EPA-560/13-79-001
        ANALYSIS FOR
       POLYBROMINATED
       BIPHENYLS (PBBs)
  IN ENVIRONMENTAL SAMPLES
             EPA
           MARCH 1979
U.S. ENVIRONMENTAL PROTECTION AGENCY
   OFFICE OF TOXIC SUBSTANCES
     WASHINGTON, D.C. 20460

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         ANALYSIS FOR POLYBROMINATED
      BIPHENYLS (PBBs) IN ENVIRONMENTAL
                   SAMPLES
                     by

    Charles L. Stratton and John J. Mousa
 Environmental Science and Engineering, Inc.
               P. 0. Box 13454
         Gainesville, Florida 32604
                     and
                Joan T. Bursey
         Research Triangle Institute
               P. 0. Box 12194
Research Triangle Park, North Carolina 27709
                  Task IIIB
          Contract No. 68-01-3248
                 March 1979
               Project Officers
               Thomas E. Kopp
              Vincent J. DeCarlo
       Environmental Protection Agency
         Office of Toxic Substances
            Washington, DC 20460

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                                  DISCLAIMER
     This report has been reviewed by the Office of Toxic Substances, U.S.
Environmental Protection Agency, and approved for publication.  Approval does
not signify that the contents necessarily reflect the views and policies of
the U.S. Environmental Protection Agency, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.

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                                   ABSTRACT
     Ninety-eight environmental samples consisting of fish, sediments, soils,
and vegetation were analyzed by gas chromatographic/mass spectrometry (GC/MS)
techniques for hexa-, hepta-, octa-, nona-, and decabromobiphenyls.  The samples
were collected by EPA regional office personnel.  Hexabromobiphenyl was the
most prevalent species detected.   This species was detected in 84 percent of
the samples over the range of 0.2 to 50,000 ppb.  Heptabromobiphenyl was detected
in 12 percent of the samples and  octabromobiphenyl in 2 percent of the samples.
Nonabromobiphenyl and decabromobiphenyl were not detected.
                                        ii

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                           TABLE OF CONTENTS


Section                                                            Page

             DISCLAIMER                                              i

             ABSTRACT                                               ii

             LIST OF TABLES                                         iv

  1.0        INTRODUCTION                                            1

  2.0        METHODS

             2.1  SAMPLE PREPARATION                                 2

             2.2  SAMPLE ANALYSIS                                    2

  3.0        RESULTS                                                 3

  4.0        CONCLUSIONS                                             3

  5.0        REFERENCES                                             19

             APPENDIX A—SAMPLES RECEIVED

             APPENDIX B—GC/MS ANALYSIS RESULTS FOR ENVIRONMENTAL
                         SAMPLE EXTRACTS

             APPENDIX C—RETENTION TIMES AND IONS MONITORED FOR
                         ANALYSIS OF POLYBROMINATED BIPHENYLS

             APPENDIX D--RATIOS OF IONS USED TO CONFIRM THE
                         PRESENCE OF POLYBROMINATED BIPHENYLS

             APPENDIX E--FULL SCAN SPECTRAL CONFIRMATION OF THE
                         PRESENCE OF POLYBROMINATED BIPHENYLS
                         FOR REPRESENTATIVE SAMPLES

             APPENDIX F—REPRESENTATIVE SELECTED ION MONITORING
                         TRACES
                                   iii

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                            LIST OF TABLES
Table                                                               Page

  1      Estimated Levels of Polybrominated Biphenyls in
         Environmental Samples                                        4

  2      Frequency and Range of Detection of Ninety-Egith Samples
         Analyzed                                                    18
                                   iv

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1.0  INTRODUCTION

Polybrominated biphenyls (PBBs) are a class of chemical compounds with a chemical
structure as follows:
                        Brx   /=
where X can be any number from 0 to 5.  These compounds were first produced in
the United States in commercial quantities in 1970.  The compounds have been
used as flame retardants for plastics, textiles, and other materials.

Polybrominated biphenyls (PBBs) are used extensively as flame retardants for
polymers, textiles, and other materials.^ '  The major component of the most
common commercial mixture, Fire Master PB-6®' ', is hexabromobiphenyl.^"''
Concern about the environmental impact and health effects of wide spread use of
PBBs has been aroused by a recent major environmental catastrophe in Michigan.'^~°
Their chemical similarity to polychlorinated biphenyls (PCB) and polychlorinated
naphthalenes (PCN) has raised the question of bioconcentration and toxicity to
the point to warrant a test of the carcinogenicity of hexabromobiphenyl by the
National Cancer Institute Bioassay Program.^''

In response to the problem in Michigan, analytical methodologies for PBBs have
been developed and applied to feeds^), dairy products'1*' and soils. ^ ' '
Although extensive analytical work has been carried out with respect to samples
originating in Michigan, little attention has been directed to the possibility
of pollution resulting from manufacture and use of PBBs in other locations
throughout the United States.

In this document is reported the results of the analysis of environmental
samples collected in the vicinity of several locations where PBBs have been
used for the manufacture of various products.  Samples were collected by
personnel from the following organizations:

     Sets a/h  New Jersey Division of Fish and Game
     Set b  Ohio EPA, Southwest District
     Set c  EPA Region III, Wheeling, West Virginia
     Set d  EPA Region III, Nashville, Tennessee
     Set e  EPA Region IX, Alameda, California
     Set f  New York State Department of Environmental Conservation, Buffalo,
            New York
     Sets g/i  EPA Region V, Central District Office
     Set j  EPA Office of Toxic Substances

The samples were sent to Environmental Science and Engineering, Inc. for extrac-
tion, clean-up, and concentration.  All samples were received in good condition
except those taken in the vicinity of General Tire and Rubber, Corporation, Ionia,
Michigan, which could not be analyzed.  The sample extracts were shipped to
Research Triangle Institute (RTI) for analysis.

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2.0  METHODS

2.1  Sample Preparation

Soils.  Soil samples were extracted with hexane in a soxhlet apparatus.  The
extract was concentrated to 1.0 ml on a Kuderna-Danish evaporator, cleaned up
on a florisil chromatographic column, and packaged in hermetically sealed vials
prior to GC/MS analysis.

Sediments and Sludges.  Sediment and sludge samples were extracted with hexane
in a soxhlet apparatus, and the extract cleaned up in the same manner as described
above for soils.  The moisture content was determined on a separate fraction of
the homogenized sample.

Biological Tissue.  Terrestrial vegetation was analyzed for PBB by rinsing a
measured quantity with hexane in a beaker.  The hexane was subsequently concen-
trated on a Kuderna-Danish evaporator concentrator to 1.0 ml and subjected
directly to GC/MS analysis.  The resulting analytical data was calculated as
mass of PBB accumulated on a unit mass of vegetation.

Animal tissue was hard frozen shortly after collection.  To a measured quantity
of crushed, frozen tissue was added 5 g of clean, sharp sand and 5 g of anhydrous
sodium sulfate  (Na2SO^).  Whole fish were used, since those analyzed were gen-
erally small in size.  The tissue was then ground to obtain a uniform, dry
granular mass.  This material was extracted with hexane in a soxhlet extraction
apparatus.  The hexane extract was concentrated to 0.5 ml on a Kuderna-Danish
apparatus and passed through a florisil chromatographic column using the proce-
dures of Fehringer(^,5) ancj EPA^^'.  The eluate was concentrated to 1.0 ml and
placed in a hermetically sealed vial prior to GC/MS analysis.   Moisture content of
the tissue was determined on a separate fraction of the homogenate.  Analytical
results are reported on a dry weight basis.

2.2  Sample Analysis

The sample extracts were stored frozen until shipment to RTI for GC/MS analysis.
The extracts were shipped on ice by air courier.

Upon receipt by RTI, samples were taken to dryness under a slow stream of dry
nitrogen.  The residue was then taken up in an appropriate volume of dry toluene
and the appropriate standards (octachloronaphthalene and decachlorobiphenyl)
added at a level of approximately 2 ng/ul.  The samples were analyzed by gas
chromatograph/mass spectrometer/computer utilizing either a Finnigan 3300 GC/MS
equipped with a PDP-12 computer (chromatographic column, 45 cm x 0.2 cm i.d.,
glass, 2% OV-101 on Gas-Chrom Q; helium flow, 20 cc/min; initial temperature,
220°C programmed to 280°-300°C at 4°/min; separator temperature, 250°C; injector
temperature, 280°C) or an LKB-2091-050 EI/CI (chromatographic column, 45 cm x
0.2 cm i.d., glass, 2% OV-101 on Gas-Chrom Q; helium flow, 18 cc/min; initial
temperature, 220°C for one minute, then programmed to 290°C at 8°/min; separator
temperature, 275°C; injector temperature, 280°C; ion source temperature, 250°C).
The polybrominated biphenyls were analyzed by selected ion monitoring techniques
(see Appendix C for ions monitored and retention times observed).

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3.0  RESULTS

A total of 144 samples were received.  Appendix A lists all the samples received
and the origin of the shipment.  Ninety-eight of these samples were selected by
the EPA Project Officer for extraction and analysis.  The results of these
analyses are shown in Table 1.

Appendix B is a summary of the PBB concentration in each sample extract.  The
retention times and the ions monitored are listed in Appendix C.  The ratios of
ions used to confirm the presence of PBBs are described in Appendix D- and full
scan spectral confirmation of representative samples are shown in Appendix E.
Appendix F are representative selected ion monitoring traces.

4.0  CONCLUSIONS

The frequence of detection of the various PBB species is summarized in Table 2.
Hexabromobiphenyl was the most prevalent species detected.  This species was
detected in 84 percent of the samples over the range of 0.2 to 50,000 ppb.
Heptabromobiphenyl was detected in 12 percent of the samples and octabromobi-
phenyl in 2 percent of the samples.  Nonabromobiphenyl and decabromobiphenyl
were not detected.

