United States Environmental Protec: .1 Agency Office of Emergency and Remedial Response EPA/ROD/R09-87/012 September 1987 SEPA Super jnd Enforc ?ment Decision Document: Litchfii Id Airport/Phoenix, AZ ------- TECHNICAL REPORT DATA 'rteau 'rtatt Inttmtnom on tut rtvtnt btfort EPA/ROD/R09-87/012 3 Reo"€Nr s Access.CN so 4. TITH ANOSUITITUI SUPERFUND RECORD OF"DECISION Litchfield, AZ Ficst Remedial Action 7 AUTMORIS) OATI ;' September 29, 1987 « MR0ORMING ORGANIZATION COOi • »f R0ORM1NG ORGANIZATION NO ». MR'ORMINO ORGANIZATION NAMI AND AOORISS 10. PROGRAM NO 11 CONTRACT/GRANT NO 12. SPONSORING AOiNCV NAM* AND AOOACSS U.S. Environmental Protection Agency 401 M Street, S.W. Washington, D.C. 20460 13. TVM O' RMORT ANQ MRlOO C0v6»eo Final ROD Report 14, SPONSORING AQINCV CQOf 800/00 19. SU^^LIMINTAAY NOTIS 14. AUTRACT The Litchfield/Phoenix-Goodyear Airport (PGA) site covers a total area of approximately 35 square miles and is located approximately 17 miles west of Phoenix, Arizona. The site is divided into a northern and a southern area by a ground water. divide running under the Yuma Road area. Section 16 (approximately 17 acres) lies in the southern area and includes the Loral Corporation facility (formerly owned by Goodyear Aerospace Corporation) and the Phoenix-Goodyear Airport (formerly owned by U.S. Navy), both being potential sources of VOC contamination. Ground water contaminant concentrations in Section 16 are at least 100 times greater than down gradient levels. Development by the City of Goodyear is planned for the area west, or downgradient, of Section 16. This development will include using the ground water resources currently threatened by contamination in Section 16. In 1981, the Arizona Department of Health Services discovered solvent and chromium contamination in the ground water within the PGA area. Additional sampling in 1982 and 1983 found 18 wells contaminated with TCE. The primary contaminants of concern include: TCE, VOCs and chromium. The selected interim remedial action for this site includes: ground water pump and treatment from the Subunit A aquifer of the entire Section 16 area by air stripping with reinjection of the stripped water back into the Subunit A aquifer; and Loral Corporation (See Attached Sheet) 17. KIV WOMOC AMO OOCUMflNT AMAl*SIS oucftirroMS b.lOINTI»ltM/OMN INOIO r(MM« C. COS-ATI F*!d/G«*jp Record of Decision Litchfield, AZ First Remedial Action Contaminated Media: gw Key contaminants: VOCs, TCE, chromium DISTRIBUTION STATIMINT 19. SECURITY CLASS ' nut Atpo'tl None 21 NO o 57 20. StCuRiTY CLASS .nut pi ft i IP* 1214-1 (*•»• 4-77) •n«yieu» IOITIQM .» O*«OW>T« ------- EPA/ROD/R09-87/012 Litchfield, AZ First Remedial Action 16. ABSTRACT (continued) and PGA will continue to pump ground water from Subunit B/C and treat with granular actived carbon. The estimated present worth cost for this selected remedy is $2,358,500 with O&M of $800,200. ------- DECLARATION FOR THE RECORD OF DECISION SITE Phoenix-Goodyear Airport (PGA) site, Section 16 Operable Unit, Goodyear, Arizona. PURPOSE This decision document represents the selected remedial action for the Section 16 Operable Unit at the PGA Superfund site (see Figure 1). This operable unit addresses groundwater contamination in the upper alluvial unit only in Section 16. Groundwater contamination beyond Section 16, as well as soil contamination, will be addressed in the final remedial action. This remedial action was developed in accordance with CERCLA, as amended by SARA, and the National Con- tingency Plan. The Arizona Department of Environmental Quality and Arizona Department of Water Resources have agreed to the selected remedy. BASIS This decision is based on the administrative record for the P<~\ site, which includes the Phase I Remedial Investigation a..d the Section 16 Operable Unit Feasibility Study. The attached index (Appendix A) identifies the items contained in the administrative record upon which the selection of the remedial action is based. DESCRIPTION The PGA site is located approximately 17 miles to the west of Phoenix, Arizona. The site is divided into a northern and a southern area by a groundwater divide running under the Yuma Road area. Section 16 lies in the southern area and includes the Loral Corporation facility (formerly owned by Goodyear Aerospace Corporation) and the Phoenix-Goodyear Airport (formerly owned by U.S. Navy), both being potential sources of volatile organic compound (VOC) contamination. Groundwater contaminant concentrations in Section 16 are at least 100 times greater than those of downgradient levels. Development by the City of Goodyear is planned for the area west, or downgradient, of Section 16. This development will include using the groundwater resources currently threatened by contamination in Section 16. As a result, the Section 16 Operable Unit was designed to address these high levels of groundwater contamination. An operable unit is a remedial action that is separated from the overall site cleanup RD/R52/021 ------- actions when it can be done expeditiously, is cost-effective, prevents contaminant migration, and is consistent with the final site remedy. To meet these objectives., the following remedial action has been chosen. The chosen alternative segregates the water in the upper alluvial unit into Subunit A, which is presently unsuitable for drinking water due to its high dissolved solids content, from the aquifers in Subunit B/C, which is a potential drinking water source. (Subunits B and C have been combined as Subunit B/C because, in this area, they are hydraulically connected.) The rationale for this operable unit is that it will stop contamination within Subunit A from spreading laterally, and it will prevent contamination from Subunit A to enter Subunit B/C via the casing of exist- ing wells in the area. Subunit B/C is planned for future use of the City of Goodyear in areas directly downgradient of the site. For Subunit A, until levels of contaminants are reduced to meet Applicable or Relevant and Appropriate Requirements (ARARs), water will be pumped from the entire Section 16 area, and air stripping will be used to reduce VOC contamination to meet federal and state standards for drinking water (see Table 1). The air stripping towers will be equipped with air emission controls in order to meet county requirements that all new air emission sources employ reasonably achievable control technology to reduce emissions, and as promulgated by the Superfund Amendment and Reauthori- zation Act (SARA), remedies should significantly and perma- -/ nently reduce the volume, toxieity, and mobility of the contaminants. At this time, aquifers in Subunit B/C are being pumped by Loral Corporation for industrial and drinking water purposes and by the Phoenix-Goodyear Airport for domestic supply. All water used for drinking is sent to a carbon adsorption system for treatment. This pumping system is helping to contain contaminant migration in a manner that is acceptable for this interim period until the final remedy is chosen. In addition, clusters of newly installed deep monitoring wells to the west of the airport will monitor Subunit B/C and detect any contaminant migration away from the source area. Therefore, no expedited remedial action is planned for Subunit B/C at this time. Pumping schedules for Loral Corporation and the airport will be designed to optimize production needs with control of the contaminant plume. The level of treatment will be in accordance with federal and state standards. Treated water from the Subunit A aqui- fer will be reinjected into that same aquifer to minimize the environmental impact of additional groundwater withdrawal, RD/R52/021 ------- Table 1 STATE AND FEDERAL APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS* (concentrations in ppb) AND OTHER CRITERIA Compound Trichloroethylene 1,1,1-Trichloroethane 1,1-Dichloroethylene Perchloroethylene Trans-1,2-dichloroethylene Carbon tetrachloride Chloroform Chromium Arsenic AWQC ADHS SDWA SDWA Proposed Proposed Drinking Water Action Treatment Plant MCL MCLG MCL MCLG Only Level Discharge Level 5 200 7 50 SO 0 200 7 0 70 0 120 50 5 200 1 3 0.5 5 200 7 3 70 5 0.5 50 Clean Water Act requirements will be determined during NPDES review. Source is not a byproduct of municipal water supply chlorination. NOTES: ADHS—Arizona Department of Health Services AWQC—Ambient Water Quality Criteria MCL Maximum Contaminant Level MCLG—Maximum Contaminant Level Goal SDWA—Safe Drinking Water Act DW—Drinking Water Sources: U.S. EPA 1986. Public Health Assessment Manual ADHS 1987. S. Eberhart RD/R56/057-4 ------- DECLARATION The selected remedy for this operable unit is protective of human health and the environment, meets federal and state requirements that are applicable or relevant and appropri- ate, and is cost-effective. This remedy satisfies the pref- erence for treatment that reduces toxicity, mobility, or volume as.a principal element. All permit requirements will be met during the implementation of this remedial action. It is determined that the remedy for this operable unit uses permanent solutions and alternative treatment technologies to the maximum extent practicable. The Arizona DEQ has concurred with the remedy presented on this document. Date h E. Ayresx" Regional Administrator Region IX RD/R52/021 ------- RECORD OF DECISION CONCURRENCE PAGE Site: Phoenix-Goodyear Airport, Goodyear, Arizona The attached Record of Decision package for the Phoenix- Goodyear Airport, Goodyear, Arizona, has been reviewed and I concur with the contents. Date flary Ann Muirhead Acting Deputy Regional Counsel Office of Regional Counsel ' U.S. Environmental Protection Agency, Region IX Dt Acting Director Toxics & Waste Management Division U.S. Environmental Protection Agency, Region IX S?% 1 Date Harry £eraydarian Director Water Management Division U.S. Environmental Protection Agency, Region IX Date/ / Date tfffurt/fssx Director Air Management Division U.S. Environmental Protection Agency, Region IX w. Murray, Jr. Assistant Regional Administ Office of Policy and Manageme U.S. Environmental Protection Agency, Region IX RD/R52/027 ------- CONTENTS Page Declaration for the Record of Decision 1 Site 1 Purpose 1 Basis 1 Description 1 Declaration 4 Record of Decision Concurrence Page 5 I. Site Description 1-1 II. Site History and Background II-l Site History II-l Site Characterization II-l Receptors II-2 Toxicity II-6 III. Enforcement History III-l IV. Community Relations History IV-J. V. Alternatives Evaluation . " V-l Listing of Alternatives V-l Screening of Alternatives V-3 Evaluation of Alternatives V-6 VI. Selected Remedy VI-1 Statutory Determinations VI-1 Description VI-3 Appendix A. Index of Administrative Record Appendix B. Responsiveness Summary TABLES Page 1 State and Federal Applicable or Relevant and 3 Appropriate Requirements and Other Criteria II-l Comparison of the Applicable or Relevant and II-3 Appropriate Requirements and Other Criteria to Groundwater Data: Summary as of August, 1986 II-2 Summary of Exposure Routes and Risks II-8 V-l Areal Extent of Pumping Alternatives V-4 ------- CONTENTS (continued) I i TABLES (continued) Page V-2 Screening of VOC Removal Technologies V-5 V-3 Summary of Screening of Water End Use V-6 Alternatives V-4 Cost Evaluation of Extraction and Monitoring V-8 Wells V-5 Costs for Subunit A—Remedial Action with V-10 Water Reinjection VI-1 - State and Federal Applicable or Relevant VI-2 and Appropriate Requirements and Other Criteria Follows Page Figures 1 Site Location Map i II-l Current Cross Section II-l View of Geology II-2 Groundwater Contamination Map, II-5 Subunits B/C II-3 Groundwater Contamination Map, II-5 Subunit A II-4 Exposure Pathway and Receptor Summary II-6 V-l Potential Remedial Alternatives, V-l Subunits A and B/C V-2 Selected Remedial Alternatives, V-6 Subunits A and B/C RD/R20/026 ------- I. SITE DESCRIPTION The Phoenix-Goodyear Airport (PGA) site covers a total area of about 35 square miles and is located about 17 miles due west of Phoenix, Arizona, in the western part of the Salt River Valley. The Section 16 Operable Unit covers about 750 acres and is located west of the City of Goodyear. The towns of Goodyear and Avondale border the site on the east- ern edge, occupying about 2 square miles. The remaining land is presently used primarily for agriculture. The gen- eral area had a combined population of about 30,000 people in 1985. The two major surface-water drainages within the area are the Gila River to the south and the Agua Fria River to the east. The Gila River flows perennially due to releases from treatment plants. The Agua Fria River is dry most of the year with occasional flows resulting from releases from dams, irrigation tailwaters, or treatment plants. The Agua Fria River drains south into the Gila River, which then flows to the west. Drinking water supplies, industrial water supplies, and irri- gation water come solely from groundwater that is pumped from the alluvial deposits of the western Salt River Valley ' underlying the entire area. Section 16 contains the Loral Corporation facility (formerly owned by Goodyear Aerospace Corporation) and the Phoenix- Goodyear Airport (formerly operated by the U.S. Navy), both of which have been identified as sources of contamination in the southern area of the PGA site. RD/R52/020 1-1 ------- II. SITE HISTORY AND BACKGROUND SITE HISTORY In 1981, the Arizona Department of Health Services discov- ered that groundwater in the PGA area was contaminated with solvents and chromium. Additional