EXHAUST EMISSIONS  FROM UNCONTROLLED
 VEHICLES  AND RELATED  EQUIPMENT USING
      INTERNAL COMBUSTION ENGINES
                         by
                    Charles T. Hare
                    Karl J. Springer


                  FINAL  REPORT
                       PART I
             LOCOMOTIVE  DIESEL ENGINES
             AND MARINE  COUNTERPARTS
                Contract No. EHS 70-108

                     Prepared for
       Characterization and Control Development Branch
          Mobile Source Pollution Control Program
                       and
             Air Quality Management Branch
         Stationary Source Pollution Control Program
             Office of Air and Water Programs
             Environmental  Protection Agency

                    October 1972

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          SOUTHWEST  RESEARCH  INSTITUTE
          Post Office Drawer 28510, 8500 Culebra Road
                  San Antonio, Texas 78284
                Emissions Research Laboratory

EXHAUST EMISSIONS FROM UNCONTROLLED
 VEHICLES AND RELATED  EQUIPMENT USING
      INTERNAL COMBUSTION  ENGINES
                          by
                     Charles T. Hare
                     Karl J. Springer
                   FINAL REPORT
                        PART I
              LOCOMOTIVE DIESEL ENGINES
              AND MARINE COUNTERPARTS
                 Contract No. EHS 70-108

                      Prepared for
        Characterization and Control Development Branch
           Mobile Source Pollution Control Program
                         and
              Air Quality Management Branch
         Stationary Source Pollution Control Program
              Office of Air and Water Programs
              Environmental Protection Agency

                      October 1972

                           Approved:
                           John M. Clark, Jr.
                           Technical Vice President
                           Department of Automotive Research

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                              ABSTRACT
       This report is Part 1 of the Final Report on Exhaust Emissions
from Uncontrolled Vehicles and Related Equipment Using Internal Com-
bustion Engines, Contract No. EHS 70-108.  Exhaust emissions from
three locomotive diesel engines were measured, including:  total hydro-
carbons by heated FLA; light hydrocarbons by gas chromatograph; CO,
CC>2» and NO by NDIR; NO and NOX by chemiluminescence; 03 by electro-
chemical analysis; and total aliphatic aldehydes and formaldehyde by the
MBTH and chromotropic acid methods, respectively. In addition,  smoke
plume opacity was measured using a special version of the PHS smoke-
meter, and an attempt was made to characterize particulate using an exper-
imental dilution-type sampling device.

       The engines tested were SP Unit 1311,  an EMD 12-567 switch engine;
SP Unit 8447,  an EMD 16-645E-3 line-haul engine; and SP Unit 8639, a GE
7FDL16 line-haul engine; and they were all operated in modes representative
of real operation. For test purposes, the engines  were loaded by absorbing
power from their main generators using the Southern Pacific SEARCH
machine facility, and all pertinent operating data were recorded.  In addition
to mass emissions computed from tests performed under the subject con-
tract, other available  data are used where possible in estimating emission
factors and national impact.
                                  11

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                               FOREWORD
        The project for which this  report constitutes part of the end product
 was initiated jointly on June 29, 1970 by the Division of Motor Vehicle
 Research and Development and the Division of Air Quality and Emission
 Data,  both divisions of the agency known as NAPCA.  Currently, these
 offices are the Characterization and Control Development Branch of MSPCP
 and the Air Quality Management Branch of SSPCP,  respectively, Office of
 Air and Water Programs, Environmental Protection Agency.   The contract
 number is EHS 70-108,  and the project is identified within Southwest Research
 Institute as 11-2869-01.

        This report (Part 1) covers the locomotive portion of the characteri-
 zation work only, and the other items in the characterization work will be
 covered by six other parts  of the final report.  Other efforts which have been
 conducted as separate phases of Contract EHS 70-108,  including:  measure-
 ment of gaseous  emissions from a number of aircraft turbine engines; meas-
 urement of crankcase drainage from a number of outboard motors; and inves-
 tigation of emissions control technology for locomotive diesel engines;  either
 have been or will be reported separately.

        Cognizant technical personnel for the Environmental Protection Agency
 are currently Messrs.  William Rogers Oliver and David S. Kircher,  and past
 Project Officers include Messrs. J. L. Raney, A.  J.  Hoffman, B. D.  McNutt,
 and G.  J. Kennedy.  Project Manager for Southwest Research Institute has
 been Mr. Karl J. Springer,  and Mr. Charles T. Hare has carried the technical
 responsibility.

        The offices of the sponsoring agency (EPA) are  located at 2565 Plymouth
 Road,  Ann Arbor,  Michigan 48105   and at Research Triangle Park, North
 Carolina 27711; and the contractor  (SwRI) is located at 8500 Culebra Road,
 San Antonio,  Texas 78284.

       The successful conduct of the locomotive portion of this project would
 not have been possible without the full cooperation of the Southern Pacific
 Transportation Company, including both San Antonio personnel and those in
 the San Francisco corporate headquarters.

       In particular, Messrs.  Phil Scott,  Earl Kaiser, and Jack Williams
 of the local Southern Pacific staff,  and Messrs.  Paul Garin, W. M. Jackie,
and Bob Byrne  of the San Francisco office were of great service to the
 project.

       Several individuals in the locomotive industry,  notably Mr.  Jack
 Hoffman of General Electric Company, and Mr. Hugh Williams and Mr. George
 Hanley of General Motors,  have provided technical assistance and a limited
amount of supplementary emissions data.

                                   iii

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                          TABLE OF CONTENTS

                                                                    Page
 LIST OF ILLUSTRATIONS                           .                  vT

 LIST OF TABLES                                                    vii

 I.    INTRODUCTION                                                 1

 II.   OBJECTIVES                                                    2

 III.   EXPERIMENTAL METHODS AND INSTRUMENTATION              3

      A.    Gaseous Emissions Measurements                           3
      B.    Smoke  Measurements                                       9
      C.    Particulate Measurements                                  11

 IV.   EMISSIONS TEST RESULTS                                      13

      A.    Gaseous Emissions Results                                 13
      B.    Smoke Results                                             20
      C.    Particulate Results                                         21
      D.    Special Test Results                                        23
      E.    Emissions During Transients                                24

 V.    ESTIMATION OF EMISSION FACTORS AND NATIONAL IMPACT    28

      A.    Emission Factors and Emission Estimates for
            Locomotive Diesel Engines                                 28
      B.    Emission Factors for the Marine Counterparts
            of Locomotive Diesel Engines                               34

 VI.   SUMMARY                               -                      36

 LIST OF REFERENCES                                               38

APPENDIXES

     Explanatory Notes on Appendix Data

     A.   Test Data and Computed Mass  Emissions, EMD 12-567
           (S. P. Unit 1311)
     B.   Test Data and Computed Mass  Emissions, EMD 16-645E-3
           (S. P. Unit 8447)
     C.   Test Data and Computed Mass  Emissions, G. E. 7FDL16
           (S. P. Unit 8639)
     D.   Analysis of Fuels Used During Locomotive Emissions Tests
     E.   Major Maintenance History of Test Locomotives

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                      LIST OF ILLUSTRATIONS

Figure                                                               Page

   1.   Main Gaseous Emissions Analysis /Readout System                4

   2.   Oven Used for  Temperature Control of FIA and Aldehyde
       Systems                                                         4

   3.   Sampling Line Installation on EMD  12-567  Switch Engine
       (SP-1311)                                                        4

   4.   Sampling Line Installation on EMD  16-645E-3 Engine (SP-8447)      4

   5.   Smokemeter Control/Readout Unit Located Inside SEARCH
       Facility                                                         10

   6.   Smokemeter 20-inch Support Ring and Optical Unit  Mounted on
       Unit 1311                                                       10

   7.   Smokemeter 40-inch Support Ring and Optical Unit  Mounted on
       Unit 8447                                                       10

   8.   Smokemeter 40-inch  Support Ring and Optical Unit  Mounted on
       Unit 8639                                                       10

   9.   Experimental Dilution-Type Particulate Sampler Used for
       Locomotive Tests                                               12

 10.   Control System Used to Maintain  Flowrate in 3 inch Diameter
       Sample Duct                                                    12

 11.  Arrangement of Sample Duct Used on Unit 1311                   12

 12.  Arrangement of Sample Duct Used on Unit 8639 (same as used
      on Unit 8447)                                                    12

 13.   Hydrocarbon Emissions (g/hr)  from three Locomotive Diesel
      Engines as a Function of Throttle Position                        14

 14.   Carbon Monoxide Emissions (g/hr) from Three Locomotive
      Diesel Engines as a Function of Throttle Position                 15

 15.   Oxides of Nitrogen Emissions (g/hr NO2) from Three Locomotive
      Diesel Engines as a Function of Throttle Position                 16

 16.   Aliphatic Adlehyde Emissions (g/hr HCHO)  from Three Loco-
      motive Deis el Engines as a Function of Throttle Position          17

                                 vi

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                          LIST OF TABLES

 Table                                                               Page

  1.    Locomotive Emissions Test Sequence                            6

  2.    Engine Speeds used as "Notches" for Unit 1311                   6

  3.    Values of Constants in Mass Emissions Equations                7

  4.    Locomotive Duty Cycles                                        8

  5.    Average Mass Emissions by Throttle Setting                    18

  6.    Locomotive Cycle Composite Emissions Results                19

  7.    Locomotive Light Hydrocarbon Data Summary                   20

  8.    Summary of Locomotive Steady-State Smoke Data               20

  9.    Summary of Locomotive Particulate Emissions Data             22

 10.    Average  Mass Emissions from a G. E. 7FDL16 Locomotive
       Engine Using Standard and Revised Engine Speeds               24

 11.    Cycle Composite  Emissions from a G. E.  7FDL16 Locomotive
       Using Standard and Revised Engine Speeds                     25

 12.    Smoke Emissions from a G. E.  7FDL16  Locomotive Engine
       Using Standard and Revised Engine Speeds                     26

 13.    Locomotive Emissions During  Acceleration Transients          27

 14.    U.S.  Locomotive  Population by Power Class and Builder        29

 15.    Summary of Reweighted Emissions from Units 1311 and 8639    30

 16.    Summary of Fuel-Based Emission  Factor Calculations          32

 17.    Summary of Brake Specific Emission Factor Calculations        32

18.    National Impact Estimates for  Locomotive Emissions            33

19.    Comparison of Subject National Impact Estimates with EPA
       Nationwide Air Pollutant Inventory Data                         33

                                vii

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                    LIST OF TABLES (CONT'D.)

Table                                                               Page

 20.   Re-Weighted Locomotive Emission Factors Used to
       Characterize Emissions from Their Marine Counterparts         35

 21.   Estimated Composite Emission Factors For 500- to 4000-hp
       Diesel-Powered U. S. Flag Merchant Vessels                    35
                                  Vlll

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                            I.  INTRODUCTION
        The program of research on which this report is based was initiated
 by the Environmental Protection Agency to (1) characterize emissions from
 a broad range of internal combustion engines in order to accurately set
 priorities for future  control,  as required, and (2) assist in developing more
 inclusive national and regional air pollution inventories.  This document,
 which is Part 1  of what is planned  to be a seven-part final report, concerns
 emissions from locomotive diesel  engines (and their marine counterparts)
 and the national impact of these emissions.

        In the case of the  locomotive diesels as well as many of the other
 engine categories investigated under this contract, very little previous
 emissions work which could be used as a guideline had been done prior to
 the subject emissions tests.  Fortunately, those who had done emissions
 testing were cooperative  in sharing their experiences,  which no doubt
 enabled the  test program to proceed more smoothly than it would have
 otherwise.   The test  procedures used were designed after discussions with
 locomotive and railroad people, but their intent is to gather useful research
 data  and nothing more.   Likewise, the  specific exhaust constituents  meas-
 ured and the techniques used were  mostly based on standard practice and
 the desire to gather meaningful  data, without considering their potential
 applicability or usefulness in  certification or surveillance testing.  The
 major exception taken to standard practice was the use of chemiluminescent
 NOX results rather than NDIR NO results for computation of NOX mass
 emissions,  a decision based on  experience in running the two types of ana-
 lyzers in parallel on a number of engines.  In addition,  since there is no
 "standard practice" for measurement of particulate emissions from loco-
 motives, an experimental sampling system was used; and it yielded extremely
 doubtful results.

        Since the size  of the locomotive engines prohibited their being brought
 to the Emissions Research Laboratory for testing, a system of instrumentation
 was designed and a crew was organized to perform the emissions tests on-
 site,  at the San Antonio Southern Pacific maintenance depot SEARCH (System
jEvaluation And Reliability jZIHecks)  facility.  These tests were conducted  over
 a~period of two weeks in April, 1972, on a two-shift basis to keep the loco-
 motives out of service only as long  as necessary.

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                           II.  OBJECTIVES

        The primary objectives of the locomotive portion of this project
 were to collect useful emissions data on three locomotive diesel engines,
 and to use these data in conjunction with supplementary data on emissions,
 number of units in service, and annual usage to estimate emission factors
 and national impact.  The  emissions to be characterized included total
 hydrocarbons,  light hydrocarbons, aldehydes,  CO, CO2, NO by NDIR and
 chemiluminescence, NOX by chemiluminescence, 03,  smoke by a modified
 PHS opacity meter, and particulate by an experimental dilution-type sampling
 system.  These emissions have been or will be measured for all diesel engines
 operated during this project, as required by the contract.