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                                                                                                   DIV4.3/PBB-HTB.1
                                                                                                             3/15/79
Table 1.
Estimated Levels of Polybrorainated Biphenyls in Environmental Samples (Page 1 of 14)
 Samples
Collected
   By
Sample
 Code
Sample Type and Location
                                                     PBB Concentration (ng/g) , parts per billion
G12H4Br6    G12H3Br7    c!2H2Br8
                     C128r10
                           FISH
             5-2     Hackensack R. at Sawmill Cr.
                                                  3.4
             5-13
               FISH
         Hackensack R. at Sawmill Cr.
                                      0.7
             5-17
               FISH
         Hackensack River at Moonachie Cr.
                                      0.6
                           FISH
             7-2     Newark Bay, Bayonne Area

                           FISH
             7-4     Newark Bay, Bayonne Area

                         SEDIMENT
             7-6     Newark Bay, Bayonne Area

                           FISH
             7-7     Arthur Kill/Howland Hook Staten Is,

                         SEDIMENT
             7-8     Kill Van Kull, Staten Is.

                           FISH
             7-9     Newark Bay, Bayonne Area

                           FISH
             7-10    Newark Bay, Bayonne Area

                           FISH
             7-14    Newark Bay, Bayonne Area
                                                  3.1
                                                  0.4
                                                  0.3
                                                  0.7
                                                  1.6
1.8

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                                                                                       DI
                                          Vf .
                                                                                                                   . 2
                                                                                                              3/15/79
Table 1.
Estimated Levels  of  Polybrominated Biphenyls in Environmental Samples (Continued, page 2 of  14)
 Samples
Collected   Sample
   By        Code
                                                                  PBB Concentration (ng/g) , parts  per billion
                         Sample  Type  and Location
C12H4Br6    C12H3Br7    C12H2Br8
                                                                                               G12Br10
9-1


9-3


9-7


9-10


9-15


9-16


9-18


9-20


9-22


9-26

9-28
                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.

                           FISH
                     Raritan  R.
                            FISH
                      Raritan  R.
at South R.


at South River


at JCP&L Power Plant


at JCP&L Power Plant


at South River Light


at South River Light


at South R. Light


at South R. Light


at South R. Canal


at Lawrence Brook


at Lawrence Brook
                                                               1.5
                                                               0.3
                                                               0.4
                                                               0.7
                                                               0.3
                                                               2.3
                                                               0.4
                                                               2.1
                                                               0.2
              0.5

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                                                                                                    DIV4.3/PBB-HTB.3
                                                                                                             3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls  in Environmental Samples  (Continued, page 3 of  14)
 Samples
Collected   Sample
   By        Code
                    Sample Type and Location
                                                             PBB Concentration (ng/g), parts per billion
c!2H4Br6    G12H3Br7
    a
                           FISH
             9-30    Raritan R. at Lawrence Brook
                       FISH
a        9-31    South R. at South R. Marina
                                                              0.3
                           FISH
             23-1    Raritan Bay/Sandy Hook Bay
                            FISH
             23-2    Raritan Bay/Sandy Hook Bay
                                                          0.4

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                                                                                                    DIV4.3/PBB-HTB.4
                                                                                                             3/15/79
Table 1.
Estimated Levels of Polybrominated  Biphenyls  in Environmental  Samples  (Continued,  page 4 of  14)
 Samples                                                    	PBB  Concentration  (ng/g),  parts  per  billion	
Collected    Sample
   By        Code       Sample Type and Location            Cj2H4Br6    C^2H3Br7    c!2H2Br8    C^HBrg     G12Br10


                          SEDIMENT
    b        8503     Cincinnati  Chem. Proc., North Ditch       5.9

                          SEDIMENT
    b        8504     Cincinnati  Chem. Proc., West Ditch        550         9.4

                          SEDIMENT
    b        8528     Cincinnati  Chem. Proc., East Ditch        270         9.2

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                                                                                                                3/15/79
   Table 1.
   Estimated Levels of Polybrominated Biphenyls in Environmental Samples (Continued, page 5 of 14)
    Samples
   Collected
      By
Sample
 Code
Sample Type and Location
	PBB Concentration (ng/g), parts per billion	

C12H4Br6    C12H3Br7    C12H2Br8    C12HBr9    C12Br10
00
              SOIL, #1
 7695     Borg-Warner, Washington Plant, WV      3,200

              SOIL #2
 7696     Borg-Warner, Washington Plant          2,800

              SEDIMENT, #3
 7714     Ohio R., Borg-Warner, Wash. Plant        5.6

              SEDIMENT, #5
 7716     Ohio R., Borg-Warner, Wash. Plant         10

              SOIL, #6
 7717     Borg-Warner, Washington Plant            <10

              SOIL, #7
 7718     Borg-Warner, Dupont and
          L. Washington Rd. Intersection            14

              SOIL, #8
 7719     Borg-Warner, Washington Plant            <10

                SOIL
 7722     Corry Foam Products, PA, S.W.             14

                SOIL
 7723     Corry Foam Products, PA, N.W.             16

                SOIL
 7726     Corry Foam Products, PA, N.E.             12

                SOIL
 7727     Corry Foam Products, PA, S.E.            480
                                                                             190
                                                                             430
                                                               64

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                                                                                                   DIV4.3/PBB-HTB.6
                                                                                                            3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls in Environmental Samples (Continued, page 6 of 14)
 Samples
Collected   Sample
   By        Code
Sample Type and Location
	PBB Concentration (ng/g), parts per billion	

G12H4Br6    G12H3Br7    c!2H2Br8    G12HBr9    G12Br10
                          SOIL, #2
             7698     Corry Foam Prod., TN

                          SOIL, #3
             7699     Corry Foam Prod., TN

                          SOIL, #1A
             7706     Corry Foam Prod., TN

                          SOIL, #6
             7709     Corry Foam Prod., TN

                          SOIL, #5
             7710     Corry Foam Prod., TN

                          SOIL, #4
             7712     Corry Foam Prod., TN
                                       6.4
                                       3.5
                                        26
                                        26
                                       4.2
                                       7.2

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                                                                                                  DIV4.3/PBB-HTB.7
                                                                                                            3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls in Environmental  Samples  (Continued,  page 7 of  14)
Samples
Collected Sample
By Code
e 7651
e 7652
e 7653
e 7654
1 *
p^
o
e 7655
e 7656
e 7657
e 7658
e 7659
e 7660
e 7661
Sample Type and Location
SOIL, #7
Borg-Warner, California Plant
VEGETATION, #8
Borg-Warner, California Plant
SOIL, #9
Borg-Warner, California Plant
SOIL, #10
Borg-Warner, California Plant
VEGETATION, #11
Borg-Warner, California Plant
SOIL, #12
Borg-Warner, California Plant
SOIL, #13
Borg-Warner, California Plant
VEGETATION, #14
Borg-Warner, California Plant
SOIL, #15
Borg-Warner, California Plant
VEGETATION, #16
Borg-Warner, California Plant
SOIL, #17
Borg-Warner, California Plant
PBB Concentration (ng/g), parts per billion
C12H4Br6 C12H3Br7 C12H2Br8 C12HBr9 C12Br10
640
—
710 47
7,300 440
<150
23
2,400 170
150
380
100
39

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                                                                                                  DIV4.3/PBB-HTB.8
                                                                                                           3/15/79
Table 1.
Estimated Levels of Polybrorainated Biphenyls in Environmental  Samples  (Continued, page 8 of 14)
Samples
Collected Sample
By Code
e 7662
e 7663
e 7728
- e 7729
e 7730
e 7731
e 7732
e 7733
Sample Type and Location
SLUDGE, #1
Oxnard, STP, California
SLUDGE, #2
Oxnard, STP, California
SOIL, #1
Borg-Warner, California Plant
SOIL, #2
Borg-Warner, California Plant
SOIL, #3
Borg-Warner, California Plant
VEGETATION, #4
Borg-Warner, California Plant
VEGETATION, #5
Borg-Warner, California Plant
VEGETATION, #6
Borg-Warner, California Plant
PBB Concentration (ng/g) , parts per billion
C12H4Br6 C12H3Br7 C12H2Br8 C12HBr9 C12Br10
91
80
6,000 150
50,000 18,000
9,200 870
50 <40
93
64

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                                                                                                 DIV4.3/PBB-HTB.10
                                                                                                           3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls in Environmental  Samples  (Continued, page  10 of  14)
Samples
Collected Sample
By Code
g 4601
g 4602
g 4603
G g 4604
g 4605
g 4606
g 4607
g 4608
g 4609
g 4610
Sample Type and
SOIL, #1
Burkart Randall,
78-CM09S01
SOIL, #2
Burkart Randall,
SOIL, #3
Burkart Randall,
SOIL, #4
Burkart Randall,
SOIL, #5
Burkart Randall,
SOIL, #6
Burkart Randall,
SOIL, #7
Burkart Randall,
SOIL, #8
Burkart Randall,
SOIL, y/9
Burkart Randall,
SOIL, #10
Burkart Randall,
PBB Concentration (ng/g), parts per billion
Location C^^Br^ Cj2^3Br7 Cl2^2Br8 C^HBrg ^12Br10
Cairo, IL 40
78-CM09S02 290
78-CM09S03 8
78-CM09S04 37
78-CM09S05 350
78-CM09S06 240
78-CM09S07 150
/
78-CM09S08 310
78-CM09S09 8
78-CM09S10 8

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                                                                                                   t)IV4.37PBB::rHrB.ll
                                                                                                             3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls  in Environmental  Samples  (Continued,  page  11  of  14)
 Samples
Collected   Sample
   By        Code
Sample Type and Location
                                         PBB Concentration (ng/g) , parts per billion
io^r*:
CioHBrq
                            SOIL, #12
             4611     Burkart Randall, 78-CM09S12