sampling of wells in 1982 and 1983 found 18 wells contaminated with trichloro- ethene (TCE). As a result, the EPA added the PGA site to the National Priorities List in September 1983. In 1984, EPA began a remedial investigation of the Litchfield Airport Area (presently known as the Phoenix-Goodyear Airport) to characterize the site, discover the extent of the contami- nation, and identify possible sources. Historical data indicate two primary contributors to the groundwater contamination in the Section 16 area: Goodyear Aerospace Corporation (GAC), currently owned by Loral Cor- poration, and activities carried out by the Navy at the Litchfield Park Naval Air Facility. Historical data on waste handling at GAC and PGA can be found in the Section 16 Operable Unit Feasibility Study. Sampling data for groundwater identified two major areas of contamination, a northern area and a southern area. Most of the contamination in the southern area of the site was iso- lated within Section 16. The Section 16 Operable Unit Feasi- bility Study was initiated in 1987 to identify remedial actions to contain further migration of contaminants and deterioration of the aquifer. Soil and soil gas sampling is currently being done to char- acterize soil contamination in Section 16. Soil and ground- water contamination will be addressed in the feasibility study for the entire site. SITE CHARACTERIZATION The site is located in a region having a climate character- ized by long, hot summers and short, mild winters. Relative humidity is low, particularly during early summer, and the rainfall averages about 7.1 inches per year. The average daily maximum temperature in July is 107°F, the average daily minimum temperature in January is 34°F, and the aver- age yearly temperature is 70°F. Groundwater is pumped from the alluvial deposits of the west- ern Salt River Valley. These deposits consist of the Upper Alluvial Unit, the Middle Fine-Grained Unit, and the Lower Conglomerate Unit, as shown in Figure II-l. The Upper Allu- vial Unit has been further subdivided into Subunit A, from the surface to about 120 feet deep; Subunit B, from about 120 to 240 feet deep; and Subunit C, from about 240 to 360 feet deep. Subunits B and C are hydraulically connected. RD/R52/020 II-l ------- GOODYEAR AEROSPACE CORP. FHOENIX-GOOOYEAR MUNICIPAL AIRPORT UNIOYNAMICS PHOENIX. INC. ;.„,.,.„„.. ,,w^i§iiiliii.,,. V;N"/'v.'.•-;!-•' •.. ' '•'-,''.'". .:••'., . \ . • ' :'. ,••'•*• ',,„• '."..'' ^^m^uyu^tmirS^^y^ FIGURE H-1 CURRENT CROSS-SECTION VIEW OF GEOLOGY EPA - JUNE 1987 1000 FT ------- Most wells in the area pump water from a zone between 100 and 600 feet deep. Depth to the water table has varied in the past, but recently has been measured between 40 and 100 feet below the ground surface. Groundwater flows in the PGA area are divided at approximately Yuma Road. The north- ern area has groundwater flows to the northwest, and the southern area, including Section 16, has groundwater flows to the southwest. In addition to the TCE and chromium identified earlier, sev- eral other compounds were found to contaminate the ground- water. Among these are perchloroethene (PCE), 1,1-dichloro- ethene (1-1 DCE), chloroform, carbon tetrachloride, and arsenic. Table II-l identifies the wells tested, concentra- tions detected, and the applicable federal or state standards or other criteria. Not all wells tested in the PGA area are listed in this table. The wells noted in this table were selected as representative samples of groundwater quality. Figures II-2 and II-3 show well locations and average con- centrations of contaminants found in the Section 16 Upper Alluvial Unit (Subunit A and Subunit B/C). The highest con- tamination levels are found in the Subunit A, which is linked to the Subunit B/C by conduit wells. RECEPTORS ENVIRONMENT The environment of the PGA area is typical of the Phoenix/ Southwest region. Within the PGA site, there are no unique habitats nor any threatened or endangered species. Native vegetation at the site is sparse. However, located immedi- ately south of the site, the lower Gila River represents the important riparian habitat in southwestern Arizona. Species that inhabit or migrate through the area include four federally listed endangered species: brown pelican (Pelecanus occidentalis), Yuma clapper rail (Rallus long- irostris yumanensis), peregrine falcon (Falco peregrinus), and the bald eagle (Haliaeetus leucocephalus). The PGA area/ particularly near the Gila River, supports viable hunting populations of mourning dove, white-winged dove, Gambel's quail, and various waterfowl. The area is especially popular for dove hunting and is known to support one of the largest breeding dove colonies in the Southwest. POPULATION In 1985, the combined population of the Goodyear and Avon- dale area was 30,000. The City of Goodyear has stated in its general plan that the city expects to grow at a rapid pace, exceeding 140,000 people within 20 years. RD/R52/020 II-2 ------- Table II-l COMPARISON OF THE APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS AND OTHER CRITERIA TO GROUNDWATER DATA: SUMMARY AS OF AUGUST, 1986 Well/Station ID Compound 16EMW-1 Trichloroethene 16EMW-2 1 , 1-Dlchloroethene Trichloroethene 16EMW-3 1,1-Dlchloroethene Trichloroethene Concentration (W/l) Maximum Average Maximum Average Maximum Average Maximum Average Maximum Average 1 1 9 <4 75 33 140 126 490 342 ARAR Exceeded MCL, MCL, MCL, MCL, MCL, MCL, MCL, MCL, .. AWQC AWQC AWQC AWQC AWQC AWQC AWQC AWQC (Hf*)a do" ) do"*) do" ) do"*) (10 ) do"*) (10 ) Other Criteria, Exceeded ADHS ADHS ADHS ADHS ADHS ADHS ADHS — action action action action action action action -. level level level level level level level Chromium (total) 16GMW-1 Trichloroethene Maximum 513 Average 472 Maximum 41.7 Average 34 MCL, AWQC (toxicity) MCL, AWQC (toxicity) MCL, AWQC do"*) MCL, AWQC (10 ) HA •-longer term/ 70 Kg,.lifetime HA--longer term/ 70 leg, lifetime ADHS action ADHS action level Chromium (total) Maximum 190 Average 150 MCL, AWQC (toxicity) MCL, AWQC (toxicity) HA—lifetime 16GMK-2 Chloroform Maximum 12.8 Average <4.6 AWQC (10) AWQC do" ) Carbon tetracblorlde Maximum 5.1 Average <2 MCL, AWQC (10) MCL, AWQC (10 ) ADHS action level ADHS action level Metaylene chloride Trichloroethene Maximum 13.2 Average <6.8 Maximum 24.9 Average 21 MCL, AWQC do"*) MCL, AWQC (10 ) ADHS action level ADHS action level ADHS action level ADHS action level 16GMW-3 1,1-Dlcbloroethene Chloroform Carbon tetrachloride Trichloroethene Maximum 12.8 Average 10.8 Maximum 9.3 Average 7.4 Maximum 5.1 Average 3.5 Maximum 155 Average 102.7 MCL, AWQC (10 ) MCL, AWQC (10 ) AWQC (10~*) AWQC do" ) MCL, AWQC (10~*) MCL, AWQC (10 ) MCL, AWQC do"*) MCL, AWQC (10) ADHS action level ADHS action level ADHS action IP ADHS action 1. ADHS action level ADHS action level RD/R52/020 II-3 ------- Table II-l (continued) Well/Station ID Compound Concentration (Uq/1) ARAB Exceeded Other Criteria Exceeded 16GMW-3 (continued) GAC #2 Chromium (total) Trichloroethene Maximum 1,340 MCL, AWQC (toxicity) Average 977 MCL, AWQC (toxicity) Maximum 16 Average 9.8 MCL, AWQC (10~*) MCL, AWQC (10 ) HA— longer term/ 10 kg & 70 kg, lifetime HA— • longer term/ 10 kg & 70 kg, lifetime ADHS action level ADHS action level GAC #3 GAC #4 Trichloroethene Chromium (total) Trichloroethene Maximum 110 Average 44 Maximum 170 Average 170 Maximum 45 Average 12 MCL, AWQC MCL, AWQC (10 ) MCL, AWQC (toxicity) MCL, AWQC do"*) MCL, AWQC (10 ) ADHS action level ADHS action level ADHS action level ADHS action level PLA #2 PLA #3 PLA #4 LPSC #4 LPSC #5 GF #27C GF #3B Trichloroethene 1,1-Dichloroethene Trichloroethene Arsenic Chloroform Chlorofora Chloroform Chloroform Maximum 36 Average 12.4 Maximum 6 Average 6 Maximum 310 Average 256 Maximum 96 Average 96 Maximum 1.4 Average 1.4 Maxlaum 5.1 Average 5.1 Maximum 3.2 Average 3.2 Maxlaum 0.8 Average 0.8 MCL, AWQC (lO) Mtt, AWQC (10 ) AWQC do"*) MCL, AWQC (10~6) MCL, AWQC (10 ) MCL, AWQC do"*) MCL, AWQC (10 ) AWQC do"*) AWQC do"*) AWQC do"*) AWQC do"6) ADHS action level ADHS action level ADHS action level ADHS action level HA—all categories RD/R52/020 II-4 ------- Table II-l (continued) Hell/Station ID Compound GF #4A Trichloroethene Concentration (UO./D Maximum 22 Average 10.5 ARAB Exceeded MCL, AWQC do"6) MCL, AWQC do"6) Other Criv=»ia Exceeded ADHS action level ADHS action level COTRIR Chloroform Trichloroethene Maximum 1 Average 0.77 Maximum 4.5 Average 3.3 AWQC (10) AHQC (10 ) MCL, AWQC (10"6) MCL, AWQC (10 ) DOMES? #3 Trichloroethene PHILLIPS Trichloroethene Maximum 2.3 Average 2.3 Maximum 12 Average 10.3 MCL MCL, AWQC (10~fj MCL, AWQC (10 ) ADHS action level ADHS action level PLUMB Trichloroethene Maximum 3 Average 3 MCL, AWQC do"6) R.WOOD1 Trichloroethene Maxima 3 Average 2.5 MCL MCL R.WOOD2 Trichloroethene Maximum 2 Average <1.3 MCL MCL R5.6W3.5 Trichloroethene Maximum 1.7 Average <1.1 MCL MCL RAYNER2 Trichloroethene Maximo 3 Average 3 MCL, AWQC RECMET2 Trichloroethene S.SMITH2 Trichloroethene Maxima 6 Average 4.4 Maxima 3 Average 2 MCL, AWQC (K) MCL, AWQC do" ) MCL, AWQC do"6) Ma ADHS action level SHAWVER Trichloroethene Maximum 3 Average 3 MCL, AWQC (10 ) a -6 "6 AWQC(10 )«the ambient water quality criteria that results in a 10 excess lifetime caacer risk. 5 ADHS action level»Arizona Department of Health Services action level. CAWQC (toxicity)-the ambient water quality criteria for human toxieity. dHA«Health advisory. MCL-Maxlaum contaminant level. MCL«Maxlaum contaminant level goal. RD/R52/020 II-5 ------- LEGEND 'WELL IDf ^x* TCE CONC M9/I PLA 3 ND- ^/ ' "" ^Cr CONC pg/l ^WELL LOCATION ND = NOT DETECTED NOTE: CONCENTRATIONS OF CONTAMINANTS ARE BASED ON DATA COLLECTED DURING MARCH AND JUNE 1987. CONCENTRATIONS ARE SINGLE EVENT. O1 600* 1000' FIGURE H-2 CROUNDWATER CONTAMINATION MAP SUBUNITS B/C PHOENIX-COODYEAR AIRPORT W63602.R4 ------- TCE CONC (ug/D r CONC (mg/l) ND EMW17 0.007 WELL LOCATION ND = NOT DETECTED NOTE: CONCENTRATIONS OF CONTAMINANTS ARE BASED ON DATA COLLECTED DURING 1906 AND 1987. CONCENTRATIONS ARE MEAN OR SINGLE EVENT. 600* 10001 FIGURE Jl-3 CROUNDWATER CONTAMINATION MAP SUBUNIT A PHOENIX-COODYEAR AIR W63602.RA . ------- All drinking water wells currently in use for municipal sup- ply meet applicable.federal and state health standards. However, future population growth will result in greater usage of groundwater resources, particularly in the contami- nated areas. Use of the groundwater will result in a poten- tial exposure to contaminants through the means described in Figure II-4, if no action is taken at this site and contami- nation migrates to areas that contribute to municipal groundwater supply. TOXICITY ORGANIC COMPOUNDS This group of compounds includes most of the contaminants identified at the PGA site. Several of these compounds, carbon tetrachloride, chloroform, 1,1,1-trichloroethane, perchloroethene, and trichloroethene, may produce liver injury. Carbon tetrachloride and chloroform have more seri- ous effects on the liver than trichloroethene and perchloro- ethene (Doull et al., 1980). Carbon tetrachloride, chloroform, perchloroethene, and trichloroethene have been classified by the EPA Carcinogen Assessment Group (CAG) as probable human carcinogens via ingestion (U.S. EPA, 1986a).. Exposures to the above compounds through inhalation may result in central nervous system depression, including anes- thesia. TCE has been used as an anesthetic (National Research Council, [NRC] 1977). other effects may include irritation of the mucous membranes of the nose and throat and irritation to the eyes (NRC, 1980). Trichloroethene and perchloroethene are also classified as probable human car- cinogens by CAG via the inhalation route (U.S. EPA, 1986a). 1,1-Dichloroethene and trans-l,2-dichloroethene exhibit simi- lar toxic effects to humans through inhalation and ingestion exposures. These compounds have anesthetic properties, and exposures to high concentrations may cause nausea and vomit- ing (U.S. EPA, 1985a). The CAG has classified 1,1-dichloroethene as a possible human carcinogen for both inhalation and ingestion exposure routes (U.S. EPA, 1986a). INORGANIC COMPOUNDS This group of compounds includes metals. Some of the inor- ganic compounds detected at the PGA site, such as chromium, are much more toxic than others. CHROMIUM Chromium has been identified in some water samples taken from the site in both the trivalent and hexavalent states. RD/R52/020 II-6 ------- MEDIA DIRECT EXPOSURE PATHWAY > RECEPTOR GROUNDWATER —> ingestion by residents who use private wells for potable water supply —> Inhalation of volatiles stripped from the drinking water during in-home uses such as bathing and cooking -> dermal contact with contaminated ground- water from resident's private wells W63602.RA FIGURE IJ.-4 EXPOSURE PATHWAY AND RECEPTOR SUMMARY I'llOf NIX (.