        The objectives included implicitly the operation of the locomotive
 engines  over a pattern of steady-state and transient conditions,  and the
 determination of the importance of each mode in the total  locomotive emissions
 picture.  These tasks are quite simple for locomotives, since there are gen-
 erally only eight throttle positions  (or "notches") at which the locomotives
 operate  (plus idle and dynamic brake).   The 12-567 switch  locomotive (unit
 1311) was an exception, since it had a continuous throttle (no notches) and no
 dynamic brake capability,  so artificial "notches" were set  for it by specifying
 a certain engine speed for  each mode.

       In addition to the  emissions measurements,  sufficient engine operating
 data were taken to ensure that  conditions repeated themselves adequately
 and that mass emissions could be calculated from the raw concentration data.
 Secondary objectives, not required by the contract, which were met included a
 limited evaluation of a modified large-ring  smokemeter using PHS optics, design
 of a test procedure which is compact but still tends to eliminate the effects of
 directional mode changes,  and an attempt at adaptation of the experimental
 dilution-type particulate sampler to locomotive  usage.

       Due to the overall brevity of the testing phase of this project,  it was
 determined at the onset that emissions from marine counterparts of the
locomotive engine would be characterized by weighting mode emissions data
taken on locomotives to more closely simulate marine operation.

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     III.  EXPERIMENTAL METHODS AND INSTRUMENTATION

        In order to fulfill contract requirements for locomotive diesel
 engine testing, three separate analysis systems were used.  Gaseous
 emissions, including light hydrocarbons and aldehydes, were measured
 by standard SAE techniques (J177 and J215) on a continuous sample
 drawn from inside the exhaust outlet to a point inside the SEARCH
 machine facility.  Smoke was measured using modified PHS-type opacity
 meters with remote readout inside the SEARCH facility,  and particulates
 were measured using an experimental dilution-type device which sampled
 from a "split" of the exhaust withdrawn through a 3-inch diameter tube.
 The techniques and instrumentation used for each type of analysis were
 quite dissimilar, so the  systems will be discussed separately.

 A.  Gaseous Emissions Measurements

        The gaseous emissions measured include:  total hydrocarbons
 by heated FIA;  CO,  CO2, and NO by NDIR;  NO and NO^by chemilumi-
 nescence; 03 by an electrochemical analyzer; total aliphatic aldehydes
 (RCHO) by the MBTH method* ' and formaldehyde (HCHO) by the chromo-
 tropic acid method1 '; and light hydrocarbons (CH4 through C^JQ) by gas
 chromatograph using a 10 ft  by 1/8 inch column packed with a mixture of
 phenyl isocyanate and Porasil C preceded by a 1 inch by  1/8 inch precolumn
 packed with 100-120 mesh Porapak N.  All the continuous measurements
 were recorded on strip-chart  recorders as well as mode-by-mode data
 sheets, but analysis of samples for RCHO, HCHO, and light hydrocarbons
 was performed at the Emissions Research Laboratory.  The aqueous
 reagents  through which exhaust was bubbled for aldehyde analysis were
 transported in small individual flasks,  and samples for light hydrocarbon
 analysis were transported in inert plastic bags. The instruments were
 located in the SEARCH machine facility, which was air-conditioned and
 served to isolate the instruments and crew members from the engine's
 heat, noise and vibration.  Figure  1 shows the main gaseous emissions
 analysis cart, including readouts for all the instruments and the analysis
 sections for all except hydrocarbons.   The oven shown in Figure 2 con-
 tained the HC detector and also served as  the wet  sample collection point
 for aldehydes. The sample line used was  3/8 inch O. D.  stainless steel,
 and was heated to maintain a sample gas temperature of 360°F.  Its  length
 (to the probe exit) was 23 ft for the  switch locomotive (unit 1311) and 17 ft
 for the two line haul locomotives, which gave response times of approxi-
 mately 7 seconds and 5 seconds, respectively.  The additional length for
 the switch locomotive was necessary because it had two exhaust stacks,
 and a "T" was added to the end of the fixed sample line to reach both of
them, as  shown in Figure 3.  The vertical (unheated) stainless  line which
joins the sample lines at the "T" carried purge air,  controlled by a re-
motely-operated  solenoid valve (hidden behind insulation at the "T").  The
air flow was considerably in excess of that required for sample line  purge,
 so the probe lines were also being backflushed by air while the purge was
occuring.   The same type of system was used for the other two locomotives,
                                   3

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 Figure 1.  Main Gaseous Emissions
 Analysis/Readout System
 Figure 2.  Oven Used for Temperature
 Control of FIA and Aldehyde Systems
Figure 3.  Sampling Line Installation
on EMD  12-567 Switch Engine (SP-1311)
Figure 4.  Sampling Line Installation
on EMD  16-645E-3 Engine (SP-8447)

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 as shown in Figure 4 for unit 8447 (the solenoid valve appears at right,
 at the end of the permanent sample line).

        Sample probes used for locomotive testing were of the multi-
 orifice or ''rake" type, patterned after those developed by engine manu-
 facturers!  '    They were constructed of 3/8 inch stainless  steel tubing
 and were oriented with holes facing upstream (not the same  as some
 previous work).  The probe locations were those determined earlier by
 manufacturers in most cases, with the possible exception that mixed flow
 was sampled near the  outlet of the G. E. U33-C (unit 8639),  above the
 crankcase eductors.  The mixed flow is that which is emitted to  the atmos-
 phere, so it should be sampled if proper mixing can be established.  The
 probes for the large locomotives had twelve 1/16 inch diameter holes,
 and each of the two probes used on the  switch locomotive had six 1/16
 inch diameter holes.

        Analysis for total hydrocarbons and aldehydes was carried out
 on hot samples, maintained at about 375°F by the oven shown in  Figure 2.
 These measurements are  considered to be on a "wet" basis, then, without
 the necessity for corrections.  All the other  emissions were measured "dry"
 that is,  on samples from which most of the ambient humidity and water of
 combustion had been removed, and the concentrations were corrected to a
 "wet"  basis mathematically. *   The primary water removal system con-
 sisted of ice-bath water traps, with further drying through anhydrous CaSC>4
 canisters upstream of the NDIR NO analyzer.  It is  recognized that water
 traps tend to  remove NO2 from the gases passed through them, so checks
 were made to determine the extent of this removal,  resulting in the  conclu-
 sion that about  11% of the NO£ was removed from calibration gases.  The
 same check was run on NO, with no measurable loss indicated.  In the
 reporting of results, no correction has been made for this measured loss.
 Such a correction would make only a very small change in composite brake
 specific emissions, and the results without correction are probably  most
 directly comparable to other reported emissions  results.  Further develop-
 ment will probably enable  the chemiluminescent instruments to sample wet
 exhaust gases,  eliminating the present problems.  It should also  be noted in
 this  discussion  that none of the NO or NOX numbers  have  been "corrected"
 for ambient humidity by any of the equations available for the purpose.  If
 the reader needs such a correction, the required ambient conditions will be
 presented in the Appendixes.

       The set  of test conditions which constituted one run for locomotive
 tests included 24 modes distributed as shown in Table 1.  This sequence
was designed for duplication of all conditions except idle (which was  included
 6 times due to idle variability), and the cancelling of directional effects by
approaching each power notch from both higher and lower power  settings.
 These goals were realized except for notch 4, which is  approached only from
lower power  settings, but test results were not affected by this imperfection.
The EMD 12-567 switch locomotive (unit 1311) had a continuous throttle with

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        TABLE 1.  LOCOMOTIVE EMISSIONS TEST SEQUENCE

          Notch or                    Notch or                    Notch or
 Mode    Condition           Mode    Condition           Mode    Condition
   1         Idle               9         N7                17       N5
   2         Nl               10         N8                18     Dynamic Brake
   3         N2               11         Idle               19       Idle
   4         N3               12      Dynamic Brake       20       N4
   5         N4               13         Idle               21       N3
   6         Idle              14         N8                22       N2
   7         N5               15         N7                23       Nl
   8         N6               16         N6                24       Idle
 no notches,  so artificial notches were made based on engine rpm.  Idle
 speed was 275 rpm for unit 1311, and rated speed was 800 rpm,  so the
 decision was made to set notch 1 at 300 rpm and divide the speed range
 up to 800 rpm into roughly equal increments.  The result of this arbitrary
 procedure is shown in Table 2, and it should also be noted that this locomotive
  TABLE 2.  ENGINE SPEEDS USED AS "NOTCHES" FOR UNIT 1311

               Notch   Engine rpm         Notch   Engine rpm

                1         300               5         584
                2         371               6         655
                3         442               7         726
                4         513               8         800
did not have a dynamic braking provision.  The procedure used for unit 1311
ended up having 21 modes,  all those shown in Table 1 except 12, 13, and 18.

       Although the sampling procedure was not performed  on a strict time
schedule, time for one run  was  generally 2 to 2. 5 hours, or 5 to 7 minutes
per mode.  To avoid excessive  analysis  time,  aldehydes and  light
hydrocarbons were measured only for idle, dynamic brake (where applicable),
and notches 2,  4,  6, and 8.   Even with the smaller number of samples taken,
the relationship between aldehydes and throttle notch was fairly well established,
as will be discussed later.

       Since it was relatively easy to measure fuel  consumption of the loco-
motive engines (using a weight-scale system with a  heat exchanger on the
return line) and quite difficult to measure airflow, it was decided that a
carbon balance technique would be used to calculate mass emissions from
                                 6

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 concentrations and fuel rates.  The formulas used to perform these cal-
 culations were:

        TC = total carbon = (1 x 10'4) (ppm C + ppm CO) + % CC>2

        HC (g/hr) = 0.0454 (ppm C) (FUEL lbm/hr) /TC

        CO (g/hr) = Kco (ppm CO) (FUEL lbm/hr) /TC

        N0x as N02 (g/hr) = KNQ  (ppm NOX) (FUEL Ib  /hr) /TC
                                •JC

        RCHO  as HCHO (g/hr) = KRCHO (ppm RCHO) (FUEL lbm/hr) /TC
 The "K" constants (except for Kpjc,  which is always 0.0454) depend some-
 what on the fuel hydrogen/carbon ratio, and since each locomotive used a
 somewhat different fuel,  each one required different constants.  The "K"
 values are given in Table 3, and complete fuel specifications are given in
 Appendix D.  The fuel H/C ratios also influenced the conversion of emis-
 sions measured on a dry basis back to a wet, or actual basis.  Once the
 mode-by-mode emissions had been determined on a g/hr basis,  brake
 specific values (g/bhp hr) were computed by dividing g/hr by observed
 power and fuel specific emissions (g/lbm fuel) were calculated by dividing
 g/hr by fuel rate (lbm/hr).
 TABLE 3.  VALUES OF CONSTANTS IN MASS EMISSIONS EQUATIONS

                        _ Locomotive Number
Constituent
SP-1311
0.0924
0.152
0.0990
SP-8447
0.0925
0. 152
0.0992
SP-8639
0.0918
0. 151
0.0984
CO
NOX as
RCHO as HCHO
       Thus far the analysis has only progressed to mode-by-mode con-
centration and mass emissions data, and in order to  compute composite
emissions,  operating cycles which lead to mode weighting factors must
be considered.  Manufacturers and industry groups have worked on the
duty cycle problem quite extensively, using on-board mode monitors, and
the cycles which seem to represent their latest results(4, 5, 6) are  sum-
marized in Table 4.  These cycles were adopted for use in this  project,
and composite specific emissions were calculated using these cycles as

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               TABLE 4.  LOCOMOTIVE DUTY CYCLES

                          Percent of Operating Time in Notch or Condition
 Notch or Condition   ATSF Switch(4)   EMD Line Haul*5)  *G. E.  Line Haul(6)

      Idle                 77                41                  43
  Dynamic Brake           --                 88
        1                  10                 3                   3
        2                   533
        3433
        4233
        5133
        6133
        7033
        8                   0                30                  28

 #This cycle is a compromise between one originally submitted by G. E.
 for use in smoke measurement studies and the EMD line-haul cycle.

 basis.  The particular relationships used to  calculate cycle composite
 emissions were:
              n
 cycle g/hr =  /     M^Wj;   Mi = individual mode emissions, g/hr,  W^
             i=l            time based weighting factor,  n = number of
                            modes (21  or 24)
                    >  MiWi

cycle g/bhp hr =  i=l - ; hpj = individual mode power, hp
                  n
                     n
                    £ MiWi
cycle g/lbm fuel =  1=1 - ; (fuel rate)^ = individual mode
                                                         fuel rate, lbm/hr
                        (fuel
It should be obvious that the very large amount of idle time included in the
switch cycle will contribute to causing brake specific and fuel specific
emissions from the switch  engine to be higher than those from the two
line haul engines.  The EMD and G. E. cycles are so similar that the use
of the other would have made only little difference in either case.  If more
                                  8

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 conclusive duty cycle data are developed at some later date for either or
 both of the types of locomotives tested, the individual mode mass emis-
 sions (g/hr) reported here can still be used to calculate cycle composites
 by deriving new weighting factors
      As noted in the Appendixes, a special approach was required for cal-
 culation of cycle composite aldehyde emissions,  because they were measured
 only at even-numbered notch positions (plus idle and dynamic brake).  The
 method employed was to give each even-numbered notch a new weight consisting
 of its normal weight plus that of the next lower notch.  This approach was
 completely arbitrary, but yielded useful results.

