MIDWEST RESEARCH INSTITUTE
                                                EPORT
IRON AND STEEL PLANT OPEN SOURCE FUGITIVE EMISSION CONTROL EVALUATION
                     DRAFT FINAL REPORT
          EPA Contract No.  68-02-3177, Assignment No.  1
                   MRI Project No. 4862-LC'l)

                 Date Prepared:  June 5,  1980
                        Prepared for

          Industrial Environmental Research Laboratory
              U.S. Environmental Protection Agency
          Research Triangle  Park, North Carolina  27711

                    Attn:  R. V. Kendriks

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MRI-NORTH STAR LABORATORIES 10701 Red Circle Drive, Minnetonka, Minnesota 55343 • 612 933-7880
MRI WASHINGTON, D.C. 20006-Suite 250,1750 K Street, N.W. • 202 293-3800

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      IRON AND STEEL PLANT OPEN  SOURCE  FUGITIVE EMISSION,CONTROL EVALUATION
                               DRAFT  FINAL  REPORT
                  EPA Contract No.  68-02-3177,  Assignment No.  1
                            MRI Project  No.  4862-L(l)

                          Date Prepared:   June  5,  1980
                                  Prepared  for

                  Industrial Environmental  Research Laboratory
                      U.S. Environmental Protection Agency
                  Research Triangle Park, North  Carolina  27711

                              Attn:  R. V.  Hendriks
MIDWEST RESEARCH INSTITUTE  425 VOLKER BOULEVARD, KANSAS CITY, MISSOURI 64110  •  816753-7600

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                                  PREFACE
     This  report  was prepared for the Environmental  Protection Agency's
Industrial Environmental Research Laboratory under EPA Contract No. 68-02-
3177, Work Assignment  No.  1.   Mr.  Robert V.  Hendriks, Metallurgical  Pro-
cesses Branch, was the requestor of this work.  The report was prepared in
Midwest Research  Institute's  Air Quality Assessment Section (Dr. Chatten
Cowherd, Head).  Dr.  Cowherd was the principal author.
Approved for:

MIDWEST RESEARCH INSTITUTE
                       kJ^^\
M. P. Schrag, Director
Environmental Systems Department

June 5, 1980
                                    11

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                                 CONTENTS
1.0  Introduction	      1
2.0  Open Dust Sources and Potential Emissions	      3
          Emissions data from previous studies 	      5
          Methodology for more extensive plant surveys 	      9
          Updated emissions inventory	     11
          Sampling and analysis methods	     13
3.0  Control Technology for Open Dust Sources	     20
          Types of control techniques	     20
          Efficiency and cost of control	     21
          Current industry control practices 	     23
          Selection of best controls	     27
4.0  Recommendations for Phase II	     30
          Data needs	     30
          Sampling and analysis procedures 	     32
          Quality assurance program	     40
          Statistical basis for sampling plan	     49
          Distribution of tests	     50
          Proposed test sites	     51

References	     55
Appendices

     A.  Example data compilation from materials handling flow
           charts	:    A-l
     B.  Bibliography for open dust control	    B-l
                                    111

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                                  FIGURES






Number                                                                Page




  1       Effectiveness of road dust suppressants	     8




  2       Example exposure profiling arrangement 	    18




  3       MRI exposure profiler	    34




  4       MRI portable and tunnel	    38
                                    IV

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                                  TABLES






Number                                                                Page




   1      Fugitive Dust Emission Factors Experimentally Determined
2

3

4
5
6

7
8

9
10

11
12
13
14
15
16

17
18
Preliminary Inventory of Open Dust Source Contributions
to Suspended Particulate Emissions 	
Recent and Current Investigations of Control Technology
Applicable to Open Dust Sources 	
Cost Effectiveness of Fugitive Emissions Control Methods .
Control Efficiencies of Road Dust Suppressants 	
Reported Efficiencies for Control of Wind Erosion of
Storage Piles 	
Summary of Fugitive Emissions Controls (By Plant) 	
Parameters Affecting Emission Factors for Open Dust
Sources 	
Sampling Equipment for Open Dust Sources 	
Criteria for Suspending or Terminating an Exposure
Profiling Test 	
Moisture Analysis Procedures 	
Silt Analysis Procedures 	
Quality Assurance Procedures for Sampling Flow Rates . . .
Quality Assurance Procedures for Sampling Media 	
Quality Assurance Procedures for Sampling Equipment. . . .
Quality Assurance Procedures for Data Processing and
Calculations 	
Proposed Distribution of Tests 	
Sources Proposed for Testing at. Armco's Middletown Works .
w
12

22
24
25

26
28

31
33

36
41
42
44
45
46

47
52
53

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                             1.0  INTRODUCTION
     Iron- and steel-making  processes,  which are characteristically batch
or semicontinuous operations,  generate  substantial quantities of fugitive
(nonducted) emissions at  numerous  points in the process cycle.  There are
numerous materials handling  steps  in the storage  and  preparation  of raw
materials and  in  the  disposal of process wastes.  Additionally, fugitive
emissions escape from reactor vessels during chargine, process heating, and
tapping.

     Fugitive emissions in the iron and steel industry can be generally di-
vided into two classes—process fugitive emissions and open dust source emis-
sions.  Process fugitive emissions include uncaptured particulates and gases
that are generated by steel-making furnaces, sinter machines, and metal form-
ing and finishing equipment, and that are discharged to the atmosphere through
building ventilation systems.  Open dust sources of fugitive emissions include
such sources as raw material storage piles,  from which emissions are generated
by the  forces  of  wind and machinery  acting  on exposed  aggregate materials.

     Recent studies of  fugitive  emissions from integrated  iron and  steel
plants1'2 have provided strong evidence that open dust sources (specifical-
ly, vehicular traffic on unpaved and paved roads and storage pile activities)
rank with  steel-making  furnaces  and sinter machines as sources which emit
the largest quantitites  of  fine and suspended  particulate  matter, taking
into account typically applied control measures.  Moreover, preliminary analy-
sis of promising control options for both process sources of fugitive emis-
sions and  open dust sources  indicate that control  of open  dust sources has
a highly favorable cost-effectiveness ratio for particulate.  Although lim-
ited in  scope,  these  studies show that  open dust  sources  should occupy  a
prime position in control strategy development  for fugitive particulate emis-
sions within integrated iron and steel plants.

