INVENTORY AND TOXICITY
PRIORITIZATION OF INDUSTRIAL
FACILITIES DISCHARGING INTO THE
CHESAPEAKE BAY
GCA CONTRACT: 1-614-040
EPA CONTRACT: 68-02-2607
TASK NO. 30
PREPARED FOR:
INDUSTRIAL ENVIRONMENTAL RESEARCH LABORATORY
RESEARCH TRIANGLE PARK
NORTH CAROLINA 27711
CONDUCTED AT:
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
WATERSIDE MALL 401 M STREET SW
WASHINGTON, DC 20460
INVENTORY/PRIORITIZATION WORKSHOP
SEPTEMBER 27, 1979
GCA/TECHNOIOGY DIVISION
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CHESAPEAKE BAY TOXIC CHEMICAL DISCHARGE
INVENTORY PRIORITIZATION WORKSHOP
SEPTEMBER 27, 1979, 10:30 A,M,
ROOM 3906, WATERSIDE MALL
EPA HEADQUARTERS
101 M STREET
WASHINGTON, D,C,
AGENDA
10:30 WELCOME AND INTRODUCTION FRANCISCO
10:15 INTRODUCTION TO GCA/TECHNOLOGY HOPPER
DIVISION INVENTORY/PRIORITIZATION
STUDY
11:15 DISCHARGE MULTIMEDIA ENVIRONMENTAL KINGSBURY
. GOALS (DMEG)
12:00 SOURCE ASSESSMENT MODEL IX (SAM LO FRANCISCO
12:15-1:30 LUNCH
1:30-5:30 SELECTED CASE STUDIES PETROCCIA
KLEMM
ALLIED CHEMICAL-BLOCK ST, AT
WILLS, BALTIMORE, MD
WESTVACO-LUKE MILL, LUKE, MD
E,I, DUPONT-WAYNESBORO,
WAYNESBORO, VA
BETHLEHEM STEEL CORP,-SPARROWS
POINT, MD
VEPCO-YORKTOWN STATION, YORKTOWN,
VA
AMOCO-YORKTOWN, VA
5:30 ADJOURN
LIST OF SPEAKERS
DONALD E, FRANCISCO, IERL/RTP
THOMAS HOPPER, GCA/TECHNOLOGY DIVISION
GARRIE KINGSBURY, RESEARCH TRIANGLE INSTITUTE
HANS KLEMM, GCA/TECHNOLOGY DIVISION
MALCOLM PETROCCIA, GCA/TECHNOLOGY DIVISION
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CHESAPEAKE BAY PROGRAM
TOXIC POINT SOURCE ASSESSMENT:
INTRODUCTION
I, OBJECTIVES OF CBP Toxic POINT SOURCE ASSESSMENT
A, To CHARACTERIZE THE EFFLUENTS OF A BROAD
RANGE OF INDUSTRIES DISCHARGING INTO THE BAY
OR ITS TRIBUTARIES IN ORDER TO ASSESS THE
IMPACT OF THESE DISCHARGES ON THE BAY ECOSYSTEM,
SUCH CHARACTERIZATION SHALL PARTICULARLY STRESS
TOXICITY,
B, To DEVELOP A PROTOCOL FOR CHARACTERIZATION OF
SUCH EFFLUENTS WHICH MAY BE IMPLEMENTED BY THE
STATES AND EPA TO SUPPORT DISCHARGE CONTROL
DECISIONS,
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11, PROGRAM PLAN
CHESAPEAKE BAY PROGRAM
TOXIC POINT SOURCE ASSESSMENT
Inventory/Pri on' ti zati on
Develop list of outfalls
Prioritized On the basis
of presumed toxicity
Select outfalls
of concern by
EPA/III, CBP,
Md. and Va.
Contractor
Selects specific
outfalls to be
sampled to best
develop a test
analysis
scheme
Characterize 80
Outfalls
1) Chemical
2) Bioassay
3) Bioaccumulation
4) Develop protocol
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Ill, INVENTORY AND TOXICITY PRIORITIZATION OF INDUSTRIAL
DISCHARGES PHASE OF PROGRAM
A, PRIMARY PURPOSE
1, DEVELOP LIST OF MAJOR DISCHARGES
2, DEVELOP LIST OF CHEMICALS ASSUMED TO BE
IN THE DISCHARGE BY EVALUATING AVAILABLE
INFORMATION, (NPDES, EGD REPORTS, CH, E,
REFERENCES, ETC,)
3, RANK THE CHEMICALS ON THE BASIS OF RELATIVE
TOXICITY (DMEG)
4, PRIORITIZE THE OUTFALLS ON THE BASIS OF
PRESUMED TOXICITY, (TUDR)
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B, SECONDARY PURPOSE
1, DEVELOP A LIST OF MINOR DISCHARGERS WHICH
MAY HAVE TOXIC EFFLUENTS (NO SPECIFIC
EFFLUENT INFORMATION)
2, DEVELOP AN INVENTORY OF THE DISCHARGERS
TO THE BALTIMORE AND HAMPTON ROAD MUNICIPAL
SYSTEMS, (TO GIVE INDICATION OF PROBLEMS
ASSOCIATED WITH INDUSTRIAL DISCHARGES TO
PUBLICALLY OWNED TREATMENT WORKS)
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C, How WILL THE INVENTORY/PRiORITIZATION RESULTS
BE USED?
1, SELECT THE SPECIFIC OUTFALLS TO BE
CHARACTERIZED,
2, DETERMINE WHICH SPECIFIC CHEMICALS WILL
BE INCLUDED IN THE ANALYSIS (THIS WILL
BE MODIFIED WITH AN ON-SITE SURVEY)
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D, ADVANTAGES OF THE INVENTORY/PRIORITIZATION
APPROACH
1, RELATIVELY INEXPENSIVE
2, CAN BE ACCOMPLISHED IN SHORT TIME
PERIOD
3, MAXIMIZES THE PROBABILITY THAT THE
OUTFALLS WHICH ARE SAMPLED WILL YIELD
RESULTS WHICH ARE REQUIRED BY THE
PROGRAM,
4, MAXIMIZES THE PROBABILITY THAT THE
SPECIFIC CHEMICAL ANALYSES WILL BE THE
APPROPRIATE ONE FOR THE SAMPLE,
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SECTION II
INTRODUCTION TO GCA/TECHNOLOGY DIVISION
INVENTORY/PRIORITIZATION STUDY
In the 1976 Independent Agencies Appropriations Bill, the United States
Congress directed the Environmental Protection Agency to conduct an indepth
study of the Chesapeake Bay for the purpose of determining and assessing the
principal environmental factors adversely affecting the water quality of the
bay and ultimately recommending appropriate control measures to preclude fur-
ther degradation of the bay ecosystem. In response to this congressional man-
date, EPA established the Chesapeake Bay Program (CBP) to be implemented by
the Regional Administrator, Region III, Philadelphia, Pennsylvania. The pro-
gram has established as its goal "... to protect and preserve the quality
of the Chesapeake Bay by effectively managing its uses and resources." To
achieve this goal, the program has been organized into four phases:
• Submerged aquatic vegetation
• Toxics accumulation in the food chain
•' Eutrophication
• Management
It is hoped that successful accomplishment of the aggregate objectives
of all phases will lead directly to the achievement of this overall program
goal.
EPA's Industrial Environmental Research Laboratory (IERL), located at
Research Triangle Park (RTP), North Carolina has been.directed by the Chesa-
peake Bay Program Office at Region III in Philadelphia, Pennsylvania to conduct
GCA/TECHNOIOGY DIVISION
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certain Environmental Source Assessment activities within the "Toxics" phase
of the program. The GCA/Technology Division has, in turn, been retained by
IERL/RTP to undertake the first major subtask of the Environmental Source
Assessment Program, namely an "Inventory and Toxicity Prioritization of Indus-
trail Facilities Discharging into the Chesapeake Bay Basin." The results of
the GCA study will provide the rationale for selecting certain facilities to
be the subject of an intensive effluent sampling program to be conducted as
a subsequent subtask within the Environmental Source Assessment Program. The
selection will be made on the basis of a qualitative ranking of facilities and
each of their outfalls, according to the degree of relative potential hazard
posed by that particular discharge stream on the environment. The techniques
used to develop such a facility prioritization are highly subjective and only
applicable to the specific purpose of this project. It must be expressly
understood by all those using the data that the results are based on relative
environmental hazard factor indicators and in no way should be construed either
directly or indirectly as a quantitative measure of the potential toxicity or
hazard of any waste stream discharge evaluated. To so assume would be a gross
misapplication of the data presented.
The relative potential hazard of each given waste stream was determined by
first developing a list of known or suspected chemical constituents presumed
to be in a particular discharge. The discharge rate of each constituent was
then computed based upon flow and concentration data. A relative indicator
of toxicity was then developed for each chemical of concern, predicated on the
application of a toxicity model to certain fundamental toxicblogical and water
quality data. An indicator of the degree of hazard of each constituent presumed
to be in a given discharge was then computed based on the flow, concentration
GCA/TECHNOLOGY DIVISION
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and toxicity indicator of that chemical. This indicator, called the Toxic
Unit Discharge Rate (TUDR), will be described more fully later in this pre-
sentation. All such values for the waste stream were totaled for individual
or aggregated multiple outfalls at any one facility and then compared to
similar values computed for all the other outfalls and facilities within the
study population. Such determinations have been made for each outfall at 102
major sources discharging into the Bay or its tributaries. These 102 sources
have been categorized into facility groupings, or genera of similar effluent
characteristics and those outfalls within each genera which exhibit the highest
potential degree of hazard are "flagged" as possible candidates for future
extensive effluent sampling programs to confirm the presence (or lack) of those
chemical constituents presumed to be in the discharge stream.
The scope of our study included an inventory of both major and minor direct
industrial dischargers to those river basins in Virginia, Maryland and the
District of Columbia which directly feed into the Bay. The major facilities
are the subject of the categorization/prioritization elements of the study,
and, therefore, have received the greatest degree of attention. Minor direct
industrial dischargers, on the other hand, have not been prioritized but have
been simply listed as possible toxic contributors to the Bay to the extent that
such a presumption could be made based on general knowledge of the type of in-
dustry. The differentiation between major/minor sources was based on defini-
tions provided by each State Agency and EPA. In general, a source was classi-
fied as a major if its discharge flow rate exceeded 100,000 gallons per day
(gpd)5 however, many additional smaller sources were considered "major" by these
regulatory agencies because of presumed or known toxic/hazardous discharge
potential.
GCA/TECHNOLOGY DIVISION
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GCA and EPA recognize that a significant volume of industrial discharge
wastewater is directed into Publicly Owned Treatment Works (POTW) as the result
of sewer tie-ins. The dischargers from these POTWs in turn empty into those
river basins feeding the Bay. An evaluation of these industrial inputs was
< not considered to be within the scope of this project; however, a cursory
investigation of the major industrial inputs into two large municipal districts
was undertaken for the purpose of developing an estimate of the extent to which
such discharges may contribute to toxic loadings.
The results of our study are presented according to River Basin in order
to provide consistency and compatibility with other studies (303(e) basin
plans, 208 area wide plans) and to provide a meaningful reference for comparing
data to ambient toxic/hazardous chemical studies which have been or will be
conducted. We have plotted the location of each individual source on maps
defining each basin within the geographical confines of our study. Majors and
minors are presented separately. For each basin, we have developed a complete
listing of industrial dischargers identified by NPDES* permit number, location
data, SIC"*" code number(s), and discharge rate. In addition, each appropriate
facility outfall is identified and the presumed chemical constituents, concen-
trations, flow rates and relative toxic indicator values are presented. Again
majors and minors are treated separately.
Our categorization process defined 21 groups of facilities, or genera,
exhibiting common effluent characteristics. Each genus contained as few as 1
and as many as 21 individual facility entries. The genera defined were
*NPDES - National Pollution Discharge Elimination System
SIC - Standard Industrail Classification
GCA/TECHNOLOGY DIVISION
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reflective of major industrial categories not unlike those being utilized by
EPA's Effluent Guidelines Division for BATEA, NSPS and PSNS determinations.*
Because of the specific nature of our source population and considering that
our study covered a far more extensive list of chemical constituents than the
Effluent Guidelines Studies, there were some notable differences. The indi-
cators of potential waste stream hazard were compared within each individual
genus as well as for the entire population notwithstanding categorical
association.
A total of 102 major dischargers were identified for the study area, and
based on the concentration and speciation of chemicals discharged, a measure
of potential hazard was computed for each operation. This procedure allowed
us to rank the industrial facilities and their respective outfalls on a rela-
tive scale of decreasing hazard. We also ranked all of the individual outfalls
from among the total facility population of 102 to provide further definition
relative to the ultimate selection of specific waste streams to be sampled.
Finally, we have ranked all 102 facilities among the 21 genera with respect
to the potential hazard of their effluent.
The results of our work are being made available to a variety of regula-
tory agency personnel at the State and Federal levels as well as various work
groups and committees consisting of government officials and private citizens.
Accordingly, we anticipate that many uses will be made of the data presented.
For that reason, a computer data file has been developed which provides a
storage library of all the pertinent information developed. This file is
*BATEA - Best Available Technology Economically Achievable
NSPS - New Source Performance Standards
PSNS - Pretreatment Standards for New Sources
GCA/TECHNOIOGY DIVISION
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available to any potential user group and has been written so as to permit
ready incorporation into another computer-based information system. The data
file is flexible enough to allow expansion of record length and addition of
new or revised record information.
We again caution the reader to use the information presented with appro-
priate discretion and within the context of its applicability to this project.
The listing or prioritization of a facility is in no way to be considered an
indication of that facilities' hazardous discharge potential nor are the values
presented meant to have any quantitative implications.
GCA/TECHNOIOGY DIVISION
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PURPOSE OF WORKSHOP
• DESCRIBE GCA'S INVENTORY/PRIORITIZATION
STUDY FOR EPA/IERL
• PRESENT ENVIRONMENTAL ASSESSMENT MODEL USED
FOR RANKING FACILITIES
i OUTLINE SOURCE ASSESSMENT PROCEDURES EMPLOYED
TO CHARACTERIZE SEVERAL SELECTED FACILITIES
GCA/TECHNOLOGY DIVISION
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PROJECT OBJECTIVES
• IDENTIFY INDUSTRIAL SOURCES POTENTIALLY DIS-
CHARGING HAZARDOUS/TOXIC SUBSTANCES TO THE
CHESAPEAKE BAY BASIN
• CHARACTERIZE DISCHARGERS ON THE BASIS OF
CHEMICAL SPECIES AND CONCENTRATION
0 CATEGORIZE FACILITIES INTO GROUPS EXHIBITING
SIMILAR EFFLUENT CHARACTERISTICS
t RANK FACILITIES ACCORDING TO POTENTIAL
DEGREE OF HAZARD
GCA/TECHNOLOGY DIVISION
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PROJECT SCOPE
THE OVERALL GCA STUDY CONSIDERED , , ,
• 102 MAJOR INDUSTRIAL FACILITIES INCORPORATING
272 TOTAL OUTFALLS
• 362 MINOR INDUSTRIAL FACILITIES
• 2 LARGE MUNICIPAL WASTEWATER TREATMENT DISTRICTS
INCORPORATING
11 POTW'S
38 MAJOR INDUSTRIAL TIE-INS
- 360 MINOR INDUSTRIAL TIE-INS
9 23 RIVER BASINS
• 550 CHEMICAL CONSTITUENTS
GCA/TECHNOIOGY DIVISION
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PROJECT ORGANIZATION
TASK I
• DEVELOP INVENTORY OF MAJOR/MINOR INDUSTRIAL SOURCES
DISCHARGING POTENTIALLY HAZARDOUS/TOXIC SUBSTANCES
TO THE CHESAPEAKE BAY BASIN
VIRGINIA
MARYLAND
DISTRICT OF COLUMBIA
• DEVELOP INVENTORY OF MAJOR/MINOR POTW'S DISCHARGING
TO THE CHESAPEAKE BAY BASIN
• LOCATE MAJOR/MINOR INDUSTRIAL DISCHARGERS ON MAPS
DESCRIBING THE GEOGRAPHICAL AREA
RIVER BASINS
CITY
TASK 1
• IDENTIFY CHEMICAL CONSTITUENTS PRESUMED TO BE
DISCHARGED
MAJOR SOURCES
INDIVIDUAL OUTFALLS
TASK IE
• CATEGORIZE FACILITIES EVALUATED INTO GENERA OF
SIMILAR EFFLUENT CHARACTERISTICS
TASK 3g
• RANK FACILITIES ON THE BASIS OF RELATIVE POTENTIAL
DEGREE OF HAZARD
INDIVIDUAL OUTFALLS
TOTAL FACILITY
WITHIN CATEGORY
• DEVELOP COMPUTER DATA FILE
GCA/TECHNOIDGY DIVISION
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DEVELOPMENT OF INDUSTRIAL
POINT SOURCE INVENTORY
DATA DEVELOPED FROM:
t NPDES PERMITS
• NPDES PERMIT APPLICATIONS
• DISCUSSIONS WITH REGULATORY AGENCY PERSONNEL
EPA REGION III
STATE OF MARYLAND, WATER RESOURCES ADMINISTRATION
COMMONWEALTH OF VIRGINIA, WATER CONTROL BOARD
INFORMATION DERIVED:
• SOURCE NAME
• ADDRESS
• OWNER/OPERATOR
• NPDES NUMBER
e SIC CODE(S)
• RIVER BASIN LOCATION
• COUNTY
• LATITUDE/LONGITUDE
• NUMBER OF OUTFALLS
• DESCRIPTION OF OUTFALLS
• FACILITY FLOW RATE
• INDIVIDUAL OUTFALL FLOW RATES
• MAJOR/MINOR DEFINITION
GCA/TECHNOLOGY DIVISION
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APPROACH USED TO CHARACTERIZE
EFFLUENT DISCHARGES
i
t IDENTIFY SPECIFIC PROCESSES AND/OR PRODUCTS
• IDENTIFY OUTFALLS AND LINK TO PROCESSES
NONCONTACT COOLING WATER
DIRECT CONTACT COOLING WATER
DIRECT PROCESS WASTEWATER
PLANT SEWERS AND DRAINS
t QUALITATIVE ANALYSIS OF EACH OUTFALL
FACILITY-SPECIFIC DISCHARGE DATA
FACILITY-SPECIFIC PROCESS/PRODUCT DATA
GENERAL INDUSTRIAL CATEGORY DATA
ENGINEERING JUDGMENT
• QUANTITATIVE ANALYSIS OF EACH OUTFALL
FACILITY-SPECIFIC DISCHARGE DATA
FACILITY-SPECIFIC PROCESS/PRODUCT DATA
GENERAL INDUSTRIAL CATEGORY DATA
ENGINEERING JUDGMENT
GCA/TECHNOLOGY DIVISION
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DATA SOURCES
PRIMARY SOURCES OF CHEMICAL DATA
• NPDES FILES
MARYLAND
VIRGINIA
• DISCHARGE MONITORING REPORTS
SUPPLEMENTARY SOURCES OF CHEMICAL DATA
• HAZARDOUS SUBSTANCES REPORTS (MARYLAND)
§ BUREAU OF TOXIC SUBSTANCES INFORMATION (VIRGINIA)
GENERAL SOURCES OF CHEMICAL DATA
• TECHNOLOGY REVIEW SERIES (NOYES DATA CORPORATION)
t PUBLISHED REPORTS/ARTICLES
t INDUSTRIAL PROCESS PROFILES
> JOURNAL OF THE WPCF
• PROCEEDINGS OF THE ASCE
t TECHNOLOGY TRANSFER SEMINAR PUBLICATIONS
• TECHNICAL STUDY REPORTS FOR BATEA, NSPS, AND PSNS
• U,S, INTERNATIONAL TRADE COMMISSION - SYNTHETIC
ORGANIC CHEMICALS
t VARIOUS CHEMICAL PROCESS ENGINEERING TEXTBOOKS
GCA/TECHNOIDGY DIVISION
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RELIABILITY FACTORS
NUMBER DEFINITION
1 MEASURED - SUBSTANTIVE DATA
2 MEASURED - LIMITED DATA
3 ESTIMATED - GOOD DATA
H ESTIMATED - LIMITED DATA
5 ENGINEERING JUDGMENT
TYPICAL DATA SOURCE
DMR
NPDES PERMIT APPLICATION
APPLICATION OF SIMILAR DATA
INDUSTRY SUMMARY DATA
PRIORITY POLLUTANT LISTING
GCA/TECHNQIDGV DIVISION
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CATEGORICAL DISTRIBUTION
OF MAJOR INDUSTRIAL DISCHARGERS
CATEGORY
COAL WASHING
FERROUS METAL MANUFACTURE
FOOD PROCESSING
INDUSTRIAL INORGANIC CHEMICALS
INDUSTRIAL ORGANIC CHEMICALS
MACHINERY AND METAL FABRICATION
NONFERROUS METALS MANUFACTURE
PESTICIDES
PETROLEUM REFINERIES
PHARMACEUTICAL PRODUCTS
PIGMENT MANUFACTURE
PLASTIC AND SYNTHETIC MATERIALS
PULP, PAPER, AND PAPER BOARD
RUBBER MANUFACTURE
SHIPBUILDING AND REPAIR
SOAPS AND DETERGENTS
STEAM ELECTRIC POWER PLANTS
TANNERIES (LEATHER)
TEXTILES AND RELATED PRODUCTS
TOBACCO PROCESSING
WATER TREATMENT PLANTS
TOTAL
NUMBER OF
FACILITIES
CONSIDERED
1
2
19
7
3
3
2
1
2
1
3
7
8
1
8
3
21
2
4
1
3
102
GCA/TECHNOIDGY DIVISION
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DISCHARGE MULTIMEDIA ENVIRONMENTAL GOALS
by
Garrie L. Kingsbury
Research Triangle Institute
P. 0. Box 12194
Research Triangle Park, North Carolina 27709
Presentation for the
Toxic Chemical Discharge Inventory Prioritization Workshop
September 27, 1979
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MULTIMEDIA ENVIRONMENTAL GOALS (MEG'S)
Multimedia Environmental Goals (MEG's) have been developed for use in
environmental assessment. Environmental assessment involves:
1. The determination of contaminant levels associated with emissions
and effluents from a point source.
2. Comparison of those determinations with research objectives.
The need for MEG's arises in this latter aspect of environmental assessment.
MEG's for specific chemical contaminants describe desirable control levels in
air, water, and soil. They are expressed in appropriate concentration units
and may be compared directly with established or estimated levels in streams
to be assessed.
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ASSESSMENT ALTERNATIVES
MEG's provide several assessment alternatives. Five alternative subsets
of MEG's that may be used in environmental assessment are listed below:
Existing ambient standards
Ambient MEG's (AMEG's)
Discharge MEG's (DMEG's)
Natural background/elimination of discharge goals
Best technology goals (Not yet developed)
The Discharge MEG values (DMEG's) for water are the subset of MEG's
applied for ranking chemicals in the Chesapeake Inventory with respect to
their individual potential environmental impacts. The DMEG's coupled with the
Source Analysis Model 1A (SAM/1A) provide a tool to allow systematic priori-
tizing of discharging facilities.
DMEG's selected from the list in the report entitled Multimedia Environmental
Goals for Environmental Assessment. Volume _! are used in the Chesapeake
analysis as chemical ranking factors. The method developed for computing
DMEG's has been applied by GCA to additional chemicals on the Chesapeake
inventory (but not included in the original MEG's list) to establish ranking
factors to supplement the published DMEG's list.
The remainder of this section presents the equations used to establish
DMEG's for aqueous streams. Assumptions inherent in the methodology, its
limitations, and its advantages are presented. The rationale behind the
hierarchy established for selecting the preferred basis for DMEG's applied in
the Chesapeake study is also discussed.
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DMEG'S FOR AQUEOUS STREAMS
DMEG's for aqueous streams may be based on human health or on ecological
factors. They may reflect established federal guidelines (i.e., Drinking
Water Standards; Criteria for Protection of Aquatic Life) or their bases may
lie in the results of laboratory bioassay or industrial, hygiene experience.
