United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EPA-450/4-80-035
November 1980
Air
Continuous Rural Ozone
Data Collection in the
Northeast United States
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EPA-450/4-80-035
Continuous Rural Ozone Data
Collection in the Northeast
United States
by
Environmental Research and Technology, Inc.
696 Virginia Road
Concord, Massachusetts 01742
Contract No. 68-02-3522
EPA Project Officer: Edward J. Hanks, Jr.
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air, Noise, and Radiation
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
November 1 980
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TECHNICAL REPORT DATA
{Please read Instructions on the reverse before completing/
1 REPORT NO. 2.
EPA-450/4-80-035
4. TITLE AND SUBTITLE
Continuous Rural Ozone Data Collection
in the Northeast United States
7. AUTHOR(S)
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Environmental Research & Technology, Inc.
696 Virginia Road
Concord, Massathusetts 01742
12. SPONSORING AGENCY NAME AND ADDRESS
United States Environmental Protection Age
Office of Afr Duality Planning and Standa*
Research Triangle Park, North Carolina 27>
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
November 1980
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-3522
13. TYPE OF REPORT AND PERIOD COVERED
jncy
"CJS 14. SPONSORING AGENCY CODE
m
is. SUPPLEMENTARY NOTES EpA Project officer: Edward J. Hanks, Jr.
Contractor Project Manager: Richard D. Andrews
16. ABSTRACT
This report presents rural ozone data collected in the Northeast United States
during the summer period of July 1 to September 12, 1980. The monitoring was
performed at four former Electric Power Research Institute-Sulfate Regional
Experiment (EPRI-SURE) monitoring stations at Montague, MA; Scranton, PA;
Indian River, DE; and Lewisburg, WV.
17 KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Air Quality Monitoring
Ozone
Rural Oaone
EPRI-SURE
Northeast United States
NECRMP
Data Collection
19. DISTRIBUTION STATEMENT
b.lDENTIFIERS/OPEN ENDED TERMS c. COSATI Field/Group
41
20. SECURITY CLASS 'T),is page> 22. PRICE
Fwm 2220-1 (Re». 4-77} SREVIOUS EDITION is OBSO'-ETE
-------
This document is issued by the Environmental Protection Agency to report
technical data of interest to a limited number of readers. Copies are
available free of charge to Federal employees, current EPA contractors and
grantees, and nonprofit organizations - in limited quantities - from the
Library Services Office (MD-35), U.S. Environmental Protection Agency,
Research Triangle Park, North Carolina 27711; or, for a fee, from the
National Technical Information Service, 5285 Port Royal Road, Springfield,
Virginia 22161.
This report was furnished to the Environmental Protection Agency by
Environmental Research and Technology, Inc., 696 Virginia Road,
Concord, Massachusetts 01742, in fulfillment of Contract No. 68-02-3522.
The contents of this report are reproduced herein as received from
Environmental Research and Technology, Inc. The opinions, findings and
conclusions expressed are those of the author and not necessarily those
of the Environmental Protection Agency.
Publication No. EPA-450/4-80-035
ii
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TABLE OF CONTENTS
Page
DISCLAIMER ii
ABSTRACT l
INTRODUCTION 2
CONFIGURATION 3
OPERATIONS 11
DATA VALIDATION 15
APPENDIX A - DATA REPORT 21
APPENDIX B - CALIBRATION SUMMARIES 34
APPENDIX C - ERT STANDARD OPERATING PROCEDURES 40
ill
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LIST OF FIGURES
Figure Page
Figure 1 Sample and Data Flow for Continuous Monitoring 6
Q
Figure 2 System for Generating Test Atmospheres
Figure 3 Level I Data Validation Flow 16
Figure 4 Level II Data Validation Flow 18
IV
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LIST OF TABLES
Table Page
1 Monitoring Station Locations and Identification 4
2 External Sampling Location Criteria for Sites 5
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ABSTRACT
This report presents rural ozone data collected in the Northeast
United States during the summer period of July 1 to September 12,
1980. The monitoring was performed at four former Electric Power
Research Institute-Sulfate Regional Experiment (EPRI-SURE) monitoring
stations at Montague, MA; Scranton, PA; Indian River, DE; and
Lewisburg, WV.
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INTRODUCTION
The network of ozone monitoring stations was defined by EPA to be
the four former EPRI-SURE monitoring stations located near Lewisburg,
West Virginia; Indian River, Delaware; Scranton, Pennsylvania; and
Montague, Massachusetts. Analyzers were supplied as Government
Furnished Equipment. Specifically, Monitor Labs Model ML 8410E ozone
analyzers and strip chart recorders were used in the program.
The monitoring program was conducted during the period of July 1
through September 12, 1980. Scheduled checks and calibrations were
performed at times other than during the daily time period of 9:00 AM
and 6:00 PM LOT, thus allowing a continuous record of daytime ozone
concentrations.
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CONFIGURATION
Four existing EPRI-SURE monitoring station locations were
selected by the EPA for the conduct of this program. Station
locations and their identifications are listed in Table 1.
When the stations were originally located in 1977, it was
desirous that the locations meet EPRI-SURE program specified
criteria. The external siting criteria is presented in Table 2. It
was impossible for all sites to comply exactly with all of the
external criteria. Confirmation of or deviations to the external
criteria follow:
Montague - Met all external criteria except for the
proximity of tall trees.
Scranton - Met all external criteria except for its close
proximity to a dirt road and corn field.
Indian River - Met all external criteria and the Prevention
of Significant Deterioration (PSD) Guideline siting criteria.
Lewisburg - Met all external criteria and the PSD Guideline
siting criteria.
Environmentally controlled shelters housed the monitoring
equipment. Each shelter was equipped with a Monitor Labs Model 8410E
ozone analyzer, Esterline Angus MS 412C strip chart recorders, signal
distribution system, and an air inlet manifold system. An equipment
block diagram is presented in Figure 1.
Ambient air entered an inverted sampling probe located
approximately one meter above the shelter roof (between 4 and 7 meters
above grade elevation) and was moved into the sampling manifold at
approximately 80 1/min using a continuously operating pump at the
opposite end of the manifold. Thus, a constant supply of ambient air
was available for sampling.
The Monitor Lab 8410E chemiluminescent 0., analyzer operating on
the 0.5 ppm scale was used to monitor 0^. This instrument was
chosen because of its availability on loan from EPA. In this system
the fixed air flow is mixed with a fixed ethylene flow. Any 0.,
-------
TABLE 1
MONITORING STATION LOCATIONS AND IDENTIFICATION
SURE
Site Name/No. ID No. SAROAD ID No. UTM Coordinates UTM Zone
Montague - Ul 1 22 1392 001 A05 00702880
4715550
Scranton - U2 2 39 8040 100 A05 00410640
4604800
Indian River - U3 3 08 0240 001 A05 00476160
4270480
Lewisburg - U4 9 50 0580 002 A05 00558720
4180800
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TABLE 2
EXTERNAL SAMPLING LOCATION CRITERIA FOR SITES
EPRI-SURE PROGRAM
These criteria involve local environment requirements of the sampling
sites .
station location generally to the west of significant point
sources or urban areas. This is upwind under prevailing
wind conditions;
in the case of river-valley terrain, station location above
and away from valley flow regimes;
minimum flow interference by tall trees and obstacles. A
horizontal clearance of ten times the obstacle height is
preferred when the available alternatives permit this.
However, an angular clearance of 30° or less from the
horizontal was acceptable;
avoidance of dirt roads and plowed fields in the vicinity of
the station. A minimum acceptable distance of 30 meters was
sought, but notable exceptions could not be obviated when
placing stations into rural areas; and
a distance of 16 km from any significant sources of sulfur
such as polluted waterways and ponds, and waste-water
treatment ponds.
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Strip Chart
Recorders
Signal
Distribution
System
Chemilumines cent
03
Monitor
Particulate\
Filter
From
Ambient
Air
Probe
Manifold
Exhaust
Fan
Figure 1. Sample and Data Flow for Continuous Monitoring
-------
present reacts with the ethylene to produce a blue light, the
intensity of which is proportional to the amount of 0^ present
(measured with a photomultiplier). No significant interferences are
present in normal, ambient air. The minimum detectable concentration
of this instrument is 2 ppb according to the manufacturer, and this
was attained under field conditions.
The complementary component to the continuous gas measurement
process was the in-station test atmosphere generation system. This
system produced standardized concentrations of 03 against which to
compare instrument responses; it also provided zero air against which
instrument baselines were established.
Figure 2 shows the test atmosphere generation system in block
diagram form. The principle of this system is to dilute a standard
gas concentration with known volumes of air from which that gas has
been scrubbed. This dilution process allows a number of standard
concentrations to be generated so that instrument response in a number
of concentration ranges could be tested.
Zero air was produced by feeding ambient air with an oilless
compressor through a water trap and heatless dryer which consisted of
two tightly-packed columns each containing molecular sieve and
activated charcoal. These columns were switched with a control valve
every 30 seconds to allow recovery and to prevent saturation of the
column. Nearly all of the N02, and Oj were scrubbed by the
charcoal. Following the dryer, 0^ was introduced into the airstream
to convert any remaining NO to NO- which was subsequently scrubbed
by the next activated charcoal column along with the excess Oo. ^
filter following the scrubber removed any particulate matter entrained
in the airstream.
The zero airstream was divided into three lines to serve as zero
or dilution air. The dilution air flow was varied manually with a
Brooks mass flow controller. Changes in this flow rate over its 2 to
15 1/min range allowed different gas concentrations to be generated.
For this program, the uses for the zero air supply were as follows:
-------
60 cc/min
Ambienl
Air
Heatlees
Dryer
Ozonalor
Reaclion
Coil
-
Activated
Charcoal
Silica
Gel
Panicu-
late
Filler
To ML8410
Exhaust
; i''ti re 2.
The System for Generating Test Atmospheres was used for
Continual Tracking of Gas Monitoring Performance
-------
To supply the ozonator, 50 cc/min of the zero air was passed
over the ultraviolet lamp. The amount of 02 produced was
controlled by positioning an adjustable cylindrical shield
at several fixed lengths of lamp exposure to the passing
air, or by adjusting the zero air flow rate.
To dilute or to mix with established 03 concentrations, a
standard concentration of NO in N2 from an NBS traceable
standardized compressed cylinder. The NO was introduced
into the system at 40 cc/min.
To produce standard concentrations, the 03 sweep gases and the
NO standard gas were routed from their normal paths through the
exhaust manifold into the 150cc mixing chamber where they mixed with
the zero dilution air under turbulent air conditions.
