FINAL REPORT
TOXIC POINT SOURCE ASSESSMENT OF INDUSTRIAL
DISCHARGES TO THE CHESAPEAKE BAY BASIN. PHASE
PROTOCOL VERIFICATION STUDY
VOLUME IV
APPENDICES F- J
Contract 68-02-3161
August 1982
MONSANTO RESEARCH CORPORATION
. A SUBSIDIARY OF MONSANTO COMPANY
Monsanto
DAYTON
LABORATORY
DAYTON, OHIO 454OT
-------
903R81107
TOXIC POINT SOURCE ASSESSMENT OF INDUSTRIAL DISCHARGES TO THE
CHESAPEAKE BAY BASIN. PHASE III:. PROTOCOL VERIFICATION STUDY
VOLUME IV
APPENDICES F-J
by
S. C. Wilson
B. M. Hughes
G. D. Rawlings
Monsanto Research Corporation
Dayton, Ohio 45418
Contract 68-02-3161
August 1982
Project Officer
Mark Alderson
Chesapeake Bay Program
U.S. Environmental Protection Agency
Annapolis, Maryland 21401
CHESAPEAKE BAY PROGRAM OFFICE
TOXICS PROGRAM
U.S. ENVIRONMENTAL PROTECTION AGENCY
ANNAPOLIS, MARYLAND 21401
-------
CONTENTS
Appendices
F. Relative Retention Indices of Phase III Effluents . -. F-l
G. Total Ion Chromatograms for Phase III Effluent
Samples G-l
H. Relative Retention Indices of Phase III Sediments . . H-l
I. Total Ion Chromatograms for Phase III Sediment
Samples 1-1
J. Analysis of Blanks and Standards Associated with the
Analysis of Plant Effluents and Sediments J-l
111
-------
APPENDIX F
RELATIVE RETENTION INDICES OF PHASE III EFFLUENTS
A discussion of the generation of these data is contained in
Appendix C, Section 10.
F-l
-------
TABLE F-l. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT A109, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY45
Effluent A109 (8233-Acid)
ANP3 8233
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
I'-'EAK*
1
2
5
6
7
8
9
10
11
12
13
14
15
AREA
28456
6.12828E+07
2629*53
1981.62
19607.5
199572.
4929.37
2278.11
1296.62
1425.94
17074.2
7496,44
3634.37
1779.25
2426.78
TIME
2.08212
2.18333
2.85196
13,99:1.0:1
3.47097
3*5332
7.63229
8.45292
8,59931
9,66632
10,9208
11.5474
12.0143
12.8589
27.6677
INDEX
#**
***
***
***
***
***
***
***
###
***
***
***
***
236.513
F-2
-------
I
U)
•
'Si
o
-n 10000.
i
r-*
UJ
ill RRFifi .
-ri
o
'!'
I.M
i
;>
3
uj 6000 •
<:•)
X
u
p
0.
^-
.
-
-
J
Effluent A109 (8233-Acid)
_
-
\ - . ..<\ k.. I .
'
•
i I. J. .. » . . .. . . j i iii. . . t~. . j. i .
i . i . i . i . i . i , i
a 0.00 6.46 12.80 19.29 25.60 32.00 33.40 44.80
RT in minutes SRMPLE : PNP3 8233 INJECTED PT 14:52:47 ON PUG 9, 1981
Method: BOY 11 Raw: ERY45 Proc: *PRC11
Figure F-l. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent A109.
-------
TABLE F-2. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT A109, FID/GC
PROCESSED FILE! *PRC32
RAW FILE: CBS48
Effluent A109 (8233-Base/Neutral)
SAMPLE NAME:
BNP4 8233
RELATIVE RETENTION VALUES
OUTPUT FILE:
PEAK*
i
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
i8
19
20
21
22
23
24
25
26
27
28
AREA
6486.08
118360.
1.01374E+06
6.42724E+07
1382.12
5332.7
193504.
1384.25
3077.63
2206.37
11350.1
19314.6
1888.22
5878.03
1.50672E+06
213992.
4605,94
2708,69
23563.3
99447.
4994.3
4022.58
3286.52
1612,63
1216,1
1679.05
4646,09
5042,72
TIME
2.15045
2,18696
2.26458
2,28542
3,48958
3,60256
3,71147
4,97917
8.79097
8.87917
11.699
12,4602
13.3462
13.4428
13.8451
13.8562
13.8996
14,5159
15.8896
16,2994
16,3178
16,3452
16.3664
16,3876
16.4067
16.54
16,7582
16,9402
INI1EX
***
***
#**
***
***
***
***
***
**#
***
***
***
***
***
***
**#
***
***
**#
***
***
***
***
#**
***
***
F-4
-------
TABLE F-2 (continued)
29
30
31
32
33
34
35
'A 6
37
38
39
40
41
42
43
44
45
46
47
48
49
50
56
57
1790.5
1226.92
1767.47
6528.86
1056,39
2292.8
14790.1
1112.87
1009.87
36484.3
9932.39
2504
2196.37
51286.6
93933. 1
2427
1264.25
2360,84
4814.62
9753.05
1662.83
28828.2
1153
1857.23
4843.61
23430.9
1499
12049,5
4884,75
17.0033
17.0117
17.0506
17.0778
17.2979
18.3323
18.4193
19.0625
19.1704
19.6089
19,9039
20,4193
20.6052
21.2866
21 ,2982
21 ,7097
22.1234
22.1983
22.5528
23.0415
23.3698
25.922
28.0979
30.2117
30.3057
30,7718
31 .6635
34.8283
41,0875
***
***
***
***
***
***
***
##*
***
#*#
103,393
111.201
114.018
124.343
124.519
130.753
137.022
138.156
143.527
150.932
155.906
194.576
239,867
286,222
288,282
298.505
320,086
397.276
497,271
F-5
-------
10000.
^
I
O>
•3
*
p-
*
C
o
•J
*
Ml
I
\f>
X
u
a
8006
6000
4000. -
Effluent A109 (8233-Base/Neutral)
0.00
RT in minutes
2.10
4.20
6.30
8.40
10.50
12.60
14.70
16.80
SfiMPLE: BHP4 8233 INJECTED OT 11:52:43 ON SEP 11, 1981
Method: BOY32 Raw: CES48 Proc : *PRC32
Figure F-2. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent A109.
-------
G>
O
X
•n
U
i/i
OJ
u
CT
8000
6000 .
4000
Effluent A109 (8233-Base/Neutral)
.,,'
RT in minutes
18.90
21.00
23.10
25.20
27.30
29.40
31.50
33.60
SfiMPLE: BHP4 8233 INJECTED fit 11:52:43 OH SEP 11, 19S1
Method: BOY32 Raw: CBS48 Proc : *PRC32
Figure F-2 (continued)
-------
I
00
e
X
T?
01
o
'J
Ml
i
UJ
OJ
X
u
LL
a
8060 ,
6000 ,
4000. -
-\ q
Effluent A109 (8233-Base/Neutral)
RT in minutes
35.70
37.80
39.90
42.00
44.10
46.24
48.30
50.40
SflMPLE: EHP4 8233 INJECTED fiT 11:52:43 OH SEP 11, 1981
Method: BRY32 Raw: CES48 Proc : *PRC32
Figure F-2 (continued)
-------
TABLE F-3.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B112D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY42
Effluent B112D (8219-Acid)
ANP3 8219
RELATIVE RETENTION VALUES
OUTF-UT FILE: OPF2
PEAK*
1
4
5
6
7
Q
9
10
1 1
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
AREA
3773.4
46008.3
5.64821E4-07
3866.8
70970.4
19574.4
1587.25
1176.7
1747.25
1233.81
11838.9
2984,69
64033.2
72816.2
11649
12035.
6293.23
2187.43
4854.87
3002.25
1597.73
14497.7
5758.72
1035.34
23389.4
7676,31
7764, :16-
5050 , 64
4611.08
13450,7
10958.1
3340.58
1048.34
1320.82
2866.87
TIME
2.096
2.16782
2.19583
3.4737
3.53507
10.9149
12,2344
12.491
12.6969
13.1646
13.9044
14.5571
14.8179
15,2445
115.4275
15,7244
15,8337
15,9804
16.2237
16.4202
16.4875
16.4268
• 16.7142
16.7908
17.0446
17,2121
17,2953
17,3847
18.1648
18,221.1
18,6134
18,6691
18,825
19.003:1
19.0906
INDEX
***
***
***
***
#*#
***
v *• ^
**#
***
***
***
***
***
***
***
***
DC**
***
*#*
***
***
***
***
***
**#
^ ^ 'P
***
***
***
***
***
F-9
-------
TABLE F-3 (continued)
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
4639.94
4323.24
1704.83
2158.69
2865.66
4675.11
2031.44
1824.25
5709.09
1293.91
2146.19
2452.84
4296.84
1748.54
1438.76
4388.83
4267
6336.5
13670.8
8279.73
8717.05
8928.55
3643.12
2789,56
1401.66
2808.03
3465.95
1704.48
6138,34
1408.48
1970.75
4680.52
3118.86
1463.86
8225.69
5134.12
1333.75
19.3367
19.4965
19.65
19.9835
20.2046
20.5451
21.0S42
21.3196
2:1.7539
21.9632
22,2667
22.3542
22.5927
22,8039
23.2971
23.431
23.7429
24,3902
24,6347
24.7972
24.8879
24.8967
24.9536
25.425
25.5548
25.6305
25.9784
26.2672
26.6387
26.7625
26.9528
27.0848
27.1881
27.3865
28.5407
29.4872
30.4435
***
100.86
103,:l96
108.273
1:11.637
116.82
124.56.9
128.609
135.219
138.405
143.024
144.356
147.986
151.201
158.707
160.746
165.493
175.346
179.068
181.541
182.921
183.055
183.922
191.096
193.071
194.223
199.519
205.665
213.849
216.575
220.766
223,673
225.949
241.332
255.743
276.591
297.653
F-10
-------
Q
Cij
rf
-r, 10000.
i
'IT'
i — i
ill
'.'I 8000 .
TH
I I
M u:, 6000 .
C'J
u
1=)
1—
r< 4000.
Eff
-
-
,
luent B112D (8219-Acid)
..i ^_
1
1 . 1 ,1 . 1
._.^vil,..v_
J
I
I
L.
1
-
•
.M
0.00 2.10
RT in minutes
4.20
b .3 a
8.40
10.50
:.6Q
14 .70
SfiMPLE: RHP3 8219 INJECTED fiT 11:44:10 OH flUG
Method: EPV11 Raw: EOY42 Proc: *PRC11
9, 1981
16.80
Figure F-3. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B112D.
-------
l
H
to
O
©
Ill
lfl
to
•D
C
O
ili
Mi
OJ
X
£L
a
10000
8000
6000 .
4000 .
Effluent B112D (8219-Acid)
RT in minutes
IS. 98
21.00
23.10
25.20
27.30
29.40
31 .EQ
33.69
flMPLE: fiHPS 8219 INJECTED fiT 11:44:10 ON flUG 9, 1981
Method: EfiYll Raw: EflY42 Proc : *PRC11
Figure F-3 (continued)
-------
I
M
U)
CJi
v.
Ill
r—*
C
LJ
I/I
C
o
IJ
I/I
OJ
X
Ld
10000,
3000
6000
4900 .
Effluent B112D (8219-Acid)
RT in minutes
35.70 37.80 39.90 42.00 44.10 46.20
SPMPLE: RNP3 3219 INJECTED flT 11:44:10 ON flUG 9,
48.30
50.40
1981
Method: EfiYll Raw: ERY42
Figure F-3 (continued)
Proc : *PRC11
-------
TABLE F-.4.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B112D, FID/GC
PROCESSED FILE:
^AW FILE:
SAMPLE NAME:
*PRCII
BAY93
Effluent B112D (8219-Base/Neutral)
BNP3 8219
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
AREA
5381.73
75340.
5.61918E+07
2445.75
104589.
8763.5
3138.25
2278.5
3936.62
1331.45
2236.11
1469.64
2792.5
2017.53
3511.72
2252
19272,4
23380,6
1966.62
1361.31
4965.4
3403.95
1933.95
1274.96
8916.69
1516.41
1029.15
2440,61
1442.38
20602.7
4731.3
3352.42
2909.7
6173.02
TIME
2.14839
2.21809
2.25417
3.41979
3*44178
5.41163
8.19333
8.85042
9.82232
9.95764
10.7167
10.8847
11.1437
11.4438
11.5271
12.2517
12.5149
12.5904
12.7996
13.3156
13,3751
13,4569
13.5835
13.79
14.2155
14.425
14,5337
14.8253
14.9698
15.1039
15.2133
15.3257
15,4578
15.5281
INDEX
*#*
***
***
***
***
***
X<#*
:***
#**
***
***
#**
* ^ *p
•T -T *
***
***
***
***
/p ^ ^
#**
***
***
***
***
***
^ ^ ^
***
#**
^ ^ ^
***
F-14
-------
TABLE F-4 (continued)
36
37
38
3?
40
4i
42
43
44
45
46
47
48
49
50
51
53
54
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
,95
,56
.73
3830.73
1532,76
1087.89
1688.59
9477.54
14247.
14889.3
2144.18
27683.&
5394.94
3311.
6793
4617
2004
12755.7
5066.73
1490.81
2829.24
14094,2
26405.2
2158.65
2306.52
1260.12
42960.6
5004.48
5327.37
9665,2
12998.1
6524.16
1083.98
5023.69
4522.45
1704.91
3672,53
12272.6
72043,4
8334,42
1137.87
5324,34
30878
3566.98
2378.37
6906,16
9696.02
285853, 7
15.735
15.8976
15.9937
16.0551
16.1539
16,3016
16.5516
16.7471
:l 4.9:l 7:1
17.0466
17.3712
17,5442
17.63:1.7
17,7736
17.9223
18.0729
18,226
18,3852
18.4493
18.5323
18.606
19.343
19,4851
19.6916
19.7484
19.8894
20.2201
20.4973
20.5587
20,6464
20,8502
20;9035
20.97:19
21.1316
21.4004
21,6949
21,8421
21,943
22,1229
22.19*34
22.2901
22,3846
22.6671
22.9125
23.2005
***
***
***
***
***
***
#**
***
**#
#**
***
***
***
***
***
***
#**
#**
'P ^ M •
***
**#
***
***
101.806
106.809
111.004
111.932
,258
,342
,148
,183
',599
127.692
129,12
131,349
132.874
135.596
136.739
138,126
139.555
143.829
147,542
113
116
117
118.
120
F-15
-------
TABLE F-4 (continued)
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
41-811.1
2754.98
4833.36
2441.53
3473.95
1941.15
1472.63
3212.31
18073.9
8175.05
3127.27
1551.73
1804.75
1060,91
4685.16
6886.56
3717.42
41775.8
5308.83
5930,47
2840,63
1321.28
9731.64
1713.41
3657.03
2313.55
4120.29
2418.81
5230.41
1131.29
2667,95
1736,02
11219.5
22756.7
1255.12
5583.59
1819
11446
7166
23.3125
23.5109
23,6064
23.7167
23.8756
23.9635
24.0078
24.0082
24.5722
24.7338
24 . 8227
25.0967
25,3699
25.8797
25.9409
26.1795
26.2526
26.3658
26.4921
26.6461
26 . 7323
26.8396
27.0996
27.1765
27.556
27.9421
28.0323
20.1535
28.2991
28,38
28,8738
30,1385
30.2046
30.8637
31.3444
31.9951
33.4781
34.9294
41.2586
153*593
156,595
158.04
159.708
162.112
163.442
164.112
165.328
172.651
175*096
176.44
180,585
184,719
192,431
193.357
196.966
198.072
199.785
202.458
205,836
207,726
210,079
215.78
217.467
225,789
234,256
236,234
230.892
242,006
243.86
254.688
282,424
283.873
298.327
309.841
325.672
361. 755
397.066
497.01
F-16
-------
I
M
^J
10000
v.
ill
Ml
TJ
\fi
X
a.
8000
6000
4900 .
Effluent B112D (8219-Base/Neutral)
0.00 2.10
RT in minutes
6.30
i .40
10 .50
12.60
14 .70
16.30
SOMPLE: ENP3 3219 INJECTED flT 21:16:50 ON• ftUG 12, 1931
Method: BOY 11 Raw: BRY93 Proc : *PRC11
Figure F-4. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B112D.
-------
©
I
H
00
4'
a>
V-
Ul
1.0
TO
111
I/I
I
Ul
1=1
13338,
8383,
6888
4388 . -
Effluent B112D (8219-Base/Neutral)
RT in minutes
18.93
£1 .33
£3.18
25.23
27.30
29.40
31 .56
33.69
SflMPLE: ENP3 8219 INJECTED flT 21:16:59 ON RUG 12, 1981
Method: BOY 11 Raw: BRY93 Proc : *PRC11
Figure F-4 (continued)
-------
LJ
I/I
"O
C
o
IJ
111
I/I
I
Lfi
OJ
X
u
M
—I
I-
H-4
_l
CL
a
8000,
6000
4000.
Effluent B112D (8219-Base/Neutral)
RT in minute;
35.70
57.89
42.00
44.1Q
46.20
48.30
50.40
SfiMPLE: ENP3 8219 INJECTED fiT 21:16:50 OH fiUG 12, 1981
Method: BfiYll Raw: BOY93 Proc : *PRC11
Figure F-4 (continued)
-------
TABLE F-5.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B119D, FID/GC
PROCESSED FILE:
&AW FILE:
SAMPLE NAME:
DUCK
BAY27
Effluent B119D (8205-Acid)
A.NP3 8205
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
AREA
21606.1
6.29105E+07
11835.1
13995.3
129799,
14990.8
3857,44
1137,44
167781.
1160.81
1207.5
5367,37
11062.7
6082.5
17450.5
5727,78
15176.4
7941.81
1 903 . 75
1847,5
1898,5
3004
1532.44
2101.19
TIME
2.09668
2.19375
3.21388
3.49747
3.55638
4.04308
7.6475
8,46667
11.0221
12.8413
14.4792
15.2469
16.3004
17.3403
19.1779
19.519
19.6167
21.9134
24.3984
24.9028
26.07Q9
27.0757
27.755
34.9915
INDEX
***
*'**
***
#**
***
X**
***
***
^ ^ T-
***
***
***
#**
***
***
101.203
102.689
137.647
175.471
183.147
201.517
223.473
238.436
.449
F-20
-------
10090,
UJ
if
OJ
UJ
^1
(--
8000
4000
Effluent B119D (8205-Acid)
0.00 6.4 0
RT in minutes
12.30
19.29
25 .60
'3 £ . R 0
38.40
SONPLE: flNPS 3295 INJECTED RT 20:07:33 ON PUG 3, 19S1
M e t hod : E fi V11 R aw : EH V 27 P ro c : * P R C1 1
Figure F-5. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B119D.
-------
TABLE F-6. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B119D, FID/GC
PROCESSED FILEJ DUCK Effluent B119D (8205-Base/Neutral)
RAW-FILE: BAY?I
SAMPLE NAME:
BNP3 8205
RELATIVE FSETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
rt
3
4
6
7
8
9
JO
11
12
13
34
15
16
17
18
19
20
21
22
23
24
AREA
4193.58
98240.3
5.32565E+07
31484.2
106838.
9106.34
1088.56
14768
2304.5
24456.1
3224.31
31594.2
2792,5
1118,55
10031.9
3320,64
3362.31
1049,71
2004.5
1423.05
3822.24
33419.8
1137.25
16775.6
3076.06
TIME
2.10802
2.16831
2.21042
3.21525
3.5565
4.04542
8.66458
12.236
14.1437
16,3588
18.3618
19.3698
19.8247
27.3365
27.8537
28.0799
28.7641
28.963
29.3995
29.7562
29.8714
30.4896
32.1701
34,5176
40.5507
INDEX
**#
***
##*
***
**#
**#
***
*#*
***
***
***
*#*
105.552
228.713
240.081
245.052
260.089
264,462
274.056
281.896
234.427
298.013
339.263
397.224
497.22
F-22
-------
I
N)
G>
C"
GI
•f
IT
111
l?l
'*.
Ill
Ld
,,
o
u
I*
lM
u
o
10900.
'3090
6000
4000
Effluent B119D (8205-Base/Neutral)
0.00 6.40
RT in minutes
*• --••- J* .. — .<.
i.. *n^J, .*"••-*•
JuU
12.80
19.20
25.60
32.00
38.40
44 .80
SRMPLE: BHP3 8206 INJECTED RT 3:07:02 ON PUG 11, 1981
Method: BfiYU Raw: ERY71 Proc : *PRC11
Figure F-6. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B119D.
-------
TABLE F-7. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C150D, FID/GC
PROCESSED FILE:
RAW FILE?
SAMPLE NAME:
DUCK
BAY46
Effluent C150D (8237-Acid)
ANP3 8237
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
AREA
14298.5
122608.
5.89483E-K>7
1141.1
6635.63
94355.6
1297
1036,19
1498
12283.5
5854.53
1082.37
18066.7
1179.81
51097*7
25502.4
1164.75
4678.48
7151.25
21906
TIME
2*08684
2.16512
2.18958
2.85129
3*47014
3.53092
6.11071
7.63875
8*84:167
10.9096
11.2781
12.7118
13.1645
13.6986
IS* 6725
17,1002
17.2932
17.8427
. 18.578
19.1411
INDEX
##*
***
***
***
^ ^ *
***
***
***
#*#
***
***
***
***
'r * *
***
***
***
F-24
-------
TABLE F-7 (continued)
21
2> 2
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
70929,7
1195,89
1462,22
1321.5
2110.75
21424.7
1199.25
1719.12
1437.62
1659.37
6726.75
20506.6
1035
17180.2
9519,75
1735,12
2803.25
14241 .5
23.
23.
23.
24 .
25*
26.
26,
'26.
26.
27.
28.
28,
30 ,
30.
32.
32.
33.
5001
1736
25
8212
7234
3532
18
3004
67A7
8042
8071
0755
5448
3 1 23
5696
6833
8904
3161
146.570
156.828
159.143
166.6(36
180.418
190.003
203.7-45
206.397
214.641
217.493
239.585
245.496
255.832
294.764
300.495
352.675
357.788
368 .3
F-25
-------
I
N)
O\
X
T5
v.
•T)
•—»
c
u
i.'l
Tl
c
UJ
X
u
1=1
s
cr
8008
6000 .
^ 4000.
Effluent C150D (8237-Acid)
RT
0.00
in minutes
2.10
4.20
6.30
S.40
10.50
12.60
14.70
16.89
SflMPLE: ONP3 8237 INJECTED fiT 15:55:44 ON RUG 9, 1981
Method: BflYll Raw: EOY46 Proc:.*PRCll
Figure F-7. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C150D.
-------
*J
I
Effluent C150D (8237-Acid)
L_A^_JL
~J>-.~.*.
RT in minutes
18.90
21.00
23.10
25.20
27.30
29.40
31.50
SfiMPLE: OHP3 8237 INJECTED RT 15:55:44 ON RUG 9, 1981
Method: BRY11 Raw: ERY46 Proc : *PRC11
Figure F-7 (continued)
-------
I
NJ
00
Gt
•
®
G'
v.
(D
T3
C
o
1.1
']'
Ul
I
X
1=1
10000,
8330,
6000
4000. -
—I • 1 1 1—
Effluent C150D (8237-Acid)
RT in minutes
35.70
44.10
46.20
37.80 39.90 42.00
SflMPLE: ONP3 3237 INJECTED RT 15:55:44 OH RUG 9, 1981
Method: EflYll Raw: EOY46 Proc: *PRC11
43.30
50.40
Figure F-7 (continued)
-------
TABLE F-8. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C150D, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAYIOO
SAMPLE NAME:
Effluent C150D (8237-Base/Neutral)
BNP3 8237
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
TEAK*
3
A
CT'(
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
AREA
18396.7
194497.
5.66849E+07
1216.08
2675.31
11494.7
147085.
1594.25
1222.81
1081.87
1245.53
103Q.59
1022,99
1246.27
18550,2
1052.81
5660,69
2050.08
8569.45
2240.21
2400,94
4415.37
TIME
2.18178
2,26247
2.29167
2.98653
3.48125
3,64482
3,70998
S.4875
9,25238
10,7042
12,005
12.0847
12.317
12.3964
12.5264
13.8542
14,3975
14.845
15.0675
15.1392
15.5766
15,6782
INDEX
***
***
*##
#**
***
***
***
***
***
***
***
#**
***
^ ^ ^
***
###
***
**#
#**
F-29
-------
TABLE F-8 (continued)
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
1925.55
18398.5
3322,8
1084.36
24520.2
8406
2641.25
2762.67
3169.25
2074.78
4122.45
1023.27
1277.75
3545.25
2330.44
2982.75
15836.1
1340
8329,62
1594.75
6385.5
5028.25
7603.06
15.9589
16,0715
18.3225
19,1427
19.6822
21.1906
22.951
23.2988
24.4177
27.1625
27.3335
27.4297
27,8514
28,3753
29.9881
30,6449
30.8602
34.2042
34.9284
35.4529
41.2599
45.4969
46.6392
W*(f
***
***
***
#**
121.491
146.612
153.386
170.313
217. 16
220.911
223.019
232.267
243.758
279.125
293.529
298.249
379.42
397.041
406.295
497.03
542.734
554.796
F-30
-------
I
U)
CD
® 10000
X
-n
i
t—i
i'f, 8008,
u:-
C'J
LJ
(=1
4000.
0 .00
RT in minutes
Effluent C150D (8237-Base/Neutral)
'AWl
l
6. 4Q
12.80
19.20
25.60
32.90
38.40
44.80
SRMFLE: ENP3 3237 INJECTED fiT 3:42:25 OH OUG 13, 1981
Method: EflYll Raw: BOY 100 Proc : *PRC11
Figure F-8. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C150D.
-------
TABLE F-9.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C155D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY44
Effluent C155D (8230-Acid)
ANP3 8230
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFZ
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
AREA
15557.5
6.05553E+07
1929.27
1689.47
11364.6
160645.
7055.25
2103.36
4625.25
1280
24439.9
2243.69
1058.31
2161.56
2133.75
3204.02
1334.12
1349. :12
27548.7
2231.38
1017
4950
6156.5
5013.2
5609.92
2867,5
1921.12
3440.44
2202.12
1079.5
1804
4114.61
1419.12
1455.75
TIME
2.08692
13*1875
2.85339
2.99375
3*47422
3.53508
7.63634
8.45833
8.97869
9.67167
10.924
11.1508
12.0121
12.2427
12.7222
12.872
14.084
14.1754
15.5771
15.6653
17.201
17.8073
18.5516
19.0451
21.7479
22.2889
23.3115
r 25 . 2795
26.8083
27.4757
27 . 7958
28.0254
30.2854
30*5349
INDEX
#**
***
***
#**
***
^ 4^^
***
X**
***
***
***
***
##*
***
***
***
***
***
***
#**
***
***
***
***
135.128
143,362
158.926
188*832
217,585
232.284
239.336
244.396
294 . 172
299.667
F-32
-------
OJ
U)
"3
•r, 10000,
i
iri
U
TT
CM
X
U
6090
4000
Effluent C155D (8230-Acid)
y
i,i 11
I.J,y.J T+JlMAJ \~*J
\fC\*r*-iJm.
0.00 6.40
RT in minutes
12.80
5.60
32.00
38.40
19.20
SflMPLE: fiNPS 8230 INJECTED RT 13:49:50 ON flUG 9, 1981
Method: ERV11 Raw: EOY44 Proc : *PRC11
44.80
Figure F-9. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C155D.
-------
TABLE F-10.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C155D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC11
BAY96
Effluent C155D (8230-Base/Neutral)
BNP3 9230
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
1
2
3
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
ARE:A
8148.84
92661.
5.61383E+07
1485.75 .
153735.
2601.75
1667,75
1543.19
4413,75
5008.72
1730.62
1652
3087
5555,56
1702,08
1774.81
1271.64
26019.8
1127.93 ,
1498.3
1202.97
1180.6
1496
2815.94
6246.78
2298.73
5708.26
1756.02
2083.05
1136.12
2407,43
1765,06
TIME
2.17845
2.26205
2.28542
3,47222
3,70013
5 , 47833
8.2366)
8.91562
9.24314
10.7333
10.9031
11.2
11,3301
11,54
12,0007
12,2595
12.3854
12.5245
12.95
13.0388
13.1104
13,191
13.3375
13.9995
14.3979
14.8385
15.0663
15.1368
15.2042
15.2929
15.381
15.525
INDEX
^ ^ T*
***
***
***
***
* ^ ^
***
***
***
*#*
***
***
*#*
##*
***
*##
***
***
***
***
/l\ ^ ^
***
***
***
***
***
***
F-34
-------
TABLE F-10 (continued)
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
3847.73
3501.27
1394,8
5430.03
19232.4
2216.01
2230
1782.12
1234.77
1696.24
3007.61
3220.84
2072.69
3670.64
1226.67
1438.48
1096.87
41254.
1890.02
1032.87
1636.4
1079.94
1715.84
1089.56
1028.64
1572.5
21904.1
1839.31
12924.2
2553
2837
12961.7
3366.87
15.5714
15.6773
15.795EJ
15,9594
16.0701
16,1233
16.4062
17,1613
17.2904
17.3808
17,5556
18.0723
IE). 1782
18.3217
18.5187
19.1448
19.4BOB
19.6898
19.8854
20.9604
21.5875
22,1083
23.2969
27.1517
27,3302
29,9833
30.8603
33.8479
34,9345
35,3802
39,2667
41.2727
46.6375
##*
#**
***
***
***
***
^ ^\ ^\
***
***
*#*
***
***
***
101
113
127
135
153
216
220
279
298
370
397
405
465
497
554
.746
.009
.496
. 376
.357
.923
.838
.021
,253
.752
.19
.159
.085
.229
.778
F-35
-------
"3
I
TJ
ill
*
•—«
Ld
01
U
U
Hi
M'l
I
Iff
U
10000,
8000
6000
^ 4000.
Effluent C155D (8230-Base/Neutral)
0 . 00
RT in minutes
2.10
4.20
6.30
S.40
10.58
12.66
14.70
16.86
SflMPLE: BHP3 8230 INJECTED fiT 0:29:24 OH PUG 13, 1981
Method: BflYll Raw: BflY96 Proc : *PRC11
Figure F-10. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C155D.
-------
'.I'l
TJ
C
o
u
I
-=.
3
C'j
X
LJ
LL
H
CT
8000
6000 .
4090
Effluent C155D (8230-Base/Neutral)
•V* L'—» f^. |
1
RT in minutes
18.90
21 .00
23.10
5.20
29.40
31 .50
33.60
SflMPLE: BNP3 8230 INJECTED RT 0:29:24 OH RUG 13, 1981
Method: BflYll Raw: ERY96 Proc : *PRC11
Figure F-10 (continued)
-------
GP
G'
"O
a>
c
Ul
TJ
C
o
'J
u>
OJ
u
o
131
16060
3600
6000
4000. -
Effluent C155D (8230-Base/Neutral)
JL
RT in minutes
35.70
37.80
39.90
42.00
44.18
46.20
48.30
50.49
SflMPLE: EHP3 8230 INJECTED fiT 0:29:24 ON OUG 13, 1981
Method: BflYll Raw: BRY96 Proc : *PRC11
Figure F-10 (continued)
-------
TABLE F-ll. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C156D, FID/GC
PROCESSED FILE: DUCK
ir
-------
TABLE F-ll (continued)
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
9570.31
49998.5
2664.31
6323.94
21746.8
32229,7
1315.69
1049
1453.11
1671.89
1618
71533.5
1218.69
1294
12860.6
1901.25
2831.5
6087.75
5027
2145.56
1863.69
14.4008
17.2289
:17,38
-------
4'
iri
Ml
TJ
O
'J
*
U'l
I
X
LJ
19000,
S0Q0
6600 .
