PB85-245306
Part 2 of 2
Industrial Process Profiles for Environmental Use. Chapter lOb Plastics
Additives
Radian Corp., McLean, VA
Prepared for
Environmental Protection Agency, Cincinnati, OH
Jul 85
U.S. DEPARTMENT OF COMMERCE
National Technical Information Service
NTIS
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TABLE A-i5 (Continued)
BoIUI18
Iblnt. "C ~1f1c Flash AppUcabIl1ty to IbljllEr 'I)pe
1blecu1ar Solubility (li!lt1l1l! Q-avlty Iblnt (See FIrst I'a&I' of Table for IbIiJer Code) .
OeId.c:al ~ Water Alcohol ~ Fo1nt )t (at 2O"C) "C (a:x:)1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26
nvmrs (luble Soluble S:>luble 77 o.!m 7.2 X X X
[W:PXI:il5)
I!thylbenzene [Cdl~il5J 106. 2 Insoluble S:>luble S:>luble 136. 2 0.867 15 X X X X X
Furfuryl alcd-ol 9fU S:>1uble S:>luble S:>luble 170 1.1285 75 X
[CtlljX1lpl) or
(~(J]j:fll)
a.ptane [CIl3(~)9I3) 100.2 Insoluble S:>luble S:>luble 98.4 0.68368 -3.9 X X X X
(closed
cup)
Hexane [CIl3(W2)4W3) 86.2 Insoluble S:>luble 68.7 0. 6603 -23 X X X X X X
-I"
-1"" IaohJtane [See 0Ia1n Transfer X X
..... Agmta)
IsohJtyl alcohol [See ODin X
Transfer Agents)
Iaohd:yr1c sel.d 88.1 S:>luble S:>luble 154.4 0. 94(M). 950 77 (T(C) X X
(W3)proI)
Isooctane 114.3 Insoluble Slight 99.2 0.6919 -12 X X
(W3>jXlIpI(CIl3>2 J
I.sopentane 72.2 Insoluble \l!ry Sllght S:>luble 27.85 0.61967 -57 X X
(W3)prnpl3)
Isopropyl alcohol (See ODIn X X X
Transfer Agents)
Isopropyl benzene [See 0Ia1n X
Transfer AgmtB (Omne»)
Kerosene Insoluble Hlseible 18>-300 0.81 38~5 X X X
(Continued).
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TABLE A-15 (Continued)
i 8011108
! 8>1nt, "C ~flc Flash App11cabIUty to 8>lyuer Type
."
j 1b1ecuJar Solubt11ty (Helt!ng G"avlty 8>1nt (See First Page of Table for IbDber Code)
a1n X X X
1
i Transfer Agents)
,
! &\.9 40.1 1.335 (15°)
.1 "'thylene d11or1de [0I;F12) Sl1ght Soluble Nonflam- X X X
I mable
,
, !t!thyl ethyl ketone [See
!
: 2-futamne)
"'thyl tsoh.d:yl ketone 100. 2 SUght Hl.sclble 115.8 a. 1042 23 X X
[(0I3);PDIpnl3)
!t!thyl lsob1tymte 102.2 X
~ H1neral all X X
~
N tbphths Hl.sclble 160 a. 86HJ.892 -49 X X X
Nitrobenzene [CdI?J21 123.1 SUght . Soluble Soluble 210. 9 1.19867 88 X X
R!ntsne (0I3(0I2):PI3) 72.2 Insoluble \A!ry SUght Soluble 36.07 a. 62624 -49 X X X X X
3-ft!:ntamne [Dlethyl ketone), 86.2 SUght Soluble 101 0.816 13 X
[CiI~zH5)
2-Propmol (Isopropyl alodx>l), X
[See O>a1n Transfer Agent)
1 n;>ropyl acetate 102.2 SUght H1sclble Hl.sclble 96-102 0.887 14 X
"I
j [Cjlpmi31
,,:] Pyridine (~(OI):P,') 79.1 Soluble Soluble Soluble 115.5 a. 978 20 X X
1,1,2. 2'"l'etrafluorodlchloro- Insoluble 3.55 X
:! ethane [CClF;FClF21. (Freon
:/ 1141
:'1 Tetrahydrofuran 72.1
Soluble Soluble Soluble 66 0.888 -15 X X X
1?';PI;P';PI
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i TABLE A-15 (Continued)
.j
I
1
I
,
;
i lIoi ling
Rl1nt, "C ~1fic Flash Applicability to Rll}lDl!r Type
1b1ecu1ar Solubility (Helt~ IDvity R>1nt ~See Flmt Page of Table for IUJb!r Code)
C1emI.cal ~ Water A1.ocb>l ~ R>1nt)t (at 20"C) "C (ax)' 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26
SLVfNl'S (OXltlrned)
'lbluene [See (})ain Transfer X X XX X X X X X
Agents J
Tr1ethylamtne [See O1ain X
Transfer Agents I
2, 2,4-'l'r1.uEthylpentsne [See
Isooctane I
I Water X X X X X X X X X X
I
i Xylene [Cdl4(Q!3)21 Insoluble S:>luble S:>luble 0.86 27-46 'X XX X X X X
!
,
.J:- 1JIICI(EIUS
.J:-
\,.0.) Glycerol [Cjl5«(I\)3] S:>luble S:>luble Insoluble 2!n >1.249 160 X
(25")
Glycols X
Po1yglycols X
.i
!
j
RXJOOl1!:S :
..
.0,
j
m,y for boiling point, (aeltl'1! point): d - decaIp>ses.
'%y for flash point: co:: - C1evelsm Open (lJp; To:: - 'DIg1lsbJe Open CIJp.
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/
TABLE A-16. ULTRAVIOLET STABILIZERS
PHYSICAL AND CHEMICAL CHARACTERISTICS WITH POLYMER APPLICATION
UIe
So1ubility "'lting ~1nt Specific (hn;:en- Applicability to ~lyaer Type (lUJiJer Coded Below)
(Boiling ~nt), \y- lbo:Ier 12H~ 1.345 0.1-1.5 X X
~ [Uv1ml 0-49)
2, 2' -llihydr0xy-4.".,tIoxybEnzopIe- lbider Soluble 68-70 1.382 0. 2S- 3.0 X X X X X
mne (Cyasorb IN 24) (160-170 (7o-1~ (25"1:)
'J 111»
,
2,2' -llihydr0xy-4(octoxy)benzo....
phemne (Cyasorb IN 314)
DJ.sod1... 2, 2' -dihydroxy-4, 4' -di- Ibwder >350 0.1-1.5
uetlmty-5, 5'-disu1foko~...""..
(1M..w. 00-49)
4-ibdecyloxy-2-hydraxyb."~""",,,,, lbo:Ier Insoluble Soluble 43-52 4.1 Ibs/gal 0.2s-2.0 XX X X X X X X X X X X X X
(Ry1ex D) Flakes
tmE: 1 - AcrylJc Resi...; 2 - Acryloo1tri~ene-5tyrme; 3 - Alkyd Resi...; 4 -1IIIino Resi...; 5 - ~r1ng 1hemq>lastica (lblypht!ny\a1e Oxide and ~lypheny\a1e !Wiide); 6 - Epoxy Resins;
7 - Fluoropolyaera; 8 - 1beno11c Resins; 9 - ~lyacetals; 10 - ~lyam1de Besl...; 11 - ~lytutylene; 12 - ~lY1=3r1x>nate; 13 -lI1gh o....lty Iblyethylene; l4 - Llnear Inw o....lty ~lyethylene;
15 - low o.mity Iblyethylene; 16 - Iblyethy\a1e Terephthalste/lblytutylene Terephthalste; 17 - ~lypropylene; 18 - ~lystyrene/
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TABLE A-16 (Continued)
,i
I
J
'I lIIe
I Solubility I2lUng l\)io1 ~f1c (ba:en- Applicability to l\)lym>r Type (See First Page of Table for IbItJer Code)
, 'I (BoiU. l\>1nt), Ihvity tmUm Fm
I Ultrsvio1et Stabilizer Form Water ~ "I: at 20"1: ,Z Sancticot 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27
j BmlOH£NH!S «(bnt1roed)
,
j 4(\Ieptyllub1e 62-63.5 1.324 0.1-1.5 X XXX X X X X X X X
IlMml H 40), ICyasorb \JV9) (150-11;0 (670 (25"1:)
.) Pa»
" 2-flydraxy-Jl_th>xy-s-..ethylbenzo-
! phemne Ilbiatat 2211 I
.I:'- 2-11ydroxy-s-tInly""''''''''.''''''''
.I:'-
lJ1 2-11ydroxy-l ~1nIy-S-SUUobenzo- Ibwder 145
ptemne 11Mml16-401
2-flydraxy-Ji_th>xy-5-sulfobenzo-
phencne ICyasorb 1N-28$)
2-11ydroxy-4-n-octyIIub1e 48-49 1.160 0.1-1.0 X XXX X X X X X X X X X X X X X X
ICya90rb IN 531) (25"1:)
Hark 1535 U..,Id 0.1-1.0 X X X X X X X X X X X X
Peruvi 8100 l!UbstUlJted li>enmel ftMIer 03. -0. 7 X X X X X X X X
Resyn 7!H1121 11011 molecular
weit1It alkyl methal:rylatIMlUbsU-
tuted benzophenone)
2,2' ,4,4'-'l'etrahyd~IZOtJI>eooo'" RMler 1.216
IlMml D-50)
IMml 4!n Imixture of 2,2'-«hy- Ib«Ier Hixture 8) 1.084 0.1-1.5 X X
draxy-Jl, 4' -d1meth>xyb.,.~.e
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TABLE A-16 (Continued)
\Be
Solubility Itlltlng 1\)1nt ~f1c Oxan- Applicability to I\)lymr Type (See First Page of 'nIble fot IiIai>er Code)
(80m. I\)int), Ibrity tmtfm FIl.
Ultraviolet Stabilizer Form Water ~ "I: at 20"1: Z Sanctiont 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27
) I!I'NlDIRIAZIli
2(3'-t-lUtyl-2'-hydroxy-5'-methy1- Ibder Insoluble Sligltt 14(}.141 0.1-3.0 X X X X X X X X X X X
phenyl)-5-chlorobenzotriazole
(Tiruvin 3261
2( 3' ,5'-i!l-t-bJtyl-2' -hydroxy- Ibder Insoluble Soluble 154-158 1.20 0.1-3.0 X X X X X X X X X X X
;.': pheny 1)-5-chlorobenzotriazole
"1 (Tiruvin 3271
.1 2(2' -ffydroxy-3' ,5-di -t"""""l- Ibder Insoluble Soluble 81 0.91 0.1-3.0 X X X X X X X X X X X X
oJ phenyl)benzotriazole (UlIJIIin 3281 (391(d»
j o.i-3.0
I 2(2' -ffydroxy-3' ,5' -
-------
,
J
. !
I
.1
1
"
".1
.!
. j
..!
TABLE A-16 (Continued)
Solubility
!Be
Ibrrsr-
tratlm
%
Ultraviolet Stabilizer
~
M>lting IV1nt !Peclfic
(80ili'1l R>tnt). Invity
"C at 20"<:
1.21 (1.1-0. 5 X X X X
1.11 0.1-2.5 X X X X
1t>1IIB1 X X X
5.(>-10.0 X X X
0.1-1.0 X X X X
1.13 (25"C) 0.2~.5 X X X X X
0.1-1.5 X X X X
HISCI!IJ.AIIDf), N:RYIA:IEi
&l:yl 2-cyano-J.1nethyl-3-(p-meth- Uqu1d
oxyphenyl)acrylate (IN Absorber
311)
N-{B~t'balletlGtyv1nyl)- Ibwder 98 0.~5.0 X X X X X X
2.".,thylindol1ne (IN Absorber 3401
Ethyl 2-cyano-3,3-diphenylacrylate Ibwder 96-98 1.164
(IMrul 1+-35)
2-ahylhexyl 2-cyano-3,3-d1pi1enyl- Uquid -10 1.()(j8 ..
acrylate (Uvirul 1+-539)
tt.thyl-2-carbooJ!tlDxy-3-{p-ueth- RMler 56
oxyphenyl)acrylate (Cyaaorb
1N-l988)
"'thyl 2-cyano-).".,thyl-3-{p-ueth- RMler 65-85
oxyphenyl)acrylate (IN AbsorlEr
318)
Form
Water
NJaQ!L 2g)(d)
10% Nickel Hex-Cem
Uquid
10011 IE III
IIolleta
Sarmwr NI\J (R>enylmethyl-
decamyl pyrazolat~) .
(2,2' -'Ihiobls( H-octylpbeno-
lato) }-u-bJtylamine nickel
(Cyaaorb IN 1081t)
Ibwder
14G-160
Ibwder
Soluble
258-261
.t:-
.t:-
-...J
IN Ihek ltH-205
F1aItes
Applicability to IVlyuer Type (See First I's&I! of Table for IUIb!r Code)
1 2 3 4 5 6 1 8 9 10 11 12 13 14 15 16 11 18 19 20 21 22 23 24 25 26 21
FD\
s.u.:Uwt
140
(Continued)
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'. .
''Ii"
TABLE A-16 (Continued)
UIe
Solubility Ii!1ting 1\:>1nt ~f1c Qn:en- Applicability to I\:>lyaer Type (See FIrat Page of Table for IUIi>er Code)
(Bolli. RI1nt), (hvlry trstim FD\.
Ultravlolet Stabilizer Fom Water ~ "C at 2O"C % So""'!mt 1 2 3 4 S 6 1 8 9 10 11 12 13 14 IS 16 11 18 19 20 21 22 23 24 2S 26 21 . ~
Hl&EIJJI/I!XUI, SALICYIAlES
~-a.tyl Ji>enY1 aalieylate (b1Dr1eaa Insoluble Soluble 62-4i6 0. 2-0. 6 X X X X X X X X X X X
~tal
10316 OOP HP (I'roprtetBryl Pellets 10.0 X X X
Dlpropy1ene glycol aaUcylate Uqu1d Insoluble Soluble 1.16 (4O"C)
(C:tI6(axx:dltIB)OC:l!6(IJ I
2-Ethylhexyl aalicylate
p-Octylp.,nyl aalieylate !WIer Insoluble Soluble 12-14 So 6 llll/gal 0.5-2.0 X X X X
(CdltJHIXx:dltI=I#I11 I
(Inh1bltor OPSI
RJenyl aalieylate Solid !prlngly Soluble 42 1.2614 X X X X X X
(Cdl4c:mxx:dlsl (112-113)
.I:'- p-{I,I, 3.:HI!tr8lll!thylbJtyl)phenyl
.I:'- salieylate (See Octylphenyl ~.. or
00 aa11eylatel
; '.
aJIIfR HIS£EUAItDl) AND
l'RJI'RIF:D\Ry
AST-l00l lJ.qu1d 1. ()-50. 0 X X X X X X X X X
Bar1uD metaborate. lIIXI1f1ed lbwder )1(XX! 2.()-10.0 X X X X X X X X X X X
81s(2, 2, 6, 6-1:etrsmethyl-4-p1perl- X X X X
d1noxy)selDcate
aortoo black (CI Ibwder Insoluble Insoluble X X X X X X
OrlIIBsoorb 9It4 (IIlndered BIII1ne I lb.der 0.1-0.4 X X X X
C;aJm-2164 (IIlndered amine I lb.der
C-PIR-1DJ4 (IIlndered BIII1ne I lb.der
C-PIR-ImS (IIlndered amine I lb.der
(Continued)
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TABLE A-16 (Continued) L
I
'!
!lie
Solubility "'lUng Iblot ~nc
HllHUEfARY (1hnt1nued)
(bpper 1odid! ftJwder I'nmluble W6 5.653 X
(l5"C)
; 0.
2,~bEI1my1 nsorclm1 ~tala Insoluble Soluble 125-128 l. ~
3, Sill ~-bJty1.,,-bydraxybenzoic Ibwder 200-210 0. 5-1.0 X X X X
acid ~ . : .
2, 4-Dl ~-bJty1jh!ny 1-3, 5-dJ. ~- ftJwder 196 0.2-1.0 X X X X
luty1-4~raxybenzoate [IN 0Iek
Nt-340)
2, 4-Dl ~-bJty1jh!ny 1-3, 5-dJ. ~- ftJwder 196 0.2-1.0 X X X X
luty1-4~raxybenzoate
Dlmethy1-2-( 4"11Etlmtybenzylidene)
~ IIBlonate
~
\0 sIh>rlc tr1am1de liquid Soluble Soluble (2D-239) 1.llll X
[Imib1tor HPrI (16"1:)
Ibstavln H2O ~talline I'nmluble 225 0.1-1.0 X X X X X X X X
Ibwder
2-(2-ilydraxy-4"11EtIDxybenzoy1)
benzoic acid [Cyasorb IN 207)
H3ng;mese 1od1d! Solid Soluble 638 5.01 X
Pambolir-l00 Uqu1d 0.1-10.0 X X X X ,x
1'1)1-0199 [I:enzophenooe/hlndered X X X
amine mixture I
10328 ft! lIB, UD59 ft! III l\!1leta 2.IHI.O X X X
'40375 PI' HP [lI1ndered amine] l\!1leta 1.0-2.0 X
, . (Continued)
..
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TABLE A-16 (Continued)
UIe
; Solubility IWting fulnt ~fic O>ncen- AppUcability [0 fulyaer Type (See First l'a8e of Table for It1d>er Code)
1 (Boiling fu1nt), Q-avity tmUm FD\
. ! Ultraviolet Stabilizer Fom Water ~ "I: at 20"1: % 5aIx:tiont 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 t
. ~ 0llI!R IillD!IlAIIDS All) r
lHJHUErARY (lhnt1n!ed) i:
ResorclnollIDIObenzmte RMIer Sl4!J>t Sl4!J>t 132-135 1.0-2.0 X X X X ,.
[Cdl9JX:dItJII ) (1110 (20 III» i
t
SaIWvor ERJ [axalanitideJ lbwder 116-124 0.1-0. 5 X X X X
f.:
SaIWvor \ISU [axalaniUdeJ lbwder 127 0.1-0. 5 X X X X X !
Tiwvin 144 [stellrlca11y Idndered lbwder 150 0.1-0.5 X X X X X X X X
amine)
l1nuv1n 770 [llteadeally Idndered RMIer 150 0.1-0.5 X X X X X X X X
amI.ne )
Tlwvin 662 [hindered .mne ) lbwder Inaolubl.e (300) 0.2~1.0 X X X
Ti tanIuD dl.mdde lbwder Inaolubl.e Inaolubl.e X
.po
VI IJV-O>ek 541A lbwder 0.1-2.0 X ,X X
0
IlV-01eclt Rt-595 lbwder 0.1;-2.0 X X X
IUnatay L [phoapmte-qpe RMIer 2.W 3.0 ,X
lltabilizer ) 1Jf!I,.3
Zinc odde Rlwder Inaolubl.e Inaolubl.e >110) 5.47 2.0-10.0 X ~ X X X X X X X
FOOIHJIES: fIhe Federallleglster and Code of Federal ~UOO9 detail uv StabiUzers approved for food contact appUcatlom. FD\ Sanctions are giW!l1 for specific c:hBn1cals and ,.
approval is generally based ..,.,.. extent of extraction of the stabilizer fraa the polyaer. ItudDuD use concentrations ...y also be delineated. '!he Code of Federal
ReIPJlationa aubplrts 175.105 for adhesiws; 177.26W for rubbers and 178.2010 for plaat1ca IIhJuld be conauited [0 determine s'pecific reg.Jlatlons for UV Stabilizera.
.i
i
;
,
'1
i
,
I
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APPENDIX B.
CONSUMPTION AND OTHER USES FOR PLASTICS ADDITIVES
Antioxidant
PHENOLICS
l,2-Bis(3,S-di-t-butyl-4~hydroxyhydro-
cinnamoyl)hydrazine (Irga.ox MD 1024)
. 2,6-Bis(1-methylheptadecyl)-p-cresol
4-«4,6-Bis(octylthio)-s~triazin-2-yl)-
amino)-2,6-di-t-butylphenol
Bisphenol A (CH3)2C(C6H40H)2)
Butylated Bisphenol A (Vsnox 1004)
.p.
\J1
I-'
Butylated hydroxyanisole (BBA),
(CH3)3CC6H30H(OCR3»)
Butylated hydroxy tOluene (BHT), (DBPC),
(Di-t-butyl-p-cresol)
Butylated octylated phenol
Butyiated resction product of p-cresol and
dicyclopentadiene
Butylated styrenated cresols
. !
4,4'-Butylidenebis(6-t-butyl-m-cresol)
(Ssntowhite powder)
Cyclohexylidenebis(2-cyclohexylphenol)
2,6-Di-t-butyl dimethyl smino-p-cresol
(Ethanox 703),
(C4H9)2C6HZOR(CH2N(CH3)2»)
2,6-Di-t-butyl-4-ethylphenol
TABLE B-1.
Consumptiont
1.4 x 108 kgs (75)
(total)
1.9 x 105 kgs (80)
(in plsstics)
6.4 x 106 kgs (80)
(in plastics)
ANTIOXIDANTS
. .
!!!!
Intermediate in manufacture of epoxy, poly~arbonate, phenoxy,
polysulfone snd certsin polyester resins, flame retardsnts,
rubber chemicala
Antioxidant for fats and oils, food psckaging
30% antioxidant in rubber, 30% antioxidant in plastics, 20%
antioxidant in petroleum, lS! sntioxidant in food snd animal
feed, 5% in miscellaneous applications
Antioxidant for rubber, dry or latex
(Continued)
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Ant ioxidant
PHENOLICS (ContInued)
3,5-Di-t-butyl-4-hydroxybenzyl alcohol
(AntioxIdant 7541
3,5-Di-t-butyl-4-hydroxyhydroclnnamlc
acid, 1,3,5-trIa(2~lydroxyethyl)-s-
trlazIne-2,4,6(lH,3H,5H)-trlone (Good-Rite
31251
2,6-Di-t-butyl methylamino-p-cresol
2,4-Di(o-methylbenzyl)-4-methylphenol
Dioctadecyl(3,5-di-t-butyl-4-hydroxy-
benzyl)phosphonate (Irganox 10931
Hexamethylenebis(3.5-dI-t-butyl hydroxy-
cinnamate) (Irganox 2591
.po
VI
N
N,N-Hexamethylenebis-(3.5-di-t-butyl-4-
hydroxyhydrocinnamamide) (Irganox 10981
2(-4-Hydroxy-3.5-c-butylanillno)-4.6-bls-
(n-octylthio)1.3,5-trlazine (Irganox 5651
4-Hydroxymethyl-2.6-dI-t-butylphenol
3-Methyl-6-t-butylphenol/crotonaldehyde
condensate
2.2-HethylenebIs(6-t-butyl-4-ethylphenol)
(Cyanox 4251
2,2'-Methylenebis(6-t-butyl-4-methyl-
phenol) (See 2.2'-Hethylenebis(4-methyl-
6~t-butylphenol)1
TABLE B-1 (Continued)
Consumption t
!!!!
Antioxidant for gasoline and other hydrocarbons
f ~
(
f
. .
,.
V
:,'
(Continued)
-------
Antioxidant
PHENOLICS (Continued)
4.4'-Hethylenebis(2.6-di-t-butylphenol)
[Ethanox 702)
'j
j
'j
j
j
'I
i
1
~
"
2.2'-Hethylenebis(4-methyl-6-t-butyl
phenol) [CAO 5). [Bis(2-Uydroxy-3-t-
butyl-5-methyl phenyl)methsne). [Cyanox
2246)
2.2-Hethylenebis(6(I-methylcyclohexyl)-p-
cresol) [Nonox WSP)
2.2-Hethylenebis(4-methyl-6-nonylphenol)
[Naugswhite)
4-Hethyl-2-(1-methylcyclohexyl)phenol
[Nonox WSLJ
.p.
lJ1
l.U
Octsdecyl 3.5-di-t-butyl-4-hydroxyhydro-
cinnamate [Irgsnox 1076)
Phenol alkylated with approximately 1:4
ratio of 2,3-Benzofuran and Indene
[Nevastain A). [Nevastain B)
Tetrakis(methylene(3,5-di-t-butyl-4-
hydroxyhydrocinnamate»methane [Irganox
1010)
4.4'-Thiobis(6-t-butyl-m-cresol)
[ Santonox)
4,4'-Thiobis(6-t-butyl-o-cresol)
[Antioxidant 736). [Santonox R)
.' j
1
,
.1
,i
.,
""j
'j
2,2'-Thiobia(6-t-butyl)-4-methylphenol)
[CAO 4)
"j
"1
TABLE B-1 (Continued)
Consumptiont
5.4 x 105 kgs (80)
(1n plastics)
1.3 x 106 kgs (80)
(1n plastics)
Use
Oxidation inhibitor and antiwear agent for motor oils. avia-
tion piston engine oils. and industrial oils; antioxidant for
rubbers. resins and adhesives
Antioxidant
.,
Protection of light-colored rubber from oxidation and of non-
stainin8 neoprene compounds against deterioration; antioxi-
dant for olefins
(Continued)
-------
j
. ,
!
!
.' ,
Antioxidant
PHENOLICS (Continued)
4,4'-Thiobis(2-t-butYl)5-methylphenol)
(see 4,4'-Thiobis(6-t-butyl-m-cresol»)
. i
Thiodiethylenebis(3,5-di-t-butyl-4-
hydroxy)hydrocinnamate (Irganox 1035)
j
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2,2'-(3,5,5-Tri8ethylhexylidene)bis(4,6-
dimethyl phenol) (Nonox WSO)
1,3. 5-Trimethyl-2.4,6-tris(3. 5-di-t-
butyl-4-hydroxybenzy1)benzene (Ethyl 330)
1.3, 5-Trh(4-t-butyl-3-hydroxy-2, 6-
dimethylbenzyl)l,3,5-triazine-2,4.6-(lH,
3H,5H)-trione (Cyanox 1790)
.po
l/1
.po
1.3,5-Tria(3.5-di-t-butyl-4-hydroxy-
phenyl)methyl-1,3,5-triazine-2,4,6(lH,3H,
5H)-trione (Good-Rite 3114)
Tris(2-methyl-4-hydroXY-5-t-butylphenyl)-
butane [Topanol CA)
AROMATIC AHlNES
N-(1.3-Dimethylbutyl)-N'-phenyl-1.4-
benzendiamine [Vulkanox 4020)
Di-S-naphtha-p-phenylenediamine
'1
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.-- j
4-Isopropyl-N'-phenyl-p-phenylenediamine
[Vulkanox 1040 NA)
4 -( 1-ttethyl-l-phenylethyl)-N-( 4-( 1-
methyl-l-phenylethyl)phenyl)benzenamine
[Naugard 445)
.; .~
.J
I
TABLE B-1 (Continued)
Consumptiont
Uae
Antioxidant .for polypropylene. high-density polyethylene,
spandex fibera, polyamides and specialty rubbers
!
Protection of rubbers against oxidation. ozone. f1ex-cracking
and poisoning by copper and manganese
(Continued)
-------
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Antioxidant
THlOESTERS
Dicetyl thiodipropionate
Dilauryl thiodipropionate
Dimethyl thiodipropionate
Dimyristryl thiodipropionate
Distearyl thiodipropionate
Ditridecyl thiodipropionate
.J:-
VI
VI
Hixed lauryl-stearyl thiodipropionate
[Cyanox 1212)
Pentaerythrit01 tetrakis(B-lauryl
thiodipropionate)
PHOSPHORUS COHPOUNDS
J
I
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Alkylaryl bisphenol phosphite
Bis-tridecyl phosphite
2-t-Butyl-a(3-t-butyl-4-hydroxyphenyl)-p-
cumenyl-bis(p-nonylphenyl)phosphite
Dibutyl phosphite
Didecyl phosphite
D1isodecyl pentaerythritol phosphite
[Weston 600)
,
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TABLE B-1 (Continued)
Consumptiont
1.1 x 106 kgs (80)
(in plastics)
1.4 x 105 kgs (80)
(in plastics) .
1.1-1.4 x 106 kgs
(80) (in plastics)
>4.5 x 102 kgs (15)
(total )
Use
Antioxidant; additive for high-press~re lubricants and
greases; plasticizer and softening agent; antioxidant for
edible fsts and oils; stabilization of food packaging films
Antioxidant; plasticizer; softening agent
Stabilizer; plasticizer and softening agent for plastics;
lubricant additive
'.
Solvent; antioxidant; intermediate
(Continued)
-------
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Antioxidant
PHOSPHORUS COMPOUNDS (Continued)
Diisodecyl pentaphosphite
Dilauryl phosphite (C1ZHZ50)ZPHO)
;
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.!
Dimethyl phosphite (CH3P)ZPHO)
Dioctyl phosphite [(C8H1JO)zPHOI
Dioleyl phosphite
..~
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;
Diphenyl decyl phosphite
«C6H50)ZPOCloHzl I
Diphenyl isodecyl phosphite [Weston DPDPI
~
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Diphenyl phosphite [Weston DPPI
Distearyl pentserythritol diphosphite
[Weston 618)
.' I
Ditetradecyl phosphite [Dimystryl
phosphite I
i
..1
Isooctyl diphenyl phosphite [Hark CI
Octyl diphenyl phosphite
Phenyl didecyl phosphite
[C&" sOP(OCI oH2l hi
Tetrakis(Z,4-di-t-butyl)phenyl-(I,l-bi-
phenyl)-4,4'-diylbisphosphite
[Sandostab P-EPQI
Tributyl phosphite [(C4HgO)3PI
,
,
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.
TABLE B-1 (Continued)
Consumptiont
>4.5 x 10Z kgs (15)
(total)
>4.5 x 10Z kgs (15)
(total)
5.9 x 105 kgs (80)
(1n plastics)
i
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Use
Synthesia of organic phosphorus compounds for extreme pres-
sure lubricants, adhesives, textile finishing agents, pesti-
cides; catalyst in polymerization of unsaturated compounds
Lubricant additives; intermediate; sdhesive; fire retardant
.(
Solvent; antioxidant; intermediate
Antioxidant
,.
Chemical intermediate; stabilizer for polyvinyl and polyole-
fin resins
Synthesis of organophosphorus compounds
Chemical intermediate; antioxidant; ingredient in stabilizer
systems for resins
Additive for greases and extreme-pressure lubricants; stabi-
lizer for fuel oils and polyamides; gasoline additive
(Continued)
-------
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Antioxidant
"
PHOSPHORUS COMPOUNDS (Continued)
Trldecyl phoaphite (CloHzO)3P)
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Trllaodecyl phoaphite (Weston TDP)
Trilsononylphenyl phosphite
i
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Trilsooctyl phosphite (Weston TIOP)
Triisopropyl phosphite
( (CH3>2CH)3P03)
Trilauryl phosphite (Weston TLPj
Trilauryl trithiophosphite (Weston TLTTP)
..
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Trlmethyl phosphite (CHjJ )3P)
Trioctyl phosphite
(Tria-2-ethylhexyl phosphite).
(C4HgCH(C2H5)CHzO)3P)
Triphenyl phosphite (C&"50)3P)
Tri(polynonylphenyl)phosphite (Polygard)
,
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Tris(2-chloroethyl)phosphite
(CIC2H40)3P)
,.
Tris(2.4-di-t-butylphenyl)phosphlte
Trisnonylphenyl phosphite
Trisnonylphenyl phosphite/formaldehyde
polymer (Wytox 438)
,
. i
!
Tristearyl phosphite (Weston TSP)
TABLE B-1 (Continued)
ConsumpUon t
>4.5 x 102 kgs (75)
(total)
>9.1 x 102 kgs (75)
(total )
7.7 x 105 kgs (80)
(in plasUcs)
Use
Chemical intermediate: stabilizer for polyvinyl and polyole-
fin resins
i
~ .
Intermediate for insecticides: component of vinyl stabI-
lizers; lubricant additive: specialty solvent
Intermediate for insecticides: component of vinyl stabi-
lizers: lubricant additive: specialty solvent: antioxidant
Stabilizer in polymers: chemical intermediate
Stabilizer: lubricant: chemical intermediate
Chemical intermediate,., especially for insecticides
Synthesis; plasticizers: stabilizers; lube and grease addi-
tives: flameproofing compositions
Chemical intermediate: stabilizer system for resins: metal
scavengerj diluent for epoxy resins
Intermediate: component of vinyl stabilizers; grease addi-
tives; flameproofing compositions; color inhibitor in esteri-
fication '
(Continued)
-------
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1
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Antioxidant
MISCELLANEOUS, QUINONES
p-Benzoquinone [C6H402)
2,5-Di-t-butylhydroquinone
Hydroquinone (C6H4(OH)2)
Hydroquinone monomethyl ether
[CH3OC6H40H)
.po
VI
00
Mono-t-butylhydroquinone
[C6H3(OH)2C(CH3)3)
Toluhydroquinone (CH3C6"3(OH)2J
MISCELLANEOUS, OTHER
D1stearyl disulfide
Msrk 1475 (N-(2H,l,2,4-triazol-5-yl)-
sal1cylamide)
Thermolite 31 (Bis(isooctyloxycarbonyl-
methylthio)dibutylstannate)
Thiodipropionic acid
[HOOCCH2SCH2CH2COOH)
Zinc dibutyldithiocarbamate
[Zn(SC(S)N(C4Hg)2)2)
TABLE B-1
Consumptiont
>2.3 x 103 kgs (76)
(total)
~ .
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(Continued)
,
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Use
;
j.
Manufacture.of dyea and hydroquinone, fungicides; chemical
intermediate, rubber accelerator, oxidizing agent; polymeri-
zation inhibitor, photographic chemical, strengthening animal
fibers, reagent
l
POlymerization inhibitor, antioxidapt; stabilizer against
ultraviolet deterioration of rubber
Photographic developer, dye
dant, inhibitor, stabilizer
fuels aod.oils, antioxidant
polymerization
intermediate; medicine; antioxi-
in paints and varnishes, motor
for fats and oils, inhibitor of
Manufacture of antioxidants, pharmaceuticals, plasticizers,
dyestuffs; stabilizer for chlorinated hydrocarbons and ethyl
cellulose, inhibitor for acrylic monomer and acrylonitriles;
ultraviolet inhibitor, stabilizer in textile lubricating
oils; chemical intermediate
. .
Intermediate; antioxidant in vegetable fats and oils
Antioxidant; polymerization inhibitor
,.
i
Preservative and antioxidant for edible fats and oils;
pharmaceuticals; food packaging ingredient
Accelerator for latex dispersions, cements, etc.; ultra-
accelerator for lubricating oil additive
tAnnual Consumption is presented parenthetlcally for the most recent year available.
-------
,
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.
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Antistatic Agent
.::: "~
: ~
AMlNES
, !
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Bis(hydroxyethyl) coco amine
Bia(hydroxyethyl) tallow amine
Ethoxylated amines
"
Octsdecyl amine salt of stearic
add
2,2'-(Octadecylimino)bisethanol
Polyoxyethylene alkyl amine
IMUstat N-20)
Triethanolamine
'I
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Triethanolamine salt of
octadecyl phosphonic acid
QUATERNARY AMMONIUM COMPOUNDS
AHCO C-330
Baraquat CHE IN-cetyl-n-ethyl-
morpholinium etho sulfate)
Benzyl hexadecyldimethyl
ammonium chloride
N,N-Bis(2-hydroxyethyl)-N-(3-
dodecyloxy-2-hydroxypropyl)
methylammonium methosulfate
(Carboxymethyl)dlmethyl-
octadecyl ammonium hydroxide
TABLE B-2. ANTISTATIC AGENTS
CONSUMPTION AND OTHER USES
Consumption t
Use
Fatty acid soaps used in dry cleaning. cosmetics,
household detergents, and emulsions; wool scouring;
textile antifuae agent and water repellant; dis-
persion agent; corrosion inhibitor; softening
agent, humectant, and plasticizer; insecticide;
chelating agent; rubber accelerator
Shampoos; disinfectant; deodorant; antistatic agent
Medicine; gericide; fungicide; surface-active agent
Antistatic agent
(Continued)
-------
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Antistatic Agent
QUATERNARY AMMONIUM COMPOUNDS
(Continued)
. ,
(Carboxymethyl)hexadecyl-
dimethyl ammonium hydroxide
Dihexadecyldimethyl ammonium
chloride
Dimethyldioctadecyl ammonium
chloride
Dioctyldi8ethyl ammonium
bromide
.p-
O-
a
(3-(Dodecyloxy)2-hydroxypropyl)
bia(2-hydroxyethyl)methyl
ammonium methyl sulfate
Salt of Guanidine and octa-
decyltrimethyl ammonium
chloride
(2-Hydroxyethyl)dimethyl(3-
stearamidopropyl) ammonium
nitrate
(3-Lauramidopropyl)trimethyl-
ammonium methyl sulfate
Stearamidopropyldimethyl-2-
hydroxyethylammonium dihydrogen
phosphate
Stearamidopropyldimethyl-2-
hydroxyethylammonium nitrate
Tetrabutyl ammonium bromide
Trimethyl ammonium methyl-
aulfate
TABLE B-2 (Continued)
Consumptiont
~
Antistatic for plastica, waxes, textiles, and
glaas; emulsifier: dispersant
Antiatatic agent for plastics, surface coatings,
peper, and glass; dispersant
(Continued)
-------
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Antiststic Agent
ANIONICS
Didodecyl hydrogen phosphate
o-Dndecyl~-hydroxypoly(oxy-
1,2-ethsnediyl)phosphate
Garfac as 710
a-Nonylphenyl-w-hydroxypoly-
(oxy-I.2-ethanediyl) phosphate
Potassium alkyl phosphate
Sodium dodecylbenzene
sulfonate
o-Tridecyl-w-hydroxypoly(oxy-
1,2-ethanediyl) phosphate
MISCELlANEOUS
~
(7\
~
Butyl stearate
Glycerol
TABLE B-2 (Continued)
Consumption t
Use
Synthetic detergent
Ingredient of polishes, special lubricants and
coatings; lubricants for metals, and in textile and
molding industries; in wax polishes as dye solvent;
plasticizer for laminated fiber products, rubber
hydrochloride, chlorinated rubber, and csble
lacquers; carbon paper and inks; emollient in cos-
metics and pharmaceutical products; lipsticks;
damp-proofer for concrete; flavoring
Alkyd resins; explosives; ester gums; pharmaceuti-
cals; perfumery; plasticizer for regenerated cellu-
lose; cosmetics; foodstuffs, conditioning tobacco;
liqueurs; solvent; printers ink rolls; polyurethane
pol yo Is; emulsifying agent; rubber stamp and copy-
ing inks; binder for cements and mixes; paper coat-
ings and finishes; special soaps; lubricant and
softener; bacteriostat; penetrant; hydraulic fluid;
humectant
(Continued)
-------
"
Antistatic Agent
MISCBLLANBOUS (Continued)
Glycerol mnnostearate [I-mono-
stearin)
Polyethylene glycol hexadecyl
ether
Polyethylene glycol monodecyl
ether
Polyethylene glycol 200
monolaurate
.po
0\
N
Polyethylene glycol
monostearate
Sorbitan, dodecanoate, poly-
(oxy-l,2-ethanediyl)
derivatives
Tris(isooctadecanoato-0)-(2-
propanolato)titanium
INORGAHICS
Aluminum flakea
Carbon black
TABLE B-2 (Continued)
Consumptiont
3.1 x 106 kgs (75)
Use
Thickening and emulaifying agent for aargarine,
shortenings and other food products; flavoring;
emulaifying agent for oila, waxea and aolvents;
protective coating for hygroscopic powders; cosme-
tics; opacifier; detackifier; rea in lubricant
Bmulsifier in cosmetics; pharmaceuticals; textile
finishea; defoamers; dye assiatant; lubricant;
antistatic agent
POWDE8: Paints and protective coatings; rocket
fuel; incendiary mixtures; catalyst; foamed con-
crete; vacuum metallizing and coating plastics
FLAKES: Inaulation of liquid fuels; plastics
Pigment; reinforcing agent; pigment' for cements,
ceramic ware, mortar, inks, linoleum, surface
coatings, crayons, polishes, carbon paper, soap.
etc.; in insulsting compoaitions; liquid-air explo-
sives, matches. fertilizers, furnace lutes,
lubricating composItions; carbon brushes
(Continued)
-------
TABLE B-2 (ContInued)
Antiststic Agent
Consumptiont
Use
INORGANICS (Continued)
Lithium chloride
Air conditioning: welding and soldering flux: dry
batteries; heat exchange media; salt baths; desic-
cant: humectsnt: production of lithium metal; soft
drinks and mineral water to reduce the escape of
carbon dioxide
tAnnual COnsumption is presented parenthetically for the most recent year avsilable.
.t'-
(1\
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-------
TABLE B-3.
;
:!
j
Blowing Agent/Foam Hodifier
PHYSICAL BLOWING AGENTS
Acetone (CHjCOCH3!
Air
Ammonia (NH3!
"
.j:-
0-
.j:-
Benzene (C6H6)
-.1
:,":]
;
'j
..,
Carbon dioxide (C02)
: ~
Dichlorodifluoromethane
(see Freon 12)
l,2-Dichloroethane (CICH2CH2Cl)
- .
. i
;
;.
BLOWING AGENTS AND OTHER ADDITIVES FOR FOAMED PLASTICS
CONSUMPTION AND OTHER USES
Consumptiont
8.2 x 108 kgs (82)
(total)
1.4 x 1010 kgs (82)
(total )
3.5 x 109 kgs (82)
(total)
3.4 x 109 kgs (82)
(total )
4.5 x 109 kgs (82)
(total)
Use
Chemicals (methyl isobutyl ketone, methyl isobutyl carbinol,
methyl methacrylate, biaphenol-A); paint, varniah and lacquer
solvent; cellulose acetate, especially as spinning aolvent;
to clean and dry parts of preclalon equipment; solvent for
potassium iodide snd permanganate; delusterant for cellulose
acetate fibers; specification testing of vulcanized rubber
producta; photographic films; atoring acetylene gaa; harden-
Ing and hydrating tlssuea; naU polish remover'; food additive
Fertllizera; manufacture of nitric acid, hydrazlne hydrate,
caprolactam, acrylonltrlles, hydrogen cyanide, urethane,
acrylonitrile and aodlum carbonate; refrigerant; nltriding
of steel; condenaation catslyst; synthetic fibers; dyeing;
neutralizing agent in petroleum industry; latex preservative;
sulfite cooking liquors; fuel cells; rocket fuel; yeast
nutrient; developing diazo films; explosives; solvent;
cleaning and bleaching; cotton defoliant
Ethylbenzene (for styrene monomer); dodecylbenzene (for
detergents); cyclohexane (for nylon); phenol; nitrobenzene
(for aniline); maleic anhydride; chlorobenzene; diphenyl;
benzene hexachloride; benzene sulfonic acid; anthraquinone;
cumenej solvent; antiknock gasoline
Refrigeration; carbonated beverages; aerosol propellant;
chemical Intermediate; low temperature testing; fire extin-
guishing; Inert atmospheres; municipal waste treatment;
medicine; enrichment of air in greenhousea; fracturing and
acidizlng 011 wells; mining; miscellaneous pressure source;
hardening of foundry molds and cores; shielding gaa for weld-
Ing; cloud aeedlng, moderator In some nuclear reactors; Immo-
bilization for humane animal killinga; special laaers;
blowing agent
Vinyl chloride intermediate (Wulff process); aolvent; lead
scavenger in antiknock gasoline; paint, varnish, and finish
removers; metal degreasingi soaps and scouring compounds;
~etting and penetrating agents; organic synthesis of tri-
chloroethylene, perchloroethylene and methyl chloroform;
ore flotation
(Continued)
'.
-------
Blowing Agent/Foam Modifier
PHYSICAL BLOWING AGENTS (Continued)
Dichloromethane (see Methylene
Chloride)
Ethyl alcohol (C2H50U)
, j
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Freon 11 (Trichlorofluoromethane)
Freon llA
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Freon lIB (Trichlorofluoromethane)
~
0\
V1
Freon 12 (Dichlorodifluoromethane)
Freon 22
Freon 11) (1,I,2-trichlorotrifluoro-
ethane), (CI2CFCCIF2)
Freon 114 (Dichlorotetrafluoro-
ethane). (CI2CFCF))
Freon HE (Blend of Freon II)
'j
n-Heptane (CH)(CH2)5CH))
n-Hexane (CH)(CH2)4CII))
TABLE B-3 (Continued)
Consumption t
4.5 x 109 kgs (82)
(total)
1.2 x 108 kgs (75)
(total)
1.8 x 108 kgs (75)
(total)
>4.5 x 102 kgs (75)
(total)
1.8 x 10) kgs (79)
(total )
1.8 x 108 kgs (79)
(total)
Use
Solvent for resins, fats, oils, fstty acids, hydrocarbons,
alkali hydroxides; extractive medium; manufscture of inter-
mediates, organic derivatives (especially acetaldehyde),
dyes, synthetic drugs, esters, elastomers, detergents, clean-
Ing solutions, surface coatings, cosmetics, pharmaceuticals.
explosives, antifreezei beverages; antisepsis; medicine;
gasoline additive; yeast growth medium .
Refrigerant; propellant; blowing agent; cleaning compound;
fire extinguishers; monomer for resins
Propellant; degreaser; monomer for resins; refrigerant and
air conditioner; blowing agent; low temperature solvent; leak
detecting agent; freezing of foods by direct contact;
chilling cocktail glasses
Refrigerant; solvent for photographic film and magnetic tape;
cleaning agent for plastics and electronic equipment; inter-
mediate for fluoropolymers; fire extinguiahers; blowing
agent; dry cleaning solvent; to make chlorotrifluoroethylene
Solvent; fire extinguishers; refrigerant and air conditIoner;
aerosol propellants; blowing agent; dielectric fluid; monomer
for resins
Stsndard for octane rsting determinations; anesthetic; sol-
vent; organic synthesis; preparatIon of laboratory reagents
Solvent, especially for vegetable oils, low temperature
thermometers; calibrations; polymerizstion resction medium;
paint diluent; slcohol denstursnt; determination of refrac-
tive index of materials
(Continued)
-------
"
j
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Blowing Agent/Foam Modifier
PHYSICAL BLOWING AGENTS (Contlnued)
--
Isopentane [Z-uethylbutane),
[ (CH3)ZCHCHZCH3)
Isopropyl alcohol [CH3CH(OH)CII3)
Isopropyl ether
.po
0\
0\
K-ll [See Freon 11)
Methylene chloride [CHZCIZ)
-,
-,
Nitrogen [NZ)
n-Pentane [CH3(CHZ)3CH3)
Perchloroethylene [CIZC:CCIZ)
TABLE B-3 (Continued)
Consumptlont
7.3 x 108 kgs (7Z)
(total)
5.9 x 108 kgs (8Z)
(total)
3.6 x 106 kgs (75)
(total)
Z.3 x 108 kgs (75)
(total )
1.6 x 1010 kgs (8Z)
(total)
3.3 x 107 kgs (79)
(total)
Use
Solvent; manufacture of chlorinated and alcohol derivatives;
blowing agent for polystyrene; antiknock gasoline additive
Manufacture of acetone and its derivatives; manufacture of
glycerol and isopropyl acetate; solvent for essential and
other oils, alkaloids, gums, resins, shellacs, etc.; latent
solvent for cellulose derivatives; coatings solvent; deicing
agent for liquid fuels; pharmaceuticals; perfumes; lacquers;
extraction processes; dehydrating agent; preservative; quick
drying inks; antiseptic; coupling agent in oil emulsions
Solvent for animal, vegetable, mineral oils, waxes, and
resins; extraction of acetic acid from aqueous solutions;
solvent for dyes in presence of small amounts of alcohol;
paint and varnish removers; spotting compositions; rubber
cements
Solvent for photographic film, synthetic fibers and cellulose
acetate; paint removers; propellant for aerosol sprays; sol-
vent degreasing; plastics processing; blowing agent in foams;
solvent extraction; refrigerant; fire extinguishers
Production of ammonia, acrylonitrile, cyanamide, cyanides,
nitrides; inert gas fur purging, blanketing and exerting
preasure; electric and electronic industries; in-transit food
refrigeration and freeze drying; pressurizing liquid propel-
lants; quick-freezing foods; chilling in aluminum foundries;
bright annealing of steel; cryogenic preservation; inert
preasuring and blanketing gas in missiles; food antioxidant;
source of presaure in oil wells; inflating tires
Artificial ice manufacture; low temperature thermometers;
solvent extraction processes; blowing agent in plastics;
pesticide; propellant; refrigerant; fuel; cleaning and
degreas1ng
Dry cleaning solvent; vapor-degreasing solvent; drying agent
for metals and certain other solids; vermifuge; heat trans-
fer medium; manufacture of fluorocarbons
(Continued)
-------
,
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!
Blowing Agent/Poam Modifier
PHYSICAL BLOWING AGENTS (Continued)
Toluene [C6HsCH31
Tetrachloromethane [Carbon tetra-
chloride I, [CC141
Trichloroethylene
~
0\
~
Trichlorofluoromethane [see Freon III
Trichloromethane [Chloroform I ,
[CHCl]1
l,l,2-Trichlorotrifluoroethane (see
Preon 113 I
Water
[H:zO I
CHEMICAL BLOWING AGENTS
Ammonium bicarbonate [N1I4HC031
Ammonium carbonate
[(NH4)HC03.NH2OCONH41
TABLE B-3 (Continued)
Consumptiont
2.3 x 1010 kgs (82)
(total)' .
3.2 x 108 kgs (19)
(total)
2.0 x 108 kgs (1S)
(total)
1.6 x 108 kgs (19)
(total )
.,
Use
Avistion gasoline and high octane blending stock; benzene,
phenol, and caprolactam, solvent for paints and coatings,
guma, resins, most oils, rubber, vinyl organosols, diluent
and thinner in nitrocellulose lacquers; adhesive solvent in
plastic toys and model airplanes, chemicals (benzoic acid,
benzyl and benzoyl derivatives, saccharin, medicines, dyes,
perfumes), source of toluene diisocyanates; explosives (TNT);
toluene sulfonates, scintillation counter
Refrigerants ~nd propellants, especially the chlorofluoro-
hydrocarbons, metal degreasing; agricultural fumigant, chlor-
inating organic compounds; production of semiconductors,
solvents
Metal degreasing; extraction aolvent for oils, fats, waxes,
solvent dyeing; dry cleaning; refrigerant and heat exchange
liquid, fumigant; cleaning and drying electronic parta,
diluent in paint and adhesivea, textile processing, chemical
intermediate, aerospace operations (fluahing liquid oxygen);
pharmaceutica Is
Pluorocarbon refrigeranta and propellants, fluorocarbon plas-
tics, solvent, analytical chemistry, fumigant; Insecticides
Production of ammonium salts, dyes, leavening agent for
cookies, crackers, cream puff doughs, fire extinguishing com-
pounds, pharmaceuticala; degreasing textiles, blowing agent
for foam rubber, boiler scale removal, compost treatment;
ceramics; fertilizer, tanning; smelling salts
Ammonium salts, medicine (expectorant), baking powders;
smelling salts; fire extinguishing compounds; pharmaceuti-
cals, textiles (mordant), fermentation accelerator In wine
manufacture; organic chemicals; ceramics; washing wool
(Continued)
-------
'.
,
i
i
Blowing Agent/Foam Modifier
CHEMICAL BLOWING AGENTS (Continued)
l,l'-Azobiscyclohexanecsrbonltrile
Azobisformsmide (Azodicarbonamide).
(ABFAJ. (AZ). (HZNCON:NCONHZ)
Azobisformamide. nonplateout
Azobis(isobutyronitrlle) (AZDN)
Barlum azodlcarboxylate
Benzene dlsulfonyl dihydrazlde
Benzene sulfonyl hydrazlde (BSH)
1.3-Bis(o-xenyl)triazene
.p-
O>
00
2-Butylazo-2-hydroxy-5-methylhexane
(Lucel 7-AzoJ
2-Butylazo-2-methoxy-5-methylpentane
(wcel 135)
Celogen CB (Proprletary hydrazldel
Celogen HT-5oo (Modlfled hydrazlne
derivative)
Celogen HT-550 (Hydrazlne derlvatlve)
Celogen XP-IOO (Sulfonyl hydrazide
type)
Citric acld
(HOC(CH2COZH)2COZH)
Dlazoamlnobenzene (1.3-Dlphenyl-
trlazene)
N,N'-dl-t-butylazoblsformamlde
TABLE B-3 (Continued)
Consumpt1o~t
8.2 x 106 kgs (82)
(In plastics)
Use
Blowlng agent for plastlcs and rubbers; maturing sgent for
flours; food sddltive
Catalyst for vinyl polymerlzatlons and for curlng unsaturated
polyester resins; blowing sgent for plastlcs
Organlc synthesls; dyes; Insectlclde
(Continued)
-------
"'
~ .!
";
Blowing Agent/Foam Modifier
CHEMICAL BLOWING AGENTS (Continued)
N,N'-di-n-decylazobisformamide
N,N'-Dinitroso-H,N'-dimethyltere-
phthalamide [N,N'-dimethyl-H,N'-
dinitrosoterephthalamidel, [NTAI
Dlnitrosopentamethylenetetramine
Oiphenylsulfon-3,3'-disulfonyl
hydrazide
N,N'-Dlphenylazobisformamide
Ethylene csrbonate [OC(CH2)21
.po
0\
\0
Expandex 150 [5-phenyltetrazole
analogi
Expandex 175 [5-phenyltetraznle
analogi
Flcel AF-IOO
KemTec 350
KemTec 500
N-Nitroguanidine
Nitropore ATA
N-Hitrourea
Oxamic acid [NH2COCOOHI
p,p'-oxybis(benzene sulfonyl
hydrazide) [OBSHI
TABLE B-3 (Continued)
Consumption t
>4.5 x 102 kgs (79)
(total)
4.5 x 105 kgs (82)
(1n pIns tlcs)
Use
Blowing agent for rubber and plastics
Solvent for many polymers and resins; solvent extraction;
synthesis of pharmaceuticals, rubber chemicals, textile
finishing sgents
High explosives, especially flashless propellant powder;
chemical intermediate
Explosives
BlowIng agent for sponge rubber and expanded plastIcs
(Continued)
-------
..
<
,
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J
~
~
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j
.,
1
..1
~
,
.
.,
I
.]
i
,
,
Blowing Agent/Foam Modifier
CHEMICAL BLOWING AGENTS (Continued)
p,p'-oxybia(benzene aulfonyl
aemicarbazide) (OBSCI
S-Phenyl tetrazine
S-Phenyl tetrazole
Potaaaium borohydride (KBH41
Salicylaldehyde hydrazone
Silicon oxyhydride
Sodium bicarbonate (NaHC031
.1
I
\
j
,"
.po
.....
o
Sodium borohydride (NaBH41
3,3'-Sulfonbis(benzene sulfonyl
hydrazide)
p-Toluene sulfonyl hydrazine
p-Toluene sulfonyl semicarbazide
(TSSC)
Trihydrazine triazine (THTI.
(Cyanuric trihydrazidel
TABLE B-3 (Continued)
I
!
Conaumptiont
Uae
Source of hydrogen; reducing agent for aldehydea, ketonea and
acid chloridea; foaming agent for plaatlcs
Manufacture of ,effervescent aalta and beverages, artificial
mineral water, baking powder; other aodium aalta; pharmaceu-
ticala; aponge rubber; gold and platinum plating; treating
wool and ailk; fire extinguiahers; ceramics; prevention of
timber mold; laboratory reagent; antacid; mouthwash; skin
ointment; cleaning compound
Source of hydrogen, diborane, and other borohydrldea; reduces
aldehydes, ketones, and acid chloridea; bleaching wood pulp;
blowing agent for plastics; precipitation of mercury from
waste effluent; decolorizer for plaaticizers; recycling of
gold and platinum group metals; inorganic snd organometallic
reductions; organic synthesis
Blowing agent
(Continued)
-------
,
.1
TABLE B-3 (Continued)
Blowing Agent/Foam Hodifier
Consumptiont
Use
BLOWING AGENT CATALYSTS
Acta foam F 2
Actafoam R-3
Actafoam R-5
Actafoam R-IO
Actafoam R-34
RIK [ures (surface trested»)
Urea: Fertilizer; animal feed; plastics; chemical intermedi-
ate; stabilizer in explosives; medicine; adhesives; separa-
tion of hydrocarbons (as urea adducts); sulfamic acid produc-
tion; flameproofing agents; viscosity modifier for starch and
casein-based paper costings; reported helful in treating
sickle-cell snemia
~
......
......
Inters tab ABC 1
Interstsb ABC 2
Interstab ABC 6
lnte rstsb ABC 7
lnterstab ABC 18
lnterstab ABC 50
Nuostabe V-1530 [ZInc-based
sctivator)
RIA
Zinc oxide
DiffusIng pigment; accelerator; activator; reinforcing agent;
ointments; pigment and mold-growth inhibitor in paints; cera-
mics; floor tile; glass; zinc salts; feed addItive; dIetary
supplement; seed treatment; cosmetics; semiconductor; photo-
conductor; dental cement; flame retardant; antiseptic
(Continued)
-------
Bloving Agent/Foam Hodifier
SURFACTANTS
SILICONES
Dabco (silicone, tetraethylene-
diamine)
Dimethylsilicone oil
Dov 190 (silicone-glycol)
Dov 192 (silicone-glycol)
Dov 193 (silicone)
Dow 194 (silicone-glycol)
Dow 195 (silicone-glycol)
.po
......
N
Dov 197 (silicone-glycol)
Dov 1250 (silicone-glycol)
Dov 1251 (silicone-glycol)
Dow 1252 (silicone-glycol)
Dow 1253 (silicone-glycol)
Dov 1254 (silicone-glycol)
Dow 1312 (silicone-glycol)
,
. ,
Dow F-11630 (silicone-glycol)
G. E. SS-4255 (silicone)
Tegostsb B 3640 (silicone)
Tegostsb B 4113 (silicone)
Union Carbide L-520 (silicone)
Union Carbide L-532 (silicone)
TABLE B-3 (Continued)
Consumptlont
Use
(Continued)
-------
TABLE B-3 (Continued)
Blowing Agent/Foam Hodifier . ConsumpUont Use
SILICONES (Continued)
Union Carbide L-540 (slliconeJ
Union Carbide L-546 (silicone (
Un ion Carbide L-548 (silicone!
Union Carbide L-550 (silicone)
Union Carbide L-562 (silicone)
Union Carbide L-5302
Union Carbide L-5303
Union Carbide L-5305
Union Carbide L-5307
.po.
'-I Union Carbide L-5340
W
Union Carbide L-5350
Un ion Carbide L-5410
Union Carbide L-5420
Union Carbide L-5430
Union Carbide L-5612
Union Carbide L-5710
Union Carbide L-5 720
Union Carbide L-6202
Union Carbide LC-5613
Un ion Carbide Y-6402
Un ion Carbide Y-6454
(Continued)
-------
Blowing Agent/Foam Modifier
SURFACTANTS
MISCELLANEOUS
Air Prod LK-221 (organic amine)
Air Prod LK-)22 (all organic)
Ai r Prod LK -44)
Empicol LZ (sodium alkyl sulfate)
Ethylsn TC (amine ethylene oxide)
Ethylan reo (fatty amine oxide)
Interwet 212 (non-ionic ester I
Zonyl FSA (fluorosurfactant)
~
......
~
Zonyl FSB (fluorosurfactsnt)
Zonyl FSC (fluorosurfactant)
Zonyl FSJ (fluorosurfactant)
Zonyl FSN (fluorosurfactant)
Zonyl FSP
NUCLEATING AGENTS
Adipic Acid
Benzoic Acid
Calcium csrbonate (CsCO))
TABLE B-3 (Continued)
Consumptiont
2.~ x 109 kgs (81)
(in plastics)
Use
Manufacture of nylon and polyurethane foams; preparation of
esters for use as plasticizers and lubricants; food additive;
adhesives
Sodium and butyl benzoates; plasticizers; benzoyl chloride;
alkyd resins; food preservative; seasoning tobacco; flavors;
perfumes; dentrifices; medicine
Source of lime; neutralizing agent; ftller and extender in
rubber, plast lcs, and paints.; opacifying agent In paper;
forti fication of bread; putty; tooth powders; antacid; white-
wash; Portland cement; S02 removsl from stack gases;
,metallurgical flux; analytical chemistry; C02 generation
(Continued)
-------
1
",
,
j
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!
Blowing Agent/Foam ~odifier
NUCLEATING AGENTS (Continued)
Silica [Si021
Sodium silicofluoride [Na2SiF61
Talc
.f-'
-...J
\JI
TABLE B-3 (Continued)
Consumptiont
8.2 x 107 lbs (80)
(in plastics)
1.5 x 108 kgs (82)
(in plast lcs)
Use
Manufacture of 818s9, vater glass, ceramics; abrasives; water
filtration; component of hydraulic cements; source of ferro-
silicon snd elemental silicon; filler in cosmetics, pharma-
ceuticals, paper, insecticides; rubber reinforcing agent;
snticaking ag~nt for foods; flatting agent in paints; thermal
insulator
Fluoridation of drinking water; laundry aours; opalescent
glass; vitreous enamel frits; metallurgy of aluminum and
beryllium; insecticide and rodenticides; chemical intermedi-
ate; glue, leather, and wood preservative
CeramIcs; cosmetics and pharmaceuticals; filler and pigment
in rubber, paints, soap, putty, plaster,. oilcloth; abherent;
dusting agent; lubricant; paper; slate pencils and crayons;
electrical insulation: insecticide diluent; refractories;
flltration
tAnnual Consumption is presented parenthetically for the most recent year available.
"I
i
i
l
!
-------
TABLE B-4.
Catalyat
Acetic Acid [CH)COOH)
i
.;
i
I
,
j
. j
Acetic Anhydride
[(CHJCO):zOJ
N-Acetylcaprolactam
Acetyl perchlorate
Aluminum Chloride [AICI))
..j
.1
~
......
a-
Aluminum isopropoxide
[AI(OC)H1>3) .
Aluminum oxide
£-Aminocaprolactam
Ammonium hexafluorotitanate
[ (NH4)2TiF6)
Antimony trifluoride
Antimony trioxide [Sb20)J
'j
CATALYSTS FOR THERMOPLASTICS POLYMERIZATION.
CONSUMPTION AND OTHER USES
Consumptiont
1.) x 109 kgs (82)
(total)
5.0 x 108 kgs (82)
(total)
4.5 x 109 kgs (15)
(total)
Use
Hanufacture of acetic anhydride, cellulose acetate,
vinyl acetate monomer, acetic estera, and chloro-
acetic acid; production of plastics, rubbera,
pharmaceuticals, dyea, insecticides, photographic
chemicals; food additive; latex coagulant; oil well
acidizer; textile printing
Cellulose acetate fibers and plastics; vinyl ace-
tate; dehydrating and acetylating agent in produc-
tion of pharmaceuticals, dyes, perfumes, explo-
sives; aapirin; esterifying agent for food starch
Ethylbenzene catalyst; dyestuff intermediate;
detergent alkylate; ethyl chloride; pharmaceuticals
and organics; butyl rubber; petroleum refining;
hydrocarbon resins; nucleating agent for titanium
dioxide pigments
Dehydrating agent; catalyat; waterproofing
textiles
Production of aluminum; manufacture of abrasivea,
refractories, ceramics, electrical insulators.
catalyst and catalyat supporta; paper; spark plugs;
cruciblea and laboratory ware; absorbing gases and
water vapors; chromatographic analysia; fluxes;
light bulba; artificial gems; heat resistant
fibera; desiccant; abrasive; electrical insulation;
dental cementa; artificial gems; chromatography
procelain; pottery; dyeing; fluorinating agent
Flame proofing textilea, paper, plastics; paint
pigments; ceramic opacifier; catalyst; intermedi-
ate; staining iron and copper; phosphors; mordant;
glass decolorizer
(Continued)
-------
I
,
,
.,
j
I
:
Catalyat
"!
Benz 11
[C6HsC°.COC6'lsl
!
.'
Benzophenone [(C6'ls)zC01
1
". .it
,
1
i
.,
Biacetal
Bis(cyclopentadienyl) titanium
chloride
.- i
Bis(triphenylsilyl) chromate
[«C68S)3SiO)2Cr021
Boric Acid [8]8031
~
~
~
Boron trifluoride
Boron trifluoride dibutyl-
etherate
Boron trifluoride etherate
Butyl lithium
Butyl zinc
Cadllium acetate
[Cd(OOCC83>2 1
Calcium acetate
[Ca(C8zCOO>21
TABLE B-4 (Continued)
ConsUllption t
Use
Organic synthesis; insecticide
Organic synthesis; odor fixative; derivatives are
used as UV absorbers; flavoring; soap fragrance;
pharmaceuticals; polymerization inhibitor for
styrene
Carrier of aroma for butter, vinegar, coffee and
other foods; aynthetic flavoring substance and
adjunctive
Heat resistant glass; glass fibera; porcelain
enamels; boron chemicals; metallurgy; fireproofing
compositions; fungus control; ointment and eyewash;
nickel electroplating
Catalyst in organic synthesis; instruments for
measuring neutron intensity; silver soldering
fluxes; gas brazing
Polymerization of iaoprene and butadiene; inter-
mediate in preparation of lithium hydride; rocket
fuel component; metalating agent
Cer8llics (glazes); manufacture of acetates; assis-
tant in dyeing and printing textiles; laboratory
reagent .
Hanufacture of acetone, acetic acid, acetates;
IIOrdant in dyeing and printing textiles; stabilizer
in resins; additive in calcium soap; lubricants;
food additive; catalyst manufacture; medicine
(Continued)
-------
..
i
I
'j
,
Catalyat
Carbon dioxide [C02)
p-cblorophenyl diazonium hexa-
fluoroarsenate
p-Chlorophenyl diazonium hexa-
phosphate
~
'-J
00
Chromocene [(CsHS)2Cr)
Chromic Acid [CrO))
Chromyl chloride [Cr02C12)
Cobalt acetate
(CO(C2H)02)2 )
Cobalt on charcoal
Copper (I) chloride [CuCl)
Copper (II) chloride [CuCI2)
,
TABLE B-4 (Continued)
ConsumpUont
).4 x 109 kgs (82)
(total)
Use
Refrigerant; carbonated beversges; manufacture of
carbonates; fire prevention and extinction; inert
gas blanketing of reactors; propellant for
aerosols, antiseptic in bacteriology and frozen
food industry; treatment of carbon BOnoxide poison-
ing, shielding-arc welding; in greenhouses to
increase growth rate; manufacture of drugs and
white lead; textile and leather industry; process-
ing and preserving food; production of urea, sodium
carbonate, methanol, carbonic acid, inorganic car-
bonates, petroleum, and hyd~ocarbons, oil well
stimulation; !ivestock slaughtering; municipal
water treatment, as fertilizer
Chromates; oxidizing agents; catalysts; chromium
plating, process engraving; intermediate, medicine;
anodizing; ceramic glazes; colored glass; metal
cleaning; inks; tanning; paints; textile mordant
Organic oxidation and chlorination; solvent for
chromic anhydride, chromium complexes and dyes
Sympathetic inks; paint and varnish dryers; cata-
lyst; anodizing; mineral supplement in feed addi-
tives, foam stabilizer
Catalyst; preservative and fungicide; desulfurizing
agent; decolorizing agent In petroleum industry;
absorbent for carbon monoxide
Isomerization and cracking catalyst; mordant in
dyeing and printing fabrics; sympathetic ink; dis-
infectant; pyrotechnics; wood preservation; fungi-
cides; metallurgy; deodorizing and desulfurizing
petroleum distillates; photography; water
purification; feed additive
~ .
~ .
(Continued)
-------
Catalyat
Cyanuric chloride
[C)N)Cl))
Dibutyl aluminum chloride
[Al(C4Hg>2Cl)
Diethyl aluminum chloride
«C2H5>2AlCl)
Diethyl ethoxy aluminum
[AlEt2<>Et)
Diethyl zinc [ZnEt2J
Di-(2-methyl borneal) chromate
Di(triphenylsilyl) chromate
.r--
......,
\0
Ethyl aluminum sesquichloride
[ (C2H5)]A12Cl))
Ethyl 88gnesium bromide
Ferric acetyl acetonste
[Fe(OC(CH):CHC(O)CH)))
Germanium dioxide [Ge02)
Iodine
Lead acetate
[Pb(C2HJ02)2)
Lead dioxide [Pb02)
TABLE B-4 (Continued)
Consumptiont ,
>9.1 x 102 kgs (75)
(total )
Use
Chemical synthesie; dyestuffs; herbicides; optical
brightners
Polyolefin catalyst; inter.ediate in production of
organometalUcs
Organic synthesis; catalyst for polymerization of
olefins; high energy aircraft and missile fuel;
production of ethyl mercuric chloride
Catalyst for olefin polymerization; aromatic hydro-
genation; interaediate,
Grignard-type reactions
Koderating and combustion catalyst; solid fuel
catalyst; bonding agent; curing accelerator;
intermediate
Special glass mixtures; phosphors; transistors and
diodes
Dyes (aniline dyes, phthalein dyes); catalyst;
iodides; iodates; pharmaceuticals; process engrav-
ing and lithography; special soaps; analytical
reagent; iodized salt; medicine; in special lubri-
cants for titanium and stainless steel parts
Hedicine; lead salts; dyeing of textiles; water-
proofing; varnishes; lead dryers; chrome pigments;
gold cyanidstion process; insecticide; antifouling
paints; analytical reagent
Oxidizing agent; electrodes; lead-acid storage
batteries; curing agent for polysulfide elastomers;
textiles (dyeing); matches; explosives;' analytical
reagent
! ,
i'
~.
..
(Continued)
-------
,
j
i
I
'.1'
j
Catalyst
Lead oxide (PbOJ
Lithium acetate
(LiC2D302J
Lithium s-butoxide
Lithium carbonate (Li2C031
.c-
OO
o
Lithium hydride (LiD)
. !
Magnesium
Magnesium acetate
(Mg(OOCCD3)z J
Magnesium dichloride [MgC121
TABLE B-4
Consumptiont
1.2 x 108 kgs (75)
(total)
(Continued)
Use
Storage batteries; ceramic cements aod fluxes;
pottery and glazes; glass; chromium pigments; oil
refining; dryer for varnishes, paints, enamels,
ink, linoleum; insecticides; metal cement; acid-
resisting compositions; match-head compositions;
rubber accelerator; chemical intermediate; oint-
ments; plasters; coloring sulfur-containing sub~
stances; artificial tortoise shell and horn
Ceramic and porcelain glazes; pharmaceuticals;
catalyst; other lithium compounds; coating for arc
welding electrodes; nucleonics; luminescent paints,
varnishes and dyes; glass ceramics; aluminum
production
Desiccant; source of hydrogen; condensing agent in
organic synthesis; preparation of lithium amide and
double hydrides; nuclear shielding material; reduc-
ing agent; manufacture of electronic tubes;
ceramics
Alloys for structural parts, die-csst auto,parts,
missiles, space vehicles; powder for pyrotechnics
and flash photography; production of iron, nickel,
zinc, etc.; magnesium compounds and Crigna~d
synthesis; cathodic protection; reducing agent;
precision instruments; optical mirrors, dry and wet
batteries.
Dye fixative in textile printing; medicine;
deodorant; disinfectant; antiseptic
Source of magnesium metal; disinfectants; fire
extinguishers; fireproofing wood; magnesium
oxychloride cement; refrigerating brines; ceramics;
cooling drilling tools; textiles; paper manufac-
ture; road dust-laying compounds; floor sweeping
compounds; flocculsting agen~; catalyst
,.
"
(Continued)
"
-------
Catalyst
Hagnesium hydroxide [Hg(OH)~1
Hagnesium hydroxychloride
[Hg(OH)Cll
Hagnesium odde [HgO!,
. i
Hagnesium sulfate [HgS041
~
00
.....
Hanganese acetate
[Hn(C2HJ02hl
Hanganese dioxide
-1
Holybdenum trioxide [HoO)1
"
. J
Nickel on charcoal
Palladium [Pdl
IJ
"I
i
.,
TABLE B-4 (Continued)
Consumptiont
!!!!.
Intermediate for obtaining aagnesiua metal; sugar
refining; medicine; residual fuel oil additive;
sulfite pulp; uranium processing; dentifrices; in
foods as alkali, drying agent, color retention
agent; frozen desserts
Refrsctories; polycrystslline ceramic for aircraft
windshields; electrical insulation; cosmetics;
inorgsnic rubber accelerator; oxychloride and oxy-
aulfate cementa; paper manufscture; fertilizers;
removal of sulfur dioxide from atack geaes; adaorp-
tion and catalyaia; semiconductors; pharmsceuti-
cals; food and feed additive
Fireproofing; textiles; mineral waters; catalyst
carrier; ceramics; fertilizers; paper sizing; cos-
metic lotions; dietary supplement; medicine
Textile dyeing; oxidation catalyst; psint and var-
nish dryer; fertilizers; food packaging; feed
additive
Oxidizing agent; depolarizer in dry cell batteries;
pyrotechnics, matches, etc.; catalyst; lsboratory
reagent; scavenger and decolorizer; textile dyeing
Source of molybdenum compounds; agriculture; ana-
lytical chemistry; manufacture of metallic molybde-
num; corrosion inhibitor; ceramic glazes; enamels;
pigments; catalyst in petroleum industry; medicine
Alloys for electrical relays aod awitching systems
in telecommunications equipment; catalyat for'
petroleum; metallizing ceramics; "white gold"
jewelry; resistant wires; hydrogen valves; aircrsft
spark plugs; protective coatings
(Continued)
-------
Catalyst
Perchloric acid
Phenyl isocyanate (C6R~COJ
Phenyl-H-phenyl benzimidoether
Phosphoric acid (H)P04!
~
CO
N
Potassium csrbonate (K%C0)!
Potassium ferrocysnide
(K)Fe(CN)6!
Potassium triphenyl methoxlde
Pyridine (~(CH)4~H!
Sodium acetate
Sodium csprolsctam
: I
:.
TABLE B-4 (Continued)
Consumptiont
7.8 x 109 kgs (82)
(total )
Use
Medicine; analytical chemistry; catalyst; manufac-
ture of various esters; ingredient of the electro-
lytic bath in the depoaition of lead; electro-
polishing; explosives
Reagent for identifying alcohols and amines;
intermediate
Fertilizers; soaps and detergents; inorganic phos-
phates; pickling and rust-proofing metals; phar-
maceuticals-; sugar refining; gelatin IISnufacture;
water trestment; animal feeds; electro-polishing;
gasoline additivs; conversion coatinga for metals;
dyeing; yesst; soil stabilizer; waxes and polishes;
binder for ceramics; activated carbon; in foods and
carbonated beversges; laboratory reagent; source of
uraniwa
Special glasses (optical and color TV tubes);
potassium silicate; dehydrating agent; pigments;
printing inks; laboratory reagent.. snft soaps; rsw
wool washing; general purpose food additive
Medicine; potassium cyanide and ferricyanide; dry
colors; tempering steel; dyeing; explosives; pro-
cess engraving and lithography; laboratory reagent
Synthesis of vitsmins and drugs; solvent; water-
proofing; rubber chemicals; denaturant for alcohol
and antifreeze mixtures; dyeing assistant for
textiles; fungicides
Dye and color intermediate; pharmaceuticals; cinns-
mic acid; soaps; photography; purification of glu-
cose; mest p£eservation; medicine; electroplsting;
tsnning; dehydrsting agent; buffer In foods;
laboratory reagent
1 .
'-
(Continued)
-------
Catalyat
Sodium carbonate (1Ia;zC0))
Sodium hydride (NaH)
Sodium hydrozide (MaOH)
, ,
Sodium hypophosphite
(NaH2P02 )
Sodium methozide
+'-
00
UJ
Stannic chloride
j
: j
i
:i
'J'
Sulfuric acid (H2S04)
(SO) in H~)
Tetraallyl zirconium
(Zr(ally1)4 )
J
'!
Tetrabenzyl titanium
(Ti(C&8S)4)
Tetrabenzyl zirconium
(Zr(C&8S)4 )
TABLE B-4 (Continued)
Consumptiont
7.2 z 109 kgs (82)
(total)
8.4 z 109 kgs (82)
(total)
S.O z 106 kgs (7S)
(total)
2.9 z 1010 kgs (82)
(total)
Uae
Medicine; photography; cleaning and boiler com-
pounds; pH-control of vater; food additiv~
Condensing or alkylating agent; descaling metals;
reducing agent and reduction catalyst
Chemical aanufacture; rayon and cellophane;
petroleum refining; pulp and paper; aluminum;
detergents; aoap; teztile processing; vegetable oil
refining; reclaiming rubber; regenerating ion
ezchange rea ins; organic fuaions; peeling of fruits
and vegetables; laboratory reagent; etching and
electroplating
Medicine; reducing agent in electroless'nickel
plating of plastics and metals; laboratory reagent
Catalyst in condensation reactions; catalyst for
treatment of edible fats and oils; intermediate for
pharmaceuticals; preparation of sodium celluloaate;
analytical reagent; ester-alcohol interchange
Electroconductive and electrolumineacent coatinga;
teztiles; perfume stabilization; manufacture of
fuchains; color lakes; ceramics; bleaching agent
for sugar; stabilizer for certain resins; manufac-
ture of blue print and other sensitized papers;
other tin salts; bacteria and fungi control in
soaps
Fertilizers; chemicals; inorganic pigments; petro-
leum refining; etchant; alkylation catalyst;
electroplating baths; iron and steel; rayon and
film; industrial ezplosives; laboratory reagent;
nonferrous metallurgy
(Continued)
-------
Catalyat
Tetrabutyl zirconate
[Zr(OC4Hg)41
Tetrabutyl titanium [TiBu41
Tetraethyl titanium
[Ti(OC2HS)41
N,N,N',N'-Tetramethylethylene-
diamine [(CH3)2NCH2CH2N
(CH3>21
Tetramethylguanidine
[(CH3)2NC(NH)N(CH3)21
Thiocarbo"illide
Titanium dichloride [TiC121
~
(X)
~
Titanium dichloride diieo-
propylate [TiC12(OPr)21
Titanium dio"ide [Ti021
r
i
Titanium iaopropylate
[T1(OC3H8)41
Titanium tetrachloride
[TiC141
Titanium trichloride [TiC131
Triallyl halfium bromide
Triallyl titanium bromide
[Ti(a11yl hBr 1
TABLE B-4 (Continued)
Coneumptiont
2.0" 108 kgs (82)
(1n plastics)
Use
Condensstion catalyst and crosslinking agent
Preparation of epo"Y curing agents; polyurethane
formation; corrosion inhibitor; te"tile 'finishing
agents; intermediate for quaternary ammonium
compounds
White pigment; opacifying agent; cosmetics; radio-
active decontamination of skin; floor coverings;
glassware and ceramics; enamel frits; delustering
synthetic fibers; printing inks; welding rods;
source of titanium metal; synthetic sunscreens;
dusting powder
Bster e"change reactions; adhesion of paints, rub-
ber and plastic to metals; condensation catalyst;
flue gas sorbent; controlled release pesticide
For titanium and titanium salts; mordant dye; irri-
descent effects in glass; s.oke screen; titanium
pigments; polymerization catalyst
Reducing agent; organic synthesia; cocatalysts for
polyolefin polymerization; organometallic synthesis
involving titanium; laundry stripping agent
(Continued)
-------
Catalyst
. j
Trisllyl zirconium bromide
Tributyl aluminum
[ (CHJCHzCHzCH2>]Al)
Tricyclohexyl aluminum
[Al(C6'l13>3)
Triethyl aluminum
[ (C2HS>]Al)
., .
'. .
Triethylamine [(C2HS>JN)
!
'j
Triethylbenzyl ammonium
chloride
~
Co
IJ1
Triethylsulfonium iodide
Triisobutyl aluminum
[«CH3>zCHCH2>JA1)
Triphenylphosphine
Vanadium oxytrichloride
[YOCI3)
Vanadium trioxybutylate
[YO(OC4Hg>3)
Vanadium tetrachloride [YCI4)
Vanadium trichloride [YCI3)
Zinc acetate
[Zn(C2HJ02>2)
. .
TABLE B-4 (Continued)
Consumptiont
Uae
Production of organotin compounds
Catalyst intermediate for polymerization of ole-
fina; pyrophoric fuela; production of alpha-olefins
and long chain alcohols; gas plating of aluminums
Catalytic solvent in chemical synthesia; accelera-
tor for rubbers; wetting, penetrating and water-
proofing agents of quaternary ammonium types;
curing and hardening polymers; corrosion inhibitor;
propellant
Polyolefin catalyst; manufacture of primary
alcohols and olefins; pyrophoric fuels
Synthesis of organic compounds, phosphonium salts,
and other phosphorus compounds
Catalyst in olefin polymerization; ~rganovanadium
synthesis
Preparation of vanadium trichloride, vanadium
dichloride, and organovanadium compounds
Preparation of vanadium dichloride and organo-
vanadium compounds
Hedicine; preserving wood; textile dyeing; zinc
chromate; laboratory reagent; feed additive; cross-
linking agent for polymers; ingredient in dietary
supplement
(Continued)
-------
TABLE B-4 (Continued)
Catalyst
Consumption t
Use
Zinc chloride (ZnCIZ)
Galvanizing iron; catalyst; dehydrating and con~
densing agent in orgsnic synthesis; wood preserva-
tive; soldering flu~es, burnishing and poiishing
compounds for steel; electroplating; antiseptic and
deodorant preparations; textiles; adhesives; dental
cements; glass etching; petroleum refining; parch-
ment; dentrifices; embalming and taxidermist's
fluids; medicine; dyestuffs, pigments; antistatic;
feed additive; denaturant for alcohol; dietary
supplement
Zinc formate [Zn(CHOZ}Z)
Catalyst for production of methanol; water proofing
agent; textiles; anti~eptic .
Zinc oxide (ZnO)
.J:-
CO
(J\
SUPPORTS
-
S10Z
Al z03
HgO
HgOHCl
HgClz
Hg(OH)Z
Tl02
Accelerator, activator, pigment and reinforcing
agent for rubber; ointments; pigments and mold-
growth inhibitor in paints; ceramics; floor tile;
glass; zinc salts; feed additive; dietary supple-
ment. seed treatment; cosmetics, semiconductor in
electronic devices; photoconductor; piezoelectric
devices; dental cement; flame retardant; antiseptic
Manufacture of glas8, water 81888, ceramics;
abrasives; water filtration; component of hydraulic
cements; source of ferrosl1icon and elemental
silicon; filler in cosmetics, pharmaceuticals,
paper, insecticides; rubber reinforcing agent;
anticaking agent for foods; flatting agent in
paints; thermal insulator
See Catalysts.
See Catalysts
See Catalysts
See Catalysts
See Catalysts
See Catalysts
(Continued)
-------
. ~ !
~
- -1
---I
J
j
1
-J
- j
J
1
1
j
TABLE B-4 (Continued)
Catalyat
SUPPORTS (Continued)
Conaumptiont
Uae
TiCl)
See Catalyata
Cao
Refractory; flux in steel manufacture; pulp and
paper; manufscture of calcium carbide; S02
removal of stack gases; sewage treatment; poultry
feeda; neutralization of acid waste effluents;
inaecticides and fungicides; dehairing of hides;
food processing; sugar refining
i
j-
CaS(P04»OH
Hg(OEt)2
NEUTRALIZERS
Calcium oxide
See Catalysts
.p-
00
"'-J
Calcium stearate
Water repellent; flatting agent in paints; lubri-
cant in making tablets; emulsions; cements; wax
crayons; stabilizer for vinyl resins; anticaking
agent in foods; cosmetics
n-Heptane
[CH)(CHZ)SCH))
Standard for octane rating determinations;
anesthetic; solvent; organic synthesis; preparation
of laboratory reagents
Hydrochloric acid [HCll
Acidizing of petroleum wells; chemical inter-
mediate; ore reduction; food processing; pickling
and metal cleaning; industrial acidizing; general
cleaning; alcohol denaturant
Isopropyl alcohol
[ (CH)}zCHOH)
Manufacture of acetone and its derivatives; manu-
facture of glycerol and isopropyl acetate; solvent
for essential and other oils, alkaloids, gums,
resins. etc.; latent solvent for cellulose deriva-
tIves; coatings solvent; deicing agent for liquid
fuels; pharmaceuticals; perfumes; lacquers; extrac-
tion processes; dehydrating agent; preservative
(Continued)
-------
"
;
//
,
~
co
co
"TABLE B-4 (Continued)
Catalyat
Conaumptiont
NEUTRALIZERS (Continued)
Methanol
Phosphoric Acid
n-Propanol [CH3CH2CH20H)
3.8 x 107 kgs (72)
(total)
Triphenyl phosphate
Water (as steam)
I-
Use
Manufacture of foraaldehyde and dimethyl tere-
phthalate; chemical syntheais; aviation fuel, auto-
motive antifreeze; solvent for nitrocellulose,
ethylcellulose, polyvinyl butyral, shellac, rosin,
manila resin, dyes; denaturant for ethyl alcohol;
dehydrator for natural gas; fuel for utility
planta; feedstock for manufacture of synthetic pro-
teins by continuous fermentation
See Catalysts
Organic synthesis and chemical intermediate;
solvent for waxes, vegetable oils, natural and
synthetic resins, cellulose esters and ethers;
polishing compositions; brake fluids; solvent
degreasing; antiseptic; pharmaceuticals; lacquers
and dopes; cosmetics; component of brake fluid;
antiseptic agent; dental lotions; synthetic flavor
Fire-retarding agent; plasticizer
tAnnual Consumption Is presented parenthetically for the most recent year a~ailable.
#
~
-------
..
,
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!
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, 1
.: i
,
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,
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,
Colorant
-
INORGANIC PIGHEHTS
WHITE
Aluminum Silicate (A12(Si03)3)
Barium Sulfate [BaS04)
(Blanc fixe)
I
"
Calcium Silicate (CaSi03)
(Wollastonite)
.t-
OO
\0
Lithopone (28% ZnS and 72% BaS04)
Titanium dioxide (Ti02)
Wollastonite (see Calcium Silicate)
Zinc oxide (ZnO)
TABLE B- s. COLORANTS
CONSUMPTION AND OTHER USES
Color Index
Pig. White 22, 77102
Pig. White 21, 77115
Pig. White 5, 17115
Pig. White 6, 77891
Pig- White 4, 77947
Consumptiont
2.0 x 108 kgs (82)
(in plasUca)
Uae
Extender for thermoset polyesters; acts
as a reinforcer as well
Diffusing pigment for acrylics; weighing
mud in oil drilling; paper coating;
filler and deluatrant; base for lake
colora; X-ray photography; battery plate
expanders
Polyethylene, vinyla, and thermoset
resins; absorbent; antacldj adhesives;
filler for paper; coametics; food addi-
tive (anticaking agent)
White pigment for paints, rubber, paper
and leather
53% in paints, varnishes, lacquers; 21%
in paper; 10% in plastics; 3% in elasto-
mers; 2.5% in ceramics; 2% in floor
covering; 2% in printing inks; 1% in
coated fabrics and textiles; 1% in roof-
ing granules; 4.5% for other pigments
Ceramics; paint extender; welding rod
coatings; rubber filler; silica gels;
paper coating; filler in plastica,
cementa, and wallboard; mineral wool:
soil conditioner
Diffusing pigmen~; accelerator; activa-
tor; reinforcing agent; ointments: pig-
ment and mold-growth inhibitor in paints;
ceramics; floor tile; glass; zinc salts;
feed additive; dietsry supplement: seed
treatment. cosmetics; semiconductorj
photoconductor
(Continued)
-------
. f'"
Colorant
-
WHITE (Cont1nued)
Zinc Sulfide (ZnS)
BLACK
Bone Black (C+Ca3(P04)2)
Ceramic Black
Iron Oxide (FeO.Fe203)
.t--
\0
a
Copper Chromite Black (Cu(Cr02)2)
Cobalt Black (CoO)
BLUE, GREEN
Barium Manganate (BaHn04)
(Hanganeae green)
Cassel Green (MnO)
Chrome Cobalt-Alumina (turquoise)
ICrCoAl oddes)
Chrome Green (green) (PbCr04.PbS04.
FeNH4Fe(CN)6)
Chromium Oxide (dull green) ICr203)
TABLE B-5
Color Inde..
Pig. White 7, 77957
Pig. Black 9, 77267
Pig. Black 26, 77494
Pig. Black 28, 77428
Pig. Black II, 77499
Pig. Blue 36, 77343
Pig. Green 15, 77510,
77600
Pig. Green 17. 77288,
77289
(Continued)
Consumpt1ont
Use
Diffusing pigment; white and opaque
glass; base for color lakes; rubbers;
dyeing; phosphor in X-ray and television'
screens. luminous watch faces;
fungicides
Pigment; polishing compound; metallurgy;
medicine; magnetic inks; coatings for
magnet1c tape
Paint, enamel, and ceramic pigment; other
cobalt salts; catalyst; feed additive
Paint pigment
Paints, enamels, lacquers, printing inks,
paper coating, staining and plastics such
as thermoset polyesters and polyethylene
leaf bags
Metallurgy; green paint pigment; ceram-
ics; catalyat in organic aynthesis; green
granules In aaphalt roofing; component of
refractory brick
(Continued)
-------
.1
J
'j
1
!
1
Colorant
BLUE, GREEN (Continued)
Cobalt Aluminate (blue) (CoO.AIZ031
Cobalt Chrome Green
Hydrated Chrome Oxide (green)
(CrZ03. ZHZO I
Iron Blue (blue) (Prussian
(Hilori and Chinese Blue)
(FeHH4Fe(CN)6) or
(FeHH4Fe(CN)6.FeKFe(CN)6)
Blue)
Hsnganese (blue) (BaHn04.BaS041
~
\0
......
Hyrtle Green (CrCoAI oxidesl
Shamrock (CoTiZnNiAI oxides I
Titanium Pigments (blue) (TiOZ with
CaO.AlZ031
Titanium Pigments (green)
Titanium Pigments (light green)
(TiOZ with Ni and Col
Ultramarine Blue (blue) (NaAISiOSI
(Complex aluminum sulfo-silicate
produced by heating Ultramarine
Green in presence of sulfur)
Ultramarine Green (green)
(Approximately Na1Al6
Si60Z4S3)
TABLE B- 5
Color Index
Pig. Blue Z8, 11346
Pig. Green Z6
Pig. Green 18, 11Z89
Pig. Blue Z1, 17510
175Z0
Pig. Blue 33, 11112
Pig. Green 50, 11311
Pig. Green 50, 77377
Pig. Blue Z9, 17007
17013
(Con tinued)
ConsumpUoDt
Use
Artist's color, paints, printing inks,
lacquers
Rubber, psper, plsstics, printing inks,
lacquers, enamels
Paints; printing inks; plastics; cosme-
tics (eye shadow); srtist colors; laundry
blue; paper dyeing; fertilizer ingredi-
ent; baked enamel finishes for autos and
appliances; industrial finishes
Cement
Intensifies whiteness of white enamel,
rubber compounds, laundered clothing,
etc.
(Continued)
-------
i
1
Colorant
-
j
VIOLET
Cobalt Lithium Phosphate (CoLiP04)
Cobalt Phosphate (C03(P04>2)
Hanganese Violet (HnHP207.NH3J
(Hineral Violet)
Ultramarine Violet (Complex aluminum
sulfosUicateJ
~
\0
N
Ultramarine Pink (Complex aluminum
sulfosilicate produced by heating
Ultramarine Green at 200-250.C for 4
days in the presence of ammonium
chloride)
RED, RED-QKANGB
Cadmium Hercury (maroon, red, orangeJ
(CdS and HgS)
Cadmium Sulfoselenide (maroon, red,
orange) (CdSe and CdS)
Cadmium Sulfide (orange) (CdS)
Chrome-tin (pink)
Chrome Orange (PbCr04.PbO)
Copper Haroon (CuK2Fe(CN)6)
TABLE B-S
Color Index
Pig. Violet 14, 77360
Pig. Violet 47, 77363
Pig. Violet 48, 77352
Pig. Violet 14
Pig. Violet. 16, 77742
Pig. Violet 5
Pig. Violet 15, 77007
Pig. Red 113, 77201
Pig. Orange 23, 77201
Pig. Red 108, 77196,
77202
Pig. Orange 20,
77106, 77196, 77198,
77199
Pig. Orange 21, 77601
Pig. Red 121, 77320
(Continued)
Consumptiont
Use
Ceramics, glass, artists' color, rubber,
plastics, paper
Cobalt pig8ents; coloring glass, painting
porcelain; animal feed supplement
Paints and crayons
Distemper and paints
Paints, enamels, printing inks, plsstics,
rubber, paper, textiles printing
Pigment for paints, plastics, enamels,
lacquers; semiconductor
Pigments snd inks; ceramic glazes; pyro-
technics; phosphors; fluorescent screens;
scintillation counters; rectifiers;
photoconductors in xerography; transis-
tors; photovoltaic cells; solar cells
Paints, enamels, inks, lacquers, paper,
rubber, plastics, artist's colors
Rubber, paper, plastics, printing inks,
lacquerst enamels
(Continued)
-------
Colorant
RED, RED-oRANGE (Continued)
Hematite (Ve203!
