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                                           APTD-1518
SUMMARY  OF  DEMONSTRATION METHODS
  FOR  EXTINGUISHING  CULM-BANK FIRES
                  R. C. Flegal
                     and
                  N. J. Gahr
       U.S. ENVIRONMENTAL PROTECTION AGENCY
           Office of Air and Water Programs
        Office of Air Quality Planning and Standards
       Research Triangle Park, North Carolina 27711
                   July 1973

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The APTD (Air Pollution Technical Data) series of reports is issued by the Office of Air
Quality Planning and Standards, Office of Air and Water Programs, Environmental Protec-
tion Agency, to report technical data of interest to a limited number of readers.  Copies
of APTD reports are available free of charge to Federal employees, current contractors
and grantees, and nonprofit organizations - as supplies permit - from the Air Pollution
Technical Information Center, Environmental Protection Agency, Research Triangle Park,
North Carolina 27711 or may be obtained, for a nominal cost, from the National Technical
Information Service,  5285 Port Royal Road, Springfield, Virginia 22151.
                           Publication No. APTD-1518
                                         II

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                                CONTENTS
LIST OF TABLES	iii
ABSTRACT	 ,  ,	  . .  4	  iv'
SUMMARY AND RECOMMENDATIONS	   v
1.   INTRODUCTION	   1

2.   DESCRIPTION OF BURNING-CULM-BANK PROBLEM	   3
    2.1  Composition of Culm Banks   	   3
    2.2  Dimensions of Problem	   3
    2.3  Location of Burning Banks	   3
    2.4  Emission of Air Pollutants	   4
    2.5  Historical Efforts to Control Burning	   5

3.   PURPOSE OF DEMONSTRATION PROGRAMS AND AIR POLLUTION CONTROL
      OFFICE GUIDELINES FOR AWARDING GRANTS	   7

4.   FACTORS INFLUENCING SELECTION OF CONTROL METHODS	   9
    4.1  Physical Requirements	   9
    4.2  Econcimic Considerations	:	10

5.   REFERENCES	t	11

APPENDIX.  SUMMARIES OF DEMONSTRATION PROJECTS FUNDED
  BY APCO 1966 TO 1968	13
    A.I  MANCHESTER, KENTUCKY (66A-2001D)	  15
    A.2  HESHBON, PENNSYLVANIA (66A-4103D)	17
    A. 3  HESHBON, PENNSYLVANIA (66A-4104D)	'.	19
    A.4  SHAMOKIN, PENNSYLVANIA (67A-4112D)	21
    A. 5  CARROLLTOWN, PENNSYLVANIA (66A-4102D)	23
    A.6  TUSCARORA, PENNSYLVANIA (66A-4107D)	25
    A.7  ALLEN JUNCTION, WEST VIRGINIA (66A-5301D)	:	27
    A.8  TUSCARORA, PENNSYLVANIA (67A-4110D)	29
    A.9  ISELIN. PENNSYLVANIA (67A-4111D)	31
    A. 10  ASHLEY, PENNSYLVANIA (66A-4101D)	33
    A. 11  GYPSY, PENNSYLVANIA (66A-4105D)	35
    A.12  WHITE STATION, PENNSYLVANIA (66A-4106D)	  39
    A. 13  SCRANTON, PENNSYLVANIA (66A-4108D)	41
    A. 14  NORTH SCRANTON, PENNSYLVANIA (67A-4109D)	43
    A. 15  ASHLEY, PENNSYLVANIA (68A-4113D)	45
                              LIST  OF TABLES

Table                                                                 Page
   1    Comparison of Demonstration Methods by Unit Costs and Effectiveness
        Ratings	vii
                                     in

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                                    ABSTRACT


        Sealing, grouting, and mechanical-hydraulic methods of extinguishing burning
coal-refuse banks were evaluated through 15 demonstration grants in three states of the
Appalachian region of the United States.  The primary purpose of the demonstration grant
program was to evaluate various techniques for extinguishing culm-bank fires.  Both
effectiveness and unit cost were major considerations in the evaluation.  Mechanical-
hydraulic methods were the most successful procedures used in terms of effectiveness
and economy; they completely extinguished the fires and had a moderate unit cost of
$0.66 to $2.19 per cubic yard of material treated.  These methods, however, require
large quantities of water and a large disposal area - requirements that are not always
present at burning culm-bank sites. The wide diversity of coal-refuse-bank sizes,
shapes, compositions,  and locations makes selection of  a universally recommended con-
trol method impossible.
Keywords:  culm-bank fires, air pollutant emissions, demonstration projects, costs.
                                         IV

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                     SUMMARY  AND RECOMMENDATIONS
        Fifteen demonstration grants were funded by the Federal government between
July 1966 and February 1968 to determine efficient, effective, and economical methods of
extinguishing culm-bank fires in three states of the Appalachian region.

        Three basic methods were demonstrated:

        1.  Sealing  - the prevention of air from reaching the hot zones of the bank.  The
           fire is extinguished because of insufficient oxygen for combustion.

        2.  Grouting - the injection of a slurry consisting of water, limestone, vermicu-
           lite, sodium bicarbonate, or vermiculite plus sodium bicarbonate into the hot
           zones of the pile.

        3.  Mechanical-Hydraulic - the use of water as the extinguishment medium.  The
           quenched material is subsequently replied and compacted.

        Mechanical-hydraulic methods were the most successful procedures used in
terms of effectiveness and economy; they completely extinguished the fire and had a
moderate unit cost of $0.66 to $2.19 per cubic yard of material treated.
                                                f
        Some of the sealing methods yielded low unit costs of $0.20 to $1.04 per cubic
yard, but were not  successful in completely extinguishing the fires. One recent sealing
project at Iselin, Pennsylvania, (appendix A.9) appears to have successfully extinguish-
ed the fire but at a relatively high unit cost of $3. 36 per cubic yard.
                                                          \
        In three of  the four grouting projects,  the grout was not able to completely ex-
tinguish the fires and also had high unit costs of $1.50 to $6.51 per  cubic yard.  In the
fourth project, however, at Fails Slope, Pa., the method appears to have extinguished
the fire  at an acceptable unit cost of $1.25 per cubic yard.

        The 15 completed projects  cost a total of $2,501,313, including contributions by
the states.  An estimated 3,021,485 cubic yards of burning refuse was processed, for an
average unit cost of $0.83 per cubic yard.

        All 15 projects had some beneficial effects upon air pollutant emissions from the
banks, but efforts to measure these effects were inconclusive.

        Of the 15 demonstration projects, 7 were judged to have produced good results
considering both the economics and the technology involved in extinguishing the burning
coal-refuse banks.  Successful methods used include:

        1.  Grouting with a lime-limestone slurry and covering the  pile with limestone
           refuse.

        2.  Sealing  with polyurethane foam after shaping the pile and quenching hot
           spots with wate"r.

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        3. -Quenching or sprinkling with water;  earth-movers used to repile and com-
           pact the waste.  Water monitors and lagoons were also used to effectively
           extinguish fires.

A comparison and evaluation of the 15 projects is  given in Table 1.

        A mechanical-hydraulic method would be the logical choice for the control of
burning culm banks that are in close proximity to densely populated areas such as the
northern anthracite region of Pennsylvania.  Although mechanical-hydraulic methods
require ample space and abundant water, they extinguish the burning banks quickly and
completely and produce low, level piles of reduced volume.  These compacted, extin-
guished sites can be developed as commercial and industrial locations.

        In contrast to the urban situation, the valleys and hills of the coal-producing
states are dotted with many  small, burning coal-refuse banks that are usually the only
source of air pollution in the immediate area. Because of the topography, access is often
difficult and sufficient water is not easily available; therefore, sealing with natural cover
would probably be the chosen control method in the majority of cases. Although it is
neither as quick nor as complete as mechanical-hydraulic methods in extinguishing burn-
ing banks, sealing was used in some projects, and produced dramatic effects upon local
air pollution - at 30 to 50 percent of the unit cost of hydraulic methods.  The sealing
method appears to be effective if enough  cover material is applied initially and if adequate
maintenance is provided to repair erosion damage that may otherwise destroy the seal.

        In some instances, grouting may be employed either separately or in combination
with a  refuse-limestone seal..  The limestone grout and seal not only completely extinguish
flie burning material but also effectively  neutralize runoff water that might otherwise be-
come highly acidic after percolating through the burning bank.

CONCLUSIONS  AND RECOMMENDATIONS

        Factors that influence selection of the method used to extinguish fires in coal-
refuse  banks include:  size, shape, and  composition of the bank; topography; avail-
ability of water; and the proximity of the bank to  population centers.

        The successful methods noted in Table 1  and the potential applicability of other
appropriate methods should  be considered and evaluated in light of specific site condi-
tions when efforts to extinguish coal-refuse banks are undertaken in the future.
                                         VI

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Table 1.  COMPARISON OF DEMONSTRATION METHODS BY UNITS, COSTS,
                  AND EFFECTIVENESS RATINGS
Location and
project number
Manchester, Ky.
Shamrock Coal Co.
66A-2001Dt>
Heshbon, Pa.
Pennsylvania Coal
and Coke Mine
66A-4103DC
Heshbon, Pa.
Pennsylvania Coal
and Coke Mine
66A-4104DC
Fails Slope,
Shamokin, Pa.
Rossini Coal Co.
67A-4112DC
Carroll town, Pa.
Bakerton Bank of
Barnes and Tucker
Coal Co.
66A-4102DC
Tuscarora, Pa.
Mary-D Bank
66A-4107DC
Allen Junction,
W. Va.
66A-5301Dd
Tuscarora, Pa.
Mary-D Bank
67A-4110DC
Iselin, Pa.
Roch and Pitts-
burg Bank
67A-4111DC
Ashley, Pa.
Huber Bank
66A-4101DC
Gypsy, Pa.
Maryland Tro-
jan Mine
66A-4105DC
White Station,
Pa, , Westmorland
Coal Co. Mine
66A-4106DC
Scranton, Pa.
Baker Bank
66A-4108DC


Federal
grant,
$
101,850


139,874



34,170



30,000



117,098




81 ,220


57,389


128,621


126,066
V


259,125


96,427



49,762



27,073




Total
cost,
$a
146,504


178,498



.-45,570



40,000



156,131




108,293


79,979


171,495


168,090



345,500


128,570



66,350



36,097




Method
demonstrated
Grout - 40% vermiculite,
40% limestone, 20% bi-
carbonate of soda
Grout - 70% vermiculite,
20% limestone, 10%
bicarbonate of soda

Grout - "Yellow boy"
sludge from neutraliza-
tion of mine water

Grout - lime-limestone
slurry. Pile covered
with limestone refuse

Polyurethane foam seal ,
nitrogen injection,
chemical (CWS)


Seal - clay on sides,
cement dust on top

Seal - asphaltic sand-
limestone, emulsion
sprayed on
Seal - limestone refuse,
pile seeded after seal
is applied
Seal - polyurethane foam
after shaping pile and
quenching hot spots
with water
Quench - water, repile
with earth-movers

Quench - water spray, 5%
ammonium sulfamate on
hot spots

Water sprinkling - repile
in compacted layers


Explosive breakup of
portions of bank,
water quenching and
removal to disposal
area
Material
processed,
cubic
yards
22,508


