United SIMM Environmental Protection Agency Office* Emergency end EPA/ROO/R07-88/017 September 1088 &EPA Superfund Record of Decision: Hasting Ground Water/Far-Mar, NE ------- ...!ft.... REPORT =MENTAtION .1 a. ItVOIIf "P A/ROD/R07 -8 8/0 17 t~~CORD OF DECISION , Hastings Ground Water (PAR-MAR-CO), NE First Remedial Action uII8of(a) .. .. -.ctpl,nra ~tc...... .... - .~ .,--........ . . .. ~Jro/88 .. .. ""rforml"l O'l8ft1a8tlon .... No; t. ~... Otpnla...... ...,.. .nd AcId.... 10. .-.o)8CtIT.III!WO" Unit No. -- IL Contr8ct(C) or GI8I1t(Q) No. It) (0) 12. SponSOrinC Orpnlutlon N,me .nd Add,.., U.S. Env~ronmenta~ Protection 401 M Street, S.W. Washington, D.C. 20460 Agency II. T1118 of "eOOft .. ...rIod CowNd 800/000 I" II. Supplement8ry Not.. I" Ab8tr8ct fLJmlt: 200 words).. . . . . The FAR-MAR-CO subslte of the Hastlngs Ground Water Contam1nat10n slte 1S located east of the City of Hastings, Adams County, Nebraska. The subsite is a part of an industrial enterprise zone which contains industrial properties situated along the Burlington-Northern railroad' right-of-way. Residential properties. are located immediately northwest of the site and agricultural lands are located east of the site. Historical and current use of the area has been for grain storage and railcar loading. The site is currently owned by Farmland Industries, Inc., who acquired the property ~ough a merger with FAR-MAR-CO, Inc. in 1967. The current and previous owners used rious chemicals onsite for fumigation of stored grain. Contamination was discovered when complaints about water quality were received by the Nebraska Department of Health (NDOH). Subsequently, the NDOH and the Nebraska Department of Environmental Control began investigating widespread ground water contamination in the Hastings area. Wells that are part of CMS, Inc. public supply system are located east and downgradient of the sUbsite. Contaminated soil a.t the subsite are believed to be the result of accidental spills and may be the direct result of a 1959 grain dust explosion which damaged a fumigation tank system, releasing 997 gallons of fumigant. The highest levels. of contamination of soil and soil-gas occur within close proximity to the original grain (See Attached Sheet) 17. Document AftaIy8l8 .0 Desertptora Record of Decision Hastings Ground Water (FAR-MAR-CO), NE First Remedial Action Contaminated Media: gw, soil Key Contaminants: carbon tetrachloride, b. ld8nt1f1era/Oll8ftoEnd8d TetmI . . ethylene dibromide Co COSATI Fleld/Group ,-- Anll.bUIly St.tement It. Security Clan (This Report) None 21. No. of Pale' 29 I -- 20. Security Class (ThIs Pale) None Z2. Price CS.. ANSI-Z39.Uh $ee In.tn/ctlon. 0/1 R.".,.. OPTIONAL FOR" 272 14-171 (Formerly NTI5-35) o.partment of Commerce ------- EPA/ROD/R07-88/017 ~tings Ground Water (FAR-MAR-CO), NE st Remedial Action 16. ABSTRACT (continued) elevator in relatively small zones. The volume of contaminated soil is estimated to be 33,800 yd3 yards and is the focus of this ROD. High levels of the contaminants are also found in the ground water beneath the site. The primary contaminants of concern affecting soil and ground water are carbon tetrachloride and ethylene dibromide (EDB). The selected remedial action for this site includes: in situ soil vapor extraction, utilizing vacuum extraction technologies; treatment of extracted vapor with an activated carbon system, if necessary; access restrictions; and implementation of an O&M program which includes soil, air and ground water monitoring. Results of the ground water monitoring will be used to develop a technical approach for plume management and evaluate the need for ground water treatment in a subsequent ROD. The estimated present worth cost for this remedial action is $2,526,000, which includes a projection of annual O&M costs for the five year operating period. Long-term O&M costs will depend on the success of the vapor extraction during the operating period. r ------- \ . RECORD OF DECISION DECLARATION INITIAL SOURCE CONTROL OPERABLE UNIT SITE NAME AIm LOCATION FAR-MAR-CO-- Hastings "Ground Water Contamination Hastings, Nebraska STATEMENT Ql BASIS MiD PURPOSE This decision document presents the selected remedial action for the FAR-MAR-CO subsite developed in accordance with the Comprehensive Environmental Response, Compensation and Liability Act of 1980, as amended by the Superfund Amendments and Reauthorization Act of 1986 and consistent with the National oil and Hazardous Substances Pollution Contingency Plan to the extent practicable. This decision is based upon the contents of the administrative record for the FAR-MAR-CO subsite. The State of Nebraska concurs on the selected remedy. DESCRIPTION Ql rHI REMEDY This initial source control operable unit was developed to protect public health and the environment by controlling the migration of contaminants present in the soils which overlie the aquifer. Prior to implementation of a full-scale remedy for soil vapor contamination, a pilot-scale test will be undertaken. This pilot-scale test may be done at another subsite. The operable unit is fully consistent with all planned future activities. Future activities will be addressed in subsequent Records of Decision and will include a decision on possible remediation of contaminated ground water. The major components of the selected remedy are as follows: Measures to prevent direct contact to soils contaminated with ethylene dibromide: Extraction of volatile contaminants from the silt and sand unsaturated zones: Monitoring contaminants in the soils above the aquifer: and Monitoring ground water contamination at the site. ------- 2 DECLARATION This selected remedy is protective of human health and the environment, attains Federal and state requirements that are applicable-Gr relevant and appropriate to the remedial action and is cost-effective. This remedy satisfies the statutory preference for remedies that employ treatment that reduces toxicity, mobility or volume as a principal element and utilizes permanent solutions and alternative treatment technologies to the maximum extent practicable. This remedy will mitiqate future releases to the qround water: however, this action will not address other contaminant source areas. Due to its limited scope of miqration control, this remedy does not address remediation of the qround water. Subsequent actions are planned for the site that will address all remaininq concerns. C(-30"'~' Dat'e /'I''l% /<~ ~I/ .