Iron and Steel Foundries Manual Emissions Testing, Cupola Wet Scrubber, General Motors Corp., Saginaw, Michigan ; Final Report- Volume II of II


United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
July 1999
AIR
       EPA
   Final Report - Volume II of II

   Iron and Steel Foundries
   Manual Emissions Testing
   Cupola Wet Scrubber
   General Motors Corp.

-------
                FINAL REPORT

         IRON AND STEEL FOUNDRIES
         MANUAL EMISSIONS TESTING
            CUPOLA WET SCRUBBER
GENERAL MOTORS CORP., SAGINAW, MICHIGAN

                VOLUME II OF II
             APPENDICES C through F
            EPA Contract No. 68D70069
             Work Assignment No. 2-08

                   Prepared for:

           Mr. Michael K. Ciolek (MD-19)
             Work Assignment Manager
               SMAG, EMC, OAQPS
         U.S. Environmental Protection Agency
          Research Triangle Park, NC 27711

                    July 1999
                 P:\i528\finrpt\gm\gmfm.rep

                   Submitted by

    PACIFIC ENVIRONMENTAL SERVICES, INC.
            5001 S. Miami Blvd., Suite 300
               Post Office Box 12077
        Research Triangle Park, NC 27709-2077
                 (919)941-0333
                FAX (919) 941-0234
                                            E—/ i  ''    "*
                                            il I A L-    - '
                                          R"^ if^t r FI ""*• c~  ' ^^i 4i

-------
                                   DISCLAIMER

      This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-08.  This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.

-------
                        TABLE OF CONTENTS


VOLUME I                                                     Page

1.0   INTRODUCTION	1-1

2.0   SUMMARY OF RESULTS 	2-1

     2.1   EMISSIONS TEST LOG	2-1
     2.2   PARTICULATE MATTER AND METALS 	2-1
     2.3   DIOXINS AND FURANS	2-7
     2.4   SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS	2-14
     2.5   VOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS  	2-28

3.0   PROCESS DESCRIPTION	3-1

     3.1   INTRODUCTION	3-1
     3.2   PROCESS DESCRIPTION	3-1
     3.3   PROCESS AND CONTROL DEVICE MONITORING RESULTS 	3-8

4.0   SAMPLING LOCATIONS	4-1

     4.1   CUPOLA WET SCRUBBER INLET	4-1
     4.2   CUPOLA WET SCRUBBER OUTLET	4-1

5.0   SAMPLING AND ANALYTICAL PROCEDURES 	5-1

     5.1   LOCATION OF MEASUREMENT SITES AND
          SAMPLE/VELOCITY TRAVERSE POINTS 	5-1
     5.2   DETERMINATION OF STACK GAS VOLUMETRIC
          FLOW RATE	5-1
     5.3   DETERMINATION OF DRY MOLECULAR WEIGHT
          AND EMISSIONS CORRECTION FACTORS	;. 5-1
     5.4   DETERMINATION OF STACK GAS MOISTURE CONTENT  	5-2
     5.5   DETERMINATION OF PARTICULATE MATTER
          AND METALS	5-3
     5.6   DETERMINATION OF DIOXINS AND FURANS	5-3
     5.7   DETERMINATION OF SEMIVOLATILE ORGANIC
          HAZARDOUS AIR POLLUTANTS (SVOHAPS)  	5-8

-------
                      TABLE OF CONTENTS (Concluded)

     5.8   DETERMINATION OF VOLATILE ORGANIC HAZARDOUS AIR
          POLLUTANTS (VOHAPs) ........................................ 5-8
6.0   QUALITY ASSURANCE/QUALITY CONTROL (QA/QC)
     6.1   CALIBRATION OF APPARATUS ................................. 6~l
     6.2   ON-SITE MEASUREMENTS ..................................... 6'4
     6.3   LABORATORY ANALYSIS ...................................... 6'8
     APPENDIX A - RAW FIELD DATA
     APPENDIX B - ANALYTICAL DATA, PCDDs/PCDFs AND SVOHAPs
VOLUME II
     APPENDIX C - ANALYTICAL DATA, PARTICULATE MATTER AND METALS
     APPENDIX D - CALCULATIONS
     APPENDIX E - QA/QC DATA
     APPENDIX F - PARTICIPANTS

-------
                                  LIST OF TABLES
VOLUME I
Page
Table 2.1     Emissions Test Log, General Motors Corporation - Saginaw, Michigan	2-2
Table 2.2     Particulate Matter/Metals Emissions Sampling and Flue Gas Parameters,
             Cupola Wet Scrubber Inlet, General Motors Corporation, Saginaw,
             Michigan  	2-3
Table 2.3     Particulate Matter Concentrations and Emission Rates, Cupola
             Wet Scrubber Inlet, General Motors Corporation - Saginaw, Michigan	2-4
Table 2.4     Metals Concentrations and Emission Rates, Cupola Wet Scrubber Inlet,
             General Motors Corporation - Saginaw, Michigan	2-5
Table 2.5     Particulate Matter/Metals Emissions Sampling and Exhaust Gas Parameters,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan  	2-8
Table 2.6     Particulate Matter Concentrations and Emission Rates, Cupola Wet
             Scrubber Outlet, General Motors Corporation - Saginaw, Michigan  	2-9
Table 2.7     Exhaust Gas Metals Concentrations and Emission Rates, Cupola Wet
             Scrubber Outlet, General Motors Corporation - Saginaw, Michigan  	2-10
Table 2.8     Particulate Matter and Metals Removal Efficiencies, Cupola Wet
             Scrubber, General Motors Corporation - Saginaw, Michigan	2-12
Table 2.9     PCDDs/PCDFs Emissions Sampling and Exhaust Gas Parameters,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan  	2-13
Table 2.10   PCDDs/PCDFs Exhaust Gas Concentrations and Emission Rates,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan  	2-15
Table 2.11   PCDDs/PCDFs Exhaust Gas Concentrations and 2378 Toxic Equivalent
             Stack Gas Concentrations Adjusted to 7 Percent Oxygen,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw,
             Michigan 	2-16
Table 2.12   SVOFtAPs Emissions Sampling and Exhaust Gas Parameters,
             Cupola Wet Scrubber Outlet, General Motors Corporation - Saginaw
             Michigan 	2-17
Table 2.13   SVOHAPs Exhaust Gas Concentrations and Emission Rates, Cupola
             Wet Scrubber Outlet, General Motors Corporation - Saginaw, Michigan .... 2-19
Table 2.14   SVOHAPS Detection Limits, PPBVD, Cupola Wet Scrubber Outlet,
             General Motors Corporation - Saginaw, Michigan	2-26

-------
                               LIST OF TABLES (Concluded)
VOLUME I
Page
Table 3.1     Typical Cupola Charge Materials 	3-3
Table 3.2     Typical Results from Greens Sand Analysis	3-6
Table 3.3     Chemicals Used in Core Making and Mold Spraying	3-7
Table 3.4     Summary of Cupola Monitoring Results	3-9
Table 3.5     Summary of Cupola Charging During the Test Days 	3-10
Table 3.6     Summary of Number of Molds Poured on Line 4	3-14
Table 3.7     Summary of Metal Poured and Downtime for Line 4	3-15
Table 3.8     Line 4 Mold Counts During Testing Periods	3-16
Table 3.9     Mold Line 4 Production During Testing Periods	3-18

Table 5.1     Sources, Test Parameters, and Test Methods  Summary,
             General Motors Corporation - Saginaw, Michigan	5-2

Table 6.1     Summary of Temperature Sensor Calibration Data	6-2
Table 6.2     Summary of Pitot Tube Dimensional Data	6-3
Table 6.3     Summary of Dry Gas Meter and Orifice Calibration Data 	6-5
Table 6.4     Summary of EPA Methods 23 and 29 and S W-846 Method 0010
             Field Sampling QA/QC Data	6-7
Table 6.5     Summary of EPA Method 29 Analysis QC Data, Lab Control Spikes	6-9
Table 6.6     Summary of EPA Method 29 Analysis QC Data, Matrix Spikes
             (Post Digestion)	6-10
Table 6.7     Summary of EPA Method 29 Analysis QC Data, Duplicate Analyses	6-11
Table 6.8     Summary of EPA Method 29 Analysis QC Data, Serial Dilution	6-12
Table 6.9     Summary of EPA Method 29 Analysis QC Data, Method Blanks Results ...  6-13
Table 6.10    Summary of EPA Method 29 Analysis QC Data, Field Blanks Results	6-14
Table 6.11    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Lab Control Spikes 	6-15
Table 6.12    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Matrix Spikes (Pre-Digestion)	6-16
Table 6.13    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Method Blank  	6-17
Table 6.14    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Field and Reagent Blanks  	6-18
Table 6.15    Summary of EPA Method 23 Standards Recovery Efficiencies	6-20
Table 6.16    S W-846 Method 0010 Field and Laboratory Blanks Results 	6-21
Table 6.17    S W-846 Method 0010 Surrogate Recovery Results 	6-22

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                                 LIST OF FIGURES


VOLUME I                                                                     Page

Figure 1.1    Key Personnel and Responsibility for Testing at GM - Saginaw, Michigan ...  1-3

Figure 3.1    Schematic of the Cupola Gas Handling System 	3-2
Figure 3.2    Schematic of Capture and Control System for Line 4	3-5
Figure 3.3    Hot Blast Temperature During Each Test Run  	3-11
Figure 3.4    Hot Blast Rate During the Test Runs	3-12

Figure 4.1    Cupola Wet Scrubber Inlet Sampling Location	4-2
Figure 4.2    Cupola Wet Scrubber Inlet Traverse Points Locations  	4-3
Figure 4.3    Cupola Wet Scrubber Outlet Sampling Location  	4-4
Figure 4.4    Cupola Wet Scrubber Outlet Traverse Point Locations	4-5

Figure 5.1    EPA Method 29 Sampling Train Schematic  	5-4
Figure 5.2    EPA Method 29 Sample Recovery Scheme	5-5
Figure 5.3    EPA Method 29 Sample Preparation and Analysis Scheme  	5-6
Figure 5.4    EPA Method 23 (PCDD/PCDF) and SW-846 Method 0010
             Sampling Train Schematic	5-7
Figure 5.5    Schematic of Direct Interface GC/MS Sampling System 	5-9

-------
         APPENDIX C




       ANALYTICAL DATA

-------
      Appendix C.I




     Analytical Data

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              Facsimile Transmission
                 From:   Barbara DeWees
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                   Air Pollution Consultants
  Mailing Address:
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-------
                              FILTER WEIGHT LOG SIZE
Filter
 No.
Weight
  g.
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Date/Time
m/d/24hr
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Weight
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Date/Time
m/d/24hr
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                             FILTER WEIGHT LOG SIZE    llO
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                               FILTER WEIGHT LOG  SIZE
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-------
                              FILTER WEIGHT LOG  SIZE
Filter
 No.
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-------
                              FILTER WEIGHT LOG SIZE
Filter
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                                                                                           00
                                                                                           (A)
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-------
7 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                        3708 Mayfair Street, Suite 202
                                                        Durham, North Carolina 27707
                                                                (919) 493-3536
                                                              Fax:(919)493-7779
        Plant
            -  ov\
                    SAMPLE ANALYTICAL DATA FORM

                         	  Run  number T • Wlft '
        Sample location
        Relative humidity
        Density of acetone
                               0
                                                                g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
oacV)u?-Cocc)   (

Date  and time of wt  \cj?« K"*
Date  and time of wt
                               to
                                          Gross wt
                                          Gross wt
                                          Average gross wt
                                                    Tare wt
                                Less acetone blank wt (W  )
                                                         ol
              Weight of particulate in  acetone rinse (m_)
                                       "^                  a
                                                                 m'g
Filter(s) container number
Date  and time of wt  lofc'	
Date  and time of wt  lti|?i |S>     V53o
                                          v-aL  VU-7C   R\U  r\cf.  VOTS
                                          C$O>
                                        	 Gross wt
                                        _ Gross wt
                                  Average gross wt
                                                               114;
                                                                         yig
                                                              0.
          Weight of particulate on filter(s)  (m~)
           Weight of particulate in acetone rinse
                 Total weight of particulate  (m )
                                                               6.0364
                                                                 ipftg
                                                                 mg
                                                                 ijdg
         Note;  In no  case should a blank residue >0.01 mg/g or 0.001% of
         the weight  of acetone used be  subtracted from the sample weight.
         Remarks
              Signature of analyst
              Signature of reviewer

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                               3708 Mayfalr Street. Suite 202
                                                               Durham. North Carolina 27707
                                                                       (919)493-3536
                                                                     Fax:(919)493-7779
       Plant
                    SAMPLE ANALYTICAL DATA FORM

                                                Run number  1~
Sample  location 	
Relative humidity 	
Density of acetone (pa)
                                                                        g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
&Urr VW-^0
%tder lM?
Liquid level marked
and/or container sealed

Acetone rinse container number
Acetone rinse volume
                               =l_
                               3W
                                         404,
Acetone blank residue  concentration (C  )
Wa  = ca vaw pa = * °
Date and time of wt
Date and time of wt
                               to (,«•/,   N-11   P.
Date  and time of wt   /o/?	 Gross wt
Date  and time of wt   (uft> n^    I T?o	 Gross wt
                                  Average gross wt

          Weight of particulate on filter(s) (m-)
           Weight of particulate in acetone rinse
                 Total weight of particulate (m )
Note;   In no case should a blank residue >0.01 mg/g  or 0.001% of
the weight of acetone used be subtracted from the sample weight.
                                                                               c ?*"•'
       Remarks
            Signature of analyst
            Signature of reviewer

-------
!7 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                         3708 Mayfair Street, Suite 202
                                                         Durham. North Carolina 27707
                                                                 (919) 493-3536
                                                              Fax: (919) 493-7779
                             SAMPLE ANALYTICAL DATA FORM
        Plant
                                                Run number  I"-
        Sample location     Its
        Relative humidity 	
        Density of acetone (p_)
                               a
                                                                 g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
BfcAVt* V^-^o
R3\\MTX- W~?i
Liquid level marked
and/or container sealed

Acetone rinse container number
Acetone rinse volume
                                      nt
                                               t£l\¥*f-
                                 awj
                                                                            ml
Acetone blank residue  concentration  (C )
                                         Si
                                                               6.
Wa =
                      pa =
                                                                6-
Date  and time of wt
Date  and time of wt
                               (ofr?/4?
Gross wt
Gross wt
1(6.
                                                                 pig
                                                               1(0.
                                  Average gross wt
                                            Tare wt
                        Less acetone blank wt (W,)
                                                 a
      Weight of particulate in acetone rinse (m  )
Filter(s) container number     oa^ttrf-   VW-ffi  r->\W
Date  and time of wt   |o fn ni-	£)%>     Gross wt
Date  and time of wt   jo /^( n"*-	I^SlSs    Gross wt
                                  Average gross wt
                                                      1(0.-
                                                                          rig
                                                               lCfl.1438  1*
                                                               V02Z 4" to? "5
                                                                          mg
                                                        ( .
                                            Tare wt Q.Cf>\B\ i
          Weight of particulate on  filter(s) (mf) _
           Weight  of particulate  in acetone rinse _
                 Total weight of  particulate (m  ) __
                                                                          pig
                                                                          jag
                                                                          m"g
         Note;  In  no case should a blank residue  >0.01 mg/g or  0.001% of
         the weight of acetone used be subtracted  from the sample weight.
         Remarks
              Signature of analyst
              Signature of reviewer

-------
7 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                                3708 MayfairStreet, Suite202
                                                                Durham, North Carolina 27707
                                                                        (919) 493-3536
                                                                      Fax: (919) 493-7779
        Plant
                    SAMPLE ANALYTICAL DATA FORM

                                               Run number
Sample  location    1 ML&T
Relative  humidity 	
Density of acetone (p  )
                                                                         g/ml
Sample
type
Acetone rinse
filter(s)v
Sample
identifiable
&
Acetone blank residue  concentration (C  )
                                        a.

Date and time of wt  -yd. bo fcn
Date and time of wt
                                                               6 ,
                                      -	 Gross wt
                                 	 Gross wt
                                  Average gross wt
                                           Tare wt
                       Less  acetone blank wt  (W  )
                                                Si
     Weight of particulate  in acetone rinse  (m=)
Filter(s)  container number       pgfltaE  VH-31
Date and time of wt
___ ml
 jfa/g
 mg
 mg
                                                                         mg
        Date  and time of wt   lofr'fq>
                                       	 Gross wt
                        	 Gross wt
                                  Average gross wt
                        \-l)\ TU« - 102.02-^0 Tare wt
          Weight of particulate on filter(s)  (mf)
           Weight of particulate in acetone rinse
                 Total weight of particulate  (m )
                                                                          g,
                                                                          *><
                                                                         jttg
        Note;   In no case should a blank residue >0.01 mg/g or 0.001% of
        the weight of acetone used be subtracted from the sample weight.
        Remarks
              Signature of analyst
              Signature of reviewer

-------
m	
 7 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                3708 Mayfair Street. Suite 202
                                                Durham. North Carolina 27707
                                                        (919) 493-3536
                                                      Fax:(919)493-7779
         Plant
g>m-
                    SAMPLE  ANALYTICAL DATA FORM

                          	         Run number
                              O
Sample  location	
Relative humidity 	
Density of acetone (Pa)
               UTLET
                                                                          g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
V\*-34
V\A-3?
Liquid level marked
and/or container sealed

         Acetone rinse container number
Acetone rinse volume (V,..)
\^U6
Acetone blank residue concentration (C_)
a a aw a
Date and time of wt (uf^1/^?
Date and time of wt f^/Z"2 /4*

5i.o ) (o.^Styl ) =
C^S^o Gross wt
/SCO Gross wt
Average gross wt
Tare wt
ml
0 . O&GO mg/g
0 . ODOO tfo;
IOC. (fC^\(j njfcf
\c&. ($6^3 mg
\Qb ($(fi^ mtr
160. ^W v6
                                 Less acetone blank wt (W  )
                                                          SL
               Weight of particulate in Acetone  rinse (»_)
                                                fj. CdQQ  ma
 Filter(s) container  number
 Date and time of wt  ic(?c/Q>
 Date and time of wt
                                                          F.lW
                                !*>/
                          Ofico
                              _ Gross wt
                        	 Gross wt
                        Average gross wt
                       Fitted + ^f^v^i. Tare wt
Weight of particulate on filter(s)  (mf)
 Weight of particulate in acetone rinse
       Total  weight of particulate  (mn)
                                                                          mg
                                                                          nrg
         Note;  In no case  should a blank residue >0.01 mg/g or 0.001% of
         the weight of acetone used be subtracted from the  sample weight.
          Remarks
               Signature  of analyst
               Signature  of reviewer
                            CfrvC

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                               3708 Mayfair Street. Suite 202
                                                               Durham. North Carolina 27707
                                                                       (919) 493-3536
                                                                     Fax: (919) 493-7779
                          SAMPLE ANALYTICAL DATA FORM
       Plant
                                               Run number <0
Sample location    Oc/r
Relative humidity 	
Density of acetone (p_)
                      cl
                                                                       g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
WV-3T ,
KW-3&
Liquid level marked
and/or container sealed

       Acetone rinse container number
                                            VK-B6
       Acetone rinse volume
                      
Acetone blank residue concentration (C )
                                        cl
                                                             O
Wa =
            ca vaw pa =  (o •
                                              )  =
Date  and time of wt
Date  and time of wt
                                  /$>
                             \*\ii
                                          Gross wt
                                          Gross wt
         	 ml
         _ mg/g
  6-QQQ6  mg-
_(6£_li?l_mg
                                  Average gross  wt
                                           Tare  wt
                       Less  acetone blank wt  (W )
     Weight of particulate  in acetone rinse  (ma)
Filter(s)  container number     bri40.01 mg/g or 0.001% of
       the weight of acetone used be subtracted from the  sample weight.
       Remarks
            Signature of  analyst _
            Signature of  reviewer

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                              3708 Mayfair Street, Suite 20!
                                                              Durham. North Carolina 27701
                                                                      (919) 493-3531
                                                                    Fax: (919) 493-777!
                          SAMPLE ANALYTICAL DATA FORM
       Plant
       Sample location
       Relative humidity
       Density of acetone  (p_)
                                               Run number  O-
                                                                g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
III
Liquid level marked
and/or container sealed

Acetone  rinse container number
Acetone  rinse volume
                                          -&*
              fc=fcfr  w
                                               -3ft- (&fcU.
                               _u
                               clW
                                                                         ml
       Acetone blank residue concentration (C )
                                               cl
                                                                mg/g
W=CV   p   = ( 6
 a     a  aw Ka   v
Date  and time  of wt
Date  and time  of wt
                                 6, )   (
                                   C/>ct>
                                 4:?r§o
                                                    ) =
                              0 .
                     |o
?(
                                  -#ttc»
                                                 Gross wt
                                                 Gross wt
                                , Q8Z(   mg
                                 Average gross wt
                                           Tare wt
                       Less acetone blank wt (W_)
                                                cl
     Weight of particulate in  acetone rinse (m_)
                                tjr^        ^	cl
Filter(s)  container number
Date and time of wt J.
Date and time of wt  \
                                                               0-0061-
                                                                       pg
                                                                       jng
                                       orioo
                                          Gross wt
                                          Gross wt
                                        mg
                                  Average gross wt
                                           Tare wt
          Weight of particulate on filter(s) (mf)
           Weight of particulate in acetone rinse
                 Total weight of particulate (mn)
                                                               .006^
                                                              0 .
                                        oig
                                        mg
                                        mg
       Note:   In no case should a blank residue >0.01 mg/g or 0.001% of
       the weight of acetone used be subtracted from the  sample weight.
       Remarks
             Signature of analyst
             Signature of reviewer

-------
7 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                                3708 Mayfair Street Suite202
                                                                Durham. North Carolina 2770T
                                                                        (919)493-3536
                                                                      Fax:(919)493-7779
                            SAMPLE ANALYTICAL DATA FORM
        Plant
Sample location	£J
Relative  humidity 	
Density of acetone (p_)
                      Cl
                                               Ran number  Q -
                                      £X"r8Tl
                                                       g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
W-4o
Wl3q
Liquid level marked
and/or container sealed

        Acetone rinse container number   Vdr>W   (HP.    lAA. ~
Acetone rinse volume
                               (V_u)
                                ciw
                                                         ml
Acetone blank residue concentration (C  )
Wa  = Ca Vaw 'a « <°
Date and time of wt
Date and time of wt
                                           Tare wt
                       Less  acetone blank wt (V/a)
      Weight of particulate  in acetone rinse (m )
                                                                6 COC56
                                                                6.O6OO
»o|?
tof?

• |flT-
, (^

0*i<*>
KI6
Average
Gross
Gross
gross
wt
wt
wt
\lft.
v\c
\\o
116^
uei
\iSl
                                                                  \fel-Q
                                                                6
Filter(s) container number
Date  and time of wt
Date  and time of wt
                                                N&
                              	 Gross wt
                        	 Gross wt
                        Average gross wt
                        I. "3(iCs0.01 mg/g or  0.001% of
        the weight of acetone used be subtracted from the sample weight.
        Remarks
              Signature of analyst _
              Signature of reviewer
                    WASHINGTON. O.C. • RESEARCH TRIANGLE PARK. NC • LOS ANGELES. CA • CINCINNATI

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                          3708 Mayfair Street, Suite 202
                                                          Durham, North Carolina 27707
                                                                  (919)493-3536
                                                                Fax: (919) 493-7779
                         BLANK ANALYTICAL DATA  FORM
                                              0
Plant 	
Sample  location  	  	
Relative humidity 	
Liquid  level marked and container sealed
Density of acetone (p  )
                      a
Blank volume (V  ) 	
                CL   ~~ ~  '
Date and time of wt   |o)
Date and time of wt
              M 0U)
                            lof?i
                                                                      g/ml
                                                                        ml
Gross wt
Gross wt
107. 0414-  nig
  L 64-10
                                        Average gross wt
                                                  Tare wt
                                                       107 . 64-1*2- jriq
                                                       \62. 64^4 ate
                                   Weight of  blank (m^)   (6.
                                                (
                                                 )
                                                            Q.OOOQ  mg/g
     Note;   In no case  should a blank residue greater than  0.01 mg/g
     (or 0.001% of the  blank weight) be subtracted from the sample
     weight.
      Filters
     Date and time of wt (o
     Date and time of wt t^fc'
                                 Filter  number
                                      Gross wt
                                      Gross wt
                       jag
                                   Average  gross wt
                                             Tare wt
                                      Difference wt
     Note;  Average  difference must be less  than ±5 mg or  2% of total
     sample weight whichever is greater.
     Remarks
          .	N^/
           Signature of analyst     CXx^l/
           Signature of reviewer

-------
r~~7r—7f—7
1 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                   3708 Mayfair Street, Su«e 202
                                   Durham, North Carolina Z7707
                                           (919) 493-3536
                                         Fax: (919) 493-7779
                           BLANK ANALYTICAL DATA  FORM
                        ortfe
                                        l4
Plant	
Sample  ]r»~at--inp-
Relative  humidity	
Liquid  level marked and  container sealed
Density of acetone (p=)
                      a.
Blank volume (V,) 	
                oi      ~~
Date and  time of wt
k
       Date  and time of wt  ID \1
                                fc.
Gross wt
Gross wt
                                                               us.
                                                                        g/ml
                                                                          ml
                                          Average  gross wt
                                                    Tare wt
                                    .6881- jrig
                                     Weight of blank (m^)   - Q. OOo 1  jfy
                                                        -
       Note;   In no case should a blank residue  greater than  0.01 mg/g
       (or  0.001% of the blank weight) be subtracted from the sample
       weight.
       Filters
       Date  and time of wt
       Date  and time of wt  (&/?(
         Filter number
       /"3?6 	 Gross wt
               Gross wt
                              Average gross  wt
                            f R/rV     Tare  wt
                                 Difference  wt
                             /OS.
                                                                          jug
                                                             Q>OOO4-
       Note:   Average difference must be less  than ±5 mg or  2% of total
       sample  weight whichever is greater.
       Remarks
            Signature of analyst
            Signature of reviewer

-------
7 PACIFIC ENVIRONMENTAL SERVICES, INC.
                                                         3708 Mayfair Street, Suite 202
                                                         Durham, North Carolina 27707
                                                                 (919) 493-3536
                                                               Fax: (919) 493-7779
       Sample locati
       Relative hum!
                           BLANK ANALYTICAL DATA FORM
                                                           £   iQ
                                                         r Vifalid \fcb&
       Date and time  o
       Liquid level marked and container  sealed
       Density of acetpne (p.,) 	/
       Blank volume  (T
       Date and time  oJ
                                           Gross wt
                                           Gross wt
                                          Average gross wt
                                                   Tare wt]
                                    Weight of blank (m
                                                                g/ml
                                                               __ ml
                                                               	 mg
                                                               	 mg
                                                               	 mg
                                                               	 mg
                                                               	 mg
                                m.
                          C  =
                               V
                                                                mg/g
Note;   In no case should  a blank residue greater than 0.01 mg/g
(or  0.001% of the blank weight)  be subtracted  from the sample
weight.
          / ft. I
                                 Filter number
                                    _ Gross wt
                                      Gross wt
Filters
Date  and time of wt
Date  and time of wt
                                                          /Oft
                                    Average gross wt
                                    $ £,//
-------
m
z

I

in
                                                  METHOD 5
                                                FINAL WEIGHT
Project Number:
 Date
 R.H.
     ^  (°P)
 Std. Wt.
 Analyst
 ID Number
 \W-7T-
 IM-3T
                   Field Sample
                      Number
             t-
            O -
            0 -
                  \-Wb-i. -F.\
            6 -
-P'
                                                         Item Weighed: _

                                                                     KBo
                                    &8.S
            1st
         (Qg. 023
                              I60-573I
                                              25
2nd
                                       114-1
                                       ill.
                                           M:
                                      /i'-
                                       NO-
                                           |OIv
                                      H?:
3rd
                                                   U4-.I464
                                               \flft.0fll4-
                                                   ID 6.
                                               102. 04%)
4th
                                                        I. 044
5th
 Final
Wt. (g)
                                                                            /I/.0630
                                                                            ice.
                                                                       lOS-
                                                                            llo.MBZ-
                                                   108.3^23
                                                                            \OC.
  Tare
Wt. (g)
Difference
   (mg)
                                                                                                              B>
-------
                                                 METHOD 5
                                               TARE HEIGHT
Project Numbert  ^444-
                                                    Item Weighed.
Date
R.H. (%)
                                       l&G
                                                       70,3
Std. Ht.
                               Cu-rapto
                                              /oO.oooo
                      /oo.ooof
Analyst
                                                m.
ID Number
              Field  Sample
                 Number
1st
2nd
3rd
4th
5th
 Final
Ht. (g)
  Tare
Ht. (g)
Difference
   (mg)
                                                                                 -terror^
  1*1-34-
                                               100. 51W
                                                                                 IK- 1436
                                              ill.
                                                                                  \IO.
  i/H-4/
                                         . (
                                                                                                            in
-------
                                                      METHOD 5
                                                     TARE HEIGHT
Project Numbers
                                                          Item Weighed i
Tl
O
n>
m

co
m
5
o
S
     Date
     R.H.  (%)
     Temp.  (°P)
     Std.  Wt.
     Analyst
      ID Number
         <-<&
              Field Sample
                 Number
                                      1st
2nd
                                           (01,4*30
                                           (Oft.
                                       107.ST15
                                           31.8280
                                               /OO.OOOD
                                                 titt
3rd
                                                    100,
4th
              100. &81-
5th
 Final
Wt. (g)
  Tare
Wt. (g)
                                                                                      .4*536
                                                                                        \01
Difference
   (rag)
-------
  Appendix C.2




 Analytical Data




-------
   i	U	/
PACinC ENVIRONMENTAL SERVICES, INC.
     5001 South Miami Boulevard. P.O. Box 12077

Research Triangle Park, North Carolina 27709-2077

           (919)941-0333 FAX: (919) 941-0234
                                               Chain of Custody Record
Project Numb^ ^ ^ ^mj
Project Name
US EPA EMC Aspha^GemMtrRE/LConstRietien
Samplers:
Dickerson, McDonald, Thompson, Dougherty, Hamilton
Date













i







Time
















»




Field Sample ID














'






Relintjujsjbed by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)

Date/Time
Date/Time
Dateffime
Sample Description
-M29-1 -Filter
-M29-1 -Front Half Rinse
-M29-2-Filter
-M29-2-Front Half Rinse
-M29-3-Filter
-M29-3-Front Half Rinse
-M29-4-Filter
-M29-4-Front Half Rinse
O-M29-1 -Filter
O-M29-1 -Front Half Rinse
O-M29-2-Filter
O-M29-2-Front Half Rinse
O-M29-3-Filter
O-M29-3-Front Half Rinse
O-M29-4-Filter
O-M29-4-Front Half Rinse
0-M29-BLK-Filter
O-M29-BLK-Front Half Rinse
O-M29-RB-3 Filter
O-M29-RB-4-Filter
O-M29-RB-Acetoije /\
Re«
1
Reck
1
ved by: (Signatur
-------
                            CASE NARRATIVE
        Analysis of Samples for the Presence of Trace Metals
                           Method 29 April 1996 Rev.
             Client:                    PES, Inc.


             TLI Project Number:      43452


             Date:                     November 20,1997
                        This report should only be reproduced in full.
                  Any partial reproduction of this report requires permission from
                              Triangle Laboratories, Inc.
Rev. 07-May-97
                                            Triangle Laboratories, Inc.
                                 801 Capitola Drive             P.O. Box 13485
                                 Durham, NC 27713-4411         Research Triangle Park, NC 27709-34$
-------
Triangle Laboratories, Inc.                                        November 20,1997
Case Narrative                                                TLI Project #: 43452

Overview

Eight train samples, two blank train samples and a DI water sample were analyzed for
silver (Ag), arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co),
chromium (Cr), manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), antimony (Sb),
selenium (Se), thallium (Tl), zinc (Zn), and mercury (Hg). For all analyses, the samples
and associated QC samples were prepared and analyzed following the guidelines of
Method 29 April 1996 Rev. Results reported relate only to the items tested.

OC Remarks

The release of this set of data by Triangle Laboratories, Inc. was authorized by the Quality
Control Chemist who has reviewed each sample data package individually following a
series of inspections/reviews. When applicable, general deviations from acceptable QC
requirements are identified below and comments are made on the effects of these
deviations upon the validity and reliability of the results.  Specific QC issues associated
with this particular project are:

Sample Receipt:

Eight train samples, two blank train samples and a reagent blank were received without
coolant (thus causing the high temperature of  26 °C) on September 30,1997 in good
condition under project # 43452. The filter and acetone rinse samples were processed for
gravimetrics and were re-received under project # 43775 on October 28, 1997. All
components were processed under project # 43452.

The first page of the client's chain- of- custody (COC) was faxed from DEECO.  The rest of
the pages of the COC were received with the samples.

Sample I-M29-2-H202 2 was not analyzed. It  was archived.

Sample Preparation:

Laboratory documentation of the sample preparation is included in the data package.

Instrumentation:

Silver (Ag), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co), chromium (Cr),
manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), antimony (Sb), selenium (Se),
thallium (Tl), (front half samples) and zinc (Zn) concentrations were determined by
Inductively Coupled Plasma Emission Spectroscopy (ICP).

Arsenic (As) and cobalt (Co) concentrations were analyzed by Graphite Furnace Atomic
Absorption (GFAA). Thallium (Tl) concentrations for all the back half samples and front
-------
Triangle Laboratories, Inc.                                        November 20,1997
Case Narrative                                                TLI Project*: 43452

BLK-FHAR FH, Beaker No.M43,M44,m45,O-M29-RB-0.1N HNO3 FH, M29-RB-DI
H2O FH, and Beaker N6.M39.M40.O-M29-4-FHAR FH were analyzed by GFAA.

These elements demonstrated some insignificant negative interference as seen by the
negative concentration values. Please note that all quality control checks and the other
elements were within criteria for these elements, therefore they were not analyzed by
GFAA.

Mercury (Hg) concentrations were determined by Cold Vapor Atomic Absorption
(CVAA).

The linear range for the instrument TJA 61E Trace Analyzer was based on four standards
and a blank, which established a correlation coefficient value greater than or equal to
0.995.  A calibration curve, based on a blank and one standard, is established for each
analytical run, followed by a check high standard and an initial calibration verification
(ICV). The check high standard does not deviate from the calibration curve by more than
5%. In addition, continuing calibration verifications (CCVs) are performed throughout
the analytical run.

A Reporting Detection Limit (RDL) is used instead of an Instrument Detection Limit
(DDL). The spectrometer and atomic absorption instruments can achieve low detection
limits between 0.2-8 ppb levels for many analytes.  Triangle Labs is using RDL values of
1-10 times the DDL as detection limits for reporting purposes.

Data Review:

All analytes found in the method blank (MB) are detected at a level equal to or less than
the respective Reporting Detection Limits (RDLs).

The laboratory control spike for As demonstrated a percent recovery slightly outside the
QC criteria. Please note that this analyte was found in the MB at a level equal to or less
than the respective Reporting Detection Limits (RDLs).

The front half serial dilution results for Cd, Co, Ni and Tl for the sample Beaker
No.M25,M26,I-M29-l-FHAR FH demonstrated RPDs outside the QC control criteria of
10.0 percent, which indicates the presence of a significant amount of interferents specific
to these analytes in the native sample matrix. The results for Cd, Co, Ni and Tl in this
sample should be considered biased low due to matrix interferences.

The front half serial dilution results for Ag, Cr, P, and Sb for the sample Beaker
No.M25,M26,I-M29-l-FHAR FH demonstrated RPDs slightly outside the QC control
criteria of 10.0 percent, which does not indicate the presence of a significant amount of
-------
Triangle Laboratories, Inc.                                        November 20,1997
Case Narrative                                                 TLI Project*: 43452

Beryllium (Be) concentrations were initially analyzed by Graphite Furnace Atomic
Absorption (GFAA). The post-digestion spike (PDS) failed for both the front half and
back half samples in the original GFAA analyses. The MSAs were run twice for the front
half samples and the correlation coefficients were below 0.995, therefore the ICP results
were reported for this element for all front half samples in this data package. The back half
samples displayed some interference problems when analyzed by GFAA, therefore the ICP
data was reported for the back half samples.

The front half post-digestion spike (PDS) for Be for the sample Beaker No.M25,M26,I-
M29-1-FHAR FH demonstrated a percent recovery outside the QC criteria, which may
indicate significant matrix effects specific to these analytes in the native sample matrix.
Please note that the results for Be in the front half samples should be considered biased
low due to matrix interferences.

 The back half post-digestion spike (PDS) for Se for the sample I-M29-1-H2O2 BH
demonstrated a percent recovery slightly outside the QC criteria, but does not indicate
significant matrix effects specific to these analytes in the native sample matrix. Please note
that the results for Se in the back half samples should be considered biased low due to
matrix interferences.

The recoveries for the front half post-digestion spike (PDS) are not reported for Ba, Cd,
Co, Cr, Mn, Ni, Pb, Sb, Se, Tl,  and Zn for sample Beaker No.M25,M26,I-M29-l-FHAR
FH. The spike concentrations added were insignificant in comparison to the levels of these
analytes present in the native sample.

A duplicate analysis is not reported for elements analyzed by GFAA. The GFAA
instrument analyzes two separate aliquots of the sample and averages the values for a final
result. These two analyses agree within a RPD of 20% or a second run is done for that
sample. The ICP instrument analyzes one continuous aliquot three times and averages the
values for a final result. The ICP does not take two separate aliquots, therefore a DA is
performed.

The post-digestion spike (PDS) for Co for sample I-M29-1-H2O2 BH demonstrated
percent recoveries outside the QC criteria of 80-120 percent, which indicates significant
matrix effects specific to these analytes in the native sample matrix. The interference QC
analysis is not reported (i.e. PDS and duplicate) for this analyte since the Method of
Standard Additions (MSA) was performed. The MSA results are reported if the
correlation coefficient value is at least 0.995. All samples results are reported from the
MSA analysis for Co, for  the back half samples.

Because client paperwork did not include sampling date information, the expiration of the
sampling to analysis holding times could not be determined. All samples were analyzed
-------
Triangle Laboratories, Inc.                                        November 20,1997
Case Narrative                                                 TLI Project*: 43452

QC requirements:
                     *
The duplicate analyses for analytes analyzed by GFAA cannot be considered valid
qualifiers if the concentrations of the analytes in the original and/or duplicate sample are
not at least five times the respective RDL.  The RPDs for these analyses are indicated by
"
-------
Triangle Laboratories, Inc.                                        November 20,1997
Case Narrative                                                TLI Project*: 43452

By our interpretation, the analytical data in this project are valid based on the guidelines of
Method 29 April 1996 Rev. Any specific QC concerns or problems have been discussed in
the QC REMARKS section with emphasis on their effect on the data. Should PES, Inc.
have any questions or comments regarding this data package, please feel free to contact
Project Scientist, Amy J. Boehm, at (919) 544-5729 ext.268.

For Triangle Laboratories, Inc.,

Report Preparation                             Quality Control
BrendaRBell
Report Preparation Chemist                      Report Preparation Chemist
-------
                      TRIANGLE LABORATORIES, INC.

                 LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American Association for Laboratory Accreditation. Accredidation  pending.   Certificate
Number 0226-01.  Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste,  Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama,  Department of  Environmental  Management.  Expires December  31,
1997. Laboratory I.D. #40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department of  Health  Services.   Expires  May  26, 1998.  Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of  Arkansas,  Department of  Pollution Control  and Ecology.  Expires February  18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.

State of  California,  Department of  Health Services.  Expires August 31, 1999.  Certificate
#1922. Selected Metals in Waste Water; Volatiles. Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut, Department of Health Services.  Recertification pending. Registration
# PH-0117. Dioxin in drinking water.

Delaware Health and  Social Services.  Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.

Florida Department of Health and Rehabilitative Services.  Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424.  Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC)  and Volatiles  (GC/MS)  in Environmental Samples.   Environmental water ID HRS#
E87411.

Hawaii Department  of Health.  Expires  March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 10/28/97 RM
Printed 10/29/97                                   Triangle Laboratories, Inc.
                                  801 Capitola Drive             P.O. Box 13485
                                  Durham, NC 27713-4411         Research Triangle Park, NC 27709-3485
-------
Idaho Department of Health and Welfare.  Expires November 30,  1997. Dioxin in drinking
water.

State of Kansas, Department of Health and  Environment.   Expires January 31,  1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste.  Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.

Commonwealth  of  Kentucky, Department  for  Environmental  Protection.    Expires
December 31, 1997. ID#90060. Dioxin in drinking water.

Maryland Department  of Health and Mental Hygiene.  Expires  September 30,  1998.
Certification #235. Drinking water by Method 1613A.

State of Michigan, Department of Public Health.  Expires June 3,  1998. Drinking water by
Method 1613.

Mississippi State Department of Health. No expiration date..  Dioxin in drinking water.

Montana Department of Health and Environmental Services.  Expires December 31, 1997.
 Dioxin in drinking water.

State of New Jersey, Department of Environmental Protection and Energy.  Extended by
state. Temporary certificate until December 31, 1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.

State of New Mexico, Environment Department. Recertification pending. Dioxin in drinking
water.

New York  State Department of Health.  Expires April 1,  1998. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in  DW.

State of North  Carolina, Department of Environment Health and Natural  Resources
Expires August 31,1999. Certificate # 37751. Dioxin in drinking water.

State of North Carolina,  Department of  Environment, Health, and  Natural Resources,
Division of Environmental Management.  Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.

North  Dakota State Department of  Health and  Consolidated Laboratories.   Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 10/28/97 RM

Printed 10/29/97
-------
Oklahoma  Department  of Environmental Quality.   Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A,  8290 and 8280.

State of South Carolina, Department of Health and Environmental Control.  Expires April 1,
1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.

State of Tennessee. Department of Environment and Conservation.  Expires  February 5,
1999. ID #02992.  Method 1613 Drinking water only.

U.S. Department of Agriculture Soft Permit.  Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil  samples for use in laboratory analysis.

U.S. Army Corps of Engineers.  Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.

U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.

U.S. EPA Region VIII, for the State of Wyoming.   Expires November 13,  1997. Dioxin in
drinking water.

State of Utah, Department of Health. Expires December 31, 1997. Certificate  Number E-166.
Certification for the following parameters:  Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act;  Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.

Commonwealth  of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30,1998. ID # 00341. Dioxin in drinking water.

State of Washington,  Department  of Ecology.    Expires September 11,  1998.  Lab
Accreditation  Number  C067. Scope of  Accreditation   applies  to  water  analyses  for
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.

State of Washington, Department of Health.  Expires April 30, 1998. Dioxin in drinking water
 Lab I.D.  129

State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 10/28/97 RM

Printed 10/29/97
-------
State of Wisconsin,  Department  of  Natural  Resources.   Expires August 31,  1998.
Laboratory  ID  Number 999869530. Certification  for the following  categories of Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin.  Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement Agency (DEA).   Expires November  30,  1997.  Registration  number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human  Resources.  Expires October 31, 1998.  Registration  number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.

Food &  Drug Administration (FDA)  Registration.   Expires June 1998.  ID #'s  001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID  # 34D0705123.   Department  of  Health  &  Human  Services,  Health Care  Financing
Administration.

U.S. EPA Large Quantity Hazardous Waste Generator.    No expiration  date.   EPA  ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina Radioactive Materials License.  Expires April  30 1998.  License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.

North Carolina General License for Radiation Protection.  No. expiration date. License No.
032-875-OG. The  general license applies only to radioactive material contained in  devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 10/28/97 RM

Printed 10/29/97
-------
   = BackHaif
CCB » Continiiing Calibration Blank
CCV = Continuing Cilibtacion Verification
CHECK HS = Check High Standard
D = DUP = Analytical Dupacace (Piepaied DnpBrate)
DA = Duplicate Analysis
   = Front Half
   = Hnal Digestate Volume
ICB = Ininat Calibration Blank
ICV = Ini"al Calibration Verification
ICS AB = Interference Check Solution (Solution AB)
       Is: Initial
       F = Final
       Solution AB contains common ?wnf»g"« in addition to the anafyte of interest.
IDL = Instrurcent Detection Hr^m
L = Serial Dilution
LCS = Laboratory Control Spike Sample
MB = Method Blank
MPV = Mercury Preparation Volume
MS = Pre-digestion Spike
MSD = Pre-digestion Spike Duplicate ^
N/A = Not Applicable
N/Av = Not Available
N/V = Not Valid
PDS = Post-digestion Spike
%REC = Percent Recovery
RDL = Reporting Detection T'tnir
RPD = Relative Percent Difference
T = Analytical Triplicate (Prepared Triplicate: for Eg anarysis by Method 7471 only)
TV = Total Sample Volume
< = Analyte concentration in the sample is less than the respective RDL
-------
                   STANDARD CONCENTRATIONS
                 for the TJA 61E TRACE ANALYZER
Analvte
Ag
As
Al
B
Ba
Be
Ca
Cd
Ce
Co
Cr
Cu
Fe
K
Li
Mg
Mn
Mo
Na
Ni
P
Pb
Sb
Se
Sn
Sr
Tl
Tl
V
Zn
Units
ppb
ppb
ppb
Ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
High Std
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
10000
1000,
1000
1000?
1000
roocxr
1000
100ft-
1000
lOOfr
1000
ioofr
1000
1000
1000
1000
1000
ICV/CCV
500
500
500
500
500
500
500
500
500
500
500
500
50ft
5000
:- . 50®* ;
500
500
500
V50QO "
500
500
500
•- — 5QQ^~-
500
-"-"500™;
500
500
500
500
500
ICSAB
500
500
500000
500
500
500
500000
500
500
500
500
500
200000
19000
500
500000
500
500
5000
500
500
500
500
500
" 500
650
500
500
500
500
RDL
1
5
50
7
2
1
60
1
3
1
2
2
40
220
1
30
- 2
2
300
3
30
2
4
3
13
1
8
5
2
12
Wavelength
3280
1890
3082
2496
4934
3130
3179
2265
4186
2286
2677
3247
2714
7664
6706
2790
2576
2020
3302
2316
2149
2203
2068
1960
1899
4215
3349
1908
2924
2062
Note:  Use this reference page to review the raw data from the TJA 6IE Trace Analyzer.

This page includes the standard concentrations for the check high standard, initial calibration
verification (ICV), continuing calibration verification (CCV), and the interference check solution
(ICSAB). In addition the reporting detection limit (RDL) and wavelength are reported for each
analyte.
                                                         Revision Date: 15-Jul-96
-------
             CALCULATIONS FOR AIR SAMPLES

RESTS FOR TRACE METALS ("except mercury):
      RESULT in ug (Front Half) = fig/L * FV CmD * DF
                               1000 mL/L

     . RESULT in jig (Back Half & Impingers) =  u.g/L * TV ( mD * FV CmD * DF
                                            mL used * 1000 mL/L

            FV = final volume in mL
            TV = total volume in mL
            DF = Dilution Factor

The RESULTS for combined Front Half & Back Half samples use the same calculation as the
Back Half & impinger samples.

RESULTS FOR MERCURY Ofa);

      RESULT in |ig (Front Half) = u.g/L * (mL FV/mL aliquot) * MPV * DF

      RESULT in jig (Back Half & Impingers) =  jig/L * (mL TV/mL aliquot) * MPV * DF

            MPV = mercury preparation volume = 0. 1 L

%REC (Percent Recovery) for MS/MSP He spikes:

      %REC = spike sample results - original sample results * 100
                  true spike sample results

NOTE: Original sample results less than the RDL are not used in emulations.

%REC (Percent Recovery) for PDS;

      %REC = Spike sample ug/L cone. - original sample u.g/L cone.  * 100
                        spike cone. (u,g/L)

%REC (Percent Recovery) for LCS/LCSD:

      %REC = Spike sample \is/L cone. * 100
                  spike cone. Qig/L)
RPDs:      RPD =  I Result 2 - Result 1 I   * 100
-------
Client:       PES, Inc.
Project Number:	
45452
 Sample Report
Client Sample ID:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M25,M26,I-M29-1-FHAR FH
188-52-1.2.185-26-1CFH
Sept. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06 -11 & 19. 1997
Air
Attalyte !
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
(UQ/U
108.353
56.3
4060.503
-7.919
828.458
62.6
5019.044
6126.112
375.269
4764.237
955.950
665.061
250.750
307.846
7722.537
















rrl i
TotelVol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mk v-
Final V
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed'
Matrix:
Beaker No. M25.M26J-M29-1-FHAR FH L
188-52-1,2,185-26-lCFHL
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19, 1997
Air
Anah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
{uo'U
24.699
54.6
847.781
-1.217
193.935
81.4
1147.985
1247.558
89.861
1060.123
192.128
148.802
46.977
78.983
1564.468
















fit :
TotatVol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















ml
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
FmadVd.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dlutiofl
Factor
5
5
5
5
5
5
5
500
5
5
500
5
5
5
500
















Total uq
Result
12.3
27.3
424
< 0.500
97.0
40.7
574
62400
44.9
530
9610
74.4
23.5
39.5
78200
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, Norti Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                   Printed:   20-Nov-97  at   04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1-H2O2BH
185-26-1DBH
Sept. 30 & Oct. 28
Oct. 31 -Nov. 04,
November 06 - 1 1
,1997
1997
& 19. 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
{uoto
2.038
3.3
5.604
-0.075
2.715
2.2
15.011
96.612
7.191
92.266
96.694
7.416
3.555
0.4
522.834
















trt
Total Vol.
600
600
600
600
600
600
600
600
600
600
600
600
600
600
600
















ni.
Used
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
















; , mi
RrerfVcL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Oiubor*
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totefug :
Result
0.245
< 0.900
0.672
< 0.120
0.326
0.264
1.80
11.6
0.863
11.1
11.6
0.890
0.427
< 0.240
62.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                         Printed:   20-Nov-97  at   04:28 PM
-------
 Client:       PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed*
Matrix:
I-M29-1-H202BHL
185-26-1DBHL
Sect. 30 & Oct. 28. 1997
Oct. 31 - Nov. 04, 1997
November 06- 11 & 19, 1997
Air
Analyt^
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















:; . Cbndt. -'
- - {ucfe;
0.775
-1.2
1.016
-0.141
0.317
-0.000
1.991
20.497
0.713
11.532
20.616
-0.313
-0.905
0.7
117.430
















•j -jBi^'H
TbtalVol,
600
600
600
600
600
600
600
600
600
600
600
600
600
600
600
















:; rnL
Used
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
















B*.
FinsiVol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















DUoR
Factor
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
















Totefuei ;
Result ;
< 0.600
< 4.50
< 1.20
< 0.600
< 0.600
0.900
< 1.20
12.3
< 1.80
< 18.0
12.4
< 2.40
< 1.80
< 1.20
70.5
















Triangle Laboratories, Inc.
801 Capitola Dnve * Durham, Nortii Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:       PES, Inc
 Project Number:	
4S452
 Sample Report
Client Sample ID:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M27.M28J-M29-2-FHAR FH
188-52-3A185-26-2CFH
Sept. 30 & Oct. 28. 1997
Oct-31-Nov. 04, 1997
November 06 -11 & 19. 1997
Air
Anah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
luoto
251.685
82.4
11740.365
23.654
2313.309
93.4
10238.519
14077.762
556.573
55553.270
2225.871
543.854
600.472
636.570
16070.912
















Bl
TofetfVoL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















ml
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















RjL
: Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Diution
factor
1
10
1
1
1
5
1
100
1
1
100
1
1
1
100
















Totafug
Result
25.2
82.4
1170
2.37
231
46.7
1020
140800
55.7
5560
22300
54.4
60.0
63.7
160700
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                 Printed:  20-Nov-97  at  04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M27>I28,I-M29-2-FHAR FH DA
1 88-52-3.4, 185-26-2CFH DA
Sept. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04. 1997
November 06- 11 & 19. 1997
Air
Analvte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cona
foq/U
246.918
N/A
11855.433
23.371
2270.033
N/A
10054.249
14953.808
552.032
55487.777
2384.730
590.575
587.472
632.233
17206.398
















ml !
TctelVoL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















Ol
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















rnL
I Final Voi
100
N/A
100
100
100
N/A
100
100
100
100
100
100
100
100
100
















Diution
factor
1
N/A
1
1
1
N/A
1
100
1
1
100
1
1
1
100
















Totelyg
Result
24.7
N/A
1190
2.34
227
N/A
1010
149500
55.2
5550
23800
59.1
58.7
63.2
172100
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham. North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:       PES, Inc.
 Project Number:	
42452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2-H2O2 1 OF 2,2 OF 2 BH
185-26-2D.12BH
Sept. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06- 11 & 19. 1997
Air
Arafyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
footo
21.359
17.5
294.765
1.890
98.350
37.9
256.897
30967.557
18.969
912.030
4575.688
35.767
14.641
0.7
37672.477
















rat
TotalVol
1260
1260
1260
1260
1260
1260
1260
1260
1260
1260
1260
1260
1260
1260
1260
















mL
Used
1160
1160
1160
1160
1160
1160
1160
1160
1160
1160
1160
1160
1160
1160
1160
















nt
RnaWoi.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dpufior*
JFaetor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totafua '.
Result
2.32
1.90
32.0
0.205
10.7
4.12
27.9
3360
2.06
99.1
497
3.89
1.59
< 0.217
4090
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                          Printed:  20-Nov-97  at  04:28 PM
-------
 Client:       PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received'
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2-H2O2 1 OF 2,2 OF 2
185-26-2D.12BHDA
Sent. 30 & Oct. 28. 1997
BHDA


Oct. 31 -Nov. 04, 1997
November 06 -11 & 19. 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
footo
22.434
N/A
293.313
1.894
99.234
N/A
259.333
354.705
20.029
919.878
4613.094
39.051
14.208
N/A
38076.535
















mL
TotalVoL
1260
N/A
1260
1260
1260
N/A
1260
1260
1260
1260
1260
1260
1260
N/A
1260
















mL
Used
1160
N/A
1160
1160
1160
N/A
1160
1160
1160
1160
1160
1160
1160
N/A
1160
















wi.
Final VoL
100
N/A
100
100
100
N/A
100
100
100
100
100
100
100
N/A
100
















DlutJorc
Factor
1
N/A
1
1
1
N/A
1
100
1
1
1
1
1
N/A
1
















Total us :
Result
2.44
N/A
31.9
0.206
10.8
N/A
28.2
3850
2.18
99.9
501
4.24
1.54
N/A
4140
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                         Printed:   20-Nov-97 at  04:28 PM
-------
Client:       PES, Inc.
Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed'
Matrix:
Beaker No. M29M30.I-M29-3-FHAR FH
188-52-5.6.185-26-3CFH
Sept. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06- 11 & 19, 1997
Air
Ansfyte :
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone, .*
{uofl-V
299.016
66.3
8355.201
-11.394
2308.063
82.1
7981 .024
10702.499
539.854
34047.375
2464.629
2151.186
412.601
486.711
19227.254
















Rt i
TotalVoL i
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















frtL
RnalVol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dilution
Factor
1
10
1
1
1
5
1
100
1
1
100
1
1
1
100
















Total ug
Result
29.9
66.3
836
< 0.100
231
41.1
798
107000
54.0
3400
24600
215
41.3
48.7
192300
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:       PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-3-H2O2 BH
185-26-3DBH
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06- 11 & 19. 1997
Air
Analyte-
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone*
(uoto
8.861
4.2
61.4951
0.194
26.755
4.3
78.615
5828.679
34.552
110.770
1501.071
9.779
8.043
0.9
9978.375
















Ol
TotarVc-l
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
















rtL
Used
900
900
900
900
900
900
900
900
900
900
900
900
900
900
900
















ml
RnsiVd.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















TotaNg
Result
0.985
< 0.833
6.83
< 0.111
2.97
0.478
8.73
648
3.84
12.3
167
1.09
0.894
< 0.222
1110
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:       PES, Inc.
 Project Number:	
42452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M33,M34,O-M29-1-FHAR FH
188-52-9.10.185-26-4CFH
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06- 11 & 19. 1997
Air
Anah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
(uc^L)
49.120
49.4
525.725
2.167
86.064
40.9
617.358
643.586
91.412
3061.411
8243.760
105.580
58.554
40.443
66464.688
















mi.
TctelVbL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Usecf
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mt
RrialVol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















dutton
fiaetor
1
1
1
1
1
1
1
100
1
1
1
1
1
1
1
















Total ug
Result
4.91
4.94
52.6
0.217
8.61
4.09
61.7
6440
9.14
306
824
10.6
5.86
4.04
6650
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                  Printed:   20-Nov-97  at  04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-1-H2O2 BH
185-26-4DBH
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19. 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cona
fosto
1.115
0.6
4.164
-0.067
0.388
1.0
11.139
12.844
5.895
75.216
13.193
4.896
1.330
0.1
86.853
















Rt
Total VoL
540
540
540
540
540
540
540
540
540
540
540
540
540
540
540
















rnL
Used
440
440
440
440
440
440
440
440
440
440
440
440
440
440
440
















nt
Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















D8utiort
factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totals :
Result ;
0.137
< 0.920
0.511
< 0.123
< 0.123
< 0.184
1.37
1.58
0.723
9.23
1.62
0.601
< 0.368
< 0.245
10.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                          Printed:   20-Nov-97  at  04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ED:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
Beaker No.M35,M36,0-M29-2-FHAR FH
188-52-1 1.12.185-26-5CFH
Sept. 30 & Oct. 28, 1997
Oct. 31 -Nov. 04, 1997
November 06 -11 & 19, 1997
Air
Arelyte-
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
(not*
76.664
60.6
1026.195
5.073
217.630
43.9
1013.231
1082.762
97.079
508.692
15648.782
139.702
78.002
49.218
1265.164
















rrt
Total Vol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















rnL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















rri.
FJnalVol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dilution
Factor
1
1
1
1
1
1
1
100
1
1
1
1
1
1
100
















Total yg
Result
7.67
6.06
103
0.507
21.8
4.39
101
10800
9.71
50.9
1560
14.0
7.80
4.92
12700
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                   Printed:   20-Nov-97 at  04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-2-H202 BH
185-26-5DBH
Sept 30 & Oct. 28. 1997
Oct 31 -Nov. 04. 1997
November 06- 11 & 19. 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
futfU
1.856
0.90
7.619
-0.059
13.351
11.9
13.390
23.408
20.752
120.396
131.061
8.067
12.750
1.3
156.465
















rot
TotetVoi
850
850
850
850
850
850
850
850
850
850
850
850
850
850
850
















mL
Used
750
750
750
750
750
750
750
750
750
750
750
750
750
750
750
















rr4
Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Diutior^
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Total ug
Result
0.210
< 0.85
0.863
< 0.113
1.51
1.35
1.52
2.65
2.35
13.6
14.9
0.914
1.44
< 0.227
17.7
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
Client:       PES, Inc.
Project Number:	
43452
 Sample Report
Ghent Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed'
Matrix:
Beaker No.M37,M38,0-M29-3-FHAR FH
188-52-13.14.185-26-6CFH
Scot. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06 -11 & 19. 1997
Air
Analyte"- •
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
71
Zn
















Cone.
&tfU
19.956
20.3
364.474
0.739
40.157
19.7
260.967
15267.756
57.392
881.175
4525.863
87.368
46.901
9.7
27701.213
















ml :
TotelVoL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Diution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Total u<3
Result
2.00
2.03
36.4
< 0.100
4.02
1.97
26.1
1530
5.74
88.1
453
8.74
4.69
0.970
2770
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                  Printed:   20-Nov-97 at  04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
0-M29-3-H202 BH
185-26-6DBH
Sept. 30 & Oct 28. 1997
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19, 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
&c*U
0.496
-0.3
4.640
-0.142
0.400
0.0
9.143
27.304
5.253
69.649
14.850
2.873
0.917
1.1
105.025
















mL
Total Vol.
510
510
510
510
510
510
510
510
510
510
510
510
510
510
510
















rnL
Used
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
















rri
RnaJVdL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Oluttw
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totaf ug :
Result '•.
< 0.124
< 0.933
0.577
< 0.124
< 0.124
0.187
1.14
3.40
0.653
8.66
1.85
< 0.498
< 0.373
< 0.249
13.1
















Triangle Laboratories, Inc.
801 Capitola Dnve * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:      PES, Inc.
 Project Number:	
42452
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No.M41,M42,0-M29-BL
188-52-17.18.185-26-7CFH
Sept. 30 & Oct. 28. 1997
K-FHARFH


Oct. 31 -Nov. 04, 1997
November 06- 11 & 19. 1997
Air
Aoah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
(tio/U
1.286
3.3
129.797
-0.018
-1.160
6.4
70.559
15.439
40.309
51.869
2.369
38.886
40.653
7.2
102.083
















Ht ;
Total Vd.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















tnL
Final Vol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Olution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Total m
Result •'
0.129
< 0.750
13.0
< 0.100
< 0.100
0.640
7.06
1.54
4.03
5.19
0.237
3.89
4.07
0.720
10.2
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                  Printed:  20-Nov-97  at  04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-BLK-FHAR-H2O2 BH
185-26-7CDBH
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19, 1997
Air
Attah/te
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Gone.
{iiqflJ>
1.279
0.6
3.665
-0.053
0.684
0.4
7.373
46.947
-0.385
43.515
10.807
5.495
0.439
6.1
67.789
















roL
TctalVol
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
















mL
Used
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
















H*.
RnatVdL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















DiJutfor*
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totaiuq
Result ;
0.128
< 0.750
0.366
< 0.100
< 0.100
< 0.150
0.737
4.69
< 0.300
4.35
1.08
0.550
< 0.300
0.610
6.78
















Triangle Laboratories, Inc.
801 Capitola Dnve * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                         Printed:  20-Nov-97  at   04:28 PM
-------
 Client:      PES, Inc.
 Project Number:	
45452
 Sample Report
Client Sample ID:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No.M43,M44,M45,0-M29-RB-0
188-52-19.20.21. 185-26-8E FH
Scot. 30 & Oct. 28. 1997
1N HNO3 FH


Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19. 1997
Air
Attatyt^
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cona
&0/U
2.568
21
991 .093
-40.530
-3.530
97.5
304.915
183.382
119.127
747.386
44.093
44.077
45.659
-0.0
491 .286
















lit.
TotalVol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















fflL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mt
Final Vot
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dilution
{•actor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Total ug
Result
0.257
2.10
99.1
< 0.100
< 0.100
9.75
30.5
18.3
11.9
74.7
4.41
4.41
4.57
0.200
49.1
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                  Printed:   20-Nov-97  at   04:28 PM
-------
 Client:       PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
M29-RB-DI H2O FH
185-26-8HFH
Sept. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04 & 05, 1997
November 6-11 & 19. 1997
Air
Arelyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone.
&0/U
0.411
0.6
4.569
-0.150
-0.471
4.4
7.673
3.502
3.484
0.817
1.185
4.794
2.428
2.5
14.394
















mL
Total Vol.
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
















mL
Used
44
44
44
44
44
44
44
44
44
44
44
44
44
44
44
















mL
RnsfVoL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Btutior*
fetor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totafug
Result
< 0.100
< 0.750
0.457
< 0.100
< 0.100
0.440
0.767
0.350
0.348
< 3.00
< 0.200
0.479
< 0.300
0.250
1.44
















Triangle Laboratories, Inc.
801 Capitola Dnve * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:       PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
0-M29-RB-HN03/H20Z0.1N HN03
185-26-8DEBH
BH

Sept. 30 & Oct. 28, 1997
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19, 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cone,
(utfU
0.560
-1.2
2.298
-0.107
-0.014
0.1
5.178
2.714
-1.556
32.808
5.703
3.737
-0.536
2.2
46.883
















trl
Total VoL
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
















ttiL
Used
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
















Bt
Final Vol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dtutron :
factor :
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Totafug •
Result
< 0.100
< 0.750
0.230
< 0.100
< 0.100
< 0.150
0.518
0.271
< 0.300
3.28
0.570
< 0.400
< 0.300
0.220
4.69
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                          Printed:   20-Nov-97  at   04:28 PM
-------
 Client:       PES, Inc.
 Project Number:	
43452
 Sample Report
Client Sample ID:
TLI Sample ED:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No.M31,M32,I-M29-4-FHAR FH
188-52-7,8,185-26-90 FH
Scot. 30 & Oct. 28. 1997
Oct. 31 - Nov. 04 & 05, 1997
November 6- 11 & 19. 1997
Air
Artalvt&
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















•Cone.
:{UQ/U
181.759
84.5
10862.378
-2.354
1839.752
85.0
7506.006
11515.893
456.268
33490.906
2559.745
2528.033
446.947
520.430
24973.715
















mL> ::
TotatVol "
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















:- •;. ; nC:^'
X' •'. .lfeedl;-;-
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















,.-:,.:, mf .
: ::RnalVol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















DSutfeH;: --:-:
••••• :-':l=Jsetbif :
1
10
1
1
1
5
1
100
1
1
100
1
1
1
100
















:xi-l«taliJig^'.:|i;:i
•:|-:|Ri^itlM;pJ
18.2
84.5
1090
< 0.100
184
42.5
751
115200
45.6
3350
25600
253
44.7
52.0
249700
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                          Printed:   20-Nov-97  at  04:26 PM
-------
 Client:      PES, Inc.

 Project Number:	
43452
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-4-H2O 1 OF 2,2 OF 2 BH
185-26-9D.il BH
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04 & 05, 1997
November 6- 11 & 19. 1997
Air
Anah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Gone.
{uoiU
1.326
-0.8
7.231
-0.068
1.588
1.5
10.776
413.740
1.896
78.195
59.330
5.136
0.750
0.5
558.737
















mt
Total Vol.
1098
1098
1098
1098
1098
1098
1098
1098
1098
1098
1098
1098
1098
1098
1098
















mL
Useef
998
998
998
998
998
998
998
998
998
998
998
998
998
998
998
















nt
RnalVoL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Diufion
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Total *JQ
Result
0.146
< 0.825
0.796
< 0.110
0.175
0.165
1.19
45.5
< 0.330
8.60
6.53
0.565
< 0.330
< 0.220
61.5
















Triangle Laboratories, Inc.

801 Capitola Drive * Durham, North Carolina 27713

Tele: (919) 544-5729 * Fax: (919) 544-5491
                          Printed:   20-Nov-97  at   04:26 PM
                                                                           r
-------
 Client:      PES, Inc
 Project Number:	
43452
 Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No.M39,M40,O-M29-4-FHAR FH
188-52-15.16.185-26-10C FH
Sent. 30 & Oct. 28. 1997
Oct. 31 -Nov. 04 & 05, 1997
November 6-1 1& 19. 1997
Air
Aralyte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
71
Zn
















Cone.
(uoL)
16.375
15.8
235.914
0.462
20.706
19.0
181.609
10393.382
55.149
519.517
2248.414
78.829
40.770
12.3
25008.109
















WL
Total VoL
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















mL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
















ml
RnalVoL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















Dfertjor*
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















Total yg I
Result ;
1.64
1.58
23.6
< 0.100
2.07
1.90
18.2
1040
5.51
52.0
225
7.88
4.08
1.230
2500
















Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
-------
 Client:       PES, Inc.
 Project Number:	
45452
 Sample Report
Client Sample ID:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analyzed'
Matrix:
0-M29-4-H2O2 BH
185-26-10DBH
Sept. 30 & Oct. 28. 1997
Oct. 31 - Nov. 04 & 05, 1997
November 6-11 & 19 1997
Air
Analvte-
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Cooa
(uoto
1.322
-0.4
4.148
-0.152
1.988
1.1
9.103
31.147
0.737
60.269
42.467
-0.819
8.306
1.6
125.499
















ni.
TotalVof. ^
535
535
535
535
535
535
535
535
535
535
535
535
535
535
535
















mL
Used
435
435
435
435
435
435
435
435
435
435
435
435
435
435
435
















mL
RnafVol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
















DSutibff--?
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
















; xiTbtefug
;- Result-
0.163
< 0.922
0.510
< 0.123
0.244
< 0.184
1.12
3.83
< 0.369
7.41
5.22
< 0.492
1.02
< 0.246
15.4
















Triangle Laboratories, Inc.
801 Capuola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                         Printed:   20-Nov-97  at   04:26 PM
-------
 Client:       PES, Inc.
 Project Number: 43452
QA: Serial Dilution
Client Sample ID:
TI. I Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M25.M26.I-M29-1-FHAR FH
m-52-1.2.185-26-irFH
Oct. 31 - Nov. 04, 1997
November 06 - 11 & 19, 1997
Air
Beaker No. M25JM26.I-M29-1 -FHAR FH L
188-52-l.2.l85-26-irFHT,
Oct. 31 -Nov. 04. 1997
November 06 - 11 & 19, 1997
Air

Anatvte :
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
71
Zn
















Native Sample
: Totattjg
Result
10.8
28.2
406
< 0.100
82.8
31.3
502
61300
37.5
476
9560
66.5
25.1
308
77200
















ugfc
Cone*
108.353
56.300
4060.503
-7.919
828.458
62.600
5019.044
6126.112
375.269
4764.237
955.950
665.061
250.750
307.846
7722.537
















Serial Dilution
Total tig
Result
12.3
27.3
424
< 0.500
97.0
40.7
574
62400
44.9
530
9610
74.4
23.5
395
78200
















ugt
Conc,
24.699
54.600
847.781
-1.217
193.935
81.400
1147.985
1247.558
89.861
1060.123
192.128
148802
46.977
78983
1564.468
















BPO
13.0%
-------
 Client:      PES, Inc.
 Project Number: 43452
QA:  Serial Dilution
Client Sample ID:
TLI Sample ID-
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1-H202BH
185-26-1DBH
Oct. 31 -Nov. 04. 1997
November 06 - 11 & 19. 1997
Air
I-M29-1-H202BHL
185-26-1DBHL
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19, 1997
Air

Anah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Native Sample
Totdug
Rest*
0.245
< 0.900
0.672
< 0.120
0.326
0.264
1.80
11.6
0.863
11.1
11.6
0.890
0.427
< 0.240
62.7
















ug€ ;
Cone;
2.038
3.300
5.604
-0.075
2.715
2.200
15.011
96.612
7.191
92.266
96.694
7.416
3.555
0.4
522.834
















Serial Dilution
Total ug
Result
< 0.600
< 4.50
< 1.20
< 0.600
< 0.600
0.900
< 1.20
12.3
< 1.80
< 18.0
12.4
< 2.40
< 1.80
< 1.20
70.5
















ug/t
Conc>
0.775
-1.200
1.016
-0.141
0.317
-0.000
1.991
20.497
0.713
11.532
20.616
-0.313
-0.905
0.7
117.430
















RPD
-------
 Client:
 Project Number:
PES,Inc.
                       43452
QA: Duplicate
Client Sample ID:
TLI Samole ID:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M27.M28.I-M29-2-FHAR FH
188-52-3A185-26-2CFH
Oct 31 -Nov 04. 1997
November 06 - 11 & 19, 1997
Air
Beaker No. M27 M7JU-M29-2-FHAR FH DA
188-52-3,4, 185-26-2C FH DA
Oct 31 - Nov 04. 1997
November 06 - 11 & 19, 1997
Air

Anah/te
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Sample
Total ug
Result
25 2
82.4
1170
2.37
231
46.7
1020
140800
55.7
5560
22300
54.4
60.0
63.7
160700
















ug/L
Cortex
251 685
82.4
11740.365
23.654
2313.309
93.4
10238.519
14077.762
556.573
55553.270
2225.871
543.854
600.472
636.570
16070.912
















Duplicate
Tctal ug
fiesatt
24.7
N/A
1190
2.34
227
N/A
1010
149500
55.2
5550
23800
59.1
58.7
63.2
172100
















ug/t
Cem
246.918
N/A
11855.433
23.371
2270.033
N/A
10054.249
14953.808
552.032
55487.777
2384.730
590.575
587.472
632.233
17206 398
















IRPD
2.00%
N/A
1.69%
1 .27%
1.75%
N/A
0.985%
5.99%
0.902%
0.180%
6.51%
8.28%
2.19%
0.788%
6.85%
—
	 .
—
—
—
—
_
—
_
—
—
—
—
„
—
—
Triangle Laboratories, Inc.
801 Capitola Dnve * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                  Pr
20-Nov-97
                                                                  at
04:43 PM
-------
 Client:
 Project Number:
PES,Inc.
                       43452
QA: Duplicate
Client Sample ID:
TLI Sample CD-
Date Prepared:
Date Analyzed:
Matrix:
I-M29-2-H202 1 OF 2.2 OF 2 BH
185-26-2D.12BH
Oct. 31 -Nov. 04. 1997
November 06- 11 & 19. 1997
Air
I-M29-2-H2O2 1 OF 2.2 OF 2 BH DA
185-26-2D.12BHDA
Oct. 31 -Nov 04. 1997
November 06 -11 & 19. 1997
Air

Analvte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Sample
; Total og
Result
2.32
1.90
32.0
0.205
10.7
4.12
27.9
3360
2.06
99.1
497
3.89
1.59
< 0.217
4090
















ug/t
Cone.
21.359
17.5
294.765
1.890
98.350
37.9
256.897
30967.557
18.969
912.030
4575.688
35.767
14.641
0.7
37672.477
















Duplicate
TolaJug
Ftesuft
244
N/A
31.9
0.206
10.8
N/A
28.2
3850
2.18
99.9
501
4.24
1.54
N/A
4140
















ug/L
Cone.
22434
N/A
293.313
1.894
99.234
N/A
259.333
354.705
20.029
919.878
4613.094
39.051
14.208
N/A
38076.535
















RPD
5.04%
N/A
0.313%
-------
 Client:  PES, Inc.
 Project Number:
43452
QA: Matrix  Spikes (Post-Digestion)
Client Sample ID:
TLJ Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
Beaker No. M25,M26,I-M29-1-FHAR FH PDS
188-52-1.2.185-26-1C FH PDS
Oct. 31 -Nov. 04, 1997
November 06 - 11 & 19, 1997
Air






AnaMe-
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Post-Dia
Recovered
Amount (uat?
151.75
97.4
3994.51
32.58
871.87
85.7
5057.21
6106.34
416.45
5593.92
1001.89
696.81
295.75
368.99
7879.28
















estion Spike
Sp&B
Amount teat J: ;
50
50
50
50
50
25
50
50
50
1000
50
50
50
50
200
















%:,.•
Recovery
87°/
82°/
Spike Low
65°/
Spike Low
92°/<
Soike Low
Spike Low
Spike Low
83°/<
Spike Low
Spike Low
Spike Low
Spike Low
Spike Low
















Post-Diqestion Spike Duplicate
Recovered
Afnoantfuq/U































Sp&ex:-.
Afnoofltfoot}































%
Recovery































; RPD
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
	
	
—
	
	
	
	
	
—
	
—
—
	
—
Tnangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                                          Printed:    20-Nov-97
                                                                 at
04:30 PM
                                                                                         4r>
-------
Client:  PES,Inc.
Project Number:
43452
QA: Matrix Spikes (Post-Digestion)
Client Sample ID:
TLI Sample ED:
Date Prepared:
Date Analvzed:
Matrix:
I-M29-1-H202BHPDS
185-26-1DBHPDS
OcL 31 -Nov. 04. 1997
November 06- 11 & 19. 1997
Air






Anatvta
Aa
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Post-Diqestion Spike
Rec*>w$rek}
Amount ftjoti
40.27
52.1
53.78
46.36
51.32
N/A
61.84
143.39
54.76
953.49
143.09
52.50
39.58
23.2
703.35
















S&fca
Amount fuc$U
50
50
50
50
50
N/A
50
50
50
1000
50
50
50
25
200
















%
Fteeoverv
76°/<
104°/<
96°/
93°/
97°/
N/A
94°X
94°/
95°X
86°/
93°/
90°/
72°/
93°/
90°/
















Post-Diaestion Spike Duplicate
Recovered
Amount (Uo/U































Spi®
;Amcnwt(ya/Lii































% :
Recovery































; HPO
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
--
—
—
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919)544-5729 * Fax: (919)544-5491
                                               Printed:
20-Nov-97
04:43 PM
-------
 Client:    PES, Inc.
 Project Number:   43452
QA: Method Blank
TLJ Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43452 MB
Oct. 31 -Nov. 04, 1997
November 06 - 1 1 & 19, 1997
N/A

£palvt«:
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
















Method Blank
Recovered !
Amouttiuo'lJ
-0.47
-0.30
-0.05
0.01
-0.37
0.70
-0.92
0.12
-1.13
-12.45
0.20
-1.43
0.08
-2.46
5.47
















Oeffctttm
iMi.isoiy 	
1
7.5
2
1
1
1.5
2
2
3
30
2
4
3
5
12
—
—
—
—
—
—
—
—
—
—
	
—
—
—
—
—

Pasaor
Fai
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
	
	
—
—
—
	
	
	
—
—
	
	
—
	
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed:  20-Nov-97
                       at
-------
 Client:   PES, Inc.
 Project Number:   43452
QA: GFAA Method Blank
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43452 MB
Oct. 31 -Nov. 04 & 05, 1997
November 6-11 & 19, 1997
N/A

Analyte
Tl






























Method Blank
ffecovered
Amount (uoD
1.20






























Defection
Umft(uq/L)
2
—
—
._
—
~
...
—
—
._
—
—
—
—
—
—
—
—
—
—
„
—
—
—
—
—
—
_.
—
—
._

Pass or
Fail
Pass
...
—
—
—
—
—
—
—
—
—
—
—
—
—
— ,
—
—
„
—
._
—
—
._
—
—
—
—
—
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 2771
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: 20-Nov-97
at
04:26 PM
                                                                       A ^
-------
 Client:  PES, Inc.
 Project Number;
43452
QA: Lab Control Spikes
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43452 LCS
Oct. 31 -Nov. 04,
November 06 - 1 1
1997
& 19, 1997
N/A





Artalvte
Aq
As
Ba
Be
Cd
Co
Cr
Mn
Ni
P
Pb
Sb
Se
Tl
Zn

















Recovered ;
Amount 
-------
 Client: PES, Inc.
 Project Number:
43452
QA: GFAA Lab Control Spikes
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
43452 LCS
Oct. 31 -Nov. 04 & 05, 1997
November 6-11 & 19. 1997
N/A





Analyte •
71






























Lab Control Spike
Recovered
Amount (uo/L)
40.20






























Spike
Amount {ug/i.)
50






























%
Flecoverv
80%






























Lab Control Spike Duplicate
Recovered
Amount fuq/t)































• , -Spike
Amount{ug/L)































%
Recovety































RPD
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
...
—
—
—
—
—
—
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
                           Printed:    20-Nov-97
at
-------
 Client:
                                            PES.Inc.
 Sample Report
Page 1 of 3
Dale Received-
D.iie Prepared:
D:ire Analvzed:
DATA FILE:
Malnx
Sew. 30 & Oct.28. 1997
Ocl.31 -Nov 6. 1997
November 06. 1997
AM 33
Air
                                                                                                       ANALYTE: Ho
                                                                                                       [jo/1 HDL-  0.2
                                                                                                       Anatvsrs Method:
                                                                                                       Instrument: P E Zeeman 5100
                                                                                                       Sake Cone. (ug/U
                                                                      CVM ANALYTC SUMMARY REPORT
MertSampteJD
3eaker No.M25,M26,l-M29-1-FHAR FH
3eater NO.M25.M26J-M29-1-FHAR FH D
I-M29W2O2 BH
I-M29-H202 BH D
I-M29-1-8HAR HNO3
I-M29-1-BHARHNO3D
I-M29-1-KMNO4 KMVO4
I-M29-1-KMNO4 KMnO4 D
I-M29-1-HCLHCI
I-M29-1-HCLHCID
Beaker No.M27,M28,i-M29-2-FHAR FH
Beaker NO.M27.M28J-M29-2-FHAR FH D
I-M29-2-H2O2 1 OF 22 OF 2 BH
I-M29-2-H2O2 1 OF 22 OF 2 BH D
Beaker NO.M29.M30.I-M29-3-FHAR FH
Beaker NO.M29.M30J-M29-3-FHAR FH D
I-M29-3-H2O2 BH
I-M29-3-H2O2 BH D
I-M29-3-BHAR HNO3
I-M29-3-8HAR HNO3 0
I-M29-3-KMNO4 KMnO4
I-M29-3-KMNO4 KMnO4 D
Beater No.M33,M34,O-M29-1-FHAR FH
Beaker NO.M33.M34.O-M29-1-FHAH FH D
O-M29-1-H2O2BH
O-M29-1-H2O2 BH 0
O-M29-1-8HARHNO3
O-M29-1-8HAH HNO3 D
O-M29- 1 -KMNO4 KMnO4
O-M29- 1 -KMNO4 KMnO4 D
Beater No.M3S,M36,O-M29-2-FHAR FH
Beater No.M3S,M36.O-M29-2-FHAR FH D
O-M29-2-H2O2 BH
O-M29-2-H202 BH D
O-M29-2-BHAR HNO3
O-M29-2-8HAR HNO3 D
O-M29-2-KMNO4 KMnO4
O-M29-2-KMNO4 KWiO4 D
O-M29-2-HCL HCI
O-M29-2-HCL HCI D
Beater Mo.M37.M38.O-M29-3-FHAR FH
Beater No.M37,M38.O-M29-3-FHAR FH D
O-M29<3-H2O2 BH
O-M29-3-H2O2 BH D
O-M29-3-6HAR HNO3
O-M29-MHAR HNO3 D
O-M29-3-KrvtO4 KMnO4
O-M29-3-KMNO4 KMnO4 0
O-M29-3-HCL HCI
O-M29-3-HCLHCID
TUSftMfflC
18S-S2-1Z18S-26-1C
188-52-1 .2.185-26-1CD
185-26-1D
185-26-1DO
185-26-1 E
185-26-1 ED
185-26-1F
185-26-1FD
185-26-1G
185-26-1G D
188-52-3A185-26-2C
188-52-3,4.18S-26-2C D
185-26-20,12
185-26-20,12 D
1 88-52-5,6, 18S-26-3C
1 88-52-5,6, 18S-26-3C 0
18S-26-3D
185-26-3DD
18S-26-3E
185-26-3ED
185-2&3FDX2
185-26-3F DX2 D
188-52-9.10.185-2&4C
188-52-9.10.185-26-4C D
185-26-d
185-26-WDD
1S5-2&4E
185-26-4ED
185-26-4F
185-26-4FD
188-52-11, 12.185-26-5C
188-52-1 1,12,185-26-SCD
185-26-5D
185-26-5D D
18S-26-5E
iaS-26-5ED
185-26-5F
18S-26-5FO
185-26-5G
185-26-5GD
188-52- 13,1 4, 18S26-6C
188-52-13,H.1B5-26-6C D
185-26-6O
185-26-6OD
185-2&6E
185-26«EO
185-26-6F
1S5-2&«FD
1S5-26-6Q
185-2&6QD
ugfL
COW
0.122
0.096
0.039
0.042
0.013
O.OOS
0/78
0.507
0.026
0.021
0.130
0.125
0/»10
0.442
1.546
1/76
0.803
0.790
0.096
0.096
4^23
SJ05
0.049
0.023
0.010
0.010
0.029
0.021
0.894
0556
0.031
0.016
0.036
0.029
0.018
0.023
1.922
Z172
0.047
0.039
0.018
0.023
0.055
0.057
0.010
0.005
aosi
8.695
0.166
0.174
rrf
ly
(*A
N/A
600
600
104
104
390
390
235
235
r-VA
N^A
1260
1260
N/A
MM
1000
1000
122
122
400
400
N/A
N/A
540
540
104
104
400
400
NVA
N/A
850
850
135
135
395
395
222
222
NW
WA
510
510
114
114
305
305
210
210
at
f*
100
100
N/A
N/A
fVA
NTA
N/A
N/A
N/A
N/A
100
100
N/A
N/A
100
100
N/A
N/A
NIA
N/A
N/A
NIA
100
100
IYA
N/A
N/A
N/A
N/A
N/A
100
100
I*A
NIA
N/A
N/A
N/A
N/A
WA
N/A
100
100
N/A
N/A
N/A
NIA
N/A
N/A
N/A
N/A
irt
AfiW*
5
5
S
5
S
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
£JtL
FACTO'
1
1
1
1
1
t
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
1
1
1
t
1
1
1
1
1
1
1
1
t
t
1
1
1
1
1
t
1
1
1
1
1
t
1
t
•IQM-UQ
sesun
< 0/00
< 0.400
< 2.40
< 2.40
< 0/16
< 0.416
373
3^5
< 0540
< 0.940
< 0/00
< 0.400
103
11.1
3.09
235
16.1
15.8
< 0.488
< 0.488
78.8
843
< 0/00
< 0.400
< 2.16
< i16
< 0/16
< 0/16
7.15
7.65
< 0.400
< 0.400
< 140
< 3.40
< 0.540
< 0.540
15.2
17.2
< 0.888
< 0.888
< 0.400
< 0.400
< 2.04
< 2.04
< 0.4S6
< 0.456
49.1
53-0
< 0.840
< 0.840
A*g.
	 mm?
< 0/00
< 2.40
< 0.416
3.84
< 0.940
< 0.400
10.7
3.02
15.9
< 0.488
81.8
< O/OO
< 2.16
< 0.416
7/0
< 0.400
< 3.40
< 0.540
167
< 0.888
< 0.400
< 2.04
< 0.456
51.1
< 0340
..WO.
-
-
-
-
-
-
-

_

-
_
_
_
-
_
_
_
_
_
_
-

_
-
. r^eu.
-
-

-
-
_
-
-
_
-
_
-
_
-
_
_



_
:
_
_
_
-
"nangle Laboratories. IDC.
101 Caprtda Drue ' Durham. North Caroina 27713
'ete: (919) 544-5729 ' Fax: (919) 544-5491
                    Printed:   20-Nov-97
-------
aitnt: ' PES.LIC.
Prnifft Ni'mhrr- 114S2
•ample Report Page 2 ot 3
~mt Rccentd:
3nc Prepared:
"'•Me \najv7ed:
EAFILE
"•

Ocl 31 - New <5 1997
November 06. 1997
AB833
Air

ANALYTE Ha
ual-RDL: 02
Analyses Method: 29
Instrument P E Zeeman 5100
SoikfiConc (uo/L) 5

                                                                        CVAA ANALYTE SUMMARY REPORT
Lnt SaniptelCi :; K. '•
leaker NoJvVH,M42.O-M29-8LK-FHAR FH
Beaker NO.M41.M42.O-M29-BLK-FHAR FH D
FLK-FHAR.H2O2 BH
IK-FHARH202 BH 0
O-M29-BLK-6HAR HNO3
O-M29-8LK-eHAR HNO3 0
l-M29-eLK-KMNO4,R8-DI H20 KMnO4
IM29-BLK-KMNO4.RB-DI H20 KMnO4 D
O-M2^BLK-KMNO4,HCURB-CX H20 HCI
O-M29-eiK-KMNO4j-tCLRB-OI H20 HCI D
leaker No.M43,M44,M45,M29-HB-0. 1 N HNO3 FH
Meaker No.M43.M44,M4£.M29-RB-0.1NHNO3FHD '
M29-RB-HNO3/H2O2.0.1 N HNO3 BH
M29-RB-HNO3/H2O2.0. 1 N HNO3 BH D
•29-flB-O. 1 N HNO3 HNO3
p29-flB-0. 1 N HNO3 HNO3 D
M29-RB-KMNOVH2SO4.DI H20 KMnO4
^29-flB-KMNO4/H2SO4.D H20 KMnO4 D
B.29-RB-KMNCWH2SO4.8N HCL.DI H20 HCI
•29-RB-KMNO4/H2SO4.SN HCUD H20 HCI D
M29-RB-OIH20
^29-RB-OI H20 0
Beaker NO-M31 ,^e2,l-M^9-A-FHAR FH
Seakw NoA<31 .MSaj-NOS-t-FHAR FH D
I-M2W-H2O2 1 OF 22 OF 2 BH
B/2W-H2O2 1 OF 22 OF 2 BH D
•M2&4-8HAR HNO3
?M2»4-BHAR HNO3 D
I-M29-4-KWNO4 KVWM
•M29-4-KMNO4 KWnO4 D
Iftakar NoJvt39,M40,O-M29-4-FHAfl FH
BMkw ^lo.M39.^MO.O-M2^-4-FHA^:t FH 0
EH2O2BH
H2O2 BH 0
BHARHNO3
O-M2J-4-BHAR HNO3 D
•-M2W-KMNO4 KWnO4
B-M2^4-KWNOl KKAiO4 D
WfSAM^^<*OtU
F>CTD(
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
t
1
1
1
1
1
1
1
t
1
t
1
1
1
1
1
1
1
1
1
1
••••:•: ^RXalMS
	 HESUtl
< 0.400
< 0.400
< 0.600
< 0.600
< 0.400
< 0.400
< 1.60
< 1.60
< 0.880
< 0.880
< 0.400
< 0.4OO
< CL600
< 0.6OO
< 0.116
< 0.116
< 1.60
< 1.60
< 0520
< 0520
< 0.176
< 0.176
< 0.400
< 0.400
11.0
9.93
0^38
0^99
6.01
6.05
< 0/400
< 0.4OO
< 2.14
< 2.14
< 0.432
< 0.432
14.0
16.0
..•., : ft¥5, .
BESttLT

< 0.400
_
< 0.600

< 0.400

< 1.60
_
< 0^80
< 04OO
_
< 0.600

< 0.116
_
< 1.60
_
< 0520
_
< 0.176
_
< 0.400
_
10/4
_
0368

S.03
< 0.400
_
< 2.14

< 0.432
15.0
FPO

-
_
-
_
-


_


_
-
_
-
_
-
_
-
_
-
_
-
_
-
„
-
_

-
_
-
_
-
-
•'iJtfiSS1

-
_


-



-

_




-
_
-
_
-
_
-


_
-


-
_

_

-
TnangK Laboratories. Inc.
901 CapKola Ove ' Durham, Morth Caroiru 27713
•to: (919) 544-5729 • Fax (919) 544-5491
-------
                                          PES.Inc.
 Sample Report
Pag«3ol3
Dale Rtcriwd:
Dale Preoared:
Date Analvzed:
DATA FILE.
Matnx
Sew 30 & On 28. 1 997
Ocl. 31 - Nov 6. 1997
November CK5. 1997
AB833
Ail
ANALYTE Ha
uatRDL: 0.2
Analysts Method:
29
Instrument: P E Zeeman 5100
Saks Cone, (ua/lj
5
                                                                   CVAA ANALYTE SUMMARY REPORT
Sent SarntifaiD ; :
I-M29-H2O2 BH MS
I-M29-H2O2 BH MSD
aM29-1-H2O28HMS
O-M29-1-H2O2 BH MSD
O-M29-2-H2O2 BH MS
0-M29-2-H202 BH MSD
O-M29-44H2O2 BH MS
O-M29-4+I2O2 BH MSD
I-M29-H2O2 BH MS
I-M29-H2O2 BH MSD
O-M29-1-H2O2BHMS
O-M29-1-H2O2 BH MSD
O-M29-2-H2O2 BH MS
O-M29-2-H2O2 BH MSD
O-M29-WH2O2 BH MS
OM29-44^O2 BH MSD
Method Blank
Method Blank D
.CS
.CSO
detnod Blank
Method Blank D
.CS
.CSD
TU-SAMP10
185-26-1DMS
185-26-1DMSD
18S-2&4OMS
18S-26-5DMS
185-26-5OMSD
185-26-10OMS
1 85-26- 10OMSO
True Spike MS
True Spike MSD
True Spike MS
True Spike MSD
TrueSpxkeMS
True Spike MSO
True Spike MS
True Spike MSD
43452 MB1
43452 MB1 D
43452 LCS1
43452 LCS1 D
434S2MB2
43452 MB2D
43452 LCS2
43452 LCS2D
•CONS
4374
5.009
4.027
4.159
5204
5.562
5.404
5.674
5
5
5
5
5
5
in en
0.023
0.005
4.744
4324
0.018
0.010
5.157
5.180
::$:;;
600
600
540
540
850
850
535
535
600
600
540
540
850
850
535
535

-
_

IWK
WA
N/A
UA
NIA
NIA
WA
™
r^A
WA
N/A
_
_
_
-
ASquoi
5
5
5
5
5
5
5
5
5
5
5
5
5
5
in in
_.
_
.
-
FACTCJF
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
-
_
_
"
... foW ug
'f ferns
58.5
60.1
43.5
44^
Ha;
94.6
573
60.7
60.0
60.0
54.0
54.0
85.0
85.0
53.5
53^

-
-
"
i-iEstk
593
442
9^
SS3
-

-
-
_
_
-
-
tyi
2.73%
3^3%
6.65%
4.87%
-

-
-
_
_
_
~~
ms*3*.
97%
100%
81%
83%
104%
111%
108%
113%
-
-
-
-

95%
96%
-
103%
1CM%
Triangle Laboratories, Inc.
801 Caprtola Drive " Durham, North Caroina 27713
Teto: (919) 544-5729 * Fax (919} 544-5491
-------
'PACIFIC ENVIRONMENTAL SERVICES. INC.
                          Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919)941-0333 FAX: (919) 941-0234
                                                Chain of Custody Record
/

Project Numbs ^^003

Project Name
USE!