NO reacted with 03 j_n this chamber to create N02. With NO in
excess, the difference between the readings of the NO and NOX
channels of a calibrated instrument is equal to the 0., concentration
at the given rate of dilution for a setting of the ozonator UV lamp.
Thus the NO source, together with the ozonator and NO source flow
controllers, served as the in-station standard for OT
The gas mixture was presented to the monitors through a
calibration manifold, distinct from the sampling manifold, which was
accessible by the monitors when a set of solenoid valves switched the
analyzer input to it.
The test-atmospheres could be presented to the monitoring
instruments by either automatically or manually switching the valves.
The automatic feature was used to check baseline and span values for
each instrument daily. These checks took place in the early morning
hours of each day.
The manual switching was used to check the automatic spans when
it showed instrument performance tracking outside of specifications
and on a weekly basis to present a range of test gas concentrations to
the instruments.
-------
All monitoring equipment was field calibrated prior to the start
of data collection. The ML 8410E analyzer was calibrated with a
Dasibi 1003 (Federal Register, Vol. 44, No. 28, Thursday, February 8,
1979) ultraviolet absorption ozone monitor with its internal
calibration source. The Dasibi was also used as a transfer standard
to verify the in-station calibration system. A multipoint calibration
check of the ML 8410E was then performed using the in-station
calibration system.
10
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OPERATIONS
Station operations consisted of keeping all instruments
functioning in such a way that precise and accurate measurements were
made. ERT standard operating procedures were used to govern these
activities. These procedures were supplemented by the manufacturers'
manuals for each instrument and a series of Field Operations Bulletins
which modified standard operating procedures in light of new
experience. A listing of ERT proprietary standard operating
procedures is presented in the Appendix.
A part-time technician was assigned to each monitoring station;
these were veterans of the SURE. Each technician received initial and
follow-up training in the standard procedures for each station and
instrument. The objectives of the field technicians' routine visits
were to:
assess the status of all instruments;
perform maintenance tasks as scheduled or required;
document all significant information for later use in the
analysis of data validity;
report the station status and any problems to the network
operations supervisor in Concord, MA; and
deliver supplies to the station.
A routine visit checklist was filled out each time the sites were
visited. Any negative response to an item was cause for corrective
action. In most cases, this was a regular maintenance item, such as
changing charcoal, which was handled by the field technician without
further consultation. If the problem could not be corrected by the
field technician, he would immediately call the network operations
supervisor to advise him of it. The network operations supervisor
would pinpoint the problem and devise the most efficient method of
solving it. The options ranged from a temporary modification of the
standard operating procedure to airshipping replacement equipment or
sending a repair technician. All negative checklist items and the
11
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corrective actions taken were noted in the station logbook. The
logbook entry was made on a form in three copies one of which remained
in the shelter for future reference; the other two were sent to
Concord, MA on a weekly basis where they were reviewed by the network
operations supervisor and the data validation technicians. This
review resulted in further operations follow-up and was used for
evaluating the data. Since the logbook and checklist entries were
meant to be of use in the data validation process, the field
technicians were instructed to provide as much useful information as
possible which might explain anomalies in the data. The logbook
entries also included:
changes and calibrations of all equipment and serial numbers
of each piece of equipment;
a description of abnormal conditions in the vicinity of the
site such as prevailing weather, or construction which might
affect or bias the data;
a classification of data as valid, invalid or suspect based
on an evaluation of the monitoring instrument status;
activities related to data collection such as the
performance of routine and weekly checks, mailing
checklists, logs and data.
Once per week, the routine visit was extended to perform a more
lengthy evaluation of station performance. The key element of this
check was in-station tracking of all measured quantities. This
involved generating test atmospheres at two concentrations daily (zero
and one concentration level), and at several concentrations weekly
(zero and four concentration levels).
The daily checks were diagnostic; if the instrument response to
the test atmosphere differed from the previous days response by more
than ^10%, the span was re-checked and if still out of tolerance, a
full-scale instrument checkout was initiated.
Additional calibrations were made.following repairs or
replacements of components which failed. The performance of each of
the in-station calibration devices was traceable to a primary standard.
12
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Maintenance items such as changing exhaust filters, etc., were
also attended to on a weekly basis. After these checks, the strip
charts for the week were cut and mailed to the network operations
supervisor in Concord, MA together with the routine visit checklists,
weekly visit checklists, logbook entries and multipoint tracking
results .
Aside from numerous power outages during the program, a few
equipment problems caused losses of data. The following is a data
capture (%) summary for the contract period.
Site July August September
Montague - Ul 98.52 98.92 99.31
Scranton - U2 97.31 95.70 98.26
Indian River - U3 81.59 98.66 98.61
Lewisburg - U4 98.66 99.33 98.26
Copies of,the data reports are enclosed in the Appendix. A magnetic
tape of all valid data was submitted to the EPA project officer as a
part of this report.
Also enclosed in the appendix are summaries of the daily
automatic span delta percents, and summaries of the multipoint
calibration check delta percents for each station. The multipoint
summary also presents the results of the reference Dasibi checks and
the RTI performed audits.
Noted equipment problems during the program were as follows:
Montague - Ul
Balston auto drain broke on 7/23 causing air leak. Suspect water
leak caused erroneous span value on 7/30. Power failure interrupted
span check on 8/11.
13
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Scranton - U2
Multiple power failures disrupted the timer, resulting in missed
span checks.
Indian River - U3
The ML8410E was down on 7/1. A broken wire on the fuse holder
was replaced on 7/2. A power failure on 7/17 caused the ML 8410E to
go full-scale. The chopper motor belt was replaced on 7/21, restoring
the unit to service. On 8/20, the shelter air conditioner failed; the
unit was repaired on 8/29. During a part of this period, the
in-station calibration system was shut down due to the air conditioner
problems. On 9/12 the primary chart recorder jammed. Data was
recovered from the backup recorder -
Lewisburg - U4
Failure of the zero air system on 7/10 and the NO dilution air
system on 7/22 resulted in losses of daily span values. Three span
values were lost in August due to electrical storms and power failures.
On 9/3, the mass flow meter failed causing full-scale span checks
from 9/3 to 9/5. A needle valve was installed in the dilution air
line, restoring the calibration system to partial service.
14
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DATA VALIDATION
The hourly averages determined from Che continuous gaseous
measurements at the sites were subjected routinely to two levels of
validation. These levels have been defined as follows:
Level I - Data which have been compared with station records
but have been only partially edited; this level of data was
used to support initial analyses and interpretations.
Level II - Data which have been validated through instrument
performance checks, calibration, digitization and machine
reading.
The process for obtaining Level I validation is illustrated in
Figure 3. The flow of data began with the instrumentation at each
station providing the station technician with various information
about instrument status, strip chart traces, zero and span values, and
analyzer responses to various tests (multipoint tracking). With this
information, the station technician classified data for specified
periods into three classes.
INVALID over periods when the monitor was not operating at
all.
SUSPECT when the analyzer was operating, but zero/span and
multipoint tracking checks were out of specification, or
when some monitor or system failure which did not stop data
acquisition cast doubt on the data quality.
VALID when all instruments were functioning properly, and
zero/span and multipoint tracking criteria were met.
These designations were recorded in the logbook, and INVALID and
SUSPECT periods were communicated to the network supervisor for
immediate corrective action. The network supervisor also recorded
high and low percent deviations of weekly multipoint tracking to
observe trends which might indicate preventive maintenance. The strip
15
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Instrumentation
-------
charts, logs and tracking data were then transferred to the data
analyst who verified the field technicians' INVALID designations and
confirmed that all such data over the specified period was actually
deleted from the data base.
Strip chart traces were machine digitized. Periods of VALID data
designed by the technician were checked to assure that the data had
been entered into the data base.
SUSPECT data were underlined on the monthly data summaries
(CAPTUR) for each site and parameter. The reasons for the SUSPECT
designation were transferred from the station logsheets onto the
CAPTUR together with daily span and weekly multipoint performance test
data.
During this process, the designations of the station technician
were double-checked to assure that all VALID and INVALID data had been
properly classified. A group leader supervising a team of data
analysts reviewed all monthly data summaries to assure that the above
procedures had been carried out and returned them to the data analyst,
who entered the completed data set into the computerized data base and
archived the annotated CAPTUR. At this point, the data for the
particular parameter, site and month under consideration was
designated as being at Level I validation.
To achieve Level II validation, data from the station
calibrations, daily and weekly performance tests, and performance
evaluations were reviewed together with the tracking graphs, and, if
necessary, the logs and strip charts. This part of the process is
illustrated schematically in Figure 4. All decisions concerning
Level II data validation were documented by the data validation
coordinator, approved by the Technical Director, and implemented by
the data analyst. Typical actions required in the course of this
process included:
examination of the tracking graphs. These were plots of the
changes in percent deviation from designated values of the
lowest and highest test atmosphere concentrations observed
weekly;
17
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Hardcooy
Storage
Logs
_ Stn'o Charts
Tracking Graoh
Validation Summ.
_ CAPTUR
Data
Validation
Coordinator
Corrected
CAPTUR *
cr
3
t-
0.
O
' f
Level II
Validation
Notea
Data Analyst
Approval^
Comments
c
0
~ a
c ««
> 2 o
.r
Technical Director
Data From
Calibration
Performance
Tests and
Evaluation
Computer
Data Base
Figure 4. Level II Data Validation Flow for Measurements at the Sites
18
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assignment of uncertainties to periods of erractic analyzer
responses; and
reclassification of SUSPECT into VALID or INVALID data.
During periods in which deviations of the 0, analyzer responses
were less than 25%, no changes were made in VALID classification or in
the data. When the responses to the test atmospheres exceeded these
deviations, three possibilities were considered:
the test atmosphere was generated within tolerances and the
analyzer response had drifted;
the test atmosphere composition had changed, and the air
analyzer was operating within tolerance; and
both the test atmosphere concentrations and the analyzer
performance had changed.
To determine which possibility applied, an evaluation Vas done of
the station operating logs in which failures of specific components
and the repair or replacement were recorded, and of the performance
test and recalibration data provided by the visits to each station
with the reference Dasibi.
If the Dasibi performance test showed the first possibility, that
in-station test atmosphere was in tolerance, but the analyzer response
was not, then the analyzer was recalibrated.