~, S-iqnature/(RA/AA) Attachments: Index to Administrative Record Decision Summary Responsiveness Summary . - -- - -- ----~--- ----~-~ - ------- -. -.-.. RECORD OF DECISION DECISION SUMMARY HASTINGS GROUND WATER CONTAMINATION FAR-MAR-CO SUBSITE HASTINGS, NEBRASKA Prepared By: U.S. Environmental Protection Agency Region VII Kansas City, Kansas September 1988 ------- ~ I. II. III. IV. V. VI. VII. VIII. IX. x. XI. XII. XIII. XIV. xv. Record of Decision Decision Summary _. ---- Contents Paae Site Description site History 1 1 Enforcement History Community Relations 5 5 Site Characteristics 6 Risk Assessment 13 Scope of Operable Unit Evaluation of Alternatives 1.5 16 Summary of Alternatives Selected Alternative 16 22 Cleanup Levels Operation and Maintenance 24 24 Statutory Findings Schedule 25 25 Future Action 25 ------- DECISION SUMMARY FAR-MAR-CO SUBSITE .HASTINGS GROUND WATER CONTAMINATION SITE DESCRIPTION The-:FAR-MAR-CO subsite is located east of the City of Hastings, Adams County, Nebraska. Adams County has an estimated population of 30,000 and is in south central Nebraska. The locations of Adams County and Hastinqs are shown by Fiqure 1. The subsite is a part of an industrial enterprise zone which contains industrial properties situated alonq the Burlinqton- Northern railroad riqht-of-way. These properties formerly owned by the Morrison-Quirk Grain Corporation, were used for qrain storaqe. However, one major qroup of buildings was converted to manufacturing use in 1968. These buildinqs adjoin the current grain elevator properties on the south and are occupied by Hastings Irrigation Pipe Company. Residential properties are located immediately northwest of the FAR-MAR-CO subsite. Aqricultural lands are located east of the site. Other industrial properties are adjacent to the subsitei however, no significant levels of contamination have been found on the other properties. Therefore, this remedial action will' occur onsite. The Burlinqton-Northern railroad right-of-way divides the former Morrison-Quirk Grain Corporation properties into two parcels. The right-of-way is a major east-west transportation route. Railroad spur tracks used for loading grain into railcars are also present at the subsite. The contamination found in soils at the FAR-MAR-CO subsite is believed to be a result of accidental spills and may be the direct result of a 1959 qrain dust explosion. This explosion damaged the tank and fumiqation system resultinq in loss of 997 qallons of fumigant. Volatile chemicals have miqrated downward, entered the ground water and traveled in the ground water some distance downgradient from the subsite. Wells that are part of CMS, Inc., public supply system are located east and downgradient of the subsite. SITE HISTORY In 1983, the Nebraska Department of Health sampled the CMS, Inc. public water supply system east of Hastings in response to citizen complaints of taste and color in the drinking water. That same year, the Nebraska Department of Health (NDOH) and the Nebraska Department of Environmental Control (NDEC) began investigatinq wide-spread ground water contamination in the Hastinqs area. ------- , -':' ~. aT I 0" 0" _0"'0- \i . -+0 ~ i ! ---- .--+... S o ... i . 0 . i- . . --.....- Site HASTINGS, Location Map NEBRASKA o 5 Miles tN Hss tings . 116::> I 0- Nebraska Figure 1 <:;~a/~ -.. --. -- ......u -.- .~. ~-~_.~ ------- J . curing this investigation, samples collected from the CMS Well 24 indicated that the well was contaminated with several compounds, primarily chlorinated solvents, including carbon tetrachloride (CC14 and low levels of trichloroethene (TCE). eMS Well 24 is. located approximately one mile east of the FAR-MAR-CO subsite. According to field investigations conducted by EPA, CMS Well 24 is hydrologically downgradient from the subsite. -. -.-.. In 1984, the state of Nebraska collected additional samples from CMS, Inc. supply wells and from private wells in the area. In late 1984, EPA laboratories confirmed findings by the State of Nebraska Laboratory that ethylene dibromide (EDB) was also present in samples taken from CMS Well 24. In an effort to define the extent of contamination in Hastings, Nebraska, EPA began sampling wells in 1985. Field investigations, which included soil-gas sampling, soil sampling and the installation of one monitoring well were conducted in 1986 to identify and characterize suspected sources of contamination in the Hastings area. As a result of the analysis of data collected in 1985 and 1986, EPA identified this subsite as the area from which CC14 and EDB found in CMS Well 24 emanated. Results of soil-gas sampling are shown in Figure 2.. High levels of CC14 were found in the soil-gas north of the original grain elevator structure within approximately 10 feet of a large liquid fumigant bulk storage tank. This same area also has significant levels of EDB contamination in. the soils. The EDB contaminated zone is small, indicating that its presence was probably caused by an accidental spill. Morrison-Quirk Grain corporation used CC14 at the site during the 1950's and 1960's. The liquid fumigant bulk storage tank was placed at the present location after a grain dust explosion occurred in 1959. Morrison-Quirk Grain Corporation sold the major part of the properties to FAR-MAR-CO Inc. in 1975. Farmland Industries; Inc., the current owner of the FAR-MAR- CO subsite, acquired the property through a merger with FAR-MAR- CO, Inc. in 1976. The present owners have used CC14 (80-20 mixture) to fumigate grain at the site. EDB has been found in the ground water, soil-gas and soil onsite. Prior to its being banned by EPA in 1983, EDB was commonly used to fumigate stored grain. EPA's investigations at the FAR-MAR-CO subsite were documented in a report prepared by REM II in 1987. Sampling of an irrigation well (I-46) located at the Central Community College has shown CC14 and EDB contamination. This well is located approximately 1 1/2 miles southeast and downgradient of the FAR-MAR-CO subsite. ------- LEGEND I \ (f) ~ EPA MONITORING WELL [ (f) « fI)~ CONTOURS REPRESENT APPROXIMATE 0- L AREAS OF EQUAL CCI4 <"'9/1) >- \ m CONCENTRA 110N IN SOIL' 'GAS. [ 1 r I <0 t >-= N 3: 0 100 200 300FEET I C--=:J ~ BUAUNGTON NORtHERN R.R. ~ MW-8 HASTINGS GROUND WATER CONTAMINATION SITE HASTINGS, NEBRASKA D FAR-MAR-CO AREA SUBSITE CCI4 CONCENTRATIONS IN SOIL GAS Figure 2 o HWY. U. S. 6 ------- 5 EPA conducted soil samplinq and soil-qas samplinq in 1987 and 1988 to better define the extent of contamination at the subsite and to refine preliminary desiqn data for the source control remedy. An Enaineerina Evaluations ADS Cost ~ (EE/CA) was released by EPA for public comment on February 3, 1988. The oriqinal-pUb~ic comment period for this subsite was extended until April 30, 1988. EPA has prepared a responsiveness summary which addresses the comments received. EPA has no information indicatinq qeneration of hazardous substances resultinq from qrain storaqe operations at the site. Therefore, no onsite burial of wastes is suspected. Public access to the subsite is not restricted at this time: however, the owner of the subsite has been advised by EPA that precautions should be taken durinq maintenance activities which could disturb the contaminated soils. ENFORCEMENT HISTORY In September 1985, qeneral notice letters were issued to potentially responsible parties (PRPs) connected with the Hastings Ground Water contamination NPL site. The first PRP meetinq was held in October 1985 at which time the PRPs were asked to perform the needed RI/FS studies. No proposals to undertake the RI/FS were made by the PRPs. In December 1986, EPA notified Farmland Industries, Inc. and Morrison-Quirk Grain Corporation of their potential liability at the FAR-MAR-CO subsite. In January 1987, a PRP meeting was held to review EPA's findings to date. Farmland Industries and Morrison-Quirk Grain Corporation were asked to undertake the next phase of investiqations. Neither party made an offer. Durinq meetinqs held with the PRPs in 1987, EPA requested that the needed removal actions be done by the PRPs. EPA issued special notice letters on November 5, 1987 to Farmland Industries and Morrison-Quirk Grain Corporation. The PRPs subsequently received draft administrative orders on consent in March 1988 which included source control and ground water remediation. The PRPs responded to EPA on April 13, 1988, with an offer to participate in a pilot study. of soil vapor extraction. On June 8, June 28 and July 22, 1988, EPA met with PRPs to discuss pilot scale testing for source control. COMMUNITY RELATIONS Community relations activities for the Hastings Ground Water Contamination site were initiated by the EPA in 1984 with the development of a Community Relations Plan. Since December 1984, EPA has conducted meetings periodically with Hastings city officials to update them regarding site work and findings. ------- b A public meeting was held in November 1985 to present site information and plans for the RI/FS. In February 1987, the Report ot Investiqation for the FAR-MAR-CO subsite was placed in the public information repository and was mailed to all interested parties. EPA-:Req!on V1:I Public Affairs Office has mailed Fact Sheets periodically to parties who have expressed an interest in the Hastings Ground Water contamination site. This office also responds to inquiries regarding this site made by news media and members of the public. An Engineering Evaluation/Cost Analysis was released for public comment in February 1988. This document set forth EPA's proposed cleanup plans for the FAR-MAR-CO subsite. A public meetinq findings and the need environmental impacts were voiced. was held on March 5, 1988, to discuss EPA's for site cleanup. Concerns regarding the of contamination and the cost of cleanup Several issues were raised by residents during the course of the remedial investigation, as well as at the most recent public meeting. A responsiveness summary, which addresses the comments and questions raised, is attached to this ROD. SITE CHARACTERISTICS Investigations conducted by EPA during 1985 and 1986 are documented by Report g! Investiaations. Hastinas Ground Water contamination. FAR-MAR-CO Subsite, dated February 24, 1987. Data presented by this report show that the highest levels of CC14 contamination in the soils and soil-gas occur in the area defined by the soil-gas contours illustrated in Figure 2. Data presented in this report also show high levels of CC14 in ground water at the subsite. EPA has published a maximum contaminant level (MCL) of 5 ppb for CC14. Significant levels of EDB contamination are a1so present in monitorinq well MW-8 at the subsite and in downgradient water supply wells. The above-referen~ud report a180 contains an assessment of potential risks to human health from. the contaminated ground water. The amount of CC14 and EDB contamination present in the ground water and in 801ls above the water table necessitate some response action at the FAR-MAR-CO subsite to reduce the potential carcinogenic risks to human health. The analytical risk assessment can FAR-MAR-OO subsite. below. results from the subsite investigation and th~ be found in the referenced report for the A brief summary of the results is presented ------- 7 Ground Water contamination Ground water at the subsite is found at a depth of approximately 120 feet. The subsite is underlain by a sand and gravel aquifer, having a saturated zone approximately 100 feet deep. ~~s_Aquifer is the sole source of drinking water and is used extensively tor industrial and irrigation purposes. The lateral flow in the aquifer was found to be generally eastward from the subsite. However, the potentiometric surface map of the area indicates the direction of flow east of the subsite is influenced by the regional east-southeast gradient. Ground water samples were collected from the monitoring well located at the subsite and from monitoring wells located , upqradient from the subsite. The highest detected contaminant concentrations were seen at well MW-8 as shown in Table 1-1. contamination with CC14 and EDB is seen in the shallow portion of the aquifer (120-140ft.) at the subsite. Private irrigation wells located 2,000 - 6,000 feet downgradient from the subsite have shown CC14 and EDB contamination. One domestic well (D-8) is also contam1nated with EDB. The sand and gravel aquifer is underlain by thick deposits of clay and shale. Depths to the clay/shale formations range from 200-220 feet. Historical water quality data for municipal water supply well CMS 24 and private wells are given in Tables 1-2 and 1-3. Soil contamination soil sampling and soil-gas sampling were performed in 1986. This sampling shows high levels of contamination in the soil-gas. Analytical data from the soils show localized areas of contamination. Figure 3 shows the proposed response area where the highest levels of CC14 in soil-gas have been detected. Soil- gas sampling was conducted in 1987-88 in order to better define zones with the highest concentration of volatiles in the soils. The remedy selected in this document will mitigate future releases to the ground water by removing the high levels of CC14 and EDB from the unsaturated zone above the ground water.