Rinse Container I.D.: 	
 Impinger Contents Container:  	
                                             	 Sealed: Y N
                                              Liquid Level  Marked/Sealed: Y N
                                              Liquid Level  Marked/Sealed: Y N
 BLANKS: Probe rinse:
                                   lapinger:

-------
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
                         In
                                              Pacific Environmental Services, Inc.
                                             ;..   Dry Molecular Weight Determination
 Orsat No.
 Operator
 Comments:
Site Location:
                                                                                  Q-1-
                           Run 1
             0,'
             CO"
                                 Net
                                              Run 2
                                         Actual
                                                    Net
                                                                  Run 3
                                                             Actual
                                                                        Net
                                                                               Average
                                                                                 Net
                                                                               Volume
                                                                                         Multiplier
                                                                                           0.44
                                                                                           0.32
                                                                                           0.28
                                                                                           0.28
                                   Molecular Weight
                                          of
                                    Stack Gas. Md
                                       (Ib/Mole)
                                                                                           Md
Run No.(s)
^

Gas
•
CO,
o,'
CO"
N,'
Run 1
Actual
ft1/
20,6


Net
^
p-.i


Run 2
Actual
Vb
2.t.o


Net
$,&
(14


Run 3
Actual




Net




Average
Net
Volume
%
«K
&%




Multiplier
0.44
. 0.32

0.28
0.28
Molecular Weight
of
Slack Gas. Md
(Ib/Mole)




Md =
Run No.(s)

Gas
•
CO,
o,'
CO"
N,c
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md»
* O, Net Volume is O, actual reading minus CO, actual reading.
* CO Net Volume is CO actual reading minus O, actual reading.
c N, Net Volume is 100 minus CO actual reading.

-------
                                            Pacific Environmental Services. Inc.
                                                Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. 'F
Run No.(s)
v 2/1

Run No.(s)
/VP

Gas
CO,
<6

/&0.0
Net
M
/if

79. >
M I f • °£> > Great No.
Operator:
Comments:
Site Location:
Run 2
Actual
f.Y
^.fc

tM.O
Net
^,V
/?'/

7^2-
Run 3
Actual




Net




£/~ ^*
fi-J&i

S&tU/L/ <£^7

Multiplier
0.44
0.32
0.28
0.28

Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
?,70
^2?

2/f<5?
Md= ^£j?

Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
#^t
£<£/

2/<7b
Md= 2/9 /^*
A~^~''
te.07-
	
Run No.(s)


Gas
•
CO,
Oi§
CO"
N,e
Run 1
Actual




Net




Run 2
Actual




Net




Run3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md-
*O, Net Volume is O, actual reading minus CO, actual reading.




" CO Net Volume is CO actual reading minus O, actual reading.




c N, Net Volume is 100 minus CO actual reading.

-------
                                             Pacific Environmental Services, Inc.
                                                 Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. 'F
 Orsat No.
 Operator:
 Comments:
Site Location:
                                                                                  0-2.
Run No.(s)
\*fr

Gas
•
CO,
o,'
CO"
N,e
Run 1
Actual
16±
tod


Net
1^
11.4-


Run 2
Actual
/fc/
11.4


Net
/
-------
                                            Pacific Environmental Services, Inc.
                                               Dry Molecular Weight Determination
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
Run No.(s)


Run No.(s)
"j^£*^y
L*^ feJPW

Gas
•
CO,



Orsat No.
Operator.
Comments:
Site Location:
Run 2
Actual
1/.1-
V2.0


Net
||,V
'Ml


Run 3
Actual




Net




iJ ~~r~*
P 5tS*-Mj
1 '
////fr »

Average
Net
Volume
in
/A/



Gas
CO,
o,'
CO"
N,«
Rum
Actual
M.ft
Z2-.^


Net
(fij
^.»


Run 2
Actual
w
(/



Multiplier
0.44
0.32
0.28
0.28
9
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md =

Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md =
<\
Run No.(s)


Gas
•
CO,
o,'
CO"
N,C
Run l
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Mi*
* O, Net Volume is Oj actual reading minus CO; actual reading.




" CO Net Voluma is CO actual reading minus Oj actual reading.





-------
Client/Location:
RUN No.:
                        PARTICULATE/ SAMPLE RECOVERY DATA SHEET
Sampling Date(s):

  Recovered By:
Recovery Date:
                6HR.
Impingers:
Final Wt.
Initial Wt.
Net Weight
1234 5 6 Silica Gel
57t, 0
575.6
04
£ff/,Z
6%0,£
0,+
732.2
732.3
0,5
62/.J
621, Z
O.I
743.1
1+5A
0.0
737. £
73 ?. £
0.0
Z29.0
K8.Z
0$
Description of Impinger Contents:
Silica Gel Color:
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:  	
Impinger Contents Container: 	
                                         Total Moisture =
                                                   grams
                    Percent Spent:  	
                    Filter Container I.D.:
                                             Sealed:
                         Liquid Level Marked/Sealed:
                         Liquid Level Marked/Sealed:YN
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt.
Initial Wt.
Net Weight
1234 5 6 Silica Gel





















Description of Impinger Contents:
Silica Gel Color: 	
Filter I.D. No.: 	
Description of Particulate on Filter:
Probe Rinse Container I.D.:  	
Impinger Contents Container: 	
                                          Total Moisture =
                                                   grams
                    Percent Spent: 	
                    Filter Container I.D.:
                                             Sealed:  Y N
                         Liquid Level Marked/Sealed:  Y N
                         Liquid Level Marked/Sealed:  Y N
RUN No.:
Recovery Date:
Recovered By:
Impingers:
Final Wt. '
Initial Wt.
Net Weight
123456 SilicaGel





















Description of Impinger Contents:
Silica Gel Color: 	
Filter I.D. No.:
                                          Total Moisture =
                                                   grams
                     Percent Spent: 	
                     Filter Container I.D.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:  	
Impinger Contents Container: 	
                         	  Sealeefi~Y~N
                         Liquid Level Marked/Sealed: Y N
                         Liquid Level Marked/Sealed: Y N
 BLANKS: Probe rinse:
              lapinger:

-------
   Appendix A.2




  Raw Field Data





-------

Plant:  & F\
Date:
        TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
                                                              r
         - 9./-  17
Samohng Location:
Inside of Par Wall to Outside of Nippie:
Inside of Near Wall to Outsiee of Nipple  *~
                                                dd
                                                                Schematic of
                                                             Santpiing Location
                                                              larnpii
Traverse
Point
Numoer
I
Fracnon
of
Length
, 0\L
^ W^iwS).
3
9
$
c
0
«
1
\
, If*
,1-77
, *ro
,3»J-fe
, t>&
.1*0
i 8±*
^91
. fa
x ^11
Lengtn
(inches)
1^
1




,









\
T3T* 	
f
Proaua of
Columns 2 & 3
(To nearest 1 /8")
US"!
<-D
^^€5
\0,9-
\^.1
7C.T
Vy.3
rQ>.2«.
6J.-7
6c,,i
6R,°|
•73.4,
Nipple
Length
(inches)
4-.?5"









\








.X

Traverse Point
Location
(Sum of Col. 4 & 5)
S".tf
^r,p7
I 3- )
i -7--*
•^3. 0
3o,«)
r^.c
Co.r
GS-.^
^70,4-
7^-4

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                        Project No.
Page
of
                                        Client
                                        Location
 Prepared By       Date   Checked By   Date   Sheet Title

-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: r,M Date: °l"^5 -91
c
f
I
1
c
\
0 «) PCW-*-
£ *<-

"<
.3 c<"
e> —
it, i«^
-T"'
o
^x \
* ^
/C^ £~ *-4^
I £^ £• ^-**
' • I £• ^*|11^'
Sampling Loc
^un#:_id
Barometric P
Moisture, %:
Stack Dimen
/Vet Bulb, °F
Point
Numbar
A /
1
--.3
. V
5
6.
7
g
^
to
11
11

V2> '
2-
7,
V
.5
U
7
fj
^
lO
ll
\1

:ation: ^,,^/< n^-hiA- Clock Time: yz.'?*/
\M^.^c,^J nnnratorS! 7nrf-y(5r,
ressure, in. H
ia: static Pressure, in. HoO: . /"7
Molecularwt , Drv Pitot Tube, Cp: - ^ .
sion, in. Diameter or Sick
: DrvE

Velocity
Haad
in. H2O
,7-j
,^ *y
.?z
,55
^5 2-
« 5^
.^1
.^
. V_5
,V^
•3S
'J,O

3-7
»3^
,V3
,^
'V 7
<$L
-SI
•H$
• ^13
•*{0
55
Oz
^p -
Stack
Tamp.
°F
'Tf
/3Z.
\}/J
*3^/
'11
J35
. i^
/3f
/&
• }?
i U
I3>J

137
'3>?
} bL
i&
•3$
;35
/3?
•35
>&J
t&j
>&3
l?>\
Ta-
J1: -7^ Side 2:
?ulh,°F-
Md - (0.44 x %CO2> + (0.32 X %O2> -t- (0.28 X%^)
Md - (0.44 x ) -t- (0.32 X ) + (0.28 X )
Md-
% H.O % HO
™ 100 100
Ma-
Ta- °F- 0R(°F-..460)
Pa - Pb + S-P' = ( ) + 	
13.8 13-8
Pa - In. Hg
VS? =
— I Ts(°R)
y i s x MO

Va- ft/a
A.- ft2
Qa- VaxAaxMa/m
Qa - x X00
Qa - acfrn
Pa %H,0
08^.= Qa x 17.847 x 	 x (1 • 	 =— )
91U yj 1IM

atd 100
                    O«std~

-------
Plant:	
Sampling Location
Run Number:  TU°|-O| Date:
Pretest Leak Rate: 0.QQ5  cfm
                                         FIELD DA I A SHEET
                                     Sample Type: |/X) •
                                     Pbar:
                                     C02:
                                                            Operator:
                                                        Ps: +\ . \
                                                        02:   10 %
                                                               Nozzle ID: .2 $5 Thermocouple it:
                                                               Assumed Bws: /TJ^ilter #: 3465
                                                               Meter Box *:W15-loY: O^AH®: /.S9/
Pretest Leak Check: Prtot:
                           Orsat:
in. Hg.   Probe Length/Type:
        Stack Diameter:  75
                                               As:
                                                    Post-Test Leak Rate: g:{X>( c^m © _2l 'n-
                                                    Post-Test Leak Check: Pilot:  v^Orsal:  .
    Travaree
     Pobil
    Number
     Sampling
      Time
      (mln)
QockTime
 (24-hour
 dock)
Gas Meter
 Reading
 (Vm)ttS
                                  Velocity
                                 Head (Ap)
                                  inH2O
              Orifice Preuur* Drlfercntiat
                  (AH) in H20
               Desired     Actual
sired "J
7/7//
Stack
Temp.
 (Ts)
  Temperature
     °F
Probe
Filtw
Impinger
 Temp.
  °F
             Dry Gas Meter Temp-
  Inlet
(Tmin0F)
 Outlet
(Tm out°F)
 Pump
Vacuum
fm.Hg)
           O
     2.
       10
           15
                                 -734
               .73^
                                                         ••73
                                           73
                                                     1,0
                                                             50
                                                                                                li
                                                                                                ?
           20
                                                                           24B*
                                                                             43
           30
                    £??»/?
                       L36.
                                                                               Zto
                                                      4.
                                       2S2*
                                                                232
                                                                                    '
           35
                                 0,51
                                 i,53
                                                      ^5/?a
                                            i.
                                                                        260
                       1.98
                                                                                Zrs*
                                                                                                7?
                                                                                            5"
           50
           55
                                 0,63
                                                                256
                                                                                        •101
                                                                               255°
                                                                                                       5''
                        304,^8
                                            LB6
                                                                Z54*
      8
      70
                       L:
                                                                ^5-5-°
           75
                                             ,&(>
                                                                                               ''
      O
           35
                         3m 7 36
                                                   •  l.t,
                      i.
                                            18
                                                   :te
                                                                                         73
                                                                                     ?
                                                        252.
                                                          1. 8
                                                                                          82°
                                                                                  5"
                                                                                                              "
                        3380^
                                 0.2S
                               ^2i
14:4^  iWcktoM
                                 ^/
                                 -  zm" m.  /,gy   is. /«s"

-------
                                                                                                        .  I ,  r  2,
:: Grt
Plant:
Sampling Location CpHpalfr 4B
Run Number: rTU°K?-2^ Date:
Pretest Leak Rate: ,002    cfm (
                                             FIELD DA I A SHEET

                                        Sample Type:  W\ %tf Operator:
                                        Pbar
                                                                                                       'J
                                     C02: J!_%_02:_LQ_7b
                            i|"in. Hg.    Probe LengttVType: *7 '$
                                        Nozzle ID:0.?55 Thermocouple
                                        Assumed Bws: /7^Rlter #
                                        Meter Box #:^s-to Y: ^11
Pretest Leak Check: Pitot:OK , Orsat: 6,
Stack Diameter:   15'    As:
                                                                   #: £•? -Z  Post-Test Leak Rate: .flpf  cfm @ ^ 'In. Hg.
                                                                             Post-Test Leak Check: Pitot: Q^
-------
                                                                        Page   2-   of
Plant Name:
Run Number:

                                                  Test Date:
                                                  Operator:
Traverse
 Point
Number
Sampling  /dock Time
 Time,  / (24 hour
 fmin.)  /  clock)
               Gas Meier
                Reading
 Velocity
llead^P.)
 iiLlhO
Orifke Pres. Differential
   (£ll)in.U2O
                              Desired
         Actual
 Slack
Temp. • F
  Probe
Temp./ Filter
 Temp* F
Impingcr
 Temp.
 •F
Dry Oas Meter Temp.
                                         Inlet
         UUIICI
 Pump
Vacuum
 IlLllg
        13.0   '
                \
                         0.30
                              (9.81
                fl
                13-3
                                   07
  2,
 130  '
                                              1315'
                                                        9?
                        23/20
                                               /31'
                                                                               -78
                                                                                                  "
                                                                                                3
                                                                                           'r
                                                     133
                      436,21
                                        hJ
                                             132
  b
                         0,47
                                       1,3
                                                        s
                      W5A
                                               L32'
        no
                         0.4
                               ,323
                ,3
                I3/
                   14
        17 r
                                                                         r-
  7
        iSS   '
                 57,
                        OS'l
        1,377
  8
       /
                60,66
        1,3??
        MS   /
                         OAl
                                                                                         *
        £60  /
                                                                                as73
        205  /
                                 ,617
                                                               42
                                                        83°
                                                           "
        210
                                                                                        5'
                                              1.6
                                                                 •fz
  N
 22P  /
                                              Jii
                                               Ml
                                                   2sz_
                               Oil
                                       IiZ.
2-36  /  \^
                               <£>«?/
                                1.1*7
                                               TSft
                      ^5.876


-------
'^\Ql t^lCtoQ
      f~* W\  O
Plant:  Uf. I  l> O
Sampling Location ^egpaN
Run Number: 0 - rVtt^ - 3  Date:
                                             FIELD DA IA SHEET
                                                                      A  I
                                         Sample Type:  ^^9  Operator: Mot/one.
                                         Pbar. ^Qt)O   Ps:   D-35	
                                         C02:    l|%   02:   [O%	
Pretest Leak Rate:. QQ2-  cfm @ ID "in. Hg.
Pretest Leak Check: Pilot: o^. Orsat: (9,«i
                                         Probe LengbVType:
                                         Stack Diameter:   75"
                                                    Pitot #: P-7'4
                                                 As:
                                                                                       Nozzle ID:^rQ^fflermocoup»e #: DloO-7
                                                                                       Assumed Bws: fo% Fdter #:
                                                                                       Meter Box #: W-IO Y: -W
                                                                                       Post-Test Leak Rate: >G&Z. cfm @/J_ in. Hg.
                                                                                       Post-Test Leak Check: Pitot: Q.'/t .Great:
0

-------
                                              FIELD DA I A SHEET
Plant:	
Sampling Location
Run NumberO-
Data: Cf-26~cl'7
 cfm @ [\ _ in. Hg.
Sample Type:
Pbar: £.4 JO   Ps:
C02:
                                        Operator:
                                          Q »35
11%  O2:    ( O%>
                                                                                  Nozzle ID: - 3 1 Q  Thermocouple »
                                                                                  Assumed Bws: (£^fiHer #:
                                                                                  Meter Box *: n5 - K3 Y:
Pretest Leak Rate:
Pretest Leak Check: Pilot: O.K, Orsat:  O.
Probe Length/Type: *J ^
Stack Diameter:
                  Ptot #: k-
                                           As:
                          H@:  /« 5i
Post-Test Leak Rate: 6MOZ cfm @ j/^in. Hg.

-------
                      PARTICULATE/SAMPLE RECOVERY DATA SHEET
Client/Location: r £3[ V^\ ~jn
-------
Client/Location
RUN
            PARTICULATE/SAMPLE RECOVERY DATA SHEET


iQn;  feS/GHrftGMtW     Sampling Date(s):  ^/Z^??

      T*  Recovery Date:
  Impingers:

  Final Wt,

  Initial Wt.

  Net Weight
                                 Recovered By:  _
                                      5         6
                                                                  O/7A
                                                                    Silica Gel
isq.3
                                   IO.B
                                 1.4
I.
                                               /.r
-.3
                                                                    77?. 7
19.5
Description of Impinger Contents:
Silica Gel Color:  	
Filter I.D. No.:	
Description of Particulate  on  Filter:
Probe Rinse Container I.D.: 	
Impinger Contents Container: 	
                                         Total Moisture =   -t-O ni* T
                                                       grams
                         Percent Spent: 	50
                         Filter Container  I.D.: 	
                             	  Sealed: Y  N
                              Liquid Level Harked/Sealed: Y  N
                              Liquid Level Marked/Sealed: Y  N
RUN No.:
     Recovery Date:
                                                  Recovered By:
Impingers:
Final Wt.
Initial Wt.
Net Weight
123456 Silica Gel





















Description of Impinger Contents:
Silica Gel Color: 	
Filter I.D. No.:
Description of Particulate on Filter:
Probe Rinse Container I.D.:  	
Impinger Contents Container: 	
                                          Total Moisture =
                         Percent Spent:  	
                         Filter Container I.D.:
                                                        grams
                             	  Sealed:  Y N
                              Liquid Level Marked/Sealed:  Y N
                              Liquid Level Marked/Sealed:  Y N
RUN No.:
     Recovery Date:
                                                  Recovered By:
Impingers:
Final Wt. '
Initial Wt.
Net Weight
123456 SilicaGel





















Description of Impinger Contents:
Silica Gel Color: 	
Filter I.D. No.:
                                          Total Moisture =
                         Percent Spent:  	
                         Filter Container I.D.:
                                                        grams
Description of Particulate on Filter:
Probe Rinse Container I.D.:  	
Impinger Contents Container: 	
                              	  Sealed:  Y N
                              Liquid Level Marked/Sealed:  Y N
                              Liquid Level Marked/Sealed:  Y N
 BLANKS: Probe rinse:
                  Iipinger:

-------
Client/Project:

Date/Time:

Sample Type:

Ambient Temp. °F
Pacific Environmental Services, Inc.

   Dry Molecular Weight Determination

                  Orsat No.      	

                  Operator      	

                 Comments:     	

                Site Location:      /
Run No.(s)    Gas
                          Run 1
                     Actual
            CO,
            CO"
                    /C7V.0
                                Net
                                             Run 2
                                        Actual
                                        to
                                      -2XB
                                                   Net
                                                                Run3
                                                           Actual
                                                                      Net
                                                                              Average
                                                                                Net
                                                                              Volume
                                                                                       Multiplier
                                             0.44
                                                                                         0.32
                                                                                         0.28
                                                                                         0.28
                                                   Molecular Weight
                                                          of
                                                    Stack Gas. Md
                                                       (Ib/Mole)
                                                                                         Md
Run No.(s)


°»
CO,
o,'
CO"
N,'
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md =
Run No.(s)


Gas
•
CO,
o,'
CO"
N,'
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md>
' Oj Net Volume is O, actual reading minus CO, actual reading.

" CO Net Volume is CO actual reading minus O, actual reading.

0 N, Net Volume is 100 minus CO actual reading.
                                                                                                                              -I—

-------
                                          Pacific Environmental Services, Inc.

                                             Dry Molecular Weight Determination
Client/Project:

Date/Time:

Sample Type:

Ambient Temp. 'F
             -70   '
                                                          Orsat No.

                                                          Operator:

                                                          Comments:

                                                         Site Location:
Run No.(s)
*<«

mm
CO,
o,'
CO"
N,e
Run 1
Actual
toj
22.Y

/«
IZ.O

77.7

Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)
vC^?
3,%0,1>   772
                                           Run 2
                                      Actual
/o.fc
                                                Net
                                                            Run 3
                                                        Actual
                                                                  Net
                                                             Average
                                                               Net
                                                             Volume
                                                                        "777
                                                                                  Multiplier
                                                                                    0.44
                                               0.32
                                                                       0.28
                                                                                    0.28
                                                     Molecular Weight
                                                           of
                                                      Stack Gas. Md
                                                         (Ib/Mole)
                                                                                   Md
* O, Net Volume is O, actual reading minus CO, actual reading.

0 CO Net Volume is CO actual reading minus O, actual reading.

c N, Net Volume is 100 minus CO actual reading.
                                                                                2-
                                                                                                                    5  /0-Gr

-------
                                            Pacific Environmental Services. Inc.
Client/Project:
Date/Time:
Sample Type:
Ambient Temp. °F
                        7*
Dry Molecular Weight Determination
               Orsat No.      	
               Operator.      __
              Comments:
             Site Location:
                         Run 1
                            77 /
                                            Run 2
                                       Actual      Net
                                                               Run 3
                                                           Actual
                                                                      Net
                                                                             Average
                                                                                Net
                                                                              Volume
                                                                                      Multiplier
                                                                                        0.44
                                                                                        0.32
                                                                                        0.28
                                                                                         0.28
                                                Molecular Weight
                                                      of
                                                 Stack Gas. Md
                                                    (IWMols)
Run No.(s)

Gas
CO,
o/
CO"
N,e
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md =
Run No.(s)

Gas
•
CO,
o,'
CO"
N,'
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md*
• Oj Net Volume is O, actual reading minus CO, actual reading.
" CO Net Volume is CO actual reading minus O, actual reading.
' N, Net Volume is 100 minus CO actual reading.
                                                                                                                  0'
                                                                                                                  fa^
                                                                                                                   W?

-------
                                            Pacific Environmental Services, Inc.

                                                Dry Molecular Weight Determination
Client/Project:

Date/Time:

Sample Type:

Ambient Temp. °F
                               Orsat No.

                               Operator

                              Comments:

                              Site Location:
Run No.(s)|   Gas
                          Run 1
             CO,
             0,'
             CO"
             N,c
                                Net
u
 A
                                             Run 2
                                        Actual
                                                  Net
                 WA
                                                               Run 3
                                                           Actual
                                                                     Net
                                              Average
                                                Net
                                              Volume
                                                                                      Multiplier
0.44
0.32
                                                         0.28
0.28
       Molecular Weight
             of
        Stack Gas. Md
          (Ib/Mole)
                                                                                              11. 83
                                                                                        Md
Run No.(s)    Gas
                          Run 1
                     Actual
             CO,
             0,'
             CO"
             N,c
                                Net
                                             Run 2
                                        Actual
         17
                                                  Net
                                                               Run 3
                                                           Actual
                                                                     Net
                                              Average
                                                Net
                                              Volume
                                                                                      Multiplier
                                                                                        0.44
                                                         0.32
                                                                                        0.28
                                                         0.28
       Molecular Weight
             of
        Stack Gas. Md
          (Ib/Mole)
       -L/-7E
                                                                                       Md
                                                                70,
Run No.(s)


Gas
•
CO,

-------
Client/Project:

Date/Time:

Sample Type:

Ambient Temp. °F
'PA
                                             Pacific Environmental Services, Inc.

                                                Dry Molecular Weight Determination
10
          / MM
          '
 Orsat No.

 Operator.

 Comments:

Site Location:
                          Run 1
                                Net
                                             Run 2
                                        Actual
                                                   Net
                                                                 Run 3
                                                            Actual
                                                                       Net
                                                     Average
                                                       Net
                                                     Volume
                                                                                        Multiplier
                                                                                         0.44
                                                                          Molecular Weight
                                                                                of
                                                                           Stack Gas. Md
                                                                             (Ib/Mole)
                                                                                         0.32
                                                                                         0.28
                                                                                         0.28
 Run No.(s)
 Run 1
                                Net
                     Run 2
                                        Actual
                                        10-
                                                   Net
                                        Run 3
                                                            Actual
                                                                       Net
                                                        Average
                                                          Net
                                                        Volume
                                                                                        Multiplier
                                                                0.44
                                   Molecular Weight
                                         o»
                                    Stack Gas. Md
                                      (Ib/Mole)
             0,'
                                                                0.32
             CO"
                                                                0.28
              N,'
                                                                0.28
                                                                                         Md
                          Run 1
                                Net
                                              Run 2
                                        Actual
                                       10-*)
                                                    Net
                                                                 Run3
                                                            Actual
                                                                       Net
                                                     Average
                                                       Net
                                                     Volume
                                                                                        Multiplier
                                                                0.44
                                                                          Molecular Weight
                                                                                of
                                                                           Stack Gas. Md
                                                                             (Ib/Mole)
                                                                                         0.32
                                                                                         0.28
                                                                                         0.28
                                                                                         Md
' O, Net Volume is 0, actual reading minus CO, actual reading.

" CO Net Volume is CO actual reading minus O, actual reading.

c N2 Net Volume is 100 minus CO actual reading.

-------
Client/Project:
Date/Time:

Sample Type:

Ambient Temp. °F
Pacific Environmental Services, Inc.

   Dry Molecular Weight Determination

                  Orsat No.
                  Operator:

                  Comments:

                 Site Location:
                           Run 1
                                 Net
                                              Run 2
                                         Actual
                                                    Net
                                                                  Run 3
                                                             Actual
                                                                        Net
                                  Average
                                    Net
                                  Volume
                                                                                         Multiplier
                                                                                           0.44
                                                                                           0.32
                                                                                           0.28
                                                                                           0.28
Molecular Weight
      of
 Stack Gas. Md
    (Ib/Mole)
                                                                                           Md
Run No.(s)


Gas
•
CO,
o,'
CO"
N,e
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mols)




Md =
Run No.(s)

Gas
•
CO,
o,*
CO"
N,«
Run 1
Actual




Net




Run 2
Actual




Net




Run 3
Actual




Net




Average
Net
Volume
%





Multiplier
0.44
0.32
0.28
0.28
Molecular Weight
of
Stack Gas. Md
(Ib/Mole)




Md-
*O, Net Volume is O, actual reading minus CO, actual reading.

" CO Net Volume  is CO actual reading minus O, actual reading.

* N, Net Volume is 100 minus CO actual reading.

-------
               Gn
Plant
      Sampling Location
-—t^Run Number: fe  V*     Date:
                                              FIELD DA IA SHEET
                                         Sample Type: jfV3_2l__ Operator:
                                         Pbar 9*)."? 4-   Ps:   J-  \. t
                                         C02:     ~     O2: l,Q
                                                                                Nozzle ID: .2*3. Thermocouple #:
                                                                                Assumed Bws: ) 1 Filter #:  )*i  ?^-
                                                                                Meter Box #: g*.6>», Y: \.0lo
 Pretest Leak Rate:  »0o>  cfm @ \J in. Hg.
 Pretest Leak Check: Pilot:  (/ Orsat: V>> A
                                         Probe Length/Type:
                                         Stack Diameter:  "1
                                                                  Pilot #:
                                                              As:
                                                                                       Post-Test Leak Rate: ,Q0 3  cfrn @ j£_ in. Hg.
                                                                                       Post-Test Leak Check: Pilot:  ^ Orsat:
Traverse
 Point
Number
    Sampling
     Time
     (mln)
                   (24-hour
                    dock)
                       Gas Meter
                        Reading
                         (Vm)tt3
 Velocity
Head (Ap)
 'inH2O
Orifice Pressure Differential
    (AH) in H2O
 Desired
Actual
Stack
Temp.
 (Ts)
                   Temperature
                      °F
Probe
Filter
tmptnger
 Temp.
  °F
                                                                                                       Dry Gas Meter Temp.
  Inlet
(Tmin°F)
  Outlet
(Tmout°F)
 Pump
Vacuum
(in.Hg)
                                 y//////////////y//////////////////////^^^
        O
                                                 \.o
                                                         1.0
                                                                                                        is
       IS
                                                            .01 t
                                                                                         feJ.
                                                L 0
                                                                                                        Sfi
                                                                                                                       S
                                                  \. 1
                       \\o-
                                                                         "Mb
                                                                                                                 7-7
_t
       10
                                                                                                JL
                                                                                                   $7
                                                                                                               S
       40
            3:55
                                                                                 1JJ
                                                                                   Wo
              ^00
                                                                                                                A
                                                                                                                  (a
                                                                 114-
                                                                                                   SI
      -o
                                     i IS
                                                    (ob
                                                                                                               _r
       "I/
                                                                                        •n
                                                                                                                 r /
       to
                                                            a I
   \0
                                                         sS
                                                                        \IC,
                                                                                                                  £L
       voo
       VOJ
                       \ ^-
   \r
               \1

-------
09/09/97   10:19    ©19199410234
PES RTF NC
©003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: C-aJi( - Sb4C^mMk)
Sample Date: QJZ?)^
Sample Location: B> &v~crdL
Recovery Date: n|^ 1 ' ^

Filter No.fs): *S^-t3-«
r\ / _rx^£-u.ftfte^ ( MTtfr
Run No.: 50> -25- 1
JobNo.:SHM.il3

XAD-2 Trap No.(s): ST 0 - £3 ~
Sample Recovery Person: K^~|£)E_

1
Impingers XAD-2 (knockout)
Trap
Final wt. — (^(o-3
Initial wt. — 4^,4-
Netwt. ~~ /5V- 6
2 3
(100mlH2O) (100mlH2O) (ki
(untipped) (tipped) (u
70^3 >/?.3 <
"7.03,^ ^iT-,1^ 5
• *A3 -a.ro
4
lockout) Silica gel
ntipped) (untipped)
5f5W ggO.-^ g
f y O Z^Mf^TA : g
/.^ 8^-^ • g

Train System: E^PPl fAsVfte
A Z3 /l>ox ^24 / TOTAL: A/.?
Probe: 1 hb?*> / CJter
Filter: Color - (Jret, / T,\n
Loading- (H^:^
Filter Container No. S^ " t-
XAD Module Container No.: ^
3V
"o - Z3V
Probe (FH) & Back Half Rinse (Acetone) Container No.: -2 3 -/
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.
It ut-f\4
Impinqer Rinse (Acetone/l\d«St2)
: S.-ZJ'/
Container No.:

marked/sealed:
marked/sealed: <-^
Liquid level
marked/sealed: ^/
Liquid level
marked/sealed: ^*<^
Liquid level
marked/sealed:
Liquid level \/
marked/sealed: ^



-------
                                                      FIELD DA I A SHEET
                                                                                                         V
Plant: Cot<\ 9j «=>
Sampling Location
Run Numberf) VV>
^-s\V
^fo
>rv
'N'V
Ob-
Date:

x*f
a-^<\-^'
Sample
Pbar:_2
) C02:
Type: V

<1
\^^J
Ps:
02:
Operator
-T"l,
i?

i

OA


Pretest Leak Rate: -003-  cfm @ j£ in. Hg.
Pretest Leak Check: Pilot: J/_ Orsat: rQ*
Probe Length/Type: _gj_
Stack Diameter:
                                                                            Pilot #: 9 <-
                                                                         As:
                                                                           Nozzle ID:  . IS 3-  Thermocouple »:
                                                                          AssumedBws:HFilter#:
                                                                          Meter Box #:
                                                                           Post-Test Leak Rate: $>-
                                                                                           ->-s>-
                                                                                          -W-
                                                                                                 If
-3-
 Jlfe
                                                                                                          95"
                                                                                                    (bo
                                                                                                                   63
                                                                  65
                                                                                                                  t-7
                                                                                                   e-7
                                                                                                                  70
                                                                                                          U
                                                                                                         •is
                                                                                                         jza
                                                                                                               JT
                                                                         fa
                                                                                                          JT
                                                                                                                               *•/

-------
                                                                             Page
                                                                                      of
Plant Name:

Run Number:   .
     b          \W1
                                                      Test Date:  _.
                                                  .   Operator:  _
                                                   \Vi
                                                                              f
Traverse
 Point
Number
Sampling /dock Time
 Time,  / (24-hour
 (min.) /   dock)
Gas Meier
 Reading
 Velocity
llead^P.)
 in-lhO
Orifice Pres. Differential
    (AH)in.H20
                Desired
         Actual
 Stack
Temp. • F
   Probe
Temp./ Filter
 Temp" F
Impinger
 Temp.
  •F
Dry Gas Meter Temp.
                                             net
                                     UUIICt
 Pump
Vacuum
 In.llg
       YK
          \\ii-
         .a
                                                                                                JT
                                          \,0
                                           l.o
                                            l.o
                                                                                                      jr
                  \-X\-L
                                                                           Sy
                                                                                              7*
         \<<>
           \1J-a
           4-0
         \,
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                                          is
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                                                                                        er
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                                                                                                     JO
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                       305.
                                   v>
                                                          \1>V
                                                          /^

-------
09/09/97   10:19    ©19199410234
PES RTF NC
©003
/
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: (^
A/I s^~~>
iYl-s.AC/j0.^a)
Sample Date: QlZ'JnJ-

Filter No.(s): S6-Z3-2,
Run No.: *So-*3-2
Job No.: ^5«/A/. ^^3
Sample Location: Y) i^MDita ^—^cr^D^f Ot. | ^CXo-H
~K)O i -5 ~3\5(0, u
- • »H o. z.
4
1 (knockout) Silica gel
(untipped) (untipped)
(^t>5v 6 8^&.?- 9
UjO^.2. ^>*y*D g
O £ ^ * 1 ••• M
^** 1& ^ v» / 9
Shl^SiliraiS^l^ll^iiS^
ii z^ / fe^ IB- M-5
/T^~r/)U If Li. L
Probe: ^' ^\0^>
Filter: Color- TAU
Loading - n&Au »v>

Impinger Contents: CJ<2ar-
Silica Gel:
@Grams Used - ^fx:
D Color - U . h^ % Spent - (^ b
Condensate Observed In Front Half: MO -^ >?^/3
Container No.:

marked/sealed: <-^
marked/sealed: ^
Liquid level ,
?>'^ marked/sealed: <:-^
Liquid level
marked/sealed: k<"
Liquid level
marked/sealed: <• — "
Liquid level ^
marked/sealed: N


-------
Plant:   V-, V\
Sampling Location
Run Number:
                                              FIELD DA IA SHEET
                                                           	Operator:  (j
Pretest Leak Rate: .
                      Date:
                       cfm
                                        Sample Type:
                                        Pbar:
                                        CO2:
                            Ps:.
                            O2:
                                                                  1.1
\S jn. Hg.    Probe Length/Type:
 Pretest Leak Check: Pitot:  i/ Orsat:
                                        Stack Diameter:  IS
                                                      Pitot #:
                                                   As:   3p. Gfe
                                                                    Nozzle ID:  atfQ. Thermocouple #: jT£
                                                                    Assumed Bws: jfe Filter #:   £oa> 3
                                                                                    Y: I 0/fr AH@:
                                            Meter Box #:
                                            Post-Test Leak Rate: . Q|CJ  cfm
                                                    Post-Test Leak Check: Phot:
                                                                    tXO
                                                                                                               in. Hg.
                                                                                                             rsat:
Traverse
 Point
Number
     Sampling
      Time
      (mln)
dock Time
 (24-hour
 dock)
                       Gas Meter
                        Reading
                        (Vm)ft3
 Velocity
Head (Ap)
 inH20
                  Orifice Pressure Dittertntia)
                       (AH) in H2O
                    Desired
Actual
Stack
Temp.
 (Ts)
                  Temperature
                      °F
Probe
Filter
               Impinger
               Temp.
              Dry Gas Meter Temp.
  Inlet
(Tm in°F)
  Outet
(Tm out°F)
 Pump
Vacuum
On. Hg)
                                   y////////////////////////////////////////////////////////////,
                                                           Kft
                                                                  los
                                                                                                          6-S
                                                                                                     JT
              I? « 4-
                                                                                        se,
       \5
                                                          •Z.-7
                                                                               TO
                                                                                                    to
                                                                   110
                                                                                                  7V
                                                                                             77
                                        45
                                                                   no
                                                               Wo
                                                         _3jL
                                                      IQ^
                                                                          7-Sp
                                                                                        ro
                                                                                                           7o
                                                                                                                   Z.
                                         1-1
                                                1.4.
                                             3.4-
                                                                  In 7
                               rj
                                                                      71
                                                                                     l-r
                                                                   /07
                                                                          w/
                                                                                                      S
       55
                                                          3,4
                                                      IcO
                                                                             2-
                                                                     7)
       (bo
                                                                                                                  LT
                                                                                         TJ-
                                                                                         rs  JT
                                                                                               •  V*-
                                                                                                          *?/-
                                                                                                     LS
                                                  1.2,

                       1.7X
                                                                                                                 /r
                                         fS
                                                                                            j-f
                                                             , .3
                                                                                                                 /r
   VO
             \0\q
                                                                                         -SV
   \\
                                                                                                                  f S"
                                                                  IQQI
                                                                                            57
                                                                                                 9$
                                                                                             76
                                                                   \VO
                                                                   VQI
                                                                          af7

-------
Plant Name:
Run Number:
                                                                               Page

                                                              Test Date:	ft
                                                              Operator:        C^c*
                                                                                                of
                                                                                                          Pump
                                                                                                         Vacuum
                                                                                                          IlLllg
Traverse
 Point
Number
Sampling /dock Time
 Time,  /  (24-hour
 (min.) /   clock)
                             Gas Meier
                              Reading
          Velocity
          llead^P,)
          in. IhO
Orifice Pres. Differential
    (All) In. 11,0
                                              Desired
          Actual
 Slack
Temp. • F
  m
   Probe
Temp./ Filter
 Temp* F
Impinger
 Temp.
  •F
Dry Gas Meier Temp.
Inlet
          UUIICI
         o
                                           1,0
&
                                           'i.O
                                                           I ID
                                                                                          7-7
*
                                                           f/D
                                                                             fe/
                                                                                          71
                                                           \01
                                                                             70
                                                                                          17
                                                                                                             /J-
         \
                         4*9,1
                                                   -3-0
                                                           2 53 /
                                                                                 6V
                                           3.3
                                                   3,3
         \5°   '  MM
                                           3,3
                                                            lD
                                                                                                         If
                                                                                                         14-
                                                    2.4-
                                                           i
                                    v SO
                                                                 o-ft.
                                                           HO
                                                                       Ml
                                                                                ***
                                                                                                 40
                                                                                                   L5"
                                           3.5
                                                           II
                                                           \lo
                                                          \l A
                                                                                                         /6
                                                          hi
                                                          \\
                                           V.I
                                                           ll 2)
    IU
                                                                                                           tt
                                                                                                         f o
    n
                                                                                        10
                  \\\
                                                                                                          ,\
    \r-

-------
09/09/97   10:19    ®19199410234
PES RTF NC
@003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: ^Af — ^A&IVA
Sample Date: ^/to/^^-
u/
Filter No.(s): l3T)~2£-3
Run No.: SO -.2V =i
Job No.: SHH . 6b?>
/*""} x1* 	
Sample Location: *j C>^p©(a j^cru/lob^y— *Ovc*t,ET"~
Recovery Date: ' 9 /£$ / f ^
XAD-2 Trap No.(s): S»& - i3'3
Sample Recovery Person: M^- 1 v3>E-
siig^^
Impingers
Final wt.
Initial wt.
Netwt.
i'ggg^g
1
XAD-2 (knockout)
Trap
— 8>5»C>
"^ ^TSTo?
3^-^
2 3
(100mlH20) (100mlH20)
(untipped) (tipped)
l»^.0 7-/V. ^
"^Q-^. ^ ^l^.ly
- /A . 5" -* 3"* V
r.r£1r£^lri'2i'Hwi^i^'.->-":^':;i;s^»;'-rf;;;'v]^?&>w-,''
..;. i: -Vv%^;i;«-^yi^H^^'^*OSii^:3KXi^y;i,
•...."— . -• .•...••l-'_-.Tr«i ':• ••• •^'-•••^-.^ -.'Oi- .»^. ••'•-. .,".'?;CV';— «^c
4
(knockout) Silica gel
(untipped) (untipped)
* * \s^^ *j y
S*fcr.< Q£0*3> g
>. 2 ^?.z. g
f|S^^^J;!|^^":|i|g^
J;..l..^;.•:^f:^^.A:v.:^i•::•:^^.-^V^^:fy•^;'^•v:^x-•^.•".^;.^l>-.^•^.WSi?.V•J.HIWW•.•^.™;,-^^^
Train System: E?/X (^e^u
) 9 ^ / ^D si I ts ' AJ - <
«L X- P / 1 JO' ?v 1 1 3 • r N .3
h~ferAu: Wbrt
Probe: Cxi ^£v*~
Filter: Color- "T^^
Loading- N€cl^
^
Impinger Contents: C \-eat
Silica' Gel:
@GramsUsed- 3o6 Color- jlf. I?/A# % Spent- U6
Condensate Observed In Front Half JUndB
»;:•::•:•:• ;i™-:'.-,'i-:-.:i:'i:-.r«S','>-t,-;., i:/.^v-;i.v*.vv^Vi:-K'.;£."™^^«iV^i'v:JA^
Filter Container No. fSo - ^- 3 - 3
XAD Module Container No.: So ~ 2. ;>•"./
Probe (FH)
Probe (FH)
& Back Half Rinse (Acetone) Container No.:
& Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.
Impinger Rinse (Acetone/MfSSSj
£-2-3-3
Container No.:

marked/sealed:
marked/sealed:
-i _ j Liquid level ,
marked/sealed:
Liquid level
marked/sealed:
Liquid level ^
marked/sealed:
Liquid level
marked/sealed:






-------
Plant:
Sampling Location
Run Number:
                        Date:
 Pretest Leak Rate: vOoS   c(m @ \£_ In. Hg.
 Pretest Leak Check: Pilot:  J  Orsat:
                                                   FIELD DA IA SHEET
                   Sample Type:  X*\'V2?   Operator:
                   Pbar:  ^A.N      Pa:    T 19 3
                   C02:      ID     O2:       | ~L,
                   Probe Length/Type: "g1'
                   Stack Diameter:    ~\ 6
                                                                           Nozzle ID:
                                                                                                           Thermocouple
                                                                           Assumed Bws:  \p  Filler f :
                                                                           Meter Box
                                                            PHot #: ye,
                                                        As:
                                                                                        Post-Test Leak Rate: «Q£>;I ofm @ j^ In. Hg.
                                                                                        Post-Test Leak Check: PHot: J^jDrsat: /»
Traverse
 Pbbit
Number
      Sampling
       Time
       (mln)
Qock Time
 (24-hour
  dock)
Gas Meter
 Reading
 Velocity
Head (Ap)
 inH2O
Oiice Piessui* DrftBrenhaJ
     (AH) In H20
Desired   I   Actual
Stack
Temp.
 (Ts)
                               Tempeiature
                                   °F
                                                        Probei
                                        Rlet
Impinger
 Temp.
  °F
 Dry Gaa Meter Temp.
  Inlet
(Tmin0F)
  Outtel
(Tmout°F)
 Pump
Vacuum
On.Hg)
   4-
        5
        \o
        Ins
                                                       3.1
                                                       3.1
                                                                 3,-z.
                                                                         11-2-
                                                                         n
                                                                         U 1
                                                                                  15-7
                                                                                                            flfl
                                                                                                  to
                                                                                                 Co G,7
                                                                                    Co 60
                                                                                    60
                                                                                    feo
                                                                                   13
                                                                                                   )o
                                                                                                               a
   1
                       Til-
                                                                                                  60
                                             40.
                                                                  3.
                                                       3.5
                                                                                                            13L
   VO
         QO
                         CoKJ
                                                      0..-J
                                                                2.4-
                                                                •2-.
                                                                                                                            I  |
   \\
                         t, T,
-------
                                                                                                     of
       Plant Name:
       Run Number:
                V>
                                    Test Date:
                                    Operator:
                                                                              irv--<
       Traverse
        Point
       Number
Sampling /dock Time
 Time.  / (24-hour
 (min.) /   clock)
Gas Meter
 Reading
Velocity
Orifke Pres. Diffeieotial
                Desired
                Actual
 Stack
Temp. • F
  m
   Probe
Temp./ Filler
 Temp." F
Impinger
 Temp.
Dry Gas Meter Temp.
                                                   Inlet
                                                            UullCI
 Pump
Vacuum
 liullg
                 0
           z
                                   'b. V
                                          <<*•&
                                                                                                  14-
                                          , 4-0
                                            3.3
                                 toy
                              213  /
                                                                U
                Uo
                                    3,-f
                                 ( OV
                                                                            /
                                                                 toy
                                  _£JL
                                                                                  O
                                                                                                It
                                                                                                               f-
                                                 3,
                                            1). 3
                                 1 /t?
                                         60  6)
                                              qf-
                                                          Sf-
                                                    o-
                                       3-5$,  '
                                                                                   61
                                                                                93
                                                                 f 07
                                                                        £&
               \qS
                                                   IDl
                                                      to
                                                              y •>
                                                               14
           \0
                              4-0
                                             S
                                   1.1
                                 loyj
                                         60 JY
                                                           - 1
                                                                     Oi
                                                                               li
                                                                len
*">
                                                \\
                                                                     &i
                                                             If-
                                                                     H.
                        -Ms
                                                                              Ak
                                                                       JLL
                                                                     Ik

-------
09/09/97   10:19
                ©19199410234
                                      PES RTF NC
                  METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant:
       :    C?M -
                         jOAW
Sample Date:
                                Filter No.(s): Sb-
   Sample Location:
                       r.
   Recovery Date:  °( \fi\ °i\    |XAD-2 Trap No.(s):   SO- 25"
   Sample Recovery Person:
    ^;?"'vv:^*'':-;-"'i'v'~£'^??'^^~^':yi:;K^
   ^gr-^Sr?^^
   Impingers
          XAD-2
            Trap
                       1
                   (knockout)
(100 ml H20)
 (untipped)
(100mlH2O)
  (tipped)
    4
(knockout)
(untipped)
 Silica gel
(untipped)
   Final wt.
                                                                            _g
   Initial wt.
   Netwt.
                 ^^
                A^^^
                                ^3  /  6fr/  Kj -5  /


                                                                                :?•
   Train System:
   Probe:
   Filter: Color-
                                   Loading -   N\6 D ( UAA^
   Impinger Contents:
Silica Gel:  @Grams Used -
                                   Color-
                                                       % Spent-
   Condensate Observed In Front Half:   M"D
                                                                   g':sr
                                                                   •Wfr-ttS;
                                                                   K!^::
                                                                          *?=ii^p®-
   Filter Container No.
                                                           marked/sealed:
XAD Module Container No.:
                                                             marked/sealed:
   Probe (FH) & Back Half Rinse (Acetone) Container No.: 5o-23-
                                                           Liquid level
                                                           marked/sealed:
   Probe (FH) & Back Half Rinse (Toluene) Container No.:
                                                           Liquid level
                                                           marked/sealed:
   Impinger Contents Container No.:    fv - 2-3 -
                                                           Liquid level
                                                           marked/sealed:
   Impinger Rinse (Acetone/MeCI2) Container No.:
                                                           Liquid level

-------
                                                 FIELD DA IA SHEET
Plant:  ^M
Sampling Location
Run
 Pretest Leak Rate:
 Pretest Leak Check: Pilot:
Dale:  7-23-7-7
 cfm @ IS  in. Hg.
    Orsat:
                                            Sample Type:
                                            Pbar
                                            CO2:
          IV    Ps:
                 02:
Probe Length/Type: 7'
Slack Diameter:
                                                                Operator:
                                                                     /J
                                                                                     Nozzle ID: .
                                                                                          Thermocouple #:
                                                                       Pilot #:
                                                                        Assumed Bws: ,a(.  Filter #:  o^
                                                                        Meter Box #:  /-V   Y: .?66 A
                                                                        Post-Test Leak Rate: ^03^ cfm @ ^_ •"
                                                           75'/'   As:
                                                                                     Post-Test Leak Check: PHot:
                                                                                                     Orsat:
Traverse
 Pobit
Number
      Sampling
       Time
       (mln)
dockTima
 (244iour
 dock)
                         Gas Meter
                         Reading
                                       Velocity
                                       Head (Ap)
                                        inH20
                           Oifice Pressure DHferenlial
                                (AH) in H2O
                                                   Desired
                                       Actual
                            Stack
                            Temp.
                             (Ts)
  Temperature
      °F
Probe
Oter
Impinger
 Temp.
  °F
               Dry Gas Meter Temp.
  Inlet
(Tmin0F)
  Outlet
(Tm out°F)
 Pump
Vacuum
ftn.Hg)
  0
        O
tf/JS
                                             y/////////////^^^^
         /o
                 jjti...
                                                    AY
                                                /
                                                                      ,7.7
                                                                                255?
                                                                                        ,*• 2-
                                                                                                        7?
                                                                                                  77
                                                                                     >>?:*»?%
        20
                                                                                                       •77
                                                                                                  75-
        7-5
                                         Jo
                                                         /2-7
                                                                                        250
                                                                                                                        c
        36
                                                              I.H
                                                                           •2.30
                                                                                                                               SQ,
4-
        35
                           ,  z.
                                       /. 2.
        66
                       67.
                                                              l.t.
                                                    /.S
                                                                  •2.53
                                                                                                                7C
        55
                           . I*
                                                                  z-SC
        60
                                                             AC
                                                                                                                TJ?
                                                                                                                        1
                                                                                                                 ScT
                                                                      til
                        9-1,
                                                   _Zi_6_
                                                            / .
                                                                                                       TS
                                                   /..S
                           . "
 tb
                                                            AJ
A-
                                                                                               Sy
                                                    /. 2.
                                                                                                       0-7

-------
METHOD OOlcJifW SAMPLE RECOVERY DATA
f*
Plant: C^jij- V^f/JAW"
Sample Date: ^ (2? / *? ^
Sample Location: r) O^po
Recovery Date: ^) 1 £l 1 ^ 91

Filter No.(s): _S£> M/115' (
A /<^r,e_uA&^ T)UT^-
XAD-2 Trap No.(s): ^d - /^fc.f
Initial wt. — - M45*2)
!*tef wt «* A  ^'5 (o
7z /. z 7^.2- ^
"::f--r';\-rJ.'^-;:"iJ',l.:.;a;%.-.«iSV'X.p:i>vS~'d /u YW
^f^^ ^-/Aw^M


Impinger Contents: Cj(Qo^
Silica' Gel: ©Grams Used - ^Dt> Color- I4^))1-L^ % Spent- VO
Condensate Observed In Front Half: jU>*J^
••::•:•?::.. f^-c-,»~-G4Z~-7&^
Filter Container No. £o-MM£ -*
XAD Module Container No.: ^
Probe (FH) & Back Half Rinse (Aa
/
-Mf '/
setene) Container No.: fa-hMt /
Probe -(FH) & Back Half Rinse CEofa*ne) Container No.: So-MM^-
Impinger Contents Container No.
Impinger Rinse (Aee*one/MeCI2)
: .^O-AA^-/
Container No.:

marked/sealed: <-/
marked/sealed: LX
Liquid level >•
^ marked/sealed:
Liquid level v
/ marked/sealed:
Liquid level S
marked/sealed:
Liquid level
marked/sealed:



-------
                                                   FIELD DA IA SHEET
    Plant:   £
Sampling Location
Run Number: o-
Pretest Leak Rate:	
Pretest Leak Check: Pilot:
r. 2. Date:  ?-
     cfm
                Sample Type:
                Pbar:  3fr» 8S
                CO2:     °l
                                                                 Operator:
                Ps:
                02:
                                                                         ll
               Nozzle ID: .230
               Assumed Bws:
               Meter Box #:
                        Thermocouple #:  "7<1
                        Filter #:  &—**/»?$'- 2.
                        Y:
   <5_ in. Hg.
Orsat:   —
Probe Length/Type:
Stack Diameter:
                                                                )' 6/eff   Pilot #:
                                                                                                                    :  / '•
                                                                      As:   J0. f» 8
                                                                                       Post-Test Leak Rate:  foQz. cfm @ _?_ in. Hg.
                                                                                       Post-Test Leak Check: Phot:
   Traverse
    Point
   Number
        Sampling
         Time
         (mln)
             aockFime
              (24-hour
              docfc)
       Gas Meter
       Reading
        (Vm)«3
             Velocity
            Head (Ap)
             inH2O
      OriBce Presoure Differential
           (AH) In H2O
        Desired  |   Actual
Stack
Temp.
 (Ts)
  Temperature
     °F
Probe  I   Rltef
Impinger
 Temp.
  °F
Dry Gas Meter Temp.
  Inlet
(Tmin0F)
  Outlet
(Tm out°F)
 Pump
Vacuum
ftn- Hg)
     O
          O
                                            ///////////////////M^^
6
           10
               Wot
           15
                         111 0
                                          .31
                                                  /. V
                                                                                           62,
                                                                                           J^_
                                                                                            ^
           2-6
                         /2Z,
           2=5
                                                                                                               C-2-
                                                      /. 1
                                                                                 2.41
                                                                /.r
                                                      A -5
                                                              1*5
           (tO
                                                    /. 5"
           •70
                            ?. t-
           75
                                                      /.J
                                                                                                  Cz.
                                                                                                                     t.
                                                      /,
                                                                                               CO
                                                                                           72-
                                                                                                  62L
                                                                                                             70
           arc*
                                                      /. 2.
                                                                                                                7f
           to
                                                              1,2.
     /o
          /GO
                                           31
                                                  1.1
                                          1, <
                                                           ISO
                                           3-?
                                                  A/
                                          /I/
                                                                  .TIL
                                                                     Of
     II
                                          .31
                                                            M
                                                                   ISO
                                                                     00
                                                                   7f
                          ITt.H
                                                              1.1
                                                                                               o-O
     I'A
                n
                                                                                                            79
                                                                                                                        3"
/V-
                                                              ill
          i2>0
                                          •3-*
                                                           iii
                                                                        =  ,33.5

-------
Plant Name:
Run Number:
                                                                        Page

                                                       Test Date:  _JL_*
                                                                                                of
                                                       Operator:     T/t
Traverse
 Point
Number
Sampling / Clock Time
 Time,  / (24-hour
 (min.)  /   clock)
Gas Meier
 Reading
 Velocity
Hcad^P.)
 in. IhO
Orifke Prcj. Differential
    (All) in. 1 1,0
                 Desired
          Actual
 Stack
Temp.«F
  m
   Probe
Temp./ Filler
 Temp." F
Impinger
 Temp.
Dry Oas Meter Temp.
          Inlet
                   UUllCl
 Pump
Vacuum
 likllg
               1  t z 15
                                                                      38
               1 i
                            . 3-7
                 M
                                                                      16
  3
                                                                                J-5
                                                                               S-G
                                    .*!? *
                                            /,£
                                                   O.O
                                              38
                                            93,
                                                                                               7?
                                                                  2V
                                                                     51
                                                                         SY
                                                                                               9-1
               1 £2.30
                                                                                                   7
  6,
                                     35
                                              1
                                                       Co
                                     57
                                                               =h
                                    .si
                                   .  1
                          • 1
                                                   If
                                                                                               P3
                         *"&>
                                   /.I
                         /•I
                                          /•I
                                           /. 7
                                                   CO
        •He,    1  i 5 30
                                           1.
                  ^
                                            i 2
                                                                                               9LT
        2-24.
                 2*7, (
 it
                                            /.c
                                                                     5-7
 IZ.
                                            7-5
                                                   SC
               1   »H(sb


-------
                 METHOD
                                       SAMPLE RECOVERY DATA
 Plant:
                                                              Run
 Sample Date:   Q [ZM Hi-
                                    No. (s):
                                                      - 2
                                                              Job No.:
 Sample Location:
                                                    ^^(ek
Recovery Date:  l
                         >
                                XAD-2 Trap No.(s):
 Sample Recovery Person:
V-V^V^j:^^^
^£g£-^;y&^
Impingers
           XAD-2
             Trap
                    (knockout)
                               (100mlH2O)
                                 (untipped)
(100mlH2O)
   (tipped)
    4
(knockout)
(untipped)
 Silica gel
(untipped)
 Final wt.
 Initial wt.
 Netwt.
    i" »••••*•.•-""'••"*' •«*-*vSj»~is**«* *— —'j***1* ••••*»• V-r-V-c'r':*«'***v^t'^'""7~*''"' 1 SliTAlii..''.'^"*;' •"«.•••.•••*»..•. ., •». .'';««.•-•• /.T***^*^*^".", *:• • > -"•" '"T -"it •;».—,- •••,••••— Vi'-'-^'1'.'.^.' .'•••^•^ "•*V"VtX*i"v*i-" »• ••rik*.'^'Si'XZ'»
    ..;,^^^^^;;^ 5^^;^^,:^ ^^

    •:-i-"Z±r.vA-l?fr..^..*,-M%-J.:;;-*:y*:^
                                                                                  .
 Train System:
 Probe:
Filter: Color-
                                      Loading -

 Impinger Contents:
Silica'Gel:  ©Grams Used -
                                      Color - LA B U<   % Spent -
Condensate Observed In Front Half:
Filter Container No	So - MM ^ " 2—
                                                              marked/sealed:
XAD Module Container No.:
                                  *4/l
-------
 Plant:
 Sampling Location
 Run Number: &O-M.*?- 3  Date:
                                          FIELD DA IA SHEET
                                     Sample Type: AVH S    Operator:  T
                                                                                                      Thermocouple #:  7C
                                     Pbar:   2*7,  I
                                     CO2:     if,
                                                           Ps:  -f- . -7 Z,
                                                           02:      /i
Pretest Leak Rate: JL
Pretest Leak Check: Phot:
                                  in. Hg.    Probe Length/Type: 7' 6f*>j  Phot*:
                           Orsat:
    Slack Diameter:   "~7_T
                                                             As:
                                    Nozzle ID:
                                    Assumed Bws: r/o Filter #:
                                    Meter Box #:  /4   Y: >^^
                                    Post-Test Leak Rate: ,oa^  cfm @ ^/_ in. Hg.
                                    Post-Test Leak Check: PKot: —^"Orsat:  —
Traverse
 Poht
Numbef
Sampling
 Time
 (mln)
                        Gas Meter
                         Reading
 Velocity
Head (Ap)
 inHZO
Oifice Pressure Differential
     (AH) in H20
                                                  Desired
            Actual
Stack
Temp.
 (Ts)
  Temperature
     °F
Probe  I   Filtef
Impinger
 Temp.
  °F
Dry Gas Meter Temp.
 Het
  Outlet
(Tm out°F)
 Pump
Vacuum
(in.Hg)
                                    •  .33
        /•o
        '5
                                                    Z. 5
                                                      2.
                                                                 \\6
                                                                _LLL
                                       2.^6
                                                •2.39
                                                                                      Z-V2
                                                                                        31
                                                                                                 "11
                                                                                                       It
                                                                                                              6  "I
                                                                                                                        7
                                                                      J2_
                                                                      1
  3
                     5 3
                                         .37
                                                                      ILL
                                                       3.0
                                         . --V7
                                             -bo
             6 "? 24
                                                                                        o
                                                                                                       "7.5
                                                                                                 7 s
                                        ,41-
                                                                                        CO
                                                    3,1
                                                                                                "76
                                                                                                                       /o
                                                             3-.
                                                                                        C2.
                                                                                              (•I
                                        .35
                                                       *••
                                                                M
                                                                                             do
                                                                                 9
                                                    2.9
       -\5
                                   35
                                                   \ r
                                                                      il 0
                                          1,5
                                             2,7
                                                            z.
                                                                     HO
                                                                         73
                                         .31
                                                      t-o
                                                                                                               73
                                         ,37
                                                                                           45
                                                                      IK
       /eo
                                                                      hi
                                                                                       &tf*
                                                                                       ?^J»»J,
                            . 5
                                  i .5 2-
                                                             2-


-------
                                                                        Page
                                                                                                of
Plant Name:
Run Number:
                      .SO -.*
                                                       Test Date:
                                                       Operator:
Traverse
 Point
Number
Sampling
 Time
 (niin.)
            ng /
            ,  /
            ) /
dock Time
(24 hour
  clock)
Gas Meter
 Reading
 Velocity
llcadfP,)
 in. IliO
Orifice Pres. Differential
    (£ll)in.U2O
                 Desired
          Actual
 Stack
Temp. • F
  m
   Probe
Temp./ Tiller
 Temp* F
Impinger
 Temp.
Dry Oas Meter Temp.
                                             Inlet
                   (JUllCl
 Pump
Vacuum
  "L
           \\lti
                                   .32.
                           z.c.
                         2,6,
                         i/i
         iHO   1
                                           2.. (,
                                                                         *•*
                                                   , /
                                                   Ho
                                                                                      £5
                                                          hd
                                                                                         $0
                                                                                                         t
                                                                                                *<>
         ,1,6   1
                                    3-V
                                                   3.V
                                            Hi
                                                                       SO
                                                                      /O
         ,(,5   1  •* 00
                                                    1/
          '~t6  1 ft It
                                   3,3
           75
                             "
                             -31
                                                   34
          1*6  /
                                           3.1
                                                           III
                                   .35
                                   2.-T
                                    -S3
                                          3*1
                                                    Hi
                                                                             66
                                                           /J
                                    J7
                                                                                                 9
                                                           US
                                                                                        to
  to
  2-15
                                                           70
   M
                             yz,
                                                                                                          $
                                     32.
                                                                               Mr
   IV
                           '  ,30

-------
                METHOD  00)0     SAMPLE RECOVERY DATA
Plant:
                                                          Run No.: So -
Sample Date:
                             Filter No. (s):  So~/if#4-
                                                          Job No.:
Sample Location:   S<.r~ky Ft
Impinger Contents:  LJ\
Silica'Gel: @Grams Used -
                                   Color - 1 1.
                                                    % Spent -  <-*
Condensate Observed In Front Half:
Filter Container No.    t>-0
                                                          marked/sealed:
XAD Module Container No.:
                                                          marked/sealed:
Probe (FH) & Back Half Rinse (AoaoB^Container
                 ^^^
                                                          Liquid level
                                                          marked/sealed:
Probe (FH) & Back Half Rinse
                                   Container No.:
                                                          Liquid level
                                                          marked/sealed:
Impinger Contents Container No.:
                                                          Liquid level
                                                          marked/sealed:
Impinger Rinse (>
                       eCI2) Container No.
                                                          Liquid level

-------
 Plant:  £
Sampling Location
Run Number: f,o -*•>?-
Pretest Leak Rale:  ,&^
                      Data:
                                  FIELD DA IA SHEET
                             Sample Type: ***\s    Operator:

                             CO2:    ,o      O2:    /-z_
                                                                                                                        (
                                                           Nozzle ID:. *>os   Thermocouple »:.  "?<-
                                                           Assumed Bws:  .6V Filter #: go-/^^.^-^.'^
                                                           Meter Box #:  «V  Y: ?
Pretest Leak Check: Pftot:
                           @ ££. 'n- H
                           Orsat:   —
                             Probe Length/Type: -)' Ci'oJ    Pilot #: 1C     Post-Test Leak Rate: /dp3 cfm @ y In. Hg
                 Slack Diameter:   -7^
                                                    As:
                                             Post-Test Leak Check: Pilot:
                                                     \
Traverse
 POht
Number
     Sampling
       Time
       (mln)
Qoch Tun*
 (24-hour
 dock)
Gas Meter
 Reading
 (Vm)«3
 Velocity
Head (Ap)
 lnH2O
Oiice Pteasur* DrtferenBal
    (AH) In H2O
Desired  |  Actual
Stack
Temp.
 (Ts)
Temperature
   °F
                            Probe
       Filer
                                          Impingei
                                           Temp.
Dry Gas Meter Temp.
  Inlet
(Tmln0F)
  Ouflrt
(Tmout°F)
Vacuum
(in. Hg)
        /o
       16
       2.0
                     52/^5
       -75
                                      .3,5
              JSI3
       35
                           . 5
                      £41.5
                       *<((..«/
             _A6.
                       SSI. 3
                                       .13
                                        .3-7
        76
                                                Y////////////777777WY77^^
                                                   S,    I   J,/   I  / /Cr   P^ife    235   '-£>   Ql    &7   I  
-------
                                                                               Page
                                                                                        of
Plant Name:
Run Number:
                   - Jv\w5-
                                    Test Date:  _.
                                    Operator:  _
                                               -T74—
Traverse
 Point
Number
Sampling /dock Time
 Time,  /  (24-hour
 (min.) /   clock)
Gas Meter
 Reading
 Velocity
1 Icad^P.)
 ialhO
                                         Orifke Pres. Dirfeieotial
                 Desired
Actual
 Slack
Temp. • F
  m
   Probe
Temp./ Filler
 Temp* F
                         Impingcr
                          Temp.
                           •F
Dry Gas Meter Temp.
Inlet
          UUllCl
 Pump
Vacuum
 iiullg
               It-lit
                             .30
                                  HI
                                     2.32.
         wo   1 n 33
                             '36
                                 ifu
                                                                              .'A
               / nsjjT
                                   2.2-
                                           1 1
                                           .SYUo
                                                           In
               I
                                                                                                         ^/
               1 n £3
                                                                                                  It
                 /75g
        no    i *
                                                                                                 /i
                                                                     f-7&r
                                                                                                         if
               '  IS 13
               /
                            .35-
                                                                               Y*
         /so   '
                                                                                                 n
                                         z-f
                                                                                       X3
                                   •
                                                                 24 71
        •2/0
                                   3/2-
               '
                                           3.2-
         "2-20  /
                                                   /o?
                                                      fe
  i
                                                          left
                                                                                       $0
                         -725.1
                            , to
                •3-3
                        /of
             _*3L
                                          $0
                                                                               0
  it-
                                                                                                        i+

-------
                METHOD  00/0
                                     SAMPLE RECOVERY DATA
Plant:
Sample Date: Q \tf \ 9 ^
                              Filter No.(s):
                                                           Job No.
Sample Location:
Recovery Date:
                             XAD-2 Trap No.(s):
                                                      ~ fl\ W B -
Sample Recovery Person:   f\ 1C (vD C-
 Irnpingers
           XAD-2
            Trap
                   (knockout)
(100 ml H2O)
(100mlH2O)
  (tipped)^
    4
(knockout)
(untippedl
Silica gel
(untipped)
Final wt.

Initial wt.
                                                       '6 -i^»^«']
Train System:  &PA
                                       /  6"bK  i 0'
                                                                      ^3.
Probe:
Filter: Color-
                                   Loading -
Irnpinger Contents:
Silica Gel: ©Grams Used ^
                                   Color -
                                                    % Spent -
Condensate Observed In Front Half:
                                                                        ?-?'".™V??'?5-:
Filter Container No.	So- /kttA5'
                                                           marked/sealed: <.	?
XAD Module Container No.: $_o '
                                                           marked/sealed:
Probe (FH) & Back Half Rinse (AcstonsKontalner No
                                                           Liquid level
                                                           marked/sealed:
Probe -(FH) & Back Half Rinse
                                   Container No.:
                                                           Liquid level
                                                           marked/sealed:
Impinger Contents Container No.:
                                                           Liquid level
                                                           marked/sealed:
Impinger Rinse (,
                        eCI2) Container No.:
                                                           Liquid level

-------
FIELD DA IA SHEET
Plant: 6^
Sampling Location A .it-t-
Run Number: fc^Ajli. Date: <7-z.i-%: 'VO\O Al
Post-Test Leak Rate:	cfm
Post-Test Leak Check: Pilot:
                                                           @: \. fl &\
                                                            _ in. Hg.
                                                           Orsat:
Traversa
Point
Number

V
r
. >
i ^
•





















Sampling
Time
(mln)



























Clock Time
(24-hour
dock)


/
-Z-
'*)




/

2.


2>












Gas Meter
Reading
(Vm)«|3

^(VV^"
, Ob'b
.Ad L,
a

. 00 2>

> Op "^


^0^












Velocity
Head (Ap)
inH2O
Oifica Pressure Differential
(AH) in H2O
Desired | Actual
Stack
Temp.
(Ts)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Wet
(Tmin°F)
Outlet
(Tm out°F)
Pump
Vacuum
fin. Hg)
y////////////////////////////////////////////////////////////,

P I*. V
^ n i
^"> /C,'k
/v>v)«//i/x
/



<0 n:tfa
/
1-^^Hl


15'>Hu













IA
5







































































































































































































































    AH-

-------
METHOD TXDIC

Plant: ^M — C^lMd
Sample Date: °[ \22 \ ^-V
>/iHH5- SAMPLE RECOVERY
!*>
Filter No.(s):r$^HA<^l=4.^t
f* S\
Sample Location: ^r>1>v^> ~Tfc*rtid
Probe:
>' k
^s
Filter: Color- ^ Charon

/ BD-X f^.

::^iV:'.Tv..:;.:k.%j\;.;;^v-^^^^r~>V-Tt;CH,tv;V:"'t
^#&j^$i&3i#&8S$l&^$
•:.^^.\••^'_•^•^•''^•r'•n.•^.•.»..:•.•.-^v',..t^^^ ^•..^V'-,i^is^^.P
4
lockout) Silica gel
ntipped) (untipped)
f5-G &(o%.i g
&J5 &U2.2. g
£TVO O . c> g
lif^;ip^;:^^iiP|?^SpS
;.:k^v^ii:ii;."!t,lvUi:;: yisbt' ao A

Loading - tOo 10^
Impinger Contents: CJLSA^I w> C WT^H/^E:
Silica' Gel:
@Grams
Used- 3c>0 Color -
Condensate Observed In Front Half: ^O^E
'vio OtAOsr % Spent - Ud/^c


-•;;•• •«»WWV:^.^>;;Tr^
:-:^:;^i£^<^
Filter Container No.
A'^/^ /
&Hf

XAD Module Container No.: /-V*?>/~ /M^
Probe (FH)
Probe -(FH)
& Back Half Rinse (Aeelane) Container No.: ^/- //A$
& Back Half Rinse (Toluene) Container No.: /v0/-^/e
Impinger Contents Container No.:
Impihqer Rinse (Acatene/MeCI2) Container No.:

marked/sealed: <*/
marked/sealed: LS
Liquid level j
marked/sealed: ^
Liquid level s
$ marked/sealed: */
Liquid level
marked/sealed:
Liquid level
marked/sealed:

£




-------
09/09/97   10:19    Q19199410234
PES RTF NC
METHOD 23 CDD/CDF SAMPLE RECOVERY

Plant: ^?M - ^/^//O/
Sample Date: ^pl / ?9~
Sample Location: \j {jUjftt
Recovery Date: *?/22j r 7"
u>
<~c>i ^2-2*
Ciltmr Mn fo\- CK, .? SJJJP I. &f
rmer INO.IS^. *&v^ t*y~\ ~^i>-
lA CcHtUi^ &RL&T-
DATA
.P6J- ^3
Run No.: f-ft- g^H ^
Job No.: SW. 06 3

XAD-2 Trap No.(s): <^^-=r23^»Vl£ F&i - -^3
Sample Recovery Person: <^V^ L»yEL
>_c< 1._. %•»*- r~', . -^
1
Impingers XAD - 2 (knockout)
Trap
Final wt. — VH >
Initial wt. -— */T*/-7-
Netwt. -— ffX 0
-"NioistureData; *('
2 3
(100mlH2O) (100mlH2O) (k
(untipped) (tipped) _[u
>o3.(p T-/ .^ ^ -
"^•^.iD "?•/?•.& ^
D. *3 (}-O
•^ilSt^^^^^^^iSBiHB^^^^i
Train System: Bv« f*\erlr|&ol
^^> / box I'D*, /y-fr
-. - -* * T ^T-"* • i
V
4
nockout) Silica gel
ntipped) (untipped)
5?V.£> 6Ta.^ 9
WO ^Qv.^ g
D,0 D.o g
- ...., • , ... >.,-r.-. -.-h,-..vv -. ... . s.,. ..^^^^.i^xj;/;.^!! r:;.;v;.»"-t-.
i^i" rvr:^^.':VX1*^r-'^!^^^
/To+aQ- O.Da
Probe: I-1 QloS£>
Filter: Color- Ha Charge Loading- /VJdfjF

Impinger Contents: Ah O£
Silica Gel: @Grams Used - 3^0 Color-^Oijv^/ % Spent- M^Mf
Condensate Observed In Front Half jvdur
^.•'•'••;:&^J-V-.y"&;f&ttr:'.;:--*^^
•'^m;:&^£^mmmMZ^^
Filter Container No. /' h (' ^ /
XAD Module Container No.: p fa /- Z 3
Probe (FH) & Back Half Rinse (Acetone) Container No.: f &(-1-s
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.:
Impinger Rinse (Acetone/Mglle)
Container No.:

marked/sealed: 
-------
09/09/97   10:19    ©19199410234
PES RTF NC
@]003

METHOD
Plant: c?M- 3L^VvW
Sample Date: ^AvV
23 CDD/CDF SAMPLE RECOVERY DATA
yftj«~ A f
/ ltC"i f3jf**^
FilterNo.(s):^-23-2.
Run No.: F&~ 23- ^
I i_ ki V'Unt aO^L
uOD NO.: *J 7 ' '" .
' ^ C // X
Sample Location: J)£r^//£/- //Ww' — floor
Recovery Date: ' Q/l-k/'i 7
Sample Recovery Person:

1
Impingers XAD-2 (knock
Trap
Final wt. — i?£<.
Initial wt. ' ~ tf7«
Net wt. -
i^^^^^|g5^^^rp^;^±;::
. •;::?:-y-./-i-V«;iM.-.'.1S5«;.5. ..i.-vi'lfc •^.^••••\.:^- to.;.-* *
Train System: £/% A^
Probe: 7 ^ //L/rW
Filter: Color- MA ^
XAD-2 Trap No.(s): ^ - Z3~ "2-
£&^ v- ^^>x
liliiSiiii^ia^^llill
2 3
out) (100mlH2O) (100mlH2O)
(untipped) (tipped)
$ ~7&&.i/ ~7't3'<(^
f ~7z£.3 ~?2"$,(f,


tj> 21
*6jr^«J- -&U **•&?£,
Loading- A/ 4

4
(knockout) Silica gel
(untipped) (untipped)
<£&?. 7 ^ ^/> ^ g
fp&2-- 0 $&/. y g
g
*:.•;.••-:••. • :"•»• .. T/ ^•!'".1- ••'•w-r.v-: '••••. • •.-^- ^i-*'».-**;-^.'A£ rj»/*1' !';:«''/'•»•'»•
«.:5:;t^:'^f:^-^**w->vi^>\^Ti»vuiK:*K£5«K
l?^4^^^^^i.2^.>r^i ^- ^4(?
Silica Gel: @Grams Used -
2. t>o Color - /^e,y£^X % Spent - ^9
Condensate Observed In Front Half: 4/&\Ajzs
-»:-.•• rV'.'i --»"•'. ••.''•:':iJ—'V^vt'*i-^«^^fc:/i^>WA*« w'¥iC\%^^yf»Jt^^^^
Filter Container No. /^-- 2^3 - z-"
XAD Module Container No.: /£#- 1?-^
Probe (FH) & Back Half Rinse (Acetone) Container No.:/v?-27-
Probe-(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.: i'~/9-2- '" "^


Impinqer Rinse (Acetone/MeCI2) Container No.: /»- 2 ' ' ^

marked/sealed: l^x^
marked/sealed: ^
Liquid level >
^ marked/sealed: **/
Liquid level
marked/sealed:
Liquid level
marked/sealed:
Liquid level
marked/sealed:





-------
                     FIELD DA IA SHEET
Plant: £/n
Sampling Location
Run Number: fry m
Pretest Leak Rate:
Pretest Leak Check:

C /
*Va>*tS
7
Pilot:

,, o^U-4-
Date: ^-23-^7
cfm @ in. Hg.
Orsat:
Sample Type: ^ . V
Pbar. Z«?.7y Ps:
C02: O2 :
Probe Length/Type: */' >
Stack Diameter: ~7_5
Operator:


:/ Pitot #:
As:
                                                       Nozzle ID:	
                                                       Assumed Bws: _
                                                       Meter Box »: /V
                                                       Post-Test Leak Rate:
                	cfm @	in. Hg.
Post-Test Leak Check: PHot:     Orsat:
                Thermocouple
                Filter #:
                Y:
Traverse
Point
Number



























Sampling
Time
(mln)
£,
/o
IL.3
























dock Time
(24-hour
dock)
I2,o2>


























Gas Meter
Reading
(Vm)f|3
72MT-
30 ,0
3^ liO















(e/7, 7*0








Vetocity
Head (Ap)
inH2O
Otifica Pressure Drftertntial
(AH) in H2O
Desired
Actual
Stack
Temp.
fTs)
Temperature
°F
Probe
Filter
Impinger
Temp.
°F
Dry Gas Meter Temp.
Inlet
(Tmin0F)
OuHat
(Tm out°F)
Pump
Vacuum
(in.Hg).
y////////////////////////////^^^

















, /^/^7 -


5,/^7
- ' 	 : — -7
•7 //3-*_i_ y-'f

r^ ^




	


















&


( I . _
^

<«•

















/"y#
//;



//ot
-• /
-------
Plant:
Date:
 SAMPLE RECOVERY DATA
	  Run No.:
                        I  Job No.:
                     Sample Box No.:
Sample Location:.
Sample Type:	
                                            Filter No.:
Sample Recovery Person:
Comments:
FRONT HALF
Acetone
Container No. L
                          Liquid
                          Level Marked:.
Filter
Container NO.L
                           Sealed:
                                             Sealed:
Description of Rlter:
Samples Stored and Locked:
BACK HALF/MOISTURE
Container No.:	
                                             Sealed:

IMP. NO.
1
2
3
4
5
6
CONTENTS
P;r ^
p£ H^°
Zrfi
5-fce. Li


TOTAL
INITIAL
VOL (ml)
/(JO
/DO
b
ISO



WEIGHT (arams)
INITIAL
57f'6
lif -"A
Lj^.o
~7;$- ^



FINAL
fr%lb


73^



NET
^/


^7


fo7.7

-------
jaca a
                                      K- 9,36
                    GAS VELOCITY AND VOLUMETRIC FLOW RATE
                                                   Date:  '7- 25"-^
Sampling Lo<
Run#: £«.i
\
\
i
\

\ ^
"V
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Trov«rM
Point
Number
/
Is
1
*j
5
Cj2
^""7
3"
^
If)
//
/Z

/
^-
i
LJ
$
(j
i
4
"I
10
},
|V

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-------
      APPENDIX B




   ANALYTICAL DATA





-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                     Project No.
                                                                             Page        of

                                                                                _|	3
                                     Client
                                     Location

                                                   j;
Prepared By
                 Date   Checked By   Date   Sheet Title
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-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
                                                             Page
                                                                                          of
                                      Client
                                      Location
 Prepared By
Date   Checked By   Date   Sheet Title
                                              z
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                                      filkr

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                        Project No.
                                        Client
                                        Location
                                                                Page         of
                                                                        3     3
 Prepared By
Date   Checked By   Date   Sheet Title

-------
CLIENT CHAIN OF CUSTODY

   From: Pacific Environmental Services
        5001 S. Miami Blvd. Suite 300
        RTF, NC 27709

   Project: Tell City,IN

               >'
                                         SAMPLER'S SIGNATURE

                                             Contact: Frank Meadows
                                              Phone: 919-941-0333
                                                Fax: 919-941-0234
                                              P.O.#:	
  (PES03/AJB)
                           If the data will be reported to a state agency, which one?.
 Sample Name
                     Date
                            Time
Comp
             Grab
Matrix
Sample Amt.
                                                Analysis Wanted:
                                                                                                      P/Q 03927/0700003270
                                                                                                         Total Number of
                                                                                                         Containers:
Remarks
                                                   6/Ar,
                                                                  T
                                                                                  X
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                                                                  »
                                                                                 X
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                                                  £'/Ar *#*,/
                                                                                  X
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Date/Time
                                                               Relinquished By/Sign.
                                                                                              Date/Time
                                                                        Received By/Sign.
 Relinquished By/Sign.
                              Date/Time
                                           Recei^e¥By/Sign.
                             Relinquished By/Sign.
                                                                Date/Time
                                                        Received By/Sign.
Received for Laboratory By/Signature
                                        Date/Time
                                                            Send Samples to: Triangle Laboratories, Inc.
                                                                          Attn: Sample Custodian
                                                                          SO11 capitola Drive
                                                                          Da ham, NC 27713 USA

-------
                          ANALYTICAL REQUEST AND CHAIN OF CUSTODY
PLANT:
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PROJECT #:
                                           , ,/
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 SAMPLE IDENTIFICATION
                    COLLECTION
                    DATE  TIME
                       SAMPLE NAME
              NUMBER OF
              CONTAINERS
    COMMENTS

  (Typa of container,
 special preparation.
special handling. «te.)
                                                       X
                            DATE/TIME
                            DATE/TIME '
                                        REUNQUISHER'S SIGNATURE
                                          RECEIVER'S SIGNATURE

-------
                         ANALYTICAL REQUEST AND CHAIN OF CUSTODY
PLANT:
  PROJECT*:
RECOVERY
PERSON:
SAMPLE
TECHNICIAN:  (•?.
 SAMPLE IDENTIHCATION
                   COLLECTION
                   DATE  TIME
    SAMPLE NAME
NUMBER OF
CONTAINERS
                           ANALYTICAL REQUEST
            COMMENTS
          (Typ« of contains,
          •*•*& prepaiatton.
         *>«clal handing, ate.)
    - 00/0- /
                             f&-oo/o-l
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  REUNQUISHER'S NAME
DATE/TIME
     REUNQmSHEfrS SIGNATURE
SHIPPER'S NAME AND ID NUMBER
   RECEIVER'S NAME
DATE/TIME

-------
     Appendix B.I




    Analytical Data





-------
                 AIR QUALITY PREPARATION WORK ORDER FORM
                          TRIANGLE LABORATORIES, INC.
                                                                                 -1% "
TLI Project Number:
03927
                                                      Due Date:
Client/Company Nam
Project Manager:
Client MILES Code:
Quote.Number:
^
' ]£ Filters
31/z79.0 cm
4710.16cm
41/271 1 .0 cm
5712.5cm
Other
Filter Material:
Shio filter in:
A - A • ORDER INFORMATION
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Client Project #:
Client P.O. #:

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MATERIALS NEEDED
It- XAD traps PUFs
y^Ball and Socket
Socket and Socket
	 Screw cap
Other ftu/CW/tf

Sandwich PDF: yes
Ship PUFs in : jars
' t-A'T
no
sleeves
Quartz glass fiber other
one petri dish separate
petri dishes

Preparer:
# of Laboratory Blanks:
XAD Resin Batch #:
Pre-spike required:
Intended Analysis:
 (Circle ail applicable)        Other:

Spiker/Observer Initials:
Spiking Date:
Spiking Solution ID:
Volumn Spiked (uL):
Nominal Concentration:
Expiration Date:
PCDD/PCDF Surrogates
37CI<-2,3,7,8-TCDD       _4
"C,2-2,3,4,7,8-PeCDF
13C,2-1,2.3,4,7,8-HxCDF
'3C,2-1,2,3,4,7,8-HxCDD
'3C,2-1,2,3,4,7,8,9-HpCDF
Ship to the Attention of
Mailing Address
Street Address

Phone Number
Special Instructions:
                            PVE PREPARATION INFORMATION
                                                        Date:
                                                        Supplier:
                                                                          cO
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                                 Dioxi
                                                                Organics
                                  /
                                        I  
-------
                             CASE NARRATIVE
                      Analysis of Samples for the Presence of

             Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by

      High-Resolution Chromatography / High-Resolution Mass Spectrometry
                                Method 23 (6/93)
              Date:
              Client ID:
              P.O. Number:
              TLI Project Number:
October 21,1997
Pacific Environmental Services
43432
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 05/08/97
                                             Triangle Laboratories, Inc.
                                 801 Capitola Drive             P.O. Box 13485
                                 Durham, NC 27713-4411         Research Triangle Park, NC 27709-3485

-------
Triangle Laboratories, Inc.                                               October 21,1997
Case Narrative                                                                43432
Overview

Seven M23 samples were received from Pacific Environmental Services at 3 °C in good
condition on September 29, 1997 and were stored in a refrigerator at 4°C. The samples
and any associated QC samples were extracted and analyzed according to procedures
described in the Triangle Laboratories' Data User's Manual (Rev. 12/92-HK-2-AH-2/93).
Any particular difficulties encountered during the sample handling by Triangle
Laboratories will be discussed in the QC Remarks section below.  Results reported relate
only to the items tested.

Quality Control Samples

A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples.

Quality Control Remarks

This release of this particular set of Pacific Environmental Services analytical data by
Triangle Laboratories was authorized by the Quality Control Chemist who has reviewed
each sample data package individually following a series of inspections/reviews.  When
applicable, general deviations from acceptable QC requirements are identified below and
comments are made on the effect of these deviations upon the validity and reliability of the
results.  Please consult Triangle Laboratories' Data User's Manual for  further details.
Specific QC issues associated with this particular project are:

Sample Preparation Laboratory: None

Mass Spectrometry: None

Data Review: None

Other Comments: Any analytes found hi the TLI Blank are detected at a level equal to or
less than the Target Detection Limit. This level of contamination is acceptable as per TLI
guidelines.

Sample Calculations:

Analyte Concentration

The amount of any analyte is calculated using the following expression.
                    Amt(0)=

-------
Triangle Laboratories, Inc.                                               October 21,1997
Case Narrative                                                                 43432
Where:

Amt (0) is the amount of a given analyte,

AO is the integrated current for the characteristic ions of the analyte,

Ap is the integrated current of the characteristic ions of the corresponding internal
standard,

Qp represents the amount of internal standard added to the sample before extraction,

RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,

W is the sample weight or volume (W = 1 for M23)

The amount is expressed hi nanograms (ng) or picograms (pg).


Detection Limits

The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression.  The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor.  The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.

                           2 * 2.5 * (F * H)  * Qp
                     DL(0)= 	
                           Ap*RRF(0) *W
Where:

DL(0) is the estimated detection limit for a target analyte,

2.5 is the minimum response required for a GC signal,

F is an empirical number that approximates the area to height ratio for a GC signal. This
number is 3.7 for both the DB-5 GC column and the DB-225 GC column,


-------
Triangle Laboratories, Inc.                                                October 21,1997
Case Narrative                                                                  43432
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,

Qp represents the amount of internal standard added to the sample before extraction,

RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,

W is the sample weight or volume

The detection limit is expressed in nanograms (ng) or picograms (pg).

Other sample calculations may be found in the Triangle Laboratories Data User's Manual.


 Data Flags

In order to assist with data interpretation, data qualifier flags are used on the final reports,
as discussed in Triangle Laboratories' Method 23 Data User's Manual. Please note mat all
data qualifier flags are subjective and are applied as consistently as possible.  Each flag has
been reviewed by two independent Chemists and the impact of the data qualifier flag on
the quality of the data discussed above. The most commonly used flags are:

A 'B* flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag will be used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories guidelines, a laboratory blank is acceptable if the tetra-
through hepta-CDD/CDF levels are all below the target detection limits (TDLS) or if the
contamination levels are less than 5% of the levels detected in the associated field samples.
If these conditions are satisfied or if the blank is unable to be reextracted, the
interpretation of the contamination levels relative to the samples should be as follows: 1)
analyte quantitations should be considered valid if the level of blank contamination is less
than five percent of the level detected in the field sample, 2) analyte quantitations should
be considered estimated if the analyte level in the sample is five to twenty times the level
of the analyte in the blank, or 3) analytes whose level in a sample is the same as or less
than five times the level detected in the associated blank should be considered present
likely due to laboratory contamination and not native to the sample.

An 'E' flag is used to indicate that an PCDF peak has eluted at the same time as the
associated diphenyl ether (DPE) and that the DPE peak intensity is ten percent or more of
the PCDF peak intensity.  Total PCDF values are flagged 'E' if the total DPE contribution
to the total PCDF value is greater than ten percent.  All PCDF peaks that are significantly

-------
Triangle Laboratories, Inc.                                                October 21,1997
Case Narrative                                                                  43432
the isotopic abundance ratio. These EMPC values are most likely overestimated due to
the DPE contribution to the peak area.

An 'I' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks.  The interference may have caused the standard's
area to be overestimated.  All quantitations relative to this standard, therefore, may be
underestimated.

A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.

A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences.  Affected analytes may be overestimated or underestimated as a result of this
interference. A peak is flagged 'Q' only if it is affected by a QC ion deviation greater than
20% full scale as determined relative to  the labeled standard against which it is
quantitated. Total PCDF/PCDF quantitations will be flagged 'Q' if the interferences affect
ten percent or  more of the total PCDD/PCDF peak areas.

An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference.  This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.

A 'U* flag is used to indicate that a specific (2,3,7,8-substituted) isomer cannot be
resolved from  a large,  coeluting interferent GC peak. The specific isomer is reported as
not detected as a valid concentration/amount cannot be determined. The calculated
detection limit, therefore, should be considered an underestimated value.

A' V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one.  The standard is considered reliably quantifiable. All quantitations derived from the

-------
Triangle Laboratories, Inc.                                               October 21,1997
Case Narrative                                                                 43432
By our interpretation,  the analytical data in this project are valid based on the guidelines
of EPA Method 23 (6/93) and Triangle Laboratories' Method 23 Data User's Manual.
Any specific QC concerns or problems have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data.  Should Pacific
Environmental Services have any questions or comments regarding this data package,
please feel free to contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Report Preparation                        Quality Control
Vijay S. Chhabra
Report Preparation Chemist                Report Preparation Chemist

-------
                     TRIANGLE LABORATORIES, INC.

                 LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American Association for  Laboratory  Accreditation. Certification  pending.   Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices)  Parameters are AOX/TOX,
Volatiles, Pesticides, RGB's, BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of Environmental Management Expires December 31, 1997.
Laboratory I.D. # 40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation.  Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona,  Department of Health Services.  Expires May  26,  1998.  Certificate
#AZ0423. Drinking Water for Dioxin,  Dioxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology.   Expires February 18,
1998. Pulp/paper, soil, water,  and Hazardous Waste for Dioxin/Furan; AOX/TOX.

State of California, Department of Health Services. Expires August 31, 1999.  Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut, Department  of  Health Services.  Expires  September 30,  1997.
Registration # PH-0117. Dioxin in drinking water.

Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.

Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC)  and Volatiles (GC/MS) in Environmental Samples.   Environmental water ID HRS#
E87411.

Hawaii Department of Health.  Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 9/18/97 RM


-------
Idaho Department of Health and Welfare.  Expires November 30, 1997. Dioxin in drinking
water.

State of Kansas, Department of Health and Environment. Expires January 31,  1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste.  Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.

Commonwealth of Kentucky, Department for Environmental Protection. Expires December
 31, 1997. ID#90060. Dioxin in drinking water.

Maryland Department of Health and  Mental  Hygiene.   Expires  September 30,  1997.
Certification #235. Drinking water by Method 1613A.

State of Michigan, Department of Public Health.  Expires March 31, 1998. Drinking water by
Method 1613.

Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.

Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.

State of  New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31,1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.

State of New Mexico, Environment Department Certification  pending. Dioxin  in drinking
water.

New York State Department of Health. Expires June 30, 1997. ID  #11026.  Environmental
Analyses of non-potable Water, Solid and Hazardous Waste.  Method 1613 in DW.

State of North  Carolina, Department of  Environment Health and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.

State of North  Carolina, Department of Environment, Health, and Natural Resources,
Division  of Environmental Management  Expires December 31,  1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.

North Dakota State Department of  Health and  Consolidated Laboratories.  Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 9/18/97 RM
Printed 9/18/97

-------
Oklahoma Department  of Environmental Quality. Expires October  31,  1997. Laboratory
#9612. Dioxin by 1613A.  8290 and 8280.

State of South Carolina, Department of Health and Environmental Control.  Expires June
30, 1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.

State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992.  Method 1613 Drinking water only.

U.S. Department of Agriculture Soil Permit  Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission  is granted to receive
foreign soil samples for use in laboratory analysis.

U.S. Army Corps of Engineers. Expires November 30, 1997.  Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.

U.S. EPA Region VIII,  for the State of Wyoming.  Expires November 13, 1997.  Dioxin in
drinking water.

State of Utah, Department of Health.  Expires December 31,1997. Certificate Number E-166.
Certification for the following parameters:  Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.

Commonwealth of Virginia, Department of General Services, Division  of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.

State of Washington, Department of Ecology. Expires September 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for Polychlorinated  Dibenzo-
p-dioxins and Polychlorinated Dibenzofurans,  BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.

State of Washington, Department of Health. Expires April 30, 1998. Dioxin  in drinking water.
 Lab I.D. 129

State of West Virginia, Department of  Health.  Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 9/18/97 RM


-------
State of  Wisconsin,  Department of Natural Resources.  Expires  August 31, 1998.
Laboratory ID  Number 999869530. Certification for the following categories  of  Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement Agency (DEA).  Expires  November 30,  1997.  Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources. Expires October 31,1997. Registration number NC-
PT 0000 0031. North  Carolina controlled  substances registration. Application submitted for
renewal.

Food &  Drug  Administration  (FDA)  Registration.  Expires June  1998. ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May  30, 1999.
ID # 34D0705123.   Department  of Health & Human  Services,  Health  Care  Financing
Administration.

U.S. EPA Large Quantity Hazardous Waste Generator.  No expiration date.   EPA  ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina Radioactive Materials License.  Expires April 30  1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.

North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG.  The general  license applies  only to radioactive material  contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 9/18/97 RM
Printed 9/18/97


-------
DOCUMENT
  CONTROL
          Triangle Laboratories, Inc.
    801 Capitola Drive      P.O. Box 13485
    Durham, NC 27713-4411    Research Triangle Park, NC 27709-3485
    919-544-5729        Fax # 919-544-5491

-------
                              ANALYTICAL REQUEST AND CHAIN OF CUSTODY
         :  &M-
            PROJECT *:
     RECOVERY
     PERSON:
     SAMPLE
     TECHNICIAN:  (y.
  _^_
,   (.
     SAMPLE IDENTIFICATION
                        COLLECTION
                        DATE   TIME
               SAMPLE NAME
NUMBER OF
CONTAINERS
    COMMENTS
  (TypcofcontokMr.
  pedal preparation.
•pedal handling. etc.)
         - 00/0- /
                                     X
                                                                   K
                          ff?
                                   5*0 - 33- 1
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                                                          V
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                                                '
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                                DATE/TIME
                                                     REUNQUISHER'S SIGNATURE
                                 RECEIVER'S SIGNATURE

-------
                                                                       7
 CUENT CHAIN OF CUSTODY
                                          SAMPLER'S SIGNATURE
                                                                                                 P/Q 03927/0700003270
 From: Pacific Environmental Services
     5001 S. Miami Blvd. Suite 300

     RTP, NC 27709
Project: Tull Ctty,1N
                                              Contact: Frank Meadows
                                               Phone: 919-941-0333
                                                Fax: 919-941-0234
                                               P.OJ: 	
 (PES03 /AJB)

                        If the data will be reported to a state agency, which one?.
 Sample Name
                  Date
                             Time
Comp
Grab
                    Matrix
Sample Amt.
                                               Analysis Wanted:
                                                                                                       Total Number of
                                                                                                       Containers:
Remarks
                                                                                 X
                                                                                         X
So -
                                                                  i
                                                                              X
so- flf- y.
   fl-23-*"
                                                               2
                                                                                  X
 Relinquished. By/Sign.
                            Date/Time
                                                                                               Date/Time
 Relinquished By/Sign.
Date/Time
                                         Recei^eia By/Sign.
                                                                 Reiinquilngcf By/Sign.
                                                           Date/Time
                                                               Received By/Sign.
ujleceived for Laboratory By/Signature
GO  "'        "
                                        Date/Time
                                                         Send Samples to: Triangle Laboratories, Inc.
                                                                       Attn: Sample Custodian
                                                                       801 Capitola Drive
                                                                       Durham, NC 27713 USA

-------

                       ANALYTICAL REQUEST AND CHAIN OF CUSTODY
                          PROJECT ,:
RECOVERY
PERSON:
SAMPLE
TECHNICIAN:
SAMPLE IDENTIFICATION
                  COLLECTION
                 DATE   TIME
SAMPLE NAME
NUMBEROF
CONTAINERS
                        /
                         ANALYTICAL REQUEST
  °°MMENTS
(TVP-oleontaJn.,.
SSS3S&

                                                 X

-------
19/09/97   10:19
U19199410234
PES RTF NC
31003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: G^/v} - ^>
Sample Date: Wl M
Sample Location: C
Recovery Date: 7/Zl.i
^M)AUJ
\1- Cill»r MX i'.i\. Ctl "> 3 i_ 4. " ^
7 riller iNU.(a^. Ow* 6-5^ | ~»t x
CUf«U CchlX,^^- 2>U/TL&T-
)'} XAD-2 Trap No.(s): *^cV
.H-6J^ ^3
Run No.: Ste=^3=4~^
JobNa-r'S^W. 063

=-2^-^^ Fft»- 3-3
Sample Recovery Person: \V\ 1 r)EL

Impingers XAD-2 (kr
Trap
Final wt. — V
Initial wt. — *f i
Net wt — 
S^S^SflifEiiSS
Train System: ESRt P\e
12 3
lockout) (100mlH2O) (100mlH2O)
(untipped) (tipped)
7^-? ^clG? ^t-Tk^
i^.'y. "^OS.ID *?/?•. s
. D /":. 0 (}-O
£?5i^^^S'DisiSC]H§8^
i^rticcl &?> / box I'D'. V-
4
(knockout) Silica gel
(untipped) (untipped)
5W-& 6?^,^ g
5^.0 ^^i..1^ g
1}.C* P» . c> g
•'•-T:;' •"-. ;-;:;T:j7r«-i • •• -\«{-*x:i"^'.i-.'v:a«::
K-^-Jti-A"- ; '-•'•'-' '~ •••'•' T " '-' ••Ki'Kf'Sir-.i-SV" »•— '-«.i
V .'.•'••.•iivr-n- •.V-^1iii^X._Tr.»i-cJ.':;:-~i: •';•..*"'-«' ^.I.VjJw: • •'-
^ / } C-A'7 C • I ' /-/ *7
Probe: ~V Qla^>
Filter Color- ^ Chfli
\\ e Loading - /\j ?? ivjF

Impinger Contents: Ah Gt*A*JC»f
Silica' Gel: ©Grams Used - 3fca Color - }\> (LHw > % Spent - \i^t^C
Condensate Observed In Front Half: jWiir
±r^liii?iS?;^Bi

i','.' v;" > RB c ova ra di'S ampl e^Wracti o nss~-
Filter Container No. /'* A /' 2- £
XAD Module Container No.; /' /? / - Z 3
Probe (FH) & Back Half
Probe -(FH)& Back Half
Rinse (Acetone) Container No.: f Af
Rinse (Toluene) Container No.:
Impinger Contents Container No.:
.^*
Impinger Rinse (Acetone/M5©£) Container No.:

^^SfiKISSS^^S
marked/sealed: <*/
marked/sealed: ~s
Liquid level
-2-3 marked/sealed: ^^
Liquid level
marked/sealed: \^
Liquid level
marked/sealed: %
Liquid level ,
marked/sealed: ^
15

-------
19/09.-97   10:19     ^19199410234
PES RTF NC
2)003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: (— ,ji{ - SvAGiftMu)
Sample Date: ^|Z3l^>
Sample Location: p (C-uoolc
Recovery Date: ^1 |2*f p T
Sample Recovery Person: w~
^.>^-3:'^:i^^^^M^l^^r%M
1
Impingers XAD - 2 (knockout)
Trap
Final wt. 	 (0A(*-3
Initial wt. — H3-H.4-
Netwt. ~~~ /5V. to

Filter No. (s): £.£.u Aft£{. ( 'aTttT
XAD-2 Trap No.(s): S: 0
Run No.: 56 2,-s-
JobNo.:^^.^

33-
i6E-
^SliWiSisitureL: iSalferl'H;^::
2 3
(100mlH2O) (100mlH2O)
(untipped) (tipped)
"TOx:7.^ ^/-?- 3
"7-^3.^? ^i?-.H
-/.3 -0.5*0
r;:fp|gi|:^|§|^g^y
4
(knockout) Silica gel
(untipped) (untipped)
^iW ^B^---Z g
6"^ y O J2H^**Oi ? g
' * * j £•'*(' g

Train System: §r(pP\ MfMrtte
\ zs /ix^x "^H
/ 7o-rAu : /6A?
Probe: 1 ' r» fc<5 / L/*v
Filter Color- <^r«?£ -2
Probe -(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.
Impinqer Rinse (Acetone/Ma&t2)
s.-zJV
Container No.:

SlBISIIgSlSi^
marked/sealed:
marked/sealed: -~s
Liquid level
^ -/ marked/sealed: >-/
Liquid level
marked/sealed: ^
-------
09/09/97   10:19    S19199410234
                                       PES RTF NC
                   METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
Plant:
                -   fl C
                                                            Run No.:
                                                        -3 -
   Sample Date:
                              Filter No.(s): "G6- 2.3-
                                          Job No.:
Sample Location:  ft ^Mptirt
                                     r w
   Recovery Date:  ^ \l*{ \ ^
                              XAD-2 Trap No.(s):  SC - £*>-
Sample Recovery Person:
                                  1
                                                •„.».•—•:_•.-,•- ^vrsv-^r^i^r^r-.;:;-.,--. ; '•^^•^•^f^^-^'-rf -*. irrW-^viV-- "
                                                5fi •• -; *'-i*« «»-,•-•"• •• • • ••— ..- x^i-"- —"^ •' • • v^i  -.%. .*• •••w .*.. "r*'4« •.v^*»«[^'•* » •,- X-
                                                ia^^-y^^?^ ~ e--^sasafc^ggs^^g?^^
   Impingers
           XAD-2
            Trap
      1
  (knockout)
                              (100mlH2O)
                               (untipped)
(100mlH2O)
   (tipped)
    4
(knockout)
(untipped)
Silica gel
(untipped)
   Final wL
   Initial wt.
   Netwt.
                                                0.2-
                                      (•••• *'?•••.* •^.'.T»"w™t'~,'?r"'''r "."" **"*" '.tv .<"•?: &1-!—'-•".""• • r>" >••"•• •*?(taCX''r- -i
                                      i^^
Train System:
Pfl~
                                I3)  /
                                                 ID-
   Probe:
   Filter Color-
                                    Loading -
                                 iu
   Impinqer Contents:   C>i
   Silica'Gel: @GramsUsed- .3ro     Color- U fttu-e    % Spent-  U b	
   Condensate Observed In Front Half:   MO iJ£	


   Filter Container No.     SO - t^ -  ^-^                       marked/sealed:   ^^
  XAD Module Container No.:  S V
                                                            marked/sealed:
   Probe (FH) & Back Half Rinse (Acetone) Container No.:5o - 23
                                                            Liquid level
                                                            marked/sealed:
   Probe-(FH) & Back Half Rinse (Toluene) Container No.
                                                            Liquid level
                                                            marked/sealed:
   Impinqer Contents Container No.:
                                                            Liquid level
                                                            marked/sealed:
   Impinqer Rinse (Acetone/MeCg) Container No.:
                                                            Liquid level
                                                            marked/sealed:

-------
19--09/97   10:19    O19199410234
                                     PES RTF NC
               METHOD 23 COD/CDF SAMPLE RECOVERY DATA
Plant:
                                                            Run No.:SO -
Sample Date: °1t6
                               Filter No.(s): •$?) - Z i -3
                                                         JobNo.rSHH.bbS
   Sample Location
              :   *o
Recovery Date:  ' ^ fc? / 9 >
                             XAD-2 Trap No.(s):
                                                     ~ * 3 -3
Sample Recovery Person:   MT- \ \jE-
Impingers
             XAD-2
              Trap
    1
(knockout)
                             (100 ml HZO)
                              (untipped)
(100mlH20)
  (tipped)
    4
(knockout)
(untipped)
 Silica gei
(untipped)
Final wt.
                                                                      2.5
Initial wt.
                                                                        . 3
   Netwt      —
                              -/a.5"

Train System: E?A
                                     /
                                            1>>;
Probe:
Filter Color-
                                     Loading -  r\
Impinger Contents:   C
Silica Gel:  @GramsUsed- 3o6     Color- ||. l?/^  % Spent-  (id
Condensate Observed In Front Haft
Filter Container No.
                                                            marked/sealed:
XAD Modv!«9 Container No.:
                                                            marked/sealed:
Probe (FH) & Back Half Rinse (Acetone) Container No.:
                                                            Liquid level
                                                            marked/sealed:
Probe (FH) & Back Half Rinse (Toluene) Container No.
                                                            Liquid level
                                                            marked/sealed:
Impinger Contents Container No.:  5o -2-3-3
                                                            Liquid level
                                                            marked/sealed:
Impinger Rinse (Aceton
                               Container No.:
                                                         Liquid level
                                                         marked/sealed:

-------
09/09/97   10:19
S19199410234
PES RTF NC
©003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

Plant: C,M - <
Sample Date: n/^5"
Sample Location:
5A6l*>AW
' Cl > Rlter No.(s): Sb-23-J
& C u*ob £
J^tiS!S^KS
Impingers XAD - 2
Trap
Final wt —
Initial wt. —
Netwt —
llpl^^ggppi^iall^lliai
12 3
(knockout) (100m»H2O) (100mlH2O]
(untipped) (tipped)
£,">\/5~" ^9D.^ ^?4, /
Ml^.T- ~j~ol.,1 "/'OU'-f'
-/Oi>.fi *W-3 -?-U?
":{^®|||^|§p:|^g§|
4
(knockout) Silica gel
(untipped) (untipped)
fclO.-l ^19.5 g
OcH-k .^r^r^.4/ g
^"•9 5t>'/ g

Train System: c*r/-
* ^A^^^K^ ,23 / 60^ M-5 /
-r^r^u- ^3(^.8
Probe: ~V £,Lfr56
Filter Color- ~~r~
A^ Loading- lA^D'W.
V\^
Impinger Contents: C^\^> Color- 'H- VD\VX£ % Spent- Uo
Condensate Observed In Front Half. M? N £•
^tf-rijs— ''•'•'"i*-:-';s™-***t*-"'' '•-'-^•»~^1>^vc^i^>^ssjvv»\i«^7^V*>«»^«i1SiiV-!<»i^.^(«'^^
-^i^iE^^;^^
Filter Container No. 5c - ^ > ' V^
XAD Module Container No.: £i> - 2 3 - V
Probe (FH) & Back Half Rinse (Acetone) Container No.: ^o-2-
Probe-(FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.: fa " 23 - tf
Impinqer Rinse (Acetone/MeCI2) Container No.:

marked/sealed: «— '
marked/sealed:
Liquid level ^
5-/ marked/sealed:
Liquid level
marked/sealed:
Liquid level ^
marked/sealed:
Liquid level
marked/sealed:
19

-------
09/09/97   10:19    O19199410234
PES RTF NC
121003
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA

-•> + i
Plant: c?M- _>L>fVw Aw^
Sample Date: ^ M/V Filter No.(s): /=#- 23 -2.
/ '
Sample Location: _!>£>«.//£/- flvJ&J' — >locr
Recovery Date: ' 3/'1>k/4> 7 XAD-2 Trap No.(s): /"£ -
Run No.: ffr. 21- T-
JobNo.: Silt-***

-23- "2-

i *
Sample Recovery Person: £•&<£« v- <2£ /T^us
^^^rap^^^^^Maa^ffi^a^
1 2 3
Impingers XAD-2 (knockout) (100mlH2O) (100mlH2O
Trap (untipped) (tipped)
Final wt — i?£»$ ~76&.y_ -72.5/U.
Initial wt. ' — ^7^(f 17^.3 "7.2 3. £
Netwt -
^^—f-y-n:-^-; ..^Ui»it=.ViS}^jrf=^V»J«Pf.:»at'^'
\?;K f= •"-^•^:fe^vv^:5!S-5^J^¥SSS
4
i (knockout) Silica gel
(untipped) (untipped)
kv2. 7 <$£/, ^
^2.9 66/. y


9
q
9
SSIlSli^SfiiiSi^l^S^Si^Sffl
Train System: £PA fikd-d} 2- 3
Probe: 7^/4^U *6x J*J- ^6^, MT.^
Filter Color- N^ ^ Loading- A/ 4
Impinger Contents: "7^, -^ //i^?
Silica' Gel: @GramsUsed- 2.5i7 Color - &Le,/{jluA* % Spent - ^
Condensate Observed In Front Half: /^£no£/
^^s^%^^^?S^ipBZaMgSg^^^S3g^^
-•== i^'MtL^ifS^'^fSwSvi'^a'if.aSt^is-A •^llSPCOyaflBaSJMOTpleL^liaCupn.S?-?:^ '; ^v!S;: Siy -fesS^a1^ •r-rv^n'fe-'^'i^S
Filter Container No. /^- 13> ~~L-
XAD Module Container No.: /^^ ^.^ - "2^"
Probe (FH) & Back Half Rinse (Acetone) Container No.: /v?-??
Probe (FH) & Back Half Rinse (Toluene) Container No.:
Impinger Contents Container No.: f/^-^- )1" ^

Impinqer Rinse (Acetone/MeCI2) Container No.: /^- ^ ? '

marked/sealed: L-x^
marked/sealed: ^
Liquid level y
•** marked/sealed: t^^
Liquid level
marked/sealed:
Liquid level
marked/sealed:
Liquid level
marked/sealed:
2(

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                  Project No.

                                     SW.OO?
                                  Page
                                  Client
                                  Location
                                                              ff
                                            of
                                                                         io»S
 Prepared By      Date   Checked By   Date  Sheet Title
       [70. Q
        -23 -/
     $0-
           ft
/=:• V
                       3^2.       a
                                          t
   st.  C/?<*/o»«c  
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
                                   Client
                                   Location
Page
                                                                                  of
 Prepared By     Date  Checked By  Date  Sheet Title
       -216,
               - 3
                                   t>+UdkW.
                                          z
                                                                              .28-
      &'
      50-23-3
                                   filkr
                                                u»c,
                                                                                          22

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Project No.
                                                                             Page        of
                                                                                    3     3
                                      Client
                                      Location
 Prepared By       Date   Checked By  Date   Sheet Title
                                     f;fkr
                                                                                                23

-------
b
II
II
U
11
y
B
Custody Seal :
Chain of Custody :
Sample Tags :
Sample Tag Numbers:
SMO Forms :
Ice Chest
Absent
Present
Absent
Not Listed
N/A

Sample Seals:
Container. . . :
on Chain of Custody
ICE Temp
WliljtS IjABUKATUKlBS, IMC. -- LOU iH Kl
Absent
Intact
3.0 C
| TLI Project Number 43432 '
j Client: PES03 - Pacific Environmental Services
1
j *.
\
\ Date Received
j
| Carrier and Number
| 09/29/97
1 *** MZ^fodft k
| Book I)
1 II
1 "5 U
ft f ||
M&\
1 '.I " ' ' "
| TOM MCDONALD •) | 6 ||
JTLI Number Client Sample ID. 	 Matrix)
jjmR/H:CPM ....Client COC ID 	 * Location 	 j
»i
U185-6-1A SO-
II so-
il
||l8S-6-lB SO-
li SO-J
||l85-6-lC SO-
II so-
il
||l85-6-lD SO-
ii so-
il
||l8S-6-lE SO-
II SO-
|
IJ18S-6-2A SO-
II SO-
II
II
||l8S-6-2B SO-
II SO-
||l8S-6-2C SO-
II SO-
|
II
||!85-6-2D SO-
lj j SO-
l|!85-6-2E SO-
II so-
||l8S-£-3A SO-
II so-
||l85-6-3B SO-
II SO-
||lB5-6-3C SO-
II SO-
||1BS-S-3D SO-
II SO-
To LAB
Date/Init
A ^
23-1 FILTER) 
-------
                                          -TRIANGLE LABORATORIES, INC.  -- LOG IN RECORD/CHAIN OF CUSTODY"
|| Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container. . . : Intact
U Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
|| ice Chest
ICE Temp 3.0 C
||TLI Number Client Sample ID 	 Matrix)
jjmR/H-CPM Client ™c* ID.. ._• location 	

||l85-6-4A SO-I
U so-
il
II
||l85-6-4B SO-I
II SO-I
JJ185-6-4C SO-I
|| SO-I
||!85-6-4D SO-
II so-

23-4 y FILTER
23-4 rjJj^H*- C01
23-4 XAD
23-4 C01
23-4 ACE/TOLUENE
23-4 C01
23-4 CONDENSATE
23-4 C01
JJ18S-6-5A FB1-M23 FILTER
jl FB1-M23 C01
II
||l85-6-5B FB1-M23 XAD
I) FB1-M23 C01
||!85-6-5C FB1-M23 CONDENSATE
|| FB1-M23 C01
|i 185-6- 6A FB2-M23 FILTER
jj FB2-M23 C01
I
II
||l85-6-6B * FB2-M23 XAD
jl "i F82-M23 C01
II '
II
||!85-6-6C FB2-M23 ACE/TOLUENE
|| FB2-M23 C01
||l85-6-7A LAB BLANK M23 FILTER
U LAB BLANK M23 C01
||l85-6-7B LAB BLANK M23 XAD
II LAB BLANK M23 C01
||l85-6-7C | LAB BLANK M23 ACETONE
|| LAB BLANK M23 C01
To LAB
Date/lnit
xfv
lOA-W


-









II 	 	 .
||l85-6-7D LAB BLANK M23 H20| \
|j LAB BLANK M23 C01 j
U Receiving Remarks:
1
II
|| Archive Remarks:

— |






	 «

TLI Project Number 43432 , | Book ||
Client: PES03 - Pacific Environmental Services j ||
1 IBS ||
Date Received j 09/29/97 | Bv^fk2g£> tJ^T*/*^^^-^336 II
i • '.; • i u
Carrier and Number | TOM MCDONALD , | 6 ||
To STORAGE |
Date/lnit
i jyC

\-*fl
J


/
} .
/""
r

/
1

<
V
J
\

>_


>-^fO

,


J_
To LAB
Date/lnit











To STORAGE
Date/lnit














To LAB
Date/lnit












To STORAGE
Date/lnit













i i
To LAB
Date/lnit
t





t







To STORAGE
Date/lnit



'










DISPOSED ||
Date/IniL ||
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
U
II
II
II
II
a
u
D
II
1
II
II
                                                      »Forro Revised  05/27/1997 -- Page 2 OF 3=
ro

-------
!vi == = = == = *TRI»- LABO. .IBS, _. -- L. -1 REC-.
0 Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container...: Intact
|| Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
TLI Project Number 43432 Book ||
Client: PES03 - Pacific Envi/ronmental Services ||
Date Received j 09/29/97 j By^p%^^/^7y?x^2 ^^9£ 1
U I I* • v ii
|| Ice Chest ICE Temp 3.0 C Carrier and Number | TOM MCDONALD '•, 6 ||
l|TLI Number Client Sample ID 	 Matrix)
jjmR/H-CPM Client COC ID . ..* Location 	
n
U
Q18S-6-7E . LAB BLANK M23 TOLUENE
y LAB BLANK M23 C01
n
n
II
II i
II
D
II
II
j
u
II
II
n
u
II
n
n
n
n
n
n '
ii -
«i
u
ii
ii
n
u
n
.
n
u
To LAB
Date/Init
^


'










To STORAGE
Date/Init
)o>*o
jj^r












To LAB
Date/Init












To STORAGE
Date/Init












To LAB
Date/Init










-



To STORAGE |
Date/Init



•







To LAB
Date/Init


1

1
1








TO STORAGE
Date/Init
.













DISPOSED ||
Date/Init ||
n
II
n
II
II
.11
II
II
II
II
II
n
II
y
n
u
n
«"
u
• u
ii
u
n



D  Receiving Remarks:
y
n
||  Archive Remarks:
                                                              =Forra Revised 05/27/1997  --  Page 3 OF 3=
      ro

-------
                       TRIANGLS LABORATORIES, INC.
               SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
                       -ADMINISTRATIVE INFORMATION	±J^>~r-	'	 - - A
 TLI  Proj#:  43432-      Samples:  7           TurnAround. : -¥5" Day(s)      |£L»^"
 Prod Code:  D23061      Matrix.:  M23Train    Hold Time..: 30 Day(s)    /  ..,,
 DetectLim:  0.05 ng     Type...:  A           Start Date.: lO/er^T?"1^   /  "i^n?;
                        Recvd. . :  09/29/97    Ship By	: 1Q/^2/^^^^\ 'Ofl
                                             DWL Due Dt. : Ig^O-W*?     ^4oL
                                                                         I1

 Analyte List.: tetra-octa PCDDs/PCDFs

 Method	: Method 23:Tetra-Octa (Tol Combined)
 Client Proj..:
 Client	: Pacific Environmental Services  (PES03)
 P.O.  No	:                              Collect Dt/Tm: 09/22/97
 Contact	: Frank Meadows                Phone	: 919-941-0333
 Proj .  Mgr. . . < : Amy J. Boehm                 Fax	: 919-941-0234
                                             Sample Origin: NC
		SPECIAL INSTRUCTIONS / QA REQUIREMENTS	
 Assoc Proj 1: 43433                     Prespike Standard: USF-CS
 Assoc Proj 2: 43452                     Prespike Amount..: 4.0ng
 Prep Project: 03927
---- ..... ----------------- REPORTING REQUIREMENTS
 Reporting Format: Report Option II

 See  MILES for Instructions/Communications .
 Completed by:     Wl-.ljJ _  DATE:   /C -'Z~97


 Reviewed by: _ /)& _  DATE:  fJ^JW '     (PMGT0197)
                    ^-,

-------
                   TRIANGLE LABORATORIES OF RTP, INC.

                    PROJECT COMMUNlCATfON TRACKING FORM
                                                                       page	of	
                      TL1 Project Number:
Use this form to record-all exchanges of information beNveen production units as well as personnel
handling -this project. Decisions, corrective actions and recommendations must also appear on this
                                tracking document.   ..^
         Comment / Decision / Resolution / Action / Observation
               Triangle Laboratories, Inc
               Til PROJECTS  03927
               DATE 9/18/97  TLI BLANK
               SPIKE 4.0ng USF-C & USF-S
               SPIKE 100ug TERPHENYL-DU
               SPIKER W^    PREP.

-------
Date: 10/10/97
Time: 07:26
                                                                TRIANGLE LABORATORIES,  INC.
                                                               Met Lab MM5/PUF Observations
                                                                      Project: 43432
PRDPERC V4.00
      Page: 1
Sample
ft crd TLI_Number. .
000 TLI Blank
001
002
003
004
005
006
007
OOB
009
185-6-1A-D
1B5-6-2A-C
185-6-3A-C
1B5-6-4A-C
1BS-6-5A-B
185-6-6A-C
185-6-7A-C.E
TLI LCS
TLI LCSD
Cus
TLI
SO-
SO-
SO-
SO-

Blank \
-------
1
i 'reject: 43432
1 Solvent (s)/Acid(s) : iDCe^Sc
1 x>t Numbers: ^TZ.\\^[
| IS Spike: 40 M! cone: 0.1C
1 SS Spike: ui cone:
TRIANGLE LABORATORIES , INC. PAGE 1 OF 1
Dioxin Sample Preparation Tracking & Management Form '
Client: Pacific Environmental Services (PES03)
/ / Method: Method 23:Tetra-Octa
/ / Extraction Date: \fc / *t fi^r

ng/Ml 1 £-Kr" 1 L^fy~ 1
MS Spike: 0 M! cone: 0.0000 ng/fil 1 SH^l"? 1 ^233^31 |
1 ^CS Spike: 0 Ml cone: O.OOOOng/Ml 1 OVf-1 | 0<>\' •flfl*' \
| OPR Spike: 	 20 M! cone: _0.01 	 ng/jil | &-V /C^ Fi£ 1 IS / !i /S9" 1
	 . 	 	 	 	 + 	 + 	 ... 	 . I'D / c« /q'a. i to iCt Aa i
| I TLI / | GROSS | SAMPLE | (Q_ : _QQ | [Q : QO \
|S#.crd| SAMPLE / CLIENT | WEIGHT | SIZE | DJ nq/ul | &.0>ng/gl |
I | ID / SAMPLE ID | Before After | g / ml | t-\'D M! 1 H*Q (il 1
1 1 TLI Blank till -^-Q 1 1
|000 | TLI Blank | | 1^1 -1-^.D 1 1
1 | 185-6-1A-D
|001 | SO -I
| | 18S-6-2A-C
|002 | SO-t
\ 18S-6-3A-C
|u03 | SO-t'
\ 18S-6-4A-C
, 14 | SO-t
\«\T T
Ji^V 111 I 1
Ify \Q\ » 1 1 i 1 '^sv O 1 1
1 1 1 i 1 1 1
23-2 | | II 1)6 1 1
1 ' ' i ' 9x0 ' '
23-3 | | 1 ' 1 \)|3 1 I
1 ' ' i ' na ' '
23-4 | | 1 l I UO 1 1
\ 185-6-5A-B | | | j | --x-^ I I
IS | FB1-M23 | | 1 I I DO 1 1
(Tol Combined)
	 ^_j_, .
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|
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MS !
(>b !
ws !
| | 185-6-6A-C | | III 	 1 1 , \
16 | FB2-M23 | | 1 1 1 J3V^ ' 1 **1 J 1
| | 185-6-7A-C.E
17 | LAB BLANK
| | TLI LCS
1-08 | TLI
1 1 II -xn 1 1
M23 | | ill Dtj 1 1
LCS | | | 1 | ^^ | T>0 |
MS !
Ms !
| | TLI LCSD | | 1 » 1 -\ <--N ' «O ' to £ '
|009 | TLI LCSD | | ill U|j ' V^ b ' ' 1
Matrix :W£5

IChe
ISpi
1 '•
_/_/_! •
_/_/_! "
	 = 	 1 "
nq/ill 1 •

|Any
l
-------
            PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 43432
Ext S#.crd and |
TLI Number |
\ 7 1 . 1 . 1 - 1 . 1 __ 1 n 1 f. 1 1
t Z- i 4/\ i b i ~> i U5 i 9" ' x i " i i
i$ jS&Pt''
TLI Blank | , 'f A*<«J \
001 |
185-6-1A-D |
002 |
185-6-2A-C |
003 |
185-6-3A-C |
004 |
185-6-4A-C |
005 |
185-6-5A-B |
006 |
185-6-6A-C |
007 |
185-6-7A-C.E |
008 |
TLI LCS |
009 |
TLI LCSD |
i
i
i
i
i
i
i
i
i
i
i
i
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3
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i /
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....: .j LI....L.L.I...
i
i
i
i
i
i
1?
i i^ i
$d
I
\
ij

Enter the procedure number below into- the
Initial and date each sample for each num
# 	 PROCEDURE 	 DETAILS
7t) EXTRACTION ON^_ OF
C2» SPIKE AFTER EXTRACTION t^,*O
9 ADD TRIDECANE *°
ROTOVAP 40mL /
^f COMBINE
® DIVIDE / LIPID DETERMINATION 20*/80%
(j) SOLVENT EXCHANGE ^ 	 ^
Q» CLEANUP /'DSP 26£,
(5} TRANSFER
10) ADDITIONAL CLEANUP Mod. DS
11) FINAL TRANSFER
li
1
1
1
1 \
^SSSE&BBSS?
box^at t
bered pro
(circle)
? 	 SJSScKli
5^7)
) / DSP
P 260 /
1 I 1
1 i '
1 1 I
1 / 1
1 .1
+ r *"
1 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1
vV V1
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/ 1
1
1
1
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1
1
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1
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1
1
' i
1
1
1
1
1
1
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^
	 a^^ 	 "V' 	
Vl Al
41..J-1L-

ie top of each column to si
cedure performed.
st / Jar / Sep Funnel / Ste
.x^-vB
BrynesJT
0% 5mL/20mL Other
225 / DSP 115
DSP 225 / DSP
^=,+==-.
jnify the
am Dist /
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
II 1
111 1
111 1
II 1
--— '-" \£J"+ 	 + 	
, 'tf/to/tf ' '
step perfornnsd.
Cont LL / ASE / Waste Dilution
/ DSP 215 / DSP 267 / Other
US / DSP 215 /
DSP 267 / Other

Comments: tOl lt£/W. 3 3 <./ jfZ>/ / f
-------
                                                                  PAGE 1 OF 1
           TRIANGLE LABORATORIES, INC.
          Transfer Chain-of-Custody Form
                  Project 43432

       Transfer  From: DWLH5     To: DMS5

              Initials..    Date	

Released by:   \J' Lfc       J&_l LJ£L.131
                . Sn -^
Accepted by:
                                                         Time. . .

                                                         /'/ **£
         MILES.ID.