When malfunction of the test atmosphere generation was indicated,
and the analyzer response remained correct, the SUSPECT data was
reclassified as VALID. Tracking drifts caused by the test atmosphere
generator were primarily due to changes in the gas concentrations
introduced to the dilution air system, rather than due to inaccurate
dilution air flowrates.
Verification of this with the Dasibi performance test allowed the
standard concentrations to be redesignated and their reliability
preserved by the quality control test function.
19
-------
When the Dasibi performance tests showed both the analyzer and
the in-station test atmosphere standard to be outside of
specification, a data qualification with a higher uncertainty would
have been required. This condition did not occur.
Level II of these continuous analyzer data validation activities
included some redundancy of the procedures carried out at the previous
level. This served incidentally as a continual verification of the
data validation procedures.
20
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APPENDIX A
21
-------
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.045
.016
.034
.037
.S. EPA
( ?FM :
HOURS (LST)
10
11
.045
.043
.049
.046
.071
.032
.031
.023
.043
.u42
.068
.026
.028
.035
.085
.082
.042
.026
,0-i9
.071
.056
.0^6
!o32
.029
.036
.064
.074
.050
.015
.044
.037
! 1
12
.044
.040
.061
.048
.087
.028
.033
.027
.042
.042
.075
.027
.029
.036
.067
.085
.053
.027
.062
.090
.071
.051
.OJ8
.026
.036
.068
.066
.056
.018
.053
.036
12
13
.046
.053
.068
.048
.076
.026
.034
.043
.043
.043
.071
.029
.030
.034
.084
.074
.056
,021
.062
.091
.073
.051
.041
.026
.035
.070
. 095
.058
.019
.051
.039
13
14
.05!
.059
.070
.049
.087
.023
.034
.042
.039
.055
.079
.029
.028
.035
.091
.070
.060
.OcM
.079
.085
.067
.050
,04-J
.028
.033
.070
.095
.057
.019
.059
.041
14
15
.058
.072
.077
.054
.1)90
.028
.037
.030
.036
.059
.083
.026
.031
.036
.090
.077
.064
.030
.096
.081
.070
.052
.047
.0211
.039
.067
.1)94
.060
.015
.059
.047
)
15
16
.057
.068
.068
.056
. 104
.037
.030
.999
.040
.063
,05b
.027
.033
.038
.078
.078"
.056
.026
.090
.ObO
.070
.053
.044
.032
.047
.064
.101
.065
.014
.051
.050
16
17
;05fj
.065
.088
.047
.104
.037
.039
.999
.041
.073
.044
.026
.032
.042
.077
.076
.054
.025
.064
.063
, O6 n
.060
.039
.035
.057
.065
. 1 ' 1
.063
.013
.055
.05;
17
ia
.059
.063
.096
.045
.009
.034
.042
.034
.031
.063
.028
.028
.027
.044
.999
.072
.999
.025
.071
.057
.056
.056
.043
. 0 i r.
.060
.061
. 106
.053
.016
.999
.051
18
19
.057
.057
.093
.034
.091
.031
.039
.029
.013
.999
.042
.026
.016
.027
.110
.043
.999
.024
.068
.054
.055
.05'4
.999
.023
.046
.043
. 0 .1 7
.05(1
.012
.999
.035
19
20
.046
.037
.075
.019
.096
.030
.022
,014
.006
.035
.053
.016
.008
.017
.091
.050
.999
.013
.064
.043
.050
.050
.027
.019
.030
.025
.076
.056
.014
.021
.010
LiATA FUR JULY 1Q80
20
21
.059
.017
.052
.006
.063
.025
.014
.005
.003
.019
.046
.010
.000
.015
.075
.O']/
.',-99
.005
,fi59
.037
.051
.048
.(17
.011
.017
.018
.064
.054
.012
.014
.006
21
cd
.Ob9
,('lc
.J37
.002
. 064
.018
.014
.0
.001
.040
.046
.010
.003
.007
.056
.03(1
.032
.0
.059
.025
.036
.039
.Old
. 00}
.015
.014
.054
.042
.009
.003
.003
22
£3
.ObO
.'J06
.oid
.0
.056
.015
.01?
.0
.0
.057
.029
.007
.001
.002
. 0 4 /
.035
.029
.0
. u5b
. ^16
.1)35
.024
.015
. 0
. o 1 u
. u09
,0'j !
.029
.011
.002
.Oii2
23
2'!
.055
.001
. 0 1 c
. 0
,039
.Ot'fc
.011
.0
.0
.057
.021
. LO 3
.0
.003
.042
. 0 ? 9
.022
. 0
.055
.010
.cm
.029
.010
.0
. I.
.008
.o50
.021
.('11
.0
.002
,U 55
.0*0
.fid
. Oc.'b
.053
.027
.021
.013
.Oil
. ! \ 4
.1)49
.(/I"
.('15
.'Jl 1
. 05 i
. C 5 J
. 0 5 2
.OIL
. j .'; <
. tit
- C it
. C i*.
. 026
.016
.u? 2
.032
. L' 5 ^
.01,'
. 022
.021
0
o
o
o
^
<->
Cr
c
G
(D
O
O
o
C;
!; .nil .On .O'is .009 .009 .014 .023 .031 .039 .046 .050 .052 .053 .056 .056 .05i> .052 .047 .037 .030 .025 .021 .017 .('32
31
31
31
31
3i
31
31
31
31
31
31
30
3J
28
27
*!-:. r..,i^b -- 744 NUMbEK OF GOOD HOURS = 733 NUMbFR OF MISSING HOURS = 11 DATA CAPTURE =
...v.Vc I'.ntc ROviS ARE TulAL HOURLY AVERAGES, TOTAL OBSERVATIONS/HOUR AND DATA CAPTURE STATISTICS
.\ffcL. AvErfAi'.t = 0.032 MAXIMUM HOURLY VALUE = 0.111 STANDARD DEVIATION = 0.0259
30 30
98.52
31 31 31
( PEriCENT )
733
o
-------
«.'Jd OAlA REDUCTION PROGRAM VERSION 3.1 (770201)
sc
kANluN
OZONE
U.S. tPA
( PPM }
DATA FOR
JULY
1980
HOURS (LST)
I t.' - j
h .-. - L
JAY
1
?.
3
^
0 i b
J 5 /
,!l.'5
.013
.0^3
. i> : y
.0 .9
.Oil
. 0 J 1
,l'cb
.0 -.4
.dii
. 0 5 b
. n ! 'i
.070
. n,:U
,'J ;9
. 0 1 .1
.0 i9
.Oc:0
.0*4
. c -. j
. (/<;,'
.u ?;
. 0 iO
. O^b
01
0?
.032
.019
.014
.Olb
.Olb
.035
.023
.Oil
.O'lO
.0?!
.02^
.'151
C ^ 3
.020
.016
.052
."U
.032
.013
.On 3
. i>j9
.999
.Olb
.0)5
.013
.u32
.'135
.0 :a
. '.> 2 fc
.021
.017
02
03
.032
.o;6
.019
.019
.Oil
.041
.Olb
.004
.038
.013
.022
.031
& 1 9
.Olb
.OiO
,01
.0 J5
.';)'»
. 0 <5 1
.013
.01 1
. 0 c% b
.0.20
.0"4S
.02!
. 0 ! b
.010
03
04
.029
.0)4
.019
.014
.008
.038
.014
.008
.039
.013
.016
.027
009
.010
,(id I
.Oil;
. o :, ,'
. l>20
.002
.045
.0^1
. 9 v; 9
.O2'j
.011
. Olf
.020
.020
,0s3
.017
, O'l?
.010
04
05
.023
.009
.012
.015
.0 J7
.032
.011
.014
.027
.012
.013
.027
,012
.(.(la
.010
.025
.019
. U24
.001
.050
.049
.010
.022
.009
.010
.013
.008
.030
.009
.038
.010
05
06
.013
.021
.023
.013
.007
.033
.009
.018
.018
.015
.013
.025
.012
.003
.014
.022
.016
.026
.003
.J25
.027
.011
.021
.013
.005
.006
.007
.021
.000
.034
.007
06
07
.019
.027
.025
.015
.008
.033
.004
.026
.014
.016
.018
.024
.Olb
.011
.008
.030
.03b
.022
.003
.012
.012
.015
.021
.020
.003
.003
.008
.033
.009
.024
,012
07
08
.021
.028
.031
.020
.009
.031
.012
.025
.017
.013
.022
.022
. 026
.017
.Olb
.034
.038
.030
.001
.018
.020
.011
.023
.021
.012
.001
.016
.036
.016
.025
.012
08
09
.027
.030
.030
.036
.021
.032
.027
.023
.031
.028
.013
.024
.034
.022
.033
.030
.999
.032
.005
.021
.047
.012
.032
.026
.006
.006
.020
.040
.013
.026
.018
09
10
.034
.034
.029
.055
.041
.034
.033
.029
.038
.039
.015
.028
.037
.015
.043
.053
.033
.036
.013
.043
.050
.015
.037
.030
.020
.033
.042
.042
.017
.030
.015
10
11
.035
.031
.029
.059
.073
.035
.034
.038
.039
.052
.018
.035
.036
.034
.054
.049
.044
.999
.031
.050
.052
.018
.039
.031
.041
.069
.062
.0<,0
.015
.046
.032
11
12
.040
.035
.036
.059
.074
.033
.035
.045
.041
,062
.035
.040
.039
.048
.053
.051
.048
.039
.054
.050
.054
.029
.038
.035
.053
.068
.069
.043
.025
.048
.047
12
13
.041
.037
.039
.059
.071
.030
.035
.044
.044
.065
.044
.043
.045
.049
.058
.055
.047
.042
.055
.057
.056
.035
.040
.044
.061
.G90
.0/8
.UoO
.035
.049
.049
IS
14
.043
.045
.036
.057
.066
.Oil
.037
.042
.046
.067
.052
.042
.046
.048
.071
.056
. 0 ! 4
.049
.050
.065
.059
.0-10
.044
.044
.060
.086
.082
.062
.029
.053
.04fl
14
15
.044
.056
.032
.056
.066
.1)37
.1/34
.044
.C47
.067
.056
.042
.046
.053
.076
.055
.045
.045
.057
.076
.057
.045
.045
.043
.063
.078
.080
.061
.030
.Ofal
.046
15
16
.040
.05b
.032
.057
.070
.042
.034
.049
.048
.062
.059
.042
.044
.054
.076
.050
.048
.042
.058
.090
.ObO
.045
.043
.042
.Ob4
.079
.078
.057
.041
.060
.040
16
17
.045
.049
.030
.057
.062
.04)
.034
.033
.049
.055
.060
,044
,04.3
.050
.060
.046
.040
.045
.059
.106
.Obb
.050
.034
.046
,071
.062
.067
.054
.041
.05!