(H)I)YI AK A I KM SECTION l(i GUIS ------- Chromium compounds in the trivalent ( + 3) state are of a low order of toxicity. In the hexavalent (+6) state, chromium compounds are irritants and corrosive and can enter the body by ingestion, inhalation, and through the skin (Sittig, 1981) . Hexavalent chromium may cause liver and kidney damage, inter- nal bleeding, and respiratory disorders (U.S. EPA, 1985b). Hexavalent chromium has been designated by the CAG as a human carcinogen, via the inhalation route (U.S. EPA, 1986a). RISK Risk is a function of both toxicity and exposure. At present, the exposure to contaminated groundwater is limited, and the population and environment are not in any immediate danger. However, future migration of the contaminants could affect plant and animal life, and future use of contaminated ground- water will result in heightened risks as shown in Table II-2. The risk associated with exposures to contaminated groundwater, particularly for future use scenarios, is an excess lifetime cancer risk. This risk can go as high as 2 x 10-3 (two excess lifetime cancer occurrences per 1,000 people exposed over the course of a 70-year lifetime). There does not appear to be an ingestion risk from exposure to noncarcinogens. More information on health effects associated with contaminants found at the PGA site can be found in the Preliminary Public Health Endangermen-t Assessment in the administrative record. RD/R52/020 II-7 ------- Table II-2 SUMMARY OF EXPOSURE ROUTES AND RISKS Media Exposure Setting Exposure Risk Results Groundwater Residential—Current and Ingestlon Potential For the Goodyear municipal wells (COG 01,2,3,6), there Is an excess lifetime cancer risk of 2 x 10 based on the maximum trlchloro- ethylene concentration for these wells. There does not appear to be a risk from the Intake of noncarcinogens. COG #1,2,3,6 are blended to provide water as demanded. I oo For the private domestic wells PLUMB, SHAUVER, and DOMEST3, the risk due to trichloroethylene contamination of these wells can only be qualified because fewer than three samples were collected from eai-h well. A carcinogenic health risk may be present; however, the exact nature of the risk cannot be identified. There does not appear to be a risk from the Intake of noncarcinogens. Inhalation o The risk from inhalation of volatlles released from the groundwater In the course of in-home uses such as cooking, bathing, etc., cannot be quantified. However, it should be recognized that this exposure could contribute to the overall,risk from the use of contaminated groundwater. Residential—Potential Only Ingest ion The GAC monitor wells follow with excess lifetime cancer risks of -4 2 x 10 based on the maximum concentration of 1 ,l-d(cliloroethene, 2 x 10 for carbon tetrachloride, 3 x 10 for chloroform, and 5 x 10 for trlchloroethylene, all based on the-maximum concen- tration of each constituent from the three wells. There does not appear to be a risk from the Intake of noncarcinogens. For the EPA monitor wells, there Is an excess lifetime cancer risk of 2 X 10 for 1,1-dlchloroethene and 1 X 10 for trlchloroethem- based on their maximum concentrations, due to exposure through Ingestlon of groundwater. There does not appear to be sk from the intake of noncarcinogens. ------- Table 11-2 (continued) Media Exposure Setting Exposure Risk Results Groundwater Residential—Potential Only IngestIon I vo Other wells In the area that presented an excess lifetime cancer risk due to trlchloroethylene include the following: - GAC «3: 3 X 10 based on the maximum concentration - GAC 14: 1 X 10 based on the maximum concentration - PLA 12: 1 X 10 based on the maximum concentration - PLA 13: 1 x 10 based on the maximum concentration There was also an excess lifetime cancer risk of 6 X 10 tor COG #5 (fire control well) due to the maximum concentration of arsenic. There does not appear to be a risk from the Intake of noncarclnogens. The risk from Inhalation of volatlles released from the groundwatet In the course of in-home uses such as cooking, bathing, etc., can- not be quantified. However, this exposure could contribute to the overall risk from the use of contaminated groundwater. Assumptions: Dally water Intake for 0-6 years, 1.0 liter/day; 6-18 years, 1.4 liters/day; 18-70 years, 2.0 liters/day. Lifetime average dally Intake for drinking water - 0.029 liter/kg of body weight/day based on a 70 kg individual consuming 2 liters/day of water over the course of a 70-year lifetime. ------- III. ENFORCEMENT HISTORY In Section 16, two responsible parties have been identified as the major sources of groundwater contamination, Goodyear Aerospace Corporation (GAC) and the Department of Defense (for past naval operations). GAC has been participating in the RI/FS since 1984. Its efforts have been concentrated on determining the extent of soil contamination at the facility and the extent of ground- water contamination underneath the GAC facility and the PGA. A history of EPA enforcement actions toward GAC includes: o July 23, 1982—RCRA Section 3007/CERCLA Section 104 request for information issued to GAC o March 27, 1984—General notice letter sent to GAC from EPA o March 27, 1984—RCRA Section 3013/CERCLA Section 106 Administrative Order on consent issued to GAC o December 20, 1984—Violation of the Clean Water Act issued to GAC from EPA * o January 14, 1986—Violation of the Clean Water Act issued to GAC from EPA o March 19, 1986—CERCLA Section 106 Administrative Order on consent signed by GAC and EPA The U.S. Corps of Engineers had begun researching Navy activities at the airport and believed that the Navy is a potentially responsible party for the groundwater contamination emanating from the PGA area. The Navy had sold the facility to the City of Phoenix in 1968. The U.S. Corps of Engineers was assigned in May 1985 to represent the Department of Defense on the Phoenix-Goodyear Airport Interagency Committee, which was established by EPA to involve state and local agencies as well as responsible parties in CERCLA actions at the site. GAC is currently conducting RI activities at the site in accordance with the March 19, 1986, order. These activities will be completed by the end of the calendar year. RD/R52/020 ' III-l ------- IV. COMMUNITY RELATIONS HISTORY The following is a list of community relations activities conducted by the U.S. EPA at the PGA Superfund site (formerly the Litchfield Airport Area [PLA] site): o EPA conducted interviews with Goodyear and Avondale residents and state and local officials in 1984 to improve EPA's understanding of community concerns. These interviews provided the basis for the Phoenix- Litchfield Airport Area Community Relations Plan released in October 1984. o EPA established information repositories at the Avondale Public Library, Phoenix Public Library, and the Arizona Department of Health Services. EPA updated repositories periodically with fact- sheets and other relevant documents. o EPA established a computerized mailing list with over 200 addresses of interested individuals. o EPA contributed PGA-related information to Groundwater Quality Update, a newsletter that pro- vides information about groundwater quality to ' interested parties, prepared and distributed by the Arizona Department of Health. Services. o EPA distributed a factsheet in July 1984 which provided an overview of the Superfund process, a brief description of the PGA site contamination, and described proposed remedial investigation/ feasibility study (RI/FS) activities. o EPA held a community meeting on August 1, 1984, to provide an overview of the Superfund process, infor- mation on past site activities, and outlined future RI/FS activities. o EPA distributed an "Update on Site Activities" factsheet in February 1985 which described ongoing RI/FS activities including water level measurement and water quality sampling, soil boring and sampling, well installation, and computer modeling. o EPA released the "Water and Soil Sample Results" factsheet in June 1985 which reported the results of the soil and water sampling, and discussed how this information would be used in the second phase of the RI/FS. o EPA held a community meeting on February 19, 1986, to report the remedial investigation Phase I RD/R52/020 IV-1 ------- results, and to discuss the additional information needed to complete the RI and the plan for obtain- ing this information during the upcoming RI Phase I activities. o EPA sent out a factsheet in January 1987 which provided groundwater sampling results and discussed .the Operable Unit Feasibility Study (OUFS) . o EPA distributed a factsheet in May 1987 announcing the release of the OUFS and the beginning of a public comment period for the study, as well as announcing a community meeting on June 4, 1987. o EPA held a public comment period from June 2, 1987, to July 2, 1987, on the draft OUFS and prepared a responsiveness summary to address the comments received. o EPA announced the public comment period on the draft OUFS and the public meeting with a public notice placed in Goodyear's weekly newspaper Westsider which ran on Thursday, May 28, 1987, and Thursday, June 4, 1987. In addition, EPA will continue to conduct ongoing community. relations activities at the PGA site throughout the duration of the comprehensive RI/FS. RD/R52/020 RD/R52/020 IV-2 ------- V. ALTERNATIVES EVALUATION LISTING OF ALTERNATIVES A wide range of alternatives was identified for the Sec- tion 16 Operable Unit. These alternatives were separated into three groups: groundwater, water treatment, and water end use (see Figure V-l). Groundwater alternatives were selected to compare the relative values of containing or pumping different areas of groundwater contamination at dif- ferent rates. Treatment alternatives were selected based on institutional requirements and the best available technology. Water end use alternatives were selected based on the feasi- bility of delivering the water and the distance to sites capable of accepting the estimated flows. As shown in Fig- ure V-l, if groundwater pumping and rehabilitation alter- natives are selected, an appropriate water treatment alter- native and a water end use alternative would also be selected. The no-action and containment alternatives will not require associated water treatment or end use alternatives. Although chromium is above the federal primary drinking water standard in portions of the aquifer, the extent of the chro- mium contamination is not precisely known at this time. Therefore, treatment of the chromium contamination will be ' addressed in the final remedy. In the interim, all water extracted from the aquifers will be blended and then treated for VOC's and discharged to the appropriate end use location. This discharge will meet all federal primary drinking water standards for all contaminants, including chromium since the water containing chromium will be blended with water free of chromium. This is possible since the volume of water being extracted and treated creates a stream that lowers the chro- mium concentration to acceptable levels for the interim per- iod. This treatment scheme is only an interim solution, and all contamination will be fully addressed in the final remedy. GROUNDWATER ALTERNATIVES The groundwater alternatives are: o No action o Containment of the contaminated groundwater by use of a slurry wall extending to the Middle Fine-Grained Unit and surrounding a range of areas within Section 16 o Extraction of contaminated groundwater from four potential areas. These areas were chosen based on location of contaminant disposal and extent, of groundwater contamination. RD/R52/023 V-l ------- GROUNDWATER GROUNDWATER REHABILITATION ALTERNATIVES ALTERNATIVES WATER ALTERNATIVES WATER TREATMENT TECHNOLOGIES WATER END USE/DISPOSAL ALTERNATIVES NO ACTION H CONTAINMENT PUMPING QAC OAC 4 PGA SECTION 16 SECTION 16- ACCELERATED NO REHABILITATION MEET ARAR'S MEET BACKGROUND NO TREATMENT MEET ARAR'S MEET BACKGROUND 1 • ^ — STRIPPING (STEAM/AIR) CARBON ADSORPTION REVERSE OSMOSIS DISTILLATION LIQUID-LIQUID EXTRACTION CRITICAL FLUID EXTRACTION PHOTOLYSIS BIOLOGICAL DEGRADATION (AEROBIC/ANAEROBIC) •L AGRICULTURAL •L INDUSTRIAL H •\ H H MUNICIPAL RECREATIONAL SURFACE DISCHARGE GROUNOWATER REINJECTION I lUUHt V I POTENTIAL REMEDIAL ALTERNATIVES 8UBUNIT8 A AND B/C PMOENIX-GOODVEAR AIRPOH I SECTION 10 W83802 H4 > ------- GROUN ATER ALTERNATIVES GROUNDWATER REHABILITATION ALTERNATIVES I ALTERNATIVES WATER TREATMENT TECHNOLOGIES WATER END USE/PIS ^ ALTERNATIVES NO ACTION CONTAINMENT NO REHABILITATION PUMPING QAC ft PGA SECTION ie SECTION Ifl- ACCELERATED MEET ARAR'8 MEET BACKGROUND NO TREATMENT 1-H H MEET ARAR'i MEET BACKQROUN —1 HIM a iMirrinu CARBON ADSORPTION m •\ H SURFACE OISCHARQE REINJECTION FIGURE V-2 SELECTED REMEDIAL ALTERNATIVE SUBUNITS A AND 8/C PHOENIX-OOODYEAR AIRPORT SECTION t6 W63602.R4 -« ------- Extraction of groundwater from Subunit A within the Upper Alluvial Unit beneath source areas at the GAC facility only. Extraction of groundwater from Subunit A within the Upper Alluvial Unit beneath source areas at the GAC and PGA facilities. Extraction of groundwater from Subunit A beneath all of Section 16, with the exception of the area northwest of the runway at the PGA. (Groundwater monitoring indicates levels of contaminants below ARARs in Subunit A for the area northwest of the runway.) Extraction of groundwater at an accelerated rate from aquifers in Subunit A beneath all of Section 16, with the exception of the area northwest of the runway at PGA. This would be accomplished by using more wells and higher pumping rates. (Groundwater monitoring indicates levels of contaminants below ARARs in Subunit A for the area northwest of the runway.) Each extraction alternative is associated with two ground- . water level of treatment alternatives that are directly related to the duration of pumping. The longer the period of pumping the more pore volumes of groundwater in the cap- ture zone will be removed, thus the greater the cleansing of the aquifers. The groundwater rehabilitation alternatives for Subunit A of the Upper Alluvial Unit are: o Removal until water from monitoring wells is of a quality that meets ARARs o Removal until levels of VOC's in water from monitor- ing wells are below detection