      In addition to the  steady- state emissions tests just described,  emis-
 sions were also measured during engine speed and load transients and
 during  start-up.  Analysis of transient emissions, however,  is limited to
 determining concentration as a function of time and relating changes to
 varying engine conditions. Since continuous sampling is necessary for
 meaningful results during transients,  the emissions measured are limited
 to hydrocarbons,  CO, CO2, NOX, and smoke  opacity.  The other emissions
 either did not have chart readouts or required a  constant condition for
 sampling.

      To  calculate mass emissions from locomotive-type engines used in
 marine applications, an attempt will be made to  re -weight individual mode
 emissions to simulate marine operation more closely.  This analysis will be
 deferred until the section containing estimation of emission factors and
 national impact since the method is essentially the same  as that described
 above and the mode weights will be based on information  presented in
 Section V.

 B.    Smoke Measurements

      Locomotive smoke measurements for this project were made with
 modified PHS full-flow opacity meters, utilizing  standard optics and
 electronics.   The sole modifications made were in the sizes of the rings
used to hold  the source and detector tubes, with a 20 inch diameter ring
being used for the switch engine (SP-1311) and a  40  inch diameter ring being
used for the  line haul locomotives (SP-8447 and SP-8639).  The smokemeter
 control unit and strip chart readout, which were  located inside the SEARCH
facility, are shown in Figure 5.   Figures  6, 7, and  8 show the smokemeters
mounted on units 1311,  8447, and 8639, respectively. Padding  similar to
that shown in Figure 8 was added under the support  legs of the optical unit
used on unit  8447 after Figure 7  was taken.  In Figure 7,  the  smokemeter
is shown in what was called "longitudinal" position,  or aligned with the
longer axis of the  stack, and the position shown in Figure 8 was called
"transverse".

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  Figure 5.  Smokemeter Control/Readout
  Unit Located Inside SEARCH Facility
  Figure 6.  Smokemeter 20-inch Support
  Ring and Optical Unit Mounted on
  Unit  1311
Figure 7.  Smokemeter 40-inch Support
Ring and Optical Unit Mounted on
Unit 8447
Figure 8.  Smokemeter 40-inch
Support Ring and Optical Unit Mounted
on Unit 8639
                                     10

-------
        Data on smoke opacity were taken with the optical unit in both
 transverse and longitudinal positions (where applicable),  and smoke was
 measured  continuously in all modes, just like gaseous emissions.  The
 rationale for using the PHS smokemeter is that it is supposed to see smoke
 as nearly as possible like the human eye,  and that it can follow smoke during
 transient conditions. It was found during calibration of the large-ring optical
 units that response was  equivalent to that of 10 inch ring optical units (standard
 for small diesel engine use).  Analysis  of the smoke results was straight-
 forward, and the results will be presented  later in the report.

 C.     Particulate Measurements

        Exhaust particulate from the locomotive engines was measured using
 an experimental dilution-type sampler developed  for mobile source usage.
 This system was used because no standard or accepted technique was available.
 The immediate problem encountered was inability to place the sampler close
 enough to the exhaust outlet to keep the  sample line short.  Particles tend
 to deposit themselves on the walls of sample lines,  making long lines extremely
 undesirable, so an alternative scheme was  sought.  The method used involved
 a compromise on the type of sampling used at the stack, in that a "split" of
 the exhaust was taken by drawing it into a 3 inch diameter duct, but not neces-
 sarily at the isokinetic rate.  This compromise permitted samples to be with-
 drawn from the 3 inch diameter duct at the  isokinetic rate without experimenting
 with flowrates, which made the  overall sampling time shorter but reduced the
 credibility  of the results.

        The particulate sampler is  shown in Figure 9 during operation on the
 first engine (SP-1311).   The 3 inch diameter duct which carried sample down
 from the engine exhaust  outlet appears just behind the sampler,  and it curves
 away toward the lower left of the Figure downstream of the sampling point.
 The duct terminated in the orifice, valved bypass, and blower shown in Figure
 10, and this control  system was used to  maintain  a constant mass flow in the
 duct.  The  "ram" effect of exhaust gases entering the 2 inch collectors some-
 times forced more gas into the duct than was desired, so in these modes the
 blower was removed, the open pipe end was capped, and the valve was used
 as a restrictor.  Separate 2 inch diameter collectors, which came together
 at the "Y" shown above the engine in Figure 11, were used for unit 1311 so
 both stacks could be  sampled.  The duct shown in Figure 12 was used on unit
 8639, and a very similar one was used for unit 8447 since  they both had  single
 stacks.

       Particulate samples from the locomotives  were acquired at idle, notch
 4, and notch 8,  each condition being repeated 4 times.  The abbreviated
 schedule  resulted from the desire  to tie up the  locomotives for as short a
 time as possible, and from analysis time considerations.  Previous experience
 with other diesel engines on the  subject contract had also shown that full load,
 half load, and no load conditions were generally sufficient  to characterize
particulate.  The results of the particulate measurements  will be summarized
 and discussed later in the report.
                                  11

-------
Figure 9.  Experimental Dilution-Type      Figure 10.  Control System Used to
Particulate Sampler Used for Locomotive   Maintain Flowrate in 3-inch Diameter
Tests                                      Sample Duct
 Figure 11. Arrangement of Sample
 Duct used on Unit  1311
Figure 12.  Arrangement of Sample
Duct used on Unit 8639 (same as used
on Unit 8447)
                                     12

-------
                    IV.  EMISSIONS TEST RESULTS

        The results of tests for smoke,  particulates, and light hydrocarbons
 are summarized in this section without being included in the Appendixes.
 Gaseous  emissions, on the other hand,  are given in detail in the Appendixes,
 along with operation and performance data on the locomotives.  These data are
 given in Appendix A for unit 1311 (EMD 12-56? Switch engine).  In Appendix B
 for unit 8447 (EMD 16-645E-3 line-haul engine), and in Appendix C for unit
 8639 (G.E.  7FDL16 line-haul engine).  The arrangement of the Appendix tables
 places the two pages of data from each run on facing pages for convenience,
 with ambient data,  operating data,  and concentrations on the even-numbered
 page,  and computed mass and specific emissions on the odd-numbered page.
 Note also that the Appendix data are considered to be intermediate results, and
 there  fare significant figures in excess  of the three considered reliable have
 been retained assuming that final results will be rounded off individually as they
 are obtained by averaging or further computation.

 A.     Gaseous  Emissions Results

        The discussion in this subsection is limited to steady-state runs under
 normal engine operating conditions. Thus transients and runs 4 and 5 on unit
 8639 are  specifically excluded, and will be handled in another report subsection.

        As already mentioned, all gaseous emissions except light hydrocarbons
 are given in terms of concentrations, and HC, CO, NOX,  and RCHO are given
 in terms  of g/hr, g/bhp hr, and g/lbm fuel by mode,  and in g/hr,  g/bhp hr,
 and g/lbm fuel on a cycle composite basis in the Appendixes. As a first sum-
 mary of these results, Table 5 gives average mass emissions by throttle set-
 ting for the three locomotives.  Perhaps a better way of examining these data
 is provided by Figures 13 through 16, which show the relationships between
 emission rates and  throttle  settings graphically.   The hydrocarbon emissions
 shown in  Figure  13  are perhaps a bit surprising,  with the 12-567 switch engine
 (unit 1311) being consistently higher than the larger 16-645E-3 (unit 8447).  It
 is assumed that the "hump" in the curve for the G. E.  engine (unit 8639) is due
 to mismatching of engine and turbocharger in the lower power range.  Figure 14
 shows that the smaller,  Roots-blown engine had much lower CO emissions over
 most of the power range than the two larger engines  did.  In addition,  the shape
 of the  curve for the smaller engine  is conspicuously different than those for the
 other two, due to the absence of a turbocharger.  The NOX emissions shown
 graphically in Figure 15 exhibit a strong,  consistent increase with power output,
 as expected.  The aldehyde emissions given in Figure 16 show consistent trends,
 and it appears that the 4-stroke engine (unit 8639) was considerably higher on
 aldehydes than the 2-stroke  engine of similar size and output (unit 8447).

       Table 6 provides a look at run-to-run variability in mass  emissions,
 brake specific emissions, and fuel specific emissions from the three engines,
as well as averages. Although the composite mass emissions from unit 1311
 (g/hr)  are much lower than those from the other engines,  the specific emis-
 sions from the switch engine are higher.  This effect occurs because the
 cycle used for unit 1311 contains a large percentage of idle time (77%),
                                  13

-------
             7000
                                   I     I      I     I      I     I
co

g
ri

bO


«T

o
    1
    W
    n
    o
    n)
    u
    O
    t-l
            6000  -
            5000
            4000
       3000
            2000
            1000
               0 L
                                                                    8639
                                                                    1311
                                                                   8447
                    Idle    1234    5     6    7     8



                           Throttle Position




     FIGURE 13. HYDROCARBON EMISSIONS (g/hr)  FROM THREE


LOCOMOTIVE DIESEL ENGINES AS A FUNCTION OF THROTTLE POSITION
                                  14

-------
          16,000
     
-------
        34,000  |-



        32,000




        30,000



        28,000




        26,000
   O


   3  24,000



   8  22,000
    
-------
              600
 O

 u

 (0

 JM
 o

 h
 0)
 PH
 (0
 a
     to
     C
     O
    •H
     CD
     CO
w

-------
      TABLE 5.  AVERAGE MASS EMISSIONS BY THROTTLE SETTING
 Condition

   Idle
 Dyn. Brake

    Nl
    N2
    N3
    N4
    N5
    N6
    N7
    N8
SP-1311 Mass Rates,
HC CO
387 160
452 273
638 341
984 481
1480 560
1830 702
2390 768
2960 1050
3980 1840
NOy
335
626
920
2, 000
3,220
4,950
6,720
8, 370
10, 200
g/hr
RCHO
48.
47.
72.
--
78.

148
SP-8639
Condition
Idle
Dyn. Brake
Nl
N2
N3
N4
N5
N6
N7
N8
HC
551
2400
588
1780
2120
2130
2600
4080
5740
6630
,2
6
9

7


Mass
CO

2,

6,
11,
14,
13,
12,
9,
9,
828
050
991
590
700
400
800
600
310
630
SP-8447 Mass Rates,
HC
254
377
225
322
493
610
766
1070
1520
2010
Rates,
NOY
1, 030
5,200
3,390
10, 300
12, 600
16, 000
17,500
22,900
29,400
33, 200
CO
523
732
293
386
9,490
12,200
15,700
16,000
10, 200
9. 740
g/hr
NOX
978
2, 180
1,870
4,860
8,520
10,800
13, 000
16,200
21,600
25. 500

g/hr
RCHO
76.8
130
75.9
106
_ _
152
_ _
224

RCHO
67.
158
_ _
74.
--
167
--
314
--
538
5


2
















during which mass emissions are low and specific emissions are high.  As
could have been predicted from Figure 13,  composite hydrocarbon emissions
from unit 8639 were considerably higher  than from unit 8447, and unit 8639
also emitted somewhat more NOX and aldehydes.

      Light hydrocarbon emissions from  these locomotive engines were
measured by the previously-described gas chromatographic method,  which
is reliable for  7 compounds ranging from methane through butane.  No
propane or butane was found in any of the samples, however, and methane
was the only compound found in the exhausts of all three locomotives.
Average concentrations of light hydrocarbons are given in Table 7, and all
of them are extremely low.   Those compounds not listed averaged less than
0. 1 ppm in all  modes, which is  considered to be the limit of readability  of
the present technique.  In most  cases the light hydrocarbons (combustion
                                18

-------
TABLE 6.  LOCOMOTIVE CYCLE COMPOSITE EMISSIONS RESULTS
                  Mass, g/hr
          Brake Specific,  g/bhp hr
Unit Run
1311 1
3
4
Average
8447 1
2
3
4
Average
8639 1
2
3
Average





HC
550
423
485
486
817
872
968
897
888
2880
2740
2950
2860

Unit
1311


CO
277
160
201
213
4860
4980
5090
5580
5120
5750
4940
5200
5300

Run
1
3
4
Average




8447



1
2
3
4
Average




8639


Ave
1
2
3
rage
NOX
636
616
630
627
10, 600
10, 300
10,500
10,600
10,500
13,900
13,300
13,400
13,500
Fuel
HC
13.6
10.8
12.4
12.3
1.66
1.78
1.97
1.83
1.81
6.38
6.06
6.50
6.31
RCHO
63.
42.
44.
50.
128
140
148
118
134
246
295
165
235
4
7
4
2









Specific,
CO
6.
4.
5.
5.
9.
10.
10.
11.
10.
12.
10.
11.
11.
85
07
14
35
90
2
4
4
5
7
9
5
7
HC
10.2
7.82
8.58
8.87
0.635
0.691
0.759
0.717
0.700
2.23
2.12
2.23
2.19
CO
5. 15
2.95
3.56
3.89
3. 78
3.94
3.99
4.45
4.04
4.45
3.83
3.95
4.08
NOX
11.
11.
11.
11.
8.
8.
8.
8.
8.
10.
10.
10.
10.
8
4
1
4
25
18
25
48
29
7
3
1
4
RCHO
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
18
79
79
92
107
111
116
094
107
190
228
125
181
g/lbm fuel
NOV
15.7
15.7
16.1
15.8
21.6
21.1
21.4
21.7
21.4
30.7
29.4
29.5
29.9
RCHO
1.57
1.09
1.14
1.27
0.264
0.286
0.302
0.241
0.273
0.554
0.653
0.364
0.524
























































               Duty Cycles Used:
1311 - Santa Fe Switch
8447 - EMD Line-Haul
8639 - G.E. Line-Haul
                            19

-------
   TABLE 7.  LOCOMOTIVE LIGHT HYDROCARBON DATA SUMMARY
                           Concentrations in ppm
Condition

  Idle
Dyn. Brake

   N2
   N4
   N6
   N8
Unit 1311
C2H4
0.2
	
0.1
0.4
0.8
5.2
Unit 8447
CH4
2.2
1.8
1. 7
1.8
1.4
1.4
C2H4
1.3
0.9
0.5
2.6
3.0
3.7
CH4
8.0
7.6
24.0
15.0
7.8
7.1
C2H6
0.0
0.1
0.9
0.7
0.3
0.1
Unit 8639
C2H4
6.6
7.8
18.2
23.9
21.2
14. 0
C2H2
1.3
3.2
5.0
3.6
2.2
1.4
C3H6
0.0
0.1
3.6
4.4
3.5
3.0
products) did not constitute large fractions of the total hydrocarbons.