Samplers:
Dickerson, McDonald. Thompson. Dougherty, Hamilton
Date





















Time





















Field Sample ID
















i




Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
i


Date/Time
Dale/Time
DateTTime
Sample Description
-M29-1 -Filter
-M29-1 -Front Half Rinse
-M29-2-Filter
-M29-2-Front Half Rinse
-M29-3-Filter
-M29-3-Front Half Rinse
-M29-4-Filter
-M29-4-Front Half Rinse
O-M29-1-Filter
O-M29-1 -Front Half Rinse
O-M29-2-Filter
O-M29-2-Front Half Rinse
O-M29-3-Filter
O-M29-3-Front Half Rinse
O-M29-4-Filter
O-M29-4-Front Half Rinse
O-M29-BLK-Filter
0-M29-BLK-Front Half Rinse
0-M29-RB-3 Filter
0-M29-RB-4-Filter
0-M29-RB-Acetoije f\
Ret*
Reel
Rece
L
Analysis Requested
MM
•
•
•
•
•
•
•
•
•
•
•
•
•
•


•
•
•
•
•
Hg
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
.
•
•




































•*





























ved by: (Signature^ / J^, Relinquished by: (Signature)
i/ed by: (Signature^7 Relinquished by: (Signature)












































Dale/Time
Date/Time
Ivedfor lab by. (Signature) REMARKS
WJfatT
Remarks
Beaker No. M25
Beaker No. M26
Beaker No. M27
Beaker No. M28
Beaker No. M29
Beaker No. M30
Beaker No. M31 i
Beaker No, M32
Beaker No. M33
Beaker No. M34
Beaker No. M35
Beaker No. M36
Beaker No. M37.
Beaker No. M38
Beaker No. M39
Beaker No. M40
Beaker No. M41
Beaker No. M42
Beaker No. M43
Beaker No. M44
Beaker No. M45 ,
Received by: (Signature)
Received by: (Signature)

jPage: ot
-------
PES, Inc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: PES Plant Location: Saglnaw, Ml facility
Rcllnqulihed fcj: (Signature)
'&*AJ jfl -VldrtA*
Rclfaoidfbedbpploiirfum) (
Rtlioipuibed bj: (Signature)
I
«
RelliH|ulihed by: (Signature)
i
field Sun pit
No.
l-M29-1-FHter
l-MW-l-FHAca
I-MW-I-FHAR
I-M29-I-H2O3
I.M29-I-BHAJV
I-M20-I-KMNO4
|
I-M29-I-HCL. (
•
KM29-*«ll»r ^
Oile
9/_J97
ai_jn
«/_j97
9/_/97
of_jn
V_jn
»/_/»7
B/_/B7
DateAIlBve
//^^
q-jo-f/ '
Dite/Iln*
/
Date/lime
Dale/Hat
Coinpolila
or Grab
Compotft*
Cempoini
Composite
Compotll*
Compojln
Convoalto
Compos ft*
Composite
Etccdvcil by: (Slgmlurt)
f3>L&-J?J
Rcoeiwd.by:(Sp|iului«) .
tf^W'W^
R«wlvcdl)y:(SI(natuie)
Received by: (Slfiwnue)
An*l}i)l RequlKd
EPA Method «/ EPA Method 29
EPA Mrihod V EPA MOhod 29
EPA Method »
EPAMMhod29
EPA Mrthod »
EPAM«(hod»
EPAM«thodZ9
*
EPA Mtftod Ef EPA Method 20
5»n>|>nn( 1>a)n
PartfeuteWMMtli
PBrSoutaWMMUi
MMdl
•
MMH»
•
MMflt
•
MM«J
»
MM<*
P«rtculBt«/MMIIt
Diu/now
Hi &0
5-^-4?-
f^;
/?57
Ditammo
Date/Time
SaraploDetcrlpdon
4* Quartz Flltw
Front Half
\cctonfl rV^isft
Rant W( Add HnM
O.IN HN09
8XHNOS/IOHHJ05
lrrpinfl«rtnrvae
Honk tap. Add ffrw»
O.f N HNO3
4KKMhM/tOKH2S
hnpinger+Hna*
8NHCI
4' Quartz niter

Dale:
Lab;
Train:
9/__J97
TLI
M29
Project Name: EPA Job No. 414.003
f* 	 .
LAnmiRnft
|
Comnenls
Comotatt
CtmincBlf
IpeeUlNoni
M29Ccntainwf1
1
M29Cerrtalnw«
M2BConWnarf3
M 29 Container #4
M 39 ConttftMT f SA
M»Contafn«-«B
M»Cont«Jn»r#BC
MI9Conta]n«r*l
Ub
PES/TU
1
PE8/TU
Til
(
TLI
i
1LI
*
TU
TU
-------
J
/^^yVfeLOf- -fVo^kUc. r\e.#dL(fW5 PES,lnc
^" /? /~~?T £V\ x- 4700 Duke Dr., Suite 150
#i- f^C;-5- J^ _.; / Mason, OH 45040
Z?U_ r~C>G\fr S € d
-------
FES, Inc
4700 Duke Dr., Suite 150
, , Mason, OH 45040
513-398-2556
Plant Name: PES Plant Location: Saginaw, Ml
Relinquished by: (Signature) '
"*J%^/^fc^
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
« i
Field Sample
No. ' |
I-M29-3-FHAH
I-M29-3-H202
•
I-M29-3-BHAR ''
l-M29-3-KMnO4
liM90i?iHCL


PMi9-BLK-rMAuu* |,
"A
IMBODLKrilAn '
Date
01 	 107
01 	 /97
01 	 107
01 	 /97
a; m

DJLJIJ.

O;_WWT-
Date/Tlme
/AW..
f-Jd-77
Date/Time
Date/Time
•
Dale/Time
Composite
or Grab
Composite
Composite
Composite
Composite


•eomposits 	

eempeslta 	
Received by: (Signature)
/^//£L-6/
Received by: (Signature)
fl^^^rt^
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
era MUIIIUO M-


.
1
Sampling Train
MMUs
MMBs
MMtts
MMUa


PallLulale/MMUs
nrirlBiinli -
Partleulale/MMUa
FirH Bin"1'
UUUv 	
Jalrl BlanK 	
Date/Time
X/rdo
-------
PES, /nc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: PES Plant Location: Saginaw, Ml
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.


\,UJO Bin OHAH_
LftlCO Dll< KMnB4
l'MBg'DLK-ll9L
I
'
i
^

Date



OL_/tf7
"' 	 '""
1
'
1

Date/Time
1-30-17
D»le/Tlrae
Date/Time
Dale/Time
Composite
or Grab


'
-CcmpwHa 	
Composite 	
'
'
'

Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required

t
EPAMelhedCO'p
EPA Mall lud 88
-EPA Mefted 09
:
:
:
•
Sampling Train
„
•nelJ Oaiilt 	
mold Dlonli
MMh
MMIto 	
t
:
i
i





Date/Time
*-•?,»-
Date/Time
Date/Time
Date/Time
Sample Description

Implnpnfimrnn,
01MIIM03
.*KMnQ4UaSJJ2a.
OH 1 101
.
*
.
•
Date:
Lab:
Train:
9/JO/97
TLI
M29 i
Project Name: EPA Job No. 414.003
Comments
Comment!
Comments
Comment!
Special Note!


•
MgBfinntnlnarffiP
MEUOiJlil,,*. *SL
*
*
,

Lab
TU
1
TU
TU
*
f
1
*
o
o

-------
PES, /nc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: PES Plant Location: Saglnaw, Ml
Relinquished by; (Signature)
-?iu4 o
?-3*-5>
Dale/Time
y-*qfr7
1^57
Date/Time
Date/Time
Sample Description
3* Quartz Filter
Front Half ^
Acetone Rinse
Front Hall Acid Rinse
Q.1NHNO3
5%HNO3/10%H202
Implnger+Rlnse
Blank Imp. Acid Rinse
0.1NHN03
4K KMnO4/tO% H2S
lmplnger+ Rinse
.
3- Quartz Filter
«
Date:
Lab:
Train:
9/ 	 /97
TLI
M29
Project Name: EPA Job No. 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container *1
M 29 Container <*2
M 20 Container #3
M 29 Container #4
M 29 Container #SA
M 29 Container #5B
i
M 29 Container <*t
1
Lab
PESmJ
PES/TU
(
TU
TU
TU
TU
TU
-------
PES, /nc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: PES Plant Location: Saginaw, Ml
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
I
Field Sample
No.
O-M29-2-FHAce '
OM2S-Z-FHAR
O-M29-2-H2O2
0-M29-2-BHAR
0-M29-2-KMN04
O-M29-2-HCL
O-M29-3-Filter |,
O-M29-3-FHAce
I
Date
0/_/07
01 	 /or
91 	 /B7
9/__/97
9/_/97
9/_JB7
01 	 197
9/_/97
Date/Time
lf'«w
/(•0D«k,
Date/Time
Date/Time
Date/Time
Composite
or Orab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method SI EPA Method 20
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method S/ EPA Method 29
1
EPA Method S/ EPA Method 29
Sampling Train
PartculaU/MMHs
1
MMDS
MMHs
MMHs
1
MMHs
MMHs
Partculate/MMds
ParHculale/MMtls





Date/Time
sr-oa
Date/Time
Date/Time
Date/Time
Sample Description
Front Hall
Acetone Rinse
Front Half Ao)d Rinse
0.1NHNO3
6% HNO3 / 10% H2O2
Implnger+Rlnse
Blank Imp. Acid Rinse
0.1NHNO3
4% KMnO4/10% H2S
Implnger+Rlnse
8NHCI
3" Quartz Filter
Front Half
Acetone Rinse
Date:
Lab:
Train:
9/ 197
TU
M29
Project Name: EPA Job No. 414.003
Comments
Comments
Comments
I
Comments
Special Notes
M 29 Container #2
M 29 Container #3
M 29 Container #4
, I
M 29 Container ISA
t
M 29 Container *5B
M 29 Container *5C
M 29 Container #1
M 29 Container #2
Lab
PES/TLI
TLI
TLI
TU
TU
TLI
PES/TLI
-------
PES, Inc
4700 Duke Dr., Suite 1 50
Mason, OH 45040
513-398-2556

Date:
Lab:
Train:
9/ 	 /97
TLI
M29
Plant Name: PES Plant Location: Saginaw, Ml Project Name: EPA Job No. 414.003
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
I
Relinquished by: (Signature)
Field Sample
No.
O.M29-3-FH/*|R
O-M29-3-H2O2
i
*
0-M29-3-BHAR
0-M29-3-KMnO4
0-M29-3-HCL
Q-M29-BLK-Rlter
0-M29-BLK-FHACB |,
O-M29-BLK-FHAR
Dale
8/ 	 /B7
9/_/97
9/ /97
97 197
01 	 /97
9/ 	 /B7
9/_/87
01 	 /97
Date/Time
ll'OO *•»
1-3Q-97
Date/Time
Date/Time
Date/Time
Composite
or Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
deceived by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method SI EPA Method 29
EPA Method 5/ EPA Method 29
EPA Method 29
Sampling Train
MMUs
MMUs
MMUs
MMUs
MMUs
ParHculate/MMHs
Reid Bank
Parttculate/MMUs
Reid Bank
MMUs
Reid Bank
Date/Time
Date/Time
ty/*jf)/&'7
S3S7
Date/Time
Date/Time
Sample Description
Front Hall Add Rinse
0.1N HNO3
6% HN03 / iqji H2O2
Implnger+Rlnse
Bank Imp. Add Rinse
0.1NHNO3
4%KMnO4/10*H2S
Implnger+Rlnse
8NHCI
3* Quartz Filter
Front Hall
Acetone Rinse
Front Hall Add Rinse
0.1NHNO3
Comments
Comments
Comments
Comments
Special Notes
M 29 Container «
M 29 Container #4
M 29 Container *6A
M 29 Container fSB
M 29 Container *5C
M 29 Container #1
M 29 Container *2
M 29 Container #3
1
Lab
TLI
TU
1
TU
1
TLI
TU
PES/TU
PES/TU
TU
-------
PES, Inc
4700 Duke Dr., Suite 150
Mason, OH 45040
1 513-398-2556
Plant Name: PES Plant Location: Saginaw, Ml
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
O-M29-8LK-H2O2
0-M29-BLK-BHAR
O.M29-BLK-KMnO4 '*
0-M29-BLK-HCL
'
'•
1

Date
9/__/97
9/_J97
9/ 	 107
9/__/97
1
1
'

Date/Time
\MOi~
Date/Time
Date/Time
Date/Time
Composite
or Grab-
C omp osl i9
Composite
Compoalte
Composite
'
'
*

Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 29
EPA Method 29
EPA Method 29
1
EPA Method 29
1
1
.
1
1
•
Sampling Train
MMtls
Field Blank
MMtls
Field Blank
MMtls
Field Blank
MMtls
Field Blank
1
1
*
•




Date/Time
*jj?7
Date/Time
Date/Time
Sample Description
5% HNO3 / 10% H2O2
Implnger+Rlnse
Blank Imp. Acl|( Rinse
0.1NHNO3
4X KMnCM/10% H23
lmplnger+ Rinse
8NHCI
*
1
1
t
Date:
Lab:
Train:
9/ 	 /97
TLI I
M29
Project Name: EPA Job No. 414.003
Comments
Comments
Comments
I
Comments
Special Notes
M 29 Container #4
1
M 29 Container *5A
M 29 Container *5B
M 29 Container *5C
1
*
,
•
Lab
TU
TU
TU
t
TLI
1
,
,
-------
                                         PES, Inc
J
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
i
Plant Name: PES Plant Location: Saginaw, Ml
Relinquished by: (Signature)
Relinquished by: (Signature)
I
Relinquished by: (Signature)
Relinquished by: (Signature)
4
Field Sample
No.
M28-Reagent Blank-4' Filter
M29-Reagent Blank-3' Filter
M29-Reagent Blank-Acetone '
M28-Reagent Blank-HNO3/H2O2
M28-Reagent Blank-0.1N HNO3
U28-Reagent Blank-KMnO4/H2SO4
M29-Reagenl Blank-6N HCL |, '
M29-Reagent Blank-DI H2O
Date
8/_^87
9/_J97
9/__/97
B/ 	 /97
9/_/97
8/ 	 /B7
8/_/97
9/__/97
Date/Time
\Mo*^
9-J0"97
Date/Time
Date/lime
Date/Time
Composite
or Orab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Received by: (Signature)
deceived by: (Signature)
deceived by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method 81 EPA Method 28
EPA Method 81 EPA Method 28
EPA Method SI EPA Method 28
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
Sampling Train
Partculate/MMtla
Ho&gent Blank
Partculate/MMtla
Reagent Blank
Partculate/MMtts
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank
MMTL
Reagent Blank


Date/Time
-------

PES, /nc
4700 Duke Dr., Suite 150
Mason, OH 45040
513-398-2556
Plant Name: PES Plant Location: Saginaw, Ml
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
I
Relinquished by: (Signature)
Field Sample
No.
l-M29-4-Filter
l-M29-4-FHAce
I-.M29-4-FHAR
I-M2S-4-H2O2 ^ O^F "2-
I-M29-4-BHAR
I
1-M29-4-KMN04
I-UM-I-IICL j|.
O-M29-4-Fllter
Date
01 	 107
9/_/97
9/__/97
9/__/B7
9/_/B7
8/_J87
^'— /"
9/ 	 107
Date/Time
//w «.
Dale/Time
Date/Time
*
Date/Time
Composite
or Orab
Composite
Composite
Composite
Composite
Composite
Composite
&i.l|n«ll.
Composite
Received by: (Signature)
Received by: (Signature)
-A/
t
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method S/ EPA Method 29
EPA Method S/ EPA Method 29
1
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
t
EPA Melhee1 CO -
EPA Method 5/ EPA Method 29
Sampling Train
Partlculate/MMUs
Partlculate/MMUs
1
MMUs
t
MMUs
MMUs
1
MMtts
1
MMUe
(
ParUculate/MMUs
*





Date/Time
Date/Time
Date/Time
Date/Time
Sample Description
4' Quartz Filter
Front Hall ^
Acetone Rinse
Front Half Add Rinse
0.1NHN03
5XHNO3/10KH2O2
Implnger+Rlnse
Blank Imp. Add Rinse
O.INHN03
4% KMnO4/10K H2S
Implnger+Rlnse
.
3* Quartz Filter
Date:
Lab:
Train: (
9/ 	 /97
TLI
M29
Project Name: EPA Job No. 414.003
Comments
Comments
Comments
Comments
Special Notes
M 29 Container #1
1
M 29 Container *2
M 29 Container #3
M 29 Container #4
M 29 Container *5A
M 29 Container #5B
M °° "-Trrtritntr ifl? .
M 29 Container *1
Lab
PES/TLI
1
PES/TU
TU
TU
TU
TU
TU
-------
     PES, Inc
4700 Duke Dr., Suite 150
   Mason, OH 45040
    513-398-2556
Date:
Lab:
Train:
9f 	 /97
TLI
M29
Plant Name: PES Plant Location: Saglnaw, Ml Project Name: EPA Job No. 414.003
Relinquished by: (Signature)
~7W*^/-*wJw,
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
Field Sample
No.
0-M29-4-FHAce '
O-M29-4-FHAR
•
0-.M29-4-H2O2
0-M29-4-BHAR
O-M29-4-KMNO4
ft MTO A HPL
3?M^-M~Hzjpz SL£>fA
^Mfl-Zr-HxOj.ZOrFz
Date
9/__/97
9/_J97
8/ 	 /97
9I_/B7
9/ 	 /97
St 	 W


Dale/Time
ll-'ff>^
I'JD'f?
Date/Time
Date/Time
•
Date/Time
I
Composite
or Grab •
Composite
Composite
Composite
Composite
Composite
ww 1 If/uail0


Received by: (Signature)
Received by: (Signature)
^^M^^
Received by: (Signature)
Received by: (Signature)
Analysis Required
EPA Method S/ EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29
EPA Method 29


rtrc^vvre : G>o
Sampling Train
Partlculate/MMtls
*
MMtis
MMDs
MMUs
MMHs
MM«9 	

AJof- ft
Date/Time
'/.' 'oti
1-30^*
Date/Time
tM97
t&7
Dale/Time
Date/Time
Sample Description
Front Half
Acetone Rlnaa
Front Half Acld^lnse
0.1NHNO3
5% HN03 / 10% H2O2
Implnger+RJnse
Blank Imp. Add Rinse
0.1NHNO3
4% KMnCM/10% H2S
Implnger+Rlnse
•W4-HCI 	

r^^l^S^.
Comments
Comments
Comments
Comments
I
Special Notes
M 29 Container #2
M 29 Container #3
M 29 Container #4
M 29 Container *5A
M 29 Container *5B |
>l oa r-~,t.i»-. f^p .


Lab
PESmJ
TLI
TLI
TLI
TU
TLI

-------
                                                                  iORATORIES, INC. -- LOG IN RECORD/CHAIN OP CUSTODY=
Jl Custody Seal : Absent Sample Seals: Absent
jj Chain of Custody : Present Container. . . : Intact
|| Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
jj SMO Forms : N/A
TLI Project Number 43452 • Book ||
Client: PSC01 - PES, Inc. jj
j. 185 jj
JF J *Lf} / II
Date Received j 09/30/97 j **%%& ' $?< $}tfttf^*'** \
II i • •( • »
|| Box NO COOLANT Temp 26.0 C Carrier and Number | TOM MCSONALD ' 26 ||
||TH Number 	 Client Sample ID 	 Matrix
||mR/H:CPM. 	 Client COC ID 	 * Location 	

-
||l85-26-lA I-M29-1-FILTER FILTER
I) I-M29-1-FILTER METALS LAB
||l85-26-lB I-M29-1-FHACE FH ACETONE RNS
|| I-M29-1-FHACE METALS LAB
||l8S-26-lC I-M29-1-FHAR FH .IN HNO3
I) I-M29-1-FHAR METALS LAB
|i
II
||l85-26-lD I-M29-1-H202 HN03/H202
|| I-M29-1-H202 METALS LAB
II
H185-26-1E I-M29-1-BHAR BH HN03
I) I-M29-1-BHAR METALS LAB
||lB5-26-lF I-M29-1-KMNO4 KMnO4
(I I-M29-1-KMN04 METALS LAB
||l85-26-lG I-M29-1-HCL HC1
|| I-M29-1-HCL METALS LAB
||l85-26-2A I -M29-2 -FILTER FILTER
|| I-M29-2-FILTER METALS LAB
||l85-26-2B I-M29-2-FHACE FH ACETONE RNS
jj I-M29-2-FHACE METALS LAB ,
||l85-26-2C I-M29-2-FHAR FH .IN HN03
IJ I-M29-2-FHAR METALS LAB
||
||lB5-26-2D I-M29-2-H202 1 OF 2 HN03/H202
I) I-M29-2-H202 1 OF 2 METALS LAB
||lB5-26-3A I-M29-3-FILTER FILTER
Jl I-M29-3-FILTER METALS LAB
To LAB
Date/Init



V







To STORAGE
Date/Init

To LAB
Date/Init












||185-2S-3B I-M29-3-FHACE FH ACETONE RNS|
jj I-M29-3-FHACE METALS LAB
]|l85-26-3C I-M29-3-FHAR FH .IN HN03 1
jj I-M29-3-FHAR METALS LAB









To STORAGE |
Date/Init














To LAB
Date/Init


'











To STORAGE
Date/Init







-






To LAB
Date/Init













i
To STORAGE
Date/Init









;
. ..._
	
i


DISPOSED ||
Date/Init jj
II
II
II
II
II
II
II
II
II
1 "
' II
II
II

II
II


II
II
II
II
                                                                                                                                                                         II  -tf
,||   Receiving Remarks:   NO COOLANT WITH SAMPLES, THUS  THE  HIGH TEMPERATURE.   FIRST PAGE OF COC WAS  FAXED  FROM DEECO.  THE
    •                    REST OF COC WAS RECEIVED WITH  SAMPLES. SAMPLE  I-M29-2-H202 2,  ARCHIVE:  DO NOT ANALYZE.
   Archive  Remarks:
-------
Custody Seal : Absent
Chain of Custody t Present
Sample Tags : Absent
SMO Forms : N/A
II 	
	 — 	 — 	 .*.iv.i.«-u.iuuu Jjruiwcwi* wnj.E>0 t AHV. • 	 AASU 4.11 nD\.VSItU/ l-flAXr
Sample Seals: Absent
Container. . . : Intact
	
TLI Project Number
Client! PSC01 - PES,
Date Received |
1 	 L
43452 •
Inc. i
f *
09/30/97 j ^^ta^^Sl^t,
Book ||
II
IBS ||
S II
kPage^H
II   Box
NO COOLANT
                Temp  26.0 C
|  Carrier and Number |  TOM MCSONALD
I   26  II
                                                                                                                                                                            CO

||TIiI Number Client Sample ID 	 Matrix]
||mR/H-CPH Client COC ID 	 * Location 	 |
»i
	 — • " 1
||l8S-26-3D I-M29-3-H202 HNO3/H2O2
I) I-M29-3-H202 METALS LAB
	
||l85-26-3E I-M29-3-BHAR BH HN03
I) I-M29-3-BHAR METALS LAB
||lB5-26-3F i I-M29-3-KMNO4 KMnO4
|| I-M29-3-KMN04 METALS LAB
||lBS-26-4A O-M29-1-FILTER FILTER
|| 0-M29-1-FILTER METALS LAB
||!85-26-4B 0-M29-1-FHACE FH ACETONE RNS
jl 0-M29-1-FHACE METALS LAB
II
IJ18S-26-4C 0-M29-1-FHAR FH .IN HNO3
jj O-M29-1-FHAR METALS LAB
||l85-26-4D O-M29-1-H2O2 HN03/H2O2
jj 0-M29-1-H202 METALS LAB
||!85-26-4E 0-M29-1-BHAR BH HN03
jj O-M29-1-BHAR METALS LAB
II
||l85-26-4F O-M29-1-KMN04 KMn04
j| 0-M29-1-KMN04 METALS LAB
||
||l85-26-SA 0-M29-2-FILTER FILTER
II • 0-M29 -2 -FILTER METALS LAB
||l85-26-5B 0-M29-2-FHACE FH ACETONE RNS
I) 0-M29-2-FHACE METALS LAB
II
||l85-26-5C 0-M29-2-FHAR FH .IN HN03
|| 0-M29-2-FHAR METALS LAB
||
||!8S-26-SD O-M29-2-H2O2 HNO3/H2O2
|| 0-M29-2-H202 METALS LAB
_jj 	 	
||l85-26-5E 0-M29-2-BHAR BH HN03
|| O-M29-2-BHAR METALS LAB

To LAB
Date/Init




>





j
1
I
1
|.. . 	
1
1
-,
1

TO STORAGBJ
Date/Init
















To LAB
Date/Init









-

u



1
To STORAGE
Date/Init
















To LAB
Date/Init





.









i
To STORAGE
Date/Init







.
V







To LAB
Date/Init

i









-~




To STORAGE
Date/Init

.








•'


ji


DISPOSED
Date/Init


1


1
1
1
1
1
1
i
1
1
1


'
	 	 1

    Receiving Remarks:  NO COOLANT WITH SAMPLES,  THUS THE HIGH TEMPERATURE.   FIRST  PAGE OF COC WAS FAXED FROM DEECO.  THE
                        REST OF COC WAS RECEIVED WITH SAMPLES.  SAMPLE I-M29-2-H202  2, ARCHIVE: DO NOT ANALYZE.
    Archive Remarks:
-------
                                                  ^TRIANGLE LABORATORIES,  INC.  --  LOO  IN RECORD/CHAIN OF CUSTODY=
Custody Seal      :  Absent
Chain of Custody  :  Present
Sample Tags       :  Absent
Sample Tag Numbers:  Not Listed on Chain of Custody
SMO Forms         :  N/A
                                         Sample  Seals:  Absent
                                         Container. , . i  Intact
TLI Project Number   43452
Client: PSC01 - PES, Inc.
                                                                                                                                                                Book ||
                                                                                                     Date  Received
                   j 09/30/97   j By
                   +
 Box
                                  NO COOLANT
                                                  Temp  26.0  C
                                                                                                     Carrier and  Number 1  TOM MCSONALD
                                                         |   26  ||
||TLI Number 	 Client Sample ID 	 Matrix)
||mR/H:CPM. 	 Client COC ID 	 * Location 	

	
||l85-26-5F O-M29-2-XMHO4 KMn04
|| i 0-M29-2-KMH04 METALS LAB
n '
II
||l85-26-5G O-M29-2-HCL 8N HC1
jj 0-M29-2-HCL METALS LAB
||l85-26-6A 0-M29-3-FILTER FILTER
jl O-M29-3-FILTER METALS LAB
11
||l85-2ff-6B 0-M29-3-FHACE FH ACETONE RNS
Jl 0-M29-3-FHACE METALS LAB
j!
II
||!85-26-6C 0-M29-3-FHAR FH .IN HNO3
|| O-M29-3-FHAR METALS LAB
||
II
||l85-26-6D 0-M29-3-H202 HNO3/H2O2
|j 0-M29-3-H202 METALS LAB
||l85-26-6E 0-M29-3-BHAR BH HNO3
j| O-M29-3-BHAR METALS LAB
II
||!85-26-6F O-M29-3-KMN04 KMnO4
|| 0-M29-3-KMHO4 METALS LAB
11
||l8S-26-6G O-M29-3-HCL 8N HC1
|| 0-M29-3-HCL METALS LAB
I
II
||l85-26-7A 0-M29-BLK-FILTER FILTER
|| 0-M2 9 -BLK- FILTER METALS LAB
II
||!85-26-7B 0-M29-BLK-FHACE FH ACETONE RNS
Jl O-M29-BLK-FHACE METALS LAB
||
||lB5-26-7C 0-M29-BLK-FHAR FH .IN HN03
jj 0-M29-BLK-FHAR METALS LAB
||l85-26-7D O-M29-BLK-H202 HN03/H202
II 0-M29-BLK-H2O2 METALS LAB
||l85-26-7E O-M29-BLK-BHAR BH HN03
II 0-M29-BLK-BHAR METALS LAB
To LAB
Date/Init




V









1
TO STORAGE)
Date/Init















To LAB
Date/Init















TO STORAGE)
Date/Init















To LAB
Date/Init















To STORAGE)
Date/Init

i













To LAB
Date/Init





.









To STORAGE
Date/Init

.

'










1
DISPOSED 1)
Date/Init ||
M
II
II
n
II
II
II
II
II
n
n
n
0
n
n
n

i
ii
ii
n
n
n
>n
ii
Receiving Remarks:  NO COOLANT WITH SAMPLES, THUS THE HIGH TEMPERATURE.  FIRST PAGE OF COC WAS FAXED FROM DEECO.  THE
                    REST OF COC WAS RECEIVED WITH SAMPLES. SAMPLE I-M29-2-H202 2, ARCHIVE: DO NOT ANALYZE.
Archive Remarks:
-------
|| Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container...! Intact
j| Sample Tags i Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
-
U Box NO COOLANT Temp 26.0 C
HTLI Number 	 Client Sample ID 	 Matrix)
IJmR/H-CPM Client COC ID . * Location 	 j
»i
1 — ... |
||lB5-26-7F O-M29-BLK-KMN04 KMn04 1
|| 0-M29-BLK-KMN04 METALS LAB
||lB5-26-7G 0-M29-BLK-HCL BN HC1
|| O-M29-BLK-HCL METALS LAB
||!85-26-8A M29-RB-4"FILTER 4" FILTER
jj M29-RB-4 "FILTER METALS LAB
1
||l85-26-8B M29-RB-3"FILTER 3" FILTER
jj M29-RB-3»FILTER METALS LAB
||!85-26-8C M29-RB-ACETONE Acetone
|| M29-RB-ACETONE METALS LAB
||l85-26-8D M29-RB-HNO3/H2O2 5%HNO/10%H2O2
|| M29-RB-HN03/H202 METALS LAB
n
II
||!8S-26-8E M29-RB-0.1N HN03 0.1N HNO3
jj M29-RB-0.1N HN03 METALS LAB
||l85-26-8F M29-RB-KMN04/H2SO4 4VKMNO4/10VH2SO4
jj M29-RB-KMN04/H2S04 METALS LAB
||!85-26-8G M29-RB-8N HCL BN HCL
I) M29-RB-BN HCL METALS LAB
||!85-26-8H . M29-RB-DI H20 DI WATER
jj M29-RB-DI H20 METALS LAB
||lBS-26-9A I-M29-4-FILTER FILTER
jj I-M29-4-FILTER METALS LAB
||
||l85-26-9B I-M29-4-FHACE FH ACETONE RNS
jj I-M29-4-FHACE METALS LAB
||185-2S-9C I-M29-4-FHAR FH .IN HNO3
jj I-M29-4-FHAR METALS LAB
To LAB
Date/Init



>









II
||l85-26-9D I-M29-4-H202 1 OF 2 HN03/H2O2)
jj I-M29-4-H202 1 OF 2 METALS LAB j
To STORAGE) To LAB
Date/Init Date/Init


























TLI Project Number 43452 < Book ||
Client: PSC01 - PES, Inc. jj
/ y* i
Date Received | 09/30/97 | ^V/pftfjwl W^ jblWrb** II
Carrier and Number | TOM MCSONALD •• 26 jj
To STORAGE
Date/Init










TO LAB TO STORAGE) TO LAB
Date/Init Date/Init Date/Init




t















-




'




1


To STORAGE
Date/Init
I

"•








.


DISPOSED 1)
Date/Init |)
' II
II
H
n
n
n
H
n
n
n
«"
u
it
u
ii
n
n
n
n
ii
i
n
n
n
n
ii
n
n
   Receiving Remarks:  NO COOLANT WITH SAMPLES, THUS THE HIGH TEMPERATURE.  FIRST PAGE OF COC WAS FAXED FROM DEECO.  THE
                       REST OF COC WAS RECEIVED WITH SAMPLES. SAMPLE I-M29-2-H202 2, ARCHIVE: DO NOT ANALYZE.
||  Archive Remarks:
-------
(I Custody Seal : Absent Sample Seals: Absent
|j Chain of Custody : Present Container...: Intact
I Sample Tags : Absent
jj Sample Tag Numbers: Not Listed on Chain of Custody
I) SMO Forms : N/A
TLI Project Number 43452 . Book ||
Client: PSC01 - PES, Inc. II
185
If- s /' / \a/ II
Date Received j 09/30/97 j By^^^'^^^^^bge jj
	 	 	 	 	 - 	 — i • •( ' «
|| Box NO COOLANT Temp 26.0 C Carrier and Number | TOM MCSONALD • 26 ||
||TLI Number 	 Client Sample ID 	 Matrix
||mR/H:CPM 	 Client COC ID 	 * Location 	
||
II
||!85-26-9E I-M29-4-BHAR BH HN03
II I-M29-4-BHAR METALS LAB
|
II
||l85-26-9F I-M29-4-KMN04 KMNO4
I I-M29-4-KMN04 METALS LAB
|
II
||l85-26-10A O-M29-4 -FILTER FILTER
|| 0-M29-4-FILTER METALS LAB
||!85-26-10B 0-M29-4-FHACE FH ACETONE RNS
|| 0-M29-4-FHACE METALS LAB
|
II
||l85-26-10C 0-M29-4-FHAR FH .IN HN03
(I 0-M29-4-FHAR METALS LAB
||lS5-26-10D 0-M29-4-H202 HH03/H2O2
|| 0-M29-4-H202 METALS LAB
,
||l85-26-10B 0-M29-4-BHAR BH HNO3
jj O-M29-4-BHAR METALS LAB
IJ185-26-10F O-M29-4-KMNO4 KMNO4
|| O-M29-4-KMNO4 METALS LAB
1)165-26-11 I-M29-4-H2O2 2 OF 2 IMPINOBR
|| I-M29-4-H2O2 2 OF 2 METALS LAB
1)185-26-12 I-M29-2-H2O2 2 OF 2 IMPINGER
jl I-M29-2-H202 2 OF 2 METALS LAB
II
II
To LAB
Date/Init



V







To STORAGE
Date/Init











To LAB
Date/Init










TO STORAGE|
Date/Init











II
n
ii '
n
To LAB
Date/Init




'









TO STORAGE
Date/Init














To LAB
Date/Init







1






To STORAGE
Date/Init


...











DISPOSED ||
Date/Init ||
II
II
||
II
II
II
II
II
II
II
II
II
II
II
|
'

1 	 1
II
II
II
II
	 11
II
                                                                                                                                                                           CD
. ||  Receiving Remarks:   NO COOLANT WITH SAMPLES,  THUS THE HIGH TEMPERATURE.  FIRST PAGE OF COC WAS FAXED FROM DEECO.  THE
 Jl                      REST OF COC HAS RECEIVED WITH SAMPLES. SAMPLE I-M29-2-H202 2,  ARCHIVE: DO NOT ANALYZE.

 If
 ||  Archive Remarks:
-------
   Custody Seal       :  Absent
   Chain of Custody  i  Present
                                                    TRIANGLE LABORATORIES, INC.  -- LOO IN RECORD/CHAIN OF CUSTODY^
Sample Seals: Absent
Container...! Intact
|  TLI  Project Number   43775
  Client:  PES03  -  Pacific Environmental Services
|  Book (I
I
Sample Tags :
Sample Tag Numbers:
SMO Forms :
Absent
Not Listed on Chain of Custody
N/A
NO COOLANT

Date Received
Carrier and Number

| 10/28/97
1
| WRIGHT
1
j j
i By//?W-i>r~~j
t - 1
188 ||
II
II
Page |)
II
52 ||
                                                                                                                                                                         CD

mR/H-CPH 	 Client COC ID 	 * Location 	

-
188-52-1 Beaker No.M25 FILTER
Beaker NO.M25 METALS LAB
|188-52-2 Beaker NO.M26 . F/H RINSE
j Beaker No.M26 METALS LAB
i
1
|!88-S2-3 Beaker NO.M27 FILTER
I Beaker NO.M27 METALS LAB
|l8B-52-4 Beaker No.M28 F/H RINSE
| Beaker NO.M28 METALS LAB
1
|l8B-52-S Beaker NO.M29 FILTER
j Beaker NO.M29 METALS LAB
(188-52-6 Beaker No.M30 F/H RINSE
j Beaker No.M30 METALS LAB
i
1
(188-52-7 Beaker No.M31 FILTER
I Beaker No.M31l METALS LAB
(188-52-8 Beaker NO.M32 F/H RINSE
j Beaker No.M32 METALS LAB
(188-52-9 Beaker No.M33 FILTER
I Beaker NO.M33 METALS LAB
188-52-10 Beaker No.M34 F/H RINSE
Beaker NO.M34 METALS LAB
188-52-11 Beaker No.M35 ' FILTER
Beaker NO.M35 METALS LAB
«- -
(188-52-12 Beaker No.M36 F/H RINSE
|| Beaker NO.M36 METALS LAB
	
1(188-52-13 Beaker NO.M37 FILTER
j Beaker No.M37 METALS LAB
	
II- I
1(1198-52-14 Beaker No.M38 F/H RINSE
|| Beaker NO.M38 METALS LAB

To LAB
Date/Init










1
1
1
1
1
1
1
1
1

To STORAGE
Date/Init











. .
_._ .
1 	 1


To LAB
Date/Init












... 	 .



To STORAGE
Date/Init
















To LAB
Date/Init
















To STORAGE
Date/Init













,


To LAB
Date/Init










1





To STORAGE
Date/Init

\










	
•-


| DISPOSED ||
Date/Init j|
||
II
II
n
ii
i n
ii
n
n
n
n
n
n
ii
n
n
ii
n
«
n
n
II
n
n
n
n
n
n
n
ii
u
ii
u
u

||-  Receiving Remarks:
r-
||  Archive Remarks:
-------
Custody Seal t Absent
Chain of Custody : Present
Sample Tags : Absent
Sample Tag Numbers: Not Listed
SMO Forms 1 N/A
Sample Seals: Absent
Container...: Intact
on Chain of Custody
•
j NO COOLANT
TLI Project Number 43775
Client: PES03 - Pacific Environmental Services
.* /I
Date Received j 10/28/97 j By /ft t'jfl SlS\/^ /fl
j i y/ ffl/l' v l/ll
Carrier and Number | WRIGHT
1
Book 1)
II
188 1)
	 	 II
Page ||^
-^
||TLI Number 	 Client Sample ID. . . . '. 	 Matrix
jjmR/H-CPM ... Client COC ID * Location 	

JJ188-52-1S Beaker NO.M39 FILTER
II Beaker NO.M39 METALS LAB
||18B-S2-16 Beaker NO.M40 F/H RINSE
II Beaker No.M40 METALS LAB
1)188-52-17 Beaker NO.M41 FILTER
I) Beaker No.M41 METALS LAB
||lB8-52-18 Beaker NO.M42 F/H RINSE
II Beaker No.M42 METALS LAB
1)188-52-19 Beaker NO.M43 FILTER
1) Beaker NO.M43 METALS LAB
It
1)186-52-20 Beaker No.M44 FILTER
(I Beaker NO.M4VI METALS LAB
I
1)188-52-21 Beaker NO.M4S ACETONE
IJ Beaker NO.M45 METALS LAB
||
II
II
II
II
II
II
II
II
||
II
II
r
ii
To LAB
Date/Init

'
1




1 	







To STORAGE
Date/Init















To LAB
Date/Init















To STORAGE
Date/Init







--







To LAB
Date/Init










.




To STORAGE
Date/Init















To LAB
Date/Init










1




To STORAGE
Date/Init















| DISPOSED 1)
Date/Init ||
||
II
II
1 II
II
II
II
1
II
II
II
II
II
II
II




II
II
II
II
II
II
n
n
|l  Receiving Remarks:
II
||  Archive Remarks:
-------
  led I
43
                                                                            Anrjlyles

                                                                tCI1  • QFAA   FI.AA  CVAA
9nf: PtfS.lh&.fPSCUU
te/lnh: A>^/T>  Volume\0^>  \ Da|e ^

                                                                                 t
                                                                      I label
                                                                      j Volume
                                                                                            ! Allquol A_
                                                                                                                  ml
i Allquol B  ^
                                                                      ilnl
                                          Reduce Volume Int.
                                            lo 20 ml. on
                                             Holplale
          iFronl l-loir Dlgeslale
                     Holplale dig
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                      and H202
 Dilute.to
 100 mis    Dale
                                                                               Aliquot A:

                                                                               Aliquot D:
                 Volume
            ml
i Aliquot D.
i  Inl
                                                                                                            i
                                                                                                              Date
                                                                                                          (Duplicate Analysis of Each
                                                                        Spike
                                                                  (1 DllllgSpIko raqulred)
                                                                                                labe
                                                                                                                      |n|
                                                                          Allquol A:  5

                                                                          Aliquot D:  6
                                                                                                       ; sok  5 ml
                                                                                                       i of >PP ppb
                                                                                                                   me
                                                                                                       itlnal spk cone.   Dale/7,'
                                                                                                       I added  S   ppb      ~+~
post cJIgesI spike on FH lor GFAA))
 & BI-J Post dig. spk.
      ppb (Instrument spiked)
                    Allduol A: _5	ml
                   .(No spike lequlred)

                   Aliquot 0:  £  ml
                                                       (One posl digestion spk on 011 for GFAA)
                                                                      FH & 13H Seilal dllullon performed

                                                                          . ml lo	ml FV +	uL Sc

-------
Tojecf II,

:ilenr:
                                                                                                       \
                                                                                                 Anrjlylos '
                                                                                            GI:AA   PIAA  CVAA.
)ate/lnr.:
                                      Triangle  Laboratories of RTP
                                                   (919)544-5729
:ilent Run//
                                              I l-lg Implnger's |

                                    CONTH.        CONT II
                                                                                                              CONT «
                                             coyn;
                                             .©
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                                                                                      IINO3          KMNO-I        MCI
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                                                           Volume
                                         label

                                         Volume
                                                          ForMelals    or l-l
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                              wllh'conc. HF
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                                                                                        (I Dl 11 Ig Spike mqulfed)
         • |''Fronl Half Dlgeslale
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                                                                       AllquorA:   £

                                                                       Allquol B:
                                                                                                 Allquol A:

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                    sp
                          Alld.uol A:  £  mi

                          .(Mo spike requlied) •

                               .I
                                                     Volume  1 OT) Dale
                                                  (One post digestion spk on DM (ot GFAA)
                                              FH & OH Serial dllullon petfotmed

-------
                                                                                                     Anolyles  '
                                                                                          id'  • Gi:AA   RAA  CVAA
 enf:
 ite/lnh:_
                           Triangle Laboratories of RTP
                                        (919)544-5729
                                                                                                                        CO
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                                                          CONTI/.        CQNTH


                                                           ©

                                                           IINO3           KMNO4
                                label

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                                                                   I' Aliquot,
                                                                                j  Inl
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                                                                                   label
                                I Volume.


                                I Allquo'j A $

                                \ Allquol 0 £
                                jlnl
                                                                   iDale M
          [Fronl Half Dlgeslale
                                                   _t
                                                                                                   (Dupllcale Analysis of Eac^
                                                               Int.
post digest spike on FU lor
                                                   lo 20 ml. on
                       3 20 ml. on       t^hthf
                       Holplale    Du\Qj&l
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                                  Daleil
                                                                          Sample
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                                                                        Inl
                                                                      j label.
                                                                                                 Inl
                                                            iVblume_/00. ogle "ffi/7  I iVolume	Dale
                                                                 r^r
                                                                           llquot A:	£

                                                                          Allquol D:,
Dilute lo
100 mis
Inl. i5£ff
Dale llb)^
                                                                                                 spk.
                                                                                                •of
                                                                                      Allquol A:.

                                                                                      Aliquot 0:.

                                                                                      	mf""
                                                                                          ppb
                                                                                                                Inl
I & DH Post dig. spk.
      .ppb (Inslrumenf spiked)
                                                                                                i Hnal spk cone.
                                                                                                i added	ppb
                         Volums
                                                 TO
                                                                 Dale
                               spike lequlr'ed) •
                                      (One post cllgesllon spk on DM for GFAA)
Allquol D:
                            ml
                                FH & OH Serial dllullon performed

                                  •  ml lo	ml FV n	uL Sc

-------
^rojecf //.

Client:
                                                                                           ICP
                                                                                                       Anrjlyles  '    '
                                                                                                  QPAA    PI.AA  CVAA
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              0 -fl\JR lobeljKi
                                                                                 1 Volume.

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                                                                                             _ml   i Volume.
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                                             j Allqudj A 6

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                                                             ! Date J
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                                                    lo 20 ml. on
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              ^=^
           Dllule lo  lnl
           100 mis   Dale
              l-lolplalo dig
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               and 1-1202
            DalellJ
                                                                            Sample
                                                              Spike
                                                         (1 DM llg Splka inquired)
                                                                                        Int
             label|^f^
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                                                   GOO
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—Aliquot A:   £_

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 i A Melol
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 & BH Post dig. spk.
                   lit sr.
                              For Mg

                             Allduol A:
                            .(Nosplke ieqv.il«j
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100 mis
                                                                Inl.
                                                               Date,
                                                                                                    j Volume
                                                                                                    ; ........... _._
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                                                                                                  \ sok 5" ml
                                                                                                  of /t>o ppb
                                                                                                                 Dale
                                                                              inr
                                                                                                  I llnal spk cpnc.
                                                                                                  j added £  ppb
                                                                              DalelV
                                           ml
                                                       Volume 10D Dale
                                                    (One posl dlgesllon spk on OH loi GFAA)
                                                             FH & UH Serial dilution performed

                                                             _ .». ..ml lo	ml FV +	uLSc
-------
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ICI1 • GFAA FI.AA CVAA
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(919)544-5729 ', '! ' ^
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                                                               i
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                                 Allquol D:
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                                                              FH & DH Serial dilution performed
                                                              -  •   ml lo	ml FV +	uL Sc
-------
rojecf //.

:ilenh
                                                                        ICP
'afe/lnt.:
                      Triangle  Laboratories of  RTF
                                    (919)544-5729
llenr Run//'    0~M#> 3
                                                                                  Anolyles  '
                                                                             QIV\/V    R.AA  CVAA
                                                                                       •Si
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                                                                                 \ Volume U^j ml
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-------
rojecl //.

  ant:
                                                                                  ICP
                                                                                                      AnrjIyleS
                                                                                                 Qi'AA   H.AA CVAA
                                        Triangle Laboratories of  RTP
                                                      (919)544-5729
 ant
  ;QNT
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                                                                     I l-lg Implngefs I
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                                                                                                                            SU
                                                                                                        KMNC"1
                                                                                                                    CONT «
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                                                                                                 FH & 13H Seilal dlluUon performed

                                                                                                  .. < _. ml lo	ml FV +	uL Sc

-------
3ro|ect //.

3llenf:
                                                                                            ICP
                                                                                                        Anrjlylos  '
                                                                                                  QFAA   F1.AA  CVAA
Dote/lnt.:.
                                         Triangle Laboratories of  RTP
                                                       (919)544-5729
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                                                                                                  .. •   ml lo	ml FV 4-	uL Sc

-------
Project II.

 Dent:
             3
                                                                                                -  Anolyles  '
                                                                                             GFAA   IM.AA  CVAA
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                                                                                               •  i ml lo	ml FV +	ul Sc
-------
                                                                                                              Anrjlyles
Cllenr:
Date/lnt.:
Client Run// vifl. -/H&3 - V

Triangle Laboratories of RTP
(919)544-5729



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                                                                                              ,  •   ml lo	ml FV +	uL Sc

-------
Project II _

  llenl:
                                                                                                    Ancjlyles  '
                                                                                         ICP  • GFAA   FI.AA  CVAA
  ate/lnt.:
  (lent Runtf
                                       Triangle Laboratories of RTP
                                                    (919)544-5729
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                                                                        I Volume ^°   Dale

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                                        ml lo	ml FV •»•	uL Sc

                                   Initials:	
                                                               Dale  lj °fl \
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       ppb (Instrument spiked)
-------
                                               PAGE
                  INORGANICS SPIKE LOG
DATE
/'Wjfl




•
r
















PROJECT *
SAMPLE IDs
fe>-L.C5





•
















ANALYTE
-*
V


» '


















ORIGINAL
STANDARD
#
3-0J3-4
<3-/5D-^






.»













_
ORIGINAL
STANDARD
CONC.
(PPM)
4f
JCOO





















SPIKE
SAMPLE
(nU
RNAL
VOLUME
(mL)
•"JU
loo/
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SPIKE
SAMPLE
(PP8)
4






















INITIALS
OiF
|





















WITNESS
^
i'
V

















*


                                                         82
-------
         * SEE SPIKE LOG
EXP date

 2/1/98
 9/1/98
 2/1/98
 9/1/98
 2/1/98
 2/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 2/1/98
 9/1/98
 9/1/98
 8/1/98
 9/1/98
 9/1/98
 2/1/98
 8/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
8/1/98
Spiking Standard Preparation
3ement Standard Orig. Std. Spike(uL) cone
10 (ppm)
^
\S
U
M
I
ia
ie
:a
!a
:d
:o
^
:u
a
:e
{
;
«g
Mg
An
via
ta
>ta
-------
                                                                 PAGE 1  OF 3
                        TRIANGLE LABORATORIES,  INC.
                       Transfer Chain-of-Custody Form
                               Project 43452
                    Transfer  From: IR

                           Initials..

             Released by:
     To:  IA I

Date	    Time,
Accej

MILES . ID
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
43452-
3 ted by:


-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
-012
-013
-014
-015
-016
-017
-018
-019
-020
-021
-022
-023
-024
-025
-026
-027
-028
-029
f)i6v

TLI No 	
TLI Blank
185-26-1C
185-26-1D
185-26-1E
185-26-1F
185-26-1G
188-52-1
188-52-2
185-26-2C
185-26-2D
185-26-12
188-52-3
188-52-4
185-26-3C
185-26-3D
185-26-3E
185-26-3F
188-52-5
188-52-6
185-26-4C
185-26-4D
185-26-4E
185-26-4F
188-52-9
188-52-10
185-26-5C
185-26-5D
185-26-5E
185-26-5F
185-26-5G
	 	 	 — _ — , — ,

Gust . Id 	
TLI Method Blank
I-M29-1-FHAR
I-M29-1-H2O2
I-M29-1-BHAR
I-M29-1-KMN04
I-M29-1-HCL
Beaker No.M25
Beaker No.M26
I-M29-2-FHAR
I-M29-2-H2O2 1 OF 2
I-M29-2-H202 2 OF 2
Beaker No.M27
Beaker No.M28
I-M29-3-FHAR
I-M29-3-H2O2
I-M29-3-BHAR
I-M29-3-KMNO4
Beaker No.M29
Beaker No.M30
0-M29-1-FHAR
0-M29-1-H2O2
O-M29-1-BHAR
0-M29-1-KMN04
Beaker No.M33
Beaker No.M34
O-M29-2-FHAR
0-M29-2-H202
0-M29-2-BHAR
0-M29-2-KMNO4
0-M29-2-HCL
Additional comments or instructions:
-------
                                                                PAGE 2 OF 3
TRIANGLE LABORATORIES, INC.
Transfer Chain- of -Custody Form
•
Project
Transfer From: IR

Released by:
Accepted by:

MILES ID
43452- -030
43452- -031
43452- -032
43452- -033
43452- -034
43452- -035
43452- -036
43452- -037
43452- -038
43452- -039
43452- -040
43452- -041
43452- -042
43452- -043
43452- -044
43452- -045
43452- -047
43452- -048
43452- -049
43452- -050
43452- -051
43452- -052
43452- -053
43452- -054
43452- -055
43452- -056
43452- -057
43452- -058
43452- -059
43452- -060
Initials . .
,^&
vA

TLI No 	
188-52-11
188-52-12
185-26-6C
185-26-6D
185-26-6E
185-26-6F
185-26-6G
188-52-13
188-52-14
185-26-7C
185-26-7D
185-26-7E
185-26-7F
185-26-7G
188-52-17
188-52-18
185-26-8D
185-26-8E
185-26-8F
185-26-8G
185-26-8H
188-52-19
188-52-20
188-52-21
185-26-9C
185-26-9D
185-26-9E
185-26-9F
185-26-11
188-52-7
43452
To: IA I
Date 	 Time . . .
II/5/J12 S:4lpM
|\ /C, A1 I : 2$~

Gust .Id 	
Beaker NO.M35
Beaker No.M36
0-M29-3-FHAR
0-M29-3-H202
0-M29-3-BHAR
0-M29-3-KMNO4
0-M29-3-HCL
Beaker No.M37
Beaker No.M38
O-M29-BLK-FHAR
0-M29-BLK-H202
0-M29-BLK-BHAR
0-M29-BLK-KMN04
0-M29-BLK-HCL
Beaker No.M41
Beaker No.M42
M29-RB-HN03/H2O2
M29-RB-0.1N HN03
M2 9 - RB - KMN04 /H2 SO4
M29-RB-8N HCL
M29-RB-DI H20
Beaker No.M43
Beaker No.M44
Beaker No.M45
I-M29-4-FHAR
I-M29-4-H202 1 OF 2
I-M29-4-BHAR
I-M29-4-KMN04
I-M29-4-H202 2 OF 2
Beaker No.M31
	 Y-F-K-pnr1 f-D^ir -\-\fnt/oA\ 	 u
Additional comments  or instructions:
-------
                                                                PAGE 3  OF 3
                       TRIANGLE LABORATORIES,  INC.
                      Transfer Chain-of-Custody Form
                              Project 43452
                   Transfer  From: IR

                          Initials..

            Released by:  _

            Accepted by:  _
                           To:  IA  I
                      Date,
                             Time,
                      JLyJL/JiJ
                       U  /<£ /
        MILES.ID.

        43452-
        43452-
        43452-
        43452-
        43452-
        43452-
        43452-
        43452-
-061
-062
-063
-064
-065
-066
-067
-068
         TLI No	   Gust. Id.
188-52-8
185-26-10C
185-26-10D
185-26-10E
185-26-10F
188-52-15
188-52-16
LCS
Beaker No.M32
0-M29-4-FHAR
0-M29-4-H202
0-M29-4-BHAR
O-M29-4-KMNO4
Beaker No.M39
Beaker No.M40
Lab Control Spike
dditional comments or instructions:
                                                    -XfrCOC (Rev 11/01/94)---*-
-------
        * SEE SPIKE LOG
EXPdata

 2/1/98
 9/1/98
 2/1/98
 9/1/98
 2/1/98
 2/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 2/1/98
 9/1/98
 9/1/98
 8/1/98
 9/1/98
 9/1/98
 2/1/98
 8/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 9/1/98
 8/1/98
Spiking Standard' Preparation
Dement Standard Orig. Std. Spike(uL)
ID (ppm)
tg
w
u
u
9
3a
to
!a
!a
:d
:o
>
:u
•e
!e
C
C
»g
»9
An
Ulo
ta
la
ili
'b
ib
la
n
n
t
'n
'n
2-115-4
3-010-10
2-115-4
3-010-7
2-115-4
2-115-4
3010-10
3-010-10
3-012-7
3010-10
3010-10
3010-10
3O10-10
3O10-10
30T2-8
2-115-4
3O12-S
3O10-10
3O1O-8
3010-10
3010-10
2-115-4
3O10-9
3O10-10
3O10-10
3010-10
3O10-10
3O10-10
3O10-10
3010-10
3-010-10
3-010-6
100
100
100
10000
100
100
100
100
10000
100
100
100
100
100
10000
1000
10000
100
10000
100
100
100
10000
100
100
100
100
100
100
100
100
1000
Fvol(IOOmU)
5000
5000
5000
950
5000
5000
5000
5000
950
5000
5000
5000
5000
5000
950
5000
1500
5000
950
5000
5000
5000
1950
5000
5000
5000
5000
5000
5000
5000
5000
1500
cone
(ppm)
5
5
5
95
5
5
5
5
95
5
5
5
5
5
95
50
150
5
95
5
5
5
195
5
5
5
5
5
5
5
5
15
SPIKING
'ram Spiking Standard
5pike(uL) .-fcong
=Vol(10bml)
1000
1000
• 1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
(PPb)
50
50
50
950
50
50
50
so
950
50
50
50
50
50
950
500
1500
50
950
50
50
50
1950
50
50
50
50
50
SO
50
50
150
combined
total
1000


1000
-
1000
2000-
1000

2000

200
"Spike separately
Sement Orig Std Spike(uL) cone
(ppm) Fvot(100m (ppb)
Au
Ce
u -
P
Pd
Pt
S
SI
Sn
Sr
1000
1000
1000
1000
1000
1000
1000
10000
1000
1000
140
30
70
100
160
300
350
350
20
5
1400
300
700
1000
1600
3000
3500
35000
200
50
        1000UL of the Spiking Standard gives the listed cone, of the above elements.
        Spiking Standard 3-025-3
        EXP: 1/31/98

        Spiked by:
        Predigestion-
        Postdigsstoon-
M
-------
       Rccort
                Tim  11-06-97  11:24:10  ?M     case  1
I  Sample Name
File     Method    Date      Time  Op!D Type Mode
1
2
3
4
5
, 6
•V- 7
/
8
9
10
11
-Y» *ft / «*
> J —«* ^Tft
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
^2.44
45
46
,. "•)
ICB/CCB
STD1-BLANK
STD3
STD3
CHECK LO
ICV/CCV

ICB/CCB
ICSAB
43452 MB
43452 LCS
•185-26-1C
185-26-1C PDS
185-26-1C L
185-26-2C
185-26-2C DA
185-26-3C
185-26-4C
185-26-5C
ICV/CCV
ICB/CCB
185-26-6C
185-26-7C
185-26-8E
185-26-8H
185-26-9C
185-26-10C
185-26-1D
185-26-1D PDS
185-26-1D L
ICV/CCV
ICB/CCB
185-26-2D
185-26-2D DA
185-26-3D
185-26-4D
135-26-5D
185-26-6D
185-26-7CD
185-26-8DE
185-26-9D
185-26-10D
ICV/CCV
r nn 'P"H

ICB/CCB
ICSAB
1 /I
110697
110697
110697
110697
110697
110697
	 HflMT
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
linen?

110697
110697
, 1 . T
TRIANGL2
TRIANGL2
TR1ANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TI ' tur" 1
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TR1ANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TXIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TR1ANGL2
rr,r> f i HIT i

TRIANGL2
TRIANGL2
^ 1
1 .A N»
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/IU/Q7
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
11/06/97
< 1 / (\ r i 't 1
1 1 / V U / .) /
11/06/97
11/06/97
/>v
18
18
18
18
18
18
18
18
18
19
19
19
19
19
19
19
19
19
19
20
20
20
20
20
20
20
20
20
20
20
21
21
21
21
21
21
21
21
21
22
22
22
22
^
TT
22
22
x,.i
:06
:12
:17
:22
:26
:31
if
M2
:52
Ml
:16
:21
:26
:3l
:36
Ml
:46
:52
:57
:02
:08
:17
:22
:27
:32
:37
:42
:47
:52
:58
:03
:18
:26
:31
:36
Ml
M6
:51
:56
:02
:07
:12
:17
- 11 .
Ttf
Ml
:56
r (
DKH


DKH
DKH
DKH
nifB
DKH
DKH
DKH
DKfi
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKB
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH
DKH

UM1
DKH
DKH
Alt
Q
X
X
Q
Q
Q
_n 	
Q
Q
S
S
S
s
s
s
s
s
s
s
Q
Q
s
s
s
s
s
s
s
s
s
Q
Q
s
s
s
s
s
s
s
s
s
s
Q


Q
Q
IV
CONC
[R
IR
CONC
CONC
CONC
en HP
CONC
CONC
CONC lL-J- J
CONC . a
CONC !*?-**' ' '/ *
CONC '**- -^ -AJ
COHC/**- £-.3 -&£
CONC / S'S- - S-2 -3,
CONC/fr* - ST3-3.
CONC/J-?- S~J2 -S
CONC/^-^-a -Q.I-
CONC/JS-- s-jl-'/A
CONC
CONC
CONC/y? -£~3- ~/3,
CONC/S'^-Sr^-//7
CONC/J-S--s-^_/f
CONC y
CONC/S-f--•
-------
Analysis Report Su,
3 Sample Name
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
185-26-IC
185-26-IC
185-26-IC
185-26-2C
185-26-2C
185-26-3C
185-26-4C
185-26-5C
185-26-9C
185-26-2D
ICV/CCV
ICB/CCB
135-26-2D
ICV/CCV
ICB/CCB
ICSAB
XIOO
XIOO PDS
XIOO L
XIOO
XIOO DA
XI 00
XIOO
XIOO
XIOO
XlflO


XIOO DA



File
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
110697
Fri 11-07-97 12:03:26
Method Date Tine OpID
TRiAKGl2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TR1ANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TR1ANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
TRIANGL2
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
11/07/97
09
09
09
09
09
09
09
09
09
09
09
09
10
10
10
10
:02
:07
:12
:17
:22
:27
:32
:37
:42
:47
:52
:57
:03
:08
:15
:21
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
SRB
FM page J
Type Mode
S
S
S
S
S
S
5
S
S
S
Q
Q
S
Q
Q
Q
CONC
CONC
CONC
CONC
CONC
CONC
CONC
CONC
CONC
i,0 NC
CONC
CONC
C&NC
CONC
CONC
CONC
/s-l
/ft
/%$
/$*
/s-s-
/f( &
/ z'f-
l'S'4
It's







TLL
-------
          PAGE 1 OF 6
| TRIANGLE LABORATORIES, INC. '
| Sample Preparation Tracking & Management Form '
| Project: 43452 « Client: PES, Inc. (PSC01) 1
| Method: 7 / ^ . Extraction Date:
1 Solvent/Acids ( ) -. Ht\) ^ Hit XV Lot : 1 I"? O CO
Sample Information / /
/L/_1/5Z r/^T
7^(7 020 1
' "^ J> 1 / . , , Ml ( 	 —
1 1 (< 1 <* 1 f-f, f*£, — | l^e-fifair*. i i i l 1
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|Sample| SAMPLE ID / CLIENT |Wgt /(voW Volume] 	 / 	 / 	 | 	 /__/__! 	 / 	 / 	 1 	 /___/__ l__/__/^_l 	 L
|# crd| / SAMPLE ID g /I ml \ ml | | | | | I
1 1 TLI Blank! | | - | Jjl^L,^ 1 1 1 1
|000 | K/l o\ \\. TLI Method Blank | l(^^ 1 ' 1 1 1 1 1
| | 185-26-1C |
|001 | I-M29-1-FHAR |
| | 185-26-1D *:> jS\
|002 | |f$"-2b-|& £^ I-M29-1-H2O2 S\ |
| | 185-26-1E ^L^ 1
|003 \\$%-l(.-l£ J^ I-M29-1-BHAR / ( \
\ \ 185-26-1F C^s |
|004 | |tr_7i-|C |N I-M29-1-KMN04 Sf~ |
| | 185-26-1G C |
|005 | |ifc-.7< -|r f\ I-M29-1-HCL \ S{ 1
|006 | ._,, i,o /W Beaker No. M25 \ /tf 1
| | 188-52-2 | |
|007 | Beaker No.M26 | |
| | 185-26-2C | |
|008 | I-M29-2-FHAR | |
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|009 | . r , I-M29-2-H202 1 OF 2 | /^•\ | {/' \
|010 | I-M29-2rH2O2 2 OF 2 | /S \
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1 1 1 1 1 1 1
1 1 1 1 1 1 1
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|
| Comments: Se«- "H Gr ^t ' ( \ ~ I \J
1
| ^-fc £0(* # 1 f\l ib 10 \iQ,(^(T^ ^ \»\Von"I |/^-
1
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1
1
-REV 07/26/93 (PSTMF 7)—*
-------
PAGE 2 OF 6
Project: 43452
Led, 7* 70
1 Solvent/Acids 0 : -HA/0,. /|
..,§ I
1 | TLI /
-Ikmplel SAMPLE ID /
'• =rd| /
' | 185-26-3C
t .: 	
| 185-26-3D
\* i8$"24~3^ j^
| 185-26-3E
'us I «•
—M 	 j. 	
I 	 + 	 	
• | 185-26-3F
Ins 1 ^
'?16 1 \ffr t/ ir .^
t* Ifco £O 'J r Jj
I | 188-52-5 -fc-frV
I | 188-52-6
D18 |
{| 185-26-4C
9 1
1| 185-26-4D
I
• | 185-2S-4E
| 185-26-4F
w2 llj^'iw '<+f- Ci
| 188-52-9 -iO/'Sr-
I3 ' 7
! | 188-52-10
P 1
T — * 	
i | 185-26-5C
i)25 |
	
Comments :


-
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Client: PES, Inc. (PSC01)
Sample Information
Extraction Date: , ' / / '"^ i .
toa Lot: \(7ofolzr?czc> Tl ' ' 1 ( ' *^ 1 1 1 1 1
I-M29-3-KMH04 | jT^ \ \ I'l^H ' 1 1 1 1 1
Beaker NO.M29 | /^ II 1 1 1 1 1
'-k-JO J> .y/-^..-+ 	 + 	 	 _«. 	 + 	 ...+ 	 + 	 +.
Ill 1 1 1 1 1
Beaker NO.M30 III 1 1 I 1 1
III 1 1 1 1 1
0-M29-1-FHAR III I 1 1 I 1
0-M29-1-H202 | */v£ 1 1 ^ 1 1 1 1 1
1 6^-\ '-.Ic/j-, 1 1 1 1 1
O-M29-1-BHAR \./<. \ l' / M ' "^— 1 1 1 1 1
, -*/> , ,'l|jM?^, i , , i
0-M29-1-KMN04 \/( 1 1 ' ' 1 1 1 1 1
Beaker NO.M33 | /C \ 1 ' ' 1 1 1 1 1
III 1 1 1 1 1
Beaker NO.M34 III 1 I I I 1
III 1 1 1 1 1
0-M29-2-FHAR III 1 I | | I
s^ 9. l


	 - 	 - 	 	 	 - 	 REV 07/26/93
l
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-------
          PAGE 3 OF 6
| TRIANGLE LABORATORIES, INC.
| Sample Preparation Tracking & Management Form
| Project: 43452 . Client: PES, Inc. (PSC01)
| Sample Information
1 Method: /H ' vj Extraction Date: It / C. / 'i 7
1 Solvent/Acids 0 : -UMO^ mtii?j Lot: \}10^O J^lJtfZO
•*s 1 T 1
| | TLI / I Sample | Final I I 1 1 1
|Sample| SAMPLE ID / CLIENT |Wgt / Aol | Volume | 	 / 	 / 	 | 	 / 	 / 	 !__/__/ 	 1 	 / 	 / 	 !__/_
|# crd| / SAMPLE ID | g /lml/| ml | | | | |
1 | 185-26-SD | C>s' I.I 1 1 1 1
|026 l(j£.2,V,-i& \ 0-M29-2-H202 | ^/J 1 " M^ 1 1 1 1
| | 185-26-5E | S/'l.j'C 1 1 1 1 1
I027 1 |££'2(>-Sfc £ 0-M29-2-BHAR | /'C' l"' ' \A 1 1 1 1
| | 185-26-5F | 5/X"'l|(jf?7 1 1 1 1 1
|028 L-,. f-r \ 0-M29-2-KMN04 | /X" I <«d lilt
| | 185-26-5G | 5x"" '|( jfr7 'I'll
| | 188-52-11- \2./iKf-Zla"S<-' | ^X' 1 I L 1 1 1 1 1
|030 | / Beaker No.M35 | /<£ | 1 I , 0-M29-3-H202 IX(" I rf \ \ \ \ \
\ \ 185-26-6E |  0-M29-3-KMN04 \/<^ \ * fc\ 1 1 1 1
| | 185-26-6G | L , |(.u^ 1 | | | |
|036 \\
-------
1
                                                                                                  PAGE 4 OF 6
I TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Project: 43452 Client: PES, Inc. (PSC01)
	 	 	 	 	 	
n T> Sample Information
hod: I \ (0 Extraction Date:, '' / *° /H "^
Solvent/Acids ( ) : H ^ °5 1^1-^O^L Lot : /^C f J /S / 7 6 L O
».„_*___ 	 	 	 + 	 +.'„— + 	 + 	 +
1 TLI / | Sample/I) Final | ^X.fc 1 1
Unolel SAMPLE ID / CLIENT |Wgt //Voy I Volume 1 //!//!// // //
Icrd| / SAMPLE ID | g /I nd/ | ml | | |
| 1 18S-26-7CJ) | <;/1 | | 1
'F ' iy*~2k-"7ci> \ °-M29-BLK-FHAR 1 Xf i i r ^ i i
| 18S-2S-7D | ^S^ 1 n d^, 1 1
'1° ' \tf~y°~~lb N 0-M29-BLK-H2O2 | /{~ | | ' K€_ | | |
| | 185-26-7E | G^^- li.ji L 1 1
»1 li»x- •», -H r V O-M29-BLK-BHAR | -Xc 1 1 1 ' 1 1
T lCC-2-t /t A \s .>
1""+ 	 •" 	 • 	 + + 	 + 	 + 	 + 	 *•"• 	 +
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	 + 	 + 	 " 	 " + 	 * *" * " ""+ 	 * 	 	 + 	
| 188-52-17-«/l?f-H.-7C I 3/ 1 1 „ \,|-}rl>6 b M29-RB-HN03/H202 \^^ 1 1 ' ' ^ 1 1 1
II 185-2S-8E | C^-^1 ' III ' ' '
8 | _ ^ M29-RB-0.1N HN03 1 ^Xj 1 l''/ / " f£- \ 1 1
^_ | 185-26-8F-M 1 ^ ^^^ 1 ' / / ' '
§9 | c M29-RB-KMN04/H2S04 | /^ | | /T'ai^l 1
••• ijS''i^-B^H K x^ 5 ^^
| 185-26-8G-H 1 f- J 1 f, jk^ 1 1
| 185-26-8H 1 5.^1 ' 1 If/ A? ' '
f1 1 If C'Zb'S'H N M29-RB-DI H20 | ^/'f | 1 /I 1 1
*• 	 + 	 . 	 * 	 ~, * ~* " *"" + 	 + 	 + 	
| 188-52-19-10- W|»&f-ll.-£& 1 -^Xl 1 J 1 1
i52 k 1 Beaker NO..M43 | xXr' | |' I1'!'1"? *^-| | |
.£ Kf ->1- IVlo- 1( /(tf-lU-Jf £> • '
Comments : aKX^




Tl<^\
— 5
1
1
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1
1
1
1
1
1
1
I
1
1
I
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1



1
1
1
1
1

1
1
/ i
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
                                                                                       -REV 07/26/93  (PSTMF 7)--+
-------
            PAGE 5 OF 6
1
1
| Project: 43452
1 Method =14-10
| Solvent/Acids () : \

i i
1 1 TLI
| Sample | SAMPLE ID
|# crd|
| | 188-52-20
|053 |
| | 188-52-21
|054 |
| | 18S-26-9C
loss |
| | 18S-26-9D-H
loss | ij^t-'tfl.. f
| | 185-26-9E
|057 | ^.j^g
| | 185-26-9F
|OS8 l|fy_2.L-«tp \
| | 185-26-11
|059 |
| | 188-52-7-^/1
loso | M^L,~fl
| | 188-52-8
|061 |
| | 185-26-10C
|062 |
| | 185-26-100
(063 | ^_ 2,(j -|O/>
| | 185-26-10E
|064 | IgJ-.it-jOt]
| | 185-26-10F
|065 | Ifcj-lt-iof
1
| Comments :
|
1
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
• Client : FES
Sample Information
Extraction Date: U / « /'?
tl*JO, Iff, SOvt, Lot: \HCfV /-------
PAGE 6 OF 6
	 	 +
I TRIANGLE LABORATORIES, INC. |
Sample Preparation Tracking & Management Form |
Project: 43452 Client: PES. Inc. (PSC01) |
1 Sample Information |
Method: (7 'O Extraction Date: "/<*"/ ^ 7 1. 1
Solvent/Acids ( ) : i" ( AJ OS' \
f8 1 L (. S i f"> La*) Contro1 Spike | SjS' \
. 	 	 	 	 	 +1. ? . 	

1 jllV'-ZV.- 4b" MS | <^H
l(^^~2-(3 "-" ^ J^ N\ 5 N /*^ S*
•m . -) . _~t 	 4. 	

I It^r-Lt- lob MS 1 5^ 1
'(sC'Z-C- fOj) rvs J^ ^SJ '
{I LCS ^ 1 ^ \
1 Lei Vl> '-/> 1
11 H^v 1 i
1 -v II
1 lUfSl (l ' '
F*\V i^ J
. . 1 II
1 ' !
1 1 1
{I 1 1
	 * 	 • 	 --+--- 	 +--
1 1 I
t 1 II
' 1 II
1 ' ' '
\ 	 ~1^"7/
Comments: 
-------
                                                                    -PAGE
                                                         I'D
C . *•
                                MERCURY SPIKE LOG
        DATE
PROJECT*

SAMPLE IDs
ORIGINAL
  SPIKE
CONC. (Hg)
STANDARD #
 WORKING
 STANDARD
 PREPARED
  FROM
 SPIKE
AMOUNT
 (mL)
 SPIKE
SAMPLE
 (PPB)
INITIALS
WITNESS
      «/J0
                     3-ozi-Y
                         Mi
-------
J.cport   Table:  HA4J*
                                          Tiiu  11-1)6-91 03:2v:52 AM
TablAName:  3A474            Autosampier  Type:  TYPE TJA
Saupie Positions: 163/192     QC Positions:  13/19      * Sets: 1
Rinse Station location is  rack -1.  DOS.  -1.
— Racks —
Rack 1
1
2
3
4
5
Type
A ui. (L) Rack
Sample (16mm)
Sample (16mm)
Sample (16mn)
Sanple (16mn)
Usage
STD/QC/BLANK
Samples
Samples
Samples
Samples
                                                fPos Left  Analyses./Pos
13
19
48
48
48
10
1
1
1
1
— Sample Sets ---

Set*  Type      Prepare?   Description

  1   Normal      Ho      43452

— Preparation Info —

Sett  Uptake    Uptake*2     Final

Ho Saooles Preoared.
                                    Method     IPos   Rack!   StartPos

                                    TRIAHGL2     29      2       1
                           Dil.Factor
Rack H
     Rov  Col   Sanole Name
                           Set  }   KJsed     Type
1
2
3
4
5
6
17. ..19
Rack 12
Pos Ro
1
2
3
4
5
6
7
8
9
10
11
12 1
13 i
14 2
15 i
1
2
3
i
5
6
Not

i Col
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
STD3
STD1 -BLANK
ICSAB
CHECK LO
ICV/CCV
ICB/CCB
Jsed)

Sample Name
4)452 MB
43452 LCS
185-26-1C
185-26-1C PDS
185-26-1C L
185-26-2C
185-26-2C DA
185-26-3C
185-26-4C
185-26-5C
185-26-6C
185-26-7C
185-26-8E
185-26-8H
185-26-9C
-N
-NJ
-N
-NJ
-N
-NJ


Se















&-
l-
l-
i-
l-
l-


t 1
1



1










2
1
2
1
4
4


fUsed
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-HA-
-NA-
-HA-
-NA-
-NA-
-NA-
-NA-
Standard (. (."
Standard
QC Standard \
QC Standard
QC Standard \~~
QC Standard


Type
Sample
Sample
Sample
Sample ^^~^v
Sample
Sample
Sample
Sample
Sample /
Sample /
Sample 1
Sample /
Sample 1
Sample /
Sample ^ 	 J
                                                                                  \
                                                                                  <^"^  ^\\U\S

                                                                                        \.vi
-------
AiicoSd-npl&r Report Table: KA4'
r 1 ,
Rack
Pos
16
1?
18
19
20
21
22
23
24
25
26
27
28
29
(30.
Rack
Pos
(1..
Rack
Pos
(1..
Rack
Pos
(1..
12
Row
2
2
2
2
2
2
2
2
2
3
3
3
3
3
..48
«
Row
.48
*4
Row
.48
(5
Row
.48

Col
4
5
6
1
8
9
10
11
12
1
2
3
4
5
Hot

Col
Not

Col
Not

Col
Not

Sample Name
i85-262-"ioc' "*
185-26-1D
185-26-1D PDS
185-26-1D L
185-26-20/z ^
185-26-2D;?A
185-26-3D
185-26-4D
185-26-5D
185-26-6D
I85-26-1CD
185-26-8DE
185-26-9D
185-26-10D
Used)

Sample Name
Used)

Sample Name
Used)

Sample Name
Used)
!4 Tha 11-OM7 08:29:52 AM

Set 1
• 1
1
1
1
rft-vvnu: 1
I 1
1
1
1
1
1
1
1
1


Set 1


Set *


Set 1


tUsed.
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-


Klsea


lUsed


lUsed


Type
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample
Sample


Type


Type


Type

page i
-------
.VUoSaiiipier  Report   table: HA475
                                        Fri  11-07-97  08:46:45 AM     me  1
Table Name:  HA475            Autosampier Type:  TYPE TJA
Sample Positions:  181/192    QC Positions: 16/19     } Sets:  1
Rinse Station  location is rack  -1.  DOS. -1.
— Racks —
Rack * Type
i Aus. (L) Rack
2 Sample 116mm!
3 Sample (16mm)
4 Sample (16mm!
5 Sample (lono)
— Sample Sets —
Setl Type Prepare?
Usage
STD/QC/BLAHK
Samples
Samples
Samples
Samples

Description
JPos Left Analyses/Pos
16 10
37 1
48 1
48 1
48 1

Method IPos Rack* StartPos
  1   Normal      No      434S2

—  Preparation Info

Setl Uptake    Uptakei2    Final
                                     Oil. Factor
No Sampl
Rack 11
Pos Row
(1...2
3 1
(4. ..4
5 1
6 1
(7. ..19
Rack n
Pos Row
1 1
2 1
3 1
4 1
5 1
6 1
7 1
8 1
9 1
10 1
11 1
}s Prepared.
Col Sample Name
Not Used)
3 ICSAB
Not Used.)
5 ICV/CCV
6 ICB/CCB
Not Used!

Col Sample Name
1 185-26-1C X100 ' '
2 185-26-1C X100 PDS /
3 185-26-iC X100 L' "
4 185-26-2C X100 ' *
5 185-26-2C X100 DA ''
6 185-26-3C X100 < -
7 185-26-4C X100"
8 185-26-5C X100 / v'
9 185-26-9C X100
10 185-26-2D X100 ' •
11 185-26-2D X100 DA -

Set *

-NA-

-NA-
-NA-


Set 1
1
- 1
1
1
1
1
1
1
1
1
- 1

lUsed

1

2
2


(Used
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-
-NA-

Type
— 1
QC Standard /'6>5'^r /

QC Standard |-6^-f" _J
QC Standard


Type
Sample ~
Sample , e
Sample = i. , /Yln.P^l '
(It 1 rtV^
Sample ^
Sample
Sample-^ ^w... -^ly
. •• i op \ \\y\ c r ii v
Sample— Uit
Sample - Use ^Kl * l^
Sample - USe *^i^( ^ \ *
!aiP!e 1 Use W* im/«J\
Sample ^ ^3^ » j
                                                                                 5/ea
(12...48   Not Used)
-------
•utoSampier  Report   Table:  HA475         Fri  11-07-97 08:46:45  AH     page 2




Rack 13




?os  Row  Col    Sample Naae            Set I  JUsed     Type




=i...48    Not  Used!