Iron Oxide (maroon, red, light red)
(Ve203)
Hercuric Sulfide (UgS)
Molybdate Orange (PbCr04.PbO.
PbHo°4)
Molybdate Orange (coated)
Red Ochre (natural) (Ve203)
.I:-
1.0
W
Red Lead (synthetic) (Pb304)
Ultramarine Red [Complex aluminum
sulfosilicate produced by heating
Ultramarine Green at 70-200.C for 4
days in presence of HCl or by reac-
tion with gaseous HN03 at higher
temperature)
YELLOW
Burnt Umber (natural) (Ve203.H20)
Cadmium Sulfide (yellow) (CdS and ZnS) .
(Cadmium Yellow)
Ceramic Buff (Yellow buff)
(Sb, Ti, Cr oxides)
TABLE B-5
Color Index
See Iron Oxide
Pig. Red 101, 77419
Pig. Red 102, 77419
Pig. Orange 21, 77601
Pig. Red 104, 7760S
Same as Molybdate
Orange
Pig. Red 101, 77491
Pig. Red 102, 77491
Pig. Red lOS, 77S78
Pig. Red S, 12490
See Iron Oxide
Pig. Yellow 42, 77492
Pig. Yellow 43, 77492
Pig. Yellow 37,
77117, 77199
(Continued)
Coosumptiont
Use
Iron ore; rouge; paint pigment
Karine paints and metal primers; polish-
ing compounds; pigment in rubber and
plastic; theatrical rouge; grease paints
Medicine; pigment
See Chrome Orange. Pigment for printing
inks, paints, and plastics
Paints, plastics, lacquers, printing
inks, emulsion paints, rubber
See Iron Oxide
Jointing paints, protective paints
See Iron Oxide
Pigment for paints, plastics, lacquers,
paper and inks; ceramic glazes; pyro-
technics; phosphots; fluorescent screens;
scintillation counters; rectifiers,
photoconductors; transistors; photo-
voltaic cells; solar cells
(Continued)
-------
Colorant
~ (Continued)
Chrome Yellow [PbCr04)
Chrome Yellow (heat resistsnt)
[PbCr04), coated
Iron oxide (yellow) [peZ03'xHZO)
Lead Chromate
Lead Molybdate
Ocher [FeZ03.HzO)
.po
\0
.po
Sienna [peZ03)
Titanium Pigment (light yellow)
[Nickel titanate)
[NiO.TiOZ) (buff) [Ni, Sb, T1
oxides) [Pe, Zn, T1 oxides) and [Pe,
Cr, Ti, Sb, Zn oxides)
Zinc Chromate (yellow) [ZnCr04
(complex) )
BROWN
Iron Oxide (buff, brown) [(PeO)x'
(PeZ03)y)
Limonite [hematite brown)
Ocher [PeZ03)
TABLE B-5
Color Index
Pig. Yellow 34,
77603, 77600
Pig. Yellow 34
Pig. Yellow 4Z, 7749Z
See Chrome Yellow
Pig. Yellow 43
See below
Pig. Yellow 43
Pig. Yellow 53, 77788
PIg. Yellow 36, 77955
Pig. Brown 6, 77491,
7749Z, 77499
Pig. Brown 7, 77491
Pig. Brown 6, 77491
Pig. Brown 7, 77491
(Continued)
Consumptiont
.Use
Pigment for painta, inks, rubbers and
plastics
Pigment for rubbers and plastics and
occasionally inks and paper
Paints; rubber producta; plastics and
cement
Pigment for paints, rubbers, plastics,
cerallic coatings
Analytical chellistry; pigments
Paint pigllents; cosmetics; theatrical
make-up
See Ocher
Paints and printing ~nks
Artist's color; varnishes; pigment in
rust-resistant primer and automotive
paints; corrosion resistant additive to
epoxy laminate
Pigment for paints, enamels, lacquers,
plastics, rubbers
See Iron Oxide
Paint pigments; cosmetics; theatrical
makeup
(Continued)
-------
Colorant
, .
. i
. I
. j
BROWN (Continued)
Sienna (natural) (Fe203J
.]
Titanium Pigmenta (brovo) (Ti02
with up to 10% Fel
(rutile I
.1
Umber (Fe203 with ailica, alumina,
manganeae oxidea and limel
ORGANIC PIGMENTS
BLACK
Aniline Black
.to-
~
U1
Bone Black (85% Ca3 (P04)2 and
Cac03 with 12-23% C J
Carbon Black (furnace black) ICI
Carbon Black (lamp carbon black) (CI
Channel Black ICI
Thermal Black
TABLE B-5
Color Index
Pig- Brown 24
Pig - Brovo 43
Pig- Black 1, 50440
Pig- Black 9, 77267
Pig- Black 7, 77266
Pig- Black 6, 77.266
(Continued)
Conaumptiont
Use
Colorant in oil paints, stains, pastels,
etc.
Paints, inks, plastlcs
Palnt plgment; Ilthographlc ink; wall-
paper plgment; artist's color
Colorant, largely for cot~on and textlles
Manufacturing activated carbon; decolor-
izing sgent snd flltering medlum; cemen-
tation reagent; adsorptlve medlum In gss
masks; paint and varnish plgment; clari-
fying shellac; water purlflcation
Relnforcing agent, plgment for cements,
ceramic ware, mortar, Inks, linoleum,
surface coatings, crayons, polishes,
carbon paper, soap, etc.; In insulatlng
compoaltions; liquid-alr exploslves;
matches; fertillzers; furnace lutes;
lubrlcating composltiona; carbon brushes
See Channel Black and Furnace Black
Reinforclng agent for rubber tires, belt
covers and other abraslon-reslstant rub-
ber products; colorant for plastlcs;
inks, carbon paper, typewriter ribbon;
palnt; nucleatlng agent in weather modi-
flcatlon; expanders for battery plates
See Fu rnace Black
(Continued)
-------
I
j
'j
1
:,
] .
. j
Colorant
-
.,
.,
BROWN
Azoic Brown (Hanoazo)
Oisazo Brown
BLUE, GREEN
Alumina Lake (Honoazo)
Cromophtal Blue AJR
Cromophtal Green GF
Oianisidene Blue (Oisazo)
~
\0
0\
FO&C Blue 1 Aluminum Lake (food blue 2)
(Ethyl(4-p-(ethyl(m-sulfobenzyl)
amino)- -(o-sulfo-phenyl)benzylidene)
-2,5-cyclohexadien-l-ylidene)(m-sul-
fobenzyl)hydroxide ammonium inner
salt, sodium salt)
FD&C Blue 2 Aluminum Lake (food blue 1)
(indigoid)
Indanthrone Blue-Red Shade
(Anthraquinone)
Indanthrone 16,15-dihydro-5,9,14,lB-
anthrazine tetrone)
(Cromophthal Blue AJR)
(Anthrsquinone)
Nickel-Azo Yellow (greenish yellow)
(metal complex of p-chloroaniline
coupled to 2,4-dihydroxyquinoline)
Oracet Blue 2B
TABLE B-5
Color Index
Pig. Brown 25, 12510
Pig. Brown 32
Pig. Brown 23
Acid Blue 4, 73015
Pig. Blue 60, see
Indanthrone
Pig. Blue 25
42090:2
Pig. Blue 63, 73013
Pig. Blue 64, 68925
Pig. Blue 22, 69810
Pig. Blue 60, 69800
Pig. Green 10, 12755
(Continued)
Consumptiont
Use
Plastics (PVC)
Oil paints, printing inks, plastics
Rubber, plastics, textile printing,
occasionally inks, emulsion paints
Cosmetics
Text lIes
Pigment in paints and enamels
Paints, plastics, printing inks
Plastics, lacquers, inks
.'
(Continued)
-------
. '.
'. ,
.,
.1
. ~
1
Colorant
-
BLUE, GREEN (Contlnued)
Phthalocyanlne (blue)
red shade
green shade
.",'
metal free
Phthslocyanlne (green)
Phthslocyanlne Green, bromlnated
..,
Plgment Green B (dsrk green) (Nltroso)
J::-.
\0
....,
PTA AtA Toners (blue, green)
(trlphenyl-methane, phospho-
tungstomolybdic scld)
VIOLET
Allzarine Maroon (maroon)
(Anthrsqulnone)
Benzlmldazolone Vlolet (Honoazo)
Carbszole Dloxazlne Vlolet
Isovlolanthrone Vlolet (Anthraqulnone)
(Vat plgment)
HethylViolet
TABLE B- 5
Color Index
Plg. Blue 15, 76160,
74160
Plg. Blue 15: 3,
74160, 76160
Plg. Blue 16, 74100
Plg. Green 7, 74260,
74160
Plg. Green 36, 74265
Pig. Green 8, 1006
Plg. Blue 1, 42595
Plg. Green 2, 42040
Plg. Vlolet 5, 58055
Plg. Violet 32, 12517
See Honoazo Red
Plg. Vlolet 23, 51319
Plg. Vlolet 25, 51319
Plg. Violet 33
Plg. Violet 31
Vat Vlolet 9, 60005
Plg. Violet 3, 42535
(Continued)
ConaumptIont
4.0 x 106 kgs (79)
1.5 x 103 kgs (79)
3.9 x 104 kgs (79)
8.2 x 103 kgs (79)
1.5 x 105 kgs (79)
9.0 x 104 kgs (79)
Use
Decorstlve enamels; automotlve flnlshes;
llnoleum plaatlcs; rooflng granules;
prlntlng inks; wallpaper; rubber goods
Palnts, inks, dlstempers, paper coatlng,
plastics
100% as a plgment
Palnts, inks, plastlcs, rubber, lacquer,
lesther, textlle prlntlng
Very small appllcation,ln plastlcs; emul-
slon palnts, distempers, wallpaper, paper
coatlng, leathercloth, bookcloth, cement
Prlntlng inks, paints; enamels, plastlcs,
paper coat lng, carbon papers, typewrlter
r1 boons
Manufacture of alumlnum salt
Plastlcs, prlntlng tnks, stove enamels,
paints
011 palnts, emulslon palnts, plastlcs,
rubber, ink, text lIe palntlng, emulslon
palnts
Medlcine; acld-base Indlcator; denaturant
for alcohol; blologlcal staln; plgments;
dye for text lIes
(Continued)
-------
Colorant
-
VIOLET (Continued)
Honoazo Red, blue shsde
[Benzimideszolone violet)
Oracet Violet 2R
P T H A Toners (Phosphotungstomo-
lybdic acid salt of basic dye)
[Xanthene)
Perrindo Violet [Anthraquinone)
Quinacridone Red (yellow shade)
Quinacridone (violet-maroon)
~
-0
00
Thioindigo Violet
RED
Alizarine Red BLake
Alumina Lake (phthalein)
Anthraquinone Red
Orange RK
Anthraquinone Red
Azo Condensate Red
Be Lithol (medium red)
TABLE B-5
(Continued)
Color Index
Consullptiont
Use
Pig. Violet 32, 12517
Pig. Red 83, 58000
Plastics, printing inks, stove'enamels,
paints
t.
Pig. Violet 2, 45175
Pig. Violet 29, 71129 PVC pigment
Pig. Violet 19, 7.1 x 105 kgs (79) Plastics, textile emulsion inks
16500, 46500
Pig. Violet 19, 7.i x 105 kgs (79) Plastics, textile elllUlsion inks
16500, 46500
Pig. Violet 36, 73385 Textiles
Pig. Red 83, 58000
See Madder Lake
Pig. Red 172, 43439:1
Cosmetics
Pig. Red 177
Plastics, paints
Pig. Red 168, 59300
~e Vat Orange
Paints, printing inks, plastics
Pig. Red 194, 71100
See Vat Red
Plastics, lacquers
Pig. Red 242
Pig. Red 49, 15630
See Lt thol Red
2.9 x i06 kgs (79)
Printing inks, rubber, enamels
(Continued)
-------
. ,
I
..,
,
j
, )
;
,
,I
Colorant
RED (Cont inued)
Benzimidazolone Reds
(Permanent Red HFT)
(Honoazo)
(Permanent Carmine)
B.O.N. Rubine (Na Salt)
(Ca Salt)
B.O.N. Haroon (Honoazo)
(Sodium salt of acid dye)
.j:'-
~
~
Chlorinated Para (light red)
(1(-2-chloro-4-Nitrophenyl)azo)
2-Naphthol)
(Honoazo)
Cromophtal Scarlet R (Azo)
Cromophtal Red BR (Disazo)
(Disazo Condensation Red)
Cromophtal Red 3B (Anthraquinone)
Cromophtal Red G (D1sazoJ
Cromophtal Red GR (D1sazo)
Cromophtal Red 2RS
Cromophtal Rubine B
Dianisidine (medium red)
Disazo Condensation Red
TABLE B-5
Color Index
Pig. Red 171,
See Honoazo
Pig. Red 175,
See Honoazo
Pig. Red 176,
See Honoazo
Pig. Red 185,
See Honoazo
12521
12513
12516
12516
Pig. Red 52, 15860
Pig. Red 200, 15867
Pig. Red 63, 15880
Pig. Red 4, 12085
Pig. Red 6
Pig. Red 166
Pig. Red 144
Pig. Red 177
See Anthraquinone Red
Pig. Red 220
Pig. Red 139
Pig. Red 41, 21200
Pig. Red 144
See Cromophta 1 Red BR
(Continued)
Consumptiont
6.7 z 105 kgs (79)
Use
PVC, inks, lacquers
Paints, lacquers, plastics
Plastica, lacquers, inks
Plastics, lacquers, tinplate ink
Base for salts of, heavy metal inks,
paints, plastics
Base for heavy metal salts
Paints, lacquers, plastics, rubber
Plastics, paints, printing inks
Enamels, lacquera, plastics, leathercloth '
Plastics, paints
Plastics
Plastics, occasionally printing inks
Enamels, lacquera, plastics
(Continued)
-------
..r"
" ",
.i
1"
J
i
i
1
Colorant
-
RED (Continued)
Disazo Reds
Dichlorobenzidene Red
FD&C Red 3 AluminUII Lake (food red 14)
(2',4',5',7' Tetra-bromo-4,5,6,7-
tetrachloro fluorescein, disodium
salt)
FD&C Red 4D AluminUII Lake
Helio Bordeaux (maroon)
lJ1
o
o
Irgazin Red 2BLT (Isoindolinone Red)
Lake Red C (light red) (5-chloro-2-«2-
Hydroxy-l-Naphtha-lenyl)Azo)4-methyl-
benzene-sulfonic acid, barium salt)
Lithol Red (Bs of acid dye) (Honoazo)
Lithol Rubine (Na salt of acid dye)
(bluish red) (Honazo)
Lithol Rubine, Sr (Honoazo)
Hadder Lake (alizarine red)
(l,2-dihydroxy-anthraquinone)
Honoazo Red (blue and yellow shade
reds)
TABLE B-5
Color Index
Pig. Red 146
Pig. Red 166
Pig. Red 214
Pig. Red 22D
Pig. Red 221
See Pyrazolone Red
45430
16035
Pig. Red 54, 14830
Pig. Red 180
Pig. Red 53: I,
15585:1
Pig. Red 49, 15630
Pig. Red 57; 15850
Pig. Red 52, 15850
Pig. Red 83, 58000
Pig. Red 187
Pig. Red 188,
Pig. Red 246
Pi8. Red 247
Pig. Red 175,
Pig. Red 171,
12467
12513
l252l
(Continued)
Consumpt ion t
1.9 x 106 kgs (79)
2.9 x 106 kgs (79)
2.1 x 106 kgs (79)
Use
Paints, lacquers, printing inks
Printing inks, paints, plastics, paper
coating, wall paper printing, bookcloth
Paints
Printing inks, plastics, stove finishes,
foil inks, paper coloring, cosmetics
Hanufacture of metal lakes
Hanufacture of metal salts for use as
pigments
Hanufacture of metal sslts for pigments
Paints, plastics, printing inks,
lacquers, emulsion paints
Plsstics, lacquers, inks
Plastics, lacquers, inks
Paints, lscquers, plastics
Paints, lacquers, plastics
Pisstics, ink, lscquers
(Continued)
-------
Colorant
-
RED (Continued)
Honoazo Red (blue shade red)
Na, Ca Lithols (light red-maroon)
Naphthol Red (blue shade red Ba salt)
Naphthol Red (blue shade red Ca salt)
Naphthol Red (bluish red)
Naphthol Red (bordeaux shade)
V1
o
I-"
Naphthol Red (dark red)
Naphthol Red (light red)
Naphthol Red (medium red)
Naphthol Red (yellow shade)
Naphthol Red (yellow shade red Ca salt)
Oracet Red 38
Para Red (medium to deep red)
Permanent Carmine HF4C
. ,
TABLE B- 5
(Continued)
Color Index
Consumptiont
Pig. Red 176, 12515
Pig. Red 185, 12516
Pig. Red 49, 15630 Ca: 6.6 x 106 kgs
(19) 106 kgs
Ba: 2.9 x
(19)
Pig. Red 151
Pig. Red 68, 15525
Pig. Red 150
Pig. Red 210
Pig. Red 14, 12380
Pig. Red 23, 12355 1.5 x 105 kgs (19)
Pig. Red 11, 12390 4.1 x 104 kgs (19)
Pig. Red 22, 12315 4.2 x 104 kgs (19)
Pig. Red 110
Pig. Red 210
Pig- Red 1, 12420
Pig. Red 9, 12460
Pig. Red 68, 15525
Pig- Red 1, 12010
Pig. Red 185
See Honoazo
Use
Plastics, lacquers, inks
Plastics, stoving lacquer, inks
Manufacture of metal lakes for rubber,
printing inks and enamels
Plastics
~
Oil paints, plastics, rubber, printing
inks, paper, emulsion paints
Paints, inks, plastics, textiles,
lacquers, paper
Inks, rubber, plastics, emulsion paints,
paints and enamels
Inks, lacquers
Paints, inks, emulsion paints,
distempers, plastics, cosmetics
Printing inks, paints, paper
Printing inks, plastics
Paints, printing inks, rubber, paper,
plastics, paper coating
Plastics, lacquers, Inks
(Continued)
-------
Colorant
REDS (Continued)
Perll8nent Red 11FT
Permanent Red BL
Permanent Red IIFH
Permanent Red 2B-Ba Salt (light red)
Permanent Red 2B-Ca Salt (medium red)
Perinone Red FTC
U1
o
N
Perinone Red (Anthraquinon~)
Perylene, nitrogen free
Perylene Vermillion
perylene Haroon
Perylene
Perylene Scarlet
Perylene lfedium Red
Pigment Scarlet 3B Lake (bluiah red)
[Hordant Red 9 and AI2(OH)3)
(Honoazo)
Pigment Scarlet-Be Salt [Honoazo)
i
.;
TABLE B-5
Color Index
Pig. Red 175
See Honoazo Red
Pig. Red 149
See Perylene Scarlet
Pig. Red 171
See Honoazo
Pig. Red 48: I,
15865: 1
Pig. Red 48: 2, 15865
Vat Red 15
Pig. Red 194, 71100
See Va t Red
Pig. Red 175
Pig. Red 123, 71145,
71140
Pig. Red 179, 71130
Pig. Red 224
Pig. Red 149, 71137
Pig. Red 190, 71140
Pig. Red 60, 16105
Pig. Red 60: I,
16105:1
See Pig. Scarlet 3B
(Continued)
Conaumptiont
3.0 x 105 kgs ~79)
8.1 x 1"05 kgs (79)
Use
Paints, lacquers, plastics
Plastics
Plastics, inks, lacquers
Printing inks, paints, plastics,
lacquers, rubber, paper, leathercloth,
cosmetics, textiles
Plastics, lacquers, inks'
Plastics
Paints, lacquers, plastics
Plastics, textile printing
Paints, inks, plastics
Plastics
Plastics, inks, plastics
Manufacture of metal salts
Printing inks, lacquers, plastics, rub-
ber, textile printing, emulsion paints
(Continued)
-------
~
RED (Continued)
Pyranthrone Orange
Pyrazolone (medium red) [D1sazo)
Pyrazolone Red (yellow shade)
[Disazo)
Quinacridone Hagenta [Quindo Hagenta)
R.K. Anthranthrone [Anthraquinone)
Red Lake R (light red)
VI
o
VJ
Thioindigo Red
Thioindigo Haroon
Thioindigo Pink
Thioindigoid
Toluidine Haroon (light red)
[Honoazo)
[Substituted amines coupled to
naphthol)
Vat Orange [Anthraquinone)
Vat Pink
Vat Red (medium red)
TABLE B-5
Color Index
Pig. Red 191, 59110
Pig. Red 38, 21120
Pig. Red 31, 21205
Pig. Red 122, 13915
Pig. Red 202
Pig. Red 168
See Vat Orange
Pig. Red 64
Pig. Red 86, 13315
Pig. Red 88, 13312
Pig. Red 198, 13390
Not assigned, 13390
Pig. Red 181, 13360
Pig. Red 131, 13360
Pig. Red 3, 12120
Pig. Red 13, 12395
Pig. Red 168, 59300
Pig. Red 181, 13360
See Thioindigo Pink
Pig. Red 194, 11100
(Continued)
Consumptiont
1.5 x 104 kgs (19)
9.8 x 104 kgs (19)
6.8 x 105 kgs (19)
\
Use
Rubber and plastics, occasionally print-
ing inks, lacquera, emulaion paints,
textile printing
Rubber and plastics
Plastica, inka, textile printing
Paints, inks, plast~cs
Inks, plastica, textile printing
Paints, inks, plastics, rubber
Paints, inks, plastics
Paints, inks, plastics
Paints, printing inks, emulsion paints,
distempers, plastics, rubber, textile
printing
Oil and emulsion paints, plastics, lac-
quers, printing inks, textile printing,
rubber, paper
Paints, inks, plastica
Paints, inks, plastics
Plastics
(Continued)
-------
Colorant
ORANGE
Anthanthrone Orange (brominated)
Anthramide Orange [Vat pigment)
Benzidine Orange
Benzimidazolone Orange
Brominated Pyranthrone
Cromophtal Orange 4R
Dianisidine Orange
VI
o
~
Dianisidine Orange GG
Diarylide Orange
Diarylide Orange RL
Dinitroaniline Orange [Honoazo)
[1-«2,4-Dinitrophenyl)Azo)-2-
Naphthol)
Disazo Orange 4R
GR Perinone Orange [vat pigment)
[Anthraquinone)
Homolog-Red Lake C (yellowish red)
lndofast Double Scarlet
lrgazin Orange RLT
Isoindolinone Orange
TABLE B-5
Color Index
Pig. Orange 168,
59300
Vat Orange 15, 69025
Pig. Orange 13, 21110
See Diarylide Orsnge
Pig. Orange 36, 11780
See Honoazo Orange
Vat Orange 14, 59710
Pig. Orange l6~ 21160
Pig. Orange 14
Pig. Orange 13, 21110
Pig. Orange 34
Pig. Orange 5
Pig. Orange 31
Pig. Orange 43, 71105
Vat Orange 7, 71105
Pig. Orange 46, 15602
Vat Orange 4, 59710
Pig. Orange 61
Pig. Orange 42
(Continued)
ConsWlptIont
7.1 x 102 kgs (79)
3.3 x 105 kgs (79)
1.6 x 105 kgs (79)
4.3 x 104 kgs (79)
4.1 x 105 kgs (79)
Use
Textiles, paper, paint, inks, plastics
Paints and printing inks, rubber, plas-
tics, paper, leathercloth
Paints, plastics, printing inks
Textiles (mainly)
Printing inks, rubber, plastics, paper,
textiles
Rubber
Printing inks, paints, plastics, rubber,
wallpaper, textile printing
Paints, printing inks, emulsion paints,
enamels and lacquers, paper, wax, rubber,
plastics
Plastics
Paints, printing inks, plastics
Printing inks, plastics, rubber, paint
Paints
(Continued)
-------
.
j
,
j
I.
J
1
!
!
i
. t
!
I
I
I
!
Colorant
ORANGE (Continued)
Hodified Azo Orange
Honoazo Red (Orange)
Honoazo Orange [Cl1H3N605CI)
Orange RK
Perinone Orange GR [Anthraquinone)
Pyranthrone Orange [Vat Pigment)
i
VI
o
VI
Pyrazolone Orange [Diaazo)
. t
Tolyl Orange
Quinacridone Gold
YELLOW
6-Amino Anthraquinone (yellow)
Anthrapyrimidine (yellow)
[Anthraquinone)
Anthrapyrimidine (yellow, medium
yellow)
Anthraquinone Yellow
Azo Ye llow
TABLE B-5
Color Index
Pig. Orange 38, 77878
Pig. Orange 36, 11780
Pig. Orange 60
Pig. Orange 62
Vat Orange 3, 59300
Vat Orange 7, 71105
Pig. Orange 43
See GR Perinone
Orange
Vat Orange 9, 59700
Pig. Orange 40
Pig. Orange 13, 21110
See Diarylide Orange
Pig- Orange 30
Pig. Orange 48
Pig. Yellow 108,
68420
Vat Yellow 20, 68420
Pig. Yellow 108
Dis. Yellow 3, 11855
(Continued)
Consumption t
1.5 x 106 kgs (79)
~
Paints, plastics, printing inks
Textiles, paints, inks, plastics
Textiles, paints, inks, plastics
Textiles (main use)
See Diarylide Orange
Paints, printing inks, vinyl plastics,
synthetic fibers, textiles
(Continued)
-------
Colorant
YELLOW (Continued)
Aznic Yellnw (light yellow)
Azoic Yellow (medium yellow)
Azoic Yellow, specialty (light yellow)
Azomethine Yellow [Irgazin yellow SCLT)-
Benzidine Yeilow [Disazo)
[2,2'-«3,3'-Di-chloro-4,4'-bi-
phenylene)diazo)bis-acetoacetanilide)
U1
o
(j\
Benzidine Yellow HR
Benzidine Yellow AAHX [Disazo)
Benzidine Yellow AAOA
Benzidine Yellow AAOT
Cromophtal Yellow 3G (yellow) [Disazo
Condensation Yellow)
Cromophtal Yellow 6G [Diaazo)
Cromophtal Yellow GR [Disazo)
Diarylide Yellow
TABLE B-5
Color Index
Pig. Yellow
Pig. Yellow
21126
Pig. Yellow
81, 21127
113,
16, 20040
Pig. Yellow 120,
11783
Pig. Yellow 151
Pig. Yellow 154
Pig. Yellow 129
Pig. Yellow 12, 21090
See Diaryl1de Yellow
Anilide
Pig. Yellow 13
See Diaryl1de Yellow
Xyl1dide
Pig. Yellow 17
See Diarylide Yellow
Ania1dine
Pig. Yellow 14
See Diaryl1de Yellow
Ortho Toluidide
Pig. Yellow 93
Pig. Yellow 94
Pig. Yellow 95
Pig. Yellow 106
(Continued)
Consumpt ion t
5.9 x 106 kgs (79)
2.2 x 105 kgs (79)
4.9 x 105 kgs (79)
1.9 x 106 kgs (79)
'.
Use
Paints, lacquers and printing inks, emul-
sion paints and distempers, plastic, PVC
Used cheifly in PVC, slso polyethylene
and polystyrene
Printing inks and lacquers, rubber, PVC,
paper, and textile printing
Rubber and plastics, printing ink, paint,
distempers
Printing inks of high transparency
Rubber and plastics, printing inks;
occasionally paints and paper
Plastics, paints and printing inks
Plastics, paints, printing inks, stove
enamels and lacquers
Plastics, paints, printing inks, stove
enamels snd ~acquers
(Continued)
-------
Colorant
YELLOW (ContInued)
Dlaryllde Yellow AAHX (lIght
transparent)
Dlaryllde Yellow NeG
Dlaryllde Yellow AnIlIde (lIght yellow)
[Dlaryllde Yellow AAA)
Dlaryllde Yellow Anlsldlde (lIght
yellow) [Dlaryllde Yellow AAOA)
D1aryllde Yellow, DR (medIum yellow)
Dlaryllde Yellow Ortho Toluldlde
(yellow)
\J1
o
-...J
Dlaryllde Yellow Xylldlde (lIght yellow)
Dlsazo Yellowa (other)
FD&C Yellow '5 AlumInum Lake (food
yellow 4) [Honoazo AlumInum Salt)
FD&C Yellow '6 Aluadnum Lake (food
yellow 3) [Honoazo AlumInum Salt)
Flavanthrone (yellow) [AnthraquInone)
Hanaa Yellow lOG (prlmroae, lIght
medIum yellow)
Hanaa Yellow R
TABLE B- 5
Color Index
PIg. Yellow 127
PIg. Yellow 16, 20040
See AzoIc Yellow
PIg. Yellow 12, 21090
Plg. Yellow 17, 21105
PIg. Yellow 83,
21108, 21118
PIg. Yellow 14, 21095
PIg. Yellow 13, 21100
PIg. Yellow 155
PIg. Yellow 128
PIg. Yellow 100,
19140: 1
PIg. Yellow 104,
15985:1
PIg. Yellow 24, 70600
PIg. Yellow 3, 11710
PIg. Yellow 10, 12710
(Continued)
ConsumpUont
Use
Lacquers, prIntIng Inks and plastIcs
See BenzIdIne Yellow
See BenzidIne Yellow AAOA
Halnly prIntIng Inka, occsslonally paInts
and lacquers
See BenzIdIne Yellow AAOT
See BenzIdIne Yellow AAHX
Cosmetics
CosmetIcs
PaInts, prIntIng Inks, plastIcs
PaInts, prIntIng Inks, emulsIon paInts,
dIstempers, lacquera, rubbers, textIles,
leather fInIshes, plastIcs
PrIntIng Inka, emulalon palnta and dIs-
tempers, paper coating, resins
(Continued)
-------
Colorant
~ (Continued)
Hans a Yellow 4R
Hansa Yellow G (Honoazo)
lrgazin Yellow SGLT
lrgazin Yellow 2GRT
lrgadn Yellow ZRLT, JaLT
(1soindol1none)
VI
o
00
lsoindoline Yellow
lsoindolinone Yellow (lrgazln Yellow
2G1lT)
lsoindolinone Yellow (lrgazin Yellow
ZRLT, JaLT)
Hodified Azo (light yellow)
Honoazo Yellow (light yellow)
(Permanent Yellow FGL)
Permanent Yellow FGL
Permanent Yellow OR
Permanent Yellow H2G
TABLE B-5
Color lnde"
Pig. Yellow 60, 12702
Pig. Yellow I, 11680,
11860
Pig. Yellow 129
See Azomethine Ye llow
Pig. Yellow 109
See lsoindolinone
Yellow .
Pig. Yellow 110
See lsoindolinone
Yellow
Pig. Yellow 139
Pig. Yellow 109
Pig. Yellow 110
Pig. Yellow 97,
11797, 11767
Pig. Yellow 97
See Hoooazo. Yellow
Pig. Yellow 83
See Diarylide Yellow
OR
Pig. Yellow 120
See Azoic Yellow
(Continued)
Consumption t
1.8 " 105 kgs (79)
Use
Paints, lacquers, printing inks, stains,
plastics, rubbers, paper, synthetic
fibera
Paints, printing inks, emulsion paints,
distempers, lacquers, rubbers, textiles,
leather finishes, pIss tics
Paints
Paints
Printing inks, stove lacquers
Heinly printing inks, some use in paints
and lacquera
Plastics
(Continued)
-------
Colorant
YELLOW (Continued)
Permanent Yellow HIOCH (Disazo)
Quinophtalone Yellow
Sandorin Yellow GeL (lsoindolinone)
Palitol Yellow 1090
DYES (SOLUBLE)
Acetate (wide color range)
Acid Chrome and Direct (wide color
range)
lJ1
o
1.0
Basic Dyes (wide color range)
Anthraquinone (yellow-red, green, blue,
brown)
BROWN-BLACK
Azo Dyes (4-(I-Naphthylazo)
m-phenylene-diamine)
(2,3-dihydro-2,2-dimethyl-6-«4
(phenylazo)-l-Naphthyl)azo)-
perimidine)
Azo Metal Complex Dyes
Nigrosine
Induline
TABLE B-5
Color Index
Pig. Yellow 113
See Azoic Yellow
Pig. Yellow 138
Pig. Yellow 109
Pig. Yellow 138
See Quinophtalone
Yellow
Sol. Brown I, 11285
Sol. 81ack 3
Sol. Brown 11
Sol. Black 21
SoL Black 28
Sol. Black 5, 50415
(Con ti nued )
Consumption t
Paints
Solvents.
lacquers
Solvents t
waxes
Use
fats, oils, waxes, inks.
inks. lacquers, oils, fats,
Polishes, waxes, inks, 011 stains,
lacquers, varnishes, plast1cs
Lacquers, wood stains, plastics
Lacquers
Solvents, varnishes, lacquers, wood
stains, leather, printing inks, rubber,
plastics
(Continued)
-------
Colorant
YELLOW
Anthraquinone Yellow Dyea
Monoazo Dyes
[N,N-dimethyl-p-phenylazo aniline]
(1-phenylazo)-2-naphthol)
O1sazo Dyes (01sazo)
VI
......
a
Azo [N-(4«2-Hydroxy-5-methyl phenyl)
azo)phenyl) acetamide)
Azo Metal Complex Dyes
Brilliant Sulfofavine [2,3-dihydro-6-
amino-1,3-dioxo-2-p-tolyl)-lH Benz-
(de)iso-quinoline-5-sulfonic acid,
monosodium salt)
Metan 11 Yellow
Honomethine
Palacet Yellow SF7861
TABLE B-5
Color Index
O1s. Yellow 64
Sol. Yellow 2, 11020
Sol. Yellow 16, 12100
Sol. Yellow 56, 11021
Sol. Yellow 14, 12055
Sol. Yellow 30, 21240
Sol. Yellow 11
Sol. Yellow 12
Sol. Yellow 29
Dis. Yellow 23
Dis. Yellow 3
Dis. Yellow 34
Sol. Yellow 65
Sol. Yellow 79
Sol. Yellow 81
Sol. Yellow 82
Sol. Yellow 48
Sol. Yellow 89
Sof. Yellow 95
Add Yellow 1
Add Yellow 36
Sol. Yellow 93
O1s. Yellow 13, 58900
(Continued)
Consumption t
1.6 x 105 kgs (79)
7.3 x 104 kgs (19)
Use
Lacquers, varnishes, waxes, oil stains,
styrene plastics
Shoe cream, polishes, candles, plastics
Hydrocarbons, shoe polishes
Oils and waxes
~. ,:
i.
t
..
Inks, hydrocarbons and solvents,
polishes, candles, plastics
Hydrocarbons and solvents
Hydrocarbons and solvents
Inks, stains, lacquers, waxes
Solvents
Solvents, lacquers, plastics, wood stain
Solvents, varnishes
Varnishes, inks
Plastics
Textiles, leather, paper, melamine and
urea resins
Textiles, paper, soaps, drugs, biological
stains, indicator, cosmetics, lacquers,
leather
Plastics
(Continued)
,.
,.
-------
.
. I
!
,
Colorant
YELLOW (Continued)
Palacet Yellow SF7862
Quinolene Yellow
ORANGI!
Anthraquinone Dyea Perinone
(Turn Signal Color)
Azo Dyea (1-(2,4-xylylazo)-
2-naphthol)
Azo Metal Complex Dyea
Xanthene Dyes
U1
......
......
RI!D
Anthrsquinone Reds Perinone
(TaUlight Red)
Amaplast Rubinol R
Azo Dyes D1sszo
(1-«4-(phenylszo) phenyl)szo)-2-
naphthalenol)
(1-«4(0-tolylazo)-o-tolyl)azo)-2-
nsphthol)
(N-ethyl-l-«p-(phenylazo)phenyl)-
azo)-2-naphthylamine)
TABLE B-5
Color Index
O1s. Yellow 116
Sol. Yellow 33, 47000
Sol. Orange 60
Sol. Orange I, 11920
Sol. Orange. 7
Sol. Orange 54
Sol. Orange 56
Sol. Orange 59
Sol. Orange 63
Sol. Red 135
Sol. Red 195
Sol. Red Ill, 60505
Sol. Red 52, 68210
Sol. Red I, 12150
Sol. Red 27, 26125
Sol. Red 23, 26100
Sol. Red 24, 26105
Sol. Red 3, 12010
Sol. Red 19
Sol. Red 22
501. Red 40
Sol. Red 26
(Continued)
Consumpt ion t
Uae
Lacquers, plastics, cosmetics, solvents
Plastics
Oils, waxes, fats, plastics
Oils, fats, waxes, solvents, plastics
Solvents,
stains
Solvents,
stains
Lacquers
lacquers, plastIcs, wood
lacquers, plastics, wood
PlastIcs
Plastics
Plastics
Plastics
Solvents, plastics
Oils, fats, waxes, cosmetics
Oils, fats, waxes, plastics, cosmetics
Solvents, floor polishes, plastics,
lacquers, varnishes, indicator
OIls, fats, waxes, wood stains, moulding
powder
Solvents, Inks, candles, oIls, plsstlcs
Oils, fats, waxes, solvents, inks,
lacquers
Inks, oil stains, candles, gasoline,
lacquers, plastics .
OIls, fats, waxes, plastics
(Continued)
-------
Colorant
RED (Continued)
Azo Ketal Complex Dyes
Congo Red (Sodium diphenyl-
bis-alpha-naphthalamine sulfonate)
Palacet Pink 5F-7867 (l,5-Diamino-
anthraquinone)
Palacet Red 5F-7874
Rhodamine B Base
Va t Red
VI
t-'
N
Xanthene (0-(6-(ethylamino)-
3(ethylimino)-2,7-dimethyl-3H-xan-
thene-9-yl)-Benzoic acid, ethyl
ester, monohydrochloride)
VIOLET
Anthraquinone (1-Hydroxy-4-(p-
Toluidino)anthraquinone)
Carbazole Oioxazine
Palacet Red Violet 5F-7868
(1,4 Diaminoanthraquinone)
Palacet Violet 5F-7870
Palacet Blue 5F-7872
TABLE B- 5
Color Index
Sol. Red 118
SoL Red 119
Sol. Red 122
Sol. Red 125
Dis. Red 4, 60755
Dis. Red 11, 62015
Dis. Red 60
Sol. Red 49, 451708
Vat Red 1, 73360
Acid Red 52
BaBic Red 1
Dis. Violet 31
Sol. Violet 13, 60721
Sol. Violet 14, 61705
SoL Violet 23, 51319
Dis. Violet 1, 61100
Ois. Violet 4, 61105
Sol. Violet 13, 60725
See Anthraquinone dye
(Continued)
Consumption t
8.0 x 105 kgs (79)
2.3 x 104 kgs (79)
,
! "
~. ' .
[;
.f'
, "
r
,"
f :"
Uae
Lacquera, wood stains, plastics
Lacquers, wood staina, plastics
Solvents
Solvents, inka, lacquers
Dye, medicine, indicator, biological
stain
Solvents, inka, carbon paper, plastics
Textiles
Textiles, leather, paper
Textiles, paper, inks, crayons, leather
Solvents, petrol, plastics, cosmetics
Oils, waxes, petrol, plastics, wood
stains
Solvents, Iscquers
(Continued)
-------
1
'J
i
" j
," !
Colorant
VIOLET (Continued)
.j
Rhodamine B [Xanthene)
[9-(o-Carboxyphenyl)-6-(Diethyla-
mino)-JR-Xanthen-3-ylidene)diethyl
ammonium chloride)
BLUE AND GREEN
Anthraquinone
(Alizarine)
Amaplast Blue RJK [Anthraquinone)
VI
......
W
Amaplast Bordeaux BPS
Azo Dyes
Azo Metal Complex Dyes
Phthalocyanine
Palacet Blue SF-78ll [1-«2-i1ydroxy-
ethyl)amino)-4-(methylamino)
anthraquinone)
Thermoplast Brillant Yellow lOG
[Anthraquinone)
Triphenylmethane Dye
-I
Unspecified
"
Xanthene Dyes
, ,
TABLE 8-5
Color Index
Basic Violet 10
Sol. Blue 56
Sol. Blue 5B
Sol. Blue 59
Sol. Green 3.' 61565
Sol. Green 28
Sol. Blue 16
Sol. Blue 35
Sol. Blue 67
Sol. Blue 53
Sol. Blue 70
DiB. Blue 3
Sol. Green 5.
Victoria Blue B
Sol. Blue 3, 61505
Sol. Green 4
59075
(Continued)
Consumptiont
5.7 x 105 kss (79)
Uae
Textiles. paper. inks. crayons.
distempers. leather. wood stain
Solvents. inka
Solvents, oils, fats, vaxes,
products. plastics. lacquers
Solvents. oils, fats, waxes,
products. plastics. lacquers
Solvents, 0118, fats, waxes,
stains. soap, plastics, inks
petroleum
petroleum
petrol, wood
Solvents, oils, fats. waxes, plastics
Solvents, oils, fats, waxes, lacquers
Lacquera. enamels. inka. plastIcs
Solvents. inks, lacquers, plastics
Solvents, plastics, lacquers, wood
stains
Solvents
Solvents, 0118, fats, waxes, textiles
Solvents, fats, 0118, waxes
(Continued)
-------
.J
Colorant
FLUORESCENTS
Biaazolea
Vinylenebiabenzoazolea
Coumarina HDAC (4-methyl-7-
diethylamino coumarin)
[3 phenyl-7 amino coumarina!
Stilbenea Derivativea of
atilbene-naphthotriazole (4-naph-
tho-triazolylatilbene)
Fluoreacent (dyed organic glaaa
particlea, full color range)
VI
......
~
Fluoreacent
(Pure dye, aaaorted color range)
~ I
(Sulfidea)
PHOSPHORESCENT
(zinc aulfide)
. .,
(zinc cadmium aulfide or calcium
atrontium aulfide!
PEARLESCENTS
Biamuth Coated Hica (pearly luater)
Biamuth Coated Talc (pearly luater)
TABLE B-5
Color Index
(Continued)
Conaumptiont
Uae
Optical bleach for textilea; paper,
label, book cover coatinga; plaatica,
reaina, varniahea, lacquera; invisible
marking agent
Pigment for glaaa; baae color for lakea;
rubbera and plaatica; dyeing (hydroaul-
fite proceaa); ingredient in lithopone;
phoaphor in X-ray and televiaion acreena;
luminoua watch facea; fungicide
Fluoreacent pigment; depilatory; luminoua
painta; aource of hydrogen aulfide;
manufacture of atrontium chemicala
(Continued)
-------
. j
. i
1
!
I
Colorant
PEARLE SCENTS (Continued)
Bismuthoxychloride (pearly luster)
(BiOCl)
Lead Carbonate I (brilliant pearl)
(xPbCO).yPb(OH)2)
Lead Carbonate II (opaque pearl)
(xPbCO).yPb(OH)2)
j
: ~ I
I
!
.1
..\
Hetallic Oxide Brown-FDA (high heat
stable) (x-Ferric oxide crystallized
from a borox melt) and other
composi tions
Hetallic Oxide Browns (high heat
stable)
.: !
i
.' I
VI
f-'
VI
Titanium Dioxide/Hica Composite (pearly
luster)
.I
: -'1
Titanium Dioxide/Hica/lnorganic Pigment
HETALLICS
Aluminum; Plastic Grades (silver)
. .
Bronze; Plastic Grades (red gold to
yellow gold)
(pale gold bronze (92% Cu, 6% en, 2%
AI»)
(rich pale gold bronze (90% Cu, 9.25%
Zn,O.75%Al»)
(rich gold bronze (77% Cu, 22% Zn, U
AI»)
[green gold bronze (68.75% Cu, )1% Zn,
0.25% AI)I
. .
.j
TABLE B-5
Color Index
Pig. Ketal 1, 77000,
77001
Pig. Ketal 2, 77400
(Continued)
Consumptiont
Use
Hedicine; cosmetics; pigment
Industrial paint pigment
Plastics pigment
Plastics pigment
I'Owder:
Paints and protective coatings; rocket
fuel; incendiary mixtures; catalyst;
foamed concrete; vacuum metallizing and
coating; plastics
Flakes:
Insulation of liquid fuels; plastics
Paint; cosmetics; fine arts; plastics
(Continued)
-------
/
TABLE B-5
Colorant
Color Index
Ij
"1
.1
1
~
..j
1
)
. J
,
.
HETALLICS (Continued)
Copper; Plastic Grades (coppery red)
(Continued)
Conswoptiont
tAnnual Consumption is presented parenthetically for the most recent year available.
V1
......
0\
Use
Powder:
Insecticides; catalysts; antifouling
paints; plastics
Flakes:
Insulation for liquid fuels; plastics
I.
I.
i
-------
:j
1
. :1
.'1
1
.oj
. 1
.1
. ,
1
. 1
1
Coupling Agents
~
N-a-Amlnoethylamlnomethylphenylethyl-
trlmethoxysl1ane
N-a-Amlnoethyl-~-amlnopropyltrlmeth-
oxysUane
Amlnophenyltrlethoxysl1ane
. .!
i
~-Amlnopropyltrlethoxyal1ane
Amyltrlmethoxyal1ane
j
. ;
Bls(a-Hydroxyethyl)-~-amlnopropyltrl-
e thoxyal lane
Y-chlorolaobutyltrlethoxysl1ane
: ~
VI
......
-...J
Chloromethylphenylethyltrlmethoxysl1ane
Y-chloropropyltrlmethoxysl1ane
a-Cyclohexylethyltrlmethoxyailane
a-(3,4-Epoxycyclohexyl)ethyltrlmethoxy-
sUane
~-Glycldoxypropyltrlmethoxysilane
~-Kercaptopropyltrimethoxysilane
~-Kethacryloxypropyltrlmethoxysl1ane
Hethylphenyltrlmethoxyailane
Hethoxyphenyltrlmethoxyal1ane
Octyltrlethoxysilane
Phenyltrlethoxyailane
Sulfonyl azide silane (proprietary)
TABLE B-6. COUPLING AGENTS
CONSUMPTION AND. OTHER USES
Consumptlont
Use
Coupling agent
Coupling agent for glaaa-resln, metal-resin, and
resin-rea In bonda; formulation of adhesives having
built-In primer systems
(Continued)
-------
.)
j
. "
.:.j
.1
'. j
TABLE B-6
(Continued)
Coupling Agents
ConsumpUont
Use
SILANES (Continued)
y-ureidopropyltriethoxysilsne
Vinylbenzyl cst ionic silsne
Vinylbenzylpropyltrimethoxysilane
~~ i
. ,
,
Vinyltriethoxysilane
Vinyltrimethoxysilane
.j
Vinyl-tris-(2-methoxyethoxy)silane
TITANATES
Acrylaaino pyrophosphate titanate
(KR-262A)
VI
f-'
00
Acrylojunctional organotitanate
pyrophosphate (KR-238A)
4-Aminobenzenesulfonyl dodecylbenzene-
sulfonyl ethylene titanate (KR-226S)
4-Aminobenzoyl. isostearoyl ethylene
titsnste (KR-237BS)
Di(butyl. methyl pyrophosphato) ethylene
titanate (KR-262S)
Di(butyl. methyl pyrophosphsto) ethylene
titanate mono(dioctyl. hydrogen
phosphate) (KR-262ES)
Di(butyl. methyl pyrophosphato) isopropyl
titanste di(dioctyl. hydrogen) phosphite
(KR-62ES)
Di(dioctyl phosphato)ethylene titanate
(KR-212)
Di(dioctyl pyrophosphsto) ethylene
titsnate (KR-238S)
(Continued)
-------
TABLE B-6
(Continued)
Coupling Agents
Consulllption t
Use
"
."
:. j
~', "1
. .1
'i
TITANATES (Continued)
Diisostesrylethylene titsnste [KR-201)
. i
i
Dodecylbenzenesulfonyl (4-slllinobenzene
sulfonyl), ethylene titsnste [KR-226S)
Ethylene, di(dioctyl)pyrophosphato
titanate [KR-238J)
"
Ethylene, di(dioctyl pyrophosphato)
titsnste dilllethylslllino-i-butsnol adduct
Isopropyl,4-aminobenzenesulfonyl,
di(dodecylbenzenesulfonyl) titanate
[KR-26S )
Isopropyl (di-4-alllinobenzoyl)isostearoyl
titanate [KR-37BS)
\J1
.....
\0
Isopropyl diacryl isostearoyl titanate
[KR-ll)
Isopropyl diisostearoyl scryl titanate
[KR-IO)
Isopropyl diisostearoyl methacryl
titsnste [KR-6)
Isopropyl,dimethacryl, isostearoyl
titanate [KR-7)
Isopropyl di(methyl, butyl pyrophosphste)
titanate [KR-62S)
Isopropyl isostearoyl discryl titanate
[KR-ll)
Isopropyl lIIethscryl diisostesroyl
titanate [KR-6)
Isopropyl octyl, butyl pyrophosphate
titanate [KR-58DS)
(Continued)
-------
"
I
:1
,
TABLE B-6
1
j
1
1
Coupling Agents
TITANATES (Continued)
Isopropyl, triscryl titsnste (KR-39BS),
(KR-39CS)
.!
,
Isopropyl tri(2-sminobenzoyl) titsnste
(KR-52S)
Isopropyl trisminoethylethylsmino
titanate (XKR-44U)
Is propyl tri(butyl, octyl pyrophosphato)
titanate di(dioctyl, hydrogen) phosphate
(KR-58FS)
Isopropyl tricumylphenyl titanate
(KR-34BS), (KR-34S)
VI
N
o
Isopropyl,tri(dioctyl phosphato)titanste
IKR-12)
Isopropyl tri(dioctyl pyrophosphato)
titanate IKR-38S)
Isopropyl,tridodecylbenzenesulfonyl
titanate IKR-9S)
Isopropyl,tri(N-ethylaminoethylamino)
titanate IKR-44)
Isopropyl triisostearoyl titanate
IKR-15), IKR-TTS)
Isopropyl tri(3-mercaptoproplonyl)
titanate IKR-66S)
Isopropyl trimethacryl titanate
(KR-33BS), IKR-33CS)
Isopropyl triricinoyl titanate (TTR-27)
Isopropyl tri(tetraethylenetriamine)
titanate IKR-63s)
(Continued)
Consumptiont
Use
Coupling agent; antistatic agent
"
(Continued)
-------
.,
. J
,
J
i
TABLE B-6
(Continued)
. j
,
. .
1
~ !
!
1
Coupling Agents
Consumption t
Use
TITAHATES (Continued)
OXoethylene di(butyl. octyl pyrophos-
phsto) titsnste dimethylsmino-i-butanol
adduct [KR-158D)
OXoethylene di(dioctyl pyrophosphato)
titanate dimethylamino-i-butanol adduct
[KR-138D)
Oxoethylene di(dioctyl) pyrophosphato
titanate di(dimethylsminopropyl meth-
scrylamide) [KR-138J)
Oxoethylene di(dioctyl)pyrophosphate
titsnate triethylamine complex [KR-138T)
Proprietary [KR-9T)
lJ1
N
......
Proprietary [KR-238T1
Pyrophosphato titanium ammonium meth-
acrylate [KR-23BHJ
Tetra(2.2-diallyloxymethyl-i-butoxy-
titanium di(ditridecyl)phosphite [KR-551
Tetraisopropyl. di(dioctyl phosphito)
titanate [KR-4IBJ
Tetraisopropyl di(tridecyl phosphito)
titanate [KR-36CJ
Tetraoctyloxytitanium di(dilauryl
phosphite) titanate [KR-468)
Tetraoctyloxytitantium di(ditridecyl
phosphite) [KR-468 J
Titanium acrylate isostearate oxyacetate
[KR-llOS)
Titanium 4-amlnobenzoate, lsostearate,
oxyacetate [KR-131BSJ
(ConUnued)
-------
-I
;
I
!
TABLE B-6 (Continued)
Coupling Agents
Consumption t
Use
TITANATES (Continued)
Titanium 4-aminobenzene sulfonate,
dodecylbenzenesulfonate, oxyacetate
[KIH26S)
Titanium diacrylate, oxyacetate
[KR-139BS), [KR-139CS)
Titanium di(butyl, octyl pyrophosphate)
di(dioctyl, hydrogen phosphite) oxyace-
tate [KR-158FS)
Titanium di(butyl, octyl pyrophosphate)
ozyacetate [KR-158OS)
Titanium di(cumylphenolate) ozyacetate
[KR-134BS), [KR-134CS)
IJ1
tV
tV
Titanium di(dioctyl phosphate~ ozyacetate
[KR-ll2S)
Titanium di(dioctyl pyrophosphate)
oxyacetate [KR-138S)
Titanium dimethacrylate, oxyacetate
[KR-133BS). [KR-133CS)
Titanium iaostearate methacrylate
oxyacetate [KR-I06), [KR-I06S)
Titanium (IV) bismethacrylate,
ozoethylene diolato [KR-133OSI
Titanium (IV) bis(methyl, butyl) pyro-
phnsphato, ethylenediol bis 3-N-dimethyl-
amino isobutanol [KR-262D)
Titanium (IV) trisacrylsto methoxydlgly-
cola to [XKR-39DS)
Titanium (IV) tris methacrylato methoxy-
glycolato [XKR-33OSI
(Continued)
, .
-------
Coupling Agents
TITANATES (Continued)
Tri(butyl. octyl pyrophosphsto) iso-
propyl titsnste mono(dioctyl. hydrogen
phosphite) (KR-58FSJ. (KR-58S)
J
!
Tris(dioctyl)pyrophosphsto. isopropyl
titanste
~ '
ESTERS
Calcium stesrste
Stesric acid
VI
N
l.o.)
PROPRIETARY ESTERS
Anti-Terra U-80 (Unssturated acid ester
neutrslized with polyaminoamine;
electroneutralJ
Surfsid-90 (fatty acid ester)
YP-I09 (Unsaturated fstty acid. anionicJ
YP-900 (Polymeric ester, anionicJ
YP-905 (Polymeric esters. unsaturated,
combination of anionic snd cationicJ
W-900 (Low molecular weight polymeric
saltJ
W-905 (Low snd medium moleculsr weight
polymeric salt snd anionic polymeric
salt)
W-910 (Hedium moleculsr weight fatty acid
based anionic)
TABLE B-6
Consumptiont
(Continued)
Use
Water repellant; flatting agent in paints; lubri-
cant in'making tableta; emulsions; cements; wax
crayons; stabilizer for vinyl resins; anticaking
agent in foods; cosmetics
Chemicals, especially stearates and stearate
dryers; lubricants; aoaps; pharmaceuticals and
cosmetics; accelerator activator. diapersing agent
and softener in rubber compounds; shoe and metal
polishes; coatings; food packaging
(Continued)
-------
TABLE B-6
(Continued)
Coupling Agents
Consumptiont
PROPRIETARY ESTERS (Continued)
W-980 (Medium IDOle~ular weight unsatu-
rated a~id ester neutralized with
polyamino amine)
W-960 (Medium IDOle~ular weight unsatu-
rated a~id eater I
MISCELLANEOUS PROPRIETARY
.;,
PROPRIETARY ORGANOSILICONS
Union Carbide Y-9518
Union Carbide Y-9602
Union Carbide Y-1616
U1
N
.J:'-
Union Ca rbide Y-9614
Union Carbide Y-4935
Union Ca rbide Y-9682
CHLORINATED PARAFFINS
Chlorez 100 (Chlorinated paraffins, 10%
CII
Chlorez 120 (Chlorinated psrsffins, 10+%
Cl)
Chlorez 160 (Chlorinated psraffins, 10+%
CII
CHROHE-GONTAINING
Hetha~rylsto ~hromic
tAnnual Consumption is presented parenthetically for the moat recent year available.
Use
-------
,
j
!
1
TABLE B- 7 .
CURING AGENTS AND CATALYSTS FOR THERMOSETTING RESINS
CONSUMPTION AND OTHER USES
..i
!
"1
Chemical
CoosUlDptiont
Use
AHlNES
Alkanolsmine (See Ethanolamine,
Triethanolamine)
J
j
,
,
m-Aminobenzylamine
p-Aminobenzylaminoaniline
N-Aminoethylethanolamine
Textile finishing compounds; resins; rubber
products; insecticides; certsin medicinals
N-Aminoethyl piperazine
Epoxy curing agent; intermediate for pharmaceu-
ticals; anthelmintics; surface active agents;
aynthetic fibers
Benzyl dimethyl amine
Intermediate, especially for quaternary ammonium
compounds; dehydrohalogensting cat~lyst; corrosion
inhibitor; scid neutralizer
. !
VI
N
VI
8is(dimethylaminoethyl) ether
8is(hexamethylene)triamine
i
i
4-Chloroorthophenylene dismine
N-COcomorpholine
Cyclohexylpropylene diamine
Diallyltetrahydriodipyridyl
Diaminocyclohexane
Diaminodiphenyl methane
Determination of tungsten and sulfates; polymer and
dye intermedIate; corrosion inhibitor; epoxy resin
hardening agent; isocyanate resins; polyamides
Diaminodiphenyl sulfone (DDS)
(Sulfonyl dianiline)
Curing sgent for epoxy resins; medicine
3,5(Diaminomethyl) aniline
2,6-Diaminopyridine
(Continued)
-------
Che.ical
AHINES (Continued)
Dicyanodiamine
Diethanola..ine
Diethylamine
Diethyla..inoethanol
\J1
N
'"
Diethylaminopropylamine [DEAPA)
Diethylenetriamine [DETA)
Dimethylamine
Dimethyla..inoethanol
Dimethyla..inoethyl piperazine
Dimethylaminomethyl phenol
N,N-Dimethyla..inopropylamine
1,I'(3(Dimethylamino)propyl)
imino bis(2-propanol)
TABLE B-7
ConsUlDptiont
(Continued)
Uae
Liquid detergenta for e..ulsion paints;
oils; sha..poos; cleaners and polishes;
specialties; absorbent for acid gases;
intermediate for resins, plasticizers,
solubilizing 2,4-0
cutting
textile.
che..ical
etc. ;
Rubber che..icals; textile specialties; selective
solvent; dyes; flotation agents; .resins; pes~i-.
cides; polymerization inhibitors; pharmaceuticals;
petroleum che..icals; electroplating; corrosion
inhibitors
Water soluble salts; fatty acid derivatives;
textile softeners; phsrmaceuticals; antirust com-
positions; emulsifying agents in acid media; deri-
vatives containing tertiary a..ine groups; curing
agent for reains
Curing agent for epoxy reains; inter..ediate
Solvent for sulfur, acid gaaes, various resins,
dyes; saponification agent for acidic materials;
fuel component
Acid gas absorbent; solvent; antioxidants; manufsc- .
turing of dimethylformamide and dimethylacetamide;
dyes; flotation agent; gasoline stabilizers; phar-
maceuticals; textile chemicals; rubber accelera-
tors; electroplating; dehairing agent; missile
fuels; pesticide propellant; rocket propellants;
8urfactants
Antioxidants; atabilizers; catalysta; intermediates
Curing agent for epoxy resina; organic intermediate
(Continued)
, .
-------
,
1
j
1
i
i
j
1
,
.,
j
Chemical
. AHlNES (Continued)
Dimethylaminopy~idine
N,N-Dimethylbenzylamine
!
.1
Dimethylcyclohexylamine
Dimethylethanolamine
N,N-Dimethylhexadecylamine
N,N-Dimethylpipe~azine
.j
J
. !
Di(mo~pholinoethyl)ethe~
V1
N
-...J
Ethyldiethanolamine
N-Ethylenediamine
N-Ethylmo~pholine
Glycidylethe~ polyamine adducts
Heptamethylisobiguamide
Hexsmethylenediamine
Hexamethylenetet~amine
N-(B-Hyd~oxyethyl)pipe~azine
N(2-Hyd~oxyp~opyl)ethylenedi-
amine
TABLE B-7
ConsUIDptiont
(Continued)
Use
Catalyst fo~ polyu~ethane foama; inte~mediate fo~
rubbe~ accele~ato~a; t~eatment of textiles
Inte~mediate in the synthesis of dyestuffs, textile
auxilia~ies, pha~maceuticala and co~~oaion inhibi-
to~s; medicine; cu~ing fo~ epoxy, amine artd polya-
mide ~esins; emulsifie~
Cu~ing agent fo~ polyu~ethane foama; intermediate
fo~ cationic su~face active agents
Solvent; dete~gents
FUngicides; manufactu~e of chelating agents;
dimethylolethylene-u~ea ~esins; chemical inte~-
mediate
Inte~mediate fo~ dyestuffs, pha~l88ceuticals, ~ubbe~
accele~ato~s and emulsifying agents; solvent fo~
dyes, ~esins oils; catalyst fo~ polyu~ethane foams
Fo~mation of Nylon 6/6
Catalyst fo~ phenol-fQ~maldehyde and ~eso~cinol-
fo~maldehyde ~esins; ing~edient in ~ubbe~-to-
textile adhesives; p~otein modifie~; o~ganic
synthesis; pha~maceuticals; ing~edient in high
explosive cyclonite; fuel tablets
Inte~mediate fo~ pha~maceuticals, anthelmintics,
su~face active agents and synthetic fibe~s
(Continued)
-------
Chemi"al
AHlNES (Continued)
3,3'-lminob1spropylamine
Menthane diamine
N-Hethoxyethylmorpholine
o-Hethylbenzyldimethylamine
p,p'-Hethylenedianiline
(p,p'-dia8inodi-phenylmethane)
N-Hethylmorpholine
V1
N
CO
Methylpiperzine
Monomethylamine (Methylamine)
Honoethanolamine
(2-Aminoethanol)
Hoooethylamine
Olefin oxide-polyamine addu"t
Pentaethylenehexamine
TABLE B-7
Consumption t
(Continued)
!!!!
Intermediate for soapa, dyeatuffs, rubber "hemi-
"als, emulsifying agents, petroleum apecialties,
inse"ti"ides, and pharma"euti"ala
Curing agent for epoxy resins; "hemi"al
intermediate
POlymerization "atalyat
Determination of tungsten and aulfatea; polymer and
dye intermediate; "orroaion inhibitor; epoxy resin
hardening agent; iao"yanate reains; polyamides
Catalyst for polyurethane fosl88; extra"tion sol-
vent; stabilizing sgent for "hlorinated hydrocar-
bons; self-polishing waxes; oil emulsions; "orro-
sion inhibitor; pharma"euti"als
Intermediate for pharma"euti"als, surfa"e agents,
syntheti" fibers
Intermediate for accelerstors, dyes, phsrma"euti-
"sls, inse"ti"ides, fungicides, surfa"e a"tive
agents; tanning; dyeing of acetate textiles; fuel
additive; polymerization inhibitor; "omponent of
paint removers; solvent; photographi" developer;
rocket prope llant
s.,rubbing s"id gases; nonioni" detergents for dry
cleaning, wool treatment, emulsion paints,
polishes, agri"ultural sprays; "hemi"al intermedi-
ates; phsrmaceuti"als; "orrosion inhibitor; rubber
accelerator
Dye intermediates; solvent extra"tion; petroleum
refining; stabilizer for rubber latex; detergents;
organic synthesis
(Continued)
-------
1
-]
:.,
.1
.,
Chellical
AHlNES (Continued)
m-Phenylenedialline
1
. ,
1
j
Piperidine
Polyoxyalkylenepolyamine
Pyridine
Pyrrol1dine
Quinucl1dine
VI
N
\0
SUicone amine
Tetraethylenepentamine
N-Tetramethylethylenediamine
N-Tetramethyl-l,3-butanediamine
Tetramethylguanidine
Triaminomethylbenzene
Tri(dimethylaminomethyl} phenol
Triethanolamine borate
Triethylamine
TABLE B-7
Consumptiont
(Continued)
Use
Dyestuff manufacture: detection of nitrous scid:
textile developing sgent: laboratory reagent
Solvent and intermediate: curing agent for rubber
and epoxy resins: catalyst for condensation reac-
tions; ingredient in oils and fuels; complexing
agent
Synthesis of vitamins and drugs; solvent; water-
proofing: rubber chemicals; denaturant for alcohol
and antifreeze mixtures: dyeing assistant in tex-
tiles; fungicide
Intermediate in pharmaceuticals, fungicides, insec-
ticides, rubber accelerators; citrus decay control:
curing agent for epoxy resins; inhibitor
Solvent for sulfur, acid gases, various resins and
dyes; saponifying agent for acidic materials; manu-
facture of synthetic rubber: dispersant in motor
oils; intermediate for oil additives
Preparation of epoxy
formation; corrosion
agents; intermediste
compounds
curing agents; polyurethane
inhibitor; textile finishing
for quaternary aamonium
Catalyst for polyurethane foams and epoxy resins:
high energy fuels
Antioxidants, acid neutralizers, stabilizers snd
cstalysts for epoxy and polyurethane resins
Catalytic solvent in chemical synthesis; accelera-
tor activators for rubber; wetting, penetrating and
waterproofIng agents of quaternsry smmonium types;
curing and hardening of polymers; corrosion inhibi-
tor; propellsnt
".
(Continued)
-------
/
)
j
!
Chemical
AHlNES (Continued)
Triethylenedia1l1ne
Triethylenetetramine
1,2,4-Trimethylpiperazine
2,4,6-Tris(dimethylaminoethyl)
phenol
2,4,6-Tris(dimethyI81linomethyl)
phenol
1,3,S-Tris«H,N-dimethyl-3-
allino)propyl)- S-hexahydro-
triazine
m-Xylidenediamine
AHlNE OXIDES
VI
v.>
o
Dimethyldodecenylamine-N-oxide
Pyridine-N-oxide
Trimethylalline-N-oxide
AHIDES
l,l-Dimethylurea
1,3-Dillethylurea
1,3-Diphenylurea (carbanilide)
l~ethylurea
I-Phenylurea
Urea (carbamide)
TABLE B-7
Consumption t
(Continued)
Use
Catalyst for polyurethane
Detergents and softening agents; synthesis of dye-
stuffs, pharmaceuticals and rubber accelerators
POlymerization catalyst
Intermediate
Intermediate in synthesis of drugs
Organic synthesis
Fertilizer; animal feed; plastics; chellical Inter-
mediate; stabilizer in explosives; medicine; adhe-
sives; separation of hydrocarbons; sulfamlc acid
production; flame-prooflng agent; viscosity
modifier for starch or casein-based paper coatings;
reported helpful In treating sickle cell anemia
.'
i
'[..',:.
, .
,
(Continued)
-------
. .
,
Chemical
-
IHIDAZOLES
Benzimidazole
I-N-Butylimidazole
I-H-Cyclohexylimidazole
Z-Ethyl-4-methylisldazole
N-Propylill1dazole
KETAL COMPOUNDS
ANTIHONY
Antimony pentachloride
\J1
l.u
......
Antimony trichloride
CALCIUM
Calcium acetate
Calcium carbonate
Calcium naphthenate
TABLE B-7
ConsumpUont
(Continued)
Use
Curing epoxy resins
Analysis of alkaloids and cesium; dyeing; interme-
diates; as s chlorine carrier in organic
chlorinaUons
Antimony sslts; bronzing iron; mordsnt; manufactur-
ing lakes; chlorinating agent in organic synthesis;
pharmaceuticals; fireproofing textiles
Manufacture of acetone. acetic acid, acetates; mor-
dant in dyeing snd printing of textiles; stabilizer
in resins; additive to cslcium sosp lubricants;
food sdditive, ss antimold agent in bakery goods,
in sausage casings; cstalyst manufacture; medicine
Source of lime; neutralizing agent; filler snd
extender in rubber, plastics, psints; opacifying
agent in psper; fortification of bread; putty;
tooth powders; sntscid; whitewash; Portland cement;
SOZ removal from stack gases; metallurgical flux;
analytical chemistry; COZ generation (laboratory)
Waterproofing compositions; adhesives; dryers; wood
fillers; grafting waxes; cements; varnishes; color
lakes
(Continued)
-------
Chemical
~ (Continued)
Tricalciua phoaphate (Calcium
phosphate, tribasic)
~
Chromium (III) triacetyl
acetonate
Chromium (III)
tri-2-acetylcyclohexanoate
VI
I.,.)
tV
Chromium (III)
tri(dibenzoylmethane)
Chromium (III) tri(I,3-
Diphenyl-I,3-pentanedioate)
Chromium (III) tri(I,3-
diphenyl-I,3-propanedioate)
Chromium (III)
tri-2-ethylhexanoate
Chromium (III) tri(l-phenyl-
1,3-butane-dione)
Chromium (III) tripicolinoate
COBALT
Cobalt benzoate
Cobalt 2-ethylhexoate [Cobalt
octoate)
Cobalt naphthenate (Indefinite)
TABLE B-7
Consumptiont
(Continued)
~
Ceramics; calcium acid phosphate; phosphorus and
phosphoric acid; polishing powder; cattle foods;
clarifying-sugar syrups; medicine; mordant; ferti-
lizera; dentifrices; stabilizer for plastics; in
meat tenderizers; in foods as anticaking agent,
buffer, nutrient supplement; can remove strontium-
90 f rom milk
Reduction of detonation of nitromethane
Paint dryer; whitener; catalyst
Paint and varnish dryer; bonding rubber to steel
and other metals
t.
, .
(Continued)
-------
Chemical
LEAD
Lead benzoate
Lead 2-ethylhexoate
Lead naphthenate
Lead oleate
Litharge, sublimed
\.J1
W
W
HANGAllESI!
Manganese 2-ethylhexoate
[Manganese octoate)
Manganese Ilnoresinate
Manganese naphthenate
(Indefinite)
PHOSPHORUS
Hexamethylphosphorlc trlsmlde
(Hempa)
Tri-n-butylphosphine
Trlbutyldodecylphosphonlum
iodide
Trioctylphosphine oxide
Triphenyl phosphine oxide
TABLE B-7
ConsUllptiont
(Continued)
Use
Paint and varnish dryer; wood preservative; insec-
ticide; catalyst for resctlon between unsstursted
fatty sclds and sulfates in air; lube oil sdditive
Varnishes; lacquers; paint dryer; high pressure
lubricants
Storage batteries; ceramic cements and fluxes;
pottery and glazes; glass; chromium pigments; oil
refining; varnishes, paint, enamels, ink, linoleum;
insecticides; cement; acid-resisting compositions;
other lead compounds; rubber accelerator
Primarily as a dryer for paints, enamels, vsrnishes
and printing Inks
Paint and varnish dryer
Ultraviolet inhibitor in polyvinYl chloride; chemo-
sterilant for insects; promoting stereospecific
reactions; specialty solvent
Polymerization crosalinking catalyst; Inorganic
intermediate; fuels
Reagent for extraction of metals from aqueous and
nonaqueous solution, including fissionable actinide
elements
(Continued)
-------
Chemical
TIN
Dlbutyltindiacetate
.\
;
Dibutyltindilaurate
Dibutyltindioctoate
[Dibutyltindi-2-ethylhexoateJ
.~
.j
Dibutyltinbisisooctylmaleate
Dibutyltinbiaisooctylmercapto-
acetate
Dibutyltinbislsurylmercaptide
Dimethyitinbisisooctyimaleate
VI
W
.po
Dimethyltin isooctylmercapto-
acetate
\
. !
Dimethyltinbislaurylmercaptide
Stannous chloride
Stannous octoste
[Stannous-2-ethylhexoateJ
Stannous oleate
!
.\
TABLE B-7
Consumptlont
(Continued)
Use
Stabilizer for chlorinated organics; catalyst for
condensation reactions
Stabilizer for vinyl.resins, lacquers, elastomers;
catalyst for polyurethsne
Catalyst for silicone curing; polyether foams
Antioxidant and metal cleaning agent
Reducing sgent in manufacture of chemicsls, inter-
mediates, dyes, polymers, phosphors; manufacture of
lakes; textiles (reducing agent in dyeing, dis-
charge to printing); tin galvanizing; reagent in
analytical chemistry; 8Bdicine; silvering mirrors;
revivification of yeast sown in must; antisludging
agent for lubricating oils; food preservative;
stabilizer for perfume in soaps
POlymerIzatIon cstalyst for urethane foams; lubri-
cant; additIon sgent; stabilizer for trsnsformer
oils
Polymerizaton catalyst; inhibItor
. }
~, .
t.
,
(Continued)
-------
. .
.
Chemical
ZINC
Zinc acetate
Zinc-2-ethylhexoate [Zinc
octoate)
Zinc naphthenate
ZInc oxide [ZnO)
VI
W
VI
ZIRCONIUM
Zirconium 2-ethylhexoate
Zirconium naphthenate
ZIrconium toluene
HISCELLANEOUS KETAL COHPOUNDS
Aluminum isopropoxide
Aluminum-sec-butoxide
Barium carbonate
Cerium naphthenate
TABLE B-7
Consumptiont
(Continued)
~
Hedicine; preserving woods; textile dyeing (mordsnt
and resist); zinc chromate; laboratory reagent;
feed additive; crosslinking agent for polymer~;
ingredient in dietary supplements
Catalyst
Dryer and wetting agent in paints, varnishes, and
resins; insecticide, fungicide and mildew preserva-
tive; wood preservative; waterproofing textiles;
insulating materials
Accelerator, activator, pigment and reinforcing
agent in rubber; ointments; pigment and 1I01d growth
inhibitor in paints; ceramics; floor tile; glass;
zinc salts; feed additive; dietary supplement; seed
treatmenti cosmetics; semiconductor in electronic
devices; photoconductor in copy machines and color
photography; piezoelectric devices
Ceramic enamels and glazes; lubricants; paints and
varnishes
Dehydrating agent; catalyst; waterproofing
text lIes
Ester exchange catalyst; defoamer ingredient;
hydrophobIc agent intermediate
Treatment of brines in chlorine-alkali cells to
remove sulfates; rodenticide; barium salts; cera-
mic flux; optical glaas; case hardening baths;
ferrites; in rsdiation-resistant glass for color
television tubes
(Continued)
-------
Chellical
i
J
!
MISCELLANEOUS KETAL COMPOUNDS
(Cont1nued)
Lanthanum naphthanate
LithiUli acetate
MagnesiUli acetate
Magnesiull Oxide
MonopotassiUli glycoxide
PotassiUli acetate
V1
W
0\
Potassium octoate
Potassium oleate
Sodium propionste
Strontium carbonate
Tri-n-butylarsine
MISCELLANEOUS
Aminodiboron
Benzyltrimethylammonium
chloride
Cresyl1c acid
TABLE B-7
Consullpt1on t
(Continued)
Use
Dye fixative in textile printing; medicine;
deodorant, disinfectant and antiseptic
Befractorles, especially steel furnace linings;
polycrystalline cerallic for aircraft windshields;
electrical Insulation; pharmaceuticals and cosme-
tics; Inorganic rubber accelerator; oxychloride and
oxysulfate cellents; paper manufacture; fertilizers;
removal of sulfur dioxide from stack gases, adsorp-
tion and catalysis; selilconductors; food and feed
additive
Dehydrating agent; textile conditioner; reagent In
analytical chemistry; medicine; acetone; cacodylic
derivatives; crystal glass; laboratory reagent
Textile soaps; emulsifying agent
Fungicide; mold preventive; food preservative
Catslyst; In radlatlon-reslstsnt glass for color
television tubes; ceramic ferrltes; pyrotechnics
Solvent for cellulose; gelling Inhibitor for poly-
ester resins; Intermediate
Phosphste esters; phenolic resins; wire enamel
solvent; plasticizers; gasoline additives; lami-
nates; coating for magnet wire for small electrical
motors; dlsinfectsnts; metal cleaning cOllpounds;
phenolic resins; flotation agents; surfactants;
chemical Intermediates; 011 additives; solvent.
refining of lubricsting oils; scouring compounds;
pes t1cides
(Continued)
-------
Chemical
MISCELLANEOUS (Continued)
j
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i
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. .
,
;
1
Dicyand1amtde
Dimethyldilauryl ammonium
chloride
B-Hydroxyethyltrimethyl
ammonium hydroxide
Para formaldehyde
Tetrahydroxydiboron
Tetrapropylammonium chloride
Trimethylboroxine
Trioxane
.'
1
U1
VJ
......
ACIDS
Acetic add
Ammonium chloride
Ammonium fluoride
Boric add
TABLE B-7
ConsumptIont
1.3 x 109 kgs (82)
(total)
(Con tinued)
Use
Fblymerization of cyanamide in the presence of
beses
Fungicides, bacteriacides and disinfectanta; adhe-
sives; hardener and waterproofing agent for gelatin
Organic syntheais; diainfectant; nonluminoua,
odorless fue 1
Manufacture of acetic anhydride, cellulose acetate
and vinyl acetate monomer, acetic esters, and
chloroacetic acid; production of plastics, rubber,
pharmaceuticals, dyes, insecticides, photographic
chemicals, etc.; food additive; latex coagulant;
oil well acidizer; textile printing
Dry batteries; mordant in dyes and printing;
soldering flux; manufacture of various ammonia com-
pounds; fertilizer; pickling agent in zinc coating
and tinning; electroplating; washing powders; snow
treatment; resin and adhesive in urea-formaldehyde;
medicine; food industry
Fluorides; analytical chemistry; antiseptic In
brewing; etching glass; textile mordant; wood
preservation
Heat resistant glass; glass fibers; procelain ena-
mels; boron chemicals; metallurgy; fireproofing
compositions for textile products such as cotton
batting in mattresses; fungus control on citrus
fruits; ointment and eye wash; nickel electro-
plating
(Continued)
i,:
-------
I
,
,
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VI
l..>
(XI
TABLE B-7
ChelDical
ConaumptIont
~ (Continued)
Boron trifluoride
Carbon dioxide
3.4 x 109 kga (82)
(total)
Cinnamic acid
N-Cyclohexyl aulfamate
Hydrochloric acid
2.3 x 109 kgs (82)
( total)
Oxslic acid
Phosphogypsum
Phos pho r ic ac id
7.1 x 109 kgs (82)
(total )
(Continued)
Use
Catalyst in orgsnic synthesis; instruments for mea-
suring neutron intensity; silver soldering fluxes;
gss brazing
Refrigeration; carbonated beverages; aerosol pro-
pellant; chemical intermediate; low temperature
testing; fire extinguishing; inert atmospheres;
municipal vaste treatment; medicine; enrichment of
air in greenhouses; fracturing and acidizing oil
wells; mining; miscellaneous pressure source;
hardening of foundry molds aod cores; shielding gas
for welding; cloud seeding, moderator in some
nuclear reactors; immobilization for humane animal
killings; apecial lasers; blowing agent
Medicine; perfumes; intermediate
Acidizing of petroleum wells; chemical intermedi-
ate; ore reduction for tin aod tantalum; food pro-
cessing; pickling and metal cleaning; industrial
acidizing; general cleaning; alcohol denaturant;
laboratory resgent; production of chlorides;
manufacture of phosphoric acid; starch modifier;
production of vinyl chloride
Automobile radiator cleanser; general metal and
equipment cleaning; purifying agent and intermedi-
ate for many compounds; leather tanning; catalyst;
laboratory reagent; stripping agent for permanent
press resins; bleaching of textiles; rare-earth
proceasing
Fertilizers; soaps and detergents; inorganic phos-
phates; pickling and rust-proofing metals; pharma-
ceuticals; sugar refining; gelatin manufacture;
water treatment; animal feeds; eie~tro-polishing;
gasoline sdditive; conversion coating for metals;
catalyst for ethanol manufacture; lakes in cotton
dyeing; yeasts; soil stabilizers; waxes and
polishes; binder for ceramics; activated carbon; in
foods and carbonsted beverages as scidulant snd
sequestrant; lsboratory reagent; source of uranium
(experimentsl); intermediste; catslyst for making
ethylene; flavoring for ~.,ft drinks
t.
,.
"
(Continued)
-------
TABLE B-7
. J
'!
.~
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~ .j
Chemical
Conaumptiont
~ (Continued)
Phthalic anhydride
'J
)
Succinic anhydride
Sulfuric acid
2.9 x 1010 kga (82)
( total)
VI
W
\0
p-Toluenesulfonic acid
Thioglycolic acid
~
Ammonia
1.4 x 1010 kgs (82)
( total)
8arium hydroxide
(Continued)
~
Alkyd resins, plasticizers, hardener for resins,
polyesters, synthesis of phenolphthslein snd other
phthaleins, many other dyes, chlorinsted products,
phsrmaceutical intermedistes, insecticides; diethyl
phthalate, dimethyl phthalate; laboratory reagent
Manufacture of che.icala, pharmaceuticals, esters,
hardener for resins
Fertilizers, che.icals; inorganic pig.ents; petro-
leum refining, manufacture of titanium dioxide,
ammoniua sulfate, dyestuffs, other acids, paper,
and glue, etchant, alkylation catalyst, electro-
plating baths, iron and steel, rayon and film;
industrial explosives, laboratory reagent, nonfer-
rous metallurgy, dehydrating agent for ethers and
esters, gas drying, obtaining glucose from
hydrolysis of cellulose
Dyes; organic synthesis; organic catalyst
Fertilizers; manufacture of nitric acid, hydrazine
hydrate, caprolactam, acrylonitrile, hydrogen cya-
nide, urethsne, acrylonitrile and sodium carbonate,
refrigersnt, nit riding of steel, condensation
catalyst, synthetic fibers, dyeing; neu~alizing
agent in petroleum industry, latex preservative,
sulfite cooking liquors, fuel cells, rocket fuel,
yeast nutrient, developing diazo films, explosives,
solvent, cleaning and bleaching, cotton defolisnt
Manufacture of oil and grease additives, bariu.
soaps and che.icals, refining of beet sugar; alka-
lizing .agent in water softening, sulfate removal
agent in treatment of water and brine, boiler acale
removal, dehairing agent, catalyst in manufacture
of phenol-formaldehyde resina, insecticide and
fungicide, sulfate controlling agent in ceramics,
purifying agent for caustic soda; ateel carbonizing
agent; glass
(Continued)
-------
;'
I
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j
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i
,
TABLE B-7
. '~
j
Chemical
Conaumption t
~ (Continued)
Calcium hydroxide
Lime
Lithium carbonate
Lithium hydroxide
VI
.p-
O
Magnesium hydroxide
Monosodium phosphate
Potassium hydroxide
1.9 x 109 kgs (75)
(total)
Sodium aluminate
(Continued)
Use
Mortar; plastersi cements; calcium salts; caustl-
cizing soda; hydrogen; depilatory; unhairing of
hides; lime paints; aedicine; agriculture; ammonia
recovery in gas manufacture; disinfectant; water
softening; purification of sugar juices; accelera-
tor for low-grsde rubber compounds; water paints;
soil stabilizer; petrochemicals; food additive
See Calcium Hydroxide
Ceramic and" porcelain glazes; pharmaceuticals;
catalyst; other lithium compounda; coating for arc"
welding electrodes; nucleonics; luminescent paints,
varnishes and dyes; glasa ceramics; aluminum
production
Storage battery electrolyte; carbon dioxide absor-
bent in space vehicles; lubricating greases;
ceramics
Intermediate for obtaining magnesium metal; sugar
refining; medicine; residual fuel oil additive;
sulfite pulp; uranium processing; dentrifices; in
foods as alkali, drying agent, color retention
agent; frozen desserts
Medicine; baking powder; nutrient solutions; yeast
foods; buffer and sequestrant in foods; laboratory
reagent
Soap manufacture; bleaching; manufacture of potas-
sium carbonate and tetrapotassium pyrophosphate;
electrolyte in alkaline storage batteries and some
fuel cells; absorbent for carbon dioxide and hydro-
gen sulfide; dyestuffs; liquid fertilizers; food
additive; herbIcides; electroplating; inks;
analytical chemistry
Mordsnt; zeolites; wster purification; sizing
paper; manufacture Qf ,lilk-glass, soap and cleaning
"compounds
, "
!:"
(Continued)
-------
I
1
J
'I
Chemcal
t
!
j
'!
BASES (Continued)
Sodium bicarbonate
i
j
Sodium hydroxide
V1
.l:-
I-'
Strontium hydroxide
CATALYST NEUTRALIZERS
Amines
Phosphorous pentoxide
[phosphoric anhydride)
Sodium hydroxide [See Bases)
Tricslcium phosphste
Triethsnolamine
TABLE B-7
Consumptiont
8.2 x 109 kgs (82)
(total)
(Continued)
Use
Manufacture of effer~escent salts and be~erages,
srtificial mineral water, baking powder, other
sodium salts; pharaaceuticals; ,-ponge rubber; gold
~nd platLnum plating; treating wool and silk; fire
extinguishers; ceramics; pre~ention of timber mold;
laboratory resgent; antacid; mouthwash; skin oint-
ment; cleaning compound
Chemical asnufacture; rayon and cellophane; petro-
leum refining; pulp and paper; aluminum; deter-
gents; soaps I textile processing; vegetable oil
refining; reclaiming rubber; regenerating ion
exchange resins; organic fusions; peeling of fruits
and vegetables in food industry; laboratory
reagent; etching and electroplating; precipitation
of alkaloids; neutralizLng acids; deshorning
cal~es; explosivee and dyestuffs; electrolytic
extracton of zinc
Extraction of sugar from beet sugar molasses;
lubricant soaps and greases; stabilizer for
plastics; glass; adhesives
Preparation of phosphorus oxychloride and meta-
phosphoric acid; acrylate esters; surfactants;
dehydrating agent; organic synthesis; medicine;
sugar refining, laboratory reagent; fire extin-
guishing; special glasses
See Bases
See Ketal Compounds
Fatty acid soaps used in dry cleaning, cnamp-tLcs,
household detergents, and emulsions; wool scouring;
textile antifume agent and water repellant; dis-
persion agent; corrosion inhibitor, softening
agent, humectant and plasticizer; insecticide;
chelating agent; rubber sccelerator
r..
;,
(Continued)
-------
..,!
Chemical
RESIN STABILIZERS
2-Amino-2-methyl-l-propanol
Dimethylallinoethanol
II-Phenylenediamine (See Amines)
Triethylamine (See Amines)
TABLE B-7
Consumption t
..
(Continued)
t"
~
Use
i
I
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!
f'
L
(
Emulsifying .agent for oils, fats and waxes; absor-
bent for acidic gases; chemical synthesis
Intermediate in the synthesis of dyestuffs, tex-
tile auxilaries, pharmaceuticals and corrosion
inhibitors; curing epoxy, amine and polyamide
resins; emulsifier
. .
f
See Amines
See Amines
tAnnual Consumption is presented parenthetically for the most recent year available.
VI
~
N
,
. ~
i
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,
,
, "
TABLE B-8.
FILLERS AND REINFORCERS FOR PLASTICS
CONSUMPTION AND OTHER USES
",
i
..
Filler
Consumptiont
Use
INORGANIC EXTENDERS
Alumina, hydrated
[AI 20). 3H20)
2.7 x 108 kgs (80)
Glass, ceramics. iron-free. aluminum and aluminum salts; manufacture of
activated alumina; base for organic lakes; flame retardant; rubber
reinforcing agent; paper coating; filler; cosmetics
Aluminum, powder (AI)
Paints; protective coating; rocket fuel; ingredient of incendiary
mixtures; catalyst; foamed concrete; vacuum metalizing and coating
Aluminum hydroxide (See
Alumina, hydrated)
Aluminum oxide [Al~))
[Emery), (Sapphire)
Production of aluminum; manufacture of abrasives, refractories,
ceramics, electrical insulators, catalyst and catalyst supporta; paper;
spark plugs; crucibles and laboratory ware; absorbing gases and water
vapors; chromatographic analysis; fluxes; light bulbs; artificial gems;
heat resistant fibers
Aluminum silicate [See Clay)
In
.po
IJ.)
Antimony trioxide
Flame prooHng textiles, paper, plas tics; paint pigments; ceramic
opacifier; catalyst; intermedlate; staining iron and copper; phosphors;
mordant; glas8 decolorlzer
Barium csrbonate, precipitated
[BaCO)), [Witherite)
Treatment of ~rines
rodenticide; barium
baths; ferrites; in
tubes'
in chlorine-alkali cells to remove sulfates;
salts; ceramic flux; optical glass; case-hardening
rsdiation resistant glass for color television
Barium ferrite
. i
Barium titanate [BaTiO))
Barium sulfate [BaS04)
Weighting mud in oil drilling; paper coatings; paints; filler and
delustrant for textiles, rubber, linoleum, oilcloth, plastics and
lithographic ink; base for lake colors; X-ray photography; opaque
medium for gastrointestinal radiography; in battery plate expanders
Barytes
Blanc fixe (barium sulfate,
precipitated)
Barium sulfide
Dehairing hides; fireproofing agent; barium salts; generating pure
hydrogen sulfide for analytical purposes
(Continued)
: ~
:,
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-------
Filler
INORGANIC EXTENDERS
(Continued)
Bentonite clay
Beryllium oxide (BeO)
0.:
Bronze (1-10% Sn in Cu)
Cadmium sulfide (CdS)
lit
~
~
Calcium carbonate (CaCO))
Cslcium fluoride (CaF2)
Calcium hydroxide (lime)
(Ca(OH)2)
':
Calcium silicate, precipitated
(CaSiO) J
.
- I
- !
TABLE B-8
Consumption t
2.5 x 109 kga (75)
(total)
2.5 x 109 kgs (Bl)
(Continued)
Use
Oil-well drilling fluids; ce.ent slurriea for oil-well casings; bonding
agent in foundry sands and pelletizing of iron ores; sealant for canal
walls; thickener in lubricating greases and fireproofing compositions;
cos.utics; decolorizing agent; filler in ceramics, refractories, paper
coatings; asphalt modifier; poUshes and abradves-; food additive;
catalyst support; absorbent; manufacture of animal feed; pet litter
absorbent
Electron tubes; resistor cores; windows in klystron tubes; transistor
mountings; high-temperature reactor systems; additive to glass,
ceramics and plastics;. preparation of beryllium compounds
Paint; cosmetics
Pigments and inks; ceramic glazes; pyrotechnics; phosphors;
screens; scintillation counters; rectifiers; photoconductor
xerography; transistors; photovoltaic cells; solar cells
fluorescent
in
Source of lime; neutralizing agent; filler and extender in rubber,
plastics, and paints; opacifying agent in paper; fortification of
bread; putty; tooth powders; antacid; whitewash; Portland cement; S02
removal from stack gases; metallurgical flux; analytical chemistry;
C02 generation
Source of fluorine and its compounds; flux in open hesrth steel fur-
naces snd in-metal s.ulting; in ceramics; for synthetic cryolite; in
carbon electrodes; emery wheels; electric arc welders; certain cements;
dentrifices; phosphor; paint pigment; catalyst in wood preservatives;
optical equipment
~.
Hortar; plasters; cements; calcium salts; causticized soda; hydrogen;
depilatory; unhairing of hides; lime paints; medicine; agriculture;
ammonia recovery in gas manufacture; disinfectant; water softening;
purification of sugar juices; accelerator for low grade rubber com-
pounds; water paints; soil stabilizers; petrochemicals; food additive
as buffer and neutralizing agent
Adsorbent; antacid; adhesives; filler for paper and paper coatings;
cosmetics; food additlve (anticaking agent)
(Continued)
-------
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Filler
INORGANIC EXTENDERS
(Continued)
Calcium sulfate (CaS04)
Clay (Kaolin), (Aluminum
sUicate)
(A120-2Si02'2H20)
Calcined
Copper, powdered (Cu)
V1
.P-
V1
Emery (See Aluminum Oxide)
Feldspar (Potassium alumino-
sUicate) (KAlSiJDS)
:j
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Glass
,
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Graphite
Iron, powder (Fe)
Iron oxide (Fe20))
i
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INORGANIC EXTENDERS
(Continued)
Kieselguhr [See Diatomaceous
Earth)
Kryolite [Sodium Fluoro-
aluminate)
Lead, powder [Pb)
Lead oxide [PbO)
Lithium aluminum silicate
~ j
J
;
:\
"J
j
,
Lithopone [72% BaS04 + 2B%
ZnS)
VI
.t-
'"
Hagnesium carbonste,
precipitated [HgCO))
Magnesium hydroxide
Magnesium odde
Msgneaium silicate.
precipitated
[3HgSiO)' 51120)
i
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,
Hagnetite [Ferrous-ferric
Oxidel. [See" Iron Oxide)
TABLE B-8
(Continued)
Conaumptiont
1.2 x 108 kgs (75)
(total )
8.6 x 107 kgs (74)
(total)
Use
i""
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f
!"
t.