~ As shown in Table 2, there is a significant threat to public health for the EDB-contaminated zone. This increased risk could occur as a' result of direct contact with the EDB-contaminated4 soils. The Total Incremental Lifetime Cancer Risk of 9 x 10- corresponds to nine cancers in a population of 10,000. The CC14 and PCE found in soils at the subsite do not contribute to this risk estimate for direct contact. ~ Subsequent to publication of the EE/CA, data became available to EPA, which indicated high levels of CC14 and EDB in the sand materials underlying the silt. This information was discussed at the public meeting on March 5, and reviewed with the PRPs at a meeting on April 13, 19~8. 1988, ------- Table 1-1 Range of Concentrations of Volatile Organic Compounds in Ground Water East of Hastings, Nebraska, 1985 - 1987. Concentrations (ug/l) -. -- Paramaters OW-2s OW-2d MW-8 Trichloroethylene NO - 13 NO - 92 NO - 21 Tetrachloroethylene NO NO NO 1,1 Oichloroethene NO NO NO Trans-1,2- NO NO NO Oichloroethene 1,1,1 Trichloroethane NO NO ND Carbon Tetrachloride ND ND 570 - 1300 Ethylene Dibromide ND ND ND - 8 -------------------------------- Notes Data were obtained from the REM II Ground Water Investigation Report for Hastings Ground Water Contamination, May 7, 1987, the REM II Report of Investigation for Colorado Avenue Sub site , February 24, 1987, and quarterly ground water sampling data for April 1987. OW-2s and OW-2d are located upgradient of the FAR-MAR-CO subsite. MW-8 is located at the FAR-MAR-CO subsite. Key: ND - not detected s - shallow well (120-140 feet) d - deep well (approximately 170-180 feet) 8 ~ .- -----.--.-- ""'---- ---- ------- . Table 1-2 Range of Concentrations of Volatile Organic Compounds in Ground Water East of Hastings, Nebraska, 1983 - 1984 _. -- Concentrations (ug/l) Paramaters 1-49 J2:i CMS-24 I-46 Trichloroethylene NS 607 - 764 2.3 - 2.4 NS (TCE) Tetrachloroethylene HS HD - 3.8 HD NS (PCE) 1,1 Dichloroethene NS ND ND NS Trans-1,2- NS 4 - 15 ND NS Dichloroethene 1,1,1 Trichloroethane NS NO NO NS (TCA) Carbon Tetrachloride NS NO 20 - 22.6 NS Ethylene Dibromide NS NS . NS ---------------------------- Notes 1983 and 1984 analyses were reported by state of Nebraska Data were obtained from the state of Nebraska, Department of Health for 1983. No 1984 data found for 0-8 and CMS-24 wells. Key: NS - well not sampled by state ND - not detected * - Sampling of the CMS, Inc., distribution system by NDOH in 1984 revealed EDB contamination in the range of 0.62 - 1.7 ug/l. CMS well 24 was the only supply well in use at that time. 9 ------- Table 1-3 Ranqe of Concentrations of Volatile Orqanic Compounds in Ground Water East of Hastinqs, Nebraska, 1985 - 1987. -. ---- Concentrations (uq/l) Paramaters 1-49 45.0 - 69 Q:i CMS-24 ND - 7 1-46 42 - 180J Trichloroethylene (TCE) 182 - 1200 Tetrachloroethylene (PCE) ND - 1.8 ND - 6.3 ND ND - 2J 1,1 Dichloroethene 1.0 - 5(J) ND ND - 1.5 ND - . 1 ND Trans-1, 2- Dichloroethene ND ND ND 1,1,1 Trichloroethane (TCA) ND - 7(J) ND - 8 ND - .5 ND Carbon Tetrachloride Ethylene Dibromide 25 - 45 ND - 4.4 1 - 22 ND - 4 - - 3.2 - 6.8 ND - .5 ND - .32 ND - 0 04~), ---------------------------- Notes Ground water data presented here are for purposes of problem definition. Well owners have been advised that water is not suitable for drinkinq. Data were obtained from the REM II Ground Water Investiqation Report, Hastinqs Ground Water Contamination, May 7, 1987, and quarterly qround water samplinq conducted in July 1987. Above analyses were reported by EPA Labs and EPA Contract Labs Key: NO - not detected J - Compound was qualitatively meet all quality assurance only an estimated value. identified; but failed to criteria and therefore is 10 ------- { 1 J ( - ( i . "U 1 1 (/) (/) « a.. >- m U) N , ! I. l? . >- 3= I o 100 200 300FEET C8::J ] - MW-8 o F AR-MAR-CO SUB SITE . EAST ,OF HASTINGS, NE. D D D RESPONSE AREA MAP Figure 3 o HWY. u.s. 6 ------- -. --- TABLE 2 EXPOSURE TO CARCINOGENIC RISKS ASSOCIATED WITH DIRECT CONTACT OF WORKERS WITH SOILS FAR-MAR-CO SUBSITE Maximum Lifetime Carcinogenic Concen- Averaqe Potency Incremental tration Daily Exposure Factor Lifetime Chemical (uq/kq), (mq/kq/day) (mq/kq/day)-1 Cancer Riska Carbon ~etrachloride 390 3.6X10-7 1.3X10-1 SX10-S(B] Ethylene dibromideb 12,400 2.3x10-S 4.1X10-1 9X10-4(B] Tetrachloroethene 1,200 1.1X10-6 S.1x10-2 6X10-S(B] Overall 9xlO-4 a. [B2) refers to EPA's carcinoqen classification scheme ranking these compounds as probable human carcinoqens on the basis of animal data. b. Analyses of surface soils (0-2 feet) at the same location detected EDB at a concentration of 9,420 uq/kq.4 This corresponds to an Incremental Lifetime Cancer Risk of 7X10-. Subsequent samplinq has shown levels hiqher than 12,400 uq/kq at a depth of 1-3 feet. Source: Table 3-4, Report of Investiqation, Hastinqs Ground Water contamination Site, FAR-MAR-CO Subsite, REM II, February 24, 1987. - - .