To establish potential hazard ratings for the chemicals in the Chesapeake
Inventory prioritization, GCA has prescribed an order of preference among the
possible DMEG values. This order of preference assures that the specific DMEG
most relevant to potential ecological impacts is used as the ranking factor.
DATA TYPES SERVING AS BASIS FOR DMEG'S IN PREFERENTIAL ORDER
Most stringent Federal Water Quality Criteria for Protection of
Aquatic Life
Lowest reported TLm vafue (96 hr exposure, if available)
Most stringent Federal Water Quality Criteria or Standard for Drinking
Water
LDcQ, oral/rat (or reported dosage most comparable)
Lowest lethal or lowest toxic inhalation concentration reported
ACGIH or NIOSH recommendations for permissible exposure in workroom
atmosphere (time-weighted averages)
Lowest experimental dosage reported to elicit tumors or teratogenic
responses in laboratory animals.
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DMEG BASED ON FEDERAL GUIDELINES FOR PROTECTION OF AQUATIC LIFE
Equation
DMEG, (mg/£) = 5 x most stringent water quality criteria
for protection of aquatic life (mg/2) (1)
Discussion of Assumptions and Terms in Equation
2
Recognized Water Quality Criteria include the 1976 EPA Criteria and the
1972 NAS/NAE Criteria. The most stringent Water Quality Criteria for Pro-
tection of Aquatic Life is frequently designated the "Minimal Risk Level."
Levels described as "Hazard Levels" may also be specified.
The multiplier 5 in equation 1 is suggested by the relation between
minimal risk levels and hazard levels for aquatic life as recommended by the
NAS/NAE. For 22 substances both hazard levels and minimal risk levels are
recommended. The estimated hazard level is most often between 2 and 5 times
the recommended minimal risk concentration for continuous exposure.
Discharge concentrations not exceeding the DMEG-, will, upon dilution by a
factor of 5, not exceed the ambient water criterion. Short-term exposure of
aquatic life to the undiluted aqueous discharge will probably not result in
irreversible effects.
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OMEG BASED ON THRESHOLD LIMIT MEDIAN (TLm)
Equation
DMEG2 (mg/£) = 0.1 x Lowest reported TLm (mg/£) (2)
Discussion of Assumptions and Terms in Equation .
Threshold Limit Median (TLm) describes the lethal concentration of a
pollutant to 50 percent of a tested aquatic species population. TLm's are
generally expressed in mg/£. Exposure durations may be 24, 48, or 96 hours;
most frequently 96-hour values are reported. Values vary depending on species
tested, the test type (i.e., static or flowthrough bioassay), and other con-
ditions such as pH or water hardness. TLm data are compiled in the recognized
4
water quality criteria documents and in the NIOSH Registry. Other sources of
aquatic data were also used in establishing the tabulated DMEG values in
reference 1.
The multiplier 0.1 in equation 2 may be interpreted as a modified appli-
cation factor. An application factor is defined as the ratio of. "safe" to
lethal concentration of a toxicant. To predict safe ambient -concentrations
for toxic chemicals, the NAS/NAE has recommended the following application
factors:
0.05 (for nonpersistent toxicants)
0.01 (for persistent toxicants)
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Discharge concentrations not exceeding the DMEG2 will, upon dilution by a
factor of 5, not exceed safe continuous exposure levels predicted using the
NAS/NAE application factors for nonpersistent toxicants. Dilution by a factor
of 10 is required for persistent toxicants.
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DMEG BASED ON LD5Q
Equation
DMEG3 (mg/£) = 0.675 x LD5Q (mg/kg) (3)
Discussion of Assumptions and Terms in Equation
LDcQ values, i.e., lethal dose to 50 percent of population tested, are
generally reported as mg of toxicant per kg of animal body weight. Oral rat
data are used most, often. When unavailable, other route/species combinations
are substituted. The lowest published lethal dose is substituted in the
absence of more reliable data. The results of lethal dose animal studies for
approximately 20,000 chemicals are listed in the 1976 NIOSH Registry of Toxic
Effects £f Chemical Substances. LDcg values are also reported in other sources,
but the NIOSH Regi stry is the most comprehensive compilation.
The multiplier 0.675 arises as explained below:
®*
1) A relationship between TLV's and ID™ values was established by
Handy and Schindler. A quantity called TLV. representing the lower 95 percent
confidence limit for the TLV/LDcQ relationship was defined.
TLVLow (mg/m3) = 4.5 x 10"4 x LD5Q (mg/kg).5 (4)
A safety factor of ~ 100 is inherent in the TLVLow compared to
A
TLV's recommended by the ACGIH. Thus a permissible short-term inhalation
exposure concentration in mg/m is equal to 0.045 x LD,,-Q.
*See explanation of TLV's under discussion of DMEGr.
. 7 s
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2) Permissible air concentrations (mg/m ) and permissible water concen-
trations (mg/£) are related by a factor of 15 if the following assumptions are
made:
Daily tidal respiratory volume is 30 m /day.
Total contaminant from 30 m /day of air is absorbed.
Permissible daily dosage from air is equal to the permissible air
concentration (mg/m ) multiplied by 30 m /day.
Permissible daily dosage from water is equal to permissible daily
dosage from air.
Daily water consumption is 2 liters/day.
(This approach was adapted from a model introduced by E. H. Stokinger and
R. L Woodward.)6
3) Equation 3 results when statements 1 and 2 are combined.
Permissible water 3 3
concentration (mg/2) = 0.045 LDcn (mg/m ) x 30 (m )
50 ~2 (£)
= '0.675 x LD5Q (mg/<0
8
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DMEG BASED ON TOXIC OR LETHAL INHALATION LEVELS
Equation
DMEG. (mg/iO = 1.5 x Lowest reported effective inhalation
concentration. (5)
Discussion of Assumptions and Terms in Equation
o
Lethal or toxic inhalation concentrations are generally reported in mg/m
of air or in ppm. 1-0™, (lethal concentration to 50 percent of exposed
populations) are often reported from inhalation studies. Lowest reported
4
lethal or toxic concentrations are used. The NIOSH Registry contains LC
data for many compounds, and Industrial Hygiene and-Toxicology edited by
Frank A. Patty is an excellent source for such data.
The multiplier 1.5 in equation 5 is the product of two factors, 0.1 and
15, explained below.
1) The factor 0.1 is an arbitrary multiplier that may be interpreted as
an application factor similar to that discussed under DMEG2. It is applied to
convert a lethal or toxic concentration to a safe short-term inhalation exposure
level.
2) The factor 15 is used to convert a permissible air concentration to
a permissible water concentration as described in the discussion under DMEG3-
-------
DMEG BASED ON TLV® OR NIOSH RECOMMENDATION
Equation
DMEG5 (mg/2) = 15 x TLV® or NIOSH Recommendation (mg/m3) (6)
Discussion of Assumptions and Terms in Equation
Threshold Limit Values (TLV's ) are levels of contaminants considered
safe for workroom atmosphere, as recommended by the American Conference of
Governmental Industrial Hygienists (ACGIH). Time-weighted averages for exposure
durations of ten hours per day or 40 hours per week are specified for more
g
than 500 chemicals.
NIOSH Recommendations are recommendations for occupational exposure
limits for chemical contaminants 'established by the National Institute of
Occupational Safety and Health (NIOSH). These recommendations are analogous
@
to the TLV's but frequently are more stringent. More than 100 NIOSH criteria
documents are currently available addressing more than 200 specific chemicals.
The criteria documents serve as the bases for the recommendations.
The multiplier 15 in equation 6 is included to translate a permissible
short-term exposure air concentration to a permissible short-term exposure
concentration for water. See explanation in discussion of DMEG.,.
10
-------
DMEG BASED ON CARCINOGENICITY OR TERATOGENICITY
Equation
DMEGg (mg/£) = /Multiplier \ /Lowest effective dosage pro- >
I ranging between) x (ducing tumors or teratogenic
\0.12 and 0.5 / \effects in laboratory animals;
(7)
Discussion of Assumptions and Terms in Equation
Dosages eliciting tumorigenic or teratogenic effects in animals are
4
reported in several references including the NIOSH Registry' the Survey of
9
Compounds Which Have Been Tested for Carcinogenic Activity (PHS No. 149 in
7 Volumes) prepared for the National Cancer Institute; and the (IARC) Monographs
on the Evaluation o_f the Carcinogenic Risk of Chemicals to Man (now 18
volumes) prepared by the International Agency for Research on Cancer. The
lowest effective dosage reported is used in equation 7 regardless of species
or route of administration.
The multiplier is equation 7 may range between 0.12 and 0.5 depending on
the types of positive bioassay results reported for a given chemical. The
s
multiplier range has been derived through a series of assumptions that (1) relate
lowest effective dosages to concentration goals in ambient air; (2) translate
"acceptable" ambient air levels to acceptable short-term levels; and (3)
convert permissible air concentrations for short-term exposures to short-term
exposure concentration goals for water. It should be noted that the multiplier
is consistently smaller than that applied to LD50 values in calculating a -per-
missible air concentation.
11
-------
RELIABILITY OF DMEG'S
The DMEG numerical ranking factors derived through the equations pre-
viously discussed are based on empirical data presently available in general
secondary references. DMEG Values will need to be updated as new information
becomes available. Important qualifications regarding the reliability of DMEG's
are stated below. It should be emphasized that a conservative approach is
applied consistently in computing the DMEG's.
1. Toxicity data reported in the NIOSH Registry have been used extensively
in calculating DMEG ranking factors. TLm values reported for aquatic life may
vary depending on test conditions (species, pH, temperature, static or flow-through,
etc.) which are not specified in the Registry. DMEG's reflect the lowest TLm
reported.
2. LDj-Q values reported in the Registry may vary with species and route
of administration. Because they are available for the greatest number of
compounds, oral rat LD5Q values were used preferentially in calculating DMEG's
based on lethal animal dose. Specific details of the bioassays (numbers of
animals, age, sex, etc.) are not reported in the Registry.
3. In describing DMEG's, no attempt has been made to compensate for
synergistic or antagonistic effects. Bioaccumulation is also not addressed
except to the extent that Federal guidelines reflect cumulative effects.
4. Translation of acceptable levels in air to acceptable levels in
water involves a series of worst case assumptions.
®
5. The ACGIH has made clear its intention that the TLV's are to be
used only in the practice of industrial hygiene and that it does not recommend
their use as a relative index of hazard or toxicity. NIOSH recommendations
likewise are intended to be used in industrial hygiene and are not recommended
for ranking purposes.
12
-------
6. DMEG's reflecting carcinogenic potential are frequently based on the
lowest dose reported to elicit tumors in long-term animal tests. Confidence
limits associated with the bioassays are not used in the DMEG calculations.
Also, extrapolations from effective dosage to dosage of no concern and from
the specific population tested to other species involve broad assumptions.
The reliability of these assumptions can not be predicted.
7. It is recognized that carcinogens react biologically in a number of
different ways. Distinctions between cocarcinogenicity, promotion, and meta-
bolic alterations (into more or less active metabolites) are not considered
in calculating DMEG's for suspected carcinogens.
13
-------
REFERENCES
1. Cleland, J. G., and G. L. Kingsbury. Multimedia Environmental Goals for
Environmental Assessment, Volumes I and II. Industrial Environmental Research
Laboratory, U.S. Environmental Protection Agency. Research Triangle Park, N.C.
EPA-600/7-77-136a. November 1977.
2. U. S. Environmental Protection Agency. Quality Criteria for Water.
EPA 440/9-76-023, 1976.
3. National Academy of Sciences, National Academy of Engineering. Water
Quality Criteria 1972. National Academy of Sciences, Washington, DC.
EPA-R3-73-033 (1973).
4. Fairchild, Edward J., Ed. Registry of Toxic Effects of Chemical Substances,
Volumes I and II. National Institute for Occupational Safety and Health, U.S.
Department of Health, Education, and Welfare. Cincinnati, Ohio. DHEW Publication
Number (NIOSH) 78-104-B. September 1977.
5. Handy, Robert, and Anton Schindler. Estimation of Permissible Concentrations
of Pollutants for Continuous Exposure. U.S. Environmental Protection Agency.
Research Triangle Park, N.C. EPA-600/2-76-155.
6. Stokinger, E. H., and R. L. Woodward. Toxicological Methods for Establishing
Drinking Water Standards. Journal of American Water Works Association, Vol. 515
(1958).
7. Patty, F. A., Ed. Industrial Hygiene and Toxicology, Second Revised
Edition. Volume 2. Interscience Publishers, New York, NY (1963).
8. TLV's : Threshold Limit Values for Chemical Substances and Physical
Agents in the Workroom Environment with Intended Changes for 1976 and 1977.
American Conference of Industrial Hygienists. 1976, 1977.
9. Survey of Compounds Which Have Benn Tested .for Carcinogenic Activity,
1972-73 Volume. National Cancer Institute, U.S. Department of Health, Education,
and Welfare. Bethesda, MD. PHS Publication Number 149. 1973. p. 1.
10. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals
to Humans, Volumes I-XVIII. International Agency for Research on Cancer,
World Health Organization, Geneva, Switzerland. October 1973.
14
-------
SOURCE ASSESSMENT MODEL 1A
(SAM/1A)
A, DEFINITION:
1, SAM/1A IS A SIMPLE MODEL TO PRODUCE QUANTITATIVE
MEASURES OF POTENTIAL ENVIRONMENTAL HAZARD OF
INDUSTRIAL CHEMICALS AND/OR WHOLE DISCHARGES,
2, IT DOES NOT INCLUDE DISPERSION, DILUTION., OR
INTERACTION,
B, INPUT DATA:
1, CONCENTRATION OF CHEMICAL CONSTITUENTS
2, DMEG FOR CHEMICAL CONSTITUENTS (yG.O DISCHARGE
3, FLOW RATE (*/SEC)
NOTE: IN GCA/TECHNOLOGY DIVISION REPORT UNITS
ARE MG/* AND GALLONS/DAY
-------
C, COMPUTATION
1, DEGREE OF HAZARD = CONCENTRATION OF SPECIFIC CHEMICALS
(DH) DMEG FOR CHEMICAL
2, OUTFALL DH = DH} + DH2 + ... + DHN
3, Toxic UNIT
DISCHARGE
RATE (TUDR)
= DH X DISCHARGE RATE U/SEC)
, OUTFALL TUDR = TUDRi + TUDRo + ,,, + TUDR
N
5, FACILITY TUDR
= SUM OF ALL OUTFALL TUDR'S
AT A FACILITY,
NOTE: IN GCA/TECHNOLOGY DIVISION REPORT, FLOW is GAL/DAY
RATHER THAN A/SEC, To OBTAIN TUDR IN STANDARD UNITS
MULTIPLY BY 4,38 X 10,
-5
-------
D, ASSUMPTIONS
1. THE CONCENTRATION OF THE SPECIFIC TOXIC
COMPOUNDS IS KNOWN OR MAY BE ESTIMATED,
2, THE DMEG CONCEPT ASSUMPTIONS,
3, THE RELATIVE EFFECT OF INDIVIDUAL TOXIC
CONSTITUENTS IS ADDITIVE (NOT ANTAGONISTIC
OR SYNERGISTICS)
-------
E, PURPOSE
1, SAMS CAN BE USED TO DO ONE OR MORE OF THE
FOLLOWING:
A, RANK EFFLUENT STREAMS, IN THIS APPLICATION/
THE SAM IS USED TO COMPARE THE TOXIC-UNIT
RATE OF DISCHARGE INTO EACH EFFLUENT STREAM;
THESE TOXIC-UNIT SUMMATIONS CAN THEN BE
RANKED BY MAGNITUDE, EXAMINATION OF THE
RELATIVE MAGNITUDES GENERATED BY DIFFERENT
STREAMS IMMEDIATELY SHOWS THE RELATIVE POTENTIAL
HAZARD OF THE DIFFERENT EFFLUENT STREAMS,
B, ESTABLISH SPECIFIC SAMPLING AND ANALYSIS
PRIORITIES IN PERFORMING ENVIRONMENTAL
ASSESSMENTS,
c, DETERMINE PROBLEM POLLUTANTS AND POLLU-
TANT PRIORITIES, IN THIS APPLICATION/ USE
OF THE SAM CAN LEAD TO AN UNDERSTANDING
OF WHICH POLLUTANTS ARE MOST LIKELY TO
CAUSE MAJOR ENVIRONMENTAL IMPACT,
D, DETERMINE WHICH CONTROL TECHNOLOGY OPTIONS
ARE THE MOST EFFECTIVE, IN THIS APPLICATION
THE SAM IS USED TO EXAMINE A GIVEN PROCESS
STREAM WITH FIRST ONE AND THEN ANOTHER CONTROL
APPROACH,
E, DETERMINE THE NEED FOR CONTROL/DISPOSAL
TECHNOLOGY DEVELOPMENT,
-------
2, THE SAM/1A CAN NOT, IN THE ABSENCE OF
FURTHER ANALYSIS, BE USED TO!
A, SUPPORT DECISIONS TO IMPOSE CONTROLS ON
DISCHARGES,
B, IDENTIFY PARTICULAR DISCHARGES AS BFING
RESPONSIBLE FOR ENVIRONMENTAL DEGRADATION,
c, PRODUCE ABSOLUTE TOXICITY RANKING, I.E.,
ALL TUDR'S WITHIN 1-3 ORDERS OF MAGNITUDE
MAY BE EQUIVALENT,
D, EXTRAPOLATE AN EFFECT UPON THE AQUATIC
SYSTEM,
REFERENCE: SCHALIT, L, M, AND WOLFE, K, J,
SAM/1A: A RAPID SCREENING METHOD FOR ENVIRONMENTAL
ASSESSMENT OF FOSSIL ENERGY PROCESS EFFLUENTS,
ACCUREX CORPORATION/AEROTHERM DIVISION, MOUNTAIN VIEW,
CALIFORNIA,
PREPARED FOR U,S, ENVIRONMENTAL PROTECTION AGENCY, OFFICE
OF RESEARCH & DEVELOPMENT, WASHINGTON, DC-.
REPORT No, EPA-600/7-78-015, FEBRUARY, 1978,
-------
ALLIED CHEMICAL CORPORATION
A, FACILITY DESCRIPTION
1. GENERAL FACILITY INFORMATION
Allied Chemical Corp.
Block St. at Wills
Baltimore, MD
NPDES Permit No. MD 0002186
County Code 2005
Basin Code 02130903
Latitude 39° 13' 50"
Longitude 76° 36' 00.0"
Major SIC 2819
Total Flow 3.23 x 106 gallons per day
Manufacturer of Inorganic Chromium Chemicals
21 OUTFALL DESCRIPTIONS
2.1 OUTFALL 001:
2.2 OUTFALL 002:
2.3 OUTFALL 003:
2.4 OUTFALL 004:
2.5 OUTFALL 005:
2.6 OUTFALL 006:
50,000 gallons per day from cooling of
air conditioning equipment.
Flow values from NPDES Application.
7,000 gallons per day from cooling of
boiler fan room and pumps.
Flow values from NPDES. Applfcat I on .
315,000 gallons per day from manufac-
ture of chromium chemicals-potassium
bichromate (15 tons per day).
Flow values from NPDES Application.
1*70,000 gallons per day from chromic
acid manufacture (50 tons per day).
Flow values from NPDES Application.
390,000 gallons per day from sodium
bichromate manufacture (190 tons per day)
Flow values from NPDES Application.
1,990,000 gallons per day from sodium
bichromate manufacture (190 tons per day)
Flow values from NPDES Application.
GCA/TECHNOLOGY DIVISION
-------
GCA/ TECHNOOGY DIVISION
CARD
NO.
NPOES NO.
COUNTY
NO.
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL FACILITY INFORMATION
BASIN CODE
SIC CODE
MAJOR
SIC CODE
MINOR
SIC CODE
MINOR
SIC CODE
MINOR
SIC CODE
MINOR
flDW RATE
94! /day
MAJOR INDICATOR
I I
J7jl8|8tofel
13
37
» 46:
TOT-
17
-------
GOVTECHNO1OGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
i 'J
i
cjo
3
1
NPDES NO.
4
«
•
0
[_
6
O
7
0
els!*
j <
ir
S"
e
6
OUTFALL
I.D. NO.
13
O
M
O
IS
'
SIC CODE
«M|8I4D
*h'ft
?i
o,
a
ae
z
TC
SIC CODE
2t
27
J
L
I
Ji
SIC CODE
4s
i
*
T
1
4
JT
38
i
35
FLOW RATE
40
V
(c
42
0
L
13
0
44
*
49
V
U|
a
1
«
j
(7
rFLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
a
4S
^
X
0
51
0
wu
KPJ
Lj/
rV
, T
^U
^
6t
/
TT
4 |c
^{n/
r
/
0
' -IW~
MODr. np^. J iiNi-re-T * RELIABILITY FACTOR OF
DISCHARGE OF FLOW RATE FLOW RATE DETERMINATION
CARD
NO.
i
C
i
0
3
2
NPDES NO.
4
5
•
7
1
9
J.
1 !_,
e
^Ci
2*
1-
a
M
15
DESCRIPTION OF OUTFALL (CONTINUED)
«
(7
i
IB
19
20
fl
«
27
J-
T3
i
B
31
T
M
it
»
4,
i 1
39
40
n
•i
JnL
FT
| |
ri
M
f
1
tt
3
S3
M
S9
|
T
i
H
|
nL
n\ri
\
t-J-i-L.
^TTT
j ^
i I i i
-Lin
m,*i.
i i
I i
NPOES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
*-r
45«T»9«HB
DM
• 1718
QXtt
-------
GCA/TECHNOOGV DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
lU'ioiirlc
I ' I I
1*
SIC CODE
SIC CODE
SIC CODE
FLOW RATE g
c
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
•s
13 *
/7 i8l*U
»ttXV Wp3 30 3i
SB
]7<38 39 40 f 42 U 44 4! « 47 4t «S SQ5I
T&rrr&r*
00,
OO
.^gj/ft
11
1W1I .jcpjgl^
/)/V
ll
MODE OF-
DISCHARGE
UNITS
OF FLOW RATE
RELIABILITY FACTOR OF
FLOW RATE DETERMINATION
CARD
NO.
1 2
CO
3
2
NPDES NO.
4
5
C
7
•
w
1 !
1 1
B
<2
ad
a
M
13
DESCRIPTION OF OUTFALL (CONTINUED)
16
P
18
19
20
N
M
n
A
44-
| j
B
31
B
13
M
J9
)b
ii U
"h
1
9
•0
K
•TTr
1 1 i
t
!
1
f
!
0
B
a
w
„
ni
7 4r*«i)iJit mJ J_
r^r ^/^ra)rt) f f/i^rapj
1 ! ! ' II
i i i i i ! j
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNODGY DMSON
(CARD
NO.
i ;'? 3
CO j
CARD
NO.,
i 2 3
C02
CARC
NO.
.2:
e|..
NPDES
4
5
6
rfjoio
7
a
NO.
9
lojirje
OiOft/j
NPDES
4
rf
S
O
6
o
7
o
a
O
* NPOES
1 4
I
3
«
r
•
4>
NO.
9
•*i
T
"
e
6,
NO.
9
n
ii
e
^0
g*
is
13
C
H
0
IS
3
i-
13
0
M
0
IS
6
k
13
M
s
SIC
16
fi
CODE
I8JI9
20
2?|/j?l
•!
i
22
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
o, 0 o, up— FLOW RATE MEASURED OR ESTIMATED
P o o a 1
* SIC CODE | SIC CODE | FLOW RATE || DESCRIPTION OF OUTFALL
O
2C
V
ilLj
34
32
33
TT
! !
i A
P
3D
ALOE6
i ' i i i " — j " ' : i
rfjfff^ joj^ q^Oj^/jttj^j cjwjf MJ/jc^^jSi i i , i i
MODE OF * UNITS -T * RELIABILITY FACTOR OF
DISCHARGE OF FLOW RATE F«-OW RATE DETERMINATION
DESCRIPTION OF OUTFALL (CONTINUED)
16
n
T
*
a
16
6
19
/
20
C
21
//
lajsjzo
r
n
u
*.
U
0
^
n
A
/?