Storage bitteries; tetraethyl lead; radiation shielding; cable cover-
ing; ammunition; sheet and pipe; solder snd fusible alloys; type metal;
vibration damping in hesvy construction; foil; numerous alloya
Chemical intermediate; ointments; plasters; glazing pottery; glass
flux; dryer for varnishes; pigment for rubber; storage battery plates;
rubber activator; insecticides; metal cement; coloring sulfur-contain-
ing substances; artificial tortoise shell and horn
See Barium Sulfate and Zinc Sulfide
Hagnesium salts; heat insulation and refractory; rubber reinforcing
agent; inks; glass; pharmaceuticals, dentrifices and cosmetics; free-
running table salts; mineral waters; filtering medium; in foods as
alkali, drying agent, color retention agent, anticaking agent and
carrier
Intermediate for obtaining magnesium metal, magnesium carbonate and
magnesium chloride; sugar refining; medicine; residual fuel oil
additive; sulfite pulp; uranium processing; dentifices; in foods as
alkali, drying agent, color retention agent; frozen desserts; neutrali-
zation of acids
Refractories; polycrystalline ceramic for aircraft windshields; elec-
trical insulation; pharmaceuticals and cosmetics; inorganic rubber
accelerator; oxychloride and oxysulfate cements; paper manufacture;
fertilixers; removal of sulfur dioxide from stack gases; adsorption and
catalysis; semiconductors; pharmaceuticals; feed and food additives
Rubber filler; ceramics; glass; refractories; adsorbent for crude oil
spills; manufacture of permanently dry resins and resinous composi-
tions; paints, varnishes and paper (filler); animal and vegetable oil
bleaching agent; odor absorbent; filter medium; catalyst and catalyst
carrier; anticaking agent in foods
(Con ti nued )
-------
Piller
INORGANIC EXTENDERS
(Cont1nue~)
Hica [Potaasium Aluminum
Silicate!
Holybdenum disulfide
.'j
Ne phe line
[(Ns, K)(Al,Si>204!
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Nickel, powder
Perlite [See Silica)
VI
~
--.J
Pumice [67-75% Si02 + 10-20%
AI20)!
Pyrophyl11te
[AI2Si401O(OH) !
Rottenstone
Silica
Diatomaceous Earth
Pumed
- TABLE B-8
Consumpt ion t
4.5 x 105 kgs (80)
5.0 x 108 kgs (72)
(total)
1.0 x 107 kgs (80)
8.2 x 107 kgs (80)
(Continued)
Use
Electrical equipment; vacuum tubea; incandescent lamps; dusting agent;
lubricant; windows in high temperature equipment; filler in exterior
paints; cosmetics; glass and ceramic flux; roofing; rubber; mold
release agent; specialty paper for insulation and filtration; wallpaper
and wallbosrd joint cement; oil-..ell drilling muds
Lubricant in greases, oil dispersions, resin-bound films, dry powders,
etc.; hydrogenation catalyst; microprobe analysis of soil erosion
aerosols
Cersmic and glass manufacture; enamels; source of potash and aluminum
Alloys; electroplated protective coatings; electroformed coatings;
alkaline storage battery; fuel cell electrodes; ceramics; catalyst for
fuel gas and vegetable oil production
Concrete aggregate; heat and sound insulation; filtration; finishing
glass and plastics; road construction; scouring preparations; paint
fillers; absorbents; support for catalysts; dental abrasive; abherent
for uncured rubber products
Manufacture of glass, vater glass, ceramics; abrasives; water filtra-
tion; component of hydraulic cements; source of ferrosilicon and ele-
mental silicon; filler in cosmetics, pharmaceuticals, paper, insecti-
cides; rubber reinforcing agent; anticsking agent for foods; flatting
agent in paints; thermal insulator
Piltration, clarifying and decolorizing; insulation; absorbent; mild
abrasive; drilling mud thickener; extender in paints, rubber and plas-
tics products; cersmics; paper coating; anticaking agent in ferti-
lizers; asphalt compositions; chromatography
Thickener, thioxtrophic and reinforcing agent in inks, resins, rubber,
paints, cosmetics, etc.
(Continued)
-------
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INORGANIC EXTENDERS
(Cont1nued)
SiIics (Continued)
Fused
SiUca gel
Silicon carbide (SiC)
Sla te flour
VI
~
00
Sodium aluminum hydroxy-
carbonste (Dawsonite)
Sodium aluminosilicate
Sodium aluminum fluoride
. ..
Steel, stainless
.'
. .
Talc
(magnesium silicate)
(Hg3Si4010(OH>2)
Titsnium dioxide, Rutile,
Anatase
Zinc, powder
I
TABLE B-8
Consumpt1ont
1.2 x 108 kgs (75)
(total crude)
1.5 x 108 kgs (82)
(in plast1cs)
2.0 x 108 kgs (82)
(tn plast1cs)
(Continued)
Use
Ablative material in rocket engines, spacecraft, etc.
Dehumidifying and dehydrating sgent; air conditioning; drying of com-
pressed air and other gases snd liquids; recovery of natural gasoline
from natural gss; bleaching of petroleum oils; catslyst and catalyst
csrrier; chromatography; anticaking agsnt in cosmetics and pharmaceu-
ticals; in waxes to prevent slipping
. f
Abrasive for cutting and grinding metals; grinding wheels; refractory
in nonferrous metallurgy, ceramic industry and boiler furnaces; compo-
site tubes for steam forming operstions; semiconductor; structural com-
ponent of nuclear reactors
Filler In rubber and paint; abrasive
Anticaking agent in food preparations; dentrifice
Construction; ship hulls; auto bodies; machinery and machine parts;
csbles; sbrasive; chemical equipment; belts for tire reinforcement
Ceramics; cosmetics snd phsrmaceuticsls; filler in rubber, paints,
soap, putty, plaster, oilcloth; abherent; dusting agent; lubrIcant;
paper; slate pencils and crsyons; electrical insulstion; refractories;
fireproofing wood
53% in paints, varnishes, lacquers; 21% in paper; 10% in plastics; 3%
in elastomers; 2.5% in ceramics; 2% in floor covering; 2% in prInting
inks; 1% in costed fabrics and textiles; 1% in roofing granules; 4.5%
for other pigments
Alloys; gsivanizing iron and other metals; electroplsting; metal spray-
ing; automotive parts; electrical fuses, anodes; dry cell batteries;
fungicides; nutrition; roofing and gutters; engraver's plates; csble
wrsppings; organ pipes
(Continued)
-------
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~
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Filler
INORGANIC EXTENDERS
(Continued)
. 1
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Zinc oxide [ZnO)
. !
Zinc sulfide [ZnS)
Urconis [ZrOl)
.~
. -. ~
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Zirconium silicste
VI
~
1.0
ORGANIC EXTENDERS
NATURAL
-,
Bsgasse [From Sugsr Cane)
Bsrk, ground
Carbon black
"
Cherrystone flour
Carbon hollow spheres [See Fly
Ash)
Casein
TABLE B-8
Consumptiont
5.4 x 107 kgs (SO)
(Continued)
Use
Diffusing pigment; accelerator; activator; reinforcing agent; oint-
ments; pigment and mold-groyth inhibitor in paints; ceramics; floor
tIle; glass; zinc salts; feed additive; dietary supplement; seed treat-
ment; COSqettCSj sealconductorj photoconductor
Diffusing pigment; white and opaque glass; base for color lskes; rub-
bers; dyeing; phosphor in X-ray and television screens; luminous yatch
fsces; fungicides
Production of piezoelectric crystals; high frequency induction coils;
colored ceramics glazes; special glasses; source of zirconium metal;
hest resistant fibers; odor absorbent; to cure dermatitis caused by
poison ivy; refractory furnace linings, crucibles, etc.; solid electro-
lyte for batteries
Source of zirconia, metallic zirconium and halfium; abrasives; refrac-
tortes; enamels; refractory procelaln
Paper; insulating board in construction; medium for growth of nutritive
bacteria; animal feeds; manufacture of furfural
Pigment; reinforcing agent; pigment for cements, ceramic ware, mortar,
inks, linoleum, surface coatings, crayons, polishes, carbon paper,
soap, etc.; in insulating compositions; liquid-air explosives; matches;
fertilizers; furnace lutes; lubricatlng compositions; carbon brushes
Cement additive for oil-field yell casings; adsorbent for oil spills
(silicone coated); fi~ler in plastics; source of germanium
Cheese making; plastic items; paper coatings; yater-dispersed paints
for interior use; adhesives, especially for yood laminates; textile
sizing; foods and feeds; textile fibers
(Continued)
-------
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VI
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NATURAL EXTENDERS (Continued)
Coconut-shell flour
Cof fee, ground
Cellulose, hydrated
Cellulose, oxidized
Cork dus t
Ply Ash (C), (Soot)
Gllsonite
Keratin (ground feathers)
Lignin, processed
Peanut shells, ground
Pecan shell flour
PetroleWl coke
Blce hull ash
TABLE B-8
Consumption t
4.0 x 106 kgs (80)
8.2-9.1 x 107 kgs
(79) (total)
1.2 x 107 kgs (80)
(all shell flours)
1.2 x 107 kgs (80)
(all shell flours)
1.2 x 107 kgs (80)
(all shell flours)
(Continued)
Use
In the manufacture of paper, vulcanized fiber, mercerized cotton,
viscose rayon
Surgery and medicine; ion exchange medium; thickening agent
See Carbon Spheres
Acid, alkali and waterproof coating; black varnishes, lacquers, baking
enamels and japans; wire insulation compounds; linoleWl and floor tile;
paving; insulation; diluent in low-grade rubber compounds; a possible
source of g3s01ine, fuel oil and metallurgical coke; raw material for
explosives and nuclear graphite industries; dark photographIc lnks
Component of groundwood paper (newsprint); stabilization of asphalt
emulsions; ceramic binder and deflocculant; dye leveler and dispersant;
drilling fluid additIve; precipitation of proteins; extender for
phenolic plastics; special molded products; vanillin; source of a
component of battery expanders
Reduction of iron ore in blast furnaces; source of synthetic gas;
refractory furnace linings in electrorefining of aluminum and other
high-temperature service; for electrodes in electrolytic reduction of
alumina to aluminum; electrothermal production of phosphorus, silicon
carbide and calcIum carbide
(Continued)
-------
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NATURAL EXTENDERS (Continued)
Rubber, natural (Gutta Percha)
Saw duat
"
Soybean meal
Starch
. .
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,...
Walnut-ahell flour
SYNTHETIC EXTENDERS
Acrylic
Cellophane
Phenol-Formaldehyde
Polyfluoroethylene
Polyethylene
Polyatyrene
INORGANIC FIBERS
Alumina (ceramic) (A120])
Aluminum (AI)
TABLE B-8
Consumption t
1.2 x 107 kga (80)
(all shell flours)
1.2 x 107 kga (80)
(all shell flours)
(Continued)
Use
Tires; hoses; conveyor belt covera; footwear; specialized mechanical
products; drug sundries; foam rubber; electric insulation; cements;
adhesives
Animal feeds; abrasivea; medium for bacitracin production
Adhesive; machine-coated paper; textile filler and sizing agent; bester
additive in papermaking; gelling agent and thickener in fooda; oil-well
drilling fluids; filler in baking powdera; fabric stiffener in lsunder-
ing; ures-formaldehyde resin adheaive for particleboard and fiber-
board; explosives; dextrin; chelating and sequeatering agent in foods;
indlcator in analytical chemistry; anticaking agent In sugar; face
powders; abherent and mold release agent; polymer. base
See Organic Fibers, see alao IPPEU Chapters 10 and lOa
Wrapper or protective packaging
Hany different products, see IPPEU Chapters 10 and lOa
See Organic Fibers, see also IPPEU Chapters lO snd lOa
Hany different products, see IPPEU Chapters 10 and lOa
Hany different products, see IPPEU Chapters 10 and lOa
See Inorganic Extenders
(Continued)
-------
. "
..)
Filler
INORGANIC FIBERS (Continued)
Aluminum nitride
Aluminum oxide (Alt03)
Aluminum sillcste
[A120)"Si02)
Asbestos
Beryllia (ceramic)
Beryllium
Vt
Vt
N
Beryllium carblde [BezC)
Beryllium oxide
Boron
Boron carbide [B4C)
Boron nltrlde [BN)
Boron tungsten fllament
Calcium sulfate [Franklin
fiber)
Carbon
TABLE B-8
ConsumptIont
4.5 x 108 kgs (82)
(in plastics)
2.7 x 105 kgs (73)
(total Be capacity)
1.6 x 106 kgs (82)
(Continued)
Use
See Inorganlc Extenders
Nonwoven fabrics; woven fabric structures; cordage; thermal insulation;
repair of furnace l[nlngs; piping molten metals; welding insulation;
insulation for rocket and spsce appllcations
Fireproof fabric~ brake lining; gaskets; roofing composltions; electri-
cal and heat lnsulation; paint fliler; chemical fllters; reinforcing
agent in rubber and plastics; component of paper.dryer felts;
diaphragm cells
See Inorganlc Extenders (Beryllium Oxide)
(8e): Beryllium-copper alloys; refractor in ceramics; radio, tele-
vlsion and fluorescent tubes; moderator and neutron source in nuclear
reactors; additlve in solid propellant rocket fuels
(Be2C):
Atomlc energy applications; experimental rocket fuels
See Inorganlc Extenders
Aircraft and spacecraft composltes; woven fabrlcs
(B4C): Abrasive powders; abrasion resister and.refractory; control
rods in nuclear reactors; reinforcing agent in composltes for mllitary
aircraft and other apecial applicatlons
(BN): Refractory; furnace insulation; cruclbles; rectlfying tubes;
dlelectric; chemical equipment; self-lubrlcating bushlngs; molten metal
pump parts; transistor and rectifler mounting wafers; heat shleld for
plasma; Dose-cone windows; heat reslstant fibers for military compo-
sltes; metalworking abrasive; high temperature insulator; high strength
fibers
See Inorganlc Extenders
(Continued)
-------
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.
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INORGANIC FIBERS (Continued)
Carbon-dialllOnd
Chromium
Copper
Fybex [See Potassium titanste)
Glass
\J1
\J1
W
Graphite
Hsfis (ceramic) [Hf02)
Iron
Iron-nickel
Magnesia [HgO)
Hagnes1um
!
Holybdenum
Nickel
TABLE B-8
Consumption t
1.3 x 108 kgs (82)
(Continued)
.'
Use
(Cr): Alloying and plating element on metal and plastic for corrosion
resistance; chromium-contsining snd stsinless steels; protective.
coating for automotive snd equipment accessories; nuclear and high
temperature reaearch; constituent of inorganic pigments
Thermal and electrical composites
Thermal, acouatic and electrical insulation (coarse fibers in bata or
sheets); decorative and utility fabrics such as drapes, curtains, table
linen, carpet backing, tenting, etc.; tire cord, as belt between tread
and carcass; filter medium; reinforced plastica; light transmission for
communication .signals; reinforcement of cement products for
construction use
Heating pads (combined with glasa fiber); protective clothing for elec-
trical workers; polyester and epoxy composites for jet engine compo-
nents, 8pacec~aftJ compressor blades. airframe structures; electrodes
for spark-bardening metals
(Hf02):
Refractory metal oxide
See Inorganic Extenders
See Inorganic Extenders (Magnesium Oxide)
(Hg): Ailoys for structural parts, die cast auto parts, missles, space
vehicles; powder for pyrotechnics and flash photography; production of
iron, nickel, zinc, etc.; magnesium compounds and Grignard synthesis;
cathodic protection; reducing agent; precision instruments; optical
mirrors; dry and wet batteries
(Ho): Alloying agent in steels and cast iron; high temperature alloys;
tool steels; pigment for printing inks, paints and ceramics; catalyst;
solid lubricants; missile and aircraft parts; reactor vessels; cermetsj
die-casting copperbase alloys; special batteries
See Inorganic Extenders
(Continued)
-------
Filler
INORGANIC FIBERS (Continued)
Sapphire (See Aluminum Oxide)
Processed mineral fiber
Potassium titanate (Fybex)
(K20'(Ti02)n n-4-7)
Qusrtz (ceramic)
SiUca
Silicon carbide (Silagl
SiUcon nitride
\J1
V'
.po.
Sodium aluminum hydroxycar-
bonate (Dawsonite)
Steel
Tantalum
Thoria (ceramic) (Th02)
Titanium
Tungsten
TABLE B-8
ConsumpUont
(Continued)
Use
Rockets, missiles, nuclear power applications as an insulator
(Quartz): Electronic components; piezoelectric cnntrol in filters,
oscillators, frequency standards, wave filters, radio and TV compon-
ents; barrel-finishing abrasive
Reinforced plastics, see also Inorganic Extenders
~. .
See Inorganic Extenders
See Inorganic Extenders
(Ta): Capacitors; chemical equipment; dental and surgical instruments;
rectifiers; vacuum tubes; furnace components; high speed tools; cata-
lyst; getter alloys; sutures and' body implants; electronic circuitry;
thin film components
(Tb02): Cersmics; gas mantles; nuclear fuel; flame spraying; cruci-
bles; medicine; nonsilica optical glass; catalyst; thoriated tungsten
filaments in incandescent lamps, cathode in electron tubes and arc-
melting electrodes
(Ti): Alloys (especially ferrotitanium); as structural material in
aircraft, jet engines, missiles, marine equipment, textile machinery,
chemical equipment, surgical instruments, orthopedic appliances, food-
handling equipment; X-ray tube targets; abrasives; cermets; metal-
ceramic brazing; electrodeposited and dip coating on metals and cera-
mics; electrode in chlorine battery
(W): High speed tool steel; ferrous and nonferrous alloys; ferro-
tungsten; filaments for electric light bulbs; contact points;
dentistry; X-ray and electron tubes; welding electrodes; heating
elements lo furnaces and vacuum metallizing equipment; rocket nozzles
and other aerospace applications; shell steel; chemical apparatus; high
speed rotors as Ln gyroscopes; solar energy devices
(Continued)
-------
FUler
INORGANIC FIBERS (Continued)
Tungsten monocsrbide
Wollastonite (CaSi03)
Zlrconia (Zr02)
Zircon (66% Zr02 + 33%
Si02)
ORGANIC FIBERS
NATURAL
Abaca (Hanila hemp)
VI
VI
VI
Broomroot
o-Cellulose (Paper pulp)
Coir
Corn cobs and stalks
Cotton flock
linters
Cottonseed hulls
Crin vegetal
Flax (Bast fibera)
Hemp
TABLE B-8
(Continued)
Consumptiont
Use
Ceramics; paint extender; welding rod coatings; rubber filler; silica
gels; paper coating; filler in plastics, cements and wallboard; mineral
wool; soil conditioner
See Inorganic Extenders
Heavy cordage and twine; manila paper
Apparel; industrial and household fabrics; automobile tires;
upholstery; medicine
Rayon manufacture; cellulosic plastics; nitrocellulose lacquers; aoil-
cement binder in road conatruction; explosives
Apparel fabrics (linen); thread; rope; twine; cigarette paper; dupli-
cating. paper
Blended with cotton or flax in towelling and heavy fabrics; twine;
cordage; packaging
(Continued)
-------
Filler
NATURAL FIBEBS (Continued)
Henequen
Istle (Talllpico)
Jute (Bast fibers)
Kapok
Palm
Palmyra
Paper
Piassava
Ramie (Helllp)
i
VI
VI
0\
Raffia
Sisal
Sunn
Wood flour (Wood flock)
Wood cellulose (Paper pulp)
(See -Cellulose)
Wool
SYNTHETIC FIBERS
Acrylic
A ramid
Carbon
..
TABLE B-8
Consulllptiont
1.2 x 1010 kgs (B2)
7.7 x 105 kgs (82)
1.6 x 106 kgs (82)
(Continued)
Use
Binder twine; cordage
Burlap; sacking; linoleum, twine; carpet backing; packing; coarse paper
Life jackets; insulation; pillows; upholstery
High grade paper; fabrics (weaving apparel and car seat covers); stern-
tube packing in ships; patching water mains
TWine; rope; sacking; upholstery; life preservers
Manufacture of dynamite; filler for plastics, rubber and paperboard;
fur cleaning; polishing agents; Sorel cement
Newsprint; cheap manila papers; nonpermanent ti9Sues
Outerwear; blankets; carpets; upholstery; felts; clothing; source of
lanolin
Kodacrylic fibers; blankets; carpets, see also IPPEU Chapters 10 and
lOa
See Graphite Fibers
(Continued)
-------
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TABLE B-8
Fi ller
Consumptiont
SYNTHETIC FIBERS (Continued)
Fluorocsrbon (PTFE)
Nylon
Polyscrylonitrile [Dyne 11,
[OrIon)
Polyester
Polypropylene
U1
U1
--.J
Polyvinyl alcohol
Polyvinyl chloride
Rayon
(Continued)
Uae
Hany dIfferent products, see IPPEU Chapters 10 and lOa
Tire cord; hosiery; apparel component; bristle for toothbruahes, hair-
bruahea, paInt bruahea; cordage and towllnea for gliders; flah neta and
linea; tennis rackets; ruga and carpets; turf for athletIc fIelds;
parachutes; composites; 88118; automotive upholstery; surgical sutures;
see also IPPEU Chap'ten 10 and lOa
See AcrylIc Fibers
Tire fabric; seat belts; reinforcement in rubber hose for seawater
cooling systems; as blended in clothing fabrIcs; fIre hose jackets;
see also IPPEU Chapters 10 and lOa
Carpets; upholstery; cordage and bristles; storage battery cases; arti-
ficial grass and turfs; wearing apparel; fish nets; surgical casts;
strapping; synthetic paper; reinforced plastics; see also IPPEU
Chapters 10 and lOa
See IPPEU Chapters 10 and lOa
Hany dIfferent products, see IPPEU Chapters 10 and lOa
Nonwoven fabrics; surgIcal dresaings; wearing apparel; mechanical
rubber gooda; coated fabrics; felts and blankets; blends wIth cotton
for home furnishings; tire cord
tAnnual COnsumptIon is presented parenthetically for the most recent year avaIlable.
-------
-'
,
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Flame Retardant
INORGANICS
Alumina trihydrate
Ammonium bromide
j
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.,
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,
j
Ammonium fluoroborate
Ammonium orthophoaphate
[Ammonium phoaphate, dibaaic)
VI
VI
00
Ammonium pentaborate
,'!
Ammonium polyphoaphate
i
:1
Ammonium aulfamate
Anti.mony pentoxide
Antimony trioxide
.,
'!
j
I
;', .' ~
Barium metaborate
Borax
TABLE B-9. FLAME RETARDANTS
CONSUMPTION AND OTHER USES
ConaumpUont
3.2 x 108 kga (79)
(in plaaUca)
5.0 x 109 kga (75)
(total)
2.2 x 106 kga (72)
(total)
3.2 x 107 kga (79)
(in plasUcs)
5.4 x 108 kgs (75)
(total, estimated)
~
Glaaa; ceramica; iron-free aluminum and aluminum aalta; manufacture of acti-
vated alumina; baae for organic lakea; flame retardant; rubber reinforcing
agent; paper coating filler; cosmetica; ion exchanger; chromatography;
filtering medium; absorbent; antiperspiranta; dentrifices; antacid;
deaiccant; soft abrasive
Precipitating ailver salta for photographic plates; medicine (for its bro-
mide ion); analytical chemiatry; proceaa engraving; textile finishing; fire
retardant for wood; corroaion inhibitors; catalyst in production of
diphenylSllline
Flameproofing of wood, paper, and textiles; coating vegetstion to retard
forest fires; to prevent afterglow in matches and smoking of candlewicks;
fertilizer (high analysis phosphste type); plant nutrient solutions; manu-
facture of yeast, vinegar and bread improvers; feed additive; flux for
soldering tin, copper, brass, and zinc; purifying sugar; in ammoniated
dentrifices; halo phosphate phosphors
Intermediate for boron chemicals; as a power-level control in atomic
aubmarinea
Flameproofing agent for textilea and certain grades of paper; weed and brush
killer; electroplating; generation of nitroua oxide
Preparation of antimonatea and other antimony compounds
Flameproofing of textilea, paper, and plaatics (chiefly polyvinyl chloride);
paint pigments; ceramic opacifier; catalyst; intermediate; staining iron and
copper; phosphors; mordant; glass decolorizer
Hsnufscture of gla~s, enamels, and other ceramic products; herbicide;
soldering metals; tanning; cleaning compound; artifical aging of wood;
preservstive; antiseptic; fireproofing fsbrics; detergent; astringent;
fertilizers; softening water; intermediate for perborates and other
boron derivatives
(Continued)
-------
Flame Retardant
INORGANICS (Continued)
Boric Acid
Diammonium phosphate [See
Ammonium Orthophosphate)
Disodium octaborate
Ferrocene
Magnesium sulfate heptahydrate
Ion
Ion
\0
Holybdates
.;
Holybdenum oxide
Holybdenum complex
Honoammonium phosphate
[AmmonIum phosphate, monobasic)
Hulti-metal complex
Red phosphorus
SodIum antimonate
Consumptiont
6.8 x 107 kga (75)
(total)
5.4 x 106 kgs (79)
TABLE B-9
(Continued)
Uae
Neat resiatant glasa; glass fibers; porcelaIn enamels; boron chemicals;
metsllurgy (welding flux, brazing copper); fireproofing composItions for
textile products such as cotton batting in~asttresses; fungus control on
citrus fruits; oIntment and eyewash; nickel electroplating baths; westher-
proofing wood; buffer; catalyst (hydrocarbon oxidation)
Additive to fuel oils to improve efficiency of combustion and eliminate
smoke; antiknock agent; catalyst; coating for missiles and satellites; high
temperature lubricant; Intermediate for high temperature polymers; ultra-
violet absorber
Fireproofing; textiles (warp sizing snd loading cotton goods, weighting
silk, dyeing and calIco printing); mineral waters; catalyst carrier;
ceramics; fertIlIzers; paper (sizing); cosmetic lotIons; dietary supplement;
medIcine (antidote)
Source of molybdenum compounds; agriculture; analytical chemistry; manufac-
ture of metallIc molybdenum; introduction of molybdenum In alloys; corrosion
inhibitor; ceramic glazes; enamels; pIgments; catalyst in petroleum
industry; medicine
Fertilizers; fla.eproofing agent for paper, wood, and fiberboard; to prevent
afterglow in matches; plant nutrient solutIons; manufacture of yeast, vine-
gar, yeaat foods and bread improvers; 'food additIve; analytical chem1atry
Safety matches, phoaphorua compounds
Opaclfier In enamels, for cast iron snd glsss; Ingredient of scid resisting
sheet steel enamels; high temperature oxIdIzing agent
(Continued)
"
-------
Flame Retardant
INORGANICS (Continued)
Zinc borate
[Zinc oxide + Boric oxide)
CHLORINATED COMPOUNDS
Chlorinated hydrocarbons
Chlorinated paraffins
Dechlorane Plus
'.
Dispersions (Chlorinated
Organics)
Methyl pentachlorostearate
VI
0\
o
Trichloroethylene
BROMlNATED COMPOUNDS
1,2-Bis(2,4,6-tribromophenoxy)-
ethane
Bis(2,4,6-tribromophenyl)-
carbonate
1,2-Bis(tetrabromophthalimido)-
ethane
Brominated organics
Decsbromobiphenyl
TABLE B-9
Consumptiont
5.0 x 107 kgs (75)
(total)
1.3 x 108 kgs (75)
(total)
(Continued)
Use
Medicine; ~ireproofing textiles; fungistat and mildew inhibitor; flux in
cerallics
Solvent for dichloramine-To extreme pressure lubricant additive (metal-
working industry); plasticizer; binder; fire retardant
High pressure lubricants; flame retsrdant in plastics and textiles; plasti-
cizer for polyvinyl chloride in polyethylene sealants; in detergents
Metal degreasing; extraction solvent for oils, fats, waxes; solvent dyeing;
dry cleaning; refrigerant and heat exchange liquid; fumigant; cleaning and
drying electronic parts; diluent in paints and sdhesives; textile process-
ing; chemicsl intermediate for pharmaceuticals and organic chemicals; aero-
space operations (flushing liquid oxygen); solvent for sulfur and phosphorus
(Continued)
-------
-J
1
\
Flame Retardant
.,
j
!
,
BROHlNATED COMPOUNDS
(Continued)
Decabromndiphenyl oxide
(Decabromodiphenyl ether)
I-(l,2-Dibromoethyl)-
3.4-dibromocyclohexane
Hexabromobenzene
Hexabroaocyclodecane
Octabromodiphenyl oxide
Pentabroaodiphenyl oxide
Pentabromoethylbenzene
\J1
'"
......
Penta bromo toluene
Tetrabromoxylene
HIXED HALOGEN COMPOUNDS
Brominated organica
Pentabromochlorocyclohexane
HI XED HALOGEN/PHOSPHORUS
COMPOUNDS
Chlorinated mixed phoaphate
Chlorinated organic phoaphonate
Bia(2-chloroethyl)2-chloroethyl
phoaphonate
Ethylene bla(tria(2-cyanoethyl)
phosphonlum)bromide
TABLE B-9
(Continued)
ConaUllptiont
>4.5 x 102 k8a (75)
(total )
Uae
Flame retardant for plaatlca and textilea
Flame retardant for plastlca
Flame Retardant
(Continued)
-------
j
;
1
j
-j
1
i
Flame Retardant
MIXED HALOGEN/PHOSPHORUS
COMPOUNDS (COntinued)
Chlorinated polyphosphate
Halogenated organic dlphoaphate
(chloroneopentyl type)
Halogenated phosphorus compound
Halogenated organic polyphoa-
phonate (Chloroethyl phoa-
phonate (polymeric»)
Phosphonated chloroepoxy
Phosphonium bromides
[blsphosphonlum compounds)
V1
0-
tV
3. 9-Trlbromoneopentoxy-Z. 4. 8.-
10-tetra- oxa-3.9-dlphospha-
splro(5.5)-undecane-3.9-dloxlde
Trls(Z-chloroethyl)phosphate
Trls(l-chloro-Z-propyl)-
phosphate
Trls(I.3-dlchloro-Z-propyl)-
phosphate
PHOSPHORUS COMPOUNDS
Bls(5. 5-dlmethyl-Z-thlono-l. 3.-
Z-dloxaphosphorlnanyl)oxlde
t-Butyl phenyl diphenyl
phosphate
Cresyl dlphenyl phosphate
TABLE B-9
Consumption t
>9.1 x 10Z kgs (75)
(total)
Z.7 x 106 kgs (75)
(total)
,'.
(Continued)
Uae
..
Flame retardant plasticizer
r . : ~ ,
Flame retardant and aecondary plasticizer
Plaatlclzer. extreme pressure lubricant. hydraulic fluids; gasoline addi-
tive; food packaging
(Continued)
-------
Flame Retardant
PHOSPHORUS COMPOUNDS
(Continued)
Diamyl amyl phosphooate
Dimethyl methylphosphooate
2-Bthylhexyl diphenyl phosphate
[Octyl diphenyl phosphate)
Isopropyl tri(dioctyl
phosphate) titanate
Iaopropyl tri(dioctyl
pyrophosphate)titaoate
Isodecyl diphenyl phosphate
U1
0\
U)
Isopropylphenyl diphenyl
phosphate
Phenyl phosphonates
Phenyl phosphonate from
sulfonyl-bisphenol
Phosphine oxides
Octyl diphenyl phosphate
Phosphonate eaters
(Cyclic phosphonste)
Red phosphorus trested with
caprolactsll
Tributoxyethyl phosphate
TABLE B-9
Consullptiont
>4.5 x 102 kgs (75)
(total )
>4.5 x 102 kgs (75)
(total)
>4.5 x 102 kgs (75)
(total)
1.1 x 106 kgs (79)
(total)
(Continued)
Use
Hesvy aetal extraction; solvent separation; preignition additive for gaao-
line; antifo811 agent; plasticizer and stabilizer; textile conditioner; anti-
static agent; low temperature hydraulic fluida
Plasticizer for vinyl filma; fireproofing plastics
Plasticizer and flame retardant; hydraulic fluid for aircraft
Primary plasticizer for most resins and elastollers; floor finishea and
waxes; flame retarding agent; anti foaming agent
(Continued)
-------
-,
Flame Retardant
PHOSPHORUS COMPOUNDS
(Continued)
Tributyl phosphate
Tricresyl phosphate
Tricresyl phosphate dispersions
Triethyl phosphate
VI
0\
~
Triisopropyl phenyl phosphate
- ,
Trioctyl phosphate
Triphenyl phosphate
Triphenyl phosphine oxide
Trixylenyl phosphate
[tri(dimethylphenyl) phosphate)
REACTIVE ORGANICS
Alkoxide adducts of TBPA
Allyl ether of pentabromophenol
Allyl ether of TBBPA
Bis(dibromopropyl ether) of
TBBPA
TABLE B-9
Consumption t
2.3 x 106 kgs (79)
(total)
4.1 x 106 kgs (79)
( total)
>9.1 x 102 kgs (75)
(total )
(Continued)
,.,
~
Use
~.
i:
Heat exchange medium; solvent extraction of .etal ions from solution of
reactor products; solvent for nitrocellulose, cellulose acetate; plasti-
cizer; pigment grinding assistant; antifoam agent; dielectric; aircraft
hydraulic fluid
Plasticizer for polyvinyl chloride, polystyrene, nitrocellulose; fire
retardant for plastics; air filter medium; solvent mixtures; waterproofing
additive to extreme pressure lubricants; hydraulic fluid and heat exchange
medium
Solvent; plasticizer for resins, plastics, and gums; manufacture of
pesticides; catalyst; lacquer remover; ethylsting agent; flame retardant;
intermediate for tetraethyl pyrophosphate
Solvent; anti foaming agent, plasticizer
Fire retarding agent; plasticizer for cellulose acetate snd nitrocellulose,
stabilizer for cellulose derivatives; impregnating roofing paper, lacquers
and varnishes
Plasticher
(Continued)
-------
,
,
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.1
Flame Retardant
REACTIVE ORGANICS (Continued)
~ j
Bia(2-chloroethyl) vinyl
phosphonate
Bia(methyl ether) of TBBPA
-,
. ;
. ~ .
!
Bromine-phosphorus polyol
3-Bromo-2,2-bia(bromomethyl)
propanol
Bis(chlorendo)cyclooctadiene
Bis(chlorendo)furan
VI
0\
VI
Chlorendic acid (hexachloro-
endomethylene-tetrahydro-
phthalic acid), (HET Acid)
Chlorendic anhydride(hexa-
chloroendomethylene-tetra-
hydrophthalic anhydride) (HET
Anhydride)
. j
Chlorine-containing polyol
Diacrylate of ethylene oxide
adduct of TBBPA
trans-2.3-Dibromo-2-butene-
l,4-<1iol
Dibromoneopentyl glycol
Dibromophenol
Dibromopropanol
Dibromopropyl acrylate
, ,
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. !
!
TABLE B-9
Consumption t
>4.5 x 102 kgs (75)
(total)
>4.5 x 102 kgs (75)
(total)
>2.3 x 103 kgs (79)
(total)
>9.1 x 102 kgs (75)
(total)
,
(
(Continued)
.!!!!
Fire retardant monomer; extreme preaaure lubricant; intermediate for dibutyl
and dimethyl chlorendate
Flame resistant polyeater reains; hardening epoxy res~ns; chemical inter-
mediate; source of chlorendic acid
Flame retardant for epoxy, polyester, and polyurethane foama; intermediate
for flame retardanta and pentaerythritol ethers
Intermediate in preparation of flame retardants, inaecticides and
pharmaceuticals
(Continued)
-------
.
I
!
'J
Flame Retardant
REACTIVE ORGANICS
(Continued)
.
'1
j
O,O-Diethyl-l,N,N-bis-
(2-hydroxyethyl) aminomethyl
phosphonate
:1
Di(polyoxyethylene) hydromethyl
phosphonate
,
-,
'1
I
"
~
:1
!
i
Ethylene oxide adduct of TBBPA
Epibromohydrin
Hexabromobutene
Hexachlorocyclopentadiene
VI
0\
0\
Oligomeric phosphate esters
Oligomeric phosphite
Pentabromophenol
Phosphorus-c~ntaining polyols
(diol from propylene oxide and
dibutyl acid pyrophosphate(,
(high functionality polyol(
Tetrabromobisphenol A (TBBPA(
Tetrabromophthalic anhydride
(TBPA(
. ,.
",I
Tetrabromovinyl cyclohexene
Tetrachlorophthalic anhydride
(C6CI4(C0}z0 (
"'j
TABLE B-9 (Continued)
ConsumpUont
>4.5 x 102 kgs (11)
(total)
. >4.5 x 102 kgs (15)
(total)
Use
Intermediate in pesticides aod fungicides; manufacture of chlorendic acid;
fire retardant; intermediate for dyes, resins, and pharmaceuticals
;.
Flame retardant for plastics, paper and textiles
Intermediate in dyes, pharmaceuticals, plasticizers and other organic
materials; flame retardant in plsstics and surface coatings
(Continued)
-------
TABLE B-9
(Continued)
!
Flame Retardant
Consumptiont
Use
REACTIVE ORGANICS
(Continued)
Tetrakis(hydroxymethyl)-
phosphonium sulfate
Tribromoneopentyl slcohol
Tribromophenol (Bromol),
(C&fI2Br)OH)
Tris(dipropylene glycol)
phosphate
Vinyl bromide (CH2CHBr)
>9.1 x 102 kgs (15)
(total)
Flame retarding agent for acrylic fibers
\J1
CJ'\
-...J
tAnnnal Consumption is presented parenthetically for the IDOst recent yesr avsilsble.
'. .
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I
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TABLE B-10.
FREE RADICAL INITIATORS AND RELATED COMPOUNDS
CONSUMPTION AND OTHER USES
Chemical
-
ORGANIC INITIATORS
ALKYL PEROXIDES
i
;
1
!
0,0, Bis(t-butylperoxy)
diisopropylbenzene
Bis(p-methoxybenzoyl peroxide)
t-Butyl cumyl peroxide
Di-t-butyl peroxide
Dicumyl peroxide (Bis(o ,0-
dimethylbenzyl)peroxide)
"j
. ~
lJ1
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00
2,5-Dimethyl-2,5-bis(t-butyl-
peroxy)hexsne
.,
2,5-Dimethyl-2,5-bis(t-butyl-'
peroxy)hexene-3
Hydroxyheptyl peroxide
Octyl peroxide (caprylyl
peroxide)
DIACETYL PEROXIDES
Acetyl Peroxide
Acetyl benzoyl peroxide
Benzoyl peroxide (various
forms)
Consumptiont
8.0 x 106 1
-------
..
..!
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Chemical
-
DlACETYL PEROXIDES (Continued)
Bis(4-t-butyl benzoyl peroxide)
Bis(o-bromobenzoyl peroxide)
Bis(m-bromobenzoyl peroxide)
Bis(p-bromobenzoyl peroxide)
Bix(p-methozy benzoyl peroxide)
Di-p-chlorobenzoyl peroxide
Decanoyl peroxide
Dichlorobenzoyl peroxide (0 and
p)
..
VI
0\
\0
Di-2,4-dichlorobenzoyl peroxide
(in various mixtures)
Diisononanoyl peroxide
~
Lauroyl peroxide [DIdodecanoyl
Peroxide)
..j
Pelargonyl peroxIde
Propionyl peroxide
DIBASIC ACID PEROXIDES
. !
,
SuccInic Acid Peroxide
HYDROPEROXIDES
Acetyl acetone peroxide 12,4-
pentanedione peroxIde)
t-Amyl hydroperoxide
TABLE B-10
(Continued)
ConsUlDptiont
2.4 x IDS kgs (82)
1.3 x 107 kgs (82)
Use
Polymerization cstalyst
Bleach for flour, vegetable oils, fsts
and waxes; polymerization agent for plas-
tics; curing sgent for rubber; burn-out
agent for acetate yaros; cosmetics and
pharmaceuticals; catalyst for optical and
dental castings
PolymerIzation initiator
Polymerization catalyst; deodorants;
antiseptics
(Continued)
-------
,/
.:j
I
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..
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Chemical
-
HYDROPKROXIDKS (Continued)
t-Butyl hydro peroxide
t-Butyl hydroxyethyl peroxide
Cumene hydroperoxide [a,a-di-
methylbenzylhydroperoxide)
Cyclohexanone peroxide
. .
Diisopropylbenzene
hydraperodde
VI
.....
o
2,5-Dimethylhexane-2,5-dihydro-
peroxide
p-Henthane hydroperoxide
Methyl ethyl ketone peroxide
..
1,I,3,3-Tetrsmethylbutyl-2-
hydroperoxide
PKROXYCARIIONATKS
. .
Bis(4-t-butylcyclohexyl)peroxy-
dicsrbonate
oo-t-Butyl-o-isopropyl mono-
peroxycarbonate
oo-t-Butyl-o-2(ethylhexyl)mono-
peroxycarbonate
Di(sec-butyl)peroxydicarbonate
Di(2-ethylhexyl)peroxydlcar-
bonate
TABLE B-10 (Continued)
ConsumpUont
2.7 x 105 kgs (79)
(Sales)
>4.5 x 102 kgs (75)
>4.5 x 102 kga (75)
(total)
7.2 x 106 kgs (82)
Use
Intermediate for production of propylene
oxide and t-butyl alcohol; polymeriza~
tion, oxidation and sulfonation catalyat;
bleaching; deodorizing; curing agent for
thermosets
Production of acetone and phenol; polym-
erization catalyst, particulsrly in redox
aystems
Polymerization initiator (100%)
Free radical initiator
Polyester premix initiator, also for
silicone resins
Initiator for rubber and polymerizations;
coatings
Manufacture of acrylic resins; hardening
agent for fiberglass reinforced plaatics
'.
(Continued)
-------
,
"
"
i
j
Chemical
PEROXYCARBONATES (Continued)
Diiaopropyl peroxydicarbonate
, ,
Di(2-phenoxyethyl)peroxydi-
carbonate
Di(n-propyl)peroxydicarbonate
PEROXYESTERS
t-Amyl perbenzoate
, -
t-Amyl perneodecanoate
t-Amyl peroxy(2-ethylhexanoate)
. j
t-Amyl peroxypivalate
VI
--.J
~
n-Butyl-4,4-di(t-butylperoxy)
valerate
t-Butyl peroxyacetate
t-Butyl peroxybenzoate
t-Butyl peroxycrotonate
t-Butyl peroxycyclohexane
t-Butyl peroxy(2-ethylhexa-
noate)
t-Butyl peroxyisobutyrate
t-Butyl peroxyisopropyl
carbonate
t-Butyl peroxymaleic acid
t-Butyl peroxy-2-methyl
benzoate
t-Butyl peroxyneodecanoate
"
"
TABLE B-10
(Continued)
Consumptiont
>4.5 x 102 kgs (75)
(total)
7.4 x 106 kgs (82)
(total)
1.6 x 106 kgs (79)
(total)
Use
Polymerization initiator (100%)
Polymerization initiator
Initiator; chemical intermediate
Polymerization catalyst
Polymerization catalyst
Initiator, crosslinking agent
Polymerization catalyat; bleaching;
pharmaceuticals
(Continued)
-------
"
j
. t.
Chemical
PEROXYESTERS (Continued)
t-Butyl peroxyperphthalic acid
t-Butyl peroxypivalate
Butyl peroxy-o-toluate
Cumyl peoxyneodecanoate
':
Cumyl perpivalate
Di(t-amylperoxy)cyclohexane
Di-t-butylperoxyazelate
l,l-Di-t-butylperoxycyclohexane
V1
......
N
l,l-Di(t-butylperoxy)-3,3,5-
trimethylcyclohexane
Di-t-butyl diperoxyphthalate
2,5-Dimethyl-2,5-bis(benzoyl-
preoxy)hexsne
2 ,5-Dimethyl-2,5-bis(2-ethyl-
hexsnoylperoxy)hexane
2,5-Dimethyl-2,5-di(t-butyl-
peroxy)hexsne
2,5-Dimethylhexyl-2,5-diperoxy-
2-ethylhexoate
Mixed peresters
2,4,4-Trimethylpentyl-2-peroxy-
cyclohexane csrboxylate
SULFONYL ACETYL PEROXIDES
"
Acetyl cyclohexyl sulfonyl
peroxide
TABLE B-10 (Continued)
ConsumpUont
9.1 x 105 kgs (79)
(total)
!!.!!
Polymerization catalyst; oxidizing sgent
"
Polymerization initiator
Polymerization catalyst
Oxidizing agent, polymerization agent
Polymerization initiator
(Continued)
-------
J
." ~
1
j
-,
,
J
Chemical
TERTIARY ALKYL PBRKETALS
2.2-Bis(t-butylperoxy) butane
"
l.l-Bis(t-butylperoxy)
cyclohexane
1.1-Bis(t-butylperoxy)3.3,5-
trimethylcyclohexane
n-Butyl-4.4-bis(t-butylperoxy)
valerate
Cyclic peroxyketsls
l.l-Di(t-butylperoxy)
cyclohexane
r
Bthyl-3.3-bis(t-butylperoxy)
butyrate
AZO COKPOUNDS
lJ1
-...J
v.J
2.2'-Azobis(2,4-dimethyl-4-
methoxyvaleronitrile)
2.2'-Azobis(2,4-dimethyl-
valeronitrile)
2,2'-Azobis-2-methylbutyro-
nitrile
2,2'-azobis(methylisobutyrate)
2,2'-Azobis(lsobutyronltrl1e)
Azo-cyclohexane carbonltrlle
2-t-Butylazo-2-cyanobutane
I-t-Butylazo-l-cyanocyclohexane
2-t-Butylazo-l-cyanocyclohexane
2-t-Butylazo-2-cyano-4-methoxy-
4-methylpentane
TABLE B-10 (Continued)
Consumptiont
!!!!
Catalyst for plastics; blowing sgent for
plastics
(Continued)
-------
;
.;.
oj
J
I
1
j
.1
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j
Chemical
AZO COMPOUNDS (Continued)
2-t-Butylazo-2-cyano-4-methyl-
pentane
,j
, 1
I
i
2-S-Butylazo-2-cyanopropane
2-t-Butylazo-2-methoxy-4-
methylpentane
a,a-Diphenyl-6-picrylhydrazine
INORGANIC INITIATORS
Ammonium Persulfate
VI
-..J
.j:>.
Ferrous Ammonium Sulfate Hexa-
hydrate
Hydrogen Peroxide
Oxygen
TABLE B-10
Consumptiant
6.8 x 104 kgs (72)
(total)
1.3 x 1010 kgs (82)
(total)
(Continued)
Use
Oxidizing 'agent; bleaching agent; photo-
graphy; etchant for circuit boards; etch-
ing capper; electroplating; manufacture
of other persulfates; deodorizing and
bleaching oils, aniline dyes; preserving
foods; depolarizer in batteries; washing
infected yeast '
Medicine; analytical chemistry;
metallurgy
Bleaching and deodorizing; source of
organic and inorganic peroxides; pulp snd
psper industry; plasticizers; rocket
fuel; foam rubber; manufacture of glyce-
rol; antichlor; dyeing; electroplating;
antiseptic; laboratory reagent; epoxi-
dation; hydroxylation; oxidation and
reduction; viscosity control; refining
and cleaning of metals; bleaching and
oxidizing agent for foods; neutralizing
agent for wine distillation; seed disin-
fectant; substitute for chlorine in water
and sewage treatment; renovating paint-
ings and engravings; cleaning metal sur-
faces; production of pesticides
Chemical intermediate; liquid fuels; to
relieve hypoxia; copper smelting and
steel production; synthesis gas for
ammonia, methyl alcohol, acetylene, etc.
(Continued) ,
-------
Chemical
INORGANIC INITIATORS
(Continued)
Potaaaium Blaulfate
Potaaaium Peraulfate
Sodium Hetablaulflte
Sodium Peraulfate
VI
-...I
VI
PROHOTORS IACT IVATORS
Alkaline Nitroprusside
Chromate-Arsenious Oxide Mixes
Cobalt Naphthenate
Cobalt Octoate
6% Cobalt Octoate + 14% Potas-
sium Octoate +'Trlphenyl
Phosphite
Dlethyl Anlline
, ,
N,N-Dlmethylanlllne
. ,
N,N-Dlmethyl-p-toluldlne
Ferrous Pyrophosphate
;.
TABLE B-10
(Continued)
Consumptiont
1.2 x ID6 kgs (79)
(total )
4.5 x 106 kgs (75)
(total)
Use
Production of potassium bitartrate; flux;
fertilizers; anisole; methyl acetate;
ethylacetate; laboratory reagent
Bleaching; oxidizing agent for dyes;
reducing agent for photography; antisep-
tic; aoap manufacture; analytical
reagent; polymerization promoter; pharma-
ceuticals; modification of starch; flour
maturing agent; deslzlng of textiles
Preservative for fooda; laboratory
reagent; antioxidant for pharmaceutlcala;
deodorizing manure
Bleaching agent for fats, oils, fabrics,
and soaps; battery polarlzers; medicine
faint and varnish dryer; bonding rubber,
steel and other metals
faint dryer; whitener; catalyst
Organic synthesis of pharmaceuticals;
dyestuff in~ermediate
Dyes; lntermediatea; solvents; manufac-
ture of vanillin; stabilizer (acid accep-
tor); hardener for fiberglass resins;
reagent; activator for polyester
(Continued)
/
-------
.'
Chemical
PROHOTORS/ACTIVATOR (ConUnued)
Ferrous Sulfate
"
j
Ferroua Sulfide
Hydrazine
VI
'-I
G\
Hydroquinone
, i
Hydroxylamine
Lauryl Hercaptide
-,
2-Hercaptobenzothiazole +
. .1
Cupric Chlor ide
,...'
TABLE B-10
(Continued)
ConsumpUont
>4.5 x 102 kgs (75)
(total)
7.7 x 106 kgs (75)
(total)
>1.4 x 103 kga (75)
(total)
2.7 x 106 kgs (77)
(total)
Use
Iron oxide pigment; other iron salta;
ferrites; water and aewsge treatment;
cstalyst for ammonia; fertilizer; feed
additive; flour enrichment
Rocket propellant; agricultural chemi-
cals; drugs; polymerization catalyst;
blowing agent; 'short-stopping agent;
Spandex fibers; antioxidants; plating
metals on glass and plastic; fuel cells;
aolder fluxes; scavenger for gases (40%);
explosives; photographic developers; cor-
rosion inhibitora; oil well drilling in
soils; buoyancy agent; diving equipment;
text Ues
Photographic developer; dye intermediate;
medicine; antioxidant; inhibitor; stabi-
lizer in paints and varnishes; motor
fuels snd oils; antioxidant for fata and
oils; polymerization inhibitor; phosphate
determination; bleaching of skin
blemishes
Reducing agent; organic synthesis
Hanufacture of rubber and plastics;
pharmaceuticals; insecticides and fungi-
cides; nonionic detergent; polymerization
regulation; complexing agent; removal of
metals from wastes
Vulcanization accelerator for rubber;
tire treads; fungicide; corrosion inhi-
bitor for cutting oila and petroleum
products; extreme pressure additive in
greases.
(Continued)
-------
,
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Chemical
!
I
,
PROHOTORS/ACTIVATOR (Continued)
2,4-Pentanedione [Acetylace-
tone)
i
1
. I
,
!
!
Pyrogallol
Sodium Formaldehyde Sulfoxylate
:! j
Sodium Hydrosulfite (sodium
dlthionlte)
VI
......
......
Sodium Hyposulfite
.-' :
Sodium Sulfide
Sodium Thiosulfate
Sugar [dextrose), [glucose)
: ~
TABLE B-IO
(Continued)
Consumptiont
9.1 x 102 kgs (75)
(total)
>9.1 x 102 kgs (75)
(total)
Use
Solvent for cellulose acetate; intermedi-
ate; metal chelates; psint dryers; lubri-
cant additives; pesticide; colorant
intermediate; crossli~king agent'
Protective colloid for metallics; photo-
graphy; dyes; intermediates; synthetic
drugs; medicine; process engraving; labo-
ratory reagent; gss analysis; reducing
agent; antioxidant for lubricating oils
Stripping and discharge agent for tex-
tiles; bleaching agent for 80lasses snd
soap
Vat dying of fibers snd textiles; strip-
ping sgent for dyes; reagent; bleaching
sugar, soap. oil, minerals;'oxygen
scavenger for synthetic rubbers
Organic chemicals, dyes; intermediates;
rayon; leather depilstory; paper pulp;
solvent for gold; sulfiding oxidized lead
and copper ores preparatory to flotation;
sheep dips; photographic reagents;
engraving snd lithography; analytical
reagent
Photography; chrome tanning; removing
chlorine in bleaching and paper making;
extraction of silver from ores; dechlori-
nation of vater. mordant; reagent; medi-
cine; bleach; reducing agent in dying;
sequestrant in foods
Confectionery; infant foods; medicines;
brewing and wine making; intermediate;
carmel coloring; baking and canning
(Continued)
-------
i
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Chemical
-
PROHOTORS/ACTIVATOR (Continued)
Thioglycolic Acid
.
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Vanadyl Acetyl Acetone
Versene Iron
INHIBITORS
Benzaldehyde
VI
--.J
00
p-Benzoquinone
p-t-Butyl Catechol
Catechol
Chloroanll
Copper
TABLE B-10
ConsullpUont
>4.5 II 103 kgs (79)
(total)
4.3 II 106 kga (75)
(total)
>4.5 x 102 kgs (75)
( total)
>4.5 II 102 kgs (75)
(total)
2.2 II 109 kgs (75)
(total)
(Continued)
Use
Resgent for iron, 8OlybdenuII, silver snd
tin; manufscture of thioglycolates; per-
manent wsve solutions snd dipilstories;
vinyl stsbilizer; aanufscture of phsraa-
ceuticals; per1l3nent creases in textiles;
microorganism growth media; chelating
agent .
Chemical intermediate for dyes, flavor-
ings, perfumes, ar01l3tic alcohols; sol-
vent for oils, reains, cellulose ethers,
cellulose acetate and nitrate; flavoring
compounds; synthetic perfumes; aanufac-
ture of cinnallic acid, benzoic acid;
phar1l3ceuticals; photographic chemicals;
bee repellant in honey harvesting
Manufacture of dyes and hydroquinone;
fungicide; polymerization inhibitor for
polyesters; photographic chemical; tan-
ning hides; rubber accelerator; pH deter-
minations; making gelatin insoluble;
strengthening animal fibers; reagent
Inhibitors for styrene-butadiene and
other olefins
Antioxidant in rubber, chemicals, and
dyes; cosmetics and pharmaceuticals;
photographic developer
Brass and bronze production (43%); elec-
trical wiring (40%); plumbing and heat-
ing (6%); roofing and construction (4%);
machinery(l%); other (1%); electroplat-
ing; insecticide; catalyst; antifouling
paInts; coins
(Continued)
-------
,
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Chemical
INHIBITORS (Continued)
2,5 Dichlorobenzoquinone
2,6-Dichlorobenzoquinone
m-Dinitrobenzene
Diphenylamine
2,5-Diphenyl-p-benzoquinone
.. .
Ferric Salts
Furfurylidene malonitrile
Hydroquinone (see Promotorsl
Ac ti vators )
VI
......
-0
1,4-Naphthalenediol
Naphthoquinone
. .
Nitrites
p-Nit roto luene
Oxygen (02) (see Inorganic
Ini tia tors )
Phenylanthraquinone
N-Phenyl-B-naphthylamine
TABLE B-10
ConsUllptiont
Not produced in U.S.
>4.5 x 102 kgs (75)
(total)
7.3 x 105 kgs (75)
(total )
(Continued)
Use
POlymerization inhibitor
POlymerization regulator for rubber and
polyester resins; synthesis of dyes and
pharmaceuticals; fungicide, algicide
Explosives; intermediate for dyea and
other chemicals
Rubber antioxidsnt; lubricant; inhibitor;
electrical insulating enamela; vulcaniza-
tion acceleration; component of rocket
fuels; surgical plasters; tin electro-
plating baths; dyes; chemical intermedi-
ate; catalyst
-.
(Continued)
-------
;.i"
/
,
,.
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Chemical
INHIBITORS (Continued)
Picric Acid
j
:. ~
Primary and Secondary Amines
Pyr id ine
""
Pyrogsllol (see Promotors/
Act! vators I
lJ1
CO
o
Quinone
Sulfur
Trinitrotoluene
, "
TABLE B-10
(Continued)
Consumptiont
>4.5 x 102 kgs (15)
(total)
6.8 x 106 kgs (15)
(total)
Use
Explosives; leathers; electric batteries;
etching copper; manufacture of colored
glass; textile mordant; rocket fuel;
photographic emulsions; manufacture of
picramic acid and chloropicrin; dye;
intermediate for metal picrates
Solvent in drug manufacture; intermediate
for pharmaceuticals and piperdine; inter-
mediate for textile waterproofing com-
pounds; flavoring; denaturing alcohol;
antifreeze mixtures; fungicidea; rubber
manufacture
'"
Sulfuric acid manufacture; pulp and paper
manufacture; carbon disulfide; rubber
vulcanization; dyes and chemicals; phar-
maceuticals; explosives; insecticides;
rodent repellants; soil conditioning
fungicide; coating for controlled release
fertilizers; nucleating agent for photo-
graphic film; cement sealant; road paving
compositions; bleaching wood pulp, straw,
wool and sillr.
Explosives; intermediate for dyestuffs"
and photographic chemicals
tAnnual Consumption is presented parenthetically for the most recent year available.
-------
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Heat Stabilizer
KETAL COMPOUNDS
. ~
BARIUH
!
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Barium benzoate
(Ba(C7Hs02)2'2H20!
Barium bis(4-nonylphenoxide)
Barium caprate
I
.:
Barium caprylate
Barium carbonate [BaCO]!
.,
I
, r
VI
00 Barium 2-ethylhexanoate
I-'
Barium laurate (Ba(C12H2]02)2J
Barium myristate [Ba(C14H2702)2J
Barium naphthenate
Barium nonylphenate
Ba ri um oleste
Barium phenate
Barium phenodde
Barium ricinoleate
Barium silicate [BaSiO]!
Ba ri um stearate [Ba(CIBH]S02>2J
TABLE B-11. HEAT STABILIZERS
CONSUMPTION AND OTHER USES
Conaumptlont
2.7 x 107 kga (7S)
(total)
Use
! .
, .
I
Treatment of brines in chlorine-alkali cella to remove
sulfatea; rodenticide; barium salts; ceramic flux;
optical glass; csse-hardening baths; ferrites; in radia-
tion resistant glass for color television tubes; photo-
graphic paper coating; anslytical reagent; antiscumming
agent in brick and clay products
Waterproofing agent; lubricant in metal~working. plas-
tics. and rubber; wax compounding; preparation of
greases; heat and light stabilizer in pl~stics
(Continued)
-------
,
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Heat Stabilizer
CADMIUM
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Cadmium benzoate
(Cd(C7HS02)2'2HZOJ
Cadmium caprate
Cadmium caprylate
Cadmium 2-ethylhexanoate
Cadmium laurate
Cadmium lauryl .ercaptide
Cadmium myriatate
Cadmium naphthenate
V1
00
'N
Cadmium oleate
Cadmium phenate
Cadmium phosphite
Cadmium ricinoleate
(Cd(CH3(CH 2)SCHOHCH2CH:CH(CH 2)]C02) J
Cadmium stearate
~
Calcium benzoate
(Ca(C7HS02)2'3HZOJ
Calcium caprate
Calcium 2-ethylhexanoate
Calcium laurate
(Ca(CIZH2J02)z'IIZO J
Calcium naphthenate
TABLE B-11
Consumptlont
(Continued)
Uae
, .
Heat and light atabilizer for pye
Lubricant and stabilizer for plastics
Waterproofing compoaitions; adhesives; dryers; wood
fillers; grafting waxea; cements; varniahes; color lskes
(Continued)
-------
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Heat Stabilizer
CALCIUH (Continued)
Calcium oleate (Ca(CI8H3302)2)
Calcium phenoxide (Ca(OC6HS)2)
Calcium ricinoleate
(Ca(CH3(CH2)SCHOHCH2C8CH(C82)7C02)2)
Calcium atearate (Ca(CI8H3S02)2)
MAGNESIUH
Magneaium 2-ethylhexanoate
VI
00
W
Hagneaium laurate
(Mg(CI2H2302)2'2H20)
Magneaium phenoxide
Magneaium aalicylate
(Mg(C7HS03)2'4H20)
Magneaium atearate
(Mg(C18H3S02>2 )
MANGANESE
Manganeae carbonate (MaC03)
Manganeae oxide, hydrox~de (Mn304)
TABLE B-11
Conaumptiont
1.8 x 106 kgs (7S)
(total)
(Continued)
Uae
Greasea and lubricanta; atabilizer for PVC
Water repellent; flatting agent in painta; lubricant in
making tablets; emulsions; cements; wax crayons; stabi-
lizer in vinyl resins; anticaking agent in foods;
cosmetics'
Medicine
Dusting powder; lubricant
lets; dryer in paints and
medicines; stabilizer and
fying agent in cosmetics;
binder and emulsifier
in making pharmaceutical tab-
varnishes; flatting agent; in
lubricant in plastics; emulsi-
in food a 3S anticaking agent,
Manufacture of manganese salts; medicine; dryer for
varnishes
Medicine; textile printing; analytical chemistry; cata-
lyst in manufacture' of allyl alcohol; ceramics; paints;
colored gla8a; bleaching tallow; animal feeds; ferti-
lizers; food additives and dietary supplements
(Continued)
-------
J'
TABLE B-11
Heat Stabilizer
COD8umptiont
POTASSIUK
Potassium benzoate
(KC7HS02'3H20)
Potassium Iaurate (KOOCCIIH23)
Potassium naphthenate
Potassium oleate (C17H3jCOOK)
Potassium salicylate (KC7HS03)
Potassium stearate (KClsH3s02)
SODIUK
Sodium benzoate (C~SCOONa)
4,3 x 106 kgs (7S)
(total)
VI
00
~
Sodium borate (Na28407'l0820)
Sodium carbonate (Na2C03)
Sodium laurate
Sodium phosphate (Na3P04'lOH~)
Sodium phosphite (2NaH2P03'SH20)
Sodium salicylate (HOC~4COONa)
Sodium stearate [NaOOCC17H3S)
(Continued)
Uae
Emulaifying agent; baae for liquid aoapa and shampoos
Dryers; emulsifying agents
Textile soaps; emulsifying agent
Base for textile softeners
Food preservative; antiseptic; medicine; tobacco, phar-
maceutical preparations; intermediate for manufacture of
dyes; rust and mildev inhibitor
Heat resistant glass, porcelain enamel, starch and adhe-
siyea, detergenta; herbicidea, fertilizers, rust inhib-
itors, pharmaceuticala, leather; photography; bleaches,
paint, boron compounda, flux for smelting; antifreeze,
adheaiyea; insulation materials; laboratory reagent
Medicine, photography, cleaning and boiler compounds, pH
control of vater; food additive '
Medicine; sntidote in ~rcuric chlorrde poisoning
Medicine; production of sslicylic acid; preservative for
paste, mucilage, glue and hides
Waterproofing and gelling agent; toothpaste and cosmet-
ics; stabilizer in paints
(Continued)
-------
Heat Stabilizer
STRONTIUM
Strontium 2-ethylhexsnoate .
Strontium laurate
Strontium naphthenate
Strontium stearate
ZINC
Zinc benzoate [Zn(C7Hs02)2)
Zinc caprate
Zinc caprylate [Zn(CSHls02)2)
\J1
00
\J1
Zinc 2-ethylhexanoate [Zinc octoate),
[Zn(OOCCH(C2H5)C4Hg)2)
Zinc laurate [Zn(CI2H2JP2)2)
.i
Zinc naphthenate
Zinc octoste [see Zinc caprylate)
Zinc oleate [Zn(Cla"3202)2)
Zinc 'phenate
Zinc stearate [Zn(Cla"3s02)2)
TABLE B-11
ConsUl8pUont
(Con tinued)
Use
Grease and wax compounding
i
!
Fungicide
Catalyst
Paints; varnishes; rubber compounding (softener and
acUvator)
Dryer and wetting agent in paints, varnishes, and
resins; insecticide, fungicide, and mildew preventative;
wood preservative; waterproofing textiles; insulating
materials
Paint, resin and varnish dryer
Cosmetics, lacquers, plastics, powder metallurgy; lubri-
cant; mold-release agent; filler; antifoamer; heat and
light stabilizer; medicine (dermatitis); tablet manufac-
ture; dietary supplement
(Continued)
-------
Heat Stabilizer
OTHER KETAL STABILIZERS
Alumium stearate (AI(CIBH350Z)3)
Barium cadmium laurate
Barium cadmium stearate
Lithium stearate (LiCIBH350Z)
TIN
\J1
00
0\
Dibutyltin bia(n-butyl maleate)
(C4H9)zSn(OOCCH:CHCOOC4H9)Z)
Dibutyltin S,S-bis(isooctyl thioglyco-
late) (C4H9)ZSO(SCHZCOOCBHI7)2),
(Dibutyltin bia(isooctyl mercapto-
acetate»)
Dibutyltio bis(lauryl mercaptide)
(C4H~)ZSO(SCIZHZ5)Z)
Dibutyltio bis(o-octyl maleate)
(C4H9)zSn(OOCCH:CHCOOCBH17)Z)
Dibutyltin diacetate
(C4H9)zSn(CzH30Z)Z)
Dibutyltin dicaprylate (Dibutyltin
dioctoate)
Dibutyltin dilaurate
(C4H9)zSn(OOCCIIHZ3)Z),
(Dibutyl tin laurate)
TABLE B-11
Cooaumpuoot
>4.5 x 10Z kga (75)
(Continued)
Uae
Paint and varnish dryer; greaaes; waterproofing agent;
cement additive; lubricanta; cutting compounds; flatting
agent; cosmetics and pharmaceuticals; additive for
chewing gWD8
Cosmetics; plastics; waxea; greases; lubricant in powder
metallurgy; "corrosion inhibitor io petroleum; flatting
agent in varnishes and lacquera; high-temperature
lubricant
Stabilizer for chlorinated organics; catalyat in conden-
satton reactions
Catalyst for silicone curing; polyether foams
/
Stabilizer for vinyl reains, lacquers, elastomers; cata-
lyst for urethane and siliconea; anthelmintic (chicken
tapeworms)
(Continued)
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Reat Stabilizer
TIN (Continued)
Dlbutyltin laurate-maleate
Dlbutyltin maleate
ft( C4Rg) ZSnOOCCR: CIICOO~ J
n - I to 3
Dibutyltin 6-aercaptoproplonate
Dibutyltin octoate (see Dibutyltin
caprylate)
Dibutyltin succinate
Dibutyltin sulfide (C4Rg)ZSn:S)
Dimethyltin bis(isooctyl aercaptoacetate)
VI
CO
-...J
Dimethyltin bis(6-alkanonyl oxyethyl
mercsptide)
Dimethyltin bis(dibutyl dithiocarbamate)
Di-n-octyltin S,S-bis(isooctyl
thloglycolate) (Di-n-octyltln S,S-bis-
(isooctyl mercaptoacetate»)
Di-n-oetyltin bis(Z-ethylhexyl maleate)
Di-n-octyltin dilaurate
'.
Di-n-octyltin 6-mercaptopropionate
(Dl-n-octyltin thiodlproplonate)
Di-n-octyltin maleate
Di-n-octyltin maleate polymer
(Haleoxyldioxy)bis(dibutyl(lauroyloxy)
tin)
TABLE B-ll
Consumptiont
;.
(Continued)
Use
Stabilizer for polyYinyl chloride resins; condensation
catalyst
Vinyl stabilizer; antioxidant; lubricating additiye
Heat stabilizer for PVC food packaging
(Continued)
-------
/
Heat Stabilizer
;
.,
!!! (Continued)
Thiabis(monobutyltin sulfide)
(S(Sn(S)C4H9)z1
ThiabiaJDOnometbyltin bia(a-all
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.,
!
Beat Stabilizer
J
LEAD (Continued)
Lesd chlorosilicate (Lectro 60)
Lesd chlorosilicate sulfate complex
[Lectro 80)
Lead-Z-ethylhexanoate
[Pb(C7H15COO)Z)
.;
Lesd naphthenate
. !
. . j
Lesd salicylate (Pb(00C(OB)C6H4)Z)
Lead silicate sulfste
VI
00
\0
Lesd stearate (see Normal Lead Stearate)
Lead sulfate (PbS04)
Litharge (PbO)
Monobasic lead sulfate (PbO"PbS04)
Normal lead orthosilicate (SiOZ
35-45%). (PbSi03)
Normal lead stesrate
(Pb(Cl7H35COO)Z)
Tetrabssic lead fumarate
[4PbO"Pb(OOC)ZCZHZ"ZHZO)
Tetrabasic lead sulfste
[4PbO"PbS04"HZO)
TABLE B-11
Consumptiont
1.8 x 105 kgs (75)
(total)
(Continued)
~
Vinyl electrical inaulation and tapes
Curing agent for silicone paints snd insulsting
vsrnishes
Paint snd vsrnish dryer; wood preservative; insecticide;
cstalyst for reaction between unssturated fatty acids
and sulfates in the presence of air; lube oil sdditive
Stabilizer and costsbilizer for flooring
Storsge batteries; paint pigments
Storsge batteries; cersmic cements and fluxes; pottery
snd glazes; glass; chromium pigments; oil refining;
varnishes. paints. enamels. ink, linoleum, insecticides;
cement; acid-resisting compositions; matchhead composi-
tions: other lead compounds; rubber accelerator
Paints; ceramics; pigments
Ceramics~ fireproofing fabrics
Vsrnish and lacquer dryer; high pressure lubricsnts;
lubricant in extrusion processes; stsbilizer for vinyl
polymers; corrosion inhibitor for petroleum; component
of greases, waxes and psints
Hest stsbilizer for plastisols, phonograph records, and
electrical insulation
(Continued)
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Heat Stabilizer
~ (Continued)
"
, ,
, ,
Tribasic lead maleate
[3PbO'Pb(OOC)2C2H2'1/2H20)
, .
Tribasic lead sulfate
[3PbO'PbS04'H20)
ANTIMONY HERCAPTlDES
Antimony thioglycolate
Antimony S,S',S"-tris(isooctyl mercapto-
acetate) [Sb(SCH2COOCSH17)3)
Antimony tris(lauryl mercaptide)
[Sb(SC12H2Shl
MISCELLANEOUS
V1
\0
o
2-Aminocrotonic acid
Benzoguanamine
[C6R5C3N3 (NH2 >2 )
Dicyandiamide [NH2C(NH)(NRCN»)
Dipentaerythritol
(CR20H)3CCR20CR2C(CR20H)31
Diphenylthiourea [Thiocarbanilidel,
[CS(NRC6H5>21
TABLE B-11
Consumptiont
3.4 x 104 tgs (75)
(total refinery
production)
(Continued)
!!!!
Highly basic atabilizer for vinyls
. Heat stabilizer for electrical and other vinyl compounds
Thermosetting resins, resin modifiers; chemical interme-
diate for pesticides, pharmaceuticals and dyestuffs
57% jewelry and arts; 27% industrial applications; 15%
dietary applications; 6% investment products; ferti-
lizers; nitrocellulose stabilizer; organic synthesis;
especially for melamine, barbituric acid and guanidine
salts; pharmaceutical products; dyestuffs; explosives;
retarding rancidity in fats and oils; fireproofing com-
pounds; case-hardening preparations; cleaning compounds;
soldering c~mpounds; accelerator; thinner for oil-well
drilling muds; stabilizer in detergent compositions;
modifier for starch products; catalyst for epoxy resins
, ,
Paints and coatings
Intermedistes; dyes; vulcanizstion accelerator; synthe-
tic organic phsrmaceuticals; flotstion agent; acid
inhibitor
(Continued) ,
-------
.. .....
-j
-1
1
TABLE B-11
Heat Stabilizer
Consumptiont
MISCELLANEOUS (Continued)
Glycerol
,
,
- '
Pentaerythritol IC(CHZOH)4J
a-PenyUndole
Sorbitol IC6HS(OH)6J
VI
\0
I-'
Thiolauric anhydride
Trimethyolethane ICH3C(CHzOH)3J
Trimethylolpropane
ICZH5C(CHZOH)3J
(Continued)
Use
Alkyd resins; explosives; ester gums; pharmaceuticals;
perfumery; plasticizer for regenerated cellulose; cos-
metics; foodstuffs; conditioning tobacco; liqueurs; sol-
vent; printer's ink rolls; polyurethane polyols; emulsi-
fying agent; rubber stamp and copying inks; binder for
cements and mixes; paper coatings and finishes; special
soaps; lubricant and softener; bacteriostat; penetrant;
hydraulic fluid; humectant
Alkyd resins; rosin and tall oil esters; special var-
nishes; pharmaceuticals; plasticizers; insecticides;
synthetic lubricants; explosives; paint swelling agents
,
!. ,"
Ascorbic acid fermentation; cosmetic creams and lotions,
toothpaste, tobacco, gelatin; bodying agent for paper,
textiles, and liquid pharmaceuticals; softener- for
candy; sugar crystallization inhibitor; surfactants;
urethane resins and rigid foama; plasticizer; stabilizer
for vinyl resins; varnishes and lacquers; food sdditive
Copditioning agent; manufacture of varnishes, alkyd and
polyester resins; synthetic drying oils
Conditioning agent; manufacture of varniahes, alkyd
resins; synthetic drying oils; urethane foams and coat-
ings; silicone lube oils; lactone plasticizers; textile
finishes; surfactants; epoxidation products
tAnnual Consumption is presented parenthetically for the most recent year available.
. i
:
-------
TABLE B-12. LUBRICANTS AND OTHER PROCESSING AIDS
CONSUMPTION AND OTHER USES
I
. !
I
Lubricant/Processing Aid
ConsWlptiont
!!.!!.
FATTY ACIDS AND ALCOHOLS
Behenic acid
Cosmetics; waKeS, plaaticizera; chemicsla; atabilizera
~. .
.
Oleic acid
Soap baae; aanufacture of oleates; ointment a; cosmetica;
poliahing compounds; lubricanta; ore flotation; intermediate;
surface coating; food-grade additives
..
Pal~tyl alcohol
Perfumery; emulaifier; emollient; foam ~tabilizer for deter-
gents; face creams, lotions, lipsticka, and toilet prepara-
tions; chemical intermediate; detergenta; pharmaceuticals;
cosmetics; base for making sulfonated fatty alcohola; to
retard evaporation of water when aprayed as a film on
reservoirs or sprayed on growing plants .
Stearic acid
4.3 x 107 kgs (75)
(total)
Chemicals, especially stearate a and stearate dryers; lubri-
cants; aoapa; pharmaceuticals and cosmetica; accelerator
-activator, dispersing agent, and softener in rubber com-
pounds; shoe and metal poliahes; food packaging; impregnating
plaster of paris; candles; release agent in baking goods and
confectionaries
\JI
-0
N
Stearyl alcohol
Perfumery; cosmetics; intermediate; surface active agent;
lubricants; resins
AHIDES
Behenamide
Erucamide
Foam stabilizer; solvent for waxes and resins; emulsions;
antiblocking agent for polyethylene
Ethylene bisstearamide
Ethylene hydroxystearamide
12-Hydroxy-N-(2-hydroxyethyl)
stearamide
Hethylene bisstearamide
(Continued)
. !
-------
Lubricant/Processing Aid
AHIDES (Continued)
Oleamide
Saturated fatty amide
Steara.ide
Stearoguanamine
ESTERS
Acetylated partial esters
l2-Acetyloxy-9-octodecenoic
acid, butyl ester
Alkoxylated fatty acid esters
VI
\0
(.oJ
Butyl stearate
. i
Cas tor 011
Cetyl palmitate
"1;
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,',
TABLE B-12
Consumptiont
(Continued)
Use
Slip agent for extrusion of polyethylene; waa additive; ink
additive
Corrosion inhibitor in oil wells
Ingredient of polishes; specisl lubricants, snd costings;
lubricant for aetals and in textile and molding industries;
in wax polishes as dye solvent; plasticizer for laminated
fiber products, rubber hydrochloride, chlorinated rubber, and
cable lacquers; carbon paper snd inks; emollient in cosmetic
and pharmaceutical products; lipsticks; damp-proofer for
concrete; flavoring
Plasticizer in lacquers and nitrocellulose; production of
dibasic acids; lipsticks; polyurethane coatings, elastomers
and adhesives; fatty acids; surface active agents; hydraulic
fluids; pharmaceuticals; industrial lubricant; electrical
insulating compounds; manufacture of Turkey Red' oil; source
of sebacic acid and ricinoleates; medicine
Base for ointments, cerates and emulsions; manufacture of
candles, soaps, etc.
"
, '
,
i:
(Continued)
-------
,.
. !
Lubricant/Proceasing Aid
ESTERS (Continued)
Diethylene glycol monostesrste
Diethylene glycol oleste
Diethylene glycol ricinoleate
Ethylene glycol distearate
Ethylene glycol monostearate
. '
Ethyl stearste
Glycerol monooleate
V1
'"
.p..
Glycerol monoricinoleate
Glycerol-mono-12-hydroxy-
stearate
Glycerol monostearate
Glycerol trioleate
Glycerol tris(12-hydroxy-
stearate)
"I. !
TABLE B-12
ConsWDpUont
(Continued)
!!!!
Emulsifier and thickener in cosmetics; mold release lubricant
for die casting; temporary binder for ceramics and grinding
wheels
Emulsifying agent' for fluid water-in-oU emulsions for the
manufacture of furniture and automobile polish; water-
emulsion paints; agricultural sprays
Plasticizer for high polymers and elastomers
Foods, pharmaceuticala, and coametics; rust-preventive oils;
textile finishing; vinyl light stabilizers; odorless base
paints; flavoring
Non-drying emulsifying agent; solvent; plasticizer; in
polishes, in cosmetics, in textile, paper, and leather
processing; low temperature lubricant; stabilizer for latex
paints
Thickening and emulsifying agent for margarine; shortenings
and other food products; flavoring; emulsifying agent for
oils, waxes and solventa; protective coating for hygroscopic
powders; cosmetics; opacifier; detacifier; resin lubricant
Used in making hydroxystearlc acid; lubricants; heavy metal
soaps; waxes; plasticizers; cosmetlca; chemical intermediate
(Continued)
-------
. ~
I
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j
Lubricant/Processing Aid
ESTERS (Continued)
Guanidine stearate
J
1
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!
" I
Hardened vegetable oila
Hydrogenated castor oil (see
Glycerol tris(12-bydroxy-
atearate) )
Hydrogenated vegetable oil
Kethyl l2-bydroxystearate
Hethyl atearate
Hontan eaters
J
VI
\0
VI
Octyl stearate
Pentaerythritol tetrastearate
Polyoxyethylene glycol mono-
stearate
Sorbitan trioleate
Stearyl stearate
':1
I
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J
Sulfonated castor oil (Turkey
Red 011)
Triglyceryl l2-bydroxystearate
Triglyceryl palmitate
i
".
Triglyceryl atearate
TABLE B-12
Conaumptiont
(Continued)
Uae
Adhesives; inka; cosmetics; greaaes
Intermediate for stearic acid detergenta, emulaifiers,
wetting agents, stabilizers, reaina, lubricants, plasticizers
and textiles; biochemical and medical research
Polishes; coatings; textile finiahes
Ointments; emulaifier; aurfactant; food additive
Emulaifiers and stabilizers in fooda, coametics, drugs,
textilea, plastics; agricultural chemicals
Textilea; leather; manufacture of soaps; alizarin dye asais-
tanto paper coatings
(Continued)
-------
j
1
Lubricant/Proceasing Aid
METALLIC SOAPS
Aluminum stearate
Barium stearate
j
"
Cadmium stearate
Calcium oleate
Calcium ricinoleate
Calcium stearate
VI
\0
0\
Lead oleate
Ij
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Lead stearate (Dibasic lesd
stearate)
."',
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Lithium atearate
. ,
Hagnesium oleate
Hagnesium stearate
TABLE B-12
Consumption t
(Continued)
Uae
Paint and varnish dryer; greases; waterproofing agent; cement
additive; lubricants; cutting compounds; flatting agent;
cosmetica aod pharmaceuticala; additive for chewing gum
Waterproofing agent; lubricant in metal working, plastics and
rubber; wax compounding; preparation of greases; heat and
light stabilizer in plastics
Lubricant and stabilizer in plastics
Greases and lubricants; stabilizer for polyvinyl chloride
Water repellent; flatting agent in paints; lubricant for
making tablets; emulsions; cements; wax crayons; stabilizers
for vinyl resins; anticaking agent in foods; cosmetica
Varnishes; lacquers; paint dryer; high pressure lubricants
Varnish and lacquer dryer; high-pressure lubricants; lubri-
cant in extrusion processes; stabilizer for vinyl polymers;
corrosion inhibitor for petroleum; component of greases,
wsxes and paints
Cosmetics; plastics; waxes; greases; lubricant in powder
metallurgy; corrosion inhibitor in petroleum; flatting agent
in varnishea and lacquers; ,high-temperature lubricant
Varniah dryers; in dry cleaning solventa (to prevent spon-
taneous ignition); emulaifying agent; lubricant for
plasticizers
Dusting powder; lubricant in making tablets; dryer in paints
and varniahes; flatting agent; in medicines; stabilizer and
lubricant for plastics; emulsifying agent in cosmetics; in
foods as anticaking agent, binder, emulsifier
(Con tinued )
-------
j
j
I
I
Lubricant/Processing Aid
METALLIC SOAPS (Continued)
Potassium stearate
Sodium dioctyl sulfosuccinate
[Dioctyl sodium sulfosuccinate)
Sodium stearate
. i
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. I
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Stannous octoate
Stannous ricinoleate
Stannous stearate
-',I
: .j
Zinc oleste
VI
\0
-...J
Zinc stearate
NATURAL WAXl!S
Carnauba wax
Castarvaa
Dammer wax
. !
TABLE B-12
Consumptiont
(Continued)
!!!.!
Base for textile softeners
Food additive (processing aid for sugar and stabilizer for
hydrophilic colloids); wetting agent; dispersant; emulsifier
Waterproofing and gelling agent; toothpaste and cosmetics;
stabilizer in plastics
Polymerization catalyst for urethans foams; lubricant;
addition agent; stsbilizer for transformer oils
Paints, resIns and varnishes .(dryer)
Cosmetics; lacquers; plastics; powder metallurgy; lubricant;
mold-release agent; filler; antifoamer; heat and light
stabilizer; .edicine (dermatitis); tablet manufacture;
dietary supplement .
Shoe polishea; leather finishes; varnishes; electric insulat-
ing compositions; furniture and floor polishes; carbon paper;
waterproofing; to prevent sun-checking of rubber and plastics
products; confectionery
Potting compounds, greases, sealants and impregnating compo-
sitions; wax blends where increase in grease and solvent
resistance, hardness and melting point is desired; blending
agent and viscosity reducer in hot melts; dire~t application
to paper for resistance to moisture and fat
Colorless and overprint varnishes; cellulosic lacquers; alkyd
baking enamels; paper and textile coatings
(Continued)
-------
Lubricant/Processing Aid
NATURAL WAXES (Continued)
Spermaceti wax
PETROLEUK-BASED WAXES
Candllilla wax
Ceresin vax
VI
\0
00
Microcrystalline wax
Paraffin wax
POLYMERIC LUBRICANTS
Carboxymethyl cellulose
TABLE B-12
Consumptiont
(Continued)
Use
Base for ointments, cerates and emulsions; I18nufacture of
candles, soaps, cosmetica, laundry vax; finishing and
lustering linena
Leather dressing; polishes; cements; varnishes; candles;
electric insulating compositions; sealing wax; waterproofing
and insect-proofing containers; paint removers; dentiatry;
rubber and rubber substitutes; paper sizes; stiffener for
soft waxes .
Candles; sizing; bottles for hydrofluoric acid; electrical
insulation; shoe and leather polishes; impregnating and
preserving agent; lubricating compounda; wood filler; floor
polishes; antifouling paints; waxed papers; cosmetics; oint-
ments; matrix compositions; waterproofing textile fabrics
~ :
Candles; paper coating; protective sealant for food products,
beverages, etc.; glass-cleaning preparations; hot-melt carpet
backing; biodegradable mulch; impregnating matches; lubri-
cants; crayons; surgery; stoppers for acid bottles; electri-
cal insulation; floor polishes; cosmetics; photography; anti-
frothing agent in sugar refining; packing tobacco products;
protecting rubber products from sun-cracking; chewing gum
base
Detergents, soaps, and food products as thickener, suspending
agent, and emulsion stabilizer; textile manufacturing; coat-
ing paper and paperboard to lower porosity; drilling muds;
emulston paints; protective colloid; pharmaceuticals;
cosmetics .
(Continued)
-------
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POLYHI!IUC LUBIUCANTS
(Continued)
Cellulose acetate lacquers
Nylon
Polyethylene wax
Polypropylene wax
~ .1
. .
.: '
Polytetrafluoroethylene wax
Polyvinyl acetate
V1
\0
\0
Polyvinyl alcohol
Silicone grease (see Silicone
OU)
SUicone 011
POLYHI!R FlLIIS AND SHEI!TS
Cellophsne
Cellulose acetste
TABLE B-12
ConsUlllption t
(Continued)
Use
Lacquers; protective coating solutions; photographic film;
acetste fiber; transparent sheeting; thermoplastic molding
composition; cigarette filters; magnetic tapes; osmotic cell
aae.brane
Hany different products, see IPPBU Chapters 10 and 10s
Hold release agent for rubber and plastics; paper and con-
tainer coatings; liquid polishes and textile finishing sgents
Hany different products, see IPPBU Chapters 10 and lOa
Hany different products, see IPPEU Chapters 10 and lOa
Adhesives; lubricants; protective'coatings; coolant; mold-
release agent; dielectric fluid; heat transfer; wetting agent
and aurfactant; foam stabilizer in polyurethanes; diffusion
pumps; anti foaming sgent for liquids; textile finishes; wster
repellent; weatherproofing concrete
Wrspper or protective pscking for fabricated articles and
industrial applications
Acetate fibers; lacquers; protective coating solutions;
photographic fil8; transparent sheeting; thermoplastic
801ding cnmpoaition; cigarette filters; magnetic tape;
osmotic cell membrane
(Continued)
-------
/
-/
j
I
.!
j
!
]
Lubricant/Processing Aid
POLYMER FILMS AND SHEETS
(Continued)
Cellulose acetate butyrate
Methyl cellulose
"
Nylon
Polyethylene
Polyethylene terephthalate
Polyester (Mylar)
Polytetrafluoroethylene
0\
o
o
Polyvinyl acetate
Polyvinyl alcohol
Polymethacrylate
Polydimethylsiloxaoe
Polytetrafluoroethylene
Polyvinyl chloride
Polyvinylidene chloride
Si Hcone rea10a
TABLE B-12
Consumptiont
(Continued)
Use
Protective colloid in water-based painta to prevent floccula-
tion of pigment; filii and sheeting; binder in ceramic glazes,
lesther tanning; dispersing, thickening and sizing agent;
adhesive, food additive
Many dif ferent products, see IPPEU Chapters 10 and lOa
Many different products, see IPPEU Chapters 10 and lOa
Many different products, see IPPEU Chspters 10 and lOa
Many dif ferent products, see IPPEU Chapters 10 and lOa
Many different products. see IPPEU Chapters 10 and lOa
Many dif ferent products. see IPPEU Chapters 10 and lOa
Many different prOducts, see IPPEU Chspters 10 and lOa
Many different products, see IPPEU Chapters 10 and lOa
Many different products, see IPPEU Chapters 10 and lOa
Many different products, see IPPEU Chapters 10 and lOa
Many dif ferent products, see IPPEU Chapters 10 and lOa
Coatings, 1I01diog co.pounds, laminates; filament winding,
sealants; room-temperature curing cements; electrical insula-
tion; impregnating electric coils; bonding agent, modlfier
for alkyd resins; vibration-damping devices
i .
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t.
i
, .
(Continued)
-------
.'
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Lubricant/Processing Aid
KISCI!LLAllEOUS
DibutyI phthalate
Lec it hin
..,
"
INORGANICS
Aluminum silicate (see Clay)
0-
o
......
Calcium carbonate
Calcium siUcate
Clay
Graphite
TABLE B-12
Consumptiont
1.5 x 108 kgs (81)
(Continued)
!!!.!
Plasticizer for nitrocellulose lacquers, elastomers, explo-
sives, nail 101ish and solid rocket. propellants; solvent for
perfume oils; perfume fixative; textile lubricating agent;
safety glass; insecticidea; printing inks; rea in solvent;
paper coatings; adhesivea
Emulsifying, dispersing, wetting, penetrating agent and
antioxidant; in margarine, mayonnaise, chocolate and candies,
baked gooda, animal feeds; printing inks; soaps snd
cosmetics; mold relesae agent for plsstics; blending agent in
oils and resins; rubber processing; lubricant for textile
fibers
Source of lime; neutralizing agent; fliler and extender in
rubber, plastics, snd paints; opacifying agent in paper;
fortification of bresd; putty; tooth powders; antacid; white-
wash; Portland cement; S02 removal from stack gases;
metallurgical flux; analytical chemistry; C02 generation
Adsorbent; antacid; adhesives; filler for paper and paper
coatings; cosmetics; food additive (anticaking agent)
Ceramic products; refractories; colloidal suspensions; oil-
well drilling fluids; filler for rubber and plastics
products; fil...; paper coatings; decolorizing oils; temporary
molds; filtration; carrier in insectlcidsl sprays; cstalyst
support; cosmetics; cements; 8~urce of alumina
Pencils; crucibles; retorts; foundry facings; molds;
lubricants; psints and castings; boiler compounds; powder
glazing; electrotyping; monochromator in X-ray diffraction
(Continued)
-------
,',' .:: ':'~."
I'
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TABLE B-12
Lubricant/Processing Aid
Consumptiont
1
INORGANICS (COntinued)
Hagnesium siliste
Hica
4.5 x 105 kgs (80)
Holybdenum disulfide
a-.
a
N
Potassium silicste
SiUca (fumed)
Talc
1.5 x 108 kga (82)
(ContInued)
~
Rubber filler; cer88ics; glass; refractories; absorbent for
crude oil spills; manufacture of permanently dry resins and
resinous compositions; paints; varnishes and paper (filler);
animal and vegetable oil bleaching agent; odor absorbent;
filter medium; catalyst and catalyst carrier; anticaking
agent in foods '
Electrical equipment; vacuum tubes; incandescent lamps; dust-
ing agent; lubricant; windows in high temperature equipment;
filler in exterior paints; cosmetics; glsss and ceramic flux;
roofing; rubber; mold release agent; specialty paper for
insulation and filtration; wallpaper and wallboard joint
cement; oil-well drilling muds
Lubricant in greases, oil dispersions, resin-bound film8, dry
powders, etc.; hydrogenation catalyst
Hanufacture of glass and refractory material; welding rods;
,potassium silicate solutions
Thickener; thioxtrophic and reinforcing agent in inks,
resins. rubber. paints. cosmetics. etc.
Ceramics; cosmetics and pharmaceuticals; filler in rubber,
paints, soap, putty, plaster, oilcloth; abherent; dusting
agent; lubricant; paper; slate pencils and crayons;
electrical insulstion
. :
tAnnual COnsumption is presented parenthetically for the most recent year available.
-------
-,
1
.1
I
I
!
I
!