---- I ~. --- -- ------- .J The carcinogenic risks are theoretical quantifications and are reported as excess lifetime cancer risks. Excess lifetime cancer risk is defined as the incremental increase in the probability of qettinq cancer compared tg the probability if no exposure occurred. For example, a lxlO- excess lifetime cancer risk represents an exposure that could result in one extra cancer case per ~illion people exposed. RISK ASSESSMENT The primary potential human health impacts at the FAR-MAR-CO subsite are the exposure of re.idents to contaminated ground water and exposure of worker. to contaminated 80ils. In order to evaluate this public health impact, a risk assessment, which evaluates risks as a result of the exposure, was conducted. The risk assessment addressed the health effects associated with ingestion of contaminated ground water and incidental direct contact to the contaminated soils. This assessment provides a quantitative estimate of risk levels under existing conditions, that is, an estimate of risk levels in the absence of remedial action. This serves as a baseline against which the need for remedial action is evaluated. The risk assessment included calculations of the human dosage for contaminants in ground water. Potential exposure pathways to humans from the use of contaminated ground water include: Ingestion of ground water Inhalation of volatile chemicals released during water use Direct dermal contact with contaminated water l Persons potentially at risk of exposure to the contaminants in ground water include users of private and industrial wells downgradient from the subsite and customers who depend on the CMS, Inc. public water supply east of Hastings. This includes a11 employees at the Hastings East Industrial Park, all residents of the u.S. Air Force housing located at the Hastings East Industrial Park and all employees and students at the Hastings Central Community College Campus. Future users of the ground water would include communities located east of Hastings. To characterize risk at a site, indicator chemicals are first identified. Factors considered in identifyinq these chemicals include: maximum concentrations of contaminants at the subsite and their comparison to standards, presence of contaminants in qround water samples collected downgradient from the subsite, and carcinogenicity of contaminants. These chemicals were ultimately selected and are listed in Table 2 and Table 3. EDB and CCl4 are considered the main contaminants of concern based on the above factors. Both are highly persistent in the environment and are no longer used for grain fumigation. EDB and CC14 are c~assified as probable human carcinogens. --~-- ------- ~it _. -.-... TABLE 3 CHRONIC DAILY INTAKE OF CARCINOGENIC CONTAMINANTS PRESENT IN GROUND WATER AND CALCULATION OF INCREMENTAL LIFETIME CANCER RISK FAR-MAR-CO SUBSITE Maximum Lifetime Carcinoqenic Concen- Average Potency Incremental tration Daily Exposure Factor Lifetime Chemical (ug/kg) (mg/kg/day) (mg/kg/day)-1 Cancer Riskc Carbon tetrachloride 1200 3.4X10-2 1.3x10-1 4X10-3[B] Ethylene dibromide 6.8 1.9x10-4 41 8X10-3[B] Overall L 1XIO-2 a. [B2] refers to EPA's carcinogen classification scheme ranking these compounds as probable human carcinogens on the basis of animal data. NOTE: Calculations were made utilizing the highest contaminant concentrations observed (well MW-8) based on available data in 1986. More recent ground water sampling of well MW-8 at the sUbsite has shown higher levels present for both contaminants. Source: Table 3-8, Report of Investigation, Hastings Ground Water Contamination Site, FAR-MAR-CO SUbsite, REM II, February 24, 1987. ------- ~- . The potential human health impact of the remedy has been investiqated. Calculations based on air dispersion modelinq and estimates of emissions have been presented in the EE/CA. The results of these calculations show the need for air monitorinq durinq cleanup. actions. As explained in the EE/CA, air emissions controls will be used if needed. The Aqency will request an opinion from the Aqency for Toxic Substances and Disease Reqistry (ATSDR) ~~~~dinq proposed ambient air emission levels. Because the incremental cancer risk associated with direct contact to EDB-contaminated soils approximates one in one thousand, it was determined that the surficial soils do pose an imminent health threat to the workers at the subsite. . I SCOPE Ql OPERABLE UNIT This response action is an initial source control operable unit and is consistent with section 300.68(c) of the National Oil and Hazardous Substances Pollution Continqency Plan (NCP). This initial source control operable unit is beinq implemented to' protect public health and the environment by qontro11inq the miqration of contaminants from the soils to the qround water. The operable unit addresses known areas of contamination in the sands and silts which overlie the aquifer. . The miqration of contaminants from the soils into the aquifer is one of the major concerns posed by the site. This operable unit was initiated to deal with these concerns and is further described in the EE/CA document which was released for public comment. The operable unit is fully consistent with all future site work, inc1udinq the onqoinq qround water investiqations. In addition, it is believed that the remedy will reduce overall costs of cleanup actions needed at this site. The pilot study will provide information to more accurately determine the cost of an SVE system for the recovery and treatment of volatile chemicals and further information reqardinq the feasibility of removal of EDB from the upper 30 feet of soils at the FAR-MAR-CO subsite. l,l,l-trichloroethane (TCA) was found in surface soils at the southern boundary of the Farmland Industries property. This chemical is not classified as a carcinogen. As. a part of the risk assessment, . analytical data were reviewed for noncarcinogenic health etfects. Noncarcinogenic risks are determined by comparinq potential doses of contaminants received by site visitors to contaminant specific.reterence doses. The reference dose is an estimate of an exposure level that would not be expected to cause adverse effects when exposure occurs. This analysis shows an insiqnificant health risk from direct contact to the TCA-contaminated soils; however, cleanup action may be warranted to protect qround water. The TCA spill area is ------- _...' small and is located about 200 feet from the EDB-spill. The TCA contamination is not being addressed in this Record of Decision since the most cost-effective cleanup action has not been determined. EVALUATION Q[ ALTERNATIVES Remedial alternatives for the FAR-MAR-CO subsite have been developed. ~order to aeet the objectives of the Comprehensive Environmental Response, Compensation and Liability Act of 1980, as amended (CERCLA): and the NCP, 40 CFR Section 300.68. The process used to evaluate alternatives for this subsite is discussed in the EE/CA and is addressed briefly here. The first step in the evaluation of alternatives was to investigate technologies and determine which technologies may be both feasible and suitable for the FAR-MAR-CO subsite. The technologies were screened, based on technical feasibility, subsite conditions, environmental/public health protectiveness and regulatory requirements. Table 4 lists the technologies that were considered in the screening process and whether or not the technologies were considered for further evaluation. Based on this initial screening, response action alternatives were identified for development and evaluation of their ability to meet environmental laws and standards. The viable alternatives were then developed to permit relative cost comparisons of the technically feasible alternatives. The results of this evaluation were that four response alternatives were identified in addition to the NO ACTION alternative. , section 121(d) of CERCLA, as amended by the Superfund Amendments and Reauthorization Act of 1986 (SARA), requires that remedial actions comply with applicable or relevant and appropriate requirements or standards (ARARs) under Fe~eral and State environmental laws. EPA's findings with regard to protectiveness are shown in Table 5. Also shown in this table is the ability of the five source control alternatives to meet major regulatory requirements. I . Delay of the source control implementat~on would increase the total response action costs for this subsite because costs associated with recovery and treatment of the contaminated ground water are significantly higher. The selected remedy will be cost-effective because further contamination of the ground water will be averted. Recovery and treatment of the hazardous substances in the soils and soil-gas incorporates technologies that are proven and easily adapted to the FAR-MAR-Co subsite. SUMMARY Q[ ALTERNATIVES CERCLA, as amended, and the National Contingency Plan require that each alternative developed, including the no-action <.---~-c ------- ." TABLE 4 SCREENING OF POTENTIAL RESPONSE TECHNOLOGIES FOR CONTAMINATED SOILS FAR-MAR-CO SUBSITE -- ---- Screening Result Technoloqy Potentially Applicable Not Developed Excavation X Incineration X Flushing (with water) X Biodegradation X Composting 1. X -- -- - .-.-- ---.. In situ soil vapor extraction X In situ air stripping X In situ stream stripping. X Thermal processing X Capping X -. - ~ -- ------- 18 TABLE 5 Al ternative-- Summary of Alternatives Evaluation for Source Control Response Actions Ability to Meet Major Statutory & Requlatory Requirements. Is Response Protective No Action Soil Vapor Extraction No No Yes Yes Excavation with Onsite Treatment Yes Yes.. (Partial) Excavation with Offsite Treatment Yes Yes.. (Partial) Limited Excavation Treatment Plus Soil Vapor Extraction with Yes Yes 1.. ---.. .---.-- . The following potential ARARs have been identified and evaluated for remedial alternatives in this Record of Decision. Federal laws are shown with the corresponding state requlations. . Federal Resource Conservation and Recovery Act state Requlations, Title 128, Title 132 . Federal Safe Drinking Water Act State Requlations, Title 118, Title 178 . Federal Clean Water Act . state Requlation, Title 117 . Federal Clean Air Act State Regulation, Title 129 .. Sand material below silt-soils would not be treated, therefore, contaminants would remain below depth of excavation. . ---~ .._--_.~ . ------- 19 alternative, must be evaluated with respect to two major criteria -- protection ~f human health and the environment and compliance with applicable laws and regulations. Seven additional criteria are considered as a means to compare the alternatives. These include: -- ---- Long-term effectiveness Reduction of toxicity, mobility Short-term effectiveness Impl.mentability Cost State acceptance Community acceptance Each alternative must be evaluated for the degree of onsite and ottsite protection required (and thus to be provided) by the actions involved, as part of the overall effectiveness. - or volume The follQwing summary will focus on significant evaluation criteria as they relate to the alternatives developed for the FAR-MAR-CO subsite. No-Action Alternative The Agency has evaluated the no-action alternative for source control. Because hazard~us substances are known to exist in the soils above the aquifer, the concept of a no-action alternative is not protective. Moreover, this alternative does not comply with cleanup objectives including protection of the . drinking water aquifer for future use. Monitoring of downgradient water quality would help identify wells to be closed, but would 'not prevent continued migration and would not assure availability of alternate water supplies to users. Based on downqradient water quality and the hiqh levels of contamination at the FAR-MAR-CO subsite, the no-action alternative would not reduce migration of contaminants and may permit the level 'of risk to increase due to the amount of contamination in the soils. Regarding other long-term aspects of the no-action alternative, long-term reliability of monitoring would decrease with the passage of time and with distance from the site. There would be no reduction of mobility, toxicity or volume; therefore, no action would create the hiqhest likelihood of future exposure to hazardous substances being released to the environment. ' Under the 1986 amendments to CERCLA, should a remedial action result in hazardous substances, pollutants or contaminants remaining at a site, the remedial action taken must be reviewed within five years to evaluate if the actions taken are protective of public health and the environment. Potential remedial action costs would thus be maximized, since all the contaminants present might have to be remediated as a result of this review. Natural ------- tJ.