X
7
27
^
•J-
T
t±a
"r
1
a
5J
'
3)
5
32
53
r
34
/»
a
•
s
B
n
M
JB
D
•
Jb
JT
^ j
30
39
l inJ««Lr ^ «iL-« jLJ», j J-i _,(• Jn.
(ill 1 iii i i i i
•
DESCRIPTION OF OUTFALL (CONTINUED)
K
u
U
i
*
tO If Mtfl M •
^* »• V^w W «
•
a
I 1 1 J 1 ' I 1
1 1 i 1 1 j i i i 1
-------
GCA/TEOflOlDGV DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
(CARD
NO.
NPDES NO.
SIC CODE
SIC CODE
SIC CODE
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
4 5
7 8l
1314
rr|i8|i920?i
a B34H2C2?
BI3
co
i/|g|6jo|Q
CjH|^p/l
Mi
t__ RELIABILITY FACTOR OF
FLOW RATE DETERMINATION
I 1 I I
DISCHARGE
OF" FLOW RATE
NPDES NO.
5
I i
DESCRIPTION OF OUTFALL (CONTINUED)
i
OM
/7
16
»ao>i
KB
M?9H?
SB
JJ4Cf
« O 44 «9 « 47 4| If K U
I I
CARD
NO.
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNOIOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
ARD
NO.
NPDES NO.
SIC CODE
J7|i8|l9|20t?l
SIC CODE
SIC CODE
FLOW RATE *
c
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
1 *
4 5
7 sl9lK>|ifo
13 M
22 23 M » 2t 2?
»i
BBJ4
1371383940
43 « «7 4t It V&
rr^^r
TartwwenrB?
II
%0\*p
w\cmo
-1—L
MODE OF
DISCHARGE
UNITS
OF FLOW RATE
RELIABILITY FACTOR OF
FLOW RATE DETERMINATION
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
I920JI
22
MH2C2
11
LLl
NPOES NO.
s
DESCRIPTION OF OUTFALL (CONTINUED)
4 3 C 7
0ne
13 M
«J7«
»an
i I
-------
GCA/TECHNOIOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
MO.
NPDES NO.
I?
SIC CODE
SIC CODE
SIC CODE
u
FLOW RATE;
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
8l9liO|if|B
u «
I8|l9 JO ?l
Z2 23 M M 2€ 2
BOJ43S*
OT3V940
42I344494(47«(«IS49'
S?JEK4 S3 SBCTH O
I I I I ""^
*liO:-r-tf • tm*>£l~
n
«78?aBC
co
dip
00
It
7H-6
5J0
I\
pm£
MODE OF
DISCHARGE
UNITS
RELIABILITY FACTOR OF
CARD
NO.
NPDES NO.
OF FLOW RATE FLOW RATE DETERMINATION
DESCRIPTION OF OUTFALL (CONTINUED)
CARD
NO.
NPOE8 NO.
DESCRIPTION OF OUTFALL (CONTINUED)
13 M
CO
i i
-------
A, FACILITY DESCRIPTION (CONTINUED)
3, FACILITY DIAGRAM
INTAKE
GENERAL
COOLING
OUTFALLS
001
POTASSIUM
BICHROMATE
PROCESS
CHROMIC
ACID
PROCESS
SODIUM
DICHROMATE
PROCESS
002
003
004
005
006
\/
1 /
THOUSAND GALLONS PER DAY
1,990 390 470 315 7
50
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1, CONSTITUENT DATA FOR EACH OUTFALL
1.1 OUTFALL 001:
CONSTITUENT
Ch romi urn
Lead
Magnes i urn
Cyan i de
F1uor i de
Alumi num
Arsen i c
Ba r i urn
Boron
Cadmi urn
Copper
I ron
Z i nc
Manganese
Mercury
Tin
Tltan i urn
50,00 gallons per day from cooling of
air conditioning equipment.
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
Appl i cat ion
Appl i cat ion
Appl i cat ton
Appl i cat i on
Appl i cat ion
App 1 i cat i on
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
on
on
on
on
on
on
on
on
on
on
on
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.2 OUTFALL 002:
CONSTITUENT
Ch romiurn
Lead
Magnes i urn
Cyan i de
F1uor i de
Alurn i num
Arsenic
Barium
Boron
Cadmiurn
Copper
I ron
Zinc
Manganese
Mercury
Tin
Titanium
1.3 OUTFALL 003:
CONSTITUENT
, Fluoride
Alurn i num
Ba r i urn
Ch romi urn
Copper
I ron
Lead
Magnes i urn
Tin
Ti tan i urn
Z i nc
Phenol
Surfactants
7,000 gallons per day from cooling
of boiler fan room and pumps.
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
App 1 i cat i on
App 1 i cat i on
App 1 i ca t i on
App 1 i cat i on
App 1 i cat i on
App 1 i cat i on
App 1 i cat i on
App 1 i cat i on
Appl i ca t i on
Appl i cat i on
Appl i cat i on
Appl i cat i on
App 1 i cat i on
App 1 i cat i on
Appl i ca t i on
App 1 i cat i on
App 1 i cat i on
315,000 gallons per day from manufac
ture of potass i urn
RE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
b i ch romate .
FERENCE
App 1 i cat i on
App 1 i cat i on
App 1 i ca t i on
App 1 i cat i on
App 1 i cat i on
App 1 i cat i on
App 1 i ca t i on
App 1 i cat i on
Appl i ca t i on
Appl i ca t i on
App 1 i cat i on
App 1 i ca t i on
Appl i cat ion
GCA/TECHNOIQGY DMSQN
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.4 OUTFALL 004: ^70,000 gallons per day from manufac-
ture of chromic acid.
CONSTITUENT REFERENCE
Fluoride NPDES Application
Aluminum NPDES Application
Barium NPDES Application
Boron NPDES Application
Cadmium NPDES Application
Chromium NPDES Application
Copper NPDES Application
Iron NPDES Application
Lead NPDES Application
Magnesium NPDES Application
Manganese NPDES Application
Mercury NPDES Application
Ti n NPDES Application
Titanium NPDES Application
Zinc NPDES Application
Phenol NPDES Application
Surfactants NPDES Application
1.5 OUTFALL 005: 390,000 gallons per day from manufac-
ture of sodium bichromate.
CONSTITUENT REFERENCE
Cyanide DMR
Fluoride NPDES Application
Aluminum NPDES Application
Barium NPDES Application
Cadmium DMR
Boron NPDES Application
Chromium DMR, EPA Publication1
Copper DMR, EPA Publication1
Iron DMR
Lead DMR
Magnesium NPDES Application
Manganese NPDES Application
Mercury NPDES Application
Ti n NPDES Application
Titanium NPDES Application
Zinc NPDES Application
Phenol DMR
Surfactants NPDES Application
Nickel EPA Publication1
Silver DMR, EPA Publication1
Selenium EPA Publication,1
Engineering Judgment3
GCA/TECHNOtOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.6 OUTFALL 006; 1,990,000 gallons per day from manu-
facture of sodium bichromate.
CONSTITUENT REFERENCE
Cyanide DMR
Fluoride NPDES Application
Aluminum NPDES Application
Barium NPDES Application
Cadmium DMR
Boron NPDES Application
Chromium DMR, EPA Publication1
Copper DMR, EPA Publication1
Iron DMR
Lead DMR
Magnesium NPDES Applicat on
Manganese NPDES Applicat on
Mercury NPDES Applicat on
Tin NPDES Appli cat on
Titanium NPDES Applicat on
Zinc NPDES Applicat ion
Phenols DMR
Surfactants NPDES Application
Nickel EPA Publication1
Silver DMR, EPA Publication1
Selenium Engineering Judgment,3
EPA Publication1
OCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
Development Document, including the Data
Base for Effluent Limitations Guidelines (BATEA) ,
New Source Performance Standards for the Inorganic
Chemicals Manufacturer's Point Source Category,
prepared by Jacobs Engineering Group, Inc.,
Pasadena, California, Contract No. 68-01-4492.
2.2 ENGINEERING JUDGMENT
aThis compound was found to be present at only one
of the plants tested as reported in reference 1.
Since all pollutants with potential to be dis-
charged were identified, this compound was assumed
to be presen t .
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT CONCENTRATIONS
1, CONCENTRATION DATA FOR EACH OUTFALL
1.1 OUTFALL 001: 50,000 gallons per day from cooling
CONSTITUENT
Chromi urn
Lead
Magnes i urn
Cyanide
Fluoride
Al umi num
Arsen i c
Barium
Boron
Cadml urn
Copper
1 ron
Zinc
Manganese
Mercu ry
Tin
T i tan i urn
1.2 OUTFALL 002
of air cond \ t i
CONCENTRATION
30 ppb
23 ppb
5 ppm
10 ppb
0 . 8 ppm
90 ppb
1 0 ppb
AO ppb
1 .3 ppb
6.8 ppb
7.0 ppb
228 ppb
34 ppb
1 1 ppb
0.8 ppb
161 ppb
60 ppb
: 7,000 ga 1 Ions
oning equipment.
REFERENCE
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Application
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
per day from cooling of
boiler fan room and pumps.
CONSTITUENT
Ch rom i urn
Lead
Magnes i urn
Cyan i de
Fluoride
Al umi num
Arsen i c
Ba r i urn
Boron
Cadmi urn
Coppe r
1 ron
Zinc
Manganese
Mercury
Tin
T i tan i urn
CONCENTRATION
30 ppb
23 ppb
5 ppm
10 ppb
0.8 ppm
90 ppb
10 ppb
1)0 ppb
1 .3 ppb
6.8 ppb
7.0 ppb
228 ppb
3*» ppb
11 ppb
0.8 ppb
161 ppb
60 ppb
REFERENCE
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl ication
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.3 OUTFALL 003:
315,000 gallons per day from manufac-
ture of potassium bichromate (15 tons/
day)
CONSTITUENT
CONCENTRATION
REFERENCE
Fl uor i de
Al um i num
Bar i um
Ch romi um
Copper
1 ron
Lead
Magnes i um
Tin
Titanium
Zinc
Phenol
Su rf actan ts
1.4 OUTFALL 004:
CONSTITUENT
F 1 uor i de
Al um i num
Bar i um
Boron
Cadm i um
Chromi um
Coppe r
1 ron
Lead
Nagnes i um
Manganese
Mercu ry
Tin
Ti tan i um
Zinc
Pheno 1
Su rf actant s
0.
204
115
3600
18
534
101
363
1350
319
45
10
100
470,
tu re
4 ppm
ppb
Ppb
ppb
Ppb
ppb
ppb
ppb
ppb
Ppb
ppb
ppb
ppb
000 gal Ion
of chromi
NP
NP
DES
DES
NPDES
NP
DES
NPDES
NP
NP
NP
NP
NP
NP
NP
DES
DES
DES
DES
DES
DES
DES
NPDES
s per
c acid
CONCENTRATION
0.
281
92
1800
180
2870
16
887
78
201
286
3.
3430
405
59
10
10
5 ppm
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppm
ppb
5 ppb
ppb
ppb
ppb
ppb
ppb
NP
NP
NP
NP
RE
DES
DES
DES
DES
NPDES
NP
NP
NP
NP
NP
NP
NP
NP
NP
NP
NP
NP
DES
DES
DES
DES
DES
DES
DES
DES
DES
DES
DES
DES
App
App
App
App
App
App
App
App
App
App
App
App
App
day
(50
1
1
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1
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ton
FERENC
Appl i
App
App
App
App
App
App
App
App
App
App
App
App
App
App
App
App
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on
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on
on
on
on
on
on
on
on
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.5 OUTFALL 005:
CONSTITUENT
Cyan i de
Fluoride
Al umi num
Barium
Cadm! urn
Boron
Chrom i um
Copper
1 ron
Lead
Magnes i um
Manganese
Me rcu ry
Tin
Titanium
Zinc
Phenol
Su rf actants
Nickel
Si Iver
Se 1 en i um
ture of
day) .
sod
CONCENTRATION
16
0.5
281
92
22
1 .8
2.1
33
0.58
0.55
208
2kO
3.9
3.*»
405
1 .2
10
10
1.3
228
22
ppb
ppm
PPb
ppb
ppb
ppm
ppm
PPb
ppm
ppm
ppm
ppb
ppb
ppm
ppb
ppm
ppb
PPb
ppiTi
PPb
PPb
390,000 gallons per day from manufac-
urn bichromate (190 tons/
REFERENCE
DMR
Eng i neer i
Eng i neer i
Eng i neer i
DMR
Eng i neer i
DMR, EPA
Eng i neer i
DMR, EPA
Eng i neerI
DMR
DMR
NPDES App
NPDES App
NPDES App
Eng i nee r i
Eng l-neer i
EPA Publi
DMR
Eng i neer i
EPA Publi
EPA Publi
EPA Publi
ng Judgment3
ng Judgment3
ng Judgment3
ng Judgment3
PublI cat ion.1
ng Judgment
Publication,1
ng Judgment^
1i cat i on
1i cat i on
1i cat i on
ng Judgment3
ng Judgment3
cat i on*
ng Judgment3
cat S on -
cation1
cat i on1
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.6 OUTFALL 006:
CONSTITUENT
Cyan i de
Fl uor i de
A1 umi num
Ba r I urn
Cadmi urn
Boron
Chrom i urn
Copper
1 ron
Lead
Magnes i urn
Manganese
Mercury
Tin
Ti tan i urn
Zinc
Phenol '
Surfactants
Nickel
S i 1 ver
Se 1 en i urn
ture of
sod
CONCENTRATI ON
16
0.5
281
92
22
1 .8
2.1
33
0.58
0.55
208
2^0
3.9
3. A
kQ$
1 .2
10 *
10
1.3
228
22
ppb
ppm
ppb
ppb
ppb
ppm
ppm
ppb
ppm
ppm
ppm
ppb
ppb
ppm
ppb
ppm
ppb
ppb
ppm
ppb
ppb
1,990,000 gallons per day
i bichromate
from manufac-
(190 tons/day).
REFERENCE
DMR
Eng i neer i ng
Eng i nee ring
Eng i nee r i ng
DMR
Eng i nee ri ng
Judgment3
Judgment3
Judgment3
Judgment*
DMR, EPA Publicatlon,1
Engineering Judgment"
DMR, EPA PublIcatlon,1
Engineering Judgment"
DMR
DMR
NPDES Application
NPDES Application
NPDES Application
Engineering Judgment3
Engineering Judgment3
EPA Publication1
DMR
Engineering Judgment3
EPA PublIcation1
EPA Publication1
EPA Publicatlon1
GCA/TECHNOtOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
*Draft Development Document including the Data Base
for Effluent Limitations Guidelines (BATEA), New
Source Performance Standards for the Inorganic
Chemicals Manufacturing Point Source Category,
prepared by Jacobs Engineering Group, Inc.,
Pasadena, California, Contract No. 68-01-4492.
2.2 ENGINEERING JUDGMENT
No values given on NPDES or DMR for this outfall.
- Values assumed to be the same as Outfall 004.
Concentration data differed between Discharge
Monitoring Reports (DMR) and literature values.
Since DMR values are measurements of the actual
outfall concentrations, the DMR values were used.
GCA/TECHNOIDGY DIVISION
-------
GCA TKHNODGr- DM3ON
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DETERMINATION OF OUTFALL TUDR
SOURCE.
NPDES PERMIT NO,.
OUTFALL NO,.
FLOW RATE 100.OOP GALLONS PER DAY
A B C D E
CHEMICAL CONSTITUENT CONCENTRATION DMEG VALUE DEGREE OF HAZARD TUDR
(D x FLOW RATE)
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CHROMIUM
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01
TUDR
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FACILITY
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-------
WESTVACO CORP, (MD 1122)
A, FACILITY DESCRIPTION
1, GENERAL FACILITY INFORMATION
Luke Mill
Luke, MD 21562
NPDES No. MD 1422
County Code 2001 (Allegheny County)
Basin No. 02141005
Latitude 39° 3' 17"
Longitude 79° 28' 46"
Major SIC 2611, 2653
Total Flow 3.0 x 107 gallons per day
Kraft Process Pulp and Paper Mill
2, OUTFALL DESCRIPTION
2.1 OUTFALL NO. 1
Flow - 1.0 x 107 gallons per day of treated
process wastewater from NPDES Outfall
Nos. 1, 2, 8, 9, 10, 12, 13, H, 15,
16, 17, 18, 19, 20, 21, and 22
Flow from NPDES Application
2.2 OUTFALL No. 002
Flow - 1.6 x 107 gallons per day of cooling
water from turbine condensers (NPDES
Outfall Nos. 3, 4, 5, and 11)
Flow from NPDES Application
2.3 OUTFALL No. 003
Flow - 3-66 x 106 gallons per day of cooling
water from chiller units of chlorine
dioxide generators (NPDES Outfall Nos. 6, 7)
Flow from NPDES Application
GCA/TECHNOLOGY DIVISION
-------
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OWNER /OPERATOR NAME
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DESCRIPTION OF OUTFALL (CONTINUED)
-------
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-------
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GCA/TECHNOUDGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
(CARD
NO.
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DESCRIPTION OF OUTFALL (CONTINUED)
-------
A, FACILITY DESCRIPTION (CONTINUED)
3, FACILITY DIAGRAM
TURBINES
CONDENSER COOLING WATER
BLEACHED DRAFT
PULP AND PAPER PROCESS
CHLORINE DIOXIDE
GENERATORS
V V
^
3
3-66 x 106 GALLONS PER DAY
1.0 x 107 GALLONS PER DAY
2) 1.6 x 107 GALLONS PER DAY
INTAKE
GCA/TECHNOIQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1, CONSTITUENT DATA FOR EACH OUTFALL
1.1 OUTFALL NO. 1 - 1.0 x 107 gallons per day of
treated process waste
CONSTITUENT
Magnes i urn
Manganese
Me rcury
Nickel
Si 1ver
Potass i urn
Sod i urn
Zinc
Phenol
Dehydroabietic Acid
Monoch1orodehydroabietic Acid
Dich1orodehydroabietic Acid
Tetrachloro-2-methoxyphenol
Tri chloro-2-methoxyphenol
Octadecanoic Acid
Palustric AcJ d
Organ i c N
Ni trate
Ni tri te
Phos phorus
Sulfate
Sulfi te
Sulfide
B romi de
Chloride
Fluor i de
Alumi num
Boron
Ch romi urn
Copper
I ron
P i mar i c Ac i d
Oleic Acid
L i no 1e i c Ac i d
Li nolen i c Aci d
REFERENCE
NPDES
NPDES
NPDES
TAPPI
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
TAPP
TAPP
TAPP
TAPP
TAPP
TAPP
TAPP
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
TAPPI
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
TAPPI
TAPPI
TAPPI
TAPPI
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
i cat i on
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i cat i on
i cat i on
i cat i on
ica 15 on
Appl i c a t
Appl i cat
App 1 i cat
App 1 i cat
Appl
Appl
2
Appl
Appl
Appl
Appl
Appl
ca t
cat
cat
cat
cat
cat
cat
App 1 i ca t
App 1 i cat
Appl i cat
i on
i on
i on
i on
i on
i on
i on
i on
i on
i on
i on
i on
i on
i on
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1.2 OUTFALL NO. 2 - 1.6 x 107 gallons per day of
cooling water from turbine condensers
CONSTITUENT
Sulfate
Sulfite
B romi de
Chloride
Fluor i de
Aluminum
Boron
Ch romi urn
Copper
I ron
Magnesi urn
Manganese
Ti tatan i urn
Zinc
Algee i des
Lead
Cyani de
Arsen i c
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
Appl i
App 1 i
Appl i
Appl i
App 1 i
Appl i
Appl i
Appl i
Appl i
Appl i
Appl i
Appl i
Appl i
Appli
Appl i
Eng i neeri ng
Engineering
Eng i neer i ng
cation
cat i on
cat i on
cat i on
cat i on
cat ion
cat i on
cat i on
cat i on
cation
cat i on
cation
cat i on
cation
cat i on
Judgment3
Judgment3
Judgment3
OCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1.3 OUTFALL NO.
cooli ng
d i ox i de
3 - 3.66 x 106
from chiller
water
gene rators
ga11ons per day of
units of chlorine
CONSTITUENT
Sulfate
Sulfi te
Bromi de
Chloride
Fluori de
Alurn i num
Boron
Chromi urn
Coppe r
I ron
Magnes i urn
Manganese
T i tatan i um
Z i nc
Algee i des
Lead
Cyan i de
Arsen i c
REFERENCE
\
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
Eng i nee r i n<
Eng i neer i n<
Eng i nee r i n(
ca t i on
cat i on
cat i on
cat i on
cat i on
cat i on
cat i on
cat i on
ca t i on
cation
cation
ca t i on
cat i on
cat i on
cat i on
3 Judgment3
3 Judgment3
3 Judgment3
GCA/TECHNOIQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES CITED
1TAPPI, Vol. 60, No. 1, p. 122 (1977).
2TAPPI, Vol. 56, No. 5, P. 135 (1973).
3Marton, J. and T. Marton, "Mercury in the Pulp
and Paper Mill Environment — Appraisal and
Perspective," TAPPI, Vol. 55, No. 11, p. 16H»
(1972).
Bleach, '.J .M. and A.N. Thaakore, "Toxic Constituents
in Mechanical Pulping Effluents," TAPPI, Vol. 59,
No. 2, p. 129 (1976) .
2.2 OTHER LITERATURE REFERENCES USED
5Leach, J.M. and A.N. Thaakore,"I dentification
of the Constituents of Kraft Pulping Effluent
that are Toxic to Juvenile Coho Salmon," Journal
of Fish Res. Board of Canada, Vol. 30, p. 479
(197M-
6C1aeys, R.R., "Analysis of Volatile Halogenated
Organic Compounds in BKME," NCASI Technical
Bulletin No. 298 (August 1977).
7Lindstrom, K. and J. Nordin, "Gas Chromatography/
Mass Spectroscopy of Ch1orophenols in Spent
Liquors," Journal of Chromatography, Vol. 128,
No. 1, p. 13 (1976).
2.3 ENGINEERING JUDGMENT
aCompounds added based on data from other cooling
water discharges.
GCA/TECHNOUOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT CONCENTRATIONS
1, CONCENTRATION DATA FOR EACH OUTFALL
1.1 OUTFALL NO. 1 - 1.0 x 107 gallons per day of
treated process waste
CONSTITUENT
CONCENTRATION
REFERENCE
Magnes i urn
Manganese
Mercury
Nickel
Silver
Potass i urn
Sod i urn
Zinc
Phenol
Dehyd roab i et i c
Acid
Monoch1orodehydroabietic Acid
Dichlorodehydroabietic Acid
Tetrachloro-2-methoxyphenol
Trichloro-2-methoxyphenol
Octadecanoic Acid
Pa 1ustri c Aci d
Ammon i a
Organ i c N
Nitrate
Nitrite
Phosphorus
Sulfate
Sulfite
Sulfide
Bromi de
Chloride
Fl uor i de
Alumi num
Boron
Chromi um
Copper
I ron
Pi mari c Ac i d
Oleic Acid
L i no 1e i c Ac i d
L i no 1 en i c Ac i d
1
1
1
1
0
0
0
0
0
0
.2
.1
100
1
*
1
0
1
5
0
1
0
0
5
5
0
75
1
0
1
1
.6
.1
.3
.4
.0
.0
.0
.0
100
1
1
1
1
1
1
0
0
1
0
0
1
0
0
0
1
1
5
5
5
.1
.4
.0
.0
.0
ppb
ppb
ppb
ppb
ppb
ppm
ppm
ppb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppb
ppb
ppb
ppb
ppm
ppm
ppm
ppm
ppm
ppm
Engi
Engi
Engi
TAPP
Eng i
Engi
Eng i
Eng i
Engi
Eng i
Eng i
TAPP
TAPP
TAPP
TAPP
TAPP
Engi
TAPP
Eng i
TAPP
Engi
Eng i
Eng i
Engi
Engi
Engi
Engi
TAPP
Eng i
Engi
Engi
Engi
Engi
Engi
Eng i
Engi
TAPP
Engi
TAPP
Eng i
TAPP
Eng i
TAPP
neer
neer
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I3
nee
nee
nee
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r
r
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nee
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nee
nee
nee
nee
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J
J
J
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udgment
udgment
udgment
udgment
udgment
udgment
Judgment
Judgment
J
J
J
J
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J
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udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
udgment
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J
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udgment
udgment
udgment
udgment
udgment
ugemen t
a
a
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a
a
a
a
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a
a
a
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a
a
a
a
a
a
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a
a
»
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Judgment ,
a
b
b
b
b
b
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.2 OUTFALL NO. 2 - 1.6 x 107 gallons per day of
cooling water from turbine condensers
CONSTITUENT
Sulfate
Sulfi te
Bromide
Chlor ide
Fluor i de
Alurn i num
Boron
Chromi urn
Copper
I ron
Magnesi urn
Manganese
T i tatan i urn
Zinc
Algee i des
Lead
Cyan!de
Arsen i c
CONCENTRATION
REFERENCE
270
2
8
100
1
0.