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     Recent guidance for  State  Implementation Plan revision has generally
included provisions for control of open dust sources.   However,  lack of in-
formation on emissions and control capabilities for these sources has pre-
vented control officials  from  taking full advantage of control  strategies
that include provision for control of the open dust sources.  Furthermore,
although trade-offs between  open  source's and process  sources might result
in significantly improved air quality at a lower cost, this improvement can
only occur if open dust sources can be quantified and  controlled successfully.

     This report presents an evaluation  of  existing data on  the quantities
of pollutants  from open dust sources in  steel plants  and on  the capability
of control procedures  for eliminating or reducing these emissions.   Based
on this  evaluation,  a  testing  program designed to provide needed data on
emissions and controls is outlined.

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              2.0  OPEN DUST SOURCES AND POTENTIAL EMISSIONS
     The open dust sources which are found within integrated iron and steel
plants may be placed into the following generic categories, based on similar-
ity of physical mechanisms for dust generation:

             Vehicular traffic on unpaved surfaces

               Unpaved roads
               Storage pile maintenance
               Unpaved parking lots

             Vehicular traffic on paved surfaces

             Batch drop operations

               Loaders
               Railcars
               Trucks
               Gantry/clamshell buckets

             Continuous drop operations

               Stackers
               Conveyor transfer stations
               Bucket wheels

             Wind erosion

               Storage piles
               Exposed areas
                                   3

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     The ranking of the emissions potential of open dust sources within the
integrated iron and  steel  industry is an important tool in deciding where
control studies should be focused.  This requires the development of a nation-
wide emissions inventory for the industry.

     Calculation of  the  emission rate for a given source requires data on
source extent, uncontrolled  emission  factor and control efficiency.  The
mathematical expression for this calculation is as follows:

          R = Me (1 - c)

          where:   R = mass emission rate
                  M = source extent
                  e = uncontrolled emission factor, i.e., rate of uncontrolled
                      emissions per unit of source extent
                  c = fractional efficiency of control

     Because of the  wide range of particle size associated with emissions
from open  dust sources,  it is important that the applicable particle size
range be  specified  for the calculated emission  rate.   The particle size
range is that for which the uncontrolled emission factor and the fractional
efficiency of control apply.

     As noted  above,  a nationwide inventory of  emissions  from open dust
sources within the integrated iron and steel industry was developed as part
of an  earlier  study.2  For  that  inventory,  source  extent values were based
in part on:  (a)  1976 industry consumption of coal and pelletized iron ore,
and (b) 1977 surveys of four plants.  Representative source parameter values
were taken to be the averages of the values obtained from the plant surveys.
Representative control practices  for  the industry were based on the plant
surveys, and  control  efficiency values for these  measures  were estimted.
The emission factors used for the inventory were those judged to be the most
reliable at the time of the inventory.

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     The reliability of the emissions inventory was limited by its dependence
on data from the plant surveys and on assumed values where data were lacking.
The four surveyed plants may  not have constituted  an adequate  data base to
represent the  industry.  Emission  factor data were sparse  for  some generic
source categories, and control efficiency data were almost totally lacking.

     The remainder of this section reports on the efforts to develop a more
reliable emissions  inventory  to  be used as  the basis  for  determining  the
open dust sources and most promising control measures for which further test-
ing is needed.

2.1  EMISSIONS DATA FROM PREVIOUS STUDIES

     The most extensive emission factor data base available to date for open
dust sources  is  that developed by Midwest Research Institute  (MRI).2  As
shown in Table 1, the MRI emission factors take the form of predictive equa-
tions which contain correction parameters to account for source variability.
The  correction parameters  may be  grouped  into  the following categories:

     1.  Measures of source activity or energy expended (for example, the
speed and weight of a vehicle traveling on an unpaved road).

     2.  Properties of the material being disturbed (for example, the content
of silt in the surface material on an unpaved road).

     3.  Climatic parameters  (for example, number  of precipitative-free days
per year on which emissions tend to be at a maximum).

     The emission factors developed by MRI have been made specific to parti-
cles smaller than 30 |Jm in Stokes diameter, so that emissions may be related
to ambient  concentrations  of total suspended particulate.  The upper size
limit of 30 [Jm for suspended particulate is the approximate effective cutoff
diameter for capture of fugitive dust by a standard high volume particulate
sampler (based on a typical particle density of 2  to 2.5 g/cm).3  It should
be noted,  however,  that analysis of parameters  affecting  the  atmospheric

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                       TABLE  1.     FUGITIVE  DUST  EMISSION  FACTORS  EXPERIMENTALLY DETERMINED BY  MRI
     Soureo catego
                                                M**ar.urt: of  extent
 I.

 2.
I In paved roads


Paved Roads
    Hatch Load-In
      (d.g., front-end ionder,
      titi tear dump)

    Cmiti nuouK Ixiad- in
      (e.g., st.ickcf, transfer
      station)
Vehicle-Mi les Traveled


Voli i c I n- Ml 1 os Tra v o I et\


Tons  of material  I .o ad ed In



To i is  o C Ma t c rial  l
7.  Batch loail-diit
                                     Tons of Mitcsrt.ll  Ixiailpd  (Hit
8.  Wind Erosion of Exposed Areas    Acre-Years of  Exposed  l.and
                                                                                                              a/
                                                                                               tin Is.'. Jon  laclnr-
                                                                                           (lh/iinl.t of  sonrco  oxtcnt )
                                                                                                0.7
 '•' (fc)ft)tf)     (f)
o.oi j  /A)/s_W_i_W«\
       Wlio/u.oooM-)/
                                                                                                        0.5
0.7
                                                                                n.ooin
                                                                           o.onis
                                                                                0.10 K
                                                                                           5 mo

                                                                                O.OOIft
                                           3,400
                                                                                  (!)   (i)
                                                                                  jjojjIl/Tp
                                                                                    f.tiS ) '
                                                                                    I 50 /
                                                                                                                                      Correct lh)

  M - Material Surface Moisture Content (7«)

  Y ~ Dumping Device. (.,'apac i.ty (yd )

  IC~ Activity Correction—

  /

ct
    *  E<|tial.s 7.0 for trucks coining from unpaved to paved  roads  and  releasing  dust  from uiiderhody  of  vehicle;
    *  Equals 3.5 when 207. of the vehicles are forced to travel  temporarily with  one set  uf  wheels .111 ; ..... npaved  road  berm while passing on narrow roads;
    *  Equals 1.0 for traffic entirely on paved surfaces.