limits, which is the background quality of groundwater in the area WATER TREATMENT TECHNOLOGIES The possible technologies identified to treat water are: o Air stripping o Activated carbon o Reverse osmosis o Distillation o Critical fluid extraction o Liquid-liquid extraction o Photolysis o Aerobic biological treatment o Anaerobic biological treatment o Steam treatment o Wellhead treatment RD/R52/023 V-2 ------- WATER END USE ALTERNATIVES The water end use alternatives are: o Reinjection o Surface discharge The possible uses identified are: o Reinjection up to 2 miles from the site in a manner that will not have any deleterious effect on the remedial action o Discharge to the City of Goodyear o Discharge to the Agua Fria River o Discharge to GAC o Discharge to Arlington Canal Co. o Discharge to Buckeye Irrigation District o Discharge to City of Avondale o Discharge to City of Phoenix o Discharge to Cotton Tree Apartments o Discharge to Estrella Golf Course o Discharge to Goodyear Farms, Inc. o Discharge to Litchfield Park Service Company o Discharge to Maricopa County WCD o Reinjection for plume control o Discharge to Roosevelt Irrigation District o Discharge to Salt River Project o Discharge to St. Johns Irrigation District o Discharge to Valley Utilities Company o Reinjection at Unidynamics SCREENING OF ALTERNATIVES As promulgated under CERCLA and SABA/ remedial actions are those responses to releases that are consistent with a per- manent remedy to prevent or minimize the release of hazard- ous substances, pollutants, or contaminants so they do not migrate to cause substantial danger to present or future public health or welfare or the environment. SARA, Sec. 121, states further, "Remedial actions...shall attain a degree of cleanup of hazardous substances, pollutants, and contami- nants released to the environment and of control of further release at a minimum which assures protection of human health and the environment. Such remedial actions shall be relevant and appropriate under the circumstances presented by the release or threatened release of such substance, pollutant, or contaminant." SARA also states that remedial actions should be favored that permanently and significantly reduce the volume, toxicity, or mobility of hazardous substances, pollutants, and contaminants. The offsite transport and disposal of hazardous substances or contaminated materials without such treatment should be the least favored alterna- tive remedial action where practicable treatment technologies are available. RD/R52/023 V-3 ------- Alternatives are screened based on their ability to meet the above-stated requirements and to meet the objective of the operable unit. The objective is to control the migration of contaminants within the Section 16 boundaries while being con- sistent with the final remedial action for the entire site. GROUNDWATER ALTERNATIVES The no-action and containment alternatives must be evaluated by law and were retained for later evaluation. The pumping alternatives were evaluated based on their abil- ity to clean up the targeted Section 16 area. Table V-l summarizes the findings. Table V-l AREAL EXTENT OF PUMPING ALTERNATIVES Gallons Relative Area Pumping Target Cleanup per (percent of Alternative Subunit Area (acres) Minute largest target area) GAC A 120 200 24 GAC and PGA A 325 ' 250 65 Section 16 A 500 300 100 Section 16— A 500 1,200 100 Accelerated Pumping Alternative GAC would not adequately protect the downgradient groundwater sources by covering only 24 percent of Subunit A. Since there are high levels of contamination in Subunit A throughout the Section 16 area, it is reason- able to provide the most efficient means of removing as much contamination as possible from the entire area. For this reason the GAC alternative was dropped from further consid- eration. The remaining pumping alternatives were evaluated in detail. TREATMENT ALTERNATIVES Table V-2 presents an evaluation of the technologies for VOC removal and screens out those that are not applicable. Air stripping and activated carbon adsorption were retained for detailed evaluation. The other technologies identified were dropped from further consideration for a variety of reasons RD/R52/023 V-4 ------- Table V-J OP voc REMOVAL TECHNOLOGIES SECTION U ROD Proceea Description Air Stripping Activated Carbon Adsorption Reverae Oaaoala DIatlllatlon f Liquid-Liquid Ln Extraction Critical fluid Extraction Pbotolyal* Aerobic Biological Anaerobic Biological Steam Stripping State of Development Commercial Commercial Commercial Commercial Limited Commercial Limited Commercial Limited Commercial Commercial Commercial Ability to Meet Otecbarce Standard* Capable of VOC removal exceeding 99.9 percent Capable of VOC removal exceeding 99.9 percent Relatively poor performance for VOC'a Capable of achieving very high VOC removal Unknown--pollahlng 1* u*ually required Unknown- -a 1 though unlikely to reduce below 100 ppb ' Unknown "iimi compound* not readily biodegradable Nay not consistently meet standards Capable of VOC removal exceeding 99.9 percent Performance Record Excellent Excellent Poor for VOC remove I Good on high concentration at reams; not appropriate for low concentra- tion streams Good, but ability to meet dtacharge requirement* la unknown Limited— few large-acale application* Limited- -com- plete conversion unlikely Variable performance for VOC'a Variable performance for VOC'a Excellent Relative Coat* Capital Operation Low Low to Moderate Low Moderate to High High High Moderate Very High High Very High Very High Moderate to •t*> Unknown None Ulgb High High High High Hlgb Waste Streams Air exhaust (can be carbon treated) Carbon containing organlca requires regeneration or replacement Producee a concen- trate at ream that requires additional treatment Exhaust containing organlca Solvent with extracted organlca None May produce more harmful byproducts; some appllcattona require very long residence times Sludge produced tbst require* disposal Sludge produced Air exhauat Additional Commenta Commonly uaed for removal of VOC'a at low concentration Relatively poor carbon utilisation for treatment of stream* with very low organic concentratlooa' Generally uaed for removal of aslts and high molecular weight organlca Generally uaed for treatment of concentrated streams where high degree of separation 1* required Produce* s solvent stream with organlca that requlrea additional treatment; require* uae of potentially bsxardoua solvents None None May not be stable, susceptible to •bock, temperature-dependent, acclimation la Important May not be ateble, susceptible to shock, temperature -dependent, acclimation Is Important Not used for this type of application Retained for further Analyula Yes Yes--uaelul for vapoi and aqueou* phaae Voc removal No—poor performance for VOC removal No-*not approprldie for low levela of contaminant* No--ablllty lo Steel discharge rerqulic- menta la unknown No--poor peflolodntc for thla applli.41 Ion No- -lack of Jevclopofiu performance No--varl*ule performance No—variable performance No* -not demount I 41 t«l fur removal ol low concent rat lona ol VOC'a Wellhead Treatment Commercl*! Variable depending on Variable Variable Variable Variable ------- including poor, variable, or unproven performance, institu- tional and management constraints, or inapplicability to expected contaminant concentrations. Chapter 7 of the Section 16 Operable Unit Feasibility Study provides the methodology for -the screening of treatment alternatives. WATER END USE ALTERNATIVES Based on water quality, potential interest by end users, and future water requirements of end users, the water from Subunit A was screened, with the results shown in Table V-3. Because of the high levels of TDS in Subunit A (about 3,900 ppm as compared to the secondary MCL of 500 ppm), water from this subunit can only be used for reinjection after treatment as it cannot be used for drinking or irrigation purposes. There are no other suitable uses for this water. Table V-3 SUMMARY OF SCREENING OF WATER END USE ALTERNATIVES Use Subunit A Agricultural Eliminated Industrial Eliminated Municipal Eliminated Recreational Eliminated Groundwater Recharge Retained Surface-Water Discharge Eliminated aRetained for reinjection into Subunit A only. In summary, the only end use alternative that appears to be available is reinjection. EVALUATION OF ALTERNATIVES The remaining alternatives are shown in Figure V-2. A short summary of the technical and economic evaluation of each alternative follows. GROUNDWATER ALTERNATIVES No Action Alternative The no-action alternative would allow the groundwater con- tamination to spread over an ever-widening area and would RD/R52/023 V-6 ------- likely have continuing adverse environmental and health consequences. These include exposure of carcinogens and other harmful contaminants through ingestion of water and soil and inhalation of soil gas and gas released from pumped groundwater. Containment Alternative The containment alternative will accomplish the purpose of isolating contaminants in the contained area for some period of time but would not accomplish the objective of perma- nently reducing waste volume or toxicity. Institutional controls would be necessary to prevent usage of contained groundwater in the future. A containment wall could be constructed to surround GAC and PGA, or all of Section 16. They have been demonstrated at numerous areas to contain groundwater under saturated conditions; however, there is no guarantee of continuous or permanent containment. The use- ful life of containment walls is unknown, but is expected to be more than 100 years. Containment walls as deep as 325 feet have been constructed, but with great difficulty. If a containment wall were to be constructed at this site, it would take about 2 to 3 months to build around the GAC and PGA area, or about 9 to 12 months to build around the Section 16 area. No significant safety hazards are expected during construction. If after construction the containment' wall failed, there would be a threat to public health and the enviro-nment as contamination moves offsite and pollutes water supplies. Containment walls of the depth required at the PGA site are difficult to construct, and cost estimates for this alternative range from $111 million to $148 million, making it an extremely expensive alternative. It cannot be guaranteed that contaminants would be permanently contained within slurry walls. Pumping Alternative The pumping alternatives also accomplish the objective of stopping migration of contaminants in Section 16. When coupled with treatment, they also will reduce the volume, mobility, and toxicity of the groundwater. Pumping to extract contaminated groundwater would prevent migration of contaminants from the chosen pumping area. This technology has been demonstrated to be successful in other areas. However, aquifer rehabilitation estimations are based on hydrogeologic principles and regional flow characteristics. There is some uncertainty as to the time required for rehabilitation due to limited knowledge of the stratigraphy. Analysis of water samples from monitoring wells for contam- inant levels will indicate aquifer cleanup. The period esti- mated for,cleanup for Subunit A under GAC and PGA is 57 years, for Section 16, 82 years, and for Section 16—accelerated, 37 years. Pumping rates for these alternatives are found in RD/R52/023 V-7 ------- the Operable Unit Feasibility Study. Operation is relatively simple and is not expected to signficantly affect the alter- native's reliability. It is likely that during the remedial action, some components will require maintenance or replace- ment. No impediments to well construction are foreseen, and no significant safety hazards are expected during construc- tion. If pump failure occurs, there would be no release of contaminants that could pose a threat to public health or the environment. Table V-4 summarizes the capital costs associated with these options. Table V-4 COST EVALUATION OF EXTRACTION AND MONITORING WELLS Cost Pumping Pumping Pumping Item GAC and PGA Section 16 Section 16-ACC Extraction Wells $110,000 $275,000 $600,000 and Pumping Monitoring Wells 60,000 150,000 360,000 Total $170,000 $425,000 - ' $960,000 TREATMENT ALTERNATIVES Both air stripping and activated carbon adsorption achieve the desired goal of reducing volume and toxicity of the groundwater sufficiently to meet the applicable and appropri- ate requirements and will likely exceed these requirements. Treatment of contaminated groundwater, either by air strip- ping or the use of granular activated carbon, has been shown to be very effective with removals of organic often exceed- ing 99.9 percent. These processes are relatively predictable, and they have been used successfully at a number of CERCLA sites. Equipment is relatively easy to operate once initial adjustments have been completed. Operator training will be required. Occasional attention for adjustment, monitoring, and testing will be required. With industrial-grade compon- ents and regular preventive maintenance, process integrity should be 10 years or more. Scaling of air stripping tower internals has been a problem at some sites. A small amount of an anti-sealant, such as hypochlorite, would be required to remedy this. RD/R52/023 V-8 ------- Numerous vendors are available to produce, the process components. Conventional materials for construction are required. All equipment items can be shop-fabricated and skid-mounted, making field erection easier. Construction of