Rack 14




?os  Row  Coi    Sasipie Naae            Set i  fllsed     Type




M...43    Not  Used)




Rack »




?os  Row  Col    Sample Naiie            Set I  IQsed     Type




II...48    Not  Used)
-------
Ani:;.»,8 neper:      Averiiei             Tha 11-06--'; i'i:0t>:i8  :'<     -sue
llethod: TRIANGL2   Sample IJiae: STD1-BLANK             Operator:
Run Time:  11/06/97 18:12           Filenaue: 110697
Hode: IR           Type: X         Corr. Factor:        l.(
Lab ID.:           Cast. Sasl. ID.:            Cost.  ID.:
Elems     Ag3280   A13082   Asl890   BJ496   Ba4934   Be313fl
Units     count    count    count    count    count    count
Avge       -.00011  .00378   -.00017  .0009    .00009   .00039
SDev      .0002    .00014   .00003   .00018   .00005   .00001
XRSD      120.154  3.82867  21.8552  20.854   64.3538  4.3798

Eleus     Ca3179   Cd2265   Ce4186   Co2286   Cr2677   Cu3247
Units     count    count    count    count    count    count
Avge   .    .0005    -.00005  .00033   -.00006  -.00003   .00238
SDev      .00004   .00033   .00014   .00009   .00017   .00017
SRSD      9.08573  595.82S  43.6894  143.351  438.601  7.54101

Eleins     Fe2714   KJ664   Li6707   Kg2790   Mn2576   Ho202fl
Units     count    count    count    count    count    count
Avge       .00009   5.15142  .10991   .0003    .00003   .00005
SDev      .00008   .10679   .00213   .00021   .00002   .00005
JRSD      87.6664  2.07308  1.94127  72.4949  61.6871  98.36

Bleus     Ha3302   Hi2316   PJ149   2203-1   2203-2   Sb2068
Units     count    count    count    count    count    count
Avge       -.00022  -.00104  -.0006   .00024   .00011   .00029
SDev      .00345   .00037   .00019   .00029   .00002   .00025
XRSD      1555.76  35.4258  31.7646  120.751  22.441   85.0391

Elenis     1960-1   1960-2   Snl899   Sr4215   Ti3349   T11908
Units     count    count    count    count    count    count
Avge       -.00513  .00187   -.00023  .00016   .00044   -.00025
SDev      .00016   .00017   .00009   .00008   .00056   .00002
JRSD      3.1328   9.49874  39.1099  51.3481  125.803  10.4495

Elenis     VJ924   Zn2062   512881
Units     count    count    count
Avge       -.0003   .00023   .02123
SDev      .00003   .00008   .00048
SRSD      12.7622  36.792!  2.26301
-------
                                           iilu ii--.G---  I i.;-r..-:.  r*     Pci-'; j
Method: 7RIANGL2    Sample  Sane;  STD3                   Operator:
Run Tine:  11/06/97  13:17           Filename:  I1G697
Mode:  IR            Type: X         Corr.  Factor:         l.OCOOO
Lab ID.:            Cast. Soipl.  ID.:  *         Cust.  ID.:
Elens     Ag3280    A13082    Asl890   BJ496    Ba4934    Be3130
Units     count     count     count    count     count     count
Avge        .38907    .01794    .04758   .15781    .29167    .2525
SDev      .00219    .00038    .00003   .00033    .00089    .00101
5SRSD      .56367    2.15727   .07089   .20964    .30217    .40147

Elems     Ca3179    Cd2265    Ce4186   Co2286    Cr2677    Cu3247
Units     count     count     count    count     count     count
Avge        .02181    .872      .11287   .09621    .13801    .17647
SDev      .00015    .00368    .00146   .00039    .00056    .00098
SKSD      .69832    .42215    1.29929  .40763    .40725    .55594

Blenis     Fe2714    KJ664    U6707   Hg2790    Mn2576    Ho2C20
Units     count     count     count    count     count     count
Avge        .00393    27.1069   19.316   .01943    .12056    .07057
SDev      .00012    .37331    .33256   .00032    .00034    .00018
SR3D      3.25399   1.37719   1.72168  1.68395   .2872     .26116

Elems     Ma3302    HJ2316    PJ149   2203-1    2203-2    S&2068
Units     count     count     count    count     count     count
Avge        .23671    .32849    .02073   .15986    .08306    .10583
SDev      .00412    .00087    .00021   .00175    .00054    .00067
SRSD      1.74076   .26679    1.021    1.09859   .65734    .63933

Bleu     1960-1    1960-2    Snl899   Sr4215    TS3349   T11908
Units     count     count     count    count     count     count
Avge        .24707    .14988    .10029   .86376    1.09101   .02749
SDev      .0037     .00193    .00041   .00215    .00154    .0001
XRSD      1.49779   1.29277   .40973   .24922    .14137    .37615

Elems     VJ924    Zn2062    SJ2881   Pb2203    Se)960
Units     count     count     count
Avge        .03694    .08433    .44196
SDev      .00004    .00057    .00342
-------
                                         t-    i i ft *  'i ™  1 i , i1   (•*. r- ii
                                         i iu  11 ~uO ••?'  11 . 
-------
AnaiVf
1
Method
. < Rtpori
L
: TRIANGL2
Run Tiae: 11/06/97
Mode:
Lab ID
Eleias
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
SRSD
El eras
Units
Avge
SDev
2RSD
El ems
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
5RSD
OONC
•:
Ag3280
ppb
497.9
2.002
.402
Ca3179
opb
"510.6
7.596
1.488
Fe2714
pub
514.7
23.09
4.486
Ha3302
ppiD
5.170
.3603
6.97
1960-1
ppb
494.0
4.281
.8666
TJ3349
ppb
496.2
.5142
.1036
Aver

Sample
18:31
Type:
Cast.
A13082
ppb
500.4
5.963
1.192
Cd2265
ppb
502.1
5.602
1.116
1.7664
ppra
4.825
.0996
2.065
NJ2316
ppb
514.3
6.896
1,341
1960-2
ppb
498.6
12.18
2.442
T11908
ppb
495.5
2.608
.5264
ig"

Til.

j !i-i!l>--

Name: ICV/CCV

Q
Snpl. ID.:
Asi890
ppb
503.0
2.52
.5009
CeM36
ppb
498.3
5.718
1.147
Li6707
ppb
476.9
11.75
2.463
PJ149
ppb
498.9
6.357
1.274
Pb2203
ppb
503.6
6.823
1.355
VJ924
ppb
498.9
2.254
.4518
Filename:
11069?
Corr. Factor:
•
BJ496
ppb
495.8
1.269
.2561
Co2286
ppb
501.8
4.186
.8342
Mg2790
ppb
503.7
10.22
2.028
2203-1
ppb
503.0
7.564
1.504
Sel960
ppb
497.1
9.508
1.913
Zn2062
ppb
508.2
10.31
2.028
Cust.
Ba4934
ppb
497.2
3.66
.7362
Cr2677
ppb
502.7
4.618
.9187
Mn2576
ppb
503.7
3.083
.612
2203-2
ppb
503.9
7.029
1.395
Snl899
ppb
496.5
5.141
1.035
31/331
opb
"5098.
18.47
.3623
<• •.,:•&:-••

Operator:

1,00000
ID.: 4345;
Be3130
ppb
"498.0
4.696
.9428
Cu3247
ppb
499.5
4.621
.9252
Mo2020
ppb
497.5
3.456
.6946
Sb2068
ppb
512.4
2.954
.5765
Sr4215
ppb
492.2
2.516
.5111





DKH
-------
An a i
                                        Tfiii
Method:  TR1ANGL2   Simple Name:  ICB/CCB               Operator:
RunTime:  11/06/9? 18:36          Filename:  110697
Mode:  CONC         Type: Q        Corr. Factor:        l.OuOOO
Lab ID.:           Cust. Snipl.  ID.:            Cust. ID.:  43452
El ems
Units
Avge
SDcv
USD
Elems
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
XRSD
Elems
Units
Avge
SDev
XRSD
Elems
Units
Avge
SDev
XRSD
Elems
Units
Avge
SDev
USD
Ag3280
ppb
.7671
1.128
147
Ca3179
ppb
1.340
2.131
159.1
Fe2714
pub
-2.695
27.39
1016
Na3302
ppn
.2392
.2936
122.7
1960-1
ppb
3.005
3
99.83
TJ3349
ppb
-.1472
.5155
350.1
A130S2
ppb
2.167
7.681
354.5
Cd2265
ppb
-.0590
.3241
549.4
KJ664
ppij
.0079
.0611
770.6
Ni2316
ppb
.2186
.9817
449.1
1960-2
ppb
-.8082
2.223
275.1
T11908
ppb
Q5.497
.9422
17.14
Asl890
ppb
-.8604
1.191
138.5
Ce4186
ppb
-.1214
7.177
5913
Li6707
ppb
.0174
.1614
929.8
PJ149
ppb
-5.663
9.844
173.8
Pb2203
pob
:.2383
.4819
202.2
VJ924
ppb
-.5270
.8735
165.7
BJ496
oob
"2490
1.904
764.7
Co2286
ppb
.0140
1.419
10120
Hg2790
npb
"-1.390
14.39
1035
2203-1
ppb
2.537
3.237
127.6
Sel960
ppb
.4617
1.051
227.7
Zn2062
ppb
-.4737
.8701
183.7
Ba4934
ppb
-.0191
.2287
1199
Cr2677
ppb
.3764
1.456
386.8
Mn2576
ppb
.2003
.2027
101.2
2203-2
ppb
-1.624
1.38
84.95
Snl899
ppb
'-1.456
2.188
150.2
Si2881
ppb
60.36
18.07
29.94
BeJijO
pob
"0238
.0724
304.4
Cu3247
ppb
-.0294
1.142
3884
Mo2020
pub
"3767
.5606
255
Sb2068
ppb
3.793
4.382
115.5
Sr4215
ppb
.0219
.1173
535.5





-------
                    Averages
Thu
Method:  TRIANGL2   Sample Name:  ICB/CC3               Operator:  DKH
RunTime:  11/06/97 18:42           Filename:  110697
Node:  CONC        Type:  Q        Corr. Factor:        1.30000
Lab ID.:           Cust.  Snipl.  ID.:     •       Cust. ID.:  43452
Elenis
Units
Avge
SDev
SRSD
El ens
Dnits
Avge
SDev
XRSD
El ems
Units
Avge
SDev
?RSD
Eleins
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
*RSD
Elens
Units
Avge
SDev
XRSD
Ag3280
ppb
-.0937
.5463
582.9
Ca3179
ppb
-1.596
1.92
120.3
Fe2714
ppb
-20.96
30.32
144.6
Na3302
ppm
-.0497
.1646
331.2
1960-1
ppb
3.365
2.266
67.34
TJ3349
ppb
-.4149
.4667
112.5
A13082
ppb
-3.137
10.26
327
Cd2265
ppb
-.3408
.185
54.27
KJ664
ppni
.0032
.063
1987
Ni2316
ppb
-.6086
.5676
93.28
1960-2
ppb
-2.155
.4989
23.15
TH908
ppb
-2.530
3.285
129.8
Asl890
ppb
"-1.749
2.741
156.7
Ce4186
ppb
Q-6.639
1.157
17.43
LJ6707
ppb
-.0382
.1427
373.7
PJ149
ppb
-5.586
8.942
160.1
Pb2203
ppb
-.3679
.8735
237.4
VJ924
opb
"-.8426
1.022
121.3
8.2496
ppb
-2.381
1.008
42.32
Co2286
ppb
-.9695
1.108
114.3
Mg2790
ppb
-9.804
11.68
119.1
2203-1
ppb
2.941
.9617
32.71
Sel960
ppb
-.3169
.4709
148.6
Zn2062
ppb
-1.357
.9692
71.41
Ba4934
ppb
-.1670
.1863
111.5
C:2677
ppb
-.7593
1.001
131.8
Mn2576
ppb
-.1461
.1571
107.5
2203-2
ppb
-2.020
1.62
80.23
Snl899
ppb
-1.832
1.25
68.22
Si2881
opb
"41.61
17.72
42.6
E.e3130
PDO
"-.0497
.i635
127.9
Ca3247
:pb
"-.7959
i.Oll
127.1
Ho2020
;ob
-.8411
.7247
io.16
Sb2068
poo
"9103
2.965
325.7
Sr4215
oob
"-.0609
.0801
131.5





-------
                     Averages
Tiiii il-06-97  11:06:44  rH
Method: TRIAJJGL2   Sample Name:  iCSAB                  Operator: DKH
Run Tiae:  11/06/97 18:52            Fileaaie:  110697
Mode: COHC         Type: Q          Con. Factor:        1.00000
Lab ID.:           Cust. Stupl.  ID.:            Cast. ID.: 13452
Sleas
UuitS
Avge
SDev
SRSD
El ens
Units
Avge
SDev
JRSD
El ems
Units
Avge
SDev
3RSD
El ess
Units
Avge
SDev
XRSD
El ens
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
?RSD
Ag3280
ppb
551.1
2.889
.5242
Ca3179
ppb
450500.
5958
1.323
Fe2714
oob
"180300.
1357
.7525
Na3302
ppn
5.876
.2415
4.111
1960-1
Dpb
"549.9
3.228
.587
TS3349
pob
504.0
1.891
.3752
A13032
ppb
527100.
3977
.7546
Cd2265
ppb
476.3
3.757
.7887
KJ664
ppn
Q26.29
.766
2.914
Ni2316
ppb
459.7
3.425
.745
1960-2
ppb
528.5
4.19
.7928
T11908
ppb
513.4
14.77
2.876
AS1890
ppb
529.6
6.489
1.225
Ce4186
ppb
506.1
4.322
.854
L16707
ppb
632.3
19.58
3.096
PJ149
ppb
548.2
5.902
1.077
Pb2203
ppb
493.5
5.387
1.092
VJ924
ppb
499.4
2.089
.4184
BJ496
ppb
534.2
2.911
.5449
Co2286
ppb
477.4
3.294
.69
Bg2790
ppb
536300.
4262
.7946
2203-1
ppb
511.7
19.52
3.814
Sel960
ppb
535.6
2.505
.4677
Zn2062
ppb
451.1
5.509
1.221
Ba4934
opb
"525.5
3.97
.7554
Cr2677
ppb
483.8
4.301
.889
Mn2576
ppb
464.2
2.954
.6364
2203-2
ppb
484.4
11.21
2.313
Snl899
ppb
515.6
2.045
.3966
SJ2881
opb
"5606.
45.02
.803
Be3130
ppb
490.0
2.461
.5024
Cu3247
pob
560.1
7.038
1.257
Ho2020
ppb
500.6
.6101
,1219
Sb2068
ppb
536.2
6.814
1.271
Sr4215
ppb
515.3
2.976
.5774



-------
Allii/2::  Re CO.".      Av'ci'aSci            Filil il-vb-i?
Method:  TRIANC-L2   Sample Name:  43452  MB               Operator:  DKH
Run Tise:  11/05/97 iS:il           Filename: 110697
Mode:  CONC        Type: S         Corr. Factor:         1.00000
Lab ID.:           Cast. Sip 1.  ID.:     -      Cast.  ID.:  43452
El ems
Units
Avge
SDev
USD
Ag32iO A31890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
L-.1698 L-2.617 L-.0474 L.OQ62 L-.3678 L-1.092
.8497 1.569 .184 .053 .271 1.078
180.5 59.95 388.2 852.6 73.69 98.78
El eras
Dnits
Avge
SDev
XRSD
Cr2677 Ms2576 NJ2316 PJ149 Pb2203 Sb2068
ppb pob ppb ppb pob ppb
L-.9207 l!l!75 L-1.133 L-12,45 L~2029 L-1.432
1.06S .1409 1.597 8.391 .4342 3.215
116 119.9 140.9 67.4 214 224.5
El eras
Units
Avge
SDev
USD
Sei96fl T11908 Zn2062
ppb pob ppb
L0759 L-2.463 5.466
1.169 1.547 1.007
1462 62.81 18.42
-------
Method:  TRIAHGL2   Sample Name:  43452 LCS
Run Time:  11/06/97 19:16          Filename: 110697
Nude:  CONG        Type: S        Corr. Factor:        I.OOflflO
Lab ID.:           Cust. Snpl.  ID.:            Cust.  iD.:  43452
il:l!i:ix  ?N    page li


Operator: DKK
Elems
Units
Avge
SDev
SRSD
Ag3280
job
43.98
.169
.3843
Asi390
pnb
43. «
1.S64
4.288
Ba4$34
ppb
45.60
.2142
.4698
Be3130
ppb
43.77
.2823
.6462
Cd2265
ppb
45.56
.2249
.4937
Co2286
ppb
45.64
.9028
1.978
Elems
Units
Avge
SDev
SRSD
Cr2677 Hn2576 Ni2316 PJ149 Pb2203 Sb2068
spb ppb ppb ppb ppb ppb
'45.70 45.95 45.14 907.7 45.36 46.09
.8015 .3279 .7213 6.692 1.089 2.962
1.754 .7136 1.599 .7372 2.402 6.427
EleBis
Units
Avge
SDev
!RSD
Sel960
sob
45.35
.7495
1.653
TWOS
ppb
45.73
1.97
4.307
Zn2C62
ppb
"184.3
2.741
1.487
-------
         Kecuf
HethoJ:  TRIAHGL2   Simple Sdae: 185-26-1C             Operator: DKH
Riifi Time:  11/06/97 19:21           Filename: 110697
Mode:  CONC        Type: S         Corr. Factor:        1.00000
Lab ID.:          Cust. Sssi. ID.:    •       Cast.  ID.: 43452
Eienis
Units
Avge
SDev
SR5D
Ag3280
ppb
108.4
1.534
1.415
Asl590
ppb
265.7
4.627
1.742
5a4934
ppb
"4061.
13,68
.3368
Be3130
ppb
L-7.919
.3354
4.235
Cd2265
opb
328.5
9.458
1.142
Co2286
ppb
36.53
3.087
8.451
El ems
Units
Avge
SDev
SRSD
Cr2677
ppb
5019.
46.36
.9236
Mn2576
ppb
11113500.
3009
2.652
Ni2316
ppb
375.3
4.66
1.242
PJ149
ppb
4764.
27.84
.5843
Pb2203
pob
H76140.
998.3
1.312
Sb2068
ppb
665.1
3.122
.4695
Elems     Sel960   T11908   2n2062
Units     ppb      ppb      ppb
Avge      "250.8    307.8   H256700.
SDev      8.13     19.55    6740
SR5D      3.242    6.352    2.626
-------
               Alidij      .....       niiiag;a             itl'J il-05-i?  .iiiio.id  P«i
               Method: TRIANGL2    Sample Name:  185-26-1C PDS          Operator:  DKH
               Run Time:  11/06/57 19:26           Filenane:  110697
               Mode: CONC          Type: S         Corr.  Factor:         l.OOCOO
               Lab ID.:            Cust. Smpl, ID.:            Cast.  ID.:  43452
Elems
Units
Avge
SDev
SRSD
Ag3280
ppb
151.8
3.83
2.524
Asl890
ppb
299.6
3.552
1.186
Ba4934
ppb
3995.
28.66
.7175
Be3130
p?b
32.58
.2621
.8045
Cd2265
ppb
871.9
7.232
.8295
C$2286
33b
82.47
.9588
1.163
El eras
Units
Avge
SDev
XRSD
Cr2677
ppb
5057.
41.12
.8132
Mn2576
ppb
H11880C
4494
3.782
Ni2316
ppb
!. 416.4
3.24
.7781
PJ149
ppb
5594.
15.22
.2721
Pb2203
ppb
H76890.
809
1.052
Sb2068
opb
"696.8
8.477
1.217
                Elens      Sel960   T11908   Zn2062
                Units      ppb      ppb      ppb
                Avge        295.7    369.0   H269000.
                SDev       8.575    9.435    9552
                XRSD       2.899    2.557    3.551
-------
".lid i; i ': 3  ;.cp'u'f'.
                                            in* ii-yu"  !i. ');..-:• r.i    uasc
                                 \8X-"-\,V          .  on tt
Hethod: TR1ASGL2   Sample Name: 185-2HC  L     "**     Operator: DKfl
Run Time:  11/06/97 19:31            Filenaae:  110697
Mode: CONC          Type: S          Corr. Factor:         1 .00000
Lab ID.:            Cast. Soipl.  ID.:             Cust.  ID.:  43452
El ems
Units
Avge
SCev
2RSD
El ems
Units
Avge
SDev
iRSD
El ens
Units
Avge
SDev
JRSD
A§3280
ppb
24.70
1.082
4.381
Cr2677
ppb
1148.
5.587
.4867
Sel960
opb
"46.98
.6755
1.438
Asl890
ppb
57.34
1.242
2.167
Mn2576
ppb
H82150.
614.6
.7482
T11908
ppb
78.98
2.577
3.263
B&4S34
ppb
847.8
3.696
.4359
NJ2316
ppb
89.86
.8111
.9026
Z (12062
ppb
H126800.
1384
1.091
Be3130
ppb
L-1.217
.0397
3.264
P.1149
ppb
1060.
9.581
.9037





Cd2265
ppb
"193.9
1.118
.5765
Pb2203
pob
'18460.
125.2
.678





Co2286
ppb
10.44
.5057
4.843
Sb2068
ppb
148.8
2.004
1.347




-------
Asa !..„.„ n^yuii      Averages            T'liU ii-..-;.-i?  il:0c:i:
                               \»3-&2-3,A/  Jo,
Nethod:  TEIANGL2   Sample Name:  185-26-2C             Operator: DKH
Run Time:  11/06/97 19:36           Filenaue: 110697
Kode:  COHC         Type: S         Corr. Factor:         1.00000
Lab ID.:           Cast. Snol.  ID.:            Gust.  ID.:  43452
El ens
Units
Avge
SDev
SRSD
Ag3280
ppb
251,7
2.848
1.132
Asl890
ppb
769.3
21.59
2.806
Ba4934
ppb
11740.
68.91
.5869
Be3130
ppb
23.65
1.051
4.444
Cd2265
ppb
2313.
30.25
1.307
Co2286
ppb
36.91
6.011
16.29
El eras
Units
Avge
SDev
SRSD
Cr2677
ppb
10240.
118.5
1.157
Hn2576
ppb
H92920.
3948
4.248
N12316
ppb
556.6
5.772
1.037
PJ149
ppb
55550.
157
.2826
Pb2203
ppb
H163600.
1777
1.086
Sb206g
ppb
543.9
46.77
8.6
 Elens     Sel960   T11908   Zn2062
 Units     ppb      ppb      ppb
 Avge       600.5    636.6   H291600.
 SDev      6.839    55.62    10100
 USD      1.139    8.738    3.465
-------
                      AVcf aiirS
i i-iib-.- •  i. :.J6:4s  .-.u
                                                                       CdtC
Method: TRIAHGL2   Saipie  Kane;  185-25-2C DA           Operator: DKH
Run Tiffle: 11/06/97  19:41            Filename: 110697
Mode: CONC         Type: S          Corr. Factor:        i.00000
Lab ID.:           Cust. Snip!.  ID.:  •         Cust. ID.:  43452
Eleiss
lin i i s
Avge
SDev
5RSB
Eieras
Units
Avge
SDev
;RSD
El ens
Units
Avge
SDev
SRSD
Ag3280
ppb
246.9
4.076
1.651
Cr2677
ppb
10050.
143. 3
1.425
Sel960
ppb
587.5
11.9
2.025
AS1890
opb
787.5
7.651
.9716
Mn2576
ppb
H84390.
5223
6.188
T11908
ppb
632.2
32.91
5.205
Ba4534
ppb
11860.
76.12
.6421
Ni2316
ppb
552.0
6.926
1.255
Zn2062
ppb
H269800.
13710
5.081
BeJ 130
ppb
23.37
.5075
2.171
PJ149
ppb
55490.
229.7
.4139





Cd2265
ppb
2270.
36.59
1.612
Pb2203
ppb
H159100.
2544
1.599





Co2286
psb
39.07
2.721
6.965
Sb2068
p0b
590.6
30.09
5.095




-------
         f.tpofi      nVc.'aees             Tiiu  ii-Gb-?/ ii;0b:4» PH    page  !/
                               \   --  , v.(    .1,, xs.vc,.Mntt
Method: TRIANGL2   Saaple Name:  1S5-26-3C              Operator:  DKH
Run Time: 11/06/97 19:46           Filename:  110697
Mode: CONG         Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. Siool.  ID.:             Cust.  ID.: 43452
El ems
Units
Avge
SDev
%m
Ag3280
opb
"299.0
4.414
1.476
Asi890
ppb
614.0
3.877
.6315
Ba4934
opb
"8355.
81.61
.9767
Be3130
ppb
L-11.39
.7574
6.647
Cd2265
ppb
2308.
53.39
2.313
Co2286
ppb
46.65
2.18
4.673
Eleffls
Units
Avge
SDe?
JRSD
Cr2677
pob
7981.
166.8
2.09
Hn2576
ppb
B89550.
6003
6.703
Hi2316
ppb
539.9
9.577
1.774
PJ149
DDb
"34050.
170.8
.5013
Pb2203
ppb
11165300.
4853
2.937
Sb2068
ppb
2151.
12.7
.5905
 Eleos     Sel960   T11908   Zn2062
 Units     ppb      ppb      ppb
 Avge       412.6    486.7   H275800.
 SDev      16.66    35.96    16470
 SRSD      4.037    7.388    5.972
-------
         r>epOi":.       Avtiojei             Thu  ii—-v-H  ii:!)6:4i .-Si    case IS
                                                l
Method:  TRIANGL2    Sample Nine; 183-26-4C              Operator: DKH
Run Time:  11/06/9?  19:52           Filename:  110697
Mode:  CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. Soiol. ID.:    .        Gust,  ID.: 43452
Elems
Units
Avge
SDev
XRSD
Ag3230
ppb
49.12
1.669
3.399
Asl890
ppb
45.88
3.37
7.346
Ba4934
ppb
525.7
5.639
1.073
Be3130
ppb
2.167
.0731
3.375
Cd2265
ppb
86.06
.2847
.3308
Co2286
ppb
L-13.97
.5719
4.093
Elems
Units
Avge
SDev
%m
Cr2677
ppb
617.4
6.832
1.107
Mn2576
pob
H48260.
532.5
1.103
(112316
ppb
91.41
.5792
.6337
PJ149
ppb
3061.
18.6
.6075
Pb2203
ppb
"8244.
90.24
1.095
Sb2068
ppb
105.6
4.404
4.171
Elens     Sel960   T11908   Zn2062
Units     ppb      ppb      ppb
Avge       58.55    40.44    66460.
SDev      2.916    4.391    1288
XRSD      4.98     10.86    1.938
-------
                                                                       19
Method: TRIANGL2   Sample Name:  135-26-5C             Operator: DKH
RunTime:  11/06/97 19:57          Filename:  110697
Mode:  CONC         Type: S        Corr. Factor:        1.30000
Lab ID.:           Cust. Smpl.  ID.:           Cust. ID.:  43452
El ens
Units
Avge
SDev
XRSD
Ag3280
ppb
76.66
.4606
.6003
Asl890
ppb
57.15
4.442
7.774
Ba4934
ppb
1026.
5.382
.5245
Be3130
ppb
5.073
.0452
.8905
Cd2265
ppb
217.6
1.639
.7531
Cc2286
ppb
L-16.94
.8757
5.169
El ems
Units
Avge
SDev
XRSD
Cr2677
ppb
1013.
7.684
.7584
Mn2576
ppb
H73510.
1225
1.667
Ni2316
ppb
97.08
1.151
1.185
PJ149
ppb
508.7
11.27
2.216
Pb2203
ppb
15650.
171.8
1.098
Sb2068
pob
139.7
4.034
2.887
El ens
Units
Avge
SDev
XRSD
Sel960
ppb
'78.00
1.089
1.397
T11908
pob
49.22
3.665
7.446
Zn2062
opb
H101800.
2138
2.1
-------
Afii./iii  Report      AvtfiZci             iflu  ii-'J6"i iiiy
Me'.liod:  TRIANGL2   Sample Name:  ICV/CCV               Operator: DSH
Riiii Tiae:  11/06/9? 20:02          Filename:  110697
Mode:  CONC         Type: Q        Corr. Factor:        i.00000
Lab ID.:           Cast. Sop I.  ID.:     .       Cast. ID.:  43452
Eieas
Units
Avge
SDe?
SRSD
Eleas
Units
Avge
SDev
SRSD
Eleas
Units
Avge
SDev
SRSD
Eleas
Units
Avge
SDev
SRSB
Elcffls
Units
Avge
SDev
*RSD
El ems
Units
Avge
SDev
USD
AgJ280
ppb
498.6
6. 808
1.365
Ca3179
ppb
505.5
1.74
.3443
Fe2714
ppb
499.9
29.34
5.87
Na3302
ppm
4.705
.292
6.207
1960-1
DDb
"490.9
3.045
.6203
TJ3349
ppb
488.3
.6043
.1236
A13082
ppb
469.2
11.97
2.55
Cd2265
ppb
506.1
1.184
.234
KJ664
PPra
4.800
.0087
.1812
N12316
ppb
513.5
1.628
.3171
1960-2
DDb
484.9
4.483
.9245
T11908
ppb
487.5
4.541
.9316
AslS90
ppb
505.4
1.012
.2002
Ce4186
pub
495.0
7.13
1.44
Li6707
ppb
474.9
2.996
.6308
PJ149
ppb
499.1
7.036
1.41
Pb2203
ppb
503.0
2.016
.4008
VJ924
ppb
499,8
1.603
.3208
BJ496
ppb
537.6
7.836
1.458
Co2286
ppb
503.4
1.674
.3325
Mg2790
ppb
492.6
14.46
2.936
2203-1
ppb
499.7
16.66
3.334
Sel960
ppb
486.9
2.023
.4155
Z (12062
ppb
515.0
1.008
.1958
Ba4934
pcb
496.8
.758
.1526
Cr2677
ppb
503.7
1.557
.309
Mn2576
ppb
493.1
1.299
.2636
2203-2
ppb
504.7
6.305
1.249
Snl899
ppb
497.1
3.137
.6311
SJ2881
ppb
Q27730.
406.6
1.466
Be3130
opb
"500.4
1.828
.3653
Cu3247
ppb
490.3
2.538
.5177
Mo2020
ppb
502.4
1.431
.285
Sb2068
Dob
"504.6
2.669
.5289
Sr4215
ppb
486.6
.6404
.1316





-------
                                        Thii ii-S5-97 11:06:48  ?H    page
Kethod:  TRIANGL2   Sample Same:  ICB/CCB               Operator:  DKH
Run Tine:  11/06/97 20:03          Filename:  110697
Hode:  CONC        Type: Q        Corr. Factor:        1.00000
Lab ID.:           Cust. SID!.  ID.:            Cost.  ID.: 43452
Elems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
Elerns
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
El ens
Units
Avge
SDev
USD
Ag3280
ppb
.5831
1.255
215.2
Ca3179
ppb
""2939
.395
134.4
Fe2714
pob
-3.068
7.592
247.4
Ha3302
ppu
.1257
.318
253
1960-1
ppb
3.621
3.707
102.4
Ti3349
ppb
"-.0884
.1043
118
A13082
Ppb
-5.757
6.686
116.1
Cd2265
ppb
.0179
.0753
420.2
K.7664
ppffl
.0570
.0247
43.35
Ni2316
ppb
.2245
.5409
240.9
1960-2
ppb
-1.645
4.039
245.5
T11908
ppb
3.404
2.492
73.2
Asl890
ppb
-1.920
.481
25.05
Ce4186
opb
"-1.713
3.051
178.1
L167Q7
ppb
.1192
.0524
43.98
PJ149
ppb
.4887
4.141
847.3
Pb2203
ppb
-.0490
.4499
917.7
VJ924
ppb
.4462
.229
51.31
BJ496
ppb
64.29
3.363
5.232
Co2286
ppb
-.0268
.4619
1725
Kg2790
ppb
1.046
4.137
395.4
2203-1
ppb
1.371
6.605
481.8
Sel960
ppb
.1086
1.738
1600
Zn2062
ppb
4.527
1.003
22.16
Ba4934
ppb
-.0045
.0444
983.8
Cr2677
ppb
.8673
.4644
53.54
Hn2576
ppb
.0689
.0622
90.27
2203-2
ppb
-.7579
3.949
521
Snl899
ppb
-.7881
.5904
74.91
SJ2881
ppb
Q11970.
1128
9.421
Be3130
ppb
-.0403
.0407
100.9
Cu3247
ppb
-.5120
.5161
100.8
Mo2020
ppb
-.1225
.5282
431
Sb2068
ppb
1.343
1.08
80.42
Sr4215
ppb
.0072
.0212
295





-------
                                               .
Method: TR1ANGL2   Sample Name: 185-26-6C              Operator:  DKK
Ran Tine: il/06/97 20:17           Filename: 110697
Mode: CONC         Type: S         Corr.  Factor:         1.00000
Lab ID.:           Cast. Sopl. ID.:    •        Cust.  ID.:  43452
El ems
Units
Avge
SDev
SRSD
Eleins
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
USD
Ag3280
ppb
19.96
2.142
10.74
Cr2677
ppb
"261.0
3.943
1.511
Sel960
ppb
"46.90
2.015
4.296
AS1890
ppb
19.72
2.674
13.56
Mn2576
ppb
15270.
213.1
1.396
T11908
ppb
L-12.55
.9297
7.41
Ba4934
ppb
364.5
1.627
.4464
Ni2316
pob
57.39
.4527
.7888
Zn2062
ppb
27700.
750.9
2.711
Be3130
ppb
L.7395
.0985
13.32
PJ149
ppb
881.2
17.92
2.034





Cd2265
ppb
40.16
.8972
2.234
Pb2203
ppb
4526.
79.51
1.757





Co2286
ppb
L-19.18
.6045
3.152
Sb2068
ppb
87.37
1*1 S *
.101
2.023




-------
                     Averases
                                                     11:06:48
                                                          pise
Method:  TRIANGL2   Sample  Naae:  135-26-7C             Operator: DKH
Run Tiise:  11/06/97 20:22           Filename: 110697
Mode: CONC         Type: S         Corr. Factor:         1.00000
Lab ID.:           Cast. Smpl.  ID.:            Cast.  ID.: 43452
El eras
Units
Avge
SDev
USD
Ag3280
ppb
1.286
.4907
38.17
Asl890
ppb
L3.338
1.957
58.62
Ba4934
ppb
129.8
.5357
.4127
Be3130
ppb
L-.0184
.0732
398.5
Cd2265
ppb
1-1.160
.4438
38.24
Co2286
ppb
L-14.00
1.294
9.246
El ems
Units
Avge
SDev
JRSD
Cr2677
ppb
70.56
.3053
.4326
Kn2576
ppb
15.44
.9564
6.195
NJ2316
ppb
40.31
.9308
2.309
PJ149
ppb
51.87
10.65
20.53
Pb2203
ppb
2.369
1.313
55.42
Sb2068
ppb
38.89
2.189
5.629
El ems
Units
Avge
SDev
IRSD
Sel960
ppb
 40.65
1.309
3.22
                   T11908    Zo2062
                   ppb      ppb
                   L-20.88    102.1
                   3.205    3.199
                   15.35    3.133
-------
Analysis  Report      Averages            liiu iI-G5-il  Ihib.-ia FH
                                           c*. u-iVVI ec
Method:  TRIANGL2   Sample tae:  185-26-SE             Operator:  DXfi
Run Time:  11/06/97 20:27           Filename: 110697
Mode:  CONG         Type: S         Corr. Factor:         1.00000
Lab ID.:           Cast. Sinol.  ID.:    .       Cast.  ID.: 43452
Elems
Units
Avge
SDev
XRSD
Ag3280
ppb
2.568
.3084
12.01
Asl890
ppb
26.68
3.686
13.81
Ba4934
ppb
991.1
7.606
.7674
Be3130
ppb
L:40.53
.4013
.9902
Cd2265
ppb
L-3.530
.4551
12.89
Co2286
ppb
24.33
.7949
3.268
Elems
Units
Avge
SDev
XRSD
Cr2677
ppb
304.9
1.235
.4049
Hn2576
ppb
183.4
1.097
.5981
Ni2316
ppb
119.1
.3963
.3327
PJ149
ppb
747.4
11.04
1.477
Pb2203
ppb
44.09
4.328
9.816
Sb2068
ppb
44.08
5.789
13.13
El ens
Units
Avge
SDev
XRSD
Sel960
ppb
45.66
2.345
5.136
T11908
ppb
L-3.325
5.244
157.7
Zn2062
ppb
491.3
10.28
2.092
-------
.;na .  ..  ....,,„       nvciaiies             Thii  11-06-'? !l:Uc:4S ?M
Method:  TRIANGL2    Sample Name: 185-26-8H              Operator: DKH
RunTime:  11/06/97  20:32           Fileiaie:  11069?
Mode:  CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. Sipl. ID.:           Cust. ID.:  43452
El eras
Units
Am
SDev
!ERSD
Ag3280
ppb
L.4109
.8115
197.5
Asi890
ppb
L-1.545
1.516
98.13
Ba4934
ppb
4.569
.0942
2.061
Be3130
ppb
L-.1502
,0163
10.85
Cd2265
ppb
L-.4708
.2759
58.6
Co2286
ppb
L-1.944
.58
29.84
Elems
Units
Avge
SDev
XRSD
Cr2677 Hn2576 HJ2316 PJ149 Pb2203 Sb2068
ppb Dob ppb pob ppb ppb
7.673 "3.502 3.484 f.8169 LI. 185 4.794
.661 .0727 .2227 2.613 .4166 2.666
8.614 2.075 6.392 319.9 35.16 55.61
Elens
Units
Avge
SDev
XRSD
Sel960 T11908 Zn2062
ppb ppb ppb
L2.428 L-5.021 14.39
1.416 1.531 .7053
58.34 30.5 4.9
-------
         RcpOi'i       Averages             Iliii 11-06--T  ;;;,,6:4S FM    past- 16
                                                    "\l tc
Method:  TRIANGL2   Sanple Name: 135-26-9C              Operator: DO
Run Tiae:  11/06/97 20:37           Filename: 110697
Mode: CONC        Type: S         Corr. Factor:         1.00000
Lab ID.:          Cast. Sapl. ID.:   .         Ciist.  ID.:  43452
El ems
Units
Avge
SDev
JRSD
Ag3280 Asl890 Ba4934 Be3130 Cd2265 Co2236
ppb ppb ppb ppb ppb ppb
181.8 803.7 10860. L-2.354 1840. 39.29
1.02 20.13 92.83 .6654 29.56 4.621
.5613 2.505 .8546 28.26 1.607 11.76
Elems
Units
Avze
SDev
SRSD
Cr2677
ppb
7506.
84.15
1.121
Mn2576
ppb
H93530.
8208
8.776
Ni2316
ppb
456.3
4.657
1.021
PJ149
ppb
33490.
153
.4568
Pb2203
ppb
H173400.
2890
1.667
Sb2068
ppb
"2528.
58.43
2.311
Elems     Sel960   T11908   Zn2062
Units     ppb      ppb      ppb
Avge       446.9   "520.4   H309700.
SDev      8.049    19.41    18120
SRSD      1.801    3.73     5.849
-------
ii fl d i< i * j  u t t
                                        Ili'j 1 i-vo-- •  ii ;uo:»o n
                              l3--,,          ,,.,,
Method:  TRIANGL2    Sample Name: 185-26-10C     ^     Operator: DKH
Ran Time:  11/06/91  20:42           Filenaue: 11369?
liode:  COHC         Type: S         Corr.  Factor:        1.00000
Lab ID.:           Cust. Srapi. ID.:            Cust. ID.:  43452
Eleffls
Units
Avge
SDev
JRSD
Ag3280
ppb
16.38
.8942
5.46
As'1890
ppb
17.04
1.785
10.48
Ba4934
ppb
"235.9
1.188
.5034
Be3130
ppb
L.4616
.0244
5.28
Cd2265
ppb
20.71
.2969
1.434
Co2286
ppb
1-16.21
.2335
1.44
Eleus
Units
Avge
SDev
USD
Cr2677
ppb
181.6
.541
.2979
Mn2576
ppb
10390.
43.33
.4169
Ni2316
ppb
55.15
.6768
1.227
PJ149
ppb
519.5
6.07
1.168
Pb2203
ppb
2248.
18.67
.8304
Sb2068
ppb
78.83
2.485
3.152
El 60S
Onits
Avge
SDev
XRSD
Sel960
ppb
40.77
1.032
2.532
T11908
ppb
L-16.18
6.009
37.14
Zn2062
ppb
25010.
55.08
.2202
-------
                                         T'tlu ii-vO-fl  il:-.'d:4j  PM     Daze i*
Method:  TRIAHGL2    Sample Name:  185-26-1D             Operator: DKH
Run Time:  11/06/97  20:47           Filename:  110697
Mode: CONC         Type: S         Corr. Factor:         1.00000
Lab ID.:           Cust. Sinpl.  ID.:     '      Gust.  ID.:  43452
El ems
Units
Avge
SDev
5RSD
Ag3280
ppl)
2.038
.4145
20.34
Asl890
ppb
L-3.443
1.976
57.38
Ba4934
ppb
5.604
.051
.9108
Be3130
ppb
L-.0754
.0651
86.41
Cd2265
opb
"2.715
.0369
1.36
Co2286
cpb
L-2.204
.3318
15.05
El ems
Units
Avge
SDev
SRSD
Cr2677
pob
15.01
.4245
2.828
Mn2576
ppb
96.61
.7874
.815
«i2316
pob
7.191
.644
8.956
PJ149
ppb
92.27
3.219
3.488
Pb2203
ppb
96.69
1.075
1.112
Sb2068
ppb
7.416
1.982
26.72
EL ens
Units
Avge
SDev
XRSD
Sel960
ppb
3.555
1.011
28.44
TU908
ppb
L-10.27
3.677
35.79
Zn2062
ppb
522.8
1.65
.3156
-------
         neperi      Averages            Tau 11-86-97  11:06:43 ?M    page  25
Method:  TRIANGL2   Sample Hane:  185-26-1D PDS         Operator: DKH
RunTime:  11/06/97 20:52           Filename: 110697
Mode:  CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:          Cust. Siol.  ID.:            Cust.  ID.: 43452
El ens
Units
Avge
SDev
MSB
Ag3280
ppb
40.27
1.411
3.503
Asi890
ppb
35.67
1.553
4.354
Ba4934
ppb
53.78
.1687
.3136
Be3130
ppb
46.36
.3169
.6836
Cd2265
ppb
51.32
.458
.8923
Co2286
ppb
47.08
.3844
.8163
Eieas
Units
Avge
SDev
XRSD
Cr2677
ppb
61.84
.5063
.8187
Mn2J76
pob
"i43.4
.8702
.6069
Ni2316
pob
54.76
.6172
1.127
PJ149
pob
953.5
4.843
.5079
Pb2203
ppb
143.1
2.379
1.662
Sb2068
pob
52.50
.2548
.4853
El ems
Units
Avge
SDev
XRSD
Sel960
ppb
39.58
.5201
1.314
TU908
ppb
37.32
4.273
11.45
Zn2062
ppb
703.4
10.15
1.443
-------
Ar.i.ysis  Rtcort      Averages            Tiu II-Jo-?/  ll:io:4j  FM    case
He-iiod:  TRIAHGL2   Sample Name:  185-25-1D L            Operator: DKH
Ran Time:  11/06/97 20:58           Filename: 110697
Mode:  CQNC        Type: S         Corr. Factor:        1.00000
Lab ID.:          Cut. Smpl.  ID.:     -       Cast.  ID.:  43452
Eieas
units
Am
SDev
SRSD
Ag3280 Asl390 Ba4934 Be3130 Cd2265 Co22S6
ppb pob ppb ppb ppb ppb
L.7747 L-3.615 LI. 016 L-.141S L.3167 L-1.447
1.188 1.652 .207 .0876 .277 1.207
153,4 45.69 20.38 61.95 87.46 83.46
El ens
Dnits
Am
SDev
SRSD
Cr2677 Hn2576 HJ2316 PJ149 Pb2203 Sb2068
ppb ppb ppb ppb ppb ppb
LI. 991 20.50 L.7126 L11.53 20.62 L-.3129
1.492 .5072 1.563 11 1.817 3.041
74.93 2.474 219.3 95.42 8.314 971.8
EUms      Sel960   T11908   Zn2062
Units      ppb      ppb      ppb
Avge      L-.9052  L-5.855   117.4
SDev      1.122    1.842    5.892
SRSD      124      31.46    5.018
-------
                                         Tiiu  il-'Ji>--5  ii:i'5>s
«ethod:  TRIANGL2   Sample Name: ICV/CCV                Operator: DKH
Run Tiiae:  11/06/97 21:03           Fiienaue: 110697
Mode:  CONC        Type: Q         Corr.  Factor:        l.OCOOO
Lab ID.:          Cust. Sopl. ID.:           Cust.  ID.:  45*52
Eiems
Units
Avge
SDev
5RSD
El ems
Units
Avge
SDev
JRSD
El ens
Units
Avge
SDev
5RSD
El ens
Units
Avge
SDev
XRSD
El ens
Units
Avge
SDev
XRSD
El ens
Units
Avge
SDev
SRSD
Ag3280
ppb
493.5
7.476
1.515
Ca3l79
ppb
523.7
12.96
2.476
Fe2714
opb
'499.3
39.91
7.993
Na3302
ppa
Q3.906
1.027
26.28
1960-1
opb
"475.8
12.61
2.65
TJ3349
ppb
489.0
1.754
.3588
A13082
oob
"460.6
14.81
3.215
Cd2265
ppb
512.7
8.474
1.653
1.766*
ppra
4.603
.201
4.367
Ni23!6
ppb
516.6
6.766
1.31
1960-2
ppb
469.0
11.8
2.515
T11908
ppb
488.1
4.628
.9483
Asl890
ppb
504.1
2.162
.429
Ce4186
ppb
488.5
6.734
1.378
Li6707
ppb
451.0
22.39
4.965
PJ149
ppb
488.0
6.971
1.428
Pb2203
ppb
505.5
12.3
2.434
VJ924
ppb
501.3
3.804
.7587
B.2496
ppb
589.1
8.04
1.365
Co2286
ppb
508.3
7.936
1.561
Mg2790
ppb
492.0
14.16
2.877
2203-1
ppb
495.0
29.32
5.923
Sel960
ppb
471.3
11.01
2.335
Zn2062
ppb
532.9
16.69
3.132
Ba4934
opb
"492.2
3.915
.7954
Cr2677
ppb
509.1
8.169
1.605
Mn2576
ppb
510.7
5.929
1.161
2203-2
ppb
510.8
10.13
1.982
Snl899
ppb
502.5
5.778
1.15
Si2881
ppb
Q11180.
490.6
4.386
Be3ijO
pob
509.5
5.224
1.025
Cu3247
ppb
482.8
1.972
.4085
Mo2020
ppb
501.3
3.096
.617
Sb2068
ppb
501.0
6.663
1.33
Sr4215
ppb
484.8
2.182
.4501





-------
AiiiiYSis RiCOit      .;.Tc;-ijc5             Tilii  i.-:/&-'7 11:06:4;;  f'M

Method: TRIAKGL2   Sis:^ Name:  iCB/CCB                Operator:
Run Time:  11/06/97 21:!<           Filename: 110697
Mode: COHC        Ty:e: Q         Corr.  Factor:        1.00000
Lab ID.:           Cus;. Snpl.  ID.:    *        Cast. ID.:  43452
El ems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
Elems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
Ag3280
ppb
.7262
.7451
102.6
Ca3179
ppb
.6787
2.203
324.6
Fe2714
ppb
-13.49
21.41
158.7
Ha3302
ppm
".1988
.1927
96.91
1960-1
ppb
5.257
4.714
89.66
TJ3349
ppb
-.2906
,383
131.8
Al};i2
ppb
-3.544
6.33
164.7
Cd22o5
ppb
-.1799
.28*4
160.3
K_7664
ppG
-.0352
.0343
98.33
Hi2-l6
pob
-.2294
.8636
376.5
1960-2
poo
-3.187
2.654
84.53
111*08
ppb
-.5281
.5005
94.77
AS1890
pub
-2.416
2.714
112.4
Ce4186
ppb
Q-6.308
3.24
51.36
LJ6707
ppb
-.1782
.0695
39.03
PJ149
ppb
-6.059
7.59
125.3
Pb22Q3
ppb
.1015
1.236
1218
VJ924
ppb
-.8122
1.003
123.4
BJ496
ppb
148.5
15.26
10.27
Co2286
ppb
-.4820
1.022
212.1
Hg2790
ppb
-3.931
9.619
244.7
2203-1
ppb
6.956
5.774
83.01
Sel960
ppb
-.3752
.8109
216.1
Zn2062
ppb
2.924
1.039
35.54
Ba4934
pob
-.0606
.1613
266.2
Cr2677
pot)
-.3557
1.053
296
Mn2576
ppb
.8954
.2923
32.65
2203-2
ppb
-3.321
4.418
133
Snl899
ppb
-.9658
.6967
72.13
Si2881
ppb
Q2623.
443.3
16.9
Be3130
ppb
-.0324
.0448
138.1
Cu3247
ppb
-.7340
.9151
124.7
Mo2020
ppb
-.2543
.233
91.64
Sb2068
ppb
.6791
1.51
222.3
SH215
ppb
-.0235
.0799
339.6





-------
Analysis  Report       Avcroita             Tr:u  ii-Ob-K ii:3bMH  FH    page JJ
Method:  TRIAMGL2    Sample Name: 185-26-2C\i -JvviMVV«*Operator: DKH
RunTime:  11/06/97  21:25           Filename:  110697
Hode:  CONC         Type: S         Corr.  Factor:        1.00000
Lab ID.:           Oust. Sipl.  ID.:           Cast. ID.:  43452
Elens
Units
Avge
SDev
USD
Ag3280 As',890 Ba4934 Be3lJi) Cd2265 Co2286
pob cob ppb ppb ppb ppb
21.36 10.11 294.8 1.850 98.35 L-1.458
2.289 .3944 1.263 .0227 1.842 .9631
10.72 3.503 .4285 1.202 1.373 66.06
Elems
Units
Avge
SDev
gRSD
Cr2677
pob
256.9
4.952
1.928
Hn2576
ppb
H30970.
390.5
1.261
NJ2316
ppb
18.97
.9461
4.988
PJ149
ppb
912.0
15.4!
1.69
Pb2203
ppb
4576.
86.98
1.901
Sb2068
pub
35.77
4.304
12.03
Elens     Sel960    T11908   Zn2062
Units     ppb      ppb      ppb
Avge       14.64     11.49    37670.
SDev      1.994    5.893    1010
SRSD      13.62    51.28    2.681
-------
      is  iUpori       Averdiss             Tim  i!-"'»--  .1:1/6:46  ,-jj
Method:  TEIAHGL2   Sample Name: 185-26-2DizDA  <^ntw Aerator: DKH
Run Tine:  11/06/97 21:31           Filename:  110697
Mode:  CONC        Type: S         Corr.  Factor:        1.00000
Lab ID.:          Cust. Smpl. ID.:   •       Cust. ID.:  43452
El ems
Units
Avge
SDev
USD
Ag3280 AS1890 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
22.43 10.28 293.3 1.894 99.23 L-.5537
1.042 1.254 3.73 .0349 1.861 .8046
4.647 12.2 1.272 1.843 1.875 145.3
Eleras
Units
Avge
SDev
5SRSD
Cr2677 Hn2576 Ni2316 PJ149 Pb2203 Sb2068
ppb ppb ppb ppb ppb ppb
259.3 H31040. 20.03 919.9 4613. 39.05
3.902 453.4 1.345 14.15 98.59 1.971
1.505 1.461 6.717 1.539 2.137 5.047
          Sel960   T11908   Zn2062
Units     ppb      ppb      ppb
Avge       14.21    15.32   '38080.
SDev      .6966    3.779    1258
SRSD      4.903    24.67    3.305
-------
                     n»eiiut;s             liiit  ! 1-1)5-^•  :::«o:+» :s    Ddgc j.
Method:  TR1ANGL2    Sample Name:  185-26--D             Operator: DKH
Run Tine:  11/06/97  21:35           Filename:  110697
Mode:  COHC         Type: S         Corr.  Factor:        1.00000
Lab ID.:           Cust. Smpl.  ID.:           Cust. ID.:  43452
Eiems
Units
Avge
SDev
USD
Ag3280 Asl890 Ba4934 Be3UO Cd2265 Co2286
ppb ppb ppb pob ppb ppb
8.861 L.5774 61.49 L1938 26.76 L-.6942
1.135 I. Oil .438 .0754 .6657 1.242
12.81 175.1 .7123 38.91 2.488 179
El ems
Units
Avge
SDev
USD
Cr2677
ppb
78.61
2.475
3.148
Hn2576
ppb
5829.
53.96
.9257
Ni2316
ppb
34.55
1.217
3.521
PJ149
ppb
110.8
13.29
12
Pb2203
ppb
1501.
19.48
1.298
Sb2068
ppb
9.779
3.937
40.26
El ems
Units
Avge
SDev
}RSD
Sel960
DDb
1.043
1.024
12.74
T11908
ppb
L.4333
1.457
336.3
Zn2062
ppb
9978.
253.4
2.54
-------
Aiiii?S;i
Method:  TKIANGL2   Sanple Name:  185-26-4B              Operator: DO
Run Tims:  11/06/97 21:41           Filename: 110697
Mode:  CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:          Cast. Siol.  ID.:     •       Cust.  ID.: 43452
Clems
Units
Avge
SDev
SRSD
Ag3230
ppb
1.115
.3508
31.46
Asl390
pob
L-6.435
.8736
13.65
Ba4934
ppb
4.164
.0341
2.021
Be3130
ppb
L-.0672
.0623
92.64
Cd2265
ppb
L.3876
.2766
71.38
Co2286
ppb
L-.9298
.7895
84.91
El ems
Units
Avge
SDev
XRSD
Cr2677 Mn2576 Ni2316 P.2149 Pb2203 Sb2068
pgb ppb ppb ppb ppb ppb
11.14 12.84 5.895 75.22 13.19 4.896
.6877 .2189 .2578 5.274 1.608 1.422
6.174 1.705 4.373 7.012 12.19 29.05
El ems
Units
Avge
SDev
Sel960
ppb
11.330
1.411
106.1
T11908    Zn2062
ppb      ppb
L-10.05    86.85
1.801     2.165
17.92     2.493
-------
Afi»iy5.is  Report      Averages             Thu  11-06-$? ;i:23:Jl ?H     page 3
Method:  TRIANGL2   Sample Name:  185-26-5D              Operator: DSH
Run Tiae;  11/06/97 21:46           Filename:  110697
Mode:  COHC        Type: S         Corr. Factor:        l.OOCOO
Lab ID.:           Cust. Snpl. ID.:            Gust. ID.:  43452
El ems
Units
Avge
SDev
XRSD
Ag3280
PP
1
1.
56
b
.856
058
.98
T11908
ppb
L-7.652
2.336
30.52
Ba4934
ppb
7.619
.3104
4.075
BeJUO
ppb
L-,0592
.0532
89.82
Cd2265
ppb
13.35
.6561
4.914
Co2286
ppb
17.25
1.759
10.19
Elects
Units
Avge
SDev
USD
Cr2677
ppb
13.39
1.856
13.86
Mn2576
ppb
23.41
.3611
1.543
NJ2316
ppb
20.75
1.295
6.242
PJ149
pub
'l20.4
10.52
3.74
Pb220J
ppb
131.1
1.662
1.268
Sb2068
ppb
8.067
4.027
49.92
El ens
Units
Avge
SDev
SRSD
Sel960
DDb
"J2.75
1.656
12.99
Asl890
opb
L-5.551
1.23
22.15
Zn2062
ppb
156.5
2.326
1.487
-------
•ni:»siii ReD'on       Amaees             Thu ll-Gb-i'i  11:23:3; ?M     aaae 4
He:,lod:  TRIANGL2    Sample Maine: 185-26-6D             Operator: QKH
sin Tine:  11/06/97  21:51           Filename:  110697
Mode:  CONG         Type: S         Corr. Factor:         1.30000
Lab ID.:           Cust. Soipi. ID.:            Cast.  ID.:  <3452
El ems
Units
Avse
SDer
JRSD
Ag3280
ppb
L.4960
2.096
422.6
T11908
ppb
L-9.534
2.637
27.66
Ba4934
ppb
4.640
.1362
2.936
Be3130
ppb
L-.1418
.0602
42.5
Cd2265
ppb
L.3996
.2609
65.29
Co2286
ppb
L-1.46!
.7113
48.44
Eieffls
Units
Avge
5Dev
!1RSD
Cr2677
ppb
9.143
.7417
8.112
Hn2576
ppb
27.30
.0776
.2843
NJ2316
ppb
5.253
.2075
3.95
PJ149
ppb
69.65
5.022
7.21
Pb2203
ppb
14.85
.7636
5.142
Sb2068
ppb
L2.873
1.676
58.36
          Sel960   Asl890   Zn2062
Units     ppb      ppb      ppb
Avge      L.9166   L-6.845   105.0
SBev      1.542    1.572    .6393
USD      168.2    22.97    .6037
-------
         Resort
           Averages
                      Tliii 11-06-97 11:23:31  FM     page 5
Method:  TRIANGL2   Sample Name: 185-26-7CD            Operator:
5un Time:  11/06/97 21:56           Filename:  11069]
Node;  CCNC         Type: S         Corr.  Factor:         1.00000
Lab ID.:           Cust. Sraol. ID.:            Cust.  ID.: 43452
Eieras
Units
Avge
SDev
JRSD
Ag3280 T11908 Ba4934 Be3130 Cd2265 Co2286
ppb ppb ppb ppb ppb ppb
"l.279 L.2338 3.665 L-.0532 L.6835 L-.7493
.6268 1.131 .1213 .0488 .2814 .7189
49.02 483.6 3.31 91.58 42.04 95.94
El ems
Units
Avge
SDev
5RSD
Cr2677
ppb
7.373
.9771
13.25
Kn2576
ppb
46.95
.479
1.02
NJ2316
ppb
L-.3851
.5051
131.2
PJ149
ppb
43.51
7.204
16.55
Pb2203
ppb
10.81
.8513
7.877
Sb2068
ppb
5.495
2.45
44.59
 El ens
 Units
 Avge
 SDev
 XRSD
Sel960
ppb
L.4394
.9151
208.3
Asl890   Zn2062
ppb      ppb
L-4.468   67.79
.5683    1.489
12.72    2.196
-------
Analysis Report      Averages
                               Thu 11-06-97  11:06:48 PH    page 40
Method: TR1ANGL2    Staple Name: 135-26-8DE             Operator:  DO
Run Time: 11/06/97  ;::02           Filename:  110697
Mode: CONC         Tjpe: S         Corr.  Factor:        1.00000
Lab ID.:           Cist. Smpl. ID.:            Cast.  ID.: 43452
El eras
Units
Avge
SDev
XRSD
Ag3280
pob
L5599
.6308
112.7
As 1890
DCO
L-7.723
.3629
12.47
Ba4934
ppb
2.298
.1794
7.81
Be3130
ppb
L-.1071
.0325
30.39
Cd2265
ppb
L-.0145
.2568
1773
Co2286
ppb
L-1.470
.9884
67.24
El ems
Units
Avge
SDev
XRSD
Cr2677
ppb
5.178
.9602
18.54
Xn2576
PD'D
"2.714
.1044
3.849
012316
ppb
L-1.556
.7623
48.99
P.1149
ppb
32.81
4.952
15.09
Pb2203
ppb
5.703
.3512
6.158
Sb2068
ppb
13.737
3.539
94.7
El ems
Units
Avge
SDev
SRSD
Sel960
ppb
L-.5361
1.545
288.3
T11908    Zn2062
ppb      ppb
L:8.718    46.88
1.195    .0907
13.71    .1935
-------
Anai.vYis  Recorc       Averaees
                               rhu 11-06-5; li:0c:ii  FSI    page 41
Method:  TRIANGL2   Sample Name:  135-26-9D              Operator:  DKH
Run Tine:  11/06/97 22:07           Filename: 110697
Mode:  CONC         Type: S         Corr. Factor:        1.00000
Lab ID.:           Cust. Srool.  ID.:            Cust. ID.:  43451
Eleois
Units
Avge
SDev
USD
Ag3280
ppb
1.326
.5055
38.11
Asl890
ppb
L-3.682
1.56
42.37
Sa4934
ppb
7.231
.1272
1.759
Be3130
ppb
L-.0682
.0778
114
Cd2265
ppb
1.588
.3049
19.21
Co2286
ppb
L-.7454
.8324
111.7
 Elens
 Units
 Avge
 SDev
 USD

 El ems
 Units
 Avge
 SDev
 KRSD
Cr2677   Hn2576
ppb      ppb
 10.78    413.7
.9432    3.019
8.753    .7298
                  Ni2316
                  ppb
                  LI.896
                  .4973
                  26.23
                  PJ149   Pb2203
                  ppb      ppb
                   J8.I9    59.33
                  7.243    1.721
                  9.262    2.901
Sb2068
ppb
 5.136
2.36
45.94
Sel960
ppb
L.7496
2.547
339.8
T11908   Zn2062
ppb      ppb
L-6.742   558.7
2.384    10.43
35.36    1.866
-------
  alysis  Report      Averages            Tnti ;j-i)6-9i  l!:0c;:48 Fto    page 42
Method:  TRUMGL2   Sispie Nane:  185-26-1'JD            Operator:  DKH
RunTime:  11/06/97 22:i2           Filename: 11069]
Mode:  CONC         Type: S         Corr. Factor:        i.00000
Lab ID.:           Cust. Sao I.  ID.:            Cust.  ID.; 43452
El ems
Units
Avge
SDev
USD
Ag3280
ppb
1.322
.9591
72.57
As 1390
pcb
L-9.582
.4598
4.799
Ba4934
ppb
"4.148
.0873
2.104
Be3130
ppb
L-.1521
.0702
46.15
M2265
ppb
1.988
.1778
8.945
Co2286
ppb
L-1.199
,4785
39.9
Elems
Units
Avge
SDev
SRSD
Cr2677 Xo2576 Ki2316 PJ149 Pb2203 Sb2068
ppb ppb ppb ppb ppb ppb
9.103 31.15 L.7368 60.27 42.47 L-.8190
.7205 .1374 1.047 5.237 1.023 .8659
7.915 .6018 142.1 8.69 2.408 105.7
Elems
Units
Avge
SDev
KRSD
Sel960
ppb
8.306
1.278
15.39
T11908
ppp
L-13.35
2.143
16.05
Zn2062
ppb
125.5
1.308
1.042
-------
Analysis Report      Averages
Th'J 11-06-91  11:06:43
page 43
Method:  TRIANGL2   Sample (lane:  ICV/CCV                Operator:
Run Time:  11/06/97 22:11           Filename: 110691
.Mode: CONC         Type: Q         Corr. Factor:         1.00000
Lab ID.:           Cust. Sup 1.  ID.:            Cast.  ID.:  43452
El ens
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
mil
Elens
Units
Avge
SDev
USD
Elens
Units
Avge
SDev
XRSD
Eleijs
Units
Avge
SDev
MSD
Elens
Units
Avge
SDev
XRSD
Ag3280
ppb
501.8
4.731
.944
Ca3119
ppb
532.0
6.311
1.186
Fe2714
ppb
525.9
28.26
5.373
Na3302
POD
4.758
.3405
7.156
1960-1
ppb
489.4
5.912
1.208
TJ3349
pob
498.8
2.051
.4112
A13082
pob
460.1
12.06
2.62
Cd2265
pob
525.7
3.332
.6339
K_7664
ppn
4.711
.0739
1.569
Ni2316
ppb
523.5
3.267
.6241
1960-2
DDb
"481.7
3.125
.6406
T11908
ppb
501.4
2.617
.5218
Asl890
ppb
507.5
1.824
.3594
Ce4186
ppb
496.9
7.155
1.44
Li6701
ppb
451.9
6.422
1.402
PJ149
ppb
503.6
11.08
2.2
Pb2203
ppb
522.2
4.265
.816?
VJ924
ppb
510.1
2.911
.5111
BJ496
pob
~523.7
2.36
.5462
Co2286
pub
520.6
4.048
.7775
Ng2790
ppb
509.7
14.2
2.786
2203-1
ppb
520.1
8.311
1.598
Sel960
ppb
488.3
4.046
.8285
Zn2062
ppb
539.0
6.165
1.144
Ba4934
pob
492.2
.6035
.1226
Cr2677
ppb
522.5
4.491
.8608
Hn2516
ppb
514.7
2.454
.4767
2203-2
ppb
52J.3
3.212
.6138
Snl899
pob
513.3
2.059
.4011
Si2881
ppb
5311.
66.46
1.251
Be] n!j
ppb
519.4
1.342
.2583
Cu3247
ppb
483.4
2.26
.4676
Mo2020
ppb
510.0
.5833
.1144
Sb2068
ppb
507.3
3.83
.7549
Sr4215
ppb
490.1
1.071
.2185





-------
Analysis  Report       Averages
Thu 11-06-:-"  11:06:48 F«    oaze 44
Method:  TR1AHGL2   Sample Name:  ICB/CCB               Operator: DKH
Run Time:  11/06/97  22:22           Filename:  110697
Mode: CONC         Type:  Q        Cofr. Factor:        1.00000
Lab ID.:            Cast.  Sopl.  ID.:            Cust.  ID.: 43452
El ems
Units
Avge
SDev
IRSD
Elens
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
*RSD
El ems
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
XRSD
Elems
Units
Avge
SDev
USD
Ag3280
ppb
Q1.370
1.032
75.35
Ca3179
opb
"2.961
2.499
84.41
Fe2714
ppfa
5.727
29.18
509.5
Ka3302
ppm
.2654
.242
91.17
1960-1
pob
2.039
7.275
356.9
TJ3349
ppb
.1792
.4377
244.2
A13082
ppb
-7.820
6.178
79
Cd2265
ppb
.2290
.1804
78.79
KJ664
ppm
.1998
.0111
5.572
N12316
ppb
.0680
1.242
1828
1960-2
ppb
-1.136
4.556
401
T11908
ppb
4.084
1.953
47.82
Asl890
ppb
-.3935
1.8
457.4
Ce4186
ppb
Q3.660
6.695
182.9
LJ6707
ppb
'.4200
.1076
25.62
P.2149
ppb
2.110
14.2
673.1
Pb2203
opb
".4733
.4393
92.71
VJ924
ppb
.8287
1.376
166
BJ496
ppb
29.29
1.219
4.162
Co2286
ppb
.4016
1.104
274.9
Mg2790
ppb
4.852
13.16
271.2
2203-1

1.284
8.595
669.5
Sel960
ppb
-.0790
.7034
890.5
Zn2062
ppb
.2496
.811
325
Ba4934
ppb
.1459
.2206
151.3
Cr2677
ppb
.6518
1.279
196.2
Mn2576
ppb
.5819
.1886
32.41
2203-2

.0694
4.825
6950
Snl899
ppb
.0899
1.27
1413
SJ2881
ppb
Q267.4
10.82
4.048
Be3130
ppb
.0202
.1664
825.1
Cu3247
ppb
-.3766
1.109
294.4
Mo2020
ppb
.7872
.8789
111.6
Sb2068

Q4.442
2.992
67.36
Sr4215
ppb
.1340
.1453
108.4





-------
    ysis  Report
Tn» i1-G6-S7 ii:.jc;i3 ?K    page  45
Method:  TKIANGL2   Sample Naae: ICB/CCB                Operator:  DKH
RunTime:  11/06/97 22:41           Filename: 110697
Mode:  CONC         Type: Q         Corr.  Factor:        i.00000
Lab ID.:           Cast. Snot. ID.:           Cust.  ID.: 4j452
El eras
Units
Avge
SBev
SRSD
El ems
Units
Avge
SDev
XRSD
Elems
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
XRSD
Ag3280
ppb
.5688
1.516
266.6
CaJ179
ppb
-1.439
1.207
33.84
Fe2714
ppb
-20.94
17.78
84.91
Ha3502
ppB
.1397
.3934
281.5
1960-1
Ppb
3.035
6.249
205,9
TJ3349
ppb
-.4506
.3357
74.51
A13082
ppb
-13.47
8.282
61.48
Cd2265
ppb
-.0925
.221
239
KJ664
ppiD
.0199
.0499
250.3
N12316
ppb
-.9610
.3364
35.01
1960-2
ppb
-4.628
3.036
65.61
T11S08
ppb
-3.300
1.074
32.54
AS1890
ppb
-1.224
.2506
20.47
Ce4186
ppb
Q-8.714
5.72
55.64
LJ6707
ppb
-.0683
.1309
191.8
PJ149
opb
"-8. 305
5.573
67.1
Pb2203
ppb
-.2863
.7024
245.3
VJ924
pcb
-.7315
.7156
97.82
B.2496
ppb
18.06
1.562
8.652
Co2286
ppb
-.9489
.9597
101.1
Hg2790
ppb
-9.726
9.064
93.2
2203-i
ppb
8.419
8.967
106.5
Sel960
ppb
-2.076
.4791
23.08
Zn2062
ppb
-1.213
.8563
70.6
Ba4934
ppb
-.1674
.1348
80.54
Cr2677
ppb
-.9021
.9304
103.1
Mn2576
ppb
-.1179
.1015
86.1
2203-2
ppb
-4.632
5.517
119.1
Snl899
ppb
-2.738
1.547
56.5
SJ2881
pob
115.1
17.52
15.22
Be J 130
Ppi)
-.1251
.0539
43.1
Ca3247
ppb
-1.196
.7679
64.23
Mo2020
poi)
-.6455
.1638
26.15
Sb2068
ppk
-1.182
3.323
281.3
Sr4215
ppb
-.0722
.0655
90.69





-------
Report
                    Averages
I!iu  ll-06-?7 ;:   ;:43 FM    page '4
Method:  TRIANGL2   Sample Hasie: iCSAB                 Operator:
Ran Tine:  11/06/97 22:55           Filename: 110691
Mode:  CGNC        Type: Q         Corr. Factor:        i.JGOOO
Lab ID.:           Cust. Smpl.  ID.:            Oust.  ID.:  ij452
E!e5is
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
5RSD
El ems
Units
Avge
SDev
SRSD
Elems
Units
Avge
SDev
SRSD
El eras
Units
Avge
SDev
SRSD
El ess
Units
Avge
SDev
USD
Ag3280
ppb
550.8
1.384
.2512
Ca3179
ppb
468900.
2297
.4899
Fe2714
ppb
184400.
671.6
.3642
Na3302
ppra
"5.380
.0213
.396
1960-1
ppb
542.6
5.121
.9433
Ti3349
ppb
502.8
1.964
.3907
A13082
ppb
517300.
2154
.4164
Cd2265
ppb
490.7
1.973
.4022
KJ664
ppm
Q24.10
.0248
.1029
112316
ppb
471.6
3.535
.7496
1960-2
ppb
528.9
6.38
1.206
T11908
ppb
516.1
12.3
2.383
Asl890
ppb
533.3
1.351
.2532
Ce4186
ppb
504.5
3.95
.783
Li6707
ppb
581.6
.2748
.0473
PJ149
ppb
543.9
8.211
1.51
Pb2203
ppb
508.!
5.691
1.12
VJ924
ppb
506.4
2.538
.5013
BJ496
ppb
555.5
1.822
.323
Co2286
ppb
490.0
2.72
.5551
Mg2790
ppb
546500.
1832
.3353
2203-1
ppb
532.4
2.193
.4118
Sel960
ppb
533.5
4.198
.7868
Zn2062
ppb
471.7
2.934
.622
Ba4934
ppb
518.4
1.964
.3789
Cr2677
ppb
497.1
2.277
.458
Kn2576
ppb
471.9
1.868
.3959
2203-2
ppb
495.9
9.515
1.919
Snl899
ppb
526.1
4.636
.8814
Si2881
pob
5664.
16.39
,2894
Be5!30
ppb
506.1
2.797
,5;26
Cu3247
ppb
540.7
2.159
.3553
Ilo2520
ppb
5D9.4
2.S62
.5cl9
Sb2068
Dpb
'5)3.7
5.471
1.025
Sri2l5
pDO
509.7
1.741
.3415





-------
Analysis  Report      Averages             Fri  11-07-97 10:29:32 AH     page 1
                               i* V 5 Z-\ 2- ,    c^.
Method:  TRIANGL2   Saaple (fane: 185-26-1C XiOO         Operator: SRB
RunTime:  11/07/97 09:02           Filename:  110697
Mode:  COHC         Type: S         Corr. Factor:        1. 00000
Lab ID.:           Cast. Sfflol. ID.:           Cast. ID.:  43452
Eieffls
Units
Avge
SDev
XRSD
Hn2576
ppb
"6126.
22.95
.3753
Pb2203
poo
956.0
4.613
.4825
Zn2062
ppb
7723.
47.87
.6199
-------
Analysis Report      Averages             Fri 11-07-97 ii):23:32  AH     page 2
                                                           tt
Method:  TRIAHGL2    Sample Name:  185-26HC X100 PDS     Operator:  SRB
Run Time: ii/07/97  09:07           Filename: 110697
Mode: CONC         Type: 8         Corr. Factor:        1.00000
Lab ID.:           Gust. Smol.  ID.;            Cost. ID.:  43452
Eisins     Mn257o   Pb2203    Zn2062
Units     ppb      ppb       ppb
Avge      "6106.    1002.    '7879.
SDev      50.96    9.61      34.73
XRSD      .8346    .9592     1.202
-------
Analysis  Report       Averages             Fri  11-07-97  10:29:51 AH     page 3
Method:  TRIAHGL2   Sample Name: 185-26-1C X100  L       Operator: SRB
Run Time:  11/07/97 09:"l2           Filename:  110697
Mode:  CONC         Type: S         Corr. Factor:         1,00000
Lab ID.:           Cast. Sup I. ID.:            Gust.  ID,: 43452
Elenis     Hfl2576   Pb2203   Zn2062
Units     ppb      ppb      ppb
Avge      "1248.     192.1    1564.
SDev      1.736    1.087    2.219
XRSD      .1391    .5658    .1419
-------
Analysis Report      Averages             Fri  ii-i)7-}? 10:29:32 AM     page  4

                               183-52. -3, A,    as. \HMViefi
Method:  TRIANGL2   Saaple Narae:  185-2fr-2C  X100         Operator:  3RB
Run Time:  11/37/9; .;?: 17           Filename:  110637
Mode:  CONG        Type: S         Corr. Factor:        1.00000
Lab ID.:          -lust. Sinpl,  ID.:            Cost. ID.:  43452
Elems     Ha2576   ?b2203   Zn2062
Units     ppb      ppb      ppb
Avge       14080.   2226.    16070.
SDev      129.6    25.68    329.1
SRSD      .9205    1.154    2.048
-------
Analysis  Report      Averages            Fri 11-37-97 10:29:32  AM     page
Method:  TRIAKGL2   Sample Nut:  185-26-2C X100 DA      Operator: SRB
Run Time:  11/07/9? 09:22           Filename: 110697
Mode:  COSC        Type: S         Corr. Factor:        1.00000
Lab ID.:          Oust. Soipi. ID.:           Cust. ID.:  43452
Elena     Hn2576   Fb2203   Zn2062
Dnits     ppb      ppb      ppb
Avge       H950.   2385.    17210.
SDev      15.75    4.149    132.3
HID      .112     .174     .7691
-------
     1
Analysis Report      Averages             Fri 11-07-97  10:29:32 AX     page 6
Method:  TRIANGL2   Sample Name:  135-26-iC X100         Operator: SRB
Run Tiae: 11/07/97 09:27           Filename: 110697
Mode: CONC         Type: S         Corr. Factor:        1.00000
Lib  ID.:           Gust. Smpl. ID.:            Cust. ID.: 43452
Eleffls     Hn2576   Pb220J   Zn2062
Units     ppb      ppb      ppb
Avee       10700.    2465.    19230.
SDe?      129.2    32.19    510.7
-------
Analysis Report      Averages             Fri il-07-:^ !0:25:J2  AH     page  1
                                                           to
Method: TR1AKGL2   Sample Name: 135-26-4C X100         Operator:  SRB
Run Tine: 11/07/97 09:32            Filename:  110697
Node: COHC         Type: S          Corr. Factor:        1.00000
Lab  ID.:           Cust. Smpi.  ID.:            Cast. ID.: 43452
Elems     Mn2576   Pb2203   Zn2062
Units     ppb      ppb      ppb
Avge       643.6    96.00    806.1
SDev      4.304    1,444    16.11
-------
Analysis  Report      Averages            Fri 11-07-37 10:29:32 AM     page 8
Method;  TRIAHGL2   Sample Name:  185-26.5C X100         Operator: SRB
Run Tine:  11/07/97 09:37           Filenaue:  110697
Mode:  CONC        Type: S         Corr. Factor:        1.00000
Lab ID.:          Cust. Srapl.  ID.:            Cast. ID.:  43452
Elems     Mn2576   Pb2203   Zn2062                                      >^<* •*•  **   SuVv)  ^  \v\vn
Units     ppb      ppb      ppb
Avge       1083.    177.5    1265.
SDev      6.914    1.069    15.56
SRSD      .6385    .6024    1.23
-------
Analysis Report       Averages             Fri  11-07-3?  i.;:23:32 AM     page 9
                               \$5 - 52.- 7y 3   , c&
Method: TRIAHGL2    Sample Nane: 1S5-26-9C X100        Operator:  SRB
Run Time:  11/07/9?  05:42           Filename:  110697
Kode:  CONG        Type: S         Corr.  Factor:
Lab ID.:           Cust. Smpl. ID.:            Cust.  ID.
El eras     Hn2576    Pb2203   Zn2062
Units     ppb      ppb      ppb
Avge       11520.    2560.     24970.
SDev      25.66    3.045    144.7
JRSD      .2228    .119     .5796
                                                       .00000
                                                        43452
-------
Analysis  Report       Averages             Fri li-0"-?? 10:29:32 AM    page 10
Method:  TR1ANGL2    Sample  Name:  185-26*20,13(100   ^   Operator: SRB
Run Time:  11/07/97  09:47            Filenane: 110697
Mode:  CONG         Type: S          Corr. Factor:        1.00000
Lab ID.:           Gust. SUP I.  ID.:            Cast.  ID.: 43452
Eleois     Mn2576    Pb2203    Zn2062
Units     ppb      ppb       ppb
Avge       358.0     48.37     416.7
SDev      2.788     .0393     6.944
SRSD      .7787     .0822     1.667
-------
Anaivsis Report
Averages
rri  11-07-91  10:29:32 AH    page 11
Method: TRIANGL2   Sample Name:  ICV/CCV                Operator:  SRB
Run Time: 11/07/97 09:52            Filename:  110697
Hode: COSC         Type: Q          Corr. Factor:        1.00000
Lab ID.:           Cust. Snip I.  ID.:            Cast.  ID.: 43452
El ens
Units
Avge
SDev
XRSD
El ens
Units
Avge
SDev
XRSD
Eleios
Units
Avge
SDev
XRSD
El ens
Units
Avge
SDev
XRSD
Eleas
Units
Avge
SDev
XRSD
Elems
Units
Avge
SDev
XRSD
Ag3280
ppb
512.0
3.436
.6711
Ca3179
ppb
512.5
12.86
2.51
Fe2714
ODD
"524.9
28.41
5.412
Na3302
ppu
5.039
.2426
4.815
1960-1
ppb
514.6
9.143
1.777
TJ3349
ppb
509.3
3.006
.5902
A13082
ppb
481.9
3.899
.809
Cd2265
ppb
504.5
9.403
1.864
KJ664
ppii
4.898
.1212
2.475
Ni2316
ppb
507.9
10.29
2.026
1960-2
ppb
500.2
6.906
1.381
TH908
ppb
497.7
7.256
1.458
Asl890
ppb
508.7
6.622
1.302
Ce4186
DD'D
513.5
1.537
.2994
Li6707
ppb
430.0
13.85
2.826
PJ149
ppb
502.6
7.918
1.575
?b2203
ppb
511.6
8.199
1.602
V.2924
ppb
513.4
5.484
1.068
BJ496
ppb
509.3
2.039
.4003
Co2286
ppb
513.9
8.305
1.616
Mg2790
ppb
521.4
15.3
2.934
2203-1
ppb
522.2
15.32
2.933
Sel960
ppb
505.0
7.39
1.463
Zn2062
ppb
506.9
15.99
3.155
Ba4934
ppb
518.4
3.145
.6066
Cr2677
ppb
509.5
8.223
1.614
Mn2576
opb
"509.1
6.599
1.296
2203-2
ppb
506.3
5.284
1.044
Snl899
ppb
514.5
10.74
2.087
Si2881
ppb
5179.
21.91
.423
Be3130
ppb
520.5
8.744
1.68
Cu3247
ppb
519.3
4.947
.9518
Mo2020
pub
506.2
3.853
.7611
Sb2068
ppb
525.3
4.033
.7678
Sr4215
ppb
512.0
1.158
.2262




-------
Analysis  Report      Averages
Fri  11-07-97 10:29:32 AH    page 12
Method;  TRIAN6L2   Sample Name:  ICB/COB                Operator: SRB
Run Tiie:  11/07/97 09:57           Filename: 110697
Mode:  CONC        Type: Q         Corr.  Factor:        1.00000
Lab ID.:           Cast. SUP!.  ID.:            Cust.  ID.:  43452
El em s
Units
Avge
SDev
USD
El ens
Units
Avge
SDev
USD
El ems
Units
Avge
SDev
USD
El ens
Units
Avge
SDev
USD
Elems
Units
Avge
SDev
USD
Elems
Units
Avge
SDev
USD
AgJ280
ppb
.8005
.4031
50.36
Ca3179
ppb
2.703
.3394
12.56
Fe2714
ppb
-8.231
3.105
37.72
Na3302
PPB
.2448
.05
20.44
1960-1
ppb
6.414
5.098
79.48
TJ3349
ppb
-.2056
.1158
56.31
A13082
ppb
-41.54
1.651
3.974
Cd2265
ppb
-.0682
.125
183.4
KJ664
ppiD
-.0840
.0233
27.75
Ni2316
Dob
",9935
.389
39.16
1960-2
ppb
-5.182
2.706
52.22
T11908
ppb
.2386
2.915
1222
AS1890
ppb
-2.863
1.477
51.57
Ce4186
ppb
Q-9.725
6.453
66.36
Li6707
ppb
-.3379
.0488
14.43
PJ149
ppb
-7.597
2.046
26.93
Pb2203
ppb
-.5159
.572
110.9
VJ924
ppb
Q-2.301
.0578
2.511
B.2496
ppb
2.283
.84
36.79
Co2286
ppb
-.2663
.4003
150.3
Mg2790
opb
'-5.324
2.49
46.77
2203-1
ppb
9.052
6.064
66.99
Sel960
ppb
-1.321
.5374
40.69
Zn2062
ppb
-1.226
.2878
23.49
Ba4934
ppb
-.0508
.0448
88.37
Cr2677
ppb
-.4495
.4269
94.96
Mn2576
ppb
-.0250
.0579
231.8
2203-2
ppb
-5.293
2.224
42.02
Snl899
ppb
-1.939
.3087
15.93
312831
ppb
27.47
14.29
52.03
BeJlJO
ppb
-.3900
.0244
6.257
Cu3247
ppb
1.467
.438
29.86
Mo2020
ppb
-.0283
.7822
2765
Sb2068
ppb
-.5498
.8877
161.5
SH215
ppb
-.0114
.0335
294.3





-------
Analysis  Report      Averages             Fri  11-07-97  10:23:32 AH    page  13
Method:  TRIANGL2   Saopie Hame: 185-26-2D X100  DA      Operator:  SR3
Run Time:  11/07/97 10:03           Filename:  110697
Mode:  CONC         Type: S         Corr.  Factor:        1.00000
Lao ID.:          Cast. Ssipl. ID.:            Cast.  ID.: *3452
Elems     Hn2576   Pb2203   Zn2062
Units     ppb     ppb      ppb                                          V*»*  0^3
Avge       351.7    47.31    404.8
SDev      2.07     .3937    6.061
USD      .5837    .8322    1.497
-------
Analysis  Resort
Averages
Fri  11-07-97  10:29:32 AM    page 14
Method:  TR1ANGL2   Sample Name:  ICV/CCV "               Operator: SRB
RunTime.:  11/07/97 10:08          Filename: 110697
Mode:  CONG         Type: Q        Corr. Factor:         1.00000
Lab ID.:          Cast. Snipl.  ID.:            Cust.  ID.:  43452
El ems
Units
Avge
SDev
SRSD
Eleins
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
SRSD
Elens
Units
Avge
SDev
JR5D
El ens
Units
Avge
SDev
XRSD
El ems
Units
Avge
SDev
SRSD
Ag3280
opb
"512.1
7.463
1.457
Ca3179
ppb
511.4
20.25
3.959
Fe2714
ppb
533.9
52.87
9.903
Ha3302
npiB
Q5.648
.6675
11.82
1960-1
pob
517.1
14.97
2.894
T13349
pub
507.4
4.399
.367
A13082
ppb
487.6
10.4
2.133
Cd2265
ppb
501.7
13.5
2.69
1.7664
ppm
4.912
.1408
2.866
N12316
ppb
505.3
13.79
2.73
1960-2
ppb
505.2
13.17
2.607
T11908
ppb
502.7
1.816
.3612
Asl890
ppb
503.9
6.873
1.364
Ce4186
ppb
514.3
13.6
2.645
LJ6707
ppb
487.8
21.65
4.439
P.I 149
ppb
502.3
19.37
3.856
Pb2203
ppb
512.1
12.4
2.421
VJ924
ppb
511.6
7.536
1.473
BJ496
ppb
506.7
3.01
.5941
Co2286
ppb
511.9
13.2
2.579
Mg2790
ppb
523.3
30.12
5.756
2203-1
ppb
530.4
19.1
3.6
Sel960
ppb
509.1
13.77
2.704
Zn2062
ppb
503.8
22.99
4.563
Ba4934
ppb
516.4
4.371
.8464
Cr2677
ppb
507.8
13.62
2.682
Mn2576
ppb
507.9
9.78
1.925
2203-2
ppb
503.0
9.244
1.838
Snl899
ppb
510.0
12.52
2.455
SJ2881
pob
5128.
66.32
1.293
Be3130
ppb
515.2
10.08
1.956
Cu3247
ppb
519,5
5.169
.995
Mo2020
ppb
502.6
6.977
1.388
Sb2068
ppb
523.8
9.367
1.788
Sr4215
ppb
509.7
2.521
.4947





-------
Analysis  Report      Averages
Fri  11-07-97 10:29:32 AM    page 15
Method:  TRIAHGL2   Sample Name: ICB/CCB                Operator: SRB
RunTime:  11/07/97 10:15           Filename: 110697
Mode:  CONC        Type: Q         Corr. Factor:        1.00000
Lab ID.:           Cast. Sop 1.  ID.:            Cust.  ID.: 43452
El eras
Units
Avge
SDev
XRSD
Eiens
Units
Avge
SDev
3R3D
Eieins
Units
Avge
SDev
XRSD
5 leas
Units
Avge
SDev
SRSD
El ens
Units
Avge
SDev
XRSD
El ems
Units
Avge
SDev '
XRSD
Ag3230
ppb
.1580
.64
405
Ca3179
ppb
-.2391
1.732
598.9
Fe2714
ppb
-31.57
25.41
79.48
Na33C2
ppm
.0356
.1696
475.9
1960-1
ppb
1.701
2.58
151.7
TJ3349
ppb
-.5628
.4387
77.95
A13032
ppb
-42.57
9.814
23.06
Cd2265
ppb
-.3523
.2483
70.49
K.7664
ppffi
-.2328
.0417
17.91
NJ2316
ppb
-1.205
1.202
99.77
1960-2
ppb
.2326
2.636
1133
T11S08
ppb
-.4746
3.686
776.7
Asl890
ppb
-1.990
.3305
16.61
Ce4186
ppb
Q-3.444
1.224
35.53
LJ6707
ppb
-.6341
.0818
12.91
PJ149
ppb
-12.49
7.853
62.9
Pb2203
ppb
-.3035
1.72
566.5
VJ924
ppb
Q-3.342
1.127
33.71
B.2496
ppb
-1.313
1.442
109.3
Co2286
ppb
Q-1.212
1.327
109.4
Mg2790
ppb
-13.41
11.58
86.33
2203-1
ppb
.1911
3.683
1927
Sel960
ppb
.7215
1.546
214.3
Zn2062
ppb
-2.130
.6137
28.81
Ba4934
ppb
-.1866
.1973
105.8
Cr2677
ppb
-1.692
1.174
69.36
Hn2576
ppb
-.1681
.1649
98.12
2203-2
ppb
-.5505
4.341
788.5
Snl899
ppb
-2.748
.9602
34.95
Si2881
ppb
-44.60
1.913
4.238
Be3130
ppb
-.3757
.0716
19.05
Cu3247
ppb
.9688
1.146
118.3
»o2020
ppb
-.5215
.5275
101.1
Sb2068
ppb
-3.604
3.41
94.61
Sr4215
ppb
-.0910
.0812
89.26



-------
Analysis  Repor
Averages
Fri  11-07-?] 10:44:15 AM   page  112
Method: TR1ANGL2   Saaple Name: ICSAB   '              Operator;  SRB
Run Tint:  11/01/97 10:21           Filename:  110697
Mode:  COIJC         Type: Q         Corr. Factor:        1.00000
Lab ID.:           Cust. Sup I. ID.:            Cast. ID.:  43452
Elems
Units
Avge
SDev
SRSD
Elems
Units
Avge
SDev
5RSD
Elems
Dnits
Avge
SDev
SRSD
Elems
Units
Avge
SDev
SRSD
Elems
Units
Avge
SDev
SRSD
El ems
Units
Avge
SDev
SRSD
AgJ230
ppb
56!. 1
1.819
.3242
Ca3179
ppb
450800.
5181
1.149
Fe2?14
opt
'181400.
1586
.8745
Na3302
ppu
Q6.063
.2369
3.908
1960-1
ppb
564.7
19.57
3.433
TJ3349
ppb
510.4
2.694
.5279
A13082
ppb
533700.
2263
.42
Cd2265
ppb
477.5
4.237
.8874
KJ664
PPffl
Q26.I8
.6052
2.259
N12316
ppb
460.7
6.484
1.407
1960-2
ppb
534.3
7.748
1.45
T11908
pp'o
521.9
7.119
1.364
Asl890
pob
530.3
3.705
.6987
Ce4186
ppb
519.3
5.638
1.086
L16707
ppb
644.3
13.66
2.12
PJ149
ppb
578.1
35.12
6.074
Pb2203
ppb
502.1
6.174
1.23
VJ924
ppb
508.4
4.5
.8851
BJ496
ppb
541.0
1.654
.3058
Co2286
ppb
486.2
5.023
1.033
Mg2790
ppb
541400.
4933
.9204
2203-1
ppb
515.0
8.908
1.73
Sel960
ppb
544.4
6.614
1.215
Zn2062
ppb
453.1
5.194
1.146
Ba4934
ppb
537.9
.8804
.1637
Cr2677
ppb
486.3
5.431
1.117
Hn2576
ppb
468.1
3.359
.7177
2203-2
ppb
495.6
10.63
2.145
Snl899
ppb
530.4
1.939
.3655
SJ2831
ppb
5576.
40.85
.7327
Be3130
opb
"505.7
3.938
.7786
C«)247
ppb
"572.4
1.833
.3203
Mo2020
ppb
'506.0
1.417
.2799
Sb2068
ppb
545.3
2.6
.4768
Sr4215
ppb
"526.1
.9573
.182





-------
,     -,	  i-uau i r, g map
Element  File: fiS.GEL

Lbc.  Concentration
 1
 2
 4
 5
 6
 7
 a
 9
18
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
39
      50.8  ug/L
      180.8 ug/L
     ID/Weight File: EB178. IDW

Solut ions

Calib.  Blank / Diluent  /  ICB  /  CCB
Stock I-     "
Stock / Recovery Stock \~bH'if
ICV=38 ug/L
CCV=68
CHECK LO
43452 MB
43452 LCS
                             135-26 -3D
                             185-26-40^^
                             1 85-26 -fcD/
                             185-26-7CD
                             185-26-8DE
                             1S5-26-9D
                                                                   fq rf
                                                                ///«?/'
                   x
                    . ^^f,^//a85-26-4C'='-'-
                                         '
                             Modifier 1
-------
C. .1 is III £ I I t,  r-ij.tr.  n _j . u >_ i_
Element :  As
Print  Data:  Main+Suppl.
Print:  Calib.  Curve
Analyst: BENNETT
Peak Storage:  1 Repl./Sample
 INSTRUMENT:  4100 ZL
 Wavelength:  193.7 Peak
 Signal  Type:  Zeeman AA'
 Read Time: 5.0
 Sample  Replicates:  £
 Standard  Replicates: 2
Technique: HGA            Version:  7.30
Slit: 0.78 Low
Signal Measurement:  Peak  Area
Read Delay: 0.0           BOC  Time:  £

Spike Replicates: Same  as Sample
CALIBRATION:
Solutions 1 ID
1
Calib. Blank 1 STD BLK
Standard 1 1 STD 1 = £5 ug/L
Standard £ 1 STD £ = 50 ug/L
Standard 3 1 STD 3 =100 ug/L
Reslope Std. 150 ug/L
Cone 1 Location
1
— 1 (7l