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transport of fugitive dust indicates that only the portion smaller than about
5 |Jm in diameter will be transported over distances greater than 5 to 10 km
from the source.4

     Other than MRI' s  previous  work,  a few emission factor data  for open
dust sources exist.  Estimated emission 'factors have been developed for the
handling and transfer of storage materials.  An uncontrolled emission factor
of 0.033 Ib/ton coke for coke being dumped into a blast furnace was calculated
from a measured blast  furnace cyclone  catch.5  This factor might  be appli-
cable to a coke conveyor transfer station.  AISI6 estimated an emission factor
of 0.13 Ib/ton of coke for a conveyor transfer station.  Also AISI6 discovered
an emission  factor  range  from the literature  of  0.04  to  0.96  Ib/ton coal
for general  coal  handling.   Speight7  estimated a value of 1.0  Ib/ton  for
general coal handling.

     In connnection with MRI's emission factor development program,2 limited
testing of  the  effects of a chemical dust suppressant was also conducted.
Coherex® (a petroleum-based emulsion) was used to treat a dirt/slag surfaced
service road  traveled  by  light- and medium-duty vehicles at an integrated
iron and  steel plant.  Coherex® was  applied  at  10%  strength  in water.

     Figure 1 shows a plot of measured dust control efficiency as a function
of the number of vehicle passes following application of the road dust suppres-
sant.  Control  efficiency was calculated  by comparing  controlled  emissions
with uncontrolled  emissions measured  prior to road surface treatment.   As
indicated, the effectiveness of the road dust  suppressant was initially high
but began to decay with road usage.  It should also be noted that the apparent
performance of Coherex® was negatively affected by tracking of material from
the untreated road surface connected to the 100-m treated segment.

     Figure  1  also  shows  the results obtained from the similar testing of
another  chemical  dust suppressant at  a  taconite  mine.8   TREX  (ammonium)
lignin sulfonate--a water soluble by-product of papermaking) was applied to
the waste  rock aggregate  comprising the  surface  of a  haul road.   A 20  to
25% solution  of TREX in water was  sprayed on the road at a rate of 0.08
gal./sq yard of road surface.
                                   7

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                                 EFFECTIVENESS OF ROAD DUST SUPPRESSANTS
00
                  100
                   90
U  80
Z
UJ
U
4-  70
                O
                o;
                »—

                O
                U
   60
                   50
                   40
                                VEHICLE TYPE
                                   DUST SUPPRESSANT
O Haul Truck
A Light Duty Vehicles
Lignin Sulfonate
Co he rex
                     100    120    140    160    180    200    220    240   260
                                   VEHICLE PASSES  FOLLOWING TREATMENT
                                                                280    300
                                Figure 1.  Effectiveness  of road dust suppressants.

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     Once again the  effectiveness  of the dust suppressant was found to be
initially high, but  decayed  with road usage.  According  to taconite mine
personnel, the binding effect of TREX can be partially restored by the addi-
tion of water to the road surface.

2.2  METHODOLOGY FOR MORE EXTENSIVE PLANT SURVEYS

     In order to gather more extensive and reliable data on source extents,
correction parameters  and  control  practices for open dust sources within
integrated iron and  steel plants, a  questionnaire was designed in the  form
of materials  handling flow charts to  be completed for specific plants.

     The  flow  charts  displayed several alternate handling schemes for the
following materials:

     1.  Coal
     2.  Iron ore pellets
     3.  Unagglomerated iron ore
     4.  Limestone/dolomite
     5.  Sinter, nodules, and briquettes
     6.  Coke
     7.  Sinter input  (flue dust, iron ore, and coke fines)
     8.  Slag

     The  completed  flow  charts for a  specific plant provides information
on:  (a) the materials handling routes used at the plant, (b)  the amount of
material passing  through  each handling step, (c) physical characteristics
of the  handling  equipment (e.g., bucket size, drop height, etc.), and (d)
the handling  steps  that  are controlled  and  the  type of  control  utilized.

     Through the assistance of the American Iron and Steel Institute (Mr. John
Barker, Chairman  of  the AISI  Fugitive  Emissions  Committee, and Mr. William
Benzer),  the  following companies agreed  to  complete the materials handling
flow charts for the indicated plants:

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Armco Steel, Incorporated

     Middletown Works
     Houston Works

Interlake, Incorporated

     Chicago Plant (coke ovens and blast furnace)
     Works at Riverdale (BOFs)

Bethlehem Steel Corporation

     Burns Harbor
     Sparrows Point

National Steel Corporation

     River Rouge Plant (coke ovens and blast furnaces)
     Works at Ecorse (BOFs and EAFs)
     Works at Granite City

U.S. Steel Corporation

     Geneva Works
     Gary Works

Republic Steel Corporation

     Cleveland District Plant

Jones and Laughlin Steel Corporation

     Aliquippa Works
     Indiana Harbor Works
                         10

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     At the time of the writing of this report, most of the completed flow
charts had been received.   Appendix A gives an example of materials handling
data compiled from the charts for two plants.

2.3  UPDATED EMISSIONS INVENTORY

     The completed materials  handling  flow charts for the 14 plants will
provide input data for a more representative industry-wide emissions inven-
tory of open  dust  sources.   Pending the compilation of data from the flow
charts, the preliminary inventory developed earlier was updated by using the
revised emission factors for unpaved roads, paved roads,  and continuous drop
operations, as developed in Reference 2.

     The updated inventory,  shown in Table  2, has the  same features as  the
inventory published earlier.  Vehicular traffic on unpaved surfaces accounts
for over 71% of the total open dust source emissions while batch and continu-
ous drop operations combine  for less than 5% of the total.  This  inventory
will be further refined by incorporation of the results of the 14 plant sur-
veys .

     Because the data base on the field performance of control measures for
open dust sources is so small as to be insignificant,  control measure testing
should be distributed in relation to the magnitude of uncontrolled emissions.
According to  Table  1,  testing should focus on control measures applicable
to:

        Unpaved roads
        Paved roads
        Storage pile maintenance
        Storage pile wind erosion
     •  Unpaved parking lots
        Conveyor transfer stations
        Exposed area wind erosion
                                   11

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  TABLE 2.  PRELIMINARY INVENTORY OF OPEN DUST SOURCE CONTRIBUTIONS TO SUSPENDED PARTICULATE EMISSIONS
                 Source
    1976  Nationwide  suspended
    particulate  emission  rate
 for the  iron  and  steel industry
         Uncontrolled!/
	(tons/yr)	
  Percent of
total emissions
   Vehicular traffic on unpaved surfaces

     Unpaved roads
     Storage pile maintenance
     Unpaved parking lots

   Vehicular traffic on paved surfaces

   Batch drop operations

     Loaders
     Railcars
     Trucks
     Gantry/clamshell

   Continuous drop operations

     Stackers
     Conveyor transfer stations
     Bucket wheels

   Wind erosion

     Storage piles
     Exposed areas
             50,100
              9,270
              3,350

             11,300
                 13
                 35
                  9
                 26
                122
              3,840
                 38
              6,500
              3,110
             87.700
     71.5



     12.9

      0.1
                                              4.5
                                             11.0
£/  Except that natural control due to precipitation is included.

