United States Environmental Protection Agency Office of Emergency and Remedial Response EPA/ROD/R04-93/164 September 1993 SERA Superfund Record of Decision: Savannah River (USDOE) (Operable Unit 7), SC ------- 50272-101 REPORT DOCUMENTATION '• REPORT NO. PAGE EPA/ROD/R04-93/164 3. Recipient1* Accession No. 4. THK «nd Subtitle SUPERFUND RECORD OF DECISION USDOE Savannah River (Operable Unit 7) , SC Fifth Remedial Action 5. Report Date 09/10/93 6. 7. Authors) 8. Portormlng Organization Rapt No. 9. Performing Organization Nam* and Address 10 Project Task/Work Unit No. 11. Contract(C)orGram(G)No. 12. Sponsoring Organization Nam* and Address U.S. Environmental Protection Agency 401 M Street, S.W. Washington, D.C. 20460 13. Type of Report*. Parted Covered 800/800 14. 15. Supplammtaiy Notes PB94-964019 16. Abstract (UmH: 200 words) The US DOE Savannah River (Operable Unit 7) site is part of the 300-square mile Savannah River Site (SRS) facility located in Aiken, Barnwell, and Allendale Counties, South Carolina. Land use in the area is predominantly agricultural, with no residential uses. The Savannah River Site (SRS) is a secured, national defense-related facility, co-operated by the Westinghouse Savannah .River Company, that produces tritium, plutonium, and other special nuclear materials. The site also provides nuclear materials for the space program, and conducts medical, industrial, and research efforts. From 1955 to 1988, the central area of the site, termed the H-Area, was used as a Hazardous Waste Management Facility (HWMF). The H-Area HWMF consists of four unlined, earthen surface impoundments located near the center of SRS. During its operation, the facility received waste effluents from H-Area chemical separation facilities processes such as a nitric acid recovery unit, waste storage system evaporator overheads, and general purpose evaporator overheads. In 1962, one of three basins was closed and replaced by a fourth basin. The three remaining basins had a combined maximum operating capacity of 26.5 million gallons of wastewater. Significant amounts of nitrate and caustic were received from wastewater discharge into the H-Area basins, and these radioactive releases to the three basins were greater than 99 percent (See Attached Page) 17. Documant Analysis a. Descriptors Record of Decision - USDOE Savannah River (Operable Unit 7), SC Fifth Remedial Action Contaminated Medium: None Key Contaminants: None b. Mantlfian/Opan-EndadTanns c. COSATI Bold/Group 18. Availability Statement 19. Security Class (This Report) None 20. Security Class (THs Page) None 21. No. of Pages 20 22. Price (See ANS1-Z39.18) See Instructions an R»nn* OPTIONAL FORM 272 (4-77) (Formerly NTO-35) ------- EPA/ROD/R04-93/164 USDOE Savannah River (Operable Unit 7), SC Fifth Remedial Action Abstract (Continued) tritium. Several studies showed that 90 percent of the radionuclides/ cations, and anions were concentrated within the top 1 foot of basin soil. In 1988, a RCRA closure plan for the site was developed. The closure of the H-Area HWMF began in 1989, and was completed in early 1991. Closure activities included removing standing water remaining in the 3 original basins and in the basin added in 1962; stabilizing the basin sludge with a layer of granite, limestone, and blast furnace slag; constructing a low permeability multi-layer cap over the basins; and restoring the area. The site closure prevents physical exposure to contaminants and mitigates further migration of contaminants from the H-Area HWMF to ground water through rainwater percolation. The H-Area HWMF is being routinely inspected for a minimum of 30 years and institutional controls, including deed restrictions, have been implemented. This ROD addresses contaminated soil and sludge in the H-Area, as OU7. Future RODs will address the ground water beneath the site. EPA investigations indicate that the previous RCRA closure of the site sufficiently has reduced the threat to human health and the environment; therefore, there are no contaminants of concern affecting this site. Future RODs will address the remaining OUs at this site. The selected remedial action for this site is no further action, with ground water monitoring. EPA has determined that the previous RCRA closure of the site has prevented the risk of physical exposure to site contaminants, reduced further migration of site contaminants to ground water, and that the site poses no threat to human health and the environment. However, as a condition of the RCRA Hazardous Waste Permit, post closure ground water monitoring is required to verify that no unacceptable exposures to