£5.01 1
50.01 1
100.01 £
50.0! 1
	 1 	
Volume

10
5
10
10
10
1 I7l
Di luent
Volume
5
10
5
5
5
<*.
Modifier!
#1
5
5
5
5
5
=;
tt£





 Diluent Location:  0
 Modifier #1  Location:  39
 Calibration  Units: ug/L
 Calibration  Type:  Nonlinear
Modifier #£ Location:
Sample Units: ug/L
Furnace Time/Temperature Program:
SteplTemp
1 1 110
£ 1 130
3 ll£00
4 !£100
5 l£500
Injection
Ramp
5
1
5
0
1
Temp:
Hold
35
35
30
5
5
Gas Flow
£50
£50
£50
0
£50
Read



*

Gas Type
Norm
Norm
Norm
Norm
Norm






£0 Pipette Speed: 85* Extraction System: On
SEQUENCE:
Step  Action and Parameters
   1    Pipet diluent + modifier
   £    Run HGA  steps 1 to End
spike •+• sample/std
CHECKS:
Recalibration Type: Reslope
Locations: None

Cone. Above Calibration Action: Dilute  &  Reanalyze  After'l Rep
Alternate Sample Volumes   £0.0      and Concentration > 3.3       then Retry 1  times
Check '/.RSD on: Samples + Standards  + Spikes  +  QC  Samples

Recovery Measurements:
5  uL of 100 ug/L Standard at Location  £  Gives      50.0 ug/L
Measure Recovery on Samples: 9, 10,£1,££
Add to QC Samples: Yes              % Recovery Limits:  85 to 115
-------
uu,:
#•!• A/S  I   QC Sample    I     Cone.  Limits      I AfterI PeriodicI At  ICount  As I
 I 'Loc.I      ID        I   Lower     Upper    ICalibl   Check  lEnd!  Sample  I
1   ' A   ICV=30  ug/L      £7.0       33.0
2    0   ICB              -3.3       3.3
3    5   CCV=60  ug/L      48.0       7£. 0
4    0   CCB              -3.3       3.3          X              X
Run Periodic QC Samples:  Every  10
Out of  Limit Action:  Reslope and  Rerun Samples

Matrix  Check Calculations:
•/. Difference for  Dupls:  No     Locations:
% Recovery for  Spike:  No       Locations:         Cone:
-------
As     ID:  STD ELK            Seq. No.: 00001    A/S Pos. :  0     Dates ii/06/9V

uL dispensed: 5 from 0,  5 from 39, IB from 0
Replicate   1                            Time: 09:36
Peak  Area  (A-s):  0.004                 Peak Height  (A):  0. 01£
Background Pk Area (A-s): 0.033        Background Pk  Height (A):  0.058
Blank Corrected Pk Area  (A-s): 0.006
Concentration 
-------
st.a   ~ -  .-''..-•=.  _ ..pp.ied.   C£5. 03
Correlation  coefficient: 1.00000       Slope: 0.0011
                                          ^^^A,^^^
fts     ID:  STD  £ = 50 ug/L    Seq. No. : 00004    ft/S  Pos. :  1      Date:  11/0&/97

uL dispensed:  5 from 0, 5 from 39, 10 from 1
Replicate   1                            Time: 09:55
Peak flrea  (fl-s): 0.059                 Peak Height  (fl) :  0.166
Background Pk  ftrea (fl-s): 0. 03£        Background Pk  Height  (ft):  0. 06£
Blank  Corrected Pk Area   : 0.057
Concentration   : 0.056                 Peak Height  (ft):  0.154
Background Pk  ftrea (fl-s): 0.033        Background Pk  Height  (ft):  0.063
Blank  Corrected Pk Area  (fl-s): 0.054
Concentration  (ug/L  ): 47.4

Mean Cone   (ug/L  ):       48.5        SD: 1.56                 RSD(*): 3. £1

Standard number £ applied.   C50. 03
Correlation coefficient: 1.00000       Slope: 0.001£


fls     ID:  STD  3 =100 ug/L    Seq. No.: 00005    ft/S  Pos.:  £      Date:  11/06/97

uL dispensed:  5 from 0, 5 from 39, 10 from £
Replicate   1                            Time: 10:0£
Peak flrea  (fl-s): 0.113                 Peak Height  (fl) :  0. 3£8
Background Pk  ftrea (fl-s): 0.033        Background Pk Height  (ft) :  0.065
Blank  Corrected Pk flrea  (fl-s): 0.111
Concentration  (ug/L  ):  106. £

uL dispensed:  5 from 0, 5 from 39, 10 from £
Replicate   £  (Peak Stored)             Time: 10:05
Peak flrea  (fl-s): 0.113                 Peak Height  (fl) :  0.344
Background Pk  flrea (fl-s): 0. 03£        Background Pk Height  (fl) :  0.068
Blank  Corrected Pk flrea  (fl-s): 0.111
Concentration  (ug/L  ): 106.3

Mean Cone   (ug/L  ):      106.3        SD: 0.10                 RSD ('/-): 0.09

S-shaped calibration curve detected.  £-coef. equation used.
Standard number 3 applied.   [100.03
Correlation coefficient: 0.99990       Slope: 0. 001£
-------

 As
      ID:  ICV=30  ug/L
Seq.  No. :  00006
                   A/S Pos. :  4
Date: 11/06/971
 uL dispensed:  5 from 0,  5 from 39, 18 from 4
 Replicate  1                           Time: 10:14
 Peak  Area :  0.034                 Peak Height  (A): 0.108
 Background Pk  Area (A-s): 0.031        Background Pk Height   :  0. 0&4
 Blank Corrected Pk Area  (A-s): O. 03£
 Concentration  -------
Mea           =. _  , .        -l.£        3D: 0.90                 RSDC/O:  74. £5

QC sample  is  within  range -3.3 - 3.3
                                        t^f^t^t^i^i\i^^
As     IDs  CHECK LO           Seq. No.: 00008    A/S Pos. : 6      Date:  11/06/9

uL dispensed:  5 from 0,  5 from 39,  10 from 6
Replicate   1                            Time: 10:£7
Peak Area  (A-s):  0.004                 Peak Height  (A):  0. 01S
Background Pk  Area (A-s): 0.034        Background Pk Height  (A):  0. 06&
Blank  Corrected Pk Area -------
Mean Cone   M.ig/L  ;

*\f 'V *V "»* *V *V *\* *V *"v *%*• A* *\* *\* 'W A/ *\f *V *V *V *"
As  '  ID: 43452 LCS
                            -W.
                                        bL>: 1.1'?
                                                                          61.1i.-.
                              Seq. No.: 00011    A/S Pos. :  8
                                                                                I
                                                                                (H
                                                                  Date: 11/06/9J
uL dispensed: 5  from  0,  5 from 39,  10 from B
Replicate   1
Peak Area  (A-s) :  0.044*
Background  Pk  Area  (A-s) :  0.037
Blank Corrected Pk  Area  :  37.1

uL dispensed:  5 from  0,  5  from  39, 10
Replicate   2   :  0.047
Concentration   :  0.160
                                        Background Pk Height  
-------
 n c si   N^.-- -
 Cor. =V.WBU  cone (ug/L  ): £81.
                  * *\* *V *\* *\* *\* «\* A*
            W--5Z-V2v
 As     ID:r>ia5-2&-lCj=HPi>S  c-tf  Secl-  No- :  0®015    ft/S Pos. : 9     Date:  11/06/9.
            .
 uL dispensed:  8 from 0, 5  from  39,  5 from £,  2 from 9
 Replicate   1                            Time:  11:8&
 Peak flrea   &t
  uL  dispensed: 5 from 0, 5  from  39,  10 from 10
I  Replicate   1                            Time: 11:12
I  Peak  ftrea  (ft-s): 0.062                  Peak Height (ft): 0.088
  Background Pk ftrea  (ft-s):  0.296        Background Pk Height  (ft):  0.221
I  Blank Corrected Pk flrea  (fl-s):  0.060
  Concentration (ug/L  ): 53.4

  IuL  dispensed: 5 from 0, 5  from  39,  10 from 10
  Replicate   S (Peak Stored)              Time: 11:15
  Peak  flrea  (fl-s): 0.065                  Peak Height (fl) : 0.085
  Background Pk flrea  (fl-s):  0.297        Background Pk Height  (fl) :  0.238
I  Blank Corrected Pk flrea  (fl-s):  0.063
  Concentration (ug/L  ): 55.8

I  Mean  Cone   (ug/L  ):       54.6        SD: 1.71                 RSDC/):  3.13

  ^^^^^^^^^^-y^^^^^^^^^^^A,^^^^^^
,  fls     ID :^A 85-26- 1CVL         Seq.  No. :  00017    fl/S Pos. : 10    Date:  11/06/97
  uL dispensed:  5 from 39, 5  from  2,  10 from 10
  Replicate   1                             Time:  11:19
  Peak  flrea  (fl-s): 0.121                  Peak Height (fl) : 0.172
  Background  Pk  flrea  (fl-s): 0.293         Background Pk Height  (ft):  0.212
  Blank  Corrected Pk flrea  (fl-s): 0.119
  Concentration  (ug/L  ):  108.5

  uL dispensed:  5 from 39, 5  from  2,  10 from 10
  Replicate   2  (Peak Stored)              Time:  11:22
  Peak  ftrea  (fl-s) : 0. 123                  Peak Height (fl) : 0. 161
  Background  Pk  flrea  (fl-s): 0.275         Background Pk Height  (fl) :  0.230
  Blank  Corrected Pk flrea  (fl-s): 0.121
-------
i_. o n c e n t r a 'c i o n  ^ u g /1_  > : 11 v.<. H                                                    ^

Mean Cone   (ug/L  ):      189.4         SD: 1.31                 RSD(%):  1 • £®   I

Recovery is  189.fr'/i

*V *V *V A* *\* *\* *\* A/ *V *%/ *V *\* A/ f\f *\* *\/ *X» *V *V *V «V *\* *\/ *V I/ *\* *V *V *V *V *V *V *V *V *V *\* *V *\* *V *V *\* *V *V *\* A/ *\* «v^*V A*'\**V'V'V'V*V'W'\**VJV*V'W'V'V'\**\*'\*'V'V*%*'\**V: 8.834         Background Pk Height (ft): 8.861
Blank Corrected  Pk ftrea 5
Concentration  (ug/L  ): 58.1

uL dispensed:  5  from 8,  5 from 39,  18 from 5
Replicate   £  (Peak Stored)              Time: 11:28
Peak flrea  (fl-s): 8.868                  Peak Height  (ft):  8.£83
Background  Pk  Area  (fl-s): 8.835         Background Pk Height (ft): 0.864
Blank Corrected  Pk ftrea (ft-s): 8.866
Concentration  (ug/L  ): 58.4

Mean Cone   (ug/L  ):       58. £         SD: 8.25                 RSD(5t):  8.44

QC sample  is within range 48.8 - 72.0
As     ID:  CCB                 Seq.  No. :  00819     A/S Pos. :  8      Date:  11/86/97

uL  dispensed: 5 from 8, 5  from  39,  18 from 0
Replicate   1                            Time:  11:32
Peak  Area  (A-s): 8.883                  Peak Height (A):  8.009
Background Pk Area  (A-s):  8.828        Background  Pk Height  (A):  8.066
Blank Corrected Pk Area  (A-s):  0.881
Concentration (ug/L  ): 8.5

uL  dispensed: 5 from 8, 5  from  39,  18 from 8
Replicate   2 (Peak Stored)              Time:  11:35
Peak  Area  (A-s): 8.880                  Peak Height (A):  0.018
Background Pk Area  (ft-s):  0.831        Background  Pk Height  (ft):  8.066
Blank Corrected Pk flrea  (ft-s):  -8.88£
Concentration (ug/L  ): -1.6

Mean  Cone   (ug/L  ):       -8.5        SD: 1. 48                 RSD ('/.): £78.98

QC  sample  is within range  -3.3  -3.3
                                                                                 I
As     ID:  1 85-26 -2C Plf       Seq.  No.:  88828     A/S Pos.: 11     Date:  ll/86/97

uL dispensed:  5 from 8,  5 from  39,  18 from 11
Sample abs.  is greater than that  of the largest  standard.
Replicate   1                             Time:  11:38
Peak Area  (A-s): 8.348                  Peak Height  (ft):  £.513
Background  Pk  Area (A-s): 8.871         Background Pk Height  (A):  0.889
Blank Corrected Pk Area (A-s):  8.846
Concentration  (ug/L  ):  1099.8
                                                                                 'y
                                                                                 •
                                                                                 |
-------
As     ID:  1S5-26-2C          Seq.  No.: 00021    ft/S  Pos. :  11     Date:  11/06/9
uL dispensed:  10 from 0,  5 from 39, 5 from  11
Sample abs.  is greater than that of the largest  standard.     /l/-   r, ff ^ /
Replicate   1                            Time:  11:41
Peak ftrea  (A-s): 0.455                 Peak Height  (ft):  0.779
Background  Pk  Area (A-s): 0.616        Background Pk  Height  (A):  0.539
Blank Corrected Pk Area : 478.9          Corrected Cone  ^3/                          *-"£/,*/?>
uL dispensed:  13  from 0,  5 from 39, 2 from  11
Sample  abs.  is greater than that of the  largest standard.
Replicate   1                            Time:  11:44
Peak Area  (A-s):  0.215                 Peak Height  (A):  0.379
Background  Pk  Area  :  0.528        Background Pk Height  (A):  0.500
Blank  Corrected Pk Area (A-s): 0.213
Concentration  (ug/L  ): 201.6          Corrected Cone  »ia5-2&-2CRt>f /£>     Seq. No.: 00023    A/S  Pos.:  11     Date:  11/06/9'
uL dispensed:  14 from 0,  5 from 39, 1 from  11
Replicate   1                            Time:  11:47
Peak Area   : 0.089                 Peak Height  (A):  0.111
Background  Pk  Area (A-s): 0.381        Background Pk  Height  (A):  0.301
Blank  Corrected  Pk Area (A-s): 0.087
Concentration  (ug/L  ): 78.4           Corrected Cone (ug/L   >:  784.

uL dispensed:  14 from 0,  5 from 39, 1 from  11
Replicate   2  (Peak Stored)             Time:  11:50
Peak Area  (A-s): 0.098                 Peak Height  (A):  0.119
Background  Pk  Area (A-s): 0.408        Background Pk  Height  (A):  0.314
Blank  Corrected  Pk Area (A-s): 0.096
Concentration  (ug/L  ): 86.5           Corrected Cone (ug/L   ):  865.

Mean Cone   (ug/L  ):        82.4        SD:  5.78                 RSDC/.):  7.01
Corrected Cone (ug/L   ) :  824.
As     ID:  185-26-3C          Seq. No.: 00024    A/S  Pos.:  12     Date:  11/06/97
                                                  'n^t   6t^^      y
uL dispensed:  5 from 0,  5 from 39,  10 from  12                  &  ,tl,3lS-7
Sample  abs.  is greater than that of the largest standard.
Replicate   1                            Time: 11:53
Peak Area  (A-s):  0.625                 Peak Height  (A):  1.237
Background  Pk  Area (A-s): 0.735        Background Pk Height  (A): 0.697
Blank Corrected Pk Area (A-s): 0.623
Concentration  (ug/L  ):  715.8


As     ID:  185-26-3C          Seq. No.: 00025    A/S  Pos.:  12     Date:  11/06/97

uL dispensed:  10 from 0,  5 from 39,  5 from  12             r\A    w^-J
Sample  abs.  is greater than that of the largest standard.
Replicate   1                            Time: 11:56
-------
Peak Area  m-s) :  $. 3b4                  Peak  Height
Background  Pk  Area : 0.371        Background Pk Height  (A): 0.278
Blank Corrected Pk Area  (A-s): 0.074
Concentration  (ug/L  ): 66.6           Corrected Cone  (ug/L  ): 666.

Mean  Cone   (ug/L  ):        66.3        SD :  0.37                RSD<#):  0.56   '
Corrected Cone (ug/L   ) :  663.

r\ti^'^f\^f^t\f'\ff^'\rt\t»^'\f*\f*^l^'^'^t^f\tt^e^'^
As     ID:A 1S5-2&-4C          Seq. No.: 00028     A/S Pos.: 13    Date:  11/06/97
 / g*-Sl - fj id,            <** X*-^'' '/-"^                                             ,
uL dispensed:  5 from  0, 5 from 39, 10 from  13                                   I
Replicate   1                            Time:  12:09                             '
Peak  Area  (A-s): 0.056                 Peak Height (A): 0.088
Background  Pk  Area (A-s)  : 0. 147        Background Pk Height  (A) : 0. 139         I
Blank Corrected Pk Area  (A-s): 0.054                                            I
Concentration  (ug/L  ): 48.2

uL dispensed:  5 from  0, 5 from 39, 10 from  13                                   j
Replicate   2  (Peak Stored)             Time:  12:12
Peak  Area (A-s): 0.059                 Peak Height (A): 0.089                  i
Background  Pk  Area (A-s)  : 0. 147        Background Pk Height  (A) : 0. 127
Blank Corrected Pk-Area  (A-s): 0.057
Concentration  (ug/L  ): 50.6

Mean  Cone   (ug/L  ):        49.4        SD :  1.73                RSD(?O:  3.50   «
As    ID:A185-26-5C          Seq. No.: 00029     A/S Pos.: 14    Date:  11/06/97)
     ltf-$3-lljMj      £* /S>»SttIizk->
uL dispensed:  5  from 0,  5 from  39, 10 from  14                                   .
-------
K e P •
Peak Area  (A-s):  0.068
Background  Pk  Area (A-s):  3. 137
Blank Corrected  Pk Area -------
As     ID:A185-£6-6C F       ^Seq.  No.: 0003£    A/S  Pos. :  15    Date: 11/06/9'
uL dispensed:  5 from 0,  5 from 39,  1® from 15
Replicate   1                            Time: 1£: 34
Peak Area  (A-s>:  0. 0£3                 Peak Height  (A):  0.049
Background  Pk  Area (A-s^) : 0.079        Background Pk  Height  :  0. 065
Blank Corrected Pk Area* : £5.76 j


As     ID:A185-£6-8E Ft4       Seq.  No.: 00034    A/S Pos.:  17    Date: 11/06/9JJ
        --                        <-                                           •
uL dispensed:  5 from 0,  5 from 39,  10 from 17
Replicate   1                            Time: 1£:47
Peak Area  (A-s):  0. 0£8                 Peak Height  (A):  0.064
Background  Pk  Area (A-s):  0.509        Background Pk  Height  (A):  0.408
Blank Corrected Pk Area  (A-s): 0. 0£6
Concentration  (ug/L  ):  ££.9

uL dispensed:  5 from O,  5 from 39,  10 from 17
Replicate   £  (Peak Stored)              Time: 1£:50
Peak Area  (A-s):  0. 0£4                 Peak Height  (A):  0. 05£
Background  Pk  Area (A-s):  0. 48£        Background Pk  Height  (A):  0.444
Blank Corrected Pk Area  (A-s): 0. 0££
Concentration  (ug/L  ):  19.1

Mean Cone   (ug/L   ):        £1.0        SD: £.70                 RSD(%): 1£.86
-------
As    iU:  185-26-SH £#  .^  !)  Seq.  No. :  00035    ft/3 Pos. :  13     Date:  11/06/9"
                         "' /Zf ,,/
fls     ID:  185-26-9C          Seq. No.: 00037    fl/S Pos.:  19     Date:  11/06/97
uL dispensed:  10 from 0,  5 from 39, 5 from 19
Sample abs.  is greater than that of the largest standard.      /S^*—*   i  )
Replicate   1                            Time: 13:03                   ////3/'?"7
Peak flrea  (fl-s): 0.469                 Peak Height  (ft):  0.758
Background  Pk  flrea (fl-s): 0.568        Background Pk Height  (ft):  0.465
Blank Corrected Pk flrea  (fl-s): 0.467
Concentration  (ug/L  ): 496.3          Corrected Cone  (ug/L   ):  992.7
fls    ID:  185-26-9C          Seq.  No. :  00038    A/S Pos. :  19     Date:  11/06/97

uL dispensed:  13 from 0,  5 from 39,  2 from 19
Sample abs.  is  greater than that of the largest standard.
Replicate   1                            Time: 13:06
Peak flrea  (A-s):  0.209                 Peak Height  (ft):  0.295
Background  Pk  ftrea (ft-s): 0.482        Background Pk Height  (ft): 0.396
Blank Corrected  Pk ftrea (ft-s):  0.207
Concentration  (ug/L  ): 195.9          Corrected Cone  (ug/L   ):  979.
                             A* *\f *\/ *\/ *
fls     ID:AlS5-26-9C tftV/£>     Seq.  No.: 00039    fl/S Pos. :  19     Date: 11/06/97
                                   7
uL dispensed:  14 from 0,  5 from 39,  1 from 19
Replicate   1                            Time: 13:09
Peak flrea  (ft-s): 0.092                 Peak Height  (ft):  0.132
Background  Pk  flrea (fl-s): 0.372        Background Pk  Height  (A): 0.303
-------
Blank  Corrected Pk Area   :  0.090
Concentration (ug/L  ): 81.0            Corrected Cone  (ug/L  ): 810.

uL dispensed: 14 from 0, 5  from 39,  1 from 19
Replicate   £ (Peak Stored)              Time: 13:12
Peak Area  (A-s): 0.100                  Peak Height  (A):  0.138
Background  Pk Area (A-s,): 0.379        Background Pk Height 
-------
Cor
                ,.a,,_
                      , : 56. 6
uL Dispensed:  5 from 39, 5 from £,  10 from £1
Replicate   £ (Peak Stored)             Time:  13:3£
Peak flrea  (ft-s):  0.056                 Peak Height  (ft):  0. £06
Background  Pk  ftrea (fl-s) : 0. 03£        Background Pk Height  (ft):  0.049
Blank Corrected Pk Area A.z: 199.86
                                                           £2
                                                                  Date: 11/06/97
-------
                                         i j. IM t_- i
Peak  Area (A-s): -0.001                 Peak  Height  (A):  0.007
Background Pk Area  (A-s): i3. 03&         Background Pk  Height (A): 0. 068
'Blank Corrected Pk Area  (A-s) : -0.003
Concentration (ug/L  >:  -£.5

uL  dispensed: 5 from 0,  5 from 39,  10  from ££
Replicate  £ (Peak Stored)              Time:  13:51
Peak  Area (A-s): 0. 00£                  Peak  Height  (A):  0.009
Background Pk Area  (A-s): 0. 038         Background Pk  Height (A): 0.069
Blank Corrected Pk Area  (A-s): 0.000
Concentration (ug/L  ):  3.0

Mean  Cone  (ug/L   ):       -l.S         SD: 1.74                 RSDC/O:  14£. 63
                      *V A/ A* A* *
 As     ID:  185-£6-lD L        Seq. No. : 00046     A/S Pos. :  ££    Date:  11/8&/97

 uL  dispensed: 5 from 39, 5 from £,  10 from ££
 Replicate   1                           Time: 13:55
 Peak Area  (A-s): 0.048                 Peak Height  (A):  0.174
 Background Pk Area (A-s): 0.037        Background Pk Height (A): 0.061
 Blank Corrected Pk Area  (A-s): 0.046
 Concentration (ug/L  ): 41.0
 uL dispensed: 5 from 39, 5 from £,  10  from ££               /
 Replicate  £ (Peak Stored)             Time: 13:58                             j
 Peak Area (A-s): 0.054                 Peak Height  (A):  0.184
 Background Pk Area (A-s): 0.031        Background Pk  Height (A): 0.065        .
 Blank Corrected Pk Area  (A-s): 0.05£                             .             'I
 Concentration (ug/L  ): 46.4                                                   "

 Mean Cone  (ug/L  ):        43.7        SD: 3.80                 RSD(*): 8.70   J

 Recovery is 89.9%
 As     ID:  185-£6-£D/»?##    /< .  Seq. No.: 00047     A/S  Pos.:  £3    Date: 11/06/97

 uL  dispensed:  5 from 0,  5 from 39, 10 from £3                                  I
 Replicate   1                            Time: 14:01
Repli
Peak Area  (A-s):  0.0£4                 Peak Height (A): 0.05£
Background Pk Area  (A-s) :  0.178        Background Pk Height  (A) :  0.13£       I
Blank Corrected Pk  Area (A-s):  0.0££                                          I
Concentration  (ug/L  ): 19.4

uL dispensed: 5 from  0,  5  from  39,  10 from £3                                 I
Replicate  £  (Peak  Stored)              Time: 14:04
Peak Area  (A-s):  0.0£0                 Peak Height (A): 0.051                 I
Background Pk Area  (A-s):  0.18£        Background Pk Height  (A):  0.13£       I
Blank Corrected Pk  Area (A-s):  0.018                                          '
Concentration  (ug/L  ): 15.7

Mean Cone  (ug/L  ):        17.5        SD: £.63                 RSDCX): 15.01  |
As     ID:  185-£6-3D          Seq. No.: 00048    A/S  Pos.:  £4    Date:

uL dispensed:  5 from 0,  5 from 39, 10 from £4
-------
RejL         _                             Time:  14:03
Peak Area  (A-s) :  0.010                  Peak  Height (ft):  0.026
Background Pk Area (A-s): 0.047         Background Pk Height (A): 0.061
Blank Corrected  Pk Area  (A-s) : 0.003
Concentration -------
Background  Pk  Area (H-SJ: id. ^4-        Background  Pk  Heiar.s 'i--m — •»— ;r.-j- ,-
Blank Corrected Pk flrea  (fl-s): 0.000
Concentration  (ug/L  ): 0.0

uL dispensed:  5 from 0, 5 from 39,  10  from £6
Replicate   £ (Peak Stored)             Time:  14:30
Peak flrea  (fl-s) :  0. 00A .               Peak Height (ft):  0. 01£
Background  Pk  Area (fl-s): 0.041        Background  Pk  Height (ft): 0. 0&3
Blank Corrected Pk flrea  (A-s): 0. 00£
Concentration  (ug/L  ): 1.7

Mean Cone   (ug/L   ):         0.9        SD: l.£l                 RSDC/):  137.16
fls     ID:  185-£&-&D ^ /• x/  Seq. No.: 0005£     fl/S  Pos. :  £7    Date:  11/06/9"
 uL  dispensed:  5 from 0, 5 from 39, 10 from £7
 Replicate   1                            Time: 14:33
 Peak  ftrea  (fl-s) :  0. ©01                 Peak Height  
-------
  uL'dispensed: 5 from 0,  5  from  39,  10 from 29
  Replicate  2  (Peak Stored)              Time:  14:49
  Peak  Area (A-s): 0.004                  Peak Height (A): 0.014
  Background Pk Area  (A-s):  0.036        Background Pk Height  (A): 0.069
  Blank  Corrected Pk Area  (A-s):  0.002
  Concentration ^   ,Seq.  No.:  00057    A/S Pos.: 30     Date:  11/06/97
  uL dispensed: 5 from 0,  5  from  39,  10 from 30
  Replicate  1                            Time:  15:05
  Peak Area (A-s): 0.001                  Peak Height (A): 0.009
-------
Blank Corrected  Pk  Area (ft-s): -0.001
Concentration  (ug/L  ): -0.6

uL dispensed:  5  from 0,  5 from 39,  10 from 30
Replicate   £ (Peak  Stored)              Time: 15:08
Peak Area  (A-s):  0.001                  Peak Height  (A): 0.008
Background  Pk  Area  (A-s)-: 0. 032        Background Pk Height  (A):  0.053
Blank Corrected  Pk  Area (A-s): -0.001
Concentration  (ug/L  ): -1.0

Mean Cone    : 0.013
Background  Pk  flrea 
-------
Ba.
               i-ir-ea
                            0. 024
Bl-ank  Corrected Pk  Area (A-s): -8. 082
Concentration  /vJJV.*vJA[JJ'linir^i ~M ii || U \r "ir ^r "i r "ir^r * -*—»-•*•-«• -^ -*^* --

As     ID:  CCB                 Seq.  No.: 00066
                                                -Jv- -»--^ -J»..

                                                   A/S Pos.:  8
                                                                    Date: 11/06/97
uL dispensed: 5 from  0,  5 from 39,  18  from  0
Replicate  1                            Time: 15:52
Peak  Area (A-s): 8.882                 Peak Height  (A):  8.008
Background Pk Area  (A-s): 0.018        Background Pk Height  (A): 0. 0S6
Blank Corrected Pk  Area  (A-s): -0.088
Concentration (ug/L  ):  -8.4

uL dispensed: 5 from  8,  5 from 39,  18  from  8
Replicate  £ (Peak  Stored)              Time: 15:55
Peak  Area (A-s): -8.881                 Peak Height  (A):  8.808
Background Pk Area  (A-s): 8.888        Background Pk Height  (A): 8.817
Blank Corrected Pk  Area  (A-s): -8.883
Concentration (ug/L  ):  -£.4
Mean Cone  (ug/L   ):        -1.4        SD:  1.42

QC sample is within range -3.3 - 3.3
                                                                   RSDC/O: 98.77
-------
fv.-tt osampi er Loading  Map
 > Element File: COflSA.GEL

  Loc.  Concentration
0
1
2
6
7
a
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
40

25.0 ug/L
50.0 ug/L



"If
/
/
/
/
~x
\















        ID/Weight File: EB179.IDW

   Solutions

   Calib.  Blank / Diluent
   Stock
   Stock
   CHECK  LQ
   43452  MB
   43452  LCS
£-, 135-26- 1C
,2-^185-26-1C  L
3,4,185-26 -£C
5,t,lS5-26-3C
9,10,185-26-4C

      -26-feC
                                  -£6-8E
                               185-£6-8H
                              1S5-2&-10C
                              185-2&-lDBff
                              185-26-lDfiL
                               185-26-3D
                               1S5-26-4D
                               185-26-5D
                               185-26-6D
                               185-26-7CD
                               1S5-2&-SDE 6 14
                               185-26-9 D^B Jf
                               185-26-10D  ~"
                               Modifier 1
-------
E-lement: Co
Pr'irrt Data: Main+Suppl.
Print: Calib. Curve+Elem. Params.
Remarks:
 CALIBRATION STDS PREPPED FROM £-100-4
 CHECK STDS PREPPED FROM £-88-3
     Analyst: Bennett
     Peak Storage:  1 Repl./Sample
INSTRUMENT: 4100 ZL
Wavelength: £40.7 Peak
Signal Type: Single Beam
Read Time: 3.0
Sample Replicates: £
Standard Replicates: £
     Technique: HGA           Version: 7-30
     Slit: 0.£0 Low
     Signal Measurement: Peak Area
     Read Delay: 0.0          BOC Time: £

     Spike Replicates: Same as Sample
CALIBRATION:
Solut ions

_ t - • . n 1 I
Lai ID. Blank
Standard 1
Standard £
O ^ •*• r-k 1 B B

ID

G~TT% Ql ANIL/
o 1 U t>UHNrS
ADD1=£5PPB
ADD£=50PPB

Cone



£5.0
50. 0

Locat ion



1
£

Volume

4 |7|
IV)
10
10
1 l7l

Diluent
Volume
4 iTl
1 W

1 I7l

Mod 3
#1
^i
5
5
5
er

L f ier
tt£




 Diluent Location: 0
 Modifier #1 Location: 40
 Calibration Units: ug/L
 Calibration Type: Method of Add.
     Modifier #£ Location
     Sample Units: ug/L
Furnace Time/Temperature Program:
Stepl Temp
1 1 110
£ 1 130
3 11400
4 1 £400
5 l£500
Inject ion
Ramp Hold
1 £0
1 £5
5 £0
0 4
1 5
Gas Flow
£50
£50
£50
0
£50
Read



*

Gas Type
Norm
Norm
Norm
Norm
Norm






Temp: £0 Pipette Speed: 100% Extraction System: On
SEQUENCE:
Step  Action and Parameters
  1    Pipet diluent + modifier
  £    Run HGA steps 1 to End
     spike + sample/std
CHECKS:
Additions Preparation: Automated
Periodic Autozero Locations: All Samples
QC:
Matrix Check Calculations:
'/• Difference for Dupls: No
'A Recovery for Spike: No
Locat i ons:
Locat ions:
Cone:
-------
Element  File:  COMSA.GEL
Date:  11/07/97
Data File:  EB179.DAT
Technique:  HGA
                              Element: Co
                              Time:  13:35
                              ID/Wt  File: EB179.IDW
                              Calib.  Type: Method  of  Add.
                                                             Wavelength: £40.7
                                                             Slit:  0.20 L
                                                             Lamp Current : 30
                                                             Energy:  49
Remark  1:  CALIBRATION STDS PREPPED FROM £-100-4
Remark  £:  CHECK STDS PBEPPED FROM £-88-3
Co
       ID:  STD  BLANK
                             Seq.  No.:  00078    A/S Pos.: 0
 uL  dispensed:  10 from 0,  5 from 40, 10 from 0
 Replicate   1                            Time: 13:37
 Peak  Area  (A-s): 0.011                 Peak Height  (A):  0.030
 Blank Corrected  Pk Area (A-s): 0.004

 uL  dispensed:  10 from 0,  5 from 40, 10 from 0
 Replicate   £  -------
Bis
                      ;a tfi-s> :
uL dispensed:  5 from 40,  10 from 2, 10 from E'l
Replicate   £ (Peak Stored)              Time:  13:55
Peak flrea  (fl-s):  0.207
                                        Peak Height  (fl) :  0.212
Blank Corrected Pk flrea 
-------
Peak Area  :

Co    ID: ADD1=£5PPB
-0.000

     Seq. No.:
uL dispensed: 5  from  40,  10  from 1,  10
Replicate   1
Peak Area  (A-s):  0.109
Blank Corrected  Pk  Area  (A-s):  0.094

uL dispensed: 5  from  40,  10  from 1,  10
Replicate   £  (Peak  Stored)
Peak Area  (A-s):  0.111
Blank Corrected  Pk  Area  (A-s):  0.097
               Peak  Height
                from  ££
                Time:  14:05
                Peak  Height (A):  0.030
SD: 0.0003               R3DC/O: 5£7.27!

00084    A/S Pos. :  ££    Date:

from ££
Time: 14:07
Peak Height  (A):  0.11&
               from  ££
               Time:  14:10
               Peak  Height  (A):  0.115
                                                                         5£7. 27j

                                                                        11/07/97
Mean Pk Area  (A-s):

Co    ID: ADD£=50PPB
 0.096

     Seq. No.:
uL dispensed: 5  from  40,  10  from £,  10
Replicate   1
Peak Area  (A-s): 0.£06
Blank Corrected  Pk  Area  (A-s):  0.191

uL dispensed: 5  from  40,  10  from £,  10
Replicate   £  (Peak  Stored)
Peak Area  (A-s): 0.£04
Blank Corrected  Pk  Area  (A-s):  0. 190

Mean Pk Area  (A-s):       0.191

Co    ID:  ISS-Ee-lD^L     ;    ?eq.  No. :

Concentration (ug/L  ):  —0.0

Correlation coefficient:  0.99999
SD: 0.0019               RSDC/-)

00085    A/S Pos. :  ££    Date:

from ££
Time: 14:13
Peak Height  (A):  0. £05
                                        from ££
                                        Time: 14:15
                                        Peak Height  (A): 0. £01
                                        SD: 0.0009               RSDC/4)

                                        00083    A/S Pos. : ££     Date:



                                        Slope: 0.0038
                                                                         1.97

                                                                        11/07/97
                                                0.45

                                               11/07/9|
-------
                        Hlni«snlau Calihratinn  - C?\AA
                        1.

                                                    .
                                                «*.: d.»»»*
                                                .aoaa
                          0.0
                                   Concentration
                                                   30.0
Co
ID: STD BLflNK
Seq. No.: 80886

                                                 fl/S Pos.:  8
                                                                 Date:  11/87/9?
uL dispensed: 18  from  8,  5 from 48, 18
Replicate  1
Peak flrea   : 299.87
                              Seq.  No.:  88887
                   ii
Co    ID: 185-26-2D
uL dispensed: 10  from  0,  5 from 40, 10
Replicate  1
Peak flrea  -------
Blank Corrected  Pk  Area (A-s>:  0. S0c!
uL' dispensed:  5  from  40,  10 from i,  10 from £3
Replicate   £  (Peak  Stored)              Time: 14:30
Peak Area  :  0. £££                 Peak Height  (A):  0.£91
Blank Corrected  Pk  Area (A-s): 0.£03
                        *
Mean Pk Area  (A-s):       0.£05         SD:  0.004&

Co    ID:  ADD£=50PPB          Seq.  No. : 00089    A/S Pos. :  £3

uL dispensed:  5  from  40,  10 from £,  10 from £3
Replicate   1                            Time: 14:33
Peak Area  (fl-s):  0. £9£                 Peak Height   :  0. 33£
Blank Corrected  Pk  Area (A-s): 0.£78

uL dispensed:  5  from  40,  10 from £,  10 from £3
                                                                 RSDC/4) :  S. £7

                                                                  Date:  11/07/97
Replicate  £  (Peak  Stored)
Peak Area  (A-s): 0. £95
Blank Corrected Pk  Area  (A-s):  0.£8£

Mean Pk Area  (A-s):       0. £80

Co    ID:  185-£€>-£D 3H ^/    Seq.  No.

Concentration  (ug/L  ):  37.9

Correlation coefficient:  0.99781
                                        Time: 14:35
                                        Peak Height  (A):  0.337
                                        SD: 0.0023

                                        00087    A/S Pos.:  £3



                                        Slope: 0.003£
                                                                 RSDC/.) :  0. 81

                                                                  Date:  11/07/97
                        MJDisplay  Calibration - C;\flft
                                  0.2*0-,
                         -37. 9
                                   Concentration
                                                   30.0
                                                        II
Co
       ID:  STD BLANK
      Seq. No.: 00090

,  5 from 40,  10 from 0
A/S Pos.
                                                            0
uL dispensed:  10  from
Replicate   1
Peak Area  (A-s):  0.119
Blank Corrected Pk  Area (A-s):  0.106
                                        Time:  14:38
                                        Peak Height (A):
Date: 11/07/97
                                                          0. ££1
-------
ul_ c "-"•"'"           	 _i, -i Train  *+w,
Replicate   £ (Peak Stored)
Peak Area  (A-s): 0.060
Blank Corrected Pk Area  (A-s): 0.046

Mean Pk  Area (A-s):      0.076

Auto-zero  performed.
            1 V.I  I r • o III ti
               Time:  14:41
               Peak Height (A): 0.079


               SD:  0.04£0
I
Co
       A**V» *V *\/ *\*

ID: 185-£&-3D
    Seq. No. :  00091
                                                  A/S Pos. : £4
  IuL dispensed:  10 from 0,  5 from 40, 10 from £4
  Replicate   1
  Peak Area  (A-s):  0.093
  Blank Corrected  Pk  Area (A-s): 0.004
                                         Time: 14:43
                                         Peak Height : 0.104
 Blank Corrected Pk Area  (A-s): -0.003

 Mean Pk  Area (A-s):      0.000          SD: 0.0053

 Co    ID:  ADD1=£5PPB         Seq.  No. : 0009£    A/S Pos. : £4

 uL dispensed: 5 from 40, 10 from  1,  10 from £4
 Replicate   1                            Time: 14:48
 Peak Area  (A-s): 0.141                  Peak Height (A): 0.139
 Blank Corrected Pk Area  (A-s): 0.05£

 uL dispensed: 5 from 40, 10 from  1,  10 from £4
 Replicate   £ (Peak Stored)              Time: 14:51
 Peak Area  (A-s): 0.1£8                  Peak Height (A): 0.137
 Blank Corrected Pk Area  (A-s): 0.039
 Mean  Pk  Area (A-s):

 Co     ID:  ADD£=50PPB
0.045          SD:  0.0090

    Seq. No. :  00093    A/S Pos. : £4
 uL  dispensed: 5 from 40, 10 from £,  10 from £4
 Replicate   1                            Time: 14:53
 Peak Area  (A-s): 0.199                  Peak Height (A): 0.198
 Blank  Corrected Pk Area (A-s): 0.110
  IuL dispensed: 5  from  40,  10 from £,  10 from £4
  Replicate  £  (Peak  Stored)
I

J
  Peak Area  (A-s):  0. £01
  Blank Corrected  Pk  Area (A-s):  0.11£
 Mean Pk  Area (A-s):
0. Ill
                                         Time:  14:56
                                         Peak Height (A): 0.£10
                                  SD: 0.001£
 The  standard additions calibration  curve may not be linear.
 Co     ID:  185-£6-3D          Seq. No. :  00091    A/S Pos. : £4
  Concentration  (ug/L  ):  0.1

  Correlation coefficient:  0.97141
                                                                   RSDC/.) : 55.41
                                                                    Date: 11/07/9
                                       RSDC/4) :  19b8. 5£

                                        Dates  11/07/97
                                                           RSDC/4): 19.78

                                                            Date: 11/07/97
                                                                 RSDC/) :  1.09
                                                                    Date:  11/07/97
                                         Slope:  0.00£1
-------
                         "{Display Calibration - C:\ftftJ
                         L11-,
                                               of A44
                                             . C***.5
                                            ooa; fl.float
                          -ff.i
                                   Concentration
                                                    5O.0
 *\* *V A* *V *\* *\/ A* 'V *V *V A/
 Co
       ID:  STD BLflNK
                              Seq.  No.: 08894
A/S Pos.: 8
                          Date:  11/07/9"
uL dispensed:  10 from 8, 5 from 40, 10
Replicate   1
Peak  ftrea  (fl-s): 0.813
Blank Corrected Pk Area (A-s) : -8.076

uL dispensed:  18 from 0, 5 from 40, 18
Replicate   £  (Peak Stored)
Peak  Area  (A-s) : 0.81£
Blank Corrected Pk Area (fl-s) : -8.877
Mean  Pk  Area (A-s):

Auto—zero performed.
                         -8.877
                                         from 0
                                         Time:  14:59
                                         Peak Height (ft): 0.823
                                         from 0
                                         Time:  15:01
                                         Peak Height 
-------
  Blar
  uL'dispensed.: 5 from  40,  10  from  1,  18  from  £5
  Replicate  t:  (Peak  Stored)              Time:  15:12
  Peak ftrea (ft-s): ©.113                  Peak  Height (fl) :  0.115
  Blank Corrected Pk  flrea  (A-s): 0.101
  Mean Pk flrea :  0. 19£

uL dispensed: 5 from  40,  10  from  £,  10  from £5
Replicate  £  (Peak  Stored)
Peak flrea (fl-s): 0.196
Blank Corrected Pk  flrea  (fl-s):  0.183
                                       Time:  15:17
                                       Peak Height (fl):  0. 194
Mean Pk flrea (fl-s) :

Co    ID:  185-£6-4D0/f

Concentration (ug/L   ):  1.0

Correlation coefficient: 0.99816
0.187         SD: 0.006£
K
    Seq. No. : 00095    fl/S Pos. :  £5
                                        Slope:  0.0037
                                                                RSD (50 : 3.31

                                                                 Date: 11/07/97
                        "{Display Calibration - Ci
{  Co    ID: STD BLflNK          Seq. No. : 00098     fl/S Pos. :  0     Date: 11/07/97
I
uL dispensed: 10 from  0,  5  from 40,  10  from  0
Replicate  1                            Time:  15:£0
Peak flrea (fl-s): 0.011                  Peak  Height (fl):  0.0£3
Blank Corrected Pk  flrea  (fl-s): -0.001
-------
uL dispensed:  10  from  0,  b from 4-W,  iw
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0. 012
Blank Corrected Pk  Area (A-s):  -0.001
Mean Pk Area  (A-s):

Auto-zero performed.
                         -0.001
                                        tr-om w
                                        Time: 15:22
                                        Peak Height  (ft)
                                        3D:  0.0004
                                                         0.022
                     A* *W *\/ *V *V
Seq.  No.: 00099
Co    ID: 185-26-5D 8hl-
uL dispensed:  10  from  0,  5 from 40,  10
Replicate   1
Peak Area  (A-s):  0.056
Blank Corrected Pk  Area (A-s):  0.044

uL dispensed:  10  from  0,  5 from 40,  10
Replicate   2  (Peak  Stored)
Peak Area  (A-s):  0.053
Blank Corrected Pk  Area (A-s):  0.042
                                                 fl/S Pos. :  26
Mean Pk Area  (A-s):

Co    ID: ADD1=S5PPB
                          0.043

                              Seq.  No.:
uL dispensed: 5  from  40,  10 from 1,  10
Replicate   1
Peak Area  (A-s):  0.148
Blank Corrected  Pk  Area (A-s):  0.136

uL dispensed: 5  from  40,  10 from 1,  10
Replicate   £  (Peak  Stored)
Peak Area  (A-s):  0.148
Blank Corrected  Pk  Area (A-s):  0.136
Mean Pk Area  (A-s):

Co    ID: ADD2=50PPB
                          0. 136

                              Seq.  No. :
uL dispensed: 5  from  40,  10 from 2,  10
Replicate  1
Peak Area  (A-s): 0.232
Blank Corrected  Pk  Area  (A-s):  0.220

uL dispensed: 5  from  40,  10 from 2,  10
Replicate  £  (Peak  Stored)
Peak Area  (A-s): 0.234
Blank Corrected  Pk  Area  (A-s):  0.222

Mean Pk Area  (A-s):       0.221

Co    ID:  185-26-5D BM-    .   Seq.  No. :

Concentration (ug/L  ):  11.9

Correlation coefficient:  0.99834
                                        from 26
                                        Time: 15:25
                                        Peak Height (ft): 0.066
                                        from 26
                                        Time: 15:27
                                        Peak Height (A): 0.064
SD: 0.0015

00100    A/S Pos.:  26

from 26
Time: 15:30
Peak Height  (A):  0.155


from 26
Time: 15:32
Peak Height  (A):  0.151


SD: 0.0001

00101    A/S Pos.:  26

from 26
Time: 15:35
Peak Height  (A):  0.226
                                        from 26
                                        Time: 15:38
                                        Peak Height (A): 0.233
                                        SD:  0.0016

                                        00099    A/S Pos.: 26



                                        Slope:  0.0036
                                                                 RSDC/O: 36.71
                                                                  Date: 11/07/9

                                                                 RSDC/) :  3. 5b  I

                                                                  Date:  11/07/97
                                                                               1

                                                                               I

                                                                               I
                                                                RSDC/) :  0. 11

                                                                 Date:  11/07/97,
                                                 I
                                                                               1
                                                                               J
                                                                 RSD(%) :  0.71

                                                                  Date:  11/07/97
-------
 I
 I
 I
                           K iDianlau  Calihratinn - C :\AA_JJ •»
                               fl.iat-.
-M.»
          Concentration
                           50.0
J'i  ^/^ A**WA* A*A*Av AvA*A*A*Av^^ A*A* A* A* Av A* Av A* A* A* A^A/A* A*AvA**\» AvA* A>A> A»A* A* A* Av A* A* A* A* A^ A* A* A* Ay A* A*A*A*A* A*^ A*^

 * Co    ID:  STD BLflNK           Seq.  No. : 00102     fl/S Pos. : 0     Date:  11/07/97
   uL dispensed: 10 from  0,  5 from 40, 10 from  0
   Replicate  1                            Time:  15:40
   Peak flrea (fl-s): 0.017                 Peak  Height (fl): 0.028
   Blank Corrected Pk flrea (fl-s): 0.005

   uL dispensed: 10 from  0,  5 from 40, 10 from  0
   Replicate  2 (Peak Stored)             Time:  15:43
   Peak flrea (fl-s): 0.012                 Peak  Height (fl): 0.018
   Blank Corrected Pk flrea (ft-s): -0.000
Mean Pk flrea  (fl-s):

fluto-sero performed.
                    0.003
               SD: 0.13036
 I

 1

 I

1

 I
   uL dispensed: 10 from  0,  5 from 40, 10 from  27
   (Replicate  1                            Time:  15:45
   Peak flrea (fl-s): 0.016                 Peak  Height (fl) : 0.028
   Blank Corrected Pk  flrea (ft-s): 0.002
                                                                    RSD(*):  144.76

Co
ID: 185-26-6D
      eq.  No.: 00103
                                                     fl/S Pos.: 27
                                                                   Date:  11/07/97

   uL  dispensed: 10 from 0,  5 from 40,  10 from 27
   Replicate  2 (Peak Stored)              Time:  15:48
   Peak  flrea (fl-s): 0.013                  Peak Height (fl): 0.032
   Blank Corrected Pk Area  (fl-s):  -0.002
   Mean  Pk  flrea (fl-s):

   Co     ID:  flDDl=25PPB
 0.000         SD: 0.0023

     Seq.  No. :  00104     fl/S Pos. : 27
                                                            RSDC/.) :  2405.54

                                                             Date:  11/07/97
  uL dispensed: 5 from 40,  10 from 1,  10 from 27
  Replicate  1                            Time:  15:50
  Peak  flrea (fl-s): 0.111                  Peak Height (fl): 0.115
-------
                r~ PI  ni
uL dispensed: 5  from  40,  10 from 1, 10 from 27
Replicate  2  (Peak  Stored)              Timer  15:53
Peak Area  (A-s):  0.189                  Peak Height (ft):  0.115
Blank Corrected  Pk  ftrea  (A-s): 8.095

Mean Pk Area  (A-s):     *  0.096         SD: 0.0009

Co    ID:  ADD2=50PPB          Seq.  No.: 00105     A/S Pos.:  27
                                                                 RSDC/.)

                                                                  Date:
                        0.99

                       11/07/97
uL dispensed: 5  from  40,  10 from £, 10 from 27
Replicate   1                            Time:  15:5&
Peak Area  (A-s):  0.199                  Peak Height (ft)
Blank Corrected  Pk  Area (ft-s): O.185

uL dispensed: 5  from  40,  10 from 2, 10 from £7
                                                          0. £00
Replicate  £  (Peak Stored)
Peak Area  (A-s): 0.193
Blank Corrected Pk Area  (A-s):  0.179

Mean Pk Area  (A-s):       0.182

Co    ID:  135-26-6D tftf  -^ 0  Seq.  No.

Concentration  (ug/L   ):  0.0

Correlation coefficient:  0.99795
                                        Time:  15:53
                                        Peak Height (A):  0.191
                                        SD: 0.0043

                                        00103     A/S Pos. : £7



                                        Slope:  0.0037
                                                                 RSDC/)

                                                                  Date:
                        2. 34

                       11/07/97]
                                                                                j
                          (Display Calibration - C;\ftfl
                          -O-O
                                   Concentrotlon
                                                    30.0
                            r^r^t^ff^f^ff^f^f^/^r^t^i^f^f^r^f^
Co
       ID:  STD  BLANK
                              Seq.  No. : 00106
A/S Pos. : 0
Date: 11/07/97
uL dispensed:  10  from  0,  5 from 40,  10  from  0
Replicate   1                             Time:  16:01
Peak Area  (A-s):  0.012                  Peak  Height (A): 0.018
Blank Corrected Pk  Area (A-s): -0.002
-------
  UL cn - "•'-,-
 IReplicate
                             r • u HI t vj,
            IE:  (Peak Stored)
Peak Area  (A-s):  0.011
Blank Corrected  Pk Area (A-s): -0.004
 I
Mean Pk Area  (A-s):

Auto-zero  performed.


Co
                           -0.003
                                  Time: 16:03
                                  Peak Height  (A)


                                  SD: 0.0012
                                                             .018
ID: 185-26-7CD
Seq. No.: 00107
                                                   A/S Pos. :  23
IuL dispensed:  10 from 0,  5 from 40, 10
Replicate   1
 I
Peak Area  (A-s):  0.015
Blank Corrected  Pk Area (A-s): 0.003
  uL dispensed: 10  from  0,  5 from 40,  10
 _ Replicate  2  (Peak  Stored)
 I Peak Area  (A-s):  0.011
I

 I

 I

 1

 I

 1

 I
 Blank Corrected  Pk Area (A-s): 0.000

 Mean Pk Area  (A-s):      0.002

 Co    ID: ADD1=25PPB         Seq. No.:

 uL dispensed:  5  from 40,  10 from 1,  10
 Replicate   1
 Peak Area  (A-s) :  0. 108
 Blank Corrected  Pk Area (A-s): 0.097

 uL dispensed:  5  from 40,  10 from 1,  10
 Replicate   2  (Peak Stored)
 Peak Area  (A-s):  0.108
 Blank Corrected  Pk Area (A-s): 0.097
 Mean Pk Area  (A-s):

 Co     ID:  ADD2=50PPB
                          0.097

                              Seq. No.:
 uL dispensed:  5  from 40,  10 from 2, 10
 Replicate   1
 Peak Area  (A-s):  0.201
 Blank Corrected  Pk Area (A-s): 0.190
  IuL dispensed: 5 from 40,  10  from 2,  10
  Replicate  2  (Peak  Stored)
  Peak Area (A-s): 0.205
 . Blank Corrected Pk  Area  (A-s):  0.193
                            0. 192
                           ct
Mean Pk Area  (A-s):

Co    ID:  185-26-7CD l$» ^J  , Seq.  No. :

Concentration  (ug/L   ):  0.4

Correlation coefficient:  0.99999
                                          from £8
                                          Time: 16:06
                                          Peak Height  (A): 0.024
                                        from 28
                                        Time:  16:08
                                        Peak Height  (A):  0.026
          SD: 0.0022

          00108    A/S  Pos. :  28

          from 28
          Time:  16:11
          Peak Height  (A):  0.113


          from 28
          Time:  16:14
          Peak Height  (A):  0.113


          SD: 0. 0000

          00109    A/S  Pos. :  28

          from 28
          Time:  16:16
          Peak Height  (A):  0.205
                                        from 28
                                        Time:  16:19
                                        Peak Height  (A):  0.199
                                        SD: 0. 0024

                                        00107    A/S  Pos. :  28



                                        Slope: 0.0038
                                                                 RSDC/-) : 44. 19
                                                                  Date: 11/07/97
                                                                 RSD(5O :  140.83

                                                                  Date:  11/07/97
                                                          RSD(%):  0.

                                                           Date:  11/07/97
                                                           RSD(5O:  1.27

                                                            Date:  11/07/97
                                                                   .19
-------
                                   Calibration - Ci\0LB*
                                          ^__. __..
                                          Sir*. C«»*-J *-»»»*
                                          :A<»D»; a.aaaa
                          -ff.4
                                   Concentr atlon
                                                   se.e
 Co
       ID: STD  BLANK
                              Seq.  No.:  00110
fl/S Pos. : 0
Date: 11/07/9";
 uL  dispensed:  1© from 0,  5 from 40, 10
 Replicate   1
 Peak  flrea  (fl-s): 0.014
 Blank Corrected Pk flrea (fl-s): 0.002

 uL  dispensed:  10 from 0,  5 from 40, 10
 Replicate   2  (Peak Stored)
 Peak  flrea  (fl-s): 0.012
 Blank Corrected Pk flrea (fl-s): 0.001
 Mean  Pk  flrea (fl-s):

 fluto-zero  performed.
                          0.002
                                        from 0
                                        Time: 16:22
                                        Peak Height  (fl) :  0.02£


                                        from 0
                                        Time: 16:24
                                        Peak Height  (fl):  0.020
                                        SD: 0.0008
                                                                 RSD(%): 51.67
Co
      ID:  1S5-26-8DE
uL dispensed:  10  from  0,  5  from  40,  10
Replicate   1
Peak flrea  (fl-s):  0.013
Blank Corrected Pk flrea  (fl-s): 0.000

uL dispensed:  10  from  0,  5  from  40,  10
Replicate   £  (Peak Stored)
Peak ftrea  (fl-s):  0.013
Blank Corrected Pk flrea  (fl-s): 0.000
Mean Pk flrea  (fl-s):

Co    ID: flDDl=£5PPB
uL dispensed: 5  from  40,  10 from 1,  10
Replicate   1
Peak flrea  (fl-s):  0.106
                              Qq,  No.: 00111    fl/S  Pos.:  29    Date: 11/07/9
                                        from £9
                                        Time:  16:26
                                        Peak Height  (fl) :  0.027
                                        from £9
                                        Time: 16:29
                                        Peak Height (fl): 0.026


                                        SD:  0.0002               RSD<*>:  79.71

                                        0011£    fl/S Pos.: 29     Date:  11/07/9

                                        from £9
                                        Time: 16:3£
                                        Peak Height (fl): 0.11£
                          0.000

                              Seq.  No.:
-------
 tt j. an
 fuL'dispensed: 5 from 40,  10  from  1,  18 from £9
 fReplicate  £ (Peak Stored)              Time: 16:34
 Peak  Area (A-s): 0.111                  Peak Height  (A): 0.113
 IBlank Corrected Pk Area  (A-s):  8.898
 Mean  Pk  Area (A-s):

 Co     ID:  ADD£=50PPB
8.096         SD:  8.0037

    Seq. No.: 00113     A/S Pos.:  £9
                                                                  RSD(%) : 3. 84

                                                                   Date: 11/07/97
 uL dispensed: 5 from 40,  10  from  £,  18 from £9
I Replicate  1                            Time: 16:37
 Peak  Area (A-s): 0.194                  Peak Height  (A): 0. £00
 Blank Corrected Pk flrea  :  0.181

 uL dispensed: 5 from 40,  10  from  £,  18 from £9
 Replicate  £  (Peak Stored)
-Peak Area  (A-s) :  0. 194
•Blank Corrected  Pk Area (A-s): 0.181
 Mean Pk Area  (A-s):

 Co     ID:  185-£6-8DE
0. 181

    Seq. No.
'^Concentration (ug/L   ): 0.1
•
  i

I

I

I

I
V
I

I
 Correlation  coefficient: 0.9973£
                                          Time: 16:39
                                          Peak Height  (A): 0. 19£
              SD:  8.0083

              80111     A/S Pos. :  £9



              Slope:  0.0837
                                                                  RSDCyt) :  0. 16

                                                                   Date:  11/07/97
                           Pisolay Calibration - C; \ftfl 11
                         LI*
                           -9.1
                                     Concentrotlon
                                                     30.
             i\fi\f'\ft^»\f'\f'\ff\f^i\ff^'\f'\ff^t^»\^

I  Co     ID:  STD BLANK           Seq.  No.:  80114    A/S Pos.: 8      Date:  11/07/97

| uL  dispensed: 10 from 0, 5 from  48,  10  from 0
  Replicate   1                            Time: 16:4£
,  Peak  Area  (A-s): 0.015                  Peak Height  (A): 0.0£6
  Blank Corrected Pk Area  (A-s): 0.00£
-------
ui_ d is pen sea:  iiti  rrum ti,  _i i rum Tf,  j.v
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.011
Blank Corrected Pk  Area (A-s): -0.00£
                                         I U 111 *.'
Mean Pk Area  (A-s):

Auto—aero  performed.
                         -0.000
                                        Time: 16:45
                                        Peak Height  :  0.005

uL dispensed:  10  from  0,  5 from 40,  10
Replicate   £  :  0.013
Blank Corrected Pk  Area :

Co    ID: ADD£=50PPB
uL dispensed:  5 from 40,  10 from £,  10
Replicate   1
Peak Area  (A-s):  0.£00
Blank  Corrected Pk Area (A-s):  0.187

uL dispensed:  5 from 40,  10 from £,  10
Replicate   £  (Peak Stored)
Peak Area  (A-s):  0.£00
Blank  Corrected Pk Area (A-s):  0.187

Mean Pk Area  (A-s):       0.187

Co     ID:  185-£6-9Df(x2# .--  ,,, Seq.  No.:
                        £0 ^^£f i .  '
                         v^^ ///I"}/ C "^
Concentration  (ug/L   ): 1.5

Correlation coefficient:  0.99780
                              Seq.  No.: 00115    A/S Pos.:  30
                                        from  30
                                        Time:  16:47
                                        Peak  Height (A):  0.034
                                        from 30
                                        Time:  16:49
                                        Peak Height  (A):  0.03£
                                        SD:  0.000£

                                        00116    A/S Pos.:  30

                                        from 30
                                        Time: 16:5£
                                        Peak Height  (A):  0. 1£3
                                        from 30
                                        Time:  16:55
                                        Peak Height  (A):  0.1£3
                                        SD: 0.0009               RSD('yC): 0.88

                                        00117    A/S Pos.:  30     Date:  11/07/97

                                        from 30                                '
                                        Time: 16:57
                                        Peak Height  (A): 0.£01
                                        from 30
                                        Time: 17:00
                                        Peak Height  (A): 0.198
                                        SD:  0. 000£               RSD <•/.):  0.03   1

                                        00115    A/S Pos.: 30     Date:  11/07/97



                                        Slope:  0.0037
                          0. 101

                              Seq. No.:
-------
                                     Calibration - C:\AA
                                     Concentration
                                                     39.0
 I

 I

 I
        ID: STD BLflNK
                                Seq.  No.:  00116
                                                 fl/S Pos.:
                                                                 Date:  11/07/97
ul_ dispensed: 10  from  0,  5  from 40,  10
Replicate  1
Peak flrea (fl-s):  0.011
Blank Corrected Pk  flrea  (fl-s):  -0.003

uL dispensed: 10  from  0,  5  from 40,  10
Replicate  £ (Peak  Stored)
Peak flrea (fl-s):  0.013
Blank Corrected Pk  ftrea  (fl-s):  -0.000
'•
 •
Mean Pk flrea (fl-s):

fluto-zero performed.
                           -0.001
                                          from 0
                                          Time: 17:03
                                          Peak Height  (fl) : 0.023
                                          from 0
                                          Time: 17:05
                                          Peak Height  (fl) : 0.018
                                          SD: 0.0013
                                                                 RSDC/.) :  133.4S
Co
        ID: 185-26-10D
                                Seq. No. :
                                   ~
00119
                                                 fl/S Pos. : 31
Date: 11/07/97
 I
  uL dispensed: 10  from  0,  5 from 40,  10
  Replicate  1
  Peak flrea (ft-s) :  0.016
  Blank Corrected Pk  flrea  (fl-s):  0.004
  IuL dispensed: 10  from  0,  5 from 40,  10
„  Replicate  S  (Peak  Stored)
  Peak flrea (fl-s):  0.016
  Blank Corrected Pk  flrea (fl-s):  0.004
1
  Mean Pk flrea  (fl-s):

  Co    ID: flDDl=25PPB
                            0.004

                                Seq.  No.:
  uL dispensed:  5 from 40,  10 from 1, 10
  Replicate   1
  Peak flrea  (fl-s):  0.116
                                        from 31
                                        Time: 17:07
                                        Peak Height  (fl): 0.0£5
                                          from  31
                                          Time:  17:10
                                          Peak  Height  (fl) :  0. 0£6
                                        SD: 0.0003               RSDC/.): 6. 6£

                                        001£0    fl/S Pos. :  31     Date: 11/07/97

                                        from 31
                                        Time:  17:1£
                                        Peak Height  (fl):  0.1£4
-------
                 t~ r\  n i
uL- dispensed: 5  from 40,  10 from 1,  10 from 31
Replicate  £  (Peak  Stored)              Time: 17:15
Peak flrea  (fl-s):  0.115                 Peak Height  (fl): 0.120
Blank Corrected  Pk  flrea (fl-s):  0.103

Mean Pk flrea  (fl-s):    *  0.104          SD: 0.0003               RSD(*>« ®-£S

Co    ID:  flDD£=50PPB         Seq.  No. : 001£1    fl/S Pos. :  31     Date: 11/07/97^
                                                                                i
uL dispensed: 5  from 40,  10 from £,  10 from 31
Replicate  1                            Time: 17:17                             I
Peak ftrea  (fl-s):  0.198                 Peak Height  (fl) : 0.198                  j
Blank Corrected  Pk  flrea (fl-s):  0.186

uL dispensed: 5  from 40,  10 from £,  10 from 31                                 I
Replicate  £  (Peak  Stored)              Time: 17:20
Peak flrea  (fl-s):  0.£06                 Peak Height  (ft): 0. £04
Blank Corrected  Pk  flrea (fl-s):  0.194                                           j

Mean Pk flrea  (ft-s):       0.190          SD: 0.0058               RSD<*>: 3.04

Co    ID:  185-£6-10D #H  0  Sec1-  No- ! ®®H9    B/S P°s- :  31     Date: 11/07/9

Concentration  (ug/L  ): 1.1

Correlation  coefficient:  0.996£9       Slope: 0.0038
\

I
                          [Display Calibration - C; \ftft li
                        .1*0
                                   Concentration
                                                   90.0
-------
Co
        ID: STD BLANK
                             Seq. No.: 001££
                                                 ft/S Pos. : 0
                                       Date: 11/10/9*
  uL  dispensed: 10 from 0, 5  from 40,  10 from 0
  Replicate  1                           Time: 09:£S
  Peak Area (A-s): 0.011                 Peak Height  (A):  0.012
  Blank Corrected Pk Area  (A-s): -0.001

  uL  dispensed: 10 from 0, 5  from 40,  10 from 0
  Replicate  £ (Peak Stored)             Time: 09:30
  Peak Area (A-s): 0.008                 Peak Height  (A):  0.014
  Blank Corrected Pk Area  
-------
Co    ID:  185-26-3D firt  ^*  Seq.  No.: 00123     ft/3 F
                          /////i/fr7
Concentration  (ug/L  ): 4.3

Correlation  coefficient: 0.99920       Slope: 8.0030
                                                  .1/1 a/,?
"(Display Calibration - Ci\flft_l
 -4-5
           Concentration
                           Sfl.fl
-------
•Element  File:  CO. BEL
    •
Loc.   Concentration
 1
 £
 4
 5
 6
 7
 a
 9
10
11
1£
13
14
15
16
17
13
19
£C
£1
££
£3
£4
£5
£&
£7
£8
£9
30
31
48
       58.0 ug/L
       180.0 ug/L
                                 ID/Weight  File:  EB179.IDW

                           Solut i ons
Calib. Blank / Diluent /  ICB / CCB
Stock / Recovery, Stock |-'
Stock      \ -k<
ICV=30ug/L  (-(
CCV=fc0ug/L  i-j^-ny              |
CHECK LO                      x
4345£ MB
4345£ LCS
                             185-£6-£C
                             185-£6-3C
                             185-£fe
                            ; i85-£6
                             185-£6
                             185-£6
                            &;185-£6
                             185-£6
                               5-£&
                             185-£6
                             185-£fe
                             185-E6
                             185-£6
                             185-E6
                             185-£fe
                             185-£6
                             185-£&
                             185-£fe
                             185-£&
                             Modifi
I  4LjP
  N
kill
                                                            20i
-------
tiement I-i i e :  UU. blr.L
Element:  Co
Print.Data: Main+Suppl.
Print:  Calib.  Curve+Elem.
                Analyst:  HOLS1E
                Peak Storage:  1  Repl./Sample
      Par am s.
INSTRUMENT: 4100  ZL
Wavelength: £40.7 Peak.
Signal Type:  Single Beam
Read Time: 3.0
Sample Replicates:  2
Standard  Replicates:  £
                Technique: HGA
                Slit: 0. £0 Low
                Signal Measurement
                Read Delay: 0.0
   Peak
Version: 7.30

Area
BOC Time: S.
                Spike Replicates:  Same  as  Sample
CALIBRATION:
 Solut i ons

Calib. Blank
Standard  1
Standard  £
Standard  3
Reslope Std.
Samples
 Diluent  Location:  0
 Modifier #1 Location: 40
 Calibration Units: ug/L
 Calibration Type:  Nonlinear
1 ID
1
1 C"TT\ Ql AML/
I O 1 U ol_HNr\
ISTD l=£5ug/L
ISTD £=50ug/L
ISTD 3=100ug/L
1 Reslope 50ug/L
Cone
_
£5.0
50.0
100.0
50.0
Locat ion
1
1
£
1
                                VolumeIDiluentI  Modifier
                                      I Volume I  #1
10  I   10
 5  I   15
10  I   10
10  I   10
10  I   10
10  I   10
                                                 5
                                                 5
                Modifier tt£ Location:
                Sample Units: ug/L
Furnace Time/Temperature Program:
Step 1 Temp
1 1 110
£ 1 130
3 11400
4 1 £400
5 l£500
Inject ion
Ramp
1
1
5
0
1
Temp
Hold
£0
£5
£0
4
5
: £0
IGas Flow
1 £50
1 £50
1 £50
1 0
1 £50
Read



*

Gas Type
Norm
Norm
Norm
Norm
Norm






Pipette Speed: 100/4 Extraction System: On
SEQUENCE:
Step  Action and Parameters
   1    Pipet diluent +• modifier  1
  £    Run HGA steps 1 to End
                spike +• sample/std
CHECKS:
Recalibration Type:
Locations: None
Autosero Only
Cone. Above Calibration Action: Dilute &  Reanalyze  After 1
Alternate Sample Volumes   £0.0      and Concentration  > 5         then  Retry 1
Check 54RSD on: Samples + Standards + Spikes •+• QC  Samples
                                           times
Recovery Measurements:
5  uL of 50 ug/L Standard at Location  1  Gives      £5.0  ug/L
Measure Recovery on Samples: None
Add to QC Samples: Yes              •/.  Recovery  Limits: 75 to 1£5
-------
 G!LJ:
 ttl.ft/S I    QC Sample   I     Cone.  Limits      IflfterI Periodic I fit  ICount Os I
  .1 'Loq. I       ID       I   Lower     Upper     ICalibl  Check  I End I Sample  I
 1    A  ICV=30ug/L      £7.0       33.0          X
 £    0  ICB             -£.0       S-0           X
 3    5  CCV=60ug/L      48.0       7£. 0                  X      X
 A    0  CCB             -£. 0       £. 0                   XX
 Run Periodic QC Samples: Every 10
 Out of Limit fiction: Print Message Only

 Matrix Check Calculations:
 % Difference for Dupls: No     Locations:
1 % Recovery for Spike: No       Locations:          Cone:
-------
Element File: CO.GEL
D-ate: -11/06/97
Data File: EB179.DAT
Technique: HGA
                              Element:  Co
                              Time:  19:34
                              ID/Wt  File:  EB179.IDW
                              Calib.  Type: Nonlinear
                               Wavelength: £40.7
                               Slit: 0.£0 L
                               Lamp Current: 30
                               Energy: 49
Co
      ID: STD BLANK
Seq. No.: 00001
ft/S Pos.
uL dispensed:  10  from 0,  5  from  40,  10 from 0
Replicate   1                            Time: 19:36
Peak flrea  
Blank Corrected Pk Area  (A-s): 0.007
Concentration  (ug/L  ):  £.5
0
                                                         0.044
                                                                 Date:  11/06/97
                                                         0.041
Mean Cone   (ug/L   ):

Auto-zero performed.
                            £.8
          SD: 0.35
     RSDC/>: 1£.59
Co    ID: STD l=£5ug/L
Seq. No.: 0000£    A/S  Pos.:  1
                                                                 Date:  11/06/9";
uL dispensed: 15 from 0, 5  from  40,  5 from 1
Replicate   1                            Time:  19:41
Peak Area  (A-s): 0. 08£                  Peak Height (A): 0.099
Blank Corrected Pk Area  (A-s): 0.065
Concentration (ug/L  ):  £3.1

uL dispensed: 15 from 0, 5  from  40,  5 from 1
~~^^~^~^^^^~^^^^*,A,^A,^^^^^^^^^

Co    ID:  Seq. 00003          Seq.  No.: 00003     A/S Pos.: —     Date:  11/06/91
Replicate  1
Peak Area  (A-s): 0.005
Blank Corrected Pk Area  (A-s):  -0. 01£
Concentration  (ug/L  ):  -4.4
                                        Time:  19:46
                                        Peak Height (A): 0. 01£
-------
      ID: STD  BLANK
                               Seq.  No.:  00004     A/S Pos. :
                                                                   Date:  ll/06/9
* uL  dispensed: 10  from 0,  5
  Replicate  1
  JPeak Area (A-s):  0.014
  Blank Corrected Pk Area  (A
ill  Concentration (ug/L   ):  -l.
                             from 40, 10 from 0
                                         Time: 19:55
                                         Peak Height  (A):  0.033
                             s): -0.003
                             S
 uL dispensed:  10 from 0, 5 from 40, 10 from 0
                             t\ff^
Co
        ID: STD BLANK
I

\
  uL dispensed: 10 from 0,  5
  Replicate  1
  Peak Area (A-s) : 0.017
  Blank Corrected Pk Area  (A
  Concentration (ug/L   ):  -0.
                                Seq.  No. :  00005    A/S Pos. : 0

                              from  40,  10  from 0
                                          Time: 19:59
                                          Peak Height (A): 0.036
                              s): -0.001
                              £
                                                                   Date:  11/06/9

Co
        ID: Seq. 00006
                               Seq. No. : 00006     A/S  Pos. :  —    Date:  11/06/97
ill
  (Replicate  1
  Peak Area  (A-s):
I

I

I

I

I
                  0.005
Blank Corrected  Pk Area
Concent rat ion  (ug/L  ):
                                         Time: £0:01
                                         Peak Height  (A):  0.013
                           (A
                           -4.
                             s): -0. 01£
                             3

Co
        ID: STD BLANK
uL dispensed: 10 from 0,  5
Replicate  1
Peak Area (A-s): 0.014
Blank Corrected Pk Area  (A
Concentration (ug/L  ):  -1,

uL dispensed: 10 from 0,  5
Replicate  cL  (Peak Stored)
Peak Area (A-s): 0.014
Blank Corrected Pk Area  (A-
Concentration (ug/L  ):  —1

Mean Cone  (ug/L  ):

fluto—zero performed.
                               Seq. No.: 00007     A/S Pos.:  0     Date: 11/06/97

                             from 40, 10 from 0
                                         Time: £0:06
                                         Peak Height   :  0.034
                             s> : -0.003
                              from  40,  10 from 0
                                          Time:  £0:09
                                          Peak Height (A):
                              s): -0.003
                              0
                                                           0.033
                            -1.1
                                          SD:  0.10
                                                                  RSD(3O: 9.07
  i i %.» i

 I
 I
  Co
      ID:  STD  l=£5ug/L
  uL dispensed:  15 from 0, 5
  Replicate  1
  Peak  Area (A-s): 0.078
  Blank Corrected Pk Area  (A
  Concentration  (ug/L  ): ££.

  uL dispensed:  15 from 0, 5
  Replicate  £ (Peak Stored)
  Peak  Area (A-s): 0. 08£
  Blank Corrected Pk Area  (A
                                Seq.  No. :  00008    A/S Pos. : 1

                              from  40,  5  from  1
                                          Time: £0:11
                                          Peak Height (A): 0. 10£
                              s): 0.064
                              6

                              from  40,  5  from  1
                                          Time: £0:14
                                          Peak Height (A): 0.109
                              s): 0.068
                                                                   Date: 11/06/97
-------
Uoncentration  \ug/i_  i :  c:<+. vt

Mean C.onc   
-------
J
1
'1

 I

 I

 I

1
                                       Calibration - C:\Aft if*
>.*»-,
                             *
                             a
                              0.0
                                       Concentration
                                                        190.9
-------
Element File: CO. GLL
Date: 11/06/97
Data File: EB179.DAT
Technique: HGA
                              Element: Co
                              Time: £0:34
                              ID/Wt File: EB179. IDW
                              Calib. Type: Nonlinear
                                                            Waveiengtn:  e40. 7
                                                            Slit:  0.20 L
                                                            Lamp Current: 30
                                                            Energy:  49
                         * A/ A* A* A/ A*
Co
      ID: ICV=30ug/L
                              Seq.  No.: 00011
                                                 fi/S Pos. :  4
                                                                  Date:  11/06/9
uL dispensed:  10  from 0,  5 from 40,  10
Replicate   1
Peak Area  (fl-s) :  0.099
Blank Corrected Pk  Area : 31. £

uL dispensed:  10  from 0,  5 from 40,  10
Replicate   £  (Peak  Stored)
Peak Area   :  0.101
Blank Corrected Pk  Area  :  0.017
Blank Corrected Pk  Area (A-s) :  0.003
Concentration   : 0.034
                                        from 0
                                        Time: £0:44
                                        Peak Height  (A):
                                        SD: 0.13
                                                          .041
                                                                RSD(%>:  11.46
                                                    ^<\»^
      ID: CHECK LO
                              Seq.  No. :  00013    A/S Pos. : 6
                                                                 Date:  11/06/97
uL dispensed:  10  from  0,  5 from 40,  10
Replicate   1
Peak Area  (A-s):  0. 03£
Blank Corrected Pk  Area (A-s):  0.018
Concentration  (ug/L  ):  6.6

uL dispensed:  10  from  0,  5 from 40,  10
Replicate   £  (Peak  Stored)
Peak Area  (A-s):  0.030
Blank Corrected Pk  Area (A-s):  0.016
Concentration  (ug/L  ):  5.8
                                        from 6
                                        Time: £0:47
                                        Peak Height (A): 0. 05£
                                        from 6
                                        Time:  £0:49
                                        Peak Height (A): 0. 05£
-------
? Mean
                             6. £
                                           SD:  0.53
                                                                   RSD<%>:
Co
        ID: 43452  MB
                                     ^^A»^A,^^^',,rw^^^^^A»^'w^'v^^^^^«v^
                                Seq. No. :  00014     A/3 Pos. :  7     Date:  11/06/9:
  uL  dispensed:  10  from 0,  5 from 40, 10  from  7
  Replicate  1                             Time: £0:5£
  Peak  flrea (A-s):  0.017                  Peak  Height (A):  0.041
  Blank Corrected Pk Area (A-s): 0.003
  Concentration  (ug/L  ): 1.0

  uL  dispensed:  10  fron 0,  5 from 40, 10  from  7
  Replicate  £  :  0.015
  Blank Corrected Pk  Area -------
uL dispensed:  18  from W,  5 from 4U, ii from y
Replicate   1                            Time: £1:87
Peak Area  (A-s):  0.161                 Peak Height  (A):  0.£10
Blank Corrected Pk  Area (A-s) :  0. 147
Concentration  (ug/L  ): 53.7           Corrected  Cone  (ug/L  ): £68.

uL dispensed:  1Q  from 0,  5 from 40, £ from 9
Replicate   £  (Peak  Stored)             Time: £1:10
Peak Area  (A-s):  0.156                 Peak Height   :  0.198
Blank Corrected Pk  Area (A-s) :  0. 14£
                                                                              +
Concentration (ug/L ): 5£. 0 Corrected Cone (ug/L ): £60.
Mean Cone (ug/L ): 5£.9 SD: 1.17 L fl « RSDC/O: £. ££ I
Corrected Cone (ug/L ): £64. j^yf ft'liy!**7 1
' J
&fi
Co ID:/l185-£6-lC/L Seq. No.: 00019 A/S Pos.: 10 Date: 11/06/91
uL dispensed: 10 from 0, 5 from 40, 10 from 10
Replicate 1 Time: £!:!£
Peak Area  (A-s): 0.188
Blank Corrected Pk  Area (A-s):  0.173
Concentration  (ug/L  ):  63.5
                                        Peak Height  (A):  0.£51
uL dispensed:  10  from  0,  5 from 40,  10 from 10
Replicate  £  (Peak  Stored)              Time: £1:15
Peak Area  (A-s):  0.177                 Peak Height  (A):
Blank Corrected Pk  Area  (A-s):  0.163
Concentration  (ug/L  ):  59.7
                                                          0.££3
Mean Cone   (ug/L   >:
                            61.6
          SD: £. 6£
                                                          RSD<5t) :  4. £5

Co
      ID: 185-£6-.£C
Seq.  No.: 000£0
                                           A/S Pos. : 11
                                                                  Date:
uL dispensed:  10  from 0,  5 from 40, 10 from 11
Sample abs.  is  greater than that of the largest  standard.
Replicate   1                            Time: £1:17
Peak Area  (A-s):  0.717                 Peak Height  (A):  0.776
Blank Corrected Pk  Area (A-s): 0.70£
Concentration  (ug/L  ): £54.£


Co
      ID: 185-£6-£C
Seq.  No.: 000£1
                                           A/S Pos. : 11
                                                                  Date: 11/06/91
uL dispensed:  15  from 0,  5 from 40,  5 from 11
Sample abs.  is  greater than that of the largest  standard.
Replicate  1
Peak Area  (A-s): 0.419
Blank Corrected Pk  Area  (A-s):
Concentration  (ug/L  >:  147.3
                                 .405
          Time: £1:£0                   /S
          Peak Height  (A):  0.481        ,/

          Corrected  Cone  (ug/L  ): £94.7
Co
ID:4 185-£6-£Cff*r
Seq.  No.: 000££
                                                 *V *V *\* «V *\/ *\* *V *\* *V *\/ *Vr *V» *\/ *\*

                                                 A/S Pos.: 11
                                                                  Date: 11/06/9
uL dispensed:  18  from 0,  5 from 40,  £ from 11
Replicate   1                            Time: £!:££
Peak Area  (A-s):  0. £5£                 Peak Height  (A):  0. 3£8
Blank Corrected Pk  Area (A-s): 0.238
-------
                                                          .H/ ._
 IuL dispensed:  18  from  0,  5 from 40,  i
 Replicate  £  (Peak  Stored)
 Peak Area  (A-s):  0.£87
IBlank Corrected Pk  Area (A-s>:  0.£73
^Concentration  (ug/L  ):  99.7

.Mean Cone  (ug/L   ):        93.4
[Corrected Cone  (ug/L   ):  467.
                                        from 11
                                         Time: £1:£5
                                         Peak Height  (A): 0.339

                                         Corrected Cone  
-------
Co.   ID:/L185-£6-3C X        Seq.  No.: 00026    fl/S
uL dispensed:  15 from 8,  5 from 40,  5 from 1£
Sample abs.  is  greater than that of the largest standard.          /"   /  /
Replicate   1                            Time: £1:40                    ////S/'»>
Peak Area  (A-s):  0.390                 Peak Height  (A) :  0.483
Blank Corrected Pk  Are,* (A-s): 0.376
Concentration  (ug/L  ): 136.9          Corrected Cone  (ug/L  ):  £73.8

A»^»\/^A,^^*VA»^^^<\,^A»^^^^^'V~A»^^^A/.^A»<\/^A»^^^^^^^^^^^A»~A/^~^~^~~~^~~~~~~^~~^
Co    ID:/185-£6-3Cj#r<5      Seq.  No.: 000£7    A/S Pos. :  1£    Date: ll/06/9?J
uL dispensed:  18 from 0,  5 from 40,  £ from 1£
Replicate   1                            Time: £1:4£
Peak Area   : 0. £39                 Peak Height  (A):  0. £95
Blank Corrected  Pk Area (A-s) :  0. ££4
Concentration   :  0. £96
Blank Corrected  Pk Area (A-s):  0. ££5
Concentration  (ug/L  ): 8£. £           Corrected Cone  (ug/L  >: 411.

Mean Cone   (ug/L  ):        8£. 1        SD: 0.08                 RSD(%): 0.10
Corrected  Cone (ug/L   ):  411.
Co     ID:A185-£6-4C f-l4       Seq.  No. : 000£8    A/S Pos. :  13    Date: 11/06/91

uL dispensed:  10 from 0,  5 from 40,  10 from 13
Replicate   1                            Time: £1:47
Peak Area  (A-s): 0.1£5                 Peak Height  (A):  0. £19
Blank  Corrected Pk Area (A-s): 0.111
Concentration  (ug/L  ): 40.6

uL dispensed:  10 from 0,  5 from 40,  10 from 13
Replicate   £  (Peak Stored)              Time: £1:50
Peak Area  (A-s): 0.1£7                 Peak Height  (A):  0. £17
Blank  Corrected Pk Area (A-s): 0.113
Concentration  (ug/L  ): 41.3

Mean Cone   (ug/L  ):       40.9        SD: 0.55                 RSDC/4): 1.34

Co     ID:x185-£6-5C Fti     .  Seq.  No.: 000£9    A/S Pos.:  14    Date: 11/06/9"
uL dispensed:  10 from 0,  5 from 40,  10 from 14
Replicate   1                            Time: £1:5£
Peak Area  (A-s): 0.134                 Peak Height  (A):  0.198
Blank Corrected  Pk  Area (A-s) :  0. 1£0
Concentration  (ug/L  ): 44.0

uL dispensed:  10 from 0,  5 from 40,  10 from 14
Replicate   £  (Peak  Stored)             Time: £1:54
Peak Area  (A-s): 0.134                 Peak Height  (A):  0.177
Blank Corrected  Pk  Area (A-s) :  0. 1£0
Concentration  (ug/L  ): 43.8
-------
  Meai
                                          SD:  0. i
                                                                   RSD<%>:
  Co
        ID:  185-£&-6C#
i
\
                                Seq. No.: 00038
                                                    A/S Pos. :  15    Date: ll/06/«
  uL dispensed:  10 from 0, 5 from 40, 10 from  15
  Replicate   1                            Time:  £1:57
  Peak Area  (A-s): 0. 069                 Peak  Height  (A):  0.138
  Blank  Corrected Pk Area  (A-s): 0.054
  Concentration  (ug/L  ): £0.0

  uL dispensed:  10 from 0, 5 from 40, 10 from  15
  Replicate   £   :  0.128
  Blank  Corrected Pk Area  :  19.5
                              19.7
                                          SD:  0.35
\

  Co    ID:A185-£6-7CfW.or  /
-          W-S-Z-n,!*,    rfi
I uL dispensed:  10 from 0,  5 from 40, 10 from 16
* Replicate   1                            Time: ££:0£

I
Mean Cone   (ug/L  ):

*vJv*wA/'\*j\»A**w'w'\**\*'\**\»j\*'vr-«w****\*
Co     ID:^185-£6-
                                                                   RSD<%):  1.78
                                Seq. No.: 00031     A/S Pos.:  16    Date: 11/06/97
   Repl
   Peak  Area (A-s): 0.030
   Blank  Corrected Pk Area  : 5.8
                                                    0£
                                          Peak  Height (A):  0.045
   fuL dispensed:  10 from 0, 5 from 40, 10 from  16
   Replicate   £ -------
Peak Area  (A-s):  0. 0£7
Blank Corrected Pk  Area (A-s):  0.013
Concentration  (ug/L  ) : 4.6
                                        Peak Height  (F
uL dispensed:  10 from 0,  5 from 40,  10 from IS
Replicate   £ (Peak Stored)             Time: 2£:14
Peak Area  (A-s):  0. 026                 Peak Height  (ft):  0.049
Blank  Corrected  Pk Are-a (A-s): 0.01£
Concentration  
                        f^f\ft^
Co
ID: 185-£6-9C
                              Seq.  No
                                        00035
                                                 A/S Pos.:  19
                                                                  Date: 11/06/9"
 uL  dispensed:  15 from 0,  5 from 40,  5 from 19
 Sample  abs.  is greater than that of the largest  standard.
 Replicate   1                            Time: £2:19
 Peak  Area  -------
LiL c  ,,;.„, r,«,MU  ,,*-  . . «...  '-•!  => rrom
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.174
Blank Corrected Pk  Area (A-s) :
Concentration  (ug/L  ): 58.4
                                   . 1&0
I Mean Cone  (ug/L  ):       58.2

  JQC sample is within range 48.0 - 72.0
                                          rrom s
                                          Time: 22:29
                                          Peak Height  (A):
                                                  u
                                           SD:  0.35
                                                            0.201
                                                                 RSDC/O :  0.60

  Co
        ID: CCB
                              Seq. No.: 00038
A/S Pos.: 0
Date: 11/06/97
  uL dispensed:  10 from O,  5 from 40,  10  from  0
  Replicate   1                             Time: £2:31
  (Peak Area  (ft-s): 0.019                  Peak  Height  :  0.037
  Blank Corrected  Pk Area (A-s): 0.004
  Concentration  (ug/L  ): 1.6

I uL dispensed:  10 from 0,  5 from 40,  10  from  0
  Replicate   £  (Peak Stored)              Time: 22:33
_ Peak Area  (A-s): 0.013                  Peak  Height  (A):  0.034
"I Blank Corrected  Pk Area (A-s): 0.004
'•  Concentration  (ug/L  ): 1.5
I

I

I

I

I

I
  Mean Cone  (ug/L  ):         1.5

  QC sample is within range -2.0  —2.0
                                        SD: 0.08
               RSD(54) :  5.46
  Co    1 0:^,1 85-26 - 1 0C F#"      Seq.  No.: 00039    A/S Pos.: 20     Date:  11/06/97
  uL dispensed: 10 from 0, 5  from  40,  10 from 20
  Replicate  1                            Time: £2:36
  Peak Area (A-s): 0.068                  Peak Height (A): 0.151
  Blank Corrected Pk Area  (A-s): 0.053
  Concentration (ug/L  ):  19.6

  uL dispensed: 10 from 0, 5  from  40,  10 from £0
  Replicate  £ (Peak Stored)              Time: £2:38
  Peak Area (A-s): 0.064                  Peak Height (A): 0.131
  Blank Corrected Pk Area  (A-s): 0.050
  Concentration (ug/L  ):  18.4
  Mean Cone   (ug/L   ):
                              19.0
                                        SD: 0. 87
               RSDC/O :  4.60
  Co    ID:  185-26-1D

                               Seq.  No.:  00040
                                                 A/S Pos.:  21
                Date:  11/06/97
  uL dispensed:  10  from  0,  5 from 40, 10 from 21
  Replicate   1                            Time: 22:41
  Peak Area  (A-s):  0.031                 Peak Height  (A):  0.060
  Blank Corrected Pk  Area (A-s): 0.017
  Concentration  (ug/L  ): 6.3

  uL dispensed:  10  from  0,  5 from 40, 10 from 21
  Replicate   £  (Peak  Stored)              Time: £2:43
  Peak Area  (A-s):  0.027                 Peak Height  (A):  0.054
-------
Concentration  (ug/L  ) :

Mean Cone   (ug/L   ):
                             5.4
          SD:  1.28
                RSDC/O : £3.61
Co
      ID: 185-£6-lD
Seq.  No.: 00041
A/S Pos.: £1
                                                                  Date: 11/0&/91
uL dispensed:  10  from .0,  5 from 40,  10
Replicate  1
Peak Area  (A-s):  0. 0£8
Blank Corrected Pk  Area (A-s):  0.014
Concentration  (ug/L  >: 5.1

uL dispensed:  10  from  0,  5 from 40,  10
Replicate  £  . 158
Mean Cone   (ug/L   ):
                            33.9
          SD: £.58
                RSDC/0 : 7. &£
Co    ID: 185-£fe-3D           Seq.  No. :

uL dispensed:  10  from  0,  5 from 40,  10 from £4
                                        00044    A/S Pos.:  £4     Date: 11/06/91
-------
  Peak nr e=i KH-S; : vt. IOHH                  Peak Height  (fl) : 0. 088
,|Biank Corrected Pk flrea  (fl-s):  0.030
 {Concentration  (ug/L   ):  11.1
x
4;i uL dispensed:  10 from 0,  5  from 40,  10 from £4
 I Replicate  £ :  0. 0£6
 [Concentration  : £.££
 Co     ID:  185-£6-6D           Seq.  No.:  00047    fl/S Pos.: £7     Date: 11/06/97

 uL dispensed:  10 from 0, 5  from  40,  10  from £7
 Replicate   1                             Time: £3:16
 Peak  flrea  (fl-s): 0.0£5                  Peak Height  (fl): 0.044
 Blank  Corrected Pk flrea  (fl-s): 0.011
 Concentration  (ug/L  ):  4.0

 uL dispensed:  10 from 0, 5  from  40,  10  from £7
 Replicate   £  (Peak Stored)              Time: £3:19
 Peak  flrea  (fl-s): 0.0£5                  Peak Height  (fl): 0.050
-------
Blank  Corrected Pk ftrea (ft-s>: 0.011                                           "*J
Concentration :  £-03  !