B.    Smoke Results

      Smoke data were recorded during steady-state conditions in terms of
percent opacity using two modified smokemeters based on PHS optics,  as
explained in subsection III. B.   These data were  taken concurrently with
gasoline emissions data, and the  averages are given in Table 8. For unit
1311, which had two stacks, two complete runs were made on each stack
with virtually identical results  from the two stacks.  All the results were
averaged, so the idle numbers  are averages of 24 data points and the
remaining numbers are averages of 8 data points.

  TABLE 8. SUMMARY OF LOCOMOTIVE STEADY-STATE SMOKE DATA
Condition

  Idle
Dyn. Brake

   Nl
   N2
   N3
   N4
   N5
   N6
   N7
   N8
Average %
 Opacity
Unit 1311

   1.5
   2.8
   3.2
   2.7
   2.0
   2.0
   1.9
   2.2
   2.8
                             Average % Opacity
                                Unit 8447
                               Average % Opacity
                                   Unit 8639
  .	Unit 8447	  	unit OQJ?	
Transverse  Longitudinal  Transverse  Longitudinal
    1. 7
    2.0

    2.1
    4.5
   11.2
   11.1
   12.1
    9.1
    5.5
    6.4
 2.2
 3.8

 2.3
 5.2
22.8
22.0
21.4
18.4
11.2
10.0
 3.7
 4.0

 4.9
14.8
15.1
12.1
 9.8
 6.4
 4.6
 4.8
 6.7
 8.2

 8.9
28.0
29.2
25.8
19.5
13.0
 9.0
 9.2
                                20

-------
 For unit 8447,  two runs were made in the transverse position and two in the
 longitudinal position (transverse is the short path across the stack), so idle
 numbers are averages of 12 points and the others are averages of 4 points.
 Two runs (or 12 data points at idle, and 4 data points elsewhere) are
 represented by the numbers for unit 8639  in the transverse position, and
 one run (or 6 idle  data points,  and 2 data points on other conditions) by the
 numbers for the longitudinal position.  In  the case of unit 1311,  the nominal
 optical path length through the smoke plume was 10 inches,  and identical for
 all runs.  For unit 8447,  the exhaust outlet was 11.5 inches (transverse) by
 29. 75  inches (longitudinal), and the corresponding dimensions for the exhaust
 outlet  on unit 8639 were 11.5 inches and 26.5 inches, respectively.  More so
 for unit 8447 than  for the  other two locomotives, however,  the exhaust gases
 were underexpanded at the outlet  for the  several highest notches,leading  to
 a rapid divergence upon entering the atmosphere.  This divergence was an
 important enough factor,  at least in the case of unit 8447 at higher power
 conditions, to cause variation in the optical path length through the smoke
 plume as conditions varied, making the length an undetermined variable.
 This divergence is one reason why no mathematical correlation of transverse
 and longitudinal results has been attempted,  and another is that the geometric
 characteristics of the smoke plume change quite rapidly after entering the
 atmosphere, making the perception of the  plume density more equal in all
 directions.  Further perceptual effects occur,  of course, with wind or motion
 of the  locomotive.   In order to make path lengths more nearly equal for test
 purposes, the installation of a standardized stack was considered, but time
 and financial constraints did not permit this  extension beyond the intended
 scope  of work.  Such a duct might be 27 to 30 inches in diameter and circular
 at its outlet, shaped enough at its base to conform somewhat to the standard
 stack and prevent leaks, and long enough to produce a relatively uniform flow
 at its outlet (perhaps 36 to 48 inches). Another alternative for possible future
 use would be to devise an  equitable,  accurate,  particulate sampling procedure,
 and thereby eliminate stack geometry as a factor.

 C.    Particulate Results

      As  mentioned previously,  results of the locomotive particulate measure-
 ments  were less than satisfactory due to the sampling method which had to be
 employed. The experimental method was an adaptation of that developed for
general use in the  characterization work,  and was used because no standard or
 accepted technique was available.  To explain the situation  more fully, the ex-
 perimental sampler which has been used on this project weighs several hundred
pounds and is physically quite large (ref.  Figure 9)   so it was impractical to
 lift it'to the top of  each locomotive to keep the sample line short.  It was like-
wise impractical to use  a  long, constant-diameter sample line (3/8 inch O. D. )
due to  particle deposition  on the tube walls.  A good solution would have been
to withdraw a "split" of the exhaust isokinetically into a fairly large tube (the
larger the tube, the less wall area per unit volume),  and then to sample
isokinetically from that  tube via a  short sample line at ground level.  The
reason this procedure was not followed is that each condition would have
required:  (1) an accurate  exhaust velocity measurement; (2) adjustment of

                                   21

-------
blower controls to achieve an isokinetic sample rate,  taking temperature
changes,  etc. , into account;  and (3) calculation of sampling rate for the
particulate system based on the conditions in the larger tube.  Since the
particulate measurements had to be taken separately from the other measure-
ments, the additional time and personnel required to set the sampling con-
ditions simply could not be justified.  The compromise which was employed
was to maintain a constant mass flow rate in the 3 inch diameter duct,  and
sample from it into the sampler itself at the isokinetic rate.  This technique
required only the setting of one control  on the 3 inch duct (the bypass valve)
and allowed the use of the same sample rate for all  runs.

      The  problem with the system as used  was that sampling into the 3 inch
duct was subisokinetic at higher power  settings to such an extent that con-
siderably more heavy particles were sampled than the number representative of
the exhaust stream.  This effect was most pronounced for unit 1311, which had
relatively  large cinders in its exhaust,  especially at high power.  It could be
speculated that the cinders were agglomerations of carbon which had built up on
the inside  surfaces of the exhaust system, and that they were dislodged while
the engine ran at high power.  Such particles could build up over a period of
time if the operational history of this particular locomotive did not include
much running at "notch 8". To further  support this  theory, no cinders were
observed in the exhausts of the other two engines (which very probably operated
at high power settings much more than the switch engine did) and examination
of the filters used for particulate sampling showed no  large cinder-type particles.
These observations seem to correlate with the test results summarized in
Table 9, which show that the  measured  particulate concentrations tended to

TABLE 9.   SUMMARY OF LOCOMOTIVE PARTICULATE EMISSIONS DATA

NOTE: THESE PARTICULATE DATA ARE NOT CONSIDERED RELIABLE
Unit
No.

1311
8447
8639
Condition

  Idle
  N4
  N8

  Idle
Dyn.  Brake
  N4
  N8

  Idle
Dyn.  Brake
  N4
  N8
FOR DOCUMENTATION PURPOSES
Individual Results,
mg/SCF Exhaust
0.308
3.42
21.6
1.62
2.53
2.59
2.80
1.12
4.05
1.45
3.27
0.412
2. 78
25. 1
2.17
0.823
2.50
2.22
1.31
3.71
2. 77
2.69
0.519
1.69
18.9
1.35
1.40
0.862
1.65
1.34
2.74
3.15
2.81

1.69
12.7
1.75


2.75
_ _
2.13
2.37
2.44
ONLY
Avg.
Result,
mg/SCF
0.413
2.40
19.6
1.72
1.58
1.98
2.36
1.26
3.16
2.44
2.80
Avg. %
Opacity
1.5
2. 0
2.8
1.7
2.0
11.1
6.4
3.7
4.0
12.1
4.8
                                22

-------
 increase with exhaust velocity (or exhaust mass flow) regardless of the
 trend in smoke density (or opacity).  It should also be recognized that some
 particulates measured on the filter (taken at about 90° F) may have been
 gases as they left the stack,  tending to further decrease the correlation
 between particulate weight and smoke density.

        Due to the reservations expressed above about the data acquired on
 particulates during this program, the subject results will not be used to
 estimate emission factors or national impact for locomotives.  While the
 attempt to  obtain reliable data within the time and financial constraints of
 the program failed, the efforts and experience should be valuable to those
 attempting further such work.  It may be necessary to standardize the type
 of exhaust  stack used for particulate sampling in somewhat the same manner
 as the standardization suggested  for smoke measurements, just to get a flow
 of exhaust which is acceptably directional for sampling.   In any case, the
 need for precisely isokinetic sampling has been demonstrated quite vividly,
 along with the need for development of suitable instrumentation and procedures.

 D.   Special Test Results

      Runs 4 and  5 on unit 8639,  the 16-cylinder G.  E. locomotive, type
 U-33 C, were  designated "special runs" because some of the speeds at
 which the engine ran were altered for test purposes.  These speed changes
 were made in response to a suggestion by G. E. technical personnel to
 operators in California that smoke might be reduced if the engine speeds
 were changed in several notch positions.  The two special runs were  con-
 ducted immediately after run 3, on the same day,  to avoid keeping the
 locomotive out of service an extra day.

      The altered engine operation schedule was designed to retain approxi-
 mately the same power output in each notch as with the standard schedule,
 but to run notches  1, 2,  and 3 at the standard speed for notch 5 (783 rpm)
 and notches 4 through 8  at the standard speed for notch 8 (1077 rpm).   The
 effect of these changes was to leave idle,  dynamic brake, and notch 8 un-
 changed, and raise engine speeds in notches 1 through 7.  The increased
 engine speeds resulted in small increases in fuel usage proportional to the
 increases in gross horsepower.

      To examine the effectiveness of the higher engine speeds as a control
 measure for unit 8639, Table 10 has been prepared to compare mass  emis-
 sions by throttle setting for the standard and revised schedules.  A cursory
 examination of Table 10 shows that the revised conditions (notches 1-7)
 tended to produce  higher hydrocarbons, slightly higher NOX and aldehydes,
and much lower CO than the standard conditions. The overall effects of the
 revised conditions  on gaseous  emissions can be  seen in Table 11,  and after
weighting of the modes it appears  that for the experimental runs hydrocarbons,
NO  and aldehydes were about the same as for the  standard runs and GO was
   J±
                                 23

-------
      TABLE 10.  AVERAGE MASS EMISSIONS FROM A G. E. 7FDL16
         LOCOMOTIVE ENGINE USING STANDARD AND REVISED
                            ENGINE SPEEDS
               Emissions at Standard Speeds
                         (g/hr)
 Condition

   Idle*
 Dyn.  Brake*  2400
    Nl
    N2
    N3
    N4
    N5
    N6
    N7
    N8*
HC
551
2400
CO
828
2,050
NOy
1,030
5, 200
RCHO
67.5
158
         Emissions at Revised Speeds
                   (g/hr)
588
1780
2120
2130
2600
4080
5740
6630
991
6,590
11, 700
14, 400
13, 800
12, 600
9,310
9,630
3,390
10,300
12,600
16,000
17,500
22,900
29,400
33,200
 74.2
167
314
538
HC
517
2280
1120
2300
2410
3750
4400
5730
6690
6650
CO
650
1780
932
2480
4300
3240
3870
5260
6200
8620
NOX
888
4,800
4, 100
10,500
12,800
16,700
20,500
24,400
28,300
32,000
RCHO
53.4
125

109
--
202
--
319
--
466
         * Condition identical for all runs.
 significantly lower than for the standard runs (changes in HC, NOX,
 aldehydes were measurable,  but hardly significant).
                           and
        Since the experimental runs were intended to investigate a smoke re-
 duction technique,  smoke was measured by a modified PHS opacity meter
 with the results presented in Table 12.  The engine speed revisions did seem
 to reduce smoke quite significantly in notches 1-7, although the engine smoked
 slightly less during runs 4 and 5 even in conditions which were not revised.
 The most dramatic reductions in smoke were for notches 2 through 6, the
 same notches in which large reductions in CO were in evidence.

        No particulate or light hydrocarbon measurements were made during
 the two runs using the experimental speeds, primarily to keep the overall
 time requirement reasonable. Although the speed changes had to be made
'manually for these tests, the regular engine speed control system could be
 modified so that positioning the throttle control in the normal way would
 automatically set the ending speed at the new value.