either process could be completed within one year. The startup period may take several days. Catastrophic failure of components are unlikely, and any threat to public health and the environment are relatively low. Air emission con- trols will be placed on the air stripping towers for two reasons. First, SARA states that a remedy should signifi- cantly reduce the toxicity, mobility, and volume of contami- nants. By just removing VOC's from water and placing them into the atmosphere, none of these objectives are satisfied. In addition, Maricopa County Air Pollution Control Board requires that all new plants with air emissions "will ade- quately dilute, reduce, or eliminate the discharge of air pollution to adjoining property." This requirement is also known as reasonably achievable control technology (RACT), and in this case, RACT is air emissions controls such as activated carbon adsorption or thermal degradation. The ; costs associated with each treatment alternative are summarized in Table V-5. END USE ALTERNATIVES As discussed previously, in the Screening of Alternatives > section, for the Subunit A water, the only viable alterna- tive is reinjection back into the Subunit A aquifer. The number and location of reinjection wells would need tp..be studied. Injection into aquifers via wells has been done successfully in the past. Operations are simple, but require maintenance from time to time. Periodic redevelopment will prevent clog- ging of the wells, thus maintaining the wells' ability to accept the generated flow. Redevelopment will require a temporary shutdown. Drilling and developing wells is rou- tine, and the construction period, including construction of the conveyance system, is expected to be less than 18 months. No threats are expected to public health or the environment during construction or in the event of system failure. Costs are included in Table V-5 along with the treatment alterna- tives. RD/R52/023 RD/R52/023 V-9 ------- Table V-5 COSTS FOR SUBUNIT A REMEDIAL ACTION WITH WATER REINJECTION Pumping Alternative Treatment Method CAPITAL COSTS Air Stripping: To ARAR To Background Granular Activated Carbon: To ARAR To Background GAC & PGA $2,077,500 2,139,500 2,032,500 2,032,500 Section 16 Section 16-Accelerated $2,358,500 2,438,500 2,338,700 2,338,700 $5,043,100 5,222,100 5,226,500 5,226,500 OPERATING COSTS b Air Stripping: To ARAR 765,500 800,200 To Background 787,400 872,300 Granular Activated Carbon: To ARAR 3,532,400 - 4,203,900 To Background 3,532,400 4,203,900 1,521,500, 1,555,700 15,085,700 15,085,700 aCosts are shown as present worth at a 10-percent rate of return. 'costs for air stripping include air emission control. RD/R63/001 V-10 ------- VI. SELECTED REMEDY STATUTORY DETERMINATIONS CERCLA and its reauthorization, known as SARA, requires that permanent reductions of contaminants through treatment be preferred over containment alternatives.• It also requires that Applicable or Relevant and Appropriate Requirements (ARARs) be used to determine the treatment levels. By achiev- ing these requirements, the selected remedy for the Section 16 Operable Unit reduces the present and future risks associ- ated with use of the groundwater in the Section 16 area. By reducing the contaminant levels and restricting their mobil- ity, this remedy protects both human health and environmental quality. Table VI-1 shows the ARARs identified for the groundwater and the proposed treatment levels. In all cases, contami- nant levels found in Section 16 Subunit A wells are greater than the Safe Drinking Water Act maximum contaminant levels (MCL) and the Arizona Department of Health Services action levels. While the selected remedy satisfies the requirements for treatment and risk reduction, it does so in the most economi- cal manner. Since Subunit A is the most contaminated aqui- fer, the entire Section 16 area will be treated and pumped to prevent lateral and vertical migration. Although the recommended alternative at the beginning of the public com- ment period called for limited pumping and treatment of water from Subunit B/C this water is much less contaminated and will be pumped and treated as part of the current industrial practice until the final remedy is chosen next year. This reduces pumping and well costs while capturing the most con- taminated water. Of the proven technologies, air stripping proved to be the most economical treatment method available, both for capital and operating costs. It will also reduce residual wastes to a minimum. Reinjection proved to be the only viable alternative for Subunit A water. By reducing migration of contaminated groundwater outside of Section 16 and permanently reducing the levels of contamination in Section 16, the risks associated with use of the water are reduced to acceptable levels. The selected remedy satis- fies the requirement of reducing the mobility, toxicity, and volume of contaminated water. It does so by using treatment technology to the maximum extent practicable and does so in a cost-effective manner. RD/R52/024 VI-1 ------- Table VI-1 STATE AND FEDERAL APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS* (concentrations in ppb) AND OTHER CRITERIA Compound Trichloroethylene 1,1,1-Trichloroethane 1,1-Dichloroethylene Perchloroethylene Trans-1,2-dichloroethylene Carbon tetrachloride Chloroform Chromium Arsenic SDWA MCL 5 200 7 50 50 SDWA MCLG 0 200 7 Proposed MCL Proposed MCLG AWQC Drinking Water Only ADHS Action Level 5 200 1 3 70 0.5 120 50 Proposed DW Treatment Level 5 200 7 3 70 5 0.5 50 I N> Clean Water Act requirements will be determined during NPDES review. Source is not a byproduct of municipal water supply chlorination. NOTES: ADHS—Arizona Department of Health Services AWQC—Ambient Water Quality Criteria MCL Maximum Contaminant Level MCLG—Maximum Contaminant Level Goal SDWA—Safe Drinking Water Act DW—Drinking Water Sources: U.S. EPA 1986. Public Health Assessment Manual ADHS 1987. S. Eberhart RD/R56/057-3 ------- DESCRIPTION. The selected alternatives for the Section 16 Operable Unit are: o Groundwater Water from Subunit A will be drawn from the entire Section 16 area until contaminant levels are reduced to meet ARARs, and the water treated to meet ARARs. Water from Subunit B/C will continue to be pumped by Loral Corporation and the Phoenix-Goodyear Airport and closely monitored. Currently, GAC-2 is pumped about 50 percent of the time at 1,000 gpm during the irrigation season and about 15 percent of the time during the winter. GAC-3 is used for standby fire protection and not normally pumped. GAC-4 has very little usage. PLA-2 is pumped for 2 to 3 hours per day at a rate of about 450 gpm. Pumping from those wells may be altered to optimize plume containment and removal. o Treatment Air stripping towers will be used to remove the VOC's from the groundwater. Emission controls such as activated carbon units will be used to treat the air effluent. . Contaminated water will be pumped out of the ground and routed via pipelines to the treatment plant. There the water will be sprayed down as air is pumped up a packed column to remove VOC's. Air flowrate, column diameter/ and packing depth will be designed based on maximum contaminant levels and organic volatilities. Stripped water will then be reinjected into the aquifer at a loca- tion that will not adversely affect the groundwater flow to the supply wells, or adversely affect con- taminant flow in the groundwater system. Air containing the stripped organics will be treated in a bed of granular activated carbon to reduce air emissions. When the carbon becomes saturated with organics, it will require regeneration or proper disposal. At other sites, this has typi- cally been done once or twice a year. End Use Reinjection is the preferred end use for the water from Subunit A. RD/R52/024 VI-3 ------- It is expected that treatment facilities for Subunit A will be in operation for a period of 82 years. Additional study is required to determine if further water treatment is necessary to prevent scaling and biological growth in the air strippers, the proper location of the reinjection wells. By capturing the contaminant plume in Section 16, this selected remedy will accomplish the objective of the Sec- tion 16 Operable Unit, which is to stop migration of con- taminants beyond Section 16 in Subunit A and from entering Subunit B/C. It will reduce further deterioration of the aquifer outside of Section 16 and reduce the volume and toxicity of the contamination in Section 16. It also ful- fills the statutory preference for permanent solutions at Superfund sites. The .selected remedy, as proposed, will meet all enforceable federal and state requirements for water quality. The result- ing saturated carbon from the air emission control equipment will either be regenerated or disposed of in a safe manner at an approved RCRA facility. RD/R52/024 RD/R52/024 VI-4 ------- Appendix A INDEX OF ADMINISTRATIVE RECORD Date of Publication June, 198'4- Ecology and Environment, Inc. Final Workplan RI/FS Litchfield Airport Area. Goodyear, Arizona. June 1984. Describes the activities to be carried out and the methodology for the remedial investigation and feasibility study of the Litchfield Airport Area (later renamed the Phoenix-Goodyear Airport). July, 1984 Ecology and Environment, Inc. Draft Community Well Sampling Plan. Phoenix- Litchfield Airport Area Remedial Investiga- tion. July 2, 1984. Specifies the procedures and activities for taking water samples from wells in the area of the Phoenix-Litchfield Airport. Done as a part of the RI. July, 1984 Ecology and Environment, Inc. Draft Sampling Plan Phase I Drilling, Well Installation and Aquifer Testing. Phoenix-Litchfield Airport Area Remedial Investigation. July 2, 1984. Specifies the procedures and activities for installing new wells and taking water samples from those wells. Aug., 1984 Engineering-Science, Inc. Contamination Assessment Plan. August 1984. Provides revised plan for assessment of groundwater contamination in the vicin- ity of the Goodyear Aerospace Corpora- tion facility (currently owned by Loral Corporation). This was done as a requirement of Administrative Order 84-02 issued by EPA, Region IX. Oct., 1984 CH2M HILL. Final Community Relations Plan. Phoenix-Litchfield Airport Area.October 1984. Prepared as part of Phase 1 of the RI/FS to provide a means of gathering back- ground, site history/ and a discussion of the concerns of interested parties. RD/R94/029 A-l ------- Date .of Publication Nov., 1984 Aug., 1985 Oct., 1985 Jan., 1986 Jan., 1986 Ecology and Environment, Inc. Quality Assurance Project Plan. Indian Bend Wash and Phoenix-Litchfield Airport Area Sites. November 1984. Describes procedures for ensuring qual- ity control and reliability of sampling procedures, field measurements, equip- ment maintenance, analytical procedures, data management, and document control. Engineering-Science, Inc. Remedial Investigation Phase I Results Contamination Assessment Report. Prepared for Goodyear Aerospace Corporation. Litchfield Park, Arizona. August 1985. Presents the results of Phase 1 drilling and depth-specific monitoring well installation conducted by Goodyear Aerospace Corporation as specified in the Contamination Assessment Plan, August 1984. Jacobs Engineering, Inc. Phoenix-Litchfield Airport Area Responsible Party Search Title Search. Final Assessment. October 25, 1985. Presents findings of investigation for site history and chronology of signifi- cant events regarding hazardous mate- rial, interviews with the industry and public witnesses, and a financial assessment of the PRP's. Ecology and Environment, Inc. Task 5.3 Phase I Data Summary/Report. Phoenix-Litchfield Airport Area Remedial Investigation. 2 Volumes. January 17, 1986. Presents data regarding aquifers, soil materials, and contamination beneath the PGA area. Ecology and Environment, Inc. Task 4.0 Source Verification, Field Investigation. Phoenix-Litchfield Airport Area Remedial Investigation. 