*V *\* *V  A/ *\* A* *\* *V A* *\* *\» *V *\» A/ *V *\* *V *^ *V A/ *V *V A/ A* A* *\t *V A* 
-------
Co.
                               Seq.  No.: 00051
JuL dispensed: 10 from 0, 5 from 40,  10
  Replicate  1
^Peak  flrea (fl-s): 0. 0£1
                                                   fl/S Pos.: £9
                                                                 Date:  11/06/9
      Corrected Pk flrea  (fl-s):  0.006
Concentration  (ug/L   ):  2.3
  IuL dispensed: 10 from 0, 5 from 40,  10
  Replicate  £  Concentration  (ug/L  ): 6.8
|
  uL  dispensed:  10 from 0, 5 from 40,  10
  Replicate   £ (Peak Stored)
  Peak  ftrea  (fl-s): 0. 03£
  Blank Corrected Pk flrea  (fl-s): 0.018
  Concentration  (ug/L  ): 6.6
Mean Cone  (ug/L   ):
                              6.7
                                        from 31
                                        Time: £3:46
                                        Peak Height  (fl) : 0.064
                                        from 31
                                        Time: £3:49
                                        Peak Height  (fl) : 0.066
                                          SD:  0. 19
Co
      ID: CCV=60ug/L
                               Seq.  No. :  00054
                                                   fl/S Pos. :  5
                                                                 RSD (•/.):  £.81
                                                                 Date:  11/06/97
 uL dispensed: 10 from 0,  5  from  40,  10
 (Replicate  1
 Peak ftrea (fl-s): 0.181
 Blank Corrected Pk flrea  (fl-s) : 0. 167
 Concentration (ug/L  ):  61. £
                                          from  5
                                          Time:  £3:51
                                          Peak  Height (fl) :
                                                         0.199
-------
ui_ dispensed:  iw rruui u,  ^i i r-um -rt',
Replicate  2  (Peak  Stored)
Peak Area  (A-s): 0.179
Blank Corrected  Pk  Area (A-s): 8.164
Concentration  (ug/L  ): 60.1
                                        Time: £3:54
                                        Peak Height  (A):  0.192
Mean Cone   (ug/L   ):        60.6        SD: 0.72
                      »
QC sample  is within  range 48.0 - 72.0

Co
       ID: CCB
Seq. No.: 00055
                    A/S Pos. : 0
uL dispensed:  10  from 0,  5 from 40,  10 from 0
Replicate   1                            Time: 23:56
Peak Area  (A-s) :  0.023                 Peak Height  (A)
Blank Corrected Pk  Area (A-s): 0.008
Concentration  (ug/L  ): 3.1

uL dispensed:  10  from 0,  5 from 40,  10 from 0
Replicate   2  (Peak  Stored)              Time: 23:59
Peak Area  (A-s):  0.022                 Peak Height  (A)
Blank Corrected Pk  Area (A-s): 0.008
Concentration  (ug/L  ): 2.8

Mean Cone   (ug/L   ):         £.9        SD: 0.17

QC sample  is out  of range -2.0 - 2.0
                                                          0. 057
                                                          0.058
Co
      ID: CCB
Seq. No. : 00056
A/S Pos. : 0
uL dispensed:  10  from  0,  5 from  40,  10 from 0
Replicate  1                            Time: 07:35
Peak Area  (A-s):  0.011                  Peak Height  (A): 0.037
Blank Corrected Pk  Area (A-s): -0.004
Concentration  (ug/L  ):  —1.4

uL dispensed:  10  from  0,  5 from  40,  10 from 0
Replicate  £  (Peak Stored)
Peak Area  (A-s): 0.011
Blank Corrected Pk Area  (A-s> :  -0.003
Concentration  (ug/L   ):  —1.2

Mean Cone  (ug/L  ):        -1.3

QC sample  is within range  -2.0  -  2.0
                                        Time: 07:38
                                        Peak Height  (A): 0.035
                                        SD: 0.1
                                                                 RSD(#>:  1.19
                 Date:
                                                                 RSD(5O : 5.78
                                    Date: 11/I37/9';
                RSDC/0 :  9.22

Co    ID: CHECK LO           Seq.  No. :  00057    A/S Pos. : 6

uL dispensed: 10 from 0, 5  from 40,  10  from 6
                                                                  Dates 11/07/91
-------
  . e i, -
  . ement
           Co""
  Print .Data: Main+Suppl.
  Print: Calib. Curve+Elem. Params.
                                      Analyst: HOLSTE
                                      Peak Storage:  1  Repl. /Sample
•1
  INSTRUMENT: 4100 ZL
  Wavelength: £40.7 Peak
  Signal Type: Single Beam
  Read Time: 3. 0
  Sample Replicates: S
  Standard Replicates: £
                                    Technique: HGA            Version:  7.30
                                    Slit: 0.£0 Low
                                    Signal Measurement:  Peak  Area
                                    Read Delay: 0.0           HOC Time:  £

                                    Spike Replicates:  Same  as Sample
(CALIBRATION:
Solutions 1 ID 1C
1 1
IPal-ih RlanL/ 1 QTH Rl QKlll 1
Standard 1 1 STD l=£5ug/L 1
Standard £ 1 STD £=50ug/L 1
(Standard 3 1 STD 3=100ug/L 1
Reslope Std. IReslope 50ug/L 1
. Diluent Location: 0
1 Modifier #1 Location: 40
* Calibration Units: ug/L
j,l Calibration Type: Nonlinear
•Furnace Time/Temperature Program:
SteplTemp Ramp Hold Gas Flow Read
"| 1 1 110 1 £0 £50
Iff £ 1 130 1 £5 £50
3 11400 5 £0 £50
4 l£400 04 0 *
1 5 l£500 1 5 £50
* Injection Temp: £0 Pipette
(SEQUENCE :
Step Action and Parameters
1 Pipet diluent + modifier 1
1 £ Run HGA steps 1 to End

one 1 Locat ion 1 Volume Diluent Modifier
1 1 Volume #1 #£
£5.01 115 15 5
50.01 1 1 10 10 5
100.01 £ 1 10 10 5
50.01 1 1 10 10 5
Modifier #£ Location:
Sample Units: ug/L
Gas Type
Norm
Norm
Norm
Norm
Norm
Speed: 100^ Extraction System: On
-i- spike +• sample/std

Recalibrat ion Typei
Locations: None
                      Autozero Only
 l
*«*
1
Cone.  Above Calibration Action: Dilute & Reanalyze After  1
Alternate Sample Volumes  (uL): 5,2,1
Run Alternate Volume Blanks: No
                                                              Rep
If '/.RSD > £0.0      and Concentration > 5
Check #RSD on: Samples + Standards + Spikes
   then Retry
QC Samples
                                                                  t imes
  Recovery Measurements:
  5  uL of 50 ug/L Standard at
  Measure Recovery on Samples:
  Add to QC Samples: Yes
                             Location 1  Gives
                             9,10,£1,££
                                    % Recovery
                                                      £5.0  ug/L
                                                 Limits:  75  to  1£5
-------
tt.l ft/S  I   QC  Sample    I     Cone.  Limits      I After I Periodic! fit '[Couifjie fisl

l' L04-'lCy=30ug/L     '£7^Wer    3^Pger     'Calibl   ChSCk IEnd'  Sample  '
£    0   ICB              -2.0       £.0
3    5   CCV=60ug/L      48.0       7£. 0                  XX
4    0   CCB              -2.0       £.0                   XX
Run Periodic QC  Samples:  Every 10
Out of Limit fiction:  FVint  Message Only

Matrix Check Calculations:
'/• Difference for Dupls:  No      Locations:
% Recovery for Spike:  No        Locations:         Cone:
-------
             rile: CO. BEL
     Date: . 11/07/97
     Data File: EB179.DAT
     Technique: HGA
                              Element: Co
                              Time: 11:08
                              ID/Wt File: EB179. IDW
                              Calib.  Type: Nonlinear
     Co     ID:A185-£6-lC fH        Seq.  No.:  00057    A/S Pos.: 9

  I  uL  dispensed: 10 from 0, 5  from  40,  10 from 9
     Sample abs.  is greater than  that  of the largest standard.
     Replicate  1                            Time: 11:10
I     Peak  Area (A-s): 0.476                  Peak Height  (A): 0.5£3
     Blank Corrected Pk Area  (A-s): 0.467
     Concentration (ug/L  ):  166.9
                                                             Wavelength: £40.7
                                                             Slit: 0.S0 L
                                                             Lamp Current:  30
                                                             Energy: 49
                                                 u "w *VW *V*WW f\t *VW *W  :  0. 185
Concentration (ug/L  ): 65.9           Corrected Cone  (ug/L  ):  3£9.

uL dispensed: 18  from  0,  5 from 40,  £ from 9
                                        Time:  11:18
                                        Peak Height  (A):  0.££7

                                        Corrected Cone  (ug/L  )

                                        SD: 4.57
      ID: la5-£6-lCF^P^5     Seq.  No. : 00060    A/S  Pos. :  9
      /?* -«s - », X,      ^  '^'^ In/fv
uL dispensed: 13  from 0,  5 from 40, 5 from  1, £ from 9
Replicate  1                            Time:  11:21
Peak Area (A-s):  0. £40                 Peak Height  (A):  0. £63
Blank Corrected Pk  Area (A-s):  0. £31
Concentration (ug/L  ):  8£. 1            Corrected Cone (ug/L  )
Replicate  £  (Peak  Stored)
Peak Area  (A-s) :  0. 177
Blank Corrected Pk  Area (A-s):  0.167
Concentration  (ug/L  ): 59.4

Mean Cone  (ug/L   ):        6£.6
Corrected Cone  (ug/L   ):  313.
Co
                                                           i £97.

                                                           RSDC/) : 7. 30
                                                                       Date:  11/07/97
                                                                       410.
     uL  dispensed:  13 from 0, 5  from  40,  5 from 1,  £ from 9
     Replicate   £ (Peak Stored)              Time: 11:£4
     Peak  Area  (A-s): 0.£61                  Peak Height  (A): 0. £88
     Blank Corrected Pk Area  (A-s): 0. £51
     Concentration  (ug/L  ): 89.3            Corrected Cone  (ug/L   ):  447.
-------
                             _
Mean Cone   (ug/L  ):       Si. 7        SD :  5.13
Corrected Cone (ug/L  ) : 4£S.

Recovery  is  9£.t'/.
                  ^ -\v\-i
Co     ID:185-£&-lC L        Seq. No.: 00061     fl/S Pos. : 10     Date:  11/07/9.--
         A
uL dispensed:  10 from 0, 5 from 40, 10 from  10
Replicate   1                            Time:  11:£6

                                                                      ^
Concentration  (ug/L  ): 77.1                                     """
Peak flrea  (fl-s):  0.££6                 Peak Height  (fl):  0. £75
Blank Corrected Pk  flrea (fl-s): 0.£17
uL dispensed:  10 from 0, 5 from 40, 10 from  10
Replicate   £  (Peak Stored)             Time:  1 1 : £9
Peak flrea  (fl-s): 0. ££9                 Peak  Height  (fl) :  0. £80
Blank Corrected Pk flrea (fl-s) : 0. ££0
Concentration  (ug/L  ): 78.1

Mean Cone   -------
  'V, 'Vw •

  Co',
      ID: 1S5-E6-1D
--V A, ••:• --w -V -V •-•-• --V .-V •->.. •-:• -V- -V .V. -V- -V -w •"v.. -VW .-

      Seq. No.: 00064
                                                    A, --W -V -V, -V  :  8.815                  Peak  Height (fl) : 8. 03£
  Blank Corrected Pk  flrea (fl-s): 0.085
  Concentration  (ug/L  ): 1.9

  uL dispensed:  18  from 8,  5 from 48,  10  from  £2
  Replicate  £  (Peak Stored)
  Peak flrea  (fl-s):  0.016
  Blank Corrected  Pk flrea  (fl-s): 0.086
  Concentration  (ug/L  ) : £.3
Mean Cone  (ug/L   ):
  Co
     £.1
                                          Time:  11:49
                                          Peak Height (fl) : 0.031
                                           SD:  8. £6
      ID: 185-£6-lD L
      Seq. No.:  88866
                                                    fl/S Pos.: ££
  uL dispensed: 5  from  8,  5 from 48, 5 from  1,  10 from ££
  Replicate  1                            Time:  11:5£
  Peak flrea (fl-s):  8.863                 Peak Height (fl) : 8.874
  Blank Corrected  Pk  flrea  (fl-s): 8.854
  Concentration (ug/L  ):  19.1

  uL dispensed: 5  from  8,  5 from 48, 5 from  1,  18 from ££
  Replicate  £  (Peak  Stored)              Time:  11:55
  Peak flrea (fl-s):  8.868                 Peak Height (fl) : 8.068
  Blank Corrected  Pk  flrea  (fl-s): 0.050
I
  Concentration  (ug/L  ):  17.9

 j Mean Cone   (ug/L   ):        18.5         SD:  0.84

 'Recovery is 65.5%    (outside of specified  limits)
                                                                   'V 't --„ ^ -V -V .-„ 
-------
Replicate   i
Pea.k Area  (A-s):  0.160
Blank Corrected  Pk Area  : 0. 151
Concentration (ug/L  ): 53.6
                                        Peak Height  (A) :  0. 157
Mean  Cone  (ug/L  ):       53.4         SD:  0.20

QC  sample is  within range 48.0 - 72.0
                                                                 RSD(54): 0.37
Co
       ID:  CCB
                              A*<^ *\» A**^*V\* *V *^ *\»^w *V A^A* A**\

                              Seq. No.: 00068
                                                  A/S Pos. : 0
                                                                  Date:  11/07/91
uL dispensed:  10 from 0, 5 from 40,  10  from  0
Replicate  1                            Time: 12:02
Peak  Area (A-s) : 0.013                  Peak  Height (A)
Blank Corrected  Pk Area (A-s): 0.004
Concentration  (ug/L  ): 1.3

uL dispensed:  10 from 0, 5 from 40,  10  from  0
Replicate  2 (Peak Stored)              Time: 12:05
Peak  Area (A-s): 0.013                  Peak  Height (A)
Blank Corrected  Pk Area (A-s): 0.004
Concentration  (ug/L  ): 1.3
                                                          0.031
                                                          0.026
Mean Cone   (ug/L  ):         1.3

QC sample  is  within range -2.0 -2.0
                                        SD:  0. 01
Co     ID:  185-26-1C4L
                    FH
                                                                 RSD(5O: 0.77
                                           A,A.A,^
                              Seq.  No.: 00069    A/S Pos.:  10    Date: 11/07/9'
uL dispensed:
Replicate   1
                 from  0,  5 from 40,  10 from 10
                                        Time: 12:14
Peak Area  (fi-s) :  0.241
Blank Corrected  Pk Area (A-s): 0.231
Concentration  (ug/L  ): 82.2
                                        Peak Height  (A): 0.285
uL dispensed: 10  from  0,  5 from 40,  10 from 10
Replicate   2  (Peak Stored)
Peak Area  (A-s):  0.236
Blank Corrected  Pk Area (A-s): 0.227
Concentration  (ug/L  ): 80.6
Mean Cone   (ug/L   ):
                            81.4
                                        Time: 12:17
                                        Peak Height  (A):  0.276
                                        SD:  1.10
                                                                 RSD
Co
      ID: 185-26-1C  L
                              Seq.  No.: 00070
                                                  A/S Pos.:  10
                                                                  SD C/.):  1.35  |

                                                                  *W'\/'V\**V*VV*W'W*l*'V^
                                                                  Date: 11/07/91
uL dispensed:  5  from  0,  5 from 40, 5 from  1,  10  from  10
Replicate   1                            Time:  12:19
Peak Area  (A-s):  0.257                 Peak Height  (A): 0.273
Blank Corrected  Pk  Area (A-s): 0.248              .
Concentration  (ug/L  ):  88.2                   "£  /-
                                             /7/
-------
  uL      :                 5 from 4O, b  from  1,  Itf from 1W
  Repucate   £  (Peak Stored)              Time:  !£:££
  Peak Area  (A-s):  0.279                  Peak Height (A): 8.292
  Blank Corrected Pk Area (A-s): 0. £&9
  Concentration  :
A* *\t *V *V A* *V *\f 'V

Co    ID:  185-£6-lD
                            5.5
                             Seq.  No.
                                          Time:  1£:32
                                          Peak Height (A)
                                          SD:  0.83
                                                            0.040
                                          00073
                                                    A/S Pos. :  £1
   uL dispensed: 5  from 0,  5 from 40, 5 from  1,  10 from £1
«   Replicate  1                            Time:  1£:35
   Peak Area  (A-s):  0.070                 Peak Height (A): 0.087
   Blank Corrected  Pk  Area  (A-s): 0.060
^Concentration (ug/L  ):  21.3
lill
 I
  uL dispensed: 5 from  0,  5 from 40, 5 from  1,  10 from 21
  Replicate  £  (Peak  Stored)              Time:  12:37
  (Peak Area  (ft-s):  0. 07£                 Peak Height (ft): 0.085
  Blank Corrected Pk  Area  (A-s): 0.063
  Concentration (ug/L  ):  ££. £
                                                                         N'ft
                                                                   RSDC/.): 95.35
                                                                    Date:  11/07/9?
                                                                   RSD(%):  15. 1£
                                                                    Date:  11/07/97

                                                                            ^xv-riq-rv
-------
Mean Cone   : £.0

uL dispensed:  10 from 8,  5 from 48,  18 from ££
Replicate   £  (Peak Stored)             Time:  1£:4£
Peak Area  (A-s) : 0. 01&                 Peak Height  (ft):  0.033
Blank  Corrected Pk Area (ft-s) :  8. 88&
Concentration  (ug/L  ): £. £

Mean Cone   (ug/L  ):         £.1        SD: 8.15                 RSD(%>: 7.11


Co     ID:  185-E6-1D L        Seq. No.: 88875    A/S  Pos.:  ££    Date: 11/87/97

uL dispensed:  5 from  8, 5 from  40,  5 from 1,  10 from ££
Replicate   1                            Time:  1£:45
Peak Area  (A-s) : 0.864                 Peak Height  (A):  0.076          \\-»-------
1
   Co'.    iL>:  CCB                Seq. No. : 00077    fl/S Pos. :  0     Date: 11/07/9"
*  ul_ dispensed: 10 from 0,  5  from 40,  10  from  0
i   Replicate  1                            Time:  1£:55
'fc  Peak flrea (ft-s): 0.016                  Peak  Height (fl):  0.029
§  Blank Corrected Pk flrea  (fl-s): 0.006
   Concentration (ug/L   ):  2.3
I

I
uL dispensed: 10  from  0,  5 from  40,  10 from 0
Replicate  £  (Peak  Stored)              Time: 12:58
Peak flrea :  0.009                 Peak Height (ft): 0.022
Blank Corrected Pk  ftrea (fi-s): -0.000
Concentration 
-------
Element File: BE.GEL
»
Loc.  Concentration
  8
  1
  4
  5
  6
  7
  a
  9
 10
 11
 1£
 13
 14
 15
 16
 17
 18
 19
 £0
 £1
 ££
 £3
 £4
 £5
 £&
 £7
 £3
 £9
 30
 31
 40
50.0 ug/L
      ID/Weight File: EE.:.~->;

 Solut ions

 Calib.  Blank / Diluent / I
 Stock  / Recovery Stock 1-
 ICV=15.0ug/L  |
 CCv=30.0ug/L  I
 CHECK  LO
 4345£  MB
 4345£  LCS

 185-E6-1C L
 185-£6-£C
 185-£&-3C
 185-£&-4C
 185-£&-5C

 185-£6-7C
 185-£6-8E
 185-£&-8H
.185-£&-9C
 185-£6-10C
 185-£&-lD
 185-£6-lD L
 185-£&-£D, 12,
 185-£&-3D
 185-£fe-4D
 1S5-E6-5D
 185-£6-6D
 185-£fe-7CD
 185-£6-8DE
 185-£&-9D
 185-£6-10D
 Modifier 1
-------
  Element:  tj e
 ^Print  Data: Main+Suppl.
  Print:  Calib.  Curve
                                     Analyst:  BENNETT
                                     Peak  Storage:  1  Repl./Sample
(INSTRUMENT: 4100 ZL
Wavelength: £34.9 Peak
Signal Type: Zeeman AA
IRead Time : 3. 0
Sample Replicates: £
Standard Replicates: £
1 CALIBRATION:
Solutions 1 ID
1
If* -s 1 •» H n 1 =,T-, b 1 C.-TH Rl QKlk*
Standard 1 ISTD1= 10ug/L
Standard £ 1 STD£= £5ug/L
- Standard 3 1 STD3= 50ug/L
1 Reslope Std. l£5ug/L
Samples I — —
Diluent Location: 0
1 Modifier #1 Location: 40
» Calibration Units: ug/L
Calibration Type: Linear
1 — .
Furnace Time/Temperature Program
SteplTemp Ramp Hold IGas Flow Re
m 1 1 110 1 £5 £50
1 £ 1 130 1 £0 £50
* 3 I1500 5 15 £50
4 l£300 03 0
15 l£500 1 5 £50
Injection Temp: £0 Pipett
I SEQUENCE :
Step fiction and Parameters
1 Pipet diluent +• modifier
_ £ Run HGA steps 1 to End
• CHECKS:
Recal i brat ion Type: Reslope
1 Locations: None
Technique: HGA Version: 7-30
Slit: 0.7 Low
Signal Measurement: Peak Area
Read Delay: 0.0 BOC Time: £
Spike Replicates: Same as Sample
Cone Location Volume Diluent! Modifier
Volume 1 ttl tt£
10 5 1 5
10.0 1 £ 13 1 5
£5.0 1 5 10 1 5
50.0 1 10 515
£5.0 1 5 10 1 5
~~ 1 *.' *J t i_f
Modifier tt£ Location:
Sample Units : ug/L
•
ad 1 Gas Type
1 Norm
1 Norm
1 Norm
* 1 Norm
1 Norm
e Speed: S5/4 Extraction System: On
1 + spike +• sample/std

  Cone.  Above Calibration Action: Dilute & Reanalyze After  1 Rep
  (Alternate Sample Volumes (uL): 5, £, 1
  Run  Alternate Volume Blanks: No

  If #RSD >  £0.0      and Concentration > 0. £      then Retry  1  times
I Check  '/.RSD on: Samples + Standards + Spikes + QC Samples
I
Recovery Measurements:
5  uL of 50 ug/L Standard at Location  1   Gives      £5.0 ug/L
Measure Recovery on Samples: 9,10,£1,££
Add to QC Samples: Yes               %  Recovery  Limits:  85 to 115
-------
#.l fl/S
!• Loc.
'l
a
3
4
Run
Out
4
0
5
0
1 QC Sample
1 ID
ICV=
ICB
15.

CCV=30.
CCB
Peri odic
of
Limit

QC
0ug/L

0ug/L

Sampl
flct ion :
1 Cone.
1 Lower
13.5
-1.0
£4.0
-1.0
es: Every 10
Reslope and
Limits 1
Upper 1
1&
1.
36
1.

. 5
0
.0
0

Rerun Samples
                                              I fif t er I Per i uu ii_:i n I  iwii'-iT.^    \
                                              ICalibl  Check  I End I  Sample 1
                                                X
                                                X
                                                         X      X
                                                         X      X
Matrix Check Calculations:
% Difference for Dupls: No     Locations:
% Recovery for Spike: No       Locations:         Cone:
-------
  Element File: BE.GEL
  •Date: 11/10/97
  Data File: EB188.DAT
  Technique: HGA
                              Element: Be
                              Time: 10:54
                              ID/Wt File: EB180.IDW
                              Calib. Type: Linear
                                                            Wavelength:  £34.9
                                                            Slit:  0.7 L
                                                            Lamp Current:  30
                                                            Energy:  66
*V\»*

Be
        ID: STD BLANK
                              Seq.  No. :  00001
                                                 A/S Pos. :  0
                                                                 Date:  11/10/97
I



I



I



I



I



I



I



I



I



I



I
uL dispensed: 5 from  0,  5 from 40,  10 from 0
Replicate  1                            Time: 10:57
Peak Area (A-s): 0.004                  Peak Height  (ft):  0.004
Background Pk Area  (A-s):  0.014        Background Pk Height  (A):  0.014
Blank Corrected Pk  Area  (ft-s): 0.002
Concentration : 0.010        Background Pk Height  (A)
Blank Corrected Pk Area  (A-s): 0.001
Concentration  -------
-v •-•-• •"•_- •"•_ •
                                                                           « ' V • \f • '/J
Be
ID: STD£= £5ug/L
Seq. No.:  00004
                   A/S Pos.:  1
                                    Date
uL dispensed:  10  from  0,  5 from 40,  5
Replicate   1
Peak Area  (A-s):  0.1S1
Background  Pk  Area  (A-s):  0.286
Blank Corrected Pk  Area (A-s):  0.179
Concentration  -------
I
I
,1
I
I
I
 I
I
                           Display Calibration - CiXftfl II
                   ^^~^~^^~^~~~^^^~~~^^
Be
      ID: STD1=  10ug/L
                               Seq.  No.
                                        00006
                                                 fl/S Pos. :  1
                                                                   Date:  11/10/97
uL dispensed: 13  from  0,  5  from 40,  £
Replicate  1
Peak flrea  (fl-s):  0.064
Background Pk ftrea   : 0.140
Blank Corrected Pk  flrea 
-------
Loncentrat i on  (ug/L  ) :  lib. tj                       *

Mean .Cone  (ug/L   ):        £&.£         SD:  8.5&                RSD<'/O: £.15

Standard number £  applied.   CSS.fl]
Correlation coefficient:  0.99832       Slope:  ®.
-------
(Display Calibration  -  C:\Afl

                        .
                Slttfttti fl.flfl«
                            -**«
         Concentration
                          SO.fl
-------
Element File:  BE. GEL
                              El ement :  Be
                                                                          £34.9
Technique:  HGfl
                                    F     EB1S0.IDW
                              Calib.  Type: Linear
                                                             Slit : 0. 7 L
                                                             Camp Current :
                                                             Energy: 66

Be    ID: STD  BLflNK          Seq.  No. :  00008

uL dispensed:  5  from  0,  5 from 40,  10 from 0

Be    ID: STD  BLflNK          Seq.  No. :  00009

uL dispensed:  5  from  0,  5 from 40,  10 from 0

Be    ID: STD  BLflNK          Seq.  No. :  00010
                                                  fl/S Pos.: 0
                                                 fl/S  Pos.:  0
                                                                  Date:  11/10/971
                                                                   Date:  11/18/97
                                                 ft/S Pos.:  0
                                                                  Date:  11/10/97J
uL dispensed:  5 from 0,  5 from 40, 10 from 0
     i^r^r^ff^f^fr^ft^ft^t^t^ff^ri^t^f^ff^ff^f^tf^fr^e^f^f^i^ff^
Be
ID: ICV=15.0ug/L
                              Seq.  No.: 00011
                                                 fi/S  Pos.:  4
                                                                  Date:  11/10/91
uL dispensed:  5 from 0,  5 from 40, 10 from 4
Replicate   1                            Time:  11:56
Peak flrea  4) : 8.89
-------
  Be              	            Seq.  No. :  00013    ft/S Pos. : 6
                                                                    Date:  11/10/9
I  'uL dispensed: 5 from  0,  5  from  40,  10 from 6
  Replicate  1                            Time: 1£:17
.  Peak fires,  (fl-s): 0.001                  Peak Height (ft): 0.003
I  Background Pk flrea  (fl-s):  0.009        Background Pk Height  (ft): 0.015
1  Blank Corrected Pk  flrea  (fl-s):  -0.001                                             j
  Concentration 
-------
Be
       ID:  185-£6-lC
                              Seq.  No.: 00016
                                                  A/S  Pos.:  -7
-uL  dispensed:  5 from 8, 5 from 40, 10 from 9
The background signal is changing during BOC measurement.
Replicate   1
Peak Area  (A-s):  0.017
Background  Pk  Area (A-s):  0.119
Blank Corrected Pk Area :  0.006
Background Pk  Area   :  0.099
Blank Corrected Pk  Area  : 0.0£1
                                        Background Pk Height   :  0.005                 Peak Height  (A):  0. 0£6
 Background  Pk  Area  : 0.003
 Concentration  (ug/L  ):  0.4

 uL  dispensed:  5 from 0,  5 from 40, 10 from 9
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.004
Background Pk Area  (A-s):  0.105
Blank Corrected Pk  Area (A-s):  0. 00£
Concentration  (ug/L  ):  0.3
                                        Time: 1£:39
                                        Peak Height  (A): 0. 0££
                                        Background Pk Height  (A)
                                                                   0. 19£
Mean Cone   (ug/L   ):
Be
                             0.3
                                        SD: 0.10
                                                                 RSDCX): 30.34
      ID: 185-E6-1C  ft
                              Seq.  No. :  00018
                                                 A/S Pos. : 9
                                                                  Date:
                                                                        ll/10/9"/t
uL dispensed: 5  from  40,
Replicate   1
Peak Area  (A-s):  0.004
Background  Pk Area  (A-s):  0.108
Blank Corrected  Pk  Area (A-s):  0.00£
Concentration  (ug/L  ):  0.3
                          5 from £,  10 from 9
                                        Time: 1£:4£
                                        Peak Height  (A): 0. 0£1
                                        Background Pk Height  (A):
                                                                    . ££6
uL  dispensed:  5 from 40,  5 from £, 10 from 9
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.004
Background Pk Area  (A-s):  0.110
Blank Corrected Pk  Area  (A-s):  0.001
Concentration (ug/L  ):  0. £
                                        Time: 1£:44
                                        Peak Height  (A): 0.031
                                        Background Pk Height  (A)
                                                                   0. £49
Mean Cone   (ug/L   ):         0. £        SD: 0. 06

Recovery is -1.6%    (outside of specified limits)
                                                                 RSD(3i): £4.84
-------
 Be    ,„; Aoo-c:&-lC  fi>>     Seq.  No.:  00019    fl/S Pos.: 9      Date:  11

 uL dispensed: 5  from  40,  5  from £,  10 from 9
 Replicate  1                            Time: 1£:47
 Peak flrea (fl-s): 0.004                  Peak Height  (fl): 0.031
 Background Pk flrea  (fl-s): 0.109        Background Pk Height  (fl):  0. £45
 Blank Corrected  Pk flrea  (fl-s):  0.001
 Concentration (ug/L   ):  0. £

 uL dispensed: 5  from  40,  5  from £,  10 from 9
 Replicate  £ (Peak Stored)              Time: 1£:49
 Peak flrea (fl-s): 0.004                  Peak Height  (fl) : 0.0£5
 Background Pk flrea  (fl-s): 0.108        Background Pk Height  (fl):  0. £46
 Blank Corrected  Pk flrea  (fl-s):  0.00£
i Concentration (ug/L   ):  0.£

 Mean Cone  (ug/L  ):         0. £        SD: 0.05                 RSD(%): £1.7£

I Recovery is —£.£#    (outside of specified limits)
I Be    ID: 185-£6-lC L         Seq.  No.: 000£0    fl/S Pos.:  10     Date:  11/10/97

 uL dispensed: 5 from 0,  5  from 40,  10 from 10
I Replicate  1                            Time: 12:52
 Peak ftrea (fl-s): 0.001                  Peak Height  (fl) : 0. 0££
 Background Pk flrea  (fl-s):  0.084        Background Pk Height  (fl):  0.161
-Blank Corrected Pk flrea  (fl-s): -0.001
I Concentration (ug/L  ) :  —0. £

 uL dispensed: 5 from 0,  5  from 40,  10 from 10
I Replicate  £ (Peak Stored)              Time: 1£:54
 Peak Area (fl-s): 0.000                  Peak Height  (fl) : 0.022
 Background Pk flrea  (fl-s):  0.078        Background Pk Height  (fl):  0.149
I Blank Corrected Pk flrea  (fl-s): -0.00£
 Concentration (ug/L  ):  -0.3

-Mean Cone  (ug/L  ):        -0. £        SD: 0.07                 RSD(#): 31.79


 Be    ID: 185-£6-lC L         Seq.  No.: 000£1    fl/S Pos.:  10     Date:  11/10/97

I uL dispensed: 5 from 40, 5 from £,  13 from 10
 Replicate  1                            Time: 1£:57
I Peak ftrea (fl-s): 0.003                  Peak Height  (fl) : 0.023
 Background Pk flrea  (fl-s):  0. 08£        Background Pk Height  (fl):  0.144
 Blank Corrected Pk flrea  (fl-s): 0.000
.Concentration (ug/L  ):  0.0

' uL dispensed: 5 from 40, 5 from £,  18 from 10
 Replicate  £ (Peak Stored)              Time: 1£:59
 Peak flrea (fl-s): 0.003                  Peak Height  (ft) : 0.0£7
 Background Pk flrea  (fl-s):  0. 08£        Background Pk Height  (ft):  0.146
 Blank Corrected Pk flrea  (fl-s): 0.001
 Concentration (ug/L  ):  0.1

 Mean Cone  (ug/L  ):         0.1        SD: 0.08                 RSDC/O: 89. ££
-------
Kecover-y  15  b.b:.'-    '.outside of  specified  limits)

"i/ *V *\/ *\/ *V A/ *\* *V *\* *Vr r\yWtf*V *V*S *"w^ n"fLtiy *^* *^* *^* *^* *** *"** ** *** *^* *^ *^ *^* *^* A*A/'V'\*'U'\^A*'VA*A*'VA*A^'V'V'\*'V*V'\/*V:  -0.1

uL dispensed:  5 from 0,  5 from 40,  10  from  0
Replicate   2  (Peak Stored)              Time: 13:14
Peak Area  (A-s):  0.001                  Peak Height (A): 0.003
Background Pk Area (A-s): 0.011         Background Pk Height (A): 0.022
Blank  Corrected Pk Area (ft-s): -0.001
Concentration (ug/L  ):  -0.2
                                                            24
                                                                                H

-------
 QC  sample is within range  -1.0 - 1.0
                                         ^A»^

• Be     ID: 185-26-3C           Seq. No.: 00025    fl/S Pos. : IS    Date:  11/10/97

 uL dispensed: 5 from 0,  5  from 40,  10 from  1£
 Replicate  1                            Time: 13:16
I Peak  flrea (fl-s): -8.006                 Peak  Height (fl) : 0.041
I

I

I
  Background Pk flrea  (fl-s) :  0. 103        Background Pk Height  (ft): 0. 187
  Blank  Corrected Pk ftrea  (ft-s):  -0.008
  Concentration (ug/L   ):  —1.2

  uL dispensed: 5 from  0,  5  from 40,  10  from  1£
  Replicate  2 (Peak Stored)              Time:  13:18
  Peak flrea (fl-s): -0.007                 Peak Height (A): 0.029
  Background Pk flrea  
-------
mean  uonc  *. ug/ t_   .» :        —»6f. •+         ou s  *.•. t-w                          x   w !

*VA/A\rA/A/A*A*A*A/A*A*A^»*A>.A//^A*A/A»A*Af A*AyA*A*A*A*A$A*A*A*A*A/A*A*A*A^
Be     ID: l&5-lfe-6d"'V  "l""'"'7 "" Seq. No.:  00028    A/S Pos. :  15    Date:  11/10/9:

uL dispensed: 5 from 0,  5 from 40,  10 from  15                                 w
Replicate  1                              Time: 13:30
Peak  Area (A-s): 0.001                   Peak Height  (A):  0.005
Background Pk Area  (A-s) : 0.035         Background Pk Height (A): 0.080
Blank Corrected Pk Area  (fl-s): -0.001
Concentration  (ug/L  >:  -0.2

uL dispensed: 5 from 0,  5 from 40,  10 from  15
Replicate  2 (Peak Stored)               Time: 13:32
Peak  Area (A-s): 0.001                   Peak Height  (A):  0.004
Background Pk Area  :  -0.2

Mean  Cone  (ug/L   ):        -0.2         SD:  0.03                 RSDC/4):  14.97

/\, A/ A* A/ A/ A* A* A* A* A* A* A/ A*^ A* A/ A/ A/ A* A/ A* A* A* A* A/ A* A* A/ A/ A/ A/ A* A/ A/ A* A* A/ A* A/ A* A* A* A* A* A* A/ A* A/ A* A* A* A* A* A* A* A^
           irs-sZ-^p^  > I/ A/ *V A/ 
-------
  Be     iij! lUD-c-'b-BH           Beq.  No.:  00031    A/S pos. :  18     Date:  11/10/97

  uL  dispensed: 5 from 0,  5  from  40,  10 from IS
  Replicate  1                            Time: 13:44
I  Peak Area (A-s): 0.000                  Peak Height  (A):  0.003
  Background Pk Area (A-s):  0.017        Background Pk Height  (A):  0.037
  Blank Corrected Pk Area   :  0.004
 'Background Pk Area (A-s):  0.012        Background Pk Height  (A):  0.023
  Blank Corrected Pk Area  (A-s):  -0.002
 • Concentration (ug/L  ):  -0.3

  Mean Cone  (ug/L  ):        -0.3        SD: 0.01                 RSDC/O: 4.62
I
+,

1
                             /»»,/:  -2.0

  Mean Cone  (ug/L  ):        -1.8        SD: 0.19                 RSDC/O: 10.40
  Be    ID:  185-26-10C "'   *~  Seq.  No.:  00033    A/S Pos.: 20     Date:  11/10/97
11

I uL dispensed: 5 from 0, 5  from  40,  10 from 20
  Replicate  1                            Time: 13:53
  Peak Area (A-s): 0.000                  Peak Height  (A): 0.005
  [Background Pk Area  (A-s): 0.049         Background Pk Height  (A):  0.103
  Blank Corrected Pk Area  (A-s): -0.002
  Concentration (ug/L  ):  -0.3

  uL dispensed: 5 from 0,  5 from 40,  10 from 20
  Replicate  2 (Peak Stored)              Time: 13:56
  Peak Area (A-s): 0.001                  Peak Height  (A): 0.010
  Background Pk Area  (A-s): 0.037         Background Pk Height  (A):  0.079
  Blank Corrected Pk Area  (A-s): -0.002
  Concentration (ug/L  ):  -0.3

  Mean Cone  (ug/L  ):       -0.3         SD: 0.04                 RSDC/4): 15.61
-------
Be
      ID:  185-£6-lD
                              Seq. No.: 00034
                                                  ft/S Pos.:  El
                                                                  Date:  11/10/91
uL dispensed:  5 from 0,  5 from 40, 10 from £1
Replicate   1                            Time:  13:58
Peak Area  (fl-s):  0.001                 Peak Height (fl) :  0.011
Background  Pk  flrea (A-s): 0. 0££        Background Pk Height  (A): 0.054
Blank Corrected Pk Area  (A-s): -0.001
Concentration    : 0. 0£0        Background Pk Height  (ft) : 0.050
Blank Corrected Pk Area  (A-s) : -0. 00£
Concentration  
-------
 L-onc                     oc.. ?

 Mean .Cone   (ug/L  ):       33.4        SD:  0.73                RSDC/.): £.18
                                               ^'V'V^
IBs     ID:  CCB                Seq. No.: 80038    A/S Pos. : 0     Date: 11/10/97

 uL dispensed: 5 from 0, 5 from 40, 1® from  0
 (Replicate   1                            Time:  14:15
 Peak Area  (A-s):  0.002                 Peak  Height (ft): 0.004
 Background Pk Area (ft-s) : 0. 016        Background Pk Height (A): 0. 8£6
 Blank  Corrected Pk Area 
-------
      i_>u 1 1(_'  \uy/i_  in       i_uj. <         uju .  if, i w                          . - — —


Recovery  is 103. 7'A

t\friff\ff\tt\ff\ff\ff\fr\ff^f^^^f^t\f*^r^r^^\ff\fi^e\,r^f'vf^f\ff^

Be     ID: 185-£6-£D ,L ^.,,.,^17%^.  Mo.:  00041    fl/S Pos. : £3     Date: 11/10/97
uL dispensed:  5 from 0., 5 from 40,  10  from  £3
Replicate   1          "                  Time:  14:£9
Peak  flrea  (fl-s): 0. 0£6                  Peak Height (ft): 0.063
Background Pk  flrea  (ft-s): 0.114         Background Pk Height  (A):  0.151
Blank Corrected Pk Area (A-s) : 0. 0£4
Concentration  (ug/L  ): 3. &

uL dispensed:  5 from 0, 5 from 40,  10  from  £3
Replicate   £ (Peak Stored)              Time:  14:3£
Peak  Area   : 0. 0£4                  Peak Height (ft): 0. 060
Background Pk  Area  (ft-s) : 0.119         Background Pk Height  (ft):  0.166
Blank Corrected Pk Area (ft-s): 0. 0££
Concentration  (ug/L  ): 3.3

Mean  Cone   (ug/L  ):        3.5         SD:  0.18                 RSDC/): 5.18
Be     ID:  185-£6-3D          Seq. No.: 0004£    A/S Pos.: £4     Date:  11/18/97

uL  dispensed:  5 from 0, 5 from 40,  10 from  £4
Replicate   1                           Time: 14:34
Peak  Area  (ft-s) : 0.004                 Peak Height (A): 0.008
Background Pk  ftrea  (A-s) : 0.037        Background Pk Height  (A):  0.073
Blank Corrected Pk Area (A-s): 0. 00£
Concentration   (ug/L  ): 0.3

uL  dispensed:  5 from 0, 5 from 40,  10 from  £4
Replicate   £ (Peak Stored)             Time: 14:37
Peak  Area  (A-s): 0.004                 Peak Height (A): 0.010
Background Pk  Area  (A-s): 0.035        Background Pk Height  (A):  0.070
Blank Corrected Pk Area (A-s): 0. 00£
Concentration   (ug/L  ): 0.3

Mean  Cone   (ug/L  ):        0.3        SD:  0. 0£                 RSDC/O: 7.14
Be     ID:  185-£6-4D          Seq. No.: 00043     ft/S Pos.: £5     Date:  11/10/97J

uL dispensed:  5 from 0, 5 from 40,  10 from  £5                                   i
Replicate   1                            Time:  14:39
Peak Area  (ft-s): 0.000                 Peak Height (ft): 0.005
Background  Pk  flrea (fl-s) : 0.017        Background Pk Height  (A):  0.031
Blank  Corrected Pk Area (A-s): -O. 00S
Concentration  (ug/L  ): -0.3                                                    I

uL dispensed:  5 from 0, 5 from 40,  10 from  £5
Replicate   £  (Peak Stored)             Time:  14:4£
Peak Area  (A-s): 0.001                 Peak Height (A): 0.004
Background  Pk  Area (A-s): 0.016        Background Pk Height  (A):  0.033
Blank  Corrected Pk ftrea (fl-s): -0.001
-------
  PleaT                         -0. £        b'D:  w. Wi
I

I
I
I
I;

I

I
                                               ^^^^w^*Vf^A**\#*\/*\*i\/*vf*V'VA*^«V'\r«\/*\*'V*V«\/*\/*V/v*v«V*V«VA*«Xr *•!.••
  Be     ID:  185-26-5D           Seq.  No.:  00044    fl/S Pos.:  £6     Date: 11/10/9"

  uL dispensed: 5 from 0, 5  from 40,  10 from £6
  Replicate   1                            Time: 14:44
  Peak flrea  (ft-s): 0.001                  Peak Height (fl):  0.005
  Background Pk flrea (fl-s):  0.017        Background Pk Height  (ft):  0.033
  Blank  Corrected Pk flrea  (fl-s): -0.80£
  Concentration (ug/L  ): -0.3

  uL dispensed: 5 from 0, 5  from 40,  10 from £6
  Replicate   £ (Peak Stored)              Time: 14:47
  Peak flrea  (fl-s): 0.000                  Peak Height (fl):  0.005
  Background Pk flrea (fl-s):  0.018        Background Pk Height  (ft):  0.035
  Blank  Corrected Pk flrea  (fl-s): -0.00£
  Concentration (ug/L  ): -0.3

  Mean Cone   (ug/L  ):        -0.3        SD: 0.03                 RSD(5O: 10.3£
                         f\ff\f'\fr^f\ft\ff\f^^^ff^

   Be     ID:  185-2&-&D           Seq.  No.:  00045    fl/S Pos.:  £7     Date: 11/10/97

   uL  dispensed: 5 from 0,  5  from 40,  10 from £7
   Replicate   1                            Time: 14:49
   Peak  flrea  (fl-s): 0.000                  Peak Height  (fl):  0.004
   Background Pk flrea  (fl-s):  0.016        Background Pk Height  (fl):  0.030
   Blank Corrected Pk flrea  (fl-s): -0.00£
   Concentration (ug/L  ):  -0.3
   IuL dispensed: 5 from 0,  5  from 40,  10 from £7
   Replicate   £ (Peak Stored)              Time: 14:51
I
   Peak  flrea (fl-s): 0.001                  Peak Height  (fl) : 0.004
   Background  Pk ftrea  (fl-s):  0.016        Background Pk Height  (fl):  0.030
   Blank  Corrected Pk flrea  (fl-s):  -0.00£
   Concentration (ug/L  ):  -0.3
I
   PMean Cone   (ug/L  ):        -0.3        SD:  0.04                 RSDC/.): 13. &£
,
1
   Be     ID:  1S5-26-7CD          Seq.  No.:  00046    fl/S Pos.: £6     Date:  11/10/97

   uL dispensed:  5 from 0, 5  from  40,  10 from £8
   Replicate   1                             Time: 14:54
   Peak flrea  (fl-s): 0.00£                  Peak Height  (fl): 0.005
   Background  Pk  flrea (fl-s):  0.016        Background Pk Height  (fl):  0.0£8
   Blank  Corrected Pk flrea (fl-s):  -0.001
   Concentration  (ug/L  ): -0.1

   uL dispensed:  5 from 0, 5  from  40,  10 from £8
   Replicate   £  (Peak Stored)              Time: 14:56
   Peak flrea  (fl-s): 0.001                  Peak Height  (fl): 0.004
  Background  Pk  flrea (fl-s):  0.016        Background Pk Height  (fl):  0.0£7
  Blank  Corrected Pk flrea (fl-s):  -0.00£
  Concentration  (ug/L  ): -0. £

  Mean Cone   (ug/L  ):       -0. £        SD: 0.09                 RSDC/.): 53.31
-------
      ID: CCV=38.0ug/L
                              Seq.  No.:  00847
                                                 A/S ,-0 =
                                                                        11/10/9
uL dispensed:  5  from  0,  5 from 40,  10 from 5
Replicate   1                            Time: 14:59
Peak Area  (A-s):  0.216                  Peak Height : 0.509
Background  Pk  Area (A-s): 0.338        Background Pk Height  (A):  0.595
Blank Corrected  Pk Anea  (A-s): 0.214
Concentration  (ug/L  ):  3£. 4

ul_ dispensed:  5  from  0,  5 from 40,  10 from 5
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.217
Background Pk Area  (ft-s):  0.340
Blank Corrected Pk  flrea  (A-s):  0.214
Concentration  (ug/L  ):  3S. 5
                                        Time:  15:01
                                        Peak Height (A): 0.511
                                        Background Pk Height  (A): 0.598
Mean Cone   (ug/L   ):        3£.5        SD:  8.03

QC sample is within range  £4.0 - 36.0
                                                                 RSD(5O :  0. 10

Be
      ID: CCB
                              Seq.  No.
          0O048
A/S Pos. : 0
Date:
uL dispensed: 5  from  0,  5 from 40,  10 from 0
Replicate   1                            Time: 15:04
Peak Area  (A-s):  0.001                  Peak Height (A): 0.004
Background  Pk Area  (A-s): 0.016        Background Pk Height  (A): 0.025
Blank Corrected  Pk  Area  (A-s): -0.001
Concentration  (ug/L  ):  -0.2

uL dispensed: 5  from  0,  5 from 40,  10 from 0
Replicate  £  (Peak Stored)
Peak Area  (A-s): 0.001
Background Pk Area  (A-s):  0.015
Blank Corrected Pk Area  (A-s): -0.801
Concentration (ug/L   ):  — 0. £
                                        Time:  15:06
                                        Peak Height (A): 0.006
                                        Background Pk Height  (A): 0. 0£5
Mean Cone   (ug/L   ):        -0. £         SD:  0.00

QC sample is within range  -1.0 - 1.0
                                                                RSD(%>:  1.62

Be
      ID: 185-26-8DE
Seq. No
                                        80049
A/S Pos.: £9
                                                                 Date:
uL dispensed: 5  from 0,  5  from  40,  10 from £9
Replicate   1                            Time:  15:88
Peak Area  (A-s): 0.001                  Peak Height (A): 0.004
Background  Pk Area  (A-s):  0. 0££        Background Pk Height  (A): 0.049
Blank Corrected  Pk  Area  (A-s):  -0. 80£
Concentration  (ug/L ):  -8.3

uL dispensed: 5  from 8,  5  from  40,  10 from £9
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.081
Background Pk Area  (A-s):  0. 0££
Blank Corrected Pk  Area  (A-s):  -0.881
Concentration  (ug/L  ):  -8.2
                                        Time:  15:11
                                        Peak Height  (A): 0.004
                                        Background Pk Height (A)
-------
  Mean                        -0. £         3D:  «. W3                 Kbur/.; :  iw. t»t>
I
i
rt«
1
                                                            'W ^^*W*V *^ ^ *V*V**w*^ *^*V^^^ *V *V *\/ *V 'w ~_
Be    ID:  185-26-9D          Seq.  No.:  88050    fl/S Pos.:  38     Date: 11/10/ST

uL dispensed:  5  from 0,  5 from 48,  18 from 30
Replicate   1                             Time: 15:13
Peak flrea  (fl-s):  8.881                  Peak Height  (fl) : 8.884
Background  Pk  flrea (fl-s): 8.817         Background Pk Height  (ft): 8.829
Blank Corrected  Pk ftrea (fl-s): -8.882
Concentration  (ug/L  ):  -8.3

uL dispensed:  5  from 8,  5 from 48,  18 from 38
Replicate   2  (Peak Stored)              Time: 15:15
Peak flrea  (fl-s):  8.881                  Peak Height  (fl): 8.085
Background  Pk  flrea (fl-s): 8.816         Background Pk Height  (fl) : 8.838
Blank Corrected  Pk ftrea (fl-s): -8.882
Concentration  (ug/L  ):  -8.2

Mean Cone   (ug/L   ):       -8.3         SD: 0.02                 RSDC/O: 7.88
                                                                                  •

 Be    ID: 1S5-26-18D         Seq.  No. :  88851    fl/S Pos. : 31     Date: 11/10/97
  uL dispensed: 5 from  8,  5 from 48,  18  from 31
  (Replicate  1                             Time:  15:18
  Peak flrea (fl-s): 8.881                   Peak Height (fl) : 8.884
  Background Pk ftrea  (fl-s): 8.817         Background Pk Height  (fl) : 8.828
  (Blank Corrected Pk  flrea (fl-s): -8.081
  Concentration (ug/L   ):  -0.2

  uL dispensed: 5 from  8,  5 from 48,  18  from 31
  Replicate  2 (Peak  Stored)               Time:  15:28
  Peak flrea (fl-s): 8.881                   Peak Height (fl) : 8.884
  Background Pk flrea  (fl-s): 8.818         Background Pk Height  (fl) : 8.831
  Blank Corrected Pk  flrea (fl-s): -8.082
  Concentration (ug/L   ):  -8.3

  Mean Cone  (ug/L  ):        -8.2         SD:  0.03                 RSD(5O: 13.77
                                               ff^i\ft\ft\f
  Be    ID:  CCV=38.8ug/L        Seq. No.: 88852     fl/S Pos.: 5     Date:  11/18/97

  uL dispensed: 5 from 8,  5 from 48, 18 from  5
  Replicate   1                            Time:  15:22
  Peak flrea  (fl-s): 8.224                  Peak Height (fl) : 8.581
  Background Pk flrea  (fl-s):  8.348        Background Pk Height  (fl) : 8. &21
  Blank Corrected Pk flrea  (fl-s): 8.222
  Concentration (ug/L  ):  33.6

  uL dispensed: 5 from 8,  5 from 48, 18 from  5
  Replicate   2 (Peak Stored)              Time:  15:25
  Peak flrea  (fl-s): 8.215                  Peak Height (fl): 8.484
  Background Pk flrea  (fl-s):  8.338        Background Pk Height  (fl): 8.581
  Blank Corrected Pk flrea  (fl-s): 8.213
  Concentration (ug/L  ):  32.2

  Mean Cone   (ug/L  ):        32.9        SD:  1.88                  RSDC/4):  3.85
-------
   sampie is WIT: n in  range  c:^. W - jib.
                                               ^
Be    ID: CCB                 Seq. No. : 00053    A/S Pos. :  0      Date: ll/10/<

uL dispensed: 5 from  0,  5  from 40,  10 from 0
Replicate  1                            Time: 15:27
Peak Area (A-s): 0.002                  Peak Height  :  0.017        Background Pk Height  (A):  0.024
Blank Corrected Pk  Area  (A-s): -0.001
Concentration  (ug/L  >:  -0.1

uL dispensed: 5 from  0,  5  from 40,  10 from 0
Replicate  2  (Peak  Stored)              Time: 15:30
Peak Area :  -0.2

Mean Cone  (ug/L  ):        -0.1        SD: 0.04                 RSDC/4):  31.31

QC sample is within range  —1.0 — 1.0
-------
  M U 1- U           ..••-•'•
   ^Element File:  BEMSfl.GEL
/i!
Loc.  Concentration
      0
      1
      6
      7
      8
      9
     10
     11
     IS
     13
     14
     15
     16
     17
     IS
     19
     £0
     £1
     22
     23
     24
     25
     26
     27
     28
     29
     30
     31
     40
      ID/Weight File:  E&1S0.IDW

Solut i ons
      50.0  ug/L
                            V
           ^
                     l8f
      Calib.
      Stock
      CHECK  LO
      43452  MB
      43452  LCS
      185-2&-lC"~
    *-, 185-26-1C L
      185-26-2C
•SZ.-?,k, 185-26-3C
ri-7,/0, 185-26-4C
^2.-////iv185-26-5C
ii-13,/^ 185-26-&C
si-n,'K> 185-26-7C
-^2-/^1°,185-26-8E
      185-S6-SH
-^;-7 s-x 185-26-9C
'-Si-15-,^185-26 -10C
      185-26-1D
      185-26-1D L
      185-26-20,^
      185-26-3D
      185-26-4D
      185-26-5D
      185-26-6D
      185-26-7CD
      185-S6-8DE
      185-26-9D
      185-26-10D
      Modifier 1
                                     Blank  /  Diluent
                                i  /
                              i'/to ft 7
-------
E,l ,e m e n t File: HEMS A .GEL
El e merit : Be
Print Data: Main+Suppl.
Print: Calib. Curve
     Analyst: BENNETT
     Peak Storage:  i Repl./Sample
INSTRUMENT: 4100 ZL
Wavelength: £34.9 Peak
Signal Type: Zeeman AA
Read Time: 3.0
Sample Replicates: £
Standard Replicates: £
     Technique: HGA            Version:  7.30
     Slit: 0.7 Low
     Signal Measurement: Peak  Area
     Read Delay: 0.0           BOC  Time:  £

     Spike Replicates: Same  as Sample
CALIBRATION:
Solut ions

P\I-L ni-fcwi*
Calib. Blank
Standard 1
Standard £
C^ •* m f* 1 » e

1 ID
1
1 OTl^ Ol /"\Ml/
1 Si U tJLHNK
ISTD1= 10 ug/L
ISTD£= £5 ug/L

1 Cone 1 Location
1 1


1 10.01 1
1 £5.01 1
_ i 	 1 	

Volume

1 I7l
J. Vf
S.
5
1 171

Di luent
Volume
1 (7l
* v
13
10
1l7l

Modifier!
#1 #£ |
51
i
5 1
5 1
=: i
 Diluent Location: 0
 Modifier #1 Location: 40
 Calibration Units: ug/L
 Calibration Type: Method of Add.
     Modifier #£ Location:
     Sample Units: ug/L
Furnace Time/Temperature Prog*
SteplTemp Ramp Hold IGas Flow
1 1 110 1 £51 £50
£
3
4
5
1 130
1 1500
l£300
l£500
Inject ion
1
5
0
1
Temp
£0
15
3
5
: £0
1
1
1
1

£50
£50
0
£50





"am :
Read




Pipett


*

e
IGas Type
1 Norm
1
1
1
1
Norm
Norm
Norm
Norm





Speed: 35% Extraction System: Off
SEQUENCE:
Step  Action and Parameters
  1    Pipet diluent + modifier 1
  £    Run HGA steps 1 to End
  3    Extra washes: 1
   + spike + sample/std
CHECKS:
Additions Preparation: Automated
Periodic Autozero Locations: All Samples
If %RSD > £0.0      and Peak Area
Check %RSD on: Samples + Additions
       >  .005
then Retry 1  times
QC:
Matrix Check Calculations:
'/• Difference for Dupls: No
% Recovery for Spike: No
Locat ions
Locat ions
 Cone:
-------
  Element File:  BEMSfl.GEL      Element:  Be                    Wavelength: £34.9
  Date: 11/10/97               Time:  15:31                    Slit:  0.7 |_
  Data File: EB180.DflT         ID/Wt  File: EB1S0. IDW          Lamp Current: 30
  Technique: HGft               Calib.  Type: Method of fldd.    Energy: 6&
                                                           v*\*'\*A/'V\#lW'Vr'V'VW\«'V'V\«'VV\«'VJ\r'V '"'-""
  Be    ID: STD BLflNK           Seq.  No.:  00054    fl/S Pos.:  0     Date:  11/10/97

  uL dispensed: 10  from  0,  5 from 40,  10  from 0
  Replicate   1                            Time: 15:33
  (Peak flrea  (fl-s):  0.000                 Peak Height  (fl):  0.004
  Background  Pk flrea  (fl-s):  0.015        Background Pk Height (fl):  0.0£7
 H Blank Corrected Pk flrea (fl-s):  0.000
 i
  IuL dispensed: 10  from  0,  5 from 40,  10  from 0
  Replicate   £  (Peak Stored)              Time: 15:36
  Peak flrea  (fl-s):  0.000                 Peak Height  (fl):  0.004
  Background  Pk flrea  (fl-s):  0.014        Background Pk Height (fl):  0.0£7
  Blank Corrected Pk flrea (fl-s):  0.000

  Mean Pk flrea  (fl-s):       8.000          SD: 0.0001               RSDC/.): 41.90

  fluto-zero performed.
   Be    ID:  185-S6-1C          Seq.  No. : 00055    fl/S Pos. :  9     Date: 11/10/97

   uL dispensed:  10  from 0,  5 from 40,  10 from 9
   Replicate   1                            Time: 15:38
   Peak flrea  (fl-s):  0.008                 Peak Height  (fl) :  0.044
   Background  Pk  flrea (fl-s): 0.£08        Background Pk  Height (fl): 0.37£
   Blank Corrected Pk flrea (fl-s):  0.008

   uL dispensed:  10  from 0,  5 from 40,  10 from 9
 I  Replicate  £  (Peak  Stored)              Time: 15:41
\

1

I
 Peak flrea  (fl-s):  0.008                 Peak Height  (ft):  0.067
 Background Pk flrea (fl-s):  0.198        Background Pk  Height (fl):  0.345
 Blank Corrected Pk flrea (fl-s):  0.007

 Mean Pk flrea  (fl-s):       0.007          SD: 0.0005               RSD(K): &.££

 Be    ID: STD1= 5 ug/L       Seq.  No. :  00056    fl/S Pos. :  9     Date: 11/10/97

 uL dispensed: 5 from  40,  10 from 1,  10 from 9
 Replicate  1                            Time: 15:44
 Peak flrea  (fl-s):  0.005                 Peak Height  (fl):  0.09£
 Background Pk flrea (fl-s):  0.193        Background Pk  Height (fl):  0.341
 Blank Corrected Pk flrea (fl-s):  0.005

 uL dispensed: 5 from  40,  10 from 1,  10 from 9
 The background signal is  changing  during BOC measurement.
 Replicate  £  (Peak Stored)              Time: 15:47
Peak flrea  (fl-s):  0.006                 Peak Height  (fl):  0.07£
Background Pk flrea (fl-s):  0.183        Background Pk  Height (fl):  0.333
Blank Corrected Pk flrea (fl-s):  0.005

Mean Pk flrea  (fl-s):       0.005          SD: 0.0004               RSDC/.): 7.65
-------
•uL. dispensed: 5  from  40,  18 from £,  10 from 9
The background signal is  changing during BOC measurement.
Replicate   1                            Time: 15:49
Peak ftrea  (fl-s):  0.806                  Peak Height  (fl) : 0.852
Background  Pk flrea  (ft-s) :  8.184        Background Pk Height  (fl) :  0.327
Blank Corrected  Pk  flr,ea  (fl-s):  0.085

uL dispensed: 5  from  48,  18 from £,  10 from 9
Replicate   2  (Peak  Stored)              Time: 15:52
Peak flrea  (fl-s) :  8. 80&                  Peak Height  (fl> : 0.857
Background  Pk ftrea  (fl-s):  8.191        Background Pk Height  (ft):  0.393
Blank Corrected  Pk  flrea  (fl-s) :  0. 086
Mean Pk flrea  (fl-s):
 0.005
                                        SD: 0.0083
Standard  abs.  & cone,  values are not in the same order.
Be     ID:  185-26-1C          Seq. No.: 88855    fl/S Pos. :  9
                                                                 RSDC/O:  5.48


                                                                  Date:  ll/10/<=
Concentration  (ug/L   ):
Be
      ID: STD BLfllMK
     Seq. No.: 88858
                                                 fl/S Pos.:  8
                                                                  Date:  11/18/9
 uL  dispensed:  18 from 8,  5 from 40,  10
 Replicate   1
 Peak flrea  (fl-s):  -8.888
 Background  Pk  flrea (fl-s): 8.828
 Blank  Corrected  Pk flrea (fl-s): -8.881

 uL  dispensed:  18 from 8,  5 from 48,  18
 Replicate   2  (Peak Stored)
 Peak flrea  (fl-s):  8.800
 Background  Pk  flrea (fl-s): 0.817
 Blank  Corrected  Pk flrea (fl-s) : -8.
                                        from  0
                                        Time: 15:55
                                        Peak  Height (fl) : 8.885
                                        Background Pk Height  (fl) : 0.840
                                        from 0
                                        Time:  15:57
                                        Peak Height (fl) : 0.005
                                        Background Pk Height  (fl) : 8.829
Mean Pk flrea  (fl-s):

fluto-zero performed.
-0.080
                                        SD: 0.0003
                                                                RSDC/O: 86.13
Be
      ID: 185-26-1C L
     Seq. No.: 88059
                                                 fl/S Pos.:  10
                                                                 Date:  11/10/9
uL dispensed:  18  from  0,  5 from 40,  10
Replicate   1
Peak flrea  (fl-s):  8.884
Background  Pk  flrea  (fl-s):  8.136
Blank Corrected Pk  ftrea  (fl-s):  8.084

uL dispensed:  18  from  8,  5 from 48,  18
Replicate   2  (Peak  Stored)
Peak flrea  (fl-s):  8.005
Background  Pk  flrea  (fl-s):  0.138
Blank Corrected Pk  flrea  (A-s):  8.004

Mean Pk flrea  (fl-s):       8.884

Be    ID: STD1= 5 ug/L       Seq.  No. :
                                        from  18
                                        Time:  16:00
                                        Peak  Height (fl) : 8.838
                                        Background Pk Height  (fl) : 8.247
                                        from  18
                                        Time:  16:83
                                        Peak  Height (fl) :  0.047
                                        Background Pk Height  (fl) : 0.256
                                        SD:  8.8005              RSD(5t):  11.16

                                        00868     fl/S Pos. : 18    Date:
-------
  uL c \ - •" -   __   _..-...
  Peplicate  1
  Peak  Area  (A-s):  8. 042
  Background Pk  Area  (A-s) :  i3. 198
  Blank Corrected Pk  Area (A-s):  0
                          10 from 1,  10  from  10
                                         Time:  16:06
                                         Peak  Height (A): 0.132
                                         Background Pk Height  (A): 0.335
I
1
uL dispensed: 5  from 40,  10 from
Replicate  2  (Peak  Stored)
Peak Area  (A-s):  0.045
Background Pk Area  (A-s): 0.205
Blank Corrected  Pk  Area -
                                           (tethod^o-F_ft«W. ^..--
                                           C»rir. £«««.: A.9*44
                                           Slttttttl - 	
                           -0-5
                                     Concentration
                                                     to.fl
-------
•Be   "ID:  STD BLANK           Seq.  No. :  00062    A/S Pos. :  0      Date: ll/llZ)/'

uL  dispensed: 10 from 0,  5  from  40,  10  from 0
Replicate   1                            Time: 1&:17
Peak  Area  (A-s): 0.001                  Peak Height (ft):  0.004
Background Pk Area  (ft-s): 0.015         Background Pk Height   rtZ,
Be     ID:  185-2&-2C           Seq.  No. :  00063    A/S Pos. :  11     Date: 11/10/9

uL  dispensed: 10 from 0,  5  from  40,  10  from 11                                \
Replicate   1                            Time: 16:22
Peak  Area  (A-s): -0.008                 Peak Height -------
      Hrea  (ft-s):  -0.002                Peak Height  -------
 !h(3  background  signal is changing during  BQC measurement.
Replicate   1                             Time:  16:49
Peak Area  (A-s):  -0.005                 Peak  Height (A): 0.111_.   ,„
Background  Pk Area (A-s): 0.193         Background Pk  Height (A): 0.
Blank  Corrected Pk Area  (A-s): -0.085

uL dispensed: 5 from .40, 10 from 1,  10  from  12
The  background  signal is changing during  BOG  measurement.
Replicate   £  (Peak Stored)               Time:  16:5£
Peak Area  (A-s):  -0.004                 Peak  Height (A): 0.089
Background  Pk Area : 0.468
Blank  Corrected Pk Area 
-------
 •~v *\* ~w •"!.• 'V «^.' -"V '"V '^> -X- 'V 'V '"V -V ~w JV\i -"W 'W *V 'V 'V '"V "w *W 'W -"W -*W •%.- •"•»-• ^V :\f -~-w "•_!• J\j «„• ---u- *\rf -"X.- -"W -\j *V 'W rt • -^/ 'S, ^.--..- r
 Be    ID: 185-£:6-4c  '" '' '"   Seq.  No. : 00071    fl/S Pos. : 13    Date: 11/10/T.-

 uL dispensed:  10 from 0, 5 from 40,  10 from 13
 Replicate  1                             Time: 17:05
 Peak flrea (fl-s): 0.00£                  Peak Height (A): 0.009
 Background Pk  flrea (fl-s>:  0.070         Background Pk Height  : 0.018                  Peak Height (fl): 0.077
 Background Pk  flrea (fl-s):  0.090         Background Pk Height  (fl): 0.143
 Blank Corrected Pk flrea (fl-s): 0.017

r uL dispensed:  5 from 40, 10 from  1,  10 from 13
 Replicate  £  (Peak Stored)              Time: 17:13
I Peak flrea (fl-s): 0.014                  Peak Height (fl): 0.057
 Background Pk  flrea (fl-s):  0.080         Background Pk Height  (fl): 0.138
 Blank Corrected Pk flrea (fl-s): 0.013

I Mean Pk flrea  (fl-s):       0.015          SD: 0.00£9               RSDCX): 18.73

 Be    ID: STD£= 10 ug/L      Seq.  No.: 00073    fl/S Pos.: 13    Date: 11/10/97

I uL dispensed!  5 from 40, 10 from  £,  10 from 13
 Replicate  1                             Time: 17:16
I Peak flrea (fl-s): 0. 0£3                  Peak Height (fl) : 0. 07£
 Background Pk  flrea (fl-s):  0.089         Background Pk Height  (fl): 0.154
 Blank Corrected Pk flrea (fl-s): 0.0£3

1 uL dispensed:  5 from 40, 10 from  £,  10 from 13
'Replicate  £  (Peak Stored)              Time: 17:19
 Peak flrea (fl-s): 0.017                  Peak Height (fl) : 0.059
F Background Pk  flrea (fl-s):  0.077         Background Pk Height  (fl) : 0. 13£
 Blank Corrected Pk flrea (fl-s): 0.017

I Mean Pk flrea  (fl-s):       0. 0£0          SD: 0.0041               RSDC/4): £0.99

 Be    ID: STD£= 10 ug/L      Seq.  No. : 00074    fl/S Pos. : 13    Date: 11/10/97
i
 uL dispensed:  5 from 40, 10 from  £,  10 from 13
 Replicate  1                             Time: 17:££
 Peak flrea (fl-s): 0.015                  Peak Height (fl) : 0.053
 Background Pk  flrea (fl-s):  0.077         Background Pk Height  (ft): 0.1£5
 Blank Corrected Pk flrea (fl-s): 0.015

 uL dispensed:  5 from 40, 10 from  £,  10 from 13
 Replicate  £  (Peak Stored)              Time: 17:£4
-------
Peak Area  (ti-si :  0. Wlc:
Background Pk Area  : 0.000
Background  Pk  Area :  0.01S
Blank Corrected  Pk Area -------
 Blank                 __.  (A-s) : 0.004

 Mean Pk Area  (A-s):      0.804          SD:  0.0002

 Be    ID: STD£=  10  ug/L       Seq.  No. :  00078    A/S Pos. : 14
                                                          RSDC/4) : 4.74

                                                           Date: 11/10/97
 uL dispensed: 5 from 40,  10 from £,  10  from  14
 Replicate  1                            Time:  17:43
 Peak Area  (A-s): 0.006                  Peak  Height (ft): 0. 0£8
 Background Pk Area  (A-s): 0.047         Background Pk Height  (A): 0.095
 Blank Corrected Pk  Area  -------
Replicate   2  (Peak Stored)
Peak .Area  (A-s):  0.080
Background  Pk  Area (A-s):  0.009
Blank Corrected  Pk Area (A-s):  -0.000
                                        Time: 17:51
                                        Peak Height  : 0.004
                                        Background Pk Height  (A):  0.018
                                                                              ~
Mean Pk  Area  (A-s) :
Auto-zero  performed.
                          0.000
                                 SD: 0.0005
                                                                RSDC/O:  183.10
Be
ID: 185-26-6C
                              Seq.  No.:  00080
                                                 A/S Pos.:  15
Date: 11/10/97
uL dispensed:  10 from 0,  5 from 40,  10
Replicate   1
Peak Area  (A-s):  0.001
Background  Pk  Area (A-s):  0.015
Blank Corrected  Pk Area (A-s):  0.000

uL dispensed:  10 from 0,  5 from 40,  10
Replicate   £  (Peak Stored)
Peak Area  (A-s):  0.000
Background  Pk  Area (A-s):  0.014
Blank Corrected  Pk Area (A-s):  0.000
Mean Pk  Area  (A-s):

Be     ID:  STD1= 5 ug/L
                          0.000

                              Seq.  No.:
ul_ dispensed:  5  from  40,  10  from  1,  10
Replicate   1
Peak Area  (A-s):  0.004
Background  Pk  Area (A-s):  0.020
Blank Corrected  Pk Area  (A-s):  0.003

uL dispensed:  5  from  40,  10  from  1,  10
Replicate   2  (Peak Stored)
Peak Area  (A-s):  0.003
Background  Pk  Area (A-s):  0.020
Blank Corrected  Pk Area  (A-s):  0.003

Mean Pk Area  (A-s):      0.003

Be    ID: STD£=  10 ug/L       Seq.  No. :

uL dispensed:  5  from  40, 10  from  2,  10
Replicate   1
Peak Area  (A-s):  0.005
Background  Pk  Area (A-s):  0.024
Blank Corrected  Pk Area  (A-s):  0.005

uL dispensed:  5  from  40, 10  from  2,  10
Replicate   2  (Peak Stored)
Peak Area  (A-s):  0.006
Background  Pk  Area (A-s):  0.023
Blank Corrected  Pk Area  (A-s):  0.006
                                        from 15
                                        Time: 17:54
                                        Peak Height  : 0.004
                                        Background Pk Height  -------
                 ug/i_  > : 0.1
 Correlation  coefficient: 0.99173
                                        Slope:  0.0005
I

I

I

I
                                    Calibmian -  CiXAfl
Be
           *V *V *V *V *V *\* *N* *V *V *V *\* A/ *\*- *\* A* *V A* A* A* *V *V *V A* *V

        ID:  STD BLflNK          Seq.  No.

               00083     fl/S Pos. : 0
                                                                  Date:  11/10/97
uL dispensed:  10  from 0,  5 from 40, 10
Replicate  1
Peak flrea  (fl-s):  0.001
Background Pk  flrea  (fl-s): 0.010
Blank Corrected Pk  flrea  (fl-s): 0.000

uL dispensed:  10  from 0,  5 from 40, 10
Replicate  2  (Peak  Stored)
Peak flrea  (fl-s):  0.000
Background Pk  flrea  (fl-s): 0.010
Blank Corrected Pk  flrea  (fl-s): -0.000
                                          from 0
                                          Time: 18:10
                                          Peak Height   :
  fluto-zero  performed.
-0.000
                                          SD: 0.0004
                                                                  RSD<%) :  £14.00
                          A* A* *\* *Vf «\* *\/ *Vr ** *V A* A/ 
-------
Mean Pk Area  (A-s):       tf. 001         SD:  0. 0Wti5                       1S&.1

Be    ID: STD1=  5  ug/L        Seq.  No.:  00885    fl/S Pos. :  16     Date: 11/10,
uL dispensed:  5  from  40,  10 from 1,  10 from 16
Replicate   1                            Time: 18:£1
Peak Area  :  0.003                  Peak Height  (A): 0.009
Background  Pk  Area  (A-s):  0.019        Background Pk Height  (A):  0.030
Blank Corrected  Pk  Area  :  0.003                  Peak Height  (ft): 0.009
Background  Pk  ftrea  (ft-s):  0. 0S0        Background Pk Height  (ft):  0.031
Blank Corrected  Pk  Area  (A-s):  0.003

Mean Pk flrea  (A-s):       0.003          SD:  0.0001               RSDCX): 4.36

Be    ID: STDS=  10  ug/L       Seq.  No.:  00086    fl/S Pos.:  16     Date:  11/10/'

uL dispensed:  5  from  40,  10 from £,  10 from 16
Replicate   1                            Time: 18:£6
Peak Area  (A-s):  0.006                  Peak Height  (A): 0.013
Background  Pk  Area  (A-s):  0. 0£5        Background Pk Height  (A):  0.037
Blank Corrected  Pk  Area  (A-s):  0.006

uL dispensed:  5  from  40,  10 from £,  10 from 16
Replicate   S  (Peak  Stored)              Time: 18:£9
Peak Area  (A-s):  0.005                  Peak Height  (A): 0.011
Background  Pk  Area  (A-s):  0.0£4        Background Pk Height  (A):  0.035
Blank Corrected  Pk  Area  (A-s):  0.005

Mean Pk Area  (A-s):       0.005          SD:  0.0008               RSD(5O:  16.37

Be    ID: 185-£6-7C           Seq.  No. :  00084    A/S Pos. :  16     Date:  11/18/9

Concentration  (ug/L   ): 3.5

Correlation coefficient: 0.99£98       Slope:  O.0004
-------
                                  Calibration - C; \ftft
                  *V A* *V *V A* *\
Be
        ID:  STD BLflNK
Seq. No
                                       00087
fi/S Pos.: 0
                                                                 Date:  11/1(3/97
uL dispensed: 10 from
Replicate  1
Peak flrea : 0.000
                           5 from 40,  10  from  0
                                          Time:  18:32
                                          Peak  Height (fl): 0.004
                                          Background Pk Height  (fl): 0.018
  uL dispensed: 10 from 0, 5 from 40,  10
nil Replicate  S  :  0.030
                                        Background Pk Height  (ft):  0.268
                                        from 17
                                        Time: 18:39
                                        Peak Height  (fl) :  0.022
                                        Background Pk Height  (fl) :  0.271
Mean Pk flrea  (fl-s):
                           0.008
                                       SD:  0.0022
                                                                 RSD<*): 26.27
-------
-Be
ID:  185-26-BE
Seq.  No.: 00089
fl/S Pos.: 17
                                                                  Date:
 uL  dispensed:  10 from 0, 5 from 40, 10 from  17
 The background signal is changing during BOC  measurement.
 Replicate  1                           Time:  18:42
 Peak ftrea (A-s): 0.005                 Peak Height  (fl) :  0.020
 Background Pk  flrea (tf-s): 0.152        Background Pk  Height (fl) : 0.274
 Blank Corrected Pk ftrea (fl-s): 0.005

 uL  dispensed:  10 from 0, 5 from 40, 10 from  17
 The background signal is changing during BOC  measurement.
 Replicate  £ (Peak Stored)             Time:  18:45
 Peak Orea (fl-s): 0.005                 Peak Height  (ft):  0.023
 Background Pk  flrea (fl-s): 0.153        Background Pk  Height (fl): 0.269
 Blank Corrected Pk flrea (fl-s): 0.004

 Mean Pk ftrea (fl-s):      0.004         SD: 0.0003               RSD(5t): 5.95

 Be     ID: STD1= 5 ug/L       Seq.  No. : 00090    fl/S Pos. :  17    Date: 11/10/9

 uL  dispensed:  5 from 40, 10 from 1, 10 from 17
 The background signal is changing during BOC  measurement.
 Replicate  1                           Time:  18:47
 Peak flrea (fl-s): 0.049                 Peak Height  
-------
\-
      A etc i on  coefficient: 0.99817
                                          Slope:  0.0085
                          "{Display Calibration - C;\ftfl II*
                         0.0**-,
                           -ff-5
                                     Concentration
                                                     a .
                                                     £.»*««
                                                     10.0
  Be
       ID: STD  BLflNK
                              Seq.  No. :
                                           fl/S Pos. :  0
\

I
uL dispensed: 1® fir-oro 0,  5 from 40, 18
Replicate  1
Peak flrea  : 0.001
Background Pk Area  w»w»w
I Background  Pk flrea  (fl-s): 8.818
* Blank Corrected  Pk flrea  (fl-s): -8.


I
                                     881
                                          from  0
                                          Time: 18:58
                                          Peak  Height  : 69.30
Be
ID: 185-26-8H
                              Seq.  No.: 08893
                                                   fl/S Pos.: 18
                                                                    Date:  11/18/97
 uL dispensed:  18 from 8, 5 from 48,  18
 Replicate   1
 Peak flrea  (fl-s): 8.001
 Background  Pk  flrea (fl-s): 0.818
 Blank Corrected  Pk flrea  (fl-s): 0.088

, uL dispensed:  10 from 0, 5 from 40,  18
\ Replicate   2  (Peak Stored)
 Peak flrea  (fl-s): -8.888
 Background  Pk  flrea (fl-s): 8.818
 Blank Corrected  Pk flrea  (fl-s): -8.888
                                          from 18
                                          Time:  19:83
                                          Peak Height (fl) : 0.084
                                          Background Pk Height  (fl) :  8.817
                                          from 18
                                          Time: 19:86
                                          Peak Height (fl): 8.884
                                          Background Pk Height  (fl):  8.817
 Mean Pk flrea  (fl-s):
                           8. 000
                                        SD: 0.8885
                                                           RSDC/-) :  1781. ££
-------
Be    ID: 3TD1=  S ug/L       'deq. No. :  WWW's *»    H/"o v-'»-.- -  ««=>    «««,«     '' *•"*.* "

uL dispensed:  5  from Aw,  id from 1,   18 from 18
Replicate   1                       '     Time: 19:09
Peak flrea  (fl-s):  0.WW£                 Peak Height  (fl) :  0.006
Background  Pk  flrea (fl-s): 0.015        Background Pk Height  (ft): 0. 0£3
Blank Corrected  Pk flrea (fl-s): 0.002
                       *
uL dispensed:  5  from 40,  10 from 1,   10 from 18
Replicate   £  (Peak Stored)              Time: 19:11
Peak flrea  (A-s):  0.003                 Peak Height  :  0.007
Background  Pk  ftrea (ft-s): 0.015        Background Pk Height  
-------
J
                          HlDisplau Calibration - C.'XAfl
                                                       ftt
                         -9-1
                                   Concentration
                                                   IB.fl
I
Be    ID:  STD BLflNK
                             Seq.  No.
00096
ft/S Pos. : 0
Date: 11/10/97
. uL dispensed:  10 from 0,  5 from 40,  10
I Replicate   1
* Peak flrea  (fl-s): 0.001
  Background  Pk  Area (fl-s) :  0.010
1 Blank Corrected Pk flrea (fl-s): 0.001

  uL dispensed:  10 from 0,  5 from 40,  10
| Replicate   £  (Peak Stored)
I Peak flrea  (fl-s): 0.001
  Background  Pk  flrea (ft-s) :  0.009
  Blank Corrected Pk flrea (fl-s): 0.000
                                        from 0
                                        Time: 19:£0
                                        Peak Height  (ft): 0.00&
                                        Background Pk Height  (ft):  0.013
                                        from 0
                                        Time: 19:££
                                        Peak Height  (ft): 0.005
                                        Background Pk Height  (fl):  0.017
Mean Pk flrea (fl-s):

fluto-zero performed.