         43432-
         43432-
         43432-
         43432-
         43432-
         43432-
         43432-
         43432-
         43432-
         43432-
     -000
     -001
     -002
     -003
     -004
     -005
     -006
     -007
     -008
     -009
              TLI No	  Gust. Id.
TLI Blank
185-6-1A-D
185-6-2A-C
185-6-3A-C
185-6-4A-C
185-6-5A-B
185-6-6A-C
185-6-7A-C,
TLI LCS
TLI LCSD
TLI Blank
SO-I|I23-1
SO-1I23-2
SO-H23-3
SO-IJI23-4
FB1-M23
FB2-M23
LAB BLANK M23
TLI LCS
TLI LCSD
Additional comments or instructions:
                                                      -XfrCOC (Rev 11/01/94)--+

-------
                                                                                                                 PAGE I OF 1
I
|    Method: Method 23:Tetra-Octa  (Tol Combined)
|    Required Detection Limit: 0.05 ng
TRIANGLE LABORATORIES,  INC.
   HR GC/HRMS ANALYSIS
                                                           |PROJECT:   43432
I
    SAMPLE INFORMATION
                                      1ST COLUMN
                                                                             2ND COLUMN
                                                           RS Cone
                                                      20 All a  100.0 PG/jO.
1st.
1
1
|ooo
|001
1
|002
1
|003
1
|004
1
loos
1
|006
|007
1
(008
1
|009
1
1
1
1
I TLI / | GC/MS FILENAME. (CONFIRM | CONFIRM FILENAME (USF-R
crdl SAMPLE ID / CLIENT I COLUMN:U ' x) I ICOLOMllSGs lW~ IVOLOM
1 / SAMPLE ID | ||
| TLI Blank
\ \\<*-\ -xo ' V^>' '
1
1
1
1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 I
1
| Comments :
1
I
1
I
1
1









1
Type: A |
1
1
1
Spike File: SPX23704 I
1
Amt of Extract: 50% |
                                                                                                         -REV 03/07/95  (PSTMF  6)- —

-------
         .time _____ )
Ca-.._;TvL.
                                   _NarL
                                                                                                   luisT
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                                                                                       Signature
                                                                                                                             Date
    Filename
           Date*
Time*
Project^
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
                                                         o
                                                                                            2-3
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                                                                                                                       Page:
                                                                                                                              77

-------
Instrument ID Column Type Column ID Plot Name
^OS ^>^ "l-M-iTBinrf Tov

Ini. Vol. Acquisition QIC
~y A^>X v* — -- i -• / > A h v
Signature Date
Filename
                 Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Dale
Comments**
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-------
. lun L
Instrument ID Column TVPB Column ID
VGTou^ "fc&^r "HSw^iiT*

Plot Name
TOv

Inl.Vol. Acquisition Q/Q
o*..0i-L_ Ej>Cu±i- MftfcfU^.
UUvX. ^ 	 .=M^
Signature Date
Filename
tm^M^
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-------
                                                       Triangle Labc    'es, Inc.
                                                              RUIIL ^
Instrument ID       Column TVPB
                                           Column ID
                                                         Plot Name
                            In). Vol.

                           3. &.!*(?
                                                                            Acquisition
                                                                                         G/C

                                                                                        0 ftJ s
                                                                                         Signa
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                                                                                                                   Date
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Time*
Projed #
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No.
Client Sample ID
Syr
332
Operator/Dale
Comments
'•'I
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                                                           TU
                                                                                                                  'G 7
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                                                        ConCal Due:

-------
                                                           mangle uauoratonca, Inc.
                                                                  Run Log
Instrument ID Column Type Column ID Plot Name Ini. Vol.
~~7(~)~~5 f) ( 5^S ~7v i f£^ 1 ~T& ^— 9 • ® M £—
^^f^Q^y^t'
Acquisition
£ rC-14,5 ^.
^ ^^C^i^L4A--^^\^__^.
Signature
G/C
-- lO~3yf7
Date
    Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments**
                                                                                     Al-D
                                                         2-
                                                                                 §0-10 -13-7J
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*      Transcribed from chromatographic data
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                                          ConCal Due:

-------
                                                          Triangle Laboratories, Inc.
                                                                  Run Log
Instrument ID Column Type Column ID Plot Name Ini. Vol. Acquisition
"2OT" P/3 22.^" ~}?24>(&-f 77~7 X &i/r£ ^.(y^jf^Tr"
-i^'/L
Signature
QIC
K-t&iF—TjT*
Jo //"?•/ f*r>
Date
    Filename
Date*
Time*
Project^
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments*

                                                                                                       J
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-------
                                                                  R- •"' og
Instrument ID        Column Type        Column ID
       V6X
                    Plot Name
                      TTf
                                                                                      In. Vol.
                                                                                      Acquisition
                                                                          / Signature
                                                                                                     G/C
                                                                                                                                 '
                                                                                                                             Date
    Filename
Date*
Time*
                           Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
                 t
                                                                                           1.1.
                                                                              C  v
*     Transcribed from chromatographic data
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                                          ConCal Due:
                                                                                                                       Page:

-------
                                                         Triangle Laboratories, Inc.
                                                                 Run Log
Instrument IP Column Type Column ID Plot Name

Inj. Vol. Acquisition
X2-xlj2-
-------
SAMPLE
  DATA
         Triangle Laboratories, Inc.
  801 CapHola Drive        P.O. Box 13485
  Durham, NC 277134411      Research Triangle Park, NC 27709-3485
  919444-5729           Fax # 919-544-5491

-------
                           TRIANGLE LABORATORIES,  INC.
                     Sample Result  Summary for Project 43432
                      Method  23X Full Screen Analyses (DB-5)
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378- PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HXCDD 478
13C12-HpCDF 789
Other Standards
13C12- HxCDF 789
13C12-HXCDF 234
U973257
TLI Blank
ng
10/09/97
10/17/97
U
XAD


(0.004)
(0.005)
(0.008)
(0.007)
(0.007)
(0.008)
0.04
(0.003)
(0.003)
(0.003)
(0.004)
(0.003)
(0.004)
(0.004)
(0.005)
(0.006)
(0.008)
(0.004)
(0.005)
(0.007)
(0.008)
(0.003)
(0.003)
(0.004)
(0.005)
Percent Recovery
92.5
100
92.3
96.7
91.3
Percent Recovery
68.6
81.4
U973258
SO-23-1
ng
10/09/97
10/17/97
U
M2 3 TRAIN


£0.05}
0.07
0.02
{0.02}
0.03
0.02
0.03 B
2.4
0.36
0.38
0.16
0.07
0.05
(0.006)
{0.07}
(0.01)
{0.01}
2.7
0.84
0.19
0.02
19.1
6.1
0.69
0.04
Summary (% Rec)
93.7
95.6
92.0
98.9
101
Summary (% Rec)
101
112
S976909
SO-23-2
ng
10/09/97
10/23/97
S
M2 3 TRAIN


0.21
0.23
0.07
0.08
0.11
{0.12}
{0.09} B
6.6
1.4
1.4
0.91
0.46
0.26
{0.04}
{0.30}
{0.05}
0.04
6.6
2.4
1.1
0.14
60.0
24.2
4.7
0.10

102
92.0
95.8
85.6
94.6

107
116
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123
13C12-P6CDD 123
79.4
75.4
96.9
86.6
89.8
85.5
78.8
83.7
103
90.5
96.1
103
Page  1
 10/24/97
                                                                           U973260
                                                                           SO-23-3

                                                                             ng
                                                                          10/09/97
                                                                          10/17/97
                                                                              U
                                                                          M2 3TRAIN
                                                                             0.13
                                                                             0.10
                                                                            (0.05)
                                                                            (0.04)
                                                                            (0.04)
                                                                            (0.04)
                                                                            {0.04} B
                                                                             4.5
                                                                             0.65
                                                                             0.47
                                                                             0.18
                                                                             0.09
                                                                             0.05
                                                                            (0.03)
                                                                             0.04
                                                                            (0.05)
                                                                            (0.03)
                                                                             4.1
                                                                             0.74
                                                                             0.24
                                                                            (0.04)
                                                                            51.2
                                                                               7
                                                                               92
   10
    0
                                                                             0.04
                                                                            85.9
                                                                            80.7
                                                                            88.1
                                                                            97.6
                                                                            97.2
                                                                            49.2
                                                                            48.9
                                                                            45.9
                                                                            58.6
                                                                            77.7
                                                                            84.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
   Printed: 13:37 10/24/97

-------
                           TRIANGLE LABORATORIES,  INC.
                     Sample Result Summary  for Project  43432
                      Method 23X Full  Screen Analyses  (DB-5)
                                                   Page  2
                                                    10/24/97
 Data  Pile
 Sample  ID

 Units
 Extraction Date
 Analysis Date
 Instrument
 Matrix
 Extraction Type
 U973257
TLI Blank

   ng
10/09/97
10/17/97
    U
   XAD
 D973258
 SO-23-1

   ng
10/09/97
10/17/97
    U
M23TRAIN
 Internal Standards Percent Recovery  Summary (%  Rec)
 13C12-HXCDF 678     123               111
 13C12-HXCDD 678      94.9              94.1
 13C12-HpCDF 678      92.5              61.3
 13C12-HpCDD 678      87.5              95.0
 13C12-OCDD           84.0              63.5
 S976909
 SO-23-2

   ng
10/09/97
10/23/97
    S
M23TRAIN
                                    120
                                    106
                                     92.4
                                     89.7
                                     63.8
 U973260
 SO-23-3

   ng
10/09/97
10/17/97
    U
M23TRAIN
                                     62.8
                                     61.3
                                     47.5
                                     70.9
                                     89.2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                      Printed: 13:37 10/24/97

-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Method 23X Full Screen Analyses
Data File
Sample. ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HXCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12- HxCDF 478
13C12-HXCDD 478
13C12-HpCDF 789
Other Standards
13C12- HxCDF 789
13C12-HXCDF 234
0973261
SO-23-4
ng
10/09/97
10/17/97
U
M2 3 TRAIN


0.12
0.10
{0.02}
0.03
0.04
{0.03}
0.08 B
4.1
0.61
0.52
0.26
0.11
0.06
(0.01)
0.07
(0.02)
(0.01)
4.6
1.3
0.41
0.03
43.0
11.3
1.2
0.07
Percent Recovery
91.1
95.4
99.0
101
105
Percent Recovery
75.3
82.5
U973262
FB1-M23
ng
10/09/97
10/17/97
U
M23TRAIN


(0.007)
(0.008)
(0.01)
(0.01)
(0.01)
(0.01)
(0.01)
(0.009)
(0.007)
(0.007)
(0.008)
(0.006)
(0.007)
(0.008)
(0.01)
(0.01)
(0.01)
(0.007)
(0.008)
(0.01)
(0.01)
(0.009)
(0.007)
(0.007)
(0.01)
Summary ( % Rec )
85.8
97.7
88.3
94.3
98.3
Summary ( % Rec )
79.9
91.8
43432
(DB-5)
U973263
FB2-M23
ng
10/09/97
10/17/97
U
M23TRAIN


(0.006)
(0.008)
(0.01)
(0.009)
(0.009)
(0.01)
(0.01)
{0.03}
(0.007)
(0.006)
(0.007)
(0.005)
(0.006)
(0.007)
(0.008)
(0.01)
(0.01)
(0.006)
(0.008)
(0.01)
(0.01)
{0.03}
(0.006)
(0.006)
(0.009)

89.0
94.4
95.3
99.6
88.0

93.3
104
Page 3
10/24/97
U973264
LAB BLANK M23
ng
10/09/97
10/17/97
U
M2 3 TRAIN


(0.003)
(0.004)
(0.006)
(0.005)
(0.005)
(0.005)
0.01 B
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.004)
(0.004)
(0.004)
(0.003)
(0.004)
(0.005)
(0.005)
(0.003)
(0.003)
(0.003)
(0.004)

94.1
98.5
93.1
96.8
92.4

95.3
104
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123
13C12-PeCDD 123
69.7
83.5
96.0
110
57.6
86.4
93.5
109
78.9
90.2
87.5
100
85.0
82.3
101
118
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:37 10/24/97

-------
                            TRIANGLE LABORATORIES,  INC.
                      Sample Result Summary  for Project 43432
                       Method 23X Full Screen  Analyses (DB-5)
Page  4
 10/24/97
Data Pile
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Internal Standards
13C12-HXCDP 678
13C12-HXCDD 678
13C12-HpCDP 678
13C12-HpCDD 678
13C12-OCDD
D973261
SO-23-4
ng
10/09/97
10/17/97
U
M2 3 TRAIN

Percent
85.6
87.7
65.1
84.5
95.2
=f as as as a== ss as as
U973262
FB1-M23
ng
10/09/97
10/17/97
U
M2 3 TRAIN

Recovery Summary (% Rec)
110
102
80.5
99.6
99.7
U973263
FB2-M23
ng
10/09/97
10/17/97
U
M23TRAIN


102
101
82.1
94.8
95.1
U973264
LAB BLANK M23
ng
10/09/97
10/17/97
U
M23TRAIN


105
95.7
90.0
102
104
 {Estimated Maximum Possible Concentration},   (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
   Printed: 13:37.10/24/97
13:37

-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project

Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF

X973636
SO-23-1
ng
10/09/97
10/18/97
X
M2 3 TRAIN


0.72
Method 23X (DB-225)
X973637
SO-23-2
ng
10/09/97
10/18/97
X
M23TRAIN


2.3
43432

X973638
SO-23-3
ng
10/09/97
10/18/97
X
M23TRAIN


1.8
Page 1
10/23/97

X973639
SO-23-4
ng
10/09/97
10/18/97
X
M2 3 TRAIN


1.3
 Internal Standards  Percent Recovery Summary (% Rec)
 13C12-2378-TCDF       95.4             102
58.9
87.9
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                  Printed: 23:4
        :4B*p/2

-------
                           TRIANGLE LABORATORIES, INC.                  Page  2
                     Sample Result  Summary for Project  43432            10/23/97
                               Method 23X (DB-225)
 Data File           X973680
 Sample ID           FB2-M23

 Units                 ng
 Extraction Date    10/09/97
 Analysis Date      10/22/97
 Instrument             X
 Matrix             M23TRAIN
 Extraction Type

 Analytes
 2378-TCDF             (0.01)

 Internal Standards Percent Recovery Summary (% Rec)
 13C12-2378-TCDF       81.8

 (Detection Limit).
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713                                    Printed: 23-40 10/23/97

-------
TLI Project:      43432
Client Sample:   TLI Blank
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U973257
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
XAD
TLI Blank

1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
II
10/09/97
10/17/97
n/a
U973257
GG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
A*rfp& ; v * *'£%y ;
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
U,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
U,3,7,8-PeCDF
2,3,4,7,8-PeCDF
U,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
lWalr'^\ f^w;
Total TCDD
Total PeODD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
^;-!|>>B^i^
ND
ND
ND
ND
ND
ND
0.04
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
\*?SlV**SS;'?
ND
ND
ND
ND
ND
ND
ND
ND
XiM*e^if l^^^^l^f:-^!^;
0.004 	
0.005 	
0.008 	
0.007 	
0.007 	
0.008 	
0.90 36:26 	
0.003 	
0.003 	
0.003 	
0.004 	
0.003 	
0.004
0.004
0.005 	
0.006 	
0.008 	
'^^^:\m^^:^'y^f^ > «^*^£;; 7vifc£^
0.004
0.005
0.007 	
0.008 	
0.003 	
0.003
0.004
0.005
                                      Page 1 Of 2
                         X237_PSRvlOOl LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 20:00 10/21/97

-------
     w
                                                                   ,- .", -t   -  A   -    .
TLI Project:
Client Sample:
                      43432
                      TLI Blank
      Method 23 PCDD/PCDF Analysis (a)
                     Analysis File:   U973257
 Internal Standards
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C.2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
                                   3.2
                                   3.0
                                   3.9
                                   3.5
                                   4.9
                                   3.8
                                   3.7
                                   3.5
                                   6.7
 79.4
 75.4
 96.9
 86.6
123
 94.9
 92.5
 87.5
 84.0
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.77
0.80
1.43
1.50
0.50
1.26
0.42
1.02
0.77
21:32
22:27
26:16
27:28
30:14
30:59
33:01
33:53
36:26
 SuiTogatfl Standards 
-------
                        Initial
                                      Date..
 Data Review By:
                                              Calculated Noise Area:
                                             2.59
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
Listing of  U973257B.dbf
Hatched GC  Peaks / Ratio / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306

304-306
13C12-TCDF
316-318





316-318
0.65-0.
DC
DC

NL
SN
0
0:00
18:55
Peaks
0
RO 0

.86
.55

0.65-0.
DC


DC



NL


SN


4
0:00
21:03
21:32
21:53
22:06
22:27
Peaks
RO 0
0
0
RO 3
0
RO 0

.93
.72
.77
.46
.71
.99

89
14
21
0
89
1
45
7,668
10
81
33
7,829
0.813-1.106
.56
.17
.00
0.
0.

000
878

0.954-1.046
.82
.19 18.91
.75 3,328.24
.73
.38 33.71
.93 18.99
.25
0.
26.28 0.
4,340.51 1.
1.
47.67 1.
19.17 1.

000
978
000 13C12-2378-TCDF ISO
016
026
043


TCDD
320-322







320-322
37C1-TCDD
328















0.65-0.
DC
DC
DC
DC
DC
DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN
0
0:00
19:15
20:45
21:31
22:22
22:30
22:47
23:28
Peaks
RO 1
RO 1
RO 4
RO 1
RO 0
RO 0
RO 1
0

.18
.32
.96
.11
.52
.26
.63
.75

nhsww i * wwf / AV»W f WA AWIVV — ~~™
89
2
0
0
6
1
6
1
3
0
.42
.94
.94
.99
.93
.55
.19
.93
.00
0.848-1.061
0.
0.
0.
0.
0.
1.
1.
1.

000
857
924
958
996
002
015
045

0.911-1.089
DC



DC

DC


DC

DC
DC
DC

DC
NL



SN

SN


SN

SN
SN
SN

SN
0:00
20:43
22:28
22:48
22:53
22:58
23:03
23:11
23:18
23:22
23:28
23:38
23:46
23:51
23:59
24:11
































0
23
5,076
13
8
13
7
13
16
5
17
10
6
10
11
6
.97
.95 23.95
.57 5,076.57
.46 13.46
.86
.40 13.40
.92
.02 13.02
.16 16.16
.52
.39 17.39
.26
.77
.42
.27 11.27
.45
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
923
001 37C1-TCDD SDR1
016
019
023
027
033
038
041
045
053
059
062
068
077
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 20:00 10/21/97

-------
 Page No.
 10/21/97
Listing of O973257B.dbf
Hatched GC Peaks / Ratio / Ret. Tim*
 Compound/
 M_Z	QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area. Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.
328
13C12-TCDD
332-334










332-334

PeCDF
340-342






340-342
13C12-PeCDF
352-354










352-354
DC

DC




DC
DC

DC
DC
DC



DC
DC
DC
DC
DC
DC
DC


DC

DC


DC




DC

SN
8

NL




SN
SN

SN
SN
SN
5


NL
SN
SN
SN
SN
SN
SN
0

NL

SN


SN




SN
7
24:14
Peaks

0:00
21:00
22:14
22:27
22:53
23:02
23:08
23:41
23:51
23:58
24:12
Peaks


0:00
24:06
25:17
25:43
26:14
27:18
27:27
Peaks

0:00
25:19
25:52
26:16
26:35
26:50
27:05
27:26
27:36
27:48
28:03
Peaks

0.
RO

5,
5
185
.36
.22
65-0.89
1.
99
0.88


RO
RO
RO
RO
RO
RO
RO


1.

RO
RO
RO
RO
RO
RO

1.
RO

RO


RO

RO
RO
RO
RO

0.
0.
0.
0.
4.
1.
0.
0.
1.


82 6,
80 5,
95
63
21
04
42
54
50
12.
, __
32-1.78
1.
1.
3.
0.
1.
0.
0.

33
21
92
81
95
45
18

3
36
952
811
137
16
8
46
21
24
15
984
.54
.73 17.21
.75 3,134.57
.53 2.588.02
.39 73.82
.99
.99
.41 27.26
.61
.44
.74
.81

0.

19.52
3,818.18
3,223.51
77.62


26.22




1.
079
911-1.089
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.

000
935
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
019
026
030
055
062
068
078



7
4
11
5
12
2
0
0
.75
.56
.65
.81
.55
.55
.94
.00
32-1.78
0.
1.
2.
1.
1.
8.
1.
0.
0.
1.
0.

97
68
12
43 7,
72
63
48 7,
52
55
04
69
14.
2
117
15
371
88
9
170
23
22
23
9
818
.11
.04 73.34
.38
.87 4.337.08
.99 56.33
.08
.47 4,283.39
.90 14.53
.60 13.74
.64 14.37
.38
.51
0.








0.

43.70

3,034.79
32.66

2,887.08
28.03
25.14
13.78


906-1.077
0.
0.
0.
0.
0.
1.
1.

000
918
963
979
999
039
045

848-1.152
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.

000
964
985
000 13C12-P«CDF 123 IS2
012
022
031 13C12-PeCDF 234 SUR2
044
051
058
068


PeCDD
356-358






DC
DC
DC
DC
DC
DC

NL
SN
SN
SN
SN
SN

0:00
25:29
26:16
26:36
26:46
28:07
1.

RO
RO
RO
RO
RO
32-1.78
1.
0.
1.
1.
2.
0.
61
26
94
18
11
67
2
2
5
2
2
1
.51
.42
.97
.88
.70
.45
0.921-1.025






0.
0.
0.
0.
0.
1.
000
928
956
968
975
024
Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
 Page No.
 10/21/97
Listing of U973257B.dbf
Hatched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z	  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Coropound.Name..  ID.. Flags.
356-358
13C12-PeCDD
368-370








368-370
HXCDF
374-376

374-376
13C12-HXCDF
384-386







384-386
HxCDD
390-392






390-392
DC WH 28:13
DC WH 28:19
DC WH 28:29
0 Peaks
DC NL 0:00
DC SN 25:20
DC SN 25:56
DC SN 26:16
DC SN 26:37
DC SN 27:06
DC SN 27:13
27:28
27:38
DC SN 27:51
27:59
28:14
DC SN 28:22
DC SN 28:29
4 Peaks

DC NL 0:00
DC SN 30:47
0 Peaks

DC NL 0:00
30:07
30:14
30:21
30:26
30:28
30:46
31:30
7 Peaks

DC NL 0:00
DC SN 30:02
DC SN 30:08
DC SN 30:14
DC SN 30:46
DC SN 30:53
DC WH 31:31
0 Peaks
RO
RO
RO
1.
RO
RO
RO
RO



RO
RO
RO
RO
RO

1.

RO

0.




RO
RO


2.08
1.18
0.55
32-1.78
1.27
1.54
1.42
0.92
3.95
1.84
1
1
1
2
0
1
2
2

.43
.50 3
.49
.33
.83
.04
.71
.31
4
05-1.43
1
1

.21
.02

1.
3.
0.
0.
2.
3.
2.
7.
2.
6.
2.
,610.
407.
17.
24.
22.
12.
19.
56
49
99
00
04
20
40
81
86
83
92
79 2,168.94
88 244.22
93
35 14.80
08 13.42
57
53
0.

1,441.85
163.66

17.93
12.89


1.027
1.031
1.037
855-1.145
0.000
0.922
0.944
0.956
0.969
0.987
0
1
1
1
1
1
1
1
.991
.000 13C12-P*CDD 123
.006
.014
.019
.028
.033
.037

IS3






,065.10

8.
9.
0.
78
12
00
43-0.59
0
0
0
0
1
0
0
0
.54
.52 4
.50 5
.51
.16
.89
.51 3
.50 2
85.
,902.
,452.
61.
32.
42.
,387.
.685.
95
39 1,675.31
11 1,811.01
72 20.89
80 25.27
78 25.29
59 1,150.74
45 898.85
0.



0.

3,227.08
3,641.10
40.83
21.72
28.33
2,236.85
1,786.60
958-1.051
0
1

.000
.018 234678-HxCDF


AN

868-1.132
0
0
1
1
1
1
1
1
.000
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.004
.007
.008
.018 13C12-HXCDF 234
.042 13C12 -HXCDF 789

SOR3
IS4



ALT2
ALT1
16,564.84
.___ KluH*M . Uu**n« 1 u.^*v%v\ -B.1 1 ,_^».
1.

RO
RO
RO
RO



05-1.43
1
1
1
1
1
1
1

.17
.45
.96
.78
.72
.36
.15

5.
1.
6.
5.
4.
3.
3.
0.
68
05
63
64
82
82
21
00
0.








952-1.015
0
0
0
0
0
0
1

.000
.969
.973
.976
.993
.997 123478-HxCDD
.017






AN


Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:00 10/21/97

-------
 Page No.
 10/21/97
Listing of 0973257B.dbf
Hatched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.
13C12-HXCDD
402-404








402-404

HpCDF
408-410





408-410
13C12-HpCDF
418-420




418-420

HpCDD
424-426



424-426
13C12-HPCDD
436-438



436-438

OCDP
442-444

1.05-1.43
DC NL 0:00 1.25
DC SN 30:20 RO 0.91
30:53 1.26 3
30:59 1.26 3
31:11 RO 2.25
31:17 1.22 4
31:27. RO 2.89
31:32 RO 0.96
DC SN 31:37 RO 6.88
6 Peaks 11

0.88-1.20
DC NL 0:00 1.16
DC SN 33:01 1.14
DC SN 33:21 RO 1.50
DC SN 33:37 RO 2.30
DC SN 33:50 RO 0.73
DC SN 33:55 RO 2.89
0 Peaks
0.37-0.51
DC NL 0:00 RO 0.59
33:01 0.42 3
33:12 RO 0.57
33:25 RO 0.55
34:14 0.41 2
4 Peaks 6

0.88-1.20
DC NL 0:00 RO 0.85
DC SN 33:17 1.14
DC SN 33:53 RO 0.78
DC WH 34:14 1.13
0 Peaks
0.88-1.20
DC NL 0:00 RO 0.85
DC SN 33:17 1.13
33:53 1.02 3
34:04 0.88
2 Peaks 3

0.76-1.02
DC NL 0:00 0.90
DC SN 32:59 RO 0.38

5.70
16.91
,174.01
,660.40
57.48
,011.35
31.79
101.45
18.66
,036.48


7.87
17.17
11.22
4.04
3.37
1.31
0.00

18.78
,536.24
88.57
58.77
,850.98
,534.56


3.83
14.41
14.26
7.42
0.00

9.81
12.93
.220.59
152.18
,372.77
LJnpnn / fy
nft^uu i \JG
6.75
6.39
0.968-1.032
0.000
0.979
1,768.08 1,405.93 0.997 13C12-HXCDD 478
2,038.93 1,621.47 1.000 13C12-HXCDD 678
57.69 25.66 1.006
2,204.68 1,806.67 1.010 13C12-HXCDD 789
41.00 14.19 1.015
56.16 58.77 1.018
1.020


0.996-1.043
0.000
1.000 1234678-HpCDF
1.010
1.018
1.025
1.027

0.939-1.121
0.000
1,050.52 2.485.72 1.000 13C12-HpCDF 678
35.25 61.51 1.006
22.50 40.81 1.012
822.48 2,028.50 1.037 13C12-HpCDF 789


0.977-1.005
0.000
0.982
1.000 1234678-HpCDD
1.010

0.971-1.029
0.000
0.982
1,623.47 1,597.12 1.000 13C12-HpCDD 678
71.32 80.86 1.005


0.890-1.110
0.000
0.905



SUR4
IS5

RS2







AN







IS6


SDKS





AN





IS7






Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:00 10/21/97

-------
  Pago No.
  10/21/97
Listing of U973257B.dbf
Matched GC Peaks /  Ratio /  Ret. Time
 Compound/
 M_Z	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak. 1..  Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
 442-444
 OCDD
 458-460
 458-460

 13C12-OCDD
 470-472

 470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC

DC
DC


DC


SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL

SN
SN
1

NL

1
35:17
35:26
35:42
35:43
36:32
36:58
37:09
37:20
37:39
37:45
38:36
38:45
Peaks

0:00
36:26
36:36
36:53
Peak

0:00
36:26
Peak
RO

RO
RO

RO
RO
RO
RO

RO
RO

0.



RO

0.
RO


1
1
3
2
0
0
0
2
1
0
1
0

.21
.00
.72
.02
.82
.40
.68
.10
.81
.89
.16
.58

76-1.02
0
0
0
1

.86
.90
.84
.84

76-1.02
0
0

.70
.77

                                                 7.65
                                                 5.61
                                                 1.02
                                                 0.83
                                                15.04
                                                  .04
                                                  .61
                                                  .91
                                                  .57
                                                  .80
                                                  .95
                                                  .76
                                                 0.00
                                                7.59
                                               26.40
                                                3.90
                                                3.57
                                               26.40
                       3.53
                   5,141.90
                   5,141.90
                                                        0.968
                                                        0.973
                                                        0.980
                                                        0.980
                                                        1.003 OCDF
                                                         .015
                                                         .020
                                                         .025
                                                         .033
                                                         .036
                                                         .059
                                                                                                       AN
                                                                                 1.064
                                                                             0.890-1.110
                                   12.50
                                                 13.90
                       0.000
                       1.000 OCDD
                       1.005
                       1.012
                                                                             AN
2,243.66
      0.995-1.005
          0.000
2,898.24  1.000 13C12-OCDD
                                             IS8
 Column Description.
       •Why  Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time (ram:33)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO'Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report
       WL-Below Retention Time Window
       HH-Above Retention Time Window
       SN-Below Signal  to Noise Level
       
-------
 'llatU973257 #1-1024 Acq:17-OCT-1997 15t44i3S OC EI+ Voltage SIR 70S SOiB«t3362
303.9016 Ps2 BSUB(aS6,30,-3.0) PO3(9,5,3t 0.10*, 13448. 0,1. OOX,F,V) ExptEPCUSS
 •RIAKOLB LABS  TextiTil BLANK  TLIit43432
100*               A9.21E4
       18(00         19:00        20:00         21:00        22:00        23:00
Plla:U9732S7 11-1024 Acgtl7-OCT-1997 15:44:35 OC BI+ Voltage SIS  70S Xoinai3922
305.8987 ft2 BSOB(256,30,-3.0) PKD(9, 5,3,0.10%, 15688. 0,1.00\,P,T) Exp:EPCUS2
TRIASOLB LABS  TmxttTLI BLANK  TLH43432
       18:00         19:00        20:00         21:00        22:00        23tOO
fllmtU9732S7 tl-1024 Acqtl7-OCT-1997 15:44:35 OC EI+ Voltaffa SIR 70S tfoisat482
315.9419 fi2 BSVB(256,30,-3.0) PXHI9,5,3,0.101,1928.0,1.00f,P,T) Exp:EPCUS2
TRZAOOLS LABS  TfXt*TLI BLANK  TLX#43432
IOCS
 80:
 601
 40:
   oj
                                                      A3
                                                           IS7
       18(00         15(00        20(00         21(00        22(00        23(00
Pll»iU973257 tl-1024 Acq:17-OCT-1997 15t44t35 OC EH- Voltayt SIR 70S Nola»:516
317.9389 Fl2 B3UB(256,30,-3.0) PKD(9,5,3,0.10*,2064.0,1.00*,P,T)  Exp:EPCU33
TRIASOLX LABS  fncttTLI BLANK  TLH43432
1005
 80:

 40:
 20:
  0.
                                                      A4
                                                         J4E7
        18:00        19:00         20:00        21(00        22(00
Pilu:U973257 tl-1024 Aoqtl7-OCT-1997 15t44>35 OC EH- Voltagt SIR 70S
330.9792 P:2 Exp:EPCU32
TRIANOLS LABS  TextlTLI BLANK  7LIH43432
                                                                           23*00
 1009
  00:
  60:
  40:
  20:
   0.
     17:48   18(22 18:46
                                                                                        24 tOO
                                                                                                  Time
                                                                                        24 tOO
                                                                                                 oso
                                                                                                  Via*
                                                                                                 IBS
                                                                                                 9E6
                                                                                                 7S6
                                                                                                 4E6
                                                                                                 2S6
                                                                                                .OEO
                                                                                        24100
                                                                                        24(00
        18,00        19:00        20:00         21:00        22(00
Pll»tU973257 tl-1024 Acqt 17-OCT-1997 !Si44,35 OC EH- Voltagm SIR 70S
375.8364 P:2 SxptBPCUS2
TRXANOLg LABS  TaxtlTLI BLANK  TLXt43432
1003
  80:
  60:
  40:
  20:
   o:
                                                                           23 tOO
                                                                                        24 tOO
 ass
 2S6
.7E6
.1X6
.6X6
.0X0
  Time

.1X7
.9X6
.6X6
.4X6
.2X6
.0X0
  Tim»
                                                                                              ..3.SE4
              18'37  T5 igta                  aogi               "I"   23,04          -   f-.«
       t^^^M^^L^^                                                                 r'
        18(00
                                                                                               -.7.1X3
                      19100
                                   20:00
                                                21 tOO
                                                             22100
                                                                           23 tOO
                                                                                                . oso
                                                                                                  Tlm«

-------
Plle*U973257 #1-1024 Acq*17-OCT-1997 15*44*35 OC EI+ Voltage SIR  70S
319.8965 P*2 BSUB(256,30.-3.0) PXD(7, 5,3,0.10X, 3244.0,1. 00*,F,T)  Exp,EPCUS2
TRIASOLS LABS  TexttTLI BLANK  TLIJ43432
                   20tOO             21(00             32:00             23*00
Pll»*U973257 *1-1024 Aoq*17-OCT-1997 15t44s35  OC BI+  Voltage SIR 70S Soil*:687
321.8936 P*2 BSOB(2S6,30,-3.0) PXO(7,5,3t0.10\,2748.0,1.00*,P,T) Exp:EPCUS2
TSIASOLS LABS  TfXttTLI BLASK TLH43432
2004                                                            AJ.08E5
                   20,00             21iOO              22tOO             23tOO
Pll»:U973257 91-1024 Acqtl7-OCT-1997 15:44:35 OC ZI+ Voltage SIR 70S Noli*il992
331.9368 P:2 B3U3(256,30,-3.0)  PKH(7,5,3, 0.10\, 7968. 0,1. 00*,P,T) SxptBPCU32
TRIANOLE LABS  Tmxt:TLI BUHK  TLI»43432
                                                                                                    .1.4E4
                                                                                             24100
                                                                                             24100
1003

  00:

  so.

  40.

  20:
                                                          A3.13B7
                                                             \A2.59B7
                   20,00             21,00              22,00             23,00
Fll»tU973257 11-1024 JLcytn-OCT-1997 15,44:35 OC BI+ Voltag* SIS 70S SOll»t998
333.9338 Pt2 BSVB(256,30,-3.0)  PXD(7,5,3,0.10*,3992.0f1.00*,P,T) Sxp,SPOJ33
TRUUtOLB LABS  TmxttTLI BLUR  TLXf43432
loan
                                                                                             24 tOO
                   20(00             22(00              22(00             23(00
Plle*U973257 11-1024 Acq*17-CCT-1997 15*44*35 OC XI* Voltage SIS 70S No±*e*48S
327.8847 P*2 BSOB(256,30,-3.0)  PKD<7,5,3, 0.10*, 1940.0,1.00*,P,T) Xxp,EPCUS2
TRIANOLE LABS  TextlTLI BLASK  TLI143432
                                                                                             24*00
 100*

  so:

  ffo:

  40:

  20.

   0.
                                                               AS
                                                                   08B7
                   20<00             21(OO              22(00             23tOO
F11»,US73257 tl-1024 Acqtl7-CCT-1997 15,44,35 OC Sl-f Voltagt SIS 70S
330.9792 P,2 Sxp,SPCU32
TSIASOL8 LABS  TmxttTLI BLUOT  TLH43432
       19*21  19i45_ 2.0*07   20*33 20*51     21*23  21*48      22*23   22*50
100J
 00:
 60:
 40:
 20:
  o.
                                                                                            24100
                   20*00
                                     21*00
                                                        22*00
                                                                          23*00
                                                                                             24*00
-6.2B6

-4.9S6

.3.7E6

.2.SSS

.1.2E6
                                                                                                     .0.050
                                                                                                        Tin*
A3.B3B/
1,
22B7
\
                                                                                                    7.7B6

                                                                                                    S.1SS

                                                                                                    4.6E6

                                                                                                    3.1B6

                                                                                                    1.5E6

                                                                                                    O.OSO
                                                                                                       Tim*



                                                                                                    .1.0S7

                                                                                                    .8.2ES

                                                                                                    .6.2S6

                                                                                                    .4.1X6

                                                                                                    .2.1S6

                                                                                                    .0.0*0
 .1.0X7

 .8.2X6

 .6.2X6

 .4.1X6

 .2.1X6

 .0.0X0
    Tim*


-------
 'Iloi0973257 #1-1024 Acqtl7-OCT-1997 15:44:35 OC EH- Voltago SIR 70S NolB»t2210
 \39.8S97 Ft2 BSUB(2S6,30,-3.0) PKD(7,5,3,0.10^,8840.0,1.00*,F,T) ExptEPCUS2
TRXANOLE LABS  ToxtiTLI BLANK 713*43432
100H
    24100              25tOO             26tOO              27:00              28s00
Pilot0973257 #1-1024 Acqt17-OCT-1997  15i44i35 OC EH- Voltage SIR  70S Nol*o:1663
341.8S67 Ft2 BSUB(25S,30,-3.0)  PKD(7,5,3,0.10*,6652.0,1.00*,P,T) BacptSPCns2
TRIANOLX LABS  ToxttTLZ BLANK  TLI943432
100*                    A7  3S4
     24100              25  0             26tOO              27*00              28tOO
Fll*t09732S7 91-1024 A&jt 17-CCT-1997 15t44i3S OC Eli- Voltagt SIS 70S Nolm»t641
351.9000 Ft3 BSUB(256,3Q,-3.0)  PKD(7,5,3,0.101,3564. 0,1. 00*,P,T)  ErpiEPCUS2
TRIANOLS LABS  ToxtiTLI BLANK  TLIf43432
 ion
  80.

  SO.

  40:

  20.
                                            14.34E7
     24.100              25100             26tOO              27iOO              28tOO
Fil»iU973257 tl-1024 A.CXJ: 17-OCT-1997 15t44t3S OC SI+  Voltagu SIS 70S Nolt»t6S8
353.8970 ft2 B3UB(256,30,-3.0) PKD(7,5,3,0.10*,2632.0,1.00*,P,T)
TRIASQIiB LABS  TmxtiTLX BLANK  TLIS43432
100%
Pll»iU973257 91-1024 Aegil7-OCT-1997 15t44i35 OC BI+  Voltayt SIR 70S
330.9792 Ft2 S*ptSPCUS2
TRIASOLS LABS  ToxttTLI BLANK  TLX#43432
  40:
  20.
   o:
                                                                                             .1.0X7

                                                                                             .7.6X6

                                                                                             '.5.0X6

                                                                                             .2.5S6

                                                                                              0.0X0
A3.03E7 A3. 89X7
I 1


11 11
24tOO 25(00 26:00 27(00 28\00
-8.5X6
.6.8X6
'-.5.1X6
-.3.4X6
-.1.7X6
0.0X0
Tlaa
                                                                       37t31
                                                                                 28t03
                                                                                             -9.8S6

                                                                                             -.7.8X6

                                                                                             .5.986

                                                                                             .3.9X6

                                                                                             -.2.0X6
    24t00              25tOO              26tOO              27:00
F11»:U973257 91-1024 Acytl7-OCT-1997 15:44:35 OC Eli- Voltage SIR 70S
409.7974 Ft2 Exp:EPCUS2
TRIASOLX LABS  TmxtiTLX BLANK TLX943432
100H                                                    (
                     24:52 25(11
SO.

40.

20:

 0.
                                                                                28tOO
                                                                                              0.0X0
                                                                                                 Tim*
     24100
                        25\00'
                                           26:00
                                                           27:OO'
                                                                                               -3.3X4

                                                                                                .2.6X4

                                                                                                '-.2.0X4

                                                                                                -.1.3X4

                                                                                                -.6.6X3
                                                                                28:00
                                                                                               LO. 0X0
                                                                                                   Wa.

-------
 'llatQ973257 tl-1024 AcqiU-OCT-1997 15,44,35 OC SI* Voltage SIR  70S SoiS»t777
 55.8546 Pi2 BSUB(256,30,-3.0) PKD(S,5,3,0.OS\,3108.0,1.00*,P,T)  ExptEPCUSl
TRIAKOLS LABS  ToxtlTLI BLANK  TLI143432
100*           A3. 5E4
                     26iOO                         27:00                         28'tOO
Fllu,U973257 91-1024 Aatjtl7-OCT-1997 15i44t35 OC SI* Voltaffm SIR  703 Noie»,482
357.BS16 Pt2 BSVB(2S6,30,-3.0) PKD(5,5,3,O.OS\, 1928.0,1.00\,P,T)  ExpiEPCUS2
TRIANOLB LABS  TtatttTLI BLUOC TLXI43432
100*A5.61E4
                     36,00                         37 tOO                         20100
Pil»tU973257 01-1024 Aeqtl7-OCT-1997 15144,35 OC Sit- Voltafff SIR 703 Nod.f»,618
367.8949 fi2 BMUB(2Sf,30,-3.0) PXD(5,5,3,0.05\.2472.0,1.00*,PtT)  Exp,EPCVS2
TRULXOLB LABS  TwctiTLI BLABX TLXI43432
10A                                                            A2.J.7S7

  80.

  60.

  40.

  20.
                     36,00                         27,00                         28,00
Pilm,U973257 01-1024 Aaqtl7-OCT-1997 15,44,35 OC SI* Voltaffm SIR 70S Nols»,492
369.8919 Pt2 BSOB(256,30,-3.0)  PKD(5,S,3,O.OS\,1968.0,1.00*,P,T) Sxp,EPCUS2
TRIASOLS LABS   TuxttTLI BLASK  TLI143432
200JI                                                            A1.44S7
  80.

  60.

  40.

  20:
                     26,00                         27,00
Fllf,0973257 #1-1024 Acq,17-OCT-1997 15,44,35 OC SI* Voltajr* SIR 70S
330.9792  Ft2 Exp,BPCVS2
TRXASOLX  LABS  TuxttTLI BLAOC  TLIf43432
          25,36        .   26,0826,19
     '  yV^vVvx^~'WvWVV\  '
  soJ

  60.

  40.

  20.

   0.
                                                                                 28100
.6.5X6

.5.2X6

.3.9X6

.2.6E6

.1.3X6

 0.0X0
                      36,00
                                                   27tOO
 4.4E6

 3.6E6

 2.7X6

 1.BE6

 8.9S5

 .O.OSO
    Time



 .9.7S6

 .7.8X6

 .5.8S6

 .3.9X6

 .1.9X6
                                                                                 28100
 0.0X0

-------
Pllf:ff973357 #1-404 Acq:17-OCT-1997 15:44i3S QC EH- Voltage SIR 703 NOlBa:3400
373.8208 P:3 BSVB(256, 30,-3.0) PKD(7,5,3,0.10*,9600.0,1.00*,F,T) ExpiEPCUS2
TRIASOLS LABS  ToxttTLX BLANK  TLI043432
IOCS

 so:
   29:00                        30:00                       31:00
Fll«iU973257 #1-404 Aaq:17-OCT-1997  15:44:35 OC EI+ Voltaffa SIR 70S Nolsa:lS8B
375.8178 P:3 B3VB(256,30,-3.0)  PKD(7,5,3,0.101,7953.0,1.00X,P,T) Exp:BPCUS2
TRIASOLB LABS  TrnxttTLI BLANK   TLI043432
100%                                                A4.33E4

 so:

 sol

 40:

 201
   29:00                        30:00                       31iOO
Pi.l»:U973257 91-404 Aaqt 17-OCT-1997  15:44:35 OC SH- Voltago SIR 70S Noll*: 15100
383.8639 Pi3 BSUB(3S6,30,-3.0)  PKD(7,5,3,0.10*, 60400.0,1. 00*,P,T) Bxp:EPCUS3
TRIANOLX LABS  TvcttTLI BLANK  TLI*43432
100H                                 Al. 8.1X7
                                                                                         32:00
                            A2.45E4
                                                                                               .3.4S4

                                                                                               12.7S4

                                                                                               .2.0B4

                                                                                               .1.3S4

                                                                                               .6. 7S3
                                                                                         32:00
  00:

  60-

  401

  aoj
A1.15S7
                     A8.99BS
                                                                                                0. OSO
                                                                                                   Time
                                                                                               .6.1E6

                                                                                               .4.8E6

                                                                                               .3.6S6

                                                                                               13.4S6

                                                                                               ''.1.2E6
   39100                        30:00                       31:00
Pll»:U973257 #1-404 Aaqt17-OCT-1997 15:44:35 OC ST* Voltaff* SIR  70S Noia»:27876
385.8610 P:3 B3US(2S6,30,-3.0)  PXD(7.5,3,0.10*,111504.0,1.00*,P,T)  S3Cp:BPCU32
     aLX LABS  TtactlTLI BLANK  TLI*43432
1003C
                                                                                         32100
                                                                                                0.050
                                                                                                   Tima
A3.S4B7
ft n
M A2.24E7
A A1.79B7
A
V A
7 V v. ; V / V
.1.2E7
.9.7B6

.7.3E6
.4.9ES
.3.4E6

   29:00                        30:00                        31:00
Pll»iU973257 01-404 Acytl7-OCT-1997 15:44:35 OC BH- Voltage  SIR 70S
392.9760 P:3 Exp:EPCUS2
TRIANOLE LABS  TvxtlTLI BLANK  TLZ#43432
      29:05  29:19   29:35    29:54 30:0730:18       30:43
                                     32:00
  ao:
  #o:
  40:
  20:
   o:
                                                               31:06   31:22
                                                                                31:39
                                           _5.4E6

                                           14.3ES

                                           13.2B6

                                           .2.1B6

                                           .1.1S6
                                 ~r
   25(00                         30iOO                        31>00
Pll»:U973257 01-404 Acq:17-OCT-1997 15:44:35 OC ET+ VoltafiT* SIR 703
445.7555 P:3 Exp:BPCUS3
TRIANOLS LABS  TfXt:TLI BLANK   TLI043432
100H                                                         .....
              29:24 10.1*                30:19       30:46  I  I     31«17
                                                                                         32:00
                                           tO.OBO
                                               Tiom
   29:00
                                30:00
                                                             31:00
                                                                                          32:00

-------
 'li«*V973357 91-404 Acq: 17-OCT-1S97 15*44*35 OC EZ+ VOltaffB SIR 70S NoiS0,1531
389.8156 P:3 BSVB(256,30,-3.0) PKD(7,5,3, 0.10*, 6124.0,1.00X,F,T) Exp:EPCU32
 'RIANOLE LABS  TuxttTLI BLANK  TLH43432
100H                      A5.81S4
     29:36   29*48    30,00   30*12    30*24    30*36   30:48    31*00   31*12   31*24
Pil»*U973257 11-404 Aag*17-OCT-1997 15*44*35 OC EH- Voltagm SIR 70S Noil*: 1310
391.8127 P:3 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,5240.0,1.00*,P,T) ExptSPCVS2
TRIANGLE LABS  TmxttTLI BLANK  TLH43432
                               6S4
     29*36    29i48    30*00   30*12    30*24   30*36   30:48    31*00   31*12   31*24
Fll»*U973257 tl-404 Acq, 17-OCT-1997 15*44*35 OC ZT+ Voltago SIS 703 Noie»:1586
401.8558 P:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,6344.0,1.00*,P,T) Exp:SPCU32
         LABS  TfXttTI,! BLANK  7LIt43432
100H                                                          i3.a*B7     A2.30S7
                                                                                         31:36
                                                                                         31:36
  80.

  60.

  40.

  20.
                                                          41.77.
     29,36    29*48   30*00    30*12    30,24   30*36   30*48    31*00   31*12    31*24    31*36
Pil*:U973257 #1-404 Acq*17-OCT-1997 15,44*35 OC EH- Voltay» SIR 70S Soi*»*1264
403.8529 P,3 BSVB(256,30,-3.0)  PKD(7,5,3,0.10*e505t.O,1.00*,P,T) Sxp,XPCU32
TRIANGLE LABS  T*Xt:TLX BLANK  TLIt43432
 1001

  80.

  60.

  40.

  20.
                                                             A1.62E7
                                                                          A1.81S7
                                                         A1.41E1
     29*36   29,48    30*00   30*12    30*24    30*36   30*48    31*00
Pile:U973257 #1-404 Acq:17-OCT-1997 15*44*35 QC XI* Voltagm SIR 70S
392.9760 P,3 BxptBPCUS2
TRIANGLE LABS  TmxtiTLI BLANK  TLH43432
100X29(35   39,45 29{54^  30*07  30*18 30,37
                                                                                 31124
                                                                                         31*36
                                                                                                       Time
                                                                                                    7.5S6

                                                                                                    6.0E6

                                                                                                    4.5X6

                                                                                                    3.0X6

                                                                                                    1.5X6

                                                                                                    0. 0X0
.6.3E6

.5.0X6

.3.8X6

.2.SE6

.1.3E6
                                                                                                    ,0.050
                                                                                                        Time
  so:

  eo:

  40.

  20.

   0.
    ®Z^^^
.5.3X6

".4.2X6

.3.2X6

.2.1X6

-1.1X6
      29*36   29*48
                      30,00
                               30,12   30,24   30*36    30,48
                                                                31,00    31*12
                                                                                 31,24
                                                                                         31,36
                                                                                                    0.0X0
                                                                                                       Tim,

-------
 •lla:U973257 #1-596 Acqtl7-OCT-1997 15(44(35 OC BH- Voltage SIR 70S Noino:2117
407.7818 Pi4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*,846B.O,1.00X,J?,T) ExptEPCUS2
 •SIANGLE LABS  TfUCtsTLI BLANK  TLI«43432
100H  A9.J.4E4
      33tOO     33t12     33i24     33>36     33(48     34:00    34il2     34:24
Pilu:U9732S7 91-596 Acy: 17-OCT-1997 15t44t35 OC BH- Voltaff* SIB 709 Hole*11820
409.7789 Pi4 BSUB(2S6,30,~3.0) PKD(7,S,3, 0.10\,7280.0,1.00*,P,T) ExplSPCUS2
TRIANGLE LABS  TmxttTLI BLANK  TLI#43432
loon
      33»00     33s 12     33:24     33:36    33:48     34:00    34.112    34:24
Pllm:U9732S7 *l-596 Acq:17-OCT-1997 15:44:35 GC SH- Voltagt SIS 70S Koita:3867
417.8253 P*4 BSUB(256,30,-3.0) PKD(7,5,3,0.10^,15468.0,1.00\,P,T) Exp:BPCU32
TRIANOLB LABS  TfXttTLI BLANK TLHf43432
lOOSt  A1.05E7
                                                                                    34:36
                                                                                    34:36
 so:
 fffl:
 40:
 20:
   OJ
                                                                 A8.22S6
       33:00    33:12     33:24     33:36    33:48     34:00     34:12    34:24
Pil»:U973257 tl-596 Acgi 17-OCT-1997 15:44:35 OC BH- Voltag* SIR 70S Nola»:6S22
419.8220 Pi4 B3UB(2S6,30,-3.0)  PXD(7,5,3,0.10*,26088.0,1.00*,J*,T)  SxptSPCUS2
TRIANOLE LABS  TvctlTLI BLANK  TLI*43432
100H   A2.49B7
  so:
  60:
  40:
  20:
                                                                 A2.03E7
       33:00    33:12     33:24     33:36    33:48     34:00     34:12
Pll»:U9732S7 tl-596 Acq:17-OCT-1997 15:44:35 OC SH-  Voltagt SIR 70S
430.9729 Pi4 Exp:SPCUS2
TRIANQLB LABS  TtXttTLI BLANK  TLI#43432
100*

  80:

  60:

  40.

  20:

   a:
                                                                           34:24
      33(00     33(12     33(24     33(3ff     33(40     34(00    34(12
Pil»:U9732S7 01-596 Acq: 17-OCT-1997 15(44(35 OC BH- VoJtagr* SIR 70S
479.7165 Pi4 Bxp:BPCV32
TRIANOLB LABS  TextiTLI BLANK  TLI043432
                                         33143
  so:

  sol

  40:
  20:

   0.
                                                                           34:24
                                                                         34:22
    32:57
              33:1
                        33t21.
                                33132
                                                                  34113
       33100
                 33112
                          33:24
                                    33:36
                                              33(48
                                                       34:00
                                                                 34(13
                                                                           34.24
                                                                                    34:36
                                                                                    34136
                                                                                    34:36
                                                                                       34(4
                                                                                     34:36
.3.8E6

.3.1S6

.2.3E6

•.1.5B6

'•.7.6BS
                                                                                                -.o.oso
                                                                                                    Tim*
 9.1B6

 .7.3E6

 5.5E6

 3.7B6

 1.8E6
                                                                                                0. OBO
                                                                                                   Time
 .2.7B6

 .2.2B6

 .1.6B6

 .1.1B6

 .S.SBS

 .0.0X0
    Tin*



 .3.3B4

 .3.024

 .2.324

 .1.524

 .7.523
                                                                                                 O.OSO
                                                                                                    Tim*

-------
FHOSUS73257 91-596 Acqt17-OCT-1997 15:44:35 OC EH- VolCago SIR 70S NOISO1973
423.7766 Pt4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,3892.0,1.00*,P,T) Exp:EPCUS2
TRIANQLB LABS  TaxtlTLI BLANK  TLI943432
icon
     33:12   33:18  33:24   33:30   33:36  33:42  33:48   33:54   34:00   34:06
?!!•: 17973 257 91-596 Acqt 17-OCT-1997 15:44:35 OC BH- Volt ay • SIS 70S Noia»:1147
425.7737 P:4 BSOB(2S6,30,-3.0) PKD(7,5,3,0.10\r4588.0,1.00\,PfT) Exp:EPCUS2
TSXANOLS LABS  TfXtlTLI BLANK  TLI943432
lOOn                                                     A9.34E4
                                                                                	O.OEO
                                                                                '34': 12 '  '34\ 18 ' '34\24   tiaa
     33:12   33:18  33:24   33:30   33:36  33:42  33:48   33:54  34:00   34:06
Pil9iO9732S7 91-596 Acyt17-OCT-1997 15:44:35 OC Elf Volta£T« SIS 70S Sois»:2499
435.8169 P:4 B3UB(256,30,-3.0) PKD(7,5,3,0.10\,9996.0,1.00\,P,T) Exp:EPCU32
TRIANQLE LABS  T*Xt:TLI BLANK  TU943432
lOOn                                                   Al.f2S7
  so:
  eo:
  401
 20.
                                                                                                    O.OEO
                                                                                34': 12   34:18  34:24   Tima
                                                                                                    S.8E6

                                                                                                    4.7B6

                                                                                                    3.5E6

                                                                                                    2.3B6

                                                                                                    1.2B6
                                                                                                     0.050
      33112   33118   33:24   33:30   33:36  33:42   33:48   33:54  34:00   34:06
P±l»tU973257 91-596 Acq: 17-OCT-1397 15:44:35 OC ET* Voltagt SIR 703 Hoist:2957
437.8140 Pi4 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,11828.0,1.00*,P,T) Bxp:EPCVS2
TRIANQLB LIBS  TmxtiTLI BLANK TLH43432
100H                                                   A1.60K7
  80.

  60.

  40.

  20.
                                                                                '34*112 ' '34*118 ' '34124   Tim*
                                                                                                   rS.6E6

                                                                                                   .4.SB6

                                                                                                   .3.4B6

                                                                                                   .2.2E6

                                                                                                   .1.1B6
                                                                                                     0.050
     33:12   33tl8  33:24   33:30   33:36  33:42  33:48   33:54   34:00   34:06  34:12   34:18  34,24   Tim*
Filet0973257 91-596 Acq: 17-OCT-1997 15:44:35 OC EH- Yoltaff* SIR 70S
430.9729 Pi 4 Bxp:SPCU32
TRIANOLX LABS  T*Xt:TLX BLANK  TLI943432


                                                                                                    .2.2S6

                                                                                                    .1.6E6

                                                                                                    .1.1X6

                                                                                                    .5.4B5
  80.

  60.

  40.

  20.
                                                                                                     o.oso
      33i12  33:18   33:24  33:30   33:36  33:42   33:48   33:54   34:00  34:06   34:12  34:18   34:24   Tim»

-------
>il»tV9732S7 ti-$9* Acqtl7-OCT-19Sl i5,44>35 OC EI+ Voltag» SIR  iOS Noise,1598
\41.7428 P,4 BSUB(256,30,-3.0) PKD(7,S,3,0.10X,6392.0,1.00*,P,T) ExptEPCUS2
•RIANQLB LABS  TaxttTLI BLANK  TLIV43432
         33(00       34(00       35tOO       36tOO      37iOO       36tOO
 'llmtU9732S7 *l-596 Acqil7-OCT-1997 15i44i3S OC SI> Voltage SIR 70S Nola«:1777
443.7399 Pt4 BSVB(256,30,-3.0) PKD(7,3,3,0.10*,7108.0,1.00*,F,T)  ExpsEPCUS2
TRIANOLE LABS  TexttTLI BLANK  TLX*43432
                                                                                39 tOO
         33100       34»00       3StOO       36tOO       37iOO       38:00
filmtU973257 fl-596 Acqil7-OCT-1997 15t44i35 OC EH- Voltage SIS 70S
430.9729 fi4 ExpiEfCV32
TRIANOLE LABS  TfXttTLI BLANK  TLX#43432                                  •
100H     32tS6 33,30  34l03
         'J      '               "	        	  37,26    38,13
                          39 tOO
3St47
          33(00       34>00       35(00       36iOO       37,00       38tOO
Pll»t09732S7  tl-596 Aeyil7-OCT-1997 15,44,35 OC Bl+ Voltage SIR 70S
513.6775  Pi4  BxpiSSCUS2
TRIABOLB  LABS TexttTLI  BLANK  TLI*43432
                          39100
-2.7B6
.2.SS6
.2.2P.6
.1.9S6
.1.6S6
.1.4B6
.1.1S6
.8.235
IS.SBS
.2.7B5
 O.OEO
    Tim
          33 tOO

-------
 '110IU973257  91-596 Acq: 17-OCT-19S7 15,44,35 GC EI+  Voltagf SIR  70S NO1B»,175S
457.7377 Pit  BSUB(256,30, -3.0)  PKD(7,5,3, 0.10%, 7036.0,1.00*,P,T) Exp,BKUS2
TRIAKOLS LABS TlXtlTLI BLANK  TLI#43432
100H                  JL1.48B5
 80.

 60.

 40.

 20.
    36tl8          36,24         36:30         36,36         36,42          36,48
Pll»,V973257  #1-596 Acqt17-OCT-1997 15,44,35 OC SX+ Voltafff SIR 70S Solm»,2036
459.7348 F,4  BSUB(256,30,-3.0)  PKD(7,5,3, 0.101,8144.0,1.OOX,P,T) ExpiXPCUS2
TRIAHOLB LASS  TfXttTLI BLANK  TLI#43432
100H                11.',
 80.

 60.

 40.

 20.
    36,18          36,24         36,30         36,36         36,42          36,48
Pll»tU973257 fl-596 JLcqt 17-OCT-1997 15,44,35 OC BX+ Voltagf SIR 70S Soltm,829
469.7779 ft4 BSUB(256,30,-3.0)  PKD(7,5,3,0.10*,3316.0,1.00*,P,T)  Exp,SPCUS2
TXIUMLX LABS  TmxtlTLI BLANK  TLI*43432
100H                  A2.2.4X7
    36,18          36*24         36,30          36,36          36,42       ..36,48
Pll»,U973257 §1-596 Acqtl7-OCT-1997 15,44,35 OC KT* Voltay* SIR 70S Soim»,1188
472.7750 P,4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,4752.0,1.00*,P,T) Bxp,EPCVS2
TRIANQLX LABS  TfXttTLI BLANK  TLI*43432
10OH                  A2.90S7
     36,18         36,24         36,30          36,36         36,42
Pil»lU9732S7 91-596 Ac
-------
                                                                               CD
                                                                               CC
Peak Locate Examination:17-OCT-1997:15:43 File:U973257

-------
File:U973257 #1-596 Acq:17-OCT-1997 15:44:35 GC EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:TLI BLANK  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%                                   A1.25E5
  OJ
              '0	36iOO             37iOO             38iOO
File:U973257 #1-596 Acq:17-OCT-1997 15:44:35 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:TLI BLANK  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%                                  A1.39E5
 80 j
60j
40 j
20 j
 OJ
                                                     39:00
                                                         5.
                                           \sAd*}u^J\^ikfy^^
                                                                                         13
                                                                                         ;2
              35:00             36:00             37:00             38:00
File:U973257 #1-596 Acq:17-OCT-1997 15:44:35 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:TLI BLANK  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%                                    36;26
 801
 60 j
 401
 20 j
  OJ
                                                         0
                                                     39:00
              35:00
36:00
                                                         s
                                                        13
                                                        L2
                                                        Ll
                                                        LO
37:00
                                                                   38:00
39:00
                                         5E4
                                         4E4
                                         3E4
                                         2E4
                                         1E4
                                         ,OEO
                                          Time
.3E6
.1E6
.8E6
.5E6
.3E6
.OEO

-------
     r-r
TLI Project:      43432
Client Sample:   SO-23-1
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U973258
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-1A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
Anafytes %" -^" ^ J'^ 75
2,3,1,S~TCDD
1,2,3,1, 8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
^'i^c^^^^^i
EMPC
0.07
0.02
EMPC
0.03
0.02
0.03
2.4
0.36
0.38
0.16
0.07
0.05
ND 0.006
EMPC
ND 0.01
EMPC
*$**?-;
0.05


0.02










0.07

0.01
XV;;ife*fc

1.68
1.23

1.32
1.08
0.88
0.74
1.47
1.54
1.32
1.36
1.27




- '?
-------
TLI Project:      43432
Client Sample:   SO-23-1
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U973258
Internal Standards

13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
nCl4-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13Cl2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
13Ci2-l,2,3,4,7,8,9-HpCDF


Alternate Standards (Typ* A) \V
13C12-i,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards •, .?; :;
13C,2-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt {ng} 'V
"• ••
3.6
3.4
3.2
3.3
4.4
3.8
2.5
3.8
5.1
Amf^Wf-^
3.7
3.8
3.7
4.0
4.0


Mft|OT%C^
4.0
4.5
v- \ '\ '•• ,1*1


* "; v %7$regvg
....•; 	 ':.':..<...':.. •:.
89.8
85.5
78.8
83.7
111
94.1
61.3
95.0
63.5
f£ '^fl&SKS&ve
93.7
95.6
92.0
98.9
101


X ? *° i% -. •. s- '••••• v>
101
112
5i\SS$


nv QC Limits ^
-.
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
^x^Ci,tn»it» >^
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%

;• •- \f -A "• -•'"• ""-. s %>
i5i;;||QC?;l«lRiite:.^.rJ
40%-130%
40%-130%
"r^A^ ^


Ratio
f
0.77
0.82
1.51
1.44
0.51
1.21
0.38
1.04
0.87
*tori*

1.48
0.51
1.22
0.38


* s Ratio:
0.50
0.50
;;Ratfe
0.81
1.20
RT ^ x Flaas^
% s
21:32 	
22:28 	
26:16 	
27:28 	
30:14 	
30:59 	
33:01 	
33:54
36:26 •
^^m^$'&*&^
22:29 	
27:05 	
30:08 	
30:54 	
34:14


.^r-ST^-- PiS[S;>
31:30 	
30:46 	
> * m->V;Fteas-
22:15 	
31:17 	
                     Data Reviewer.
                                        Vc-
                                       Page 2 of 2
            10/23/97
                          X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 23:13 10/23/97

-------
                        Initial
                                     3ate. .
 Data Review By:
                          \i
                                              Calculated Noise Area:
                                                                      5.22
 The Total Area  for each peak with an ion abundance ratio outside
 ratio limits  has been recalculated according to method requirements.
 Page No.      1
 10/23/97


 Compound/
 M_Z	 QC.Log Omit Why
Listing of U973258B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.
TCDF
304-306











TO




304-306
13C12-TCDF
316-318









316-318
TCDD
320-322






D
0.65-0.89
DC NL 0:00
17:41
18:14
18:28
18:54
19:16
19:48
20:11
20:36
20:44
21:01
21:20
21:34
22:08
22:24
22:40
23:41
16 Peaks
RO 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.

40
75
74
72
75
75
75
75
77
77
75
74
74
74
75
83
79


2,
1,
1,
8,
5,
5,
4,
4,
1,
2,
2,
6,
2,
1,


51,
6
553
584
121
898
706
505
401
028
875
601
245
391
499
477
249
151
292
.51
.72
.24
.96
.98
.43
.12
.39
.35
.96
.20
.63
.04
.99
.95
.33
.02
.31

1,091
675
470
3,822
2,445
2.355
1,885
1,750
818
1,118
953
2,712
1,065
634
116
66


.14
.10
.34
.61
.54
.78
.53
.79
.32
.99
.39
.86
.03
.25
.81
.77


1,462
909
651
5.076
3,260
3.149
2,515
2,277
1,057
1,482
1,292
3,678
1,434
843
132
84

0.65-0.39
DC NL 0:00
DC WL 20:09
21:00
21:32
DC SN 22:16
DC SN 22:32
DC WH 22:42
DC WH 22:45
DC WH 23:36
DC WH 23:46
2 Peaks
RO 2.
0.
0.
0.
RO 0.
RO 1.
RO 3.
RO 1.
RO 0.
RO 3.

29
78
79
77
64
79
15
03
47
88




9,






10,
3
83
56
962
14
12
5
6
24
4
018
mr*n
.22
.29
.08
.59
.11
.83
.10
.09
.44
.25
.67
0 /
0.65-0.89
DC NL 0:00
19:10
19:40
20:04
20:59
21:20
21:49
D CO 22:14
RO 2.
0.
0.
0.
0.
0.
0.
0.
03
77
79
77
78
78
72
73

1,


1,



2
588
803
400
142
662
315
346
.14
.49
.32
.85
.44
.34
.08
.90


24
4,331








.74
.81








31
5,630






0.

.58
.14
.62
.37
.89
.34
.86
.56
.64
.21
.24
.18
.96
.70
.52
.25

0.


.34
.78






813-1.106
0.000
0.821
0.847
0.858
0.878
0.895
0.920
0.937
0.957
0.963
0.976
0.991
1.002 2378-TCDF AH
1.028
1.040
1.053
1.100

954-1.046
0.000
0.936
0.975
1.000 13C12-2378-TCDF ISO
1.034
1.046
1.054
1.057
1.096
1.104
tV*TMl ITrtl 1 /M*re • — •_ — —


689
353
174
502
289
132


.88
.66
.31
.09
.49
.21


898
449
226
640
372
182

0.

.61
.66
.54
.35
.85
.87

848-1.061
0.000
0.853
0.875
0.893
0.934
0.950
0.971
0.990
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 23:13 10/23/97

-------
 Page No.
 10/23/97
Listing  of U973258B.dbf
Matched  GC Peaks /  Ratio / Ret.  Time
 Compound/
 M_Z	  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.
TM
AN







320-322
37C1-TCDD
328

















328
13C12-TCDD
332-334








332-334
PeCDF
340-342









DC
DC

DC


DC
DC
DC
DC
DC

DC






DC
DC
DC
DC
DC


DC






DC
DC


DC

DC
DC
DC





SN
SN

WH
12

ML
WL
WL
WL
WL

SN






SN
SN
SN
SN
SN
7

NL






SN
SN
6

NL

SN
SN
SN
22:21
22:28
22:41
22:54
23:10
23:24
23:33
23:41
23:58
Peaks

0:00
19:09
19:23
19:32
19:42
20:45
21:00
22:29
22:44
22:50
23:00
23:20
23:30
23:48
23:51
23:52
23:56
24:05
Peaks

0:00
22:15
22:28
22:53
23:20
23:29
23:48
23:56
24:10
Peaks

0:00
23:59
24:25
24:34
24:46

RO


RO
RO


RO





















0.
RO


RO
RO
RO
RO
RO
RO

1.


RO
RO
RO
0
0
0
0
0
1
0
0
5





















.76
.59
.73
.80
.91
.82
.74
.74
.28
6






1

6










a
998.00
121.60
134.83
201.94
54.85
3.66
5.51
49.68
1.19
,473.42

2.04
9.01
4.47
34.09
35.09
,154.25
7.41
,698.67
13.01
14.27
190.30
33.98
35.88
2.39
2.92
2.56
11.49
12.00
.140.36
430
52
56
89
28


21








1,154

6,698
13
14
190
33
35






.00
.90
.79
.57
.26


.12








.25

.67
.01
.27
.30
.98
.88






65-0.89
2
0
0
0
1
1
1
1
0

.56
.81 7
.82 7
.94
.09
.84
.25
.07
.53
15
32-1.78
1
1
4
1
2
.45
.58 1
.10
.92
.11
1.68
,980.42
,569.82
182.13
28.74
30.16
31.84
11.89
16.25
,823.11
TV nn /
L \-LJU 1
4.65
,467.60
4.79
4.51
26.19

3,580
3,418
96
17
31
22



.03
.87
.73
.71
.34
.45


568.00
89.70
78.04
112.37
30.99


28.56


0.



















0.

4,400.39
4,150.95
102.90
16.24
17.04
17.99


0.995
1.000 2378-TCDD AN
1.010
1.019
1.031
1.042
1.048
1.054
1.067

911-1.089
0.000
0.852
0.863
0.869
0.877
0.924
0.935
1.001 37C1-TCDD SUR1
1.012
1.016
1.024
1.039
1.046
1.059
1.062
1.062
1.065
1.072

911-1.089
0.000
0.990 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.019
1.039
1.045
1.059
1.065
1.076
P&C DP F*o 1 1 ows —


898




.62



0.

568.98



906-1.077
0.000
0.913
0.930
0.935
0.943
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Caroina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
 Page No.
 10/23/97
Listing of U973258B.dbf
Matched GC Peaks / Ratio  / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. .  Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.






A
M








340-342
13C12-P6CDF
352-354









352-354
PeCDD
356-358













356-358
13C12-PeCDD
368-370
DC SN 24:52
25:09
25:19
25:30
25:45
25:58
26:12
26:17
26:28
26:37
27 : 06
27:15
27:35
DC SN 27:42
DC SN 28:00
28:09
14 Peaks

DC NL 0:00
25:19
DC SN 25:53
26:16
26:36
DC SN 26:46
27:05
DC SN 27:25
DC SN 27:41
DC SN 28:08
4 Peaks

DC NL 0:00
25:28
26:00
26:17
26:26
26:39
26:50
26:56
27:09
27:18
27:29
27:39
27:59
DC WH 28:12
12 Peaks

DC NL 0:00
RO











RO

RO


1
RO



RO
RO

RO
RO
RO

1
RO
RO







RO

RO
RO
RO

1
RO
3.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

99
53
53 3,
58
51
61 1,
38
47
58
49
54
50
28
41
02
49
11,
3.49
744.06
638.16
790.08
397.26
196.37
276.00
678.00
534.92
670.53
741.14
574.00
80.83
15.61
11.38
59.02
847.97

450
2,198
483
239
737
160
404
327
401
449
344
49


35


.23
.98
.91
.12
.82
.00
.00
.30
.61
.02
.77
.13


.36


293
1,439
306
158
458
116
274
207
268
292
229
38


23

.32-1.78
1.
1.
1.
1.
1.
0.
1.
0.
4.
0.

08
50
66
51 6,
23
54
48 6,
55
40
50
13,
1.83
126.98
30.07
879.94
86.19
9.30
377 . 82
18.52
15.63
15.89
470.93
t**f*no I
.32-1.78
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

30
92
70
53
49
50
46
50
39
05
68
96
84
95
1,
2.43
485.32
60.81
368.66
97.67
281.41
55.30
103.50
107.42
51.66
94.24
46.51
45.65
2.70
798.15

76

4,137
52

3,803




.23

.36
.39

.77




50

2,742
42

2,574




.83
.18
.17
.14
.55
.00
.00
.62
.92
.12
.23
.26


.66

0.

.75

.58
.53

.05



0.947
0.957
0.964
0.971
0.980
0.989
0.997
1.001 12378-PeCDF
1.008
1.013
1.032 23478-PeCDF
1.037
1.050
1.055
1.066
1.072

848-1.152
0.000
0.964
0.985
1.000 13C12-PeCDF
1.013
1.019
1.031 13C12-PeCDF
1.044
1.054
1.071







AN


AN










123 IS2


234 SUR2






295
38
223
58
168
32
62
62
31
59
35
32



.00
.28
.06
.47
.91
.85
.08
.45
.40
.13
.80
.85



321
22
145
39
112
22
41
44
29
35
18
17


.32-1.78
1.
07
1.32



0.

.84
.53
.60
.20
.50
.45
.42
.97
.92
.11
.24
.90


0.

921-1.025
0.000
0.927
0.947
0.957
0.962
0.970
0.977
0.981
0.988
0.994
1.001 12378-PeCDD
1.007
1.019
1.027

855-1.145
0.000











AN






Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 23:1 3 10/23/97

-------
 Page No.      4
 10/23/97

 Compound/
 M_Z.... QC.tog Omit Why
Listing  of U973258B.dbf
Matched  GC Peaks / Ratio / Ret. Time
. RT.  OK Ratio Total.Area	Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.








368-370

HxCDF
374-376












K
374-376
13C12-HXCDF
384-386




384-386
HxCDD
390-392







K


DC SN 26:17
DC SN 26:25
DC SN 26:47
27:28
27:38
DC SN 27:58
DC SN 28:11
DC SN 28:19
DC SN 28:28
2 Peaks

1
1
1
1
1
1
RO 7
1
1


.71
.38
.42
.44 4
.44
.38
.43
.32
.57
4

1.05-1.43
DC NL 0:00
29:06
29:15
29:25
29:34
29:45
DC SN 29:56
30:08
30:14
30:22
30:34
30:46
DC SN 31:31
31:36
11 Peaks
1
1
1
1
1
RO 1
1
1
1
1
1
1
RO 1
RO 1

.11
.25
.23
.16
.39
.01
.25
.32
.36
.42
.41
.27
.47
.53
1
8.48
6.77
2.35
,005.78
420.09
27.02
8.03
24.22
17.31
,425.87


11.73
159.87
537.06
66.70
76.45
34.94
6.11
334.38
189.25
41.57
88.22
107.22
8.29
21.24
,656.90


2,361
248







.06
.08







1,644
172







.72
.01





0.
0.
0.
1.
1.
1.
1.
1.
1.

957
962
975
000 13C12-PeCDD 123
006
018
026
031
036



I S3









88
296
35
44
19

190
109
24
51
59

14


.97
.33
.79
.43
.34

.17
.06
.36
.62
.94

.47


70
240
30
32
19

144
80
17
36
47

9

0.43-0.59
DC NL 0:00
30:08
30:14
30:46
31:30
4 Peaks
RO 0
0
0
0
0

.41
.51 6
.51 7
.50 6
.50 5
25
KW«M. 1
1.05-1.43
DC NL 0:00
29:39
30:08
DC SN 30:14
30:22
DC SN 30:32
DC SN 30:40
DC SN 30:46
30:55
31:00
DC SN 31:04
RO 0
1
1
RO 0
RO 1
1
1
RO 1
1
RO 0
RO 2
.62
.05
.24
.87
.44
.30
.40
.60
.23
.93
.49
88.26
,342.46
,074.93
,744.22
,717.46
,879.07

3.32
49.79
129.21
7.57
84.96
14.90
3.00
8.04
21.35
25.27
1.55

2,136
2,377
2,261
1,906

.79
.66
.64
.91

4,205
4,697
4,482
3,810
0.

.90
.73
.91
.02
.11

.21
.19
.21
958-1.051
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
.60 1.
.28

.48

0.

.67
.27
.58
.55
1.
1.
1.

000
963
967
973
978
984
990
997 123478-HxCDF
000 123678-HxCDF
004
Oil
018 234678-HxCDF
042 123789-HxCDF
045








AN
AN


AN
AN


868-1.132
0.
0.
1.
1.
1.
000
997 13C12-HXCDF 478
000 13C12-HXCDF 678
018 13C12-HXCDF 234
042 13C12-HXCDF 789

SUR3
IS4
ALT2
ALT1



25
71

54



11
13


.48
.49

.66



.76
.99


24
57

37



9
14

0.

.31
.72

.93



.59
.98

952-1.015
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
957
973
976
980
985
990
993
998 123478-HxCDD
001 123678-HxCDD
003








AN
AN

Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 23:13 10/23/97

-------
 Page No.
 10/23/97
Listing of 0973258B.dbf
Matched GC Peaks /  Ratio / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.

390-392
13C12-HXCDD
402-404








402-404
HpCDF
408-410
M
K
K



408-410
13C12-HpCDF
418-420




418-420

HpCDD
424-426
MX

M



424-426
13C12-HpCDD
436-438



31:18 1.32
6 Peaks
1.05-1.43
DC NL 0:00 RO 0.68
DC SN 30:21 1.21
30:54 1.22 4
30:59 1.21 5
31:08 1.07
31:17 1.20 5
31:33 1.28
31:35 RO 0.70
DC SN 31:37 RO 4.61
6 Peaks 15
0.88-1.20
DC NL 0:00 RO 1.48
33:02 RO 1.22
33:16 1.02
33:23 0.94
DC SN 34:15 RO 0.77
DC SN 34:22 RO 1.77
DC WH 34:38 RO 1.62
3 Peaks
0.37-0.51
DC NL 0:00 RO 0.65
33:01 0.38 3
33:13 RO 1.20
34:14 0.38 3
DC SN 34:26 RO 0.09
3 Peaks 6

0.88-1.20
DC NL 0:00 RO 1.24
33:17 RO 0.83
DC SN 33:31 RO 1.84
33:54 1.08
DC WH 34:11 RO 2.95
DC WH 34:15 RO 1.40
DC WH 34:21 RO 2.76
2 Peaks
0.88-1.20
DC NL 0:00 1.20
DC SN 33:17 1.09
33:54 1.04 5
34:16 RO 1.43
44.49 25.29
355.07

3.65
24.85
,662.16 2,562.36
,253.10 2,878.93
109.84 56.67
,802.06 3,160.17
44.18 24.79
24.84 13.75
25.92
,896.18
HxCDD / HpCDF Follows ~**
5.41
86.70 51.70
23.50 11.84
20.19 9.79
13.16
4.57
2.88
130.39

14.73
,390.65 938.25
27.85 23.29
,017.10 834.73
20.98
,435.60


3.00
17.18 8.76
1.69
24.80 12.90
1.67
7.06
1.94
41.98

12.35
19.21
,057.51 2,582.80
51.88 36.32
19.20 1.010 123789-HXCDD

0.968-1.032
0.000
0.980
2,099.80 0.997 13C12-HXCDD 478
2,374.17 1.000 13C12-HXCDD 678
53.17 1.005
2,641.89 1.010 13C12-HXCDD 789
19.39 1.018
19.58 1.019
1.020

0.996-1.043
0.000
42.50 1.001 1234678-HpCDF
11.66 1.008
10.40 1.011
1.037 1234789-HpCDF
1.041
1.049

0.939-1.121
0.000
2,452.40 1.000 13C12-HpCDF 678
19.34 1.006
2,182.37 1.037 13C12-HpCDF 789
1.043


0.977-1.005
0.000
10.50 0.982
0.989
11.90 1.000 1234678-HpCDD
1.008
1.010
1.013

0.971-1.029
0.000
0.982
2,474.71 1.000 13C12-HpCDD 678
25.43 1.011
AN




SUR4
IS5

RS2






AN


AN





IS6

SUR5







AN







IS7

Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 23:13 10/23/97

-------
 Page No.     6           Listing of U973258B.dbf
 10/23/97                 Matched GC Peaks / Ratio /  Ret.  Time

 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area	Area.Peak. 1. . Area.Peak.2..  Rel.RT Compound.Name. .  ID..  Flags.

 436-438               2 Peaks               5,109.39

                	Above:  !$>CDD / Octa-CDD and CDF Follows	
 OCDF                           0.76-1.02                                     0.890-1.110
 442-444         DC  NL   0:00     0.91          5.82                              0.000
                 DC  SN  34:43 RO  0.27          2.68                              0.953
                 DC  SN  34:49 RO  1.36          6.50                              0.956
                 DC  SN  36:20 RO  1.03          2.85                              0.997
         MK              36:33 RO  0.73         11.66          5.49          7.51  1.003 OCDF            AN
                 DC  SN  36:50 RO  1.92          3.12                              1.011
                 DC  SN  36:57 RO  1.18          4.27                              1.014
                 DC  SN  37:49 RO  2.46          2.06                              1.038
                 DC  SN  37:54 RO  1.33          1.25                              1.040
                 DC  SN  38:11 RO  1.51          4.69                              1.048
 442-444               1 Peak                   11.66

 OCDD                           0.76-1.02                                     0.890-1.110
 458-460         DC  NL   0:00 RO  1.86          2.38                              0.000
         MK              36:27     0.88         22.80         10.70         12.10  1.000 OCDD            AN
                 DC  SN  36:36 RO  0.37          0.85                              1.005
                 DC  SN  36:38 RO  0.34          0.81                              1.005
                 DC  SN  36:40 RO  0.36          4.03                              1.006
 458-460               1 Peak                   22.80

 13C12-OCDD                     0.76-1.02                                     0.995-1.005
 470-472         DC  NL   0:00     0.95          1.97                              0.000
                         36:26     0.87      5,622.50      2,617.42      3,005.08  1.000 13C12-OCDD      IS8
                 DC  WH  36:52 RO  1.81         36.19                              1.012
 470-472               1 Peak                5,622.50
 Column Description	  "Why" Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)     WL-Below Retention Time Window   A-Peak Added
 . .RT. -Retention Time (mm:ss)   WH-Above Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below Signal to Noise Level   D-Feak Deleted
 OK    -RO=Ratio Outside Limits  
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P11«*097325B #1-595 Acq,17-(7,S,3,0.10*,2940.0,1.00\,P,T)  EXp,BPCUS2
TRIANOLB LABS  T«rt»SO-M23-l  TLU43432
1009k                                                      A1.28ES
      33:12  33*18   33*24  33*30  33*36  33*42   33*48  33*54   34*00  34*06  34*12
Pllm*U973258 #1-596 Acy:17-OCT-1997 16*30*11 OC ET+ Voltage SIR 70S Nolso:3365
435.8169 P:4 BSUB(2S6,30,-3.0)  PXD(7,5,3,0.10*,13460.0,1.00*,P,T)  Exp:BPCU32
TRIANGLE LABS   Tucti3O-K23-l   TLU43432
                                                         A2-SBE7
  so:

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           A1.23E5
                          A3.28S3  A1.S7B4
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                                                                                                   .3.1S4

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-------
PilatU9732$8 #1-596 Aaqi 17-OCT-1997 16i30tll OC EH- Voltaffo SIR 70S Noist:1390
441.7428 Pl4 BSUB(256,30,-3.0) PKD(7,5,3,0.10X,5560.0,1.00\,P,T) ExptSPCUS2
TRIANGLE LABS  T0JCt:SO-M23-l  TLI#43432
         33(00       34/00       35(00      3ff«00      37(00       30(00      35(00
Fll»:U9732S8 #1-596 Acqt 17-OCT-1997 16t30>ll OC EH- Voltag* SIR 70S Noil*11519
443.7399 Pt4 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,6076.0.1.00*,P,T) Exp:EPCUS2
TRIANGLE LABS  T»3ftiSO~H23-l  TLX143432
                                                                                               Tim*
         33(00      34>00       35(00      36:00      37(00       30(00
Pll»iU973258 #1-596 Aaqt 17-OCT-1997 16i30tll OC Elf Voltafo SIR 70S
430.9729 Pt4 Exp:EPCUS2'
TRIANGLE LABS  T*Xt:SO-K23-l  TLI943432
100H         33(31              35(00
    .   	   I    33iS4     I.I          , 36il3
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                                  I           3* 13            37t44                       P"
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                                                                              r1.3S6
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                                                                               16.3B5
                                                                               .S.1S5
                                                                               -.3.8SS
                                                                               L2.SE5
                                                                               L1.3E5
                                                                                O.OSO
         33tOO       34:00      35tOO       36:00       37:00       38;00
 P11»:U9732S8 #1-596 Acqtl7-OCT-1997 16:30:11 OC Sit Voltaya SIR 70S
 513.6775 Pi4 Sxp:SPCUS2
 TRIANOLE LABS  T»Xt:3O-U23-l  fLI#43432
                                                                 39100
                                                                                   Tim*
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  30-
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                                                     96:51
                                                                 40
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                                                       38109
                                                               38(50
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                                                                              39100
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-------
 '11«,U97325B #1-596 Acgil7-6fflP-lJJ7 16i30ill OS El* Voltage SIR 703 Nbis»tll70
 57.7377 Pt4 BSUB(2S6,30,-3.0) PE3(7,5,3, 0.10*, 4680.0,1.OOX,P,T) ExptEPCUS2
TRIANGLE LASS  TextiSO-H23-l  TLI043432
100*                    ALICES
    36il8          36i24         36t30         36t36         36t42          36i48
 '11»:U973258 01-596 Aeqtl7-OCT-1997 16t30tll  OC BH- Voltafff SIR 70S NolB»,631
459.7348 Pt4 BSUB(2S6,30,-3.0)  PKD(7, 5,3.0.10\,2524.0,1.00\,P,T) Exp:EPCUS2
TRIANGLE LABS   TfXtiSO-H23-l  TLIX43432
1009k                    Al.fSES
 80.

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    36tl8          36,24         36i30         36t36         36:42         <.36t49
fil»tU97325B 01-596 Acq:17-OCT-1997 16i30tll OC SH- Volt ago SIR  70S Nolaet479
469.7779 f>4 BSOB(2S6,30,-3.0)  PKD<7,S,3,0.10*,1916.0,1.00*,P,T) BatptBPCUS2
TRIAKOLB liABS  TfXttSO-M23-l  71,1*43432
100H                  A2.62B7
  80.

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  20.
    361 IB          36t24         36,30         36,36         36,42          36,46
Pil»tU973258 01-596 Acytl7-OCT-1997 16,30,11 OC BI+ Voltafff SIR 70S BoimatSOS
471.7750 Pt4 BSUB(256,30,-3.0) PXD(7,5,3.0.10*,202Q.O,1.00*,f.T) Exp,EPCUS2
TRIANOLE LASS  T*xt,SO-H23-l  TZiI*43432
100H                  A3.01S7
  80.

  60.

  40.

  20.
     36,18         36,24         36t30          36,36          36,42
 Pll»,U973258 01-596 Acqi 17-OCT-1997 16,30,11 OC BH- Voltagm SIR 70S
 430.9729 fi4 B*piBPCUS2
 TRIANGLE LABS  T9XttSO-H23-l  TLI043432
                                                                            '36,48
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  20.
36,23
                                           36142
     36,18
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-------
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Peak Locate Examination:17-OCT-1997:16:28 File:U973258


-------
File:U973258 ttl-1024 Acq:17-OCT-1997  16:30:11 GC  EI+ Voltage  SIR  70S
319.8965 F:2 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File  Text:TRIANGLE LABORATORIES,  INC.
100%                  A4.30E6
 80 j
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              22:00                     23:00                      24:00
File:U973258 #1-1024 Acq:17-OCT-1997  16:30:11 GC  EI+ Voltage  SIR 70S
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432  File  Text:TRIANGLE  LABORATORIES,  INC.
100%                  A5.68E6
              22:00                     23100                      24iOO
File:U973258 #1-1024 Acq:17-OCT-1997  16:30:11  GC  EI+ Voltage  SIR 70S
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432  File  Text:TRIANGLE  LABORATORIES,  INC.
100%                22:1522;28
 80 j
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                                                 .7.9E5
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.7.5E6
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                                                                                                     .CD

-------
File:U973258 #1-1024 Acq: 17-OCT-1997 16:30:11 GC EI+ Voltage SIR
319.8965 F:2 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text : TRIANGLE LABORATORIES,
100%
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                                                                 70S
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              22:00                     23:00
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EH- Voltage SIR
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES,
100%
 80 j
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              22:00                     23:00
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES,
100%                22:15 22; 28
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                                                                  24:00
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-------
File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
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File:U973258 #1-1024 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                   26;16                     27-05
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-------
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File;U973258 #1-1024 Acq;17-OCT-1997 16;30ill GC EI+ Voltage SIR 703
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE  LABORATORIES, INC.
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351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE  LABORATORIES, INC.
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-------
File:U973258 #1-404 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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File:U973258 #1-404 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                            31;35
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 80J
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File:U973258 #1-404 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                       31j30
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-------
File:U973258 #1-404 Acq:17-OCT-1997 16:30
389.8156 F:3 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text
lOOi                           A1.34E5
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                                         :TRIANGLE LABORATORIES, INC.
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File:U973258 #1-404 Acq:17-OCT-1997 16:30
391.8127 F:3 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text
100%                          A1.47E5
                                           31:12      31:24      31:36
                                          11 GC EI+ Voltage SIR 70S
                                          : TRIANGLE LABORATORIES, INC.
                                           31:48
          30:36      30:48      31:00
File:U973258 #1-404 Acg:17-OCT-1997 16:30
401.8558 F:3 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text
1002s.                           30:59
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               31:17
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-------
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File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS2
Sample Text :SO-M23-1 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
100%
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File:U973258 #1-596 Acq: 17 -OCT- 19 97 16:30:11 GC EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS2
Sample Text :SO-M23-1 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
100%
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File:U973258 #1-596 Acq: 17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS2
Sample Text :SO-M23-1 TLI#43432 File Text : TRIANGLE LABORATORIES, INC.
100%
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0:
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-------
File:U973258 #1-596 Acq:17-OCT-1997 16:30
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLItt43432 File Text
100%                   A5.17E5
 80 j
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      •
:TRIANGLE LABORATORIES,  INC.
                                               _1.5E5
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  32:24   32:36  32:48  33:00  33:12  33:24
File:U973258 #1-596 Acq:17-OCT-1997 16:30:
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:
100%                  A4 25E5
 80 j
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  OJ
 33:36  33:48  34:00  34:12
 11  GC EI+  Voltage  SIR 70S
 TRIANGLE LABORATORIES,  INC.
34:24  34:36  34:48    Time
                                                1.5E5
                                               L1.2E5
                                               L8.9E4
                                               L5.9E4
                                               L3.OE4
                                                O.OEO
  32:24   32:36  32:48  33:00  33:12  33:24
File:U973258 #1-596 Acq:17-OCT-1997 16:30:
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:
100%                   33;01
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 201
  OJ
 33:36  33:48  34:00  34:12
 11  GC EI+  Voltage  SIR 70S
 TRIANGLE LABORATORIES,  INC.
                        34:14
34:24  34:36   34:48    Time
                   3.5E6
                  L2.8E6
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 .32:24   32:36   32:48  33:00  33:12  33:24

-------
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%                          A1.29E5
 80 J
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            33:00                34:00                35:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%                          A1.19E5
 80J
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  0
                                           36:00
            33:00                34:00                35:00
File:U973258 #1-596 Acq: 17-OCT-1997  16:30:11 GC EI+ Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text : TRIANGLE LABORATORIES, INC,
100%                           33,- 54
 80 J
 60J
 40 j
                                           36:00
  OJ
                                   5.9E4
                                   4.7E4
                                   3.5E4
                                   2.3E4
                                   1.2E4
                                   O.OEO
                                      Time
                                   6.4E4
                                   5.1E4
                                   3.8E4
                                   2.6E4
                                   .1.3E4
                                   .O.OEO
                                      Time
            33:00
34:00
35:00
36:00
.8.9E6
.7.1E6
.5.4E6
.3.6E6
.1.8E6
.O.OEO

-------
                                                                                                      in
File:U973258 ttl-596 Acq:17-OCT-1997  16:30:11 GC  EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC,
100*
 80J             A8.76E4
 60 j
 40J
 20J
            33:00                34:00                 35:00
File:U973258 tl-596 Acq:17-OCT-1997  16:30:11  GC  EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
100&
 80j             A1.05E5
 601
 40 j
 20J
            33:00                34:00                 35:00
File:U973258 #1-596 Acg:17-OCT-1997  16:30:11  GC EH- Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
100%                           33.54
 80J
 60J
 40J
 20 j
  0
                                           36:00
                                           36:00
                                   .5.9E4
                                   .4.7E4
                                   .3 . 5E4
                                   .2.3E4
                                   .1.2E4
                                   .O.OEO
                                      Time
                                   .6.4E4
                                   .5. 1E4
                                   .3.8E4
                                   .2. 6E4
                                   .1.3E4
                                   .O.OEO
                                      Time
            33:00
34:00
35:00
36:00
.8.9E6
.7. 1E6
5.4E6
.3.6E6
.1.8E6
.O.OEO

-------
                                                                                                     CD
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EH- Voltage SIR 70S
441.7428 F:4 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                         36:33
                             36:00                         37:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%                                         36:33
                             36:00                        37100
File:U973258 #1-596 Acq:17-OCT-1997 16:30:11 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-l  TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%                                     36;26

 80 j

 60 j
 20j

  OJ
                                O.OEO
                                   Time
                             36:00
37:00
                                O.OEO
                                   Time
8.4E6

6.7E6

5.0E6

3.3E6

1.7E6

O.OEO

-------
File;U973258 #1-596 Acq;17-OCT-1997 16;30;11 GC EH- Voltage SIR 70S
441.7428 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%                                        A5.49E4
 80 j
 60 j
 40J
 20 j
                             36:00                        37:00
File:U973258 #1-596 Acq: 17-OCT-1997  16:30:11 GC  EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC,
100%                                        A7.51E4
                             36:00                        37:00
File:U973258 #1-596 Acq:17-OCT-1997  16:30:11 GC  EI+ Voltage  SIR  70S
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC,
100%                                     36;26
 80 j
 60 j
 40J
 20 j
                             36:00
37:00
                               .3.7E4
                               .3.0E4
                               .2.2E4
                                1.5E4
                               .7.4E3
                               .O.OEO
                                   Time
                                5.2E4
                                4.2E4
                                3. 1E4
                                2. 1E4
                                1.0E4
                                O.OEO
                                   Time
8.4E6
.6.7E6
.5.0E6
3.3E6
.1.7E6
.O.OEO

-------
File:U973258 #1-596 Acq:17-OCT-1997 16:30
457.7377 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text
100%                         A1.Q7E5
:11  GC EI+  Voltage  SIR 70S
:TRIANGLE LABORATORIES,  INC.
                                          37:00                38:00
                                             GC EI+ Voltage SIR 70S
  0
      	 36:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30
459.7348 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC,
100%                         A1.21E5
 80 J
 60 j
 40 j
 20J
                                          37:00                38:00
                                             GC EI+ Voltage SIR 70S
                     36:00
File:U973258 #1-596 Acq:17-OCT-1997 16:30
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-1  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                          36;26
 80 j
 60 J
 40 J
 20 J
  OJ
                                         39:00
                                         39:00
                           .O.OEO
                              Time
                                                                                         6.0E4
                                                                                        L4.8E4
                                                                                        L3.6E4
                                                                                        L2.4E4
                                                                                        L1.2E4
                           O.OEO
                              Time
                                                                                        _8.4E6
                                                                                        L6.7E6
                                                                                        L5.0E6
                                                                                        L3.3E6
                                                                                        L1.7E6
                     36:00
37:00
38:00
                                                                                  39:00
E.O.OEO

-------

TLI Project:
Client Sample
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
^^#*-JE£
43432
: SO-23-1
Saginaw, MI
M23TRAIN
185-6-1A-D
1.000
n/a
DB-225

es^> ,^51^r ,:t :^v
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973636
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/18/97
Dilution Factor: n/a
Blank File: U973257
Analyst: WK
Spike File: SPC2NF04
ICal: XF24087
ConCal: X973633
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

Analyse _:t' /^7,-r : Att^Ctt^lt **r , "$&*&-' ^; ^i*%?;^V^*ki^:
2,3,7,8-TCDF
Internal Startdaitl
13Cl2-2,3,7,8-TCDF
Recovery Stancfan

-% ,;, ^v^'^Ari

* ^*v>' "
0.72
si C«rf^%^»ec<^f^Llmtts
3.8 95.4 40%-130%
^v * <** %?l *$ '^-^
t v*v"' s ^y. •• ,,,;^xx^ c " ? \
0.81 24:33 	
'» ^v^f^\^^ ?:m&}
0.81 24:32 	
- ^«atlaJ^^^S^^s
13C,2-1,2,3,4-TCDD
      0.85       23:20      	
                          Data Reviewer.
10/23/97
                                                  Page 1 of 1
                 C2NFJ>SR vIOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 23:34 10/23/97

-------
 Data Review By:
Initial    	Date...
_\U_, s,^
                                             Calculated Noise Area: n/a
 The Total Area  for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
 Listing of X973636B.dbf
 Hatched GC Peaks /  Ratio / Ret. Time
 Compound/
 M_Z	QC.Log Omit Why ..RT. OK Ratio Total. Area...  Area.Peak.1.. Area. Peak. 2.. Rel.RT Compound. Name..  ID.. Flags.
TCDF
304-306 DC

DC
DC




DC





DC


DC











DC

DC
DC
DC
DC
DC
DC
DC
304-306
13C12-TCDF
316-318 DC
DC
0.65-0.89
NL

SN
SN




SN





SN


SN











SN

SN
SN
SN
SN
SN
SN
SN
24
0:00
19:46
19:59
20:02
20:47
20:55
21:04
21:14
21:22
21:30
21:40
21:49
21:59
22:08
22:15
22:31
22:37
22:45
23:01
23:08
23:16
23:32
23:46
23:57
24:25
24:33
24:48
25:09
25:18
25:41
26:14
26:34
26:44
26:47
26:52
26:57
27:01
27:07
Peaks
0
0
0
0
0
0
0
0
RO 1
0
0
0
0
0
RO 2
0
0
RO 1
0
RO 0
0
0
0
0
0
0
0
0
0
RO 1
0
0
0
0
RO 0
RO 2
0
0

.70
.88
.78
.84
.81
.78
.80
.79
.20
.79
.78
.77
.82
.77
.77
.88
.68
.22
.82
.95
.80
.80
.80
.80
.73
.81
.80
.81
.80
.04
.82
.81
.74
.75
.95
.08
.84
.65


1,


2,
1,
2,
1,

1,
1,

3,
1.

2,
1,

1,

1,
1,

1,
1,
1,
1.

1,









34,
18.97
726.96
6.73
16.96
571.89
470.27
126.51
549.13
29.81
097.19
646.18
746.28
844.10
090.97
5.58
199.30
490.17
20.73
705.74
267.71
555.01
651.14
200.92
203.24
066.83
157.80
038.14
938.20
785.89
5.54
789.84
5.38
4.69
6.17
7.49
4.14
9.04
106.01
919.41

809


1,153
643
942
683

483
723
325
1,733
474

1,027
602

767
142
689
735
89
536
449
517
461
420
791

355









.44


.29
.09
.10
.08

.64
.37
.00
.01
.33

.79
.04

.88
.99
.42
.20
.41
.12
.75
.91
.91
.59
.16

.86









917


1,418
827
1,184
866

613
922
421
2,111
616

1,171
888

937
151
865
915
111
667
617
639
576
517
994

433








0.65-0.89
NL
WL
0:00
19:56
RO 0
RO 1
.63
.21


15.59
12.92






0.798-1.112

.52


.60
.18
.41
.05

.55
.81
.28
.09
.64

.51
.13

.86
.25
.59
.94
.51
.12
.08
.89
.23
.61
.73

.98








0.000
0.806
0.815
0.817
0.847
0.853
0.859
0.865
0.871
0.876
0.883
0.889
0.896
0.902
0.907
0.918
0.922
0.927
0.938
0.943
0.948
0.959
0.969
0.976
0.995
1.001 2378-TCDF
1.011
1.025
1.031
1.047
1.069
1.083
1.090
1.092
1.095
1.099
1.101
1.105

0.959-1.041


0.000
0.813
                                                                                                  AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed:

-------
 Page No.     2           Listing of X973636B.dbf
 10/21/97                 Matched GC Peaks / Ratio / Ret.  Time

 Compound/
 M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.

                 DC  WL  20:46 RO  1.04         10.35                              0.846
                 DC  ML  22:48 RO  0.57          5.08                              0.929
                 DC  WL  22:53 RO  0.54          8.14                              0.933
                 DC  WL  23:00 RO  0.62         40.66                              0.938
                 DC  WL  23:14 RO  1.16         58.29                              0.947
                         24:32     0.81      6,657.81      2,987.98      3,669.83   1.000 13C12-2378-TCDF ISO
                 DC  WH  26:58     0.65         67.57                              1.099
 316-318               1 Peak                6,657.81
                                        Above:  TCDF / TCDD Follows
 13C12-TCDD                     0.65-0.89                                     0.913-1.087
 332-334         DC  NL   0:00 RO  2.23          7.26                             0.000
                 DC  SN  21:51 RO  0.28          9.63                             0.950
                 DC  SN  22:37 RO  1.06          6.28                             0.983
                 DC  SN  22:44 RO  2.05          1.40                             0.988
                         23:00     0.79      4,515.84      1,995.41      2,520.43  1.000  13C12-2378-TCDD  131
                         23:20     0.85      5,011.54      2,301.28      2,710.26  1.014  13C12-1234-TCDD  RSI
                 DC  SN  23:58 RO  1.18          8.27                             1.042
                 DC  SN  24:05     0.72         71.30                             1.047
                 DC  SN  24:34 RO  0.61          4.34                             1.068
                 DC  SN  24:45 RO  0.56          7.31                             1.076
                 DC  WH  25:12     0.70         11.36                             1.096
                 DC  WH  25:18 RO  1.00          8.07                             1.100
                 DC  WH  25:22 RO  9.79          1.42                             1.103
                 DC  WH  25:27 RO  1.50          8.16                             1.107
                 DC  WH  25:55 RO  1.79          3.91                             1.127
                 DC  WH  26:01 RO  4.50          2.96                             1.131
                 DC  WH  26:08     0.66         26.47                             1.136
                 DC  WH  26:12 RO  0.60         13.29                             1.139
 332-334               2 Peaks               9,527.38
 Column Description	  'Why*  Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)      WL-Below Retention Time Window   A-Peak Added
 ..RT. -Retention Time (mm:ss)    WH-Above Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below Signal  to Noise Level   D-Peak Deleted
 OK    -RO=Ratio Outside Limits  
-------
 '1I»:X973636 91-803 Acqi 1B-OCT-1997  14:45:51 
-------
 '1101X973636 91-BO3 AcqtlB-OCT-1997 14:45:51 OC EH- VOJ-Cayo SIR Autospac SOlB»i22BB
319.8965 BSUB(256,30,-3.0) PKD(5,3,1,0.10*,9152.0,0.00*,P,P) XjCptXCONP_TT
Saapla Text:SO-M23-l TLI#43432 Pllu TfJCt: JWZAITOLE LABS
100H
 80.
           21:00          22:00          23:00          24:00          25:00          26:00
PlletX973636 #1-803 Acy: 18-OCT-1997 14:45:51 OC EH- Voltage SIR AutoSpac Holeet2407
321.8936 BSV3(256,30,-3.0) PXO(5,3.1f0.10*,9628.0,0.00*,P,P) XxptXCONP_TT
Saoplt TexttSO-M23-l TUK43432 Pile Text: TRIANGLE LABS
1009

 00.
 60.

 40.

 20.
            A2.24E6
                      A1.77E6
                           1.08E
                                  A1.
                                             A1.29S6
  60.

  40.

  20.
            A3.87B6
                      A2.2SE6
                                  A1.19S6
                                             A2.90B6
                                                         A9.12E5
           SliOO          22:00          23:00          24:00          25:00
Sil»tX97363S #1-803 Acy: 1B-OCT-1997 14t45<51 OC ET+ Voltay* SIR AutoSpuc Soim»iSB46
327.8847 BSUB(256,30,-3.0)  PXD(5,3,1,0.10*,23384.0,0.00*,P,P) Exp:KOllP_TT
Sanpl* TfXt:SO-M23-l  TLI143432 film TfXti TRIAKOLS LABS
lOOIf                                    A4.22S7
  80.

  60.
                                                                                      26:00
  40.

  20.
                AS.03B6
                                              JL9.3BE6
                                                A
          21JOO          22:00          23:00          24:00          25:00
Pile :X973 636 il-803 Aeqtl8-OCT-1997 14:45t51 OC XH- Voltage SIR AutoSpoc Noi*»:4563
331.9368 BSOB(256,30,-3.0) PKO(S,3,1,0.10\,182S2.0,0.00*,P,F) Exp:XCOKP_TT
       T*Xt:SO-H23-l TLI*43432 Pile Text! TRIABQLB LABS
                                                                                       26 tOO
  BO:
  eo:

  40:

  20:
           21:00          22tOO          23:00          24:00          25:00
PiletX973636 fl-003 *cq:18-Ocr-1997 14:45:51 OC XI* Voltage SIR AutoSp»c Hoit«t2050
333.9338 BSUB(256,30, -3.0) PXD(S.3,1,Q.10\,B3QO.O,0.00*,P,F) X*ptXCOSP_TT
Saaplf TvrttSO-H23-l  TLX#43432 Pile TMctt TRUUtOLf LABS
                                                                                       26:00
  BO:

  so:

  40.

  20.

   0.
           31 tOO
                          22100
                                         23100
                                                        24100
                                                                        25100
                                                                                       26:00
-1.SB6

.1.2S6

'.B.7S5

.5.ass

.2.9ES
                                                                                                    0.080
                                                                                                       Tim*
.1.9S6

'.1.5X6

".1.2X6

'.7.7X5

.3.9X5
                                                                                                   10.020
                                                                                                       Tim*
.1.1*7

.B.BX6

.6.6X6


'.4.4X6

.2.2X6

 0.0X0
                                                                                                   -.5.7X6

                                                                                                    .4.6X6

                                                                                                    .3.4X6

                                                                                                    .2.3X6

                                                                                                    .1.1X6
                                                                                                     0.0X0
                                                                                                        MUM
                                                                                                   .6.8X6

                                                                                                   '.5.4X6

                                                                                                   .4.1X6

                                                                                                   J.7X6

                                                                                                   .1.4X6
                                                                                                    0.0X0
                                                                                                       Tim

-------
FllmiX973636 #1-803 Acqi 18-OCT-1997
303.9016 Exp:XCOKP_TT
Saapla Taxt,SO-M23-l TLI#43432 Pile
      20,00      21,00      22,00
Pilo:X973636 #1-803 Acy,lB-OCT-1997
315.9419 ExptXCONFjer
Soaplm Taxt,SO-M23-l TLI#43432 Film
100*
 80:
 60:
 40:
 20:
  o:
      20,00      21,00      22,00
Pila,X973636 #1-803 Aay,18-OCT-1997
319.8965 BxptXCOSP TV
Saaplm Taxt:SO-H23-l TLHM3432 Film
100*         20/35
looa
 ao:
 60:
 40:
 20:

              20:47
                           2159
                                  14,45,51 OC EH-  Voltage SIR AutoSpac

                                  Taxtt TRIANGLE LABS
     II  ,23,32              "I18
        flA       24/25      A
     uuLjiiyi
                                                                        26:14
                                                                         A
                                     23/00      24/00     25/00
                                  14/45/51 OC EH- Voltays SIR AutoSpac
                                                                     26:00
                                                                               27:00
                                  Ttuctt TRIAKOLB LABS
                                                      24,32
                                     23,00      24,00     25,00
                                  14,45,51 OC EH- Voltaga SIR AutoSpac

                                  Taxt: TRIAHOLE LABS
                                                                     26:00
                                                                                2TiOO
 ao:
 60:
 40:
 20:
  0J
                  21/10
                                  22/37
      20/00      21/00      22/00
Pll»:X973636 #1-803 AcyilB-OCT-1997
331.9368 Exp:XCONP_TT
Saapl* Tuct:SO-U23-l TLI#43432 Film
100*
  80:
  60:
  40:
  20:
    23,00      24,00      25,00
14,45,51 OC EH- Voltaga SIR AutoSpac

Taxt,  TRIAKOLB LABS
                                                                     26:00
                                                                                27io

      20,00      21,00      22,00
Film,X973f36 #1-803 Acq,18-OCT-1997
292.9825 Bxp,XCONF_TT
Saapla Taxt:SO-M23-l TLH43432 Film
                                                                                2700
  ao:
  60:
  40:
  20:
   o.
    23,00      24,00      25/00      26:00
14,45,51 OC BI+ Voltaga SIR AutoSpac

Taxt,  TRIANGLE LABS
         _ 23/45 24,19 24,50           26,1726,45
      20,00      21,00      22:00
Film,X973636 #1-803 Acy,18-OCT-1997
330.9792 Bxp,XCOSF_TT
Saapla Ta3tt,SO-H23-l TLI#43432 Film
 100»
  ao:
  60:
  40:
  20:
  o:
          30,23
    23,00      24,00      25,00
14,45,51 OC Eli- Voltaga SIR AutoSpac

Taxt:  TRIANOLE LABS
       23,21   24,08  IA.A*-,*.,*
                                                                     26: 00
                                                                                27:00
.3.6E6

.2.9E6

.2.1B6

.1.4E6

.7.2ES
                                                                                          O.OEO
                                                                                            Tima
                                                                                          6.7S6

                                                                                         .5.4E6

                                                                                         .4.0B6

                                                                                         .2.7B6

                                                                                         .1.3S6
                                                        O.OEO
                                                          Tima
                                                        1.5B6

                                                       .1.2E6

                                                       .8.BBS

                                                       •.S.9B5

                                                       .2.9B5
                                                                                          O.OEO
                                                                                             Timm
                                                                                          5.7B6

                                                                                         .4.6B6

                                                                                         .3.4E6

                                                                                         .2.3B6

                                                                                         .1.1E6
                                                                                          O.OEO
                                                                                             Tima
                                                                                         -1.3EB

                                                                                         ll.OBB

                                                                                         '-.7.7E7

                                                                                         .5.2B7

                                                                                         .2.6B7
10. 010
    Tima
                                      ^6,17 26,47 27/20
                                                                                         ,.1.2*8

                                                                                         .9.6E7

                                                                                         .7.2B7

                                                                                         .4.827

                                                                                         .2.457
      20(00
                 21(00
                           2200
                                      23/00
                                                24(00
                                                           25/00
                                                                     26,00
                                                                                27 1 00
                                                                                          O.OEO
                                                                                             Tima

-------
Peak Locate Examination:18-OCT-1997:14:45 File:X973636

-------
TO Project:      43432
Client Sample:   SO-23-2
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:   S976909
Client Project:
Sample Matrix:
TLIBD:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-2A-C
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst:
09/29/97
10/09/97
10/23/97
n/a
U973257
GO
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S976907
n/a
n/a
n/a
Unaiyik:^^^:?;
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3.6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4,7,8-HxCDF
1,2,3.6.7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3.4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2.3.4,6,7,8,9-OCDF

^TOtalS \?,;1 *?¥?*" :^,VX
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
r^^^Wti^lBgJ-l
0.21
0.23
0.07
0.08
0.11
EMPC
EMPC
6.6
1.4
1.4
0.91
0.46
0.26
EMPC
EMPC
EMPC
0.04

Vv^UatflH^
6.6
2.4
1.1
0.14
60.0
24.2
4.7
0.10
SI^Ut^ViMRC--





0.12
0.09






0.04
0.30
0.05


gj^ber*^^»c \
13
8 3.6
6 1.1
1 0.26
13 60.3
15
11 4.7
1 0.51
vc; "\tlRatfc ,s
0.68
1.54
1.28
1.26
1.18


0.82
1.45
1.40
1.26
1.27
1.25



0.98

,^:\ ,0^^""^








7^?^
21:33
26:06
29:20
29:25
29:42


20:47
24:59
25:44
28:35
28:41
29:12



34:49

%\>;x:^f








^agsV




FR
	
B_





^PR

	
	


vFtogsx;f



—



	
                                       Page 1 of2
                          X237.PSR v2.00. LARS & 10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 13:29 10/24/97

-------
       ^|^V^g^^
   •S^^elsfe:
                                 .*. •*&&••*
TLl Project:      43432
Client Sample:   SO-23-2
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:   S976909
F&temaJ Standard v ^ - ,t. An
^| /_ | % %"• *• s | •• "• ..
13C,2-2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
l3C12-1.2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
l3C,2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD

^^a&Ispp* fry pe Afc ^ An
37CU-2,3,7,8-TCDD
13Ci2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-U,3,4,7,8-HxCDD
l3C,2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A) An
13C12-U,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
^c^ry^taadirttee^ ri: 'V V;>*
I3CI2-1A3,4-TCDD
l3C,2-l,2,3,7,8,9-HxCDD
it/Otgj!^^^ ^"2
™ * >'-^s '"• *
4.1
3.6
3.8
4.1
4.8
4.3
3.7
3.6
5.1

tt^ti^^g
4.1
3.7
3.8
3.4
3.8
it'^/ifV'
4.3
4.6
i^v'^4;f


^Rprni
."". *" *^t
103
90.5
96.1
103
120
106
92.4
89.7
63.8

/*F f»frvW^!
102
92.0
95.8
85.6
94.6
^R6C^
107
116
If^bj


ery'^cymits
% -. 7* •;
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%

Irsr^C^lml^
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
Vk •• ^ •> "• %
40%-130%
40%-130%
||^x ;*' - ^


<- - %, Ratio?-. -,.

0.76
0.80
1.47
1.53
0.52
1.19
0.43
0.99
0.91

\ _ \ f

1.53
0.51
1.25
0.41
^ o ffetfifr , *
...AN v ...:•... .
0.51
0.52
"•^Ratio f -'
0.81
1.20
*fff- - ,,-
•.-: •. *••• ss
20:44
21:32
24:58
26:05
28:41
29:24
31:23
32:14
34:43

>tfl^-%
21:33
25:43
28:35
29:19
32:34
VRTKf
29:55
29:12
^FTP^
21:20
29:41
Flags
•*?










f^k




—
"* ' V. ^ "• %

	
Rag* ;


                     Data Reviewer.
            10/24/97
                                       Page 2 of 2
                          X237JSR vZOO, LARS & 10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 13:29 10/24/97

-------
                        Initial
                                  ....Date.
 Data Review By:
                                              Calculated Noise Area: n/a
 The Total Area  for each peak with an ion abundance ratio outside
 ratio limits  has been recalculated according to method requirements.
 Page No.
 10/23/97
Listing  of S976909B.dbf
Hatched  GC Peaks / Ratio  / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2..  Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306










N





D

304-306
13C12-TCDP
316-318


316-318

TCDD
320-322













DC NL 0:00
17:21
17:51
13:05
18:29
18:49
19:19
19:37
19:57
• 20:18
20:34
20:47
21:02
21:14
21:27
21:43
22:01
D SN 22:16
DC WH 22:54
16 Peaks

DC NL 0:00
20:17
20:44
2 Peaks


DC NL 0:00
18:44
19:10
19:30
20:15
20:32
20:58
21:20
21:26
21:33
21:43
21:54
22:08
0.65-0.89
RO 1.45
0.80 1
0.80 1
0.82
0.81 6
0.82 3
0.81 3
0.80 2
0.84 2
0.82 1
0.82 1
0.82 3
RO 1.14
0.81 1
0.80 1
RO 0.96
RO 0.91
RO 1 . 68
0.67
31
0.65-0.89
RO 2 . 63
RO 0.59
0.76 1
1
w™
0.65-0.89
0.73
0.77
0.83
0.73
0.79
0.80
0.82
0.69
0.83
0.68
0.87
0.73
0.80

2.37
,985.05
.022.23
588.58
,142.53
,951.40
,253.75
,733.29
,991.29
,510.30
,207.88
,460.28
9.88
,433.00
.060.16
141.21
16.60
2.25
34.12
,507.43

1.77
9.08
,670.99
.680.07
rppTvp / ny*
IX. Ur / l\*
3.19
464.71
243.13
127.66
460.67
267.81
119.68
140.59
228.91
73.15
51.92
119.67
29.00


883.80
453.46
264.81
2,751.22
1,777.89
1,456.94
1,213.42
1,364.20
682.53
543.15
1,557.61
6.37
641.22
471.92
76.75
8.52





3.95
721.14




202.38
110.22
53.79
203.31
119.28
53.86
57.26
103.57
29.70
24.14
50.31
12.87
0.

1,101.25
568.77
323.77
3,391.31
2,173.51
1,796.81
1,519.87
1,627.09
827.77
664.73
1.902.67
5.58
791.78
588.24
79.78
9.38



0.

6.72
949.85


0.

262.33
132.91
73.87
257.36
148.53
65.82
83.33
125.34
43.45
27.78
69.36
16.13
828-1.098
0.000
0.837
0.861
0.872
0.891
0.908
0.932
0.946
0.962
0.979
0.992
1.002 2378-TCDF AN
1.014
1.024
1.035
1.047
1.062
1.074
1.105

952-1.048
0.000
0.978
1.000 13C12-2378-TCDF ISO


862-1.057
0.000
0.870
0.890
0.906
0.940
0.954
0.974
0.991
0.995
1.001 2378-TCDD AN
1.009
1.017
1.028
Triangle Laboratories, inc.® Analytical Services Division
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 23:24 10/23/97

-------
 Page No.
 10/23/97
Listing of S976909B.dbf
Hatched GC Peaks  / Ratio / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why . .RT. OK Ratio Total .Area...  Area. Peak. 1.. Area. Peak. 2..  Rel.RT Compound. Name..  ID.. Flags.

320-322
37C1-TCDD
328















328
13C12-TCDD
332-334












332-334

PeCDF
340-342
D

D






A
22:37
13 Peaks

DC NL 0:00
DC WL 18:43
DC WL 19:04
DC WL 19:11
DC WL 19:18
20:03
20:18
20:30
20:47
DC SN 20:57
21:33
21:43
21:51
22:00
22:43
DC SN 22:49
9 Peaks

DC NL 0:00
DC WL 18:55
DC WL 19:10
DC SN 19:43
20:16
21:20
21:32
21:53
DC SN 22:09
DC SN 22:15
DC SN 22:37
DC SN 22:51
DC SN 22:53
4 Peaks


DC NL 0:00
D SN 22:44
22:53
D SN 23:08
23:35
23:56
24:05
24:15
24:30
24:42
24:56
0.89
2











1





1
0.65-0.89
RO 1.19
RO 4.20
RO 1.95
RO 1.38
RO 1.39
0.81 1
0.80 1
0.74
RO 1.65
RO 3.79
0.67
0.79
0.66
2

1.32-1.78
RO 0.80
RO 2.03
1.58 1
RO 0.83
1.44
1.55
1.50 2
1.49
1.44
1.53
1.59
22.91
.349.81

0.31
4.72
7.19
8.56
0.60
350.21
4.64
2.43
2.75
1.10
,019.56
1.96
1.70
60.62
2.30
0.69
,446.17

0.48
0.44
2.35
1.84
7.77
,233.72
,190.18
21.80
0.41
0.60
1.55
0.75
1.23
,453.47
wnn /
L\,IJLJ f
0.33
3.29
,182.44
14.77
26.94
681.11
,867.11
704.25
349.28
724.11
174.30
10.77







350.21
4.64
2.43
2.75

1,019.56
1.96
1.70
60.62
2.30







6.10
553.95
529.88
9.25










724.07

15.90
413.73
1,721.02
421 . 67
206.28
437.60
107.00
12.14

0.

















0.




4.39
679.77
660.30
12.55







0.


458.37

11.04
267.38
1,146.09
282.58
143.00
286.51
67.30
1.050

907-1.093
0.000
0.869
0.885
0.891
0.896
0.931
0.943
0.952
0.965
0.973
1.001 37C1-TCDD SUR1
1.009
1.015
1.022
1.055
1.060

907-1.093
0.000
0.878
0.890
0.916
0.941
0.991 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.016
1.029
1.033
1.050
1.061
1.063


909-1.076
0.000
0.911
0.917
0.927
0.945
0.959
0.965
0.971
0.981
0.989
0.999
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 23:24 10/23/97

-------
 Page No.
 10/23/97
Listing  of S976909B.dbf
Matched  GC Peaks / Ratio  / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT.  OK  Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.
M


D





340-342
13C12-PeCDF
352-354








352-354
PeCDD
356-358






M







356-358
13C12-PeCDD
368-370







24:59
25:09
25:18
D SN 25:32
25:44
25:52
26:11
DC SN 26:36
26:43
15 Peaks

DC ML 0:00
DC SN 23:01
DC SN 23:44
24:05
24:58
25:16
25:43
DC SN 26:32
DC SN 26:42
4 Peaks

DC NX, 0:00
24:13
DC SN 24:27
24:43
24:59
25:08
25:19
25:35
25:47
25:55
26:06
26:14
DC SN 26:24
26:35
DC WH 26:48
11 Peaks

DC NL 0:00
DC SN 24:41
DC SN 24:56
DC SN 25:04
DC SN 25:36
DC SN 25:48
26:05
26:14



RO



RO


1.
RO
RO
RO


RO

RO
RO

1.

RO
RO






RO

RO
RO

RO

1.
RO
RO
RO
RO
RO



1.45
1.50
1.51
0.80
1.40
1.65
1.49
0.49
1.58

32-1.78
1.09
1.00
1.86
1.55
1.47
0.74
1.53
1.20
0.42

32-1.78
1.45
1.08
0.04
1.38
1.62
1.58
1.62
1.36
1.51
1.02
1.54
1.86
1.00
1.61
4.25

32-1.78
1.09
4.06
3.11
2.33
1.06
1.35
1.53
1.53
526.00
367.13
469.27
2.94
534.91
368.08
40.96
1.61
45.09
9,060.98

0.39
1.30
2.37
14.48
1,343.24
7.49
1,198.20
0.81
1.83
2.563.41
311
220
282

312
229
24

27





8
799
4
724


.00
.33
.15

.00
.11
.50

.59





.81
.83
.55
.67


215.
146.
187.

222.
138.
16.

17.





5.
543.
6.
473.


00
80
12

91
97
46

50

0.



67
41
13
53


1.
1.
1.
1.
1.
1.
1.
1.
1.

001 12378-PeCDF
007
013
023
031 23478-PeCDF
036
049
065
070

AN



AN





840-1.160
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
922
951
965
000 13C12-PeCDF
012
030 13C12-PeCDF
063
069




123 IS2

234 SUR2




0.54
259.23
1.40
30.24
168.45
70.22
118.90
88.40
51.28
23.02
58.13
28.84
0.56
24.45
0.61
921.16

157

17
104
43
73
50
30
13
35
21

15



.57

.56
.14
.02
.50
.90
.81
.99
.22
.09

.10



145.

12.
64.
27.
45.
37.
20.
13.
22.
11.

9.


0.

90

68
31
20
40
50
47
71
91
31

35


923-1.026
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.

000
928
937
948
958
964
971
981
988
994
001 12378-PeCDD
006
012
019
027











AN





0.847-1.153
0.41
1.35
1.17
1.40
1.25
1.41
806.89
77.43






487
46






.35
.80






319.
30.






54
63
0.
0.
0.
0.
0.
0.
1.
1.
000
946
956
961
981
989
000 13C12-P6CDD
006






123 IS3

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed:

-------
 Page No.
 10/23/97
Listing of S976909B.dbf
Matched GC Peaks / Ratio / Ret.  Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
 368-370
 HxCDF
 374-376
 374-376

 13C12-HXCDF
 384-386
 384-386
 HxCDD
 390-392
DC


DC














DC
DC



DC

DC
DC

DC
DC


DC
DC

DC
DC
DC



DC



SN
2

NL












12

NL
SN



SN

SN
SN

SN
SN
5

NL
SN

SN
SN
SN



SN



26:36
Peaks

0:00
27:36
27:45
27:54
28:03
28:13
28:35
28:41
28:48
29:00
29:12
29:55
30:00
Peaks

0:00
27:35
27:44
28:35
28:41
29:01
29:12
29:23
29:38
29:55
30:09
30:23
Peaks

0:00
27:59
28:08
28:14
28:24
28:29
28:35
28:48
28:57
29:16
29:20
29:25
29:42
RO

1.











RO


0.
RO
RO
RO


RO

RO



RO

1.
RO
RO

RO

RO


RO
RO



0.46

05-1.43
1.19
1.42
1.34
1.27
1.26
1.38
1.26
1.27
1.26
1.25
1.25
0.98
1.28

43-0.59
1.74
0.37
0.77
0.51
0.52
0.17
0.52
0.14
0.44
0.51
0.58
1.46

05-1.43
0.60
0.64
1.23
0.42
1.10
0.42
1.10
1.24
0.78
0.73
1.28
1.26
1.18
0
384
DerfT
r&*.U
3
163
584
78
94
33
312
203
45
93
91
11
18
1,729

0
1
4
1,035
1,127
1
1,009
0
1
812
1
1
3,989
Hvf™Ti
too~v
0
0
37
0
0
0
76
69
5
0
13
18
25
.90
.32

.26
.15
.98
.00
.29
.03
.14
.49
.19
.38
.66
.31
.93
.55

.53
.27
.68
.31
.29
.10
.48
.33
.76
.31
.31
.09
.07

.54
.54
.82
.42
.65
.25
.30
.43
.20
.72
.08
.98
.75
                                                     HxCDF Follows
                                                            95.83
                                                            334.47
                                                            43.61
                                                            52.51
                                                            19.16
                                                            173.72
                                                            113.76
                                                            25.20
                                                            51.79
                                                            50.95
                                                             6.26
                                                            10.64
                                                             2.38
                                                           348.88
                                                           384.21

                                                           346.56
                                                           273.37
                                                          Follows
                                                            20.87
                                                            39.94
                                                            38.37
                                                             2.88

                                                             7.34
                                                            10.59
                                                            13.92
                                                                                 1.020
                                                   0.956-1.052
                                                       0.000
                                                67.32  0.962
                                               250.51  0.967
                                                34.39  0.973
                                                41.78  0.978
                                                13.87  0.984
                                               138.42  0.997 123478-HXCDF
                                                89.73  1.000 123678-HXCDF
                                                19.99  1.004
                                                41.59  1.011
                                                40.71  1.018 234678-HXCDF
                                                 6.42  1.043 123789-HXCDF
                                                 8.29  1.046
AN
AN
AN
AN
                                                   0.861-1.139
                                                       0.000
                                                       0.962
                                                 3.10  0.967
                                               686.43  0.997 13C12-HXCDF 478 SOR3
                                               743.08  1.000 13C12-HXCDF 678 IS4
                                                       1.012
                                                                         662.92
                                                                         538.94
                                                                                 1.018  13C12-HXCDF 234 ALT2
                                                                                 1.024
                                                                                  .033
                                                                                 1.043  13C12-KXCDF 789 ALT1
                                                                                 1.051
                                                                                 1.059
                                                   0.951-1.015
                                                       0.000
                                                       0.952
                                                16.95  0.957
                                                       0.960
                                                       0.966
                                                       0.969
                                                36.36  0.972
                                                31.06  0.980
                                                 3.70  0.985
                                                       0.995
                                                 5.74  0.998 123478-HxCDD
                                                 8.39  1.001 123678-HxCOD
                                                11.83  1.010 123789-HxCDD
AN
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 23:24 10/23/97

-------
 Page No.
 10/23/97
Listing of S976909B.dbf
Hatched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.