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     Based on preliminary  analysis  of the materials handling flow charts,
uncontrolled emissions from conveyor  transfer stations are probably larger
than the value given in Table 1 because the number of transfer stations ex-
ceeds the average value of two per material that was assumed in the calcula-
tions .

2.4  SAMPLING AND ANALYSIS METHODS

     Fugitive emissions are  especially difficult to characterize  for  the
following reasons.

     1.  Emission rates have a high degree of temporal variability.

     2.  Emissions are discharged from a wide variety of source configura-
tions .

     3.  Emissions are comprised of a wide range of particle sizes, includ-
ing  coarse  particles which deposit  immediately adjacent to the  source.

The scheme for quantification of emission factors must effectively deal with
these complications.

     Three basic techniques have been suggested.9

     1.  The quasi-stack method involves capturing the entire emissions stream
with enclosures or hoods and applying conventional source testing techniques
to the confined flow.

     2.  The roof monitor method involves measurement of concentrations and
air flows acress well defined building openings such as roof monitors,  ceil-
ing vents, and windows.

     3.  The upwind/downwind method involves measurement of upwind and down-
wind air quality, utilizing ground-based samplers under known meterorlogical
conditions and  calculation of source strength with atmospheric dispersion
equations.

                                   13

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Of these techniques, only the upwind/downwind method is suitable for applica-
tion to open dust sources.

     As .an  alternative to the upwind/downwind method for quantification of
source-specific emission  factors  for  open dust sources, MRI developed the
"exposure profiling" technique,  which uses the isokinetic profiling concept
that is  the  basis  for conventional source testing.10   Exposure profiling
consists of the direct measurement of the passage of airborne pollutant im-
mediately downwind of the source by means of simultaneous multipoint sampl-
ing over the effective cross section of the fugitive emissions plume.   This
technique uses a mass-balance  calculation scheme similar to EPA Method 5
stack testing rather than requiring indirect calculation through the appli-
cation of a  generalized  atmospheric dispersion model.   Exposure profiling
is compared  with conventional  upwind/downwind sampling in the subsections
below.

2.4.1  Open Dust Source Quantification by Upwind/Downwind Method

     The upwind/downwind method has frequently been used to measure fugitive
particulate emissions from open (unconfinable) sources, although only a few
studies have been conducted in the integrated iron and steel industry.  Typi-
cally, particulate concentration samplers (most often high-volume filtration
samplers) are positioned  at a  considerable distance from the source  (for
example, at  the  property line  around an industrial operation) in order to
measure the highest particulate levels to which the public might be exposed.
The calculation of the emission rate by dispersion modeling is oftern treated
as having secondary importance,  especially because of the difficult problem
of identifying the contributions of elements of the mix of open sources (and
possibly fugitive emissions discharged from process installations).

     While  the above  strategy  is  useful in characterizing the air quality
impact of an open source mix, it has significant limitations with regard to
control strategy development.  The major limitations are as follows:
                                   14

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     1.  Overlapping of source plumes precludes the determination of source-
specific  contributions  on the basis of particulate  concentration alone.

     2.  Air samplers with poorly defined intake flow structure  (including
the conventional high-volume sampler) exhibit diffuse cutoff size character-
istics for particle capture, which tend "to be affected by wind conditions.11

     3.  Uncalibrated atmospheric dispersion models introduce the possibil-
ity of  substantial  error  (a factor of three12) in the calculated emission
rate, even  if  the  stringent requirement of unobstructed dispersion from a
simplified source configuration is met.

     The first  two  limitations are not a direct consequence  of the upwind/
downwind method but of  the way it is used.  These  limitations could be  re-
moved by using samplers designed to capture all or a known size fraction of
the atmospheric particulate,  and by designing  sampler placement  to isolate
the air quality impact of a well defined source operation.

     However, there would remain the need to improve method accuracy by cali-
bration of the dispersion model for the specific conditions of wind,  surface
roughness, and  so on, which  influence  the near-surface dispersion process.
This need  is  evident  from the significant size of the variation in model-
calculated emission rates  for aggregate  process operations, based on data
from individual samplers operated simultaneously at different downwind loca-
tions.13  The  suggested use  of tracers for this purpose is complicated by
the characteristically  diffuse  and  variable nature of an open dust source
and the need for a polydisperse tracer test dust approximating the particle
size distribution of the source emissions.

2.4.2  Open Dust Source Quantification by Exposure Profiling Method

     As stated  above,  the exposure  profiling method was developed by MRI3
to measure  particulate  emissions  from  specific  open  sources, utilizing  the
isokinetic profiling concept which is the basis for conventional source test-
ing.  For  measurement on  nonbuoyant  fugitive emissions,  sampling heads  are
                                   15

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distributed over a vertical network positioned just downwind (usually about
5 m) from the source.   Sampling intakes are pointed into the wind and sampl-
ing velocity is  adjusted  to match the local mean wind speed, as monitored
by distributed anemometers.  A vertical line grid of samplers is sufficient
for measurement of emissions from line or moving point sources while a two-
dimensional array of samplers is required for quantification of area source
emissions.

Grid Size and Sampling Duration--
     Sampling heads are distributed  over a sufficiently large portion of
the plume  so  that vertical and lateral plume boundaries may be located by
spatial  extrapolation  of  exposure measurements.  The size  limit  of area
sources  for  which exposure profiling  is  practical  is determined by the
feasibility of  erecting sampling  towers  of  sufficient height  and number to
characterize the plume.  This problem is minimized by sampling when the wind
direction is parallel to the direction of the minimum dimension of the area
source.

     The size of the sampling grid needed for exposure profiling of a particu-
lar source may be estimated by observation of the visible size of the plume
or by calculationof plume dispersion.  Grid size adjustments may be required
based on the results of preliminary testing.

     Particulate  sampling  heads  should be symmetrically distributed over
the concentrated portion of the plume containing about 90% of the total mass
flux (exposure).  For example, if the exposure from a point source is normally
distributed, as shown in Figure 2, the exposure values measured by the sam-
plers at the edge of the grid should be about 25% of the center line exposure.