~ attenuation of contamination is the only process that could reduce such costs, but due to the toxicity and concentrations of the wastes present, this alternative would not be protective. In situ soil Vapor Extraction This alternative involves treatinq contaminated soils in- place without excavation. This alternative will provide permanent removal and destruction of contaminants and, thereby, achieve a reduction in mobility, toxicity and volume. The need for direct action was stressed in public comments submitted to the Aqency. This alternative is acceptable to the state of Nebraska and the co..unity. In a vapor extraction system, VOCs are removed from soil by applyinq a vacuum and usinq a conventional industrial blower and standard valvinq, pipinq and instrumentation. Vacuum extraction has been used successfully in full-scale operations for removinq many types of VOCs in soils ranqinq from fine-qrained silts to coarse~qrained sand and qravels. The extracted vapor may have to be treated by a vapor phase activated carbon system if siqnificant air emissions result from implementation of this response alternative. This alternative was retained for cost evaluation. Excavation ADd Onsite Incineration This alternative' employs soil remediation and air treatment technoloqies that have been fully demonstrated to be effective. Incineration followinq .soils excavation will permanently destroy orqanic compounds present at the FAR-MAR-CO subsite. This alternative would comply with requirements of 1986 amendments to CERCLA to reduce mObil,ity, toxicity or volume. This alternative would require air quality monitorinq and other precautions to minimize miqration of air-borne contaminants from the subsite. The air that will be emitted from the incinerator stack may be subject to regulations under the Resource Conservation and Recovery ~ct. This alternative would address contaminated soils only to the feasible limit of excavation depth. Therefore, additional soil remediation measures would likely be needed to achieve objectives of ainimizinq further miqration of contaminants to the qround water. This alternative was retained for cost evaluation to provide cost comparisons to other response action alternatives. Excavation ADd Offsite Incineration In terms of lonq-term public health and environmental protection and reliability, this alternative is similar to the alternative described above (involvinq onsite incineration). Under this alternative, the excavated 80il will be transported offsite for incineration treatment at a RCRA-permitted facility, -~- ~._. -- ------- 21 . which will require continqency planninq in the event of a hiqhway accident. Air quality monitorinq and other precautions may also be required durinq soil excavation to minimize miqration of air borne contaminants from the subsite. Implementation of this alternative for treatment of all contaminated soils may not be cost-effective, but it could be used in combination with another alternative (such as vapor extraction) by excavatinq localized areas of hiqh contamination and incineratinq this soil offsite. This alternative was retained for cost evaluation to provide cost comparisons to other response action alternatives. ~ 2f Excavation And Incineration with In situ Soil VaDor Extraction ADd Treatment This alternative involves excavatinq localized areas where hiqh concentrations of volatiles are present in soils and subsequently incineratinq these soils onsite. The remaininq soils would be treated by in' situ vapor extraction (SVE), and the VOC air emissions treated by vapor phase carbon adsorption if emissions exceed state air emission requlations or result in siqnificant increased risk to human health. The air that would be .emitted from the incinerator stack may be subject to requlations under the Resource Conservation and Recovery Act, and the EPA would review the emissions control equipment to assure that air emissions do not have an adverse effect on public health. - This alterpati ve may be' 'appropriate due to the fact that the hiqhest levels of contamination are found in the upper 30 feet of the soils. within the upper 30 feet of soil, the most contam- inated section is the upper 5 feet. Limited excavation is considered feasible for implementation at the FAR-MAR-CO subsite. Under this alternative, the depth of excavation would be determined by analysis of site specific factors and would likely be between 5 and 25 feet. Unit costs (i.e., estimated cost per yard of soil) were determined to provide cost comparisons to other response action alternatives. An estimate for total capital costs of this alternative has been prepared. The EDB-contamination zone extendinq to a depth of 5 feet consists of approximately 150 cubic yards of 80il. The volume of EDB contaminated soil correspondinq to a depth of 30 feet is 400 yards. The estimated costs associated with excavation and onsite thermal treatment of 400 cubic yards of soil is $520,000. Therefore, the maximum total capital costs for this alternative could be as much as $520,000 plus $1,044,000 - $1,564,000. Cost comparison data are shown by Table 6. These estimates were prepared based upon enqineerinq judqments reqardinq implementability of the alternatives evaluated for abatement of direct contact threats and source control at the FAR-MAR-CO subsite. ------- .... SELECTED ALTERNATIVE Based on available data and analysis conducted to date, the U.S. BPA .elected soil vapor extraction as the .ost appropriate solution for .eeting the goals of the source control operable uni t at the PAR-MAR-CO subsi te. The characteristics of the selected remedy that are considered most important are: _.- _~e alternative provides protection to human health and the environment from the potential threats associated with no action. The alternative li.its .igration of contaminants to the aquifer at the site. The alternative provides for compliance with applicable laws and requlations. - The alternative is consistent with additional site actions and will be compatible with the final site remedy. The Regional Administrator retains the authority to make changes in the scope and nature of source control actions to be undertaken at this site. If new information or additional environmental data warrants a change, then the impacts of the suggested change will be reviewed to determine if any significant departure from the selected alternative does in fact exist. Cost impact of any propos~d changes will be taken into account. New information about the- subsite-- could alter the cost estimates shown in Table 6. Selection of the in situ vapor extraction technology is being made at this time; however, a pilot project is planned prior to full-scale implementation of soil vapor extraction. The pilot scale testing for an active gas extraction system will provide the following data: 1. 