390-392
13C12-HXCDD
402-404









402-404
HpCDF
408-410
M








408-410
13C12-HPCDF
418-420




418-420

HpCDD
424-426






424-426
DC
DC
DC


DC
DC

DC



DC
DC
DC


DC



DC
DC

DC
DC
DC


DC

DC

DC




DC

DC
DC

DC
DC

SN
WH
WH
7

NL
WL

SN



SN
SN
SN
4

NL



SN
SN

SN
WH
WH
4

NL

SN

SN
2



NL

SN
SN

WH
WH
2
29:49
29:53
30:01
Peaks

0:00
28:14
28:48
29:12
29:19
29:24
29:41
29:55
30:02
30:09
Peaks

0:00
31:23
31:36
31:43
32:22
32:24
32:36
32:44
32:54
33:03
Peaks

0:00
31:23
32:08
32:34
32:46
Peaks



0:00
31:39
31:53
32:00
32:14
32:29
32:36
Peaks
RO
RO
RO

1.
RO

RO
RO



RO
RO
RO

0.
RO
RO

RO
RO
RO
RO
RO
RO
RO

0.
RO

RO

RO



0.


RO
RO
RO
RO
RO

0
0
0

.43
.24
.67

0.40
0.27
0.11
246.56
05-1.43
0
1
0
0
1
1
1
1
1
0

.79
.27
.75
.67
.25
.19
.20
.64
.95
.37
ltW«M..
88-1.20
3
1
0
0
2
6
1
1
7
7

.42
.23
.93
.84
.13
.30
.67
.77
.48
.90

0.40
0.68
3.76 2.08
0.65
690.11 382.85
828.75 450.31
782.11 427.38
0.63
0.94
0.42
2,304.73
Uvf^nn 1 U«<"*TO7 17/tl 1 m*re

0.49
73.24 44.30
22.64 10.92
12.30 6.27
0.98
0.67
9.98 8.17
2.04
0.55
0.61
118.16
37-0.51
0
0
1
0
3



.78
.43
.00
.41
.12



0.39
640.83 192.53
1.31
467.44 136.01
1.18
1,108.27
tin/Tit? 1 UnffV) T?«1 1 ni*te

88-1.20
1
1
2
0
0
1
4

.05
.08
.82
.71
.77
.55
.19

0.45
21.22 11.00
1.00
1.26
17.93 9.14
0.67
0.63
39.15




0.


2.77

307.26
378.44
354.73




0.

35.90
11.72
7.50


4.89




0.

448.30

331.43




1.
1.
1.

014
016
021





966-1.034
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.

000
960
980
993
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
018
022
026





SUR4
IS5
RS2




995-1.044
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.

000
000 1234678-HpCDF
007
Oil
031
032
039 1234789-HpCDF
043
048
053


AN




AN




936-1.127
0.
1.
1.
1.
1.



000
000 13C12-HpCDF 678
024
038 13C12-HpCDF 789
044




IS6

SUR5



0.977-1.006

10.22


11.94



0.
0.
0.
0.
1.
1.
1.

000
982
989
993
000 1234678-HpCDD
008
Oil





AN



Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive* Durham, North Carolina27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 23:24 10/23/97

-------
 Page Mo.
 10/23 '97
Listing of S976909B.dbf
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z ----  QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.
13C12-HpCDD
436-438






436-438

OCDF
442-444













M




442-444
OCDD
458-460
M


458-460
13C12-OCDD
470-472



470-472

DC
DC
DC
DC

DC
DC




DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

DC
DC
DC
DC


DC

DC
DC


DC

DC
DC


NL
SN
SN
SN

SN
SN
1



NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN

SN
SN
SN
SN
1

NL

SN
SN
1

NL

SN
WH
1

0:00
31:38
31:56
32:05
32:14
32:27
32:40
Peak



0:00
31:36
32:05
32:55
33:07
33:15
33:31
33:42
33:52
34:02
34:21
34:25
34:30
34:42
34:49
34:59
35:34
35:45
35:57
Peak

0:00
34:44
35:06
35:15
Peak

0:00
34:43
34:53
35:16
Peak
0.
RO
RO
RO
RO

RO
RO



0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO
RO

RO
RO
RO
RO

0.

RO
RO
RO

0.


RO
RO

88-1.20
1.
1.
0.
0.
0.
2.
0.



39
35
63
87
99
09
77

- Above:
0
2
0
1
571
1
1
571
.47
.02
.75
.61
.53
.14
.10
.53
HpCDD /
76-1.02
1.
10.
0.
2.
5.
0.
0.
0.
4.
0.
0.
3.
1.
2.
0.
0.
3.
2.
0.

67
00
30
13
88
66
43
16
78
61
92
61
64
68
98
27
86
97
60

0
0
0
0
0
0
0
0
0
1
1
.34
.21
.87
.72
.15
.57
.91
.40
.17
.34
.59
0.62
0
.53
0.7C
3
0
0
0
1
3
.91
.40
.68
.70
.13
.91
76-1.02
0.
1.
1.
0.

91
23
70
61

0
.42
6.29
0
0
6
.38
.53
.29
76-1.02
0.
0.
1.
1.

83
91
17
32

0
517
1
1
517
.42
.94
.95
.70
.94
                                                          284.61
                                                  0.969-1.031
                                                      0.000
                                                      0.981
                                                      0.991
                                                      0.995
                                              286.92  1.000 13C12-HpCDD 678 IS7
                                                      1.007
                                                      1.013
                                                                    Follows
                                                            1.94
                                                            4.11
                                                                           0.885-1.115
                                                                               0.000
                                                                               0.910
                                                                               0.924
                                                                               0.948
                                                                               0.954
                                                                               0.958
                                                                               0.965
                                                                          1.97
                                                      0.971
                                                      0.976
                                                      0.980
                                                      0.989
                                                      0.991
                                                      0.994
                                                       .000
                                                       .003 OCDF
                                                       .008
                                                       .024
                                                       .030
                                                                                                    AN
                                                          246.14
                                                                               1.036
                                                  0.885-1.115
                                                      0.000
                                                3.33  1.000  OCDD
                                                      1.011
                                                      1.015
                                                  0.995-1.005
                                                      0.000
                                              271.80  1.000  13C12-OCDD
                                                      1.005
                                                      1.016
                                                                                                    AN
                                                                                                    IS8
Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 23:24 10/23/97

-------
 Page No.
 10/23/97
Listing of S976909B.dbf
Matched GC Peaks /  Ratio / Ret.  Time
 Compound/
 M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound. Name..  ID..  Flags.
 Column Description	  'Why* Code Description	  QC Log Desc.
 M_Z   -Nominal  Ion Mass(es)
 ..RT. -Retention Time  (mm:ss)
 Rat.l -Ratio of M/M+2  Ions
 OK    -RO=Ratio outside Limits
 Rel.RT-Relative Retention Time
     End of Report
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
File ,3976909 tl-848 Aoq,23-OCT-1997 17,16,18 EH- Voltage SIR 70S Soiae>968
303.9016 Fi2 BSUB(256,30,-3.0) fXD(9, 5,5,0.05%, 3872.0,1.00\,F,T) ExptEPCUS
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TRIANGLE LABS Text,SO-M23-2 TLIt 43432
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-------
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TRIASGLX LABS Text: SO-H23-2 TLIt 43432
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TRIASGLX LABS Text: SO-H23-2 TLIt 43432
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TRIASGLX LABS Text:SO-H23-3 TLIt 43433
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TRIANGLE LABS Text: SO-H23-2 TLIt 43432
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-------
rlla:S976909 tl-848 Acq:23-OCT-1997 17:16:18 EH- Voltage SIS 70S Noise: 98
339.8597 T,2 BSUB(256, 30, -3.0) PKD(7, 5,3,0 .OS\, 392. 0,1. 00\,f,T) EzptEPCVS
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341.8567 t,2 BSOB(256, 30, -3.0) PKD(7,5,3,0.05\,492.0,1.00\,F,T) Exp:EPCUS
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Time
rile:S976909 tl-848 Acq:23-OCT-1997 17,16,18 EH- Voltage SIS 70S Noise: 122
351.9000 F:2 SSUB(256,30, -3 .0) PXD(7,5,3,0.05\t488.0,1.00\rr,T) XxptXPCOS
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353.8970 T,2 B3UB(256, 30, -3.0) PKD(7, 5, 3,0. 051,440. 0,1.00\,T,T) XxpiXfCUS
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369.8919 T>2 BSOB(2S6, 30, -3.0) PKD(7,5,3,0 .05\,452.0,1.00\,F,T) XxpiEPCUS
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Filet S976909
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389.8156 r,3 BSUB(256,30,-3.0) PXD(7,5, 3, 0.051,600 .0,1. 00*,r,T) ExpsEPCOS
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rile, 3976909 01-445 Acq,23-OCT-1997 17,16,18 EI+ Voltage SIS 70S Noise « 252
391.8127 T,3 BSUB(256,30,-3.0) PKD(7, 5, 3, 0.051,1008. 0,1.00\,F,T) ExpiEPCUS
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401.8558 Ti3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,444.0,1.00\,r,T) ExpiEPCUS
TRIANGLE LABS Toxt,SO-H23-2 TLIt 43432
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Tile, 3976909 #1-445 Aoq,23-OCT-1997 17:15:10 EH- Voltage SIS 70S Noise .-140
403.0529 Fi3 BSUB(256,30,-3.0) PXD(7,5,3,O.OS\,560.0,1.00*,F,T) ExpiEPCUS
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rile ,3976909 #1-445 Aeqt23-OCT-1997 17:15:10 BI+ Voltage SIS 70S
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F±le:S976909 tl-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S Soiso:408
407.7818 F:4 SSOB(256,30,-3.0) PXD(7,5,3,0.05\,1632.0,1.00\,F,T) Exp:EPCOS
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409.7789 Tit BSUB(256,30,-3.0) PXD(7, 5, 3,0. 051,484. 0,1.00*,F,T) ExptEPCUS
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417.8253 F:4 BSUB(256,30,-3.0) PXD(7,5,3,0. 051,420. 0,1.00\,F,T) Exp:EPCUS
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430.9739 F:4 ExptEPCUS
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423.7766 F:4 BSUB(256, 30, -3.0) PKD(7, 5, 3,0. 051,460 .0, 1.00\,r,T) Exp:EPCUS
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437.8140 F:4 BSUB(256, 30, -3.0) PKD(7,5,3,0.05\,460 .0,1.00\,F,T) ExpiEPCUS
TRIANGLE LABS Text:SO-M33-3 TLIt 43432
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443.7399 Ft4 3303(356,30, -3.0)  tXD(7,5r3,0.05\,368.0,l.OO\,F,T) ExptSPCUS
TRIANGLE LABS  Text:SO-M23-2  TLIt  43432
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441.7438 Ti4 BSOB(256,30,-3.0)  PXD(7,S,3,0.05%,600.0,1.00\,f,T) ExpiSPCUS
TRIANGLE LABS  Text,SO-H23-2 TLIt 43433
   31:00             32tOO             33,00             34tOO
TilutS976909 tl-403 Acq:23-OCT-J.997 17tl6tl8 XH- VoltMgt SIS 70S
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TRIANGLE LABS  Text:SO-M23-2  TLIt 43432
                                                                          35:00
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                                                                                   35,28
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File:S976909 tl-403 Acq:23-OCT-lS97 17,16,18 XH- Voltage SIX 70S
513.6775 r,4 XxpiEPCUS
TRIANGLE LABS  Text:SO-M23-2 TLIt 43432
                                                                          35,00
,.3.0X6
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 2.4X6
 2.1X6
 1. 8X6
 1.5X6
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                     32,00
                                       33,00
                                                        34,00
                                                                          35,00

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FileiSS7690S #1-403 Acqt 13-OCT-1991 17H6,18 EH- Voltage SIR 70S Noise1102
457.7377 T,4 BSOS(256,30, -3.0) Pn>f7,5,3,0.05\,408.0,1.00\,r,T) XxpiEPCUS
TRIANGLE LABS  TaxttSO-H23-2  TLIt 43433
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                                                                   A5.61X3
       34.35          34142         34:48         34s54          35,00
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459.7348 T>4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,440.0,1.00\,F,T) XxptEPCUS
TRIANGLE LABS  TextiSO-M23-2  TLIt 43433
1004                  R4.26E4
                                                                              35:06
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       34136          34t42         34:48         34,54         35:00
Tile:3976909 tl-403 Acqt23-OCT-1997 17tl6>18 EI+ Voltage SIR 70S Noiae:97
469.7779 Fi4 BSUB(256,30r-3.0) PXD(7,5,3,0.05\,3B8.0r1.00\rTrT) EipiEPCUS
TRIANGLE LABS  Text.:SO-M23-2 TLIt 43433
1001                  A2.46E6
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                                                                              35 i 06
      34,36          34:42         34,48         34,54         35:00
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471.7750 r>4 BSOB(256,30,-3.0) PKD(7,5,3,0.051,468.0,1.00\r,T) ExpiEPCUS
TRIANGLE LABS  Text:SO-M23-2 TLIt 43433
100*                  A2.72E6
                                                                              35 > 06
      34:36          34,42         34:48         34:54         35,00
File,3976909 tl-403 Acq,23-OCT-1997 17:16,18 EI+ Voltage SIR 70S
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TRIANGLE LABS  Text,SO-H23-2 TLIt 43432
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File:S976909 #1-848 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
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File:S97690y
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File:S976909 #1-445 Acq:23-OCT-1997  17:16
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Sample Text .-SO-M23-2 TLIt 43432 File Text
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Sample Text :SO-M23-2
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Sample Text -.SO-M23-2
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100%                      A4.19E4
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100%                      32;34
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Sample Text :SO-M23-2 TLI# 43432 File
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Sample Text :SO-M23-2 TLI# 43432 File Text :SO-M23-2 TLI# 43432
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File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
441.7428 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%                                               A1.94E4
 80 j
 60 j
 40 J
 20 j
  0
       33:36   33:48  34:00   34:12  34:24  34:36   34:48  35:00
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%
                                                                  35:12   35:24  35:36
 60J
 40 j
 20J
                                                    A1.97E4
       33:36   33:48  34:00   34:12   34:24  34:36   34:48   35:00
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EH- Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%                                            34;43
 80 J
 60 j
 40 J
 20J
                                                                   35:12   35:24  35:36
.1.2E4
.9.5E3
.7 . 1E3
.4.8E3
2.4E3
.O.OEO
   Time
.1.6E4
.1.3E4
9.8E3
6.6E3
.3.3E3
O.OEO
   Time
       33:36   33:48  34:00   34:12   34:24  34:36   34:48  35:00  35:12   35:24  35:36
.9.6E5
.7.7E5
.5.7E5
.3.8E5
.1.9E5
.O.OEO
   Time

-------
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage  SIR  70S
457.7377 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
100%                                         A4.11E4
 80 j
 60 j
 40J
 20J
    33:24  33:36 33:48  34:00  34:12 34:24  34:36  34:48 35:00  35:12
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18 EI+ Voltage  SIR  70S
459.7348 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
lOOi                                         A3.33E4
 80 j
 6Ql
 40J
 20J
                                                                    35:24 35:36 35:48
    33:24  33:36 33:48  34:00  34:12 34:24  34:36  34:48 35:00  35:12  35:24 35:36 35:48
File:S976909 #1-403 Acq:23-OCT-1997 17:16:18  EI+ Voltage  SIR  70S
469.7779 F:4 Exp:EPCUS
Sample Text:SO-M23-2 TLI# 43432 File Text:SO-M23-2 TLI# 43432
lOOi                                          34;43
 80J
 60 J
 40J
 20 j
  OJ
.2.5E4
.2.0E4
.1.5E4
.9.8E3
.4.9E3
.O.OEO
   Time
                                                                                         .2.0E4
                                                                                          1.6E4
                                                                                         .1.2E4
                                                                                         .8.0E3
                                                                                         .4.0E3
                                                                                         .O.OEO
                                                                                             Time
     33:24  33:36 33:48  34:00  34:12 34:24  34:36  34:48 35:00
                                                              35:12
35:24 35:36 35:48
.9.6E5
.7.7E5
.5.7E5
.3.8E5
.1.9E5
.O.OEO
   Time

-------
TLI Project:      43432
Client Sample:   SO-23-2
           Method 23 TCDD/TCDF Analysis (DB-225)
                                Analysis File:   X973637
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-2A-C
1.000
n/a
DB-225
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/18/97
Dilution Factor: n/a
Blank File: U973257
Analyst: WK
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
XF24087
X973633
n/a
n/a
n/a
2,3,7,8-TCDF
2.3
                       0.81
                      24:34
    a$^^                                                               ^T
13C12-2,3,7,8-TCDF
4.1
102
40%-130%
0.81
24:32
13C,2-1,2,3,4-TCDD
                                    0.77
                               23:19
                      Data Reviewer
                                10/23/97
                                         Page 1 of 1
                                             C2NF.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                          Printed: 23:35 10/23/97

-------
                        Initial
                                  	Date..
 Data Review By:
                            NJCxo^^
                     Calculated Noise Area: n/a
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according  to method requirements.
 Page No.
 10/21/97
Listing of X973637B.dbf
Matched GC Peaks  / Ratio
/ Ret. Tina
 Compound/
 M_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.

 TCDP
 304-306
 304-306

 13C12-TCDF
 316-318
0.65-0.89
DC

DC
DC
DC
DC




DC





DC
DC


DC











DC

DC
DC

DC
DC

NL

SN
SN
SN
SN




SN





SN
SN


SN











SN

SN
SN

WH
WH
25
0:00
19:46
19:53
20:02
20:14
20:24
20:47
20:55
21:03
21:14
21:21
21:30
21:39
21:49
21:59
22:06
22:14
22:20
22:31
22:36
22:44
23:00
23:07
23:15
23:31
23:46
23:57
24:25
24:34
24:48
25:07
25:17
25:55
26:14
26:23
26:58
27:06
27:21
27:33
Peaks
0.
0.
RO 3.
RO 1.
RO 0.
RO 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RO 0.
RO 1.
0.
RO 0.
RO 3.

66
80
00
01
60
34
79
77
78
78
72
76
79
78
78
76
80
61
75
77
81
79
73
79
79
82
77
80
81
81
78
78
76
78
91
23
80
43
24

21
8,495
62
73
39
148
13,320
7,752
8,644
7,099
169
4,675
6,195
2,341
15,202
4,162
78
43
7,726
5,226
104
6,044
1,175
5,631
5,798
707
4,023
3,633
4,152
3,185
2,895
6,382
11
3,455
19
17
391
4
7
138,322
.56
.70
.55
.76
.58
.95
.82
.27
.06
.25
.50
.95
.78
.81
.73
.71
.00
.40
.96
.59
.58
.28
.93
.71
.13
.60
.08
.01
.48
.56
.64
.38
.19
.95
.52
.75
.69
.30
.01
.07

3,766




5.869
3,377
3.782
3,117

2.021
2.728
1,023
6,682
1,800


3,314
2.281

2.664
494
2,485
2,553
317
1,750
1,611
1,852

.87




.09
.05
.61
.04

.87
.44
.23
.46
.26


.63
.35

.57
.50
.71
.03
.89
.34
.11
.31
1,428.29
1,270
2,788

1,517


173



.67
.82

.73


.82




4,




7,
4,
4,
3,

2,
3,
1,
8,
2,


4,
2,

3,

3,
3,

2,
2,
2,
1,
1,
3,

1,






0.65-0.89
DC
NL
0:00
0.
77
19
.98



0.

728.83




451.73
375.22
861.45
982.21

654.08
467.34
318.58
520.27
362.45


412.33
945.24

379.71
681.43
146.00
245.10
389.71
272.74
021.90
300.17
757.27
624.97
593.56

938.22


217.87



0.

798-1.112
0.000
0.806
0.810
0.817
0.825
0.832
0.847
0.853
0.858
0.865
0.870
0.876
0.882
0.889
0.896
0.901
0.906
0.910
0.918
0.921
0.927
0.938
0.942
0.948
0.959
0.969
0.976
0.995
1.001 2378-TCDP
1.011
1.024
1.031
1.056
1.069
1.075
1.099
1.105
1.115
1.123

959-1.041
0.000
                                                                                                    AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 20:5AlO/21/97

-------
 Page No.
 10/21/97
Listing of X973637B.dbf
Matched GC Peaks / Ratio /  Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.
 316-318
 13C12-TCDD
 332-334
 332-334
DC
DC
DC
DC
DC

DC
DC
DC


DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

WL
WL
WL
WL
SN

SN
SN
WH
1

NL
SN
SN


SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
WH
WH
2
21:04
22:59
23:14
23:20
23:37
24:32
24:45
25:16
26:59
Peak

0:00
21:03
22:00
23:00
23:19
23:32
23:37
24:05
24:15
24:39
24:42
24:45
24:59
25:25
26:03
26:11
26:24
26:41
Peaks
RO
RO
RO
RO
RO

RO
RO
RO

0.
RO
RO
RO


RO
RO
RO
RO
RO
RO
RO

RO
RO
RO
RO
RO

2
1
0
1
1
0
0
0
1

.38
.18
.26
.04
.19
.81
.20
.21
.19

65-0.89
1
2
1
0
0
1
0
0
0
4
0
2
0
8
0
1
2
1

.63
.41
.09
.80
.77
.00
.53
.59
.59
.03
.49
.22
.80
.21
.50
.64
.46
.38

                       4.53
                      29.06
                      11.98
                       8.16
                       5.20
                   7,632.04      3,415.57
                       6.34
                      10.44
                      70.78
                   7,632.04

              Above:  TCDF / TCDD Follows -
                                                                        4,216.47
                 0.859
                 0.937
                 0.947
                 0.951
                 0.963
                 1.000  13C12-2378-TCDF ISO
                 1.009
                 1.030
                 1.100
                                                7.59
                                                4.80
                                                6.58
                                             5,214.85      2,316.60
                                             5,391.44      2,347.91
                                               30.64
                                                3.31
                                               53.79
                                                3.56
                                                2.57
                                                8.32
                                                6.85
                                                7.32
                                                2.19
                                                7.65
                                               ' 6.99
                                                3.56
                                                6.00
                                            10,606.29
                                                    0.913-1.087
                                                        0.000
                                                        0.915
                                                        0.957
                                              2,898.25  1.000  13C12-2378-TCDD IS1
                                              3,043.53  1.014  13C12-1234-TCDD RSI
                                                        1.023
                                                        1.027
                                                        1.047
                                                        1.054
                                                        1.072
                                                        1.074
                                                        1.076  .
                                                        1.086
                                                        1.105
                                                        1.133
                                                        1.138
                                                        1.148
                                                        1.160
 Column Description	   "Why"  Code  Description	  QC Log Desc.
 H_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio outside Limits
 Rel.RT-Relative Retention Time
 *** End of Report ***
       WL-Below Retention Time Window
       WH-Above Retention Tim* Window
       SN-Below Signal  to Noise Level
       
-------
FllatX973637 #1-003 Acq: 18-OCT-1SS7 15*37*41 OC EH- Voltage SIX AUtOSpec Ooiee:4274
303.9016 BSUB(256,30,-3.0) PKD(5,3,1,0.10*,17096.0,0.00\,F,P) Exp:XCOBP_TT
Sample TaxttSO-H23-2   TLIif43432 Pile Text* TRIJUmLE LABS
100*          A5.87S7

 BO.
      20100      31*00       22:00      23:00      24iOO       2SiOO      26tOO      27:00
file: 1973 637 #1-003 AaqtlB-OCT-1997 15:37:41 OC EI+ Voltage SIR AutoSpec Nolae:6504
305.8987 BSUB(256,30,-3.0) PXO(5,3,1,0.10*,26016.0,O.OOX,F,P)
Saaplf T*xt:SO-K23-2   TLI*43432 Pllf Tuttt TRUWQLB LAB3
IOOH          JL7.4SE7
      20:00       21:00       22:00      23:00      24*00       25*00      26:00      27*00
Film 1X973637 #1-803 ley: 18-OCT-1997 15:37:41 OC EH- Voltage SIR XutoSptc Holm*:4359
315.9419 B3UB(256,30,-3.0) PXD(5,3,1,0.10*, 17436.0,0.00*,F,P) Sq?»XCOHP_TT
Saoplu T»Xt:3O-IO3-2   TLIK43432 Film Tmxt: TRIUSUKS tABS
100JC                                                    A3.42E7

  BO.

  60.

  40.

  20.
      20:00       21:00      22:00      23:00       24*00      25*00      26*00      27*00
Pile :X973 637 #1-003 Aag*18-OCT-1997 15*37*41 OC KT+ Voltage SIR JLutoSpec Soi*e:S629
317.9389 BSUB(25f,30,-3.0) PXD(5,3,1,0.10*,22516.0,0.00*,P,P) BtptXCOBFJTV
Staple TextiSO-H23-2   TLX143432 Pile Text* TRaOOLS UBS
                                                         A4.22S7
BO:

eo:

40.

20.

 o:
      20(00       21<00      22(00      23(00       24(00      25(00      2tf»00
Pilu:XS73637 #1-003 JL.c
-------
Pile,X973S37 #1-903 Acqil9-
-------
Pll»*X973637 #1-003 Aaq*18-OCT-1997 15:37:41 OC EH- Voltago SIR AutoSpac
303.9016 Exp*XCONP_TT
Saapla Toxt:SO-M23-2   TLIt43432 Filo Taxtt TRIASBLE LABS
      20(00       21<00      22:00      23:00      24:00       25:00
P11»:XS73637 #1-003 AeqilB-OCT-1997 15:37:41 OC EH- Voltayt SIR AutoSpfc
315.9419 SxptXCOSP TV
Sanpl* T*Xt:SO-H23-2   TLH43432 Pile Text: TRIABOLE LABS
iota
 sol
 60:
 40:
 20.
      20*00       21>00      22 tOO      23tOO      24:00      25:00
Pilf 1X973637 * 1-803 AcqtlB-OCr-1997  15 1 37 t 41 OC SH- Voltage SIS AutoSpec
319.8965 S*piKOHf_Tr
Saoplf Text:SO-K23-2    TLH43432 Film Ttxtt TRIMK3LE LABS
100*         20(34
  80:
  60:
  40:
  20:
                                                                      •i-
  OJ
                                                                          26:00
                                                                                     27(00
                   21(10
                           21(51
                                           23:18
                                                     24(00
      20(00      21(00      22(00      23(00      24(00       25:00
Pil»*X973637 #1-003 AcytlB-OCT-1997 15*37*41 OC El* Voltage SIS AutoSpea
331.9368 SxptXCONP_TT
       TextiSO-K23-2   TLIf43432 Pile Text: TSIABOLX LABS
100*                                        23,19
 so:
 ffflj
 40:
 20:
                                                                          26*00
                                                                                     27100
   oj
      20(00      21(00      22(00      23(00      24(00       25(00
Pile*X973637 #1-003 ActjtlS-OCT-1997 15(37(41 OC EH- Voltage SIS
292.9825 ExptXCONP_TT
Staple TexttSO-K23-2   TLIf43432 Pile Text* TRIAHOLE LABS
1003^	^0(24  31(03  21*36      	_^^JV1^-12314g.  24(22 ,24(54  75(25
 80:
 60:
 40:
 20:
                                                                                               8.2X6
                                                                                               6.6X6
                                                                                               .4.9X6
                                                                                               3.3X6
                                                                                               .1.6X6
                                                                                               .0.0X0
                                                                                                  Time
                                                                                               .2.2E6
                                                                                               .1.6S6
                                                                                               .1.1S6
                                                                                               .5.425
                                                                                                0.050
                                                                                                   Tim*
                                                                                               .6.3E6
                                                                                               '-.5.0E6
                                                                                               '-3.8B6
                                                                                               .2.5E6
                                                                                               .1.3E6
                                                                                     27(00
                                                                             26*16 26*49 27*20
                                                                                                O.OEO
                                                                                                   Time
                                                                                               .9.3X7
                                                                                               .6.9X7
                                                                                               .4.6X7
                                                                                               -.2.3X7
      20*00       21(00      22(00      23(00      24(00       25(00      26:00
PileiX973637 #1-003 Actjil8-OCT-1997 15(37(41 OC SI* Voltage SIS AutoSpeo
330.9793 XxptXCOSPJTT
Staple Text:SO-M23-2   TLH43432 Pile Text* TRIANGLE LABS
lOOH  ^jOjOy     20(50      21(50	33*36 23*58 ^24,39    25(27   36*11
                                                                                     27:00
                                                                                                0.0X0
                                                                                                   Time
  00:

  40:
  20:
   o:
       20(00
                  21(00
                             22(00
                                         23(00
                                                                                               .1.1X8
                                                                                               .8.6X7
                                                                                               .6.5X7
                                                                                               -.4.3X7
                                                                                               .2.2X7
                                                                                                0.0X0
                                                    24(00
                                                               25(00
                                                                          2f(00
                                                                                     27(00

-------
               Peak Locate Examination:18-OCT-1997:15:37 File:X973637
                    Experiment:XCONF_TT Function:! Reference:PFK
-U

-------
          %  "*
TLI Project:      43432
Client Sample:   SO-23-3
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U973260
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-3A-C
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
"", \ "\ vv ^^^^ £$',* ^ J <^
•AfWww'9' % % ^ ^ s s \ '•>• % % %--
* s % V
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
total* : ,:x*;/ , " ^
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
&£i£j%X$i&
^•w^mjfc.
>' v>. * ^¥^.*"T
0.13
0.10
ND
ND
ND
ND
EMPC
4.5
0.65
0.47
0.18
0.09
0.05
ND
0.04
ND
ND
5 &rafe-$|t
4.1
0.74
0.24
ND
512
10.7
0.92
0.04
V^ic^fc^Wi^ ^V-3^ii*£ttiv'% 0 " -• * ->"s > W z w?V ^^^B^- '"•"' ^\iii ^%
% s
-------
TLI Project:      43432
Client Sample:   SO-23-3
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U973260
Internal Standards* , - ? "\ An
13C12-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C.2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13Ci2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C.2-l,2,3,4,6,7,8-HpCDD
I3C.2-1,2,3,4,6,7,8,9-OCDD
£^*t*^r^$,{!yp*A)^ An
37CU-2,3,7.8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13C12-l,2,3,4,7,8-HxCDD
l3C.2-l,2,3,4,7,8,9-HpCDF
Alternate Standards  	
0.73
0.78
1.45
1.41
0.50
1.14
0.42
0.96
0.84
[tette'"^

1.46
0.53
1.25
0.43
^aitio
0.51
0.52
iteitia - " '-
0.80
1.17
RT - Flags
21:36 	
22:32 	
26:18 	
27:30 	
30:15 	
30:59 	
33:03 	
33:54 	
36:26 	
;\8r>; BMJ$;\
22:32
27:07 	
30:09 	
30:55 	
34:16 	
lf^vj?lags\
31:31 	
30:47 	
rwr:*?^j*tas*.
22:17 	
31:18 	
                     Data Reviewer.
                                       Page 2 of 2
            10/23/97
                          X237_J>SR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 23:14 10/23/97

-------
                        Initial
                                  	Date.
 Data Review By:
                     Calculated Noise Area:   7.22
 The Total Area Cor each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
Listing of O973260B.dbf
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_2	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306



304-306
13C12-TCDF
316-318










316-318

TCDD
320-322




H

M
DC NL



IS

DC NL
DC WL
DC WL
DC WL
DC SN

DC SN
DC SN
DC SN
DC SN
DC WH
1


DC NL







0:00
17:44
18:17
18:33
18:57
19:19
19:52
20:15
20:41
21:05
21:23
21:39
22:11
22:26
22:43
23:44
Peaks

0:00
18:49
18:56
19:00
21:05
21:36
21:54
22:20
22:24
22:26
22:56
Peak


0:00
19:15
19:43
20:08
21:03
21:22
21:52
22:24
0.
RO

RO
RO

0.
RO
RO

RO
RO

RO
RO
RO
RO
RO


0.
RO







65-0.89
1.34
0.71
0.75
0.74
0.73
0.74
0.74
0.78
0.74
0.74
0.76
0.74
0.73
0
0
1

.79
.97
.21

9
2,831
1,243
577
7,721
4,752
3,941
2,728
3,085
1,796
1,312
3,061
1,218
696
76
38
35,081
.27
.28 1,179.33
.82 532.84
.11 246.22
.50 3,265.44
.79 2,019.10
.26 1,672.04
.83 1,191.72
.78 1,315.78
.14 765.67
.02 567.37
.36 1,305.04
.59 513.33
.24 308.03
.84 42.24
.30 26.17
.86
65-0.89
1
1
0
0
0
0
1
0
0
1
1


.15
.21
.78
.40
.49
.73
.22
.44
.30
.45
.01

nv-
65-0.89
1
0
0
0
0
0
0
0
.07
.75
.74
.72
.72
.74
.69
.80
8
3
7
8
15
2,536
.04
.63
.62
.80
.15
.01 1,071.86
0.813-1.106
0.000
1,651.95 0.821
710.98 0.846
330.89 0.859
4,456.06 0.877
2,733.69 0.894
2,269.22 0.920
1,537.11 0.938
1,770.00 0.958
1,030.47 0.976
744.65 0.990
1,756.32 1.002 2378-TCDF AN
705.26 1.027
388.21
43.41
21.64

0.





1,464.15
7.27
5
2
8
9
2,536

iv% s TCu
5
723
414
156
632
295
171
507
.45
.09
.99
.13
.01
B 1 IfVnn T7/\l 1 ruia —

.77
.32 310.56
.15 176.78
.31 65.35
.93 264.91
.00 125.00
.36 69.74
.00 225.00






0.

412.76
237.37
90.96
368.02
170.00
101.62
282.00
1.
1.
1.

039
052
099

954-1.046
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.


000
871
877
880
976
000 13C12-2378-TCDF ISO
014
034
037
039
062


848-1.061
0.
0.
0.
0.
0.
0.
0.
0.
000
854
875
893
934
948
970
994
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 20:17 10/21/97


-------
 Page No.
 10/21/97
Listing of U973260B.dbf
Matched GC Peaks  / Ratio / Ret. Time
 Compound/
 M_Z	  QC.Log Omit Why  .-RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID..  Flags.
H


K




320-322
37C1-TCDD
328























328
13C12-TCDD
332-334










332-334




DC
DC
DC
DC





SN
SN
WH
WH
11
22:32
22:43
22:57
23:12
23:22
23:44
24:08
24:13
Peaks
0.
0.
0.
RO 0.
0.
0.
0.
RO 2.

87
74
84
52
86
80
66
42

99
62
124
26
5
26
3
3
3,212
.00 46.10
.31 26.52
.14 56.79
.80 11.66
.87
.20
.28
.49
.32
52.90 1
35.79 1
67.35 1
22.22 1
1
1
1
1

.000 2378-TCDD AN
.008
.018
.030
.037
.053
.071
.075

0.911-1.089
DC
DC
DC
DC
DC
DC
DC
DC
DC

DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC

NL
WL
WL
WL
WL
WL
WL
WL
WL

SN
SN
SN
SN
SN


SN
SN
SN
SN
SN
SN
SN
3
0:00
19:36
19:45
19:53
20:02
20:14
20:15
20:21
20:30
20:48
21:04
21:12
21:18
21:36
21:39
22:32
23:03
23:12
23:21
23:34
23:45
23:51
24:06
24:09
Peaks










4
12
9
3
1
.82
.91
.23
.66
.74
1.29




1
3
.26
.49
3.77
































411
7
6
3
5
1
2,095
49
3
8
8
5
12
4
3
2.556
.94 411.94
.18
.18
.72
.80
.10
.49 2,095.49
.33 49.33
.85
.68
.06
.75
.25
.14
.04
.76
0.65-0.89
DC
DC
DC



DC
DC
DC
DC
DC

NL
WL
WL



SN
SN
SN
SN
SN
3
0:00
19:23
19:29
22:17
22:32
22:55
23:18
23:25
23:28
23:57
24:06
Peaks
RO 2.
RO 3.
RO 3.
0.
0.
0.
RO 0.
RO 4.
RO 1.
RO 0.
RO 0.

24
37
21
80
78
88
49
02
17
46
25

6
2
3
3,973
2,582
86
6
4
13
8
6
6,642
.53
.50
.56
.84 1,767.61
.73 1,128.21
.42 40.33
.23
.60
.52
.78
.69
.99
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1

.000
.870
.876
.882
.889
.898
.899
.903
.910
.923
.935
.941
.945
.959
.961
.000 37C1-TCDD SOR1
.023
.030
.036
.046
.054
.058
.070
.072

0.911-1.089
0
0
0
2,206.23 0
1,454.52 1
46.09 1
1
1
1
1
1

.000
.860
.865
.989 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.017
.034
.039
.041
.063
.070

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 20:17 10/21/97

-------
 Page No.
 10/21/97
Listing of U973260B.db£
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z	  QC.Log Omit Why  .-RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.












K



356-358
13C12-PeCDD
368-370







368-370
HxCDF
374-376







K
K


374-376
13C12-HXCDF
384-386




25:30
DC SN 25:45
26:02
26:19
26:28
26:40
26:52
26:58
27:11
27:20
27:30
27:40
28:02
DC WH 28:22
DC WH 28:28
DC WH 28:39
12 Peaks

DC NL 0:00
DC SN 25:35
DC SN 26:19
DC SN 27:21
27:30
27:40
DC SN 28:02
DC SN 28:12
2 Peaks

DC NL 0:00
29:07
29:17
29:26
29:35
DC SN 29:45
30:09
30:15
30:23
30:35
30:47
DC SN 30:53
9 Peaks

DC NL 0:00
30:09
30:15
30:47
31:31
RO
RO

RO


RO
RO



RO


RO
RO

1.

RO

RO

RO

RO

1.
RO




RO


RO


RO

0.





0.91
0.22
1.47
1.29
1.51
1.51
0.95
1.30
1.61
1.78
1.63
1.89
1.68
1.65
1.91
0.67

32-1.78
1.60
4.46
1.68
1.79
1.41
1.82
1.36
2.12

05-1.43
0.92
1.35
1.14
1.34
1.15
1.48
1.24
1.23
1.64
1.07
1.25
0.35

43-0.59
0.50
0.53
0.50
0.52
0.51
346.44
12.80
43.00
207.37
86.05
169.49
27.24
63.34
78.52
38.38
68.47
36.80
31.57
5.41
3.65
5.77
1,196.67

7.98
3.90
6.89
6.68
2,022.65
198.11
23.24
14.74
2,220.76
210

25
126
51
101
16
38
48
24
42
27
19









1,182
141


.58

.57
.05
.80
.87
.56
.50
.48
.55
.41
.24
.80









.19
.32


231

17
97
34
67
17
29
30
13
26
14
11









840
77


.06

.43
.80
.25
.62
.42
.54
.04
.83
.06
.43
.77




0.




.46
.69


0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.

927
936
947
957
962
970
977
981
988
994
000 12378-PeCDD
006
019
032
035
042











AN






855-1.145
0.
0.
0.
0.
1.
1.
1.
1.
000
930
957
995
000 13C12-PeCDD 123
006
019
025




IS3



/*no •Bol l .&•„•*•

8.35
65.54
210.58
32.20
33.99
10.21
103.82
64.46
13.22
24.63
28.79
1.41
577.23

37
112
18
18

57
35
'9
12
15



.68
.30
.41
.18

.53
.60
.70
.71
.98



27
98
13
15

46
28
5
11
12


0.

.86
.28
.79
.81

.29
.86
.90
.92
.81


958-1.051
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.

000
963
968
973
978
983
997 123478-HXCDF
000 123678-HxCDF
004
Oil
018 234678-HxCDF
021







AN
AN


AN


0.868-1.132
24.69
1,607.85
1,872.93
1,372.74
1,300.14

559
623
469
437

.51
.88
.24
.48

1,048
1,249
903
862

.34
.05
.50
.66
0.
0.
1.
1.
1.
000
997 13C12-HXCDF 478
000 13C12-HXCDF 678
018 13C12-HXCDF 234
042 13C12-HXCDF 789

SUR3
134
ALT2
ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:1710/21/97

-------
 Page No.
 10/21/97
Listing of U973260B.dbf
Hatched GC Peaks /  Ratio / Ret. Time
 Compound/
 M_2	  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
 384-386
                      4 Peaks
                                          6,153.66
HxCDD
390-392
K

X







390-392
13C12-HXCDD
402-404







402-404
HpCDF
408-410
MX


408-410
13C12-HpCDP
418-420



418-420

HpCDD
424-426




DC



DC
DC
DC
DC
DC
DC
DC


DC
DC


DC


DC


DC

DC
DC


DC

DC





DC
DC
DC
DC

NL



SN
SN
SN
SN
WH
WH
WH
3

NL
WL


SN


SN
4

NL

SN
SN
1

NL

SN

2



NL
SN
SN
WH

0:00
29:40
30:09
30:22
30:56
31:00
31:11
31:19
31:36
31:41
31:47
Peaks

0:00
29:45
30:55
30:59
31:11
31:18
31:29
31:36
Peaks

0:00
33:03
33:16
34:16
Peak

0:00
33:03
33:21
34:16
Peaks



0:00
33:18
33:54
34:08
1.
RO




RO
RO


RO
RO

1.

RO




RO
RO

0.


RO
RO

0.
RO

RO




0.
RO
RO
RO
RO
05-1.43
0.64
1.39
1.12
1.34
1.17
0.94
0.69
1.35
1.09
0.34
2.93

05-1.43
1.43
0.31
1.25
1.14
1.23
1.17
0.47
0.19

88-1.20
1.11
1.04
1.70
1.23

37-0.51
0.84
0.42
0.73
0.43



88-1.20
1.33
0.76
0.62
0.59
ax^u
4
20
45
28
10
8
2
14
3
1
1
94

8
1
1,398
1,597
11
2,707
24
15

.46
.51 11.94
.98 24.29
.27 16.20
.94
.96
.17
.71
.64
.84
.37
.76

.61
.39
.49 775.88
.71 852.68
.60
.98 1,461.46
.26 13.43
.75
0.

8.57
21.69
12.07








0.


622.61
745.03

1,246.52
28.51

952-1.015
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.

000
958
973
980
998 123478-HXCDD
001 123678-HxCDD
006
Oil 123789-HXCDO
020
023
026





AN
AN

AN




968-1.032
0.
0.
0.
1.
1.
1.
1.
1.
000
960
998 13C12-HXCDD 478
000 13C12-HXCDD 678
006
010 13C12-HXCDO 789
016
020


SOR4
IS5

RS2


5,728.44

5
16
8
6
16

9
1,226
18
1,053
2,280
HpCDi

3
13
8
1
.58
.84 8.59
.34
.81
.84

.88
.83 363.96
.53
.28 314.82
.11



.81
.61
.89
.79
0.

8.25



0.

862.87

738.46



0.




996-1.043
0.
1.
1.
1.

000
000 1234678-HpCDP
007
037 1234789-HpCDF


AN

AN

939-1.121
0.
1.
1.
1.



000
000 13C12-HpCDF 678
009
037 13C12-HpCDF 789




IS6

SUR5


977-1.005
0.
0.
1.
1.
000
982
000 1234678-HpCDD
007


AN

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:17 10/21/97

-------
 Page No.
 10/21/97
Listing of U973260B.dbf
Hatched GC Peaks  /  Ratio  / Ret. Time
 Compound/
 H_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Nam*..  ID..  Flags.
 424-426
                       0 Peaks
                                                0.00
 13C12-HpCDD                    0.88-1.20
 436-438         DC  NL   0:00 RO  1.30          9.85
                         33:54     0.96      1.763.70
                 DC  SN  34:24 RO  2.18          5.30
 436-438               1 Peak               1,763.70
                                  863.44
             0.971-1.029
                 0.000
         900.26  1.000 13C12-HpCDD 678  IS7
                 1.015
 OCDP
 442-444
 442-444

 OCDD
 458-460
 458-460

 13C12-OCDD
 470-472
 470-472

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC

DC
DC


DC

DC
DC


NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL

SN
SN
1

NL

WH
WH
1

0:00
33:34
36:07
37:14
37:17
37:27
37:32
37:38
37:51
37:54
38:49
39:17
39:40
39:49
39:55
Peaks

0:00
36:27
36:47
36:58
Peak

0:00
36:26
36:49
36:58
Peak
0

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO

0

RO
RO


0


RO
RO

.76-1.02
1
2
1
3
1
0
0
1
0
0
2
0
1
1
1

.01
.16
.09
.08
.55
.63
.72
.16
.15
.32
.96
.74
.01
.37
.89

.76-1.02
0
0
3
0

.97
.63
.39
.99

.76-1.02
0
0
1
0

.97
.84
.49
.43

                                      Above: HpCDD / Octa-CDD and CDF Follows
                                                8.20
                                                2.76
                                                6.58
                                                2.46
                                                2.14
                                                5.80
                                                8.96
                                                5.52
                                                2.14
                                                3.27
                                                1.68
                                               11.09
                                               16.74
                                                2.31
                                                2.46
                                                0.00
                                                6.02
                                               19.35
                                                0.83
                                                4.10
                                               19.35
                                                6.52
                                            3,686.48
                                               26.52
                                               18.56
                                            3,686.48
                                                    0.890-1.110
                                                       0.000
                                                       0.921
                                                         .991
                                                         .022
                                                         .023
                                                         .028
                                                         .030
                                                         .033
                                                         .039
                                                         .040
                                                         .065
                                                         .078
                                                         .089
                 0.
                 1.
                 1.
                 1.
                 1.
                 1.
                 1.
                 1.
                 1.
                 1.
                 1.
                 1.093
                 1.096
                                                    0.890-1.110
                                                       0.000
                                    9.11         14.50  1.000 OCDD            AN
                                                       1.010
                                                       1.015
                                                   0.995-1.005
                                                       0.000
                                1,678.82      2.007.66  1.000 13C12-OCDD      IS8
                                                       1.011
                                                       1.015
 Column Description	   "Why Code Description	  QC Log Desc.
 H_2   -Nominal Ion Mass(as)
 ..RT. -Retention Time (nm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
       HL-Below Retention Time Window
       MH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
  OGT
       18*00         19*00        20*00        21*00         22*00        23*00
Fil*:U973260 tl-1024 Aeqil7-OCT-1997 18*41*01 OC SI* Voltage SIB  705 Koit»i2622
305.8987 Fl2 BSUB(256,30,-3.0)  PKD(9,S,3,0.10\,10488.0,1.00\,F,T) ExptEPCUS2
TRIAKOLE LABS  T*XtlSO-K23-3  TLIt43432
ion

 so:
       18*00         19*00        20,00        21,00         22,00        23,00
Pil*>U973260 tl-1024 Acqt 17-OCT-1997 18,41,01  OC EJ+ Voltage SIR  70S Koie*:2616
315.9419 Fl2 BSVB(256,30,-3.0) PKD(9,S,3,0.10\f 10464.0,1. OO\,P,T)  ExptEPCUS2
TRIAKOLE LABS  TfxttSO-tS23-3  TLH43432
                                                       A1.07E7
 •liftU973260 tl-1024 Aoqi17-OCT-1997  18*41*01 OC EH- Voltage SIR 70S Noil*t3503
 03.9016 Pt2 BSOB(256,30,-3.0)  PKD(9,5,3,0.10*, 14012.0, 1. 00*,P,T) ExptEPCUS2
 •RXAKOLE LABS  TfJCt: SO-1123-3  TLIt43432
 LOOJf               A3.2.7*7
 80:

 eol

 401

 aol
                                                       A.1.31B7
                                           i.32^7-rff       -•*»•
                                           /^V/VAA     A
                                                                    A
                                                                                             .4.2E6

                                                                                             -3.4B6

                                                                                             .2.5E6

                                                                                             -1.7B6

                                                                                             .8.4X5
                                                                                        24*00
                                                                                               0. OBO
                                                                                                  Hoe
                                                                                        24*00
 80.

 60:

 40:

 20:

  0.
                                                                                              .0. OEO
                                                                                                  Time
                                                                                             ,2.0B6

                                                                                             -1.6E6

                                                                                             .1.2E6

                                                                                             .7.9E5

                                                                                             .4. OSS
       18*00         19*00        20*00         21*00         22,00        23*00
Fll»tV973260 tl-1024 Acqtl7-OCT-1997 18*41*01  OC El* Voltage SIR 70S Noie»i2268
317.9389 Pl2 BSVB(2S6,30,-3.0) PKD(9,5,3,0.10\,9072.0,1.00*,F,T) SxpiEPCffS2
TRIAKOLE LABS  TvetiSO-lO3-3  TLIt43432
IOCS

  eol

  eol

  40:

  20:
                                                                                        24*00
                                                                                              0.020
                                                                                                 Time
                                                                                             -2.7E6

                                                                                              -2.2E6

                                                                                              .1.6116

                                                                                              .i.ise

                                                                                              .5.4E5
       18*00         19,00        20,00         21,00        22,00
Fil»tU973260 tl-1024 Actjt 17-OCT-1997 18,41,01 OC EI+ Voltage SIR 70S
330.9792 Pt2 ExptEPCUS2
TRIAKOLE LABS  Text>SO-H23-3  TLXt43432
100*
                                                                          23*00
                                                                                        24*00
                                                                                               O.OFO
                                                                                                  Time
lf^*^w^^

23,53

       18,00         19,00        20*00        21*00         22*00
Fll»tU973260 tl-1024 Acy:17-OCT-1997 18*41*01 OC EI+ Voltage SIR 70S
375.8364 Ft2 Exp:EPCUS2
TRIANBLE LABS  Taxti3O-t!23-3  TLIt43432
                                                          21 f 45
                                 19155
                                                                           23*00
                                                                                        24«00
IOCS

 80:

 60.

 40:

 20:

  0.
                                                                                              _8.9S7

                                                                                              17.2B7

                                                                                              -.5.4E7

                                                                                              .3.6E7

                                                                                              .1.8E7

                                                                                              Lo. 050
                                                                                                  Tim*
                                                                                               4.8S4
     "47
        ISiOO
                     19*00
                                   20 »00
                                                21*00
                                                             22*00
                                                                           23*00
                                                                                               0.050

-------
Pll»iU973260 91-1024 Acqt 17-OCT-1997 18*41*01 OC EH- Voltag« SIR 70S Soi8»tl742
319.8965 Pt2 BSVB(256,30,-3.0) PXD(7, 5, 3,0.10*, 6968.0,1. 00*,P,t) ExpiEPCUS2
TRIAHQLB LABS TEPCUS2
TRIANGLE LABS T*XttSO-H23-3 TLI943432
ion
80:
60:
40.
20:
I
I A3.68S6
\ A
"T6 \ Al-?9B6
\ \ \ A1.02E6 A
\ / I A9.10S5 I \ UL-89B6 ». l\ A6.73ES
I V I V .A ./ IPV A /T VA Af-«- _ .
.7.025
.5.6ES
.4.2E5
.2.025
.1.425
0.020
	 20*00 	 21>0o' '22*00 	 23*00 ' ' 24*00 Mm*
Pllf>U973260 91-1024 Aeqil7-OCT-1997 10*41*01 OC EH- Voltagu SIR 70S Sol f»i 4140
331.9368 Fi2 B3VB(256,30,-3.0) PXD(7,5,3,0.10*,16560.0,1.00*,P,T) SxptEPCUS2
TRIANQLB LABS TmxttSO-H23-3 9LI943432
ion\
80:

60:
40.
20.

A1.77S7
n
ft
I \A1.13E7
A


/ V7 v
.3.6X6
.2.9E6

.2.2S6
'•.1.SE6
17.325
• 0. 020
'20*00' ' ' '21«00' ' ' ' '22*00 	 23*00 	 24*00' Tim*
Pil»tO973260 91-1024 Acqt 17-OCT-1997 10*41*01 OC 2J+ Voltagt SIR 70S Nolt»tl846
333.9338 Pt2 B3UB(256,30,-3.0) PXD(7,5,3,0.10X,73a4.0,1.00*,P,T) EXptSPCUS2
TRIANGLE LABS TvttiSO-H23-3 TUt 43432
ion
80:

60:
40:
20:
o:
A2.21S7
ft
IUl.<5B7
r A


/ U V
-4.6E6
'-.3.7S6

'-.2.8X6
'-.1.8X6
15.225
• o.oxo
'20*00 	 21*00 	 22*00' ' ' ' '23*00 	 24*00' «a»
P110IU973260 91-1024 Acqt 17 -OCT- 19 97 10*41*01 OC EH- Voltagt SIR 70S Noit»i2409
327.8847 Pi2 B3UB(256,30,-3.0) PXD(7,5,3,0.10*,9636.0,1.00*,P,T) ExptSPCUSS
TRIANQLB LABS T»xttSO-H23-3 VLI943432
100*

80.
60.
40:
20.
o:
A2.10B7




A4.12S6
/V I V
-4.4S6

.3.525
.2. 725
.1.025
.8.025
0.020
'20*00 ' 21*00 	 22*00 	 23*00 	 24*0o' Timt
Pll»t0973260 91-1024 Acqi 17-OCT-1997 10*41*01 OC XH- Voltag* SIR 70S
330.9792 Pt2 XxpiXPCU32
TRIAmtiX LABS T«tC»SO-J€23-3 TLI943432
100*
00:
60:
40:
20.
o.
^l^t^---^^^^




_7.«27
'
.6.1X7
.4.6X7
.3.027
.1.527
O.OXO
20*00 21*00 ^22»0o' ^ ' '23«00' ' ' " "" 24\00 Tiou

-------
Pll»tU9732SO tl-1024 Acqil7-OCT-1997 18(41,01 OC El* Voltage SIR 70S Woise*1843
339.8597 Pi2 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,7372.0,1.00*,P,T) Sxp:EPCUS2
TSIASOLE LABS TucttSO-M23-3 TLI043432
100*
ao:
60:
40:
20:
o:




A5.11E6
•JWA J\ A A "AT
.4.6E6
.3.6B6
.2.7B6
.1.8SS
.9. IBS
O.OBO
24*00 	 25*00 	 2«,00 	 27,00 ' '28,00 ' Time
Pll«tU973260 01-1024 Aaqil7-OCT-1997 18,41,01 OC SI* Voltaga SIS 70S Nois*i2130
341.8567 Pi2 BSV3(256,30,-3.0) PXO(7, 5,3,0. 10*,8520. 0,1. 00*,P,T) BxptBPCUSS
TRIANGLE LABS T»xti3O-M23-3 TLI043432
ion
80:
60:
40:
20:
o:
Al 33S7


A
/I A A « *A A2.08E6 A1.91E6
l\ J\l lA-jswA /AAA /v/v
-2.8B6
'•.2.2B6
.1.7B6
-1.1B6
.5.6B5
O.OBO
24*00 	 25*00 	 2*»00 	 27*00 ' ' 28*00 ' Tia»
Pll»iO973260 01-1024 Aaqt 17-OCT-1997 18,41*01 OC EI+ Voltage SIR 70S So±mm*1223
351.9000 Pt2 BSVB(256,30,-3.0) PSD(7f 5,3,0. 10*,4892. 0,1. 00*,P,T) BxptSPCUS2
TSIASOLE LABS T»xt t 3O-M23-3 TLI043432
100*
•
80:
60:
40:
20:

A2.QOE7
n A1.57B7
Jl
1


/I / V
_5.fiBff

.4.4E6
.3.3BS
-2.2S6
.1.1E6
'•O.OBO
24*00 	 25*00 	 26iOo' ' ' ' 27,00 ' ' 28,00 ' ' Time
FllutU973260 01-1024 Acqt 17-OCT-1997 18*41*01 OC BI+ Voltage SIR 70S Soln»t2113
353.8970 P*2 BSVB(256,30,-3.0) PSD(7,5,3,0.10Xr8452.0,1.00*,P,T) BxpiBPCVS2
TRIANGLE LABS TvtttSO-M23~3 TU043432
loot
so:
60:
40:
20-
a-
A1.3857
I "'f'*7
ft


/I ; V
-3.8B6
'-3.1B6
.2.3E6
.1.5E6
'•.7. TBS
O.OSO
24,00 25,00 26tOO 27,00 28,00 Tim»
PilftO973260 01-1024 Aaqtl7-OCf-1997 18,41,01 OC SI* Voltage 3IR 70S
330.9792 7(2 BxpiEPCUS2
TRIASQLB LABS T»XtiSO-H23-3 TLX043432
ion
80.
60.
40.
20.
0
~^^*»*l^fl^v*v^^^
~^^-VV^^~^^~-W*^AS^*>^*^^^^ ^VAV^AV'




C7.9B7
.6.3B7
-4.7B7
•-3.2B7
.1.6B7
'• o. oso
24*00 25*00 ' ' 26tOO 	 27,00 ' ' ' '28*00 ' ' Tlae
PllftU973260 01-1024 Aeyt 17-OCT-1S97 18,41,01 OC SI+ Voltage 3IR 70S
409.7974 Pt2 ExptEPCUS2
TRIANGLE LABS Tuxt I SO-H23-3 TLI043432
ion

80.
60.
40.
20.
0.
24*37 2tf,00 "
1 1 25*45 1 1 26t48 27il9 27t44
JT4.01 1 . I 25,35i «'« I , j, * 1 28,24
IH A".'2fi lul JU . «»^I LJUL , A. lA /W/LnH.*7M L ,1 1« 1 - i
"\v\jW VV*VvA"r y>"^ ^nVA/^NA-wflrv/v '^/' v>'''AJ1 Vv\p^\/\V/ \y/ " V ruiA/NV VJIVT*^''Vv UV^


5.824

'-.4.7E4
.3.524
.2.3E4
11.224
• o. oso
24,00 25,OO 29,00 27\00 ' ' ' 2e'tOo' ' ' ' rime

-------
F1101U97326O 91-1O24 Acqt 17-OCT-1997 10*4.1*01 QC SI* Voltage SIS 703 NolB*t2359
355.8546 ft 2 BSUB(256,30,-3.0) PXD(5,5,3,0.05*,9436.0,1.00*,?,T) ExpiEPCUS2
TRIABGLB LABS Text t SO-U23-3 TLIJ43432
10091

801

60.
401


20.
A2.11E6
A A1.26E6
/ I
A Al 02X6
A '

1 Ime ia~* \ A4.85E5
\ P'i8*5 I A A4.24ES
II 9 cc B I I i\ I A3 85E5 l\ f\ A3 . 72E5
.4.8ES

.3 . 8E5

.2.9ES
.1.9E5


.9.5E4
O.OSO
26tOO 	 37*00 ' ' ' 30*00 Tiaa
Plle>U973260 #1-1024 Acqtl7-OC7-1997 18t41t01 OC BZ+ Voltage SIR 703 Noia«il799
357.8516 Pi2 BSUB(256,30,-3.0) PKD(5,5,3.0.0S\,7196.0,1.00\,P,T) BxpiEPCUS2
TRIAKOLS LABS Text t SO-H23-3 TLIf 43432
10C»
801
60.

401
201
A3. 31X6
A
fl

1 A9.7BXS
\ A A6.76E5
\ A3. 50X5 l\ A
\ A / f3-*3*5 \ A3.00E5 A2.61E5
\ /\ A1.74X5 \ \ /N / \ .. /\A1.38X5 A A. A1.10BS
J \. JX_ JuvJ.^y W v_y \_> — rV^JTt^C /V.JV- . s^ ^
.5.7X5
.4.6X5
.3.4X5

.2.3X5

26tOO 	 37*00 ' 30*00 ' ' ' Mm*
PH0IU97326O §1-1024 Acqtl7-OCT-1997 10(41*01 OC Xlf Voltage SIR 70S Holm ft 2454
367.8949 Pi2 BSOB(256,30,-3.0) PXD(5,5,3,0.05*,9B16.0,1.00\,P,T) E*ptXPCVS2
TRIASOLS LABS Text t SO-M33-3 TLH43432
looa
00J
601
401
201
O
A1.18B7



L '
/ r^r
-3.8X6
.3.1X6
-2.3E6
'.1.5X6
.7.6X5
' O.OSO
26*00 27 tOO 30*00 Time
Fil»iO973260 §1-1024 Acq:17-OCT-1997 10*41*01 OC EH- Voltage SIR 703 Noise 1 1537
369.8919 P:2 BSUB(256,30,-3.0) PXD(S,S,3,0.05*,6148.0,1.00X,P,T) ExptEPCUSS
TRIASOLE LABS TfXt : SO-M23-3 TLH43432
IOCS
801
60.
401
20.

0
A8.40X6
i


I
/ U7.77S5
/ vy\
-2.6X6
.2.1E6
.1.6X6
.1.0X6
.5.2X5

0. OSO
26\00 	 37*00 	 30*00 ' ' ' Tlttf
PllmiU973260 §1-1024 Acqtl7-OCT-1997 10*41*01 OC XI-f Voltage SIR 70S
330.9792 Vi2 KxptZPCUSS
TRIANOU LABS Text 1 3O-M23-3 TLI§43432
ion
80.
60.
40.
20.
0.
35*57 26*45 37*41
V^X-vvrvs^^ -Vv^N^v^^— ^^V-^AA/^^^^^^^^^




r7.9X7
.6.3X7
.4.7X7
.3.2X7
'.1.6X7
O.OSO
26tOO 37*00 30*00 Time

-------
P±letU973260 #1-403 Aaqtl7-OCT-1997 10(41(01 SC EH- Voltage SIR 70S Soiao:230B
373.8208 Pi3 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,9232.0,1.00*,P,T) Exp:BPCUS2
TRIANGLE LABS Text:SO-M23-3 TLH43432
100*
sol
so:
40:
20.
A1.12E6
|
J
A3. 7755^ A5.7555
AjL. /ill „,„,
j vy v~/v_/v^-^ . / \f v-«t. .rv_r*v_ . - - - —, 	 -
.3.755
.3.055
.2.255
.1.555
.7.454
O.OEO
25(00 30(00 ' 31(00 32(00 Tim*
PlletU973260 91-403 Acqtl7-OCT-1997 18 : 41 1 01 OC EH- Voltage SIR 70S Noiee:2506
375.8178 P*3 BSUB(2S6,30f-3.0) PXD(7,5.3.0.10\,10024.0,1.00*,P.T) BxptEPCUS2
TRIANGLE LABS TexttSO-M23-3 TLH43432
10«
00J
sol
40:
20:
A5.0355
|

J I A4.63E5
A2.79BS: A
A ] A1.5055 A A 3gss
J \ 1 \ -v A /I I*?'90B4 A1.28B5
f \J V_X>_y \^ 	 ^ -/ \JV^— -S~*L- _A-Vn - --ntft j, ,-.-, 	 	 _ -
.3.155
.2.555
.1.555
.1.355
_ff.354
O.OBO
29 tOO • • • • 30l0o ' ' 31(00 32(00 Time
PiletU973260 §1-403 Acqt 17 -OCT- 1997 10(41(01 OC EH- Voltage SIR 70S Noiaet4114
383.8639 Pt3 BSUB(256,30,-3.0) PXD(7,5,3,0.10X.16456.0,1.00*,P,T) Exp:EPCUS2
TRIANGLE LABS TextiSO-M23-3 TLIf 43432
lOOJj
00:
so:
40:
20:

AS.24S6
\ 1 A4.69S6 A4.37S6
fl A

U \
y Y v y v / v
-2.2E6
li.ass
-.1.3E6
L0.555
14.555

25(00 	 30(00 	 31(00 	 32(00 Time
Pile:U973260 #1-403 Acqt 17 -OCT- 1997 18(41(01 OC SH- Voltage SIR 70S SoiaetB232
385.8610 Pt3 BSUB(256,30,-3.0) PXD<7,5,3,0.10*,32928.0, 1.00*,P,T) Exp:BPCUS2
TRIANGLE LABS T»XttSO-M23-3 TLH43432
100*
80:
sol
40:
201

A1.2557
fl 11 A5.035ff A0.«Sff
A A

y
/ V V y V / v
..4.3E6
.3.455
.2.655
.1.75*
.8.SBS

25(00 	 30(00 	 31(00 	 32(00 Time
Pile:U973260 tl-403 Acq: 17 -OCT- 19 97 10(41(01 OC EH- Voltage SIR 70S
392.9760 Pt3 BxptBPCUS2
TRIANGLE LABS TextiSO-M23-3 TLH43432
IOOS
aoj
sol
401
201
01
31j04 ,, nf 31 1 SO


-

3.657
12.557
12.257
.1.457
.7.255
0.050
25(00 30(00 ' ' ' 31(00 ' 32(00 Time
PlletU973260 §1-403 Acqt 17 -OCT- 1997 10(41(01 OC 5X+ Voltage SIR 70S
445.7555 Pt3 ExptEPCU32
TRIANGLE LABS Text i SO-H23-3 TLIf 43432
ion
80.
SO.
40.
20.
0.
^ArMAAA^AAM^A^^



_4.354
E.3.554
.2.654
.1.754
.0.753
O.OSO
25(00 30(00 31(00 ' ' 32(00 Time

-------
 '110IU973260 fl-403 Aoqs 17-OCT-1997 18:41:01 OC SI* voltage SIR 70S Noise:1235
389.8156 Pt3 BSUB(256,30, -3.0) PKD(7,5,3, 0.10\,4940.0,1.00*.P,T) Exp:EPOJS2
TRIANGLE LABS  TexttSO-M23-3  TUf43432
1009
     25(39    25(48   30(00   30:12    30(24   30(39   30(48    31(00   31(12
PilmiU973260 91-403 Acqt 17-OCT-1997 18(41(01 OC ST+ Voltage SIR 703 Noiae:1923
391.8127 Pi3 BSOB(256,30,-3.0) PXD(7,5,3,0.1OX,7692.0,1.00*,P,T) ExpiEPCUS2
TRIANGLE LABS  T*Xt:SO-M23-3  TLI943432
100H                       A2.J.7B5
                                                                                 31:24    31(39
     25(39    25(48   30(00    30(12    30(24   30(39   30(48    31(00   31(12"   31(24
Pile:U973260 91-403 Acqil7-OCT-1997 18(41(01 OC 5J+ Voltage SIR 70S Boise: 2537
401.8558 Pi3 BSOB(2S6,30,-3.0) PXD(7,S, 3, 0.10\f 10148.0,1.00\tP,T) S*piEPCU32
TRIANOLB LABS  Text:SO-U23-3   TLX943432
IOC*                                                                       A1.46B7


  80.

  60.

  40.

  20.
                                                                                         31(3tf
     25(39   25(48   30(00   30(12    30(24    30(39   30:48    31:00   31(12    31:24
Pil»tV973260 91-403 Aeqt 17-OCT-1997 18(41(01 OC EH- Voltage SIR 70S Noioetl769
403.8529 Pi3 BSUB(2S6,30,-3.0) PXD(7.5,3,0.10*,7076.0,1.00*,P,T) Exp:EPCUS2
TRIAmLS LABS  Text:SO-M23-3  TLH43432
100H                                                                       A1.2SB7
                                                                                         31(39
 80.

 60.

 40.

 20.
                                                               A7.45E6
     25(39   25(48   30(00    30(12   30(24   30(39    30(48   31(00
File:0973260  91-403 Aaqi 17-OCT-1997 18(41(01 OC KT* Voltage  SIR 703
392.9760 Pt3  Bxp:SPCUS2
TRIANGLE LABS  Text:SO-M23-3  TU943432
100H                                                               31:04
  80.

  60.

  40.

  20.

   0.
                                                                        31(f12  '  31(24   31(39
      25(39 '  '25(48'  ' '30(do' ' '30(12' '  '30(24' '  '30(39  ' '30\48 '  's'l'tOO  ' '31(12' '  '31(24'
                                                                                         31(39
                                                                                                     .050
                                                                                                       time
                                                                                                   .4.559

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-------
 •Ila*a973260 #1-596 Acq: 17-OCT-1997 18:41:01 QC Bit Voltago SIR 70S NolBf*1463
 107.7818 P*4 BSUB(256,30,-3.0) PKD(7,S,3,0.10*,5852.0,1.00*,P,T) Exp*EPCUS2
TRIANGLE LABS  T«XtiSO-M23-3  TLI#43432
100H    A1.43S5
      33*00     33i13     33*24    33:36     33,48     34*00     34tl2     34t24
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409.7789 Ft4 BSUB(256,30,-3.0) PXD(7, 5,3,0.10*, 5308.0,1.00X,P,T) ExptEPCUSS
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lOOtl   A1.01ES
       33'tOO    33*12     33*24     33i36    33/48     34tOO    34tl2     34t24
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417.8253 P:4 BSOB(2S6,30f-3.0) PXD(7,S,3,0.10*,11472.0,1.00*,P,T) Exp:BPCUS2
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430.9729 Pt4 Exp:EPCUS2
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                                                            SIR 70S
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-------
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-------
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-------
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-------
                  Peak Locate Examination:17-OCT-1997:18:40 File:U973260
                        Experiment:EPCUS2 Function:2 Reference:PFK

-------
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319.8965 F:2 Exp:EPCUS2
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-------
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-------
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage  SIR 70S
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-------
File;U973260 #1-1024 Acq;17-OCT-1997
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File
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18:41:01 GC EI+ Voltage SIR 703
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Sample Text:SO-M23-3  TLI#43432 File
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Text:TRIANGLE LABORATORIES, INC.
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File:U973260 #1-1024 Acq:17-OCT-1997
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File
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-------
File:U973260 #1-1024 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES,
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        25:48  26:00   26:12  26:24   26:36   26:48  27:00   27:12
File:U973260 #1-1024 Acq:17-OCT-1997  18:41:01 GC EI+ Voltage SIR
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File  Text:TRIANGLE LABORATORIES,
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File:U973260 #1-1024 Acq:17-OCT-1997  18:41:01 GC EI+ Voltage SIR 70S
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Sample Text:SO-M23-3  TLI#43432 File  Text:TRIANGLE LABORATORIES, INC.
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-------
File:U973260 #1-403 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
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Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%    29:07
     29100                    30100                   31:00
File:U973260 #1-403 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%    29;07
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     29:00                   30:00                   31:00
File:U973260 #1-403 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
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-------
                                                                                                      GO
                                          :01 GC fil+ Voltage  SIR  70S
                                          :TRIANGLE LABORATORIES,  INC,
File:U973260 #1-596 Acq:17-OCT-1997 18:41
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text
100%               A8.59E4
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                   33:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text
100%.               A8.25E4
 80J
 60 J
 40J
 20J
                                                 34:00
                                          :01 GC  EI+ Voltage  SIR 70S
                                          ;TRIANGLE LABORATORIES,  INC,
  OJ
                   33:00
File:U973260 #1-596 Acq:17-OCT-1997  18:41;
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:
100%                33j03
                                                 34:00
                                           01 GC  EI+ Voltage  SIR 70S
                                           TRIANGLE LABORATORIES,  INC,
                                                        34:16
35:00
35:00
4.9E4
.3.9E4
.2.9E4
.2. OE4
.9.8E3
O.OEO
   Time
5.2E4
4.1E4
3 . 1E4
.2. 1E4
.1.0E4
.O.OEO
   Time
                   33:00
                                                 34:00
35:00
.1.2E6
.9.4E5
.7.0E5
.4.7E5
.2.3E5
.O.OEO

-------
File;U973260 #1-596 Acq;17-OCT-1997 18;Alt01 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text;TRIANGLE LABORATORIES, INC.
100&                     33:1833:
     32:33       _„     i   |y,               1        34:16
                                               34:08 A       34;37     34:59
8CL
  OJ
                 33:00	34100                      35:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100*                     ,,..,0           33:54
                 33:00                      34:00
File:U973260 #1-596 Acq:17-OCT-1997  18:41:01 GC EI+ Voltage  SIR  70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
lOOi                                     33;54

 80 j

 60J

 40J

 20J

  OJ
                                                                     35:00
                                                                                         O.OEO
                                                                                           Time
                 33:00
                                          34:00
35:00
                   .O.OEO
                      Time
3.1E6

2.4E6

1.8E6

.1.2E6

.6.1E5

.O.OEO
   Time
                                                                                                    CD

-------
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
457.7377 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES,
100%                               A9.11E4
 80 J
 60J
 40 j
 20J
        35:00                36:00               37:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
459.7348 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES,
                                    70S
                                     INC.
                                       38:00
                                    70S
                                      INC.
100%,
 80J
 60 J
 40J
 20J
        A1.45E5
        35:00               36:00               37:00
File:U973260 #1-596 Acq:17-OCT-1997 18:41:01 GC EI+ Voltage SIR
469.7779 F:4 Exp:EPCUS2
Sample Text:SO-M23-3  TLI#43432 File Text:TRIANGLE LABORATORIES,
100%                                36:26
 80J
 60 J
 40 j
 20J
                                        38:00
                                     70S
                                      INC.
                                          5.4E4
                                          4.3E4
                                          3.2E4
                                          2.2E4
                                          1.1E4
                                          O.OEO
                                             Time
                                          6.8E4
                                          .5.5E4
                                          .4.1E4
                                          .2.7E4
                                          1.4E4
                                          .O.OEO
                                             Time
        35:00
36:00
37:00
38:00
5.4E6
4.3E6
3.3E6
2.2E6
1.1E6
O.OEO
   Time

-------
TLI Project:      43432
Client Sample:   SO-23-3
Method 23 TCDD/TCDF Analysis (DB-225)
                     Analysis File:   X973638
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:

&**I**\C^
Saginaw, MI
M23TRAIN
185-6-3A-C
1.000
n/a
DB-225

Xv$* ^j^$|i
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:

IJSi^^fl^r
09/29/97
10/09/97
10/18/97
n/a
U973257
WK

> ^mto*Str;}
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:

if*fi*fe^V$
SPC2NF04
XF24087
X973633
n/a
n/a
n/a

fe ^*&*& '
2,3,7,8-TCDF
                               1.8
                         0.79     24:34     _
 Internal Standard; ^ -
l3C12-2,3,7,8-TCDF
                              2.4
   58.9      40%-130%
                                                                   0.83     24:32
13C12-1,2,3,4-TCDD
                         0.81     23:19     	
                      Data Reviewer
                     10/23/97
                                         Page 1 of 1
                                  C2NF.PSR vlOa LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                               Printed: 23:35 10/23/97

-------
                        Initial
                                  	Date...
 Data Review By:
                                             Calculated Noise Area: n/a
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
Listing of X973638B.dbf
Hatched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z	QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID., nags.
TCDF
304-306 DC NL 0:00
19:46
20:04
20:47
20:56
21:03
21:14
21:31
21:40
21:49
21:59
22:06
22:31
22:36
22:43
23:00
23:06
23:16
23:32
23:45
23:57
24:25
24:34
24:49
25:09
25:18
26:14
26:41
26:45
26:50
27:07
304-306 30 Peaks
13C12-TCDP
316-318 DC NL 0:00
DC WL 19:39
DC WL 21:09
DC WL 23:16
DC WL 23:21
24:32
24:45
DC WH 26:57
316-318 2 Peaks
0.65-0.89
RO 0.57
0.77
RO 1.42
0.78
0.77
0.81
0.88
0.78
0.76
0.69
0.79
0.79
0.83
0.70
RO 1.39
0.77
0.67
0.79
0.75
0.86
0.79
0.86
0.79
0.83
0.75
0.79
0.83
0.82
RO 1.99
0.66
RO 3.76

0.65-0.89
RO 0 . 60
RO 0.32
RO 2.00
RO 0.96
RO 0.97
0.83
RO 0.33
RO 1.91

0.798-1.112
14.27
1,661.40
9.10
2.612.58
1.488.78
1.672.95
1.355.79
833.10
1.173.28
402.29
2.854.09
680.65
1.485.58
915.03
7.29
1.214.31
200.26
821.83
1,049.31
126.58
549.02
538.17
718.21
442.56
379.69
994.30
415.57
7.79
2.89
5.76
11.81
24.630.02

723.10
7.29
1.145.05
649.22
750.51
636.30
366.13
504.75
164.27
1,256.38
300.19
675 . 67
375.48
5.71
526.40
80.14
361.63
448.33
58.66
242 . 40
249.06
316.28
200.83
162.93
438.01
188.51
3.50
3.25
2.28
25.06


938.30
5.14
1,467.53
839.56
922.44
719.49
466.97
668.53
238.02
1,597.71
380.46
809.91
539.60
4.12
687.91
120.12
460.20
600.98
67.92
306.62
289.11
401.93
241.73
216.76
556.29
227.06
4.29
1.63
3.48
6.67

0.000
0.806
0.818
0.847
0.853
0.858
0.865
0.877
0.883
0.889
0.896
0.901
0.918
0.921
0.926
0.938
0.942
0.948
0.959
0.968
0.976
0.995
1.001 2378-TCDP AN
1.012
1.025
1.031
1.069
1.088
1.090
1.094
1.105

0.959-1.041
12.67
3.93
7.65
5.86
3.96
1,648.32
4.30
15.03
1,652.62





746.51
1.87







901.81
5.68


0.000
0.801
0.862
0.948
0.952
1.000 13C12-2378-TCDP ISO
1.009
1.099

Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 20:54 10/21/97

-------
 Page No.
 10/21/97
Listing of X973638B.
-------
Fil»tX97363B #1-903 icqtlB-OCr-1997 16*30*40 X S* Voltaga
303.9016 BSUB(2S6,30,-3.0) PKD(S,3,1.0.10\.12423.0,0.00*,P,F)
Sajnplo ToxtiSO-M23-3   TLI*43432 Pilt Tsortr TRZWH3LB L3UB3
100*          A1.J.5E7
                                                                Auto^pae Soisa*3107
      30'tOO      21*00       2atOO      23tOO      24100      25 tOO       26tOO
P11»*Z973638 #1-803 Acg(10-OCT-1957 lf(30(48 OC SI* Voltag* SIR AutoSpao
305.8987 B3UB(256,30,-3.0) PKD{5,3,l,0.10*,21688.0,0.00*rP,F) SxptXCONP_TT
Sanpl* ToxttSO-K23-3   TLIX43432 gilt Ttocti TXUUmS LABS
1009C          A.1.47E7
                 aitoo      22*00      23*00      24*00      25*00       26*00
Pil»*Z973638 tl-803 JLcqt 18-OCT-1997 1ft 30*40 OC JET* Volt ay • SIR JiutoSpoc Soim»*2757
315.9419 BSOB(2S6.30,-3.0) fXD(S,3,l,0.10*.11028.0.O.OO*,P.P) BxptZCONP_TV
Sonplf raxtiSO-M23-3   TLH43432 Pll» Tuctl THIAHOLB UBS
                                                                                     27<00
                                                                                     27JOO
Pil»tI97363B 91-803 Acq*18-OCT-1997 16*30*48 OC SZ+ Voltag* SIR AutoSJ)»c Kblm»*4626
317.9389 BSUB(256,30,-3.0) PKD(S,3,1,0.10^,18504.0,0.00\,P,P) SxpiKONP_TT
Saopl* T»XttSO-H23-3   TLIV43432 Film TfXtt TRIABOUB
Fil»tX973€38 91-803 Acqt 18-OCT-1997 16*30*48 OC SX+ Voltage SIR JLutoSpmo
375.8364 SxptKONP_TT
Saaplf Tmxti30-H23-3    TLH43432 Pil» ttott* BUIBOU IABS
IOC*
                                                                                               .O.OSO
                                                                                                   Time
                                                                                               10.050
                                                                                                   rlao
009
00J
60.
40.
20.

A7.47S6



11
20»00 21>00 22(00 23iOO 24tOO 25*00 26*00 27*00
.1.8S6
.1.4S6
.1.1S6
.7. OSS
.3.525
Tim*
oca
ao.
60.
40.
20.

JL9.02S6



11
20<00 21 It 00 22(00 22(00 24*00 25(00 26tOO 27(00
.2.0S6
.1.6S6
.1.2S6
.7. 8SS
.3.9S5
Tim*
      20*00
                  21*00
                             22(00
                                        23(00
                                                   24(00
                                                               25(00
                                                                          2«(00
                                                                                     27(00

-------
 'ii»tX97363B wi-aoa Acq:iu-ocT-i997 16:30:48 ac EI+ voltage SIR Autospec noisa:i7Oi
319.89SS BSUB(256,30,-3.0) PXD(5,3,1,0.10*,6804.0,0.00*,P,P) ExpiXCOKP__TT
Saapla TaxtlSO-M23-3   TLI043432 Pila TfXtt TRIMBLE LASS
icon
          21tOO          22100          23tOO          24:00          25:00
Flit 1X973638 #1-003 AcqtlB-OCT-1997 16i30t48 OC XX+ Voltag* SIR JLutoSpoc So±s»:1813
321.8936 BSOB(256,30.-3.0) PXD(5.3,1,0.10*,7252.0,0.00*,P,P) Xxp:XCOSP_TT
Saoplm r«xt*5O-JC23-3   TLIf43432 Pll» ItorCs TRUOOLB LABS
100K
 80.
                                                                                      26100
           21tOO          22s00          23tOO          24tOO          25tOO
Silm*X973638 #1-003 t.cqtia-OCT-1997 16t30t48 OC JET* VolCagr* SIX AutoSpmc Soim»t4903
327.8847 BSUB(256,30,-3.0) PKD(5,3,1, 0.10*, 19612.0,0.00*,P,f) ixp»ZCC»P_rT
       T«Zt
-------
Pile:X973638 #1-003 Acys 18-OCT-1997 16,30,48 OC EH- Voltage SIR AutoSpec
303.9016 ExpiXCONP TV
Sample TexttSO-M23-3 TLI#43432 Pile Text, TRIANOLB LABS
iota
so:
60:

40:
20:
20(47
1 ^l59
1 i | M(M
I II H I ft Jl i 23>°°

II III II 1 A A ll l\ l\ fl* A 24(34 "A18
20(00 21(00 22(00 23(00 24(00 25(00
Pil»iI97363B #1-003 Acgd0-OCT-1557 16,30,48 OC EH- Voltage SIR AutoSpec
315.5415 BxptKONPjrT
Sample Text,SO-M23-3 TLI*43432 Pile Text, TRIASOLS LABS
ion
00:
50:
4flJ
20:

24<32




. . J V .
20(00 21(00 22(00 23(00 24,00 25(00
Pile ,197363 8 #1-003 Ac
-------
Peak Locate Examination:18-OCT-1997:16:30 File:X973638

-------
                                jt?.5..4.'..?.....*&*.	"Sac1-!.... ?*&^..^ v --^
TLI Project:       43432
Client Sample:   SO-23-4
                                                       Method 23 PCDD/PCDF Analysis (a)
                                                                     Analysis File:   U973261
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-4A-C
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
JfoaJ^V^^'T!*'*"
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6.7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
$ ,
0.12
0.10
EMPC
0.03
0.04
EMPC
0.08
Pg^^ei%'^^ ; J^ft*^
0.74
1.49
0.02
1.26
1.22
0.03
0.80
*" "• ""• ^ ft**E*':'£ *•*
^ •. -rl t"^ s s s
22:30
27:31

31:00
31:18

36:27
^ ^%V:





	
B_
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
                                  4.1
                                  0.61
                                  0.52
                                  0^6
                                  0.11
                                  0.06
                                 ND
                                  0.07
                                 ND
                                 ND
              0.01

              0.02
              0.01
                               0.74
                               1.46
                               1.50
                               1.22
                               1.19
                               1.27

                               1.05
21:38
26:19
27:07
30:09
30:16
30:47

33:03
 totals  :
                   % .-.V.
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD

Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
 4.6
 1.3
 0.41
 0.03

43.0
11.3
 1.2
 0.07
13
 9
 5
 1

15
14
10
 1
                                                          2.1
                                                          0.43
                                                          0.05
                                                         11.3
                                              Page 1 of 2
                                                                                     X237.PSR V2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                Printed: 23:14 10/23/97

-------
,; ;' ,;V ? ^^F^e-^S^^^i^, , ; x;;V£ ;£ ,^/f
TLI Project:
Client Sample:
Internal Standards, ,
13C,2-2,3,7,8-TCDF
13Cr.-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-1,2,3,4,6,7,8-HPCDF
13Cr- 1,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD

37Cl4-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
l3C,2-l,2,3,4,7,8-HxCI>D
13Cl2-l,2,3,4,7,8,9-HpCDF
Ait0rnat9 Standards p
	 > 	 1 	 .-!(, 	
13C,2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards ,
13C,2-1,2,3.4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
43432
SO-23-4
Amfc {ngj \,
2.8
3.3
3.8
4.4
3.4
3.5
2.6
3.4
7.6
fyp&"A>-; Affli Cl^v"
3.6
3.8
4.0
4.1
4.2
y^^^AnirCii^
3.0
3.3
-.^ •• \ •••.•.•. •• s*
< * XXrt-f ss ^ •. ^A--^.\-.O -.5 '*.-.




Method 23

;^ %^/ \% Recowwy A- &C Limits-
69.7
83.5
96.0
110
85.6
87.7
65.1
84.5
95.2
0^^
91.1
95.4
99.0
101
105
ttif&RscoS
75.3
82.5
^£%?*%*


4Q%-130%
4Q%-13Q%
4Q%-130%
4Q%-130%
40%-130%
4Q%-130%
25%-l3Q%
25%-l3Q%
25%-l3Q%
»^||f^tt»tlfe
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
i^tc^^iife:
40%-130%
40%-130%
f^|CC ,^^-


PCDD/PCDF Analysis (a)
Analysis
v .Ratio,
0.75
0.79
1.49
1.45
0.51
1.22
0.42
1.03
0.85
\Y^&*teFr-

1.55
0.51
1.19
0.42
5?rBa8oC^
0.52
0.51
?>t:RattoV'
0.78
1.20
File:
-- irr
21:35
22:30
26:18
27:30
30:15
31:00
33:02
33:54
36:26
A81^
22:32
27:06
30:09
30:54
34:15
; ^-X^fTf^
31:31
30:47
'* \(BT 5
22:16
31:18
U973261
„- o Flags

	




	

—
;>,fW»^




—
^fla^

—
rf;^» "


                         Data Reviewer.
                                                 Page 2 of2
10/23/97
                X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 23:14 10/23/97

-------
                        Initial
                                  	Date...
 Data Review By:
                                              Calculated Noise Area:   4.66
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
Listing  of U973261B.db£
Matched  GC Peaks / Ratio /  Ret. Time
 Compound/
 H_Z.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name..  ID.. Flags.
TCDF
304-306







M







304-306
13C12-TCDF
316-318





316-318

TCDD
320-322




M








DC NL 0:00
17:43
18:15
18:31
18:57
19:18
19:51
20:14
20:39
21:04
21:22
21:38
22:10
22:26
22:42
23:43
15 Peaks

DC NL 0:00
DC WL 18:50
DC WL 18:57
21:35
22:08
DC WH 22:50
2 Peaks


DC NL 0:00
19:13
19:42
20:07
21:02
21:24
21:52
22:17
22:24
22:30
22:43
22:56
23:13
0.65-0.89
RO 1.53
0.73
0.72
0.68
0.74
0.74
0.76
0.75
0.70
0.73
0.74
0.74
0.78
0.78
0.72
0.73

0.65-0.89
RO 1 . 42
RO 3 . 49
RO 1.95
0.75
RO 0.43
RO 0.45

.__ _____ AHr
0.65-0.89
RO 1.00
0.75
0.79
0.73
0.73
0.75
0.79
0.81
0.66
0.74
0.75
0.78
0.81

9.04
4,217.43
1,838.77
982.99
10,891.24
6,806.53
5,162.02
4,093.17
4,560.00
2,215.57
1,738.07
4,754.83
1,752.93
1,116.57
187.32
97.84
50,415.28

7.12
3.58
5.56
4,350.31
29.70
22.14
4,380.01
wa • TVTO7 /
7VW ! l>\rVr /
6.46
1,430.78
781.91
307.44
1,033.81
517.00
274.43
336.15
505.18
155.26
107.31
181.17
66.26


1,785.67
772.23
397.93
4,617.98
2,891.33
2,224.15
1,748.84
1,880.00
934.04
739.48
2,023.95
766.91
491.02
78.21
41.23





1,867.59
12.92





612.34
345.72
129.51
436.04
221 . 00
121 . 05
150.93
200.74
66.13
46.04
79.46
29.72
0.

2,431.76
1,066.54
585.06
6,273.26
3,915.20
2,937.87
2,344.33
2,680.00
1,281.53
998.59
2,730.88
986.02
625.55
109.11
56.61

0.



2,482.72
30.27



0.

818.44
436.19
177.93
597.77
296.00
153.38
185.22
304.44
89.13
61.27
101.71
36.54
813-1.106
0.000
0.821
0.846
0.858
0.878
0.894
0.920
0.937
0.957
0.976
0.990
1.002 2378-TCDF AN
1.027
1.039
1.052
1.099

954-1.046
0.000
0.873
0.878
1.000 13C12-2378-TCDF ISO
1.025
1.058


848-1.061
0.000
0.854
0.876
0.894
0.935
0.951
0.972
0.990
0.996
1.000 2378-TCDD AN
1.010
1.019
1.032
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 20:41 10/21/97

-------
  Page No.
  10/21/97
Listing of O973261B.dbf
Matched GC Peaks / Ratio / Ret.  Time
 Compound/
 M_2	 QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1..  Area.Peak.2..  Rel.RT Conpound.Name..  ID.. Flags.
  320-322

  37C1-TCDD
  328
 328

 13C12-TCDD
 332-334
 332-334
 PeCDF
 340-342

DC


DC
DC
DC
DC
DC

DC
DC
DC
DC
DC
DC

DC
DC
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC




DC
DC
DC


DC

DC

WH
13

ML
ML
WL
WL
WL

SN
SN
SN
SN
SN
SN

SN
SN
SN

SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
3

KL




SN
SN
SN
4

NL

SN
23:44
23:54
Peaks

0:00
19:11
19:20
19:36
19:44
20:46
20:59
21:08
21:34
21:46
21:50
22:02
22:32
22:45
22:47
22:50
23:02
23:13
23:22
23:27
23:35
23:42
23:45
23:48
23:53
24:02
24:13
24:18
Peaks

0:00
22:16
22:30
22:55
23:13
23:16
23:42
24:00
Peaks

0:00
24:01
24:18
0.84 42.27 19.28
RO 0.40 4.18
5,738.97

5.42
10.98
3.13
20.57
18.75
411.21 411.21
11.46
2.23
8.59
2.42
6.12
1.84
3,570.97 3,570.97
3.94
4.54
4.44
89.32 89.32
5.43
11.78
8.65
6.49
9.81
1.50
4.35
6.83
2.81
5.58
3.64
4,071.50
0.65-0.89
RO 2.73 4.87
0.78 4,488.34 1,970.01
0.79 4,154.02 1,838.72
0.69 89.02 36.37
0.70 36.43 14.96
RO 1.92 17.68
RO 1.22 15.33
RO 4.96 5.89
8,767.81
1.32-1.78
RO 1.00 6.15
1.51 2,163.54 1,302.44
RO 1.05 16.37
22.99 1.055
1.062

0.911-1.089
0.000
0.853
0.859
0.871
0.877
0.923
0.933
0.939
0.959
0.967
0.970
0.979
1.001 37C1-TCDD SDR
1.011
1.013
1.015
1.024
1.032
1.039
1.042
1.048
1.053
1.056
1.058
1.061
1.068
1.076
1 . 080

0.911-1.089
0.000
2,518.33 0.990 13C12-1234-TCDD RSI
2,315.30 1.000 13C12-2378-TCDD IS1
52.65 1.019
21.47 1.032
1.034
1.053
1.067

0.906-1.077
0.000
861.10 0.913
0.924
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:41 10/21/97

-------
 Page No.
 10/21/97
Listing  of U973261B.dbf
Matched  GC Peaks /  Ratio
                       / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak.1..  Area.Peak.2.. Rel.RT Conpound.Name.. ID.. Flags.


A
M








340-342
13C12-PeCDF
352-354










352-354
PeCDD
356-358













DC SN 24:24
DC SN 24:34
24:47
DC SN 24:54
25:10
25:20
25:32
25:42
25:59
26:12
26:19
26:30
26:38
DC SN 26:54
27:07
27:17
27:36
28:10
DC WH 28:21
15 Peaks

DC NL 0:00
25:19
DC SN 25:54
26:18
DC SN 26:28
26:38
27:06
DC SN 27:20
DC SN 27:26
DC SN 27:31
DC SN 28:06
4 Peaks

DC NL 0:00
25:29
26:02
26:18
26:28
26:40
26:51
26:58
27:10
27:19
27:31
27:40
DC SN 27:50
28:02
RO
RO





RO



RO
RO

1.
RO
RO
RO

RO
RO



RO
RO

1.

RO







RO


RO
RO
1
5
1
3
1
1
1
1
1
1
1
1
1
0
1
1
1
1
1

.66
.34
.58
.25
.50 1
.49 4
.59 1
.56
.47 1
.50
.46
.54
.60
.52
.50
.46
.61
.29
.17
14
28.37
4.46
58.76
9.00
,093.16
,822.60
,107.39
536.44
,342.12
330.00
803.00
625.42
733.24
12.83
695.59
530.94
88.45
62.12
13.05
,992.77
35.
655.
2,888.
679.
326.
798.
198.
476.
379.
451.

417.
314.
54.
37.


98
13
73
96
58
24
00
00
66
36

56
85
55
76


22
438
1,933
427
209
543
132
327
245
281

278
216
33
29


32-1.78
0
0
0
1
4
1
1
1
1
0
1

.85
.96
.95
.49 4
.13
.06
.55 4
.41
.72
.90
.07
9
ftU.»M. '
3.22
46.85
20.55
,711.36
12.75
37.49
,361.63
28.51
18.25
18.46
15.30
,157.33
n«/>«nn /
32-1.78
1
1
1
1
1
1
1
1
1
1
1
1
2
1
.36
.26
.58
.49
.65
.54
.74
.43
.48
.10
.49
.36
.85
.83
7.16
662.61
75.49
411.65
129.07
287.74
57.67
104.00
129.67
52.89
106.91
61.62
5.89
41.11

28.

2,818.

22.
2,653.





48

45

79
12





29

1,892

21
1,708




.78
.03
.87
.43
.86
.88
.00
.00
.76
.88

.03
.09
.90
.28


0.

.59

.91

.53
.51




0.928
0.934
0.942
0.947
0.957
0.963
0.971
0.977
0.988
0.996
1.001 12378-PeCDF
1.008
1.013
1.023
1.031 23478-PeCDF
1.037
1.049
1.071
1.078

848-1.152
0.000
0.963
0.985
1.000 13C12-PeCDP
1.006
1.013
1.030 13C12-PeCDP
1.039
1.043
1.046
1.068



AN



AN









123 IS2


234 SUR2







402.
46.
246.
80.
174.
36.
61.
77.
32.
64.
35.

29.

76
20
51
31
34
65
14
38
15
01
53

55

318
29
165
48
113
21
42
52
29
42
26

16
0.

.43
.29
.14
.76
.40
.02
.86
.29
.33
.90
.09

.12
921-1.025
0.000
0.927
0.947
0.956
0.962
0.970
0.976
0.981
0.988
0.993
1.001 12378-PeCDD
1.006
1.012
1.019











AN



Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:41 10/21/97

-------
 Page No.
 10/21/97
Listing of U973261B.dbf
Hatched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT compound.Name.. ID.. Flags.
356-358
13C12-PeCDD
368-370






368-370
HxCDF
374-376










A
374-376
13C12-HXCDF
384-386





384-386

HxCDD
390-392





DC SN 28:07
DC WH 28:15
12 Peaks
DC NL 0:00
DC SN 26:19
DC SN 26:39
DC SN 26:50
DC SN 27:15
27:30
27:39
DC SN 27:50
DC SN 28:06
DC SN 28:14
2 Peaks

DC NL 0:00
29:07
29:16
29:26
29:35
DC SN 29:46
30:09
30:16
30:22
30:35
30:47
31:36
10 Peaks

DC NL 0:00
30:09
30:15
30:27
30:47
31:31
5 Peaks


DC NL 0:00
29:41
DC SN 29:46
30:09
DC SN 30:16
30:22
RO 1 . 80
RO 0.67
2
1.32-1.78
1.53
1.53
RO 5.61
RO 2.15
RO 2.17
1.45 2
1.43
RO 0.93
RO 1.22
RO 3.93
3
1.05-1.43
RO 1.50
1.17
1.31
1.30
1.28
1.42
1.22
1.19
1.16
1.33
1.27
1.34
1
0.43-0.59
0.50
0.51 3
0.51 3
RO 0.75
0.51 2
0.52 2
11
1W~.~
1.05-1.43
RO 0.81
1.29
RO 1.78
1.15
RO 1.71
1.09
7.22
3.60
,120.43
4.70
6.97
1.84
2.96
3.24
,950.88
322.08
12.49
12.96
5.84
,272.96

10.08
145.01
424.79
53.75
60.36
18.55
249.31
133.93
28.91
60.83
64.93
14.25
,236.07

20.11
,062.15
,175.81
27.63
,880.40
,475.69
,621.68


3.74
43.87
2.28
116.14
4.12
79.73


1.746.08
189.57






78.09
240.83
30.37
33.83

136.84
72.78
15.50
34.74
36.27
8.15



1,037.43
1,069.26
13.71
971.03
841.83




24.71

62.07

41.62
0.

1,204.80
132.51




0.

66.92
183.96
23.38
26.53

112.47
61.15
13.41
26.09
28.66
6.10

0.

2,024.72
2,106.55
18.30
1,909.37
1,633.86


0.!

19.16

54.07

38.11
1.022
1.027
855-1.145
0.000
0.957
0.969
0.976
0.991
1.000 13C12-POCDD 123
1.005
1.012
1.022
1.027

958-1.051
0.000
0.963
0.967
0.973
0.978
0.984
0.997 123478-HXCDF
1.001 123678-HXCDF
1.004
1.011
1.018 234678-HXCDF
1.045

868-1.132
0.000
0.997 13C12 -HXCDF 473
1.000 13C12-HXCDF 678
1.007
1.018 13C12-HXCDF 234
1.042 13C12-HXCDF 789


952-1.015
0.000
0.958
0.960
0.973
0.976
0.980


IS3












AN
AN


AN




SDR3
IS4

ALT2
ALT1









Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 20:41 10/21/97

-------
Plle*U973261 #1-1024 Acqil7-OCT-1997 19*38*42 QC EI+ Voltage SIR 70S NOiae*3913
303.9016 P*2 BSUB(2S6,30,-3.0) PXD{9,5,3,0.10*,15652.0,1.00*,P,T) BxptEPCOS2
TRIANGLE LABS TexCiSO-M23-4 TLI#43432
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TRIANGLE LABS TextiSO-M23-4 TLI#43432
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-------
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TRXASOLE LABS TextlSO-H23-4 VLI#43432
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PlleiU973261 #1-1024 Aoytl7-OCT-1997 19:38>42 QC XI* Voltage SIR 70S
330.9792 P>2 XxpiEPCUS2
TRIASOLB LABS TextiSQ-H23-4 TLI#43432
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-------
PllatU973261
339.8597 Pi2
#1-1024 Aaqtl7-OCT-1997 19t38i42 OC EH- Volt ago SIR 70S HoiaailB69
BSUB(256,30,-3.0) PKD(7,S,3,0.10X,7476.0,1.00X,P,T) ExpsEPCUS2

TRIANGLE LABS Text :SO-H23-4 TLI843432
1003
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341.8567 Pi2
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BSUB(256,30,-3.0) Pa3(7,S,3,0.10*,7500.0,1.00*,P,T) ExptEPCUS2

TRIANQLE LABS TtacttSO-103-4 TLIt43433
1003
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BSUB(256,30,-3.0) PXD(7,S,3,0.10*,3928.0,1.00\,P,T) ExpiEPCUS2

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100*
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TRIANOLE LABS TaxC « SO-JO 3-4 TLH43432
1009

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-------
Flla>U9/3161 91-1024 Acqtl7-OCT-1997 19t3Bi42 OC EI+ Voltage SIS 70S SOiB»t205B
355.8546 Pi2 BSUB(256,30, -3.0) PXD(5, 5,3, 0.051,8232 .0,1. 001,P,T) ExpiEPCUS2
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1003
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A4.03B6
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P110IU973261 #1-1024 Acqtl7-OCT-1997 19t38t42 OC BX+ Voltagf SIR 70S Noll»tl520
357.05157(2 BSBB(256, 30, -3.0) PJO)(5, 5,3, 0.051, 6080. 0,1. 001,P,T) Exp,BPCVS2
TRIANGLE LABS T*Xt:SO-M23-4 TLI#43432
1003
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Pile,O973261 #1-1024 Acyt 17-OCT-1997 19i38i42 OC EX+ Voltagt SIR 70S Solm»il419
367.8949 7(2 BSUB(2S6, 30, -3.0) PKD(5, 5, 3, 0.051,5676. 0,1. 001,P,T) Exp,EPCVS2
TRIANQLS LABS T*xt,SO-IU3-4 TLI#43432
1003
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P110IU973261 #1-1024 Acgi 17-OCT-1997 19i38i42 OC BI+ Voltafff SIR 70S Nola»>930
369.8919 Pi2 BSUB(256, 30, -3.0) PXD(S, 5, 3, 0.051,3720. 0,1. 001,P,T) Exp,EPCU32
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10031
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330.9792 7(2 SxptSPCUS2
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100S
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-------
PlletU973261
#1-404 Acq:17-OCT-1997 19s38t42 GC EI+ Voltage SIR 70S Holeat33S5
373.8208 Pt3 BSOB(2S6,30, -3.0) PXD(7,5,3,0.10*,13460.0,1.00*,P,T) ExpiBPCUS2
TRIANGLE LABS TejctiSO-023-4 TLI843432
100k
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A7.81ES
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PlleiU973261
375.8178 Pt3
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385.8610 Pi3
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31(00 	 32(00 time
#1-404 Acqtl7-OC7-1997 19t38t42 OC EH- Volt*ff» SIS 70S Solm»t6723
BSUB(256,30,-3.0) PXD(7,5,3,0.10\,26892.0,1.00\,P,r) BxpiEPCUS2
TRIANGLE LABS TexttSO-IO3-4 TLI#43432
IOCS

80:
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392.9760 Pt3
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A
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31(00 	 32(00 Time
#1-404 Acqil7-OC7-1997 15(30(42 OC BH- Voltage SIR 70S
ExpiEPCU32

TRIANGLE LABS TextiSO-M23-4 TLU43432
IOCS
80.
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29 1 07
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#1-404 Acqil7-OCT-1997 19i38t42 OC EH- Voltage SIR 70S
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TRIANGLE LABS T*XtiSO-M23-4 TLZX43432
100S
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30il2 " 5.2S4
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31(00 ' ' ' 32(00 Tin*

-------
 '11»*U973261 91-404 Acqi 17-OCT-1937 19*38*42 SC BI+ Voltage SIR 703 NoiSO:1034
363.8156 P*3 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*, 413f. 0,1. 00\,P,T) ExptEPCUSS
TRIANGLE LABS  T*xtsSO-H23-4  TLM43432
100H                       A6.21B5
     29*36    39148   30,00   30113    30*24   30*36   30:48    31tOO   31:12   31*24    31*36
Pllf*U973261 #1-404 Atsq*17-OCT-1997 19i38t43 OC ST+ Voltage SIR 70S Hoio»:1287
391.8127 Pi3 BSVB(256,30,-3.0) PKD(7,S,3,0.10*, 5148.0,1.00*,P,T) Bxp:EPCUS2
TRIANOLB LABS  TextiSO-K23-4  TLI143432
100H                       A5.41ES
     29:36  ' '29:48   30*00    30tl2   30*34   30>36    30t4B    SltOO   31H3    3lt24    31i36
P110I0973261 01-404 JLc
-------
Pllet0973261 Kl-596 Acgtl7-OCT-1997 19:38t42 QC BI+
407.7818 Ps 4 BSOB(256,30, -3.0) PKD(7,5,3,0.10*,6000.
TRIANQLS LABS TexttSO-M23-4 TLI#43432
10031 A5.76E5
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409.
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33'tOo' ' 33112' ' 33\24~ ' ' 33»3ff' ' 33i48
10973261 01-596 Aagtl7-OCT-1997 19t38t42 OC BI+
7789 Pi4 BSOB(256,30,-3.0) ?KD(7.5,3,0.10*,2796.
VOLE LABS Texti3O-K23-4 TLI843432
A2.80B5
A

/ L A6.88E4
' 33'tOo' ' 33': 12' ' 33:24' ' 33*: 36 33\48
10973261 §1-596 Aegtl7-OCT-1997 19:38:42 OC EH-
8253 Pi4 BSOB(256,30,-3.0) PXD(7,5,3,0.10*,8716.
HOLE LABS Te3cttSO-H23-4 TLI143432
A6.21S6
A


A
Voltage SIR
0,1.00*,P,T)



SM^UJM
34 tOO
Voltage SIR
0,1.00*,P,T)


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34:00
Voltage SIR
0,1.00f,P,T)




70S Noise: 1500
ExptSPCOS2
1.2B5



... A5-/OS4 A3.73S4
~ /^-A A^V-Sy^V^^-v/^ 	 ^^x
34:12 34t24 34\36
70S Soieet699
BxplEPCOSa


A3.27B4 U.95E4
34:12 34:24 34:36
70S Solmet2179
SxptSPCOS2
AS.70B6
A:,



33iOO 3 3': 12 33:24 33>36 33:48 34': 00 34:12 34:24 34:36
IO973261 *1-S96 Acgtl7-OCT-1997 19:38:42 OC EH- Voltage SIR 70S Soimei3439
8220 Pi4 BSOB(256I30.-3.0) PKD(7, 5,3, 0.10*, 13756. 0,1. 00*,P,r) BxptBPCUS2
HOLE LABS TexttSO-K23-4 TLIK43432
A1.47S7
A


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33<00 33:12 33:24 33:36 33t48
,0973261 tl-596 Acqtl7-OCT-1997 19:38:42 OC EX+
9729 Pt 4 SxpiBPCOSa
MOLE LABS TextiSO-H23-4 TLI»43432




33:00 33': 12 33:24 '33:36 '33:48
10973261 91-596 Ac/ 1 *^ * *— ' ^*"

34:12 34:24 34:36
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Time
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•.4.6E5
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Time
S.8E6
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O.OEO
Time
C1.1E7
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O.OEO
Time
3.6S4
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.1.SS4
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O.OEO
Time

-------
fiJL«iUS73261 #1-596 Acijt 17-OCT-1SS7 19:38:42 OC EH- Voltage SIS 70S KoiS»:742
423.7766 Pt4 BSOB(256,30,-3.0) Pn}(7,5,3,0.10X,2968.0,1.00*,P,T) BxptEPCUS2
TRIANGLE LABS  TncttSO-O23-4  TLI143432
IOOH        A1.07BS
     33:12   33:18  33:24   33:30   33:36  33:42   33:48  33:54   34:00  34:06   34:12   34(18
Pil»iff973261 tl-596 Acy: 17-OCT-1997 19:38:42 OC EH- Voltaff* SIR  70S Noil*:691
425.7737 Pi4 BSOS(256,30,-3.0) PXD(7,S,3,0.10*,2764.0,1.00*,P.T)  BxptBPCUS2
TRIANOLB LABS  Tvct:SO-M23-4  TKCt43432
100*                                                      A1.23B5
 80.

 60.

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                                                                                      A4.34S4
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                                                                                                    O.OBO
                                                                                               34:24   Via»
     33:12   33:18   33:24   33:30   33:36  33:42   33:48  33(54   34:00  34:06   34:12  34:18
Fll»:0973261 tl-596 Acytl7-OCT-1997 19:38:42 OC EH-  Voltaff* SIR 70S Boim*t2647
435.8169 Pi4 BSOB(256,30,-3.0) PXD(7,5,3r0.10»l, 10588.0,1.00»l,P,T)  Bxp:BPCUS2
TRIANOLB LABS  T»Xt:3O-M23-4  TLI043432
10091                                                     A1.3.2E7

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                                                                                                '34': 2 4   Tim*
                                                                                                   .4.8B6

                                                                                                   .3.8B6

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                                                                                                   -1.9S6

                                                                                                    .9.SS5
                                                                                                     O.OBO
     33:12   33:18  33:24   33:30   33:36  33*42   33:48  33:54   34:00  34:06
Fll»:U973261 tl-596 Acyt17-OCT-1997 19:38:42 OC SX+ Voltaym SIR  70S Soit»»2239
437.8140 Pt4 BSOB(256,3O,-3.0) PXD(7,5,3,0.10*,8956. 0,1.00*,P,T)  B*ptBPCUS2
TRIANGLE LABS  TfXt:SO-M23-4  TU«43432
                                                                                 34:12  34\13   34\24.   fim»
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80.
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33:12 33: 18 33': 24 33:30 33136 33142 33:48 33:54 34<6o' 34*: 06 34(12 34(10 34(24 rim«
Pil*:U973261 tl-596 Acqt 17-OCT-1997 19t38i42 OC EH- Voltage SIR 70S
430.9729 Pt4 BxptSPCUS2
TRIANGLE LABS T*xt:3O-M23-4 TLIt 43432
1009

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  0.
      33:12
                                                                                   34(13
      33(12  33(10' '  '33(24  33(30 '  '33(3tf ' '33(42  ' '33(40 ' 33(54  ' '34(00 ' 34(05 '  '34(12 ' '34(10
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                                                                                                     O.OBO
                                                                                                34 2 4   Tlm»

-------
 '11010973261 H-596 Acqtl7-OCT-199l 19:38:42 OC EH- Voltage SIR 70S NOis0>1430
441.7438 Pt4 BSUB(2S6,30,-3.0)  P1H>(7,5,3,0.10*,5720.0.1.00*,P,T)  E3CptEPCUS2
TRIANOLE LABS  TWCCISO-U23-4  TLI043432
100H
         33'iOO       34tOO       35'tOO       36'tOO      37:00       38*00       39'tOO
Pll»:ff973261 #1-596 Acqt 17-OCT-1S97 19t38i42 OC EH- Voltafff SIR 70S Ko±a»:1440
443.7399 Pi4 BSUB(236,30,-3.0) PXD(7,3,3, 0.10\,S760.0,1.00*,P,T) ExptEPCUSl
TRIANOLE LABS  TfXtiSO-K23-4  TLX#43432
100H
                                                               Tlaa
          33100       34:00       35iOO       36:00       37:00
Pllmiff973261 01-596 Acy: 17-OCT-1997 19:38:42 OC EH- Voltag» SIR 70S
430.9729  Pi4 SxptBPCUS2
TRXANOLE  LABS  T»xt!3O-K23-4  TLI043432
10031
                                                                     38:00
                                                                                39 tOO
                                                                                                   lima
  901

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35>10                                    (I                 |l.
.1.9B7

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   5E7
          33:00      34:00       35:00       36:00       37:00       38:00
Pll»:U973261  01-596 Acgtl7-OCT-1997 19:38:42 OC EH- Voltay» SIR 70S
513.6775 Pt4  Exp:BPCU32
TRIANOLE LABS  T»xt:SO-H23-4  TLH43432
                                                                                39 tOO
                                                               OEO
                                                                Maw
          33:00
                      34:00
                                 35100
                                             36:00
                                                         37:00
                                                                     38100
                                                                                 39:00

-------
 Page No.
 10/21/97
         Listing  of 09732618.dbf
         Matched  GC Peaks / Ratio / Ret.  Time
 Compound/
 M_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.
                                                                                          Flags.
 13C12-HpCDD
 436-438
 436-438
 OCDF
 442-444
                                0.88-1.20
                                                                             0.971-1.029
 442-444
DC

DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

NL

SN
SN
1

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:00
33:54
34:05
34:25
Peak

0:00
33:27
33:38
35:10
35:53
36:34
36:49
37:33
37:43
37:54
38:01
39:19
39:19
39:27
Peaks


RO
RO

0.

RO
RO
RO

RO

RO
RO
RO
RO

RO
RO

1
1
0
6

.18
.03
.31
.59
UK,
76-1.02
0
0
0
1
0
0
0
0
1
0
1
0
1
0

.99
.66
.46
.36
.86
.46
.97
.70
.95
.58
.39
.93
.36
.55

                               9.77
                           2,610.01      1,321.34      1,288.67
                               9.44
                               2.84
                           2,610.01

                     Above: HpCDD / Octa-CDO and CDF Follows —
                                                                                 0.000
                                                                                 1.000 13C12-HpCDD 678  IS7
                                                                                 1.005
                                                                                 1.015
                                                5.74
                                                7.60
                                                3.99
                                                4.71
                                                3.81
                                                7.69
                                               11.34
                                                3.21
                                                2.84
                                                2.51
                                                4.50
                                                1.54
                                                1.06
                                                5.35                             1.083
                                                0.00
                                                            0.890-1.110
                                                                0.000
                                                                0.918
                                                                0.923
                                                                0.965
                                                                0.985
                                                                1.004 OCDF
                                                                 .011
                                                                 .031
                                                                 .035
                                                                 .040
                                                                 .043
                                                                 .079
                                                                 .079
                                      AN
 OCDD
 458-460
 458-460
               0.76-1.02
DC  HL   0:00    1.01          4.50
        36:27    0.80         55.20
DC  SN  36:40 RO 0.38          2.06
      1 Peak                  55.20
                                                             24.50
             0.890-1.110
                 0.000
          30.70  1.000 OCDD
                 1.006
 13C12-OCDD                     0.76-1.02
 470-472         DC  NL   0:00 RO  1.10          2.95
                         36:26     0.85      4,889.16
                 DC  WH  36:53     1.02         27.89
 470-472               1 Peak               4,889.16
                                        2,253.07
             0.995-1.005
                 0.000
       2,636.09  1.000 13C12-OCDD
                 1.012
                                                                                     IS8
 Column Description	   'Why Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Hass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report
               WL-Below Retention Time Window
               HH-Above Retention Time Window
               SN-Below Signal to Noise  Level
               
-------
Fil»,0973261 #1-596 Acqtl7-OOt-i997 19:38,41 X BI+ Voltage SIR 70S Jtoia«»1131
457.7377 Pt4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10^,4524. 0,1. OOf,F,T) BxptEFCUS2
TRIANGLE LASS  T*XttSO-M23-4  TLI143432
100H                     A2.JJ7E5
    36118          36', 24         36', 30         36,36         36,42         36,48
Pil»iU973261  tl-596 Acytl7-OCT-1997 19,38:42 X EH- Voltage SIS 70S Kolm»tlll9
459.7348 Pt4  BSUB(256,30,-3.0) PXD(7.S,3,0.10*,447f.Oe1.00*,P,T) Exp,EPCV32
TRIANGLE LABS  TuxttSO-H23-4  TLI*43432                                   • •
lOCA
    36,18          36,24         36,30         36,36         36,42         .36,48
Fil*,U973261  tl-596 Aagt 17-OCT-1997 19,38,42 OC BI+ Voltag* 3IR 703 Nolle,855
469.7779 Pi4  B3UB(256,30,-3.0)  PXD(7,5,3,0.10*,3420.0,1.00X,F,T) Exp,EPCUS2
TRIANGLE LABS  TtXti3O-M23-4 TLH43432
100H                    A2.25E7
                            4E7
    36,18          36,24          36,30         36,36         36,42         36,48
Pll»,U973261 tl-596 Acq, 17-OCT-1997 19t38t42 OC EH- Voltag* SIR 70S Nolt«,782
471.7750 Pt4 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,3128.0.1.00*,P,T) Exp,EPCUS2
TRIANGLE LABS  T»Xt,SO-H23-4  TLI*43432
100*                   A2.(
  80.

  60.

  40.

  20:
    36,18         36,24         36,30         36,36         36,42
Fill, 0973261 tl-596 Acqt 17-OCT-1997 19,38,42 OC XL* Voltag* SIR  70S
430.9729 Pi4 2xp,EPCU32
TRIANGLE LABS  TvtttSO-H23-4  TLI143432
3-OOH                                                         36,42
  801

  60.

  40.

  20.
                                                                           36,48
                                                                                         36,54
                                                                                          36,54
                                                                                          36154
                                                                                          36,54
                                                                                                    .O.OBO
                                                                                                        Tima
                                      .7.1E6

                                      -5.7E6

                                      .4.3S6

                                      '.2.8E6

                                      -1.4E6

                                      .O.OEO
                                           Tim*



                                      .8.3E6

                                      '.6.6E6

                                      '.5. OE6

                                      -3.3E6

                                       .1.7E6

                                        O.OEO
     36il8
                   '36\24
                                 '36', 30
                                               36,36
'36,42
'36,48
i  I   i
36,54
-1.1E7

'.9.1S6

'.6.8E6

.4.6E6

.2.3E6

 O.OEO
    Tim

-------
Peak Locate Examination:17-OCT-1997:19:37 File:U973261
      Experiment:EPCUS2 Function:2 Reference:PFK
CO

-------
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC  EI+ Voltage  SIR  70S
303.9016 F:2 Exp:EPCUS2
Sample Text;SO-M23-4  TLI#43432 File Text:TRIANGLE  LABORATORIES,  INC.
lOOi
           19:00                   20:00                  21:00
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC  EI+ Voltage  SIR  70S
305.8987 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%
 80 j
 60 j
 40J
 20J
                                               A2.68E7
                                                                                    A
                                                                                22:00
     T	f-	,	,	T - <"i	1	f=—i	i^ '"'I   I    I  '  I	r—	1	=f=
           19:00                   20:00                   21:00
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC  EH- Voltage  SIR 70S
315.9419 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                                                  21;35
 80 J
 60 J
 40J
 20J
                                                                                    A
                                                                                22:00
  0.
           19:00
                                  20:00
                                                         21:00
22:00
                                                                                          6.3E6
                                                                                         L5.0E6
                                                                                         L3.8E6
                                                                                         _2.5E6
                                                                                         L1.3E6
                                                                                         LO.OEO
                                                                                             Time
                                                                                          8.3E6
                                                                                         L6.7E6
                                                                                         L5.0E6
                                                                                         L3.3E6
                                                                                         L1.7E6
                                                                                         LO.OEO
                                                                                             Time
                                                                                         _3.5E6
                                                                                         L2.8E6
                                                                                         _2.1E6
                                                                                         _1.4E6
                                                                                         L7.0E5
LO.OEO

-------
File:U973261 ttl-1024 Acq: 17-OCT
319.8965 F:2 Exp:EPCUS2
Sample Text :SO-M23-4  TLI#43432
100%
             21:00
File:U973261 #1-1024 Acq:17-OCT
321.8936 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432
100%
                   1997 19:38:42 GC EI+ Voltage SIR 70S

                   File Text : TRIANGLE LABORATORIES, INC.
                      22:00                 23:00
                   1997 19:38:42 GC EI+ Voltage SIR 70S

                   File Text:TRIANGLE LABORATORIES, INC,
                                                                               24:00
             21:00
File:U973261 #1-1024 Acq:17-OCT
331.9368 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432
100%
 80 j
 60 j
 401
 201
                                   22:00                 23:00
                                •1997 19:38:42 GC EI+ Voltage SIR 70S

                                File Text:TRIANGLE LABORATORIES, INC.
                                         22'1622:30
                                                                  24:00
                                                                                        .O.OEO
                                                                                            Time
21:00
                                   22:00
                                                         23:00
                                                                               24:00
                                                                                         .O.OEO
                                                                                            Time
4.2E6

3.4E6
2.5E6
1.7E6

8.4E5
O.OEO

-------
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
      25:36  25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36  27:48  28:00  28:
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS2
Sample Text:SO-M23r4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
      25:36  25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36  27:48  28:00  28
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
                           26:18   '                27:06

 80 j

 60J

 401

 20 J
  OJ
                                                                                         O.OEO
                                                                                            Time
      25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:
                                                                                         O.OEO
                                                                                            Time
                                                                                         8.1E6

                                                                                         .6.5E6

                                                                                         4.9E6

                                                                                         .3.2E6

                                                                                         .1.6E6

                                                                                         .O.OEO

-------
File:U973261 tfl-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                       A4.76E6
      25i36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS2
Sample Text :SO-M23-4  TLI#43432 File Text-.TRIANGLE LABORATORIES, INC.
100%                       A3.27E6
 80-
 60 j
 40J
 20J
15
i.3
Ll
      25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28il2
File:U973261 #1-1024 Acq:17-OCT-1997 19:38:42 GC  EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES, INC.
100%                       26;18                   27:06
                                                                                         10,
 80.:
 601
 40.:
 201
  OJ
L4
_3
Ll
      25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28il2
LO
,7E5
,7E5
,8E5
,9E5
.9E5
.OEO
 Time
 1E6
 5E6
 9E6
 2E6
 6E6
,OEO

-------
File:U973261 #1-404 Acq;17-OCT-1997 19:38;42 GC EI+ Voltage SIR 70S—
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100*                                           31;37
                          31:17            31:3:
 80J         31:06
 60J
 40 j
 20J
  0.
32:06
_4.
L3.
i_2.
L1.
L8.
       31:00  31:06  31:12 31:18  31:24 31:30  31:36  31:42 31:48  31:54  32iOO 32506 32il2
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                          31;36
           ^O
4E4
5E4
6E4
8E4
8E3
OEO
 Time
                                                                                         o
       31:00  31:06 31:12  31:18  31:24 31:30  31:36  31:42 31:48  31:54  32:00 32:06 32:12
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100*                                     31A31
 80J                                      / \                                            t-2
 60J
                                         /  \
 40J                                     /  \                                           Ll
 20J                                     /    \                                          L5
       31:00  31:06 31:12  31:18 31:24 31:30  31:36 31:42 31:48  31:54  32:00 32:06  32:12
              2E4
              3E4
              5E4
              ,7E4
              ,3E3
              ,OEO
               Time
              8E6
              ,3E6
              ,7E6
              ,1E6
              , 6E5
              , OEO

-------
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                          A8.15E4
 80 j
 60 J
 40 J
 20 j
       31:00  31:06 31:12  31:18  31:24 31:30 31:36  31:42 31:48 31:54
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%.                                        A6 . 1QE4
 80 J
  OJ
32
:00 32:06
                  _4.4E4
                  _3.5E4
                  _2.6E4
                  _1.8E4
                  _8.8E3
                  O.OEO
32:12
Time
  OJ
       31:00  31:06 31:12  31:18  31:24 31:30  31:36  31:42 31:48  31:54
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                    3U31
 80 J
 60 J
 40 J
 20 J
32
:00 32:06
32:12
Time
  OJ
                  _2.8E6
                  L2.3E6
                  L1.7E6
                  L1.1E6
                  L5.6E5
                  LO.OEO
       31:00  31:06 31:12  31:18 31:24 31:30  31:36  31:42 31:48  31:54  32:00 32:06  32:12
                     Time
                             O

-------
File:U973261 #1-404 Acq:17-OCT-1997 13:38:42 GC  EI+ Voltage  SIR 70S
389.8156 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%
 80 j
 60 j
 40 j
 20J
  OJ
                                                31:18
     30:32
                                                                                   6.2E4
                                                                                  _5.0E4
                                                                                  _3.7E4
                                                                                  _2.5E4
                                                                                  _1.2E4
          30:36       30:48       31:00      31:12      31:24       31:36
File:U973261 #1-404 Acq:17-OCT-1997  19:38:42  GC  EI+  Voltage SIR  70S
391.8127 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
100%.                              31;01
                                                 31:17
       30:33                30.54
                                                                             31:48
80j
60 j
40J
 20j
  OJ
"
                30
                          :50A/ \/
                          ^v     v~~
                                                      31:30
                              Lj.43.
                          	3.1.;.54
                                                                                  .O.OEO
                                                                                     Time
                       5.4E4
                      L4.3E4
                      _3.2E4
                       272 E4-
                      L1.1E4
          30:36       30:48      31:00      31:12       31:24       31:36
File:U973261 #1-404 Acq:17-OCT-1997  19:38:42  GC El* Voltage SIR 70S
401.8558 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
lOOi                                              31;18
 80J                             31:0°
 60 J
 40 j
 20J
                                                                             31:48
                                                                                   O.OEO
                                                                                     Time
  OJ
                                                                                        _5.2E6
                                                                                        _3.9E6
                                                                                        .2.6E6
                                                                                        _1.3E6
          30:36
                    30:48
                          31:00
31:12
31:24
31:36
31:48
.O.OEO

-------
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
 80J
 60 j
 40 j
 20J
  0
          30:36      30:48       31:00       31:12      31:24      31:36
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%
 60J
 40J
 20 j
          30:36      30:48       31:00       31:12      31:24      31:36
File:U973261 #1-404 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                             31;18
 80J                            31:0°
 60 J
 40 J
 20J
  OJ
                                                                             31:48
                                                                             31:48
                                                                    6.2E4
                                                                    .5.0E4
                                                                    .3.7E4
                                                                    .2.5E4
                                                                    .1.2E4
                                                                    .O.OEO
                                                                       Time
          30:36
30:48
                                 31:00
31:12
31:24
31:36
31:48
                                                                    O.OEO
                                                                       Time
6.5E6
.5.2E6
3.9E6
2.6E6
.1.3E6
.O.OEO

-------
File:U973261 #1-596 Acq:17-OCT-1997  19:38:42  GC EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
100*  33JT6	
                                                         34:40       35i°°35:09
               3-:29 ,,.,o	33u:54	,^.^—A-7!	A	o	A-.	**	11	A—,	35-^23-
    33il2  33:24  33:36  33:48   34:00   34:12  34:24  34:36  34:48  35:00  35:12  35:24
File:U973261 #1-596 Acq:17-OCT-1997  19:38:42 GC EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
100%   33:17
 80j
 60 j
 40 j
 20 j
                                                                           13
                35:27
 —I—i—i—i—i—i—I—r—T—i i i—i—i—i i i  i I i—i—i—i i I—i—i—i  i i—i—i—i  i i—r—i—i  i i—i—i—r—i—i-
33:12  33:24  33:36  33:48   34:00   34:12   34:24  3.4:36
                                                               T
                                                             34:48
File:U973261 #1-596 Acq:17-OCT-1997  19:38:42 GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-4   TLI#43432  File Text:TRIANGLE LABORATORIES, INC.
100%                                      34;15
 80 j
 60 J
 40J
 20J
i i I  i i i i i I  i i i i i I  i i
35:00  35:12  35:24
                                                                                      .4.0E4
                                                                                      .3.2E4
                                                                                      :2v4E4
                                                                                      .1..6E4
                                                                                      .8.0E3
                                                                                      O.OEO
                                                                                         Time
4.1E4
.3.3E4
2.5E4
1.6E4
.8.2E3
.O.OEO
   Time
    33:12  33:24   33:36   33:48   34:00  34:12  34:24  34:36  34:48  35:00  35:12  35:24
                                                                                      2.1E6
                                                                                      1.7E6
                                                                                      .1.2E6
                                                                                      .8.3E5
                                                                                      .4.2E5
                                                                                      .O.OEO
                                                                                         Time
                                                                                                 10

-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:
407.7818 F:4 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text:
100%               A2.81E5
 42 GC EI+ Voltage SIR 70S
 TRIANGLE LABORATORIES, INC,
                   33:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38
409.7789 F:4 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text
100%               A2.67E5
    34:00
:42  GC  EI+ Voltage SIR 70S
:TRIANGLE LABORATORIES, INC.
35:00
                   33:00
File:U973261 #1-596 Acq:17-OCT-1997 19:38
417.8253 F:4 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432 File Text
100%,                33; 02
 80 j
 60 J
 40J
 20 J
  OJ
    34:00
:42  GC  EI+ Voltage SIR 70S
;TRIANGLE LABORATORIES,  INC.
          34:15
35:00
                   33:00
    34:00
35:00
 1.3E5
 1.1E5
 8.0E4
 5.3E4
 2.7E4
.O.OEO
   Time
 1.2E5
 9.3E4
 6.9E4
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-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EH- Voltage SIR  70S
423.7766 F:4 Exp:EPCUS2
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Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC,
100%                            33 54
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-------
File:U973261 #1-596 Acq:17-OCT-1997 19:38:42 GC EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS2
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Sample Text:SO-M23-4  TLI#43432 File Text:TRIANGLE LABORATORIES,  INC,
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File:U973261 #1-596 Acq:17-OCT-1997  19:38:42 GC  EI+ Voltage SIR 70S
435.8169 F:4 Exp:EPCUS2
Sample Text:SO-M23-4  TLI#43432  File Text:TRIANGLE LABORATORIES,  INC.
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-------
File:U973261 #1-596 Acq: 17-OCT-l
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-------
TLI Project:      43432
Client Sample:   SO-23-4
           Method 23 TCDD/TCDF Analysis (DB-225)
                                Analysis File:   X973639
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-4A-C
1.000
n/a
DB-225
Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/18/97
Dilution Factor: n/a
Blank File: U973257
Analyst: BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
XF24087
X973633
n/a
n/a
n/a
2,3,7,8-TCDF
1.3
                      0.78     24:33
»C12-2,3,7,8-TCDF
3.5
87.9     40%-130%
0.79     24:32     	
 Recovery Stantiarrf
13C12-1,2,3,4-TCDD
                                     0.81      23:19      	
                      Data Reviewer.
                                10/23/97
                                         Page 1 of 1
                                              C2NFJ>SR vlOO. LARS «. 10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                          Printed: 23:35 10/23/97

-------
                        Initial
                                  	Date...
  Data Review By:
 \j (_.  _lD/JLl/_L_  Calculated Noise
Area:  n/a
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
Listing of X973639B.dbf
Matched GC Peaks / Ratio  / Ret. Time
 Compound/
 M_2	QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Ral.RT Compound.Name..  ID.. Flags.
TCDF
304-306 DC NL 0:00
19:46
19:53
20:04
20:12
20:17
20:24
20:47
20:55
21:03
21:14
21:20
21:30
21:39
21:48
21:58
22:07
22:31
22:36
22:44
22:52
23:00
23:07
23:15
23:31
23:46
23:57
24:24
24:33
24:48
25:08
25:17
25:33
25:40
26:13
27:07
304-306 35 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 19:35
DC ML 22:29
DC WL 22:39
0.65-0.89
RO 1.33
0.79
RO 2.93
RO 0.57
0.70
0.67
0.81
0.78
0.79
0.79
0.79
RO 0.63
0.79
0.78
0.79
0.77
0.75
0.78
0.79
RO 0.90
0.80
0.79
0.77
0.79
0.78
0.77
0.77
0.79
0.78
0.75
0.77
0.79
RO 1 . 27
0.86
0.78
RO 0.43

0.65-0.89
0.66
RO 0.59
RO 1 . 62
RO 0.56
0.798-1.112
11.15
7,257.49
75.07
57.12
20.30
62.05
102.11
10,340.25
6,091.61
7,180.72
5,508.93
99.86
3,661.54
4,925.04
1,924.21
11,238.99
2,985.97
5,724.63
3,924.73
82.80
90.26
4,116.99
747.45
3,663.88
3,889.24
448.24
2,567.26
2,301.89
2,387.65
2,018.92
1,711.85
3,476.71
15.15
6.21
1,588.19
105.17
100,398.48

3,197.52
124.33
24.85
8.36
24.92
45.84
4,536.10
2,682.27
3,169.05
2,438.33
43.44
1,614.56
2,157.04
849.86
4,904.51
1,277.81
2,511.50
1,726.42
41.95
40.18
1,818.00
324.58
1 , 619 . 04
1,709.35
194.47
1,115.13
1,018.31
1,049.80
868.41
743.93
1,538.69
10.90
2.88
693.66
45.75


4,059.97
42.41
43.39
11.94
37.13
56.27
5,804.15
3,409.34
4,011.67
3,070.60
69.11
2.046.98
2,768.00
1,074.35
6,334.48
1,708.16
3,213.13
2,198.31
46.78
50.08
2,298.99
422.87
2,044.84
2,179.89
253.77
1,452.13
1,283.58
1,337.85
1,150.51
967.92
1,938.02
8.56
3.33
894.53
106.41

0.000
0.806
0.810
0.818
0.823
0.827
0.832
0.847
0.853
0.858
0.865
0.870
0.876
0.882
0.889
0.895
0.901
0.918
0.921
0.927
0.932
0.938
0.942
0.948
0.959
0.969
0.976
0.995
1.001 2378-TCDF
1.011
1.024
1.031
1.041
1.046
1.069
1.105

0.959-1.041
17.59
6.30
13.58
6.76








0.000
0.798
0.916
0.923
                                                                                                   AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 20:55 10/21/97

-------
 Page No.     2           Listing of X973639B.dbf
 10/21/97                 Matched GC Peaks / Ratio / Ret. Time

 Compound/
 H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak. 1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.