potential hazards posed by conditions at OU7 occur in the future. There are no present worth or O&M costs associated with this no action remedy. PERFORMANCE STANDARDS OR GOALS: Not applicable. ------- WSRC-RP-93-1043 Revision 1 September 2, 1993 UNITED STATES DEPARTMENT OF ENERGY SAVANNAH RIVER SITE FINAL RECORD OF DECISION REMEDIAL ALTERNATIVE SELECTION FOR (bui) H-Area Hazardous Waste Management Facility (U) Prepared by WESTINGHOUSE SAVANNAH RIVER COMPANY SAVANNAH RIVER SITE AIKEN, SC 29802 PREPARED FOR THE US DEPARTMENT OF ENERGY UNDER CONTRACT DE-AC09-89SR18035 ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF . REV.1 September 2, 1993 DECLARATION FOR THE FINAL RECORD OF DECISION Site Name and Location H-Area Hazardous Waste Management Facility (HWMF) Savannah River Site Aiken County, South Carolina Appendix H of the Federal Facility Agreement (FFA) lists this unit as the H-Area Hazardous Waste Management Facility (Building Numbers 904-44G, 904-45G, 904-46G, and 904-56G). Statement of Basis and Purpose This document presents the selected final preventive action for the H-Area HWMF Operable Unit at the Savannah River Site (SRS), which was developed in accordance with the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA), as amended by the Superfund Amendments and Reauthorization Act of 1986 (SARA), and to the extent practicable, the National Oil and Hazardous Substances Pollution Contingency Plan (NCP). This decision is based on the Administrative Record File for this unit Description of the Selected Remedy The selected final action remedy involved the stabilization and placement of all contaminated materials under a low permeability cap. This remedy prevents physical exposure to contaminants and mitigates further migration of ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF REV.1 " September 2, 1993 contaminants to the groundwater by minimizing a liquid medium pathway (rainwater percolation) for transport. No further action is necessary for the unit. However, as a condition of the RCRA Hazardous Waste Permit, post closure groundwater monitoring is required to verify that no unacceptable exposures to potential hazards posed by conditions at the operable unit occur in the future. The major components of the preventive action included: 1) Elimination of free liquids by removing liquid waste and solidifying the remaining waste and residues, 2) Stabilization of the remaining wastes to a load bearing capacity sufficient to support the cover system, 3) Placement of a final cover over the surface impoundment. The cover consists of a layer of backfill, a nine inch sand layer, a two foot layer of compacted kaolin clay, a geotextile fabric, topped with two feet of topsoil to support a vegetative cover. (See below) u Vegetative Cover Top Sol (2 ft) Geotextile Fabric Sand Drainage Layer (9 In) Low Permeability day Layer (2 ft) dean Soil Backfill and Contour Layer Limestone and Blast Furnace Slag (1 ft) Granite Aggregate (3-6 ft) Basin Sediments II ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF % REV.1 * September 2, 1993 4) The H -Area HWMF is being routinely inspected for a minimum of 30 years to verify the integrity of the cover system, fences, signs, etc. Any necessary repairs to the cap will be made as part of the maintenance program. 5) Access to the H-Area HWMF is restricted to authorized personnel with appropriate training on applicable requirements. The survey plat and records associated with deed restricted use of the H- Area HWMF have been filed with Aiken County, SC. Declaration Statement Previous action taken at the H-Area HWMF was under a RCRA Closure Plan approved by the state of South Carolina and was protective of human health and the environment. Therefore, no further remedial action is necessary under CERCLA. To ensure continued protection of human health and the environment, this remedial action will be reviewed every 5 years, consistent with the requirements of the NCP. 1. Roberson I Assistant Manager for Environmental Restoration and Solid Waste U.S. Department of Energy Patrick M. Tobin Acting Regional Administrator, U.S. Environmental Protection Agency Region IV III ------- WSRC-RP-93-1043 Revision 1 September 2, 1993 SUMMARY OF FINAL ACTION REMEDIAL ALTERNATIVE SELECTION FOR H-Area Hazardous Waste Management Facility (U) Prepared by WESTINGHOUSE SAVANNAH RIVER COMPANY SAVANNAH RIVER SITE AIKEN, SC 29802 PREPARED FOR THE US DEPARTMENT Of ENERGY UNDER CONTRACT DE-AC09- ------- FINAL ROD WS.RC-RP-93-1043 H-AREA HWMF REV.1 ! September 2, 1993 DECISION SUMMARY TABLE OF CONTENTS Section Page I. Site and Operable Unit Names, Locations, and 1 Descriptions II. Operable Unit History and Compliance History 4 III. Highlights of Community Participation 7 IV. Scope and Role of Operable Unit within the Site 7 Strategy V. Summary of Operable Unit Characteristics 7 VI. Summary of Operable Unit Risks 8 VII. Explanation of Significant Changes 9 Appendices A. References for Development of ROD Format 10 B. Responsiveness Summary 11 ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF REV.1 , September 2. 