4000.
Effluent C156D (8238-Acid)
JU
0.00 . 2.10
RT in minutes
4.20
:.40
10.50
12.60
6.30
SRMPLE: RMP3 8238 IHJECTED RT 18:01:52 OH RUG 9, 1981
Method: ERY11 Raw: ERV4S Proc : *PRC11
14.70
16.80
Figure F-ll. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C156D.
-------
"3
I
iU
NJ
©
•Z
u
c
o
IJ
*
III
U)
OJ
u
PI
a.
^
a
10800. -
8000 . -
6000. -
Effluent C156D (8238-Acid)
4000. -
RT in minutes
IS. 90
21 .00
23.16
25.26
27.30
£9.40
31 .50
33.60
SflMPLE.: flNP3 8238 INJECTED flT 18:01:52 ON OUG 9, 1981
Method: BflYll Raw: EflV48 Proc : *PRC11
Figure F-ll (continued)
-------
101300
o*
iTt
Tl
fj
'I'
l.'l
I
10
fj
LJ
<=t
~l
I-
»—4
_1
u_
a
4000.
Effluent C156D (8238-Acid)
RT in minutes
35.70
.37.80
42.00
44.10
46.20
50.40
SfiHPLE: OHP3 8233 INJECTED fiT 13:01:52 ON flUG 9. 1931
Method: BflYll Raw: EOV43 Proc : *PRC11
Figure F-ll (continued)
-------
TABLE F-12. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C156D, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAYIOI
SAMPLE NAME:
Effluent C156D (8238-Base/Neutral)
BNP3 8238
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
I'-'EAK*
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
AREA
2125143
105811.
5.79440E+07
2230*75
1643.26
8960.51
112584.
1649.5
5366,69
5004,19
3132.25
2174.83
1457.91
1382.7
1385.35
28402.9
1750.83
1788
5438.92
1580.94
TIME
2,17635
2.26167
2.28542
3.47674
3.50521
3.63943
3,70246
8,2475
9,24702
10,704
11,3307
11.5422
11.6608
12.0042
12.3917
12.5324
13.3306
14.0021
14,4014
14.8443
INDEX
#*#
***
###
***
***
***
^ ^ ^
***
***
***
***
***
***
F-44
-------
TABLE F-12 (continued)
21
24
25
26
.27
28
29
30
31
32
33
34
35
36
37
38
39
5749.57
1138.41
3886.95
2287.66
3830.14
16868.1
1111.87
1810,57
3405.84
1015.11
18212.2
2882.06
1070.75
1629
1605.19
1031.25
11266.7
5630.31
4208.12
15.0663
15.1365
15.5741
15.6774
15,9628
16.0708
17.5583
18.1333
18.3255
19.1443
19.6825
21.1889
22.1125
23,2983
27.1558
27.95
30.8528
34.9295
41.2615
***
***
***
***
***
***
*#*
***
***
***
121
135
153
217
232
298
397
497
.466
,439
.379
.014
.237
.088
.067
.054
F-45
-------
G'
GI
^ 10000.
X
'!>
0)
^. 8000 ,
w
c
o
u
a>
MI
OJ
u
P.
6000
4090.
Effluent C156D (8238-Base/Neutral)
0.00 2.10
RT in minutes
4.20
6.3©
8.40
10.50
12.60
14.70
16.88
SfiMPLE: BHP3 S23S INJECTED flT 4:46:47 ON OUG 13, 1981
Method: BOY 11 Raw: BOY101 Proc: *PRC11
Figure F-12. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C156D.
-------
I
-J
Q
05
0
-n
a>
c
o
i
M
I
OJ
X
O
-I
10009.
S000.
6009
4000 .
Effluent C156D (8238-Base/Neutral)
RT in minutes
IS. 90
21.00
23.10
25.20
7.30
31.50
33.60
SflMPLE: BNP3 8238 INJECTED RT 4:46:47 ON OUG 13, 1931
Method: FRY 11 Raw: ERV101 Proc: *FRC11
Figure F-12 (continued)
-------
I
00
OS
T3-
0>
cn
16090
t! 8060
Ml
•D
O
u
ili
tfl
ID
OJ
6000
4000. '
Effluent C156D (8238-Base/Neutral)
JL^~_^
-J_
RT in minutes
35.70
A
_l_
_1_
J L.
1
1
37.80
39.90
42.00
44.10
46.20
48.30
56.49
SflMPLE: BNP3 8238 INJECTED fiT 4:46:47 OH OUG 13, 1981
Method: EfiYll Raw: BOY101 Proc: *PRC11
Figure F-12 (continued)
-------
TABLE F-13.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C157D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
FAY36
Effluent C157D (8211-Acid)
ANP3 8211
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
o
3
A
C'i
6
7
AREA
12667.7
6.03088E+07
9403.31
96749.9
2600.07
19032.1
5789.25
TIME
2.0892
2..-U3958
3.47756
3.53771
7.&M72
10. 90S:!.
16.9444
INDEX
***
***
***
##*
***
***
***
F-49
-------
c-
Q
X
-0 10000.
CTl
c
LU
^J 8000 .
3
0
ill
'.'1
1
i "5
^ U-. 6000 .
OJ
X
LJ
<=l
K
H-l
^ 4000.
E
_
-
• i • i • i • i • i • i • i J
Effluent C157D (8211-Acid)
•
1 1. .
.'
•
.
1 » 1 1 • 1 1 1 1 L i 1 i 1 i
0.00 6.40 12.80 19.20 25.60 32.60 38.40
RT in minutes SftMPLE : flNPS 8211 INJECTED PIT 5:28:10 OH RUG 9, 1981
Method: BflYll Raw: BOY36 Proc: *PRC11
44.80
Figure F-13. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C157D.
-------
TABLE F-14.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C157D, FID/GC
PROCESSED FILE! *PRC11 Effluent C157D (8211-Rao /»
RAW FILE: BAY?? Base/Neut
ral)
SAMPLE NAME:
^S 8211
RELATIVE: RETENTION VALUES
OUTPUT FILE: OPFI
l-'EAKt
i
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
AREA
2734.25
56211.2
5.50257E+07
•4473 . 45
83169.
4016*92
20178.1
3964.94
36718*7
2561.87
1400.75
1060.87
3403.66
41746.4
18028.2
3611.5
TIME:
2.12468
2.19117
2.225
3.58436
11?. 11 8:1
12* 2-499
16.959E)
19*3738
24.7568
27*8131=5
20*0389
29,6554
30.4978
34.5:152
-40.551-4
INDEX
***
***
***
***
***
**#
***
***
***
180.622
239.2815
244.249
279.854
298.41
397.412
497.236
F-51
-------
o
o
c*
X 10000.
•o
•— i
C
u
„. 8000 .
TJ
C
O
w
111
I/I
1 >
Ul 3
10 u., 6000 .
CM
X
U
1=1
^1
t-1
£ 4000.
• 1 • 1 • 1 • 1 • 1 f 1 • 1
Effluent C157D (8211-Base/Neutral)
_
-
I.*
•. . i . i l i
'
I . IL .JL.JL
•
'
._ 1
0.00 6.40
RT in minutes
12.80
19.20
.00
38.40
44.80
SfiMPLE: BNP3 8211 INJECTED flT 19:55:58 OH OUG 11, 1981
Method: BflYll Raw: BOY79 Proc: *PRC11
Figure F-14. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C157D.
-------
TABLE F-15.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C161D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY 50
Effluent C161D (8239-Acid)
ANP3 8239
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
o
3
4
5
6
7
8
9
10
11
12
13
14
15
16 -
17
18
19
20
21
t>2
23
24
25
26
27
28
29
30
31
32
33
AREA
8556.5
6.15164E+07
1425,87 -
1474.5
6869.76
109222.
1183.25
1848.25
1744.03
6236.25
5269.33
1967.48
1529.7
1074.25
26456*2
14455,9
1734.69
3523.45
33368.5
1869.11
1489.5
1829*07
1905.87
7520.08
30146.8
1907.66
15724.4
5726.62
34538.7
2248.06
6568.5
6035.61
12252.3
TIME
2.08574
2.18542
2.8511(3
2.99181
3.47118
3.53029
4.19792
7.63932
8.01597
8.30292
B.9912
9.18229
9.21667
9.68056
10*93:12
11.4825
12.2521
12.9091
13.1894
13.4252
13.5442
14*0937
14.7854
15.4552
15*6885
15.7122
15.7679
16.5058
17.1596
17,3688
17.8968
18.6254
19.1652
INDEX
***
***
*r ft* ^'
#**
***
***
***
***
#*#
***
***
***
***
***
***
***
#**
^ ^ ^
*#*
#**
***
***
***
***
***
^ ^ ff*
***
***
Ht**
***
***
F-53
-------
TABLE F-15 (continued)
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
151
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
1426.33
1378
2823.11
1038.2
25602.3
1237.56
1516.66
1274
1297.56
1666
1433.8
18405.5
1041.89
2652.3
2705.66
2228.83
2102.17
1913.81
8165.97
46515.1
1669.94
1718,12
1582.19
34803.8
14370.5
27195.3
1478.87
1630.63
7343.96
113803.
2361.84
1404,31
2870,25
1412
19.3779
20,887
21,765:1
22.2174
22.4135
23.1601
23.3323
23.8259
24.1472
24.7247
25,05:1
25.3555
26.0792
26.1964
26.3206
26.6983
26.3236
27.4875
27.Q2B-.1
28,1336
28.5573
29.3208
29.6391
30.3652
30,4085
30.6299
31,4443
32.6306
32.7232
32.9855
33.5537
33,6875
40,0323
40.4365
***
122.
135.39
142.273
145.259
156.622
159.243
166.756
171.647
1(30,436
135,404
190.038
201.524
204.105
206.841
215.161
217.921
232.544
240.046
246.775
256.108
272,926
279.935
295.929
296,883
30:1.973
322.081
351,372
353,703
360,136
374.165
377.469
489.494
496,153
F-54
-------
'5
G>
GJ
X
Tj 10000.
V-
U
* 3000 .
c
o
u
i
";.
3
U-.i 6000.
•:-'i
x
u
(=1
~ 1
1—
»— 1
gJ 4000.
El
'
Ef
-
-
-
fluent C161D (8239-Acid)
JL,
%
V. .-4 » j k.«v' I /I r
1 . 1 i 1
-
1 , ,,,
/I uA
1
-
-
1
v .1. ,/l ,/
0.00 2.10
RT in minutes
4 .20
S.40
10.50
12.60
14.70
16.80
Method: ERY11 Raw: BOY50 Proc: *PRC11
Figure F-15. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C161D.
-------
I
Ul
a\
c
u
W
TJ
C
O
u
w
I
"D
10
X
u
a
10000.
8000
6000
4006. -
Effluent C161D (8239-Acid)
RT in minutes
18.90
21 .00
23.10
25.20
27.38
29.40
31 .56
33.66
SfiHPLE: ONP3 8239 INJECTED flT 28:07:58 ON flUG 9, 1981
Method: BfiYll Raw: B8Y50 Proc : *PRC11
Figure F-15 (continued)
-------
I
cn
•o
C"
v.
iTl
C
LJ
•n
o
u
u
(=1
—I
10000
6000
4000.
Effluent C161D (8239-Acid)
RT in minutes
35.70
37.80
39.99
42.09
44.10
48.30
50 .40
SRMPLE: RNP3 8239 INJECTED RT 20:07:58 ON RUG 9, 1981
Method: BRV11 Raw: BRY50 Proc: *PRC11
Figure F-15 (continued)
-------
TABLE F-16.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C161D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC11
BAY102
Effluent C161D (8239-Base/Neutral)
BNP3 8239
E;: RETENTION WALUES
OUTPUT FILE: OPFI
PEAK*
i
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
AREA
80077.5
6.16668E+07
1078,12
1253»5
4249.52
223854.
4442,87
7327,2
12122,9
2202.89
1181.11
6209,25
1283,75
2730.37
1962.75
4123,27
6170,73
4051,25
2045.62
4531.57
2341.32
4218.06
42525,9
4265,03
2571.76
1812.12
2665.62
2075.75 ;
1415,25
1959.6
1262,04
8649.5
10957.5
TIME
2.17288
2.275
2,97765
3.13255
3.47125
3.70033
5.47778
8.06699
8.25602
8.88385
9.0-4931
9.2525
9.96458
10.9387
11.2049
11.5454
1 1 . 6635
12.0056
12.0857
12.2579
12.3205
12.4116
12.5356
12.9802
13.0438
13.1153
13.1944
13.3437
13.4842
13*7517
13.8589
14.0059
14.411
INDE
###
***
***
*##
***
***
***
***
***
***
***
***
***
***
***
***
***
***
* V ^
***
***
***
***
***
***
***
***
***
***
***
***
***
***
F-58
-------
TABLE F-16 (continued)
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
2638.7
3977.22
12027.
3556.95
2963.78
1139.64
2963
2820.62
7006.41
3907.91
2400.75
5231.59
44611.
1753.58
1344.37
1058.69
2261.19
4277.55
1985.53
4819
1301.42
1190.08
1252.06
48544.
5510.52
1187.35
1794.23
1571.75
13731
4421.87
1827.42
2611.69
1093.8
2864.28
8631,81
2835.7
4103.98
1746.2
1485.69
7798
2500,11
3414,8
1175.02
14.5458
14.8528
15.078
15.1452
15.2194
15.299
15.3944
15.5063
15.582
15.6884
15.8033
15.9714
16.0926
16.2203
16.4141
17.3899
17.5625
18,0771
18,1824
18,3297
19,1542
19.2382
19.4857
19.6975
19..892S
19.9595
20.824
20.9658
21,1983
21.5967
21.6867
22.1171
22.2052
22.6174
22.8584
23.2083
23.3019
23.4767
24,3469
24.4267
24.7313
24.828
25.0563
***
***
***
***
***
*#*
***
***
***
***
***
#**
***
*#*
***
***
***
***
T> ^ ^
***
***
***
101.853
102.867
115.945
118.09
121.608
127.635
128,997
135.508
136.841
143.078
146.723
152.017
153.432
156.077
169.242
170.449
175.057
176.521
179.974
F-59
-------
TABLE F-16 (continued)
77
78
79
80
81
82
33
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
1398.14
8550.05
1825.16
1923.12
2102.3
1263.05
1552.52
1037.12
10772.9
2929.41
2140.25
3329.34
1256.88
2248.22
65560.8
1228.65
1146
2132.12
7512.37
1517.95
5274.5
20279.5
9029.27
23787.2
23770.1
1019.69
2120.47
2607.25
14007.9
2864
7338.87
20918.3
20406.4
25.1119
25.6532
25.9233
26.1821
26.5288
26.655
27.0358
27.1716
27.3445
27.4394
27.6903
27.8647
27.935
28.1848
28.519
28.5816
28.9167
29.2304
30
30.1507
30.2637
30.7033
30.7473
30.8814
30.9676
33.6191
33.8574
34.2:184
34.9473
35.4715
41.2743
45.5383
46,6937
180.815
189.004
193.091
197.007
203.262
206,031
214.382
217.36
221.152
223.233
228.734
232.56
234,101
239,579
246,908
248.281
255,629
262.509
279.386
282.691
285.17
294.81
295.773
298.715
300.672
365.185
370.984
379.766
397.501
406.586
497.255
543.171
555.372
F-60
-------
G'
G'
O
-1-
V-
m
ui
C
o
OJ
•
X
u
10908
8Q00
D 6000.
4000
Effluent C161D (8239-Base/Neutral)
UJ '•!
0.00 2.10
RT in minutes
4.20
6 .30
8.40
10.50
12.60
(s
14.70
SOMPLE: ENF3 8239 INJECTED fiT 5:51:18 ON OUG 13, 1981
Method: BflYll Raw: EflY102 Proc : *PRC11
'UA,
16.30
Figure F-16. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C161D.
-------
Q
OS
X
TJ
c
LI
Ml
TP
C
o
IJ
>1>
w
I
10000. -
8000. -
Effluent C161D (8239-Base/Neutral)
4000. -
RT in minutes
. 90
21 .00
23.10
25.20
27.30
29.40
31 .50
SfiMPLE: ENP3 8239 INJECTED fiT 5:51:18 ON RUG 13, 1981
Method: EflYll Raw: BOY 102 Proc : *PRC11
33.60
Figure F-16 (continued)
-------
I
U)
o
Q
'Si
*
Q*
i-rt
LJ
I/I
|J
ili
LJ
1=1
\~
10000
3900
6000
4000
Effluent C161D (8239-Base/Neutral)
'-_
RT in minutes
;.?0
S7.80
42.01
44.10
46 .20
43.30
50.40
SflMPLE: BNP3 8239 INJECTED flT 5:51:13 ON flUG 13, 1981
Method: BfiYll Raw: BOY102 Proc: *PRC11
Figure F-16 (continued)
-------
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C164D, FID/GC
Effluent C164D (8212-Acid)
SORRY, PRINTER BUSY OR DOWN
RELATIVE RETENTION VALUES
TABLE F-17
ft/fit;
OUTPUT FILE: OPF2
PEAK**
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
AREA
13528.2
6. 10730E+07
10620.2
127099.
8855.5
3605
1263.25
1995.5
1128.19
21614.4
7655.41
3000
5370.87
2107.5
3373.5
1311.19
1076.37
23338.2
3351.19
1073.31
1358.5 .
1260
TIME
2.08995
2.18958
3.47976
3.53893
7.63493
8.44948
8.97639
9.66204
10.2245
10.9124
12.0053
12.8494
13.0045
13.1437
13.8693
16.8229
18.4568
22.9656
27.7807
27.9993
34.4469
35.0035
INDEX
•ft**
***
***
***
***
***
***
***
***
***
**#
*«*
***
***
***
***
***
153.663
239.001
243.817
396.219
406.647
F-64
-------
G5
o
o
Tt
X
-n 10000.
'H
cn
V.
.— «
C
u
W 8000.
C
o
>J
l.ll
1 >
(n 3
01 u> 6000 .
OJ
X
u
H
gj 4000.
Effluent C164D (8212-Acid)
-
-
u
LL_
ik
[JL^-
.
'
•
>t 1 n
i . i . i . i . i . i
CT
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.90
38.40
44.80
SRMPLE: ONP3 8212 INJECTED OT 6:30:34 ON fiUG 9, 1981
Method: ERY11 Raw: ERY37 Proc : *PRC11
Figure F-17. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C164D.
-------
TABLE F-18.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C164D, FID/GC
PROCESSED FILE:
KAW FILE:
SAMPLE NAME:
*PRC32
CBSD4
Effluent C164D (8212-Base/Neutral)
BNP3 8212
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
AREA
3470.25
5.84154E+07
1140.87
21754.6
83792.9
20428.3
35195.7
1282.56
3456.69
1456.49
4247.66
26269.8
18795.1
16288.7
TIME
2.0739
2.16042
3.31563
3.4791
3.53517
12.2582
19.403
19.9354
27.8437
28.0609
30.3867
.30,5238
34.5604
40.6458
INDEX
***
^ ^ ^
#**
***
***
***
***
107.236
239.95
244,734
295,963
298,983
398.286
497.978
F-66
-------
CD
'3?
G*
G>
10000.
.••^
i
IT*
ifl
U
8000 .
TJ
C
o
u
*
>
11 6000 .
Lfl
PJ
X
u
Pi
Q.
11 0.
RT in n
' | ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 '
Effluent C164D (8212-Base/Neutral)
-
-
~
"/
^ !
.
-
•
"
1.
_ .1 L ll ^ _
i i i . i . i . i . i
00 6.40 12.30 19.20 25.60 32.00 38.40 44.89
Figure F-18. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C164D.
-------
TABLE F-19. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C169D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY32
Effluent C169D (8208 Acid)
ANP3 8208
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
F'EAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
AREA
12241.6
5.95355E+07
1435.3
1984.37
16585.
220305,
1089.23
1507.25
3583
18332.1
13521.1
1314
3300.25
1624.37
1204.87
2590.62
1109
2724.5
1524,56
6777.5
1574.5
6445.34
4748.81
1323.56
1639.42
1564.62
1672.55
1112.27
1901.75
2519,69
11841,2
1552.06
2883.05
2099.75
TIME
2.0957
2.195(33
2.86181
3.20882
3,48482
3.54747
4,04375
7.46597
10.6531
10.9098
12.1615
13.2422
15.7744
16.2326
17.0175
17,9558
19,3167
19.7015
21.6889
23.3461
24.3049
24.8747
25.0832
27.2141
27,6474
27.9932
28.3797
30.4142
32.95
33.6435
34,0765
34.449
34.5701
35,0071
INDEX
***
##*
*#*
#>»*
***
**#
*##
##*
***
***
#>**
***
***
fl\ ^ /f
***
***
103,98
134,23
159.453
174.047
182.72
185.894
226.1521
236.066
243.682
252.196
297.008
359.259
376.383
387.075
396.271
399.263
406.706
F-68
-------
0
c
u
TJ
•z
o
•J
*
III
I
>
10
OJ
X
u
19600.
8000
6006
4090.
Effluent C169D (8208-Acid)
JL
«^JL
\
.' ii^ _J
0.00 2.10
RT in minutes
4.20
6.30
8.40
10.50
12.60
14.70
SOMPLE: OHP3 8208
INJECTED OT 1:18:47 ON OUG 9, 1981
Method: BfiYll Raw: ERY32 Proc: *PRC11
Figure F-19. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C169D.
-------
I
-J
o
CD
•4-
CT>
c
u
O
Proc: *PRC11
Figure F-19 (continued)
-------
GI
<3
G"
rn
j.
,11
O
u
C'J
x
LJ
a
a
10009
8009.
6000 . -
Effluent C169D (8208-Acid)
4000 .
RT in minutes
35.7(
37.30
39.98
42.00
44.10
46.20
48.30
59.40
SRMPLE: flNPS S20S INJECTED flT
Method: BflYll Raw: EOY32 Proc : *PRC11
1 :13:47 ON flUG 9, 1981
Figure F-19 (continued)
-------
TABLE F-2-0. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C169D, FID/GC
PROCESSED FILE*. *PRC11 Effluent C169D (8208 Base/Neutral)
RAW FILE: BAY76
SAMPLE NAME:
BNP3 8208
RELATIVE: RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
AREA
3899*16
59784.2
5.75354E+07
1023*34
5639*84
140028.
1348,75
1258.12
4731.56
1086*61
204315 ,6
4751.19
2240.37
8092
2177.37
14515.87
7790.87
41622.7
1528.25
4434.55
TIME
2*10-4 03
2.15297
2.20833
2.86505
3*21163
3.55104
6.53819
9.68167
9.84732
11*2424
12*2306
13.202
13.9442
14.3112
17.5777
18.7802
18.8654
19.3602
19.5812
21.9178
INDEX
#**
***
#**
fr ^ ^
***
**#
##*
***
#**
***
***
***
*#*
***
**>»
***
101, (3-46
137.41
F-72
-------
TABLE F-20 (continued)
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
10590(3.
2345,48
2160
56073.2
2662.62
2712.97
1832.09
4685.66
3579.02
4448,71
3 34 2 4. '8
1490.32
14512.7
2419,715
15748.7
18156.4
2700.75
2 3. -4412
25.4208
25.15517
27.2902
27.6598
27*801
27.9232
29.0264
30,3177
30.3527
30.4721
30.5586
30.6589
33.6(33:1
34.4917
35.0455
40.5031
160.596
190.728
192,72:1
227,757
235.999
239,01
241.701
243.973
294.443
295.213
297.843
299.75
302.195
376.867
396.831
406.975
496.445
F-73
-------
-J
itfc
©
o
c
LJ
TJ
C
o
u
Hi
X
LJ
1=1
10000.
800Q
6000 .
4000.
Effluent C169D (8208 Base/Neutral)
I
\
V_
-~*-A
0.00 2.10
RT in minutes
4.20
6.30
8.40
10.50
12.60
14.70
16.80
SRMPLE: BHP3 8208 INJECTED OT 16:43:47 OH RUG 11, 1931
Method: EflYll Raw: BRY76 Proc : *PRG11
Figure F-20. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C169D.
-------
I
-o
in
G"
10000.
LO
C'J
o.
E
CT .
8090,
6009
4000 .
Effluent C169D (8208 Base/Neutral)
•A-^AJlAAJiJ1
_v-J
.-.-.r.--*.-.' r.-
A^v—v.-'W.'--^-.-^..-y.Jv-J'^—'^•'V
-•v.'V
'llUv-1
•*iA_.V>^-n-»*«
,\,^_.\
J_
RT in minutes
13.90
21 .08
23.10
25.20
'.30
29.40
31 .50
33.60
SfiMPLE: ENP3 8208 INJECTED fiT 16:43:47 ON RUG 11, 1981
Method: BOY 11 Raw: EOY76 Proc: *PRC11
Figure F-20 (continued)
-------
V.
•n
-a
c
o
u
*
I/I
I
X
Ul
LL
a
10009,
8000
If, 6000
4000. -
Effluent C169D (8208 Base/Neutral)
JL.
RT in minutes
35.70
37.80
39.90
42.00
44.10
46.2©
43.30
50.40
SflMPLE: BNP3 8208 INJECTED FIT 16:43:47 ON BUG 11, 1981
Method: EftYll Raw: BOY76 Proc: *PRC11
Figure F-20 (continued)
-------
TABLE F-21. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B133S, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAYS
SAMPLE NAME:
Effluent B133S (8183-Acid)
ANP3 8183
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
F-EAK*
A
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
AREA
18792.(3
5.34888E+07
62425,8
51546,7
2433
15722.5
22409,9
3342.12
11996.7
1945,42
5649.37
3034.33
2363.93
1169.06
3814.62
1931.19
1612,06
2013.49
2016.24
3084.09
1411.98
4692.28
1420.41
1066.95
1557.12
4768.27
1349,28
1408.37
1132,64
2044.42
TIME
2.14595
2.23125
3.56967
4,07079
10,46
10,9474
11,565
11.7622
12.1389
12.7399
12.9039
13.7111
13.7512
14,0596
14.5292
15.35
15,5167
16.8197
16.927:1
16,9949
17,0745
17.4428
17,9177
18.0385
18.2091
18,25(32
18,4117
18.538
19.3354
19.5932
INDEX
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
**#
*#*
***
***
***
^ ^ ^
***
***
***
102.179
F-77
-------
TABLE F-21 (continued)
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
10501,8
5973.81
15177,5
1467.11
4514.5
2624.67
4902.16
2714.34
1285.1
1209.2
3986.83
6878.52
3192,81
1192.03
4788,72
2557,34
2387.66
1084.66
2801,91
2072.75
2791.48
2834.55
1851,48
3579,16
1512,5
3015.47
1596,14
5485,56
1889.04
1335.55
1078.12
19.3906
20.7307
20.9467
21.0434
21.3588
21.6208
21.7678
21.8597
22.4607
22.5346
22.6984
22.8534
22.9293
23.0368
23.1275
23.2458
24.005
24.7771
25.1109
25.3523
25.938
26.2679
26.3569
26.7171
27,1771
27,4596
27.8587
27.9643
28.0732
30,7971
32.0437
106.707
119.494
122.781
124.252
129.053
133.042
135.278
136,678
145.826
146.95
149.443
151.802
152.957
154.594
155.975
157.775
169.33
181.082
186.163
189,838
198.751
205,461
207.422
215.354
225.486
231,71
240.5
242.826
245.224
305.839
336.545
F-78
-------
Gl
c-
GI
tj
•D
*
O'
v.
C
u
Iflflflfl
W 8000
c
o
u
1=1
6900 .
Effluent B133S (8183-Acid)
^ft-W^J ^-J
0.00 2.10
RT in minutes
4.20
6.30
8.40
10.50
12.60
14.70
16.80
SflMPLE: RNP3 8183 INJECTED RT 0:05:03 ON RUG 7, 1981
Method: BOY 11 Raw: BfiYS Proc : *PRC11
Figure F-21. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B133S.
-------
TABLE F-22. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B133S, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY56
Effluent B133S (8183-Base/Neutral)
BNP3 8183
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
.13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
AREA
5414
6.03591E4-07
2305*98
76651*2
86440,6
9436
2116
3493,81
1632
3214,7
52297,5
56192,4
4586,25
4449.11
30465,1
1931*3
1798,41
2469.12
26796.5
13120.7
3181.19
15906,7
1233.67
3318.02
2840
1212.94
3119.69
6456
1283.97
TIME
2.08533
2.18333
3.19365
3.52735
4.03368
5.33559
5.85104
7.84258
Q . 125
8.34427
8.5069
10.0584
10*4281
10*9414
11*558
11.7305
11.838
11.9974
12.2417
12*8974
13.8351
14*6374
14.9635
15.5116
15.9829
16.3071
16.49
16,9332
17.4146
INDEX
#**
***
***
***
***
***
*##
***
***
***
***
##*
#:**
***
>»**
***
***
***
>»**
***
^ ^ -T
F-82
-------
TABLE F-22 (continued)
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
1118*81
1621.55
1047
520215 .
1175
1155.23
6871.89
8602.19
4040,88
1380.34
1722.84
2345.7
1096.93
1390.44
3412,55
3311.5
2077.72
12639.6
7481.11
11417.2
3417.44
8121
49426,4
1963,12
3070.12
3266.75
4675.48
12788
17.7799
18.0484
18.1156
3.8.416
19.39:16
20,4493
20*9281
21.0189
22.9082
23.0995
23.2187
23.4062
23.5554
23.6472
24,775
25.2984
26.209:1
27.5724
27.8662
27.95
28,0942
29.2161
30.3868
30.5174
31.0531
33.5809
34.5073
35.06
40.5440
***
***
***
***
***
115.362
122*415
124.032
152.789
155.7
157.515
160.369
162.639
164.037
18:1.202
189.17
204,396
234.414
240*885
242,731
245,906
270,618
296.406
299.283
312.423
374.837
397.711
407.578
497*937
F-83
-------
I
00
•u
C'
Ci
Tf
X
T> 10000.
ili
O*
ill
i— i
c
u
^ 8000.
c
o
Ul 6000 .
O.J
X
Ul
^ 4000.
E:
Efi
'
•
,
fluent B133S (8183-Base/Neutral)
JL
^
v_
, L . . l/,l
L^^-
I
JjL
1
4.
,*.
.^.-r-j^JL — >^J
^JjA-!
0 .00
RT in minutes
2.10
4.20
6.30
8.40
10.50
12.60
14.70
16.80
SflMPLE: BNP3 8183 INJECTED fiT 2:26:01 OH flUG 19, 1981
Method: EflYll Raw: BflY56 Proc : *PRC11
Figure F-22. FID/GC chromatogram of relative retention indices for components in
the' extractable organics base/neutral fraction from effluent B133S.
-------
co
01
"35
0
G"
OS
C
u
Vi
I
C'J
X
10000 .
^ 8000
C
O
L'
6000 .
4000 .