Plasticizer
PHTHALATES
Alkyl benzyl phthalate
Bis(tetrahydrofufural)
phthalate
Butyl benzyl phthalate
Butyl benzyl tetrachloro
phthalate
Butyl cyclohexyl phthalate
Butyl decyl phthalate
C1'
'0
lJ,)
Butyl ethylhexyl phthalate
Butyl hexyl phthalate
Butyl isodecyl phthalate
Butyl octyl phthalate (see
Butyl ethylhexyl phthalate)
Cyclohexyl benzyl phthalate
Cresyl benzyl phthalate
n-Decyl n-octyl phthalate
Decyl tridecyl phthalate
Diallyl phthalate
TABLE B-13. PLASTICIZERS
CONSUMPTION AND OTHER USES
Production/Consumptiont
6.8 x 107 Itga (79)
>1.4 " 103 kgs (75)
( total)
>2.3 " 106 kga (79)
(total)
Uses
Plasticizer for PVC and cellulosics;
organic intermediate; carrier and dis-
persing media for catalysts, initiatora,
pesticides, cosmetics, and colorants
Plasticizer for polymera and elaatomers;
nitrocellulose lacquers
Primary plasticizer for PVC and copolymer
resins
PVC plasticizer
Vinyl plasticizer
Plast ic.izer
Low pressure laminates with fillers;
plasticizer; monomer for unsaturated
polyeater resina; peroxide diluent for
polyester spray; dye carrier; aealant;
impregnant
(Continued)
-------
Plaaticizer
PHTHALATES (Continued)
Di-n-amyl phthalate
Dibenzyl phthalate
Dibutoxyethyl phthalate
(Dibutyl Cellosolve phthalate)
Dibutyl phthslate
Dibutyl tetrachloro phthalste
0\
a
.p.
Dicapryl phthslate (Di-2-octyl
phthalate), (Bis(-l-methyl-
heptyl) phthalate)
Dicyclohexyl phthalate
Didecyl phthalate
Di(2,3-epozypropyl) phthalate
Diethoxyethoxy ethyl phthalate
(Dicarbitol phthalate)
Di(2-ethylbutyl) phthalate
Di(2-ethylhexyl) phthalate
(Dioctyl phthalate)
TABLE B-13
(Continued)
Production/Consuuptiont
7.7 x 106 kgs
(includes diisobutyl)
(79)
1.4 x 107 kgs (79)
Uses
Plasticizer
Plasticizer for PVC, polyvinyl acetate
and other resins
Plasticizer (35%) 88inly for plastisols,
nitrocellulose lacquers, elastomers,
explosives, nsil polish, and chlorinated
rubber; solvent for perfumes; textile
lubricsnt; safety glass; insecticides;
printing inks; resin solvent; paper coat-
ings and adhesives; manometer fluid
Plasticizer for vinyl and cellulose
resins
Plssticizer for nitrocellulose, ethyl
cellulose, chlorinated rubber, polyvinyl
acetate, polyvinyl chloride
Vinyl plasticizer especially for electric
cables and plastiaola
Plasticizer
ester (4%),
other vinyl
(1%); other
for PVC (86%), cellulose
synthetic elastomer (3%),
resins (3%), other polymer
uses (3%)
(Continued)
-------
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Plasticizer
PHTHALATES (Continued)
Diethyl phthalate
Di-n-heptyl phthalate
:,1
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Dihexyl phthalate
Dihydroabietyl phthalate
Diisobutyl phthalate
Diisodecyl phthalate
Diisoheptyl phthalate
Diisohexyl phthalate
Diisononyl phthalate
Diisooctyl phthalate
Dilauryl phthalate
Dimethoxyethyl phthalate
Dimethyl phthslate
Dimethyl isobutyl carbinyl
phthalate
Dinonyl phthalate
.i
"
TABLE B-13
(Continued)
Production/Conswaptiont
1.0 x 107 kgs (78)
>4.5 x 102 kgs (75)
(total)
See dibutyl phthalate
7.7 x 107 kgs (79)
8.2 x 107 kga (79)
1.6 x 107 kgs (79)
2.3 x 103 kgs (79)
(total)
5.0 x 106 kgs (79)
>4.5 x 102 kgs (75)
( total)
~
100% aa a plaaticizer,and aolvent for
cellulose estera: solid rocket propel-
lent: insecticide spray
Plasticizer: carrier and dispersing aid
Plasticizer for vinyls and cellulose
esters
Plasticizer
Plasticizer
Plasticizer for vinyls, cellulosics,
acrylics, and synthetic rubber
Plasticizer, especially for vinyl resins
and cellulose acetate: solvent
Plasticizer (70%), principally for
cellulose esters; insect repellent (30%);
solvent
Plasticizer for vinyls; stationary liquid
phase in chromatography; carrier and dis-
persing aid for catalysts, initiators,
pesticides, cosmetica, and colorants
I,i Ii
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(Continued)
i.
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Plasticizer
PHTHALATES (Continued)
Di-n-octyl phthalate
Di-n-octyl, n-decyl phthalate
Diphenyl phthalate
Dipropyl phthalate
Ditridecyl phthalate
Di(3,5,5-trimethylhexyl)
phthalate
i
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Diundecyl phthalate
'"
o
'"
Bthylhexyl decyl phthalate
2-Bthylhexyl isodecyl phthalate
Heptyl nonyl phthalate
n-Heptyl, n-nonyl, n-undecyl
phthalate
n-Hexyl, n-decyl phthalate
Hexyl octyl decyl phthslate
(20%/36%/44%)
(5%/56%/38%)
Iaodecyl benzyl phthalate
Isooctyl isodecyl phthalate
Methoxyethoxyethyl phthalate
Methoxyethoxyethyl benzyl
phthalate
TABLE B-13
(Continued)
I.
. ProductIon/ConsumptIont
>4.5 x 102 kgs (75)
(total)
1.2 x 107 k8s (79)
Demsnd estimated at
6.8 x 106 k8S (79)
7.3 x 106 k8S (78)
~
Plasticizer; perfume fixative; solvent
Vinyl plasticizer
Plsstlcizer for ethyl cellulose, nitro-
cellulose and other polymers
Plaaticizer, little used
Plasticizer
Plasticizer
Plasticizer
Plasticizer
(Continued)
-------
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PHTHALATES (COntInued)
"
Octyl benzyl phthalate
n-Qctyl. n-decyl phthalate
7-(2. 6. 6.8-Tetramethyl-4-oxa-
3-oxo-nonyl)benzyl phthalate
BlSPHTHALATES
Ethylene glycol bIa-(n-butyl)
phthalate
HEXAHYDROPHTHALATES
DI-2-Ethylhexylhexshydro-
phthalate
0\
o
.....
2-Ethylhexylhexahydro
isophthalate
ISOPHTHALATES
Diethyl Iaophthalate
DI-(2-ethylhexyl) Iaophthalate
(Dloctyl Iaophthalate)
DIIaooctyl Isophthalate
DImethyl Iaophthalate
Dlnonylphenyl Iaophthalate
TEREPHTHALATES
Dl-(2-ethylhexyl) terephthalate
(Dloctyl terephthalate)
ChlorInated dioctyl terephtha-
late
TABLE B-13
(Continued)
Productlon/Conaumptlont
VInyl plaaticizer
Plaaticher
Uaea
(Continued)
-------
TABLE B-13 (ContInued)
Plasticizer
Productioo/Coosumptioot
Uses
TETRAHYDROPHTHALATES
IChloreodatesl
2-f!thylhexyl epoxy
tetrahydrophthalate
PHTHALATE MIXTURES
AND UNSPECIFIED
Blend (SO/50) of dioctyl and
dioctyldecyl phthalates
Bleod (SO/50) of dioctyl and
didecyl phthalates
Kixed Alcohol phthalates
Mixed Alcohol phthalates
C\
o
CO
Mixed Normal Alcohol phthalates
Straight Chain Alcohol
phthalates
Straight Chain Alcohol
phthalates
Mixed alkyl phthalates
MIxed-a-alkyl phthalates
Alkyl aryl phthalate
Alkyl aryl modIfIed phthalate
Alkyl aryl modified phthalate
HIgh molecular weight phthalate
High molecular weIght linear
phthalate
HIgh solvating phthalate
ModIfied phthalate
(Continued)
-------
Plasticizer
PHTHALATE "IXTURES
AND UNSPECIFIED (ContInued)
Octyl fatty phthalate
HIgh molecular weIght phthalate
"polyester"
TRIHELLITATES
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Dllsooctyl monolsodecyl
trillellitate
Heptyl nonyl trll1ellltate
Heptyl nonyl undecyl trll1elll-
tste
Isooctyl Isodecyl trimeilitate
a-
o
\0
n-octyl, n-decyl trimeilitate
Trlcapryl trimeilitate
Tri-(2-ethylhexyl) trimeilitate
Trl-n-hexyl trimeilitate
Trllaodecyl trimeilitate
Trllsononyl trimeilitate
Trllsooctyl trimeilitate
Trl-n-octyl trll1ellltate
Tri-n-octyl n-decyl trll1elli-
tate
PYROHELLITATES
Tetra-n-butyl pyromeilitate
Tetraethyl pyromeilitate
Tetramethyl pyromellitate
TABLE B-13
(Continued)
Production/Conaumptiont
4.1 x 106 kgs (79)
5.4 x 106 kgs (79)
Plasticizer
Plasticizer
~
(Continued)
-------
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EPOXY TYPE PLASTICIZERS
Bisphenol A diglycidyl ethers
(8.0-9.4% oxirane)
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Di-2-ethylhexyl-4,5-epoxy
tetrahydro phthalate
().6-).9% oxirane)
Di-isodecyl tetrahydro-4,5-
epoxy tallate
Diisodecyl-4,5-epoxy tetra
hydrophthalate ().O% oxirane)
. !
0\
......
o
Epoxidized linseed oil (9.0-
10.0% oxlrane)
i
, ,
Epoxidized soybean oil (6.7-
7.0% oxlrsne)
2-Ethylhexyl epoxy tallate
(4.4-4.9% oxirane)
Epoxy tallate
Epoxy fatty nitrile
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Octyl epoxy stearate
().5-).9% oxirane)
Octyl epoxy tallate
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POLYESTERS AND OTHER POLYMERIC
PLASTICIZERS
Acrylic-type Polyester
Adipic Acid Polyesters
TABLE B-13
(Continued)
Production/Consuaptiont
).) x 107 kgs (79)
!!!!!.
Sealing and encapsulating; castings and
pottings; epoxy resins; binder for paper,
polyester, fiberglasa aod wood
Fungi resistant plasticizer and stabi-
lizer in vinyls for outdoor use
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(Continued)
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TABLE B-13 (Continued)
Plasticizer
ProductioD/CoDsumptiont
Uses
POLYESTEB.S AND OTHER POLYKI!IUC
PLASTICIZI!B.S (COntinued)
Adipic Acid POlyesters
Low Viscosi t Y
Medium Viscosity
Medium Moleculsr Weight
Medium High Moleculsr Weight
Alkyds
,',
Azelsic scid polyesters
Butsdienescrylonitrile polymer
0\
~
~
!!ssy processing polymeric
2-l!thyl-I,3-hexsDediol
polysdipste
NeopeDtyl glycol polysdipste
Polybutylene glycol
Polyester, scetylsted
Polyester, Dot scetylsted or
not "terminsted"
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Polypropylene glycol polyadi-
pate
Polystyrene resin, polyalpha
methyl
POlyurethane-based polymeric
power
(Continued)
-------
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POLYESTERS AND OTHER rOLYKERIC
PLASTICIZERS (Continued)
Reainoua plaaticizer, EVA
terpolymer
Sebacic acid polyester
Sebaclc acid polyester 011
mod If led
Sulfonamide-Formaldehyde
Reactive-type plasticizer
PHOSPHATES
Alkyl aryl phosphate
. a-
t-'
N
p-t-Butylphenyl diphenyl
phosphate
Chlorophenyl dlphenyl phosphate
Chlorinated diphosphate
Cresyl dlphenyl phosphate
DI-(2-ethylhexyl) phenyl
phosphate
Dlphenyl octyl phosphate
2-Ethylhexyl dlphenyl phosphate
Halogenated organic phosphate
TABLE B-13
(Continued)
Production/Consuaptiont
2.7 x 106 kgs (75)
(total)
>4.5 x 102 kgs (75)
( total)
6.4 x 106 kgs (79)
(Includes Isodecyl
dlphenyl phosphate)
!!!!!.
Plasticizer; extreme pressure lubricant;
hydraulic fluids; gasoline additive; food
packaging; flameproofing
Plasticizer; hydraulic fluid; flame
retardant
PVC plaatlcizer; fireproofing
Plasticizer and flame retardant for
polyurethane foams
ii.
,
(Continued)
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PHOSPHATES (Continued)
Isodecyl diphenyl phosphate
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Isooctyl diphenyl phosphste
Isopropylated phenyl phosphste
18opropyl phenyl diphenyl
phosphate
Phenyl isopropyl phenyl
pho8phate
o-Phenylphenyl diphenyl
phosphate
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Triaryl phosphate (aynthetic)
0\
~
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Tributoxyethyl phosphate
Tributyl phosphate
Tricresyl phosphate
Tricresyl diphenyl phosphate
Triethyl phosphate
Tri-(2-ethylhexyl) phosphate
;
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TABLE B-13
(Continued)
Production/Consumptiont
See 2-ethylhexyl
diphenyl phosphate
1.1 x 106 kgs (79)
2.3 x 106 kgs (79)
4.1 x 106 kgs (79)
1.1 x 106 kgs (79)
Uses
Primary plasticizer for most resins and
elastomers; floor finishes and waxes;
flame retarding agent; anti foaming agent
Heat exchange medium; aolvent extraction
of metal ions; 80lvent for nitrocellu-
lose, cellulose acetate; plasticizer;
pigment grinding assistant; antifoam
agent; dielectric; hydraulic fluid
Plasticizer for PVC, PS, nitrocellulose;
fire retardant for plastics; air filter
medium; solvent mixtures; wsterproofing.
additive to extreme pressure lubricants;
hydraulic fluid and heat exchange medium
Solvent; plasticizer for resins, plas-
tics, gums; manufacture of pesticides;
catalyst; lacquer remover; flame retar-
dant for polyesters
Plasticizer with flame retardant and
fungicide properties; antifoaming agent
;'.
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(Continued)
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PHOSPHATES (Continued)
Tri-n-hexyl phosphate
Triisopropyl phenol phosphate
Tri-2-methoxyethyl phosphate
Triphenyl phosphate
Tris(2-chloroethyl) phosphate
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Tris(chlorophenyl) phosphate
0\.
......
~
Tris-chloropropyl phosphate
Tris(2,3-dichloropropyl)
phosphate
Tris(tetrahydrofurfuryl)
phoaphate
Trixylenyl phosphate Itri(di-
methylphenyl) phosphite)
Unspecified ph9sphate
PHOSPHONATES
Chlorinated organic phosphonate
Chlorinated polyphosphonate
(27% CI, 15% P)
Di-(2-ethylhexyl n-octyl)
phosphonate
Halogenated organic polyphos-
phosphonate
TABLE B-13
(Continued)
Production/Consumptiont
3.0 x 106 kgs (79)
(estilll4te)
>9.1 x 102 kgs (75)
(total)
Uses
Fire retarding agent; plasticizer for
cellulose acetate and nitrocellulose,
lacquers and varnishes, hot melt
adhesives; chemical intermediate; metal
scavenger; atabilizer for alkyd reains;
antioxidant; roofing peper; substitute
for camphor in celluloid
Flame-retardant plasticizer; medication
Essentially 100% as a flame retardant;
secondary plasticizer
Flame retardant; aecondary plasticizer
Plasticizer; flame retardant
. .
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Plasticizer
PBOSPBITES
Triphenyl phosphite
Tris(2-chloroethyl) phosphite
LINEAR PLASTICIZERS
GLUTARATES
Dialkyl diether glutarate
Dibutoxyethyl gluts rate
0-
I-'
VI
Dibutoxyethoxyethyl gluts rate
Dicumylphenyl glutsrate
Didecyl glutarate
Diisodecyl glutarate
. .
Hixed dialkyl glutsrste
ADIPATES
Benzyl octyl sdipste
Butyl carbitol sdipste
Dialkoxyethyl adipate
Dibenzyl adipate
Dibutoxyethyl sdipate
Dibutoxyethoxyethyl adipste
Dibutyl adipste
TABLE B-13
Production/Consumptiont
4.5-9.1 x 105 kgs
(12 )
>9.1 x 102 kgs (15)
(total)
(Continued)
Uses
ChemicaJ intermediste; stabilizer for
resins; metal scsvenger; diluent for
epoxy resins; antioxidant for rubbers
Intermediate; component of vinyl stabi-
lizers; grease additive; flame proofing
compositions; color inhibitor in
esterifications
Primary plasticizer for most resins at
low temperatures, sdds UV stability
Little used
(Continued)
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ADIPATES (Continued)
Dicapryl adipate
Didecyl adipate
Di-(I,3-di-methylbutyl) sdipate
Diethyl adipate
Di-(2-ethylhexyl) adipate
0\
,"""
0\
Di-n-hexyl adipste
DUsobutyl sdipate
DUsodecyl adipate
Dii80nonyl adipate
D!isooctyl adipate
Diisopropyl adipate
Dimethyl adipate
Dinonyl adipste
Dipropyl adipate
Ditridecyl sdipate
Di-(2,2,4-Trimethyl-l,3-penta-
nediol monoisobutyrste) adipate
Reptyl nonyl adipate
o-Rexyl n-decyl adipate
TABLE B-13
(Continued)
Productioo/Coosumptioot
2.1 x 107 kgs (79)
5.9 x 105 kgs (79)
1.2 x 105 kgs (79)
5.9 x 105 kgs (79)
1.1 x 106 kgs (79)
!!!!!
Plasticizer for vioyls and cellulosics
Plaaticizer, especially for electric
cables
Plasticizer - coamooly blended with DOP
sod DIOP io vinyls and other polymers;
solvent; aircraft lubricant
Plasticizer for SBR (low temperature)
Plasticizer
Primary plasticizer for polymers
Low volatility plasticizer
Low temperature plastici~er
Plasticizer
Low temperature plasticizer
(Continued)
-------
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ADIPATES (Continued)
lsooctyl isodecyl adipate
n-octyl n-decyl adipate
Tridecyl adipate
MIXED ADIPATES
C7-C9 linesr adipatea
Straight chsin alcohol adipatea
Straight chain alcohol sdipates
POLYHRRIC ADIPATES
Di-(2-ethylhexyl) adipate
(polymeric)
High molecular weight adipate
Modified polypropylene sdipate
Polypropylene sdipate
!
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ClTRATES
Acetyl tri-n-butyl citrate
.1
Acetyl triethyl citrate
Acetyl tri-(2-ethylhexyl)
citrate
Acetyl tri-n-hexyl citrate
Acetyl tri-(n-octyl. n-decyl)
citrate
Tribenzyl citrate
,
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TABLE B-13
(Continued)
Production/Consumptiont
)2.0 z 103 kgs (76)
(total)
Uses
. ~
Low temperature plasticizer
.. ,
Plasticizer; flavoring ingredient
Plasticizer for cellulose
Low volatility plasticizer for vinyl
resins
(Continued)
-------
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CITBATES (Continued)
Tributyl citrate
Triethyl citrate
Tris(-2-ethylhexyl) citrste
AZELATES
Dibenzyl azelate
Dibutozyethyl azelate
Diethyl azelste
Di-(2-ethylbutyl) azelate
Di-(2-ethylhexyl) azelate
Di-n-hezyl azelate
Diisobutyl azelate
I
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Diisooctyl azelate
Dimethyl azelate
Low temperature azelate
plasticizer
SEBACATES
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Butyl scetoxy sebacate
Butyl benzyl sebacate
"
TABLE B-13
Production/Consumptiont
>4.5 z 102 kgs (75)
( total)
(Continued)
~
Plasticizer; anti foam agent; solvent for
nitrocellulose
Solvent and plasticizer for nitrocellu-
lose and natural resins; softener; paint
removers; agglutinant; perfume base; food
additive (not over 0.25%)
Low temperature plasticizer especially
for vinyls; base for synthetic lubricsnts
Vinyl resin plasticizer; base for
synthetic lubricants
t.
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(Continued)
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SEBACATES (Continued)
Dibenzyl sebacate
Dibutoxyethyl sebacate
Dibutoxyethoxyethyl sebacate
Dibutyl sebacate
Di(-l,3-dimethylbutyl) sebacate
Dihexyl sebacate
Diisooctyl aebacate
Diisopropyl aebacate
Dimethyl aebacate
Dinonyl sebacate
Dioctyl aebacate Idi-(2-
ethylhexyl) sebacateJ
Heptyl nonyl sebacate
ISOSEBACATES
Di-n-butyl iaosebacate
Di-(2-ethylhexyl) iaoaebacate
SUCClNATES
Diethyl succinate
Tetrabutyl thiosuccinate
I
.;
TABLE B-13
(Continued)
Productlon/Conaumptiont
(aee dioctyl
aebacate)
2.5 x 106 kga (75)
Usea
Plasticizer, especially for plaatic
linings for containers
Plasticizer; rubber softener; dielectric
liquid; cosmetics snd perfumes; sealing
food containers; flavoring; lubricating
ingredient in shaving lotions
Plaaticizer
Solvent and plasticizer for nitrocellu-
lose and vinyl resins; intermediate
Plasticizer
,t
Plasticizer; intermediate; flavoring
(Continued)
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Butyl carbitol formal
Dibutoxyethoxyethyl formal
PBLAROONATES
Isodecyl pelargonate
TARTRATES
Diisobutyl tartrate
.,
,
.,
: !
FIlllARATES
.,
,
,
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Dlbutyl fumarate
'"
N
o
Diisooctyl fumarate
Dioctyl fumarate
. i
ISOBUTYRATBS
. .
2,2,4-Trimethyl-I,3-pentsndiol
dUsobutyrate
Sucrose acetate isobutyrste
IlALBATBS
Di-n-butyl maleste .
Dioctyl maleate
Monobutyl maleste
TABLE B-13
(Continued)
Production/Consumptiont
Uses
Monomeric plasticizer; copolymers;
intermediate
Monomer for polymerization and copoly-
merization
Intermediate in manufacture of plssti-
cizers, surfactants, pesticides and
resins
Modifier for lacquers, hot-melt coating
formulstions and extrudable plastics
Copolymers; plasticizers; intermediate
Copolymers; intermediste
(Continued)
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PENTAERYTHRlTOL
Pentaerythritol fatty acid
ester
Pentaerythritol tetrscaprylate-
caprate
OTHER LINEAR ESTERS
Mixed dibaaic ester
Sucrose octoacetate
EXTENDERS
0-
tV
t-'
PETROLEUM DERIVATIVES
Alkyl aryl hydrocarbons
Aromatic hydrocarbons (70%
sromatic hydrocarbons, 23%
polar compounda)
Biphenyl
Butyl naphthalene
Diisopropyl biphenyl
Naphthalene
Naphthenic 011
.j
TABLE B-13
Production/Consuaptiont
1.0 x 108 kgs (75)
(total)
(Continued)
Uses
Plasticizer for cellulose and synthetic
resios; adhesives; coatings; insecti-
cides; termite repelleot; denaturant in
rubbing alcohol; paper; plastics;
lacquera
Insecticide; vermicide; antiseptic; manu-
facture of anthranilic acids; naphthols;
naphthyldmines and sulfonic acid; resins;
explosives; surface active agents :
i.
(Continued)
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PETROLEUM DERIVATIVES
(Continued)
PoIyslkyl nsphthslene
Terphenyls, partislly
hydrogenated
o,m,p-Terphenyl mixture
Poly-alpha-methyl styrene
CHLORINATED AROMATICS
Chlorobenzene
0\
N
N
o-Dichlorobenzene
Chlorinated biphenyl
21% Cl
32% Cl
42% Cl
48% Cl
54% Cl
60% Cl
68% Cl
TABLE B-13
Production/Consumptiont
1.5 x 108 kgs (75)
(total)
2.5 x 107 kgs (75)
(total)
(Continued)
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Uses
i.
Solvent for paints; dry cleaning solvent;
intermediate for phenol, 0- and p-chloro-
nitrobenzene, DDT, and anilinei insecti-
cide; manufacture of dyestuffs
Organic synthesis of pesticides (53%)i
solvent in toluene diisocyanate process
(15%)i dyestuff manufacture (8%); miscel-
laneous uses (4%) including removing sul-
fur from illuminating gss, heat transfer
medium, degreasing sgent, metal polishes,
rust proofing, wood preservation, magnetic
coil coolant, and deodorizing garbage and
sewage
(Continued)
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CHLORINATED AROMATICS
(Continued)
Chlorinated Naphthalene
22% Cl
50% Cl
56% Cl
10% Cl
Chlorinated Terphenyl
60% Cl
Chlorinated
40% Cl
42% Cl
52% Cl
10% Cl
Paraffin
~
N
W
PARAFFIN OILS
White paraffin oil, highly
refined
Petrolatum
OTHER CYCLIC PLASTICIZER
ABIETIC DERIVATIVES
Hydroabietyl alcohol
Hydrogenated methyl abietate
Methyl abietate (methyl ester
of rosin)
,
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TABLE B-13
Production/Consumptioot
)5.0 a 101 kgs (19)
(Total)
3.0 x 108 kga (15)
( total)
.'
(Continued)
Uses
High pressure lubricants; flame retardant
for plastics and textiles; secondary
plasticizer for PVC in polyethylene
sealants; detergents; solvent for
dichloroamine-T
Floor treatment; lubricant; medicinal
(when purified); suspending agent; grain
preservation
Emollient base; lubricating firearms and
machinery; leather grease, shoe polish;
modeling clays; cosmetics; food additive;
rust preventative; protective dressings;
perfume extractor; insect repellents;
rubber softener; release agent
Plasticizer
Solvent and plasticizer: lacquers; var-
nishes; coating compositions
(Con tinued )
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Plasticizer
BENZOIC ACID DERIVATIVES
Benzyl benzoate
Cumyl phenyl dibenzoate
Diethylene glycol dibenzoate
Dipropylene glycol dibenzoate
Diethylene and Dipropylene
glycol dibenzoate blend
Ethylene glycol dibenzoate
0-
N
~
Glyceryl tribenzoate
Neopentyl glycol dibenzoate
Pentaerythritol tetrabenzoate
Octylene Glycol Dibenzoate
'J
Polyethylene glycol (200)
dibenzoate
Polyethylene glycol (300)
dibenzoate
Polyethylene glycol (400)
dibenzoate
Polyethylene glycol (600)
dibenzoate
Sucrose benzoate
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TABLE B-13
(Continued)
Production/Consumptiont
3.4 x 105 kgs (75)
(total)
!!!!!
Solvent for cellulose acetate, nitro-
cellulose and artificial 8Usk; perfume
fixative; caaphor subatitute in celluloid
and plastic pyroxylin c08pounda; confec-
tionary and chewing gum flavors; remedy
for scabies; plasticizer; dye carrier
Plaaticlzer
Plasticizer
Plasticizer
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BENZOIC ACID DERIVATIVES
(Continued)
Triethylene glycol dibenzoate
Trimethylolethsne Tribenzoate
2,2,4-Trimethyl-I,3-pentanediol
isobutyrate benzoste
Proprietsry low stain benzoic
add derivstive
POLYPHBNYL
Hydrogensted terphenyl
LACTAH
2-Pyrrolidone
ACETATES
Cumyl phenyl acetate
PllENOXYS
Acetyl paracumyl phenol
~
Benzophenone
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TABLE B-13
Production/Consumptiont
>5.9 x 106 kgs (75)
(total)
(Continued)
Uses
Vinyl plasticizer; sdhesives
Pissticizer and coalescing agent for
acrylic floor polish; solvent for poly-
mers, insecticides, polyhydroxylic
alcohola, sugar, iodine, inks; monomer
for nylon 4 and other polymers
Organic synthesia; odor fixation; deriva-
tives used as UV absorbers; flavoring;
soap fragrance; phar88ceuticals; poly-
merization inhibitor for styrene
(Continued)
-------
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Plasticizer
GLYCOLATES
Butyl phthalyl butyl glycolate
Dibutyl methylene bisthioglyco-
late
Dicapryl diglycolate
Dioctyl thiodiglycolate
Ethyl phthalyl ethyl glycolate
Kethyl phthalyl ether glycolate
GLYCEROL DERIVATIVES
Glycerol
0\
N
0\
Glycerol carbonate
Glycerol diacetate
Glycerol mooacetate
~ '.'
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Glycerol triacetate
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Glycerol tributyrate
Glycerol triricinoleate
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,
TABLE B-13
Productioo/Coosumptiont
1.4 x 107 kgs (75)
>4.5 x 102 kgs (79)
(total)
(Continued)
Uses
Plasticizer
L
!
t.
23% in drugs; 21% io production of alkyd
surface coatings; 15% as humectant io
tobacco; 12% as solvent for flavors and
food colora; 11% aa plasticizer io cello-
phane; 7% in manufacture of polyester
polyols for urethane foams; 5% as inter-
mediate for nitroglycerin; 6% other
sppUcations
Gelatinizing agent for explosives; sol-
vent for basic dyes; tanning leather;
food additive
Plasticizer for cellulose acetate; binder
for solid rocket fuels; fixative in per-
fumes; fungicide in cosmetics; to remove
carbon dioxide from natural gas; food
additive
Synthetic flavoring; solvent; plasticizer
(Continued)
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Plasticizer
GLYCOL DERIVATIVES
GLYCOLS AND GLYCOL ESTERS
l,3-Butsnediol
2,3-Butanediol l,4-Butsnediol
d1c:aprylate
l,4-Butanediol dipelsrgonate
Butyl carbitol acetste
Diethylene glycol dipelargonate
Diethylene glycol mono butyl
ether acetste
[Butyl Carbitol Acetate)
2,2-Diethyl-l.3-propanediol
Ethylene glycol diacetate
Ethylene glycol dipelsrgonste
2-Ethyl-l,3-hexanediol
~ .~
l,5-Hexanediol
Polyethylene glycol 200
: ~
Polyethylene glycol 300
!
.;
TABLE B-13
Production/Consumptiont
>9.1 x 102 kgs (75)
( total)
(Continued)
~
Intermediate in manufacture of polyester
plasticizers; humectsnt for cellophane;
tobacco; Gold inhibitor; surface active
agents; coupling agenta; solvent;
flavoring
r
Solvent for oils, explosives, cellulose
ethers, printing inks; plasticizer; per-
fume fixative
Anthropod and inaect repellent; solvent
for resins and inks; plasticizer; inter-
mediate in the production of polyurethane
resins
(Continued):" .
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Plaaticizer
GLYCOLS AND GLYCOL ESTERS
(Continued)
Tetraethylene glycol dl-(2-
ethylenehexsnoate)
Tetraethylene glycol
dlheptanoate
Trlethylene glycol dlacetate
Trlethylene glycol dlcaprylate
Trlathylene glycol dlcaprylate-
caprate
Trlethylene glycol dl-(2-ethyl-
butyrate)
0\
N
CD
Trlethylene glycol dl-(2-
ethylhexoate)
Trlethylene glycol dlheptanoate
Trlethylene glycol
dlperlargonate
"
;
Trlethylene glycol ester of
fatty sdd
Trlglycol ester of vegetable
011 fstty add
Trlmethylol ethane trlcarpry-
late-caprate
Trlmethylol propane
triheptanoate
TABLE B-13
(Continued)
Productlon/CoDsugptloDt
Plasticizer
Uses
!" :
II" .
(Con tinued )
",1,
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,
0\
N
\0
-;
Plasticizer
GLYCOLS AND GLYCOL ESTERS
(Continued)
Polyethylene glycol 400
Polyethylene glycol 600
Polyethylene glycol 900
Polyethylene glycol 1000
Polyethylene glycol 1500
Polyethylene glycol 1450
Polyethylene glycol 1500 and
500B
Polyethylene glycol 1530
Polyethylene glycol 3350
Polyethylene glycol 4000
Polyethylene glycol 4500
Polyethylene glycol 6000
Polyethylene glycol 8000
Polyethylene glycol 2(tf
Polyethylene glycol (200)
di-(2-ethylhexoate)
(Polyethylene glycol dioctoate)
Polyethylene glycol (600)
lIOoolaurate
TABLE B-13
Production/Consumptiont
(Continued)
!!!!!.
Plasticizer: softening agent; mold
release sgent: solvent: dispersing agent:
binder: chemicsl intermediate
(Continued)
-------
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DERIVATIVBS OF FATTY ACIDS
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LAURATI!S
Butoxyethyl laurate
Diethylene glycol monolaurate
. ~
Glycerol 8Onolaurate
'j
Polyethylene glycol (400)
dUaurate
..
0\
lAJ
o
1,2 Propylene glycol
8IOnoiaurate
HYRISTATI!S
n-Butyl myriatate
Isopropyl myriatate
Iaopropyl myristate-palmltate
~
Butozyethyl oleate
Butyl oleate
.t
TABLE B-13
(Continued)
Production/Consumptiont
1.3 x 106 kga (79)
1.2 x 106 kga (79)
Uaes
Emulsifying agent, e8Olsio08 for lubri-
cants, sizing, finishing of textiles,
paper and leather, fluid emulsions of
oils, dry cleaning soap base, anti foaming
agent
Emulsifying and dispersing agent for food
products, oils, waxes and solvents, anti-
foaming agent, dry-cleaning soap base
Plasticizer, lubricant for textiles,
paper stencils, cosmetic preparations
In cosmetics as emollient snd emulsifier,
reagent, solvent
Cosmetics (emollient and e8OIsifier)
PVC plasticizer, solvent, lubricant,
wster-resisting agent, coating composi-
tions, polishes, water-proofing compounds
! '
(Continued)
-------
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Plasticber
,
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Diethylene glycol aonooleate
,
.
,
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Ethylene glycol monobutyl ether
oleate
",
Glycerol monooleate
Glycerol trioleate 101ein)
Isopropyl oleate
Lesd oles te
0\
W
I-'
Methoxyethyl oleste
Methyl oleste
n-Propyl oleate
Tetrshydrofurfuryl oleate
PALHITATES
Isooctyl palmitate
Isopropyl palmitate
Myricyl palmitate IBeeswax)
. !
TABLE B-13
Production/Consumptiont
1.7 x 106 kgs (75)
( total)
1.8 x 105 kgs (79)
2.0 x 106 kgs (79)
(Continued)
~
Emulsifying agent for furniture and auto-
mobile polish; water-emulsion paints;
agricultural sprays
Foods; pharmaceuticals; cosmetics; rust
prevention oil; textile finish; vinyl
light stabilizer; odorless base paints;
flavoring
Vsrnishes; lscquers; paint drier; high
pressure lubricsnt
:t "
I,.' .
Intermediate for detergents, emulsifiers,
. wetting agents, stabilbers; textile
treatment; plasticizer for inks, rubbers,
waxes, and plastics; chromatographic
standard; biomedical research
III,
Plasticizer
Secondary plasticizer, extrusion aid;
emollient and emulsifier in cosmetics
Emollient and emulsifier for cosmetics
and lot ions
(Continued)
-------
Plasticizer
IUCIHOLEATES
n-Butyl acetyl ricinoleate
Butyl ricinoleate
Diethylene glycol monoricino-
leate
Glycerol ricinoleate
(Caster 011 )
Glycerol triacetyl ricinoleate
0'\
UJ
N
Methyl acetyl ricinoleate
Methoxyethyl acetyl ricinoleate
Methyl ricinoleate
Propylene glycol monoricino-
leate
STEARATES
Butyl acetoxystearate
Butoxyethyl stearate
Butyl epoxystearate
TABLE B-13
(Continued)
Production/ConsU8ptiont
Uses
Plasticizer: emulsifier: lubricant:,
detergent: protective coating: special
cleansing co.pounds: quick-breaking
e...lsions
Plasticizer: lubricant
Plasticizer for high polymers and
elsstomers
Hon-dryiQg emulsifying agent: solvent:
plasticizer; paper, cosmetics, textiles,
and leather processing: lubricant; paint
stabilizer
Plasticizer: lubricant: protective
coating
Plasticizer: lubricant: protective coat-
ing: synthetic rubbers: vinyl compounds
Plasticizer: lubricant: cutting oil addi-
tive: wetting agent
Plasticizer: 'dye solvent: lubricant:
cosmetics: urethane polymers: hydraulic
fluids
Plasticizer: textile oils: adhesives
Plasticizer and solvent
(Continued)
I
i
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It,I-,
-------
Plasticizer
STEARATES (Continued)
Butyl stearate
Diethylene glycol distearate
Ethyl stearate
Glycerol monostearate
0\
W
lJ.)
Glycerol triacetoxystearate
Glycerol tri(epoxy acetoxy
stearate)
Hexadecyl stearate
(Cetyl Stearate)
Isobutyl stearate
".1
Isooctyl epoxy stearate
Hethoxyethylacetoxy stearate
.1
! .
TABLE B-13
(Continued)
Production/Consumptiont
3.8 x 106 kgs (79)
(total)
7.7 x 105 kgs (79)
(total)
!!!!!
Polishes; special lubricanta; coatinga;
metal lubricant; plasticizer for Ismina-
ted fiber producta, rubber. hydrochloride ,
chlorinated rubber and cable lacquers;
carbon paper snd inks; emollient; in
cosmetic preparations; flsvoring; soften-
ing agent; dye solvent
Emulsifying agent; lubricating agent;
suspending medium; temporary binder; pro-
tective coating; thickening agent;
pharmaceuticals
Thickening and emulsifying sgent for
foods; flavoring; emulsifier for oils;
protective coating; cosmetics; opacifier;
detackifier; resin lubricant
Plssticizer for nitrocellulose, ethyl
cellulose and PYC; lubricsnt; protective
coating
Wsterproof coatinga; polishes; fsce
creams; rouge; ointments, soaps; rubber
manufacture: dye solution; inks;
lubricsnts
(Continued)
-------
"
Plasticber
STBARATES (Continued)
Methoxyethyl stearate
Methyl hydroxystesrate wax
Methyl pentachlorostearate
(atabilbed)
Methyl stearate
Octyl stesrate
0\
UJ
.po
l,2-Propylene glycol
DIOoostearate
Vinyl stesrste
TALL OILS
Isooctyl esters of tsll oil
Methyl esters of tall oil
PATTY HITaILES
Patty acid nitrile
Oleyl nitrile
Tallow nitrile
OTHER MISCELLANEOUS
PLASTICIZERS
CARBONATES
Bis-dimethyl benzyl carbonste
Dinonyl phenyl csrbonate
'.
TABLE B-13
Production/Consumptiont
>4.5 x 102 kgs (75)
(total)
(Continued)
Uses
Intermediste for stearic acid detergents,
emulsifiers, wettioa agents, stabilizers,
resins, lubricants, textiles, and plasti-
cizers; lubricating oil component; lip-
stick, nail varnishes, and ointments
I"
Emulsifier; stabilizer
Plasticizer; lubricant
(Continued)
-------
Plaaticher
ETHERS
Bis(disethylbenzyl) ether
Cumyl phenyl benzyl ether
Nonylphenol ethylene oxide
Tridecanol ethylene oxide
adduct
SULl'OHAHIDES
n-Cyclohexyl-p-toluene
sulfonallide
n-Ethyl-o,p-toluene sulfon8llide
n-Ethyl-p-toluene sulfonamide
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Sulfonallide-formaldehyde resin
o,p-Toluene sulfonamide
AMIDES
Benzallide
Dibutyl laur8llide
2,2'-(2-Ethylhexallidodiethyl)
di-2-ethylhexoate
. ,
;-1
TABLE B-13
(Continued)
I. .,
Production/CoDaumptiont
".1.
Uses
Reactive plasticizer in hot lIelt adhe-
sives of therllosetting resins, e.g.,
allioo and phenolic resins; plasticizer
for casein, shellac, zein and soya
protein coating; carrier for fluorescent
pigments; intermediate in production of
saccharin
(Continued)
-------
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AHIDES (Continued)
Urea
NITRO COMPOUNDS
Nitrobenzene
i
':
o-Nitrobiphenyl
0\ 2-Nitrodiphenyl ether
v.>
0\ o-Nitrotoluene
SULFONATES
" Phenol, cresol esters of
pentsdecylsulfonic scid
Cresyl-p-toluene sulfonate
~
Csmphor
alpha-Hethyl-D glucoside
TABLE B-13
(Continued)
Production/Consumptiont
3.8 " 106 kgs (75)
(total)
9.1 " 106 kgs (75)
( total)
Uses
37% as a liquid fertilizer; 24% other
fertilizers; 22% livetock nutrient; 17%,
resins and other uses including phsrma-
ceutical production, cellulose softener,
ammoniated dentrifices, diuretic, e"plo-
sives stabilizers, separation of hydro-
carbons, and flameproofing agent
Solvent; chemlcsl intermediste for
aniline and derivatives; soaps; shoe and
floor polish; refining lubricating oils;
preservative in spray paint
Intermediate for o-toluidine, fuchsine,
o-nitrobenzoic acid; manufacture of dyes
E"ploslves; moth repellent; embalming
fluid; manufacture of cymene; preserva-
tive; Insect repellent; cosmetic
ingredient
'1' .
I,,' ,
III,
(Continued) ,
-------
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TABLE B-13
(Continued)
1
Plasticher
Production/Consumptiont
Usea
OTHERS (Continued)
Sorbitol
5.9 a 107 kgs (75)
(total)
Manufacture of sorbose, escorbic acid,
propylene glycol, synthetic plasticizers,
and resina; huaectant on printing rolls;
in leather; antifreeze adatures; bulking
agent for food; flavor additivea; sur-
factants; cOBGetics; stabilizers for
vinyl resins
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tAnnual Consumption is presented parenthetically for the most recent year availsble.
,
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Preservati ve
-I
,
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Barium metaborate (Busan Il-H-l)
Butyl p-hydroxybenzoate (Butyl psrsben)
!
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Copper-8-quinolinste
1.2-Dibromo-2.4-dicyanobutane (Tektamer
38)
.. ,
-,
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- i
3.5-Dimethyltetrahydro-l,3,5-thiadia-
zine-2-thione (Hylone). (Dozomet)
D1phenyl antimony 2-ethylhexanoate
2-Hydroxy-5-chlorobenzoic-3.4'-dichloro-
anilide
'"
v.J
ex>
8-Hydroxyquinoline
Intercide N-638 (trialkyl organotin)
2-Hethyl-l-naphthyl male imide
Hethyl p-hydroxybenzoate (Methyl paraben)
2-N-Dctyl-4-isothiazolin-3-one (Hicro-
Chek 11), (Hicro-chek 110)
10,lD-Oxybisphenoarsine (Vinyzene BP-5).
(Vinyzene BP-5-2I, (Vinyzene SB-l)
Phenyl mercuric salicylate
(C6"4(OH)(COOHgC6"5)1
Propyl p-hydroxybenzoate (Propyl para-
benl, [CloH1203)
; -
TABLE B-14. PRESERVATIVES
CONSUMPTION AND OTHER USES
Conaumptiont
1.0 x 104 kgs (72)
(total)
4.5 x 104 kgs (15)
(total)
2.2 x 105 kgs (75)
(total)
>1.4 x 103 kgs (15)
(total)
!!.!!.
Paint mildewcide
Antifungsl preservative for pharmaceuticals, creams. and
fooda; flavoring agent
Fungicide and mildew-proofing of fabrics and plastics for
military applications; analysis for copper
Soil fungicide; crop herbicide; antimicrobial sgent for
slimicide preparations and adhesives
Precipitating and separating metals; preparation of fungi-
cides; chemical intermediate; antiseptic; stabilizer for
hydrogen peroxide -
Medicine; food additive (preservative); antimicrobial agent
for cosmetics. food, and pharmaceuticals
Fungicide for paint and plastics
Antimicrobial agent fo plastics and textiles
Seed disinfectant
Medicine; food preservative; fungicide; mold control in
sausage casings
;;
(Continued)
-------
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Preservative
PPC (DH-50), (organometallic)
Quaternary ammonium naphthenate
3,5,3',4'-Tetrachloroaalicylanilide
2,2'-Thiobia(4,6-dichlorophenol)
Tributyltin fluoride
Tributyltin oxide
(C4Hg)3SnOSn(C4Hg)3)
Tributyltin salicylate (Cotin PI
Trichloromethylmercapto-4-cyclohexene-
l,2-dicarboximide (Captan), (Vancide 89),
(CgHSC13N02S), (N-trichlo-
romethylmercaptotetrahydrophthalimide)
0\
VJ
\0
n-(Trichloromethylthio)phthalimide
(Folpet), (Phaltan),
[C6"4(CO)2NSCC13)
N-(Trichloromethylthio)tetraphthalimide
Zinc borate [3ZnO'2B~3)
TABLE B-14
Conaumptiont
4.5 x 106 tga (75)
(total )
1.8 x 105 tga (75)
(total)
"
(Continued)
Uae
Fungicide and bactericide for vinyl film, coating, and fabric
Antifungal agent for paint
Bactericide; fungicide for paint and plaatica; intermediate
Seed treatment; fungicide in painta, plaatica, lacquera,
leather, fabrica, and fruit preaervation
Fungicide-bactericide for vinyla, painta and enamela;
fu~gicide for fruita, vegetablea, and flowera
Medicine; fireproofing textilea; fungiatat and mildew
inhibitor; flux in ceramica
tAnnual Conaumption ia preaented parenthetically for the moat recent year available.
I,; "
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Solution Modifier/Polymerization Aid
ACIDS, BASES, AND BUFFERS
ACIDS
Foradc Acid (IICOOH)
",1
Hydrochloric acid (HCl)
Lactic acid (CH)CHOHCOOH)
0'\
~
a
Maleic acid (HOOCCH:CHCOOH)
Nitric acid (HNO))
2-Naphthalenesulfonic acid
(ClOII7S0JRI
Phosphoric acid (H)P04)
, .
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, ,
\
TABLE B-15. SOLUTION MODIFIERS
CONSUMPTION AND OTHER USES
Consumptiont
2.8 x 107 kgs (74)
(total)
2.) x 109 kgs (82)
(total)
6.8 x 109 kgs (82)
(total)
7.7 x 109 kgs (82)
(total)
Use
Dyeing and finishing of textiles and paper, leather treatment; chemi-
cals (formates, oxalic acid, organic estera); manufacture of fumigants,
insecticidea, refrigerants, solventa for perfumes, lacquers; electro-
plating; medicine; brewing (antiseptic); silvering glass; cellulose
formate; rubber latex coagulant; ore flotation; vinyl resin plasti-
cizers; animal feed additive; electroplating; chemical analysis
~ . ;
Acidizing of petroleum wella; chemical intermediate; ore reduction
for tin and tantalum; food processing; pickling and metal cleaning;
industrial acidizing; general cleaning; alcohol denaturant; laboratory
reagent; production of chlorides; manufacture of phosphoric acid;
starch modifier; production of vinyl chloride
..
Cultured dairy producta; as acidulent; flavoring; preservative; chemi-
cals (salts, plasticizers, adhesives, pharmaceuticals)
Organic synthesis (maleic, succinic, aspartic, tartaric, propionic,
lactic, malonic, acrylic, hydroacrylic acids); dyeing and finishing of
cotton, wool, and silk; preaervative for oils and fats
Manufacture of ammonium nitrate for fertilizer and explosivea;
and inorganic syntheais (dyes, isocyanates, drugs, explosives,
cellulose nitrate, nitrate salts); metallurgy; photoengraving;
steel; ore flotation; medicine; reagent
organic
etching
Starting materi,l for a-naphthol, a-naphthol sulfonic acid, a-naphthyl-
aminesulfonic acid, etc.
Fertilizers; soaps and detergents; inorganic phosphates; pickling and
rust-proofing metals; pharmaceuticals; sugar refining; gelatin manu-
facture; water treatment; animal feeds; electro-pollshing; gasoline
additive; conversion coating for metals; catalyst for ethanol manufac-
ture; lakes in cotton dyeing; yeasts; soil stabilizers; waxea and
polishes; binder for ceramics; activated carbon; ~n foods and carbon-
ated beverages as acidulent and sequestrant; labo~AtDry reagent; source
of uranium (experimental); intermediate; catalyst for making ethylene;
flavoring for soft drinks ' II ~'
I t
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; {J.!
rip
.I.h~l,
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(Continued)
-------
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Solution Hodifier/Polymerization Aid
ACIDS (Continued)
Sulfuric acid (H2S04)
BASBS
Ammonia (NH3)
Q'\
~
......
Ammonium hydroxide (NH40H) iSee
Ammonia )
Hethanolic aodium methoxide (Sodium
methoxide in methyl alcohol)
(CRJONa 'CH30R)
Potassium hydroxide (KOH)
Sodium hydroxide (NaOH)
TABLE B-15
ConsWlpUont
2.9 x 1010 kgs (82)
(total )
1.4 x 1010 kgs (82)
(total)
4.2 x 106 kgs (79)
(total)
1.9 x 108 kgs (75)
(total)
8.2 x 109 kgs (82)
(total)
(Continued)
;"
Use
,
t. ..,
Fertilizers; chemicala; inorganic pigments; petroleum refining;
titanium dioxide; manufacture of ammonium sulfate, dyestuffs, other
acida, paper and glue; etchant; alkylation catalyst; electroplating
baths; iron and steel; rayon and film; induatrial exploaives; labora-
tory reagent; nonferrous .etallurgy; dehydrating agent for ethera and
esters; gaa drying, obtaining glucose from hydrolysis of cellulose
Fertilizers; manufscture of nitric scid, hydrazine hydrate,
caprolactsm, acrylonitrile, hydrogen cyanide, urethane, acrylonitrile
and sodium carbonate; refrigerant; nitriding of steel; condensation
catalyst; synthetic fibers; dyeing; neutralizing agent in petroleum
industry~ latex preservative; sulfite cooking liquors; fuel cells;
rocket fuel; yeast nutrient; developing diazo films; explosives;
solvent; cleaning and bleaching; cotton defoliant
Textiles; manufacture'of rayon, rubber, fertilizers; refrigeration;
condensation polymerization; photography; pharmaceuticals; smmonia
soaps; lubricants; fireproofing wood; ink manufacture; explosives;
ceramics; ammonium compounds; saponifying fats and oils; organic
synthesis; detergent; food additive; household,cleanser
Condensation reactions; catalyst for treatment of edible fats and oils
(especially lard); intermediate for pharmaceut~cals; preparation of
sodium cellulosate; anslytical reagent
Soap manufacture; bleaching; manufacture of potassium carbonate and
tetrapotassium pyrophosphate; electrolyte in alkaline storage batteries
and SODe fuel cells; absorbent for carbon dioxide and hydrogen sulfide;
dyestuffs; liquid fertilizers; food additive; herbicides;
electroplating; inks; analytical chemistry
Chemical manufacture; rayon and cellophane; petroleum refining; pulp
and paper; sluminum; detergents; soaps; textile processing; vegetable
oil refining; reclaiming rubber; regenerating ion exchange resins;
organic fusions; peeling of fruits and vegetables in food industry;
laboratory reagent; etching and electroplating; precipitation of
alkoloids; neutralizing acids; deshorning calves; explosives snd
dyestuffs; electrolyttc extraction of zinc
(Continued)
-------
,
. ,
.'
Solution Modifier/Polymerization Aid
~
Ammonium acetate
[(NH4)C2Hj!21
Borax [Na2B4071
,;
Calcium carbonate [Cac031
-,
-j
- j
Potaasium bicarbonate [KHC031
..
Sodium acetate (NaC2Hj!2!
,
-i
0-
.l:-
N
. ~
Sodium bicarbonate (NaHC03!
. !
'j
. ;
Sodium carbonate
(Na2C03.H~1
Sodium formate (BCOONaI
Sodium hydrogen phosphate (aodium
phosphate, dibasicl [NaH2P041
j
J
- ~ I
j
TABLE B-15
Consumptlont
5.9 x 105 kgs (79)
(total)
7.3 x 109 kgs (82)
(totsl)
1.5 x 107 kgs (72)
(total )
3.1 x 107 lbs (72)
(total)
(Continued)
I
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,-
Use
Reagent in analytical chemistry; drugs; textile dyeing; preservative
for meats; foam rubbers; vinyl plastics; explosives'
Manufacture of glass, enamela, and other ceramic products; herbicide
Source of lime; neutralizing agent; filler and extender in rubber,
plastics, paint; opacifying agent in paper; fortification of bread;
putty; tooth powders; antacid; whitewash; POrtland cement; 502
removal from stack gases; metallurgical flux; analytical chemistry;
C02 generation (laboratory)
Baking; aoft drinka; medicine (antacid); manufacture of pure potassium
carbonate; fire extinguishing agent; low pH liquid detergents; labora-
tory reagent
Dye and color intermediate; pharmaceuticala; cinnamic acid; soaps;
buffer; photography; purification of glucose; meat preservation;
medicine; electroplating; tanning; dehydrating'agent; buffer in foods;
laboratory reagent; meat preservation
Manufacture of efferveacent salts and beverages, artifical mineral
water, baking powder; other aodium aalts; pharamaceuticals; sponge
rubber; gold and platinum plating; treating wool and silk; fire
extinguishers; ceramics; prevention of timber mold; laboratory reagent;
antacid; mouthwash; skin ointment; cleaning compound
Medicine; photography; cleaning and boiler compounds; pH control of
water; food additive; manufacture of sodium aalts; glass; aoap; washing
wool; bleaching; analytical reagent; aluminum production; petroleum
refining; pulp and paper
Reducing agent; manufacture of formic acid and oxalic acid; organic
chemicals; mordant; manufacture of aodium dithionite; complexing agent;
analytical reagent; acidulent in textile and leather industry;
preciprtant; astringent
Boiler water treatment; electroplating; dyeing; acid cleansera; baking
powders; cattle food supplement; buffer, emulsifier, nutrient supple-
ment in food; laboratory reagent; laxative; textile processing
(Continued)
-------
.j
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Solution Modifier/Polymerization Aid
CHAIN TRANSFER AGENTS
Acetaldehyde [CH)CHO)
"
Acetic acid [CH3COOH)
, ,
Acetic anhydride [CH3(CO)20)
Acetone [CH)COCH3)
0\
~
W
Acetylene [HCCH)
Benzene [C6H6)
Bromoform [CHBr3)
~ ! .
n-Butane [C4HlO)
.'
"
, "
,>
l-Butanethiol [C4HgSH)
Butyl chloride [(CH3)3CCl)
TABLE B-15
ConsUllptiont
4.1 x 108 kgs (79)
(total)
1.3 x 109 kgs (82)
(total)
5.0 x 108 kgs (82)
(total)
8.2 x 108 kgs (82)
(total)
3.5 x 109 kgs (82)
(total)
1.1 x 109 kgs (15)
(total)
(Continued)
Use
Hanufacture of acetic acid and acetic anhydride, n-butanol, 2-ethyl-
hexanol, peracetic acid, pentaerythritol, pyridines, chloral, 1,3-
butylene glycol, and trimethylolpropane. also as an intermediate.
synthetic flavoring. plastics. synthetic rubber; silvering mirrors
Manufacture of acetic anhydride, cellulose acetate, vinyl acetate
monomer, acetic esters and chloroacetic acid. production of plastics,
rubber, pharmaceuticals, dyes, insecticides, photographic chemicals,
etc.. food additive. latex coagulant. oil well acidizer; textile
printing ,
Cellulose acetate fibers and plastics. vinyl a~*.te. dehydrating and
acetylating agent in production of pharmaceuti~Jls, dyes, perfWles,
explosives, etc.; aspirin. esterifying agent f~ fO~ starch
Chemicals (methyl isobutyl ketone, methyl iso~utyl: J.rbinol; methyl
methacrylate, bisphenol-A). paint, varnish ana l.c~uer solvent. cellu-
lose acetate, especially as spinning solvent. foo "I'En and dry parts of
precision equipment; solvent for potassium iofllde' a permanganste;
delustersnt for cellulose acetate fibers; sp~~i~~~~,ion testing of
wlcanized rubber products. photographic films, :'uppng acetylene gas.
hardening and dehydrating tissues. nail polis~' ~~~ver; food additive
\ I , ill
Vinyl chloride and vinylidene chloride. VinYlla~~~~; welding and
cutting metala. acrylonitrile; acrylatea. per- and trichloroethylene,
cyclooctatetraene, l,4-butanediol. carbon black ~ I'
Ethylbenzene (for styrene monomer). dodecylbenzeae'~'for detergents);
cyclohexane (for nylon). phenol. nitrobenzene (for aniline). maleic
anhydride. chlorobenzene. diphenyl. benzene hexachloride; anthraqui-
none. cUllene. benzene sulfonic acid. solvent. antiknock gasoline
Intermediate in organic synthesis; geological assaying; solvent for
waxes. grease and 0118
Organic ayntheais of acetic acid, butadiene and maleic anhydride; raw
material for aynthetic rubber and high octane liquid fuela. fuel for
houaehold and many induatrial purposes; manufacture of ethylene;
solvent. refrigerant.' standby snd enricher gas; propellant in aerosols.
pure grades used in calibrating instruments. food additive
Intermediate; solvent; pesticides
Organic synthesis
(Continued)
-------
Solution Modifier/Polymerization Aid
CHAIN TRANSFER AGENTS (COntinued)
1
.,
t-Butyl mercaptan (2-methyl-2-
propanethio 1 I
Carbon tetrabromide (CBr41
Carbon tetrachloride (CC14I
Chlorobenzene (C6H5Cll
Chloroform (CHCl)1
Crotonaldehyde (2-butenall
(CH)CH:CHCHOI
0\
.po
.po
Cyclohexane (C6"121
.,
'r:
",!
,
. ,
n-Decyl mercaptan (CloH21SHI
trana-Dichloroethylene (ClHC:CHCl)
.. .
..
'.1
./
Diethyl zinc (Zn(C2H5)21
" .1
Dipentene (CloH161
"
. I
',~: -~1
TABLE B-15
Conaumptiont
>4.5 x 102 kga (15)
(total)
).2 x 108 kga (19)
(total)
1.5 x 108 kga (15)
(total )
1.6 x 108 kga (19)
(total)
5.9 x 108 kga (82)
(total)
(Continued)
Uae
Intermediate; gaa odorant for detecting leaka
Organic aynthesis
Refrigerants and propellants, especially the Chlbr,ofluorohydrocarbons;
metal degreasing; agricultural fumigant; chlorina~ing organic com-
pounds; production of semiconductors; solvent. II \'
Phenol; chloronitrobenzene; aniline; solvent c~rrie~ tor methylene
diisocyanate; solvent; pesticide intermediate.
\ 'l~
Fluorocarbon refrigerants and propellanta; fluyJocaf~. n plastics; sol-
vent; analytical chemistry; fumigant; insectic~de,\,: .,
. '- I \
Intermediate for n-butyl alcohol and 2-ethYlhe~'lV~cOhOl; aolvent;
preparation of rubber acceleratora; purificati~~of;!+bricating oils;
insecticidea; tear gas; fuel-gas warning agent~ otg~"c synthesis;
leather tanning; alcohol denaturant '
\\ ""
Manufacture of caprolactam, hexamethylenediamine, c~c~ohexanone,
cyclohexane, cyclohexyl chloride, and nitrocyclohesa8e; solvent for
cellulose ethers, fats, oils, waxes, bitumens, resins, crude rubber;
extracting essential oils; recrystallizing medium; paint and varnish
remover; glass substitutes; vapor has been used as lubricant for steel;
analytical chemistry
Intermediate; synthetic rubber processing
General solvent for organic materials; dye extraction; perfumes;
lacquers; thermoplastics; organic synthesis; medicine
Organic synthesis; catalyst for polymerization of olefins; high energy
aircraft and missile fuel; production of ethyl mercuric chloride
Solvent for oleoresinoua products, rosin, ester gum, alkyd resins,
waxes, metallic soap dryera, rubber, etc.; rubber compounding and
reclaiming; dispersing agent for oils, resins, resin-oil combinations,
pigments and dryers; paints, enamels, lacquers and varnishes; general
wetting and dispersing agent; printing inks; peifumes; floor waxes and
furniture polishes; synthetic resins; polyterpenes; chemicals
(Continued)
-------
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Solution Modifier/Polymerization Aid
CHAIN TRANSFER AGENTS (Continued)
Dodecylmercaptan [C12H258HI
j
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Ethane (C2H61
Ethanethiol [C2H58HI
Ethyl acetate [CH3COOC2HSI
Ethylbenzene [C&"SC2HSI
Ethylmercaptoacetate
'"
.po
VI
Formic Add [See Acids 1
Hydrogen [H21
"
Isobutsnol [(CH3)2CHCHiOHI
Isobutsne [(CH3)~HCH31
Isopropanol [(CH3)2CHOHI
.1
,',
, ,
"
!
1
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TABLE B-15
Consumptiont
>4.S x 102 tgs (7S)
(total)
3.6 x 109 tgs (79)
(total)
>9.1 x 102 kgs (7S)
(total)
7.7 x 107 kgs (7S)
(total)
3.0 x 109 tgs (82)
(total)
6.S x 107 tgs (79)
(total)
6.8 x 108 tgs (7S)
(total)
S.9 x 108 tgs (82)
(total)
(Continued)
Use
Hanufacture of synthetic rubber, plastics, pharmaceuticals, insecti-
cides, fungicides, snd styrene-butadiene rubber
Petrochemicals (soarce of ethylene, halogenated ethanes); refrigerant;
fuel
LPG odorant: adhesive stabilizer; chemical intermediate for acaricides,
defoliants, pharmaceuticals and adhesives
General solvent in coatings and plastics: organic synthesis: smokeless
powders; pharmaceuticals: artificial fruit essences: artificial
leather: photographic films
Intermediate in production of styrene and xylene; solvent and diluent:
component of gasoline: manufacture of cellulose acetate
Production of ammonia and methanol; hydrocracking, hydroforming and
hydro refining of petroleum; hydrogenation of vegetable oils: hydrogeno-
lysis of coal: reducing agent in organic synthesis and metallic ores:
reducing atmospheres to prevent oxidstion; as oxyhydrogen flame for
high temperatures: atomic-hydrogen welding; instrument carrying
balloons; making hydrochloric and hydrobromic acids; production of
high-purity metals; coolant and propellant; fuel for'nuclear rocket
engines for hypersonic transport; missile fuel; cryogenic research
Organic synthesis; latent solvent in paints snd lacquers; intermediate
for ~mino coating resins: substitute for n-butyl alcohol: paint
removers; fluorometric determinations; liquid chromatography;
flavorings
Organic synthesis of propylene oxide and t-butyl alcohol; refrigerant;
fuel; aerosol propellant; high octane gasoline (aviation fuel):
synthetic rubber; instrument calibration fluid
Hanufacture of acetone and its derivatives; manufacture of glycerol and
isopropyl acetate; solvent for essential and other oils, alkaloids,
gums, resins, shellacs, etc.; latent solvent for cellulose derivatives;
coatings solvent: deicing agent for liquid fuels; pharmaceuticals:
perfumes; lacquers; extraction processes; dehydrating agent;
preservative; quick drying inks; antiseptic; coupling agent in oil
emulsions
(Continued)
-------
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CHAIN TRANSFER AGENTS (Continued)
Isopropyl benzene [Cumene),
[C6BSCH(CH3)2 )
Lauryl mercaptan (C12H2sSH)
Mercaptoacetic acid (Thioglycolic
acid), [BSCH2COOH)
2-Hercaptoethsnol [HSCH2CHzOH)
Methane [CH4)
(]\
.po
(]\
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]
Methanol [CHJOH)
. .
Methylacetate
. .
2-Methyl-2-propanethiol (See t-Butyl
mercaptan)
O-Hethyl styrene dimer
2-Haphthalenethiol (RPA),
[ClO"lSH)
TABLE B-15
Conaumptiont
1.2 x 109 kga (82)
(total)
3.3 x 109 kgs (82)
(total)
(Continued)
Use
Production of phenol, acetone, and alpha-methyl atyrene; aolvent
for paints, enamels, lacquers. fats and resins
Manufacture of synthetic rubber and plaatics, also in synthesis of
pharmaceuticals and in inaecticides and fungicides; nonionic detergent
/.
Reagent for iron; manufacture of thioglycolates, permanent wave solu-
tions and depilatories; vinyl stabilizer; manufacture of pharmaceuti-
cals
Solvent for dyestuffa; intermediate for producing dyestuffs, pharmaceu-
ticals, rubber, chemicala, flotation agenta, insecticides, plasti-
cizers, textile assistants and other compounda; water soluble reducing
agent; biochemical reagent
Source of petrochemicals by conversion to hydrogen and .carbon monoxide
by ateam cracking or partial oxidation, important products are metha-
nol, acetylene, hydrogen cyanide; chlorination gives carbon tetrachlor-
ide, chloroform, methylene chloride and methyl chloride; in the form of
natural gaa, methane is used as a fuel, as a source of carbon black,
,and aa a .starting material for manufacture of synthetic proteins
Manufacture of formaldehyde and dimethyl terephthalate; chemical
aynthesis (methyl aminea, methyl chloride, methyl methacrylate, etc.);
aviation fuel (for water injection); automotive antifreeze; aolvent for
nitrocellulose, ethyl cellulose, polyvinyl butyral, shellac, rosin,
manila resin, dyes; denaturant for ethyl alcohol; dehydrator for
natural gaa; fuel for utility plants (methyl fuel); feedstock for
manufacture of synthetic proteina by continuous fermentation;
pharmaceuticals
Paint remover compounda; lacquer solvent; intermediate; synthetic
flavoring
Intermediate; gaa odorant for detecting leaka
Feptizlng agent for natural and aynthetic rubber
(Continued)
-------
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Solution Modifier/Polymerization Aid
CHAIN TRANSFER AGENTS (Continued)
3-Pentanol
[CH3CH2CHOHCH2CH3 I
Perchloroethylene [CI2C:CCI2/
"
Phenol [C6"sOH/
Polybromobutenea
Propane [C3H8/
~ . ~
'"
~
-..J
2-Propanethiol [C3H7SHI
Propylene [CH3CH:CH2/
Sodium acetate [NaC2H~2/ [See
Buffers /
Terpinolene [Cl0816/
Thiophenol [C6RsSHI
Toluene [C6HSCH31
TABLE B-15
Consumptiont
4.5 x 109 kga (79)
(total}
5.4 x 109 kgs (82)
(total)
6.8 x 109 kgs (82)
(total)
(Continued)
i' )'~
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\ I I {II
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Use
OJ '1/'
Solvent; flotation agent; pharmaceuticals
Dry cleaning aolvent; vapor-degreaslng solvent; drying agent for metals
and certain other solids; vermIfuge; heat transfer medium; manufacture
of fluorocarbona
Phenollcs resins; epoxy resins; nylon-6,; 2,4-0; selective solvent for
refining lubricating oila; adipic acid; salicylic acid; phenolphtha-
lein; pentachlorophenol; acetophenetidine; picric acId; germicIdal
paints; pharmaceutIcals; laboratory reagent; dyes and indIcators;
sllmlcide
OrganIc synthesis of ethylene and propylene; household and Industrial
fuel; manufacture of ethylene; extractantj solvent; refrigerant; gas
enricher; aerosol propellant; mixture for bubble chambers
ChemIcal intermediate; herbIcIde
Isopropyl alcohol, polypropylene, synthetic glycerol, acrylonitrile,
propylene oxide, heptene, cumene, polymer gasoline; acrylic acId; vinyl
resins; axo chemicals
Solvent for resina; essential oIls; manufacture of synthetic resin,
chemIcal 'derivatIves
Pharmaceutical synthesIs
AviatIon gasoline and high octane blending stock; benzene, phenol, and
caprolactamj solvent for paints and coatings, gums, resins, most oils,
rubber, vinyl orgaoosols; dIluent and thinner in nItrocellulose
lacquers; adhesive solvent in plastic toys and model aIrplanes; chemi-
cals (benzoic scid, benzyl and benzoyl derIvatives, saccharIn, medi-
cInes, dyes, perfumes); source of toluene diisocyanates; explosives
(TNT); toluene sulfonates; scintIllatIon counter
(Continued)
't~
~~ ,
,
./'
"fer
-------
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Solution Modifier/Polymerization Aid
CHAIN TRANSFER AGENTS (COntinued)
: '
Trichloroethylene ICHCl:CC12)
'i
"
"
Triethylamine I(C2HS)]N)
Water
COAGULANTS
Calciwa chloride ICaC12)
'"
~
Hydrochloric acid ISee Acida)
Sodium chloride INaCl)
Sulfuric acid ISee Acida)
CROSSLINKING AGENTS
Dialdehyde starch
Diepoxides
TABLE B-15
Consumptiont
2.0 x 10S kgs (75)
(total)
S.2 x 10S kga (S2)
(total)
(Continued)
, ""
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\ ,'\. '/
'-,( \
; v ~ '
L ,.\1
,k 111
I\" ,
, -
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Use
Metal desreasing; extraction solvent for oils, fats, waxes; solvent
dyeins; dry cleaning; refriserant and heat exchange liquid; fumigant;
cleaning and drying electronic parts; diluent in paint and adhesives;
textile processing; che8ical intermediate; aerospace operations
(flushing liquid oxygen); pharmaceuticals
Catalytic aolvent in chemical synthesis; accelerator activatora for
rubber; wetting. penetrating and waterproofing agents of quaternary
ammonium types; curing and hardening of polyme~s; corrosion inhibitor;
propellant
De-icing and dust control of roads; drilling muds; dustproofing.
freezeprooflng and thawing coal, coke. stone. sand, orei concrete con-
ditioning; paper and pulp industry; fungicides; refrigeration brines;
drying and desiccating agent; sequeatrant in foods; firming agent in
tomato canning; tire weighting; pharmaceuticals; electrolytic cells
Chemicals (aodium hydroxide, aoda ash. hydrochloric acid, chlorine,
metallic aodium); ceramic glazea; metallurgy; curing of hides; food
preservative; mineral watera; soap manufacture (aalting out); home
water softenera; highway de-icing; regeneration of ion-exchange resina;
photography; food aeasoning; herbicides; fire extinguishing; nuclear
reactors; mouthwash; medicine (heat exhaustion); salting out dyestuffs;
supercooled solutions; aingle crystals for spectroscopy. ultraviolet
and infrared transmission
Thickening agent; tanning agent; binder for leaf tobacco; adheaives;
wet-strength additive in paper
'...,..
(Continued)
'.,
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",
,
CROSSLINKING AGENTS (Continued)
.i
Dimethylolurea ICO(NHCH20H)2)
,"
"
Dihydroxydiphenylsulfone
I (C6"40H)2S02)
Diisocyanates
Di vinyl benzene
IC6"4(CH:CH2>2)
Divinyl sulfone
ICH2:CHS02C8:CH2)
Glutaraldehyde
0'
~
\0
Glycol dimethacrylates
Glyoxal 10HCCOH)
Oxalic acid IHOOCCOOH)
Polyacrolein
Trimethylolmelamine
Trivinyl benzene
TABLE B-15
Consumptiont
>2.3 x 103 kgs (76)
(total)
1.1 x 106 kgs (75)
(total)
(Continued)
Use
First stage of urea-formaldehyde resins; impregnating wood to increase
hardneas and fire resistance and 'to form self-binding laminationa for
plywood manufacture; permanent press fabrics
Electroplating; phenolic resins; polyvinyl chloride; intermediate
POlymerization monomer for special synthetic rubbers, drying oils, ion
exchange resins, casting resins and polyesters
Mnnomer used in manufacture of polymers with diols, urea, and malonic
esters; shrinkage control agents (textiles)
Intermediate for adhesives, sealants and electrical products; fixative
fnr tiasues; for crosslinking protein and polyhydroxy materiala;
tanning of soft leather; disinfectant; sterilizing agent
Permanent press fabrics; dimensional stabilization of rayon and other
fibers; insolubilizing agent for compounds containing polyhydroxyl
groups (polyvinyl alcohol, starch and cellulnsic materials); insolub-
lizing agent for proteins (casein, gelatin and animal glue); embalming
fluids; leather tanning; paper coatings with hydroxyethylcellulose;
reducing agent for dyeing textiles; intermediate for dihydroxydi-
methylol ethylene urea; tobacco treatment; crossllnking agent
Automobile radiator cleanser; general metal and equipment cleaning;
purifying agent and intermediate for many compounds; leather tanning;
catalyst; laboratory reagent; stripping agent for permanent press
resins; bleaching of textiles; rare-earth processing
First stage in making melamine resins
(Continued)
-------
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DEFOAMANTS
Aluminum oxide, hydrated (See
Protective Colloids)
Decanol (CH3(CHZ)sCHZOH)
Dimethyl silicone (polymeric)
((CH3)zSiO)x)
Glycerol IZ-hydroxyoleate Iglyceryl
monoricinoleate)
IC6HrfHOHClDHIgCOOCHZCHOHCHZOH)
Heptsnol ICH3(CHZ)SCHZOH)
Hexanol (CH3(CHZ)4CHZOH)
0\
\J1
o
Octanol (CH3(CHZ)6CHZOH)
EHULSlFlERS
Alkyl naphthalene sulfonic acid
Ammonium oleate ICI7H33COONH4)
Ammonium stearate
(CI JH3sCOONH4)
Cetyl trimethyl ammonium bromide
ICI6833(CH3)3NBr)
Cetyl pyridinium chloride
(CI6HnCs"sNCl"HzO)
Dihexyl sodium sulfosuccinate
Dodecyl benzene aulfonate
TABLE B-15
ConsWlpUont
(Continued)
'I,
Use
Plasticizera; detergents; synthetic lubricants; solvents; perfumes;
flavorings
Nondrying emulsifying agent; solvent; plasticizer; in polishes, in coa-
metics, in textile, paper and leather procesaing; low temperature
lubricant; atabilizea latex paints against breakdown due to repeated
freeze-thaw
Organic intermediate; solvent; cos.etic formulations
Pharmaceuticals; solvent; plasticizer; intermediate for textile and
leather finishing agenta
Perfumery; cosmetics; organic synthesis; solvent; manufacture of high-
boiling esters; anti foaming agent; flavoring agent
Emulsifying agent; cosmetics
Vanishing creams, brushless shaving creams, other cosmetic products;
waterproofing of cements, concrete, stucco, paper, textiles, etc.
Surface active agent; germicide
Medicine
(Continued)
-------
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I
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EMULSIFIERS (Continued)
Dodecyl benzene sodium sulfonate
[C12H2SC6'l4S0Jlfa )
Dodecyl pyridinium chloride
Dresinate [Rosin soap)
Ethyl crotonate
[CH]CH:CHCOOC2HS)
Isopropyl amine dodecyl benzene
sultona te
Lauric acid [CH](CH2)loCOOH)
(J'\
V1
~
Lauryl trimethyl quaternary ammonium
bromide
Lauroxypolyethylene glycol
Myristic acid [CH](CH2)12COOHI
Palmitic acid [CH](CH2)14COOR)
Polyoxyethylene oleate
Potassium caprate
Potassi<811 caprylate
Potassium dehydroabletate
Potassium laurate [KOOCCllH2])
Potassium lDyristate
Potassium oleate [C17H]]COOK)
TABLE B-15
Consumptiont
4.9 x 106 kgs (79)
(total)
(Continued)
Use
Synthetic detergent
Emulsifier; dispersant for soluble oils. cleaning compounds and other
composi tions
Solvent and aoftening agent; lacquers; organic aynthesis
Alkyd resins; wetting agent; soaps; detergents; cosmetics; insecti-
cides; food additive
.....
Soapa; cosmetics; synthesis of esters for flavors and perfumes; com-'
ponent of food-grade additives
'"
Manufacture of metallic palmitates; soaps; lube oils; waterproofing;
food grade additives; cosmetic formulationa; cleansing crealD;
intermediate for manufacture of esters
"
~t
.. .
. r~~ .
~'\
Emulsifying agent; base for liquid soaps and shampoos
Textile soaps; emulsifying agent
(Continued)
-------
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Solution Modifier/Polymerization Aid
EMULSIFIERS (Continued)
Potassium palmitate
Potassium sodium tsrtrate
(KNaC4H406"4HZO)
Potassium atearate (C17H3SCOOK)
Sodium capryl aulfonate
Sodium cetyl sulfate
Sodium decyl aulfate
Sodium decyl sulfonate
a-
U'!
tV
Sodium dioctyl sulfosuccinate
(CSH170OCCHZCH(S03Na)COOCSHI7)
Sodium dodecyl diphenyl ether
disulfonate
Sodium dodecyl sulfate (See Sodium
lsuryl sulfate)
Sodium dodecyl sulfonate
Sodium hexadecyl sulfate
Sodium lauryl benzene aulfonate
Sodium lauryl sulfate
(NaC1ZHZSS04). (Sodium dodecyl
sulfate)
:
Sodium naphthalene sulfonate
(C12H7S0]Na)
Sodium oleate (Cl]B3JCOONa)
Sodium resinate (Sodium abietate),
(ClgHZgCOONa)
TABLE B-15
Consumptiont
9.1 x 106 kgs (79)
(total)
(Continued)
Use
Sequestrant and general-purpose food additive; baking powders; medicine
(cathartic); component for Fehling's solution
Base for textile softeners
""If'
Food additive (processing aid in sugar industry, stabilizer for hydro-
philic colloids); wetting agent; dispersant; emulsifier
~, ,
1."
'h
\.1
'h
~\
Wetting agent in textiles; detergent in toothpaste; food additive and
surfactant
Organic preparations; liquefying agent in animal glue preparations;
naphthols
Ore 'flotation; waterproofing textiles; emusifier of oil/water systems;
pois index soap
Medicine; soap making; paper coating
(Continued)
-------
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Solution Modifier/Polymerization Aid
EMULSIFIERS (Continued)
Sodium atearate (NaOOCCI7U35)
. Sodium tetradecyl aulfonate
Stearic acid (CU3(CH2)16COOHI
Stearyl trimethyl ammonium chloride
Sulfooated caater oil (Turkey Red
0111
Triton X-IOO
0\
VI
!,.oJ
Triton X-200
FEED STREAK DESSlCANTS
Alumina (See Protective Colloidal
Aluminum alky la
Calcium hydride [CaU2I
':
I
Calcium aulfate (anhydroua)
(Cas041
'.
Cauatic Soda (aolid) [See Baaea
(Sodium hydroxide»)
TABLE B-15
Conaumptiont
4.3 x 107 kga (75)
(total)
(C
-------
Solution Hodifier/Polyaerization Aid
FEED STREAK DESSICANTS (Continued)
Copper, (metallic) (Cu)
Holecular seive
Silica gel
Sodium, (metal) (Ha)
0-
VI
~
Sodium hydroxide on asbestos (See
Bases)
INERT GASES
Carbon dioxide (C02)
Nitrogen (N2)
TABLE B-15
Consumptiont
3.4 x 109 kgs (82)
(total)
1.6 x 1010 kgs (82)
(total)
(Continued)
Use
Electrical wiring; switches. plumbing. heating. roofing, building con-
struction; chemical and pharmaceutical machinery; alloys; electroplated
protective coatings and undercoats for nickel, chromium, zinc, etc.;
cooking utensils; corrosion resistant piping; insecticides; catalysts;
antifouling paints; thermal and electrical composites
Drying gases and liquids; selective molecular separations; ion
exchange; catalyst; chemical carriers; in gas chromatography; in
petroleUm to remove paraffins
Dehumidifying and dehydrating agent; air conditioning; drying of com-
pressed air and other gases and liquids; recovery of natural gasoline
from natural gas; bleaching of petroleum oils; catalyst and catalyst
carrier; chromatography; anticaking agent in cosmetics and pharmaceu~
ticals; in waxes to prevent slipping
Tetraethyl and tetramethyl lead; titanium reduJ~~qn; sodium peroxide;
sodium hydrides; polymerization catalyst for sf.nthetic rubber; labora-
tory reagent; coolant in nuclear reactors; ele~tricipower cable
(encased in polyethylene); non-glare lighting for hIghways; radioactive
forms in tracer studies and medicine i' I,
;, y,
II. ' \
.. ~I ;,
; ".( I
I' ~ ~ I
Refrigeration; carbonated beverages; aerosol\prop,IJant; chemical
intermediate; low temperature testing; fire ert(n~~shing; inert atmos-
pheres; municipal waste treatment; medicine; 'enrichment of air in
greenhouses; fracturing and acidizing oil wells~"~~ing; miscellaneous
pressure source; hardening of foundry molds and corfs; shielding gas
for welding; cloud seeding. moderator in some nuclear reactors; immo-
bilizstion for humane animal killings; special lasers; blowing agent
Production of ammonia, acrylonitrile, cyanamide. cyanides, nitrides;
inert gas for purging. blanketing and exerting pressure; electric and
electronic industries; in-transit food refrigeration and freeze drying;
pressurizing liquid propellants; quick-freezing foods; chilling in
aluminum foundries; bright annealing of steel; cryogenic preservation;
inert pressuring and blanketing gas in missiles; food antioxidant;
source of pressure in oil veils; inflating tires
(Continued)
-------
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Solution Modifier/Polymerization Aid
PROTECTIVE COLLOIDS
Acrylic acid-Z-ethylhexyl- acrylate
copolymer
Alumina [AIZO)I
Barium peraulfate
[BaSZOB" 48Z01
Barium phosphate [Ba81'041
Barium sulfate [BaS041
(;\
V1
V1
Calcium persulfate
Calcium phosphate [Ca)(1'04)zl
Carboxymethyl cellulose
Clay [KaoUnl, [AIZ0)SiOzl
Ethyl cellulose
TABLE B-15
Consumptiont
4.5 x 109 kgs-(75)
( total)
1.5 x 108 kgs (81)
(in plastics)
(Continued)
Use
Glass. ceramics. iron-free aluminum and aluminum salts; manufacture of
activated alumina; base for organic lakes; flame retardant; rubber
reinforcing agent; paper coating; filler; cosmetics; desiccant; abra-
sive; electrical insulstion; dental cements; artificial gems; chromato-
graphy; refractory; cstalyst
Weighting mud in oil drilling; paper coatings; paints; filler and
delustrant for textiles, rubber, linoleum, oilcloth, plastics and
lithographic ink; base for lake colors; X-ray photography; opaque
medium for gastrointestinsl radiogrsphy; in battery plate expanders
Ceramics; calcium acid phosphate; phosphorus and phosphoric acid;
polishing powder; cattle foods; clarifying sugar syrups; medicine; mor-
dant (dyeing textiles snd Turkey Red); fertilizers; dentrifices;
stabilizer for plastics; in mest tenderizers; in foods as anticsking
agent, buffer, nutrient supplement; can remove strontium-90 from milk
Detergents, soaps, food products (especially dietetic foods and ice
cresm, where it acts as s binder, thickener, suspending agent, and
emulsion stabilizer); textile manufacturing (sizing); coating paper and
paperboard to lower porosity; drilling muds; emulsion paints; protec-
tive colloid; pharmaceuticals; cosmetics
Ceramic products; refractories; colloidal suspensions; oil-well drill-
ing fluids; filler for rubber and plastics products; films; paper coat-
ings; decolorizing oils; temporary molds; filtration; carrier in insec-
ticidal sprays, catalyst support. cosmetics; cement, source of alumina
Hot melt adhesives and coatings for cables, paper, textiles; etc.;
extrusion wire insulation; protective coatings; pigment-grinding bases;
toughening agent for plastics; printing inks; molding powders;
proximity fuses; vitamin preparations; casings _for rocket propellants;
food and feed additive
(Continued)
-------
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Solution Hodifier/Polymerization Aid
PROTECTIVE COLLOIDS (Continued)
Gelstin
Cum accscia
Hydroxyapatite
(CalO(P04)6(OH)2)
.. ~
Hydroxyethyl cellulose (Cellosize)
Uydroxypropyl cellulose
C\
VI
C\
Hydroxypropyl methyl cellulose
Hsgnesium carbonate (HgCO))
Hagnesium oxide [HgO)
..
..
"
Hagnesium persulfate
Hagnesium phosphate
(Hg»)(P04)2.4HzO)
Hagnesium silicste (HgSiO))
TABLE B-15
Consumptiont
1.1 x 108 kgs (75)
( total)
(Continued)
[,
! '
i
Use
Photogrsphic filII; lithography; sizing; plastic compounds; textile and
paper adhesives; cements; cspsules for medicinals; matches; light
filters; clarifying agent; desserts, jellies, etc.; culture medium for
bscteria; blood plasma volume expander; microencapsulation
Thickener and suspending agent; stabilizer for vinyl polymerization;
retards evaporation of water in cements, mortars snd concrete; binder
in ceramic glazes; f11ms and sheeting ,
Emulsifier; film former; protective colloid; stsbilizer; suspending
agent; thickener; food additive
Hsgnesium salts; heat insulation and refractory; rubber reinforcing
agent; inks; glass; pharmaceuticals, dentrifices and cosmetics; free-
running table salts; mineral waters; filtering medium; in foods as
alkali, drying agent, color retention agent, anticaking agent and
carrier; antaci~and cathartic
Refractories; polycrystalline ceramic for aircraft windshields; elec-
trical insulation; pharmaceuticals and cosmetics; inorganic rubber
accelerator; oxychloride and oxysulfate cements; paper manufscture;
fertilizers; removal of sulfur dioxide from stack gases; adsorption and
catalysis; semiconductors; pharmaceuticals; feed and food additives;
wallbosrd; petroleum additives; casein glue; laxative; wsste treatment
Dentrifice polishing agent; pharmaceutical antacid; adsorbent;
stabilizer for plastics; food additive and supplement
Rubber filler; ceramics; glass; refractories; adsorbent for crude oil
spills; manufacture of permanently dry resins and resinous composi-
tions; ,paints, varnishes and paper (f11ler); animal and vegetable 011
bleaching agent; odor absorbent; filter medium; catalyst and catalyst
carrier; anticaking agent in foods
(Continued)
-------
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Solution Hodifier/Polymerization Aid
PROTECTIVE COLLOIDS.(Continued)
Hethyl cellulose (Hethocell
.1
Hethyl(hydroxypropyl)cellulose
"
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Pectin
Polyacrylamide resin
( -CH:zCH0NB2- >xl
Polyvinyl alcohol (-CH:zCH0H-)xl
.j
Polyvinyl pyrrolidone
(-C6HgN°-)xl
0-
'JI
-...J
Potassium persulfate (K2S~81
I
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Sodium polyacrylate
Starch (-C605HIO-)x(
Sulfonated polystyrene
Talc (Hg3Si4010(OH)21 or
(3HgO'4Si02'H~(
Zinc oxide (ZnO(
TABLE B-15
Consumptiont
5.6 x 108 kga (75)
(total)
3.8 x 103 kga (75)
(total)
1.5 x 108 kgs (82)
(total) .
(Continued)
I,; Ii
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. II
l'
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I '
Protective colloid in water-baaed paints to prevint~locculstion of
pigment; film and sheeting; binder in cersmic g,lazes,; lesther tanning,
dispersing. thickening. and sizing agent; sdhe~ive,\,.'f, od sdditive '
, '{Ii
"'1.Ut
Jellies, foods, cosmetics, drugs; protective cotloJ~~, emulsifying
sgents; dehydrating sgents I ,
,-:,1"
Thickening agent; suspending sgent; production of ura~ium: sdditive to
sdhesi ves t; 'JI
Heny different products, see IPPEU Chapte~s 10 snd lOa
Pharmaceuticala; blood plasma expander; cast films; adherent to glass,
metals and plastics; complexing agent; detoxification of chemicals such
as dyes, iodine, phenol, and poisonoua drugs; tableting: photographic
emulsiona; cosmetics (hair spray, shampoo, hand cream, skin lotion);
dentrifices; dyestripping; textile finishes; protective colloid; deter-
gents: adhesives; beer and wine clsrificstion
81eaching; oxidizing agent; reducing agent for photography; antiseptic;
soap manufacture; analytical reagent; polymerization promotor; pharma-
ceuticala; modification of starch; flour maturing agent; deaizing of
textiles '
Adheaive: machine-coated paper; textile filler and sizing agent: beater
additive in papermaking; gelling agent and thickener in foods; oil-well
drilling fluids; filler in baking powders; fsbric stiffener in launder-
ing; urea-formaldehyde resin adhesive for particleboard and fiberboard;
explosives; dextrin; chelating and sequestering agent in foods; indica-
tor in analytical chemistry; anticaking agent in sugar; face powders;
abherent and mold relesse agent; polymer base,
Ceramica; cosmetics snd pharmaceuticals: filler and pi~ent in rubber,
paints, soap. putty, plaster, oilcloth; abherent; dusting agent;
lubricant; paper; slate pencils and crayons; electrical insulation:
insecticide diluent; refractories; filtration
Diffusing.pigment; accelerator; activator; reinforcing agent;
ointments; pigment and mold-growth inhibitor in paints; ceramics; floor
tile; glass; zinc salts; feed additive; dietary supplement; seed
treatment. ~osmet1c8; semiconductor; photoconductor; dental cement;
flame retardant; antiseptic
(Continued)
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,
,
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Solution Modifier/Polymerization Aid
SOLVENTS
Acetic acid [See Chain Transfer
Agents)
Acetone [See Chain Transfer Agents)
Amyl acetate (CH)COOCSHll)
i
,
:
n-Amyl alcohol [CsHllOH)
Benzene (See Chain Transfer Agents)
Benzyl alcohol [C6RSCHZOH)
0\
U1
00
Bromobenzene [C~SBr)
n-Butane [C4HlO), (See Chain
Transfer Agents)
I-Butanol [CH)(CH2>2CH;zOH)
2-Butanol [sec-Butyl Alcohol).
(CH)CH2CHOHCH))
2-Butanone [Methyl ethyl ketone).
[CH)CH2COCH) )
TABLE B-15
Consumptiont
).S x 108 kgs (19)
(total)
I,; Ii
II
(Continued)
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Solvent for lacquers and paints; extraction of penicillin; photographic
film; leather polishes; nail polish; warning odor; flavoring agent;
printing and finishing fabrics; solvent for phosphors in fluorescent
lamps
Raw material for pharmaceutical preparations; organic synthesis;
solvent
~rfumes snd flavors; photographic developer for color movie films;
dyeing nylon filament; textiles and sheet plastic; solvent for dye-
stuffs, cellulose esters, casein, waxes, etc.; heat sealing polyethy-
lene filma; intermediate for benzyl esters and ethers; local
snesthetic; cosmetics, ointments, emulsions; ball point pen inks;
stencil inks; embedding material in microscopy
Solvent; motor fuels; top-cylinder compounds; crystallizing solvent;
organic synthesis
Prepsration of esters, especially butyl acetate and glycol ethers;
fats, waxes and coatings; plasticizers; dyeing assistant; hydraulic
fluids; detergent for 8ulations; dehydrating agent (by azeotropic
distillation); intermediate for pharmaceuticals and plasticizers;
"butylated" melamine resins; glycol ethers; butyl acrylate; flsvoring
ingredient
Preparstion of methyl ethyl ketone; solvent; organic synthesis of
flotation agents, flavors, perfumes, dyestuffs .and wetting agents;
industrial cleansers; paint removers; hydraulic brake fluids; polishes
Solvent in fabric coating, adhesives, varnishes. lacquers, pharmaceu-
ticals, cosmetics, ink, and hardwood pulping; manufscture of tere-
phthalic acid; lube oil dewaxing by solvent extraction
(Continued)
'"
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Solution Modifier/Polymerization Aid
SOLVENTS (Continued)
t-Butyl alcohol (CH3)3COH)
t-Butyl benzene (CloH14)
Carbon tetrachloride (See Chain
Transfer Agents)
Chlorobenzene (See Chain Transfer
Agents)
Chloroform (See Chain Transfer
Agents)
Cumene (Isopropyl benzene), (See
Chain Transfer Agents)
a-
VO
\0
Cyclohezane (See Chain Transfer
Agents)
Cyclohexanone (C&81oP)
n-Decane (CH3(CH2)SCH3)
o-Dichlorobenzene (C6H4C12)
l,2-Dichloroethane (ClCHzCHzCl)
Diesel fuel, hydrogenated
TABLE B-15
Consumptiont
4.0 x 108 kgs (79)
(total)
2.6 x 107 kgs (79)
(total)
4.5 x 109 kgs (79)
(total)
(Continued)
Use
Alcohol denaturant; solvent for pharmaceuticals; dehydration agent;
perfumery; chemical intermediate in perfumes, flavors, resins, chlori-
nated derivatives; octane improver in gasoline
Organic synthesis; polymerization solvent; polymer linking agent
Organic synthesia, particularly adipic acid and caprolactam; polyvinyl
chloride and its copolymers, and methacrylate ester polymers; wood
stains; paint and varnish removera; spot removers; degreasing of
metals; polishes; leveling agent in dyeing and delustering silk; lube
oil additive; general solvent
Organic synthesis; solvent; standardized hydrocarbon; jet fuel research
Hanufacture of 3,4-dichloraniline; solvent for a wide range of organic
materials and for oxides of nonferrous metals; solvent carrier in pro-
duction of toluene diisocyanate; dye manufacture; fumigant and insecti-
cide; degreasing hides and wool; metal polishes; industrial odor
control
Vinyl chloride intermediate (Wulff process); solvent; lead scavenger in
antiknock gasoline; paint, varnish and finish removers; metal
degreasing; soaps and scouring compounds; wetting and penetrating
agents; organic synthesis of trichloroethylene, perchloroethylene and
methyl chloroform; ore flotation
(Continued)
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/
Solution Modifier/Polymerization Aid
~ (Continued)
Dimethyl acetamide
[CH)CON(CH)zl
Dimethyl formamide [HCON(CH)>21
Dimethyl sulfoxide (CH)ZSOJ
p-Dioxane [?CHzCHZOCH~HZ J
(7\
(7\
o
Dodecane (CH)(CHZ)loCH)J
Ethanol [CZHSOHI
,
"
Ethylene dichloride (See
l,Z-DichloroethaneJ
Z-Ethoxyethyl acetate
[CH )COzCHzCHZOCHzCH) J
Ethyl acetate [CH)COOCZHSJ
Ethylbenzene [C6"sCzHsl
TABLE B-15
Consumptiont
4.S x 108 kgs (8Z)
(total)
7.7 x 107 kgs (7S)
(total)
(Continued)
Use.