118,755



10,300



32,000



150,000
/



384,673


410,000


384,327


50,000



304,000


-



100,485



16,500




Cost
per
cubic.
yard ,
$a
6.51


1..50



4.42



1.25



1.04




0.28


0.20


0.45


3.36



1.14


-



0.66



2.19




Rating
Poor


Partial



Poor



Good



Partial




Partial


Partial


Partial


Good



Good


Poor



Good

k

Good




                                VII

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             Table 1  (continued).   COMPARISON.OF DEMONSTRATION METHODS BY UNITS,
                               COSTS,  AND EFFECTIVENESS RATINGS



Location and
project number
Lackawanna
County, Pa.
Marvin Bank
67A-4109DC
Ashley, Pa.
Huber Bank
68A-4113D6






Total all
projects'


Federal
grant,
$
240,000



281,736








1,764,619



Total
cost,
$a
448,500



381,736








2,501,313




Method
demonstrated
Water monitors - quench-
ing and removal by
earth-mover

(1 ) Water monitors,
lagoons - repile and
compact with earth-
movers
(2) Method 1 plus water
monitors to spray bank,
remove to disposal area
and deposit in alternate
layers and compact



Material
processed,
cubic
yards .
586,666



261,771



189,500




3,021,485

Cost
per
cubic
ya rd ,
$a
0.76



0.71



1.04










Rating
Good



Good



Good






 Includes cost incurred by grantee agency in supervising and monitoring the project.
3Grantee:  Kentucky Air Pollution Control Commission.
"Grantee:  Pennsylvania Department of Mines and Mineral  Industries.
 Grantee:  West Virginia Air Pollution Control  Commission.
^Grantee:  Commonwealth Development Association of Pennsylvania.
 The seven projects rated "good"  processed or extinguished  1,540,992 cubic yards  of material
 at a cost of $1,486,253 or $0.96 per cubic yard.
                                            VIII

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          SUMMARY  OF  DEMONSTRATION  METHODS


            FOR  EXTINGUISHING  CULM-BANK  FIRES


                              1.   INTRODUCTION

        Burning coal-refuse piles have probably been causing air pollution since coal
mining started, but methods for controlling and extinguishing the fires have only been
investigated during the past 50 years in both Europe and the United States. These
efforts have frequently met with short-term success, but after a year or two the piles
have reignited.  Because air pollution was not considered a serious problem, except in
local areas, these surface coal-refuse fires did not attract nationwide attention.

        With the increased interest in air pollution abatement in recent years, studies of
the burning-culm-bank problem have increased and several states have begun programs
to extinguish culm'-bank fires.  Activity to expedite public works projects in many areas
where mine-refuse fires cause serious air pollution problems increased within the
Federal  government with the passage of the Appalachian Regional Development Act of
1965.  Federal grants were channeled through State agencies to fund  15 demonstration
projects conducted between July 1966 and February 1968.  Three basic methods were
demonstrated:

        1.  Sealing - the covering over of the surface to prevent air from reaching the
           hot zones of the burning bank; the blaze is extinguished  because the avail-
           able oxygen is insufficient to support combustion.

        2.  Grouting - the injection of a slurry consisting of water, limestone, vermicu-
           lite, sodium bicarbonate, or vermiculite plus  sodium bicarbonate into the
           hot zones of the pile.

        3.  Mechanical-hydraulic - the use of water to extinguish the fire and earth-
           moving equipment to repile and compact the quenched material.

        The primary purpose of the demonstration grant program  was to determine a
unit cost for each effective method of  extinguishing culm-bank fires.

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           2.   DESCRIPTION  OF BURNING-CULM-BANK  PROBLEM

2.1 COMPOSITION OF CULM BANKS

        A culm bank is an accumulation of refuse that results from mining and preparing
coal for marketing.  The banks are usually composed of loose rock and coal, bonded rock
and coal, carbonaceous shale, and pyrites. They may also contain foreign materials such
as timber, discarded machine parts, paper containers, decaying brattice cloth, oily rags,
and grease. Occasionally, a culm bank may also be the dumping area for trash and gar-
bage from nearby homes. These combustible materials, of course, substantially increase
the banks' susceptibility to inadvertent or spontaneous ignition. The combustible content
of culm banks can vary from 10 to 60 percent, depending on the age of the pile and the
mining and preparation methods employed at the site. Prior to 1920, hand mining was the
general practice, and much of it was done in relatively "clean" coal. The advent of open-
pit mining, underground mechanization, and stringent market specifications required
the construction of hundreds of preparation plants to "wash" the coal to remove sulfur
and achieve higher levels of purity.

2.2 DIMENSIONS OF PROBLEM

        Estimates from the Bureau of Mines indicate that the bituminous coal industry
produces approximately 100 million tons of refuse per year. 1  Accurate estimates of the
total refuse collected are difficult to obtain, however. Recent estimates from the Bureau
of Mines indicate that approximately 73 billon tons of coal (anthracite and bituminous)
have been mined in this country since commercial operations began. An estimated 10
percent of this total was waste and mine losses. *•'

        In the United States,  anthracite has been commercially mined since 1860 and has
always required some form of cleaning, either by hand or by mechanical methods.
Approximately 4.5 billion tons of anthracite coal have been mined since 1890 of which 40
percent was waste material.    The bituminous mines did not adopt mechanical cleaning
until much later. I -.  1927 the  Bureau of Mines reported that only 5. 3 percent of the bitu-
minous coal produced was mechanically cleaned.  The use of this process has steadily
increased, and at present 64 percent of all the coal produced is mechanically cleaned.

2.3 LOCATION OF BURNING BANKS

        A 1969 national survey and inventory of coal-mine refuse banks by the U.S.
Bureau of Mines identified, by visual determination, 292 burning banks in 13 of the 26
coal-producing states.

        More than 90 percent of these burning banks were found in 7 states in the Appa-
lachian region:   West Virginia had 132 ignited banks; Pennsylvania, bituminous 48 and
anthracite 25; Kentucky, 27; Ohio, 6;  Alabama, 6; and Maryland, 2.  Of the remaining 6
states with burning coal-refuse banks, Colorado had 15 culm-bank fires; Illinois, 4;
Utah, 4; Montana, 3; Oklahoma, 1; and Washington, 1.

        Calculations based on pile dimensions reported in the inventory indicate that the
total volume of burning materials approximated 270 million cubic yards.

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2.4 EMISSION OF AIR POLLUTANTS

        Burning coal-refuse piles form sulfuric acid and emit oxides of sulfur, which are
formed by the thermal decomposition and oxidation of pyritic material in the refuse:
      FeS2
ferrous disulfide
      (pyrite)
        302
      oxygen
        FeSO,
                       ferrous sulfate
       SO2
   sulfur dioxide
                    (1)
       2FeS2      +   2H2O    +    7O2 —
ferrous disulfide      water      oxygen
      (pyrite)
                                2FeSO4
                            2H2S04
                        (2)
                            ferrous sulfate   sulfuric acid
        Many burning piles also emit hydrogen sulfide.  Although no information exists
that delineates the mechanism of hydrogen sulfide formation in burning coal-refuse piles,
two possible reactions are:
        1. The reaction of sulfuric acid with pyritic material in the refuse:
    H2SO4
sulfuric acid
     FeS
ferrous sulfide
	• FeSO4
 ferrous sulfate
      H2S
hydrogen sulfide
                    (3)
        2. The reaction of carbon with sulfur dioxide to form carbon disulfide in hot
           sections of the pile.  The carbon disulfide would hydrolize to form hydrogen
           sulfide:
      CS2        +   2H2O -
carbon disulfide       water
                    hydrogen sulfide
                            CO2
                       carbon dioxide
                                                               (4)
        By virtue of the heterogeneous nature of the individual piles, there are many
other possible reactions in which hydrogen sulfide is likely to be formed.

        Burning piles also emit other gases usually associated with coal combustion.  As
these gases pass through the pile, many reactions including incomplete combustion, re-
duction, and the thermal decomposition of pyrite occur. One manifestation of these reac-
tions is the appearance of  small rivulets of sulfur on the surface near the site of interior
burning.  This sulfur could be formed by the thermal breakdown of ferrous disulfide, or
by the reaction of hydrogen sulfide and  sulfur dioxide:
      2H2S
hydrogen sulfide
           SO-
                 3S
       sulfur dioxide
               sulfur
+  2H20
   water
                        (5)
        The Pennsylvania Department of Health has conducted air-sampling programs in
the area of burning piles and found carbon monoxide, sulfur dioxide, hydrogen sulfide,
and ammonia in samples taken from the surface of the piles.  Atmospheric air sampling
conducted in communities located near burning banks has frequently produced evidence
of sulfur dioxide concentrations exceeding  4.5 parts per million (ppm) and of hydrogen
sulfide concentrations of 4.0 ppm.  Gaseous emissions of these concentrations can ad-
versely affect the property and health of the inhabitants of nearby communities.  Because

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some coal miners already suffer from respiratory illnesses, the adverse health effects
resulting from culm-bank emissions may be accentuated within this occupational group.

2.5 HISTORICAL EFFORTS TO CONTROL BURNING

        One of the earliest efforts to extinguish a burning culm bank in this country was
conducted by the Philadelphia and Reading Coal and Iron Company at its St. Nicholas
Colliery near Mahoney City, Pa., during 1937 and 1938.  This project involved moving
approximately 1,685,300 cubic yards of burning material at a cost of $532,000.5  The
techniques employed were basically the same as those used in subsequent projects:  iso-
lating the fire area and quenching the pile with water, followed by excavating the burning
material and repiling the cooled material.

        The literature contains many references to private efforts to extinguish or prevent
culm-bank fires. ••>"'   The first broad-scale efforts to control burning coal-refuse piles
began in England during World War II.  These efforts consisted primarily of water
quenching to prevent the culm-bank flames from being used as navigational check-points
by German bomber pilots.  Unfortunately, these endeavors stopped at the end of the war,
and most of the piles reignited. The British experience not only provided several valu-
able techniques that were employed in later studies, but also underscored the vital
importance of continued vigilance to prevent reignition.
                        ,          \
        In 1957 the U.S. Bureau of Mines initiated laboratory research to determine some
of the factors affecting  ignition of coal-mine refuse; the methods developed in the labora-
tory were then field-tested from 1963 to 1965. Laboratory studies showed that particle-
size distribution of the refuse has a greater effect on spontaneous-heating tendency than
does the combustible, or pyritic content. The field tests demonstrated that water, applied
in sufficient quantity and over an extended period of time, can control surface  burning
and prevent the liberation of noxious gas.

        In 1963 the Pennsylvania Department of Mines and Mineral Industries awarded a
contract to Bituminous  Coal Research Incorporated to explore the possibility of controlling
culm-bank fires  by injection of finely divided material; unfortunately, the effect of this
"grout" material was temporary.

        The Division of Air Pollution Control of the Public Health Service (PHS) became
actively involved in the problem of burning coal-mine-refuse banks in March 1961. The
first project that dealt directly with culm banks was funded in 1962 as a research grant to
Pennsylvania State University.  This grant was designed to determine the technical and
economic feasibility of recleaning culm banks to reduce the combustible content and to
produce a marketable coal product. The resulting laboratory and pilot-plant work suc-
cessfully demonstrated the  technical capability of meeting both objectives, but  the market
conditions in that area  of Pennsylvania at the time (1965) made a commercial application
only marginally attractive.