Effluent B133S (8183-Base/Neutral)
RT in minutes
18.90
21 .00
23.10
25.20
27.30
29.40
31 .50
SRMPLE: BNP3 8183 INJECTED PT 2:26:01 ON PUG 10, 1981
Method: BfiYll Raw: BRY56 Proc: *PRC11
jL
33.60
Figure F-22 (continued)
-------
I
00
en
05
©
rj-
X
•0 10000,
CP
«)
*-4
c
c
o
•J
111
I/I
I
Ul
OJ
Ui
Z)
8000.
6000 .
4000. r
Effluent B133S (8183-Base/Neutral)
jd
_i_
RT in minutes
35.70
39.90
42.00
44.10
46.29
37.80
SflMPLE: ENP3 8183 INJECTED flT 2:26:01 ON fiUG 10, 1981
Method: BflYll Raw: BRY56 Proc:.*PRCll
48.30
50.46
Figure F-22 (continued)
-------
TABLE F-23. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B141S, FID/GC
PROCESSED FILE! *PRC11 Effluent B141S (8185-Acid)
RAW FILE: BAYIO
SAMPLE NAME:
•ANP3 B185
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
l-'EAKt
1
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
AREA
14653.5
27214.3
5.67861E4-07
1845.31
81739.6
1448.25
33169,6
17385.6
1093.25
5628.87
1617.75
2365.31
1219.87
14172.3
15505,
6117,34
1055.87
1888.23
1289.51
25554
2538.87
3758.37
18933
1216.56
3889.72
1722.5
20353.8
1771.12
1461.86
3259.06
TIME
2 . 096 1
2.13779
2.2125
2.97895
3,56563
4.11042
4.593215
4.66118
7.68264
9.01814
9.51667
:10 .3297
10.4446
10.7406
10.9802
11.3617
12.2672
:12,(3403
12.9198
13.1965
13.425
13.7235
14.1175
14.2924
15.5933
15.8379
17,0739
17.2977
17,8583
18.5792
INDEX
***
***
***
***
***
***
***
*#*
***
***
#*#
***
***
**#
^ ^ ^
***
***
***
***
**#
^ ^ ^
***
***
***
***
F-87
-------
TABLE F-23 (continued)
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
5922.84
24503.8
11293.2
1085.12
5311.72
38836.3
14146.5
1560.42
5170.75
1715.5
1190.77
2486.47
21587.3
2349.79
2255.69
1770.44
1401.44
2172.5
1552,73
15207.8
41165.7
1513.25
1572.12
1801.37
24249.9
21727.1
21724.
2948.81
5952.87
1476,69
18.9778
19.19
20,8924
21.7745
22.2264
22.4702
22.4917
23.3385
24,1039
24.7347
25.0698
25,1802
25,3772
26,2055.
26,3267
26,7042
26.8245
27.0076
27.4942
27 . 8581
28.1371
28.5646
29,3323
29.6504
30.3658
30.3754
30.6238
32.7155
32.922
34,1056
***
***
121,955
135.38
142,259
145.969
146,298
159.186
170.835
180.437
185.537
187.218
190.217
204,086
206.756
215.07
217.72
221.752
232.471
240.486
246.633
256.048
272.958
279.964
295*723
295.933
301,573
353.091
358.177
387.329
F-88
-------
CD
•a
O
GI
•#
X.
^ 10000.
i
a>
i-
iTl
r—t
LJ
W 8000.
"O
£
O
1.'
*
w
I >
«> m A000 .
OJ
X
u
p
^ 4000.
z:
11 0.
RT in n
• r
Effluent
-
-
,
B141S (8185-Acid)
,
J
i
_
. 1- i 1 i 1
-
•
'''Lw^.JU\A-
-
•'uL
,<
A
A_^y vv^_^/-.
i . i
00 2.10 4.20 6.30 8.40 10.50 12.60 14.70 16.80
linutes onMDi r. nkico 01 oc- T ki irnrrn I-.T o.oo.oo ni.i nnr •? IQOI
Method: EflYll Raw: EfiYlQ Proc : *PRC11
Figure F-23. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B141S.
-------
I
vo
o
16000.
1.
U
TJ
C
O
u
a<
irt
I
u:-
OJ
X
u
0.
2
8800
6008
4000 .
Effluent B141S (8185-Acid)
in minutes
18.90
21 .00
23.10
25.26
27.39 29.40
2:69:23 OH OUG 7, 1981
-- •-. r^ .-v
31.50
33.68
SflMPLE: ONP3 81S5 INJECTED flT z-.u?.^^ .... ...
Method: EfiYll Raw: BOY 10 Proc : *PRC11
Figure F-23 (continued)
-------
I
VD
IS'
CD
u
u>
OJ
u
1=1
o.
E:
CT
10000.
8000 ,
6000
4000.
. Effluent B141S (8185-Acid)
RT in minutes
35.70
37.30
39.90
42.06
44.1Q
46.20
4S.30
50.40
SfiMPLE: ONP3 8135 INJECTED flT 2:09:23 ON RUG 7, 19S1
Method: BOY11 Raw: BOY10 Proc: *PRC11
Figure F-23 (continued)
-------
TABLE F-24.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B141S, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY60
Effluent B141S (8185-Base/Neutral)
BNP3 8185
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
1
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
AREA
1356.5
5277»67
5.97145E+07
3247.12
7188.54
103436.
1188.04
68925.6
40178.2
8423.19
2814.62
19887.8
1444.62
4472,16
3516.8
1418.47
12665.4
2191,75
1431.66
9750.05
204786,
8628.52
10590.1
2761.22
2947.05
9042,5
4468.71
4036.24 '•
17807,1
45631.4
1145.19
3475.33 .
2345.08
1927.54
2420.42
TIME
1,93125
2,08782
2.18542
2,94939
3,47217
3.53049
3.83333
4,57561
4.63546
5.25061
6.11012
6.30585
7.31042
7,97812
8,645
8.78194
8.99417
9.68594
10,25
10,4375
10.8625
11.276
11.3922
11.5236
11.726
11,8044
11.9823
12.0427
12.1369
12.2508
12.512
12.6955
12.758
12.8312
12.9126
INDEX
***
#*#
***
***
***
***
***
***
*P r|\ f^
***
***
*•##
***
***
*##
***.
***
***
*#*
***
***
#**
#**
***
***
***
#**
***
F-92
-------
TABLE F-24 (continued)
36
37
38
39
40
41
42
43
44
45
46
47
46
49
50
51
52
53
54
55
56
57
58
59
60
6J
62
63
64
65
66
67
68
69
70
71
72
73
1546.75
1142.95
9700.19
1160.5
26156.1
98805.4
2261.09
1200.03
1455.64
4635.62
2202.48
7090.34
1534.85
2311.45
2872.61
3153.93
5130.91
5821.72
1510.22
4117.64
1475.81
32958.5
23528.7
3362.48
2703.87
1151.41
2664.06
1819.56
4708.44
3964.46
10640.2
1144.11
19462,
3596.97
1049.49
6886.82
2623.15
4203.52
13.0596
13.1966
13.4037
13.5507
13.7314
14.1666
14.2561
14.4104
14.4484
14,578
14-. 6569
14.8034
14.8463
14.9238
15.1034
15.2393
15.2995
15.4059
15.5167
IS.6742
15.6887
15,8052
15.8472
15.9433
16.1271
16,6729
16.871
17.0059
17.0989
17,2336
17.2956
17,3964
17.7892
17.8727
17.9867
18,0566
18.2069
18.5383
**#
##*
***
^ ^ *
***
***
***
***
***
***
***
***
***
#**
**#
Jf. *K/f\
***
**#
***
*##
**#
***
#*#
^ v ^
**#
*#*
***
**#
***
***
***
***
#**
##*
F-93
-------
TABLE F-24 (continued)
74
75
76
77
78
•79
80
81
82
83
84
85
86
87
88
8V
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
i07
108
309
110
111
112
113
114
115
116
10162.8
1633,55
2745,59
3423.69
62385.5
1047.39
14768.7
1851.11
3178.2
2831,55
1099,87
2586.8
1782,02
6253.66
59910.2
125366.
10711.
11916.9
2079,25
2808.52
3232.8
14547. 1
3741.45
2838.84
3999.69
13945.7
9825.12
4731,61
2910.01
1869.61
3002.3
2574,68
13517.9
62397.7
1252.22
13690.8
8619.95
15147.4
14014.5
4232.81
8185.16
2830.51
2034.3
18.6133
18.8597
18,9391
19.1867
19.3863
19,4525
19.5985
19.9021
20.1781
20.2407
20,4448
20.5073
20.6
20.6725
20,8588
20,9568
21.301
21,4988
21.8192
22.059
22.4047
22.4899
22,5684
22.6659
22.8417
22.9044
22.9968
23.1901
23.6552
23.8244
23.8754
23.9762
24.0465
24,1449
24.3635
24.4282
24.5113
24,5891
24.6654
24.7278
24.7393
24.8109
24.9512
***
V n^ y
#**
###
###
100.191
102.412
107,033
111.235
112.108
115.294
116.245
117.656
118.76
121*594
123,086
128,325
131.337
136.213
139.863
145.125
146.422
147.6:1 6
149,1
151,776
152.731
154,137
157,079
164,158
166,734
167,51
169.043
170.114
171 .612
174,94
175.924
177,188
178.374
179,535
130.485
130.658
181.749
183.835
F-94
-------
TABLE F-24 (continued)
117
118
119
120
121
1 '•'2
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149 -
150
151
J52
153
1964.96
3012.13
3454,76
6494,19
13227.2
37183.5
3775,23
10412.4
4528.41
3487.12
8299.62'
9079.66
1238,34
17819.8
7530.48
50921.9
3475.66
4966.66
16068.7
6566.52
9003.17
102334.
240597.
28836.4
34796.
64430.
10248.3
4031.8
4081.46
10305.4
4838.43
4638.25
3666.28
10862.3
1778.46
38352.3
3531.2
25.026
25.0777
25.1974
25.2814
25.4135
25.5084
25.6174
25.8697
26,0062
26.2402
26,3325
26,4532
26,6793
26,8345
26,9534
27.0481
27.1485
27.2467
27,5454
27.6137
27*8227
28.0471
28.3722
28,3845
28.4057
28.4267
28.5261
28.5673
28.6295
28.9119
28.9998
29,1117
29.2196
29.4516
29.5988
29.7032
29.8318
185.81
187.632
188.91
190.921
192.365
194.025
197.864
199.943
205.07
207.104
209.763
214.742
218.162
220.781
222.865
225,076
227.24
233.819
235,324
239.928
244,87
252,032
252.303
252,769
253.232
255.42
256.328
257.698
263,92
265.854
268.32
270.695
275.806
279.048
281.349
284.181
F-95
-------
TABLE F-24 (continued)
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
5632.25
4705.26
12823.6
8033.2
1882.19
359892.
14505.5
32988.6
199429.
163801.
10758.3
6743.39
3131.03
1164.02
1277.72
2186.33
3203.3
1971.14
1202.05
4131.95
1103.45
1517.7
6101.99
1757,52
3704.22
3046.06
1721.22
1651,7
3411.44
2197.61
2490.17
7989.57
1625.25
1999
1142.81
1262.75
4580.12
1796.12
24693.5
21462
29.9
29.9953
30.0864
30.1924
30,2155
30.5529
30.5908
30.6042
30,6326
30.8678
31.045
31.1617
31.3405
31.4133
31.4696
31.8388
31.9821
32,182
32.3039
32.6108
32.6941
32.9382
33,0418
33,1065
33,2901
33.5349
33.7992
34.195
34.3579
34.5288
34.9979
35.0726
35.1833
35,4911
36.2109
36.7385
38.8219
41.213
44.5932
45.6536
285.683
287,783
'289.789
292.123
292,633
300.073
301.006
301.338
302,039
307.E546
312,222
315.103
319.517
321.316
322.707
331 .822
335.359
340.297
343.307
350,885
352.941
358.968
361.526
363.123
367.658
373.701
380.228
390.
394.022
398.241
406.555
407. 785
409,61
414.68)1
426,539
435.231
469.553
506.157
544.481
556.503
F-96
-------
I
vo
0 32009.
x
TJ
c
u
c
o
IJ
'!•
I/I
I
C'J
X
24000.
16000
8009
Effluent B141S (8185-Base/Neutral)
0.00
RT in minutes
2.10 4.20 6.30 8.40 10.50 12.60 14.70
SfiMPLE: BNP3 8185 INJECTED flT 6:38:39 ON flUG 10, 1981
Method: BfiYll Raw: BOY60 Proc : *PRC11
16.80
Figure F-24. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B141S.
-------
I
vo
00
o
u
111
Effluent B141S (8185-Base/Neutral)
2 32080,
TJ
Oi
"• 24090
c
u
Ul
r>
16006,
U 8000.
i=i
RT in minutes
13.90
21 .00
23.10
25.20
27.30
29.40
31 .50
33.60
SflMPLE: EHP3 8185 INJECTED flT 6:38:39 ON fiUG 10, 1981
Method: BOY 11 Raw: BRY60 Proc : *PRC11
Figure F-24 (continued)
-------
i
10
vo
C5
"Si
S>
2 32900,
T?
a-
O>
c
u
c
o
1J
a>
w
i
Lf>
X
U
>4009,
16000,
8000,
Effluent B141S (8185-Base/Neutral)
RT in minutes
35.70
37.80
39.90
42.1
44.10
46.20
48.30
50.40
SfiMPLE: BNP3 8185 INJECTED OT 6:38:39 ON RUG 10, 1981
Method: EflYll Raw: BOY60 Proc: *PRC11
Figure F-24 (continued)
-------
TABLE F-25. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B142S, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAY?
SAMPLE NAME:
Effluent B142S (8184-Acid)
ANP3 8184
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
F'EAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
AREA
51106*
5.47952E+07
1023
88331.6
1970.87
2346.5
1817.75
2728
1097
3678
4862.91
13467.7
1331.23
21151.
4110.73
9119.02
1254.5
2823.03
17977
10143.2
TIME
2.129
2,22708
3,37708
3.5662
,87083
,06319
5.08125
5.57232
6.01146
,08687
.56968
9.01322
11.6692
12.0548
,9125
.0409
,725
,2773
, 5321
3,
4,
8.
8.
12,
13,
13,
14,
14,
INDEX
***
***
***
*#*
*r ^ ^
***
***
***
T* * *
*#*
***
***
***
15,3833
***
###
***
***
F-100
-------
TABLE F-25 (continued)
21
11
23
24
25
26
27
28
29
30
3i
32
33
34
35
36
37
38
39
40
2609.11
7958.25
6647.7
28261.7
1029.52
1200.26
5433.44
5101.64
2376.04
3410.5
1432,28
1123,71
1977.8
1774.41
8284.5
3456.5
1244
3257.37
6064
2796,56
15.5734
15,7008
16.2285
16.7453
16,8375
16.9358
17.0588
17.4313
17.5771
18.4597
19,2417
19.3589
21.2194
21.5698
21.9244
23.3363
24.1354
25,1493
25.6936
27.0396
***
***
#**
***
***
***
***
*#*
#**
##*
126.
132.
137,
159,
171.
186,
195.
932
265
663
151
315
747
031
458
F-101
-------
o
to
•s
OJ
rf
c
LJ
W
X)
O
u
>
3
OJ
X
LJ
1=1
13093
8089
6900
Effluent B142S (8184-Acid)
0 . 00 2.10
RT in minutes
4.20
6.33
SfiMPLE: OHP3 8184 INJECTED flT
Method: BfiYll Raw: EOY9 Proc : *PRC11
8.40 10.50 12.60
1 :07:19 OH RUG 7, 19S1
14.70
16.83
Figure F-25. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B142S.
-------
o
Ixl
G'
G'
TJ
*
u
c
o
u
111
Ij'l
I
in
OJ
X
u
10008,
8000 ,
6009 .
4000.
Effluent B142S (8184-Acid)
A1
W-./v'J
RT in minutes
18.90
21 .00
23.10
25.20
29.40
31 .50
33.60
SfiMFLE: RNP3 8184 INJECTED RT 1:07:19 ON RUG 7, 1981
Method: BRY11 Raw: BRY9 Proc : *PRC11
Figure F-25 (continued)
-------
T)
4'
O»
i-
•fl
W
TJ
C
O
u
Qi
X
LU
16000,
8900 ,
Uj 6000 ,
4300.
Effluent B142S (8184-Acid)
RT in minutes
35.70
37.80
39.90
42.00
44.10
46.20
48.30
50.40
SflMPLE: flNPS 8184 INJECTED OT 1:07:19 OH RUG 7, 1981
Method: EflYll Raw: BOY9 Proc : *PRC11
Figure F-25 (continued)
-------
TABLE F-26. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B142S, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY59
Effluent B142S (8184-Base/Neutral)
BNP3 8184
RELATIVE RETENTION VALUEIE5
OUTPUT FILE: OPF2
PEAK*
4
5
6
7
8
9
10
11
12
13
14
If.
16
17
18
19
20
21
oo
23
24
25
26
27
28
29
30
31
32
33
34
35
A RE: A
3569
6394
6, 06277 E +07
1216.2
7340.79
93373*7
36691.6
3382.46
1131.91
5673.87
1425.75
15744.6
15096.5
8768.16
8832.16
3281.3
5408.84
2534.31
2131.71
8529.87
17064.1
1521.06
7043 * 06
27789.7
6936.57
4318.45
1729.37
46157.6
26318. .9
1896.34
1544,44
15637.5
1073.66
3755.61
1519.2
TIME
2.05396
2.08639
2*18333
2.98845
3.47188
3.52088
3.60656
4,01667
4.125
4.66847
4.80694
5*24493
7.65074
7.73737
7.95938
8.02865
8.39583
E»« 47133
8.546:1(3
8.63423
8.99688
9.1169
10.4215
10.8935
10.9845
11.0457
11.2652
12.1507
12.2464
12.7698
12.925
13.0536
13.1448
13.4886
13.5799
INDEX
***
**X
XXX
^ ^ ^
**x
x**
x**
^^^ *
***
***
T- ^ *^
***
#*#
***
^ ^ ^
***
***
***
X**
***
X**
X**
*x*
***
XXX
XXX
XXX
F-105
-------
TABLE F-26 (continued)
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
3112.34
1771.32
7514,84
4149.21
16304,4
1156,54
2585.75
1293,05
1389.44
2437.97
24646.1
23176,7
1042.12
1695.55
3501.16
7531.41
1016.18
2582.69
5235.66
15195*3
1605.27
12728,2
1868,68
2574.8
,3019.55
3936.5
1451.52
2169.19
7765.31
1512,66
1316,73
1089,7
1371,3
6962.48
7102.65
3267.63
2839,95
45670.4
4266.37 !
1654.85
1900,05
5803 . 3
1080.51
1733.25
13.7358
14,0529
14.1356
14*2379
14.3122
14,5503
14.9517
15*0383
15,1271
13.2649
15.5484
15.7305
15.8067
115. (3708
16.1516
16.2994
16,3757
16.7119
16 . 7902
16*0807
17.0448
17.1409
17,2632
17.3047
17.818
17,9075
18.1534
18.2463
18.401
18.6025
18,6878
18.746
18*8901
13,9689
19.0369
19.2189
19,3133
19.4145
19.6226
19.8655
20*6932
20 . 3726
21*201
21,3212
***
***
##*
*#*
***
*#*
***
***
***
***
***
***
***
***
3ff /H 3^
*#*
/p ft ^
***
***
#;**
#**
***
#*#
**#
#**
***
*#*
***
XX*
*r n^ ^
**#
***
#**
m*
'i*'p ^
^ ^ ^
***
***
102
106
119
121
126
128
.78
.477
.074
.805
. 804
.634
F-106
-------
TABLE F-26 (continued)
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
12416.2
1294.06
1416.83
2850.95
2553.77
2271.62
1794.56
1715.75
1355.69
1182.5
1761.25
1453.5
9077.92
2430.2
2078.25
39369.5
7711.06
3144.37
4727
4819.36
2125.97
1577.75
2358.25
1314.38
1098.62
1293.69
8928.94
21,3997
2 2.'0302
22.6729
23.0104
23,660:1
23.7687
24.1704
25.2687
25.8247
27.1417
28.253:1
28.633
28,7933
29.2196
29.2992
29.5118
30.5257
30.7064
30.8542
31.056
31.2023
32.7729
33,0292
34.5184
34.9993
35.1755
35.8715
40.5729
129.829
147,0135
149.207
154.344
164.233
165.887
' 172.
188.718
197.179
224.927
249.408
257.775
26-1.316
270.695
272.45
277.132
299,465
303.862
307,51
312.494
316*106
354,887
361.214
397.985
406,578
409.481
420.948
498,401
F-107
-------
o
00
Hi
O"
c
Ul
Ifl
T?
C
O
Ul
I
u.
s:
a
10000.
8030.
6000 .
4000.
Effluent B142S (8184-Base/Neutral)
0.00
in minutes
2.10 4.20 6.30 8.40
SfiMPLE: ENP3 8134 INJECTED flT
10.50
12.60
14.70
16.86
Method: BflYll Raw:
5:35:2-0 ON RUG 10, 1981
BRY59 Proc: *PRC11
Figure F-26. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B142S.
-------
o
vo
'3?
CJ
i.
ill
C
u
c
o
(.1
111
1.0
X
LJ
d
100(30
8000
w 6000.
4000.
Effluent B142S (8184-Base/Ncutral)
-A-*— w-*1
RT in minutes
18.90
21.00
23.10
25.20
27.30
29.40
31.50
33.60
SRMPLE: BHP3 8184 INJECTED OT 5:35:20 OH RUG 10, 1581
Method: BRY11 Raw: BPY59 Proc : *PRC11
Figure F-26 (continued)
-------
I
M
M
O
©
•s
XJ 10000.
u
C
o
u
m
Ml
I
:=•
in
CvJ
u
1=1
a.
s:
a:
8000
6000
4000. -
Effluent B142S (8184-Base/Neutral)
RT in minutes
35.70
37.80
39.90
42.09
44.10
48.30
50.40
SfiMPLE: ENP3 8184 INJECTED flT 5:35:29 OH OUG 10, 1981
Method: BflYll Raw: BflY59 Proc: *PRC11
Figure F-26 (continued)
-------
TABLE F-27.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B149S, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC11
BAY17
Effluent B149S (8193-Acid)
ANP3 8193
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
I='EAK*
1
6
7
8
9
10
11
12
13
14
15
16
AREA
81586.4
5.555
1058.75
108549.
1364.75
3440.75
9895.06
3461.44
1906.87
3239.12
3540.75
1240.92
2049.92
1014.64
1295.31
2277.14
TIME
2.12867
2.22083
3.09676
3.56115
4.05774
7.66747
10.9277
12.0283
12.87
14.2701
14,4774
15.805
16.6698
19.5875
20.6771
21.874
INDEX
#*#
ff ^ ^
***
**#
***
***
***
***
***
#**
##*
*#*
102,093
118.677
136,894
F-lll
-------
©
C'
G'
X
10000.
•o
u.
•fl
C
U
lrt 8000 .
•o
o
hrj *
1 «
H J..
10 u, 6000 .
f.j
X
Ul
p
^J 4000.
TT-
-
-
I
1 1 1 . 1 ' 1 ' 1 ' r ' '
Effluent B149S (8193-Acid)
-
-
'
-
'
t j^ JjJjV L.JL - ^ i.Jl .
i . 1 , 1 . 1 — . 1 • 1 • " • '
0.00
RT in minutes
6.40 12.80 19.20 25.60 32.00 38.40
SfiMPLE: flNP3 8193 INJECTED flT 9:26:17 ON OUG 7, 1981
Method: BOY11 Raw: BOY 17 Proc: *PRC11
44.80
Figure F-27. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B149S.
-------
TABLE F-28. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B149S, FID/GC
PROCESSED FILE: DUCK
RAW FILE: &AY68
SAMPLE NAME:
Effluent B149S (8193-Base/Neutral)
BNP3 8193
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
4
5
6
7
8
9
10
11
12
33
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
AREA
7665.68
5.41472EE4-07
19706,5
4675.87
1820.56
1947.5
2000.9
1258.59
1238.25
1423.62
13368,2
1521.85
2260
1081.21
1044. &
2159,53
1245.21
3830.95
1689,8
2519.19
2990,41
2173,45
2288.53
21812.5
1004.55
5755.97
1075.89
2047.96
1166.2
3043.03
1021.23
1912.09
1850.91
1989.16
4305,19
TIME
2.17477
2.21 25
3.53824
11.3769
11.9308
12,2167
12.7432
12.8192
12.9017
13,049
13.7122
14.0204
14.0986
14.2264
14.3091
14.3903
14.5115
14.9081
14.9946
15.083
15.2236
15.5881
15.6885
15,8316
15.9137
16.1075
16.2733
16.3833
16.4717
16.6598
16.7075
16.8611
16.8979
16.9908
17.0834
INDEX
***
***
***
***
***
**#
*#*
***
**#
***
***
***
**#
##*
***
***
***
***
**#
***
***
##*
***
***
***
***
***
***
***
***
***
F-113
-------
TABLE F-28 (continued)
36
37
38
3?
40
41
42
43
44
45
46
47
48
49
SO
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
1807.1
9252.85
25513.1
5275.05
1909.53
1965.89
2590.92
2332.44
3811.65
2413.51
1903,06
2363.09
4523,2
3405.69
6491.66
3743.66
22708.2
2134.79
1492.87
3839.19
4620.89
4650
1763.78
3542,67
1610.33
7266.17
1651.12
17777.4
1262,16
1756.66
1894.87
1970.62
8459
1431.56
3654.19
2601,31
2142,37
2218.52
1923.06
1816
1000.97
2636.94
1209.12
17.2163
17.2558
17.7768
17.8526
17.9833
18.1058
18.1933
18.2964
18.6369
18.6982
18,7539
18,8409
18.9339
19.0569
19.171
19.3469
19,5844
19,6503
19.7426
19.8806
20.1562
20.2244
20,425
20.4839
20.5785
20.6497
20.7885
21.2804
21.4172
22.0358
22.2035
22.3021
22.8817
23.6283
24.3965
24.4869
25.842
25.9822
27.2175
28.5306
29.7896
30,4625
34.4958
*«X
#**
***
***
#**
***
**#
***
***
^r *• ^
^ T^ ^
***
***
***
##*
***
101.894
102.897
104,301
106.401
110.597
111.635
114,688
115.584
117.025
118.107
120.221
127.708
129.79
139.205
141.758
143,258
152,081
163.444
175.137
176.513
197.138
199.272
226.1
254.958
282.628
297.418
396.687
F-114
-------
*J
I
en
*
C"
c
u
o
•1'
O
u
1=1
8090 .
6009 .
^ 4000
Effluent B149S (8193-Base/Neutral) OIL 1:10
I
uiv^Xta-'VWi^*
RT
0.00
in minutes
2.10
4.20
6 .30
8.40
10.50
12.60
14.70
16.80
SfiMPLE: BNP3 8194 INJECTED fiT 23:56:40 ON RUG 10, 1
Method: BOY 11 Raw: BRY68 Proc,: *PRC11
981
Figure F-28. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B149S.
-------
©
10000,
CT'
i-
lf\
T>
o
u
LJ
M
8009,
6000. h
4000. \-
Effluent B149S (8193-Base/Neutral) OIL 1:10
RT in minutes
18.90
21 .00
23.16
25.20
27.30
29.40
31 .50
33.60
SfiMPLE: BNP3 8194 INJECTED fiT 23:56:40 ON flUG 10, 1981
Method: BflYll Raw: BflY68 Proc: *PRC11
Figure F-28 (continued)
-------
IS-
o
Tfr
o»
i.
u
I.H
I.}
c
o
i-'
111
'M
X
Ul
a
a
10000
8000
6000
4000 .
Effluent B149S (8193-Base/Neutral)
-|.-|o
_i_
_i_
i
RT in minutes
35.70
39.90
42.00
44.10
46.20
37.80
SfiMPLE: BNP3 8194 INJECTED flT 23:56:40 OH RUG 19, 1981
Method: BfiYll Raw: EflY68 Proc : *PRC11
43.30
50.4.0
Figure F-28 (continued)
-------
TABLE F-29. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT A101, FID/GC
PROCESSED FILE? DUCK Effluent A101 (8217-Acid)
RAW FILE: BAYS?
SAMPLE NAME: ANPS 8217
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK* AREA TIME INDEX
1 11348.5 2*08999 #**
2 5.99558E407 2.18958 ***
3 6938.67 3.47813 ***
4 92278.1 3.53702 ***
5 20202.1 10.9111 ***
6 1240.5 35.0292 407.07
F-118
-------
05
Tf
X
T-, 10000.
i
CTi
r-4
c
LJ
W 8000.
C
o
u
a>
i
>
3
LO 6000 .
OJ
X
u
0
1—
£ 4000.
a 0.
RT in r
-
-
L
Effluent A101 (8217-Acid)
•
•
V i . ,
-
i ..l
i i i i i i i
00 6.40 12.80 19.20 25.60 32.00 38.40 44.80
minutes SOMPLE: RNP3 8217 INJECTED fiT 8:35:44 ON RUG 9, 1981
Method: BRY11 Raw: ERY39 Proc : *PRC11
Figure P-29.
FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent A101.
-------
TABLE F-30. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT A101, FID/GC
PROCESSED FILE: *PRCII vff,
RAW FILE: BAY91 ««uent.A101 (8217-Base/Neutral)
SAMPLE NAME:
BNP3 8217
RELATIVE RETENTION VALUERS
OUTPUT FILE: OPFI
PEAK*
3
4
5
6
7
8
9
10
11
12
AREA
8996.81
81812.7
5.71283E+07
1130.5
120182,
1169,87
23662.2
39381,6
2270.25
34114.4
18465.5
12986.5
TIME
2*3.4662
2.22875
2*25208
3.41979
3.64517
11,4535
12.513
19.6855
20,3092
30.8594
34.9208
41.2517
INDEX
##*
***
***
***
***
***
108.157
298.233
396.856
496.901
F-120
-------
05
G5
G>
10000.
O*
nf
c
U
8000 .
1.0
T?
C
0
U
i
11 ftflOfl .
U-
C'J
X
U
3
t— 1
Q.
E:
a 0.
RT in ii
1111111
-
-
-
u
Effluent A101 (8217-Base/Neutral)
-
1
-
-
. 1. 1
i .1.1.1.1 .1.1.
00 6.40 12.80 19.20 25.60 32.00 38.40 44.80
i * • ' *-J l £ S -r-rkMoir-. TMiri--i .-*^«-? Tiiirr-TC~Ti r» T 10.00.10 »-* ki oiir^ i--k 1001
Figure F-30. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent A101.
-------
TABLE F-31. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT BlllD, FID/GC
PROCESSED FILE: DUCK
RAW FILE:
SAMPLE NAME:
Effluent B111D (8207-Acid)
ANP3 8207
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
AREA
11198
6.00141E+07
12065.5
148360.
1305.37
19945.1
1012,5
1190,56
1203
136088.
1422.37
1103.59
3098.39
26000.
1596.3
2916.55
12453.8
1667.06
5954.67
13357.4
3774.2
TIME
2.09785
2.19792
3.48844
3.54958
7 .64305
10.9033
19.0379
29.6057
139.7979
33.3508
34.4583
34«<$9
-------
ro
G>
Tf
X
^ 10000 .