Solvent for plastics, resins, gums and electrolytes; intermediate;
catalyst; paint remover; high purity solvent for crystallization and
purification
Solvent for vinyl resins and acetylene, butadiene, and acid gases;
catalyst in carboxylation reactions; organic synthesis
Solvent for polymerization and cyanide reactions; analytical reagent;
spinning polyacrylonitrile and other aynthetic fibers; industrial
cleaners, pesticidea, paint stripping; hydraulic fluids; preservation
of cells at low temperatures; diffusion of drugs, etc. into blood-
stream by topical application; medicine; plant pathology and nutrition;
pharmaceutical products
Solvent for cellulosics and wide range of organic products; lacquers;
paints; varnia~es; paint and varnish removers; wetting and dispersing
agent in textile processing, dye baths, stain and printing composi-
tions; cleaning and detergent preparationa; cements; cosmetics; deodor-
ants; fumigants; emulsions; polishings compositions; stabilizer for
chlorinated aolvents; scintillation counter
Solvent; organic synthesis; distillation chaser; jet fuel reaearch
t.
Solvent for resins, fats, oils, fatty acida, hydrocarbons, alkali
hydroxidea; extractive medium; manufacture of intermediates, organic
derivatives (especially acetaldehyde), dyes, synthetic drugs, eatera,
elastomers, detergents, cleaning solutions, surface coatings, cosme-
tics, pharmaceuticals, explosives, antifreeze; beverages; antisepsis;
medicine; gasoline additive; yeast growth medium
General solvent in coatings and plastics; organic synthesis; smoke leas
powders; pharmaceuticals; artificial fruit essencea; photographic
films and platea; artificial silk; synthetic flavor
Intermediate in production of styrene; solvent; fuel component;
manufacture of cellulose acetate; solvent for mixed xylenes
(Continued)
-------
Solution Modifier/Polymerization Aid
SOLVENTS (COntinued)
Furfuryl alcohol [C4U3OCHZOH)
or [PCH:CHCH:~CHzOU)
Heptane [CU3(CHZ)SCH3)
Uexane [CH3(CHZ)4CH3)
,
-,
Isobutane [See Chain Transfer
Agents)
Isobutyl alcohnl [See Chain Transfer
Agents)
-,\
- -
0-
0-
......
Isobutyric acid [(CH3)ZCHOOU)
laooctane
[(CH3)3CCUZCH(CH3)Z)
Isopentane (CH3)ZCHCUZCU3)
Isopropyl alcohol (See Chain
Transfer Agents)
Isopropyl benzene (See Chain
Transfer Agents (Cumene»)
iCe rosene
-,
Methanol [See Chain Transfer Agents'
Methyl acetate [See Chain Transfer
Agents'
-,
.!
'{
.!
TABLE B-15
Consumptiont
1.7 x 108 kgs (79)
(total)
7.Z x 108 kgs (7Z)
(total)
(Continued)
Use
Wetting agent; furan polymers; corrosion-resistant aealants and
cementa, foundry cores; modified ures-formaldehyde polymers; penetrant;
solvent for dyes and resins; flsvoring; propellant
Stsndard for octa~e rating determinations; snesthetic; solvent; organic
synthesis; preparstion of lsboratory reagents
Solvent, especially for vegetable oils, low temperature thermometers;
calibrations; polymerization reaction medium; paint diluent; alcohol
denaturant; determination of refractive index of materials
Manufacture of esters for solvents, flavors and perfume bases; disin-
fecting agent; varnish; deliming hides; tanning sgent
Organic synthesis; solvent; motor fuel; used with normal heptane to
prepare standard mixtures to determine antiknock property of gasoline
Solvent; manufacture of chlorinated ,nd alcohol derivatives; blowing
agent for polystrene; antiknock gasoline additive
. ~ -r"
Rocket and jet engine fuel; domestic heating; solvent; insecticidal
sprays; diesel an& tractor fuel
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(Continued)
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Solution Hodifier/Polymerization Aid
SOLVENTS (Continued)
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Hethylene chloride (CH2CI2J
Hethyl ethyl ketone (See 2-Butanone)
Hethyl isobutyl ketone
( (CH3)2CHCH2COCH3)
Hethyl isobutyrste
Hineral oil
Naphtha
a-
a-
N
Nitrobenzene (C6"sN02)
Pentsne (CH3(CH2)jCH3)
3-Pentanone (Diethyl ketone),
(C2HSCOC2HSJ
2-Propanol (Isopropyl alcohol), (See
Chain Trsosfer Agent)
1
n-Propyl acetate (C3HJOOCCH3)
pyridine (~(CH)~N)
TABLE B-15
Consumptiont
2.3 x 108 kgs (7S)
(total)
4.3 x 108 kgs (79)
(total)
3.3 x 107 kgs (79)
(total)
(Continued)
Use
Paint removers; propellant for aerosol aprays; solvent degreasing;
plastics processing; blowing sgent in f0888; aolvent extrsction;
refrigerant; fire extinquisher composltions; solvent for photogrsphic
film, synthetic fibera and cellulose acetate
Solvent for paints, varnishes, nitrocellulose lacquers; manufscture of
methyl amyl alcohol; extraction processes, including extrsction of
uranium from fission products; organic synthesis; denatursnt for
alcohol
Source of gasoline, special naphthas, petroleum chemicals, especially
ethylene; solvent; xylene; cumene; nitrated, for incorporation in
dynamite
Manufacture of aniline; solvent for cellulose ethers; modifying ester-
fication of cellulose acetate; ingredient in metal polishes and shoe
polishes; manufacture of benzidine, quinoline, azobenzene, etc.
Artificial ice manufacture; low temperature thermometers; solvent
extraction proceases; blowing agent in plastics; pesticide;
propellant; refrigerant; fuel; cleaning and degreasing
",otrf'
Hedicine; organic synthesis
,I
"h,.
Flavoring agents; perfumery; solvent for nitrocellulose and other'
cellulose derivatives; natural and synthetic resins; lacquers;
plastics; organic synthesis; laboratory reagent
I '
. '~t
Synthesis of vitamins, drugs, dyes, explosives and disinfectants;
solvent; waterproofing; rubber chemicals; denaturant for alcohol and
antifreeze mixtures; dyeing asa1stant in textiles; fungicides.;
analytical chemistry
. I
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(Continued)
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Solution Modifier/Polymerization Aid
SOLVENTS (Continued)
l,l,2,2-Tetrafluorodichloroethane
[CCIF2CCIF2)' (Freon 114)
Tetrahydrofuran
[~HzCHzCHzCH~)
Toluene (See Chain Transfer Agents)
Triethylamine (See Chain Transfer
Agents)
2,2,4-Trimethylpentane [See
Iaooctane)
(1\
C\
UJ
Water
Xylene [C&"4(CH3)2)
THICKENERS
Glycerol [CJH5(OH)])
Glycola
Polyglycols
TABLE B-15
Conaumptiont
5.4 x 107 tgs (79)
( total)
2.4 x 109 kgs (82)
(total)
(Continued)
Use
Solvent; fire extinguiahers; refrigerant and air conditioner; aerosol
propellsnts; blowing agent; dielectric fluid
Solvent for natural and synthetic resins, psrticularly vinyls; in top-
costing solutions, polymer costing, cellophane, protective coatings,
adhesives, magnetic tapes, printing inks, etc.; Grignard reactions,
lithium aluminum hydride reductions and polymerizstions; chemical
intermediate and monomer; solvent for histological techniques
Aviation gasoline; protective coatings; solvent for alkyd resins,
lacquers, enamels, rubber cements; synthesis of organic chemicals
Alkyd r~sins; explosives; ester gums; pharmaceuticals; perfumery;
plasticizer for regenerated cellulose; cosmetics; food stuffs; condi-
tioning tobacco; liqueurs; solvent; printer's ink rolls; polyurethane
polyols; emulsifying agent; rubber stamp and copying inks; binder for
cements and mixes; paper coatings and finishes; special soaps;
lubricant and softener; bacteriostat; penetrant; hydraulic fluid;
humectant
tAnnual Consumption is presented parenthetically for the most recent year available.
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TABLE B-16. ULTRAVIOLET STABILIZERS
CONSUMPTION AND OTHER USES
Ultraviolet Stabilizers
Coosuaptloo t
Use
BI!NZOPHENONES
i
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4-Alkoxy-2-bydroxybeozopheoooe
(Uvioul 410)
4-Butozy-2,2'-dihydrozybeozophe-
nooe (Cyasorb UV287)
, .
.)
.1
S-chloro-2-bydrozybeozophenone
(C~SCOC~s08Cl )
Lil!ht absorber
Cyasorb UV 2126 (Polymer of 4-(2-
Acryloylozyethozy)-2-bydrozybenzo-
phenone)
UVabsorber for plastics in automotive, greenhouses, home
siding, and solar applications
4-Decylozy-2-bydrozybenzophenone
.,
~. ~
2,4-Dibeozoyl resorciool (DBR)
Light absorber
2,4-Dihydrozybenzophenone
(C6HsCOC6H3(OH)2)
Ultraviolet absorber in polymers
. j
0\
0\
.t-
:..
2,2'-Dihydrozy-4,4'-dimethozy-
benzophenone (Uvioul D-49)
2,2'-Dihydrozy-4-methoxybeozophe-
oooe (Cyasorb UV 24)
2,2'-Dihydrozy-4(octozy)benzo-
pheoone (Cyasorb UV 314)
Disodium 2,2'-dihydrozy-4,4'-di-
methozy-S,S'-disulfobeozophenooe
(Uvioul DS-49)
4-Dodec y loxy- 2 -byd roxybeozo phenone.
(Rylex D)
Ultraviolet light inhibitor in plastics
4(Heptylozy)-2-bydroxybeozophenone
(Uo1stat 247)
(Continued) .
..
-------
j
j
;
I
1
1
!
1
1
TABLE B-16
(Continued)
Ultraviolet Stabilizers
ConsUllptlon t
Use
BI!NZOPBBNONES (Contlnued)
2-Hydroxy-4-acryloxyethoxybenzo-
phenone
"'''f'
2-Hydroxy-4(-2-ethylhexoyl)benzo-
phenone
~, ,
2-Hydroxy-4-isooctoxybenzophenone
.,' ,
I !I
i ~t
2-Hydroxy-4-methoxybenzophenone
(Uvinul "40), (Cyasorb UV9)
I
, '!~ .
~'dl
2-Hydroxy-4-methoxy-S-methylbenzo-
phenone (Unistat 2211)
2-Hydroxy-S-methoxybenzophenone
0-
0-
VI
2-Hydroxy-l-methoxy-S-aulfobenzo-
phenone (Uvinul "S-40)
2-Hydroxy-4-methoxy-S-aulfobenzo-
phenone (Cyasorb UV-2841
2-Hydroxy-4-n-octyloxybenzophenone
ICyasorb UV S31)
Hark lS3S
Permyl Bloo (Substituted phenone)
Besyn 78-6121 (low molecular weight
alkyl methacrylate-aubstituted
benzophenonel
2,2',4,4'-Tetrahydroxybenzophenone
(Uvinul D-SO)
Uvinul 490 (mixture of 2,2'-Dihy-
droxy-4,4'-dimethoxybenzophenone)
(Continued)
-------
.~. )'
. .,y.
..ii'
,
j
j
j
j
-1
-:1
TABLE B-16
(Continued)
"j
i
I
1
J
I
i
!
I
i.
f" ,
,
:-"1"
UltravIolet Stabilizera
Conawaptiont
Uae
".
~,,~ .
BENZOTlUAZOLES
2(3'-t-Butyl-2'-hydroxy-5'-methyl-
phenyl)-5-chlorobenzotrlazole
(TInuvln 326)
II \
: .'~t
"j
2(3',5'-DI-t-butyl-2'-hydroxy-
phenyl)-5-chlorobenzotrlazole
(Tinuvin 327)
,'"\..'
~~
" "
; ~,
2(2'-Hydroxy-3',5-dI-t-amyl-
phenyl)benzotriazole (TInuvln 328(
2(2'-Hydroxy-3',5'-dl-t-butyl-
phenyl)benzotriazole (TInuvln 320)
2(2'-Hydroxy-5'-aethylphenyl)-
benzotriazole (TInuvln P)
0\
0\
0\
2(2'-Hydroxy-5-t-octylphenyl)-
benzotriazole
Hark 446
NICKEL ORGANICS
r".
BIa(2,2'-thlobIa(4-t-octylpheny-
lato»nlcltel (See NIckel
bIa(octylphenyl sulfIde»)
Hark 1306A
Negopex A
NIckel bIs(0-ethyl(3,5-dI-t-butyl-
4-hydroxybenzyl»phosphonste
(Irg&8tsb 2002)
NIckel bIs(octylphenyl sulfIde)
(Ferro AM-IOI snd AM-I05)
(Continued)
-------
TABLE B-16
Ultraviolet Stabilizera
RICKEL ORGANICS (Continued)
,
-j
1
I
Rickel dibutyldithiocarbamate
(Ri(SC(S)R(C4H9)2)2)
Rickel diisobutyldithiocarbamate
(ISO Butyl Riclste)
Rickel dimethyldithiocarbamate
(Hethyl Riclate)
10% Rickel Hex-Cem
10071 PI! HB
Sanduvor RPO (Phenylmethyl-
decsnoyl pyrazolate-Rickel)
0\
0\
......
(2,2'-Thiobis(4-t-octylpheno-
lato»-n-butylsmine nickel (Cyasorb
UV 1084(
UV Chek AH-205
HISCELLANI!OUS, ACRYLATES
Butyl 2-cyano-3-methyl-3-(p-meth-
oxyphenyl)acrylate (UV Absorber
317)
R-(S-Cyano-S-carbomethoxyvinyl)-
2-methylindoline (UV Absorber 340(
Ethyl 2-cyano-3,3-diphenylacrylate
(Uvinul R-35)
2-Ethylhexyl 2-cyano-3,3-diphenyl-
acrylate (Uvinul R-539)
Hethyl-2-carbomethoxy-3-(p-meth-
oxyphenyl)acrylate (Cyasorb
UV-1988)
.1
(Continued)
ConsWlptlont
Uae
Antioxidant for rubbers
(Continued)
-------
.j
Ultraviolet Stabilizers
MISCELLANEOUS, ACRYLATES
(Contlnued)
Methyl 2-cyano-3-methyl-3-(p-meth-
oxyphenyl)acrylste [UV Absorber
31S)
MISCELLANEOUS, SALICYLATES
p-t-Butyl phenyl salicylate
10316 COP MP [Proprietary)
Dipropylene glycol salicylate
[C3H6(OOCC6H40H)OC3H OH)
2-Ethylhexyl salicylate
0\
0\
00
p-OCtylphenyl salicylate
[C6H40HCOOC6H4CSHl7 )
[Inhibitor OPS)
Phenyl salicylste
[C6H40HCOOC6H5)
p-(I,I,3,3-Tetramethylbutyl)phenyl
sslicylate [See Octylphenyl
sslicylate)
j
OTHER MISCBLLANEOUS AND PROPRIETARY
..,
AST-IOOl
Barium metaborate, modified
Bis(2,2,6,6-tetrsmethyl-4-piperi-
dinoxy)sebacate
Carbon black
. ,
J
I
"
..1
i
.,
TABLE B-16
Consumptiont
(Continued)
Use
Light absorber
Ultraviolet light-screening agents; protective coating;
plssticizer
Prevents photoxidation of polyolefins
Medicine; preservative; UV sbsorber in plastics, waxes,
polishes, suntan oils; laboratory reagent
Reinforcing sgent, pigment for cements, ceramic ware, mortar,
inks, linoleum, aurface. coatIngs, crayons, polishes, carbon
paper, soap, etc.; in insulating compositions; liquid-air
explosives; matches; fertilizers; furnace lutes; lubricsting
compositiona; carbon brushea
i..
I
t
,
! :
(Continued)
-------
",
Ultraviolet Stabilizers
OTHER HISCELLANEOUS AND PROPRIETARY
(Continued)
Chimassorb 944 (Hindered amine)
C-HDPE-2764 (Hindered amine)
.,
j
j
C-Ppa-8004 (Hindered amine)
C-PPR-800S (Hindered amine)
Copper iodide
2.4-Dibeozoyl resorcinol
3.S-Di-t-butyl-p-hydroxybenzoic
acid
CT\
CT\
\0
2.4-Di-t-butylphenyl-3.S-di-t-
butyl-4-hydroxybenzoste (UV Chek
AH-340)
2. 4-Di-t-butylphenyl-3.S-di-t-
butyl-4-hydroxybenzoate
Dimethyl-2-(4-methozybenzylidene)
malonate
Good-rite UV 3034 (Hindered amine)
N-Hezsdecyl-3.S-di-t-butyl-4-
hydrozybenzoate
Hezamethyl phosphoric triamide
(Inhibitor HPr)
Hostavin N20
2-(Z-Hydrozy-4-methoxybenzoyl)
benzoic scid (Cyasorb UV 207)
Hanganese iodide
Parabol1x-IOO
TABLE B-16
Consumptiont
i.
;~.
(Continued)
Use
Feed additive; in table salt as source of dietary iodide
"
UV inhi~itor for PVC; chemosterilant for insects; promoting
stereospecific reactions; specialty solvent
. ,
,
(Continued)
-------
I
i
1
Ultraviolet Stabilizera
OTHER MISCELLANEOUS AND PROPRIETARY
(Continued)
PDI-0199 (benzophenone/hindered
amine mixture I
10328 PH M8, 10359 PH MB
40375 PP MP (Hindered amine I
Resorcinol monobenzoate
(C&'!5COOC&'!40HI
Ssnduvor EPU (oxalsnitidel
Ssnduvor VSU (oxalsnilidel
Tinuvin 144 (stearically hindered
sminel
.'
0\
-....j
o
Tinuvin 770 (stesrically hindered
amine I
Tinuvin 662 (hindered aminel
J
I
!
,j
" J
'. j
Titanium dioxide
UV-chek 54lA
UV-check AM-595
. '
Vanstay L (phosphste-type
stabllizerl
Zinc oxide
TABLE B-16
Consumptiont
2.0 x 108 kgs (82)
(in plastics)
(Continued)
Use
Noncoloring ultraviolet inhibitor for plastics; color
stabilizer in cosmetics
53% in paints, vsrnishes, lacquers; 21% in paper; 10% in
plastics; 3% in elastomers; 2.5% in ceramics; 2% in floor
covering; 2% in printing inks; 1% in coated fabrics and
textiles; 1% in roofing granules; 4.5% for other pigments
Diffusing pigment; accelerator; activstor; reinforcing agent;
ointments; pigment and mold-growth inhibitor in paints;
ceramics; floor tile; glass; zinc salts; feed additive;
dietary supplement; seed treatment; cosmetics; semiconductor;
photoconductor
tAnnual Consumption is presented parenthetically for the most recent year avsilable.
. ..".
- .,
.
.1
-------
APPENDIX C.
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS FOR PLASTICS ADDITIVES
Antioxidant
PHENOLICS
1.2-Bis(3,S-di-t-butyl-4-hydroxyhydro-
cinna~oyl)hydrazlne (Ir84nO~ "0 1024)
2.6-Bis(1-Qethylheptadecyl)-p-cresol
4-«4.6-Bis(octylthlo)-s-triazin-2-yl)-
a~ino)-2,6-di-t-butylphenol
8isphenol A (CH3)2C(C6H40H)21
0\
.....
......
Butylated Bisphenol A (Vanox 10041
Butylated hydroxyanlsole (BHAI,
(CH3) 3CC6H30H(OCH3) I
Butylated hydroxy toluene (BHTI. (DBPCI.
(Dl-t-butyl-p-cresoll
Butylated octylated phenol
BlJtylat~d re.actlol1 p['ofllJct of p-crdQolo'll1d
dicyclopentadiene
Butylated styren4ted cresols
4. 4 '-Butylidenebis(6-t-butyl-m-cresol)
(Santowhite powderl .
Cyclohexylldenebls(2-cyclohexylphenol)
2,6-01-t-butyl di~ethyl amlno-p-cresol
(Ethanox 703 I.
(C4H9)2C6H2OH(CH2N(CH3)2»)
2,6-0l-t-butyl-4-ethylphenol
TABLE C-l.
Toxicity
Oral. rat
LDSO:4040 mg/kg
Moderate
Oral, rat
LDw:2200 mg/kg
Oral, mouse
LOSO: 1040 mg/kg
ANTIOXIDANTS
Concern
Teratogen
Primary Irritant
Ingestion
TUllorigen
ltutagen
Teratogen
Tlfmorigen
Mutage'l
Teratogen
PrImary IrrItant
OSHA Regulation
10 "81m3 TIIA
(rl~':')'lbael1,jed )
(CAS No. I
(32687-78-8 I
(991-84-4 I
(80-0S-7 )
(2S013-16-S1
" '
I '
(128-37-01
I'I
(32509-66- 3 I
(Continued)
-------
j
')
j
j
I
j
j
'j
.
1
!
~i
J
j
;j
j
1
TABLE C-l (Continued)
..
Antioxidant Toxicity Concern OSHA Regulation (CAS No.1
PHENOLICS (Continued)
3,5-Di-t-butyl-4-bydroxybenzyl alcohol Oral, rat Mutagen (88-26-61
(Antioxidant 7541 LDto: 7 p/kg
3,5-Dl-t-butyl-4-bydroxyhydroclnnamlc (34137-o9-ZI
acid, l,3,5-tria(2-bydroxyetbyl)-s-
triazlne-Z,4,6(lB,38,5B)-trione (Good-Rlte
31251
Z,6-Dl-t-butyl metbylamino-p-cresol
Z,4-Dl(a-methylbenzyl)-4-methylphenol (1817-68-11
Dloctadecyl(3,5-dl-t-butyl-4-bydroxy- (3135-18-01
benzy~)phosphonate (Irganox 10931
Bexamethylenebis(3,5-dl-t-butyl hydroxy- (35074-77-ZI
cinnamate) (Irganox Z591
0'\
'-I R,N-Bexa8Bthylenebia-(3,5-di-t-butyl-4- (23128-74-7)
N
bydroxyhydrocinnamaalde) (Irganox 10981
Z(-4-8ydroxy-3,5-t-butylanilino)-4,6-bis-
(n-DCtylthio)l,3,5-trlazlne (Irganox 5651
4-8ydroxymethyl-Z,6-di-t-butylphenol Hay be Toxic Ingeation
3-Hetbyl-6-t-butylphenol/crotonaldehyde
condensate
Z,Z-Hethylenebia(6-t-butyl-4-ethylphenol)' Oral, rat Mild Bye and Sltln (88-24-4)
(Cyanox 425) LD50:>15 811~ Irritant
Z,Z'-Hethylenebia(6-t-butyl-4-methyl-
phenol) (See Z,Z'-Hethylenebls(4-methyl-
6-t-butylphenol»)
"
.i
(Continued)
-------
TABLE C-l (Continued)
Antioxidant Toxicity ~ OSHA Regulation ICAS Bo.1
PHENOLICS (Continued)
4,4'-Hethylenebia(2,6-di-t-butylphenol)
[Bthsnox 7021
2,2'-Kethylenebia(4-.ethyl-6-t-butyl Orel, rat' Prigery Irritant 1119-47-1)
phenol) ICAD 51, [Bia(2-Rydroxy-3-t- LD50: 4880 118/kg
butyl-5-methyl phenyl)methsne), ICyanox
2246)
2,2-Hethylenebia(6(I-.etbylcyclobexyl)-p- 177-62-3)
creaol) INonox VSP)
2,2-Hetbylenebia(4-metbyl-6-nonylpbenol)
[Naugavhitel
4-Hetbyl-2-(1-metbylcyclobexyl)pbenol 116152-65-1)
[Honox VSL)
'" Octadecyl 3,5-di-t-butyl-4-bydroxybydro- 12082-79-31
-...J cinnamate Ilrganox 10761 .""
(....)
Phenol alkyIated witb approximately 114 .,
ratio of 2,3-Benzofuran and Indene "
INevaatain A), INevaatain 8)
I.' I
Tetrakia(8ethylene(3,5-di-t-butyl-4- IIDntoxic 16683-19-81 :~.
bydroxyhydrocinnamate»methsne [Irganox
1010) 'i.
4,4'-Thiobia(6-t-butyl-.-creaol) Intraperitoneal, 10 118/.3 1WA 196-69-5) ~,.:
ISantonox) lIOuse (reco_oded)
LD50' 50 as/ka
4,4,' -Thiob1a(6-t-butyl-o-creaol) Oral, ma_l 196-66-2)
[Antioxidant 7361, [Santonax R I LD50' 6340 1I8/l
-------
T
:/
--"
j
I
TABLE C-l (Continued)
,.
J
,
j
~j
.!
(]\
"
~
Antioxidant Toxicity Concern OSHA Regulation [CAS No.)
PHENOLICS (Continued)
4,4'-Thiobis(2-t-butyl)5-methylphenol) Intraperitoneal, 10 mg/m3 NA [96-69-5)
(see 4,4'-Thiobis(6-t-butyl-m-cresol») mouse 20 IIg/1I3 STEL
LD50:50 IIg/kg (recommended)
Thiodiethylenebis(3,5-di-t-butyl-4- [41484-35-9)
hydroxy)hydrocinnamate [Irganox 1035)
2,2'-(3,5,5-Trillethylhexylidene)bis(4,6- (1292-14-0)
dimethyl phenol) [Nonox WSO)
1,3,5-Trimethyl-2,4,6-tris(3,5-di-t- Low Teratogen [1790-70-21 (
butyl-4-hydroxybenzyl)~enzene [Ethyl 330) Oral, rat
TDu,: 1100 mg/kg . 'If
Toxic Effect: Repro-
ductive; Developmen- ,.
tal '"
1,3,5-Tris(4-t-butyl-3-hydroxy-2,6- Oral, rat (40601-76-1) ,.
dimethylbenzyl)l,3,5-triszine-2,4,6-(IH, LD50: >10 gm/kg :'~t
3H,5H)-trione [Cyanox 1790)
., I
1,3,5-Tris(3,5-di-t-butyl-4~hydroxy- [27676-62-6) th
phenyl)methyl-l,3,5-triazine-2,4,6(IH,3H, ~
5H)-trione (Good-Rite 3114)
Tris(2-methyl-4-hydroxy-5-t-butylphenyl)- (1843-03.-4)
butane [Topanol CA)
AROMATIC AKINES
N-(I,3-Dimethylbutyl)-N'-phenyl-l,4- 1793-24-8 J
benzendiamine IVulkanox 40201
Di-B-oaphtha-p-phenylenediamine Oral t mouse 'fumorigen 193-46-9)
TDu,:3l gm/kg/78W-I Primary Irritant
Toxic Effect: Equiv-
oeal TUmorigenic
Agent
4-Isopropyl-N'-phenyl-p-phenylenediamine Oral, rat Primary Irritant (101-72-4)
(Vulksnox 1040 HA) LD50:555 ms/kg (Dermatitis)
.' .~
.1
'. ~
-1
"1
J
"
. .!
.,
i
,
.,
-!
;
"
(Continued)
-------
/
Antioxidant
AROMATIC !MINES (Continued)
4-(I-Methyl-l-phenylethyl)-N-(4-(I-
methyl-l-phenylethyl)phenyl)benzenamine
[Naugard 445)
THIOESTERS
Dicetyl thiodipropionate
Dilauryl thiodipropionate
Dimethyl thiodipropionate
0\
'-J
VI
Dimyristryl thiodipropionate
Distearyl thiodipropionate
Ditridecyl thiodipropionate
Mixed lauryl-stearyl thiodipropionate
[Cyanox 1212)
Pentaerythritol tetrakis( -lauryl
thiodipropionate)
PHOSPHORUS COMPOUNDS
Alkylaryl bisphenol phosphite
Bis-tridecyl phosphite
2-t-Butyl-a(3-t-butyl-4-hydroxyphenyl)-p-
cumenyl-bis(p-nonylphenyl)phosphite
TABLE C-l (Continued)
Toxicity
Nontoxic
Generally Recognized
as Safe
Eye, rabbit
500 IIg/24H
T"oxic Effect:
Moderate Irritation
Low
Oral, rat
LD50:)l 0 pI kg
Generally Recognized
as Safe
Concern
OSHA Regulation
Eye Irritant
[CAS No.)
, .
[ 10081-67-11
[123-28-4 )
[693-36-71
(Continued)
-------
..
J
:"
.1
.i
.j
1-
I
i
t
!
!
Antioxidant
PHOSPHORUS COMPOUNDS (Continued)
Dibutyl phosphite
Dideeyl phosphite
D1isodeeyl pentaerythritol phosphite
[Weston 600)
D1isodeeyl pentsphosphite
Dilauryl phosphite [(C12H2sO)2PHO)
Dimethyl phosphite [(CHjO)2PHO)
Dioetyl phosphite [(Cs"lJO)2PHO)
0\
.....
0\
Dioleyl phosphIte
Diphenyl deeyl phosphIte
[(C6"50)2POCloH21 )
Diphenyl Isodeeyl phosphite [Weston DPDP)
Diphenyl phosphIte [Weston DPP)
Distearyl pentaerythritol diphosphite
[Weston 618)
Ditetradeeyl phosphIte [Dlmystryl
phosphite)
lsooetyl diphenyl phosphIte [Hark C)
Octyl diphenyl phosphIte
Phenyl dIdeeyl phosphite
(C6H50P(OC loH21 h)
TABLE C-l (Continued)
Toxicity
Oral, rat
LD50:3200 mg/kg
Oral, rat
LD50:4250 mg/kg
Concern
Primary IrrItant
Hoderate FIre Risk
Tumorigen
Primary Irritant
OSHA Regulation
[CAS No.1
[1809-19-4)
[ 868-85-9 )
[25088-57-7)
[3806-34-6 )
[26401-27-4)
(Continued)
-------
Antioxidant
PHOSPHORUS COMPOUNDS (Continued)
Tetrakis(2,4-di-t-butyl)phenyl-(l,l-bi-
phenyl)-4,4'-diylbisphosphite
(Sandostab P-EPQ)
Tributyl phosphite (C4HgO)3P)
Tridecyl phosphite (CloH~)3P)
Triisodecyl phosphite (Weston TDP)
Triisononylphenyl phosphite
Triisooctyl phosphite (Weston TIOP)
0\
--.J
--.J
Triisopropyl phosphite
( (CH3)2CH)3P03)
Trilauryl phosphite (Weston TLP)
Trilauryl trithiophosphite (Weston TLTTP)
Trimethyl phosphite (CH)O)3P)
Trioctyl phosphite
(Tris-2-ethylhexyl phosphite),
(C4H~H(C2HS)CH~)3P)
Triphenyl phosphite (C6HsO)3P)
Tri(polynonylphenyl)phosphite (Polygard)
Tris(2-chloroethyl)phosphite
( (CIC2H40)3P)
TABLE C-l (Continued)
Toxicity
Low
Oral, rst
LDSO:3000 ..g/kg
Intraperitoneal,
mouse
LD SO: SOO ..g/kg
Probably Low
Probably Low
Low
Intraperitoneal.
mouse
LDSO:S234 ..g/kg
Oral. rat
LDSO:1600 ..g/kg
Oral, rat
LDSO:20 gm/kg
Intraperitoneal,
mouse
LIIt.o : 250 mglkg
Concern
Primary Irritant
Hutagen
Hoderate Fire Risk
Primary Irritant
OSHA Regulation
(CAS No.)
(38613-77-3) -
(102-8S-2 )
(116-17-6 )
[121-4S-9 J
(3028-88-4 )
[101-02-01
[S8968-S3-9)
( 140-08-9 )
',.".
I"
I' ,
Jf';,. .'
I
'IP
~,,;
(Continued)
-------
Antioxidant
PHOSPHORUS COMPOUNDS (Continued)
Tris(2,4-di-t-butylphenyl)phosphite
Trisnonylphenyl phosphite
Trlsnonylphenyl phosphite/formaldehyde
polymer (Wytox 438)
Trlstearyl phoaphite (Weston TSP)
MISCELLANEOUS, QUINONES
p-Benzoqulnone (C&H402)
2,S-Oi-t-butylhydroqulnone
0-
.....
00
Hydroqulnone (C&H4(OH)2)
Hydroqulnone monomethyl ether
(CH)OC&H40H)
Hono-t-butylhydroqulnone
(C6H3(OH)2C(CH3)31
Toluhydroquinone (CHJC&H3(OH)21
MISCELLANEOUS, OTHER
Oistearyl disulfide
Hark 1475 (N-(2H,l,2,4-triazol-5-yl)-
salicylamide 1
TABLE C-l (Continued)
Toxicity
Toxic
Intravenous, rat
LOSO: 25 ..g/kg
Oral, rat
LOW: 800 109/kg
Toxic
Oral, rat
TOW: 2500 109/kg
Toxic Effect: Repro-
ductive, Fertility
Moderately Toxic
Oral, rat
LOSO:1600 109/kg
Oral, rat
LOSO:800 109/kg
Concern
'l\Jmorigen
Mutagen
Inba lation
Strong Skin
'l\Jmorigen
Mutagen
Teratogen
Ingestion
Inhalation
Irritant
Eye Contact
Mutagen'
Irritant
OSHA Regulation
0.01 ppll TWA
2 IIg/..3 TWA
:t~
h,
, ,
:1' ,
"t/'Jt
I
, I
; th
: ~I;
I .
(CAS No.)
(31S70-04-4 )
(63981-08-8 )
( 56889-59-91
(106-51-41
(88-58-4)
(123-31-91
( IS0-76-51
(1948-33-01
[36411-52-61
(Continued)
-------
,
1
I
TABLE C-l (Continued)
f.
Antioxidant Toxicity Concern OSHA Regulation (CAS No. J
MISCELLANEOUS (Continued)
Thermolite 31 (Bia(isooctyloxycarbonyl- Orsl, rat 0.1 mg(Sn)/m3 TWA (25168-24-5 J
methylthio)dibutylstannateJ LD50:500 mg/ltg
Thiodipropionic acid
(HOOCCH2SCHr;Hr;OOH J
Zinc dibutyldithiocarbamate Toxic Inges tion (136-23-2 J
(Zn(SC(S)N(C4Hg)2)2J Inhalstion
0\
"
1.0
,.
'II
-------
/
,
j
..j
j
i
TABLE C-2. ANTISTATIC AGENTS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
.!
Antistatic Agent
AMlNES
Bis(hydroxyethyl) coco amine
Bis(hydroxyethyl) tallow amine
Ethoxylsted amines
Octadecyl amine salt of stearic
acid
2,2'-(Octadecylimino)bisethanol
Polyoxyethylene alkyl amine
0'\
00
o
Triethanolamine
Triethanolamine salt of
octadecyl phosphonic acid
QUATERNARY AMMONIUM COHPOUNDS
AHCO C-330
.i
Baraquat CHE (N-Cetyl-n-ethyl
morpholinium etho sulfate)
.:
..'!
Benzyl hexadecyldimethyl
ammonium chloride
. }
N,N-Bis(2-hydroxyethyl)-N-(3-
dodecyloxy-2-hydroxypropy1)
methylammonium methosulfate
'. .
(Carboxymethyl)dimethyl-
octadecyl ammonium hydroxIde
;
f
I
.. i
Toxicity
Oral
LDSO:18S0 mg/kg
LDSO:2S00 mg/kg
Oral, rat
LDSO: 1. 26 gm/kg
Oral, rat
LDSO: 1. 43 gm/kg
Oral, rat
LDSO:I.68 ml/kg
Oral, rat
LDSO:4.1 ml/kg
Concern'
Primary Irritant
Primary IrrItant
Eye Irritant
Eye Irritant
Respiratory
Irr itant
Eye Irritant
Skin Irritant
Eye Contact
OSHA Regulation
(CAS No. (
(37241-10-4 )
(10213-78-2 )
(78-21-4 )
(122-18-9)
(820-66-6)
(Continued) i'
-------
Antiststic Agent
1UATERNARY AHIIONIUH COMPOUNDS
Continued)
)
1
,
!
,
I
1
;
I
1
I
'f
(Csrboxymethyl)hexadecyl-
dimethyl ammonium hydroxide
Dihexadecyldimethyl ammonium
chloride
Dimethyldioctadecyl ammonium
chloride
Dioctyldimethyl ammonium
bromide
"
0-
00
.....
(3-(Dodecyloxy)2-hydroxypropyl)
bis(2-hydroxyethyl)methyl
ammonium methyl sulfate
Salt of Guanidine and octa-
decyltrimethyl ammonium
chloride
(2-Hydroxyethyl)dimethyl(3-
stearamidopropyl) ammonium
nitrate
(3-Lauramldopropyl)trimethyl-
ammonium methyl aulfate
Stearamldopropyldimethyl-2-
hydroxyethylammonium dihydro-
gen phosphate
Stearamidopropyldimethyl-2-
hydroxyethylammonium nitrate
Tetrabutyl ammonium bromide
Trimethyl ammonium methyl-
aulfate
TABLE C-2 (Continued)
Toxicity
Subcutaneous. mouse
TOto: SO mg/ltg
Toxic Effect: Repro-
ductive Developmental
Oral. rat
LDSO: 7 gm/ltg
Oral, rat
LDSO: 1.8 mg/ltg
Oral. rat
LDSO: 1 gm/ltg
(3S% solution)
Or81. rat
LDSO:320 mg/ltg
Concern
Eye Contact
Skin Irritant
Eye Contsct
Eye Contac t
OSHA Regulation
[CAS No.)
[693-33-4)
[1812-S3-9 )
[107-64-2 )
[18602-17-0 )
[2764-13-8)
(Continued)
-------
TABLE C-2 (Continued)
Antistatic Agent Toxicity Concern OSHA Regulation ICAS No.)
AHIONICS
Oidodecyl hydrogen phosphate [39464-66-9)
'o-Dodecyl-~-hydroxypoly(oxy- [39464-66-9)
l,2-ethanediyl)phosphate
Garfac RS 710 [12674-36-1)
o-Honylphenyl-~-hydroxypoly- [51811-79-11
(oxy-l,2-ethanediyl) phosphate
PotassiUII alkyl phospate Oral, rat Eye Irritant 50 ppm TLV (akin)
L050:6.6 gm/kg HUd Skin
Irritant
SodiUII dodecylbenzene sulfonate
0'\ o-Tridecyl-~ydroxypoly(oxy- [9046-01-9)
00 l,2-ethanedlyl) phosphate
N
HISCELLANEOUS
Butyl stearate Lo" [123-95-51
Oral, rat
L050:>32 gm/kg
Glycerol 156-81-51
Glycerol monoatearate [l-..ono- Intraperitloneal, [31566-31-1)
stearinl mouse [123-94-4)
L050:200 mg/kg
Polyethylene glycol hexadecyl
ether
Polyethylene glycol monodecyl [9002 -92 -0 1
ether
Polyethylene glycol 200 Oral, rat 10 mg/m3 TLV [9005-64-5)
monolaurate L050:>10 gm/kg (recommended)
(Continued)
-------
TABLE C-2 (Continued)
Antistatic Agent Toxicity Concern OSHA Regulstion (CAS No.1
MISCELLANEOUS (Continued)
Polyethylene glycol Intravenous, mouse (9004 -99-31
monostearate LDSO:2SD.mg/kg
Sorbitan, dodecanoate, poly- (9062-73-11
(oxy-1,2-ethsnediyl)
derivatives
Tris(isooctadecanoato-o)-(2- (61417-49-01
propsnolato)titsnium
I NORGANICS
AIUlllinulI flakes Nontoxic Pine Powders- 10 mg/llg3 NA (7429-90-81
Pire Risk
Ca rbon black Intravenous. mouse 3. S mg/1l3 1WA (1333-86-41
LDSO:440 mglkg
Lithium chloride
Q\
ex>
v..>
.,' .
I'
III
-------
.~
/'
TABLE C-3.
BLOWING AGENTS AND OTHER ADDITIVES FOR FOAMED. PLASTICS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Blowlng Agent/Foam Hodlfler Toxicity Concern OSHA Regula Uon (CAS No.)
PHYSICAL BLOWING AGENTS
Acetone (CH3COCH3) Inhalatlon, humans Prlmary Irritant 1000 pplD TWA (67-64-1)
TCLo: 500 pplD Inhalatlon
Toxic Effect: Eye Dangerous Flre Rlsk
IrritatIon Hutagen
Alr
AlDIDOnla (NH3) Toxic Inhalation 50 pplD (7664-41-7)
Oral, rat Irritant
LD50:350 109/kg Hoderate Fl r" Rlsk
Hutagen
Benzene (C6H6) Toxic Dangerous F1 re Rlsk 10 pplD TWA (71-43-2) ,;
InhalatIon, humana Inges t 10n
TCLo:I00 pplD/I0Y-1 Inhalat 10n
Toxlc Effect: Carclnogen Skln Absorpt 10n I,..
Hutsgen
C\ Teratogen
00
.po Carclnogen
Prlmary Irrltant
1,1,
Carbon dloxlde (C02) Inhalatlon, humans 5000 pplD TWA (124-38-9)
LCLo:100,OOO ppm/lH
Dlchlorodlfluoromethane
(see Freon 12)
l,2-Dlchloroethsne [ClCH2CH2Cl) Toxic Hutagen 50 pplD TWA [107-06-21
Oral, humans TUlDorlgen 100 pplD Celling
TDLo: 428 109/kg Inges t Ion
Toxic Effect: Gastroln- Inhala tlon
testlnal Tract PrllDary Irrltant
Skln AbsorpUon
Strong Eye and Skln
Irritant
Dlchloromethane [see Hethylene
Chlorlde)
Ethyl alcohol [C2HSOH) Oral, rat Depreaaant Drug 1000 ppm TWA [64-17-5)
LD50:14 gm/kg Dangerous Flre RIsk
(Continued)
-------
TABLE C-3 (Continued)
Blowing Agent/Foam Hodifier Toxicity Concern OSHA Regulation (CAS No.)
PHYSICAL BLOWING AGENTS (Continued)
Freon II (Trichlorofluoromethane) Inhalation, rat Inhalation 1000 ppm TWA (75-69-4)
LCLo:IO pph/]O min. Skin Contact
Freon llA
Freon 11B (Trichlorofluoromethane)
Freon 12 (Dichlorodifluoromethane) Inhalation, rat Inha lation 1000 ppm TWA (75-71-8)
LCSO:80 pph/]O min.
Freon 22
Freon II] (l,l,2-trichlorotrifluoro- Oral, rat Inhalation 1000 ppm TWA (76-13-1 J
ethane), (Cl~FCClF2) LDSO: 4] gm/kg Nervous System
Disorders
Primary Irritsnt
0\ Freon 114 (Dichlorotetrafluoro- Hoderately Toxic Inhalation 1000 ppm TWA (76-14-2 J
00 ethane I, (C12CFCF]1 Inhalstion, rat
VI LCSO:72 pph/]O min.
Freon HE (Blend of Freon III
n-lleptsne (CH](CH2) SCH]) Moderately Toxic Inhalation SOD ppm TWA (142-82-5 I
Intravenous, mouse Dangerous Fire Risk
LDSO:222 mg/kg
n-Hexane (CH](CH2)4CH]1 Hoderstely Toxic Primary Irritant 500 ppm TWA (110-54-] I
Inhalation, humans Ingestion
TCLo:SOOO ppm/lOH Inha lation
Toxic Effect: Central Dangerous Fire Risk
Nervous System; Behsvioral Teratogen
Symptoms
Iso pentane (2-methylbutanel, Low Dangerous Fire Risk ]50 mg/m] TWA (78-78-4 I
(CH]>2CHCH2CH]) 1800 mg/m]/lSll
eel Ung
(recommended)
(Continued)
-------
Blowing Agent/Foam Modifier
PHYSICAL BLOWING AGENTS (COntinued)
Isopropyl alcohol (CHJCH(OH)CH31
Isopropyl ether
K-ll (See Freon III
Methylene chloride [CHZCIZI
0\
00
0\
Nitrogen [Nzi
n-Pentane (CH3(CHZ)jCH31
Perchloroethylene [CIZC:CCIZI
Toluene (C6HSCH31
TABLE C-3 (Continued)
Toxicity
Oral, man
LDLa' 8600 mg/kg
Inhalation, humans
TCLa,400 ppm
TOKic Effect: Irritation
Todc
Oral, rat
LDSO' 8470 mg/kg
Moderately TOKic
Oral, rat
LDSO: 167 mg/kg
Inhalation, humans
Tela' 90,000 ppm/SH
Toxic Effect' Central
Nervous System
Moderately TOKic
Inhalation, humans
TCLa: 96 ppm/7H
TOKic effect: Systemic
Todc
Inhalation, rat
TCLa' 4000 ppm/4H
~
Primary Irritant
Ingestive
Inha lation
Dangeroua Fire Risk
Tumorigen
Mutagen
Inhahtion
Irritant
Dangerous Fire Risk
Inhalation
Ingestion
Skin Absorption
Primary Irritant
Tumorigen
Teratogen
Mutagen
Narcotic
Dangerous Fire and
EKploslon Risk
Irritant to Eyes and
Skin
Posit i ve Ani....l
Carcinogen
Primary Irritant
Ingest ion
Inhalation
Skin Absorption
Dangerous Fire Risk
Tumorigen
Mutagen
Teratogen
OSHA Regulation
400 ppm TWA
SOO ppm TWA
SOO ppm TWA
1000 pm Ceiling
1000 ppm TWA
100 ppm TWA
ZOO ppm CeiUng
ZOO ppm TWA
300 ppm Ceiling
:'
I
, [
"
[CAS No. I
[67-63-01
(108-Z0-31
(7S-09-Z I
[109-66-0 J
(IZ7-18-4 I
[108-88-31
(Continued)
f.
-------
Blowing Agent/Foam Modifier
PHYSICAL BLOWING AGENTS (Continued)
TrIchloroethylene
Trichiorofluoromethane [see Freon III
Trichioromethsne [Chloroform I ,
[CHC131
0-
00
.......
l,l,2-Trlchlorotrlfluoroethane [see
Freon 113 I
Water [H20 I
CHEMICAL BLOWING AGENTS
AmmonIum bicarbonate [NH4HC03I
Ammonium carbonate
[(NH4)HC03'NH2OCONH41
l,l'-Azobiscyciohexanecarbonitrile
Azobisformamide [Azodicarbonamidel,
[ABFA I, [All, [H2NCON: IICONH21
Azobisformamide, nonplateout
Azobls(isobutyronltrile) [AZDNJ
TABLE C-3 (Continued)
Toxicity
Toxic
Inhalation, humans
T0Lo:6900 mg/m3/1ON
Toxic Effect: Central
Nervous System
Toxlc
InhalatIon, humans
TCLo,lOOO mg/m3/1Y
ToxIc Effect: Systemic;
Behavioral SymptoMS; Gas-
troIntestinal Tract
Intravenous. mouse
L050:96 mg/kg
Intravenous. mouse
L050: 245 mg/kg
Nontoxlc
Toxlc
Oral. mouse
L050' 700 mg/kg
Concern
Inhalstion
1'081 ti ve Animal
Carcinogen
Mutagen
Teratogen
Pr1mary IrrItant
Ingestion
Inhalation
Narcotic
Suspected CarcInogen
Tumor1gen
Mutagen
Teratogen
Primary Irritant
Fumes are Irr1tant
Fumes are Irritant
RespIrable Dust
Ingestion
OSIIA Regulation
100 ppm TWA
200 ppm Ceiling
50 ppm TWA
;. .
[CAS No. I
1'1,
[79-01-61
[67-66-31
(506-B7-61
[1066-33-7 I
[123-77-31
[78-67-11
(Continued)
-------
i
. ,
1
!
,
.j
Blowing Agent/Foam Modifier
,
,
!
CHEMICAL BLOWING AGENTS (Continued)
Barium azodicarboxylate
'J
Benzene diaulfonyl dihydrazide
,
>
'j
1
."
j
Benzene sulfonyl hydrazide [BSH)
1,3-Bia(o-xenyl)triazene
2-Butylazo-2-hydroxy-S-methylhexane
[Luce1 7-Azo)
. .
2-Butylazo-2-methoxy-S-methylpentane
[Luce1 135)
Celogen CB [Proprietary hydrazide)
"
Celogen HT-SOO [Modified hydrazine
derivative)
0\
CO
CO
Celogen HT-5S0 [Hydrazine derivative)
Celogen XP-I00 [Sulfonyl hydrazide
type)
Citric acid
[HOC(CH2C02H)ZC02H)
.>1
:'\
'.1
:.j
j
.Oiazoaminobenzene (1, 3-Diphenyl-
trlazene)
N,N'-di-t-butylazobiaformamide
N,N'-di-n-decylazobiaformamide
'1
.,
N,N'-Dinitroao-N,N'-dimethyltere-
phthalamide [N,N'-dimethyl-N,N'-
dinitroaoterephthalamide), [NTA)
Din i t rosopentamethylelle tet ramine
TABLE C-3 (Continued)
Toxicity
Oral, rat
TDLo:1480 mg/kg/S9D
Toxic Effect: Equivocal
Tumorigenic Agent
Oral, rat
LD50:940 mg/kg
Concern
Exploaive at IS0.C or
greater
Mutagen
OSHA Regulation
O.S mg(Ba)/mj TWA
, .
I'I
(CAS No.)
(136-3S-6)
(101-2S-7)
(Continued)
-------
TABLE C-3 (Continued)
BlowIng Agent/Foam ModIfIer Toxiclty Concern OSHA Regulation [CAS No.)
CHEMICAL BLOWING AGENTS (ContInued)
Dlphenylau1fon-3.3'-dlsu1fonyl
hydrazLde
N,N'-Dlphenylazoblsformamlde
Ethylene carbonate [OC(CH2)2) Low Combuatlb1e [96-49-1)
Oral, rat PrImary IrrItant
LD50:10 gm/ltg
EI
-------
.'
TABLE C-3 (Continued)
Blowing Agent/Foam Modifier Toxicity Concern OSHA Regulation [CAS No.1
I CHEMICAL BLOWING AGENTS (Continued)
i Salicylaldehyde hydrazone
,
J
1 Silicon oxyhydride
~ ~J Sodium bicarbonate [NaIl:031 Low Primary Irritant [144-55-8)
, Oral, rat
"
:! LD50:4220 mg/kg
,j Sodium borohydride [NaBH41 Oral. rat Reacts with Water [16940-66-2)
, . .-.~
", LDLo: 160 mg/kg Dangerous Fi re Risk
/~
,J
,,1 3,3'-Sulfonbis(benzene sulfonyl
',)
. I hydradde)
" .'
p-Toluene aulfonyl hydradne
p-Toluene aulfonyl semicarbadde
0' [TSSC)
\0
0 Trihydrazine trIazine [THT),
[Cyanuric trihydrazide)
GASEOUS DECOMPOSITION PRODUCTS OF
,. CHEMICAL BLOWING AGENTS
Ammonia [aee Physical Blowing Agents)
Carbon dioxide [see Physical Blowing
.~, Agents)
'.'
Carbon monoxide [CO) Highly Toxic Inhalation 50 ppm TWA [ 630-08-0)
Inhalation, humans Highly Flammable
LDLo:4oo0 ppm/30 min.
Formaldehyde (II:HO) Highly Toxic Inhalation 3 ppm TWA [ 50-00-0 )
., Inhalation, humana St rong Irritant 5 ppm Ceiling
,
TeLo:17 mg/m3/30 min. Moderate Fire "Riak 10 ppm Peak/30 min./
Toxic Effect: Eye Irrita- Positlve Animal 8 houra
tion, Pulmonary System CarcInogen
Mutagen
(Continued)
-------
i
Blowing Agent/poam Hodifier
GASEOUS DECOMPOSITION PRODUCTS OP
CHEHICAL BLOWING AGENTS (Continued)
Nitrogen [see Physical Blowing
Agents)
Nitrous oxide [N20)
Water [ses Physical Blowing Agents)
RESIDUE paOH CHEHICAL BLOWING AGENTS
Ammonium bicarbonate [see Chemical
Blowing Agents)
0-
\0
.....
Ammonium carbamate [NH4C02NH2)
Barium carbonate [BaC03)
Biurea
Cyamel1de
Cyanuric acid
[HO«NC(OH)NC(OH)r- 2H~)
Diisopropyl carbonate
Diisopropyl ether [see Physical
Blowing Agents)
2,3-Dimethylbutane [see Physical
Blowing Agents)
TABLE C-3 (Continued)
Toxicity
Inhalation, humans
TDto:24 mg/kg/2 hours
Toxic Effect: Behavioral
Symptoma, Csrdiovascular,
Hetabolism, Nutrition
Int~avenOU8, mouse
LD50:77 109/kg
Todc
Oral, humans
LDLo:57 109/kg
Low
Oral, rat
LDLo: 500 109/kg
Concern
Hoderate Pire Risk
"'tagen
Irritant
Ingestion
Primary Irritant
Equivocal Tumorigenic
Agent
OSHA Regulation
25 ppm TWA
(recommended)
0.5 mg(Ba)/m3 TWA
.11
I
i
;. )',
t ; \
I ,~, "
,', r!
; Y L'
L '{ ,I
'j ,t' iI i
, '-j
[CAS No,)
[10024-97-2 )
11111-78-01
[ 513-77-9)
[108-80-5 )
I. I'
" .
l'
.
. ,
(Continued)
'11
-------
"
.' . ,/"
>. - ,
. '"
/
. j
,
."J
. .,
i
,
i
TABLE C-3 (Continued)
Blowing Agent/Foam Modifier Toxicity. Concern OSHA Regulation (CAS No.1
RESIDUE FROM CHEMICAL BLOWING AGENTS
(Continued)
N,N'-DiIDethylterephthalamide
Diphenylamine (C6H5)2NHI Toxic Skin Absorption 10 .g/m3 TWA (122-39-41
Oral, rat Inhalation 20 .g/.3 STEL
LDu,:3000 mg/kg (reco_ended)
'.
Diphenyl disulfide
Ditolyl disulfide Intraperitoneal, mouse (B82-33-11
, LD50:100 IDg/kg
Hydrazine (H2NNH21 Toxic Ingestion I ppm TWA (skin) (302-01-21
Inhalation, rat Inbs lation
LC50:510 pPID/4 hours Skin Absorption
I Skin snd Eye Irritant
Severe Explosion
1 0\ Haza rd ,.
\0 Positive Animal
N Carcinogen
Mutagen
\ Isobutyronitrile Oral, rat Primary Irritant 22 mg/1D3 TWA (18-82 -0 I
.! LD50:102 IDg/kg (recommended)
KetenllDine
, Hethacrylonltrlle 81ghly Toxic PrilDary Irritant 1 ppm TWA (skin) (126-98-11
Oral, rat Ingestion 2 ppm STEL
LD50:250 IDg/kg Inha14tion (recoOllDended)
Skin Absorption
Dangerous Fire Risk
OxalDide (NHzCOCONH21 Intraperitoneal, mouse Primary Irritant (411-46-51
LDLo: 128 IDg/kg
Phenylbenzenethiosulfonate
Tetramethylsuccinonitrile Intravenous, mouse
LD50:18 IDg/kg
3 mg/ID3 TWA (skin)1 ' /' (3333-52-61
" '
, II
l'
I
t
, ,""
I' r j
t ", ~
\ ,~,,',.
"'.[1
, ~ ~ '
III ; "I
I ,~' ~ \,
,
~', ';'
(Continued)
,
.f 'd
-------
TABLE C-3 (Continued)
Blowing Agent/Foam Modifier Toxicity Concern OSHA Regulation [CAS No.)
RESIDUE FROM CHEMICAL BLOWING AGENTS
(Continued)
p-Thiocresol Intraperitoneal, mouse [l06-45-6)
LD50:200 mg/ltg
p-Toluene sulfinic acid
p-Tolyl p-toluene thiosulfonate
Urazole
BLOWING AGENT CATALYSTS
Actafoam F2
Actafoam R-3
Actsfoam &-5
0\
\0 Actafoam R-lO
W
Actsfoam R-34
BIK [urea (surface treated»)
Interstab ABC 1
Interstab ABC 2
Interstab ABC 6
Inters tab ABC 7
Interstab ABC 18
Interstab ABC 50
Nuostabe V-l530 [Zinc-based
activator)
RlA
7.1nc oxide Nontoxic Primary Irritant 5 mg/m3 TWA [13l4-13-2)
Oral, rat Inhalation
LDLo: 684 6 mg/kg Teratogen
Mutagen
(Continued)
-------
. . ~;>-F
./
..1
.:'.~'. .1
: j
..,
!
.j
1
;
\
J
.1
.1
Blowing Agent/Foam Modifier
SUIlFACTANTS
SILICONES
Dabco Isilicone, tetraethylene-
diamine)
.J
Dimethylsilicone oil
Dow 190 Isilicone-glycol)
, !
Dow 192 Isilicone-glycol)
Dow 193 Isilicone)
Dow 194 Isilicone-glycol)
Dow 195 Isilicone-glycol)
0'\
\C)
.I:-
Dow 191 Isilicone-glycol)
Dow 1250 Isilicone-glycol)
Dow 1251 Isilicone-glycol)
Dow 1252 Isilicone-glycol)
Dow 1253 Isilicone-glycol)
Dow 1254 Isilicone-glycol)
Dow 1312 Isilicone-glycol)
Dow F-11630 Isilicone-glycol)
G. g. SS-4255 Isilicone)
Tegostab B 3640 Isilicone)
i
Tegostab B 4113 Isilicone)
Union Carbide L-520 Isilicone)
TABLE C-3 (Continued)
Toxicity
OSHA Regulation
Concern
Low
Oral. rat
LD50:22 am/kg
ICAS No.)
(Continued)
-------
TABLE C-3 (Continued)
Blowing Agent/Foam Modifier Toxicity
SILICONES (Continued)
Union Carbide L-532 (silicone)
Union Carbide L-540 (silicone)
Union Carbide L-546 (silicone)
Union Carbide L-548 (silicone)
Union Carbide L-550 (silicone)
Union Carbide L-562 (silicone)
Union Carbide L-5302
Union Carbide L-5303
Union Carbide L-5305
0\
\0 Union Carbide L-5307
VI
Union Carbide L-5340
Union Carbide L-5350
Union Carbide L-5410
Un ion Ca rbide L-5420
Union Carbide L-5430
Union Carbide L-5612
Union Carbide L-5710
Union Carbide L-5720
Union Carbide L-6202
Un ion Ca rbide LC-5613
OSHA Regulation
Concern
I,; /;
. II
, '-"
t, .r I
I. . ~
I ,.<,,/
.. ,{ \
i '{ ~ '
,II . \,.
I ,~' jI .
. ',Ii
\, t
~.
I
.
t,f ',l
(CAS No.)
(Continued)
-------
;/
/
Blowing Agent/Foam Modifier
SILICONES (Continued)
Union Carbide Y-6402
Union Carbide Y-6454
SURFACTANTS
MISCELLANEOUS
Air Prod LK-22l (organic amine)
Air Prod LK-322 (all organic)
Air Prod LK-443
Empicol LZ (sodium alkyl sulfate)
Ethylsn TC (amine ethylene oxide)
0\
\0
0\
Ethylan TCO (fatty amine oxide)
Interwet 212 (non-ionic ester)
Zonyl FSA (fluorosurfactant)
Zonyl FSB (fluorosurfactant)
Zonyl FSC (fluorosurfactant)
Zonyl FSJ (fluorosurfactant)
Zonyl FSN (fluorosurfactant)
Zonyl FSP
TABLE C-3 (Continued)
Toxicity
Concern
OSHA Regulation
(CAS No.)
II; Ii
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; 'ill
tl d:1
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(Continued)
-------
TABLE C-3 (Continued)
Blowing Agent/Foam Modifier Toxicity Concern OSHA Regulation (CAS No. 1
NUCLEATING AGENTS
Adipic Acid Oral, rat Primary Irritant (124-04-91
LDto' 3600 mg/kg
Benzoic Acid Oral, lUaD Primary Irritant (65-85-0)
L°Lo' 500 mg/kg
Calcium carbonate (Cac031 Nontoxic 10 mg/m3 'NA (471-34-11
(recommended)
Silica (Si021 Toxic lnha lation 80 mg/m3 'NA (7631-86-91
Oral, rat (allicoata)
L050: 3160 mg/kg
Sodium ailicofluoride (Na2SiF61
Talc Hoderate Skin, humans Inhalation 20 mppcf 'NA (14807-96-61
300 g/30-1 Primary Irritant (nonftbrous)
0\ Toxic Effect: Mild Tumorigen (recommended)
\0 Irritation
-..J
-------
"
TABLE C-4. CATALYSTS FOR THERMOPLASTICS POLYMERIZATION
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
!. .
!:
Catalyst Toxicity Concern OSHA Regulation (CAS No.)
Acetic Acid (CHj:OOH) Toxic Moderate Fire Risk 10 ppm 'lVA (64-19-7)
Skin, humans Ingestion
50 mg/24H Inhalation
Toxic Effect: Mild Primary Irritant
Irritstion Mutagen
Acetic Anhydride Oral, rat Primary Irritant 5 ppm 'lVA (108-24-7)
((CHj:°hO) L050: 1780 mg/kg Co rrosi ve
N-Acetylcaprolactam
Acetyl perchlorate
Aluminum chloride Toxic Ingestion [7446-70-0)
Oral, rat Inhala t ion
L050:3700 mg/kg Strong Irritant
Reacts Violently With
Water
0'
\0 Aluminum isopropoxide Oral, rat (555-31-7)
2TiF6) L050:56 mg/kg (recommended)
Antimony trifluoride Toxic Strong Eye and Skin 0.5 mg(Sb)/m3 'lVA [7783-56-4)
Sub~utaneou8. frog Irritant (recommended)
L°Lo: 224 mg/kg
Antimony trioxide (Sb~3) Toxic De rma ti t is 500 ug/m3 TWA (1327-33-9)
Intravenous, dog ,
LDLO:3 mg/kg
(Continued)
-------
Catalyat
Benzil
[C6"5CO'COC6"51
Benzophenone [(C6"5)2COI
Biace t al
Bia(cyclopentadienyl) titanium
chloride
Bia(triphenylailyl) chromate
[«C6H5)3SiO)2Cr021
Boric Acid [H3B03)
0\
\0
\0
Boron trifluoride
Boron trifluoride dibutyl-
etherate
Boron trifluoride etherate
Butyl lithium
Butyl zinc
Cadmium acetate
[Cd(OOCCH3)21
Calcium acetate
[Ca(CH;zCOO)21
I .
TABLE C~4 (ContInued)
III
Toxicity Concern OSHA Ilegulation [CAS No.)
Oral, rat Primary Irritant [134-81-61
LD50: 2710 IIg/ltg
Oral, rat Tullorigen [119-61-91
LDSO:'2895 IIg/ltg
Oral, rat [431-03-81
LD50:1580 mg/ltg
(127-19-81
Oral, rat .100 ug(Cr03)/1I3 Ceiling [1624-02-81
LD50:3360 mg/ltg
Toxic Ingeation [10043-35-31
Oral, hUll8na Irritant
LOto: 214 IIg/ltg.
Toxic Inhalation 1 ppll Ceiling [7637-07-2)
Inhalation. rat Corroai ve to Slr.1n and"
LCLo: 750 ppm/5.58 Tiaaue
Toxic
Inhalation
Corroaive to stin and
Tisaue
Toxic
Highly Flammable
Irritant
[109-72-81
Toxic
Intraperitoneal, rat
TOto: 2371 ug/ltg
4 ug(Cd)/.3 TWA
(recommended) .
[543-90-81
Hutagen
Teratogen
Nontoxic
Intravenous, rat
TOto: 147 IIg/ltg
[62-54-4 )
(Continued)
-------
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Catalyst
. j
1
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"
Carbon dioxide [C02)
p-Chlorophenyl diazoniWl hexa-
fluoroaraenate
p-Chlorophenyl diazoniWl hexa-
fluorophosphate
, ,
. ~
Chromocene [(CY'S)2Cr)
Chromic Acid [Cr03)
':j
',' ~
, i
"
o
o
Chromyl chloride [CrO~12)
-.1
Cobalt acetate
[CO(C2H]02>2)
Cobalt on charcoal
'j
~
Copper (I) chloride [CuCl)
",;
,;
i
'I
Copper (II) chloride [CUC12)
. ,
Cyanuric chloride
[C3N ]C13)
Dibutyl aluminum chloride
[Al( C4H9>2Cl)
TABLE C-4 (Continued)
Toxicity
Inhalation, rat
TCLa,6 pph/24 Hr.
Toxic Effect: Reproduc-
tive, Developmental
Toxic
Inhalation, humans
TCLa' HO ug/m3
Toxic
Subcutaneous, mouse
L~: S. 4S .mg/kg
Intravenous, mouse
LDSO:31 mg/kg
Toxic
Oral, rat
LDSO:26S mg/kg
Moderately Toxic
Oral, rat
LDSO:140 mg/kg
Low
Intravenous, mouse
LDSO:18 mg/kg
~
Inhalation
Skin Corrosion
Strong Reducing Agent
Tumor1gen
Mutagen
Teratogen
Skin Corrosion
Ingestion
OSHA Regulation
[CAS No.)
[124-38-9 )
SOOO ppm 'NA
100 mg(Cr03)/m3
[1271-24-S)
[1333-82-0)
0.025 ppm TLV
[14977-61-8 )
[71-48-7 )
[77S8-89-6 )
1 mg(Cu)/m3 'NA
[1344-67-8)
[108-77-0)
(Continued)
I'
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Catalyat
Dtethyl aluminum chloride
(C2H5hAlCl)
Diethyl ethoxy aluminum
(AlEt 20Et)
Diethyl zinc (ZnEt21
Di-(2-methyl horneal) chromate
Di(triphenylailyl) chromate
Ethyl aluminum sesquichloride
«C2H5hAl2C131
-...J
o
I-'
Ethyl magneaium bromide
Ferric acetyl acetonate
(Fe(OC(CH3):CHC(0)CH3)3)
Germanium dioxide (Ge021
Iodine
Lead acetate
(Pb(C2HJ02)21
TABLE C-4 (Continued)
Toxicity
Intravenous, mouse
LD SO: 100 IIg/kg
Intraperitoneal, rat
LD50:7S0 mg/kg
Highly Toxic
Oral, rat
LD50:14 gm/kg
Highly toxic
Oral, rat
TDLo: 314 IIg/kg
Concern
Highly Flammable
Ignites Spontaneoualy
in Air
Decollposes Violently
in Water
Inhala tion
Ingestion
Inhalation
Ignites on Contact
With Air
Reacts Violently in
Water
Irritant to Eyes and
Hucoua Hembranes
Dangeroua Fire Risk
Ingestion
Inhalstion
Strong Eye
Irritant
s,!d Skin
Tumorigen
Hutagen
Ingeation
Inhalation
Skin Absorption
Teratogen
OSHA Regulation
5 mg/1I3 TLV (ZnO fume)
0.1 ppm Ceiling
200 ug(Pb)/..3 TWA
(CAS No.1
(557-20-01
(1634-02-81
(12075-68-21
(14024-18-11
(1310-53~8 1
(7553-56-21
(301-04-21
(Continued)
, . .
-------
./
TABLE C-4 (Continued)
Catalyst Toxicity Concern OSHA Regulation [CAS No.)
Lead dioxide [Pb02) Toxic Fire Riak in Pres- 200 ug(Pb)/.3 ~A [1309-60-0)
Intraperitoneal, guinea ence of Organic
pig Materials
LDSO:220 mglkg
Lead oxide [PbO) Toxic Primary Irritant SO ug(Pb)/.3 TWA (1317-36-8)
Intraperitoneal, rat Ingestion
LDto:430 mg/kg Inhalation
Tumorigen
Hutagen
Lithium acetate
[LtC2"J02)
Lithium a-butoxide
LithLum carbonate [Lir;03) Low Hutagen [S54-13-2)
Or al, human Teratogen
TDLo: 4111 mg/kg
~
a Lithium hydride [Li") Inhalation, rat Primary Irritant 2 S ug/m3 TWA [7S80-67-8)
N LCLo:22 mg/m3/4H Fire Risk
Toxic Effect: Pulmona ry Ignitea Spontaneoualy
System 10 Hoist Ai r
Hagnesium Oral, dog Fire Risk (powder) (7439-9S-4)
LDLo:230 mg/kg
Magneaium acetate Intravenous, mouse [142-72-3)
IHg(OOCCH3)2) LDSO:16 mg/kg
Hagnesium dichloride [HgC12) Hoderate (7786-30-3)
Oral, rat
LDSO:2800 mg/kg
HagneaLum hydroxide [Hg(OH)2) Nontoxic [ 1309-42 -8)
Hagnesium hydroxychloride,
[Hg(OH)CI)
Magnesium oxide [HgO) Toxic Inhalation lS mg/m3 TWA [1309-48-41
Inhalation, humana
1'CLo: 400 mg/m3
(Continued)
-------
"
TABLE C-4 (Continued)
Catalyst Toxicity ~ OSHA Regulation
Magnesium sulfate (MgS04) Low
Intrsperitoneal, rat
Mutagen: 450 mg/kg
Hanganese acetate Hode'rate Mutagen
(Mn(C28302)2) Oral, rat
LD50: 2940 mg/kg
Manganese dioxide Moderate Oddizing Agent
Subcutaneous, mouse May Ignite Organics
LD50:422 mg/kg
Molybdenum trioxide (Mo031 Todc Inhalation 5 mg(Ho)/.3 TWA
Oral, rat
LD50: 125 mg/kg
1 mg(Ni)/m3 TWA (skin)
Nickel on charcoal
--.J
a Palladium (N)
lJ,)
Perchloric acid Oral, rat Skin Contact
LD50' 1100 mg/kg Inha lation
Todc Effect: Behavioral Inges tion
Symptoms, Pulmonary Sys- Strong Oxidizer -
tem, Metabolism and Sometimes Explosive
Nutrition St rong Irri tant
Phenyl isocyanate (C68sNCO) Todc Irritant
Oral, rat Lachry....tor
LD50' 940 mg/kg Fire Risk
Phenyl-N-phenyl bendm1doether
Phosphoric add (831'04) Todc Ingestion I mg/m3 TWA
Inhalation, hu....ns Inha lation
TCLo: 100 mg/m3 Pri....ry Irritant
Todc Effect: Irritant
Potassium carbonate (K2C03) Oral, rat Tissue Irritant
LD50:1870 mg/kg
(CAS No.)
(14567-64-71
(638-38-0 )
(1313-13-91
(1313-27-5)
(7440-02-01
(7601-90-3)
(103-71-9)
(7664-38-2)
(584-08-7 )
I,; I;
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(Continued)
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Catalyat
Potaaaium ferrocyanide
(KJfe(CN)61
Potassium triphenyl methoxide
Pyridine (N(CH)4CHI
L-....:.J
Sodium acetate
Sodium caprolactam
Sodium carbonate (NaZC031
-...J
a
.p.
Sodium hydride (NaHI
I
I
Sodium hydroxide (NaOHI
Sodium hypophosphite
(NaH2P02(
Sodium methoxide
Toxicity
Low
Oral, rat
LDLo: 1600 mg/kg
Toxic
Oral, rat
LDSO: 891 mg/kg
Nontoxic
Oral, rat
LDSO:3S30 mg/kg
Low
Oral, rat
L~o:4000 mg/kg
Toxic
Toxic
Eye, rabbIt
1 mg/24H
Toxic Effect:
Irritant
Intraperitoneal, rat
LDSO:1S84 mg/kg
Toxic
TABLE C-4 (Continued)
Severe
Concern
Primary Irritant
Ingestion
Inhala tion
Mutagen
Primary Irritant
Fire Risk
Reacts Violently
With Water
Ingestion
Inhalstion
Skin Contact
Corrosive
PrImary Irritant
Explosion Risk With
Oxidizing Agents
Co rroBi ve
Fire Risk
Skin Contact
Inhala tion
Ingestion
OSHA Regulation
S ppm 'NA
2 mg/m3 'NA
(CAS No.1
(13146-66-2 I
1110-86-1 I
(121-90-31
(491-19-81
(1646-69-1 I
(1310-13-21
(1681-S3-<11
, .
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, / l~24-41-41
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(Continued)
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-------
TABLE C-4 (Continued)
Catalyat Toxicity Concern OSHA Regulation ICAS No. J
Sulfuric acid IHzS°4J Highly Toxic Irritant 1 mg/..3 'NA 17664-93-9 J
IS03 in H20 J Humans
LDLo' 13S mg/kg
Tetraallyl zirconiu..
IZr(allyl)4 J
Tetrabenzyl araonium chloride
Tetrabenzyl phosphonium
chloride
Tetrabenzyl titanium
ITi(C6'\S)4 J
Tetrabenzyl zirconium
IZr(C6'\S)4J
Tetrabutyl zirconate
..... IZr(OC4H9)4 J
0
V1 Tetrabutyl titanium ITiBu4J Oral, rat 15593-70-4 J f
LDSO' 3122 mg/kg
Tetraethyl titaniu..
1T1(OC2HS)4 J
N,N,N',N'-Tetramethylethylene- Skin, mouse 1110-18-9 J
diamine I (CH3)2I1:H:zCH2N LDSO' 7 am/kg
(CH3)2J
Tetramethylguanidine
I (CH3)2NC(NH)N(CH3)2J
Thiocarboximide
Titanium dichloride ITiCl2J Fire Risk II0049~6-6 J
Titanium dichloride diiao-
propylate ITiC12(OPr)2J
(Continued)
-------
TABLE C-4 (Continued)
"'
,
,
Catalyst Toxicity Concern OSHA Regulation (CAS No.1
Titanium dioxide (Ti021 Nontoxic Tu80rigen 15 IIg/lI~ 'lWA (13463-67-71
Intramuscular, rat Primary Irritant
TDLo' 30 mg/kg/84W
Toxic Effect: Carcinogen
Titanium isopropyl ate (546-68-91
(Ti(OC]ll8>4I
Ti tanium tetrachloride Toxic Inhalation No Standard (7550-45-0 I
ITiCI4) Inhalation, mouse Skin Irritsnt
LCLc1' 10 mg!m3/2H
Titanium trichloride (TiC131 Intrstesticular, rat Fire Risk (7705-07-91 ,
LGw,1234l ug/kg Skin Irritant '"
Toxic Effect: Reproduc-
ti ve, Pa ternal
Triallyl halfium bromide
-...J Triallyl titanium bromide
a (Ti(allyl»8r)
0'
Triallyl zirconium bromide
Tributyl aluminum Fire Risk (1116-70-7)
(CH]CH~8~82)3 All Ignites Spontaneously
Tricyclohexyl aluminum
(AI(C~13)31
Triethyl aluminum 8ighly Toxic Tissue" Destruction (97-93-81
(C2H5>3Al) Fire Risk
Reacts Violently With
Water, Alcohol,
Amines, Halogens
Triethylamine nC2H5hN) Toxic Fire Risk 25 "ppm 'lWA (121-44-8)
Oral, rat Ingestion
LD50:460 mg/kg Inhalation
Primary Irritant
Mutagen
. i
" .
(Continued)
,"
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-------
TABLE C-4 (Continued)
Catalyat Toxicity Concern OSHA Regulation [CAS No.)
Triethylbenzyl ammonium Intravenous. mouse [56-37-11
chloride LD50:18 18g/"g
Triethyl sulfonium iodide [1829-92-11
Triphenylphosphine Oral, rat [603-35-01
LD50:800 IIg/"g
Triisobutyl aluminum Highly Toxic Ignites Spontaneously
((CH3)2CHCH2»)All Tissue Destruction
Vanadium oxytrichloride Highly Todc Strong Tissue 0.05.g(V)/.3 15 .inute Iii Ii (772 7-18-61
(VOC131 Oral, rat Irritant ceiling (recommended) II ~'
LD50:140 mg/"g
I
Vanadium trioxybutylate : '
(VO(OC4H9hl 'Y
0.05 IIg(V)/.3 15 lIinute t, ,,(
Vanadium tetrachloride (VC141 Highly Todc Ingestion " ", (7632-51-1 J
" Oral, rat Inhalation ceiling (recommended) I, .\. '{
0 LD50:160 IIg/kg Skin Absorption ' '. sf
" 1/ Y f I
Vanadium trichloride (VC131 Toxic Irritant 0.05 18g(V)/.3 15 lIinute ',i, + ;\, (7727-18-61
Oral, rat ceiling (recommended) ,
LD50:350 IIg/kg \> l
Zinc: acetate Low ti "",' (557-34-61
(Zn(C2HJ02)21 Oral, rat
LD50:2510 IIg/"g
Zinc chloride Toxic Skin Irritant 1 18g/113 TWA (fume) (7646-85-71
Oral, rat Inhalation
LD50:350 .g/kg
Zinc: formate [Zn(CH02)21 Hay be Toxic Ingestion
Zinc: odde (ZnO 1 Nontoxic Inhalation 5 IIg/1I3 TWA (fume) (1314-1]-21
Oral, rat Mutagen
TDLo: 6846 IIg/"g Teratogen
(Continued)
-------
/,/
TABLE C-4 (Continued)
i.
,
.,
j Catalyst Toxicity Concern OSHA Regulation (CAS No.)
I SUPPORTS
..j
i Si02 Toxic Inhalstion 80 ..g/..3 TWA (7631-86-9)
j Oral, rat (Silicosis)
i LDSO:3160..g/kg I,; I'
! Alz03 [See Catalysts)
. II ~ 1309-48-4)
HgO (See Catalysts)
" I .
: .
HgOHCI (See Catalysts) 'V
HgCl2 (See Catalysts) I' ,. (
II . ",
Hg(OH)2 (See Catalysts) I , ;Y/fl1309-42-8)
,~ '
i Ti02 (See Catalysts) {I i f 1'(13463-67-7)
", till
! TiCl3 (See Catalysts) I . ,', 1770S-07-9)
...... ". t',
.! 0 Cao Strong Irritant S ..g/..3 TWA (130S-78-8) ,
~ 00 II. I ,.
ti.il'
CaS(P04»OH (12167-74-7)
Hg(OEt)z
HgS04 Low (7487-88-9)
Oral, mouse
LDSO:SOO ..g/kg
NEUTRALIZERS
. , Calcium o"ide (See Supports)
.- i
.;'! Calcium stearate Low
1
n-Heptane Todc Fire Risk SOO ppll TWA (142-82 -S)
.. (CH3(CH2)SCH3) Intravenous, mouse . Inha lation
LDSO:222 ..g/kg
(Continued)
'1
,
-------
Catalyat
NEUTRALIZERS (Continued)
Hydrochloric acid (HCI)
laopropyl alcohol
(CH3):z(;HOH)
Hethanol
Phoaphoric Acid (See Catalyata)
n-Propanol (CHJCHzCH:zOH)
"
o
\0
Triphenyl phoaphate
Water (aa ate am)
TABLE c-4 (Continued)
Toxicity
Toxic
Inhalation, humans
LCLo: 1300 ppm/31M
Toxic
Oral, rabbit
LDt.o: 5000 mg/kg
Eye f human
5 ppm
Toxic Effect:
Irritation
Low
Inhalation, mouse
LC50: 48 gm/m3
Toxic
Oral, rat
LD50:260 mg/kg
Concern
Inhalation
Ingestion
Irritant to
Skin
Eyes and
fire Risk
Ingestion
Inhalation
Mutagen
Teratogen
Primary Irritsnt
Skin Contact
Inhale tion
Fire Risk
Primary Irritant
Inhalation
OSHA Regulation
(CAS No.)
5 ppm celling
[7647-01-0)
(67-63-0 )
200 ppm TWA
(67-56-1)
200 ppm TWA
(71-23-8 )
3 mg/m3 TWA
(115-86-6 )
-------
,
,
-'
Colorant
-
INORGANIC PIGMENTS
WHITE
Aluminum Silicate (Al2(Si03)3)
Barium Sulfate (BaS04)
(Blanc fixe)
Calcium Silicate (CaSi03)
(Wollastonite)
Lithopone (28% ZnS and 72% BaS04), (see
Barium Sulfate and Zinc Sulfide)
Titanium dioxide (Ti02)
-...,J
.....
a
Wollastonite (see Calcium Silicate)
Zinc oxide (ZnO)
Zinc Sulfide (ZnS)
BlACK
Bone Black [C+ca3(P04)2)
Ceramic Black
TABLE C-5. COLORANTS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Color Index
Pig. White 22, 77102
Pig. White 21, 77115
Pig. White 5, 77115
Pig. White 6, 77891
Pig. White 4, 77947
Pig. White 7,77957
Pig. Black 9, 77267
Pig. Black 26, 77494
Pig. Black 28, 77428
Toxicity
Nontoxic
Intrapleural, rat
TOu,: 200 mglkg
Toxic Effect: Tumorigen
Nontoxic
Nontoxic
Skin, humans
300 ug/3D
Toxic Effect:
Irritation
HUd
Nontoxic
Nontoxic
Oral, rat
LOu,: 6846 mglkg
Hoderate
Concern
Irritant
Inhalation
Tumorigen
Irritant Dust
Tumorigen
Primary Irritant
Inhalation
Irritant
Dust
Primary Irritant
Inhalation
Hutagen
Teratogen
Hutagen
Teratogen
Primary Irritant
OSHA Regulation
10 mg/m3 TWA
(recommended)
10 mg/m3 TWA
(recommended)
15 mg/m3 TWA
10 mg/m) TWA
(recommended)
5 109 1m3 TWA
5 mg/m3 TWA
t>
!.
[GAS No.)
( 14504-95-11
,
f
(7727-43-7 )
[13462-86-7 )
(10101-39-0 )
[1345-05-7)
[1317-80-2) ,
(1346)-67-7 )
(14567-51-2)
(13983-17-0)
(1314-13-2)
( 1314-98-31
; >
,
.>
(Continued»
!
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1
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j
Colorant
BLACK (Continued)
Iron Oxide (FeO.Fe20]1
Copper Chromite Black (Cu(Cr02)2)
Cobalt Black (COO)
BLUE, GREEN
Barium Hanganate (BaHn041
(Manganese green 1
--.J
......
......
Cassel Green (HnO)
Chrome Cobalt-Alumins (turquoise)
(CrCoAI oxides)
Chrome Green (green) (PbCr04.PbS04'
FeNH4Fe(CN)6)
Chromium Oxide (dull green) (Cr20]1
Cobalt Aluminate (blue) (CoO.Al20])
Cobalt Chrome Green
Hydrated Chrome Oxide (green)
(Cr20]' 2H20)
Iron Blue (blue) (Prussian
(Milori and Chinese Blue)
(FeNH4Fe(CN)6) or
(FeNH4Fe(CN)6" FeKFe(CN)6I'
Blue)
Color Index
Pig. Black II, 77499
Pig. Black 1], 77]22
77726
Pig. Blue ]6, 77]4]
Pig. Green 15, 77510,
77600
Pig. Green 17, 77288,
77289
Pig. Blue 28, 77]46
Pig. Green 26
Pig. Green 18, 77289
Pig. Blue 27, 77510
77520
TABLE C-5 (Continued)
Toxicity
Subcutaneous, rat
TOto: 1]5 ..g/kg
Toxic Effect: Equivocal
Tumorigenic Agent
Intratracheal, rat
1.DJ.o: 50 109/kg
Subcutaneous, mouse
LD50:l000mg/kg
Toxic
Impregnation, rat
TDw:90 109/kg
Toxic Effect: Equivocal
Tumorigenic Agent
j "
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11'liP
I,+'ll,
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Concern
. ,
" :II
OSHA Regulation
Inhalstion 5 mg(Fe)/m] 'n/A
Tumor igen 10 mg(Fe)/m] STEL
Indefinite Carcinogen (recommended)
0.5mg(Cr(VI»/m]
'n/A
100 ug(Co)/m] 'n/A
(fume and dust)
5 mg(Mn)/m] 'n/A
(recommended)
5 IDg(Hn)/m] 'n/A
(recommended)
Tumorigen 0.5mg(Cr(VI»/m]
Mutagen 'n/A
Tumorigen 0.5 IDg(Cr(VI»/m]
Mutagen NA
Indefinite Carginogen
100 ug(Co)/m] 'n/A
Tumorigen
Mutagen
0.5mg(Cr(VI»/m]
NA
(CAS No.)
(1317-61-9)
"
(12018-10-9)
~ ,
,
(1307-96-6)
r
(7787-]5-1 )
,-
(1344-4]-0)
~ . .
(7758-97-6 )
(1]08-]8-91
(1 ]]]-88-6)
'(12182-82-01
to'.:
(140]8-4]-81
I
(Continued)
'.~
1.~ ,
I. ,:
; t-r '
"
'I,
-------
.,
,/
,
.'
Colorant
BLUE, GREEN (Continued)
Hanganese (blue) [BaMn04.BaS04)
Myrtle Green (CrCoAl oxides)
Shsmrock (CoTiZnNiAl oxides)
Titanium Pigments (blue) (Ti02 with
CaO.A12031
Titanium Pigments (green)
.....
I-'
tV
Titanium Pigments (light green)
(TiOZ with Nt and Co)
Ultrsmarine Blue (blue) (NaAISiOS)
[Complex aluminum sulfo-silicate
produced by heating Ultramarine
Green in presence of sulfur)
Ultramarine Green (green)
[Approximately
Na7Al6Si60Z4S3)
VIOLET
Cobalt Lithium Phosphate (CoLiP04)
Cobalt Phosphate (C03(P04)2)
Manganese Violet (HnHPz07.NH3)
[Mineral Violet)
Ultramarine Violet (Complex aluminum
sulfosllicate)
TABLE C-5 (Continued)
Color Index
Pig. Blue 33, 7711Z
Pig. Green 50, 77377
Pig. Green 50, 77377
Pig. Blue 29, 77007
77013
Pig. Violet 14, 77360
Pig. Violet 47, 77363
Pig. Violet 48, 77352
Pig. Violet 14
Pig. Violet 16, 77742
Pig. Violet 5
Toxicity
Low
Low
Oral, rat
TD50:387 mglkg
Toxic Effect: Behavioral
Symptoms; Gastrointestinal
Tract; Metabolism and
Nutrition
I. . ~
, ".1,;.
,"II
, ~ ~ I
f; I ~ I'
I ,h j/I
I, ' "Ii
\, l
,,"iJ'
Concern
OSHA Regulation
Tumorigen
Mutagen
100 ug(Co)/m3 TWA
5 mg(Mn)/m3 Ceiling
. .
I'.
(CAS No.)
t
~ .
\
I
(57455-37-5 J
(1308-38-9)
(138Z4-63-() )
.[ 13455-36-2)
,.
(10101-66-3 )
[12769-96-9 )
"or'
\
'.
(Continued)
,. . ..
., I
.' "t
'~,
, , ,I
, .~":'
-------
j
1
1
1
i
~
VIOLET (Continued)
Ultramarine Pink (Complex aluminwa
sulfosilicate produced by heating
Ultramarine Green at 2oo-250.C for 4
days in the presence of amaoniwa
chloride(
RED, REIHJRANGE
Cadmium Mercury (maroon, red, orange)
(CdS and HgS(
Cadmium Sulfoselenide (maroon, red,
orange) (CdSe and CdS)
-..J
~
W
Cadmium Sulfide (orange) (CdS(
Chrome-tin (pink)
Ch roIlS Or ange [ PbCrO 4' PbO)
Copper Haroon [CuK2Fe(CN)61
Hematite [Fe203)
Color Index
Pig. Violet IS, 77007
Pig. Red 113, 77201
Pig. Orange 23, 77201
Pig. Red 108, 77196,
77202
Pig. Orange 20,
77106, 77196, 77198,
77199
Pig. Orange 21, 77601
Pig. Red 121, 77320
See Iron Oxide
TABLE C-5 (Continued)
Toxicity
Toxic
Toxic
Oral, mouse
LD50: 2425 I8g/kg
Toxic Bffect: Behavioral
Sy.ptollS i .Metabolis. and
Nutrition
Toxic
Subcutaneous, rat
TOto: 90 .g/kg
Toxic Bffect: Carcinogenic
Toxic
Subcutaneous, rat
TD: 135 '"8/kg
Toxic Bffect: Neoplastic
Concern
Ingestion
Inhalation
Tumorigen
Mutagen
I'bsi ti ve Animal
Carcinogen
Carcinogen
Mutagen
OSHA Regulation
200 ug(Cd)/m3 TWA
200 ug(Cd)/.3 TWA
200 ug(Se)/m3 TWA
200 ug(Cd)/m3 TWA
(dust)
0.5.g(Cr(Vl»/.3
TWA
50 ug(Pb)/.3 TWA
100 ug(Cr03)/.3
Ceiling
1.0 .g(Cu)/.3 TWA
5 mg(Fe )/.3 TWA
10 .g(Fe)/.3 STBL
(recommended)
(CAS No.1
, ".
[1306-24-7)
[12626-36-71
[1306-23-6 )
(1344-38-3 )
(18454-12-1 )
(1317-60-8 )
(Continued)
'"
-------
j
!
I
I
-j
. j
J
. !
......
~
.po.
,
i
!
i
j
I
!
I
i
Colorant
RED, -REO-QRANGE (Continued)
Iron Oxide (maroon, red, light red)
[Fe20)1
Mercuric Sulfide [HgSI
Molybdate Orange [PbCr04.PbO.
PbMo041
Molybdate Orange (coated)
Red Ochre (natural) [Fe20)1
Red Lead (synthetic) (Pb)041
Ultramarine Red [Complex aluminum
sulfosilicate produced by heating
Ultramarine Green at 70-200.C for 4
days in presence of HCl or by reac-
tion with gaseous HNO) at higher
temperature 1
YELLOW
Burnt Umber (natursl) [Fe20).H201
Cadmium Sulfide (yellow) [CdS and ZnSI
(Cadmium Yellowl
TABLE C-5 (Continued)
Color Index Toxicity Concern OStIA Regulation [CAS No. I
i
f'o.:'
'-,
Red 101, 71419 Subcutaneous, 5 mg(Fe)!m) TWA [1309-)7-11 t
Pig. rat Tumorigen .-
Pig. Red 102, 77419 T0Lo,I)5 mg!kg Inhalation 10 mg(Fe)!m) STEL t...
Toxic Effect: Equivocal Sus pec ted Human (recommended) i'
Tumorigenic Agent Carcinogen i:
Il1ghly Toxic Ingestion 0.1 mg(Hg)!m) TWA (1)44-48-5 I
Inhala tion
Skin Absorption
Pig. Orange 21, 71601 Toxic Ingestion 50 ug(Pb)!m) TWA [12656-85-81
Pig. Red 104, 71605 5 mg(Mo)!m) TWA
100 ug(Cr(VI»!m)
Ceiling
Same as Molybdate
Orange
See Iron Oxide 5 mg(Fe)!m) TWA [1309-)7-11
Pig. Red 101, 71491 10 mg(Fe)!m) STEL
Pig. Red 102, 77491 (recommended)
Pig. Red 105, 71578 Intraperitoneal, mouse 50 ug(Pb)!m) TWA [1314-41-6 I
L050:6)0 IDg!kg
Pig. Red 5, 12490
See Iron Oxide
PIg. Yellow 42, 77492
Pig. Yellow 4), 77492
5 IDg(Fe)!m) TWA
10 IDg(Fe)!m) STEL
(recomlDended)
[1309-)7-11
Pig. Yellow 37,
71117, 77199
200 ug(Cd)!m) TI~A
[1306-2)-6 I
Toxic
Subcutaneous. rat
TOto: 90 IDg!kg
Toxic Effect: Carcinogen
Ingestion
Inhalation
Tumorigen
Mutagen
Possible Carcinogen
(Continued)
-------
"
TABLE C-5 (Continued)
Colorant Color Index Toxicity Concern OSHA Regulation [CAS Ho.)