 E.  Emissions During Transients

       Emissions were measured during changing speed and load conditions
 on each engine, generally prior to  each day's operation.  The  continuous
 measurements made during these transients included  hydrocarbons, CO, CO2,
                                24

-------
 NOX by chemiluminescence, and smoke opacity.  The reason for making
 these measurements was primarily to determine whether or not transient
 emissions were sufficiently different than steady-state emissions so as to
 change the overall emissions picture significantly.  The types of conditions

    TABLE 11.  CYCLE COMPOSITE EMISSIONS FROM A G. E. 7FDL16
 LOCOMOTIVE ENGINE USING STANDARD AND REVISED ENGINE SPEEDS
   Run
     4
     5

Average
Revised
Runs 4 & 5
                     Mass,  g/hr
 HC
CO
NO,
3160   3610   13,500
2960   3640   13,000
3060   3620   13,200
RCHO
                 211
                 211
 Brake Specific,  g/bhp hr
HC    CO     NOX    RCHO
                 2.33
                 2.19
               2.66
               2.69
              9.96
              9.59
0.156
                 2.26   2.68    9.78   0.156
Average
Standard
Runs 1-3
2860   5300   13,500
                 235
                 2.19   4.08  10.4
                              0.181
                              Fuel Specific,  g/lbm fuel
                Run
                 4
                 5

              Average
              Revised
              Runs 4 & 5

              Average
              Standard
              Runs 1-3
              HC

             6.69
             6.38
             6.54
             6.31
               CO

               7.66
               7.83
                NO,
                -««w*«^

                28.6
                27.9
              RCHO
              0.447
               7.74    28.2  0.447
              11.7
                29.9    0.524
'investigated were engine acceleration through the notches with load, decel-
 eration with load, and cold starts.

        Emissions during transients were taken to be of no special significance
 if concentrations changed smoothly between initial and final steady-state values,
 a result termed "smooth transition".  Without exception, such changes were
 the case for all decelerations of the engines from notch 8 to idle.  Some cold
 starts were run also, with no significant excursions of gaseous emissions
 due to engine  start-up,  very little drift in CO, CO2, or NOX, and about 15%
                               25

-------
 downward drift in hydrocarbons during a 15-minute idle following startup.
 One significant smoke puff was observed at engine startup,  ranging up to 95%
 peak opacity, with a duration of about 2 seconds.

        The accelerations from idle to notch 8 produced most of the excursions
 from smooth transitions which were observed, but the durations of peaks


  TABLE 12.  SMOKE EMISSIONS FROM A G. E.  7FDL16 LOCOMOTIVE
      ENGINE USING STANDARD AND REVISED  ENGINE SPEEDS

                    % Opacity, Standard            % Opacity,  Revised
                 	Engine Speeds	      	Engine Speeds	
 Condition        Transverse   Longitudinal     Transverse  Longitudinal

  Idle*              3.7           6.7             2.7         5.8
 Dyn.  Brake*         4.0           8.2             2.6         5.0

    Nl      .         4.9           8.9             3.0         5.0
    N2             14.8           28.0             6.8        12.8
    N3             15.1           29.2             7.1        14.0
    N4             12.1           25.8             3.5         7.0
    N5              9.8           19.5             3.2         6.8
    N6               6.4           13.0             3.0         7.2
    N7               4.6           9.0             3.0         7.0
    N8*             4.8           9.2             4.0         8.5

    * "revised1'' engine speeds same as standard

 were very short in most cases.   Table 13 summarizes  the results of the
 acceleration tests in terms of concentrations and peak durations.  The
 durations were taken to be the time  during which the concentrations (or
 opacities) were 10% or more over the final steady-state values,  and
 maximum values are expressed as peak value divided by final steady-state
 value.  No significant excursions were observed for either CO2 or NOX,  so
 they were not included in the table.  For unit 1311, the peaks occurred
 within a few seconds after initial throttle movement, and only a single peak
.occurred for each constituent. The picture was a bit more  complex for
 unit 8447, with the first set of peaks (CO and smoke) being observed going
 into notch 3, and with subsequent smaller peaks going into each notch through
 8.  The peaks observed for unit 8639 were of much longer duration, as
 shown in Table 13, and they occurred  late in the accelerations  (beginning
 around notches 6 to 8).

        The values given in  Table 13 are representative of 6 to  10 repetitions
 made with each locomotive, as are the comments  made on decelerations.
 The charts were  examined carefully, and 2 runs were picked for analysis to

                                26

-------
  minimize computation time.  The analysis of transient emissions shows
  that they are probably not important in the overall locomotive emissions
  picture due to the short time in which emissions are outside those
  expected from steady-state operation. At this point we have no rigorous
  way of determining mass emissions during transients, so these results
  will not be used in estimating emission factors and national impact.
TABLE 13.  LOCOMOTIVE EMISSIONS DURING ACCELERATION TRANSIENTS
           Peak Value -r* Final Value
                                        Peak Duration,  sec.
  Unit

  1311
  8447
  8639
HC
CO

35
 4
 5
Smoke

   10
   10
   10
HC
CO

 7
 4
20
Smoke

    5
    4
   16
                                  27

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      V.  ESTIMATION OF EMISSION FACTORS AND NATIONAL IMPACT

       Emission factors for locomotives are to be estimated based primarily
  on the tests conducted as part of the subject program,  although results of
  other studies will be referenced and taken into consideration.  If it is shown
  later that the engines tested were not representative, or if additional, more
  comprehensive data become available, the factors and impact estimates can
  be updated using the  subject techniques as a guide.  Factors will be estimated
  on both brake specific and fuel specific bases,  and parallel  impact calculations
  will be made using independent locomotive utilization and fuel usage data.

       Emission factors for the marine counterparts of locomotive  diesel
  engines will be estimated from much less comprehensive information, and
  will be treated separately.

  A.   Emission Factors and Emission Estimates for Locomotive Diesel Engines

        As a prerequisite to determining emission factors, the composition
 of the locomotive population must be known so the proper weight can be
 given to each size category and each type of operation.   The most recent
 population data available are as of January 1, 1972/  and Table 14 shows
 these data in their most useful form.  These figures are intended to be for
 the 48 states only, but slight errors may have occurred in separating U. S.
 from non-U. S.  railroads.

        The first use of the data in Table 14 will be to calculate percentages
 of total yearly railroad diesel fuel usage which  can be attributed to engines
 represented by each of those tested under this project.   These calculations
 will be used along with national fuel consumption figures **'  and fuel specific
 emissions data from Table 6 to calculate emission factors and impact. Pur-
 suing the fuel-based calculations, available data^10' indicate that 25.9% of
 active locomotives were engaged in yard service in 1971, and that 70. 0%
 were in freight service and 4. 1% were in passenger service.  Since it is not
 known just which particular locomotives were in yard service (6, 951 total),
 the assumption will be made that they were the 6, 951  smallest locomotives
 listed in Table 14.  In terms of a cut-off point, this assumption means that
 1437  of the 1500 hp units and all those  smaller than 1500 hp are assumed to
 be in yard service.  If a second assumption is made to the effect that the
 average power of  the "under 1000 hp" units is 750  hp, the total horsepower
 in yard service comes  out to  7, 032, 150 (or 1012 hp per unit) and that in road
 service to 45, 295, 750 (or 2278 hp per unit).

       The next item is determination of load factors for road and yard
 operations, defined as average power produced during operation divided by
 available power.  Based on power measurements taken during this project,
 the  load factor for the EMD line-haul cycle is 0. 397,  that for the G. E. line -
 haul cycle is 0. 365, and that for the switcher  cycle is 0.0507.  Another
necessary item of information is operating time per year for each category

                                  28

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                TABLE 14.  U. S. LOCOMOTIVE POPULATION
                      BY POWER CLASS AND BUILDER
Horsepower
       Builder
Class
5000
3600
3300
3000
2800
2750
2700
2500
2400
2350
2300
2250
2000
1850
1800
1750
1600
1500
1400
1350
1300
1200
1000
Under 1000
EMD
45
1359
1
2211
-
_
_
1555
306
_
77
1217
1413
138
329
3898
22
4471
_
39
2
1639
985
720
Alco
-
31
-
77
_
115
18
76
168
_
-
_
142
_
534
-
712
152
4
_
-
38
1136
223
G.E.
66
97
373
435
236
_
_
549
-
_
_
155
_
_
9
_
_
-
_
-
-
_
-
67
GMD
_
-
-
3
_
_
_
-
-
-
-
_

_

2
-
21
-
-
-
1
-
23
MLW
_
-
_
16
_
_
_
_
-
_
-
_
-
-
29
-
25
-
-
-
-
-
3
-
BLH
-
-
-
_
-
-
-
-
-
-
-
-
13
-
2
2
77
32
-
-
'
233
163
25
FM
-
-
-
_
_
_
_
_
26
8
-
-
-
_
-
-
63
2
-
-
-
153
50
-
Others
_
-
_
_
_
_
_
-
-
-
-
-
-
-
-
-
2
14
-
-
-
-
2
8
Totals
111
1487
374
2742
236
115
18
2180
500
8
77
1372
1568
138
903
3902
901
4692
4
39
2
2064
2339
1066
Totals    20,427     3426   1987      50     73      547   302    *27 *26,839

* Includes one engine with no power class given

          Abbreviation                      Builder Name
              EMD
              G.E.
              GMD
              MLW
              BLH
              FM
Electro-Motive Division, General Motors Corp.
General Electric
Diesel Division, General Motors of Canada
MLW Industries,  Canada
Baldwin-Lima-Hamilton
Fair banks-Morse
                                    29

-------
 of application, and 1971 statistics(10) also yield this information.  For road
 freight and passenger service combined, some 64.4 x 10& locomotive hours
 were used, and for all switching operations about 39. 3 x 106 locomotive
 hours were used. The foregoing figures yield about 2015 x  10^ hp hours  for
 switching operation and about 57,400 x 10& hp hours for road operation
 during 1971.  Converted to percentages,  some 96.6% of locomotive hp hours
 were used in road service, leaving 3. 39% for  switching operations.  As-
 suming that fuel usage is directly proportional to work produced, the
 estimate is made that these latter percentages also represent fuel consumed
 in road and switching  operations,  respectively.  Since no data are presently
 available on load factors for passenger service, they are being assumed  as
 equal to those for freight service.

        The latest available fuel consumption figure for railroad diesels is
 for 1970^1), and it totals  3804 x 106 gallons,  or approximately 27, 100 x
 lo6lbm (at 7. 12 lbm gal).   This figure when divided by the total hp hours
 above,  yields an average brake specific fuel consumption for all railroad
 operations of 0.456 lbm/bhp hr, which sounds somewhat high, but may be
 reasonable in view of the relatively large fractions of time spent at idle.
Another error may be inherent in this BSFC calculation because undoubtedly
 some of the diesel fuel used by railroads is used in equipment other than
locomotives.  In order to calculate factors and impact as accurately as pos-
 sible,  the switch engine population will be considered to be 75% 2-stroke
 engines and 25% 4-stroke engines  (on a horsepower basis).   These smaller
 2-stroke engines are probably characterized adequately by unit 1311,  but
the 4-strokes are not yet represented.  To overcome this problem, mode
emissions from runs  1 through 3 on unit 8639 have been re-weighted
according to the ATSF switcher cycle, with the results shown in Table 15.
 Table  15 also contains emissions from unit 1311,  reweighted according to
the EMD line-haul cycle (except that dynamic brake was omitted and the
other mode weights were increased by a factor of 100 -j-  92 = 1. 087) for use

             TABLE  15.  SUMMARY OF REWEIGHTED
              EMISSIONS  FROM UNITS 1311  AND 8639
Unit   Cycle

1311   EMD
      . line-
       haul
8639   ATSF
       switch
Contaminant   Mass,  g/hr
             Brake Specific  Fuel Specific
               g/bhp hr      g/lbm fuel
   HC
   CO
   NOX
   RCHO

   HC
   CO
   NOX
   RCHO
1820.
 809.
4360.
  44.1

 766.
2000.
2560.
  79.4
 3.95
 1.76
 9.45
 0.096

 4.96
12.9
16.6
 0.514
 9.43
 4.20
22.6
 0.229

 9.33
24.3
31.2
 0.967
                                 30

-------
 in estimating emissions from line-haul 2-stroke engines which are Roots-
 blown rather than turbocharged.  The estimated breakdown of locomotives
 used in road service is 37% Roots-blown 2-strokes, 37% turbocharged 2-
 strokes, and 26% 4-strokes, on a horsepower basis.

        Five engine categories have been defined in the process of arriving
 at a calculation technique for  mass emissions based on fuel usage, and each
 of the five is represented by emission factors shown in either Table 6 or
 Table 15.  The total weight for each  category is the fraction  of all fuel used
 by engines  in that category, and these weights multiplied by the proper emis-
 sion factors yield quantities which sum to composite emission factors for
 the whole locomotive population.  A summary of the results of this analysis
 is  shown in Table 16,  and it is a  simple matter  to progress to total mass
 emissions (or impact)  by multiplying  the composite factors by total fuel
 usage.   This step will  come later in the report.   Mass emissions for each
 engine  category can be determined by multiplying the category factors by
 total fuel usage.

        To calculate emission  factors  on a brake specific basis, the analysis
 is the  same as the foregoing down to the point where fractions of total horse-
 power hours produced by engines in each category were taken to be equal to
 fractions of total fuel used.  In the brake specific case,  this last assumption
 is not necessary,  and Table 17 shows the results of brake  specific  emissions
 factor calculations.  To determine impact from  the brake specific data,  the
 factors can be multiplied by the total work (horsepower hours) produced per
 year, which was derived earlier.

        Emissions of sulfur oxides have not been mentioned as yet because
 SOX was not measured,  but sulfur oxides have been calculated on a basis
 of 0. 35% by weight fuel sulfur  content, assuming that all the sulfur is
 oxidized to  SC>2.  Particulate emissions have been discussed earlier, but
 the particulate results  generated  by this study are not  considered accurate
 enough  for use in estimating factors and impact,  so no improvement can be
 made on the latest EPA figures.   Impact estimates based on the above
 procedures and factors are given in Table 18, and these estimates are com-
 pared with recent EPA nationwide estimates in Table 19. With the  exception
 of the SO  estimate, which was calculated from  fuel usage  only, the more
 accurate factors and estimates are probably those derived  on  a brake
 specific basis.  The reason for a degree of lack  of confidence in the fuel-
 based numbers is  simply that the overall fuel consumption  figure has  a lot
 of room for error, since in some cases accurate data may not be kept on
 how much fuel is used in locomotives  and how much in other engines.