'!•
CTi
t— <
C
u
W 8000 .
c
0
U, 6000 .
OJ
X
u
— 1
1-
^ 4000.
* 1 ' 1 * 1 • 1 ' 1 ' 1 • 1 *
Effluent B111D (8207-Acid)
-
-
-
r-i
-
-
i. I i .
^^ ^
-
_
'
-
1
1. .
RT in minutes
.40
12.80
19.;
38.40
44 .80
SfiMPLE: RNP3 820? INJECTED OT 0:16:22 OH RUG
Method: BflYll Raw: BOY31 Proc : *PRC11
Figure F-31. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B111D.
-------
TABLE F-32.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B111D, FID/GC
PROCESSED FILE I
fi:AW FILE:
SAMPLE NAME:
DUCK
BAY73
Effluent BlliD (8207-Base/Neutral)
HC STD 100
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
AREA
4108.56
79892.3
5.37905E+07
102807.
13476.7
4956.75
29200 .
2050.2
1628,72
2258.37
1167.62
28059.5
13796.6
2442.75
TIME
2.10977
2.16442
2.21458
3.55685
12.2379
18.8262
19,3688
21.2045
26,1986
27,8247
28.0503
30.492
34.5254
40.5531
INDEX
***
***
***
***
^ ^ T
126
203
239
244
298
397
497
,706
.445
.402
,066
,417
,26
F-124
-------
•s
rf
X 10000.
TJ
'!'
CT>
frt
C
Ul
|ft 8000 .
C
7 r
H >
NJ j
01 b, 6000 .
C'j
X
Ld
O
— 1
t-H
^ 4000.
-
-
f
-
1 ' 1 ' 1 ' 1 • 1 ' . I ' 1 '
Effluent B111D (8207-Base/NeutraU
\
-
•
, 1 . , \ ^-'1- -li-..v "1
-
-
-
*~— — — -. t. . .
i . i . i . i . i . i . i
a
Kl In
0.00
19.20
25.60
32.00
38.40
6.40 12.80
SRMPLE: HC STD 100 INJECTED fiT 5:14:15 ON RUG 11, 1981
Method: BflYll Raw: BOY73 Proc : *PRC11
44.80
Figure F-32. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B111D.
-------
TABLE F-33. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B113D, FID/GC
Effluent B113D (8204-Acid)
SORRY, PRINTER BUSY OR DOWN
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK* AREA TIME INDEX
1 6090.91 2.10658 ###
2 46274.8 2.18632 #*#
3 5.65916E+07 2.20625 *#*
4 4383.39 3.49375 **#
5 63351.1 3.55693 *##
6 3036.5 7.64646 #*#
7 16804.4 10.8978 *##
8 1109.62 11.9911 #**
9 3683.75 32.5884 350.331
F-126
-------
i
H
N)
c
id
1.1
TJ
O
>J
UI
I
Ul
a
10000
8000
6000
4000.
Effluent B113D (8204-Acid)
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44 .80
SRMPLE: RHP3 8204 INJECTED flT 19:05:32 ON OUG 8, 1981
Method: EflYll Raw: BPY26 Proc : *PRC11
Figure F-33. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B113D.
-------
TABLE F-34. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B113D, FID/GC
PROCESSED FILE:
FILE:
SAMPLE NAME:
B113D (8204-Base/Neutral)
BNP3 820^
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
F'EAK*
1
2
3
A
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
AREA
5809*96
103445.
5.58039E+07
5281.49
104432.
20300.7
1016.75
41610.6
1649.84
1882.62
1599.34
3183.84
5393.44
1639.84
39348,9
16957,4
2138,75
20123.8
3063.37
4400.5
TIME
2,10632
2,16754
12.21042
3,49196
3.55653
12.2402
17.8177
19.3733
23,1421
26.9292
29.2792
29,3664
30.0521
30,3536
30.4998
30,6992
34.001
34.J5235
35.0608
40.5458
INDEX
***
#**
***
*##
*#*
***
***
156.044
219.762
271,41
273.328
288.397
295.025
298,238
302.944
384.47
397.37
407.074
497.14
F-128
-------
N)
G5
E
U
E
O
i
1.0
I
f'
U
1=1
—I
10900.
8009
6000. -
4060
Effluent B113D (8204-Base/Neutral)
-L-J.
JL-
^xJ
»«-^*.-^*_JL. *|J LXr^
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SRMPLE: ENP3 8205 INJECTED fiT 2:03:34 ON OUG 11, 1981
Method: BflYll Raw: EOY70 Proc : *PRC11
Figure F-34. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B113D.
-------
TABLE F-35.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B124D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY28
Effluent B124D (8206-Acid)
ANP3 J3206
RELATIVE; RETE-irrroN VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
AREA
50EJ8.42
94931*6
3.69077EI407
7246,86
122657,
3119.5
2095.25
,19754.2
4947.75
1300.75
3122.28
1046.87
1787.94
TIME
2.10588
2*1307
2.20625
3.48942
3.55279
7.64427
8.45479
10.9068
12.0005
12.3578
12.8443
14.4427
34.9944
INDEX
#**
#**
***
#<*
***
#**
***
***
***
***
***
406.498
F-130
-------
o
0
'•t
X 10090.
C.
ni
c
Ld
!„ 8000 .
T?
C
o
y
*
w
i
~>
U, 6000.
T'J
X
u
K
J 4000.
CT 9.
RT in n
i • i • i • i • i • i • i
-
-
. .
Effluent B124D (8206-Acid)
-
.
( h .
• i •
•
-
•
IjL ,. j.i.. i. . ..^-.^~ .'« <*^*» — i J__
00 6.40 12.80 19.20 25.60 32. 0Q 38. 40 44.80
ninutes SRMPLE : RNP3 8206 INJECTED PT 21:09:56 OH PUG 8, 1981
Figure F-35. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B124D.
-------
TABLE F-36.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B124D, FID/GC
PROCESSED FILE: DUCK
RAW FILE: BAY72
SAMPLE NAME:
Effluent B124D (8206-Base/Neutral)
BNP3 8206
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
4
5
6
7
8
9
JO
11
12
13
14
15
16
AREA
5341.33 ,
98569.8
5.43091E+07
6235.7
116794.
16521.
9530
33720.6
2756.12
1157.25
1028.87
30849,1
1143.25
15816
1143.36
2991
TIME
2.10816
2.16867
2.2125
3,49088
3.55766
12.2378
18.827
19.3722
20.2097
22.0715
24.8076
30,4939
31.0347
34.5205
35.0587
40.5594
INDEX
#**
***
***
***
***
***
***
***
111.411
139.749
181.395
298.108
311.228
397.297
407.04
497.362
F-132
-------
G3
•
©
X 10000,
T3
ill
TJ
C
O
OJ
•
X
u
n
8000
6000
4000.
0
RT in
"I'l'l'l'l'l'l*
-
-
.
Effluent B124D (8206-Base
-
/Neutral)
1
J 1 ' h L 4& R> t
-
J ll_. t.
1 . 1 . , . 1 . 1 . 1 . 1
.00
minutes
6.40
12.80
19.29
25.60
32.00
38.40
44.80
S9MPLE: BNP3 8207 INJECTED OT 4:10:34 ON RUG 11, 1981
Method: BRY11 Raw: ERY72 Proc: *PRC11
Figure F-36. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B124D.
-------
TABLE F-37. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT CISID, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY34
Effluent C151D (8209-Acid)
ANF:'3 8209
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
6
7
8
AREA
15123.6
6.18457E+07
12887.7
115155.
1087.62
10610
24605.3
7594.75
TIME
2.09001
2.1875
3.48403
3,54248
7.63889
10.8949
33.296
35.0057
INDEX
***
***
***
***
***
•367 . 802
406.684
F-134
-------
^s
*s*
©
*»•
X
-0 10000.
*
o>
I.
•—4
C
u
«> 8000.
c
o
u
j
u> 6000.
OJ
X
u
o
£ 4000.
* I * 1 * 1 ' 1 • ' . 1 * 1 " 1 *
Effluent C151D (8209-Acid)
~
-
-
u
V 1 .
\
~
-
i . i . i . i . i . i
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SRMPLE: RNP3 8209 INJECTED RT 3:23:14 ON RUG 9, 1981
Method: BRY11 Raw: BRY34 Proc : *PRC11
Figure F-37. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C151D.
-------
TABLE F-38. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C151D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
#PRC11
BAY77
Effluent C151D (8209-Base/Neutral)
BNP3 0209
RELATIVE RETENTION WALUES
OUTPUT FILE: OPFI
PEAK*
1
*5
3
A
5
6
7
8
9
10
11
12
AREA
5253.93
101636*
5.50926E+07
8143.18
139417.
10899.
19029.7
22878.6
28142.6
10572*4
8852*25
1853.12
TIME
2*11872
2.1853
2.22083
3.51162
3.57834
12.2467
19.3698
30.4875
33.3491
34.5162
35*065
40.5635
INDEX
***
***
***
X**
***'
***
***
298.184
368.619
397.437
407.296
497.435
F-136
-------
©
©
X 10000.
TJ
'!'
V.
fl)
C
Ld
(r| 8000 .
"b
c
o
IJ
hj '!>
1 '•''
to >
^ ^ 6000 .
OJ
u
—1
\-
" 4000.
CL
s
-
-
(j
\ ' 1 ' 1 ' ' 1 * 1 * 1 ' 1 '
Effluent C151D (8209-Base/Neutral)
•
•
•
-
\
1 . 1 . 1 . 1 . 1 . 1 . 1 .
cr
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SflMPLE: ENP3 8209 INJECTED PIT 17:47:51 ON RUG 11, 1981
Method: BOY 11 Raw: EflY77 Proc:.*PRCll
Figure F-38. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C151D.
-------
TABLE F-39. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C153D, FID/GC
PROCESSED FILE: DUCK
RAW FILE! BAY43
SAMPLE NAME:
Effluent C153D (8225-Acid)
ANP3 8225
RELATIVE F^ETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
6
7
8
9
10
AREA
21674
6.16924E4-07
1630.14
1752
15486.
146779.
3276.56
1227
21950,7
2322.75
TIME;:
2,
2.10333
2.85155
2.99258
3.47225
3.53244
7.63
3.4474
10.9121
12*0044
INDEX
***
**#
***
###
***
**#
***
***
F-138
-------
GI
©
CD
Tf
X
-o 10099.
fli
r-H
£
ui
^ 8000.
o
»TJ *'
1 j
^ ip 6000 .
CM
LJ
=•
H
^ 4000.
E
-
-
-
i , . 1 . 1 i I i 1 . , , I .
Effluent C153D (8225-Acid)
.1
-
\ 1 i
-
'
•
'
i . i . i . i . i • i . i .
a
0.00
RT in minutes
6.40
12.80
19.20
25.60
32.00
38.40
44.80
SfiMPLE: flNP3 8225 INJECTED flT 12:46:50 OH RUG 9, 1981
ftethod: EPY11 Raw: EPY43 Proc: *PRC11
Figure F-39. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C153D.
-------
TABLE F-40. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT CIS3D, FID/GC
PROCESSED FILE: *PRCII
RAW FILE:
SAMPLE NAME:
Effluent C153D (8225-Base/Neutral)
BNP3 8225
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
1
2
3
4
5
6
7
8
9
10
11
AREA
12621*4
5.75303E+07
1110.19
1138.25
10712,2
130574.
1901.5
22426
36199,5
33319,8
12190.6
4430.5
TIME::
2.16317
2.26875
3.11875
3.45104
3.61577
3.67989
7.89583
12.5226
19,6868
30.8645
34.9333
41.2578
INDEX
***
***
#**
***
***
***
298.344
397.161
496.997
F-140
-------
CD
10000.
X
13
a-
c
u
8000.
TJ
C
0
1.1
a>
i
J 6000.
C'j
X
u
1=)
Z'
1 —
1— 1
^ 4006.
a 0.
* 1 ' 1 ' ! ' 1 ' I • 1 ' 1
Effluent C153D (8225-Base/Neutral)
-
.
-
I,
1 1 ,
"
.
-
1 !
i i i i i . i i
00 6.40 12.80 19.20 25.60 32.00 38.40 44.80
RT in minutes
SPMPLE: BHP3 8225 INJECTED flT 22:21:03 ON RUG 12, 1981
Method: EflYll Raw: ERY94 Proc : *PRC11
Figure F-40.
FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C153D.
-------
TABLE F-41. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C154D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
Effluent C154D (8240-Acid)
ANP3 8240
RELATIVE: RETENTION VALUES
OUTPUT FILE: OPF2
F'EAK*
1
2
3
6
7
8
9
10
11
AREA
38384.4
91894.2
6.05743E+07
2149.2
1614.75
13521.1
15763:1,
1077.25
2413,44
21762.5
1062.62
TIME
2.08037
2.17123
2.18333
2.85152
2.98893
3.4A66A
3.53084
7.22344
7.63194
10.924
12.0154
INDEX
**#
***
***
***
***
***
#**
***
***
***
F-142
-------
Gl
'3
G1
G'
Tf
X
10000 .
TJ
*
(-H
c
u
W 8000 .
"D
O
*
M
1
>
u> 6000.
OJ
.X
Ul
p
1—*
^ 4000.
\
-
-
~l
-
I
Effluent C154D (8240-Acid)
-
'
: ,iL|
-
.
L
i • i . i . i .1 . i . i >
RT in minutes
12.!
SPMPLE: RNP3 8240
Method: BfiYll
INJECTED fiT 21:11:09 ON RUG 9, 1981
44
Raw: EflYBl Proc : *PRC11
Figure F-41. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C154D.
-------
TABLE F-42.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C154D, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAYIQ-J
SAMPLE NAME:
Effluent C154D (8240-Base/Neutral)
BNP3 8240
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
AREA
25474.2
180471.
5.78843E+07
1291.43
1119.97
2189.44
12145*7
158354.
1238.25
1551.5
25027,
1001.56
1956.31
1184
1950,62
1234
2974.37
1965.37
1784.75
38625.1
1153.5
37792.1
14570,7
6772.5
TIME:
2.17554
2.25687
2.28542
2.98216
3.13636
3.475
3.63706
3.70369
6.0475
12.2667
12.5309
15.0639
15,25
16,4135
16.8:12:1
16.9719
17.5622
18.1516
19.486
19.6958
20.9649
30,8782
34.9395
41.2719
INDEX
***
***
^ * ^
***
***
***
™ ^ ^
*#*
***
***
***
***
***
***
***
***
118.078
298.644
397.31
497.217
F-144
-------
*l
I
OJ
•*
i—I
c
c
o
a-
w
u>
OJ
LJ
o
o
a.
a
10000.
8000 .
6000 .
4000.
0.
-
-
-
-
-
I
Effluent C154D (8240-Base/
\ L 11 _^il
i i i
Neutral)
-
-
.1 1
i ii i
00 6.40 12.80 19.20 25.60 32.00 38.40 44.80
Kt
in 1 nU I &S
SfiMPLE: BHP3 8240 INJECTED RT 6:55:49 ON OUG 13, 1981
Method: EfiYll Raw: BPY103 Proc : *PRC11
Figure F-42. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C154D.
-------
TABLE F-43. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C158D, FID/GC
PROCESSED FILE: DUCK
FILE:
SAMPLE NAME:
Effluent C158D (8210-Acid)
A'NP3 8210
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
4
5
6
7 •
8
9
10
11
12
13
14
15
16
AREA
10542.7
6.01550E4-07
7264.37
88805.
5543.87
1979.37
13687*1
3124.25
1852
1228.23
1008.25
2973.5
1937,25
1098.06
3223.19
2110.31
TIME
2.09257
2.19167
3.48105
3.54101
7.63484
8.44958
10-.9024
11.9975
12.8382
14.4451
22 .24
24.4642
25.2542
27.6531
27.7785
28.0021
INDEX
##*
***
***
***
***
***
***
***
***
***
142.6:19
174.472
188.496
236.192
238.954
243,879
F-146
-------
•5
G>
c?
0
X
n 10000.
i
i_
in
f~
LJ
W 8000 .
o
1 1
a-
w
i
Lf, 6000 .
OJ
X
u
(=>
p-
KH
^ 4000.
a 0.
RT in n
-
-
-
V-
Effluent C158D (8210-Acid)
.
-
-
L L L L u J_L ^ J , - - ^ .. - jJL^^_J-JjU'- - M. ._ /d . . j ^. , ...
00 6.40 12.S0 19.20 25.60 32.00 38.40 44.30
n mutes SRMPLE: ONP3 8219 INJECTED RT 4:25:38 ON RUG 9, 1981
Proc : *PRC11
Figure F-43. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C158D.
-------
TABLE F-44. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C158D, FID/GC
PROCESSED FILE: *PRC11 Effluent C158D (8210-Base/Neutral)
RAW FILE: HAV™
SAMPLE NAME:
BNP3 8210
RELATIVE FttmEiNTlQN VALUES
OUTPUT FILE? (DPF1
PEAK*
3
A
5
6
7
8
9
10
11
12
13
14
15
AREA
2909,7
50519.5
5.56040E+07
4263,55
75526.7
16027,7
29690.5
1136.66
1030.12
1865.19
1072.25
36284.1
19725
1911.87
4365.81
TIME
2.12467
2.19218
2.225
3,5190:1.
3.58441
12.2475
19,3728
24.0246
27,8104
28.0321
30.302:1
30.4983
34.5198
35.0535
40.5458
INDEX
***
***
***
***
**#
***
***
169.-476
239.2:16
244,099
294.099
298.42
397.526
407.106
497,145
F-148
-------
. Q
*
X 10000.
i_
•tl
C
U
„, 8000 .
~n
c
o
u
trj Oi
1 «
M 4.
jj 6000.
•
X
u
^ 4000 .
•EL
•I'l'l'l'l'l'l*
-
-
L
L
Effluent C158D (8210-Base/Neutral)
-
,
•
L_
1
-
-Jl___JL_
0.00 6.40
RT in minutes
12.80
19.20
25.69
32.00
38.40
44.80
SRMPLE: ENP3 8210 INJECTED RT 18:51:56 ON RUG 11, 1981
Method: BflYll Raw: ERY78 Proc : *PRC11
Figure F-44. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C158D.
-------
TABLE F-45.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C159D, FID/GC
PROCESSED FILE: DUCK
RAW FILE: BAY52
SAMPLE NAME:
Effluent C159D (8245-Acid)
ANP3 8245
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
.1.
2
3
4
5
6
7
8
9
10
11
12
AREA
17419.2
6.24384E+07
1880.93
1808.62
9900.4
141284.
20027.7
1923.75
3557.08
14216.5
2962.22
1484.12
TIME:
2.08278
2.18333
2.85225
2.98833
3,4713
3.53073
10.9383
25.316
26.2226
27.8824
28.0849
30.3758
INDEX
***
X**
***
^ ^ ^
***
**#
***
189.
204.602
241.243
245.703
296.164
,436
F-150
-------
05
o
c?
X
XI 10000.
w
V-
(-4
C
LJ
W 8000.
C
0
u
4'
IT 6000.
C'j
X
Ul
h-
1— 1
0.
.
-
1
Effluent C159D (8245-Acid)
-
\ I) A „ L
0
.
lij UL_
i . ^i • . . ...... _jJ /It — f -kU — A 1^
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SPMPLE: RNP3 8245 INJECTED OT 22:13:57 ON OUG 9, 1981
Method: ERY11 Raw: EPY52 Proc : *PRC11
Figure F-45. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent C159D.
-------
TABLE F-46.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C159D, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
BAY104
BNP3 8245
RELATIVE RETENTION VALUES
Effluent C159D (8245-Base/Neutral)
OUTPUT FILE: OPFI
PEAK*
1
2
3
A
5
6
7
8
9
10
11
12
13
14
15
AREA
18262.2
193086.
5.74097E+07
1064.23
1002.12
2466.25
9911.56
145989.
24766.1
37704.4
1349.45
1665
32028.7
17505.8
12441,2
TIME
2.1725
2.25113
2.28125
2.97564
3.13065
3.46875
3.63165
3.69527
12.5302
19.6928
28.1392
28.363
30.8698
34.9426
41.2854
INDEX
***
***
***
***
***
***
***
***
***
***
238.578
243.437
298.461
397.388
497.428
F-152
-------
•3)
•* 10000.
X
•o
i-
rtl
»— 4
c
^ 8000.
1.0
TJ
c
o
u
a>
w
3 6000.
IP
OJ
X
u
J 4000.
1 ' 1 ' 1 ' 1 ' 1 • ! • 1 • 1
-
-
i-
__.
\
Effluent C159D (8245-Base/
i ^ k» 1 1, J j
4
Neutral)
^JL-J
.
•
'
L___
0.00 6.40
RT in minutes
12. S0
19.20
25.60
32.00
38.40
44.80
SflMPLE: BHP3 8245 INJECTED RT 8:00:25 OH PUG 13, 1981
Method: BPY11 Raw: BRY104 Proc : *PRC11
Figure F-46. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C159D.
-------
TABLE F-47. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C160D, FID/GC
PROCESSED FILE: DUCK Effluent C160D (8218-Acid)
,f
-------
0
G>
X
-p 10000.
C"
V.
c
u
to 8000.
TJ
C
o
(J
Hj
-------
CUOD
SAMPLE NAME:
BNP3 8218
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
1
6
7
8
9
10
11
12
AREA
9536.14
88563.2
5.63320E+07
1100.75
7236.95
109182.
22808.2
37869.7
33864.1
14163.9
4260.25
9308.37
TIME
2.14312
2.22718
2.24792
3.4125
3.57415
3.63658
12.5099
19.6832
30.8652
34,932:1
35.4567
41.27IS
INDEX
#**
#**
##*
#**
***
#**
***
298*361
397.132
406.354
497.211
F-156
-------
o
E>
T»'
10000.
X
•o
ili
0»
u.
U
8000 .
TJ
C
o
u
111
7) i/i
1 ^
5 3 6000.
OJ
X
u
r>
t—
£ 4000.
E:
•I'i'i'i'i'i't'
Effluent C160D (8218-Base/Neutral>
-
.
-
U
1 1 t ill
•
-
-
'
\ I
1 1 1 . 1 . 1 . 1 . 1 . 1 I
0.00 6.49
RT in minutes
12.80
19.29
25.60
32.00
38.40
44.80
SRMPLE: BNP3 8218 INJECTED RT 20:12:36 ON RUG 12, 1981
Method: BRY11 Raw: ERY92 Proc : *PRC11
Figure F-48. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent C160D.
-------
TABLE F-49. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B126S, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAY14
SAMPLE NAME:
Effluent B126S (8191-Acid)
ANP3 8:1.91
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
I:>EAK*
i
2
3
4
5
6
7
AREA
35452*
36599.2
5.93664E+07
68477.1
1221.62
13744.5
1530.55
TIME
2.08949
2.1492S
2.19583
3.538
-------
*J
I
vo
o
*
C"
C
u
Tl
O
OJ
X
u
1=1
10900
8000
6000
4000.
Effluent B126S (8191-Acid)
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SRMPLE: RHP3 8191
INJECTED OT 6:13:42 ON RUG
1981
Method: BRY11 Raw: BRY14 Proc: *PRC11
Figure F-49. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B126S.
-------
TABLE F-50. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B126S, FID/GC
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY 6 5
Effluent B126S (8191-Base/Neutral)
HC STD 20
RELATIVE RETENTION VALUE'S
OUTPUT FILE: OPF2
PEAK*
6
7
8
9
10
11
12
13
14
15
J6
A RE: A
6020.19
98198.8
6.03961E+07
6693.88
104611.
81279.6
3575.75
22146.4
4794.78
1153.59
3722.75
4053.37
40957.4
42096.
17745,7
3093.09
TIME
2.10513
2.18202
2.20625
3.4962
3.55722
7.66124
8.66154
12,24:O
13,0081
13.0889
16.8688
19,1096
19.3789
30.5053
34.5236
40*559
INDEX
***
***
***
***
^ *• ^
***
*#*
***
***
#*#
***
298.357
397.373
497.357
F-160
-------
•
^33*
X
"0 10000.
•li
cn
•— i
c
Ul
•0 8000.
c
o
IJ
>TJ *
Ivl
1
H- >
O\ -i
I . -'
lit 6000.
•> . •
-
.
. 1 A
0.00 6.40
RT in minutes
12.89
19.20
25.60
32.00
38.40
44. S0
SRMPLE: HC STD 20 INJECTED flT 20:46:38 ON BUG 19, 19S1
Method: BBY11 Raw: BBY65 Proc: *PRC11
Figure F-50. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B126S.
-------
TABLE F-51. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B143S, FID/GC
PROCESSED FILE: *PRCII
RAW FILE: BAY:UI
SAMPLE NAME:
Effluent B143S (8188-Acid)
ANP3 81£)8
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
f-'EAK*
1
2
3
6
7
8
9
AREA
6939*77
48125.4
5.61495E+07
123086.
1065*37
23288.6
1068.62
12170.3
13573.9
TIME
2.10803
2.13886
2.21875
3.56482
7.67708
10,9436
15,259
19,9653
20.0924
INDEX
***
***
***
***
***
107,843
109.777
F-162
-------
CD
©
13
n-
X
^ 10000.
i
V.
r*
C
UI
w 8000.
c
o
u, 6000.
CJ
X
u
Q
:D
_i 4000 .
CL
s:
-
-
-
i.
i'1'i'i'i'i'i*
Effluent B143S (8188-Acid)
.
.
^ I f .
'
.....
i . i . i . i . i . i . i
0.00 6.40
RT in minutes
12.30
19.20
25.60
32.00
38.40
44.80
SPMPLE: RNP3 8188 INJECTED OT 5:16:31 ON RUG 7, 1981
Method: BRY11 Raw: BRV13 Proc : *PRC11
Figure F-51. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B143S.
-------
TABLE F-52.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B143S, FID/GC
PROCESSED FILE:
FILE:
SAMPLE NAME:
DUCK
BAY64
Effluent B143S (8188-Base/Neutral)
BNP3 8191
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
A
5
6
7
8
9
10
11
12
13
14
AREA
2486.28
48803*6
5.74448E+07
4564.98
6168.97
116016.
2645.25
19794.5
42433.7
4912
34797.7
1449.06
3874.25
3980.19
TIME
2.11057
2.17412
2.21042
3.34146
3.49306
3.55855
7.9875
12.2449
19.3793
23.7397
30.4989
34.5177
35.0645
40.5615
INDEX
***
***
***
***
***
***
***
***
***
165.141
298,218
397.227
407.134
497.397
F-164
-------
Q
'31*
G'
4-
X
o*
C
r~t
C
ui
"" RflOO .
•n
C
o
i
in
i
I/, 6000 .
•:-j
X
LJ
-I 4000 .
a.
7-
Effluent B143S (8188-Base/Neutral)
•*
-
-
—
y _ ,J.
i 1 •
_J i 1 c_
! 1 1 . ! 1 1 r
-
'
1,
1 . 1 . 1 . 1 .
0.00 6.'
RT in minutes
12.80 19.20 2S.&0 32.00 38.40
SRMFLE: ENP3 8191 INJECTED RT 19:43:13 ON RUG 10, 1981
Method: BRV11 Raw: BRY64 Proc : *PRC11
44.80
Figure F-52. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B143S.
-------
TABLE F-53. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT B147S, FID/GC
PROCESSED FILE: *PRC11 Effluent B147S (8192-Acid)
RAW FILE: BAY16
SAMPLE NAME: ANPS 8192
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK* AREA TIME: INDEX
1 11855,7 2.10631 ***
2 64713,3 2.14021 ***
3 5.57071E+07 2.21667 ***
4 96469.2 3.56072 ***
5 13787.7 10.9287 ***
F-166
-------
M
01
**•
O»
V.
C
u
c
o
(J
w
OJ
X
LJ
a
10000
8000
6000
4000.
Effluent B147S (8192-Acid)
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SRMPLE: RNP3 8192 INJECTED PT 8:23:46 ON RUG 7, 1981
Method: BflYll Raw: BPY16 Proc : *PRC11
Figure F-53. FID/GC chromatogram of relative retention indices for components
in the extractable organics acid fraction from effluent B147S.
-------
TABLE F-54.
RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT B147S, FID/GC
PROCESSED FILE:
KAU FILE:
SAMPLE NAME:
DUCK
BAY*?
Effluent B147S (8192-Base/Neutral)
BNP3 8195-
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
6
7
B
9
10
11
12
13
14
15
16
17
18
AREA
7957.78
148717,
5.75058E+07
1073
8225.63
169129.
22259.4
43285.6
35799.6
1048.62
21171.
2065.94
5672.81
7428.44
2601,05
3480.5
5495.25
4293.25
TIME
2.10569
2.16197
2.21042
3.33906
3.49066
3.55834
12.2386
19.3722
30.4986
33.626
34.5255
35.1534
36.7193
38.418
38.5806
39.3996
40.5667
4:1.4927
INDEX
***
***
***
***
***
***
***
***
298.21
375.211
397,419
408.594
434,307
462.2
464.87
478,318
497.482
508.682
F-168
-------
vo
C
u
VI
r>
c
o
w
O
UJ
_J
a.
10000.
8000
6000
4000,
Effluent B147S (8192-Base/Neutral)
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.30
SOMPLE: BNP3 8193 INJECTED fiT 22:53:15 ON RUG 10, 1981
Method: BfiYll Raw: BPY67 Proc: *PRC11
Figure F-54. FID/GC chromatogram of relative retention indices for components in
the extractable organics base/neutral fraction from effluent B147S.
-------
TABLE F-55. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS ACID FRACTION
FROM EFFLUENT C169S, FID/GC
PROCESSED FILEJ *PRC11 Effluent C169S (8194-Acid)
RAW FILEJ BATIB
SAMPLE NAME: ANPS {3:i9'i
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK* AREA TIME INDEX
1 23922.5 2.10282 ***
2 84457.5 2.13243 ***
3 5.65566E+07 2.21458 ***
4 109157. 3.55873 ***
5 19266.4 10,9375 ***
F-170
-------
I
H
©
rf
C
u
1.0
TJ
o
L'
I.M
i
CL
s:
a
10000
S000. -
6000. -
4000 .
Effluent C169S (8194-Acid)
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
33.40
44.80
SfiMPLE: RNP3 8194 INJECTED fiT 10:32:36 ON flUG 7, 1981
Method: BflYll Raw: ERY18 Proc : *FRC11
Figure F-55. FID/GC chromatogram of relative retention indices for .components
in the extractable organics acid fraction from effluent C169S.
-------
TABLE F-56. RELATIVE RETENTION INDICES FOR COMPONENTS
IN THE EXTRACTABLE ORGANICS BASE/NEUTRAL
FRACTION FROM EFFLUENT C169S, FID/GC
PROCESSED FILEt DUCK Effluent C169S (8194-Base/Neutrain
i*AW FILE: BAY69 A'
SAMPLE NAME:
BNP3 8194
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
2
3
6
7
8
9
10
AREA
4296.67
90003.5
5.55731E+07
5622.03
105962.
1345.87
16260.1
27770.9
24149.3
6449
TIME
2,10799
2.16958
2.21042
3.49148
3.55656
10.9354
12.2386
19.3684
30.4888
34.5131
INDEX
*#*
***
***
***
***
***
***
***
297.996
397,113
F-172
-------
U>
CD
©
CD
X
"D
A*
fjl
V.