                 DC  WL  22:58 RO  0.57         39.97                             0.936
                         24:06 RO  0.62          7.68         3.34          5.35   0.982
                         24:32     0.79      7,730.05     3,406.82      4,323.23   1.000 13C12-2378-TCDF ISO
                         25:05     0.88          2.72         1.27          1.45   1.022
                         25:15 RO  0.60         28.71        12.49         20.73   1.029
                 DC  WH  26:57     0.68         91.52                             1.099
 316-318               4 Peaks               7,769.16
                                        Above:  TCDF /  TCDD Follows
 13C12-TCDD                     0.65-0.89                                     0.913-1.087
 332-334
DC




DC
DC
DC
DC
DC
DC
ML




WH
WH
WH
WH
WH
WH
0:00
21:49
23:00
23:19
24:06
25:17
25:29
25:40
25:52
26:25
26:35
RO
RO


RO
RO
RO
RO
RO
RO
RO
3.
0.
0.
0.
0.
1.
2.
0.
0.
2.
2.
11
94
76
81
92
07
38
45
99
66
15
5
30
5,175
6,318
70
5
5
7
14
2
5
.20
.87
.20
.95
.99
.91
.36
.08
.05
.74
.54

16.38
2,240.34
2,837.37
36.73







17.44
2,934.86
3,481.58
40.11






0.
0.
1.
1.
000
949
000
014
1.048
1.
1.
1.
1.
1.
1.
099
108
116
125
149
156
                                                                                        13C12-2378-TCDD IS1
                                                                                  1.014  13C12-1234-TCDD RSI
 332-334               4 Peaks              11,596.01
 Column Description	  "Why" Code Description	  QC Log Desc.
 H_Z   -Nominal Ion Hass(es)      WL-Below Retention Time Window   A-Peak Added
 ..RT. -Retention Time (mm:ss)    WH-Above Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below Signal to Noise Level   D-Peak Deleted
 OK    -RO=Ratio Outside Limits  
-------
 'lletX973639 71-803 Acqt1B-OCT-iSyl 17:20:10 OC EH- Volt ago SIR AUtoSpea Noise:4194
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Sample Text:SO-U23-3   TLI*43432 Pile Text: TRIAHOLE LABS
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100JI
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-------
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-------
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-------
                 Peak Locate Examination:18-OCT-1997:17:19 File:X973639
                      Experiment:XCONF_TT Function:! Reference:PFK

-------
   < :>?l \ i^fff^*; ^o^x*3*
TLI Project:      43432
Client Sample:   FB1-M23
                                              Method 23 PCDD/PCDF Analysis (a)
                                                          Analysis File:   U973262
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-5A-B
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
***^-*r&r^
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
U,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals " ^ -,\, { ,^--^;]
•. \ *• •• \ v f ^v,S- stkrf v. •>
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Awt |ngJ ;
\f •>•• ^-M^W-"*
ND
ND
ND
ND
ND
ND
ND
ND
0.007 	
0.008 	
0.01 	
0.01 	
0.01 	
0.01 	
0.01 	
0.009 	
0.007 	
0.007 	
0.008 	
0.006 	
0.007 	
0.008 	
0.01 	
0.01 	
0.01 	
N«rat>«i^ &. I*IP<* 4 >x? - ^ '"r> vx* >X " s ^: ^teggiA ,
^^^W• %%s^->"-. s f •• <. y S "• ~~ <••$'.•.•.•'•' f
-------
TLI Project:
Client Sample:
43432
FB1-M23
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U973262
Mental Standards ,„ t \
13Cl2-2,3,7,8-TCDF
l3C12-2,3,7,8-TO>D
13C12-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13CI2-l,2,3,4,6,7,8-HpCDF
13C,2-1.2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
^. ^»''.*i»^ ~J ^t *»V
Surrogap stat^aitfd^ {Ty
37Cl*-2,3,7,8-TCDD
l3C12-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
»C,2-l,2,3,4,7,8-HxCDD
13C12-l,2,3,4,7,8,9-HpCDF
Alternate Standards * fy - A Wfe?;-\W0|^ %
3.4
3.9
3.5
3.8
3.9
R&-^^\$ii^
3.2
3.7
\;'^;5^^^^


^ -- -VJtRtBtw*
57.6
86.4
93.5
109
110
102
80.5
99.6
99.7
^ ** *^^*-i %
-<%v '^•^^BCd-ye;
85.8
97.7
88.3
94.3
98.3

79.9
91.8
;"^>^J


ry\5-QCL%lt» ,;
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
•••.!'. A>^ i^f {» % N •&.*
^ ^tSQ^IWilK- - ^N
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
ryvvo^l»is>V
40%-130%
40%-130%
^^ -%^^


nRaBa
0.80
0.76
1.46
1.54
0.51
1.24
0.42
1.01
0.85
•;Ni*,»*t ^ *
> *W*^X

1.53
0.51
1^4
0.43
'••• patioli
0.49
0.52
"RkW
0.80
1.21
?;c^8t^
21:36
22:31
26:18
27:29
30:15
30:59
33:02
33:54
36:27
**Ut^5»t^f*% ^
x^^^*V
22:32
27:06
30:09
30:54
34:15
iftS**^
31:31
30:47
"*'\**Wi83$
22:17
31:18
;5^s/

__


	
__
	
	
—
^*N^tn^%S •>S"-
*v*|r^%;4




—
?t\8^|

—
^Ssr^


                     Data Reviewer.
                                       Page 2 of2
                                        10/21/97
                                                      X237.PSR xiOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                  Printed: 20:41 10/21/97

-------
                        Initial
                                    . .Data..
 Data Review By:
                                              Calculated Noise Area:
                                                                     2.37
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.      1
 10/21/97


 Compound/
 M_Z	QC.Log Omit Why
Listing of U973262B.dbf
Matched GC Peaks / Ratio
/ Ret. Tine
.RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306










304-306
13C12-TCDF
316-318














316-318
TCDD
320-322









DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC

DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL
WL
ML
WL
WL
SN
SN

SN
SN
WH
WH
WH
WH
WH
1

NL
SN
SN
SN
SN
SN
SN
SN
SN

0:00
18:27
18:41
19:02
19:18
19:53
20:04
20:13
21:57
22:24
22:32
Peaks

0:00
18:50
19:10
19:40
20:14
20:51
21:03
21:36
21:51
22:09
22:40
23:00
23:13
23:56
24:06
Peak

0:00
19:17
19:31
21:15
21:20
21:30
21:35
22:04
22:09
0.
RO
RO

RO


RO

RO

RO

0.

RO
RO
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
RO

0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0
0
0
1
0
0
1
0
2
0
2

.91
.35
.79
.18
.79
.82
.73
.78
.88
.75
.14

3.33
1.33
1.
10.
11
60
7.73
11.
1.
8.
1.
4.
2.
0.
23
65
76
38
25
14
00
65-0.89
0
3
1
0
0
1
1
0
0
0
6
0
0
2
0

.82
.83
.21
.90
.64
.32
.21
.80 2
.52
.26
.46
.28
.40
.56
.28
2
M !«»•_. .
3.
1.
2.
2.
22.
2.
14.
.517.
12.
8.
4.
7.
3.
6.
5.
.517.
Htf+rva
65-0.89
1
3
0
0
2
0
1
2
0
.93
.47
.96
.58
.66
.28
.17
.15
.44
i.
0.
0.
0.
0.
0.
3.
2.
1.
14
65
34
21
64
28
00
83 1.123.19
80
99
81
75
56
04
36
83
/
-------
 Page No.     2
 10/21/97


 Compound/
 M_Z.... QC.Log Omit Why
Listing of U973262B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.



320-322
37C1-TCDD
328

















328
13C12-TCDD
332-334











332-334
DC
DC
DC

SN
SN
SN
0
23:16
23:25
23:33
Peaks
RO
RO


1
1
0

.26
.66
.88

2
1
2
0
.04
.31
.40
.00
1.
1.
1.

033
040
046

0.911-1.089
DC
DC
DC
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC



DC
DC
DC
DC
DC

NL
WL
SN
SN

SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1

NL
ML
WL
SN



SN
SN
SN
SN
SN
3
0:00
20:19
20:48
21:03
22:32
22:49
22:57
23:03
23:03
23:11
23:16
23:29
23:34
23:40
23:48
23:55
23:59
24:06
Peak

0:00
19:09
19:23
21:02
22:17
22:31
22:54
23:16
23:21
23:27
23:40
23:56
Peaks



















0
RO
RO
RO
RO


RO

RO
RO
RO
RO







































0
1
8
2
2,439
5
1
1
4
7
10
1
3
7
4
4
4
2
2,439
.86
.17
.31
.61
.26 2,439.26
.86
.70
.92
.68
.80
.88
.32
.38
.38
.04
.99
.49
.22
.26
.65-0.89
1
0
0
2
0
0
0
0
1
1
0
1

.96
.62
.37
.21
.80
.76
.55
.86
.25
.53
.39
.01

3
5
1
10
3,143
3,012
60
12
10
9
9
11
6,216
.52
.86
.31
.64
.12 1,392.24
.10 1,304.89
.87 26.48
.51
.90
.77
.03
.91
.09
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

000
902
924
935
001 37C1-TCDD SOR1
013
019
024
024
030
033
043
047
051
057
062
065
070

0.911-1.089
0.
0.
0.
0.
1,750.88 0.
1,707.21 1.
48.11 1.
1.
1.
1.
1.
1.

000
850
861
934
990 13C12-1234-TCDD RSI
000 13C12-2378-TCOD IS1
017
033
037
041
051
063

KVuuvn . mf*T\r\ / n**s*no w*»t "I «».«»
PoCDF
340-342








DC
DC
DC
DC
DC
DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN

0:00
24:14
24:26
25:21
25:58
26:53
27:29
27:36
1
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
0
0
1
0
2
1
0
2
.88
.21
.09
.96
.42
.01
.28
.99
w i i\*vu f fv^uc c wi j. wwa 	
•^ 2
1
3
12
1
2
0
1
.09
.05
.77
.16
.40
.58
.72
.96
0.906-1.077
0.
0.
0.
0.
0.
1.
1.
1.
000
921
929
964
987
022
045
049
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 20:41 10/21/97


-------
 Page No.
 10/21/97
Listing  of O973262B.dbf
Hatched  GC Peaks / Ratio /
Rat. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Hi
                                                                   fama..  ID.. Flags.


340-342
13C12-P8CDF
352-354








352-354

PeCDD
356-358









356-358
13C12-PeCDD
368-370










368-370
HxCDF
374-376



DC
DC


DC
DC

DC

DC


DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC


DC
DC
DC
DC


DC
DC
DC
DC
SN
WH
0

NL°
SN

SN

SN


SN
4


NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL
SN
SN
SN
SN


SN
SN
SN
SN
2

ML
SN
SN
SN
28:10
28:23
Peaks

0:00
25:10
25:20
25:54
26:18
26:29
26:38
27:06
27:32
Peaks


0:00
25:21
25:29
25:45
25:51
26:17
26:40
26:51
26:55
27:34
Peaks

0:00
26:29
26:50
27:06
27:15
27:29
27:39
27:49
28:03
28:23
28:31
Peaks

0:00
28:59
29:05
29:09
RO
RO
1
1
.19
.20
2
4
.39
.31
1
1
.071
.079
0.00
1.
RO
RO

RO

RO


RO


1.

RO
RO
RO
RO

RO

RO
RO

1.

RO
RO
RO
RO


RO
RO
RO


1.
RO
32-1.78
1
0
1
1
1
2
1
1
1


.13
.90
.39
.26
.46
.08
.38
.53
.26


32-1.78
1
0
0
0
3
1
2
1
0
0

.76
.83
.70
.90
.32
.38
.55
.53
.71
.42

1
1
56
16
3,215
20
35
3,047
11
6,355
.78
.83
.91 33.12
.75
.49 1,905.76
.63
.75 20.75
.45 1,843.61
.27
.60
0.848-1.152
0
0
23.79 0
0
1,309.73 1
1
15.00 1
1,203.84 1
1

.000
.957
.963
.985
.000 1
.007
.013
.030 1
.047



2
2
3
2
0
7
3
2
1
1
0
.18
.12
.92
.12
.97
.22
.52
.93
.51
.66
.00
32-1.78
1
1
2
2
0
1
1
2
3
2
1

.61
.24
.36
.82
.87
.54
.47
.62
.48
.65
.47
*!..»_ .
2
4
2
1
0
2,054
218
12
7
6
4
2,273
*»— r^rv
05-1.43
1
.50
1.18
RO
RO
2.22
0.39
2
1
1
0
.09
.31
.42
.56
.67
.64 1,247.07
.86 130.12
.98
.57
.40
.45
.50

.84
.66
.10
.99
0.921-1.025
0
0
0
0
0
0
0
0
0
1

.000
.922
.927
.937
.941
.956
.970
.977
.979
.003

0.855-1.145
0
0
0
0
0
807 . 57 1
88.74 1
1
1
1
1

.000
.964
.976
.986
.992
.000 i:
.006
.012
.021
.033
.038

0.958-1.051
0
0
0
0
.000
.958
.961
.964
                                                                               000 13C12-PeCDF 123 IS2
                                                                               007
                                                                               013
                                                                               030 13C12-PeCDF 234 SDR2
                                                                               000 13C12-PeCDD 123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:41 10/21/97

-------
 Page No.
 10/21/97
Listing of U973262B.dbf
Matched GC Peaks  / Ratio /  Ret. Time
 Compound/
 H_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.













374-376
13C12-HXCDF
384-386





384-386
HxCDD
390-392







390-392
13C12-HXCDD
402-404










402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC



DC



DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC




DC

DC
DC

SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL



SN

4

NL
SN
SN
SN
SN
SN
WH
WH
0

NL
SN
SN




SN

SN
SN
5
29:15
29:22
29:26
29:34
29:43
29:47
29:56
30:03
30:09
30:16
30:47
31:17
31:29
Peaks

0:00
30:09
30:15
30:47
30:57
31:31
Peaks

0:00
29:39
29:59
30:12
30:24
31:19
31:32
31:40
Peaks

0:00
30:10
30:22
30:54
30:59
31:09
31:18
31:29
31:32
31:39
31:45
Peaks
RO


RO
RO
RO
RO
RO

RO
RO
RO


0.
RO



RO

2
1
1
0
0
1
2
0
1
2
0
0
1

.75
.21
.38
.70
.55
.55
.19
.51
.07
.05
.96
.58
.21

1
1
1
0
2
0
2
1
5
2
4
1
1
0
.59
.57
.45
.83
.19
.65
.98
.08
.13
.22
.10
.03
.06
.00
43-0.59
0
0
0
0
0
0
.22
.51
.51
.52
.77
.49
11
2,165
2,517
1,979
8
1.623
.72
.97 727.27
.24 849.00
.95 676.70
.62
.54 533.41
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.

967
971
973
977
982
985
990
993
997 123478-HxCDF
001 123678-HxCDF
018 234678-HxCDF
034
041 123789-HxCDF









AN
AN
AN

AN

0.868-1.132
0.
1,438.70 0.
1,668.24 1.
1,303.25 1.
1.
1,090.13 1.
000
997 13C12-HXCDF 478
000 13C12-HXCDF 678
018 13C12-HXCDF 234
023
042 13C12-HXCDF 789

SUR3
IS4
ALT2

ALT1
8,286.70
1.
RO
RO
RO
RO
RO
RO
RO
RO

1.


RO


RO

RO

RO
RO

05-1.43
0
0
0
1
1
2
1
0

.76
.92
.51
.48
.68
.21
.03
.69

f w. fw*tus i «MvwA/is f W*A wna 	
1
1
0
4
2
1
3
0
0
.63
.25
.70
.97
.28
.05
.22
.92
.00
05-1.43
1
1
1
1
1
1
1
0
1
0
1

.09
.40
.69
.24
.24
.58
.21
.40
.08
.87
.64

3
3
7
1,721
2,035
34
2,080
8
34
11
11
5,906
.56
.07
.32
.79 954.16
.52 1.126.67
.88 24.61
.58 1,140.65
.13
.17 17.74
.00
.58
.94
0.952-1.015
0.
0.
0.
0.
0.
1.
1.
1.

000
957
968
975
981
Oil 123789-HxCDD
018
022






AN



0.968-1.032
0.
0.
0.
767.63 0.
908.85 1.
15.57 1.
939.93 1.
1.
16.43 1.
1.
1.

000
974
980
997 13C12 -HxCDD 478
000 13C12-HXCDD 678
005
010 13C12-HXCDD 789
016
018
022
025




SUR4
IS5

RS2





Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 20:41 10/21/97

-------
  Page No.
  10/21/97
Listing of U973262B.dbf
Matched 
-------
 Page No.
 10/21/97
Listing of U973262B.dbf
Hatched GC Peaks /  Ratio / Ret. Time
 Compound/
 M_Z.... QC.Log omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.
                                                                             ID.. Flags.
 442-444

 OCDD
 458-460
 458-460

 13C12-OCDD
 470-472

 470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC


DC


SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL
SN
SN
SN
0

NL

1
36:24
36:44
37:00
37:06
37:39
38:03
38:23
38:30
38:58
39:09
Peaks

0:00
36:17
36:31
36:48
Peaks

0:00
36:27
Peak
RO
RO
RO
RO
RO
RO
RO
RO

RO

0.
RO
RO
RO
RO

0.
RO


1.
0.
1.
1.
4.
0.
1.
0.
0.
0.

78
24
59
13
05
37
10
61
86
70

76-1.02
1.
1.
0.
0.

11
03
17
66

76-1.02
1.
0.

05
85

                                                3.27
                                                1.40
                                                3.65
                                                4.18
                                                1.46
                                                1.23
                                                3.55
                                                4.25
                                                6.00
                                                3.16
                                                0.00
                      2.21
                      1.76
                      1.57
                      2.72
                      0.00
                      1.95
                   3,166.63
                   3,166.63
                                                                                 0.999
                                                         008
                                                         ,015
                                                         ,018
                                                         ,033
                                                         .044
                                                         .053
                                                         .056
                                                         069
1,457.83
                                                       1.074
                   0.890-1.110
                       0.000
                       0.995
                       1.002
                       1.010
                   0.995-1.005
                       0.000
              1,708.80  1.000 13C12-OCDD
IS8
 Column Description	   "Why" Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Hass(es)
 ..RT. -Retention Tima (nm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
 *•* End of Report ***
       WL-Below Retention Tima Window
       HH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
File:U973262 #1-1024 Acg* 17-OCT-1997 20i33s28 OC EH- Voltage SIR 70S Noise: 853
303.9016 F:2 BSVB(256,30,-3.0) PKB(9, 5,3,0.10\,3412.0,1.00\,P,T) ExptEPCVS2
TRIASOLB LABS  Text:PBl-H23 TLI943432
        18'tOO         IS'tOO         20*00        21iOO         22:00        23:00
P±le*U973262 #1-1024 Acqt17-OCT-1997 20:33:28 OC EH- Voltage SIR 70S Soime*939
305.8987 Pi2 BSVB(256,30,-3.0) PXD(9,5,3,0.10*,3756.0,1.00*fP,T) ExptEPCUS2
TRIANQLX LABS  Text:PB1-X23 TLX943432
IOCS

 801
        18:00         19:00         20:00        21*00         22*00        23*00
PileiU973262 91-1024 Aog* 17-OCT-1997 20*33*28 OC XI* Voltage SIR 70S Hoife:707
315.9419 P:2 BSVB (256,30,-3.0) PXD(9, 5,3,0.10*,2828.0,1.00*,P,T) Exp:EPCUS2
TRIAHQLX LABS  Text:PB1-K23 TLI943432
lOOSi

   0.

   0.

   0.

   0.

   0.

rlle*U973262 91-1024 Acq* 17-OCT-1997 20*33*28 OC XI* Voltage SIR 70S Kolmet865
317.9389 P:2 B3UB(256,30,-3.0) PXD(9,5,3,0.10*,3460.0,1.00*,P,T) Sxp:EPCU32
TRIAHOLX LABS  Text:PBl-H23 TLI943432
lOOh
                                                                                         24 tOO
Al.





'l8:00 ' ' ' 19*00 ' ' ' 20*00 ' ' ' 21*: 00
2B7
••



V ,
22:00 '23*00 24*00
-2.1X6-
.1.7X6
.1.3X6
.8.4X5
.4.2X5
0.0X0
Time
X1.4QE7
A
1


H
18<00 15(00 20(00 21(00 22(00 23:00 24*00
.2.6B6
'.2.1S6
.1.5X6
-.1.0X6
-.5.2X5
'• o. oxo
Time
Plle:U973262  91-1024 Acy* 17-OCT-1997 20*33*28 OC EH- Voltage SIR 70S
330.9792 P*2  Exp:BPCUS2
TRIAHOLB LABS  Text:PB1-K23 TLX143432
IOC
   ffi1^^^
  601

  401

  201

   01
                 21*35
                           22*22  22*52
                                                23*52
           -1.5X7

           .1.2X7

           -9.1B6

           .6.1X6

           .3. OSS
        18:00         19*00         20*00        21*00         22*00
Plle:U973262 91-1024 Acq* 17-OCT-1997 20*33*28 OC SH- Voltage SIR 70S
375.8364  P*2 Sxp*SPCUS2
TRIAHOLB  LABS  TexCtFB1-M23 TLI943432
100H
                                                                           23*00
                                                 24*00
                                                        .0.0X0
                                                            Time
  801

  601

  401

  201

   0.
                                                                     22*33 22*58
           18*13
20*20
   23149
23*351
        10(00
                      19*00
                                   20*00
                                                21:00
                                                              22*00
                                                                           23 tOO
                                                                                         24*00
-2.7X4

.2.1X4

.1.6X4

.1.1X4

.5.3X3

 0.0X0
    Time

-------
Plle*a973262 01-1024 Acqtl7-OCT-1997 20*33:28 OC Elf Voltage SIS  70S Noise:705
319.8965 P*3 BSOB(256,30,-3.0)  PKD(7,5,3,0.10\,2820.0,1.00*,P,T)  Exp:EPCUS2
TRIANOLX LABS  TexttPBl-M23  TLI043432
lOOS
                                                                                                        /'
-------
PilaiU973262 #1-1024 Acqtl7-OCT-1997 20t33t28 QC EI+ Voltage SIR  703 Ko±amt636
339.8597 P*2 BSUB(256, 30,-3.0) PXD(7,5,3,0.10*,2544.0,1.00*,P,T)  ExpiBPCUS2
TRIANOLB LABS  ToxtiFBl-M33 TLIK43432
    24*00              25*00             26:00              27*00              20*00
PlleiU973262 91-1024 Aaqil7-OCT-1997 20*33*2* OC EH-  Voltage SIR 70S Noil*1719
341.8567 Pt2 BSUB(2S6,30,-3.0)  WtDf7,5,3,0.10*,207tf.O,1.00%,F,S1;  SxpiEPCffS2
TRIAHOLB LABS  Text t PB1-H23  TLI043432
ion
 00:
     24:00              25(00             26iOO              27*00              20(00
Pil»:U973262 01-1024 Aaj: 17-OCT-1997 20*33*2* OC JET* Voltage SIR 70S Boime*541
351.9000 Pt2 BSUB(256,30,-3.0)  PKD<7,5,3,0.1091,2164.0,1.00t,P,T)  Exp:BPCUS2
TRUOfOLE LABS  Text > PB1-M23  TLX043432
iom
 sol
 60:
 40:
 20:
                                                                                                 0.050
                                                                                                    Timu
                                                                           A3.24S4
                                                                    A1.47S4  I A1.68E4
  oj
                                  C5.786
                                  .4.SS6
                                  .3.4E6
                                  '.2.3SS
                                  '.1.1S6
                                  O.OSO
     24:00              25*00              26tOO              27*00              20*00
Pil»:U973262  01-1024 Aoqt17-OCT-1997 20*33*2* OC BI+ Voltage SIR 70S Holme:481
353.8970 Pt2  BSUB(256,30,-3.0)  PXD(7,5,3,0.10*,1324.0,1.00*,P,T) SxptXPCOS2
TRIANOLS LABS  Text >PB1-H23 TLI043432
 1009
  80:
  ffOj
  401
  20.
   0:
A.1.20E7
-3.9B6
-3.1B6
.2.4S6
.1.6S6
.7. 8S5
     24iOO              25*00              26tOO              27*00
Pil»:U9732S2  91-1024 Acqtl7-OCT-1997 20*33*2* OC 5X4- Voltafff SIR 70S
330.9792 Pl2  Sxp:EPCUS2
TRIANQLE LABS  Text:PB1-M23 TLXX43432

  00:
  60:
  40:
  20.
   o:
                                                                                28100
                                   .O.OSO
                                      Tlm»
                                  -1.3S7
                                  -1.0S7
                                  _7. 7S6
                                  -5.2S6
                                  -2.6S6
     24*00              25*00              26iOO              27*00
Pll»:U9732S2  §1-1024 Acqtl7-CCT-1997 20i33i2* OC XT* Voltage SIR 70S
409.7974 Pi2  fxp:XPCU32
TRIAKOLS LABS  Text:PB1-M23 TLIt43432
                                25:26
                  28 tOO
 O.OSO
    Tlam
     24100
                        25100
                                           26 tOO
                                                             27*00

-------
 '110IU9732S2 91-1024 Acqt17-OCT-1997 2QI33S2B OC EI+ VOltaga SIR 70S NO18»:696
355.8546 Pt3 BSUB(256,30,-3.0) PKD(5,5,3.0.0S*,2784.0,1.00*,P,T) ExptEPCUS2
TRIANGLE LABS  TuxttPBl-U23  TLX#43432
loo*
                     26tOO                         27tOO                        28tOO
Pll»iU973262 #1-1024 Aaqt 17-OCT-1997 20t33t28 PBl-H23 TLX143432
100H                                                             A8 OSES
  80.

  60.

  40.

  20.

   0.
8.B7E5
                      26iOO                        27iOO
Pil»tU973262 tl-1024 Acqil7-OCT-1997 20:33t28 OC SIf Voltage SIR 70S
330.9792 Ft2 BxptEPCU32
TRIANOLB LABS  Tuct:PBl-H23 TLX«43432

     ^^^^\* ^^^     Af^ ^k A         ^JT     AA /V*v   AA       *       ?** •

  80.


  60.


  40.


  20.


   0.
           28:00
                      26:00
                                                                                 28100
                              .3.8E6


                              .3.0B6

                              .2.3S6

                              .1.5S6

                              .7.5S5
                                                                                                     O.OEO
                                                                                                        Time
 2.4E6

.1.9B6

.1.4E6

'.9.6S5

 4.8E5

 O.OEO
                               1.3S7

                              '.1.087

                              ".7.7S6

                              '.S.1S6

                              "2.6S6
                              '.O.OEO
                                  Time

-------
Pile:V9732€2 #1-405 Aey:17-OCT-1997 20:33:28 OC Eli- Voltage SIR 70S Nolse:953
373.8208 Pi3 BSUB(256,30, -3.0) PXD(7,5,3,0.10X,3812.0,1.00*,P,T) Exp:BPCU32
TRIANOLE LABS  T«Xt:FBl-M23 TLI943432
100*
   29100                        30:00                       31:00
Pile:U973262 91-405 Aeg:17-OCT-1997 20:33:28 OC SH- Voltage SIR 703 Holse:636
375.0178 P:3 BSUB (256,30,-3.0) PKD(7,5,3,0.10*,2S44.0,1.00\,P,T) Exp:EPCUS2
TRIAKOLB LABS  Text:PBl-M23 TLI943432
100*
                                                    A6.77S6
   29:00                        30:00                       31:00
File:U973262 91-405 Jicqi 17-OCT-1997 20:33:28 OC EI+ Voltaff* SIS 703 Noit»tl978
383.8639 P:3 BSUB(256,30,-3.0) PKD(7,S,3,0.im,7912.0,1.00*,P,T) Bxp:EPCU32
TRIAKOLS LABS  TfXt:PB1-M23 TLI*43432
IOCS
 80:

 sol

 40:

 aol

   o.
                                                                                       32:00
                                                                                        32:00
                                                                         J&.33B6
   29100                       30:00                       31:00
Pil»tU9732S2 91-405 Icqt 17-OCT-1997 20:33:28 OC SH- Voltagf SIR 70S Soim91Sl
385.8610 F:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10*,36604.0,1.00*,P,T) Exp:EPCU32
TRIANOLB LABS  TfXtiFBl-H23 TLI943432
                                                                                        32 tOO
 8S6

 3S6

 7S6

 1S6

 6S5

.OBO
  Tim*
 1009

  80:

  sol

  40:

  20:

   o:
                                          7X7
                                                    A1.30S7
                                                                         A1.09B7
   29:00                        30:00                       31:00
Pil»iU973262 91-405 lcq:17-OCT-1997 20:33:28 OC SH- Voltmff* 3IR 70S
392.9760 F:3 Exp:EPCUS2
TRIANGLE IAB3  T»Xt iFB1-M23 TLI943432
                                                                                        32:00
 ion
  80:
  60:
  40:
  20:
   o.
      29t07       '        39tSO          '         30'*3            A       11, 75 31,^*      r
    J^^r^M^^^^^^
                a9'38      39tSO
                                        30'17
   29:00                        30:00                       31:00
P11»:U973262 91-405 Acy:17-OCT-1997 20:33:28 OC JET* Voltage SIR  703
445.7555 P:3 Exp:EPCUS2
TRIAKOLS LABS  Text:PB1-K23 TLI943432
100*
                                                                                        32:00
 7B6

 6B6

 4S6

 3B6

 IBS

.OBO
  Time



.8B6

.4E6

.1S6

.7B6

.436

.OBO
  Time
   29:00
                                30:00
                                                            31:00
                                                                                        32:00

-------
 
-------
Fil»sU973262 #1-596 Acqsl7-OCT-lS97 20t33i28 OC El*  Voltaya SIX 70S Noisai789
407.7818 Fit BSUB(256,30,-3.0) PJO3(7, 5,3, 0.10*, 3156. 0,1.00*,P,T) Xxp,EPCUS2
 •RIANOLB LABS  Text IPB1-M23 TLI943432
loan
       33', 00    33112     33:24     33,36    33,48     34,00    34,12     34,24
Pil»iU973262 91-596 Acqsl7-OCT-1997 20,33,28 OC BH-  Voltage SZH 705 Nolle,622
409.7789 P,4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*,2488.0,1.00*,P,T) XxptBPCUS2
TRIANGLE LABS  T*xC,PBl-H23 TLI943432
100H   A1.21B4
       33,00    33,12     33,24     33,36    33,48     34,00    34,12     34,24
Pll»,U973262 »l-59€ Acqil7-OCT-1997 20,33,28 OC SZ> Voltaffu SIS 703 Nol*»,1702
417.8253 Fi4 BSUB(256,30,-3.0) PKD(7,5,3,0.10*, 6808.0,1.00*,P,T) Kxp,BPCUS2
TRIANGLE LABS  TfXt,FB1-K23 TLH43432
                                                                                    34,36
                                                                                    34,36
ion
 sol
 fol
 40:
 20:
       A4.72E6
                                                                 A4.18E6
       33,00    33,12     33,24     33,36    33,48     34,00     34,12     34,24
Pll»,U973262  91-596 Acq,17-OCT-1997 20,33,28 OC BX+ Voltmfff SIR 70S Nolm»i2280
419.8230 Pi4  B3UB(2S6,30,-3.0)  PKD(7,5,3,0.10*,9120.0,1.00*,P,T) Xxp,BPCUS2   "'
TRIANQLE LABS T»xC tPB1-H23 TLHf43432
100H
  80:
  60:
  40:
  20:
                                                                  A9.66S6
       33,00     33,12     33,24     33,36    33,48     34,00     34,12
Pll»,U973262  f 1-596 Aogtl7-OCT-1997 20,33,28 OC SXf Voltagm SUt 70S
430.9729 Pi4  Exp,BPCUS2
TRIANGLE LABS  T*xC:PBl-M23  TLH43432
                                                33151
                                                                          34,24
1003
 flOJ
 ffflj
 40:
 20:
  OJ
      32,59
                 33112
                          33,24
       33,00     33tl2     33,24     33,36     33,48    34,00     34,12
Pllf,U973262  91-596 Acq,17-OCT-1997 20,33,28 OC Sit- Volt»g» SIR 70S
479.7165 Pi4  Bxp,SPCVS2
TRIANOLS LABS  T*xClPBl-lt23  TLH43432
loan
                                                                          34,24
  80:
  60:
  4 a:
  20:
   0:
                 33/13
     32(50
                           33,26
                                        33141
                                                                      34,20
       33(00
                 33(12
                          33,24'
                                    33,36
                                              33,48
                                                       34i60'
                                                                 34112
                                                                                    34,36
                                                                                    34,36
                                                                                   34,36
                                                                                      34,40
i i  I  i i
 34,36
                                                                                               .0. OBO
                                                                                                   Tim»
             1.8B6
             1.4E6
             .1.1S6
             7.2*5
             3.6B5
             .0.050
                Tim*

             .4.2E6
             .3.4B6
             .2.5S6
             .1.7B6
             .8.5BS
             .0.0X0
                Tin*
             4.1S6
            .3.3X6
            '•.2.5X6
            11.7X6
            :8.3X5
             0.0X0
            -3.0B4
            .2.4X4
            .1.8X4
            .1.2X4
            .6.1X3
0.0X0
   Mm*

-------
fil»:U9732S2 M-5S6 Acq: 17-OCf-i997 20,33,28 OC BT* Voltage SIR 70S tbis»tS51
433.7766 Fit BSUB(256,30,-3.0) PKD(7, 5,3,0.10\,2204.0,1.00*,Z,T) BxpiXPCOS2
THZANOLE LABS  TfXt,PBl-M23 TLI1t43432
                                                          A2.J.7E4
          A1.24E4
      33il2   33'tlB   33:24  33,30   33,36  33,42   33:48  33:54   34:00  34:06
Pll»,U973262 #1-596 Acq,17-OCT-1997 20:33:28  OC XX+  Voltagt SIR  703 Solm»:416
425.7737 Ft4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10*,1664.0,1.00*,P,T)  X3tp,XPCVS2
TRIANOLB LABS  TfXttPBl-M23 TLX#43432
lOOSt
  80.
                                                                                34:12   34:18  34:24   Tia»
                                                                                                   .6.2E3
                                                                                                    .4.9S3
      33:12  33:18   33:24   33:30   33:36  33l42   33:48  33:54   34:00  34:06   34:12
P11»:U973262 «l-596 Atojt 17-OCT-1997 20:33:28 OC BH- Voltage SIR 70S So±au:1744
435.8169 Fi4 BSUB(256,30,-3.0)  PKD(7,5,3,0.10*,6976.0,1.00*,P,T) BxptSPCUS2
TRUUfOLB LABS  T»Xt:PBl-M23 TLIV43432
lOOH                                                     A9.55S6
  80.


  60.


  40.

  30.
                                                                                                    LO.OEO
                                                                                        '34lie '  34124   Mae
                                                                                                   .3.7S6

                                                                                                    .2.9E6


                                                                                                    J.2S6


                                                                                                    .1.5S6


                                                                                                    .7.3B5
                                                                                                     O.OBO
     33:12   33:18   33:24  33,30   33:36  33,42   33,48  33,54  34,00   34,06   34:13
P11»:U973262 fl-5S6 Acy:17-OCT-1997 20,33,28 QC EH- Voltafff SIS 70S Hoia»ti619
437.8140 Pit B3UB(256,30,-3.0) PKD(7,5,3,0.10*,6476.0,1.00\,P,T) Xxp,XPCOS2
TRIANOLB LABS  T»xt:PBl-M23 TLIS43432
                                                         A9.47S6
  80.

  60.


  40.

  20.
                                                                                        34:18  34.124   Man
                                                                                                   .3.SE6


                                                                                                   .2.8B6

                                                                                                   .2.1E6


                                                                                                   .1.4E6


                                                                                                   '.7.0B5
     33:12   33:18   33:24  33:30   33:36  33:42   33:48
Pil»iO973362 tl-596 Acqt 17-OCT-1997 20:33:28 OC EH-
430.9729 Pi 4 Sxp:SPCU32
TRIANGLX LABS  T«urC>FBl-M33 TLIt43432
lOOSi 33tl2   33,111  33t24   it, in      .     .         33t51
                                                                                                     O.OBO
                                                           33:54   34:00
                                                             SIR 70S
34:06   34:13  34x10   34:24  Tim*
  80.

  60.


  40.

  30.


   0.
              33:18
                             33:30..
                                                                            34:08
                                                                                            34,21
                                                                                                    .3.2B6


                                                                                                    .2.4X6


                                                                                                    .1.6X6


                                                                                                    .8. OSS
                                                                                                     0.0X0
      33:12   33:18  33:24   33:30  33:36   33:42  33t4B   33:54  34:00  34:06  34:12   34:18  34^24   Timu

-------
 '±10:0973262 #1-596 Acq: 17-OCT-19S7 20:33:28 OC EH-  Voltaffa SIR  70S Nolaa:728
441.7438 Pi4 BSUB(256,30,-3.0) PXB(7,5,3,0.10X,2912.0,1.00*,P,T) ExptEPCUS2
TRIANGLE LABS  ToxttFBl-M23 TLI*43432
100*
                                            A2.99E4       A2.41B4
         33*00       34:00       35.00      36:00       37:00       36:00
Pll»tO973262 #1-596 Acqt 17-OCT-1997 20:33:28 OC SH- Voltaym SIR 70S Nola»:770
443.7399 Pt4 BSUB(2S6,30,-3.0) PKD(7,S,3,0.10X,30BO.O,1.00*tP,T)  ExptEPCU32
TRIANOLE LASS  TutttPBl-lOS TLH43432
                       A2.29E4
                                  A2.19E4
                              A1.0SE4
                             .S8E
                                                                                39100
         33tOO       34:00       35:00       36:00      37:00       38:00
Pll»:U973262 #1-596 Acq: 17-OC7-1997 20:33:28 OC Eli- Voltage SIR 70S
430.9729 Pt4 Exp:EPCUS2
TRIANGLE LABS  TmxttPBl-M23 TLIt43432
                                          35f44  ig,n      37tl4
                                                                                39 tOO
         33lOO       34:00       35:00       36tOO      37': 00
Pll»tU973262 #1-596 Acq: 17-OCT-1997 20:33:28 OC EH- Voltaff* SIR 70S
513.677S Pt4 ExptSPCUS2
TRIANOLE LABS  Tf3rttPBl-M23 TLH43432
33:00
            39 tOO
         33 tOO
                     34:00
                                 35:00
                                             36:00
                                                         37:00
                                                                    38:00
                                                                                39 tOO

-------
?ila:l}373262 91-596 Acq: 17-OCT-1997 20:33:28 OC EH- Voltay a SIR 70S Soia»>649
457.7377 P*4 BSVB(256,30,-3.0) PXD(7,5,3,0.10*,2596.0,1.00X,P,T) E3cp*BPCUS2
TRIANGLE LABS  Tf3CtiPBl-M23 TLI043432
100H                     A3.30E4
    36:18          36*24          36*30         36*36         36*42         36i4B
Pll»*U973262 tl-596 Acytl7-OCT-1997 20t33t2B OC EH- Voltage SIS 70S Noise,583
4S9.7348 Pt4 B3UB(2S6,30,-3.0) PXD(7,5,3,0.10*,2332.0,1.00*,P,T) Exp,EPCUS2
TRIAHOLB LABS  T»Xt,FBl-H23 TLZ#43432
100H                                A4.46B4
    36tlB          3fi24         36t30         36t36         36i42          36i4B
Pil»>U973262  f 1-596 Acytl7-OCT-1997 20l33t28 OC EH- Voltafff SIX 703 Noim»t539
469.7779 Pt4  BSUB(256,30,-3.0) PKD(7,5,3,0.10*,2156.0,1.00*,F,r) SxptEPCUSS
TRIANOLB LABS T*3tt tPB1-M23  TLIt43432
100H                    A1.46S7
                                             .'.*'
    36tl8          36,24         36i30         36t36         36*42         -36t48
P±lftO973262 tl-596 Actjt 17-OCT-1997 20t33t28 OC BI+ Voltagf SIR  70S Soimmi'515 .
471.7750 Pl4 BSUB(256,30,-3.0)  PXD(7,5,3,0.10*,2060.0,1.00*,P,T) SxptBPCU32
TBIAKOLS LABS  Tnct tPB1-H23  TLI#43432
100H                    A1.J1S7
  BO!
  60.
  40.
  20.
    36,18          36,24         36,30         36,36         36,42
Pil»iU973262 tl-596 Acqil7-OCT-1997 20i33t28 OC SH- Voltagm SIR  70S
430.9729 Pi4 SxpiBPCUS2
TRIAKOUS LABS  T»xtiPBl-M23 TLIt43432
        36*20
                                           36l48
                                                                                          36*54
  BO.

  60.

  40.

  20.

   0.
     36*18
                   '36*24
'36*30
'36*36
                                                             36*42
'36\4B
                                                                                          36,54
                                                                                          36,54
                                                         36*54
                                                                                       36*53
i  I   i
36,54
                                                                   .0.050
                                                                      Tim*
                                                                   .4.7S6

                                                                   .3.'7Bg

                                                                   .3.8S6

                                                                   .1.9E6

                                                                   .9.3X5

                                                                   .O.OSO
                                                                       Vim*



                                                                    S.5S6

                                                                   .4.4E6

                                                                   .3.3B6

                                                                   .2.2B6

                                                                   .1.1E6

                                                                    O.OSO
                                                                   r4.4S6

                                                                   .3.5BS

                                                                   .2. TBS

                                                                   .l.BSS

                                                                   .8. BBS
O.OSO
   tta*

-------
Peak Locate Examination:17-OCT-1997:20:32 File:U973262

-------
File:U973262 ttl-596 Acq:17-OCT-1997 20:33:28 GC EH- Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:PBl-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100i.34f45
                                          36:27
 80J
 60J
 40J
 20J
35:39   36:00
                                           29
                                                           38:21
          35:00                 36:00                 37:00
File:U973262 #1-596 Acq:17-OCT-1997 20:33:28 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:FBl-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
10 0*
                   35:26                  36:2(7   36:48
    34:44             -----            . I
 60 j
 40 j
 20 j
                                                                           38:00
                                                                                  38:17
          35:00                 36:00                 37:00
File:U973262 #1-596 Acg:17-OCT-1997  20:33:28 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:FBl-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                                      36;27
 80J
 60 j
 40J
 20J
                                                   38:00
                                   _2 . 9E4
                                   _2.3E4
                                   _1.8E4
                                   _1.2E4
                                   _5.9E3
                                                                  O.OEO
                                                                    Time
                                    .2. 6E4
                                    2. 1E4
                                    .1.6E4
                                    1. 1E4
                                    .5.3E3
                                    .O.OEO
                                       Time
          35:00
        36:00
37:00
                                                                           38:00
4.7E6
3.7E6
2.8E6
1.9E6
9.3E5
.O.OEO

-------
.. > '« ^ .. '"f \
s
™>; * \/. T > «/-jv *""•;'««
* "*T**»*-&*J6;
"^ ,\,^ 0 v\^^«W«*f*
TLI Project:
Client Sample
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
43432
: FB2-M23
Saginaw, MI
M23TRAIN
185-6-6A-C

1.000
n/a
DB-5
> *^>5^\ v ^ - -5S ^ * "^^^fe-
% A* Xvi f. A\. V, •, _. ^^ VX5S&
• Fri^rjrnnrri^rt fai Qp
K^l^a^ij«Miine^»ai\*3^
$£&•'$$& K<* ^ " "$>" \ ""x"-' ' " ;

^^f^^^ V55'*"* ' ,' \-^^ ov'\M...*i.*..*....\.r.
Method 23 PCDD/PCDF Analysis (a)


Date Received: 09/29/97
Date Extracted: 10/09/97
Date Analyzed: 10/17/97
Dilution Factor: n/a
Blank File: U973257
Analyst: BB
Analysis File: U973263

Spike File: SPX23704
ICal: UF59167
ConCal: U973252
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

AhaJytes v "* \ \*

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
U,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
,,- , -- ; -, ^ ^ '^'-^^4jn
^ *^ % .. % ,vJ^ . ....... s »% «
ND
ND
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
j^T-i '^"l&V ^\^JsMNM§
"••? , fV. ,^^**v» ^ i»^ •., '• < &?
0.006
0.008
0.01
0.009
0.009
0.01
0.01
0.03
0.007
0.006
0.007
0.005
0.006
0.007
0.008
0.01
0.01
tf^^^^f^jipC;^^!^, "xs-l-^feHte " -
v^ % ff£ \"':. ' '' •.%?• •• ™. * ° .?^% **^





	
	

	


	


	
	
	
Totals ^ , j^ps ^V*IM'^Y^ *
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
EMPC
ND
ND
ND
0.006
0.008
0.01
0.01
0.03
0.006
0.006
0.009



	



	
                                                   Page 1 Of 2
X2I7.PSR V2.00, LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:


-------
                                                                   x »sV*1 v ***ur^?l
TLI Project:      43432
Client Sample:   FB2-M23
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U973263
Internist Standards ••''••
13C,2-2,3,7,8-TCDF
13Ci2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
% %Amf» CBS&^S
3.2
3.6
3.5
4.0
4.1
4.0
3.3
3.8
7.6
r'v%R»c«v»fv
78.9
90.2
87.5
100
102
101
82.1
94.8
95.1
->;acum|S^
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
\ Ratio*
0.78
0.79
1.48
1.44
0.50
1.18
0.43
1.01
0.90
JBT: ,-; flags. ,>;
21:32 	
22:27 	
26:16 	
27:27 	
30:14 	
30:58 	
33:01 	
33:53 	
36:26 	
$«rr<*g^Sta^ante^
37Cl.-2,3,7,8-TCDD
1JCir2,3A7,8-PeCDF
'3C,2-l,2,3,4,7,8-HxCDF
I3C,2-l,2,3,4,7,8-HxCDD
t3C,2-l,2,3,4,7,8,9-HpCDF
3.6
3.8
3.8
4.0
3.5
89.0
94.4
95.3
99.6
88.0
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%

1.53
0.51
1.21
0.41
22:28 	
27:05 	
30:07 	
30:53 	
34:14 	
^Mtei^S&rida^^^^
13C,2-l,2,3,7,8,9-HxCDF
13C.2-2,3A6,7,8-HxCDF
Recovery Standards i: ,\r;
13C12-1,2,3,4-TCDD
'3C,2-l,2,3,7,8,9-HxCDD
3.7
4.2
* "V- % ^V s -X Ms >
*% •• •••••>•• •* s*** •• ~-\


93.3
104
w *••"•••' '* V *fyk : :: ""> "~ •!"
•.fjf... jf\ \ %V %^.


40%-130%
40%-130%
V>' ^5|f£


0.49
0.50
!;, Ratio--' \;
\
0.83
1.18
31:30 	
30:46 	
^RT^f^lagsV
22:13 	
31:16 	
                     Data Reviewer
                                        Page 2 of 2
            10/23/97
                          X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
                         Initial
                                   ---- Date. . .
 Data Review By:
                                            .
                                              •
                  n 't      •
                  J_i_/ _ / _
                                               Calculated Noise Area:
                                                                        2.00
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/23/97
         Listing of  O973263B.dbf
         Matched GC  Peaks / Ratio / Ret. Time
 Compound/
 H_Z	 QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
TCDF
304-306 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
K
DC
DC
DC
304-306
13C12-TCDF
316-318 DC
DC
DC
DC
DC
DC
DC

DC
DC
DC
DC
DC
DC
DC
316-318

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN

SN
SN
SN
1

NL
WL
ML
WL
WL
WL
WL

SN
SN
SN
SN
WH
WH
WH
1

0:00
17:40
17:46
18:11
18:51
19:28
19:46
20:11
20:26
20:39
20:46
21:03
21:34
22:05
23:10
23:39
Peak

0:00
17:55
19:14
19:43
19:55
20:09
20:31
21:32
21:48
22:06
22:19
22:27
23:00
23:15
23:48
Peak
0.


RO
RO



RO

RO
RO
RO
RO
RO
RO


0.
RO
RO
RO
RO
RO

RO


RO
RO
RO
RO
RO


65-0.89
0
0
0
1
0
0
0
0
0
0
0
.79
.72
.14
.17
.87
.75
.87
.60
.76
.44
.24
0.22
0
.94
0.47
0
0

.27
.87

2
5
0
2
18
3
16
9
3
2
1
3
21
8
0
3
21
.76
.36
.37
.57
.24
.60
.70
.06
.70
.71
.38
.47
.47
.74
.74
.82
.47
65-0.89
1
1
1
0
1
0
0
0
0
0
1
1
1
0
0

.06
.01
.94
.29
.36
.67
.48
.78
.81
.96
.31
.45
.51
.44
.78
	 lV»/r
1
3
1
1
2
46
4
3,180
7
22
7
7
6
3
4
3,180
tTA . TTff
.38
.01
.66
.17
.05
.27
.14
.34
.09
.37
.54
.49
.57
.54
.70
.34
p /
                                                                             0.813-1.106
                                                                                 0.000
                                                                                 0.820
                                                                                 0.825
                                                                                 0.844
                                                                                 0.875
                                                                                 0.904
                                                                                 0.918
                                                                                 0.937
                                                                                 0.949
                                                                                 0.959
                                                                                 0.964
                                                                                 0.978
                                                             11.44
                                                                          12.13
                                                                                  .002 2378-TCDF
                                                                                  .026
                                                                                  .076
                                                                                                      AN
                                                          1,391.79
                                                                                 1.098
                                                            0.954-1.046
                                                                0.000
                                                                0.832
                                                                0.893
                                                                0.916
                                                                0.925
                                                                0.936
                                                                0.953
                                                       1,788.55  1.000 13C12-2378-TCDF ISO
                                                                1.012
                                                                1.026
                                                                1.036
                                                                1.043
                                                                1.068
                                                                1.080
                                                                1.105
                                                     TCDD Follows
 TCDD
 320-322
               0.65-0.89
DC  NL   0:00 RO  0.99
DC  SN  19:36 RO  7.53
DC  SN  21:59     0.89
DC  SN  22:10 RO  0.93
                                                1.43
                                                0.53
                                                1.55
                                                5.50
0.848-1.061
    0.000
    0.873
    0.979
    0.987
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
 Page No.
 10/23/97
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.




320-322
37C1-TCDD
328












328
13C12-TCDD
332-334











332-334
PeCDF
340-342











DC
DC
DC
DC

SN
SN
SN
WH
0
22:30
22:51
22:58
23:56
Peaks
RO
RO
RO
RO

0
1
0
1

.56
.42
.44
.80

5
1
0
1
0
.31
.47
.71
.54
.00
1.
1.
1.
1.

002
018
023
066

0.911-1.089
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC



DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
ML
WL


SN
SN
SN
SN
SN
SN
SN
SN
2

NL
HL
SN



SN
SN
SN
SN
SN
SN
3

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
19:12
19:54
20:43
22:28
22:51
22:59
23:12
23:19
23:26
23:33
23:56
24:11
Peaks

0:00
19:31
20:56
22:13
22:27
22:51
22:59
23:08
23:37
23:46
24:03
24:15
Peaks

0:00
23:48
23:57
24:29
25:06
25:16
25:30
25:40
25:46
26:09
26:17
26:30














0.
RO
RO
RO


RO
RO

RO
RO
RO
RO

1.
RO
RO
RO
RO
RO
RO

RO
RO
RO
RO
RO


















• 2








2
0
2
0
54
.435
7
5
5
2
6
6
4
2
,489
.76
.18
.92
.32 54.32
.30 2,435.30
.18
.77
.43
.54
.43
.69
.86
.72
.62
65-0.89
2
1
1
0
0
1
0
0
1
0
0
0

.49
.35
.44
.83 2
.79 2
.07
.63
.79
.24
.53
.58
.38
5
32-1.78
0
0
0
1
2
1
1
3
0
0
3
2
.84
.64
.95
.25
.62
.02
.38
.30
.57
.66
.09
.85
1
2
14
,898
,900
48
12
8
4
7
6
6
.45
.50
.96
.12 1,311.33
.22 1,277.31
.78 29.44
.18
.84
.46
.01
.76
.02
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.

000
855
886
923
001 37C1-TCDD SUR1
018
024
033
039
044
049
066
077

0.911-1.089
0.
0.
0.
1,586.79 0.
1,622.91 1.
27.56 1.
1.
1.
1.
1.
1.
1.
000
869
932
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
018
024
030
052
059
071
080
,847.12
TCDD / PftCDF Poll ows — —

i
i
5
1
3
12
6
1
0
1
1
1
.04
.65
.28
.74
.42
.17
.20
.63
.99
.55
.89
.56
0.906-1.077
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
906
912
932
956
962
971
977
981
996
001 12378-PeCDF AN
009
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 23:43 10/23/97

-------
 Page No.
 10/23/97
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z	 QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.l..  Area.Peak.2..  Rel.RT Confound.Name..  ID.. Flags.











340-342
13C12-PeCDF
352-354







352-354

PeCDD
356-358











356-358
13C12-PeCDD
368-370









DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC

DC

DC

DC
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC


DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0

ML

SN

SN

SN
SN
3


NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0

NL
SN
SN
SN
SN
SN


SN
SN
26:44
26:50
27:04
27:15
27:27
27:47
27:57
28:01
28:12
28:32
28:45
Peaks

0:00
25:17
25:52
26:16
26:36
27:05
27:20
28:07
Peaks


0:00
25:35
26:17
26:21
26:31
26:40
26:43
27:10
27:22
27:54
28:05
28:27
Peaks

0:00
25:31
25:42
26:24
26:34
27:14
27:27
27:38
27:52
28:00
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO

1.
RO

RO

RO

RO



1.
RO

RO
RO
RO
RO

RO

RO
RO
RO

1.
RO
RO

RO
RO
RO


RO
RO
0.
0.
0.
0.
1.
1.
1.
11.
1.
0.
0.

39
25
55
18
11
22
18
19
48
91
58

0
0
4
1
1
1
1
0
0
1
1
0
.74
.66
.08
.17
.37
.53
.74
.41
.77
.41
.65
.00
32-1.78
1.
1.
2.
1.
0.
1.
2.
1.


00
65
20
48
98
53
86
73


32-1.78
1.
1.
0.
0.
0.
4.
1.
0.
1.
0.
0.
0.

10
33
67
55
64
86
34
99
46
97
68
53

1
63
13
2,774
22
2.540
3
11
5,378
.30
.39 39.48
.80
.19 1.654.48
.57
.82 1.534.67
.29
.37
.40
1
1
1
1
1
1
1
1
1
1
1
'
.018
.022
.030 23478-PeCDF AN
.037
.045
.058
.064
.067
.074
.086
.095

0.848-1.152
0
23.91 0
0
1,119.71 1
1
1,006.15 1
1
1

.000
.963
.985
.000 13C12-PeCDF 123 IS2
.013
.031 13C12-PeCDF 234 SUR2
.041
.070

PoCDF / PfeCDD Follows —

i
i
2
1
2
1
1
1
1
1
0
1
0
.28
.61
.52
.27
.07
.45
.59
.63
.18
.04
.89
.17
.00
32-1.78
0.
2.
1.
2.
1.
0.
1.
1.
1.
0.
74
47
46
19
31
63
44
59
25
91
0
0
1
2
2
1
1.744
175
4
4
.97
.97
.99
.88
.53
.23
.52 1.030.41
.78 107.86
.87
.98
0.921-1.025
0
0
0
0
0
0
0
0
0
1
1
1

.000
.932
.957
.960
.966
.971
.973
.990
.997
.016
.023
.036

0.855-1.145
0
0
0
0
0
0
714.11 1
67.92 1
1
1
.000
.930
.936
.962
.968
.992
.000 13C12-PeCDD 123 IS3
.007
.015
.020
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 23:43 10/23/97

-------
 Page No.     4
 10/23/97


 Compound/
 M_2.... QC.Log Omit Why
Listing of U973263B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID..  Flags.


368-370
HxCDF
374-376









374-376
13C12-HXCDF
384-386












384-386

HxCDD
390-392












390-392
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC


DC
DC

DC

DC
DC
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

SN
SN
2

NL
SN
SN
SN
SN
SN
SN
WH
WH
WH
0

NL
SN
SN


SN
SN

SN

SN
SN
SN
4


NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
28:16
28:34
Peaks

0:00
29:15
29:34
30:41
30:47
30:53
31:37
31:57
32:02
32:08
Peaks

0:00
29:05
29:13
30:07
30:14
30:23
30:35
30:46
31:01
31:30
31:40
31:44
31:57
Peaks


0:00
29:31
29:33
29:37
29:47
30:08
30:14
30:36
30:45
30:54
31:17
31:28
31:33
Peaks
RO
RO

1.
RO
RO
RO



RO
RO
RO
RO

0.
RO




RO
RO

RO


RO
RO


1.

RO

RO
RO

RO
RO
RO
RO
RO
RO
RO

1
0

.00
.67

05-1.43
0
0
0
1
1
1
0
5
0
0

.97
.81
.51
.25
.11
.17
.57
.19
.92
.89

8
4
.19
.13
1
1
.030
.041


1,920.30

2
3
0
1
6
2
0
0
0
1
0
.33
.63
.74
.89
.52
.47
.58
.36
.87
.12
.00
43-0.59
1
0
0
0
0
0
0
0
3
0
0
2
7


.51
.50
.51
.51
.50
.30
.09
.50
.73
.49
.53
.05
.14


05-1.43
1
0
1
0
0
1
0
0
1
0
1
3
0

.20
.56
.41
.62
.55
.25
.92
.82
.02
.62
.65
.54
.70

3
10
25
2,283
2.459
20
7
2,359
6
1,997
17
8
1
9,099
.16
.55
.56
.17 769.43
.91 817.06
.76
.79
.53 790.89
.90
.36 656.52
.78
.71
.19
.97
0.958-1.051
0
0
0
1
1
1
1
1
1
1

.000
.967
.978
.015
.018 234678-HxCDF
.021
.046
.057
.060
.063





AN






0.868-1.132
0
0
0
1,513.74 0
1,642.85 1
1
1
1,568.64 1
1
1,340.84 1
1
1
1

.000
.962
.966
.996 13C12-HXCDF 478
.000 13C12-HJCCDF 678
.005
.012
.018 13C12-HXCDF 234
.026
.042 13C12-HXCDF 789
.047
.050
.057




SOR3
IS4


ALT2

ALT1






1
0
1
1
1
3
3
0
3
1
2
0
0
0
.80
.69
.06
.30
.28
.76
.05
.65
.56
.81
.80
.63
.96
.00
0.952-1.015
0
0
0
0
0
0
0
0
0
0
1
1
1

.000
.953
.954
.956
.962
.973
.976
.988
.993
.998 123478-HXCDD
.010 123789-HxCDD
.016
.019










AN
AN



Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
 Page Ho.     5
 10/23/97

 Compound/
 H_Z.... QC.Log Omit  Why
Listing of U973263B.dbf
Matched GC Peaks  / Ratio /  Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
13C12-HXCDD
402-404










402-404

HpCDF
408-410








408-410
13C12-HpCDF
418-420




418-420
HpCDD
424-426




424-426
13C12-HpCDD
436-438





DC
DC
DC


DC

DC
DC
DC
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC


DC


DC
DC


DC
DC
DC
DC
DC


DC
DC

DC
DC

NL
SN
SN


SN

SN
SN
SN
SN
3


NL
WL
SN
SN
SN
SN
SN
SN
WH
0

NL


SN
SN
2

NL
SN
SN
SN
WH
0

NL
SN

SN
SN

0:00
30:20
30:39
30:53
30:58
31:05
31:16
31:23
31:35
31:39
31:48
Peaks


0:00
32:50
32:58
33:03
33:11
33:14
33:22
34:23
34:41
Peaks

0:00
33:01
34:14
34:28
34:35
Peaks

0:00
33:11
33:54
34:00
34:13
Peaks

0:00
33:16
33:53
34:03
34:14
1.

RO
RO


RO

RO
RO
RO



0.
RO
RO
RO

RO
RO
RO

RO

0.



RO
RO

0.

RO
RO
RO
RO

0.
RO
RO

RO
RO
05-1.43
1.
0.
2.
1.
1.
1.
1.
1.
0.
1.
1.


16
94
03
21
18
94
18
65
39
76
19


88-1.20
1.
2.
5.
1.
1.
4.
1.
0.
3.

35
04
02
05
39
94
72
92
76

2.
10.
0.
1,900.
2,128.
28.
2,191.
18.
13.
14.
10.
6,220.
64
57
67
63 1,040.31
10 1,153.87
94
63 1,188.48
41
26
94
48
36
0.968-1.032
0.
0.
0.
860.32 0.
974.23 1.
1.
1,003.15 1.
1.
1.
1.
1.

000
980
990
997 13C12-HXCDD 478
000 13C12-HXCDD 678
004
010 13C12-HXCDD 789
013
020
022
027




SUR4
IS5

RS2







2.
1.
1.
4.
2.
0.
1.
2.
1.
0.
06
04
08
52
02
67
90
46
47
00
37-0.51
0.
0.
0.
0.
0.

47
43
41
52
14

11.
1,715.
1,333.
13.
9.
3,048.
u»*^nc
88-1.20
1.
0.
0.
1.
16.

15
61
33
22
17

1.
2.
1.
1.
0.
0.
15
36 513.44
53 389.61
15
13
89

40
22
14
04
24
00
88-1.20
1.
1.
1.
6.
0.
25
22
01
04
59
5.
8.
1,907.
6.
12.
47
24
82 956.89
55
63
0.996-1.043
0.
0.
0.
1.
1.
1.
1.
1.
1.

000
994
998
001 1234678-HpCDF
005
007
Oil
041
050




AN






0.939-1.121
0.
1.201.92 1.
943.92 1.
1.
1.

000
000 13C12-HpCDF 678
037 13C12-HpCDF 789
044
047


IS6
SUR5



0.977-1.005
0.
0.
1.
1.
1.

000
979
000 1234678-HpCDD
003
010



AN



0.971-1.029
0.
0.
950.93 1.
1.
1.
000
982
000 13C12-HpCDD 678
005
010


IS7


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 23:43 10/23/97

-------
 Page No.
 10/23/97
         Listing of U973263B.dbf
         Matched GC Peaks /  Ratio / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak. 2. . Rel.RT Compound.Name..  ID..  Flags.
 436-438
 OCDF
 442-444
 442-444
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

SN
1

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
34:19
Peak

0:00
32:54
33:18
33:32
33:43
34:07
34:43
35:09
35:15
35:31
35:56
36:28
36:58
37:07
37:51
37:57
38:51
39:12
39:23
Peaks

0.
RO
RO
RO
RO

RO
RO



RO
RO
RO
RO
RO
RO
RO

RO

1
.20
76-1.02
1
0
0
1
0
4
0
1
0
0
1
0
0
0
1
0
0
0
1

.09
.24
.28
.67
.83
.23
.15
.00
.97
.85
.32
.67
.19
.64
.30
.66
.42
.78
.51

                              11.75                             1.013
                            1,907.82

                      Above: HpCDD / Octa-CDD and CDP Follows  	
                               2.12
                               1.23
                               1.36
                               0.45
                               2.16
                               0.59
                               0.55
                               1.52
                               0.69
                               4.08
                               2.55
                               3.57
                               1.87
                               4.61
                               2.68
                               3.89
                               2.89
                               3.24                              1.076
                               3.33                              1.081
                               0.00
             0.890-1.110
                 0.000
                 0.903
                 0.914
                 0.920
                 0.925
                 0.936
                 0.953
                 0.965
                 0.968
                 0.975
                 0.986
                  .001
                  .015
                  .019
                  .039
                  .042
                  .066
 OCDD
 458-460
 458-460
               0.76-1.02
DC  NL   0:00     0.82
DC  SN  36:33     0.96
DC  SN  36:50 RO  0.70
      0 Peaks
                                                1.98
                                                2.31
                                                1.85
                                                0.00
             0.890-1.110
                 0.000
                 1.003
                 1.011
 13C12-OCDD
 470-472
 470-472

DC

DC
DC


NL

WH
WH
1

0:00
36:26
36:45
36:51
Peak
0.


RO
RO

76-1.02
0.
0.
0.
1.

88
90
31
85

1
3,182
10
10
3,182
.99
.05
.89
.41
.05
                                                             0.995-1.005
                                                                 0.000
                                         1,508.40      1,673.65   1.000 13C12-OCDD
                                                                 1.009
                                                                 1.011
                                                                                                       IS8
 Column Description	   "Why Code Description	   QC Log  Desc.
 M_Z   -Nominal Ion Hass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
 *** End of Report ***
                WL-Below Retention Time Window
                WH-Above Retention Time Window
                SN-Below signal to Noise Level
                
-------
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375.8178 F:3 BSU3(256,30,-3.0) PXD(7,5,3,0.10*,2668.0,1.00*,P,T) Exp,BPCVS2
TRIANQLE UBS  Text:PB2-M23 TLHH3432
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     29*36    29*48   30'tOO    30*12    30*24    30i36   30*48    31': 00   31,12    31t24   31i36
rlle*U973263 01-404 Acg* 17-OCT-1997 111 17112 OC ET+ Voltage SIS 70S Solse:408
391.8127 Pi3 BSOB(256,30,-3.0) PXD(7,5,3,0.10*,1632.0,1.00*,P,T) ExpsEPCVS2
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401.8558 F*3 BSOB(2S6,30.-3.0) PXD(7,S,3,0.10\,2836.0,1.00\,F,T) Exp:EPCUS2
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       33'tOO    33(12     33:34     33:36     33s 48    34:00     34:12     34:24    34:36
Fllf:U973263 *l-596 Aaq>17-OCT-1997 21:17:12 OC ET+ Voltage SIS 70S Soia«t504
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430.9729 Pt 4 Exp:BPCUS2
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437.8140 P:4 BSUB(256,30,-3.0) PXD(7,S,3,0.10X,5364.0,1.00*eP,T)  Sxp:SPCUS2
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                                                                                                   -1.4E6

                                                                                                   -6. ass
      33:12  33:18   33:24  33:30   33:36  33:42  33:48   33:54  34:00
Pil»,0373263 91-596 Acq: 17-OCT-1997 21:17:13 OC ST+ Voltage SIR 70S
430.9729 P:4 Exp:SPCUS2
TRIAHOLS LABS   Tmxt IPB2-K23 TLX943432
                                                                                                    0.050
                                                                        34-106  34:12 ' 34*18  ' 34(24   Tia»
 ion

  80.

  60.

  40.

  20.

   0.
               33*a°33t24
                                33i33   33:40
                                                     33:50
                                                                         34:06
      33:12  33:18   33:24   33:30   33:36  33:42  33:48   33:54  34:00   34:06   34:12   34:18
.2.0BS

.1.636

.1.2X6

.8. IBS

-4.OSS
                                                                                                     O.OEO

-------
 'U»tU9732t3 ti-596 Acq:l7-OCT-199} 21:17:i2 OC SI* Voltag* SIR 70S Noise,
-------
Pil»tU973263 il-596 Acq,17-
-------
                Peak Locate Examination:17-OCT-1997:21:15 File:U973263
                      Experiment:EPCUS2 Function:2 Reference:PFK

-------
File:U973263 #1-596 Acq:17-OCT-1997 21:17:12 GC EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:FB2-M23 TLItt43432 File Text : TRIANGLE LABORATORIES, INC.
1004                                .                             37:37
80 j
60

20J
      35:21
                            38:04
                       36:00                     37:00
File:U973263 #1-596 Acq:17-OCT-1997 21:17:12 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:FB2-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100*            35:44             36:26                  ^   n
           __ ,_  I                  A        -JC.KO       37:20
 80J ,      35:33
 60 j
 40 j
 20J
                          38:00
                           38:02
                       36:00                     37:00
File:U973263 #1-596 Acq:17-OCT-1997 21:17:12 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:FB2-M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                              36;26
 80J
 60 J
 40 J
 20J
                          38:00
              .2.5E4
              .2.0E4
              .1.5E4
              .9.9E3
              .4.9E3
              .O.OEO
                  Time
               2.8E4
               2.2E4
               1.7E4
               1.1E4
               5.6E3
               O.OEO
                  Time
                       36:00
37:00
38:00
                                                                                        .4.9E6
                                                                                        .3.9E6
                                                                                        .2.9E6
                                                                                        .1.9E6
                                                                                        .9.7E5
                                                                                        .O.OEO

-------
TLI Project:      43432
Client Sample:   FB2-M23
Method 23 TCDD/TCDF Analysis (DB-225)
                    Analysis File:   X973680
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-6A-C
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/29/97
10/09/97
10/22/97
n/a
U973257
GG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
XF24087
X973676
n/a
n/a
n/a
2,3,7,8-TCDF
                              ND
0.01
                                                     OC Lteitta
13C12-2,3,7,8-TCDF
                              3.3
   81.8
                                                     40%-130%
0.79
24:18     _
13C12-1,2,3,4-TCDD
                         0.82
                                                                          23:07     	
                     Data Reviewer.
                    10/23/97
                                         Page 1 of 1
                                  CZNF.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                              Printed: 23:32.10/23/97

-------
 Data Review By:
                         Initial
                        \ \ C
                        XI ^
                                    ...Date.,
                                               Calculated Noise Area:
                                                                        9.99
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according  to method requirements.
 Page No.
 10/23/97
Listing of X973680B.dbf
Matched GC Peaks / Ratio / Ret.  Time
 Compound/
 M_Z	  QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. R«1.RT Compound.Name.. ID.. Flags.
 TCDF
 304-306
 304-306
 13C12-TCDF
 316-318
 316-318
 13C12-TCDD
 332-334

DC
DC

DC


DC
DC
DC
DC

DC
DC
DC
DC


DC
DC




DC
DC
DC
DC
DC
DC
DC

NL
SN

SN
1

NL
WL
WL
WL

SN
WH
WH
WH
1

NL
SN




SN
WH
WH
WH
WH
WH
WH

0:00
20:52
24:34
24:40
Peak

0:00
22:20
22:47
23:03
24:18
24:35
25:44
26:42
26:46
Peak

0:00
20:52
22:49
23:07
23:24
23:53
24:44
24:56
24:59
25:09
25:25
25:33
25:51
0.

RO



0.
RO
RO
RO
RO

RO
RO

RO

0.
RO
RO



RO
RO

RO

RO
RO
RO
65-0.89
0.
0.
0.
0.

65
93
70
69

65-0.89
0.
2.
2.
1.
0.
0.
0.
0.
1.

54
85
62
09
79
26
54
76
19

65-0.89
2.
1.
0.
0.
0.
0.
5.
0.
3.
0.
0.
0.
0.
12
36
79
82
67
48
03
67
17
87
30
57
90
                      17.53
                       9.01
                      16.64          6.87
                       6.48
                      16.64
                      23.26
                      10.12
                      14.73
                      64.53
                   7,789.42      3,430.53
                      10.83
                       9.95
                      63.12
                      14.02
                   7,789.42

              Above:  TCDF / TCDD Follows -
      0.800-1.112
          0.000
          0.859
    9.77   1.011
          1.015
      0.959-1.041
          0.000
          0.919
          0.938
          0.949
4,358.89  1.000  13C12-2378-TCDF ISO
          1.012
          1.059
          1.099
          1.102
 332-334
                       4  Peaks
                       8.30
                       6.99
                   5,739.59      2,541.14
                   6,840.77      3,089.24
                      15.31          6.14
                      53.88         23.44
                       5.26
                       4.68
                      10.02
                       2.90
                       4.11
                       7.33
                      21.05
                  12,649.55
      0.912-1.088
          0.000
          0.915
3,198.45  1.000  13C12-2378-TCDD IS1
3,751.53  1.013  13C12-1234-TCDD RSI
    9.17  1.026
   49.27  1.047
          1.084
          1.093
          1.095
          1.102
          1.114
          1.120
          1.133
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                       Printed:

-------
 Page No.
 10/23/97
Listing of X973680B.dbf
Matched GC Peaks  /  Ratio / Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
 Column Description.
       "Why-  Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Hass(es)
 ..RT. -Retention Tim* (mn:ss)
 Rat.l -Ratio  of H/H+2 Ions
 OK    -RO=Ratio Outside Limits
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
FiJ.e,X973680 tl-803 Acq,22-OCT-1997 14t44t32 GC EH- Voltage SIR AutoSpec Noia»,J464
303.9016 BSUB(256,30,-3.0) PKD(5, 3,1,0.10\, 13856.0,0.00\,F,F) ExpiXCONT_TT
Sample Text:FB2-H23  TLH43432 OJ.e Texts TRIANGLE LABS
        20»00       ill 00      Mi 00       23'tOO       24(00       25iOO      iff 100
Flle,X973680 tl-803 Acqi22-OCT-1997 14,44,32 GC EH- Voltage SIS AutoSpmc Hti±a«i5301
305.8987 BSOS(356,30,-3.0) PKD(S,3,1,0.101,21304.0,0.00\,r,F) ExptXCOHT_TT
Sample T»xttFB2-H23  TLH43432 Tile Tart. TSIAXGLB LABS
1004            	                                   A1.23X5
       0.0X0
27100      Time
        20100       21100      22100       23,00       24:00       25.00      26tOO
F±letX973680 fl-803 Acqt22-OCT-1997 14t44i32 GC EI+ Voltage SIR AutoSpec SoifetS059
315.9419 BSOB(256,30,-3.0) P1O>(5,3,1,0.101,20236.0,0.00\,r,F) ElptXCOKr_TT
Sample TexttFB2-H23  TLH43432 rile Textt TRIANGLE LABS
1004                                                    A3.43X7
 80.

 60.

 401

 30.
                                                                                        27100
      -B.OE6

       .6.4E6

       •-4.8S6

       .3.2X6

       '.1.6X6
        20,00       21,00      22,00      23,00       24,00       25,00       26,00
rile,X973680 tl-803 Acqi22-OCT-1997 14,44,32 GC EH- Voltage SIR AutoSpec Noise,9385
317.9389 BSUB(256,30,-3.0) PKD(S,3,1,0.10\,37540.0,0.00\,r,r) ExpiXCOHT_TT
Sample T»xt,FB2-H23  TLH43432 rile Tazti TRIANGLE LABS
1004                                                    A4.36E7
 80.

 60.

 40.

 20.
27100
0.0X0
   Time
      -1.0X7

      '.8.2X6

      .6.1X6

      .4.1X6

      '.2.0X6
        20,00       21,00      22,00      23,00       24,00       25,00
rileiX973680 tl-803 Acq,22-OCT-1997 14,44,32 GC XII- Voltage SIR AutoSpec
375.8364 XxptXCOar_TS
Sample Texttn2-H23  TLH43432 rile Text, TRIANGLE LABS
100\19,41                 21,34
                                                                             26100
       .0.0X0
27,00      rime
        201 00
                    21100
                               22,00
                                          23,00
                                                      24,00
                                                                 25100
                                                                             26100
                                                                                        27 tOO

-------
Fll*,X973680 fl-803 Aoq:23-OCT-1997 14:44:3? SC EI+ VoJLtMff* SIS AutoSp*a S6if*»16B2
313.8965 BSU3(2S6,30,-3.0)  PXD(S,3,1,0.10\,6728.0,0.00\,T,T) ExptXCONT IT
Samplm  Taxt.,TB2-M23  TLH43432 ril* Tkztt  TRIANGLE LABS
100*
              21t00          32tOO           23100           24,00          25,00
Fil* 1X973680  H-803 Acq:22-OCT-1997 14:44:32 SC EH- Voltaga SIS AutoSpac Noia*,2006
321.8936 BSUB(256,30,-3.0) fXD(5,3,1,0.10\,8024.0,O.QO\,T,r) SzpiXCO»r_TT
Stmpl* T*xt,n2-H23  TLH43432 ril* Tmrti  TRIANGLE LABS
1001
                                                                                           26,00
              21,00          22:00          23,00           24,00          25,00
Til*:X973680  H-803 Acq:22-OCT-1997 14:44,32 GC EI+ Voltagw SIX AutoSpoc Noil*:6271
327.8847 BSUB(256,30,-3.0) HD(5,3,l,0.10\,25084.0,0.00\rT,r) ExptXCONF_TT
Sample T*xt:TB2-M23   XLIf43432 r±lm Tart.- TRIANGLE LABS
100*                                     AS.22X7

  80.

  eo:

  40.

  20:
                                                                                           26,00
              21,00          22>00          23:00           24:00          25,00
rilmtX973680  41-803 Acq:22-OCT-1997 14:44:32 SC EI+ Voltag* SIS AutoSpfo Noll*:4964
331.9368 BSOB(256,30,-3.0) H3>(5t3,l,0.10\, 19856.0,0.00\,T,f) Exp:XCONT_TT
Stmpl* T»xttfB2-M23   TLH43432 Til* T*xt, TXIANSLE LABS
100*                                         A3.09X7
                                                                                           26:00
 so:
 50:
 40:
 20:
                                        A2.54E7
              21,00          22,00          23:00           24,00          25,00
rll*,X9736aO  H-803 Aoq:22-OCT-1997 14:44:32 SC XI + Voltmy* SIS AutoSpmc Nolf*:2344
333.9338 BSUB(256,30,-3.0) PfD(S,3,l,0.10\,9376.0,0.00\,F,T) Ejcp:XCONT_TT
Stmpl* T*zt:rB2-M23  TLH43432 ril* T*rt» TRIANGLE LABS
100*                                         A3.75X7
                                                                                          26:00
 80.

 60.

 40.

 20.
                                        A3.20X7
             21100
                             22,00
                                            23100
                                                            24:00
                                                                           25:00
                                                                                          26100
-1.3X7

J..1X7

.7.9X6

.5.3X6

.2.6X6
                                                                                                    .0.0X0
                                                                                                        Tim*
-7.9X6

.6.4X6

.4.8X6

.3.2X6

.1.6X6
 0.0X0
    Tim*
.1.0X7

.8.0X6

.6.0X6

.4.0X6

'-2.0X6
 0.0X0
    Tim*

-------
Tilm
303.
Samp
1001
80:
60:
40:
20:
0
Tilm
315.
Samp
1001
eo:
60:
40:
20:
Tllo
319.
Samp
1001
80:
60:
40:
20:
0
Tilm
331.
Samp
1001
80:
60:
40:
20:
Tilm
292.
Samp
1004
00:
eo:
40:
20:
o-
Tilm
330.
Samp
1004
80:
60:
40:
20:
0:
1X973680 fl-803 Acq,22-OCT-1997 14*44*32 CC EH- Voltagm SIS AutoSpmc
9016 Exp,XCONT_TT
1m Tmxt,TB2-H23 TLIf43432 Tile Text* TSIAOGLX LABS
20,38 21,47
1 I 1 22,19 24,19 25,02
J^!^^


20,00 21,00 22*00 23*00 24*00 25*00 26,00 27,00
,X973680 fl-803 Acq:22-OCT-1997 14*44*32 GC EH- Voltagm SIS AutoSpmo
9419 XxpiXCONT_TT
1m Tmxt,TB2-M23 TLIf 43432 Tilm Texts XXIABGLX LABS
24*10



11
20*00 21*00 22*00 23*00 24*00 25*00 25100 27100
1X973680 #1-803 Aoq,22-OCT-1997 14*44*32 GC EH- Voltagm SIS AutoSpmo
8965 XxptXCONr TT
1m Tmxt,TB2-M23 TLIf 43432 Tilm Text* TSUOKLX LABS
24,21 35 41
21,07 It I 25(58
\Jk£^

20*00 21*00 22*00 23*00 24*00 25*00 25*00 27*00
,X973680 f 1-803 Acq,22-OCT-1997 14*44*32 GC EI+ Voltagm SIS AutoSpmc
9368 Xxp,XCOHr_TT
1m Tmxt,TB2-H23 TLIf 43432 Tilm Text* TMIABGLE LABS
23,07
T


111
20 lob 21*00 22 lob 23*00 24*00 25*00 iff 1 00 27lo0
,X973680 fl-803 Acq,22-OCT-1997 14*44*32 GC EH- Voltagm SIS AutoSpmo
9825 X3Cp,XCOHT_TT
1m Tmxt,TB2-M23 TLIf43432 Tilm Text* TXIARGLE LABS
20,13 20f49 21,30 	 M.I-732..4*,,. ,, 24,14 ^^^L?^ 35*42 25*152(y,4j




20 lob ' ' ' 21 lob ' ' 22*00 ' ' 23 lob ' ' ' 24*00 ' ' ' 25*00 ' ' ' 26*00 ' ' ' 27*00
1X973680 #1-803 Acq,22-OCT-1997 14*44*32 CC EH- Voltagm SIS AutoSpmo
9792 Exp,XCOlTT_TT
1m Tmxt,TB2-H23 TLH43432 Tilm Text* TRIAHGLX LABS
19$43., 2.0*15 20*47 21*41 22*10 33,41 23,35 24t20 25,0025,27 26,17




20*00 21*00 22*00 23lob 24lob 25100 25*00 27lob
_S.2r4
.7.4E4
.5.5X4
'.3 . 7X4
.1 . BE4
0.0X0
Timm
-8.0X6
.6.4X6
'-.4.8X6
13.2X6
.1.6X6
Timm
r.6.4E4
1.5.1X4
.3.8X4
'•o.oxo
Timm
-8.0X6
-.6.4X6
.4.8X6
.3.2X6
.1.6X6
Timm
-1.5X8
.1.2X8
.9.2X7
.6.2X7
.3.1X7
0.0X0
Tlmm
-1.9X8
.1.5X8
.1.2X8
.7.7X7
.3.9X7
0.0X0

-------
TLI Project:      43432
Client Sample:   LAB BLANK M23
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U973264
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Saginaw, MI
M23TRAIN
185-6-7A-CE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst*
09/29/97
10/09/97
10/17/97
n/a
U973257
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
UF59167
U973252
n/a
n/a
n/a
'AnaTyt**^ '^4^8fe '*
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
U,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3.4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
,tatate^ : ° xV^^lr -
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
*< £%&.&&$:
ND
ND
ND
ND
ND
ND
0.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
*nte&%jfj$
ND
ND
ND
ND
ND
ND
ND
ND
*A* S'aiPC ^ %Kft%a^%4^l^^^
0.003 	
0.004 	
0.006 	
0.005 	
0.005 	
0.005 	
0.84 36:25 B_
0.003 	
0.003 	
0.003 	
0.003 	
0.003 	
0.003 	
0.003 	
0.004 	
0.004 	
0.004 	
^^^^;j;pim ^ ^^^^///^iSSIS^^J
0.003 	
0.004 	
0.005
0.005 	
0.003 	
0.003
0.003
0.004 	
                                      Page 1 of2
                         X237JPSR rZOX LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
TLI Project:      43432
Client Sample:   LAB BLANK M23
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U973264
Interr^ Standards ^%""-> ,^lf:Ai
I3C,2-2,3,7,8-TCDF
13C.2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-1.2,3,7,8-PeCDD
l3Cl2-l,2,3,6,7,8-HxCDF
l3Ci2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Surix>gate Standards (TyiJe^i Ar
"CU^SJ-S-TCDD
l3C,2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
^tw^^pawxisCfyiP^r^
13d2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards *%'V^| f
13Ci2-l,2,3.4-TCDD
13C.2-l,2,3,7,8,9-HxCDD
nfc jtng$^|
3.4
3.3
4.0
4.7
4.2
3.8
3.6
4.1
8.3
M» /*»*&• ' *'*>*?
IjU A»^5>> s ?%
3.8
3.9
3.7
3.9
3.7
. ** ^s^\^&
&*&$&*&
3.8
4.2
" '' ^^1


H»ittmy
85.0
82.3
101
118
105
95.7
90.0
102
104
|j|$* H^csoveiy
94.1
98.5
93.1
96.8
92.4

95.3
104
H^S?-:^


.;•":.•• OO l»ltll{ts
- , -^ %
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
*• "" ^l^*^1 t t^MtSf*J>
•> *u(l^ t^tf-HlmiiT'
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QC Limits
40%-130%
40%-130%
' *.* ^\\"'"


& ?'*&n*3$>
0.75
0.80
1.46
1.50
0.50
1.24
0.42
1.01
0.85
Vf ^ 8*P?&

1.44
0.50
124
0.42
^|l|tit^!
0.51
0.50
^i^iwhiy;;
0.79
1.22
; *w
21:31
22:27
26:16
27:28
30:13
30:58
33:01
33:53
36:25
x^%?1
22:28
27:04
30:07
30:53
34:14
£Sf&?
31:30
30:45
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22:13
31:16
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—



                    Data Reviewer
                                       Page 2 of 2
            10/21/97
                         X237.PSRy2.Oa LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 20:4210/21/97

-------
Initial^
  Data Review By:
                                     . .Date. .
                       alculated Noise Area:
                                                                       1.20
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.
 10/21/97
 Listing  of U973264B.dbf
 Matched  OC Peaks / Ratio
                                                  / Ret. Time
 Compound/
 M_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak. 1..  Area.Peak. 2.. Rel.RT Compound.Name..  ID.. Flags.
TCDF
304-306













304-306
13C12-TCDF
316-318














316-318
TCDD
320-322






DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
HH
0

NL
HL
SN
SN

SN
SN
SN
HH
HH
HH
HH
HH
HH
HH
1

NL
SN
SN
SN
SN
SN

0:00
17:38
18:55
20:15
20:19
20:52
20:59
21:21
21:34
22:06
22:22
23:02
23:42
24:02
Peaks

0:00
20:09
20:37
21:01
21:31
22:05
22:12
22:26
22:38
22:53
23:09
23:23
23:38
23:54
24:15
Peak

0:00
19:10
19:57
20:23
20:38
21:30
0.

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

0.

RO
RO


RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

0.
RO
RO
RO
RO
RO
RO
65-0.89
0.
1.
0.
0.
1.
0.
0.
0.
1.
0.
1.
1.
0.
4.

88
71
38
32
75
44
35
14
12
99
25
94
55
68

1
4
2
1
0
2
3
1
10
4
4
1
2
0
0
.47
.04
.28
.95
.78
.60
.95
.01
.67
.00
.73
.96
.99
.50
.00
65-0.89
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
2.
0.
2.

86
60
30
73
75
52
58
57
37
51
58
82
24
58
68

1
28
3
21
3,821
14
9
9
3
5
6
3
3
3
1
3,821
.71
.87
.65
.21
.99
.78
.45
.24
.13
.13
.32
.17
.08
.43
.15
.99
D *
65-0.89
0.
2.
2.
2.
1.
3.
96
96
34
48
28
48
1
0
1
1
1
1
.40
.85
.04
.29
.13
.96
                                                         1.642.76
                                                                            0.813-1.106
                                                                                0.000
                                                                                0.820
                                                                                0.879
                                                                                0.941
                                                                                0.944
                                                                                0.970
                                                                                0.975
                                                                                0.992
                                                                                1.002 2378-TCDF       AN
                                                                                1.027
                                                                                1.040
                                                                                1.070
                                                                                1.101
                                                                                1.117
                                                   0.954-1.046
                                                       0.000
                                                       0.936
                                                       0.958
                                                       0.977
                                              2,179.23  1.000 13C12-2378-TCDF ISO
                                                       1.026
                                                       1.032
                                                       1.043
                                                       1.052
                                                       1.064
                                                       1.076
                                                       1.087
                                                       1.098
                                                       1.111
                                                       1.127
                                                    TCDD Follows 	
                                                                            0.848-1.061
                                                                                0.000
                                                                                0.854
                                                                                0.889
                                                                                0.908
                                                                                0.919
                                                                                0.958
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                            265

-------
 Pag* No.
 10/21/97
Listing of U973264B.dbf
Matched GC Peaks / Ratio /  Ret. Time
 Compound/
 M_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2..  Rel.RT Compound.Kame..  ID..  Flags.




320-322
37C1-TCDD
328












328
13C12-TCDD
332-334












332-334
PeCDF
340-342










DC
DC
DC
DC

SN
SN
SN
SN
0
22:00
22:30
23:14
23:25
Peaks
RO
RO
RO
RO

0
0
1
0

.48
.29
.04
.41

1
3
1
1
0
.24
.33
.19
.61
.00
0.
1.
1.
1.

980
002
035
043

0.911-1.089
DC
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC


DC

DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN

SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1

ML
SN
SN
SN


SN

SN
SN
SN
SN
SN
3

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
20:42
22:28
22:46
23:05
23:15
23:26
23:27
23:38
23:54
24:01
24:07
24:15
Peak

0:00
20:55
21:29
21:50
22:13
22:27
22:38
22:52
23:20
23:27
23:53
23:57
24:11
Peaks

0:00
23:51
24:00
24:59
25:06
25:11
25:17
25:42
26:11
26:19
26:43














0.
RO
RO
RO



RO
RO

RO
RO
RO


1.
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO
















2










2
0
6
.622
2
4
2
2
1
6
4
2
2
2
,622
.77
.98
.50 2,622.50
.22
.18
.15
.45
.96
.04
.06
.35
.20
.45
.50
65-0.89
1
1
1
0
0
0
0
0
0
0
0
0
0

.25
.19
.14
.86
.79 3
.80 2
.57
.94
.66
.52
.17
.35
.72
6
*!».«••_ .
32-1.78
0
0
2
1
1
1
0
0
3
1
0
.99
.95
.09
.17
.83
.26
.14
.22
.54
.66
.18
1
15
2
3
.236
.953
15
58
9
3
4
3
7
.43
.72
.85
.68
.15 1,428.45
.50 1,311.21
.33
.96 31.28
.52
.75
.53
.79
.05
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

000
922
001 37C1-TCDD SOR1
014
028
036
044
045
053
065
070
074
080

0.911-1.089
0.
0.
0.
0.
1,807.70 0.
1,642.29 1.
1.
33.31 1.
1.
1.
1.
1.
1.
000
932
957
973
990 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
008
019
039
045
064
067
077
.248.61
TCDD / P^CPP PoUows ™—

i
2
2
1
0
0
0
0
1
4
0
.15
.17
.01
.23
.61
.87
.81
.66
.56
.15
.18
0.906-1.077
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
908
914
951
956
959
963
978
997
002 12378-PeCDF AN
017
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                          266

-------
 Page No.
 10/21/97
Listing of U973264B.dbf
Matched GC Peaks /  Ratio / Ret. Time
 Compound/
 H_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.





340-342
13C12-PeCDF
352-354









352-354
PeCDD
356-358









356-358
13C12-FeCDD
368-370












368-370
DC
DC
DC
DC
DC


DC

DC



DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC

SN
SN
SN
SN
WH
0

NL

SN



SN
SN
SN
SN
4

NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
0

NL
SN
SN
SN
SN
SN


SN
SN
SN
SN
SN
2
27:03
27:45
27:49
28:17
28:33
Peaks

0:00
25:17
25:51
26:16
26:37
27:04
27:29
27:36
28:09
28:40
Peaks

0:00
26:17
26:29
26:33
27:05
27:26
27:36
27:48
27:55
28:29
Peaks

0:00
25:42
25:53
26:07
26:15
26:38
27:28
27:37
27:55
28:05
28:17
28:23
28:34
Peaks
RO
RO
RO

RO

1.
RO



RO

RO
RO
RO
RO
0.
0.
0.
1.
0.

71
93
94
49
19

2
0
1
2
0
0
.58
.63
.04
.59
.35
.00
32-1.78
0.
1.
1.
1.
0.
1.
0.
0.
2.
0.
97
55
38
46
85
44
75
93
02
46
1
55
18
3,564
27
3,407
7
11
15
0
.09
.90 33.98
.62
.87 2,117.73
.47 16.70
.15 2,013.27
.16
.01
.61
.90
1
1
1
1
1

.030 23478- PeCDF
.056
.059
.077
.087

AN





0.848-1.152
0
21.92 0
0
1,447.14 1
19.61 1
1,393.88 1
1
1
1
1
.000
.963
.984
.000 13C12-PeCDF 123
.013
.030 13C12-PeCDF 234
.046
.051
.072
.091



IS2

SOR2




7,055.39
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

1.
RO
RO
RO
RO




RO

RO
RO
RO

32-1.78
1.
2.
0.
0.
1.
3.
0.
1.
1.
3.

10
94
63
53
89
15
73
21
88
10

rw i f^^isf i f m»w c~ w**w**« 	
1
3
0
0
2
0
1
1
2
1
0
.27
.93
.86
.79
.32
.66
.05
.88
.55
.96
.00
32-1.78
1.
4.
2.
2.
1.
1.
1.
1.
0.
1.
0.
1.
1.

09
02
54
08
72
73
50
58
22
46
61
18
18

1
1
0
0
4
2
2,292
227
1
5
2
3
4
2.520
.23
.22
.61
.99
.41
.27
.92 1,374.35
.91 139.61
.09
.22
.93
.37
.03
.83
0.921-1.025
0
0
0
0
0
0
1
1
1
1

.000
.957
.964
.967
.986
.999 12378-PeCDD
.005
.012
.016
.037






AN





0.855-1.145
0
0
0
0
0
0
918.57 1
88.30 1
1
1
1
1
1

.000
.936
.942
.951
.956
.970
.000 13C12-PeCDD 123
.005
.016
.022
.030
.033
.040







IS3







Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               . Printed: 20:43 10/21/97

-------
 Page No.
 10/21/97
Listing of 0973264B.dbf
Matched GC Peaks / Ratio /  Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK  Ratio Total.Area...  Area.Peak. 1.. Area.Peak.2..  Rel.RT compound.Name..  ID.. Flags.
HxCDF
374-376















374-376
13C12-HXCDF
384-386










384-386
HxCDD
390-392










390-392

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC



DC
DC
DC
DC
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


NL
SN
SK
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0

NL
SN



SN
SN
SN
SN
SN

4

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0

0:00
29:01
29:13
30:08
30:13
30:24
30:29
30:45
30:59
31:05
31:11
31:16
31:19
31:26
31:38
31:55
Peaks

0:00
29:14
30:07
30:13
30:45
30:54
30:56
31:10
31:15
31:18
31:30
Peaks

0:00
29:38
29:43
29:50
29:54
30:13
30:40
30:45
30:56
31:16
31:29
Peaks
1.

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO


0.
RO
RO



RO
RO
RO
RO
RO

05-1.43
1
2
0
2
0
0
1
0
0
0
0
2
0
1
0
1

.08
.76
.85
.57
.69
.94
.64
.82
.69
.57
.73
.19
.83
.32
.67
.40

2
0
1
2
1
1
0
4
1
0
0
1
0
1
1
1
0
.25
.47
.61
.44
.82
.10
.49
.25
.34
.36
.52
.19
.89
.30
.23
.25
.00
43-0.59
0
0
0
0
0
0
0
1
0
1
0
.41
.67
.50
.50
.50
.28
.26
.02
.83
.07
.51
15
17
2,848
3,141
2,931
10
4
5
3
4
2,529
.46
.32
.05 952.23
.70 1,052.43
.27 974.64
.75
.80
.39
.44
.88
.35 852.20
0.958-1.051
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1

.000
.960
.967
.997 123478-HXCDP
.000 123678-HxCDP
.006
.009
.018 234678-HxCDF
.025
.029
.032
.035
.036
.040
.047
.056




AN
AN


AN









0.868-1.132
0
0
1,895.82 0
2,089.27 1
1,956.63 1
1
1
1
1
1
1,677.15 1
.000
.967
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.018 13C12-HXCDF 234
.023
.024
.031
.034
.036
.042 13C12-HXCDF 789


SOR3
IS4
ALT2





ALT1
11,450.37
1.

RO
RO
RO
RO
RO
RO
RO

RO
RO

05-1.43
1
0
0
0
2
0
0
1
1
0
1

.20
.89
.71
.88
.25
.79
.64
.98
.39
.33
.04

RAW W / CWMrW *i W**WW» — ~
1
1
0
0
0
4
2
2
1
0
2
0
.74
.03
.54
.81
.36
.91
.35
.91
.96
.96
.84
.00
0.952-1.015
0
0
0
0
0
0
0
0
0
1
1

.000
.957
.960
.963
.966
.976
.990
.993
.999 123478-HxCDD
.010 123789-HxCDD
.017









AN
AN


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                          2H8

-------
 Pag* No.
 10/21/97
Listing  of U973264B.dbf
Matched  GC Peaks / Ratio / Ret. Time
 Compound/
 H_Z	 QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name..  ID..  Flags.
13C12-HXCDD
402-404








402-404

HpCDF
408-410






408-410
13C12-HpCDF
418-420





418-420
HpCDD
424-426





424-426
13C12-HpCDD
436-438





436-438

DC
DC


DC

DC
DC
DC



DC
DC
DC
DC
DC
DC
DC


DC

DC
DC
DC



DC
DC
DC
DC
DC
DC


DC
DC

DC
DC
DC


NL
SN


SN

SN
SN
SN
3


NL
SN
SN
SN
SN
WH
WH
0

NL

SN
SN
SN

2

NL
SN
SN
SN
WH
WH
0

NL
SN

SN
SN
SN
1

0:00
30:20
30:53
30:58
31:06
31:16
31:25
31:30
31:48
Peaks


0:00
32:59
33:39
34:01
34:09
34:31
34:36
Peaks

0:00
33:01
33:11
33:39
33:53
34:14
Peaks

0:00
33:17
33:26
33:53
34:11
34:14
Peaks

0:00
33:17
33:53
34:04
34:21
34:28
Peak
1.
RO





RO
RO
RO


0.
RO
RO
RO

RO
RO


0.
RO


RO



0.

RO
RO
RO
RO


0.

RO

RO
RO
RO

05-1.43
0
1
1
1
1
1
3
9
2


.96
.15
.24
.24
.42
.22
.12
.68
.14


88-1.20
1
5
1
0
3
1
1

.47
.24
.35
.95
.30
.32
.06

2
13
2,172
2,502
17
2,717
5
5
6
7,392
.31
.68
.90
.01
.48
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Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
 Page No.
 10/21/97
Listing of U973264B.dbf
Hatched OC Peaks / Ratio /  Ret. Time
 Compound/
 M_2	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
 OCDF
 442-444
 442-444

 OCDD
 458-460
         MK
 458-460

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC

DC


NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL
SN

SN
1

0:00
32:39
32:48
33:30
33:38
34:14
34:37
34:47
35:02
36:02
36:17
39:07
39:14
39:26
39:32
39:40
Peaks

0:00
36:17
36:25
36:45
Peak
0.
RO

RO
RO
RO
RO
RO
RO
RO

RO
RO

RO
RO
RO

0.

RO

RO

76-1.02
1.
0.
1.
1.
4.
0.
1.
5.
1.
0.
3.
3.
0.
0.
1.
0.

14
79
31
59
25
73
13
48
14
98
78
31
84
64
25
20

76-1.02
0.
0.
0.
0.

91
44
84
39

                                      Above: HpCDD / Octa-CDD and CDF Follows
                                                2.66
                                                2.94
                                                1.93
                                                1.51
                                                0.45
                                                3.06
                                                1.68
                                                0.91
                                                2.21
                                                3.62
                                                1.12
                                                0.96
                                                4.48
                                                1.97
                                                1.74
                                                1.15
                                                0.00
                       1.97
                       2.72
                       7.07
                       1.17
                       7.07
                                                   0.390-1.110
                                                       0.000
                                                       0.897
                                                       0.901
                                                       0.920
                                                       0.924
                                                       0.940
                                                       0.951
                                                       0.955
                                                       0.962
                                                       0.989
                                                       0.996
                                                         .074
                                                         .077
                                                         .083
                                                         .086
                                                              3.22
                                                       1.089
             0.890-1.110
                 0.000
                 0.996
           3.85   1.000 OCDD
                 1.009
                                                                                                      AN
 13C12-OCDD                     0.76-1.02
 470-472         DC  NL   0:00 RO  1.15          1.74
                         36:25     0.85      4,321.34
                 DC  WH  36:37 RO  0.58         25.76
                 DC  WH  36:54 RO  0.27          6.56
 470-472               1 Peak               4.321.34
                                                   0.995-1.005
                                                       0.000
                                1,988.45      2,332.89  1.000 13C12-OCDD
                                                       1.005
                                                       1.013
                                      IS8
 Column Description	   'Why* Cod* Description	   QC Log D«»c.
 M_Z   -Nominal Ion Hass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO»Ratio Outside Limits
 Rel. RT-Relative Retention Time
 *«* End of Report ***
       WL-Below Retention Time Window
       WH-Abovo Retention Time Window
       SN-Below Signal  to Noise Level
       
-------
P1101U973264 #1-1024 Acqi 17-OCT-1997 22(01(31  0C *1> Voltage SIS 70S Noim»t347
303.9016 Pi2 BSOB(256,30,-3.0) SXD(9,5.3,0.10\,1388.0,1.00\,P,T) ExpiBPCUS2
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305.8987 P>2 BSOB(256,30,-3.0) PXD(9,5,3,0.10*,1552.0,1.00*,P,T) XxptSPCUS2
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Pil»iU973264 01-1024 Aaqt 17-OCT-1997 22(02(31 OC *X+ Voltmgu SIS 70S Nairnft397
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-------
PilfiU973264 #1-1024 Acgt 17-OCT-1997 22(01(31 OC XI* Voltafft SIS 70S No±t»l382
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-------
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-------
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 .0.0X0
   29:00                        30:00                        31:00
Pll«lU973264  tl-405 Aoyt 17-OCT-1997 22:01:31 OC XI* Voltmgm SIR 70S
445.7555 P:3  XxptXPCUS2
TRIANQLX LABS  TmxCtLAB BLANK H23 TLH43432
lOOtt
                                                                                         32:00
  80.
                                                        30:50
     29105
                       29141
  61

  40.

  20.

   0.
   29 tOO
               29125
                             29,S3
                                       30>15
                                    30»0«
                                                  30«37
                                                                     31»17
                                30tOO
                                                                103
                                                             31100
                                                                             lit 33
                                                                                         31:58
                                                                                          32100
 .2.7X4

 .2.2X4

 .1.6X4

 .1.1X4

 .5. 4X3

 .0.0X0
     ria»

-------
fJ.lmtV973at4 91-405 Acq:17-3 BSUB(256,30, -3.0) PXD(7,5,3,0.10*,1892.0,1.00*,P,T) XxptBPCUS2
TRIANGLE LABS  T«UCt I LAB BLANK H23 TLI943432
100H
     29:36    29:48   30:00    30:12   30:24   30:36   30:48    31:00   31:12    31:24   31:36
Pll»:U973264  91-405 Aoqt 17-OCT-1997 22:01:31 OC JET* Voltmfff SIR 703 Noi**:394
391.8127 fl3  B3UB(256,30,-3.0)  PXD(7,5,3,0.10\,1576.0,1.00*,P,T) Bxp:XPCUS2
TRIANOLS LASS TfXtiULB BLANK 1123  TLH43432
                                                A2.02X4
     29:36   29:48   30:00    30:12   30:24   30t36    30:48    31:00   31:12    31:24
Pllm:U973264  91-405 Jicqi 17-OCT-1997 22:01:31 OC MX* Voltmfff SIR 703 No±*»:641
401.8558 fi3  B3UB(256,30,-3.0)  PKD(7,5,3,0.101.2564.0,1.00X,P,T) ExptSPCUS2
TRUUfOLX LABS  TutlLAB BLANK H23 TLH43432
100H                                                         ., ,„„      JL1.49S7
  80.

  60.

  40.

  20.
                                                                               A1.51S4
                                                                                         31:36
  80.

  60.

  40.

  20:
                                                             A1.39B7
      29:36   29:48   30:00    30:12   30:24    30:36    30:48    31:00   31:12    31:24
P±1»:U973264 91-405 Acq:17-OCT-1997 22:01:31 OC JX+ Voltmgm SIR 703 Soim»t669
403.8529  ft3 BSUB(256, 30, -3. 0)  PKD(7,5,3,0.10\,2676.0,1.00*,P,T) Sxp:SPCU32
TRIANQLX  UUB3  TfXttlAB BLANK X23 TLX943432
100H                                                                     A1.23E7
                                                                                     31:36
  80.

  60.

  40.

  20.

   0.
                                                             A1.12S7
      29:36   29:48    30:00    30:12   30:24    30:36    30:48    31:00
Pll»:U973264 91-405 Acq: 17-OCT-1997 22:01:31 OC U* Volt*g» SIR  70S
392.9760 P:3 fxp:SPCVS2
TRIAKOLX IAB3  Text:LAB BLANK H23 TLX943432
                                                                    31112
                                                                            31:24
                                                                                     31:36
.1.3X4

.1.124

.7.9X3

.5.3X3

.2.6X3

 0.0X0
                                                                                                       Tim*
                                                                                              rS.3X6

                                                                                               .4.3X6

                                                                                               .3.2X6

                                                                                               .2.1X6

                                                                                               .1.1X6
                                                                                                     O.OSO
                                                                                                   rim*
                                                                                               .4.6E6

                                                                                               .3.7S6

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                                                                                               '.1.8X6

                                                                                               '.9.2X5
                                                                                                     0.0X0
 1009

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                                                                 31:02
/sJ^^!N/^\/J^^^
      29,36
              29:48    30:00
                               30:12
                                       '30t24  ' '30t36
                                                        30:48
                                                                31 tOO
                                                                   '3i\12 '  '31:24
.2.3X6

'.1.8X6

'.1.4X6

.9.2X5

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                                                                                                     0.0X0
                                                                                          31:36
                                                                                                        Tim*

-------
Pil»*U973264 #1-596 Acy* 17-OCT-1997 22t01i31 QC Eli' Voltag* SIX 70S Koim»:623
407.7019 Pt4 BSUB(2S6,30,-3.0) PO>(7,5,3,0.10*,2492.0,1.00\,P,T) Xxp*XtOJS2
TRIAHOLB LABS  Text * LAB BLANK M23 tLX*43432
100H M.18X4
       33'tOO     33*12     33t24     33t36    33t48     34tOO    34il2     34t24
P110IU973264 91-596 *c
-------
SileiU9732S4 #1-596 Acqs 17-OCT-1S97 22(0.1(31 QC BI+ voltage SIX 70S NOiaeut
423.7766 Pi4 BSUB(256,30,-3.0) PKD(7,5.3,0.10*,1444.0,1.00\,P,T) BxptEPCUtt
TRIANGLE LABS  Text tLAB BLANK H23 TLIH43432
IOOH
      33:12   33(10   33(24  33*30   33't36  33(42   33*48   33(54  34.00   34 i Off
Fll»tU973264 91-596 Acqt 17-OCT-1997 22(01(31 QC XT* Voltage SIR 70S Noimet401
425.7737 Pi4 B3UB(256,30,-3.0) PKD(7,5,3,0.10*,1604.0,1.00X,P,T) XxptXPCUS2
TRIANQLX LABS  Text,LAB BLANK H23 TLI943432
100H     A3.69X4
     33(12   33(10 '  33(24   33(30   33(3tf  33(42  33(40   33(54  34(00
FlletU973264 91-596 Aagi17-OCT-1997 22(01(31 OC XT* Voltage SIR 70S Noieeil694
435.8169 Pi4 BSOB(256,30,-3.0) PKD(7,5,3,0.10*,6776.0,1.00*,P,T) XxptXPCU32
         LABS  Text:LAB BLANK H23 TLI943432
                                                       41.20X7
                                                                                 0X4               ,.1.3X4

                                                                                                   -1.0X4

                                                                                                   .7.5X3

                                                                                                   .5.2X3

                                                                                                   .2.6X3


                                                                                34(12   34(10  34(24   Time
  00:

  60.

  40.

  20.
                                                                                                     O.OEO
                                                                                 34(12 '  34(10 '  34(24   Tim*
                                                                                                   -4.5S6

                                                                                                   .3.6E6

                                                                                                   -2.7E6

                                                                                                   .1.8X6

                                                                                                   .9.OSS
                                                                                                    .O.OEO
      33(12  33(10   33(24   33(30   33»3tf  33(42   33(40  33(54   34(00
Pll»tU973264 tl-596 Aaqil7-OCT-1997 22(01(31 OC EH- Voltmgm SIR  70S Nolf»ilS28
437.8140 Pi4 BSDB(256,30,-3.0)  PXD(7,5,3,0.10*,6112.0,1.00*,P,T)  ExptEPCtTS2
TRXANOLX LABS   Text I LAB BLANK H23  TLIf 43432
100H                                                  Al.2.7X7
  00.

  60.

  40.

  20J

   0.
                                                                                34(12   34(10  34(24   Time
                                                                                                   -4.5S6

                                                                                                   .3.6X6

                                                                                                   ,.2.7*6

                                                                                                   .1.8X6

                                                                                                   .8.9X5
      33(12   33(10   33(24   33(30  33(3*   33(42   33(40  33(54   34(00 ' 34(6*
Pil»tU973264 91-596 Actjtl7-OCT-1997 22(01(31 OC JET* Voltuye SIR 70S      ;'
430.9729 Pi4 E*ptSPCUS2
TRIANOLX LABS  TexttLAB BLANK JQ3 T1J*43432
                                                                                                     0.0X0
 IOCS

  801

  eo:

  40.

  20.

   0.
                                                      33151
                                                                     34103
                                                                                34(12   34(10   34(24   Time
.1.4X6

.1.1X6

-0.1X5

_5.4X5

.2.7X5
                                                                                                     0.0X0
      33(12   33(10  33(24   33(30  33»3tf   33f42   33(40  33(54   34(00  34.Off   34.13 ' 34(10 '  34(24   Tin*

-------
Fil»:U973264 tl-596 Acqil7-OCT-1997 22t01t31 QC EH-  VoJtajr* SIR  70S Solf»t804
441.7428 Pit BSOB(256,30,-3.0) PKD(7,5,3, 0.10X,3216.0,1.00*,F,T) Exp:EPCVS2
TXXAHOLS LABS  TexttLAB BLANK K23 VLIt43432
         33:00       34:00       35:00      36'tOO       37:00       38,00
P11»:U973264 tl-596 Aagil7-OCT-1997 22:01:31 OC KC+ Voltaff* SIS 70S Sol*ft705
443.7399 P:4 BSUB(256,30,-3.0) fXD(7f 5,3,0.10\,2820.0,1.00\,P,T) Exp:EPCU32
TRUUtOLS LABS  TUXttL&B BLANK H23 TLH43432
100*
39:00
              -.0.0*0
                  Via*
         33iOO       34tOO       35iOO       36:00       37:00       38:00
Pll»:U973264 tl-596 Acqil7-OCT-1997 22:01:31 OC Kf Voltmffu SIX 70S
430.9729 Pi4 *xpi*PCUS2
TSUUKIL* LABS  TfXtiLAB BLANK H23 TLI143432
39,00
         33:00       34:00       35:00       36:00       37:00       38:00
Pll»:U973264 tl-596 Acq:17-OCT-1997 22:01:31 OC JET* Voltaga SIR 70S
513.6775 Ft4 XxptXPCVS2
TRIAOOL* LABS  TfXttLAB BLANK M23 TLHH3432
                                                                                39:00
          33100
                     34100
                                 35:00
                                             36:00
                                                        37:00
                                                                    38100
                                                                                39100

-------
                      AS
    361 IB          36*24          36*30         36*36         36*42          36*48
Pll»*a973264 il-596 Aaq*17-OCT-1997 22t01t31  OC XH- Voltfgt SIR 703 Holm»:513
459.7348 P*4 B3UB(256,30,-3.O} PgD(7,5,3,0.lO*,2052.0,1.00X,P,T) SxptBPCUSS
TRIANOLS LAJUT  TfXttLAB BLUf H23 TLHf43432
loan
 80.

 60.

 40.

 20.
    36tl8          36t24         36i30         36t36          36t42         3Si48
Pll»iU973264 tl-596 JLcqi 17-CCT-1997 22t01t31 OC JET* Voltagu 3IR 703 Nolm»tS28
469.7779 Pl4 BSVB(256,30,-3.0) PXD(7,5,3,0.10\,2112.0,1.00\,P,T) gxptKPCUS2
TRUUX3LX LABS  TfXttlAB BLUf U23 TLX143432
100H                A1.99X7
             91-596 Acqt 17-tiCf-lHi>'7 22*01*31 OC SH- VOJitag* SIS  70S NOlt«t469
457.7377 Pit BSUB(256,30,-3.0) PXD(7,5,3,0,10*,1876.0,1.00\,P,r) Exp:EPCOS2
TRIAKOLS LABS  Tact:LAB BLAOC K23 TLI*43432
IOOH                A4.31B4
 80.

 60.

 40.

 30.
                                                                  A1.42S4
    36110          36t24         36t30         36:36          36:42       -36148
PilttU973264  tl-596 Acqi 17-OCT-1997 22:01:31 OC SX+ Voltmgt SIS 70S Soim»t459
471.7750 Pl4  B3UB(2S6,30,-3.0) PXD(7,5e3f0.10*,1836.0r1.00*,P,T) SxpigPCUS2
TSUUIOLM LJLB3  TfXttLAB BUHT JQ3  TLII43432
100H                12.3.3X7
    36:18          36:24         36:30         36:36          36:42
Pllu:U973264  tl-596 JLcqt 17-CCT-1997 22:01:31 OC SH- Voltagm SIX 703
430.9729 Pt4  Bxp:BPCUS2
         LABS  Text tLAB BLAMf M23  TLX*43432
                                                              36t42
                                                                                          36:54
                                                                                        A7.33S3
                                                                                          36:54
                                                                                          36:54
  80.

  60.

  40.

  20.

   0.
                      36:25
                                      36*32
                                                                         36*47
                                                                                  36*50
                                                                                                    -1.4E4

                                                                                                    .1.2S4

                                                                                                    '.8. 753

                                                                                                    .5.8E3

                                                                                                    .2.9S3
                                                                                                     O.OSO
                                                                                                        Tlmm
.1.424

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                                                                                                     ,0. 0X0
                                                                                                        tiam
                                                                                                    .6.6X6

                                                                                                    '.5.3X6

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                                                                                                    .1.3X6
    36*18
                   36*24
                                 36*30
                                                36*36
                                                              36*42
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                                                                                                        rim*
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    Vim*



 .1.4X6

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 .8.1X5

 .5.4X5

 .2.7X5

 .0.0X0
    Tim*

-------
Peak Locate Examination:17-OCT-1997:21:59 File:U973264

-------
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%                               36;25
 80 J
 60 J
 40 J
 20J
                                                                                        _5.5E3
                                                                                           7E4
                                                                                           2E4
                                                                                           6E4
    35124 35I36
                       36:00  36:12  36:24  36:36  36:48 37:00 37:12 37:24 37:36 37:48 38:00
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EH- Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
                                    36:26
100%
 80 J
 60 j
 40 J
 20J
                                                                3723
       35-30
                                                                                   54
                                                                                           OEO
                                                                                            Time
7E4
2E4
6E4
                                                                                        _5.4E3
    35I24 35136 35148  36166
                                   36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
                                                                                           OEO
                                                                                            Time
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES,  INC.
100%
36:25
A


l{
35l24 35\36 35\48 36166 36li2 36124 3el36 36\48 37166 37li2 37l24 37136 37148 38166
6.6E6
.5.3E6
_3.9E6
_2.6E6
L1.3E6
:O.OEO
Time

-------
File;U973264 #1-596 Acq;17-OCT-1997 22:01:31 GC El+ Voltage SIR 703
457.7377 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                              A3.22E4
 60J
 40J
 20J
    35:24 35:36  35:48  36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48  38:00
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                               A3.85E4
 80.:
 60 J
 40 j
 20J
                                                                                         2 . 7E4
                                                                                         L2.2E4
                                                                                         _1.6E4
                                                                                         L1.1E4
                                                                                         _5.5E3
                                                                                         O.OEO
                                                                                            Time
                                                                                          2.7E4
                                                                                         L2.2E4
                                                                                         Ll.6E4
                                                                                         L1.1E4
                                                                                         L5.4E3
                                                                                         .0. OEO
                                                                                            Time
    35:24 35:36  35:48  36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36  37:48  38:00
File:U973264 #1-596 Acq:17-OCT-1997 22:01:31 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS2
Sample Text:LAB BLANK M23 TLI#43432 File Text:TRIANGLE LABORATORIES, INC.
100%                               36:25                                                  6.6E6
 80J                                 A                                                 L5.3E6
 60J                                   I                                                 L3.9E6
 40J                                 I  1                                                 L2.6E6
 20J                                 /  I                                                 L1.3E6
    35:24 35:36  35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24  37:36
                                                                              37:48 38:00
                                                                                         LO.OEO
                                                                                            Time
                                                                                                     00

-------
CALIBRATION
      DATA
            Triangle Laboratories, Inc.
      801 Cap/to/a Drive       P.O. Box 13485
      Durham, NC 27713-4411     Research Triangle Park, NC 27709-3485
      919-544-5729         Fax # 919-544-5491

-------
 3ate: 10/18/97
       TRIANGLE LABORATORIES,  INC.
     Continuing Calibration Cor  X973633
 Analysis Date	:  10/18/97
 Operator	:  WK
 Init Calibration.:  XF24087
 ICal Date	:  04/08/97
 Analysis Time	:  10:55
                           Method	: C2NF
                           Instrument..: X
                           Std.Cone	:       5.00

                           GC Column...: DB-225
 Analyte Summary
 Name

 2378-TCDF

 TOTAL TCDF

 2378-TCDD

 TOTAL TCDD
 RF   Ratio
RT
             ICal   Delta
RT   Rel.  RT  RF      RF    %D
       1&2    Lo/High
1.079  0.77    19:36  24:34 1.0007   0.967  0.112  11.6%
               27:18
1.079  0.77                         0.967  0.112  11.6%

1.265  0.75    20:25  23:01 1.0000   1.095  0.170  15.5%
               26:21
1.265  0.75                         1.095  0.170  15.5%
 Other Standard Sumnary
 Name               RF   Ratio
                          1&2
 37C1-TCDD         1.062
                                   ICal   Delta
                RT     RT   Ral. RT  RF      RF    %D
              Lo/High
               21:01  23:02 1.0007   1.018  0.044   4.3%
               25:01
 Internal Standard Sumnary
 Name               RF   Ratio
                          1&2
 13C12-2378-TCDF   1.495  0.80

 13C12-2378-TCDD   1.011  0.79
                                   ICal   Delta
                RT     RT   Rel. RT  RF      RF    %D
              Lo/High
               23:33  24:33 1.0000   1.392  0.103   7.4%
               25:33
               21:01  23:01 1.0000   1.105 -0.094  -8.5%
               25:01
 Recovery Standard Summary
 Name               RF   Ratio
                          1&2
 13C12-1234-TCDD   1.000  0.81
                                   ICal   Delta
                RT     RT   Rel. RT  RF      RF    %D
              Lo/High
                      23:19 1.0130   1.000  0.000   0.0%
                                 Page
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 12:50 10/18/97

-------
 Dace: 10/22/97
       TRIANGLE LABORATORIES.  INC.
     Continuing Calibration for X973676
 Analysis Date	:  10/22/97
 Operator	:  GG
 Init Calibration.:  XF24087
 ICal Date	:  04/08/97
 Analysis Time....:  11:06
 Analyte Summary
 Name

 2378-TCDP

 TOTAL TCDF

 2378-TCDD

 TOTAL TCDD
 RF   Ratio
RT
    Method	:  C2NF
    Instrument.. :  X
    Std.Conc	:       5.00

    GC Column...:  DB-225

             ICal    Delta
RT   Rel. RT  RF     RF    %D
       1&2    Lo/High
1.002  0.78    19:26  24:19 1.0014   0.967  0.035   3.6%
               27:00
1.002  0.78                          0.967  0.035   3.6%

1.038  0.69    20:14  22:49 1.0000   1.095  -0.057  -5.2%
               26:05
1.038  0.69                          1.095  -0.057  -5.2%
 Other Standard Summary
 Name               RF   Ratio
                          1&2
 37C1-TCDD         1.001
                                    ICal   Delta
                RT     RT   Rel. RT  RF     RF    %D
              Lo/High
               20:49  22:49 1.0000   1.018  -0.017  -1.7%
               24:49
 Internal Standard Sumnary
 Name               RF   Ratio
                          1&2
 13C12-2378-TCDF   1.228  0.77

 13C12-2378-TCDD   0.975  0.78
                                    ICal   Delta
                RT     RT   Rel. RT  RF     RF    %D
              Lo/High
               23:17  24:17 1.0000   1.392 -0.164 -11.8%
               25:17
               20:49  22:49 1.0000   1.105 -0.130 -11.8%
               24:49
 Recovery Standard Summary
 Name               RF   Ratio
                          1&2
 13C12-1234-TCDD   1.000  0.79
                                    ICal   Delta
                RT     RT   Rel. RT  RF     RF    %O
              Lo/High
                      23:06 1.0124   1.000  0.000   0.0%
                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 11:58 10/22/97

-------
 Date: 10/17/97
TRIAKSLE LABORATORIES OF RTF,  INC.
 Continuing Calibration for U973252

Init Calibration.
ICal Date 	
Analyte Summary
Name
• GG
Tn at rumen t -
: UF59167
• 09/17/9?