2 Volumes. January 31, 1986. RD/R94/029 A-2 ------- Date of Publication Provides a history of hazardous waste disposal practices, assessment of known and suspected contaminant source areas, and a determination of other potential sources. Apr., 1986 Ecology and Environment, Inc. PLA Sampling Plan. March 19, 1986. Provides objectives, methods, and procedures for semiannual well water sampling and analysis. Sampling was done in April 1986. Oct., 1986 CH2M HILL. Technical Memorandum; Results of Soil Gas Sampling and Analysis.Phoenix- Litchfield Airport Remedial Investigation Phase II, Stage 1. October 3, 1986. Discusses soil gas sampling and mobile analysis conducted at the PGA superfund site from July 17 to 25, 1985. * Dec., 1986 CH2M HILL. Evaluation of Potential Water Use Alternatives"Phoenix-Goodyear Airport Remedial Investigation Phase II, Stage 1. December 1, 1986. Presents an evaluation of potential water user alternatives near the Unidynamics site. Also applies to Section 16 because of its proximity. Dec., 1986 U.S. Environmental Protection Agency. Interim Guidance on Superfund Selection of Remedy'. December 24, 1986. Provides new guidance on the selection of remedial actions in the absence of a new edition of the NCP. Incorporates Superfund Amendments and Reauthorization Act of 1986 (SARA). Feb., 1987 CH2M HILL. Soil Gas Technical Memorandum RI/FS. Phoenix-Goodyear Airport. February 27, 1987. Discusses soil gas sampling and mobile analysis conducted at the PGA superfund site from January 3 to 22, 1987. RD/R94/029 A-3 ------- Date of Publication Mar., 1987 Apr., 1987 Apr., 1987 May, 1987 June, 1987 July, 1987 CH2M HILL. Draft Work Plan Operable Unit Feasibility Study for Section 16 of Phoenix-Goodyear Airport Site. March 1987. Defines activities to be carried out to conduct an operable unit feasibility study for Section 16 of the PGA site. CH2M HILL. Technical Memorandum; Groundwater Extraction Alternatives for Section 16 of Township 1 North, Range 1 West. Phoenix-Goodyear Airport RI/FS.April 8, 1987. Provides preliminary estimate of ground- water extraction rates and well loca- tions necessary to control migration of contamination within Section 16 of the PGA site. CH2M HILL. Draft Preliminary Public Health Endangerment Assessment. Phoenix-Goodyear Airport Superfund Site. 2 Volumes. April 10, 1987. Provides an assessment of risk of public health and the environment associated with the PGA site. Letter from Lee Thomas, Administrator, U.S. EPA, to Honorable James J. Florio. May 21, 1987. Discusses the uses of maximum contaminant levels versus maximum contaminant level goals. CH2M HILL. Public Comment Feasibility Study for Section 16 Operable Unit. Goodyear, Arizona.June 1987. Discusses and screens remedial actions for providing an expedited cleanup of the Section 16 Operable Unit. U.S. Environmental Protection Agency. Interim Guidelines on Compliance with Applicable or Relevant and Appropriate Requirements. July 9, 1987. RD/R94/029 A-4 ------- Date of Publication Provides new guidance on selection of ARAR's and MCL's as cleanup standards for Superfund sites. Incorporates SARA. Currently being CH2M HILL. Technical Data Management II updated computerized data base located in CH2M HILL's Phoenix and Redding offices. Contains all water elevation and quality data from ADHS, responsible parties and EPA sampling. (1981-present) RD/R94/029 RD/R94/029 A-5 ------- Appendix B RESPONSIVENESS SUMMARY PHOENIX-GOODYEAR AIRPORT SECTION 16 OUFS OVERVIEW During the public comment period for the Public Comment Operable Unit Feasibility Study from June 2 through July 2, 1987, EPA received comments on the recommended remedy for the cleanup of Section 16 of the Phoenix-Goodyear Airport site. Comments were received from persons residing or doing business in that area. Most of the comments were of an editorial nature or addressed issues that are not fundamental to EPA's selection of a remedial action; however, the OUFS will be reissued to reflect all comments noted, and the remedial design will respond to comments as a part of this record of decision. This responsiveness summary reflects the changes made in tiie OUFS as a result of comments received and indicates where those changes were made. One issue that is fundamental to the selected alternative is the appropriateness of pumping aquifers in Subunit B/C at greater than current rates while still gathering information on these subunits. It has been decided to not expand the pumping in Subunit B/C until additional data pertaining to the aquifers and contaminants in this Subunit become avail- able, and an alternative selection can be reevaluated during the final remedy. Final selection, including extraction and injection well placement and pumping rates for Subunit A, will be determined during the remedial design period. SUMMARY OF PUBLIC COMMENTS AND AGENCY RESPONSES FROM PAMELA SWIFT, TOXIC WASTE INVESTIGATIVE GROUP 1. Question/Comment: I want to see some health studies done in this area. Response; As part of the overall remed- ial investigation/feasibility study (RI/FS) an endangerment assessment (EA) will be conducted. The EA will consist of a public health evaluation and environmental assessment. The Agency for Toxic Substances and Disease Registry will review the EA as well as conduct a health impact study prior to signing of the final record of decision, which is planned for summer 1988. See page 3-21 of OUFS. RD/R9/018 B-l ------- FROM SUNCOR DEVELOPMENT COMPANY 1. Question/Comment; We have a need for irrigation water for our farm crops and would like to use the treated ground- water if it becomes available for irrigation purposes. Response; Reinjection is the selected alternative for Subunit A water because of the high IDS levels that make this water unsuitable for irrigation. See pages 5-6 and 8-12 of OUFS. FROM CRANE, UNIDYNAMICS 1. Question/Comment; Consideration should be given to the possibility of conveying water pumped from wells in the Unidynamics area to the OU for treatment and subsequent end-use, precluding the need for a separate treatment facility in the Unidynamics area. Response; The overall RI/FS will consider this configuration. The treatment plant will be designed in a modular fashion to allow expansion for increased capacity. 2. Question/Comment; Hydraulic connection of Subunits B and C pertain only to the PGA area. A good hydraulic connection between the two units has not been shown in the Unidynamics area. Response; See pages ES-1 and 2-1 of OUFS. • 3. Question/Comment; The public health evaluation pertains to the entire Superfund study area, including PGA, GAC, and Unidynamics. Should it be modified to address only PGA and GAC for this document? Response; The public health evalua- tion portion of the OUFS, Chapter 3, was modified to address only PGA and GAC. See Chapter 3 of OUFS. 4. Question/Comment; Where appropriate, text and figures should be modified to reflect the purchase of Goodyear- Westinghouse property by SunCor. Response; See Chapter 2 of OUFS. 5. Question/Comment; On Figure ES-2, steam stripping is indicated under water treatment alternatives but is not addressed in the text. Response; Steam stripping is addressed in Table 7-2. See Table 7-2 of OUFS. 6. Question/Comment; On page 1-1, 5th paragraph, 1st sen- tence, it may be more appropriate to say "... acceptable level of contaminants in Arizona ground water." Response; See page 1-1 of OUFS. 7. Question/Comment; On page 1-1, 5th paragraph, 4th sentence, refer to treatment levels in aquifer and extracted water. Response; See page 1-1 of OUFS. RD/R9/018 B-2 ------- 8. Question/Comment; By page 1-3, the PGA and Unidynamics areas have not been defined. A map prior to this may help clarify. Response; See Figure 1-1 of OUFS. 9. Question/Comment; Are the estimated contaminant concen- trations presented on Figures 2-3 and 2-4 mode, mean, or median values? Response; See Figures 2-1 and 2-2 of OUFS. 10. Question/Comment; PLA is used to designate wells. Should it be said that PLA = PGA? Response; Although the airport name has been changed, the well designations have not been changed. 11. Question/Comment; Is TDS concentration of 3,900 ppm in Subunit A an average for all measurements? Response; Yes. See page 3-2 of OUFS. 12. Question/Comment; Unidynamics does not, and never has had, a separate production well for its water supply. The City of Goodyear has always provided water to the facility. Response; See Chapter 2 of OUFS. 13. Question/Comment; For comparison purposes, it would be easier if the zip patterns in the legends of Figures 3-1 and 3-2 were consistent. Response; See Figures 3-1 and 3-2 of OUFS. 14. Question/Comment; On page 5-2, various alternatives could be linked more directly to Figure 5-1 by labeling each bullet with abbreviations from Figure 5-1, such as GAG, GAC & PGA, Section 16, etc. Response: See page 5-2 of OUFS. 15. Question/Comment; On Figure 5-1, steam stripping is listed but never discussed in the text of that section. Response; Steam stripping is discussed in Table 7-2. None of the screened out alternatives are discussed in the text. See Table 7-2 of OUFS. 16. Question/Comment; On page 5-5, what is Storm Treatment? Response; A typographical error—should have been Steam Treatment. See page 5-5 of OUFS. 17. Question/Comment; On page 7-17, line 18, "backing" should be packing. Response; See page 7-17 of OUFS. 18. Question/Comment; On page 7-26, under General Assump- tions, will monitoring wells, as well as influent and efflu- ent wells, be sampled for analysis on a weekly basis? Response; This frequency was used as a cost basis. The actual sampling frequency will be determined during the remedial design phase. RD/R9/018 B-3 ------- FROM EPA, AIR TOXICS OFFICE, AMD 1. Question/Comment; We recommend that you consider sev- eral design and operating factors for the stripping towers during the design stage of the project. Response; The design and operation factors have been received from your office and will be considered during design. 2. Question/Comment; Although ambient air concentrations in the vicinity of the stripping tower would be expected to be low, you may want to consider some initial ambient air monitoring. This has been performed at other Superfund sites to demonstrate to interested parties that concentra- tions are in fact as low as expected. Response; Air sampling will be added to OU operations. FROM U.S. ARMY CORPS OF ENGINEERS, OMAHA DISTRICT 1. Question/Comment; Subunit B/C should be evaluated more carefully in light of recent and forthcoming data. Reinjec- tion of treated effluent for plume control should be care- fully evaluated and considered. A technical memo outlining new information would be helpful in making decisions con- cerning remediation of Subunit B/C. Response? The OUFS stage is considered to be a 10-percent design. It is con- ducted to compare several alternatives that can provide an- expeditious response to the contamination hazard while not being inconsistent with the final remedy. Deep wells being installed at this time will provide additional data to be incorporated into the design. It has been determined that the best approach to Subunit B/C is to allow Loral Corp- oration and the airport to continue pumping as they cur- rently do, and conduct an extensive groundwater monitoring program. 2. Question/Comment; Information available at the time this OUFS was prepared does not adequately define the con- taminant plume and is insufficient to design an extraction scheme. Work in progress may be sufficient; however, addi- tional work may be required during the design phase. Bench and/or pilot scale treatability testing will be necessary to properly design the proposed treatment system. Response; Comment will be noted in final OUFS. Bench and/or pilot scale testing is planned for final design of the air stripping process. 3. Question/Comment; On page ES-1, the word "minor" in sentence "Other VOC's have been identified sporadically and in minor concentrations..." is misleading as it seems to indicate that these levels are inconsequential when in fact some exceed regulatory standards. See Chapter 3, Table 3-2. Response; See page ES-1 of OUFS. RD/R9/018 B-4 ------- 4. Question/Comment; On page ES-2, 8th bullet, clarify that this refers to treated groundwater. Response; See page ES-2 of OUFS. 5. Question/Comment; On page ES-5, the definition given for rehabilitation is inaccurate. Response; See page ES-5 of OUFS. 6. Question/Comment; On pages ES-5 and 6, rehabilitation and level of treatment seem redundant. Clarify the distinc- tion between these two. Response; Rehabilitation refers to aquifer treatment. Level of treatment under Treatment Alternatives refers to treatment of extracted groundwater. 7. Question/Comment; On page 2-1, 4th paragraph, clarify that Unit A should be Subunit A. Response; See page 2-1 of OUFS. 8. Question/Comment; On page 2-1, 4th paragraph, you say, historically, groundwater flow direction under Section 16 is to the southwest. However, flow has been more westerly than southwesterly in the UAU. Clarify. Response; There are not enough data to conclusively state whether the flow is more southwesterly or west by southwesterly due to occasional fluctuations. . 9. Question/Comment; On page 2-2 there is reference to PGA well No. 3 as having the highest level of TCE. The location of this well should be indicated on appropriate drawings. Response; The well location is indicated as PLA3 on Figure 2-3. 10. Question/Comment; Clarify what contaminant concentra- tions represent in Figures 2-2 and 2-3. Response; They represent single event values. 11. Question/Comment; The historical waste disposal prac- tices section does not provide a comprehensive understanding of past chemical use and disposal practices. More investi- gations should provide a clearer picture; however, a detailed and quantitative determination will probably not be possible. The information presented in this report has been compiled from many sources and may be accurate for certain periods of operations only. The nature of the information—verified from more than one source, secondary, etc.—should be identified. Response; Comment will be noted in final OUFS. EPA is continuing to try to determine the history and source(s) of contaminants at the site. 12. Question/Comment; Re page 2-9, 1st paragraph, avail- able information indicates that most of the Goodyear facil- ity was owned by Southwest Cotton Company/Goodyear Tire/ RD/R9/018 B-5 ------- Aircraft. Several small parcels, which apparently consisted of a portion of the building referred to as Building/ Hangar 6 and several very small areas, were purchased by the Gov- ernment in 1943. A greater portion of the Goodyear facility was purchased by the Government in 1947. The entire "plant" area (present facility) was quitclaimed to Goodyear Aircraft in 1950. Response; See page 2-7 of OUFS. 13. Question/Comment; Re page 2-11-14,, it should-'be clari- fied that the entire aircraft was usually not covered with the protective coating, only key sections of the aircraft that would be prone to moisture-induced corrosion s.a. open- ings, fabric surfaces, etc. Stripping consisted of peeling of the coatings manually and not by use of chemical strippers, except for early coatings on windows which were removed with ammonia or alcohol. Latex materials were used in protective coatings for some portion of the total time of operations. Coatings used included "liquid envelope" and later "spraylat." "Gunk" was not used in stripping of protective coatings and was probably used more extensively for engine degreasing or to degrease metal surfaces prior to preservation, again a limited portion of the airplane. Also note that many air- planes stored were fabric and dope structure. 