1993 I. Site and Operable Unit Names, Locations, and Descriptions The Savannah River Site (SRS) occupies approximately 300 square miles (483 km) adjacent to the Savannah River, principally in Aiken and Barnwell Counties of South Carolina (Figure 1). SRS is a secured facility with no permanent residents. The site is approximately 25 miles (40 km) southeast of Augusta, Georgia, and 20 miles (32 km) south of Aiken, South Carolina. The average population density in the counties surrounding SRS ranges from 23-560 people per square mile (60-1452 per square km) with the largest concentration in the Augusta, Georgia, metropolitan area. Based on 1980 census data, the population within a 50-mile (80 km) radius of SRS is approximately 555,100. SRS is owned by the United States Department of Energy (DOE). Westinghouse Savannah River Company (WSRC) is the manager and operating contractor for DOE. SRS produces tritium, plutonium, and other special nuclear materials for national defense. The site also provides nuclear materials for the space program, and conducts medical, industrial, and research efforts. The H-Area HWMF is a source specific operable unit within the H-Area Fundamental Study Area. The H-Area HWMF consists of three unlined, earthen surface impoundments located in the center of SRS, southwest of Road E and north of road 4 approximately 6 miles (10 km) from the nearest site boundary (Figure 2). ------- FINAL ROD H-AREA HWMF WSRC-RP-93-1043 REV.1 September 2. 1993 SAVANNAH RIVER SITE Figurel Location of the Savannah River Site (SRS) (Source: Modified from the Savannah River Environmental Report, 1990) ------- FINAL ROD H-AREA HWMF WSRC-RP-93-1043 REV.1 September 2. 1993 Figure 2 H-Area HWMF (Source: Modified from the EIO for the H-Area Seepage Basins, 1987) ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF REV.1 _ I September 2, 1993 II. Operable Unit History and Compliance History Operable Unit History The H-Area HWMF operated from 1955 until November 7, 1988. The original H-Area HWMF consisted of basins H-1, H-2 and H-3 and operated from 1955 to 1962. In 1962 H-3 was replaced by H-4. The dimensions and volumetric capacity of the basins were as follows: H-1:90 ft x 240 ft x 9 ft, 1.1 million gallons H-2:110 ft x 460 ft x 9 ft, 2.8 million gallons H-3:350 ft x 480 ft x 17 ft, 9.4 million gallons H-4: (130-430) ft x 2400 ft x 8 ft. 22.6 million gallons At the time of closure, the H-Area HWMF (basms H-1. H-2, and H-4) had a combined maximum operating capacity of 26.5 millcn gallons of wastewater. The H-Area HWMF received waste effluents from H-Area chemical separation facilities processes such as the nitric acid recovery urut. waste storage system evaporator overheads, and general purpose evaporator overheads. The H-3 basin was not a RCRA regulated un< but was identified as a RCRA 3004(u) unit requiring investigation and rem«<*ation. It was decided to incorporate basin H-3 into the RCRA closure. The four basins were dosed by dewatering. pnyacafty and chemically stabilizing the remaining sludges and placing a prate** mutHayer cover system (Figure 3) over them reduce rainwater contact w9> basin bottoms. ------- FINAL ROD H-AREA HWMF W-SRC-RP-93-1043 REV.1 September 2, 1993 Vegetative Cover Top Soil (2 ft) Geotextile Fabric Sand Drainage Layer (9 In) Low Permeability Clay Layer (2 ft) Clean Soil Backfill and Contour Layer Limestone and Blast Furnace Slag (1 ft) Granite Aggregate (3-6 ft) Basin Sediments Figure 3 H-Area HWMF Cap Cross Section ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF REV.1 ' September 2, 1993 Compliance History Preventive actions at the H-Area HWMF were conducted pursuant to the requirements of the Resource Conservation and Recovery Act (RCRA) per Settlement Agreement 87-27-SW. In 1988, a RCRA Closure Plan was submitted to the South Carolina Department of Health and Environmental Control (SCDHEC). The closure plan underwent several revisions prior to approval by SCDHEC in 1989. Closure of the unit was begun in 1989 and completed in May 1991. The H-Area HWMF was certified closed in July 1991. In October 1991, the closure certification was accepted by SCDHEC as being in