        During June 1965,  the Area Redevelopment Administration (ARA) of the U.S.
Commerce Department funded a short project at the Huber Bank near Ashley, Pa.  The
State of Pennsylvania continued this work during October 1965.  Additional efforts to
extinguish the burning refuse were conducted at the Huber Bank during August and
September of 1967,  under a cooperative grant by the Economics Development Administra-
tion (the successor to ARA) and the State of Pennsylvania.  This project was notable
because it conclusively demonstrated the effectiveness of the "water cannon," or  "moni-
tor," as an earth-moving-quenching device that creates no plumes of black smoke when
it disturbs the pile.

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        With the passage of the Appalachian Regional Development Act of 1965, activity
increased within the Federal government to expedite public works projects in many
areas where mine-refuse fires cause serious air pollution problems.  The Public Health
Service assumed the authority to undertake culm-bank abatement procedures under the
Clean Air Act  of 1963, and Congress appropriated $975,000 for this-project during fiscal
year 1966 and $525,000 for more projects in fiscal year 1967.

        To date, 15 projects have been funded and completed.

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               3.   PURPOSE  OF DEMONSTRATION  PROGRAM

           AND  AIR  POLLUTION CONTROL OFFICE GUIDELINES

                            FOR AWARDING GRANTS

        The primary purpose of the demonstration grant program was to determine a unit
cost for each effective method of extinguishing culm-bank fires.  Where possible, the unit
cost was to be expressed as dollars per cubic yard of material treated.  Because determi-
nation of unit costs was the focus of the study, only a limited number of before-and-after
air-quality measurements were attempted, and, because of the limited availability of
equipment, those measurements proved inconclusive.

        Visual observation was the principal method of determining the  effect of efforts
to extinguish the burning banks.  As a secondary method of evaluation,  thermowells were
placed in the various piles to permit internal temperature monitoring.

        Grants were given to official State agencies for projects designed to demonstrate
methods for extinguishing  and controlling fires in coal-mine-refuse piles.   (One grant
was made to a nonprofit corporation during 1968.)  Federal funds provided as much as
75 percent of the total cost of a project.  The contribution of the State agency could be in
cash or in services provided, but the State agency was responsible for the supervision of
the  project and for the preparation of reports relating to the project. Participation of Air
Pollution Control Office (APCO) personnel was limited to monitoring the projects, but
that cost was not included in the Federal share of the project costs.

        State agencies submitted proposals for projects to APCO for approval.  The State
agency could enter into a contract with an outside individual, agency, or firm to perform
portions of the project as approved by APCO.

        In  reviewing project proposals, APCO considered:

        1.  The potential effectiveness of the proposed method, or combination of methods,
           in extinguishing fires and preventing reignition.

        2.  The probable applicability of the proposed method, or combination of methods,
           to fires in piles with substantially different physical and chemical character-
           istics or types of locations from the one in which the proposed project was
           conducted.

        3.  The possible air pollution, water pollution, and physical danger that might
           result from the demonstration.

        4.  The severity of the existing, fire-caused air pollution problem in the area
           where  the demonstration was to be conducted.

        5.  The probable relative cost of the proposed  method as compared with other
           methods, based on:  (a) the level of subsequent maintenance costs, (b) the
           value of materials salvageable from the pile, and (c) the extent to which the
           method would result in,  or facilitate restoration of, usable land.

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        Opinions and recommendations on specific project proposals were solicited from
members of the Appalachian Regional Commission and other agencies that had specific
interest in such projects and from qualified professionals at universities, in other Federal
agencies, and in private industry.

        Applications for grants were required to include the following information:

        1. A general description of the proposed project including an explanation of the
           theory on which the method was based and, based on previous use, a report
           of the effectiveness, cost, and applicability of the method.

        2. A description of the bank where the proposed demonstration would be con-
           ducted, including the dimensions, the physical and chemical characteristics,
           the status of the fire, the topography,  the proximity to populated areas, and
           the name of the owner.

        3. A detailed description of how the project would be carried out, the portion of
           the fire to be controlled, the personnel and equipment to be  employed, the
           period of time to be required, and the methods to be used to measure the
           effectiveness of the demonstration.

        4. The cost of the project,  including a budget showing the distribution of costs
           for personnel,  equipment,  supplies, and other needs; the portions to be con-
           ducted by contract services; and the proposed Federal and non-Federal con-
           tributions to the project.

        Grantees were required to keep appropriate records of expenditures for audit
purposes.  They also  submitted periodic progress and expenditure reports and a compre-
hensive final report of the project.  The cost of the final report was included in the project
budget.

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     4.   FACTORS INFLUENCING  SELECTION  OF CONTROL METHODS


        A 1963 Bureau of Mines survey disclosed that 40 percent of the burning culm
banks in the United States were within 1 mile of a town.  In some sections of the anthracite
region of Pennsylvania, large burning banks are within city limits. The proximity of
these banks to population centers is an added constraint in the selection of the method
used to extinguish the flames. In several instances, the tested methods revealed poten-
tially dangerous side effects that would reduce their value in heavily populated areas.  At
one demonstration site, mist from water monitors settled on a section of an interstate
highway; during winter operations, ice formed an unanticipated traffic hazard.

        Successful methods of extinguishing burning banks usually require that the pile
location be accessible to heavy equipment and that adequate space surround the pile to
permit rehandling the extinguished material.

        An ample water supply is a primary requirement of most methods for  extinguish-
ing burning culm banks. The size of the bank and the type of control method  chosen
usually determine the quantities of water required.  With the exception of the  sealing pr .--
jects at Tuscarora, Pa.,  some water was used in each of the projects to cool the bank for
further work, to carry grouting material, or to douse the fire.

        The use of large volumes of highly acidic water usually requires additional neu-
tralization techniques to protect pumps and pilelines against corrosion.  In addition to
these techniques, the Huber and Marvin projects (appendices A. 14 and A. 15)  required
the construction of storage  reservoirs to collect the  run-off water for reuse and to prevent
stream pollution.

        The wide diversity of coal-refuse-bank  sizes, shapes, compositions,  and loca-
tions makes selection of a universally desirable control method impossible. The ultimate
selection of a method will depend upon all of the  foregoing physical considerations and
upon economic factors, such as cost and potential end use  of the reclaimed land.

4.1 PHYSICAL REQUIREMENTS

        A mechanical-hydraulic method would be the logical choice for the control of
burning culm banks that  are in close proximity to densely  populated areas such as the
northern anthracite region  of Pennsylvania. Although mechanical-hydraulic methods
require ample space and  abundant water, they extinguish  the burning banks quickly and
completely and produce low, level piles of reduced volume.  Furthermore, these sites can
be developed as commercial and industrial locations.

        In contrast to the urban situation, the valleys and hills of the coal-producing
states are dotted with many small burning-coal-refuse banks that are usually  the only
source of air pollution in the immediate area. Because of the topography, access is often
difficult and sufficient water is not easily available;  therefore,  sealing with natural cover
would probably be the chosen control method in the  majority of cases. Although sealing
is neither as quick nor as complete as mechanical-hydraulic methods in extinguishing
burning banks, the projects in which it was demonstrated  produced dramatic  effects upon

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 local air pollution - at 30 to 50 percent of the unit cost of mechanical-hydraulic methods.
 The sealing method appears to be effective if enough cover material is applied initially,
 and if adequate maintenance is provided to repair erosion damage that may otherwise
 destroy the seal.

        Where natural or mine-by-product cover is not available for adequate sealing,
 other cover material, such as plastic foam, will have to be employed at a much higher
 unit cost.

        In some applications, grouting by the "Fails Slope" method may also be employed
 either separately or in combination with a refuse-limestone seal.  The limestone grout and
 seal not only completely extinguish the burning material but effectively neutralize run-off
 water that might otherwise become highly acidic after percolating through the burning
 bank.

 4.2 ECONOMIC CONSIDERATIONS

        Mechanical-hydraulic methods were most successful in completely extinguishing
 culm-bank fires at moderate unit costs of $0.66 to $2.19 per cubic yard of material
 treated.

        Some of the sealing methods yielded low unit costs ranging from $0.20 to $1.04 per
 cubic yard of material treated, but were not successful in completely extinguishing the
 fires.  The sealing project at Iselin, Pa.  (Table 1) appears to have successfully extin-
 guished the fire but at a relatively high unit cost of $3 .36 per cubic yard of material
 treated.

        Three of the four grouting projects were not able to completely extinguish the
 fires and also had high unit costs of $1.50 to $6.51 per cubic yard.  The fourth project,
 however, at Fails Slope, Pa., appears to have extinguished the fire at an acceptable
 unit:cost of $1.25 per cubic yard of material treated.

        The 15 completed projects cost a total of $2,501,313, including contributions by
 the states, and processed 3,021,485 cubic yards of burning refuse for a unit cost of $0.83
 per cubic yard of material treated.  Seven of these projects demonstrated the  capability of
 completely extinguishing the fires.  Two of the techniques (projects 66A-4101D and 66A-
 4108D) had attendant side effects that would preclude their use in densely populated areas,
 however. Excluding the Gypsy project, the remaining seven projects extinguished
 1,480,563 cubic yards of burning refuse at a total cost of $886,470 for a unit cost of
 $0.601 per cubic yard of material treated.
10

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                               5.   REFERENCES
1.  McNay, L. M.  Coal Refuse Fires, an Environmental Hazard.  U.S. Bureau of Mines,
    Department of the Interior, Washington, D. C. Information Circular 8515.  1971.

2.  Pennsylvania Anthracite Refuse, A Survey of Solid Waste from Mining and Prepara-
    tion. U.S.  Bureau of Mines, Department of the Interior, Washington, D. C. Informa-
    tion Circular 8409.  1969.

3.  Luckie, P. T.  Operation Anthracite Refuse.  Earth and Mineral Sciences 39(3): 20-21,
    December 1969.

4.  Metals, Minerals and Fuels. Minerals Yearbook. U.S. Department of Interior, Bureau
    of Mines, Washington, D. C. 1970.

5.  Lieitch, R.  D.  Some Information on Extinguishing an Anthracite Refuse-Bank Fire
    near Mahoney City, Pennsylvania. U.S. Bureau of Mines, Department of the Interior,
    Washington, D. C.  Information Circular 8209. 1964.

6.  Stahl, R. W. Survey of Burning Coal-Mine Refuse Banks. U.S.  Bureau of Mines,
    Department of the Interior, Washington, D. C. Information Circular 8209.  1964.

7.  Pfeiffer, J.  J., E. M. Murphy,  and F. E. Griffith.  Ignition and Control of Burning
    Coal-Mine Refuse.  U.S. Bureau of Mines, Department of the  Interior, Washington,
    D.  C.  Report of Investigation 6758.  1966.
                                        11

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                                APPENDIX.

               SUMMARIES OF DEMONSTRATION PROJECTS
                   FUNDED BY APCO  1966  TO  1968

    The 15 projects described individually in this appendix are grouped according
to the method used to extinguish the fires. Grouting was the primary method in projects
described in appendices A.I through A.4, sealing in appendices A.5 through A.9, and
mechanical-hydraulic in A. 10 through A. 15.

NOTE:  Mention of a specific product or company name does not constitute endorsement
by the Environmental Protection Agency.
                                    13

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                        A.I   MANCHESTER,  KENTUCKY
PROJECT NUMBER:    66A-2001D.

TERM OF PROJECT:   July 1, 1967 to November 18, 1968.