4 While the Airport property was transferred to the City of Phoenix in 1968, Navy operations ceased prior to 1 July 1967 Response; See pages 2-9 through 2-14 of OUFS. 14. Question/Comment; Re page 2-14, more recently acquired information indicates that most drums and other chemical containers were returned to suppliers for reuse and that little if any local disposal of containers occurred. Response; See page 2-12 of OUFS. 15. Question/Comment; Re page 2-15, drawings ("as-built") on file with the City of Phoenix should be consulted for details on the washrack and drainage system design and con- struction and these discussions corrected/clarified appropri- ately. The washracks still exist, much as constructed. Response: See page 2-13 of OUFS. 16. Question/Comment; Re page 2-15, describe sources of information on historical activities, such as statement con- cerning air flotation not being used. Was source directly involved with treatment plant operation, i.e., did source have direct knowledge? Response; Historical information came from the Source Verification Report, Ecology and Environment, Inc. January 1986. See page 2-13 of OUFS. RD/R9/018 B-6 ------- 17. Question/Comment; Re Table 2-4, it should be made clear that this table does not indicate either relative or absolute amounts of chemicals used. Response; Unnecessary due to no mention of amounts. 18. Question/Comment; Re page 5-2, for clarity, the ini- tial paragraph under GROUNDWATER ALTERNATIVES should include pumping as well as no-action and containment, then the pump- ing alternatives detailed. Response; See page 5-2 of OUFS. 19. Question/Comment; . Re page 5-2, area NW of runway should be excluded for pumping Subunit B/C based on no concentrations reported above 1 ppb in that area. Response; The decision to include this area was not based on data, but on suspected contamination. New data will provide an opportunity for reevaluation. 20. Question/Comment; Re Chapter 6, information available at the time this OUFS was prepared does not adequately define the contaminant plume and is insufficient to design an extraction scheme. Work in progress may be sufficient or additional work may be needed during the design phase. Response: See previous response. 21. Question/Comment; Re page 6-1, monitoring is usually, considered part of the no-action alternative. Response; ' See page 6-1 of OUFS. 22. Question/Comment; Re page 6-3, a discussion of prob- able molecular diffusion rates into "dead" zones is needed. These areas would be subject to reverse gradients as cleanup continues. Since it is unlikely that significant volumes of contaminant would be tied up in these zones, this is a super- fluous discussion. Sorbed contaminant soil particles in dewatered zones is of greater concern. Response: The diffu- sion of contaminants into low permeability units can be an important process. Such units can act as long-term sources for contaminants, thus delaying total cleanup. See, for example, Gilliam, et al, (1984), An Advection-diffusion Concept for Source Transport in Heterogeneous Unconsolidated Geological Deposits, Water Resources Research, Vol. 20, No. 3, pp. 369-378. As noted, sorbed (or otherwise slowly mobile chemicals) in the vadose zone can be another long-term source of contaminants. See page 6-3 of OUFS. 23. Question/Comment: Re Table 6-2, the choice of 10 pore volumes for extended cleanup gives an unrealistically conservative estimate of cleanup time. Note difference between values given on page 9-7 and Table 6-2. Response; The time required for cleanup is not known. For the purposes of comparing alternatives, five pore-volumes were used. RD/R9/018 B-7 ------- 24. Question/Comment; Re Figure 6-4, it is evident that capture zones greatly exceed the targeted cleanup area under this alternative. Note "stagnant" zones near divides between cones - the "accelerated" nature is not apparent. Response; This alternative was presented to provide a wide choice of cleanup. Appropriate capture zones will be developed during the remedial design activities. 25. Question/Comment; Re Figure 6-6, 7, 8, these scenarios should be reconsidered in view of more recent monitoring well data. Response; All pumping alternatives will be reeval- uated with new data during design. 26. Question/Comment; Re page 6-21, it is not clear if the combined effect of contaminated groundwater withdrawal and normal seasonal pumping will impact nearby wells. Please clarify. Response; There is no seasonal pumping of Subunit A. Water levels in Subunit A will be maintained in accordance with remedial design parameters. See page 6-21 of OUFS. 27. Question/Comment; Re page 6-22, it is not clear if declines in Subunit A water levels (because of the proposed extraction of contaminated water) has been considered in estimating transmissivity for the subunit and hence for per- formance of the extraction wells. (Efficiency is reduced as drawdown occurs.) Please clarify. Response: Drawdown effects were considered. A typical guideline of maintaining drawdown in the pumping well at less than two-thirds of the available drawdown was followed. Drawdown in most of the Subunit A zone is expected to be less than 20 percent of the saturated thickness. See page 6-22 of OUFS. 28. Question/Comment; Re page 6-24, for the monitoring wells, it was assumed that three per extraction well was sufficient. This was apparently applied across the site regardless of location. In areas of numerous existing wells or densely spaced extraction wells, this number of new wells may not be necessary. More detailed analyses should be per- formed for actual numbers of monitoring wells needed. Response: Three wells were chosen for cost estimating pur- poses. A more detailed analysis will be done during design. 29. Question/Comment: Re page 7-7, the OOFS should include an expanded discussion concerning the necessity of pilot testing. Pilot testing could determine pretreatment require- ments (due to high TDS and sulfide levels), evaluate or con- firm the mass transfer efficiency of a particular packing, verify removal efficiency, verify mathematical model, clar- ify off-gas pretreatment requirements and design parameters, possible scaling problems, anti-scaling problem design con- siderations, etc. Response: Bench testing will be con- ducted during design. RD/R9/018 B-8 ------- 30. Question/Comment; Re page 7-16, chemical feed system design and potential problems associated with scaling need to be addressed. This is particularly important with the high concentrations of TDS and sulfate in Subunit A. With the high concentrations of sulfate, there is a good possi- bility of a manganese sulfide precipitation, this would probably require removing the filter media for cleaning of the precipitate. An estimate on the frequency and approxi- mate down time in the system operation should be analyzed. These factors should be addressed briefly in the OUFS and in detail during pre-design and design. Response; Research on this factor is currently being done by GAG. This will be addressed in detail during predesign and design. 31. Question/Comment; Re page 7-16, onsite versus offsite cost comparisons should be analyzed for carbon regeneration. Has ttie cost of an onsite or the operational cost of offsite carbon regeneration been incorporated into the estimate? Response; Onsite regeneration is part of the carbon adsorp5- tion alternative. The onsite costs included significant fluctuations as to overlap costs for offsite regeneration. 32. Question/Comment; Re page 7-17, indicate how/where the disposed scale cleaning solution could be disposed of and the cost associated with that disposal. Response; See pre- vious response. • 33._ Question/Comment; Re page 7-17, has the impact (environmental and O&M considerations) of an influent pipe rupture been considered? Response: A detailed risk assess- ment will be conducted during design. 34. Question/Comment; Re page 7-18, carbon usage could be evaluated in pilot study. Response; It will be. 35. Question/Comment; Re page 7-27, the impact of the high TDS on treatment should be addressed in more detail. Impact (including impact on costs) could be significant. See also comments on pages 7-16 and 7-17. Response: See response to those comments. 36. Question/Comment; Re Chapter 8, address the advantages and disadvantages with combining the treatment and collec- tion lines in the preferred alternatives. Also indicate the cost benefits that would be obtained by combining the treat- ment for Subunit A and B/C. It seems that if the treatments proposed are similar or identical that they could be com- bined. Response; A detailed analysis will be conducted during design. Alternatives for Subunit B/C are not included in this remedy. 37. Question/Comment; Re Chapter 8, a discussion of the potential use of reinjection for plume control should be RD/R9/018 B-9 ------- included. Effluent piping costs would decrease as may over- all treatment costs/time. This must be addressed—if not ir the OUFS, then in the OU predesign phase. Response; see page 8-15 of OUFS. 38. Question/Comment; Re page 8-5, include, if available, the water quality in Subunit B/C. This information will be helpful in determining water quality of the influent to the air stripper. Response; See Table 8-2 of OUFS. 39. Question/Comment; Address items which should/could be considered for implementation/construction with the OU facilities which would facilitate implementation of the final remedy—s.a. to lay additional piping, providing space for additional stripping towers, etc. Response; A detailed analysis will be conducted during design. 40. Question/Comment; Re page 9-13, reinjection wells will undoubtedly need rehabilitation and/or replacement. (Cost estimates should reflect this.) Response; This will be addressed during predesign and design. 41. Question/Comment; There is no discussion of the fine tuning of the design through testing during the construction phase and use of wells during the startup and operation phases. This need not be addressed in detail at this point but should be addressed during the subsequent project phases. Response; This will be addressed during predesign and design. FROM ARIZONA DEPARTMENT OF WATER RESOURCES 1. Question/Comment: The Middle Fine-Grained Unit at the site is actually 800 to 1,000 feet thick at the site, and the Lower Conglomerate Unit is thicker than 1,000 feet. Response; See pages ES-1 and 2-1 of OUFS. 2. Question/Comment; The PLA well No. 3 is also referred to as the PGA well No. 3. This is inconsistent. Response; The well designations have never been changed. The correct designation is PLA well No. 3. 3. Question/Commentt There should be some mention of the recent purchase of the Goodyear Aerospace Corp. facility at the site by the Loral Corporation. Response: See page 2-9 of OUFS. 4. Question/Comment: Regarding current conditions and land use, agricultural land use would seem to be more related to industrial-based mixed use than recreational-based mixed use. Response; See page 3-4 of OUFS. RD/R9/018 B-10 ------- 5. Question/Comment; General response actions and tech- nologies: Justification for applicable response actions should make some statement to the effect that there are • technologies which have been proven to be effective in -the past. Also', rejection of in situ treatment should state that the time required to effect cleanup is excessive. Response; See Table 4-2 and Chapter 7 of OUFS. 6. Question/Comment; The Arizona Department of Water Resources has jurisdiction over contamination problems and the proposed remedial alternatives impacting the ongoing water conservation efforts within the Phoenix Active Management Area. Response; See page 6-1 of OUFS. 7. Question/Comment; Regarding RESSQ modeling, a statement should be made to the effect that, due to the uncertainties inherent in the RESSQ model, final remedial alternatives will be determined with the results of the numerical modeling efforts currently underway. Response; Remedial alternatives will be addressed in detail during the remedial design period, including placement of wells and pumping rates. This will take into account all new data and models which are available. See page 6-4 of OUFS. 8. Question/Comment; On page 9-1 under PUMPING; suggest replacing the word "significantly" with "sufficiently." Response; See page 9-1 of OUFS. FROM GOODYEAR TIRE AND RUBBER COMPANY 1. Question/Comment; The Goodyear Tire and Rubber Company submitted its comments in the form of a preferred alterna- tive report. Their preferred alternative is to treat all groundwater in Subunit A in Section 16 using air stripping; however, they have offered an alternate scheme for extrac- tion and reinjection. This alternative includes five extraction wells and nine injection wells. The injection wells would serve to recharge the aquifers of Subunit A and to provide contaminant plume control to force contaminants towards the extraction wells. Response; The use of injec- tion wells to enhance plume recovery is not justified under the current state of knowledge at the site. Injection wells will cause an increase in the hydraulic gradient downward to Subunit B/C in the vicinity of the wells. High permeability conduits or holes in the aquitards could cause contaminants to move into presently uncontaminated areas as a result of injection. In addition, the proposed location of the injection wells is actually within the contaminated plume. Reinjection into contaminated groundwater will enhance the rate of spreading of contamination both laterally and vertically. In view of this, injection wells should be rejected at the present time for the purpose of plume RD/R9/018 B-ll ------- control. Additional information may become available to warrant consideration of injection wells at the time of final remedy selection. The' drawdown of groundwater levels and the pumping water levels in the wells apparently have not been calculated. This is an important consideration in designing the extrac- tion well field. 