                            SOIL, #13
             4612     Burkart Randall, 78-CM09S13

                            SOIL, #1
             4613     Burkart Randall, 78-CM09S14

                            SOIL, #15
             4614     Burkart Randall, 78-CM09S15

                            SOIL, #16
             4615     Burkart Randall, 78-CM09S16

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                                                                                                  DIV4.3/PBB-HTB.12
                                                                                                            3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls in Environmental Samples (Continued,  page  12 of 14)
 Samples
Collected   Sample
   By        Code
Sample Type and Location
	PBB Concentration (ng/g), parts per billion	

C12H4Br6    C12H3Br7    C12H2Br8    C12HBr9    C12Br10
                            SOIL, '#1/7
             4616     Cincinnati Chemical
                      Batavia, OH

                            SOIL, #2/7
             4617     Cincinnati Chemical
                      Batavia, OH

                            SOIL, #3/7
             4618     Cincinnati Chemical
                      Batavia, OH

                            SOIL, #4/7
             4619     Cincinnati Chemical
                      Batavia, OH

                            SOIL, #5/7
             4620     Cincinnati Chemical
                      Batavia, OH

                            SOIL, #6/7
             4621     Cincinnati Chemical
                      Batavia, OH

                            SOIL, #7/7
             4622     Cincinnati Chemical
                      Batavia, OH
                  Processing Co.,
                  Processing Co.,
                  Processing Co.,
                  Processing Co.,
                  Processing Co.,
                  Processing Co.,
                  Processing Co.,
  1020
    84
   340
   390
    17

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                                                                                                  DIV4.3/PBB-HTB.13
                                                                                                            3/15/79
Table 1.
Estimated Levels of Polybrominated Biphenyls in Environmental Samples (Continued, page 13 of 14)
 Samples
Collected
   By
Sample
 Code
Sample Type and Location
	PBB Concentration (ng/g), parts per billion	

G12H4Br6    G12H3Br7    c!2H2Br8    C12HBr9    c12Br!0
                            SOIL, #1
             4623     Borg-Warner, Ottawa, IL
                      78-CM10S01
                                                    12
                            SOIL, #2
             4624     Borg-Warner, Ottawa, IL
                      78-CM10S02
                            SOIL, #7
             4625     Borg-Warner, Ottawa, IL
                      78-CM10S07

                            SOIL, #8
             4626     Borg-Warner, Ottawa, IL
                      78-CM10S08
                                                    51
                                                    61
                            SOIL, #9
             4627     Borg-Warner, Ottawa, IL
                      78-CM10S09

                            SOIL, #12
             4628     Borg-Warner, Ottawa, IL
                      78-CM10S12

                            SOIL, #13
             4629     Borg-Warner, Ottawa, IL
                      78-CM10S13
                                                    68
                            SOIL, #14
             4630     Borg-Warner, Ottawa, IL
                      78-CM10S14

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                                                                                                   DIV*T. 77PBB-HTB. 14
                                                                                                             3/15/79
Table 1.
Estimated Levels  of  Polybrominated  Biphenyls  in  Environmental  Samples  (Continued,  page 14 of 14)
  Samples
Collected    Sample
   By         Code
                                         PBB Concentration (ng/g) , parts per billion
Sample Type and Location
G12H4Br6    G12H3Br7    G12H2Br8
G12Br10
                             CARPET
              8669      AID  Consulting Engineers

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Table 2.  Frequency and Range of Detection in Ninety-Eight Samples Analyzed
       Species




  Hexabromobiphenyl




  Heptabromobiphenyl




  Octabromobiphenyl




  Nonab romob ipheny1




  Decabromobiphenyl
Frequency




   84%




   12%




    2%




    0%




    0%
Range (ppb)




0.2-50,000




0.5-18,000




1.8-64
      Material




tissue, soil, sediment




tissue, soil, sediment




tissue, soil
                                       18

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 5.0  REFERENCES

 1.   G. Sundstrom, 0. Hutzinger, S. Safe and V. Zitko, The  Science  of  the  Total
     Environment, 6_, 15 (1976).

 2.   Michigan Chemical Corporation, St. Louis, Michigan.

 3.   W. H. Gutenmann and D. J. Lisk, J. Agr. Food Chem.,  23,  1005  (1976).

 4.   N. V. Fehringer, J. Ass. Offic. Anal. Chem., 58, 978 (1975).

 5.   N. V. Fehringer, J. Ass. Offic. Anal. Chem., 58_, 1206  (1975).

 6.   L. W. Jacobs, S. F. Chou and J. J. Tiedje, J. Agr. Food  Chem.,  24,  1198 (1976).

 7.   A. B. Filanow, L. W. Jacobs, and M. M. Mortland, J.  Agr.  Food  Chem.,  24,
     1201 (1976).

 8.   L. 0. Ruzo, G. Sundstrom, 0. Hutzinger and S. Safe,  J. Agr. Food  Chem.,
     _24, 1082 (1976).

 9.   Pest. Tox.  Chem. News, February 9, 1977, p. 25.

10.   Environmental Protection Agency.  1974.  Analysis of Pesticide Residues
     in Human and Environmental Samples.  National Environmental Research
     Center, Research Triangle Park, North Carolina.
                                        19

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   APPENDIX A




SAMPLES RECEIVED

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Table A-l.  Sample Description
     New Jersey Division of Fish and Game
     Nacote Creek Research Station
     Star Route
     Absecon, New Jersey  08201
                                                   Set a
                                                                                      DIV4.3/SAMPDES-HTB.1
                                                                                                   3/22/79
                                                                                              Page  1  of  15
Sample No.
     Sampling Location
  Sample Description
Analyzed?
   5-1
   5-2
   5-3
   5-13
   5-14
   5-15
   5-16
   5-17
   6-1
   7-2
   7-3
   7-4
   7-5
   7-6
   7-7
Hackensack River at Sawmill Creek
Hackensack River at Sawmill Creek
Hackensack River at Rt. 1 & 9 Bridge
Hackensack River at Sawmill Creek
Hackensack River at Sawmill Creek
Hackensack River at Sawmill Creek
Hackensack River at Sawmill Creek
Hackensack River at Moonachie Creek
Passaic River at Rt.  1 & 9 Bridge
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Arthur Kill/ Howland  Hook Staten Island
Blue Crab—Composite
Spot—Composite
Sediment—1/3 pint
American Eel—Single
American Eel—Single
American Eel—Single
American Eel—Single
Br. Bullhead Catfish—Single
Sediment—1/3 Pint
Menhaden—Composite
Spot —Compos ite
Blue Crab—Composite
Kill ifish—Composite
Sediment—1/3 Pint
Sediment—1/3 Pint
 Broken
   Yes
   No
   Yes
   No
   No
   No
   Yes
   No
   Yes
   No
   Yes
   No
   Yes
   Yes

-------
                                                                                       DI
                                                                             l/s
                                      S-H
                                      3/15/79
Table A-l.  Sample Description
                                              Set  a  (continued)
                                                                               Page  2 of  15
Sample No.
     Sampling Location
  Sample Description
Analyzed?
   7-8
   •7-9
   7-10
   7-11
   7-14
   9-1
   9-3
   9-5
   9-7
   9-9
   9-10
   9-11
   9-12
   9-13
   9-15
   9-16
   9-17
   9-18
   9-19
Kill Van Kull, Bement Ave., Staten Island
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Newark Bay, Bayonne Area
Raritan River at South River
Raritan River at South River
Raritan River at South River
Raritan River at JCP&L Power Plant
Raritan River at JCP&L Power Plant
Raritan River at JCP&L Power Plant
Raritan River at JCP&L Power Plant
Raritan River at JCP&L Power Plant
Raritan River at JCP&L Power Plant
Raritan River at South River Light
Raritan River at South River Light
Raritan River at South River Light
Raritan River at South River Light
Raritan River at South River Light
Sediment—1/3 Pint
Striped Bass—Single
Striped Bass—Single
Menhaden—Single
Kill ifish—Composite
Bluefish—Composite
Blue Crab—Composite
Spot—Composite
Striped Bass—Single
American Eel—Single
Striped Bass—Single
American Eel—Single
White Perch—Single
White Perch—Single
Striped Bass—Single
Striped Bass—Single
Striped Bass—Single
Striped Bass—-Single
Striped Bass—Single
   Yes
   Yes
   Yes
   No
   Yes
   Yes
   Yes
   No
   Yes
   No
   Yes
   No
   No
   No
   Yes
   Yes
   No
   Yes
   No

-------
                                                                                                      3/15/79
   Table A-l.  Sample Description
                                                Set a (continued)
                                                                                           Page 3 of 15
   Sample No.
                 Sampling Location
                                                Sample Description
                                    Analyzed?
UJ
9-20
9-22
9-24
9-26
9-28
9-29
9-30
9-31
23-1
23-2
23-4
23-5
Raritan River at South River Light
Raritan River at South River Canal
Raritan River at South River Light
Raritan River at Lawrence Brook
Raritan River at Lawrence Brook
Raritan River at Lawrence Brook
Raritan River at Lawrence Brook
South River at South River Marina
Raritan Bay/Sandy Hook Bay
Raritan Bay/Sandy Hook Bay
Raritan Bay/Sandy Hook Bay
Raritan Bay/Sandy Hook Bay
White Perch—Single
White Perch—Single
American Eel-—Single
White Perch—Single
Carp—Single
Carp—Single
Carp—Single
White Catfish—Single
Winter Flounder—Single
Winter Flounder—Single
Winter Flounder—Single
Winter Flounder—Single
Yes
Yes
No
Yes
Yes
No
Yes
Yes
Yes
Yes
No
No

-------
Table A-1.  Sample Description
     Southwest District
     Ohio EPA
                                                   Set  b
                                                                                       V4
                                                                                                  3/15/79
Page 4 of 15
Sample No.
8503

8504

8528

Sampling Location
Cincinnati Chemical
North Ditch
Cincinnati Chemical
West -Ditch
Cincinnati Chemical
East Ditch
Processing,

Processing,

Processing,

Sample Description

Sediment

Sediment

Sediment v_
Analyzed?