RF

Std.Conc



. : O


ICal
Ratio
1&2
Total MCDF

Total MCDD

Total DCDF

Total DCDD

Total TriCDF

Total TriCDD

2378-TCDF

TOTAL TCDF
2378-TCDD

TOTAL TCDD
12378-PeCDF

23478-PeCDF
TOTAL PeCDF
12378 -PeCDD

TOTAL PeCDD
123478-HXCDF

123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HXCDD

123678-HxCDD

0.000

0.000

0.000

0.000

0.000

0.000

1.159

1.159
1.022

1.022
1.206

1.267
1.237
1.390

1.390
1.083

1.399
1.070
1.037
1.147
0.721

0.839













0.

0.
0.

0.
1.

1.
1.
1.

1.
1.

1.
1.
1.












74

74
67

67
53

51
52
61

61
23

25
24
24
RT
Lo/High
1:37
15:37
2:32
16:32
8:37
16:37
9:32
17:32
12:37
19:37
14:32
20:32
17:35
23:55

19:06
23:55

23:51
28:21


25:21
28:13

28:58
31:47



RT Rel. RT





RF

2

2


.585

.303

0.892







21:38 1.0008


22:32 1.0000


26:20 1.0006

27:08 1.0310

27:31 1.0000


30:10 0.9972

30:16 1.0006
30:48 1.0182
31:32 1.0424
1.24
1.

1.

26

25

29:31
31:27

Page
30:56 0.9978

31:01 1.0005
1

1

0

0

1

1
1

1
1

1
1
1

1
1

1
1

.770

.250

.000

.077

.077
.210

.210
.109

.138
.124
.382

.382
.212

.541
.267
1.207
1
0

1

.307
.857

.071





50.


00




Delta
RF

-2

-2

-0

-1

-0

0

0

0
-0

-0
0

0
0
0

0
-0

-0
-0
-0
-0
-0

-0


.585

.303

.892

.770

.250

.000

.082

.082
.188

.188
.097

.129
.113
.008

.008
.129

.142
.197
.170
.160
.136

.232

%D

100.

100.

100.

100.

100.

100.

7.

7.
-15.

-15.
8.

11.
10.
0.

0.
-10.

-9.
-15.
-14.
-12.
-15.

-21.



0%

0%

0%

o*

0%

0%

6%

6%
6%

6%
8%

4*
0%
6%

6%
6%

2%
6%
1%
2%
9%

6%
....
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                             Printed:

-------
Dace: 10/17/97
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF

OCDD






TRIANGLE LABORATORIES OF RTF, INC.
Continuing Calibration for O973252
0.906 1.20 31:19 1.0102 1.042
0.822 1.23 0.990
1.348 1.02 32:54 33:03 1.0005 1.467
34:27
1.141 1.00 34:16 1.0373 1.241
1.245 1.01 1.354
0.957 1.03 33:09 33:55 1.0000 1.012
34:05
0.957
1.427

1.039

1.03
0.89

0.84


32:27
40:27
32:27
40:27

36:34

36:27


1.0032

1.0000

Other Standard Summary
Name

37C1-TCDD

13C12-PeCDF

13C12-HXCDF
13C12-HXCDF
13C12-HXCDF
13C12 -HxCDD
13C12 -HpCDF





234

478
234
789
478
789

Internal Standard
Name



13C12-2378-TCDF


13C12-2378-TCDD

13C12-PeCDF

13C12-PeCDD

13C12-HXCDF

13C12 -HxCDD


123

123

678

678

RF

0.927

0.992

0.921
0.863
0.807
0.913
0.904

Ratio
1&2


1.55

0.52
0.52
0.52
1.21
0.42

RT
Lo/High
20:32
24:32
22:19
30:19




31:02
37:02
RT

22:33

27:08

30:09
30:47
31:31
30:55
34:15

Rel. RT

1.0007

1.0310

0.9967
1.0176
1.0419
0.9973
1.0368

Summary
RF

1.128

1.074

0.963

0.448

1.070

0.949

Ratio
1&2
0.78

0.82

1.49

1.46

0.52

1.19

RT
Lo/High
20:37
22:37
20:32
24:32
22:19
30:19
23:31
31:31
26:15
34:15
30:00
32:00
RT

21:37

22:32

26:19

27:31

30:15

31:00

Rel. RT

1.0000

1.0000

1.0000

1.0000

1.0000

1.0000

1.
1.

1.

012
308

077

ICal
RF

0.

0.

0.
0.
0.
0.
0.



944

970

974
941
886
897
883

ICal
RF

1.

1.

1.

0.

1.

0.



390

109

094

600

102

962

-0
-0
-0
-0
-0
-0
-0
0

-0

.137
.168
.119
.100
.109
.055
.055
.119

.038

-13.1%
-17.0%
-8.1%
-8.0%
-8.1%
-5.4%
-5.4%
9.1%

-3.6%

Delta


-0

0

-0
-0
-0
0
0

RF

.017

.022

.053
.078
.079
.016
.021

%D

-1.8%

2.2%

-5.5%
-8.2%
-9.0%
1.8%
2.4%

Delta


-0

-0

-0

-0

-0

-0

RF

.262

.035

.131

.152

.032

.013

%D

-18.9%

-3.1%

-11.9%

-25.3%

-2.9%

-1.3%

                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
 'hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1

-------
 Data: 10/17/97        TRIANGLE LABORATORIES OF RTF, INC.
                        Continuing Calibration for U973252
 13C12-HpCDF 678   0.835  0.43    31:02  33:02 1.0000   0.953 -0.118 -12.4%
                                  37:02
                                  32:55  33:55 1.0000   0.918 -0.085  -9.3%
                                  34:55
                                  36:17  36:27 1.0000   0.763 -0.138 -18.0%
                                  36:37
13C12-H&CDD 678   0.833   1.01

13C12-OCDD        0.625   0.85
 Recovery Standard Sunsnary
 Name               RF   Ratio
                                  RT
                          1*2    Lo/Hign
 13C12-1234-TCDD   1.000   0.80

 13C12-HXCDD 789   1.000   1.18
              ICal   Delta
 RT   Rel.  RT  RF      RF    %D

22:18 0.9896   1.000  0.000   0.0%

31:18 1.0097   1.000  0.000   0.0%
                       QC Front End Check:
                                              1.1102
                                  Page
Trianglo Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491

-------
   ite:  '10/23/97
  TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976907

.
lit Calibration.:
lal Date 	
lalyte Summary
ime

Total MCDF

>tal MCDD

Total DCDF

>tal DCDD

Total TriCDF

Jtal TriCDD

2378-TCDF

JTAL TCDF
3378-TCDD

JTAL TCDD
•"2378-PeCDF

_J478-PeCDF
""JTAL PeCDF
_2378-PeCDD

"•JTAL PeCDD
^..23478 -HxCDF

" 73678 -HxCDF
^34678-HxCDF
23789 -HxCDF
lOTAL HxCDF
23478-HxCDD

123678-HxCDD

•^ w/ «^
GO
Instrument .
SF56117
Ofi/10/
-------
Date: ,10/23/97
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF

OCDD






Other Standard
Name

37C1-TCDD

13C12-PeCDF

13C12-HXCDF
13C12-HxCDF
13C12-HXCDF
13C12- HxCDD
13C12- HpCDF





234

478
234
789
478
789

1
0
1
1
1
0
0
1

1

TRIANGLE LABORATORIES, INC.
Continuing Calibration for S976907
.025 1.22 29:43 1.0102 1.091
.995 1.24 1.059
.489 1.02 31:15 31:25 1.0005 1.543
32:46
.148 1.10 32:36 1.0382 1.184
.319 1.06 1.363
.999 1.05 31:30 32:15 1.0005 1.068
32:25
.999
.728

.049

1.05
0.91

0.86


30:44
38:44
30:44
38:44

34:51

34:44


1

1


.0034

.0000

Summary


0

0

0
0
0
0
0

RF

.929

.988

.940
.860
.789
.940
.792

Ratio
162


1.59

0.51
0.52
0.52
1.21
0.41

RT
Lo/High
19:34
23:34
21:00
29:00




29:24
35:24
RT

21:35

25:44

28:36
29:13
29:56
29:20
32:36

Rel. RT

1

1

0
1
1
0
1


.0008

.0293

.9965
.0180
.0430
.9972
.0382

Internal Standard Summary
Name



13C12-2378-TCDF


13C12-2378-TCDD

13C12-PeCDF

13C12-PeCDD

13C12-HXCDF

13C12- HxCDD


123

123

678

678



1

1

1

0

1

1

RF

.378

.047

.060

.617

.418

.036

Ratio
162
0.71

0.80

1.50

1.52

0.52

1.19

RT
Lo/High
19:47
21:47
19:34
23:34
21:00
29:00
22:06
30:06
24:42
32:42
28:25
30:25
RT

20:47

21:34

25:00

26:06

28:42

29:25

Rel. RT

1

1

1

1

1

1


.0000

.0000

.0000

.0000

.0000

.0000

1.068
1.493

1.105

ICal
RF

0.843

0.970

0.959
0.926
0.805
0.973
0.771

ICal
RF

1.318

1.066

1.133

0.635

1.204

0.995

-0.066
-0.064
-0.054
-0.036
-0.044
-0.069
-0.069
0.235

-0.056

Delta
RF

0.086

0.018

-0.019
-0.066
-0.016
-0.033
0.021

Delta
RF

0.060

-0.019

-0.073

-0.018

0.214

0.041

-6.0%
-6.0%
-3.5%
-3.0%
-3.2%
-6.5%
-6.5%
15.8%

-5.1%


%D

10.2%

1.9%

-2.0%
-7.2%
-2.0%
-3.4%
2.7%


%D

4.6%

-1.8%

-6.5%

-2.9%

17.8%

4.1%

                                Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:06 10/23/97

-------
 Date: 10/23/97           TRIANGLE LABORATORIES,  INC.
                        Continuing Calibration for S976907
 13C12-HpCDF 678   0.960  0.44    29:24  31:24 1.0000    0.887  0.073   8.3%
                                  35:24
                                  31:14  32:14 1.0000    0.815  0.032   3.9%
                                  33:14
                                  34:34  34:44 1.0000    0.519 -0.129 -24.9%
                                  34:54
13C12-HpCDD 678   0.847  1.01

13C12-OCDD        0.390  0.93
 Recovery Standard Summary
 Name               RF   Ratio
                                   RT
                                                      ICal   Delta
                                         RT    Rel. RT   RF       RF
%D
                          162    Lo/High
 13C12-1234-TCDD   1.000  0.86

 13C12-HXCDD 789   1.000  1.23
                                        21:22  0.9907    1.000   0.000    0.0%

                                        29:42  1.0096    1.000   0.000    0.0%
                       QC Front End Check:
                                              1.9799
                                 Page   3
.Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
      : (919) 544-5729 • Fax: (919) 544-5491
                                                                                   Printed: 17:0610/23/97

-------
                           TRIANGLE LABORATORIES, INC.
                      Initial Calibration Summary for SF56117
Date: 06/10/97
Instrument 	 :
Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378 -TCDD
TOTAL TCDD
12378 -PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789 -HxCDF
TOTAL HxCDF
123478 -HxCDD
123678 -HxCDD
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HxCDF 478
13C12 -HxCDF 234
13C12-HXCDF 789
13C12-HXCDD 478
13C12- HpCDF 789
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12- PeCDF 123

s
'/ *•*-,
f -«•
RF
2.
1.
0.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
087
625
687
326
082
933
251
251
191
191
111
115
113
256
256
215
574
247
105
285
953
133
091
059
543
184
363
068
068
493
105
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
0.
0.
0.
0.
0.
0.
0.
843
970
959
926
805
973
771
0
0
0
0
0
0
0
RF
1.
1.
1.

318
066
133

0
0
0


SD
.000
.000
.000
.000
.000
.000
.116
.116
.231
.231
.082
.061
.069
.113
.113
.064
.099
.069
.060
.062
.067
.070
.067
.067
.103
.100
.095
.089
.089
.131
.066
SD
.038
.030
.042
.021
.044
.027
.049
SD
.065
.020
.051


%RSD
0%
0%
0%
0%
0%
0%
9%
9%
19%
19%
7%
5%
6%
9%
9%
5%
6%
6%
5%
5%
7%
6%
6%
6%
7%
8%
7%
8%
8%
9%
6%
%RSD
5%
3%
4%
2%
5%
3%
6%
%RSD
5%
2%
5%
Page

RT
8:15
8:42
10:38
11:09
13 : 59
14:03
19:43

20:36

24:12
24:59

25:22

27:55
28:01
28:32
29:15

28:41
28:46
29:03

30:45
31:57

31:37

34:09
34:03
RT
20:36
24:58
27:55
28:32
29:15
28:40
31:57
RT
19:43
20:34
24:11
1

RT/LO
0:01
0:34
6:43
7:34
10:43
12:34
15:43

16:34

20:11


21:21

24:01




24:45



26:45


27:36

30:02
30:02
RT/LO
18:34
22:11




28:45
RT/LO
18:43
18:34
20:11



RT/HI
13:43
14:
14:
15:
34
43
34
17:43
18:
23:

24:

28:


29:

32:




32:



34:


35:

38:
38:
34
43

34

11


21

01




45



45


36

02
02
RT/HI
22:
26:




34:
34
11




45
RT/HI
20:
22:
28:

43
34
11



Ratlol Ratio2
2.
2.
5.
1.
1.
1.
0.
0.
0.
0.
1.
1.
1.
1.
1.
931
827
965
609
025
064
799
799
772
772
552
470
509
526
526
1.247
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
260
243
246
249
265
251
233
249
034
080
053
993
993
876
902
Ratiol Ratio2

1.
0.
0.
0.
1.
0.

470
518
517
519
241
424
Ratiol Ratio2
0.
0.
1.

734
802
447

                                                                               N
                                                                               1
                                                                               1
                                                                               1
                                                                               1
                                                                               1
                                                                               1
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               S
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               5
                                                                               S
                                                                               5
                                                                               5
                                                                               5
                                                                               S
                                                                               5
                                                                               5
                                                                               5
                                                                               S
                                                                               5
                                                                               5

                                                                               N
                                                                               5
                                                                               5
                                                                               5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                 Printed: 09:49 06/10/97

-------
                           TRIANGLE LABORATORIES, INC.             Date:  06/10/97
                       Initial Calibration Summary for SFS6117
  13C12-PeCDD 123     0.635 0.082   13%    25:21  21:21  29:21   1.461           5
  13C12-HXCDF 678     1.204 0.073    6%    28:01  24:01  32:01   0.522           5
  13C12-HxCDD 678     0.995 0.017    2%    28:45  27:45  29:45   1.240           5
  13C12-HpCDF 678     0.887 0.046    5%    30:45  28:45  34:45   0.429           5
  13C12-HpCDD 678     0.815 0.077    9ft    31:36  30:36  32:36   1.019           5
  13C12-OCDD          0.519 0.080   15%    34:02  32:02  36:02   0.866           5

  Recovery  Standards   RF     SD   %RSD      RT   RT/LO  RT/HI  Ratiol  Ratio2   N
  13C12-1234-TCDD     1.000 0.000    0%    20:21                 0.811           5
  13C12-HXCDD 789     1.000 0.000    0%    29:02                 1.231           5

  ***  End of  Report •**
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713                                        Printed: 09:49 06/10/97
3hone: (919) 544-5729 • Fax: (919) 544-5491

-------
                        TRIANGLE LABORATORIES OF RTP, INC.
                      Initial Calibration Summary for UF59167
Date: 09/17/97

Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDP
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-P*CDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HxCDD
123678-HxCDD
123789-HXCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Oth*r Standards
37C1-TCDD
13C12-P«CDF 234
13C12-HXCDF 478
13C12-HXCDF 234
13C12 -HxCDF 789
13C12-HXCDD 478
13C12-HpCDF 789
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12-P*CDF 123

u
RF
2
2
0
1
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
0
1
1
1
1
1
1
1
.585
.303
.892
.770
.250
.000
.077
.077
.210
.210
.109
.138
.124
.382
.382
.212
.541
.267
.207
.307
.857
.071
.042
.990
.467
.241
.354
.012
.012
.308
.077
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
0
0
0
0
0
0
0
.944
.970
.974
.941
.886
.897
.883
0
0
0
0
0
0
0
RF
1
1
1

.390
.109
.094

0
0
0

SD
.566
.263
.121
.150
.000
.000
.056
.056
.179
.179
.022
.080
.040
.159
.159
.049
.067
.111
.061
.069
.045
.039
.020
.032
.037
.084
.051
.044
.044
.078
.039
SD
.015
.043
.026
.046
.036
.023
.031
SD
.117
.027
.045

%RSD
22%
11%
14%
8%
0%
100%
5%
5%
15%
15%
2%
7%
4%
12%
12%
4%
4%
9%
5%
5%
5%
4%
2%
3%
3%
7%
4%
4%
4%
6%
4%
%RSD
2%
4%
3%
5%
4%
3%
4%
%RSD
8%
2%
4%
Pag*
RT
9:04
9:40
12:12
12:53
11:49

23:33

24:20

27:49
28:33

28:55

31:27
31:33
32:03
32:47
RT/LO
3:32
4:20
10:32
11:20
14:32
16:20
19:32

20:20

23:48


24:54

27:32



RT/HI
17:32
18:20
18:32
19:20
21:32
22:20
27:32

28:20

31:48


32:54

35:32



Ratiol Ratio2
3
2
6
1
0

0
0
0
0
1
1
1
.578*
.804
.782
.518
.237*

.752
.752
.738
.738
.480
.470
.474
1.548
1
1
1
1
1
.548
.293
.256
.271
.260
1.268
32:10
32:15
32:33

34:14
35:29

35:06

37:59
37:50
RT
24:20
28:32
31:26
32:02
32:46
32:09
35:28
RT
23:32
24:20
27:48
1
28:14



30:14


31:05

33:50
33:50
RT/LO
22:20
25:48




32:14
RT/LO
22:32
22:20
23:48

36:14



38:14


39:05

41:50
41:50
RT/HI
26:20
29:48




38:14
RT/HI
24:32
26:20
31:48

1
1
1
1
1
0
1
1
1
0
0
.272
.236
.258
.254
.045
.993
.020
.031
.031
.899
.839
Ratiol Ratio2

1
0
0
0
1
0

.421
.514
.511
.515
.197
.427
Ratiol Ratio2
0
0
1

.746
.805
.441

N
5
5
5
5
2
0
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
N
5
5
5
5
5
5
5
N
5
5
5

Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                  Printed: 14:02 09/17/97

-------
                         TRIANGLE LABORATORIES OF RTF,  INC.         Date: 09/17/97
                       Initial Calibration Sumnary  for  j*?59167
  13C12-PeCDD 123     0.600 0.047    8%    28:54  24:54  32:54   1.424           5
  13C12-HXCDP 678     1.102 0.047    4%    31:32  27:32  35:32   0.520           5
  13C12-HXCDD 678     0.962 0.014    1%    32:14  31:14  33:14   1.207           5
  13C12-HpCDP 678     0.953 0.050    5%    34:14  32:14  38:14   0.420           5
  13C12-HpCDD 678     0.918 0.029    3%    35:05  34:05  36:05   1.030           5
  13C12-OCDD          0.763 0.065    9*    37:50  35:50  39:50   0.856           5

  Recovery Standards   RF     SD   %RSD     RT   RT/LO  RT/HI  Ratiol  Ratio2   N
  13C12-1234-TCDD     1.000 0.000    0*    24:08                 0.820           5
  13C12-HXCDD 789     1.000 0.000    0*    32:32                 1.210           5

  *** End of Report ***
                                   Page    2
Trianglo Laboratories, Inc.®  Analytical Services Division
n01 Caprtola Drive • Durham, North Carolina 27713                                         Printed-14-02 09/17/97

-------
                          TRIANGLE LABORATORIES, INC.
                     Initial Calibraeion Sumnary Cor XF24087
                                              Date:  04/09/97
 Analysis Dace	: 04/08/97
 Instrument	: X
                          Method	:  C2NF
                          GC Column...:  DB-225
 Analycas
 2378-TCDF
 TOTAL TCDF
 2378-TCDD
 TOTAL TCDD
 RF     SO   %RSD
0.967 0.044    5%
0.967 0.044    5%
1.095 0.097    9%
1.095 0.097    9%
  RT   RT/LO  RT/HI  Raciol   RaCio2   N
21:49  14:49   25:49    0.779
                      0.779
20:37  16:36   24:36    0.793
                      0.793
10
10
10
10
 Other Standards
 37C1-TCDD
 RF     SD   %RSD      RT   RT/LO  RT/HI  Ratiol  Ratio2   N
1.018 0.047    5%    20:37  18:36  22:36                 10
  Internal Standards  RF      SD   %RSD      RT   RT/LO  RT/HI  Ratiol
  13C12-2378-TCDF     1.392  0.071     5%    21:49  20:49  22:49   0.787
  13C12-2378-TCDD     1.105  0.037     3%    20:36  18:36  22:36   0.783
                                                  Ratio2
                                                          N
                                                         10
                                                         10
  Recovery Standards  RF      SO   %RSD
  13C12-1234-TCDD     1.000  0.000    0%

  ***  End of Report ***
                       RT   RT/LO  RT/HI  Ratiol  Ratio2   N
                     20:50                 0.796          10
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 02:46 04/09/97

-------
    Appendix B.2




   Analytical Data





-------
-  Vr
                                  CASE NARRATIVE
                         Analysis of Samples for the Presence of

                                 Semivolatile Analytes by

       High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
                             METHOD 8270A Rev. 1 (7/92)
                  Date:
November 13,1997
                  Client ID
Pacific Environmental Services
                  TLI Project Number :   43433
      This report should only be reproduced in full. Any partial reproduction of this report requires permission from
      Triangle Laboratories, Inc.
                                                 Triangle Laboratories, Inc.
                                       801 Cap/to/a Drive           P.O. Box 13485
                                       Durham, NC 27713-4411        Research Triangle Park, NC 27709-3485

-------
TRIANGLE LABORATORIES, INC.                          November 13,1997
CASE NARRATIVE                                                     43433

Objective: Analysis of six MM5 train samples for Method 8270 polynuclear aromatic
hydrocarbon (PAH) and Clean Air Act (CAA) semivolatile compounds.
Method:

Six MM5 train samples were received by Triangle Laboratories, Inc. on ice at 3°C on September
29,1997. Although a condensate was listed on the client chain-of-custody (COC) for sample SO-
MM5-1, no condensate was received for that sample. In addition, the Lab Blank sample was not
listed on the client COC.  The samples were stored in a cooler at 4°C prior to extraction. The
XAD traps used for sampling were pre-spiked with 100 micrograms (ug) of terphenyl-dn prior to
sampling. Prior to extraction, the XAD, filter, and rinses were spiked with 100 ug of phenol-ds,
2,4,6-tribromophenol, l,4-dibromobenzene-d4, and pyrene-dio.  These portions of the MM5 trains
were Soxhlet extracted with methylene chloride for 16 hours. The impinger condensates, when
present, were spiked with 100 ug of the surrogate standards anthracene-dlO, 2-fluorobiphenyl,
nitrobenzene-ds  and l.S.S-trichlorobenzene-da before being extracted with methylene chloride
using a separatory funnel. The extracts were combined and brought to a final volume of 1.0 mL
for the semivolatile analysis. The analysis is based on the guidelines of Method 8270A Rev. 1
(7/92).  The results reported relate only to the items tested.

The internal standards, l,4-dichlorobenzene-d4, naphthalene-dg, acenaphthene-dio, phenanthrene-
dio, chrysene-di2, and perylene-dja, were added to the extracts such that the final internal standard
concentration was 40 ug/mL immediately prior to analysis by GC/MS.

The GC/MS analysis conditions are listed below:

GC Conditions:
  Column:                              J&W DB5-625, 30m x .32mm x lum
  Program:                              35C, ramp at 12C/min to 285C, hold for 2 min.
                                       ramp at 8.5C/min to 315 C, hold for 6.5 min.
  Carrier Gas:                           Helium

MS Conditions:
  Instrument:                            HP MSD, Chemsystem and Target data systems
  Scan:                                 35-550 amu at 1.67 scan/sec
  Interface:                              Capillary, Injector:  250C, Detector:  275C
Report:

Enclosed with the case narrative are the sample identification index, project summary sheets,
client and TLI chain of custody sheets, wet laboratory extraction information sheets, GC/MS
tracking forms, and analytical run logs. The sample identification index correlates the client
sample name, TLI sample number and the analytical file name for the each sample. The project
summary sheets list the amounts of analytes detected in gray and list the estimated detection limits
in parentheses for analytes which were not detected.

-------
TRIANGLE LABORATORIES, INC.                          November 13,1997
CASE NARRATIVE                                                        43433

The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target analytes. The quantitation report header lists the TLI project number, analysis
method, instrument sample file name, and client sample name. The client project number, TLI
sample number, calibration file, dilution factor, and date received, extracted, and analyzed are also
listed in the quantitation report header. The response factors used for all calculations are from the
continuing calibration listed in the header. All initial and continuing calibration data are located in
the back of the data package.  The amount reported for each target analyte detected in the
samples is reported in total ug. The retention time (RT) will be listed for all internal standards
and analytes which are detected. If a target analyte is not detected, it will be flagged with a "U"
and a detection limit will be listed. Estimated detection limits are calculated using an area of
10,000 for all analytes which were not found in the samples. The estimated detection limits
reported are the average detection limits achievable over time on an instrument type. The actual
detection limit for a given compound on a given day may vary from the estimate reported.  The
quantitation limit for all analytes is half of the low point of the initial calibration adjusted for
dilution when appropriate. Below this point the calibration cannot be considered to be linear.
Any amounts reported at a level below the quantitation limit will be flagged with a "J" and should
be considered estimated. If a target analyte is found at a level exceeding the upper calibration
limit, it will be flagged with an "E" and should also be considered estimated. Any analytes flagged
with a "B" on the sample topsheets were detected in the associated laboratory blank. All target
analytes are quantitated against the internal standard preceding them on the target analyte list.
Surrogate standards are quantitated against the internal standard with the matching internal
standard reference number. For example, phenol-ds  has 1 in the IS Ref column and would be
quantitated against the internal standard which has IS1  listed in the flag column. If an internal
standard area is above or below the quality control limits as defined by the continuing calibration,
it will be flagged with "High" or "Low" in the flag column.

Immediately following the quantitation report are two pages which comprise the total ion chro-
matograms. Labeled internal and surrogate standards present in the sample have their identifica-
tions and retention time printed above their peak on the chromatogram.  The chromatogram is
followed by the interim report. On the interim report a $ is indicative of a surrogate standard and
a * represents an internal standard. The interim report  from the instrument is followed by the
target spectra of detected compounds. Four spectral  plots are included for each compound: a raw
spectrum of the peak, a background subtracted version of the same spectrum, a library spectrum
of the compound, and a plot showing the percent difference between the library spectrum and the
background subtracted spectrum. Extracted ion current profiles are plotted on the right-hand side
of the page showing the quantitation mass and one or two other prominent ions known to be
present in target compound as they appear in the sample peak.
Results:

All samples were extracted outside the fourteen day sampling to extraction holding time. All
samples and blanks were analyzed within the extraction to analysis holding time.

Please note that several target analytes were found at levels below the quantitation limit in the
laboratory blank. These analytes should not be considered truly present in the native samples

-------
TRIANGLE LABORATORIES, INC.                         November 13,1997
CASE NARRATIVE                                                     43433

is twenty times the level in the blank, the blank contribution can be considered statistically
insignificant.

The internal standard area for perylene-d!2 was outside Method 8270 quality control limits in
samples SO-MM5-2-17 and SO-MM5-4-51. These internal standards were flagged with "IS
High" and the amounts quantitated against them should be considered estimated.

Each sample was processed twice, once against the calibrations containing the PAH compounds
and once against the calibrations containing CAA compounds. Therefore, each sample reported
contains topsheets and interim reports for both the PAH and CAA analyses as well as a chroma-
togram and spectra for all analytes. Please note that the surrogate standards have been reported
from the PAH analyses only.

All surrogate standard percent recoveries were within in-house quality control limits as defined by
the following 95 percent confidence intervals:
Surrogate Standards                   Mean        95% confidence interval

l,3,5-trichlorobenzene-d3                55                 22.19  - 87.75
l,4-dibromobenzene-d4                  69                 34.65  - 103.19
2,4,6-tribromophenol                    78                 32.43  - 123.81
2-fluorobiphenyl                        77                 37.70  - 115.87
anthracene-dio                          77                 37.45  - 116.75
nitrobenzene-ds                         68                 30.52  - 105.65
phenol-ds                              70                 28.39  - 112.40
pyrene-dio                             80                 33.65  - 126.15
terphenyl-d14                           77                 18.86  - 135.64
Sample Calculations:

Response Factor, RF =      Area analyte x Amt Is
                          Area IS x Amt analyte in the ccal

Amount ug =               Area analyte x Amt IS x DF
                          Area IS x RF
Where:

Amt IS = amount of internal standard = 40 ug
Amt analyte in the ccal = amount of analyte in the continuing calibration = 50 ug

-------
TRIANGLE LABORATORIES, INC.                        November 13,1997
CASE NARRATIVE                                                    43433
The data reported has been judged to be valid and in compliance with the guidelines of Method
8270A Rev. 1 (7/92) except as noted above. Should you have any questions about this project,
please feel free to contact our Project Scientist, Amy Boehm, at (919) 544-5729, extension 268.
For Triangle Laboratories, Inc.,

Report Preparation:                                  Quality Control:
Sarah A. Hubbard
Report Preparation Chemist                           Report Preparation Chemist

-------
                     TRIANGLE LABORATORIES, INC.

                 LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American Association for Laboratory Accreditation. Accredidation  pending.   Certificate
Number 0226-01.  Accreditation for technical competence in Environmental Testing.(lncluding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of  Environmental Management.  Expires  December 31,
1997. Laboratory I.D. # 40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation.  Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department  of  Health  Services.  Expires May  26,  1998.  Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department of  Pollution  Control and Ecology.  Expires February 1S,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.

State of California, Department of  Health Services.  Expires  August 31, 1999.  Certificate
#1922. Selected Metals in Waste Water; Volatiles. Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut, Department of Health Services. Recertification pending. Registration
# PH-0117.  Dioxin in drinking water.
                   V *

Delaware Health  and Social Services.  Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.

Florida Department of Health and Rehabilitative Services.  Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424.  Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC)  and Volatiles  (GC/MS) in  Environmental Samples.   Environmental water ID  HRS#
E87411.

Hawaii Department of Health.  Expires March 1,  1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
 Revised 10/28/97 RM
 Printed 10/29/97                         oni .  ., ,  Triangle Laboratories, Inc.
                                   801 Capitola Drive            P.O. Box 13485
                                   Durham, NC 27713-4411        Research Triangle Park, NC 2TZ09-3485

-------
Idaho Department of Health and Welfare.  Expires November 30, 1997. Dioxin in drinking
water.

State of Kansas, Department of Heajth  and Environment.  Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste.  Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste -E-1209.

Commonwealth  of Kentucky,  Department for  Environmental  Protection.   Expires
December 31, 1997. ID#90060. Dioxin in drinking water.

Maryland Department of Health and Mental Hygiene.   Expires September 30,  1998.
Certification #235. Drinking water by Method 1613A.

State of Michigan, Department of Public Health.  Expires June  3, 1998. Drinking water by
Method 1613.

Mississippi State Department of Health.  No expiration date..  Dioxin in drinking water.

Montana Department of Health and Environmental Services.  Expires December 31, 1997.
 Dioxin in drinking water.

State of New Jersey, Department of Environmental Protection  and Energy.  Extended by
state. Temporary certificate until December 31, 1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.

State of New Mexico,  Environment Department.  Recertification pending. Dioxin in drinking
water.

New York  State Department of Health.   Expires April 1, 1998.  ID #11026.  Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.

State of North  Carolina, Department of Environment Health  and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.

State of North  Carolina, Department of Environment, Health, and  Natural Resources,
Division of Environmental Management.  Expires December 31, 1997. Certificate # 485.
Metals,  pesticides & PCBs, semi-volatiles and volatiles; TCLP.

North Dakota  State  Department of Health and  Consolidated Laboratories.  Expires
December 31,  1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.    •—
 Revised 10/28/97 RM

 Printed 10/29/97

-------
Oklahoma  Department of Environmental Quality.  Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.

State of South Carolina, Department of Health and Environmental Control. Expires April 1,
1998. Certificate number #99040001 -(drinking water). Expires August 31, 1999.  Certificate  '
number #99040002 (other parameters). Dioxin/Furans, SNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.

State of Tennessee. Department of Environment and Conservation.  Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.

U.S. Department of Agriculture Soil  Permit.  Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission  is granted  to receive
foreign soil samples for use in laboratory analysis.

U.S. Army  Corps of Engineers.  Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockbourne Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.

U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.

U.S.  EPA Region  VIII, for the State  of Wyoming.  Expires November 13, 1997. Dioxin in
drinking water.

State of Utah, Department of Health.  Expires December 31, 1997. Certificate Number E-166.
Certification for the following parameters:  Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans  by  Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.

Commonwealth of Virginia, Department of General Services, Division  of Consolidated
Laboratory Services.  Expires June 30, 1998. ID # 00341. Dioxin in drinking water.

State of  Washington,' Department  of Ecology.   Expires  September 11, 1998.  Lab
Accreditation Number C067.  Scope of Accreditation  applies  to  water  analyses  for
Polychlorinated Dibenzo-p-dioxins and  Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.

State of Washington, Department of Health.  Expires April 30, 1998. Dioxin in drinking water.
  Lab I.D. 129

State of West Virginia, Department of Health.  Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
      10/28/97 RM

 PrintBd 10/29/97

-------
State of Wisconsin,  Department of  Natural  Resources.   Expires August 31,  1998.
Laboratory  ID  Number 999869530. Certification for the following  categories of Organics:
Purgeable, Base/Neutral, Acid, RGBs,  and Dioxin. Expires November 14, 1999. .Laboratory ID
999869530. Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement Agency (DEA).    Expires  November  30,  1997.  Registration  number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources.  Expires October 31, 1998.  Registration  number
NC-PT 0000 0031. North Carolina controlled substances registration.  Application submitted for
renewal.

Food &  Drug Administration  (FDA)  Registration.   Expires June  1998.  ID #'s  001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration.  Expires May 30,  1999.
ID  # 34D0705123.   Department  of  Health  &  Human  Services,  Health Care  Financing
Administration.

U.S. EPA Large Quantity Hazardous Waste Generator.    No expiration  date.   EPA  ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina Radioactive Materials License. Expires April 30  1998.  License No.  032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.

North Carolina General License for Radiation Protection.  No. expiration date. License No.
032-875-OG.  The  general license applies only  to radioactive material contained in  devices
which have been manufactured and labeled in accordance with specific requirements.
 Revised 10/28/97 RM


-------
                                        Triangle Laboratories of RTF
                                Sample Identification Index for Project: 43433
ClientTd:
SO-MM5-1-8
SO-MM5-2-17
SO-MM5-3-37
SO-MM5-4-51
FBI-MM5-1
LAB BLANK-MM5-28
SBLK101497
185-7-2A-C,E
185-7-3A-F
185-7-4A-F
185-7-5A-E
185-7-1A-D
185-7-6A-C
SBLK101497
YP788
YP789
YP790
YP791
YP775
YP774
YP773
 Triangle Laboratories of RTF, Inc.
 801 Capitola Drive • Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                      Proj_Sumv4.0

-------
                                           Triangle Laboratories of RTF
                                        Project Summary for Project 43433
Client ID:

ilename :
.11 Id :
Matrix :
Jnits :
SO-MM5-1-8

YP788
185-7-2A-QE
MM5
ug
SO-MM5-2-1
7
YP789
185-7-3A-F
MM5
«g
SO-MM5-3-3
7
YP790
185-7-4A-F
MM5
"g
SO-MM5-4-5
1
YP791
185-7-5A-E
MM5
"g
FBI-MM5-1
*
YP775
185-7-1A-D
MM5
"g
Naphthalene             J/L"'!lxcJE&S,L *Kt  ' Y-;'V•£1pM  7^ j^f ?,!2.14;     f 1 &;*&*''            (0-25)
 tenaphthene              ,    C   aiS             (0.44)  "/,'*""'4*4*   X,- "-^\^2;            (0.42)
Fluorene                    ,V *    ^^ A%,,, JUl*$&'   _  \,\\ 1$3     J""  "  ^5^7            (0.41)
nhenanthrene            'ss\  ,„„"  2.07   /  s si^^slllS,     -^f" "  1*77     '  %/,T ,1^7        "I-""'   &&.
 imthracene                  '\  ; \9M             (0.28)    **„   ,  0^4      /'*\%W»%            (0.31)
Fluoranthene            s {  " "-" '   &M    '     ,," t47             0*8&       s 1    * &91.            (0.29)
 >yrene                    ,\  ,     lift         A/,%,1^         %    1.05             0.9$            (0.26)
Jenzo(a)anthracene                (0.24)             (0.19)            (0.24)            (0.19)            (0.30)
Chrysene                   ,        0.22             (0.19)            (0.25)            (0.19)            (0.30)
 Jenzo(b)fluoranthene              (0.20)             (0.15)            (0.19)            (0.16)            (0.24)
Benzo(k)fluoranthene              (0.20)             (0.16)            (0.20)            (0.17)            (0.23)
T3enzo(e)pyrene                    (0.18)             (0.14)            (0.18)            (0.15)            (0.22)
 Jenzo(a)pyrene                    (0.21)             (0.16)            (0.20)            (0.17)            (0.25)
Perylene                          (0.20)             (0.16)            (0.19)            (0.16)            (0.23)
 ndeno(l,2/3-cd)pyrene             (0.18)             (0.14)            (0.17)            (0.15)            (0.22)
Jibenz(a,h)anthracene             (0.24)             (0.19)            (0.23)            (0.20)            (0.29)
Benzo(g,h,i)perylene               (0.20)             (0.16)            (0.19)            (0.16)            (0.24)
                                         ( )-Estimated Detection Limit    Page 1
Triangle Laboratories of RTF, Inc                                                                                 Savar v3.5

-------
                                          Triangle Laboratories of RTF
                                       Project Summary for Project 43433
Client ID:                   LAB BLANK-     SBLK101497
                            MM5-28
Filename :
TLJId :
Matrix :
Units :
YP774
185-7-6A-C
MM5
ug
YP773
SBLK101497
XAD
ug
Naphthalene                      (0.29)   ,-„  ^
2-Methylnaphthalene              (0.47)            (0.43)
2-Chloronaphthalene              (0.43)            (0.44)
Acenaphthylene                   (0.27)            (0.27)
Acenaphthene                    (0.45)            (0.45)
Fluorene                          (0.44)            (0.45)
Phenanthrene                     (0.32)            (0.29)
Anthracene                       (0.33)            (030)
Fluoranthene                     (031)            (0.29)
Pyrene                           (031)            (0.28)
Benzo(a)anthracene               (037)            (032)
Chrysene                         (037)            (033)
Benzo(b)fluoranthene              (0.36)            (030)
Benzo(k)fluoranthene              (0.34)            (0.29)
Benzo(e)pyrene                   (0.33)            (0.28)
Benzo(a)pyrene                   (0.37)            (031)
Perylene                          (034)            (0.28)
Indeno(l,23-cd)pyrene            (0.32)            (0.27)
Dibenz(a,h)anthracene             (0.43)            (0.36)
Benzo(g,h,i)perylene              (0.35)            (0.29)
                                        ( )-Estimated Detection Limit     Page 2
 Triangle Laboratories of RTF, Inc.                                                                               Savar v3.5
 801 Capitals Drive • Durham, North Carolina 27713                                                     Printed: 1721:40 11/13/97

-------
                                            Triangle Laboratories of RTF
                                        Project Summary for Project 43433
Client ID:

Filename :
mid :
Matrix :
Units :
h-Nitrosodimethylamine
Cumene
Phenol
Aniline
Benzyl Chloride
1 .4-Dichlorobenzene
SO-MM5-1-8

YP788
185-7-2A-C,E
MM5
ug
(1.49)
(0.38)
yvvvy
(0.50)
(0.39)
x"" ' ''"' Q»7J
SO-MM5-2-1
7
YP789
185-7-3A-F
MM5
ug
__(1^0)
:^* ?ifc&
(050)
(0.39)
< ~ ss, ' " 0J12
SO-MM5-3-3
7
YP790
185-7-4A-F
MM5
ug
_Jl-59)
>'^!tio* '
,%lj" "-" -V?"2i27.
' s'% ie3&
SO-MM5-4-5
1
YP791
185-7-5A-E
MM5
ug
	 _O39)v
'^;7:f;ym44 r;-
(0.46)
(0.36)
...Xv.....1-.., ....-.•• i-SO « :
FBI-MM5-1
"
YP775
185-7-1A-D
MM5
ug
(1-44)
(039)

(052)
(0.40)
i % % ;% 5 0^43
2-Methylphenol                     (0.86)
Acetophenone            ,,„" "        SJ£
n-Nitrosomorpholine               (1-44)
o-Toluidine                         (0.52)
Hexachloroethane                  (1-37)
l,2-Dibromo-3-chloropropane       (1-42)
N,N-Diethylaniline                 (0.51)
bis- (2-Chloroethyl) ether            (1.07)
3/4-Methylphenol                  (0.76)
Nitrobenzene                       (0.52)
N,N-Dimethylaniline               (0.50)
Isophorone                         (0.44)
o-Anisidine                         (0.91)
1,4-Phenylenediamine              (0.72)
1,2,4-Trichlorobenzene              (0.83)
Hexachlorobutadiene               (1.35)
a,a,a-Trichlorotoluene              (0.64)
Hydroquinone                     (0.76)
2-Chloroacetophenone         -     (0.35)
Hexachlorocyclopentadiene         (1-51)
2,4,6-Trichlorophenol               (1.29)
2,4,5-Trichlorophenol               (1.21)
Biphenyl                   "         2.13
Dimethylphthalate           ,,      %M
4-Nitrophenol            •          (1.72)
2,4-Dinitrotoluene                  (1-41)
Dibenzofuran                      (0.33)
4/6-Dinitro-2-methylphenol          (2.80)
Trifluralin                          (2.09)
(0.86)
                                    (0.82)
(1.44)
(0.52)
(1.37)
(1.43)
(0.51)
(1.07)
(0.76)
(052)
(0.50)
(0.44)
(0.92)
(0.73)
(0.83)
(1.36)
(0.64)
(0.77)
(0.35)
(1.50)
(1.21)
(154)
(0.56)
(1.46)
(1.52)
(0.55)
(1.14)
(0.81)
(0.56)
(054)
(0.47)
(0.98)
(0.78)
(0.89)
(1.45)
(0.69)
(0.82)
(0.38)
(1.57)
(1.34)
(1.26)
(1.34)
(0.49)
(1-27)
(1.32)
(0.48)
(0.99)
  6.99
(0.49)
(0.47)
(0-41)
(0.86)
(0.68)
(1.71)
(1.41)
(0.33)
(2.79)
(2.08)
,  2.2$
 (1.78)
 (1.47)
(1.27)
(0.60)
(0.72)
(0.33)
(1.40)
(1-20)
(1.12)
  2.50
  145
(1.59)
(131)
 (2.91)
 (2.18)
(2.60)
(1.94)
(1-44)
(0.52)
(1.35)
(1.43)
(0.49)
(1.11)
(0.83)
(0.52)
(0.53)
(0.44)
(0.95)
(0.69)
(0.80)
(1.37)
(0.65)
(0.71)
(0.35)
(1.34)
(1.22)
(1.06)
(0.33)
"""332
(1.79)
(1.38)
(0.30)
(3.05)
(2.22)
                                          (  )-Estimated Detection Limit    Page 1
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                        Savar v3.5
                                           Printed: 12:49:03 11/13/97

-------
                                            Triangle Laboratories of RTP
                                        Project Summary for Project 43433
Client ID:                    SO-MM5-1-8      SO-MM5-2-1     SOMM5-3-3     SO-MM5-4-5     FBI-MM5-1
                                               771
Filename :
TLJId :
Matrix :
Units :
YF788
185-7-2A-C,E
MM5
«g
YP789
185-7-3A-F
MM5
«g
YP790
185-7-4A-F
MM5
"g
YP791
185-7-5A-E
MM5
ug
YP775
185-7-1A-D
MM5
«g
2,4-Dinitrophenol                   (3.75)            (3.73)             (3.90)            (3.48)             (4.70)
Di-n-butylphthalate        %x^\^ !x &$&  %\,\ ^•-'"^%.$&'  'I^x x   -''4=67,  -"V^"**^  SJ^"  i'\^"^  s^£ii?
        J I                "• "•        "•    "•    f    f w •.*.•.:::•.•.  f  f -.-• f  ~.  •• -.-.-.     f      f.       ~.    :    -..--.-..v-..-
Hexachlorobenzene                 (0.99)            (0.88)             (1.00)            (0.84)             (0.88)
4-Aminobiphenyl                   (0.41)            (0.37)             (0.42)            (035)             (038)
Pentachlorophenol                  (1.75)            (156)             (1.77)            (1.49)             (1.68)
Pentachloronitrobenzene            (3.83)            (3.41)             (3.87)            (3.26)             (3.55)
4-Nitrobiphenyl                    (1.06)            (0.94)             (1.07)            (0.90)             (0.96)
Benzidine                          (0.33)            (0.26)             (0.33)            (0.26)             (0.44)
4,4'-Methylenedianiline             (0.80)            (0.63)             (0.80)            (0.63)             (1.02)
Dimethylaminoazobenzene         (0.71)            (0.56)             (0.71)            (0.56)             (0.88)
33'-Dimethylbenzidine             (0.41)            (0.32)             (0.41)            (0.32)             (0.55)
33'-Dimethoxybenzidine            (0.82)            (0.64)             (0.81)            (0.64)             (1.13)
33'-Dichlorobenzidine              (0.60)            (0.48)             (0.60)            (0.47)             (0.74)
Methylenebis-chloroaniline         (1.40)            (1.10)             (1.39)            (1.09)             (1.68)
bis(2-Ethylhexyl)phthalateJ\;:/   Ipfr    ,  ; ^••203?    i   ^ .'
                                          (  )-Estimated Detection Limit     Page 2
 Triangle Laboratories of RTF, Inc.                                                                                  Savar v3.5
 801 Capitola Drive • Durham, North Carolina 27713                                                       Printed: 12:49:03 '"

-------
                                           Triangle Laboratories of RTF
                                       Project Summary for Project 43433
Client ID:                   LAB BLANK-    SBLK101497
                            MM5-28

Filename:                   YP774           YP773
Olid  :                    185-7-6A-C       SBLK101497
Matrix  :                   MM5            XAD
Units   :                    ug               ug
n-Nitrosodimethylamine            (1.50)            (1.41)
Cumene                           (0.41)            (039)
Phenol                            (0.66)            (0.63)
Aniline                            (0.54)            (051)
Benzyl Chloride                    (0.41)            (0.39)
1,4-Dichlorobenzene                (0.67)            (0.63)
2-Methylphenol                    (0.86)            (0.81)
Acetophenone                     (0.61)  c, \% V'„ 2&&
n-Nitrosomorpholine               (1.49)            (1.41)
D-Toluidine                        (0.54)            (0.51)
Hexachloroethane                  (1.41)            (1.33)
l,2-Dibromo-3-chloropropane       (1.48)            (1-40)
N,N-Diethylaniline                 (0.51)            (0.48)
bis- (2-Chloroethyl) ether           (1.15)            (1.08)
3/4-Methylphenol                 (0.99)            (0.89)
Nitrobenzene                      (0.62)            (0.56)
N,N-Dimethylaniline               (0.63)            (0.57)
Isophorone                        (0.52)            (0.47)
o-Anisidine                        (1.13)            (1.02)
1,4-Phenylenediamine              (0.82)            (0.74)
1,2,4-Trichlorobenzene             (0.95)            (0.86)
Hexachlorobutadiene               (1.63)            (1.47)
a,a,a-Trichlorotoluene              (0.77)            (0.70)
Hydroquinone                     (0.85)            (0.77)
2-Chloroacetophenone        -     (0.41)        ^    3.83
Hexachlorocyclopentadiene         (1-44)            (1-46)
2,4,6-Trichlorophenol               (1.31)            (1.33)
2,4,5-Trichlorophenol               (1.14)            (1.15)
Biphenyl                          (0.36)            (0.36)
Dimethylphthalate        s    ,     "  144            (0.42)
4-Nitrophenol            •         (1.93)            (1.96)
2,4-Dinitrotoluene                 (1.48)            (1.50)
Dibenzofuran                     (0.32)            (0.32)
 l,6-Dinitro-2-methylphenol         (3.27)            (3.32)
 Trifluralin                         (239)            (2.42)
                                         (  )-Estimated Detection Limit    Page 3
 Triangle Laboratories of RTF, Inc                                                                               Savar v3.5
 801 Capitola Drive • Durham, North Carolina 27713                                                       Printed: 12:4943(41 /13/97

-------
                                           Triangle Laboratories of RTF
                                       Proj ect Summary for Proj ect 43433
Client ID:                   LAB BLANK-    SBLK101497
                            MM5-28
Filename :
TLJId :
Matrix :
Units :
2,4-Dinitrophenol
YP774
185-7-6A-C
MM5
ug
(5.05)
YP773
SBLK101497
XAD
ug
(5.12)
Di-n-butylphthalate      -
Hexachlorobenzene                (0.96)            (0.87)
4-Aminobiphenyl                  (0.41)            (0.37)
Pentachlorophenol                 (1.82)            (1.66)
Pentachloronitrobenzene           (3.84)            (3.50)
4-Nitrobiphenyl                    (1.04)            (0.95)
Benzidine                         (0.54)            (0.47)
4,4'-Methylenedianiline             (1.26)            (1.11)
Dimethylaminoazobenzene         (1.08)            (0.95)
3,3'-Dimethylbenzidine             (0.67)            (0.59)
3,3'-Dimethoxybenzidine           (1.39)            (1.22)
33'-Dichlorobenzidine             (0.91)            (0.80)
Methylene bis-chloroaniline         (2.06)            (1.81)
bis(2-Ethylhexyl)phthalate     \/   &&   I.."'"""  QS7
                                         ( )-Estimated Detection Limit    Page 4
Triangle Laboratories of RTF, Inc.                                                                                Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713                                                       Printed: 12:49:03 11/13/97

-------
CLIENT CHAIN OF CUSTODY
                                         SAMPLER'S SIGNATURE
                                                                          P/Q 03927/0700003270
  From: Pacific Environmental Services
       5001S. Miami Blvd. Suite 300

       RTF, NC 27709
. Project: Tull Citji/iN
                                             Contact: Frank Meadows

                                              Phone: 919-941-0333

                                                Fax: 919-941-0234
                                               P.O.tf:
 (PES03/AJB)

If the data will be reported to a state agency, which one?.
Relinquished. By/Sign.
Analysis Wanted:
                                                                             Total Number of
                                                                             Containers:
Relinquished By/Sign.
Received for
Date/Time
                                                     y/Sign.
                                     Relinqui^e^ By/Sign.
                                                                                              Date/Time
                         Received By/Sign.
                                       Date/Time
                                 Send Samples to: Triangle Laboratories, Inc.
                                                Attn: Sample Custodian
                                                801 Capitola Drive
                                                Durham, NC 27713 USA

-------
                       ANALYTICAL REQUEST AND CHAIN OF CUSTODY
                                                                                                     oo
                          PROJECT,:
RECOVERY
PERSON:
 If.
/fa
SAMPLE
TECHNICIAN:
 SAMPLE IDENTIFICATION
                  COLLECTION
                 DATE   TIME
         SAMPLE NAME
                                       NUMBER OF
                                       CONTAINERS
                                             ANALYTICAL REQUEST
                                                                        —
                               SSTSS3
      U
  gEUNqus^En ^VME-
0£7£/6»A-
"^ RgCETVErf&NAME
                         D'ATE/TIM
HTURE
                                                             SHIPPER'S NAME AND ID NUMBER
                         bATE/f IME

-------
METHOD -PCIC

Plant G^M-£A6|Ato
Sample Date: °[ \22 \ °Pr
Sample Location: ^>E|
Recovery Date: ^t\22_ \\\"
ji*«f SAMPLE RECOVERY DATA
U)
F£?l- MO"1?
Filter No.(s):-$^-f|^«^=^•lfl'
t TVofsr B CvcDy\^
1 ^
\ XAD 2 Tran No (sV S li v-l

Run No.:J3-5«*f*tf5=e>^
t Job No.:*S*{M.Dii3>

HAW2 -Pfti- nn-

Sample Recovery Person: *^- ' OuL.
,.- ;\F*:.^-::^~r£t^r' ;>'''..>.5>--y. ^JJ'-V f"."" "i'i'J
Impingers
Final wt.
Initial wt.
Netwt
XAD-2
Trap
—
—
—
1
(knockout)
•y^1^
V"^.^
OD
^^Iiiiipiisturei'i3^tife:v 1^^;-
2 3
(100mlH2O) (100mlH2O)
(untipped) ^tipped)
Jn(~^ f~j "^^ — TJ
'^i it ^^1 —A // ^^
"^l*?^ "?-2(»*>
C7.D /O.iv
.•:.^i\-j*/s-r':.:; .- \.~'-1,'«.. .r^VK7s.:v-.v.{*> VV-» -C.1^; v.V- *'
:•% ^•^•^b?':^;S^r '^^'^i>
4
(knockout) Silica gel
(untipped) (untipped)
C? /5"- C t^(^ ^ . 2^ 9
0?t5»^b ^loZ.2. g
(f^-.f) Q.O g
P^^SM^
Train System: fe^ft ^V^tS ^
Probe:
">' k
h**
Filter: Color- K/0 (JVcrA*
Impinger Contents:
Silica Gel:
©Grams
>T>N^ "T^irto / BDX

Loading - Wo ur
I^X A>-IC5 / te./£. tfOtr


— lJ \ t. ~\ S*
C . 1 K' I [UK. is- r-
\ 	 (uC\i^.l '^D Vw. l<>\WO->t
Used- 3oO Color -^c Cuiuior % Spent - K}^,J*
Condensate Observed In Front Half vWf
':v^¥"M;^^^^^S^^^^r^^m^^^SvS^
Filter Container No. ¥&!- foftS
XAD Module Container No.: f^fel- fifa£
Probe (FH)
& Back. Half Rinse (Acetone) Container No.: f-&{- /
Probe '(FH) & Back Half Rinse (Toluene) Container No.: rfij-
Impinger Contents Container No.:
Impmqer Rinse (Acetone/MeCI2)
Container No.:

-^v^lt^-ffe^^SifeS'
marked/sealed: ^-^
marked/sealed: >^
Liquid level j
ci/-i$ marked/sealed: ^
Liquid level ;
fyfy marked/sealed: 
-------
fW
r*
METHOD O-OieyW SAMPLE RECOVERY DATA
Plant: C^fij- S/-l6,/^AuT Run No.: So • (vjrwc- 1
Sample Date: c\ \W \ '? } Filter No.(s): _S£ Aim - / Job No.: S-i ,M uctf
Sample Location: f) O^pol^ cl_. ,rpwnS££ .\ML£~\ —
Recovery Date: ^IM \ uf ?• XAD-2 Trap No.(s): St> mr* *i - 1
Sample Recovery Person: >**f^r ^V^-IO1 —
•^:fe:- ":r'"^h^fe^:^^?^iv.v/:St.?^"'v "^Svvrr^ Md istuirei. Datasjir.' £".:;•• -^•••-'^ j— :.^^j-2^:'v T.V^-^^-r^^^i;;-
1234
Impingers XAD-2 (knockout) (100mlH2O) (100mlH2O) (knockout) Silica gel
Trap (untipped) (tipped) (untipped) (untipped)
'SrrgTwt. — llk.l 7^ O- 7 /^- /5". 2. g
Initial wt. -*- ^5^ >\>-H ~>l^-5 U/>2. p. ^S.S g
luwfwt. «^ ^7/'V 7>/.Z 7^.2- 6/^K:5^iii^SSLffiW:B^
Train System: &r(\ CT\i>VnDA T^C> r A\m^ / BfcV J^T^^ ^V r?^ _>,? ^
Probe: I-' ^Uv^ / ^-'^*r
Filter: Color- (_^re^ /"Oi" Loading- i\1frf/urvN
Impinger Contents: (f.| ft-^
Silica Gel: ©Grams Used - ^CD Color- !l V!-L'S< % Spent- VO
Condensate Observed In Front Half: X^xt
.»;-.- . • . ._ • • • 	 	 I'ir.-.atiT''- » i - '.••-»»^*t|>».i*'i'd^ur.W'.i*!*>T-1Ai .:j"v.j^",'*"t-'« ~"£:.:-.t'*t"'~t>^^-'i*t'^\.***-*'-«<'^'-?'~^>'':-^^^
• ' T*:.*' TIL; ^r^rir-ii^-;^:.^;^; • .; ]^ R^cpvered: S^ ni pli£1- ractj oriss-- ^f : -; v;:v • v ; :^^j;-;_f v^":^:^^^
Filter Container No. Sb- itfMfj - 1 marked/sealed: ^
XAD Module Container No.: Sd-fa/bS'/ marked/sealed: ^
p\<-~\\ -Te-tK..^ Liquid level ^
Probe (FH) & Back Half Rinse (Acetone) Container No.: ."> » /
-------

METHOD *>*
Plant: G^ M - C-,SQ6
Sample Date: -] JZM I^T-
Sampie Location: r) O*-0<.
1
Recovery Date: 'Q |
Sample Recovery Person: k£
( 0 SAMPLE RECOVERY DATA
^) NJQ"oO
Filter No.(s): SO - -O^S - 2
si*. C,c,ruJk-k~ ^.^
Run No.: Sfc - rA^ - a
Job No.: "SHIM .ot)b
l^t
XAD-2 Trap No.(s): ?'**&:\'S-?x* ••'••••ii^'J':"V-'V-r'.;->'':"'- v'is;';v _••;••?•.' ^ •,':-:-"".--
.^•!>::^J:^^^ Dates::"?/.:- -->.v
1
Impingers XAD - 2 (knockout)
Trap
Final wt. - — /D^D.fe
Initial wt. 	 V ^S"^
Netwt. 	 	 fcl^l
2 3
(1QOmlH2O) (100mlH2O;
(untipped) [tipped)
'^O.T. ^(.^
~J\t\,oi ~'}2I -*>
^D^> °>~)~
'^pfggl^lp^^f^g
4
(knockout) Silica gel
(untipped) (untipped)
6>/^5" &\2.*> g
Lf'^-C £{£>:!.£. g
a^ 3*0.*^ g
!^^&7£^s:-l^
Train System: £- K!
• (C ("l^ul ^V^?,2
Probe: "? ' (Jj,^>*-> .' C_ le^r
Filter: Color- C^reoj /~fAN
^ Loading- ^UHl-'uv
YY^
Impinger Contents: C~Aea>r
Silica' Gel: @Grams Used - 3o
o Color- MBl\At % Spent- ^
Condensate Observed In Front Half. fOz>w ^
:.VT^rf^:;.:^??vfcik%:-^^3^^
Filter Container No. .^0 - Mh^> ' ^*
XAD Module Container No.: 5i? - itifa$ ' 2-
V
Proba (FH) & Back Half Rinse (Acetone) Container No.: >->-/•
Probe '(FH) & Back Half Rinse (Toluene) Container No.:5<5-j!|
Impinger Contents Container No.
Impinger Rinse (Acetone/MeCI2)
5 ^ - AA/ - ^ i
Container No.:

?^-j7^s^"^^"^.s~!^''-'y^s^v'^^»-
marked/sealed:
marked/sealed:
Liquid level
^-^ marked/sealed: ^
Liquid level
*4^ marked/sealed:
Liquid level . 	 /
2> marked/sealed:
Liquid level
marked/sealed:
?1

-------
METHOD
SAMPLE RECOVERY DATA
/I
Plant: LZ?
>JU~ ^rtLA
'
^
Sample Date: ^faffo
Run No.: <5b -/f/i£- 2
Filter No.(s): So-ftA^' ^
Job No.: 5yy/oo S
Sample Location: Sc^^c^ D^±<*sf
Recovery Date: ^p-S/v 3-
XAD-2 Trap No.(s): 5b -/^/^- ^
Sample Recovery Person: ft/' / P&
, si*.-^*:::tt£s^f'&^?^-^'*!^ >:*••*<: •?.
; w..;.-^-- .i.^-^--^ ••.?i-/.u \-y;.>->">;-~>- -is t-7~:-> ;••.-••••••••..»:(••.•
Impingers
Final wt.
Initial wt.
Netwt
XAD'- 2
Trap
— -
- — .
	 	
1
(knockout)
/C3/.V
^3(0.0
535"-?-
y^Moislttilra
2
(100mlH2O)
(untipped)
L-M^i ^
"•M^-l
-UM->
Sa^^?^?s^|^:4
3 4 . -
(100mlH20) (knockogt)
(tipped) (untippedt
0^.3.^ 'vjLZ.Z
•^•Z5.Go Iol3.>
- b? I • 6 J - 5
SS?fSSS
Silica gel
(untipped)
"V"* -*
/T5'V. c*i g
Cfrt>£.O g
^6: - 6 g
u;"5iSlSi5KS^SfSii'S^
Train System: £ PA- M M.^T/oo it? / &'
Probe:
1V £\a<>
•5
Filter: Color- /Atf
Impinger Contents:
Silica Gel:
@Grams
CJ\ # F , ivo-r j^

^ Color -

') V,IVM % Spent- ^>

G
Condensate Observed In Front Half. f° 5 •**£-
"V'. .:.,'.vi~^i '':':-v.:;;
••^Vt'-^.'ti'.ili
Filter Container No.
P?5'';:=s:r->"' •^"'.^'O'ei',
.;-^ifV^;^, .'.v jj- •>*•'
5-5) ^/^/
XAD Module Container No.: &0
MeC
Probe (FH) & Back Half Rinse (A
H^O,
Probe -(FH) & Back Half Rinse £6
c o ve ra d: Szini p
yti.^ 'J
-•/i/f^ 3
|:Sr^^cj^*^^^^^^SSf^
leiFractians^^f-nS-i'v^y^


aeoafi^ Container No.:^>t? -/v*>-?
tifuiiniii) Container No.: S^-/*/%/-3
Impinger Contents Container No.: "Tv ~ l'^f^^-3
Impinqer Rinse (Aefflinac/MeCI2)
Container No.:

wASCWft •- ^c'SftT.'.rsr-'." •
'$. t-5;:T:ntS'"
-------
                METHOD DO/0
                                    SAMPLE RECOVERY DATA
Plant:
                                                         RunNo.rSD
Sample Date:
                             Filter No.(s):5V
                                                          Job No.:
Sample Location:  p>
Recovery Date:
                             XAD-2 Trap No.(s):
Sample Recovery Person:

Impingers
          XAD-2
           Trap
                       1
                   (knockout)
(100mlH2O)
£ (untipped)
(100mlH2O)
  (tipped)£-
    4
(knockout)
(untipped)
 Silica gel
(untipped)
Final wt.
Initial wt.
Net\wt.

Train System:
                                   o  /  B^x   i Q.'  M- I ts   / 7bT*6
                                                                         . 8
Probe:
Filter: Color -
                                   Loading -
Impinger Contents:
Silica'Gel: @Grams Used -
                                  Color -
                                                    % Spent -
Condensate Observed In Front Half:

Filter Container No.
                                                          marked/sealed:
XAD Module Container No.: 5o "
                                                          marked/sealed:
Probe (FH) & Back Half Rinse (AsetocaK^ontainer No
                                                          Liquid level
                                                          marked/sealed:
Probe (FH) & Back Half Rinse Gfeiueae) Container No.:
                                                          Liquid level
                                                          marked/sealed:
Impinger Contents CQntainer No.:
                                   a\9"
                                                          Liquid level
                                                          marked/sealed:
              ci-^
Impinger Rinse (Acmane/MeC12) Container No.:
                                                          Liquid level

-------
Custody. Seal : Absent Sample Seals: Absent
Chain of Custody : Present Container. . . : Intact
Sample Tags : Absent ,
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A
Ice Chest ICE Temp 3.0 C
|TLI Number Client Sample ID 	 Matrix)
jmR/H-CPM. 	 Client COC ID 	 * Location 	 \
II
TLI Project Number 43433 j Book j|
Client: PES03 - Pacific Environmental Services j <£
1 18S(i
f' 1 1
Date Received j 09/29/97 j *vj%^ ^ forffa*
i g i
	 Carrier and Number | TOM MCDONALD | 7
'TO LAB'
^ate/Infit
\S~^s
I185-7-1A FBI-MM5-1 FILTERj^^Jc
I FBI MMS * COI K^X/
5 " Y '*
H 1
|!8S-7-lB FBI-MM5-2 XAD
| FBI-MMS * COI
|!8S-7-lC FBI-MMS-3 FH/RINSE
| FBI-MMS * • COI
»|
(18S-7-1D FBI-MM5-4 BH/RINSE
B • FBI-MMS * COI
u
n
(18S-7-2A j SO-MM5-1-8 FILTER
H . SO-MM5-1 * COI
H
H185-7-2B SO-MM5-1-9 . XAD
|| SO-MM5-1 * COI
||
||!85-7-2C SO-MM5-1-10 FH/RINSE
|| I ! SO-MMS-1 * CO!
||l85-7-2E SO-MM5-1-.12 BH/RINSE
I) SO-MMS-1 * COI
H '
II
||!85-7-3A SO-MM5-2-17 FILTER
H SO-MM5-2 * COI
||!8S-7-3B SO-MM5-2-1B XAD
|| ' SO-MM5-2 * COI
•
8185-7-3C SO-MM5-2-19 FH/RINSE
|| SO-MM5-2 * COI
u
|l85-7-3D SO-MM5-2-20 CONDENSATE BOTTLE A
IJ SO-MMS-2 * COI
-
B185-7-3E SO-MMS-2-21 CONDENSATE BOTTLE B
D SO-MMS-2 * COI
n
W
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\





,


1
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,

'







fll85-7-3F SO-MM5-2-22 ' ' BH/RINSE|Vl
I) SO-MM5-2 * COI j >/"*
To STORAGE
Date/Init
ffafak.




















To LAB
Date/Init
'











\
£7 t*l
-------
                                                        RIANGLB LABORATORIES.  INC.  •- LOG IN RECORD/CHAIM OF CUSTODY*
H Custody Seal : Absent Sample Seals: Absent
fl Chain of Custody t Present Container. . . : Intact
D Sample Tags : Absent
U Sample Tag Numbers: Not Listed on Chain of Custody
H SMO Forms : N/A
TLI Project Number 43433 | Book JJ
Client: PES03 - Pacific Environmental Services j j
1 "S^
Date Received j 09/29/97 | ^Jj^^^^/ WJySt4&&~^~fage
n "• i • / i
I) Ice Chest ICE Temp 3.0 C Carrier and Number | TOM MCDONALD | 7
HTLI Number 	 Client Sample ID 	 Matrix] To L
jjmR/H'CPM Client COC ID 	 * Location 	 j Date
II 1 j->
AB | To STORAGE) To LAB
/Init | Date/Init | Date/Init
fll8S-7-4A SO-MMS-3-37 FILTER A) ^f-/ / \ ^*X-jr \
jj , so-MMB-3 • * coi \y&7e/ffl\&'rttfiki
II 1 7 J ' Jr
||l8S-7-4B SO-MM5-3-38 FILTER B| f \
D SO-MM5-3 * COI III
n i '
II 1
H185-7-4C SO-MM5-3-39 XAD|
I) SO-MMS-3 * COI j
1
||l85-7-4D SO-MM5-3-40 FH/RINSE|
1) ' SO-MM5-3 * COI j
D i
fl!85-7-4E SO-MMS-3-41 CONDENSATE|
1) i SO-MM5-3 * COI |
n .._....
||l8S-7-4F SO-MMS-3-42 BH/RINSE)
(I SO-MM5-3 * COI ' |
U j
||l85-7-5A SO-MM5-4-51 , FILTER)
1) SO-MM5-4 * COI j
fll I
II 1
1)185-7-58 SO-MM5-4-52 XAD|
H ' SO-MM5-4' * COI |
n i i
II ' 1
H18S-7-5C SO-MM5-4-S3 , FH/RINSE|
1) SO-MM5-4 • COI j
n
II 1
H185-7-5D SO-MMS-4-54 CONDENSATE|
|j SO-MM5-4 * COI j j
n I
II 1
H185-7-5E SO-MM5-4-55 BH/RINSE|
H SO-MM5-4 * COI |
II 1
II 1
fll85-7-6A LAB BLANK-MM5-28 FILTER)
D NOT ON COC * COI |
Ri
1
1)185-7-68 LAB BLANK-MM5-30 CH2CL2/CH3OH|
fl NOT ON COC * COI |
!)• I
1
1
j >
' \
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/ \
i

\%%toL
\
\
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j <jrt$p
\ 1 \
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II 1 i . , i
B185-7-6C LAB BLANK-MM5-31 TYPE II WATER | 1 IC$ 1
H NOT ON coc * coi | feV \£S) /£//V/T?
To STORAGE
Date/Init














To LAB
Date/Init













To STORAGE
Date/Init












•

To LAB
Date/Init


1








.


To STORAGE
Date/Init




'


'






DISPOSED
Date/Init



i
i
\
i
i
ii
ii
i
— fl
i
i
n
i
n
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r
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i t
jj Receiving Remarks: COC LIST A CONDENSATE FOR SO-MM5-1 BUT A CONDENSATE' WAS NOT RECEIVED. • -•
II ' ' 1
1 ' f
|  Archive Remarks:

-------
                                                                                                              PAGE 1 OF 1
I
|  Project: 43433
                                                TRIANGLE LABORATORIES, INC.
                                        Sample Preparation Tracking & Management  Form
                                                                          Client: Pacific Environmental Services  (PES03)'
I  Method:
                                                    Sample Information
                                    Extraction Date: (Q__/'_/^J
II                                II
|       |   TLI        /                 | Sample  | Final
|Sample| SAMPLE ID   /     CLIENT       |Wgt / Vo:
|*  crd|             /     SAMPLE ID     | g  / ml |  ml
                                                            £•
                                                                            VA*>
                                                                                              1*1*31
                                                                     A0t/32li£/J!L/£2l.{a/uty43l	/	/	l_/_/__l
I      |  TLI Blank                       |
|000   |                            SBLK  |
|      |  18S-7-1A-D
1001   |
                             FBI-MM5-1
|      |  18S-7-2A-C.E
1002   |
                            so-MMs-i-8
                                                                     vrki
                                                                      \\I\IM\
|      |  185-7-3A-F
1003   |
                           SO-MM5-2-17
|       | 185-7-4A-F
(004    |
                           SO-MM5-3-37  |
        185-7-5A-E
|OOS
                           SO-MM5-4-51
|       | 185-7-6A-C
1006    |
                      LAB BLANK-MM5-28
|       | TLI LCS
|007    |
|      |  TLI LCSD
1008   |
                                                ii
                                                ii
                                                      i
  Comments:    O
                                                    txn
                                                                                                                          I
                                                                                                  -REV 07/26/93 (PSTMF 7)--*

-------
70MM5.TXT      OWL SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
21 '97               8270 MM5 PROJECT (IMPINGER INCLUDED)

SOP #    STEP  DESCRIPTION .

OV i-118  Prep .glassware for soxhlet extraction.-
OVfu-111  K/D front half and back'half rinses to' 1 ml.
OWL-118  Place  filter and XAD into MeCl2 presoxed thimble. tf lo/Wl
0* ,-118  Add concentrated FH and BH rinses to thimble.
DLJ-128  Spike  lOOOul Spike X @ 100 ug/ml into all samples.
DSP-128  Spike  lOOOul BN QC CHECK @ 100 ug/ml into LCS/LCSD.
D! '.-128  Spike  lOOOul A QC CHECK @ 100 ug/ml into LCS/LCSD.
0! j-118  Soxhlet  extract 16 hours with CH2C12.      .
OWL-111  K/D down impinger rinses, if any.   4  JIN*
OT~j-118  Pour  impinger water in separatory . funnel, ^measure and
         record pH and volume. A "7&V  I°/16]17  V'~l
OWL-118  'Add concentrated impinger-rinses to the water. A/T      .
D.^P-128  Spike  lOOOul Spike W @ 100 ug/ml into all samples. \\\\/^[^f
         NOTE:  LCS/LCSD does not have a water fraction.
OwL-118  Extract  3 X 60 mL MeCl2.  JArf' /«?//<5/^7
OWL-111  Filter the  sox and impinger extracts through Na2S04 .1 |Y1I^-fov
0 [,-111  K/D the  to  10  mL,                                    l     '
O..L-111  N2 to 1  ml.
OWL-111  Transfer to 1/2 cjram vial with 2 X 0.5 mL of CH2C12 rinses.
0 L-lli  N2 to 1  mL.
         Relinquish  to  LRGC/MS for analysis.


                          / / S7  *         ~y

-------
Dates 10/16/97                                                    TRIANGLE  LABORATORIES,  INC.                                                     PRDPERC v4.00
Times 15s35 ,    .                                              Wet Lab  Extraction and  Observations                                                       Page: 1         ^^
                                                                         Projects 43433                                                                                  OO

 Sample                                         Init.  NaOH  Adj.   H2SO4   Adj.
 ft  crd Tt,I_Number.. Customer. Sample. Id	  pH. . .  mL. .  pH.l.  mL. . .   pH.2.  Appearance. Color	 Odor... Vol.  Entered.By	  Date	  Time	 S

 000    TLI Blank    SBLK                        7.00  n/a   n/a    n/a     n/a    HPLC WATER  COLORLESS   NONE     620  SYKOROVA          10/16/97  15:34:47 F

 003    185-7-3A-F   SO-JM5-2-17                 7.00   1.5  12.00     0.4    2.00  CLEAR WATER COLORLESS   NONE     620  SYKOROVA          10/16/97  15:34:47 F

 004    185-7-4A-F   SO-WB-3-37                 7.00   1.0  12.00     0.3    2.00  CLEAR WATER COLORLESS   NONE     530  SYKOROVA          10/16/97  15:34:47 F

 005    185-7-5A-E   SO-MM5-4-51                 7.00   0.8  12.00     0.2    2.00  CLEAR WATER COLORLESS   NONE     420  SYKOROVA          10/16/97  15:34:48 F

 006    185-7-6A-C   LAB BLANK-MM5-28            7.00   1.5  12.00     0.5    2.00  CLEAR WATER COLORLESS   NONE     440  SYKOROVA          10/16/97  15:34:48 F


-------
Date: 10/14/3?
Time I 18:28'
 Sample
 #  crd TLI_Number..  Customer.Sample.Id

 000    TLI Blank    SBLK

 001    185-7-1A-D   FBI-MM5-1

 002    185-7-2A-C.E SO-MME-1-8

 003    1B5-7-3A-F   SO-MM5-2-17

 004    18S-7-4A-F   SO-MM5-3-37

 005    185-7-5A-E   SO-MM5-4-51

 006    185-7-6A-C   LAB BLANK-MM5-28

 007    TLI LCS      TLI LCS

 008    TLI LCSD     TLI LCSD
 TRIANGLE LABORATORIES,  INC.
Wet Lab MM5/POF Observations
       Project: 43433
PRDPERC V4.00
      Page: 1
F.
	 No

1
1
1
2
1
1


XAD
Color
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE

WHITE
WHITE
Filter

WHITE
BROWN
BROWN
BROWN
LGHT BROWN
WHITE


Glass Wool PUF

WHITE
WHITE
WHITE
WHITE
WHITE



. . Odor . . .
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
Air
.. Q.No. Entered. By ...
P1039 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
3927 LIVENGOOD
LIVENGOOD
P1035 LIVENGOOD
P1035 LIVENGOOD
                                                                 Date....   Time..

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F

                                                                10/14 18:25 F
                                                                                  .  S
                                                                                                                                                                      CD

-------
                                              >»
                                                    AV^^ -Cv>
                                    PES03-Paciflc  Environmental Services
                                                FBI-MM5-2
                                      Pr-o.j ©ot. : 4-3-4.33
                                           iea-7--, B
                                     Triangle Lator?
                                     TLI PROJECT* Oj  '•'
                                     DATE 9/18/97
                                     SPIKE 4.0ng USF
                                     SPIKE lOOug TERP.-.X""
                                     SPIKER \A/^   PRE.-.'.
                                            PACIFIC ENV.
PES03-Pacif1c Environmental  Services
           SO-MM5-1-8
                  : 4-3-4-33
                                                                 • \
                                          DATE 9.r-.

-------
                                   Services
                                               r-^nq-Pacific Environmental Services
                                                          SO-MM5-2-18
                                                 Pr-ojeot.: 4-34-33
                                                     185—7—3B
                                             TLI PROTv'* 03927
                                             DATE 9/1* ^7
                                             SPIKE 4.ong USF-C *
                                             SPIKE 100ilg TERPHENY'.  014
                                             SPIKER_J/VU_ PREP.
                                                    PACIFIC ENV.
         PES03-Pacific EnvirofWentaT  Services
                    SO-MM5-3-37
           Rr-ojoot- : 4-3-4-33
                1 85— 7 —4-A
     PES03-Pacific Environmental Servtces
                SO-MM6-3-38
       R r- o  © o t. : 4- 3 4- 3 3
PES03-Pacific Environmental Services
           SO-MM5-3-39       '   "
  Rr-cijeot:  4-34-33

-------
                — s B
         ? Laboratories,  Inc.
  TLI PROJECTS 03927
  DATE 9/18/97
  SPIKE 4.0ng USF-C &  USF-S
  SPIKE 100ug TERPHENYL-D14
  SPIKER 1/t*]  PEEP.
        PACIFIC  ENV.
                                                                          'J
PES03-Paclfic Environmental

-------
                                                                 PAGE  1 OF 1
                        TRIANGLE  LABORATORIES, INC.
                       Transfer Chain-of-Custody Form
                               Project 43433

                    Transfer   From: OWLS5     To: OMSSV

                            Initials. .    Date	    Time

             Released by:   	

             Accepted by:   	
         MILES.ID.

         43433-
         43433-
         43433-
         43433-
         43433-
         43433-
         43433-
         43433-
         43433-
-000
-001
-002
-003
-004
-005
-006
-007
-008
         TLI No,
              Cust.Id.
TLI Blank
185-7-1A-D
185-7-2A-C,E
185-7-3A-F
185-7-4A-F
185-7-5A-E
185-7-6A-C
TLI LCS
TLI LCSD
SBLK
FBI-MM5-1
SO-MM5-1-8
SO-MM5-2-17
SO-MM5-3-37
SO-MM5-4-51
LAB BLANK-MM5-28
TLI LCS
TLI LCSD
. iditional comments or instructions:
                                                      -XfrCOC  (Rev 11/01/94)--+

-------
                 SEMIVOLATILE GC/MS TRACKING FORM
TL-RTP Project #:
MATRIX^MMS) PUF  Water Soil  Other



METHOD: (^27(1) 625  CLP



ANALYTELIST: Table 2 TCLP  625  CLPfCA;
AP
                                               CB/CP  Other
CAfl / 736Z/5W
Date
'*/«/W
^
/
J
/
)
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O*)£(*
1313
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537^
3-S20
^
/V5 7 fo/J-C
/5-S 7-^-0
•^
'%

3-»yy
S3-79
5520
/«S7^^£
/yS^.-J^-r
/X5 m-f
/V5.T5/,^







" ; Sample tD
DFTPP
SSTD050 PAi-t
SST&C'S^' CAA
5Bi^i. /O/«/97
LAf, ~&iAAi !& -/M/MS'J^
rf)C ~ ffl/YlS' 1
US
LCS D<.'f>

QrTPt?
SSfi^C'Zb PfrH
£>:*T0I)S& C/IA
•$c-fn/n$-/' $
So - /n/ns- 3-i-j
SC>-fY>^-3M
so-m.^-+-*i







Rfe Name
1p-7»i
yp7c,o
V'^7 77/
VP77J
irn
-------
                                                 Triangle Laboratories, Inc.
                                                        Run Log
	 Standards
QnternaJ^Surrogale / Recovery
SUoiC 6n> iz|3i\«n
£ufl <5>8iM fjqtrvj^
Internal / Surrogate / Recovery
"A
Analyte
"/A
                                                                             Extract / Sample volume
                                                                                       GO
                                                                            Signature
                                                                                                     Date
                                                                                                                       in
Column Type
Ob5-l02S
Column #
4^^W51T
Analysis*
^
Acquisition
MelhocJ
CC/&.IY)
GC Method*
^
Find DBS'
•^
Other*
^
                                                                                                       to unit
                                                                                                          mL
Dale**
Time*
Prolect
Sampled
Client ID
Filename    pH* Operator/Date Backup*  Proc  Comments***
9%
                               OfTPP
                                                                                        W


                                                       1PM-
                         531$
                                                                                 vo
      tKft
                   5375?
                                                         00 lojnfa
                                                       Wlfl
                                                                                 DP
                         5577
                                     CAA
                        35/S
                                  ri CM
      1566
*  Volatile Data Only
SRVR1\\QMFORMS\LRRUNLOa.DOC
 I .
                                            (Mr
                                               VH1I
                                                         'V*
                       Transcribed Data
                 ***  Dated Signature/Initials Required
                                                                                          Page.

-------
                                                      Triangle Laboratories, Inc.
                                                             Run Log
         	;	Standards
 jlnteroaj^ Surrogate / Recovery  I Internal / Surrogate / Recovery
                                                                Analyte
                                                           Extract / Sample volume
                                                                                           Signature
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                                                                                                                             CD
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Column Type
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^^
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Time
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-------
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Column Type
£65 -££5
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3RVR1Wtt\FORMS\LRRUNlOO.DOC (t/23/97)
                          Transcribed Data
                                                         ***  Dated Signature/Initials Required

-------
                                                   Triangle Laboratories, Inc.
                                                            Run Log
     urrogale / Recovery
                                Standards
   Internal / Surrogate / Recover
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-------
*'•.," " , ' «
I N% s% "• ' <•>'•'' %VV Pit
Project Number: 43433
Sample File: YP788

Client Project: £#gittaw;MI ,* \ x , ,
fFUE ID* li8ffiW?*'2A,-C!yB- "^'i ^ %4-^ ** '
\ ^ ' - -C^ \*> -\ ^-^^ "
1

_ j. *. ., ^v. A\ -.x -".wp^ £2 fiffc-. ^ "v-.^ ^ ^
1% "" ••"• --^ f •• ^ f -^ % •• •^•T^ -^ A-. ^ %$ %
Naphthalene-d
Naphthalenev
2-Methylnaphthalenc /
Acenaphthene-d
2-Chloronaphthalene /"
Acenaphthylene •/
Acenaphthene
Fluorene--''
Phenanthrene-d
10
Phenanthrene •/
Anthracene y
FIuoranthene\/
Chrysene-d
Pyrene v/
Benzo(a)anthracene ^/
Chrysene v
Perylene-d /
12 /
Benzo(b)fluoranthene • /
Benzo(k)fluoranthene •/
Benzo(e)pyrene <-/ /
Benzo(a)pyrene v/
Perylene -./
Indeno(l ,2,3-cd)pyrene v'
D ibe nz(a, h) an thracene \J
Ben2»(g,h,i)perylene y/
cificEnvuonm.nUl


'Daie;Seceived:(l!
' i"53tt* fitfft'jt^teti* ^li
f Q^Aiitfpii^
Dilution Facton

^%s«SlW
... «»*^?.Vxv.^.v..^>.*.>.-:... >.?*^>
IS 2
24.93 B
25.56
IS 3
U
0.81 J
0.28 J
0.94 J
IS 4
2.07 J
0.26 J
0.96 J
IS 5
1.18 J
U
0.22 J
IS 6
U
U
U
U
U
U
U
U
$$£f -1 •
ff:' ".
'. •
wi$z-\: * x
*$l$/8¥- \
LO/±^^;/
1.00

*vl^>;J;
12.76
12.81
14.24
16.41
16.12
16.48
17.56
19.54
19.59
19.70
22.09
25-27
22.57
25.29
29.39







^!^^4&!&J
Method 8270A MM5
-^ Sample ID: SO-MM5-1-8
—
: , ^$$&i^$^vm®^ : H
V L " >5| "^ \ - N « V^,, ^ ^ «" '•
-^-"'' " il^'bi v ^sXC %S


v -.-Si ^ " •• ^ V^"^H*X vf ^s1"^ ^^ "• S.i
; ^:m -^ ^:-:m^M?^i :\

10
10
0.43 10
10
10
10
10
10
10
10
0.24 10
10
0.20 10
0.20 10
0.18 10
0.21 10
0.20 10
0.18 10
0.24 10
0.20 10
                             NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: QuantiUtion Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below QuantiUtion Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
              Savarv3.5
Printed: 09:55  11/13/1997

-------
                                                    ^.J&'^-j   4-r£*<
                                                                          ^ ^    ^ .   :
                                                                         v s ,•> -•.  ^ •;  ••'
Project Number. 43433
Sample File: YP788
                                                 Method 8270A MM5
                                            Sample ID: SO-MM5-1-8
                                                                            •  •.  '• \f^ * ..&-F-*'- * ^-^ i *;r* - -. ^ 5 ^ "-
                                                                            -^:..^.%.^:..''- 1-  >-•:*> ^^ -^^v^^^^
                                           Dilution Factor    1.00
Nitrobenzene-d
1,3,5-Trichlorobenzene-d
1,4-Dibromobenzene-d
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
           10
Pyrene-dio
Terphenyl-d
       77.36
       76.47
       80.13
       82.46
       82.30
      102.84
      102.73
       82.46
       90.89
 9.45
11.29
11.98
12.86
15.00
18.06
19.66
22.53
22.90
1
2
2
1
3
3
4
5
5
 77
 76
 80
 82
 82
103
103
 82
 91
Reviewed by.
DwcH /
                         NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Savar v3.5

-------
I
 Project Number 43433
 Sample File: YP788
     Method 8270A MM5
Sample ID: SO-MM5-1-8
Client Project Sagihaw, MI i
plUE IDt IS&T-^^J;^;^:
* " „ - - N^^-xv /
>-Toluidine -J
Hexachloroethane \i
1 ,2-Dibromo-3-chloropropanev
N,N-Diethylaniline /
Naphthalene-d
^M-MethylphenolV^
Nitrobenzene *J
N,N-Dimethylaniline V
sophorone •-•
o-Anisidine ^/
. ,4-Phenylenediamine>/
. ,2,4-Trichlorobenzene^
Hexachlorobutadiene-\/^
i,a,a-Trichlorotoluene v
Hydroquinone *
::; f*x -ViBSifiW
•>»*§, .^^
' ,-^- <; ^<~&t&>Yzt(£e
:---»i" \^^^?
Dilution

^-'r-v> \^^^^^«
v^;\i^^4j
IS
u
u
6.57 }
U
U
U
0.73 ]
U
8.19 BJ
U
U
U
U
U
IS
U
u
u
u
u
u
u
u
u
u
£v*£ tatiw*. ^;;;^f »«sa*asii
% .I". -. ^ s T \ ->f^ ~ s A ^O > ^ s v ^ «^ v v% '•••• s -X^X--
taetefc Wl*»8*>4^ ^^^K
i^g^^e^i^
Factor: 1.00

bt*3." ^ * ^ "x^-8^^ ' ' ;-C "Sftfeft ¥< 1^^ -' xX4^
;v; ^ ^^'^ '*t tk>*&* ?;SS^
1 10.21
1.49
0.38
9.47
0.50
1.07
0.39
10.25
0.86
10.98
1.44
0.52
1.37
1.42
0.51
2 12.76
0.76
0.52
0.50
0.44
0.91
0.72
0.83
1.35
0.64
0.76
l^8l^!i
£&^v£:':s
i^l--vVo- V,
V^-' >•;, \
^^"vv^y.


•^fStflB^^^lt -^
k^6*% "!

10
10
10
10
10
10
10
10
10
10
10
10
10
10

10
10
10
10
10
10
10
10
10
10
                          NA- Not Applicable; Del. Limit: Detection Limit; Quan. Limit: Quantisation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
 Triangle Laboratories of RTF, Inc.
 801 Capitola Drive • Durham, North Carolina 27713
 lione: (919) 544-5729 • Fax: (919) 544-5491
                     Savarv3.5
         Printed: 12:42 11/13/1997

-------
\ 5 ' : s s , ***°&'> ^s' I-4 -
, \ *s " "t~ ;'^-V^: '* -
Project Numben 43433
Sample File: YP788
Client Pro] ect Sagiitaw, MI ;-
mJP:1^7^^^;^

^ -A ^ $ ^ ^ ^ •• ,. X o^ ^
>.O' ^ %A N*A!i ? ^^ \ %> %* sv s% ^
%\»* ^»k. «>»'1' »* « *'»<«•». * fk
^ Pacific Bnvirqnmenial S
« ^ , f -.-. -. ' 4 •* fe ,', ••

v^.* ^^J |TiV^J;>j^
^vic«s^ ,^;k^ -'4fMl
' ' ^^ , ^SS ^ 'v '^X>.^%5
Method
4vi^ "\ "
^v% ^^. s %
*s^*"*Cf, /
\ -^v '\
8270AMlVf5
Sample ID: SO-MM5-1-8
^ 5^-^^i^w^
y^ f|*^!^|6 E^&ff^jy&
Dilution Facton
&*&&'-" ^ "'^f^- •^--^,^
S^r^fe-^ss
1.00
nnw^SI
'SH^^J


A ^ v ^^ "-X--. -. J f '•• *•*••• •> •.
ji ,^^j -!1 \' ' % ^ ^ ^ •• ^ %^ ^ s
awaiyw ^ >< __ ^^ ^v*. ^ ^ f ..
"'- ?^vj%i,^;%^
2-Chloroacetophenonc \^
Acenaphthene-d /
Hexachloroqrclopentadiene \/
2,4,6-Trichlorophenol v
2,4,5-Trichlorophenol >/
Biphenyl v/
Dimethylphthalate-/
2,4-Dinitrophenol v
4-Nicrophenol'/
2,4-Dinitrotoluene-M'
Dibenzofurany
4,6-Dinitro-2-methylphcnol^
Trifluralinv
Phcnanthrene-d
10
Di-n-butylphthalate-Y
Hexachlorobenzene \/
4-Aminobiphenyl \/'
Pentachlorophenol v
Pentachloronitrobenzene-/
4-Nitrobiphenyl v
Chrysene-d
Benzidine v^
4,4'-Methylenedianiline -^
Dimethylaminoazobenzene v
3,3'-Dimethylbenzidine ,],
S.S'-Dimethoxybenzidine^/
•'?f^ ••• '•'' -^ o A * ^ •• •• J« %^ A*%'t ••
% ^v. --C • A*"icijiiiA.?..;
U
IS 3
U
U
U
2.13 J
2.49 J
U
U
U
U
U
U
IS 4

9.59 BJ
U
U
U
U
U
IS 5
U
U
U
U
U
•x* •F\'^\ •••• % -. ^ •••• ^ * •& /? f -~ *••' %•>**• f v%x-. v
v^D^V ^ % *••%'"'' >f^Al>: T j|s 1 1<^% ' ^ f * •? %
"^* '' ^'' # * ^ **»B* A SX- ij*
..*. ~.L*.-L..^.. ^'^..'^.\-.^"^.
0.35
16.41
1.51
1.29
1.21
15.21
15.84
3.75
1.72
1.41
0.33
2.80
2.09
19.54

20.77
0.99
0.41
1.75
3.83
1.06
25.27
0.33
0.80
0.71
0.41
0.82
* -. Xs%s -t^ ' ' :
•/^-U**^*"' T<4^*^*-'' :
Sg'MiWwt JUtlOU :
f ""^S 'S " % %• S •.
<* ^tt« ^ •
10

10
10
10
10
10
25
25
10
10
25
10


10
10
10
25
10
10

10
10
10
10
10
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limib Quantitation Limit
IS: Internal Standard; U: Undetected; B
: Present In Blank; ): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544^5729 • Fax: (919) 544-5491
              Savarv3.5

-------
Li
 Project Numben 43433
 Sample File: YP788
                                                                                          Method 8270A MM5
                                                                                     Sample ID: SO-MM5-1-8
                                              Dilution Factor    1.00

 i,3'-Dichlorobenzidine -^
 Mcthylene bis-chloroaniline •
 >is(2- E thylhexyl) p hthalate /
                                                      U
                                                      U
                                               11.05   B
25.34
                   0.60
                   1.40
10
10
10
Reviewed by
                                        Date  H /  !?>/ ^7
                           NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
 Triangle Laboratories of RTF, Inc
 "01 Capitola Drive • Durham, North Carolina 27713
  'hone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                                          Savar v3.5

-------
   Data ,1;ile: /chen/Y.i/10-23-97.b/YP788.d
   Date * 23-OCT-1997 13:33
   Instrument : Y.I
   Sample ID : SO-MM5-1-8
   Column phase : DB-5
   Volume Injected (uL> : 1.0
                                                              Page 9
      of RTF, Inc.
Column diameter :   0,32
                                                          /chem/Y.i/10-23-97.b/YP788.d   (Part  1  of 2)
0.0
                                                                       11        12
                                                                         Time  
-------
     Data fii le: /chem/Y.i/10-23-97.b/YP788.d
     Date { 23-OCT-1997 13:33
     Instrument : Y.i
     Sample ID : SO-HH5-1-8
     Column phase : DB-5
     Volume Injected (uL>  : 1.0
                                               Triangle
                                                    of RTF, Inc.
                                             Column diameter :   0.32
    Page 10
                                 in
  5.2-.
  5.0-i
  4.8-i
  4.6-^
  4.4-j
  4.2-j
  4.0-.
  3.2-i
^•»-
H
I
                                                           /chem/Y.i/10-23-97.b/YP788.d   (Part 2 of 2)
         20
23
24
25
26
27        28
Time (min.)
29
30
31
32
33
34

-------
Data File: /chem/Y.i/10-23-97.b/YP788.d
Report Date: 23-Oct-1997  14:54
                                                                              Page 1
Data file
Lab. Id.
Inj  Date
Operator
Smp  Info
Misc Info
Comment
Method
Meth Date
Cal  Date
Als  bottle
Oil  Factor
Integrator
Sample Type:
                              TRIANGLE LABORATORIES, INC.
                           SEMI-VOLATILE QTJANTITATION  REPORT
              /chem/Y.i/10-23-97.b/YP788.d
              43433
              23-OCT-1997 13:33              Autotune  Date:  22-Oct-97 09:14:0
              DD                                Inst ID:  Y.i
              SO-MM5-1-8
              185-7-2A-C,E
              /chem/Y.i/10-23-97.b/cclist.m
              23-Oct-1997 14:39 target
              23-OCT-1997 09:12              Cal  File:  YP783.d
              4
              1.000                            Target Version:  Target  2.20
              HP  RTE                           Compound  Sublist: pah.sub
               AIR
                                                        CONCENTRATIONS
  Compound*

*  1 1,4-Dichlorobenzene-d4
*  2 Naphthalene-dS
*  3 Aeenaphthene-dlO
•  4 Phenanthrene-dlO
•  5 Chry««ne-dl2
*  6 Perylene-dl2
$  7 2-Fluorophenol
$  8 Phenol-dS
$  9 2-Chlorophenol-d4
$ 10 !<2-Diehlorobenzene-d4
$ 11 Nitrobenzene-d5
$ 12 l,3,5-Trichlorobenzene-d3
$ 13 l,4-Dibromobenzene-d4
$ 14 2-Fluorobiphenyl
$ 15 2,4,6-Tribromophenol
$ 16 Anthcacene-dlO
$ 17 Pyrene-dlO
$ 18 Terphenyl-dl4
  42 Naphthalene
  46 2-Methylnaphthalene
  50 2-Chloronaphthalene
  56 Acenaphthylene
  58 Acenaphthene
  65 Fluorene
  73 Phenanthrene
  74 Anthracene
  77 Fluoranthene
  78 Pyrene
  83 Benzola)anthracene
  84 Chrytene
  86 Benzo(b)fluoranthene
QUANT SIO
MASS
152.00
136.00
164.00
188.00
240.00
264.00
Compound
99.00
Compound
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
244.00
128.00
142.00
162 .00
152.00
154.00
166.00
178.00
178.00
202.00
•59 D no
24u . uu
228.00 3
252.00
OS-COLUMN
RT (REL RT)
10.214(1.000)
12.763(1.000)
16.411(1.000)
19.537(1.000)
25.271(1.000)
29.393(1.000)
Not Detected.
9.452(0.925)
Not Detected.
Not Detected.
11.290(0.885)
11.976(0.938)
12.863(1.259)
14.997(0.914)
18.064(1.101)
19.659(1.006)
22.531(0.892)
22.898(0.906)
12.806(1.003)
14.237(1.116)
16.117(0.982)
16.476(1.004)
17.561(1.070)
19.587(1.003)
19.702(1,008)
22.567(OTSS3L1*'"
-^'l-. °ittt nirn
RESPONSE
458159
1487169
860099
1322472
1531806
2077760

1489537


1071904
989049
878330
2198028
658947
3644235
3713702
2843543
938092
630000
30926
6399
23520
69913
, 8455
[ "Tn^OJ—
l» y s \ " ^—>
59151
A f1^ O|a •
( ng)
40.00
40.00
40.00
40.00
40.00
40.00

77.37


76.49
80.01
82.46
82.27
102.67
102.71
82.49
90.84
24.92
25.55
0.81
0.28
0.94
2.07
0.26
1.18
0.05
FINAL
( ug)







77.37


76.49
80.01
82.46
82.27
102.67
102.71
82.49
90.84
24.92
25.55
O.SKa)
0.28UQ)
0.94 (a)
2. 07 (a)
0.26UQ)
1.18UQ,
	 O.Ugfxl
                                                                         -^1
                                               Data Review:
                                               Date: U

-------
Data  File: /chem/Y.i/10-23-97 .b/YP788.d                                   Page 2
Report Date:  23-Oct-1997  14:54


                                                            CONCENTRATIONS                    _ —
                             QUART SIQ                      OH-COLOMN     FINAL
  Compound*                      MASS        RT (RKL RT)  KBSPOHSK   (   ng)   (  ug)
   87 Benzo (k) f luor»nthene          252.00      2frr»»tflT3TB1	2m	0.04      O.Otd
   88 Benzo(e)pyrene                Compound Hot Detected.
   89 Benzo(»)pyrene              252.00      29.>81UiB«0)	57*?	B7TI	0". 11 («
   90 Perylene                   252.00      2^-r+*Hl.UUfr)	-5246	n.ii>-	e • 18 (j
   91 Ind»no(l,2,3-cd)pyr»n»          Compound Hot D«t«et«d.
   92 Dlb«nz(*,h)anthraocn*           Compound Hot D«taetad.
   93 B«nzo(g,h,i)p«ryl»n«            Compound Hot 0«t«ot«d.
QC Flag  Legend

a  - Target compound  detected but, guantitated amount
     Below Limit  Of Quantitation(BLOQ).
Q  - Qualifier signal failed  the ratio  test.

-------
Data File: /chem/Y.i/10-23-97.b/CAA/YP788.d
Report Date:  23-Oct-1997  15:01
                                                                 Page 1
                               TRIANGLE  LABORATORIES,  INC.
Data file
Lab. Id.
Inj  Date
Operator
Snip  Info
Hisc Info
Comment
Method
Meth Date
Cal  Date
Als  bottle
Dil  Factor
Integrator
                                                            REPORT
             SEMI-VOLATILE  QUANTITATION
/chem/Y.i/10-23-97.b/CAA/YP788.d
43433
23-OCT-97  13:33                 Autotune Date:
DD                                Inst ID:  Y.i
SO-MM5-1-8
185-7-2A-C/E
                                        22-Oct-97  09:14:0
/chem/Y.i/10-23-97.b/tlicaa.m
23-Oct-1997 10:51
23-OCT-97
4
1.000
HP  RTE
09:56
Sample  Type:  mm5
Cal  File:  YP784.d
Target Version:  Target  2.20
Compound  Sublist: CAAl.sub
                                                        CONCENTRATIONS
  Compound*

*  1 1,4 Dichlorob*nz«n*-d4
*  2 N»phth»l«n«-d8
*  3 Ac«n»phth«n«-dlO
*  4 Ph«n»nthr«n«-dlO
*  5 Chry«*n«-dl2
*  6 P»ryl«n«-dl2
$  7 2-Fluoroph«nol
$  8 Phanol-d5
$  9 2-Chloroph«nol-d4
$ 10 1,2-Dichlorob*nz«n*-d4
$ 11 Hitrob«nz«n«-dS
$ 12 l,3,5-Trichlorob.nz«n«-d3
$ 13 l,4-Dibromob«iz*n*-d4
$ 14 2-Fluorobiph«nyl
$ 15 2,4,6-Tribromoph«nol
$ IS Anthr»c«n«-dlO
$ 17 Pyr«n«-dld
$ 18 T«rph«nyl-dl4
  20 n-NitroBodim«thylamin*
  21 Cumana
  23 Ph»nol
  24 Anilin.
  27 bi«-(2-Chloro«thyl)«th.r
  26 Banzyl Chloride
  29 l,4-Dichlorob»nz«n«
  31 2-M«thylph«nol
  32 3/4-ltethylphanol
  33 Ac«toph«non«
  34 n-Nitro«omorpholin«
  35 o-Toluidin.
  36 R«xachloro«thana
QUANT SIO
MASS
152
136
164
188
240
264
.00
.00
.00
.00
.00
.00
Compound
99
.00
Compound
Compound
82
185
240
172
329
188
212
244
74

94
gl
91
146
10(

105
106

.00
.00
.00
.00
.80
.00
.00
.00
.00
. 00
.00
n n
. u u
. 00
.00
.00
. 00
. 00
.00
.00
.00
Compound
10
12
16
19
25
29
Not
9
Mot
Mot
11
11
12
14
18
19
22
22
4

9


10

10
Xfl
Mot
RT (RBL RT)
.214(1.
.763(1.
.411(1.
.537(1.
.271(1.
.393(1.
000)
000)
000)
000)
000)
000)
ON-COLUKM
RESPONSE
458159
1487166
860099
1322472
1531806
2077760
(
40.
40.
40.
40.
40.
40.
ng)
00
00
00
00
00
00
FINAL
( ug)






D«t«ot«d.
.452(0.
925)
1489537
87.
77
87.77
D«t«ot«d.
D«t«ct«d.
.290(0.
.976(0.
.863(1.
.997(0.
.064(1.
.659(1.
.531(0.
.898(0.
-Ill 10

.474(0.
787 (JK
_20(l (0
.250(1.

.983(1.
yf t (1 	
885)
938)
259)
914)
101)
006)
892)
906)
aci>

928)

»aa>
004)

075)
O7*»
1071904
989049
878330
2198028
658947
364423S
3713698
2843543
?9«RC

98543


11151

138901
etjAi
D«t«ct«d.
71.
71.
81.
87.
115.
103.
77.
92.
A

6.


0.

8.


79
32
60
10
29
60
64
15
47

57

22 	
72

19


71.79
71.32
81.60
87.10
115.29
103.60
77.64
92.15
A 42.

6.57

	 0,72
0.72

8.19


                                                         PP
                                                        »PP
                                                   Data Review:
                                                   Date:  id 1

-------
Data  File:  /chem/Y.i/10-23-97.b/CAA/YP788.d
Report  Date:  23-Oct-1997  15:01
Page  2
                                                                        CONCENTRATIONS
   Compound*

   37 Nitrob.nz.n.
   38 H,N-Dim.thyluilin.
   39 l,2-Dibromo-3-chloroprop»n.
   40 I.ophoron.
   41 o-Anisidin.
   42 1,4-Ph.nyl.n.diamin.
   43 1,2,4-Trichlorob.nz.n.
   44 N«phth»l.n.
   46 H.x»chlorobut»di.n.
   47 N,N-Di.thyl»nilin.
   48 af a, a-Trichlorotolu.n.
   49 Hydroquinon.
   51 2-Chloroac.toph«non.
   52 H.xachlorooyclop.ntadi.n.
   53 2,4,6-Trichloroph.no!
   54 2,4,5-Trichloroph.no!
   60 Biph.nyl
   61 Dim.thylphthalat.
   62 2,4-Dinitroph.nol
   63 4-Nitroph.nol
   64 2,4-Dinitrotolu.n.
   65 Dib.nzofuran
   66 Di-n-butylphthalat.
   67 4,6-Dinitro-2-m.thylph.no!
   68 Trifluralin
   69 H*x»chlorob«nz*n*
   70 4-Aminobiph»nyl
   71 P«nt»chloroph«nol
   72 P«ntachloronitrob«nz«n«
   73 4-Nitrobiph«nyl
   74 Banzidin*
   75 4,4'-M»thyl«n«dianilin«
   77 Dim«thylamlnoazobttnz«n«
   78 3,3'-Dim«thylb«nzidin«
   80 3,3'-Dim«thoxyb«nzidin»
   81 3,3'-Dichlorob«nzidin«
   82 M«thyl«n« bi«-ohloroanilin«
   83 bi»(2-Bthylh«xyl)phthal»t*
QUANT SIO ON-COLUMN
MASS RT (RBZi RT) RSSPONSK ( ng)

Compound Not D«t*ct*d.
03 00 1,1 , noi (0. 935) ^fi?° n "*!
Compound Not D«t«etad.

180.00 13-.C34 (OiDSO) 5097 — Or4J
128.00 12.806(1.003) 938092 26.80
Compound Not D«t«ot*d.



Compound Not D«t«ct«d.

154.00 15.205(0.927) 62543 2.13
163.00 15.837(0.965) 60060 2.49
Compound Not D.t.ct.d.
n«-00 -l.fi ^c I? ti. niai ^ 19*5 n •»•»


149.00 20.773(1.063) 448996 9.59
Compound Not D.t.ct.d.

Compound Not D.t.ct.d.
Compound Not D.t.ct.d.

Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
Compound Not D.t.ct.d.
149.00 25.336(1.003) 404215 11.04
FINAL
( ug)
^> f* P •*& *T
'F9^C(U

°'i0 .} F^ '•>
0.49
26.80
30i57— \ urf1 A /!/-
f-\ /fr(r
0.04 —1 '
	 ff 13v- p J,frtf

2.13
2.49
' 	 1~2*-\ P P SZ0^
0.92'
9.59 . 	
a*tf-
y


	 3 aj ^ p CL. c^^U-
11.04

-------
 Data File: /che»/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB-5
 Volume Injected (uL> : 1.0
42 Naphthalene
                                              Page 11
Column diameter :   0.32
Scan 1215 (12.806 min) of YP788.d
.
5.0-i
4.0-;
s j
•*™l
£2.0-i
^ 1.0-i
Oft-
•





i
•• .... ll 	 -II 	 	 --• - ll






i
1 ,,
.g T^ T i i • | i • • • | i i i • | i i i • | i . . • | • . i . | ... | .... | ... ,....,..,,,,
40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
.
5.0-j
4.0-!

3 * =
£2.0-1
1.0-!
0.0-
Scan 1215 (12.806 min) of YP788.d (Subtracted)





1
. ,,'.,, ,,, . ,. |l








1 .

40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
42 Naphthalene (PBM Reference Spectrum)
•
.
8.0-;
•
ro * •
< .
3 4.0-
XX "
>- "
2.0-
0 0—









ii .Hi iin. . i . i










40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Scan 1215 (12.806 min) of YP788.d (2 DIFFERENCE)
100-

504
25i

S -25-;

"*-50-j

-75-1
-100-










40 50 60 70 80 90 100 110 120 130 140 150
Mass/Charee
Mass 128.00
5.5^
5.0-i
4.5-j
4.0-j
3.5-j
S3.0-!
32.5-i
3_2.0-i
1.5-1
i.o-i
0.5-1
0 0-








ro
CM
T-H
J\j
~*A
*








LL
12.4 12.6 12.8 13.0" 13.2
Time (min.)
Mass 129.00
__. /s
6.0-5

5.0^
4.0:

? :
£ * •
"2.0-;


1.0-

0/\







5\
ro
CM
i
^<|A

s[
CM
•r-l








L
A^v,

.0 i i i i i | i i i i i i i | i i i | i i
12.4 12.6 12.8 13.0 13.2
Time (min.)
Mass 127.00
"
7.0-j
:
6.0-
•
5.0-
I4«H
^<
-3.0-5
2.0-;
.

1.0-;
0 0-

a*


ll




ro
S.
SM

1
A, 	 J









12.4 12.6 12.8 13.0 13.2
Time (min.)

-------
 Data File: /chew/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB-5
 Volume Injected (uL)  : 1.0
46 2-Methylnaphthalene
                                             Page 12
Column diameter  :  0.32
Scan 1415 (14.237 win) of YP788.d
3.5-1
3.0-1
2.5-j
o * :
XX * •
="•1.0-:
o.s-i
OrtJ







J.L j..i 1 i,^.^L _ 	 	
40 80 120








160 200 240 280 320 360
Mass/Charee
Scan 1415 (14.237 min) of YP788.d (Subtracted)
7 KJ
•J + -J ,
3.0-i
^ 2.5-j
o * :
-*1*5"
>-1.0-i
0.5-i








. Ill J,L -I. 	 	
.g t i i i , . i i | .
40 80 120








160 200 240 280 320 360
Mass/Charee

8.0-j
•
M * '
3 4.0-
XX
>- -
2.0-
On—
46 2-Meth






,1 III. nk ,J . , .
40 80 120
ulnaphthalene (PBM Reference Spectrum)







160 200 240 280 320 360
Mass/Charee
Scan 1415 (14.237 min) of YP788.d (Z DIFFERENCE)
100-
75-j
50-j
25-E
20-
o
3l»6-i
*~ 1 1-
'•
0.8:
0.4:
0 0-
I ro
\ ^
3










-
5
;






U^i/V
13.8 14.0 14.2 14.4 "14.6
Time (min.)
Mass 141.00
3.0-1
2.8-i
2.5-j
2.2-j
2.0-i
£1.8-:
< - ;
^1.2-j
0.8-i
0.5-j
0.2-1

.











13.8 14.0 14.
™
^^
*
1





I I | , 1, I | ! .
2 14.4 14.6
Time (roin.)
















-------
 Data File: /chew/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB-5
 Volume Injected 
    : 1.0 56 Acenaphthylene Page 14 Column diameter : 0.32 Scan 1677 (16.117 min) of YP788.d 6.0-j 5.0-1 ^4.0-i x : 1-°i 0.0J . ......ill . , ., JiL 1... ., ,ih . i . ..L. . ...illiifl 40 60 80 100 120 140 160 180 200 Mass/Charee 6.0-j 5 0- iJ * V . _4.0-j Ss.o-i X • i.o-i 0.0- Scan 1677 (16.117 nin) of YP78 8.d (Subtracted) Ii 1 1 .1 . .llij., ...... | i i | i i l | l l i | l i l | i i i f •! ••!""( >| •!• |. 1 | i i i | i i 40 60 80 100 120 140 160 180 200 Mass/Charee 8.0: ^6 Oj ff) <•> 34.0- 5_ 2.0- - 0.0- 56 flcenaphthylene (PBM Reference SF J i ll J ijl ., i. ,i ,|l >ectruw) 40 60 80 100 120 140 160 180 200 Mass/Charee Scan 1677 (16.117 min) of YP788.d (2 DIFFERENCE) 100- 75-j 50-j 25-j **" : «-25-j "*-50-j -754 100 : " i i ,,U ...J.L. I..I.....A <\ 40 60 80 100 120 140 160 180 200 Mass/Charee Mass 152.00 1.6-i 1 4-^ i2- .-.1.0- |°*8" 0.4-j 0.2-! 0.0- I • Li W JV\ i i i 1 i i i 1 i i i 1 'i r>i' | i i i"|' 15.8 16.0 16.2 ISA 16.6 Time (min.) Mass 151.00 3.6-j • 3.2-i 2.8-i 2.4^ **. '• S * : 31-6-: 0.8^ 0.4: . Of»- ri 1 ^Q n ^ i J " * \ rH 1 A KiA ALA /\ J 1 "i ^/V-uAvW^^Jf W^rvJ 1 * 15.8 16.0 16.2 16.4 16.6 Time (min.) Mass 153.00 7.0q 6.0-j 5 0- J. V ,-.4.0-1 < ; 1 S -I 1 3 *• i 7 a ^3 0- J I 1 1 '11 -*1 i Ak ? CM » / i » *•* « 1.0- o o- V U 1 1 V i / 1 . i ,i J hJ p u v V W U m \! 1 B. , . .n . W, I! llWfJl , ,fll 15.8 16.0 16.2 16.4 16.6 Time (min.)

-------
 Data File: /chem/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB-5
 Volume Injected *» ;
s-l.OH
o.s-i
0 0-






1 1 1
i l

1, H
111
IlllJIIIll, 111











40 80 120 160 200 240 280 320
Mass/Charge











360 400 440 480 520

58 ftcenaphthene (PBM Reference Spectrum)

8.0-
^6.0-

0
34.0-
,_
2.0-
0.0-







. ,









40 80 120 160 200 240 280 320
Mass/Charee
Scan 1727 (16.476 min) of YP788.d
100-g
75H
50-j
'25-i
Jt 0-|
3-25-i
*"-50-i
-75-!
100 =
1

"
j,i,v,i, , Jiii k <

1










360 400 440 480 520

(2 DIFFERENCE)







40 80 120 160 200 240 280 320 360 400 440 480 520
	 Mass/Charge

Mass 154.00
5.5-|
5.0-j
4.5-j
4.0-j
^3.5-j
fftf n:-
S •
3 2.5-;
^~ 2»0~
1.5-i
i.o-i
n ^"^ VO
II * iCl
a -.
f
l

s „
al S
I ^ J %
\ ^ 7 § ^

lit J 1s* ^s
u 1 1 11 1 1 1 ' i '"' '
0.5-iilJ 1 liMlil.Ai/IU
0.0-3
n\ i\ mini inniivrnMyviiif

16.0 16.2 16.4 16.6 16.8
Time (min.)
Mass 153.00
4.8-;

4.4-

4.0-i
3.6-
3.2-
^2.8-i
ro
^2.4-;
32.0-i
^1.6-
0*8^
0.4-

l~rS
1 ^^
1 * °°
S r^ ft "^ l°2n
3 S Jig
7 a Pjp3

1 111 I 11 g
fl IJ 1 7 1 a
f I / I*^H ll II III
1 1 I 1 1 1 4ll rlnl 1 1 U Mr U
, u , n/1
y In ill
1(111 III) /Will 11 Flu 1 1 llr 1
16.0 16.2 16.4 16.6 16.8
Time (win.)
Mass 152.00
1 6-
* «
1.4-

1.2-
-1.0:
<*"
|0.8,
^0.6-j
0.4^

0.2:
0.0-
I-^T^'
3
"



8
"°*
?^ . »«.
1^5 ii a ^
11 In TH 7 ' "^
u L.JluV^Ai
16.0 16.2 16.4 16.6 16.8
Time (min.)

-------
 Data File: /chem/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MH5-1-8
 Column phase :  DB-5
 Volume Injected (uL)  :  1.0
65 Fluorene
                                               Page 16
Column diameter :  0.32

2.4-.
2.0-i
^1.6-i
Si.2-
S0<9j

.O-1
4

.
1.4-i

1
^ 1.0-
o0.8-i
-0.6-i

^0.4-i
0.2-;
f\ ft '
y.u
i



•
8.0-

6 0-
s * :
c^
^4.0-
>. :
2.0-
0 0-
t


100-
75-
50-
25-
£ 0-
S-25-
**-50-
-75-









IU4
[" r"i'^"
10










vl lli.uii
" ' ' '
(0












\ 1 .1
1 • '
to





>il jbiSiU




40

Scan 1878 (17.561 win) of YP788.d





I y 1 III
lUlluL ill lu. Ll 1 L .tL U 1 1.. > ...A • i .1. 1 L ,

80 120 160 200 240 280 320 3
Mass/Charee
Scan 1878 (17.561 win) of YP788.d (Subtracted)








|j.ll.,,,|L l.,lli 111 ,1 nil ,1 in ll ,
80 120 160 200 240 280 320 3
Mass/Charee
65 Fluorene (PBM Reference Spectrum)
1







-
1 1
LJ,, , 1 Jl
80 120 160 200 240 280 320 3
Mass/Charee
Scan 1878 (17.561 win) of YP788.d (2 DIFFERENCE)



l.J^ Ml r^S ' 5n
A "V ^l\ '•Tn k. '
17.2 17.4 17.6 17.8 18.<
Time (min.)
Mass 165.00





OD p«r
in r£"l
•^ ',
.' |[\
1 [1J S
^ H^ ™}\ ^
"• 131 ^1 *"*
JH Hi t;j '
i i} \ i j ft
VAAV^^^r!* ftlJ-i-^O'V*
'"I*'1 I1'* (' " * 1 " *" 1
17.2 17.4 17.6 17.8 18.(
Time 
Mass 167.00
[~3
s





J
B S 55 £ II ^
^ S/l\] ( V

1. 1 mjju M / wL-LJ' r ]V|
1[ »| 1 if 1\*I V r 1 T
17.2 17.4 17.6 17.8 18.C
Time 
-------
 Data File: /chem/Y.i/'10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase :  DB-5
 Volume Injected 
    : 1,0 73 Phenanthrene Page 17 Column diameter : 0.32 Scan 2160 (19.587 min) of YP788.d 4.0-^ 3.5-j 3.0-j £2.0-= »- 1.0-j 0.5-j n n-3 1 ji.JLuiiulU..i..^^....jLi.. V.V | i i i | i i i | i i i | i 40 80 120 160 * 200 240 280 320 360 400 440 Mass/Charge Scan 2160 (19.587 min) of YP788.d (Subtracted) 4.0- 3.5-1 3.0-j -.2.5-i £2.0-j 3 1.5-: *- 1.0-1 0.5-j 0.0-3 i i ... .... 1 I.I IK ..... ,11. 1 ' 1' • 1 1 1 1 | ' » «• | ' 40 80 120 160 200 240 280 320 360 400 440 Mass/Charge 8.0- xx 6.0- to <^ *4-0' 5_ 2.0: o.o: 73 Phena •ithrene (PBM Reference Spectrum) , . . . 1 | 1 1 • | • • • | . • • | • • . | • . • | • • . | • • 40 80 120 160 200 240 280 320 360 400 440 Mass/Charge Scan 2160 (19.587 min) of YP788.d (Z DIFFERENCE) 100- 75:: 504 25^ S£ 0-1 « -25-' -50-j -75 -i •••§••» m '•« "* • •*••* ••• •*• * -V * * 40 80 120 160 200 240 280 320 360 400 440 Mass/Charge Mass 178.00 4.0-3 3.6-i • 3.2-i 2.8-i S2-0^ ^1.6-j 1.2: 0.8- 0.4-i rt 0- l~w u L 1 1 s i \\A \ *. A /xJ-1 , JLXV ^ A- IW-jLvWWxA^^^v 19.2 19.4 19.6 19.8" 20.0 Time (min.) Mass 179.00 7.0- 6.0- 5.0- xx 4.0- <_> x3.0- 1^^^. s 1 - ON T-l 1 U n Ai :::i i J II M 1 1 ill M IJ '"nlM \ H IIIRJl n li 1 raV ill In if I ll A A. I 111 ill II III iFlllll Fill I II 19.2 19.4 19.6 19.8 20.0 Time (min.) Mass 176.00 8.0T 7.0-: 6.0J 5.0-j XX '. ro . 3 j *-3'°1 2.0- 1.0-= 0 0- R s § ii * 5 j I 1 A 11 A i A | ji M WM I An A 111 "*v • - 1 • * • 1 - • • 1 • . • J . 1 . 1 . 19.2 19.4 19.6 19.8 20.0

-------
 'Data File: /chem/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB-5
 Volume Injected (uL>  :  1.0
74 flnthracene
                                              Page 18
Column diameter :   0.32
Scan 2176 (19.702 min) of YP788.d
:
1.2:

1.0-;

r°*8i
'x * •
^0.4^
0.2:
Oft-
«v
4
•





i
III
ilulMitf.^.'







1, , 1 i .
0 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee

4.0:

^3.0-
<
32.0-
X
"1.0-
0 0-
Scan 2176 (1<







Illllllll , .1,
J.702 min) of YP788.d (Subtracted)







, 1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
74 flnthracene (PBM Reference Spectrum)



8.0-


ro
Trl 4 fi-
XX

*~2.0-
0 0-










. . . J 1 . . J J











40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 2176 (19.702 min) of YP788.d (2 DIFFERENCE)
100-q
75-j
50-i
25-i

T* •
»-25-i
**-50-i
-75-i



I " I
, 1 h
JjlijiJiLiI] j , , i,k lil i
1




40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 178.00
4.0-1

3.6-i
-
3.2-i
2*H
-2.4-i
•*
!*-H
1*2"
0.8-.
0.4^
19
S
1 3
S









o
1 ^-"
J 1 '

.2 19.4 19.6 19.8 26.0 20.2
Time (min.)
Mass 176.00
8.0T
'-
7.0-i
6.0^
5 0*~
XX '.
^4.0-i
X ;
o#0~

.
2.0-:
•
l.O-j
0.0-
r~So
1 "^
s













CM
O
fx.
OS
•r*
\ \ 1 1
rt. rt 
-------
 Data File: /chem/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB-5
 Volume Injected (uL) : 1.0
77 Fluoranthene
                                              Page 11
Column diameter  :  0.32
Scan 2508 (22.086 «in) of YP788.d
d
4.0-j
3.5-i
3.0-i
32.5-i
I2-°1
-1.5-i
0.5-i
0.0-3






It
J






KlUjJUub...! L ..,..„....



i, 	 ,- •
\ i i | i i i ( ... , ... | i i i |
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2508 (22.086 min) of YP788.d (Subtracted)
4.0-=
3.5-i
3A
#o-
32.0-j
•21.5-
*~1.0-
0.5-
0.0-3





II
.
il
, a\ ..if







1 1
. n ,L Juli ..L. . li L j .,. ii —







• • • i • • • i • • • i • • • i • • • i
40 80 120 160 200 240 280 320 360 400
Mass/Charse

8.0-J
;
ff) * •
<
34.0:
>- '•
2.0-
0.0:
77 Fluoranthene (





x

t -
I (" i I T | II 17
PDM Reference Spectrum)








• • i i • i • i i i i i •• i i i . i i
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2508 (22.086 min) of YP788.d (Z DIFFERENCE)
100 -3
:
75 -j
so-i

25 -i
£ 
-------
 Data File: /chen/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-HH5-1-8
 Column phase : BB-5
 Volume Injected .
2.0-
0.0-










,,->!., i « i
I ' • • i • i | i i i | ... 7











. . .j ...... .g ... | .,.,.,
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 2575 (22.567 min) of YP788.d (2 DIFFERENCE)
100-

754

50-j
254
£ 
-------
 Data File: /chen/Y.i/10-23-97.b/YP788.d
 Date : 23-OCT-1997 13:33
 Instrument : Y.i
 Sample ID : SO-HM5-1-8
 Column phase : DB-5
 Volume Injected -0.5-
0.2-









_. ..i. 	 . JU
40 80 120 160 200
«in) of YP788.d






•





ll
1
lJ|l
240 280 320 360 400
Mass/Charee
Scan 2955 (25.293 min) of YP788.d (Subtracted)
8.0-1
7.0-j
g 0-:
* :
-5.0-i
ro j
33.0-1
*"2.0-!
1.0-j
0.0-3






1
1.1 I [1, 1,1,1 .1 ll.il! l,lj 1... 1.1 I

40 80 120 160 200








il








| II 1 , . |

240 280 320 360 400
Mass/Charee
84 Chrysene (PBM Reference Spectrum)

8.0-J

xx 6.0-
ro
I4-0'
«_ :
2.0-







^

. . . i,








I









40 80 120 160 200 240 280 320 360 400
Mass/Charee
100-
75-j
50-j
25-j
fc o-f
5-25-1
** :
-50H
-75-!

Scan 2955 (25.293 min) of YP

'
1 1
ill jl. Jl llj.- * :
0.6-
04-
***
0.2-

his

1 liT *
K
uiHl J *
1

m
1

i

ii i

I i
I

1 11 (1
25.0 25.2 25.4 25.6 25.8
Time (min.)
Mass 226.00
1.0-3
0.9-
0.8-
0.7-!
^0.6-
5°
o0.5-
•^0.4-
^0.3-

0.2^
o.i-i

0.0J


5
1









i n








— ^u
R
S

ro
*









25.0 25.2 25.4 25.6 25.8
Time (min.)
Mass 229.00
1.4-
1.2-j
1.0-

ro *
xO.6-
>-
0.4-

0 2-

0 0-
1— ro
1 S
ro
CNJ
in
Of
J?
•
r
Lo
r
Ml
i ii ii







i


m
111

III







25.0 25.2 25.4 25.6 25.8
Time (min.)