     Sampling time  should  be  long enough to provide  sufficient particulate
mass and to average over several units of cyclic fluctuation in the emission
rate (for example, vehicle passes on an unpaved road).  The first condition
is  easily  met because  of  the  proximity of the  sampling  grid  to the  source.
                                   16

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Virtual  Point Source
                                                                                                          X
                                                                                               Exposure
                                                                                               Profiles
                                                Wind Direction
                      Figure  2.   Example exposure profiling arrangement.

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     Assuming that sample collection media do not overload,  the upper limit
on sampling time is dictated by the need to sample under conditions of rela-
tively constant wind direction and speed.   In the absence of passage of weather
fronts through the area, acceptable wind conditions might be anticipated to
persist for a period of 1 to 6 hr.

     In order to obtain an accurate measurement of airborne particulate ex-
posure, sampling must  be conducted isokinetically, i.e., flow streamlines
enter the  sampler  rectilinearly.   This means that  the sampling intake must
be aimed directly  into the wind and, to the extent possible, the sampling
velocity must  equal  the local wind speed.  The  first condition  is by far
the more critical.

     Based on replicate exposure profiling of open dust sources under vary-
ing conditions  of  source activity and properties of the emitting surface,
emission factor  formulae  have been derived that successfully predict test
results with a maximum error of 20%.3  These formulae account for the frac-
tion of silt (fines) in the emitting surface, the surface moisture content,
and the rate  of mechanical energy expended in the process which generates
the emissions.  Based on the above results, the accuracy of exposure profil-
ing is considerably better than the ± 50% range given for the upwind/downwind
method with site-specific dispersion model calibration.9

2.4.3  Methods for Particle Sizing

     High-volume cascade  impactors with  glass  fiber impaction substrates,
which are  commonly used to measure particle size distribution of atmospheric
particulate, may be  adapted  for  sizing of  fugitive particulate.  A  cyclone
preseparator  (or  other device)  is needed to remove coarse particles which
otherwise  would  be subject to particle bounce within the impactor causing
fine particle  bias.14   Once  again, the sampling  intake  should be pointed
into the wind  and the sampling velocity adjusted  to  the mean local wind
speed by fitting the intake with a nozzle of appropriate size.
                                   18

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     The recently developed EPA version of the dichotomous sampler,15 which
is virtually  free  of  particle  bounce  problems  is  useful  for  quantification
of fine  particle  mass concentrations.  However, this device operates at a
low flow rate (1 cu m/hr) yielding only 0.024 mg of sample in 24 hr for each
10 (Jg/m3 of TSP concentration.  Thus, an analytical balance of high precision
is required to determine mass  concentrations below and above the fine particu-
late (2.5 fjm) cutpoint (the minimum in the typical bimodal size distribution
'of atmospheric particulate).    In addition, the dichotomous sampler was designed
to have  a  15  [Jm  cutpoint for  capture  of  airborne  particles  (the  upper  size
limit for inhalable particulate based on unit density); however, recent wind
tunnel studies have shown that this cutpoint is wind sensitive.16

     The size-selective  inlet  for a  standard high-volume sampler9 is also
designed to  capture  particles smaller than 15 |Jm in aerodynamic diameter.
This unit is much less wind sensitive than the dichotomous sampler16 but it
does not provide  a cutpoint at 2.5  (Jm.   However,  it  can  be  adapted  for use
with a  high volume cascade impactor  to  obtain an IP size  distribution.
                                    19

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               3.0  CONTROL TECHNOLOGY FOR OPEN DUST SOURCES


     A number of publications are available which describe in some level of
detail the various control techniques which have been applied to open dust
sources.   A bibliography of such literature resources is presented in Appen-
dix B.

3.1  TYPES OF CONTROL TECHNIQUES

     Standard preventive techniques  for  the control of open dust sources
may be divided into three basic types:

     1.  Maintenance of high moisture levels in the exposed surface.

     2.  Chemical stabilization of the exposed surface.

     3.  Protection of the exposed surface by physical emplacements.

Each of these control method types is discussed briefly below.

     Decades of  research  on  the physical principles of soil loss by wind
erosion have quantified the  dependence of dust generation  on moisture con-
tent.17'18  This  may be approximated as an  inverse square relationship.
Maintenance of high moisture levels in exposed surfaces associated with open
dust sources is  very effective  in  controlling dust  emissions.  This may  be
accomplished by periodic or continuous watering using fixed or mobile spray
systems.   Moisture penetration  and.or retention may be enhanced by the use
of:   (a)  chemical wetting  agents or  foams,  or  (b) dessicant materials such
as calcium chloride.
                                   20

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     Chemical stabilization of an exposed dusty surface to control dust emis-
sions is accomplished  by  the direct application of chemical agents to the
surface.  These agents  bind  the loose surface particulate which otherwise
would be subject  to  entrainment into the atmosphere by the forces of wind
or machinery.  If the  surface is subject to large mechanical stresses  (for
example, as  would be the  case for an unpaved haul  road),  it is important
that the base  below  the surface be  strong enough to absorb the stresses.
Otherwise,  the surface  crust may be broken and become uneffective in con-
trolling dust emissions.

     Because the rate of dust generation by wind erosion increases substan-
tially with wind speed  (above the "threshold" value), control of wind erosion
can be effected by reducing the wind speed near the exposed surface in rela-
tion to  the  ambient  wind.  This may  be  accomplished by enclosures  or  other
forms of windbreaks.

     Nonpreventive control of emissions  from open dust sources entails the
capture of emissions usually by some combination of hooding and enclosures.
Water sprays are  not very effective for this purpose,  although recent re-
search efforts have shown that charged fogs are substantially more effective.
Table 3  lists  current  research  studies  dealing with control technology for
open dust sources.

3.2  EFFICIENCY AND COST OF CONTROL

     Ideally,  the selection  of  "best" controls for a particular open dust
source  should  be  based on  cost-effectiveness evaluation of each of the po-
tentially applicable control techniques.  Unfortunately,  the data  for these
evaluations are sparce  and generally do not reflect the wide variability of
source conditions.

     Cost and  estimated efficiency data on open dust  source controls  for
the  integrated iron  and steel industry have been compiled by Bohn et al.1
These costs  included initial and annual operating costs of several control
                                   21

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     TABLE 3.  RECENT AND CURRENT INVESTIGATIONS OF CONTROL TECHNOLOGY
                 APPLICABLE TO OPEN DUST SOURCES
1.   Paved and unpaved road emissions, Midwest Research Institute,
     Dr. Chatten Cowherd, EPA Contract No.  68-02-2814.