.052
17
18
.050
.045
.026
.056
.047
. 043
.999
.037
.043
.058
.052
.047
.041
.046
.068
.042
.039
.045
.Obb
.110
.073
.035
.032
.046
.077
.087
.081
.052
.039
.044
.048
18
19
.042
.035.
.025
.062
.050
.046
.9', 9
.045
.043
.058
.045
.044
.044
.046
.067
.039
.040
.045
.078
.097
.999
.999
.029
.046
.077
.101
.083
.041
.030
.044
.056
19
20
.048
.039
.023
.051
.050
.043
.022
.048
.039
.050
.042
.038
.99S
.047
.089
.035
.038
.043
.082
.097
.999
.999
.030
.040
.063
.107
.086
.999
.034
.049
.051
20
21
.052
.033
.022
.043
.043
.041
.021
.055
.032
.046
.043
.038
.999
.051
.086
.034
.042
.036
.061
.107
.999
.999
.024
.034
.065
.100
.086
.032
.038
.045
.038
21
22
.049
.023
.013
.044
.039
.0-41
,0<:b
.053
.023
.040
.038
.038
. 024
.ObO
.063
.039
.046
,02cJ
.07 V
.096
.999
.050
.017
.033
.Oo7
.085
.Ob7
.038
,0t!b
.042
.029
22
23
.040
.018
.013
.029
.041
.Uii
.02.1
.05b
.024
.043
.036
.030
Oc' ^
.051
.oc,b
.0^2
. (i
.030
.062
.1)9-4
. 4 l; s
.027
.021
.03'.
.OhO
.Oh 0
.056
,03b
.023
.02?
.020
23
24
.028
.012
.011
.024
.041
.Oil
.017
.054
.025
.041
.035
.031
.029
.051
.069
.032
.Oi9
.017
,0h2
.(loci
.999
.020
.023
.025
.051
.OfcO
.047
.031
.021
.032
.010
AVG
.036
.OiO
.024
.03S
.039
.036
. OcM
.0 J4
.035
.040
.034
.034
.051
!li5«!
.042
.037
.034
.041
.Obb
.051
. 9->V
.029
.030
.041
.Ob7
.053
.043
.025
.040
.029
AvG .OJ1 .027 .025 .022 .010 .016 .017 .020 .025 .0?3 .041 .047 .050 .052 .053 .054 .054 .053 .053 .051 .049 .044 .040 .035 .038
OAfb 3C 30 30 30 21 31 31 31 30 31 30 31 31 31 31 31 31 30 28 27 28 30 30 30 724
UT/L HuUrtb = 744 NUMbErt OF GOOD HOURS = 724 NUMBER OF MISSING HOURS = 20 DATA CAPTURE =
ALOVt THKtt ROWS AKE TOTAL HOURLY AVERAGES, TOTAL OBSERVATIONS/HOUR AND DATA CAPTURE STATISTICS
,oTAL. AVERAGE = o.osa MAXIMUM HOURLY VALUE s 0.110 STANDARD DEVIATION = 0.0204
97.31 ( PEKCtNT )
-------
Il.lllAN RIVER
U.
OZONE
,S. EPA
( PPM )
DATA FUR
JULY
1980
HOURS (LST)
l!"-Bfl
> 00
h.v-tMJ 01
D.O
1
e
I
C
t
t
7
c
c.
It
; i
\c
i ?.
i t
^ ^,
It
: 7
i C
i V
2(
i <- 1
,. :
Ji
^/
,:
L.'t
,i~l
'I-
J-
.1
., I
;, .M.
D.IO
.949
. 9"9
. O'H
.030
. UMO
.029
. I'
.999
.949
.027
.014
.004
.019
.999
.028
.012
.025
.054
.043
.032
.010
.022
.026
.025
.949
.449
.994
.999
.032
.019
.002
.016
.OJ2
.020
.031
.021
.023
.029
.024
24
05
06
.999
.999
.025
.009
.005
. (i 1 7
.999
.033
.012
.016
.053
.037
i029
.006
.020
u 2 '!
.030
.991
.444
.999
^999
.024
.Olfl
.005
.007
.038
.017
.033
.019
.019
.02(1
.022
24
06
07
.999
.999
.023
.010
.020
.019
.949
.Oi9
.010
.023
.045
.037
.030
.999
.014
.022
.033
.499
.449
.999
.999
.017
.019
.001
.003
.025
.005
.034
.021
.0!7
.013
.021
23
07
08
.999
.999
.027
.017
.045
.033
v-)99
.035
.012
.021
.049
.034
.034
.999
.027
.025
.033
.999
.444
.999
.999
.013
.021
.003
.002
.026
.020
.999
.019
.018
.014
.024
22
08
09
.999
.999
.029
.027
.060
.047
.020
.032
.027
.021
.042
.041
.035
.028
.U36
.033
.034
.999
.449
.999
.999
.019
.021
.006
.024
.035
.046
.999
.020
.030
.033
.031
24
09
10
.999
.999
.034
.047
.079
.043
.030
.020
.040
.023
.049
.056
.040
.049
.047
.044
.039
.999
.944
.999
.034
.029
.020
.010
.046
.045
.053
.040
.017
.041
.039
.039
26
10
11
.999
.999
.039
.057
.OHO
.047
.041
.018
.041
.027
.052
.056
.043
.071
.059
.056
.051
.999
.999
.999
.042
.041
.027
.018
.058
.056
.053
.037
.016
.054
.039
.045
26
11
12
.999
.999
.046
.074
.063
.044
.044
.025
.057
.037
.073
.059
.042
.075
.071
.067
.060
.999
.994
.999
.054
.045
.026
.033
.058
.066
.052
.034
.027
.064
.068
.053
26
12
13
.999
.999
.051
.089
.060
.048
.046
.036
.067
.046
.081
.067
.046
..074
.079
.072
.068
.999
.949
.999
.056
.053
.023
.052
.057
.068
.054
.037
.031
.062
.055
.057
26
13
14
.999
.999
.050
.094
.049
.044
.042
.039
.079
.056
.069
.072
.063
.081
.079
.069
.065
.999
.999
.999
.062
.048
.025
.054
.062
.070
.053
.035
.014
.065
.052
.058
26
14
15
.999
.999
.051
. 108
.051
.049
.031
.043
.077
.063
.070
.071
.063
.084
.070
.080
.069
.999
.999
.999
.064
.043
.026
.047
.071
.070
.051
.036
.034
.070
.071
.060
26
15
16
.999
.041
.044
.112
.050
.051
.029
,04U
.078
.059
.070
.066
.067
.086
.078
.085
.061
.999
.999
.999
.065
.057
.028
.050
.079
.070
.047
.034
.041
.074
.084
.063
27
16
17
.999
.050
.038
.110
.054
.050
.048
.040
.080
.055
.067
.087
.072
.086
.074
.080
.OdS
.999
.949
.999
.065
.047
.030
.054
.078
.067
.041
.030
.053
.074
.086
.063
27
17
18
.999
.043
.041
.106
.056
.051
.049
.037
.073
.054
.071
.087
.080
.080
.075
.077
.076
.999
.444
.999
.066
.037
.029
.047
.071
.065
.042
.029
.070
.100
.089
.063
27
18
19
.999
.037
.051
.101
.055
.048
.049
.0^6
.075
.049
.073
.086
.083
.074
.068
.949
.049
.999
.444
.999
.056
.027
.021
.044
.076
.067
.042
.029
.072
.095
.089
.059
26
19
20
.999
.036
.047
.100
.044
.043
.045
.019
.067
.052
.105
.079
.072
.068
.058
.999
.999
.999
.999
.999
.043
.016
.023
.038
.077
.065
.044
.027
.065
.075
..081
.056
25
20
21
.999
.035
.043
.081
.038
.034
.042
.016
.060
.043
.112
.064
.058
.063
.049
.042
.999
.999
.994
.999
.036
.034
.023
.025
.061
.061
.039
.025
.049
.056
.068
.048
26
21
22
.999
.036
.041
.069
.036
.034
.03b
.018
.052
.040
.042
.059
.045
.055
.041
.052
.949
.999
.944
.949
.024
.OiO
.022
.028
.056
.056
.038
.027
.052
.043
.063
.044
tb
22
23
.999
.037
.045
.061
.036
.032
.042
.old
.031
.037
.076
.044
.042
.040
.056
. 03cl
.494
.494
.444
.999
.041
.02U
. U 1 o
.008
.070
.057
.032
.024
.046
.043
.051
.040
2o
23
24
.994
.041
.039
.045
.031
.022
.042
.025
.044
.038
.072
.035
.038
,0'i4
.036
,03'(
.444
.999
.444
.999
.046
.024
.010
.001
.069
.059
.027
.028
.044
.049
.044
.038
26
AVG
.999
.994
.040
.060
.043
.036
.036
.030
.045
.041
.064
.059
.048
. 054
.0*9
,04»
.049
.949
.944
.499
.949
.034
.021
.023
.045
.057
.037
.031
.035
.049
.052
.044
607
li'l.^L HuuKS = 744 NUMBER OF GOOD HOURS = 607 NUMBER OF MISSING HOURS = 137 DATA CAPTURE
,i H.^E lh.
-------
.-it
III UCU1 I
otr j-»ou
HK-Jtb 00 01
H^-c.'\Li U 1 02
Oil
1 . 0 d C- .019
i
3
4
f,
fc
7
t
'j
1C
1 1
12
1 i
14
15
1 6
J 7
Id
1 9
to tO
en ^ \
£ P.
^ i
^4
c;~
c't>
. /
i n
< S
: i/
Jl
1. V&
L.'' Y 3
Ui T AL
Ai.Ovt
I U 1 A L
.030 .023
.Oi9 .054
.0^5 .024
.Qtl .021
.o« l . ov;
.022 . 0 1 P
.024 . J 2 3
.030 .n32
.035 .035
.036 ,U2C/
.049 .045
.042 .043
.023 .022
.019 .021
. >j 2 0 .016
.02 j .022
. 029 . 025
.026 .022
.021 .01.',
.016 .nil
.014 . (J 1 0
.026 . 0 2 d
. ti c- 9 .025
. d i/ 3 . J 1 6
. (V* .030
.. '< i -j ,0«b
. U S -> .032
.Oil . 0 2 'J
.1-30 .1)32
,02i' ,u2b
.029 .027
jl 31
HOURS =
FHKEE K0«
AVERAGE =
02
03
.013
.021
.052
.027
,020
.050
.Olo
.023
.036
.038
.018
.039
.039
.018
.016
.0)4
.014
.022
.017
.01''
.011
.007
.024
. 024
.022
.029
.143
.033
.022
.029
.022
.025
31
744
b AK'E
0.