2. rate of gas withdrawal and air recharge. radius of influence and other information to design the final gas extraction well network. information to design the gas monitoring well network. 3. Pending successful completion of the pilot, the most cost- effective design will be prepared for the source control remedYe As a part of the initial action, the PRPs have agreed to construct a fence to restrict access to the EDB spill zone. This temporary aeasure will minimize potential health risk to employees and other site visitors. --.-.. - --- --~-~- --- ------- TABLE 6 COST COMPARISON OF RESPONSE ACTION ALTERNATIVES FOR CONTAMINATED SOILS FAR-MAR-CO SUBSITE ($ x 1,000) . Total (a) First Year unit Cost -. -- Alternative ~ Cost 2iK Cost 1IU tS/CUbi.& Yard) In situ vapor $1,044 $391 75 . extraction and treatment (c) Excavation and 20,354(d) 610 onsite incineration Excavation---and 22,116(d) 660 offsite incineration Excavation and incineration of hotspots in combination with in situ vapor --extraction and treatment 520(e) 1,300 (Excavation and onsite incineration) 600(e) 1,500 (Excavation and offsite incineration) + costs for in situ SVE Notes: (a) Estimate includes gas extraction system, air treatment system, engineering"design, construction management and other contingency costs. (b) Estimates include power costs, maintenance, labor, monitoring of air and soils and contingency costs. (c) A total present worth estimate for this alternative has been prepared. The estimated cost is $2,526,000 based on a five-year operatinq period, a 10 percent discount rate and projection of the first year O'M costs over the five-year operating period. (d) Estimates include all costs associated with site work for an estimated volume of 33,800 cubic yards of soil. (e) Estimates include all costs associated with site work for excavation and treatment of an estimated volume of 400 cubic yards of 80il. 23 ------- 24 temporary measure will minimize potential health risk to employees and other site visitors. . CT.R1N-up LEVEIS The initial source control operable unit is being implement:_cl-40r the purpose of controlling contaminant aigration, not restoration of the aquifer to drinking water standards. Therefore, no cleanup levels for the SVE process are being established at this time. The vapor extraction system will initially operate under controlled conditions to provide for collection and analysis of operational data. This data will be used to refine final design information and to establish ettectiveness of the vapor extraction system. Cleanup effectiveness will be evaluated based on volume of contaminants recovered trom the soils. In addition to 80il-gas monitoring, soil sampling will be required to demonstrate effectiveness of the cleanup. Review and decision-making regarding cleanup levels will be closely coordinated with the state of Nebraska. Air emissions will be monitored to assure concentrations of volatile chemicals which present a public health risk do not occur. As previously stated, recovery of volatiles by SVE will be less costly than treating large volumes of contaminated ground water at a future. date. Therefore, the volume of volatile contaminants recovered will be one measure of success of the selected remedy. Ground water monitoring is expected to show a decreased concentration of contaminated ground water migrating from the site. These monitoring data will be direct measures of success of the selected remedy. The anticipated result is that the duration of any long-term. actions will be decreased by this remedy. The Agency believes that the maximum contaminant levels established under authority of the Safe Drinking Water,Act are relevant and appropriate for ground water remedies. However, this initial operable unit does not provide for treatment of ground water at the FAR-MAR-CO subsite. section 121 of CERCLA, a. amended,. does provide for waiver of the requirement to attain MCLs where an interim remedy is to be selected. Air emissions will be monitored to assure no significant air emissions will be created by this remedy. OPERATION aim MAINTENANCE The recommended alternative requires a certain degree of annual operation and maintenance (O&M) activity to ensure proper operation of the system and compliance with environmental laws and regulations. The costs of O&M will depend on volume of contaminants recovered and the size of the completed vapor extraction system. An O&M plan will be developed during remedial ------- 1/..;) \; .. design after the initial phase of operation and testing of the system. A ground yater monitoring plan will also need to be developed and implemented to demonstrate reduced migration of contaminants in the ground water. This plan will be incorporated into the O&M plan. Farmland Industries and Morrison-Quirk Grain Corporation, the res~n.i:IIle parties, have been requested to assume responsibility for the O~. The EPA will assist the PRPs during transition. , STATUTORY PINDINGS The U.S. EPA and the State of Nebraska believe that this remedy will 8atisfy the statutory requirements for providing protection of human health and the environment, attaining applicable or relevant and appropriate requirements of other environmental statutes, will be cost-effective and will utilize permanent solutions for this operable unit and alternative treatment technoloqies or resource recovery technoloqies to the maximum extent practicable. SCHEDULE The following are the key milestones for implementatiort of the remedial action in the event that RD/RA negotiations are not successfu: Approve Remedial Action (execute ROD) Initiate Remedial Design Initiate Remedial Action Complete Remedial Design September 1988 September 1989 December 1989 April 1990 FUTURE ACTION Ground water monitoring wells located at the site will continue to be sampled and a technical approach for plume management will be developed. Agency decision-making regarding ground water treatment will be discussed with the State of Nebraska prior to preparation of a Record of Decision for ground water treatment. ------- |