Yes

Yes

Yes

-------
Table A-l.  Sample Description
     U.S. Environmental Protection Agency
     Region III
     303 Methodist Building
     Wheeling, West Virginia  26003
                                                   Set  c
     3/15/79


Page 5 of 15
Sample No,
7695
7696
7714
!> 7715
w 7716
7717
7718
7719
7720
7721
1111
7723
Sampling Location
Borg-Warner, Washington Plant
Borg-Warner, Washington Plant
Borg-Warner, Ohio River below Borg-Warner
Effluent
Borg-Warner, Washington Plant
Ohio River at Old Lock and Dike, just
below Borg-Warner Washington Plant
Along Road to Old Lock and Dam, just
downstream Borg-Warner Washington Plant
DuPont and Lake Washington Roads
Intersection
DuPont Road at Entrance to Landfill
Area of DuPont
1/2 mile S.E. of Corry Foam Products,
Corry, PA
1/2 mile N.W. of Corry Foam Products,
Corry, PA
Corry Foam Products, Corry, PA, S.W.
Corry Foam Products, Corry, PA, N.W.
Sample Description
Soil, Sample #1
Soil, Sample #2
I
Sediment, Sample #3
Water, Sample #4
Sediment, Sample #5
Soil, Sample #6
Soil, Sample #7
Soil, Sample #8
Soil
Soil
Soil
Soil
Analyzed?
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
No
No
Yes
Yes

-------
                                                                                                  3/15/79


Table A~l.  Sample Description                                                               Page 6 of 15
                                             Set c (continued)
Sample No.
7724
7725
7726
7727
Sampling Location '
1/2 mile N.E. of Corry Foam Products,
Corry, PA
1/2 mile S.W. of Corry Foam Products,
Corry, PA
Corry Foam Products, Corry, PA, N.E.
Corry Foam Products, Corry, PA, S.E.
Sample Description
Soil
Soil
Soil
Soil
Analyzed?
No
No
Yes
Yes

-------
Table A-i.  Sample Description
     U.S. Environmental Protection Agency
     Pesticides Branch
     Nashville, Tennessee
                                                   Set d
                                                                                                  3/15/79
Page 7 of 15
Sample No.
7697
7698
7699
7700
7701
7702
7703
7706
7707
7708
7709
7710
7711
7712
7713
Sampling Location
Point #9
Point #2
Point #3
Point #8, Sub 8A
Point #1, Sub C., Corry Foam Products
Milan, TN
Point #8
Point #1, Sub B
Point #1, A
Point #1, Sub
Point #1, Sub E
Point #6
Point #5
Point #8
Point #4
Point #8, Sub 8
Sample Description
Soil
Soil
Soil \
Soil
Live Frog
2 Live Chub
Soil
Soil
Soil
Piece of Foam
Soil
Soil
Wood Soil
Soil
Soil
Analyzed?
No
Yes
Yes
No
No
No
No
Yes
No
No
Yes
Yes
No
Yes
No

-------
                                                                                                          3/15/79
       Table A-l.   Sample Description
                                                          Set e
Page 8 of 15
            U.S. Environmental Protection Agency
            Region IX
            Alameda, California
I
oo
Sample No.
7651
7652
7653
7654
7655
7656
7657
7658
7659
7660
7661
7662
7663
7728
7729
7730
7731
7732
7733
Sampling
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Oxnard STP
Oxnard STP
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Borg-Warner,
Location
California
California
California
California
California
California
California
California
California
California
California


California
California
California
California
California
California

Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant


Plant
Plant
Plant
Plant
Plant
Plant
Sample Description
Soil, Sample #7
Vegetation, Sample #8
Soil, Sample #9
Soil, Sample #10
Vegetation, Sample #11
Soil, Sample #12
Soil, Sample #13
Soil, Sample #14
Soil, Sample #15
Vegetation, Sample #16
Soil, Sample #17
Sludge #1
Sludge #2
Soil, Sample #1
Soil, Sample #2
Soil, Sample #3
Oleander Leaves, Veg., Sample #4
Oleander Leaves, Veg., Sample #5
Oleander Leaves, Veg., Sample #6
Analyzed?
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes

-------
Table A-l.  Sample Description
                                                   Set  f
     New York State Department of Environmental Conservation
     Buffalo, New York
  -  -3/15/79


Page 9 of 15
Sample No.
#1
#2
#3
#4
#5
#6'
#7
#8
Sampling Location
Chemtrol Pollution Services
Chemtrol Pollution Services
Chemtrol Pollution Services
Chemtrol Pollution Services
Chemtrol Pollution Services
Chemtrol Pollution Services
Chemtrol Pollution Services
Chemtrol Pollution Services
Sample Description
W. Faculatative Pond Liquid
E. Faculatative Pond Liquid
New Faculatative Pond Liquid
Landfill #5 Liquid N. Standpipe
Landfill #5 Liquid S. Standpipe
W. Faculatative Pond Sediment
E. Faculatative Pond Sediment
New Faculatative Pond Sediment
Analyzed?
No
No
No
No
No
No
Yes
Yes

-------
Table A-1.  Sample Description
     U.S. Environmental Protection Agency
     Region V, Central District Office
     Sampling and Analysis Division
     E.N. Mortenson, Chemical Engineers
                                                   Set g
                                                                                     DIV4.3/SAMPDES-HTB.10
                                                                                                   3/15/79
Page 10 of 15
Sample No.
4601
4602
4603
4604
4605
4606
4607
4608
4609

1.
2.
3.
4.
5.
6.
7.
8
9.
Sampling Location
SW Corner of Intersection 38th St.
and Commercial, Cairo, IL
Next to Bunge property fence at
36th St. and Commercial, Cairo, IL
SE Corner of Intersection 34th and
Commercial, Cairo, IL
SW Corner of. Intersection 34th and
Poplar, Cairo, IL
SW Corner of Intersection 34th and
and Sycamore, Cairo, IL
NW Corner of Intersection 36th and
Sycamore, Cairo, IL
SW Corner of Intersection 38th and
Sycamore, Cairo, IL
NW Corner of Intersection 38th and
Poplar, Cairo, IL
500 feet NE of Burkart plant property,
Cairo, IL
Sample Description
Soil
78-CM09S01
Soil
78-CM09S02
Soil
78-CM09S03
Soil
78-CM09S04
Soil
78-CM09S05
Soil
78-CM09S06
Soil
78-CM09S07
Soil
78-CM09S08
Soil
78-CM09S09
Analyzed?
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes

-------
Table A-l.  Sample Description
                                             Set g (continued)
      3/15/79






Page 11 of 15
Sample No.
4610
—
4611
4612
4613
4614
4615

10.
11.
12.
13.
14.
15.
16.
Sampling Location
500 feet straight east of plant
property, Cairo, IL
Sample not taken — location not accessible
NW Corner of Intersection 34th and
Poplar, Cairo, IL
SW Corner of Intersection 33rd and Elm,
Cairo, IL
NW Corner of Intersection 36th and Elm,
Cairo, IL
NW Corner of Intersection 39th and Elm,
Cairo, IL
NW Corner of Intersection 40th and
Poplar, Cairo, IL
Sample Description
Soil
78-CM09S10
—
Soil
78-SM09S12
Soil
78-SM09S13
Soil
78-SM09S14
Soil
78-SM09S15
Soil
78-SM09S16
Analyzed?
Yes
No
Yes
Yes
Yes
Yes
Yes

-------
Table A~l-  Sample Description
     Ohio EPA
     Southwest District Office
     7 East Fourth Street
     Dayton, Ohio 45402
     Ken M. Harsh
                                                   Set h
                                                                                                   3/15/79
                              Page  12  of  15
Sample No.
                    Sampling Location
Sample Description
Analyzed?
4616
4617
4618
4619
4620
4621
4622
NE of Cincinnati Chemical Processing
Co. , Batavia, OH
SE of Cincinnati Chemical Processing
Co., Batavia, OH
SW of Cincinnati Chemical Processing
Co., Batavia, OH
NW of Cincinnati Chemical Processing
Co. , Batavia, OH
West Bank Little Miami River near new
SR-32 bridge
Ditch along west bank Little Miami
River near new SR-32 bridge
West bank Little Miami River near old
SR-32 bridge
Soil,
Soil,
Soil,
Soil,
Soil,
Soil,
Soil,
Sample
Sample
Sample
Sample
Sample
Sample
Sample
#1/7
#2/7
#3/7
#4/7 v -
#5/7
#6/7
#7/7
Yes
Yes
Yes
Yes
Yes
Yes
Yes

-------
     Table A~l.  Sample Description
          U.S. Environmental Protection Agency
          Region V, Central District Office
          Sampling and Analysis Division
          E.N. Mortenson, Chemical Engineer
                                                        Set i
                                                                                              '  3/15/79

                                                                                          Page  13 of  15
     Sample Mo.
                 Sampling Locat ion
  Sample Description
Analyzed?
Co
4623     1. West end of north side of Bells' Island,
            south of B/W plant.  6-13-78, Ottawa, «IL

4624     2. Soil with turf from Bells' Island,  south
            of B/W plant and straight north of  Lock-
            master control house, Ottawa, IL

         3. Weitz's cornfield, adjacent east property
            of B/W plant, Ottawa, IL

         4. Weitz's cornfield, 500 feet east of B/W
            property, Ottawa, IL

 —      5. Weitz's cornfield, adjacent to NE corner
            of B/W property, Ottawa, IL