10
10
10
0.
1 .
10
10
10
1
10,
10
10
ppm
ppm
ppm
ppm
ppm
ppm
ppb
ppb
ppb
ppm
ppm
ppb
ppb
ppb
ppm
ppb
ppb
ppb
NPOES Appli
NPDES Appli
NPOES Appli
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i neer i ng
cat i on
cat ion
cat i on
Judgment**
Judgment**
Judgment4*
Judgment
Judgment**
Judgment**
Judgment^
Judgmen t
Judgment
Judgment1*
Judgment**
Judgment**
Judgment**
Judgment**
Judgment**
OCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.3 OUTFALL NO. 3 - 3.66 x 106 gallons per day of
cooling water from chiller units of chlorine
dioxide generators
CONSTITUENT
Sulfate
Sulfi te
Bromide
Chloride
Fluor i de
Alurn inum
Boron
Chromi urn
Copper
I ron
Magnes ! urn
Manganese
Ti tatan i urn
Zinc
Al gee i des
Sod i urn
Lead
Cyan i de
Arsenic
CONCENTRATION
REFERENCE
270
2
8
100
1
1
1
1
1
1
1
0.1
0
0
0
0.1
1
0
0
0
1
73
1
1
1
0
0
0
Ppm
ppm
ppm
ppm
ppm
ppm
ppb
ppb
ppb
ppm
ppm
ppb
ppb
ppb
ppm
ppm
ppb
.Ppb
ppb
NPDES App
NPDES App
NPDES App
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
i neer
i neer
i neer
i neer
i neer
i nee r
i nee r
i nee r
i neer
i neer
i nee r
i neer
i
i
i
J
i
i
i
i
i
i
i
i
NPDES App
Eng
Eng
Eng
t neer
i neer
i neer
i
i
i
1 i
1 i
1 i
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
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ng
ng
ca t i on
cat i on
ca t i on
Judgment
Judgment
Judgment
Judgmen t
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
cat ion
J udgmen t
Judgment
Judgment
d
d
d"
d
d
d
d
d
d
d
d
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES CITED
, Vol. 60, No. 1, p. 122 (1977)
2TAPPI, Vol. 56, No. 5, P. 135 (1973)
3Marton, J. and T. Marton, "Mercury in the Pulp
and Paper Mill Env i ronment--Appra i sa 1 and
Perspective," TAPPI, Vol. 55, No. 11, p. 16H»
(1972) .
Bleach, J.M. and A.N. Thaakore, "Toxic Constituents
in Mechanical Pulping Effluents," TAPPI, Vol. 59,
No. 2, p. 129 (1976).
2.2 OTHER LITERATURE REFERENCES USED
5Leach, J.M. and A.N. Thaakore, "Identification
of the Constituents of Kraft Pulping Effluent
that are Toxic to Juvenile Coho Salmon," Journal
of Fish Res. Board of Canada, Vol. 30, p. 479
(197M-
6Claeys, R.R., "Analysis of Volatile Halogenated
Organic Compounds in 6KME," NCAS i Technical
Bulletin No. 298 (August 1977).
7Lindstrom, K. and J. Nordin, "Gas Chromatog raphy/
Mass Spectroscopy of Ch 1 oropheno 1 s in Spent
Liquors," Journal of Ch roma tog raphy , Vol. 128,
No. 1, p. 13 (1976).
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2.3 ENGINEERING JUDGMENTS
•»
Concentrations were estimated based on a small
sample of data from other Kraft process effluents
Literature Reference stated concentrations are
usually less than 5 ppm; therefore, the assumed
5 ppm should be considered a maximum number.
cThe assumed ammonia concentration is based on a
19 mg/1 daily average reported for the Kraft
process effluent at a Chesapeake Bay Corp. of
Virginia Facility (NPDES Permit No. VA 3115).
Assumed concentrations are based on data from
similar cooling water effluents.
GCA/TECHNOLOGY DIVISION
-------
OCA TECHNOUXTT WV1SON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT COOING FORM
DISCHARGE CONSTITUENT INFORMATION
CASC
NO
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GCA TECHNOLOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
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NPDES PERMIT NO,.
OUTFALL NO.
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A B C D E
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2
-------
DUPONT-WAYNESBORO
A, FACILITY DESCRIPTION
1, GENERAL FACILITY INFORMATION
Dupont-Waynesboro
Waynesboro, VA 22980
NPDES Permit No. VA 0002160
County Code 3820
Basin Code IB
Latitude 38° 3' 31"
Longitude 78° 53' 28"
Major SIC 2821
Total Flow 52,000,000 gallons per day
Manufacture of cellulose acetate resin, acrylic
resin and spandex and acrylic fibers
2, OUTFALL DESCRIPTION
2.1 OUTFALL 001:
2.2 OUTFALL 003:
2.3 OUTFALLS
004 AND 007;
10,700,000 gallons per day general
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cellulose acetate resin, acrylic
resins and spandex and acrylic fibers.
Data from NPDES Application.
70,000 gallons per day general process
effluent from manufacture of cellulose
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spandex and acrylic fibers-cooling
water .
Data from NPDES Application.
Identical sources-20 , 600 , 000 gallons
per day of cooling water each.
Data from NPDES Application.
GCA/TECHNOIOGY DIVISION
-------
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GCA/TECHNOtOGV DMSON
SOURCE INVEIMTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
MODE
DISCHARGE
UNIT«!
OF FLOW RATE
RELIABILITY FACTOR OF
F«-OW RATE DETERMINATION
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
CARD
NO.
NPDES NO.
s
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNOOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
MODE OF
DISCHARGE
UNITS -
OF FLOW RATE
.RELIABILITY FACTOR OF
FLOW RATE DETERMINATION
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
CARD
NO.
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S2
DESCRIPTION OF OUTFALL (CONTINUED)
011
13 M
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-------
GCA/TECHNOuOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
SIC CODE
T
SIC CODE
SIC CODE
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FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
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GCA/TECHNOtOGY DMSK3N
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
.s
SIC CODE
SIC CODE
SIC CODE
FLOW RATE g
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-------
A, FACILITY DESCRIPTION (CONTINUED)
3, FACILITY DIAGRAM
INTAKE
RESIN AND FIBER
MANUFACTURER -
PROCESS WASTES
RESIN AND FIBER
MANUFACTURER -
COOLING
COOLING WATER
OUTFALLS
001
003
007
00k
THOUSANDS OF GALLONS PER DAY 20,600
20,600
70
10,700
GCA/TECHNOQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1, CONSTITUENT DATA FOR EACH OUTFALL
1.1 OUTFALL 001:
10,700,000 gallons per day from general
process effluent, manufature of cellu-
lose acetate resin and acrylic resin,
manufacture of spandex and acrylic
fiber.
CONSTITUENT
Chloride
Cyan i de
Chromiurn
Copper
I ron
Magnesi urn
Ti tani urn
Zinc
Phenols
Algicides
Surfactants
Aery Ion i trile
Toluene Diisocyanate
Toluene
Ethylene Di ami ne
Acet i c Ac i d
Acetic Anhydride
Methyl Methacrylate
Acetone Cyanohydrin
REFERENCE
App
App
App
App
App
App
App
App
App
App
App
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
EPA Publi
Eng i neer i
EPA Publi
Eng i neer
EPA Publ
Eng i neer
EPA Publ
Eng i neer
Techn i ca
Techn i ca
Techn i ca1
Techn i ca1
1i cat i on
1icat ion
1
cat on
1 cat on
1 cat on
1 cat on
1 cat on
1 cat on
1 cat on
1 cat on
1 cat on
cation,1
ng Judgment3
cation,2 .
ng Judgment
cation,2
ng Judgment"
cation,2
ng Judgment'5
Literature3
Li terature3
Li terature3
Li terature3
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.2 OUTFALL 003:
70,000 gallons per day from general
process effluent, manufacture of
cellulose acetate resin and acrylic
resin, manufacture of acrylic fiber-
coo ling water
CONSTITUENT
Sulfide
Chlorine
Iron
Phenols
Chromium
Copper
Zinc
REFERENCE
NPDES Application
NPDES Application
NPDES Appl i cat ion
NPDES Application
NPDES Application
NPDES Application
NPDES Appl ication
1.3 OUTFALL 004;
20,600,000 gallons per day from
coo ling wate r
CONSTITUENT
Sulfite
Chloride
Zinc
Phenols
REFERENCE
NPDES Application
NPDES Application
NPDES Appl 5 cat ion
NPDES Application
1.4 OUTFALL 007
20,600,000 gallons per day from
cool i ng water
CONSTITUENT
Sulfite
Chloride
Zinc
Phenols
REFERENCE
NPDES Application
NPDES Application
NPDES Appl ication
NPDES Application
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Synthetic Resins Segment of the Plastics
and Synthetic Materials Manufacturing Point Source
Category, EPA-UO/1 -74-01 Oa , March 1971*.
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Synthetic Polymers Segment of the Plastics
and Synthetic Materials Manufacturing Point Source
Category, EPA-440/1 -75-036b, January 1975.
3Sittig, M., Pollution Control in the Plastics and
Rubber Industry, Noyes Data Corporation, 1975.
2.2 ENGINEERING JUDGMENTS
The general category of acrylic fibers is based
on polyacryIonitrile for which aery 1 onitri1e is a
raw material. It was assumed that this raw material
may exist in the discharge from spills, washouts,
etc.
These compounds are used in the production of
Spandex and may, similarly, be present in the
effluent due to spills, washouts, direct process
wastes, etc .
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT CONCENTRATIONS
1, CONCENTRATION DATA FOR EACH OUTFALL
1.1 OUTFALL 001:
10,700,000 gallons per day from
general process effluent, manufacture
of cellulose acetate resin and acrylic
resin, manufature of spandex and acrylic
fiber
CONSTITUENT
Chloride
Cyan i de
Chromi urn
Copper
I ron
Magnesi urn
Ti tan i urn
Zinc
Pheno1s
Alg i c i des
Surfactants
Aery 1 on i t r i1e
Toluene Diisocyanate
Toluene
Ethy1ene Di ami ne
Acetic Acid
Acetic Anhydride
Methyl Methacrylate
Acetone Cyanohydrin
CONCENTRATION
REFERENCE
42
0.05
90
2k
380
20
264
60
70
0.067
0.15
100
. 100
100
100
78
48
1500
100
ppm
ppm
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppm
ppb
ppb
ppb
ppb
ppm
ppm
ppm
ppb
NPDES Appl icat ion
NPDES Appl icat ion
NPDES Appl i cation
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
EPA Publ ication,1
Engineering Judgment3
EPA Publ ication,1
Engineering Judgment
EPA Publ ication,1
Engineering Judgment3
EPA Publ i cat ion , 1
Engineering Judgment"
Technical Literature,2
Engineering Judgment0
Technical Literature,2
Engineering Judgment0
Technical Literature.2
Engineering Judgment
Technical Literature,2
Engineering Judgment6
GCA/TECHNOIQGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.2 OUTFALL 003:
70,000 gallons per day from general
process effluent, manufacture of
cellulose acetate resin and acrylic
resin, manufacture of acrylic fiber-
coo ling water
CONSTITUENT
Sulfi de
Chlorine
I ron
Phenols
. Chromi urn
Coppe r
Zinc
CONCENTRATION
7 PPm
1 .2 ppm
5k ppb
36 ppb
173 ppb
2 ppb
50 ppb
REFERENCE
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Appli cat i on
1.3 OUTFALL 004:
20,600,000 gallons per day from
cooli ng water
CONSTITUENT
Sulfite
Chloride
Z i nc
Phenols
CONCENTRATION
1 .1
2
30
10
ppm
ppm
ppb
ppm
REFERENCE
NPDES Application
NPDES Application
NPDES Application
NPDES Application
1.4 OUTFALL 007:
20,600,000 gallons per day from
cooli ng water
CONSTITUENT
Sulfi te
Chlor ide
Zinc
Phenols
CONCENTRATION
1
2
30
10
ppm
ppm
ppb
ppm
REFERENCE
NPDES Application
NPDES Application
NPDES Application
NPDES Application
GCA/TECHNOiOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
1Memo from M. Dean Neptune to R.B. Schaffer,
Effluent Guidelines Division. Tabulation of
Priority Pol 1 utant ""Occur rences in Each Industry
Category, November 13, 1978.
2Sittig, M., Pollution Control in the Plastics
and Rubber Industry, Noyes Data Corporation,
1975.
2.2 ENGINEERING JUDGMENTS
Concentration data for aery 1 on i t r i 1 e and toluene
could not be found. However, from Reference. 1,
acrylon i tr i le was found in the effluent of some
facilities in the Organic Chemicals and Plastics
Industry at concentrations exceeding 10 ppb. A
value of 100 ppb was assumed.
Concentration data for toluene diisocyanate and
ethylene diamine were not available. To be con-
sistent with other assumptions, a value of 100 ppb
was chosen for the concentrations of these two
compounds .
Reference 2 reported that in the production of
cellulose acetate resin approximately 99.8 per-
cent of the acetic acid used is recycled. The
remaining 0.2 percent is presumably lost in the
wastewater. Part of this loss Is actually acetic
anhydride. Approximately 3.25 lb of acetic acid
and 2 lb of acetic are used to produce 1 lb of
cellulose acetate. Also, approximately 5,000
gallons of wastewater are generated per 1,000 lb
of resin. The following calculation was used to
determine the concentration of the acid and
anhyd ride:
"*
ppm
x
5
lb
0.2%
1
.25
lb
aceta
loss
00
te
x
• x
1
mi
1
000
5000
O6 lb
1 1
i on
lb
ga
lb
aceta
1 wa
te
53
te
r
8. 3 1 b water
GCA/TECHNObOGY DIVISION
-------
C, DETERMINATIONS OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
This value was assumed to be the total acetic
acid plus anhydride in the effluent. The anhydride
concentration was determined from the ratio of the
anhydride to the total; i.e.:
2
ppm anhydride = •?—=-7- x 253 = 96
j • t- y
The remaining 157 ppm were taken to be acetic acid.
Good production and flow data for this specific
process were not available. A dilution factor of 2
(when mixed with other process streams) was there-
fore assumed. The final concentrations are there-
fore J»8 ppm acetic anhydride and 78 ppm acetic acid
Reference 2 reports that wash water from the produc-
tion of acrylic resins contains about 1.5 percent
monomer (methyl methacry1 ate). This corresponds
to 15,000 ppm. Since some degree of control is
likely applied and since this wastewater is diluted
with other streams at the plant, the concentration
was diluted by a factor of 10 to give a final con-
centration of 1,500 ppm.
eConcentration data for acetone cyanohydrin were
not available. A value of 100 ppb was assumed
to be consistent with other assumptions.
GCA/TECHNOOGY DIVISION
-------
OCA TBDHNCXOGY DIVHON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
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GCA. TECHNOiOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
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'•- t
| 1
; :
^.
m' i
"~
i
-
—
4
,.j
'*»
;
i
— -
i
j i i
j
•
4—
i •• i
i : i ;
1
i
,_
1
i
1
-1
"
i
i
!
» !
I
i
.
i
~-t
j
-------
DETERMINATION OF OUTFALL TUDR
SOURCE.
NPDES PERMIT NO,.
OUTFALL NO.
FLOW RATE 1QQ.QQQ GALLONS PER DAY
A B C D E
CHEMICAL CONSTITUENT CONCENTRATION DMEG VALUE DEGREE OF HAZARD TUDR
(D x FLOW RATE)
EXAMPLE:
CHROMIUM
1 X 10
-6
1 X 10
-3
(B/C)
1 x 10"3
1 x 10H
o
CONSTITUENT N
OUTFALL
= 7 X 10'
DETERMINATION OF FACILITY TUDR
OUTFALL NO,
EXAMPLE:
oT
TUDR
7 X 102
8
OUTFALL N
J>DR]
FACILITY
= 8,1 x 102
-------
BETHLEHEM STEEL (MD 1201)
A, FACILITY DESCRIPTION
1, GENERAL FACILITY INFORMATION
Bethlehem Steel Corp.
Sparrows Point, MD
NPDES No. MD 0001201
County Code 2005
Basin Code 02130903
Latitude 39° 12' 54"
Longitude 76° 27' 47"
Major SIC 3312
Total Flow 8.11 x 108 gallons per day
Iron and Steel Manufacturing 12,000 tons per day
production
2, OUTFALL DESCRIPTION
2.1 OUTFALL NO. 1
Flow - A.36 x 10® gallons per day wastewater
and cooling water from Iron and steel
p roduct i on
2.2 OUTFALL NO. 002
Flow - 3.6 x 106 gallons per day of wastewater
from sintering operation
2.3 OUTFALL NO. 003
Flow - 6.9 x 105 gallons per day of wastewater
from sintering operation
2.4 OUTFALL NO. 004
Flow - 3-3 x 105 gallons per day of wastewater
from sintering operation
GCA/TECHNOOGY DIVISION
-------
A, FACILITY DESCRIPTION (CONTINUED)
2.5 OUTFALL NO. 007
Flow - 1.0 x 106 gallons per day of sulfuric
acid plant wastewater intermittent
storm flow
2.6 OUTFALL NO. 008
Flow - 1.M x 106 gallons per day of sulfuric
acid plant wastewater/coo1ing water and
intermittent storm flow
2.7 OUTFALL NO. Oil
Flow - 2.9 x 107 gallons per day of wastewater/
cooling water from coke production and
coke byproduct plant
2.8 OUTFALL NO. 12
Flow - 1.4 x 108 gallons per day of wastewater
from steel manufacture
2.9 OUTFALL NO. 13
Flow - 3.4 x 107 gallons per day of wastewater/
cooling water from hot forming and
pi ck1 ing
2.10 OUTFALL NO. 16
Flow - 7.2 x 103 gallons per day - intermittent
storm flow
2.11 OUTFALL NO. 17
Flow - 1.4 x 106 gallons per day of cooling water/
wastewater from galvanizing operation and
intermittent storm flow
2.12 OUTFALL NO. 18
Flow - 5-0 x 101* gallons per day of cooling water,
water treatment filter backwash and inter-
m i ttent storm f1ow
GCA/TECHNOIQGV DIVISION
-------
GCA TECHNODGY DIVISION
SOURCE INVENTORY/ TOXIC DISCHARGE
INPUT CODING FORM
GENERAL FACILITY INFORMATION
MAJOR INDICATOR-
CARD
NO.
NPDES NO.
SOURCE NAME
OWNER /OPERATOR NAME
73
«3
67
3JM|is|i6 i7jiBJi»|g) 21 zaa » ajzy? 49P° >p[
ig£^3^ti|4^«^^"^|B^^H5^^
H^M/?MU% MOMl\ I i I I i i i I I ! i i I i I I I I . I i M , . i ! i : i i
isioji
CARD
NO.
NPOES NO.
T~
7 a
STREET
I i i i i i I I t i •
J|K IS l£ f7|l9 /9l20?l 2X3
T inriT1
CITY
ZIP
CODE
LATITUDE
d d m mi• s
LONGITUDE
dd
d m
n •
35
9i«
IH » 2' M 29 » 34
33 M
a a s? SOB t n
oM
t.'j
Oi7
i 1 / i
-------
GCA/TECHNOtOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
FLOW RATE |
1
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
MODE OF
DISCHARGE
UNITS-
OF FLOW RATE
FLOW RATE DETERMINATION
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
.F,
liH
I920M
SO*
fl
34 35 56 JT 31 39 40 tl
iM Atvs?^sasfea^n|7^7^?^^ffiL^kj
I i i i i i : i : i '•
C|0
i
Ti&fi
fy*&
I I 1 I
c^°
i 2
CO
3
9
NPOES NO.
4
3
<
T
•
S
0
ulc
1
j
OUTMLL
I.D. MO.
I]
H
IS
DESCRIPTION OF OUTFALL (CONTINUED)
"F
• 4°
1 i!
ft
brio
T
iJi
u
Mi
X
B
a
M
•
»
H
u
a
40
H
m
a
«
«
•
a
«
•
K
nkzuWss
up men
ill!
VI
Tn^
! I 1
i i i
t
| |
i
i
i i
j
i i
-------
GCA/TECHNOOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
MODE OF
DISCHARGE
UNITS -
OF FLOW RATE
RELIABILITY FACTOR OF
FLOW RATE DETERMINATION
NPDES NO.
s
DESCRIPTION OF OUTFALL (CONTINUED)
is
s*
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNOiOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
(CARD
NO.
NPDES NO.
s
SIC CODE
12
SIC CODE
SIC CODE
§
J7J38
FLOW
£
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
8l9|K>|lfB
UM
J7|l8|l920?l
-+-
2<» a 2?
SB
3940
42k!44494l(74(4gxbi
rt !._. . — — — — —
-t-
co
Mp
q^'frt
00
JL
Mlok-
ii«io
j.
K)
liaT
OiRiiMfr
!Eii
1
I.I 1 i I i i
MODE OF T UNITS-T t RELIABILITY FACTOR OF
DISCHARGE OF FLOW RATE FLOW RATE DETERMINATION
CARD
NO.
I 2
CO
3
Z
NPDES NO.
4
5
•
7
I
9 OJH
1 i
e
it
is
ii
M
13
DESCRIPTION OF OUTFALL (CONTINUED)
«p
j
16
19
20
»
U
M
»
2t
2'
J..
2^9
i
B
J
BB3
M
35
T
1 i
M
39
4ol
t/
(2
O
44
+
47
«
TT
| -.(•••
I.
KIN
1
JwL
Tr
1
J.,
S^M
1
I
f
1
i
«
S
a
V
S3
i
T
!
a
irJrrJTil- j" ^>^Thr n
wj"^n|nq/qA
1 ! ' ' • '
1 1 i , i l i i
11.
raraoj
i i
CARD
NO.
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNOtOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
TH
s
SIC CODE
SIC CODE
SIC CODE
J7J38
FLOW RATE g
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
,LLJJ.,' -JZL
T72J73WVrJ777Bf7
:2|3
4 5
»|9'IO|I
I i I
IJM
16 tf I8|I920?I
22 B 24 H 26 27
39«
C^Ojl
Nqo|0|Oi'No|«
oo»4
Mia,
l
I I A.
o|ri, jMift|f)|0|FiAiq
i i,
MODE OF
DISCHARGE
iiNms-T -c RELIABILITY FACTOR OF
OF FLOW RATE FLOW RATE DETERMINATION
•
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
C^
ft
OM
(8
(920M
22 B 24 » 2C 2
38J)«0*l
itfawrA
r,
ii
CARD
NO.
NPOES NO.
s
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNCXQGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
MODE
MUUt
DISCHARGE
iiNi-n?
UNITS
OF FLOW RATE
i-i nui nA-rp nr-Tr-r>t
7
•
f
O
II le
I
i
I*
13
M
e
DESCRIPTION OF OUTFALL (CONTINUED)
*l
i
ifljojzc
i i
»
r4n
I
^
^
PI
ff
•
B
B
S
B
n
^
in
•r
r
U
X
«
II
•
a
«4
a
•
a
•
t
1
j
w
B
4f
i i I
K
TT
I 1
j i
B
j
1
I
1
1 |
. . T
- ^P
i i ! I
-------
GCA/TECHNOLOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
MODE OF
DISCHARGE
NPDES NO.