-
YELLOW (Continued)
Ceramic Buff [Yellow buff) Toxic Ingestion
[Sb, Ti, Cr oxides) Inhalat ion
Chrome Yellow [PbCr04) Pig. Yellow 34, Toxic Hutagen ~O ug(Pb)/m3 TWA [77~8-97-6)
77603, 77600 Subcutaneous, rat Ingestion 100 ug(Cr03)/m3
TDu,: 13~ mg/kg Inhalation Ceiling
Toxic Effect: Heoplastic Positive Carcinogen
Chrome Yellow (heat resistant) Pig. Yellow 34 Positive Carcinogen ~O ug(Pb)/m3 TWA (17~8-97-6)
[PbCr04), coated 100 ug(Cr03)/m3
Ceiling
Iron oxide (yellow) (FeZ03.xHzO) Pig. Yellow 4Z, 7749Z Subcutaneous. rat Inhalation ~ mg(Fe)/m3 TWA [1309-37-11
TDu,: 13~ mg/kg Tumor igen 10 mg(Fe)/m3 STEL
Toxic Effect: Equivocal (recommended)
Tumorigenic Agent
'-J Lead Chromate See Chrome Yellow Toxic Ingestion ~O ug(Pb)/m3 TWA [77~8-97-6)
.... Inhala tion 100 ug(Cr03)/m3 ..,.
lJ1 Positive Carcinogen Ceiling
Lead Nolybdate Toxic Inhalation 100 ug(Pb)/m3 TWA :'"
(recommended)
, i
Ocher [FeZ03.HZO) Pig. Yellow 43 Nontoxic Inhalation ~ mg(Fe)/m3 TWA [1309-37-1) >t
See Iron Oxide 10 mg(Fe)/m3 STEL I
(recommended) ,rip
Sienna [FeZ03) Pig. Yellow 43 ~ mg(Fe )/m3 TWA (1309-37-1) ~\I
See Iron Oxide 10 mg(Fe)/m3 STEL
(recommended)
Titanium Pigment (light yellow) Pig. Yellow ~3, 77788
(Hickel titanate)
(HiO.TiOZ) (buff) (Hi, Sb, Ti
oxides) [Fe, Zn, Ti oxides) and (Fe,
Cr, Ti, Sb, Zn oxides)
Zinc Chromate (yellow) [ZnCr04 Pig. Yellow 36, 779~~ Toxic Ingestion 100 ug(Cr03)/m3 [13~30-6~-9)
(complex») Intravenous, mouse Inhalat ion TWA
TDu,: 30 mg/kg. Ca rc inogen
(Continued)
-------
TABLE C-5 (Continued)
Colorant Color Index Toxicity Concern OSHA Regulation [CAS No.)
BROWN
Iron Oxide (buff, brown) (FeO)x' Pig. Brown 6, 71491, Inhalation S mg(Fe)/m3 TWA [ l309- 38-2)
(Fe203)y) 71492, 77499 Tumorigen 10 mg(Fe)/m3 STEL
Pig. Brown 7, 71ft91 (recomme nded)
Limonite (hematite brown) Pig. Brown 6, 77491 S mg(Fe)/m3 TWA (l317-63-1)
Pig. Brown 7, 77491 10 mg(Fe)/m3 STEL
(recommended)
Ocher [Fe203) See Iron Oxide S mg(Fe)/m3 TWA (1309-37-1)
10 mg(Fe)/m3 STEL
(recommended)
Sienna (natural) (Fe203) See Iron Oxide S mg(Fe)/m3 TWA (1309-37-11 .~
10 mg(Fe)/m3 STEL !,
(recommended) I;;
Titanium Pigments (brown) [TI02 Pig. Brown 24 .
'-I with up to 10% Fe) :I, . 'I
...... [rutile) ~t
0\
Umber [Fe203 with silica, alumina, Pig. Brown 43 S mg(Fe)/m3 TWA (12713-03-0) ,I
manganese oxides and lime) 10 mg(Fe)/m3 STEL:' fl,
(recommended) " 'II
;~
ORGANIC PIGMENTS
BLACK
Aniline Black Pig. Black I, S0440
Bone Black [8S% Ca3(P04)2 and Pig. Black 9, 71267 Nontoxic
Cac03 with 12-23% C)
Carbon Black (furnace black) (C) Pig. Black 7, 77266 Intravenous, mouse 3. S mg/m3 TWA (l333-86-4)
LOSO:440 mg/kg 17440-44-0)
Carbon Black (lamp carbon black) IC) Pig. Black 6, 71266 Intravenous, mouse 3.S mg/m3 TWA (7440-86-4)
LOSO: 440 mg/kg
Channel Black IC] Intravenous, mouse 3.S mg/m3 TWA (1333-86-4)
LOSO:440 mg/kg
Thermal Black Intravenous. mouse 3.S mg/m3 TWA (7440-86-4)
LOSO:440 oig/kg
(Continued)
-------
Colorant
-
BROWN
Azoic Brown [Honoazo)
Dlaazo Brown
BLUE, GREEN
Alumina Lake [Honoazo)
Cromophtal Blue A3R
Cromophtal Green GF
Dianiaidene Blue [Dlsazo)
......
......
......
FD&C Blue 1 Aluminum Lake (food blue 2)
[Ethyl(4-p-(ethyl(m-sulfobenzyl)
amino)- a -(o-sulfo-phenyl )benzyl1dene)
-2,5-cyclohexadien-l-ylidene)(m-sul-
fobenzyl)hydroxide ammonIum Inner
salt, sodium saltl
FD6C Blue 2 Aluminum Lake (food blue 1)
lindigoidl
Indanthrone Blue-Red Shade
[Anthraquinone)
Indanthrone [6,15-dihydro-5,9,14,18-
anthrazine tetrone) :
[Cromophthal Blue A3RI
[Anthraquinone)
Nickel-Azo Yellow (greenish yellow)
[metal complex of p-chloroaniline
coupled to 2,4-dihydroxyquinoline)
Oracet Blue 2R
Color Index
Pig. Brown 25, 12510
Pig. Brown 32
PIg. Brown 23
AcId Blue 4, 73015
PIg. Blue 60, see
Indanthrone
PIg. Blue 25
42090:2
PIg. Blue 63, 73013
Pig. Blue 64, 68925
PIg. Blue 22, 69810
Pig. Blue 60, 69800
Pig. Green 10, 12755
TABLE C-5 (Continued)
Toxicity
Subcutaneous, rat
TDLo:5.5 gm/kg/91W-I
Toxic Effect: Neoplastic
Subcutaneous, rat
TOLQ: 5. 5 gm/kg
Concern
Positive Animal
Carcinogen
Positive Animal
Carcinogen
OSHA Regulation
[CAS No.)
[57972-00-6)
, .
[5437-88-7)
[10121-03-4)
[3844-45-9 )
[3844-45-9)
.,
[81-11-6)
[51931-46-5 )
[61125-51-7 )
(Continued)
-------
.. ,-
I
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,
,}
j
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1
)
!
1
i
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1
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'.'J
. ~
,'I
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j
',1
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"-:1
.1
.;~
..,
:!
.!
,
I
,
,
'j
"
:
. ~,
,
"
I
J
1
-..J
I-'
00
Colorant
BLUE, GREEN (Continued)
Phthalocyanine (blue)
red shsde
green shsde
metal free
Phthalocyanine (green)
Phthalocyanine Green, brominated
Pigment Green B (dark green) [Nitrosol
PTA PHA Toners (blue, green)
[triphenyl-methane, phospho-
tungstomolybdic acidl
VIOLET
Alizarine Maroon (maroon)
[Anthraquinone I
Benzimidazolone Violet [Honoazol
Carbazole Dioxazine Violet
lsoviolanthrone Violet [Anthraquinone I
(Vat pigment I
Hethyl Violet
Methyl Violet Lake
Honoazo Red, blue shade
(Benzimideazolone violet I
I
,
:.
TABLE C-5 (Continued)
!
f.
Color Index Toxicity Concern OSIIA Regulation [CAS No.1
i
01206 Subcutaneous. rat Primary Irritant [3468-11-91 I
TDto:990 mg/kg/44W-I (147-14-8 I
Toxic Effect: Tumorigenic
. Agent
Pig. Blue 15, 76160,
74160 ,
Pig. Blue 15: 3, I
74160, 76160
Pig. Blue 16, 74100 [574-93-6 I
Pig. Green 7, 74260, [1328-53-61
74160
Pig. Green 36, 74265
Pig. Green 8, 1006
Pig. Blue I, 42595
Pig. Green 2, 42040
, ~.
Pig. Violet 5, 58055
Pig. Violet 32, 12517
See Monoazo Red
Pig. Violet 23, 51319 [6358-30-11
Pig. Violet 25, 51319
Pig. Violet 33 [81-28-71
Pig. Violet 31 [1324-55-61
Vat Violet 9, 60005 [1324-17-01
Basic Violet I, 42535 Oral, mouse Mutagen [8004-87-3 I
LD50:105 mg/kg
Pig. Violet 3, 5 mg(Mo)/m3 TWA [1325-82-2 I
42535: 2
Pig. Violet 32, 12517
Pig. Red 83, 58000
(Continued)
-------
,.
J
,
,
I
I
1
i
j
1
!
j
!
I
J
1
)
J
!
j
......
I-'
\0
Colorant
VIOLET (Continued)
Oracet Violet 2R
P T H A Toners [Phosphotungstomo-
lybdic acid salt of basic dye)
[Xanthene)
Perrindo Violet [Anthraquinone)
Quinscridone Red (yellow shade)
Quinacridone (violet-maroon)
Thloindigo Violet
RED
Alizarine Red BLake
Alumins Lake [phthalein)
Anthraquinone Red
Orange RK
Anthraquinone Red
Azo Condensate Red
Ba Lithol (medium red)
Benzimldszolone Reds
[Permanent Red 11FT)
[Honoazo)
[Permanent Carmine)
TABLE C-5 (Continued)
Color Inde"
Pig. Violet 2, 45175
Pig. Violet 29, 71129
Pig. Violet 19,
16500, 46500
Pig - Violet 19,
16500, 46500
Pig. Violet 36, 73385
Pig- Red 83, 58000
See Hadder Lake
Pig. Red 172, 43439:1
Pig. Red 177
Pig- Red 168, 59300
See. Vat Orange
Pig- Red 194, 71100
See Vat Red
Pig. Red 242
Pig. Red 49, 15630
See Uthol Red
Pig- Red 171,
See Honoazo
Pig. Red 175,
See Honoazo
Pig. Red 176,
See Honoazo
Pig- Red 185,
See Honoazo
12521
12513
12516
12516
To"icity
Concern
OSHA Regulation
I
,
....,.
~, ~
,"
.!1';.,. I
[CAS 110.)
I
. ~~
, .' I
; 1,."
r
[128-95-0)
[1325-82-2 )
[1047-16-1)
[ 72-48-0)
[4216-01-7)
[4378-61-4 )
(Continued)
-------
,
r'
!
:1
,1
"I
;:J
,:j
'. .-j
.j
!
"'
"J
',\
;'"1
',~'. J
":i
,
"j
-...j
N
o
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" ,
. ~
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1
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,
1
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I
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j
j
I
Colorant
RED (Cont inued)
B.O.N. Rubine (Na Salt)
(Ca Salt)
B.O.N. Maroon (Honoazo)
[Sodium salt of scid dye)
Chlorinated Psra (light red)
(1(-2-chloro-4-Nitrophenyl)szo)
2-Naphthol)
(Honoazo)
Cromophtal Scsrlet R (Azo)
Cromophtal Red BR [Oisazo)
(Oisazo Condensation Red)
Cromophtsl Red 3B (Anthraquinone)
Cromophtal Red G (Oisazo)
Cromophtal Red GR (Oisazo)
Cromophta1 Red 2RS
Cromophta1 Rubine B
Oiantsidine (medium red)
Oisazo Condensation Red
Ohazo Reds
Oich10robenzid~ne Red
PD&C Red 3 Aluminum Lake (food red 14)
(2',4',5',7' Tetra-bromo-4,5,6,7-
tetrsch10ro fluorescein, disodtum
salt)
TABLE C-5 (Continued)
Color Index
Pig. Red 52, 15860
Pig. Red 200, 15867
Pig. Red 63, 15880
Pig. Red 4, 12085
Pig. Red 6
Pig. Red 166
Pig. Red 144
Pig. Red 177
See Anthraquinone Red
Pig. Red 220
Pig. Red 139
Pig. Red 41, 21200
Pig. Red 144
See Cromophta1 Red BR
Pig. Red 146
Pig. Red 166
Pig. Red 214
Pig. Red 220
Pig. Red 221
See Pyrazo10ne Red
45430
Toxicity
Oral. mouse
1.050:2500 Mg/kg
Concern
OSHA Regulation
Hutagen
",."
I.,
I
'I
i ":~!
, "
: ~ 1
~" '~1
! "f
} ~
(CAS No.)
(2814-77-9)
(12225-04-6)
(5280-78-4)
(6505-29-9)
(16423-68-0)
(Continued)
-------
I
1
1
j
I
I
......
N
~
Colorant
RED (ContInued)
FD&C Red 40 AlumInum Lake
Hello Bordeaux (maroon)
Irgazln Red 2BLT [Isolndollnone Red)
Lake Red C (lIght red) [5-chloro-2-«2-
Hydroxy-l-Naphtha-lenyl)Azo)4-methyl-
benzene-sulfonlc acId, barIum salt)
Lithol Red (Ba of acId dye) [Honoazo)
Lithol Rublne (Na salt of acId dye)
(bluish red) [H008Z0)
Lithol Rublne, Sr [Honoazo)
Hadder Lake (alIzarIne red)
[I,2-dlhydroxy-anthraqulnonel
Honoazo Red (blue and yellow shade
reds)
Honoazo Red (blue shade red)
Na, Ca Llthols (lIght red-maroon)
Naphthol Red (blue shade red Ba salt)
Naphthol Red (blue shade red Ca salt)
Naphthol Red (bluIsh red)
Naphthol Red (bordeaux shade)
Naphthol Red (dark red)
Color Index
16035
PIg. Red 54, 14830
PIg. Red 180
PIg. Red 53: I,
15585:1
PIg. Red 49, 15630
PIg. Red 57, 15850
PIg. Red 52, 15850
PIg. Red 83, 58000
TABLE C-5 (Continued)
Toxicity
Oral, rat
TDto:130 gm/kg/2Y
ToxIc Effect: Tumorlgen
Eye, rabbit
500 mg/24 Hours
ToxIc Effect: Severe
Irritation
Concern
OSHA Regulation
[CAS No.)
IndefInIte Anlma¥
Ca rc Inogen
[ 5160-02-11
Hutagen
[1248-l8-6)
PrImary Irritant
Hutagen
(72-4g-o )
PIg. Red 187
PIg. Red 188, l2467
PIg. Red 246
PIg. Red 247
PIg. Red 175, 12513
PIg. Red 171, l252l
PIg. Red 176, 12515
PIg. Red 185, 12516
PIg. Red 49, l5630
PIg. Red l51
PIg. Red 68, l 552 5
PIg. Red 150 [56396-10-2)
PIg. Red 210 [61932-63-6)
PIg. Red 14, 12380
PIg. Red 23, 12355 [64 7l-49-4 )
(Continued)
-------
j
Colorant
RED (Continued)
Naphthol Red (light red)
Naphthol Red (medium red)
Naphthol Red (yellow ahade)
Naphthol Red (yellow ahade red Ca aalt)
Oracet Red 3B
Para Red (medium to deep red)
Permanent Carmine 1IF4C
....,
N
N
Permanent Red HFT
Permanent Red BL
Permanent Red HFH
Permanent Red 2B-Ba Salt (light red)
Permanent Red 2B-Ca Salt (medium red)
Perinone Red FTC
Perinone Red (Anthraquinone 1
Perylene, nitrogen free
perylene Vermillion
TABLE C-5 (Continued)
Color Index
Pig. Red 17, 12390
Pig. Red 22, 12315
Pig. Red 170
Pig. Red 210
Pig. Red 7, 12420
Pig. Red 9, 12460
Pig. Red 68, 15525
Pig. Red I, 12070
Pig. Red 185
See Hanoazo
Pig. Red 175
See Honoazo Red
Pig. Red 149
See Perylene Scarlet
Pig. Red 171
See Honoazo
Pig. Red 48: I,
15865:1
Pig. Red 48:2, 15865
Vat Red 15
Pig. Red 194, 71100
See Va t Red
Pig. Red 175
Pig. Red 123, 71145,
71140
Toxicity
Concern
OSHA Regulation
Hutagen
(CAS No.1
(12236-67-81
(61932-63-61
. .
( 116-85-8 1
(6410-10-21
(7585-41-31
(3564-21-41
(7585-41-3)
(3564-21-4 )
(23108-89-21
(Continued)
-------
Colorant
-
RED (Continued)
Perylene Haroon
Pe ry lene
Perylene Scarlet
Perylene Hediu~ Red
Pig~ent Scarlet 3B Lake (bluish red)
(Hordant Red 9 and AI2(OH)3)
(Honoazo)
Pigment Scarlet-Ba Salt (Honoazo)
Pyranthrone Orange
.......
N
UJ
Pyrazolone (medium red) (Olsazo)
Pyrazolone Red (yellow shade)
(Diaazo)
Quinacridone Hagenta (Quindo Hagenta)
R.K. Anthranthrone (Anthraquinone)
Red Lake R (light red)
Thioindigo Red
Thioindigo Haroon
Thioindigo Pink
Thioindigoid
Toluidine Haroon (light red)
(Honoazo)
TABLE C-5 (Continued)
Color Index
Pig. Red 179, 71130
Pig. Red 224
Pig. Red i49, 7U}7
Pig. Red 190, 71140
Pig. Red 60, 16105
Pig. Red 60: I,
16105: 1
See Pig. Scarlet 38
Pig. Red 197, 59710
Pig. Red 38, 21120
Pig. Red 37, 21205
Pig. Red 122, 73915
Pig. Red 202
Pig. Red 168
See Vat Orange
Pig. Red 64
Pig. Red 86, 73375
Pig. Red 88, 73312
Pig. Red.198, 73390
Not assigned, 73390
Pig. Red 181, 73360
Pig. Red 131, 73360
Pig. Red 3, 12120
Toxicity
Concern
OSHA Regulation
Hutagen
Tumorigen
(CAS No.)
( 5521-31-31
(198-55-0 )
112225-02-4 )
(6424-77-71
(1836-22-2 )
(1324-33-0)
(980-26-7)
(2425-85-6 J
(Continued)
-------
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. :,;,,"
j
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,
'j
j
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1
.
,
i
j
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......
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']
Colorant
RED (Continued)
Toluidine Haroon (Continued)
[Substituted amines coupled to
naphthol)
Vat Orange [AnthraquinoneJ
Vat Pink
Vat Red (medium red)
ORANGE
Anthanthrone Orange (brominated)
Anthramide Orange [Vat pigment)
Benzidine Orange
Benzimidazolone Orange
Brominated Pyranthrone
Cromophtal Orange 4R
Dianisidine Orange
Dianisidine Orange GG
Diarylide Orange
Diarylide Orange RL
Dinitroaniline Orange [HonoazoJ
[1-«2,4-Dinitrophenyl)Azo)-2-
Naphthol)
Disazo Orange 4R
GR Perinone Orange [vat pigment)
[Anthraquinone)
Homolog-Red Lake C (yellowish red)
TABLE C-5 (Continued)
Color Index
Pig. Red 13, 12395
Pig. Red 5, 12490
Pig. Red 168, 59300
Pig. Red 181, 13360
See Thioindigo Pink
Pig. Red 194, 11100
Pig. Orange 168,
59300
Vat Orange 15, 69025
Pig. Orange 13, 21110
See Diary1ide Orange
Pig. Orange 36, 11180
See Honoazo Orange
Vat Orange 14, 59110
Pig. Orange 16, 21160
Pig. Orange 14
Pig. Orange 13, 21110
Pig. Orange 34
Pig. Orange 5, 12015
Pig. Orange 31
PIg. Orange 43, 11105
Vat Orange 7, 71105
Pig. Orange 46, 15602
Toxicity
Concern
OSHA Regulation
Hutagen
(CAS No.)
[4318-61-4 )
(2319-78-4)
(3520-72-1 )
[1324-33-0 )
16831-31-2 )
115193-73-4 )
(3468-63-1 J
112286-58-1 )
142612-21-5 )
(Continued)
-------
Colorant
ORANGE (Continued)
Indofast Double Scarlet
Irgazin Orange RLT
Isoindolinone Orange
Hodified Azo Orange
Honoazo Red (Orange)
Honoazo Orange [CIJH3N60sCl)
Orange RK
'"
N
VI
Perinone Orange CR [Anthraquinone)
Pyranthrone Orange [Vat Pigment)
Pyrazolone Orange [Dlsazo)
Tolyl Orange
Qulnacridone Gold
YELLOW
a-Amino Anthraquinone (yellow)
Anthrapyrlmldlne (yellow)
[Anthraquinone)
Anthrapyrimidine (yellow, medium
yellow)
Anthraquinone Yellow
TABLE C-5 (Continued)
Color Index
Vat Orange 4, 59110
Pig- Orange 61
Pig- Orange 42
Pig- Orange 38, 11818
Pig- Orange 36, 11180
Pig- Orange 60
Pig- Orange 62
Vat Orange 3, 59300
Vat Orange 1, 11105
Pig- Orange 43
See CR Perlnone
Orange
Vat Orange 9, 59100
Pig - Orange 40
Pig- Orange 13, 21110
See Diarylide Orange
Pig- Orange 30
Pig- Orange 48
Pig- Yellow 108,
68420
Vat Yellow 20, 68420
Pig- Yellow 108
Toxicity
Concern
OSHA Regulation
[CAS No.)
[128-10-1)
[4216-01-1)
(Continued)
-------
Colorant
YELLOW (Continued)
Azo Yellow
Azoic Yellow (light yellow)
Azoic Yellow (medium yellow)
Azoic Yellow, specislty (light yellow)
Azomethine Yellow (lrgszin yellow SGLT)
.......
N
(j\
Benzidine Yellow (Oieazo)
(2,2'-«3,3'-Oi-chloro-4,4'-bi-
phenylene)diazo)bie-acetoacetanilide)
(Olarylide Yellow Anilide)
Benzidine Yellow HR
Benzidine Yellow AAHX (Oieazo)
Benzidine Yellow AAOA
Benzidine Yellow AAOT
Cromophtal Yellow 3G (yellow) (Oieazo
Condeneatlon Yellow)
Cromophtal Yellow 6G (Oleezo)
Cromophtal Yellow GR (Oleazo)
Oiaryllde Yellow
Olaryllde Yellow AAHX (light
transparent)
TABLE C-5 (Continued)
Color Index
----
Ois. Yellow 3, 11855
PIg. Yellow
PIg. Ye llow
21126
Pig. Yellow
81, 21127
113,
16, 20040
PIg. Yellow 120,
11783
Plg. Yellow 151
Pig. Yellow 154
PIg. Yellow 129
Pig. Yellow 12, 21090
Pig. Yellow 13
See Olarylide Yellow
Xy lid ide
PIg. Yellow 17
See Oisrylide Yellow
An1s1dine
PIg. Yellow 14
See Dlaryllde Yellow
Ortho Toluldlde
PIg. Yellow 93
Pig. Yellow 94
PIg. Yellow 95
Plg. Yellow 106
Plg- Yellow 127
Toxicity
Concern
NegatIve CarcInogen
OSIlA Regulation
(CAS No.)
(6358- 58-6 )
(20139-68-9)
(5102-83-0)
(4531-49-11
(5468-75-7)
(5580-57-4) -
(5580-58-5)
(5280-80-8)
(Continued)
-------
Colorant
YELLOW (Cant inued)
Diarylide Yellow NeG
Diarylide Yellow Anilide (light yellow)
(Diarylide Yellow AAAI
Diarylide Yellow Anisidide (light
yellow) (Diarylide Yellow AAOAI
Diarylide Yellow. HR (medium yellow)
Diarylide Yellow Ortho Toluidide
(yellow)
Disrylide Yellow Xylidide (light yellow)
.......
N
.......
Disazo Yellows (other)
FD&C Yello.. '5 Aluminum Lalte (food
yellow 4) (Honoazo Aluminum Salt 1
FD&C Yellow '6 Aluminum Lalte (.food
yellow 3) (Honoazo Aluminum Salt 1
Flavanthrone (yellow) (Anthraquinone I
Hansa Yellow lOG (primrose. light
medium yellow)
Hansa Yellow II
Hansa Ye 11 ow 411
Hansa Yellow G (Honoazol
Irgazln Yellow 5GLT
Irgazin Yellow 2Gl1T
Color Index
Pig. Yellow 16. 20040
See Azoic Yellow
Pig. Yellow 12, 21090
(See 8enzldene
Yellow 1
PIg. Yellow 11. 21105
Pig. Yellow 83.
21108. 21118
PIg. Yellow 14, 21095
Pig. Yellow 13, 21100
Pig. Yellow 155
PIg. Yellow 128
Pig. Yellow 100.
19140:1
PIg. Yellow 104,
15985: 1
PIg. Yellow 24, 10600
Pig. Yellow 3, 11110
Pig. Yellow 10. 12110
PIg. Yellow 60, 12102
Pig. Yellow 1, 11680.
11860
PIg. Yellow 129
See Azomethlne Yellow
Pig. Yellow 109
See Isolndollnone
Ye 110w
TABLE C-5 (Continued)
Toxicity
Oral, mouse
LD50:12150 mglltg
Intraperitoneal. rat
LD50:3800 mglkg
Concern
IndefInIte Carcinogen
OSHA lIegulation
(CAS No.1
(6358-85-61
(1934-21-01
(2183-94-01
(415-11-21
(6401-14-51
(2512.-29-0)
(Continued)
-------
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Colorant
YELLOW (Continued)
lrgazin Yellow 2RLT. JRLT
(laolndolinone)
laolndollne Yellow
Isolndolinone Yellow (lrgazi n Yellow
2GRT)
laolndolinone Yellow (lrgazin Yellow
2RLT, 3RLT)
Hodl fled Azo (light yellow)
Honoazo Yellow (llght yellow)
[Permanent Yellow FGL)
Permanent Yellow FGL
Permanent Yellow DR
Permanent Yellow H2G
Permanent Yellow HIOCH (Dlaazo)
Qulnophtalone Yellow
Sandorln Yellow GGL [laolndollnone)
Palltol Yellow 1090
TABLE C-5 (Continued)
Color Index
--
Plg. Yellow 110
See laolndollnone
Yellow
Plg. Yellow 139
Plg. Yellow 109
Plg. Yellow 110
Plg. Yellow 97.
11797, 11767
Pig. Yellow 97
See Honoazo Yellow
Plg. Ye llow 83
See Dlaryllde Yellow
HK
Plg. Yellow 120
See Azoic Yellow
Plg. Yellow 113
See Azoic Yellow
Plg. Yellow 138
Pig. Ye llow 109
Pig. Yellow 138
See Qulnophtalone
Toxicity
Concern
OSHA Regulation
(CAS No.)
[12225-18-2)
~ .
(Continued)
-------
Colorant
DYES (SOLUBLE)
Acetate (wide color range)
Acid Chrome and Direct (wide color
range)
Baaic Dyes (wide color range)
Anthraquinone (yellow-red, green, blue,
brown)
BROWN-BLACK
Azo Dyes [4-(1-Naphthylazo)
m-phenylene~diamine)
.....,
N
\0
[2,3-dihydro-2,2-dimethyl-6-«4
(phenylazo)-l-Naphthyl)azo)-
perimidine)
Azo Hetal Complex Dyes
Nigrosine
Induline
YELLOW
Anthraquinone Yellow Dyea
HonoAzo Dyes
[N,N-dimethyl-p-phenyl~7.o aniline)
[1-phenylazo)-2-naphthol)
Color Index
--
Sol. Brown I, 11285
Sol. Black 3
Sol. Brown 11
Sol. Black 27
Sol. Black 28
501. Black 5, 50415
Dla. Ye llow 64
Sol. Yellow 2, 11020
Sol. Yellow 16, 12700
Sol. Yellow 56, 11021
Sol. Yellow 14, 12055
TABLE C-5 (Continued)
Toxicity
Oral, rat
T~: 34 gm/kg
Toxic Effect:
Carcinogen
Intravenous. mouse
LD50:63 mg/~g
Oral, rat
LD50:200 mg/kg
Subcutaneous, mouse
T~:6,ooO mg/kg/57W-l
Toxic Effect: Equivocal
Tumorige~lc Agent
Concern
In~eftnite Carcinogen
Positive Animal
Carcinogen
Hutagen
Positive Animal
Care inogen
OStIA Regulation
[CAS No.1
[646-57-51
[4197-25-51
[60-11-71
1842-07-91
(Continued)
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Colorant
-
YELLOW (Continued)
Disazo Dyes (Disazo)
Azo (N-(4«2-Hydroxy-5-methyl phenyl)
azo)phenyl) acetamide)
Azo Ketal Complex Dyes
Brilliant 5ulfofavine (2,3-dihydro-6-
amino-1,3-dioxo-2-p-tolyl)-lH Benz-
(de)iso-quinoline-5-su1fonic acid,
monosodium aalt)
Hetanil Yellow
Honomethine
Pa1acet Yellow 5F1861
Palacet Yellow 5F1862
Quino1ene Yellow
ORANGE
Anthraquinone Dyes Perinone
(Turn 5ignal Color)
TABLE C-5 (Continued)
Color Index Toxicity Concern 05HA R~gulation (CA5 No.) \
501. Yellow 30, 21240
501. Yellow 11
501. Yellow 12 (61813-98-1)
Sol. Yellow 29
Dis. Yellow 23
D1s. Yellow 3 Oral, rat lndetlnite Carcinogen (2832 -40-8)
LDLo:180 gm/kg/2Y-C Hutagen
Toxic Effect: Carcinogen
D1s. Yellow 34
501. Yellow 65
501. Yellow 19 ,
Sol. Yellow 81
So 1. Ye 11010 82
Sol. Yellow 48
501. Yellow 89
Sol. Yellow 95
Acid Yellow 1 Intravenous, mouse (2391-30-2)
LD50: 110 mg/kg
Acid Yellow 36
Intraperitoneal, mouse
LD50:1000 mg/kg
Negat! ve Animal
Care inogen .
(581-98-4)
501. Yellow 93
Dis. Yellow 13, 58900
(3688-19-1)
Dh. Yellow 116
Hegat! ve Anima 1
Carcinogen
501. Yellow 33, 41000
Sol. Orange 60
(61969-41-9)
"
(Continued)
-------
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Colorant
ORANGE (Continued)
Azo Dyes Il-(2,4-xylylazo)-
2-naphthol)
Azo Metal Complex Dyes
Xanthene Dyes
RED
Anthraquinone Reds Perinone
ITsillight Red)
Amaplast Rubinol R
Azo Dyes Disazo
Il-«4-(phenylazo) phenyl)azo)-2-
naphthalenol)
Il-«4(0-tolylazo)-0-tolyl)azo)-2-
naphthol)
IN-ethyl-l-«p-(phenylazo)phenyl)
azo)-2-naphthylamine)
Azo Metal Complex Dyes
Color Index
Sol. Orange I, 11920
Sol. Orange 7
Sol. Orange 54
SoL Orange 56
Sol. Orange 59
Sol. Orange 63
Sol. Red 135
SoL Red 195
Sol. Red Ill, 60505
Sol. Red 52, 68210
Sol. Red I, 12150
Sol. Red 27, 26125
Sol. Red 23, 26100
Sol. Red 24, 26105
Sol. Red 3, 12010
SoL Red 19
Sol. Red 22
Sol. Red 40
Sol. Red 26
Sol. Red 118
Sol. Red 119
Sol. Red 122
Sol. Red 125
TABLE C-5 (Continued)
Toxicity
Implant, mouse
TI>[..,: 80 109/kg
Toxic Effect:
Carcinogen
Intraperitoneal, rabbit
LDLo:250 109/kg
Subcutaneous. rat
TDLo:512mg/kg/5SW-I
Toxic Effect: Carcinogen
Oral, rat
TDLo: 15 gm/kg/51701-C
Toxic Effect: Equivocal
Tumorigenic Agent
Concern
Conflicting Data
Posi ti ve Animal
Carcinogen
Indefinite Carcinogen
Positive Animal
Ca rci nogen
Negative Animal
Ca rcinogen
Indefinite Carcinogen
Mutagen
OSllA Regulation
ICAS No.)
(3118-97-6 )
154578-43-7 )
182-38-2)
11229-55-6)
185-86-9 )
185-83-6 )
. i
16368-72-5)
14477-79-6)
(Continued)
-------
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Colorant
RED (Continued)
Congo Red (Sodium diphenyl-
bis-alpha-naphthalamine sulfonate)
Palacet Pink 8F-7867 (1.5-Diamino-
anthraquinone)
Palacet Red 8F-7874
Rhodamine B Base
Vat Red
Xanthene (0-(6-(ethylamino)-
3(ethylim1no)-2.7-dimethyl-3H-xan-
thene-9-yl)-Benzoic acid. ethyl
ester. monohydrochloride)
VIOLET
Anthraquinone 11-Bydroxy-4-(p-
Toluidino)anthraquinone)
Carbazole Dloxazine
Pa1acet Red Violet SF-7868
(1.4 Diaminoanthraquinone)
Pa1acet Violet 8F-7870
Palacet Blue 8F-7872
TABLE C-5 (Continued)
Color Index
Direct Red 28
Dis. Red 4. 60755
Dis. Red 11. 62015
Dis. Red 60
801. Red 49. 45170B
Vat Red I, 73360
Acid Red 52
Basic Red 1
Dis. Violet 31
Sol. Violet 13. 60721
Sol. Violet 14, 61705
Sol. Violet 23, 51319
Dis. Violet I, 61100
Dis. Violet 4, 61105
801. Violet 13, 60725
See Anthraquinone dye
Toxicity
Toxic
Intravenous, rat
LD50:190 mg/kg
Intraperitoneal, rat
LD50:2600 mg/ltg
Intraperitoneal, rat
LD50:13oo mg/kg
Eye. rabbit
500 mg/24 Hr.
Toxic Effect:
Irritation
MUd
Intravenous, mouse
LD50:310 mg/kg
Intraperitoneal. mouse
LDto:2 mg/kg
Intraperitoneal. rat
LD50: 1300 mg/ltg
Intraperitoneal. rat
LD50:1000 mg/kg
Intraperitoneal, mouse
LDto: 512 mg/kg
~
Possible Carcinogen
Allergen
Mutagen
Primary Irritant
Primary Irritant
Positive Animal
Carcinogen
Mutagen
Primary Irritant
Mutagen
08HA Regulation
(CAS No.)
(573..58-0 )
(2379-90-0)
(129-44-2 )
{.
(17418-58-5)
,
r
f.,
[,.0-
r-.
r;.
r
L
(3520-42-1)
(989-38-8)
f'
(81-48-1)
(128-95-0 )
11220-94-6)
(81-48-1 )
(Continued)
-------
Colorant
VIOLET (Continued)
Rhodamine B (Xanthene)
(9-(0-Carboxyphenyl)-6-(Diethyla-
mino)-3H-Xanthen-3-ylidene)diethyl
ammonium chloride)
BLUE AND GREEN
Anthraquinone
j'
1
(Alizarine)
Amaplast Blue RJK (Anthraquinone)
Amaplast Bordeaux BPS
.....
VJ
VJ
Azo Dyes
Azo Metal Complex Dyes
Phthalocyanine
Palacet Blue 5F-7871 (1-«2-Hydroxy-
ethyl)amino)-4-(methylamino)
anthraquinone)
Thermoplast Brillant Yellow lOG
(Anthraquinone)
Triphenylmethane Dye
Unspecified
Xanthene Dyes
FLUORE5CENT5
Bisazoles
Vinylenebisbenzoazoles
TABLE C-5 (Continued)
Color Index Toxicity Concern OSHA Regulation (CAS No.)
Basic Violet 10 Intravenous I rat Posi t1 ve Animal (81-88-9 )
LD50: 89 mg/llg Carcinogen ..
Mutagen t
~ .
Sol. Blue 56 (14233-37-5)
Sol. 81ue 58
Sol. 81ue 59
Sol. Green 3, 61565 Oral, rat Primary Irritant (128-80-3)
LD50:3060 mg/llg
Sol. Green 28
Sol. Blue 16
Sol. Blue 35
Sol. Blue 67
Sol. Blue 53
Sol. Blue 70
O1s. Blue 3 Oral, rat Primary Irritant (2475-46-91
LD50:3000 mg/llg
Sol. Green 5, 59075
Victoria 81ue B (6786-83-01
Sol. Blue 3, 61505
Sol. Green 4 (81-37-8)
(Continued)
-------
-.
Colorant
. FLUORESCENTS (Continued)
Coumarins MOAC (4-methyl-7-
diethylamino coumarin)
(3 phenyl-7-amino coumarins)
Stilbenes Derivatives of
stilbene-naphthotriazole (4-naph-
tho-triazolylstilbene)
Fluorescent (dyed organic glass
particles, full color range)
Fluorescent
(Pure dye, assorted color range)
(Sulfides)
. i
-......
W
~
(zinc sulfide)
PHOSPHORESCENT
(zinc cadmium sulfide or calcium
strontium sulfide)
PEARLE SCENTS
Bismuth Coated Mica (pearly luster)
-.j
Bismuth Coated Talc (pearly luster)
Bismuthoxychloride (pearly luster)
(BlOCII
Lead Carbonate I (brilliant pearl)
(xPbC03.yPb(OH)21
Lead Carbonate II (opaque pearl)
(xPbC03.yPb(OH)2)
Color Index
TABLE C-5 (Continued)
Toxicity
Oral, rat
LD50' 5 mg/kg
Toxic
Low (ZnS)
Toxic (SrS), (CdS)
Toxic
Oral, guinea pig
LDLo' 1000 mg/kg
Oral, guinea pig
LOu,' 1000 mg/kg
Concern
OSHA Regulation
Irritant
0.5 mg(Cd)/m3 TWA
Inhala Uon
Si licosia
20 mp,pcf
50 ug(Pb)/m3 TWA
50 ug(Pb)/m3 TWA
, .
I .
1.
F
..
(CAS No.)
(91-44-11
(12001-26-2 )
(mica)
(59B-63-{) )
(598-63 -() )
(Continued)
-------
TABLE C-5 (Continued)
Colorant Color Index Toxicity .,
Concern OSHA Regulation [CAS No.)
PEARLESCENTS (Continued)
Hetallic Oxide Brown-FDA (high heat
stable) [x-Ferric oxide crystallized
from a borox melt) and other
compositions
Hetallic Oxide Browns (high heat
stable)
Titanium Dioxide/Hica Composite (pearly Nontoxic 10 mg(T102)/m)
luster) 1\IA
Titanium Dioxide/Hica/lnorganic Pigment 10 mg(T102)/mJ
1\IA
HETALLICS
Aluminumi Plaatic Grades (silver) Pig. ~letal I, 77000, 1100 toxic Fine Powders - Fire 10 mg/mJ 1\IA [7429-90-8)
...., 77001 Risk (recommended)
W
1.11 Bronze; Plastic Grades (red gold to Pig. Hetal 2, 77400 I mg(Cu)/mJ 1\IA
yellow gold)
[pale gold bronze (92% Cu, 6% Cn, 2%
AI»)
[rich pale gold bronze (90% Cu, 9.25%
Zn, 0.75% AI»)
[rich gold bronze (77% Cu, 22% Zn, 1%
AI»)
(green gold bronze (68.75% Cu, )1% Zn,
0.25% AI»)
Copper; Plas'tic Grades (coppery red) Toxic (powders) Hutagen I mg/mJ nIA [7440-50-8 J
Oral, rat Teratogen 2 mg/m) STn
TDLo' 152 mg/kg Inhalation (recommended)
Toxic Effect' Reproduc- Powder is Flammable
tive; Embryotoxicity;
Developmental
-------
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TABLE C-6. COUPLING AGENTS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
.,"
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Coupling Agent Toxicity Concern OSHA Regulation [CAS 110.1
SILAIIES I
II-B-Aminoethylaminomethylphenylethyl-
trimethoxysilane
II-B~minoethyl-Y-aDinopropyltrimeth- Oral. rst Primary Irritant [1160-24-3)
oxysilane (A-l120) LD50:1460 mg/kg
,
Aminophenyltriethoxysilane i
I
Y-Aminopropyltriethoxy~ilane. [A-nOO, Oral. rat Primary Irritant [919-30':21 !-"
A-1l12. A-1l14) LD50:1180 mg/kg ..
Amyltrimethoxysilane Oral, rat (299-95-4)
LD50: 4920 mg/kg
Bis(B-Hydroxyethyl)-Y-aminopropyltri- (1538-44-51
ethoxysllane
Y-Chloroisobutyltriethoxysilane
Chloromethylphenylethyltrimethoxysilane
Y-Chloropropyltrimethoxysilane (Z-60161 [2530-87-2)
B-Cyclohexylethyltrimethoxysilane
B-(3.4-Epoxycyclohexyl)ethyltrimethoxy- Oral, rat Primary Irritant [3388-04-3)
silane (A-I 86 J LD50:12300 mg/kg
Y-Glycidoxypropyltrimethoxysilane [A-181 J Oral. rat Primary Irritant [2530-83-8)
LD50:23 gm/kg
Y-Mercaptopropyltrlmethoxysilane Oral. rat Primary Irritant [4420-14-0 J
LD50:2830 109/kg
Y-Methacryloxypropyltrimethoxysilsne Hay Be Toxic Fire Risk (2530-85-0)
[A-1141 Oral. rat Primary Irritant
LD50:23 gm/kg
Hethylphenyltrimethoxysilane
Hethoxyphenyltrimethoxysilane None
(Continued)
j
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i
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1
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I
Coupling Agent
.,
.1
SILANES (Continued)
OctyItrlethoxysliane
PhenyItrlethoxysliane
Sulfonyl azIde sIlane (proprIetary) .
Y-Ureldopropyltrlethoxysilane [A-11601
VInyl benzyl catIonIc sIlane
Vlnylbenzylpropyltrlmethoxysllane
Vlnyltrlethoxysllane [A-lSll
.
'.
Vlnyltrlmethoxysllane
......
IN
......
Vlnyl-trls-(Z-methoxyethoxy)sllane
[A-1721
,.,
.
"'
i
.,
TlTANATES
Acrylamlno pyrophosphate tItanate
[KR-Z62A 1
Acrylojunctlonal organotltanate
pyrophosphate [KR-Z38AI
4-Aminobenzenesulfonyl dodecylbenzene-
sulfonyl ethylene tItanate [KR-ZZ6S1
4~mlnobenzoyl, Isostearoyl ethylene
tItanate [KR-Z37BSI
Dl(butyl, methyl pyrophosphato) ethylene
titanate [KR-Z6ZS 1
Dl(butyl, methyl pyrophosphato) ethylene
tItanate mono(dloctyl, hydrogen
phosphate) [KR-Z62ESI
TABLE C-6 (Continued)
ToxIcity
Oral, rat
LDSO:Z830 mg/kg
Oral, rat
LDSO:Z3 gm/kg
Oral, rat
LDSO:11300 mg/kg
Oral, rat
LDSO:2960 mg/kg
Concern
PrImary IrrItant
PrImary IrrItant
IngestIon
Skin Contact
IngetJtion
OSHA gegulation
[CAS No.1
, [780-69-81
[23179-3Z-01
[78-08-01
[2768-0Z-7 J
[1067-5)-41
(Continued)
-------
"
Coupling Agent
1
. J
: ~ 1
j
. ~
. :,j
.:j
"'-' j
'.1
.,
'":2
'., j
TITANATES (Continued)
Dl(butyI, methyl pyrophosphato) isopropyl
titanate mono(dioctyl, hydrogen)
phosphite [KR-62ES)
Di(dioctyl phosphato)ethylene titanate
[KR-212)
Di(dioctyl pyrophosphato) ethylene
titanate [KR-2385)
Diisostearylethylene titanate [KR-20l)
Dodecylbenzenesulfonyl (4-aminobenzene
sulfonyl), ethylene titanate [KR-2265)
. .
Ethylene, di(dioctyl)pyrophosphato
titanate [KR-238J)
.....
W
00
Ethylene, di(dioctyl pyrophosphato)
titanate dimethylamino-i-butanol adduct
..
Isopropyl ,4-aminobenzenesulfonyl ,
di(dodecylbenzenesulfonyl) titanate
(KR-265 )
Isopropyl diacryl isoatearoyl titanate
[KR-11)
Isopropyl (di-4-sminobenzoyl)isostearoyl
titanate [KR-318S)
Isopropyl diisostearoyl aeryl titanate
[KR-lO)
.. -
Isopropyl diisostearoyl methacryl
titanate [KR-6)
Isopropyl ,dimethacryl , isostearoyl
titanate [KR-7)
TABLE C-6 (Continued)
Toxicity
Concern
Skin Contact
Skin Contact
Skin Contact
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
OSHA Regulation.
[CAS No.)
,.
, .
" '.
(Continued)
-------
I
.
j
j
I
i
i
i
~I
Coupling Agent
;
'I
\
TITAHATES (Continued)
Isopropyl di(methyl, butyl pyrophosphate)
titanate [KR-6ZS)
Isopropyl Isostearoyl diacryl titanate
[ICR-H)
Isopropyl methacryl diisostearoyl
titanate [KR-6)
Isopropyl octyl, butyl pyrophosphate
titanate [ICR-58DS)
Isopropyl, triacryl titanate [ICR-39BS).
[ICR-39CS)
Isopropyl tri(Z-smlnobenzoyl) titanate
[ICR-52S)
'-..I
v.J
\0
Isopropyl triaminoethylethylamino
titanate [XICR-44U)
Is propyl tri(butyl, octyl pyrophosphato)
titanate di(dioctyl, hydrogen) phosphate
[ICR-58FS)
Isopropyl tricumylphenyl titanate
[KR-34BS). [KR-34S)
Isopropyl,tri(dioctyl phosphato)titanate
[KR-1Z)
Isopropyl tri(dioctyl pyrophosphato)
titanate [KR-38S1
Isopropyl,tridodecylbenzenesulfonyl
titsnate [KR-9S1
Isopropyl,tri(N-ethylaminoethylamino)
titanate [KR-441
TABLE C-6 (Continued)
Toxicity
Concern
Hoderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
IngestIon
Moderately Severe
Skin Irritant
Ingestion
Inhalation
Skin Irritant
Hoderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
OSHA Regulation
[CAS No.1
I. ,;
j!.
,II [6~17-55-8)
I
, ,
;, ).',
t ' ,
\ "" 'I
. ~'f \
L '\ II
.I,h~l,
\', i'
i.;. ~1J1,
(Continued)
-------
J
.'
"
;
;
" i
1
i
1
Coupling Agent
TITAHATES (Continued)
Isopropyl, triisoatearoyl titanate
[KR-TTS). [KR-15)
Isopropyl tri(3-mercaptopropionyl)
titanate [KR-66S)
laopropyl trimethacryl titanate
[KR-nBS), [KR-33CS)
laopropyl triricinoyl titanate [TTR-27)
Isopropyl tri(tetraethylenetrismine)
titanate [KR-63S)
-...J
~
a
Oxoethylene di(butyl. octyl pyrophos-
phato) titanate dimethylamlno-i-butsnol
adduct [KR-158D)
Oxoethylene di(dioctyl pyrophoaphato)
titanate dimethylamino-i-butanol adduct
[KR-138D)
Oxoethylene di(dioctyl) pyrophosphato
titanate di(dimethylaminopropyl meth-
acrylamide) [KR-138J)
Oxoethylene di(dioctyl) pyrophosphate
titanate triethylamine complex [KR-138r)
Proprietary [KR-9T)
Proprietsry [KR-238r)
Pyrophoaphato titanium ammonium meth-
acrylate [KR-238H)
Tetra(2,2-diallyloxymethyl-l-butoxy-
titanium di(ditridecyl) phosphite [KR-55)
Tetraiaopropyl. di(dioctyl phosphito)
titanate [KR-41B)
TABLE C-6 (Continued)
Toxicity
~
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
Moderately Severe
Skin Irritant
Eye Contact
Moderately Severe
Skin Irritant
Skin Irritant
OSHA Regulation
[CAS No.)
[61417-49-0 )
1111;
, II
l'
I
, ,
I
I
, '-",
I' r. ~
,', \
\ "'."
~' Jt~4157-14-8)
I' ~,
\ ; .. { ,\1
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I
,:. ~"
ti ,.1,
(Continued)
-------
Coupling Ageot
TIT!NATES (Continued)
Tetraisopropyl di(tridecyl phosphito)
titanate [ICR-36C)
Tetraoctyloxytitanium di(dilauryl-
phoaphite) titanate [KR-46B)
Tetraoctyloxytitantium di(ditridecyl
phosphite) [KR-46B)
Titanium acrylate iaostearate oxyacetate
[KR-11 00 )
Titanium 4-amlnobenzoate. lsostearate,
oxyacetate [ICR-137BS)
-.I
~
......
Titanium 4-aminobenzene sulfonate,
dodecylbenzeneaulfonate, oxyacetate
[KR-126S) .
Titanium diacrylate,oxyacetate
[KR-139BS), [KR-139CS I
Titanium di(butyl, octyl pyrophosphste)
di(dioctyl, hydrogen phosphite) oxysce-
tate [KR-158FS)
Titsnium di(butyl, octyl pyrophosphate)
oxyacetate [KR-158DS)
Titanium di(cumylphenolate) oxyacetate
[KR-134BS), [KR-134CS)
Titanium di(dioctyl phosphate) oxyacetate
[KR-112S )
Titanium di(dioctyl pyrophosphate)
oxyscetate [KR-13BS)
TABLE C-6 (Continued)
Toxicity
Concern
Moderately Severe
Skin Irritant
Skin Contac t
Skin Contsct
OSHA Regulation
[CAS 110.)
[65345-30-4)
" .
I .
III.
(Continued)
-------
Coupling Agent
TITANATES (Continued)
Titanium dimethacrylate, oxyacetate
[KR-133BS I, [KR-133CS 1
Titanium isostesrate methacrylate
oxyacetate [KR-I06I, [KR-I06S 1
Titanium (IV) biamethacrylate.
oxoethylene diolato (KR-133DSI
Titanium (IV) bis(methyl, butyl) pyro-
phosphato, ethylenediol bis 3-N-dimethyl-
amino iaobutanol (KR-262DI
Titanium (IV) trisacrylato methoxy-
diglycolato (XK&-39DSI
N.
~
N
Titanium (IV) trismethacrylato methoxy-
glycolate [XKR-33DSI
Tri(butyl, octyl pyrophosphato) iso-
propyl titanate mono(dioctyl, hydrogen
phosphite) [KR-58FSI, [KR-58S1
Tria(dioctyl)pyrophosphato. iaopropyl
tltanate
ESTERS
Calcium stesrate
Stearic acid
PROPRIETARY ESTERS
Anti-Terra U-80 (Unsatursted acid ester
neutralized with polyaminoamine;
e1ectroneutrall .
Surfaid-90 (fatty acid ester)
TABLE C-6 (Continued)
Toxicity
Low
Nontoxic
Skin, humans
75 mg/3D
Toxic Effect:
Irrita Uon
Concern
Ingestlon
Inges t ion
Skin Contact
Skin Contact
Ingestion
Tumorigen
Primary Irritant
Hild
OSHA Regulation
[CAS No.1
[63735-11-51
[57-11-4 )
(Continued).
,.
Of'"
:1 '
I .
III.
: .
-------
Coupling Agent
PROPRIETARY ESTERS (Continued)
VP-I09 [Unsstursted fstty acid, anionic)
YP-9OQ [Polymeric ester, anionic)
~ .
YP-905 [Polymeric eaters, unsaturated,
combination of anionic and cationic)
W-900 [Low molecular weight polymeric
salt)
W-905 [Low and medium molecular weight
polymeric salt and anionic polymeric
salt)
W-910 [Medium molecular weight fatty acid
based snionic)
........
.j:-
v..>
W-980 [Medium molecular weight unsatu-
rated acid ester neutralized with
polyamino amine)
W-960 (Medium molecular weight unsatu-
rated acid ester)
MISCELLANEOUS PROPRIETARY
PROPRIETARY ORGANOSILICONS
Union Carbide Y-9578
Union Carbide Y-9602
Union Carbide Y-7676
Union Carbide Y-9674
Union Carbide Y-4935
Union Carbide Y-9682
TABLE C-6 (Continued)
Toxicity
Concern
OSHA Regulation
[CAS No.)
I,; I;
. II
l'
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;. )",
I. \
I ,~. 'I
. ?/\
I,i I ; f il
l.h~1.
I
\; 'I
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OJ ~
(Continued)
-------
Coupling Agent
CHLORINATED PARAFFINS
ChIorez 700 [ChlorInated paraffIns, 70%
ClI
Chlorez 720 [ChlorInated paraffIns, 70+%
CII
Chlorez 760 [ChlorInated paraffIns, 70+%
CII
CHROHE-CONTAINING
Kethacrylato chromIc
-...J
.j::-
.j::-
TABLE C-6 (Continued)
ToxicIty
OSHA RegulatIon
[CAS No. I
I,; Ii
l'
,
.
Concern
, II
1
I
. '-"
I' r,
I ", ,
\' ':'.\'/~
i ~~ '
1'1 ; (,1,'
I,h~i,
I
\\
-------
TABLE C-7.
CURING AGENTS AND CATALYSTS FOR THERMOSETTING RESINS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Chelilcal Toxicity Concern OSHA Regulation (CAS No.)
AHlNES
I'
Alkanolall1ne (See Bthanolamine,
Trlethanolall1ne)
II-Amlnobenzyl8111ne I'I
p-Alilnobenzylalilnoanlllne
N-Amlnoethylethanolamine Low (111-41'-1)
Oral, rat
LDSO:3000 IIg/kg
N-Amlnoethyl piperazine Oral, rat Co croal ve (140-31-8)
LDSO:2140 mg/kg Tisaue IrrItant
Benzyl dlmethylall1ne . Oral. rat Collbustible (103-83-3)
LDSO:2S6 mg/kg
"'-J Bls(dimethylaliinoethyl) ether Oral. rat Primary Irritant (3033-62-3)
~
VI LDSO:1230 mg/kg
Bis(hexamethylene)trlamlne
4-chloroorthophenylene dlaliine Oral, rat Poal ti ve Carcinogen (9S-83-6)
TOw: 136 gm/kg (Anll1al)
N-Cocomorpbollne
Cyclohexylpropylene dialilne
Dlallyltetrahydrlodlpyrldyl
Diaminocyclohexane Oral, rat (338S-2l-S)
LDSO:390 mg/kg
Diaminodiphenyl methane Subcutaneous. rat Cauaes Todc (1208-S2-2)
LDSO:33oo mg/kg Hepatitis
Diamlnodiphenyl sulfone (DDS) Todc ~sitlve Carcinogen (80-08-2)
(Sulfonyl dianillne) Oral, humans (Anll1Sl)
LOW: 18 gm/kgllS Ingestion
years Tumorlgen
Todc Bffect: Hutagen
Sys temlc
Oral, rat
LOw: 1000 IIg/kg
(Continued)
-------
,
,
i
1
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,
,
TABLE C-7 (Continued)
','
Chelli c:a 1 Toxicity ~ OSHA Regulation iCAS No. I I'
AHINES (Continued)
3,S(D1811inomethyl) aniline III,
2,6-Diaminopyridine Intraperitoneal, 1141-86-6 I
mouse
LDSO: 100 mg/kg
Dic:yanodialline
Diethanolalline Low 3 ppm (TLV) 1111-42-42-21
Oral, rat (propoaed)
LDSO: 71 0 mg/kg
Diethylamine Oral, rat 2S ppm (air) 1109-89-71
LDSO:S40 IIg/kg
Diethylaminoethanol Low Primary Irritant 10 ppll TWA (skin) 1100-37-81
Oral, rat
LDSO: 1300 IIg/kg
--.J Diethylaminopropyl8lline IDEAPAI Oral, rat Skin Irritant 1104-78-91
.p. LDSO: 1410 IIg/kg
0\
Diethylenetriamine 1 DETA I Toxic: Ingeation 1 ppll (TLV) 1111-40-01
Oral, rat Inhalation (rec:olDIDended)
LDSO:l080 mg/kg Irritant (skin and
eyes)
Dimethylalline Toxic: Fire Risk 10 ppll TWA 1124-40-31
Oral, rat Irritant
LDSO: 698 mg/kg
Dimethylallinoethanol Low Primary Irritant 1108-01-0)
Oral, rat Hoderate Fire Riak
LDSO: 2340 mg/kg
. ,
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, .~1
:""j
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I
Dimethyl8llinoethyl piperazine
Dimethylallinomethyl phenol
May be toxic:
, ,
N,N-Dillethylallinopropylamine
Todc:
Oral, rat
LDLo: 1870 mg/kg
Ingestion
Inhalation
Irritant
Ft re Risk
1 109-SS-7 I
, .
l,l'(3(Dimethylallino)propyl)
imino bis(2-propanol)
(Continued)
-------
j
I
i
I
I
j
!
Chemical
AHlNES (Continued)
Dimethylaminopyridine
N,N-Dimethylbenzylamine
Dimethylcyclohexylamine
Dimethylethanolamine
N,N-Dimethylhezadecylamine
N,N-Dimethylpiperazine
-...J
.I:'-
-...J
Di(morpholinoethyl)ether
Ethyldiethanolamine
N-Ethylenediamine
N-Ethylmorpholine
Glycidylether polyamine adducts
Heptamethylisobiguam1de
Hexamethylenediamine
TABLE C-7 (Continued)
Todc1ty
Intravenous, mouse
LDSO:l82 mg/kg
Oral, rat
LDSO:26S mg/kg
Low
Oral, rat
LDSO:2340 mg/kg
Presumed Low
Oral, rat
LD50:3160 mg/kg
Low
Toxic
Oral, rat
LDSO:1200 mg/kg
Toxic
Inhalation, humans
teLo:100 ppm/2.S
months
Toxic Effect:
Irritation
Oral, rat
LDSO:12oo mg/kg
Toxic
Oral, rat
LD50:7S0 mg/kg
Concern
Moderate Pire Risk
Moderate Fire Risk
Irritant to skin and
eyes
Inhalation
Skin Absorption
Tumorigen
Irritant to skin and
eyes
Skin absorption
Fire Risk
Corrosive
Ingestion
Irritant
OSHA Regulation
10 ppm
20 ppm TWA
. ,
o,ul
~~
(S683-33-D)
(103-83-3)
(108-01-D )
'(106-SS-8)
(107-15-3)
(100-74-31
(124-D9-4 )
r'
O'--rr
'"
(Continued)
'.' t
~.,. .
'I~
l .,
.fto II
-------
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j
,~
i
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. .
1
Chemical
AlfINES (Continued)
Hexamethylenetetramine
N-(B-Hydroxyethyl)piperazine
N(2-Hydroxypropyl)ethylenedi-
ami ne
3,3'-Iminobiapropylamine
Kenthane diamine
-.I
~
00
N-Kethoxyethylmorpholine
, ,
, '
D-Kethylbenzyldimethylamine
p,p'-Kethylenedianiline
(p,p'-diaminndi-phenylmethane)
N-Kethylmorpholine
Kethylpiperzine
, ,
Honomethylamine (Methylamine)
Honoethanolamine
(2-Aminoethanol)
"
Honoethylamine
TABLE C-7 (Continued)
Toxicity
Hoderately toxic
Oral. lIouse
LOto: 512 ..g/kg
Low
Oral, rat
LD50:4920 109/kg
Moderately Toxic
Oral, rat
LD50: 810 mg/kg
Oral, rat
LD50: 170 mg/kg
Low
Toxic
Oral, rat
LD50: 347 mg/kg
Toxic
Oral, rat
LD50:600 mg/kg
Oral, rat
LD50:2830 109/kg
Toxic
Subcutaneous. rat
LDLo: 200 109/kg
Toxic
Oral, rat
LD50: 2100 mg/kg
Toxic
Oral, rat
LDLo: 400 mg/kg
~
Skin Irritant
Pi re Riak
Corroai ve
Ingeation
Inhalation
Irritant
Irritant to akin and
eyes
Kay Cause Toxic
Hepatitis
Pire Risk
Skin Irritant
Pire Risk
Irritsnt to Skin
Pire Riak
Irritsnt to Skin
Strong Irritsnt
Pi re Risk
OSHA Regulation
0.1 ppm TLV
10 ppm 'NA
3 ppm 'NA
10 ppm 'NA
, 1.
(CAS No.)
(100-97-6)
(103-76-4 )
(56-18-8)
(80-52-4 )
(101-77-9)
(76-57-31
(109-61-3)
(74-89-5 )
(141-43-5)
[75-04-71
.,~
"
"
.,
,r,t
(Continued)
r~,
~~'
-------
TABLE C-7 (Continued)
Chemical Toxicity Concern OSHA Regulation (CAS No.)
AHlNES (Continued)
Olefin oxide-polyamine adduct
Pentaethylenehexamine Oral, rat (4067-16-7)
LD50:1600 mg/kg
m-Phenylenediamine Toxic Inhalation (108-45-2)
Oral, rat Irritant to Skin
LD50:650 mg/kg Tumorigen
Mutagen
Piperidine Toxic Irritant (110-89-4)
Oral, rat Ingeation
LD50:30 mg/kg Inhalation
Fire Illak
Tumorigen
Mutagen
Teratogen
Polyoxyalkylenepolyamine
'"
.po Pyridine Oral, rat 5 ppm TWA (110-86-1)
\0 LD50:89l mg/kg
PyrroUdine Moderately Toxic Ingeation (123-75-1)
Oral, rat Inhalation
LD50:3oo mg/kg Fire Illak
QuinucUdine (100-76-5)
Silicone _ine
Tetraethylenepentamine Toxic Irritant to Skin and (112-57-21
Oral, rat Eyea
LD50:3990 mg/kg
N-Tetramethylethylenediamine Oral. rat (110-18-9)
LD50:l580 mg/kg
N-Tetramethyl-l,3-butanediamine Oral, rat Primary Irritant (97-84-7) .
LD50:750 mg/kg
Tetramethylguanidine
Triaminomethylbenzene
Tri(dimethylaminomethyl) phenol Hay be Toxic
Oral, rat
LD50:1200 mg/kg
Primary Irritant
( 90-72-2)
I,i I;
, II
l'
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(Continued)
-------
. J
,
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,'(
TABLE C-7 (Continued)
Concern
OSHA Regulation
(CAS No.)
Chemical Toxicity
AMINES (Continued)
Triethanolamine borate Oral t mouse
LD50:62oo 109/kg
',:.-.- Triethylamine Toxic
Oral, rat
'j LD50:460 109/kg
'j
Triethylenediamine Oral, rat
LD50:1870 109/kg
Trlethylenetetramine Oral, rat
, " LD50: 2500 109/kg
,
i
.1
1,2,4-Trimethylpiperazine
.....
lJ1 2,4,6-Tria(dimethylaminoethyl)
0 phenol
..
2,4,6-Tris(diIDethylaminomethyl) Oral, rat
, phenol LD50: 1200 109/kg
1,3,5-Tris«N,N-dimethyl-3- Oral, rat
amino)propyl)- 5-hexahydro- LD50:3250 109/kg
triazine
m-Xylidenediam1ne
AMINE OXIDES
Dimethyldodecenylamine-N-oxide Oral, rat (1643-20-5)
LOto: 1000 IDg/kg
Pyridine-N-oxide Intravenous, mouse (694-59-7)
LD50: 180 mg/kg
Trimethylamine-N-oxide Oral, rat (62637-93-81
LD50:8700 109/kg
AMIDES
1,l-DiIDethylurea
(283-56-7)
Inhalation
Ingestion
Irritant to Tissue
Fire Risk
25 ppm TWA
(121-44-8)
(280-57-9)
Irritant
Eyes
Hutagen
Teratol\en
to Skin and
(112-24-3)
(90-72-2)
(15875-13-5)
I,; t:
, II
l'
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. ~,
I
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1
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,
,I
"
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(Continued)
-------
TABLE C-7 (Continued)
-, Chemica 1 Toxic:1ty Concern OSHA Regulation [CAS No.]
! -_.-
AHIOKS (Continued)
l,3-0imetbylurea Unknown, rat [96-31-3]
TDLo:lOOO mg/kgl
13 0 preg
l,3-0iphenylurea [carbanilide] Oral, rat [102-07-8]
LDLo:500 mg/kg
1-Methylurea Oral, rat [598-50-5)
L0Lo: 500 mg/kg
1-Phenylurea Oral, mouse [64-10-8)
LD50:1580 mg/kg
.."
Urea [carbamide) Low Primary Irritant [57-13-6)
Oral, rat Tumorigen .\
TDLo:821 gm/kg/lY Hutagen "
Toxic Kf fect:
....., Carcinogen I I.
VI "rvt
..... IHlDAZOLES
I
8enzImidazole Oral, rat [51-17-2) 'h
L050:500 mg/kg ~1.:11
I-N-Butylimidazole
l-N-Cyclohexylimidazole
2-Kthyl-4-methylimidazole
N-Propylimidazole
HKTAL COHPOUNDS
ANTIHONY
Antimony pentachloride Toxic Corrosive 500 ug(Sb)/m3 TWA [7647-18-9)
Oral, rat Hutagen
L050: 1115 mg/kg
Antimony trichloride Oral, rat Corrosive 500 ug(Sb)/m3 TWA [10025-91-9)
L050:525 mg/kg Irritant to skin and
eyes
(Continued)
-------
,," ..
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:
i
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Chellical
"1
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Calc1UID acetate
CalcIum carbonate
CalcIum naphthenate
Trlcalcluli phoaphate (CalclulD
phoaphate, trIbasIc)
CHROMIUM
Chrollium (Ill) triacetyl
acetonate
.......
VI
N
Chrollium (Ill)
trl-2-acetylcyclohexanoate
ChrolDlum (Ill)
tri(dibenzoyimethane)
Chromium (Ill) trI(l,3-
Diphenyl-l,3-pentsnedloate)
ChrolDlum (Ill) trI(l,3-
diphenyl-l,3-propanedioate)
ChrolDlum (Ill)
trl-2-ethylhexanoate
ChrolDlum (Ill) trI(l-phenyl-
l,3-butane-dlone)
Chrollium (Ill) tripicolinoate
COBALT
Cobalt benzoate
Cobalt 2-ethylhexoate [cobalt
octoate)
Cobalt naphthenate (IndefinIte)
- i
'1
. ~
TABLE C-7 (Continued)
Toxic1ty
Concern
Nontoxic
Intravenous. rat
LOLa' 147 IDg/kg
Nontoxic
Nontoxic
Intravenous. mouse
LD50.180 IDg/kg
Oral, rat
L050.3900 IDg/kg
OSHA Regulation
10 IIg/1I3 TLV
(recolllllended)-'
(CAS No.)
(62-54-4 )
(1317-65-3)
(16432-36-3 )
(61789-51-3)
" ."..
I, ~
.
IlfI)'r
, "
'\1
.~
(Continued)
-------
'~'
,
f
;
I
I
I
!
I
I
'.
Chell1 c:a 1
-
LEAD
Lead benzoate
Lead 2-ethylhexoate
Lead naphthenate (Indefinite)
Lead oleate
Lltharge, sublimed
MANGANESE
.......
U1
VJ
Mangsnese 2-ethylhexoate
(Mangsnese oc:toate)
Mangsnese linoresinste
; .
Manganese naphthenste
(Indefinite)
PHOSPHORUS
Hexamethylphosphoric: trisllide
[Hellps)
Tri-n-butylphosphine
Tributyldodec:ylphosphoniull
iodide
Trioc:tylphosphine oxide
Triphenyl phosphine oxide
TABLE C-7 (Continued)
Toxic:1ty
Todc:
Oral, rat
LDSO' 5100 IIg/l
-------
TABLE C-7 (Continued)
Chemical Toxicity Concern OSHA Regulation ICAS No.)
-
TIN
Dlbuty1tlndlacetate Toxic 100 ug(Sn)/.3 TWA 11067-33-0)
Oral, rat (sUn)
LDSO:32 IIS/kS
Dlbuty1tlndllsurate Toxic PrImary IrrItant 0.1 IIs(Sn)/.3 TWA I 17-S8-7 )
Oral, rat (recolllllended)
LDSO: 17S IDS/kS
Dlbuty1tlndloctoate ToxIc 0.1 mg(Sn)/.3 TWA 12781-10-4)
IDlbutyltlndl-2-ethylhexoate) Oral, rat (recolllllended)
LDSO:20D IDS/kg
Dlbuty1tlnbls1soocty1ma1eate 100 us(Sn)/.3 TWA
(recolI!Iended)
DlbutyltlnblslsooctyllDercapto- 100 us(Sn)/.3 TWA Iii Ii
acetate (recollJlended)
, '-I
I.J> Dlbuty1tlnbls1aury1mercaptlde Toxic 100 us(Sn)/m3 TWA ' II ~'
~
(recommended) ,
.' .
Dlmethyltlnblslsooctylma1este 100 us(Sn)/.3 TWA 'y
(reco_nded) I',. (
100 ug(Sn)/.3 TWA ",
Dlmethy1tln Isoocty1mercapto- I .~' ~" 'j
acetate (recommended) 'l{
; ~.
Dlmethy1tlnbls1aurylmercaptlde 100 us(Sn)/.3 TWA \1 i .. ,,,1,1
(reco_nded) I.V'Vi,
, .
~., ! Stsnnous chlorIde Toxic SkIn Irritant 2 .s(Sn)/.3 TWA (1172~9c1-11)
Oral, rat ,,'')J'
LDSO:700 IIS/kS
J Stannous octoate Toxic 100'us(S~)/.3 TWA
! [Stannous-2-ethylhexoate) (reco_nded)
Stannous oleate Todc SkIn Absorption 100 us(Sn)/.3 TWA [1912-84-1)
Intravenous, mouse (recommended)
LDSO:100 IDS/kS
(Continued)
-------
Chemical
ZINC
Zinc acetate
Zinc-2-ethylhexoate (Zinc
octoate)
Zinc naphthenate
Zinc oxide (ZnO)
ZIRCONIUM
Zirconlu~ 2-ethylhexoate
......
lJ1
lJ1
ZIrconIum naphthenate
Zirconl~ toluene
IIISCELLANEOUS IlETAL COIlPOUNDS
Aluminum iaopropoxide
Aluminum-eec-butoxide
Barium carbonate
Cerium naphthenate
Lanthanull naphthanate
Lithium acetate
llagnesium acetste
llagneslum oxide
TABLE C-7 (Continued)
Toxicity
Low
Oral, rat
LD50:2510 IIg/kg
Low
Low
Oral, rat
LD50:4920 mg/kg
Nontoxic
Toxic
Toxic
Oral, humans
LOto: 57 109/kg
Intravenous. ~ouse
LD50:16 109/kg
Toxic
Concern
Inhalation
Ingestion
Inhalation (fume)
O_SHA Regulation
5 mg/1I3 TWA (fume)
.. ,
500 ug(Ba)/1I3 TWA
(CAS No.)
(557-34-6)
(12001-85-3)
(1314-13-2)
(555-31-7)
(513-11-9 )
(142-72-31
(1309-48-4 )
'.."
h,
I,. II
~ I-t
. ''"
. ~,!;,
(Continued)
-------
Chemical
HISCELLANEOUS KETAL COMPOUNDS
(Continued)
Honopota991u~ glycoxide
Potass1um acetate
Potassium octoate
Potassium oleate
Sodium propionate
Strontium carbonate
Tri-n-butylarsine
HISCELLANEOUS
.....
\J1
0\
AIIinodiboron
Benzyltri8ethyla~on1u~
chloride
CresyUc acid
Dicyandia18ide
"
Dimethyldilauryl ammonium
chloride
8-Hydroxyethyltri8ethyl
ammonium hydrozide
"
Paraformaldehyde
Tetrahydroxydiboron
Tetrapropylal8l8Onium chloride
Trimethylboroxine
Trioxane
"
,I
1
TABLE C-7 (Continued)
Toxicity
Low
Oral, rat
LD50:32,50 mg/kg
Low
Subcutaneous, qouse
LD50: 2100 IIglkg
Low
Oral, rat
LDLo:250 mg/kg
Oral, rat
LD50:l45411g/kg
Toxic
Oral, rat
LD50:800 mg/kg
Oral, rat
LD50:800 mg/kg
Concern
Primary Irritant
Corrosive
Skin Absorpt1on
Ingestion
Primary Irritant
Fire Risk
OSHA Regulation
[CAS No.)
[127-08-2)
[ 164-11-61
[143-18-0)
[137-40-6)
[56-93-9)
[1319-77-3 )
[461-58-5 )
[110-88-3)
[110-88-3 )
I.,'
. ~;,.
~ "I~
: ~"i
(Continued)
-------
./
Che..ical
ACIDS
Ace tic ac id
Ammonium chloride
Ammoniu.. fluoride
Boric acid
'-I
U1
'-I
Boron trifluoride
Carbon dioxide
Cinna..ic acid
N-Cyclohexyl aulfal88te
Hydrochloric acid
Oxalic acid
~hoaphogypaUID
Phoaphoric acid
TABLE C-7 (Continued)
'I; Ii
,11 l'
I I .
I :
Toxicity Concern OSHA Regulation (CAS ),1
I' (
I "
\' ,I' '
Toxic Ingeation 10 pp.. 'IWA (6Hf.?I(
Inhalation, humans Inhalation II! I , ~~I
TeLo: 816 pp../:II Irritant
Toxic Effect: I ,~' jI:
Irritation I ..II
'" 1"
Toxic Inhalation 10 ..g/..3 TWA (12125-02;:-91
Oral, rat OJ 'JI
LD50:1650 ..g/ltg
Toxic Inh" x..tion 2500 ug(F)/..3 TWA (12125-01-81
Intraperitoneal, rat Corrosive
L050,32 ..g/1t8
Toxic Ingestion (10043-35-31
Oral, humans Irritant
LDLo: 214 ,"g/kg
Toxic Inhala tion 1 pp.. Ceiling (7637-07-21
Inhalation, rat Corrosi ve
LCLo' 750 pp../5. 58
Inhalation, humana 5000 ppm TWA (124-38-91
LCLo' 100,000 pp../llt
Oral, rat (62i-g2-91
LD50:2500 ..g/ltg
Toxic Ingeation 5 pp.. Ceiling (1647-01-01
Inhalation, humana Inhalation
LCLo' 1300 pp../3Ot Irritant to Sltin and
Eyea
Toxic Inhalation 1 ..g/..3 TWA (144-62-71
Oral, humans Ingeation
LDt.o: 11 mg/ltg Strong Irritant
(13397-24-51
Toxic Corrosl ve 1 mg/..3 TWA (7664-38-21
Inhalation, humana Ingestion
TCLo: 100 mg/..3 Inha 1at ion
Toxic Effect: Irritant
Irritation
(Continued)
-------
j"
1
J
,
,
1
j
1
!
Chemical
~ (Continued)
Phthalic anhydride
Succinic anhydride
Sulfuric acid
p-Tolueneaulfonic acid
Thioglycolic acid
. '
--.J
\J1
CO
~
Ammonia
, ,
Barium hydroxide
Calcium hydroxide
Lime
Lithium carbonate
Lithium hydroxide
Magnesium hydroxide
Monosodium phosphate
TABLE C-7 (Continued)
Toxicity
Toxic
Oral, rat
LDSO:4020 mg/kg
Toxic
Subcutaneous, rat
TOto:2600 mg/kg/
6SW-1
Todc Effect:
Tumorigen
Highly Toxic
Oral, rat
LDSO:2140 mg/kg
Moderately Toxic
Oral, rat
LDSO: 2480 IIg/kg
Oral, rat
LDSO:2S0 mg/kg
Toxic
Oral, rat
LDSO:3S0 mg/kg
Toxic
Subcutaneous, mouse
LDSO: 50 mg/kg
See Calcium Oxide
Low
Oral, rat
LOto,710 mg/kg
Nontoxic
Low
~
Skin Irritant
Negative Animal
Carcinogen
I rri tant
Suspected Carcinogen
Strong Irritant
Skin Irritant
Corrosive
Inhala tion
Irritant
Moderate Fire Risk
Ingestion
Skin Irritsnt
Inhalation
Irritant
Strong Irritant
OSHA Regulation
2 ppll TWA
1 mg/m3 TWA
50 ppm
500 ug(Ba)/m3 TWA
5 mg/m3 TWA
I, I'
I' '
,11
~'
I
, ,
I
I
, ~'
~
\ """
:tl!
(¥~-44-g'l)
I ,~' ti,
I ,
~" l
(108':39-,5 )
ti j/
(7664-93-9)
(104-15-4 )
(68-11-1 (
(7664-41-7)
(1304-28-5 )
(1305-78-81
(554-13-2 )
(1310-65-2)
(1309-42-9 )
(7558-80-7)
(Continued)
.i~ .
,
'.
-------
Chellical
-
BASES (Continued)
PotassiUli hydroxide
Sodium aluminate
Sodium bicarbonate
SodiUli hydroxIde
Strontiull hydroxide
.....
VI
\0
CATALYST NEUTRALIZERS
Amines
Phosphorous pentoxlde
[phosphoric anhydride)
Sodium hydroxIde [See Bases)
TrlcalciUli phosphate
TrIethanolamine
RESIN STABILIZERS
2-Amlno-2-methyl-l-propannl
Dimethylaminoeth3nol
II-Phenylenedialline [See Amines)
Triethylamine [See Amlnes)
TABL& C-7 (Continued)
Toxicity
Todc
SkIn, hUll3ns
50 uS/24H
Toxic Effect:
Toxic
Low
Oral, rat
LD50:4220 IIS/kS
Todc
Eye, rabbit
U
Toxic Effect:
Low
See Bases
See Metal Compounds
Low
Oral. rat
LD 50: S680 IIS/kS
Oral, rabbit
LOW: 1000 IIS/kS
s.... Am 1 nes
See Amines
See Amines
Concern
I~"8tlon
Inhalatlon
Strong Irr U'iot
Severe
St rORS Irritant
Priamry Irritant
Corrosl ve
Strons Irritant
Severe
Corroslve
Stroos Irritant
Reacts VIolent wIth
Water
Danserous FIre Risk
OS~_~esulat1on
2 IIS/1I3 TWA
(reco_oded)
2 IIS/1I3 TWA
(CAS No.)
[1310-58-3 )
[11138-49-1)
(144-55-8)
(1310-73-21
(18480-07-4 )
(1314-56-3)
(102-71-6)
[ 124 -68-5 )
-------
TABLE C-8. FILLERS.AND REINFORCERS FOR PLASTICS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Fillers Toxicity Concern OSHA Regulation (CAS No.)
INORGANIC EXTENDERS
Alumina. hydrated Practically Nontoxic Hutagen 10 mg/m3 TWA (21645-51-21
(Al203.3820) Oral, humans (recommended)
TDLo:122 gm/kg/4D
Toxic Effect: Gastronintesti-
nal Tract
Aluminum, powder (Al) Nontoxic Flammable 10 mg/m3 TWA (1429-90-51
Explosive (recommended)
Aluminum hydroxide (See
Alumina. hydrated)
Aluminum oxide (A12031 Nontoxic Inhalation 10 mg/m3 TWA (1344-28-1)
(Emery). (Sapphire) Intrapleural, rat Tumorigen (recommended)
TDLo: 90 mg/kg
Toxic Effect: Equi voca 1
Tumorigenic Agent
......
0\ Aluminum silicate (See Clay)
0
Antimony trioxide Oral, rat Hay Cause Dermatitia 0.5 mg/m3 TWA (1321-33-9)
LD50:)34.6 g/kg
Barium carbonate. precipitated Toxic Ingestion 500 ug(Ba)/m3 TWA (513-71-91
(BaC031. (Witherite) Oral, human
LDto: 51 mg/kg
Barium ferrite
Barium titanate (BaTi03)
Barium sulfate (BaS04) Nontoxic Tumorigen (13462-B6-11
Intrapleural, rat
TDLo : 200 mg/kg
Toxic Effect: Equi voca 1
Tumorigenic Agent
Barytes
Blanc fixe (Barium Sulfate, See Barium Sulfate (1121-43-11
precipitated)
(Continued)
-------
I
J
1
;
!
!
TABLE C-8 (Continued)
Fillers
Toxicity
INORGANIC EXTENDERS
(Continued)
Barium sulfide
Todc
Orsl, humans
TOto: 226 ms/lts
Toxic Effect: Peripheral Ner-
vous System; Behavioral Symp-
toms; Pulmonary System
Bentonite clay
Nontoxic
Intravenous, rat
LD50:35 mg/ltg
Beryllium oxide (BeO)
Highly Toxic
Inhalation, 'rat
TeLo: 28 mg/m3/17W
Toxic Effect: 1Umorigen
'-I
'"
.....
Bronze [1-10% Sn in Cu)
Todc
Oral, humans
TOto: 120 ug/ltg
Todc Effect:
Gostrointestinal
Cadmium sulfide (CdS)
Highly Todc
Subcutaneous, rat
TDLo: 90 mg/kg
Toxic Effect: Carcinogen
Calcium carbonste (CaC031
Nontoxic
Concern
OSHA Regulation
Ingestion
0.5 mg(Ba)/m3 TWA
Inhala tion
Inhalation
Positive Animal
Carcinogen
2 ug/m3 TWA
Inhalation
Powder is FiaDlDable
I mg(Cu)/m3 TWA
(dust) (recommended)
Tumorigen
Mutagen
Inhalation
Ingestion
40 uS/.3 TWA
(recommended)
10 mg/m3 TWA
(recommended)
Calcium fluoride (CaF2) Toxic Irritant 2.5 mg(F)/m3 TWA
Oral, rat Inhalation (recommended)
LD50:4250 mg/lts
Calcium hydroxide [lime) Oral, rat Skin Irri tant 5 ms/m3 TWA
[Cs(OHh) LD50: 7340 mg/ltg Inhalation (recommended)
Mutagen
Calcium silicate, precipitated Nontoxic Irri tant Dust 10 mg/m3 TWA
[CaSi03) (recommended)
[CAS No.)
(50864-67~ 1
[1302-78-9)
(1304-56-9 )
(12597-70-51
[1306-23-6)
(471-34-1) pre-
cipitated
[1317-65-3 )
limestone
[13397-26-7 )
whit ing
',..,.,
".
[7789-75-51
'''~t '
[1305-62~1
[1344 -96-31
'h
. ~~.,
(Continued)
-------
/
/
.'
TABLE C-8 (Continued)
!!!!!!! Toxicity Concern OSHA Regulation (CAS No. 1
INORGANIC EXTENDERS
(Continued)
Calcium aulfate (Cas041 Nontodc TUllorigen 10 IIg/..3 TLV, (10101-41-4)
Intraperitoneal, rat (reco_nded) \1778-18-91
TDto:4~0 mg/kg/3W gypsum
Todc Effect: Carcinogen (14798-04-0)
anhydrite
(23296-1~-3)
precipitated
Clay (KaoUn), (Aluminum Irritant 10 18g/..3 TWA (1327-36-2)
s11 teate) Inhalation (reco_ended)
(A120'2Si02"2H20)
Calcined
Copper, powder (Cu) Toxic (powders) Inhalation 1 '"8/113 TWA (dust) (7440-~0-8 1
Oral, rat Powder is Flammable (reco_nded) " ',
TDLo: 1~2 mg/kg
.....
0\ Emery (See Aluminum Oxide) 10 mg/1I3 TWA (112-62-9)
N
(reco_nded)
Feldspar (Potassium alumino- Nontoxic
sUicate) (KAlSi3081
Glass Nontodc
'or'
Graphite Low Fire Risk 1 ~ mppcf (7782-42-~ 1
1
Iroo, powder (Fe) Toxic Inhalation '.
Intratracheal, rat Explosion Hazard
TDLo:~O mg/kg/1SW " !
Todc Effect: Tumorigen "~t
Iron oxide (Fe2031 Subcutaneous, rat Tumorigen ~ ..g(Fe)/m3 TWA (1309-37-11 ,r
LDLo: l3~ mg/kg Inhalation (recommended) , I\~
Toxic Effect: Equivocal . j, I
Tumorigenic Agent ~..
Kieselguhr (See Diatomaceous
Earth)
Kryolite (Sodium Fluoro- Oral, rat 2~00 ug(F)/1I3 TWA (1 ~096-~2-3 1
aluminate I LD~O: 200 mg/kg
(Continued)
-------
TABLE C-8 (Continued)
,
Fillers Todcity Concern OSHA Regulation [CAS Nool
INORGANIC EXTENDERS
(Continued)
Lead, powder [Pbl Todc Ingestion 200 ug/..3 TWA 11439-92-11
Intraperitoneal, rat Inhalation
LIJu>: 1000 mg/kg
Lead odde [PbO) Todc Inhalation 50 ug(Pb)/m3 TWA [1317-36-8)
Intraperitoneal, rat Pril88ry Irritant
LIJu>:430 mg/kg Tumorigen
Hutagen
Lithium aluminum silicate 2 ..g(Al)/m3 TWA [ 1302 -66-51
(recommended)
Lithopone [72% BaS04 + 28% See Barium Sulfate and Zinc [1345-05-7)
ZnS) Sulfide [8006-32-4)
Hagnesium carbonate, Inhalation [546-93-01
....... precipitated [HgC03) Ingestion
'"
V-1 Hagnesium hydroxide Nontoxic 11309-42-81
Oral, hUl88na
LIJu>:5000 mg/kg
Hagnesium oxide Toxic Inhalation 15 mg/m3 TWA ( 1 309-4 8-41
Inhalation, hUl88ns Tumorigen
TCLa: 400 mg/..3
Toxic Effect: Una peel tied
Magnesium silicate, Todc Inhala tion [1343-90-41
precipitated Skin, humans Primary Irritant
[3HgSi03° 5H~1 300 ug/3D
Toxic Effect: Hild Irritation
Magnetite [Ferrous-ferric
Oxide). [See Iron Oxidel
Hica [Potassium Alu..inum Inhala tion 20 IIppcf [1327-44-21
Silicate I Irritant [1200-26-2)
Holybdenum disulfide Law Inhalation 10 118/113 TWA [1317-33-51
(recommended)
Nepheline [14797-52-51
[(Na,K)(Al,Si)2041
(Continued)
I.
-------
TABLE C-8 (Continued) ,.
. ,
Fillers Toxicity Concern OSHA Regulstion (CAS No.)
INORGANIC EXTENDERS
(Continued)
Nickel, powder (Ni) Intravenous. mouse Flsmmable 1.0 mg/1I3 TWA (7440-0Z-o)
LDLo: 50 mg/kg Post ti ve Animal (skin)
Carcinogen
Perlite (See Silics) 30 mppcf
PUllice (61-15% SiOZ + 10-ZO%
AIZ03)
Pyrophyllite (IZZ69-78-ZI
(AIZSi401O(OH) I
Rottenstone
SiUcs Toxic Inhslation go IIg/..3 TWA (7631-86-91
Oral, rat (Silicosis)
....... LD50:3160 mg/kg
0'\
.p. Amorphous. fumed Intraperitoneal, rat go IIg/..3/%S1OZ [7631-86-91
LDLo:50 mg/kg
Amorphous, fused Intraperitoneal, rat 8 IIg/1I3/%SiOZ (60676-86-01
L~:400 mg/kg
Diatomaceous earth 1.5 IIg/m3 (respira- (60676-86-0)
ble) (recommended)
Quartz Intraperitoneal, rat Tumorigen 10 mg/1I3/15iOZ+Z (14808-60-11
TDto:45 mg/kg (respirable) or
Todc Effect: Carcinogen 30 118/.3 TWA
(recommended)
., Allorphous, hydrated (HiSHI go IIg/1I3/151OZ (7631-86-91
Silicon carbide (SiC) Inhalation 10 IIg/..3 TWA (409-Z1-ZI
ZO mg/m3 STEL
(recommended)
., Slate flour
.'
(Continued)
-------
TABLE C-8 (Continued)
Fillers Toxicity Concern OSHA Regulation (CAS No.)
INORGANIC EXTENDERS
(Continued)
....
Sodium aluminum hydroxy-
carbonate (Dawsonite) "
",
Sodium aluminosilicate Low (1344-00-9)
2500 ug(F)/..3 TW" ' I
Sodium aluminum fluoride Oral, rat (15096-52-3) 'tOt
W50:2oo 109/kg
,
Steel, stainless : 11.
Talc Moderate Inhalat ion 2 mppcf TW" (non- (14807-96-6) ~':
(magnesium silicate) Skin, humans Primary Irritpnt fibrous)
(Mg3Si4010(08)2) 300 ug/3D-I
Canadian Toxic Effect: MUd Irritation
Titanium dioxide, rutile, Nontoxic Primary Irritant 15 mg/m3 TW" (1317-70-01
....., anatase Skin, humans Tumorigen (13463-67-3)
0\ 300 ug/3D
\JI Toxic Effect< MUd Irritation
Zinc, powder Low Fi re Risk (7440-66-61
Skin, humans
300 ug/3D
Toxic Effect: MUd Irritation
Zinc oxide (ZnO) Nontoxic Primary Irritant 5 mg/m3 TW" (1314-13-2 I
Oral, rat Inhalation
TDLo: 6846 109/kg Mutagen
Teratogen
Zinc sulfide (ZnS) Moderate llutagen 5 mg/m3 TW" (12402-34-5)
Teratogen
Primary Irritant
Zirconia (Zr021 Toxic Inha lat ion
Zirconium silicate 5 mg(Zr)/m3 TW" (14940-68-21
(Continued)
-------
./
~
ORGANIC EXTENDERS
NATURAL
Bagasse (From Sugar Cane)
Bark, ground
Carbon black
Cherrystone flour
"
Carbon hollow spherea (See Fly
Ash)
Casein
i
Coconut-ahell flour
......
'"
'"
Coffee, ground
Cellulose, hydrated
Cellulose, oxidized
Cork dust
Fly Ash (C), (Soot)
GUsonite
Keratin (ground feathers)
, j
. ,
,"j
. ..1
Lignin, processed
Peanut shells, ground
j
. ~
Pecsn shell flour
".
)
TABLE C-8 (Continued)
Toxicity
Concern
Toxic
Inhalstion
Intravenous. mouse
LD50:440 mg/kg
Nontoxic
Combustible
Combustible
Nontoxic
Moderate
Inhalation
Irritant to Skin and
Eyes
Skin Sensitizer
Suspected Carcinogen.
Intravenous. mouse
LD50: 45 mg/kg
Mutagen
OSNA Regulation
3.5 mg/m3 TWA
'..~
(GAS No.)
~~ "
"
"/or
( 1333-86-4 )
(7440-44-0 )
',I,
~'
( 61789-98-81.
(12002-43-6 )
( 9008-18-8)
(9005-53-2)
(Continued)
-------
!.!!.!!!!
NATURAL EXTENDERS (Continued)
Petroleum coke
Rice hull aah
Rubber, natural [Gutta Perchal
Saw duat
Soybean Ileal
Starch
Walnut-ahell flour
SYNTHETIC EXTENDERS
-...J
0\
-...J
Acrylic
Cellophane
Phenol-Formaldehyde
Polyfluoroethylene
,
,
i
Polyethylene
Polyatyrene
INORGANIC FIBERS
Alumina (ceramic) [Al2031
Aluminum [All
TABLE C-8 (Continued)
Toxicity
Nontoxic
Skin, humans
300 ug/3D
Toxic Effect'
HUd Irritation
Impregnation, rat
TDLo' 18 109/kg
Toxic Effect' Tumorigen
See Organic Fibers
Impregnation, rat
TDLo,33 109/kg
Toxic Effect' Tumorigen
Inhalation. mouse
LD50,120 mg/m3/1OH
See Inorganic Extenders
See Inorganic Extenders
Concern
Posti ve Animal
Carcinogen
Tumor1gen
Positive Animal
Carcinogen
OSHA Regulation
10 me/m3 TWA
(recommended)
[CAS No.)
[64743-05-1)
[9005-25-81
[9005-81-6)
19003-35-4 I
[ 9002 -88-4 I
[9003-53-6 I
(Continued)
-------
TABLE C-8 (Continued)
Fillers Toxicity Concern OSHA Ilegulation [CAS No.)