OBJECTIVES:

1.   To determine which of four laboratory slurry mixtures would be most suitable for
    large-scale grouting to extinguish culm-bank fires.

2.   To demonstrate that the latent heat could be removed from a burning  pile and the flow
    of oxygen to the interior of the pile diminished, or stopped, by grouting with a mix-
    ture of vermiculite,  sodium bicarbonate, and limestone; and by using the same grout
    mixture with a copolymer resin added to provide stability and to seal the surface.

3.   To determine the effectiveness of the demonstration by comparing temperature pro-
    files taken before, during, and after the grouting operation.

GRANTEE:    The Commonwealth of Kentucky, Air Pollution  Control Commission.

CONTRACTOR:   Melpar, Inc., 7700 Arlington Boulevard, Falls Church, Virginia.

FUNDS ALLOCATED:    Federal funds             $101,850.00
                       State services               44,654.13
                             Total                $146,504.13

COST PER CUBIC YARD:   $6.51 (22, 508 cubic yards) .

STATUS AT LAST INSPECTION:   (Oct. 29, 1968) - The contractor's field work was
completed. Visible emissions and open flames in one area showed that the piles were
not effectively extinguished.

BACKGROUND:  The refuse bank near Manchester, Ky. , is an actively burning bank
used by the Shamrock Coal Company for waste disposal.  The bank  was selected because
it was creating an air pollution problem in the area, was of an appropriate size for the
demonstration, was reasonably accessible, and was near a stream.  The Federal  share
of the allocated funds was used to pay for the contract work performed by Melpar, Inc.
The State portion of the funds was used to pay for the services of the Kentucky Air
Pollution Control Commission personnel who monitored the project,  performed a sulfa-
tion survey in the project area, and maintained a temperature monitoring program for
1 year after the completion of the contract work.

METHOD:   A front-end loader was used to level and compact the tops of three distinct
culm piles at the site;  additional dirt was added in the areas where  the original mantle
had been disturbed. A total of 371 holes were drilled around the periphery of the piles
in  4 concentric rows to depths of 20, 15, 10, and 20 feet, from outer to inner row.  A
1.25-inch  steel pipe was  inserted in each hole to facilitate temperature monitoring and
grouting.   The pipes were capped to prevent the emission of gases from the piles and to
help prevent chimneys from forming within the piles.


                                         15

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        Selection of the grouting mixture was based on extinguishment tests conducted
with a small quantity of coal-refuse pile material, on freight and material costs, and on
handling characteristics of the mixtures. Mixture 1 was composed by weight of vermicu-
lite, 40 percent; sodium bicarbonate, 30 percent; and limestone dust, 30 percent.  Mix-
ture 2 was composed of shale dust,  40 percent; sodium bicarbonate, 20 percent; fly ash,
30 percent; and fine sand, 10 percent.  Mixture 3 was composed of vermiculite, 20 percent,
sodium bicarbonate, 20 percent; Fuller's Earth, 20 percent; Epsom salt, 10 percent;
Borax, 10 percent;  gypsum, 10 percent; and coal fines, 10 percent.  Mixture 4 was com-
posed of vermiculite, 20 percent; sodium bicarbonate,  20 percent; fly ash, 30 percent;
shale dust, 20 percent; and limestone dust, 10 percent. Mixtures 1,2,  and 4 were
fairly comparable in cost but because shale dust, which was needed in mixtures 2 and 4,
was not commercially available,  mixture 1 was used for the rest of the project.

        Grouting and sealing began on November 22, 1967, and was completed on Decem-
ber 14, 1967.  In the initial phase, piles I and III were grouted and piles II and III were
surface sealed.   The surface sealing mixture was composed by weight of  37.50 percent
texpanded vermiculite, 31.25 percent sodium bicarbonate,  and 31.25 percent limestone
-dust.

        A  total of 597,400 pounds of chemicals was used for the internal grouting of the
;piles, and 33,630 pounds were used for the surface sealing.

        Temperatures were monitored from July 1, 1967,  to November 18, 1967. The
^highest temperature recorded was 1290 °F.  Temperatures were monitored intermittently
cduring the grouting period.  Piles I and II were extinguished to some degree, as evidenced
:by  a sharp decrease in temperature, but the grouting had little effect on temperature in
pile HI.

        Starting on January 10, 1968, 1 month after sealing,  the piles were monitored
"for 5  days  a week for a period of 60 days.  The temperature decreased significantly imme-
diately after grouting; however,  approximately  72 hours after the start of  temperature
monitoring the internal temperatures started increasing and eventually reached 1030 °F  in
pile I.  Piles II and III  stabilized at approximately 400 °F.  In April 1968, pile II was
grouted internallv and a surface seal was applied to pile I. The west bank of pile I was
regrouted to extinguish hot spots.  Piles II  and III were given another surface seal at that
time.

        The contractor's final temperature monitoring, conducted between April 24 and
June  26, 1968, showed that the second grouting  and sealing operation had little effect on
extinguishing the fire.  Spots with temperatures as high as 920 °F were measured in pile
I.   Temperatures in areas of pile III had increased to as high as 990 °F.  The temperature
of pile II remained relatively stable for the  longest period  after the second grouting and
sealing, but temperatures in portions of this pile had started increasing and were re-
corded as high as 620 °F.  The Kentucky Air Pollution Commission continued to monitor
the condition and temperature of the project on a monthly basis  and to conduct the sulfa-
tion survey of the area until June 1969.

COMMENT AND EVALUATION:  The project was not successful in extinguishing the
burning culm bank at Manchester, Kentucky,  and unit extinguishment cost appears
excessively high.   The approach used in this  demonstration proved satisfactory under
ideal, controlled conditions;  however, culm banks rarely  exist under ideal conditions.
The project may have been more successful had the demonstration area been isolated from
the working bank,  which was also burning.
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                       A.2   HESHBON,  PENNSYLVANIA
PROJECT NUMBER:   66A-4103D.

TERM OF PROJECT:  July 1, 1966 to September 30, 1968.

OBJECTIVES:

1.   To investigate the technical feasibility of extinguishing coal-refuse-bank fires by
    grouting the fire area with a mixture of vermiculite, sodium bicarbonate, limestone
    dust, and resin.

2.   To prevent rekindling of the fire by covering the extinguished bank with a premixed
    slurry of the grout.

GRANTEE:   The Commonwealth of Pennsylvania,  Department of Mines and Mineral
Industries.

CONTRACTOR:   Melpar, Inc., Falls Church, Virginia.

FUNDS ALLOCATED:     Federal funds             $133,873.80
                        State services               10,500.00
                        State funds                  34,124.60
                            Total                $178,498.40

COST PER CUBIC YARD:   $1. 50 (118, 755 cubic yards) .

STATUS AT LAST INSPECTION:   (July 1969) - Steam was emanating from surface cracks
on pile I.  Pile II appeared dormant. The surface covering had entirely washed off the
sides of both piles.

BACKGROUND:   The Heshbon bank, owned by the Pennsylvania Coal and Coke Company,
is located less than 1 mile from the'town of Heshbon,  Pa.  The bank is about 1,000 feet long
and is divided into 3 piles  by 2 run-off gullies; only two of the piles, containing  79,170
cubic yards and 39, 585 cubic yards of material, respectively, were used for the project.
The site was selected by Melpar and the Pennsylvania Department of Mines and Mineral
Industries.

METHOD:   After the top surfaces of the piles were leveled, four concentric rows  of 3-
inch-diameter holes were drilled around the top edge of each pile to depths of 20, 15,  10,
and 20 feet from outermost  to innermost row.  Steel pipes, 1.25 inches in inside diameter
and beveled at the bottom to aid the flow of grout, were inserted to maintain the openings.
Each hole in the first row and every fifth hole in the fourth row were used only for tem-
perature monitoring and were 25 feet apart.  A total of 384 holes were placed in the piles.

        Approximately 670,000 pounds of grout that consisted by weight of 70 percent
unexpanded vermiculite, 20 percent sodium bicarbonate,  and 10 percent limestone dust
was mixed with 140 gallons of water and pumped into the pipes at a rate of 25 gallons per
minute (gal/min) at 130 psig .


                                         17

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        The reasons for including particular ingredients in the grout mixture were:

        1.  Water to serve as a vehicle for the suspension and transport of the solid com-
            ponents and to participate in extinguishing the fires by dissipating much of the
            heat.

        2.  Sodium bicarbonate to decompose in the heat of the fire and produce carbon
            dioxide.

        3.  Powdered limestone to inhibit air flow by filling the void spaces in the pile and
            to neutralize any acid water that might form during the grouting operation.

        4.  Unexpanded vermiculite to supplement the limestone as a filler and, by expan-
            sion on exposure to heat, to more completely fill the void spaces and further
            impede the flow of air to the fire.

        The external covering mixture consisted of 60 pounds of expanded vermiculite,
100 pounds  of unexpanded vermiculite, 40 pounds of limestone dust, and 3.75 pounds of
copolymer resin in water.  A total of 197,000 pounds of the mixture was applied  to the pile
in April and June of 1968.

        Temperature measurements were taken before grouting, immediately after grouting,
and after the surface covering was applied.

COMMENT AND EVALUATION:  Although this pile was not entirely extinguished, visual
and gaseous emissions have been greatly  reduced. The temperature measurements taken
monthly from August 1968 to March 1969 indicated a slight increase near one thermoprobe
(386 °F in March  1969);  several other spots in the pile were near the 200 °F level.

        The surface covering used did not resist weathering as well as anticipated and
will not be repeated on future projects.

        The budget for this project contained a relatively large expenditure for "engineer-
ing, monitoring,  and temperature measurements."  This $10,000 expenditure added to the
contractor's cost  for drilling and  grouting results in a cost of $57,130 for the grouting
phase.  The cost  per cubic yard of material treated for this project was $0.48.
18

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                       A.3   HESHBON, PENNSYLVANIA
PROJECT NUMBER:  66A-4104D.

TERM OF PROJECT:   July 1, 1966 to November 1,  1968.

OBJECTIVES:

1. To demonstrate the effectiveness of the neutralization product of acidic mine water •
   (yellow boy) as a grout and covering material to extinguish burning coal-refuse
   piles.

2. To build and demonstrate a small acid-mine-water neutralization facility.

GRANTEE: The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:  Melpar, Inc., Falls Church, Virginia.

FUNDS ALLOCATED:     Federal funds             $34,177.50
                        State  funds                '  8,392.50
                        State  services               3,000.00
                             Total                 $45,570.00

COST PER CUBIC YARD:  $4.42 (10,300 cubic yards).

STATUS AT LAST INSPECTION:   (Dec. 31, 1970) - Project was not successful. Contrac-
tors were unable to carry out project to full extent. The State planned additional work in
Spring 1971.

BACKGROUND:   The pile is adjacent to the larger refuse piles at Heshbon,  Pa. ,  that are
described in project 66A-4103D. The bank was chosen because of its small  size and its
proximity to a stream of highly acidic mine water.

        The neutralization  of acidic mine water with lime or limestone produces a complex
precipitate of calcium sulfate and hydrated ferric oxide. This material, known colloqui-
ally as yellow boy,  is collected in basins that must be dredged periodically  to maintain
sufficient room for further neutralization.  An estimated 60 to 80 tons of yellow boy are
produced by the neutralization of 1 million gallons of acidic mine water.  Disposal of the
material without polluting the streams has become a problem in western Pennsylvania.