HNi-re-T T= RELIABILITY FACTOR OF
OF FLOW RATE FLOW RATE DETERMINATION
DESCRIPTION OF OUTFALL (CONTINUED)
*
UM
ff 18
I9ZON
SB
i x a jo 3i
SIM
*r
LI HAG
r*
7&
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNCXOGY DIVISION
MO. NPDES NO.
i ;2 3
cjoi
CARD
NO.
i 2.3
C02
i 2 :
C|0:
4
5
6
7
8
9
MDJOJ3JOJI
NPDES
4
5
6
7
1
1
' NPDES
4
1
9
C
7
•
10
a
ir
o
e
i
NO.
»
_J
o
i
It
e
NO.
9
a
II
e
OUTFALL
1.0. NO.
13
0
M
I
1}
1
OUTFALL
I.D. Na
a
M
19
ii
13
M
0
SIC
16
3
rr
18
CODE
19
20
3\\
?>
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
Oi o o imp— FLOW RATE MEASURED OR ESTIMATED
O Q 0 0
* SIC CODE | SIC CODE § FLOW RATE || DESCRIPTION OF OUTFALL
&
o
24
?5
?€
27
*Ju
*f
31
Ci3J4J^36J7
; 1
A
38
39
to
«e
37
Lj k_
4344
?jf
49
7
41
47
I
^CjOKe' JAjUP > RjOlO jM|A}OUfjfr&|ruR|,|U|
-------
GCA/TECHNOtOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
i :? 3
NPDES NO.
< 5 6 T alsiioire
sio'
o
o.-
13 M IS
SIC CODE
16 J7|I8|I920?I
SIC CODE
M»2C2
SIC CODE
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
BJ3
«J
9rorJr^3MrMif.K7
jo I o I a. 3
Ffl
ffild
I_L
MODE OF
DISCHARGE
UNITS
OF FLOW RATE
RELIABILITY FACTOR OF
FLOW RATE DETERMINATION
CARD
NO.
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
4
13 M
1920?!
M 29 ZC 2
BUM
33 K PP» j) «C «i <
i_i
I i
CARD
NO.
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TKHNCHOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
«S
is
sic CODE
SIC CODE
§
SIC CODE
§
FLOW RATES
£
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
4 5
8l9lK>
ine
13 M
/7|i8|l920fl
Vt
J7J383S40W
A «9 ««7 Jrei76l77}7B?'^
HDD
01
L
M
njo
M
i.i—i—i—i—i i • i i
f RELIABILIT
I_L
MODE OF
DISCHARGE
UNITS
OF FLOW RATE
Y FACTOR OF
FLOW RATE DETERMINATION
NPDES NO.
s
DESCRIPTION OF OUTFALL (CONTINUED)
%
13H 15
1718
I920N
n a » » »z
383840H
SDW
I_L
l i
CARD
NO.
NPDES NO.
§s
DESCRIPTION OF OUTFALL (CONTINUED)
45(7190 II
n M a
-------
GCA/TKHNOIOGY DIVISION
SOURCE INVENTORY /TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
NPDES NO.
MODE OF
UNITS
DISCHARGE OF FLOW RATE FLOW RATE DETERMINATE
DESCRIPTION OF OUTFALL (CONTINUED)
C02
NPDES NO
S3
DESCRIPTION OF OUTFALL (CONTINUED)
-------
OCA /TECHNOLOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
(CARD
NO.
NPDES NO.
s
Ui
SIC CODE
SIC CODE
SIC CODE
FLOW RATE |
f •• -.. - yn— S
FLOW RATE MEASURED OR ESTIMATED
!? J
4 3
7a9
liojifg
13 X
J7|i8|l5»?l
Z2 Q M M 2€ 2
SB
37VJ8 35«OHCC*(4J4«<7«|4)SC<5(
MJD
1
MH-fo
MODE OF
DISCHARGE
iiMiTt:-r -= RELIABILITY FACTOR OF
OF FLOW RATE FLOW RATE DETERMINATION
CARD
NO.
NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
4
a«
UM
1718
1920?)
n a » » a z
940HI
CO
2^ booo >|a{g
PWo
C5
IX
STteis
CARD
NO.
NPOES NO.
S
§5
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GO* /TECHNOtOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
NPOE8 NO.
is
Is
MODE OF _ UNITS - RELIABILITY FACTOR OF
DISCHARGE OF FLOW RATE pLOW RATE DETERMINATION
DESCRIPTION OF OUTFALL (CONTINUED)
erne
13 MQ
•pnsuon
-------
A, FACILITY DESCRIPTION (CONTINUED)
3, FACILITY DIAGRAM
OUTFALL NO.
1
2
3
4
7
8
11
12
13, 14, 15
16
17
18
USAGE
Iron and Steel
Manufacture
S i nteri ng Operat ion
Sintering Operation
S i nteri ng Operat ion
Sulfuric Acid Plant
and Storm Water
Sulfuri c Acid Plant
and Storm Water
Coke Production
(Quenching) and Coke
Byproduct Plant
Iron and Stee 1
Manufacture
Hot Forming and
Pickling
Intermi ttent Storm
Fl ow
Galvanizing and Inter-
mittent Storm Flow
Water Treatment Filter
Backwash and Storm
Flows
QUANTITY
(gpd) RECEIVING BODY
4.36 x 108 Old Road Bay
3.6 x 106 Patapsco River
6.9 x 105 Patapsco River
3.3 x 105 Patapsco River
1.0 x 106 Patapsco River
1 .kk x 106 Patapsco River
2.9 x 107 Patapsco River
1 . I* x 108 Patapsco River
3.A x 107 Patapsco River
Bear Creek
7.2 x 103 Jones Creek
.4 x 106 Jones Creek
5.0 x 101* Bear Creek
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1, CONSTITUENT DATA FOR EACH OUTFALL
1.1 OUTFALL NO. 001 - 5.0 x 10 gallons per day of
wastewater and cooling water from iron and
steel production
CONSTITUENT
REFERENCE
Phosphate (as
Organic Nitrogen las N£)
Ammon i a
Cyan i de
Sulfate (as NaaSO^)
Phenol
Mercury
Hydrogen Su1f i de
I ron
Zinc
Copper
Lead
Cadrnj um
Chromi um
Oi1 and Grease
Fluor i de
Ant i mony
Arsen i c
Be ry11i um
Nickel
Se1 en i um
Si 1ver
Tha11i um
Acenaphthene
Ac ry1 on i t r i1e
Benzene
Benz i d i ne
Carbon Tetrachloride
Hexachlorobenzene
Di chloroethane-1 ,2
Trichloroethane-1 , 1 ,1
Trichloroethane-1 ,1 ,2
Tetrach1 oroethane-1,1 ,2,2
Chloronaphthalene-2
Trichloropheno1-2,l»,6
Pa rach1orometacreso1
Chloroform
Ch1oropheno1-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
NPDES Apr
NPDES Ap|
NPDES Ap[
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Apr
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES API
NPDES Ap|
NPDES Ap|
NPDES Ap|
NPDES Ap|
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
EPA Publ
J 1 i C c
Jl \Ci
j 1 i a
Jl \Ci
3 ] I C c
jl i c<
Jl \Ci
Jl \Ci
jl ic<
Jl \Ci
Jl ic«
Jl ic<
Jl ic«
Jl i C<
Jl I Cc
Jl ic«
Jl ic<
Jl ic<
?i : - -
1 1 I* C
Jl ic<
jl ic<
jl ic;
Jl ic«
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
cat
at i or
3t ior
it ior
)t i or
at ior
3t ior
Jtior
at i or
at ior
3t ior
at ior
Jtior
atior
Jtior
a t i or
Jtior
Jtior
Jtior
i t i or
Jtior
Jtior
Jtior
Jtior
on 1
on1
on 1
on 1
on1
on1
on1
on 1
on1
on1
on *
on1
on1
on 1
on1
on 1
on1
i
i
^
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
GCA/TECHNOIQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
D!ch1orobenzene-para
Vinylidienechloride
Trans-d!chloroethylene-1,2
Dlchlorophenol-2,4
Dimethyl phenol-2,4
Di ni trotoluene-2,6
Dipheny1hydrazine-1,2
Ethyl Benzene
Fluoranthene
Di ch1orobromomethane
Isophorane
Naphtha 1ene
Nitrophenol-2
Ni trophenol-k
Nitrophenol-P
Dinitro-O-cresol-4,6
Pentach1oropheno1
Phenol
Bls(2-ethy1hexyl)phthalate
Butylbenzylphthalate
Di-N-butylphthalate
Di-N-octy1phthalate
Diethylphthalate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11,12
Chrysene
Acenaphthy1ene
Anthracene
Benzoper1i ne
Fluordene
Phenathene
Dibenzo(A,11)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
REFERENCE
EPA Publication1»2
EPA Publication1 >2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1 »2
EPA Publication1» 2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1'2
EPA Publication1 »2
EPA Pub!ication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1 » 2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1'2
EPA Publication1>2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA PublIcation1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1 »2
OCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.2 OUTFALL NO. 002 - 3.17 x 106 gallons per day of
wastewater from sintering operation.
CONSTITUENT
Phosphate (as
Organic Nitrogen (as
Ammoni a
Cyanide
Sulfate (as Na2SOit)
Phenol
Me rcu ry
Hydrogen Sulfide
I ron
Zinc
Copper
Lead
Cadmi urn
Chrom!urn
Oil and Grease
Fluor i de
Ant i mony
Arsen i c
Bery11i urn
Nickel
Se1 en i urn
S i1ve r
Tha11i urn
Acenaphthene
Aery Ion i trile
Benzene
Benz i dIne
Carbon Tetrach1 oride
Hexach1orobenzene
Dichloroethane-1 ,2
Trichloroethane-1 ,1 ,1
Trichloroethane-1 ,1 ,2
Tetrachloroethane-1,1 ,2,2
Chloronaphthalene-2
Trichlorophenol-2,A,6
Pa rach1orometacresol
Chloroform
Chlorophenol-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
Appl i cat on
App1i cat on
App1i cat on
Appli cat on
Appli cat on
Appli cat on
Appli cat on
Appli cat on
Appli cat on
Appli cat on
Appli cat on
App1i cat on
App1i cat on
Applicat on
App1i cat on
Appli cat on
Appli cat on
Appli cat on
Appli cat on
App1i cat on
Appli cat on
Appli cat on
Appli cat i on
Publication1>2
Publi cat i on1» 2
Publication1»2
Publication1»2
Publication1»2
Publication1'2
Publication1'2
Publication1»2
Publication1'2
Publication1'2
Publi cation1»2
Publication1»2
Publication1'2
Publication1'2
Publication1'2
EPA Publication1'2
EPA Publication1'2
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
Olchlorobenzene-para
VinylIdienechloride
Trans-dlchloroethylene-1,2
Dlchlorophenol-2,k
Dimethylphenol-2,4
Di nltrotoluene-2,6
Dlphenylhydrazine-1,2
Ethyl Benzene
Fluoranthene
Dlch1orobromomethane
Isophorane
Naphthalene
Ni trophenol-2
Ni trophenol -k
NI trophenol-P
Dinitro-0-cresol-A,6
Pentach1orophenol
Phenol
Bis(2-ethylhexyl)phthalate
Butyl benzylphthalate
Di-N-butyIphthalate
Di-N-octyIphthalate
Diethy1phthalate
Dimethy1phtha1 ate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11,12
Chrysene
Acenaphthylene
Anthracene
Benzoper1 Ine
F1uordene
Phenathene
Dibenzo(A,1l)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
TrIchloroethylene
Pyrene
REFERENCE
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1 >2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1 »2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publi cation1» 2
EPA Publication1»2
EPA Publication1'2
EPA Publi cation1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1.2
EPA Publication1'2
EPA Publicat ionl»2
EPA Publication1.2
EPA Pub 1i cat ion1»2
EPA Publication1'2
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.3 OUTFALL NO. 003 - 6.9 x 105 gallons per day of
wastewater from sintering operation
CONSTITUENT
Phosphate (as NaH2POit)
Organic Nitrogen, (as N2)
Ammonia
Cyan i de
Sul fate (as Na2SOit)
Phenol
Me rcury
Hydrogen Su1f i de
I ron
Z i nc
Copper
Lead
Cadmlurn
Chromi urn
Oi1 and Grease
Fluor i de
Ant i mony
Arsen i c
Be ry11i urn
Nickel
Se1 en i urn
Silver
Acenaphthene
Ac ry 1 on i t r i 1 e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1,2
Trichloroethane-1
Trichloroethane-1
1,1
1 ,2
Tetrachloroethane-1,1,2,2
Chloronaphthalene-2
Trichlorophenol-2,4,6
Parach1orometacreso1
Chloroform
Ch1orophenol-2
Dlchlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
NPDES Application
NPDES Application
NPDES Applicat ion
NPDES Application
NPDES Application
NPDES Appl icat ion
NPDES ApplIcation
NPDES Applicat ion
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES ApplIcation
NPDES Application
NPDES Applicat ion
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
EPA Publication1»2
EPA Publication1.2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1 '2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1'2
GCA/TECHNOOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
Dlchlorobenzene-para
VinylIdienechloride
Trans-dichloroethylene-1,2
Dlchlorophenol-2,^
Dimethyl phenol-2,A
DInltrotoluene-2,6
Dipheny1hydrazIne-1,2
Ethyl Benzene
Fluoranthene
DIchIorobromomethane
Isophorane
Naphthalene
Ni trophenol-2
Ni trophenol -*»
NItrophenol-P
DInitro-0-cresol-A,6
Pentachlorophenol
Phenol
Bis(2-ethylhexyl)phthalate
Buty1 benzylphthai ate
DI-N-butylphthalate
Di-N-6cty1phthalate
Di ethylphthalate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzof1uoranthene-3,^
Benzofluoranthene-11,12
Chrysene
Acenaphthylene
Anthracene
Benzoper1i ne
Fluordene
Phenathene
Dibenzo(A,11)Anthracene
Indeno(1,2,3~CD)Pyrene
Tetrachloroethylene
To 1uene
Trichloroethylene
Pyrene
REFERENCE
EPA Publication1»2
EPA Publi cation1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publi cation1»2
EPA Publication1 »2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publi cation1»2
EPA Pub.l ication 1 >2
EPA Publication1»2
EPA Publication1'2
EPA Publi cation1»2
EPA Publ ication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publi cation1»2
EPA Publi cation1>2
EPA Publi cation1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1 '2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1»2
EPA Publ ication1 »2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.4 OUTFALL NO. 004 - 3.3 x 105 gallons per day of
wastewater from sintering operation
CONSTITUENT
Phosphate (as
Organic Nitrogen (as N2)
Ammoni a
Cyan i de
Sulfate (as Na2SOlt)
Phenol
Mercury
Hydrogen Sulfide
I ron
Zinc
Copper
Lead
Cadmlurn
Chromiurn
011 and Grease
FluorIde
Ant i mony
Arsen i c
Be ry11i urn
Nickel
Selenium
S i1ver
Tha i1i urn
Acenaphthene
Aery 1 on i t r i1e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexach1orobenzene
Dichloroethane-1 ,2
Trichloroethane-1 ,1 ,1
Tr i chloroethane-1 ,1,2
Tetrachloroethane-1,1,2,2
Chloronaphthalene-2
Trichlorophenol-2,4,6
Pa rach1orometacreso 1
Ch1oroform
Ch1orophenol-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
NPDES Applicat ion
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Appl icat ion
NPDES Application
NPDES Application
NPDES Appli cation
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
Publication1'2
Publication1'2
Publication1'2
Publication1 »2
Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA PublicatJon1'2
EPA Publication1'2
EPA Publication1'2
EPA
EPA
EPA
EPA
EPA
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
i)fchlorobenzene-para
VinylIdienechloride
Trans-dlchloroethylene-1,2
DIchlorophenol-2,k
Dimethyl phenol-2,A
DIn i trotoluene-2,6
Diphenylhydrazine-1,2
Ethyl Benzene
F1uoranthene
Dlchlorobromomethane
Isophorane
Naphtha 1ene
Ni trophenol-2
Ni trophenol-A
Ni trophenol-P
Dini tro-O-cresol-^,6
Pentachlorophenol
Phenol
BIs(2-ethylhexyl)phthalate
Butylbenzylphthalate
Di-N-butylphthalate
Di-N-octylphthalate
Diethy1phthalate
Dimethylphtha1 ate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-Sf^
Benzofluoranthene-11,12
Chrysene
Acenaphthylene
An th racene
Benzoper1i ne
Fluordene
Phenathene
Di benzo(A,11)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
Tri chloroethy1ene
Pyrene
REFERENCE
EPA Publication1 »2
EPA Publication1'2
EPA PublI cation1*2
EPA Publication1 »2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1 »2
EPA Publi cation1'2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1'2
EPA Publi cation1 »2
EPA Publication1 »2
EPA Publication1 »2
EPA Publication1 »2
EPA Publicat ion1 »2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publicatiori1 »2
EPA Publication1'2
EPA Publication1»2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1 »2
EPA Publicat ion1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
GCA/TECHNOIQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.5 OUTFALL NO. 07 - 1.0 x 106 gallons per day of
sulfuric acid plant wastewater and intermittent
storm flow
CONSTITUENT REFERENCE
Oil and Grease NPDES Application
Iron BSC(3)
Antimony NPDES Application
Arsenic NPDES Application
Copper BSC(3)
Cyanide BSC(3)
Cadmium BSC(M
Chromium BSC(4)
H2S BSC(3)
Lead BSC(3)
NH3 as N BSC(3)
Sulfate BSC(3)
Zinc BSC(3)
Phenol BSC(3)
1.6 OUTFALL NO. 08 - 1.H x 106 gallons per day of
sulfuric acid plant wastewater/cooling water and
intermittent storm flow
CONSTITUENT REFERENCE
Oil and Grease NPDES Application
Iron BSC(3)
Antimony NPDES Application
Arsenic NPDES Application
Copper BSC(3)
Cyanide BSC(3)
Cadmium BSC(M
Chromi urn BS C(4)
H2S BSC(3)
Lead BSC(3)
NH3 as N BSC(3)
Sulfate BSC(3)
Zinc BSC(3)
Phenol BSC(3)
GCA/TECHNOIDGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.7 OUTFALL NO. Oil - 2.9 x 107 gallons per day of
wastewater/cooling water from coke production
and coke byproduct plant
CONSTITUENT
Phosphate (as NaH^
Organic Nitrogen (as I
Ammon i a
Cyan i de
Sul fate (as Na2SOi,)
Phenol
Mercury
Hyd rogen Su1f i de
I ron
Zi nc
Copper
Lead
Cadmiurn
Chromi urn
Oil and Grease
Fl uori de
Ant Imony
Arsen I c
Be ry1li urn
Nickel
Selen iurn
Silver
Thai 1 I urn
Acenaphthene
Aery 1 on i t r i 1 e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1,2
Tr ichloroethane-1,1,1
Trichloroethane-1,1,2
Tetrachloroethane-1,1
Chloronaphthalene-2
Trichlorophenol-2,J»,6
Parachlorometacresol
Ch1oroform
Ch1orophenol-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
2 2
* > *•
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
Appli cat i on
Appl cat i on
App1 cat i on
Appl cation
Appl cation
App1 cat i on
App1i ca t i on
Appli cat i on
Appli ca t i on
Appli cat i on
Appli cat i on
Appli cat i on
App1 i cat i on
Appli cat i on
Appli cat i on
App1i cat i on
Appli cat i on
Appl i ca t i on
Appli ca t i on
App1i cat i on
Appli cat ion
Appli cat i on
Appli cat i on
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publ cation1'2
EPA Publ
EPA Publ
EPA Publ
EPA
EPA
EPA
EPA
EPA
EPA
Publ
Publ
Publ
Publ
cat ion1»2
cation1» 2
1, 2
1 .2
cation
cat i on
cat i.on
1,2
1 ,2
1 ,2
cation
cat i on
Publication1'2
Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
OCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
Dlchlorobenzene-para
VIny11d i enechlori de
Trans-dlchloroethylene-1,2
DIchlorophenol-2,*»
Dimethyl phenol-2,k
Dl ni trotoluene-2,6
Diphenylhydrazine-1,2
Ethyl Benzene
Fluoranthene
D i ch1orob romomethane
Ispphorane
Naphtha 1ene
Ni trophenol-2
Ni trophenol-k
Ni trophenol-P
01ni tro-O-cresol-^,6
Pentachlorophenol
Phenol
Bi s(2-ethylhexyl)phthai ate
Butylbenzylphthalate
DI-N-buty1phthalate
Di-N-octy1phtha1 ate
Diethylphthai ate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11,12
Chrysene
Acenaphthy1ene
An th racene
Benzoper1i ne
F1uordene
Phenathene
Di benzo(A,11)Anthracene
Indenod ,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
Trichloroethylene
Pyrene
,2
,2
,2
. 2
REFERENCE
EPA Publication1'2
EPA Publication1-2
EPA Publication1
EPA Publication1
EPA Publication1
EPA Publication1
EPA Publication1'2
EPA Publication1»2
EPA Publication1 »2
EPA Publ ication1 >2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publi cation1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publi cat ionl»2
EPA Publication1»2
EPA Publication1'2
Publi cation1» 2
Publication1'2
Publication1'2
Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1>2
EPA Publi cation1»2
EPA Publication1'2
EPA Publication1»2
EPA
EPA
E^PA
EPA
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.8 OUTFALL NO. 012 - 1.4 x 108 gallons per day of
wastewater/cool!ng water from coke production
and coke byproduct plant
CONSTITUENT
Phosphate (as NaH2POit)
Organic Nitrogen (as N2)
Ammon i a
Cyan i de
Sul fate (as Na2SO(J
Phenol
Mercury
Hyd rogen Su1f i de
I ron
Zinc
Copper
Lead
Cadmium
Chromium
Oil and Grease
Fluor i de
Ant i mony
Arsen I c
Be ry11i um
Nickel
Se1 en i um
Silver
Thai 1lum
Acenaphthene
Aery 1 on i t r i1e
Benzene
Benz i di ne
Carbon Tet rach 1 or i d,e
Hexachlorobenzene
Dichloroethane-1,2
Trichloroethane-1
Trichloroethane-1
,1,1
.1.2
Tetrachloroethane-1,1,2,2
Chloronaphthalene-2
Trichlorophenol-2,4,6
Parachlorometacresol
Chloroform
Chlorophenol-2
Oichlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
NPOES Application
NPDES Application
NPDES Appli cation
NPDES Application
NPDES Appli cat ion
NPDES Applicat ion
NPDES Application
NPDES Appli cat ion
NPDES Applicat ion
NPDES Application
NPDES Applicat ion
NPDES Application
NPDES Appli cation
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Appli cation
NPDES Application
NPDES Application
NPDES Application
EPA Publication1»2
EPA Publication1»2
EPA Publication1>2
EPA Publication1»2
EPA Publication1»2
EPA Publication1 »2
EPA Publication1'2
EPA Publ icat.ion1 »2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
Dlchlorobenzene-para
Vinyl tdienechlori'de
Trans-dlchloroethylene-1,2
Dlchlorophenol-2,4
Dimethyl phenol-2,k
DIni trotoluene-2,6
Diphenylhydrazine-1 ,2
Ethyl Benzene
F1uoranthene
D I ch1orobromomethane
I sophorane
Naphthalene
Ni trophenol-2
N I t rophenol-k
NI trophenol-P
Dlnitro-0-cresol-A,6
Pentachlorophenol
Phenol
Bls(2-ethylhexyl)phthalate
Buty1benzy1phtha 1 ate
DI-N-butylphthalate
Dl-N-octylphthalate
Of ethylphthalate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,4
Benzofluoranthene-11,12
Chrysene
Acenaphthy1ene
Anthracene
Benzope r1 Ine
F1uordene
Phenathene
Dibenzo(A,11)Anthracene
lndeno(l,2,3~CD)Pyrene
Tetrachloroethylene
Toluene
Trichloroethylene
Pyrene
REFERENCE
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1.2
EPA Publication1.2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1.2
EPA Publication1.2
EPA Publication1.2
EPA Publication1.2
EPA Publication1»2
EPA Publication1.2
EPA Publication1.2
EPA Publication1.2
EPA Publication1.2
EPA Publication1.2
Pub 1i cat i on1» 2
EPA
EPA
Publication1 » 2
EPA Pub 1i cat i on 1 > 2
EPA Publication1 »2
EPA Publication1'2
EPA Publication1» 2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1» 2
EPA Publ ication1 »2
EPA Publication1'2
EPA Publication1»2
EPA Publication1 »2
EPA Publication1 »2
EPA Publicat ion1»2
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.9 OUTFALL NO. 013 - 3-*» x 107 gallons per day of
wastewater/coo1ing water from hot forming and
pi ckling
CONSTITUENT
Phosphate (as Naf
Organic Nitrogen (as N2)
Ammoni a
Cyan i de
Sul fate (as Na2SOi4)
Phenol
Mercury
Hydrogen Sulfide
I ron
Zinc
Copper
Lead
Cadmium
Chromi urn
Oi1 and Grease
Fluor i de
Antimony
Arsen i c
Be ry11i urn
Nickel
Selenium
S i1ver
Thai 1ium
Acenaphthene
Ac ry 1 on i t r i 1 e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1 ,2
Tr ichloroethane-1 ,1,1
Trichloroethane-1 , 1 ,2
Tetrachloroethane-1,1 ,2,2
Chloronaphthalene-2
Trichlorophenol-2,4,6
Parachlorometacresol
Ch1oroform
Chlorophenol-2
Oichlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
NPDES,
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
EPA Pub
Engi
Engi
Engi
Engi
Eng i
Engi
Engi
Engi
Engi
Engi
En g i
Engi
Eng?