2.   Improved street sweepers for paved roads, Air Pollution Technology,
     Dr. Richard Parker, EPA Contract No.  68-02-3148.

3.   Road carpet for unpaved roads, Monsanto,  Mr.  Keith Tackett,  EPA
     Contract No. 68-02-3107.

4.   Windscreening and chemical additives  for  area sources,  The Research
     Corporation of New England, Mr. Dennis Martin, EPA Contract No. 68-
     02-3115.

5.   Charged fog for construction sight activity and front-end loaders,
     Aerovironment, Mr. John Kinsey, EPA Contract No.  68-02-3145.

6.   Dust control for haul roads, Midwest  Research Institute, Mr.  Russel
     Bohn, BuMines Contract No. J0285015.

7.   Emission factors and control technology for fugitive dust from coal
     mining sources, PEDCo/MRI, Mr. Ken Axetell/Dr. Chatten Cowherd, EPA
     Contract No. 68-02-2585.

8.   Fugitive emissions from integrated iron and steel plants, Midwest
     Research Institute, Mr. Russel Bohn,  EPA  Contract No.  68-02-2120
     (see EPA-600/2-78-050, March 1978).
                                   22

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options applied to each source.   As part of the same study, cost-effective-
ness evaluation was performed for a typical process source of fugitive emis-
sions  (electric arc  furnace)  and for several open dust sources (see Table
4).

     Recently, Cooper  et  al.19  have compiled cost-effectiveness data for
the control of  emissions  from unpaved roads by paving, oiling, watering,
calcium chloride,  and  speed  control.   However, details on the application
frequency and intensity of dust suppressants is sketchy.

     Another recent  compilation  of  cost-effectiveness  data for the  control
of emissions  from  unpaved mining haul  roads  and access  roads has been pre-
pared by Bohn et al.20  As shown in Table 5, the product control efficiencies,
although largely estimates,  are properly tied to prescribed levels of appli-
cation density and frequency.

     As illustrated in the above examples, the most serious data gap affect-
ing cost-effectiveness evaluation  is  the  nearly total  lack of  actual field
data on control  method performance, especially for the preventive control
techniques.  Table 6 illustrates this point by summarizing the reported ef-
ficiencies for  control of wind erosion from storage piles; all but one of
the efficiency values are estimates.

     Because of  the  finite  durability of all  control  techniques,  ranging
from hours (watering) to years (paving), it is essential to tie an efficiency
value to a frequency of application (or maintenance).   For measures of lengthy
durability, such as paving of unpaved roads, the maintenance program required
to sustain control effectiveness should be indicated.   One likely pitfall
to be avoided is the use of field data on a freshly applied control measure
to represent the lifetime of the measure.

3.3  CURRENT INDUSTRY  CONTROL PRACTICES

     Analysis of  the materials  handling flow charts for the 14 integrated
iron and steel plants  indicate that a number of control techniques are being

                                    23

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   TABLE 4.    COST  EFFECTIVENESS OF  FUGITIVE  EMISSIONS. CONTROL  METHODS
Source
Process
EAF
Open dust
Storage pile
activities
Load-In/
load -out
Wind erosion
from storage
piles
(lump iron ore )
Control method
Canopy hoods
Utilize mobile
stacker /reclaimer
combination rather
than front-end
loader activity
for pellet piles
Watering
Chemical stabilizers
(Coherex 207. solution)
/fEstlraate/f Annual Iced Annual
\ȣojjt*^l investment Ranking operating
efficiency cost . order cost
70 1.44 [8] NA
80 8.68 [9] NA
80 0.02 [4] NA
97 0.02 [4] 0.008
Ranking
order
CO
  Vehicular traffic
    Unpaved roadways
Watering
Road oil
Oil and double  chip
Chemical stabilizers
  (Coherex)
Paving
50
75
80
90

90
0.006
0.006
0.02
0.02

0.08
[2]
C23
03
                                                                       [5]
0.06
0.4
0.03
0.08

0.08
C7]
CO


[6]
Paved roadways


Wind erosion
from exposed
areas

Broom sweeping
Vacuum sweeping
Road flushing
Watering. .
Chemical stabilizers-
Oiling
Paving with cleaning
70
75
30
50
70
30
95
0.005
0. 01
0.006
0.21
0.16
0.02
0.01
(0
[3]
[2]
[7]
[6]
l~4l
[3] •
0.05
0.05
0.05
0.01
0.05
NA
NA
f4l
[5]
0]
[2]
[4]
.
-
MA - Not available.

£/  Dollar per  pound reduction aC fine partlculate per  year.

b/  No specific chemical  stabilizer given;  707. control  efficiency  Is assumed to be the average of all
    available chemical stabilizers  for this  control purpose.
                                          24

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                                  TABLE 5.   CONTROL EFFICIENCIES OF  ROAD DUST  SUPPRESSANTS
NJ
Ul
Parameter
Control efficiency
Maul road
Access road
Application density
Maul road
Initial
Suhse<|iieut
Access road
Ligniii sul fonate

75%
70%

2 gal ./yd2 of 15%
solution
Same
2. It gal ./yd2 of
12% solution
Coh<; rex®

75%
. 70%

2 gal./yd2 of 1:4
di lution
0.5 gal./yd2 of
1 : 10 diultion
1 gal./yd2 of
1 :7 dilution
Calcium chloride

75%
70%

1 gal./yd2 of 30%
solution
0.3 gal./yd2 of
30% solution
0.6 gal. /yd2 of
of 30% solution
Road watering

75%
70%

0.05 gal ./yd2
Same
0.05 gal ./yd2
Wetting agents

75%
70%

0.05 gal ./yd2
Same
0.05 gal./yd2
      Ap|il icatioii Frequency/
        Year

        Maul  road
        Access  road
Summer:  Hourly              Summer:  Daylight In
Spring anrl Fall:  Every  2  lir  Spring and Fall:  Every 2
                              daylight hr
Winter:  Once per day        Winter:  Every other day
Summer:  Every 2 hr          Summer:  Every 2 daylight
                              In
Spring and Fall:  Every       Spring and Fall:  Every 3
                              daylight hr
Winter:  Once every 2 days   Winter:  Once per week

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        TABLE 6.  REPORTED EFFICIENCIES FOR CONTROL OF WIND EROSION
                    OF STORAGE PILES
     Control method
 Reported
efficiency  Reference
   (%)       -(year)*
Method of determination
Watering - periodic            50      22 (1976)
  sprinkling                           23 (1977)
Watering - wind-activated      80       1 (1978)
  sprinkler system
Chemical wetting agents        90
  or foam
Continuous chemical spray      90      22 (1976)
  onto input material                  23 (1977)
Surface crusting agents    Up to 99     1 (1978)

Enclosure                  95 to 99    23 (1977)
Storage silos                 100       1 (1978)
Vegetative windbreak           30       1 (1978)
Low pile height                30       1 (1978)
                        Ref. 21 (1973) - estimate
                        Ref. 22 (1976) - estimate
                        Estimate
            23 (1977)   Estimate
                        Vendor brochure -
                          estimate
                        Ref. 24 (1974) - wind
                          tunnel tests
                        Estimate
                        Estimate
                        Estimate
                        Estimate
*  Reference 25 cites References 23 and 1.
                                   26

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applied to open dust sources at one or more locations.   These are summarized
in Table 7.