METHOD:   After the top surface of the  pile was leveled, four rows of 3-inch-diameter
holes,  5 feet apart,  were drilled in the north  perimeter of the pile. Pipes,  1.25 inches in
interior diameter and beveled at the bottom to aid  the flow of grout, were inserted into
the holes.  The outermost row of holes, drilled as close as possible to the top edge, was
20 feet deep, the third row  15 feet deep, the second row 10 feet, and the first (innermost)
row 20 feet. In all but the first row, holes were placed at 5-foot intervals.  Each hole in
the first row and every fifth hole in the fourth row were used for thermometry; thus, the
temperature monitoring  holes were 25 feet apart.
                                         19

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        A small neutralization facility was constructed near a small stream of highly
acidic mine water.  Yellow boy production began in July 1968. The pile was grouted in
August and the cover was applied during September 1968.

COMMENT AND EVALUATION:   This project was not successful because slow production
of the neutralization product limited the grout slurry to only 4 to 5 percent solids.  In
addition,  the area of the pile that was grouted was not hot enough to solidify the grout.
Grout should be at least 15 percent solids and the internal pile temperature at least
1000 °F.

        The prototype neutralization facility, however, worked well with  lime and lime-
stone addition and could serve as  a model that could be built by the states  on other
streams in the coal regions.  The  contractor has also done preliminary work on a mobile
neutralizer  that could be easily moved about on  a stream or watershed.

        The cost of the neutralization represented a major portion of this project
($21,595) .  The cost of the grouting and monitoring was approximately $23,875. If the
$3,000 for state services is excluded, the cost of treating the pile was  approximately
$20,875, a unit cost of $2.03 per cubic yard.

        Because of the relatively  high unit cost compared with other methods, this
method will probably not be used  unless the cost of disposing of yellow boy becomes high
enough to offset part of the grouting cost.
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                      A.4   SHAMOKIN,  PENNSYLVANIA
PROJECT NUMBER:  67A-4112D.

TERM OF PROJECT:  August 1, 1967 to September 30, 1969.

OBJECTIVES:

1. To determine the effectiveness of a limestone-water-slurry grout for extinguishing
   fires  on and within a coal-refuse bank.

2. To keep accurate records in order to develop unit costs for the various operations.

GRANTEE:  The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR: Drew Development Co., RD #2, Box 796, Pottsville, Pennsylvania.


FUNDS ALLOCATED:    Federal funds             $30,000
                       State funds                5,922
                       State services              4,078
                            Total                $40,000


COST PER CUBIC YARD:   $1.25.

STATUS AT LAST INSPECTION:   (Dec. 31,  1970) - Project was completely successful.

BACKGROUND:   The bank, known as the Fails Slope Pile, is on the property of the
Rossini Coal Company in Carbon Township,  Pa.  No fresh refuse has been added since
the fire was discovered. The bank has been the source of noxious fumes since the onset
of active burning.

METHOD:   All vegetation was removed from the base of the pile to isolate the test area
from other coal refuse in the vicinity.  The top of the pile was graded to a concave sur-
face and flooded  with water. Grouting operations began after the surface had cooled and
dried enough to permit equipment to operate.  A modified hydroseeder was used to mix
the water-limestone slurry.  Best results were obtained with a mixture of 4 pounds of
limestone per gallon of water at an injection  pressure of 50 psi. Injection pipes, 1 inch
in diameter, were cut into  4-foot lengths, threaded on both ends for coupling with
standard ferrule and driven to the bottom of the bank by a backhoe.

        A rivet head completely sealed the end of the pipe to prevent intrusion by bank
material. After reaching bottom, the pipe was withdrawn a few inches to permit the
loose rivet to drop out and provide  an open end for injection.  Injection proceeded to
refusal; the pipe was withdrawn; a 4-foot section was removed; and injection resumed.
This procedure was followed on each injection well from the bottom of the well to the
surface of the bank.
                                        21

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        During the project, 392 injection holes were grouted with 947 tons of pulverized
limestone mixed with approximately 474,000 gallons of water.  An additional 510,000
gallons of water was used to suppress fires on the surface of the bank during the flooding
operation and injection period.

COMMENT AND EVALUATION:  Final data that would permit complete evaluation of this
project are not available.  Ultimate extinguishment seems possible because (1) the entire
pile was  grouted, not just the periphery as in projects 66A-2001D, and (2) by withdraw-
ing the probes in 4-foot sections, the greater part of the pile was grouted, not just the
volumes  adjacent to the  ends  of the pipes.

        The cost for this project was the lowest of the grouting methods. Less the State
monitoring charges, the cost per cubic yard was approximately $1.12. Competitive bid-
ding on future projects  could reduce unit costs to approximately $1.00 per cubic yard.

        It is unlikely that many of the older, smaller, burning banks will lend themselves
to this method because the older banks frequently contain clinkers and fused culm,  which
require drilling and do  not allow the grout pipes to be driven by a backhoe.
22

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                    A.5   CARROLLTOWN,  PENNSYLVANIA


PROJECT NUMBER:  66A-4102D.

TERM OF PROJECT:  June 1, 1966 to September 30,  1967.

OBJECTIVE:

        To demonstrate the feasibility of bringing a burning culm bank under control
with a three-phase combination of grouting and sealing techniques:

        Phase 1.   Injection of chemicals to extinguish and/or prevent the spread of
                        active combustion in the pile.

        Phase 2.   Injection of a nitrogen-gas-purge flow into the pile to displace air and
                        extinguish the fire.

        Phase 3.   Application of plastic foam to the surface of the pile to seal out air and
                        stop combustion in coordination with phase 2.

GRANTEE:   Commonwealth of Pennsylvania, Department of Mines and Mineral Industries .

CONTRACTOR:  Gallery Chemical Company, Gallery, Pa.

FUNDS ALLOCATED:     Federal  funds             $117,098.25
                        State funds                 24,532.75
                        State services               14,490.00
                            Total                $156,131.00


COST PER CUBIC YARD:  $1.04  (150,000 cubic yards).

STATUS AT LAST INSPECTION:  (December  21,  1970)  - Various hot spots  broke out
because of voids  in the foa~m seal.  A contract issued to repair the voids was
successful.

BACKGROUND:    The bank,  owned by the Barnes  and Tucker Coal Company, is
located in West Carrolltownship,  Cambria County, Pa.  The pile contained approxi-
mately 150,000 cubic yards of burning  refuse and was estimated to be 500 feet long, 300
feet wide, and 65 feet high at its highest point. The pile is situated at the head of a
small, steep valley about 0.3-mile above the village of Bakerton; gaseous emissions,
which tend to follow the valley slope downhill to the village,  cause numerous complaints.

METHODS:   The site was prepared by constructing  an earth pond to collect mine
water and a loamy-clay-filled trench  to serve as a fire-stop.  An estimated 4.1
million gallons  of quenching  water was applied during 24  days  of continuous sprink-
ling  and lancing.  During  the  final days  of the watering,  and for  1 month  afterwards,
the bank was terraced and benched,  and 57 thermowells were installed.
                                        23

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        Air pollution testing equipment was installed at the beginning of phase 1, which
began one month after watering had been stopped.  During the 8-day period, two test
areas were injected with CWS (proprietary chemical):   the same two areas were covered
with polyurethane foam 10 and 16 days later, respectively.  Phase 2 began 1 month after
the phase 1 holes had been covered.  An estimated 5,450 cubic yards of pile material
was injected with nitrogen and purged in 1 month.  At the same time, the polyurethane
foam covering was applied over an estimated 14,700 square yards of the  pile leaving the
top of the pile open to allow gases to escape. Five months later, damaged foam had to
be removed; the area was then requenched and foam was  reapplied.

COMMENT AND EVALUATION:   The results of the first two phases,  chemical treat-
ment  of hot spots and  the nitrogen purge, were inconclusive but did  not warrent
further study.  The use of polyurethane foam (phase 3), however, was demonstrated
as a  conditionally effective method for  sealing burning  refuse banks:   most of the
bank  is still sealed in testimony to  this fact.

        The foam-seal method can find its major  field of  application in  areas  where
water is scarce and the  terrain  is difficult:   qualifications  that apply to many small
banks in  Pennsylvania.

        Although  none of the objectives of the Carrolltown  project were successfully
demonstrated,  this project pointed up the importance of thorough pile preparation  and
induced the contractor to adopt  a low-profile pile for his next project rather  than
continue with the terraced configuration.  A  secondary finding was the  limited  value
of shallow, widely spaced  thermowells  for monitoring hot spots in piles greater  than
40 feet in  depth.   The burn-off of a large portion of the foam at one  end of the pile
demonstrated  that a substantial  hot  zone remained deep within the pile,  but none of
the thermowells indicated this heat.  Probes  driven  horizontally into  the pile from
the terrace, however,  indicated temperatures over 752  CF at depths of 1 to 2  feet
below the  surface.  This phenomena suggests that thermowells  have limited value
unless they are spaced at  less than 10-foot intervals and at depths of at least 20 feet.
It is doubtful  that piles 200,000 cubic yards  or larger  can  be  monitored effectively
with thermowells alone.  Temperature monitoring would also appear to  be  quite
difficult on piles that are more  than 40 feet  deep.  Not only would it require expen-
sive drilling to make adequate holes for the thermowells, but the  additional chimneys
created by the  drilling would frustrate the purpose  of  a sealing program.   Data on
the temperature history after sealing are not available.

        Air-quality measurements are not complete primarily because the equipment
was not on the site early enough to record background levels. Sulfur dioxide levels
were  reduced  after the pile  was sealed; average hydrogen sulfide concentrations stayed
about the same,  but  the occurrence and magnitude of short-term hydrogen sulfide concen-
trations increased.  In the absence of background readings, the significance of these
single point readings is open to question.

        The polyurethane foam sealing method yields a unit cost of $1.04 per cubic yard
based on an estimated total cost of $72,162 to extinguish 150,000 cubic yards of material.
The foam seal method could prove valuable in sealing banks at a relatively modest cost.
24

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                     A.6   TUSCARORA,  PENNSYLVANIA

PROJECT NUMBER:   66A-4107D.

TERM OF PROJECT:  August 1, 1966 to July 31, 1967.

OBJECTIVES:

1.   To determine whether the application of fine cement-industry waste would provide
    skin-deep protection against wind erosion and emission of fumes after the surface of
    a culm-bank had been water stabilized.

2.   To determine if the underlying dust would retain its semifluid, self-sealing charac-
    teristics and contribute to the  extinguishment of the fire over a period of time.

3.   To determine the economy of the waste-cement-dust method.

GRANTEE:   The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:  Drew Development Company, Pottsville, Pa.

FUNDS ALLOCATED:      Federal funds             $81.220.00
                        State funds                 16,573.45
                        State services               10,500.00
                            Total                 $108.293.45

COST PER CUBIC YARD:  $0.28 (384,673 cubic yards).

STATUS AT LAST INSPECTION:  (April 24, 1969) - The major portion of the pile was
adequately  covered with cement dust.  A small hot area appeared to be forming near the
rim at the north edge of the pile.  The seeding had taken root on about 30 percent of the
pile.  The cement-dust seal on the top of the pile was intact and grass was beginning to
grow.  (December 31, 1970)  - Project proved completely successful.