Engi
Engi
Eng i
Engi
Engi
Engi
Engi
Engi
Eng i
Engi
neer
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neer
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neer
neer
nee r
nee r
neer
neer
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neer
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nee r
nee r
neer
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ng
ng
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ng
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Judgment3
Judgment3
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Judgment3
Judgment3
Judgment3
Judgment3
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Judgment3
Judgment3
Judgment3
Judgment3
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1 icat i on* ' ^
1 i ca
tion
1 icat ion
1 i cat i on
1 i ca
1 ica
1 i ca
1 i ca
1 ica
1 i ca
1 ica
1 ica
1 ica
1 i ca
1 i ca
1 ica
1 ica
t i on
t ion
tion
tion
tion
1 , z
1,2
1,2
1,2
1,2
1,2
1,2
1,2
ticn1'2
t i on
t ion
t ion
t i on
t ion
1,2
1,2
1,2
1,2
1,2
tion1'2
t ion
1,2
GCA/TECHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
3lchlorobenzene-para
V Iny1 Idienechloride
Trans-dichloroethylene-1 ,2
Dichlorophenol-2,4
DImethylphenol-2,4
D!n i trotoluene-2 ,6
Diphenylhydrazine-1,2
Ethyl Benzene
Fluoranthene
Dlch1orobromomethane
Isophorane
Naphtha 1ene
Ni trophenol-2
Ni trophenol-k
N!trophenol-P
Dlni tro-0-cresol-k,6
Pentachlorophenol
Phenol
Bis(2-ethy1hexyl)phthalate
Butylbenzylphthalate
Di-N-butylphthalate
Dl-N-octyIphthalate
Diethy1phthalate
Dimethylphthalate
Ber.zo(A)aritnracene
Benzo(A)py rene
Benzofluoranthene-3,4
Benzofluoranthene-11 ,12
Ch rysene
Acenaphthy1ene
Anthracene
Benzoper1f ne
F1uordene
Phenathene
D i benzo(A,11)Anthracene
Indeno( 1,2,3~CD)Pyrene
Tetrachloroethylene
To 1uene
Trichloroethylene
Pyrene
REFERENCE
EPA Publ ication1'2
EPA Publ ication1-2
EPA Publ ication1
EPA Publ ication1
Publ ication1
Publ ication1
Publ ication1 »2
Publ ication1 »2
Publ ication1
Publ ication1 »2
EPA
EPA
EPA
EPA
EPA
EPA
EPA Publ ication1 >
EPA Publ ication1 »2
EPA Publ ication1 »2
EPA Publ ication1 »2
EPA Publ ication1'2
EPA Publ ication1 »2
EPA Publ icat Jon1 »2
EPA Publ ication1 »2
EPA Publ ication1 » 2
EPA Publ ication1 »2
EPA Publ ication1'2
EPA Publ ication1'2
EPA Publ ication1 »2
EPA PubJ ication1 '2
EPA Publ ication1 »z
EPA Publ ication1'2
EPA Publ ication1'2
EPA Publ ication1 »2
EPA Publ ication1'2
EPA Publ ication1'2
EPA Publ ication1 »2
EPA Publ ication1'2
EPA Publ ication1 »2
EPA Publ ication1 «2
EPA Publ ication1.2
EPA Publ ication1'2
EPA Publ ication1'2
EPA Publ ication1 '2
EPA Publ ication1 »2
EPA Publ ication1 »2
GCA/TEGHNOIOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.10 OUTFALL NO. 016
Flow - 7.2 x 103 gallons per day of intermittent
storm d i scharge
CONSTITUENTS
F1uro i de
Sulfate
Cyan i de
Ant imony
Arsenic
Cadm i urn
Ch romi urn
Copper
I ron
Lead
Nickel
Tin
Zinc
Oil and Grease
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
i cat i on
i cat i on
i cat i on
icat i on
icat i on
i cat ion
i ca t i on
i cat i on
i cat i on
icat ion
i cat i on
i cat i on
i cat ion
i cat ion
GCA/TECHNOIDGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.11 OUTFALL NO. 017 - 1.4 x 106 of wastewater/coolIng
water from ga1 vanizing operations and intermittent
storm flow
CONSTITUENTS
Phosphate (as NaH2P0lt)
Organic Nitrogen (as
Ammoni a
Cyan i de
Sulfate (as Na2SOiJ
Phenol
Mercury
Hydrogen Su1f i de
I ron
Zinc
Coppe r
Lead
Cadmlurn
Chromi urn
Oil and Grease
Fluor i de
Ant Imony
Arsen i c
Be ry11i urn
Nickel
Selenium
S i 1 ver
Thai 1 I urn
Acenaphthene
Aery 1 on i t r i 1 e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1,2
Trichloroethane-1,1,1
Trichloroethane-1,1,2
Tetrachloroethane-1,1,2,2
Chloronaphthalene-2
Trichlorophenol-2,k,6
Parachlorometacresol
Ch1oroform
Chlorophenol-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
REFERENCE
NPDES Appl i cat ion
NPDES Application
NPDES Appli cation
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Applicat ion
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
NPDES Application
EPA Publication1'2
EPA Publicat
EPA Publication1
EPA Publicat
EPA Publication1»2
EPA Publication1'2
EPA Publ(cation*'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1 »2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
on1'2
on1'2
GCA/TECHNOIDGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
CONSTITUENT
i)Ichlorobenzene-para
V!nylId i enechlori de
Trans-dichloroethylene-1 ,2
Dichlorophenol-2,'»
Dimethylphenol-2,'*
Dln i trotoluene-2,6
Diphenylhydrazine-1,2
Ethyl Benzene
Fluoranthene
D i ch1orobromomethane
Isophorane
Naphtha 1ene
Nitrophenol-2
Ni trophenol-4
Ni trophenol-P
Dlni tro-O-cresol-4,6
Pentachlorophenol
Phenol
Bis(2-ethylhexyl)phthalate
Butylbenzylphthalate
Di-N-buty1phtha1 ate
Di-N-octylphthalate
Diethy1phtha late
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11 ,12
Chrysene
Acenaphthy1ene
Anthracene
Benzoperli ne
F1uordene
Phenathene
D i benzo(A,11)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
Toluene
Trichloroethylene
Pyrene
REFERENCE
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publicat
Publicat
Publi cat
Publicat
Publicat
Publicat
Publicat
on1'2
on
1,2
on1'2
on1'2
on1'2
on1'2
1'2
on
Publ ication1 »2
Publ ication1'2
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA
EPA Publication1>2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1»2
EPA Publication1»2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1'2
EPA Publication1»2
EPA Publication1'2
EPA Publication1'2
EPA Publication1.2
EPA Publ icat ion1»2
EPA Publicat ion1»2
GCA/TECHNOIQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.12 OUTFALL NO. 018 - 5.0 x lO* gallons per day of
cooling water, water treatment filter backwash
and intermittent storm flow
CONSTITUENT
REFERENCE
(as NaH2P0lt)
trogen (as N
Phosphate
Organ i c N
Ammoni a
Cyan i de
Sulfate (as Na2SOu)
Pheno1
Me rcu ry
Hydrogen Su1f i de
I ron
Zinc
Coppe r
Lead
Cadmi urn
Chromi urn
Oi1 and Grease
Fluor i de
Antimony
Arsen i c
Be ry11i urn
Nickel
SeI en iurn
S i1ver
Thai 1lum
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appl
Appi
Appl
Appl
i cat ion
i cat i on
i cat i on
i cat i on
icat ion
i cat ion
i cat ion
icat ion
icat ion
icat ion
icat ion
i cat i on
t cat i on
i ca t i on
i cat i on
i cat i on
i cat i on
i ca t i on
i ca t i on
icat ion
i cat i on
i cat ion
i cat ion
GCA/TECHNOiOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
2, LIST OF REFERENCES
2,1 LITERATURE REFERENCES CITED
Industry Summary: Iron and Steel,
March, 1979.
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Steel Making Segment of the Iron and
Steel Manufacturing Point Source Category,
June 197^, EPA-HO/1 -7^-0243 .
3Bethlehem Steel Corp., Waste Summary, Table 3,
from EPA Region III Permit File.
^Bethlehem Steel Corp., Laboratory Analysis,
Table 5, Samples Taken December 1971, from
EPA Region I I I Permit File.
2.2 OTHER LITERATURE REFERENCES USED
Anderson, W.C. and M.P. Youngstrom, "Coal Pile
Leachate Quantity and Quality Characteristics."
Jour. Env. Engr. Div., Proc. Amer. Soc. Civ.
Engr., 102, 1239 (1976).
Barton, P.J., et al, "Analysis of Cyanides in
Coke Plant Wastewater Effluents." Jour. WPCF,
2, 50, 23*» (1978) .
Economic Analysis of Proposal and Interim Final
Effluent Guidelines: Integrated Iron and Steel
Industry. EPA-230/1-76-048, March 1976.
EPA Technology Transfer Capsule Report, Pollution
Abatement in a Copper Wire Mill.
"Evaluation of EPA Recommended Treatment and
Control Technology for Blast Furnace Wastewater,"
Journal of the Environmental Engineering Division,
Vol. 104, No. EE2, April 1978.
GCA/TECHNOIDGY DIVISION
-------
1, CONCENTRATION DATA FOR EACH OUTFALL
1.1 OUTFALL NO. 001 - 5.0 x 108 gallons per day of
wastewater and cooling water from iron and steel
product i on
CONSTITUENT
CONCENTRATION
(as NaH2POiJ
trogen (as N2)
Phosphate
Organ i c N
Ammon i a
Cyan Ide
Sulfate (as Na2S04)
Phenol
Mercury
Hydrogen Sulfide
I ron
Zinc
Copper
Lead
CadmI urn
Chromiurn
Oil and Grease
FluorIde
Ant Imony
Arsen Ic
Be ry11i urn
Nickel
Se1 en I urn
SiIver
Thai Hum
Acenaphthene
Ac ry1 on i t r i 1 e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1,2
Trichloroethane-1,1,1
Trichloroethane-1,1,2
Tetrachloroethane-1,1
Chloronaphtha Iene-2
Trichlorophenol-2,4,6
Parach1orometacreso1
Ch1oroform
Ch1orophenol-2
DIchlorobenzene-meta
Dichlorobenzene-ortho
2,2
1
1
1
J*0
2,850
0
1
30
1
0
30
0
20
50
1
1
17
170
0
0
0
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
.0
.0
.2
.1
.2
.8
.2
.5
.0
.0
.97
ppm
ppm
ppm
PPb
ppm
ppm
PPb
ppb
ppm
ppm
ppb
PPm
PPb
ppb
ppm
ppm
ppb
PPb
ppm
ppb
PPb
ppb
ppb
ppb
PPb
ppb
ppb
PPb
ppb
ppb
ppb
ppb
PPb
ppb
ppb
ppb
REFERENCE
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Engi neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i neer i ng
NPDES Appli
NPDES Appli
NPDES Appli
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
NPDES Appl
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i nee r i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i nee r i ng
Eng i nee r i ng
Eng i neer i n'g
Engi neer i ng
Eng i neer i ng
Judgment,
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
cat ion
cat i on
cation
cat i on
cation
cation
cation
cat i on
cat ion
J udgment
Judgment''
Judgment
Judgment"
Judgment"
Judgment"
Judgment"
Judgment"
Judgment I*
Judgment
Judgment''
Judgment''
Judgment
Judgment''
Judgment
Judgment
Judgment''
a
>
a
9
a
9
a
9
a
9
a
9
a
9
a
9
a
9
a
9
a
9
a
9
a
9
a
9
BSC*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC**
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
DIchlorobenzene-para
Vinylidienechloride
Trans-dlchloroethylene-1,2
Dlchloropheno1-2,J»
Dimethylphenol-2,4
01nItrotoluene-2 , 6
Diphenylhydrazine-1 ,2
Ethyl Benzene
Fluoranthene
Dlenlorobromomethane
Isophorane
Naphtha Iene
Ni trophenol-2
Nltrophenol-k
NItrophenol-P
Dlni tro-O-cresol-^,6
Pentachlorophenol
Phenol
BIs(2-ethylhexyl)phthalate
Butylbenzylphthalate
DI-N-butyIphthalate
Di-N-octylphthalate
Diethy1phthalate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene~3»4
Benzofluoranthene-1 1 ,12
Chrysene
Acenaphthylene
Anth racene
Benzoper1 Ine
F1uordene
Phenathene
DIbenzo(A,11)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
CONCENTRATION
REFERENCE
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
i
i
i
i
i
i
i
I
I
1
i
i
i
i
i
1
i
f
i
i
i
i
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i
i
i
i
I
i
1
i
i
i
1
I
i
i
i
neer 1
neer 1
neer i
nee r i
neer i
neer i
neer i
neer 1
neer i
neer i
neer i
neer i
neer i
neer i
neer 1
neer i
neer i
neer i
neer i
neer i
neer 1
nee r i
neer i
neer 1
neer i
neer 1
neer i
neer!
neer i
neer J
neer i
neer i
neer i
neer i
neer i
neer i
neer 1
neeri
ng
ng
ng
ng
ng
ng
ng
ng
ng
"9
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
Judgment
Judgment
Judgment
Judgment
Judgment
Judgmen t
Judgment
Judgment
Judgmen t
Judgment
Judgment
Judgment
Judgment
J udgmen t
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgmen t
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgment
Judgmen t
Judgment
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.2 OUTFALL NO. 002 - 3.17 x 106 gallons per day of
wastewater from sintering operation
CONSTITUENT
CONCENTRATION
REFERENCE
(as NaH2PO.J
trogen (as N2)
Phospha te
Organ i c N
AmmonI a
Cyan Ide
Sulfate (as Na2S04)
Pheno1
Mercury
Hydrogen Sulf i de
I ron
Zinc
Copper
Lead
Cadmlurn
Chromiurn
Oil and Grease
F 1 uor i de
Ant i mony
Arsen Ic
Be ry1li urn
Nickel
Se I en i urn
SiIver
Thai 1 turn
Acenaphthene
Aery Ion i tri1e
Benzene
Benz id i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1 ,2
Trichloroethane-1 , 1 , 1
Trichloroethane-1 , 1 ,2
Tetrachloroethane-1,1 ,2,
Ch1oronaphtha 1ene-2
Trichlorophenol-2,4,6
Parachlorometacresol
Chloroform
fhiorophenol-2
Dich1orobenzene-meta
Dichlorobenzene-ortho
12.0
1 .2
14.0
40
820
80
0
15
10
0.4
0.1
0.5
20
40
1 .0
1 .0
0.23
40
0
14
0
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppm
ppm
ppm
ppb
ppm
ppb
ppm
ppm
ppm
ppm
ppm
ppb
ppb
ppm
ppm
ppm
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
Engineering Judgment, a
Engineering Judgment,8
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
Engineering Judgment,3
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
NPDES Appl cat on
Engineering Judgment1*
Engineering Judgment^
Engineering Judgment
Engineering Judgment''
Engineering Judgment"
Engineering Judgment"
Engineering Judgment"
Engineering Judgment"
Engineering Judgment;*
Engineering Judgment"
Engineering Judgment'1
Engineering Judgment**
Engineering Judgment
Engineering Judgment''
Engineering Judgment
Engineering Judgment"
Engineering Judgment**
BSC"
BSC1*
BSC1*
BSC"
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC1*
BSC**
BSC1*
BSC1*
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Dichlorobenzene-para
Vinylidienechloride
Trans-dlchloroethylene-1,2
Dichlorophenol-2,J»
Dimethylphenol-2,4
DIn i trotoluene-2,6
Di phenylhydrazine-1,2
Ethyl Benzene
F1uoranthene
DIch1orobromomethane
Isophorane
Naphthalene
Nltrophenol-2
Ni trophenol-4
Ni trophenol-P
DIni tro-O-cresol-4,6
Pentachlorophenol
Phenol
BIs(2-ethylhexyl)phthalate
Butyl benzylphthalate
DI-N-butyIphthalate
Di-N-octyIphthalate
Diethy1phthalate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)py rene
Benzofluoranthene-3,4
Benzo.fl uoran thene-1 1 ,1 2
Ch rysene
Acenaphthylene
Anth racene
Benzoper1i ne
Fluordene
Phenathene
D I benzo(A,11)Anthracene
lndeno(l,2,3-CD)Pyrene
Tetrachloroethylene
To 1 uene
Trichloroethylene
Pyrene
CONCENTRATION
REFERENCE
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
PPb
ppb
ppb
EngIneer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Engi neeri ng
Eng i neer i ng
Eng i neer i ng
Engi neer i ng
Eng i neer i ng
Engi nee r i ng
Eng i neer i ng
Eng i neer i ng
EngIneer i ng
Eng i nee r i ng
Engi neer i ng
Eng i nee r i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
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Eng i neer i ng
Eng i neer i ng
Engi neeri ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee ring
Engi neeri ng
Eng i neer!ng
Eng!neer i ng
Eng i nee ring
Eng i neer i ng
Eng i neer ing
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Eng ? neer i ng
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GCA/TECHNODGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.3 OUTFALL NO. 003 - 6.9 x 10 gallons per day of
wastewater from sintering operation
CONSTITUENT
Phosphate (as NaH2POJt)
Organic Nitrogen (as N2)
Ammoni a
Cyan i de
Sulfate (as Na2S04)
Pheno1
Mercury
Hydrogen Su1f i de
I ron
Zinc
Copper
Lead
Cadm!urn
Chromlurn
01 I and Grease
Fluor i de
Antimony
Arsen i c
Be ry11i urn
Nickel
Se1 en i urn
SiIver
Tha11 I urn
Acenaphthene
Ac ry1 on i t r i1e
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Dichloroethane-1,2
Trichloroethane-1,1,1
Trichloroethane-1,1,2
Tetrachloroethane-1,1
Chloronaphthalene-2
Trichlorophenol-2,4,6
Parachlorometacresol
Ch1oroform
Ch Sorophenol-2
DIchlorobenzene-meta
Dichlorobenzene-ortho
CONCENTRATION
REFERENCE
2,2
20
1 .4
22.0
20
230
20
3.5
250
0.6
61
1 .5
0.52
20
70
1 .0
1 .0
230
40
0
14
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppm
ppm
ppm
ppb
ppm
ppb
ppb
ppb
ppm
ppm
ppm
ppm
ppb
ppb
ppm
ppm
ppb
ppb
ppb
ppb
ppb
ppb
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NPDES Appl ication
NPDES Appl ication
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NPDES Appl ication
NPDES Appl ication
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NPDES Appl ication
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BSC"
BSC1*
BSC1*
BSC1*
BSC"
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BSC1*
BSC"
GCA/TECHNOIQGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Di ch1orobenzene-para
Vinylidienechloride
Trans-dlchloroethylene-1,2
Dlchlorophenol-Z,'*
Dimethylpnenol-2,k
Dlni trotoluene-2,6
Diphenylhydrazine-1 ,2
Ethyl Benzene
Fluoranthene
D i ch1orobromomethane
Isophorane
Naphthalene
Nltrophenol-2
N!trophenol-4
Ni trophenol-P
Dlni tro-O-cresol-^.G
Pentachlorophenol
Phenol
Bis(2-ethylhexyl)phthalate
Butylbenzylphthalate
Di-N-butyIphthalate
Di-N-octylphthalate
Diethy1phtha late
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11,12
Chrysene
Acenaphthylene
Anthracene '
Benzoper1i ne
Fluordene
Phenathene
Di benzo(A,1l)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
CONCENTRATION
REFERENCE
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
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Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Engi neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i neering
Eng i neer i ng
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Eng i neer i ng
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Eng i neer i ng
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GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.4 OUTFALL NO. 004 - 3.3 x 105 gallons per day of
wastewater
CONSTITUENT
Phosphate (as NaH2POtt)
Organic Nitrogen (as N2)
Ammon i a
Cyan i de
Sul fate (as Na2S04 )
Phenol
Mercury
Hydrogen Sul f i de
1 ron
Zinc
Copper
Lead
Cadmi urn
Chromi urn
Oi 1 and Grease
Fl uor i de
Ant i mony
Arsen i c
Be ry 1 1 i urn
Nickel
Se 1 en i urn
Si 1 ver
Tha 1 1 i urn
Acenaphthene
Aery Ion i tri le
Benzene
Benz i d i ne
Carbon Te t rach I or i de
Hexachlorobenzene
Dichloroethane-1 ,2
Trichloroethane-1 , 1 , 1
Trichloroethane-1 ,1 ,2
Tetrachloroethane-1 ,1 ,2 ,
Chloronaphthalene-2
Trichlorophenol-2,4,6
Parachlorometacresol
Ch 1 orof orm
Ch 1 orophenol -2
Dichlorobenzene-meta
Dichlorobenzene-ortho
from s i nte
ring O|
CONCENTRATI ON
16.5
1 .k
20
10
620
30
10
0.2
1 .80
0.60
0.10
0.50
20
70
1
1
0.23
40
0
1.4
0
0
0
10
10
10
10
10
10
10
10
10
2 10
10
10
10
10
10
10
10
ppm
Ppm
ppm
ppb
ppm
ppb
ppb
ppm
ppm
ppm
ppm
ppm
ppb
ppb
ppm
ppm
ppm
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
REFERENCE
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i neer
Eng i nee r
Eng i neer
NPDES App
NPDES App
NPDES App
NPOES App
NPDES App
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nr uco Mpp
NPDES App
NPDES App
NPDES App
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cat on
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»
»
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»
»
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»
f
»
y
»
>
»
»
b
b
b
b
b
b
b
b
b
b
b
b
a
a
a
a
a
a
a
a
a
a
a
a
a
a
BSC
BSC
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BSC
BSC
i»
«*
<4
(4
U
U
«*
«t
«*
it
4
i*
t*
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Dichlorobenzene-para
Vinylidienechloride
Trans-dich1oroethy 1ene-1,2
Dlchlorophenol-2,i»
Dimethylphenol-2,^
Dini trotoluene-2,6
Diphenylhydrazine-1 ,2
Ethyl Benzene
Fluoran thene
DIch1orobromomethane
Isophorane
Naphtha 1ene
Nitrophenol-2
Nltrophenol-k
Nltrophenol-P
Dlni tro-O-cresol-4,6
Pentachlorophenol
Phenol
Bis(2-ethylhexyl)phthalate
Butyl benzylphtha 1 ate
D!-N-butylphthalate
DI-N-octylphthalate
Diethy1phthalate
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzof1uoranthene-3 , ^
Benzofluoranthene-11 , 12
Ch rysene
Acenaphthy1ene
Anth racene
Benzoper1 Ine
F1uordene
Phenathene
Dibenzo(A,1l)Anthracene
lndeno(l,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
Trlchloroethylene
Py rene
CONCENTRATION
REFERENCE
10
10
10
10
10
10
10
10
10
10
10
10
.10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
Eng i nee r i ng
•Eng i neer i ng
Eng i neer i ng
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Eng i nee ring
EngIneer i ng
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Eng i neeri ng
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Eng i neer i ng
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Judgment
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GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATION (CONTINUED)