•—t
C
TJ
c
o
(J
0'
in
i
IP
-------
APPENDIX G
TOTAL ION CHROMATOGRAMS FOR PHASE III EFFLUENT SAMPLES
See Appendix D for the identification and quantitation of peaks,
G-l
-------
*:* BATCH PROCESSOR RECONSTRUCT **
1 UL 1 CO/100 D10 + 8833 *NP3 (A109) 8/12x81 BP1H
SO<4>-280<8> BTL*16 D13105
FRN 13105
1ST SC/PGI 1
X- .35 V- 1.00
o
ro
TI
Effluent A109 (8233-Acid)
10
Figure G-l,
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent A109.
-------
** B^TCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8233 ANP3 8/12x81 BP1H
50(4>-280<8> BTL*16 D13105
FRN 13105
1ST SCxPGi 933
• .25 V- 1
a
i
U)
TI
Effluent A109 (8233-Acid)
15
.2A ...
Figure G-l (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 1CO/100 Did + 8233 ANP3 (A109) 8x18x81 BNH
S0<4>-280(8> BTL*16 D13105
FRN 13105
1ST SC/PG11865
* .BS V- 1.00
Q
I
Effluent A109 (8233-Acid)
TI
25
Figure G-l (continued)
-------
o
I
Ln
** BATCH PROCESSOR RECONSTRUCT ** FRN 13132
1 UL 125X125 D10 + 8233-BNP3 (A109) 8X13x81 BP1H 1ST SCxPG« 1
50>4>-280<8> BTL*19 D13132 *<• .25 V" 1.00
TI
Effluent A109 (8233-Base/Neutral) -j
I J
. A. jj
(.
j
ll
Figure G-2,
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent A109.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 135x125 D1C 4- saSS-BNPS BTL*19 D13132
FRN 13132
1ST SCxPGt 933
X" .25 V- l
Q
I
TI
Effluent A109 (8233-Base/Neutral)
1
Figure G-2 (continued)
-------
1 UL 125/125
50<4>-280<8>
X* BATCH PROCESSOR RECONSTRUCT **
•»• 8233-BNP3 (A109) 8/13/81 BHH
BTL*19 D13132
FRN 13132
1ST SC/PGI186S
X- .25 V- 1.00
o
i
TI
Effluent A109 (8233-Base/Neutral)
\
Figure G-2 (continued)
-------
o
I
oo
1 UL
S0<4
TI
** BATCH PROCESSOR RECONSTRUCT ** FRh 13102
100/100 D10 •»• 8219 ANP3 (B112D) 8/12/81 BP1H 1ST SC/PG« 1
>-380<8> BTL*13 D13102 X- .25 V- 1.00
Effluent B112D (8219-Acid)
(0
\
>. i
1 .-.• . I t
7
i i i i i i i
5 10
/
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/1C0 D10 + 8219 ANP3 (B112D) 8/13x81 BP1H
S0(4>-380<8> BTL»13 D13102
FRN 13102
1ST SC/PG» 933
X' .25 V- 1.00
o
I
TI
Effluent B112D (8219-Acid)
H-
c?1
M-
IS
20
Figure G-3 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT *X
1 UL 100/100 D10 + 8219 ANP3 (B112D) 8/13/81 BP1H
50<4)-280<8> BTL*13 D13102
FRN 13102
1ST SC/PGU865
X- .25 V- 1.00
a
i
H1
O
TX
Effluent B112D (8219-Acid)
as
._3fi
Figure G-3 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125x125 D1C * 8219-BNP3 (B112D) 8X13/81 BHH
8> BTL*17 D13130
FRN 13130
1ST SC/PGt 1
' .25 V- 1.C0
o
i
TI
Effluent B112D (8219-Base/Neutral)
4
ic
Figure G-4.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent B112D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X135 Did + 8219-BNP3 (B112D) 8/13/81 BHH
> BTL*17 D13130
FRN 13130
1ST SC/PGi 933
X- .25 V- 1.00
o
i
M
to
TI
Effluent B112D (8219-Base/Neutral)
T
bttoa
i
20
Figure G-4 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 D10 •»- 8219-BNP3 (B112D) 8x13x81 BMH
50<4>-280(8> BTL#17 D13130
FRN 13130
1ST SCXPGH865
' .25 V" 1.00
a
i
M
OJ
Effluent B112D (8219-Base/Neutral)
TI
1
ab
Figure G-4 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X185 D10 •«• 8219-BNP3 (B112D) 8/13x81 BP1H
50M>-280(8> BTL*17 D13130
FRN 13130
1ST SCXPGI2797
X- .25 V- 1.00
Effluent B112D (8219-Base/Neutral)
5^
4
Figure G-4 (continued)
-------
o
I
H
Ul
1 UL
S0(4
TI
XX BATCH PROCESSOR RECONSTRUCT XX FRf
100/100 D10 + 8205 ANP3 (B119D) 8/12/81 BflH 1ST SC>
>-280<8> BTL*8 D13097 X- .25
Effluent B119D (8205-Acid)
<&
t
kwJ^ ^
I
t
ri l_ f i i i i
5 10
13097
Figure G-5
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent B119D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 •(- 8205 ANP3 (B119D) 8/12/81 BNH
50(4>-a80(8> BTL*8 D13097
FRN 13097
1ST SC/PGi 933
X- .35 V- 1.00
i
M
cn
TI
Effluent B119D (8205-Acid)
111
7
L
15
Figure G-5 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8SOS ANP3 (B119D) 8x12x81 BHH
S0<4)-280<8> BTL*8 D13097
FRN 13097
1ST SC/PGU865
- .25 v- 1.00
o
i
TI
Effluent B119D (8205-Acid)
Figure G-5 (continued)
-------
o
I
M
00
** BATCH PROCESSOR RECONSTRUCT ** FRN 13124
1 UL 125X135 DIO + 8205-BNP3 (B119D) 8X13/81 BHH 1ST SCxPGt 1
50(4)-280<8> BTLfcll D13124 X- .25 Y" 1.00
TI
Effluent B119D (8205-Base/Neutral)
. A
1
1
— — -• ^^^^^^^^
02.
-A
I I I I 1 1 1
5 10
Figure G-6.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent B119D.
-------
o
I
1 UL
50(4
Efflui
Tl
** BATCH PROCESSOR RECONSTRUCT ** FRN 13134
las/ias Die + saes-BNPS (Bii9D> s/is/si BHH IST SC/PG* 933
>-ase(8> BTLtll D13134 X- .35 V- 1.00
int B119D (8205-Base/Neutral)
4
. «
3>
i
. 1
i -i — i i i i
4 ** **» *A
1 y c,J
Figure G-6 (continued)
-------
o
I
to
o
** BATCH PROCESSOR RECONSTRUCT ** FRN 13124
1 UL 125/125 D10 + 8205-BNP3 (B119D) 8/13/81 BMH 1ST SC/PGU865
50(4>-280<8> BTL*11 D1312-4 X- .25 V- 1.00
\
« J
Effluent B119D (8205-Base/Neutral)
(o
\i
If
$ /O
-7 1^1
u ^ JL JL HA ^. A^J
• •
«
A. . 11
1 ' ' g's
Figure G-6 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 Die + 8205-BNP3 (B119D) 8/13x81 BHH
50(4>-280(8> BTLtll D13124
FRM 13124
1ST SC/PGI2797
X* .25 V- 1.00
NJ
Effluent B119D (8205-Base/Neutral)
TI
35
Figure G-6 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/1C0 Did + 8237 ANP3 (C150D) 8/12x81 BHH
S3<4>-280<8> BTL*17 D13106
FRN 131C6
1ST SC/PGt 1
X- .25 Y" 1
o
M
fO
TI
Effluent C150D (8237-Acid)
Figure G-7.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C150D.
-------
** BATCH PROCESSOR RECONSTRUCT *X
1 UL 100/100 D10 + 8237 ANP3 (C150D) 8/12/81 BflH
S0<4>-280<8> BTL*17 D131C6
FRN 13106
1ST SCxPGi 933
X- .25 V" 1.00
o
i
to
u>
TX
Effluent C150D (8237-Acid)
. _A .A
Figure G-7 (continued)
-------
o
i
ro
1 UL
50(4
TX
** BATCH PROCESSOR RECONSTRUCT ** FRN
100/100 D10 + 8237 ANP3 (C150D) 8/18/81 BMH 1ST SC/
>-280(8> BTL*17 D13106 X- .25 '
Effluent C150D (8237-Acid)
<2(
T t
1 1 A<~
*° * fl 1 7T\\
. ^. A* . ^/L/l . Jl JAUL
<.
25
13106
GU865
V- 1.00
.30 J
Figure G-7 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8237 ANP3 (C150D) 8/12/81 BNH
50<4)-280(8> BTL*17 D13106
FRN 13106
1ST SC/PGI2797
X- .25 V- 1.00
o'
i
N)
U1
TX
Effluent C150D (8237-Acid)
Figure G-7 (continued)
-------
1 UL
** BATCH PROCESSOR RECONSTRUCT **
125/125 D10 + 8237-BNP3 (C150D) 8/13/81 BP1H
> BTL*2C D13133
FRN 13133
1ST SC/PGt 1
X" .25 V- 1.00
a
i
N)
TI
Effluent C150D (8237-Base/Neutral)
JL
HILL r.
Figure G-8.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent C150D.
-------
o
I
NJ
•vj
1 UL
TI
** BATCH PROCESSOR RECONSTRUCT ** FRN 13133
125x125 D10 + 8237-BNP3 (C150D) 8x13x81 BHH 1ST SCxPGt 933
>-280<8> BTL*20 D13133 X- .25 V- 1.00
Effluent C150D (8237-Base/Neutral)
/ (/
I cJ"^
-
1? 1 x ,fc 1 ^
H /!> ' ^ n
1 1 I I I I 1 I 1
IB 20
Figure G-8 (continued)
-------
X* BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 D10 + 8237-BNP3 8X13/81 BMH
50<4>-280<8> BTL*20 D13133
FRN 13133
1ST SCXPGU865
X- .25 V- 1.00
Effluent C150D (8237-Base/Neutral)
Q
I
to
00
TI
Figure G-8 (continued)
-------
X* BrtTCH PROCESSOR RECONSTRUCT **
1 UL 125X185 D10 + 8237-BNP3 (C150D) 8/13x81 BHH
50(4)-280<8> BTL*20 D13133
FRN 13133
1ST SC/PG«2797
- .25 V- 1.00
i
to
vo
TI
Effluent C150D (8237-Base/Neutral)
11
Figure G-8 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8530 ANP3 (C155D) 8x18/81 BHH
S0<4>-280<8> BTL*1S D13104
FRN 13104
1ST SC/PGl 1
X* .25 V- 1.00
CD
I
u>
o
TI
Effluent C155D (8230-Acid)
10
Figure G-9.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C155D.
-------
*# BATCH PROCESSOR RECONSTRUCT **
i UL 100/100 Die + sase ANPS a/ia/ai BNH
50<4>-a80<8> BTL*15
FRM 13104
1ST SC/PGi 933
X- .25 V- 1.00
o
i
ui
TI
Effluent C155D (8230-Acid)
6
.JL
7
A
I
/O
15
Figure G-9 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8230 ANP3 (C15SD) 8/12/81 BMH
50(4)-880(8> BTL*1S D13104
FRN 13104
1ST SC/PO11865
X" .85 V- 1.00
i
U)
ro
TX
Effluent C155D (8230-Acid)
Figure G-9 (continued)
-------
** BfcTCH PROCESSOR RECONSTRUCT **
1 UL 125X125 D10 + 8230-BNP3 (C155D) 8/13/81 BP1H
50(4>-280<8> BTL»18 D13131
FRN 13131
1ST SC/PGI 1
• .25 V- 1.00
o
i
u>
U>
TX
Effluent C155D (8230-Base/Neutral)
Figure G-10.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent C155D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/185 D10 + 8830-BNP3 (C155D) 8X13/81 BP1H
S0<4>-280(8> BTL*18 D13131
FRM 13131
1ST SCXPGi 933
* .85 Y- 1.00
I
Effluent C155D (8230-Base/Neutral)
o
I
U)
TX
Jik,
Figure G-10 (continued)
-------
o
I
OJ
en
1 UL
50(4
TI
X* BATCH PROCESSOR RECONSTRUCT X* FRN 13131
125X135 D10 •»• 8330-BNP3 -38O<8> BTL*18 D13131 X- .25 V- 1.00
Effluent C155D (8230-Base/Neutral)
/
17
\ I
LA A JL *JL AJ\ ^^jg^^f
r
^>
. 'i 11 A
} ' ' af ' ' 3'a
Figure G-10 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
i UL lasxias Die •»• aaae-BNPs CCISBD) a/ia/si BNH
> BTL*18 D13131
FRN 13131
1ST SC/PG13797
X- .35 Y- 1.C0
o
i
TI
Effluent C155D (8230-Base/Neutral)
Figure G-10 (continued)
-------
** BftTCH PROCESSOR RECONSTRUCT **
UL 1OO/100 D10 + 8338 ANP3 (C156D) 8/12/81 BMH
BTL*18 D13107
FRN 13107
1ST SCxPGi 1
x- .as v- i.eo
o
I
U)
TI
Effluent C156D (8238-Acid)
Figure G-ll.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C156D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100X1C0 D10 + 8238 ANP3 (C156D) 8/18x81 BHH
50<4>-280<8> BTL*18 D13107
FRN 13107
1ST SC/PGl 933
- .35 V- 1.00
U)
00
TI
Effluent C156D (8238-Acid)
•?,"><"/'*-
-
O
^JLy
i
20
Figure G-ll (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8S38 ANP3 (C156D) 8x12x81 BP1H
EO<4>-280<8> BTL*18 D13107
FRN 13107
1ST SCXPGH86S
X- .35 Y- 1.00
o
i
OJ
vo
TI
Effluent C156D (8238-Acid)
JL
as
Figure G-ll (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D10 + 8238-BNP3 (C156D) 8x13/81 BHH
50<4>-280<8) BTL*21 D13134
FRN 13134
1ST SC/PGl 1
X- .25 V" 1.00
o
i
.u
o
TX
Effluent C156D (8238-Base/Neutral)
Figure G-12.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent C156D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 185X125 Die •»• 8838-BNP3 (C156D) 8x13X81 BHH
50<4)-880(8> BTLS21 D13134
FRN 13134
1ST SCXPGI 933
" .85 V- 1.00
a
i
TI
Effluent C156D (8238-Base/Neutral)
t**
t I
Figure G-12 (continued)
-------
i
>u
NJ
1 UL
50(4
TI
** BATCH PROCESSOR RECONSTRUCT ** FRN 13134
iaS/135 D10 + 8238-BNP3 (C156D) 8/13/81 BHH 1ST SC/PGU86S
>-E80<8> BTL*31 D1313-4 X- .35 V" 1.00
Effluent C156D (8238-Base/Neutral)
:
*
1. . t i J
0
^ '
T
.1 .
1 ' 'as ' ' a'a
Figure G-12 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D10 + 8238-BNP3 (C156D) 8X13/81 BNH
S0<4>-280<8> BTL»21 D13134
FRN 13134
1ST SC/PG12797
X- .25 V- 1.00
o
i
•u
u>
TI
Effluent C156D (8238-Base/Neutral)
1
Figure G-12 (continued)
-------
X* BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8211 ANP3 (C157D) 8/12/81 BHH
Sd<4>-380<8> BTL*10 D13099
FRN 13099
1ST SC/PGi 1
X- .35 V- 1.00
o
i
TI
Effluent C157D (8211-Acid)
Figure G-13,
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C157D.
-------
** BATCH PROCESSOR RECONSTRUCT **
i UL 100/100 010 -»• ssn ^NPS
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 DIO + 8S11 ANP3 (C1S7D) 8/18x81 BHH
50(4)-280(8) BTLS10 D13090
FRN 13099
1ST SCXPQ11865
X- .25 V- 1.00
o
i
*>.
cr>
Tt
4
Effluent C157D (8211-Acid)
Figure G-13 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT *X
1 UL 100/100 D10 + 8311 ftNPS (C1S7D) 8/13/81 BMH
50(4)-£80(8) BTL*10 D13099
FRN 13099
1ST SC/PGI3797
X" .25 V- 1.00
o
i
Effluent C157D (8211-Acid)
TI
Figure G-13 (continued)
-------
1
00
1 UL
50(4
TI
** BATCH PROCESSOR RECONSTRUCT ** FRN 13126
125X125 D10 + 8211-BNP3 (C157D) 8x13x81 BP1H 1ST SC/PG« 1
)-280(8) BTL*13 D13126 X- .25 V- 1.00
Effluent C157D (8211-Base/Neutral)
1
\ \
1 1 II I I 1 1
; id
Figure G-14.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent C157D.
-------
** BATCH PROCESSOR RECONSTRUCT ** FRN 13126
1 UL 125/125 Die + 8211-BNP3 (C157D) 8/13/81 BUM 1ST SC/PGt 933
S0<4>-280<8> BTL»13 D13136 X- .35 V- 1.00
r i
Effluent C157D (8211-Base/Neutral)
/
TI
.
i. •
, 1 . .. . "I •
i 1 i i i i i i
Figure G-14 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8239 ANP3 (C161D) 8x12x81 BHH
SOC4)-280(8) BTL*19 D13108
FRN 13108
1ST SCXPQt 1
* .25 V- 1.00
en
i
Ul
to
TI
Effluent C161D (8239-Acid)
Figure G-15.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C161D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 •»• 8839 ANP3 (C161D) 8/18X81 BMH
50(4)-880(8> BTL*19 D13108
FRN 12108
1ST SC/PQi 933
X" .85 V- l.OO
o
I
U)
TI
Effluent C161D (8239-Acid)
/L.
r A
Figure G-15 (continued)
>
^ .... J0
-------
** BATCH PROCESSOR RECONSTRUCT X*
1 UL 100/100 D10 + 8239 flNPS (C161D) 8/12x81 BHH
50<4)-280(8> BTL*19 D13108
FRN 13108
1ST SC/PGU865
X" .25 V- 1.00
o
i
ui
*>.
TI
Effluent C161D (8239-Acid)
n
I A.
Figure G-15 (continued)
-------
** BftTCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8339 ANP3 (C161D) 8x12/81 BP1H
SO<4>-280<8> BTL*19 D131C8
FRN 13108
1ST SC/PGIE797
* .25 V- 1.00
n
i
TI
Effluent C161D (8239-Acid)
Figure G-15 (continued)
-------
0
tn
1 UL
50 (4
TI
** BATCH PROCESSOR RECONSTRUCT ** FRN 13135
125/125 D10 •»• 8239-BNP3 (C161D) 8/13/81 BMH 1ST SC/PGi 1
>-280<8> BTLS22 D13135 X- .25 Y" 1.00
Effluent C161D (8239-Base/Neutral)
t ^
«
| .'
1 it
1 fc 11 i 1 1 '/
i * s^s"!1!! •4*AI/V
AA •, IL JLv*. A.A.AA/^ V. i~j^^^A.Ar^ A^.A
-------
o
I
tn
** BATCH PROCESSOR RECONSTRUCT ** FRN 13135
1 UL 125x125 D10 + 8239-BNP3 8/13/81 BMH 1ST SC/PGi 933
50(4)-280(8) BTL*22 D1313S X- .25 V- 1.00
TI
Effluent C161D (8239-Base/Neutral)
1
lfc|7 1
— ^JV^ -v-^
«
2
JiL_jULlJU--4J^_J(jds.^
i«r
J ] ik ' ' ' g'a
Figure G-16 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125x125 D10 •»• 8239-BNP3 (C161D) 8/13/81 BHH
50(4)-280(8) BTL*22 D13135
FRM 13135
1ST SCXPG11865
" .25 V- 1.00
Effluent C161D (8239-Base/Neutral) ^
i
tn
oo
Tl
Figure G-16 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT XX
1 UL 135X135 D10 •»• 8239-BNP3 (C161D) 8/13/81 BHH
50<4>-280<8> BTL*22 D13135
FRM 13135
1ST SC/PGI2797
X- .25 V- 1.00
o
i
tn
TI
Effluent C161D (8239-Base/Neutral)
35
Figure G-16 (continued)
-------
o
1
01
o
1 UL
£0(4
TI
** BATCH PROCESSOR RECONSTRUCT ** FRM 13101 .
100x100 D10 + 8212 ANP3 (C164D) 8'12/81 BHH 1ST SC/PG« 1
>-280(8) BTL*12 D13101 X- .25 V- 1.00
i
Effluent C164D (8212-Acid)
4
*"
A L. I I I ll I
1™ 1 ^ • 1 . 1 1 1 * 1
s 1Q ~ -
Figure G-17. Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C164D.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8212 ANP3 (C164D) 8/12x81 BHH
50(4)-280<8> BTL*12 D13101
FRN 13101
1ST SCXPGi 933
- .25 V- 1.00
o
i
TI
Effluent C164D (8212-Acid)
°(
Figure G-17 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8212 ANP3 (C164D) 8/12x81 BHH
50(4>-280C8> BTL*12 D13101
FRN 13101
1ST SC/PG»1865
- .25 V" 1.00
o
i
Effluent C164D (8212-Acid)
TI
Figure G-17 (continued)
-------
o
I
m
to
** BATCH PROCESSOR RECONSTRUCT ** FRN 13127
1 UL 125/125 D10 f 8212-BNP3 (C164D) 8/13/81 BMH 1ST SC/PGi 1
50(4)-280(8) BTL*14 D13127 , X- ,25 V- 1.00
TI
Effluent C164D (8212-Base/Neutral)
.
,1
.
f
•
1 I ' ' 1 ' ' 1 '
B 10
Figure G-18.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent C164D.
-------
o
** BATCH PROCESSOR RECONSTRUCT ** FRN 13127
1 UL 125/125 D10 + 8212-BNP3 (C164D) 8x13/81 BHH 1ST SC/PGi 933
50(4>-280<8> BTL*14 D13137 X- .25 Y- 1.00
Efflue
TI
nt C164D (8212-Base/Neutral)
.
?-
— A ..„ _
is a,,
Figure G-18 (continued)
-------
o
cr>
01
1 UL
50(4
TI
** BATCH PROCESSOR RECONSTRUCT ** FRN 13127
125/125 D10 «• 8212-BNP3 (C164D) 8/13/81 BHH 1ST SC/PGU865
>-280<8> BTL*14 D13127 X" .25 Y- 1.00
Effluent C164D (8212-Base/Neutral)
+
\
3
/.
Y
.[-
i i i i I I i
25
Figure G-18 (continued)
-------
1 UL
** BATCH PROCESSOR RECONSTRUCT **
125X125 D10 + 8212-BNP3 (C164D) 8/13x81 BMH
> BTL*14 D13137
FRN 13127
1ST SCXPG«2797
X- .25 V- 1.00
o
i
o>
(Tl
TI
Effluent C164D (8212-Base/Neutral)
Figure G-18 (continued)
-------
*# BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8208 ftNPS (C163D) 8/13/81 BHH
S©<4>-280(8> BTL*9 D13098
FRN 13093
1ST SC/PQi 1
X- .25 V- 1.00
o
i
TI
Effluent C169D (8208 Acid)
A
7
I
Figure G-19.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent C169D.
-------
1
00
** BATCH PROCESSOR RECONSTRUCT ** FRN 13093
1 UL 1OO/100 D10 -»• 8208 ANP3 (C163D) 8/12x81 BHH 1ST SC/PG* 933
5 BTL*9 D13098 *• .25 Y- 1,00
TI
Effluent C169D (8208 Acid)
.
n
•
» "• 1- • lr
^ °i i i ^ H 11
_ A . .A. ^ ^A iJl _..^/l . ._l\ _^_". .JUIVw J
IB 2*
Figure G-19 (continued)
!
-------
** BATCH PROCESSOR RECONSTRUCT *X
1 UL 100X100 D10 -»• 8208 ANP3 (C163D) 8x12x81 BflH
> BTL*9 D13098
FRN 13093
1ST SCxPGU865
X- .25 V« 1*00
o
i
vo
TI
Effluent C169D (8208 Acid)
I
Jt'
Figure G-19 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8208 ANP3 CC163D) 8/12/81 BNH
50(4)-280(8) BTL*9 D13098
FRN 13093
1ST SC/PG»2797
X' .25 V- 1.00
o
i
Tl
Effluent C169D (8208 Acid)
Figure G-19 (continued)
-------
** BftTCH PROCESSOR RECONSTRUCT **
1 UL 125X185 D10 + 8208-BNP3 (C163D) 8x13/81 BMH
50<4>-280<8> BTL*12 D13125
FRN 13125
1ST SC/PQt 1
' .25 V« 1.C0
o
TI
Effluent C169D (8208 Base/Neutral)
Figure G-20.
Total ion chromatogram from GC/MS analysis of extractat>le
organics base/neutral fraction from effluent C169D.
-------
o
I
~4
to
** BATCH PROCESSOR RECONSTRUCT ** FRN 13 135
1 UL 125/125 Die + 8208-BNP3 (C163D) 8/13/81 BMH 1ST SC/PGi 933
50(4>-28e<8> BTLtia D13125 X- ,25V- 1.00
TI
Effluent C169D (8208 Base
6
m
'/Neutral )
.
.. .; i
r
, i
L HA 1
i 1 ii ill ii
is aa
Figure G-20 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D10 «• 8208-BNP3 (C163D) 8/13/81 BHH
5e(4)-28O(8) BTLtlS D13125
FRN 13125
1ST SC/PGH865
X" .25 V- 1.00
o
I
U)
TI
Effluent C169D (8208 Base/Neutral)
U
A-*
i
25
is-
13
Figure G-20 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 D10 •»• 8208-BNP3 (C163D) 8/13x81 BMH
50(4>-280<8> BTL*12 D13125
FRN 13125
1ST SCXPGI2797
X' .25 Y- 1.00
o
i
TI
Effluent C169D (8208 Base/Neutral)
I
Figure G-2Discontinued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + S1S3 AMPS (B133S) 8X12/81 BflH
S3(4>-280<8> BTL*4 D13093
FRN 12093
1ST SCXPGi 1
' .25 V- 1
o
i
vj
Cn
TI
Effluent B133S (8183-Acid)
Figure G-21.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent B133S.
-------
o
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/1 CO D10 + 8183 ANP3 CB133S) 8x18/81 BflH
50(45-280(8) BTl/M D13093
FRN 13C93
1ST SC/PGi 933 j
:- .as v- 1.00
TI
Effluent B133S (8183-Acid)
15
2O
Figure G-21 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL ICO/1 CO D10 -f 8183 ANP3 (B133S) 8X12/81 BMH
50<4>-280<8> BTL*4 D13093
FRN 13093
1ST SC/PGU865
X- .25 V- 1.00
o
i
Effluent B133S (8183-Acid)
TI
I
30
Figure G-21 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT X*
1 UL 100/100 D10 + 8183 ANP3 (B133S) 8x18/81 BHH
SO<4)-280<8> BTL*4 D13093
FRN 13C93
1ST SCXPGIE797
X" .35 V- 1.00
o
i
•vj
oo
TI
Effluent B133S (8183-Acid)
Figure G-21 (continued)
-------
** BftTCH PROCESSOR RECONSTRUCT **
1 UL 135X125 D10 + 8183-BNP3 (B133S) 8x13x81 BMH
50(4>-28e<8> BTLt? D1312C
FRN 13120
1ST SCxPGi 1
- ,25 V" l.i
o
i
»j
\D
TI
Effluent B133S (8183-Base/Neutral)
(.
Figure G-22,
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent B133S.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 Die •»• 8183-BNP3 (B133S) 8X13x81 BMH
50C4>-280<8> BTL*7 D1312C
FRM 1312®
1ST SCxPGs 933
- .25 Y- 1.00
o
i
00
o
Effluent B133S (8183-Base/Neutral)
I
TI
II
<*
I <*•
I
20
Figure G-22 (continued)
-------
o
I
oo
** BATCH PROCESSOR RECONSTRUCT ** FRN 13120
1 UL 125/125 D10 + 8183-BNP3 (B133S) 8X13/81 BMH 1ST SC/PG»186S
S0(4>-280<8> BTL*7 D13120 X- .25 V- 1.00
TI
Effluent B133S (8183-Base/Neutral)
K
*— - \ A. > - r
W
-^ i JL A
1 1 1 1 1 1 1 IT
25 30
Figure G-22 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 155X125 Die + 8183-BNP3 (B133S) 8/13/81 BMH
50<4>-280<8> BTL*7 D13120
FRN 13120
1ST SC/PC5 »2797
- .25 V- I.e0
o
00
to
TI
Effluent B133S (8183-Base/Neutral)
35
Figure G-22 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100X100 D10 -»• 8185 ANP3 (B1-41S) 8X13/81 BMH
50(4)-380<8> BTL*6 D13095
FRM 13095
1ST SC/PGi 1
X- .35 V- 1.00
o
00
OJ
TI
Effluent B141S (8185-Acid)
Figure G-23.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent B141S.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 + 8185 ANP3 (B141S) 8/12/81 BMH
50<4>-280(8> BTL*6 D13095
FRN 13095
1ST SC/PGl 933
X- .25 V- l.OO
i
00
it*
TI
Effluent B141S (8185-Acid)
/z.
9
A
"A.
'' /<•
Figure G-23 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100X100 D10 + 8185 ANP3 CB141S) 8x12/81 BHH
50<4)-380<8> BTL*6 D130 95
FRN 13095
1ST SC/PGI186S
X- .35 V- 1.00
o
i
00
TI
Effluent B141S (8185-Acid)
71
J
35
3?
A
30..
Figure G-23 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
I UL 100/100 D10 -»• 8185 ANP3 (B141S) 8/1E/81 BNH
50(4)-280(8) BTL*6 D13095
FRN 13095
1ST SCXPQI2797
- .85 V- 1.00
o
i
oo
CT>
TI
Effluent B141S (8185-Acid)
V A
35
Figure G-23 (continued)
-------
o
I
GO
X* BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D1C + 8185-BNP3 (DIL 1«5> (B141S)
3/13/81 BflH BTL*9 D13122
FRN 13123
1ST SC/PGi 1
X- .25 V- 1.00
TI
Effluent B141S (8185-Base/Neutral) DIL 1:5
^. A
JL
ie
Figure G-24.
Total ion chroraatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent B141S.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 Ul 125/125 D10 + 8185-BNP3 (DIL 1»5> (B141S)
3'13/81 BnH BTLtS D13122
FRN 13133
1ST SC/PGt 933
• .25 V- 1.00
i
00
CO
Effluent B141S (8185-Base/Neutral) OIL 1:5
Figure G-24 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 Die + 8185-BNP3 (DIL 1«5> (B141S)
3/13x81 BHH BTL*9 D1318S
FRN 13122
1ST SC/PGU865
' .25 V- 1.00
o
CD
VD
TI
Effluent B141S (8185-Base/Neutral)^IL 1:5
M . H
Figure G-24 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D10 + 8185-BNP3 (DIL 1«S) (B141S)
3/13x81 BMH BTL*9 D13122
FRM 13122
1ST SC/PGt2797
' .25 Y" 1.00
o
i
VD
O
TI
Effluent B141S (8185-Base/Neutral) DIL 1:5
35
A—/v.