BACKGROUND:  The Mary-D Colliery Bank is located on the valley floor less than 0.25-
mile from the village of Mary-D. The town of Tuscarora, for which the bank constituted
a serious air pollution problem, is located 0.5-mile from the bank.

        The pile estimated to contain 796,000 cubic yards of material is approximately
1,600 feet long, 1,000 feet wide and varies  between 40 and 60 feet in depth.  The portion
treated during this project contained 384,673 cubic yards of material;  the balance was
treated under project 67A-4110D .

METHOD:   The eastern portion of  the bank was graded and shaped by bulldozers, and
two banks were separated by an 8- to 12-foot wide trench, which was backfilled with
incombustible sandy loam. Because the gradients were too steep to permit covering with
cement dust,  the northern and southern slopes were covered with sandy loam to depths
of between  3 and 8 feet.  A heavy rim of loam was constructed around the circumference
of the bank to provide a retainer for the cement dust.  A 12-inch layer of cement dust was
                                        25

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 spread using a bulldozer supplemented by hand labor for fine grading and sprayed with
 water.  A total of 183,600 cubic feet of cement dust was applied to the top of the bank.

 COMMENT AND EVALUATION:   The low cost of this method is perhaps its greatest attrac-
 tion. The easy accessibility of side-covering material was the major factor in this pro-
 ject's low unit cost. Several other burning banks in the southern anthracite field could
 be treated in a similar manner.

        The mantle of sandy loam and the cement dust proved to be an efficient filter for
 the gaseous emissions at the site. Unless one stands directly over a hot spot, it is diffi-
 cult to detect any odor, and there are no  visible emissions.

        On April 24, 1969, there had been some erosion on the north face of the bank and
 a hot-spot had  developed near the rim at  the center of the bank.  This hot-spot probably
 existed in 1968, but became more active because of the increased air permitted to  enter
 the pile by erosion gullies.
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                  A.7   ALLEN  JUNCTION,  WEST VIRGINIA

PROJECT NUMBER:   66A-5301D.

TERM OF PROJECT:  July 1, 1966 to December 31, 1968.

OBJECTIVES:

1.  To demonstrate whether the sides of a refuse bank could be effectively sealed using
    a spray-on, self-curing asphaltic emulsion. Fillers consisting of inert material such
    as fly-ash, crushed native shale, asbestos,  or similar material were to be tested for
    their effectiveness.

2.  To determine the effectiveness of the seal and the degree of cooling in the pile by
    continuous temperature measurement.

GRANTEE:   West Virginia Air Pollution Control Commission, Charleston, West Virginia.

MAJOR CONTRACTOR:   West Virginia Air Pollution Control Commission.

FUNDS ALLOCATED:      Federal funds             $57,389.22
                        State funds                 5,200.00
                        State services              17,390.00
                            Total                $79,979.22

COST PER CUBIC YARD:  $0.20.

STATUS AT LAST INSPECTION:  (October 31, 1968) - Although the fire was not com-
pletely extinguished it was under control and emissions had been reduced.

BACKGROUND:  The use of heavy construction equipment for the abatement of emissions
from burning coal-refuse banks can be hazardous to both equipment and personnel.  In
addition, water supplies are frequently meager in the immediate area around many burn-
ing coal banks.  The State of West Virginia, therefore, proposed to develop and test a
low-cost method for sealing burning banks that involved minimal use  of heavy equipment
and water.

        A coal-refuse pile covering approximately 8  acres near Allen Junction, W. Va.,
was selected for this project. The pile, owned by the Amigo Smokeless Coal  Company,
contained approximately 410,000 cubic yards of material. At the beginning of the project,
all sides were burning .

METHOD:   The top of the pile was leveled by a bulldozer. Fresh fine-coal refuse was
spread on the top of the pile and over part of one side where erosion gullies had formed.
The level areas were then compacted with a six-tire highway roller.

        Spraying operations were conducted in December 1966, from  August to December
1967,  arid from July to October 1968. The equipment used consisted of a commercial
"Refract All" rig with a wet-mix gun, a 125-ftVmin portable air compressor and a gaso-
                                        27

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line-driven water pump rated at 49 gal/min at 80 psi.  Three different sealant mixtures
were used.  The cover mixture was composed by weight of 49 percent sand,  14 percent
fly ash, 3 percent asbestos cement,  24 percent emulsion asphalt, and 10 percent water.
The asbestos mixture was composed by weight of 9 percent fly ash,  21 percent asbestos
cement, and 70 percent water.  The filler mixture was composed by  weight of 63 percent
fly ash, 12 percent emulsion asphalt,  and 25 percent water.

        The asbestos and filler mixtures were applied to the burning coal refuse pile
first in order to insulate the cover mixture from the fire and heat.  The asbestos mixture
was used over the hotter areas of the pile.

COMMENT AND EVALUATION:   The water-emulsified-asphalt base sealer was only par-
tially successful in extinguishing the fire.  Temperatures were significantly reduced at
many points, but the continuous settling of the pile cracked the seals, despite several
applications.  Observations made since  the completion of spraying operations indicated
that several hot zones existed within the pile and probably would not cool without the
application of more sealant and/or redressing the pile in the immediate area  of the hot
spots.

        The unit cost of $0.20 per cubic yard is 28 percent lower than the $0.28 per cubic
yard  developed at Tuscarora, Pa. (project 66A-4107D) .  Although the projects are not
directly comparable, they both involved sealing the exterior of the pile to cut off the
oxygen supply to the burning zones in the interior of the bank.  In the case of Tuscarora,
the top of the bank was also covered.

        Many burning banks in West  Virginia could be controlled using a water emulsion
of asphalt, fly ash, or sand as a sealant if sufficient preparation work is done on the
piles  before the sealant is applied.  The Iselin, Pa. , project (67A-4112D)  demonstrated
the importance of thorough preparation  of the surface of the pile.

        The relatively low cost of this method will undoubtedly appeal to mine operators
as a preventive measure against possible fires in their active refuse piles. The method
would abort or postpone active burning  until more comprehensive control measures
could be undertaken.
28

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                     A.8   TUSCARORA,  PENNSYLVANIA
PROJECT NUMBER:   67A-4110D.

TERM OF PROJECT:  July 1, 1967 to September 30, 1968.

OBJECTIVE:

        To determine whether the application of fine limestone  (quarry screening) to a
        burning culm pile would provide skin-deep protection  against wind and water
        erosion and smother the burning portions of the fire.

GRANTEE:   The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:   Drew Development Company, Pottsville, Pennsylvania.

FUNDS ALLOCATED:     Federal funds            $128,621.25
                       State  funds                  34,373.75
                       State  services                8,500.00
                            Total                $171,495.00

COST PER CUBIC YARD:   $0.45 (384,327 cubic yards) .

STATUS AT LAST INSPECTION:  (December 31,  1970)  - Bank was sealed and success-
fully planted with grass.

BACKGROUND:   The Mary-D Colliery Bank, located on the valley floor less than 0.25-
mile from the village of Mary-D, Pa., constituted a serious air pollution problem for
Tuscarora, Pa.  The pile containing approximately 769,000 cubic yards of material is
approximately 1,600 feet long,  1,000 feet wide, and varies between 40 and 60 feet  in
depth. The western portion of the bank, which was treated during this project, contains
384,327 cubic yards:  the balance of the bank was treated under project 66A-4107D.

METHOD:   The western portion of the bank was graded and shaped by bulldozers, and
the southern side and part of the western end were covered with sandy loam from  an
adjacent strip bank.  Quarry screening was hauled to the project site by  truck and was
pushed to the edge of the pile by bulldozer. Final grading on the sides of the pile was
done by hand.  The mantle is approximately 2- to 3-feet deep on the sides and 1.5- to
3.0-feet deep on the top of the pile. Extra covering was placed over  and  near known hot
spots.  Several tons of limestone quarry screening were used to cover the pile.  When
final grading was completed, the entire project'area was hydroseeded.

COMMENT AND EVALUATION:  The major portion of this pile appears to  be dormant,
but, in the absence of temperature probes,  it is impossible to determine whether this is
actually the case. The cooling  process may take  several years, but, if the areas of
erosion are promptly  repaired, hot spots in the pile will eventually go out.  The mantle
of limestone quarry screenings has proved  to be an effective filter for the gaseous emis-
sions:  odors are only detected when standing  directly  over a hot spot. Surprisingly,
                                        29

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 this odor is not hydrogen sulfide or sulfur dioxide as might be expected, but a combina-
 tion of phenol and ammonia.

         The unit cost of this method is moderately low compared with other methods of
 extinguishing culm-bank fires.  Because limestone quarries are widely distributed in
 Pennsylvania and other states that have many coal-refuse piles, the technique will
 probably be widely used.
30

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                        A.9   ISELIN,  PENNSYLVANIA
PROJECT NUMBER:   67A-4111D.

TERM OF PROJECT:  July 1, 1967 to September 30, 1969.

OBJECTIVE:

1.  To study and compare various seal systems and procedures for extinguishing culm-
    bank fires.

2.  To grade and shape the pile into a low profile.

3.  To evaluate the  effectiveness of surface stabilization and foam reinforcement.

GRANTEE:   The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:  Gallery Chemical Company, Gallery, Pennsylvania.

FUNDS ALLOCATED:    Federal funds             $126,066
                       State funds                 33,524
                       State services                8,500
                            Total                $168,090

COST PER CUBIC YARD:   $3.36 (50,000 cubic yards) .

STATUS AT LAST INSPECTION:   (December 31,  1970) - The foam seal had weathered;
project was not completely successful.

BACKGROUND:  The refuse bank located in Iselin, Pa. , is currently owned by, but has
been abandoned by, the Rochester and Pittsburgh Coal Company. The material in the
pile consisted primarily of breaker refuse and mine rock.  Approximately 4 acres of
material were burning in a slight ravine approximately 25 feet  above grade at it's highest
point.  Water for quenching was available from a nearby stream.


METHODS:   The pile was regraded and the actively burning areas were cooled and
partially quenched with water.  An earth-filled fire trench was placed on three sides of
the bank to prevent the fire from spreading to other potentially combustible portions of
the pile.  Fine red dog  (coal ash) and refuse was placed over the hot areas and compacted
by bulldozers and sheep-foot rollers.  The final configuration  of the pile resembled an
inverted saucer.  Thirty-five thermowells were placed in the pile to a depth of 14 feet.
This phase of the work required about 6 weeks.

        Several  10-square-foot test patches were prepared to test the  effectiveness of
calcium chloride and sodium silicate as soil stabilizers.  It was concluded that the use of
these chemicals on the entire pile was not justified.
                                        31

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        The polyurethane foam covering was applied during a 6-week period ending in
October 1968.  Two 2000-square-foot areas were foamed over two substrates - fiberglass
and burlap brattice cloth. The remaining portion of the pile was compacted with a small
road roller and foamed.  After the foam had been applied, 65 percent of the pile was
spray-coated with a tar-based coating that contained powdered aluminum.  The remaining
portion of the pile was sprayed with latex paint.

        Temperature measurements began in September  1968, and continued on a monthly
basis through September 1969.

COMMENT AND EVALUATION:  Air pollutant emissions have been eliminated from  this
refuse bank. Hot zones in the pile will probably go out eventually, if the foam seal
remains intact.

        The major problem was drainage;  heavy fall and winter rains and snow caused
the edges of the foam to lose its seal for several feet around the perimeter of the foam cap.
The contractor  repaired the seal, but better drainage control will be required on future
projects.