OZONE
03 04 05 06 07 08
04 0} 06 07 08 09
.Olo .011 .010 .011 .019 .031
.017 .
.'J-J7 .
.02« .
.023 .
.043 .
.Ol/ .
.021 .
.039 .
.01') .
.021 .
.031 .
.029 .
.010 .
.Olo .
.012 .
.Ol« .
.017 .
.014 .
.015 .
.013 .
.007 .
. O2'j .
.024 .
.023 .
.034 .
.038 .
. 02d .
.U2,J .
.022 .
.021 .
.023 .
31
014 .013
043 .040
027 .023
029 .033
048 .049
018 .019
019 .021
043 .031
039 .040
014 .015
027 .027
027 .027
013 .016
012 .013
Oil .009
012 .008
014 .017
016 .014
013 .016
006 .008
008 .005
0^5 .u23
020 .021
023 .020
Oil .028
037 .033
026 .025
U 2 c .016
019 .022
020 .017
022 .021
31 31
.015 .027
.041 .039
.023 .032
.037 .036
.047 .048
.020 .026
.016 .023
.031 .038
.040 .040
.023 .999
.026 .031
.031 .035
.018 .025
.016 .019
.013 .022
.011 .025
.022 .021
.019 .015
.015 .020
.010 .018
.011 .015
.024 .022
.028 .026
.025 .026
.035 .048
.054 .039
.Olb ,u!6
.021 .033
.033 .032
.014 .015
.023 .028
31 30
NUMbER OK GOOD HOURS =
TOTAL
HOURLY
AVERAGES,
041 MAXIMUM HOURLY
.043
.037
.038
.oaa
.045
.031
.037
.011
.011
.010
.056
.039
.030
.021
.031
.016
.028
.021
.039
.031
.021
.024
.035
.028
.048
.051
.026
.051
.033
.025
.036
31
734
TOTAL
VALUE
U,
09
10
.040
.059
.041
.043
.032
.046
.039
.049
.039
.041
.043
.063
.036
.047
.019
.050
.057
.044
.047
.046
.037
. d 3 3
.026
.045
.042
.062
.064
.027
.u5l
.040
,u5b
.045
31
S. EPA
HOURS
10 11
11 12
.043 .045
.062 .
.045 .
.045 .
.045 .
.046 .
.048 .
.056 .
.030 .
.047 .
.050 .
.075 .
.037 .
.050 .
.054 .
.055 .
.Oo5 .
.055 .
.058 .
.047 .
.038 .
.043 .
.039 .
.049 .
.065 .
.073 .
.069 .
.030 .
.057 .
.055 .
.069 .
.052 .
31
065
039
047
054
045
053
057
043
050
054
080
041
051
056
069
069
058
062
050
036
048
047
066
076
077
070
040
060
061
069
056
31
( PPM ]
(LST)
12 13 14
13 14 15
.045 .045 .045
.064 .
.040 .
.046 .
.056 .
.044 .
.051 .
.058 .
.055 .
.050 .
.054 .
.079 .
.044 .
.051 .
.052 .
.066 .
.075 .
.061 .
.064 .
.054 .
.037 .
.048 .
.052 .
.064 .
.080 .
.078 .
.077 .
.040 .
.062 .
.060 .
.066 .
.057 .
31
NUMBER OF MISSING
OBSERVATIONS/HOUR AND
- =
0.090
070 .
042 .
043 .
999 .
047 .
053 .
060 .
058 .
05.3 .
052 .
074 .
045 .
049 .
060 .
060 .
070 .
063 .
063 .
053 .
037 .
037 .
049 .
065 .
075 .
078 .
076 .
039 .
074 .
060 .
068 .
057 .
30
HOURS
DATA
072
042
043
040
047
057
060
055
047
052
065
050
050
051
063
060
060
063
054
038
035
056
067
069
073
080
037
080
064
ObB
05b
31
=
15
16
.046
.072
.040
.039
.038
.049
.063
.059
.053
.046
.052
.060
.048
.047
.052
.061
.053
.054
.061
.056
.041
.032
.063
.007
.073
.074
.073
.038
.074
.084
.061
.056
31
10
CAPTURE
STANDARD DEVIATION =
16
17
.051 .
.068 .
.011 .
.012 .
.042 .
.048 .
.063 .
.058 .
.056 .
.047 .
.055 .
.062 .
.047 .
.051 .
.054 .
.064 .
.055 .
.050 .
.065 .
.056 .
.040 .
.032 .
.060 .
.068 .
.079 .
.077 .
.065 .
.034 .
.062 .
.090 .
.067 .
.057 .
31
DATA
DATA FOH JULY 1960 _
O
17 18 19 20 21 22 23
18 19 20 21 22 «!3 21 ©
AVG
059 .055 .011 .051 .039 .036 .032 .031
073 .066 ,05« .050 ,03d .ulO .046 .046 ©
041 .040 .040 .038 .033 .034 .028 .04]
043 .042 .036 .026 .024 .019 .022 .034
017 .050 .053 .051 .052 .050 .043 .039 O
050 .048 .042 .036 ,OJ2 .028 .028 .0*4
056 .050 .044 .036 .037 .028 .027 .037
049 .044 .042 .042 .999 .034 .034 .040
050 .047 .047 .040 .035 .G3b .033 .042
048 .046 .046 .047 .046 .037 .035 .043
058 .064 .072 .066 .Ob5 .059 .050 .0^5
059 .056 .048 .039 .037 .036 .038 .050
Oil .040 .011 .035 .031 .027 .026 .038
055 .048 .037 .029 .030 .026 .024 .031
056 .054 .999 .046 .038 .031 .023 .036
066 .059 .044 .041 .036 .025 .024 .039
078 .077 .075 .060 .038 .034 .031 .045
052 .047 .036 .029 .028 .019 .029 .037
063 .057 .039 .033 .031 .027 .023 .03J
057 .041 .032 .023 .021 .019 .019 .033
031 .026 .027 .021 .017 .014 .016 .u21
037 .999 .032 .027 .027 .032 .027 .02fa
999 .999 .999 .999 .Os2 .043 .036 .037
Ob3 .054 .048 .045 .035 .027 .026 .043
077 .Obb .050 .048 .037 .034 .029 .\ _..__ 9//r/r, AY
\3\DA i t 7 I f'£C/:y
O
O
O
0
o
Q
o
o
c
o
e
c
o
0
o
-------
****** *************
MUNTAbUE
***»»»»**********«***»*»*««****»**********»*»***"*******
U.S. EPA
OZONE
( PPM )
DATA FUR AUGUST
1980
HK-UEL, 00
HK-ENU 01
DAY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
t2
23
24
<;5
dh
27
d6
29
30
31
.001
.001
.014
.002
.002
.002
.0
.0
.047.
.004
.019
.006
.0
.0
.001
.005
.003
.0
.028
.015
.019
.019
.0
.0
.0
.0
.003
.003
.0
.0
.021
01
02
.0
.004
.020
.0
.0
.0
.0
.0
.029
.012
.014
.003
.0
.0
.003
.004
.001
.0
.018
.015
.016
.018
.0
.0
.0
.0
.001
.010
.0
.0
.018
02
03
.0
.009
.023
.0
.0
.0
.0
.0
.025
.021
.014
.004
.0
.0
.003
.002
.002
.0
.015
.015
.015
.019
.0
.0
.0
.0
.0
.007
.0
.0
.017
03
04
.0
.016
.024
.0
.0
.0
.0
.0
.031
.015
.004
.007
.0
.0
.002
.0
.001
.0
.016
.016
.010
.020
.0
.0
.0
.0
.0
.002
.0
.0
.015
04
05
.0
.014
.027
.001
.0
.0
.0
.0
.033
.010
.012
.006
.0
.0
.0
.0
.0
.0
.013
.021
.007
.016
.001
.0
.002
.0
.0
.0
.0
.0
.010
05
06
.0
.013
.022
.005
.0
.0
.0
.0
.036
.010
.032
.004
.0
.0
.0
.0
.0
.0
.01 1
.023
.008
.018
.004
.0
.001
.0
.0
.0
.0
.0
.008
06
07
.0
.017
.018
.006
.006
.002
.0
.001
.035
.010
.015
.003
.003
.0
.0
.003
.0
.0
.008
.024
.013
.018
.007
.004
.007
.0
.003
.007
.0
.0
.005
07
06
.007
.023
.022
.014
.016
.012
.021
.011
.040
.013
.004
.005
.006
.002
.0
.013
.009
.004
.010
.026
.021
.016
.009
.015
.Oil
.005
.009
.030
.0
.004
.007
08
09
.013
.043
.023
.025
.029
.033
.040
.030
.043
.018
.007
.012
.021
.008
.005
.016
.018
.013
.010
.029
.025
.019
.018
.028
.020
.011
.005
.027
.001
.007
.015
09
10
.039
.053
.028
.042
.034
.047
.050
.059
.042
.025
.007
.014
.034
.018
.018
.014
.021
.021
.013
.030
.027
.021
.022
.040
.024
.023
.023
.019
.003
.013
.021
HOURS (L3T)
10 11 12
11 12 13 ,
.073
.057
.039
.050
.041
.060
.050
.070
.040
.031
.009
.030
.043
.018
.033
.015
.027
.026
.015
.033
.026
.023
.029
.041
.030
.043
.034
.024
.005
.037
.036
.090
.062
.052
.049
.056
.061
.050
.065
.045
.033
.011
.046
.042
.024
.041
.013
.029
.038
.020
.035
.025
.031
.030
.040
.032
.057
.038
.027
.01-0
.052
.047
.101
.067
.050
.047
.078
.059
.051
.060
.046
.037
.012
.045
.038
.023
.046
.014
.030
.051
.024
.033
.029
.031
.032
.041
.031
.067
.053
.024
.009
.056
.041
13
14
.115
.068
.045