        One positive feature of the fuel-based calculations,  however, is
 that they can be updated very quickly if it is assumed that the  locomotive
population and its  operation do not change greatly (probably a  valid  assump-
 tion over 5 years or so).   The  calculations  based on work output (brake
 specific) are not difficult,  either, if information on operating  hours per

                                 31

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                    TABLE 16.  SUMMARY  OF FUEL-BASED EMISSION FACTOR CALCULATIONS
      Engine Category

      2-s (Blown) Switch
      4-s Switch
      2-s (Blown) Road
      2-s (T. C.) Road
      4-s Road
Fraction
of Total
Fuel Used
0.0254
0.00848
0.3575
0.3575
0.2512
Emission Factors for
Category (g/lbm fuel)
HC
12.3
9.33
9.43
1.80
6.31
CO
5.35
24.3
4.20
10.4
11.7
NOX
15.8
31.2
22.6
21.2
29.9
RCHO
1.27
0.967
0.229
0.271
0.524
Weighted Factors for
Category (g/lbm fuel)
HC
0. 312
0.0791
3.37
0.644
1.59
CO
0. 136
0.206
1.50
3.72
2.94
NO*
0.401
0.265
8.08
7.58
7.51
RCHO
0.0323
0.00820
0.0819
0.0969
0. 132
CO
y  = composite factor,  g/lbm fuel

    composite factor,  lbm/1000 gal fuel
                                                                        6.00
                                                                       94.2
         8.50   23.84    0.351
       133.
      374.
        5.51
                  TABLE 17.  SUMMARY OF BRAKE SPECIFIC EMISSION FACTOR CALCULATIONS
      Engine Category

      2-s (Blown) Switch
      4-s Switch
      2-s (Blown) Road
      2-s (T. C. ) Road
      4-s Road
                      E
Fraction
of Total
hp hours
0.0254
0.00848
0. 3575
0. 3575
0.2512
Emission Factors for
Category, g/bhp hr
HC
8.
4.
3.
0.
2.
87
96
95
695
19
CO
3.89
12.9
1.76
4.00
4.08
NOX
11.4
16.6
9.45
8.22
10.4
RCHO
0.92
0.514
0.096
0. 104
0. 181
Weighted Factors for
Category, g/bhp hr
HC
0.
0.
1.
0.
0.
225
0421
41
248
550
CO NOY
0.
0.
0.
1.
1.
0988
109
629
43
02
0.290
0. 141
3. 38
2.94
2.61
RCHO
0.023
0.00436
0.034
0.0372
0.0455
     = composite factor,  g/bhp hr
2.48
3.29
9.36
0. 144

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             TABLE 18.  NATIONAL IMPACT ESTIMATES
                    FOR LOCOMOTIVE EMISSIONS
        Contaminant

          HC
          CO
          NOX
          RCHO
          SOX
          Particulate
       Total Estimated Emissions, 10" tons per year
       Fuel Specific Basis     Brake Specific Basis
              0. 177
              0.247
              0.698
              0.010
              0.0947
                 *
                        0. 162
                        0.215
                        0.613
                        0.00943
                        0.0947
        *EPA figure not improved upon
 TABLE 19.  COMPARISON OF SUBJECT NATIONAL IMPACT ESTIMATES
     WITH EPA NATIONWIDE AIR POLLUTANT INVENTORY DATA
Contaminant

    HC
    CO
    NOX
  RCHO
    SOX
Particulate
                  EPA Inventory Data,
                      106 tons/yr(17)
                       1970,
 All
Sources

   34.7
 147.
   22.7

   33.9
   25.4
Mobile
Sources

   19.5
  111.
   11.7

   0.986
   0.655
Railroads

 0.093
 0. 100
 0. 142

 0. 124
 0.047
Subject Estimates of % of
  All          Mobile
 Sources       Sources
  0.467
  0. 146
  2.70

  0.279
 *0.185
 0.831
 0. 194
 5.24

 9.60
*7. 18
*EPA figure
year continues to be available.  The only major change in railroad operation
occurring at the present time is the institution of Amtrak.  Separate statistics
on Amtrak may be available later,  and they could be used to supplement infor-
mation available from AAR and other sources.  As was mentioned earlier,
some 96. 6% of locomotive horsepower hours are produced in road service,
and it seems logical that a similar percentage of total locomotive emis-
sions (at least 90 to 95%)  could be classed as  "rural" rather than "urban
or suburban".  Without doing an analysis of commercial traffic which is
really outside the intent of the  current project,  it can only be assumed  that
most locomotive pollutants are emitted between the  larger areas, .or in
"commercial corridors", if that is an acceptable term.   These emissions
should have little connection with peak traffic hours, season of year, or
other factors normally associated with detailed  impact analysis.
                                 33

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         Up to this point, the results of other studies of locomotive emissions^'
 5, 12,  13, 14) have not been mentioned  specifically.  All the information in
 these references stems from either in-house research at EMD or G. E. or
 the study funded jointly by AAR, Santa Fe, Southern Pacific, and Union
 Pacific (called the  "Richmond" study).  In general terms, the emissions
 results generated under this program agree fairly well with the other pub-
 lished information,  although the NOX emissions observed during the San
 Antonio tests are consistently somewhat lower  than most of the  EMD and
 Richmond results.   The NOX results used in calculating impact  for this
 study were those generated by the chemiluminescent analyzer,  which
 generally gave somewhat lower results than the NDIR NO analyzer, which
 can be verified by examining the data in Appendixes A through C.  The use
 of the chemilumine scent results is a best  judgement decision based on ex-
 perience using both types of analyzers in parallel on a variety of engines.

 B.      Emission Factors for the Marine Counterparts of Locomotive
        Diesel Engines

        Since early  in this project,  it has been anticipated that one of the
 weakest areas would be population and usage information on vessels in the
 class between pleasure boats and ocean-going craft.  Although a considerable
 amount of effort has been expended, a general lack of comprehensive data is
 still  the case, but limited information is available.  Data retrieved from one
 publication^*?) indicate that there may be as few as  3230  commercial vessels
 using diesel engines between 500 and 4000 horsepower (1970), having an
 aggregate rated horsepower of about 2. 26  x 10°.  This source shows total
 diesel merchant vessel horsepower as about 6. 62  x  10 ,  excluding ocean-
 going ships.  Other data indicate that all diesel  merchant vessels (excluding
 ocean-going vessels) use about 6. 7 x 10^ gallons of diesel fuel per year.  If
 3000  hours' operation per year are assumed for the  500-4000 hp class of
 vessels, along with a load factor of 0. 5 and a brake  specific fuel consumption
 of 0.4, fuel consumption for the class could be estimated at about 1. 9 x 10&
 gallons per year. This figure is about 28% of the  merchant vessel fuel con-
 sumption noted above,  while the 500-4000 hp class has about 34% of the diesel
 merchant vessel horsepower,  so the agreement  is not too bad.

        Some confirmation of the assumptions made on diesel  vessels is
 provided by independent data developed by  the U. S.  Army Corps of
 Engineers(20) an£j information obtained by  direct contacts with boat
 operators(21> 22, 23, 24)>  -phe Corps of Engineers' data indicates that
 about 2500 vessels fulfilling the above engine criteria were operated in
 transportation service (not including fishing, dredging,  etc.) in  U.  S.
 waters during 1970.  The information from the commercial boat  operators
 indicates load factors from 0. 56 to 0. 9 (mostly estimates rather than hard
 data), usage up to 500 hours per month, and specific data showing wide
usage of EMD and Fairbanks-Morse engines similar to those used in
 lo c omoti ve s.

                                 34

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        It should be obvious that the population and usage data are quite shaky
 for this category of engine application,  so only little credibility can be
 attached to the resulting emission factors.   The duty cycles of the vessels
 are likewise substantially undefined, but perhaps a reasonable guess would
 be 10% idle, 20% full load, and 10% at each of the seven intermediate load
 conditions (although such notches do not exist for marine applications).
 The assumption is also made that the emissions from these marine engines
 can be characterized by re-weighted locomotive emissions, and emission
 factors based on the cycle above are shown in Table 20.  It will also be

 TABLE 20. RE-WEIGHTED  LOCOMOTIVE EMISSION FACTORS USED TO
  CHARACTERIZE EMISSIONS FROM THEIR MARINE COUNTERPARTS
Engine

Unit 1311
 (2-s Blown)

Unit 8447
Unit 8639
 (4-s T. C.)
 Fuel Specific, g/lbm fuel
 HC     CO    NO*  RCHO
                       Brake Specific,  g/bhp hr
                       HC    CO    NOX    RCHO
8.78
3.69   21.9  0.378
                1.49   13.6
5.84   15.9
                20.7  0.217
       31.9  0.457
3.50   1.47
                       0.561  5.11
8.74  0.151
               7.79  0.0815
2.02   5.49   H.O   0.158
assumed for calculation purposes that marine units under 1000 hp can be
represented by unit 1311, and that units over 1000 hp can be represented
by a 50-50 weighting of factors based on units 8447 and 8639. Since more
is known about the population of marine units in service than about fuel
consumption at this point,  calculation of composite emission factors will
proceed on the brake specific basis  rather than the fuel  specific basis.
The  results of this  analysis are shown in Table 21, but they probably have
only order-of-magnitude accuracy,  at best.  It might be noted, however,
that  most of the emissions would occur either in ports,  cities where river
or lake commerce is common, or further off shore where fishing boats
run.   The emissions probably have a seasonal nature only where harbors
are impassable in winter, in areas where industries employing the vessels
have seasonal transportation needs, or where fishing is  seasonal.

     TABLE 21. ESTIMATED COMPOSITE EMISSION FACTORS
500-to-4000-HP DIESEL-POWERED U.S. FLAG MERCHANT VESSELS
               Pollutant

                 HC
                 CO
                 NOX
                 RCHO
                  Composite Factor
                      g/bhp hr

                      3.42
                      2.30
                      9.65
                      0.159
                                35

-------
                              VI.  SUMMARY

        This report is on a study of locomotive emissions,  and constitutes
 Part 1 of a planned seven-part final report on "Exhaust Emissions from
 Uncontrolled Vehicles and Related Equipment Using Internal Combustion
 Engines, " Contract No.  EHS 70-108.  It includes documentation and dis-
 cussion on characterization of emissions from three locomotive diesel
 engines (sections III and IV),  test data and computed mass  emissions
 (Appendixes A, B, and C), estimation of emission factors and national
 impact for locomotive diesels (section V) and estimation of emission
 factors for their marine counterparts (section V).  As a part of the final
 report on the characterization phase  of EHS 70-108,  this report does not
 contain information on aircraft turbine emissions, outboard motor crank-
 case drainage,  or locomotive emissions control  technology.  As required
 by the contract, these three latter areas have been or will  be reported
 separately.

        Emissions  tests on the three locomotive engines, each of which
 represented a widely-used type having distinctive design features, were
 conducted during April,  1972, at the San Antonio maintenance facility of
 the Southern Pacific Transportation Company.  Southern Pacific personnel,
 both local and those in the corporate headquarters, were extremely co-
 operative, and the importance of this cooperation cannot be overstated.
 The emissions data gathered during this  program are considered quite
 reliable,  with the exception of particulate data which were acquired under
 less-than-ideal conditions.  The data on  hydrocarbons,  CO, CC>2, NO and
 NOX, oxygen, light hydrocarbons, aldehydes, and smoke were all quite
 repeatable, and where data from  other investigations exist  for comparison,
 agreement is reasonably good.  As additional data is acquired in ongoing
 studies,  it may be desirable to update the factors and impact estimates made
 in this report if the data  on which these quantities are based is  shown to be
 atypical for engines in service.

       To measure smoke from the locomotive engines, special versions  of
 the PHS smokemeter were fabricated  with standard optical units mounted on
 20-inch diameter and  40-inch diameter support rings to encompass the
 large locomotive exhaust stacks.   These  instruments were quite successful.

       Expressing the results of this  study in terms of national emissions
 impact of locomotive engines (after numerous assumptions regarding appli-
 cability of the subject  results to the current locomotive population),  figures
were arrived at for locomotive emissions expressed as percentages of the
(1970) national total.   On this basis, locomotive emissions amounted to
0. 467% of hydrocarbons from all sources and 0. 831% of those from mobile
 sources, 0. 146% of CO from all sources  and 0. 194% of that from mobile
 sources, 2. 70% of NOX from all sources  and 5. 24% of that from mobile
sources, and 0. 279% of SOX from all sources and 9. 60% of SOX  from  mobile

                                  36

-------
sources.  Particulate data generated during this study are not considered
reliable enough to be used in computing national impact.  The other emis-
sions measured are not relatable to available national source inventories.

        In order to compile more comprehensive characterization data
and make impact estimates more accurate,  additional engines should be
chosen  to represent the locomotive population more fully, and they should
be tested in a manner similar to the subject test program.  An improve-
ment could be made, however, by using a more highly-developed particulate
sampling system.  Regarding the class of diesel-powered vessels,  the most
notable  need for further information is in the areas of population and usage.
A separate study aimed at surveying the vessel population is really the
answer  to this problem, because the level of effort anticipated is too large
to be accommodated by a  study such as the subject effort.
                                   37

-------
                         LIST OF REFERENCES

  1.  Sawicki, E.,  et al, The 3-Methyl-3-benzothiazalone Hydrazone
      Test, Anal. Chem.  33:93.  1961.

  2.  Altshuller,  A. P,, et al,  Determination of Formaldehyde in Gas
      Mixtures by the Chromotropic Acid Method, Anal. Chem. 33:621.  1961.