1.5 OUTFALL NO. 07 - 1.0 x 106 gallons per day of
su 1 f ur i c ac
storm flow
CONSTITUENT
Oil and Grease
1 ron
Ant i mony
Arsen i c
Coppe r
Cyan! de
Cadm i urn
Ch romi urn
H2S
Lead
NH3 as N
Sul fate
Z i nc
Phenol
1.6 OUTFALL NO.
su 1 f u r i c ac
i ntermi tten
CONSTITUENT
Oi 1 and Grease
1 ron
Ant i mony
Arsen i c
Coppe r
Cyan ! de
Cadmi urn
Chromium
H2S
Lead
NH3 as N
Sul fate
Zinc
Phenol
id plant wastewate
CONCENTRATION
17-6 ppm
1 ,800 ppm
1 .6 ppm
0.48 ppm
60 ppm
61 ppb
0.1 ppm
0.2k ppm
0 . 8 ppm
7 ppm
S . 88 ppm
69 , 1 80 ppm
1 7 ppm
0. I45ppm
r and i nte rmi ttent
REFERENCE
NPDES Appl ication
BSC(3)
NPDES Appl ication
NPDES Appl ication
BSC(3)
BSC(3)
BSC(A)
BSC(4)
BSC(3)
BSC(3)
BSC(3)
BSC(3)
BSC(3)
BSC(3)
08 - 1 .kk x 106 gallons per day of
id plant wastewate
t storm flow
CONCENTRATION
10.0 ppm
1 . 1 ppm
1 .0 ppm
0 . 1 ppm
0.30 ppm
16.1 ppm
<0.02 ppm
0.05 ppm
1 .79 ppm
<0 . 5 ppm
58.8 ppm
3,245 ppm
0.21 ppm
23.5 ppm
r/cooling water and
REFERENCE
Engineering Judgment0
BSC(3)
Engineering Judgment0
Engineering Judgment0
BSC(3)
BSC(3)
BSC(4)
BSC(4)
BSC(3)
BSC(3)
BSC(3)
BSC(3)
BSC(3)
BSC(3)
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATION (CONTINUED)
1.7 OUTFALL NO. Oil - 2.9 x 107 gallons per day of
wastewater/coolJng water from coke production
and coke byproduct plant
CONSTITUENT
Phosphate (as NaH2POtt)
Organic Nitrogen (as N2)
Ammoni a
Cyan i de
Sulfate (as NaaSOi,)
Phenol
Mercury
Hydrogen Sulfide
I ron
Zinc
Copper
Lead
Cadmi urn
Chromlurn
Oil and Grease
F 1 uor i de
Ant i mony
Arsen i c
Be ry I 1 i urn
Nickel
Se1 en i urn
SiIver
Thai 11 urn
Acenaphthene
Acrylon i trile
Benzene
Benz i d i ne
Carbon Tetrach1 oride
Hexachlorobenzene
Di chloroethane-1,2
Tr ichloroethane-1,1,1
Tricoloroethane-1,1 ,2
Tetrachloroethane-1 ,1 ,2,2
Chloronaphthalene-2
Trichlorophenol-2,4,6
Parach »orometacreso1
Ch1oroform
Ch1orophenol-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
CONCENTRATION
REFERENCE
2.4
1 .0
3.2
O.k
3,1*00
0.35
0
60
1»
0.5
60
0.5
20
50
1
1
81
120
0
7.2
0
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppm
ppm
ppm
ppm
ppm
ppm
ppb
ppm
ppm
ppb
ppm
ppb
ppb
ppm
ppm
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
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NPDES Appl ication
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BSC1*
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BSC1*
BSC1*
BSC1*
OCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Dichlorobenzene-para
Vinylidlenechloride
Trans-dichloroethylene-1,2
Dlchlorophenol-2,i»
Dimethyl phenol-2 ,k
DI n i trotoluene-2,6
Di phenylhydrazine-1 ,2
Ethyl Benzene
F1uoranthene
DIch1orobromomethane
Isophorane
Naphthalene
NItrophenol-2
N!trophenol-k
Nitrophenol-P
Dinitro-O-cresol-4,6
Pentachlorophenol
Phenol
Bis(2-ethylhexyl)phthalate
Butylbenzylphthalate
Di-N-butylphthalate
Di-N-octy1phthalate
Diethylphtha late
Dimethylphthalate
Benzo(A)anthracene
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11 ,12
Chrysene
Acenaphthy 1 ene
Anth racene
Benzope r1 Ine
Fluordene
Phenathene
Dibenzo(A,1l)Anthracene
lndeno(l,2,3~CD)Pyrene
Tetrachloroethylene
Toluene
Trichloroethylene
Pyrene
CONCENTRATION
REFERENCE
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
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ppb
ppb
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ppb
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ppb
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ppb
ppb
ppb
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Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
Eng
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Eng
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Eng
Eng
Eng
Eng
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Eng
Eng
Eng
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b
b
b
b
b
b
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b
b
b
b
b
b
b
b
b
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b
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b
"
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
OCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.8 OUTFALL NO. 012 - 1.k x 108 gallons per day of
wastewater from steel manufacture
CONSTITUENT
Phosphate (as NaH2POit)
Organ i c Nit rogen
Ammoni a
Cyan i de
Sulfate (as Na2SOiJ
Phenol
Mercury
Hyd rogen Su1f i de
I ron
Zinc
Copper
Lead
Cadm i urn
Chromi urn
Oil and Grease
Fluor i de
Ant i mony
Arsen ic
Beryl Ii urn
Nickel
Se1 en i urn
CONCENTRATION
13.7 ppm
0.2 ppm
8.5 ppm
50 ppb
118,000 ppm
0.15 ppm
0
60 ppb
750 ppm
A3 ppm
110 ppm
5.5 ppm
140 ppb
30 ppb
1 ppm
1 ppm
170 ppb
170 ppb
0
100 ppb
0
REFERENCE
BSC, 3
Engineering Judgment3
BSC, 3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
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l ication,
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l ication,
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l ication,
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BSC,1*
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NPDES App
Engineeri
NPDES App
Engineeri
NPDES App
Engineeri
NPDES App
Engineeri
NPDES App
Engineeri
NPDES App
Engineeri
NPDES App
Engineeri
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
S i1ver
Tha 1 1 i urn
Acenaphthene
Aery 1 on It r i1e
Benzene
Benz i dene
Carbon Tetrach1 oride
Hexach1orobenzene
Dichloroethane-1 ,2
Trichloroethane-1 , 1 , 1
Trichloroethane-1 , 1 ,2
Tetrachloroethane-1 ,1,2,2
Chloronaphthalene-2
Trichloropheno 1-2,^,6
Parachlorometacresol
Ch1oroform
Ch1orophenol-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
Dichlorobenzene-para
V i n> •i d i enech1 or i de
Trans-dichloroethylene-1,2
CONCENTRATION
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
REFERENCE
NPDES App] icat ion ,
Engineering Judgment
NPDES Appl ication,
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication,1
Engineering Judgment
EPA Publ ication,1
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
EPA
Eng
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Judgment
a
a
b
b
b
b
b
b
b
b
b
b
b
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Dichlorophenol-2,A
Dimethyl phenol-2,k
Dinitrotoluene-2,6
Diphenylhydrazine-1,2
Ethyl Benzene
Fluoranthene
D i ch1orobromomethane
I sophorane
Naphtha 1ene
Ni trophenol-2
Ni trophenol-A
Nitrophenol-P
Dinitro-O-cresol-^,6
Pentachlorophenol
Phenol
Bis(2-ethylhyxyl)phthalate
Butylbenzylphthalate
Di-N-butylphthalate
Di-N-octylphthalate
Diethylphthalate
Dimethylphthalate
Benzo(A)anthracene
CONCENTRATION
1 0 ppb
1 0 ppb
10 ppb
10 ppb
10 ppb
1 0 ppb
10 ppb
1 0 ppb
1 0 ppb
1 0 ppb
1 0 ppb
10 ppb
10 ppb
1 0 ppb
1 0 ppb
1 0 ppb
1 0 ppb
1 0 ppb
10 ppb
10 ppb
1 0 ppb
10 ppb
REFERENCE
EPA Publication,1
Engineering Judgment
EPA Publicat ion,1
Engineering Judgment
EPA Publication,l
Engineering Judgment
EPA Publicat ion,1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publication,l
Engineering Judgment"
EPA Publication,1
Engineering Judgment"
EPA Publ ication, l
Engineering Judgment"
EPA Publication,1
Engineering Judgment"
EPA Publication, l
Engineering Judgment
EPA Publication,l
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publicat ion,1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publication,l
Engineering Judgment
EPA Publ ication,1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publication,1
Engineering Judgment1*
EPA Publication,1
Engineering Judgment
EPA Publication,1
Engineering Judgment
GCA/TECHNO1OGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Benzo(A)pyrene
Benzofluoranthene-3,^
Benzofluoranthene-11,12
Chrysene
Acenaphthy1ene
Anthracene
Benzope r1 Ine
F1uordene
Phenathene
Dibenzo(A,11)Anthracene
lndeno(l,2,3-CD)Pyrene
Tetrachloroethylene
Toluene
Trichloroethylene
Pyrene
CONCENTRATION
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppb
ppb
ppb
ppb
Ppb
Ppb
Ppb
ppb
Ppb
ppb
ppb
Ppb
ppb
ppb
Ppb
EPA
Eng i
EPA
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REFERENCE
Pub
nee
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k
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k
u
k
U
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GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.9 OUTFALL NO. 013 - 3.4 x 107 gallons per day of
Ammoni a
Cyan i de
Sulfat
Phenol
Me rcu ry
Hydr
I ron
Zinc
Copper
Lead
Cadm iurn
Chrom i u
Oil and
Fluorid
Ant i mon
Arsen i c
Beryl 1
Nickel
wastewa ter/coo
p i ckl ing
CONSTITUENT
ate (a.s NaH2POiJ
c Nit rogen
a
e
e (as Na2SOit)
•y
ien Su 1 f i de
jm
i urn
id Grease
ide
jny
ic
1 i urn
!
i urn
ling wa te r
CONCENTRAT
7.2
1 .2
6.0
30
1,870
0.15
1 .0
0.1
3.0
0.25
70
0.5
20
50
1
1 .
0. 15
92
0
4.7
0
frc
ION
ppm
ppm
ppm
ppb
ppm
ppm
ppb
ppm
ppm
ppm
ppb
ppm
ppb
ppb
ppm
ppm
ppb
ppb
ppb
REFERENCE
BSC,3
Engineering Judgment
BSC,4
Engineering Judgment3
BSC,4
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
NPDES Appli cat ion ,
Engineering Judgment3
BSC,4
Engineering Judgment3
BSC,3
Engineering Judgment
NPDES Application,
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,3
Engineering Judgment3
BSC,4
Engineering Judgment
NPDES Application,
Engineering Judgment3
NPDES Application,
Engineering Judgment3
NPDES Application,
Engineering Judgment3
NPDES Application,
Engineering Judgment3
NPDES Application,
Engineering Judgment3
NPDES Application,
Engineering Judgment3
NPDES Applicat ion,
Engineering Judgment3
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Si 1ver
Tha 1 1 i urn
Acenapnt hene
Aery Ion i tr ile
Benzene
Benz i dene
Carbon Te t rach 1 or i de-
Hexachlorobenzene
Dich1oroethane-1 , 2
Trich1oroe thane-1,1,1
Trichloroethane-1,1,2
Tetrachloroethane-1,1,2,2
Chloronaphthalene-2
Trichlorophenol-2,^,6
Parachlorometacresol
Chloroform
Ch1oropheno1-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
Dichlorobenzene-para
'/Ir/lidienechloride
Trans-dichloroethylene-1,2
CONCE
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
NTRATION
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
REFERENCE
NPDES Appl icat ion ,
Engineering Judgmen
NPDES Appl icat ion ,
Engineering Judgmen
EPA Publ icat ion, l
Engineering Judgmen
EPA Publ i cat i on , 1
Engi
&PA
Eng i
EPA
Eng i
EPA
Eng i
EPA
Eng i
EPA
Eng i
EPA
Engi
EPA
Engi
EPA
Eng i
EPA
Engi
EPA
Eng i
EPA
Engi
EPA
Eng i
EPA
Eng i
EPA
Engi
EPA
Eng i
EPA
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EPA
Eng i
EPA
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1
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1
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a
a
b
b
b
b
k
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.
b
b
b
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Dichlorephenol-2, A
Dimethyl phenol-2 , k
Di n i trotoluene-2 ,6
Diphenylhydrazine-1 ,2
Ethyl Benzene
F1uo ran thene
D i ch1orobromomet hane
Isophorane
Naphtha 1ene
Ni trophenol-2
N i t rophenol-k '
Ni trophenol-P
Dini tro-O-cresol-^,6
Pentach1oropheno1 ,
Pheno1
Bis(2-ethylhyxyl)phthalate
Butylbenzylphthalate
Oi-N-buty1phtha1 ate
Di-N-octylphtha1 ate
Di ethylphtha1 ate
D i m e i h y 1 p h t h a 1 a t e
Benzo(A)anthracene
CONCENTRATION
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
REFERENCE
EPA Publ icat ion , l
Engineering Judgment
EPA Publ icat ion , 1
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
EPA Publ ication, l
Engineering Judgment"
EPA Publ i cat i on , l
Engineering Judgment*1
EPA Publ i cat i on , 1
Engineering Judgment*3
EPA Publ icat ion, 1
Engineering Judgment"
EPA Publ icat ion, l
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publ icat ion, x
Engineering Judgment
EPA Publ icat ion , 1
Engineering Judgment
EPA Publ icat ion , l
Engineering Judgment
EPA Publ icat i on , l
Engineering Judgment
EPA Publ i cat i on , 1
Engineering Judgment
EPA Publ icat ion , 1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publ icat ion, l
f\
Engineering Judgment
EPA Publ icat ion,1
Engineering Judgment
EPA Pub 1J cat ion, 1
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Benzo(A)pyrene
Benzofluoranthene-S,**
Benzofluoranthene-11,12
Chrysene
Acenaphthy1ene
Anthracene
Benzope r1 i ne
Fluordene
Phenathene
Di benzo(A,1l)Anthracene
lndeno(1,2,3-CD)Pyrene
Tetrachloroethylene
Toluene
Trichloroethylene
Pyrene
CONCENTRATION
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
PPb
REFERENCE
EPA Publ icat ion , l
Engineering Judgment
EPA Publ icat ion, 1
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publ icat ion, 1
Engineering Judgment
EPA Publ icat ion, 1 fa
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ icat i on , 1
Engineering Judgment
EPA Publ icat ion, l
Engineering Judgment
EPA Publ icat ion, l
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment0
EPA Publ ication , *
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.10 OUTFALL NO. 16
Flow - 7.2 x 103 gallons per day of intermittent
storm di scharge
CONSTITUENT
Fluor i de
Sulfate
Cyani de
Ant i mony
Arsen i c
Cjadmi urn
Ch romi urn
Coppe r
I ron
Lead
Nickel
Tin
Zinc
Oil and Grease
CONCENTRATION
REFERENCE
0
.84
500
1
2
3
0
0
5
.5
.99
20
0
3
.8
.8
50
0
1
0
1
.3
.3
.25
ppm
ppm
PPb
ppm
ppm
ppb
ppb
ppm
ppm
ppb
ppm
ppm
ppm
ppm
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
App
App
App
App
App
App
App
App
App
App
App
App
App
App
1
1
1
1
1
1
1
1
1
1
1
1
1
1
i
i
i
i
i
*
i
i
i
•
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i
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on
on
on
on
on
on
on
on
on
on
on
on
on
on
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.11 OUTFALL NO. 017 - 1 . *» x 106 gallons per day of
wastewater/coolIng water from galvanizing opera-
tions and intermittent storm flow
CONSTITUENT
Phosphate (as NaH2POit)
Organ i c Nit rogen
Ammon i a
Cyan i de
Sulfate (as N
Pheno1
Me rcu ry
Hydrogen Sulfide
I ron
Zinc
Copper
Lead
Cadm iurn
Ch rom i urn
Oil and Grease
Fluoride
Ant i mony
Arsenic
Be ry11i urn
Nickel
Se)en i urn
CONCENTRATION
REFERENCE
1
1
1
79
780
52
0
0
2
0
50
80
25
k
Ik
2
0
0
0
130
0
.0
.0
.0
.1
.5
.9
.6
.8
.56
.5
.9
ppm
ppm
ppm
ppb
ppm
ppb
ppm
ppm
ppm
ppb
ppt>
ppb
ppm
ppm
ppm
ppm
ppm
ppb :
Engineering Judgment
Engineering Judgment'}
Engineering Judgment"
NPDES Appl ication,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment
NPDES Appl ication,
Engineering Judgment3
Engineering Judgment
NPDES Appl ication,
Engineering Judgment3
NPDES Appl i cat ion ,
Engineering Judgment
NPDES Appl icat ion,
Engineering Judgment3
NPDES Application,
Engineering Judgment3
NPDES Appl i cat ion ,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment
NPDES Appl ication,
Engineering Judgment3
NPDES Appl icat ion,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment
NPDES Appl ication,
Engineering Judgment
NPDES Appl ication,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment3
NPDES Appl icat ion,
Engineering Judgment3
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
S i1ver
Tha11 i urn
Acenaphthene
Aery 1 on i t r i1e
Benzene
Benz i dene
Carbon Tetrach1 oride
Hexachlorobenzene
Dich1oroethane-1 ,2
Trichloroethane-1 , 1 , 1
Trichloroethane-1 ,1 ,2
Tetrachloroethane-1 ,1 ,2,2
Chloronaphthalene-2
Trich1orophenol-2,A,6
Parachlorometacresol
Chloroform
Ch1oropheno1-2
Dichlorobenzene-meta
Dichlorobenzene-ortho
Dichlorobenzene-para
V i n ,' I i d i e n e c h 1 o r i d e
Irans-dichloroethylene-1,2
CONCENTRATION
0
0
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
Ppb
ppb
ppb
ppb
ppb
ppb
ppb
Ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
REFERENCE
NPDES Appl icat ion ,
Engineering Judgment3
NPDES Appl ication,
Engineering Judgment3
EPA Publ ication, l
Engineering Judgment'3
EPA Publ icat i on, *
Engineering Judgment
EPA Publ icat ion , 1
Engineering Judgment
EPA Publ i ca t i on , l
Engineering Judgment
EPA Publ icat i on, 1
Engineering Judgment*3
EPA Publ icat ion, 1
Engineering Judgment
EPA Publ icat ion, 1
Engineering Judgment
EPA Publ icat ion, 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment"
EPA Publ ication, 1
Engineering Judgment
EPA Publ icat ion, l
Engineering Judgment
EPA Publ icat ion, x
Engineering Judgment
EPA Publ icat ion , l
Engineering Judgment
EPA Publ icat ion, J
Engineering Judgment
EPA Publ icat ion,1
Engineering Judgment
EPA Publ ication,1
Engineering Judgment
EPA Publ icat ion, x
Engineering Judgment
EPA Publ icat ion, x
Engineering Judgment
EPA Publ ication,1
Engineering Judgment
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Di chlorophenol-2,k
Dimethyl phenol-2,k
Dinitroto1uene-2 , 6
Diphenylhydrazine-1,2
Ethyl Benzene
Fluoran t hene
D i chIorobromomet hane
Isophorane
Naphtha 1ene
Ni trophenol-2
Ni trophenol -1*
Ni t rophenol-P
Dinitro-0-cresol-A,6
Pentachlorophenol
Phenol
Bis(2-ethylhyxyl)phthalate
Butyl benzylphthalate
Di-N-buty1phtha1 ate
Di-N-octylphthalate
D i ethy1ph tha 1 a te
Dtmeihylphthalate
Benzo(A)anthracene
CONCENTRATION
1
1
1
1
1
1
1
1
1
1
1
i
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ppb
ppb
ppb
ppb
ppb
ppb
ppb
Ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
PPb
ppb
ppb
EPA
Eng i
EPA
Eng i
EPA
Eng i
EPA
Eng i
EPA
Eng i
EPA
Engi
EPA
Engi
EPA
Eng i
EPA
Eng i
EPA
Engi
EPA
Engi
EPA
Eng i
EPA
Eng i
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EPA
Eng i
EPA
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EPA
Eng i
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EPA
Eng i
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Pub
nee
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nee
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nee
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1
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1
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1
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1
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1
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1
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1
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1
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1
r
1
r
1
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b
b
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
CONSTITUENT
Benzo(A)pyrene
Benzofl uoranthene-3,'*
Benzofluoranthene-11,12
Chrysene
Acenapht hy1ene
Anthracene
Benzope r1 i ne
F1uo rde ne
Phenathene
Dibenzo(A,1l)Anthracene
lndeno(l,2,3-CD)Pyrene
Tetrachloroethylene
To 1uene
Trichloroethylene
Py rene
CONCENTRATION
10
10
10
10
10
\
10
10
10
10
10
10
10
10
10
10
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
REFERENCE
EPA Publ icat ion, l
Engineering Judgment
EPA Publ i cat i on , 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
EPA Publ ication, l .
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Pub 1 i cat ion , 1
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication,1
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
EPA Publ ication, 1
Engineering Judgment
EPA Publ ication, l
Engineering Judgment
EPA Publication,1
Engineering Judgment
EPA Publ icat ion, l
Engineering Judgment
OCA/TECHNOLOGY DIVISION
-------
Cr DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.12 OUTFALL NO.
cool i ng wate
and i ntermi t
CONSTITUENT
Phosphate (as NaH2POi4)
Organic Nitrogen (as N2)
Ammonia
Cyan i de
Sulfate (as Na2SOit)
Phenol
Mercury
Hydrogen Sul f i de
1 ron
Zinc
Coppe r
Lead
Cadmi urn
Ch rom i urn
Oi 1 and Grease
Fluoride
An t i mony
Arsenic
Bery 1 1 i urn
Nickel
Se 1 en i urn
Si Iver
Thai 1 ium
r , water t
tent storm
CONCENTRAT
17
1 .2
12
0
1 ,320
70
0
0
19.2
7.2
0. 12
0.72
30
70
1 .0
1 .0
0.23
40
o
14.0
0
0
0
real
f 1<
ION
ppm
ppm
ppm
ppm
ppb
ppm
ppm
ppm
ppm
ppb
ppb
ppm
ppm
ppm
ppb
ppb
018 - 5.0 x 10" gallons per day of
snt filter backwash
ow
REFERENCE
Eng i neer i ng
EngIneerIng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee rIng
Eng i neer i ng
Eng i neer i ng
Eng i neer i ng
Eng i nee r i ng
Eng i neer i ng
Eng i nee r i ng
Eng i nee r i ng
NPDES Appli
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
Appl i
App! i
Appl i
Appli
Appli
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Judgment,a
Judgment a
Judgment
Judgment
J udgmen t
Judgment
Judgment
Judgment
Judgment
Judgment,a
Judgment,a
Judgment,a
Judgment,a
Judgment,a
J udgmente
J udgmen te
cat i on
cat i on
cation
cat i on
cat ion
cat i on
cat i on
BSC"
BSC14
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
BSC"
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES CITED
1 Deve 1 opmen t Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Steel Making Segment of the Iron and
Steel Manufacturing Point Source Category,
June 1971*, EPA-^0/1 -Jk
2Bethlehem Steel Corp., Waste Summary, Table 3,
from EPA Region III permits file.
3Bethlehem Steel Corp., Laboratory Analysis,
Table 5, samples taken December 1971, from EPA
Region III permits file.
2.2 OTHER LITERATURE REFERENCES USED
Anderson, W.C. and M.P. Youngstrom, "Coal -Pile
Leachate Quantity and Quality Characteristics."
Jour. Env. Engr. Div., Proc. Amer. Soc. Civ.
Engr., 102, 1239 (1976).
Barton, P.J., et al, "Analysis of Cyanides in
Coke Plant Wastewater Effluents." Jour. WPCF,
2, 50, 23*» (1978).