compliance with RCRA requirements. A RCRA Part B Permit Application for Post-Closure Care was submitted in December 1990 and a Hazardous Waste Permit was effective November 1992. Closure activities specifically included removal of standing water remaining in the basin; stabilization of the basin sludge with a layer of granite, limestone, and blast furnace slag; construction of a low permeability cap over the basin; and restoration of the area. Preventive activities at the H-Area HWMF became subject to CERCLA when the entire SRS facility was placed on the National Priorities List (NPL) in December 1989. The H-Area HWMF is a source-specific operable unit within the H-Area Fundamental Study Area. ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF _ REV.1 " September 2, 1993 III. Highlights of Community Participation The public review period that ran from 18 June 93 - 2 August 93. SCDHEC submitted comments on the Proposed Plans which have been incorporated into this ROD, where appropriate. IV. Scope and Role of Operable Unit Within the Site Strategy The selected remedy involved the placement of all contaminated materials under a low permeability cap. The remedy prevents physical exposure to contaminants and mitigates further migration of contaminants from the H-Area HWMF to groundwater by minimizing a liquid medium pathway (rainwater percolation) for transport. V. Summary of Operable Unit Characteristics Waste effluents from H-Area chemical separation facilities processes such as the nitric acid recovery unit, waste storage system evaporator overheads, and general purpose evaporator overheads were discharged to the H-Area HWMF. Significant amounts of nitrate and caustic were received. Radioactive releases to these basins were greater than 99% tritium. Several studies were conducted to characterize the subsoils. A 1984 soil coring study showed that approximately 90% of the radionuclides, cations, and anions were concentrated ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF RE V.I " September 2. 1993 within the top 1 foot of basin soil. The chemicals of concern at the H-Area HWMF are arsneic, barium, cadmium, lead, mercury, cobalt-60, copper, nickel, vanadium, zinc, tetrachloroethylene, gross alpha, gross beta, nitrate, radium- 226, radium-227, tritium, iodine-129, strontium-90, technetium-99, uranium- 233/234, and carbon-14. VI. Summary of Operable Unit Risks Due to the previous H-Area HWMF RCRA preventive action, No Further Action under CERCLA is necessary for this unit. The RCRA preventive action is protective to human health and the environment and satisfies CERCLA requirements. Contaminated sediments of the H-Area HWMF were stabilized in the basin during closure. The basin then was covered with a low permeability soil cap. Therefore, exposure through surface soil and sediment pathways is minimized because of this RCRA cap. Preventive alternatives were developed for the H-Area HWMF based on effective technologies available at the time the RCRA Closure Plan was prepared. The RCRA Closure Plan was initially submitted to SCDHEC in early 1989 and was approved, following several revisions, in Junel989. 8 ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF REV.1 ' September 2, 1993 Options regarding the H-Area HWMF evaluated at that time included: Alternative 1 No Action Alternative 2 No Waste Removal, Waste Consolidation, Treatment, and Closure Alternative 3 Waste Removal and Closure Alternative 2 was selected within the RCRA closure process in 1988 as the most technically effective of the three alternatives for protection of human health and the environment. Closure of the H-Area HWMF was begun in 1989 and completed in July 1991. The closure certification was accepted by SCDHEC in 1991 as being in compliance with RCRA and state requirements. The closure is considered a final action under CERCLA VII. Explanation of Significant There were no significant changes. ------- FINAL ROD WSRC-RP-93-1043 H-AREA HWMF REV.1 . ' September 2, 1993 Appendix A References for Development of ROD Format Weeks, Victor, 1993. "Regarding Records of Decision, F-Area and H-Area, Savannah River Site, Aiken , South Carolina", Letter to Goidell (DOE), Savannah River Site, Aiken, SC, April 14, 1993. EPA, 1991. "Guide to Developing Superfund No Action, Interim Action, and Contingency Remedy RODs," OSWER Publication 9355.3-02FS-3, U.S. Environmental Protection Agency, Washington, D.C., April 1991. WSRC, 1992. "Draft RCRA Facility Investigation/Remedial Investigation Program Plan," WSRC-RP-89-994, Chapter 15, Westinghouse Savannah River Company, Aiken, South Carolina, May 1992. 10 ------- |