2. Question/Comment; Goodyear also recommends that EPA delay pumping and treating Subunit B/C groundwater for the following four reasons: (1) The remedial investigation to define the areal extent of contamination in Subunit B/C is still ongoing. The outstanding data are essential for selecting the optimal location of Subunit B/C groundwater recovery wells and evaluating treat- ment alternatives. Response; EPA intends to make a final selection for remedial action in Subunit B/C when additional data are available. (2) Subunit B/C groundwater is pumped continuously for use by the Loral Corporation and the Phoenix- Goodyear Airport as process and drinking water. The extraction, combined with pumping Subunit A • groundwater to prevent migration of contaminants, will slow or stop contaminant migration and pro- vide some measure of cleanup to Subunit B/C ground water. As shown by EPA in Table 6-5 of the "Public Comment Feasibility Study," Subunit A groundwater contains 95 percent of the TCE contamination in the Upper Alluvial Unit. Response; The current extraction of groundwater may or may not prevent contaminant migration. Additional monitoring wells are necessary to determine the hydraulic effect of the existing and future wells. (3) Adverse health effects from postponing extensive treatment of Subunit B/C groundwater will be negli- gible. Recently acquired data suggest that con- tamination in Subunit B/C is in the immediate vicinity of production wells on Loral and airport properties. The affected population is supplied with treated or carefully monitored drinking water to protect human health. EPA's Public Comment Feasibility Study states on page 3-3: "West of the City of Goodyear, most of the land is currently used for agricultural production. Some smaller areas of residential development exist outside of Goodyear, but these are several miles to the west of the city." Growth of the city is expected to be to the west. If the City of Goodyear expands RD/R9/018 B-12 ------- its extraction network in light of the projected population increase, the new wells are not likely to exhibit contamination, nor are they likely to become contaminated since pumping of Subunit A groundwater will halt any migration of contaminants. Response; There is no proof that new wells to the west are not likely to be contaminated. The area downgradient of the site will need to be monitored on a long-term basis to ensure that contaminated groundwater is not being pumped and delivered to a municipal or private system. (4) There is a technical advantage to delaying extrac- tion of Subunit B/C groundwater. The different aquifer characteristics of Subunits A and B/C indi- cate that the water level in Subunit B/C will drop much faster than that of Subunit A if the two are pumped simultaneously. Under such conditions, the potential for downward migration of contaminants will greatly increase. Pumping Subunit A alone for a period of time will lower the Subunit A watex level and alleviate possible problems if a decision is made to increase pumping from Subunit B/C. Response; Although the comment is strictly true, the fact that a vertical downward gradient has existed for many years at the site suggest that there is little advantage in delaying additional installation of wells and pumping of the B and C subunits. 3. Question/Comment; On page 2-10 of the "Public Comment Feasibility Study for Section 16 Operable Unit, dated June 1987, the text reads: "Only one of the six is currently being used as a source of drinking water, and GAC, the owner, is providing bottled water as an alternative." GAC (Goodyear Aerospace Corporation) did offer bottled water at its facility when groundwater contamination was first dis- covered, but has since installed a carbon adsorption/reverse osmosis treatment system to produce safe drinking water. Response: See page 2-5 of OUFS. 4. Question/Comment: On page 2-10, Table 2-2 estimates that GAC disposed of 31,000 gallons of halogenated and non- halogenated solvents between 1949 and 1974. The only docu- mented onsite disposal of solvents (not necessarily TCE) by GAC was a small volume placed in a lined drying bed in 1971. Because there is no sound basis for the total quantity of 31,000 gallons for the corresponding time period, Goodyear requests that the value be omitted. In addition, the foot- note "a" is inappropriate for the 4,900 gallons specified for 1,1,1-trichloroethane. That volume is a documented, RD/R9/018 B-13 ------- offsite disposal quantity, not an approximation. Response; Volumes generated by disposal practices are currently being investigated. See Table 2-2 of OUFS. 5. Question/Comment; It should be noted on Table 2-2 that the 12 tons of chromate sludge placed in onsite disposal pits contained relatively nontoxic, immobile trivalent chro- mium and- not hexavalent chromium. Also, when the pits were closed in 1980, a total 383 tons of soil, sludge, and fabric liner were excavated and transported to an offsite disposal facility. Response: Volumes have been removed from Table 2-2. 6. Question/Comment; Figure 2-4 on page 2-12 contains some errors and omissions in locations of legend numbers. The plant powerhouse, Circle 24, is actually adjacent to Building 16, Circle 5. The 1,1,1-trichloroethane storage tank, Circle 25, belongs in the northwest corner of Buildings 1 and 2. Circle 19 is missing from the parking lot east of Litchfield Road. Table 2-3, the legend to Figure 2-4, also requires some cor- rection. Items 2 and 3, Buildings 1 and 2, are currently mostly manufacturing, not offices as stated. Item 6, Build- ing 76, was built in the 1940's, not in 1976. Item 7, Building 70, formerly was used for shipping and receiving ' but currently is used as storage space. Item 8 used to be a general storage building and now serves as office space; it was never used for virgin chemical storage. Item 10 is the virgin chemical storage building. Item 11, Building 50, was constructed in the 1980's and not the 1960's. Response: See Figure 2-3 and Table 2-3 of OUFS. FROM EPA, REGIONAL ADMINISTRATOR'S OFFICE 1. Question/Commentt Several of the proposed maximum con- taminant levels are now Safe Drinking Water Act maximum con- taminant levels. Proposed drinking water treatment levels have been changed-to reflect those levels. Also, EPA has issued a health advisory that chloroform should not exceed 0.5 parts per billion in drinking water. Drinking water standards exceed Ambient Water Quality Criteria. Response: The new material has been received and will be incorporated. See Table ES-1 of OUFS. 2. Question/Comment: In the section that identifies ARARs, there should be consideration given to other criteria and health advisories. Response: See page 1-1 of OUFS. 3. Question/Comment; On Table 3-3, there needs to be a total cancer risk assessment for all chemicals identified. RD/R9/018 B-14 ------- Why is Unidynamics mentioned? 1,1-DCE is not a carcinogen. Response; See Table 7-3 of OUFS. FROM EPA, OFFICE REGIONAL COUNSEL 1. Question/Comment; Shouldn't containment technology be included in the surviving technologies? Response: Yes, this technology will be added. See Chapter 9 of OUFS. 2. Question/Comment; Is the DCE target level accurate? The arsenic treatment target level does not comply with AWQC. Response; The target level for DCE has beed changed to reflect the new SDWA maximum contaminant levels. Arsenic will be addressed in the overall feasibility study. See Table ES-1 of OUFS. 3. Question/Comment; SARA is the Superfund Amendments and Reauthorization Act of 1986. Response; See page 1-1 of OUFS. 4. Question/Comment; For chromium the MCL is more strin- gent than the AWQC. Response; The correct MCL and AWQC are the same. 5. Question/Comment; On page 2-15 "floting" should be floating. Response; See page 2-13 of OUFS. • 6. Question/Comment; On Table 3-3, why reference Unidynamics?Response; See Table 3-3 of OUFS. 7. Question/Comment; Are attainable removal rates of TCE 99.9% or 99.99%? Response; 99.99%. See Table 7-1 of OUFS. 8. Question/Comment; On page 7-15 the discussion of RACT is very cursory. Response; An operable unit feasibility study is considered to be a 10% design, and as such the description of control technologies is sufficient. 9. Question/Comment: In Table 7-4, it is indicated that the expected removal efficiency from subunit B/C is 94/95%. This should be noted and discussed earlier in the screening. Response; See page 7-12 and Table 7-4 of OUFS. 10. Question/Comment: Table 7-4 focuses on 10 E-6 cancer risk as removal criterion. Table 7-5 focuses on either 5 ppb or background. Does this distort the comparison? Response; The different removal requirements for meeting the various levels of cleanup has no effect on the compari- son of technologies. If the required removal of contami- nants to meet ARARs were also entered on Table 7-4, Air Stripping, the values would be the same as they are on Table 7-5, Activated Carbon. See Tables 7-4 and 7-5 of OUFS. RD/R9/018 B-15 ------- 11. Question/Comment! On page 9-1, note that in situ treatment was also screened out. Response; See page 9-1 of OUFS. 12. Question/Comment: Why do you need to design and con- struct wells for surface discharge? Response; To extract contaminated groundwater and to monitor groundwater quality. FROM EPA, TOXICOLOGY 1. Question/Comment; Consistent with my oral comments to you and the contractor during the second week of June of the "Draft Preliminary Public Health Endangerment Assessment" for this site, quantitative expressions of risk should be presented in a way to indicate that they are upper-bound estimates developed using many, mostly conservative, assump- tions about both the potential toxicity and exposures to man. Therefore, phrases such as "risks up to" or "risks may be as much as" should precede quantitative risk numbers presented in Table 3-3 (pp 3-19). Response; See Table 3-3 of OUFS. 2. Question/Comment; Furthermore, the "uncertainties..." section on pp. 3-21 should be expanded to include additional areas of uncertainty inherent in the quantitative risk esti- mates, e.g.: a. Toxicity (1) Choice of bioassay (2) Choice of data, e.g., tumor site, tumor type (3) Dose conversion, i.e., relationship between applied dose of the parent chemical to target organ dose of the active chemical (possibly different than the parent chemical). (4) Extrapolation from animal to man b. Exposure. Type of data; uncertainty increases as data available becomes more remote from the likely receptor (e.g., biological measurements in blood, tissues, etc. personal monitors concentrations in media plus modeling uptake emission data plus model- ing fate, transport, and update...) Response: See page 3-21 of OUFS. 3. Question/Comment: The treatment level options under active consideration include (a) no action, (b) removal to meet ARARs, and (c) treatment to background levels. In option (b), the AWQCs are considered to be among the ARARs. For nearly all the organic contaminants at the site the RD/R9/018 B-16 ------- AWQCs are the most conservative and drive the proposed treatment level (Table 1-1 and Table 7-1). The AWQCs may not be appropriate target treatment levels for two reasons. First, for carcinogens, the AWQCs are concentrations in drinking water which present an estimated cancer risk of less than 10 E-6. From a public health perspective this level of protection may be unduly restrictive given the fact that subsequent treatment (chlorination) of water for drinking may produce halomethanes at concentrations in excess of those predicted to present cancer risks of 10 E-6. Second, headquarters has recently provided additional guidance on compliance with ARAR requirements (July 9, 1987 memo from J. Winston Porter to Regional Administrators and Division Directors) which states that MCLs should be used when available and that "The Agency is still formulating a position with respect to the use of FWQC (AWQC) for protection of human health." Response: The water will be treated to attain MCL's. See Table ES-1 of OUFS. 4. Question/Comment; Will the public have a major role in selecting, from among the treatment options considered implementable, sufficiently effective, and technically feasible (those presented in Chapter 9), the specific treatment to be enforced at this site? Response; The public and appropriate agencies will have a major role in selecting the options as evidenced by the treatment of groundwater in aquifers of Subunit B/C. RD/R9/018 RD/R9/018 B-17 ------- |