INORGANIC FIBERS (Continued)
Aluminum nitride
Aluminum oxide [AI203) See Inorganic IIxtenders
Aluminum silicate Intrapleural, rat [1302-76-7)
[AI203"Si02) TDt.o: 90 mg/kg
Toxic IIffect: TUlllOrigen
Asbestos Toxic Inhalation 2 fibers/cm3 TWA [1332-21-4)
Intrapleural, rat Tumorigen 10 fibers/cm3 [1343-,90-4)
TDLo:IOO mg/kg Carcinogen Ceiling
Amosite Toxic Inhalation O. S fibers ) S um/cc [12172-73-S 1
Chrysotile Toxic Inhala tion 2 fibers ) S um/cc [ 12001-2 9-5 J
Crocidolite Toxic Inhalation 0.2 fibers ) S um/cc [12001-28-41
......
0\ Other forms Toxic Inhalation 2 fibers ) 5 u",1 cc
r~ 00
1 Beryl1ia (ceramic) See Inorganic IIxtenders
1 (Beryllium Oxide)
.1 Beryllium Inhalation, humans Ingestion 2 ug/",3 TWA [7440-41-7 J
'I TCLo: 300 mg/m3 Inhalation 5 mg/m3 Ceiling
Toxic IIffect, Metabolism and Mutagen 25 ug/m3/30 Min.1 ....
Nutrition, Pulmonary System Tumorigen 8 Hr. Peak
Beryllium carbide [Be~) Toxic Inhalation
Beryllium oxide See Inorganic IIxtenders
Boron Oral, mouse [ 7440-42-8)
LDSO:2000 mg/kg
Boron carbide [B4C) Inha lation
Boron nitride [BN) Low
80ron tungsten filament
(Continued)
-------
1,
~~" :
TABLE C-8 (Continued)
FUlers Toxicity Concern OSHA Regulation (CAS No.)
INORGANIC FIBERS (Continued)
Calcium sulfate (Franklin See Inorganic Extenders
fiber)
Carbon
Carbon-dia..ond
. Chromium Toxic Inhalation 1 ..g/..3 TWA (7440-47-3)
" Intravenous, rat Suspected CarcInogen
I
J TDto:260 ug/kg/6W
J Toxic Effect: Tumorlgen
1
.\ Copper See Ino rganic Extenders
,i
! Fybex (See Potassiu.. tItanate)
Glass InhalatIon, hUlDSns Inhalation (Fibrosis) 5 "'8/..3 TWA (14808-60-7)
""-J LCLo: 300 ug/m3/loY (reco_nded)
0\
\0 Graphite 10 "'8/..3 TWA
(reco-ended)
IIa fia (cera..ic) (Hf02)
Iron See Inorganic Extendera
Iron-nickel
llagneaia (MgO) See Inorganic Extenders
(llagnealum Oxide)
MagnesIum Oral, dog Fire Rlsk (7439-95-4)
L°Lo: 230 mg/kg
Molybdenum Nontoxic 10 mg/m3 TLV (7439-9B-7)
Intraperitoneal, rat (reco-ended)
LoLo: 114 mg /kg
Nickel Toxic Inhalation 1 "'8/..3 TWA (skin) (7440-02-0)
Oral, guInea pIg Positive AnImal
L0Lo: 5 mg/kg Carcinogen
(Continued)
-------
TABLE C-8 (Continued)
I
j
1 Fillers Toxicity Concern OSHA Regulation (CAS No.)
. : INORGANIC FIBERS (Continued)
,J
;~j Sapphire (See Aluminum Oxide)
j 10 mg/m3
. 'Frocessed mineral fiber
.;j i'
'" (recommended)
': ~ Potassium titanate (Fybex)
!
.1 (KzO.(TiOZ)n n-4-1)
:J
. 1 Quartz (ceramic) See Inorganic Extenders
1 (Silica)
\ Silica See Inorganic Extenders
'
<: (Silica)
Silicon carbide (Silag) See Inorganic Extenders
Silicon nitride
-..J
-..J Sodium aluminum hydroxycar-
0 bonate (Dawsonite)
Steel See Inorganic Extenders
Tantalum Toxic Inhalation 5 mg/m3 'NA (1440-Z5-1)
Impregnation, mouse Fire Risk
TDLo: 3160 mg/kg
Toxic Effect: Tumorigen
" "
.i Thoria (ceramic) (ThOZ) Intramuscular, mouse 0.1 mg/m3 'NA (1314-Z0-11
'J TDt.,:400 mg/kg (skin) (recommended)
Toxic Effect: Tumorigen
Titanium Low Fire Risk
., Tungaten Low Flammable 5 mg(W)/m3 'NA (1440-33-1)
i Intraperitoneal, rat (recommended)
':~ LD50:5000 mg/kg
Tungsten monocarblde
Wollaatonite (CaSi03) Nontoxic Irritant Dust 10 mg/m3 'NA (13983-11-0)
.,
,
,
i
,
(Continued)
-------
j
j
j
1
.i
1
Fillers
INORGANIC FIBERS (Continued)
Zirconis (Zr02)
Zircon (66% Zr02 + 33%
Si02)
ORGANIC FIBERS
NATURAL
Abscs (Hanils hemp)
Broomroot
a-Cellulose (Paper pulp)
Coir
......
......
f-'
Corn cobs and stalks
Cotton flock
Cotton linters
Cottonseed hulls
Crin vegetal
Flax (Bast fibers)
Hemp
Henequen
IsUe (Tampico)
Jute (Bast fibers)
TABLE C-8 (Continued)
Toxicity
See lnorgagic Extenders
See Inorganic Extenders
Inhalation, humans
TCLo:IO,OOO mg/m3/10Y
Toxic Effect: Pulmonary
Irritation
Moderate
See Cotton flock
Concern
Inhalat ion
Flammable
Inhalation
Flammable
Combustible
Combustible
Combustible
Combustible
OSHA Regulation
10 mg/m3 TWA
(recollDlended)
1 mg/m3 TWA
1 mg/..3 TWA
(CAS No. )
(14940-68-2 )
(9004-34-61
:':
(Continued)
-------
'-,../"
j'
",
,j
, ~
j
j
, i
I
TABLE C-8 (Continued)
. ,
Fillers Toxicity Concern OSHA Regulation (CAS No.)
NATURAL FIBERS (Continued)
Kapok Combustible
Palm
Pslmyra
Psper Combus ti b le 10 IIg/1l3 'NA
(reco_ended)
Piassava
Ramie (Hemp) Combustible
Raffia
Sisal Moderate Inhalation
Combustible
~
~ Sunn
""
wood flour (Wood flock) Combustible 1 ma/m3 'NA (hard-
woods)
5 IIg/.3 'NA (soft-
woods) (recommended)
Wood cellulose (Paper pulp) Combustible See above
(See -cellulose 1
Wool
SYNTHETIC FIBERS
Acrylic Combustible ( 9003 -01-4 1
Arallid
Carbon
Fluorocarbon (PIFE) Impregnation, rat Poal ti ve Animal (9002-84-01
TDLa: 80 mglkg Carcinogen
Toxic Effect: Tumorigen
, i
"
, ,
! '.
(Continued)
-------
.-
-,
,
1
I
I
Fillers
SYNTHETIC FIBERS (Continued)
Nylon
Polyacrylonitrile (Dyne II,
(Orlonl
Polyester
Polypropylene
Polyvinyl slcohol
-...J
-...J
W
Polyvinyl chloride
Rayon
TABLE C-8 (Continued)
Toxicity
ImpregnatIon, rat
T~: 116 mg/kg
Toxic Effect: Tumorlgen
Subcutaneous. rat
TDLo: 2500 mg/kg
Toxic Effect: Carcinogen
Nontodc
Concern
Pod ti ve Animal
Carcinogen
Suspected Human
Carcinogen
OSHA Regulation
(CAS No.1
( 9003 -56-9 1
(9003-00-31
[9003-54-71
[25038-59-41
(9003-07-01
[9002-89-51
[9002-86-21
-------
"
....-
-
~ .-1
1
. i
.
TABLE C-9. FLAME RETARDANTS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
i
"
. j
,
,
.1
. ~
Flame Retardant Toxicity Concern OSHA Resulation (CAS No. J
INORGANICS
Alumina trihydrate Intraperitoneal, rat Mutaaen 2 ma(AI)/.3 TWA (21645-51-2 J
L~: 80 ma/ka (recommended)
Ammonium bromide Moderately Toxic Inaestion (12124-91-9)
Inhalation
Mutaaen
Toxic Fumes When
Heated
Ammonium fluoroborate 2.5 ma(F)/.3 TWA (13826-83-0)
Ammonium orthophosphate Low Inhalation (1183-28-0)
(Ammonium phosphate, dibasic) Skin Contact
Ammonium pentaborate
Ammonium polyphosphate
...... 15 ma/m3 TWA
...... Ammonium sulfamate Moderate loges tion (1713-06-0)
.po Oral, rat Can be Explosi ve (recommended)
LD50:1600 ma/ka
Antimony pentoxide Toxic Inhalstion 500 ua(Sb)/m3 TWA (1314-60-9)
Intraperitoneal, rat Oxidizer
LOW: 4000 ma/ka Moderate Fire Risk
Antimony trioxide Toxic Hay Cause Dermatitis 500 ua(Sb)/..3 TWA (1309-64-4)
Intraperitoneal, rat Inhalation
LD50:3250 ma/ka Mutaaen
Barium metaborate (21043-84-1)
Borax Moderate Inaestion 5 ma/.3 TWA (skin) (1303-96-4)
Oral, rst (recolD1lended)
LD50:5330 ma/ka
Boric Acid Oral, human Primary Irritant (10043-35-3)
LOW: 200 ma/ka
Dia1DlDonium phosphate (See
Ammonium Orthophosphate)
Disodium octaborste Oral, auinea pia [12008-41-2)
LD50:53oo ma/ka
(Continued)
-------
.'
.j
1
1
.
I
i
,
J
TABLE C-9 (Continued)
Flame Retardant Toxicity ~ OSHA Regulation [CAS No.)
INORGANICS (Continued)
Ferrocene Oral, rat Toxic Fumea When 10 .g/.3 1\IA [102-54-5)
LD50:1320 mg/kg Heated (recommended)
Equivocal Tumorigenic
Agent
Magneaium aulfate heptahydrate Low Mutagen Monohydrate
Intraperitoneal, rat [14567-64-7)
Mutation: 450 .g/kg
Molybdates
Molybdenum oxide Toxic [1313-29-7)
Molybdenum complex
Honoammonium phoaphate Low Toxic Fumes When [7722-76-1)
(Ammonium phosphate, monobaaic) Heated
"
" Hulti-metal complex.
VI
Red phoaphorus Hay React
Spontaneously
Sodium anti.onate Toxic Ingestion 0.5 mg(Sb)/.3 1\IA [15593-75-6)
Inhalation [11112-10-0)
Mutagen
Zinc borate Low [13701-59-2)
[14720-55-91
[Zinc oxide + Boric oxide) [12513-27-8)
CHLORINATED COMPOUNDS
Chlorinated hydrocarbons
Chlorinated paraffins Primary Irritant [63449-39-8)
Low
Skin, rat
100 mg/24H
Toxic Effect:
Irritation
MUd
Dechlorane Plua
Post ti ve Animal
Carcinogen
Suspected Human
Csrcinogen
[13560-89-9 )
Oral, rat
TDLo: 46 mg/kg
Toxic Effect: Reproduc-
tive, Developmental
(Continued)
-------
/
Flame Retardant
CHLORINATED COMPOUNDS
( Continued)
Dispersions (Chlorinated
Organics)
Hethyl pentschlorostearate
Trichloroethylene
BROHlNATED COMPOUNDS
"
"
0\
I,Z-Bis(2,4,6-tribromophenoxy)-
ethane
Bis(Z,4,6-tribromophenyl)-
csrbonate
I,Z-Bis(tetrabromophthslimido)-
ethane
Brominated organics
Decsbromobiphenyl
Decabromodiphenyl oxide
[Decsbromodiphenyl ether)
1-(I,Z-Dibromoethyl)-
3,4-dibromocyclohexane
Hexabromobeozene
Hexabromocyclodecane
Octabromodiphenyl oxide
TABLE C-9 (Continued)
Toxicity
Toxic
Eye, humans
5 ppm
Toxic Effect:
Irritation
Nontoxic
Oral, rat
LD50:>10 g/kg
Oral, rat
IOu, : 100 mg/kg
Toxic Effect: Reproduc-
tive, Fertility
Oral, rat
LDSO:>4 gm/kg
~
Positive Ani1881
Cercinogen
Inhalation
Skin and Eye
Irritant
Toxic Fumes Formed on
llesting
Tumorigen
Teretogen
Liver and Kidney
Injury
OSHA Regulation
100 ppm TWA
200 ppm Ceiling
300 ppm/5 Hin./2 Hr.
Peak
ICAS No.)
119-01-6)
[67990-32-3 )
137853-59-1 J
[32588-76-4 J
[1163-19-5 J
13322-93-8 J
[87-82-1 J
[25637-99-4 J
(Continued)
-------
Flame Retardant
BROMINATED COMPOUNDS
(Continued)
Pentabromodiphenyl oxide
Pentabromoethylbenzene
Penta bromo toluene
Tetrabromoxylene
MIXED HALOGEN COMPOUNDS
Brouinated organics
Pentabromochlorocyclohexane
......
......
......
MIXED HALOGEN/PHOSPHORUS
COMPOUNDS
Chlorinated mixed phosphate
Chlorinated organic phosphonate
Bis(2-chloroethyl)2-chloroethyl
phosphonate
Ethylene bis(tris(2-cyanoethyl)
phosphonium)bromide
Chlorinated polyphosphate
Halogenated organic diphoaphate
(chloroneopentyl type)
Halogenated phosphorus compound
Halogenated organic polyphos-
phonate (Chloroethyl phos-
phonate (polymeric)1
Phosphonated chloroepoxy
Phosphonium bromides
(bisphosphonium compounds)
TABLE C-9 (Continued)
Toxicity
~
Oral, rat
L050' 10 gm/kg
OSHA Regulation
(CAS No.)
(32534-81-9 )
(85-22-3)
(32534-81-91
( 87 -8)-21
(23488-36-21
(25495-99-2 1
(10310-38-01
(Continued)
-------
F lame Retardant
MIXED HALOGENlpHOSPHORUS
COMPOUNDS (Continued)
3,9-Tribromoneopentoxy-2,4,8,-
lo-tetra- oxa-3,9-diphospha-
spiro(5,5)-undecane-3,9-dioxide
Tris(2-chloroethyl)phosphste
Tris(1-chloro-2-propyl)-
phosphate
Tris(l,3-dichloro-2,propyl)-
phosphate
-...J
-...J
00
PHOSPHORUS COMPOUNDS
Bis(5,5-dimethyl-2-thiono-l,3,-
2-dioxaphosphor~nanyl)oxide
t-Butyl phenyl diphenyl
phosphste
Cresyl diphenyl phosphste
Dismyl amyl phosphonste
Dimethyl methylphosphonate
2-Ethylhexyl diphenyl phosphate
(Octyl diphenyl phosphsteJ
Isopropyl tri(dioctyl
phosphate) titsnste
Isopropyl tri(dioctyl
pyrophosphate)titsnate
Isodecyl diphenyl phosphste
.!
TABLE C-9 (Continued)
Toxicity
Intraperitonesl, rat
LD50:250 mg/kg
Intravenous, mouse
L050:56 mg/kg
Oral, rat
TDLo: 3600 mg/kg
Toxic Effect: Reproduc-
tive, Fertility, Embryo-
toxicity
Intravenous, mouse
LOto: 100 mg/kg
Oral, rat
LD50:6400 mg/kg
Intravenous, rabbit
LOto: 272 mg/kg
~
Suspected Carcinogen
Tumor1gen
Primary Irritant
Inhalation
Mutagen
Teratogen
Ingestion
OSHA RegulatioD
(CAS No. J
(115-96-8 )
(13674-84-5 )
(13674-87-8)
(981-40-8)
(56803-37-3)
(26444-49:-5 )
(156-79-6 )
(1241-94-7)
(29761-21-5)
(Continued)
-------
./
TABLE C-9 (Continued)
Flame Iletardant Toxicity Concern OSHA Ilegulation (CAS No.)
PHOSPHOIlUS COMPOUNDS
(Continued)
Iaopropylphenyl diphenyl (26967-76-0)
phoaphate
Phenyl phosphonatea
Phenyl phosphonate from
aulfonyl-biaphenol
Phosphine oxides
Octyl diphenyl phoaphate Skin Contact (115-88-8 )
Inhalation
Phosphonate esters
(Cyclic phoaphonate)
..... Iled phosphorua treated wi th
..... caprolactam
\0
Tributoxyethyl phoaphate Hay be Todc Heating Ileleaae (18-51-3)
Oral, guinea pig Todc Fumea
LD50:3000 mg/kg
Trlbutyl phosphate Toxic Ingestion 5 mg/.3 'IlIA (126-73-8)
Oral, rat Inhalation
LD50:3000 mg/kg Skin Irritant
Toxic Fumes When
Heated
Tricresyl phosphate Hoderately Toxic Ingestion Ortho - 0.1 mg/m3 (1330-78-5)
Oral, rat Skin Absorpt Ion 'IlIA Ortho (18-30-8)
LDLa: 4680 mg/kg Primary Irritant
'l'umorlgen
Tricresyl phosphate d1apera1ons (See Tricresyl phosphate)
Triethyl phosphate Oral, rat Mutagen (18-40-0)
LDLa: 1600 mg/kg Hay Cause Nerve
Damage
Slight Irritant
Triisopropyl phenyl phosphate
(Continued)
-------
TABLE C-9 (Continued)
Flame Retardant Toxicity Concern OSHA Regulation (CAS No.)
PHOSPHORUS COMPOUNDS
(Continued)
Trioctyl phosphate Low (1806-54-8)
Oral, rat (78-42-2)
LD50:37 gm/kg
Triphenyl phosphate Toxic Inhalation 3 mg/m3 'NA (115-86-6 )
Oral, rat Ingestion
~: 3000 mg/kg Eye Contac t
Triphenyl phosphine oxide
Trixylenyl phosphate (25155-23-1)
(Tri(dimethylphenyl) phosphate)
Rl!ACTIVl! ORGANICS
Alkoxide adducts of TBPA
......
00 Allyl ether of pentabromophenol
0
Allyl ether of TBBPA
Bis(dibromopropyl ether) of
TBBPA
Bis(2-chloroethyl) vinyl
phosphonate
Bis(methyl ether) of TBBPA
Bromine-phosphorua polyol
3-Bromo-2,2-bia(bromomethyl) (1522-92-5)
propanol
Bis(chlorendo)cyclooctadiene
Bis(chlorendo)furan
Chlorendic acid (hexachloro- Oral, rat Tumorigen (115-28-6)
endomethylene-tetrahydro- LD50:1770 mg/kg
phthalic acid), (HET Acid)
(Continued)
-------
/
TABLE C-9 (Continued)
Flame Retardant Toxicity Concern OSHA Regulation ICAS No.)
REACTIVE ORGAHICS
(Continued)
Chlorendic aohydridelheza- Eye Irritant 1115-27-51
chloroeodomethylene-tetra-
hydrophthalic aohydridel IHI!T
Anhydridel
Chlorine-containing polyol
Diacrylate of ethylene ozide
adduct of TBBPA
trana-2,3-Dibromo-2-butene- 13234-02-41
1, 4-diol
Dibromoneopentyl glycol Oral, rat (3296 -90-0 1
LD50:3458 IIg/kg
'-I Dibrollophenol Oral, mouse 1615-58-71
00 LD50:282 mg/kg
......
Dibromopropanol Iotraperitoneal, mouse Tumorigen 196-13-91
LOto: 125 mg/kg Mutagen
Dibromopropyl acrylate 13066-70-41
O,O-Diethyl-l,N,N-bia-
(2-hydrozyethyl) allinomethyl
phosphonate
Di(polyozyethylene) hydromethyl
phosphonate
Ethylene oxide adduct of TBBPA
Epibromohydrin Intraperitoneal, mouse Mutagen 13132-64-71
LD50:30 mg/kg
Hexabromobutene
Hex8chlorocyclopentadiene Oral, rat Tumorigen 10 ppb TWA (77-47-41
LD50: 115 mg/kg Teratogen (recommended)
Primary Irritant
Ingestion
Inhalation
Skin Absorption
(Continued)
-------
TABLE C-9 (Continued)
Flame Retardant Toxicity Concern OSHA Regulation ICAS No.)
REACTIVE ORGANICS
(Continued)
Oligomeric phosphate esters
Oligomeric phosphite
Pentabromophenol Intraperitonal. lIouse 1608-11-9)
LDLo:2S0 mg/kg
Phosphorus-containing polyols
Idiol from propylene oxide and
dibutyl acid pyrophosphate). ,.,
Ihigh functionality polyol)
Tetrabromobisphennl A ITBBPA) (79-94-7)
Tetrabromophthalic anhydride 1632-79-1)
ITBPA)
i -...J Tetrabromovinyl cyclohexene
.00
N Tetrachlorophthalic anhyd ride Slight Skin Contact Smg/m3 TWA 1117-08-8 J
IC6CI4(CO)20) Oral. rat Ingestion (recommended)
TOW: 70 gm/kg Inhalation
Toxic Effect: Reproduc- Hutagen
tive. Paternal
Tetrskis(hydroxymethyl)-
phosphonium sulfate
Tribromoneopentyl alcohol
Tribromophenol IBromolJ. Hay be Toxic 1118-79-6 J
IC6H2Br30H) Oral, rat
LDSO:200 mg/kg
Tris(dipropylene glycol)
phosphate
Vinyl bromide ICH~HBr) Hoderate Inhalation 1 ppm TWA I S93-60-2 J
Oral. rat TUllOrigen (recommended)
LDSO:SOO mg/kg Hutagen
Indefinite Animal
Carcinogen
Eye Irritant
, .
-------
TABLE C-IO. FREE RADICAL INITIATORS AND RELATED COMPOUNDS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Chemical
ORGANIC INITIATORS
ALKYL PEROXIDES
o,o,Bia(t-butylperoxy)
diiaopropylbeozene
Bis(p-methoxybenzoyl peroxide)
t-Butyl cumyl peroxide
Di-t-butyl peroxide
Dicumyl peroxide (Bis(o ,"-
dimethylbenzyl)peroxide)
......
00
W
2,5-Dimethyl-2,5-bia(t-butyl-
peroxy)hexane
2,5-Dimethyl-2,5-bia(t-butyl-
peroxy)hexene-3
Hydroxyheptyl peroxide
Octyl peroxide [caprylyl
perodde)
DIACETYL PEROXIDES
Acetyl Perodde
Acetyl benzoyl peroxide
Todcity
Eye, rabbit
500 mg/248
Todc Effects:
Irritatioo
KUd
Oral, rat
LD50: 4100 mg/kg
Moderately Toxic
Eye, rabbit
60 IIg/lK
Toxic Effect: Severe
lrritatioo
Moderately Toxic
Concern
Tumorigeo
Primary Irritant
Pi re Risk
Inhalation
Oxidizer
Ignit ioo Source
Irritaot
Irritant
Strong Oxidizer
Kay Igoite
Orgaoics
Fi re Risk
Strong Oxidizer
Reactive
Fire Risk
St roog Oxidizer
Irritsot
Tumorigeo
Ingestion
Irritsot
Explosive
OSHA Regulation
[CAS No.)
[110-05-4 )
[80-43-3 )
I,; I;
~'
I
. ,
. II
;, y,
, ' ,
I '~""
. ".( I
'i ~ I
1"1 ; i I'
[75:i0~741
[19102;:7yO)
" ,
0:. ,~
[110-22-5 )
[644-31-5)
(Continued)
-------
Chemical
DLACETYL PEROXIDES (Continued)
Benzoyl peroxide (various
forms )
Bis(4-t-butyl benzoyl peroxide)
Bis(-o-bromobenzoyl peroxide)
Bis(-m-bromobenzoyl peroxide)
Bis(p-bromobenzoyl peroxide)
Bia(p-methoxy benzoyl peroxide)
Di-p-chlorobenzoyl peroxide
.......
00
~
Decanoyl peroxide
Dichlorobenzoyl peroxide (0 and
p)
Di-2,4-dichlorobenzoyl peroxide
(in vsrious mixtures)
Diisononsnoyl peroxide
Lauroyl peroxide (Didodecanoyl
Peroxide)
Pelargonyl peroxide
Propionyl peroxide
DlBASIC ACID PEROXIDES
Succinic Acid Peroxide
TABLE C-10 (Continued)
Toxicity
Eye, rabbit
500 mg/248
Toxic Effect:
Irritation
Severe
Intrsperitonesl,
mouse
LI>[.o:500 mg/kg
Intraperitonesl,
mouse
LDLo: 500 mg/kg
Intraperitoneal,
mouse
LDLo: 512 mg/kg
Toxic
Subcutaneous. mouse
TDLo: 185 mg/kg/4&1
Toxic Effect: Equi-
vocsl Tumorigenic
Agent
Inhalation, rat
LCLo: 100 pp..
Concern
. Allergen
Irri tant
Explosive
Tumorigen
Fire Risk
Strong Oxidizer
Explosive
Oxidizing Agent
Fire Risk
Tumorigen
Primary Irritant
Ingestion
Inhslstion
Explosive
Skin Irritant
Fire Risk
OSHA Regulation
5 mg/1I3 'l'WA
(CAS No,)
(94-36~)
1'1:
(94-17C7 )
. !I ~.
I I
(76~~12.-9) ,
I'll
(94t17;il.\
: ~'ll
tl , ~ :1
(80J43f3} I,
,
'i' ',,""
. ,
ti 'II
, (105-74-8)
(3248-28-0 )
(Continued)
-------
Chemica 1
HYDROPEilOXIDES
Acetyl acetone peroxide (2,4-
pentanedione peroxide)
t-Amyl hydroperoxide
t-Butyl hydroperoxide
t-Butyl hydroxyethyl peroxide
Cumene hydroperoxlde [a,a-dl-
methylbenzylhydroperoxlde)
-..J
00
\J1
Cyclohexanone peroxide
Dlisopropylbenzene
hydroperoxide
2,5-Dil88thylhexsne-2,5-dihydro-
peroxide
p-Henthane hydroperoxide
Hethyl ethyl ketone peroxide
l,l,3,3-Tetramethylbutyl-2-
hydro peroxide
TABLE C-10 (Continued)
Toxicity
Hoderately Toxic
Skin, rabbit
500 mg/24H
toxic Effect: Severe
Irritation
Toxic
Inhalation, rat
LC50: 220 ppm/4H
Toxic Effect:
Pulmonary System
Eye, rabbit
80 mg/lK
Toxic Effect:
Irritation
Severe
Unknown, mouse
TDt.o: 391 IIg/kg
Toxic Effect: Equi-
vocal Tumorigenic
Agent
Unknown, mouse
TDLo:620 mg/kg
Oral, mouse
LD50:470 mg/kg
Concern
Hutagen
Primary Irritant
Tumorigen
Mutagen
Primary Irritant
Inhalation
Skin Absorption
Fire Risk
Strong Oxidizer
Primary Irritant
Skin Irritant
Inhalation
Tumorigen
Primary Irritant
Fire Risk
Strong Oxidizer
OSHA Regulation
200 ppb
[CAS No.)
[37187-22-7 )
[75-91-2)
[80-15-9)
[78-18-2)
,[ 12262-58-7)
[26762-93-6)
None
[80-47-7)
[1338-23-4 )
[5809-D8-5 )
(Continued)
-------
"
Chellical
PI!ROXYCARBOHATES
Bis(4-t-butylcyclohexyl)peroxy-
dicsrbonate
oo-t-Butyl-o-isopropyl mono-
peroxycarbonste
oo-t-Butyl-o-2(ethylhexyl)mono-
peroxycsrbonste
Di(sec-butyl)peroxydicarbonate
Di(2-ethylhexyl)peroxydlcar-
bonate
DIlsopropyl peroxydicarbonste
'-I
CO
0\
Di(2-phenoxyethyl)peroxydl-
carbonate
DI(n-propyl)peroxydlcsrbonate
PI!ROXYI!STERS
t-Amyl perbenzoate
t-Amyl perneodecanoate
t-Amyl peroxy(2-ethylhexanoate)
t-Amyl peroxypivalate
n-Butyl-4,4-dI(t-butylperoxy)
valerate
TABLE C-IO (Continued)
Toxicity
Oral, rat
LD50:1020 IIg/kg
I!ye, rabbit
500llg
ToxIc Effect: Severe
Irritation
Oral, rat
LD50: 2140 IIg/kg
Oral, rat
LD50:3400 IIg/kg
~
Primary IrrItant
OSHA Regulation
ICAS No.)
115520.,11-3 )
119910-65-7)
l16l11~2-9)
1105-64-6 )
) 16066-38-9)
(Continued)
-------
,
, .
Chemical
PEROXYESTERS (Continued)
t-Butyl peroxyacetate
t-Butyl peroxybenzoate
t-Butyl peroxycrotonate
t-Butyl peroxycyclohexane
t-Butyl peroxy(2-ethylhexa-
noate)
""-J
CO
""-J
t-Butyl peroxyisobutyrate
t-Butyl peroxyisopropyl
carbonate
t-Butyl peroxymaleic acid
t-Butyl peroxy-2-methyl
benzoate
t-Butyl peroxyneodecanoate
t-Butyl peroxyperphthalic acid
t-Butyl peroxypivalate
Butyl peroxy-o-toluate
Cumyl peoxyneodecanoate
Cumyl perpivalate
TABLE C-IO (Continued)
Toxicity
Eye, rabbit
100 IIg/lK
Toxic Effect: Moder-
ate Irritation
Oral, mouse
LDSO:632 mg/kg
Oral. mouse
LDSO:2S00 lIS/kg
Intraperitoneal,
mouse
L~: 128 IIg/kg
Oral, rat
LDSO:4300 mg/kg
Concern
Primary Irritant
Tumorigen
Primary Irritant
OSHA Regulation
',; I;
, II
~'
I
, .
I
I
, ;"u'"
I' ",
1I[c.\;'II\.1
.(1.1
II' "~'t
\I . { \
[10j7-h4i
I
" I'
, ,
OJ 11
[614-4S-91
[lS042-77-01
[927-01-1 J
(Continued)
",-
-------
Chemic:al
PEROXYESTERS (Continued)
Di(t-amylperoxy)c:yc:lohexane
Di-t-butylperoxyazelate
l,l-Di-t-butylperoxyc:yc:lohexane
1,I-Di(t-butylperoxy)-3,3,5-
trimethylc:yc:lohexane
Di-t-butyl diperoxyphthalate
2,5-Dimethyl-2,5-bia(benzoyl-
preoxy)hexane
"-j
2,5-Dimethyl-2,5-bia(2-ethyl-
hexanoylperoxy)hexane
~
00
00
2,5-Dimethyl-2,5-di(t-butyl-
peroxy)hexane
2,5-Dimethylhexyl-2,5-diperoxy-
2-ethylhexoate
Mixed pereaters
2,4,4-Trimethylpentyl-2-peroxy-
c:yc:lohexane carboxylate
SULFONYL ACETYL PEROXIDES
,.
Ac:etyl c:yc:lohexyl aulfonyl
peroxide
TERTlARY ALKYL PRB.KRTALS
2,2-Bia(t-butylperoxy) butane
1,1-Bia(t-butylperoxy)
c:yc:lohexane
j
,i
.:
"
i
'j
!
TABLE C-IO (Continued)
Toxic:ity
Concern
Intraperitoneal,
mouse
L~: 1700 mg/kg
OSHA &egulation
I,; I;
,11
l'
I
, .
;, /,
I. ' \
I '" 'i
"-J:
i Y S I
II '~I
I I , { \
I,t'li,
, ,
[CAG 110.)
,. ~
Or 'II
(78-63-7 )
(3179-56-4)
(Continued)
',...
I
1,:,
"
-------
TABLE C-IO (Continued)
Chemical Toxicity ~ OSHA Regulation [CAS No. J
TERTIARY ALKYL PERKETALS
(Continued)
l,l-Bla(t-butylperoxy)3,3,5-
trlmethylcyclohexane
n-Butyl-4,4-bla(t-butylperoxy)
valerate
Cyclic peroxyketals
l,l-Dl(t-butylperoxy)
cyclohexane
Ethyl-3,3-bla(t-butylperoxy)
butyrate
AZO COMPOUNDS
--.J 2,2'-Azobls(2,4-dl.ethyl-4-
00 methoxyvsleronltrlle)
\0
2,2'-Azobla(2,4-dlmethyl-
valeronltrile)
2,2'-Azobls-2-methylbutyro-
nitrile
2,2'-azobls(methyllsobutyrate)
2,2'-Azobls(lsobutyronltrlle) Toxic Ingestion [78-67-1 J
Intraperitoneal,
mouse
LD50:25 109/kg
Azo-cyclohexane carbonltrlle
2-t-Butylazo-2-cyanobutane
l-t-Butylazo-l-cyanocyclohexane
2-t-Butylazo-l-cyanocyclohexane
2-t-Butylazo-2-cyano-4-methoxy-
4-methylpentane
(Continued)
-------
-
",
j
TABLE C-10 (Continued)
Che.ical Toxicity ~ OSHA Regulation (CAS No.]
AZO COIIPOUNDS (Continued)
2-t-Butylazo-2-cyan0-4-methyl-
pentane
2-5-Butylazo-2-cyanopropane
, 2-t-Butylazo-2-methoxy-4-
methylpentane
'! ' -Diphenyl- -picrylhydrazine Intravenous. mouse (1898-66-4)
LD50:1800 ug/kg
"
INORGANIC INITIATORS
Ammonium Persulfste Oral, rat Strong Oxidizer 2 mg/m3 TWA (7727-54-0)
LD50:820 "'II/kg Fire Risk in (recommended)
Contact With
Organics
"-J
\C Ferrous Ammonium Sulfste Hexa- Orsl, rat (718]-85-9)
o
hydrate LD50:]250 mg/kg
Hydrogen Peroxide Toxic Irritsnt 1 ppm TWA (1722-84-1)
Inhalation, mouse Fi re and Explo-
LCLo:227 ppm sion Riak
Stroog Oxidizer
Hutagen
Suspected Animal
Carcinogen
Oxygen Hutagen (1782-44-7)
Highly Flammable
"' ,: ~
Inhalation, humans
TCLo:100 pph/14n
Toxic Effect: Pul-
monary System
,- ,
Potassium Bisulfste
(7646-9]-7 )
Low
Oral, rat
LD50:2]40 mg/kg
Potassium Persulfate
2 mg/m3 TWA
(recommended)
(1727-21-1 )
Hoderately Toxic
Irritsnt
Strong Oxidizer
Fire Riak in
Contact with
Organics
(Continued)
-------
Chemical
INORGANIC INITIATORS
(Continued)
Sodium Hetabiaulfite
Sodium Peraulfate
PROHOTORS/ACTIVATORS
Alkaline Nitropruaside
Chromate-Arsenious Oxide Hixes
'-I
\0
......
Cobalt Naphthenate
Cobalt Octoate
6% Cobalt Octoate + 14% Potas-
sium Octoate + Triphenyl
Phosphite
Diethyl Aniline
N,N-Dimethylaniline
N,N-Dimethyl-p-toluidine
Ferrous Pyrophosphate
Ferrous Sulfate
Fer rous Sulf ide
TABLE C-10 (Continued)
Toxicity
Hoderate
Intraperitoneal,
rsbbit
LDr.o.192 mg/kg
Intraperitoneal,
mol\se;
LD50.226 mg/kg
Inhalation, humans
LDr.o.ll mg/kg 58
Oral, rat
LD50.3900 mg/kg
Hay be Toxic
Oral, rat
LD50:782 mg/kg
Toxic
Oral, rat
LDr.o.1410 IIg/kg
Low
Oral. rat
LDr.o: 138 9 IIg/kg
Concern
Ingestion
Inhalation
Primary Irritant
Skin Abaorption
Tumorigen
OSHA Regulation
5 mg/-' TWA
(recommended)
2 IIg/-' TWA
(recommended)
100 ug(Co)/-'
TWA
( recolll1llended)
5 ppll TWA (skin)
[CAS No,)
[7681-57-4 )
[7775-27-1)
[ 14402-89-21
[61789-51-3)
[91-66-7)
[1~1-69-71
[7782-63-0)
't~
.\
"
I
~r
'~,
~"
(Continued)
"
i .
v
-------
/
i
Chemical
PROMOTORS/ACTIVATOR (Continued)
Hydrazine
I
<~
Hydroquinone
!
1
"-I
1.0
N
Hydroxylamine
Lauryl Mercaptide
2-Hercaptobenzothiazole +
Cupric Chloride
2,4-Pentanedione (Acetylace-
tone)
Pyrogallol
TABLE C-10 (Continued)
Toxicity
Toxic
Inhalation, rat
LC50:570 ppm/4H
Toxic
Oral, humans
L~:29 mg/kg
Intraperitoneal,
mouse
LD50:59mg/kg
Inhalation, rat
5.02 ug/..3/HM
Toxic Effect: Muta-
gen
Low
Oral, rat
LD50: 3000 mg/kg
Oral, rat
LD50: 140 mg/kg
Moderate
Skin, rabbit
488 mg open
Toxic Effect:
Irritation
MUd
Toxic
Oral, rat
LD50:789 mg/kg
Concern OSHA Regulation (CAS No.)
Tumorigen 1 ppm TWA (skh) (302-01-2)
Mutagen
Ingestion
inhalation
Skin Absorption
Skin and Eye
Irri tant
Explosion Hazard
Suspected
Carcinogen
Ingestion 2 mg/..3 TWA (123-31-9)
Inhalation
Irritant
Tumorigen
Mutagen
Teratogen
Strong Irritant (7803-49-8)
Decomposes
Rapidly at Room
Temperature .~~
gye Injury 0.5 pp./15 M (112-55-0)
Inhalation Ceiling .,
'.
Mutagen (recollllllended)
i'
(149-30-4) 'h
,
..i
Ih
Mutagen (1344-67-8) ..~
Fire Risk (123-54-6)
Primary Irritant
...
Primary Irritant
Ingestion
Skin Absorption
Tumorigen
Mutagen
(87-66-1)
(Continued)
-------
J
1
1
1
1
J
"
'i '
,I
j
TABLE C-IO (Continued)
Chemical To"idty ~ OSHA Regulation (CAS No.1
PROHOTORS/ACTIVATOR (Continued)
Sodium Formaldehyde Sulfoxylate Probably To"ic (149-44-0)
Subcutaneous, mouse
LDt.o: 3000 mg/kg
Sodium Bydrosulfite (sodium Oral, humans Fire Risk (7715-14-61'
dithionite) TDt.o:300 mg/kg/7D Strong Reducing
Toxic Effect: Pul- Agent
monary System
Sodium Hyposulfite Oral, humans (10102-17-7)
TDt.o:300 mg/kg/7D
Sodium Sulfide Intraperitoneal, rat Mutagen (16721-80-5)
LD50:30 mg/kg Fire Risk
Strong Skin
Irritant
Add Sensitive
-..J (releases B2S)
\0
U) Sodium Thiosulfate Low Up to 0.1% in (10102-17-7)
Food
Sugar (de"trose),(gluc:ose) Nonto"ic ( 50-99-7)
Oral, rat
LD50:25,800 mg/kg
Thioglycolic Acid Toxic Ingestion 1 ppm TWA (skin) (68-11-1)
Oral, rat Inhalation ( reco-ended)
LD50:250 mg/kg Irritant to Skin
Vanadyl Acetyl Acetone
Versene Iron
INBIBITOIlS
Benzaldehyde Moderate Ingestion (100-52-7)
Oral, mouse Tumorigen
LD50:13 mg/kg Mutagen
Primary Irritant
,
J
i
,.
(Continued)
-------
...
.''-
'"
\
J
."1
'1
,J .
Chemical
INHIBITORS (Continued)
p-Benzoquinone
p-t-Butyl Catechol
Catechol
......
\0
.po
Chloroanll
Copper
2,S-Dichlorobenzoquinone
2,6-Dichlorobenzoquinone
Dinitrobenzene
Diphenylalline
2,S-Diphenyl-p-benzoquinone
Ferric Salts
Furfurylidene malononitrile
Hydroquinone (see PrOllotors/
ActivatorsJ
TABLE C-IO (Continued)
Toxicity
Todc
Orsl, rst
LDSO:2S0 IIg/kg
Skin, rsbbit
500 .g/24H
Todc Effect:
Irritstion
Severe
Oral, rst
LDSO: 3890 IIg/kg
Toxic
Oral, rat
TOto: 1520 \III/kg
Toxic Effect: Repro-
ductive, Developmen-
tal
Oral, rat
LOto:3OOD "'8/kg
Intravenous. mouse
LDSO:S600 IIg/kg
Concern
Inhalation
Strong Skin
I rri tant
TUllorigen
Mutagen
Indefinite
An ill8 1
Carcinogen
Skin Irritant
Todc Fumes
Inhalation
Ingestion
Flammable in
Powder Fol'll
Inhalation
OSHA Regulation
0.01 pp.. 1WA
5 ppm 1WA
Dust: 1 IIg/.,1
TWA
(rec01lllended)
10 "'8/,.3 TWA
20 IIg/.,1 STEL
(CAS No. )
(106-51-4 J
(9B-29-3 )
(120-80-9 J
(7440-50-8 )
(122-39-4 J
None
,.
.'
(Continued)
-------
TABLE C-10 (Continued)
Chemical Toxicity Concern OSHA Regulation ICAS No.)
~~
INHIBITORS (Continued)
1,4-Naphthalenediol Oral, rat 1571-60-8) 1,:,.
LDt.o:1OO Gg/kg
" i
Naphthoquinone Todc Irritant 1130-15-4) h
Oral, rat Equivocal
LD50: 190 mg/kg Tumorigen . I
:'h
Nitritea :~'!:
p-Nitrotoluene Oral, rat Inhalation 5 ppll TWA 199-99-{))
LD50:2144 mg/kg Ingeation
Skin Abaorption
Oxygen (02) 11782-44-7)
Pheny I anthraquinone
-...J N-Phenyl-a-naphthylamine Oral. 80use Mutagen 1135-88-61
\0 LD50:1450 mg/kg Animal
VI Carcinogen
Tumorigen
Picric Acid Oral, rabbit Ingeation 0.1 .8/,.3 TWA 188-89-11
LDt.o: 120 109/kg Skin Contact (akin)
Explosive
Pr imary and Secondary Amines
Pyridine Moderate Primary Irritant 5 ppm TWA 1110-86-1)
Oral, rat Ingestion
LD50:891 mg/k8 Tumorigen
Mutagen
Pyrogallol laee promotors/ 187-66-11
Acti vators)
Quinone
Sulfur Eye, humans Primary Irritant 11704-34-9)
8 ppm Fire Risk
Todc Effect: lrri- Explosion Risk
tat10n
Trinitrotoluene Moderate Inhalation 1.5 mg/.,3 TWA 1118-96-7)
Oral, rat Ingestion (skin)
LDt.o: 700 mg/kg
-------
.j
j
i
I
. t
'1
Heat Stabilizer
METAL COMPOUNDS
BARIUM
Barium benzoate
(Ba(C7H50Z)Z'ZHZO)
Barium bis(4-nonylphenoxide)
Barium caprate
Barium caprylate
Barium carbonate (BaC03)
"
\0
0'\
Barium Z-ethylhexanoate
I
;
'j
Barium laurate (Ba(CIZHZJOZ)Z)
Barium myristate (Ba(CI4HZ]OZ)Z)
B~riUII naphthenate
Barium nonylphenate
Barium oleate
Barium phenate
Barium phenoxlde
TABLE C-IL HEAT STABILIZERS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Toxicity
Concern
OSHA Regulation
500 ug(Ba)/.3 TWA
(recolllllended)
500 ug(Ba)/..3 TWA
(recolllllended) .
500 ug(Ba)/..3 TWA
(recolllllended)
500 ug(Ba)/..3 TWA
("recollUlended)
Toxic
Oral, rat
LD50:630 mg/kg
500 ug(Ba)/.3 TWA
(recolllllended)
Ingeatlon
500 ug(Ba)/..3 TWA
(recolllllended)
500 ug(Ba)/..3 TWA
(reco...ended)
500 ug(Ba)/..3 TWA
(reco_ended)
500 ug(Ba)/..3 TWA
(recolllllended)
500 ug(Ba)/..3 TWA
(reco_ended)
500 ug(Ba)/..3 TWA
(reco....ended)
500 ug(Ba)/..3 TWA
(recolllDended)
500 ug(Ba)/..3 TWA
(recollUlended)
-,.,
~~ ,
(CAS No)
;L
~1
i' t~1
:' .~
(41157-58-8)
( 513-77-9)
(Continued)
-------
Heat Stabilizer
BARIUM (Continued)
Barium rieinnleate
Barium silicate (BaSi031
Barium stearate (Ba(C18H3s02)21
CADMIUM
Cadmium benznate
(Cd(C78s02)2.2HZOI
Cadmium caprate
.....
\D
.....
Cad~ium caprylate
Cadmium 2-ethylhezanoate
Cadmium laurate
Cadmium lauryl mercaptide
Cadmium myristate
Cadmium naphthenate
,
't
TABLE C-ll (Continued)
Toxicity
Concern
T!,xie
Ingestion
Toxic
Oral, rat
LD50:950 mg/kg
OSHA Regulation
500 ug(Ba)/.3 TWA
(reenmmended)
500 ug(Ba)/.3 TWA
(reeo_ended)
500 ug(Ba)/.3 TWA
(reeo_ended) .
50 ug(Cd)/.3 TWA
200 ug(Cd)/m3 STEL
(reeo_ended)
50 ug(Cd)/.3 TWA
200 ug(Cd)/.3 STEL
(reeo...ended)
40 ug(Cd)/.3 TWA
200 ug(Cd)/.3/15
mn. ceiling
(reeo_ended)
50 ug(Cd)/.3 TWA
200 ug(Cd)/.3 STEL
(reeo_ended)
50 ug(Cd)/.3 TWA
200 ug(Cd)/.3 STEL
(reeo-ended)
50 ug(Cd)/.3 TWA
200 ug(Cd)/..3 STEL
(recommended)
50 ug(Cd)/.3 TWA
200 ug(Cd)/m3 STH
(reeo_ended)
50 ug(Cd)/..3 TWA
200 ug(Cd)/..3 STEL
(recommended)
i
l'
i"
(CAS No I
(2191-10-81
(2420-98-6 I
(Continued)
-------
Heat Stabilizer
CADMIUM (ConUnued)
Cadmium oleate
Cadmium phenate
Cadmium phoaphite
Cadmium ricinoleate
(Cd(CHj(CHZ)SCHOHCHZCH: CH(CHZ)7COZ) I
-..J
\0
CO
Cadmium stearate
:i
,
~
Calcium benzoate
(Ca(C7HsPZ)Z"3H2D1
Calc1U11 caprste
Calcium Z-ethylhezanoate
Calc1U11 laurste
(Ca(ClzHz3PZ)Z"H2D1
CalciUII naphthenate
Calcium oleate (Ca(CI8R3]OZ)Z)
Calcium phenozide (Ca(OC6HS)Z)
,
',,1
, !
. o.j
.i
~'j
",1
Concern OSHA RegulaUon (CAS No)
50 Ug(Cd)/83 TWA,
ZOO ug(Cd)/83 STEL
(reco_ended)
50 Ug(Cd)/83 TWA
ZOO ug(Cd)/83 STEL
(reco-ended)
50 Ug(Cd)/83 TWA
ZOO ug(Cd)/83 STEL
(reco-ended)
50 ug(Cd)/.3 TWA
ZOO Ug(Cd)/83 STEL
(reco_ended)
40 ug/83 TWA (ZZZ3-93-o)
ZOO ug/83/IS 8in.
ceiling
TABLE C-ll (Continued)
Todcity
Highly Todc
Highly Todc
Oral, rat
LDSO: 11ZS IIg/kg
(Continued)
-------
TABLE C-ll (Continued)
Heat Stabilizer Toxicity Concern OSHA aegulation (CAS Nol
CALCIUK (Continued)
Calcium ricinoleate Low Toxicity
ICa (CH 3( CH Z)5CHOHCHZCHCH( CHZ)7COZ)Z )
Calcium stearate (Ca(ClsH3sOZ)zl Low Toxicity (159Z-Z3-o I
HAGNESIUK
Hagnesium Z-ethylhexanoate
Hagnesium laurate
(Hg(CIZHZ30Z)Z"2HzOl
Hagnesium phenoxide
Hagnesium salicylate
(Mg(C7Hs03)z' 4HzOi
-...J Magnesium stearate Nontoxic Inhalation (557-04-01
\0 (Mg(CI8H350Z)zl
\0
MANGANESB
,
Manganese carbonate (MnC031 Inhalation 5 .g(Hn)/.3 TLV (598-6Z-91
Ingestion (recollllllended)
Primary Irritant
Manganese oxide, hydroxide (HnJ041 Nontoxic 3 Bg(Hn)/..3 'lVA (1317-35-71
(vapor) (recommended)
POTASSIUK
Potassium benzoate
IKC7H50Z'3HzOi
Potassium laurate (KOOCCUH231 Primary Irritant ( 10124 -65-91
Potaasium naphtheoate
(Continued)
-------
. {
. i
j
-j
i
]
,
.
Heat Stabilizer
POTASSIUK (Continued)
Potaaaium oleate [Cl]H3jCOOKI
Potaasium salicylate [KC]Hs031
Potassium stearate [KC18H3s021
~
SodilJIII benzoate [C6'lsCOONaI
. ,
Sodium borate [Na2840]OlO11zOl
Sodium carbonate [lIazC031
'Ii
.- ;1
- ~
-:~
'-:i
-1
-:)
/1
00
o
o
SodiUIII laurate
Sodium phosphate [Na3P04°1OHzOl
Sodium phosphite [2NaH2P03°~201
Sodium aalicylate [HOC6'l4COOIia I
Sodium stearate [IIaOOCCl]H351
..
STBONTIUK
Strontium 2-ethylhexanoate
Strontium laurate
. .
TABLE C-ll (Continued)
Toxicity
Eye, rabbit
12 mg/48H
Toxic Effect: Irritation
Nontoxic
Low
Oral, rat
LD50: 4100 mg/kg
Low
Low
Skin, rat
28 mg/24H
Toxic Effect:
Irritation
Severe
Low
Oral, rat
TOW: 250 mg/kg
Toxic Effect: Reproduc-
tive, Developmental
Intravenoua, doga
LOW: 10 mg/kg
Concern
Primary Irritant
Mutagen
Teratogen
Mutagen
Primary Irritant
Mutagen
Teratogen
OSHA Regulation
[CAS Nol
[143-18-01
[532-32-1 I
[1303-96-4 I
[49]-19-81
[629-25-4 I
[54-21-] I
[822-16-21
(Continued)
-------
.'
TABLE C~ll (Continued)
8eat Stabilizer Toxicity Concero OSHA Resulation [CAS No)
STRONTIUM (Continued)
Strontium naphthenate
Strontium stearate
, ZINC
-j
j Zinc benzoate [Zn(C18s02>2)
j Zinc caprate
j
I
Zinc caprylate [Zn(CsHls02)2) Oral. mouse [551-09-5)
LD50:2310 liS/itS
Zinc 2-ethylhexanoate (Zinc octoate). IDw [136-53-S 1
[Zn(OOCC8(C285)C489)21
Zinc laurate [Zn(C1282302)2) IDw
CO
0 Zinc naphthenate IDw [12001-S5-31
.... Oral, rat
LD50:4920 liS/itS
Zinc octoate [see Zinc caprylate)
Zinc oleate [Zn(ClS83~2)21 IDw Tumorisen (551-07-31
Oral, .ouae
TDLo:I0S0 gm/ItS/lY
Toxic Effect: Equivocal
TUllorisen
Zinc phenate
Zinc stearate [Zn(ClS83s02)2) Nontoxic 10 IIS/.3 1VA [557-05-11
Intratracheal, rat 20 IIS/1I3 STEL
LDID: 250 liS/itS (recollllended)
(Continued)
-------
(
,I
j
,I
TABLE C-ll (Continued)
1; -
''4
, i
: J
,:' j
::J
:'~
"!
,
, .
:
Heat Stabilizer Toxicity Concern OSHA Regulation [CAS No)
OTHER METAL STABILIZERS
Alumium stearate (Al(C1S"3S0Z)3) Nontoxic Z .g(Al)/.3 'IWA
(reco-ended)
Barium cadmium laurate Oral, rat SO ug(Cd)/.3 'IWA
LDSO:1696 IIg/kg ZOO ug(Cd)/.3 STEL
(recollllllended)
Barium cad.ium stearate 50 ug(Cd)/.3 'IWA (1191-19-3)
ZOO ug(Cd)/.3 STEL
(recommended)
Lithium stearate (LlC1SH3sOZ)
TIN
Dlbutyltin bis(n-butyl maleate) 0.1 mg(Sn)/.3 'IWA
(C4Hg)ZSn(OOCCH:CHCOOC4"9)Z) 0.2 I18(Sn)/.3 STEL
OJ (reco-ended)
0
N Dibutyltin S,S-bis(isooctyl thioglyco- Oral, rat 0.1 I18(Sn)/.3 'IWA [ZS16S-Z4-S)
late) (C4Hg)ZSn(SCHzC°OCS"11)Z), LDSO:SOO mg/kg O.Z .g(Sn)/.3 STEL
(Dibutyltin bis(isooctyl mercapto- (recollllended)
acetate»
Dibutyltin bis(lauryl mercaptide) 0.1 .g(Sn)/.3 'IWA [11SS-S1-S)
(C4"g)ZSn(SCIZ"ZS)Z) O.Z .g(Sn)/.3 STEL
(recollllllended)
Dibutyltin bis(n-octyl I18leate) 0.1 .g(Sn)/m3 'IWA
(C4"g)ZSn(OOCCH:CHCOOCsHl1)Z) O.Z I18(Sn)/m3 STEL
(recollllllended)
Dlbutyltin diacetate Oral, rat loges Uon 0.1 mg(Sn)/m3 'IWA (1061-33-0)
(C4Hg)ZSn(CZ"]OZ)Z) LDSO: 110 mg/kg O.Z .g(Sn)/m3 STEL
(recommended)
Dibutyltin dicaprylste (DibutylUn Oral, rat Primary Irrl tant 0.1 .g(Sn)/.3 'IWA (4131-11-S)
dioctoate) LDSO: 130 mg/kg O.Z mg(Sn)/.3 STEL
(recolllllended)
, ,
,
, ,
. .
..;
>.
, "
, "
(Continued)
-------
TABLE C-ll (Continued)
Heat Stabilizer Toxicity Concern ~SHA Regulation ICAS No)
TIN (Continued)
Dibutyitiri dilaurate Toxic Inhalation 0.1 q(Sn)/.3 !VA (77-58-7)
I(C4H9)2Sn(OOCCll"23)2), Oral, rat SkIn Irritant 0.2 .g(Sn)/.3 STEL
IDlbutyl tIn laurate) LD50: 175 IOS/kS (reco_ended)
Dibutyltin laurate-aaleate 0.1 .s(Sn)/.3 !VA
0.2 .s(Sn)/.3 STEL
(reco_ended)
Dibutyitin aaleate Toxic Inhalation 0.1 q(Sn)/83 tWA 115535-69-0)
ft
-------
,J
"
J
.1
!
TABLE C-ll (Continued)
.1
Heat StabUher Todeity Concern OSHA Regulation (CAS No)
TIN (Continued)
:J 0.1 .g(Sn)/.] TWA
,,'j Dl-n-octyltln bls(2-ethylhexyl maleste) Oral. rat (100]9-]]-5)
LD50:2760 .g/kg 0.2 .g(Sn)/.] STEL
1 (reeo_ended)
Dl-n-oetyltln dl1aurate 0.1 88(Sn)/.] TWA
0.2 8g(Sn)/.] STEL
(reeOlllllended)
Dl-n-oetyltln B-mereaptoproplonate 0.1 88(Sn)/.] TWA
(Dl-n-oetyltln thlodlproplonate) 0.2 .g(Sn)/.] STEL
(reeo8lDended)
Dl-n-octyltln maleate 0.1 .g(Sn)/.] TWA
0.2 .g(Sn)/.] STEL
(recommended)
Dl-n-octyltln maleate polymer 0.1 .g(Sn)/.] TWA
00 0.2 mg(Sn)/.] STEL
0 (reeoUlDended)
:j ~
(Haleoxyldloxy)bls(dlbutyl(lsuroyloxy) 0.1 .g(Sn)/m] TWA (132]9-20-8)
tin) 0.2 .g(Sn)/.] STBL
(recommended)
Thlabla(monobutyltln sulfide) 0.1 88(Sn)/.] TWA (]98]9-19-5)
[S(Sn(S)C4H9)2) 0.2 mg(Sn)/m] STEL
(reeo8lDended)
Thlablamonomethyltln bls(B-alkanoyloxy- 0.1 mg(Sn)/.] TWA
ethylmereaptlde) 0.2 8g(Sn)/.] STBL
(reeo_ended)
LEAD
Basic lesd carbonate Toxic Inhslation 0:15' .g(Pb)/.] TWA [1 ]19-46-6)
(2PbC03.Pb(OH)2). [White Lead) 0.45 .g(Pb)/.] STEL
(reeo8lDended)
Ba sic lead ehlorosl11eate [47% S102 + 0.15 .g(Pb)/m3 TWA .
3% Cl1 0.45 mg(Pb)/.3 STEL
(reeo_ended)
(Continued)
-------
TABLE C-ll (Continued)
Heat Stabilizer Todc:1ty Concern OSHA Regulation (CAS Nol
LEAD (Continued)
Baalc lead alilcate Toxic Inhalation 0.15 mg(Pb)/m3 TWA
(3PbO'2S102'2HzOI 0.45 mg(Pb)/m3 STEL.
(reco-ended)
Baalc lead s111catesu1fate (undlsclosed 0.15 ag(Pb)/m3 TWA
complex, 24% S102 + 60% S031 0.45 .g(Pb)/m3 STEL
(recolllllended)
Baalc lead sulfate Toxic Inhalation 0.15 mg(Pb)/m3 TWA
0.45 mg(Pb)/m3 STEL
(reco_ended)
Baslc lead sulfate phthalate 0.15 mg(Pb)/.3 TWA
0.45 mg(Pb)/m3 STEL
(recolllllended)
Dlbaalc lead phosphate [PbHP041 Toxlc Inha la tion 0.15 ag(Pb)/.3 TWA.
00 0.45 mg(Pb)/m3 STEL
0 (recolllllended)
\;11
Dlbaslc lead phosphlte Toxic Inhalation 0.15 mg(Pb)/.3 TWA [1344-40-7 I
[2PbO'PbHP03'1/2HzOI 0.45 mg(Pb)/m3. STEL
(reco_ended)
Dlbaalc lead phthalate Toxic Skln Absorption 0.15 mg(Pb)/.3 TWA (69011-06-9 I
[2PbO'Pb(OOC)2C~4'1/2HzOI 0.45 mg(Pb)/m3 STEL
(recommended)
Dlbaslc lead stearate 0.15 mg(Pb)/m3 TvA (56189-09-4 I
(2PbO'Pb(C1JH35COO)21 0.45 mg(Pb)/m3 STEL
(recommended)
Lead 2-butenedlolc acld [Lectro 781 0.15 mg(Pb)/m3 TWA (13698'-55-01
0.45 mg(Pb)/m3 STEL
(recommended)
Lead carbonate (PbC031 Toxlc Inhalation 0.2 mg(Pb)/m3 TWA (598-63-01
Oral, gulnea plg Ingestion (recommended)
LDLa : 1000 mg/kg Tumor 1gen
(Continued)
, .
i .
I"
-------
.;
J
.-
. !
I
!
Heat Stabilizer
LEAD (Continued)
Lead chlorosilicate (Lectro 60)
Lead chlorosilicate sulfate complex
[Lectro 80)
Lead-Z-ethylhexanoate
[Pb(C1H15Coo)Z)
Lesd nsphthenate
Lead salicylate [(Pb(OOC(OH)C6H4)Z)
ex>
o
0\
Lead silicate sulfate
Lead stearate [see NOrmal Lead Stearate)
Lead sulfate (PbS04)
Utharge (PbO)
MonobasIc lead sulfate [PbO'PbS04)
NOrmal lead orthosilicate [SiOZ
35-45%), [PbSi03)
TABLE C-ll (Continued)
Toxicity
Oral, rat
LD50: 5100 mg/ltg
Probably Todc
Toxic
Oral, guinea pig
LDLa:30 8II/kg
Toxic
Intraperitoneal, rat
LDLa: 430 mg/kg
Todc
Todc
Concern
Strong Tissue
Irritant
Inhalation
Primary IrrItant
Ingestion
Inhalation
'lUmorigen
Mutagen
Inhalation
Inhalation
OSHA Regulation [CAS No)
0.15 mg(Pb)/.3 TWA
0.45 .g(Pb)/m3 STEL
(recolllllended)
0.15 mg(Pb)/.3 TWA
0.45 mg(Pb)/m3 STEL
(recolllllended)
'0.15 mg(Pb)/m3 TWA
0.45 mg(Pb)/m3 STEL
(recoaaended)
0.15 .g(Pb)/m3 TWA [61190-14-5)
0.45 mg(Pb)/m3 STEL
(reco_ended)
0.15 mg(Pb)/m3 TWA
0.45 mg(Pb)/m3 STEL
(recol8lDended)
0.15 mg(pb)/m3 TWA
0.45 .g(Pb)/m3 STEL
(reco_ended)
ZOO ug(Pb)/m3 TWA [1446-l,4-Z)
ZOO ug(Pb)/m3 TWA [1311-36-8)
0.15 mg(Pb)/m3 TWA
0.45 mg(Pb)/m3 STEL
(recommended)
ZOO ug(Pb)/m3 TWA
[ 10099-16-0)
i .
(Continued)
-------
Heat Stabilizer
LEAD (Continued)
Normal lead atearate
(Pb(Cl ]H35COOh I
Tetrabaaic lead fumarate
(4PbOoPb(OOC)2C2H2'2HzOl
Tetrabasic lead sulfate
(4PbO.PbS04°HzOl
Tribasic lead maleate
(3PbO'Pb(OOC)2C282'1/2HzOl
00
o
......
Tribasic lead sulfate
(3PbOoPbS04°HzOl
ANTIMONY HERCAPTIDES
Antimony thioglycolate
Antimony S,S',S"-tris(isooctyl mercapto-
acetate) (Sb(SCHzCOOC8817)31
Antimony tris(lauryl mercaptide)
(Sb(SC12H25>3)
MISCELLANEOUS
2-Aminocrotonic acid
Benzoguanamlne
(C6'l5C3N3(NH2h I
Dicyandiamide (NHzC(NH)(NHCN»)
TABLE C-ll (Continued)
Todcity
Toxic
Oral, guinea pig
LDLo: 6000 mg/kg
Toxic
Toxic
Intravenous. mouse
LD50:180 IDg/kg
Intraperitoneal. mouse
LD50:100 mg/kg
Concern
Skin Absorption
Skin Absorption
Inhala tion
OSHA Regulation (CAS No)
001 mg(Pb)/m3 TWA (7428-48-0)
(recommended)
0.15 mg(Pb)/m3 TWA
0.45 mg(Pb)/m3 STEL
(recollllended)
0.15 mg(Pb)/m3 TWA
0.45 mg(Pb)/m3 STEL
(recommended)
0.15 mg(Pb)/.3 TWA
0.45 mg(Pb)/m3 STELo
(recommended)
0.15 IDg(Pb)/m3 TWA (12202-17-4)
0.45 mg(Pb)/m3 STEL (12397-06-7)
(recolIIDended)
0.5 mg(Sb)/m3 TWA
0.5 mg(Sb)/m3 TWA (27288-44 -4 )
0.5 mg(Sb)/..3 TWA (6939-83-9)
(20748-08-7 )
(91-76-9)
(461-58-5)
(Continued)
-------
TABLE C-ll (Continued)
Heat Stabilizer Toxicity Concern OSHA Regulation (CAS No)
MISCELLANEOUS (Continued)
Oipentaerythritol Low (126-S8-9)
(CHzOH)3CCHzOCHzC(CHzOH)3)
Oiphenylthiourea (Thiocarbanilide), Low (3898-06-0)
(CS(NHC6HS}z) Intraperitoneal, mouse (102-08-9)
LOSO:SOO .g/ltg
Glycerol Low (S6-81-S)
Pentaerythritol (C(CH20H)4) Oral. mouse Nuiaance Particulate S .g/.3 TWA (dust) (l1S-77-S)
LOSO: 2 S. S p/ltg (reco_ended)
a-PenyUndole (948-6S-2)
Sorbitol (C6"8(OH)6) (50-70-4)
Thiolauric anhydride (7362S-5O-4)
00 Trimethyolethane (CH3C(CH20H)3) (77-8S-o) I
o
00
Trimethylolpropane
(C2HsC(CHzOH)3)
j
-------
Lubricant/Processing Aid
FATTY ACIDS AND ALCOHOLS
8ehenic acid
Oleic acid
Palmityl alcohol
Stearic acid
Stearyl alcohol
ex>
o
\0
MIDES
8ehenamide
Erucamlde
Ethylene bisstearamide
Ethylene hydroxystearamide
12-Hydroxy-N-(2-hydroxyethyl)
stear amide
Hethylene bisstearamide
TABLE C-12. LUBRICANTS AND OTHER PROCESSING AIDS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
TOxicity
Nontoxic
Skin, rabbits
500 1118 ope...
Toxic Effect:
Skin, humans
75 IIg/3D-I
Toxic Effect:
Nontoxic
Skin, humans
75 mg/3D-8
Toxic Effect:
Nontoxic
Oral, rat
LD50:20 em/kg
Hild Irritation
Hild Irritation
Hild Irritation
Concern
OSHA Regulation
Prillsry Irritant
Hutage...
Primary Irritant
Primary Irritant
Tumor1gen
Tumorigen
(CAS No. J
(112-g0-1 J
(36653-82-4 )
(57-11-4)
(112-92-5)
(3061-75-4 J
(112-84-5 J
(110-30-5 )
(8031-03-9)
(12764-90-8)
(123-16-2)
(106-15-0)
I
I'I
(Continued)
-------
Lubricant/Proceaaing Aid
AHIDES (Continued)
Oleallide
Saturated fatty alii de
Stear alii de
Stearogusnalline
ESTERS
Acetylated partial eatera
12-Acetyloxy-9-octodecenoic
acid, butyl eater
co
......
o
Alkoxylated fatty acid eatera
Butyl atearate
Caator 011
Cetyl palmitate
Diethylene glycol monoatearate
Diethylene glycol oleate
Diethylene glycol ricinoleate
TABLE C-12 (Continued)
Toxicity
Low
Implant, mice
TDLo: 1000 IIg/kg
Toxic Effect: Carcinogenic
Oral, rat
TDLo:418 gm/kg
Toxic Effect: Reproductive,
Newborn Effects
Eye, rabbit
50llg
Toxic Ef fect:
Irritation
Non toxic
Nontoxic
Int~8pe~1toneal. mouse
LD50:200 mg/kg
Nontoxic
Nontoxic
Concern
Teratogen
TUllorigen
Primary Irritant
OSHA Regulation
(CAS No-)
(301-02-0)
1124-26-51
(140-04-5 J
(123-95-5 )
(8001-79-4 J
1106-11-61
(Continued)
:1 .
I'
III
-------
.-
Lubricant/Processing Aid
ESTERS (Continued)
Ethylene glycol distearate
Ethylene glycol monostearate
Ethyl stearate
Glycerol monooleate
Glycerol monoricinoleate
Glycerol-mono-12-hydroxy-
stearate
Glycerol mono8tearate
co
......
......
Glycerol trioleate
Glycerol tris(12-hydroxy-
stearate)
Guanidine stearate
Hardened vegetable oils
Hydrogenated castor oil (see
Glycerol tris(12-hydroxy-
stearate»)
Hydrogenated vegetable 011
Methyl 12-hydroxystearate
TABLE C-12
Toxicity
Skin, rabbits
500 mg/24H
Toxic Effect:
Mild Irritation
Nontoxic
Nontoxic
Intr~perltoneal. mouse
LlJ50:200 mg/kg
Low
(Continued)
Concern
Primary Irritant
OSHA Regulation
(CAS No.)
(111-61-5)
(1323-38-21
(31566-31-1)
(141-24-21
(Continued)
-------
TABLE C-12 (Continued)
Lubricant/Processing Aid Toxicity Concern OSHA Regulation ICAS No.)
ESTERS (Continued)
Methyl stearate
Hontan esters
Octyl Btearste
Pentserythritol tetrastearate
Polyo"yethylene glycol IIOno-
stearate
Sorbitan trioleate
Stearyl stearate 12778-96-3 I
Sulfonated castor 011 ITurkey 18002-33-31
{ Red OUI
00
~ Triglyceryl l2-hydro"yatearate
N
Triglyceryl pala1tate
Triglyceryl stearate
Hl!TALLIC SOAPS
Aluminum stearate Nontodc 2 .g/.3 TI/A 1637-12-7 I
(reeo_nded)
BariUII stearate To"ic 0.5 88/.3 TWA 16865-35-6 I
(ree_ended)
CadaiUII stesrate Highly Todc 40 ug/.3 TWA I 2223-93-() I
Inhalation, huaans 300 ug/.3/15 .in.
TeLo: 1800 ug/.3/2Y Ceiling (recommended)
Toxic Effect: Cardiovasculsr;
Metabolism, Nutrition
.-j
:~
'.,
, '
. I
(Continued)
-------
Lubricant/Proceasing Aid
METALLIC SOAPS (Continued)
Calcium oleate
Calcium ricinoleate
CalcIum stearate
Lead oleate
Lead stearate IOibasic lead
stearate 1
Lithium atearate
Hagnesium oleate
Hagneaium atearate .
co
I-'
W
Potassium stesrate
Sodium dioctyl sulfosuccinate
IOioctyl sodiua sulfosuccinatel
Sodium stearate
Stannous octoate
Stannous ricinoleate
Stannous stearate
TABLE C-12 (Continued)
Toxicity
Concern
Low
Low
Toxic
Skin absorption
Toxic
Oral, guinea pigs
LoLo: 6000 ag/kg
Skin absorption
Low
Nontoxic
Nontoxic
Low
Intravenous, dog
L0Lo'lO mg/kg
Toxic
OSHA Regulation
0.1 ag(Pb)/..3
(recommended)
100 ug(Sn)/m3 TWA
(recommended)
100 ug(Sn)/..3 TWA
(reco_ended)
100 ug(Sn)/..3 TWA
(recommended)
I .
,..1
1 CAS No.1
11592-23-01
(7428-48-01
(4485-12-5)
1557-04-01
1~22-l6-21
(Continued)
-------
I'
TABLE C-12 (Continued)
I'I
Lubricant/Processing Aid Todc1ty Concern OSHA Regulation (CAS No.1
METALLIC SOAPS (Continued)
Zinc oleate Low
Zinc stearate Nontodc 10 rag/.3 TWA . (557-05-11
Intratracheal, rat 20 .g/.3 STBL
LDLo:250 .g/I
-------
Lubricant/Processing Aid
POLYMERIC LUBRICANTS
(Continued)
Polyethylene vax
Polypropylene vax
Polytetrafluoroethylene vax
Polyvinyl acetate
Polyvinyl alcohol
00
......
lJ1
Silicone grease [see Silicone
011)
Sl1 icone 011
POLYMER FILMS AND SHEETS
Cellophane
Cellulose acetate
Cellulose acetate butyrate
Methyl cellulose
TABLE C-12 (Continued)
Toxicity
Impregnation, rat
TOW: J3 mg/kg
Toxic Effect: Tumorigen
Impregnatlon. rat
TOW: 80 IIg/kg
Toxic Effect: TUllorigen
Subcutaneous. rat
TOW: 2500 mg/kg
Toxic Effect: Carcinogen
Nontoxic
Nontoxic
Impregnation, rat
TOW: 18 mg/kg
Toxic Effect: Tumorigen
Nontox lc
Concern
Positive Anillal
Carcinogen
Positive Animal
Carcinogen
Positive Animal.
Carcinogen
Ca rel Rogen
OSHA Regulation
[CAS No.)
[9002-88-4)
[9003-07-0)
[ 9002 -84 -0 1
[ 9003-20-71
[ 9002-89-51
[9005-8l-61
[9004-35-7)
[9004-36-81
[9004-67-51
(Continued)
-------
. ,.
..7
TABLE C-12 (Continued)
Lubricant/Processing Aid Toxicity Concern OSHA Regulation (CAS No. I
POLYMER FlLHS AND SHEETS
(Continued)
Nylon Implant, rat Positive Ani....l (63428-83-11
TDw: 33 mg/ltg Care inogen
Toxic Effect: '1\1morigen
Polyethylene Impregnation, rat Positive Animal (9002-88-41
TDLo: 33 mg/ltg Carcinogen
Toxic Effect: '1\1morigen
Polyethylene terephthalate
Polyester (Hylarl Impregnation, rat '1\1morigen (25038-59-4 I I.
TDw: 116 mE/ltg
Toxic Effect: '1\1morigen ..
Polyte t ranuo roetl'ylene Impregnation, rat Positive Animal (9002-84-01
TDw: 80 mg/ltg Carcinogen
00 Todc Effect: '1\1morigen
.....
C\ Polyvinyl acetate (9003-20-11
Polyvinyl alcohol Subcutaneous, rat Carcinogen (9002-89-51
TDLo:2500 ..g/ltg
Toxic Effect: Carcinogen
Polymethacrylate Tumorigen (9003-01-41
Polydimethylsiloxane Nontoxic
Polytetrafluoroethylene
Polyvinyl chloride Nontoxic Suspected Human 19002-86-21
Carcinogen
Polyvlnylidene chloride
SI Hcone resins Nontoxic
(Continued)
. ;
I
-------
TABLE C-12 (Continued)
Lubricant/Processing Aid Toxicity Concern OSHA Regulation (CAS No.)
MISCELLANEOUS
Dibutyl phthslste Toxic Irritant 5 mg/m3 TWA (air) (84-14-2)
Oral, humans Causes Nausea
LOW: 140 mg/ks
Lecithin Nontoxic '
1;.
INORGANICS
Aluminum silicate (see Clay)
Calcium carbonate Nontoxic 10 ms/m3 TWA (1344-95-2)
(recommended)
Calcium silicate Nontoxic Irritant Dust 10 mg/m3 TWA (1332-58-1)
(recollllllended)
Clay Nontoxic Tumorigen 10 mg/m3 TLV (1182-42-5)
00 Intraperitoneal, rat (recommended)
...... TDLo:450 mg/kg/3W
--.J
Toxlc Effect: Carcinogen
Graphite Low Fire Rlsk 15 mppcf (1182-42-5)
Magneslum aiUate Toxic Inhalation 112001-26-2 J
Skin, humans Primary Irrltant
300 ug/3D
Toxic Effect: Mild Irritation
Mica Inhalatlon 20 mppcf (1321-44-2)
Irritant (1200-26-2)
Molybdenum disulflde Low Inhalation 10 mg/m3 TWA (1311-33-5)
(recollllllended)
Potassium sillcate
, II
I,; I:
~'
I
, I
(Continued)
, ,""
I' ."
I . \
I '\'..
//1
f I If:,
I ,~. j/ ;
, t .. 'i
\. I'
-------
"
TABLE C-12 (Continued)
,.
Lubricant/Processing Aid Toxicity Concern OSHA ReRulation (CAS No.)
INORGANICS (Continued)
Silica (fumed) Intraperitoneal, rat 80 mg/1I3/%SiOZ (7631-86-9)
LDLo'50 mg/kg
Talc Moderate Inhalation Z mppcf 11IA (14807-96-6)
~r1....ry Irritant (nonfibrous)
(reco_ended)
00
......
00
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, Ii
1'1 I;
\'
I
.
, ,"'
I' r.,
I " ,
, It \~. ;,
'ill
" ~,
\ I , ~ ,i
I,h~i.
~, I'
t:.'''''
i
;
, '
..1
-------
TABLE C-13. PLASTICIZERS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Plasticizer Todc1ty ~ OSHA Ilegulation ICAS No.)
PHTIIALATES
Alkyl benzyl phthalate 168S1 S-40-2 1
Bis(tetrahydrofufural)
phthalate
Butyl benzyl phthalate Ifoderste Ingestion 185-68-7)
Impregnation, mouse Inhalation
LDSO:3,160 mg/ks Skin Irritant
Indefinite Animal
Carcinogen
Butyl benzyl tetrachloro
phthalate
Butyl cyclohezyl phthslate Probably Low 184-64-0)
Butyl decyl phthalate Probably Low 189-19-01
CO Oral, rst
~ LDSO:21 gm/kg
\0
Butyl ethylhezyl phthslate Low 18S-69-8)
Butyl hexyl phthalate
Butyl isodecyl phthalate 142343-36-21
Butyl octyl phthalate Isee 184-78-61
Butyl ethylhezyl phthalate 1
Cyclohezyl benzyl phthalate
Cresyl benzyl phthalate
n-Decyl n-octyl phthalate Oral, rat 1119-07-31
LDSO:l.7 am/kg
Deeyl trideeyl phthalate
Diallyl phthalate Slightly Tode Skin Irritant 1131-17-91
Oral, rat
LDSO: 770 ms/kg
(Continued)
...........
-------
~
/
TABLE C-13 (Continued)
.'
Plasticizer Toxicity ~ OSHA Regulation [CAS No.)
PHTHALATES (Continued)
Di-n-amyl phthalate Oral, rat Inhalation [131-18-0)
TI>J.o: 8. 8 gm/kg Skin Contact
Toxic Effect: Reproduc-
tive; Paternal
Dibenzyl phthalate [523-31-9)
Dibutoxyethyl phthalate Low Teratogen [111-83-9)
[Dibutyl Cellosolve phthalate) Oral, guinea pig
LI>J.o:6000 mg/kg
Dibutyl phthalate Toxic Irritant 5 8g/...3 t'WA [84-14-2)
Oral, human Inhalation
TI>J.o: 140 ...g/kg
Toxic Effect: 8ehavorial
Symptoms; Gastrointestinal
Tract; Urogenital System
CO
N Dibutyl tetrachloro phthalate
0
Dicapryl phthalate [Dl-2-oc:tyl Low [131-15-11
phthalate), [Bls(-l......,thyl- Impregnation, mouse
heptyl) phthalate) LD50:14 p/kg
Dicyclohexyl phthalate Oral, rat Inhalation [84-61-1)
LD50:30 g.../kg
Didecyl phthalate Low Primary Irritant [84-17-5)
Percutaneous, rabbit
LD50: 11 gm/kg
Di(2,3-epoxypropyl) phthalate Oral, rat [1195-45-1)
LD50:1245 mg/kg
Diethoxyethoxy etbyl pbthalate
[Dicarbltol phthalate)
Dl(2-ethylbutyl) phthalate
Dl(2-ethylhexyl) phthalate Oral, rat Poaitive Animal 5 mg/...3 t'WA 1111-81-1)
[Dloctyl phthalate) LD50:. 31 p/~g Carcinogen
Mucous llembrane
Irritant
CNS Depressant
(Continued)
-------
TABLE C-13 (Continued)
Plastic:1zer Toxicity Concern OSHA Regulation [CAS No.1
PHTIIALATES (Continued)
Diethyl phthalate Moderate Primary Irritant 5 IIg/1I3 TWA [84-66-21
Inhalation, humans Ingestion 10 IIg/1I3 STEL
'lCLo: 1000 IIg/m3 Inhalation (recolIIIDended)
Todc Effect: Irritant to Eye and Hucous
Eye and Pulmonary System Membrane Irritant
CNS Depressant
Di-n-heptyl phthalate Sk in Contac t [3648-21-31
Dihexyl phthalate Low Primary Irritant [84-75-31
Skin, rabbit Skin Contsct
LD50: 20 gm/kg . loha laHon 1'1
Dihydroabietyl phthalate " '
, Ij ~
Diisobutyl phthalate Low [r4-69- 'I
Intrsperitoneal, rat t : I
00 LD50:3749 mg/kg ''{
N i' t
...... Diisodecyl phthalate Hoderate Irritant ~26761 0-01
'j , "~'...
Diisoheptyl phthalate [41t5"-~8-91
" ~ I
j D11sohexyl phthalate hOf8t9~-01
I. 'I:
D11sononyl phthalate Skin Contact [28553:'1'2-01
Inhalation 'e. .;
. .
Diisooctyl phthalate Low [2 75tiU26-3 1
Oral, rat
LD50:17.3 Ill/kg
Dilauryl phthalate
Dimethoxyethyl phthalate Low Irritant [117-82-81
Intraperitoneal, rat Hutagen
LD50: 3735 mg/kg
Dimethyl phthalate Toxic Primary Irritant 5 "'8/m3 TWA [131-11-31
Oral, rat Ingestion
LD50:6900 mg/kg Inhalation
Irritant
(Continued)
-------
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Plaaticizer
PHTHALATES (Continued)
Dimethyl iaobutyl carbinyl
phthalate
O1nonyl phthalate
Di-n-octyl phthalate
Di-o-octyl, n-decyl phthalate
Diphenyl phthalate
Dipropyl phthalate
(XI
N
N
Ditridecyl phthalate
Di(3,5,5-trimethylhexyl)
phthalate
O1undecyl phthalate
.".-. ,
""'; ~
Ethylhexyl decyl phthalate
2-Ethylhexyl i.odecyl phthalate
Keptyl nonyl phtbalate
n-Heptyl, n-oonyl, n-undecyl
phthalate
TABLE C-13 (Continued)
Toxicity
Low
Oral, rat
LD50:2000 mg/kg
Skin, rabbit
500 mg/24 Hr.
Toxic Effect: Hild
Irritant
Low
Hoderate
Low
Low
Skin, rabbit
10 mg/24 Hr. Open
Toxic Effect: Hild
Irritant
Eye, rabbit
100 mg
Toxic Effect:
Irritant
Hild
Concern
Primary Irritant
Skin Irritant
Inhalation
Primary Irritant
OSHA Regulation
[CAS No.)
[84-76-4)
1'1:
'1117-81-7)
II [11\,84-0)
I
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t I' Jr..~62-8)
1: ~h6~-17-9)
\' ~ . ~ \'
1.01*6-2)
I
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t) "'1'
13648-20-2)
[119-07-3)
[ 1330-96-7)
[19295-81-91
[70955-56-5)
[ 68515-44-6)
[68515-41-3)
[68515-42-4)
[68514-45-7)
[68515-43-5)
[ 3648-20-2)
(Continued)
-------
Plasticher
PHTHALATES (COntinued)
n-Hexyl, n-decyl phthalate
Hexyl octyl deeyl. phthalate
(20%/36%/44%)
(5%/56%/38%)
Isodecyl benzyl phthalate
Isooctyl Isodecyl phthalate
Methoxyethoxyethyl phthalate
Methoxyethoxyethyl benzyl
phthalate
00
N
W
Octyl benzyl phthalate
n-octyl, n-decyl phthalate
7-(2,6,6,8-Tetramethyl-4-oxa-
3-oxo-nonyl)benzyl phthalate
BISPHTHALATES
Ethylene glycol bls-(n-butyl)
phthalate
HEXAHYDROPHTHALATES
DI-2-Ethylhexylhexahydro-
phthalate
2-Ethylhexylhexahydro
isophthalate
TABLE C-13 (Continued)
Toxicity
Concern
Oral, rat
LD50:49 gm/kg
Low
Oral, rat
LD50:45 am/kg
OSHA Regulation
[CAS No.)
[25724-58-7 )
[68515-51-5 )
[68648-93-1)
[119-07-3)
[16883-83-3 )
(Continued)
-------
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Plasticher
ISOPHTHAIATES
Diethyl isophthalate
Di-(2-ethylhexyl) isophthalate
[Dioctyl isophthalate)
Diisooc:tyl isophthalate
Dimethyl isophthalate
, !
Dinonylphenyl isophthalate
TEREPHTHAIATES
Di-(2-ethylhexyl) terephthalate Low
[Dioc:tyl terephthalate)
co
N
.~
Chlorinated dioc:tyl terephtha-
late
TETRAHYDROPHTHALATES
[Chlorendates)
,
2-Ethylhexyl epoxy
tetrahydrophthalate
"
,}
i
PHTHALATE HIITIIRBS
AND UHSPECIPIBD
,J
Blend (50/50) of dioctyl and
dioctyldecyl phthalates
.:
Blend (50/50) of dioctyl and
didecyl phthalates
Hixed Alcohol phthalates
Hixed Alcohol phthalates
Hixed Normal Alcohol phthalates
TABLE C-13 (Continued)
Toxic:1ty
Concern
Low
Oral, rat
LD50:4390 mg/kg
Primary lrritant
Oral, rat
LD50:4390 mg/kg
OSHA Regulation
[CAS No.)
1636-53-3 )
[137-89-3)
[1459-93~ )
[6422-86-2)
(Continued)
-------
/
Plasticher
PHTHALATE IlIXTURES
AND UNSPECIFIED (Continued)
Strsight Chsin Alcohol
phthalates
Strsight Chain Alcohol
phthslates
Hixed alkyl phthslates
Mlxed-n-alkyl phthalates
Alkyl aryl phthalate
Alkyl aryl modifled phthalste
Alkyl aryl modifled phthalste
00
N
\J1
Hlgh molecular weight phthalste
. High IIIOlecular weight linear
phthalate
High solvating phthalate
Modlfied phthalate
Octyl fatty phthalate
High molecular weight phthalate
"polyester"
TRIHELLITATES
D1isooctyl 8Dnoisodecyl
trimellitate
Heptyl oonyl tri.ellitate
Heptyl oonyl undecyl trimelli-
tate
Isooctyl isodecyl trimellitate
TABLE C-13 (Continued)
Toxicity
Concern
OSHA Regulation
..
.
f
.
i, )'~
II 'i'.'
/l\
fl,h
I . ~-li
I . ~ i
\-."
[CAS No.)
t: ~1J"
[685U-60-6)
[68515-60-5)
[68515-58-2 )
(Continued)
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Toxicity
.!
TRlHELLITATES (COntInued)
n-OCtyl. n-decyl trImellltate
Tricapryl trImellltate
TrI-(2-ethylhexyl) trimeilitate Low
TrI~-hexyl trimeilitate
Trl1sodecyl trImel1Itate
Trl1sononyl trImel11tate
Trl1sooctyl trIl1ell1tate Low
TrI-n-octyl trImel11tate
00
N
0\
TrI-n-octyl n-decyl trlmelll-
tate
PYROHELLlTATES
Tetra-n-butyl pyromeilitate
Tetraethyl pyromeilitate
Tetramethyl pyromeliitate
EPOXY TYPE PLASTICIZERS
Bisphenol A dI8lycidyi ethers
(8.0-9.4% oxirane)
Nontoxic
SkIn, rabbIt
500 m8, Open
Toxic Eft ec t :
Irri tant
DI-2-ethylhexyl-4.5-epoxy
tetrahydro phthalate
(3.6-3.9% oxirane)
D1-1sodecyl tetrahydro-4,5-
epoxy tallate
TABLE C-13 (Continued)
Concern
PrImary Irritant
Mutagen
HUd
OSHA Regulation
, '"'.
I' r.,
I" \
I 'I',.
:', /.!
i ~ ~ '
,'I .. {It
:1 .h~i.
\', l
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",'1/
(CAS No. J
(3319-31-1 J
(36631-30-8 J
(53894-23-81
(21251-75-81
(89-04-31
(3319-31-11
(67989-23-51
(1675-54-3 J
'.-
(Continued)
.
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-------
Plaaticizer
EPOXY TYPE PLASTICIZERS
(Continued)
Diisodecyl-4,5-epo.y tetra
hydrophthalate (3.0% oxirane)
Epoxidized linseed oil (9.0-
10.0% odrane)
Epoxidized soybean oil (6.7-
7.0% odrane)
2-Ethylhexyl epoxy tallate
(4.4-4.9% oxirane)
Epoxy taUate
Epoxy fatty nitrile
co
N
....
Octyl epoxy stearate
(3.5-3.9% oxirane)
Octyl epoxy tallate
POLYESTERS AND OTHER POLYMERIC
PLASTICIZERS
Acrylic-type Polyester
Adipic Acid Polyeatera
Adipic Acid Polyesters
Low Vi acoai t y
Medium Viscosity
Medium Molecular Weight
Medium High Molecular Weight
Alkyda
TABLE C-13 (Continued)
Todcity
Concern
Oral, rat
LD50:20.8 gm/kg
Oral, rat
LD50:32 gm/kg
OSHA Regulation
(CAS No.)
(8016-11-3)
(8013-07-8 )
[61789-01-3)
[61788-72-5 )
[39363-92-3 )
[68583-85-7 )
(Continued)
-------
.i
Plaaticizer
POLYESTERS AND OTHBa POLYMERIC
PLASTICIZERS (Continued)
Azelaic acid polyestera
Butadieneacrylonitrile polymer
Easy processing polymeric
2-1!thyl-l,3-bexanediol
polyadipate
Neopentyl glycol polyadipate
Polybutylene glycol
Polyester, acetylated
00
N
00
Polyester, not acetylated or
not "terminated"
Polyester
Polypropylene glycol polyadi-
pate'
Polystyrene resin, polyalpha
methyl
Polyurethane-based polymeric
powder
Resinous plasticizer, EVA
terpolymer
Sebacic acid polyeater
Sebacic acid polyester oil
modI Hed
Sulfonamide-Formaldehyde
Reactive-type plastIcizer
TABLE C-13 (Continued)
Toxicity
Concern
OSHA Regulation
[CAS No.1
[39316-47-11
[39316-47-7)
(Continued)
-------
Plasticizer
PHOSPHATES
Alkyl aryl phosphate
p-t-Butylphenyl diphenyl
phosphate
Chlorophenyl diphenyl phosphate
Chlorinated diphosphate
Cresyl diphenyl phoaphate
Di-(2-ethylhexyl) phenyl
phosphate
Diphenyl octyl phosphste
00
N
\0
2-Ethylhexyl diphenyl phosphate
Halogensted organic phosphate
Isodecyl diphenyl phosphate
Isooctyl diphenyl phosphste
Isopropylsted phenyl phosphate
Isopropyl phenyl diphenyl
phos pha te
Phenyl isopropyl phenyl
phosphate
o-Phenylphenyl diphenyl
phosphate
Trisryl phosphate (synthetic)
Tributoxyethyl phosphate
TABLE C-13 (Continued)
Toxicity
Intravenous. mouse
LDJ.o: 100 109/kg
Oral, rat
LD50:6.4-12.8 gm/kg
Intrsvenous, rsbbit
LDJ.o : 272 109/kg
Intravenous, rabbit
LDJ.o: 272 109/kg
Hay be Toxic
Oral, guinea pig
LD50:3000 109/kg
Concern
Inhalation
Skin Contsct
Ingestion
OSHA ReguIstion
[CAS No.)
(981-40-8)
. [56803-37-3)
[38051-10-4 )
. [26444-49-5)
(78-31-9 )
(115-88-8 )
[1241-94-7 )
[29761-21-5)
[26967-76-0)
(78-51-3 )
'..".
".
"
":-r I
'1~
~'"
(Continued)
-------
TABLE C-13 (Continued)
Plaaticizer Toxicity Concern OSHA Regulation ICAS No.)
PHOSPHATES (Continued)
Trlbutyl phosphate Toxic: Inhalation 5 ~g/..3 'NA 1126-73-8)
Oral, rat Skin Irritant
LD50:3000 mg/ltg
Trlcresyl phosphate Toxic Primary Irritant Ortho - 0.1 188/..3 Ortho (78-30-8)
Oral, rat Inhalation 'IlIA Other 11330-78-5)
LDLo: 4680 mg/ltg Skin Absorption
Trlcresyl dlphenyl phosphate
Trlethyl phosphate Oral, rat Nerve Damage 178-40-0)
LOw: 1600 mg/ltg Slight Irritant
Mutagen
Trl-(2-ethylhexyl) phosphate Low 118-42-2)
Oral, rat ,''''
ex> LD50:37 gm/kg
lJ.) Trl-n-hexyl phosphate "
a "
Trllsopropyl phenol phosphate 1,,,
!