-------
 Data File: /chem/Y.i/10-23-97.b/CftfVYP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB.5-625
 Volume Injected (uL) : 1.0
23 Phenol
                                              Page 14
Column diameter :  0.32
Scan 748 (9.474 win) of YP788.d
7.0-j
6.0-

5.0-j
34.0-;
33'0'
^2.0-
1.0-
Ofi-
»u





i

111 ii > I J i
Jill h|l(i|j, ill i|l.i,,!n. 1
40 60 80
•





i 1

..l|.,i. ,.f . , . ji . v , Ik
100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 748 (9.474 min) of YP788.d (Subtracted)
7.0-
6.0-i
5.0-i

34.0-1
33.0-;
^2.0-i
i.o-i
0.0J







1 II J 1 ,
III i.lli .lit i. lii l
1 i i | i i ] i i






1
J 	 , . 1


40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee


8.0-

-6.0-
s
^4.0-
XX

*~2.0-







II 1
J. lllj .J. 	
40 60 80
23 Phenol (PBM Reference Spectrum)







100 120 140 160 180 200 220 240 260 280
Mass/Charee
Scan 748 (9.474 min) of YP788.d (2 DIFFERENCE)
100-
75-
50-
25-
£ 0-
S-25-
**-50-
-75-



i.l... ..,.11 	 i.l 	 !•. -i 	 iL 	 . . , .t . . .. .. hi



40 60 80 100 120 140 160 180 200 220 240 260 280
Mass/Charee
Mass 94.00
7.0-

6.0-

5.0-:
-4.0-;
o
3 3.0-
5-
2.0-
1A
.0-
0 0-













9.00 9.20 9.40
— •*
o£











t f l l i | r i 1
9.60 9.80
Time (min.)
Mass 65.00
4.0-
3.6-;
3.2-i
2.8-j
2 4-
fc*" .
"^
Sl.6-i
*"l.2-i
•
0.8-;
0.4-.
0.0-
9


£
?
1






w^rW 1
.00 9.20 9.40 9.60 9.80
Time (min.)
Mass 66.00
4.8-
4.4-
4.0-
3.6-
3.2-
-2.8-
|2.4-
32.0-
=-1.6-
1.2-
0.8-
0.4-
0 0-

ft ^





1


^



U 	 , .A.,
9.00 9.20 9.40 9.60 9.80
Time (min.)

-------
 Data File: /chem/Y.i/10-23-97.b/CflA/YP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB.5-625
 Volume Injected (uL> : 1.0
29 1,4-Dichlorobenzene
                                              Page 18
Column diameter :  0.32
Scan 857 (10.250 min) of YP788.d

8.0-

xx 6.0-

?4 0-
XX * •
-



1


>- Jjl 1 1
2.0H, . LI II
0.0-
i
ill In i hi III i






i
10 80 120 160 200 240 280 320 31
Mass/Charee









1
V) 400 440 480 520

Scan 857 (10.250 min) of YP788.d (Subtracted)
7.0-:
6.0-j
5 0-
<•>* V .
XS 4 rt-
ro ^*v
XX
>-2.0-

1.0-
0 0-










1 1










1 1
40 80 120 160 200 240 280 320 3
Mass/Charee

8.0:
xx 6.0-
ro
^
^4.0-
XX
>-
2.o:

29 1


















|
SO 400 440 480 520

,4-Dichlorobenzene (PBM Reference Spectrum)






*









40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charee
100-
75-i
50-i
25-1
£  4,0~
^ \

2.0:

1.0:
0 0-
1 c3
a

1

^
.
i
|

II

i \
s
a*
•
L




\ II
9.80 10.00 10.20 10.40 10.60
Time (min.)
Mass 148.00

3.6-d
3.2:

2.8:

2.4:
-.2 Oj
S * :
XX "
0.8:
0.4:
•
0 0-
i^- 1 ui
a Jo
* II «H 1 t I
o -^r
•<-< LO
1 °*

j 1
n
1 Jl

I

I III
1 1 ' '
9.80 10.00 10.20 10.40 10.60
Time (min.)
Mass 113.00
•
8*°1
7.0^
6.0-i
xxS.O^
S :-
X •
^3.0-i
2.0-i

i.o-i
0.0-
113
u •
a





IVJ
s
*
a
Jl III /i
1 1 ' * ' i ' ' '



U)
a*
\ ?
l|n A f
. i * 1 1 1 < 1 1 1
9.80 10.00 10.20 10.40 10.60
Time (min.)

-------
 Data File: /chem/Y.i/10-23-97.b/Cf)A/YP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-HM5-1-8
 Column phase : DB.5-625
 Volume Injected (uL> : 1.0
33 flcetophenone
                                              Page 21
Column diameter :  0.32

7.0-j
6.0-j
5.0-J
XX
£4.0-!
33.0-J
XX .
=-2.0-1
i.o-i







1

40


7.0-j

6.0-j
^5.0-j
S4*°"i
33.0-i
>-2.0-:
1.0-i







J
40


•
8.0-J

^4.0-
XX H
>- I
2.0-
0.0:







1
40


100-
75-j
50-1
25-j
£ oi
** :
-50-:

-75-1




U-<




40

Scan 960 (10.983 ruin) of YP788.d








•W













_ilH.ll . . i
80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 960 (10.983 min) of YP788.d (Subtracted)







in ii




ii>. 11







l
80 120 160 200 240 280 320 360 400 440
Mass/Charee






.ji J





33 flcetophenone (PBM Reference Spectrum)




'


80 120 160 200 240 280 320 360 400 440
Mass/Charee
Scan 960 (10.983 min) of YP788.d (2 DIFFERENCE)




M— f 	 L ,




80 120 160 200 240 280 320 360 400 440
Mass/Charee
Mass 105.00
1.2-j
-
1.0-j

'
0.8:
XX
in
S0.6-
X
XX
* "
09_
«c
0.0-









\
d
N\
JVli/
I1 1 1 1 1 1 1

ro
§^
o
fo
ICO


! ^

^ ,
1 h
A ft
i i/HuILi
5
^










i/
, i i i f r r r | i
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 77.00
1.0-^
0.9-;
0.8-
0.7-;
^0.6-
o0.5-
-o^-i
*"o.3-i

0.2-









A J
I~S
^ P
8 B
O |
" 4

K)
s
O
*"*

ft
I.

*"* J 1








10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 120.00
1.6-^

1.4-
:
!«2~
~ i.o-l
<*
!°-81
^0.6-j
0.4-^
•
0.2-
0 0-










.
J

1
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-
ffi
s
7
g
e I-
-------
 Data File: /chem/Y.i/10-23-97.b/CAfl/YP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB.5-625
 Volume Injected 
    : 1.0 60 Biphenyl Page 36 Column diameter * 0.32 - 3.5-j 3.0-j ^2.5-j o * : 0.5-! . ii • »i| p|inpii 40 60 3.5-j 3.0-i 2rr • **~ 1 1.5-1 ^i.o-i 0.5^ Ort- • ll, ,. 40 60 8.0- : £5 ^> -34.0- XX ""2.0- 1 ll 1 40 60 100- 75-i 50-i 25 -i £ _ _uyr i .. i 80 100 120 140 160 180 200 220 240 260 280 Mass/Charee Mass 154.00 3.6H 3.2: 2.8: 2.4: XX 0.8: 0.4: 0.0: -if> CM ID 5 i A, M i Ail A* *Mi /AuA/ 14.8 15.0 15.2 15.4- 15.6 Time (min.) Mass 152.00 6.0- 5.0: ~4.0- <^ 33.0- *".2.0: 1.0- 1 * a 4 \ \ CSJll si 1 A * I / V I AT rs ... , .1 .i ...r. r. .v^s*/.v\/. 14.8 15.0 15.2 15.4 15.6 Time (min.) 1.2- • 1.0-j 0.8- *^ J ; •^jO.6- :0.4- 0.2- 0 0- Mass 155.00 1 I CM 1 1 CM . !3 1 I i • 1 in ll 1 " II |1 uA A A Al^ili » f Uf 14.8 15.0 15.2 15.4 15.6 Time (min.)

-------
 Data File: A*em/Y.i/10-23-97.b/OWYP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB.5-625
 Volume Injected (uL> : 1.0
61 Dimethylphthalate
                                             Page 37
Column diameter :  0.32

3.2-!
2.8-j
2.4-j
52.0-i
^ois-i
0.4-:
Ort J
Scan 1638 (15.837 min) of YP788.d




i i 1
i hi J i j ,i il
lUlilMiiiliiUMn iLlii
^ V iitiiiiiiiii
40 80 120 16






,T. J . . ^ i , ! .
0 200 240 280 320 360 400 440 480
Mass/Charge
Scan 1638 (15.837 min) of YP788.d (Subtracted)
3.2-|
2.8-.

$2.0-!
|wj

*"0.8-j
0.4-;
0 0-







I i 1
A .,^li \ , 1.JJK .111.








.... J . . I I .
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
61 Dimethylphthalate (PBM Reference Spectrum)

8.0-
~6.0-
PO
§4.0-
>. ;







.i..li,.,






1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Scan 1638 (15.837 nin) of YP788.d (Z DIFFERENCE)
100 -:
75-i
50-1
254

•*• •
» -25-:
"-50-J
-754
100 :


•
j
^-^L^.^.-.JV.J-.I- * . . k i .
T



40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
Mass 163.00
3.2:

2.8-
2.4-
SlV
***
»-i.2:
0.8:

0.4^
0.0-




1




dUta

^^"^
ro
GO
*
a





T*
iS
ft '
fvf^nuJ \jr TX, fj*.
«II«IJ"'«II>II>I«I«"
15.4 15.6 15.8 16.0 -16.2
Time (min.)
Mass 194.00
1.8-3
1.6-:
1.4:

1.2-
ffil 0_
< *
o ;

^0.6^








,
0.4-51
0.2-1
0 0 /
15.4 15.6 15.
rf>
oo
in




3
T-l
\s>
T
il
11
[fii
3 16.0 16.2
Time (min.)
4.0-;
3.6^

3.24
2.84"
^24-:
32.04
x =
^1.6-
1 2-
Mass 164.00'
\n *5
a


1 1




III L
H j 1 1 n i
°*8il Wl J \l\lr




PS.
*J9
1 It J *^
In U Ji i
ill M \t
Illf
15.4 15.6 15.8 16.0 16.2
Tine (win.)

-------
 'Data File: /chem/Y.i/10-23-97.b/Cfl(VYP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB.5-625
 Volume Injected 
    : 1.0 66 Di-n-butylphthalate Paee 41 Column diameter : 0.32 Scan 2325 (20.773 min) of YP788.d 2.4-3 2.0: • ^1.6: £ ; x ; •-0.8- 5- ; 0.4: ...III.. .1.^.1,. .!._.. Jl... . .J. -^ V*V 1 . i i 1 i i i 1 i • • 1 i i. I . • • I . 40 60 80 100 120 140 - 160 180 200 220 240 260 280 Mass/Charee Scan 2325 (20.773 min) of YP788.d (Subtracted) 2.4-3 2.0-j _1.6: £l.2-i ~0.8- >• 0.4- 0 0- .1 .... , ,. .1. ... 40 60 80 100 120 140 | . 1 1 , 1 , 1 | I I 1 , I l| 1 | | 1 I | I , | | , 160 180 200 220 240 260 280 Mass/Charee 66 Di-n-butylphthalate (PBM Reference Spectrum) • - 8.0-_ ~6.0-] < §4.0^ ,_ ; 2.0- o.o: 1 1 .. ..II i. 1. I IL L | . 1 I , I , I ( . . , , I , , | . . 1 | . 1 1 ' 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charee Scan 2325 (20.773 min) of YP788.d (Z DIFFERENCE) 100- 75-j 50 -j 25H Q- 0~ u~ : ~-50-^ -75-i 100- "r " 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charee Mass 149.00 2.4-^ 2.2-1 2.0- 1.8-i * in • o 1 2" •Sl.O- *"0.8- 0.6- 0 4-^ v.t 0.2- li "~R a i 20.4 20.6 20.8 21.0 21.2 Time (min.) Mass 150.00 2.0- 1.8-i 1.6- 1.4- -1.2- O 1 ft- ^a1*0 ^0.8- >- : 0.6: 0.4: 0.2-i AAn/tfW/lrtAAiWY — TO fc * CM ^Vw1f^«^ NiiAf^P ^U i i | i i i | i i i | i i i | i i i | i 20.4 20.6 20.8 21.0 21.2 Time (min.) Mass 104.00 1.0-j 0.9^ 0.8- 0.7- .jO.6- o0.5- X ^0.4- '"o.s- 0.2- 0.1- 0.0- |~fc 1 ^* M«W nJKftttf 20.4 20.6 20.8 21.0 21.2 Time (min.)

-------
 Data File: /che«/Y.i/10-23-97.b/CAfl/YP788.d
 Date : 23-OCT-97 13:33
 Instrument : Y.i
 Sample ID : SO-MM5-1-8
 Column phase : DB.5-625
 Volume Injected 
    : 1.0 83 bis(2-Ethylhexul)phthalate Page 48 Column diameter : 0.32 Scan 2961 (25.336 win) of YP788.d 1.4-3 1.2-j 1.0-f £0.8-1 o ^0.6- XX 0.2-j 0.0-: 4 ll ll U i .JU .1. ... LrL i 0 80 120 • 1 ^ J - ||- 160 200 240 280 320 360 400 Mass/Charee Scan 2961 (25.336 min) of YP788.d (Subtracted) 1.4-d 1.2-i 1 0- J-.v . £0.8- < : o ^0.4-i 0.2-i 0 0- II J 1 1 Jl ....... i 40 80 120 160 200 240 280 320 360 400 Mass/Charee 8.0-i ~6.0: 34-°~ ;_ 2.o: o.o- 83 bis(2-Ethy 1 | 1 l.f.l. J . . T , 1 1 1 f 1 1 IhexyDphthalate (PBM Reference Spectrum) \ 40 80 120 160 200 240 280 320 360 400 Mass/Charge Scan 2961 (25.336 min) of YP788.d (2 DIFFERENCE) 100-: 75-= 50-i 251 Jt 0-1 S-25-1 "*-50-j -75-j -100- 'r"'T Vv -••"«-- - 40 80 120 160 200 240 280 320 360 400 Mass/Charee Mass 149.00 1.4-3 • 1.2-i 1.0-j u)Q.Q-. §0.6^ 0.4^ : 0.2^ ! 1 '• ': -^^^l^-^f^ 25.0 25.2 25.4 25:6 25.8 Time (min.) Mass 167.00 • 3.6-i 3.2-; 2.8-j 2j " .4- ^2.0- 3l.6i 0.8-; 0.4-f 0.0^ I— MD 1 ffy II « CM 1 1 1 .A.. ^1\ . i*r, f'/'n ***?( i >i v^ f^».rti ff- 25.0 25.2 25.4 25.6 25.8 Time (min.)

-------
, - *v, v-^ vx *v ^v? -V-
, -. ^"% ,; - ,, *^4 f' f, ->-, p&i
" '< ' * 'X s «. s v. ', " •. v. •. -x^ <. /: v JF«
' V. i % vt ^ JV S •* S %
V f
Project Number 43433
Sample File: YP789
aiefttF^lecfe^iftMMI'';"; *
TO ID: ISSf'^-E-' j ^ J^^^V ^
i-'\' ' : '

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S!-^ ;i - ]
Method 8270AMM5
Sample ID: SO-MM5-2rl7
'^J^I^^C^
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- - |?at^4«3|l3?2Eea ; 10
Dilution Factor:
t^rf'r-* ""' %sv
W?, %t ,
f&Wff * ^
1.00
^»&9$««$ya
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X.VK " ' ^ ,, ^

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•. ''/..'.:•. .£ '%S •• '"• ^ $ ' ., -."^ ,"•
Naphthalenc-d
Naphthalene
2-Methylnaphdialene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)an thracene
Chrysene
Perylene-d
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e) pyrene
Benzo(a) pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
D ibe nz(a, h) an thracene
Benzo(g,h,i) perylene
? '„ " ^ ?*•!,.-• sv 5- ^^ 5
IS 2
28.20 B
22.37
IS 3
U
0.64 ]
U
0.61 }
IS 4
1.16 ]
U
1.37 ]
IS 5
1.66 ]
U
U
IS 6 High
U
U
U
U
U
U
U
U
'F; -V^
12.75
12.80
14.23
16.41
16.12

17.55
19.54
19.59

22.09
25.26
22.56


29.40







^\T«g- v^^



0.43

0.44


0.28


0.19
0.19
0.15
0.16
0.14
0.16
0.16
0.14
0.19
0.16
""•if -.^ 1 ^ ^V*- % •. ""

10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
                             NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
              Savar v3.5
Printed: 17-70 11/13/1997

-------
Project Numben 43433

Sample File: YP789
                                                                                            Method 8270A MM5

                                                                                      Sample ID: SO-MM5-2-17
                             xSrirx. '•••• ^W^W
                      LIU***f «H  %f, % 4 •ss* vv  o
                      •j" ~ 
                      ^.,,^-S ^^-^^-K- ^ -•.!•  •  %-
Qient


£ XtM. -CJL^ AW*?^* MT^AV«.  -LV v"« •. 'vT  \ ^v% \"-5.%^^x •>«
       --   ,v<   '  x^^j^V^^ti's  '-H^x^u^
       \ - -.5  •,;,,", cc.*x ^X'SA ,^\  \ ?'>iv-^i5'-  x ,'
  ^   ..  -   \ - -t  o "•  * -" v*^ "^ ^ - i,  > .% '  ^
                                               Dilution Factor:    1.00
: ,"-^s ,^'7^ : ^ - -> '^
Phenol-d
s
Nitrobenzene-d
s
1 ,3.5-Trichlorobenzcne-d
3
1 ,4-Dibromobcnzene-d
4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
' 10
Terphenyl-d
St'Ve:
78.58

68.08

63.30

80.78

77.96
107.83
92.58

80.73
90.28
ilv'^/P
9.45

11.29

11.97

12.86

15.00
18.06
19.65

22.53
22.90
f'KS!
i

2

2

1

3
3
4

5
5
,Vt -^ ; ' ;
79

68

63

81

78
108
93

81
90
Reviewed by.
                                        Date  I/  /
                          NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit

     IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc

801 Capitola Drive • Durham, North Carolina 27713

Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                                             Savar v3.5


-------
I
    A •• •• .   •»

^fliL^IiSH
**{' *'V*SV%S-
^''tr '*;
 Project Number 43433
 Sample File: YP789
                                                                    Method 8270A MM5
                                                              Sample ID: SO-MM5-2rl7
 Clien
       ^MI;,  -^feX
1
Dilution Factor: 1.00



r1"* -"• .'.' ;-fesl 'Sf^^KJ^^SSS^i^I^W
1 ,4-Dichlorobenzene-d
n-Nitrosodimethylamine
Cumene
Phenol
Aniline
bis-(2-Chloroediyl)ether
Benzyl Chloride
1 ,4-Dichlorobenzene
2-Mediylphenol
Acetophenone
n-Nitrosomorpholine
j-Toluidine
Hexachloroethane
1 ,2-Dibromo-3-chloropropane
N,N-Diethylaniltne
Naphthalene-d
3/4-Methylphenol
Nitrobenzene
N,N-Dimediylaniline
Isophorone
o-Anisidine
1 ,4-Phenylenediamine
1 ,2,4-Trichlorobenzene
Hexachlo robutadiene
:i,a,a-Trichlorotoluene
Hydroquinone
IS 1 10.22
U
0.56 } 8.71
35.15 9.48
U
U
U
0.82 ] 10.24
U
8.93 BJ 10.99
U
U
U
U
U
IS 2 12.75
U
U
U
U
U
U
U
U
U
U
1.50


0.50
1.07
0.39

0.86

1.44
0.52
1.37
1.43
0.51

0.76
0.52
0.50
0.44
0.92
0.73
0.83
1.36
0.64
0.77
10
10
10
10
10
10
10
10
10
10
10
10
10
10

10
10
10
10
10
10
10
10
10
10
                          NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
 Triangle Laboratories of RTF, Inc.
 801 Capitola Drive • Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                    Savar v3.5

-------
Project Number 43433
Sample File: YP789
      Method 8270A MM5
Sample ID: SO-MM5-2rl7
Client Project; Sqgfattr JtfE ,\ 'tl-
', ^ - -^\VS


A 1 " "^ * " , ^"V^' A " ",
(flUtt^JLYtCt1 ff v •. s \" ^ "~ *$fi ^ *• ^
/x-*-1 >^\\ - -:\
2-Chloroacetophenone
Acenaphthene-d
Hexachlorocyclopentadienc
2,4,6-TrichlorophenoI
2,4,5-Trichlorophenol
Biphenyl
D ime diylp h thalate
2,4-Dinitrophenol
4-Nitrophenol
2,4-Dinitro toluene
Dibenzofuran
4,6-Dinitro-2-methylphenol
Trifluralin
Phenanchrene-d
10
Di-n-butylphthalate
Hexachloro benzene
4- Ami nobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Benzldine
4,4'-Methylenedianiline
Dimethylaminoazo benzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine

'•••.'• *v ^^..L^r^ W** *yf*»?ifj? s;
Dilution Factor: 1.00

i ' "iU *x ^i?rAr^ ""'- " »«r^- "
»0+Q wPE^ _,^ "• -• *r*«^l*4'' •• % !; % s »v 3^ jv <§;''
^^-::..\: ^;— i."v-,5
u
IS 3 16.41
U
0.39 J 14.80
U
1.22 J 15.20
1.89 J 15.84
U
U
U
U
U
U
IS 4 19.54

8.83 BJ 20.77
U
U
U
U
U
IS 5 25-26
U
U
U
U
U
V '; ' ':»*^V\
•.•.-•* V V-;;


^ '"^'r\*frT*»&. " "-" ^^ ;
'^~ y^ *<^*1S Jwtwtlt'' ^ "•"
!>?- ^i4\riv>
0.35

1.50

1.21


3.73
1.71
1.41
0.33
2.79
2.08



0.88
0.37
1.56
3.41
0.94

0.26
0.63
0.56
0.32
0.64




"-*-••* Vi^"'tT *H
•.v:..;"\, -. VjJl*****A- -JWwSwJt? :
^14'*^* v% 1
10

10
10
10
10
10
25
25
10
10
25
10


10
10
10
25
10
10

10
10
10
10
10
                          NA- Not Applicable; DeL Limit Detection Limit; Quan. Limit: Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 « Fax: (919) 544-5491
                      Savar v3.5

-------
Project Number: 43433                                                                 Method 8270A MM5
Sample File: YP789                                                              Sample ID: SOMMS-2^17
Client Project: Sagina
                                              Dilution Factor:    1.00
3,3'-Dichlorobenzidine                                   U                               0.48                    10
Methylene bis-chloroaniline                               U                               1.10                    10
bis(2-Ethylhexyl)phthalate                         20.27  B             2533                                      10
Reviewed by	S=>aMr      Date   II / O
                          NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.                                                                                Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713                                                       Printed: 12:42 11/13/1997

-------
   Data, file: /chem/Y.i/10-23-97.b/YP789.d
   Date •: 23-OCT-97 14:21
   Instrument : Y.i
   Sample ID : SO-HM5-2-17
   Column phase :  DB-5
   Volume Injected 
    : 1.0 triangle UbwWI* $ RTF* too. Column diameter : 0.32 Page 9 1.1- /chei»/Y.i/10-23-97.b/YP789.d (Part 1 of 2) 11 12 Tine (min.> 13 14 15 17 i 18

-------
   Data Rile: /chen/Y.i/10-23-97.b/YP789.d
   Date } 23-OCT-97 14:21
   Instrument :  Y.i
   Sample ID : SO-HM5-2-17
   Column phase  :  DB-5
   Volume Injected (uL>  : 1.0
        Triangle Laboratories
             of RTF, Inc.

          Column  diameter  :  0.32
                                                   Page 10
                                                                                                                                                                 CO
1.1-


1.0-


0.9-


0.8-


0.7-
0.5-
0.2-
0.1-
0.0


                                                         /chem/Y.i/10-23-97.b/YP789.d   (Part 2 of 2)
                                                         IT)
                                                         CM
20       21        22       23        24
                                                      25
 27        28
_Time (min.)
29
30
31
32
33
34

-------
.Data File: /chem/Y.i/10-23-97.b/YP789.d
 Report Date:  23-Oct-1997  15:26
                                                                 Page  1
 Data file
 Lab. Id.
 Inj  Date
 Operator
 Sxnp  Info
 Misc Info
 Comment
 Method
 Meth Date
 Cal  Date
 Als  bottle
 Dil  Factor
 Integrator
                 TRIANGLE LABORATORIES,  INC.
             SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/10-23-97.b/YP789.d
43433
23-OCT-97  14:21                 Autotune Date: 22-0ct-97
DD                                 Inst  ID: Y.i
SO-MM5-2-17
185-7-3A-F
                                                  09:14:0
/chem/Y.i/10-23-97.b/cclist.m
23-Oct-1997 15:22  target
23-OCT-1997
5
1.000
HP  RTE
09:12
 Sample  Type:  AIR
Cal  File:  YP783.d
Target Version:  Target   2.20
Compound  Sublist: pah.sub
                                                          CONCENTRATIONS
   Compounds

 *  1 l,4-Dichlorobanzana-d4
 *  2 Naphthal»ne-d8
 *  3 Acanaphthana-dlO
 *  4 Phenanthrana-dlO
 *  5 Chryaene-dl2
 *  S P*rylana-dl2
 $  7 2-Fluorophanol
 $  8 Phenol-dS
 $  9 2-Chlorophenol-d4
 $ 10 1,2-Dichlorobanzana-d4
 $ 11 Nitrobanzana-d5
 $ 12 1.3,5-Trichlorobanzana-d3
 $ 13 l,4-Dibromobanzana-d4
 $ 14 2-Fluorobiphonyl
 $ 15 2,4,6-Tribromophanol
 $ 16 Anthraeana-dlO
 $ 17 Pyrana-dlO
 $ IB Tarphanyl-dl4
   42 Naphthalene
   46 2-Methyln.phehalene
   50 2-Chloronaphthalane
   56 Aeenaphthylena
   58 Acanaphthana
   £5 Pluorana
   73 Phananthrana
   74 Anthracene
   77 Fluoranthana
   78 Pyrane
   83 Banzo(a)anthracene
   84 Chrysene
   86 Banzo(b)fluoranthena
QUANT SIO
MASS
152.00
136.00
164.00
188.00
240.00
264.00
112.00
99.00
132.00
Compound
82.00
185.00
239.80
172.00
329.80
188.00
212.00
244.00
128.00
142.00
162 . 00
152.00
154.00
166.00
178.00
178.00
202.00
202.00
228.00
228.00
252.00
ON-COLOMN
RT (REL RT)
10.216(1.000)
12.754(1.000)
16.411(1.000)
19.535(1.000)
25.261(1.000)
29.404(1.000)
8.089(0.792)
9.446(0.925)
10.216(1.000)
Hot Detected .
11.286(0.885)
11.973(0.939)
12.861(1.259)
15.000(0.914)
18.056(1.100)
19.651(1.006)
22.528(0.892)
22.896(0.906)
12.804(1.004)
14.232(1.116)
15.303 io.gaa>- —
16.116(0.982)
16.476(1.004)
^7^ 5 5 1 (i_B*M—
19.586(1.003)
19.694(1.008)
22.088(1.131)
22.564(0.893)
25.239(0.999)
2a-.aaau.663) —
la^tnm OCA\
RESPONSE
457778
1474295
864321
1484212
1946041
2631565
937
1511762
467

946009
774522
859747
2092326
694334
3685890
4618603
3588450
1051943
546689
24704
7625
43994
6508
53366
106043
5824
1911 ~~
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
0.07
78.59
0.03

68.10
63.20
80.78
77.94
107.65
92.56
80.75
90.23
28.19
22.36
T75T 	
0.64
0.34
iT7T — •*
1.16
0.18
1.37
1.66
«-ii
— OTIS —
FINAL
( ug)






0.07(aQR)
78.59
0.03UQR)

68.10
63.20
80.78
77.94
107.65
92.56
80.75
90.23
28.19
22.36
	 l.Ji(aU)-
0.64UQ) .
0.34UQ) .
• ««TT»0)"^
1.16U)
0.18 (a)
1.37 (a)
1.66UQ)
n 11 '-? — ^

                                                   Data Review:
                                                   Dats:  1.112.|^7

-------
Data File: /chem/Y.i/10-23-97.b/YP789.d
Report  Date:  23-Oct-1997 15:26
                                                    Page 2
  Compound*
                           QUANT SXG
                              MASS
                                        RT (RKL RT)
                             CONCENTRATIONS
                           ON-COLTMN    FINAL
                     RKSPONSB   (  ng)   (  ug)
  87 Benzo(k)fluoranthene
  88 Benzo(e)pyrene
  89 Benzo (•)pyrene
  90 Perylene
  91 Indeno(1,2,3-ed)pyrene
  92 Dibenz(m,h)anthracene
  93 Benzo(g,h,i)perylene

QC  Flag  Legend
252.00
252.00
252.00
252.00
M til (n ig«) «;
14 	 o.oi


2A.AM-H
L.8B1) 	 K
Lg fl 02 	

•\
"-

  Compound Hot Detected.
  Compound Not Detected.
  Compound Not Detected.
a  - Target  compound detected but,  guantitated amount
     Below Limit Of Quantitation(BLOQ).
Q  - Qualifier signal failed the  ratio  test.
R  - Spike/Surrogate failed  recovery limits.

-------
Data File:  /chem/Y.i/10-23-97.b/CAA/YP789.d
Report Date: 23-Oct-1997  15:28
                                                                 Page 1
Data file
Lab. Id.
Inj  Date
Operator
Smp  Info
Misc Info
Comment
Method
Meth Date
Cal  Date
Als  bottle
Dil  Factor
Integrator
                               TRIANGLE LABORATORIES,  INC.
                                                            REPORT
             SEMI-VOLATILE  QUANTITATION
/chem/Y.i/10-23-97.b/CAA/YP789.d
43433
23-OCT-97  14:21                 Autotune Date:
DD                                Inst ID:  Y.i
SO-MM5-2-17
185-7-3A-F
                                        22-Oct-97 09:14:0
/chem/Y.i/10-23-97.b/tlicaa.m
23-Oct-1997 10:51
23-OCT-97
5
1.000
HP  RTE
09:56
Sample Type: mm5
Cal  File:  YP784.d
Target Version:  Target  2.20
Compound Sublist: CAAl.sub
                                                        CONCENTRATIONS
  Compound*

*  1 1,4 Dichlorob.nz.n.-d4
*  2 N»phth»l«n»-d8
*  3 Ac.n»phth.n.-dlO
*  4 Ph«n»nthr«n«-dlO
*  5 Chry««n«-dl2
*  6 P«ryl»n«-dl2
$  7 2-Fluoroph«nol
$  8 Ph«nol-dS
$  9 2-Chloroph«nol-d4
$ 10 l,2-Dichlorob.nz.n.-d4
$ 11 Nitrob.nz.n.-d5
$ 12 l,3,5-Trichlorob.nz»n»-d3
$ 13 l,4-Dibromob.nz.n.-d4
$ 14 2-Fluorobiph.nyl
$ 15 2,4,6-Tribromoph.no!
$ 16 Anthr»c.n.-dlO
$ 17 Pyr.n.-dlO
$ 18 T.rph.nyl-dli
  20 n-Nitro»odim.thyl»min.
  21 Cum.n.
  23 Ph.no1
  24 Anilin*
  27 bi.-(2-Chloro.thyl).th.r
  28 Benzyl Chloride
  29 1,4-Dichlorob.nz.n.
  31 2-M.thylph.no1
  32 3/4-M«thylph.no1
  33 Ac.toph.non.
  34 n-NitroBomorpholin*
  35 o-Toluidin.
  36 H.xachloro.than.
QUANT SIO
MASS
152
136
164
188
240
264
112
99
132

82
185
240
172
329
188
212
244
105
94

63
01
y i
146
106
108
.LUC
105
56

IOC
.00
.00
.00
.00
.00
.00
.00
.00
.00
Compound
.00
.00
.00
.00
.80
.00
.00
.00
. 00
.00
.00
Compound
.00
nn
. uu
.00
.00
nn
. uu
.00
. 00

. 00
Compound
10
12
16
19
25
29
8
9
10
Not
11
11
12
15
18
19
22
22
8
9
Not
^

10

10

Not
RT (RBI. RT)
.216(1
.754(1
.411(1
.535(1
.261(1
.404(1
.089(0
.446(0
.216(1
D.t.c
.286(0
.973(0
.861(1
.000(0
.056(1
.651(1
.528(0
.896(0
.713(0
.475(0
.000)
.000)
.000)
.000)
.000)
.000)
.792)
.925)
.000)
t.d.
.885)
.939)
.259)
.914)
.100)
.006)
.892)
.906)
.853)
.927)
ON-COLDMN
RES PONS B
457778
1474295
864321
1484212
1946041
2631565
937
1511762
467

946009
774522
859747
2092326
694334
3687417
4618603
3588450
14645
526594
(
40
40
40
40
40
40
0
89
0

63
56
79
82
120
93
76
91
0
35
ng)
.00
.00
.00
.00
.00
.00
.07
.15
.02

.91
.34
.94
.51
.88
.40
.00
.54
.55
.14
FINAL
(






0
89
0

63
56
79
82
120
93
76
91
0
35
ug)






.07
.15
.02

.91
.34
.94
.51
.88
.40
.00
.54
.55
.14
D.t.c t*d.
,781 (tt

.244(1

.986(1

357)

.003)

.075)

5171

12592

151270

.

0

8

D.t.ct.d.
57

.82

.93


	 a

0

8


c.,
/
.82
'"V
.93


                                                     Data Review:
                                                     Dats:  n

-------
Data  File:  /chem/Y.i/10-23-97.b/CAA/YP789.d
Report  Date:  23-Oct-1997  15:28
Page  2
                                                                         CONCENTRATIONS
   Compound*

   37 Nitrobenzene
   38 N, It-Dime thy laniline
   39 1, 2-Dibromo-3-chloropropane
   4 0 Isophoron.
   41 o-Anicidine
   42 1,4-Phanyl.nediamine
   43 1,2,4-Trichlorob.nz.n.
   44 Naphthalene
   46 Hexachlorobutadi.ne
   47 N,N-Di.thylanilin.
   48 a, a, a-Trichlorotoluene
   49 Hydroquinon.
   51 2-Chloroacetophenone
   52 Hexaohlorocyclopentadiene
   53 2,4.6-Trichlorophenol
   54 2,4,5-Trichloroph.no!
   £0 Biphenyl
   61 Dimethylphthalate
   62 2,4-Dinitrophenol
   S3 4-Nitroph«nol
   £4 2,4-Dinitrotoluene
   €5 Dibenzofuran
   66 Di-n-butylphthalate
   67 4,6-Dinitro-2-m.thylph.nol
   68 Trifluralin
   69 Hexachlorobenzene
   70 4-Aminobiphenyl
   71 Pentachlorophenol
   72 Pentachloronitrobenzene
   73 4-Nitrobiph.nyl
   74 Benzidine
   75 4,4'-Methylenedianiline
   77 Dim«thylaminoazob«nz«n«
   78 3,3'-Dim»thylb«nzidin«
   80 3,3'-Dim«thoxyb«nzidin«
   81 3,3'-Dichlorob«nzidin«
   82 Mathylcn* bi»-chloroanilin»
   83 bi.(2-Ethylh«xyl)phthalat«
QUANT SIS ON- COLUMN
MASS RT (RSL RT) RBSPONSB ( ng)

Compound Not Detected.
Compound Not Detected.

180.00 ll.aJMO.99i) 	 W7W2 — 1.23
128.00 12.804(1.004) 1051943 30.32
Compound Not Detected.



Compound Not Detected.
196.00 14.799(0.902) 3068 0.39
196.00 14.799(0.902) 3068 atK
154.00 15.202(0.926) 35873 1.21
163.00 15.835(0.965) 45791 1.89
1R4 nn 1.C 716(1.020) IQB-? 	 n 1^


165.00 Id 099 (1.984) '0361 	 Lib
149.00 20.769(1.063) 464077 8.83
198.00 17,731(1.080) «" n •"»
Compound Not Detected.
283.80 19.016(0.973) .. m£S 	 s^-aa 	
169.00 •"».], flijtn^ftM 	 3TO7 OTM 	
Compound Not Detected.
Compound Not Detected.
152.00 20.105(3 "5.9 o.aa




212.00 23 . 877 (0 i»43) TH 0.02
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
149.00 25.333(1.003) 941724 20.26
FINAL
( ug)
-•••V y. pJ^LfT"
_^^ -fp^

S-PJ*
30.32
•\ PM+

- ™'
0.39 j
1.21
1.89
\
1*" \ PP -fc'w
I'll/
8.83

0 ly/ '
, .,\
i-"> \
	 n ?s \ ff D 9~£lA
(rr2S^ ] V rJyu
J-"s y
HJ-.UJ /
20.26

-------
 Data File: /chem/Y.i/10-23-97.b/YP789.d
 Date : 23-KT-97 14:21
 Instrument : Y.i
 Sample ID ; SO-MM5-2-17
 Column phase : DB-5
 Volume Injected  '•
o3.0-
x •
^2*°~
1.0-i




.
•
8.0:
~6.0-
tf>
<
^4.0-
>- I
2.0-
0 0-



100-
75i
50-:

25-1
£ H
= -25-:
^-504
-75-f











f ,« » J
tO 80 120

Scan








. /^ -,, ./
40 80 120











1 t ^ • I
40 80 120

Scan





V » *t» Wl "" *T ** "•



40 80 12C

Scan 1214 (12.804 min) of YP789.d
-








160 200 240 280 320 360 400 440
Mass/Charee
1214 (12.804 min) of YP789.d (Subtracted)









160 200 240 280 320 360 400 440
Mass/Charee
42 Naphthalene (PBM Reference Spectrum)








%

160 200 240 280 320 360 400 440
Mass/Charee
L214 (12.804 nin) of YP789.d w«w \\tfJ \y *\_
12.4 12.6 12.8 13.0 13.2
Tine (min.)
Mass 127.00












^A^vAN
12.4 12.6 12.8 13.0 13.2
Time (min.)

-------
 Data File: /chem/Y.i/10-23-97.b/YP789.d
 Date : 23-OCT-97 14:21
 Instrument : Y.i
 Sample ID : SO-MM5-2-17
 Column phase : DB-5
 Volume Injected (uL> : 1.0
46 2-Methylnaphthalene
                                              Page 12
Column diameter :  0.32
Scan 1413 (14.232 min) of YP789.d
3.2-3
2.8-^

2.4-j
s2*°i
3i.2-i
=~0.8-i

0.4-i
0.0-3









. ll (I., i 1 .III III Ilil .ilill - .- .It.. - . 1

40 60 80 100
*




















120 140 160 180 200
Mass/Charee
Scan 1413 (14.232 min)
3.2-
2.8-f
2A\

£l.6-i
1-1 '•
"- 0.8-i
0.4-;
ft ft-








1 II. . .ll.. ,1 .1.. ..1 1 	 1
U.U | i i i | i i • | i i i | i •
40 60 80 100
of YP789.d (Subtracted)


















120 140 160 180 200
Mass/Charee
46 2-Methulnaphthalene (PBM Reference Spectrum)
.

8.0:
S6*0^
0 •
34.0-
J_
2.0-1







^

ll II 1 ll. II ll,, 1.1 . 1
40 60 80 100


















120 140 160 180 200
Mass/Charee
Scan 1413 (14.232 min) of YP789.d (Z DIFFERENCE)
100-:
75-j
50-j
25-j
£ 0-!
S-25-j
**-5o4
-75-j
— iflfl-




•II ' !•" | •!»"• I*1 -Mil • ••*•"• 	 -'•



40 60 80 100








120 140 160 180 200
Mass/Charee
Mass 142.00
3.2-]
-
2.8-

2.4-J
s2-°i
ol.6-
•3 :

^1.2-
0.8-

0.4:
0 0-













1
•g
^
T-l

o
1







1
13.8 14.0 14.2 14.4 "14.6
Time (min.)
Mass 141.00
2.8JJ
2.5-j
2.2-i
2.0-i
1O •
.8-
Lf) 1 ^~

sx !
s-l.OH
0.8-i

0.2-=
0.0^
Ho
5
II ?









__

3
;






\j. i/ Vi
1 'r i 1 i T i i i i
13.8 14.0 14.2 14.4 14.6
Time (min.)
















-------
    Data File:  /chem/Y.i/10-23-97.b/YP789.d
    Date :  23-OCT-97  14:21
    Instrument  :  Y.i
    Sample  ID : SO-MM5-2-17
    Column  phase  :  DB-5
    Volume  Injected 
£3.0-:

-2.0-

  1.0-i

  0.0
                        Scan 1675 (16.116 win) of YP789.d
Jjlll, liLlrjIllLLllllllin.^!.!.....!!,. ,,,,1,1 	 lll.l
1 III)
p., . ll..|.iii|llll|ll.l.i.... . ..,.,. .
 40      60      80     100     120     140
	Mass/Charge
                                                     160
                                                            180     200
                  Scan 1675 (16.116 min) of YP789.d  (Subtracted)
 5.0-1

 4.0-i

»     I

^2.0^

 l.Or
  0.0-
        i
       40
               Ik   .nllll   . li
               ^^^~^^^^T 1  I
              60      80      100    120     140
             	Mass/Charge
160
                                                       180
                                       200
                     56 ftcenaphthylene (PBM Reference Spectrum)
  8.0-
  2.0-
  0.0-
40
60
80
100     120    140
    Mass/Charge
                                               160
        180
                                                                    200
  lOOq
                 Scan 1675 (16.116 win)  of  YP789.d (2 DIFFERENCE)
«-25-
"-50,
  -75-
       40      60      80     100     120     140     160     180
       	Mass/Charge	
                                                                    200
                       220
                                                      220
                                                                             220
., . .1. .1.11. ..Jll. .,11 ....III... 	 •.»•
1 . . 1. . ,
L 	
                        220
                                                                                               Mass 152.00
                                                                                             15.80  16.00 16.20  16;40 16.60
                                                                                                 Time  (min.)	
                                                                                                 Mass 151.00
                                                                                             15.80 16.00 16.20  16.40 16.60
                                                                                                 Time (min.)
                                                                                                 Mass 153.00
                                                                                       15.80 16.00 16.20  16.40 16.6(
                                                                                          Time  (min.)	

-------
 Data File: /chem/Y.i/10-23-97.b/YP789.d
 Bate : 23-OCT-97 14:21
 Instrument : Y.i
 Sample ID : SO-HM5-2-17
 Column phase : DB-5
 Volume Injected 
    : 1.0 65 Fluorene Page 16 Column diameter : 0.32 1.2- 1.0-i - 0.8-j |o.6-i *• 0.2- 8*0~ xx 6.0- ro O| ^f 4 0"* XX >- " 2.0- 100- 75- 50- 25- £ o- "-50- -75- *,«• f i1^11" 10 ,l ^ 10 . I J 40 J „ 40 Scan 1874 (17.551 min) of YP789.d 1 1 i i.,LJ , Ln . L i i J. 80 120 160 200 240 280 320 360 400 440 Mass/Charge Scan 1874 (17.551 min) of YP789.d (Subtracted) 1 i 1 I 80 120 160 200 240 280 320 360 400 440 Mass/Charge 65 Fluorene (PBM Reference Spectrum) ' '\ ' \ 80 120 160 200 240 280 320 360 400 440 Mass/Charee Scan 1874 (17.551 min) of YP789.d (Z DIFFERENCE) i Lr-,-...TL.^ l .... 1 ... I . i . . 80 120 160 200 240 280 320 360 400 440 Mass/Charee 2.2- 2.0-j 1.8-i 1.6-i 1.4-i 51.2-! o ' x ^* ~ ^o.s-; 0.6-i 0.4-; 0.2-: ft 0 ' v.u 2.8-j 2.5-1 2.2^ 2. OH 1Q • .8- ^15- s^ -L + sJ . 3J1.2-: ^1.0-j 0.8-j 0.5-i 0.2-; 2.5-1 2.2^ 2.0- 1.8-j xx 1.5- i1^ X '• 0.8-i 0.5- 0.2- *v Mass 166.00 ^? ^-t; •
    -------
        Data File: /chen/Y.i/10-23-97.b/YP789.d
    
        Date : 23-OCT-97 14:21
        Instrument : Y.i
    
        Sample ID : SO-MM5-2-17
        Column phase : DB-5
        Volume Injected (uL)  : 1.0
    
      73 Phenanthrene
                                                                                                            Page 17
                                                           Column diameter :  0.32
      2.4-i
      2.0-:
    -1.6-i
    I1-2"
      0.
      0.4:
      0.0-
      2.4-j
    
      2.0-i
       0.4-i
       0.0-
       8.0:
    
    xx 6.0-
       0.0-
       100-
        75-j
        50-i
        25-i
    
    
    S-25-j
    
    
       -75-i
      -100-^r
                             Scan 2156  (19.586 rain)  of YP789.d
    jl.l.lllll.,.1 |J.I|i l.[lil.liil| ill[41. n..[i.if, [il.i[l.i ^iil,..!.!. .jM.!..!!!,,,.^!..
                   I     I
               . i. t\\\\\\\ li.iiin.iL .  .in  .   i. ..
                r ^  I  i |f . ,  , ,  , - r y
          40      60      80      100     120    140    160     180     200     220
                                        Mass/Charge
                      Scan  2156 (19.586 min) of YP789.d (Subtracted)
         •+•
    -t-
                                                                        J»-
           40      60      80     100     120     140     160    180     200     220
                                        Mass/Charee
                           73 Phenanthrene (PBM Reference Spectrum)
                    .,
           40      60      80     100     120     140     160    180     200     220
                                        Mass/Charee
                      Scan 2156 (19.586 min) of  YP789.d (2 DIFFERENCE)
           40      60      80     100     120     140     160    180     200     220
                                        Mass/Charee
                                                                                              Mass 178.00
                                                                                      19.20 19.40 19.60  19.80 20.00
                                                                                             Time  (min.)
                                                                                                         Mass 179.00
                                                                                                  19.20  19.40  19.60 19.80 20.00
                                                                                                         Time (min.)
                                                                                                         Mass 176.00
                                                                                       19.20  19.40  19.60 19.80  20.00
    

    -------
     Data Filet /chem/Y.i/10-23-97.b/YP789.d
     Date : 23-OCT-97 14:21
     Instrument :  Y.i
     Sample ID : SO-MM5-2-17
     Column phase  :  DB-5
     Volume Injected (uL) : 1.0
    77 Fluoranthene
                                                Page 19
    Column diameter :   0.32
    Scan 2503 (22.088 min) of YP789.d
    a
    3.54
    3.0-1
    2.5-!
    xx ;
    
    Sl.SJ
    0.5-j
    
    
    
    
    
    
    
    ll 1
    .
    
    
    
    
    
    iJJJuLli,a,u,l,. i
    
    
    
    
    
    
    L. ... i i . *
    11 ' i ' ' ' i ' ' f i ' ' ' i ' ' '
    40 60 80 100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    Scan 2503 (22.088 min) of YP789.d (Subtracted)
    3.5-j
    3«0~
    
    ^2.5-j
    o :
    -21-5":
    5— 1 ft —
    ' :
    
    
    
    
    
    
    
    
    1
    i
    
    
    
    
    
    
    
    
    ...Uli.il.iL 	 	 . , i..,..L
    
    
    
    
    
    ii. i i . i
    40 60 80 100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    77 Fluoranthene (PBM Reference Spectrum)
    8.0:
    •
    g6*0'
    I4-0:
    >.
    2.0:
    •
    0.0-
    
    
    
    
    
    
    
    
    
    i ' 1
    i \\ 	 1
    
    
    40 60 80 100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    Scan 2503 (22.088 min) of YP789.d (2 DIFFERENCE)
    100-g
    75-j
    50-1
    25-1
    «-25:
    **-5o4
    
    -75-1
    -100-
    
    
    I
    i Jl 	 L
    
    
    
    >l» L. J • i L.f it i*** 	 	 ». u,t i* .1 L, . i k . i ., « . 1. >b. I'lir* ' ' *• • i i
    i
    
    
    
    40 60 80 100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    Mass 202.00
    6.0-j
    5.54
    5.04
    4.5-1
    4.0-!
    ?S
    32.5-i
    >-2.0-j
    1.51
    1.0-1
    0.5-j
    0.0-
    
    
    
    
    §
    a
    i'
    
    
    
    	 J
    
    
    
    
    
    
    
    
    
    
    
    
    i • • i \ * * '
    21.60 21.80 22.00 22.20 22.40
    Time (min.)
    Mass 101.00
    1.1-i
    i.o-i
    •
    0.9-i
    0.8-^
    ^0.7-1
    O * :
    30.5-:
    0.3-j
    0.2-j
    °'11
    0 0-
    
    
    
    co n
    8.
    S
    i 1
    j
    i i
    1 lA
    , 1, A / " V J
    
    
    
    rfV SI
    21.60 21.80 22.00 22.20 22.40
    Time (min.)
    Mass 100.00
    
    3 2-
    •3 + £.
    2.8-
    
    2.4-;
    ~2.0-
    J*
    |1.6-
    0.8-
    
    0 4-
    v.t
    0 0-
    i
    
    
    
    
    
    
    
    
    
    
    \
    2 1
    CM
    J 1 II
    „ . A A AA/ \AA I VW*^*-V* f^fr
    21.60 21.80 22.00 22.20 22.40
    Time (min.)
    

    -------
      Data File: /chem/Y.i/10-23-97.b/YP789.d
      Date : 23-OCT-97 14:21
      Instrument : Y.i
      Sample ID : SO-MM5-2-17
      Column phase : DB-5
      Volume Injected (uL> : 1.0
    78 Pyrene
                                                 Page 20
    Column diameter  :  0.32
    6.0-:
    5.0-!
    4.0-i
    XX
    23.0^
    :^
    1.0-
    L
    .0 1 '
    40
    5.0-i
    4.0-i
    XX I
    1.0-j
    n n-
    uL^i
    y.u— i i
    40
    8.0:
    £5 * •
    >*» "
    >- ".
    2.0-
    "PVtJ
    80
    Scan 2569 (22
    L^J-fUj
    .564 min) of YP789.d
    Jil. 	 	 • i 	 L
    120 160 200 240 280 320 360 400
    Mass/Charee
    Scan 2569 (22.564 mi
    1 ' T '"^
    80
    
    40
    100-
    75-
    50-
    25-
    {£ 0-
    3-25-
    "*-50-
    -75-
    -100-
    .Bi..»
    40
    80
    n) of YP789.d (Subtracted)
    'J -i • — 	 .. . i.
    120 160 200 240 280 320 360 400
    Mass/Charee
    78 Pyrene (P
    BM Reference Spectrum)
    120 160 200 240 280 320 360 400
    Mass/Charee
    Scan 2569 (22.564 win) of YP789.d (Z DIFFERENCE)
    80
    120 160 200 240 280 320 360 400
    Mass/Charee
    6.0-
    5.5-j
    5.0-i
    4.5-i
    4.0-i
    =-2.0-=
    1.5-j
    1.0-j
    0.5-1
    0.0J
    1.0-i
    0.9^
    ^0.7-
    ?0.6-
    30.5^
    ^0.4-
    0.3-1
    0.2-i
    "i
    !
    I
    
    3.2-i
    2.8-
    2.4-
    |1.6-
    0.8-
    0.4-
    0 0-
    /
    
    Mass 202
    .00
    ~*
    Si
    ^
    •
    L.A^
    VY'ir'rv1T''u^TT ! r'l-f-VT i-T-]-f
    22.20 22.40 22.60 22.80 23.00
    Time (min.)
    Mass 101
    \k
    sl
    .00
    ?i
    CM
    CO
    GO
    8S
    MIWM
    22.20 22.40 22.60 22.80 23.00
    Time (min.)
    Mass 100
    j
    J
    V^jw\Aw~M|/^yVf
    .00
    —CO
    &
    a
    §
    LJl,
    22.20 22.40 22.60 22.80 23.00
    Time (min.)
    

    -------
     Data File: /chem/Y.i/10-23-97.b/CAA/YP789.d
     Date : 23-OCT-97 14:21
     Instrument : Y.i
     Sample ID : SO-MM5-2-17
     Column phase : DB.5-625
     Volume Injected (uL> : 1.0
    21 Cumene
                                                  Page 13
    Column diameter  :  0.32
    Scan 641 (8.713 min) of YP789.d
    2.0-j
    1.8-j
    1.5-i
    
    Si!o-i
    3o.8-|
    ^0.5-j
    0.2-!
    
    .u
    
    
    
    
    
    
    
    | ,
    III 1
    
    40
    1.8-j
    1.5-j
    1.2-j
    ?1.0-=
    f o.8-i
    >-0.5-i
    0.2-i
    
    
    
    
    
    
    
    
    
    .v-" i
    40
    
    
    
    
    
    
    
    ,ll
    ||
    
    
    
    
    
    
    
    
    1 .1
    III II
    
    
    
    
    
    
    
    1
    
    1, 1 1 III
    
    
    
    
    
    
    1 ill
    1 1 1 1 Illj , ,
    
    
    
    
    I |
    1
    
    
    
    Mil
    
    •
    
    
    
    
    
    
    
    II ,
    
    60 80 100 120
    Mass/Charee
    
    
    
    
    
    
    1,
    III
    
    Sc
    
    
    
    
    
    
    i i. [|
    an 641 (8.713 min) of YP789.d
    
    
    
    
    
    ll
    ,,
    
    
    
    
    
    
    1 II
    
    
    
    1
    
    
    
    . 1 1
    60 80 100 i:
    
    
    
    
    
    
    Il ,
    >0
    
    
    
    
    
    
    
    1
    i| 1.
    
    140 160 180
    (Subtracted)
    
    
    
    
    
    
    i . i i
    140 160 180
    Mass/Charee
    21 Cumene (PBM Reference
    
    8.0-
    
    ^.6.0-
    ro
    ^
    -34.0-
    XX
    >-
    2.0-
    Ort- »
    
    
    
    
    
    
    
    
    
    1 . 1
    
    40
    
    
    
    
    
    
    
    
    
    |§
    
    
    
    
    
    
    
    
    '
    
    .. .1 . .Ill 1
    
    
    
    
    
    
    
    
    
    |
    
    
    
    
    
    
    
    
    
    
    i
    
    60 80 100 120
    Spectrum)
    
    
    
    
    
    
    
    
    
    
    
    140 160 180
    Mass/Charee
    Scan 641 (8.713 min) of YP789.d
    100-q
    75H
    50-1
    25-i
    . I
    "-25-J
    -50-
    -75 -i
    
    
    
    
    
    
    
    
    Ml
    
    
    
    40
    
    
    
    
    
    
    
    1 1 ll
    
    
    
    
    	 1.
    
    1
    ,
    
    
    
    
    [
    
    
    
    
    
    
    ,. k
    
    
    
    60 80 100 120
    (2 DIFFERENCE)
    
    
    
    
    .* i i i
    
    
    
    140 160 180
    Mass/Charee
    Mass 105.00
    9.0-:
    s.o-i
    :
    7.0H
    6.0-j
    mS.O-i
    o ;
    £ ' :
    =~3.0-i
    2.0-i
    o'll
    
    
    
    
    
    
    
    
    
    
    —TO
    *
    CO
    
    
    
    
    
    
    
    
    
    • i * \ * ' * i ' * ' i
    8.4 8.6 8.8 7.0 9.2
    Time (min.)
    Mass 120.00
    4.4-q
    4.0-i
    3.6-
    3.2-;
    2.8-i
    
    2 *
    3^]
    1.2-
    
    0.8-1
    0.4-
    
    0 0-
    
    
    TH
    CO
    1
    1
    
    
    1
    
    1
    i
    n
    II III
    
    
    I
    fl
    n
    8.4 8.6 8.8 9.0 9.2
    Time (min.)
    Mass 77.00
    1.6-
    
    1.4-
    
    1.2-i
    xvl.O-i
    r ;
    •^0.8-
    "* - ,j
    0.4-i
    
    \
    
    
    
    
    
    \ ro
    1 I ^
    "
    \ k
    o 2-4 \ i A u IL« k 1 1 k i
    T \fi Jt A.1I I I n ITI fv 1 II J 1
    8.4 8.6 8.8 9.0 9.2
    Time (rain.)
    

    -------
     Data File: /cheni/Y.i/10-23-97.b/Cflft/YP789.d
     Date : 23-OCT-97 14:21
     Instrument : Y.i
     Sample ID : SO-MM5-2-17
     Column phase : DB.5-625
     Volume Injected (uL) : 1.0
    23 Phenol
                                                  Page 14
    Column diameter  :  0.32
    Scan 748 (9.475 min) of YP789.d
    3.54]
    3.0-j
    2.5-j
    £2.04
    3 :
    ^1.0-1
    0.5-j
    
    
    
    
    i
    1
    I
    iil,i.,.i.i.l ,iill,...,.,.
    40 60 80
    *
    
    
    •
    
    
    J - *
    100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    Scan 748 (9.475 min) of YP789.d (Subtracted)
    3 5-^
    3.0-j
    
    2.5-i
    g2.0;
    gi.5H
    
    >-1.0-;
    0.5-
    0 0-3
    
    
    
    
    
    
    J
    
    
    i
    .. ,,!.!. .lllL,.,. .
    V.U • • | . i . | i .
    40 60 80
    
    
    
    
    
    
    
    
    
    I1 - '
    100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    
    •
    8.0-
    £6'°:
    §4.0-1
    ;_
    2.0-
    0 0-
    
    
    
    
    
    I |
    
    iilLjji, .1 ..
    40 60 80
    23 Phenol (PBM Reference Spectrum)
    
    
    
    
    
    
    
    100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    Scan 748 (9.475 min) of YP789.d (2 DIFFERENCE)
    100-
    754.
    504
    
    25-:
    £ Q~-
    
    S-25-j
    "*-5o4
    -75-:
    -100 :
    
    
    
    
    
    .ii.-..,.....,.......il........ 	 ..L. ...i . . . „.. .
    
    
    
    
    
    40 60 80 100 120 140 160 180 200 220 240 260 280
    Mass/Charee
    Mass 94.00
    3.6-1
    3.2-i
    2.8-;
    •
    2.4-;
    in 2.0-
    o
    xi.6-;
    *"1.2-:
    
    0.8-
    0.4-j
    0 0-
    
    
    
    
    
    
    
    
    
    
    i
    !^
    0%
    
    
    
    
    
    
    
    
    J
    9.00 9.20 9.40 9.60 9.80
    Time (min.)
    Mass 65.00
    i.o|
    
    0.9-j
    0.8-j
    
    0.7-J
    ^0.6-J
    If)
    00.5-!
    X :
    -0.4-i
    %.3-J
    0.2-i
    0.1-J
    
    
    
    
    
    
    
    
    
    
    
    A.AJ
    r>-
    
    
    
    
    
    
    
    
    
    
    .J(
    .U-^i — i — r— i — [— i — i — i | i i — r— | — i i i — |— i — i— i-
    9.00 9.20 9.40 9.60 9.80
    Time (min.)
    Mass 66.00
    •
    1.2;
    .
    1.0;
    
    ~0.8-
    in ;
    o
    30.6;
    ^
    0.4-
    
    0.2;
    .
    0 0-
    
    '
    
    
    
    
    
    
    
    
    
    
    
    
    ,- 	 	 	 *,o.
    9.00 9.20 9.40 9.60 9.80
    Time (min.)
    

    -------
       Data File: /chem/Y.i/10-23-97.b/CAfl/YP789.d
       Date : 23-OCT-97 14:21
       Instrument : Y.i
       Sample ID : SO-MM5-2-17
       Column phase : DB.5-625
       Volume Injected 
      : 1.0 29 1,4-Dichlorobenrene Page 17 Column diameter : 0.32 Scan 856 (10.244 min> of YP789.d 50 75 100 125 150 175 200 225 250 275 300 Mass/Charge Scan 856 <10.244 rain) of YP789.d (Subtracted) 7.0- 6.0- 5.0- 4.0- §3.0- ^2.0- 1.0- 0.0- II I 50 75 100 125 150 175 200 225 250 275 300 Hass/Charge 29 1,4-Dichlorobenzene (PBM Reference Spectrum) 8.0- 2.0-j 0.0- 50 75 100 125 150 175 200 225 250 275 300 Hass/Charge 100- 75-i SO-j 251 Jt 0^ S-25- "-50^ -75- -100 Scan 856 (10.244 roin) of YP789.d (2 DIFFERENCE) ,1,1 50 75 100 125 150 175 200 225 250 275 300 Hass/Charge Hass 146.00 7.0- 6.0- 5.0- fo4.0- 33.0- 2.0- 1.0- 0.0- 9.80 10.00 10.20 10.40 -10.60 Time (min.) Mass 148.00 9.80 10.00 10.20 10.40 10.60 Tine (min.) Mass 113.00 8.0-i 7.0-i 6.0-j 5.0-i 2.0- 1.0-j 0 o r-t i 'Oj.. JI^Q.UA 9.80 10.00 10.20 10.40 10.60 Time (min.)

    -------
     Data File: /chem/Y. i/10-23-97.b/Cftft/YP789.d
     Date : 23-OCT-97 14:21
     Instrument : Y.i
     Sample ID : SO-MM5-2-17
     Column phase : DB.5-625
     Volume Injected 
      : 1.0 33 flcetophenone Page 20 Column diameter : 0.32 8.0-j 7.04 ; 6.0-: £4.0-= Ss.o-i >- - 2*0" 1.0-j 0.0-3 1 II ll, T ' 40 8.0-= 7.0-= 6. Or £4.0-! rH : •5 3. OH ^2.0-j 1.0-j 0 fl- ,,nJ V»V | ' 40 8.0- 36'0; |4.0: >. 2.0- • ,i J 40 100- 75- 50- 25- u. 0- **- S-25- "-50- -75- ....i 40 Scan 960 (10.986 Bin) of YP789.d h i II. ,i.r... I.J. ...I. ,,l. . . , . ...I 1 60 80 100 120 140 160 180 200 Mass/Charee Scan 960 (10.986 n 1 I. , ii. ..LI.. . i,j. |ll . L, n|. „ .. j in) of YP789.d (Subtracted) 1 1 ..] , i i i . i i -p r '""| i .. | ... | ... | ...,...,. 60 80 100 120 140 160 180 200 Mass/Charee 33 flcetophenone (PBM Reference Spectrum) [ , 60 80 100 120 140 160 180 200 Mass/Charee Scan 960 (10.986 min) of YP789.d (Z DIFFERENCE) , • ,- k ,- •- i 1 ' 60 80 100 120 140 160 180 200 Mass/Charee Mass 105.00 1.2-J 1.0- 0.8- XX < 3 0.6- X "0.4- OO_ *£ 0.0- § « o °o * 1 S I 0 11 •» ro II II ^^ s II ll *^ sl - 3 fl s 1 s H s J r 1(11 't i ^tn /] •n M —TO ro . ' ' ^ 10.60 10.80 11.00 11.20 11.40 Time (min.) Mass 77.00 1.0-1 ; 0.9-: 0.8-i 0.7-; • ** 0.6-- So 5-^ ^X A A ' V0.4- ^0.3-; 0.2H 0.1-i rs 1 CM I — TO 1 • e^ 1 ^j J ro ft _4* s o IJ en Jl' O» Jl 5 ^ S ' /I , *l * A ll - • si fcf i i A 10.60 10.80 11.00 11.20 11.40 Time (min.) Mass 120.00 2.2- 2.0- 1.8- 1 6- X*U ^1'4" |l£ ^0.8- 0.6- 0.4- 0.2- 0.0- ^ |~S * P 53 o CTv ' CO 1 I S i S ' I ^ vA ll 1 s ULIi .3? |h In, ft ON ^ M , 10.60 10.80 11.00 11.20 11.40 Time (win.)

    -------
     Data File: /chen/Y.i/10-23-97.b/Cfifl/'YP789.d
     Date : 23-OCT-97 14:21
     Instrument : Y.i
     Sample ID : SO-MM5-2-17
     Column phase : DB.5-625
     Volume Injected -0.4-i
    0.2-;
    
    
    
    1
    
    
    
    5
    Scan 1492 (14,
    
    
    
    
    
    1 1 1
    III
    
    i
    i i
    ,11
    ikUJij
    D 75 100 125 150
    799 min) of YP789.d
    •
    
    
    
    
    
    i -H -
    175 200 225 250 275 300 325
    
    
    
    
    
    
    
    
    
    Mass/Charee
    Scan 1492 (14.799 min) of YP789.d (Subtracted)
    2.0-:
    1.8H
    1.5H
    
    ro * :
    20.B-.
    "0.5-i
    
    0.2-.
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    1
    1 1 1
    1
    II . Ill 1
    50 75 100 125 150
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    175 200 225 250 275 300 325
    
    
    
    
    
    
    
    
    
    
    
    Mass/Charee
    53 2,4,6-Trichlorophenol (PBM Reference Spectrum)
    -1
    8.0-
    
    tfi '
    £.
    £4.0:
    5.
    2.0:
    
    
    
    
    
    
    
    ^ 1i .1
    
    
    
    
    
    1
    
    
    
    i L
    I
    i,
    !""« • 1 .11 	 Ill
    50 75 100 125 150
    
    
    
    
    
    
    
    
    4
    
    
    
    
    
    
    
    
    i
    175 200 225 250 275 300 325
    
    
    
    
    
    
    
    
    
    
    Mass/Charee
    Scan 1492 (14.799 min) of YP789.d (2 DIFFERENCE)
    100-g
    75 1
    50-q
    2H
    (4. 0 —
    i =
    "-50-!
    -75 -i
    
    1
    
    
    
    
    
    •f
    . ,.U> .4 •„• LU • J
    
    
    
    50 75 100 125 150
    
    
    I | ii
    
    
    
    175 200 225 250 275 300 325
    
    
    
    
    
    
    
    Mass/Charee
    Mass 196.00
    2.0-i
    1.8-
    1.6-i
    1.4-
    -.1.2-:
    ^1.0-i
    ^0.8-j
    0.6-
    0.4-;
    0.2-
    0.0^
    r8-
    
    
    
    
    
    
    
    
    
    
    
    *-«
    
    
    
    
    
    
    
    
    
    • i i i i i i i
    14.4 14.6 14.8 15.0- 15.2
    Time (min.)
    Mass 198.00
    2.4-H
    2.2-
    2.0-
    1 fi-
    
    1.6-
    -^1.4-
    ol.2-i
    ^51.0-
    >-O.B-.
    0.6-
    0.4-
    0.2-
    0 0-
    
    
    
    
    
    
    
    
    
    1 ,
    
    A
    1
    	 in. . . .
    "S
    
    
    
    
    
    
    
    
    
    II
    
    
    
    14.4 14.6 14.8 15.0 15.2
    Time (ruin.)
    Mass 200.00
    1 1-^
    i.o4
    Od-3
    * :
    0.8^:
    0.7-=
    §0.5^
    ^0.44
    0.3-=
    0.2-:
    0.1-=
    0 0-
    
    
    
    
    
    
    
    
    
    
    ~Ss
    ^
    
    
    
    
    
    
    
    
    14.4 14.6 14.8 15.0 15.2
    Time (min.)
    

    -------
     Data File: /che»/Y.i/10-23-97.b/Cflfl/YP789.d
     Date : 23-OCT-97 14:21
     Instrument : Y.i
     Sanple ID : SO-MM5-2-17
     Column phase : DB.5-625
     Volume Injected (uL> : 1.0
    60 Biphenul
                                                  Page 35
    Column diameter :   0.32
    Scan 1548 (15.202 min) of YP789.d
    6.0-:
    5.0-i
    ^4.0-i
    i3*°^
    X
    ~2.0-
    
    1 0-
    0>
    
    
    
    
    
    
    
    
    
    
    -
    
    
    
    
    1
    , 1
    
    
    
    40 60 80 100 120 140 160 180 200
    Mass/Charee
    Scan 1548 (15.202 min) of YP789.d (Subtracted)
    2.0-
    1.8--
    1.5-1
    ~1.2-i
    ?1*0-^
    sH *
    S0.8-;
    *-0.5-!
    
    0.2-j
    
    
    
    
    
    
    
    
    
    
    
    .
    
    
    
    
    
    II L 1
    1 i I ,i ... R i . 1 1. , . 1 1
    
    
    
    
    
    
    
    
    
    
    II 1
    40 60 80 100 120 140 160 180 200
    Mass/Charee
    60 Biphenyl (PBM Reference Spectrum)
    8.0:
    
    ~6.0^
    <°
    I4-0:
    >• '.
    2.0-
    0.0-
    
    
    
    
    
    
    i i 1
    .... |l. .11, ,,l .. ., , ,, . .,1
    
    
    
    
    
    
    
    
    
    40 60 80 100 120 140 160 180 200
    Mass/Charee
    Scan 1548 (15.202 «in) of YP789.d (2 DIFFERENCE)
    100-
    75-
    50-
    
    25-
    £ °"
    X
    -50-
    -75-
    -100-
    
    
    
    
    
    .,!
    1-
    
    
    ... .- .,f, i. i ...... ..L..,.. .k_r. _•.-., 	 i,. . _.J... J. .!„.._ i.i 1 .
    
    
    
    40 60 80 100 120 140 160 180 200
    Mass/Charee
    Mass 154.00
    2.0-;
    1.8-^
    1.6-i
    1.4-i
    1 2~
    5 * •
    ol.OJ
    ^ :
    -0.8^
    0.6^
    
    0.4-i
    0.2-:
    0 0-
    R
    |a
    
    
    
    
    
    -«r
    § s
    a
    I A '
    A^li (l. i
    kt\ 1/UvvtJW
    14.80 15.00 15.20 15.40" 15.
    Time (min.)
    Mass 152.00
    1.2-3
    :
    :
    l.Or
    0.9-:
    
    0.8-;
    ^.0.7-i
    go.6^
    3o.5-i
    0.3^
    0.2-=
    0.1^
    
    l~00
    1 °^
    1 Lf)
    I
    II
    
    ll
    
    
    J
    
    ^1 a"
    
    All 11
    
    
    
    
    
    
    
    
    
    
    
    
    1 f
    V
    60
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    
    , r
    14.80 15.00 15.20 15.40 15.60
    Time (min.)
    Mass 155.00
    1.1-1
    
    1.0-j
    0.9-=
    0.8^
    0.7-=
    ?0 6^
    ^5 * •
    30.5^
    0.3-E
    
    0.2-j
    o.i-:
    0 0-
    P
    \ '
    fl!
    
    
    
    CM
    0
    CM
    *
    1 in
    n ^
    Jl
    , 1 1
    I 1 /
    ,.Miifl..W.VUI.
    14.80 15.00 15.20 15.40 15.
    Time (min.)
    
    
    ^
    »
    0
    *
    n
    r+
    
    
    
    
    
    
    
    
    
    
    60
    
    

    -------
    Data File: /chem/Y.i/10-23-97.b/Cflfl/YP789.d
    Date : 23-OCT-97 14:21
    Instrument : Y.i
    Sample ID : SO-MM5-2-17
    Column phase : DB.5-625
    Volume Injected (uL) : 1.0
    1 Dimethylphthalate
                                                 Page 36
    Column diameter :  0.32
    Scan 1636 (15.835 min) of YP789.d
    7.0-
    6.0-j
    5.0-j
    54.0-j
    I3-0-;
    *^ '.
    ^2.0-j
    1.0-j
    Ort-i
    
    
    
    
    
    
    „
    iuu,
    .
    
    
    
    1
    
    1 J
    ^Lu.iLM,
    i
    
    .^i • i i » . ... w L i
    40 80 120 160 200 240 280 320 360 4<
    Mass/Charee
    
    
    
    
    
    
    
    
    1^ L
    )0 440 480
    
    Scan 1636 (15.835 min) of YP789.d (Subtracted)
    
    4.0-i
    
    .-.3.0-j
    ^2.0-
    v :
    *~1.0-
    0.0-
    
    
    
    
    
    
    
    
    
    
    
    
    ,A.,,4
    
    1
    .1... i i. . - 	 l.L i
    
    
    
    
    
    
    
    L I
    ii i j i ii | i i
    40 80 120 160 200 240 280 320 360 400 440 480
    Mass/Charee
    
    61 Dimethylphthalate (PBM Reference Spectrum)
    
    8.0-
    -6.0-1
    I4*0:
    ;_
    2.0-
    0 0-
    
    
    
    
    
    , J
    \A i, .„
    
    
    
    
    
    *
    i
    
    
    
    
    
    
    
    40 80 120 160 200 240 280 320 360 400 440 480
    Mass/Charee
    
    Scan 1636 (15.835 min) of YP789.d « DIFFERENCE)
    100-
    
    75-
    50-
    25-
    J£ 0-
    S-25-
    "*-50-
    -75-
    100
    
    
    
    
    ^sr
    
    
    
    i""1"*" t"" 	 L
    1
    
    
    
    
    
    
    L L L
    
    
    
    40 80 120 160 200 240 280 320 360 400 440 480
    Mass/Charee
    
    Mass 163.00
    H
    3.6-!
    3.2-j
    2.8-1
    xx2*4^
    |2.0^
    Sl.6-j
    *"1 9-
    1»2-
    0.8:
    0.4H
    0 0-
    j
    
    a*
    
    
    
    
    
    1
    
    lA I
    
    
    
    ii j<
    
    1 1 *~*
    \A~ L i A *
    ^vv** y w *-i_ u/ HJ^ xw Hwx-'1
    15.40 15.60 15.80 16.00 -16.20
    Time (min.)
    Mass 194.00
    2.0-j
    1.8-j
    1.6-1
    ^'2\
    
    S0|8j
    0.6^
    0<4j
    0.2H
    0 0-
    "yM
    o.o ^i i iM i 1 1 1 1 |l JMi [N 1 1 ifH'I
    15.40 15.60 15.80 16.00 16.20
    Time (min.)
    

    -------
     Data File: /chem/Y.i/10-23-97.b/OWYP789.d
     Date : 23-OCT-97 14:21
     Instrument : Y.i
     Sample ID : SO-MM5-2-17
     Column phase : DB.5-625
     Volume Injected 
      : 1.0 66 Di-n-butylphthalate Page 41 Column diameter : 0.32 Scan 2320 (20.769 min) of YP789.d 2.4-; 2.0-i 1 f>- P * : 3 : >• * 0 4- v»*» . 0.0- 1 ill . lL • .,il. . i.- 1 • rl''1!'''!'''^''!'''!'''!'''! 40 80 120 160 200 240 280 320 360 400 440 Mass/Charee Scan 2320 (20.769 min) of YP789.d (Subtracted) 2 A — .4-; 2.0- ~1.6- « ol.2- * ~0.8- 0.4- .,.,.» , t . .V | • • i | i . i | i i 40 80 120 160 200 240 280 320 360 400 440 Mass/Charee 66 Di-n-butylphthalate - : 0 8J v*u . 0.5-! 0.2^ -^ ..L VA a i. .. 20.40 20.60 20.80 21.00 21.20 Time (min.) Mass 150.00 2.4H 2.24 2.04 1.8-i 1.64 ^1.4-j ol.2- ^H ; ^o.s4 0.64 0.4-; 0.24 0.0" —ON ^^ rt 0
      -------
         Data File: /chem/Y.i/10-23-97.b/Cflft/YP789.d
         Date : 23-OCT-97 14:21
         Instrument : Y.i
         Sample ID : SO-MH5-2-17
         Column phase : DB.5-625
         Volume Injected 
        : 1.0 83 bis(2-Ethalhexyl)phthalate Page 50 Column diameter : 0.32 Scan 2953 (25.333 win) of YP789.d 3.2- 2.8' 2.4' Sl.6 -1.2 0.4 0.0 Wrl- 50 75 100 125 150 175 200 225 250 275 300 325 Mass/Charge Scan 2953 (25.333 rain) of YP789.d (Subtracted) 3.2 2.8 2.4 iH .21.2 "-0.8 0.4 0.0 4U H»- i. 50 75 100 125 150 175 200 225 250 275 300 325 Mass/Charge 83 bis(2-Ethylhexul>phthalate (PBM Reference Spectrum) 8.0' -6.0 §4.0 ^2.0- 50 75 100 125 150 175 200 225 250 275 300 325 Mass/Charge 100- 75 -I 50-j 251 : °1 '-50-i -75-i Scan 2953 (25.333 min) of YP789.d « DIFFERENCE) >r "T -100 1 50 75 100 125 150 175 200 225 250 275 300 325 Mass/Charge 3.2- 2.8- 2.4- 0.8- 0.4- 0.0- Mass 149.00 25.0 25.2 25.4 25-.6 25.8 Time (min.) Mass 167.00 25.0 25.2 25.4 25.6 25.8 Time (min.)

      -------
      % * "^V^ £ % '% xx "^ * *
      ' J- k t* ^>^S)> % * ^ '.v s\-X*"S'> ^
      A - ^ $*r*^' /">** < E
      s •: •.-.%••% •• v.
      Project Numben 43433
      Sample File: YP790
      Oteat Projects Sagfriaw^ MI ^* $V«
      |1J ID: laWHfcNT* , -:J-: :J -C^ ^C
      
      Vs '^i5 ^. S* % ^^ '. \,
      %- *,*
      
      \^pl^E«^ye^:^
      x^.tli^j|^*^iS^|
      V^§St^%Ra|^e10l|;i
      Dilution Factor:
      Seimces
      
      jfc#9Sf .'
      $UIBWN\
      1.00
      •'•V'^i'l-V:^^-'!
      Method 8270A MM5
      Sample ID: SO-MM5-3-37
      
      
      
      ^^ ': '.Y^i;3fffi
      Naphthalene-d
      Naphthalene
      2-Mediylnaphthalene
      Acenaphthene-d
      2-Chloronaphthalenc
      Acenaphthylene
      Acenaphthene
      Fluorene
      Phenanthrene-d
      to
      Phenamhrene
      Anthracene
      Fluoranthene
      Chrysene-d
      Pyrene
      Benzo(a)anthracene
      Chrysene
      Perylene-d
      Benzo(b)fluoranthene
      Benzo(k)fluoranthene
      Benzo(e)pyrene
      Benzo(a)pyrene
      Perylene
      Indeno(l ,2,3-cd)pyrene
      Dibenz(a,h)anthracene
      Benzo(g,h,i) perylene
      •.*• "\ '' \ •. f \ s? % \
      IS 2
      92.27 B
      136.69
      IS 3
      U
      2.14 ]
      0.94 ]
      1.33 J
      IS 4
      1.77 J
      0.34 J
      0.86 J
      IS 5
      1.05 J
      U
      U
      IS 6
      U
      U
      U
      U
      U
      U
      U
      U
      N % ' "•
      12.76
      12.81
      14.24
      16.42
      16.12
      16.49
      17.57
      19.54
      19.59
      19.70
      22.09
      25.28
      22.57
      
      
      29.40
      
      
      
      
      
      
      
      y^i&*&> v:;^f;jQtt^flia|
      10
      10
      0.44 10
      10
      10
      10
      10
      10
      10
      10
      0.24 10
      0.25 10
      0.19 10
      0.20 10
      0.18 10
      0.20 10
      0.19 10
      0.17 10
      0.23 10
      0.19 10
                                    NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
           IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
      
      Triangle Laboratories of RTF, Inc.                                                                                             Savar v3.5
      801 Capitola Drive • Durham, North Carolina 27713                                                               Printed: 09:55 11/13/1997
      

      -------
      Project Number: 43433
      Sample File: YP790
                                           Method 8270A MM5
                                     Sample ID: SO-MM5-3-37
                                                   Dilution Factor.    1.00
      \'' -, .., %- C- :',"*&&.'"-*
      Phenol-d
      5
      Nitrobenzene-d
      5
      1 ,3,5-Trichlorobenzene-d
      1 ,4-Dibromobenzene-d
      2-Fluorobiphenyl
      2,4,6-Tribromophenol
      Anthracene-d
      10
      Pyrene-d
      7 10
      Terphenyl-d
      
      77.47
      
      71.82
      
      68.00
      81.64
      83.52
      110.40
      98.43
      
      87.02
      94.18
      f*^:
      9.46
      
      11.30
      
      11.98
      12.86
      15-00
      18.07
      19-66
      
      22.53
      22.90
      ».:yp%
      1
      
      2
      
      2
      1
      3
      3
      4
      
      5
      5
      "^ •> ^v. s^^ x ^ \ %^% s :
      77
      
      72
      
      68
      82
      84
      110
      98
      
      87
      94
      Reviewed by.
      Date
      /°l~?
                                NA- Not Applicable; Det Limih Detection Limit; Quan. Limit: Quantitation Limit
           IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
      Triangle Laboratories of RTF, Inc.
      801 Capitola Drive • Durham, North Carolina 27713
      Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                           Savar v3.5
                                               Printed: 09:55 11/13/1997
      

      -------
                                                                                       v^  •• '  f f ^  ^>. £  ^
                                                                                    ^ ••••••       ^  ^>'- -,  '  v£. *V" "vs*'X-.
                                                                                      •"  -.       X j.  ^.J  x* *%"\^ ••  xs1- ••< -^
                                                                                  .:    '..i     v^^vaK ^ ..v..?.*
      Project Number: 43433
      Sample File: YP790
            Method 8270 A MM5
      Sample ID: SO-MM5-3r37
      
      > \ •? i '..
      
      
      
      <* "X "•
      *• "• \ ^ \
      1 ,4-Dichlorobenzene-d
      n-Nitrosodimethylamine
      Cumene
      Phenol
      Aniline
      bis-(2-Chloroethyl)ether
      Benzyl Chloride
      1 ,4-Dichlorobenzene
      2-Mediylphenol
      Acetophenone
      n-Nitrosomorpholine
      o-Toluidine
      Hexachloroethane
      1 ,2-Dibromo-3-chloropropane
      N,N-Diethylaniline
      Naphthalene-d
      3/4- Methy Iphenol
      Nitrobenzene
      N,N-Dimethylaniline
      Isophorone
      o-Anisidine
      1 ,4-Phenylenediamine
      1 ,2,4-Trichlorobenzene
      Hexachlorobutadiene
      a,a,a-Trichlorotoluene
      Hydroquinone
      
      I ^*fkf 7xi^^5^i^^^;^f
      Dilution Factor: 1.00
      
      •. -. f <. -. A -.y s % "? s ft^.v. -*v •.
      * ** ss % % •• ^ •f- "-^ % ? A^JjJj^WtotlsJ ^ % 'rf*^nvtfi?'':' % •.'' '^''^ " v Jv* "" % x **
      s% % . , X" XA%% . %. . "" C" ^ ' v% <4%'''' / "iS 'vs 'xNs'V^% ^ ''''i. ^% ^ -.
      % \ •:., v^.^5 %^^^^ ^^. •. ' •. $•'&* •,•••• •C**™ •. '*^- '• $s
      "• f- "" ^ *^%J "" "V ^"^ "^-f f 2"' f % ^ '\ * \ "*^ j "" "^
      IS 1 10.22
      U
      1.56 J 8.71
      11.09 9.48
      0.32 J 9.56
      U
      2.27 J 10.20
      1.28 J 10.25
      2.16 J 10.66
      13.55 B 10.99
      U
      U
      U
      U
      U
      IS 2 12.76
      U
      U
      U
      U
      U
      U
      U
      U
      U
      U
      •,•.-, f '. v. % >*r . v. -.
      \ ' •> "• •" %*•*•>• s' s
      vX v •.*<• "" "* ^ '•^"•'- S / §
      
      
      _. ^o^ % ^ s . r
      %rv& nrfltntTT •*** '" ''•
      % *^ •• / . ..
      1.59
      
      
      
      1.14
      
      
      
      
      1.54
      0.56
      1.46
      1-52
      0.55
      0.81
      0.56
      0.54
      0.47
      0.98
      0.78
      0.89
      1.45
      0.69
      0.82
      't|^|^> |
      E|^|^::i
      
      
      ^\ v^^v <• % ^ %x •* ' "*
      ^^ft3^!
      	 iO"' ""X •. . ^v 	 :
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
      10
                                NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
          IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
      Triangle Laboratories of RTF, Inc
      801 Capitola Drive • Durham, North Carolina 27713
      Phone: (919) 544-5729 • Fax: (919) 544-5491
                            Savar v3.5
                Printed 12:43 11/13/1997
      

      -------
      I
      If Pacif&i
       ',   '" *V, f' - '$ A -  "*t- •• -* ,V"  V "• O
      »..  -,  '"V- i  -  *     S$:  v"\ v"-.  ~5
          „•. •. ,< ,   s  .. ,  <  ^> ^-  ->X »'•%'•
           ,   '  '},   V    , x» %   •• - >s
       Project Number: 43433
       Sample File: YP790
                                                           Method 8270A MM5
                                                     Sample ID: SO-MM5-3-37
       CUeftfcPr^cfc^g^avt', MI 4< ^*
      1
      Dilution Factor: 1.00
      
      
      
      f"* ' v ':';' -V:.V.
      Z-Chloroacetophenonc
      Acenaphthene-d
      Hexachloroqfclopentadiene
      2,4,6-Trichlorophenol
      2,4,5-Trichlorophenol
      Biphenyl
      Dimediylphthalate
      2,4-Dinitrophenol
      4-Nitrophenol
      2,4-Dinitro toluene
      Dibenzofuran
      4,6-Dinitro-2-methylphenol
      Trifluralin
      Phenanthrene-d
      10
      Di-n-butylphthalate
      Hexachloro benzene
      4-Aminobiphenyl
      Pentachlorophenol
      Pentachloronitrobenzene
      4-Nitrobiphenyl
      Chrysene-d
      Bcnzidine
      4,4'-Methylenedianiline
      Dimediylaminoazo benzene
      3,3'-Dimethylbenzidine
      3,3'-Dimethoxybenzidine
      /;o^A*^0^^ lw ; ':^
      u
      IS 3 16.42
      U
      U
      U
      5.10 ] 15-21
      2.23 ] 15.84
      U
      U
      U
      2.49 ] 16.85
      U
      U
      IS 4 19.54
      
      8.67 ft] 20.77
      U
      U
      U
      U
      U
      IS 5 25.28
      U
      U
      U
      U
      U
      H^ti
      0.38
      
      1.57
      1.34
      1.26
      
      
      3.90
      1.78
      1.47
      
      2.91
      2.18
      
      
      
      1.00
      0.42
      1.77
      3.87
      1.07
      
      0.33
      0.80
      0.71
      0.41
      0.81
      fft?^
      10
      
      10
      10
      10
      10
      10
      25
      25
      10
      10
      25
      10
      
      
      10
      10
      10
      25
      10
      10
      
      10
      10
      10
      10
      10
                               NA- Not Applicable; Del Limit Detection Limit; Quan. Limit: Quantitation Limit
      
           IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
       Triangle Laboratories of RTF, Inc.
      
       801 Capitola Drive • Durham, North Carolina 27713
      
       Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                           Savar v3.5
                                                               Printed: 12:43 11/13/1997
      
      

      -------
                                                                               ^
      Project Number: 43433
      Sample File: YP790
                                                        Method 8270A MM5
                                                  Sample ID: SO-MM5-3-37
      Client Project: Sagitta%MI
      r ' ' ^ ?'- ''-^
      V'Days^c*e^::0$^M ;, x
      ; \l?ate^r^ted*l^J4^7\ ^
      - Response File:
      |/^K 3;
      ^P5^^J^
      s ^,-:f
      Dilution Factor: 1.00
      
      &8*lyf«!:., x „ " ^ ^,-"\'\C\'%-\ -. % ^ % %
      3,3'-Dichlorobenzidine
      Methylene bis-chloro aniline
      bis(2-Ethylhexyl)phthalate
      A-moattt ;-•
      -, ,,Vs
      Tf$- -k.
      21.21
      ••'•••••^
      ^t'Hi
      V ^s"
      U
      U
      B
      &^ -5 " - '•- 0
      r> ^^^ Sv- w \ i" „' „ ' <• s " ,
      ^W^" X^ ^ \ "•• v' ' '',' ^
      ^ * k^i-vv x ' :.* ,^'- -.^
      25.34
      s v •• \% > X
      . s^ •••••. s ^ •••> •••• y .
      ^ftiawiA^y^vo
      ^ % ^ ;C ?_;\; ^
      0.60
      1.39
      QU«t.UmU
      *\ vO*#
      •• •• ^% -. AS s ;
      > X1»g ^ :
      10
      10
      10
      Reviewed by.
      Date
                                NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
           IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
      Triangle Laboratories of RTF, Inc
      801 Capitola Drive • Durham, North Carolina 27713
      Phone: (919) 544r5729 • Fax: (919) 544-5491
                                                                         Savar v3.5
                                                             Printed: 12:43 11/13/1997
      

      -------
      Data file: /chem/Y.l/10-23-97.b/YP790.d
      Date.: 23-OCT-97 15:09
      Instrument :  Y.i
      Sample ID : SO-HM5-3-37
      Column phase  :  DB-5
      Volume Injected 
      -------
         Data,file: /chem/Y.i/10-23-97,b/YP790.d
         Date .: 23-XT-97 15:09
         Instrument : Y.i
         Sample ID : 50-1*15-3-37
         Column phase : DB-5
         Volume Injected 
        : 1.0 Page 10 Triangle o o Column diameter : 0.32 6.0- 5.8- 5.6 5.4- 5.2- s.o 4.8- 4.6- 4.4 4.2- 4.0- 3.8 3.6 2.4 2.2- 2.0- 1.8- 1.6- 1.4- 1.2- 1.0- 0.8- 0.2- e.o /chem/Y.i/10-23-97.b/YP790.d (Part 2 of 2) I fc + f~\ R in CM CM T-t 7 20 21 22 23 24 25 27 28 Time (min.) 29 30 31 32 T ' 33 ^ i ' 34

      -------
      Data File:  /chem/Y.i/10-23-97.b/YP790.d
      Report Date: 24-Oct-1997  06:54
                                                                       Page 1
      Data file
      Lab. Id.
      Inj  Date
      Operator
      Smp  Info
      Misc Info
      Comment
      Method
      Meth Date
      Cal  Date
      Als  bottle
      Dil  Factor
      Integrator
                       TRIANGLE LABORATORIES,  INC.
                   SEMI-VOLATILE  QUANTITATION REPORT
      /chem/Y.i/10-23-97.b/YP790.d
      43433
      23-OCT-97  15:09                Autotune Date:  22-Oct-97
      DD                                Inst ID:  Y.i
      SO-MM5-3-37
      185-7-4A-F
                                                        09:14:0
      /chem/Y.i/10-23-97.b/cclist.m
      24-Oct-1997 06:51  target
      23-OCT-1997
      6
      1.000
      HP  RTE
      09:12
      Sample  Type:  AIR
      Cal  File:  YP783.d
      Target Version:  Target  2.20
      Compound  Sublist: pah.sub
                                                              CONCENTRATIONS
        Compounds
      
      *  1 l,4-Dichlorob«nz«n«-d«
      •  2 Naphthal«n«-d8
      *  3 Ac«naphth«n«-dlO
      *  4 Ph«n»nthr«n«-dlO
      *  5 Chry««n»-dl2
      •  6 P«ryl»n»-dl2
      $  7 2-Fluoroph«nol
      $  8 Phanol-dS
      $  9 2-Chloroph«nol-d4
      $ 10 l,2-Dichlorob«nz«n«-d4
      $ 11 Nitrob»nz«n»-dS
      $ 12 l,3,5-Trichlorob«nz«n»-d3
      $ 13 l,4-Dibromob*nz«n*-d4
      $ 14 2-Fluorobiph«nyl
      $ 15 2,4,6-Tribromophanol
      $ IS Anthrac«n«-dlO
      $ 17 Pyr«n«-dlO
      $ 18 T«rph«nyl-dl4
        42 Naphthal«n«
        46 2-M»thylnaphthal«n«
        50 2-Chloronaphthal*n«
        56 Ac«naphthyl«n«
        58 Ac»naphth»n»
        65 Fluor«n«
        73 Ph«nanthr*n«
        74 AntAracan*
        77 Fluoranthvn*
        78 Pyr*n*
        83 Banzo(a) anthraon*
        84 Chry««n«
        86 B«nzo(b)fluoranth*n*
      QUANT SIO
      MASS
      152.00
      136.00
      164.00
      188.00
      240.00
      264.00
      112.00
      99.00
      Compound
      Compound
      82.00
      185.00
      239.80
      172.00
      329.80
      188.00
      212.00
      244.00
      128.00
      142.00
      i £? no
      IDA . uu
      152.00
      154.00
      166.00
      178.00
      178.00
      
      202.00
      30 a on
      **O • UU
      •*•) g ft ft
      *jfcQ • Uu
      252.00
      ON-COLDMN
      RT (RBL RT)
      10.218(1.000)
      12.763(1.000)
      16.421(1.000)
      19.537(1.000)
      25.275(1.000)
      29.403(1.000)
      7.316(0.716)
      9.456(0.925)
      Mot D*t*ct«d.
      Hot D«c»ot»d.
      11.296(0.885)
      11.976(0.938)
      12.864(1.259)
      15.003(0.914)
      18.066(1.100)
      19.660(1.006)
      22.532(0.891)
      22.899(0.906)
      12.807(1.003)
      14.241(1.116)
      16.119(0.982)
      16.486(1.004)
      17.568(1.070)
      19.588(1.003)
      19.703(1.008)
      RBSPONSK
      4303S4
      1386516
      827130
      1306920
      1533975
      2125148
      47891
      1401072
      
      
      938553
      782541
      816885
      2145031
      £80319
      3450884
      3924533
      2950812
      3236554
      3141382
      79028
      20453
      32030
      59246
      10776
      ( ng)
      40.00
      40.00
      40.00
      40.00
      40.00
      40.00
      3.77
      77.48
      
      
      71.84
      67.90
      81.65
      83.49
      110.22
      98.42
      87.05
      94.13
      92.23
      136.64
      2.14
      0.94
      1.33
      1.77
      0.34
      FINAL
      ( ug)
      
      
      
      
      
      
      3.77UQR)
      77.48
      
      
      71.84
      67.90
      81.65
      83.49
      110.22
      98.42
      87.05
      94.13
      92.23
      136.64
      2.14UQ)
      0.94UQ)
      1.33U)
      1.77U)
      0.34U)
      -trot D.c.at*?'471^ laK-ef
      22.568(0.893)
      
      2*r*an) W5>
      *- ~ •* ^
      52969
      
      
      l.OS
      
      
      f
      l.OS(aQ)
      
      	 0..03UOV
                                                      Data Review:
                                                      Date:
      

      -------
      Data File: /chem/Y.i/10-23-97 .b/YP790.d
      Report  Date:  24-Oct-1997 06:54
                                                                                       Page 2
        Compound*
                                  QUANT 310
                                    MASS
                                                               CONCENTRATIONS
                                                              OH-COZiQMH     FINAL
                                              KT (R1L RT) RESPOHSI   (   ng)   (  ug)
        87 Benzo(k)£luoranthene
        88 Benzole) pyrenei
        89 Benzo(a)pyrene
        90 Perylene
        91 Indeno(1,2,3-cd)pyrene
        92 Dibenz (a,h) anthracene
        93 Benzo (g,h, i) perylene
      
      QC  Flag  Legend
      252.00
      252.00
      252.00
      252.00
                                                (8.9CO)
                                                          MK3
                                                                  0.83
                                                                         ».83U)
                                            29.258 (0.94
                                                                             Uai I
                                                                             THJJ/
                                    CampouaA Hot D»t«ot»d.
                                    Conpovmd Hot D*t*ot*d.
                                    Compound Hot Detected.
      a  -  Target compound detected but,  quant ita ted  amount
           Below Limit Of Quantitation(BLOQ) .
      Q  -  Qualifier signal  failed the ratio test.
      R  -  Spike/Surrogate failed recovery  limits.
      

      -------
      Data File: /chem/Y.i/10-23-97.b/CAA/YP790.d
      Report Date:  24-Oct-1997  07:04
                                                                        Page  1
                                     TRIANGLE LABORATORIES,  INC.
      Data file
      Lab. Id.
      Inj  Date
      Operator
      Smp  Info
      Misc Info
      Comment
      Method
      Meth Date
      Cal  Date
      Als  bottle
      Dil  Factor
      Integrator
                                                                   REPORT
                   SEMI-VOLATILE QUANTITATION
      /chem/Y.i/10-23-97.b/CAA/YP790.d
      43433
      23-OCT-97  15:09                Autotune Date:
      DD                                Inst  ID: Y.i
      SO-MM5-3-37
      185-7-4A-F
                                              22-Oct-97 09:14:0
      /chem/Y.i/10-23-97.b/tlicaa.m
      23-Oct-1997 10:51
      23-OCT-97
      6
      1.000
      HP  RTE
      09:56
      Sample Type:  xmn5
      Cal  File:  YP784.d
      Target Version:  Target   2.20
      Compound Sublist: CAAl.sub
                                                               CONCENTRATIONS
        Compounds
      
      *  11,* Dichlorobenzene-d4
      »  2 N»phth»lene-d8
      *  3 Acen»phthene-dlO
      *  4 Phenanthrene-dlO
      *  5 Chry«ene-dl2
      *  6 Perylene-dl2
      $  7 2-?luorophenol
      $  8 Phenol-dS
      $  9 2-Chlorophenol-d4
      $ 10 l,2-Dichlorobenzene-d4
      $ 11 Nitrobenzene-dS
      $ 12 l,3,S-Trichlcrobenzene-d3
      $ 13 l,4-Dibromobenzene-d4
      $ 14 2-Pluorobiphenyl
      $ IS 2,4,6-Tribromophenol
      $ 16 Anthraeene-dIO
      $ 17 Pyrene-dlO
      $ 18 Terphenyl-dl4
        20 n-Nitrosodimethylaunine
        21 Cumene
        23 Phenol
        24 Aniline
        27 bi«-(2-Chloroethyl>ether
        28 Benzyl Chloride
        29 1,4-Dichlorobenzene
        31 2-Hethylphenol
        32 3/4-Methylphenol
        33 Acetophenone
        34 n-Nitroiomorpholine
        35 o-Toluidine
        36 Hexachloroethane
      QUANT SIQ
      MASS
      152.00
      136.00
      164.00
      188.00
      240.00
      264.00
      112.00
      99.00
      Compound
      Compound
      82.00
      185.00
      240.00
      172.00
      329.80
      188.00
      212.00
      244.00
      1 A. O ft
      1 % * U U
      105.00
      94.00
      93.00
      63.00
      91.00
      146.00
      108.00
      108.00
      105.00
      56.00
      infi.oo
      ON-COLOMN
      RT (REL RT)
      10.218(1.000)
      12.763(1.000)
      16.421(1.000)
      19.537(1.000)
      25.275(1.000)
      29.403(1.000)
      7.316(0.716)
      9.456(0.925)
      Not Detected.
      Not Detected.
      11.296(0.885)
      11.976(0.938)
      12.864(1.259)
      15.003 (0.914)
      18.066(1.100)
      19.660(1.006)
      22.532(0.891)
      22.899(0.906)
      8.715(0.853)
      9.477(0.927)
      9.562(0.936)
      9.719 fP.9Sll
      10.204(0.999)
      10.247(1.003)
      10.660(1.043)
      10.960(0.859)
      10.989(1.075)
      11 rufd iii)
      IB. iT4 fl.»7el
      RESPONSE
      430354
      1386516
      827130
      1306920
      1533975
      2125148
      47891
      1401072
      
      
      938553
      782541
      816885
      2145031
      680319
      3450884
      3924533
      2950812
      38470
      156252
      6042
      ____Z5*0— —
      54497
      18385
      23778
      1?2.1P -
      215752
      lift
      	 am 01
      ( ng)
      40.00
      40.00
      40.00
      40.00
      40.00
      40.00
      4.05
      87.89
      
      
      67.42
      60.53
      80.79
      88.39
      123.77
      99.27
      81.93
      95.50
      1.56
      11.09
      0.32
      2.27
      1.27
      2.16
      
      13.54
      
      	 *.«j — -
      FINAL
      ( ug)
      
      
      
      
      
      
      4.05
      87.89
      
      
      67.42
      60.53
      80.79
      88.39
      123.77
      99.27
      81.93
      95.50
      1.56
      11.09
      0.32
      	 0739
      2.27
      1.27
      2.16
      
      13.54
      	 a. 19
      
                                    Compound Not Detected.
                                                       Data Review:
                                                       Date:
      

      -------
      Data  File:   /chem/Y.i/10-23-97.b/CAA/YP790.d
      Report  Date:  24-Oct-1997  07:04
                                                                Page  2
         Compounds
                                          QUANT SIO
                                             MASS
                                                           RT  (RKL RT)
                                 CONCKNTRATIONS
                               ON-COLOMN      FINAL
                      RKSPONSS    (   ng)    (   ug)
       13 (47(n  qsn)	15044
       12.807(1.003)   3236554
      Not Detected.
       •La I->Q/I  -.BKI	14503
                                                                                    99.20
                                                        IT nf«n nnn)    3tnf7t
                                                                                    30.23-
      37 Nitrobenzene                     77.00       11.333(9.889)	8.7035	3.10
      38 N,H-Dimethylaniline              120.00       JJUMB (0 .882)	05919	9,83
      39 l,2-Dibromo-3-chloropropane        Compound Hot Detected.
      40 laophorone                       82.00       .IT i QH4 (0.941)	lUSbb       U.S1-
      41 o-Anieidine                        Compoun'd Hot Detected.
      42 1,4-Phenylenediamine             108.00       IS.C1T(1.867)	m	tT.Oi
      43 1,2,4-Trichlorobenzene           180.00
      44 Naphthalene                      128.00
      46 Hexachlorobutadiene                Compound
      47 H,N-Diethylaniline               134.00
      48 a,a,a-Trichlorotoluene           159.00
      49 Hydroquinone                     110.00       13. 5ti II
      51 2-Chloroacetophenone             105.00       13.9^6(1
      52 Hexachlorocyclopentadiene          Compound Hot Detected.
      53 2,4,6-Trichlorophenol            196.00
      54 2,4,5-Trichlorophenol            19£.00
      £0 Biphenyl                        154.00
      £1 Dimethylphthalate                163.00
      £2 2,4-Dinitrophenol                184.00
      £3 4-Hitrophenol                    139.00
      £4 2,4-Dinitrotoluene               165.00       1_» ..ain{i n->.»\	1134-9	l.CD-
      65 Dibenzofuran                     168.00       16.846(1.026)     72118       2.49
      66 Di-n-butylphthalate              149.00       20.769(1.063)    401230       8.£7
      £7 4,£-Dinitro-2-methylphenol       198.00       17 . S9» (1. 8T1)	T?n	O.U9
      £8 Trifluralin                        Compound Not Detected.
      £9 Hex&chlorobenzene                283.80
      70 4-Aminobiphenyl                  169.00
      71 Pentachlorophenol                  Compound
      72 Pentachloronitrobenzene            Compound
      73 4-Nitrobiphenyl                  152.00
      74 Benzidine                       184.00       T7 117 (n. 9"M 1-
      75 4,4'-Methylenedianiline            Compound Not Detected.
      77 Dimethylaminoazobenzene          120.00       12.9»t (0.90(i)
      78 3,3'-DimethyIbenxidine           212.00       23.914 (B.94£)-
      80 3,3'-Dimethoxybenzidine            Compound Hot Detected.
      81 3,3'-Dichlorobenzidine             Compound Not Detected.
      82 Methylene bie-chloroaniline      231.00       -85 , 3£1 10 . 9»»)	1OA4	U.1H
      83 bi«(2-Bthylhexyl)phthalate       149.00       25.340(1.003)    776924      21.20
                                                          011(8.
                                                        19
                                                        19
                                                       Hot Detected.
                                                       Hot Detected.
                                                        ""?.'"'•'11 .ft""*?
                                                                           TSK-
                                                                                              99.20
                                             MHr-23  \P
      15.212(0.926)
      15.838(0.964)
      IS E8BI1 810) 	
      ta.cT7 ri .ai3l
      143847
      51622
      	 1S99 	
      5.09
      2.22
      0.14
      	 l.tij 	
      	 V.2b
      5.09
      2.22
      	 1.37 —
                                                                                               2.49
                                                                                               8. £7
                                                 SPP
                                                                                              21.20
      

      -------
       Data Filet /chem/Y.i/10-23-97.b/YP790.d
       Date : 23-OCT-97 15:09
       Instrument :  Y.i
       Sample ID : SO-MM5-3-37
       Column phase  : DB-5
       Volume Injected (uL> : 1.0
      42 Naphthalene
                                                  Page 11
      Column diameter :  0.32
      Scan 1214 (12.807 min> of YP790.d
      2.0|
      1.8-j
      1.5-1
      
      £ * j
      loia-l
      "0.54
      0.2-i
      
      
      
      
      
      
      
      I J * . 1
      
      
      
      
      
      
      
      
      40 80 120 160 200 240 280 320 360 400 440
      Mass/Charee
      Scan 1214 (12.807 min) of YP790.d (Subtracted)
      2.0-1
      1.8-:
      1.5-!
      xxl.2-1
      Sl.O-i
      So.8-i
      ="0.54
      0.2-1
      0 0-
      
      
      
      
      
      
      
      
      , 1 J , . J
      
      
      
      
      
      
      
      
      
      40 80 120 160 200 240 280 320 360 400 440
      Mass/Charee
      
      :
      8.0-j
      
      6 0-
      s * :
      34.0-
      ._ :
      2.0-
      
      
      
      
      
      
      
      
      
      
      ..... 1
      42 Naphthalene (PBM Reference Spectrum)
      
      
      
      
      
      
      .
      
      
      40 80 120 160 200 240 280 320 360 400 440
      Mass/Charee
      Scan 1214 (12.807 min) of YP790.d (2 DIFFERENCE)
      100-
      75-i
      504
      
      25i
      l.2g]
      ~-5o4
      -754
      
      
      
      
      
      
      
      
      
      
      40 80 120 160 200 240 280 320 360 400 440
      Mass/Charee
      Mass 128.00
      2.0-3
      1.8-j
      •
      1.6-i
      1.4-i
      31.2-j
      ol.O-i
      ^O.B-j
      0.6H
      0.4^
      0.2-i
      0 0
      11
      a
      
      
      
      
      
      
      
      
      
      
      
      
      
      
      
      I
      Jli
      12.4 12.6 12.8 13.0 13.2
      Time (min.)
      Mass 129.00
      2.2-3
      2.0-j
      1.8-i
      1.6-
      1A —
      **f-
      s •
      3*1
      0.6-:
      
      0.4-i
      0.2-:
      
      (I
      i
      
      
      
      
      
      
      
      
      
      
      
      12.4 12.6 12.8 13.0 13.2
      Time (min.)
      Mass 127.00
      9 fl
      ^.o <
      2.5-i
      
      2.2-i
      2.0-
      _1.8-
      ?1.5-i
      o * :
      31'2'
      0.8^
      0.5-
      0.2-
      0 0-
      
      
      
      
      
      
      
      
      
      
      
      
      «_JV 1
      1
      
      
      
      
      
      
      
      
      
      
      
      J 	 ., ,
      12.4 12.6 12.8 13.0 13.2
      Time (min.)
      

      -------
       Data File: /chem/Y.i/10-23-97.b/YP790.d
       Date : 23-OCT-97 15:09
       Instrument : Y.i
       Sample ID : SO-MM5-3-37
       Column phase : DB-5
       Volume Injected 
        : 1.0 46 2-Methylnaphthalene Page 12 Column diameter : 0.32 1.8-j 1.5-j ^1.2-j «J) A A J |0[gj =-0.5-1 0.2-i 0.0-3 Scan 1414 (14.241 min) of YP790.d | i i i | . r i | i i i | .. ,...,.. . | , , , | 40 60 80 100 120 140 160 180 Mass/Charee Scan 1414 (14.241 min) of YP790.d (Subtracted) 1.8-j 1.5-j ^1.2-j |o.8- 0.2- 0.0- | i i i | I I •• •• | I — I i | i , ,...,. i i | i , i | 40 60 80 100 120 140 160 180 Mass/Charee 46 2-Methylnaphthalene (PBM Reference Spectrum) . 8.0^ xx 6.0- fO |4.0- ;_ 2.0- 0.0- . ll II 1 ll, II li, i.l . i I 1 ' ' ' 1 ' ' 1 ' ' ' 1 ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' I 40 60 80 100 120 140 160 180 Mass/Charge Scan 1414 (14.241 min) of YP790.d (Z DIFFERENCE) 100- 75- 50- 25- 5-25- **-50- -75- -100- 40 60 80 100 120 140 160 180 Mass/Charee Mass 142.00 1.8-i 1.6-j •1.4-1 1.2-. o - 3 0.8r ^0.6-; • 0.4-j 0.2^ 0.0- I i | • >> | i i i s 3 CM * 3 *-i i 1 1 II 1 1 •i .''Mi . -r r , , ^ p | i i 13.8 14.0 14.2 14.4 14.6 Time (min.) 16 I.*-: 1.2- 1.0- So.8- »-i X ^0.6- 0.4- 0.2- 0 0- Mass 141.00 Is V CM 3* I . 1. 13.8 14.0 14.2 14.4 14.6 Time (min.)

      -------
         Data File: /chero/Y.i/10-23-97.b/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase : DB-5
         Volume Injected 
        : 1.0 56 ftcenaphthylene Page 14 Column diameter : 0.32 6.0-; 5.0-i 1.0-1 0.0 Scan 1675 (16.119 min) of YP790.d I f% 40 JJA t^UjLi^ ^ 6.0-: 5.0-i ;2.o- i.o- 0.0 40 8.0: §4.0- *"2.0- 40 100-: 75 -I 50-j 251 £ H "-50^ -75H -100-^-r 40 •^ 60 80 100 120 140 160 180 200 Hass/Charee Scan 1675 (16.119 min) of YP790.d (Subtracted) iJll i 60 Illll. ...h. | IM ii ,iiii|> I 80 100 120 Mass/Charge 140 160 180 56 flcenaphthylene
        -------
           Data File: /chem/Y.i/10-23-97.b/YP790.d
           Date : 23-OCT-97 15:09
           Instrument : Y.i
           Sample ID : SO-MM5-3-37
           Column phase : DB-5
           Volume Injected 
        -------
         Data File: /chem/Y.i/10-23-97.b/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase :  DB-5
         Volume Injected (uL> : 1.0
        65 Fluorene
                                                    Page 16
        Column diameter :  0.32
        1.8-1
        1.5-j
        1.2-j
        XX •
        o * :
        XX -
        =-0.5-;
        0.24
        Scan 1871
        ilkiiMuladJyJilJ
        •> (17.568 min) of YP790
        liiLkLj
        .d
        , , L L
        40 80 120 160 200 240 280 320 360 400
        Mass/Charge
        1.6-i
        1.4-1
        1.2-j
        i0*8"
        3o.6-
        ^0.4-
        0.2-
        Scan 1876 (17.E
        IU.I.lll, ll. ,,,ll Jl.,lU J
        68 min) of YP790.d (Subtracted)
        LlL
        .11 i.
        40 80 120 160 200 240 280 320 360 400
        Mass/Charge
        8.0:
        -6.0:
        ?4.0-
        XX H
        >- -
        2.0-
        0 0—
        65 Fluor
        1 1 ll. ,, .
        ene (PBM Reference Spectrum)
        
        
        40 80 120 160 200 240 280 320 360 400
        Mass/Charee
        100-
        75-
        50-
        25-
        £ 0-
        «-25-
        **-50-
        -75-
        Scan 1876 (17.568 min) of YP790.d (2 DIFFERENCE)
        40 80 120 160 200 240 280 320 360 400
        Mass/Charge
        2.8-
        2.5-j
        2.2-j
        2.0-j
        1.8-j
        51.54
        ^1.0-j
        0.8-j
        0.54
        0.2-j
        Mass 166.00
        3
        in
        te
        i »•
        yj
        17.20 17.40 17.60 17.80 18.00
        Time (min.)
        3.6-;
        3.2^
        2.8-;
        2.4-j
        ?2.0-j
        O
        ^i.2-i
        0.87
        0.4:
        Mass 165.00
        I
        roiv. •»
        ""i ps? J
        \r^J^
        I— 
        t-t
        P
        r
        
        -------
         Data File: /chem/Y.i/10-23-97.b/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase :  DB-5
         Volume Injected 
          : 1.0 73 Phenanthrene Page 17 Column diameter : 0.32 Scan 2156 (19.588 min) of YP790.d 3.2-i 2.8-i 2.4-: ?2*°1 Ili-l *"0.8- 0.4-; O.O-3 1 1 1 Jl I 1 |j 111 HIM LiiiiLUk jJdi ll \ 1* kit I.L It. 11 ifilkLl.ii, la. ,. , 50 75 100 125 150 175 200 225 250 275 300 325 350 375 Mass/Charee Scan 2156 (19.588 min) of YP790.d (Subtracted) 3.2-3 2.8-i 2.4-! ~2.0-i Si.6-i •2 1.2-: ^O.S-i 0.4^ 0.0- ,,tiN(t,v,...., )........,....,....,.,...> rrr-r p r-r. , .... ( . . , , t , , , , ^ . , , , , , , . , ( , , , , ( 50 75 100 125 150 175 200 225 250 275 300 325 350 375 Mass/Charee 73 Phenanthrene (PBM Reference Spectrum) . 8.0: • KJ * J < ^x4.0-^ 5. ; 2.0- 0 0- 1 - . . , J J . II J 50 75 100 125 150 175 200 225 250 275 300 325 350 375 Mass/Charee Scan 2156 (19.588 min) of YP790.d (Z DIFFERENCE) 1003 75-j 50-j 2M £ 1 •<-• 1 ro * IT\ 1 ? - I o* h § l/U^wfi 19.20 19.40 19.60 19.80 20.00 Time (min.) Mass 179.00 6.0-; 5.0- 4.0- ro 33*°1 "2.0^ i.o-i 0.0- Is • rt— m c3 1 S' 1 II ^ I s* fl ll 1 1 .7* 1 II II 1 1 IA i )l IH In n 1 \ nil M 111 1 «1 ill 1 i ,, JL j| | 1 Iff 1 \wWlii i f n f i if iiifl i i n i i iiii * 19.20 19.40 19.60 19.80 20.00 Time (min.) Mass 176.00 7.0- 6.0-: 5.0^ ^4 Oj <° * • 0 7 fl ' ^ : 2 0- * 1.0-" —CO CO 1 Cft 1" 1 1 ^ 5 r^ S • 7 1 1 1 i 1 , I i ... it.J N.L ooW]WHfpJn" W.if, I,il I'll 19.20 19.40 19.60 19.80 20.00 Time (min.)

        -------
         Data File: /chem/Y.i/10-23-97.b/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase :  DB-5
         Volume Injected (uL)  : 1.0
        74 flnthracene
                                                       Page 18
        Column diameter :  0.32
        Scan 2172 (19.703 min) of YP790.d
        1.4-
        
        1.2-i
        1.0-
        ?0.8-
        30.6-
        ^0.4-
        0.2-
        0.0-3
        
        
        
        
        i
        
        
        
        Li
        
        
        
        
        
        
        1 1 .. 1 1 1
        1 i i 1 III hll it > 1, l,i, I ,i i I . „ .
        ll J 1, ill 11 111,1,1, llllllili L Ilillill 1,1 III lll,l,,il ii bnll 1 , 1 1,1 1 Ull hllil.li ,1 1 , 1 1
        
        
        
        
        Illlll III ill 1
        
        
        
        i 1
        
        40 60 80 100 120 140 160 180 200 220
        Mass/Charge
        Scan 2172 (19.703 min) of YP790.d (Subtracted)
        3
        6 0-
        (J* V ,
        5.0-i
        j
        ? * :
        3 0~
        x * •
        ^ 2 0-^
        *~i-°i
        0.0-3
        
        
        
        
        
        
        
        
        
        
        ii
        
        
        I 1 II I 1 ] 1 , 1 III
        I 111 ill 1 1 . ill III .1 . , 1 1 II
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        1
        1 1 1
        T • • • i • i • • i • • i • • • i • • i ... i ... i ... i
        40 60 80 100 120 140 160 180 200 220
        Mass/Charge
        74 Anthracene (PDM Reference Spectrum)
        
        
        8.0-J
        
        S6'°~
        I4-0:
        5. :
        2.0-
        0.0-
        
        
        
        
        
        
        
        
        
        
        
        
        |
        
        . ,
        . , .. J J . .. ,11 Jill
        i . i . | . . i ,..,,. i ,,...,. i , | • . i ,...,... |
        40 60 80 100 120 140 160 180 200 220
        Mass/Charge
        Scan 2172 (19.703 min) of YP790.d (Z DIFFERENCE)
        1UQ"
        75-i
        50-i
        25-=
        £ H
        ~-50i
        -754
        
        
        
        *
        i ii
        .. II. ,i L,, iii] .1 LI 1.1 i ,. .1 ..,n, i i. 1 n,i
        
        
        
        
        I 1
        
        
        
        40 60 80 100 120 140 160 180 200 220
        Mass/Chdrjfff
        Mass 178.00
        3.2-i
        
        2.8^
        -
        2.4-j
        ^2.0:
        r :
        SL6-
        x :
        XX
        >.1.2-i
        0.8-i
        
        0.4-
        0 0-
        
        
        
        
        
        
        
        
        
        
        
        
        
        w.w . . • ) ... | ... | ... | . . . ,
        19.40 19.60 19.80 20.00 20. 2(
        Time (min.)
        Mass 176.00
        7.0H
        *
        "
        6.0-i
        5.0^
        '.
        &*'°--
        ro
        ^ :
        33-^
        >-
        2.0-
        •:
        l.o-i
        Ort-
        1— §g
        1 10
        1 9^
        1 *"*
        1
        
        II
        3 i
        3 o
        1 ,
        1
        / K
        i / iHk J( h\\i
        HNW i nm¥[
        ^y-^— i — i — i — | — i — i — i — [ — i — i — i — | — i — i — i — | — i — i — i — j
        19.40 19.60 19.80 20.00 20.2(
        Time (min.)
        Mass 179.00
        6.0:
        
        5.0-
        
        4.0-j
        ? :
        3 3.0:
        XX
        "2.0-
        1.0-
        
        0 0-
        r§
        1^-HjO CNJ
        II ^* II
        II ^^ LI 1!
        s j 11
        11 il' 1 il
        llil A 1 1
        n "11
        iiA ffli/LJ 1 I Hf
        i Ii ill Y r
        Iii 'Ml i 1
        19.20 19.40 19.60 19.80 20.00.
        

        -------
           'Data File: /chemA.i/10-23-97.bAP790.d
           Date : 23-OCT-97 15:09
           Instrument : Y.i
           Sample ID : SO-MM5-3-37
           Column phase : DB-5
           Volume Injected (uL> : 1.0
        
          77 Fluoranthene
                                                                                                                   Page 11
                                                                     Colunn diameter :  0.32
                                Scan 2503  (22.085 min) of YP790.d
               40   60    80  100   120  140   160  180   200  220   240  260   280
              	Mass/Charge	
                          Scan 2503 (22.085 min) of YP790.d (Subtracted)
          2.4-1
        
          2.0-i
          0.0-
                        14
        ^4
                              uiii.,t  ,
                                    fO+
                                                                         -+-
        -+-
               40   60    80   100   120  140   160   180   200  220   240  260   280
                                          Mass/Charge	
                              77 Fluoranthene  (PBM  Reference Spectrum)
          8.0-
        g'.H
          2.0-
          0.0-
        
               40   60    80   100  120  140   160   180  200  220   240  260   280
              	Mass/Charge	
         100-
          75-i
          50^
          25^
        :   0-
        '-25-i
        '-50-
         -75-
                         Scan 2503  (22.085 min) of YP790.d (Z DIFFERENCE)
        -100 J-r
                 ..illli... ..kt.
                          h. ll.4.k i... A . i _ .u
                      .L -. I. .,-IH .. ;.«•>•
               40   60    80   100  120   140   160   180  200   220   240  260   280
                                          Mass/Charge
                                                                                                      Mass 202.00
                                                                                          0.0
                                                                                             21.6  21.8   22.0  22.2
                                                                                            	Time (min.)
                                                                                                        Mass 101.00
                                                                                               21.6   21.8  22.0   22.2   22.4
                                                                                              	Time  (min.)	
                                                                                                        Mass 100.00
                                                                                            0.0
                                                                                             21.6   21.8  22.0  22.2   22.4
                                                                                            	Time (nin.)	
        

        -------
         Da,ta File: /chem/Y.i/10-23-97.b/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase : DB-5
         Volume Injected (uL>  : 1.0
        78 Pyrene
                                                     Page 19
        Column diameter :  0.32
        Scan 2570 (22.568 min) of YP790.d
        
        3.2-
        2.8-
        
        2.44
        32.0-i
        £ 1.6-j
        -2l.2-
        *-0.8^
        0.4-
        1
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        11
        
        ,
        jiLjIL*.
        40 80 120
        
        2.8-i
        
        2.4-1
        ~2*°i
        |l.2-J
        ^0.8-1
        0.4-;
        o.o-i
        
        
        
        
        
        J
        Scan 2570
        
        
        
        
        ,.,
        
        
        
        ^iu^.
        
        40 80 120
        
        
        
        
        
        
        
        
        
        
        UL*J^
        
        
        
        
        
        
        ,
        160 200
        *
        
        
        
        
        
        
        
        
        1), ,. . tl . ... I. , ,
        240 280 320 360 400
        Mass/Charge
        (22.568 min) of YP790.d (Subtracted)
        
        
        
        
        lHi|Mi,i/. . :
        2.0:
        o.o:
        
        
        
        
        
        
        I
        - • M
        i i . . i . • . i i •
        40 80 120
        
        
        
        
        
        .
        
        
        ' l ' ' ' i
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        160 200 240 280 320 360 400
        Mass/Charge
        Scan 2570 (22.568 min)
        100 -g
        754
        504
        25-1
        £ \n
        —CO
        S
        CM
        e\i
        
        
        
        
        
        
        i
        I
        t.
        KMA **J \ *.
        i T i i i i r ' ' ' i • • ' i j ' ' i '
        22.20 22.40 22.60 22.80 23.00
        Time (min.)
        Mass 101.00
        8.0-
        7.0-
        6.0-i
        P55-°-
        n
        E
        3
        7
        i s
        
        k :n \\\
        O , A J| 1 i nil i
        S4'°I ,11 1
        >- 3.0-3 flj
        2.0-i /T'U
        
        1 \s\\\ \
        n
        
        iMj IN li nUI 1 A
        n mm w ^
        22.20 22.40 22.60 22.80 23.00
        Time (min.)
        Mass 100.00
        2.8-1
        2.5-i
        2.2-j
        2.0-i
        1.8-1
        ^v
        o * I
        
        0.8-i
        0.5^
        0.2-;
        0.0-^
        rs
        o <^
        1 CM
        1
        
        
        
        
        
        
        
        I <^
        s.
        a
        I
        fl
        
        J
        if\tf\{^r*M 1 VAIU,/, AJ*/I V«,'
        22.20 22.40 22.60 22.80 23.00
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-23-97.b/Cfifl/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase :  DB.5-625
         Volume Injected 
          : 1.0 21 Cumene Page 13 Column diameter : 0.32 Scan 641 (8.715 min) of YP790.d 2.4-1 2.0-j 1.6- l1^ -0.8-; 0.4-j 0.0: ^1 III, ll.ll i . .1 11 1 llmll ) • 1,1 !• I1 1,, . , 1 1,- 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charee Scan 641 (8.715 min) of YP790.d (Subtracted) 2.4-1 2.0- • 1.6-j -0.8-j *~ 0.4: 0.0^ .1 , III , i 1 i 1 l.n 4.,! III , 1 1 'l 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charee 21 Cumene (PBM Reference Spectrum) 8.0- xv 6.0- rf> §4.0-j >_ ; 2.0- • On- ,1 1,1 Hi. .. .1.1 ...in. i .1, . . . 40 50 60 70 80 90 100 110 U 1 JO 130 140 150 Mass/Charee Scan 641 (8.715 min) of 1001 75-j 504 25-j *j_ f\ ' = -254 "*-50-^ -754 100 = 1 i . i II . ..1,1, YP790.d (2 DIFFERENCE) 1 ti * 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charge Mass 105.00 2.4H 2.24 2.o4 1.8-i 1.6-j .^1.4- <01.2-. ^*1 0- ^o.s-i 0.6-; 0.4-i 0.0^ /uA JUAAA/ , 'iT'i | °l"V>i"'| 8.4 8.6 8.8 9".0 9.2 Time (min.) Mass 120.00 1.0-j 0.94 0.8-i 0.7-i f^. '. ro.e- o • -S 0.5- •*»x ! >-0.4H 0.34 0.2- O.l4 0 0- B K 00 1' A, 8.4 8.6 8.8 9.0 9.2 Time (min.) Mass 77.00 2.07) . 1.8-" 1.6- 1.4-- ^1.2-j gi.o-i *0.8r ^0.6: 0.4-; 0.2-i 0 0- 1 t 1 \ I \ s \ 1 1 ft 1 I VtV ... 1 ....... 1 ... 1 ... I 8.4 8.6 8.8 9.0 9.2 Time (min.)