  3.  S. A. E. Aircraft Recommended Practice 1256,  preliminary version.

  4.  Report on Exhaust Emissions of Selected Railroad Diesel Locomotives,
      Jointly Funded by the; Association of American Railroads; Atchison,
      Topeka & Santa Fe Railway Co.; Southern Pacific Transportation  Co. ;
      Union Pacific  Railroad Co. Prepared by Southern Pacific Transportation
      Company, San Francisco, California.  March  1972.

  5.  Locomotive Maintenance  Officers Association, Committee on Fuel &
      Lube Oil, Seminar on  Environmental Protection, November 10,  1971
      Electro-Motive Division, General Motors Corporation, La Grange, 111.

  6.  Unconfirmed Minutes of a meeting of The Large Engine Diesel Smoke
      Procedure  Task Force - April 18,  1972.

  7.  Railway Locomotives and Cars, May 1972.

  8.  Projected Increases in Intercity Freight Traffic to A ssociation of American
      Railroads,  August 1971,  Battelle Columbus Laboratories.

  9.  Yearbook of Railroad Facts, 1972 Edition,  Association of American Railroads.

 10.   Operating and  Traffic Statistics - Calendar  Year 1971 (Class I roads) - O. S.
      Series 213 - Association of American Railroads, Economics and Finance
      Department.

11.    Statistics of Railroads of  Class I (U. S.) - I960 - 1970 - statistical summary
      No.  55,  Association of American Railroads, Economics and Finance De-
      partment.

12.    Railway Locomotives and Cars, June 1972.

13.    Personal communication from Jack Hoffman to Karl J. Springer, July 6,  1972.

14.    SAEpaper No.  720604,  Status Report on Locomotives as Sources  of Air
      Pollution, Max Ephraim,  Jr., Electro-Motive  Division,  General Motors
      Corporation.
                                  38

-------
                    LIST OF REFERENCES (CONT'D.)

 15.    1969-1975 Market for Industrial Diesel, Natural Gas, and Gas  Turbine
       Engines,  Engine Marketing Associates, Box 15066 Phoenix, Arizona  85018.

 16.   Personal communication to Mr. B.  C. Dial from G. M. Magee, Association
       of American Railroads,  July 29, 1969.

 17.    1970 EPA Air Pollution Inventory Estimates, Annual Report of the Council
      on Environmental Quality.

 18.   United States Coast Guard Pollution Abatement Program:  A Preliminary
      Study of Vessel and Boat Exhaust Emissions, R. A. Walter, et.  al,
      Transportation Systems  Center, 55  Broadway, Cambridge, MA 02142.

 19.   Merchant Vessels of the U. S.,  1970, Department of Commerce.

 20.   Transportation Series 3, 4, and 5; statistics on U. S.  flag vessels
      operating on U.  S.  waterways in transportation service (powered by
      internal combustion engines); U. S. Army Corps of Engineers,  1970.

 21.   Personal  Communication to Mr. B.  C. Dial from Mr. Norris Mong,
      Port Engineer, Foss  Launch and Tug Co., Seattle, April 5,  1971.

 22.   Personal  Communication to Mr. B.  C.  Dial from Mr. R. X. Caldwell,
      Technical Superintendent, Marine Department, Humble Oil & Refining
      Co., Houston, March 11, 1971.

 23.   Personal Communication to Mr. B.  C.  Dial from Mr. E. Carl Dittrich,
      Dredging Department,  Jahncke Service,  Inc. , Metairie,  La. , March 8,
      1971.

24.   Personal Communication to Mr. B.  C.  Dial from  Mr.  J.  K.  Stuart,
      Manager of Operations, The Great Lakes Towing Company, Cleveland,
      February  22, 1971.
                                   39

-------
        EXPLANATORY NOTES ON
            APPENDIX DATA
All emissions data in the Appendixes are on a
wet basis, that is, corrected for removal of
intake air humidity and water of combustion.
Emissions data in the Appendixes are considered
to be accurate  to 3 significant figures.  Additional
figures have been retained in those numbers which
are considered to be  intermediate, rather than
final, results,  to avoid unnecessary rounding
errors.

-------
             APPENDIX A

Test Data and Computed Mass Emissions,
      EMD 12-567 (S. P.  Unit 1311)

-------

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1 1
	
12.
LOCOMOTt\)E  S.P.



RUN  4
DATE  4/13/72.
t EMD  V2.-S67  SvQ\TCV\  VOET




                2Q.86 irv U»  DRY &OLB TEMPV *
                                                                     74

-------

Mode
1
Z
3
4.
5
6
7
5
9
IO
1 I
/)
1 cl


\4
15
16
17


19
20
2.1
22
23
24
NotcK
of
Idle.
1
2
2.
4
IdU
5
»n.
B**.<\*
T V \ o

&
7
&
5
Pvr
&VHL Ik*.
Idle.
4
3
2
1
IdU

£
275
300
371
442
513
275
584
(555
72.6
800
275




F300
726
655
554


275
513
442
371
300
275
"Time. - &«&.«d
"A vie. VAkt^K~ts
lA "Pfttf C4H"t
15.4
5.O
2.5
2.0
l-O
15,4-
0.5
O-5
o.o
O.O
15.4




o.o
0.0
0.5
0.5


15.4
\.o
2.0
2.5
5.0
15.4

r-Vis R«ct«. Vh*
HC.
355
614
755
1203
680
390
854
2.444
304G
4324
542




3871
2B73
2214
1791


4-13
II&3
770
481
39ft
210
CO
115
245
2.70
375
456
178
536
6IO
803
1521
128




1702
1002
758
672


17G
576
461
351
330
163
NO*
315
661
955
1767
2808
346
4208
5970
7457
9520
292




K&023
80&&
6465
4653


34|
3265
2411
1076
710
396
KCHO
48.5
	
52.6
	
88.8
55.3
	
54.5
	
I2A.
47.6




128.
	
62.9




31. 0
46.7


31.3


il.2
BraVu Sv.*cvfjc.,yuv>x*
HC
IZ7.
5.90
3.73
4.09
3.83
139.
3.16
3.35
3.43
4.04
\94.




3.62
3.13
2.99
3.03


148.
2.69
2.62
2.31
3.&3
75.0

LOCO MOT iM E S.R OMIT 1B>H, HMD 12.-S67 SWITCH
RON 4
DATE 4-/I3/72


Dory CVCLE SANTA FE SWITCH
CO
41.O
2.35
1.34
1.27
1.04
63.6
0.91
0,84
0.90
1,42
4S.7




1.59
1.09
1.02
1.14


62.&
\.2>1
1.57
l.G>9
3.17
58.2
NOX
»«Z.
6.35
4.2B
6.10
6-39
124.
7.17
8.19
8.40
8-90
104.




9.2,7
8.78
8.72
7-88


122.
7.44
8.20
5.17
6-B3
141.
R.CHO
n.3
—
0.26
	
O.2O
19.7

0.075
	
O.II
n.o




OJ2
—
0.084




11. 1
O.I I


0.15

11.2.
Futl Sj.«eUcc,V»k..^u«»
HC
IG.8
10.7
10.7
10.5
vn
17.8
8.35
8.43
8-93
\o.}
2A&




8.84
8.19
7.69
7.9G


I OL Q
I O*y
7,00
f~ QO
6.63
7.06
9.50

Basis
Mats/ */h*
b*aKe. Sj>«c;{ic/Vbkh hv
Futl Specific, Mb«-t«e\
CO
5.45
4.26
3.81
3.26
2.65
8.13
2.41
2.\0
2.35
3.55
5.82




3.89
2.85
2.63
2.99


8.04
3.41
4.12
4.84
5.85
7.38
NOA
14.9
I
1.5
13.5
15.4
16.3
15.&
19.0
20.6
21.9
22.2
13-3




22.9
23.0
22.4
20.7


15.6
19.3
2\.5
14.8
12.6
17.9
RCHO
2.3O
	
0.74
	
0.52
2.53
	
o.\9
	
O.28
2.1&




0.2^
	
0.22




1.42
0,28


0.43


1.41

CycU
HC.
485
&.S8
I2..4
Co~t>o:.l
CO
201
3.56
5.14
•
-U EmUstO«S.
MO^ *RCHO
63O 44-4
U.I O.79
16.1 1.14
*See note U\ "text,
R.CHO  Cow»jpu\eCtloAS

-------
              APPENDIX B

Test Data and Computed Mass Emissions,
     EMD 16-645E-3 (S.P. Unit 8447)

-------
i
ro

Mo«ie
1
2.
3
4
5
€>
7
&
9
10
1 I
12
13
14
IS
16
17
16
19
eo
2.1
22
23
24
N.-UU
o*
L.OM&.
Idle
1
t
3
4
UU
B
6
7
6
lAk
t>y«.
B«aK.t
I4U
8
7
&
5
j>»*.
Bf.Kt
ui*.
4
3
2
I
IJU.
Lvalue.
Sj>«d,
Rt>-
307
307
360
4-90
546
307
27
54fc
307
54£
490
36O
307
307
Oks«*>»td
P«ui«*, V*J>
Ntt


69.2
495.
1055.
t460.


1772.
2165.
26 IO.
3070.
	 r-
	
	
3045.
2550.
212.2.
17 IO.
	


1458.
109 1
515.
96.5
	
G-/USS
5.6
94.6
504.
1064.
IS08.
8.6
I&33.
2279-
27G9.
3323.
IO.O
40.0
7,1
3224.
2736.
2256.
1796.
56.O
7.1
1498.
U2fc.
529.
105.
a
706
67?
Gb\
325
244
207
64O
684-
7lS
692
329
215
57O
602
44B
282
Z37
FIA
rtC.
H>~c
\08
\ot
1 08
140
1 39
9ft
145
m
ZIG
ZIO
94-
72
&&
208
191
\67
148
1&
1 02
123
I22
107
90
97
i^DIR
CO,
V.JH-
I5ft
Q>7
54-
599
\l-97
1 00
140I
1249
7
112
\4fc9
4572
54
45
\34-
NDlR
to,,
%
0.73
1.16
2.9fe
4-57
5.50
0.73
5.70
fc.\9
5.77
6.06
0.73
1.11
0.73
-
81
\98
449
t"
103
2\fc
476
642
131
1X6
764
823
884
904
127
1S1
117
882
882.
B13
7fcZ
143
m
742
709
493
235
114
Q*,
%
19.4
19.1
16.2
13.6
11.7
20.5
11.2
10.8
IV.6
\\.5
19.4
\8.9
19.4
1\.0
\\.|
10.6
11. 1
»&.8
19.3
11.6
\1.}
15.7
1&.5
19.2
RCHO
ty~
22
	
1 I
12
13
9
	
-13
	
»4
14
13
12
10


8


\3
13
5


7
	
7
RUN
                        S.P.UNlT 8447, EMD  SD- 4O (l
-------


MoJe
1


3
A.
5
6


8


IO
1 I
12.

13
14
1 C
1 ts
16

7
IB
19
20

2,1
22
o 31
Zo
24
NotcK
o/
Co*d.
Idle-
i
I
2
3
4
IAU


6


8
nu
^;;^

IA\e.
a


6


$&*«.
LU«-
4


2
i
i
IdU
Maine.
S^t.t4,
Rl>«*
507
arv-y
OV)/
360
490
544
307
/* 1'~7
JL 1
544
307
544
A an
49O
3
l
342
«79
2,338
508

5,440
5,459

7022
8237
465
625

58|

,«*, */
NO*
$40
1 QC.I
1 ofol
0>680
8770
1,426
969

3,o3fe
6,139

Z2,7toJ
6,4i8
1078
1511

<)75
Z1>940
,
Zl,4v>o
16,496

13,000
2290
996
11,031

8399
485B
|Q*7/^
ID/U
952

tv/-
RCftO
H7.


74.6
\07.
133.
49.0


172.


267.
77.5
13,0.

65.2
185.


106.


136.
72.2
46.5


45.0


38.1

&raK.
HC
4-6-9

.76
0.67
0.53
0.43
28.4
/N >l_1
0.4-3
0.47
Of r\
.(oO
0.55
23.8
8.15

30.8
0.49

5O. S
0.4S

0.4-2
6.66
36.5
O.36

O.3&
5.95
2f\Jt
.u*v
2&. 1

SVXLC
CO
14O.

6. IO
0.68
4.59
8.18
59.1

.42
6-7B

•OO
2.48
4fc.5
15.6

80.O
2.77
^ K.*^
o.oo
7.05
Q C.O
O»*>2.
11-7
81-7
8.87

\0. 1
0.61

.Oo
-79.2

^tt,V
KiO,
ISO.
_ /-
• 7. V>
13.2
8.09
7.58
113.