TrI-2-methoxyethyl phosphate "'"
Trlphenyl phosphate Toxic Inhalation 3 mg/1I3 'NA 1115-86-6) '1.,
Subcutaneous, cat . ~..:
LD50:100 mg/ltg
Trls(2-chloroethyl) phosphate Oral, rat Inhalation 1306-52-5)
LD50:1230 ..g/kg- Suspected Carcinogen 1115-96-8)
Trls(chlorophenyl) phosphste
Trls-chloropropyl pbosphate None
Trls(2,3-dlchloropropyl) Oral, rat Mutagen 118-43-3)
phosphate LD50:2830 mg/ltg
Trls(tetrahydrofurfuryl)
phosphate
(Continued)
-------
Plasticizer
PHOSPHATES (Continued)
Trixylenyl phosphate (tri(di-
methyl phenyl) phosphite)
Unspecified phosphate
PHOSPHONATES
Chlorinated organic phosphonate
Chlorinated polyphosphonate
(27% CI, 15% P)
Di-(2-ethylhexyl n-octyl)
phosphonste
Halogenated organic polyphos-
phosphonate
00
c..J
t-'
PHOSPHlTES
Triphenyl phosphite
Tris(2-c:hloroethyl) phosphite
LINEAR PLASTICIZERS
GLUTARATES
Dialkyl diet her glutarate
Dibutoxyethyl glutsrate
Dibutoxyethoxyethyl glutarate
Dicumylphenyl glutsrate
Didecyl glutarate
Diisodecyl glutarate
Hixed dialkyl glutarate
TABLE C-13 (Continued)
Toxlc:1ty
Oral, rat
LD50:1.6-3.2 gm/kg
Intraperitoneal, mouse
LDLo:250 mg/kg
Concern
Strong Irrltant
Reactive
OSHA Regulation
(CAS No. J
(25155-23-1) .
(4351-70-6)
(101-02-0 J
( 140-08-9 J
(Continued)
-------
,
.j
TABLE C-13 (Continued)
Plasticizer Toxicity Concern OSHA Regulation (CAS No.)
ADIPATBS
Benzyl octyl adlpate
Butyl carbltol adlpate
Dlalkoxyethyl adlpate
Dlhenzyl adlpate
Dlbutozyethyl adlpate Low (141-18-4)
Intraperitoneal, rat
LDSO:600 "8/1<8
Dlbutoxyethoxyethyl adlpate Oral, rat (141-17-3)
L~SO:6000 "8/1<8
Dlbutyl adlpate Oral, rat Primary Irritant [10S-99-7)
LDSO:12900 "8/k8
00
I.J.) Dlcapryl adlpate Low
tV
..I Dldecyl adlpate Low [10S-97-S1
Oral, rat
LDSO: Zl 8111/1<8
Dl-(l,3-dl-methylbutyl) adlpate
i Dlethyl adlpate Low Huta8en [141-28-61
Oral, rat
LDSO: > 1. 6 8111/1<8
.', Dl-(2-ethylhexyl) adipate Low Hoderate Eye Irritant (103-23-11
i Oral, rat Positive Anll1Sl
LDSO: 9110 "8/1<8 Carclno8en
Huta8en
Dl-n-hexyl adlpate Low [110-]]-81
Oral, rat
LDSO:S.6 8.,/1<8
Dilsobutyl adlpate Intraperitoneal, rat [141-04-81
LDSO:S9S0 "8/1<8
(Continued)
-------
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Plasticizer
ADIPATES (Cont inued)
Diisodecyl adipate
O1isononyl adipate
Diisooctyl adipate
Diisopropyl adipate
Dimethyl adipate
Dinonyl adipate
Dipropyl adipate
O1tridecyl adipate
,1
co
w
w
Di-(2,2,4-Trimethyl-l,3-penta-
nediol monoiaobutyrate) adipate
Heptyl nanyl adipate
n-Hexyl n-decyl adipate
Isooctyl isodecyl adipate
n-OCtyl n-decyl adipate
Tridecyl adipate
MIXED ADIPATES
C1-C9 linear adipates
Straight chain alcohol adipates
Straight chain alcohol adipates
TABLE C-13 (Continued)
Toxicity
Concern
Low
Low
Intravenous. rat
LD50:640 mg/kg
Low
Intraperitoneal, rat
LD50:31g6 mg/kg
OSHA Regulation
[CAS No.)
[21118-16-1)
[33103-08-1)
( 1330-86-5)
(6938-94-9)
(621-93-0 )
[151-32-6)
[106-19-4)
[16958-92-2)
[68515-15-3)
[22101-35-3)
[68130-92-1)
131414-51-4)
[110-29-21
'..,.
",
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(Continued)
-------
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POLYMERIC ADIPATES
Di-(2-ethylhexyl) adipate
(polfllleric)
High molecular weight adipate
Modified polypropylene adipate
Polypropylene adipate
CITRATES
Acetyl tri-n-butyl citrate
Acetyl triethyl citrate
Acetyl tri-(2-ethylhexyl)
cUrate
Acetyl tri-n-hexyl citrate
Acetyl tri-(n-octyl, n-decyl)
citrate
Tribenzyl citrate
Tributyl citrate
Triethyl citrate
Tria(-2-ethylhexyl) citrate
. AZELATES
Dibenzyl azelate
Dibutoxyethyl azelate
Diethyl azelate
TABLE C-13 (Continued)
Toxicity
Low
Nontoxic
Impregnation, mouse
LDSO: 1150 mg/ltg
Low
Low
Low
Oral, rat
LD50: 7 gll/itg
Concern
Inhalation
Ingestion
OSHA Regulation
(CAS No.)
(77-90-7)
(77-89-4)
(77-94-1)
(77-93-01
( 1932-84-9)
(624-17-9)
...
1~ r
I
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.'1
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(Continued)
-------
TABLE C-13 (Continued)
Plasticizer Toxicity Concern OSHA Regulation [CAS No.)
AZELATES (Continued)
Di-(2-ethylbutyl) azelate
Di-(2-ethylhexyl) azelate Very Low Primary Irritant [103-24-2)
Intravenous, rat
LDSO:I060 ..g/kg
Di-n-hexyl azelate Oral, rat [109-31-91
LDSO:16 gm/kg
Dl1sobutyl azelate
Dl1sooctyl azelate Low [26S44-17-2)
Dimethyl azelate
Low temperature azelate
plasticizer
00
UJ SEBACATES
lJ1
Butyl acetoxy sebacate
Butyl benzyl sebacate
Dlbenzyl sebacate [140-24-9 J
Dibutoxyethyl sebacate
Dibutoxyethoxyethyl aebacate
Dibutyl aebacate Low Teratogen -1109-43-3 I
Oral, rat
LDSO:16-32 sm/kg
Di(-l,3-dimethylbutyl) sebacate
Dihexyl aebacate
D1isooctyl sebacate Low [27214-90-01
Diisopropyl sebacate (7491-02-31
(Continued)
-------
/
Plastic:izer
SEBACATES (Continued)
Dimethyl sebac:ate
. Dinonyl sebac:ate
Dioc:tyl sebac:ate (di-(2-
ethylhexyl) sebac:ate)
Heptyl nanyl sebac:ate
ISOSEBACATES
Di-n-butyl isosebac:ate
Di-(2-ethylhexyl) isosebac:ate
00
U)
0\
SUCCINATES
Diethyl suc:c:inate
Tetrabutyl thiosuc:c:inate
FORHAL
Butyl c:arbitol formal
Dibutoxyethoxyethyl formal
PELARGONATES
Isodec:yl pelargonste
TABTBATES
Dibutyl tartrate
Diisobutyl tartrate
TABLE C-13 (Continued)
Toxic:lty
Low
Oral, rat
LDSO: 1280 IDg/kg
Intrsperitoneal, mouse
LDSO,200 IDg/kg
Low
Oral, rat
LDSO:8S30 IDg/kg
~
PriIDary Irritant
OSHA Regulation
(CAS No.)
( 4121-16-81
(122-62-3 )
(2432-87-3 )
(29590-28-1 )
(123-25-11
. (87-92-3)
'.
(Continued)
-------
Plasticizer
FUllARATI!S
Dibutyl fumarate
Diisooctyl fumarate
Dioctyl fumarate
ISOBIITYRATBS
2,2,4-Trimethyl-l,3-pentandiol
dUsobutyrate
Sucrose acetate isobutyrate
00
V-1
.....
HALBA TBS
Di-n-butyl maleate
Di-2-ethylhexyl maleate
Di-n-octyl maleate
HonDbutyl maleate
PI!NTAI!RYTIIRITOL
Pentaerythritol fatty acid
ester
pentaerythritol tetracaprylate-
caprate
TABLE C-13 (Continued)
Toxicity
Concern
Nontoxic
Oral, rat
LD50:8530 mg/ltg
Pr imary Irritant
Low
Oral, rat
LD50:29.2 gm/ltg
Primary Irritant
Nontoxic
Low
Oral, rat
LD50: 3730 mg/ltg
Primary Irritant
Oral, rat
LD50:14 gm/ltg
Primary Irrltant
Low
Oral, rat
LD50:14.2 gm/ltg
OSHA Regulation
(CAS No.1
(105-75-91
(1330-76-31
(1330-75-21
(2997-85-51
1141-02-61
(126-13-61
( 105-76-<>1
(2915-53-91
(2915-53-91
,
. ..
(Continued)
-------
;
TABLE C-13 (Continued)
Plasticizer Toxicity Concern OSHA Regulation ICAS No.)
OTHER LINEAR EST8RS
Hixed dibasic ester
Sucrose octoacetate Lo..
EXTENDERS
PETROLEUM DERIVATIVES
Alkyl aryl hydrocarbons
Aromatic hydrocarbons (70%
aromatic hydrocarbona, 23%
polar compounds)
Biphenyl Inhalation, humana Hutagen o. 2 ppm 'lWA 198-52-4)
'l'CLo:4.4 mg/m3 '1\Jmorigen
Todc Effect: Peripheral
00 Nervous System, Gastroin-
l;.) testional Tract
00
Butyl naphthalene
DUsopropyl biphenyl
Naphthalene Oral, rat Primary Irritant 10 ppm TWA 191-20-3)
LD50:1780 mg/kg Ingestion
Inha la tion
Skin Absorption
Tumorigen
Naphthenic on
Polyalkyl naphthalene
Terphenyla, partially
hydrogenated
o,m,p-Terpbenyl mixture Oral, rat 1 ppm Ceiling 184-15-1)
LD50:2.4 gm/kg 192-06-8)
Poly-alpha-.ethyl styrene
i .'
(Continued)
-------
TABLE C-13 (Continued)
Plasticizer Toxicity Concern OSHA Regulation ICAS No.)
CHLORINATED AROMATICS
Chlorobenzene Oral. rat 75 ppm 'NA 125321-22-6)
LD50:2910 mg/kg (108-90-7)
o-Dichlorobenzene Inhalation, rst Inhalation 50 ppm Ceiling 195-50-1)
LCLo,821 ppm/7 Hr. Indefinite Human
Toxic Effect' Behavorial Carcinogen
Sym,Ptoms. Liver. Eye
Chlorinated biphenyl
21% Cl
32% Cl
42% Cl
48% Cl
54% Cl
60% Cl
68% Cl
00
W Chlorinated Naphthalene
~
22% Cl
50% Cl
56% Cl
70% Cl
Chlorinated Terphenyl
60% Cl
Chlorinated Paraffin Low 163449-39-8)
40% Cl
42% Cl
52% Cl
70% Cl
'j
I .
1'1
(Continued)
-------
PlaaUcizer
PARAFFIN OILS
White paraffin oil, highly
refined
PetrolatUII
OTHER CYCLIC PLASTICIZER
ABIETIC DERIVATIVES
Hydroabietyl alcohol
00
.I:"-
o
Hydrogenated methyl abietate
Methyl abietate (methyl ester
of rosin)
BENZOIC ACID DERIVATIVES
Benzyl benzoate
Cumyl phenyl dibenzoate
Diethylene glycol dibenzoate
\:
)
Dipropylene glycol dibenzoate
DIethylene and D1propylene
glycol dibenzoete blend
Ethylene glycol dibenzoate
Glyceryl tribenzoate
TABLE C-13 (Continued)
Toxicity
Nontoxic
Intraperitoneal, mouee
52 gm/kg/17 Wk.
ToxIc Effect: NeoplastIc
Effect
IntraperItoneal, mouse
T~: 14 gm/kg
Toxic Effect: EquIvocal
tumorIgenic Agent; Blood;
Pulmonary System
Low
Oral, rat
" LD50: 1700 mg/kg
Nontoxic
Oral, rat
LD50:2BJO mg/kg
Oral, rat
LD50:11.7 gm/kg
Concern
Tumorigen
IngesUon
Skin and Eye IrrItant
OSHA RegulaUon
5 mg/mJ 'lWA
10 .g/.J STEL
(reco_ended)
[CAS No.)
[8012-95-1 )
(8009-03-8)
( 805O-13-JI
(120-51-4)
(120-55-8)
(94-49-5)
(271J8-31-4 )
(94-49-5 )
[614-33-51
" "
I"
1,.1
(Continued)
-------
Plaaticizer
BENZOIC ACID DERIVATIVES
(Continued)
Neopentyl glycol dibenzoate
Pentaerythritol tetrabenzoate
Octylene Glycol Dibenzoate
Polyethylene glycol (200)
dibenzoate
Polyethylene glycol (300)
dibenzoate
-t
Polyethylene glycol (400)
dibenzoate
ex>
+,
......
Polyethylene glycol (600)
dibenzoate
"
Sucrose benzoate
Triethylene glycol dibenzoate
Trimethylolethane Tribenzoate
2,2,4-Trimethyl-I,3-pentanediol
isobutyrate benzoate
Proprietary low stain benzoic
acid ded vati ve
POLYPHENYL
Hydrogensted terphenyl
LACTAH
2-Pyrrol1done
TABLE C-13 (Continued)
Toxicity
Concern
Oral, rat
LD50:5340 mg/ltg
Low
Oral, rat
LD50:2830 mg/ltg
Oral, rat
LD50: 6500 mg/ltg
OSHA Regulation
(CAS No.1
(9004-86-8 I
(9004 -86-8 I
(9004-86-81
(9004-86-3 I
( 120-56-91
None
(35164-39-1 )
(61188-32-1 I
(616-45-51
(Continued)
-------
TABLE C-13 (Continued)
Plasticizer Toxicity Concern OSHA Regulation (CAS No.)
ACETATES
-
, Cumyl phenyl acetate
.J PHENOXYS
-
Acetyl paracumyl pheno I
KETONES
Benzophenone Oral, rst (119-61-9)
LDSO:289S ..g/kg
GL YCOLATES
Butyl phthalyl butyl glycolate Oral, rst Hutagen (8S-70-1)
LD SO: IS am/kg
CO Dibutyl methylene bisthiog1yco-
.J.' late
N
Dicapry1 diglycolste
Dioctyl thiodiglycolate
Ethyl phthalyl ethyl glycolate Oral, rat (84-72-0)
LDSO:10Z in diet
Methyl phthalyl ether glycolate Oral, rst Primary Irritant (8S-71-2)
LDSO:9.04 gm/kg
GLYCEROL DERIVATIVES
Glycerol Nontoxic Primary Irritant 10 ..g/..3 TWA (S6-81-S)
Or 81, mouse (reco....ended)
LDSO:26 gm/kg
Glycerol carbonate (640S7-77-8)
Glycerol diacetate Nontoxic (106-61-6)
Oral, mouse
LDSO: 8. S gm/kg
(Continued)
-------
J
i
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.1
.'1
i
.
Plasticizer
GLYCEROL DERIVATIVES
(Continued)
Glycerol monacetate.
Glycerol trlacetate
Glycerol trlbutyrate
Glycerol trlrlclnoleate
GLYCOL DERIVATIVES
GLYCOLS AND GLYCOL ESTERS
1,3-Butanedl01
ex>
~
~
2,3-Butanedl01 1,4-Butanedl01
dlcsprylate
1,4-Butanedl01 dlpelargonste
Butyl c:arbltol acetate
Dlethylene glycol dlpelargonate
Dlethylene glycol monobutyl
ether acetate
[Butyl Csrbltol Acetate)
2,2-Dlethyl-l,3-propanedlo1
Ethylene glycol dlacetate
Ethylene glycol dlpelargonste
TABLE C-13 (Continued)
1"
Todc:1ty Concern OSHA Regulation [CAS No.)
.
. Subcutaneous, rat "'tagen [25395-31-1)
LD50:5.5 p/kg [26446-35-5)
Subcutaneous, rat Prlmary Irritant [102-16-11
LD50:2.8 gm/kS
Oral, rat 1\Jmorlgen [60-01-51
LD50:13 p/kg
Low
Oral, rat
LD50:23 p/kg
Prlmary Irrltant
1101-88-0)
[106-01-4)
Hoderate
Intraperitoneal, mouse
LD50:1010 mg/kg
Ingest 10n
Hl1d Eye Irritsnt
[111-55-1 )
(Continned)
-------
. ...
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)
Plasticizer
GLYCOLS AND GLYCOL ESTERS
(Continued)
2-Kthyl-I,3-hexsnediol
1,5-Hexsnediol
Polyethylene glycol 200
Polyethylene glycol 300
Polyethylene glycol 400
Polyethylene glycol 600
00
-l:-
-l:-
Polyethylene glycol 900
Polyethylene glycol 1000
Polyethylene glycol 1500
Polyethylene glycol 1450
Polyethylene glycol 1500 snd
50«8
Polyethylene glycol 1530
Polyethylene glycol 3350
Polyethylene glycol 4000
Polyethylene glycol 4500
Polyethylene glycol 6000
TABLE C-13 (Continued)
Toxicity
Concern
Oral, rat
LD50: 400 109/kg
Eye and Mucous
Hembrane Irritant
Oral, rat
LD50:28900 109/kg
Oral, rat,
LD50:27500 109/kg
Oral, rat
LD50:33750 109/kg
Primary Irritant
Oral t mouse
LD50:47 am/kg
Oral, rat
LD50:42 goo/kg
Oral, rat
LD50:44200 109/kg
Primary Irritant
Oral, rat
LD50: 59 goo/kg
Primary Irritant
Oral, rat
LD50:33750 109/kg
OSHA Regulation
(CAS No.)
(94-96-2)
(25322-68-3 )
(25322-68-3)
(25322-68-3 J
(25322-68-3)
(25322-68-3 )
(25322-68-31
(25322-68-3 J
(25322-68-3)
(Continued)
"
1'1
"
i-:
f'
.'
-------
..
TABLE C-13 (Continued)
Plasticizer
Toxicity
Concern
GLYCOLS AND GLYCOL ESTERS
(Continued)
Polyethylene glycol 8000
Polyethylene glycol 2CH
Polyethylene glycol (200)
di-(2-ethylhexoate)
(Polyethylene glycol dloctoate)
Polyethylene glycol (600)
monolaurate
Tetraethylene glycol di-(2-
ethylenehexanoate)
Oral. rat
LDSO: 18 gm/kg
Tetraethylene glycol
dlheptanoate
ex>
.po
VI
Trlethylene glycol dlacetate
Trlethylene glycol dicaprylate
Trlethylene glycol dlcaprylate-
caprate
Trlethylene glycol dl-(2-ethyl- Oral, rat
butyrate) LDSO:6000 mg/kg
Trlethylene glycol dl-(2-
ethylhexoate)
Triethylene glycol dlheptanoate
Trlethylene glycol
dlperlargonate
Trlethylene glycol ester of
fatty acid
Trlglycol eater of vegetable
oil fatty acid
OSHA Regulation
(CAS No.)
(18268-70-7 )
(18268-70-7 )
(9S-08-9)
(Continued)
. .
-------
i
. ,
i
i
Plasticizer
GLYCOLS AND GLYCOL ESTERS
(Conti nued)
Trimethylol ethsne tricsrpry-
late-caprate
Trimethylol propane
triheptanoste
DERIVATIVES OF FATTY ACIDS
LAURATBS
Butoxyethyl laurste
Diethylene glycol monolaurste
Glycerol monolaurate
00
-'"
0\
Polyethylene glycol (400)
dilsurate
1,2 Propylene glycol
monolaurate
IIYRISTATBS
n-Butyl myristate
Isopropyl myristate
Isopropyl myristate-palmitate
~. . 1
Toxicity
Nontoxic
Nontoxic
Nontoxic
Nootoxic
Skin, humans
85 mg/3 days
Toxic Effect:
Irritant
Nontoxlc
TABLE C-13 (Continued)
Concern
Primary Irritant
Mild
OSHA Regulation
[CAS No.)
[110-27-0)
f.
.'
"
(Continued)
-------
Plaaticizer
, OLEATES
Butoxyethyl oleate
Butyl oleate
Diethylene glycol monooleate
Ethylene glycol monobutyl ether
oleate
Glycerol monooleate
Glycerol trioleate (Olein)
ex>
.&:-
"
Isopropyl oleate
Lead oleate
Hethoxyethyl oleate
Hethyl oleate
n-Propyl oleate
Tetrahydrofurfuryl oleate
PALHITATES
Isooc:tyl palmitate
I
i
~
i
"
TABLE C-13 (Continued)
Toxicity
Low
Skin, rabbits
500 f1Jg/24 Ura.
Todc Kffect:
Irritant
Hoderate
Nontoxic
Probably Low
Nontoxic
Toxic
Oral, guinea pig
LOto:4 KID/kg
Oral, rat
LDLo:16 gm/kg
Low
Sk 1 n. ..ouse
TOto: 54 gm/kg/45 Wk.
Toxic Effect: Blood,
Skin, Tumor
Low
Concern
Skin Absorption
TUlDorlgen
OSHA Regulation
50 ug(pb)/m3 TWA
(CAS No.)
(142-7]-8)
(25496-72-4 )
(1120-46-3)
(111-10~4)
(112-62-9)
Il~4l-38-4 )
/, I,
,11
l'
I
, .
I
I
'V
I' p,.
,', \
I , ,'I',' 'I
'.,.{ 1
I' y ~ I
\ I I \ ,I
I ,V' jI i
! . ~ I
~-, I'
ti "..
I
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.
'.
(Continued)
-------
Plasticizer
PALHITATES (Continued)
Isopropyl palmitate
Hyricyl palmitate (Beeswax)
RICINOLEATBS
n-Butyl acetyl ricinoleate
Butyl ricinoleate
Diethylene glycol monoricino-
leate
00
~
00
Glycerol ricinoleate
(Caster OU)
Glycerol triacetyl ricinoleate
Methyl ,acetyl ricinoleate
Hethoxyethyl acetyl ricinoleate
Hethyl ricinoleate
Propylene glycol aonoricino-
leate
STEARATBS
Butyl acetoxystearate
Butoxyethyl stearate
Butyl epoxystearate
TABLE C-13 (Continued)
Toxicity
Nontoxic
Skin, humans
84 mg/3 dsy
Toxic Bffect:
Irritant
Low
Nontoxic
Low
Low
Bye, rabbit
500 mg
Toxic Bffect:
Oral, rat
LD50:20 am/kg
Low
Low
HUd
Irritant
Concern
Primary Irritant
Primary Irritant
Primary Irri.tant
OSHA Regulation
(CAS No.)
(142-91-6 )
( 140-04 -5 )
(140-03-4 )
(140-05-6 )
(7705-99-9 )
II; t'
\'
I
, ,
, 'I
I
1
, ,","
I' r"
I ", ~
I ,\,:"
, :~' J{\
t. ~'
t I , ,',I
I ,f iJ:i,
I '
t., ..l
. .
t,i. iI
'.
(Continued)
-------
TABLE C-13 (Continued)
. Plasticizer Todcity Concern OSHA Regulation (CAS No.)
j
! STEARATES (Continued)
j Butyl stearate Low (123-95-5)
! Oral, rat
, LD50:>32 p/kg
~ Diethylene glycol dlstearate Nontodc
,
I Ethyl stearate Low Primary Irritant (111-61-5)
!
i Skin. rabbit
500 mg/24 Hr.
I Toxic Effect: Moderate
I Irritant
Glycerol IDOnostearate Nontoxic
Glycerol triacetoxystearate Low
Glycerol tri(epoxy acetoxy
00 stearate)
~
\0 Hexadecyl stearate
(Cetyl Stearate)
Isobutyl stearate [646-13-9)
Isooctyl epoxy stearate
Methoxyethylacetoxy stearate
I Methoxyethyl stearate
~. i Methyl hydroxystearate wax
I
'j Methyl pentachlorostearate
..; (stabilized)
" Methyl stearate Low Tumor1gen (112-61-8) i
!
, Subcutaneous, mouse
.' TOW: 5200 mg/kg/65 Wk.
.
Todc Effect: Neoplastic
Effects I"
(Continued)
!
.;
,
-------
,;
-'
, ,-
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1
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/
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Plasticber
STEABATES (Continued)
Octyl stearate
l,2-Propylene glycol
mooostearate
Vinyl stearate
TALL OILS
Isooctyl esters of tall oil
Hethyl esters of tall oil
FATTY NlTlliLES
Fatty acid nitrile
00
VI
o
Oleyl nitrile
Tallow nitrile
OTREIl MISCELLANEOUS
PLASTICIZEIlS
CARBONATES
Bis-dimethyl benzyl carbonate
Dinonyl phenyl carbonate
ETHEIlS
Bia(dimethylbenzyl) ether
Cumyl phenyl benzyl ether
Nonylphenol ethylene ozide
TABLE C-13 (Continued)
Todcity
Concern
IIontozic
Impregnation, mouse
LD50:200 mg/kg
Low
Oral, rat
LD50: 1310 mg/kg
Primary Irritant
OSHA llegulation
jCAS No.)
(1323-39-3 )
(901 ('-4 5-9 )
: .
.' .
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1"
(Continued)
-------
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ETHERS (Continued)
Tridecanol ethylene oxide
adduct
S ULFONAHI DES
n-Cyclohexyl-p-toluene
sulfonamide
,j.
.,
j
)
"
I
J
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.1
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"
.
(
!
n-Ethyl-o,p-toluene sulfonamide
n-Ethyl-p-toluene sulfonamide
Sulfonamide-formaldehyde resin
00
V1
I-'
o,p-Toluene sulfonamide
AHlDES
Benzamide
Dibutyl lauramide
2,2'-(2-Ethylhexamidodlethyl)
di-2-ethylhexoate
Urea
!.
NITRO COMPOUNDS
Ni trobenzene
. ,
o-Nitrobiphenyl
)
TABLE C-13 (Continued)
Tox1c:1ty
Skin, rabbit
2 gm/4 Wk.
Todc Effect'
Irritant
MUd
Oral, rat
LDSO:4870 mg/kg
Intravenous, rabbit
LOto: 4800 IDg/kg
Percutaneous, rat
LD50:2100 mg/kg
Oral, rat
LD50'lS80 mg/kg
Concern
Primary Irritant
Eye Irritant
Suspected Animal
Carcinogen (Ortho)
Tlssue Irritant
Ingestion
Inha lat ion
Skin Contact
Primary Irritant
Mutagen
OSHA Regulation
I ppm TWA (skin)
~
[CAS No.)
[24938-91-8)
I'i:
" .
. iIt077~6-1)
I [80-3 I 7)
I : j
'J"
I ~'2,~, ?t-71-6)
\ [Sd":J"-7)
\' [101'51-3)
I I , ~Ii
.I.h~'i
'" l
. \
.,..>/
[57-13-6)
[98-95-3)
[ 86-00-0 )
(Continued)
-------
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: 1
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Plaaticizer
NITRO COHPOUNDS (Continued)
2-Nitrodiphenyl ether
o-Nitrotoluene
SULFOHATES
Phenol, cresol esters of
pentadec:ylsulfonic scid
Cresyl-p-toluene sulfonste
OTHERS
Camphor
(XI
VI
N
alpha-Hethyl-D glucoside
Sorbitol
, ,
. j
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.;
!
,1
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TABLE C-13 (Continued)
Toxicity
Oral, rat
LD50:891 IIg/kg
Subcutaneous. mouse
LDr..,: 2200 IIg/kg
Low
Oral, rst
LD50:15.9 am/kg
Concern
Ingestion
Inhalation
Skin Absorption
Irritant
Hutagen
OSHA Regulation
5 ppm TLV (skin)
(reco.....nded)
2 IIg/1I3 TWA
(CAS No.)
188-72-2 )
,i I.
II
~'
I
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I' i". (
I ",
,. ,t ~I. ..'
, ~'1!
Ii . ~ '
\ I " ,I
I (t6~2,-2)
1
1~ i'
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ti '.d
( 50-70-4 )
-------
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!
TABLE C-14. PRESERVATIVES
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Preservative
Bsrium metsborate [Bussn Il-H-l1
Butyl p-hydroxybenzoste [Butyl parsbenl
Copper-8-quinolinate
l,2-Dibromo-2,4-dicyanobutane [Tektamer
381
,
,
,
"1
3,5-Dimethyltetrahydro-l,3,5-thiadia-
zine-2-thione [My lone) , [Dazomet)
Diphenyl antimony 2-ethylhexanoate
00
VI
VJ
2-Hydroxy-5-chlorobenzoic-3,4'-dichloro-
anilide
8-Hydroxyquinoline
Intercide N-63B [trialkyl orgsnotin)
2-Methyl-l-naphthyl male imide
Methyl p-hydroxybenzoate [Methyl paraben)
2-N-octyl-4-isothiazolin-3-one [Micro-
Chek 11), (Micro-Chek IlDI
10,10-0xybisphenoarsine (Vinyzene BP-5I,
[Vinyzene BP-5-2I, [Vinyzene SB-l1
Toxicity
Low to Moderate
Intraperitoneal, mouse
LD50:230 mg/kg
May be Toxic
Low human toxicity
Intraperitoneal, mouse
LD50:67 IIg/kg
Oral, rat
LD50:500 mg/kg
Moderately Toxic
Oral, rat
LD50: 1200 mg/kg
Low
Oral, mouse
L~o:3000 mg/kg
Lo"
Toxic
Oral. bird
LD50:24 mg/kg
Concern OSHA Regulation [CAS No.1
[13701-59-2)
Primary Irritant [94-26-8)
, '
Indefinate An imal [10380-28-6) i
Carcinogen
,'I
Skin Contact [533-74-4)
Inhalation
0.5 mg(Sb)/1I3 TWA
(recommended)
Indefinite Animal
Carcinogen
Mutagen
[148-24-3 J
100 ug(Sn)/m3 TWA
(recommended)
Skin and Eye Irritant
Mutagen
[99-76-3)
Skin and Eye Irritant
200 ug(As)/m3 TWA
(recommended)
[58-36-6)
(Continued)
-------
,I
/
Preservative
Phenyl mercuric salicylate
(C6H4(OH)(CooHgC6H5»)
Propyl p-bydroxybenzoate (Propyl para-
ben), (Clol'l:z03)
PPC (III-50), (organometallic I
Quaternsry ammonium naphthenate
3,5,3',4'-Tetrachlorosalicylanilide
2,2'-Thiobis(4,6-dichlorophenol)
Tributyltin fluoride
00
VI
-P'
Tributyltin oxide
(C4"9)3SnOSn(C4"9)3)
Tributyltin salicylate (Cotin P)
Trichloromethylmercapto-4-cyclohexene-
l,2-dicarboxillide (Captan), (Vancide 89),
(CgHsC13N02S), (N-trichlo-
romethylmercaptotetrahydrophthalimide)
n-(Trichloromethylthio)phthalimide
(Folpet I, (Phaltsn),
(C6"4(CO)2NSCC13)
N-(Trichloromethylthio)tetraphthalimide
Zinc borate (3ZnO'28203)
TABLE C-14 (Continued)
Toxicity
Highly Toxic
Low
Oral, mouse
LDLo:6000 mg/kg
Oral, rat
LD50:243 mg/kg
Moderately Toxic
Oral, rabbit
LD50:50 mg/kg
Toxic
Oral, rat
LD50:87 mg/kg
Oral, rat
LD50:137 mg/kg
Toxic
Oral, humans
LDLo: 1071 mg/kg
Hay be Toxic
Oral, rat
TDw:500 mg/kg/5D
Toxic Effect: Mutsgen
Low
Concern
Ingestion
Inhalation
Skin Absorption
Eye and Skin Irritant
Primary' .Irritant
Ingestion
Skin and Eye Irritant
Inhalation
Ingestion
Skin and Eye Irritant
Positive Carcinogen
Ingestion
Skin Irritant
Inha lation
Skin COntact
Possible Teratogen
Equivocal Tumorigen
Mutagen
Possible Teratogen
Mutagen
Ingestion
OStIA Regulation
50 UK - (lIg)/m3 'NA
(recommended) .
100 ug(So)/m3 'NA
100 ug(So)/m3 'NA
100 ug(So)/m3 'NA
5 mg/m3 TWA
1'5 mg/m3 STEL
(recommended)
(CAS No.)
, .
i .
( 94-13-31
I'I,
( 1154-59-21
(1983-10-4)
(56-35-9)
(4342-30-7)
(133-06-2 )
(133-07-3)
[1332-07-6 )
-------
;
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~
.
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Chemical
ACIDS, BASES, AND BUFFERS
ACIDS
Formic Acid (lICOOH)
Hydrochloric acid (HCl)
,i
Lactic acid (CH3CHOHCOOHI
Maleic acid (HOOCC8:CHCOOHI
Nitric acid (HN03)
00
l/1
l/1
2-Naphthalenesulfonic acid
(ClOH7S03HI
Phosphoric acid (H3P041
Sulfuric acid (82S041
BASES
Ammonia
TABLE C-15. SOLUTION MODIFIERS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Toxicity
Toxic
Oral, rst
LDSO:1100 mg/kg
Inhalation, humans
LCLo: 1000 pp",/lM
Oral, rst
LDSO:3730 "'g/kg
Moderate
Oral, rat
LD SO: 708 ",g/kg
Highly Toxic
Orsl, human
LDLo:430 ",g/kg
Hay be Toxic
Oral, rat
LDSO:400 "'g/kg
Toxic
Inhalation, humans
TeLo: 100 ",g/",3
Toxic Effect: Irritsnt
Highly Toxic
Inha1stion, humans
LOto:3 "'g/",3/24W
Toxic Effect: Mouth
Toxic
Oral, rat
LDSO:3S0 "'g/kg
Concern
Primary Irritsnt
Corrosive to Tissues
Mutsgen
Pri",sry Irritsnt
Inhale tion
Corrosive
St rong Oxidizer
Ingestion
Inhalation
Primary Irritant
Primary Irritant
Inhals tion
Irritsnt
Moderate Fire Risk
Mutagen
OSHA Regulation
s PP'" TWA
s PP'" Ceiling
2 pplI TWA
1 ",g/m3 TWA
1 IIg/",3 TWA
So ppm
I. "
I ", (
\ ,I'"
. ~. if i
II/I'P
I .~' ~ Ii
I
,<. l
. ,
,,/I
(CAS No.1
(64-18-6 )
(7647-01-01
(S98-82-3)
(110-16-71
(7697-37-2 )
(120-18-31
(7664-38-21
[7664-93-9 )
(7664-41-71
(Continued)
""-:f'
'"
"I\',. .
'h
-------
. .~.
. ..;
.~. (
I
,
!
,I
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;
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Chemical
BASES (COntinued)
Ammonium hydroxide INH40HI ISee
Ammonia I
..
Methanolic aodium methoxide ISodium
methoxide in methyl alcohol I
" ICHj>Na CH30H)
Potassium hydroxide IKOH)
Sodium hydroxide I NaOH I
, ,
00
V1
0\
BUFFERS
Ammonium acetate
«NH4)CZH30z1
Borax INaZB407 I
Calcium carbonate ICaC031
Potassium bicarbonate I KHC03 I
Sodium acetate INaCzHj>zJ
, ,
',I
TABLE C-15 (Continued)
Toxicity
Todc
Todc
SUn, humans
50 mg/Z4H
Toxic Effect:
Severe Irritation
Todc
Eye, rabbit
1 IIg/Z4H
Toxic Effect:
Severe Irritation
Intravenous, mouse
LDSO:90 IIg/kg
Low
Oral, humans
LDLo: 709 IIg/ltg
Nontoxic
Low
Oral, rat
LDSO:3S30 IIg/kg
Concern
Fire Risk
COrrosive
Ingeation
Inhalation
Primary Irritant
Mutagen
Corrosive
Primary Irritant
Primary Irritant
OSHA Regulation
Z IIg/1l3 TWA
(recommended)
Z mg/m3 TWA
5 IIg/1l3 TWA
(recolDIDended)
10 IIg/1l3 TWA
(recolDIDended)
, '\' 'i
; '~'ll
, ,- ~ I
L ; t',!
I' t.,! i
, ...,
'!'/
ti, .~'
ICAS No.)
11Z4-41-4 )
11310-58-31
11310-73-Z1
1631-61-8)
11303-96-4 I
1471-34-1) precipi-
tated; 11317-65-3)
lillea tone;
I 13397-Z6-7 )
vhi ting
1127-09-3 I
'.....
'>,
(Continued)
"~'t
"h
~ '"
,'~
-------
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Chemical
-
BUFFERS (Continued)
Sodium bicarbonate (NaHC03)
Sodium carbonate
[Na2C03°H20)
SodiUla formate [!\CooNa)
Sodium hydrogen phosphate (sodium
phosphate, dibasic) [NaH2P04)
CHAIN TRANSFER ACENTS
00
VI
......
Acetaldehyde [CH)CHO)
Acetic acid [CH3CooH)
Acetic anhydride [CH3(CO)20)
Acetone (CH)COCH3)
Acetylene (HCCH)
TABLE C-15 (Continued)
Toxicity Concern OSHA Regulation [CAS Nno)
Low Primary Irritant (144-55-8)
Oral, rat
LD50:4220 mg/kg
Low Primary Irritant [497-19-8)
Oral, rat
LD50:4000 mg/kg
Oral, mouse (141-53-7)
LD50:11,2oo mg/kg
Low (7558-80-7)
Intramuscular, rat
LD50' 250 mg/kg
Highly Toxic Primary Irritant 200 ppm 'l'WA (75-07-0)
Inhslation, humans Inhalation
TCLo:134 ppm/30H Dangerous Fire Risk
Toxic Effect' Irritation, Hutagen
Pulmonary System Teratogen
Toxic Ingestion 10 ppm 'l'WA [64-19-7)
Inhalation, humans Inhalation
TCLo:816 ppm/3H Primary Irritant
Toxic Effect: Irritant Hutagen
Oral, rat Primary Irritant 5 ppm 'l'WA [108-24-7)
LD50:1780 mg/kg
Inhalation, humans Primary Irritant 1000 ppm 'l'WA [67-64-1)
TCLo: 500 ppm Inhalation
Todc Effect: Eye I rr ita t ion Dangerous Fire Risk
Hutagen
Inhalation, mammals Dangerous Fire Risk 2500 ppm Ceiling (74 -86-2)
LCLo: 500, 000 ppm/SH
(Continued)
I.. '
I. .
-------
TABLE C-15 (Continued)
Chellical Toxicity Concern OSHA Regulation (CAS No.1
CHAIN TRANSFER AGENTS (Continued)
Benzene (C6"61 Toxic Dangerous Fire Risk 10 ppm TWA ( 71-43-2 I
Inhalation, humans Inges t ion
TeLo: 100 pplI/IOY-1 Inhalstion
Toxic Effect: Carcinogen Skin Absorption
Mutagen
Teratogen f
Carcinogen
Primary Irritant
Bromoform (CHBr31 Toxic Ingestion 0.5 ppm (skin) [75-25-21
Intraperitoneal, mouse Inhala tion
TDw:l1oo IIg/kg/8W-1 Skin Abaorption
Toxic Effect: Neoplastic Mutagen
n-Butane [C4H101 Inhalation, rat Dangerous Fire Risk 800 ppm TLV [106-97-81
LC50:658 gm/m3/4H (recommended)
CD 1-Butanethiol (C4H~HI Toxic Inhalation 10 ppm TWA [109-79-5)
'-" Inhalation, rat Dangeroua Fire Risk
CD LC50:4020 ppm/4H Primary Irritant
Butyl chloride [(CH3)3CCI) Imp lan t, mouae Flammable [507-20-0)
TDLo' 3000 mg/kg/8W-1 Mutagen
Toxic Effect: Neoplaatic
t-Butyl mercaptan (2-methyl-2- Highly Toxic Dangeroua Fire Riak [75-66-11
propanethioll Oral, rat Primary Irritant
LD50:4729 mg/kg
Carbon tetrabromide (CBr41 Moderately Toxic Narcotic O. 1 ppm TWA (558-13-4 I
Intravenous. rat O. 3 ppm STEL
LD50: 56 IIg/kg (recommended)
Carbon tetrachlorida (CC141 Highly Toxic Ingeation 10 ppm TWA (56-23-51
Oral, humans Inhalation 22 ppm Ce l.1ing
LDLo:43 mg/kg Skin Absorption
Na reo tic
Positive Carcinogen
Mutagen
Teratogen
Primary Irritant
Tumorigen
(Continued)
.....
-------
Chemical
CHAIN TRANSPER AGENTS (Continued)
Chi oro benzene [C6HSCll
Chloroform [CHCI31
Crotonaldehyde [2-butenall
[CH3CH:CHCHOI
00
VI
\0
Cyclohexane [C6"121
n-Decyl mercaptsn [CloH21SHI
trans-Dichloroethylene [CIHC:CHCll
Diethyl zinc [Zn(C2HS)21
TABLE C-15 (Continued)
Toxicity
Toxic
Inhalation, mouse
LCLa:lS gm/m3
Toxic
Inhalation, human
TeLa: 1000 mg/m3/1Y
Toxic Effect: Systemic,
Behavioral Symptoms, Gastro-
intestinal Tract
Toxic
Inhalation, humans
TeLa: 12 mg/m3/10 Min.
Toxic Effect: Eye, Pulmonary
Syatem
Moderately Toxic
Oral, rat
LD50:29,S20 mg/kg
Toxic
Toxic
Inhalation, humana
TeLa: 4800 mg/m3/10'Hin.
Toxic Effect: Behavioral
, Symptama
Concern
Inhala tion
Skin Contact
Moderate Pire RJak
Inhalation
Ingestion
Marcotic
Suspected Carcinogen
Tumorigen
Mutssen
Teratogen
Primary Irritant
Irritant to Skin and
Eyes
Dangerous Pire Risk
Primary Irritant
Dangerous Pire RJsk
Inha lation
Skin Contact
Mutagen
Ingestion
Inhalation.
Ingestion
Inhalation
Skin Abaorption
Irritant
Narcotic
Dangerous Pire Risk
Ignites Spontaneously
in Air
OSHA Regulation
7S ppm TWA
SO ppm TWA
2 ppm TWA
300 ppm TWA
[CAS No.)
[IQS-90-71
[67-66-31
[123-7)-91
'.~
[110-S2-7 )
I.,
II
~~...
'~~
[156-60-S)
1,." ,
ISS 7-20-0)
(Continued)
-------
TABLE C-15 (Continued)
Chemical Toxicity Concern OSHA Regulation (CAS No. 1
CHAIN TRANSFER AGENTS (Continued)
Dipentene (CldK161 Moderately Toxic Moderate Fire Risk (138-86-31
Oral, rat Primary Irritant
LDSO:Soo? 109/kg
Dodecylmercaptan (C12H2sSHI Oral, rat 0. S ppm lS minute (1l2-SS~1
LDSO:309 mg/kg Ceiling (recolDIDended)
Ethane (C2H61 Severe Fire Risk [74-84-01
Ethanethiol (C2HSSHI Highly Toxic Primary Irritant 10 ppm Ceiling [7S~8-1 1
Inhalation, rat Ingestion
LCSO:4420 ppm/4 Hr. Inha lation t-r"
Dangerous Fire Risk
Ethyl acetate (CH]COOC2HSI Toxic Primary Irritant 400 ppm 'l\IA (141-78-61 !"
Inhalation, humans Inhalation
TCLo:400 ppm Skin Absorption
00 Toxic Effect: Irritation of Skin and Eye Irritant '
0\ Eyes, Pulmonsry System and Dangerous Fire Risk "r.'t
o Nasal Passages Tullorigen
Ethylbenzene (C6"SC2HSI Moderately Toxic Ingestion 100 ppm 'l\IA (skin) (100-41-41 'h
Inhalation, humans Inhalation ~'
TCLo: 100 ppm/8 Hr. Skin Absorption
Toxic Effect: Irritation, Skin and Eye Irritant
8ehavioral Symptoms Dangerous Fire Risk
!eratogen
Ethylmercsptoacetste Intraperitoneal, mouse (623-S1-8 1
LDSO:loo mg/kg
Formic Acid (See Acids 1
Hydrogen (H21 Highly Flammable snd (13JJ-74~ I
Explosive
Isobutanol (CH3)~HCII20HI Moderately Toxic Primary Irritant 100 ppm 'l\IA (78-83-11
Inhalation, rat Flallllll8ble
LCLo: 8000 ppm/4H Tumorigen
Mutagen
(Continued)
-------
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Chemical
CHAIN TRANSFER AGENTS (Continued)
Isobutsne [(CH3)1CUCH3)
Isopropsnol [(CH3)1CHOH)
Isopropyl benzene [Cumene),
[C6HsCH(CH3)2)
00
0'1
I-'
Lauryl mercsptsn [C12H2s5H)
[See Dodecyl mercaptsn)
Mercsptoacetic acid [Tbioglycolic
acid), (HSCH1COOH)
2-Hercaptoethanol (HSCH2CH20H)
Hethane [CH4)
Methanol (CHJOH)
TABLE C-15 (Continued)
Toxicity
Moderately Toxic
Oral, rat
LDLo: 5840 mg/kg
Todc
Inhalation, humana
TCLo: 200 ppm
Toxic Effect: Irritant
Toxic
Oral, rat
LD50:250 mg/kg
Moderately Toxic
Oral, rat
LD50:3oo mg/kg
Todc
Inhalation, humans
TCLo: 86000 mg/m3
Toxic Effect:' Irritant
Concern
Dangerous Fire Risk
Primary Irritant
Ingestion
Inhala tion
Dangerous Fire Risk
Tumorigen
Mutsgen
Suspected Human
Carcinogen
Primary Irritant
Ingeation
Inhalation
Skin Absorption
Moderate Fire Risk
Corrosive
Ingeation
Inha la tion
Skin Irritant
Primary Irritant
Inhala tion
Ingestion
Mutagen
Severe Fire Riak
Ingea tion
Dangeroua F1 re Ri sk
Mutagen
Teratogen
Primary Irritant
OSHA Regulation
400 ppm 'IWA
50 ppm TWA (akin)
200 ppm 'IWA
I,; I,
. II
;. y(
.,,1," oj
" f 1
, V .~ I
f I , "II
I .~. t i
. .'-1
~, l
(CAS No.)
(75-28-5)
(67-63~)
(98-82-8)
[68-11-11
[60-24-2)
~.
I [74-82-8)
,
[67-56-1)
".J
(Continued)
-------
Chemical
CHAIN TRANSFER AGENTS (Continued)
Methyl acetate
Z-Hethyl-Z-propanethiol [See t-Buty1
mercaptan)
o-Hethyl styrene dimer
Z-Haphthalenethiol [RPAI,
[C1oH7SH)
)-Pentanol
[CH)CHZCHOIICHZCH))
co
CI'
N
Perchloroethylene (ClzC:CCIZI
Phenol [C 6lIsOH I
Polybromobutenes
Propane [C)H8)
Z-Propanethiol (C)H7SHI
Propylene [CH)CH:CHZI
TABLE C-15 (Continued)
Toxicity
Moderately Toxic
Inhalation, humana
TCLa:1S,OOO mg/m3
Toxic Effect: Eye,
System
Pulmonary
Intraperitoneal, mouse
LDSO:Zoo mg/kg
Oral, rat
LDSO:1870 mg/kg
Moderately Toxic
Inhalation, humana
TeLa: 96 ppm/7H
Toxic Effect: Peripheral
Nervous System, Eye, Behavioral
Symptoms
Toxic
Oral, humans
LDLa: 140 mg/kg
Oral, rat
LDSO:1790 mg/kg
Concern
Inhala tion
Pri..ary Irritant
Dangerous Fire Risk
Moderate Fire RIsk
Inhalation
Irritant to Eyes and
Skin
Pod ti ve Animal
Carcinogen
Mutagen
Ingeation
Inhalation
Skin Absorption
Strong Tissue
Irritsnt
Mutagen
Dangeroua Fire Rlak
Dangeroua Fire Risk
Dangerous Fire Risk
Tumorigen
OSHA Regulation
ZOO ppm Tl/A
100 pp.. Tl/A
ZOO pp.. Ceiling
)00 ppm/5H/3H Piak
Ii I;
. II
\.
I ,',
S ppm TWA (ski~) .
'y
1";:--,(1
. :-,. I'
, ~ J,
1"1 ;~)
I.f~i,
1000 ppm TWA I
I;) l
O. S ppm Ceiling
(recommended)
[CAS No.)
[79-Z0-9 I
[7S-66-1 )
(91-60-1 )
[S84-oZ-1 J
[lZ7-18-4)
(108-9S-Z)
. .
tI. 'II'
[74-98-61
(107-0)-9)
[l1S-07-1)
(Continued)
"
. .
-------
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1
Chemical
CHAIN TRANSFER AGENTS (Continued)
Sodium acetate (NaC2"]021 (See
Buffers I
Terpinolene (CloH161
,
i
Thiophenol (C6HsSHI
Toluene (C6HSCH31
'I
.<
,
00
0\
IN
Trichloroethylene (CHC1:CC121
Triethylamine (C2"5)3NI
Water
COAGULANTS
Calcium chloride (CaC121
Hydrochloric acid (See AcidsJ
TABLE C-15 (Continued)
Toxicity
Oral, rat
LD50:4390 IIg/kg
Hoderately TOKlc
Oral, rat
LD50:46 mg/kg
Todc
Inhalation, rat
LCLo: 4000 ppm/4H
Todc
InhalatIon, humans
TDLg:6900 mg/m3/l0 Min.
Toxic Effect: Central Nervous
System, Behavioral
Todc
Oral, rat
LD50:460 mg/kg
Low
Oral, rat
LD50: 1000 mg/kg
Concern
Moderate FIre Risk
Primary Irritant
Pr Imary Irritant
Ingestion
Inhalation
Skin Absorption
Dahgerous Fire Risk
Tumorlgen
Mutsgen
Terstogen
Inhalation
PosH lve An imal
Carcinogen
Mutagen
Terstogen
Primary Irrltsnt
Ingestion
Inhalation
Pr lmary Irri tant
Mutagen
Fire Rlsk
EquIvocal TumorIgenIc
Agent
Mutagen
OSHA Regulation
O. 5 ppll TVA
(recommended)
200 pp.. TVA
300 ppll CeIling
100 ppm TVA
200 ppm CeIling
25 ppm TVA
1"
I, I.
~t
(CAS No.1
ti~
~I.II
( 586-62 -9 I
(108-98-5 I
(108-88-31
(79-01-6 I
[12l-44-8J
110043-52-4 I
(Continued)
-------
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1
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1
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i
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1
Chemical
COAGULANTS (Continued)
Sodium chloride (NaCll
Sulfuric acid (See Acidal
CROSSLINKING AGENTS
Oialdehyde starch
Oiepoxides
,
.1
, j
1
Oimethylolurea (CO(NHCHzOH)21
Oihydroxydiphenylsulfone
( (C6H40HhS021
, !
I
Oihocyanates
00
C\
~
Ohinyl benzene
(C6"4(CH:CH2h I
Ohinyl sulfone
(CH2:CHSO~H:CH21
Glutaraldehyde
"
Glycol dimethacrylates
Glyoxal (OHCCOHI
Oxalic acld (HOOCCooHI
,',
"
I.
,.~
TABLE C-15 (Continued)
: i ~
Toxicity
Concern
OSHA Regulation
(CAS No.1
Oral, rat
LDSO: 3000 mg/kg
(7647-14-S1
Oral, rst
LOSO:3400 mg/kg
Skin Irritant
(140-9S-41
Toxic Inhala t lon 10 ppll 'NA (108-S7-6 I
Oral, rat Primary Irritant (recommended)
LOSO: 4040 mg/kg
Oral, rat Primary Irritant (77-77-0 J
LOSO:32 mg/kg
Moderate Primary Irritant 0.2 ppm Ceiling (111-30-81
Skin. humans Mutagen (recommended)
6 mg/30-1 Teratogen
Toxic Effect: Severe Irrltation
Moderate Ingestion (107-22-21
Intraperitoneal, rat Inhalation
LOLa: 100 mg/kg -Primary Irritant
Mutagen
Toxic Inhalation 1 mg/m3 TWA [144-62-7 I
Oral, rat Ingestion
LOSO' 37S mg/kg Strong Irritant
(Continued)
-------
! .
Chelllical
CROSSLINING AGENTS (Continued)
Polyacrolein
Trimethylolmelamine
Trivinyl benzene
DEPOAIWITS
Aluminum oxide, hydrated ISee
Protective Colloidal
Decanol ICH3(CHZ)sCHZOHI
00
0\
VI
Dimethyl ailicone (polymeric)
1«CR3)ZSiO),,1
Glycerol lZ-tiydroxyoleate Iglyceryl
monoricinoleatel
IC6Hl3CHOHClOHl8COOCHZCHOHCHzORI
Heptanol ICH3(CHZ)SCRZOHI
Rexanol ICH3(CHZ)4CRzOHI
Octanol ICH3(CHZ)6CHZOHI
EMULSIFIERS
Alkyl naphthalene aulfonic acid
Ammonium oleate IC17H3JCOONH41
TABLE C-15 (Continued)
Toxicity
Low
Oral, rat
LDSO:47Z0 mg/kg
. Toxic Effect: Behavioral
SymptOIl8; Pulmonary Syatem
Low
Low
Oral, rat
LDSO:3ZS0 mg/kg
Low
Oral, rat
LDSO: 720 mg/kg
Low
Oral. mouse
LDSO:1790 mg/kg
Concern
Tumorigen
Primary Irritant
Primary Irritant
Mutagen
Primary Irritant
OSHA Regulatioal,; ,; ICAS No. I
,11
l'
I i
I "
, ~' 11017-S6-71
I I' ,,;
I ,\,'.}
; 't 11
1"1 ,p
.I.~/j,
t., I'
. . ,1112-30-11
tj,lj
19006-6S-91
1111-70-61
1111-27-31
1111-87-S1
(Continued)
-------
/
i '
Chemical
,',1
EMULSIFIERS (Continued)
Ammonium atearate
[C 17H 3 sCOONH4 I
Cetyl trimethyl ammonium bromide
[CI6"33(CH3)3NBrl
Cetyl pyridinium chloride
[CI6"33CsHsNCI'H:z01
Dihexyl sodium sulfosuccinate
Dodecyl benzene sulfonste
Dodecyl benzene sodium sulfonate
[C12H2sC6"4S0)Hal
00
'"
'"
Dodecyl pyridinium chloride
Dresinate [Rosin soap I
Ethyl crotonate
[CH]CH:CHCOOC2H51
Isopropy18lline dodecyl benzene
sulfonate
Lauric acid [CH3(CH2)loCOOHI
Lauryl trimethyl quaternary ammonium
bromide
Lauroxypolyethylene glycol
Myristic acid [CH3(CH2)12COOJlI
TABLE C-15 (Continued)
Toxicity
Concern
Low
Oral t mouse
LD50:60 mg/kg
Primary Irritant
Oral, rat
LD50:200 mg/kg
Primary Irritant
Oral, rat
LD50:650 mg/kg
Oral, rat
LD50: 1260 mg/kg
Primary Irritant
Oral, rat
LD50:3000 mg/kg
Strong Irritant
Dangeroua Fire Risk
Low
Oral, rat
LDSO:12 gm/kg
Tumorigen
Nontoxic
Skin, humans
15 mg/3D-I
Toxic Effect:
Irritation
Primary Irritant
Moderate
I. I;
II .
\'
I
, ,
, II
I
I
OSHA RegUlatio~~' [CAS No.1
" ,~:o.(
; '{ l' \[ 102-89-1 I
1'1 '",II ,
,I,t r 11[13316-10-61
1,,1'
t), ~l [123-03-5 I
[3006-15-3 I
[1886-81-31
[25155-30-01
[623-70-1 I
[26264-05-1 I
[143-07-1 I
[544-63-8 I
(Continued)
-------
I
i
1
Chemical
EMULSIFIERS (Continued)
Palmitic acid (CH3(CH2)14COOHI
Polyoxyethylene oleate
Potaaaium caprylate
Potasaium dehydroabietate
Potassium laurate [KOOCCI1H231
00
(1\
'-.I
Potassium myristate
Potassium oleate [C17H))COOKI
Potasaium palmitate
Potassium aodium tartrate
[KNaC4H406.4H201
Potaaaium atearate [C17H3sCOOKI
Sodium capryl sulfonate
Sodium cetyl sulfate
Sodium decyl sulfate
TABLE C-15 (Continued)
Toxicity
Nontoxic
Intravenous. mouse
LD50:57 mg/kg
Toxic Effect: Convu1aions
Intravenous, mouse
LD50:500 IIg/kg
Skin, humans
7320 mg
Toxic Effect:
Irritation
Skin, humans
9560 mg
Toxic Effect:
Irritation
Eye, rabbit
12 mg/48H
Toxic Effect:
Irritation
Skin, humana
11,800 mg
Toxic Effect:
Irritation
Nontoxic
Nontoxic
Intravenous, mouse
LD5D:56 mg/kg
Concern
Tumorigen
Primary Irritant
Primary Irritant
Primary Irritant
Primary Irritant
OSHA Regulation
~ .
(CAS No.1
(57-10-31
(9004-96-01
[764-71-61
(10124-65-9 ]
(143-18-01
[2624-31-91
[142-87-01
(Continued)
-------
I
Chemical
EMULSIFIERS (Continued)
Sodium decyl sulfonate
Sodium dioctyl sulfosuccinate
(CSH1700cCH2CH(S03Na)COOCSH171
Sodium dodecyl diphenyl ether
dhulfonate
Sodium dodecyl sulfate (Sodium
lauryl sulfate I
Sodium dodecyl sulfonate
00
C-
OO
Sodium hexadecyl sulfate
Sodium lauryl benzeoe sulfonate
Sodium lauryl sulfate
[NaC12H2sS041. [See Sodium
dodecyl sulfatel
Sodium naphthalene sulfonate
[C12H7S03Nal
Sodium oleate [C17HnCOONaI
Sodium reainate [Sodium abietatel.
[C1 !jH2 gCOONa I
Sodium stearate [NaOOCC1711351
. '
"
TABLE C-15 (Continued)
Toxicity
Low
Skin. rabbit
10 mg/24H
Toxic Effect:
Irritation
Moderate
Low
Skin. humans
250 mg/24H
Toxic Effect:
MUd Irritation
Hay be Toxic
Low
Intravenous, mouse
LDSO: 152 mg/kg
Intravenous, dog
LOto: 10 mg/kg
Concern
Primary Irritant
Tumorigen
Mutagen
Primary Irritant
Ingestion
Inhalation
OSHA Regulation
t.
i
,.
.
[CAS No.1
[577-11-7)
[151-21-31
(1120-01-0 I
(143-19-11
(6S9l9-S0-21
[822-16-21
(Continued)
-------
"
'j
Chemical
EMULSIFIERS (Continued)
Sodium tetradecyl sulfonate
Stearic acid [CU3(CH2)16COOH)
Stearyl trimethyl ammonium chloride
Sulfonated caster oil [Turkey Red
011)
Triton X-IOO
.1
Triton X-200
00
'"
\0
FEED STREAK DESSICANTS
Alumina [See Protective Colloids)
, ;
Aluminum alkyla
Calcium hydride [CaR2)
Calcium sulfate (anhydroua)
[Cas04 )
Caustic Soda (solid) [See Bases
(Sodium hydroxide»)
TABLE C-15 (Continued)
Todc! ty
Non toxic
Skin, humans
75 mg/3D-I
Toxic Effect:
Hlld Irritation
Unknown, mouse
LDLo:50 mg/kg
Low
Oral, rat
LD50:1800 mg/kg
Oral, rat
LD50:17,500 mg/kg
Nontoxic
Intraperitoneal, rat
TDLo:450 mg/kg/3W
Toxic Effect: Carcinogen
Concern
Tumorigen
Primary Irritant
Skin Irritant
Flammable
Tumorigen
OSHA Regulation
10 mg/m3 TWA
(recommended)
[CAS No.)
[57-11-4 )
[1l2-Q3-8 )
[8002-33-3 )
19036-19-5)
[9010-41-7 )
17789-78-8 J
[10101-41-4)
[7778-18-9) gypsum
[14798-{)4-Q)
anhydrite
[23296-15-3)
precipitated
'..,.
,
'"
'0.
'h
(Continued)
~,.
-------
,-
TABLE C-15 (Continued)
Chemical Toxicity Concern OSHA 8.egulation (CAS No.)
FEED STREAM DESSlCANTS (Continued)
Copper, (metallic) (Cu) Toxic (powders) Ingestion 1 mg/m3 TWA (dust) ( 7440-50-8 J
Oral, rat Inhalation 2mg/m3 STEL ,
TDLo: 152 mglltg Powder is Flammable (recommended)
Toxic Effect: Reproductive,
Embryotoxicity, Developmental
Molecular seive Oral, rat
LD50:2,OOO-28,OOO mglltg
SiUcs gel Toxic Inhalation 80 mg/m3 TWA (7631-86-9)
Oral, rat (Silicosis)
LD50:3160 mglltg
Sodium, (metal) (Na) Strong Tissue (7440-23-5 J
Irritant
Severe Fire 8.islt in
Contact with Water
00 Ignites Spontaneously
...... in Air
C
Sodium hydroxide on asbestos (See
Bases J
INERT GASES
Carbon dioxide (C02) Inhalation, humans 5000 ppm TWA (124-38-9J
LCLo: 100,000 ppm/lK
i Nitrogen (N2) (7727-37-9)
1
j PROTECTIVE COLLOIDS .,oort'
!
Acrylic acid-2-ethylhexyl-acrylate .,
copolymer )-
Alumina (AI203) Nontoxic Inhalation 10 mg/m3 TWA (1344-28-1 J \~'" ."
Intrapleural, rat Tumorlgen (recommended) :
T~: 90 mglltg I
Todc Effect: Equivocal : 11~
Tumorigenic Agent . ~1.; {I
(Continued)
-------
. .
I
1
,
,
I
1
,
j
i
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~
.1
Chemical
PROTECTIVE COLLOIDS (Continued)
Barium persulfate
[BaSzOSo4H20)
Barium phosphate [BaHP04)
Barium sulfate [BaS04)
Ii
.J
Calcium persulfate
Calcium phosphate [Ca)(P04)2)
Carboxymethyl cellulose
00
-...J
I-'
Clay [Kaolin), [AI20)Si02)
Ethyl cellulose
Gelatin
Gum acacia
Hydroxyapatite
[CalO(P04)6(OH)2)
Hydroxyethyl cellulose ICelloaize)
Hydroxypropyl cellulose
TABLE C-15 (Continued)
Todci ty
Nontoxic
Intrapleural, rat
TI>[..,: 200 mg/kg
Toxic Effect: Equivocal
Tumorigenic Agent
Nontoxic
Oral t rat
LD50:27,Ooo mg/kg
Nontoxic,
Skin, rabbit
500 mg/24 Hr °
Toxic E(fect:
Hild Irritation
Nontoxic
Oral, rabbit
LD50: 800 mg/kg
Nontoxic
Nontoxic
Oral, rat
LD50:10,200 mg/kg
Concern
Tumorigen
lrritant.
Inhalation
Primary Irritant
Primary Irritant
OSHA Regulation
10 mg/m) TWA
(recommended)
. ,
.
ICAS No.)
(1)462-86-7)
[7727-4)-71
[7758-87-4 )
[9004-)2-4 )
[ 9000-11-7)
(1)27-)6-21
[9004-57-) )
[9000-01-5 )
[9004-64-2 )
(Continued)
-------
TABLE C-15 (Continued)
.,
,
Chemical Toxicity Concern OSHA Regulation (CAS Nod
PROTECTIVE COLLOIDS (Continued)
Hydroxypropyl methyl cellulose
Magnesium carbonate (HgC031 (546-93-01
Magnesium odde (HgOI Toxic Inhalation 15 IIg/m3 TWA (1309-48-41
Inha lation, humans 1\1l1origen
TCLo' 400 m8/m3
; Todc Effect' Unspecified
. ~
Magnesium persulfate
.i Magnesium phosphate
-; (Mg)3(P04)2"4HzOl
,
Magnesium silicate (HgSi031 Toxic Inhalation [1343-90-41
Skin, humans Primary Irritant
300 ug/3D
(X) Toxic Effect' MUd Irritation
-....J
N Methyl cellulose (Methocell Intraperitoneal, mouse [9004-67-51
LD50'275 gm/ltg
Methyl(hydroxypropyl)cellulose
Pectin Nontoxic [9000-69-51
Polyacrylamide resin Nontoxic
(-CH2CHONH2-)xl
Polyvinyl alcohol «-CH2CHOH-)xl Nontodc Positive Animal [9002-89-51
Subcutaneous. rat Carcinogen
.', TOW: 2500 IIg/kg 1\1l1origen
Toxic Effect' Carcinogen
Polyvinyl pyrrolidone Nontoxic Tumorigen [9003-39-81
«-'C6H~0-)xl Intraperitoneal, rat Suspected Animal
TDLo' 2500 mg/kg Carcinogen
Toxic Effect: Carcinogen
Potassium persulfate (K2S2081 2 OIg(S208)/1I3 [7727-21-11
TWA (recoOlOlended)
(Continued)
-------
Chemical
PROTECTIVE COLLOIDS (Continued)
Sodium polyacrylate
Starch [(-C605HIO-)x)
Sulfonated polyatyrene
Talc [Hg3Si4010(OH)2) or
[3HgO.4Si02.H~)
Zinc oxide [ZnO)
00
"
W
SOLVENTS
Acetic acid [See Chain Tranafer
Agents)
Acetone [See Chain Trsnsfer Agents)
Amyl acetate [CH3COOCsHll)
n-Amyl slcohol [CsHIIOH)
Benzene [See Chain Transfer Agents)
TABLE C-15 (Continued)
Toxicity
Eye, rabbit
2 mg
Toxic Effect:
Irritstion
Hoderate
Skin, humans
300 ug/3D
Toxic Effect:
Hild Irritation
Hoderate Skin, humans
300 ug/3D-I
Toxic Effect: Hild Irritation
Nontoxic
Oral, rat
TOto: 6846 mg/kg
Hoderate
Inhalation, humans
TCLo:5000 mg/m3/30H
Toxic Effect: Behavioral
toms. Pulmonary System
Hoderate
Oral, rat
LD50:3030 mg/kg
Concern
Primary 'Irritant
Primary Irritant
Inhalation
Primary Irritant
'lUmorigen
Inhalation"
Hutagen
Teratogen
Primary Irritant
Symp-
Inhalation
Inges tron
Primary Irritant
Dangerous Fire Risk
Ingestion
Inhalation
Hoderate Fire Risk
Primary Irritant
OSHA Regulation
2 mppcf TWA (non-
fibrous)
(recollllllended)
5 mg/m3 TWA
100 ppm TWA
[CAS No.)
[9003-04-7 )
[9005-25-8)
~i~
t,,-
[14807-96-6 )
!..'t.. !"
[1314-13-2)
,',
ih
, ,./
\;.'
[628-63-7 )
[71-41-0 )
(Continued)
-------
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I
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-1
1
I
Chemical
-
SOLVENTS (Contlnued)
-
Benzyl alcohol [C6H~H20H)
Bromobenzene [C6HSBr)
n-Butane [C4HlO). [See Chaln
Tranafer Agenta)
: ~
I-Butanol [CH3(CH2)zCH20H)
00
-...J
~
2-Butanol [aec-Butyl Alcohol).
[CH)CH2CHOHCH3)
2-Butanone [Methyl ethyl ketone),
[CH3CH2COCH31
t-Butyl alcohol [(CH3)3COHI
t-Butyl benzene [CloHI4)
Carbon tetrachlorlde [See Chaln
Transfer Agents)
TABLE C-15 (Continued)
Toxicity
Low
Oral. rat
LDSO: 1230 mg/kg
InhalstIon, rat
LCSO:20.4ll mg/m3
Toxic
Inhalatlon, humans
TCLo:2S ppm
Todc Effect: Irritant.
Nasal. Eye, Pulmonsry System
Todc
Inhalation, rat
LCLo: 16,000 ppm/4H
Inhalatlon, humans
TCLo: 100 ppm/SH
Toxic Effect: Irritant.
Nasal, Eye. Pulmonary Syate..
Toxlc
Oral, rat
LDSO:3S00 mg/kg
Todc
Oral. rat
LOto: 5000 mg/kg
Concern
Primary Irritant
Tumorlgen
Inhala tion
Skln Irritant
Moderate Flre Rlsk
- Mutagen
Primary Irritant
Eye and Skln Irrltant
Moderate Flre Rlsk
Mutagen
Prlory Irr'tant
Inhalation
Eye and Skln Irrltant
Dangeroua Flre Risk
Mutagen
Teratogen
Prlmary Irritant
Inhalation
Eye and Skln Irrltant
Dangerous Flre Risk
Tumorlgen
Hutagen
Ingestion
OSHA Regulation
100 ppm 'NA
150 ppm 'NA
200 ppm 'NA
100 pp.. 'NA
[CAS No. I
[100-51-6 I
-!"'"
1.1,
[108-86-1 I
'.!r.-r
I,
'ip
. i, II
..~f.'1
[71-36-3 I
[18-92-2 I
[18-93-3 )
[15-65-0)
[98-06-6 )
(Continued)
-------
(
-I
1
j
I
1
i
Chemical
~ (Continued)
Chlorobenzene (See Chain Transfer
Agents I
Chloroform (See Chsin Transfer
Agents I
Cumene (Isopropyl benzenel, (See
Chain Transfer Agents)
Cyclohexane (See Chsin Transfer
Agents I
Cyclohexanone (C&"loPl
00
.....
VI
n-Decane (CH3(CH2)aCH31
o-Dichlorobenzene (C6H4C121
l,2-Dichloroethane (CICH~H2C11
Diesel fuel, hydrogenated
TABLE C-15 (Continued)
Todcity
Toxic
Inhalation, humans
TCLo: 15 ppm
Todc Effect: Nasal, Eye,
Pulmonary System
Skin, mouse
T~:25 gm/kg/52W
Toxic Effect: Equivocal
Tumorigenic Agent
Moderately Toxic
Inhalation, rat
LCLo: 821 ppm!1H
Toxic Effect: Behavioral
toms, Liver, Eye
Toxic
Oral. humans
T~:428 mg/kg
Toxic Effect:
Tract
Gastrointestinal
Concern
Inhalation
Skin Contact
Moderate Fire Risk -
Primary Irritant
Mutagen
Moderate Fire Risk-
Narcotic
Symp-
Primary Irritant
Inhalation
Ingestion
Tumorigen
Mutagen
Indefinite Human Car-
cinogen
Mutagen
Tumorigen
Ingestion
Inhala tion
Primary Irritant
Skin Absorption
Strong Eye and Skin
Irritant
OSHA Regulation
50 ppm nil.
50 ppm Ceiling
50 ppm nil.
100 ppm Ceiling
(CAS No.1
(108-94-1 )
(124-18-5 I
(95-50-11
(1~1-o6-2 I
(68334-30-5 I
(Continued)
-------
" .!
j
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.,
TABLE C-15 (Continued)
.~ ~
,
.J
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.'
~ : !
,
I
.,
Che..ical Toxicity Concern OSHA Regulation ICAS No. 1
SOLVENTS (Continued)
Dimethyl acetamide Intraperitoneal, mouse Inhalation 10 ppm TWA (skin) 1127-19-51
ICH]CON(CH3>21 LDSO:32oo mg/kg Skin Absorption
Strong Irritant
Dimethyl fotIDamide IHCON(CH3)21 Inhalation, !DOuse Tumorigen 10 ppm TWA (skin) 168-12-21
LCSO:94oo mg/..3/2H Teratogen
Strong Tissue
Irritant
Dimethyl sulfoxide I(CH3)2S01 Oral, rat Ingestion 167-68-51
LDSO:17,SOO mg/kg Mutagen
p-Dioxane IOCHzCH2OCHZ<;H21 Highly Todc Inhalation 100 ppm TWA (skin) 1123-91-11
I I Inhalation, humans Skin Absorption
TCLo:470 ppm/3D Primary Irritant
Todc Effect: Ca rd iovascular, Posltive Animal
Gastrointestinal, Convulsions Carcinogen
00
...... Dodecane ICH3(CH2)loCH31 Skin, !DOuse 1112-40-3)
a. TOto: 11 gm/kg/22W-I
Todc Effect: Equivocal
Tumorigenic Agent
Ethanol IC2HSOH) Oral, rat Depressant Drug 1000 ppm TWA 164-17-5)
LDSO:7060 mg/kg Dangerous Fire Risk
Todc Effect: Pulmonary
System
Ethylene dichloride ISee
l,2-Di~hloroethane)
2-Ethoxyethyl acetate Oral, rat 100 ppm TWA (skin) 1111-15-9)
ICH ]COzCHzCH2OCHzCH 3) LDSO:2900 mg/kg
Ethyl acetate ICH]COOC2Hsl Moderately Toxic Tumorlgen 400 ppm TWA 1141-78-61
Inhalation, humans Primary Irritant
TCLo: 400 ppm Inhala tion
Todc Effect: Nassl, Eye, Skin Absorption
Pulmonary System Eye and Skin Irritant
Dangerous Fire and
Explosion Risk
..,
,
".' ~
I
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(Continued)
-------
.,
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.
)
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Chemical
SOLVENTS (Continued)
Ethylbenzene (C~sC2HS)
Furfuryl alcohol (C4H3OCH~H)
or (qCH:CHCH:~CH20H)
Heptane (CH3(CH2)SCH3)
. ~
00
.....
.....
Hexane (CH3(CH2)4CH3)
laobutane (See Chain Tranafer
Agenta)
laobutyl alcohol (See Chain Tranafer
Agents)
Isobutyric acid (CH3)2CHOOH)
Isooctane
(CH3)3CCH~H(CH3)2)
Isopentsne (CH3)~HCH~H3)
TABLE C-15 (Continued)
Toxici ty
Moderately Toxic
Inhalation, huaans
TCLo: 100 ppm/811
Toxic Effect: Irritant, Eye,
Behavioral SymptOflll, Pull8Dnary
Syatell
Toxic
Inhalation, rat
.LCSO:233 pplI/4H
Moderately Toxic
Intravenous, mouse
LDSO:222I1g/kg
Moderately Toxic
Inhalation, humans
TCLo:SOOO ppm/IO Min.
Toxic Effect: Central Nervoua
Systell, Behavioral SYliptoms
Oral. rat
LDSO:280 mg/kg
Moderately Toxic
Low
Concern
Ingestion
Inhalation
Skin Absorption
Irritant to Skin and
Eyes
Dangerous Fire Risk
Teratogen
Primary Irritant
Inhalation
Tumorigen
Mutagen
Inhalation
Dangerous Fire Risk
Primary Irritant
Ingestion
Inhalation
Dangerous Fire Risk
Teratogen
Corros1 ve
Stiong Skin Irritant
Dangerous Fire Riak
Ingestion
Inhalation
Dangerous Fire Riak
OSHA Regulation
100 ppm TWA (skin)
SO ppll TWA
SOO ppll TWA
SOO ppm TWA
3S0 IIg/1I3 TWA
(recommended)
3S0 IIg/1I3 TWA
1800 IIg/1I3/lS Min.
Ceiling
(recommended)
,
'.
I
"
1>
~..
(CAS No.)
(100-41-4 )
(98-00-0 )
(142-82-S)
(11o-S4-3 )
(79-31-21
(S40-84-l)
(78-78-4 )
(Continued)
-------
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TABLE C-15 (Continued)
Chemic:al Toxic:ity Concern OSHA Regulation (CAS No.)
SOLVENTS (Continued>
-
Isopropyl alc:ohol (See Chain
Transfer Agents)
Isopropyl benzene (See Chain
Transfer Agents (CUllene»)
Kerosene Moderately Toxic: Ingestion None
Unknown. lIaD Inhalation
LDLo: 11 76 mg/kg Moderate Pire Risk
Methanol (See Chain Transfer Agents)
Methyl ac:etate (See Chain Transfer
Agents)
Methylene c:hloride (CHzCI2) Moderately Toxic: Inhalation 500 ppm TWA (75-09-2)
Oral, rat Ingestion 1000 ppm Ceiling
00 LD50:167 mg/kg Skin Absorption
"'-I Primary Irritant
00 Tumorigen
Mutagen
Teratogen
Methyl ethyl ketone (See 2-Butanone I
Methyl isobutyl ketone Inhalation, humans Ingestion 100 ppm TWA (108-10-1)
(CH3>zCHCH2COCH3) TCLo: 200 ppm Inhala tion
Toxic: Effec:t: Irritant Dangerous Pire Risk
Primary Irritant
Methyl isobutyrate Oral, rat (547-63-7)
LD50:16,OOO mg/kg
Mineral 011 Intraperitoneal, mouse (8012-95-1)
TDLo: 14 gm/kg
Todc: Effec:t: Equivoc:al
Tumorigenic: Agent
0< Naphtha Inhalation, rat Dangerous Pire Risk 100 ppm TWA (8030-306-6)
LCLo:1600 ppm/6H
.,
(Continued)
-------
TABLE C-15 (Continued)
Chemical Toxicity Concern OSHA Regulation ICAS No. J
SOLVENTS (Continued)
-
Nitrobenzene IC6IIsN0zJ Highly Toxic Ingestion 1 ppm TWA (skin) 198-95-3)
Oral, rat Inhalation
LD50:640 IIg/1ts Skin Absorption
Primary Irritant
Pentane ICH3(CHZ)3CH3J Inhalation, humans Narcotic 1000 ppll TWA 1109-66-0)
TeLo:90,OOO pPIl/5 Min. Dangerous Fire snd
Toxic Effect: Central Nervous Explosion Risk
System
3-Pentanone IDiethyl ketone), Low Dangerous Fire Hazsrd ZOO ppm TWA I 96-ZZ-o )
ICzHsCOCZH5J Inhalation, rst Primary Irritant (recommended)
1£ Lo: 8000 ppm/4H
Z-Propanol Ilsopropyl alcohol I .. ISee Oral, man 400 ppm TWA 167-63-0)
Chain Trsnsfer AgentJ L~:8600 mg/kg
Inhslation, humans
00 TCLo: 400 ppm
" Toxic Effect: Irritstton
\0
n-Propyl acetate IC3H~OCCH3J Moderately Toxic Primary Irritsnt ZOO ppm TWA 1109-60-4 J
Inhalation, humans Dangerous Fire Risk
TeLo: 1000 mg/m3
Toxic Effect: Eye, Pulmonary
System
Pyridine Ir(CII)1iN) Toxic Primary Irritant 5 ppll TWA 1110-86-1 J
Inhalation, rat Ingestion
1£50:4000 ppm/4H Inhalation
Dangerous Fire Risk
Mutagen
l,l,Z,Z-Tetrafluorodichloroethane Moderstely Toxic Inhalation
ICCIFzCClPZ), IFreon 114 J
Tetrahydrofuran Low Toxicity Dangerous Fire Risk ZOO ppm TWA 1109-99-9 J
1~lIzCHzCHzCHz?J Inhalation, rat Mutagen
LCLo:Z8,OOO mg/m3/Z8
(Continued)
-------
Chemical
SOLVENTS .(Continued)
-
Toluene (See Chain Transfer Agents)
Triethylamine (See Chain Transfer
Agents)
2,2,4-Trimethylpentane [See
Isooctane)
Water
Xylene (C6H4(CH3)2)
00
00
o
THICKENERS
Glycerol (C3HS(OH)3)
Glycols
Polyglycols
TABLE C-15 (Continued)
Toxicity
Toxic
Inhalation, humans
TCLo: 200 ppm
Toxic Effect: Irritant
Low Toxicity
Concern
Primary Irr1"tant
Inhalation
Ingestion
Hoderate Fire Risk
Hutagen
Teratogen
OSHA Regulation
100 ppm TWA
:.
(CAS No.)
[1330-20-1)
[S6-81-S)
-------
i
j
I
I
j
1
J
j
1
-I
I
TABLE C-16. ULTRAVIOLET STABILIZERS
TOXICOLOGICAL AND WORKER EXPOSURE CONCERNS
Ultraviolet Stabilizers
BENZOPHENONES
4-Alkoxy-2-hydroxybenzophenone
(Uvinul 4101
4-Butoxy-2,2'-dihydroxybenzophe-
none (Cyasorb UV2871
5-chloro-2-hydroxybenzophenone
(C6H5COC6H50HCII
Cyasorb UV 2126 (Polymer of 4-(2-
Acryloyloxyethoxy)-2-hydroxybenzo-
phenonel
4-Decyloxy-2-hydroxybenzophenone
2,4-Dibenzoyl resorcinol (DBRI
00
00
+-'
2,4-Dihydroxybenzophenone
(C6H~OC6H3(OH)2)
2,2'-Dihydroxy-4,4'-dlmethoxy-
benzophenone (Ovinul D-49)
2,2'-Dihydroxy-4-methoxybenzophe-
none (Cyasorb UV 241
2,2'-Dihydroxy-4(octoxy)benzo-
phenone (Cyasorb UV 3141
Disodium 2,2'-dihydroxy-4,4'-di-
methoxy-5,5'-disulfobenzophenone
(Uvinul DS-491
4-Dodecyloxy-2-hydroxybenzophenone
(Rylex DI
4(Heptyloxy)-2-hydroxybenzophenone
(Un1stat 2471
Toxicity
Oral, rat
LD50: >10 gll/kg
Low Oral Toxicity
Intraperitoneal, mouse
LIIto: 100 mg/"g
Low Oral Toxicity
Low Oral Toxicity
Oralt rat
LD50: >10 811/"8
Low Oral Toxicity
Low Oral Toxicity
Concern
OSHA Regulation
Primary Irritant
(CAS No.1
(85-19-81
(131-56-61
( 131-54-41
(131-53-3)
(3121-60-61
(Continued)
-------
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Ultraviolet Stabilizers
BENZOPHENOHES (Continued)
2-Hydroxy-4-acryloxyethoxybenzo-
phenone
2-Hydroxy-4(-2-ethylhexoyl)benzo-
phenone
2-Hydroxy-4-isooctoxybenzophenone
2-Hydroxy-4-methoxybenzophenone
[Uvinul H 40), [Cyasorb UV9)
2-Hydroxy-4-methoxy-5-methylbenzo-
phenone [Unistat 2211)
00
00
N
2-Hydroxy-5-methoxybenzophenone
2-Hydroxy-l-methoxy-5-sulfobenzo-
phenone [Uvinul HS-40)
2-Hydroxy-4-methoxy-5-aulfobenzo-
phenone [Cyssorb UV-2B4)
2-Hydroxy-4-n-octyloxybenzophenone
[Cyssorb UV 531)
" ,
Hark 1535
.il
Permyl Bloo [Substituted phenone)
i
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Kesyn 78-6121 [low molecular weight
alkyl methacrylate-substituted
benzophenone)
TABLE C-16 (Continued)
Toxicity
Low Oral Toxicity
Skin, rabbit
500 mg/24H
Toxic Effect:
Irri tation
Hoderate
Low Oral Toxicity
Low Oral Toxicity
Oral, rat
LD50:)10 gao/kg
Intraperitoneal, mouse
LD50:1000 mg/kg
Low Oral Toxicity
Oral, rst
LD50:)10 8II/kg
Low Oral Toxicity
Low Oral Toxicity
Concern
Primary Irritant
Primary IrrItant
OSHA Regulstion
[CAS No.)
[2549-90-8 )
[33059-05-1 )
[131-57-7)
[ 14 770-96-8 )
[4065-45-6)
[1843-05-6 )
(Continued)
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Ultraviolet Stabilizers
BENZOPHENONES (Continued)
2,2'.4.4'-Tetrahydroxybenzophenone
(Uvinul D-50)
Uvinul 490 (mixture of 2.2'-Dihy-
droxy-4.4'-dimethoxybenzophenone)
BENZOTRIAZOLES
2(3'-t-Butyl-2'-hydroxy-5'-methyl-
phenyl)-5-chlorobenzotriazole
(Tlnuvin 326)
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2(3'.5'-Di-t-butyl-2'-hydroxy-
phenyl)-5-chlorobenzotriazole
(TInuvin 327)
00
00
W
2(2'-Hydroxy-3'.5-dI-t-amyl-
phenyl)benzotriazole (TInuvin 328)
2(2'-Uydroxy-3',5'-dI-t-butyl-
phenyl)benzotriazole (TInuvin 320)
. .
2(2'-Hydroxy-5'-methylphenyl)-
benzotriazole (TInuvin P)
2(2'-Hydroxy-5-t-octylphenyl)-
benzotrlazole
Ha rk 446
NICKEL ORGANICS
BIs(2.2'-thiobIs(4-t-octylpheny-
lato»nickel (See NIckel
bIs(octylphenyl sulfIde»)
Hark 1306A
Negopex A
TABLE C-16 (Continued)
Toxicity
Concern
Low Oral Toxicity
Low Oral ToxIcIty
Low Oral ToxIcity
Low Oral ToxIcIty
Low Oral ToxIcIty
Low Oral ToxIcIty
Low Oral ToxicIty
Oral. mouse
LD50:6500 mg/kg
PrImary IrrItant
Low Oral ToxIcIty
Oral, rat
LD50:>lO gm/kg
Low Oral ToxIcity
OSHA Regulation
(CAS No.)
(131-55-5 )
(1341-54-4)
(3896-11-5)
(3864-99-1 )
(25973-55-1 )
(3846-71-7)
(2440-22-4)
(35344-07-1 )
(Continued)
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Ultraviolet Stabilizers
NICKEL ORGANICS (Continued)
Nickel bis(0-ethyl(3.5-di-t-butyl-
4-bydroxybenzyl»phosphonate
(Irgastab 20021
Nickel bis(octylphenyl aulfide)
(Ferro AH-lOl and AH-l051
Nickel dibutyldithlocarbamate
(Ni(SC(S)N(C4H9)2)21
Nickel diisobutyldithlocarbamate
(ISO Butyl Niclatel
00
00
.J:-
Nickel dimethyldithiocarbamate
(Hethyl Niclatel
10% Nickel Hex-cem
10071 PI!: HB
Sanduvor NPU (Phenylmethyl-
decanoyl pyrazolate-Nickell
(2.2'-Thiobis(4-t-octylpheno-
lato»-n-butylamlne nickel (Cyasorb
UV 10841
UV Chek AH-205
HISCELLANEOUS, ACRYLATES
8utyl 2-cyano-3-methyl-3-(p-meth-
oxyphenyl)acrylate (UV Absorber
3171 .
N-(B-Cyano-B-carbomethoxyvioyl)-
2-methylindoline (UV Absorber 3401
TABLE C-16 (Continued)
Toxicity
Oral, mouse
TDto:22 mg/kg/78W
Toxic Effect: Equivocal
Tumorlgen
Oral, rat
LD50:17 am/kg
Low Oral Toxicity
Low Oral Toxicity
Oral, rat
LD50:>10 am/kg
Low Oral Toxicity
Low Oral Toxicity
Concern
Tumorlgen
Fungicide
OSHA Regulation
15 ug(Ni)/m3 TWA
(recommended)
15 ug(Ni)/m3 TWA
(recommended)
15 ug(Ni)/m3 TWA
(reco_ended)
15 ug(Ni)/m3 TWA
(recommended)
15 ug(Ni)/m3 TWA
(recommended)
15 ug(Ni)/m3 TWA
(recommended)
15 ug(Ni)/m3 TWA
(recommended)
15 ug(Ni)/m3 TWA
(recommended) .
(CAS No.1
(30947-30-91
(13927-77-01
(15521-65-01
(14516-71-31
(Continued)
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Ultraviolet Stabilizers
HISCELLANEOUS, ACRYLATES
(Continued)
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Ethyl 2-cyano-3,3-diphenylacrylate
[Uvinul N-35)
2-Ethylhexyl 2-cyano-3,3-diphenyl-
acrylate [Uvinul N-539)
Hethyl-2-carbemethoxy-3-(p-meth-
oxyphenyl)acrylste (Cyasorb
UV-1988)
Hethyl 2-cyano-3-methyl-3-(p-meth-
oxyphenyl)acrylate (UV Absorber
318)
HlSCELLANEOUS, SALlCYLATES
co
CO
l.n
p-t-Butyl phenyl salicylate
10316 COP HP (Proprietary)
Dipropylene glycol salicylate
[C3H6(OOCC6H40H)OCjH60H)
2-Ethylhexyl salicylate
p-Octylphenyl salicylate
[C6H40HCOOC6H4CsH17)
[Inhibitor OPS)
Phenyl salicylate
(C6H40HCOOC6H5)
p-(l,l,3,3-Tetramethylbutyl)phenyl
salicylate (See Octylphenyl
salicylate)
TABLE C-16 (Continued)
Toxicity -
Intraperitoneal, mouse
LD50: 100 mg/kg
Low Oral Toxicity
Low Oral Toxicity
Low Oral Toxicity
Oral, rat
TDto:600 ,"g/I
-------
TABLE C-16 (Continued)
.', Ultraviolet Stabilizers Toxicity Concern OSHA Regulation (CAS No.)
i
, OTHER MISCELLANEOUS AND PROPRIETARY
-.:; AST-lOOl Low Oral Toxicity
Barium metaborate, modi fled Low Oral TOxicity (13701-59-2)
Bis(2,2,6,6-tetramethyl-4-piperi-
dinoxy)sebacate
Carbon black Intravenous, mouse 3.5 8g/m3 TWA (1333-86-4)
LD50:440 mg/kg (1440-44 -0)
Chimassorb 944 (Hindered aMine)
C-tlDPE-2764 (Hindered aMine)
C-PPR-8004 (Hindered aMine)
C-PPR-8005 (Hindered aMine)
00
00 Copper iodide Moderately Toxic Inhalation (7681-65-4)
C'\
. ! 2,4-Dibenzoyl resorcinol
3,5-Di-t-butyl-p-hydroxybenzoic Human Mutagen (1421-49-4)
acid
2,4-Di-t-butylphenyl-3,5-di-t- Low Oral Toxicity
butyl-4-hydroxybenzoate (UV Chelt ~ ."
AH-340) i
2,4-Di-t-butylphenyl-3,5-d~-t-
butyl-4-hydroxybenzoate
Dimethyl-2-(4-methoxybenzylidene)
malonate
Good-rite UV 3034 (Hindered amine)
N-Ilexadecyl-3, 5-di-t-butyl-4- Low Oral Toxicity [67845-93-6)
hydroxybenzoate
(Continued)
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Ultraviolet Stabilizers
OTHER HISCBLLANEOUS AND PROPRIETARY
(Continued)
Hexamethyl phosphoric triamide
[Inhibitor HPI)
Hostavin N20
2-(2-Hydroxy-4-methoxybenzoyl)
benzoic acid [Cyasorb UV 207)
Hanganese iodide
Parabollx-100
PDI-0199 (benzophenone/hindered
amine mixture)
00
~
10328 FE HB, 10359 FE HB
40375 PP HP [Hindered amine)
Resorcinol mono benzoate
[C6H5COOC6H40H I
Sanduvor BPU [oxalanitidel
Sanduvor VSU [oxalanilide)
Tinuvin 144 [stearica1ly hindered
amine)
Tinuvin 770 [stearics1ly hindered
amine I
Tinuvin 662 [hindered amine)
Titanium dioxide
TABLE C-16 (Continued)
Toxicity
Toxic
Inhalation, rat
400 ppb/35W intermittent
Toxic Effect: Carcinogenic
Hay be Toxic
Low Oral Toxicity
Low Ora1'Toxicity
Low Oral Toxicity
Low Oral Toxicity
Nontoxic
Skin, humans
300 ug/3D
Toxic Effect:
Irritation
HUd
Concern
Carcinogen
Teratogen
Hutagen
Tumorigen
Tumorigen
Primary Irritant
Inha 1at ion
OSHA Regulation
15 mg/m3 TWA
[CAS No.)
[680-31-9)
,.
r
[35001-52 -61
[23949-66-8)
[52829-07-9)
[1317-80-2)
[ 13463-67-71
(Continued)
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TABLE C-16 (Continued)
Ultraviolet Stabilizera Toxicity Concern OSHA Regulation [CAS No.)
OTHER MISCELLANEOUS AND PROPRIETARY
( Continued) I
UV-chek 54lA Low Oral Toxicity
!
: UV-check AK-595 Low Oral ToxIcIty
Vanatay L.[phoaphate-type t
atabIl1zer) i.
ZInc oxide 5 mg(fume)/m3 TWA [1314-13-2 ) r.
Nontoxic Mutagen "r
InhalatIon, humana Te ra togen
TeLo' 600 mg/m3 PrImary Irritant
Toxic Effect' l\almonary
Syatem
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