.051
.107
.067
.050
.063
.045
.035
.011
.043
.034
.031
.048
.020
.029
.054
.034
.031
.029
.032
.038
.041
.029
.069
.059
.021
.011
.055
.044
14
15
.113
.064
.046
.053
.114
.065
.049
.065
.042
.036
.009
.047
.036
.039
.045
.022
.029
.076
.040
.031
.029
.033
.035
.041
.030
.070
.069
.027
.012
.066
.051
15
16
.102
.061
.047
.057
.098
.047
.052
.065
.046
.034
.007
.050
.034
.037
.040
.022
.032
.085
.043
.030
.028
.031
.037
.042
.028
.066
.074
.025
.010
.077
.045
16
17
.100
.055
.047
.057
.101
.047
.061
.061
.038
.036
.010
.045
.031
.042
.039
.022
.034
.093
.042
.027
.029
.030
.039
.999
.028
.064
.076
.025
.006
.081
.039
17
IB
.081
.048
.048
.053
.082
.033
.999
.055
.035
.031
.005
.050
.025
.999
.035
.019
.028
.081
.034
.025
.999
.030
.036
.037
.023
.056
.072
.999
.003
.080
.022
18
19
.060
.036
.033
.030
.070
.022
.032
.040
.030
.025
.007
.036
.008
.999
.031
.020
.017
.074
.023
.022
.999
.020
.020
.025
.015
.040
.049
.999
.0
.077
.009
19
20
.028
.029
.034
.017
.052
.010
.021
.029
.024
.016
.016
.023
.005
.028
.023
.018
.012
.061
.017
.023
.025
.009
.014
.020
.006
.033
.026
.008
.0
.070
.016
20
21
.015
.027
.016
.008
.026
.003
.015
.031
.018
.010
.021
.018
.003
.027
.017
.014
.005
.052
.015
.027
.024
.003
.007
.014
.001
.023
.023
.011
.0
.063
.040
21
22
.003
.032
.011
,ou5
.014
.007
.005
.040
.016
.014
.017
.007
.0
.Oil
.008
.010
.0
,0<40
.012
.027
.026
.001
.005
.004
.0
.013
.014
.007
.0
.057
.030
22
23
.002
.022
.009
.001
.009
.0
.002
.047
.009
.016
.009
.004
.0
.007
.006
.006
.0
.028
.015
.022
.020
.0
.001
.0
.0
.009
.006
.004
.0
.045
.021
23
24
.0
.016
.003
.002
.004
.001
.0
.048
.007
.018
.008
.0
.0
.003
.005
.002
.0
.029
.012
.021
.019
.0
.0
.0
.0
.008
.001
.002
.001
.031
.017
AVG
.039
.035
.029
.024
.039
.024
.024
.035
.033
.021
.012
.021
.015
.014
.019
.011
.014
.034
.020
.025
.021
.019
.016
.019
.013
.027
.027
.014
.003
.036
.025
AVG .007 .006 .006 .006 .006 .006 .007 .012 .020 .027 .035 .040 .043 .045 .048 .047 .047 .042 .031 .023 .019 .014 .010 .008 .023
DAYS 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 30 27 28 31 31 31 31 31 736
TOTAL HUURS = 744 NUMBER OF GOOD HOURS z 736 NUMBER OF MISSING HOURS = 6 DATA CAPTURE
ABOVE THREE HOWS ARE TOTAL HOURLY AVERAGES, TOTAL OBSERVATIONS/HOUR AND DATA CAPTURE STATISTICS
TOTAL AVERAGE = 0.023 MAXIMUM HOURLY VALUE = 0.115 STANDARD DEVIATION » 0.0222
96.92 ( PERCENT )
-------
SCRANIUN
HH-UEb 00 01
HN-LNU 01 02
DAY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
26
29
30
31
.009
.050
.999
.035
.Olb
.054
.025
.073
.055
.032
.032
.051
.037
.023
.064
.036
.023
.009
.029
.044
.039
.034
.023
.045
.045
.Oib
.0/0
.0/6
.057
.Obi
.050
.034
.046
.999
.029
.010
.051
.022
.071
.057
.025
.030
.057
.034
.018
,0b7
.033
.019
.013
.029
.039
.038
.030
.025
.042
.032
.036
.068
.067
.049
.052
.033
02
03
.028
.044
.999
.024
.013
.046
.021
.066
.055
.025
.026
.057
.035
.017
.065
.032
.021
.016
.024
.040
.035
.031
.023
.044
.030
.033
.063
.066
.045
.066
.028
U.S. EPA
OZONE
HOURS (LSI)
Oi 04 05 06 07 08 09 10 11 12
04 05 06 07 06 09 10 11 12 13
.039
.036
.999
.012
.005
.034
.017
.062
.051
.015
.019
.050
.031
.013
.058
.029
.015
.016
.024
.033
.026
.027
.023
.044
.023
.025
.047
.065
.038
.073
.030
.051
.024
.999
.009
.005
.026
.017
.054
.049
.012
.024
.048
.029
.011
.056
.027
.006
.006
.023
.027
.035
.031
.018
.037
.021
.oaa
.046
.056
.036
.063
.026
.059
.011
.999
.012
.005
.023
.006
.051
.049
.014
.022
.047
.030
.014
.051
.023
.007
.004
.021
.027
.030
.029
.018
.032
.030
.oao
.044
.042
.032
.062
.039
.051
.004
.999
.999
.001
.018
.004
.048
.051
.013
.012
.043
.022
.012
.047
.023
.006
.009
.019
.027
.030
.022
.019
.032
.015
.013
.034
.038
.023
.045
.044
.041
.017
.999
.015
.003
.Olfl
.004
.041
.046
.009
.015
.042
.015
.009
.041
.024
.007
.031
.020
.031
.033
.025
.027
.032
.018
.015
.036
.034
.030
.052
.034
.050
.014
.999
.033
.004
.034
.008
.040
.043
.008
.021
.040
.020
.009
.036
.022
.012
.042
.020
.036
.036
.030
.029
.041
.029
.024
.027
.064
.025
.065
.032
.057
.051
.999
.040
.020
.030
.025
.046
.046
.013
.031
.037
.022
.013
.036
.025
.029
.046
.030
.044
.037
.031
.999
.046
.038
.044
.029
.071
.023
.066
.035
.057
.052
.999
.049
.057
.030
.059
.054
.050
.027
.042
.039
.029
.012
.045
.026
.033
.043
.040
.054
.042
.036
.999
.054
.043
.057
.073
.079
.040
.078
.045
.062
.056
.999
.056
.067
.039
.067
.054
.052
.040
.046
.047
.033
.027
.051
.024
.038
.044
.051
.055
.043
.036
.999
.055
.052
.068
.098
.087
.064
.089
.063
.070
.059
.999
.060
.070
.042
.060
.057
.053
.046
.053
.058
.035
.059
.053
.026
.039
.046
.061
.059
.046
.040
.047
.057
.056
.070
.095
.089
.083
.091
.069
( PPM ]
13 14
14 15
.077
.060
.999
.057
.070
.044
.083
.058
.054
.050
.062
.058
.039
.067
.051
.026
.041
.047
.067
.059
.044
.046
.048
.059
.053
.074
.092
.094
.075
.094
.073
.077
.999
.999
.054
.067
.051
.081
.065
.057
.056
.064
.056
.047
.070
.055
.031
.042
.048
.066
.057
.043
.042
.048
.057
.053
.074
.091
.095
.065
.OS5
.077
I
15
16
.071
.999
.033
.053
.067
.049
.068
.058
.059
.050
.064
.055
.053
.071
.053
.033
.042
.048
.064
.054
.044
.046
.045
.057
.056
.087
.094
.099
.062
.094
.086
16
17
-.067
.999
.049
.056
.059
.048
.063
.062
.058
.058
.068
.054
.050
.082
.054
.033
.041
.044
.065
.054
.045
.044
.047
.056
.061
.097
.096
.092
.060
.088
.085
17
18
.070
.999
.056
.048
.052
.043
.073
.061
.059
.058
.999
.056
.041
.083
.053
.031
.043
.041
.066
.057
.040
.044
.045
.058
.999
.104
.096
.087
.057
.088
.086
-V. . .
16 19
19 20
.063
.999
.059
.044
.051
.049
.076
.059
.062
.049
.063
.058
.037
.074
.054
.030
.042
.999
.059
.052
.038
.043
.047
.057
.043
.103
.096
.081
.047
.082
.073
.066
.999
.053
.047
.049
.050
.074
.063
.061
.050
.058
.047
.031
.076
.048
.026
.031
.036
.057
.048
.038
.039
.054
.051
.047
.098
.099
.073
.050
.076
.068
, , w-
DATA FUR
20 21
21 22
.064
.999
.055
.034
.053
.040
.071
.067
.057
.045
.067
.049
.027
.076
.047
.025
.023
.030
.062
.048
.034
.039
.051
.051
.043
.093
. 103
.072
.045
.065
.057
.057
.999
.048
.030
.053
.037
.067
.065
.047
.036
.065
.046
.021
.0/2
.045
.025
.018
.034
.059
.036
.029
.033
.0^0
.048
.038
.069
.095
.Ob7
.053
.054
.057
.
..