        Careful site preparation is  largely responsible for the success of this project.
The low profile of the pile not only facilitated the application of the foam, but minimized
the risk of air infiltration at the base.
32

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                       A.10   ASHLEY,  PENNSYLVANIA

PROJECT NUMBER:   66A-4101D.

TERM OF PROJECT:  April 15, 1966 to April  14, 1967.

OBJECTIVES:

1.  To determine the efficiency and economy  of water immersion and compaction by heavy
    equipment in reducing culm-bank material below combustion temperature and quench
    the fire.

2.  To determine if temperature of the material could be reduced below combustion tem-
    perature and to provide extinguishment by compaction through the use of heavy
    equipment.

3.  To keep accurate records on equipment utilization for moving or processing material
    to permit an accurate cost determination.

GRANTEE:   The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:   Dixon Contracting Company.

FUNDS ALLOCATED:     Federal funds            $259,125
                       State  funds                 71,875
                       State  services               14,500
                            Total                $354,500

COST PER CUBIC YARD:   $1.14  (304,000 cubic yards).

STATUS AT LAST INSPECTION:    (June 6, 1968) - The project area was partially
covered by compacted  refuse from project  68A-4113D,  which was completed June 6,
1968.  There was no evidence of heating in the pile and  no visible emissions.  The
remaining portions of the Huber Bank are  burning actively, however.

BACKGROUND:    The Huber  Bank complex, the largest burning coal-refuse  bank in
the anthracite region of Pennsylvania, has been actively burning since 1955  and is
the source of much of  the air pollution that periodically affects the towns of Ashley
and Wilkes-Barre.  Concurrent with this project,  a contract from  the Economic  Devel-
opment Administration, Department of Commerce, was  applied in an effort to reduce
smoke and dust during the excavation and quenching  phase with a fog nozzle on a
"water cannon" or "monitor."  The fog nozzle materially reduced the emission of
smoke and dust, and the direct stream from the water cannon effectively excavated
unconsolidated  bank  material.  This technique has been used in subsequent  projects,
including  project 68A-4113D,  as the major  method of excavation.   The Pennsylvania
Department of Health, Division of Air Pollution,  made  air-quality measurements  in the
town of Ashley and in  the vicinity of the bank during May  and June 1966 and from
December  1966  through February 1967. Sulfur dioxide was measured  with lead-
                                        33

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peroxide candles and a Thomas autometer.  A tape-sampler was used to measure the
levels  of hydrogen sulfide.

COMMENT AND EVALUATION:  The project successfully, extinguished 304,000 cubic
yards of burning material at the Huber Bank at an average cost of $1.14 per cubic yard.

        The use of fog nozzles  to reduce air pollution while moving the  culm was also
demonstrated.  The direct stream of the water monitor itself could be used to move uncon-
solidated culm to the quenching pools. Hydraulic methods, although not originally
included in the project objectives,  led to the development of the "placer mining" or
"hydraulic movement" concept by the contractor and the state.  Subsequent projects
using this method have reduced the unit cost of extinguishing material at the Huber Bank
to approximately $0.70 per cubic yard.  Consequently, the latter method will most likely
replace the initial project method in all future work at Huber  Bank.

        Ambient air monitoring showed no significant change in long-term average
sulfur  dioxide levels during the two periods studied. There  was also no significant
change in the maximum peaks recorded or in the average of all  peaks for sulfur dioxide;
however, the frequency of occurrence decreased slightly  during the period from Decem-
ber 1966 to February 1967. An increase in hydrogen sulfide measured for the same period
was not considered significant because concentrations during both periods were low.
Although the project itself failed to substantially reduce the pollution levels, there was
no pollution  increase during the sampling periods, possibly as  a result  of eliminating
two banks of the complex as pollution hazards.

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                        A.ll   GYPSY,  PENNSYLVANIA
PROJECT NUMBER:    66A-4105D.

TERM OF PROJECT:   September 1,  1966 to December 31.  1969.

OBJECTIVES:

1.  To develop and test in the laboratory oxidation retardant formulations that could be
    used to extinguish fires on the surface and in the interior of coal refuse piles at a
    reasonable cost.

2.  To test the best oxidation retardant formulation found in the laboratory on a portion
    of an actual coal-refuse pile.

GRANTEE:  The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:  Gallery Chemical Company, Gallery, Pennsylvania.

FUNDS ALLOCATED:     Federal  funds             $96,427.04
                        State  funds                 21,642.60
                        State  services              10,500.00
                             Total                $128,569.64

COST PER CUBIC YARD:   Relatively high cost compared with the other methods.  Cost
per cubic yard is not accurately known because most of the work was performed in a
laboratory.

STATUS  AT LAST INSPECTION:   (December 31, 1970) - This project was not successful
because of a number of hot spots still present in the bank.

BACKGROUND:  Four phases were originally planned for this project.  During work on
the project, phase 2 was  dropped  as being unnecessary and phase 4 (treatment of the
entire coal refuse pile with an oxidant retardant formulation) was deleted after the results
from phase 3  (small scale field testing of the formulations)  were found to be  unfavorable.
Instead,  two experiments, a water penetration technique involving the controlled leakage
of surfactant treated  water from a  perforated polyethylene lined trench and a fire retard-
ant injection method using lances  to place the chemical treatment near the fire zone, were
substituted for the two deleted phases.

        Initially, a method had to be developed  to evaluate the effectiveness of several
different fire retardant chemicals  in extinguishing coal-refuse-pile fires.  The greatest
difficulty encountered was in developing a test that would closely approximate the condi-
tions found in a burning pile.  A standard procedure was developed to evaluate the effec-
tiveness  of the following chemicals:  ammonium  sulfamate,  ammonium polyphosphate,
ammonium bromide, potassium bicarbonate, monoammonium phosphate,  cobaltic oxide,
methylene bromide, methyl bromide, and two proprietary chemicals, Fyrex  and CWS.
                                         35

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        The results of the testing showed ammonium sulfamate to be the most effective
chemical per pound used. The testing also showed that, on a dry weight basis, ammoni-
um polyphosphate was as effective as ammonium sulfamate when approximately 30 percent
more ammonium polyphosphate than ammonium sulfamate was used.  Although ammonium
polyphosphate was less expensive than ammonium sulfamate, ammonium sulfamate was
used in a field test at a burning refuse pile near Gypsy, Pa.,  on the property of the
Trojan Coal and Petroleum Corporation.

METHOD:  Three test areas, each 100 feet by 100 feet, were laid out on the pile and 18
thermowells were driven into the test sites. Temperature readings were recorded prior
to treatment, and periodically thereafter.  Sprinklers were used to  distribute the chemi-
cal solutions over the test areas. Test area 1 was treated with water containing the sur-
factant, area 2 was treated with a solution of ammonium sulfamate and surfactant, and
area 3 was left untreated as  a control. The field work was initiated in February 1967 and
completed in November 1969.

        For the first additional experiment, a trench was dug and two perforated poly-
ethylene-lined troughs were placed side-by-side in it.  Between the two troughs, five
thermowells were placed. The polyethylene liner was perforated with holes 1/32-inch
in diameter that allowed the water level in  the trough to drop approximately 1 inch per
hour.  The water used in this experiment contained only a surfactant.  This experiment
resulted in a definite cooling trend in the pile below it.

        In the second experiment,  16 injection wands were driven into the refuse pile.
The first four  wands were used for injection of an ammonia-water-surfactant mixture,
the next four were control wands not used  for injection and the last eight wands were
used to inject  ammonium polyphosphate,  water, and surfactant.

COMMENT AND EVALUATION:   This project involved more laboratory work than any of
the other demonstration projects.  The laboratory work established that ammonium sulfa-
mate and ammonium polyphosphate were  the most effective chemicals tested, although it
is possible that the testing method used may not have been a good representation of con-
ditions found in a burning coal-refuse pile. This note of skepticism was generated
because of the conflicting results obtained  from the laboratory and field testing. In the
field test, plain water cooled the pile just as much as, or possibly more than, the ammo-
nium sulfamate-water mix.  In the injection experiment, the ammonia, water, and sur-
factant mixture cooled the pile more than the application of nothing at all, but the pile
where nothing at all was applied cooled more than where the ammonium polyphosphate,
water, and surfactant mix was applied.  One possible explanation is that temperature
measurements were taken for too short a period (about 6 weeks) after application of the
formulation to  permit definite trends to be established.

        Another consideration in the test involving ammonium sulfamate  is that the con-
centrations of  the  chemical that were tried  in the  laboratory  were 4.8 percent of the total
sample tested; the field test was limited by economics to 1 percent by weight in 200,000
gallons  of water, or approximately 16,700 pounds of sulfamate.  The test area contained
approximately 32,000,000 pounds of refuse. A uniform distribution of sulfamate would
only result in  a concentration of 0.052 percent, which is 100 times smaller than the con-
centration indicated by laboratory testing.

        If 4.8 percent by weight of sulfamate were used to treat the 32,000,000 pounds of
refuse,  approximately 1,613,000 pounds  of sulfamate would be needed.  The Gallery
Chemical Company paid $0.20 per pound for the 20,000 pounds of sulfamate purchased for
the project. Based on this price, the necessary 1,613,000 pounds would cost $322,600.
36

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The cost of the chemicals needed to treat a cubic yard of refuse pile would be approxi-
mately $20 as compared to a total average cost for seven other "good" coal refuse pile
extinguishment projects of $0.96 per cubic yard.
                                                                                 37

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                 A.12   WHITE  STATION,  PENNSYLVANIA


PROJECT NUMBER:   66A-4106D.

TERM OF PROJECT:  August 1, 1966 to December 30, 1968.

OBJECTIVES:

1.  To determine whether the remote application of water by means of high-pressure
    spray nozzles could economically cool and quench burning culm banks.

2.  To determine whether the quenched material could be permanently extinguished by
    mixing the cooled material with noncombustible red dog.

GRANTEE:   The Commonwealth of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:   Adrian D.  Davis, Homer City, Pennsylvania.

FUNDS ALLOCATED:     Federal funds            $49,762.50
                       State funds                8,587.50
                       State services              8,000.00
                            Total               $66,350.00

COST PER CUBIC YARD:   $0.66 (100,485 cubic yards).

STATUS AT LAST INSPECTION:   (December 31,  1971) - The piles were effectively extin-
guished with no visible emissions and no indication of further heating. Project completely
successful.

BACKGROUND:   The refuse bank at White Station had burned for several years after the
mining operation of the Westmoreland Mining Company stopped in the late 1950's.  The
villages of White Station and Moween experienced increasing episodes of serious air  pollu-
tion from the gaseous emissions from these banks. The site was chosen for the demonstra-
tion because it offered not only an unlimited water supply from the Conemaugh River, but
also adequate space to permit heavy equipment to excavate the burning refuse and to re-
pile it in compacted layers without transporting the extinguished material a great distance.

METHOD:  The noncombustible red  dog was scraped off the previously burned portions
of the pile by bulldozer. Water sprays were used to wet-down and cool the hot, burning
sections of each pile.  The wet material was subsequently removed by bulldozer and re-
piled in alternate layers with red dog.  Each layer was compacted during this process and
the resultant pile was  shaped to eliminate high walls that might permit air to intrude into
the pile.