         6. Weitz's cornfield, 500 feet east of NE
            corner of B/W property, Ottawa, IL

4625     7. Across Commercial Road at NE corner of
            B/W property, Ottawa, IL

4626     8. Approximately 700 feet north of NE  corner
            of B/W property, Ottawa, IL     '      *
78-CM10S01,  Soil


78-CM10S02,  Soil



78-CM10S03,  Soil


78-CM10S04,  Soil


78-CM10S05,  Soil


78-CM10S06,  Soil


78-CM10S07,  Soil


78-CM10S08,  Soil
                                                                                                         Yes
                                                                                                         Yes
Broken on
  Receipt'

Broken on
  Receipt

Broken on
  Receipt

Broken on
  Receipt

   Yes
                                                                                                         Yes

-------
                                                Set  i
                                                                                              •   1/15/79


                                                                                           Page  14  of  15
Sample No.
4627
Sampling Location
9. Across Commercial Road at center of north
side of B/W property, Ottawa, IL
10. Approximately 500 feet north of center of
north side of B/W property, Ottawa, IL
11, 50 feet west of NW corner of B/W property,
in McLean's cornfield, Ottawa, IL
Sample Description
78-CM10S09, Soil
78-CM10S10, Soil
78-CM10S11, Soil
Analyzed?
Yes
Broken on
Receipt
Broken on
Receipt
            (Note:  duplicate of this  sample  retained
            at CDO, Region V)

4628    12. 500 feet west of NW corner  of  B/W property
            in McLean's cornfield, Ottawa,  IL

4629    13. 50 feet west of center of  west  property
            line of B/W plant, Ottawa,  IL

4630    14. 500 feet west of center  of  west property
            line of B/W plant, Ottawa,  IL        •"
78-CM10S12,  Soil


78-CM10S13,  Soil


78-CM10S14,  Soil
Yes
Yes
Yes

-------
     U.S. Environmental Protection Agency
     Office of Toxic Substances
     Washington, D.C.  20460
                                                   Set j
                                                                                     DIV4.3/SAMPDES-HTB.15
                                                                                                   3/15/79
                                                                                             Page 15 of 15
Sample No.
     Sampling Location
  Sample Description
Analyzed?
   8669
AID Consulting Engineers
Carpet Sample
   Yes

-------
                       APPENDIX B




GC/MS ANALYSIS RESULTS FOR ENVIRONMENTAL SAMPLE EXTRACTS

-------
Table B-l.  ESTIMATED LEVELS OF POLYBROMINATED BIPHENYLS IN ENVIRONMENTAL SAMPLES
                                                                                 a.n
Sample Code
7-14
5-17
7-4
7-10
5-13
9-30
m
7-6
7-8
9-3
f 8
9-7
9-16
9-15
7
9-22
9-18
7-9
23-2
9-20
9-1
7-2
23-1
Type
Killifish, Composite
Br. Bullhead Catfish
Blue Claw Crab, Composite
Striped Bass
American Eel
Carp

Sediment
Sediment
Blue Claw Crab, Composite
Sediment
Striped Bass
Striped Bass
Striped Bass
Sediment
White Perch
Striped Bass
Striped Bass
Winter Flounder
White Perch
Bluefish, Composite
Menhaden, Composite
Winter Flounder
C12H4Br6C C12H3Br7 C12H2Br8 C12HBr9 C12Br10
2.9 ng/mld -e -
2.0 ng/ml - -
Tf _
1.1 ng/mlg - -
2.9 ng/mld - - -
_

- - - - -
_ _ _ _ _
0.9 ng/mld - -
5.2 ng/ml - - - -
1.3 ng/ml - - -
1.0 ng/ml - -
T -
3.5 ng/ml - - - -
9.0 ng/mld - -
8.1 ng/ml - ' -
3.0 ng/ml - -
_ _
1.3 ng/ml - - - -
5.6 ng/ml 1.7 ng/ml - - -
5.1 ng/ml 2.6 ng/ml 2.9 ng/ml
1.5 ng/ml - -

-------
Table B-l. (continued)
Sample Code
7-7m
9-31
9-28
9-26
9-10
7657h
7727h
7723
7651h
7659
h
8504
h
7728
h
7695
h
7661
7716
7722
7706
7709
7710
7712
7714
7726
Type
Sediment
White Catfish
Carp
White Perch
Striped Bass
Soil
Soil
Soil
Soil
Soil
Sediment
Soil
Soil

Soil
Sediment
Soil
Soil
Soil
Soil
Soil
Sediment
Soil
C12H4Br6C C12H3Br7 C12H2Br8 C12HBr9 C12Br10
_
0.6 ng/ml - -
T -
0.7 ng/ml - -
2.4 ng/mld - -
111,000 ng/ml8 - 7,600 ng/ml8 - ~
12,700 ng/ml8 - -
410 ng/mld - - . - -
31,000 ng/ml1 - _ _ _
18,500 ng/mld - _ _ _
26,800 ng/ml8 460 ng/ml8 - - -
253,000 ng/ml8 6,400 ng/ml8 ~ ~
146,000 ng/mld 8,700 ng/mld 2,900 ng/ml
A
1,700 ng/ml - _ _ _
490 ng/mld - _ _ _
480 ng/mld - _ _ _
1,100 ng/mlg - -
1,200 ng/mld - _ _ _
190 ng/ml8 - -
320 ng/ml^ - _ - _
280 ng/ml8 - _ - -
450 ng/ml8 - _ _ _

-------
                                            Table B -1.  (continued)
Sample Code









w
OJ
7732
7698
7699
8503
76621"
5-2
7730h
7654h
76631"
8528m

Type
Vegetation
Soil
Soil
Sediment
Sludge
Spot, Composite
Soil
Vegetation
Sludge
Sediment

C12H4Br6C C12H3Br7 C12H2Br8 C12HBr9 C12Br10
880 ng/mlk - -
290 ng/mlg - _ _ _
160 ng/ml1 - -
290 ng/ml1 - _ _ _
950 ng/mld - - -
7.1 ng/m - . - -
429,000 ng/ml8 40,300 ng/ml8 - -
330,000 ng/mld 20,000 ng/mld - - -
590 ng/mld - -
11,500 ng/ml 400 ng/ml - - -

 Samples as received from Environmental Science and  Engineering,  Inc., were  taken  to  dryness  under  a  slow stream of
 dry nitrogen.   Samples  were then concentrated  or diluted  to  the  appropriate volume with  dry  toluene  and  the appro-
 priate standard (octachloronaphthalene or  decachlorobiphenyl) was  added  at  a  level of  2  ng/pl.   The  samples were
 analyzed by gas chromatograph/mass  spectrometer/computer  using a Finnigan 3300  gc/ms equipped with a PDP-12 computer.
 The chromatographic column used  was a 45 cm x  0.2 cm i.d.  glass  column packed with 2%  OV-101 coated  on Gas-Chrom Q
 with a helium  flow rate of 20 cc/min,  and  an initial temperature of  220°C programmed to  280°-300°C at 4°/min.   The
 temperature of the glass jet separator was 250°C, the injector 280°C.  The  polybrominated  biphenyls  were analyzed by
 selected ion monitoring techniques  (see Appendix B  for ions  monitored and retention  times  observed).

 Sample code as received from Environmental Science  and Engineering,  Inc.

"Three positional isomers used as standards were not resolved under the chromatographic conditions  used.   Ratios
 between members of the  isotope clusters were used for verification of compound  identity  (as  well as  retention  time);
 full scan verification  was obtained for some samples (see Appendices C and  D).

 Average of two determinations.

-------
                                            Table B-l. (continued)


e
 Undetectable.


 Less than 0.5 ng/yl, but distinctly present.

a
 Average of three determinations.


 Presence of polybrominated biphenyls was confirmed by full scan (see Appendix D).


 Average of four determinations.


 Average of seven determinations, over a two-week interval.


 Average of six determinations.


 Average of five determinations.


T)ecachlorobiphenyl (ion 502) was used as a standard instead of octachloronapthalene (ion 404)  because of inter-

 ferences in the 400-490 channels.


 See Appendix E for some representative Selected Ion Monitoring Traces.

-------
                     Table B-2. ESTIMATED LEVELS OF POLYBROMINATED BIPHENYLS IN ENVIRONMENTAL SAMPLES'
w
Sample Code
77-18

77-17
77-19
76-86
76-60
77-31
76-55
76-52
76-58
77-33
77-29h
76-53h»i
76-96h'i
86-69
Type
Soil

Soil
Soil
Soil
Vegetation
Oleander Leaves
Vegetation
Vegetation
Soil
Oleander Leaves
Soil
Soil
Soil
Carpet
C12H4Br6C C12H3Br7 C12H2Br8 C12HBr9 C12BrlO
610 ng/mLd -6 - -
f
T - -
Tf - - - -
1,100 ng/mLd - - -
900 ng/mLd - -
650 ng/mLd T - -
Tf - - - -
- - -
1,300 ng/mLd - -
500 ng/mL8 - -
2,291,000 ng/mLB 830,000 ng/mL -
35,000 ng/mLd 2,300 ng/mL - -
132,000 ng/mLd 20,000 ng/mL8 - -
— — _ — —
      Samples as received from Environmental Science and Engineering, Inc., were taken to dryness under a slow stream of
      dry nitrogen.   Samples were then concentrated or diluted to the appropriate volume with dry toluene and the appro-
      priate standard (octachloronaphthalene or decachlorobiphenyl) was added at a level of 2 ng/ul.  The samples were
      analyzed by gas chromatograph/mass spectrometer/computer using a FInnigan 3300 gc/ms equipped with a PDP-12 computer.
      The chromatographic column used was a 45 cm x 0.2 cm i.d. glass column packed with 2% OV-101 coated on Gas-Chrom Q
      with a helium flow rate of 20 cc/min, and an initial temperature of 220°C progrmrmied to 280°-300°C at 4°/mln.  The
      temperature of the glass Jet separator was 250°C, the injector 280°C.  The polyhromlnated blphenyls were analyzed by
      selected ion monitoring techniques (see Appendix B for ions monitored and retention times observed).