Be    ID: 185-£6-9'c
                           0.000
                                        SD: 0.0001
                         R3DC/.) :  13.40

                               Seq. No. : 00097
                                                 fl/S Pos.:  19
                          Date: 11/10/97
  uL dispensed:  10 from 0,  5 from 40, 10
  Replicate   1
  Peak flrea  (fl-s):  -0.01£
  Background  Pk  flrea (fl-s): 0. ££7
  Blank Corrected  Pk flrea (fl-s): -0.013

  uL dispensed:  10 from 0,  5 from 40, 10
  Replicate   £  (Peak Stored)
  Peak flrea  (fl-s):  -0.011
  Background  Pk  flrea (fl-s): 0. ££7
  Blank Corrected  Pk flrea (fl-s): -0.011

  Mean Pk flrea  (fl-s):     -0.01£

  Be    ID: STD1=  5 ug/L       Seq. No. :
                                        from 19
                                        Time: 19:£5
                                        Peak Height  (fl): 0. 101
                                        Background Pk Height  (fl):  0.457
                                        from 19
                                        Time: 19:£7
                                        Peak Height  (fl): 0.091
                                        Background Pk Height  (fl):  0.44£
                                        SD: 0.0011               RSDC/.) :  9. 1£

                                        00093    fl/S Pos.:  19     Date:  11/10/97

-------
uL dispensed:  5  fVom 40,  10 from 1,  10 from 19
Replicate   1                            Time: 19:30
Peak Area  :  -0.015      ^        Peak Height(A):.0.092
Background  Pk  Area (A-s):  0.208        Background Pk Height  (A):  &.
Blank Corrected  Pk Area : 18.12  j

 Date: 11/10/97]
uL dispensed:  5  from 40,  10 from 2,  10 from 19
Replicate   1                            Time: 19:35
Peak Area  (A-s):  -0.014                Peak Height  (A): 0.093
Background  Pk  Area  (A-s):  0.216        Background Pk Height  (A):  0.379
Blank Correcte'd  Pk  Area (A-s):  -0.014

uL dispensed:  5  from 40,  10 from 2,  10 from 19
Replicate   £  (Peak  Stored)              Time: 19:38
Peak Area  (A-s):  -0.010                Peak Height  (A): 0.080
Background  Pk  Area  (A-s):  0.193        Background Pk Height  (A):  0.362
Blank Corrected  Pk  Area (A-s):  -0.010
Mean Pk Area  (A-s):
                         -0.012
          SD: 13.0028
                                   RSDC/> : 22.25
Standard abs.  &  cone,  values are not in the same order.
Be     ID:  185-26-9C          Seq.  No. :  00097    A/S Pos. :  19     Date:  Il/ll3/f7|
Concentration  (ug/L  ):

Be
       ID: STD BLANK
Seq. No. : 00100
                   A/S  Pos. :  0
 Date: 11/18/97
uL dispensed:  10  from  0,  5 from 40,  10 from 0
Replicate   1                            Time: 19:41
Peak Area  (A-s):  0.001                 Peak Height  (A): 0.005
Background  Pk  Area  (A-s): 0.014        Background Pk Height  (A):  0.016
Blank Corrected Pk  Area (A-s):  -0.000
uL dispensed:  10  from  0,  5 from 40,  10 from 0
Replicate  £  (Peak  Stored)              Time: 19:43
Peak Area  (A-s):  -0.000                Peak Height  (A): 0.004
Background Pk  Area  (A-s):  0.013        Background Pk Height  (A)
Blank Corrected Pk  Area (A-s):  -0.001
Mean Pk Area  (A-s):

Auto—zero performed.
                         -0.000
                                                                   J. 017
          SD: 0.0005
                                   RSD(*>: 135.43
Be
      ID:  185-26-10C
Seq.  No.: 00101     A/S  Pos.:  £0    Date:
uL dispensed:  10  from  0,  5 from  40,  10 from 20
-------
Peak' .-,. =<=i  \n-s;:  w
Background  Pk  Area (A-s): 0.015
Blank  Corrected  Pk Area  (A-s): 0.081

uL dispensed:  10 from 0,  5 from 40, 10
Replicate   £  (Peak Stored)
Peak Area  (A-s):  0.000
Background  Pk  Area <,7 »<__
Be    ID: 185-£&-10C         Seq. No.:

Concentration  (ug/L  ): 0.£

Correlation coefficient:  0.99933
from £0
Time: 19:51
Peak Height  (A):  0.030
Background Pk Height  (A):  0.068
from £0
Time: 19:54
Peak Height  (A):  0.030
Background Pk Height  (A):  0.06£
3D: 0.0004

00103    A/S Pos. :  £0
                         RSD C/.): 3.7S

                          Date:  11/10/97
from £0
Time: 19:57
Peak Height  (A):  0.060
Background Pk Height  (A):  0.105
from £0
Time: 19:59
Peak Height  (A):  0.049
Background Pk Height  (A):  0.091
SD: 0.00£1

00101    A/S Pos. :  £0



Slope: 0. 00£0
                             %): 10.39

                          Date: 11/10/97
-------
MJfK«tn1aii  falibra*inn -  f;\»A
.0*0
            Concentration       tfi.fi
-------
Auto               ^   ._._
 ' £l*ment File: BEMSfl.GEL
»
  Loc.  Concentration
    0
    1
    6
    7
    a
    9
    10
    11
    12
    13
    14
    15
    16
    17
    18
    19
    20
    21
    22
    23
    24
    25
    2&
    27
    23
    29
    30
    31
    40
50.0 ug/L
  M. ^h1
  &
                           ID/Weight File: EB1SO.IDW

                      Solut ions
 Calib.  Blank  /  Diluent
 stock      i-64-^P   $*0
 CHECK  LO
 43452  MB
 43452  LCS
 185-26-1C —
 185-26-1C  L
 135-26-2C
 135-26-3C
.135-26-4C
 185-2fe
 185-26
 l 85-26
 185-26
 185-26
 185-26
 185-26
 185-26
 185-26
 185-26
 185-26
 185-26
 1S5-26
 1 35-26
 Modifi
                            -8H
                            -9 C
                            - 10C -
                            - ID
                            - ID L
                            -2D
                            -3D
                             4D
                             5D
                            -6D
                            -7CD
                            -8DE
                            -9D
                            -10D
                            er 1

ii
-------
b i e m e ri T. i- i i s
              0CLI'IOI-i. OC.L-
El ernsnt : Be
      Data: Main+Suppl.
      : Calib. Curve
Print
Print
Analyst: BENNETT
Peak Storage: 1 Repl./Sample
INSTRUMENT: 4100  ZL
Wavelength: £34.9 Peak
Signal Type: Zeeman Aft.
Read Time: 3.0
Sample Replicates: £
Standard Replicates: £
                                     Technique:  HGA           Version: 7.30
                                     Slit:  0.7 Low
                                     Signal Measurement:  Peak Area
                                     Read Delay:  0.0          BOC Time: £

                                     Spike  Replicates:  Same as Sample
CALIBRATION:
Solutions 1 ID
1
r^_n*L tl 1 -*•-». 1* ICTI^ QIAKIL/
Cal ID. Blank i o i JJ ttLHNK
Standard 1 ISTD1= 10 ug/L
Standard £ 1 STD£= £5 ug/L
O^mnln,- 1 	

Cone



10.0
£5.0

Locat ion



1
1

Volume

1 ff\
i  £0.0      and Peak Area
Check %RSD on: Samples •+• Additions
                                      >  .005
             then Retry 1  times
QC:
Matrix Check Calculations:
'/• Difference for Dupls: No
'/• Recovery for Spike: No
                               Locat ions;
                               Locat ions:
              Cone:
-------
Element File:  BhMSA. GEL
Date: 11/11/97
Data File: EB ISO. DAT
Technique: HGA
    Element: Be
    Time: 10:40
    ID/Wt File: EB180. IDW
    Calib. Type: Method of
                                                      Add.
                                                             Wavelength: £34.9
                                                             Slit: 0.7 L
                                                             Lamp Current: 30
                                                             Energy: 66
 Be
       ID: STD BLANK
                              Seq.  No.: 00126
                       A/S Pos.
                                                            8
                                                                  Date: 11/11/9
 uL dispensed:  10  from  0,  5  from  40,  10 from 0
 Replicate  1                            Time: 10:4£
 Peak Area  (A-s) :  0.001                  Peak Height (ft): 0.004
i Background Pk  Area  (A-s) : 0.003         Background Pk Height (A):
 Blank Corrected Pk  flrea  (A-s) : 0.001
                                                                   0. 0£5
 uL dispensed:  10  from  0,  5  from  40,  10 from 0
 Replicate  £   :  0.001                  Peak Height (A): 0.004
 Background Pk  Area  
-------
Mean l-'k ttrea  (H-S):     -0. 00£         SO:  0. 001£                        ffe.24

Be     ID:  STD£= £5 ug/L      Seq. No.: 001£9     A/S Pos.: 9     Date:  11/11/9;

uL dispensed:  10 from 0,  5 from 40, 5 from  1,  10 from 9
The background  signal is changing during BOC  measurement.
Replicate   1                            Time:  10:59
Peak Area  (A-s):  0.000*                 Peak Height  (A): 0.043
Background Pk Area (A-s): 0.143        Background Pk Height (A): 0.512
Blank  Corrected Pk Area (A-s): -0.000

uL dispensed:  10 from 0,  5 from 40, 5 from  1,  10 from 9
The background  signal is changing during BOC  measurement.
Replicate   2  (Peak Stored)             Time:  11:0£
Peak Area  (A-s):  -0.000                Peak Height  (A): 0.03£
Background Pk Area (A-s): 0.142        Background Pk Height (A): 0.510
Blank  Corrected Pk Area (A-s): -0.001

Mean Pk Area  (A-s):     -0.001         SD:  0.0001               RSDCyOs  17.39

Standard abs. & cone, values are not in the same order.
Be     ID:  135-26-1C          Seq. No.: 00127     A/S Pos.: 9     Date:  11/11/97^
Concentration  (ug/L  ):
Be     ID:  STD BLANK          Seq.  No.: 00130    A/S  Pos.:  0     Date:  11/11/97J

uL dispensed: 10 from 0,  5 from 40, 10 from 0
Replicate   1                            Time:  11:05
Peak Area  (A-s): 0.000                 Peak Height  (A):  0.003
Background Pk Area (A-s): 0.010        Background Pk Height (A): 0.029
Blank  Corrected Pk Area (A-s): -0.000

uL dispensed: 10 from 0,  5 from 40, 10 from 0
Replicate   2  (Peak Stored)              Time:  11:07
Peak Area  (A-s): 0.001                 Peak Height  (A):  0.004
Background Pk Area (A-s): 0.012        Background Pk Height (A): 0.032
Blank  Corrected Pk Area (A-s): 0.000

Mean Pk Area  (A-s):     -0.000         SD: 0.0003               RSDCfc): £103.64

Auto-zero  performed.
                                                         is t\t f\f t\t t\j i\f t\j f\r t\j fvt^ft\f*\ff\f'\f <\j *\**V *VV*\»*W
Be     ID:  '1S5-26-1C L        Seq.  No.: 00131    A/S  Pos.: 10    Date: 11/11/97
                                                                               /!
uL dispensed:  10  from 0,  5 from 40,  10 from 10
Replicate   1                            Time:  11:10
Peak Area  (A-s):  0.000                 Peak Height  (A):  0.008
Background  Pk  Area (A-s): 0.090        Background Pk Height (A): 0.171
Blank Corrected Pk Area (A-s):  -0.001

uL dispensed:  10  from 0,  5 from 40,  10 from 10
Replicate   £  (Peak Stored)              Time:  11:12
Peak Area  (A-s):  0.000                 Peak Height  (A):  0.005
Background  Pk  Area (A-s): 0.097        Background Pk Height (A): 0.173
Blank Corrected Pk Area (A-s):  -0.000
-------
t
1
                                        SD: 0.0001               RSDC/.):  £7-68

Be    ID: STD1=  10  ug/L      Seq.  No.: 0013£    ft/S Pos.:  10     Date:  ll/ll/9~

uL dispensed:  13  from  0,  5 from 40,  £ from 1, 10 from 10
Replicate  1                            Time: 11:15
Peak ftrea (fl-s):  0.001                  Peak Height  (fl): 0.005
Background Pk flrea  (fl-s):  0. 1£7        Background Pk Height  (fl) :  0.£lc:
Blank Corrected Pk  flrea (fl-s):  0.001

uL dispensed:  13  from  0,  5 from 40,  £ from 1, 10 from 10
Replicate  £  (Peak  Stored)              Time: 11:18
Peak flrea (fl-s):  0.000                 Peak Height  (fl) : 0.005
Background Pk flrea  (fl-s):  0.117        Background Pk Height  (fl):  0.196
Blank Corrected Pk  flrea (fl-s):  -0.000

Mean Pk flrea  (fl-s):       0.000         SD: 0.0005               RSDC/.):  £36.49

Be    ID: STD£= £5  ug/L      Seq.  No.: 00133    ft/S Pos.:  10     Date:  11/11/97
lit uL dispensed: 10  from  0,  5 from 40,  5 from 1, 10 from 10
 I Replicate  1                            Time: 11:£1
 I Peak ftrea  (fl-s):  0.001                 Peak Height  (fl): 0.006
  Background Pk flrea  (fl-s):  0.127        Background Pk Height  (fl):  0.£07
«| Blank Corrected Pk  flrea (fl-s): -0.000
ll.|
  uL dispensed: 10  from  0,  5 from 40,  5 from 1, 10 from 10
I  Replicate  £  (Peak  Stored)              Time: 11:24
  Peak flrea  (fl-s):  0.000                 Peak Height  (fl) : 0.006
  Background Pk flrea  (fl-s):  0.1£6        Background Pk Height  (fl):  0. £00
I  Blank Corrected Pk  flrea (fl-s): -0.000

 I Mean Pk flrea  (fl-s):      -0.000         SD: 0.0001               RSDCO: 99.64

I  Standard abs. & cone,  values are not in the same order.
  Be    ID:  185-£6-lC L         Seq.  No.: 00131    fl/S Pos.:  10    Date:  11/11/97
j
 L Concentration (ug/L ):  	
1  Be    ID: STD BLflNK           Seq.  No.: 00134    fl/S Pos.: 0      Date:  11/11/97

 F uL dispensed: 10 from  0,  5 from 40,  10 from 0
  Replicate  1                            Time: 11:27
 > Peak flrea (fl-s): 0.000                 Peak Height  (fl): 0.003
i"1' Background Pk flrea  (fl-s):  0.011        Background Pk Height  (fl) :  0.0£9
  Blank Corrected Pk flrea  (fl-s):  -0.000

  uL dispensed: 10 from  0,  5 from 40,  10 from 0
  Replicate  £ (Peak Stored)              Time: 11:29
71  Peak flrea (fl-s): 0.001                 Peak Height  (fl) : 0.003
  Background Pk flrea  (fl-s):  0.011        Background Pk Height  (fl):  0.031
  Blank Corrected Pk flrea  (fl-s):  0.000

  Mean Pk flrea (fl-s):      -0.000          SD: 0.0003               RSDC/O: 149.£1

]i  fluto-zero performed.
-------
Be  . '   ID:  'i85-£6-£C          Seq. No.: 88135    A/S Pos.:  11     Date:  ll/

uL  dispensed:  18 from 8,  5 from 48,  18 from 11
The background  signal is  changing during BOC measurement.
Replicate   1                            Time: 11:3£
Peak Area  (A-s):  8.888                 Peak Height (A): 8.859
Background Pk Area (A-s): 8.£83        Background Pk Height  (A):  8.366
Blank  Corrected Pk Area (A-s): 8.887

uL  dispensed:  18 from 8,  5 from 48,  18 from 11
The background  signal is  changing during BOC measurement.
Replicate   £  (Peak Stored)             Time: 11:35
Peak Area  (A-s):  8.811                 Peak Height (A) : 8. 844
Background Pk Area (A-s): 8.£33        Background Pk Height  (A):  8.5£1
Blank  Corrected Pk Area (A-s): 8.818

Mean Pk  Area  (A-s):      8.889         SD: 8.88££               RSDC/.): £5. £1
Be     ID:  185-£6-£C  l        Seq.  No.: 80136    A/S Pos.:  11     Date:  11/11/97

uL dispensed:  10 from 8,  5 from 40,  18 from 11                                I
The  background signal is changing during BOC measurement.
Replicate   1                            Time: 11:37                            ^
Peak Area  (A-s): 8.814                 Peak Height (A): 8.879                 I
Background  Pk  Area (A-s): 8.££5        Background Pk Height  (A): 8.439        "
Blank  Corrected Pk Area (A-s): 8.813

uL dispensed:  18 from 8,  5 from 48,  18 from 11
Replicate   £  (Peak Stored)             Time: 11:48
Peak Area  (A-s): 8.818                 Peak Height (A): 8.868
Background  Pk  Area (A-s): 8.££8        Background Pk Height  (A): 8.434
Blank  Corrected Pk Area (A-s): 8.818

Mean Pk  Area  (A-s):       8.81£         SD: 8.88£5               RSDC/O:  £1.90

Be     ID: STD1= 18 ug/L      Seq.  No.: 88137    A/S Pos.:  11     Date:  11/11/97

uL dispensed:  13 from 8,  5 from 48,  £ from 1,  18 from 11
Replicate   1                            Time: 11:43
Peak Area  (A-s): 8.81£                 Peak Height (A): 8.188
Background  Pk  Area (A-s): 8.£44        Background Pk Height  (A): 8.717
Blank  Corrected Pk Area (A-s): 8.81£

uL dispensed:  13 from 8,  5 from 48,  £ from 1,  18 from 11
Replicate   £  (Peak Stored)             Time: 11:46
Peak Area  (A-s): 8.811                  Peak Height (A): 8.1£8
Background  Pk  Area (A-s): 8.334        Background Pk Height  (A): 1.818
Blank  Corrected Pk Area (A-s): 8.811

Mean Pk  Area  (A-s):       8.811         SD: 8.8887               RSDC/):  6.38

Be     ID: STD£= £5 ug/L      Seq.  No.: 88138    A/S Pos.:  11     Date:  11/11/97

uL dispensed:  18 from 8,  5 from 48,  5 from 1,  18 from 11
Replicate   1                            Time: 11:49
Peak Area  (A-s): 8.813                 Peak Height (A): 8.188
Background  Pk  Area (A-s): 8.£69        Background Pk Height  (A): 1.841
-------
  Blan                      (A-s) : 0. 012

1    •'
| uL  dispensed: 10 from 0, 5 from 40, 5  from  1,  10 from 11
  Replicate  2 (Peak Stored)             Time:  11:52
I Peak  Area (A-s): 0.011                 Peak Height (A):  0.119
• Background Pk Area (A-s): 0.275        Background Pk Height (A): 1.027
'Blank Corrected Pk Area  (A-s): 0.011

§Mean  Pk  Area (A-s):      0.012         SD:  0.0010              RSDC/O: 8.25

  Standard abs. & cone, values  are not in  the same order.
I Be     ID: 185-26-2C           Seq. No.: 00136     A/S Pos.: 11    Date: 11/11/97

  Concentration (ug/L  ): 	

        {A/        •w^.^.w.w'
  Be     ID: STD BLANK           Seq. No.: 00139     fl/S Pos.: 0     Date: 11/11/97
ii
  4uL  dispensed: 10 from 0, 5 from 40, 10 from 0
  Replicate  1                           Time:  11:54
It  Peak  Area (A-s): 0.001                 Peak Height (A):  0.005
I  Background Pk Area (A-s): 0.017        Background Pk Height (A): 0.044
  Blank Corrected Pk Area  (A-s): 0.001

_ uL  dispensed: 10 from 0, 5 from 40, 10 from 0
I Replicate  2 (Peak Stored)             Time:  11:57
•Peak  Area (A-s): 0.000                 Peak Height (A):  0.005
  Background Pk Area (A-s): 0.019        Background Pk Height (A): 0.068
I Blank Corrected Pk Area  (A-s): 0.000

  Mean  Pk  Area (A-s):      0.000         SD:  0.0005              RSD(%): 116.13

I Auto-zero performed.
     r«\,«\/«\,s\,«w'W'X/'\&.'V
            fST -7 i
  Be     ID:  185-26-3C          Seq. No.: 00140     A/S Pos.: 12    Date: 11/11/97

  uL  dispensed:  10 from 0, 5 from 40,  10 from 12
  Replicate   1                           Time:  11:59
  Peak  Area  (A-s): 0.008                 Peak Height (A):  0.037
  Background Pk  Area (A-s): 0.178        Background Pk Height (A): 0.359
  Blank Corrected Pk Area  (A-s): 0.007

  uL  dispensed:  10 from 0, 5 from 40,  10 from 12
  Replicate   2 (Peak Stored)             Time:  12:02
  Peak  Area  (A-s): 0.010                 Peak Height (A):  0.039
  Background Pk  Area (A-s): 0.182        Background Pk Height (A): 0.350
  Blank Corrected Pk Area  (A-s): 0.009

  Mean  Pk  Area (A-s):      0.008         SD: 0.0015              RSDC/4): 18.48

  Be     ID:  STD1= 10 ug/L      Seq. No.: 00141     A/S Pos.: 12    Date: 11/11/97

  uL  dispensed:  13 from 0, 5 from 40, 2 from 1,  10 from 12
  Replicate   1                           Time:  12:05
  Peak  Area  (A-s): 0.003                 Peak Height (A):  0.081
  Background Pk  Area (A-s): 0.280        Background Pk Height (A): 1.144
  Blank Corrected Pk Area  (A-s): 0.002
-------
ui_ cjispensea:  13 rVam ti,  5 from 40, <± from  l,  id  from                         s
Replicate   £ -------
f

I
                          ed)              lime: l£:c:5
  Peak- Hrea (fl-s): 0.000                  Peak Height  (fl) :  0.004
  Background .Pk Area  (fl-s):  0.016        Background Pk Height  (fl) :  0.039
  Blank Corrected Pk  flrea (fi-s) :  -0.001

  Mean Pk flrea  (ft-s):      -0.000          SD: 0.0003               RSDC/.): 59.93

  ftuto-zero performed.
 I
4
                                             .^.v/V.V'X.A/^'V'V'W^^^^A/^^^^/v^
             Ifrr -r«- - v, ' °  nli 13/7-7 "*_
  Be    ID: 185-£6-4C           Seq.  No.: 00145    ft/S Pos. :  13    Date:  11/11/97

  uL dispensed: 10 from 0,  5 from 40,  10 from 13
  Replicate  1                            Time: 1£:£7
  Peak flrea (fl-s): 0..001                  Peak Height  -------
uL dispensed:  iv3  from W,  5 from 40,  5 from 1, 10 from
Replicate   1                            Time: IS: 44
Peak Area^A-s):  0- 00.9 v   --  •»-        £eaH Heiflb*,-,: 12.75 I

Standard abs.  & cone,  values are not in the same order.
Be    ID:  185-£6-4C          Seq.  No. :  00145    A/S Pos. : 13    Date:  11/11/97J

Concentration  
-------
 Peak  Hrea (A-s>: 0.004                 Peak  Height  (H):  0.S1£
 Background Pk Area  (A-s): 0.107        Background  Pk  Height  (A):  0.195
 Blank Corrected Pk Area  (A-s): 0.003

 uL dispensed: 13 from 0, 5 from 40, £  from  1,  10  from 14
 Replicate  2 (Peak Stored)             Time:  13:03
 Peak  Area (A-s): 0.003                 Peak  Height  (A):  0.008
 Background Pk Area  (A-s): 0.094        Background  Pk  Height  (A):  0.18£
 Blank Corrected Pk Area  (A-s): 0.00£

 Mean  Pk  Area (A-s):      0.003         SD:  0.0007               RSDC/.): £6.£0

 Be     ID: STD£= £5 ug/L      Seq.  No.: 0015£   A/S Pos.:  14    Date: 11/11/97

 (uL dispensed: 10 from 0, 5 from 40, 5  from  1,  10  from 14
 Replicate  1                           Time:  13:06
 Peak  Area (A-s): 0.001                 Peak  Height  (A):  0.007
I Background Pk Area  (A-s): 0.087        Background  Pk  Height  (A):  0.16£
 Blank Corrected Pk Area  (A-s): 0.001
I

I

I

I
i
I
uL dispensed: 10 from 0,  5 from 40,  5 from 1,  10 from 14
Replicate  £  (Peak  Stored)              Time:  13:09
Peak Area  (A-s): 0.004                  Peak Height (A): 0.011
Background Pk Area  (A-s):  0.10£        Background Pk Height  (A): 0.196
Blank Corrected Pk  Area  (A-s):  0.083

Mean Pk Area  (A-s):       0.00£          3D: 0.0018              RSDC/O: 99.73

Standard abs. & cone, values  are not in the same order.
Be    ID:  185-£6-5C          Seq.  No.:  00150    A/S Pos.: 14    Date: 11/11/97
Concentration  (ug/L   ):

Be    ID: STD BLANK           Seq.  No.:  00153    A/S Pos.: 0     Date:  11/11/97
  uL  dispensed: 10 from 0, 5 from 40,  10 from 0
1 Replicate  1                           Time:  13:11
if Peak  Area (A-s): 0.001                 Peak Height  (A):  0.004
  Background Pk Area (A-s): 0.017        Background Pk  Height (A): 0.034
. Blank Corrected Pk Area  (A-s): -0.
*uL  dispensed: 10 from 0, 5 from 40,  10  from  0
  Replicate  £ (Peak Stored)              Time: 13:14
I Peak  Area (A-s): 0.001                  Peak  Height (A):  0.005
I Background Pk Area (A-s): 0.016         Background  Pk  Height  (A): 0.035
  Blank Corrected Pk Area  (A-s): 0.000

1 Mean  Pk  Area (A-s):      0.000          SD: 0.0004               RSDC/.): 930. 1£

,, Auto-aero performed.

  ^^^A,A,.V,A,^^^~£^~~~~£^^~A,^.S,^^^
  Be     ID: 185-S6-6C    '      Seq. No.:  00154    A/S Pos.:  15    Date: 11/11/97
If
I uL  dispensed: 10 from 0, 5 from 40,  10  from  15
  Replicate  1                            Time: 13:16
•Peak  Area (A-s): 0.00£                  Peak  Height (A):  0.006
,  Background Pk Area (A-s): 0.039         Background  Pk  Height  (A): 0.080
-------
Blank Corrected  Pk  Area  :  0.001

Mean Pk flrea  (A-s):      0.001

Be    ID: STD1= 10 ug/L      Seq.  No.
                                 Peak Height  
-------
       "I Display  Calibration  - C:\flfl USERXflfl FILESXELEHEHTXBEHSfl.fiEL
                                          Method  of Add.
                                          Coir. Coef.:  8.99583
                                          Slope;  8.0882
           -5,9
                                 Concentration
Be
       ID:  STD BLflNK
Seq.  No.: 00157
                                                 fl/S Pos. :  0
Date: ll/li/%7
 uL dispensed:  10 from 0, 5 from 40, 10
 Replicate  1
 Peak  ftrea (ft-s): 0.001
 Background Pk  flrea (fl-s): 0.017
 Blank Corrected Pk flrea  (fl-s): 0.001

:. uL dispensed:  10 from 0, 5 from 40, 10
 Replicate  £  (Peak Stored)
 Peak  flrea (ft-s): 0.001
 Background Pk  flrea (fl-s): 0.018
 Blank Corrected Pk flrea  (fl-s): -0.000
                                        from 0
                                        Time:  13:33
                                        Peak Height 
-------
ilean Pk ftrea  :      -0.000         3D: 0. WWWA                        1/'/. .£

Be    ID: STD1=  13 ug/L      Seq.  No.:  00159    fl/S Pos. :  16     Date:  11/11/9]

uL dispensed:  13 from  0,  5 from 40,  2 from 1,  10 from 16
Replicate  1                            Time: 13:44
Peak ftrea (fl-s):  0. 00£                 Peak Height (ft): 0.006
Background Pk  ftrea (ft-*s> :  0. 0£0        Background Pk Height  (ft):  0.040
Blank Corrected  Pk ftrea (A-s>: 0.001

uL dispensed:  13 from  0,  5 from 40,  £ from 1,  10 from 16
Replicate  £  (Peak Stored)              Time: 13:47-
Peak Area (fl-s):  0.003                 Peak Height 
-------
        "I Display Calibration - C:\flfl USERXflfl FILES\ELEHEKT\BEHSft.fiEL
         B.B82
                                   'ft1
                                                                 'A3
                                           Nethod of Add.
                                           Corr. Coef.: B.8592B
                                           Sione: B.BBB1
             8.4
                                 Concentration
                                 25,B

 Be
      ID: STD BLANK
Seq. No.: 00161
                   A/S Pos. :
                                                           Date: 11/11/97
uL dispensed: 10 •from 0, 5 from 40,  10 from 0
Replicate  1                           Time: 13:55
Peak Area (A-s) : 0.001                 Peak Height (A):  0.006
Background Pk Area (A-s) : 0.017        Background  Pk  Height  (ft):
Blank Corrected Pk Area (A-s): -0.000
                                                                    .034
 uL  dispensed:  10 from 0,  5 from 40, 10 from 0
 Replicate   £ :  0.001
 Background Pk Area (A-s):  0.017
 Blank Corrected  Pk Area (A-s): -0.001
                                       Time:  13:5S
                                       Peak Height 
-------
Mean Pk ftrea  (A-s;:       tf. 002         SD:  0.0000
Be    ID: STD1=  10  ug/L       Seq.  No.:  08163    ft/S Pos. : 17    Date:  11/11/97]


                                                                               I
uL dispensed:  13  from  0,  5 from 40,  2 from 1,  10 from 17
Replicate  1                            Time:  14:06
Peak flrea  (fl-s):  8.012                 Peak Height (fl) : 0.072
Background Pk  flrea  (fl-s):  0.430        Background Pk Height  (ft): 0.63£
Blank Corrected Pk  flrea  (A-s):  0.011                                          j

uL dispensed:  13  from  0,  5 from 40,  2 from 1,  10 from 17
Replicate  2  (Peak  Stored)              Time:  14:39                             ,
Peak flrea  :  0.010
                                                                               i
                                                                               i
Mean Pk flrea  (fl-s):       0.010          SD:  0.0010              R3DC/): 9.97

Be    ID: STD£= 25 ug/L       Seq.  No.:  00164    ft/S Pos.: 17    Date:  11/11/97|

uL dispensed:  10  from 0,  5  from  40,  5 from  1,  10 from 17
Replicate  1                            Time: 14:11
Peak ftrea  (fl-s):  0.013                  Peak Height (fl): 0.066
Background Pk  flrea (fl-s): 0.355         Background Pk Height (fl): 0.486
Blank Corrected Pk flrea  (fl-s): 0.013

uL dispensed:  10  from 0,  5  from  40,  5 from  1,  10 from 17
Replicate  2  (Peak Stored)              Time: 14:14
Peak flrea  (ft-s):  0.014                  Peak Height (fl): 0.055
Background Pk  flrea (fl-s): 0.357         Background Pk Height (fl): 0.539
Blank Corrected Pk flrea  (fl-s): 0.014

Mean Pk flrea  (fl-s):       0.013          SD:  0.0007              RSD(5O: 5.04

The standard additions calibration curve may not be linear.
Be    ID: 185-26-8E           Seq.  No.:  00162    fl/S Pos.: 17    Date:  11/11/9"/

Concentration  (ug/L  ):  4.5

Correlation coefficient:  0.76799       Slope:  0.0005
-------
           Display Calibration - CiXflft USERXM FILg\ELEHENT\BEMSOEL
                0,013
            -4.5
                                                                  'A2
                                            Method of ftdd.
                                            Corr.  Coef.:  B.76799
                                            Slope: O.QQ85
                                  Concentration
                                  25,B
      A* A* *\* *W 
-------
Mean Pi-< Area  (H-s.»:
                          0. 000
                                        SD: d.@001
Be
      ID: STD1=  10 ug/L
                              Seq. No. : 00167
                                                 A/S Pos. :  IS
                                                                           Ha.4
-------
IBe .'  ID:  1S5-26-9C          Seq.  No.: 00173    A/S Pos. :  19    Date:  11/11/97

 i.iL dispensed:  10 from 0,  5 from 40, 10 from 19
 (The background signal is changing during BOC measurement.
 Replicate   1                            Time: 14:44
 Peak Area  (A-s): 0.007                 Peak Height  (ft): 0.050
 Background  Pk  Area (A-s) : 0.£3£        Background Pk Height  (ft): 0.788
I Blank Corrected Pk Area : 0.694
.Blank Corrected Pk Area (A-s): 0.007

1 Mean Pk  Area  (A-s):      0.007         SD: 0.0006               RSD<5O: 9.4£

I Be    ID:  STD1= 10 ug/L      Seq.  No.: 00171    A/S Pos.:  19    Date:  11/11/97

 uL dispensed:  13 from 0,  5 from 40, 2. from 1,  10 from 19
I Replicate   1                            Time: 14:49
 Peak Area  (A-s): 0.007                 Peak Height  (A): 0.151
 Background  Pk  Area (A-s): 0.350        Background Pk Height  (A): 1. 13£
• Blank Corrected Pk Area (A-s): 0.006

' uL dispensed:  13 from 0,  5 from 40, £ from 1,  10 from 19
 Replicate   £  (Peak Stored)             Time: 14:5£
I Peak Area  (A-s): 0.009                 Peak Height  (A): 0.174
f Background  Pk  Area (A-s): 0.318        Background Pk Height  (A): 0.881
 Blank Corrected Pk Area (A-s): 0.007

| Mean Pk  Area  (A-s):      0.006         SD: 0.0013               RSDC/4): £0.61

j Be    ID:  STD1= 10 ug/L      Seq.  No.: 0017£    A/S Pos.:  19    Date:  11/11/97

 uL dispensed:  13 from 0,  5 from 40, £ from 1,  10 from 19
 The background signal is changing during BGC measurement.
 Replicate   1                            Time: 14:55
 Peak Area  (A-s): 0.010                 Peak Height  (A): 0.1£1
 ^Background  Pk  Area (A-s): 0.313        Background Pk Height  (A): 0.830
 Blank Corrected Pk Area (A-s): 0.008

 uL dispensed:  13 from 0,  5 from 40, £ from 1,  10 from 19
 Replicate   £  (Peak Stored)             Time: 14:58
 Peak Area  (A-s): 0.009                 Peak Height  (A): 0.14£
 Background  Pk  Area (A-s): 0. 3£3        Background Pk Height  (A): 0.964
 Blank Corrected Pk Area (A-s): 0.008

 Mean Pk  Area  (A-s):      0.008         SD: 0.0003               RSDC/.): 3.49

 Be    ID: STD£= £5 ug/L      Seq.  No.: 00173    A/S Pos.:  19    Date:  11/11/97

 uL dispensed:  10 from 0,  5 from 40, 5 from 1,  10 from 19
 Replicate   1                            Time: 15:01
 Peak Area  (A-s): 0.005                 Peak Height  (A):  0.093
 Background  Pk  Area (A-s):  0.384        Background Pk Height  (A): 1.405
 Blank Corrected Pk Area (A-s): 0.004
-------
 uL dispensed:  i£i  from  15,  5 from 40,  5 from 1, 1@ from
' The. "background  signal  is  changing during BOC measurement.
 Replicate  £  (Peak  Stored)              Time: 15:33
 Peak Area  (A-s):  0.006                 Peak Height  (A): 0.101
 Background Pk  Area  :  0.337        Background Pk Height  (A):  0.965
 Blank Corrected Pk  Area  (A-s):  0.005                                          I

 Mean Pk Area  (A-s):    "   0.004          SD: 0.0007               RSD(%>: 15.30

 Standard abs.  & cone,  values  are not in the same order.                       j
 Be    ID:  185-£6-9C          Seq.  No. :  00170    A/S Pos. :  19    Date:  11/11/97

 Concentration  (ug/L ): 	                                              I


 Be    ID:  STD  BLANK          Seq.  No.:  00174    A/S Pos.:  0     Date:  11/11/9J

 uL dispensed:  10  from  0,  5 from 40,  10  from 0
 Replicate  1                            Time: 15:06
 Peak Area  (A-s) :  0.001                 Peak Height  (A): 0.005
 Background Pk  Area  (A-s):  0.0S0        Background Pk Height  (A):  0.045
 Blank Corrected Pk  Area  (A-s):  -0.000

 uL dispensed:  10  from  0,  5 from 40,  10  from 0
 Replicate  £  (Peak  Stored)              Time: 15:09
 Peak Area  (A-s):  0.001                 Peak Height  (A): 0.005
 Background Pk  Area  (A-s):  0.018        Background Pk Height  (A):  0.048
 Blank Corrected Pk  Area  (A-s):  -0.000

 Mean Pk Area  (A-s):     -0.000          SD: 0.0000               RSDCyO: 5.2£

 Auto—zero  performed.

 ^^^^^^~~/%,^^-V^^^~A,A,^~^~~~~~A,A,A,^A-^~^~A
-------
• .w (.1 j. ... -
PeaJj „. ==»  MI-S> :  to
Background Pk  Area  (A-s):  0.058
Blank Corrected Pk  Area  (A-s):  0.003
                                        Peak Height : 0.065         Background Pk Height (A): 0.131
Blank Corrected Pk  Area  (A-s): 0.006
Mean Pk Area  (A-s):
                          0.006
SD:
The standard additions  calibration curve may not be linear.
Be    ID: 185-£6-10C          Seq.  No. :  00175    A/S Pos. :  £0
RSDC/-) : £. 7£
                                                                 Date: 11/11/97
Concentration  
-------
flut osarapl er  Loading Map
 , Element File:  TL. GEL
  Loc.  Concentration
    0
    1
    a
    4
    5
    6
    7
    8
    9
   10
   11
   IS
   13
   14
   15
   16
   17
   Id
   19
   20
   21
   22
   S3
   24
   25
   39
50.0 ug/L
100.0 ug/L
     I
       ID/Weight File: EBit,-r. ..ww

  Solut ions

  Calib.  Blank / Diluent / ICB / CCB
  Stock   \-t '
  Stock  / Recovery .Stock
  ICy=30ug/L
                       CHECK LO
                       43452 MB
                       4345S LCS
                       185-26-6C
>fy 1S5-26-7C
jail 85-26-8E
  1S5-2&-8H
  185-26-10
  1S5-26-1D
  185-2&-lD»k.Efi
  1 S5-2&-2D •&+-, } 2.
  1 85-S6 -3D
                       1 85-26 -5D
                       185-26-6D
                       1 85-26 -7CD
                       1S5-26-8DE «$;•(-
                       185-26-10D i4
                       Modifier 1
-------
Element File:  TL.GEL
Date: 11/13/97
Data File: EB1S4.DAT
Technique: HGA
                       Element:  Tl
                       Time:  1£:30
                       ID/Wt  File:  UNTITLED
                       Calib.  Type: Nonlinear
                                                            Wavelength: £76.S
                                                            Slit: 0.70 L
                                                            Lamp Current: O
                                                            Energy: 53
Tl
ID: STD BLK
                              Seq.  No.:  00001
A/S Pos.: 0
Date: 11/18/9.
uL dispensed: 5  from  0,  5 from 39,  £0 from 0
Replicate   1                            Time:  1£:3£
Peak Area  (fl-s):  -0.001                 Peak Height  (ft): 0.006
Background  Pk Area (A-s): 0.009        Background Pk Height  (A):  0.008
Blank Corrected  Pk Area  (A-s): 0.001
Concentration  (ug/L  ):  0.4

uL dispensed: 5  from  0,  5 from 39,  £0 from 0
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  -0.001
Background Pk Area  (A-s):  0.005
Blank Corrected Pk  Area  (A-s):  0.000
Concentration  (ug/L  ):  0.£

Mean Cone  (ug/L   ):         0.3

Auto-zero  performed.
                                        Time:  1£:35
                                        Peak Height  (A): 0.006
                                        Background Pk Height  (A):  0.006
                                        SD: 0. 14
                                                          RSD(5C) : 43.40
                                                                                ,•
Tl
ID: STDl=£5ug/L
                              Seq.  No.: 0000£
A/S Pos.: 1
Date: ll/ia/9'
uL dispensed:  15 from 0,  5 from 39, 10 from  1
Replicate   1                            Time:  1£:38
Peak Area  
-------
ui_ dispensed: z>  from  w,  5 from jy,  it
Replicate  £  (Peak  Stored)
Peak Area  (A-s):  0.081
Background Pk Area  (A-s): 0.048
Blank Corrected  Pk  Area (A-s): 0.0S£
Concentration  (ug/L  ):  51.6
                                 •f r o rn  1
                                 Time:  1£:47
                                 Peak Height (A): 0.101
                                 Background Pk Height  (ft): 0.060
Mean Cone   
-------
                                                                             -
 Tl  ''   ID:  ICV=30ug/L         Seq. No. : 00005     A/S  Pos. :  4     Date:  11/18/9?

 uL  dispensed:  5 from 0,  5 from 39, £0 from  4
 Replicate   1                           Time:  13:20
 Peak  flrea  (fl-s) :  8.047                 Peak Height (A):  0.063
 Background Pk  flrea (fl-s) : 0.033        Background  Pk Height (ft): 0.033
 Blank Corrected Pk Area 
-------
     L/onc   '. '.ig/i_
Tl
      ID: 43452 MB
                              Seq.  No. :  00003
                                                  A/S  Pos. :  7
                                                                  Date: 11/13/9 V
uL dispensed:  5  from 0,  5 from 39,  £0
Replicate   1
Peak Area  (A-s):  -0.000
Background  Pk  Area (A-s): 0.003
Blank Corrected  Pk Area (A-s): 0.001
Concentration  (ug/L  ) : 0.6

uL dispensed:  5  from 0,  5 from 39,  £0
Replicate   £  (Peak Stored)
Peak Area  (A-s):  0. 00£
Background  Pk  Area (A-s): 0.002
Blank Corrected  Pk Area (A-s): 0.003
Concentration  (ug/L  >: 1.8
                                       from 7
                                        Time: 13:38
                                        Peak Height  (A): 0.006
                                        Background Pk Height  (A):  0.006
                                       from 7
                                        Time: 13:41
                                        Peak Height  (A): 0.006
                                        Background Pk Height  (A):  0.005
Mean Cone   (ug/L   ):
                             1.
                                        SD: 0.87
Tl
      ID: 43452 LCS
                              Seq. No.
                                        00009
                                                 A/S Pos. :  8
                                                                 RSDC/4):  73.31
                                                                  Date:  11/18/9
1
uL dispensed: 5 from 0,5from 39,20
Replicate  1
Peak Area  (A-s): 0.061
Background Pk Area  (A-s):  0.035
Blank Corrected Pk  Area  (A-s): 0.062
Concentration (ug/L  ): 38.9
                                       from
                                        Time: 13:44
                                        Peak Heis*t< (A):  0.075
                                        Backj3*"f}und Pk  Height  (A): 0.042
                           froj
uL  dispensed:  5 from 0,  5
Replicate   £  (Peak  Stored
Peak  Area  (A-s):  O.O
Background  Pk  Area  (A^s) : 0.038
Blank Corrected F^Area  (A-s): 0.363
Concentration  (Xg/L  ):39.£
                                    £0
Mean Cone  (ug/L
                                       from &
                                        Time: 13:47
                                        Peak Height (A): 0.079
                                        Background Pk Height  (A):  0.049
                                          _j 0.18
                                                                 RSDC/i):  0.45
                                                                              ^-B
Tl ID: 185-26-6C
uL dispensed: 5 from 0,
Tl ID: 43452 LCS
Seq. No. : 00010
5 from 39, 20 from 9
Seq. No. : 00011
A/S Pos. : 9
A/S Pos. : 8
Date: 11/18/97
Date: 11/18/97J
uL dispensed: 5  from  0,  5 from 39,  20
Replicate   1
Peak Area  (A-s):  0.064
Background  Pk Area  (A-s): 0.036
Blank Corrected  Pk  Area  (A-s): 0.065
Concentration  (ug/L  ):  40.8

uL dispensed: 5  from  0,  5 from 39,  20
Replicate   2  (Peak  Stored)
Peak Area  (A-s):  0.062
Background  Pk Area  (A-s): 0.039
Blank Corrected  Pk  Area  (A-s): 0.063
                                       from  8
                                        Time: 13:50
                                        Peak Height (A): 0.076
                                        Background Pk Height  (A):  0.047
                                       from  8
                                        Time: 13:53
                                        Peak Height (A): 0.074
                                        Background Pk Height  (A):  0.047
-------
  Mean Cone    : 0.013
I  Concentration   : 0.013
I Concentration  (ug/L  ):  7.8

  Mean Cone   S from 39,  £0  from 10
  Replicate  £  (Peak Stored)              Time: 14:11
  Peak Area  (A-s):  0.enZf3                  Peak Height  (A):  0.009
  Background Pk Area/(A-s) : 0.006         Background Pk  Height (A): 0.007
-------
Mean Cone   (ug/L  ):        £.0         SD:  1.16                 RSD ('/•): 58.57


Tl     ID:  185-£6-6C L        Seq.  No.:  00015    A/S Pos.:  10    Date:  ll/18/97j

uL dispensed:  5 from 04 5 from 39,  £0 from  10
Replicate   1                             Time: 14:13
Peak Area  (A-s): 0.004                  Peak Height  (A):  0.008                 I
Background  Pk  Area  (A-s): 0.004         Background Pk Height  (A): 0.006        I
Blank  Corrected Pk Area (A-s): 0.006
Concentration  (ug/L  ) : 3.4                                    .    J  f   i •
                                                              fP V*  -i/ I*
uL dispensed:  5 from 0, 5 from 39,  £0 from  10                      f  •'
Replicate   £  (Peak Stored)              Time: 14:16                             •
Peak Area  (A-s): 0.005                  Peak Height  (A):  0.008                 |
Background  Pk  Area  (A-s): 0.004         Background Pk Height  (A): 0.007
Blank  Corrected Pk Area (A-s): 0.006
Concentration  (ug/L  ): 3.6                                                     I

Mean Cone   (ug/L  ):        3.5         SD:  0.17                 RSD(5O: 4.9£

•\/,v~'V^~A,'\,^^^~~^^A,A,^^^^
-------
i
i
i
i
i
  Cor                    :  18. 6

  Mean Cone   
-------
Mean  L-onc  u.ig/L.  ) :       bl.D         'oij :  w. t?i-j

QC  sample is  within range 48.0 —  7£. 0
                                                                               •V--.
Tl     ID:  CCB                Seq.  No. :  000£1     fl/S Pos. :  0     Date:  11/18/97

LiL dispensed: 5 from 0,- 5 from  39,  £0  from  0
Replicate   1                             Time:  14:48                             i
Peak  flrea   :  -0.001                 Peak Height / Time: 15:01                             I
Peak  flrea  (fl-s): 0.006            /^   Peak Height  (fl) :  0.014
Background  Pk  flrea (fl-s): 0. 01&x/      Background Pk  Height (fl) : 0.014
Blank Corrected Pk flrea (ft-s>-j 0.007                                           I
Concentration  (ug/L  ): ^s^*

uL dispensed:  5 from^Sf, 5 from 39, £0 from  14                                  I
Replicate   £  (Peak/Stored)             Time: 15:04                             I
Peak  flrea  (fl-s)rX0.010                 Peak Height  (ft):  0.015
Background  Pk>£rea (ft-s): 0.015        Background Pk  Height (ft): 0.013        |
Blank Corrected Pk ftrea (ft-s): 0.011                                           I
Concentration  (ug/L  ): 6.6                      ,  /

Mean  Cone Vlug/L  ) ;	  5.6        SD:  1.45    $wfc  \1|PI  RSDC/): £6.11  j
Tl     ID:  185-£6-10C         Seq. No.: 000£3    ft/S  Pos.:  14    Date: 11/18/971

uL dispensed:  5 from 0, 5 from 39, £0 from  14
Replicate   1                            Time: 15:06                              I
Peak ftrea  (fl-s):  0.008                 Peak Height  (ft):  0.014                  ]
Background  Pk  flrea (A-s): 0.014        Background Pk Height (ft): 0.011   fl
Blank  Corrected Pk flrea  (ft-s): 0.009                                     t^(
Concentration  (ug/L  ): 5.6                                       *f,  \J^  /]    I
                                                                ,^\jj^      JJ
uL dispensed:  5 from 0, 5 from 39, £0 from  14                          f7 -I
Replicate   £  (Peak Stored)             Time: 15:09                        f'
Peak ftrea  (fl-s):  0.007                 Peak Height  (fl):  0.014
Background  Pk  flrea (fl-s): 0.016        Background Pk Height (fl): 0.01£
Blank  Corrected Pk flrea  (fl-s): 0.008
-------
Cor               _     : 4. 3
  f

Mein Cone   : 53.14
Tl    ID:  1 85-26- 1 D    t>     Seq. No.: 00025    fl/S  Pos.:  15    Date: 11/18/97
uL dispensed:  5  from 39,  5 from 2, 20 from  15
Replicate   1                            Time: 15:18
Peak ftrea  (fl-s):  0.037                 Peak Height  (fl) :  0.057
Background  Pk  flrea (fl-s): 0.026        Background Pk  Height (fl):  0.038
Blank Corrected  Pk flrea  (fl-s): 0.038
Concentration  (ug/L  ): 23.5

uL dispensed:  5  from 39,  5 from 2, 20 from  15
Replicate   £  (Peak Stored)             Time: 15:21
Peak flrea  (fl-s):  0.036                 Peak Height  (fl) :  0.058
Background  Pk  flrea (fl-s): 0.026        Background Pk  Height (fl) :  0.033
Blank Corrected  Pk flrea  (fl-s): 0.037
Concentration  (ug/L  ): 22.9

Mean Cone   (ug/L   >:    _  23.2        SD: 0.43                 RSD(5O: 1.84

Recovery is
Tl    ID: 185-£6-lD/,L        Seq.  JMo. : 00026    fl/S  Pos.:  16    Date: 11/18/97
                    firf-       &£"/**  /f/M/17
uL dispensed: 5  from  0,  5 from 39, 20 from  16
Replicate  1                            Time:  15:24
Peak flrea (fl-s):  -0.002                Peak Height  
-------
L.- O 11 c t; 11 C r • -j c i u i i  \ u y .• i_  ^  ;  i *• /•

Mean  Cone   
-------
 Mean Cone   (ug/L  ):        8-7         SD:  0. 47                 RSDCX):  78.44

 A, A/A, A/A, A, A, A, A, A, A, A/A, A, A. A, A, A< A/A, A, A/A/A, A> Ay A, A/A, A, Af A, A, A, A/A/A, A, A/A, A, A, A» A, A, A, A, A, A, A, A, A, A, A, A»^
 Tl    ID: 185-26-3D 0//  ,.  /  Seq. No.:  80038    A/S Pos. :  IS     Date:  11/18/9-
                         * /',»/wto?
 uL dispensed:  5 from 8,  5 from 39, £8  from 18
 Replicate   1                             Time: 15:48
 Peak Area (A-s):  -8.888                 Peak Height (ft):  8.886
 Background  Pk  Area (A-s): 8.888         Background Pk Height  (A):  8.887
 Blank Corrected Pk Area  (A-s): 8.881
 Concentration  :        8.9         SD:  8. £7                 RSD<*>:  31. £5
  Tl    ID:  185-26-4D &i+ , *£   Seq.  No.:  88831    A/S Pos.:  19     Date:  11/18/97
>                            |/ ( ^"0 I / }
  uL dispensed:  5  from 8, 5 from  39,  £8 from 19
  Replicate   1                             Time: 15:53
  Peak Area  (A-s):  -8.881                 Peak Height  (A): 8.885
1 Background  Pk  Area (A-s): 8.888         Background Pk Height  (A):  8.888
•Blank Corrected  Pk Area (A-s):  -8.888
  Concentration  (ug/L  ): —8. 1
I

I

I

I
uL dispensed: 5 from 8,  5 from 39,  £8 from  19
Replicate  £ (Peak Stored)              Time:  15:56
Peak flrea (fl-s): -8.881                 Peak Height  (ft):  8.886
Background Pk Area (A-s):  8.887        Background Pk  Height (A): 8.887
Blank Corrected Pk Area  (A-s): 8.888
Concentration (ug/L  ):  8.2

Mean Cone  (ug/L  ):         8.1        SD: 8. £1                 RSDOO: 38£. 98


Tl    ID: CCV=68ug/L          Seq.  No.: 8883£     fl/S Pos.:  5     Date: 11/18/97
  (uL dispensed: 5  from 8,  5 from 39,  £8  from 5
  Replicate   1                             Time: 15:59
  Peak flrea  (fl-s):  8.893                  Peak Height  (fl): 8.127
  Background  Pk ftrea (ft-s) : 8.863         Background Pk Height  (A):  8.874
I Blank Corrected  Pk ftrea (ft-s): 8.894
"Concentration  (ug/L  ):  68.1

  IuL dispensed: 5  from 8,  5 from 39,  £8  from 5
  Replicate   £  (Peak Stored)              Time: 16:0£
 Peak ftrea  (ft-s):  8.893                  Peak Height  (fl): 8.123
 Background  Pk flrea (A-s): 8.863         Background Pk Height  (A):  8.871
 Blank Corrected  Pk Area (A-s): 8.894
 Concentration  (ug/L  ):  68.2
-------
     \wUMi_   'v i-i LJ <• i_  • .        i_'«j. J.


QC sample  is within  range 48. 0 - 7£. 8
Tl    ID: CCB                 Seq. No.: 00833    A/S Pos. :  0     Date: ll/ia/97

uL dispensed:  5 from 0,  5 from 39, 20 from 0
Replicate   1                            Time: 1&:05
Peak flrea  (fl-s):  -0.002                Peak Height  (fl) :  0.007
Background  Pk  ftrea (fl-s): 0.009        Background Pk Height (fl) :  8.018
Blank Corrected Pk Area (fl-s): -0.081
Concentration  : 436.68

QC sample  is within range -2.8 -2.0
Tl     ID:  1S5-26-5D -tf)-!-       Seq. No. : 00034    ft/S Pos. : 20     Date:  11/18/971
uL dispensed:  5 from 0,  5 from 39,  20 from 28
Replicate   1                            Time: 16:11
Peak flrea  (fl-s):  0.082                 Peak Height  (fl) : 8.887
Background  Pk  flrea (fl-s): 8.884        Background Pk Height  (fl) :  8.807
Blank Corrected Pk flrea (fl-s): 0.003
Concentration  (ug/L  ):  1.9

uL dispensed:  5 from 0,  5 from 39,  20 from 20
Replicate   2  (Peak Stored)              Time: 16:14
Peak flrea  (fl-s):  -0.800                Peak Height  (fl) : 0.886
Background  Pk  flrea (fl-s): 0.005        Background Pk Height  (A):  8.006
Blank Corrected Pk flrea (fl-s): 8.001
Concentration  (ug/L  ):  0.7

Mean Cone   (ug/L   ):         1.3        SD: 0.87                 RSDCX): 66.31
Tl    ID:  185-26-6D B H-      Seq.  No.: 00035    fl/S Pos.: 21     Date:  11/18/97
uL dispensed:  5  from  0,  5 from 39,  20 from 21
Replicate   1                            Time: 16:17
Peak flrea  (fl-s):  -8.800                 Peak Height  (fl) : 8.887
Background  Pk  flrea  (fl-s): 8.807        Background Pk Height  (fl) :  8.887
Blank Corrected  Pk  flrea  (fl-s): 8.801
Concentration  (ug/L  ):  0.6

uL dispensed:  5  from  0,  5 from 39,  20 from 21
Replicate   2  (Peak  Stored)              Time: 16:20
Peak flrea  (fl-s):  0.002                 Peak Height  (fl) : 0.888
Background  Pk  flrea  (fl-s): 8.005        Background Pk Height  (fl) :  8.807
Blank Corrected  Pk  flrea  (fl-s): 0.083
-------
Mean Cone   
-------
Tl    ID:  185-26-9D ./jg/f-    y  Seq.  No.:  00039    ft/S Pos. :  £4     Date:  11/18/9
uL dispensed: 5  from  0,  5  from  39,  £0  from £4
Replicate   1                            Time: 16:41
Peak flrea   :  0.008
Blank Corrected  Pk  Area  (A-s):  0.003
Concentration   : 0.006
Background Pk Area (A-s): 0.006
Blank Corrected Pk Area (A-s) : -0
Concentration (ug/L ): -0.6
Mean Cone (ug/L ): 0.5
Tl ID: 185-£6-10D t>^r ^ /Set^-
uL dispensed: 5 from 0, 5 from 39
Replicate 1
Peak Area (A-s): 0.000
Background Pk Area (A-s): 0.006
Blank Corrected Pk Area (A-s): 0.
Concentration (ug/L ): 1.0
uL dispensed: 5 from 0, 5 from 39
Replicate £ (Peak Stored)
Peak Area (A-s): 0.002
Background Pk Area (A-s): 0.004
Blank Corrected Pk Area (A-s) : 0.
Concentration (ug/L ): £. £
Mean Cone (ug/L ): 1.6

Tl ID: CCV=60ug/L Seq.
Background Pk Height (A)
.001
SD: 1.6£
No. : 00040 A/S Pos. : £5
'n
, £0 from £5
Time: 16:47
Peak Height (A): 0.006
Background Pk Height (A)
00£

, £0 from £5
Time: 16:50
Peak Height (A): 0.007
Background Pk Height 
-------
                   «V*V'Vf'VW'W •«•-!/•«•-»'-»-•'--••"•-''-*' -•«••--• vvv w-w'V'V'V'^rw'V'V^A*'V^w^^A*^'\/n/^wA/'Vn*^w''w'V'\/'V'V'V'w'V'V'V'\f *W''.

Tl    ID:  CCB                Secl-  No- !  |Z|004£    ft/S  Pos.:  0     Date:  11/18/97
IuL dispensed:  S from 0, 5 from 39,  £0 from 0
Replicate   1                             Time:  16:59
Peak Area  (fl-s):  0. 00£                  Peak Height  (ft):  0.007
Background Pk  flrea (fl-s): 0.005         Background Pk  Height (rt): 0.008
Blank Corrected  Pk flrea  (fl-s): 0.003
Concentration  (ug/L  ): £. 1
Replicate  £  (Peak Stored)              Time:  17:0£
Peak flrea  (fl-s) :  0.001                  Peak Height  
-------
t	 J. I? Ill G7 I I Vr
£^1 e nre'n t : T1
Print Data:  Main+Suppl,
Print: Calib.  Curve
     Analyst: HOLSTE
     Peak Storage: 1
  Repl./Sample
INSTRUMENT:  4108 ZL
Wavelength:  £76.8 Peak
Signal Type:  Zeeman AA
Read Time: 4.0
Sample Replicates:  £
Standard  Replicates:  £
     Technique: HGA
     Slit:  0.70 Low
     Signal Measurement
     Read Delay:  0.0
      Peak
Version: 7-30

Area
BOC Time: £
     Spike Replicates: Same as Sample
CALIBRATION:
Solutions 1 ID 1 Cone
1 1
Standard 1 1 ADD 1 50 ug/L 1 50.0
Standard £ 1 ADD £ 100ug/L 1 100.0

Locat ion

i
£

Volume
1 ffi
10
10
i (Jt

Di luent
Vo lume
1 l7l
1 01

Modifier
#1 1 #£
er I
5 1
5 1
=: i
 Diluent Location:  0
 Modifier  #1  Location:  39
 Calibration  Units: ug/L
 Calibration  Type:  Meth. of  Add.
     Modifier #£ Location:
     Sample Units: ug/L
Furnace  Time/Temperature  Program:
SteplTemp Ramp Hold
1 1 110 5 30
£ 1 130 1 35
3 1 700 5 £0
4 I1&00 0 5
5 l£500 1 5
Gas Flow
£50
£50
£50
0
£50
Read) Gas Type
1 Norm
1 Norm
1 Norm
* 1 Norm
1 Norm






Injection Temp: £0 Pipette Speed: 80% Extraction System: On
SEQUENCE:
Step  Action  and  Parameters
   1    Pipet  diluent  + modifier 1
   £    Run  HGA  steps  1 to  End
   + spike + sample/std
CHECKS:
Additions  Preparation:  Automated
Periodic Autozero Locations:  All  Samples

If *RSD >  £0.0       and Concentration  >  1.7
Check %RSD on:  Samples
                  then Retry 1  times
QC:
Matrix Check Calculations:
'/• Difference for  Dupls:  No
•A Recovery for  Spike:  No
Locat ions
Locat ionsi
Cone:
-------
I 'glement File:  TL_MSft.BEL     Element: Tl                    Wavelength: £76.8
  Date: 11/19/97               Time: 03:25                    Slit:  0.70 L
  Data File:  EB184.DftT         ID/Wt File: EB1S4.IDW          Lamp Current: 0
•  Technique:  HGfl               Calib. Type: Meth.  of  Add.     Energy: 45
I
                t\ff\ff\ff^f^t\ff\fi\fr^j^f\fJ\ft\f^f^                                                ^v •-!_•'•.

  Tl    ID: flUTO ZERO          Seq. No.: 00044    ft/S  Pos.:  0     Date: 11/19/97
uL dispensed:  10  from  0,  5 from 39,  10 from 0
Replicate   1                            Time: 0S:£8
(Peak flrea  (fl-s):  0.802                 Peak Height  (ft):  0.012
Background  Pk  ftrea  (ft-s):  0.004        Background Pk  Height  (ft):  0.013
Blank Corrected Pk  ftrea (A-s>:  0.003
1

I
uL dispensed:  10  from  0,  5 from 39,  10 from 0
Replicate  £  (Peak  Stored)              Time: 03:30
Peak ftrea  (fl-s):  0.001                 Peak Height  (ft):  0.011
Background Pk  ftrea  
-------
u.L dispensed:  5  from 39,  10 from c., 13 from  9
Repl'icate   1                            Time: 08:45
Peak Area  (A-s):  0.067                 Peak  Height  (A):  0.123
Background  Pk  Area (A-s): 0.043        Background Pk  Height (A): 0.075
Blank Corrected  Pk Area  (A-s): 0.065

uL dispensed:  5  from 39,  10 from £, 10 from  9
Replicate  £  (Peak Stored)
Peak Area  (A-s) :  0.067
Background Pk  Area : 0.044
Blank Corrected  Pk Area : 0.074
          3D: 0.0003

          00045    A/S  Pos. :  9



          Slope: 0.0006
                RSD(50 :  0.44

                 Date:  11/19/97
                        "IDisplay Calibration - C;\ftfl I
                         0-0**-,
                                   Concentration
                                                   10D.B

Tl
       ID: AUTO  ZERO
Seq. No.: 00048
A/S Pos.: 0
Date: li/19/97*
uL dispensed:  10 from 0,  5 from 39,  10 from 0
Replicate   1                            Time: 08:51
Peak Area  (A-s): 0.004                 Peak Height  (A):  0.013
Background  Pk  Area (A-s): 0.003        Background Pk  Height (A): 0.011
Blank Corrected  Pk Area (A-s): 0.003

ul_ dispensed:  10 from 0,  5 from 39,  10 from 0
Replicate   £  (Peak Stored)             Time: 08:54
Peak Area  (A-s): -0.001                Peak Height  (A):  0.014
Background  Pk  Area (A-s): 0.004        Background Pk  Height (A): 0.010
Blank Corrected  Pk Area (A-s): -0.00£
Mean Pk Area  (A-s):
                          0. 000
          SD: 0.0035
                RSDC/.) : 3£4.i34
-------
                                                           ^'v^^                 r^r r
   Tl     10:^185-26-70  Ffr      Beq.  No.: 00049    fl/S Pos. :  11     Date:  11/19/9"
 I
            ^
            /S fr- S-JL - i 7, / c ,
   uL  dispensed: 10 from 0,  5  from  39,  10 from 11
   Replicate  1                            Time: 08:57
   Peak  flrea (fl-s): 0.006                  Peak Height  (ft): 0.018
   Background Pk Area  (fl-s): 0.006         Background Pk Height  (ft):  0.011
   Blank Corrected Pk flrea  (fl-s): 0.005
   uL dispensed: 10 from 0, 5  from 39,  10 from 11
l|  Replicate   £ (Peak Stored)              Time: 09:00
 I  Peak  Area  (fl-s): 0.007                  Peak Height  (fl): 0.017
I,,  Background Pk flrea (fl-s): 0.006        Background Pk Height  (fl) :  0.009
   Blank Corrected Pk flrea  (fl-s):  0.005
 I

 I
   Mean  Pk  flrea (ft-s) :      0.005         SD: 0.0005               RSDC/):  9.11

   Tl     ID:  flDD 1 50 ug/L       Seq.  No.: 00050    fl/S Pos.:  11     Date:  11/19/97

   uL  dispensed: 5 from 39, 10  from 1,  10 from 11
 I Replicate  1                            Time: 09:03


 I

 I

 I


   uL dispensed:  5 from 39,  10  from  £,  10 from 11
   Replicate  1                            Time: 09:09
 I Peak  flrea (fl-s): 0.081                  Peak Height (fl): 0.1£3
   Peak  ftrea : 0.046         Background Pk Height  (fl):  0.066
   Blank  Corrected Pk ftrea  (fl-s): 0.079

   uL dispensed: 5 from 39,  10  from  £,  10 from 11
„   Replicate   £ (Peak Stored)              Time: 09:1£
;l|  Peak flrea  (fl-s): 0.075                  Peak Height  (fl) : 0.110
"1  Background  Pk flrea  (fl-s): 0.047         Background Pk Height  (fl):  0.065
   Blank  Corrected Pk flrea  (fl-s): 0.073

   Mean Pk  flrea (fl-s):       0.076          SD: 0.0040               RSDCX): 5. £8

   Tl     ID:A1B5-S6-7C  F#      Seq.  No.: 00049    fl/S Pos.:  11     Date: 11/19/97
           / & f - STP- - )~\f i *,       *t/^t//'2.0/9 7
   Concentration (ug/L  ): 7. £

   Correlation coefficient:  0.99987        Slope: 0.0007
-------
                                   Calibration -  C:\ftft II +
                                                      ftt
                                   Concentration
                                                    100.0


Tl
       ID: AUTO  ZERO
Seq. No. : 00052
                    ft/S Pos. : 0
uL dispensed:  10  from 0,  5 from 39, 10
Replicate  1
Peak Area  (A-s):  0.
Background Pk  Area  (fl-s):  -0.000
Blank Corrected Pk  flrea (fl-s): 0.002

uL dispensed:  10  from 0,  5 from 39, 10
Replicate  2  (Peak  Stored)
Peak flrea  (fl-s):  -0.003
Background Pk  flrea  (fl-s):  0.005
Blank Corrected Pk  flrea (fl-s): -0.004
Date: 11/19/9
                                         from 0
                                         Time:  09:15
                                         Peak Height (fl): 0.013
                                                               (fl) :  0.012
                                         from  0
                                         Time:  09:18,
                                         Peak  Heioift (fl) : 0.010
                                         BackgrjKfnd Pk Height  (fl) :  0.011
Mean Pk Area  (fl-s) :
fluto-zero  performed.
                         -0.001
          SD:  0.0043
                                   RSD(%) :  305.47
Tl
      ID:  185-26-8E
    	J

Seq. No.: 00053     A/S Pos.: 12     Date:  11/19/97
uL dispensed:  10  from jZf,  5 from 39,  10
Replicate   1
Peak Area  (fl-s) :  0.JZT01
Background  Pk  flrea/ (fl-s): 0.073
Blank Corrected 0k  flrea (fl-s): 0.001
                                        from  12
                                        Time:  09:21
                                        Peak  Height (fl): 0.012
                                        Background Pk Height  (fl):
                                      J.052
uL dispensed:  JAJ  from 0,  5 from 39,  10
Replicate  2  (R'eak  Stored)
Peak flrea  (ft-s)\:  -0. 006
Background Pk  Are-a(fl-s): 0. 09&
Blank Corrected Pk  ArFS—f£—s^-:—-0. 00&—
                                        from  12
                                        Time:  09:24
                                        Peak  Height (A): 0.010
                                        Background Pk Height  (ft):  0.065
Mean Pk Area  (fl-s):      -0.003

Tl    ID: flDD  1  50 ug/L      Seq. No.:
                                        SD:  0.0048

                                        00054     fl/S Pos.:  12
                                    RSDC/0:  170.48

                                        >:  11/19/91
-------
I Repl-icare   i
• Peak flrea  (fl-s):  0.029
•
 I
  Background Pk flrea  D: 0.0023               RSDC/O: 4.03

                                         00053    fl/S  Pos.:  12    Date: 11/19/97



                                         Slope: 0.0006
                                     Calibration - C; \ftfl
                           *
                           a
                                               ; a.aaaf
                            •*.«
                                     Concentr atlon
-------

Tl . '   ID: AUTO  ZERO
Seq.  No. :  013056
                                                 A/S Pos. :
                                                                  Date:  ±j./19/9,'
uL dispensed:  10  from  0,  5 from 39,  10
Replicate  1
Peak Area  (A-s) :  -0.001
Background Pk  Area  (A-s):  0.007
Blank Corrected Pk  Area   :  -0.001

uL dispensed:  10  from  0,  5 from 39,  10
Replicate  2.  (Peak  Stored)
Peak Area   : 0.013
                                        Background Pk Height  (A):  0.012
                         -0.001
                              Seq.  No.:  00057
Mean Pk Area  (A-s):

Auto-zero performed.


Tl    ID: 185-26-8H
uL dispensed:  10  from  0,  5 from 39,  10
Replicate   1
Peak Area  (A-s):  0.002
Background  Pk  Area  (A-s): 0.002
Blank Corrected Pk  Area (A-s):  0.003

uL dispensed:  10  from  0,  5 from 39,  10
Replicate   2  (Peak  Stored)
Peak Area  (A-s):  -0.000
Background  Pk  Area  (A-s): 0.003
Blank Corrected Pk  Area (A-s):  0.001

Mean Pk Area  (A-s):       0.002

Tl    ID: ADD  1 50  ug/L      Seq.  No.:

uL dispensed:  5 from 39,  10 from 1,  10
Replicate   1
Peak Area  (A-s):  0.039
Background  Pk  Area  (A-s): 0.022
Blank Corrected Pk  Area (A-s):  0.040

uL dispensed:  5 from 39,  10 from 1,  10
Replicate   2  (Peak  Stored)
Peak Area  (A-s):  0.040
Background  Pk  Area  (A-s): 0.021
Blank Corrected Pk  Area (A-s):  0.041

Mean Pk Area  (A-s):       0.041

Tl    ID: ADD  2 100ug/L      Seq.  No. :

uL dispensed:  5 from 39,  10 from 2,  10
Replicate   1
Peak Area  (A-s):  0.075
Background  Pk  Area  (A-s): 0.045
Blank Corrected Pk  Area (A-s):  0.076
          SD: 0.0005
                                                                 RSD(7t>:  37.60
                                                 A/S Pos.:  13
                                    Date: 11/19/97
          from 13
          Time: 09:45
          Peak Height  (A): 0.016
          Background Pk Height  (A)
          from 13
          Time: 09:47
          Peak Height  (A): 0.011
          Background Pk Height  (A)
                                                                   0.011
                                                                   0.011
          SD: 0.0018               RSDC/4):  100.34

          00058    A/S Pos. :  13     Date:  11/19/97

          from 13
          Time: 09:50
          Peak Height  (A):  0.056
          Background Pk Height  (A):  0.036
          from 13
          Time: 09:53
          Peak Height  (A): 0.055
          Background Pk Height  (A):  0.035
          SD: 0.0006

          00059    A/S Pos. :  13
                                                                 RSDC/4) :  1.45

                                                                  Date:  11/19/971
          from 13
          Time: 09:56
          Peak Height  (A):  0. 101
          Background Pk Height  (A):  0.061
-------
(Replicate   £ (Peak Stored)
Peak Area  (A-s): a.874
Background  Pk Area  (A-s):  0.041
Blank Corrected Pk flrea  (A-s):  0.075
Mean Pk Area (A-s):      0.075


Tl    ID:  185-£6-8H ?**., J .  Seq.  No.
                        0F^idSl

Concentration  (ug/L  ): £.5


Correlation  coefficient: 0.99766
                                         Time: 09:59
                                         Peak Height  (A):  0.103
                                         Background Pk  Height (A): 0.053
                                         SD:  0.0011               RSDC/.) :  1.51


                                         00057     A/S Pos. : 13    Date:  11/19/97




                                         Slope:  0.0007
                         "IDisplau  Calibration - Ci
1



I


I


I


I


I


I


I

  uL dispensed:  10 from 0, 5 from  39,  10 from 0
I  Replicate   1                             Time: 10:03
  Peak Area   : 0.005         Background Pk  Height   :
I Blank Corrected  Pk Area  (A-s) : -0. 00£
                                           Metft. £F «
-------
Replicate   1                            lime: iw:uu                ;
Pea,k ftrea  (A-s):  0. 004                 Peak Height  (ft) : ft. &ib
Background  Pk  Area (A-s): 0.009        Background Pk Height  (ft):  0.010
Blank Corrected  Pk ftrea (A-s): 0.005

ul_ dispensed:  10 from 0,  5 from 39,  10 from 14
Replicate   £  (Peak Stored)             Time: 10:11
Peak ftrea  (fl-s):  0.007                 Peak Height  (ft): 0.0£0
Background  Pk  flrea (ft-s): 0.007        Background Pk Height  (ft):  0.011
Blank Corrected  Pk ftrea (fl-s): 0.008

Mean Pk ftrea  (ft-s):       0.007         SD: 0.0019               RSD<*): £7.98

Tl    ID: ODD  1  50 ug/L      Seq.  No. : 0006£    fl/S Pos. : 14     Date: 11/19/9

uL dispensed:  5  from  39,  10 from 1,  10 from 14
Replicate   1                            Time: 10:14
Peak ftrea  (ft-s):  0.033                 Peak Height  (ft): 0.065
Background  Pk  ftrea (fl-s): 0.023        Background Pk Height  (ft):  0.041
Blank Corrected  Pk ftrea (fl-s): 0.034

uL dispensed:  5  from  39,  10 from 1,  10 from 14
Replicate   £  (Peak Stored)             Time: 10:17
Peak ftrea  (fl-s):  0.033                 Peak Height  (ft): 0.07£
Background  Pk  flrea (fl-s): 0.0£4        Background Pk Height  (ft):  0.040
Blank Corrected  Pk flrea (A-s): 0.034

Mean Pk flrea  (fl-s):       0.034         SD: 0.0001               RSDC/): 0. £3

Tl    ID: ftDD  £  100ug/L      Seq.  No. : 00063    ft/S Pos. : 14     Date: 11/19/9"!

uL dispensed:  5  from  39,  10 from £,  10 from 14
Replicate   1                            Time: 10:£0
Peak flrea  (ft-s):  0.059                 Peak Height  (ft): 0.115
Background  Pk  ftrea (ft-s): 0.042        Background Pk Height  (ft):  0.068
Blank Corrected  Pk flrea (fl-s): 0.061

uL dispensed:  5  from  39,  10 from 2,  10 from 14
Replicate   £  (Peak Stored)             Time: 10:£3
Peak flrea  (A-s):  0.061                 Peak Height  (ft): 0.117
Background  Pk  flrea (fl-s): 0.044        Background Pk Height  (ft):  0.078
Blank Corrected  Pk flrea (fl-s): 0.063

Mean Pk flrea  (ft-s):       0. 06£         SD: 0.001£               RSDC/.): £.00

Tl    ID:A185-£6-10C  Pf+      Seq.  No.: 00061    ft/S Pos.: 14     Date: 11/19/97
        /«Sr- .ra - / i~> / £/      ^ <**'! He/S 7
Concentration  (ug/L  ): 12.3

Correlation coefficient:  1.00000       Slope: 0.0005
-------
•V
J
 I
 I

r
 I
 I
                                                  - f
                            0.042
                                                 *F 044.
                                                 e«*?.: t.eaae
                                                ; o.aaaf
                            -12.3
                                      Concentration
                                                      100.0
                               *\* A* A* A* A* A* A*
                                           A/ A^A* A* A* A* A* A* A* A^ A* A* A* A*A* A* A/ A*^w A* A* A* A^ A# A* A* A* A* A* A* A* A^A^ArA/ A* A
Tl
ID: AUTO ZERO
                              Seq.  No.: 00064
                                                     A/S  Pos. :  0
                                                                   Date: 11/19/97
I

J
uL dispensed: 10  from  0,  5 from 39,  10
Replicate  1
Peak Area (ft-s):  0.001
Background Pk Area  (A-s): 0.004
Blank Corrected Pk  Area (A-s): 0.002

uL dispensed: 10  from  O,  5 from 39,  10
Replicate  £  (Peak  Stored)
Peak Area (A-s):  0.003
Background Pk Area  (A-s): 0.000
Blank Corrected Pk  Area (A-s): 0.005

Mean Pk Area  (A-s):       0.003

Auto-zero performed.
                                         from 0
                                         Time: 10:33
                                         Peak Height  (ft):  0.012
                                         Background Pk Height  (A):  0.010
                                         from 0
                                         Time: 10:36
                                         Peak Height  (A):  0.010
                                         Background Pk Height  (A):
                                           SD: 0.0016
                                                                  RSD(5O : 45.48
   Tl
ID:.185-26-f
   Si.
                                   
-------
uL dispensed:  5  from  J'i,  1W from 1,  1W
Replicate   1
Peak ftrea  (ft-s):  0.029
Background  Pk  ftrea  (ft-s) :  0. 140
Blank Corrected  Pk  ftrea  (fl-s): 0.027

uL dispensed:  5  from  39,  10 from 1,  10
Replicate   2  (Peak  Stoved)
Peak flrea  (fl-s):  0.029
Background  Pk  flrea  (fl-s):  0.123
Blank Corrected  Pk  flrea  (fl-s): 0.027

Mean Pk flrea  (fl-s):      0.027

Tl    ID:  flDD  £  100ug/L       Seq.  No. :

uL dispensed:  5  from  39,  10 from 2,  10
Replicate   1
Peak flrea  (fl-s):  0.054
Background  Pk  flrea  (fl-s):  0.150
Blank Corrected  Pk  flrea  (fl-s): 0.052

uL dispensed:  5  from  39,  10 from 2,  10
Replicate   2  (Peak  Stored)
Peak flrea  (ft-s):  0.054
Background Pk  flrea  (fl-s):  0.143
Blank Corrected  Pk  flrea  (fl-s): 0.052
               t r o m  i £
               Time: 10:45
               Peak  Height  (ft):  0.062
               Background Pk Height  (ft):  0.071
               from  12
               Time:  10:48
               Peak  Height  (fl) :  0.067
               Background Pk  Height  (ft):  0.065
               3D: 0.0003

               00067    fl/S  Pos. :  12
                                                                RSDC/.) : 0.99

                                                                 Date:  11/19/97
               from  12
               Time:  10:51
               Peak  Height  (fl):  0.123
               Background Pk  Height (fl):  0.069
               from  12
               Time:  10:54
               Peak  Height  (ft):  0. 129
               Background Pk  Height (fl):  0.073
Mean Pk flrea  (fl-s):       0.052

Tl    ID:1/,lS5-£6-SE F//     ^

Concentration  O_ig/L   ):  -0.

Correlation coefficient:  0.99916
               SD:  0.0002              RSDC/.): 0.44

          No.: 00065     fl/S Pos.:  12    Date: 11/19/97
               Slope:  0.0005
"IDisplau Calibration - C:\flft II
-------
    we i.
  •am Die
i-' i. ~
ume ;
 .i.i lyr-: t :
-! o rn', n a .1 I
I
I
I
r
i
                                  Wei gnt
                                    C11. lu t ion
IJ
1
2
vt1
4
5
0
-7
3
9
LO
11
12
13
14
15
16
17
18
19
*~*j\
iO
21
22
23
24
25
26
27
28
29
30
STC SIX
0.2'jg/L .
0 . --'J^L.^ ^^X^
1 . Oj cf/ L j^> "3> ~ "D 2. (o —
2.0u>3/L ^""""^
5.0ug/L //x^
lO.Oug/L
1 C v = 4 . Ou g / L — 	 3 - O 2 t -
ice
CHECK LO
43452 M61
43^52 MB1
43452 LCS1
43-52 LCS1 0
1SS-52-JL-2/L85-2W- 1C.
183-52- 1 -2/185- "it - 1 c. S>
185-26-10
185-2fc-lL-' 0
185- 26- 10 MS
185-26-10 !"!SC.
CCV 1 - 6 , Ou g / L 	 o— t/ cb
cce i
135- 26- IE
185-26-1E C>
185-26-1F
185- 26- IF 0
1SS-26-1G
185-26- 1G 0
1SS-52-3-4./ 155-it-Zc
188- 52-3-4X 185- it, - 2- <- j>
185-26-12-20
                                                  (b 
-------
            :. -iTIC L-~
                                              0; lu I" ton
-14
C C
           i?-=7.-LL  L2/L3j--2b-:
         CO- J = i.
                                        - 0
60
61
c-2
C.10
64
65
66
o7
oS
69
TO
71
86
91
•!•?
95
07
100
101
102
103
104
I 05
LO-6
          LS5 -I.--5E  D

          L85-26-5F  0
          15.T-2d-5G
           )(•*. d 	 ~1  ™ i ~  |~.
          . !._' —  i_ j 2J '.Ji  l_'
          186-52-13-14/1&5--
          18.3-52-i3-L4/lSf-
          185-2o-t.u

          ISS-^fc-b^
          185-26-oE  0
          CCV5-6.Oug/L
          OC& 5
          185-26-cF
          18S-.l6-6:r  D
          1£5 - 26-oG
          LS.5-2o-.-sG  D
          CC v'6- 6 . Oug/ L
          CCSo
          43452 MB2
                   D
                     MS
          185-26-50  MSD
          18?-52- 17-1S/ ISr- Zt-7 C.
          183-52- 17- LS/ L85- 2t -Tc-
          CC vIz 6.Ou g/L     	.	
          CCS I
          185-26-7D
          L85-26-7D  0
          185-26-7E
          185- Z- -7t  ij
          18::-26-~F-8H
          LS5-26-TF-3H  0
          185-26-7QF8H
          1.55-26-"GF8H  C-
          185-2o-7CD
SO
81
82
83
34
oc
1 	 1 . 	 ;
43452 1*162
4 3 4 5 2 '_ C
43452 LCS
185-26-50
185-26-50
185- 2o-5D
                                     3--oz *o-<
u
        CC'V " ~d . Oug/ L
        CCS I
                      - 2 i//Sf -
        1S5
-------
                                 weight        Dilutio
I

I
I
HO      LS':,-2fc-3FH D
.1:1      185- 26-SFGH
,.12      lS5-2t>-l3FGH 0
115      CCv3~6.0ug/l
1  la      CCe.3
115      185-26-3H
116      LS5-26-SH D
117      188-52-7-3/183-
ilS      183-52-7-8/155-
.11 v      185-26-9D-li
120      185-26-90-11 0
121      185-26-9E
122      lS5-26-'^£ 0
123      185-26-9F
124      135-26-9F D
125      CCV4=6.0ug/L
12fc      CCB4
127      l88-52-l5-i6/lSS--Zt-
12S      133-52- 15- IcVlSf-lb -
129      185-2fc.-10D
13C      185-26-100 D
131      185-26-10D MS
132      155-26-100 MSO
133      185-26-10E
134      135-26-10E D
135      185-26-10F
136      185-26-10F 0
137      CCV5 = 6.0ug./L
13S      CCS5
-------
- ;'. Ti'Tie.'": :
i; " • "i t  L
c r i n c :
-.ernar K =
         a I ib   Cu rve
                                            toi'acj-
                                                    none;
INSTRUMENT :,  5.00
"Jave Length:  ;!5i.7 Peak
S.ignai Tyoe:  AA
fte.aci  T ims :  30 , 0
Sarnp 1 2 RSD 11 Co tes :  i
Standa ~d Rap 1 Lea tes :  i
                                      Techniaue:  h'KS
                                      £ L i ';:  0 7 LOW
                                      Sianal  Mea su re r i en t:
                                      * a a d  0 e L a y :  L. 0
                           version :
Peak
He^ gh:
80C Ti-
                                   (. 5
F i.?.iTie  T\.-oe .:  H i r
0>ac:anT Flow:  10.'
                    L-/min
 i-Lame Sensor-; On
 Fuel -low: 2.0  L/miri
 S :-)Lu t ions
Cal10 . 3 Lank
Standard  1
•Standard  2
Standard  3
•Standard  4
Standard  5
Standard  6
                3TC> 2
                5TD 3
                S~D 4
                STD 5
                STD 6
 Calibration  Units:  ug/L
 Calibration  Type: Linear
                      10
                    8LK
 0.200
 0 . 500
 1 .000
 2 . 000
 5 .. ooo ;
L 0.000 ;
 Sample Units:
                                                    ug/L
  tri.-c Check  Calculations:
  Difference  for  Dupls:  No
  Recovery  for  Spike:  No
                                Locations:
                                Locations:
               Cone
-------
[
 f. leriiirnt file.. r-:G_.nt'L         £;exie"~i:  Hg2                   Wave 1 engtn : 25,"
 >ate.  11 '06/1"                Time:  ;.0 : 13                    1! 1 i .- :  v , 7  L
      Fil-:;  AB 5J.3.DAT          IC'/W::  File:  AE 333 . :C'l>v          Lo.rriD Ci_ " ren: :. 0
 Tecnnioue:  'viHc.                '.,ali&.  Type: '_ms.a             £p3rg^.- 72
 P.emai-k  1:  STANDARDS:  3-026-Z
 Remark  2:  QC- 3-C2&-4
I
 Hg2   ID: S TO ELK             -leo .  No.:  00003    A/S PCS.;  --    Date:  li/Oc
 RaDiicate  i                              Time:  10:14
 |-'eak. Area c A-= •:  -0.005                 Peak Hei:;ht (A):  -0.000
.Blank Corrected Pk  height (A):, -0.000
 'Concentration  '.ug/L  ): -0,008
t
r
  u to- zero performed.
       ID:  0. 2-jg/L             Sea.  No.:  00004     A/S PCS.:-  --     Date: 11/Ot.

     icate   L                             Time:  10:19
g"-'eak Area CA-x > : 0.171                   Peak Heicht (A):  0,007
•alan!* Corrected Pk  Height (A): 0.007
 Concentration  (ug/L  '):  0,200

•Stanolarc: number i applied.   [0.200]
Correlation coefficient:  1.00000        Slope:  0 0356
  g2   ID: 0.5ug./L             Seq.  No.:  00005    A/S Pos. :  --     Date:  11/Ot'^'

Cample aos,  is greater than that of  the largest standard.
fceolicate  1                             Time:  10:21
"Peak. Area ( A- 3 ) : 0.446                  Peak Heiriht (A):  0.01'-
 Blank Corrected Pk  Height (A): O.Olv
WCo nee n t r a t i o n  i ug/L  ) :  0.541

 Standard number 2 applied.   [0.500]
E Correlation  coefficient:  0-99777        Slope:  0.0381
                	 ...
•Ho2   [ij :  !. .0/g/L             5eq .  No.:  OOOOo    A.-'S Pos.:  --    Date:  1 i .' Ot- ?'