Figure G-24 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT *X
1 UL 100/100 D10 + 8184 ANP3 (B142S) 8x12/81 BP1H
S0(4>-280<8> BTL*5 D13094
FRN 13094
1ST SC/PG» 1
X- .25 V- 1.00
Q
I
vo
TI
Effluent B142S (8184-Acid)
\
13 1*1
Figure G-25. Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent B142S.
-------
** BfVTCH PROCESSOR RECONSTRUCT **
I UL 100/100 D10 •»• 818-4 ANP3 (B142S) S^ia/Sl BMH
SO(4)-280(8) BTl*5 D13094
FRN 13094
1ST SCxPGt 933
X- .35 V- 1.00
Q
vo
NJ
TX
Effluent B142S (8184-Acid)
n
I
Figure G-25 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 100/100 D10 •»• 8184 ANP3 (B142S) 8/12/81 BHH
SOM)-280(8) BTL*S D13094
FRN 13094
1ST SCXPGI1865
X- .25 V- 1.00
o
i
VD
CO
TI
Effluent B142S (8184-Acid)
Figure G-25 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 D1C + 8184-BNP3 (B142S) 8/13/81 BMH
50(45-280(89 BTLtS D13121
FRN 13121
1ST SCXPG» 1
• .25 V" 1.00
a
i
TI
Effluent B142S (8184-Base/Neutral)
Figure G-26.
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent B142S.
-------
0
vo
** BATCH PROCESSOR RECONSTRUCT ** FRN 13121
1 UL 125X125 D10 + 8184-BNP3 (B142S) 8x13X81 BHH 1ST SCxPGt 933
50<4>-280<89 BTL*8 D13121 X- .25 V- 1.00
n
Effluent B142S (8184-Bas
'i \ \
HilLU
i
e/Neutral)
«
ctL_JL^^
f 3i° T^i^
i >^A ^^IL A Aft A J
, .
i i i i ii i i i
15 20
Figure G-26 (continued)
-------
o
I
vo
** BATCH PROCESSOR RECONSTRUCT ** FRN 13121
1 UL 125X125 D10 •»• 8184-BNP3 (B142S) 8X13X81 BHH 1ST SCXPGU865
50(4>-280<89 BTL*8 D13121 *• .25 V- 1.00
TI
Effluent B142S (8184-Base/Neutral)
^ T
» A. /I . „,
•
'
25 aa
Figure G-26 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT *X
1 UL 125X125 Die + 8184-BNP3 (B142S) 8/13/81 BHH
BTL*8 D13121
FRM 13121
1ST SC/PGI2797
X- .25 V- 1.00
o
vo
TI
Effluent B142S (8184-Base/Neutral)
Figure G-26 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D10 •»• 8193-ANP3 8/H/81 BMH
5O<«>-280<8> BTL*22 D13157
FRN 13157
1ST SC/PGi 1
X- .25 Y- 1.00
o
i
vo
00
TI
Effluent B149S (8193-Acid)
*.
I
3
A.
I
10
Figure G-27.
Total ion chromatogram from GC/MS analysis of extractable
organics acid fraction from effluent B149S.
-------
** BATCH PROCESSOR RECONSTRUCT **
UL'125X185 D10 + 8193-ANP3 8x1-4x81 BP1H
8) BTL*aa D13157
FRN 13157
1ST SCxpQi 933
X- .35 V" 1.00
o
i
vo
vo
TI
Effluent B149S (8193-Acid)
,10
Figure G-27 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125x125 D10 + 8193-ftNP3 8/14/81 BMH
BTL*22 D13157
FRN 13157
1ST SCxPGtl865
" .25 V- 1.00
o
o
o
TI
Effluent B149S (8193-Acid)
25
Figure G-27 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X185 D1C + 8193-BNP3 CDIL It 10). 8/14/81 BMH
50<4)-280<8) BTL*8 D13143
FRN 13143
1ST SC/PGi 1
• .25 Y« 1.00
Q
I
TI
Effluent B149S (8193-Base/Neutral)
I
A.
Figure G-28,
Total ion chromatogram from GC/MS analysis of extractable
organics base/neutral fraction from effluent B149S.
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125/125 D10 + 8193-BNP3 (DIL 1*10) 8/1-4x81 BMH
50<4>-280(8> BTL*S D13143
FRN 13143
1ST SC/PGJ 933
» .25 Y" 1.03
o
i
M
O
N>
TI
Effluent B149S (8193-Base/Neutral)
Figure G-28 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 125X125 D10 + 8193-BNP3 -280(8> BTL*8 D13143
FRN 13143
1ST SCXPGH865
• .25 V- 1.00
o
i
M
O
U)
TI
Effluent B149S (8193-Base/Neutral)
25
Figure G-28 (continued)
-------
APPENDIX H
RELATIVE RETENTION INDICES OF PHASE III SEDIMENTS
A discussion of the generation of these data is contained in
Appendix C, Section 10.
H-l
-------
TABLE H-l. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE A109
PROCESSED FILE:
KAU FILE:
SAMPLE NAME:
*PRC32
CBS33
Sediment A109 (8400)
SEH 8400
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
i
2
A
7
B
9
10
11
12
13
14
15
16
AREA
2.26263E+06
1.16865E+06
6.61620E+07
1784,19
7008.94
14432*2
10169.8
23010.7
1579.75
4749.75
2015.36
1288.12
1210.87
23870.7
16744.1
7817.87
TIME
2.2:
2.28135
2.29583
3.4822
3.71597
11,1598
12.4664
19.606
19,8146
21.5191
23.1266
26.2471
30.1134
30,7795
34,8479
41.124
INDEX
***
***
***
***
***
***
***
***
102.039
127.865
152.222
199,501
284.066
298.674
397.754
497.847
H-2
-------
SB
I
©
CO
Oi
Ld
c
o
'li
Ml
I
7000
6000
5000
u
f-
^ 4000.
Sediment A109 (8400)
uu
!,,.,;«. ' ~n
, i.
0.90 6.46
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SfiMPLE: SED 8400 INJECTED RT 19:45:35 ON SEP 10, 1981
Method: BRY32 Raw: CES33 Proc : *PRC32
Figure H-l. FID/GC chromatogram for sediment sample A109.
-------
TABLE H-2. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B112D
PROCESSED FILE? *PRC32
RAW FILE: CBSIO
SAMPLE NAME:
Sediment B112D (8380) OIL 1:5
SED 8380 DIL
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
AREA
4234.05
63147.6
6.86382E+07
12993,9
16801,1
7445,75
1007.75
3961.25
2702
37269,2
1617.75
3246,27
6111.87
1222
3556.97
1157.19
4468.02
6877
1640.34
2209.56
24858.7
2046.24
26506,2
TIME
2.14964
2.21207
2.25208
3.70573
11.1376
12.4584
12.7453
15.8949
18.1093
19,6109
19,8205
20.9837
21.5307
21.5806
22.1049
22.769
23.1422
23.2135
24.6594
26.1096
26.2742
26.3511
26.4263
INDEX
*#*
***
#**
***
***
***
##*
***
102.129
119.753
128,041
128.796
136.742
146.803
152.458
153.539
175,446
197.418
199.912
201.559
203.208
H-4
-------
TABLE H-2 (continued)
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
4
49
50
53
54
55
56
57
5116.44
1753,72
1088,87
1144,99
1737.59
6056,14
3612,95
8320.47
2238.19
2204,67
2043,98
10722,2
1350.23
63399.7
16432.4
2176,17
4132.88
2612,67
2315.49
2179.43
104390.
3691.8
5795.72
1116.68
1798.65
1177.72
27009.4
18159.4
1335.66
2223.69
2223,55
1217,53
1123,23
1304.16
27.0098
27,3179
27.8777
28,0679
28.0807
28,2278
28,2385
28.6596
28.9172
28.9319
29,8274
29,9652
30.0017
30.1691
30.6656
30.6738
30.6875
30.7013
30.7127
30.7258
30,8786
31.0926
31,2854
31.6545
31.6655
31.8312
32.013
32,2242
32.3399
32.618
32.7195
33.395
33.4401
33.6188
216.
222.
235.
239,
239,
242,
242.
252.
257.
258.
277.
280.
281.
285.
296.
296.
296.
296.
297.
297.
300,
306.
310.
319.
320.
324.
328,
333.
336.
343,
345,
362.
363.
367.
003
761
037
209
489
714
95
185
833
157
793
816
617
286
176
355
656
959
208
495
94
162
864
866
135
177
609
761
584
365
842
317
418
774
H-5
-------
TABLE H-2 (continued)
58
59
60
61
62
6
6A
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
r
t.
90
91
1189,16
8249,52
5116,68
4723.73
2877.67
5759.28
7967.86
62139.9
26102.6
6479.2
30521.6
1149.1
4022.55
3085.77
5338.73
1252.22
1364.45
3609.12
2343.7
1023.41
1515.71
2666.57
1080,52
1126,59
17433.
6749.07
13740.2
1988,02
3187,69
1641,72
5922.05
4951.5
12927.
19588,2
33.6717
34.0106
34.1328
34.1527
34,5407
34.616
34.6867
34.8805
34.9031
34.9489
34.9869
35.1071
35.2478
35.2659
36.3902
36,5604
36.73
36.756
36.8997
36.9195
36.9377
36.9806
37.1344
39,1058
39.2698
39.2831
39,3229
39.6804
39,7254
40.326
40,5685
40.5944
40.8551
41.1787
369.066
377.331
380.313
380.798
390.262
392.097
393.821
398.549
399.1
400.141
400,742
402.644
404,87
405,156
422.945
425.639
428.323
428.733
431.009
431.322
431.61
432.287
434.721
465,914
468.509
468,72
469.35
475.007
475.719
485,222
489.059
489,468
493.593
498.714
H-6
-------
a
I
G'
o
IJ
a-
w
i
>
If!
-------
TABLE H-3. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B119D
PR zssED FILE:
RAW FILE:
SAMPLE NAME:
*PRC32
CBS40
Sediment B119D (8404)
SED 8404
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
4
5
6
7
6
9
10
11
12
13
14
AREA
2.09625E+06
6.81155E+07
211450.
2066.3
8319.16
14938.3
11635.4
26306.8
1112
1162.25
1666.94
31033.5
23467.5
10983,4
TIME
2.22594
2.27708
2.91147
3.4671
3.71792
11.1543
12,4599
19.6055
26.675
27.2719
29.0117
30.7787
34.8482
41.1188
INDEX
*#*
***
***
***
***
***
208.662
221.752
259,906
298.656
397,761
497,765
H-8
-------
©
G' 8000 .
ffi
Si
X
tl
*i 70013 .
i_
r— t
U
1.0
c
o
a>
K I
vo -1
u> Rfinn .
CM "
X
U
ZI1
^ 4000.
1 ' I ' 1 ' 1
Sediment B119D (8404)
-
-
1,
1
f \L ».
i
-
^JU M
I ' i ' i •
^JU
.
j. . i. j _-.—(_ i
•
^ju^^JLl—
i . i . i .
0 .00
RT in minutes
12.80 19.20 25.60 32.00 38.40
SPMPLE: SED 8404 INJECTED RT 3:15:11 ON SEP 11, 1981
Method: BRY32 Raw: CES40 Proc: *PRC32
.80
Figure H-3. FID/GC chromatogram for sediment sample B119D.
-------
TABLE H-4. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C150D
PROCESSED FILE: *PRC32
RAW FILE: SED26
SAMPLE NAME:
Sediment C150D (8393)
SEH 8393
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
AREA
2509,97
7.17189E+07
13602.9
9344.75
3108,44
28057,6
5566.75
18208.2
7915.37
2756.3
1104.06
29452
21934.5
15083.7
TIME
2.22169
2.24583
3.69792
11.126
12.4449
19.5973
19.806
21.516
23.1189
24.6412
26.0866
30,7694
34.8374
41.1235
INDEX
#**
***
***
**#
***
101.908
127.819
152,104
175.17
197.07
298.451
397.497
497.84
H-10
-------
a
i
X
~o
•1"
i.
'fl
1—I
I—
lij
C
O
*
I/I
OJ
X
LJ
u
t-
»-H
_J
IX
10000.
8000 ,
6000
4000.
0
RT in
Sediment C150D (8393)
. 0 0
minutes
6.40 • 12.80 19.20
SPMPLE: SEP 8393
Method:
25.60
32.00
33.49
44.80
INJECTED flT 9:49:03 ON SEP 25, 1981
BRY32 'Raw: CESD15 Proc: *PRC32
Figure H-4. FID/GC chromatogram for sediment sample C150D.
-------
TABLE H-5. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C156D
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF3
Sediment C156D (8379)
PEAK*
l
2
3
4
5
6
7
3
9
10
11
12
13
AREA
1.33549E+06
1.47597E+06
9.O2103E+07
1610.37
37575.9
24373'. 2
57799.2
1126.87
1812.36
1409.75
85349.2
68073.6
48306.2
TIME
2.12701
2.1729
2.24792
3.19035
11.2199
12.5136
19.6195
28.05
28.2776
30.5569
30.8127
34.8843
41.193
INDEX
#**
«*»
*«#
###
«•»#
#•#•#
238.816
243.807
293.793
299.402
398.642
498.939
H-12
-------
0
5 6300.
X
T?
E 5600.
Ul
w
•Q
o
U
H'
M r 4900.
1 >
H ^
W Irt
OJ
X
U
? 4200.
t— »
_i
0.
a 0.
RT inn
Sediment C156D (8379)
-
"
-
A_ 1.
1
!
1
.^JJUlL-L
i
>.j a, 1
* i
it. i ^ _„
.
-
"
_ .xH
i i i i
00 6.40 12.80 19.20 25.60 32.00 38.40 44.80
iinutes SflMPLE: SED 8379 INJECTED fiT 11:27:19 ON SEP 9, 1981
Figure H-5. FID/GC chromatogram for sediment sample C156D.
-------
TABLE H-6. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C157D
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC32
CBS39
Sediment C157D (8403)
SED 8403
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
i
2
3
4
5
6
7
8
*
10
11
12
13
AREA
2.39476E+06
6,85879E+07
2134,8
8102.16
13617
10100.5
22505.5
2848,37
1221.06
27238.5
20839.5
1084.25
10691.2
TIME
2.23002
2.27708
3.48307
3.71042
11.1552
12.4629
19.6013
21.5145
23,1236
30.7771
34.8451
40.313
41.1203
INDEX
***
***
***
***
^ ^ ^
127.795
152.176
298.621
397.685
485.016
497,79
H-14
-------
UI
T'
*
u
o
u
w
Lr,
OJ
X
u
7FIPH3
6960
5000
4000 .
Sediment C157D (8403)
0.00
RT in minutes
fc^ „_
SflMPLE: SED 8403 INJECTED OT 2:10:49 ON SEP 11, 1981
Method: EOY32 Raw: CES39 Proc : *PRC32
Figure H-6. FID/GC chromatogram for sediment sample C157D.
-------
TABLE H-7. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C161D
PROCESSED FILE: *PRC32
RAW FILE: CBS?
SAMPLE NAME:
Sediment C161D (8377)
SED 8377
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
•~~AK*
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
AREA
762463.
8.73528E+07
1266.81
3634.75
9918,75
18808,2
13775.4
34587.
1106.87
1149.19
1402
2682.16
2716.62
5795.34
48789.7
36232.2
1334.81
28698.1
5673.37
7335.62
TIME
2.14319
2.27292
3.06172
3.66528
5.58042
11.1719
12.4782
19.5962
24.7301
25.4993
26,2319
28.0506
28.2748
30.5525
30.777
34.845
35,3599
41.1383
45.3104
46.4464
INDEX
***
***
***
***
***
***
176.516
188.171
199.272
238.829
243.745
293.696
298.619
397,682
406.644
498.074
543.647
555,
H-16
-------
I
H1
^1
TJ
a*
•m
LJ
v.
O
i_t
ill
Vi
I
LO
OJ
a
7200 .
' 5400,
4500
Sediment C161D (8377)
JU
0.00 6.40
RT in minutes
12.80
19.29
25.60
32.00
33.40
44.80
SflMPLE: SED 8377 INJECTED RT 23:32:47 ON SEP 24, 1981
Method: ERY32 . Raw: CBSD9 Proc : *PRC32
Figure H-7. FID/GC chromatogram for sediment sample C161D.
-------
TABLE H-8. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C164D
»r«£?FILE! *Bs"2 sediment CIMD <84°7>
SAMPLE NAME:
SED 8407
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
4
5
6
7
8
9
10
11
12
AREA
1.70923E+06
6,74994E+07
76603,6
1567.37
8945.06
17114.2
11642.8
27101.7
32391.9
1061.36
24838.2
12398.7
TIME
2,21744
2.275
2.91529
3,45604
3,73073
11,1536
12,4621
19.6065
30.7808
30,8792
34.8514
41,1229
INDEX
***
***
***
***
***
298,702
300.955
397.84
497.831
H-18
-------
®
£'
X
•n
'!•
^ 7000.
•— <
c
LJ
l.'l
£ 6000 .
O
111
£ i
VO
N 5000 .
• x
Lul
— i
t-
^ 4000.
-
-
-
L
1 i ' i • i
Sediment C164D (8407)
I
i . i
L . .. ..i. . .^._r^-' ' *''
1 ' 1 ' 1
-
.
-
•
-
'
0.00 6.40
RT in minutes
12.80
19.29
25.60
32.00
38.40
44.80
SRMPLE: SED 8407 INJECTED PT 7:33:18 ON SEP 11, 1981
Method: BRY32 Raw: CBS44 Proc : *PRC32
Figure H-8. FID/GC chromatogram for sediment sample C164D.
-------
to
to
Ml
•O
Ml
I
LO
X
U
LL
0
©
C'
T3
a>
en
* 7000,
c
6606
5000
4000.
Sediment B141S (8385)
0.00
RT in minutes
2.10
4.20
6.30
8.40
10.50
12.60
14.70
16.89
SflMPLE: SED 8385 INJECTED ftT 20:59:46 ON SEP 9, 1981
Method: BOY32 Raw: CES18 Proc : *PRC32
Figure H-9. FID/GC chromatogram for sediment sample B141S.
-------
I
to
U)
©
IS
T3
a>
c
LJ
c
o
V
OP
Vl
I
CM
X
bJ
_J
a.
8000. -
^ .7000. -
6000. -
5000 . -
Sediment B141S (8385)
4000
RT in minutes
18.90
21 .60
23.10
25.20
27.30
29.40
31 .50
33.60
SRMPLE: SED 8385 INJECTED flT 20:59:46 ON SEP 9, 1981
Method: BOY32 Raw: CBS18 Proc : *PRC32
Figure H-9 (continued)
-------
55
to
T3
•1'
CT«
o
u
ill
Vi
I
U)
OJ
X
u
CL
E:
a
seee
J; 7000,
6000 .
5000 .
4000. -
Sediment B141S (8385)
RT in minutes
35.70
37 .80
39.90
42 .00
44.10
46.20
48.30
50.40
SflMPLE: SED 33SS INJECTED RT 20:59:46 ON SEP 9, 1981
Method: BOY32 Raw: CES18 Proc : *PRC32
Figure H-9 (continued)
-------
TABLE H-10. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B142S
PROCESSED FILEJ *PRC32
RAU FILE: CBSI?
SAMPLE NAME:
Sediment B142S (8386)
SEH 8386
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
AREA
831579.
8.37583E+07
42053,7
478429.
8582.52
8507.75
17872.9
1261.25
12188.3
1528.75
2639.34
1451.78
1149,73
30528.3
7304.8
4588.12
1130.12
20279.9
9433.28
1275.25
4902.92
1546.82
1047.87
2060.81
2582.56
1341.8
1168.94
1117.69
33570.
1476,47
1533,09
1272.04
28847.4
2144,47
1377.02
2702.25
20890
TIME
2.13805
2.25208
2.95609
3.10026
3.18137
3.62486
11.181
11.8058
12.4856
15.8972
18.1056
18.4448
19,376
19.6051
19.8194
20.0644
21.166
21.5265
23,1298
23.7785
24.6516
24.7424
25.2663
26,1004
26.2461
27,481
27.7454
28.2589
30.7824
31.6753
32.8597
33.5609
34,8542
35.3673
37.1137
40.326
41.1521
INDEX
#**
***
***
***
***
**#
***
***
***
***
***
***
102.113
105.824
122.515
127.977
152.269
162.098
175,327
176,702
184.64
197.28
199.486
226,339
232.136
243.396
298,737
320,3/4
349.261
366.364
397.906
406.76
434.394
485.222
498.292
H-25
-------
a
CO
CTl
X
T) 6400
o>
U
O
o
111
l.n
U'
CM
U
1=1
n
5608,
4808
4000.
Sediment B142S (8386)
0.00 6.40
RT in minutes
12.80 19.20 25.60 32.00 38.40
SfiMPLE: SED 8386 INJECTED fiT 22:03:14 ON SEP 9, 1981
Method: BRY32 Raw: CBS19 Proc : *PRC32
44.80
Figure H-10. FID/GC chromatogram for sediment sample B142S.
-------
TABLE H-ll. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE A101
PROCESSED FILE: *PRC32
RAW FILE: CBS43
SAMPLE NAME:
Sediment A101 (8406)
SED 8406
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
i
4
5
6
7
8
V
10
11
12
AREA
1.78216E+06
6.69371E+07
94423.2
1330.87
8863.87
15416.2
8808.25
26942
30037
22632.6
1423.5
11852.5
TIME
2.22005
2.275 -
2.91568
3.45389
3.73333
11.1522
12.459
19.6056
30.7792
34.8495
40.3139
41.1198
INDEX
***
***
***
***
***
***
***
***
298.666
397.793
485.03
497.781
H-27
-------
I
to
CO
® 8000,
TJ
111
Ill
1.0
I
OJ
X
u
7600 ,
6000,
5000
4000. -
Sediment A101 (8406)
0.00 6.40
RT in minutes
12.80
19.20
25 .60
32.00
38.40
44.80
SflMPLE: SEH 8406 INJECTED OT 6:28:40 ON SEP 11, 1981
Method: ERY32 Raw: CES43 Proc : *PRC32
Figure H-ll. FID/GC chromatogram for sediment sample AlOl.
-------
TABLE H-12. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B113D
PROCESSED FILE:
KAW FILE:
<; AMPLE NAME:
*PRC32
CBS34
Sediment B113D (8401)
SED 8401
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
i
2
3
4
5
6
7
0
9
10'
11
12
13
14
15
16
57
58
59
AREA
1.08143E+06
1.02069E+06
6.32984E+07
304701.
1079.25
8703.44
15443
10010
26025.9
1532
4804,25
2081,19
29813,9
21005.8
1425,12
1065.25
1770.59
10898,4
1914
TIME
2.20297
2.27292
2.29167
2.88635
3.43712
3.73611
11.1501
12.4588
19.606
19.8141
21.5197
23.1256
30,7807
34.8454
37.099
39.2854
40.325
41.1262
43.4903
INDEX
***
***
#*#
***
***
***
***
***
***
102.031
127.874
152.206
298.699
397.693
434.161
468.757
485.206
497.883
524.033
H-29
-------
a
U)
o
XI
o-
i_
.fl
r—t
•r
u
i/i
•n
c
u
•i>
w
Ll.I
OJ
Ul
1=1
8000
7000
6000 ,
5000
4000. -
Sediment B113D (8401)
•tJ
0.00
RT in minutes
6.40
i2.se
19.20
25.60
32.00
33.40
44.36
SfiMPLE: SED 8401 INJECTED RT 20:49:56 OH SEP 16, 1981
Method: EOY32 Raw: CES34 Proc: *PRC32
Figure H-12. FID/GC chromatogram for sediment sample B113D.
-------
TABLE H-13. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B124D
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC32
CBS38
Sediment B124D (8402)
SED 8402
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
6
7
8
9
10
11
12
13
14
15
16
17
18
AREA
2.08546E+06
1.09682E+06
6.54470E+07
0
1506.5
7871.75
15195.4
9867.25
25676.4
1240.47
4160.75
1760.5
1257.06
29537.4
22328.2
1350
1386.75
11850.5
TIME
2,21993
2.28125
2.29583
2.91352
3.466
3.71979
11.1533
12.462
19.6049
19.8118
21.517
23.1229
24.6465
30,7802
34.8479
37.0937
40.3174
41.119
INDEX
***
#**
#**
***
***
***
***
***
***
101.997
127.833
152.165
175.25
298,689
397.754
434,078
485.085
497,769
H-31
-------
•s
X
TjJ 7000 .
0>
i-
It)
LJ
£! 6000 .
c
o
111
1 j1
to "=>
u:i 5000 .
lM
X
u
Pi
t— 4
-I 400F1.
CL
ET
Sediment B124D (8402)
-
-
\
II
I. . .
i . i . i
> ."i
•
. . ..L- -,1,, imw'"1 • • • '
-
.
1
1
, > i ifr*
-uJ^^LjJ V_
i.i.i.
0.00 6.40
RT in minutes
12.80
19.20
SflMPLE: SED 3402 INJECTED flT 1:06:26 ON SEP 11, 1981
Method: BRY32 Raw: CES38 Proc : *PRC32
Figure H-13. FID/GC chromatogram for sediment sample B124D.
-------
TABLE H-14. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C151D
PROCESSED FILE: *PRC32
RAW FILE: CPSSO
Sediment C151D (8395)
SAMPLE NAME:
SED 8395
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
A
5
6
7
9
10
11
12
13
14
15
16
AREA
18525
148396.
7.21999E+07
12140,7
13576
7759,25
29188.2
7304.75
23215
10457,7
3650,5
1489.37
34324.
23557
1069.44
12962.7
TIME
2.13523
2,21833
2.24375
3,69688
11,1266
12.4448
19.5954
19.8046
21.5145
23.1165
24.6363
26.0861
30,7693
34.8279
40.2844
41.0924
INDEX
***
***
***
***
***
***
***
101.888
127,795
152,069
175.095
197.062
298.451
397.266
484.563
497.347
H-33
-------
ixt
l^>
•3 10000.
X
T)
0>
a«
"c 8008 .
u
•o
o
i
J3Q ii'i
1 1
£ ^ 6880 .
u?
OJ
X
(=4
1-
^ 4800.
Sediment C151D (8395)
-
1
i.i.
i_k^—
-
.
.
J
i . i . i . i •
8.00 6.4Q
RT in minutes
12.80
19.28
25.60
32.00
38.48
44.88
SfiMPLE: SED 8395 INJECTED fiT 9:48:12 ON SEP 10, 1981
Method: EflY32 Raw: CBS38 Proc : *PRC32
Figure H-14. FID/GC chromatogram for sediment sample C151D.
-------
TABLE H-15. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C153D
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC32
CBS14
Sediment C153D (8382)
SED 8362
Fv'ELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
24
25
26
27
28
29
30
31
32
33
AREA
690146,
2.93390E+06
8.32176E+07
1964,33
5970.85
199668.
2735.13
2465.53
8263
1386.5
2382.25
61443.2
4774.69
14868,5
1111.09
6836.63
1753.37
3293,42
1791.19
7046.81
1815.96
12415.2
58966.8
1213.25
4031.75
1594.3
1128,05
46630.
2246.19
2281.44
29621,7
TIME
2.14
2.23979
2.27083
2.92489
2.97498
3.05462
3,13047
3.1514
3.59508
8,82847
11.1613
12.4905
15.8937
19.6186
19.8154
21,5227
22.0924
23,1306
23.1993
24.6521
26,0982
26.2534
28.2031
30.1213
30.7985
31.2615
31.9674
32.1799
34,1083
34.8735
40.524
40.7865
41,1798
INDEX
#**
###
***
***
***
***
***
#**
***
***
***
***
***
102,051
127,919
136.551
152.282
153.323
175.335
197,245
199.598
242.174
284.239
299.09
310.279
327.497
332,68
379.715
398.378
488,354
492.507
498.73
H-35
-------
Q
K
"D
a-
LJ
o
u
l.'l
I
OJ
X
LJ
a
7000 . -
6000. -
5000 . -
-
-
.
-
Sediment C153
1 , 1
ik. . . __,[., J.J.
i ' 'i
D (8382)
1
A Ll
LA
•A*
^Jl^™"*""
4>V
I
wkA
-
wJu
JJlww • /fcA— u^*—^ A.
-
RT in minutes
SflMPLE: SED 8382 INJECTED flT 16:45:59 ON SEP 9, 1931
Method: BPY32 Raw: CBS14 Proc : *PRC32
Figure H-15. FID/GC chromatogram for sediment sample CIS3D.
-------
TABLE H-16. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C154D
PROCESSED FILE: *PRC32
RAW FILE: CBSIS
SAMPLE NAME:
Sediment C154D (8381)
SED 8381
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
A
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
AREA
8340.22
7.04994E+07
12366,6
16635.9
5831.87
1095.5
62527,5
7200.28
1296.58
1768.22
19424.8
7321.81
3230,59
1116,02
1340,29
1844,57
2379,95
1851.03
2136.41
5118.62
4664.19
1454.77
1767.07
75105.6
2132.56
1195.27
8397.36
1435.28
86808.2
1951,97
1324.55
1539,74
1016.23
1170,39
1720,41
1465,22
1343.23
17348.
13790.4
TIME
2,2192
2.25
3,70556
11,1415
12.4579
15,8974
19,6255
19.8318
20.5153
21.1615
21.5394
23.1522
24.6767
24.7798
25.3172
26.1284
26.2717
26.28
30.1142
30.146
30.6158
30.6302
30.6599
30.8243
32.0049
34.6048
34.6723
34,7106
34,913
35.3993
39.6857
40.3549
40.5526
40.5841
40.8219
40.8384
41.0344
41.1967
41.2169
INDEX
***
***
***
***
#**
***
***
102,3
112.664
122.448
128.173
152.609
175.707
177,269
185,412
197,703
199,875
199,999
284.083
284.781
295.082
295.399
296.05
299.655
328,412
391,824
393.471
394.405
399.342
407.267
475.09
485.678
488.807
489.306
493.068
493.329
496,43
498,999
499.318
H-37
-------
u>
00
o
CD
c
u
c
o
IJ
a<
M'l
I
x
u
Sediment C154D (8381)
8000,
6000 ,
4000.
0.00
RT in minutes
6.40
12.80
19.20
25.60
32.00
38.40
44.30
SfiMPLE: SED 8331 INJECTED flT 15:42:21 OH SEP 9, 1931
Method: BOY32 Raw: CBS13 Proc : *PRC32
Figure H-16. FID/GC chromatogram for sediment sample C154D.
-------
TABLE H-17. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C158D
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC32
CBS27
Sediment C158D (8394)
SED 8394
F^ELATIVE RETENTION VALUES
OUTPUT FILE:
PEAK*
i
A
5
6
7
8
9
10
11
1?
1
14
15
16
17
18
AREA
224948.
7.75013E+07
249997.
0
2586
9018.97
19434.5
14330.9
31901,2
9367.94
26581.5
11399.5
3859.5
1646.25
34989.3
24015.9
1581,87
15177.2
TIME
2.12865
2.24583
2.893
3.02672
3.45699
3.71562
11.1499
12,454
19,5991
19,8079
21,5214
23.1201
24.6414
26.0885
30.7754
34.8396
40.2979
41.1104
INDEX
***
***
***
***
***
***
***
***
101.937
127/899
152.122
175.172
197,099
298.583
397.551
484.777
497.633
H-39
-------
Q
Q
x 8000.
r>
*
-fl
C 7000.
•r
o
v 6000 .
tG (f\
0 3
^ 5009.