      Sample code as received from Environmental Science and Engineering, Inc.

-------
                                            Table B-2. (continued)


£
 Three positional isomers used as standards were not resolved under the chromatographic conditions used.   Ratios
 between members of the isotope clusters were used for verification of compound identity (as well as retention
 time); full scan verification was obtained for some samples (see Appendices C and D).
 Average of two determinations.
G
 Undetectable.

 Less than 0.5 ng/uL, but distinctly present.
p
 Average of three determinations.
 Presence of polybrominated biphenyls was confirmed by full scan (see Appendix D).
 Decachlorobiphenyl (ion 502) was used as a standard instead of octachloronaphthalene  (ion 404)  because of
 interferences in the lower mass channels.

-------
TableB -3.  Estimated Levels of Polybrominated Biphenyls
               in Environmental Samplesa»h
Sample Code
Solvent Blank #1
Soil Blank (ll/8)d
Soil Blank (11/17) 3
Soil Spike #ld
Soil Spike #2d
46-01d
46-026
46-03d
46-04d
46-056
46-066
46-076
46-086
46-09d
46-10d
46-lld
46-12d
46-13d
46-14d
46-15d
46-16d
46-17d
46-186
46-196
46-20d
46-21d
46-22d
46-23d
46-24d
46-25d
46-26d
46-27e
C12H4Br6
_f
—
—
8,000 ng/ml
7,000 ng/ml
1,700 ng/ml
13,200 ng/ml
400 ng/ml
1,600 ng/ml
11,100 ng/ml
8,300 ng/ml
6,300 ng/ml
11,300 ng/ml
300 ng/ml
330 ng/ml
100 ng/ml
70 ng/ml
100 ng/ml
— *
50 ng/ml
43,100 ng/ml
3,700 ng/ml
14,900 ng/ml
16,500 ng/ml
60 ng/ml
700 ng/ml
200 ng/ml
570 ng/ml
130 ng/ml
2,500 ng/ml
2,500 ng/ml
3,400 ng/ml
C12H3Br7
__
—
—
—
—
—
trace0
—
—
trace
trace
trace
trace
trace
trace
—
trace
trace
__
—
trace
trace
trace
trace
—
trace
—
—
trace
trace
—
trace
C12HBr9   C-pBr
                                                                10
                                       trace
                            B-7

-------
                       TableB.-3. (continued)
 Sample Codeb       C12H4Br6      C12H3Br7   C12H2Br8
46-28d
46-29d
46-30d
440 ng/ml trace
180 ng/ml
170 ng/ml
— •_ H«
— —
— —
  Samples as received from Environmental Science and Engineering,  Inc.
 were taken to dryness under a slow stream of dry nitrogen.   Samples
 were then taken up in an appropriate volume of dry toluene  and the
 appropriate standards (octachloronaphthalene and decachlorobiphenyl)
 added at a level of approximately 2 ng/yl.  The samples were analyzed
 by gas chromatograph/mass spectrometer/computer utilizing either  a
 Finnigan 3300 GC/MS equipped with a PDP-12 computer (chromatographic
 column, 45 cm x 0.2 cm i.d., glass, 2% OV-101 on Gas-Chrom  Q; helium
 flow, 20 cc/min; initial temperature, 220°C programmed to 280°-300°C
 at 4°/min; separator temperature, 250°C; injector temperature, 280°C)
 or an LKB-2091-050 EI/CI (chromatographic column, 45 cm x 0.2 cm  i.d.,
 glass, 2% OV-101 on Gas-Chrom Q;  helium flow, 18 cc/min; initial  tem-
 perature, 220°C for one minute, then programmed to 290°C at 8°/min;
 separator temperature, 275°C; injector temperature, 280°C;  ion source
 temperature, 250°C).  The polybrominated biphenyls were analyzed  by
 selected ion monitoring techniques (see Appendix B for ions monitored
 and retention times observed).
 Sample code as received from Environmental Science and Engineering, Inc.
£
 Positional isomers used as standards were not resolved under the  chro-
 matographic conditions used.  Ratios between members of the isotope
 clusters were used for verification of compound identity (as well as
 retention time); full scan verification was obtained for some samples
 (see Appendices C and D).

 Average of two determinations,  one instrument.
 Average of three determinations,  both instruments.
 Undetectable.
o
"Present as a distinct peak but not reproducibly quantifiable.

 See Appendix E for some representative Selected Ion Monitoring Traces.
                                   B-8

-------
                   APPENDIX C

RETENTION TIMES AND IONS MONITORED FOR ANALYSIS OF
             POLYBROMINATED BIPHENYLS

-------
                                            APPENDIX C

                  TableC -1.  RETENTION TIMES AND IONS MONITORED FOR ANALYSIS OF
                                     POLYBROMINATED BIPHENYLS*
        Compound                       Retention Time                       Ion(s) Monitored

Octachloronaphthalene                 ^1.3 min                             404
(Standard)
Decachlorobiphenyl                    ^1.5 min                             502
(Standard)
Hexabromobiphenyls,
2,2',4,4',6,6'-                       ^ 1.7 min                             626, 628, 630, 632
2,4,5,2',4',5'-                       ^ 1.7 min                             626, 628, 630, 632
3,3',4,4',5,5'-                       * 1.7 min                             626, 628, 630, 632
Heptabromobiphenyl                    ^2.5 min                             706
Octabromobiphenyl,                                                          784
2,2',3,3',5,5',6,6'-                  ^7.8 min
Nonabromobiphenyl                     ^8.2 min                             862
Decabromobiphenyl                     VL0.2 min                             942

 Decachlorobiphenyl was used as a standard for those samples in which the ion characteristic of
 Octachloronaphthalene (404) could not be used for quantitation.

 Under the chromatographic conditions used, the hexabromoblphenyl isomers used as standards were
 not resolved.

 Heptabromobiphenyl was present as an impurity in the octabromobiphenyl standard; the positional
 isomer was not identified.  Nonabromobiphenyl was also observed.

*Applies  to  samples  reported in Tables B-1 andB-2.

-------
                            Appendix C

    Table C.-2.  Retention Times and Ions Monitored for. Analysis
                    of Polybrominated Biphenyls*
      Compound              Retention Time       Ion(s) Monitored

Octachloronaphthalene          ^2.5 min               404
(Standard)

Decachlorobiphenyla            ^2.8 min               502
(Standard)

Hexabromobiphenyls
2, 2', 4,4', 6, 6'-
3, 3', 4, 4', 5,5'-
Heptabromobiphenyl
Octabromobiphenyl
Q
Nonabromobiphenyl
Decabromobiphenyl
'VJ.O
'XJ.O
^5.4
^7.2
^9.5
^10.8
min
min
min
min
min
min
626, 628, 630
626, 628, 630
706,
784,
864,
942,
708
786
866
944
 Decachlorobiphenyl was used as an auxiliary standard to provide
 a reference in those cases in which the ion characteristic of
 Octachloronaphthalene (404) could not be used for quantitation
 because of interferences in that channel.

 Under the chromatographic conditions used, the hexabromobiphenyl
 isomers used as standards were not resolved.
 Heptabromobiphenyl (isomer unidentified) was present as an impur-
 ity in the standards labeled "octabromobiphenyl" and "decabromo-
 biphenyl."

 Octabromobiphenyl (any isomer in a relatively pure form) can no
 longer be purchased for use as a standard.
Nonabromobiphenyl (isomer unidentified) was present as an impurity
 in the standards labeled "octabromobiphenyl" and "decabromobi-
 phenyl."

 Decabromobiphenyl in a pure form can no longer be purchased for
 use as a standard.

*Applies to samples reported in Table B-3.
                                C-2

-------
                  APPENDIX D

RATIOS OF IONS USED TO CONFIRM THE PRESENCE OF
            POLYBROMINATED BIPHENYLS

-------
                                 APPENDIX D

         Table D-l.  RATIOS OF IONS USED TO CONFIRM THE PRESENCE OF
                          POLYBROMINATED BIPHENYLS*
Hexabromobiphenyl
   Theoretical                                        Observed

   626:628       0.766                 7-10      (Striped Bass)
   628:630       1.363                           626:628      0.715
   630:632       2.553                           628:630      1.346
                                                 630:632      2.102

                                       9-1       (Bluefish, Composite)
                                                 626:628      0.754
                                                 628:630      1.373
                                                 630:632        NR*

                                       23-1      (Winter Flounder)
                                                 626:628      0.762
                                                 628:630      1.367
                                                 630:632
                                       7659      (Soil)
                                                 626:628      0.725
                                                 628:630      1.345
                                                 630:632      2.345

                                       7728      (Soil)
                                                 626:628      0.772
                                                 628:630      1.370
                                                 630:632      2.655

                                       7651      (Soil)
                                                 626:628      0.727
                                                 628:630      1.390
                                                 630:632      2.640
                                       7716      (Sediment)
                                                 626:628      0.727
                                                 628:630      1.481
                                                 630:632      2.192

                                       7732      (Vegetation)
                                                 626:628      0.716
                                                 628:630      1.509
                                                 630:632      2.404

                                       8503      (Sediment)
                                                 626:628      0.714
                                                 628:630      1.334
                                                 630:632      2.053
                                       D-l

-------
                           Table D-l.  (continued)
Hexabromobiphenyl
   Theoretical                                        Observed

                                      7654       (Vegetation)
                                                 626:628      0.746
                                                 628:630      1.373
                                                 630:632      2.404

                                      7662       (Sludge)
                                                 626:628      0.886
                                                 628:630      1.318
                                                 630:632      1.987

 wot Recorded

^Applies to samples reported in Table B-l.
                                       D-2

-------
                                 APPENDIX D

          Table D~2-  RATIOS OF IONS USED TO CONFIRM THE PRESENCE OF
                           POLYBROMINATED BIPHENYLS*
Hexabromobiphenyl
   Theoretical                                         Observed

   626:628      0.766                   76-53     Soil
   628:630      1.363                             626:628     0.750
   630:632      2.553                             628:630     1.364
                                                  630:632     2.712

                                        76-58     Soil
                                                  626:628     0.761
                                                  628:630     1.323
                                                  630:632     2.239

                                        77-29     Soil
                                                  626:628     0.700
                                                  628:630     1.382
                                                  630:632
                                        77-33     Oleander Leaves
                                                  626:628     0.716
                                                  628:630     1.377
                                                  630:632       NR*
 wot recorded.