I
Cample ab* .  1= greater-  than that of  the largest standard.
     icate   1                             Time: 10:12
      Are.H  (A-s : : 0.3S7                   Peak  Height ( A > :.  0.0 30
 6 1 .a n k. C o r r e c t a d P k.  H e i g he ( A i ,  0 . 0 3 3
 Concentr ation i ug/ L   .• :  1 . 002
Ic
B' © 3. r
leiar
 Stan^arc nurncer  3 .applied.   1.1.000]
  orrelation coefficient;  O.^^vo'1'        Slope:  0.0332


 Hg2    jr>:  2..0ug  L             Seq. No.:  0000"     A/5 Pos,,  --     Date:  11/Or

 "~amr
-------
                    H :r- .1 O '"•
    nn t ra *; i,on
   .ndar::  nuffibe"  •• apol.iec!.   [2.0'JC
   r s i. a 17. o n  coe f f ; c i e n t:  •"<. 9'^i:5 f o
                                         -Z J CDS :  0 . 03 ~4
       ED :
                                           :-oos
                        i i /O'iD/ -
S.'.micjle abs ,  is araater  n.na ~i  chat of  t ~ e largest  stanaar-d,
P ep :. i ca ta   1                             T i me :  1 0 : 24
Pe-3k Rrea  i A-s •   4 . oOc                  Peak Height  ( A i :  0.203
t l.-r.nk CorractS'',!  z'- Height  i. A • :  O.205
Concentration lug/L   ): 5.145
". t.::'.n-.1arc!  number 5 aoplieci.   C5.0CO]
Correlation  coefficient: 0.99^53
                                         -Slope; C . 0403
      1C-:  10,0ug/i.
                              Sea.  Nc„:  0000C
ft/S Po£ . :  --
Do.t.s: 11/Oc/v" i
SaiTi&le abs.  i-s greater  than  that  of  ::he largest  stand.ara.
Rerdicate   1                             Time; 10:25
Peak Area  iA-s ) :  5,398                  Peak Height  'A):  0.381
Blank Corrected  PK Height (A):  0.531
Concentration  iug/L   ): 9,444
ftandard  nutribe!'  o apolied.   [lO.OOOj
Oo"relation  coefficient: 0.99942
                                         Slope: 0.03S6
-------
  [I ~:T:'5P' ::: I I 5.1 H G .. ,:*!EL
  >.i t.e :  1 i ''Ofc /C3~
  'at a  i-i-ls:  ASS35.CMT
  •echnicue:  MHS
	i.emarK L :  STANDARDS  I--02o-3
  •'.erna r k 2 :   QC - !•-016- 4
E i '51"! i IT i": \, .'  H ••."! 2
Tune:  1.0; i:
ED/Wt ~ile. A6SZ5 LOW
Ca 11 b .  T y'De :  Li •->.&.; ••
••• a-/s  £-1 x. r;hi ;
;?• : i t :  0 .  ~  L
L amo  CLI .  ran
Enerav:  7;
Mj Display Calibration - C:\fifi_USER\flfl_FILES\ELEMEHT\HG_.HEL
0.381!
i"



0.
.-•"
pi.--'
.•"""
JSfc* Linear1
-x" u1* n 	 n 	 P , n nnnjn
ar^ borr . uoer . . u. 7774C
c^So^S3 Slope: 0,8386
0 Concentration 10.000

4






Ij
-------
           1C . --'• . Oug.- I.
                              Sec; . Ho . , 0001 j
                                                                  Oa ts :  Li •" '•-"-••
Replicate   l
p:=.?J- A re.2   A- ~. ' :  3 . 5L3
Blank Corrected  Pk  he. i»ghr
      i cr.st ion  ' ug/ L  ) :  3
                            A):
                                         Time:  10: 25
                                         PeaK  he ion r.  ( A ) :  0 . 154
H3J.   ID:  ICE-
                              Sea. No,: 00011
P e a k  Area  ( A - s .' :  0,. 01 8
Elank Corrected  Pk Height (A). 0.000
Concentrarion i. ug./L   ):  0.008
                                        Time:  10:29
                                        Peak Heioht  (A):  0.000
                                                                  1-a.r.e:  ll/06.'i~
Ha2    ID:  CHECK  LO
Seq .  No . :  0001'.
                                                 A.'S  Pos . :  --
                                    Date:  11/06/9'
Pe.r;k  H rea.  •' A-s ) :  0.134
Blank Corrected  Pk Height (A): 0.008
Concentration  (ug/L  !:  0.203
                                        Time:  10: II
                                        Peak Height  (A):  O.OOE
Hg2    ID:-  43452  MBl
                              Seq.  No.:  000i:
                    A/3  Pos.:  -~    Date:  11/Of'-"
Replicate   1
Peak  Ares  -'A-s):  0.014
Blank  Corrected Pk Height (A): 0,001
Concentration  (ug./L  ):  0.023
                                        Time:  10:52
                                        Peak Height  (A):  0.00:
Hg2    ID:.  43452  MBl
                              Seq. No.: 00014    A/S  Pos.:  --     Dater ll/Oo^'"
P.eoLicate   1
Peak Area  iA-s):  0.005
Blank  Corrected  Pk Height (A): 0.000
Concentration  (ug/L   ):  0.005
                                        Time:  10:3-i
                                        Peak Height  (A.1:  0.000
Hq2   ID: 43452 LCS1
Seq. No.: 00015     A/S  Pos,
Replicate   1
Peak Area  (H-SJ:  4.24=»
3 Lank Corrected  Pk  Height (A): 0.183
Concent rai ion  i ug./L  ):  4.^44
                                        Time: 10:34
                                        Peak Height  (A):  0.18C
                                                                  Date:
H~2    ID:  43452  LCS1  D
                              Sea.  No.: OOOlfc.    A/S  Pos.:  --     Date: 11./Ob/'
PSD lie,ate   1
Peak Are.;-  i A- 3 i :  4 ., 350
£ 1 a n k  Co r • • ac t -• d  P k  H e i g h t >, A ) :  0 . 136
Concent rs:ion fug/L   ):  4.324
                                        Time:  10:35
                                        Peak Height  (A):  0.i So
Hal
      IC>: 13S-52--1-2/1 £5-2(0-16 Seq.  No.:  0001 ~    A/S  Pos.:  ~-    Date: 11/Oc'^1"
-------
  -:: i i '.?. '. ~   '..
 '';;oi  A: -rjt  ( A •••-?..'; 0  1-0
  Lank >Ic •-rec te-2 Pk  Height  iA);
  oncent ation i ug/L   ):  0.121
                                   005
                                            ms :  10 : "c
                                            aK  Height
       I".:  186-52~l.--2.'lS5-26-lc;>Seq. No,.:  00018     A/S -'OS
      Area i'A-s;: 0.0^3
 ilank Corrected Pk Height  i. A ,)
 :oncent ration (ug/L   );  0 . 09o
                                 0,004
                                          Time:  10:59
                                          Peak  Height (A):
                                                           0,004
                                                                    Date:  11/O
1g2   It1:  185-2&.-1D
                               Sea, No.:  0001=5
                                                   A/S PQS
                                                                    Date:  li/06''~-~
 RecLicaca  1
 ;iPeak Arsi ( A-s ) ; 0.042
 Blank. Corrected Pk Height  (A): 0.002
 Concentration  (ug/L   :> :  0
                                          Time:  10:42
                                          Peak  Height (A):
                                                           0 00
HC'2   ID;  185-26-1D D
                               Seq ,  No.:  00020
"v.eDl ica-<=  1
il'iPeak Area (A-3K 0.04t-
 fe lank Cc r rec ted Pk Heigh t  iA):  0.002
 Concentration (ug/L   ): 0.042
                                                       F'O£ ,
                                          Time :  10 : 43
                                          Peak  Height (A;:
                                                           0 00
                                                                    Data,
  g2   1C:  185-26-1D MS
                               Seq. No.:  00021     A/S Pos .
  ;eolicace  i
	ak Area (A-s s: 4.275
 Ifelank Corrected Pk. Height  i. A ) :  0.1S8
 Concentration (ug/L   ):  4.874
                                          T ime :  10 : 44
                                          Peak  Heiaht ( A > :
                                                             188
                                                                    Date:
Hgl    I:-:  !S5-2fc-lD MSD
                               Seq. No.
"Peolicace  1
;T'eak Area (A-s.': 4.453
'SLank Corrected Pk Height  (A):
fconcent rati on ( ug/ L   ! :  5 . 009
                                         00022     A/S °os

                                         Time:  10:49
                                         Peak Height (A):
                                                                    Date:  11/06
r
1C;  CCVl=6.0ug/L
                                   No.: 000
                                                   A/S Pos.: --•
                                                                    Date:  11/06
• Reo 1 ic.a r.e   1
.iPeaK Area  (A-s/; 5,181
Blank  Cor- rec ted Pk Height  'Ai:  0.224
Concentration tug/'L   i: 5.804
                                          T ime :  10 : 5_
                                          Peak  Height (A;: C . 224
L":
           CC& i
                                                                    Dat= :  i 1 ''06
 eo 1 1. ca :
 e-*!- Ar :-
      I':-- rec ted Pk Maignt  '. A i :  -0.000
                                          " ime :  10 : E3
                                          Peak  h e i Q h t ' A .' :   0 . 0 0 C
-------
Conc^n i r at i on ', :~-g/ :_
       ID:  1S5-26-1E
                                                      P'os
                                                                   Da;' s:  j 1 3i
     .c.sta   L
Peak Area  :A-si:  0,vi4
Blank  Corrected  Pk Hsicr: O..OOO
HGJ    ID
185-2o-IF

 I
Sar> I icate
Peak Area  (A-s;:  O.^3r
  L-anK  Corrected Pk Heigr.c (A!
  jncentr.ation  "ug/L   i: 0.4"^S
BlanK  corrected
Concent ration '
                      0.0 IJ
                                         l'C'027
A/S Pos.r  --     C-ate:  ll'Oi/^"
                                         ; ime :  10 *. 58
                                         Peak  He:iaht i A i :.  O.C
Hal
ID:  185-2c-lF [•
                               >eq. No.
                                       A/S Pos.:  --
                 Date:  11. 06/c"
Replicate  i
Peak  Area (A-s):  0,. 455
Blank Corrected Pk Height iA): 0,020
Concentration (ug/L    ): 0.507
                                         Time:  i1:00
                                         Peak  Height (A): 0.020
       ID."  185-2e-lQ
                              Seq. No.: 00029
                                       A/S Pos.:  --
                 Date:  li/Ob/9'
Peak Area  (A-sj:  0.02~
8 lank  Corrected  Pk Heignt (A): 0,001
Concentration ( ug. L   ): 0.02fc
                                         iime:  11:01
                                         Pea k He i g h t (A ; :  0.001
Ho2
      ID:  !35-2fc-lb C
                   Sea,  No.•  00030
A/S Pos.:  --
Peak Area  (A-s):  O.!.p23
3 Link  C:orrectea Pk Heigh t (A): 0 . 00 I
Concentration  (ug/L   •: 0.021
                                        Time:  11:02
                                        Peak Height (A):  C
                                                                   Date:
Ha2
Rsolicata   1
Peak A r ea  ( A- s .' :  C1. 1 :.-£
6 I a n I- Co r r ec r -3d  P!-  He;
                         vfe-'2c 5eq. No, : 00031
                           1 H ! : 0,005
i.-oncenr. ratio
                                       A •'-;.. Pos
                                         r i.me :  11 .: 05
                                         PeaK  hei aht (A i :
-------
  .:: _    IC :

 Pec-i. i-:.a ts
                                               i-iJI.ght (M)  C  I1 It
I
               2~.-- . 2-2D C1     Sac;.  No.: 00034     A.'S Pos . :  --     Da-e:  li/Ot
  =c L ;:.?...-  J.                             Time:  1 1 : 09
  ea;-.  Area (A-s): 0.381                   Peak  Heignt (A): 0.017
  Lank Corrected  Fk  Height (A):  0.017
 Concentration  iuo/L  ) r  0,442
 I


»|ft
 Hg2   ID: CCV2=t.Oug/L        Seq. No.: 00035     A/S Pos. ;  --     Date;  i. 'Ot
 tep 1 i ca ta  L                             T i me :  1 i *. 10
 Peak Area iA-st :  5.087                   Peak  Height (A): 0.225
JBlank Corrected  Fk  Height (A):  0.225
•Concentration  (ug/L  J;  5.827


  g2   ID: CC&2                Seq.  No.:  0003&     A/S Pos.:  --     Date:  li./Ot

v Rao 1i ca te  L                             T i me :  i l : 11
•Peak Area fA-s):  0.016                   Peak  Height (A): 0. 3OO
|81ank Corrected  Fk  Height (A):  0.000
 Concentration  (ug-L  ):  0.010


  g2   ID: 18£-52-5-6/lS5-2b-3<- 5ea.  No.:.  0003"'     A-S Pcz. :  --     Date:  . i,'0c
     icate  i                            T ime:  1i:il
  sak  Area. iA-e): i . 355                  Peak  Height (A): 0 060
 & I a n k C c r r a c t e a p i- H e i cs h •:  t A ) :  0.060
 Concentration. '. uc/ u   .' :  1 . 54t
 Hg2    ID:  135 - 52-5-o/185-2fe-3c^ 5eq.  No.: 0003S     A/S Pos.   --     Dare:
  5oiic,ats  ;,                             Time :  L i : L 3
Peak  Are.;;. 'A-s/; j.. 326                  Pea!-.  Height (A.1: 0  J57
& I a n !•  >.". o r i • e c c a d P '•• H e i 
-------

-.  ini-  '.,or; ec "aa °f-  -i.~ight  ; A.) :
'...-.nce.ntration iug/L   / :.  0,801
                                          . g. J.; j,  f-j ,-• j •-_;t~. |;
       jr-;  1 ;"•' 5- 2c - •!•['  C1
                               Sec.  No, :   .'0040     A. S ? os „  : --     Date: II
:~. 3 P 1 L C .3 18  i
C' = a!- Arse-.. ( --s '  O  ~22
SL-anK Corrected Pk  H-sight  (A;:  0.330
",-oncsntration iug/-_   »:  0.790
                                              Heiaht '. A . :  0 , 0-.J--
Hc2    1C':  lSE-2t--
                               Seq,  No.: 00041     A/S Pos . : --     Date: II.

Pec- i. ica te   1                            T i me :  L i : 49
C'eak Area  i. A-s.1: 0.092                  Peak Height • A j r,  0.00-a
5 lank Corrected P\* Height  (A):  0.004
Concentration fug/L   ) : O.O^e-
Hq2   ID:  1S5-2&-3E :•
                               Seo.  No.; 0004
                                             •i r-     £.-. / •
:'OS
                                                                    Date: 11 • Ot
Peak  Area i. A-*. i : O.O^l
Siank Corrected Pk Height  (A);  0,004
Concentration,  (ug/L   >:  0.096
                                         T ime:  11:50
                                         Peak Height  Aj; 0.004
Hq2    ID:  l5o-2fc-3F
                               Sea,  No.: 00043     A/S Pos.: —     Date: 11/06/9-
      s a»s.  is greater  than that of the  largest standard.
Reolicats  i                            Time:  11:51
Peak  Area i H--S ) :  12.563                 ^eak  Height (ft): 0.542
Blank Corrected Pk- Height  (A):  0.542
Concentration  (ug/L   ):  14.031
       ID:  1S5-26-3F DX2
                               Sea.  No.;  00044
P. =D li cats  1
Peak Area i A-s i :  4 . .-..50
Slank  Correcteo Pk  Height  tA):
Concen tr atl on i uq/ L   .' :  4 . 925
                                         ~ime:  11:59
                                         Peak Heiaht !A»: O.l'^j
                                                                    Date:  11/06/9"
H.32    ID:  l = =-Zi-3F DDX2     Sea.  No.:  00045     A/S F os
••^sji' 1 ica t*5  ^.
Peak Area ( A-s • :  4 . '--r-"?
•Blank  Corrected ?i>  Height  (A):  0.205
C o n c e n t. r a t i o n i u g./ L   .> :  5.50 =
                                         Time:  1Z:01
                                         "'eak Heignt < A / :
                                                                    Date
Hg2    1 r<:  1 5S - E I:-'~ - i O/ 1S5*«"i4- Seq .  No.: 000 41-
--ec !. ic.5 ire
                                         Ti:T;e:  L2:>:-2
                                         Psai-  Height (A::  C-,0'".'Z

                                                           333
-------
  ' '••:*,'.*  •'."••<"> :-=>|- --a,*!  PI.,  :-i.= i' -i!-. I
 (- '- •    •• "  •' -  " •-  • •  • - - J" ••'' • •
 :.:.• nee'•.:'. j-..;.t.i CM .- i. -jg/ .    >r
                                       ,: 0./047     A/
    L ica *;s  ,.                              T i ne :  LI : 03
    •:  Area '. A-s > :.  0,033                   ^'sal-  Heignt (A;;  j.OOi
 6 1 a n k ••'.. o r recced  PV  Heignt  ( ^ ) :  0 . 0 01
 L .oncentrati o n  i u g./" L   ) :  0 . 0 2 o
 f.
 H _

'Feclicc
 Hg2    ID:  CCv3 = t . Oug/ L.        Sea..  No.: 00043     A/S Pos.. ;  --    Date:  11/06
'Feel ica te  l                              "Time:  12:04
 '-tes.\<  Area (A-s':  5.272                   Peak  Height (A):  0.22-?
 plank Corrected  Pk Height  (A):  0,224
 Concentration  t'ug.'L   ): 5.7°3


       ID: CCB3                 Sea. No  :  00049     A/S Pos . :  --    Date:  11.'Ot.

      cate  1                              Time :  II:05
      Area '. A-= .' :  0,020                   ^eai-;  Heignt (A):  0.001
  lank Corrected  Pk Height  (Ai:  0.001
 Co nee n tration  (u g/L   ) : 0.015
I
 Hg2   ID: l-=5-2o-4D           Sea,  No.: 00050     A/S PQE . :  --    Date;  ll'Oo
it'eclicate   i.                              fi:Tie:  12:06
•Peak Area i A-s) :  0.018                   f'eak  Height (A):  0,000
 Blank. Corrected  Pk Height  i A ) :  0.000
•Concentration  i ug, L   )„ 0.010


•Hg2   IL:: iS5-2fc-4[i u        Sea.  NO, :  00051     A/S Pos. :  --    Date:  ll/Ofc

 Psolicata   L                              ~L?ne:  12:07
iPeak Area i A-•='.':  O.Olo                   Peak  Height (A):  0.000
•Bisnl"  ilorrgcted  Pk Heignt  i A ) :  0.000
•Concentration  (ug/L   ) ; O.G10


   2'   ID: l:?5-26-4C' nS       Sea.  Mo.:  00052     A/S Pos . :  --    Dair.e:  jil.'jfc-

 {:' eo 11 ca te   1                              T L .ne :  11: OS
 Ps.-k Area >A~s);  3.54;                   Peal  Height (A):  0.15E
 •Slar/K  Cor^-cred  Pk Height  iA):  0.155
 Concentr ati on  i uc •' L   > : - . 02"
I


Hg2   ID: i -" 5- :."c- 4C- rtOC1      Sea.  r^o.:  0'."'05J     A/S Po= . :  --    [-ate:  11 Oo '

,-;' e D 1.1 care!                              71 :ii e :  12:10
^•eaK Ai'ea ' --s • :  5. oil                   Peak  Height (A;:  •j,.:o-;
olanh  ! o r re>: teo  P-  Height  <.'-.}   'j.lol
Concent r -3. t i ~ n  ( u g • i.   i : 4.1 •: •"•
-------
:: •=::•: • c.?. c.e                                r ime :  1 2 : i i
K-~ai  At 3i   .-'-xi: .V,Ji". .                  Pea* Heignt > A j : 0  00i
i-Linh  Cor •: -ec ': so "• s "ie !."•:: n i;  i A ) : 0  0-M
C oneen c r s r : on r u..; /' L    :. C . 02 c
           I ~, 5 - 21. - 4 E C         E. e a . N o . :  0 O10 5 5    A / S P o s . :  - -     Date; i 1 / 0 c / '

•^aoLicate   1                            Time: 12:12
pf=ak Area  '. A-S); 0.01Z                  Peak Height (A):  O.OOi
Blank.  Corrected Pk Heighc (A;: O.OOi
Concentration (ug/L   .': 0.021


H-a2    IC>:  l3S-2fc-4F          Sec. r--o. :  0005fc-    A/5 Pos.;  --     Date: 11 ,'Ot•/c'

s eo 1 L c a t ; O.80S                  Peak Height (A):  0.035
6 1 a n k.  0 c r r = c t a d P k H e i g h r; i A • : 0 . 0 o 5
Co nee n t r a 1.1 o r- ( u g / L   i : 0 , 39 ^


Hc2    ID:.  1S5-26-4F D        Seq. No.:  00057    A/S Pos.:  --     Date: 11/06/'""

Feiolicats   1                            Time: 12:14
PeaK Area  •A-s  ) : 0.874                  Peak Height (A):  0.03"
Slank  Corrected Pk Heigh t (A): 0.057
Concentration (ug/L   ): 0.956


Hg2    ID:  i 8S-52-11-12/l£SV4.-5t Sea. No.:  00058    A/S Pos.:  --     Date: 11/06

Replicate   i                            Time: 12:15
Peak Area  (A-s  ) : 0.021                  Peak Height (A):  O.OOi
Blank  Corrected Pk Height (A): 0.001
Concentration (ug/L   ):  O.OSi


Hq2    ID:  i 38-52-11-12/iSJ-XMSeq. No.:  0005°    A/3 Pos.:  --     Date: 11/06-
         a   1                             Time:  12:io
Peak  Area  'A-s ) :  0.017                  Peak  Height (A): 0  001
Blank C o r r e c t e d P k. H e i g h t « A ) : 0 . 001
Concentration (ug/L  ) :  O.Olfc
Hg2    ID:  !. C:V4 -e . Oug L       5ea. No.:  OOOfcO    A/S Pos.;  --     Date:

3ao lic.ane   1         ^^                  Time:  ..2; i 7
Peak Area  •A-SJ: ^.fcE'                  Peak Height (AJ:  0.200
& 1 a n K  Cc r r =c r.ed ° h H e i g h t i A .) :  0 . 200
Concent rat ion (ug/L   ' :  5.130
Hg:   ID:  '. C-r,a                 -;e 7,  '•<••: . ;  OOOfc.     A-'S POH . :  --     Dar.e:
-------
''=.;v  A; 6i  • •- ~ ^.   0,0^0
 •: ;. .-.Hi-  LO- i-'-ct-o P!- Height  I.A.I:  0. jO
 . -or.cent ra:.i on  i ug/ L   i:  •_'.. 010
                                          Ps?.   tie i an*  A j ;
                                                            .'.OOC.
                               jsc.  No-. :,  OOjtZ1    A.. 5 Pos
 ='.30 Lie.an a   L
:e^!-  Area  ; A- s .' :  0 . 022
  L.-j.nk  Corrected PL Height (A;:  0.001
  o neen t r a t i on  ( u g .•• L   ) :  0 . 018
                                          Ti:ne .  L2 : ZO
                                          Peak  HeiaM (A);
                                                            0.001
I
                                                                    [-•ate:  ll/Oc.-
  a2    ID:  185-26-5E D
                                         000&3-    A/'S Pos. :  --    Date:  11/06
.tesDLic.ate   i
i:psal-  Area  ( A-s ) -  0 . 021
 i-lank Corrected Pk Height '. A ) :  O.OOi
fl.oncentrati on (ug.L   ; :  0.025
                                          Time:  L2:2i
                                          Peak Height  (A):  0.00i
 Ha2   ID:  .tS5-2o-5F
It
Sec. Nc.:  00064
 ^aolicaca  i.
; Peak Area ( A-s);  i.70"
16 lank Corrected Pk height (A); 0.074
Loncent.ration tug/L   ):  1.922
                                                   A/S  -'os. :  --
                                          Time:  12:22
                                          PeaK Height  (A):  0.074
                                                                    Data:
       ID:  185-26-5F D
                               Sea. No.:  0006=
"Rsoiicats  1
llPeak  Area •" A-s * :
IB lank Corrected Pk. Height (A):
 Concentration (ug/L   ) :  2.172
                                  .084
                                                   A/S Pos.:  -•-    Date:  11/Ofc'-"
                                          Peak  Height  (A):  0.084
 Hg2    ID:  185-26-5G
                               Sea. No.:  OOOfefc    A/S  Pos,:  --    Date:  11/06.'
 delicate   1
  eak Area  ( A-s ) :  0 . 048
 Blank  Correctec  Pk Height (A.):  0. OO'I
 [Concentration (ug/L   ):  0.04"7
                                          Time:  12:24
                                          Peak Height  (A):  0.002
JH'22    1C':  !35-2=.-5G D
I
••3 so), icata   j
.peak Area  lA-s.1:  0.043
'Blank  Corrected P!- Height  (A;:  0.
."-cncen t rat ion ( ua.' L   .> :  0 . 03°
                                          Time:  12:25
                                          Peak  Height  i A • :  0 . 0(
                                                                    Date:
      ID:  i88- 5Z-.i3-
                               Sea. nc  :  OOOos
                                                   A/S Pos.:
                                     Date:  11.Oo
  >,:• Lir.$r&   i                              :ime:  l2:Zo
  •:•»!•- Area  'A-s-;  :.-.0.3                   Peak  Height  (A):  J.OOI
  ar,K 'l.-ji-rpc Tad °k Heignt  ( H ) :  O.OOi
-------
       1C:  186- 52 • 11- 14 •'.1 SS^feiCjSec; „  No.: OOOt^    A, 5 Pas.
ceoli':ate   L
r-'eak  Area  i A-s ; :  0.. 023
•Blank Corrected  Pk  Height (A): O.OOi
Concentration  lug/L   .) :  0.023
                                  Time:  12:27
                                  Peak Hsight  iA ) :
                                                           Dite: 1 1 'Oi
       ID:  185-2fc-&D
                            No.: 00070
                   A/S Pos.:  --
                Date:  li/Oe
'.-'solicate   L
Peak  Area  (A-s>:  0.054
(Blank Corrected  Pk  Height ;A
                         0 .00;
Concentration  ( ug/'L
                  0.055
                                  Time:  12:29
                                  Peak Height  (A;:  0.002
       ID:  185-26-6D  D
                       Sea. No.: 00071
                   A/S Pos.:  --
                Date;  11/Ot  •"'
 Peolicate   1
 Peak  Are?.  (A-s;:  0.057
 8 lank Corrected  Pk  Height (A):  0.002
 Concentration  lug/L  ):  0.057
                                  Time:  11:30
                                  Peak Height  (A) :  0 00'
       ID:  1S5-26-6E
                       Seq. No.: 00072
 Replicate   1
 Peak  Area  (A-s):  0.00^
 Slank Corrected  Pk.  Height i A) :  0.000
 Concentration  i ug/'L  ) :  0-.010
                   A/S Pos.:  --
                                  Time:  12:3i
                                  Peak Height  ('A):  0.000
                Date
Ha2
ID:  l85-2fc-6E D
Seq. No.:  00073
Replicate   1
Peak.  Area  (A-si:  0.00°
8 lank Corrected  Pk  Height (A):  0.000
Concentration  (ug/L  ;:  0.005
A/S Pos.: --
                                  Time:  12:32
                                  Peak Height  (A):  0.000
Date: 11/06-
Ha 2
ID:  CCV5=t.Oug/L
Seq.  No.:  00074
     icate   1
Paaf- Area  ( A-s i :.  4.855
Slant-  Corrected  Pk.  Height '.A)
Concentration  iug/L   > :  5.482
                                                 A/S Pos.: --
                                 Time:  12:36
                                 Peak Height  (A):  0.21:
                Date:  11/Ot '-"
       ID: CCB5
Peolicat-?   1
Pea!-. A r e.a  ! A-s > : 0 . 02 1
8 1 a n k Corrected Pk He L qht
                       Seq. No,: 00075
                     A) :  0.00 1
Co nc e n t i  a 11 o n  i LI .\ / I   )   0 . 0 i t.
                                                  /S Pos.:  --
                                 Time:  12,3"
                                 Peak Height  < A .':  C 00.
                                    Date:  11/Oc ':1"
-------
 '•->:-:, :. ic.jite  i                             rirne:  12:5,3

 8 !. .-.nk. C o r rec L'.ed Pk  Height i A )  ; 0 ,511
 lil. o n c e n t" 311 o n • u g ; L   ) :  8 . 0 5 .1
 &3-
       TD:  i55--26--,F D         Sea. No.. 000 "1~     A/S Pos,: --    Date
]-.' Pe- 1 ic •?. cs  1                             T i me :  12 : 59
 Pea-' A-ea ' ^-s i : 7.. 511                   Pea!-. Height (A): 0.33t
 [B I i •")!-  Co r r r=c ted P k.  Height ( A ) :  0 . 536
 (Concentration  t'ug/'L   ):  8.t?95
 |Hc:   ID: 135-26-6G           Seq. No.:  00073    A/S Pos.: --     Date:  11 / Oe, ''''-"

,'t|F.ac Licate  1                             "ime: 12:59
iPeak Area i A-s ) : 0.1 bO                   Peak Height -A): O.OOr,
 "6 Lank Corrected Pk. Height (A): 0.006
 Concentration  (ug/L   i:  0.16&
 i
 i	"	"	      '     "                 s     ""'          "
 Hgl   ID: 1S5-26-6G  D         Sea. No.:  00079    A/S Pos.: --     Date:  ll/Ofc-'-'

 Reclicate  1                             Time: 12:40
 Peak Area iA-s ): 0.171                   Peak Height (A): 0.007
 Siank Corrected Pk Height (A): 0,007
 Concentration  lug/L   J:  0.174

 Hg2   ID: CCV6 = 6. Oug./L        Seq. No.:  00080    A/S Pos.: --     Date:  ll-'Oc.-'^'
I
 Reolicate  1                             Time:  12:41
'|Peak Area ( A-s j: 4.^69                   Peak Height (A): 0.226
[aijink Corrected Pk  Height (A]: 0.226
 Concentration  (ug./L   ):  5.856


'Hg2   ID: CCBt..                Sea. No.:  00081     A/S Pos.: --     Date:

("Reoiicate  1                             Time:  12:42
 Pe=K Area (A-sJ: 0,030                   Peak Height (A): 0.001
 Blank Corrected Pk.  Height (A): 0.001
 Concen t ra r.i on  i ug/' L   ) :  0 . 023


 HgZ   ID: 45452 MB2           Sea. No.:  00082     A/S Pos.: --     Date: 11/06 "~"

'3e™ i ic.ate  1                             Time:  15:11
JPeak Area i A-s ; : 0.01.8                   Peak Height (A*: 0.001
Blank Corrected Pk  Height (A): 0.001
Concentrail on  (ug/L   ):  0.01 £


H?Z    ID: 43452 MB2 D         Sea. No.:  00033     A/'C Pos. : --     Date: L 1 X0o •'^'
-------
•"-'•=•-• i. L '."•••a t. A » :  0.iCiC
Slank Corrected Pk Haignt  (A):  0,199
Concentration ( ug.- L   /:  5. 15^


Hg.2    ID: 43452 LCS D         Seq. No.:  00085     A/S Pos . : —     Date: 11 /Oo/1

P ec- 1 1 c.3 te  1                             T i me :  1 3 ; i 4
Peik  Area ! A-s ) :  4 .. 50^                   Peak.  Height. (A;:  0.200
Blank Cor recced Pt< Height  (A):  0.200
Concent rata on (. uci/ L   ) :  5 ,. 130


Kg2    ID: I35-26-5D           Seq, No,:  00086     A/S Pos.: --     Date: 11/0&/1'

-ieDlicate  L                             Time:  13:15
PeaK  Area '.A-s):  0,0 it.-                   Peak  Height (A):  0.00'i
6iani- Corrected Pk Height  (A):  0.001
Concantrat •. on (ug/L   i:  0 . 03o
Hg2    ID:  1S5-26-5D D         Seq. No.: 00087     A/S Pos.: --     Date: ll/0fc/c"

•Real ic.ate   1                            Time:  13:16
Peak  Area  t A-s.i; 0.02S                  Peak Height (A): 0.001
Blank Corrected Pk Height  (A):  0.001
Concentration (ug/L   ): 0.02°


Hg2    1C':,  185-26-5D ME        Sea. No.: OOOSS     A/S Pos.: --     Date; ll/0c./0"

dedicate   1                            Time:  13: IS
Peak  Area  < A-s »  : 4,459                  Peal- Height (A): 0.201
8 1 a nk Co r i - ect ed Pk H e i ght  (A ) :  0.201
Concentration (ug/L   ); 5.204


Ha2    ID:  i85~2fc.-5D MSC'       Seq. No.; 0008^     A/S Pos.: --     Date: 11/06/'^"

*3D lichee   L                            Time:  13:21
Peak  Area  'A-s); 4.7it                  Peak Height (A«: 0.215
8 Lank  Corrected Pk Height  (A):  0,215
C once nt r at i o n i u g/L   i: 5.561


Hg2    ID;  138- 52- 17- 137 l£5-2fc-7t Seq . No.: OOC^'O     A/S Pos.: --     Data: 11/06/""

•5-3DL ic.ate   i                            Time:  13:24
PesK  Area  '. A-s): 0,015                  Peak Height (A i : 0.001
81-Snk '. Or i'^C ted  Pk H,21'.ihr  (A);  0.001
                                                                e:
-------
 '.o'icent •• at n on
       ID:  lSS-5_-l7-iS
                             No. :
 -eolicate   1
 t-eak Area  (A-s :  0.01.2
 ELank  Corrected PR Height i. A) •. 0.000
 Concentration iug/L   ): Q.GIG
                                                  A/S PCS.
                                         "irrie-:  13-: 26
                                         Pe ak  Hei gh t ( A )
                                                            Dat
                                                                         11
       ID;  CCVl-c,Oug/L
                                   Ho,
                                  0 o O 9 2
               A/S Pos.: --
'"peoLicate   1
'HPeak  Area  iA-s •:  5.150
 3 Lank Corrects 3  Pk Height iA): 0.224
 Concentration --jg/L   ):  5.81.1
                                         '" ime :  13:27
                                         Peak Height (A): 0.214
                 Date.  11 .'O
I
      ID: CC81
                        Decs,  No,
  spLicate   1
,'iPsak Area  (A-S';  0.022
felank Corrected  Pk Height (A::  0.001
Concentration  iug/L  !:  0.013
OOO93
A/ 5 Pos.: --
                                  Time:  13:28
                                  Peak  Height (A): O.OOi
                                Date:  11/06
       ID:  185-2o-7D
                              3ea, No.:  00094
     icate  1
[IJPeak Area (A-s :  0.02S
 klank Corrected Pk Height (A): 0.001
 Concentration i-jg/L   >: 0,02c-
                                            A/S Pos.:  --
                                         Time:  13:2^
                                         Peak Height (A>: 0.001
                                jate:  11/06/9-
 Hg2   ID:  185-26-70 0
                              Sec. No.: 00095
  Replicate   1
  eak  Area  (A-s,;  0.022
 Slank Corrected Pk. Height 'A): 0.001
 Concentration i-jg/L   ): 0.03b
                                            A/S Pos.
                                         Time:  13:30
                                         Peak Height (A;: 0.001
                                Date:  11/O6/9"
ID:  185-2s-7E
                              c,,= ri
                                   No
,,,?8Di icate   1
 ..-•eak Area  ( A-s .' :  0.006
 •'?lank  Correcfcso  Pk Height i, A'< : 0.000
 Concentration  'ug-L   ).-  0.000
               A/S Pos.: --
                                         T ime:  13:31
                                         Peak Height (A):
                                                                   Date:  ll.-'Ob/~'"
 Ig2    ID:  JS5-Ic-7E C>
No.. :  GOO13 7
 ;eplic.at3   j.
 ;eak Area  ( A-s .' ;  0 . 008
 llUank '."orr-ecte^  Pk Height "A). 0,001
 oncent ration  ->jg/L    .' :  (.'.OJ3
                                                  A/S Pos
                                         T i ne:  L3:32
                                         Peak Heiaht (A ) :
                                                      001
                                                            Date:  11/06
-------
       1D :
                       Sea. No,;  000^8
                                                 A/S Pc-s-.. : --
                                    Date: 1 i.•'-•
PeoLvcate   i
Pea!-- A re. a  ( A-= > :  .  021
BLanK Corrected  PL  Height  (Ai;  0-000
Concent ration  (uc  L   ):  0.OOS
                                  Time:  13:53
                                  Peak  Height ( f> > :  0.000
Hg2   10: 185- 26- "-8H D

Peplicate  1
Peak Area (A-5-: 0 017
Blank Corrected F'- Height  (A):
Concentration (ug/'_   ): 0.018
                              Sea,.  No, :  00099
                                           A/S Pos.:  --
                                0.001
                                        Time: .13:34
                                        Peak Heiaht ( A j : 0.001
                                    Date: 11/06/""
       ID:  l85-2c—7&F8H
                       Sea. No.: 00100
                    A/S Pos.
                                                                 Date:  11/06/9"
ReoLicate   1
Peak Area.  \ A- =• ) :  0.065
8 Lank Corrected  P!-  Height  (A):  0.003
Concentration  • ua.-I   ):  0.075
                                  Time:  13:35
                                  Peak  Height ( A .>:  0.003
Hg2
ID: lS5-26-~GF3H D
Seq. No.: 00101
3eo L icate   i
Peak Area  (A-s):  0.067
SlanK Corrected  PK  Height  (A):  0.003
Concentration  (ug/L   ):  0.065
                                                 A/S PCS,
                                  i ime :  13 :3t>
                                  Peak  Height (A;:  0.003
Date: 11/06/0"
       ID:  185-2fc-~CD
                       Sea. No.: 00102
Peso L ica te   1
Peak Area  (A-s ; :  0.007
Blank. Corrected  P'*  Height  (A):  -0.000
Concentration  (ug.'L   ):  -0.003
                    A/S  Pos.:  —
                                  Time:  13:37
                                  Peak  Height (A.1:  -0.000
                                                                 Date:  11/06/9'
Ha:
ID:  185-26-~CD D
Seq. No. :  0010:
Replicate   1
Peak Area  'A-s);  0.005
Blank Corrected  P.L  Height  (A):  0.000
Concentration  (ug/L   ):  O.OOS
                                                 A/S
                                  T Lme:  13:38
                                  Peak  Height. (A):  0. OOO
Date: 11/06/9"
      ID: CCV'I-6. vug/L
Reolicate   1
Peak Area iA-='r 5.224
Slant- Corrected !-•;• Height  (A):  0.23:
Co nee n t r a t. i o n ( u g L   ) : o . OOc.
                                 00104
                    A/S  Pos:. :  --
                                 Time :  lc •. 3^
                                 Peas-  Height ( A ' :  0. 2:
                                                                 Date:  i 1/06.'^"
                                   No. ;  001 -J5    A
-------
. ;f -:~,- ':. " '"a t 5   j.
 •' f: ~~, '•- '-i r 6 a  'A - s ! .  0 . 0 2
 biViCer.tr at ion < 'jci, L   • ;  0, OOS-
i::;2    1C',  l&.?-52-l--;
                    it


H.ank  Cor recced Pk  H>
,-o n c e h T r a: i o n ( LI g •' L
                                          : 'ii::- .  t I  4 L
                                         - e a K H e:.. a '•:-. t  <. A j ;  0 . 0 0 J
                                                                   Date:  i i  06-~
       JC--  188-52-lv-20-21/    Seq.  No,
                      /W-2t>iJfc £>
            i
  eak  Area  (A-s):  0.018
 blank Corrected Pk Height (A);  0,001
 toncentration lug/L   ): 0,01t-
                                        0010'
                    A/5 PCS.: --    Date:
                                         rime :  13 ,• 42
                                         Peal- H e i cj h t -. A » :.  0 , 00 i
 i-i

I
      10:  135-26-3DE
Sea- No. :  00i OS
 .eolicate  1
 'e3k Area (A-s): 0.012
flank Corrected Pk Hai-gnt (A j :  0.000
poncentration i ug.;L   )•  0.005
          T ime:  LZ: 43
          P- ea !• H e i g h t ( ft ) :  0 . 0 0 0
                                     Dare :-  1 JL  Oe -'9"
       ID:  1S5-26-3DE D
                              Sea. No.: 0010^     A/S Pos.: --     Date:  11/06/9"
 Dedicate  1
1'1'eak  Area (A-s):  0,012
 liank Corrected Pk Height  (A):  0,001
 Concentration (ug/L   ): 0.013
                                        Time;  13:45
                                        Peak Height (A):  O.OOl
 Hg2    ID:  185-2t-SE
                              Sea. No.: 00110     A/S Pos.:  --     Date:  11/06/9"
  eolicate   i
  eak Area  (A-s):  0.013
 3 lank  Corrected Pk Height  iA):
 Concentration (ug/L   ): 0.016
                                        Time:  13:46
                                        Peak Heiciht (A): O.OOi
                                0.001
 la:
      ID:  l35-2t,-SE D
Sea. No.: 001 11     A/S Pos.: --
    J. icate   I
     Area  i A- s .' :  0 . 010
 (lank Corrected  Pk Height  (A):  0.000
 Concentration  (ug/L    ;: 0.005
                                        Time:  13:47
                                        Peak Heiaht (A): 0.000
                                     Date:  11
 a2    ID:  1S5-26-3FH
                                   No. :  0011:
 eo I i.c.ste   L
 ;,eak Area  ( A-s ' :  0.012
 lank Corrected  P!-<  height  i'A»:  0.000
                                        T ime 4  L.I ; 45
                                        Peak He j oh t. ( A ) :  0 . OOO
                                     C^ate:  i A
-------
       ID:  .135-Za-SF'H
                        5. 5G .  No. ;  001 i 1
:-p•=::;• i ic.a t .-s  J.
F'eai-:  Arej; ( K- s ; ;  0 .. 01 _
«lanK. Corrected  PK Height "' A >  O.COi
Concent ration  i ug/ L    •: 0,0 LS
                                  i Line :  13:4-
                                  Peak Hei gnt (A):  0,001
Ha;;
ID; 135-26-8FGH
 '.,ec. No, :.  00114
A/S Pos .
Date: li/06/c~
Replicate  i
Peak  Area (A-s):  O.Ooi
8 1 a n k C o r r acted P !•  H e i g h t (A ) :  0 . 0 0 5
Concentration >. ug/ L   >: 0.068
                                  rime :  13 : SO1
                                  Peak Height (A):  0.003
Ha 2
ID: 185-26-5FGH D
Seq. No.:  00115
Rap ), ica ta  1
F'eak  Area. (A-s):  O.Ot-0
Slank ijorrected Pk Height (A):  0.002
Concentration (ug/L   > .*  0.055
A/S Pos . : --
                                  Time:  lo:5L
                                  Peak Heiaht  (A )
                           0.002
Date
Hg2    ID:  CCV3-t-. Oug/ _
                       Seq. No.r 00116
                   A/S Poz
Replicate   1
Peak  Area  (A-s):  5.2SO
8 Lank Corrected Pk Height (A): 0.237
Concentration iug/L   !;  6.126
                                  Time:  13:52
                                  Peak Height  (A):  0.237
                 Date:
Ha2    ID:  CCB;
                       Sea. No.: 00117
                   A/S Pos.
Reolicats   1
Peak Area  (A-s):  0,021
Blank  Corrected Pk Height (A):  0.001
Concentration (ug/L   ?:  0.016
                                  Time:  1^:53
                                  Peak Height  (A):  0,001
                 Date:  11/06/T
Ha2
ID: lS5-2fc-8H
sea .  No . :  001 IS
                                                 A/S Pos.:  --
ReoLic.ats   1
Peak A r ea  ( A- s .' :  0 , 01 ~
Slank  Corrected  Pk Height iA):  0.000
Concentration  (ug/L   i:  0.005
                                  Time:  13:55
                                  Peak Height  (A):  0,000
                 Date:  11/Ofc/"
ID:  1S5-Z6-8H D        Sea. No.:
Pec i ica te   i
Pea « Area  (A-s ) :  0.0 J E
Slank Corrected  Pk Height (A)   0.001
Conc e n t r a t i o n  (ug/L   >:  0.01 3
          0011^    A/5 Pos. -  --

          Time :  13 : 55
          Peak Height (A):  0.001
                                                                  Date:  11 /Ob/"5"
-------
      ID  .1 88- 52- 7 ~8/ 1 85 -
                                   HO
                                                      i-'OS ,
                                                            Dar. 5; 11
'^eolic-Jte   L
^'eai- Area  \ A-s > ;,  0, 144
:-lank Corrected  Fk Height • A ) : 0 . OOe,
 oncentrat^on  (ug/L    j:  0.145
                                  Time ;  1.3 : 5e.
                                  Peak. Height  :
                                                          0 .
 •Io2   ID:  188-52-7-3/185-2fc-?cj)Sea. No.:  0012.     A/3 Pos.: --    Date:  il/Ot'9-
 aplicate   i
 eak Area  (A-s ):  0. l 40
 Lank Corrected  Pk Heigh: iA): 0.00^
 Concentration  (ug/L   ): 0.148
                                        Time: 13;5T
                                        Peak Height.  (A»:  O.OCc-
iq2    ID:  185-26-9D-11
                              Sea. No.:  00122
                                                 A/5  Pos.:  --
                                                            Data
  (eDlicace   i
  eak Area  ( A~s ):  0 . 42'^
  Lank Corrected  Pk Height (A): 0.019
 .••oncentration  (ug/L   ): 0.499
                                        Time: L3:S*
                                        Peak Height.  (A):  0.01°
t
Hg
ID:  185-26-9D-11  D
                              Sea, No.: 0012Z-
                                                  A/S Pos.; --
Replicate   i
 Peak Area  (A-s):  0.392
 |iLank. Corrected Pk Height (A.): 0.017
 concentration  (.ug/L  ): 0.452
                                        Time:  14:00
                                        Peak Height  (A):  0.01"7
Date: ll/Oc/9~
  g2   ID:  1S5-26-9E
                              Sea.  No.:  0012^
                                           A/S  Pos. :
                                                                  Date:  11/0-/9'
jReplicate   L
•peak Area  (A-s):  0.200
plank Corrected  Pk Height (A): O.OO8
 Concentration  (ug/L  ): 0.210
                                        Time:  1.4:01
                                        Peak Height  (A):  O.OOS
I
 g2   ID:  1S5-26-9E  D
 teplicate   1
 eak Area (A-s ) :  0.202
Blank Corrected  Pk  Height iAi:  0.009
toncentration  (ug/L  ):  0.234
                                        00121    A/'b Pos . r  --

                                        Time: 14:02
                                        Peak. Heioht (A):  0. OO1-1
                                                            Date: ll/:-c-'9
jo
      ID:  185-2fc.-9F
                               SG.  No.:  0012c    A/S Pos,:  --
,H8D 1 ica te   i
i;;'eai-  Area ( A-s i :  O.t/95
ilank Corrected  Pk  Height >, A) :  0.030
loncentration  (ug/L  ):  0.785
                                        Time : 14: 0.1
                                        Peak Height  (A):  0.030
                                                            Date:
Ig2   ID: 135-26-9F  [.•
                              Seq.  No.:  0012'
-------
                                         f i;re .
 e :->. i-  A r •'-• a  " '-i - s .' :
  '.a •"•!-.  co r r e>~ ted F u.
                          0.
       ID:  OCV4 :-o . O'jg/ L
                               See.  No :  00123
 -.eolicate   1.
 £'e;-u- Area  ( A-s ) :  ~,27-a
 3 1 .a n K  C o r r e c t e d P k H e i g h t  ( A ) :  0  2 3 0
 Concentration (. ug/ L   J :  5.96?
A/S Pos. :  --
                                         T ime:  14:05
                                         Peak Heiaht  (A;;  0.2GO
Da r.e .  i i ' Ob ••• •" '
Ha2    ID:  CCB4
''•'eak Area  i A-s .' t  0 . 02"
3 Ian!-.  Cor-rected Pu' Height  (
'Concentration IUQ/L   )r 0.0
                               iea.  No . :
                                 0 OO1
-./£ PCS. L  --
                                         Time:  14:06
                                         Peak Height  !A < •  0.OOi
Date: 11/0*
       ID:  183-52-1 5-16/lBJ-.2i-io<:£ec.  No.:  00130    A/S  Pos
    i. Lcafce   1
Peat-.  Area  (A-s):  0
SlanK Corrected Pi- Height  i ri) :  0  001
C once n t r a t i o n ! u g / L.   j : 0.0 3 i
                                         Time: 1-4:08
                                         Peak Heiaht  (Aj:  0.001
                                                                   Date:  ll/06/ = "
       ID :  188- 52- 1 5-1 6/ 18f-.2<.-/«i(3ea -  No . :  00131    A/S  Pos
Replicate   1
PsaK  Area  (A-s»rO.O30
Blank Corrected Fk Height  (A):  0.001
Concentration (ug^L   >: 0.034
                                         Time:  14:09
                                         Peak Height  (A):  0.00.1
                                                                   Date:  ll/0'b/-"
Hg2    ID:  135-26-1OD
                               Sea.  No :  00132    A/S  Pos.:  --    Date:  11/06/0"
Reoiicata   1
Peak Area  i A-s '.' :  0 . 060
8 lank Corrected  Pk. Height  (A):  0.002
Concentration (ug/L    > -.  0.057
                                         Time: 14 : 10
                                         Peak Heiaht  (A j:  0.00:
Ho2    ID:  1S5-26-10D C-
                               Sea.  No.:  00133
Rer-licate   J.
Peak Area  (A-s):  0.OoO
8 lank Corrected P!- Height • A i :
Concentration  iug/L    i :  0,0o2
                                  . 'JO 2
                                                      Pos.:  --
                                         Time:  14:11
                                         Peak Height.  ( A ) :  0 . 00;
                 Date: 11/06/1"
Hgl   ID:  185-2&-10D M'Z

:Reo i;. ca?:e   1.
Pea-1  Area  ', A-3 ) ;  - . 5~~?
3 1.-. r t- 'I'D r ;' e':. c '-^ <:!  P '• H 3 i •:; n i:
                                IQ . No. :  00134
A/S ^os.:  --
                                         T ime :  1 ••! : 12
                                         Peak Heiaht i ft
                                                                   Date;  11
-------
     en , rat io',  i ug L
       ID.  155-26-100 MSD
                               3t? ci
 ''••eo 1j-C.s ts   L
 Peak Ar-sa  i A-s ) :  4 , 70t.
 * lank. Cor recced  Pk Height i A ;• : 0.219
 C.oncen tration (ug/L   ): 5.674
                                                   A/S PCS.
                                          T inn--- :  l.
i.| :Reol icate   1
 'Peak Area  (A-s):  0.038
  8 Lank  Corrected Pk Height (A): 0.001
 I Concentration (ug/L  ): 0.031
                    A/S  Pos.:  --
                                          Tim'2:  14:14
                                          Peak Height (A):  0.00.1
                                                                   Date:  11 /Oc.  -"
  Hg2
        ID:  185-2fc.-10E D
     No.: 00137     A/S  Pos.
;,  Reolicata   1
_ Peak  A r ea  iA-s ) :  0 . 032
I 8 Lark Corrected  Pk Height (A):  0,001
'Concentration  (ug/L   ); 0.. 021
I

t
                                          Time:  14:15
                                          Peak  Height (A):  0,001
                                                                   Date:  11/06/s
        ID:  185-26-10F
                               Sea.  No.:  00158    A/S Pos.
  Replicate   1
  Peak  Area  (A-s):  1.545
  Blank Corrected Pk Height (A):  O.C&7
  Concentration (ug/L   ): 1.746
                                          Time:  14:16
                                          Peak Heiaht (A): 0.067
                                    Date:  11/06-''0'
  Ha2    ID:  185-26-10F D
                               Sea.  No,
  Reolicate   i
'  Peak Area  (A-s):  1.691
I  5 lank Corrected Pk Height (A): 0.077
  Concentration  (ug/L   ): 1.9^8
          00139     A/S  Pos.;  --

          Time:  14:17
          Peak Height  (A):  0.07"
                                                                   Date:  11/06/'-"
 Hg2   ID: CCV5=6.0ug/L       Sea. No,

 Rsolicate   1
 Peak Area I  <-i~s / :  5.22"
 Slar.K Co-rected  Pk Height (A): 0.225
 Conce n t r a t :i o n  i u g/ L   > :  5.814
                                          00.140
                                                   A/S Pos.:
                                          Time:  14: IS
                                          Pea!-  Height (A) :  0,
                                    Date:  11/Ob.'1-"
 Ha 2
       ID:  CC&S
Sea.  No.: 00141
 :Reo1icate   1
 iPeak Area  ;A-s i :  0.02S
 S L a n k Go r- r ec t ed  P k H e L g h t L A ) : 0.001
 Concentration  (ug/L  ): 0.021
                                                   A/S  Pos.:  --
                                          Time:  14:1?
                                          Peak  Height (A):  0.001
-------
 APPENDIX D




-------
          Example Calculations for Pollutant Emissions



1.     Volume of dry gas sampled corrected to standard conditions, ft3.

      Note: Vm must be corrected for leakage if any leakage rates exceed La.
                                                Pbar  +
                     Vmstd = 17.647  *  Vm * y *
                                                  Tm, °R






2. Volume of water vapor at standard conditions, ft3.



                         Vmstd = 0.04707 * Vic + 0.04715 * Vsg



3. Moisture content in stack gas, dimension less.
                              _          Vwstd
                              Bws =
                                     Vwstd  +  Vmstd




4. Dry molecular weight of stack gas, Ib/lb -mole.



                  Md = 0.44 * %CO2 + 0.32 * %O2 + 0.28 * (%N2 + %CO)



5. Molecular weight of stack gas, Ib/lb-mole.



                            Ms=Md (1-Bws) + 18* BWS



6. Stack velocity at stack conditions, f/s.
                     Vs = 85.49 * Cp * avei&P  *
                                                \
 Ts,  °R

Ps * Ms
7.  Stack gas volumetric flow rate at stack conditions, cfm.



                                 Qs = 60*Vs *As



8.  Dry stack gas volumetric flow rate at standard conditions, cfm.
                     Qsstd = 17.647  * Qs *   Ps   * (1 -Bws)
-------
 9.    Concentration in gr/dscf.
                         CS= (0.01543) (— 22— \
                                          Vmstdj
10.   Pollutant mass emission rate, Ib/h.


                    pair, Ib/hr = l\ x Qsstd x 60
11.   Pollutant mass emission rate, Ib/mmbtu


                      pmr, Ib/mmbtu =
                      *
12.   F-f actor (Fd)


         106 (3 . 64x%#) + (1. 53x%C) + (0 . 57x%5) + (0 .14x%.A7) - (0 . 46 x%O,)
    PW =  ^—	•—	—
                                 GCVtiJtU/Ji)




13.   F-f actor, pollutant mass emission rate, Ib/mmbtu


                            Ib/dscf x F x 20.9

                               (20.9 - % 02)




14.   Heat input, mmbtu/hr fuel


                                  * Feed Rate  (Ib/hr)
                                    106




15.    Heat input, mmbtu/hr, F-factor.



-------
          EXAMPLE CALCULATIONS FOR POLLUTANT EMISSIONS

                  GASEOUS POLLUTANTS MEASURED BY
                CONTINUOUS EMISSIONS MONITORS (CEMs)
1)     Concentration, part per million, dry basis:
                        ,             ,   .        BWS, %.
                   ppm, dry = ppm, wet basis + (I-  	)
                                                  1U\J
2)     Pollutant Mass Emission Rate, pound per hour.
         PMK, Iblhr - ppm' dry * ComP°und Molecular Weight
                                (385.3 x  10 6)
      Molecular Weights of Target Compounds

      TOO  =    Total Gaseous Organics          44.09
      SO2   =    Sulfur Dioxide                 64.05
      NO2   =    Nitrogen Oxides                46.00
      CO   =    Carbon Monoxide               28.01
      BWS  =    Proportion by Volume of Water Vapor in the Gas Stream
-------
            Nomenclature and Dimensions

An    =     Cross-sectional area of sampling nozzle, ft2

As    =     Cross-sectional area of stack, ft2

Bws   =     Proportion by volume of water vapor in the gas stream, dimension less

Cp    =     Pitot tube coefficient, dimension less

Cs    =     Concentration of pollutant matter in stack gas-dry basis, grains per dry
            standard cubic foot (gr/dscf)

%CO =     Percent of carbon monoxide by volume, dry basis

%CO2=     Percent of carbon dioxide by volume, dry basis

AH   =     Average pressure drop axross the sampling meter flow ofifice, inches
            of water (in. H2O)

GCV  =     Gross calorific value, Btu/lb

I     =     Percent of isokinetic sampling

La    =     Maximum acceptable leakage rate for either a pretest leak check or for
            a leak check following a component change/ equal to 0.020 cubic foot
            per minute or 4% of the average sampling rate, whichever is less

Md   =     Dry molecular weight, Ib/lb-mole

Mn   =     Total amount of pollutant matter collected, milligrams (mg)

Ms    =     Molecular weight of stack gas (wet basis), Ib/lb-mole

%N2  =     Percent of nitrogen by volume, dry basis

%O2  =     Percent of oxygen by volume, dry basis

AP    =     Velocity head of stack gas, inches of water (in. H2O)

Pbar  =     Barometric pressure, inches of mercury (in. Hg)

-------
Pstd  =      Gas pressure at standard conditions, inches of mercury (29.92 in. Hg)
pmr  =      Pollutant matter emission rate, pounds per hour (Ib/hr)

Qs    =      Volumetric flow rate - wet basis at stack conditions, actual cubic feet
             per minute (acfm)

Qsstd =      Volumetric flow rate - dry basis at stack conditions, actual cubic feet
             per minute (dscfm)

Tin   =      Average temperature of dry gas meter, °R

Ts    =      Average temperature of stack gas, °R

Tstd  =      Temperature at standard conditions, 528°R

Vic   =      Total volume of liquid collected in impingers, ml

Vsg   =      Volume of moisture collected in silica gel, grams

Vm   =      Volume of dry gas sampled at meter conditions, ft3

Vmstd=      Volume of dry gas sampled at standard conditions, ft3

Vs    =      Average stack gas velocity at stack conditions, ft/s

Vwstd =      Volume of water vapor at standard conditions, scf

y     =      Dry gas meter calibration factor, dimensionless

0     =      Total sampling time, minutes

-------
  Appendix D. 1




   Calculations




-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION • SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Inlet
Page 1 of 4



•static
y
Pbar
vm
AP1/2
AH
Tm
Ts
Vlo
CO2
02
N2
cp
©
Dn

An
Vm(std)
Vm(std)
Qm
PS
Bws
Bws(sat)
Vwstd
1-BWS
Md
Ms
vs
A
Qa

Q!
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Stack Static Pressure, inches H2O
Meter Box Correction Factor
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Square Root Ap, (in. H2O)1/
Avg Meter Orifice Pressure, in. H2O
Average Meter Temperature, °F
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volum
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, ft3
Standard Meter Volume, m3
Average Sampling Rate, dscfm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volum
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
I-M29-1
9/23/97
1410-1841

-19.75
1.024
29.74
60.951
0.9292
0.96
92.0
125
316.3
8.90
12.30
78.8
0.84
115.0
0.192

0.000201
59.458
1.684
0.517
28.29
20.0
14.0
14.888
0.860
29.92
28.25
57.1
23.94
81,999
60,183
1,704
102.3
I-M29-2
9/24/97
0934-1343

-19.75
1.024
29.85
120.696
0.9177
0.90
74
128
1112.6
9.40
12.70
77.9
0.84
237
0.192

0.000201
122.140
3.459
0.515
28.40
30.0
15.1
52.370
0.849
30.01
28.20
56.5
23.94
81,108
58,682
1,662
104.5
I-M29-3
9/25/97
0838-1149

-19.75
1.024
29.10
107.091
0.9170
2.77
76
133
914.0
10.00
12.20
77.8
0.84
120
0.260

0.000369
105.757
2.995
0.881
27.65
28.9
17.7
43.022
0.823
30.09
27.95
57.7
23.94
82,857
56,090
1,588
102.0
I-M29-4
9/25/97
1512-1845

-19.75
1.024
29.10
109.178
0.9172
2.75
101
137
950.9
11.00
11.90
77.1
0.84
120
0.256

0.000357
103.008
2.917
0.858
27.65
30.3
19.6
44.759
0.804
30.24
27.83
58.0
23.94
83,329
54,702
1,549
105.1
Average


-19.75
1.02
29.45
99.48
0.92
1.85
85.75
130.75
823.45
9.83
12.28
77.90
0.84
148.08
0.23

0.00
97.59
2.76
0.69
28.00
27.31
16.59
38.76
0.83
30.06
28.06
57.31
23.94
82323.35
57414.26
1625.79
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Inlet
Page 2 of 4





PM
PM
PM
CPM @ 7% O2
CPM
CPM @ 7% O2
EPM
CPM
EPM

Sb
Csb
CSb @ 7% 02
ESb

Ar
CAT
CAT @ 7% O2
EAT

Ba
CBa
CBa @ 7% O2
EBa

Be
CBe
CBe @ 7% 02
EBe

Cd
CCd
CCd @ 7% O2
Ecd
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
Participate Mattel
Filter Weight Gain, mg
Beaker Weight Gain, mg
Total Catch, g
Concentration, gr/dscf @ 7% O2
Concentration, g/dscm
Concentration, g/dscm @ 7% O2
Emission Rate, kg/hr
Concentration, gr/dscf
Emission Rate, Ib/hr
Antimony (Sb)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
Arsenic (As)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
Barium (Ba)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% 02
Emission Rate, Ib/hr
Beryllium (Be}
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% 02
Emission Rate, Ib/hr
Cadmium (Cd)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% 02
Emission Rate, Ib/hr

I-M29-1
9/23/97
1410-1841


996.6
38.4
1.0350
0.434
0.61
0.99
62.9
0.269
138.6

63
37
60
0.0084

26.3
15.6
25
0.00351

307.3
183
295
0.0411

0.00
0.00
0.00
0.000000

82.9
49
80
0.0111
made.
I-M29-2
9/24/97
0934-1343


1362.7
1291.5
2.6542
0.57
0.77
1.30
77
0.34
168.7

53
15
26
0.0034

81.5
23.6
39.9
0.0052

1,103.0
319
541
0.070

2.4
0.69
1.17
0.000151

241.5
70
118
0.015

I-M29-3
9/25/97
0838-1149


1669.3
981.7
2.6510
0.62
0.89
1.41
84
0.39
186.0

211
71
113
0.0148

64.3
21.5
34
0.0045

743.5
248
397
0.052

0.00
0.00
0.00
0.000000

233.8
78
125
0.016

I-M29-4
9/25/97
1512-1845


2015.7
1051.2
3.0669
0.71
1.05
1.62
98
0.46
215.4

249
85
132
0.0175

82.5
28.3
44
0.0058

991.5
340
525
0.070

0.00
0.00
0.00
0.000000

184.0
63
97
0.013


Average



1511.08
840.70
2.35
0.58
0.83
1.33
80.36
0.36
177.17

144.04
52.12
82.69
0:Q1(

63.63
22.22
35.78
Q.OO

786.34
272.41
439.32
0.06

0.60'
ai7
Oi29
0.00

185.55
65.05
105.03
0.01
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Inlet
Page 3 of 4



Cr
CCr
CCr @ 7% O2
Ecr

Co
CCo
CCo @ 7% O2
ECO

Pb
CPb
CPb @ 7% O2
Epb

Mn
CMn
CMn @ 7% 02
EMn

Hg
CHg
CHg @ 7% O2
EHg

Ni
CNI
CNi @ 7% O2
ENi
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Chromium (Cr)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% 02
Emission Rate, Ib/hr
Cobalt (Co^
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Lead (Pti\
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Manganese (Mn)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Mercury (Hg^
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Nickel (Ni)
Target Catch, ug
Concentration, pg/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
I-M29-1 I-M29-2 I-M29-3 I-M29-4
9/23/97 9/24/97 9/25/97 9/25/97
1410-1841 0934-1343 0838-1149 1512-1845


472.8
281
454
0.0633

21.7
12.9
20.8
0.00291

9,567
5,682
9,184
1.28

61,293
36,405
58,840
8.21

8.00
4.7
7.7
0.00107

26.2
16
25
0.0035


1,016.9
294
498
0.065

40.9
11.8
20.0
0.00260

13.225
3,824
6,482
0.84

144,141
41,676
70.646
9.16

11.10
3.2
5.4
0.00071

45.6
13
22
0.0029


775.7
259
414
0.0544

31.7
10.6
16.9
0.00222

24,762
8,269
13,211
1.74

107,629
35,940
57,421
7.55

101.21
33.8
54.0
0.00710

45.6
15
24
0.0032


721.2
247
382
0.0507

32.8
11.2
17.4
0.00230

25,602
8,777
13,556
1.80

115,227
39,504
61,011
8.09

17.40
6.0
9.2
0.00122

33.7
12
18
0.0024
Average


746.65
270.28
437.00
0.06

31.76
11.63
18.78
0.00

18288.91
6637.91
10608.06
1.41

107072.71
38381.09
61979.66
8.25

34.43
11.93
19.08
0.00

37.77
13.88
22.41
0.00
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Inlet
Page 4 of 4






CP




Pse




CAg








P
CP
® 7% O2
EP

Se
CSe
@ 7% O2
Ese

Ag
CAg
@ 7% O2
EA9

Tl
CT.
C-n @ 7% 02




Czn

ETI

Zn
Czn
@ 7% O2
Ezn
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA- Continued
Phosphorus (P)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
Selenium (Se)
Target Catch, pg
Concentration, |jg/dscm
Concentration, |jg/dscm @ 7% 02
Emission Rate, Ib/hr
Silver (Ag)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
Thallium (Tl)
Target Catch, ug
Concentration, ug/dscm
Concentration, pg/dscm @ 7% 02
Emission Rate, Ib/hr
Zinc (Zn)
Target Catch, ug
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
I-M29-1
9/23/97
1410-1841


409.1
243
393
0.0548

20.70
12.3
19.9
0.00277

10.69
6.35
10.26
0.001431

30.6
18.2
29.4
0.00410

77,209
45,858
74,119
10.3
I-M29-2
9/24/97
0934-1343


5,581.1
1,614
2,735
0.355

56.7
16.4
27.8
0.00360

27.16
7.9
13.3
0.00173

63.5
18.4
31.1
0.00404

164,736
47.631
80,740
10.5
I-M29-3
9/25/97
0838-1149


3,334.0
1,113
1,779
0.23

37.3
12.5
19.9
0.00262

30.53
10.19
16.29
0.002142

48.5
16.2
25.9
0.00340

193,356
64,566
103,157
13.6
I-M29-4
9/25/97
1512-1845


3,280.6
1.125
1,737
0.23

40.2
13.8
21.3
0.00282

17.99
6.17
9.53
0.001264

51.8
17.8
27.4
0.00364

249,708
85,608
132,217
17.5
Average



3151.21
1023.67
1660.97
0.22

38.72
13.73
22.21
0.00

21.59
7.64
12.35
0.00

48.61
17.62
28.45
0,00

171252.30
60915.73
97558.37
12.98
-------
                                                                                           Cupola Wet Scrubber Inlet
Filter Diameter, inches: 4 TC//V 'A -T A TH T A \ '"^>"\ ' * '""
	 — • 17.59 •/l/6'o/y Tfl/>fi o /i ^U*^ 4 / ^^^ ^
int H Back H
lank RBlank
fhb Mbhb
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Cadmium (Cd)
Chromium (Cr)
Colbalt(Co)
Lead(Pb)
Manganese (Mn]
Mercury (Hg)
Nickel (Ni)
Phosphorus (P)
Selenium (Se)
Silver (Ag)
Thallium (Tl)
Zinc (Zn)
4.41 <0.40
2.1 <0.75
99.1 0.23
<0.10 <0.10
<0.10 <0.10
30.5 0.518
9.75 <0.15
4.41 0.57
18.3 0.271
<0.4 < 3.4 12
11.9 <0.30
74.7 3.28
4.57 <0.30
0.257 <0.10
0.2 0.22
49.1 4.69
Front H BackH
I-M29-1 I-M29-1
Mfh Mbh
66.5' "0.89
28.2 ^0.90
406^^0.672
<0.1/^0.12
82.8'''0.326
502' " 1.8
31.3X-X6.264
9,560 ^ 11.6
61,300-' /1 1.6
/<0.4 X3.84
37.5 -'•'6.863
476' /ll.l
25.1 ''"'6.427
10.8^-0.245
30.8 -5^0.240
77,200" ^2.7
Blank Adjusted
Front H BackH

62 0.890
26 0.000
386 0.442
0.00 0.000
82.8 0.326
477 1.282
21.6 0.264
9,556 11.030
61,282 11.329

26 0.863
452 10.10
20.5 0.427
10.5 0.245
30.6 (0.22)
77,151 59.57
I-M29-1
Adjusted
Mt
62.59
26.25
307.34
0.00
82.9
472.8
21.7
9,567
61,293
7.996
26.16
409.1
20.7
10.69
30.6
77,209
Front H Back H
I-M29-2 I-M29-2
Mfh Mbh
•S' 54.** 3.89
/ 82 ,f 1.9
/1, 170 32
s- .97
• 2.4 0.205
/ 231 10.7
" 1,020 27.9
x 46.7 4.12
"22,300 497
"140,800 3360
< 0.4 10.7
?£">56 2.06
/ 5,560 99.1
x 60 1.59
' 25.2 2.32
b3."*4 < 0.217
^60,700 4090
Blank Adjusted v
Front H BackH

50 3.890
80 1.900
1,112 31.770
2.4 0.205
231 10.700
990 27.382
37.0 4.120
22,296 496.430
140,782 3359.7

44 2.060
5,485 95.820
55 1.590
24.9 2.320
64 (0.220)
160,651 4085.31
I-M29-2
Adjusted
Mt
53.48
81.5
1,103
2.38
241.5
1,017
40.9
13,225
144,141
11.10
45.56
5,581
56.72
27.16
63.52
164,736
Front H BackH
I-M29-3 I-M29-3
Mfh Mbh
/215 ' \.09
, /*
•^66£ < 0.833
/ 836 ^6.83
//8.73
/•"41.1 Xfl.478
/24.600 S 167
/107.000 ./648
3.0 97.7
54 0 3 84
/ 3,400 ^ 12.3
/ 41-3 ^894
^y295 ^-^0.985
I/ ^49 -^0.222
-^192,300 -/"1110
Blank Adjusted
Front H BackH

211 1.090
64 0.000
794 6.600
0.00 0.000
231 2.970
768 8.212
31.4 0.478
24,596 166.430
106,982 647.729

42 3.840
3,325 11.300
37 0.894
29.6 0.985
49 (0.220)
192,251 1105.310
I-M29-3
Adjusted
Mt
21 1J
64.28
743.5
0.00
233.8
775.7
31.68
24,762
107,629
101.21
45.64
3,334
373
30.53
48.5
193356
Front H BackH
I-M29-4 I-M29-4
Mfh Mbh
253 0.565
85 < 0.825
1,090 0.796
<0.10 <0.11
184 0.175
751 1.19
43 0.165
25,600 6.53
115,200 45.5
< 0.4 16.998
46 < 0.330
3,350 8.6
45 < 0.33
18 0.146
52 <0.22
249,700 61.5
Blank Adjusted
Front H Back H

249 (0.435)
82 < 0.825
1,036 (0.204)
<0.10 <0.11
184 (0.825)
721 0.190
33 (0.835)
25,596 5.530
115,182 44.500

34 < 0.330
3,275 7.600
40 <0.33
18 (0.854)
52 (0.220)
249,651 58.425
I-M29-4
Adjusted
Mt
24S.8
82.48
991.5
0.00
184
721.2
32.77
25,602
115,227
17.40
33.73
3,280.6
40.16
17.99
51.8
249,708
Front Half Blank to be used:
Back Half Blank to be used.
                                If Mfhb < A, use Mfhb = Mfhb
                                If Mfhb > A, use Mfhb = A if A is > the lesser of Mfhb or 5% of Mfh
                                       If A is not (is <). use Mfhb = the lesser of Mfhb or 5% of Mfh
                                                       H
                                If Mbhb < I, use Mbhb = Mbhb
                                If Mbhb > I, use Mfhb »1 if 1 is > the lesser of Mbhb or 5% of Mbh
                                       If 1 is not (is <), use Mbhb = the lesser of Mbhb or 5% of Mbh
Total Catch = Mt - (Mfh - Mfhb) + (Mbh - Mbhb)

Mercury:        If (Hgfhb + Hgbhb) <- 0.6, use (Hgfhb + Hgbhb)
              If (Hgfhb + Hgbhb) > 0.6, use (Hgfhb + Hgbhb) = 0.6 if 0.6 is > the lesser of (Hgfhb+Hgbhb) or 5% of (Hgfh+Hgbh)
                              If 0.6 is not (is <), use (Hgfhb+Hgbhb) = the lesser of (Hgfhb+Hgbhb) or 5% of (Hgfh+Hgbh)
Total Hg Catch = Hgt = (Hgfh - Hgfhb) + (Hgbh - Hgbhb)
\\-\o
    £.37
13L.O
 tt,1
                                                                                                                                   10 IQ
                                                                                                                   5-5.7
                                                                                                                                                                      ni
                                                                                                                                                                                       /,
          M29ING.XUS AnalDataCorrectlons
                                                                                                                                 n z \oo
-------
            Method 29 Analytical Results (ug) and Blank Corrections
        GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
                        Cupola Wet Scrubber Inlet
Filter Diameter, in:    4
•^•H Front H BackH
^^^H RBlank RBlank
^B
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Colbalt
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Silver
Thallium
Zinc
Mfhb Mbhb
Front H BackH
I-M29-1 I-M29-1
Mfh Mbh
X' 441 ><- 0.40 66.5 0.89
X- 2.1 -"<0.75 28.2 <0.90
^99.1 /0.23 406 0.672
-/<0.10x<0.10 <0.1 <0.12
X< 0.10 -^0.10 82.8 0.326
/ 30.5^0.518 502 1.8
•/ 9.75 /< 0.15 31.3 0.264
x 4.41 ^0.57 9560 11.6
X" 18.3 / 0.271 61300 ^1.6
Front H BackH
I-M29-2 I-M29-2
Mfh Mbh
54.4 3.89
82.4 1.9
1170 32
2.37 0.205
231 10.7
1020 27.9
46.7 4.12
22300 497
140800 3360
7<0.4 < 3,412 /
-------
Isokinetic Calculation Sheet
Plant: U?M — OA^//*^^


Volume of drv gas sampled corrected
to standard conditions.
note: Vm must be corrected for any leakage rates
that exceed La.
1 AH\
Vnistd- 17.65 xVmxYx-^13'6/
Tm
Volume of water vapor at standard
rnnriitinns ftl
Vwstd= 0.04707 x V|c
Moisture Content in stack gas.
Vw
std
Bws= / \

Dry Molecular weight of stack gas,
Ib/lb-mole
Md- 440 x (%CO2)+ 320 x (%O2) +
.280x(%N2+CO)
Molecular Weight of Stack Gas
Ms= Md x (1-Bws) + 18 x (Bws)
Stack 0as velocitv at stack conditions
feet per second.
*
...... r
Vs= 8S.49x r v I. p v , s
p ^A 1 •
(P. X M.)

Isokinetic Variation
„! Vmstd x Ts x 17.32
Vs x Dnx Q x Ps x (1-Bws)



Vm, ft3
Y
Pbar, in. Hg
AH, in. H20
Vm std, dscf
Vlc
^wstd
Bws

1-Bws
%CO2
%O2
%N2+CO
Md, Ib/lb-mole
Ms, Ib/lb-mole
Pstatic, in. Hg
Ps, in. Hg
Ts, °R
/—
VAP
Cp
Vs, feet per sec.
On, in.
9,m,n.
%1


Run &Z
I2P t kf](c
r.6ZH
&>&$
WO
fQ>m








30.DI

-H.^5
t£*to
ssa

6 .^ 1 8
^,84

D-.IU
Wi3

Site: b^Pifc?
£,O-&t$4:£ ~ 3
Run 2
w.m
0.1&
iPl.tto
7.tf
*WI.$i3
Lf£*l ?
27.6/7
e.*n

&' ^^ 7



^D( o£
74.13
J-.Ti'
7*1.1$
i'/ 1= / £71 X
,q j
f ? IS'
OtQ1/
^<f
MO
M.3
*>6r(tbtev- '±A\t

Run 3
























-------
   Appendix D.2




    Calculations




-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Outlet
Page 1 of 4


PsUHic
Y
Pbar
vm
AP1/2
AH
Tm
Ts
Vte
CO2
02
N2
CP
©
Dn

An
Vm(std)
Vm(stri)
Qm
PS
Bws
BWS(sat)
"wstd
1-Bw,
Md
M8
v.
A
Qa
Qs
Qs
I
RUN NUMBER
RUN DATE
RUNTIME
MEASURED DATA
Stack Static Pressure, inches H2O
Meter Box Correction Factor
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Square Root Ap, (in. H2O)1/2
Avg Meter Orifice Pressure, in. H2O
Average Meter Temperature, °F
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, ft3
Standard Meter Volume, m3
Average Sampling Rate, dscfm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), lb/lb*mole
Stack Gas Velocity, ft/s
StackArea.fi2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
O-M29-1 O-M29-2 O-M29-3 O-M29-4
9/23/97 9/24/97 9/25/97 9/25/97
1412-1846 0938-1347 0845-1145 1523-1843

1.10
0.999
29.74
79.040
0.7231
1.57
86
125
242.0
4.00
16.70
79.3
0.84
110
0.255

0.000355
76.163
2.157
0.692
29.82
13.0
13.2
11.391
0.870
29.31
27.84
43.6
30.68
80,243
62,768
1,777
95.4

1.10
0.999
29.85
156.915
0.6680
1.23
85
133
635.1
10.60
11.80
77.6
0.84
240
0.255

0.000355
151.911
4.302
0.633
29.93
16.4
16.3
29.894
0.837
30.17
28.18
40.2
30.68
74.042
55.151
1.562
99.3

0.35
0.999
29.10
120.204
0.6330
2.81
87
109
243.4
9.70
12.50
77.8
0.84
120
0.310

0.000524
113.491
3.214
0.946
29.13
9.2
8.6
11.457
0.914
30.05
29.01
37.3
30.68
68,668
56,641
1,604
97.8

0.35
0.999
29.10
121.525
0.6440
2.93
95
109
254.4
10.30
12.40
77.3
0.84
120
0.310

0.000524
113.118
3.203
0.943
29.13
9.6
8.6
11.975
0.914
30.14
29.09
37.9
30.68
69,760
57,542
1,629
95.9
4-Run
Average

0.73
0.999
29.45
119.42
0.6670
2.14
88.3
119.0
343.73
8.65
13.35
78.0
0.84
147.5
0.283

0.000439
113.671
3.219
0.803
29.50
12.05
11.72
16.18
0.883
29.92
28.53
39.75
30.68
73.178
58.025
1,643
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Outlet
Page 2 of 4






CPM

CPM






csb




CAT




CBa




CBB







PM
PM
PM
@ 7% O2
CPM
@ 7% O2
EPM
CPM
EPM

Sb
Csb
@ 7% O2
Esb

Ar
CAT
@ 7% O2
EA,

Ba
CBa
@ 7% O2
EBB

Be
CBe
@ 7% O2
EBe

Cd
Ccd
Ccd @ 7% 02

ECd
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
Particulate Matter
Filter Weight Gain, mg
Beaker Weight Gain, mg
Total Catch, g
Concentration, gr/dscf @ 7% 02
Concentration, g/dscm
Concentration, g/dscm @ 7% O2
Emission Rate, kg/hr
Concentration, gr/dscf
Emission Rate, Ib/hr
Antimony (Sb^
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
Arsenic (As)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% 02
Emission Rate, Ib/hr
Barium (Ba)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
Beryllium (Re)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% 02
Emission Rate, Ib/hr
Cadmium (Cd)
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm @ 7% O2
Emission Rate, Ib/hr
O-M29-1
9/23/97
1412-1846


64.5
9.6
0.0741
0.0497
0.0344
0.114
3.66
0.0150
8.08

6.76
3.13
10.4
0.000737

4.94
2.29
7.58
0.000539

42.8
19.9
65.8
0.00467

0.217
0.101
0.333
0.0000237

8.61
3.99
13.2
0.000939
O-M29-2
9/24/97
0938-1347


130.9
27.5
0.1584
0.0246
0.0368
0.0562
3.45
0.0161
7.61

10.47
2.43
3.72
0.000503

6.06
1.41
2.15
0.000291

93.6
21.8
33.2
0.00450

0.507
0.118
0.180
0.0000243

23.31
5.42
8.28
0.00112
O-M29-3
9/25/97
0845-1145


19.2
6.7
0.0259
0.00583
0.00806
0.0133
0.776
0.00352
1.71

4.85
1.51
2.50
0.000320

2.03
0.632
1.05
0.000134

26.7
8.31
13.8
0.00176

ND
ND
ND
ND

4.02
1.25
2.07
0.000265
O-M29-4
9/25/97
1523-1843


14.2
11.2
0.0254
0.00567
0.00793
0.0130
0.775
0.00347
1.71

3.99
1.25
2.04
0.000268

1.58
0.493
0.807
0.000106

13.7
4.28
7.00
0.000922

ND
ND
ND
ND

2.07
0.646
1.06
0.000139
4-Riin
Average


57.20
13.75
0.0710
0.0214
0.0218
0.0491
2.17
0.00952
4i78

652
2.08
466
01000457

365
1121
2.9ft
0.000267

44.22
13.55
29.94
OiQ0296

ffi.181
0.0546
0.128
0.0000120

9.50
2.83
6.15
0.000616
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Outlet
Page 3 of 4












Cr
CCr
CCT @ 7% O2




CCo




CPb




CMn




CHQ




CN|

Ecr

Co
CCo
@ 7% 02
ECO

Pb
Cpb
@ 7% 02
Epb

Mn
CMn
@ 7% O2
EMn

Hg
CHg
@ 7% O2
EHa

Ni
CNi
@ 7% 02
ENi
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Chromium (Cr)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Colbalt (Col
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Lead (Pb)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Manganese (Mn)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Mercury (Hifi
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Nickel (Mi)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
O-M29-1
9/23/97
1412-1846


55.3
25.6
84.8
0.00603

3.45
1.60
5.29
0.000376

824
382
1,265
0.0899

6,439
2,986
9,881
0.702

7.40
3.43
11.4
0.000807

5.83
2.70
8.95
0.000636
O-M29-2
9/24/97
0938-1347


94.7
22.0
33.6
0.00455

5.10
1.19
1.81
0.000245

1,574
366
559
0.0756

10,800
2,511
3,835
0.519

16.20
3.77
5.75
0.000778

8.03
1.87
2.85
0.000386
O-M29-3
9/25/97
0845-1145


19.4
6.05
10.0
0.00128

1.52
0.472
0.781
0.000100

454
141
234
0.0299

1,531
476
788
0.101

51.10
15.9
26.3
0.00337

2.36
0.735
1.22
0.000156
O-M29-4
9/25/97
1523-1843


11.3
3.52
5.75
0.000758

1.26
0.393
0.643
0.0000848

229
71
117
0.0154

1,041
325
532
0.0701

15.00
4.68
7.66
0.00101

1.48
0.462
0.756
0.000100
4-Run
Average



45.17
14.30
33.55
0.00315

2.83
0.913
2.13
0.000201

770.16
240
544
0.0527

4952.83
1.574
3.759
0.348

22.43
6.95
12.8
0.00149

4.43
1.44
3.44
0.000319
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 29 - Multiple Metals
Cupola Wet Scrubber Outlet
Page 4 of 4






CP




CSe




CAg




CT,




Czn





P
CP
@ 7% O2
EP

Se
Cse
@ 7% 02
Ese

Ag
CAs
@ 7% 02
EAg

Tl
CT,
@ 7% O2
En

Zn
Czn
@ 7% O2
Ezn
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Phosphorus < P)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Selenium (Se)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% 02
Emission Rate, Ib/hr
Silver (Ag)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% O2
Emission Rate, Ib/hr
Thallium (Tl)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% 02
Emission Rate, Ib/hr
Zinc (Zn)
Target Catch, ug
Concentration, ug/dscm
Concentration, ug/dscm @ 7% 02
Emission Rate, Ib/hr
O-M29-1
9/23/97
1412-1846


309.0
143
474
0.0337

1.79
0.830
2.75
0.000195

4.79
2.22
7.35
0.000522

3.32
1.54
5.09
0.000362

6,650
3,083
10,204
0.725
0-M29-2
9/24/97
0938-1347


58.3
13.6
20.7
0.00280

5.2
1.20
1.84
0.000248

7.62
1.77
2.71
0.000366

4.20
0.976
1.49
0.000202

12,707
2,954
4,512
0.610
O-M29-3
9/25/97
0845-1145


90.6
28.2
46.6
0.00598

0.6
0.193
0.319
0.0000409

1.87
0.582
0.963
0.000124

0.250
0.0778
0.129
0.0000165

2,772
863
1,427
0.183
O-M29-4
9/25/97
1523-1843


53.2
16.6
27.2
0.00358

1.0
0.322
0.526
0.0000693

1.51
0.472
0.771
0.000102

0.510
0.159
0.260
0.0000343

2,504
782
1.278
0.169
4-Run
Average



127.79
50.4
142.2
0.0115

2.15
0.637
1.36
0.000138

3.95
126
2.95
0.000278

2.07
0.688
1.74
0.000154

6,158
1,920
4,355
0.422
-------
                                            Method 29 Analytical Results (ug) and Blank Corrections
                                       GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
                                                       Cupola Wet Scrubber Outlet
Filter Diameter, in: /X
^^^^^^H~Front H Back H
^^^^^H RBlank RBlank
H^^l^^l Mflib Mbhbi
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Colbalt
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Silver
Thallium
Zinc
\4.41 , 
-------
                                                                                 Method 29 Analytical Results (ug) and Blank Corrections
                                                                            GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
                                                                                              Cupola Wet Scrubber Outlet
Filter Diameter, inches: /K
•A" (1 .4xAreaFilter), ug: 1 7.59
H Front H Back H
&Blank RBIank
Mfhb Mbhb
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Cadmium (Cd)
Chromium (Cr)
Colbalt (Co)
Lead(Pb)
Manganese (Mn)
Mercury (Hg)
Nickel (Ni)
Phosphorus (P)
Selenium (Se)
Silver (Ag)
Thallium (Tl)
Zinc (Zn)
4.41 <0.40
2.1 <0.75
99.1 0.23
<0.10 <0.10
<0.10 <0.10
30.5 0.518
9.75 <0.15
4.41 0.57
18.3 0.271
<0.4 < 3.412
11.9 <0.30
74.7 3.28
4.57 < 0.30
0.257 <0.10
0.2 0.22
49.1 4.69
Front H BackH
0-M29- O-M29-
Mfh Mbh
10.60 0.601
4.94 <0.92
52.60 0.511
0.22 < 0.123
8.61 < 0.123
61.70 1.37
4.09 < 0.184
824 1.62
6,440 1.58
<0.4 7.4
9.14 0.723
306.00 9.23
5.86 < 0.368
4.91 0.137
4.04 < 0.245
6,650 10.7
Blank Adjusted
Front H BackH

6.19 0.601
2.84 0.000
35.01 0.281
0.22 0.000
8.61 0.000
44.11 0.852
-5.66 0.000
820 1.050
6,422 1.309

-2.76 0.723
288.41 8.23
1.29 0.000
4.65 0.137
3.84 (0.22)
6,601 9.70
O-M29-1
Adjusted
Mt
11.20
^Sd(J
8.53
63.1
^
824.3
6,435.4
10.38
9.86
315.2
?*
5.05
~$&
6,646.7
Front H BackH
O-M29-2 O-M29-2
Mfh Mbh
14.00 0.914
6.06 <0.85
103.00 0.863
0.51 < 0.1 13
21.80 1.51
101.00 1.52
4.39 1.35
1,560 14.9
10,800 2.65
<0.4 16.2
9.71 2.35
50.90 13.6
7.80 1.44
7.67 0.21
4.92 < 0.227
12,700 17.7
Blank Adjusted
Front H BackH

9.59 0.914
3.96 0.000
85.41 0.633
0.51 0.000
21.80 1.510
83.41 1.002
-5.36 1.350
1,556 14.330
10,782 2.4

-2.19 2.350
33.31 12.600
3.23 1.440
7.41 0.210
4.72 (0.220)
12,651 16.70
O-M29-2
Adjusted
Mt
14.91
^94
103.86
fc6
23.11
102.5
5.74
1,574
10,796
21.43
12.06
64.5
9.24
7.88
^Vni
12,704
Front H BackH
0-M29-3 0-M29-3
Mfh Mbh
8.74 < 0.498
2.03 < 0.933
36.40 0.577
<0.10 < 0.124
4.02 < 0.124
26.10 1.14
1.97 0.187
453 1.85
1,530 3.4
<0.4 51.1
5.74 0.653
88.10 8.66
4.69 < 0.373
2.00 < 0.124
0.97 < 0.249
2,770 13.1
Blank Adjusted
Front H BackH

4.33 0.000
-0.07 0.000
18.81 0.347
0.00 0.000
4.02 0.000
8.51 0.622
-7.78 0.187
449 1.280
1,512 3.129

-6.16 0.653
70.51 7.660
0.12 0.000
1.74 0.000
0.77 (0.220)
2,721 12.100
O-M29-3
Adjusted
Mt
«4
W6
36.98
0.00
3.94
27.20
2.16
453.6
1,527
54.84
6.39
96.76
sty
i&K
i«2
2,769
Front H BackH
O-M29-4 O-M29-4
Mfh Mbh
7.88 < 0.492
1.58 < 0.922
23.60 0.51
<0.10 < 0.123
2.07 0.244
18.20 1.12
1.90 <0.184
225 5.22
1,040 3.83
<0.4 15
5.51 < 0.369
52.00 7.41
4.08 1.02
1.64 0.163
1.23 < 0.246
2,500 15.4
Blank Adjusted
Front H BackH

3.47 0.000
-0.52 < 0.922
6.01 (0.490)
<0.10 < 0.123
2.07 (0.756)
0.61 0.120
-7.85 " 0.000
221 4.220
1,022 2.830

-6.39 < 0.369
34.41 6.410
-0.49 1.020
1.38 (0.837)
1.03 (0.220)
2,451 14.400
O-M29-4
Adjusted
Mt
N&3?
^
24.10
0.00
2.11
19.30
y#s
228.9
1,037.6
17.97.
>$8
59.40
5.10
1.80
ji^s
2,501
 Front Half Blank to be used:             If Mfhb < A, use Mihb = Mfhb
                                  If Mfhb > A, use Mfhb = A if A is > the lesser of Mfhb or 5% of Mfh
                                         If A is not (is  1, use Mfhb - 1 if 1 is > the lesser of Mbhb or 5% of Mbh
                                         If I is not (is <), use Mbhb = the lesser of Mbhb or 5% of Mbh
Tolal Catch = Mt = (Mfh - Mfhb) + (Mbh - Mbhb)

Mercury:        If (Hgfhb + Hgbhb) <- 0.6, use (Hgfhb + Hgbhb)
               If (Hgfhb + Hgbhb) > 0.6, use (Hgfhb + Hgbhb) = 0.6 if 0.6 is > the lesser of (Hgfhb+Hgbhb) or 5% of (Hgfh+Hgbh)
                               If 0.6 is not (is <), use (Hgfhb+Hgbhb) = the lesser of (Hgfhb+Hgbhb) or 5% of (Hgfh+Hgbh)
-------
Summary of Stack Gas Parameters and Test Results
GENERAL MOTORS CORPORATION - S AGIN AW, MICHIGAN
US EPA Test Method 23 - PCDDs / PCDFs
Cupola Wet Scrubber Outlet
Page 1 of 6



7
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
C02
02
N2
CP
AP1*
0
Dn

A,
Vm(std)
Vm(std)
PS
B«re
Vwstd
1-Bws
Md
Ms
vs
A
Qa
Q,
Qs(cmm)
1
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg. Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Dp, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
O-23-1
9/23/97
1415-1846

1.010
0.88
29.74
55.721
79
1.00
125
161.9
4.00
16.70
79.30
0.84
0.5895
110.00
0.242

0.000319
54.895
1.554
29.81
12.2
7.621
0.878
29.31
27.93
35.5
30.68
65,317
51,561
1,460
93.0
O-23-2
9/24/97
0851-1347

1.010
1.37
29.85
152.565
79
1.10
133
622.2
10.60
11.8
77.60
0.84
0.6646
240.00
0.252

0.000346
151.041
4.277
29.93
16.2
29.287
0.838
30.17
28.19
40.0
30.68
73,649
54,924
1,555
101.5
O-23-3
9/25/97
0844-1321

1.010
2.94
29.10
223.582
78
1.10
110
440.9
9.70
12.50
77.80
0.84
0.5953
240.00
0.304

0.000504
217.061
6.146
29.18
8.7
20.753
0.913
30.05
29.00
35.1
30.68
64,584
53,234
1,507
103.4
O-23-4
9/25/97
1443-1918

1.010
3.08
29.10
232.814
88
0.82
108
436.8
10.30
12.40
77.30
0.84
0.6153
240.00
0.304

0.000504
221.977
6.286
29.16
8.5
20.560
0.916
30.14
29.12
36.1
30.68
66,517
55,184
1,563
102.0
Average


1.010
2.07
29.45
166.171
81
1.01
119
415.450
8.65
13.35
78.00
0.84
0.6162
207.50
0.276

0.000418
161.244
4.566
29.52
11.4
19.555
0.886
29.92
28.56
36.7
30.68
67,517
53,726
1,521
-------
Summary of Stack Gas Parameters and Test Results
GENERAL MOTORS CORPORATION - SAG IN AW, MICHIGAN
US EPA Test Method 23 - PCDDs / PCDFs
Cupola Wet Scrubber Outlet
Page 2 of 6
RUN NUMBER
RUN DATE
RUN TIME
BO-23-1 BO-23-2 BO-23-3 BO-23-4
9/23/97 9/24/97 9/25/97 9/25/97 Average
1415-1846 0851-1347 0844-1321 1443-1918
EMISSIONS DATA
DIOXINS:

ng
ng/dscm
pg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
pg/hr
2378 TCDD
Catch, ng
Concentration,
Emission Rate,
Total TCDD
Catch, ng
Concentration,
Emission Rate,
12378PeCDD
Catch, ng
Concentration,
Emission Rate,
Total PeCDD
Catch, ng
Concentration,
Emission Rate,


ng/dscm, as measured
pg/hr


ng/dscm, as measured
pg/hr


ng/dscm, as measured
pg/hr


ng/dscm, as measured
pg/hr

{0.050}
{0.0322}
{2.82}

2.7
1.74
152.2

0.07
0.045
3.94

0.84
0.54
47.34

0.21
0.049
4.58

6.6
1.54
144.0

0.23
0.054
5.02

2.4
0.56
52.36

0.13
0.021
1.91

4.1
0.67
60.3

0.10
0.016
1.47

0.74
0.12
10.89

0.12
0.019
1.79

4.6
0.732
68.6

0.10
0.016
1.49

1.30
0.207
19.39

{0-13}
{0.03}
{2-78}

4.50
1.1,7
106.28

O.t3
0.03
2.98

1.32
0.36
32.50
123478 HxCDD
ng
ng/dscm
pg/hr
Catch, ng
Concentration,
Emission Rate,

ng/dscm, as measured
pg/hr
0.02
0.013
1.13
0.07
0.016
1.53
ND
(ND)
(ND)
{0.02}
{0.003}
{0.30}
{0.04}
{0.01}
{0.98}
123678 HxCDD
ng
ng/dscm
pg/hr
Catch, ng
Concentration,
Emission Rate,

ng/dscm, as measured
pg/hr
{0.02}
{0.013}
{1.13}
0.080
0.019
1.7
ND
(ND)
(ND)
0.030
0.005
0.4
{0.04}
{0.01}
{1.11}
-------
Summary of Stack Gas Parameters and Test Results
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 23 - PCDDs / PCDFs
Cupola Wet Scrubber Outlet
Page 3 of 6
RUN NUMBER BO-23-1 BO-23-2 BO-23-3 BO-23-4
RUN DATE 9/23/97 9/24/97 9/25/97 9/25/97
RUNTIME 1415-1846 0851-1347 0844-1321 1443-1918


ng
ng/dscm
pg/hr

"9
ng/dscm
pg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
pg/hr
EMISSIONS DATA -Continued
DIOXINS - Continued
123789 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1234678 HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
12346789 OCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDDs
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr


0.03
0.0193
1.69

0.19
0.122
10.7

0.02
0.013
1.13

0.02
0.013
1.1

0.03
0.019
1.69

{3.78}
{2.43}
{213}
•

0.11
0.026
2.4

1.1
0.257
24.0

{0.12}
{0.028}
{2.62}

0.14
0.033
3.1

{0.09}
{0.021}
{1.96}

{10.33}
2.4
225


ND
(ND)
(ND)

0.24
0.039
3.5

ND
(ND)
(ND)

ND
(ND)
(ND)

{0.04}
{0.007}
{0.6}

{5.12}
{0.8}
{0,075}


0.04
0.006
0.6

0.41
0.065
6.1

{0.03}
{0.005}
{0.45}

0.03
0.005
0.4

0.08
0.013
1.2

{6.42}
{1.02}
{95.76}
Average


0.06
0.017
1.56

0.49
0.121
11.09

{0.06}
{0.02}
{1.40}

0.06
0.017
1.54

{0.06}
{0.01}
{1.36}

{6.41}
{1.68}
{152.38}
-------
Summary of Stack Gas Parameters and Test Results
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 23 - PCDDs / PCDFs
Cupola Wet Scrubber Outlet
Page 4 of 6
RUN NUMBER BO-23-1 BO-23-2 BO-23-3 BO-23-4
RUN DATE 9/23/97 9/24/97 9/25/97 9/25/97
RUNTIME 1415-1846 0851-1347 0844-1321 1443-1918


ng
ng/dscm
pg/hr

ng
ng/dscm
|jg/hr

ng
ng/dscm
|jg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
ug/hr

ng
ng/dscm
Mg/hr
EMISSIONS DATA - Continued
FURANS
2378 TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, (jg/hr
Total TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
12378 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
23478 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1 23478 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr


0.7
0.46
40.6

19.1
12.29
1,076

0.36
0.232
20.3

0.38
0.244
21.4

6.1
3.92
343.8

0.16
0.103
9.0


2.3
0.54
50.2

60.0
14.03
1,309

1.4
0.33
30.5

1.4
0.327
30.5

24.2
5.66
528.0

0.91
0.213
19.9


1.8
0.29
26.5

51.2
8.33
753

0.65
0.106
9.6

0.47
0.076
6.9

10.7
1.74
157.5

0.18
0.029
2.6


1.30
0.207
19.4

43.0
6.841
641.4

0.61
0.097
9.1

0.52
0.083
7.8

11.30
1.798
168.6

0.26
0.041
3.9
Average


1.53
0.38
34.16

43.33
10.37
945.07

0.76
0.190
17.37

0.69
0.183
16.66

13.08
3.28
299.44

0.38
0.097
8.85
-------
Summary of Stack Gas Parameters and Test Results
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 23 - PCDDs / PCDFs
Cupola Wet Scrubber Outlet
Page 5 of 6
RUN NUMBER BO-23-1 BO-23-2 BO-23-3 BO-23-4
RUN DATE 9/23/97 9/24/97 9/25/97 9/25/97 Average
RUNTIME 1415-1846 0851-1347 0844-1321 1443-1918


ng
ng/dscm
Mg/hr

ng
ng/dscm
Mg/hr

ng
ng/dscm
Mg/hr

ng
ng/dscm
Mg/hr

ng
ng/dscm
pg/hr

ng
ng/dscm
Mg/hr
EMISSIONS DATA - Continued
Furans - Continued
123678 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
234678 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
123789 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
Total HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
1 234678 HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
1234789 HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr


0.07
0.045
3.9

0.05
0.032
2.8

ND
(ND)
(ND)

0.69
0.444
38.9

{0.07}
{0.045}
{3.94}

ND
(ND)
(ND)


0.46
0.108
10.0

0.26
0.061
5.7

{0.04}
{0.009}
{0.9}

4.7
1.10
102.5

{0.30}
{0.070}
{6.55}

{0.050}
{0.012}
{1.091}


0.09
0.015
1.3

0.05
0.008
0.7

ND
(ND)
(ND)

0.92
0.150
13.5

0.04
0.007
0.6

ND
(ND)
(ND)


0.11
0.018
1.6

0.06
0.010
0.9

ND
(ND)
(ND)

1.2
0.191
17.9

0.07
0.011
1.0

ND
(ND)
(ND)


0.18
0.046
4.24

0.11
0.028
2.53

{0.04}
{0.01}
{0.87}

1.88
0.471
43.22

0.12
0.033
3.03

{0.05}
{0.01}
{1.09}
-------
Summary of Stack Gas Parameters and Test Results
GENERAL MOTORS CORPORATION - SAGINAW, MICHIGAN
US EPA Test Method 23 - PCDDs / PCDFs
Cupola Wet Scrubber Outlet
Page 6 of 6





ng
ng/dscm
ug/hr

ng
ng/dscm
ug/hr

ng
ng/dscm
M9/hr

ng
ng/dscm
M9/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA- Continued
Furans - Continued
Total HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
1 2346789 OCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total PCDFs
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDDs + PCDFs
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
BO-23-1
9/23/97
1415-1846



0.04
0.026
2.3

{0.010}
{0.0064}
{0.56}

{25.94}
{16.7}
{1,462}

{29.72}
{19.1}
{1,675}
BO-23-2
9/24/97
0851-1347



0.10
0.023
2.2

0.04
0.0094
0.87

89.04
21
1,943

99.37
23
2,168
BO-23-3
9/25/97
0844-1321



0.04
0.007
0.6

{0.030}
{0.0049}
{0.441}

62.89
10
925

{68.01}
{11}
{1,001}
BO-23-4
9/25/97
1443-1918



0.07
0.011
1.0

{0.010}
{0.0016}
{0.149}

55.58
8.842
829.0

{62.00}
9.864
924.8

Average



0.06
0.017
1.52

{0.02}
{0.01}
{0.51}

{58.4}
{14.1}
{1289.8}

{64.8}
{15.8}
{1442.1}
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals and averages, which are also in brackets.
-------
Summary of Stack Gas Parameters and Test Results
Iron and Steel Foundries Manual Emission Test
GENERAL MOTORS CORPORATION - Saglnaw, Michigan
SW-846 Method 0010 - Modified Method 5 - Semivolatile Organics
Cupola Wet Scrubber Outlet
Page 1 of 13


y
AH
Pbar
vm
Tm
Pstatlc
Ts
vfc
CO2
02
N2
cp
Ap1n
®
Dn

An
Vm(sW)
Vm(sM)
ps
Bws
Bws(sat)
Vwstd
1-Bw,
Md
Ms
Vs
A
Q,
Qs
Qs(onm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, *F
Stack Static Pressure, inches H2O
Average Stack Temperature, *F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Average Square Root Ap, On. H2O)1C
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
O-0010-1
9/23/97
1415-1847

0.966
1.40
29.74
73.972
74
1.10
125
217.3
4.00
16.70
79.30
0.84
0.6726
110
0.250

0.000341
70.444
1.995
29.82
12.7
13.2
10.228
0.873
29.31
27.87
40.5
30.68
74,589
58,567
1,658
98.4
0-0010-2
9/24/97
0851-1400

0.966
1.44
29.85
161.167
79
1.10
135
646.2
10.60
11.8
77.60
0.84
0.6881
240
0.250

0.000341
152.632
4.322
29.93
16.6
17.2
30.417
0.834
30.17
28.15
41.5
30.68
76,444
56,562
1,602
101.2
O-0010-3
9/25/97
0844-1321

0.966
2.89
29.10
227.729
78
0.72
111
459.3
9.70
12.50
77.80
0.84
0.5923
240
0.305

0.000507
211.429
5.987
29.15
9.3
9.2
21.619
0.908
30.05
28.95
35.0
30.68
64,403
52,693
1,492
101.1
O-0010-4
9/25/97
1443-1919

0.966
3.04
29.10
234.250
85
0.85
111
463.8
10.30
12.40
77.30
0.84
0.6041
240
0.305

0.000507
214.771
6.082
29.16
9.2
9.2
21.831
0.908
30.14
29.03
35.6
30.68
65,580
53,676
1,520
100.8
Average

0.966
2.19
29.45
174.280
79
0.94
121
446.7
8.65
13.35
78.00
0.84
0.6393
208
0.278

0.000424
162.319
4.60
29.52
11.9
12.19
21.024
0.881
29.92
28.50
38.2
30.68
70,254
55,375
1,568
-------
                                                     Cupola Wet Scrubber Outlet
                                                            Page 2 of 13

Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
Acetophenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
4-Aminobiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Aniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
o-Anisidine
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
0-0010-1

154.21
{0.28}
{1.40E-04}
{2.19 E-02}
{3.08 E-05}

154.21
{0.81}
{4.06 E-04}
{6.33 E-02}
{8.91 E-05}

120.15
{8.19}
{4.11E-03}
{8.22 E-01}
{9.01 E-04}

169.22
ND
ND
ND
ND

93.12
ND
ND
ND
ND

123.15
ND
ND
ND
ND
O-0010-2

154.21
ND
ND
ND
ND

154.21
{0.64}
{1.48 E-04}
{2.31 E-02}
{3.14 E-05}

120.15
{8.93}
{2.07 E-03}
{4. 14 E-01}
{4.38 E-04}

169.22
ND
ND
ND
ND

93.12
ND
ND
ND
ND

123.15
ND
ND
ND
ND
0-0010-3

154.21
{0.94}
{1.57 E-04}
{2.45 E-02}
{3. 10 E-05}

154.21
{2.14}
{3.57 E-04}
{5.58 E-02}
{7.05 E-05}

120.15
13.55
2.26 E-03
4.53 E-01
4.47 E-04

169.22
ND
ND
ND
ND

93.12
{0.32}
{5.34 E-05}
{1.38 E-02}
{1.05 E-05}

123.15
ND
ND
ND
ND
0-0010-4

154.21
{0.62}
{1.02 E-04}
{1.59 E-02}
{2.05 E-05}

154.21
{1.10}
{1.81 E-04}
{2.82 E-02}
{3.64 E-05}

120.15
{8.68}
{1.43 E-03}
{2.86 E-01}
{2.87 E-04}

169.22
ND
ND
ND
ND

93.12
ND
ND
ND
ND

123.15
ND
ND
ND
ND
Average


(0.46)
(9.98 E-05)
(1.56 E-02)
(2.06 E-05


{1.17}
{2.73 E-04}
{4.26 E-02}
(5.68 E-05}


{9.84}
{2.47 E-03}
{4.94 E-01}
{5.18 E-04}


ND
ND
ND
ND


(0.08)
(1.34 E-05)
(3.45 E-03)
(2.64 E-06)


ND
ND
ND
ND
     Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                     Cupola Wet Scrubber Outlet
                                                            Page 3 of 13

Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/hr c
Benzidine
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
Benzo(b)f1uoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
Senzo(ghi)perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr e
O-0010-1

178.22
{0.26}
{1.30E-04}
{1.76E-02}
{2.86 E-05}

184.23
ND
ND
ND
ND

228.29
ND
ND
ND
ND

252.32
ND
ND
ND
ND

252.32
ND
ND
ND
ND

276.34
ND
ND
ND
ND
O-0010-2

178.22
ND
ND
ND
ND

184.23
ND
ND
ND
ND

228.29
ND
ND
ND
ND

252.32
ND
ND
ND
ND

252.32
ND
ND
ND
ND

276.34
ND
ND
ND
ND
O-0010-3

178.22
{0.34}
{5.68 E-05}
{7.66 E-03}
{1.12 E-05}

184.23
ND
ND
ND
ND

228.29
ND
ND
ND
ND

252.32
ND
ND
ND
ND

252.32
ND
ND
ND
ND

276.34
ND
ND
ND
ND
O-0010-4

178.22
{0.28}
{4.60 E-05}
{6.21 E-03}
{9.26 E-06}

184.23
ND
ND
ND
ND

228.29
ND
ND
ND
ND

252.32
ND
ND
ND
ND

252.32
ND
ND
ND
ND

276.34
ND
ND
ND
ND
Average


(0.22)
(5.83 E-05)
(7.87 E-03)
(1.23 E-05)


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND
   *  Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit.  Values are counted as zero (0) in averages.
-------
                                                     Cupola Wet Scrubber Outlet
                                                            Page 4 of 13
.
Benzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Benzyl Chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr °
Biphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
2-ChIoroacetophenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
bis-(2-Chloroethyl)ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

252.30
ND
ND
ND
ND

252.30
ND
ND
ND
ND

126.58
ND
ND
ND
ND

154.20
{2.13}
{1.07E-03}
{1.67 E-01}
{2.34 E-04}

154.59
ND
ND
ND
ND

143.02
ND
ND
ND
ND
O-0010-2

252.30
ND
ND
ND
ND

252.30
ND
ND
ND
ND

126.58
ND
ND
ND
ND

154.20
{1.22}
{2.82 E-04}
{4.40 E-02}
{5.98 E-05}

154.59
ND
ND
ND
ND

143.02
ND
ND
ND
ND
O-0010-3

252.30
ND
ND
ND
ND

252.30
ND
ND
ND
ND

126.58
{2.27}
{3.79 E-04}
{7.20 E-02}
{7.48 E-05}

154.20
{5.10}
{8.52 E-04}
{1.33 E-01}
{1.68 E-04}

154.59
ND
ND
ND
ND

143.02
ND
ND
ND
ND
O-0010-4

252.30
ND
ND
ND
ND

252.30
ND
ND
ND
ND

126.58
ND
ND
ND
ND

154.20
{2.50}
{4. 11 E-04}
{6.41 E-02}
{8.26 E-05}

154.59
ND
ND
ND
ND

143.02
ND
ND
ND
ND
Average


ND
ND
ND
ND


ND
ND
ND
ND


(0.57)
(9.48 E-05)
(1.80 E-02)
(1.87 E-05)


{2.39}
{6.53 E-04}
{1.02 E-01}
{1.36E-04}


ND
ND
ND
ND


ND
ND
ND
ND
   "  Milligrams per dry standard cubic meter at 68° F (20° C) and I atm.
     Parts per billion by volume.
   c  Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit.  Values are counted as zero (0) in averages.
-------
                                                    Cupola Wet Scrubber Outlet
                                                           Page 5 of 13

2-Chloronaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Mir c
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr °
Dibenz(a,b)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Dibenzofuran
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd k
Emission Rate, Ib/hr c
l,2-Dibromo-3-chloropropane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

162.61
ND
ND
ND
ND

228.28
{0.22}
{1.10E-04}
{1.16E-02}
{2.42 E-05}

120.19
ND
ND
ND
ND

278.33
ND
ND
ND
ND

168.20
ND
ND
ND
ND

236.36
ND
ND
ND
ND
O-0010-2

162.61
ND
ND
ND
ND

228.28
ND
ND
ND
ND

120.19
{0.56}
{1.30E-04}
{2.59 E-02}
{2.75 E-05}

278.33
ND
ND
ND
ND

168.20
ND
ND
ND
ND

236.36
ND
ND
ND
ND
O-0010-3

162.61
ND
ND
ND
ND

228.28
ND
ND
ND
ND

120.19
{1-56}
{2.61 E-04}
{5.21 E-02}
{5.14 E-05}

278.33
ND
ND
ND
ND

168.20
{2.49}
{4. 16 E-04}
{5.95 E-02}
{8.21 E-05}

236.36
ND
ND
ND
ND
O-0010-4

162.61
ND
ND
ND
ND

228.28
ND
ND
ND
ND

120.19
{0.45}
{7.40 E-05}
{1.48 E-02}
{1.49 E-05}

278.33
ND
ND
ND
ND

168.20
{1.25}
{2.06 E-04}
{2.94 E-02}
{4. 13 E-05}

236.36
ND
ND
ND
ND
Average


ND
ND
ND
ND


(0.06)
(2.76 E-05)
(2.91 E-03)
(6.05 E-06)


(0.64)
(1.16 E-04)
(2.32 E-02)
(2.34 E-05)


ND
ND
ND
ND


(0.94)
(1.55 E-04)
(2.22 E-02)
(3.09 E-05)


ND
ND
ND
ND
   1  Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                     Cupola Wet Scrubber Outlet
                                                            Page 6 of 13
•
Di-n-butylphthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
1,4-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
3,3'-Dichlorobenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
N,N-Diethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
3,3'-Dimethoxybenzidine
Molecular Weight, g/g-mole
Target Catch, u.g
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Dimethylaminoazobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

278.34
{9.59}
{4.81 E-03}
{4.15 E-01}
{1.05 E-03}

147.01
{0.73}
{3.66 E-04}
{5.99 E-02}
{8.03 E-05}

253.13
ND
ND
ND
ND

149.23
ND
ND
ND
ND

244.28
ND
ND
ND
ND

225.28
ND
ND
ND
ND
O-OOIft.2

278.34
{8.83}
{2.04 E-03}
{1.77 E-01}
{4.33 E-04}

147.01
{0.82}
{1.90 E-04}
{3.10 E-02}
{4.02 E-05}

253.13
ND
ND
ND
ND

149.23
ND
ND
ND
ND

244.28
ND
ND
ND
ND

225.28
ND
ND
ND
ND
0-0010-3

278.34
{8.67}
{1.45 E-03}
{1.25 E-01}
{2.86 E-04}

147.01
{1.28}
{2.14 E-04}
{3.50 E-02}
{4.22 E-05}

253.13
ND
ND
ND
ND

149.23
ND
ND
ND
ND

244.28
ND
ND
ND
ND

225.28
ND
ND
ND
ND
0-0010-4

278.34
{5.85}
{9.62 E-04}
{8.31 E-02}
{1.93 E-04}

147.01
{1.30}
{2. 14 E-04}
{3.50 E-02}
{4.30 E-05}

253.13
ND
ND
ND
ND

149.23
ND
ND
ND
ND

244.28
ND
ND
ND
ND

225.28
ND
ND
ND
ND
Average


{8.24}
{2.31 E-03}
{2.00 E-01}
{4.92 E-04}


{1.03}
{2.46 E-04}
{4.02 E-02}
{5.14 E-05}


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND
     Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit.  Values are counted as zenJ (0) in averages.
-------
                                                    Cupola Wet Scrubber Outlet
                                                           Page 7 of 13

N,N-DimethyIaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr °
3^'-Dimethylbenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
Dimethylphthalate
Molecular Weight, g/g-mole
Target Catch, fig
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
4,6-Dinitro-2-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
2,4-Dinitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr °
2,4-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

121.18
ND
ND
ND
ND

212.28
ND
ND
ND
ND

194.19
{2.49}
{1.25E-03}
{1.55E-01}
{2.74 E-04}

198.13
ND
ND
ND
ND

184.11
ND
ND
ND
ND

182.14
ND
ND
ND
ND
O-0010-2

121.18
ND
ND
ND
ND

212.28
ND
ND
ND
ND

194.19
{1.89}
{4.37 E-04}
{5.42 E-02}
{9.26 E-05}

198.13
ND
ND
ND
ND

184.11
ND
ND
ND
ND

182.14
ND
ND
ND
ND
O-0010-3

121.18
ND
ND
ND
ND

212.28
ND
ND
ND
ND

194.19
{2.23}
{3.72 E-04}
{4.61 E-02}
{7.35 E-05}
,
198.13
ND
ND
ND
ND

184.11
ND
ND
ND
ND

182.14
ND
ND
ND
ND
O-0010-4

121.18
ND
ND
ND
ND

212.28
ND
ND
ND
ND

194.19
{1.43}
{2.35 E-04}
{2.91 E-02}
{4.73 E-05}

198.13
ND
ND
ND
ND

184.11
ND
ND
ND
ND

182.14
ND
ND
ND
ND
Average


ND
ND
ND
ND


ND
ND
ND
ND


{2-01}
{5.73 E-04}
{7. 10 E-02}
{1.22 E-04}


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND
* Milligrams per dry standard cubic meter at 68° F (20° C) and 1 aim.
b





1     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                     Cupola Wet Scrubber Outlet
                                                            Page 8 of 13
*
bis(2-Ethylhexyl)phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
Fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Hexachlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Hexachlorobutadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
Hexachlorocyclopentadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

390.54
11.05
5.54 E-03
3.41 E-01
1.22 E-03

202.26
{0.96}
{4.81 E-04}
{5.72 E-02}
{1.06 E-04}
f
166.21
{0.94}
{4.71 E-04}
{6.82 E-02}
{1.03 E-04}

284.80
ND
ND
ND
ND

260.76
ND
ND
ND
ND

272.77
ND
ND
ND
ND
O-0010-2

390.54
20.27
4.69 E-03
2.89 E-01
9.94 E-04

202.26
{1.37}
{3.17 E-04}
{3.77 E-02}
{6.72 E-05}

166.21
{0.61}
{1.41 E-04}
{2.04 E-02}
{2.99 E-05}

284.80
ND
ND
ND
ND

260.76
ND
ND
ND
ND

272.77
ND
ND
ND
ND
O-0010-3

390.54
21.21
3.54 E-03
2.18 E-01
6.99 E-04

202.26
{0.86}
{1.44 E-04}
{1.71 E-02}
{2.84 E-05}

166.21
{1.33}
{2.22 E-04}
{3.21 E-02}
{4.38 E-05}

284.80
ND
ND
ND
ND

260.76
ND
ND
ND
ND

272.77
ND
ND
ND
ND
O-0010-4

390.54
{9.14}
{1.50 E-03}
{9.26 E-02}
{3.02 E-04}

202.26
{0.91}
{1.50 E-04}
{1.78 E-02}
{3.01 E-05}

166.21
{0.77}
{1.27 E-04}
{1.83 E-02}
{2.55 E-05}

284.80
ND
ND
ND
ND

260.76
ND
ND
ND
ND

272.77
ND
ND
ND
ND
Average


{15.42}
{3.82 E-03}
{2.35 E-01}
{8.03 E-04}


{1.03}
{2.73 E-04}
{3.25 E-02}
{5.78 E-05}


{0.91}
{2.40 E-04}
{3.48 E-02}
{5.06 E-05}


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND
   *  Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                    Cupola Wet Scrubber Outlet
                                                            Page 9 of 13

Hexachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
Hydroquinone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
Indeno(l,2,3-cd)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
Isophorone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/hr c
Methylene bis-chloroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
4,4'-Methylenediani)ine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

236.74
ND
ND
ND
ND

110.11
ND
ND
ND
ND

290.34
ND
ND
ND
ND

138.20
ND
ND
ND
ND

267.15
ND
ND
ND
ND

198.26
ND
ND
ND
ND
O-0010-2

236.74
ND
ND
ND
ND

110.11
ND
ND
ND
ND

290.34
ND
ND
ND
ND

138.20
ND
ND
ND
ND

267.15
ND
ND
ND
ND

198.26
ND
ND
ND
ND
O-0010-3

236.74
ND
ND
ND
ND

110.11
ND
ND
ND
ND

290.34
ND
ND
ND
ND

138.20
ND
ND
ND
ND

267.15
ND
ND
ND
ND

198.26
ND
ND
ND
ND
O-0010-4

236.74
ND
ND
ND
ND

110.11
ND
ND
ND
ND

290.34
ND
ND
ND
ND

138.20
ND
ND
ND
ND

267.15
ND
ND
ND
ND

198.26
ND
ND
ND
ND
Average


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND
   * Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
;ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                    Cupola Wet Scrubber Outlet
                                                           Page 10 of 13
*
2-Metbylnaphthalene
Molecular Weight, g/g-mole
Target Catch, fig
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
2-MethylphenoI
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
3/4-Methylphenol
. Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
Nitrobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
4-Nitrobiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

142.20
25.56
1.28E-02
2.17E+00
2.81 E-03

108.13
ND
ND
ND
ND

108.13
ND
ND
ND
ND

128.16
24.93
1.25E-02
2.35 E+00
2.74 E-03

123.11
ND
ND
ND
ND

199.20
ND
ND
ND
ND
O-0010-2

142.20
22.37
5. 18 E-03
8.75 E-01
1.10 E-03

108.13
ND
ND
ND
ND

108.13
ND
ND
ND
ND

128.16
28.20
6.52 E-03
1.22 E+00
1.38 E-03

123.11
ND
ND
ND
ND

154.21
ND
ND
ND
ND
O-0010-3

142.20
136.69
2.28 E-02
3.86 E+00
4.51 E-03

108.13
{2.16}
{3.61 E-04}
{8.03 E-02}
{7.12 E-05}

108.13
ND
ND
ND
ND

128.16
92.27
1.54 E-02
2.89 E+00
3.04 E-03

123.11
ND
ND
ND
ND

154.21
ND
ND
ND
ND
O-0010-4

142.20
58.46
9.61 E-03 .
1.63 E+00
1.93 E-03

108.13
{0.70}
{1.15 E-04}
{2.56 E-02}
{2.31 E-05}

108.13
{0.99}
{1.63 E-04}
{3.62 E-02}
{3.27 E-05}

128.16
45.94
7.55 E-03
1.42 E+00
1.52 E-03

123.11
ND
ND
ND
ND

154.21
ND
ND
ND
ND
Average


60.77
1.26 E-02
2.13 E+00
2.59 E-03


(0.72)
(1.19 E-04)
(2.65 E-02)
(2.36 E-05)


(OiZS);
(4JI7 E-05)
{9.05 E-03)
(8.18 E-06)


39160
UOSEflZ
L97E+DO
2J7/&03I


ND
ND
ND
ND


ND
ND
ND
ND
   "  Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                    Cupola Wet Scrubber Outlet
                                                          Page 11 of 13

4-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, lb/hrc
n-Nitrosodimethylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
n-Nitrosomorpholine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr °
Pentachloronitrobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd k
Emission Rate, Ib/hr c
Pentachlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
Perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

139.11
ND
ND
ND
ND

74.08
ND
ND
ND
ND

116.11
ND
ND
ND
ND

295.30
ND
ND
ND
ND

266.35
ND
ND
ND
ND

252.30
ND
ND
ND
ND
O-0010-2

139.11
ND
ND
ND
ND

74.08
ND
ND
ND
ND

116.11
ND
ND
ND
ND

295.30
ND
ND
ND
ND

266.35
ND
ND
ND
ND

252.30
ND
ND
ND
ND
O-0010-3

139.11
ND
ND
ND
ND

74.08
ND
ND
ND
ND

116.11
ND
ND
ND
ND

295.30
ND
ND
ND
ND

266.35
ND
ND
ND
ND

252.30
ND
ND
ND
ND
O-0010-4

139.11
ND
ND
ND
ND

74.08
ND
ND
ND
ND

116.11
ND
ND
ND
ND

295.30
ND
ND
ND
ND

266.35
ND
ND
ND
ND

252.30
ND
ND
ND
ND
Averaee


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND


ND
ND
ND
ND
   1  Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
                                                    Cupola Wet Scrubber Outlet
                                                           Page 12 of 13
„
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr c
Phenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
1,4-Phenylenediamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr °
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr °
o-Toluidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
1,2,4-Trichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-I

178.22
{2.07}
{1.04 E-03}
{1.40 E-01}
{2.28 E-04}

94.11
{6.57}
{3.29 E-03}
{8.42 E-01}
{7.23 E-04}

108.14
ND
ND
ND
ND

202.24
{1.18}
{5.91 E-04}
{7.04 E-02}
{1.30 E-04}

107.15
ND
ND
ND
ND

181.46
ND
ND
ND
ND
o-onto-2

178.22
{1.16}
{2.68 E-04}
{3.62 E-02}
{5.69 E-05}

94.11
35.15
8. 13 E-03
2.08 E+00
1.72 E-03

108.14
ND
ND
ND
ND

202.24
{1.66}
{3.84 E-04}
{4.57 E-02}
{8.14 E-05}

107.15
ND
ND
ND
ND

181.46
ND
ND
ND
ND
0-0010-3

178.22
{1.77}
{2.96 E-04}
{3.99 E-02}
{5.84 E-05}

94.11
11.09
1.85 E-03
4.73 E-01
3.66 E-04

108.14
ND
ND
ND
ND

202.24
{1.05}
{1.75 E-04}
{2.09 E-02}
{3.46 E-05}

107.15
ND
ND
ND
ND

181.46
ND
ND
ND
ND
O-0010-4

178.22
{1.17}
{1.92 E-04}
{2.60 E-02}
{3.87 E-05}

94.11
19.44
3.20E-03
8.17E-01
6.43E-04

108.14
ND
ND
ND
ND

202.24
{0.98}
{1.61 E-04}
{1. 92 E-02}
{3.24 E-05}

107.15
ND
ND
ND
ND

181.46
{1.29}
{2. 12 E-04}
{2.81 E-02}
{4.26 E-05}
Average


{1.54}
{4.48 E44}
{6.05 E-02}
{9.54 E-05}


{18.06}
{4.12 E-03}
{1.05 E+00}
{8.63 E-04}


ND
ND
ND
ND


{1.22}
{3.28 E-04}
{3.90 E-02}
{6.95 Er05}


ND
ND
ND
ND


(Oi32)
(5.30 E-05)
(7.03 E-03)
(1.07 E-05)
     Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
     Parts per billion by volume.
     Pounds per hour.
ND  Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
Cupola Wet Scrubber Outlet
    Page 13 of 13

2,4,5-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr °
2,4,6-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
a,a,a-Trichlorotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm '
Concentration, ppbvd b
Emission Rate, Ib/hr °
Trifluralin
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/hr c
O-0010-1

197.46
ND
ND
ND
ND

197.46
ND
ND
ND
ND

195.48
ND
ND
ND
ND

335.29
ND
ND
ND
ND
O-0010-2

197.46
ND
ND
ND
ND

197.46
{0.39}
{9.02 E-05}
{1.10E-02}
{1.91 E-05}

195.48
ND
ND
ND
ND

335.29
ND
ND
ND
ND
DJ10LO-3

197.46
ND
ND
ND
ND

197.46
ND
ND
ND
ND

195.48
ND
ND
ND
ND

335.29
ND
ND
ND
ND
0-0010-4

197.46
ND
ND
ND
ND

197.46
ND
ND
ND
ND

195.48
ND
ND
ND
ND

335.29
ND
ND
ND
ND
Aseraas


ND
ND
ND
ND


(0.10)
(2.26 E-05)
(2.75 E-03)
(4.78 E-06)


ND
ND
ND
ND


ND
ND
ND
ND
* Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
Parts per billion by volume.
Pounds per hour.


ND Not Detectable - Results are below target analyte detection limit.








Values are counted as zero (0) in averages.
{ } Estimate - Analyte results are below the quantitation limit and above the detection limit
-------
                    Isokinetic Calculation Sheet




Plant:    &J/A.' S&fif&J
Site:
           So -Z3-2-


Volume of dry gas sampled corrected
to standard conditions.
note: Vm must be corrected for any leakage rates
that exceed La.
/AH\
Tm ^
Volume of water vapor at standard
conditions, iu
Vwstd= 0.04707 x V,c
Moisture Content in stack gas.
Vu/
std
Bws= / \
( std + std J

Dry Molecular weight of stack gas,
Ib/lb-mole
Md— 440 x (%CO2)+ 320 x (%O2)+
.280x(%N2+CO)
Molecular Weight of Stack Gas
Ms= Md x (1-Bws) + 18 x (Bws)
Stack pas velocitv at stack conditions
feet per second.
*
/ 	 T
V«- 85.4«hc r ic I. p v s
^ / \
, (Ps X M0
» N '
Isokinetic Variation
_ . Vmstd x Ts x 17.32
Vs x Drf x 9 x Ps x (1-Bws)

Vm, ft3
Y
Pbar, in. Hg
AH, in. H2O
Vm std, dscf
Vlc
vwstd
Bws

1-Bws
%CO2
%O2
%N2+CO
Md, Ib/lb-mole
Ms, Ib/lb-mole
Pstatic, in. Hg
Ps, in. Hg
Ts, °R
r—
VAP
Cp
Vs, feet per sec.
Dn, in.
9,min.
%i
Run 1
(
M-^
Run 3
/&.&*:
/-o/o
^tf :
IM j
f$tt#>
^2Z.T^
vi,tol l
AA^: !

»w



.^o. « 7
»z.
A/d
W15
^J3

fflf&VJ
G,Q¥
#at>3>
**»
1.W
-------
JOC3
                    Isokinetic Calculation Sheet




Plant:   CiM-^4^/^/4 V\J	            k An ,
                                                       Site: j3 ^aa la Sc/~<*fate/- fla^r


1 Volume of drv pas samnieri corrected
, to standard conditions.
i note: Vm must be corrected for any leakage rates
| that exceed La.
! VnwH- rfi5,y Y Pbar+(^)
j Tm
Volume of water vapor at standard
Vwstd= 0.04707 x V,c
Moisture Content in stack gas.
Vw
VW std
Bws= /,. ., \
fVw std + Vm stdj

Dry Molecular weight of stack gas,
Ib/lb-mole
Md— 440 x (%CO2\+ 320 x f%O2^-4-
.280x(%N2+CO)
Molecular Weight of Stack Gas
Ms= Md x (1-Bws) + 18 x (Bws)
Stark one vplnritv at ctsirlc rnnHitinnc
feet per second.
1 *
L= 8^
Runt 3
^^58Z
1, 010
,M*/D
^.^
^i^.lB4/
MHO.t
^-?5
.^8-^

D.9/3



3D.^
K^o
* T^-v
^ ^ /£
5>6

"D .5^SB
"b.&'l
35>(D
.^
2.^1 r\
I r\ 2j 
-------
APPENDIX E




-------
GCMS QAQC
Table 1 . GCMS Original Calibration and Continuing Calibration Results


COMPOUND
Chloromethane
Chloroethane
Methylene Chloride
1,1-dichloroethane
c-1 ,2-dichloroethene
1,1,1-trichloroethane
1 ,2-dichloropropane
1 ,1 ,2-trichloroethane
dibromochloromethane
ethylbenzene
p-xylene
1,1,2,2-tetrachloroethan
Bromomethane
1,1-dichloroethene
t-1 ,2-dichloroethane
Methyl Ethyl Ketone
1 ,2-dichloroethane
carbon tetrachloride
trichloroethene
c-1 ,2-dichloropropene
t-1 ,2-dichloropropene
2-hexanone
chlorobenzene
m-xylene
p-xylene

vinyl chloride
carbon disulfide
vinyl acetate
chloroform
benzene
bromodichloromethane
Methyl iso-Butyl Ketone
Toluene
Tetrachloroethylene
bromoform
styrene



Three-Point Calibration Estimated Detection Limit**
15-97 %RSD
13.60%
13.30%
15.70%
9.50%
11.50%
10.50%
9.24%
10.70%
8.90%
10.70%
13.03%
17.30%
13.40%
10.30%
11.08%
31.60%
11.14%
9.40%
9.30%
8.50%
10.70%
13.50%
10.50%
11.20%
9.90%

8.60%
8.70%
15.60%
10.50%
8.20%
12.00%
16.80%
7.50%
12.80%
5.20%
5.90%

Parts per Billion (PPB)
50
50
10
25
25
25
25
25
25
10
30
10
50
25
25
500
50
10
25
25
25
500
10
30
30

250
10
250
10
10
10
1000
10
10
50
30



Continuing Calibration***
9/23/97
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Fail
Pass
Pass
Pass

Pass
Pass
Fail
Pass
Pass
Pass
Fail
Pass
Pass
Pass
Pass



Continuing Calibration***
9/24/97
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass

Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass

Bold indicates failure of three-point calibration, and precludes collection of valid data for that compound for all test days.
Bold indicates failure of Continuing Calibration and precludes collection of valid data for that compound for that day.



* Criteria for Valid Three point Calibration = 20% RSD
** Estimated Detection Limit = Approximatley 5 times signal to noise



*** Criteria for Valid Continuing Calibration = Within 20% of Certified Cylinder Value






Continuing Calibration***
9/25/97
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass

Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass






-------
GCMS Additional QA/QC Analyle Spiking Results
Table 2. General Motors Additional QA/QC Analyte Spiking Data from GCMS


Sample Name


Compound
vinyl chloride
carbon disulfide
vinyl acetate
chloroform
benzene
bromodichloromethane
MIBK
Toluene
TCE
bromoform
styrene


GMS0923B

Expected
cone. (PPM)
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.02
0.50
1.00


1ppm
Spike 1
actual (PPM)
response
1.02
0.77
0.7
1.02
0.85
0.98
0.49
0.95
0.85
0.42
0.94



Spike 1
percent
recovery
102%
77%
70%
102%
85%
98%
49%
95%
83%
84%
94%






















GMSO924D - 100 ppb

Expected
cone. (PPM
0.10
0.09
0.09
0.11
0.10
0.10
0.10
0.11
0.10
0.10
0.11
Spike 2
actual (PPM)
response
nd
0.08
nd
0.09
0.09
0.10
nd
0.12
0.14
0.10
0.12




Spike 2
percent
recovery
na
87%
na
84%
87%
99%
na
114%
135%
101%
113%





















GMSO924E

Expected
cone. (PPM)
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05



50 ppb
Spite 3
actual (PPM)
response
nd
0.04
nd
0.04
0.04
0.06
nd
0.06
0.07
0.02
0.02




SpikeS
percent
recovery
na
87%
na
75%
77%
119%
na
114%
135%
40%
38%





















GMSO924F •

Expected
cone. (PPM)
0.025
0.023
0.023
0.027
0.026
0.025
0.025
0.026
0.026
0.025
0.027



25 ppb
Spike 4
actual (PPM)
response
nd
0.02
nd
0.02
0.02
0.03
nd
0.03
0.04
nd
0.01




Spike 4
percent
recovery
na
87%
na
75%
77%
119%
na
114%
154%
na
38%
























GMSO924G - 25 ppb

Expected
cone. (PPM
0.025
0.023
0.023
0.027
. 0.026
0.025
0.025
0.026
0.026
0.025
0.027
Spike 5
actual (PPM)
response
nd
0.02
nd
0.02
0.02
0.03
nd
0.03
0.03
nd
0.01




Spike 5
percent
recover
na
87%
na
75%
77%
119%
na
114%
115%
na
-------
        PACIFIC ENVIRONMENTAL SERVICES, INC.
           CALIBRATION PROCEDURES AND RESULTS

     All of the equipment used is calibrated in accordance with the
procedures outlined in the Quality Assurance Handbook for Air Pollution
Measurement Systems. Volume III.* The following pages describe these
procedures and include the data sheets.
-------
           PACIFIC ENVIRONMENTAL SERVICES, INC.
Pitot Tube Calibration

       Each pitot tube used in sampling meets all requirements of EPA
Method 2, Section 4.1." Therefore, a baseline coefficient of 0.84 is assigned to
each pitot tube.  The following pages show the alignment requirements of
Method 2 and the Pitot Tube Inspection Data Sheet(s) for each pitot tube used
during the test program.
Transverse
Tube Axis
                                                         ,.A.or	
                                                          B	
                      Face
                     Opening-
                     Planes

                      (a)
                                                                (b)
                                           A-Side Plane
   Longitudinal
    Tube Axis

V
ft

1
Dt
*
T
} I (
A J '
B >^ i
\ \
PA

i p
1 B
 (a) end view; face opening planes
 perpendicular
   to transverse axis;

 (b) top view; face opening planes parallel to
   longitudinal axis;

 (c) side view; both legs of equal length and
   centerlines coincident, when viewed from
   both sides. Baseline coefficient values of
   0.84 may be assigned to pitot tubes con-
   structed this way
     B-Side Plane
(c)
-------
                                      Pilol Tube Calibralion Sheel




Calibrated By:        B.FISHER	                             Date:     12DEC96




Pilot Tube Number	6C	




Effective Length:          6'         	
Pilot Tube Openings Damaged?         YES
Pilot Tube Assembly Level?         |   YES  ]                   NO








      a,  =            3	°(< 10°)                       a 2  =     	3        °(< 10°)





       P ,  =            3        °(< 5°)                        P 2  =             1        °(< 5°)
             Y=         0            9=0                    A =       1.031
    z = A sin Y   	0	  cm (in.)   0.32 cm ( < 1/8 in.)




    w = A sin 9                  0           cm (in.)   0.08 cm ( < 1/32 in.)
                 PA =                                0.515          cm (in.)
                 Pp =                                0.516          cm (in.)
                                                     0.375          cm (in.)
-------
                                      Pitol Tube Calibration Sheet




Calibrated By:        B.FISHER                                        Date:     12DEC96
Pilot Tube Number        7C
Effective Lenglh:         7'
Pilol Tube Openings Damaged?        YES
Pilol Tube Assembly Level?         \  YES  |                   NO








      a,  =            0        °(< 10°)                        a 2  =            1        °(<  10°)





       P i  =            0        °(< 5°)                         02=            1        °(<  5°)
                                      9 =         1                    A =        0.98
     z = A sin Y  	0.03	 cm (in.)   0.32 cm ( <  1/8 in.)




    w = A sin 6             0.017          cm (in.)   0.08 cm ( <  1/32 in.)
                                                     0.498          cm (in.)
                 Pp =                                0.482          cm (in.)
                                                     0.375          cm (in.)
-------
                                     Pitol Tube Calibration Sheet




Calibrated By:        B.FISHER                                       Date:    12DEC96
Pilol Tube Number       8C
Effective Lenglh:         8'
Pilot Tube Openings Damaged?        YES
Pilol Tube Assembly Level?         j   YES  |                   NO








      a,  =    	0	u(< 10°)                       a 2  =    	1	°(< 10°)





      3,  =            1       °(<5°)                        P2  =            0       °(<5°)
             Y=        0            9=1                   A =       0.914
    z = A sin Y                 0          cm (in.)   0.32 cm ( <  1/8 in.)




    w = A sin 6
0.016 cm (in.) 0.08 cm ( <
PA = 0.478
Pp = 0.435
Dt = 0.375
1/32 in.)
cm (in.)
cm (in.)
cm (in.)
-------
                                      Pilol Tube Calibralion Sheel





Calibrated By:         B.FISHER	                            Dale:     12DEC96





Pilol Tube Number	7B	




Effective Lengih:         7'      	
Pilol Tube Openings Damaged?         YES
Pilol Tube Assembly Level?         |   YES  |                   NO








      a,  =     	1        °(< 10°)                        a 2  =    	0	"(< 10°)





       P ,  =             1        °(< 5°)                         3 2  =            0        °(< 5°)
             Y=         0            0=1                    A =       0.947
     z = A sin Y  	0	 cm (in.)   0.32 cm ( <  1/8 in.)




    w = Asin0             0.165          cm (in.)   0.08 cm (<  1/32 in.)
                 PA -                                0.473          cm (in.)
                 Pp =                                0.474         cm (in.)
                                                     0.375          cm (in.)
-------
a-.=.31-™    KROM 9192501835
                                                             P. 11
                           Probe or Pilot No.
Pitot Tube Inspec
c

1 ~" HI n i ~~v i ~\i^i
DUL..3.. T ^ U^V^l

. £
_^"P1
— -^s>..p2
ay=?(
-^1
U
Thermocouple Calibrat
Type of Reference Thermom
Barometric Pressure 2c>-
tioi
?'

iT
.._..
#"~
fvl
1
V
)

- ->_\
F^
.w
T

iy

Ion
eter
a 9

Source
AMfc-^4- MJ*4*r-
HOT w A.-rtf'
< c*U w*,Wr
SI ..

Date
Tube Assembly Level?
Ports Damaged?
-10D
vtt
AO
c/t
^
2°
">°
S6
JL°
flia
a Art
0/0903
a v^^T
a.  tA**C> uatc CA> lu»— T T
InHg • Ambient Temperature '^S* °F

Reference
Temperature
?)Uf U3ifc)
^lc? U^
H7'* (CO?)
Thermocouple Absolute Temperature
Temperature Difference1
1\°F(rsd 0.002-
1?>^P (CV^) -0. oo"X
^U°f (rr?^ o^o^
-------
-10-30-1997 6:53PM    FROM 9192501835
                                                                               P. 12
    P
  Pitot Tube Inspection
            BULLS=Y= LEVEL
          s:
            al

            a.2
               ..pi
               -.32
                         —\
                    8
Thermocouple Calibration
Type of Reference Thermometer
Barometric Pressurei y
                                         Probe or Pitot No.
                                                      Date
                                               Tube Assembly Level?
                                                  Ports Damaged?
                                                  -5e+ ^^' :

to. LL4*
' Reference
Temperature
ll*
Id I ,
M
Thermocouple
Temperature
;n
w
it
Absolute Temperature
Difference1
-.00 1
.002
0
                     I
                     (Ref Temn  • F .
-------
         PACIFIC ENVIRONMENTAL SERVICES, INC.
Dry Gas Meter and Orifice Meter

     Dry gas meters and orifices are calibrated in accordance with Section
3.3.2 of the QA Handbook. This procedure involves direct comparison of the
dry gas meter to a reference dry test meter. The reference dry test meter is
routinely calibrated using a liquid displacement technique. Before its initial
use in the field, the metering system is calibrated over the entire range of
operation.  After each field use, the metering system is calibrated at a single
intermediate setting based on the previous field test.  Acceptable tolerances
for the initial and final dry gas meter factors and orifice calibration factors
-------
                        DRY GAS AND ORFICE  CALIBRATION
CONTROL BOX N
DATE:

Hd ("H2O)
VACUUM ("HG)
INITIAL WTM
FINAL WTM
INITIAL DGM
FINAL DGM
TEMP. WTM (F)
TEMP. DGM (F)
TEST TIME (MIN.)
NET VOLUME WT
NET VOLUME DG
Y
H@
MB-14
26DEC96
RUN1
0.50
10
421.973
433.978
440.708
453.247
69.0
76.0
30.0
12.005
12.539
0.969
1.756
BAROMETRIC PRESS
PERFORMED BY :
RUN 2
0.75
10
434.239
445.767
453.623
465.763
68.0
78.0
24.0
11.528
12.140
0.966
1.814
RUNS
1.00
10
446.842
458.269
466.990
479.076
68.0
81.0
21.0
11.427
12.086
0.966
1.875
RUN 4
1.50
10
458.765
470.085
479.502
491.468
69.0
82.0
17.0
11.320
11.966
0.966
1.881
29.43
B.FISHER
RUNS
2.00
10
470.449
481.847
491.855
503.912
69.0
83.0
15.0
11.398
12.057
0.966
1.923


RUN 6
4.00
10
483.036
494.839
505.180
517.635
69.0
85.0
11.0
11.803
12.455
0.967
1.922
AVERAGE Y =        0.966




     ACCEPTABLE Y RANGE =




AVERAGE H@=      1.862




     ACCEPTABLE dH@ RANGE =
0.946
1.662
TO
TO
0.986
2.062
Y = (Vw x Pb x (Td + 460)) / (Vd (Pb + (dHd /13.6)) x (Tw +460))



-------
                 POSTTEST DRY GAS METER CALIBRATION
     MB#:

     DATE:

     PLANT:
 FINAL DGM
14

.9-29-97

GM-SAGINAW
                   RUN1


 VACUUM ("Hg)    11.00

 H ("H20)         3.00

 INITIAL RTM      210.419

 FINAL RTM

 INITIAL DGM
224.904

737.478

752.246
TEMP. RTM (F)    75.0

TEMP. DGM (F)    81.0

TEST TIME (MIN.)  15.0
BAROMETRIC PRE 28.83     (in. hg.)

PERFORMED BY:  S SIMON

PRETEST Y:      0.966

PRETEST H@:    1.862
  RUN 2


11.00

3.00

224.904

239.360

752.246

767.028

74.0

81.0

15.0
  RUNS


11.00

3.00

239.360

253.780

767.028

781.852

74.0

82.0

15.0
NET VOLUME RT     14.485              14.456

NET VOLUME DG     14.768              14.782

Y                   0.984              0.983

 H@                1.872              1.872
PRIOR Y =           0.966
RECHECKY=        0.982
% DIFFERENCE =     1.704
AVERAGE H@=      1.874

Y = (Vw x Pb x (Td + 460)) / (Vd (Pb + (dHd /13.6))x(Tw + 460)

 H@ = 0.0317 x  H / (Pb (Td + 460)) x ((Tw + 460) x time) / Vw)A2
                                      14.420

                                      14.824

                                       0.980

-------
                          DRY GAS AND ORFICE CALIBRATION






CONTROL BOX N RMB-13   BAROMETRIC PRESS     29.35 IN.HG.




DATE:          30May97   PERFORMED BY:    R.Kolde






                  RUN1    RUN 2     RUNS    RUN 4    RUNS    RUN 6




dHd("H2O)            0.50      0.75      1.00      1.50      2.00      4.00




VACUUM ("HG)          10        10        10       10       10       10




INITIAL WTM     874.488    885.102    896.200   904.898   915.154   925.719




FINAL WTM      884.476    895.866    904.595   9t5.004   925.266   936.622




INITIAL DGM     977.800    988.200    999.200  1007.900  1018.200  1028.800




FINAL DGM      987.585    998.870   1007.595  1018.047  1028.363  1039.750




TEMP. WTM(F)      76.000    77.000    78.000    78.000    78.000    78.000




TEMP DGM (F)      78.500    82.000    83.500    85.000    85.500    86.500




TEST TIME (MIN.)    25.000    22.000      15.0      15.0      13.0      10.0
NET VOLUME WT




NET VOLUME DG




Y




dH@
AVERAGE Y=        1.010




     ACCEPTABLE Y RANGE =            0.990 TO           1.030




AVERAGE dH@=      1.859




     ACCRPTABLE dH@ RANGE =         1.659 TO           2.059




Y = (Vw * Pb * (Td + 460)) / (Vd * (Pb + (dHd /13.6))" (Tw +460))




dH@ = 0.0317 * dHd / (Pb (Td + 460)) * (((Tw +460) * time) / Vw)A2
9.988
9.785
1.024
1.805
10.764
10.670
1.016
1.800
8.395
8.395
1.008
1.836
10.106
10.147
1.005
1.896
10.112
10.163
1.004
1.894
10.903
10.950
1.001
-------
                 POSTTEST DRY GAS METER CALIBRATION
    MB#:        RMB-13

    DATE:        .9-29-97

    PLANT:       GM-SAGINAW
                  RUN1


VACUUM ("Hg)     15.00

 H ("H20)         3.00

INITIAL RTM       165.558

FINAL RTM

INITIAL DGM
FINAL DGM
180.028

770.713

785.339
TEMP. RTM (F)    72.0

TEMP. DGM (F)    78.0

TEST TIME (MIN.)  15.0
                   BAROMETRIC PRE 28.83     (in. hg.)

                   PERFORMED BY:  S SIMON

                   PRETEST Y:      1.010

                   PRETEST  H@:    1.859
  RUN 2


15.00

3.00

180.028

194.506

785.339

800.104

73.0

81.0

15.0
  RUNS


15.00

3.00

194.506

208.994

800.104

814.913

73.0

83.0

15.0
NET VOLUME RT     14.470              14.478

NET VOLUME DG     14.626              14.765

Y                   0.993               0.988

 H@                1.865               1.859
PRIOR Y=           1.010
RECHECK Y =        0.990
% DIFFERENCE =    -1.989
AVERAGE  H@=      1.858

Y = (Vw x Pb x (Td + 460)) / (Vd (Pb + (dHd /13.6))x(Tw + 460)

 H@ = 0.0317 x H/(Pb (Td + 460)) x ((Tw + 460) x time) / Vw)A2
                                      14.488

                                      14.809

                                      0.989

-------
10-30-1997  6:50PM
FROM  9192501835
                                                                                                            ?. 3
Date
Calibrated By
Number of Runs
BEEreDd
Meier Y 1.021

Vw.inlt
Vw.fln
Vw, total
Pb
tw
Tw+460
DRYC
Previous Y 1.028
Vm, intt
Vm.fln
Vm. total
T
-------
0-L_  	  „.=«-,.,      -™-,.-, 9192501835                                                              p 2
              Date                 19-Aug-8?          Metof Box Number   M5-3
              Calibrated By          M MIIBOURNE       Initiate
              Number of Run*               3
                          • REFERENCE TEST METER •
              Meter Y         1.016

                                     RUN1     RUN 2   RUNS    RUN 4    RUNS

              VW.toR                138.412   144.623   151.744     0        0
              Vw.fin                144.623   151.744   156.916     0        0
              VW, total                5.211     7.121    5.174      0        0

              Pb                    29.99     29.99    28.99    29.99    29.99

              tW                     83       83       83       0        0
              Tw+460                 543       543     543      460      460
                            • DRY GAS METER •
              Previous Y      1.028

              Vm. Mt
              Vm. fin
              Vm. total

              TdU
              Tdif
              Tdol
              Tdof
              Td.avg
              Td+460

              Tlroa, mln
              Time, sac
              Tun* Total

              dH                    1.80      1.80     1.60     2.00      3.00
852.823
8S7.996
5.1 75
89
98
64
•6
89.5
549.5
7
2
7.03
857.996
665.078
7.06
93
100
66
67
91.5
551.5
9
36
9.60
665.078
870.234
5.156
92
100
67
66
91.75
551.75
7
0
7.00
0
0
0
0
0
0
0
0
460
0
0
0.00
0
0
0
0
0
0
0
0
460
0
0
0.00
Y
Y toUrence from avg •
dH@ tol. from avg ••
AVERAGE Y
AVERAGE dH@
W« l*C9in.!
1.031
1.817
0.00
-0.00
1.032
1.814
19 — — — — —
1.033
1.607
-0.00
0.01

1.031
1.817
0.00
•0.00

0.000
0.000
1.03
1.81

0.000
0.000
1.03
1.81

              Y •rrer (v» prior Y) •••     0.4X
              •   mu*t b* no greater than +/- 0.02
              "  muctb* no greater ihan +/- 0.20
              "• must b« no gr«atar than +/• 5*
              Orifice:
                front leak check             Y
-------
10-30-1997 6-.51PM
FROM  9192501835
                                                                                                         P. 5
Data OS-Aug-97
CaHbralad By B Palm
NumbarofRuns * . S
Meter Bex Number
•""-ifeu-
M5-4

Mater Y 1.016

Vw.Wt
Vw.fin
Vw. total
Pb
ftUNl
907.127
912.513
5.388
20.80
tw 8*
TW+460 544
RUN 2
912.875
918.262
S.367
29.80
84
544
RUNS
918.694
924.06
5.366
29.80
84
544
RUN 4
924.597
929.999
5.402
29.80
84
544
RUN. 5
930307
936.9S8
6.651
29.80
85
545
RUN 6
0
0
0
29.80
0
460
PravfewY 1.024
Vm,Wl
Vm.fln
Vm, total
TdH
TcHf
Tdel
Tdot
Td,avg
T4+46O
Tim*, mln
Tim*. *«e
Time Total
dH
- PAI IRRATir
Y
dH®
Y tolaranca from avg *
dH® tel. from avg ••
AVERAGE Y
AVERAGE dH®
853.019
658.402
5.383
85
80
82
84
85
545
13
3O
13.50
0.50
3N RESULTS
1.017
1.784
0.00
0.05
1.021
1.818
658.758
664.147
5.389
88
93
84
86
87.75
547.75
9
30
9.50
1.00
1.020
1.740
0.00
0.08

664.577
669.948
5.371
89.
97
86
87
69.75
549.75
8
0
8.00
1.50
1.022
1.861
-0.00
•0.04

670.486
675.901
5.415
92
100
88
88
92
552
7
0
7.00
2.00
1,023
1.869
-0.00
-0.05

676.205
682.864
6.659
93
104
88
89
93.5
553:5
7
0
7.00
3.00
1.023
1.854
-0.00
-0.04

0
0
0
0
0
0
0
0
460
0
0
0.00
4.00
0.000
0.000
1.02
1.82

               Y arror (v» prior Y)'
        -0.3%
               *   rnuat b« no gractar than 4-1- 0,02
               *•  mutt be no greator than +/• 0.20
-------
10-1
9192501835
                                                                                                                   P. 1
Date
Calibrated By
Number of Run*
REFER ft]
Meter Y 1.016

Vw. Wt
Vw.fln
Vw, total
Pb
Tw+460
rtt*w f
PravloutY 1.021
Vm. Init
Vin.fin
Vm, total
Tdfi
Tdif
Tdol
Tdof
Td.av0
Td+460
Time, min
Tone, see
Tiroe Total
dH
CALIBRAT
Y
dH@
Y tolerenee from avg *
dH@ tel, from avg —
AVERAGE Y
AVERAGE dH®
3l-Oct-C7
Rfehard
3
IC6TESTMI
RUN1
643.779
6S2.1
29.87
61
521
&S METER -
790.367
798.501
8.134
63
76
61
64
66
526
12
20
12.33
1.50
ION RESUL1
1.045
1.760
0.00
-0.04
1.046
1.720
STTTO

RUN 2
652.614
662.322
9.708
29.87
62
522

799.004
808.SS6
9.552
70
84
64
67
71.25
531.23
12
7
12.12
2.00
rs
1.046
1.661
0.00
0.06

Meter Box Number
M^lr j)

RUNS
662.94S
670.381
7.436
29.87
62
522

809.171
816.506
7.335
75
85
67
69
74
S34
8
31
8,52
2.50
1.047
1.740
-0,00
•0.02


RUN 4
0
0
0
29.87
0
460
0
0
0
0
0
0
a
0
460
0
0
0.00
2.00
0.000
0.000
1.05
1.72

MS-4
_ RUNS
0
0
0
29.87
0
460
0
0
0
0
0
0
0
0
460
0
0
0.00
3.00
0.000
0.000
1.05
1.72

                Y error (vs prior Y) •••
  2.9%
                •   must be no greater than +/• 0.02
                *•  must be no greater than +/- 0.20
                ••• must be no greater than +/-S%
                Orifice:
                  front leak cheek
                  back leak check
      Y
-------
10-30-1997  6:52PM
FROM  9192501835
                                                                                                           P. 3*1
Date
Calibrated By
Number of Runs
rmresm
Meter Y 1.016

Vw.Wt
Vw. fin
Vw. total
Pb
tw
TW+460
I-IBV f
Previous Y 0.992
Vm.inft
Vm.fln
Vm. total
Tdli
Tdtf
Tdoi
Tdof
Td.avg
Td+460
Time, min
Time, »ee
Time Total
dH
CALIBRAT
Y
dH®
Y tolerence from avg •
dH® tol. from avg "
AVERAGE Y
AVERAGE dH®
lS-Sep-87
R DURHAM
S
ICE TEST Mi
RUN1
524.909
530.031
5.122
29.92
81.5
541.5
IS METER -
74.004
78.4
S.306
99
101
86
87
90.5
S50.5
12
5
12.08
0.50
ION RESUU
0.996
1.532
0.00
0.06
0.999,
1.591
TEfl

RUN 2
•
.530.634
536.127
5.493
29.02
83
543

80.029
85.700
5.68
92
103
88
89
93
553
9
21
9.35
1.00
"e . . ...
0.998
1.599
0.00
-0.01
s
Motor Box Number
Initial* £k*5 0.

RUNS
537.665
543.792
6.127
29.92
84
544

87.28
93.609
6.329
97
106
89
90
95.5
555.5
8
37
8.62
1.50
1.001
1.640
•0.00
-0.05


RUN 4
544.465
550.119
5.654
20.02
84
544
94.302
100.14
5.838
96
103
90
90
94.75
554.75
6
49
6.82
2.00
0.999
1.605
0.00
-0,01

M5-10
RUNS
550.504
555.789
5.285
29.92
84
544
100.535
105.97
5.435
96
106
80
92
96
556
5
10
5.17
3.00
1.002
1.581
•0.00
0.01

               Y error (v» prior Y) •••
        0.7%
               *   must b« no greater than +/- 0.02
               ••  must be no greater than +/- 0.20
               ••• must be no greater than +/- 5%
               Orifice:
                 front leak check
                 back leak check
             Y
-------
                                                                                                         P. 8
Date
Calibrated By
Number of Runt
         28-Sep-97
         RICHARD
       Meter Bo* Nurni
       Initials
Meter Y
Vw.InK
Vw.fin
VW, total

Pb
                MS-10
• REFERENCE TEST METER	

   1.016

            RUN 1     RUN 2
                                           BUN3    RUN4    RUNS     RON 6
           770.626   785.843  806.645
           785.843   606.645  827.817
            6.217    22.802    18.972
            29.65
                                  29.65
                                           29.65
                    0
                    0
                    0

                  29.es
                    o
                    o
                    o
                  29.65
                    0
                    0
                    0

                   29.65
tw
Tw+460

Previous Y
Vm,lnlt
Vm.fn
Vm, total
Tdi
TdH
Tdol
Tdof
Td.awg
Td+460
Time, min
Time. sec
Time Total
75
535
._. rvRY RA*? MPTPR _
0.999
753.029
759.31
6.281
84
91
78
78
82.25
542.25
7
24
7.40
75
535


759.31
782.45
23.14
as
96
78
82
85.25
545.25
27
15
27.25
75
535


782.45
801.767
19.317
80
98
82
84
88.25
548.25
22
42
22.70
                                                      0
                                                     480
                                                   0
                                                  460
                                       0
                                      460
dH
                         2.00
                                  2.00
                                2.00
                                          0
                                          O
                                          0

                                          0
                                          0,
                                          0
                                          0
                                          0
                                         460

                                          0
                                          0
                                         0.00

                                         2.00
                             0
                             0
                             0

                             0
                             0
                             0
                             0
                             0
                            460

                             0
                             0
                            0.00

                            3.00
                              0
                              0
                              0

                              0
                              0
                              0
                              0
                              0
                             460

                              0
                              0
                             0.00

                             4.00
           - CALIBRATION RESULTS •
Y
dH®

Y tolerance from avg •
dH@ tol. from avg "

AVERAGEY
AVERAGE dH©
            1.014
            1.564

             0.00
             0.00

            1.016
            1.56S
Y error (vt prior Y) ••*     1,7%
•   must be no greater than 4-1- 0.02
•*  must be no greater than +/- 0.20
••* must be no greater than -f/- 5%
1.015
1.568

0.00
-0.00
1.018
1.563

-0.00
0.00
0.000
0.000

 1.02
 1.57
0.000
0.000

 1.02
 1.57
0.000
0.000

 1.02
 1.57
Orifice:
  front leak check
  baek leak cheek
                 Y
-------
10-30-1997  6:51PM      FROM  9192501835
                Date               28-Sep-97
                Calibrated By         RICHARD
                Number of Runt              3
                                                     Meter Bex Number  M5-11
Meter Y 1.016

Vw. intt
Vw.fln
Vw, total
Pb
tw
Tto+460
IWC ICOI Ml
RUN1
736.069
741.93
5.861
29.65
74
534

RUN 2
741.93
752.105
10.175
29.85
75
535

RUNS
756.95
770.37
13.42
29.65
75
53S

RUN 4
. 0
0
0
29.65
0
460

RUNS
0
0
0
29.65
0
460

Previous Y 1.024
Vm. InH
Vm,fln
Vm. total
Tdll
Tdif
Tdol
Tdof
Td,avg
Td+460
Time, min
Tune, see
Time Total
819.432
825.316
5.884
82
94
76
78
82.5
542.5
10
56
10.93
825.316
835.569
10.253
88
97
78
81
86
S46
19
2
19.03
dH 0.95 0.95
Y 1.026 1.027
dH© 1,816 1.827
Y tolerenee from avg *
dH® tol. from avg *«
AVERAGE Y
AVERAGE dH®
0.00
0.00
1.027
1.819
0.00
-0.01


840.463
854.006
13.543
89
97
81
83
87.5
547.5
25
4
25.07
0.95
1.028
1,813
-0.00
0.01


0
0
0
0
0
0
0
0
460
0
0
o.oo-
2.00
0.000
0.000
1.03
1.82


0
0
0
0
0
0
0
0
460
0
0
0.00
3.00
0.000
0.000
1.03
1.82


                Y error (v« prior Y) •••     0.3%
                •  must be rto greater than +/- 0.02
                •• muct be no greater than +/- 0.20
                •" must be no greater than +/- 5%
                Orifice:
                  front leak check
                  back leak check
Y
-------
0--
   hROM 9192501835
                                                          P. S
               Date
               Calibrated By
               Numbw of Runs
           05-Sep-07
          David Goshaw
                  5
Mater Box Number
Initial*
M5-11
               MeterY
               Vw, InK
               Vw.fin
               Vw, total

               Pb
              dH
- REFERENCE TEST METER	:

    1.010

            RUN1     RUNS
                                                         RUNS    RUN 4     RUNS
           450.702 .  458.505  465.504   474.26    487.068
           458.184   465.256  473.708   486.60    483.788
            7.482     5.751     8.198    12.63     6.72
                                       29.25
                                                29.25
                               29.25
                                                                   29.25
                                                                            29.2S
tw
Tw+460

Previous Y
Vm.lnll
Vm.fin
Vm, total
TdS
Tdlf
Tdoi
Tdof
Td.av8
Td+460
Tim», min
Tim*, toe
Tun* Total
79
53B
. . BHY CAfi MFTFB
0.987
357.35
364.051
7.601
94
90
87
87
91.75
551.75
19
0
19.00
79
539


366.294
372.125
5.831
96
87
97
87
91.75
551.75
10
30
10.50
79
939


372.376
380.676
8.3
94
105
80
$7
91.3
551.5
12
24
12.40
79
539


381.239
394.01
12.771
101
107
67
89
96
556
16
27
16.45
79
539


394.186
401.066
6.878
102
109
•9
89
97.25
557.25
7
5
7.08
                                       0.50
                                                 1.00
                               1.50
                                                                   2.00
                                                                            3.00
"" w«uiorw» i ii
Y
dH®
Y tolerenee from avg *
dH® to), from avg ••
AVERAGE Y
AVERAGE dH®
Lin ncovLK
1.022
1.796
0.00
0.06
1.024
1.861
> i
1.023
1.842
0.00
0.02


1.023 1.031
1.826 1.888
0.00 -0.01
•0.06 -0.03


1.019
1.852
0.01
0,01


              Y error (v« prior Y) »••
            2.7%
              *  mtwt be no greater than -*•/- 0.02
              •• must b* no greater than +/- 0.20
-------
(SI


d.
                                                        METHOD 5 CALIBRATION FORM
 Q :

 N '.
 0) •

 0)
  I
  Jl
  J)
  T)
                  •Reference Meter Y*=fe99£

-------
WitIMUU d DGM CALIBRATION USING CRITICAL ORIFICES
RECORDING LUG
                                                                                         INITIAL
     FINAL
DATE:
GAS METER P/N:
1 ORIFICE!
| RUNI
q->o^


K1
FACTOR
(AVG)
?

DGM SERIAL NUMBER:
CRITICAL ORIFICE SET SERIAL NUMBER:

TESTED
VACUUM
(InHg)

*
^




1
2
3
1^
2
3
1
2
3
.£5#


PC/



















A\^-V3
S^-(3>?«>

DGM READINGS (FT1)
INITIAL
FINAL

W.^oft


2lfl7$3
















NETJVm)
»/.5S^


BAROMETRIC PRESSURE (In Hfl):
lA^.cy

TEMPERATURES *F
AMBIENT
DGM INLET
INITIAL FINAL
DGM OUTLET
INITIAL FINAL

?(


7i


75-


?/


?2L


































DGM
AVG
~»2.


|?1.$-y

ELAPSED
TIME (MIN)
e

i-T





•i




\







DGM AH
(InHiO)

L-?










     NOTE:  AFTER PERFORMING CALIBRATION RUNS, RECORD DATA IN SPREADSHEET INCLUDED ON DISKETTE.
           PRINT OUT A CALIBRATION REPORT.
                                                      ii,
-------
METHOD 5 DGM CALIBRATION USING CRITICAL ORIFICES
RECORDING LOG
                                                                              INITIAL
     FINAL
AVG (Pk.)
DATE:
GAS METER P/N:
ORIFICE!
RUN!
J'^^-T
-I&-/V

DGM SERIAL NUMBER:
CRITICAL ORIFICE SET SERIAL NUMBER:

to
FACTOR
(AVG)
TESTED
VACUUM
(In Ho)

*




1
2
3
1
2
3
1
2
3
413/V


/T-


.





















DGM READINGS (FT1)
INITIAL
FINAL

/. SW


Zl.
-------
METHOD 5 DGM CALIBRATION USING CRITICAL ORIFICES
=.  /, a i'
                    RECORDING LOG
                                                                                  INITIAL
                         FINAL
AVG(P».)
DATE:
GAS METER P/N:
ORIFICE!
RUNI
1-Wl
RM&-&

K
FACTOR
(AVG)


DGM SERIAL NUMBER:
CRITICAL ORIFICE SET SERIAL NUMBER:

TESTED
VACUUM
(In Hg)

*23




1
2
3
1
1^
2
3
1
2
3
.CCSl


'9




















*#

DGM READINGS (FT1
INITIAL
FINAL

77,V<25


n*>s
















NET(V^
lU^co


BAROMETRIC PRESSURE (in Hg):
^.^2-

TEMPERATURES *F
AMBIENT
DGM INLET
INITIAL FINAL
DGM OUTLET
INITIAL FINAL

65


71


1?


*ll


75


































DGM
AVG
7V


**&*-

ELAPSED
TIME (MIN)
e

2-^





•i









Zf.f^
DGM AH
(InHiO)

2//










    NOTE:  AFTER PERFORMING CALIBRATION RUNS, RECORD DATA IN SPREADSHEET INCLUDED ON DISKETTE.
          PRINT OUT A CALIBRATION REPORT.
                       X   /,
-------
         PACIFIC ENVIRONMENTAL SERVICES, INC.
Stack Thermocouples

     Each thermocouple is calibrated by comparing it with an ASTM-3F
thermometer at approximately 32°F, ambient temperature, 100°F, and SOOT.
The thermocouple reads within 1.5 percent (%) of the reference thermometer
throughout the entire range when expressed in degrees Rankine.  The
thermocouples may be checked at ambient temperature at the test site to
verify the calibration. Calibration data are included in the following
-------
                   PACIFIC ENVIRONMENTAL SERVICES.INC.

                   TEMPERATURE SENSOR CALIBRATION DATA FORM
                            FOR STACK THERMOCOUPLES
DATE:                 10-Dec-96

AMBIENT TEMPERATURE:    70

CALIBRATOR:           B.FISHER
THERMOCOUPLE NUMBER:    T6C
BAROMETRIC PRES.(ln.Hg): 	29.09
REFERENCE:
Mercury-in-glass:

Other:
                                                               ASTM 3F
Reference
point
number
1
2
3
4
Source3
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperature,°F
69
32
200
378
Thermocouple
Potentiometer
Temperature,°F
70
31
203
375 '
Temperature
Difference,1*
%
-0.19
0.20
-0.45
0.36
"Type of calibration used.

bfref. temp.aF+46QWtest thermometer temp.eF+4601   X100
                    ref temp,°F+460

Comments:
                      100<1.5%
-------
                   PACIFIC ENVIRONMENTAL SERVICES.INC.

                   TEMPERATURE SENSOR CALIBRATION DATA FORM
                            FOR STACK THERMOCOUPLES
DATE:                 IO-Dec-96

AMBIENT TEMPERATURE:    70

CALIBRATOR:           B.FISHER
THERMOCOUPLE NUMBER:     7C
BAROMETRIC PRES.(ln.Hg):   29.09
REFERENCE:
Mercury-in-glass:

Other:
                                                               ASTM 3F
Reference
point
number
1
2
3
4
Source3
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperature,°F
70
32
204
440
Thermocouple
Potentiometer
Temperature,°F
71
33
202
437
Temperature
Difference,"
%
-0.19
-0.20
0.30
0.33
'Type of calibration used.

"(ref. temp.aF+460Htest thermometer temp.gF+46Q)   X100
                    reftemp,°F+460

Comments:
                      100<1.5%
-------
                   PACIFIC ENVIRONMENTAL SERVICES.INC.

                    TEMPERATURE SENSOR CALIBRATION DATA FORM
                             FOR STACK THERMOCOUPLES
DATE:                10-Dec-96

AMBIENT TEMPERATURE:     70

CALIBRATOR:           B.FISHER
THERMOCOUPLE NUMBER:     8C
BAROMETRIC PRES.(ln.Hg):    29.09
REFERENCE:
Mercury-in-glass:

Other:
                                                                ASTM 3F
Reference
point
number
1
2
3
4
Source3
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperature,°F
70
33
190
396
Thermocouple
Potentiometer
Temperature,°F
70
33
188
395
Temperature
Difference,"
%
0.00
0.00
0.31
0.12
"Type of calibration used.

"fref. temp.eF+460Wtest thermometer temp.aF+4601  X100
                    ref temp,°F+460

Comments:
                     100<1.5%
-------
                   PACIFIC ENVIRONMENTAL SERVICES.INC.


                   * TEMPERATURE SENSOR CALIBRATION DATA FORM
                             FOR STACK THERMOCOUPLES
DATE:                10-Dec-96

AMBIENT TEMPERATURE:     70
CALIBRATOR:
B.FISHER
                    THERMOCOUPLE NUMBER:     7B
                    BAROMETRIC PRES.(ln.Hg):    29.09
REFERENCE:
Mercury-in-glass:

Other:
                                                                ASTM 3F
Reference
point
number
1
2
3
4
Source3
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperature,°F
72
34
204
394
Thermocouple
Potentiometer
Temperature,°F
73
35
201
391
Temperature
Difference,"
%
-0.19
-0.20
0.45
0.35
"Type of calibration used.

"(ref. temp.aF+460Wtest thermometer temo.gF+46Ql
                X100
                    reftemp,°F+460
                                                               100<1.5%
Comments:
-------
         PACIFIC ENVIRONMENTAL SERVICES, INC.
Digital Indicators for Thermocouple Readout

     A digital indicator is calibrated by feeding a series of millivolt signals to
the input and comparing the indicator reading with the reading the signal
should have generated. Errors did not exceed 0.5 percent (%) when the
temperatures were expressed in degrees Rankine.  Calibration data are
included in the following Thermocouple Digital Indicator Calibration Data
-------
                     PACIFIC ENVIRONMENTAL SERVICES, INC.
DATE:   6-1-97
OPERATOR:

CALIBRATION DEVICE
                         THERMOCOUPLE DIGITAL INDICATOR
                               CALIBRATION DATA SHEET
             INDICATOR NO.:

             SERIAL NO.:

               MANUFACTURER:
R.Kolde
 Digital Indicator
                                                                       RMB-13
                                                                         207
OMEGA
TEST POINT
NO.
1
2
3
4
5
6
7
8
9
10
MILLIVOLT
SIGINAL
-0.692
1.520
3.819
6.092
8.314
10.560
22.251
29.315
36.166
42.732
EQUIVALENT
TEMP °F
0
100
200
300
400
500
1000
1300
1600
1900
DIGITAL INDICATOR
TEMP READING °F
0
99
201
301
398
499
1001
1300
1600
1901
DIFFERENCE %
0
0.18
-0.15
-0.13
0.23
0.10
-0.07
0.00
0.00
-0.04
        Percent difference must be less than or equal to 0.5 %

        Percent difference:
(Equivalent temp,.°R - Digital indicator tern, °R) * ( 100%)
                  (Equivalent temp, °R)
        Where °R = °F + 460
-------
                    PACIFIC ENVIRONMENTAL SERVICES, INC.
DATE:
27-Dec-96
                        THERMOCOUPLE DIGITAL INDICATOR
                              CALIBRATION DATA SHEET
OPERATOR:
CALIBRATION DEVICE:
            B.FISHER
INDICATOR NO.:

SERIAL NO.:

  MANUFACTURER:
                                                           MB-14
TEST POINT
NO.
1
2
3
4
5
6
7
8
9
10
MILLIVOLT
SIGINAL
-0.692
1.520
3.819
6.092
8.314
10.560
22.251
29.315
36.166
42.732
EQUIVALENT
TEMP °F
0
100
200
300
400
500
1000
1300
1600
1900
DIGITAL INDICATOR
TEMP READING °F
0
101
203
302
399
499
999
1296
1596
1894
DIFFERENCE %
0
-0.18
-0.45
-0.26
0.12
0.10
0.07
0.23
0.19
0.25
       Percent difference must be less than or equal to 0.5 %

       Percent difference:
                    (Equivalent temp..°R - Digital indicator tern, °R) * ( 100%)
                                      ( Equivalent temp, °R)
       Where °R = °F + 460
-------
         PACIFIC ENVIRONMENTAL SERVICES, INC.
Dry Gas Thermocouples and Impinger Thermocouples

     The dry gas thermocouples are calibrated by comparing them with an
ASTM-3 thermometer at approximately 32°F, ambient temperature, and a
higher temperature between approximately 100°F and 200°F. The
thermocouples agreed within 5°F of the reference thermometer. The
impinger thermocouples are checked in a similar manner at approximately
32°F and ambient temperature, and they agreed within 2°F.  The
thermocouples may be checked at ambient temperature prior to the test series
to verify calibration.  Calibration data are included in the following Dry Gas
-------
                    PACIFIC ENVIRONMENTAL SERVICES.INC.

               TEMPERATURE SENSOR CALIBRATION DATA FORM
                               FOR METER BOX
DATE:
27-Dec-96
AMBIENT TEMPERATURE:    70   °F

CALIBRATOR:     B.FISHER
THERMOCOUPLE NUMBER:
                               BAROMETRIC PRES.(ln.Hg):
                                           Other:
MB-14
                           29.4
                               REFERENCE:
                                      Mercury-in-glass:     ASTM 3F
Reference
point
number
INLET
1
2
3
OUTLET
1
2
3
Source3
(Specify)


Ambient Air
Cold Bath
Hot Bath
Ambient Air
Cold Bath
Hot Bath
Reference
Thermometer
Temperature,°F

74
33
128
70
33
149
Thermocouple
Potentiometer
Temperature,°F

75
34
129
71
34
150
Temperature
Difference,"
°F

1
1
1
1
1
1
3Type of calibration used.
Allowable tolerance ±5°F
Comments:
-------
                    PACIFIC ENVIRONMENTAL SERVICES, INC.


               TEMPERATURE SENSOR CALIBRATION DATA FORM
                               FOR METER BOX
DATE:
30May97
AMBIENT TEMPERATURE:    76  °F

CALIBRATOR:      R.Kolde
THERMOCOUPLE NUMBER:

BAROMETRIC PRES.(ln.Hg):

REFERENCE:
       Mercury-in-glass:

Other:
RMB-13
                                                         29.35
                                                                   ASTM 3F
Reference
point
number
INLET
1
2
3
OUTLET
1
2
3
Source3
(Specify)
Ambient Air
Cold Bath
Hot Bath
Ambient Air
Cold Bath
Hot Bath
Reference
Thermometer
Temperature,°F
76
34
150
76
34
150
Thermocouple
Potentiometer
Temperature,°F
76
35
149
75
35
151
Temperature
Difference,"
°F
0
1
1
1
1
1
aType of calibration used.

"Allowable tolerance ±5°F


Comments:
-------
3-3b •; ;
               3192501835
 Date            	
 Barometric pressure,  P,
                 Metering System ID No.  fff-J
  Orifice
 manometer
  setting
   AH
Sptromotop
gas volume
  (Vw)
  ft3
Dry gas
 meter
volume
 (Yin)
 ft3
          Temperatures
           Inlet
            (ti)
                                           Dry Gas Meter
Outlet
  (to)
Avg
(tm)
Time
 (0)
 min
  1.0
                       -77/
77
79/S.I
                                   77/
                           77
                                     jf-'O*
  7.0
   3.0
                                     >^IK
                                     Calculations


AH
in H20




Average
Yi ;
y ^v^i (t. * 460)
rr PB j. &H -\ /t j. x ^ n \
a * 13.5 w



«

AH@i

0.0317 Aff r (Cv * 460)0 2
P,, (ta + 460) / Vv


-


   Y

 AH0
 Ratio  of  reading  of wet-test  meter to  dry  gas  meter;  tolerance  for
 individual  values ±0,02  from average.
 Orifice  pressure differential  that  equates  to  0.75  cfm of air 0 68 °F and
-------
                 PACIFIC ENVIRONMENTAL SERVICES.INC.
                                                 4700 Duke Drive,
                                                       Suite 150
                                                Mason, OH 45040
                                             Phone: (513) 398-2556
                                               Fax: (513) 398-3342
                                                   www.pes.com
               TEMPERATURE SENSOR CALIBRATION DATA FORM
                             FOR SAMPLE HEAD
DATE:
12/19/96
AMBIENT TEMPERATURE(°F):

CALIBRATOR:
              77
            S.Simon
THERMOCOUPLE NUMBER:

BAROMETRIC PRES.(ln.Hg):

REFERENCE:
Mercury-in-glass:

Other:
SH-2
29.33
                                                                  ASTM-3
Reference
point
number
1
2
Source3
(Specify)
Ambient Air
Cold Bath
Reference
Thermometer
Temperature,°F
77
40
Thermocouple
Potentiometer
Temperature,°F
76.6
40.6
Temperature
Difference, b
°F
0.4
0.6
"Type of calibration used.

"Allowable tolerance ±2°F


Comments:
                      SAMPLE HEAD CALIBRATION FORM
-------
DATE:
                 PACIFIC ENVIRONMENTAL SERVICES.INC.     4?oo Duke Drive,
                                                                       Suite 150
                                                                 Mason, OH 45040
                                                              Phone: (513) 398-2556
                                                                Fax:(513)398-3342
                                                                   www.pes.com

               TEMPERATURE SENSOR CALIBRATION DATA FORM
                              FOR SAMPLE HEAD
12/19/96
AMBIENT TEMPERATURE(°F):

CALIBRATOR:
              76
            S.Simon
THERMOCOUPLE NUMBER:

BAROMETRIC PRES.(ln.Hg):

REFERENCE:
Mercury-in-glass:

Other:
SH-4
29.33
                                                                  ASTM-3
Reference
point
number
1
2
Source3
(Specify)
Ambient Air
Cold Bath
Reference
Thermometer
Temperature,°F
76
39
Thermocouple
Potentiometer
Temperature,°F
76
39.2
Temperature
Difference,"
°F
0
0.2
aType of calibration used.
Allowable tolerance ±2°F
Comments:
                       SAMPLE HEAD CALIBRATION FORM
-------
                 PACIFIC ENVIRONMENTAL SERVICES,INC.
                                                 4700 Duke Drive,
                                                       Suite 150
                                                 Mason, OH 45040
                                              Phone:(513)398-2556
                                                Fax: (513) 398-3342
                                                   www.pes.com
               TEMPERATURE SENSOR CALIBRATION DATA FORM
                              FOR SAMPLE HEAD
DATE:
12/19/96
AMBIENT TEMPERATURE(°F):

CALIBRATOR:
              76
            S.Simon
THERMOCOUPLE NUMBER:

BAROMETRIC PRES.(ln.Hg):

REFERENCE:
Mercury-in-glass:

Other:
SH-5
29.33
                                                                  ASTM-3
Reference
point
number
1
2
Source3
(Specify)
Ambient Air
Cold Bath
Reference
Thermometer
Temperature,°F
76
40
Thermocouple
Potentiometer
Temperature,°F
76
40.8
Temperature
Difference,1*
°F
0
0.8
aType of calibration used.

"Allowable tolerance ±2°F


Comments:
                       SAMPLE HEAD CALIBRATION FORM
-------
 DATE:
                PACIFIC ENVIRONMENTAL SERVICES.INC.     4?oo Duke Drive,
                                                                      Suite 150
                                                                Mason, OH 45040
                                                             Phone: (513) 398-2556
                                                               Fax: (513) 398-3342
                                                                   www.pes.com

              TEMPERATURE SENSOR CALIBRATION DATA FORM
                             FOR SAMPLE HEAD
12/19/96
AMBIENT TEMPERATURE(°F):

CALIBRATOR:
              77
            S.Simon
THERMOCOUPLE NUMBER:

BAROMETRIC PRES.(ln.Hg):

REFERENCE:
Mercury-in-glass:

Other:
SH-6
29.33
                                                                  ASTM-3
Reference
point
number
1
2
Source3
(Specify)
Ambient Air
Cold Bath
Reference
Thermometer
Temperature,°F
77
40
Thermocouple
Potentiometer
Temperature,°F
77.4
40.8
Temperature
Difference,11
°F
0.4
0.8
'Type of calibration used.

Allowable tolerance ±2°F


Comments:
                      SAMPLE HEAD CALIBRATION FORM
-------
 APPENDIX F




-------
                            PROJECT PARTICIPANTS
Name
Michael Ciolek
John Chehaske
Franklin Meadows
Dennis Holzschuh
Dan Scheffel
Troy Abemathy
Gary Gay
Ben Elsass
Ron Kolde
Arthur Daughtery
John Malone
Mike Milbourn
Barry Rayfield
Jim Peeler
Laura Kinner
Affiliation
USEPA, Emission Measurement Center
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc.
DEECO"
DEECO"
DEECO1
DEECO1
EMI
EMI
Responsibility
Work Assignment Manager
Program Manager
Project Manager
On-site QA/QC Officer
Field Team Leader
Site Leader/Console Operator
Site Leader/Console Operator
Sample Recovery
Sample Recovery
Site Leader/Console Operator
Site Leader/Console Operator
Site Leader/Console Operator
Sample Recovery
Site Leader/GC/MS Operator
Site Leader/GC/MS Operator
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO. 2.
EPA-454/R-99-026
4. TITLE AND SUBTITLE
Final Report - Volume II of II, Iron and Ste<
Scrubber - General Motors Corp., Saginaw,
:1 Foundries Manual Emissions Testing, Cupola We

7. AUTHOR(S) * ..
9. PERFORMING ORGANIZATION NAME
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27'
AND ADDRESS
709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
July 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-70069
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating iron and steel foundries to identify and quantify hazardous air pollutants
(HAPs) emitted from cupolas; electric arc furnaces; and pouring, cooling and shakedown operations of sand mold casting processes. General Motors
Corporation, Saginaw Casting Operations (GMC), Saginaw, Michigan was selected by the EPA as the host facility at which to 1) characterize HAP
emissions from cupolas that are controlled by wet scrubbers, and 2) assess wet scrubber performance in controlling HAP emissions from cupolas. GMC
was selected because EPA deemed this facility to be representative of a large segment of the sand casting foundry industry and GMC operates a relatively
large cupola that is controlled by a wet scrubber.
This report presents the results of a manual emissions testing program to characterize emissions from a cupola and assess the performance of the wet
scrubber in controlling HAP emissions. Testing was conducted at the cupola wet scrubber inlet and outlet to determine air emissions of particulate
matter (PM) and metal HAPs; and at the cupola wet scrubber outlet to determine organic HAPs consisting of dibenzo-p-dioxins and polychlorinated
dibenzodurans (PCDDs/PCDFs) and semi-volatile organic hazardous air pollutnats (SVOHAPs), and volatile organic hazardous air pollutants (VOHAPs)
The data may be used by the EPA as potential Maximum Achievable Control Technology (MACT) floor technology for cupolas.
During the testing program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission control system
operating parameters, and prepared Section 3.0, Process and Control Equipment operation, of this report.
This volume (Volume II) is comprised of 471 pages and consists of Appendices: C (Analytical Data - Particulate Matter and Metals),
D (Calculations), E (QA/QC Data), and F (Participants).
17. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTIONS
Cupola
Dioxins/Furans
Emission Measurements
Hazardous Air Pollutants
Metals
Particulate Matter
Semi- Volatile Organic Hazardous
Air Pollutants
Volatile Organic Hazardous Air
Pollutants
Wet Scrubber
18. DISTRIBUTION STATEMENT
Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS

19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group

21. NO. OF PAGES
1,159
22. PRICE
EPA Form 2220-1 (Rev. 4-77)  PREVIOUS EDITION IS OBSOLETE
-------