X
u
Cl
H.
a.
Sediment C158D (8394)
-
~
-
i
. .
I ' I • i • 1 •
L_Lu_
'
ld«M •" * J
~
-
-
- — L—JLL-^^
i .1 . i . i
a:
0.00
RT in minutes
6.40
12.30
19.20
25.60
32.00
38.40
44.8©
SflMPLE: SED 8394 INJECTED flT 6:29:46 ON SEP 10, 1981
Method: ERY32 Raw: CBS27 Proc:'*PRC32
Figure H-17. FID/GC chromatogram for sediment sample C158D.
-------
TABLE H-18. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C159D
PROCESSED FILE! *PRC32
RAW FILE: c&sis
SAMPLE NAME:
Sediment C159D (8383)
SED 8383
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
AREA
1.13138E+08
15337,8
11926,6
7460.68
262913.
3998.25
1913.19
24176.5
15648.5
1663.95
39937.
5286.41
1113.91
1613.17
1620.44
6175,5
40799.2
2210,44
30847.2
15282.7
TIME
2.20208
3.25912
3.30846
3.3179
3.38285
3.46374
3.85458
11.2051
12.506
15,899
19,6124
26,2494
26,3943
28.2083
28.8792
30.11
30,7864
31,9732
34.857
41.1319
INDEX
***
***
***
***
***
***
#**
***
***
***
***
199,536
202,506
242.288
256.999
283.991
298.825
327.639
397.976
497.974
H-41
-------
i
>u
N>
CO
O
T3
Hi
CT«
i.
it)
U
Wl
T3
C
o
•J
111
Ml
I
OJ
•
X
630@,
5609
4900
4200. -
Sediment C159D (8383)
^_
0.00 6.40
RT in minutes
U/'
12.80
19.20
25.66
32.00
38.40
44.80
SflMPLE: SED 8383 INJECTED fiT 17:49:23 OH SEP 9, 1981
Method: BflY32 Raw: CES15 Proc : *PRC32
Figure H-18. FID/GC chromatogram for sediment sample C159D.
-------
TABLE H-19. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C160D
PROCESSED FILE! *PRC32
RAU FILE: CBS41
SAMPLE NAME:
Sediment C160D (8405)
SEH 8405
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
i
:•>
3
4
7
8
9
10
il
12
13
AREA
119357.
1.59559E+06
6.86348E+07
39286.6
1480.12
8976.94
13252.9
9158.44
22923.7
26691.5
19866.3
1889,41
10346.4
TIME
2.14464
2.22115
2.27083
2.91393
3.45748
3,72778
11.1504
12,4599
19,6036
30.7788
34.8485
37,9479
41.1245
INDEX
***
***
***
***
***
***
***
***
***
298,657
397,769
447,594
497,856
H-43
-------
a
i
c
u
in
•o
o
IJ
8033,
? 7000,
6000 ,
5060
4000.
Sediment C160D (8405)
0.00 6.40
RT in minutes
12.S0
19.20
25.66
32.00
38.40
44.i
SflMPLE: SED 8405 INJECTED OT 4:19:35 ON SEP 11, 1981
Method: BRY32 Raw: CBS41 Proc : *PRC32
Figure H-19. FID/GC chromatogram'for sediment sample C160D.
-------
TABLE H-20. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B126S
PROCESSED FILE: *PRC32
RAW FILE: c&si?
SAMPLE NAME:
Sediment B126S (8384)
SED 8384
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
o
3
A
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
2'
•?
23
26
27
28
AREA
352177.
8.13722E+07
22675.7
409613.
5596.48
3825.66
7182.22
17642,
13046,6
1148.62
30327
5793.62
3294.69
1111,25
16696.9
6627.03
2088.59
1531,59
1544,66
4619,06
5145.28
5567.97
36060,3
1090.83
1232.09
31719.5
20932.9
2781.75
TIME-:
2,13052
2,25
2,87234
3.02784
3.11145
3,54254
3,68472
11.1645
12.476
. 19.4137
. 19.6053
19.8237
20.894
21.151
21.5288
23.1374
23.89C4
24,6559
24.6655
24.7565
26.2587
30.1284
30,7943
31.7244
31.9986
34.8767
41.1837
46.5183
INDEX
***
***
***
***
***
**#
***
**#
***
***
102.178
118.394
122.289
128.012
152.385
1.43.915
175,393
175,538
176.917
199.678
284.394
298.998
321.571
328.258
398.457
498.793
556.663
H-45
-------
EC
^
-------
TABLE H-21. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE B143S
PROCESSED FILE: *PRC32
RAW FILE: C&S25
Sediment B143S (8387)
SAMPLE NAME:
SED 8387
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF3
PEAK*
1
A
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
23
24
25
26
27
AREA
268775.
227057.
8.25621E+07
21280.2
314943.
5650.83
3708.97
6798.06
4252.5
21660.7
15074.1
14988.3
1155.25
1171.75
1437.25
5596,45
7681.69
1527.32
4876.81
1186,87
6669,02
5174.75
37116.5
9859,23
6105,31
5638.67
2635.19
22516,4
TIME
2.10432
2.13316
2.25208
2.96654
3.03786
3.12259
3.55465
3.68333
10.6719
11,1667
12.474
13.2649
13,9379
14,0729
14,7411
15.4414
16.0558
17,174
17.2287
17.5208
18.0047
19.193
19,6064
19.8212
20.7534
21.0291
21.4033
21.5356
INDEX
***
***
***
***
^ ^ ^
***
***
***
***
***
***
***
*#*
**#
***
***
***
***
***
102.139
116.263
120,44
126,111
128.115
H-47
-------
TABLE H-21 (continued)
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
4
4,
48
49
50
51
52
5"
5-,
55
56
57
58
59
60
61
62
63
64
65
66
67
68
2319.55
1946.86
2661
2431,75
3572.75
5918.89
208398.
191230.
239748.
4573.26
7263.05
6596.91
1379,18
9043.41
357993.
7045.98
5797
266824.
32484.4 -
276517.
320240.
408770.
31433.9
35622.7
34102.2
453138.
115445.
6596.24
5023,43
357355.
218700.
259631.
12822.7
32368.3
320392.
19906.6
17353.5
53903,4
12640,6
406016.
21,6238
21.6661
21,7526
21,824
21.9468
22,0809
22,3
22.4475
22.7602
22.9488
22.9892
23.086
23.0988
23.1321
23.3585
23.4824
23.5608
23.832
23.8424
23.9003
24.0593
24.3872
24.4342
24.5785
24,5881
24,9576
24.9656
25.0285
25.0917
25.3011
25.3845
25.5575
25.6405
25,7034
25.8838
25.9967
26.0564
26.1291
26.204
26.4448
129.452
130,093
131.403
132.484
134.345
136,377
139.697
141.932
146.67
149.528
150,14
151,606
151.801
152.304
155,735
157,612
158.799
162.909
163.067
163.943
166,353
171.322
172.034
174.219
174,365
179.964
180.084
181.037
181,995
185.169
186,432
189.053
190.311
191,264
193.996
195.707
196.611
197,713
198,848
203.615
H-48
-------
TABLE H-21 (continued)
69
70
71
72
73
74
75
76
77
7P
7
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
1 »
lx.J
106
149950,
88373.
8726.31
100327.
18971 .4
117789.
19075.3
26433.7
39572.3
8390,39
117460.
2905.52
22318.5
21040,5
27802.5
3934.7
1114.33
25103.9
14124.3
5534.49
24465,6
5738.62
7919.53
11210.1
24337.
2392,72
1043.98
3978.36
1783.05
1195..59
30477.2
1192,12
1575,22
28738.5
1033,42
1520,5
21684.5
6956.44
26.6631
26.7597
26.845
26.9353
27.0644
27.2691
27.3365
27.4763
27.5601
27.6573
27.799
27.8619
27.9424
27,9859
28.0859
28.192
28.2052
28.2735
28.4075
28.5528
28,6051
28.7025
28,8283
28.932
29.1212
29.2107
29.2602
29.4174
29.5713
30.2692
30.7878
32,4191
34,6292
34.8509
35.805
37.0971
41.1443
46.4467
208.401
210.52
212.39
214.37
217.202
221.691
223.168
226.235
228.072
230.205
233.311
234.69
236,456
237,41
239.602
241,93
242.219
243.718
246.656
249.841
250.989
253.124
255.883
258.159
262.307
264.269
265.354
268.802
272,177
287.482
298,855
338.515
392.419
397.826
413.687
434.131
498.169
555,891
H-49
-------
ui
o
• 40000 .
X
•o
*
? 30000 .
ifl
r-*
Ld
I/I
•o
c
8 20000 .
ili
I/I
1
3
* 10000.
U
1-
t— i
IX
Se
-
-
-
1
sdiment B143S (8387)
-
-
•
.
L iU^. . A.M. rl .11 .. . . . JL .A .
i . i , i , i . i . i . i
0.00 2.10
RT in minutes
4.20
6.38
8.40
10.50
12.60
14.70
16.80
SflMPLE: SED 8387 INJECTED flT 4:23:21 ON SEP 10, 1931
Method: BRV32 Raw: CBS25 Proc : *PRC32
Figure H-21. FID/GC chromatogram for sediment sample B143S.
-------
Ul
40090
X
111
£ 30000,
'_
u
Vi
-o
c
S 20000,
Ml
ID
u
Sediment B143S (8387)
JU^^iAjLjLwJ
RT in minutes
18.90
21 .00
23.10
25.20
27.30
29.40
31 .50
33.60
SRMPLE: SED 8387 INJECTED RT 4:23:21 ON SEP 10, 1981
Method: BRY32 Raw: CBS25 Proc : *PRC32
Figure H-21 (continued)
-------
©
m
to
t'J
X
a.
E:
a
40006.
X
Tl
a<
•<-' 30900
in
T3
C
U 20000
10000.
Sediment B143S (8387)
RT in minutes
35.70
37.80 39.90 42.00 44.10 46.20 48.30
SHMPLE: SED 8387 INJECTED FIT 4:23:21 ON SEP 10, 1981
Method: BRY32 Raw: CES25 Proc: *PRC32
50.40
Figure H-21 (continued)
-------
TABLE H-22. RELATIVE RETENTION INDICES FOR SEDIMENT SAMPLE C169S
PROCESSED FILE: *PRC32
KAW FILE:
SAMPLE NAME:
Sediment C169S (8396)
SED 8396
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
1
2
3
4
6
7
8
9
iO
i 1
12
13
14
15
16
17
18
AREA
6340,91
1.10374E+06
6.21491E+07
8156.53
5565.37
2519.87
1016.81
2692.75
23981,
8124.72
7234,31
25669.1
2211.12
1135,,52
1070.46
3909,83
8455,12
3251,98
TIME
2.21029
2,275
2.29583
3,72344
11.1476
12.4675
18.5427
19,4188
19.6104
19.8289
20.8993
21.5361
21,6768
21.8598
22.3023
22,5758
23.1394
23.8223
INDEX
***
***
#*#
*#*
#**
***
***
***
***
102.256
118.475
128.122
130.254
133,027
139,732
143.876
152,416
162.763
H-53
-------
TABLE H-22 (continued)
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
6480.08
1512.94
1371.78
3301.45
6678.45
1628.16
2538.81
6004.19
1059.96
2485.34
1137.27
1095,53
2248.43
1290.16
3077.54
31106,1
1143.94
1170.86
1197,89
9528,28
1504.91
2299.59
28283.9
1174.61
1290.58
2263.27
1146.89
7990.37
4093.37
2739.25
23,8948
24,1087
24.19
24,663
24.7532
25.3034
26.1073
26.2549
27.3102
27.4071
27.484
27,4932
30.4716
30.5561
30,5921
30,7866
31.0652
31,714
33,5613
34,6568
34,743
34,7724
34.8682
35.3825
35.8381
37.1258
37,1402
41.1325
45.3333
46.4646
163.86
167.101
168.333
175.5
176.867
185.202
197.384
199,62
222.592
224.716
226.403
226.604
291.921
293.775
294.564
298.83
305.493
321.318
366.372
393.093
395..195
395.913
398.248
407.001
414.211
434.586
434.813
497.983
543.894
556.084
H-54
-------
® 10000.
a
en
en
o>
C
bj
c
o
•J
<1<
III
I
IS)
T'J
UJ
1=1
-J 4000.
6000
Sediment C169S (8396)
0.08 6.40
RT in minutes
12.80
19.20
25.60
32.00
38.40
44.80
SOMPLE: SED 8396 INJECTED RT 17:37:02 ON SEP 10, 1981
Method: EOY32 Raw: CES31 Proc : *PRC32
Figure H-22. FID/GC chromatogram for sediment sample C169S.
-------
APPENDIX I
TOTAL ION CHROMATOGRAMS FOR PHASE III SEDIMENT SAMPLES
See Appendix D for the identification and quantitation of peaks
1-1
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + S400-SED 9/16/81 BHH
8> BTL*E0 D13448
TI
Sediment A109 (8400)
FRN
1ST SC/PGi 1
X- .35 V- 1.00
Figure 1-1. Chromatogram from the capillary GC/MS analysis of sediment sample A109
-------
i
u>
1 UL
TI
** BrtTCH PROCESSOR RECONSTRUCT ** FRN 13448
150X150 P10 + S400-SED 9x16x81 BMH 1ST SCxPQi 933
)-280(8) BTL*£0 D13-448 . X- .25 V- l.£Q
Sediment A109 (8400)
3
i i
1 4 1< •» (i"
L 11 j^ j^J 1 . 1 1 * ^ A -^ - fir* ^. - ^M^*"^-*'^*
,,,1111 1
1^ i: tl
Figure 1-1 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 •«• 8380-SED (DIL 1110) 9/16/81 BHH
> BTL*8 D13436
FRN 13436
1ST SC/PGl 1
X- .25 V" 1.00
Sediment B112D (8380) DIL l:lo
TI
i
10
Figure 1-2. Chromatogram from the capillary GC/MS analysis of sediment sample B112D.
-------
1 UL 150X150
S0(4)-280(8>
** BHTCH PROCESSOR RECONSTRUCT #*
D10 + 8380-SED (DIL It 10) 9/16x81 BNH
BTL*8 D13436,
FRN 13436
1ST SC/PGt 933
X- .35 Y" 1.00
TI
Sediment B112D (8380) DIL 1:10
15
Figure 1-2 (continued)
-------
** FnTCH PROCESSOR RECONSTRUCT ** .
1 UL 1EO/1S0 Did •»•• 83S0-5ED (DIL It 10) 9/16/81 BflH
50C4J-a80i8) BTL«8 D13436
FRN 13436
1ST SC/PGH865
X- .25 V- 1.00
i
00
TI
1? Sediment B112D (8380) DIL 1:10
10
Figure 1-2 (continued)
-------
** tHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8380-SED (DIL 1*10) 9/16/81 BHH
50C4>-280(3) BTL*8 D13436
FRN 13-436
1ST SC/PGJ2797
X- .25 Y- 1.00
i
vo
TI
Sediment B112D (8380) DIL 1:10
35
Figure 1-2 (continued)
-------
I
I-1
o
** BHTCH PROCESSOR RECONSTRUCT'**
1 UL 150/150 D10 + 8404-SED 9/16x81 BHH
8> BTL*24 D13452
FRh
1ST SC/PGil
X- .85 Y-
TI
Sediment B119D (8404)
Figure 1-3. Chromatogram from the capillary GC/MS analysis of sediment sample B119D.
-------
** trtTCH PROCESSOR FEOOMSTRUCT **
1 UL 150x150 D10 «• S404-SED 9/16/81 BNH
5*>(4 >-230(8> BTL*24
FRN
1ST SC/PGt 933
X' .25 V- l.OO
H
I
TI
Sediment B119D (8404)
I
15
Figure 1-3 (continued)
-------
M
I
H
K)
** fcwTCH PROCESSOR RECONSTRUCT #*
1 UL 150x150 D10 i- 8404-SED 9x16/81 BC1H
(8) BTLS2-4 D13452
1 UL 15(
5tU4 )-£J
TI
.,
1
.
i
FRh 1345a
1ST SC/PGH865
X- .25 Y- l.OO
Sediment B119D (8404)
\
.
L
i
25
Figure 1-3 (continued)
-------
** BfiTCH PROCESSOR RECONSTRUCT
1 UL 150x150 D10 + 8404-SED 9/16/31 BHH
D1345E,
FRN
1ST SC/PG:E797
- .25 V- 1.00
i
M
U)
TI
Sediment B119D (8404)
r
35
Figure 1-3 Ccontinued)
-------
H
I
** BnTCH PROCESSOR RECONSTRUCT
I UL 150x150 D10 + 8393-SED 9/17x81 BMH
8) BTL*8 D13468
TI
Sediment C150D (8393)
L L
1ST SC/PG,: i
V- 1.00
Figure 1-4. Chromatogram from the capillary GC/MS analysis of sediment sample C150D.
-------
•f* B-iT-;.H r'f".
1 UL 150'150 D10 + 8393-SED
50(4 )-c!S£c3 ) BTL»8
EfSOK PEC Of ir.TRUOT 'JfJf
9x17/81 BHH
D13468
FPN 134co
1ST SC/PGt 933
X- .25 V- l.OO
I
M
Ul
TI
Sediment C150D (8393)
i
15
sa
Figure 1-4 (continued)
-------
I
M
0\
1 UL
TI
it
f
*-!
15
Sed
1
K)
Aj
•vES'f.OR RECONSTRUCT
1 UL 150/150 D10 + 8393-SED S/17/81 BNH
I-280CS) BTL*8 . D13468
Sediment C150D (8393)
II
-A
I
25
FFfi 13463
1ST SCXPGU865
» .85 Y" 1.00
LJ
V A Ji
Figure 1-4 (continued)
-------
1 UL 150/150 D10 + 8393-SED
?0<-4)-£SOi8) BTL*8
Eif-OK PECGNf-TFLCT
S/ 17/81 BI1H
013^68
FRN 1
1ST SC/PGsa797
X- .25 V- 1.00
TI
Sediment C150D (8393)
30
rt
I
35
Figure 1-4 (continued)
-------
I
M
00
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8379-SED 9/16/81 BNH
50t4)-280(8> BTL*7 D13-435
TI
Sediment C156D (8379)
_S
FRN 13435
1ST SC/PGi 1
X" .25 V- 1.00
10
Figure 1-5. Chromatogram from the capillary GC/MS analysis of sediment sample C156D.
-------
1 UL 150/150
50(4)-£80<8>
** BHTCH PROCESSOR RECONSTRUCT #*
D10 -i- 8379-SED 9/16x81 BdH
BTL*7 D1343S
FRN 13435
1ST SC/PQi 933
X' .25 v- i.e'o
TI
Sediment C156D (8379)
LJ
is
Figure 1-5 ..(continued)
-------
** tnTCH PROCESSOR RECONSTRUCT ##
1 UL 150/150 D10 + 8379-SED 9x16/81 BMH
5< BTL*7 D13435
FRH 13-435
1ST SC/PGU865
• .25 V- 1.00
H
I
to
O
TI
Sediment C156D (8379)
SSL
Figure 1-5 (continued)
/O
I
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8379-SED 9x16/81 BHH
8> BTL*7 D13435
FPN 13435
1ST SC/PG»a797
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I
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Sediment C156D (8379)
I Si
i
35
Figure 1-5 (continued)
-------
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** BATCH PROCESSOR RECONSTRUCT **
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8) BTLt23 D13451
FRN 13-451
1ST SC/PGi 1
X- «£5 Y- l.C»0
TI
Sediment C157D (8403)
i
Figure 1-6. Chromatogram from the capillary GC/MS analysis of sediment sample C157D.
-------
** BHTCH PROCESSOR RECONSTRUCT
1 UL 150/150 D10 + 84S3-SED 9/16/31 BMH
) BTL*23 D13451
TI
Sediment C157D (8403)
\
15
FRN 13451
1ST SO/PG» 933
X- .35 V- 1.00
Figure 1-6 (continued)
-------
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I
to
** FnTCH PROCESSOR RECONSTRUCT *#
1 UL 15e>''150 D10 t 8403-SED 9x16x81 BHH
(S) BTL«S3 D13451
1 UL ISk
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—
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I
Sediment C157D (8403)
\\'
FRIS 13-451
1ST SC/-PGU865
X" .85 Y- 1.00
Figure 1-6 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT
1 UL 150/150 D10 + 3403-SED 9/16/81 BHH
-n-eS0C8> BTL*23 D13451
FRN :
1ST SO/PG:a797
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H
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Sediment C157D (8403)
30
!
35
Figure 1-6 (continued)
-------
I
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** BATCH PROCESSOR RECONSTRUCT **
1 UL 150X150 DIO + 8377-SED 9/15x81 BHH
8> BTL*4 D13433
FPN 13433
1ST SCxPGJ 1
- ,35 V- 1.00
TI
Sediment C161D (8377)
Figure 1-7. Chromatogram from the capillary GC/MS analysis of sediment sample C161D.
-------
•M: fcATCH PROCESSOR RECONSTRUCT
.1 UL 150/150 D10 + 8377-SED 9/15/81 BNH
E=0(4)-230(3) BTLf4 D1343E
FPN 13432
ISt SC/PGi 933
X" .35 V- 1
H
TI
Sediment C161D (8377)
15
._ i?^
Figure 1-7 (continued)
-------
H
I
M
00
*l: BATCH PROCESSOR RECONSTRUCT **
1 UL 150X150 D10 + 8377-SED 9x15/31 BHH
5014)-2SO(3> BTL*4 D13433
TI
Sediment C161D (8377)
25
FPN 13433
1ST SCXPG»1S65
> .25 Y" 1.00 !
L
Figure 1-7 (continued)
-------
*t. FHTCH PROCESSOR RECONSTRUCT #*
1 UL 1?0/150 D10 + 8377-SED 9/15/81 BHH
50(4)-3S0C8> BTL*4 D13432
FRN 13433
1ST SC/PG:E797
X- .35 V- 1.00
Sediment C161D (8377)
i
NJ
VO
TI
35
Figure 1-7 (continued)
-------
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I
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** BATCH PROCESSOR RECONSTRUCT **
1 UL 150x150 D10 + S407-SED 9/16/81 BNH
50(4)-ES0(8> BTL*27
FRM
1ST SC/PGi
» .35 V-
TI
Sediment C164D (8407)
T
Figure 1-8. Chromatogram from the capillary GC/MS analysis of sediment sample C164D.
-------
** tHTCH PROCESSOR RECONSTRUCT **
FRN 13455
I
Ul
1 UL
TI
150/150 D10 + S407-SED 9/16/81 BHH 1ST SC/PQt 933
)-£80(8) BTLt27 D13455 , X- .£5 Y- 1.00
Sediment C164D (8407)
«^
-
j
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Figure 1-8 (continued)
-------
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TT
** BHTCH PROCESSOR RECONSTRUCT ** FRN 13455
150/150 D10 + 8407-SED 9/'16/31 BHH 1ST SC/PG:1865
>-E80(8> BTL*27 D13455 ><• '.25 V- 1.00
^j Sediment C164D (8407)
6>
.
1
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1 l l I 1 I 1 1 1
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Figure 1-8 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + S407-SED 9/16/81 BFIH
5O(-4)-280<8) BTL*27 D13455 ,
FRN 1.3455
1ST SC/PGJ2797
X- .25 V" 1.00
i
to
to
TI
Sediment C164D (8407)
Figure 1-8 (continued)
-------
H
I
** BHTCH PROCESSOR RECONSTRUCT
1 UL 150x150 D10 + 8385-SED 9/17/81 BI1H
8) BTLtS D13465
FRI-< 1
1ST SO/PC,: 1
• .£5 Y- l.OO
TI
Sediment B141S (8385)
r
Figure 1-9. Chromatogram from the capillary GC/MS analysis of sediment sample B141S,
-------
I
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Ul
** BhiTCM PFO'.. Ei'f-OR RE.CONSTRUCT
1 UL 150x150 D10 + 8385-SED 9/17/81 BI1H
50(4J-£SO(8) BTL^S D13465
TI
Sediment B141S (8385)
FPN 134G5
1ST SC/PGJ S33
X" .25 Y- 1.00
Figure 1-9 (continued)
-------
H
I
** FhTCH PROCESSOR RECONSTRUCT
1 UL 150x150 D10 + 8385-SED 9/17/81 BMH
0(8) BTL*5 D13465
1 UL
50 ( 4
TI
. 3
)•
1
Jt
w^m
Sediment B141S (8385)
;i
FP.N 134S5
1ST SC/PG»1S65
X- .S5 V- 1.00
Figure 1-9 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8385-SED 9/17/81 BI1H
8) BTL«5 D13465
Sediment B141S (8385)
i
to
TI
FRN 1346S
1ST SC/PCi*a797
X- .25 V- 1.00
Figure 1-9 (continued)
-------
I
OJ
00
** BHTCH PROCESSOR RECONSTRUCT
1 UL 150/150 D10 + 8386-SED 9x17x81 BMH
8> BTL*6 D13466
TI
Sediment B142S (8386)
13-466
1ST SCxPGJ 1
X- .£5 V" 1.00
Figure 1-10. Chromatogram from the capillary GC/MS analysis of sediment sample B142S,
-------
i
CO
#.* Si-iTCH PROCciSfGR RECONSTRUCT
1 UL 150/ISO D10 + 8386-SED 9/17x81 BNH
8) BTLtS
TI
Sediment B142S (8386)
o
.1.
10
FPN 134S6
1ST SC/PGi 933
X- ,35 V- 1.00
r
Figure 1-10 (continued)
-------
** EnTOH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8386-SED 3x17x81 Bf1H
S> BTL*6 D13466
FRN 13466
1ST SC/PG:1865
- .25 V- 1.00
i
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TI
Sediment B142S (8386)
Figure 1-10 (continued)
-------
** BATCH PROCESSOR RE COM STRUCT ##
1 UL 150/150 D10 + 8386-SED 9x17x81 BMH
8) BTL*6 D13466
FRD 13466
1ST SC/PGJ2797
' .25 V- 1.00
Sediment B142S (8386)
32-
Figure 1-10 (continued)
-------
to
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + S406-SED 9/16/81 BHH
8> BTL*26 D1345-4
FRM
1ST SC/PG* i
X- .25 Y" 1.00
TI
Sediment A101 (8406)
_S
Figure 1-11. Chromatogram from the capillary GC/MS analysis of sediment sample A101,
-------
I
>Cv
Ul
1 UL
SO (4
TI
** fcHTCH PROCtSrGfc RECONSTRUCT .*# FRM 13454
150/150 D10 + 8406-SED 9/16/81 BMH 1ST SC/PGs 933
)~280(8) BTL«26 D13454 / X- .25 V- LOG
Sediment A101 (8406)
>
11
5
• 4 ^ '
him - — • - •• . 4«. A
-•
16 30
Figure 1-11 (continued)
-------
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1 UL
TI
** BHTCH PROCESSOR RECONSTRUCT ** FRN 13454
. 150/150 D10 -i- 8406-SED 9x16/81 BNH 1ST SCxpQ»1865
)-280<8) BTL*26 D13454 *• .35 V- 1.00
i
1 Sediment A101 (8406)
Li q K>
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i
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A A
3
ss
Figure 1-11 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 •»• 8406-SED 9/16/81 BNH
8) BTLf26 D13454 /
FRN
1ST SC/PG5E797
X- .S5 V- 1.00
un
TI
Sediment A101 (8406)
II
A.
Figure 1-11 (continued)
-------
X* EHTCH PROCESSOR RECONSTRUCT **
1 UL 150X150 D10 + 8401-SED 9x16/81 BMH
5<2K4>-E80(8> BTL*21 D134-49
TI
Sediment B113D (8401)
i
5
FPN
1ST SC/PGt 1 >
X- .25 Y- 1.00
Figure 1-12. Chromatogram from the capillary GC/MS analysis of sediment sample B113D.
-------
1 UL
50(4
TI
*X BHTCH PROCESSOR RECONSTRUCT ** FRN 13449
1E0X150 D10 + 8401-SED 9X16X81 BHH 1ST SC/PG» 933
)-E3tf(8) BTLS21 D13449 X' .25 V- 1.00
Sediment B113D (8401)
i
3
&
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I
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i i i i i i i i (j
Figure 1-12 (continued)
-------
H
I
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00
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TI
3
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** BHTCH FRCCE^SOR RECONSTRUCT ** FRN 13449
L50/1S0 D10 + B401-SED 9/16/81 BHH 1ST SCxPG»1865
-B80<8) BTLtSl D13449 , X- .85 V- 1.00
j'0 Sediment B113D (8401)
IV fi & H
LA~ - A U A A-
1
1
1 V A
II I l I I I I 1
£5
Figure 1-12 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 84
-------
H
I
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150x150 D10 + 840S-SED 9/16/81 BMH
50(4)-E80(8) BTL*E2 D13450,
TI
Sediment B124D (8402)
S.
F.RN 13450
1ST SC/PG* 1
X" .35 Y- 1.00
Figure 1-13. Chromatogram from the capillary GC/MS analysis of sediment sample B124D.
-------
H
I
tn
*X EHTCH PROCESSOR RECONSTRUCT #* FRN 1345O
1 UL 150/150 D10 + 84<2)2-SED 9/16/81 BHH 1ST SC/PGi 933 \
50(4)~280(8) BTL*2E D13450. X- .25 V- 1.00
TI
Sediment B124D (8402)
i
o
6
* 1 i ^
^ A A A A
i i i > i i i i i
15 2&
Figure 1-13 (continued)
-------
1 UL
** BHTCH PROCESSOR RECONSTRUCT **
D10 -i- 84
-------
** SHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 i- S4
-------
I
Ul
** FHTCH PPC'C£Si>OR KtXUhrTRUOT
1 UL 150/150 D10 + 8395-SED 9/17/81 BHH
J) BTL*11 D13471
TI
Sediment C151D (8395)
i
1
T
FRh 12-i-71
1ST SC/PGJ
X- .E5 V" 1.00
Figure 1-14. Chromatogram from the capillary GC/MS analysis of sediment sample C151D.