     In addition, plans are underway at one plant to apply Coherex® to unpaved
roads and  to  the shoulders and berms of paved roads and  to vegetate bare
ground areas.   Presumably some form of cost-effectiveness analysis was under-
taken in the selection and implementation of these control measures.

3.4  SELECTION OF BEST CONTROLS

     The selection  of  best controls was based on the extent of use within
the industry and on the results of the preliminary cost-effectiveness evalu-
ations cited above.  The "best" controls are reviewed for each source cate-
gory in the paragraphs below.

     The best  control  methods  selected  for unpaved  roads  are:  application
of Coherex®,  watering,  and application of calcium chloride.  All three of
these techniques have  been used in  the  integrated iron  and  steel  industry.
These techniques have'favorable cost-effectiveness  ratios,  although recent
increases  in  the price of calcium__chloride have made it less competitive.

     The best control methods selected for paved roads are flushing and vacuum-
ings.  These  techniques  are  used  in combination within  the  steel  industry.
Preliminary evaluation based on  estimated control efficiencies shows that
these two  methods  have similar cost-effectiveness  ratios.  At one  plant,
Coherex® is being  applied  to unpaved shoulders and  berms  of paved roads  to
reduce emissions from these areas and to prevent the rapid build-up of sur-
face loadings on the paved road.

     Watering  (possibly with the addition of wetting agents) has been selected
as the best  method to control emissions from storage pile maintenance and
wind erosion.  Because of the active nature of the surfaces involved, chemi-
cal  stabilization  is  not effective.  Also, the use of physical windbreaks
characteristically prevents the freedom of access to the pile which is nec-
essary to maintain adequate material flows into and out of storage.

                                   27

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                          TABLE 7.  SUMMARY OF FUGITIVE EMISSION CONTROLS (BY PLANT)
N3
OO
Source
I . Unpaved roads

II. Paved roads

III. Storage pile (maintenance
Control practice
A.
B.
A.
B.
A.
Watering
Oiling
Flushing
Sweeping
Watering
Plant(s)
Armco-Houston Works
J&L Steel-Aliquippa Works
None reported
Armco-Houston Works (also
1. Armco-Houston Works
•



watering)

           and wind erosion)
    IV.  Unpaved parking lots

    V.   Conveyor transfer station
B.  Chemical sprays



None indicated

A.  Enclosures
    VI.   Exposed Area Wind Erosion
B.  Water sprays



C.  Chemical sprays

Vegetation
2.  Bethlehem Steel-Burns Harbor
3.  U.S. Steel-Gary Works
4.  U.S. Steel-Geneva Works

1.  Bethlehem Steel-Burns Harbor
2.  National Steel-Great Lakes Divi-
      sion
1.  Armco-Middletown Works
2.  Bethlehem Steel-Burns Harbor
3.  Interlake Steel-Chicago
4.  J&L Steel-Aliquippa Works
5.  U.S. Steel-Geneva Works

1.  Armco-Middletown Works
2.  Bethlehem Steel-Burns Harbor
3.  U.S. Steel-Geneva Works

1.  Bethlehem Steel-Sparrows Point

None reported

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     The best method to control emissions from unpaved parking lots and other
exposed areas subject to traffic disturbance is through the application of
a chemical stabilizer.   Such areas  usually have a well compacted subsurface
to allow for mechanical stress absorbance without break up of the stabiliz-
ing agent.  Moreover, it is. usually not practical to water large areas that
are poorly accessible.

     Conveyor transfer stations are best controlled by enclosure and ducting
of the captured dust to a removal device prior to recycle or disposal.  Water
sprays on conveyed  material  is a preventive method for controlling dust.
Both of these method are widely used in the integrated iron and steel indus-
try.
                                   29

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                     4.0  RECOMMENDATIONS FOR PHASE II
     This section presents our recommendations for a field testing program
to supply the data needs for cost-effectiveness evaluation of the best con-
trols for open dust sources within the integrated iron and steel  industry.

4.1  DATA NEEDS

     The data needs for control cost-effectiveness evaluation fall into the
following categories:

        Emission  factors  for  total  suspended particulate (TSP),  inhalable
particulate (IP), and fine particulate (FP) with and without application of
the control technique.

        Emission factor correction parameters (see Table 8) for uncontrolled
and controlled test source segment.

        Control  application density  and  time after application  for which
controlled testing was performed.

        Investment and operating costs of dust control measure.

     The procedures for  development  of size specific emission factors for
open dust sources  are outlined in the next section, as are procedures for
on-site  correction  parameter  determination.   Control application density
should be expressed in units similar to that found in Table 5.

     Cost data for  the control technique being  tested should be  obtained
from the steel plant where testing is performed.   These data should include:
(a) annualized costs of equipment purchase and installation, and  (b) annual
                                   30

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                  TABLE 8.   PARAMETERS AFFECTING EMISSION FACTORS FOR OPEN DUST SOURCES
  Generic source category
        Material
   Equipment
Climate
Vehicular traffic on unpaved
  surfaces
Vehicular traffic on paved
  surfaces

Wind erosion of storage piles
  and exposed areas
Surface silt content
Surface silt content
Surface loading

Surface erodibility
Surface silt content
Surface moisture content
Vehicle speed
Vehicle weight
Number of wheels

Vehicle weight
                         Wind speed

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operating costs.  The annualized investment costs should take into account
the initial costs, the  life time of the equipment, interest and taxes.  To
calculate the total  annualized  cost,  the average annual cost of operation
is added  to the product of the initial capital investment and the capital
recovery factor.  The capital recovery factor is the percentage of the ini-
tial investment which would be paid yearly on a loan or mortgage.