        -------
         Data File: /chen/Y.i/10-23-97.b/CflA/YP790.d
         Date : 23-OCT-97 15:09
         Instrument :  Y.i
         Sample ID : SO-MM5-3-37
         Column phase :  DB.5-625
         Volume Injected (uL> : 1.0
        23 Phenol
                                                     Page 14
        Column diameter :  0.32
        Scan 748 (9.477 min) of YP790.d
        1.2-ij
        
        i.o-i
        ^0.8-j
        £0.6:
        3 :
        -0.4-
        >- ;
        0 2-
        V*fc _
        0.0-
        
        
        
        
        
        I
        
        
        
        1
        tUwJu
        
        
        
        
        
        
        
        
        |
        
        •
        
        
        
        
        
        
        
        
        n , ,1 r , I,
        , , | , , , , | ....,..,. | .,..,.... | . . ..,....,. . • • )
        50 75 100 125 150 175 200 225 250 275 300 325
        Mass/Charee
        Scan 748 (9.477 min) of YP790.d (Subtracted)
        1.2-d
        1.0-;
        
        ^0.8:
        So.6^
        T-I * ;
        X
        -0.4:
        0.2:
        0.0-
        
        
        
        
        
        i
        Liiij i ,
        
        
        
        
        
        
        I
        i
        
        
        
        
        
        
        ,J ,• , L
        , . f : , : : f , . , , f : . , , , ... . | . . ..,,,,,,,...,. . • • )
        50 75 100 125 150 175 200 225 250 275 300 325
        Mass/Charee
        23 Phenol (PBM Reference Spectrum)
        
        8.0:
        xx 6.0-
        ro
        <>
        34.0-
        NX
        
        2.o:
        
        
        
        
        
        
        
        
        , 1
        i J,,| J
        
        
        
        
        
        
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325
        Mass/Charee
        100-
        75-i
        so-;
        25-i
        £ 
        -------
         Data File: /chem/Y.i/10-23-97.b/CAfl/YP790.d
         Date : 23-OCT-97 15:09
         Instrument :  Y.i
         Sample ID : SO-MM5-3-37
         Column phase  :  DB.5-625
         Volume Injected 
        -------
         Data File: /chem/Y.i/10-23-97.b/Cftfl/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-HM5-3-37
         Column phase : DB.5-625
         Volume Injected (uL>  : 1.0
        28 Benzyl  Chloride
                                                    Page 17
        Column diameter :   0.32
        Scan 850
        1.6-3
        1.4--
        1.2-i
        xxl.OH
        ^0.8-i
        ^0.4-i
        0.2-;
        
        
        
        
        
        
        
        
        ..III, ,M. ,.,
        40 50
        
        
        
        
        
        
        
        
        
        60
        
        
        
        
        
        
        
        
        I'.M'll'
        70
        
        (10.204 min) of YP790.
        •
        
        
        
        
        
        
        
        
        
        80 90 100 110
        Mass/Charge
        d
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        120
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        1
        130 140 150
        
        
        
        
        
        
        
        
        
        
        
        
        Scan 850 (10.204 min) of YP790.d (Subtracted)
        1.6-a
        1.4-i
        1.2-
        1 0-
        go.8-
        *0.6-
        ="0.4-
        0.2-
        
        
        
        
        
        
        
        
        
        ..hi 	 1.
        
        
        
        
        
        
        
        
        .1 . ...i,
        40 50 60
        
        
        
        
        
        
        
        
        .. .,1
        70
        
        
        
        
        
        
        
        
        '/ .' V
        
        
        80 90 100 110
        Mass/Charee
        
        
        
        
        
        
        
        
        1
        
        
        
        
        
        
        
        
        
        
        120
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        130 140 150
        
        
        
        
        
        
        
        
        
        
        28 Benzyl Chloride (PBM Reference Spectrum)
        „
        8.0-
        j
        ~6.0-
        _x4.0-
        ._
        2.0-
        On—
        
        
        
        
        
        
        
        ,l . ..I
        
        
        
        
        
        
        
        J,
        40 50 60
        
        
        
        
        
        
        
        
        
        
        70
        
        
        
        
        
        
        
        
        I
        
        
        
        
        
        
        
        
        80 90 100 110
        Mass/Charee
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        ,
        120
        
        
        
        
        
        
        
        
        ,|
        
        
        
        
        
        
        
        
        130 140 150
        Scan 850 (10.204 min) of YP790.d 
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        40 50 60
        
        
        
        
        
        
        
        
        
        
        
        . . , ill
        70
        
        
        
        
        
        
        
        
        
        i 	
        
        
        
        
        80 90 100 110
        Mass/Charee
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        1
        
        
        
        
        120
        
        
        
        
        
        
        
        
        
        . . .
        
        
        
        
        130 140 150
        
        
        
        
        1
        
        
        
        
        
        
        
        Mass 91.00
        6.0-=
        5.5-i
        5.0-j
        4.5-i
        4.0-:
        53.0-=
        TH :
        ^2.5^
        *~2 0-
        1.5-1
        1 0-
        0 5-=
        0 0-
        i
        
        I
        2
        •
        
        •
        
        I
        * i I
        LA t\ A I A A
        	 J WLAJVVMAJI/V
        9.80 10.00 10.20 10.40' 10.60
        Time (min.)
        Mass 126.00
        7.0-
        
        6.0-
        
        5.0-
        ^4.0-
        O
        -3.0-
        2.0-
        
        1.0-
        
        I§
        $>
        
        
        
        
        
        
        
        
        |ilb f
        « 1 1 1 * i f 1 1
        9.80 10.00 10.20 10.40 10.60
        Time (min.)
        Mass 65.00
        
        .8-s
        2 5-
        
        2.2~-
        2.0-E
        1.8-6
        51'5!
        3^2-i
        *" ^•" :
        0.8-E
        0.5-=
        0.2^
        0 0-
        
        
        
        
        
        
        
        a
        o
        T-l
        1 1
        
        nil Jl
        AA, AA/I h &
        •Www r \P\ i V ^^itMifJ
        9.80 10.00 10.20 10.40 10.60
        Time (min.)
        

        -------
         Data File: /chen/Y.i/10-23-97.b/Cfifl/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase :  DB.5-625
         Volume Injected (uL)  : 1.0
        29 1,4-Dichlorobenzene
                                                       Page 18
        Column diameter :   0.32
        
        1.8-:
        1.54
        1.2-j
        p i.o-j
        XX I
        >.0.5-j
        fl O j
        0.0J
        
        
        
        
        
        
        ,\
        
        Scan 856 (10.247 min) of YP790.d
        
        
        
        
        
        
        1
        1
        *
        
        
        
        1
        Wl 11 i II i 1
        , ,,,1,, 1 1 111 Lnl.i , , lll.ll. , ,
        if II 1 1 f 1 1 M | 1 I | I I I I | I I I I | 1 1 .. | ..,.,...,,,.
        
        
        
        |
        
        
        
        
        
        
        
        
        i
        
        40 50 60 70 80 90 100 110 120 130 140 150
        
        
        1.0-|
        
        0.8-1
        
        Q0.6-
        o
        £0.4-
        >_
        0.2-
        
        
        
        
        
        
        
        
        
        
        
        
        
        Mass/Charee
        Scan 856 (10.247 win) of YP790.d (Subtracted)
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        |
        
        
        
        
        
        
        
        
        
        
        
        
        
        40 50 60 70 80 90 100 110 120 130 140 150
        
        
        8.0-j
        ~6 0^
        ? * -
        V<4.0:
        *** "
        >.
        2.0-
        0.0-
        
        
        
        
        
        
        
        |.
        1 '
        Mass/Charee
        29 1,4-Dichlorobenzene (PBM Reference Spectrum)
        
        
        
        
        
        .1
        .,, i i, ., l|l, ,. . 1
        
        
        
        
        
        
        
        
        |
        
        
        
        
        
        
        
        
        
        
        
        40 50 60 70 80 90 100 110 120 130 140 150
        
        
        100-
        75-=
        ™
        504
        ™
        25-:
        Jt 
        -------
         Data File: /chem/Y.i/10-23-97.b/Cflfl/YP790.d
         Date : 23-OCT-97 15:09
         Instrument :  Y.i
         Sample ID : SO-MM5-3-37
         Column phase  :  DB.5-625
         Volume Injected 
          : 1.0 31 2-Methylphenol Page 19 Column diameter : 0.32 Scan 914 (10.660 min) of YP790.d 1.4-^ 1.2-i i.o-i XX • ^0.8-: S0.6-: 0.2-i 0.0-3 1.4-1 1.2-i 1.0-i go.a- ?0.6- 0.2- 0.0- Jl 1 i II il ll |,,l III I.I III 1 llpi Mi II II 1 ii I 1 , III 40 50 60 70 80 90 100 110 120 130 Mass/Charee Scan 914 (10.660 min) of YP790.d (Subtract , ., ,|l ,. ,1 ; i. , ed) 1 , , III 40 50 60 70 80 90 100 110 120 130 Mass/Charee 8.0-i -.6.0- tf> *~2.0-i 0.0: 100- 754 50-^ 25i ~-504 -754 -100- 31 2-Methylphenol (PBM Reference Spectr • 'I'l'l' -I'l'i i •!• 'i . - urn) 40 50 60 70 80 90 100 110 120 130 Mass/Charee Scan 914 (10.660 nin) of YP790.d (Z DIFFERENCE) " •| ' ' i|ni" • '•• i| |ii" ' ' ' , ., in 40 50 60 70 80 90 100 110 120 130 Mass/Charee Mass 108.00 1.4- 1.2-i 1.0- ?0.8^ ~o.6-i 0.4: 0.2: o.o- K S o TH 1 Jj 1 VJJ VD * ^^. * S A A M ).20 10.40 10.60 10.80 11.00 Time (min.) Mass 77.00 5.0-! 4.5H 4.0r 3.5-i -3.0-i ^25- 1.5-j i.o-i 0.5-j 0.0J 1 r* I 2 1 H 5 § i fl if 111 Uli^Juw 5.20 10.40 10.60 10.80 11.00 Time (min.) 3.6-i 3.2: 2.8-i 2.4-i 5° 2.0: ^ 1.2-i 0.8^ 0.4- 0.0- 1 Mass 90.00 GO TH 1 11 lh \ 1(1 1 III 11 0.20 10.40 10.60 10.80 11.00 Time (min.)

        -------
         Data File:  /chem/Y.i/10-23-97.b/CAA/YP790.d
         Date : 23-XT-97 15:09
         Instrument  :  Y.i
         Sample ID : SO-MM5-3-37
         Column phase  : DB.5-625
         Volume Injected - * :
        0.2:
        0.0-
        
        
        
        
        
        
        J,l.
        
        40
        
        
        1.2:
        1.0:
        
        ^0.8-i
        £0.6:
        ^^
        x :
        >- * ;
        0.2:
        
        Oci-
        
        
        
        
        
        
        
        
        i
        il I,
        .U ' | '
        40
        
        
        .
        •
        8.0^
        ro6*0^
        ^x 4 0~
        XX
        >-
        2.0:
        rt rt-
        
        
        
        
        
        
        
        .il .,
        40
        
        
        100-a
        
        75-i
        50-j
        254
        «£ 0-
        e-254
        -754
        -1f>0-
        
        
        
        
        
        
        
        
        
        40
        
        
        
        
        
        
        
        .
        K,
        . . . |
        Scan 960 (10.989 min) of YP790.d
        
        
        
        
        
        
        1- ^i,!,.^!,! .,.(. .}.
        
        
        
        l... ... ..1. ... .
        
        
        
        
        
        
        
        
        50 60 70 80 90 100 110 120 130
        
        
        
        
        
        
        
        
        
        
        1
        
        Mass/Charee
        Scan 960 (10.989 min) of YP790.d (Subtracted)
        
        
        
        
        
        
        
        1
        
        i •- •• 	 	 i-
        
        
        
        
        i.. . ,.i 	 i
        
        
        
        
        
        
        
        
        i
        1.
        50 60 70 80 90 100 110 120 130
        
        
        
        
        
        
        
        
        
        
        5<
        
        
        
        
        
        
        
        l 	
        
        
        
        Mass/Charee
        33 ficetophenone (PBM Reference Spectrum)
        
        
        
        
        
        
        
        1 • I'i'v i i i1!1
        
        
        
        
        
        .
        
        
        
        
        
        
        
        (
        D 60 70 80 90 100 110 120 130
        Mass/Charee
        Scan 960 (10.989 rain) of YP790.d (% DIFFERENCE)
        
        
        
        -
        	 ., 	 	 li 	
        1
        
        
        
        
        
        50 60 70 80 90 100 110 120 130
        
        Mass/Charee
        
        
        
        
        
        
        
        
        
        140 150
        
        
        
        
        
        
        
        
        
        
        
        
        140 150
        
        
        
        
        
        
        
        
        
        
        140 150
        
        
        
        
        
        
        
        
        
        
        
        140 150
        
        Mass 105.00
        1.4-1
        1.2^
        1.0-i
        S0.8^
        <->
        S°-6~
        0 4-
        V»*T
        Oo
        .2-
        0 0-
        
        OO
        s* I
        S3
        jj
        S '
        ^ 1
        1 in ll II
        A rH [1 11
        I'
        WWu (f
        10.60 10.80 11.00 11.20 11.40
        Time (rain.)
        Mass 77.00
        1.0-j
        0.9-1
        0.8^
        
        0.7-i
        
        ^0.6-1
        £o.5-^
        -0.4-!
        s- :
        0.3^
        •
        0.1-1
        
        
        
        i
        *
        s
        ^~i
        & •
        0* (1 ^r
        3-w
        vo D 1 zT*.
        ON Jl I T^^H
        VO ,^
        S A '
        . Am
        —TO
        in
        CJ
        *
        
        |
        1
        I)
        
        
        
        1 1
        1 1
        j 1 1
        All
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        Mass 120.00
        3.6-:
        3.2^
        
        2.8-
        '.
        2.4-
        
        S * ~-
        ^1.6-
        XX
        >"1.2-
        0.8^
        0.4-i
        0 0-
        
        H »H
        
        g 3
        
        » y^ 1
        ^ 0% $^i
        k 5 4
        j [3
        
        
        
        
        
        
        ! Ml
        A Lv WL
        /« H y J K^I/ r it u/i y w ,
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        

        -------
         Data File: /chemA.i/10-23-97.b/CAfl/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase : DB.5-625
         Volume Injected (uL) : 1.0
        60 Biphenyl
                                                    Page 36
        Column diameter :  0.32
        
        8.0-i
        7.0-=
        6.0-1
        xx 5.0-=
        S4.0-J
        
        33.0-i
        ^2.0-1
        1.0-i
        0.0-3
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        i, k
        
        
        
        
        
        
        
        1 JllJll
        
        40 60
        
        
        
        
        
        
        
        
        
        
        
        iJiUi
        
        80
        
        Scan 1549 (15.212 min) of YP790.d
        
        
        
        
        
        
        
        
        
        
        
        j i. j. L .
        1^ 	 r'i "1 i i i | i i i | i i i | i r
        100 120 140 160 180 200 220 240
        Mass/Charee
        Scan 1549 (15.212 min) of YP790.d (Subtracted)
        8.0-3
        7.0-j
        6.0-j
        
        S3.0-J
        ^2.0-j
        i.o-i
        Oft-
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        1
        1,
        
        
        
        
        , id ,
        .V | i i | i •
        40 60
        
        
        
        8.0:
        
        xx 6.0-
        S
        34-°:
        .,_
        2.0-
        
        
        
        
        
        
        
        
        .
        
        
        
        
        
        
        
        
        
        1 1
        40 60
        
        
        
        
        
        
        
        
        1
        i i.li i
        80
        
        
        
        
        
        
        
        
        
        ,
        80
        
        
        
        
        
        
        
        
        I..I 1L.I. 1 III i . . 1
        
        
        
        
        
        
        
        1 i
        100 120 140 160 180 200 220 240
        Mass/Charee
        60 Biphenyl (PBM Reference Spectrum)
        
        
        
        
        
        
        
        
        |
        
        
        . . , , . .,1
        
        1
        100 120 140 160 180 200 220 240
        Mass/Charee
        Scan 1549 (15.212 min) of YP790.d (Z DIFFERENCE)
        lOOi
        -
        75-.
        504
        254
        
        S-25-j
        ~-5o4
        -754
        -100-
        
        
        
        
        
        .,.
        
        
        
        
        
        
        
        1
        
        1 	 ...Ill 	 ,„..
        
        
        
        
        40 60
        
        
        
        
        
        
        1
        i,r -
        
        
        
        
        80
        
        
        
        
        
        
        L. .»~... ._. ._..-.. ._~ ....J,.. i ...
        
        
        
        
        100 120 140 160 180 200 220 240
        Mass/Charee
        Mass 154
        8.0-i
        "
        7.0-i
        6.0-;
        :
        5.0--
        XX '
        ^4.0-i
        x :
        2.0-;
        
        1.0-i
        0.0-:
        |
        
        
        ,
        
        
        
        
        
        
        
        
        s\ . -J
        
        14.80 15.00 15.
        .00
        ra
        a
        1
        
        
        
        1
        
        
        
        
        
        
        
        
        
        
        
        ®
        So
        • *
        Itfp
        
        .
        -~ xVx -/
        "V'l t V
        »H^
        |l(ln /
        w
        ' 1 '
        
        20 15.40" 15.60
        Time (min.)
        Mass 152
        6.0-
        
        5.0-
        
        xx 4.0-
        s
        ^3.0-
        XX
        ^2.0-
        
        1 0-
        Jt « V
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        .00
        
        
        
        
        
        
        
        CM
        s.l
        -1 s
        
        
        
        
        
        «U i | i — rn — [— i — n —
        14.80 15.00 15.
        i i
        
        
        
        
        s
        f\
        1
        
        W
        
        
        
        
        
        r"r
        20 15.40 15.60
        Time (min.)
        Mass 155
        6.0-j
        5.5-!
        5.0-=
        4.5-i
        
        4.0-1
        
        S3.0-i
        ^*? $ ''
        ^ * 1
        1.54
        1.0-1
        0.54
        0.0-=
        
        
        
        
        
        
        
        
        
        .00
        
        
        
        
        
        
        
        
        
        CVJ
        
        
        
        . r~. . _ -A ^ffJa
        14.80 15.00 15
        a*
        t
        t
        I Jl J
        
        
        
        f~s
        la
        1 ^H
        1
        \
        1
        
        
        
        
        
        L
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        20 15.40 15.60
        Time (min.)
        

        -------
          IJata File:  /chem/Y.i/10-23-97.b/Cflfl/YP790.d
          Date :  23-OCT-97 15:09
          Instrument  :  Y.i
          Sainple  ID : SO-MM5-3-37
          Column  phase  : DB.5-625
          Volume  Injected • *°1
        i.o-i
        0.0-:
        
        
        
        
        1
        
        
        ill i, i y k k 11
        li M JJiuiLii U>l4ipviiP
        
        
        
        
        
        
        
        i
        lUi .,L . 1 . . 1 1 1 . • V ' '
        Pl ' I ' ' ' i * • ' F ' • ' i ' * ' i ' ' ' I ' ' ' i • ' ' i ' •
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        -,
        5.0-i
        :
        4*0~"
        |3.0-i
        £2.0-;
        >• •
        l.O-i
        0.0-
        Scan 163
        
        
        
        
        
        
        
        .
        .
        S (15.838 min) of YP790.d (Subtracted)
        
        
        
        
        
        
        1
        i H -;• • J i • f If" • V * • f
        r r ' ' i ' ' ' I h ' ' r ' ' ' I n r ' I ' ' ' I ' ' ' I ' ' ' I ' '
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        61 Dimethalphthalate (PBM Reference Spectrum)
        
        8 —
        .0-
        
        xx 6.0-
        ro * •
        I4-0:
        >_
        2.0-
        0 0-
        
        
        
        
        
        
        
        
        , , il 1 1 , il
        
        
        
        
        
        
        
        H
        i
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        Scan 1636 (15.838 min) of YP790.d (Z DIFFERENCE)
        100-
        75-j
        504
        25-=
        «- o-^
        3_25j
        ~_50j
        -75-:
        -100-
        
        
        1
        
        _ t ^ L ._ .. J L
        i |
        
        
        
        
        i
        	 • • I i* 	
        
        
        
        
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        Mass 163.00
        2.8-j
        
        2.5-|
        2.2-j
        ^1.8-j
        51-5"!
        ^< 1 2-
        ^i'.o-j
        0.8-j
        0.54
        
        ~.
        
        II "^
        
        
        
        
        
        
        
        
        
        
        
        
        CM
        O^
        .
        
        
        15.40 15.60 15.80 16.00 '16.20
        Time (min.)
        Mass 194.00
        1.1-
        1.0-j
        0.9-
        
        0.8-j
        0.7-
        XX :
        5° 0.6-
        o
        30.5-
        ^0.4-1
        0.3-
        
        0.2-!
        0.1-!
        
        iR
        P
        1
        nl i_^
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        15.40 15.60 15.
        I 1 S
        f II ^
        
        
        
        
        i
        
        
        J.
        30 16.00 16.20
        Time (min.)
        4.0-i
        3.6-i
        3ri '
        .2-
        2.8-i
        2 4j
        §2^
        'x :
        ^1.6-
        1.2-i
        0.8-i
        0.4-i
        o o-
        Mass 164.00
        1 l~SR
        GO
        n ^
        II '*""'
        
        A I
        
        
        
        
        
        
        
        S
        ft III llntn-
        
        1 fl
        III
        1
        II
        i Id i
        
        UN
        I
        . . ,i,
        1 \Mn ,
        Mil
        11 1
        111 1 1ll. . 1 VI 1 11
        15.40 15.60 15.80 16.00 16.20
        

        -------
         Hata File: /chem/Y.i/10-23-97.b/CfiA/YP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase : DB.5-625
         Volume Injected 
          : 1.0 65 Dibenzofuran Page 41 Column diameter : 0.32 3.5-j 3-°i 2.5-i 1 2.0-i S1-5"! s-l.O-j 0.5-j Scan 1776 (16.846 min) of YP790.d Jill, lllllJil I.I i.illlllinlliililJ, l.n. i,ill,,.l,,.i,l,in.,, ,,ll,l,l i.,, ill. ,I,J|I UmlllJ i 40 60 80 100 120 140 160 180 200 Mass/Charee 3.5-j 3.0-j 2.5-j 32.0-j Sig-: x -1*3 • ^•^ z ^i.o-j 0.5-; Scan 1776 (16.846 win) of YP790.d (Subt .1 i . J. ihl.. iin . ,i ill . ,. llil , , li . ill -acted! i ..i 40 60 80 100 120 140 160 180 200 Mass/Charge 8.0: ~6.0- ro ^4.0- *w* >- 2.0- 0 0 65 Dibenzofuran (PBM Reference Spectrum) i - • ii- ii I. .'•« ii. .ill- 40 60 80 100 120 140 160 180 200 Mass/Charee 100- 75-j 504 25-^ 5£ 0-j 3 -25-! ~-5o4 -75-! Scan 1776 (16.846 min) of YP790.d (Z DIP FERENCI . I) , 40 60 80 100 120 140 160 180 200 Mass/Charee 4.4- 4.0-i 3.6-i 3.2-i 2.8-i 52.4-1 S2.0^ :i.^ 1.2-; 0.8-^ 0.4-: Mass 168.00 1 \o iH — -JJ •«• CO . VO in ^ If) . \o ^-4 1 I O 1 m & n ID • 55 R 3* • ^.fc "*' A -^* i4 fl , S vL^ifV ^v/WAA ,0-t i i i | i • i | i i • | i i i | i i 16.40 16.60 16.80 17.00 "17.20 Time (min.) 1.6-! 1.4-i 1.2: 1.0- *"» l°-8i ^0.67 0.4^ 0.2: 0 0- Mass 139.00 — *s> 3 * S. S oo ^ 2 5 *2 vo **" 1 1 i P^ JJ •tH ,_^ * 1 1 ' ' j ^Tl r\^°/i h Ji 16.40 16.60 16.80 17.00 17.20 Time (min.)

        -------
         Data File: /chem/Y.i/10-23-97.b/CtWYP790.d
         Date : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase : DB.5-625
         Volume Injected (uL)  : 1.0
        66 Di-n-butylphthalate
                                                    Page 42
        Column diameter :  0.32
        Scan 2320 (20.769 min) of YP790.d
        2.0-f
        1.8-^
        
        1.5-1
        £1.2-1
        Sl.O-j
        ~0.84
        "•0.5-j
        0.24
        0 0-^
        
        
        
        
        
        
        
        
        ,ll .,,.,...1 ... l
        40 60 80 100 120 140
        
        
        
        
        
        
        
        
        
        160 180 200 220 240 260 280 300
        Mass/Charee
        Scan 2320 (20.769 min) of YP790.d (Subtracted)
        2.0-1
        1.8-1
        1 5-=
        XX 1*2^
        ol.O-=
        ^0.8-!
        ^0.5-=
        0.2-i
        0 0-^
        
        
        
        
        
        
        
        
        .1 ... I . l
        40 60 80 100 120 140
        
        
        
        
        
        
        
        
        
        160 180 200 220 240 260 280 300
        Mass/Charee
        
        
        8.0-J
        
        xx 6.0-
        ro
        <
        §4.0-
        5_
        2.0-;
        
        66 Di-n-butylphtha
        
        
        
        
        
        
        
        
        
        ,1 . Jl i i. , I, i. ..
        40 60 80 100 120 140
        late (PBM Reference Spectrum)
        
        
        
        
        
        
        
        
        
        | i
        160 180 200 220 240 260 280 300
        Mass/Charee
        Scan 2320 (20.769 nin) of YP790.d (2 DIFFERENCE)
        100 -:
        75 -j
        504
        25-j
        fc 
        -------
         Data File: /chem/Y.i/10-23-97.b/CfiA/YP790.d
         "We : 23-OCT-97 15:09
         Instrument : Y.i
         Sample ID : SO-MM5-3-37
         Column phase : DB.5-625
         Volume Injected 
          : 1.0 83 bis(2-Ethu.lhexyl)phthalate Page 51 Column diameter : 0.32 Scan 2955 (25.340 rain) of YP790.d j 2.8-i 2*4~ 2.0-: S1'6! 31.2-! x** „ 0.4-i II J 1 .11 J .in .. I t. . . L . i. 40 80 120 160 200 240 280 320 360 400 Mass/Charee Scan 2955 (25.340 min) of YP790.d (Subtracted) 20- .0 . 2 4- ^»~ i 2.0- gl.6- ^1.2- XX >-0.8- 0.4- Ofi- 1, 1 . H l.l.i 40 80 120 I 160 200 240 280 320 360 400 Mass/Charee 8.0-J ~6.0- ro |> 34.0- >- 2.0- 0.0- 83 bis(2-Eth« 1 I I..1 ,1 , . T , . , 1 f 1 1 jlhexyDphthalate (PBM Reference Spectrum) - i • ' • i • • • i | ... | ... | ... 40 80 120 160 200 240 280 320 360 400 Mass/Charee Scan 2955 (25.340 min) of YP790.d (Z DIFFERENCE) 100 -: 75 -i 50-i 25-i s-25-= >x : -50-= -754 -100- - 'T"1~T 40 80 120 160 200 240 280 320 360 400 Mass/Charee Mass 149.00 3.0-d 2.8-= 2.5-j 2.2-j 2.0-j s1*8! Ili-j >-i.o-= 0.8-j 0.5-i 0.2-= . T^-~- 25.00 25.20 25.40 25.60 25.30 Time (min.) Mass 167.00 7.0-i 6.0- 5.0- ^4.0-: •rH : X -3.0- 2.0- 1.0- 0.0- n* Is / I -P* VV • <" •"V ^-ft- f-r* -*«•«— A~ n i TT i i | i i i | i r1 r f1' ' ' 1 25.00 25.20 25.40 25.60 25.80 Time (min.)

        -------
        1 ,***'.*** , V •"
        - - < ;- ^ ~r ^ ;, ^~p
        s4» <,, *'- «$• t- &•
        Project Number 43433
        Sample File: YP791
        
        
        V*»X^*^^ %i**\ s ^ ^v.-^
        
        
        Dilution Factor:
        •,
        * ? •.- •, '
        
        tit|M^
        1.00
        ^•^^•5Sa4ii*:Ci
        Method 8270A MM5
        Sample ID: SO-MM5-4r51
        
        
        
        *•*»..' •'•'Vpjvj^yg
        Naphthalene-d
        Naphthalene
        2-Methylnaphthalene
        Acenaphthene-d
        2-Chloronaphthalene
        Acenaphthylene
        Acenaphthene
        Fluorene
        Phenanthrenc-d
        10
        Phenanthrene
        Anthracene
        Fluoranthene
        Chrysene-d
        Pyrene
        Benzo(a)anthracene
        Chrysene
        Perylene-d ^
        Benzo(b)fluoranthene
        Benzo(k)fluoranthene
        Benzo(e)pyrene
        Benzo(a)pyrene
        Perylene
        Indeno(l ,2,3-cd)pyrene
        Dibenz(a,h)anthracene
        Benzo(g,h,i)perylene
        ^MJ^S
        IS 2
        45.94 B
        58.46
        IS 3
        U
        1.10 ]
        0.62 ]
        0.77 ]
        IS 4
        1.17 ]
        0.28 ]
        0.91 ]
        IS 5
        0.98 ]
        U
        U
        IS 6 High
        U
        U
        U
        U
        U
        U
        U
        U
        •? <: •/ ![ \
        12.76
        12.81
        14.24
        16.42
        16.13
        16.49
        17.57
        19.54
        19.59
        19.70
        22.10
        25.28
        22.58
        
        
        29.40
        
        
        
        
        
        
        
        " " "JEto&IjaiJilA r 'i^^vVQtt^tti.IJiBit i
        % *'% -.*l:8t ^ *% v * * ^^ % \ ^ &8S -^c ''•
        10
        10
        0.40 10
        10
        10
        10
        10
        10
        10
        10
        0.19 10
        0.19 10
        0.16 10
        0.17 10
        0.15 10
        0.17 10
        0.16 10
        0.15 10
        0.20 10
        0.16 10
                                     NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Savar v3.5
        

        -------
        L
         Project Number: 43433
         Sample File: YP791
                                                          Method 8270A MM5
                                                    Sample ID: SO-MM5-4-51
                                   > MI
        I Dilution Factor.
        1.00
        h.s v< *sY-^ -.*, >%»"i.v\
        •> ^ \v ;- ..^ "
        ?hcnol-d
        5
        Nitrobenzene-d
        5
        1 ,3, 5-Trichlorobenzene-d
        3
        1 ,4-Dibromobenzene-d
        4
        2-Fluorobiphenyl
        2,4,6-Tribromophenol
        Anthracene-d
        10
        Pyrene-d
        Terphenyl-d
        H3^§ ^x^«^^f>^f
        >\ i0/,^ , ? f^. ^^yst^rk »s^ ,
        \ w. > \ \ -^. Xs •- «. %<• ^^ •:•. BPEPB .-. -xxx ^^ . > •> \ < s\
        ft. X- jp 5 ^ *• ^-- f V A^I-T «\*W^f ^ ^"- '.f-. ^^*\ s -.1 ^X v %
        74.76
        
        63.35
        
        57.85
        
        70.52
        
        80.59
        118.77
        90.99
        
        78.62
        86.10
        ll*^
        •^ ^. \% i"--- %
        ^ ^-- ;ix>
        9.45
        
        11.29
        
        11.98
        
        12.87
        
        15.01
        18.07
        19.66
        
        22.54
        22.90
        ^ivsjj*-^
        -. y- 's x s%>> . . •*>.•• ' •• •• ^^
        "\<- -*',«":?: - ^ Y-
        ^^% vw«% •.-'•.V.V s^.\
        1
        
        2
        
        2
        
        1
        
        3
        3
        4
        
        5
        5
        ^¥x?o^iKig,^i
        ..-. * -.x^ ^ «4 %55 v- ^ •• ^ •
        -\ o-: ^--rr*- x ," - =
        ^ % s.jX^-.issS.j. •. : ; -, \ ; \\ :
        75
        
        63
        
        58
        
        71
        
        81
        119
        91
        
        79
        86
         Reviewed by.
        Date  l\_/ '3 /T7
                                  NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
         Triangle Laboratories of RTF, Inc
         801 Capitola Drive • Durham, North Carolina 27713
         Phone: (919) 544-5729 • Fax (919) 544-5491
                                                                          Savar v3.5
        

        -------
        * % % ^
        - ~ -* - ,'„ , Y*, *'.;,';
        Project Number 43433
        Sample File: YP791
        aientPrOje<±Saginaw;MI :
        **JI Jliu*t XoJy'f ^viA.***?- "" "• ^ s^^"
        - -*^V^t^J -'%£F * V\'^x'vo-V^l
        - ^F^ci^J^^ioi»m^t-al^|vi:c«s t x ^ ?«
        %s f f •. H-^
        ^If^^l^K", -^ :v --
        Method 8270A MM5
        Sample ID: SO-MM5-4r51
        ^ ^ v^KSSK'^H
        :|t'v^;
        3P;';
        Dilution Factor 1.00
        
        toa!yt*' "' '^fe&s*^
        1 ,4-Dichlorobenzene-d
        n-N i trosodimethylamine
        Cumene
        Phenol
        Aniline
        bis-(2-Chloroethyl)ether
        Benzyl Chloride
        1 ,4-Dichlorobenzene
        2-Mediylphenol
        Acecophenone
        n-Nitrosomorpholine
        o-Toluidine
        Hexachloroethane
        1 ,2-Dibromo-3-chloropropane
        N,N-Diethylaniline
        Naphthalene-d
        8
        3/4-Methylphenol
        Nitrobenzene
        N,N-Dimethylaniline
        Isophorone
        o-Anisidine
        1 ,4-Phenylenediamine
        1 ,2,4-Trichlorobenzene
        Hexachlorobutadiene
        a,a,a-Trichlorotoluene
        Hydroquinone
        IS 1 10.22
        U
        0.45 J 8.71
        19.44 9.48
        U
        U
        U
        1.30 J 10.25
        0.70 J 10.67
        8.68 BJ 10.99
        U
        U
        U
        U
        U
        IS 2 12.76
        0.99 J 10.97
        U
        U
        U
        U
        U
        1.29 J 12.64
        U
        U
        U
        1.39
        
        
        0.46
        0.99
        0.36
        
        
        
        1.34
        0.49
        1.27
        1.32
        0.48
        
        0.49
        0.47
        0.41
        0.86
        0.68
        
        1.27
        0.60
        0.72
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit: Quantitation Limit
        IS: Internal Standard; U: Undetected; B:
        Present In Blank; ): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc.
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                      SavarvS.5
        

        -------
         Project Number: 43433
        Sample File: YP791
              Method 8270A MM5
        Sample ID: SO-MM5-4r51
                                                                    ^gfe^;^l)^^
        1
        
        riyfe ,', f.fe^?1
        J-Chloroacetophenone
        Acenaphthene-d
        rlexachlorocyclopentadiene
        -2,4,6-Trichlorophenol
        2,4,5-TrichIorophenol
        Jiphenyl
        Oimethylphthalate
        2,4-Dinicrophenol
        i-Nitrophenol
        2,4-Dinitrocoluene
        Dibenzofuran
        4,6-Dinitro-2-methylphenol
        Trifluralin
        Phenanthrene-d
        10
        Di-n-butylphthalace
        Hexachlorobenzene
        i-Aminobiphenyl
        Pentachlorophenol
        Pentachloronitrobenzene
        4-Nitrobiphenyl
        Chrysene-d
        Benzidine
        4,4'-Methylenedianiline
        Dimediylaminoazo benzene
        3,3'-Dimethylbenzidine
        3,3'-Dimethoxybenzidine
        Dilution Factor. 1.00
        
        *^^^f^'^'V3
        U
        IS 3 16.42
        U
        U
        U
        2.50 } 15.22
        1.43 ] 15-84
        U
        U
        U
        1.25 ] 16.85
        U
        U
        IS 4 19.54
        
        5.85 BJ 20.78
        U
        U
        U
        U
        U
        IS 5 25.28
        U
        U
        U
        U
        U
        
        
        "Suff
        0.33
        
        1.40
        1.20
        1.12
        
        
        3.48
        1.59
        1.31
        
        2.60
        1.94
        
        
        
        0.84
        0.35
        1.49
        3.26
        0.90
        
        0.26
        0.63
        0.56
        0.32
        0.64
        
        
        
        10
        
        10
        10
        10
        10
        10
        25
        25
        10
        10
        25
        10
        
        
        10
        10
        10
        25
        10
        10
        
        10
        10
        10
        10
        10
                                  NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated* Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                               Savar v3.5
        

        -------
             *
              5~ -*\\\, •»">,.  s   s C
              1  - ^ ?%       v vS\
        Project Number 43433
        Sample File: YP791
                                                          Method 8270A MM5
                                                    Sample ID: SO-MM5-4r51
                                                     Dilution Facton    1.00
        Amlyte
        3,3'-Dichlorobenzidine
        Methylene bis-chloroaniline
        bis(2-Ethylhexyl)phthalate
        9.14
                      U
                      U
                      BJ
                                              0.47
                                              1.09
        25.34
        10
        10
        10
        Reviewed by.
        Date U  /
                                  NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
            IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc.
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax; (919) 544-5491
                                                                          Savar v3.5
                                                              Printed-12:43 11/13/1997
        

        -------
        Data.filet /chem/Y.i/10-23-97.b/YP791.d
        Date •: 23-OCT-97 16:00
        Instrument : Y.i
        Sample ID : SO-HM5-4-51
        Column phase :  D6-5
        Volume Injected (uL)  : 1.0
        Triangle Laboratories
             of RTF, Inc.
          Column diameter :  0.32
                                                                       Page 9
                                                              /chem/Y.i/10-23-97.b/YP791.d   (Part 1 of 2)
                                                                                                                                                                   • p
                                                                                                                                                                     A  ^f
        
                                                                                                                                                                     3 0)
                                                                                                                                                                       Q
        10
        11        12
          Time (min.)
        13
        14
        15
        16
        17
                                                                  18
        

        -------
        Data, filet  /chem/Y.i/10-23-97.b/YP791.d
        Date •: 23-OCT-97 16:00
        Instrument  : Y.i
        Sample ID : SO-MM5-4-51
        Column phase : DB-5
        Volume Injected 
        -------
        Data File:  /chem/Y.i/10-23-97.b/YP791.d
        Report Date:  24-Oct-1997  06:58
                                                                         Page 1
        Data file
        Lab. Id.
        Inj  Date
        Operator
        Smp Info
        Misc Info
        Comment
        Method
        Meth Date
        Cal Date
        Als bottle
        Dil Factor
        Integrator
                        TRIANGLE LABORATORIES,  INC.
                     SEMI-VOLATILE QUANTITATION REPORT
        /chem/Y.i/10-23-97.b/YP791.d
        43433
        23-OCT-97  16:00                 Autotune Date:  22-Oct-97
        DD                                Inst ID:  Y.i
        SO-MM5-4-51
        185-7-5A-E
                                      09:14:0
        /chem/Y.i/10-23-97.b/cclist.m
        24-Oct-1997 06:51  target
        23-OCT-1997 09:12
        7
        1.000
        HP  RTE
        Sample  Type:  AIR
        Cal  File:  YP783.d
        Target Version:  Target  2.20
        Compound Sublist: pah.sub
                                                                CONCENTRATIONS
          Compound*
        
        *  1 l,4-Dichlorobenzene-d4
        •  2 Naphthalene-dS
        *  3 Acenaphthene-dlO
        *  4 Phenanthrene-dlO
        *  5 Chry«ene-dl2
        *  6 Perylene-dl2
        $  7 2-Fluorophenol
        $  8 Phenol-d5
        $  9 2-Chlorophenol-d4
        $ 10 l,2-Dichlorobenzene-d4
        $ 11 Nitrobenzene-dS
        $ 12 l,3,5-Trichlorobenzene-d3
        $ 13 l,4-Dibromobenz«ne-d4
        $ 14 2-?luorobiphenyl
        $ 15 2,4,6-Tribromoph.no!
        $ 16 Anthracene-dIO
        $ 17 Pyrene-dlO
        $ 18 Terphenyl-dl4
          42 Naphthalene
          46 2-Methylnaphthalene
          SO 2-Chloronaphthalene
          56 Acenaphthylene
          58 Acenaphthene
          65 Fluorene
          73 Phenanthrene
          74 Anthracene
          77 Fluoranthene
          78 Pyrene
          83 Benzo(a)anthracene
          84 Chrysene
          86 Benzo(b)fluoranthene
        QUANT SIO
        MASS
        152.00
        136.00
        164.00
        188.00
        240.00
        264.00
        112.00
        99.00
        Compound
        Compound
        82.00
        185.00
        239.80
        172.00
        329.80
        188.00
        212.00
        244.00
        128.00
        142.00
        ic? fin
        iDei • UU
        152.00
        154.00
        166.00
        178.00
        178.00
        Compound
        202.00
        228 .00
        228. 00
        252.00
        ON-COLOHN
        RT (RKL RT>
        10.217(1.000)
        12.762(1.000)
        16.420(1.000)
        19.543(1.000)
        25.276(1.000)
        29.405(1.000)
        7.316(0.716)
        9.455(0.925)
        Hot Detected.
        Not Detected.
        11.295(0.885)
        11.982(0.939)
        12.870(1.260)
        15.009(0.914)
        18.072(1.101)
        19.659(1.006)
        22.535(0.892)
        22.903(0.906)
        12.813(1.004)
        14.240(1.116)
        16.132(0.982)
        16.492(1.004)
        17.574(1.070)
        19.594(1.003)
        19.702(1.00.8)
        t»rt?"j?L!.2.<3.&
        22.579(0.893)
        
        AA *p M f M IT* \
        RESPONSE
        494079
        1584565
        926997
        1555065
        1960428
        2515943
        32064
        1552200
        
        
        946163
        760854
        810046
        2319718
        820242
        3795484
        4531145
        3447432
        1841526
        1535484
        45451
        14989
        20802
        46422
        10564
        4~7t>T\
        63327
        
        -S*T-»
        ( ng)
        40.00
        40.00
        40.00
        40.00
        40.00
        40.00
        2.20
        74.76
        
        
        63.37
        57.76
        70.52
        80.56
        118.57
        90.97
        78.64
        86.05
        45.92
        58.44
        1.10
        0.62
        0.77
        1.17
        0.28
        
        0.98
        
        0.01
        FINAL
        ( ug)
        
        
        
        
        
        
        2.20UQR)
        74.76
        
        
        63.37
        57.76
        70.52
        80.56
        118.57
        90.97
        78.64
        86.05
        45.92
        58.44
        u. it t«u)
        0.62U)
        0.77(a)
        1.17 (a)
        0.28UQ)
        
        0.98UQ)
        
        o.oi r»oi
                                                          Data Review
                                                          Date:  ,,)i
        

        -------
        Data File: /chem/Y.i/10-23-97.b/YP791.d
        Report Date:  24-Oct-1997  06:58
                                                            Page 2
          Compound*
                                   QUANT SIQ
                                     MASS
                                                RT (RE. RT)
                                    CONCENTRATIONS
                                   OH-COLUMN    FINAL
                             RBSPONSB   (  ng)   (  ug)
          87 Benzo (k) fluoranthene
          88 Benzo(e)pyrene
          89 Benzola)pyrene
          90 Perylene
          91 Indeno(l,2,3-ad)pyrene
          92 Dili«nz(»,h) «nthr»o«n»
          93 B»nzo(g,h,i)p«ryl«n«
        
        QC  Flag  Legend
        252.00
        252.00
        252.00
        252.00
        276.00
                 32.S42
          Compound Hot Detected
          Compound Not Detected
        a  -  Target compound detected but,  guantitated amount
             Below Limit Of Quantitation(BLOQ).
        Q  -  Qualifier signal failed  the ratio  test.
        R  -  Spike/Surrogate failed recovery limits.
        

        -------
        Data File:  /chem/Y.i/10-23-97.b/CAA/YP791.d
        Report Date: 24-Oct-1997  07:09
                                                                         Page 1
                                       TRIANGLE  LABORATORIES, INC.
        Data file
        Lab. Id.
        Inj  Date
        Operator
        Snip  Info
        Misc Info
        Comment
        Method
        Meth Date
        Cal  Date
        Als  bottle
        Dil  Factor
        Integrator
                                                                     REPORT
                     SEMI-VOLATILE  QUANTITATION
        /chem/Y.i/10-23-97.b/CAA/YP791.d
        43433
        23-OCT-97  16:00                Autotune Date:
        DD                                Inst  ID: Y.i
        SO-MM5-4-51
        185-7-5A-E
                                                22-Oct-97 09:14:0
        /chem/Y.i/10-23-97.b/tlicaa.m
        23-Oct-1997 10:51
        23-OCT-97
        7
        1.000
        HP  RTE
        09:56
        Sample  Type:  mm5
        Cal  File:  YP784.d
        Target Version:  Target   2.20
        Compound  Sublist: CAAl.sub
                                                                CONCENTRATIONS
          Compound*
        
        •  1 It4 Dichlorobenzene-d4
        *  2 Haphth«lene-d8
        *  3 Acenaphthene-dlO
        *  4 Fhenanthrene-dlO
        *  5 Chry*ene-dl2
        •  £ Perylene-dl2
        $  7 2-Fluorophenol
        $  8 Phenol-45
        $  9 2-Chlorophenol-d4
        $ 10 l,2-Dichlorobenzene-d4
        $ 11 Hitrobenzene-dS
        $ 12 l,3,5-Trichlorobenzene-d3
        $ 13 l,4-Dibroiuobenzene-d4
        $ 14 2-Pluorobiphenyl
        $ IS 2,4,6-Tribromophenol
        $ 16 Anthracene-dIO
        $ 17 Pyrene-dlO
        $ 18 Terphenyl-dl4
          20 n-Hitroiodimethylamine
          21 Cumene
          23 Phenol
          24 Aniline
          27 bis-(2-Chloroethyl)ether
          28 Benzyl chloride
          29 1,4-Dichlorobenzene
          31 2-Methylphenol
          32 3/4-Methylphenol
          33 Acetophenone
          34 n-HitroBomorpholine
          35 o-Toluidine
          36 Hexachloroethane
        QUANT SIO
        MASS
        152.00
        136.00
        164
        188
        240
        264
        112
        99
        .00
        .00
        .00
        .00
        .00
        .00
        Compound
        Compound
        82
        185
        240
        172
        329
        188
        212
        244
        105
        94
        
        91
        146
        108
        108
        105
        5C
        
        
        .00
        .00
        .00
        .00
        .80
        .00
        .00
        .00
        . 00
        .00
        .00
        Compound
        Compound
        . 00
        .00
        .00
        .00
        .00
        . 00
        .00
        Compound
        10
        12
        16
        19
        25
        29
        7
        9
        Hot
        Hot
        11
        11
        12
        15
        18
        19
        22
        22
        8
        9
        Hot
        Hot
        10
        10
        10
        10
        
        Hot
        RT (RBL RT)
        .217(1.000)
        .762(1.000)
        .420(1
        .543(1
        .276(1
        .405(1
        .316(0
        .455(0
        .000)
        .000)
        .000)
        .000)
        .716)
        .925)
        ON-COLUMH
        RESPONSE ( ng)
        494079 40.00
        1584565 40.00
        926997
        1555065
        1960428
        2515943
        32064
        1552200
        40
        40
        40
        40
        2
        84
        .00
        .00
        .00
        .00
        .36
        .81
        FINAL
        ( ug)
        
        
        
        
        2
        84
        
        
        
        
        .36
        .81
        Detected.
        Detected.
        .295(0
        .982(0
        .870(1
        .009(0
        .072(1
        .659(1
        .535(0
        .903(0
        .715(0
        .476(0
        .885)
        .939)
        .260)
        .914)
        .101)
        .006)
        .892)
        .906)
        .853)
        .927)
        946163
        760854
        810046
        2319718
        820242
        3795484
        4531145
        3447432
        12845
        314379
        59
        51
        69
        85
        133
        91
        74
        87
        0
        19
        .47
        .49
        .78
        .29
        .15
        .76
        .01
        .30
        .45
        .44
        59
        51
        69
        85
        133
        91
        74
        87
        0
        19
        .47
        .49
        .78
        .29
        .15
        .76
        .01
        .30
        .45
        .44
        Detected.
        Detected.
        .253(1
        .667(1
        .966(0
        .988(1
        
        .004)
        .044)
        .859)
        .075)
        
        
        21408
        8765
        13944
        158759
        
        
        1
        0
        0
        8
        
        
        .29
        .69
        .98
        .68
        
        
        1
        0
        0
        8
        
        
        .29
        .69
        .98
        .68
        
        Detected.
                                                             Data Review:
                                                             Date:
        

        -------
        Data  File:  /chem/Y.i/10-23-97.b/CAA/YP791.d
        Report  Date:  24-Oct-1997  07:09
                     Page 2
                                                                                CONCENTRATIONS
           Compound*
        
           37  Nitrob.nz.n.
           38  N,N-Dim.thylanilin.
           39  l,2-Dibromo-3-chloropropan*
           40  Isophoron*
           41  o-Ani«idin.
           42  1,4-Ph.nyl.n.diamin.
           43  1,2,4-Trichlorob.nz.n.
           44  N»phth»l.n.
           46  H.xachlorobutadi.n.
           47  N,N-Di.thylanilin.
           48  »,»,a-Trichlorotolu.n.
           49  Hydroquinon.
           51  2-Chloroac.toph.non.
           52  H«xachlorocyclop.ntadi.n«
           53  2,4,6-Trichloroph.no!
           54  2,4,5-Trichloroph.no!
           SO  Biph.nyl
           61  Dim.thylphth.alat.
           62  2,4-Dinitroph.nol
           63  4-Hitroph.nol
           £4  2,4-Dinitrotolu.n.
           65  Dib.nzofuran
           66  Di-n-butylphthalat.
           £7  4,6-Dinitro-2-m.thylph.nol
           68  Trifluralin
           69  H«xaehlorob.nz.n.
           70  4-Aminobiph.nyl
           71  Pvntachloroph.no!
           72  P.ntachloronitrob.nz.n.
           73  4-Nitrobiph.nyl
           74  B«nzidin»
           75  4,4*-M«thyl«n«dianilin«
           77  Dim*thylaminoazob*nz*n*
           78  3,3'-Dim«thylb«nzidin«
           80  3,3'-Dim*thoxyb«nzidin«
           81  3,3'-Dichlorob.nzidin.
           82  M«thyl«n« bi»-chloro«nilin»
           83  bi«(2-Sthylh«xyl)phthal»t»
        QUANT SIO
        MASS
        77.00
        Compound
        Compound
        Compound
        108.00
        180.00
        128.00
        Compound
        134.00
        159.00
        110.00
        105.00
        Compound
        196.00
        196.00
        154.00
        163.00
        184.00
        139.00
        165.00
        168.00
        149.00
        198.00
        Compound
        Compound
        Compound
        Compound
        152.00
        184.00
        Compound
        120.00
        212.00
        244.00
        Compound
        Compound
        149.00
        
        
        Hot
        Hot
        Hot
        12
        12
        Hot
        
        13,
        
        Not
        
        IS
        15
        yt
        
        If.
        16
        20
        Hot
        Hot
        Hot
        Hot
        
        Hot
        2*
        25.
        Hot
        Hot
        25
        RT (RKL RT)
        
        D.t.ct.d.
        D.t.ct.d.
        D.t.ct.d.
        .641(0.990)
        .813(1.004)
        D.t.ct.d.
        
        cn * f1 i W
        
        D.t.ct.d.
        
        .218(0.927)
        .844(0.965)
        if¥?(1 m*»
        
        
        .853(1.026)
        .776(1.063)
        D.t.ct.d.
        D.t.ct.d.
        D.t.ct.d.
        D.t.ct.d.
        
        D.t.ct.d.
        -2*0 (0,91'"
        D.t.et.d.
        D.t.ct.d.
        .341(1.003)
        ON- COLUMN FINAL
        RESPONSE ( ng) ( ug)
        
        
        16551
        1841526
        
        inif
        
        
        
        79149
        37203
        
        n?n —
        40497
        321779
        
        
        
        
        	 "Tie
        -5-95 —
        428009
        
        <1.U4 J.U4"
        1.28 1.28
        49.39 49.39
        4 A 4 4 1 O 4 ^
        Q 07 	 0-r07
        
        
        
        2.50 2.50
        1.43 1.43
        
        	 l-r81 	 1 frl
        1.24 1.24
        5.84 5.84
        
        
        
        
        o.oi"" 	 e-f-ei
        9 . 14 9 . 14
         f1
        fPj8ftl^
        

        -------
         Data File: /chem/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  D6-5
         Volume Injected (uL> : 1.0
        42 Naphthalene
                                                     Page 11
        Column diameter :  0.32
        Scan 1215 (12.813 min) of YP791.d
        
        1.0-
        
        0.8-i
        XX
        gO.6-
        3 0.4-
        0.2-
        0.0-
        
        
        
        
        
        
        
        *
        
        
        
        
        
        
        
        . |[ .11 i|.. .. .,1 III.
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        .
        1.0-:
        0.8J
        
        vo 0.6-
        o :
        3 0.4:
        0.2:
        .
        0.0-
        Scan 1215 (12.81:
        
        
        
        
        
        
        
        i
        5 min) of YP791.d (Subtracted)
        
        
        
        
        
        
        
        i
        , il .11 HI. . J III .
        
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charge
        42 Naphthalene (PBM Reference Spectrum)
        •
        8.0:
        •
        ^ 6.0-
        fO
        
        3 4.0-
        XX
        
        ^2.0:
        •
        o.oJ
        
        
        
        
        
        
        
        ^
        
        
        
        
        
        
        
        
        
        
        l! Hi II. ,1 ill
        II 11 Jll Illl 1 II. Ill
        
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charge
        Scan 1215 (12.813 min) of YP791.d (2 DIFFERENCE)
        100-3
        75-i
        50-i
        25-i
        fc 
        JH
        GO
        CM
        
        
        
        
        
        
        
        
        12.4 12.6 12.8 13.0 13.2
        Time (min.)
        Mass 129.00
        a
        1.1-
        1.0-j
        0.9-j
        0.8-
        0.7-
        
        gO.6-
        3°*5"
        ^0.4-1
        0.3:
        0.2,
        0.1-
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        A
        
        **V s\ — ^_JJ
        t-^o
        8
        CM
        T-l
        
        
        
        
        
        
        
        
        
        
        
        ^\ ^ , Lr^^, ^ ^j-sXV^v
        12.4 12.6 12.8 13.0 13.2
        Time (min.)
        Mass 127.00
        
        1.4:
        
        1 2-
        A»fc-
        1 0-
        
        |0.8-
        -0.6-
        >-
        0.4:
        0 2-
        '.
        0 0-
        
        
        
        
        
        
        
        
        
        
        
        
        
        ^VVr r _J
        — fO
        «o
        CM
        T-(
        
        
        
        
        
        
        
        
        
        
        i~i ^j ~T-~I - i~ <~
        12.4 12.6 12.8 13.0 13.2
        Time (min.)
        

        -------
         Data File: /chen/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : DB-5
         Volume Injected 
          : 1.0 46 2-Methy.lnaphthalene Page 12 Column diameter : 0.32 Scan 1414 (14.240 min) of YP791.d . 8.0- ^6.0-J Ul S4.0: X XX "2.0-| .„ i .,.•!. hi,,, u 40 60 80 100 . ,.,! • 120 140 160 180 200 220 240 260 280 Mass/Charee Scan 1414 (14.240 min) of YP791.d (Subtracted) 8.0^ 6.0-J 34.0- X XX "2.0- .1. i , .,1. nl „. ..i. .. . #V |- r » i | i i- r [— i i T j i i 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charee 46 2-Methylnaphthalene (PBM Reference Spectrum) 8.0- £•> £_ 34.0^ 5. 2.0- 0 0- ,ii 1 1 ll, II Ih i,l , i 40 60 80 100 Scan 1414 (14 100-: 75-i 50 -i 25-5 !_2°j "-50-; -754 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charee .240 min) of YP791.d (2 DIFFERENCE) 1 " ""• 120 140 160 180 200 220 240 260 280 Mass/Charee Mass 142.00 9.0-d 8.0-j 7.0^ 6.0-: 555.0-i ^4.0-1 XX • >- 3.0-1 2.0-f 1.0-j 0.0-^ |T§ 1* ? 1 3 J II TV' M- 13.8 14.0 14.2 14.4 '14.6 Time (min.) Mass 141.00 7.0-; 6.0-; 5.0- ^4.0-i ^3.0^ 2.0- 1.0- 0 0- 1 •* n °i 3 1 "^ *"* {' Jl. Jl, u SJt r 13.8 14.0 14.2 14.4 14.6 Time (min.)

        -------
           Data File: /chem/Y.i/10-23-97.b/YP791.d
        
           Date : 23-OCT-97 16:00
        
           Instrument : Y.i
           Sample ID : SO-MH5-4-51
        
           Column phase : DB-5
           Volume Injected (uL) : 1.0
        
          56 Acenaphthylene
                                                                                                             Page 14
                                                               Column diameter :  0.32
                               Scan 1677 (16.132 rnin)  of  YP791.d
          3.5-j
          3.0-^
          2.5-1
          0.5-
          0.0-
              ,i Lh
               40
          3.2
          2.8
          2.4
        S1.6
        -1.2
          0.4
          0.0
          8.0-
        rd
          2.0-
          0.0
        40
          lOOri
         '-25H
         '-50-j
          -75-i
                           iii.jii.l[l.i.Jii
                60
                         80
        100     120
          Mass/Charge
        140
                                 160
        180
                         Scan 1677 (16.132 rain) of YP791.d (Subtracted)
               40       60      80      100     120     140
               	Mass/Charge	
                                                         160
                                                                  180
                             56 flcenaphthylene (PBM Reference Spectrum)
                        60
        100     120     140
          Hass/Charge	
                                 160
                                                                  180
                        Scan 1677 (16.132 min)  of YP791.d (Z DIFFERENCE)
         40      60      80      100     120     140      160     180
        	Hass/Charge	
        200
        .. ,1. ,b lllll ..... -..]... .1. ,..!.
        1 ,
        1
        1,
        1 -t .
                                                 200
        	 „, ,,l. .1)1, ,„,,, 	 	 1
        1
                                 200
        	 1. ..J ...III ..J 	 1... .1 	 ll.
        1 ,1 . ,r. 1 ...
                                                                                 200
                                                                                               Mass 152.00
                                                                                                       in*
                                                                                          15.80  16.00 16.20 16.'40  16.60
                                                                                               Time (min.)	
                                                                                               Mass 151.00
                                                                                                       R
                                                                                                  15.80 16.00  16.20 16.40 16.60
                                                                                                 	Time  (min.)
                                                                                                       Mass 153.00
                                                                                           15.80 16.00  16.20  16.40  16.60
                                                                                               Time (min.)	
        

        -------
         Data File: /chen/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase :  DB-5
         Volume Injected 
        i ) S
        ffiiss aS
        li * li * * i | ^
        V V V (fiV
        ^ UA N U
        JL MMHla
        W Kw V-m N ^ ^
        16.00 16.20 16.40 16.60 16.80
        Time (min.)
        Mass 152.00
        2.2-i
        2.0-i
        1 8-
        1.6-i
        1.4-j
        pl.2-j
        o :
        ^ o.s-i
        0.6-i
        0.4^
        0.2-;
        0 0-
        
        •
        
        
        Jg
        *
        . ^_Q
        II ^7ll
        L1"^* l^1 ^Jj] ' "^
        (fiv A vfUj;
        JWM^Wia
        ^jLiiP1 iy>^i-j^\
        16.00 16.20 16.40 16.60 16.80
        Time (min.)
        

        -------
          Data File: /chem/Y.i/10-23-97.b/YP791.d
          Date : 23-OCT-97 16:00
          Instrument : Y.i
          Sample ID : SO-MM5-4-51
          Column phase : DB-5
          Volume Injected J.h.L.-r.,4..v,a.^
        
               50    75   100   125   150  175   200   225  250   275   300  325   350
              	Hass/Charge	
         100-
          75-j
          50-j
          25-!
                       Scan 1877  (17.574 min) of YP791.d (2 DIFFERENCE)
        '-25^
        '-50-j
         -75-i
        -100-Vr-r
            J 11 M^HUI, j.lli .1.  .jLi.Jl ,, I jUjilllJil j .1 11,  ,
               50    75   100   125   150  175   200   225  250   275   300  325   350
                     	Mass/Charge	
                                                                                                        Mass 166.00
                                                                                           2.8-
                                                                                           2.5-
                                                                                           2.2-
                                                                                           2.0-
                                                                                         3 1.2-1
                                                                                            0.8-:
                                                                                            0.5-^
                                                                                           0.0-
                                                                                                               &
                                                                                                 17.20
        17.40  17.60
        Time (rain.)
                                                                                                                     17.80  18.00
                                                                                                       Mass 165.00
                                                                                            3.2-
        
                                                                                            2.8-
        
                                                                                            2.4-
        
                                                                                            2.0-
                                                                                           0.8:
        
                                                                                           0.4:
                                                                                           0.0-
                                                                                                 17.20 17.40  17.60 17.80  18.00
                                                                                                	Time (min.)	
                                                                                                       Mass 167.00
                                                                                                  17.20  17.40 17.60  17.80  18.00
                                                                                                        Time  (min.)	
        

        -------
         Data File: /chem/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  DB-5
         Volume Injected (uL> : 1.0
        73 Phenanthrene
                                                    Page 17
        Column diameter :  0.32
        Scan 2157 (19.594 min) of YP791.d
        2.8-3
        2.4-!
        2.0-i
        31.6-;
        ^1-2-i
        ^0.8-;
        0.4-i
        
        
        
        
        
        
        
        
        
        
        
        
        [I I! Mill 1 1 II 1
        ill. iLlLilllllLIIJu j. i.uiJ.>i,.ji,,iL ,, , . ]l iul .„. i. ...
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 2157 (19.594 min) of YP791.d (Subtracted)
        2.8n
        
        2.4-
        2.0-1
        
        £
        Sl.2-
        ^0.8-
        
        0.4-
        0 0-
        
        
        
        
        
        
        
        
        
        I
        , .1 . ii i,.. „, . J . t
        
        
        
        
        
        
        
        
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charge
        73 Phenanthrene (PBM Reference Spectrum)
        •
        8.0-j
        
        -6.0-
        f!
        |4.0-
        >-
        2.0-
        
        
        
        
        
        
        
        i
        . ,. , J J . . .1 J
        
        
        
        
        
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 2157 (19.594 min) of YP791.d (Z DIFFERENCE)
        100-
        
        75-
        50-
        25-
        fc 0-
        e-25-
        *t
        -50-
        -75-
        
        
        
        
        
        
        ,. J .,...,.11 „!.!.,. . *\1 .t t* ' "'t ..*«!*
        
        
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Mass 178.00
        2.8-j
        2.5-1
        2.2-i
        2.0-1
        ^1.8-j
        ?1.5-j
        |l.2-i
        ^1.0-j
        . 0.8-1
        0.5^
        0 2^
        v.t .
        0 0-
        
        ^
        U)
        1 a
        
        
        
        
        
        
        
        
        CM
        e
        *
        a
        s1 S
        i \ _j .
        Illl s
        
        VsA^VvVJk/^LllVMV^
        
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        Mass 179.00
        6.0^
        5.5-!
        5.0-
        
        4.5-i
        4.0-
        ...S.S-i
        S 3.o|
        l °°
        "*
        1 'K i
        I ^
        ^ i i
        
        i
        
        32.5| 1
        >-2.0-=
        1.5-;
        i.o-i
        0.5-j
        A
        k .1 H , j n\
        l^Afl/NAJ
        ipwy
        • 1 M
        IB /I J
        111/, 1
        v a II nftl N 'TJ
        • ^ 1 M ' 1 ftll
        1 ifl
        H ui
        
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        Mass 176.00
        4.8-=
        4.4-E
        4.0-^
        3 6-
        w* w .
        3.2^
        
        ^2*4-
        2 2*0 -^
        ^i]6j
        Ifs
        P
        ii •<-*
        
        
        
        
        
        
        
        
        J'
        
        
        
        
        
        
        
        
        
        ^
        ^£
        i1 g.
        i i o^A
        11 • r ^-*ji
        
        1 . | , J L ' r 1
        n 111 finilll
        If 1111 r 1 1| 'ii 1
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  DB-5
         Volume Injected (uL> : 1.0
        74 flnthracene
                                                    Page 18
        Column diameter :  0.32
        Scan 2172 (19.702 min) of YP791.d
        1.8-3
        
        1.5-1
        1.2-1
        31.0-j
        ^0.8-;
        ^0.5-;
        0.2-i
        0.0-^
        •
        
        
        
        
        •
        
        
        
        ll 1 1 1
        III 1 1 In 1 1 1 1 1 1 1 III
        ii iiilill i|illiil|li|ji!ililh4^ .ill, , i
        iii|ii/]iii|iii]jii|iii^iiiryir^i|iii|i- * :
        0.2:
        0 0-
        Scan 2172 (19.702 min) of YP791.d (Subtr
        
        
        
        
        
        
        
        . ..Hull ,1, 1 ,,. .. .1 ..i 1. Jl 1 II, n
        acted)
        
        
        
        
        
        
        
        . i i
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        74 Anthracene (PBM Reference Spectrum)
        
        8.0:
        
        ~6.0-
        to
        <
        34*°:
        5_
        2.0-
        
        
        
        
        
        
        
        fc
        • 1
        	 1 ..1 • - 1 -III
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        Scan 2172 (19.702 min) of YP791.d (2 DIFFERENCE)
        100-q
        
        75 -i
        50-1
        25-i
        £ o-l
        S-25-:
        *« :
        -50-j
        -75-i
        
        
        
        
        
        
        
        
        
        . . „ .1 ,. lll,.|ll ^ , ., 1 	 	 	 . 1 .,„! 1 	 	 1 II. . II .. 1 ,
        
        
        1
        
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        Mass 178.00
        a
        2.8-.
        2.5-j
        2.2-j
        2.0H
        1.8-1
        |l.5j
        ,x 1»'"-
        >- 1.0-1
        0.8-;
        0.5-j
        0.2-1
        0 0-
        f~s
        1 ^
        la
        
        
        
        
        
        
        
        
        
        8
        ***"+
        1 CF* \Q **f
        If) 1 fi. O
        Ko. ON .
        i ai s^1
        ^^wvJwXJA^^
        19.40 19.60 19.80 20.00
        Time (min.)
        Mass 176.00
        4.8-1
        4.4-J
        4.0H
        3.6-
        3.2-i
        P;2.8-i
        o2.4r
        
        ^i\6\
        1.2-=
        0.8-!
        0.4-i
        Ort-
        n§
        n *
        i
        
        
        
        
        
        
        
        
        1 1 1 1 1
        MI i
        II Ml llillll 11 111
        T-l
        
        
        •
        .j^ CM
        Se ^°
        & S
        •j §/
        I I 1 [S*M i
        ,1. JLIi '/yl ii
        fffli nrn 1 ill
        II 1 1 il 1 1 ft 1 Hi 1 rllfl
        19.40 19.60 19.80 20.00 20.2C
        Time (min.)
        Mass 179.00
        6.0-1
        5.5-
        5.0-=
        4.5-=
        
        4.0-j
        
        Ss.o-i
        32.54
        ^2.0-i
        1.5-j
        
        1.0-:
        
        
        If)
        
        rs i ?
        1 "• 1 i 1
        II ^ III J if
        
        
        
        
        J
        .1 , rt
        J ll ... . ] 1
        MNtU
        :-:if,f,:;,!,
        1 111 Jl I
        
        1 9
        
        111 111
        
        
        n (If
        
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : D8-5
         Volume Injected (uL)  : 1.0
        77 Fluoranthene
                                                    Page 11
        Column diameter :  0.32
        
        5.0-
        4.0-i
        -30-^
        ^ *
        |2.o
        ^
        i.O:
        On»
        .v
        
        
        5.0:
        
        4.0-
        
        3 0-
        5 * :
        o
        ^2.0-
        XX
        "l.O-
        Ofi-
        .v
        
        
        •
        8.0:
        ro * •
        §4.0:
        >. :
        2.0:
        
        
        
        
        100-;
        
        75-j
        
        50 -i
        25 -i
        <4- ftJ
        <4- '
        **-50-
        -75-:
        -1 rift »
        
        
        
        
        
        
        
        I
        i. ,
        
        UJ
        r i j -t \v}
        50 7
        
        
        
        
        
        
        
        
        
        
        I
        JL Jj
        j . f . n
        50 7
        
        
        
        
        
        
        
        
        i, i i , ,n, ,
        50 7
        
        
        
        
        
        
        I
        1 L
        ill -Jl. .Mill
        
        
        
        
        50 5
        
        Scan 2504 (22.095 min) of YP791.d
        
        
        
        
        I
        
        
        l^l|lll.|l|L|YJbj..J[l|.rrl,1. i|...i.^.Yi|.l|l^. . ;• -,| I ' J ' I \
        5 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 2504 (22.095 min) of YP791.d (Subtracted)
        
        
        
        
        
        
        
        1
        ,
        VV if V 1 VVr"l r f 1 1 ' •'( 'IV 'If- r VI I ' i * I \
        5 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        77 Fluoranthene (PBM Reference Spectrum)
        
        
        
        
        .
        
        ,,!,, 	 ,,,,,, 	 ,,,,,1 	 ,,,,,, 	 ,,
        5 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 2504 (22.095 min) of YP791.d (Z DIFFERENCE)
        
        
        
        .
        
        
        IftiU *i i di 	 1 j nV- ,-- , , . j t A «•*— . • 1 i k .
        1 ' JI
        
        
        
        '5 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        
        3.2:
        2.8:
        2.4:
        
        ^2.0-
        Sl.6-
        
        ^1«2-
        0.8-
        
        0.4-
        On '
        
        21
        
        
        9.0-
        
        8*°i
        7.0-:
        6.0J
        -5.0^
        o
        34-°~
        ^3.0-
        2.0-j
        ;
        o'o1
        y.u
        21
        
        
        4.8-i
        4.4-j
        4 0-
        2 CJ
        o.o .
        3.2--
        
        Q2.8-
        S2.4^
        3 2.0^
        ^ ;
        1.6-:
        0.8-i
        0.4^
        
        v»v
        21
        
        Mass 202.00
        
        «
        *
        CM
        CM
        1
        
        
        
        
        
        J
        MvV\ Vl Aft AM
        
        .60 21.80 22.00 22.20" 22.40
        Time (min.)
        Mass 101.00
        i
        
        
        I
        II
        III
        j -
        ,i || |
        !| I Jl| I
        J j 1| V
        f^jw' Y nj|
        .60 21.80 22.00 22.20 22.40
        Time (min.)
        Mass 100.00
        
        
        
        
        i
        1
        fl
        I
        
        
        
        -
        1
        a
        CVJ 1 \
        .x-^rv^^^x A-f-A***
        .60 21.80 22.00 22.20 22.40
        Time (min.)
        

        -------
         fiata File:  /chem/Y.i/10-23-97.b/YP791.d
         Date : 23-OCT-97 16:00
         Instrument  :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  DB-5
         Volume Injected 
          : 1.0 78 Pyrene Page 19 Column diameter : 0.32 3.2-; 2.8-; 2.4-; xx2.o-; Si.e-; XX 1+Z~ >"0 8- . • • 0.4-: 0.0-3 ll ill 40 3.2- 2.8-i 2.4-^ 2.0-= •^ ^1.6- XX -^*^ - "-o.s-i 0.4-i «\.i lT-1Mm 40 8.0: ~ 6.0- m • < 34.0-5 >- " 2.0: 0 0- V.W | i 40 100-g 75-j 50-1 25i S"25] -50- -75-E 40 Scan 2571 (22.579 win) of YP791.d J b 1 Jjil 1 i 1 • i • I 1 U i >• 1, 1 ........ ,l> . L . , •T l"l"1 1 "i 'i t ' ' ' 1 ' ' • 1 • • ' 1 ' ' 80 120 160 200 240 280 320 360 400 Mass/Charee Scan 2571 (22.579 min) of YP791.d (Subtracted) ill 1 JL,|..|...I| till. . . i. ... .1 .1.1 , 1 . ,,i , , , ,1. i. * ' ' I * ' ' T ' ' ' 1 ' ' ' 1 ' ' ' ' ' 80 120 160 200 240 280 320 360 400 Mass/Charee 78 Pyrene (P - • ' J BM Reference Spectrum) 80 120 160 200 240 280 320 360 400 Mass/Charge Scan 2571 (22.579 min) of YP791.d (Z DIFFERENCE) ll ' 80 120 160 200 240 280 320 360 400 Mass/Charge Mass 202.00 3.2-1 ; 2.8- 2.4: |~£ a ^2-4 ? ]A *» 1.6-1 •rH HI •2 j] *• * ~ 0.8: 0.4: : i*» 0 1 °* 1 11 ^AAJk^AAAA/f VAA A 22.20 22.40 22.60 22.80 23.00 Time (min.) Mass 101.00 9 O-i ^*v . 8.0-i 7>0j 6.0-i •^50- S * ': J4.0- 2.0- 1.0-j kit ^ 1 II CM ^ 1 i Jlltl 1 1 111 IT 11 fill 7 J \rtwyiu. \m vrnv v w 111 FlfVr 1 1 I\V .0 i i | i i i | i i i i i • i | • • i | i 22.20 22.40 22.60 22.80 23.00 Time (min.) 3n .2: 2.8: 2.4- ^2.0- XX 0.8- 0 4- v.t 0.0^ Mass 100 At «.j yi i/ .00 — m to • i 8 1 1 \ J Jb^oi\A/T7r . Y^ffMfri.1, U*/ 22.20 22.40 22.60 22.80 23.00 Time (min.)

        -------
         Data File: /chem/Y.i/10-23-97.b/CAfl/YP791.d
         Date : 23-OCT-97  16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase :  DB.5-625
         Volume Injected (uL) : 1.0
        21  Cumene
                                                    Pace 13
        Column diameter :  0.32
        
        1.4-j
        1.2-j
        
        I0'8-!
        ^0.6-i
        XX
        =-0.4-:
        0.2-=
        0 0 '
        
        
        
        
        
        ,
        
        ill
        50
        
        
        1.4-i
        1.2-;
        1.0-i
        o * :
        30.6-
        >• 0 4-
        :
        0.2-;
        
        n rt-i
        
        
        
        
        
        
        I,
        N
        III
        u»y • i
        50
        
        
        8.0:
        ~6.0-^
        p> * •
        <
        ^4.0-
        XX
        
        2.0:
        0 0-
        
        
        
        
        
        
        
        ,L
        
        
        
        
        
        
        |
        II |
        y
        
        
        
        
        .1
        
        1
        Ihi
        
        
        
        
        
        
        
        ll
        Scan 641 (8.715 min) of YP791.d
        
        
        
        
        
        
        
        1
        
        
        i 1
        k II 1 ,
        75 100 125 150 175 200 225 250 275 300 325
        
        Mass/Charee
        Scan 641 (8.715 min) of YP791.d (Subtracted)
        
        
        
        
        
        
        
        
        V
        
        
        
        
        
        
        
        
        1
        1 1 i
        ..Illl I
        
        
        
        
        
        
        
        
        i
        
        
        
        
        
        . i ,
        75 100 125 150 175 200 225 250 275 300 325
        
        
        
        
        
        
        
        
        
        .... Jl
        Mass/Charee
        21 Cumene (PBM Reference Spectrum)
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        Jl
        50 75 100 125 150 175 200 225 250 275 300 325
        
        
        100-q
        :
        75-j
        50-j
        251
        S-25-1
        "-50-!
        
        -75 -!
        -100-
        
        
        
        1
        
        l*'l.fJ
        
        
        
        
        Mass/Charee
        Scan 641 (8.715 min) of YP791.d (2 DIFFERENCE)
        
        
        
        
        
        ...I
        
        
        
        
        
        
        
        
        
        
        
        
        
        •Y--r' '
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325
        
        
        Mass/Charee
        Mass 105.00
        7.0-
        
        6.0-
        5.0-
        ^
        g4.0-
        -3.0-
        >-
        2.0-
        
        1.0-
        0.0-
        I ^
        1 °°
        
        
        1
        
        
        
        
        
        
        
        
        I
        1
        ; il i \\ II d I\J
        fxj JIU M M It ft
        1 1 1 | 1 i 1 j ii i|ii ill IT i
        8.4 8.6 8.8 9;0 9.2
        Time (min.)
        Mass 120.00
        2.2-^
        2.0-1
        1.8-i
        1 fi-
        
        :
        ~ :
        £> -
        XX
        0.6H
        0.2-i
        
        Oci-
        
        
        •r-4
        »•
        
        i
        
        
        1
        1
        1
        l
        III
        I l
        
        i n
        ii n
        8.4 8.6 8.8 9.0 9.2
        Time (min.)
        Mass 77.00
        
        1.4:
        
        1.2":
        
        1.0-
        XX
        i°*8"
        X
        ^0.6-
        0.4-
        |
        I
        I
        
        \
        \
        
        
        1
        s
        ? J
        i A /^
        0.2-/ 1 A .j. (\ . il L i
        
        o o ' i 1 1 f¥ IM ! 'i \ 1 1 i iY \WJ X|
        8.4 8.6 8.8 9.0 9.2
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-23-97.b/CIWYP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : DB.5-625
         Volume Injected 
          : 1.0 23 Phenol Page 14 Column diameter : 0.32 2.0-1 -0.8-1 0.4-1 Ort- .U-i 2.0-1 1.6- |l.2- 3 0.8- 0.4- LL Scan 748 (9.476 min) of YP791.d 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charee Sc 1 1 II ,1,1 I n, , :an 748 (9.476 min) of YP791.d (Subtracted) .. . .. L 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charee 8.0-1 g6'°- 34.0: 2.0- 0 0- Kill,., 23 Phenol (PBM Reference Spectrum) 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charge 100- 75-= 50-j 254 £ o-: **-50-j -754 Scan 748 (9.476 min) of YP791.d (Z DIFFERENCE) .U.....JL...1 J..J.. .. . - ... 1. 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charee 2.2^ 2.0^ 1.8-i 1.6-i 1.4^ i * ~: 0.6H 0.4-i 0.2-j Mass 94 .00 r- ' 9.00 9.20 9.40 9.60 9.80 Time (min.) 7.0- 6.0-1 5.0- 54.0: o ^3.0- 2.0- 1.0-1 Mass 65 .00 -<3- * V.^.t/\* — , , — J \f 9.00 9.20 9.40 9.60 9.80 Time (min.) 8.0^ 7.0- 6.0^ ^5.0-1 2.0-: i.o-; 0 0- Mass 66 .00 9.00 9.20 9.40 9.60 9.80 Time (min.)

        -------
         •Data File: /chem/Y.i/10-23-97.b/CflfVYP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : DB.5-625
         Volume Injected (uL)  : 1.0
        29 1,4-Dichlorobenzene
                                                     Page 16
        Column diameter :  0.32
        Scan 857 (10.253 win) of YP791.d
        1.8-j
        1.5-1
        1.2-j
        
        Si.o-i
        30.8-j
        XX
        
        
        
        
        J
        
        .11
        
        
        I
        
        >. o 5- ill j|
        
        °:*PJL LI
        o.o-3
        •illllllijiil Ilil 1
        
        
        
        
        
        
        
        
        i
        
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        Scan 857 (10.253 win) of YP791.d (Subtracted)
        1.2-=
        1.0-i
        
        80.6-i
        x :
        >lo.4-j
        •
        0.2-i
        0.0-
        
        
        
        
        
        
        
        
        +
        
        
        
        
        , i
        i
        . 1 ..r, 1 1, ,
        
        
        
        
        
        
        
        
        i
        
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        29 1,4-Dichlorobenzene (PBM Reference Spectrum)
        
        8.0-j
        •
        ? * '
        <
        
        -------
         Data File: /chem/Y.i/10-23-97.b/Cflfl/YP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : DB.5-625
         Volume Injected (uL>  : 1.0
        31 2-Hethylphenol
                                                     Page 17
        Column diameter :  0.32
        8.0-:
        7.0-1
        6.0-j
        S55*H
        *3.o-i
        1::
        I I I
        4
        U.U | i i
        40
        5.0-;
        4.0-;
        fo3.0-
        o
        £2.0-
        "~1.0-
        0 A-
        , h
        40
        8.0-^
        Z * "
        2.0-
        Oft-
        
        • i
        80
        |j
        i
        80
        
        ,L
        40
        100-
        75-;
        50 -j
        25-
        £ Or
        « -25-!
        "-50-
        -75-
        -1ftft-
        rr
        40
        
        80
        h
        f
        80
        Scan 915 (10.667 min) of YP791.d
        III i II
        120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        J^.
        Scan 915 (10.667 min) of YP791.d (Subtracted)
        1 1
        120 160 200 240 280 320 360 400 440 480
        Mass/Charge
        
        31 2-Methalphenol (PBM Reference Spectrum) •
        120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        c
        r
        Scan 915 (10.667 Bin) of YP791.d (Z DIFFERENCE)
        t ' ' '
        120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        6.0-
        5.0-
        -4.0-
        5°
        3 3.0-
        XX
        ^2.0-
        1.0-
        M
        Hi
        ass 101
        i
        3.00
        u
        1
        \\
        —*a
        *.
        o
        "
        1), I
        10.20 10.40 10.60 10.80 il.OO
        Time (min.)
        5.0-
        4.5H
        4.0-
        3.5-
        -3.0-
        i2^
        ^2.0-
        *"i.s-i
        1.0-i
        0.5-
        Mass 77.00
        • §«
        |j vjl
        I
        10.20 10.40 10.60 10.80 11.00
        Time (min.)
        4.8-
        4.4-^
        4.0-
        3.6-;
        3.2-:
        -2.8-
        g2.4-
        >-1.6-
        1.2-i
        0.8-
        0.4-
        0 0-
        Mass 90.00
        CVJ
        Lg
        bint lii
        J
        10.20 10.40 10.60 10.80 11.00
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-23-97.b/CAft/YP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : DB.5-625
         Volume Injected (uL)  : 1.0
        32 3/4-Methy.lphenol
                                                     Page 18
        Column diameter :  0.32
        
        3.2-
        2.8-i
        2.4-=
        ~2.0-f
        Si. 6-:
        3l.2-j
        0.4-i
        
        
        
        ,
        2 8J
        *.» v .
        2.4-j
        ^2.0-:
        ?1 6^
        ^H •
        Srf* A*^ •
        *-0.8-i
        0.4-j
        
        
        
        
        •
        •
        8.0-
        ~6 0-
        P5 * •
        2 . . •
        34.0-
        ._
        2.0-
        
        • V
        
        
        100-
        75-
        50-
        25-
        «4- 0-
        <^
        S-25-
        
        ^-50-
        -75-
        inrt
        
        
        
        
        
        
        
        i
        i I
        ILkuLuj
        * * * * * * ^
        40 80
        
        Sea
        
        
        
        
        
        
        
        J
        (Lk4^
        \ ' ' ' I ' ^
        40 80
        
        
        
        
        
        
        
        
        
        
        
        -UJ
        T '
        40 80
        
        Scar
        
        
        
        J J-|Lj •_ ,_ _,
        r T> \
        
        
        
        
        
        40 80
        
        Scan 957 (10.966 min) of YP791.d
        
        
        
        
        
        
        
        J ,
        120 160 200 240 280 320 360 400
        Mass/Charee
        n 957 (10.966 min) of YP791.d (Subtracted)
        
        
        
        
        
        
        
        
        ..1.
        
        120 160 200 240 280 320 360 400
        Mass/Charee
        !2 3/4-Methylphenol (PBM Reference Spectrum)
        
        
        
        
        
        
        
        
        
        
        
        120 160 200 240 280 320 360 400
        Mass/Charee
        i 957 (10.966 min) of YP791.d (2 DIFFERENCE)
        
        
        
        i . 1 i
        
        
        
        
        
        
        120 160 200 240 280 320 360 400
        Mass/Charee
        
        :
        6.0-!
        
        5.0-;
        •
        ro '.
        33.0-;
        *•« ^:
        2.0-
        1A
        *o~
        V»V
        
        
        
        3.6H
        .
        3.2-i
        :
        2.4^
        ,
        52.0-
        s
        31.6-
        "1.2-i
        *
        0.8-^
        0.4-i
        OA
        .u
        
        
        
        :
        1.8--
        
        1.6-i
        1.4-j
        1.2-i
        ^i.o-j
        "><0 8-^
        >_ i
        0.6-:
        
        0.4-:
        
        0.2^
        0.0-
        
        
        Mass 108.00
        
        '
        
        
        
        
        I
        »
        
        
        i Ml!!1^
        
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        Mass 107.00
        IPO
        ff^
        s
        
        
        
        
        
        
        
        
        
        
        /\«^A A *AlV^ AA*J
        i I i i i I 'i 'TTI T T»r i '|lqF
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        Mass 79.00
        (1
        ll
        
        GO II
        « 1
        O II
        I j'
        111
        " 1
        
        ^ 1 III J 1 I II
        a I , I
        
        I'AJI I ll U 1 lu
        
        
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        

        -------
         Data Filej  /chem/Y.i/10-23-97.b/ClWYP791.d
         Date : 23-OCT-97 16:00
         Instrument  :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  DB.5-625
         Volume Injected 
          : 1.0 33 flcetophenone Page 19 Column diameter : 0.32 • 8.0: . 6.0- o . • £ * • *~2 0: \ , 40 8.0- xx6-°" |j4.0- X *~2.0- , . ll, 40 8.0- ~ 6.0- ro o : 34.0- ^. 2.0- fl 0- 40 100-q 75- 50 -. 25- rt ' (4- s-25- "-so-i -75- . 40 MM nl 80 i; ..-.jj LU..J Scan 960 (10.988 min) of YP791.d I >0 160 200 240 280 320 360 400 440 480 Mass/Charee Scan 960 (10.988 min) of YP791.d (Subtracted) so i: i 80 L . 20 160 200 240 280 320 360 400 440 480 Mass/Charge 33 ftcetophenone (PBM Reference Spectrum) 20 160 200 240 280 320 360 400 440 480 Mass/Charee Scan 960 (10.988 min) of YP791.d « DIFFERENCE) * a-m m * - r i ["' 80 120 160 200 240 280 320 360 400 440 480 Mass/Charee Mass 105.00 1.2-1 1.14 1.0-= 0.9H 0.8H £0.7-; ^0.51 0.3-i ft OJ o.i-i i J 1 •I III If I~-QO 1— -flP \m iS fl * n * o K o 11 ^H II v-4 S 1 II PO IH ] GO | iHro i • h ^K ft S 1 i ^ ll ^ * JrUlAi/Ul/ 10.60 10.80 11.00 11.20 11.40 Time (rain.) Mass 77.00 9.0- 8.0-; 7.0-i 6.0^ 55.0: o ' 34.0- ^ : 3.0- 2.0- 1.0- 0 J1 I §. i o 1 1 S II fl> o fl ^IM 1 'r*r1 ft /I1? I M tf Nl i) li i/ l\i * *~* 1 i HI t s ll / (Ji — nJ/ UJ/ 1 Uf i i — a/ 10.60 10.80 11.00 11.20 11.40 Time (min.) Mass 120.00 2.2J 2.0-; 10 • .OJ 1.6-^ 1.4- n.2- 31.0: A Q- 0.6- 0.4-; 0.2- 0 0- m * S ,,,A S5 I • S ft ^ °* II ro TH II o ' $ 1 , J ^1 11 1 5^ 7i' M ll 1 1 fl I I lUIIN S 10.60 10.80 11.00 11.20 11.40 Time (min.)

        -------
         flata File: /che«/Y.i/10-23-97.b/CAft/YP791.d
         Date : 23-OCT-97 16:00
         Instrument :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  DB.5-625
         Volume Injected (uL) : 1.0
        43 1,2,4-Trichlorobenzene
                                                     Page 25
        Column diameter :  0.32
        Scan 1191 (12.641 nin) of YP791.d
        7.0-d
        > + v «
        6.0-1
        
        5 0-^
        iJ.V .
        p4.0-|
        3 ^ o-
        _>< * :
        5-2.0--
        i.o-i
        0.0J
        
        
        
        
        
        
        
        
        
        i i
        Ii i|Llk Jl
        
        40 60
        
        
        
        
        
        
        
        
        
        
        *
        
        
        
        
        
        , 	 J
        I ' I
        80 100
        
        
        
        
        
        
        
        
        
        
        Ihl
        
        
        
        
        
        
        
        
        
        
        
        
        1 .1.1. J
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        II,
        1 '
        120 140
        i i | i i i | i • i | i
        160 180 200
        Mass/Charee
        Scan 1191 (12.641 min) of YP791.d (Subtracted)
        60-
        *V .
        5.0-i
        ^4.0-;
        s3*°i
        X
        5-2*0"
        i.o-i
        0.0-
        
        
        
        
        
        
        
        nil, .L...1L j|
        
        40 60
        
        
        
        
        
        
        1
        .„,
        
        
        
        
        
        1 ' * ' 1
        80 100
        
        
        
        
        
        
        
        ll 1
        
        
        
        
        
        
        
        
        
        ' '. '
        
        
        
        
        
        
        
        .1 .
        1 1 ' ' i
        120 140
        
        
        
        
        
        
        
        11
        • • I > i i | • i > I i
        160 180 200
        Mass/Charee
        43 1,2,
        8.0:
        £n * •
        I4'0:
        >_
        2.0:
        
        
        
        
        
        I
        ,, ..ll.M ., ,11
        *U~ | i i i | i i
        40 60
        4-Trichlorobenrene (PBM Reference Spectrum)
        
        
        
        
        
        1,. ,
        80 100
        
        
        
        
        
        
        
        
        
        
        
        
        1. T . J
        120 140
        
        
        
        
        
        .1
        
        
        
        
        
        
        
        160 180 200
        Mass/Charee
        Scan 1191 (12.641 win) of YP791.d (Z
        100-g
        75 -i
        50-i
        •
        25-i
        
        s-25J
        ~-50-i
        
        -754
        -100-
        
        
        
        
        
        , J.I.. ...,l,..,.JL.^r
        
        
        
        
        
        40 60
        
        
        -
        
        1.
        U. 	 i
        
        
        
        	 J
        
        
        
        
        
        80 100
        
        
        
        
        
        -I
        
        
        
        
        
        
        
        
        
        
        
        ... J... .a
        
        
        
        
        
        1 ... ...,.
        I
        
        
        
        
        120 140
        DIFFERENCE)
        
        
        
        
        
        	
        
        
        
        
        . r
        
        
        
        
        
        160 180 200
        Mass/Charee
        Mass 180.00
        
        1.0-:
        :
        0.9^
        ;
        0.8-:
        0.7-i
        
        xxO.6-1
        ?" :
        0.3-i
        
        0.2-i
        O.lT
        0 0-
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        — «H
        
        cJ
        rH
        
        
        
        8
        3
        a
        i
        1
        
        
        
        .
        I i\
        12.2 12.4 12.6 12.8 '13.0
        Time (min.)
        Mass 145.00
        3.6-j
        
        3.2-!
        2.8-i
        2.4-;
        
        ^2.0-
        ^516-
        0.8^
        0.4-
        0.0-
        1
        , . | 13
        
        1
        
        
        
        1 j|
        i 111
        II 1 fl III
        SH I 11 II 1
        Ml
        l
        11 '
        iifl
        j^ '
        I
        11 U i i
        12.2 12.4 12.6 12.8 13.0
        Time (min.)
        Mass 109.00
        8.0-1 1
        7 0~
        
        6.0-:
        
        
        .
        
        00
        5.0- 1 3 II
        ^, J a
        O 4»vT| | II (SI
        "S< "1 i / II S
        ^3.0-j
        2.0-
        
        1.0-
        
        1 ft J «
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        ftJiMljWiV Vkfv r1 r u wv
        n iifw N"*li— J ' u '^LJ
        00; , ,,II, ,, ,, 	 1,,,
        12.2 12.4 12.6 12.8 13.0
        Time (min.)
        

        -------
         'Data File: /chem/Y.i/10-23-97.b/Cftfl/YP791.d
         Date : 23-OCT-97 16:00
         Instrument :  Y.i
         Sample ID : SO-HM5-4-51
         Column phase  :  DB.5-625
         Volume Injected (uL> : 1.0
        60 Biphenyl
                                                     Page 33
        Column diameter :  0.32
        
        
        4.0-j
        3.0-
        1 :
        |2.0-
        *~1.0-
        0.0-
        
        
        
        
        
        
        i
        
        
        
        
        
        .Ii]
        1 1 . 1
        Scan 1550 (15.218 min) of YP791.d
        
        
        
        
        
        *
        
        
        
        
        ll 1
        II 1 1 1 Jl
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        
        
        
        4.0:
        
        ^3.0:
        |2.0^
        XX
        "i.o-
        
        A fl-
        
        
        
        
        
        
        
        
        
        
        
        
        
        j
        V»V ii ii
        50
        
        
        
        
        8.0-
        
        
        S)6*0"^
        £
        ^4.0-;
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        2.0-
        
        
        
        
        
        
        
        
        
        
        
        §
        1,
        50
        
        
        100-:
        
        75 -j
        50 -I
        25i
        5-25-1
        **-50-j
        -75-i
        -1ftrt-
        
        
        
        
        
        
        
        
        
        50
        
        Mass/Charee
        Scan 1550 (15.218 min) of YP791.d (Subtracted)
        
        
        
        
        
        
        
        I
        ' {•!• V Ir/'ll'i 7
        
        
        
        
        
        
        
        
        
        75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        60 Biphenyl (PBM Reference Spectrum)
        
        
        
        
        
        
        
        
        
        '
        ,„,,.., I,,-,,,,,
        
        
        
        
        
        
        
        
        
        
        
        75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 1550 (15.218 min) of YP791.d (Z DIFFERENCE)
        
        
        
        •
        | 	 	
        1 I
        
        
        
        75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Mass 154.00
        4.4-!
        4.0-i
        3.6-!
        3.2-!
        2.8-i
        |2.ji
        «**• *
        ^1.6-i
        1.2-i
        ft gj
        0.4-i
        
        c3
        a
        
        
        
        
        en
        o "J
        if) **
        *"* '
        .' ft » F
        . A JK../V, JWV/
        14.8 15.0 15.2 15.4 - 15.6
        Time (min.)
        Mass 152.00
        7.0n
        6.0-
        
        5.0-
        
        ^4.0-
        o
        33.0-
        j.
        2.0-
        
        
        1.0-
        
        0.0-
        1
        in
        •rH
        
        
        .
        
        n
        ,J
        CM 1 ?
        If) J 1 •
        *HI 1 If)
        nil 1 f
        m A. /
        / A AJ
        ^ 	 I VvrM \rAV W
        1 | f l l rT"T | * I T-| T1 I | I I
        14.80 15.00 15.20 15.40 15.60
        Time (min.)
        Mass 155.00
        3.0^
        2.8-
        2.5-1
        2.2-1
        
        2.0-i
        
        p * i
        S 1.2-i
        0.8-
        0.5-
        0.2-
        0 0-
        CM
        S
        *
        lf>
        *-< 1
        i
        K
        ft
        
        
        CO II
        §
        i 7
        » I 1
        s ft
        1 JL JL J I
        . »i. j-w. jWWwlL/ W
        14.8 15.0 15.2 15.4 15.6
        Time (min.)
        

        -------
         •Data File: /chem/Y.i/10-23-97.b/Cftft/YP791.d
         Date : 23-OCT-97 16:00
         Instrument : Y.i
         Sample ID : SO-MM5-4-51
         Column phase : DB.5-625
         Volume Injected (uL>  : 1.0
        61 Dimethylphthalate
                                                    Page 34
        Column diameter :  0.32
        Scan 1637 (15.844 min) of YP791.d
        :
        2.0-
        1.8-
        1.5-i
        
        S1-0-!
        -0.8-
        
        1
        
        
        
        i
        .
        .
        
        
        
        
        
        
        -o.5i.il I .1 1 1 il 11,1
        0.2-i
        0.0-3
        1 iw^whU 	
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 1637 (15.844 min) of YP791.d (Subtracted)
        2.0-f
        
        1.8-1
        1.5-1
        
        Sl.O-l
        3 0.8-1
        "0.5-j
        0.2-j
        
        
        
        
        
        
        
        ,
        .1. 1...I . .1 	 ill- 1.1.
        
        
        
        
        
        
        
        
        iilllL 1,1 i
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        
        •
        8.0:
        -6.0-
        <° -
        |4.0:
        >.
        2.0-
        0.0-
        61 Dimethylphtha
        
        
        
        
        
        
        
        I ! 1 4 j
        
        late (PBM Reference Spectrum)
        
        
        
        
        
        
        
        I 1
        1 i • • • • i • • • • i • • • • i • • ' • i ' ' • • i • • ' ' i • • • • i •
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 1637 (15.844 rain) of YP791.d (Z DIFFERENCE)
        100-
        75-
        
        50-
        
        25-
        <*. o-
        5-25-
        *>t
        -50-
        -75-
        100
        
        
        
        
        
        ....... -lr- •!«•' — «-• i-,-I..J.Jjl.Vr. U 1 .if. -0.8-l
        0.6-;
        0.4-:
        0.2-I
        n rt :
        W# v
        
        
        
        
        
        
        
        
        f?5
        *
        ^
        »
        AA
        xjixy^
        
        t yr
        s.
        II m
        
        
        
        
        
        
        i J
        'VUJ
        1
        
        
        
        i. 1
        *"* r
        i i
        I . 	 J\J H
        V if ^f^Y"^ Vl—J1>vvJ'
        [ -I r"r | . • , | . . . , . i T i . .
        15.40 15.60 15.80 16.00 16.20
        Time (min.)
        Mass 194.00
        1.4:
        •
        1.2:
        1.0:
        SO 8^
        o
        3 0.6:
        0.4-
        
        o.2:
        OA
        .V
        1
        
        
        
        O
        a
        
        
        
        
        
        
        5.40 15.60 15. (
        to
        CO
        §'"
        .
        r-l
        ^
        
        1?
        
        
        
        
        30 16.00 16.20
        Time (min.)
        Mass 164.00
        5.0-|
        
        4.5-ji
        4.0-j
        3.5-1
        :
        ^3.0-:
        rO
        <
        S2.5-:
        1.5-j
        
        2-i
        5
        
        
        
        T li
        
        I
        j ii
        \\
        \\ \
        III
        i.o-li \ | fy^
        0.5| JM
        o o V \\ 'i''i | i i i [
        ^.
        GO
        a*
        i
        i
        
        1 00
        k ^
        iHiM I
        1™
        15.40 15.60 15.80 16.00 16.20
        Time (min.)
        

        -------
           Data File: /chem/Y.i/10-23-97.b/Cftfl/YP791.d
           Date : 23-OCT-97 16:00
           Instrument : Y.i
           Sample ID : SO-MM5-4-51
           Column phase : DB.5-625
           Volume Injected 
          : 1.0 65 Dibenzofuran Page 38 Column diameter : 0.32 2.0: 1.6: :1.2: ^0.8: 0.4- 0.0- 8.0- !4.0- 0.0- 100- 75-1 50-j 25-i 5£ 0-! »-25-l "-50-I -75-i -100- Scan 1777 (16.853 min> of YP791.d I 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charge Scan 1777 (16.853 min) of YP791.d (Subtracted) r^ 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charge 65 Dibenzofuran (PBM Reference Spectrum) 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charge Scan 1777 (16.853 min) of YP791.d (2 DIFFERENCE) 50 75 100 125 150 175 200 225 250 275 300 325 350 Mass/Charge Mass 168.00 16.40 16.60 16.80 17.00 17.20 Time (min.) Mass 139.00 16.40 16.60 16.80 17.00 17.20 Time (min.)

        -------
         Oata File: /chen/Y.i/10-23-97.b/CftlVYP791.d
         Date : 23-OCT-97 16:00
         Instrument :  Y.i
         Sample ID : SO-MM5-4-51
         Column phase  :  DB.5-625
         Volume Injected (uL) : 1.0
        66 Di-n-butylphthalate
                                                    Page 39
        Column diameter :  0.32
        Scan 2321 (20.776 win) of YP791.d
        1.8-:
        1.5-^
        1.2-j
        £1.0-!
        ^ =
        30.8-:
        ^o.s-i
        0.2-1
        
        
        
        
        .
        
        
        
        
        .JiiiA...,,..,.,. i ...A.L.. ..„.
        50 75 100 125 1!
        •
        
        
        
        
        
        
        
        
        50 175 200 225 250 275 300 325 350
        Mass/Charee
        Scan 2321 (20.776 min) of YP791.d (Subtracted)
        1.8-3
        I
        1.5-j
        1 9-
        *. + £. -
        Sl.O-j
        |0.8-|
        ^o.s-i
        °*2i
        
        0.0-=
        
        
        
        
        
        
        
        
        
        • i
        
        , , | / , 1 , f , , , , , 1 , , 1 1 , , , /
        
        
        
        
        
        
        
        
        
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charee
        
        :
        8.0-^
        -
        x, 6.0-
        ro
        < J
        §4.0-5
        >-
        2.0:
        0.0-
        66 Di-n-butylp
        
        
        
        
        
        
        
        
        
        J I/1 1 f ' \ J-
        
        hthalate (PBM Reference Spectrum)
        
        
        
        
        
        
        
        
        
        | i
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charge
        Scan 2321 (20.776 win) of YP791.d (2 DIFFERENCE)
        100-:
        75i
        50-j
        
        254
        «4- 0™
        t»- :
        S-25i
        -50-:
        -754
        100 :
        
        
        
        
        
        r--,r 	 - 	 	 	 ...--.-
        
        
        
        
        50 75 100 125 150 175 200 225 250 275 300 325 350
        Mass/Charge
        Mass 149.00
        1.8-j
        1.6-i
        1.4^
        ;
        1.2:
        -10^
        ?* ' :
        ^0.8:
        >-0.6-^
        0 4-
        v.*t t
        0.2:
        
        J-JS
        §
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        I
        	 	 . J U. 	 ..
        
        20.40 20.60 20.80 21.00 21.20
        Time (min.)
        Mass 150.00
        
        1.4-j
        1.2-
        •
        i.O:
        
        "~"0 8-
        < * •
        o
        TH
        0 4-
        v»*t
        0.2-
        
        
        Oh-
        . ^Q
        1 o*
        j
        
        
        
        
        
        
        
        
        
        I j . n j . 1 ** J
        L>J
        
        
        
        
        
        1
        
        
        i
        \ . i A A ..I
        ill/'VAil An/^ift/y ijMJ MUiiM^rt^iJ
        Vw Uw/VV 1 I nW/VT/rVVn/
        20.40 20.60 20.80 21.00 21.20
        Time (min.)
        Mass 104.00
        8.0-j
        
        7.0-i
        :
        6.0-;
        ^s.oi
        <° :
        24.0-
        T-l ^*v .
        X ;
        ^3.0-i
        2.0-i
        1 0-
        -l.V H
        0 0-
        n=
        ^
        -
        
        
        
        
        
        
        
        j
        A * ,n
        
        
        
        
        
        f ..... 1
        WmjAifcW Ujittnl^l,iiik
        V 'YlWl Inilnml
        . , . J.u! . .If. .IMiii J 1
        20.40 20.60 20.80 21.00 21.20
        Time (win.)
        

        -------
        * Data File:  /chem/Y.i/10-23-97.b/Cfl(VYP791.d
          Date : 23-OCT-97 16:00
          Instrument  :  Y.i
          Sample ID : SO-MM5-4-51
          Column phase  :  DB.5-625
          Volume Injected (uL> : 1.0
         83 bis(2-Ethylhexyl)phthalate
                                                     Page 47
        Column diameter :  0.32
        Scan 2954 (25.341 min) of YP791.d
        1.6-J
        1.4-1
        1.2-j
        l.O-'
        LO
        ^o.s-i
        So.e-i
        "-0.4-i
        0.2-i
        
        
        
        
        
        
        
        i i
        lil^i,.-. .
        •
        
        
        
        
        
        
        
        . I ..
        40 80 120 160 200 240 280 320 360 400
        Mass/Charee
        Scan 2954 (25.341 min) of YP791.d (Subtracted)
        1.6-a
        1.4-i
        1.2-i
        1 0-
        go^
        30.6-:
        >-o.4-;
        0.2-j
        0.0-3
        
        
        
        
        
        
        
        
        	 • •-;
        1 • • T 1 • • ' 1 • '
        
        
        
        
        
        
        
        
        V T T-T-1 -
        1 ' • ' 1 • ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' 1 ' '
        40 80 120 160 200 240 280 320 360 400
        Mass/Charee
        83 bis(2-Ethylhexyl)phthalate (PBM Reference Spectrum)
        .
        8.0-^
        
        ~ 6.0^
        34-°~
        >- '.
        2.0-
        
        
        
        
        
        
        
        
        I I . . 1, I 1 . .
        
        
        
        
        
        
        
        1
        40 80 120 160 200 240 280 320 360 400
        Mass/Charee
        Scan 2954 (25.341 min) of YP791.d (2 DIFFERENCE)
        100-:
        75-=
        504
        254
        fc 
        -------
        , ' •-•-;. :,vt!4Xlf
        Project Number: 43433
        Sample File: YP775
        Client Pi»|€^St]giA*rti-.MI -"'5;
        "". \ f "• . . v \ ""
        -. : : {-. -._£. v. "v.
        
        ,->: : "" ^J^|t^t>Vf%, ^
        ll A -.-s-, v^ ':-\«r^ v o. ^
        ; >\'$&J"Vi\ ^'"•••.^.C }\
        Wrt&^Vv*
        1 s ••- \ '•'•'•.*'
        . .A v ^\ . -s /•"•
        v- ""^ v ^'^ o\^l$-A:
        ;-"->-/ ,i- -^%;^
        !x^x ^ ^j^^l^
        ISt^;;
        \^~- *"*• ?<$ s %s> '
        ^^'^-.^ ^ S >X i
        Method 8270A MM5
        Sample ID: FBI-MM5-1
        \ V * -"f; *' -Oa& Eecftlved.: i
        ' V *• "• "^1. 1 "^ ""t ^lL%ik \
        Dilution Factor:
        «BBW;*^V*"
        11^7^ ^ *?
        idis^4 ^1
        1.00
        •••• -.-. %%^. >,>•"«*
        ' •. sx , •fv.tto^ %iy
        
        ^^fv;i
        
        
        *•**' '-.v^r:;>;>
        Naphthalene-d
        8
        Naphthalene
        2-Mediylnaphthalene
        Acenaphthene-d
        2-Chloronaphthalene
        Acenaphthylene
        Acenaphthene
        Fluorene
        Phenanthrene-d
        10
        Phenanthrene
        Andiracene
        Fluoranthene
        Chrysene-d
        ' 12
        Pyrene
        Benzo(a) anthracene
        Chrysene
        Perylene-d
        ' 12
        Benzo(b)fluoranthene
        Benzo(k)fluoranthene
        Benzo(e)pyrene
        Benzo(a)pyrene
        Perylene
        Indeno(l ,2,3-cd)pyrene
        Dibenz(a,h)anthracene
        Benzo(g,h,i)perylene
        -•"^IfllfSS
        IS 2
        5.85 BJ
        0.52 ]
        IS 3
        U
        U
        U
        U
        IS 4
        0.13 ]
        U
        U
        IS 5
        U
        U
        U
        IS 6
        U
        U
        U
        U
        U
        U
        U
        U
        p:.'.;:tw
        12.77
        12.81
        14.25
        16.42
        
        
        
        19.54
        19.59
        
        
        25.28
        
        
        29.41
        
        
        
        
        
        
        
        *u^v,/y;
        
        
        0.40
        0.25
        0.42
        0.41
        
        0.31
        0.29
        0.26
        0.30
        0.30
        0.24
        0.23
        0.22
        0.25
        0.23
        0.22
        0.29
        0.24
        i^?j
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
                                      NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc                                                                                            Savar v3.5
        801 Capitola Drive • Durham, North Carolina 27713                                                               Printed: 09:53 11/13/1997^
        

        -------
        Project Number 43433
        Sample File: YP775
                                                     Method 8270A MM 5
                                                 Sample ID: FBI-MM5-1
                                                      Dilution Factor:   1.00
        Phenol-d
        Nitrobenzene-d
        1,3,5-Trichlorobenzene-d
        1,4-Dibromobenzene-d
        2-Fluorobiphenyl
        2,4,6-Tribromophenol
        Anthracene-d
                   to
        Pyrene-d
        Terphenyl-d
         66.16
         61.74
         60.34
         68.04
         71.51
         92.50
         90.07
         86.70
        107.63
         9.45
        11.30
        11.98
        12.87
        15.01
        18.07
        19.66
        22.54
        22.90
        1
        2
        2
        1
        3
        3
        4
        5
        5
         66
         62
         60
         68
         72
         92
         90
         87
        108
        Reviewed by.
                                  NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                     Savarv33
                                                         Printed: 0953 11/13/1997
        

        -------
        S % s •• ' ^^ O N ^ ? ^1
        ! , •.^^ XN'^t v s '•»'$$?'' ••'
        Project Number: 43433
        Sample File: YP775
        Client Proj ech Saginaw, MI
        ' ^> >;*T>i
        ^ ; ^H?%^7 ^  ^ <•' •&.\ "•' ' - '•<«$'#' \s< ^\ 4*
        
        ^*^^ld^li£uS; ^''^'
        f^^^^£S!^f * "]<«
        *^ *• y^ *• ^ '% ^ yfe*''
        i •• ^J% VH ^&;
        Method
        Sample ID:
        Resjwmse File
        ^f:'; f f
        i^s^i
        8270A MM5
        FBI-MM5-1
        sYEjTlV:. I
        * % ^ V 's^
        Dilution Factor: 1.00
        
        , - ^-^ £ ,vS«^~~vt*i^
        „ v ^£6?t*v%$s
        1 ,4-Dichlorobenzene-d
        n-Nitrosodimediylamine
        Cumene
        Phenol
        Aniline
        bis-(2-Chloroethyl)ether
        Benzyl Chloride
        1 ,4-Dichlorobenzene
        2-Mediylphenol
        Acetophenone
        n-Nitrosomorpholine
        o-Toluidine
        Hexachlo methane
        1 ,2-Dibromo-3-chloropropane
        N.N-Diethylaniline
        Naphthalene-d
        3/4- Methylphenol
        Nitrobenzene
        N,N-Dimethylaniline
        Isophorone
        o-Anisidine
        1 ,4-Phenylenediamine
        1 ,2,4-Trichlorobenzene
        Hexachlorobutadiene
        a,a,a-Trichlorotoluene
        Hydroquinone
        f\> *^^$^^*™*JgZ£t'*^ •."•£•'££, x;u; '•-^•^i
        :SS^^^x5$^"fe\ v ^^
        IS 1 10.22
        U
        U
        3.22 J 9.47
        U
        U
        U
        0.43 J 10.26
        U
        3.78 BJ 10.99
        U
        U
        U
        U
        U
        IS 2 12.77
        U
        U
        U
        U
        U
        U
        U
        U
        U
        U
        
        1.44
        0.39
        
        0.52
        1.11
        0.40
        
        0.82
        
        1.44
        0.52
        1.35
        1.43
        0.49
        0.83
        0.52
        0.53
        0.44
        0.95
        0.69
        0.80
        1.37
        0.65
        0.71
        fffii
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
        IS: Internal Standard; U: Undetected; B:
        Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc.
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Savar v3.5
        Printed: 12:42 11/13/1997
        

        -------
        - , %" Y-"% ^ <•
        1 > - -,i-^*^"" -v.
        'reject Number: 43433
        Sample File: YP775
        nientProjecfc Sagirtaw,MI
        bu ID: 18&t7-lA-0 r *^> * s^\
        1 -,,-•• - ^ -v
        -i.% ,
        1
        \cV^ci&^^*o»«t|iil^t Sewiw
        •. •. ^f^- ^^X- X ^v. X %v ••"'' •••••*' % ^.
        
        ^
        Dilution Factor 1.00
        ,^^f||:;:^^'/-
        Method 8270A MM5
        Sample ID: FBI-MM5-1
        \ \\u^Ri%iti«e>^S^^P37tV^
        CV-N. / ^;^ ^:w\-^,- , i
        % %•. f"CSf»^ %%^* <.« $ % *\.\ *'^*m *v ^ N»^ '•
        - ^ - r\"-« * ,* \s ,SS*^^VV^ i
        
        
        r^r>'-^^S
        .-Chloroacctophenone
        Acenaphthene-d
        •lexachlorocyclopentadiene
        ~,4,6-Trichlorophenol
        2,4,5-TrichIorophenol
        liphenyl
        Dimediylphthalate
        1,4-Dinitrophenol
        1-Nitrophenol
        2,4-Dinitro toluene
        Dibenzoruran
        i,6-Dinicro-2-methylphenol
        Trifluralin
        'henanthrene-d
        10
        Di-n-butylphthalate
        Hexachlo ro benzene
        i-Amtnobiphenyl
        Pen tachlo ro phe nol
        'entachloronitrobenzene
        i-Nitrobiphenyl
        Chrysene-d
        ienzidine
        4,4'-Methylenedianiline
        Dimediylaminoazobenzene
        l,3'-Dimethylbenzidine
        3,3'-Dimethoxybenzidine
        §i^^g^f^
        U
        IS 3 16.42
        U
        U
        U
        U
        3.32 J 15.84
        U
        U
        U
        U
        U
        U
        IS 4 19.54
        3.41 BJ 20.78
        U
        U
        U
        U
        U
        IS 5 25.28
        U
        U
        U
        U
        U
        
        0.35 10
        1.34 10
        1.22 10
        1.06 10
        0.33 10
        10
        4.70 25
        1.79 25
        1.38 10
        0.30 10
        3.05 25
        2.22 10
        10
        0.88 10
        0.38 10
        1.68 25
        3.55 10
        0.96 10
        0.44 10
        1.02 10
        0.88 10
        0.55 10
        1.13 10
        NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
        IS: Internal Standard; U: Undetected; B:
        Present In Blank; J: Estimated- Below Quantitation
        Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        
        "01 Capitola Drive • Durham, North Carolina 27713
         'hone: (919) 544-5729 • Fax: (919) 544-5491
                     Savar v3.5
        Printed: 12:42 11/13/1997
        

        -------
        Project Number: 43433
        Sample File: YP775
                                                          Method 8270A MM5
                                                       Sample ID: FBI-MM5-1
        aient Project: Sagirtaw, MI
                                                     Dilution Factor:   1.00
                                                                    ^^^ttTTv.^ -
                                                                    JJ-V ' t^ *< Sl " '";<-
                                                                    "• <• -.v. •• --^ *  ^ %5 v
        3,3'-Dichlorobenzidine
        Methylcne bis-chloroanilinc
        bis(2-Ethy!hexyl)phthalate
                                                             U
                                                             U
                                                      21.61  B
                                                       0.74
                                                       1.68
                                    25.36
        10
        10
        10
        Reviewed by.
        Date   ll
                                  NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
            IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        801 Capitola Drive • Durham. North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                          Savar v3.5
                                                              Printed: 12:42 11/13/1997
        

        -------
        Data, file: /chem/Y.i/10-22-97.b/YP775.d
        Date-: 22-OCT-97 19:06
        Instrument : Y.i
        Sample ID : FBI-HH5-1
        Column phase : DB-5
        Volume Injected (uL) : 1.0
        
        Triangle Laboratories
        of RTF, Inc.
        Column diameter : 0.32
        
        
        Page 9 CO
        CD
        f
        . . r-
        
        /chem/Y.i/10-22-97.b/YP775.d (Part 1 of 2)
        6.6-i
        6.4-i
        6.2-;
        
        5.8-i
        5.6-;
        
        5.4-j
        5.2-i
        5.0-!
        4.8-i
        4.4-i
        4.2-!
        4.0-i
        3.8-1
        3f *
        .(>-.
        xx _ . !
         — ;
        0 -
        £V
        O Q)
        BB
        QQ
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        

        -------
           Data f,ile: /chem/Y.i/10-22-97.b/YP775.d
           Date < 22-OCT-97 19:06
           Instrument : Y,i
           Sample ID : FBI-H15-1
           Column phase : DB-5
           Volume Injected 
        -------
        Data File: /chem/Y.i/10-22-97,b/YP775.d
        Report Date:  23-Oct-1997  11:43
                                                                         Page 1
        Data file
        Lab. Id.
        Inj  Date
        Operator
        Smp  Info
        Misc Info
        Comment
        Method
        Meth Date
        Cal  Date
        Als  bottle
        Dil  Factor
        Integrator
        Sample  Type:
                        TRIANGLE LABORATORIES,  INC.
                     SEMI-VOLATILE  QUANTITATION REPORT
        /chem/Y.i/10-22-97.b/YP775.d
        43433
        22-OCT-97  19:06                 Autotune Date:  22-Oct-97 09:14:0
        DD                                Inst ID: Y.i
        FBI-MM5-1
        185-7-1A-D
        /chem/Y.i/10-22-97.b/cclist.m
        23-Oct-1997 11:29  target
        22-OCT-1997 11:59              Cal File: YP766.d
        13
        1.000                            Target  Version: Target   2.20
        HP  RTE                           Compound Sublist: pah.sub
         AIR
                                                                CONCENTRATIONS
          Compound*
        
        *  1 l,4-Dichlorobenzene-d4
        *  2 Naphthalene-d8
        *  3 Acenaphthene-dlO
        *  4 Phenanthrene-dlO
        •  5 Chzyiene-dl2
        *  6 Pezylene-dl2
        $  7 2-71uorophenol
        $  8 Phenol-dS
        $  9 2-Chlorophenol-d4
        $ 10 I*2-Dichlorobenzene-d4
        $ 11 Nitrobenzene-d5
        $ 12 l,3,5-Trichlorobenzene-d3
        $ 13 l,4-Dibromobenzene-d4
        $ 14 2-Pluorobiphenyl
        $ 15 2.4,6-Tribromophenol
        $ IS Anthracene-dIO
        $ 17 Pyrene-dlO
        $ 18 Terphenyl-dl4
          42 Naphthalene
          46 2-Methylnaphthalene
          50 2-Chloronaphthalene
          56 Acenaphthylene
          58 Acenaphthena
          65 rluorene
          73 Phenanthrene
          74 Antbr»c«n«
          77 Tluoranth«n«
          78 Pyr«n«
          83 Banzo(«)anthrmc*n*
          84 Chry««n«
          86 B«nzo(b)fluoranth*n«
        QUANT SIQ
        MASS RT (REL RT)
        152.00 10.220(1.000)
        136.00 12.767(1.000)
        164.00 16.419(1.000)
        188.00 19.543(1.000)
        240.00 25.280(1.000)
        264.00 29.409(1.000)
        Compound Hot Detected.
        99.00 9.453(0.925)
        Compound Hot Detected.
        Compound Hot Detected.
        82.00 11.300(0.885)
        185.00 11.983(0.939)
        239.80 12.867(1.259)
        172.00 15.010(0.914)
        329.80 18.070(1.101)
        188.00 19.665(1.006)
        212.00 22.537(0.891)
        244.00 22.902(0.906)
        128.00 12.810(1.003)
        142.00 14.247(1.116)
        Compound Not Detected.
        152.00 16^98(0.999)
        
        Compound Not Detected.
        178.00 19.593(1.003)
        
        
        202.00 22it90 (0 .0331
        Compound Hot Detected.
        Compound Hot Detected.
        Compound Not Detected.
        ON- COLUMN
        RESPONSE
        451015
        1574677
        905865
        1341363
        1210767
        1760521
        
        1265141
        
        
        921129
        810054
        748761
        2003232
        569785
        3183532
        3154323
        2534736
        241772
        13020
        
        fill 	
        
        4478
        
        
        	 14 OS
        
        
        
        ( ng)
        40.00
        40.00
        40.00
        40.00
        40.00
        40.00
        
        66.17
        
        
        61.73
        60.34
        68.06
        71.52
        92.51
        90.05
        86.70
        107.67
        5.85
        0.52
        9.J7 	
        
        
        0.13
        
        
        "0.04
        
        
        
        FINAL
        ( ug>
        
        
        
        
        
        
        
        66.17
        
        
        61.73
        60.34
        68.06
        71.52
        92.51
        90.05
        86.70
        107.67
        5. 85 (a)
        0.52(a)
        0 - 17 ( afl) x
        
        
        0.13(aQ)
        Qly
        
        O.IUlaU/
        
        
        
                                                                Data Review:
                                                                Date:
        

        -------
        Data File:  /chem/Y.i/10-22-97.b/YP775.d
        Report Date:  23-Oct-1997  11:43
                                                                                           Page 2
          Compound*
                                    QUANT SIO
                                      MASS
                                                 XT (RE. RT)
                                                                   COHCCHTRKrXOHS
                                                                 OH-COLOMH    FINAL
                                                          RESPONSE    (  ng)    (  ug)
          87 Benzo (k) f luoruthene
          88 Benzo (•) pyrene
          89 B«nzo (a) pyr«n«
          90 P«ryl«n«
          91 Ind«no(l,2,3-od)pyr*n*
          92 Dib«nz(«,h)»nthr»c«n«
          93 B«nio(g,h,i)p«ryl»n«
        
        QC  Flag  Legend
                                       Compound Hot D«t«ot»d.
                                       Coapound Hot Detected.
                                     252.00      29^*fl*4*T*O
                                     252.00
                                                             5925
                                              Hot D«t«ot*d.
                                       Conpound Hot Detected.
                                       Coapound Hot Detected.
        a  - Target  compound detected but,  guantitated amount
             Below Limit Of  Quantitation(BLOQ) .
        Q  - Qualifier  signal failed the  ratio test.
        

        -------
        Data File: /chem/Y.i/10-22-97.b/CAA/YP775.d
        Report Date:  23-Oct-1997  09:07
                                                                         Page 1
                                       TRIANGLE  LABORATORIES, INC.
        Data file
        Lab. Id.
        Inj  Date
        Operator
        Smp  Info
        Misc Info
        Comment
        Method
        Meth Date
        Cal  Date
        Als  bottle
        Dil  Factor
        Integrator
                                                                     REPORT
                     SEMI-VOLATILE  QUANTITATION
        /chem/Y.i/10-22-97.b/CAA/YP775.d
        43433
        22-OCT-97  19:06                Autotune Date:
        DD                                Inst ID: Y.i
        FBI-MM5-1
        185-7-1A-D
        22-Oct-97  09:14:0
        Sample  Type:  mm5
        /chem/Y.i/10-22-97.b/tlicaa.m
        23-Oct-1997 08:05  target
        22-OCT-1997 15:55              Cal File: YP771.d
        13
        1.000                            Target  Version: Target   2.20
        HP  RTE                           Compound Sublist:  CAAl.sub
                                                                CONCENTRATIONS
          Compound!
        
        *  1 1,4 Dichlorobenzene-d4
        *  2 Naphthalene-d8
        *  3 Acenaphthene-dlO
        •  4 Phenanthrene-dlO
        *  5 Chzy*ene-dl2
        •  6 Perylene-dl2
        $  7 2-Pluorophenol
        $  8 Phenol-dS
        $  9 2-Chlorophenol-d4
        $ 10 l,2-Dichlorobenzene-d4
        $ 11 Nitrobenzane-d5
        $ 12 l,3,S-Trichlorobenzene-d3
        $ 13 !<4-Dibromobenzene-d4
        $ 14 2-Fluorobiphenyl
        $ 15 2,4,6-Tribromophenol
        $ 16 Anthracene-dIO
        $ 17 Pyrene-dlO
        $ 18 Terphenyl-dl4
          20 n-Nitroaodimethylamine
          21 Cumene
          23 Phenol
          24 Aniline
          27 bia-(2-Chloroethyl)ether
          28 Benzyl Chloride
          29 1,4-Dichlorobenzene
          31 2-Methylphenol
          32 3/4-Methylphenol
          33 Acetophenone
          34 n-Nitroaomorpholine
          35 o-Toluidina
          36 Haxachloroathana
        QUANT SIO
        MASS RT (REL RT)
        152.00 10.220(1.000)
        136.00 12.767(1.000)
        164.00 16.419(1.000)
        188.00 19.543(1.000)
        240.00 25.280(1.000)
        264.00 29.409(1.000)
        Compound Hot Detected.
        99.00 9.453(0.925)
        Compound Hot Detected.
        Compound Hot Detected.
        82.00 11.300(0.885)
        185.00 11.983(0.939)
        240.00 12.867(1.259)
        172.00 15.010(0.914)
        329.80 18.070(1.101)
        188.00 19.665(1.006)
        212.00 22.537(0.891)
        244.00 22.902(0.906)
        74.00 t.73tfn ut62)
        Compound Hot Detected.
        94.00 9.475(0.927)
        
        Compound Hot Detected.
        146.00 10.255(1.003)
        
        108.00 11.370 (8.891) 	
        105.00 10.986(1.075)
        
        Compound Hot Detected.
        ON- COLUMN
        RESPONSE
        451015
        1574677
        905865
        1341363
        1210767
        1760521
        
        1265141
        
        
        921132
        810054
        748761
        2003232
        569785
        3183532
        3154323
        2534736
        22711
        
        50400
        
        
        6664
        
        	 ~2Tt 	
        64637
        
        
        ( ng)
        40.00
        40.00
        40.00
        40.00
        40.00
        40.00
        
        71.18
        
        
        60.26
        63.16
        68.70
        71.13
        103.80
        84.31
        77.62
        100.38
        	 3.27 	 .
        