-------
** S'HTGH PR
I UL. 150/150 D10 + 8395-SED
50i.-4)-3SO(8) BTLtll
RECONSTRUCT
.9/17/81 BF1H
D13471
1ST SC/PG: 333
X- ,BS V- 1.00
TI
Sediment C151D (8395)
Figure 1-14 (continued)
-------
1 UL
* * t M •" '•; M r & o < : E: 9 ^ c R P E c o i -\ £> T R u c T
D10 -»• 8395-SED 9x17/81 BUM
BTL»11 D13471
FPN 13-171
1ST S^/PG:1S65
X* .55 V- 1.00
i
Ol
o>
TI
Sediment C151D (8395)
as
Figure 1-14 (continued)
-------
*+. E'hTCh PRO'". cSiOK RECU(£>TRUCT
1 UL 150/150 D10 + 8395-SED 9/.17/81 BHH
50>.4 j-£8ianS) BTL*11 D13471
FPH 1
1ST SC/PGI2797
X- .25 Y- 1.00 j
i
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TI
Sediment C151D (8395)
Figure 1-14 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT *#
en
oo
1 UL 150X150 D10 f 8382-SED 9x16x81 BMH . 1ST SCx
S
-------
#.* BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8382-SED 9/16/81 BMH
50(4)-280(8) BTL*10 D13438-
FRM 13433
1ST SC/PGi 933
X- .25 V- 1.00
Sediment C153D (8382)
Figure 1-15 (continued)
-------
i
cr>
o
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150''150 D10 + 8383-SED 9x16x81 BHH
) BTL*10 D13438
TI
Sediment C153D (8382)
ID
I
\y
>*//U^/VA*^A>A~A*/Jb
FRN 13438
1ST SC/PGH865 '
X" .25 Y- 1.00
Figure 1-15 (continued)
-------
.** BftTCM PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8382-SED 9/16/81 BHH
50C4)-S80C8) BTLtlO D13438
FRN 13-438
1ST SC/PG:2?97
X- .25 V- 1.00
Sediment C153D (8382)
TI
f)(t
I
35
Figure 1-15 (continued)
-------
a\
** BftTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8381-SED (DIL 1*3) 9/16/81 BNH
5-280(8> BTL*9 D13437,
FRN 13437
1ST SC/PG» 1
X" .25 Y- l
TI
Sediment C154D (8381) DIL 1:2
t
Figure 1-16. Chromatogram from the capillary GC/MS analysis of sediment sample C154D,
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/1S0 D10 + 8381-SED (DIL H2) 9/16/81 BHH
FRN 13437
1ST SC/PGi 933
X- .25 Y" 1.00
CT>
U>
TI
Sediment C154D (8381) DIL 1:2
15
Figure 1-16 (continued)
-------
** BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8381-SED (OIL 1»2) 9x16/81 BMH
5*H4)-ES0(8> BTL»S D13437
FRN 13437
1ST SC/PGU865
* .25 V- 1.00
TI
Sediment C154D (8381) OIL 1:2
tf
i r
25
T I T
30
Figure 1-16 (continued)
-------
** BnTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8381-SED (DIL H3) 9/16/81 BP1H
S0C4)-280(8) BTL*9 D13437,
FRh 13437
1ST SC/PG:a797
X- .25 V- l
I
CT>
O1
TI
Sediment C154D (8381) DIL 1:2
•^
35
Figure 1-16 (continued)
-40
-------
I
(Ti
** BnTCH PROCESSOR h:E'" OH:TRU'"T
1 UL 150x150 D10 1- 8394-SED 9/17/81 BHH
D13470
FRN 13-470
1ST SC/PGi 1
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TI
Sediment C158D (8394)
T
ie
Figure 1-17. Chromatogram from the capillary GC/MS analysis of sediment sample C158D.
-------
1 UL
50 M
TI
** BHTCH PROCESSOR RECONSTRUCT ## FRN 134 <9
150x150 D10 * 839^-SED 9/17/81 BHH 1ST SC/PG: 933
>-2S*H8) BTL*10 D13470, ><• .25 V- 1.00
Sediment C158D (8394)
/
I
\
i
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6.
1 i
i i i i i i i i i
IB :?0
Figure 1-17 (continued)
-------
1 UL 150-150 D10 + 8394-SED
50^-n-£S0cS) BTL*10
9x17x81 BI1H
D13470
FRN
1ST SCxPG:lS65
X- .25 V l.OO
i
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^Sediment C158D (8394)
/I
Figure 1-17 (continued)
-------
1 UL 150/150 D10 + 8394-SED
) BTL*10
PECC'hi-TRUCT
S/' 17/81 BI1H
D13470
FRO 13470
1ST SC/PGJ3797
X- .£5 V- 1.00
i
cr>
vo
TI
Sediment C158D (8394)
35
Figure 1-17 (continued)
-------
** BrtTCH PROCESSOR RECONSTRUCT ** FRN 13439
1 UL 150
TI
Sediment C159D (8383)
f
\
. IL .ju«
k
3
A
* i i i r1 r
id
Figure 1-18. Chromatogram from the capillary GC/MS analysis of sediment sample C159D.
-------
** BHT:H PROCESSOR RECONSTRUCT #* FRN 13439
1 UL 150/150 D10 + 8383-SED 9/16/81 BMH 1ST SC/PGi 933
5
-------
** E-HTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 t- 3383-SED 9/16/81 BNH
) BTLtll D13439
FRh 13439
1ST SC/PGJ1865
X- .35 Y- 1.00
i
*0
is;
Figure 1-18 (continued)
-------
*.* BHTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8383-SED 9/16/81 BHH
50k4)-280(8) BTLtll D13439
FRN 13439
1ST SC/PG«2797
X- .25 V- 1.00
Sediment C159D (8383)
TI
35
<40
Figure 1-18 (continued)
-------
H
I
** BATCH PROCESSOR RECONSTRUCT **
1 UL 150x150 D10 + 8405-SED 9x16x81 BP1H
5*(4>-£80<8> BTL*25 D13-453 ,
FRN 134S3
1ST SCxPGi 1
- .35 V- 1.00
TI
Sediment C160D (8405)
r
Figure 1-19. Chromatogram from the capillary GC/MS analysis of sediment sample C160D.
-------
I *Y t'HTCH PROCESSOR RECONSTRUCT :**
1 UL 150/150 D10 + 8405-SED 9/16/81 BP1H
8) BTL*25 D13453 ,
FRN 13*»53
1ST SC/PGt 933
X- .35 Y- 1.00
i
^j
U1
TI
Sediment C160D (8405)
ae.
Figure 1-19 (continued)
-------
** BhTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 P10 + 8405-SED 9/16/81 BNH
) BTL»25
FRN 13453
1ST SC/PGJ1865
X- .25 V- 1.
H
I
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cn
TI
Sediment C160D (8405)
A. X
.25-
Figure 1-19 (continued)
-------
** BrtTCH PROCESSOR RECONSTRUCT **
1 UL 150/-150 D10 + S405-SED 9x16/81 BC1H
50(-»)-£80<8) BTL«25 D13453
FRN 13-»S3
1ST SCXPGJ3797
X- .85 Y- 1.00
Sediment C160D (8405)
TI
30
3B
Figure 1-19 (continued)
-------
H
I
^1
CD
** BMTCH PROCESSOR RECONSTRUCT
1 UL'150x150 Did + 838-4-SED (DIL 1«2) 9/17x31 BNH
FRM 13
1ST SC/PGt 1
X' .as v- i.oo
TI
Sediment B126S (8384) DIL 1:2
i
I
Figure 1-20. Chromatogram from the capillary GC/MS analysis of sediment sample B126S,
-------
i
^i
VD
** BnTCH PR'iXE££OR RECONSTRUCT .•»:-*: FRN 13-46-4
1 UL
TI
150^150 D10 + 8384-SED ^DIL U2J 9x17/81 BNH 1ST 5C/PC.t 933
)-£S0(S9 BTL«4 D1346^ X- .25 Y- l.OO j
Sediment B126S (8384) OIL 1:2 *?
3 ,
|
i ...,..-.. T J
( • 1)
I I ^^JL-^J-^— J*-*-^
III III
15 -ii
Figure 1-20 (continued)
-------
E£:f>OK RECONi-TPUCT .**
1 UL 150/150 D10 + S3&4-SED (DIL H2) 9^17/81 BI'IH
5tH-O-E80<89 BTLS-» D13464
FRN 13-464
1ST SC/PGJ1865
X- .85 V- 1.00
i
00
o
TI
Sediment B126S (8384) DIL V.2
10
^U~-~'^^
Figure 1-20 (continued)
...30 _.J
-------
** fcHTC'H PROCESSOR RECONSTRUCT #*
1 UL 150/150 D10 + 8384-SED (DIL 1»2) 9/17x81 BNH
FRN 13464
1ST SC/PG>3797
- .25 V- 1.00
i
00
TI
Sediment B126S (8384) DIL 1:2
I
35
Figure 1-20 (continued)
I
40
-------
I
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** BnTCH PROCESSOR RECONSTRUCT **
1 UL 150/150 DBTL*7 D13467
TI
Sediment B143S (8387) OIL 1:5
I
H
I
5
FPt-< 13467
1ST SC/PG: 1
X" .25 Y- 1.00
Figure 1-21. Chromatogram from the capillary GC/MS analysis of sediment sample B143S,
-------
I
00
u>
1 UL
TI
** BHTCH PRO'.: es^uR RECONSTRUCT ** • FRN 13467
1ST SC/PGI 933
15£/150 DBTL*7 D13467, X- .BS Y- 1.00 !
Sediment B143S (8387) OIL 1:5
'i
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Figure 1-21 (continued)
-------
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1 UL
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1ST SCxPG:i865
150X150 DBTL*7 - D13467 X- .25 Y- 1.00
Sediment B143S (8387) OIL 1:5
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Figure 1-21 (continued)
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* Fi-iTCM PROCESSOR RECONSTRUCT XX
FRN 1346?
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1ST SC/PGJ2797
1 UL 150/150 DBTLS7 D13467 X- .25 V- 1.00
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Figure 1-21 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL 150/150 D10 + 8396-SED (DIL U2) 9/85/81 BP1H
50<4)-280<8> BTL*3 D13518
FRN 13518
1ST SC/PGJ1865
X- .25 V- 1.00
i
00
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TI
Sediment C169S (8396) DIL 1:2
25
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Figure 1-22 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT **
1 UL ISO/150 D10 + 8396-SED (DIL 1»2) 9/25/81 BNH
S0C4>-280<8> BTL*3 D13518
FRN 13518
1ST SC/PGJ2797
X- .25 Y- 1.00
00
vo
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Sediment C169S (8396) DIL 1:2
Figure 1-22 (continued)
-------
APPENDIX J
ANALYSIS OF BLANKS AND STANDARDS ASSOCIATED WITH
THE ANALYSIS OF PLANT EFFLUENTS AND SEDIMENTS
In addition to the standards analyses shown and discussed in
Section C.ll, a number of standards required analysis in order to:
(1) insure no instrument contamination of extracts being analyzed,
(2) calibrate the capillary GC/FID response for the determination
of TCO and TCG values, (3) calibrate the retention time axis to
calculate relative retention indices (RRI) from both GC/FID and
GC/MS data, and (4) insure that no contamination of extracts was
due to sample manipulation and handling. Figures J-l and J-2 (all
figures and tables will appear following the text of Appendix J)
show the capillary GC/FID and capillary GC/MS analyses of Burdick
and Jackson methylene chloride used for solvent/solvent extraction
of the plant effluents. Note that the mass spectral analysis in-
cludes the co-injection of 50 ng anthracene-d10 used as an inter-
nal standard for all mass spectral analyses. Figure J-3 shows the
capillary GC/FID analysis of a standard containing C7-alkane and
C17-alkane which were used to determine the retention time ranges
for the summation of FID intensities to calculate TCO and TCG
values. Figure J-4 shows the hydrocarbon standard containing C8-,
Ci2~' cis-/ C20~/ an<* C24~alkanes used to calibrate the FID re-
sponse for calculation of TCO and TCG values.
Figures J-5 and J-6 show FID and MS analyses of the spiking
standard used for the calculation of recoveries of deuterated
compounds added to the 10-L water sample or 30-g sediment sample
before methylene chloride extraction. The chromatograms shown
in Figures J-7 and J-8 show the analysis of the PNA marker com-
pounds used to externally calculate relative retention indices of
all components identified from the FID or total ion chromatogram.
J-l
-------
This standard was analyzed each time capillary GC/FID and capillary
GC/MS analyses were performed on effluent and sediment extracts.
The last group of analyses demonstrate the potential contamina-
tion in effluent and sediment extracts that may be introduced as
a result of the liquid/liquid or Soxhlet extraction of samples.
Figures J-9 and J-10 show capillary GC/FID and capillary GC/MS
chromatograms from the analysis of the base/neutral extractables
method blank. Figures J-ll and J-12 show similar analyses of the
acid extractables method blank. Tables J-l through J-4 show the
relative retention indices and the mass spectral identifications
of the major components present in these two method blanks. While
the base/neutral method blank contains only those deuterated spik-
ing compounds which were added to deterine recoveries of these
materials, the acid extractables method blank includes a very large
impurity of a common plasticizer (dioctyl ester of hexadecanoic acid)
This component and other plasticizers present in the acid extract-
ables method blank were present only in the acid extracts of efflu-
ents from plants B111D, C151D, C150D, and C161D. (The last effluent
acid extract contained only a very minor amount of the dioctyl
ester of hexadecanoic acid.)
In order to estimate the types of contaminants that may be intro-
duced in the freeze-drying process, 30 g of distilled water was
spiked with 1 mL of the deuterated spiking compounds used in the
liquid/liquid extraction of effluents and the Soxhlet extraction
of freeze-dried sediment samples. This resulting spiked water
sample was freeze-dried following the same procedures as were
used for the freeze-drying of sediment samples. Figures J-13 and
J-14 show chromatograms from the GC/FID and GC/MS analyses of a
quantitative transfer of the freeze-dried residue of the spiked
water sample. Tables J-5 and J-6 show relative retention indices
and recovery data, respectively, obtained from the data shown in
the latter two figures. Note that using spiked water is a worst
J-2
-------
case for the determination of retention of deuterated spiking com-
pounds by a typical sediment sample. However, this analysis does
show that the broad, unresolved component present in all sediment
extracts is not introduced in the freeze-drying process. The loss
of compounds with volatilities greater than pyrene is not due to
the liquid chromatographic fraction of the sediment extracts since
recoveries greater than 50% were measured for all deuterated
spiking compounds when a spiked 10-mL methylene chloride sample
was treated similar to sediment sample extracts.
J-3
-------
•3
S
'% 10000.
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i i . i . i , i . i . i
0.00
R T i n m i n u t e s
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12.80
19.20
25.60
44.80
SfiMPLE: CH2CL2 INJECTED flT 16:32:26 ON SEP 8, 1981
Method: EOY32 Raw: CES5 Proc : *PRC32 •
Figure J-l. Capillary GC/FID analysis of methylene chloride solvent blank.
-------
** SPECTRUM DISPLAY/EDIT ** FRN 13461
1 UL ISO/150 DlO + CH2CL2 (BLANK) 9/17/811ST SC/PG• 1
BNH 50<4)-280
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RT in minutes
6.40
12.;
?S.l
32.00
SfiMPLE: CE SPK INJECTED flT 17:64:23 OH fiUG 26, 1981
Method: BBY32 Raw: BOVD8 Proc : *PRC32
Figure J-5.
Capillary GC/FID analysis of a 100 pg/mL composite
spiking solution used to determine the efficiency of
the liquid-liquid extraction of the water effluent
and the Soxhlet extraction of the sediment samples.
-------
** SPECTRUN DISPLAY/EDIT **
1 UL 150/150 D10 -»• SED. SP<. SOLN 8384-96 (DIL 1
9/17X81 BHH BTL*13 D13473
FRN 13473
20) 1ST SC/PG- 1
X- .35 V- 1.00
Cj
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r-j
Figure J-6
Total ion chromatogram obtained from the capillary GC/MS analysis
of a 100 pg/L spiking solution used to determine the efficiency of
the liquid-liquid extraction of the composite water effluent
sample and the Soxhlet extraction of sediment samples.
-------
** SPECTRUM DISPLAY/EDIT ** FRN 13473
1 UL 150/150 D10 «• SED. SPK . SOLN 8384-96
-------
** SPECTRUn DISPLAY/EDIT ** FRN 13473
1 UL 150/150 D10 + SED. SPK . SOLN 8384-96 (DIL 1-20) 1ST SC/PG-1852
9/17/81 BP1H BTL*13 D13473 X- .35 V- 1.00
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Figure J-6 (continued)
-------
** SPECTRUM DISPLAY/EDIT **
1 UL 150/150 D10 + SED. SPK. SOLN 8384-96 (DIL 1
9X17X81 BflH BTL*13 D13473
FRN 13473
20) 1ST SCXPO-2778
X' .25 V- 1.00
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UJ
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35
Figure J-6 (continued)
-------
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0 . 00
RT in minutes
6.40
19.20
25.66
32.89
38.40
12.80
SfiMPLE: PHfi INJECTED fit 10:46:44 ON SEP 8, 1981
Method: BOY32 Raw: CES2 Proc: *PRC32
44.80
Figure J-7.
Capillary GC/FID chromatogram of PNA standard used to
determine relative retention indices of chroraatographable
compounds present in effluent and sediment extracts.
-------
C-l
M
00
XX SPECTRUM DISPLftV/EDIT XX FRN 13-475
1 UL 150/150 D10 + PNA MARKERS (CLH-O33181-01 *1 > 1ST SC/PG-1197
9/17/81 BMH BTLS15 D13475 X- .25 V- 1.00
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1 UL 150/150 D10 + PNrt MARKERS (CLH-033181-01 »1 > 1ST SC/PG-2125
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Figure J-8 (continued)
-------
X* SPECTRUM DISPUWXEDIT X*
1 UL 150X150 D10 + PNA MARKERS CCLH-033181-O1
9/17x81 BHH BTL915 D13-475
FRM 13475
1ST SCXPG'3054
X- .35 Y" 1.00
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Figure J-8 (continued)
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_,
-
-
J
•, . .1 „ . . L
1 ' 1 * 1 *
.
-
'
-
,
0.00 6.40
RT in minutes
12.80
19.20
25.60
32.00
33.40
44.80
SflMPLE: ENP3 8182 INJECTED RT 1:22:51 OH RUG 10, 1981
Method: BflYll Raw: BRY55 Proc : *PRC11
Figure J-9. Capillary GC/FID analysis of base/neutral extractable method blank.
-------
C-l
N)
** BATCH PROCESSOR RECONSTRUCT ** FRN 13119
1 UL. 125X125 D10 + 8182-BNP3 (METHOD BLANK) 8x13x81 BMH1ST SCxPGi 1
50(4>-280<8> BTL*6 D13119 X' .25 V- 1.00
TI
Effluent Method Blank (8182-Base/Neutral)
Figure J-10. Capillary GC/MS analysis of base/neutral extractables method blank.
-------
** BATCH PROCESSOR RECONSTRUCT ** FRN 13119
1 UL 125/125 D1C + 8182-BNP3 (flETHOD BLANK) 8x13/81 BHH1ST SC/PGt 933
50<4)-280(8> BTL*6 D13119 X" .25 V- 1.00
to
U)
TI
Effluent Method Blank (8182-Base/Neutral)
'
J.5
J2SL
Figure J-10 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT ** FRN 13119
1 UL 125X125 D10 + 8182-BNP3 (METHOD BLANK) 8x13x81 BP1H1ST SCxpQ*1865
50(45-280(8) BTL*6 D13119 *• .25 V- 1.00
(-4
I
to
TI
Effluent Method Blank (8182-Base/Neutral)
£
Figure J-10 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT ** FRM 13119
1 UL 125/125 D10 •»• 8182-BNP3 (METHOD BLANK) 8/13/81 BP1H1ST SC/PG»2797
50<4>-280<8> BTL*6 D13119 X- .25 V- 1.00
to
tn
TI
Effluent Method Blank (8182-Base/Neutral)
Figure J-10 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT ** FRN 13119
1 UL 125/135 D10 + 8182-BNP3 (HETHOD BLANK) 8/13/81 BHH1ST SC/PGI3729
SO(4)-280<8> BTL*6 D13119 X- .25 Y- 1.00
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Effluent Method Blank (8182-Base/Neutral)
Figure J-10 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT ** FRN 13119
1 UL 125/125 Die + 8182-BNP3 (NETHOD BLANK) 8/13/81 BHH1ST SC/PGH661
SCK4)-280<8> BTL*6 D13119 X- .25 V- 1.00
Effluent Method Blank (8182-Base/Neutral)
C-,
i
TI
Figure J-10 (continued)
-------
TABLE J-l.
RELATIVE RETENTION INDICES CALCULATED FROM CAPILLARY
GC/FID ANALYSIS OF BASE/NEUTRAL EXTRACTABLE METHOD
BLANK SHOWN IN FIGURE J-9.
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
DUCK
BAY55
Effluent Method Blank (8182-Base/Neutral)
BNP3 81Q2
RELATIVE RETENTION VALUES
OUTPUT FILE: OPF2
PEAK*
1
4
5
6
7
8
9
10
AREA
21630.5
7
246692.
11625.3
111007.
32282.2
53139.2
56226.6
26793
5852.75
TIME
2.081
2 *:!.£} 125
2.75327
3.46934
3.52884
12.2459
19.388-4
30.51
34.5193
40*5205
INDEX
*##
***
###
***
***
299.118
393.021
497.537
J-28
-------
TABLE J-2.
MASS SPECTRAL IDENTIFICATION OF MAJOR COMPONENTS IN THE
BASE/NEUTRAL EXTRACTABLES METHOD BLANK SHOWN IN FIGURE J-10.
i
N)
vO
Peak
No.
3
1
2
4
5
6
Retention
time ,
min
7.65
14.77
25.22
29.03
33.05
Compound
Internal standard
Anthracene-djo
Recovery standard '
1 ,2-Dichlorobenzene-d4
Biphenyl-d10
Pyrene-d10
Chrysene-d12
Perylene-d12
Organics detected
None detected
Peak area,
total counts
167,912
215,895
258,677
178,348
74,747
29,947
Amount
detected,
|jg/L
100
94.6
91.3
102
73.4
46.9
Amount
spiked,
pg/L
-
118.1
101.6
99.3
85.8
90.6
Recovery,
percent
-
80.1
89.9
102.7
85.5
51.8
Includes all substances that were found at or above a 3% threshold on the BATCH peak identifi-
cation program in the Hewlett-Packard system and are greater than 1.0 pg/L relative to the
anthracene-d10 internal standard.
Anthracene-d10 internal standard added immediately prior to analysis; 50 mg/L injected equivalent
to 100 |jg/L in original sample.
^
"Deuterated recovery standard (spike), added to original effluent before extraction.
Quantitated relative to area of major ion for authentic standard.
-------
TABLE J-3.
RELATIVE RETENTION INDICES CALCULATED FROM
CAPILLARY GC/FID ANALYSIS OF ACID EXTRACT-
ABLES METHOD BLANK SHOWN IN FIGURE J-ll.
PROCESSED FILE: *PRCII
FILE: BAY?
SAMPLE NAME:
Effluent Method Blank (8182-Acid)
ANP3 8182
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFI
PEAK*
6
7
8
9
10
11
12
13
AREA
75042.7
5.34174E+07
95870.
15534.5
66845.9
2978,37
1360.87
2366,53
1449.5
5032.31
2220,89
4349.09
1949.12
TIME
2.13093
2.23125
3,56955
10,9323
33,3729
34,508
34,8883
35,0637
35.4073
35,551
36.0917
36,3
40,5427
INDEX
***
###
#*#
369
397
404
407
412
415
424
427
497
.284
,242
.406
.286
.928
.288
.165
.586
,253
J-30
-------
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X 10000.
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> . — _ i-
i • i
•
•
-
-
.JLJ/U . ,
i . i . i . i . i i i i i
0.00
RT in minutes
6.40
12.80
19.20
25.60
32.00
38.40
SRMPLE: RNP3 8182 INJECTED RT 23:02:50 OH RUG 6, 1981
Method: BfiYll Raw: ERV7 Proc : *PRC11
Figure j-ll. Capillary GC/FID analysis of acid extractables method blank,
-------
** BATCH PROCESSOR RECONSTRUCT ** FRM 12092
1 UL 100/100 D10 + 8182 ANP3 (METHOD BLANK) 8X13x81 BMHlST SCxPGi 1
SO(4>-280<8> BTL*3 D13092 X- .25 Y- 1.00
i
CO
K)
TI
Effluent Method Blank (8182-Acid)
10
Figure J-12. Capillary GC/MS analysis of acid extractables method blank.
-------
i
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U)
** BATCH PROCESSOR RECONSTRUCT ** FRN 13C92
1 UL 100x100 D10 + 8182 ANP3 (NETHOD BLANK) 8/12/81 BMH1ST SCXPQt 933
50(4>-280<8> BTL«3 D13092 X" .25 V- l.OO
TI
Effluent Method Blank (8182-Acid)
15
Figure J-12 (continued)
-------
Q
10
1 UL
TI
** BATCH PROCESSOR RECONSTRUCT ** FRM 13092
100/100 D10 + 8183 ANP3 CP1ETHOD BLftNIO 8/13/81 BHH1ST SC/PGU865
)-380<8) BTL*3 D13093 X" .35 V- 1,00
Effluent Method Blank (8182-Acid)
1
I d .J
1 1 1 1 II II
85
Figure J-12 (continued)
-------
Q
U)
** BATCH PROCESSOR RECONSTRUCT ** FRN 13092
1 UL 100/100 D10 •*• 8182 ANP3 (METHOD BLANK) 8x12x81 BP1H1ST SCxPG«2797
50C4>-280<8> BTL*3 D13092 X- .25 V- 1.00
Effluent Method Blank (8182-Acid)
TI
Figure J-12 (continued)
-------
** BATCH PROCESSOR RECONSTRUCT *X FRN 13092
1 UL 100/100 D10 •»• 8182 ANP3 (METHOD BLANK) 8x13x81 BMH1ST SC/PQI3729
SO<4>-280(8> BTL*3 D13098 X- .35 V- 1.00
C-l
i
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en
TI
Effluent Method Blank (8182-Acid)
Figure J-12 (continued)
-------
*X BATCH PROCESSOR RECONSTRUCT ** FRIH 13092
1 UL 100/100 D10 ••• 8182 ANP3 (METHOD BLANK) 8x12/81 BHHIST SCxPGi4661
S0(4)-280(8) BTL*3 D13092 X- .25 V- 1.00
c,
i
to
Effluent Method Blank (8182-Acid)
Figure J-12 (continued)
-------
TABLE J-4.
MASS SPECTRAL IDENTIFICATION OF MAJOR COMPONENTS IN THE
ACID EXTRACTABLES METHOD BLANK SHOWN IN FIGURE J-12
C-l
00
Peak
No.
2
1
3
4
5
6
7
8
9
Retention
tine.
m in
21.10
6.50
28.42
29.03
29.73
29.92
30.28
30.87
33.05
Compound <
Internal standard;
Anthracene-dio
Recovery standard0'
Phenol-ds
Organics detected6'
Hexanedioic acid, dioctyl ester
Chrysene-d|2 (spiking compound)
Phthalate
Phthalate
Phthalate
Phthalate
Perylene-d12 (spiking compound)
Total concentration5
Peak area,
total counts
218,022
47 , 129
260,618
11,234
5,177
11,376
1,963
15,063
16,717
Amount Amount
detected, spiked. Recovery,
pg/L ug/L percent
100 - -
57.4 223 25.7
120
5.2
2.4
5.2
0.9
6.9
7.7
148.3
alcludes all substances that were found at or above a 2% threshold on the BATCH peak identifica-
tion program in the Hewlett-Packard system and greater than 0.9 ug/L relative to the anthracene-djo
internal standard.
Anthracene-d|o internal standard added immediately prior to analysis; 50 mg/L injected equivalent
to 100 pg/L in original sample.
cDeuterated recovery standard (spike), added to original effluent before extraction.
Quantitated relative to area of major ion for authentic standard.
'Estimated concentration based on area of total ion relative to that of anthracene-dlo, internal
standard.
Tentative identification, not confirmed with authentic standards.
"summation of concentrations of detected compounds, excluding standards.
-------
Ci
I
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GJ
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-n 7090.
>)'
C"
c
u
6009.
Spiked Water (8420)
o
l_t
'!.'
I/I
I
u-.
OJ
u
Pi
5000
4000.
JL
0.00 6.40
RT in minutes
1:5.80
19.20
25.60
32.00
38.40
44.86
SfiMPLE: SED 8420 INJECTED RT 8:38:10 OH SEP 11, 1981
Method: BRY32 . Raw: CES45 Proc: *PRC32
Figure J-13. Capillary GC/FID chromatogram of the extract
of a freeze-dried spiked water sample.
-------
C-|
o
1 UL
TI
** BATCH PROCESSOR RECONSTRUCT '** FRN 1 3-»b6
150X150 D10 + 8420-SED (UATER SPIKE) 9x16x81 BNH 1ST SCxPGJi i
5-280(8) BTL*28 D13456 X- *Z5 V- 1.00
Spiked Water (8420)
•
i i i i i i ii
Figure J-14. Capillary GC/MS chromatogram of the extract
of a freeze-dried spiked water sample.
-------
*.* FHTCH PROCESSOR PECOf (STRUCT .** FRM 13-456
1 UL 150/150 D10 + 8420-SED (UfVTER SPIKE) 9/16/81 BNH 1ST SC/PGt 933
S) BTLtSS D13456 X- «25 V- 1.00
TI
Spiked Water (8420)
15
Figure J-14 (continued)
-------
<-l
*»
K>
** BftTCH PROCESSOR RECONSTRUCT ** FRh 13456
1 UL 150/150 D10 + 84E0-SED CUATER SPIKE) 9X16/81 BMH 1ST SC/PG»1865
5e>(4)-E80(8) BTL«28 D13456 X" .£5 Y- 1.00
i
TI
-i
Spiked Water (8420)
1
1 1
• • • •
Figure J-14 (continued)
-------
** FHTCH PROCESSOR
-------
** BHTCH PROCESSOR RECONSTRUCT ** FPh 13456
1 UL 150''150 D10 f 84SO-SED (UATER SPIKE) 9/16/81 BNH 1ST SC/PG»3?a9
5
-------
** BHTCH PROCE'rrUR P£ CONSTRUCT
1 UL 150/150 D10 + 8420-SED CUATER SPIKE) 9/16/81
50(4^-280(8) BTL*28 D13456
FRN 1.345*5
BHH 1ST SC/PQ:4661
X- '.25 V- 1.00
c«
tn
TI
Spiked Water (8420)
Figure J-14 (continued)
-------
TABLE J-5.
RELATIVE RETENTION INDICES CALCULATED
FROM DATA SHOWN IN FIGURE J-13.
PROCESSED FILE:
RAW FILE:
SAMPLE NAME:
*PRC32
CBS45
Spiked Water (8420)
SED 8420
RELATIVE RETENTION VALUES
OUTPUT FILE: OPFS
PEAK*
i
6
7
AREA
2.34044E+06
6.89901E+07
2248.11
8423.87
4343.87
24572.4
11943.5
TIME
2.23411
2.27708
3.48056
3.71458
30.7576
34.8507
41.1267
INDEX
**#
***
***
***
298.194
397.821
497.89
J-46
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TABLE J-6.
RECOVERIES OBSERVED FOR SPIKING COMPOUNDS ADDED
TO DISTILLED WATER BEFORE FREEZE DRYING
Retention
Peak time ,
No. min Compound
Internal standara
Anthracene -d10
c d
Recovery standard '
Phenol-d5
1 , 2-Dichlorobenzene-d4
Biphenyl-d10
Pyrene-d10
Chrysene-d^
Perylene-d^
Organics detected
None detected
Amount
Peak area, detected,
total counts pg/g
33.3
<0.36
0.24
3.36
24.9
30.6
Amount
spiked, Recovery,
pg/g percent
-
35.6 <1.0
35.9 <0.3
33.5 0.7
34.3 9.8
33.7 74.0
34.0 90.0
alncludes all substances that were found at or above a 1% threshold on the BATCH peak identifica-
tion program in the Hewlett-Packard system and are greater than 0.03 pg/g relative to the
anthracene-d10 internal standard.
Anthracene-d10 internal standard added immediately prior to analysis; 50 mg/L injected equivalent
to 33.3 Mg/L in original sample.
°Deuterated recovery standard (spike), added to original sediment before freeze drying.
Quantitated relative to area of major ion for authentic standard.
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