AUGUST
22 23
23 24
.058
.999
.042
.024
.048
.03rt
.0/3
.059
.043
.025
.064
.039
.020
.07b
.044
.024
.Old
.030
.059
.031
.025
.033
.050
.043
.040
,0rt2
.084
.064
.055
.050
.057
.058
.999
.043
.020
.055
.030
.077
,0f>(>
.036
.021
.055
.037
.018
.064
.039
.026
.008
.027
.047
.036
.034
.027
.044
.044
.036
.078
.077
.060
.045
.051
.055
-
I960
AVG
.056
.999
.999
.037
.037
.036
.018
.058
.052
.032
.044
.019
.031
.044
.051
.027
.025
.031
.044
.0/14
.017
.035
.037
.048
.019
.060
.073
.072
.048
.071
.054
AVG .041 .039 .037 .033 .030 .028 .025 ,025 .030 .037 .046 .054 .059 .061 .062 .060 .061 .061 .056 .055 .053 .049 .047 .043 .046
DAYb 30 30 30 30 30 30 29 30 30 29 2<> 29 30 30 29 30 30 28 29 30 30 30 30 30 712
TUTAL HUUKS = 744 NUMBER OF GOOD HOURS 5 712 NUMBER OF MISSING HOURS = 32 DATA CAPTURE =
AbOVE THHEE RONS ARE TOTAL HOURLY AVERAGES, TOTAL OBSERVATIONS/HOUR AND DATA CAPTURE STATISTICS
TUTAL AVERAGE = 0.046 MAXIMUM HOURLY VALUE = 0.104 STANDARD DEVIATION « 0.0208
95.70 ( PERCENT )
-------
39S1 UAIA KfcUUbltUN r-KUUKAM
INDIAN RIVER
HH-bEb 00 01 02 03
HH-tNO 01 02 03 04
DAY
1
2
3
4
5
6
7
8
9
10
1 1
12
13
14
15
16
17
16
19
20
21
22
23
t!4
25
26
27
26
29
30
31
AVG
DAYS
.038
.030
.055
.051
.025
.030
.036
.037
.045
.025
.0
-------
LtWlSbUHG
HH-ttEG 00 01
HH-tNU 01 02
DAY
1
2
3
4
5
b
7
8
9
10
11
12
13
14
15
16
17
16
19
..'0
21
22
c!3
24
c!5
db
27
28
rJ9
40
41
.030
.033
.050
.044
,0i;7
.031
.022
.048
.018
.032
.047
.051
.025
.019
.021
.054
.022
.018
.031
.020
.025
,0«b
.044
.019
.013
.015
.019
.018
.0^0
.021
.Odb
.032
.030
.050
.025
.025
.026
.010
.039
.021
.025
.034
.060
.020
.023
.022
.052
.034
.016
.030
.021
.022
.041
.034
.021
.013
.009
.016
.014
.019
.025
.028
02
03
.031
.025
.050
.027
.020
.024
.013
.039
.023
.023
.027
.ObO
.020
.028
.020
.050
.037
.018
.026
.025
.024
.039
.032
.019
.014
.008
.011
.015
.014
.021
.025
03
04
.026
.025
.054
.030
.020
.016
.022
.038
.021
.022
.028
.051
.025
.021
.020
.049
.037
.020
.023
.031
.027
.037
.032
.020
.016
.010
.012
.013
.021
.024
.025
04 05 06
05 06 07
.037
.013
.053
.024
.016
.010
.021
.036
.015
.023
.029
.049
.022
.018
.018
.045
.034
.016
.025
.032
.029
.035
.034
.021
.017
.009
.014
.014
.016
.019
.025
.040
.017
.046
.024
.016
.006
.018
.029
.019
.018
.021
.048
.019
.017
.014
.038
.033
.014
.027
.035
.023
.032
.031
.025
.023
.013
.018
.013
.021
.020
.023
.046
.012
.041
.021
.017
.010
.018
.029
.021
.016
.018
.045
.019
.019
.012
.035
.034
.009
.026
.031
.018
.025
.033
.027
.029
.015
.014
.013
.017
.021
.022
OZONE
07 08
06 09
.056
.019
.052
.020
.017
.015
.022
.029
.022
.021
.023
.044
.024
.021
.016
.038
.031
.012
.023
.999
.026
.036
.043
.032
.026
.017
.016
.015
.023
.027
.020
.059
.036
.062
.028
.028
.029
.026
.031
.036
.039
.033
.038
.025
.029
.034
.040
.032
.014
.023
.032
.036
.040
.049
.034
.029
.022
.021
.018
.028
.032
.025
U.S. EPA
( PPM )
HOURS (LST)
09 10 11 12 13 14 15 16 17 18 19
10 11 12 13 14 15 16 17 18 19 20
.068
.062
.063
.052
.035
.036
.032
.034
.049
.054
.055
.042
.034
.04)
.053
.037
.034
.013
.027
.037
.037
.041
.052
.035
.033
.037
.031
.029
.037
.045
.030
.063
.067
.068
.063
.045
.039
.042
.042
.067
.064
.071
.04H
.048
.067
,060
.048
.036
.018
.037
.040
.044
.041
.054
.033
.047
.058
.056
.055
.053
.063
.038
.057
.074
.064
.062
.056
.047
.053
.051
.082
.070
.067
.054
.069
.071
.067
.051
.036
.021
.046
.044
.045
.046
.055
.038
.056
.070
.069
.066
.075
.069
.050
.062
.076
.062
.069
.056
.043
.065
.064
.079
.077
.073
.058
.067
.072
.070
.051
.037
.018
.043
.053
.055
.050
.056
.046
.058
.069
.073
.079
.079
.062
.056
.067
.074
.063
.066
.054
.052
.065
.064
.079
.080
.074
.063
.065
.075
.071
.049
.038
.025
.046
.060
.064
.054
.052
.053
.060
.071
.074
.079
.078
.057
.056
.078
.071
.064
.056
.064
.053
.060
.055
.097
.074
.072
.070
.067
.071
.066
.047
.034
.035
.050
.063
.072
.049
.053
.051
.059
.072
.074
.084
.076
.049
.060
.078
.070
.065
.062
.057
.049
.055
.066
.091
.077
.072
.071
.066
.070
.065
.042
.041
.030
.045
.065
.069
.044
.049
.050
.059
.065
.073
.085
.082
.048
.060
.075
.072
.069
.055
.056
.050
.050
.067
.075
.072
.072
.069
.072
.067
.061
.040
.040
.031
.046
.059
.058
.050
.045
.052
.055
.063
.067
.080
.090
.048
.059
.076
.074
.063
.045
.055
.053
.047
.068
.063
.079
.071
.074
.068
.065
.060
.044
.035
.027
.048
.051
.051
.052
.045
.046
.049
.057
.067
.070
.085
.047
.049
.071
.08,2
.056
.040
.047
.042
.046
.067
.063
.072
.069
.075
.063
.061
.050
.044
.033
.031
.047
.049
.047
.048
.035
.040
.043
.048
.055
.049
.07b
.041
.047
.065
.067
.042
.049
.045
.036
.041
.056
.062
.055
.067
.999
.045
.060
.039
.040
.029
.038
.037
.043
.045
.043
.033
.029
.031
.034
.035
.999
.057
.037
.042
r
MVK.
DATA FOR AUGUST
20 21 22 23
21 22 23 24
.049
.057
.049
.051
.999
.022
.030
.054
.057
.047
.065
.051
.039
.046
.048
.031
.028
.036
.023
.041
.031
.042
.029
.027
.027
.028
.030
.999
.048
.028
.041
.034
.056
.044
.047
.042
.026
.017
.040
.049
.037
.065
.046
.035
.037
.053
.024
.025
.04*
.019
.028
.0,21
.049
,02ft
.017
.021
.024
.041
.025
.047
.022
.039
.033
.051
.045
,0«3
.037
.021
.023
.028
.035
.025
.051
.039
.024
.030
.05fa
.024
.022
,03t>
.021
.018
,046
.042
.022
.017
.019
.U24
.02}
.020
.032
.029
.029
.032
.060
.034
.026
.031
.020
.028
.022
.033
.030
.049
.034
.017
.026
.064
.019
.017
.031
,01H
.020
.048
.042
.019
.015
.019
.023
.017
.020
.029
.030
.021
* v
1980
AVG
.053
.051
.055
.042
.038
.031
.034
.045
.049
.047
.052
.054
.041
.044
.044
.041
.032
.023
.033
.039
.040
.042
.040
.038
.034
.04b
.038
.040
.04b
.037
.037
AVG .028 .027 .026 .026 .025 .024 .023 .026 .033 .041 .051 .057 .Ofal .062 .063 .062 .060 .058 .053 .045 .040 .034 .031 .029 .041
OAYb 31 31 31 31 31 31 31 30 31 31 31 31 31 31 31 31 31 31 31 29 29 31 31 31 739
TUTAL HOUHS - 744 NUMBER OF GOOD HOURS = 739 NUMBER OF MISSING HOURS = 5 DATA CAPTURE
ADOVE THREE HUMS ARE TUTAL HOURLY AVERAGES, TOTAL OBSERVATIONS/HOUR AND DATA CAPTURE STATISTICS
TUTAL AVERAGE = 0.041 MAXIMUM HOURLY VALUE = 0.097 STANDARD DEVIATION * 0.0190
99.33 ( PEHCENT )
F
/ /
PATE. 79/6/fc
VALID;;,-
/£/i/& /^
-------
U.S. fcPA
MO'l I AUllI
U/UNt
( PPM )
DATA FUK
1960
n«-ti
ill. Uu
HS-C.NU u i
L/A Y
1
c
3
1
5
o
)
6
f>
I u
1 1
12
i l
1 «
Ib
1 b
1 7
1 :>
CM I"*
° dO
d 1
tl
tZ
i-'-.
, ;
.,
d 7
d*i
:;
3.1
,,,
n .».
7 .. 1 '
.'. .1.; .
'U I,
.o : 3
.I'd".
. lidO
.0
. i)5d
.uc 7
.00 1
.0
.014
.11"
.014
.44',
.4^'?
. '-4
. r -I S'
. -1 -, l;
.)'-,
.4 /
.'>~!~i
. -14"
.44 ,
. -''
. 44';
. 441-
. 44
. 44 .
. 4 4 4
. -)4 .
> 1,
l . ""J '
, t II-:
i L 4 v L
ul 0 d
02 03
.!' 7 .011
. "d 7 . I'dO
. c i P . u d 1
. d
,'ibj .libb
.i'27 ,tl9
.0
. u
. 1 :' .0110
. 1 . v, / . L- 0 1
. d 1 . L c1".
. ,44 . '' 44
. '4 . 444
.'I4'l .444
_.,..., _VJS
.4-.-I . '-.'IS
.'.4-i .^'r'j
. -' ' ' 4 .4-14
. /' , . '144
...'.,., ..,..4
. ,4 -i .449
.-.4', .444
.-.-< .444
.1)1 .444
.-'4V .4-/ 4
. ',"' .'.'44
.''l .4^4
.4'.' , .444
. '/I , . 4l'/
1 ..' ! d
281
K : . /. 3 A K h
.- .1 1 = (j .
J3
01
. U0f>
.014
. ol-j
. 0
. Jbo
. JO 2
.0
. II
.ul 7
. 'J
. udn
. 414
. 4 4 4
vj ^ y
.444
.444
.444
. 444
. 444
. ^' 'r 4
.941
. 4 4 -,
, 44 -I
.441
. S 4 4
.444
. 444
. V 4 4
Id
3 ,\ U I
II, 1 ;
027 «
01
Ob
.0 J?