* Applies to samples reported in Table B-2.
                                       D-3

-------
                      Appendix D

TableD -3.  Ratios of Ions Used to Confirm the Presence
                 of Hexabromobiphenyl
    Theoretical                    Observed
626:628 0.766 46-02 626:628
628:630 1.363 628:630
630:632 2.553 630:632
46-05 626:628
628:630
630:632
46-06 626:628
628:630
630:632
46-07 626:628
628:630
630:632
46-08 626:628
628:630
630:632
46-18 626:628
628:630
630:632
46-19 626:628
628:630
630:632
46-27 626:628
. 628:630
630:632
0.732
1.345
2.628
0.732
1.340
2.430
0.753
1.367
2.566
0.755
1.407
2.378
0.750
1.308
2.433
0.729
1.322
2.451
0.798
1.246
2.311
0.701
1.380
2.623
 aSelected Ion Monitoring to confirm ion ratios was
  performed on the Finnigan 3300 under conditions
  delineated in footnote a of Table B-3.
 *Applies to samples reported in Table B-3.
                           D-4

-------
                           APPENDIX E

FULL SCAN SPECTRAL CONFIRMATION OF THE PRESENCE OF POLYBROMINATED
              BIPHENYLS FOR REPRESENTATIVE SAMPLES

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j • i • -i i • - ! • i • i i ' i 1 i • i • i • i i • • i • i
00 o ."-0 pr'n 9'.,n
                   m/z
76-53 (Soil),  1.74 min,  hexabromobiphenyl

-------
i
M
•~J
           C
           0)
                                                 ,.l  I.,)
                                                    500
                                         .   i  IP li	' I  J	I  [i 	I i     j	II I. i.i i
                                         I 'I •  I  I • I • I • I  ' I • I ' ( '" T ' T ^ I ' I ' I  ' I ' I • |-• f • I ' I ' I "I '~r^-t • |~' I
                                               57.O        ff.ni!         6'50         rno         r'.'-n

                                                  m/z
                100-
                 eo-
           en
           C
           
-------
I
M
00
           4J
           •H
           U)
           c
           0)
           0)
           c
           0)
           4J
           C
90-


80-


ro-


60-




.10-
                                                                                            rno
                                                                                                      i  T-T- i
                                                                                                       r .11
                 20-


                 10-
                                        ?nn         q^.n         /
                                                            m/z

                                        76-96 (Soil),  1.74 min,  hexabromobiphenyl

-------
PI
i
         (0

         C
         0)
          ui
          C
          
-------
w
                   W
                   c
                   0)
..!li.::- h IIL.	,1
 i  r	r ' f
    f,dn



^
4J
•H
CO
g
4-1
e
M



100-
90-
80-
70-
60-
50-
40-
50-
ro-
10-
nn-









                                     I  T ^ I '-T  TT T^ J  I  I T T T 1 ^ I T I ' I • \ ^ 1

                                       850        3^          ?fcD      m/z


                                                    76-96  (Soil),  5.33 min,

-------
i
N3
                  108-,


                  90-


                  80-


                  70-


             W    60-
             •H


             S    5
             0)


             c    40-
                  20-


                  10-


                  no-
                    350
     iHvv
                               'j'i'i'i'i'i'i'i -i --j •
                               400         450        500
                                                                   '""T	I	I	I	I "'I "-T-i-T'-|"T"""T	-p-
                                                                    (550        rnn         r';.0
              V)

              
-------
w
M
                 0)
100-





 R0-


 70-


 60-


 50-


 40-


 in-






 10-
                                                 ill
Illl, 1,1 . .
450 500
•':''
~r"1 r| 1 ' T-'-T--
^•0
m/z

1 1 ' j r \ ' 1 ' | ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 r 1 ' 1 ' | r
GOO fi^.o n.in
_. 	 , 	 	 	 jj.,,,,,.,..
rr('|pri'i'i
r'j.n
                               i-- r- I - i • i • i • i • j • i  i ' I - T • j •
                                   P:.n        ?nn         ';..d      myfz


                                          77-29  (Soil),  1.24 min,  pentabromobiphenyl

-------
M
ensi
                 100-
                  90-
                  80-
                  70-
                  60-
                  50-
                  40-
                  30-
                  20-
                  10-
                  00-'
                                                                                          , . r ,
                                                                                           TOO
                                                               m




4J
•i-l
10
fi
0)
t-l
C
M





100-
90-
80-
70-
60-

50-

40-

30-
20-
10-
nn-













. . l . . j
8*10 S .0 "f'O "^'jO m / -7
j - j J.L .. _ j . m/^
                                            77-29 (Soil), 1.58  min, hexabromobiphenyl

-------
w

ho




X
iJ
•H
to
C
0)
c
M




ino-
90-
Pfl-
s re-
.60-
50-

40-

?0-
20-
10-

00-





i








• i • i ' i ' i '









1
I
1
           to
           C
           OJ
                   350
                100-
                 7.0-
                 10-
                                               MM  I
                                                 500
                                                                      r. no
                                                                                        i • r -• J  i • i - i ••• i • I •  i
                                                                                           rdo        r..n
                             p^n       gTn        95«       m/z

                                      17-29  (Soil),  2.58 min,  heptabromobiphenyl

-------
Sample 46-25, concentrated 20:1.  Hexabromobiphenyl (isotope cluster
centered at m/z 628) co-elutes to some extent with the octachloro-
naphthalene used as a standard.
                                  E-25

-------
N>
             Sample  46-13,  concentrated  50:1.  Hexabromobiphenyl  (isotope cluster barely visible centered
             at  m/z  628)  can just  be  seen  at  this  level.

-------
M
        £8-
                                                                                 I, jj i JlllLI.L.
J.lll..iJ.li  ..I.I..
                                                                                                            o
                                                                                                            o
                                                                                                            r\-
               Sample 46-25,  concentrated 20:1.   The hexabromobiphenyl  isotope cluster is visible.

-------
7
00
         ID.
         00
        5
         ID.
         (M
                                                                              u  .  . Ji.
1.. h.j
                                                                                        o
                                                                                        o
                                                                                        u>
               Sample 46-16, unconcentrated.  The  hexabromobiphenyl isotope cluster  is evident.

-------
                 APPENDIX F




REPRESENTATIVE SELECTED ION MONITORING TRACES

-------
co
c
0)
  100.0--
   80.0-
   60.0-
   40.0-
   20.0-
      .B-
                         ,

                         ^Vv.-s^  632x10
                          '^^  630x4

                                    628 x  2
                          '-)•>—^—r*-^-
                          —	  626 x  1
                    Time/minutes

                  7727  (Soil), 1:1
   100.0-r
   60.0-
>> 60.0-
4J

CO
c
0)


£  ^0-0-
   20 . H-
     .0-
        e
                                     706 x  10
                    Time/minutes

                  7657 (Soil),  1:1

-------
>>
4-1
•H
CO
C
01
4-1
C
    80. EH
    60.0-
   40.0-
   20.0-
      .0-
   180.e-r
    80.0-
    60.6-
co
C  40.0-

4-1
C
   20.0-
      .0-
                                     706
                                ..,.
                              •	.   628  x 1
                      Time/minutes
                    7651 (Soil),  1:1
                   •''• .   '.      .v«.  706 x  10
                   ~.-,_ :WM-^- - 62g
                      Time/minutes
                    7695  (Soil), 1:1
                         F-2

-------
  100.0-1
  80.0-
w 60.0-:
c
QJ
  40 . U -
  20.0-
     .0-
             V.
              •*>,
                      >-~«.-<.»~*j«t>   404 x 1
                                  628 x 1
                                  706 x 1
  180.0-
   80.0-
4-1
•H
cn
c
0)
   68.0-
   40.0-
   20:0-
     .8-f
                  Time/minutes
                7695 (Soil),  1:1
                   706 x  10
v \
                                   404 x 1
                                   628 x 1
                                   632 x 1
                  Time/minutes
                7728 (Soil), Diluted
                    1:100
                       F-3

-------
100.0-
80.0-
£ 60.0-
w
C
V
4J
c
M
40.0-

20 . 0-


r
•
.
• • *
.''
.''"'''<•..,*.
""*•.%-<.« 404 x 1
* *
S, ' :., V 628 x 2
— :—--*•• - -- * •' •. — -»i ••"—*»//>. , _ - .
^^: 	 ;m!^-' '• 	 626 x l
                    Time/minutes
                  7661 (Soil), 1:1
C
OJ
  100.0--
   80.0-
   G0.0-
   46.0-
   20.0-
     .o-
706 x 10


628 x 5

404 x 1
                    Time/minutes
                  7712  (Soil),  1:1
                        F-4 .