.55
7.34
81 1
././.
7.95
|0&.
37.8

137.
6.93
7Q/1
• O*r
7,31
^') A
•2-4
40.9
I4O.
7.36
*7 A f
7.46
9,18
nn
• O
1 1 1.

bVfcH*
RCHO
20.9


0.15
0.099
0.08B
5,70


0.01fe


0.080
7.75
3.25

9«l&
0.051


0.047


2.42
10.2.
0.032


0.085


4.43

Full .
HC
(b.45
3(1*9
.9Z
1.65
.37
1.12
5.92

. 12
1.2,7

.fc>7
I.5G
5.68
2.89

5.33
1.35
I/t i
S\i-
i.n

.Oo
3.IG
€,.17
0.94

.OO
1.49
31 a
.1"
5.88

b)xeU
CO
19.2

5,25
1.&6
11.9
21,3
12,3

22.2
18.3

•07
6,99
U.I
5.48

13.8
744
9QT
•97
18.4

22.2
5.53
13,8
22.9
ir 1
26.5
1.53
3nc
•Zis
lfc.5

^'Vik.
NO^
20.6

27.8
32,7
21. 0
19,7
23.5

19.9
19.8
*7O Q
zz.y
22.4
25,7
)3.2

23.7
19.2
1 1 O
/.l.o
19.1
- _
lo> /
19.4
23.7
19.0
*A /-
19i5
22.9
1"7 Q
2.7.9
23. »

.•fu.»
RC«0
2.87


0.37
0.2fc
0.23
I.19


0.20


0.23
I-85
1.I4

1.59
0.14


0.12


I. IS
I.72
0.084


0.2\


0,92
LOCOMOTIME S.R UN\T 8447, EMD SD- 40 (\fe-fe4SE. -




RON
            DM"E   4/18/72
Dory  CVC.LE   Eno  LINE. -HAUL
                                                       &O.VIS
                                                   Mais, Vh*
                                                   Fuel
                                                                        Cycle Co»«l>oi.H«.
HC
817
                                                                        0-635
l.fcfe
 ao
4858
                                                                              3.78
 9-90
I0,fe43
            8.25
2.1 .<
 \ZQ
            0.107
0.264

-------
(33
i

MoAe
1
2
3
4
5
6
7
&
9
IO
t 1
12
13
14
15
16
17
l&
1}
ZO
2.1
22
Z3
24
M»-UU
0*
kloM&.
idU
1
z.
3
4
I At*.
S
&
7
5
IAU
t>r*.
&»»«.«.
141*.
8
7
G
5
J»r«.
B »•*.«.
ut*.
4
3
2
I
Id I*.
m^iMe.
S|*«"
307
307
360
490
546
3 O7
627
725
812
900
307
54(b
307
90O
812.
728
627
546
307
546
490
3
N«t


^2.3
A-75.
U\5.
1433.


1755.
2150.
2550.
2960.
	 	


	
2<)60.
254O.
2. MO.
174-2.
	
	
1460.
1103.
524.
108.
	
G-voss
&.G
99.4
466.
U44.
1413.
8.6
1&16.
22.64.
2736.
32\3.
1O.O
40.0
7.1
3B9.
2726.
2244.
ISZfc.
56.0
7.\
1500.
H3&.
538.
116.
8.6
Fo«l
Rate,
lb-/M
40.7
67.5
203.
443.
577.
4-1.0
&90.
865.
974.
U
\\4.
4».S
\\5&.
993.
83&
(b97.
118.
4-J.3
577.
435.
204.
0>7.fc
40.4
Ti.^jMrod.u^ts,
°F
I-lofct
89
89
90
89
99
87
8&
87
88
89
91
90
90
92
92
92.
90
90
87
88
87
88
88
87
Exhouit
264
238
353
573
666
34-7
664
735
725
72.1
312.
215
201
703
725
754-
1>-
101
23 1
45&
7\&
746
109
789
839
882.
926
124
\43
94
889
89 1
829
783
148
1O6
74-7
718
471
235
U2
C.L.
NO*,
\>t~
1V9
24O
4-8\
723
760
122
802
&2>9
893
92
•Q,
%
19.9
19.0
16.3
I2.A
11.6
19.7
11. 2>
10.7
11.3
11.5
»9.6
19.3
19.9
U.I
II. Z
10.7
IO.6
18.2»
19.6
11.8
12.2
IS.8
l&.B
»9.5
RCHO
fy~
22.


13
	
18
IS
— _
i&


12.
17
16
18
»4


8


13
12
8


&


12
LOCOHOTtME  S.PUNVT 8447,


RUN  2.
                                                 SD-4O
DATE  4/18/12   BAROME.TER  29.O1
WET  6ULB TEHP. .


DRY £OLB TEMPV *
                                                                                             77

-------
w
 I

Mode
1
Z
3
4.
5
6
7
ft
9
10
t 1
\i
13
\4-
15
16
17
18
19
20
2.1
22
23
24
NotcK
ov
Lend.
Idle.
1
2
2>
4
IAU
5 -
«4,
R\>«
SOT
307
360
4-90
546
307
627
72.6
612
900
307
546
307
9OO
812
72ft

HC.
Z3I
\BO
279
4-44
591
2tG
739
985
434-
2138
24O
358
Z2.\
\912
1400
92|
700
357
235
SG.I
421
285
232
239
CO
293
an
25ft
%B9
2,273
395
l*,')73
6,»2|
%&
6fcfcO
322
Gfc9
559
9945
10,454
15,571
15,121
625
570
I2,38
8521,
10,134
10 It
3X225
{.,170
11,019
Z€>890
I0fe4
2254
903
23,845
21,IC>4
5,5?3
2,824
1%1
m
•0,193
82»7
4532
2J58
9^2
RCHO
»\9.


81.8


l(ofc.
81.5


228.


2\9.
87A
147.
&7.0
240-


9b.9


130.
65.5
75.4


47.9


63.9
B^Ke St>>v*
HC
2G.8
».8l
0.57
0.39
0.40
30.9
0.41
044
0.52
O.fct
Z4.0
8.95
31.1
O.Q>I
O.SI
0.41
0.36
6.37
33.1
0.37
0.37
O.S3
2.20
21.7
CO
52.9
2.12
0.53
8.44
8.33
45.9
8.24
7«»2
3.52
2.8
8.74
3.67
12.2
04)76


0043


2.32
9.25
O.OSO


0.089


7.44
Futl S»>«ei-f it, %_{„•»
HC
5.K^ H'
ru«l S>tscci'Tl.t , /\^ *?ut\
Cyc\t ComJ>o>l-\e Elusions.
HC
872
0.691
\.78
CO
4976
[3,94
IO.2.
NO,
10,317
8.\8
2.1. 1
*RCHO
140
0.1 11
0.280)
                                                                                                      »\o
oVe
                                                                                                             ».*\
                                                                                                                                      RCHO

-------

Mode
1
2.
3
4
5
6
7
6
9
1O
1 1
12
13
14
IS
16
17
ta
\J
20
2.1
22
23
24
N»tcU
0*
lon&.
Idle
1
t
3
4
Ult
5
6
7
5
IAU
t>y».
&»•«.«,
I4U
6
7
6
5
J>V«.
&*•£«.
Ul<-
4
3
2
1
HU
•Lupine
S|>t«d,
Rt>"*
307
307
360
490
546
307
627
726
BIZ
90O
307
54C,
307
900
bU
728
627
54k
307
54G>
490
3Q>0
3O7
507
Obs«+wtd
P»ul»*, fe)»
N«t
	
87.4
476.
973.
1410.
	
mo.
2185.
2&20.
5020-
	 r


	
iOOO.
25SCX
Z»4fc.
»722.
	
	
1420.
»090.
5\3.
99.7
	
G*ots
S.Q>
93,0
485.
99t-
1458.
8.6
»&31.
2299.
2779.
3273.
10.0
40.0
7.»
3179.
273fe.
2280.
I BOB.
5G.D
7,1
14tt>.
1\25.
527.
105.
8,6
Fu«l
Rai«,
lb-/h*
42.8
C>9,0
198.
433.
552,
4\.3
w.
856.
993.
1179.
4US
U3.
40-7
nse.
1002.
856.
703.
112
40,4
557.
433.
20G.
G>7,3
4\.6
TimjfMrocttt^tS,
°F
r-i.kt
78
78
78
7?
81
79
81
82.
81
83
65
83
84
84
84-
84
68
8
92
106
NDIR
CO,
W~
100
76
88
286
774
90
1492.
1224
G63
498
78
78
112
626
711
1313
1548
G7
100
1522
IBIS
61
0.73
NDIR
NO,
H>~
105
239
491
716
B09
142.
8C4
9o5
96&
99b
167
178
166
950
997
916
862
\91
178
863
781
571
289
142
C.L.
NO,
Y>t»-
79
^oo
41G
626
716
102
741
8\9
857
884
122
134
102.
659
839
783
74\
134
109
710
674
480
226
)02
C.L.
NO*.
Pt"
89
214
431
631
723
113
744
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LOCOMOTNE S.R OMIT &441, EMD Sb-40 (lfe-WSE,-3)
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             RUN   4     DATE  4-A9/72  BAR,OHETER  Z9.OZ  ln t^.  DRy POLB TEMR, "F

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RUN   4
                                 4-/\9/72
             OOTy  CYCLE   BMP  LINE.- HAUL
                                                                fUvs,
                                                    Fu«l Specific,
                                                                                      Cyc\t
                                                                                      HC
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1.83
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     5575
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                                                                •«>ee

-------
             APPENDIX C

Test Data and Computed Mass Emissions,
     G.E.  7FDL16 (S.P.  Unit 8639)

-------
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I

M««ie,
1
2.
3
4
5
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7
8
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At\
LOCO MOT l\) E. S.R UNIT 8639, G-.E. O-33 C	



RUN   i     DATE  4/25/12.  BAROMETER 23.20
DRY
TEMPV *
                                                                              &4

-------
0
I
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Mode
I
I
3
4.
5
6
7
6
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12
13
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15
16
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2.4O
LOCOMOTNE S.R UI01T 8639 ,



RON _l _    DATE  4/25/72.



DUTY  CVCLE
                                                Q-33 C
                              . E.  UN)E- HAOU
    Basis
                                                                 Maw, Vh*
Fuel S)i>eci(ic,
                                                                                                     Ervl»$iO»\S.
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                      Z885
                                                                                       2.23
6.38
 CO
      5752
                            4.45
12.7
      13,819
            10.7
30.7
            O.\90
0.544

-------
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LOCOHOTOJE S. RUM IT 6foS9, O.^E.. VJ-33 C.



RUN   2.     DATE   4/2.5/7Z
19. IP
                                                                            vOET 6OLB TEMP. .»F 6-6



                                                                            DRY  3OLB  TEMPV *F  89

-------
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I

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3
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5
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7
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9
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35
LOCOHCrnME. S.P.


RUN   4-    DATE
&AR.OME.TER  29.04
                       MOTE'.
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                           DATE  4/2.6/72.
                                                                  Mats,
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568
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     574
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     126
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              S.P.
RUN
                                                                                           70
                         DATE  4/26/iz  BAROMETER  29.04 1>V n^.  DRY 301.6 TEMP., *F   7fe
                              NOTE : NOTClrt ES 1—7  RON  AT  OFF- DE.SX

-------
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                         S.P. UM1T 8633 ^ a.E. O-33 C
            RUN  5
             DUTY  CYCLE-
               NOTE  OFF- DESIG-N  SPEEDS , NOTC. H t-S  1  	1

-------
                      APPENDIX D




Analysis of Fuels Used During Locomotive Emissions Tests

-------
          CHARACTERISTICS OF LOCOMOTIVE TEST FUELS


Locomotive Unit No.              SP-1311       SP-8447       SP-8639

Gravity, °API@60°F              33.5           30.8          34.2

H/C Mole Ratio                     1.73           1.71           1.82

Sulfur,  weight %                    0.22           0.37           0.21

Fluorescence Indicator
  Analysis:  % Aromatics          27.0           36.0          22.4
            %01efins               0.0            1.5           0.0
            % Saturates           73.0           62.5          77.6

Cetane No. (calculated)             44.5           41.1           45.6
Distillation Temperatures, °F
Initial Boiling Point
10%
20%
30%
40%
50%
60%
70%
80%
90%
95%
End Point
% Recovery
% Residue

376
435
456
472
487
501
518
534
556
582
605
636
99.0
1.0

382
430
455
479
497
516
535
555
578
608
631
664
99.0
1.0

386
439
458
474
488
501
515
530
549
575
597
625
99.0
1. 0
                               D-2

-------
                 APPENDIX E




Major Maintenance History of Test Locomotives

-------
        The maintenance information recorded here is that which was
 easily available at the San Antonio facility.  The salient point is that
 when emissions measurements were taken, all the engines were judged
 to be in good operating condition.  More detailed information could
 probably be obtained if the need arose.

                        Unit SP-1311 (EMD 12-567)

        The date when this unit was placed in service was not on record,
 but the last engine overhaul date was listed as September 1971. No engine
 work had been performed since the overhaul.   The engine was equipped
 with low-output 6-hole "N" injectors with 0.421 diameter plungers (not
 low sac type),  EMD part no. 8276707.

                     Unit SP-8447 (EMD  16-645E-3)

       This unit was placed in service in April 1966, and was  last over-
 hauled in December,  1968.  Maintenance was also performed January 16,
 1972, including renewal of all power assemblies, and no work had been
 performed since that time.

                      Unit SP-8639 (G. E. 7FDL-16)

       Unit 8639 was placed in service in May, 1969, and had not been
 overhauled.  It had undergone maintenance February 24, 1972,  including
 L2, L7,  R6,  and R8 power assembly replacement.   When it was tested
prior to beginning  emissions tests, the power level was low, so injector
pumps and nozzles were replaced on  L6, L7, and R7. The racks were
also set to 21mm (static) and measured at  22. 5mm running before the
emissions tests were conducted.
                                  E-2

-------