.Olb
.021
.0
. O'jh
.0
. 0
. I/
.'.27
. u
. MdO
.444
.444
.444
. -- 4
.4 ,9
.4 -y^
. 449
.444
. 4 -, 9
.4 <9
. i-<4
.4 <4
.414
.444
.499
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J-ti.Y AVfcnAStb, TUT/.L OhbtKW.T IUHS/HUU* AWO DA (A CAPTUKL
MAXIMUM riUUiv'LY VALUt - 0.091 STANOAKU OtVlATIliN =
DATA CAPTUKt =
STATISTICS
0.0206
9H.61 ( HtKCtMT )
-------
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263
TuTAL no i :> = 288 fjirv.i* ul- bOUD HUUKS = 2b3 NUMlitK OF KISSING hOUkS = 5 DATA CAHTUKE
AoOvt Ir.-Lt Ki>.ib Aht IblAL hUUKLY AVtKAGtS, TOTAL Ut! SE rf V A TI ONb /HUUK AND DATA CAPTUKE STATISTICS
TulAL Av:'
-------
APPENDIX B
34
-------
Daily span delta percents were calculated using the following
equation:
Delta % = Y - X x 100
where:
Y = Analyzer's indicated concentration
X = Known concentration of generated test atmosphere
35
-------
SPAN (DELTA%) SUMMARY FOR U.S. EPA OZONE JULY 19PO
MONTAGUE SCRANTCN INDIAN RIVER LEWISBURG
+ 6.5
+ 3.2
0
-3.2
0
-3.2
-l.fi
+ 1.6
NO SPAN
-3.2
-3.2
!
1
i
f
1
\
1
)
I
2
)
1
5
!'
>
B
5
0
1
u
-1.6
-3.2
-3.2
-3.2
-1-6
-3.2
-6.4
-6.4
-22.6
-1.6
+ 1 . 6
+ 1.6
-3.2
-3.2
-3.2
-12.9
0
-7.0
-5.0
-7.8
-7.8
-10.9
-8.9
NO SPAN
-7.8
-10.9
-ll.fi
-ll.fi
-7.7
-5.5
-7.7
-6.6
-8.e
-12.1
NO SPAN
-12.1
-17.6
MO SPAN
NO SPAN
-2.2
-3.3
-5.5
-6.6
-6.6-
-6.6-
-2.2
-3.3
NO SPAN-
NO SPAN
MO SPAN
-fi.7
-5.5
-8.7
-9 . &
-7.5
-5.5
-7. 1
-8.7
-7.9
-8.7
-14.6
-12.2
-14.fi
-14.6
-14.6
NO SPAN
NO SPAN
NO SPAN
NO SPAN
-12. 2
-14.6
-15.9
-14.6
-14.6
-14.6
-14.6
-15.9
-15.9
-15.9
-17
-17
-19
-19
-19
-17 04
_L / ^/ -
-19.85
94
94
85
P5
85
-19.
NO
NO
-23.
-19.
-21.
-18.
-18.
-18.
-18.
-18.
-24.
-24.
-18,
NO
MO
85
SPAN
SPAN
fifi
85
76
60
60
SO
60
60
42
42
60
SPAN
SPAN
-1
-1
-1
-1
-1
16
16
16
15
16
-1.16
-1.16
-1.16
36
-------
(DELTAS) SUMMARY FOR U.S. ETA CZCNE AUGUST 1980
,y MONTAGUE SCRANTON INDIAN RIVER LEWISBURG
0
i -1.6
i -3.0
, -4.8
-3.0
-3.0
i -3.0
I -1.6
1 -4.8
) -4.8
( NO SPAN
I 1.6
» 1-*
! 3.0
; 3.0
5 1.6
7 3.0
I 3.0
3 -3.0
) -3-0
1 -3.0
3 -l'.6
4 0
5 0
< -1.5
7 -3.0
B -3.0
9 0
0 4.8
1 -1.6
-2. 2
-5.5
NO SPAN
NO SPAN
-3. 3
-4.4
-7.7
-11.0
NO SPAN
-8.8
NO SPAN
-7.7
-3.3
_"5 "3
_>
-4.4
-3.3
NO SPAN
-5.5
-4.4
-3.3
-3.3
-3. 3
-3.3
-5.5
-3.3
-6.6
-5.5
-7.7
-6.6
-13.2
-14.3
-17.1
-23. 2
-23.2
MO SPAN
-20.7
-20.7
-20.7
-20.7
-20. 7
-20.7
-20.7
-23. 2
-20-7
-23. 2
-23. 2
-20.7
-18.3
-19. 5
NO SPAN
-18.3
NO SPAN
NO SPAN
NO SPAN
NO SPAN
NO SPAM
-2.4
NO SPAN
NO SPAN
NO SPAN
-26.8
-25.8
-1. Ifi
-1 . 16
NO SPAN
-1. 16
-1. 16
-1. 16
-1. 16
-1 . 16
-1. 16
-1.16
NO SPAN
-1. 16
-1. 16
-1.16
-1.16
-1.16
-1. 16
-1.16
-1.16
-1.16
-1.16
-1.16
NO SPAN
-1.16
-1.16
-1.16
-1.16
-1.16
-1.16
-1.16
-1.16
37
-------
SPAN SUMMARY (DELTA %) FOR U.S. EPA OZCNE SEPTEMBER 1980
tf MONTAGUE SCRANTON INDIAN RIVER LEWISBURG
1 -4.8 -13.2 -25.P 0
2 -3-0 -15.4 -2^.8 -1.1K
3 -1.5 -9.9 -25.8 FULL SCALE
i 1.6 -5.5 -32.9 FULL SCALE
c -3.0 -9.9 -2^.8 FULL SCALE
j- 0 -6.5 NO SPAN 1. 15
7 -3.0 -9.9 -25.8 0
8 1.5 -7.7 -2«.8 -1.1?
o 1.5 -12.] -25.8 0
10 -3.0 -12.1 -25.8 1..16
S 0 -''.V -25.S -4.55
4.8 -8.8 NO SPAN -3.49
38
-------
MULTIPOINT SUMVAPY SHEET
*****+******************
NETWORK: USEPA 03 STUDY
TEAM/ANALYST: TEAM B/ ARTHUR C.
SITE | PAR.
1
1 1 03
1 1 03
1 1 03
2 1 03
2 1 03
2 1 03
2- 1 03
3 1 03
3 1 03
3 1 03
3 1 03
4 1 03
4 1 03
4 1 03
4 1 03
4 1 03
4 1 03
4 1 03
DATE
7-1 7-80
7-23-PO
7-30-PO
7-07-80
7-13-80
7-22-80
7-2T-80
7-07-80
7-14-PO
7-21-80
7-2P-PO
6-30-80
7-00-80
7-11-80
7-] 5-80
7-22-EO
7-23-80
7-29-80
**********!
REASON
TRACKING
TRACKING
TRACKINC
TRACKING
TRACKING
DA?IBI-CAL
TRACKING
TRACKINC
TRACKING
TRACKINC
TRACKINC
TRACKING
TRACKING
AUDIT
TRACKING
TRACKING
DASIBI-CAL
TRACKINC
****************
S/N
75
75
75
70
70
70
70
78
7 8
78
78
63
63
63
r, 3
63
63
63
t********i
%
-2.2%
-4. 4%
-6.6%
-12.3%
-13. "n
-16. 2%
-6.2?,
-0.7%
-7.4%
-8.0%
-9.9%
-18.5%
-19.3%
-23.0%
-20.3%
-25. '%
-19.9%
-3.6%
t ****** <
COMMENTS/DATA ACTION
k***********************^ *
AUGUST MP'S
1
1
1
1
1
2
2
2
2
2
3
3
3
3
3
3
4
4
4
4
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
8-07-80 |
3-14-80 I
8-21-PO I
8-24-PO I
C-2S-80 |
8-04-CO I
8-11-SO |
8-18-80 I
8-23-80 I
8-25-80 I
8-04-80 1
8-11-80 1
8-1-9-PO |
8-21-80 1
8-21-80 1
8-29-80 |
03 1 3-05-80 I
03 1 8-12-80 1
03 1 8-20-80 I
03 1 8-28-00 |
***********************
TRACKING
TRACKING
TRACKING
AUDIT
TRACKING
TRACKING
TRACKINC
TRACKING
AUDIT
TRACKING
TRACKING
TRACKING
TRACKINC
75
75
75
75
75
70
70
70
70
70
78
78
78
DASIBI-CAL I 78
AUDIT | 78
TRACKINC 1 78
-5 . 6% |
-0.05%
-4.6%
-13.8%
-2.8%
-10.4%
-S. 1%
-7.7%
+ 4.9%
-9.9%
-11.4%
-15.8%
-16.6%
-5.8%
+12.5%
-18.9%
TRACKING 1 63 I -2.7%
TRACKING 1 63 1-4.7%
TRACKINC I 63 1 -5.0%
TRACKINC
63 I -2.3%
i*************************^
SEPTEMBER PPS
1 | 03 1 9-04-CO I
i 1 03 1 9-11-80 I
1 | 03 1 9-25-80
2 | 0"» 1 9-02-80
TRACKING 1 75 | -0.7%
TRACKING I 75 1+4.2%
DASIBI-CAL | 75 1-1.27%
TRACKING I 70 1-13.1%
SHUTDOWN
2
2
3
3
J
3
4
03
03
03
1 03
1 03
1 03
1 9-oo-nn
I 9-12-PO
| 9-03-CO
I 9-l?-80
| 9-17-80
| 9-16-80
TRACKING
DAf.IBI-CAL
TRACKINC
TRACKINC
DASIBI-CAL
DASTBT-CAL
70
70
78
78
70
63
1-13. 1%
1 + 1 . ] 3 %
1-23.1%
I - ? & . 5 %
1-9.23%
I -4.3%
SHUTDOWN
SHUTDOWN
SHUTDOWN
39
-------
APPENDIX C
40
-------
ERT STANDARD OPERATING PROCEDURES
Rev. Title
1 Routine Field Operations and Maintenance
1 Field Calibration of Continuous Air Quality Analyzers
0 Documentation of Field Calibration of Continuous Air
Quality Analyzers
2630-005 0 Calibration Control Logs and Charts
2000-261 A Multipoint Span Check/Field Calibration: Monitor
Labs 8410 Ozone Analyzer
2600-850 0 Strip Chart Recorder Calibration
2600-100 0 Calibration Check/Audit Using a Dasibi 1003 PC or
1003 RS
2750 0 Test Equipment Calibration and Repair
2600-001 0 Precision Checks and Zero and Span Checks of
Continuous Analyzers
2400 0 Traceability of Standards
2580-001 0 Flowmeter Calibration
4000 0 Data Validation
41
------- |