-------
c
0)
   188.0-
   80.8-
    60.0-
    40.0-
    20.8-.
      ,0-t
            ^—"^
       404 x  1
    '"" 628 x  2
       626 x  1
                        Time/minutes
              7732  (Vegetation),  Concentrated
                          5:1
>>
0-1
•H
CO
   180.0--
    80.0-
    60.0-
    48.8-
    20.0-
*.^,  » ^ x 1


  '^-*' 628 x 5
      .8-
                       Time/minutes
                  7699 (Soil),  Concentrated
                           5:1
                         F-5

-------
cn
c
(U
  100.3	
   80.0-
   60. e-
   40.0-
•.^l-Vrv"-•'./••• 706  x  15
•».  •.   •»' •• •.•
•H
(A

0)
   160.0-r
   8Q.B-
   60.0-
   40.0-

                                    628  x 5
                                   404  x 1
                       Time/minutes
                     7698 (Soil), 1:1
   20.0-

     .0--,
                                 f 404 x 1
                                /w 628 x 5
                                   630 x 1
                       Time/minutes
                     7698 (Soil), Concentrated
                          5:1
                          F-6

-------
  100.0-
   30.0-
   60.0-
01
   40. 0-:
   20.0-
                               ** 628 x 3
                     Time/minutes
                   7698 (Soil), 1:1
   IOC . "i-.
en

-------
   100.0-r
   60.0-
tn
c
01
628 x 10
                                    x  1
                 Time/minutes
              77-18  (Soil),  1:1
     ieo.e-i
      ee.0-
      68.8-
  Cfl

  S   40.B-
      20.0-
        .8-
                                628 x 1
                                502 x 1
                 Time/minutes
              77-96  (Soil), 1:5
                         F-8

-------
   100.6-
   60.0-
>i 60.0-
±j
•H
cn
c
1i
u  40.0-
C
     .0-
 w

 01
   ee.e
   60.0-
   40.0-
   20.0-
    .0-
                          ,,,%   706 x 5

                              628 x 1
                          ""   502 x 1
                 Time/minutes
             76-53 (Soil), 1:1

                                626 x 20
                               «04 x 1
                               502 x 1
                 Time/minutes
            86-69 (Carpet), 10:1
                        F-9

-------
   18B.0-1
   80.8-
•H
03  60.0-
c
OJ
4-1
C
M
   20.0-
     .0-
                                 628 x 10
                                 iOA x 1

                                 502 x 1
                Time/minutes
        77-33  (Oleander Leaves), 33:1
                      F-10

-------
(fl
c
0)
   502
   404
                 Time (minutes)


       Sample:  Soil Spike #2, Unconcentrated



   Standards:  octachloronaphthalene  (ni/z_ 404)  and

               decachlorobiphenyl  (m/^_ 502).
                           F-ll

-------
   630


>%



"5  628


0)
AJ
c
M

   626
                          Time (minutes)


                Ions monitored for hexabromobiphenyl,

                observed in Soil Spike  //2.
                                      F-12

-------
w  708
•H
05


2  706
c
                    Time  (minutes)



Ions monitored for heptabromobiphenyl,

Soil Spike //2.
                                                     Not observed in
                                          F-13

-------
Cfl
e
0)
   786
   784
                   Time (minutes)


Ions monitored for octabromobiphenyl
in Soil Spike #2.
                                                        Not  observed
                                           F-14

-------
   866 x 8
en
e
01
4J
c
M
   864 x 8
                                         Time  (minutes)



                   Ions monitored for nonabromobiphenyl.  Not observed  in

                   Soil Spike #2, even amplified by a factor of 8  (note

                   enhancement of noise).
                                            F-15

-------
»  502
c
0)
   404
                        M
                     Time  (minutes)



             Sample:   Soil  Blank //I,  Unconcentrated


          Standards:   octachloronaphthalene (m/£ 404)

                       and decachlorobiphenyl (in/£ 502)
                          F-17

-------
1  63°
0)
£  628
   626
                                  Time (minutes)

                   Ions  monitored  for hexabromobiphenyl.
                   Not observed  in Soil Blank #1.
                                     F-18

-------
   708
en
c

-------
•H  786

-------
>,  866 x 8
en
c
0)
c  864  x 8
                                                                I ..... I
                                     Time (minutes)



                   Ions monitored for nonabromobiphenyl.  Not

                   observed in Soil Blank #1.
                                           F-21

-------
   502
en
c
01
c 404
     Sample:
Standards:
                       eg      p»       •«•      i
                       Time (minutes)
                      46-02,  Unconcentrated
                    octachloronaphthalene (W^ 404) and
                    decachlorobiphenyl (m/^ 502) .   Note
                    that  while  there is interference in
                    the 404 channel, the 502 channel is
                    clear.
                             F-23

-------
   630
I  628
cu
   626
                 I '  ' ' ' '  I 	 | ..... | ... I . | .. 1 1 I  | I 1 I I T j-.-.-.-.-.-j



                 ••       cu      i*>       *      m       w      rw       •





                                Time (minutes)




                     Ions monitored for hexabromobiphenyl,


                     present  in Sample 46-02.
                                 F-24

-------
Cfl

ID
   708
  706
                               Time  (minutes)

              Ions monitored for heptabronobiphenyl, present  in
              trace quantities in Sample 46-02.
                                     F-25

-------
   630

   628
g  626
   502

   404
                 Sample:

              Standards:
 Time (minutes)

46-12, Concentrated 50:1

octachloronaphthalene (m/^z 404, note
interference) and decachlorobiphenyl
(in/£ 502, clear channel).  Ions
monitored for hexabromobiphenyl,
present in this sample.
                                     F-26

-------
  502
w 404
0)
          I
F

(M
                Time (minutes)

          Sample:  46-25, Unconcentrated

        Standards:  octachloronapthalene  (m/^ 404)
                    and decachlorobiphenyl  (m/z 502)
                       F-27

-------
(fl
c
0)
   630
   628
   626
, ,  I , 1 • I  I I I 1 1 I T , I I-I 1
                                                             I '  ' ' '"''I
                                 Time  (minutes)


                    Ions monitored for  hexabromobiphenyl,

                    present in Sample 46-25.
                                    F-28

-------
   502
Cfl
d
4J
c  404
           •'I'l'l'l'l'l'l'l'l'l'l'l'l'l'l'l' I I^T ITTI'I'I'I'l

               •«      w      r»       *      i


                    Time  (minutes)


            Sample:  46-26,  Unconcentrated

         Standards:  octachloronaphthalene (m/£ 404)

                     and  decachlorobiphenyl (ra/z  502)
                                F-29

-------
   630
1  628
0)
   626
                 "I I'l'i'i'i'i'i'i'i'i'i'i'i'i
                                                  in
                                                                   i i • i • i •
                                                                        i • i
                                  Time (minutes)


                       Ions monitored for hexabromobiphenyl,

                       present in Sample 46-26.
                                       F-30

-------
£  502
(0
c
0)
   40A
            r
                   Time (minutes)


            Sample:   46-29,  Concentrated 50:1



         Standards:   octachloronaphthalene (m/£ 404,

                     note interference) and decachloro-

                     biphenyl (m/z 502, clear channel).
                    F-31

-------
03
C
0)
   630
   628
   626
                                 Time (minutes)
                                                     I '

                                                     to
                    Ions monitored for hexabromobiphenyl,
                    present in Sample 46-29.
                                    F-32

-------
                                   TECHNICAL REPORT DATA
                            (fleas* read Instructions on the reverse before compleringl
 REPORT NO.
    EPA-560/13-79-001
                                                           3. RECIPIENT'S ACCESSION NO.
 TITLE ANO SUBTITLE
Analysis  for Polybrominated Biphenyls (PBBs) in
Environmental Samples
                                                           S. REPORT DATE
                                                             March, 1979
                                                           8, PERFORMING ORGANIZATION CODE
. AUTHORISt
Charles  L.  Stratton, John J. Mousa and Joan T.  Bursey
                                                           8. PERFORMING ORGANIZATION REPORT NO.

                                                            Research Request #3, Final Re-
                                                            port
i. PERFORMING ORGANIZATION NAME ANO AOORESS
Environmental Science and Engineering, Inc.
P. 0.  Box 13454
Gainesville,  Florida  32604
                                                            10. PROGRAM ELEMENT NO.
                                                                 Task  IIIB
                                                            1ITCONTHACT/GHANTNO.
                                                                   68-01-3248
12. SPONSORING AGENCY NAME ANO AOORESS
U.S.  Environmental Protection Agency
Office  of Toxic Substances
401 M.  Street, SW
Washington.  DC  20460	
                                                            13. TYPE Of REPORT ANO PERIOD COVERED
                                                             Final  4/78-4/79
                                                            14. SPONSORING AGENCY CODE
IS. SUPPLEMENTARY NOTES
16. ABSTRACT
Ninety-eight environmental samples consisting  of fish, sediment,  soils, and vegetation,
were  analyzed by gas  chromatographic/mass spectrometry (GC/MS)  techniques for hexa-,
hepta-,  octa-, nona-,  and decabromobiphenyls.   The samples were collected by EPA
regional office personnel.  Hexabromobiphenyl  was  the most prevalent  species detected.
This  species was detected in 84 percent of the samples over the range of  0.2 to 50,000
ppb.   Heptabromobiphenyl  was detected in 12 percent of the samples and octabromobi-
phenyl in 2 percent of  the samples.  Nonabromobiphenyl and decabromobiphenyl were not
detected.
17.
                                KEY WORDS ANO DOCUMENT ANALYSIS
                  DESCRIPTORS
                                              b.lOENTIFIERS/OPEN ENDED TERMS  C.  COSATI Field/Croup
 Polybrominated biphenyls
 PBBs
 GC/MS
 Brominated organics
18. DISTRIBUTION STATEMENT

 Release unlimited
                                              19. SECURITY CLASS (Thu Aeporti
                                                 unclassified
                                                                          21. NO. Of PAGES
                                              20. SECURITY CLASS (This parti
                                                 unclassified
                                                                         22. PRICE
EPA Form 222O-1 t»-73|

-------