        3.21
        
        
        0.42
        
        1 0.01
        3.77
        
        
        FINAL
        ( ug)
        
        
        
        
        
        
        
        71.18
        
        
        60.26
        63.16
        68.70
        71.13
        103.80
        84.31
        77.62
        100.38
        1 17- f D
        
        3.21
        
        
        0.42
        
        0.01
        3.77
        ~? F
        
                                                           Data Review:
                                                           Date:
        

        -------
        Data  File:   /chem/Y.i/10-22-97.b/CAA/YP775.d
        Report Date:  23-Oct-1997  09:07
                                                  Page  2
           Compounds
                                            QUANT SIO
                                               MASS
                                                             RT (REL RT)
                  CONCBNTRATIONS
                 ON-COLUMN      FINAL
        RESPONSE    (   ng)    (   ug)
           37 Nitrobenzene                       Compound Not Detected.
           38 N,N-Dimethylanilina             120.00       Ili3»7 10 . 882)	I5T5	OrO*	-O.08
           39 l,2-Dibromo-3-chloropropane         Compound Not Detected.
           40 Icophorone                       82.00       11.393(0.8911	mflS	Q-A9	n.AI,
           41 o-Ani«idine                        Compound Not Detected.
           42 1,4-Phenylenediamine               Compound Not Detected.
           43 1,2,4-Trichlorobenzene             Compound Not Detected.
           44 Naphthalene                     128.00       12.810(1.003)    241772       6.61       6.61
           46 Hexachlorobutadiene                Compound Not Detected.
           47 N,H-Diethylaniline              134.00       12_.J67 (1.2491    136919       s.ett	6. fin   f=-
           48 a,a,a-Trichlorotoluene             Compound Not Detected.
           49 Hydroquinone                    110.00
           51 2-Chloroacetophenone            105.00       13,»SS(1.03ir
           52 Hexachlorocyclopentadiene          Compound Not Detected.
           53 2,4, 6-Trichlorophenol              Compound Not Detected.
           54 2,4,5-Trichlorophenol              Compound Not Detected.
           60 Biphenyl                       154.00       IS . M3 (0 .01«)	STSS	0.09	0.88
           61 Dimethylphthalate               163.00       15.842(0.965)     86325       3.31       3.31
           62 2,4-Dinitrophenol                  Compound Not Detected.
           63 4-Nitrophenol                   139.00       M1613 (1.013)  	1479 	81*6	*-.2f~
           64 2,4-Dinitrotoluene              165.00       1^411C1  """?	119891	•	16.J8	16^38
           65 Dibenzofuran                       Compound Not Detected.
           66 Di-n-butylphthalate             149.00       20.776(1.063)    175808       3.41       3.41
           67 4, 6-Dinitro-2-methylph.no!      198.00       1&-J63 (1.1881	3«W	9-r«2	B-rW
           68 Trifluralin                        Compound Not Detected.
           69 Hexaehlorobenzene                  Compound Not Detected.
           70 4-Aainobiphenyl                    Compound Not Detected.
           71 Pentachlorophenol                  Compound Not Detected.
           72 Pentachloronitrobenzene            Compound Not Detected.
           73 4-Nitrobiphenyl                    Compound Not Detected.
           74 Benzidine                      184.00       22.537(0.8911     31568,
           75 4,4'-Hethylenedianiline            Compound Not Detected.
           77 Dim.thylaminoazob.nz.il.         120.00       23-r902 (0.89O—   488*5       3.Si	3 .52.
           78 3,3'-Dimethylb.nzidin.             Compound Not Detected.
           80 3,3'-Dimethoxybenzidine            Compound Not Detected.
           81 3,3' -Dichlorobenzidine             Compound Not Detected.
           82 Methylene bia-chloroaniline        Compound Not Detected.
           83 bi«(2-Kthylh.xyl)phthalat.      149.00       25.359(1.003)    617438      21.61       21.61
                                     f P ACCtJ-
        

        -------
         Data File:  /chem/Y.i/10-22-97.b/YP775.d
         Date : 22-OCT-97 19:06
         Instrument  :  Y.i
         Sample ID : FBI-MH5-1
         Column phase  :  DB-5
         Volume Injected 
          : 1.0 42 Naphthalene Page 11 Column diameter : 0.32 Scan 1218 (12.810 min) of YP775.d 1.4-i 1.2-i i.o-i £>0.8-i ^0.6-i XX 0.2-i ..I...I. il. ll .. Mill ..... . . .1 ... 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charee 1 A- l.*f . 1.2-i 1.0-i £0. 8- 30.6-i ^0.4- 0.2- 0.0- Scan 1218 (12.810 min) of YP775.d (Subtracted) 1 .1 i, • i ,-• i • 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charee 42 Naphthalene (PBM Reference Spectrum) • 8.0: s6'1 3 4.0: >. 2.0- 0.0- ,. i' i' -i'l I'i'i • • • 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charee Scan 1218 (12.810 min) of YP775.d (Z DIFFERENCE) 100-: 75": 50-j 25-! . i «£ . s-25-i **-50-j -754 100- '•' '' ' '''I' ' 'I'1'1 1' ' ' 40 50 60 70 80 90 100 110 120 130 140 150 Mass/Charee Mass 128.00 1.4: 1.2- 1.0- |o.8: So.6- >. 0.4- 0.2: 0 0- !S CJ 7 A L OO * a 12.40 12.60 12.80 13.00 13.20 Time (min.) Mass 129.00 1.6-j 1.4: 1.2-i 1.0- XX o0.8-i X XX . ^0.6- 0.4: 0.2: 0 0- 1 JH a II i-4 , 8 ^ 1 y A 1. , 12.40 12.60 12.80 13.00 13.20 Time (min.) Mass 127.00 1.8-i 1.6- 1.4- XX • ri.o^ o £0.8- ^0.6-i 0.4-; 0.2^ 0 0- |~? I a* O ro OJ 1 " , A 1 1 1 A /v A , lly^ » 12.40 12.60 12.80 13.00 13.20 Time (min.)

        -------
           Data File: /che»/Y.i/10-22-97.b/YP775.d
           Date : 22-OCT-97 19:06
           Instrument : Y.i
           Sample ID : FBI-MM5-1
           Column phase : DB-5
           Volume Injected  of YP775.d
          8.0-
          2.0-
              4
                40   50   60    70   80   90   100  110   120  130   140  150  160   170
                     	Mass/Charge	
                         Scan 1420 (14.247 min)  of YP775.d  (Subtracted)
        8.0-
        6.0-
          0.0-
                          -MW,
        k
                40   50    60    70   80    90   100  110   120  130   140  150  160   170
               	Mass/Charge	
                          46 2-Methylnaphthalene (PBM Reference Spectrum)
          8.0-
        
        
        |4.0-
        
        ""2.0-
        
          0.0-
              ll,,,,,!!,,,',,!!.,,!',!!!',,,,,',!.
                40   50    60    70   80    90   100  110   120  130   140  150  160   170
               	Mass/Charge	
          100
           75
           50
           25
        £  0
        «-25
        ~-50
          -75
         -100
                        Scan 1420 (14.247 min) of YP775.d  (Z  DIFFERENCE)
                40   50    60   70    80    90  100   110   120   130   140  150  160   170
               	Mass/Charge	
                                                                                                     Mass 142.00
                                                                                         9.0
                                                                                         8.0
                                                                                         7.0
                                                                                         6.0
        
                                                                                       3^.0:
        
                                                                                         2.0-i
                                                                                         1.0-
                                                                                           0.0
                                                                                               13.80 14.00  14.20  14.40 14.60
                                                                                              	Time (min.)	
                                                                                           9.0r
                                                                                           8.0-i
                                                                                           7.0-i
                                                                                           6.0-!
                                                                                         S4.0^
                                                                                         2-°1
                                                                                         l.Or
                                                                                                       Mass 141.00
                                                                                         0.0^
                                                                                             13.80 14.00  14.20 14.40 14.60
                                                                                                     Time (min.)	
        

        -------
         Data File: /chem/Y.i/10-22-97.b/YP775.d
         Date : 22-OCT-97 19:06
         Instrument :  Y.i
         Sample ID : FBI-MM5-1
         Column phase  :  DB-5
         Volume Injected (uL> : 1.0
        73 Phenanthrene
                                                    Page 15
        Column diameter :  0.32
        Scan 2171 (19.593 min) of YP775.d
        .
        8.0-|
        :
        fn * •
        34-°-
        *"2.0:
        
        
        
        
        
        
        ll
        III ill i ill III 1 him ih i ii 1 1 ii
        juu, — i I" 'i — P-H1 — i" 1 	 i1 "i 1 — i ' I ' 'I 'i1 i 1 I i~^ i 1
        
        
        I I
        
        ll
        ' ' I
        40 60 80 100 120 140 160 180
        Mass/Charee
        -
        3.2-i
        2 8-
        fc.O .
        2J -
        .4-
        fo2.0-|
        S1.6-!
        
        ^o'.a-i
        
        0»4-i
        
        Scan 2171 (19.593 min) of YP775.d (Subtracte
        
        
        
        
        
        
        1 i
        i ii i
        ll
        , ill llllll 1 ll , ,1 .1 1,
        d)
        
        
        
        
        
        
        
        
        
        ,
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        ,,
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        40 60 80 100 120 140 160 180
        Mass/Charge
        73 Phenanthrene (PBM Reference Spectrum)
        
        8.0:
        6 0-
        P> '
        <
        34.0-
        j.
        2.0-
        0 0-
        i
        
        
        
        
        
        ,
        
        . , , ,,l ,ll . Ill .
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        40 60 80 100 120 140 160 180
        Mass/Charee
        100-
        75 -1
        50-i
        25-i
        
        s-25-i
        ~-5o4
        -75-i
        
        Scan 2171 (19.593 min) of YP775.d (Z DIFFERD
        
        1
        n 1 1 i
        .. ll Jl, ,,lll ,|| 1, 1 k 	 1 i, 1
        ICE)
        
        
        
        -i
        
        
        
        
        
        
        
        
        
        
        
        
        
        40 60 80 100 120 140 160 180
        Mass/Charee
        
        
        
        
        
        
        
        
        
        
        200
        
        
        
        
        
        
        
        
        
        
        
        
        200
        
        
        
        
        
        
        
        
        
        
        
        200
        
        
        
        
        
        
        
        
        
        200
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        Mass 178.00
        2.8-j
        2.5-1
        2.2-i
        2.0-j
        fo1*^
        i ID
        n *
        
        r
        
        
        3*1 ||^
        ^i!o-j
        0.8--
        0.5-1
        0.2-!
        0 0-
        
        
        
        
        i .
        lv_l
        1 1
        1 II
        11
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        Mass 179.00
        1.8:
        
        1.6-
        1.4-
        
        "
        1.2:
        -1.0-^
        2 :
        3°*8"
        ^0.6:
        0.4:
        0.2:
        •
        0 0-
        
        
        ro
        in
        
        *~* II
        i |||
        1 1 1
        1 | HI
        |
        || |
        11 111 1
        || 1 1 1] |
        III III
        III 1 1 1 II III
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        Mass 176.00
        1.4-
        1.2-
        1.0-|
        ^0 j
        <° * :
        'xO.6-
        ^ * :
        o.4:
        0.2-j
        
        0 0-
        
        
        
        
        
        
        
        
        
        
        
        ~s?
        r-t
        
        
        
        
        1
        1
        ft
        
        II
        19.20 19.40 19.60 19.80 20.00
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-22-97.b/CfWYP775.d
         Date : 22-OCT-1997 19:06
         Instrument :  Y.i
         Sample ID : FBI-MM5-1
         Column phase  : DB.5-625
         Volume Injected _
        2.0-
        0.0-
        
        
        
        
        
        
        1 , I
        ill Jlh ,1,1 .
        I . 1 1 1 1 . , 1 . .
        
        
        
        
        
        
        
        
        
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        Scan 749 (9.475 nin> of YP775.d (Z DIFFERENCE)
        100-
        :
        75-j
        50-i
        £2°j
        S-25-:
        *< -
        -50-E
        -75-j
        100 :
        
        
        
        
        -ir''(r'"n" '"' r 	 -'*' '"
        1
        . ill .. 1 . \— M . 1
        
        
        
        
        
        40 60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        Mass 94.00
        3.6H
        •
        3.2-j
        2.8-i
        2.4-i
        
        g2.0-j
        2ii
        0 8-
        v*o t
        0.4T
        0.0-
        
        
        
        
        
        
        
        
        
        
        
        j
        i ' • • i * • • i •
        ~R
        •*
        ON
        
        
        
        
        
        
        
        
        IY * +
        
        9.00 9.20 9.40 9.60 9.80
        Time (min.)
        Mass 65.00
        
        1.2-j
        1.1-i
        
        1.0-
        0.9-j
        0.8-j
        
        ^06-
        20.5-
        »- 0.4-1
        0.3-
        0.2-
        0.1-
        1— -4f)
        1 •&
        5
        
        
        
        
        
        
        
        
        
        
        A A M n 1
        
        
        
        
        
        
        
        
        Li k ** rt A
        9.00 9.20 9.40 9.60 9.80
        Time (min.)
        Mass 66.00
        3.6-3
        3.2-1
        
        2.8-i
        !
        2.4-;
        
        52.0-j
        S^j
        ;
        0.8-^
        -
        0.4^
        0.0-
        r^.
        II ^
        
        
        
        
        
        
        
        
        
        
        
        1 f
        
        
        
        
        
        
        
        
        
        
        i
        . )t . . 4 ...,«.,
        9.00 9.20 9.40 9.60 9.80
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-22-97.b/Cfifl/YP775.d
         Date : 22-OCT-1997 19:06
         Instrument :  Y.i
         Sample ID : FBI-MM5-1
         Column phase  :  DB.5-625
         Volume Injected 
          : 1.0 29 1,4-Dichlorobenzene Page 9 Column diameter : 0.32 Scan 859 (10.255 min) of YP775.d 6.0-^ 5.0-i xx4.0-i I3'°i 1.0-j 0.0J 4 illlllllnfl 10 80 120 1 1 160 200 240 280 320 360 400 Mass/Charge 4.0: .3.0- ro S2 0- x *w XX "1.0- 0.0- t Scan 859 ( 111 tO 80 120 10.255 min) of YP775.d (Subtracted) 1 1 160 200 240 280 320 360 400 Mass/Charge 29 1,4-Dichlorobenzene (PBM Reference Spectrum) - 8.0: 3 4.0- ^2.0-J 0.0- „ ,..!,. 1,.. 40 80 120 * 160 200 240 280 320 360 400 Mass/Charee 100-q 75-^ 50-= 251 S-25-! "*-50r -75-: -100- Scan 859 (10.255 min) of YP775.d « DIFFERENCE) L , ,|i l| I 1 f 40 80 120 160 200 240 280 320 360 400 Mass/Charee Mass 146.00 4.4-i 4.0-; 3.6-i 3«2i 1.2-i 0.4-! 0.0-3 9 118 ^ J .80 10.00 10.20 10.40 10.60 Time (min.) Mass 148.00 2.8-j 2.5-i 2.2-! 2.0-j 1.8-1 5s 1.5-1 O - x 1*2~ x-l.Or 0.8H 0.5H 0.2-: 0.0J c ' .80 10.00 10.20 10.40 10.60 Time (min.) 8.0-i 7.0-i 6.0-i 5 0-: <° : XX 2.0-: - 0.0-: c Mass 113.00 § ,,,,,... .P. .i^... .4 1.80 10.00 10.20 10.40 10.60 Time (min.)

        -------
         Data File: /che»/Y.i/10-22-97.b/CflA/YP775.d
         Date : 22-OCT-1997 19:06
         Instrument : Y.i
         Sample ID : FBI-MM5-1
         Column phase :  DB.5-625
         Volume Injected 
        
        
        
        
        
        ,
        40 50 60 70 80 90 100 110 120
        Mass/Charee
        100-:
        75 -j
        50-i
        25-
        t. f\^
        <£ ^
        3-25-i
        *4
        -50-j
        -75-
        Scan 962 (10.986 min) of YP775.d (Z DIFFERENCE)
        
        
        
        .1. , 	 ,i 	 1 	
        
        
        
        40 50 60 70 80 90 100 110 120
        Mass/Charee
        
        1.4:
        l.O:
        
        go.8-:
        306^
        >• ' :
        0.4:
        
        0.2:
        0 0-
        Mass 105.00
        
        
        
        fo
        ^0 [o
        'o *H .
        A Sx ^^
        A • li ^
        s ft * ;
        AjtHAl
        
        
        
        
        
        
        
        
        
        
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        Mass 77.00
        1
        1.1-:
        
        i.o-i
        0.9^
        
        0.8-!
        
        •^ :
        ^0.6^
        ^o'Ji
        0.3^
        0.2-i
        0.1-j
        I
        
        r**- II
        a
        ^* I
        i
        i
        I
        |
        -
        °^
        - s
        S '
        0* |
        ,,n,/ui
        
        
        
        
        
        
        
        
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        Mass 120.00
        Q 0-
        o.v .
        7.0^
        6.0-j
        5.0-j
        fo :
        ^< * :
        ^3 0-
        *"2'0j
        
        1.0-=
        0 0-
        ^?
        »
        . s
        r*^ ^^
        ro
        CO
        *
        o
        1
        1
        
        
        II <5
        1 "^ '-'
        i ^
        1 ^H 1
        .1 1 1 flu
        10.60 10.80 11.00 11.20 11.40
        Time (min.)
        

        -------
         Data File: /chem/Y.i/10-22-97.b/QWYP775.d
         Date : 22-OCT-1997 19:06
         Instrument :  Y.i
         Sample ID : FBI-MM5-1
         Column phase  :  DB.5-625
         Volume Injected (uL> : 1.0
        61 Dimethylphthalate
                                                    Page 22
        Column  diameter :  0.32
        Scan 1644 (15.842 min) of YP775.d
        5.0-d
        
        4.0:
        
        ^3.0-
        o :
        32*°J
        
        *~1 0-
        
        
        
        
        
        
        
        
        
        , ,1
        lLl.ll.-ii
        '
        
        
        
        
        
        
        
        
        1 , 	
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        Scan 1644 (15.842 min) of YP775.d (Subtracted)
        5.0H
        
        4.0-
        g3.0:
        §2.0:
        ~ :
        1.0-
        0 0-
        
        
        
        
        
        
        I
        -iAl 	 i
        
        
        
        
        
        
        
        1 , 	
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        61 Dimethylphthalate (PBM Reference Spectrum)
        J
        8.0:
        
        xv 6.0-
        ro
        j_
        •$ 4.0:
        >_
        2.0-
        0 0-
        
        
        
        
        
        
        
        
        , L ii , ,i
        
        
        
        
        
        
        
        .
        1
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        Scan 1644 (15.842 win) of YP775.d (2 DIFFERENCE)
        100-
        75-i
        50-i
        25-
        fc 0-
        S-25-
        "-50-
        -75-
        
        
        
        
        r*—^ L- ^ r*. •- . ^ L .f . .. r • L i • i i * .
        
        
        40 80 120 160 200 240 280 320 360 400 440 480
        Mass/Charee
        Mass 163.00
        d
        4.Q-.
        4.4-.
        4.0^
        3.6-;
        7 2-=
        w*fc .
        52.8-i
        I2-4"!
        *" 1 C. -
        l.b-
        1.2-i
        0 8-^
        V.Q .
        0.4-1
        0 0-
        I "*
        
        11 ^~*
        
        
        
        
        
        
        
        
        
        
        »**
        
        
        
        
        
        
        
        
        
        
        f\. r-*
        15.40 15.60 15.80 16.00 16.20
        Time (min.)
        2.4-
        2.2-j
        2.0-=
        1.8-=
        1.6-^
        ^1.4-j
        ^1.2-:
        3 i.o^
        =-0.8-!
        0.6-!
        0.4^
        0.2-!
        
        0 0-
        Mass 194
        
        
        
        
        
        
        
        
        
        
        
        
        
        .00
        oo
        in
        'H
        
        
        
        
        
        
        1
        
        1
        I
        . . . 1 . ...
        15.40 15.60 15.80 16.00 16.20
        Time (min.)
        4J —
        *^—
        4.0-i
        
        3.6-
        3.2-f
        2.8^
        <^ .
        
        32.0-!
        >-i.6-i
        0.8-;
        0.4-i
        Mass 164.00
        I— CJ
        1 s
        
        
        
        
        
        
        
        I
        1 i
        1 ll
        a
        
        
        
        
        
        
        
        i ii ii
        y
        15.40 15.60 15.80 16.00 16.20
        Time (min.)
        

        -------
         Data File:  A*en/^. i/10-22-97.b/Cflfl/YP775.d
         Date : 22-OCT-1997 19:06
         Instrument  :  Y.i
         Sample ID : FBI-MM5-1
         Column phase  :  DB.5-625
         Volume Injected 
          : 1.0 66 Di-n-butylphthalate Page 25 Column diameter : 0.32 Scan 2337 (20.776 min) of YP775.d 8.0- 6.0: ^ 34.0- X XX "2.0- 0 0- .jltl. jl,lLi..l,ULl_jJ.^lJj_Jl li. i • i i i 40 60 80 100 120 140 160 180 200 220 240 260 Mass/Charee Scan 2337 (20.776 min) of YP775.d (Subtracted) 8.0- . 6.0: 34.0- -X. "2.0- 0 0- L .1 .. i. • ---.- . . i 40 60 80 100 120 140 160 180 200 220 240 260 Mass/Charge 8.0: -.6.0- ro • 3 4.0- XX *~2.0: 66 Di-n-butylphthalate . •.I.. ,...ll i i. i li i.. (PBM Reference Spectrum) 1 II 40 60 80 100 120 140 160 180 200 220 240 260 Mass/Charee Scan 2337 (20.776 min) of YP775.d (2 DIFFERENCE) 100- • 75- 50-i 251 £ H »-25-: "*-50-j -75-1 100 : i 40 60 80 100 120 140 160 180 200 220 240 260 Mass/Charge Mass 149.00 9.0-d 8.0-i 7.0-! 6.0-i -~5.0- |4.0-| =-3.0^ 2 0- fc*" . i.o-: 0.0^ ips Is j u. ...... 20.40 20.60 20.80 21.00 21.20 Time (min.) Mass 150.00 9.0^ 8.0-; 7.0-^ 6.0-i N>5.0-: o - ^4.0- XX 2.0-i 1.0-f 0 0- • I At , A H i/ 20.40 20.60 20.80 21.00 21.20 Time (min.) Mass 104.00 6.04 5.5-j 5.0-1 4.5- 4.0-i p;3.5- o3.0- 32.5- *-2.0- 1.5| i.o-IL J 0.5|U 1 | ~o8 § L 1 1 11 iiu 20.40 20.60 20.80 21.00 21.20 Time (min.)

        -------
         Data File: /chem/Y.i/10-22-97.b/CAA/YP775.d
         Date : 22-OCT-1997 19:06
         Instrument : Y.i
         Sample ID : FBI-MM5-1
         Column phase : DB.5-625
         Volume Injected (uL) :  1.0
        83 bis(2-Ethylhexyl)phthalate
                                                      Page 29
        Column diameter :  0.32
        
        :
        2.0-1
        1.8-i
        
        1.5-i
        £1.2-=
        < :
        I 0*"
        *o.e-i
        *-0.5-j
        0.2-j
        0.0J
        
        
        
        
        
        
        
        
        1
        1
        .«, , •)!
        Scan 2979 (25.359 min) of YP775.d
        
        
        
        
        
        
        
        
        
        II
        ..JI-L -1- • 1. • 	 .-
        
        
        
        
        
        
        
        
        
        
        i i
        40 60 80 100 120 140 160 180 200 220 240 260 280
        
        
        2.0-j
        i a-=
        * :
        1C "
        •51
        £l.2-i
        Sl.O-i
        *0.8H
        ^0.5-j
        0 2-=
        V*£. •
        0.0-3
        
        
        
        
        
        
        
        .
        .
        1
        
        
        Mass/Charee
        Scan 2979 (25.359 min) of YP775.d (Subtracted)
        
        
        
        
        
        
        
        
        
        11 ,
        
        
        
        
        
        
        
        
        
        
        
        
        i i i i | i i i | i i i i i i i | i ., ... ,...,...,...,...,...,
        40 60 80 100 120 140 160 180 200 220 240 260 280
        
        
        8.0-j
        
        ~6.0-
        g i
        J4.0-
        >-
        2.0-
        0 0-
        
        
        
        
        
        
        |
        1 i
        Mass/Charee
        83 bis(2-Ethylhexyl)phthalate (PBM Reference Spectrum)
        
        
        
        
        
        
        ll
        . . JL 1, i. ll .. .
        
        •
        
        
        
        
        
        1
        40 60 80 100 120 140 160 180 200 220 240 260 280
        
        
        100-
        75-j
        50-j
        254
        sr o4
        3-25-j
        -754
        
        
        
        
        Mass/Charee
        Scan 2979 (25.359 min) of YP775.d (Z DIFFERENCE)
        
        
        -
        
        -v -i 	 if 	 - •-• •• •" 	
        
        
        40
        
        
        
        60 80 100 120 140 160 180 200 220 240 260 280
        Mass/Charee
        Mass 149.00
        2.2-
        2*°-i
        
        1.8-j
        
        1.6-j
        1.4-j
        £1.2-1
        Sl.O-
        •2 :
        0.6-!
        0.4-j
        0.2H
        0.0^
        
        
        
        
        
        
        
        
        
        
        
        
        
        -i— ~*t— < J-
        ~~LO
        3
        CM
        
        
        
        
        
        
        
        
        
        
        U ,—
        . . 1 1 . 1 1 1 1 1 1 . . . 1 . . , , .
        25.00 25.20 25.40 25.60 25.80
        Time (min.)
        Mass 167.00
        6.0-
        5.5J
        5.0-
        4.5-j
        
        4.0-i
        
        x>. 3.5-
        ^3.0-:
        32.5-
        1.5-
        1.0-
        0.5-
        0.0-
        J-£
        i '°-
        sa
        
        
        
        
        
        
        
        
        
        
        
        
        1
        
        
        
        A. f f ., V M. - /• r
        
        25.00 25.20 25.40 25.60 25.80
        Time (min.)
        
        
        
        
        
        
        
        
        
        
        
        
        
        
        

        -------
                                                  .V^ ?\C'v' ~" "< V&V *" '  t
        Project Number 43433
        Sample File: YP774
                       Method 8270A MM5
        Sample ID: LAB BLANK-MM5-28
        Client Project: Sagittaw^ MI ' '^'
        " ' * ^
        
        
        " '' V >* ,*',.* *V^ *«' \% ^' \X
        Naphthalene-d
        Naphthalene
        2-Mcthylnaphthalene
        Acenaphthene-d
        2-Chloronaphthalene
        Accnaphthylene
        Acenaphthene
        Fluorene
        Phenanthrene-d
        10
        Phenanthrene
        Anthracene
        Fluoranthene
        Chrysene-d
        Pyrene
        Benzo(a)anthracene
        Chrysene
        Pcrylene-d
        Benzo(b)fluoranthene
        Benzo(k)fluoranthene
        Benzo(e)pyrene
        Benzo(a)pyrene
        Perylene
        Indeno(l ,2,3-cd)pyrene
        Dibenz(a,h)anthracene
        Benzo(g,h,i)perylene
        : *: Dati Received: 09/29/97 .
        ;° '/^^^l&^
        Dilution Factor: 1.00
        
        
        IS 2 12.76
        U
        U
        IS 3 16.42
        U
        U
        U
        U
        IS 4 19.55
        U
        U
        U
        IS 5 25.28
        U
        U
        U
        IS 6 29.40
        U
        U
        U
        U
        U
        U
        U
        U
        ;>\;^^M(K»ifelita:
        ijx* ^''""" v^
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
        10
                                 NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
            IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax (919) 544-5491
                                       Savarv3.5
                           Printed: 09:53 11/13/1997
        

        -------
        I
         Project Number 43433
         Sample File: YP774
                                                                                             Method 8270A MM5
                                                                               Sample ID: LAB BLANK-MM5-28
        Clien
             NlDt
                                w, MI
                                                   i-^XiST \ V  .""*•  \  "• ••  '  .   -. \ S\s..  -Xs •• x*s •» v* % •?^'.xv^s        ^  % "^\t^
                                                   J^J&fati^lMMX;;    '   ;_ -:«r   _ v,\"-:» ^f
        I
                                                    Dilution Factor:    1.00
        s ^ ' V ' -'' \ C^ % '* % ^-.^ s "%% ' "
        Sitttto04ie SttaiiftSiiijf, ^ \ v % •* ^ % 'f* -A
        - " ^ ; / -...5...
        Phenol-d
        5
        Nitrobenzene-d
        5
        1 ,3i5-Trichlorobenzene-d
        3
        1 ,4-Dibromobenzene-d
        4
        2-Fluorobiphenyl
        2,4,6-Tribromophenol
        Anthracene-d
        10
        Pyrene-d
        ' 10
        f %J. ^ ^ \
        feSHS.-.
        69.13
        
        74.18
        
        62.82
        
        74.39
        
        71.68
        91.27
        91.72
        
        97.11
        * % "" ' RT -
        5 ' «V* * 4 •• *
        , *. - \
        ','-. *$.-. 5
        9.45
        
        11.29
        
        11.98
        
        12.87
        
        15-01
        18.07
        19.66
        
        22.54
        ^XSBfcC^
        1
        
        2
        
        2
        
        1
        
        3
        3
        4
        
        5
        •&t^\ ' » -%'%K!3C% v :
        % ^ % \ * ^ % < •, s ,\\ ;
        69
        
        74
        
        63
        
        74
        
        72
        91
        92
        
        97
         Reviewed by.
                                             Date  11  /
                                 NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
         Triangle Laboratories of RTF, Inc.
         801 Capitola Drive • Durham, North Carolina 27713
         Phone: (919) 544r5729 • Fax: (919) 544-5491
                                                                                                             Savar v3.5
                                                                                                 Printed: 09:53 11/13/1997
        

        -------
        - , V //;:<;,/ x, " l^itV C
        % <• \ *• .. ' % - W* ^ :|L*$. s^sr ^ 1^^->^|^
        T^-?^^l!*;w*II?:t5o^^'7^\^*^
        ,vV:iy °^Vs4Vv^
        ^;^fx^i§8S>^
        !lAT^g|f^ I i
        v %VxS?!^'"^ \%\>vW \>Nv% ^ %
        Method 8270A MM5
        
        Dafeleceived: 0^29/97
        ; 'P^^fi^ei 48m$5
        Sample ID: LAB
        > , ,^f^R^^HW«
        "^ "^•%^?* * -.''^ •• '"*
        '/.'^'J^.V ^
        BLANK-MM5^28
        s^feYFra,:^ - I
        5' ^4-V •• **s ''''^' -^" '
        1 5t^ ^SM, i
        Dilution Factor: 1.00
        
        ArialyW \ , , -" < .. ,\ ;* ^-; \* - ™:\ ^7^
        ,;- s "\-" ^ ^ ^ ;% ° Kft^UiS
        1 ,4-Dichlorobenzene-d
        n-Nitrosodimethylamine
        Cumene
        Phenol
        Aniline
        bis-(2-Chloroethyl)ether
        BenTyl Chloride
        1 ,4-Dichlorobenzene
        2-Mediylphenol
        Acetophenone
        n-Nitrosomorpholine
        o-Toluidine
        Hexachloroethane
        1 ,2-Dibromo-3-chloropropanc
        N,N-Diethylaniline
        Naphthalene-d
        3/4-Methylphenol
        Nitrobenzene
        N,N-Dimethylaniline
        Isophorone
        o-Anisidine
        1 ,4-Phenylenediamine
        1 ,2,4-Trichlorobenzene
        Hexachlorobutadiene
        a,a,a-Trichlorotoluene
        Hydroquinone
        ..^ f. jfit+.t'^^l'\-w' *f£f AJ^' % ^ ""•'•" 'J *** s/ j>**y •,
        fjlf ^•y^jl fxi v |* • . y iyujT^rM*" ^ "• •* v \"3f^ 
        -------
        I
        5.-5J -.-.  «*   vv./^ V^™
         ^ ;->-  *  >,(^ s •.  .* .:'?.3tt.\'._.?.\.-.
        Pfcciifcl
        Rjr||^rUal JSemces, ^>v^^>^Xv|?^\^M§^v,f f&i
          •* \v% *  %^     ^ ••       x -* v vy>».'S. x^ \^ >•: *>. iS-^>^j *&.'•£.•?...' ^ '  :
         Project Number: 43433
         Sample File: YP774
                                                                             Method 8270A MM5
                                                              Sample ID: LAB BLANK-MM5-28
        Client Project: Sagirta>
        [IU ID: l£5-7-6A«€^ ;?
        " " '%t|?
        1
        
        ' •• •• ••^•^
        p* ^ ^ ^^^
        2-Chloroacetophenone
        Acenaphthene-d
        Hexachlorocyclopentadiene
        2,4,6-Trichlorophenol
        2,4,5-Trichlorophenol
        Biphenyl
        Dimediylphthalace
        2,4-Dinitrophenol
        4-Nitrophenol
        2,4-Dinitrotoluene
        DibenzoFuran
        4,6-Dinitro-2-methylphenol
        Trifluralin
        Phenanthrene-d
        10
        Di-n-butylphthalate
        Hexachloro benzene
        4-Arninobiphenyl
        Pentachlorophenol
        Pentachloronitrobenzene
        4-Nitrobiphenyl
        Chrysene-d
        Benzidine
        4,4'-Methylenedianiline
        Dimediylaminoazo benzene
        3,3'-Dimethylbenzidine
        3,3'-Dimethoxybenzidine
        '^Ml-/-\ fe, DklK««6lvea 1&&19SF - ; V " *!
        •*' "--r f % •* .. ''^t J1- <• ^i? t X*.S s^ •- "" % <
        ^;;g^v v^^l^j^W^ VS- \
        }>,; /4, &r* ^ -- P^ jygpBj^d'? "J&fi&t^ , : ;^ ; x x ;
        Dilution Facton 1.00
        
        : ^ ', '-£\ rAJ^a^^ ^MAd^—^'^RT' f^- -^0A
        ';^^%^; ^ - v^v .^.;..*. % V ^..^
        U
        IS 3 16.42
        U
        U
        U
        U
        1.14 J 15-84
        U
        U
        U
        U
        U
        U
        IS 4 19.55
        
        29.02 B 20.78
        U
        U
        u
        u
        u
        IS 5 25.28
        U
        U
        U
        U
        U
        ieSp^nseiPIiei"
        ^t'Llvtx^
        "*^:5§™*o >'4$R
        
        
        tiMt^ ^---^C
        a^:.xsN»/:lxC
        0.41
        
        1.44
        1.31
        1.14
        0.36
        
        5.05
        1.93
        1.48
        0.32
        3.27
        2.39
        
        
        
        0.96
        0.41
        1.82
        3.84
        1.04
        
        0.54
        1.26
        1.08
        0.67
        1.39
        &m^y?N
        ^^Y
        ^^^>x
        
        
        i««a*I^wlt ]
        \..:.^i... : 1
        10
        
        10
        10
        10
        10
        10
        25
        25
        10
        10
        25
        10
        
        
        10
        10
        10
        25
        10
        10
        
        10
        10
        10
        10
        10
                                  NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
             IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
         Triangle Laboratories of RTF, Inc.
         801 Capitola Drive • Durham, North Carolina 27713
         Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                              Printed:
                                                                                             Savarv3.5
        

        -------
        Project Number 43433
        Sample File: YP774
                                                                      Method 8270A MM5
                                                       Sample ID: LAB BLANK-MM5-28
                                                     Dilution Factor:   1.00
        3,3'-Dichlorobenzidine
        Methylenc bis-chloroanilinc
        bis(2-Ethylhexyl)phthalate
                                  U
                                  U
                             1.19  BJ
                           0.91
                           2.06
        25.35
        10
        10
        10
        Reviewed by.
        ^ClU"    Date »l
                                 NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
            IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
        Triangle Laboratories of RTF, Inc
        801 Capitola Drive • Durham, North Carolina 27713
        Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                      Savar v3.5
                                                                          Printed: 12:41 11/13/1997
        

        -------
        Data,file:  /chem/Y.i/10-22-97.b/YP774.d
        Date •: 22-OCT-97 18:18
        Instrument  :  Y.i
        Sample ID : LftB BLANK-MH5-28
        Column phase  : DB-5
        Volume Injected 
          : 1.0 Triangle Laboratories of RTF, Inc. Column diameter ; 0,32 Page 9 ^ -±.00 /chem/Y. i/10-22-97.b/YP774.d (Part 1 of 2) 4.0: 3.8: 3.6: 3.4: 3.2: 3.0: 2.8: 2.6: 2.4: " 2.2- XX \O 32.0: >< . ^i.s-; 1.6: 1.4: 1.2: l.O: 0.8: 0.6: 0.4: 0.2: f xs T-l If) tf NX X ^ JLl ^ O . r 1 g U Q. 1 ' , ^jV^^wJ U Jill 1 ik Ul tiHffljL. 1 C N g o * b = s ' •i-* 1 ^ 1 m n XX e * C$ (S x^ GO SO * * 3) 3 ^ £ XX XX f" I * . i LU—JLfclL v* U_ B c i i f- t j j ,,., .1 1 II LL * »n i>_| 1 q 13 •— » IL. ^ S* NX O ^H I 1 "S. T5 § ^ 1 in "11 5 6 7 8 9 10 11 12 13 14 15 16 1 Time
          -------
          Data File: /chem/Y.i/10-22-97.b/YP774.d
          Date :• 22'OCT-97 18:18
          Instriment :  Y.i
          Sample ID : LAB BLANK-MM5-28
          Column phase  :  DB-5
          Volume Injected (uL)  : 1.0
           Triangle Laboratories
                of RTF, Inc.
          Column diameter  :  0.32
                                                                      Page 10
          00
          
          4.0-
          3.8:
          3.6:
          3.4:
          3.2:
          3.0:
          2.8:
          2.6:
          2.4:
          2.2-
          XX •
          I2'0'
          
          1.6:
          1.4:
          1.0:
          0.8:
          0.6:
          0.4:
          o.2:
          
          
          
          
          
          
          
          
          
          
          
          
          
          •
          
          
          
          
          
          1 1
          XJJ
          20
          
          .
          
          
          
          
          
          
          
          
          •
          
          
          
          
          
          I
          
          L^v-^wxJJuA
          21 22
          
          XX
          a
          XX
          O
          I
          
          
          
          
          
          
          
          
          
          
          
          
          
          1 *• A -*• JLA
          23 24 5
          /chem/Y.i/10-22-97.b/YP774.d (Part 2 of 2)
          
          
          
          
          
          
          
          
          3 ff)
          CM §
          • »
          g g
          CVJ CM
          ^j T"j
          (0 •— i
          CJ ft
          1 1
          '
          '
          1
          
          1 A ILjL ^L^^- -n 	 H— V-JW-^, 	 ^^_,,.Jv.irJK_urni..-l „,
          L ^^^^^J^^^^JW-~^KA**-~*~^'^ •«v«-m«v«A5 26 27 28 29 30 31 32 33 34 35
          

          -------
          Data File:  /chem/Y.i/10-22-97.b/YP774.d
          Report Date: 23-Oct-1997  11:38
                                                                           Page 1
          Data file
          Lab. Id.
          Inj  Date
          Operator
          Smp  Info
          Hisc Info
          Comment
          Method
          Heth Date
          Cal  Date
          Als  bottle
          Dil  Factor
          Integrator
                           TRIANGLE LABORATORIES,  INC.
                       SEMI-VOLATILE  QUANTITATION REPORT
          /chem/Y.i/10-22-97.b/YP774.d
          43433
          22-OCT-97  18:18                Autotune Date:  22-Oct-97
          DD                                Inst ID:  Y.i
          LAB  BLANK-MH5-28  •
          185-7-6A-C
                                                            09:14:0
          /chem/Y.i/10-22-97.b/cclist .m
          23-Oct-1997 11:29  target
          22-OCT-1997
          12
          1.000
          HP  RTE
          11:59
          Sample  Type:  AIR
          Cal  File:  YP766.d
          Target Version:  Target  2.20
          Compound  Sublist: pah.sub
                                                                  CONCENTRATIONS
            Compounds
          
          *  1 l,4-Dichlorobenzan«-d4
          *  3 Naphthalene-d8
          *  3 Acenaphthene-dlO
          *  4 Phenanthrane-dlO
          *  5 Chry«ene-dl2
          *  6 Perylene-dl2
          $  7 2-Pluorophenol
          $  8 Phenol-dS
          $  9 2-Chlorophenol-d4
          $ 10 l,2-Dichlorobenzene-d4
          $ 11 Nitrobenzene-d5
          $ 12 l,3,5-Trichlorobenzene-d3
          $ 13 l,4-Dibromobenzene-d4
          $ 14 2-71uorobiphenyl
          $ 15 2,4,6-Tribromoph.no!
          $ 16 Anthracene-dIO
          $ 17 Pyrene-dlO
          $ 18 Tarph«nyl-dl4
            42 Naphthalene
            46 2-Hethylnaphthalene
            50 2-Chloronaphthalene
            56 Acenaphthylene
            58 Xcenaphthene
            £5 Fluorene
            73 Phenanthrena
            74 Anthracene
            77 Fluoranthene
            78 Pyrene
            83 Benzo(a)anthracene
            84 Chryaene
            86 Benzo(b)tluoranthane
          QUANT SIQ
          MASS RT (RBL RT)
          152.00 10.224(1.000)
          136.00 12.762(1.000)
          164.00 16.421(1.000)
          188.00 19.549(1.000)
          240.00 25.276(1.000)
          264.00 29.403(1.000)
          Compound Not Detected.
          99.00 9.451(0.924)
          Compound Not Detected.
          Compound Not Detected.
          82.00 11.294(0.885)
          185.00 11.982(0.939)
          239.80 12.869(1.259)
          172.00 15.010(0.914)
          329.80 18.066(1.100)
          188.00 19.663(1.006)
          212.00 22.539(0.892)
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          
          Compound Not Detected.
          Compound Not Detected.
          Compound Not Detected.
          ON-COLDMN FINAL
          RESPONSE ( ng) ( ug)
          433631 40.00
          1322956 40.00
          842411 40.00
          1241220 40.00
          985400 40.00
          1189592 40.00
          1270989 69.14 69.14
          929888 74.18 74.18
          708495 62.82 62.82
          787094 74.42 74.42
          1867470 71.70 71.70
          522817 91.27 91.27
          2999871 91.70 91.70
          2875514 97.12 97.12
          	 2336 U.US U.US lag)
          
                                                                  *•)??*#.£
                                                                           Data Review
                                                                           Date:
          

          -------
          Data File:  /chexn/Y.i/10-22-97 .b/YP774.d
          Report Date: 23-Oct-1997 11:38
                                                       Page  2
            Compounds
                                      Q0ANT SIS
                                         MASS
                                                   BT (MEL RT>
                               CONCBRKATXONS
                             OH-COLUMN    FINAL
                       RBSPONS1   (   ng)    (   ug)
            87 Benzo(k)fluoranthene
            88 Benzo(•)pyrene
            89 Benzo(a)pyrene
            90 Perylene
            91 Indeno(l,2,3-cd)pyrene
            92 Oibcnz («,h) anthraocn*
            93 B*nzo(g,h>l)paryl*n«
          
          QC  Flag Legend
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Hot
          Hot
          Not
          Hot
          Hot
          Hot
          Hot
          D«t«ot«d.
          D*t*et«d.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          a  - Target compound detected but, quantitated amount
               Below  Limit Of  Quantitation(BLOQ).
          Q  - Qualifier  signal failed the ratio test.
          

          -------
          Data File: /chem/Y.i/10-22-97.b/CAA/YP774.d
          Report Date:  23-Oct-1997  09:04
                       Page 1
                                         TRIANGLE  LABORATORIES,  INC.
                                                                      REPORT
          Data file
          Lab. Id.
          Inj  Date
          Operator
          Smp  Info
          Misc Info
          Comment
          Method
          Meth Date
          Cal  Date
          Als  bottle
          Dil  Factor
          Integrator
          Sample Type:
          22-Oct-97  09:14:0
                       SEMI-VOLATILE QUANTITATION
          /chem/Y.i/10-22-97.b/CAA/YP774.d
          43433
          22-OCT-97  18:18                Autotune Date:
          DD                                Inst ID:  Y.i
          LAB BLANK-MM5-28 '
          185-7-6A-C
          /chem/Y.i/10-22-97.b/tlicaa.m
          23-Oct-1997 08:05  target
          22-OCT-1997 15:55              Cal File:  YP771.d
          12
          1.000                            Target Version:  Target  2.20
          HP  RTE                           Compound Sublist: CAAl.sub
           mm5
                                                                  CONCENTRATIONS
            Compound*
          
          *  1 lf4 Dichlorobenzene-d4
          •  2 Naphthalene-dS
          *  3 Aeenaphthene-dlO
          •  4 Phenanthrene-dlO
          *  5 Chry«ene-dl2
          *  6 Perylene-dl2
          $  7 2-Pluorophenol
          $  8 Phenol-d5
          $  9 2-Chloroph«nol-d4
          $ 10 l,2-Dichlorobenzene-d4
          $ 11 Nitrobenzene-d5
          $ 12 l,3,S-Trichlorob«nzen«-d3
          $ 13 l,4-Dibromob«nz«ne-d4
          $ 14 2-Pluorobiphenyl
          $ 15 2,4,6-Tribromophenol
          $ 16 Anthracene-dIO
          $ 17 Pyrene-dlO
          $ 18 Terphenyl-dl4
            20 n-Nitroeodimethylamine
            21 Cumene
            23 Phenol
            24 Aniline
            27 bis-(2-Chloroethyl)ether
            28 Benzyl Chloride
            29 1,4-Diehlorobenzene
            31 2-Methylphenol
            32 3/4-Methylphenol
            33 Acetophenone
            34 n-Nitroeomorpholine
            35 o-Toluidine
            3 6 Hexaehloroethane
          QUANT SIO
          MASS
          152
          136
          164
          188
          240
          2S4
          
          99
          
          
          82
          185
          240
          172
          329
          188
          212
          74
          94
          
          
          
          
          
          
          .00
          .00
          .00
          .00
          .00
          .00
          Compound
          .00
          Compound
          Compound
          .00
          .00
          .00
          .00
          .80
          .00
          .00
          Compound
          .00
          Compound
          .00
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          56*00
          Compound
          
          Compound
          10.
          12.
          16.
          19.
          25.
          29.
          Not
          9.
          Not
          Not
          11.
          11.
          12.
          15.
          IB.
          19.
          22.
          Not
          4.
          Not
          Not
          Not
          Not
          Not
          Not
          Not
          Not
          Not
          Not
          RT (RBL RT)
          224(1.000)
          762(1.000)
          421(1.000)
          549(1.000)
          276(1.000)
          403(1.000)
          Detected.
          451(0.924)
          Detected.
          Detected.
          294(0.885)
          982(0.939)
          869(1.259)
          010(0.914)
          066(1.100)
          663(1.006)
          539(0.892)
          Detected.
          it* (n *«3)
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          ON-COLUMN
          RKSPONSB
          433631
          1322956
          842411
          1241220
          985400
          1189592
          
          1270989
          
          
          929888
          708495
          786727
          1867470
          522817
          2999871
          2875514
          138'j''
          
          
          
          
          
          
          
          
          
          
          (
          40
          40
          40
          40
          40
          40
          
          74
          
          
          72
          65
          75
          71
          102
          85
          86
          	 3.
          
          
          
          
          
          
          
          
          
          
          ng)
          .00
          .00
          .00
          .00
          .00
          .00
          
          .38
          
          
          .41
          .75
          .08
          .31
          .41
          .85
          .94
          T&7 	
          
          
          
          
          
          
          
          
          
          
          FINAL
          ( ug)
          
          
          
          
          
          
          
          74.38
          
          
          72.41
          65.75
          75.08
          71.31
          102.41
          85.85
          86.94
          	 3.07
          
          
          
          
          
          
          
          
          
          
                                                                   Data Review:
                                                                   Date:
          

          -------
          Data  File:   /chem/Y.i/10-22-97.b/CAA/YP774.d
          Report  Date:  23-Oct-1997  09:04
                                                                Page 2
             Compounds
                                              QUANT SXQ
                                                 MASS
                                                               RT  (RKt RT)
                                 CONCENTRATIONS
                               ON-COLUMN     FINAL
                      RZSPONSC    (   ng)     (   ug)
             37 Nitrobenzene
             38 N.H-Dimethylaniline
             39 l,2-Dibromo-3-chloropropane
             40 laophorone
             41 o-Anisidine
             42 1,4-Phenylenedianine
             43 1,2,4-Trichlorobenzene
             44 Naphthalene
             46 Hexachlorobutadiene
             47 N,N-Diethylaniline
             48 a,a,a-Trichlorotoluene
             49 Hydroquinone
             51 2-Chloroacetophenone
             52 Hexaehloroeyclopentadiene
             53 2,4,6-Trichlorophenol
             54 2,4,5-Trichlorophenol
             SO Biphenyl
             £1 Dimethylphthalate
             62 2,4-Dinitrophenol
             S3 4-Nitrophenol
             £4 2,4-Dinitrotoluene
             65 Dibenzofuran
             £6 Di-n-butylphthalate
             £7 4,£-Dinitro-2-methylphenol
             £8 Trifluralin
             £9 H«xaohlorob»nz«n«
             70 4-Aminobiph«nyl
             71 P«nt»ohloroph«nol
             72 P*ntachloronxtrob*nz«n«
             73 4-Hitrobiph«nyl
             74 B«nzidin«
             75 4,4'-M«thyl«n«dianilin«
             77 Dim«ehylaminoazob*nz«n*
             78 3,3'-Dim*thylb«nzidina
             SO 3, 3' -Dim*thoxyb«nzidin«
             81 3,3'-Dichlorob«nzidin«
             82 M«thyl«n« bi«-chloroanilin«
             83 bi« (2-Bthylh«xyl)phthalat«
             Compound Hot
             Compound Hot
             Compound Hot
             Compound Not
             Compound Hot
             Compound Not
             Compound Hot
             Compound Hot
             Compound Hot
             Compound Not
             Compound Hot
          110.00       13-:
             Compound Hot
             Compound Hot
             Compound Hot
             Compound Hot
          154.00       IS,
          163.00       15.
             Compound Hot
          139.00       16-
          165.00       16-,
             Compound Hot
          149.00       20.
             Compound Not
             Compound Not
             Compound Hot
             Compound Hot
             Compound Not
             Compound Not
             Compound Not
          184.00       22-
             Compound Not
             Compound Not
             Compound Not
             Compound Not
             Compound Not
             Compound Not
          149.00       25.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          520(1.OtO)
                          -5W
                                    0.04
          Detected.
          Detected.
          Detected.
          Detected.
          839(0.965)
          Detected.
          BR1 (1 . U71?)
          Detected.
          785(1.063)
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          355(1.003)
                        27547
                          5S7
                                    1.13       1.13
                       1384286
                                   29.02     29.02
                        27619
                                                                                         1.18       1.18
          

          -------
           Data File: /chen/Y.i/10-22-97.b/CfWYP774.d
           Date : 22-OCT-1997 18:18
           Instrument :  Y.i
           Sample IB : LAB BLANK-MM5-28
           Column phase  : DB.5-625
           Volume Injected _
          2.0:
          
          
          61 Dimethylphthalate (PBM Reference Spectrum)
          
          
          
          
          
          %
          
          i 11 > 1
          •" 	 •'!• "II.. .. 1. -• J.I.
          40 50 60 70 80 90 100 110 120 130 140 150 160
          
          
          
          
          
          
          
          
          
          
          
          Mass/Charee
          Scan 1665 (15.839 min) of YP774.d (Z DIFFERENCE)
          100-
          75-4
          50-j
          
          25-j
          <+. :
          S-254
          X :
          -50-j
          
          -75-i
          
          
          
          
          
          
          
          
          
          
          
          
          40 50 60 70 80 90 100 110 120 130 140 150 160
          Mass/Charee
          Mass 163.00
          1.6-5
          •
          1.4-i
          1.2:
          ;
          31'0"
          00.8:
          •2 :
          >-0.6-
          0.4:
          
          0.2:
          0 0-
          
          
          
          
          
          
          
          
          
          
          
          
          A
          •s
          *
          in
          
          
          
          
          
          
          
          
          
          
          A
          15.4 15.6 15.8 16.0 16.2
          Time (min.)
          Mass 194.00
          700-^
          '•
          600-j
          500:
          
          400-j
          •
          ^300:
          200-i
          
          100-i
          
          
          
          
          
          
          
          
          
          
          
          
          
          S
          B
          
          
          
          
          
          
          
          
          
          
          15.4 15.6 15.8 16.0 16.2
          Time (min.)
          Mass 164.00
          j
          1 4-
          A«t
          1.2-
          
          1.0-
          
          < *
          o
          ^50.6:
          0.4-
          
          
          0.2-
          
          0 0-
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          ~M
          GO
          in
          
          
          
          
          
          
          
          
          
          
          
          
          
          15.4 15.6 15.8 16.0 16.2
          Time (min.)
          

          -------
           Data File: /cliem/Y.i/10-22-97.b/Cftfl/YP774.d
           Date : 22-OCT-1997 18:18
           Instrument : Y.i
           Sample ID : LftB BLflNK-MM5-28
           Column phase :  DB.5-625
           Volume Injected 
            : 1.0 66 Di-n-butylphthalate Page 13 Column diameter : 0.32 Scan 2362 (20.785 min) of YP774.d 7.0H 6.0-i 5.0-j £4*°1 XX * j 1.0^ i .1. i. • & .. n . . 40 60 80 100 120 140 160 180 200 220 240 260 Mass/Charee Scan 2362 (20.785 min) of YP774.d (Subtracted) 7 0- f * V . 6.0-1 5.0-j ^4.0-J o : 33-°1 i.o-i 0 0 '' '", f .", 1 , -|l'| , ,', , 'l , , f; , i , . 40 60 80 100 120 140 *-i — r— r — i r i — i — i i i — I , . ' , — , — . . , — i— 160 180 200 220 240 260 Mass/Charee 66 Di-n-butylphthalate (PBM Reference Spectrum) . 8.0: • fO * ' §4.0: 3_ : 2.0: 0 0- 1 ,.,11 |. ,L 1 l|. L. ( 40 60 80 100 120 140 | | 160 180 200 220 240 260 Mass/Charee Scan 2362 (20.785 min) of YP774.d (2 DIFFERENCE) 100-q 75-j 50-j 251 t <>-• 5-25-j "*-50-j -75-. -100- ••i r - — — - • — r- •.- - 40 60 80 100 120 140 160 180 200 220 240 260 Mass/Charee Mass 149.00 7.0-i 6.0-; 5.0: |4.0: -3.0: >- ; 2.0-; 1.0-; 0 0- It— Hf) " II O II "^ 1 LI 20.40 20.60 20.80 21.00 21.20 Time (min.) Mass 150.00 6.0: 5.0: ^4.0- <^ 33'°: >• ; 2.0- i.o- ^^ o 20.40 20.60 20.80 21.00 21.20 Time (min.) Mass 104.00 3.2- 2.8- 2.4: 2 * .0- J* Sl.6- XX >-1.2- 0.8- 0.4- l~fc 1 s* ] I . >, ,1 t ,i , , A, . t ,N» , , , ,t. , . l 20.40 20.60 20.80 21.00 21.20 Time (min.)

          -------
             Data File:  /chem/Y.i/10-22-97.b/C(WYP774.d
             Date :  22-OCT-1997 18:18
             Instrument  :  Y.i
             Sample  ID : LAB BLANK-MM5-28
             Column  phase  :  DB.5-625
             Volume  Injected 
            : 1.0 83 bis(2-Ethylhexyl)phthalate Page 15 Column diameter : 0.32 Scan 3005 (25.355 min) of YP774.d 0.0 .0 "'P i I"'| i"f'l' |"l i1 l"|"i 'i'l | i i1* | i"l i |'i'i i'| i i' i | i"i i | i i i"| i i i | i i i ( 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charge Scan 3005 (25.355 min> of YP774.d (Subtracted) 8.0- 0.0- I 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charge 83 bis(2-Ethulhexyl)phthalate (PBM Reference Spectrum) 8.0- 0.0 -+- Jt- I 40 60 80 100 120 140 160 180 200 220 240 260 280 Mass/Charge 100- 75-i 50-i 25i t H 3-25-i -75-i -100- Scan 3005 (25.355 min) of YP774.d (2 DIFFERENCE) ir ,„ ,.l 40 60 80 100 120 140 160 180 200 220 _ Mass/Charge _ 240 260 280 Mass 149.00 25.00 25.20 25.40 25.60 25.80 Time (min.) Mass 167.00 3.2- 2.8- 2.4- 2.0- f<> S1*6" 0.8: 0.4- 0.0- n 25.00 25.20 25.40 25.60 25.80 Time (min.)

          -------
          [> - , ^**v£*\L'''*^ * ;,'s
          ^ . ,^ ~y,y,, ^ ^5,
          Project Number. 43433
          Sample File: YP773
          Client Proiecfe Sai&riaii^' MI-^ **
          TPTf "J 1T\» ^JL-TtT ^tr *^V*t^ Jtrfyy^" •• •' '""* •'•> •x>v-*'¥v" ""..
          Jt .TifrT j fir t YTnr n rtfc^- rUr 'Jt'*r^ff sX ' C"1^* 5O1. ^* Su% '•
          s > "* -^ "•%•••••% ^%/^% \\-. X v
          . ^i$gX$iJiib2*$
          
          :* ,\-f" ; ^^^ifeived*^/ ^*- '^v '" - --^ " '->
          " "^ ^DS®ffi^feilfM^I ^ ; ^
          ;^^^WSSS8^*^^;sV^
          •" % ^ s f v f" ^"^^^ ^ ^ % ^. :
          Method 8270AXAP
          Sample ID: SBLK101497
          ^•Resd^ri^ F^^S^'T'^H- =
          J-* ^^ Afl **»*? >^*d^^^* ^
          if'^|"^*V^^§\^!.
          Dilution Factor: 1.00
          
          te^-' •'•''«;WM?^'?t^?f^^^^®'0^^!
          Naphthalene-d
          Naphthalene
          2-Mediylnaphthalene
          Acenaphthene-d
          2-Chloronaphthalene
          Acenaphthylene
          Acenaphthene
          Fluorene
          Phenanthrene-d
          10
          Phenanthrene
          Anthracene
          Fluoranthene
          Chrysene-d
          Pyrene
          Benzo(a)anthracene
          Chrysene
          Perylene-d
          7 12
          Benzo(b) fluoran diene
          Benzo(k)fluoranthene
          Benzo(e)pyrene
          Benzo(a)pyrene
          Perylene
          Indeno(l ,2,3-cd)pyrene
          Dibenz(a,h)anthracene
          Benzo(g,h,i)perylene
          IS 2 12.76
          2.44 ] 12.81
          U
          IS 3 16.43
          U
          U
          U
          U
          IS 4 19.55
          U
          U .
          U
          IS 5 25.28
          U
          U
          U
          IS 6 29.41
          U
          U
          U
          U
          U
          U
          U
          U
          
          10
          0.43 10
          0.44 10
          0.27 10
          0.45 " 10
          0.45 10
          0.29 10
          0.30 10
          0.29 10
          0.28 10
          0.32 10
          0.33 10
          0.30 10
          0.29 10
          0.28 10
          0.31 10
          0.28 10
          0.27 10
          0.36 10
          0.29 10
                                      NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantttation Limit
               IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantttation Limit; E: Estimated- Above Calibration Range
          Triangle Laboratories of RTF, Inc.
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544-5729 • Fax: (919) 544-5491
                        Savar v3.5
          Printed: 09:47 11/13/1997
          

          -------
          I
                                                                          *  ' v^V ^s
                                                                       % % s •,   g^.  i.V \
            'reject Number: 43433
           Sample File: YP773
                                                             Method 8270A XAD
                                                         Sample ID: SBLK101497
                                                        Dilution Factor:    1.00
          \ \ s "• \ "• v. , -. ^ •. t <• %
          1 v ^ ' ^ -"'^ '
          ' " ' s '
          'henol-d
          i
          Nitrobenzene-d
          i
          ,3>5-Trichlorobenzene-d
          3
          » ,4-Dibromobenzene-d
          4
          2-Fluorobiphenyl
          ,4,6-Tribromophenol
          Anthracene-d
          to
          "yrene-d
          ' 10
          *'o,%
          C^^k ^ % ' v ''"
          
          56.67
          
          56.00
          
          53.36
          
          64.21
          
          67.25
          99.19
          95.10
          
          105.84
          -X
          "" s ssO^ ^
          
          9.45
          
          11.30
          
          11.98
          
          12.87
          
          15.01
          18.07
          19-67
          
          22.54
          % ^ .^\x%%
          "• ^v" •.
          1
          
          2
          
          2
          
          1
          
          3
          3
          4
          
          5
          ^ C*** "* N %S % '•
          ...?.$..?..?. 	 \.% 	 :
          57
          
          56
          
          53
          
          64
          
          67
          99
          95
          
          106
           Reviewed by.
          Date  II
                                    NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitatton Limit
               IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
           Triangle Laboratories of RTF, Inc
           "01 Capitola Drive • Durham, North Carolina 27713
            hone: (919) 544-5729 • Fax: (919) 544-5491
                                                                             Savarv3.5
          

          -------
          Project Number 43433
          Sample File: YP773
               Method 8270A XA-D
          Sample ID: SBLK101497
          LjLieUt JrrQTeCC SnXgluttl^- SflL .••••.•..' ••••. •.•.;.•,•.
          Tff TT%» &KT V"ttVtAOfT $ ' " ~~ •• K & v Vs.
          I IJI JlL/; OoJUiXAUa.*;?/ :.-..- , ^ „ «** *:
          4 «\ v-. o h - " '%:? v"ff ""9
          
          
          
          &nftlyffe •> „ % V ^ ^ Tv
          
          1 ,4-Dichlorobenzene-d
          n-Nitrosodimethylamine
          Cumene
          Phenol
          Aniline
          bis-(2-Ch!oroethyl)ether
          Benzyl Chloride
          1 ,4-Dichlorobcnzene
          2-MediyIphenol
          Acetophenone
          n-Nitrosomorpholine
          o-Toluidine
          Hcxachloroethanc
          1 ,2-Dibromo-3-chloropropane
          N,N-Diethylaniline
          Naphthalene-d
          3/4-Methylphenol
          Nitrobenzene
          N,N-Dimethylaniline
          Isophorone
          o-Anisidine
          1 ,4-Phenylenediamine
          1 ,2,4-Trichlorobenzene
          Hexachlorobutadiene
          a,a,a-Trichlorotolucne
          Hydroquinone
          
          , <;^^^^|iyzc4'^10^i^
          Dilution Factor: 1.00
          
          .^ifrff.^^tltf S jPJ^TTT"? % % f ^ s S^t •* % s
          
          IS 1 10.22
          U
          U
          u
          u
          u
          u
          u
          u
          2.53 J 11.00
          U
          U
          U
          U
          U
          IS 2 12.76
          U
          U
          U
          U
          U
          U
          U
          U
          U
          U
          \ '"¥'* ' '*£ X ^ ^ %-u ' j-
          •. ^ ^ s ^ V ' ^ j. ^ <•*• \XJ% •^v~ Vff '"''
          ^ £ •• J^ v yX ^ ^ x^«.% *-V*^ ^-X% N*'
          
          
          \ ^^^,^^ % N% *-^%^
          ^ ^ ^V«« 1^;^"^
          1.41
          0.39
          0.63
          0.51
          1.08
          0.39
          0.63
          0.81
          
          1.41
          0.51
          1.33
          1.40
          0.48
          0.89
          0.56
          0.57
          0.47
          1.02
          0.74
          0.86
          1.47
          0.70
          0.77
          MjMv. \> x :
          f^, •. v\
          oC^: *!
          
          
          ^% \x ^ \:
          Kt^ K»n10llTi
          % "t ' V°i
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
          10
                                   NA- Not Applicable; DeL Limit Detection Limit; Quan. Limit: Quantitation Limit
              IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
          Triangle Laboratories of RTF, Inc
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544-3729 • Fax: (919) 544-5491
                              Savar v3.5
                  Printed: 12:41 11/13/1997
          

          -------
          . %% x " rs ' ," ..-. v " v-
          1 ^ -
          F -"' , * " v%-
          Project Number: 43433
          Sample File: YP773
          pnilD:SB^101$S7i
          * %%\
          I
          v.^ ^**^ x£ ^j^-\^ ' ' v ^v s vi£i3$\<£,£% T ^C"\x. ™*rs ^^^.H-."1 ^v^x.1^
          Jv^JffX\ vV 54^
          •A ^A-V ^ X *VW"
          --', vv^W
          £^fe&vi
          xsr %\^* ;
          •• > XXi^ s x :
          Method 8270AXA-D
          Sample ID: SBLK101497
          - x l -'^ ^\v^dte"^tfasadfe^Wl4/^CAT^
          •>":** ^^':';vmtl^aj^dtlO/^^ '-^ \:
          ". "• % s *• f *.\yj^ s ^\^\v ' &^ O*-?«% ^ *• f f ^
          Dilution Facton 1.00
          Response F|I<
          > * <\^« % ^*%
          
          ^^/y
          ^^ *" ^ ^ ' ^x 1 ~" V
          !:'£^*"^ i
          
          
          1
          2-Chloroacetophenone
          Acenaphthene-d
          Hexachlorocyclopentadiene
          2,4,6-Trichlorophenol
          2,4,5-Trichlorophenol
          Biphenyl
          Dimethylphthalace
          2,4-Dinitrophenol
          4-Nitrophenol
          2,4-Dinitrotoluene
          Dibenzofuran
          4,6-Dinitro-2-methylphenol
          Trifluralin
          Phcnanthrene-d
          10
          Di-n-butylphthalate
          Hexachlorobenzene
          4-Aminobiphenyl
          Pentachlorophenol
          Pentachloronitrobenzene
          4-Nitrobiphenyl
          Chrysene-d
          Benzidine
          4,4'-Methylenedianiline
          Dimethylaminoazo benzene
          3,3'-Dimethylbenzidine
          3,3'-Dimethoxybenzidine
          • ...^^A^j;,^^ :RT '^
          3.83 J 13.86
          IS 3 16.43
          U
          U
          U
          U
          U
          U
          U
          U
          U
          U
          U
          IS 4 19.55
          1.61 J 20.78
          U
          U
          U
          U
          U
          IS 5 25.28
          U
          U
          U
          U
          U
          ^5-fc ":;:;
          
          1.46
          1.33
          1.15
          0.36
          0.42
          5-12
          1.96
          1.50
          0.32
          3.32
          2.42
          
          0.87
          0.37
          1.66
          3.50
          0.95
          0.47
          1.11
          0.95
          0.59
          1.22
          ^f*j
          10
          10
          10
          10
          10
          10
          25
          25
          10
          10
          25
          10
          10
          10
          10
          25
          10
          10
          10
          10
          10
          10
          10
          NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
          IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
          Triangle Laboratories of RTF, Inc.
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544o729 • Pax (919) 544-5491
                        Savarv3.5
          

          -------
                                         ^v.v% ^-. Jw •. ^ x £..     s  '  '^ ^ ^\<   ^
                                           ^% ^>\f  -^X OV-> ^ ,-},,  «> , ^5,
          Project Number 43433
          Sample File: YP773
                                                              Method 8270 A XAD
                                                         Sample ID: SBLK101497
                                                        Dilution Factor:    1.00
          3,3'-Dichlorobenzidine
          Methylene bis-chloroaniline
          bis(2-Ethylhexyl)phthalate
                         U
                         U
                   0.57  J
                             0.80
                             1.81
          25.35
          10
          10
          10
          Reviewed by.
          Date  \U 15 I
                                    NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
               IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
          Triangle Laboratories of RTF, Inc
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                              Savarv3.5
          

          -------
          Data ,F,ile: /chem/Y.i/10-22-97.b/'YP773.d
          Date t 22-OCT-97 17:30
          Instrument ; Y.i
          Sample ID : SBLK 101497
          Column phase :  D6-5
          Volume Injected 
            : 1.0 Triangle Laboratories of RTF, Inc. Column diameter : 0.32 Page 9 4.6-i 4.4-i 4.2: 4.0: 3.8: 3.6-i 3.4-i 3.2-i 3.0-i 2.8: 2.6: XX -2.2-i 2.0-i • 1.8: 1.6-i 1.4-i 1.2: 1.0: 0.8: 0.6-i 0.4-i 0.2: a /chem/Y. i/10-22-97.b/YP773.d ro GO cr> ro I xx c CXI Kl CNJ C S "o S ^ ^ T S -5 O* d| JSf *r4 (Part 1 of 2) —V. XX 8 ui ^ •^ £ 5 xx <~ ^O § 1 a 3 r "5 1 IM JQ xf OOJ ^ -D 10 I"O i £ § 7^| <^— ^>4 S | ^- °- -s £ J i ~ N •? i 1 11 Jt Ll JUn JL U luiJIII d H .11 5678 j, JilIM IJllJ « £ Jf -Q ^ 0 ^H .p z 1 L ^., 9 10 11 12 Time (min.) 1 : i M «tu^ ^ 1 | O *~ CD t- U 3 f cr * t- 1- 0 •* T T - g ' £ 1 0? 1 ' 1 L.. a I A • -A -ill- J. 4- 1 1 * 5 o "D 1 c to 10 1 ..I, 13 14 15 16 17 18 19

          -------
          Data file:  /chem/Y.i/10-22-97.b/YP773.d
          Date J 22-OCT-97 17:30
          Instrument  :  Y.i
          Sample ID : SBLK 101497
          Column phase  : DB-5
          Volume Injected (uL) : 1.0
          Triangle Laboratories
               of RTP, Inc.
          
            Column diameter :  0.32
                                                                        Page 10
                                                                                        00
                                                                                        03
          
          4.6:
          4.4:
          4.2:
          4.0:
          3.8:
          3.6:
          3.4:
          3.2:
          3.0:
          2.8:
          2.6:
          XX
          ^2.4-;
          -2.2:
          2.0:
          o •
          1^
          1.4:
          1.2:
          1.0:
          0.8-i
          0.6:
          0.4:
          0.2:
          0.0-
          
          •
          
          
          
          
          
          
          
          
          '
          1
          
          
          
          
          
          
          
          L^L_ JL
          /'chem/Y.i/10-22-97.b/YP773.d (Part 2 of 2)
          1
          8*
          o
          1
          
          -------
          Data File: /chem/Y.i/10-22-97.b/YP773.d
          Report Date:  23-Oct-1997 11:34
                                                                            Page 1
          Data file
          Lab. Id.
          Inj  Date
          Operator
          Smp Info
          Misc Info
          Comment
          Method
          Meth Date
          Cal Date
          Als bottle
          Dil Factor
          Integrator
                           TRIANGLE  LABORATORIES, INC.
                       SEMI-VOLATILE QUANTITATION  REPORT
          /chem/Y.i/10-22-97.b/YP773.d
          43433
          22-OCT-97 17:30                 Autotune  Date:  22-Oct-97  09:14:0
          DD                                 Inst ID:  Y.i
          SBLK 101497
          /chem/Y.i/10-22-97.b/cclist.m
          23-Oct-1997  11:29  target
          22-OCT-1997
          11
          1.000
          HP  RTE
          11:59
          Sample  Type:  AIR
          Cal  File:  YP766.d
          Target Version: Target   2.20
          Compound Sublist: pah.sub
             Compound*
                                      QUANT SIS
                                        MASS
                                                  RT (RBI. RT)
                                                     CONCENTRATIONS
                                                   ON-COLOMN    FINAL
                                             RESPONSE    (  ng)   (  ug)
          •  1 l,4-Dtchlorob«nl«n«-d4
          *  2 N«phth«l«n«-d8
          *  3 Ac«naphth«n«-dlO
          *  4 Ph«n*nthr»n«-dlO
          •  5 Chry«»n«-dl2
          *  £ P«ryl«n«-dl2
          $  7 2-Fluoroph«nol
          $  8 Phanol-dS
          $  9 2-Chloroph«nol-d4
          $  10 l,2-Dichlorob«nz«n«-d4
          $  11 Nitrob«nz«n«-d5
          $  12 l,3,S-Trichlorob«nz«n«-d3
          $  13 l,4-Dibromob«nz«n«-d4
          $  14 2-Pluorobiph*nyl
          $  15 2,4,6-Tribromoph»nol
          $  1C Anthr»o«n«-dlO
          $  17 Pyr»n«-dlO
          $  18 T«rph«nyl-dl4
             42 N»phth»l«n«
             46 2-M«thyln»phth»l.n«
             50 2-Chloron»phth»l«n«
             56 Ac«n«phthyl»n«
             58 Ao*naphth«n*
             65 Fluor«n«
             73 Ph«n«nthr«n»
             74 Anthr»c»n«
             77 Fluor«nth»n«
             78 Pyr«n«
             63 Bttnzo (•) uithrac^n*
             84 Chry»»n»
             86 Banzo(b)fluoranth«n«
          152.00
          136.00
          164.00
          188.00
          240.00
          264.00
          Compound
          99.00
          Compound
          Compound
          82.00
          185.00
          239.80
          172.00
          329.80
          188.00
          212.00
          Compound
          128.00
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          10.
          12.
          16.
          19.
          25.
          29.
          Not
          9.
          Not
          Hot
          11.
          11.
          12.
          15.
          18.
          19.
          22.
          Hot
          12.
          Hot
          Hot
          Not
          Hot
          Hot
          Hot
          Hot
          Not
          Not
          Hot
          Hot
          Hot
          223(1.000)
          764(1.000)
          426(1.000)
          546(1.000)
          280(1.000)
          408(1.000)
          D«t«ct«d.
          450(0.924)
          D«t«ot«d.
          D«t«ct*d.
          301(0.885)
          983(0.939)
          870(1.259)
          006(0.914)
          071(1.100)
          668(1.006)
          540(0.892)
          D«t«ot«d.
          806(1.003)
          Detected.
          D»t«ct«d.
          D«t«ot«d.
          D«t»ct«d.
          Dataetad.
          D*t*ct*d.
          D*t*ct«d.
          D«t«ot«d.
          D«t«ot«d.
          Dctcetad.
          D«t«ot«d.
          D«t«ct«d.
          459693
          1467052
          830491
          1360406
          1120374
          1424942
          
          1104585
          
          
          778357
          667324
          720176
          1727131
          560160
          3408997
          3563308
          
          93907
          
          
          
          
          
          
          
          
          
          
          
          
          40.
          40.
          40.
          40.
          40.
          40.
          
          56.
          
          
          55.
          53.
          64.
          67.
          99.
          95.
          105.
          
          2.
          
          
          
          
          
          
          
          
          
          
          
          
          00
          00
          00
          00
          00
          00
          
          68
          
          
          99
          35
          23
          26
          20
          07
          85
          
          44
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          56.68
          
          
          55.99
          53.35
          64.23
          67.26
          99.20
          95.07
          105.85
          
          2.44U)
          
          
          
          
          
          
          
          
          
          
          
          
                                                      Data Review.
                                                      Date'.   «i
          

          -------
          Data File:  /chem/Y.i/10-22-97.b/YP773.d
          Report Date: 23-Oct-1997 11:34
                                                                 Page 2
            Compounds
                                       QUANT SXO
                                         MASS
                      RT (XKL RT)
                 ON-COttMH     FINAL
          RXSPOHSB   (   ng)   (  ug)
            87 Banzo (k)fluoranth«n«
            88 B«nzo (•)pyr«n»
            89 B*nzo(a)pyr«n«
            90 P«ryl«n«
            91 Ind«no(l,2,3-od)pyr»n»
            92 Dlbcnz(a,b)anthracene
            93 B«nzo(g,h,i)p«ryl«n»
          
          QC  Flag Legend
            Compound Hot D«t«ct«d.
            Compound Not D«t«ot»d.
          252.00      2!T7«13(i.flOO)
          252.00      73. .Ti (1,8811)
                                 -3419-
                                          OilB-
            Compound Rot D«t«ot«d.
            Compound Hot D*t*ot>d.
            Compound Rot D«t«ot«d.
          a  - Target compo\ind detected but,  guantitated  amount
               Below  Limit Of  Quantitation(BLOQ).
          Q  - Qualifier  signal failed the ratio  test.
          

          -------
          Data File: /chem/Y.i/10-22-97.b/CAA/YP773.d
          Report Date:  23-Oct-1997  09:00
                                                                           Page 1
          Data file
          Lab. Id.
          Inj  Date
          Operator
          Smp  Info
          Misc Info
          Comment
          Method
          Meth Date
          Cal  Date
          Als  bottle
          Oil  Factor
          Integrator
                          TRIANGLE LABORATORIES,  INC.
                       SEMI-VOLATILE  QUANTITATION  REPORT
          /chem/Y.i/10-22-97.b/CAA/YP773.d
          43433
          22-OCT-97  17:30                Autotune Date: 22-Oct-97
          DD                                Inst  ID: Y.i
          SBLK 101497
                                        09:14:0
          /chem/Y.i/10-22-97.b/tlicaa.m
          23-Oct-1997 08:05  target
          22-OCT-1997 15:55
          11
          1.000
          HP  RTE
          Sample  Type:  xnm5
          Cal  File:  YP771.d
          Target Version:  Target   2.20
          Compound  Sublist: CAAl.sub
                                                                   CONCENTRATIONS
            Compounds
          
          •  1 If4 Dichlorob«nz»n«-d4
          *  2 N»phth»l»n«-d8
          *  3 Ac«naphth«n»-dlO
          *  4 Ph«n»nthr«n»-dlO
          *  5 Chry»«n«-dl2
          *  6 P«ryl«n«-dl2
          $  7 2-Pluoroph«nol
          $  8 Phanol-dS
          $  9 2-Chloroph«nol-d4
          $ 10 l,2-Dichlorob«nz»n»-d4
          $ 11 Nitrob«nz«n«-dS
          $ 12 l,3,5-Trichlorob«nz«n«-d3
          $ 13 l,4-Dibromob»nz»n«-d4
          $ 14 2-Pluorobiphvnyl
          $ 15 2,4,6-Tribromoph*nol
          $ 16 Anthr»o»n«-dlO
          $ 17 Pyr«n«-dlO
          $ 18 T*rph«nyl-dl4
            20 n-Nitro«odim*thylamin*
            21 Cuman*
            23 Phanol
            24 Anilin*
            27 bi«-(2-Chloro«thyl)»th»r
            28 Banzyl Chlorid*
            29 l,4-Dichlorob«nz«n«
            31 2-M«thylph«nol
            32 3/4-M*thylph«nol
            33 Ac»toph«non»
            34 n-Nitro«omorpholin«
            35 o-Toluidina
            36 H»x»chloro«than«
          QUANT SIO
          MASS
          152
          136
          164
          188
          240
          264
          
          99
          
          
          82
          185
          240
          172
          329
          188
          212
          14
          
          94
          
          
          
          
          
          .00
          .00
          .00
          .00
          .00
          .00
          Compound
          .00
          Compound
          Compound
          .00
          .00
          .00
          .00
          .80
          .00
          .00
          Compound
          .00
          Compound
          .00
          Compound
          Compound
          Compound
          Compound
          Compound
          Compound
          105.00
          10
          12
          16
          19
          25
          29
          Hot
          9
          Hot
          Hot
          11
          11
          12
          15
          18
          19
          22
          Hot
          Mot
          Not
          Mot
          Not
          Not
          Hot
          Not
          10
          RT (RRL RT)
          .223(1.000)
          .764(1.000)
          .426(1.000)
          .546(1.000)
          .280(1.000)
          .408(1.000)
          Detected.
          .450(0.924)
          Detected.
          Detected.
          .301(0.885)
          .983(0.939)
          .870(1.259)
          .006(0.914)
          .071(1.100)
          .668(1.006)
          .540(0.892)
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          Detected.
          .995(1.076)
          ON-COLDMN
          RESPONSE
          459693
          1467052
          830491
          1360406
          1120374
          1424942
          
          1104585
          
          
          778357
          667324
          720423
          1727131
          560160
          3408997
          3563308
          
          
          4B3H
          
          
          
          
          
          44151
          (
          40.
          40.
          40.
          40.
          40.
          40.
          
          60.
          
          
          54.
          55.
          64.
          66.
          111.
          89.
          94.
          
          
          ITT
          
          
          
          
          
          2.
          ng)
          00
          00
          00
          00
          00
          00
          
          98
          
          
          66
          85
          85
          89
          30
          01
          76
          
          
          70
          
          
          
          
          
          53
          FINAL
          ( ug)
          
          
          
          
          
          
          
          60.98
          
          
          54.66
          55.85
          64.85
          66.89
          111.30
          89.01
          94.76
          
          
          U. JO"
          
          
          
          
          
          2.53
          56.00 11.265LL-1O21 	 •**•>•* n ->c 	 O- IB
          
          
          Compound
          Compound
          Not
          Hot
          Detected.
          Detected.
          
          
          
          
          
          
          
          
                                                                     Data Review:
                                                                     Date:
          

          -------
          Data  File:   /chem/Y.i/10-22-97.b/CAA/YP773.d
          Report  Date:  23-Oct-1997  09:00
                                                                                                                 Page  2
                                           QUANT SIO
          Compound*                           MASS          KT  (RKL RT)
          
          37 Nitrobenzene                       Compound Not  Detected.
          38 N,N-Dimethylaniline                Compound Hot  Detected.
          39 l,2-Dibromo-3-chloropropane        Compound Hot  Detected.
          40 laophorone                        Compound Hot  Detected.
          41 o-Aniaidine                       Compound Hot  Detected.
          42 1,4-Phenylenediamine               Compound Not  Detected.
          43 1,2,4-Trichlorobenzene             Compound Not  Detected.
          44 Naphthalene                    128.00       12.806(1.003)
          46 Hexachlorobutadiene                Compound Hot  Detected.
          47 N,N-Diethylaniline              134.00       12.764(1.24JO_
          48 a,a,a-Trichlorotoluene             Compound Hot  Detected.
          49 Hydroquinone                    110.00       'LSaffd """>
          51 2-Chloroaoetophenone            105.00       13.863(1.086)
          52 Hexachlorocyclopentadiene          Compound Hot  Detected.
          53 2,4,6-Trichlorophenol              Compound Not  Detected.
          54 2,4,5-Trichlorophenol              Compound Not  Detected.
          £0 Biphenyl                       154.00       15.HOC id.»14)—
          £1 Dimethylphthalate                  Compound Hot  Detected.
          £2 2,4-Dinitrophenol                  Compound Not  Detected.
          £3 4-Nitrophenol                      Compound Not  Detected.
          £4 2,4-Dinitrotoluene              165.00       M.418 (1.800)
          £5 Dibenzofuran                       Compound Not  Detected.
          £6 Di-n-butylphthalate             149.00       20.781(1.063)
          £7 4, 6-Dinitro-2-methylphenol         Compound Not  Detected.
          £8 Triflurilin                       Compound Not  Detected.
          £9 Bexachlorobenzene                  Compound Not  Detected.
          70 4-Aminobiphenyl                    Compound Not  Detected.
          71 Pentachlorophenol                  Compound Not  Detected.
          72 Fentachloronitrobenzene            Compound Hot  Detected.
          73 4-Nitrobiphenyl                    Compound Not  Detected.
          74 Benzidine                      184.00       ia_c^o fn B92)
          75 4,4'-Methylenedimniline            Compound Not  Detected.
          77 Dimethylaminoazobenzene            Compound Not  Detected.
          78 3,3'-Dimethylbenzidine             Compound Hot  Detected.
          80 3,3'-Dimetboxybenzidine            Compound Not  Detected.
          81 3,3'-Dichlorobenzidine             Compound Not  Detected.
          82 Methylene bie-chloroaniline        Compound Not  Detected.
          83 bi«(2-Ethylhexyl)phthalat»      149.00       25.352(1.003)
                                                                                     CONCXMTKXTIONS
                                                                                   OH-COLDMH
                                                                           RESPONSE    (   ng)     (   ug)
                                                                             93907
          
                                                                            mi«
           2.75
          
          -S.90
           2.75
          
          -9r»ff
                                                                             _3ia9-
                                                                                       -fl.lT.
                                                                            103008
                                                                             •>•»"•"
                                                                                        3.83
                                                                                       .0.98
                                                                                                  3.83
                                                                                                  -0.90-
                                                                             83913
                                                                                        1.60
                                                                                                  1.60
                                                                            33199_
                                                                                        l.St
                                                                             15147
                                                                                        0.57
                                                                                                  0.57
          

          -------
           Data File:  /chem/Y.i/10-22-97.b/YP773.d
           Date : 22-OCT-97 17:30
           Instrument  : Y.i
           Sample ID : SDLK 101497
           Column phase : DB-5
           Volume Injected — "
          1.0-
          
          
          
          
          
          
          
          
          
          
          JLJ *.. 1 .1
          •
          
          
          
          
          
          
          
          
          1
          40 80 120 160 200 240 280 320 360 400 440 480
          Mass/Charge
          Scan 1237 (12.806 win) of YP773.d (Subtracted)
          5.0-;
          
          4.0-;
          
          ^H
          X9 0-
          xx t»V
          
          1.0-
          
          
          
          
          
          
          
          
          
          
          
          
          . ,1. .1 1. . J
          
          
          
          
          
          
          
          
          
          
          i
          40 80 120 160 200 240 280 320 360 400 440 480
          Mass/Charee
          42 Naphthalene (PBM Reference Spectrum)
          
          8.0-
          
          |6-°-
          3 4.0-
          XX
          >-
          2.0-
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          .nt. 1 1
          40 80 120 160 200 240 280 320 360 400 440 480
          Mass/Charee
          Scan 1237 (12.806 min) of YP773.d « DIFFERENCE)
          100 -:
          75-i
          50 -j
          
          254
          £ 04
          »-25i
          -50-=
          -754
          
          
          
          
          
          
          ..,.,, p . .T ...
          
          
          
          
          40 80 120 160 200 240 280 320 360 400 440 480
          Mass/Charee
          Mass 128.00
          5.5|
          5.04
          4.54
          ;
          4.0-j
          3.54
          ?3.0-=
          ^ :
          ^2.5^
          ^2.04
          1.54
          i.o4
          0.5-i
          0.0J
          
          
          
          in
          
          £*
          i
          i
          1]
          
          
          J 1
          j
          i V ^ j
          
          S4
          
          
          
          
          
          
          
          
          
          
          
          u..
          
          12.40 12.60 12.80 13.00" 13.20
          Time (min.)
          
          5.54
          
          5.04
          
          4.5r
          4.04.
          
          ~*'^.
          ^3.04
          'H O K '
          >-2.o4.
          1.54
          i.o4
          0.54"
          0 0-
          Mass 129.00
          i^^n
          1 *
          \  i
          . j
          ^ IN
          
          1
          
          
          
          
          
          
          1
          I
          
          1
          
          
          
          
          
          
          12.40 12.60 12.80 13.00 13.20
          Time (min.)
          Mass 127.00
          7.0-i
          
          6.0-
          
          5.0-
          ^ :
          < '.
          o
          33.0-
          s- :
          2.0-
          1.0-
          
          o o-
          
          t^.
          ro
          CVJ
          »H
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          ,
          "s
          CM
          
          
          
          
          
          
          
          
          
          
          
          
          12.40 12.60 12.80 13.00 13.20
          Time (min.)
          

          -------
           Data File: /chem/Y.i/10-22-97.b/Cftfl/YP773.d
           Date : 22-OCT-1997 17:30
           Instrument :  Y.i
           Sample ID : SBLK 101497
           Column phase  :  DB.5-625
           Volume Injected -
          2.0-
          On—
          ,ll,,
          •u i
          40
          100-
          75-i
          504
          254
          fc 0-1
          S-25-1
          "-504
          -75-1
          -1AO-
          
          J
          
          .]
          
          
          
          
          ", Vi > !|1
          Scan 982 (10
          .995 nin) of YP773.d
          60 80 100 120 140 160 180 200
          Mass/Charee
          Scan 9E
          1 , "I , 'l
          2 (10.995 mi
          • I. i
          n> of YP773.d (Subtracted)
          60 80 100 120 140 160 180 200
          Mass/Charee
          33
          Acetophenonc
          • (PBM
          Reference Spectrum)
          60 80 100 120 140 160 180 200
          Mass/Charee
          Scan 982 (10.995 min> of YP773.d 
          ro
          CO
          »
          s
          1
          1 p
          .00
          -»
          S
          ll
          1
          W.W^ • | ... | ... | ........ | .
          10.6 10.8 11.0 11.2 11.4
          Time (min.)
          3.2-;
          2.8-j
          2.4-;
          2.0-
          *^i
          Sl.6^
          X
          :i.2-
          0.8:
          0.4:
          Ort-
          Mass 77.
          i
          . .A ni 1
          00
          1
          o
          iH
          uw.
          1
          10.6 10.8 11.0 11.2 11.4
          Time (min.)
          6.0-j
          5.5-j
          5.0-1
          4.5-^
          4.0-i
          R'-SI
          o3.0-i
          X 0 C :
          <— 2.0-
          *• 2.0-j
          1.5-1
          i.o-i
          0.54
          0 0-=
          Mass 120
          hw
          1
          1
          u li il
          .00
          •*.
          s
          il 1
          10.6 10.8 11.0 11.2 11.4
          Time (min.)
          

          -------
           Data File: /chem/Y.i/10-22-97.b/Cflft/YP773.d
           Date : 22-OCT-1997  17:30
           Instrument : Y.i
           Sample ID : SBLK  101497
           Column phase : DB.5-625
           Volume Injected 
            : 1.0 51 2-Chloroacetophenone Page 12 Column diameter : 0.32 Scan 1386 (13.863 min) of YP773.d e.o-i 5.0-i s4-0^ i3-°i ~2.- * 1.0- 0 0- .1. . 1 1 i 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Mass/Charee 51 2-Chloroacetophenone (PBM Reference Spectrum) 8.0-J : P> ^x4.0- >_ 2.0- 0.0- % ..1 . 1 . ..il .1, .1 1 , 1 , , i 1 . . . , 1 i i i | i I i , . , l . , l i i i | i i 1 1 1 1 1 1 ,....,.... , ... 1 1 1 1 1 1 1 ....,, 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Mass/Charge Scan 1386 (13.863 min) of YP773.d (Z DIFFERENCE) 100 -q 75 -i so -i 25-i S-25-; ~-50-i -75 -i 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Mass/Charee Mass 105.00 6.0-; 5.0- ^4.0-; S3.0J X * • *••> ft 2.0- 1ft- .w 0.0- p3 II -rH gj CM1""; (1 ^ II /\'A 1 S 2 ' Jv. /VW ^^ *\^ .. , 13.40 13.60 13.80 14.00 14.20 Time (min.) Mass 77.00 3.2- 2.8- 2.4- ^2.0- <^ sx >-1.2-j 0.8-i 0.4-j 0.0- h-*-O fs 1 0^ * Iro s7 t._ *-* ro 8 ^1 A A I U\ R/UAA u K V*w »/ vvjv\ T ''it11' i™i | i' ' 13.40 13.60 13.80 14.00 14.20 Time (min.) Mass 51.00 2.0-i 1.8-j 1.6H 1.4-^ ~12^ Sl.O-i •^0.8-i ^ 0.6^ 0.4-i 0.2^ — ^o °^ 53 1 ?5 "•".S (1 ^k 11 *|/l fO . •V Jl " LA AA. , A 1 \i A i y i y y ij*fl w \jjy f\i 13.40 13.60 13.80 14.00 14.20 Time (min.)

          -------
           Data File: /che«/Y.i/10-22-97.b/CfilVYP773.d
           Date : 22-OCT-1997 17:30
           Instrument : Y.i
           Sample ID : SBLK  101497
           Column phase :  DB.5-625
           Volume Injected 
            : 1.0 66 Di-n-butylphthalate Page 15 Column diameter : 0.32 Scan 2361 (20.781 min) of YP773.d 4.0- 3.0- XX •* 32.0- XX 0 0~ • 1 ill . Illl 1. . .1. . . H 40 60 80 100 120 140 | i.. i 160 180 200 220 Mass/Charee Scan 2361 (20.781 min) of YP773.d (Subtracted) 4.0-i 3.0-i 5 < S2.0- X XX >. 1.0- 0 0- i III , .il i. .1. . . il 40 60 80 100 120 140 i —i f-i r-*- 160 180 200 220 Mass/Charee 66 Di-n-butylphthalate (PBM Reference Spectrum) • 8.0- xx 6.0- r-o * • XX 2*°~ 0.0- i! . ,n i i. i ii h. 1 . 1 1 1 1 . 1 , . . . 1 1 . . , I . 1 1 1 • 1 i . | . i • | . . , | i . . | 40 60 80 100 120 140 160 180 200 220 Mass/Charee Scan 2361 (20.781 min) of YP773.d (Z DIFFERENCE) 100- 75- 50- 25- £ 0- S-25- "-50- -75- " - .-,- .-. .- ~... — r- 40 60 80 100 120 140 160 180 200 220 Mass/Charee Mass 149.00 4.4-^ 4.0-i 3.6-i 3.2-; 2.8-; ?2.4-i XX >.1.6-i 1.2-j 0.8-i 0.4-: 0 0- l ~00 * a ' * • * 20.4 20.6 20.8 21.CT 21.2 Time (min.) Mass 150.00 4.4-q 4.0- 3.6- 3.2- 2.8- £2.4- ^2.0- ^•61 1.2-i 0.8- 0.4-i H CO o CJ 20.4 20.6 20.8 21.0 21.2 Time (min.) Mass 104.00 2.0-i 1.8-i 1.6-j • 1.4-i S * ^ x * '• ,,.0.8- 0.6-i 0.4-i 0.2-i 0 0- 1 , , r,r JU, •^r » S 1, ,-,... JU . . 20.4 20.6 20.8 21.0 21.2 Time (min.)

          -------
           Data File: /chem/Y.i/10-22-97.b/CflA/YP773.d
           Date : 22-OCT-1997 17:30
           Instrument : Y.i
           Sample ID : SBLK  101497
           Column phase :  DB.5-625
           Volume Injected \
          dj|
          l*||
          T
          1 \
          ^ A/1 I Hi A
          25.00 25.20 25.40 25.60 25.80
          Time (min.)
          Mass 167.00
          1.6-
          1.4-
          1.2-
          XX
          IV)
          So.8-
          X
          ^0.6-
          0.4-;
          0 ?-
          
          0 0—
          1 LO
          1 ro
          •OT in
          r
          
          
          
          i j
          
          
          I
          in U i
          25.00 25.20 25.40 25.60 25.80
          Time (min.)
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          
          

          -------
                                                 Triangle Laboratories of RTF, Inc.
                                                   Continuing Calibration Curve
          CCAL File: YP766
          ICAL File: ICALYO22
          Date of Analysis :10/22/97     Analyte List: 8270A
          -, % '•''S \ \ ** ^ v. *•
          Naphthalene-d8
          Naphthalene
          2-Methylnaphthalene
          Acenaphthene-d 10
          2-Chloronaphthalene
          Acenaphthylene
          Acenaphthene
          Fluorene
          Phenanthrene-d 10
          Phenanthrene
          Anthracene
          Fluoranthene
          Chrysene-dl2
          Pyrene
          Benzo(a)anthracene
          Chrysene
          Perylene-dl2
          Benzo(b)fluoranthene
          Benzo(k)fluoranthene
          Benzo(e)pyrene
          Benzo(a)pyrene
          Perylene
          Indeno( l,23-cd)pyrene
          Dibenz(a,h)anthracene
          Benzo(g,h,i)perylene
          i^sVstaj^a^ ^
          *^\0^1V4
          I
          
          
          I
          
          
          C
          
          I
          
          
          C
          I
          
          
          
          I
          
          
          
          C
          
          
          
          
          £$R'
          
          1.050
          0.638
          
          1.105
          1.777
          1.063
          1.082
          
          1.021
          0.967
          1.030
          
          1.293
          1.106
          1.086
          
          0.932
          0.977
          1.013
          0.909
          0.989
          1.038
          0.787
          0.963
          RSMEAN
          
          1.031
          0.675
          
          1.098
          1.799
          1.054
          1.079
          
          1.033
          0.990
          1.064
          
          1.278
          1.098
          1.080
          
          1.003
          1.002
          1.048
          0.946
          1.004
          1.075
          0.823
          0.974
          "SsST'^^
          
          -1.8
          5.5
          
          -0.6
          1.2
          -0.9
          -0.3
          
          1.2
          2.3
          3.2
          
          -1.2
          -0.7
          -0.6
          
          7.1
          2.5
          33
          3.9
          15
          3.4
          4.4
          1.1
          Surrogate ' flag = * Kf SO JBlMJ&tt' ]'*& \ . ,
          Phenol-d5
          Nitrobenzene-d5
          l,3,5-Trichlorobenzene-d3
          l,4-Dibromobenzene-d4
          2-Fluorobiphenyl
          2,4,6-Tribromophenol
          Anthracene-d 10
          Pyrene-dlO
          Terphenyl-dl4
          .s
          s
          s
          s
          s
          s
          s
          s
          s
          1.696
          0.379
          0.341
          0.976
          1.237
          0.272
          1.054
          1.202
          0.778
          1.664
          0386
          0.348
          0.943
          1.230
          0.276
          1.063
          1.214
          0.782
          -1.9
          1.8
          2.0
          -35
          -0.6
          1.4
          0.8
          1.0
          05
          Approved by:.
                     Date  U / IJ> m
                            *- Fails QC Criteria for %D;« - Rf leas than minimum QC RF;»- RF greater than maximum QC RF
          Triangle Laboratories of RTF, Inc
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                  Savarv3.5
          

          -------
                                                 Triangle Laboratories of RTF, Inc.
                                                   Continuing Calibration Curve
          CCALFile:YP783
          ICAL File: ICALYO22
          Date of Analysis :10/23/97     Analyte List: 8270A
          \M Ivi '^ -v "-;:
          1 , y ^^ ,
          Naphthalene-d8
          Naphthalene
          2-Methylnaphthalene
          Acenaphthene-dlO
          2-Chloronaphthalene
          Acenaphthylene
          Acenaphthene
          Fluorene
          Phenanthrene-dlO
          Phenanthrene
          Anthracene
          Fluoranthene
          Chrysene-dl2
          Pyrene
          Benzo(a)anthracene
          Chrysene
          Perylene-dl2
          Benzo(b)fluoranthene
          Benzo(k)fluoranthene
          Benzo(e)pyrene
          Benzo(a)pyrene
          Perylene
          Indeno(l,2,3-cd)pyrene
          Dibenz(a,h)anthracene
          Benzo(g,h,i)perylene
          Sarrogate
          Phenol-d5
          Nitrobenzene-d5
          l,3,5-Trichlorobenzene-d3
          l,4-Dibromobenzene-d4
          2-Fluorobiphenyl
          2,4/6-Tribromophenol
          Anthracene-dIO
          Pyrene-dlO
          Terphenyl-dl4
          "iHtat '
          ^ «*
          I
          
          
          I
          
          
          C
          
          I
          
          
          c
          I
          
          
          
          I
          
          
          
          c
          
          
          
          
          flag
          ,S
          S
          s
          s
          s
          s
          s
          s
          s
          RF50
          V
          
          1.012
          0.663
          
          1.088
          1.784
          1.051
          1.163
          
          1.022
          ' 0.969
          1.051
          
          1.313
          1.094
          1.062
          
          0.983
          0.962
          1.049
          0.922
          0.979
          1.078
          0.810
          0.979
          RF50
          1.681
          0.377
          0.332
          0.930
          1.242
          0.298
          1.073
          1.176
          0.817
          £&£&*&•' $
          	 >>f.\. .?..>.. ; **••
          
          1.031
          0.675
          
          1.098
          1.799
          1.054
          1.079
          
          1.033
          0.990
          1.064
          
          1.278
          1.098
          1.080
          
          1.003
          1.002
          1.048
          0.946
          1.004
          1.075
          0.823
          0.974
          RFMEAN
          1.664
          0.386
          0.348
          0.943
          1.230
          0.276
          1.063
          1.214
          0.782
          K%0 - --;F^ - A-^i ? " v ^-% -r r v * , ^fe:t$?: ,v^i
          »^. '^.. ''*SS.. ^ss ^ s" ^^ X ' ' ' ** s *%^ * '"^S S^** "** * - x VI
          
          1.8
          1.8
          
          0.9
          0.8
          0.3
          -7.8
          
          1.1
          2.1
          1.2
          
          -2.7
          0.4
          1.7
          
          2.0
          4.0
          -0.1
          2.5
          2.5
          -0.3
          1.6
          -0.5
          1 %B - ** < , : ^ \
          -1.0
          2.3
          4.6
          1.4
          -1.0
          -8.0
          -0.9
          3.1
          -4.5
          Approved by:.
                    .Date_ii_/_il/22_
                            *• Fails QC Criteria for %D;« - Rf leas than minimum QC RF;»- RF greater than maximum QC RF
          Triangle Laboratories of RTF, Inc.
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                  Savar v3.5
          

          -------
                                                 Triangle Laboratories of RTF, Inc.
                                                     Initial Calibration Curve
          ICAL File: ICALYO22
          RF20 YP767
          RF120 YP764
          Date of Analysis
          RFSO YP766
          RF160 YP763
          -.10/22/97
          Analyte List: 8270A
          RFSO YP765
          
          Analyte , , %\\^ ••"'
          •> * *
          Naphthalene-d8
          Naphthalene
          2-Methylnaphthalene
          Acenaphthene-dlO
          2-Chloronaphthalene
          Acenaphthylene
          Acenaphthene
          Fluorene
          Phenanthrene-dlO
          Phenanthrene
          Anthracene
          Fluoranthene
          Chrysene-dl2
          Pyrene
          Benzo(a)anthracene
          Chrysene
          Perylene-dl2
          Benzo(b)fluoranthene
          Benzo(k)fluoranthene
          Benzo(e)pyrene
          Benzo(a)pyrene
          Perylene
          Indeno(l,23-cd)pyrene
          Dibenz(a,h)anthracene
          Benzo(g,h,i)perylene
          I Surrogate
          Phenol-d5
          Nitrobenzene-d5
          l,3,5-Trichlorobenzene-d3
          l,4-Dibromobenzene-d4
          2-Fluorobiphenyl
          2,4,6-Tribromophenol
          Anthracene-dlO
          Pyrene-dlO
          Terphenyl-dl4
          1 flag *
          I
          
          
          I
          
          
          C
          
          I
          
          
          C
          I
          
          
          
          I
          
          
          
          C
          
          
          
          
          flag
          S
          's
          S
          S
          S
          S
          S
          S
          S
          *t$fcp
          
          1.076
          0.683
          
          1.201
          1.781
          1.093
          1.094
          
          1.025
          1.013
          1.038
          
          1.308
          1.149
          1.136
          
          1.044
          1.048
          1.117
          0.985
          1.041
          1.076
          0.836
          1.003
          KF2D
          1.646
          0.372
          0.379
          0.958
          1.282
          0.265
          1.089
          1.278
          0.804
          S&
          
          1.050
          0.638
          
          1.105
          1.777
          1.063
          1.082
          
          1.021
          0.967
          1.030
          
          1.293
          1.106
          1.086
          
          0.932
          0.977
          1.013
          0.909
          0.989
          1.038
          0.787
          0.963
          RFSO
          1.696
          0.379
          0.341
          0.976
          1.237
          0.272
          1.054
          1.202
          0.778
          *$g
          
          1.019
          0.671
          
          1.034
          1.742
          1.019
          1.028
          
          1.022
          0.996
          1.036
          
          1317
          1.093
          1.100
          
          1.005
          0.998
          1.020
          0.943
          0.996
          1.059
          0.804
          0.963
          RFSO
          1.692
          0.374
          0.333
          0.954
          1.192
          0.273
          1.025
          1.224
          0.795
          v s <•---'•
          
          0.946
          0.682
          
          1.091
          1.911
          1.041
          1.122
          
          1.079
          0.985
          1.118
          
          1.210
          1.024
          1.040
          
          1.000
          0.938
          1.015
          0.917
          0.956
          1.081
          0.827
          0.959
          RF120
          1.622
          0.387
          0.325
          0.885
          1.240
          0.291
          1.116
          1.171
          0.754
          m^MEA^r ^itscK-y-^^;^^^^
          
          1.063
          0.699
          
          1.057
          1.785
          1.053
          1.071
          
          1.019
          0.988
          1.096
          
          1.264
          1.119
          1.036
          
          1.035
          1.048
          1.077
          0.977
          1.038
          1.120
          0.858
          0.982
          RF160
          1.666
          0.418
          0.360
          0.941
          1.201
          0.280
          1.031
          1.197
          0.779
          
          1.031
          0.675
          
          1.098
          1.799
          1.054
          1.079
          
          1.033
          0.990
          1.064
          
          1.278
          1.098
          1.080
          
          1.003
          1.002
          1.048
          0.946
          1.004
          1.075
          0.823
          0.974
          Mean
          1.664
          0.386
          0.348
          0.943
          1.230
          0.276
          1.063
          1.214
          0.782
          
          5.1
          3.4
          
          5.8
          3.6
          2.6
          3.2
          
          2.5
          1.7
          3.8
          
          3.4
          4.2
          3.9
          
          4.4
          4.7
          4.5
          3.6
          3.6
          2.8
          3.4
          1.9
          %fc$& ,
          1.9
          4.8
          6.3
          3.7
          2.9
          3.6
          3.7
          3.3
          2.5
          Approved by:.
          .DateJi_/_i3_/fLl
                           *- Fails QC Criteria for %RSD; « - Rf less than minimum QC RF;»- RF greater than maximum QC RF
          Triangle Laboratories of RTF, Inc.
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544.5729 • Fax: (919) 544-5491
                                                                          Savar v3.5
          

          -------
                                 Triangle Laboratories of RTF, Inc.
                                   Continuing Calibration Curve
          1 CCAL File: YP771 Date of Analysis :10/22/97
          CAL File: ICALYO22
          Analyte List: 8270A
          •
          JA»aJyfe , -'; r ^ > , $*S:s;
          .,4 Dichlorobenzene-d4 I
          n-Nitrosodimethylamine
          Cumene
          'henol C
          Aniline
          bis-(2-Chloroethyl)ether
          Jenzyl Chloride
          1,4-Dichlorobenzene C
          2-Methylphenol
          \cetophenone
          i-Nitrosomorpholine
          o-Toluidine
          Hexachloroethane
          L,2-Dibromo-3-chloropropane
          vJ,N-Diethylaniline
          Naphthalene-d8 I
          1 /4-Methylphenol
          Nitrobenzene
          N,N-Dimethylaniline
          Tsophorone
          )-Anisidine
          x,4-Phenylenediamine
          1,2,4-Trichlorobenzene
          iexachlorobutadiene C
          i,a,a-Trichlorotoluene
          Hydroquinone
          *!-Chloroacetophenone
          Vcenaphthene-dlO I
          Hexachlorocyclopentadiene . P
          7.,4,6-Trichlorophenol C
          !,4/5-Trichlorophenol
          3iphenyl
          Dimethylphthalate
          !,4-DinitrophenoI P
          l-Nitrophenol P
          2,4-Dinitrotoluene
          Oibenzofuran
          l,6-Dinitro-2-methylphenol
          ;';JH* *
          
          0.616
          2.248
          1.390
          1.695
          0.802
          2.226
          1.384
          1.076
          1.517
          0.618
          1.709
          0.655
          0.622
          1.816
          
          0.306
          0.488
          0.482
          0.582
          0.267
          0.368
          0.318
          0.186
          0.391
          0.356
          0.733
          
          0.330
          0.363
          0.418
          1.337
          1.149
          0.094
          0.246
          0.321
          1.486
          0.145
          A •« •* •• $f
          
          0.600
          2.203
          1.330
          1.676
          0.797
          2.193
          1.325
          1.029
          1.442
          0.597
          1.651
          0.629
          0.610
          1.707
          
          0.312
          0.477
          0.474
          0.576
          0.260
          0.357
          0.318
          0.183
          0.386
          0.357
          0.719
          
          0.336
          0.351
          0.396
          1.296
          1.090
          0.121
          0.260
          0325
          1.495
          0.175
          ^m >>%r^'- ^^;^SJV?^^?^
          
          -2.7
          -2.0
          -4.5
          -1.1
          -0.6
          -1.5
          -4.5
          -4.6
          -5.2
          -3.5
          -3.5
          -4.1
          -2.0
          -6.4
          
          1.9
          -2.3
          -1.7
          -1.0
          -2.7
          -3.1
          0.0
          -1.6
          -1.3
          0.3
          -1.9
          
          1.8
          -3.4
          -5.6
          -3.2
          -5.4
          22.3
          5.4
          1.2
          0.6
          17.1
          *- Fails QC Criteria for %D; « - Rf less than minimum QC RF; »- RF greater than maximum QC RF
          Triangle Laboratories of RTF, Inc
          "01 Capitola Drive • Durham, North Carolina 27713
           •hone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                                       Savar v3.5
          

          -------
                                                  Triangle Laboratories of RTF, Inc.
                                                    Continuing Calibration Curve
          CCAL File: YP771              Date of Analysis -.10/22/97     Analyte List: 8270A
          ICAL File: ICALYO22
          ^rte ; ^
          Trifluralin
          E&tf^' *B$5o I^MEAMT *
          ^•^ *W|J.-> i^., ., •. v£ f ••
          0.199
          0.211
          ^1.;^!';; *'* iy:,\ \^^*Y,vj
          5.7
          Phenanthrene-dlO             I
          Di-n-butylphthalate                    1.537       1.432        -7.3
          Hexachlorobenzene                    0.337       0.299      -12.7
          4-Aminobiphenyl                      0.791       0.736        -7.5
          Pentachlorophenol            C       0.177       0.178        0.6
          Pentachloronitrobenzene                0.084       0.079        -6.3
          4-Nitrobiphenyl                        0310       0.281      -10.3
          Chrysene-dl2                 I
          Benzidine                              0.758       0.766        1.0
          4,4'-Methylenedianiline                 0323       0.321        -0.6
          Dimethylaminoazobenzene             0.375       0.370        -1.4
          33'-Dimethylbenzidine                 0.605       0.568        -6.5
          33'-Dimethoxybenzidine                0.293       0.282        -3.9
          33'-Dichlorobenzidine                  0.444       0.434        -2.3
          Methylene bis-chloroaniline             0.197       0.185        -6.5
          bis(2-Ethylhexyl)phthalate              0.944       0.946        0.2
           Approved by:	._^>{4-VC     Date   'v / '.
                            •- Fails QC Criteria for %D;« - Rf ICM than minimum QC RF;»- RF greater than maximum QC RF
          
           Triangle Laboratories of RTF, Inc                                                                               Savar v3.5
           801 Capitola Drive • Durham, North Carolina 27713                                                                 O 1 O
          

          -------
                                                  Triangle Laboratories of RTF, Inc.
                                                    Continuing Calibration Curve
          ICCAL File: YP784
           ICAL File: ICALYO22
          Date of Analysis -.10/23/97    Analyte List: 8270A
          %W\^..^ ?'$$£**]£$
          1,4 Dichlorobenzene-d4 I
          n-Nitrosodimethylamine
          Cumene
          Phenol C
          Aniline
          bis-(2-Chloroethyl)ether
          Benzyl Chloride
          1,4-Dichlorobenzene C
          2-Methylphenol
          Acetophenone
          n-Nitrosomorpholine
          o-Toluidine
          Hexachloroethane
          l,2-Dibromo-3-chloropropane
          N,N-Diethylaniline
          Naphthalene-d8 I
          3/4-Methylphenol
          Nitrobenzene
          N,N-Dimethylaniline
          Isophorone
          o-Anisidine
          1,4-PhenyIenediamine
          1,2,4-Trichlorobenzene
          Hexachlorobutadiene C
          a,a,a-Trichlorotoluene
          Hydroquinone
          2-Chloroacetophenone
          Acenaphthene-dlO I
          Hexachlorocyclopentadiene - P
          2,4,6-Trichlorophenol C
          2,4,5-Tri'chlorophenol
          Biphenyl
          Dimethylphthalate
          2,4-Dinitrophenol P
          4-Nitrophenol P
          2,4-Dinitrotoluene
          Dibenzofuran
          l,6-Dinitro-2-methylphenol
          ' 1*'ts •.
          
          0.584
          2.289
          1.309
          1.742
          0.814
          2.230
          1.337
          1.021
          1.480
          0.605
          1.665
          0.637
          0.613
          1.702
          
          0.356
          0.518
          0.538
          0.616
          0.294
          0.372
          0.325
          0.199
          0.421
          0.353
          0.766
          
          0.308
          0.360
          0.384
          1.364
          1.121
          0.124
          0.271
          0.329
          1.400
          0.166
          jMJJAN'-'W
          
          0.600
          2.203
          1.330
          1.676
          0.797
          2.193
          1.325
          1.029
          1.442
          0.597
          1.651
          0.629
          0.610
          1.707
          
          0.312
          0.477
          0.474
          0.576
          0.260
          0.357
          0.318
          0.183
          0.386
          0.357
          0.719
          
          0.336
          0.351
          0.396
          1.296
          1.090
          0.121
          0.260
          0.325
          1.495
          0.175
          \-$ySt£K^fy'$;f" " * s^V \ , « -v* ^J"""^ - ^"Vi|^\- ^1
          » ..v ^ v ^ •*•.•. "•s^."xv<% *»*^^^^X^" " V^>-^-xr-|
          
          2.7
          -3.9
          1.6
          -3.9
          -2.1
          -1.7
          -0.9
          0.8
          -2.6
          -1.3
          -0.8
          -1.3
          -0.5
          0.3
          
          -14.1
          -8.6
          -135
          -6.9
          -13.1
          -4.2
          -2.2
          -8.7
          -9.1
          1.1
          -6.5
          
          8.3
          -2.6
          3.0
          -5.2
          -2.8
          -2.5
          -4.2
          -1.2
          6.4
          5.1
                             *- Fails QC Criteria for %D;« - Rf lesa than minimum QC RF; »- RF greater than maximum QC RF
           Triangle Laboratories of RTF, Inc
           301 Capitola Drive • Durham, North Carolina 27713
           Phone: (919) 544-5729 • Fax; (919) 544-5491
                                                                                    Savar v3.5
          

          -------
                                                  Triangle Laboratories of RTF, Inc.
                                                    Continuing Calibration Curve
          CCALFile:YP784              Date of Analysis :10/23/97     Analyte List: 8270A
          ICALFile:ICALYO22
          Trifluralin                             0.222       0.211       -5.2
          Phenanthrene-dlO             I
          Di-n-butylphthalate                     1.416       1.432        1.1
          Hexachlorobenzene                     0307       0.299       -2.7
          4-Aminobiphenyl                       0.735       0.736        0.1
          Pentachlorophenol            C        0.173       0.178        2.8
          Pentachloronitrobenzene                0.079       0.079        0.0
          4-Nitrobiphenyl                        0.286       0.281       -1.8
          Chrysene-dl2                 I
          Benzidine                             0.792       0.766       -3.4
          4,4'-Methylenedianiline                 0.325       0.321       -1.2
          Dimethylaminoazobenzene             0.366       0.370        1.1
          3,3'-Dimethylbenzidine                 0.643       0.568      -13.2
          3,3'-Dimethoxybenzidine                0.320       0.282      -135
          3,3'-Dichlorobenzidme                  0.432       0.434        0.5
          Methylene bis-chloroaniline             0.187       0.185       -1.1
          bis(2-Ethylhexyl)phthalate              0.955       0.946       -1.0
           Approved by:	~*&          Date _JL/_!i/!2_
                            *- Fails QC Criteria for %D;« - Rf lea* than minimum QC RF;»- RF greater than maximum QC RF
          
           Triangle Laboratories of RTF, Inc                                                                               Savar v3.5
           801 Capitola Drive • Durham, North Carolina 27713
          

          -------
                                                   Triangle Laboratories of RTF, Inc.
                                                       Initial Calibration Curve
          TCAL File: ICALYO22 Date of Analysis -.10/22/97
          P20 YP772 RF50 YP771
          RF120 YP769 RF160 YP768
          Analyte List: 8270A
          RF80 YP770
          .
          Ana^ V ;;^^%g;
          ,4 Dichlorobenzene-d4 I
          n-Nitrosodimethylamine
          Cumene
          henol C
          4lniline
          bis-(2-Chloroethyl)ether
          enzyl Chloride
          ,4-Dichlorobenzene C
          2-Methylphenol
          \cetophenone
          -Nitrosomorpholine
          o-Toluidine
          Hexachloroethane
          ,2-Dibromo-3-chloropropane
          . J,N-Diethylaniline
          Naphthalene-d8 I
          /4-Methylphenol
          litrobenzene
          N,N-Dimethylaniline
          T".ophorone
          -Anisidine
          1,4-Phenylenediamine
          1,2,4-Trichlorobenzene
          texachlorobutadiene C
          _,a,a-Trichlorotoluene
          Hydroquinone
          -Chloroacetophenone
          .cenaphthene-dlO I
          Hexachlorocyclopentadiene - P
          °,4,6-Trichlorophenol C
          ,4,5-Trichlorophenol
          oiphenyl
          Dimethylphthalate
          ,4-Dinitrophenol P
          .-Nitrophenol P
          2,4-Dinitrotoluene
          "Hbenzofuran
          ,6-Dinitro-2-methylphenol
          ?\F^
          
          0.550
          2.256
          1.287
          1.645
          0.821
          2.203
          1.383
          0.963
          1.499
          0.610
          1.668
          0.629
          0.619
          1.703
          
          0.317
          0.480
          0.480
          0.559
          0.269
          0.358
          0.338
          0.188
          0.375
          0.363
          0.713
          
          0.292
          0.326
          0.365
          1.278
          1.059
          
          
          0.281
          1.508
          
          Rfso
          
          0.616
          2.248
          1.390
          1.695
          0.802
          2.226
          1.384
          1.076
          1.517
          0.618
          1.709
          0.655
          0.622
          1.816
          
          0306
          0.488
          0.482
          0.582
          0.267
          0368
          0318
          0.186
          0391
          0356
          0.733
          
          0.330
          0.363
          0.418
          1.337
          1.149
          0.094
          0.246
          0.321
          1.486
          0.145
          *JH*;
          
          0593
          2.078
          1.278
          1.642
          0.758
          2.159
          1.292
          1.005
          1.389
          0579
          1597
          0.615
          0.599
          1.615
          
          0.317
          0.479
          0.468
          0.574
          0.247
          0.355
          0.315
          0.181
          0.390
          0358
          0.676
          
          0.344
          0.334
          0378
          1.215
          1.037
          0.105
          0.240
          0317
          1.483
          0.159
          OK*
          
          0.620
          2.195
          1366
          1.714
          0.772
          2.139
          1.274
          1.062
          1.454
          0.601
          1.712
          0.621
          0.609
          1.701
          
          0.295
          0.469
          0.473
          0.565
          0.257
          0348
          0.306
          0.178
          0.369
          0.341
          0.696
          
          0.363
          0364
          0.409
          1.341
          1.116
          0.130
          0.263
          0.341
          1.478
          0.186
          |»fcj
          
          0.621
          2.238
          1329
          1.686
          0.832
          2.237
          1.294
          1.040
          1.352
          0.579
          1.569
          0.623
          0.599
          1.700
          
          0.325
          0.471
          0.468
          0.601
          0.260
          0.354
          0.313
          0.182
          0.404
          0.368
          0.779
          
          0.353
          0.371
          0.409
          1.311
          1.088
          0.155
          0.291
          0.363
          1.522
          0.207
          rfEAN
          
          0.600
          2.203
          1.330
          1.676
          0.797
          2.193
          1.325
          1.029
          1.442
          0597
          1.651
          0.629
          0.610
          1.707
          
          0312
          0.477
          0.474
          0.576
          0.260
          0.357
          0.318
          0.183
          0386
          0.357
          0.719
          
          0.336
          0.351
          0.396
          1.296
          1.090
          0.121
          0.260
          0.325
          1.495
          0.175
          ^^M;\Sr^l
          
          5.1
          33
          3.7
          1.9
          3.9
          1.9
          4.0
          4.4
          4.9
          3.0
          4.0
          2.5
          1.8
          4.2
          
          3.8
          1.6
          1.4
          2.8
          3.4
          2.1
          3.8
          2.2
          3.6
          2.9
          5.5
          
          8.2
          5.7
          5.7
          4.0
          4.1
          22.5
          8.8
          9.4
          1.2
          15.9
                           *- Fails QC Criteria for %RSD;« - Rf less than minimum QC RF;»- RF greater than maximum QC RF
          Triangle Laboratories of RTF, Inc
          ""!! Capitola Drive • Durham, North Carolina 27713
           lone: (919) 544-5729 • Fax: (919) 544-5491
               Savar v35
          

          -------
                                                  Triangle Laboratories of RTF, Inc.
                                                      Initial Calibration Curve
          ICAL File: ICALYO22
          RF20  YP772
          RF120 YP769
                                        Date of Analysis -.10/22/97
                                        RF50  YP771
                                        RF160 YP768
          Analyte List: 8270A
          RF80  YP770
          £aalyfceA> \ > ->-" .4- ^ fj> ^v^|t
               •.   x %    ^.^..^...^X.^l^.'i.. ^< Y^.l:s^K
                                                      , % JtfSO /.
          Trifluralin
          Phenanthrene-dlO
          Di-n-butylphthalate
          Hexachlorobenzene
          4-Aminobiphenyl
          Pentachlorophenol
          Pentachloronitrobenzene
          4-Nitrobiphenyl
          Chrysene-dl2
          Benzidine
          4,4'-Methylenedianiline
          Dimethylaminoazobenzene
          S/S'-Dimethylbenzidine
          33'-Dimethoxybenzidine
          33'-Dichlorobenzidine
          Methylene bis-chloroaniline
          bis(2-Ethylhexyl)phthalate
                                                 0.163   0.199   0.210  0235   0.249  0.211  15.8
          
                                                 1.290   1537   1388  1371   1575  1.432   8.4
                                                 0.291   0.337   0.285  0.285   0.297  0.299   73
                                                 0.711   0.791   0.727  0.709   0.743  0.736   4.6
                                                        0.177   0.172  0.174   0.187  0.178   35
                                                 0.072   0.084   0.079  0.078   0.082  0.079   6.0
                                                 0.199   0.310   0.284  0.292   0.317  0.281  16.9
          
                                                 0.662   0.758   0.747  0.768   0.894  0.766  10.9
                                                 0.258   0.323   0.316  0.323   0386  0.321  14.2
                                                 0316   0.375   0.375  0.377   0-408  0.370   9.0
                                                 0.472   0.605   0.573  0.522   0.670  0.568  13.4
                                                 0.211   0.293   0.295  0.289   0321  0.282  14.8
                                                 0.412   0.444   0.422  0.414   0.481  0.434   6.6
                                                 0.164   0.197   0.186  0.177   0.200  0.185   8.1
                                                 0.844   0.944   0.957  0.938   1.046  0.946   7.6
          Approved by:.
                                                   Date   li in  /?7
                           *- Fails QC Criteria for %RSD; « - Rf less than minimum QC RF; »• RF greater than maximum QC RF
          Triangle Laboratories of RTF, Inc
          801 Capitola Drive • Durham, North Carolina 27713
          Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                                                   Savarv3.5
          

          -------
          TECHNICAL REPORT DATA
          Please read instructions on the reverse before completing
          1. REPORT NO.
          EPA-454/R-99-025
          2.
          4. TITLE AND SUBTITLE
          Final Report - Volume I of II, Iron and Steel Foundries Manual Emissions Testing, Cupola Wet
          Scrubber - General Motors Corp., Saginaw, Michigan
          7. AUTHOR(S)
          Franklin Meadows
          Daniel F. Scheffel
          9. PERFORMING ORGANIZATION NAME AND ADDRESS
          Pacific Environmental Services, Inc.
          Post Office Box 12077
          Research Triangle Park, North Carolina 27709-2077
          1 2. SPONSORING AGENCY NAME AND ADDRESS
          U.S. Environmental Protection Agency
          Office of Air Quality Planning and Standards
          Emissions, Monitoring and Analysis Division
          Research Triangle Park, North Carolina 2771 1
          3. RECIPIENT'S ACCESSION NO.
          5. REPORT DATE
          July 1999
          6. PERFORMING ORGANIZATION CODE
          8. PERFORMING ORGANIZATION REPORT NO.
          10. PROGRAM ELEMENT NO.
          11. CONTRACT/GRANT NO.
          68-D-70069
          13. TYPE OF REPORT AND PERIOD COVERED
          Final
          14. SPONSORING AGENCY CODE
          15. SUPPLEMENTARY NOTES
          16. ABSTRACT
          The United States Environmental Protection Agency (EPA) is investigating iron and steel foundries to identify and quantify hazardous air pollutants
          (HAPs) emitted from cupolas; electric arc furnaces; and pouring, cooling and shakedown operations of sand mold casting processes. General Motors
          Corporation, Saginaw Casting Operations (GMC), Saginaw, Michigan was selected by the EPA as the host facility at which to 1) characterize HAP
          emissions from cupolas that are controlled by wet scrubbers, and 2) assess wet scrubber performance in controlling HAP emissions from cupolas. GMC
          was selected because EPA deemed this facility to be representative of a large segment of the sand casting foundry industry and GMC operates a relatively
          large cupola that is controlled by a wet scrubber.
          This report presents the results of a manual emissions testing program to characterize emissions from a cupola and assess the performance of the wet
          scrubber in controlling HAP emissions. Testing was conducted at the cupola wet scrubber inlet and outlet to determine air emissions of paniculate
          matter (PM) and metal HAPs; and at the cupola wet scrubber outlet to determine organic HAPs consisting of dibenzo-p-dioxins and polychlorinated
          dibenzodurans (PCDDs/PCDFs) and semi-volatile organic hazardous air pollutnats (SVOHAPs), and volatile organic hazardous air pollutants (VOHAPs)
          The data may be used by the EPA as potential Maximum Achievable Control Technology (MACT) floor technology for cupolas.
          During the testing program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission control system
          operating parameters, and prepared Section 3.0, Process and Control Equipment operation, of this report.
          This volume (Volume I) is comprised of 688 pages and consists of the report text, and Appendices: A (Raw Field Data) and B (Analytical Data -
          PCDFs/PCDDs and SVOHAPs).
          17. KEY WORDS AND DOCUMENT ANALYSIS
          a. DESCRIPTIONS
          Cupola
          Dioxins/Furans
          Emission Measurements
          Hazardous Air Pollutants
          Metals
          Particulate Matter
          Semi-Volatile Organic Hazardous
          Air Pollutants
          Volatile Organic Hazardous Air
          Pollutants
          Wet Scrubber
          18. DISTRIBUTION STATEMENT
          Unlimited
          b. IDENTIFIERS/OPEN ENDED TERMS
          
          19. SECURITY CLASS (This Report)
          Unclassified
          20. SECURITY CLASS (This page)
          Unclassified
          c. COASTI Field/Group
          
          21. NO. OF PAGES
          1,159
          22. PRICE
          EPA Form 2220-1 (Rev. 4-77)  PREVIOUS EDITION IS OBSOLETE
          

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