        The work was accomplished over a 33-week period, during which time 100,485
cubic  yards of material were processed.  The combined piles were spread over approxi-
mately 19 acres.
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COMMENT AND EVALUATION:   This project successfully extinguished the burning banks
at White Station.  The cost appears to be quite reasonable considering that the contractor
had no previous experience with such work.

        The major value of this project is that it demonstrated conclusively that, if ample
water and space are available, many of the burning banks in western Pennsylvania can
be extinguished by competent earth-moving contractors using standard equipment and
commercially available pumps equipped with an easily fabricated sprinkler system. In
the future, competitive bidding will, no doubt, reduce the unit cost below the reported
values.
40

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                    A.13   SCRANTON,  PENNSYLVANIA
PROJECT NUMBER:   66A-4108D.

TERM OF PROJECT:  August 1, 1966 to June 30, 1968.

OBJECTIVES:

1.   To determine whether the use of explosives to loosen the heavy clinker in burning
    culm banks could successfully open the underlying hot areas to solid streams of water.

2.   To determine whether the heavy application of water, with rapid heat exchange at
    the seat of the fire, would reduce the temperature of the mass below combustion levels
    and permanently extinguish the fire.

GRANTEE:   The Commonwealth of Pennsylvania, Department of Mines  and Mineral
Industries.

CONTRACTOR:   Scranton Excavating Company.

FUNDS ALLOCATED:      Federal  funds             $27,073.00
                        State funds                 4,024.48
                        State services               5,000.00
                            Total                $36,097.48

COST PER CUBIC YARD:   $2.19 (16,500 cubic yards) .

STATUS AT LAST INSPECTION:   (December 31, 1970) - The major portion of the pile was
burning; however, project was completely successful.

METHOD:   Site preparation required the installation of a pump and a 14-inch-diameter
water pipeline, and the drilling of five 6-inch-diameter horizontal holes.  The holes
varied in depth from 34 to 47 feet.  Internal temperature measurements were taken to
ensure safe conditions for Ipading explosives. After the holes were cooled with water,
explosive charges were inserted and detonated.  The rubble was subsequently doused
with water  at the rate of 4,000 gal/min, for 8 hours a day, over a 5-day period. The
cooled rubble was then removed to  an adjacent disposal area.

COMMENT AND EVALUATION:  The project successfully demonstrated that explosives
can be used to break up monolithic surface clinkers in culm banks and permit subsequent
water extinguishment.  The economics of this project were not particularly attractive
($2.19 per  cubic yard of material extinguished) because of high nonrecurring costs and
site-preparation expenses. A later $50,000 project funded entirely by the State of Penn-
sylvania extinguished 125,000 cubic yards of material at a unit cost of $0.40 per cubic
yard.  The two projects together had a cost per cubic yard of approximately $0.61, a
more valid  figure to use for estimating purposes.

        Assuming that the original survey of this bank was fairly accurate and that the
bank contains approximately 2,746,000 cubic yards of material, an additional expenditure

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of approximately $1,100,000 would be required to completely extinguish this bank at a
unit cost of $0.40 per cubic yard.

        The air pollution measurements show a local increase in particulate, hydrogen
sulfide, and sulfur dioxide levels shortly after the explosions and during the "wet down"
period. The State Department of Health, therefore, believes that this method of extin-
guishing culm-bank fires may not be appropriate for use in densely populated areas. The
Department of Mines  and Mineral Industries, however, believes that these adverse air
quality conditions were a temporary, minimal hazard in  view of the overall success of the
proj ect.

        This method will probably not be widely used outside the anthracite region of
Pennsylvania because of its requirements for an unlimited water supply and for ample
space to dispose of quenched material. Many of these banks are in late stages of burning,
so that the surface of the pile is covered with red dog and consolidated clinker to a depth
of 10 to 20 feet or more. In order to get at the fire in these banks, explosives will have to
be used.  It is believed, however, that after the consolidated material  has been removed
there are more effective means of extinguishing and moving the remaining material.  These
include the water-monitor-lagoon method and the water-monitor-dozer method that was
demonstrated in project 66A-4101D (appendix A. 10).

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                A.14   NORTH  SCRANTON,  PENNSYLVANIA


PROJECT NUMBER:   67A-4109D.

TERM OF PROJECT:  January 1, 1967 to June 1, 1968.

OBJECTIVES:

1.  To determine whether the remote application of water by means of high-pressure
    hydraulic guns could quench burning culm material efficiently and economically.

2.  To determine whether the quenched material could be moved and compacted.

GRANTEE:   The Commonwealth  of Pennsylvania, Department of Mines and Mineral
Industries.

CONTRACTOR:   Dixon Contracting Company.

FUNDS ALLOCATED:     Federal funds            $240,000
                       State funds                200,000
                       State services                8,500
                            Total               $448,500

COST PER CUBIC YARD:  $0.76 (586,666 cubic yards).

STATUS AT LAST INSPECTION:   (December  31, 1970) - Project was a complete success.

BACKGROUND:   The bank is located near the former Marvin Colliery of the Glen Alden-
Hudson Coal Company at Dixon City, Pa. The bank is divided into two separate piles
estimated to contain 3,760,000 and 4,300,000 tons of refuse, respectively. When this
project began, approximately 50 percent of each pile was burning.  These banks have
been on fire for at least 10 years. The smaller bank was selected for the demonstration
project because of its proximity  to a section of highway where the smoke and fumes often
created a serious traffic hazard.

METHOD:   A depression between the banks was deepened to form a basin for catching the
run-off water,  and a 165-foot well was drilled to tap a pool of mine water. A 6,000  gal/
min pump was installed and 1,500 feet of pipe were utilized to  transport the water to the
water monitors.  A direct stream of water from the monitors was played on the pile, work-
ing from the top downward to the quenching pool at the base of the bank. When the dis-
lodged hot material had been quenched, it was removed from the pool by  the dragline and
dumped a short distance from the pile.  A bulldozer then spread the material in 1-foot
layers to allow it to cool.  Landscrapers removed the cooled material to the disposal area,
where a second bulldozer spread the quenched culm and compacted it. During the  142-
day project, 586,666 cubic yards of material were extinguished.

COMMENT AND EVALUATION:  The project effectively extinguished the burning material,
proved that the use of earth-moving equipment was feasible, and showed a $0.76 per
cubic yard cost that was significantly lower than previous mechanical-hydraulic methods.

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Subsequent state projects using this method and costing $1,000,000 have practically
leveled the pile and extinguished all fire in the smaller portion of the Marvin Bank.
Because the cost includes approximately $122,000 for installation, such as: drilling a well,
preparing the site, and installing the deep-well pump, future projects at this site should
have a unit cost of approximately $0.54 per cubic yard of material treated.  Pennsylvania
mine officials believe that these unit costs could be further reduced, if an additional drag-
line-were used on subsequent projects.

        The use of a fog  nozzle on one of the water monitors minimized dust and fumes in
the working area.  The method also practically eliminated the need for protective breath-
ing apparatus for workmen.

        This method will be followed in most culm-bank-extinguishment projects in the
anthracite region, where the terrain and water supplies permit.

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                       A.15   ASHLEY,  PENNSYLVANIA

PROJECT NUMBER:  68A-4113D.

TERM OF PROJECT:  March 1, 1968 to September 30, 1968.

OBJECTIVE:

    To determine the relative effectiveness of two methods of extinguishing culm-bank
    fires.  Method 1 used a water monitor, dragline, bulldozer, and landscraper to
    remove, quench, transport,  and compact the burning material.  Method 2 repeated
    method 1, but also  used the water monitor to cool the bank material, remove it and
    transport it to an area where it was compacted in alternate layers with material
    quenched by  method 1. The methods were operated concurrently upon adjacent
    portions of the bank, but the disposal areas were separated.

GRANTEE:   Commonwealth Development Association of Pennsylvania.

CONTRACTOR:  Dixon Contracting Company.

FUNDS ALLOCATED:     Federal funds             $281,735.65
                       Non-Federal  funds         100,000.00
                            Total                $381,735.65

COST PER CUBIC YARD:    Method 1 - $0.71 (261,771 cubic yards)
                          Method 2 - $1.04 (189.500 cubic yards)
                             Project Total  451,271 cubic yards

STATUS AT LAST INSPECTION:  (July 23,  1969) - No evidence of heating was found in
either refuse-disposal area.

BACKGROUND:  The Huber Bank complex,  the largest burning coal-refuse bank in  the
anthracite region of Pennsylvania, has been actively burning since  1955 and is the source
of much of the air pollution that periodically affects the towns of Ashley and Wilkes-Barre.
This project and the other  projects conducted at this site were undertaken in response to
citizen's complaints and to state and Federal concern over the air pollution problem.
The methods demonstrated had been successfully applied elsewhere in Pennsylvania,
but not in combination or on the scale of this project.

METHOD:   In method 1, a  water monitor was used to excavate the burning material from
the highwall of the bank into a water-filled lagoon that was  formed at the base of the  high-
wall.  The wet, quenched culm was removed by a dragline to a landscraper, transported
to the disposal area, dumped, and smoothed and compacted by a bulldozer. Method  2
essentially  duplicated method 1, but the water monitor alternated between excavating the
culm and wetting  down  the top portion of the bank.  This latter material was pushed down
an inclined portion of the bank to a landscraper that moved it to a separate disposal
area, where it was deposited in alternate  layers with the monitor-quenched material
from method 2.

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        Method 2 required two 19-cubic-yard landscrapers; method 1 required only one.
With these exceptions,  the equipment used in each method was identical and consisted of
one 7-cubic-yard dragline, four bulldozers, and a water monitor.  The hydraulic system
consisted of an existing 12,000,000 gallon collecting reservoir, approximately 2,500 feet
of 10- to 8-inch steel and aluminum pipe. An electrically powered Barret and Haentjens
horizontal pump rated at 4,000 gal/min at 150 psig served the piping system that supplied
both water monitors.

        At the completion of the active extinguishment work, thermowells were placed in
18 open-cased bore holes that were strategically located throughout both storage areas.
All of these thermowells registered only ambient temperatures since the completion of  the
project.

COMMENT AND EVALUATION:  This was the largest and most effective extinguishment
project that had been undertaken at Huber.  Before its completion, various  efforts to
extinguish the burning refuse in this area of the Huber Bank had extinguished approxi-
mately 610,000 cubic yards at a total  cost of $697,500.00, a unit cost of $1.14 per cubic
yard. Together, the project methods had an average unit cost of $0.845 per cubic yard;
method 1 had a unit cost of approximately $0.71 per cubic yard.  For method 2 the higher
cost of $1.04 per cubic yard was at least partially dictated by the shape of the pile and
the longer distances that the quenched material had to be moved  to reach the disposal
area.

        The Pennsylvania Department of Mines and Mineral Industries has conducted
several  large extinguishment projects using method 1 at the Marvin  and Huber Banks
since the completion of this project.  The State of Pennsylvania expects to use this method
whenever available water and terrain permit.  Pennsylvania is expected to continue using
bond-issue funds, augmented with Federal funds, for projects to extinguish these fires.
In a 1968 survey, the U.S. Bureau of Mines estimated that the 27 burning banks in the
anthracite region contained approximately 54,500,000 cubic yards of refuse.  Assuming
that half of this volume must be processed in order to  extinguish these fires,  it is esti-
mated that the total cost of such an effort  will approximate $20 to $25 million.

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