Economic Analysis of Proposal and Interim Final
Effluent Guidelines: Integrated Iron and Steel
Industry. EPA-230/1 -76-048 , March 1978.
EPA Technology Transfer Capsule Report, Pollution
Abatement in a Copper Wire Mill.
"Evaluation of EPA Recommended Treatment and Control
Technology for Blast Furnace Wastewater," Journal
of the Environmental Engineering Division, Vol. 10^,
No. EE2, April 1978.
Industry Summary: Iron and Steel, March 1979-
GCA/TECHNQIQGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
3, ENGINEERING JUDGMENTS
aDue to limited information all "process" streams were
assumed to have similar constituents and concentrations
Whenever possible Bethlehem Steel Corp. "Laboratory
Analysis" data was used instead of NPDES data. Some
adjustments to BSC and NPDES data were made to improve
consistency between the two data sets.
Potential dishcarge stream constituents which are also
on EPA's list of 129 priority pollutants were assigned
a concentration of 10 ppb, if no quantitative data
could be found.
Concentration estimates based on NPDES data for
Outfall No. 7-
Concentration estimates based on NPDES and BSC data
for Outfal1 No. 13.
eConcentration estimates based on NPDES and BSC data
for Outfal1 No. 16.
GCA/TECHNOIDGY DIVISION
-------
>OA TECHNOLOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
CARD
NO.
i
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?CA TECHNOiOGY DMSON
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INPUT CODING FORM
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CARD
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TEOflMOTKSY DMSON
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|CARO
NO.
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GCA TECHNOOGY DM9ON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
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CARD
NO.
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DETERMINATION OF OUTFALL TUDR
SOURCE.
NPDES PERMIT NO..
OUTFALL NO,.
FLOW RATE 100.000 GALLONS PER DAY
A B C D
CHEMICAL CONSTITUENT CONCENTRATION DMEG VALUE DEGREE OF HAZARD
EXAMPLE:
CHROMIUM
1 X 10
-6
1 X 10
-3
(B/C)
1 x 10"3
E
TUDR
(D x FLOW RATE)
1 x 10
+2
CONSTITUENT N
ETUDR
OUTFALL
= 7 X 10'
O
DETERMINATION OF FACILITY TUDR
OUTFALL NO,
EXAMPLE:
01
TUDR
7 X 102
OUTFALL N
ETUDR]
FACILITY
= 8
,1
X
102
-------
VEPCO-YORKTOWN
A, FACILITY DESCRIPTION
1, GENERAL FACILITY INFORMATION
Virginia Electric Power Company (VEPCO)
Yorktown Station
Yorktown, VA
NPDES Permit No. VA 0004103
County Code 3199
Basin Code 08
Latitude 37° 13' 36"
Longitude 76° 27' 17"
Major SIC 4911
Total Flow 1,430,000 gallons per day
Oil-Fired Steam Electric Power Plant - 1220 MW Capacity
2, OUTFALL DESCRIPTION
2.1 OUTFALL 001: 1,430,000 gallons per day from all
sources in plant including ceding
water and ash lagoons.
GCA/TECHNOIOGY DIVISION
-------
GCA, TECHNOOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL FACILITY INFORMATION
CARD
NO.
NPOES NO.
1 I
COUNTY
NO.
BASIN CODE
SIC CODE
MAJOR
T~
/7|i8ii9l20fel
SIC CODE
MINOR
SIC CODE
MINOR
SIC CODE
MINOR
flCWRATE
90I/day
MAJOR INDICATOR-
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LONGITUDE
dd
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is «
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|
-------
GCA/TECHNOIOGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
FLOW RATE MEASURED OR ESTIMATED
DESCRIPTION OF OUTFALL
MODE OF—
DISCHARGE
UNITS
OF FLOW RATE
f REL
(ABILITY FACTOR OF
FLOW RATE DETERMINATION
CARD
NO.
NPOES NO.
s
DESCRIPTION OF OUTFALL (CONTINUED)
' 2
4 S
ii e
13 M a
•J17I8
eaon
tfc=Wi
CO 3
-------
A, FACILITY DESCRIPTION (CONTINUED)
3, FACILITY DIAGRAM
INTAKE
INTAKE
COOLING SYSTEM
STEAM GENERATOR
WATER CYCLE
WATER TREATMENT
DEMINERALIZERS
BOILER SLOWDOWN
TUBE CLEANING, ETC.
ASH HANDLING SYSTEM
RUNOFF
FLOOR AND YARD
DRAINS
wOUTFALL 001
THOUSAND
GALLONS
PER DAY
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1, CONSTITUENT DATA FOR EACH OUTFALL
1.1 OUTFALL 001:
1,430,000 gallons per day from all
sources at the plant
CONSTITUENT
Ammon i a
Ammon i um Nit rate
Chi ori ne
Chromium
Zinc
Nickel
Copper
Organ i c N i trogen
Ni trate
Phosphorus
Sulfite
B romi de
Fluorine
Aluminum
I ron
Magnes i um
Manganese
Sod i um
Titanium
Oil and Grease
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
Appl i
Appl i
Appl i
Appl i
Appl i
Eng i neer i ng
Eng i neer i ng
EPA Publica
NPDES Appli
NPDES Appli
EPA Publica
NPDES Appli
EPA Publica
NPDES Appli
EPA Publica
NPDES Appli
EPA Publica
NPDES Appli
EPA Publica
NPDES App i i
EPA Publica
NPDES Appli
EPA Publica
NPDES Appli
EPA Publica
NPDES Appli
Eng i nee r i ng
Eng i nee r i ng
Eng i nee ring
cat i on
cation
cat i on
cation
cation
Judgment3
Judgment3
tion ,l
cation
cation
tion,1
cat i on
tion,x
cation
t i on , 1
cation
tion,1
cat i on
tion,1
cation
tion,1
cation
t i on , 1
cat i on
tion,1
cat i on
Judgment3
J udgmen ta
Judgment3
GCA/TECHNOLOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Steam Electric Power Generating Point
Source Category, EPA-4^0/1-7*»-029a, October
2.2 ENGINEERING JUDGMENT
aThese compounds were assumed to be present since
they have been reported as existing in the dis-
charges of other oil-fired boiler facilities.
GCA/TECHNOLOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT CONCENTRATIONS
1, CONCENTRATION DATA FOR EACH OUTFALL
1.1 OUTFALL 001:
1,430,000 gallons per day from all
sources at the plant
CONSTITUENT
Ammon i a
Ammonium Nitrate
Chlorine
Chromiurn
Zinc
Nickel
Copper
Organ i c Nit rogen
Ni trate
Phosphorus
Sulfi te
Bromi de
Flou r i ne
Alumi num
I ron
Magnes i urn
Manganese
Sod i urn
Titanium
0! 1 and Grease
CONCENTRATION
0.609 ppm
1.43 ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
8.57
2.40
1 .29
6.43
1 .29
1 .00
0.61
1 .00
ppm
0.01 ppm
0.01 ppm
1.00 ppm
1.00 ppm
0.01 ppm
10.0 ppm
0.01 ppm
5.00 ppm
0.01 ppm
1 .00 ppm
REFERENCE
NPDES Application
NPDES Appl i cat ion
NPDES Appli cat ion
NPDES Application
NPDES Appli cat ion
Engineering Judgment3
Engineering Judgment3
Engineering Judgment3
NPDES Application
EPA Publication,l
Engineering Judgment"3
Engineering Judgmentc
Engineering Judgment3
Engineering Judgment3
EPA Publication,1
Engineering Judgment1*
EPA Publication,l
Engineering Judgment6
EPA Pub 1i cation,1 f
Engineering Judgment'
EPA Publicat ion,l
Engineering Judgment3
Engineering Judgment3
Engineering Judgment3
EPA Publication,1
Engineering Judgment^
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Steam Electric Power Generating Point
Source Category, EPA-HO/1 -7V-029a, October
2.2 ENGINEERING JUDGMENTS
Concentration data for this compound was taken
from data reported on NPDES Permit Applications
of other power plants having characteristics
similar to those of this station.
Phosphorus concentrations ranging from 0.1 to 2 ppm
were reported in Reference 1. The range is due to
the different treatment methods which could be used,
An average value of 1 ppm was assumed for this
plant.
This value was arbitrarily chosen.
This value corresponds to the minimum solubility of
aluminum at a pH = 7. Solubility varies with pH.
The concentration of iron was taken to be the
minimum solubility of that compound as reported in
Refe rence 1.
The background concentration for magnesium was
assumed.
^Reference 1 reported oil and grease concentrations
of 2 to 20 mg/1. Using an average concentration of
10 mg/1 and a dilution factor of 10, the resultant
oil and grease concentration is 1 ppm.
GCA/TECHNOIDGY DIVISION
-------
GCA TEOHNOIQGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
CARD
NO.
l
D
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COMMENTS
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-------
GCA TECHNOOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
I—METHOD OF ANALYSIS
UNITS OF 1
CONCENTRATION
FACTOR OF ENCODED CONCENTRATION
LOCATION—i
IN PROCESS
CHEMICAL GAS NO. f
-------
DETERMINATION OF OUTFALL TUDR
SOURCE.
NPDES PERMIT NO,.
OUTFALL NO,
FLOW RATE 100.OOP GALLONS PER DAY
A B C D E
CHEMICAL CONSTITUENT CONCENTRATION DMEG VALUE DEGREE OF HAZARD TUDR
(D x FLOW RATE)
EXAMPLE:
CHROMIUM
1 X 10
-6
1 X 10
-3
(B/C)
1 x 10"3
1 x 10J
CONSTITUENT N
OUTFALL
= 7 X 10'
O
Si
e
-<
c/5
DETERMINATION OF FACILITY TUDR
OUTFALL NO
EXAMPLE:
oT
TUDR
7 X 102
OUTFALL N
ETUDR]
FACILITY
= 8,1 x 102
-------
AMOCO (VA 3018)
A, FACILITY DESCRIPTION
1, GENERAL FACILITY INFORMATION
American Oil Co.
Yorktown, VA 23490
NPDES No. VA 0003018
County Code 3199
Basin Code 08
Latitude 37° 13' 18"
Longitude 76° 26' 18"
Major SIC 2911
Total Flow 7.26 x 107 gallons per day
50,000 barrels per day petroleum refinery
produces - gasoline, distillate fuels, LPG,
sulfur coke, and gas
2, OUTFALL DESCRIPTION
2.1 OUTFALL No. 1
Flows - 39,100 gallons per minute (5.6 x 107
gallons per day) from once-through
cool ing water.
- 1,300 gallons per minute (0.19 x 107
gallons per day) from process.
Total
Flow - 40,400 gallons per minute (5.82 x 107
gallons per day) from process.
Flow values from NPDES Application.
2.2 OUTFALL NO. 2 '
Flow - 1.00 x 101* gallons per minute (1.44 x 107
gallons per day) from sewers and storm
runoff, flow depends on rainfall.
Flow values from NPDES Application.
GCA/TECHNOIOGY DIVISION
-------
GCA, TECHNOQGY DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL FACILITY INFORMATION
CARD
NO.
NPOES NO.
COUNTY
NO.
>1*
I1JMJIJ|I6
BASIN CODE
/7II8II9 IZOfel
34 »
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MINOR
SIC CODE
MINOR
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MINOR
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SIC CODE
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90l/day
m
MAJOR INDICATOR-
m
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AOl
i
CARD
NO.
NPDES NO.
SOURCE NAME
OWNER/OPERATOR NAME
4 15
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NO.
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GCA/TKHNOUDGY DMSION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL INFORMATION
CARD
NO.
NPDES NO.
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SIC CODE
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UNITS -
OF FLOW RATE
RELIABILITY FACTOR OF
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NPDES NO.
DESCRIPTION OF OUTFALL (CONTINUED)
CARD
NO.
NPOES NO.
i
is
DESCRIPTION OF OUTFALL (CONTINUED)
-------
GCA/TECHNOOGV DIVISION
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
GENERAL OUTFALL
CARD
NO.
; '••>
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11 i 1 i - 1 ; i 1 i i i 1
-------
A, FACILITY DESCRIPTION (CONTINUED)
3, FACILITY DIAGRAM
0.19 x 107 GALLONS PER DAY
OXIDATION PONDS
5.63 x 107 GALLONS PER DAY
5.82 x 107
GALLONS PER
DAY
1.M x 107
GALLONS PER DAY
OUTFALL
NO. 1
OUTFALL
NO. 2
50,000 BARRELS/DAY
PETROLEUM
PROCESS
COOLING SYSTEM
SEWERS
GASOLINE,
DISTILLATE
FUELS,ETC.
INTAKE
GCA/TECHNOIOGY DMSION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS
1, CONSTITUENT DATA FOR EACH OUTFALL
1.1, OUTFALL NO. 001 - 5.63
cooling water and 0.19
process water
107
107
gallons per day
ga11ons per day
CONSTITUENT
Chloride
Cyan i de
F 1 uor i de
Aluminum
Ar sen i c
I ron
Lead
Zinc
Oil and Grease
Phenols
Cadm i urn
Chromium
Copper
Nickel
Total Organic Carbon
Bis (2-ethylhexyl)phthalate
Chrysene
Benzo (a)anthracene
Benzo (a)pyrene
Perylene
Mercury
Cyan i de
Phenol
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
EPA
EPA
App
App
App
App
App
App
App
App
App
App
App
App
App
App
App
Publ i
Publ i
1 cation
cation
cat i on
cat i on
cation
cation
cation
Eng i neer i
EPA Publ
Eng i neer
EPA Publ
Eng i neer
EPA Publ
neer
Publ
Publ
Publ
Eng I
EPA
EPA
EPA
cat on
1 cat on
cat on
1 cat on
1 cat on
1 cat on
1 cat on
1 cat on
cat i on1
cat i on , 1
ng Judgment3
cat i on, 1
ng Judgment3
cat ion,1
ng Judgment3
cat i on , 1
ng Judgment3
cat i on*
cation1
ca t i on 1
GCA/TECHNOtOGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
1.2 OUTFALL NO. 002 - 1.U x 107 gallons per day from
sewers and storm runoff.
CONSTITUENT
Total Organic Carbon
Chi or i de
Cyan i de
Fl uorIde
Alum!num
Arsen i c
I ron
Lead
Zinc
Oil and Grease
Phenols
Cadmi urn
Copper
Nickel
Bis(2-ethylhexyl)phthalate
Chrysene
Benzo(a)anthrecene
Benzo(a)py rene
Perylene
Mercury
Cyan i de
Phenol
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
EPA
EPA
App
App
App
App
App
App
App
App
App
App
App
App
App
App
Publ i
Publ i
1i cat i on
1 i cat i on
1 i cat i on
1
Eng i neer i
EPA Publ i
Eng i neer i
EPA Publ i
neer i
Publ i
neer i
Publ i
Publ i
Publ 1
cat ion
cat on
cat on
cat on
cat on
cat on
cat on
i cat on
i cat i on
I cat 1 on
i cat i on
cation1
cation,1
ng Judgment3
cation,
1
ng Judgment
cation
1
Eng i
EPA
Eng i
EPA
EPA
EPA
ng Judgment3
ca t i on , l
ng Judgment3
ca t i on *
cat! on1
cation1
GCA/TECHNOIQGY DIVISION
-------
B, IDENTIFICATION OF DISCHARGE CONSTITUENTS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Petroleum Refining Point Source Category,
Effluent Guidelines Division, USEPA, April ^^7k.
2.2 ENGINEERING JUDGMENT
The Development Document for Petroleum Refining
presents a single quantity for both chrysene
and benzo(a)anthracene because the analysis pro-
cedure used does not differentiate between the
two compounds. The same situation exists for
perylene and benzo(a)pyrene . These compounds
are listed as pairs in the next section to
facilitate the quantitative portion of the project
GCA/TECHNOIOGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT CONCENTRATIONS
1. CONCENTRATION DATA FOR EACH OUTFALL
.1.1 OUTFALL NO. 001
CONCENTRATION
CONSTITUENT
Chloride
Cyanide
Fluoride
Aluminum
Arsen i c
I ron
Lead
Zinc
Oil and Grease
Phenol s
Cadmium
Coppe r
Nickel
Total Organic Carbon
Bis(z-ethylhexyl)phthalate
Chrysene and
benzo(a)anthracene
Benzo(a)pyrene and
pery1ene
Me rcu ry
REFERENCE
2.1 x 10~7 ppm NPDES, Engineering
Judgment3
1.5 x 10~6 ppm NPDES, Engineering
Judgment3
1.4 x 10~2 ppm NPDES, Engineering
Judgment3
1.2 x 10~2 ppm NPDES, Engineering
Judgmen ta
1.5 x 10"1* ppm NPDES, Engineering
Judgment3
1.1 x 10~2 ppm NPDES, Engineering
Judgmen t3
3.9 x 10~3 ppm NPDES, Engineering
Judgment3
1.2 x 10~3 ppm NPDES, Engineering
Judgment3
2.3 x 10~3 ppm NPDES, Engineering
J udgmenta
6.0 x 10~2 ppm NPDES, Engineering
Judgment3
6,8 x 10~2 ppm NPDES. Engineering
Judgment3
5.6 x 10~2 ppm NPDES, Engineering
Judgment3
ppm NPDES, Engineering
Judgment3
ppm NPDES, Engineering
Judgment3
ppb EPA Publ cation1
1 .8
1 .2
0. 1
0.01
0.01
1 .0
EPA Publ
ppb Engineer
EPA Publ
Engineer
ppb EPA Publ
cat ion, l
ng Judgment
cat ion,l
ng Judgment'3
cation
GCA/TECHNOIDGY DIVISION
-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
1.2 OUTFALL NO. 002
CONSTITUENT
Chloride
Cyan i de
Fluoride
Alurn i num
Arsen i c
I ron
Lead
Zinc
Oil and Grease
Phenols
Cadmi urn
Ch romi urn
Copper
Nickel
Total Organic Carbon
B5s(z-ethylhexyl)phthalate
Chrysens and
benzo(a)anthrecene
Benzo(a)pyrene and
pe ry1ene
Mercury
CONCENTRATION
REFERENCE
6
5
3
.!» x 102
.1 x 10"1*
.9 x TO'2
10
< 0.06
190
150
25
23
55
55
100
55
95
k. 8
10
1
1
1
ppm
ppm
ppm
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
NPDES Appl Ication
NPDES Appl icat ion
NPDES Appl icat Ion
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl ication
NPDES Appl i cation
NPDES Appl ication
NPDES Appl tcation
NPDES Appl ication
NPDES Appl icat ion
NPDES Appl i cat i on
NPDES Appl ication
EPA Publ icat ion1
EPA Publ ication, l
Engineering Judgmen
EPA Publ ication, 1
Engineering Judgmen
EPA Publ ication, l
Engineering Judgmen
tb
tb
tc
GCA/TECHNOLOGY DIVISION
-------
OCA. TECHNOIDGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
UNITS OF -
CONCENTRATION
(—METHOD OF ANALYSIS
r-RELIABILITY FACTOR OF ENCODED CONCENTRATION
LOCATION —,
IN PROCESS!
-------
GCA TECHNOLOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
CARD
NO.
i
D
0
0
0
0
0
0
D
0
D
0
D
0
0
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0
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1
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4
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GCA TKHNCHOGY DM3ON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
CARD
NO.j
i
D
0
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COMMENTS
K
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-------
GCA TECHNOiOGY DMSON
SOURCE INVENTORY/TOXIC DISCHARGE
INPUT CODING FORM
DISCHARGE CONSTITUENT INFORMATION
CAPO
NO.
l
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0
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-------
C, DETERMINATION OF DISCHARGE CONSTITUENT
CONCENTRATIONS (CONTINUED)
2, LIST OF REFERENCES
2.1 LITERATURE REFERENCES
Development Document for Effluent Limitations
Guidelines and New Source Performance Standards
for the Petroleum Refining Point Source Category,
Effluent Guidelines Division, USEPA, April 197**.
2.2 ENGINEERING JUDGMENT
It was assumed that the NPDES data represented
process water only and a dilution factor of 100
was included to account for cooling water in the
d i scha rge.
Reported as a single concentration in reference.
Intake concentrations of these compounds were
significantly higher than discharge concentrations
Reported discharge concentration is equivalent
to intake concentration.
GCA/TECHNOIOGY DIVISION
-------
DETERMINATION OF OUTFALL TUDR
SOURCE
NPDES PERMIT NO,.
OUTFALL NO,
FLOW RATE 100,000 GALLONS PER DAY
A B C D E
CHEMICAL CONSTITUENT CONCENTRATION DMEG VALUE DEGREE OF HAZARD TUDR
(D x FLOW RATE)
EXAMPLE:
CHROMIUM
1 X 10
-6
1 X 10
-3
(B/C)
1 X 10"3
1 X 10
+2
O
CONSTITUENT N
OUTFALL
- 7 x 10'
DETERMINATION OF FACILITY TUDR
OUTFALL NO,
EXAMPLE:
01
TUDR
7 X 102
O
I
OUTFALL N
ETUDR]
FACI
LITY
_ 0
,1
X
10
2
-------
APPENDIX A
RELIABILITY OF CHEMICAL CHARACTERIZATION DATA
The reliability of Che data utilized for the chemical characterization
phase of this study varies significantly as a function.of its origin. In order
to provide the reader with an appreciation of the value of these estimates, a
set of reliability factors were developed which reflect the validity of the
data sources and assumptions employed. The definition of these reliability
factors is summarized in Table A-l.
TABLE A-l. RELIABILITY FACTORS
Number Definition Typical data source
1 Measured - Substantive data Discharge Monitoring Report (DMR)
2 Measured - Limited data NPDES permit application
3 Estimated - Good data Application of similar data
4 Estimated - Limited data Industry summary data
5 Engineering judgment Priority pollutant listing
Reliability Factor No. 1 was "reserved" for Discharge Monitoring Reports since
these documents reflect a continuum of actual measured data from the specific
source and on a relative basis should be fairly accurate. Reliability Factor
No. 2 reflects direct and reliable, but limited, data determined from NPDES
permit applications and other regulatory authorized reporting forms. Such in-
formation is based on spot measurements or well-developed plant estimates.
Reliability Factor No. 3 was developed to reflect the application of good (RF
No. 1 or RF No. 2) data to a source which has comparable processes/unit opera-
tions, and as a result, may exhibit some degree of inaccuracy. Factor No. 4 •
is based on the application of generic industry data to a specific source and
GCA/TKHNOtOGY DIVISION
-------
therefore can be erroneous depending on the degree to which the source descrip-
tion parallels the general description. Factor No. 5 is reserved for the most
subjective of judgments - engineering estimates. Such estimates are based on
general scientific principles such as lowest level of solubility, minimum detec-
tability limits, mass balances, extension of facility effluent comparability
information, and extrapolation of similar discharge concentrations. The relia-
bility factor for each compound is given in column 45 of the sample D cards.
CONCENTRATION AND QUANTITY UNIT CODES
Quantitative data gathered during the course of this study were re-
ported in several different types of units. A code letter was assigned to
each type of unit. The code letters and the units which they represent are
given in Table A-2. Unit code letters appear in column 43 of the sample D
cards.
TABLE A-2. CONCENTRATION
AND QUANTITY
UNITS CODES
Code
letter
M
M
B
B
K
P
Concentration
or quantity
units
mg/1
ppm (by weight)
Mg/1
ppb (by weight)
kg/yr
Ib/day
OCA/TECHNOLOGY DIVISION
-------
CHEMICAL USE CODES
Chemical Use Codes were assigned to each compound to separate those com-
pounds presumed to be a discharge stream from the compounds which were stored,
used or manufactured by a facility. Although this study primarily sought to
define chemical compounds that were present in the effluent discharge streams
under consideration, other information on compounds handled by a facility was
considered for its potential to be discharged. When specific information
existed on compounds that were manufactured, used or stored at a facility,
this information is included on the D card, but it is not used in the calcu-
lation of facility toxicity. The Chemical Use Codes in Table A-3 may be found
'x
in column 44 of the sample D cards.
TABLE A-3. CHEMICAL
USE CODES
Code
, Description
letter *
U Used within process
M Manufactured
S Stored
D Discharged
GCA/TECHNODGY DIVISION
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