4.2  SAMPLING AND ANALYSIS PROCEDURES

     This section describes the field sampling and laboratory analysis pro-
cedures that will be used to quantify (a) particulate emission rate and par-
ticle size distribution, (b) meteorological conditions, and (c) process con-
ditions.  The quality assurance program is also discussed.

4.2.1  Mechanically Generated Particulate Emissions

     Table 9  lists  the  equipment that will be  used  to  sample particulate
emissions from  unpaved  roads,  paved roads, storage  pile maintenance,  and
unpaved parking lots.  Equipment locations and intake heights are  specified.
The primary tool  for quantification of emission rate will be the  exposure
profiler, operated in the moving point source mode.

     The exposure profiler  (Figure  3) consists  of a  portable tower (4  to 6
m height) supporting an array of four sampling heads.  Each sampling head
is operated as an isokinetic exposure sampler directing passage of the flow
stream  through  a  settling chamber  (trapping particles  larger than about 50
|jm in  diameter) and  then upward  through a  standard 8 by 10 in. glass fiber
filter positioned horizontally.   Sampling intakes are pointed into the wind,
and sampling  velocity of  each intake is adjusted to match the local mean
wind speed, as  determined  prior to each test.  Throughout each test, wind
speed is monitored by recording anemometers at two heights,  and the vertical
profile of wind speed is determined by assuming a logarithmic distribution.
Normally, the exposure profiler is positioned at a distance of 5 m from the
downwind edge of the road.
                                   32

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            TABLE 9.  SAMPLING EQUIPMENT FOR OPEN DUST SOURCES
Location
Distance from
 source (m)
       Equipment
Intake height
     (m)
Upwind
    5-10
Downwind
1 Standard Hi-Vol
1 Hi-Vol with 15 pm inlet*
1 Hi-Vol with 15 |Jm inlet
1 Continuous wind monitor

1 MRI exposure profiler with
  four sampling heads
                               1 Standard Hi-Vol
                               2 Hi-Vol cascade impactors
                                 with 15 |Jm inlet or
                                 cyclone precollector
                               2 Warm wire anemometer
     2.0
     2.0
     4.0
     4.0

     1.0
     2.0
     3.0
     4.0
     2.0
     1.0
     3.0

     1.0
     3.0
a  A particle sizing unit will be operated in place of this unit for one run
     in each 3-run test series.

b  This unit will be used only on tests of controlled emissions.
                                   33

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                                       Flow Control Circuit Box
                      Warm-Wire
                      Anemometer
                        Electronic Readout/Control Unit-
Figure 3.  MRI exposure profiler.

                34

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     Particle size distribution will be measured using a high volume cascade
impactor preceeded either by a  size-selective  intake  (15 Mm  cutpoint) or a
cyclone preseparator (10 |Jm cutpoint).  The first option provides for direct
measurement of inhalable particulate, but requires total (isokinetic) particu-
late concentrations  from  the  exposure profiler for the calculation of the
particle size distribution of total airbo'rne particulate matter in the emis-
sion plume.   The  second option provides for direct isokinetic measurement
of the total particle size distribution but requires extrapolation from the
cyclone cutpoint  (10 |jm)  to determine IP concentrations.  In either case,
particle sizing samplers will be operated along side of the exposure profiler
at two heights (usually the first and third profiler levels) in the fugitive
dust plume.

     Also, a  high-volume  sampler with a size-selective inlet (Hi-Vol/SSI)
will be operated at  the upwind monitoring station to determine the IP frac-
tion of the  background  particulate.   This will be  replaced with  a particle
sizing sampler for one run in each 3-run test  series.  For tests of control-
led emissions, a  second Hi-Vol/ SSI  will be operated  at  a higher elevation
to determine the change of background IP concentration with height.   Conven-
tional high-volume samplers will be  operated at one  height both  upwind and
downwind of the source.

     Table 10  lists  the critiera for suspending or terminating an exposure
profiling test.  Some of these  criteria address the wind conditions in rela-
tion to the  requirements  for isokinetic sampling.  Testing may also cease
if rainfall ensues (reducing emissions to negligible levels) or if light is
insufficient for safe operation.  The final criterion deals with an unaccept-
able change in source condition.

     Sampling time will be sufficient to provide sufficient particulate mass
and to average over  several units of  cyclic fluctuation in the emission rate,
e.g., vehicle  passes on an unpaved  road.  Because of the proximity of the
sampling  grid  to  the source, the first  condition is  easily met for  testing
of uncontrolled sources.  However, testing of  controlled sources may require
a  sampling period of  up  to 4  hours  to  provide sufficient  sample mass.
                                   35

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TABLE 10.  CRITERIA FOR SUSPENDING OR TERMINATING AN EXPOSURE PROFILING TEST
A test will be suspended or terminated if:—

1.  Rainfall ensues during equipment setup or when sampling is in progress.

2.  Mean wind speed during sampling moves outside the 4 to 20 mph accept-
      able range for more than 20% of the sampling time.

3.  The angle between mean wind direction and the perpendicular to the path
      of the moving point source during sampling exceeds 45 degrees for more
      than 20% of the sampling time.

4.  Mean wind direction during sampling shifts by more than 30 degrees from
      profiler intake direction.

5.  Mean wind speed approaching profiler sampling intake is less than 80% or
      greater than 120% of intake speed.

6.  Daylight is insufficient for safe equipment operation.

7.  Source condition deviates from predetermined criteria,(e.g., occurrence
      of truck spill).
a/  "Mean" denotes a 15-min average.
                                     36

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     Emissions from conveyor transfer stations will be measured by standard
stack sampling methods using the quasi-stack method as described in Reference
9.  This will  necessitate  the testing of a well enclosed station with an
adequate run of ducting.  The uncontrolled emission rate will be determined
by sampling the ducted conveyor emissions upstream of the particulate removal
device.

4.2.2  Wind-Generated Particulate Emissions

     A portable wind  tunnel fabricated by MRI  (Figure 4) will be used to
measure emissions from wind erosion of storage piles or other exposed areas.
The wind tunnel consisted  of  a  two-dimensional  5:1  contraction section, an
open-floored test section,  and a roughly conical diffuser.   The test section
of the tunnel  is  placed directly on the surface to be tested (30 cm x 2.4
m), and the tunnel centerline air flow is adjusted to predetermined veloci-
ties up to 18 m/sec (40 mph), as measured by a pitot tube at the downstream
end of the test section.

     An emissions sampling module2 has been designed and fabricated for use
with the pull-through wind tunnel in measuring particulate  emissions and
particle size  distributions generated by wind erosion.  As shown in Figure
4, the sampling module is  located between the  tunnel outlet hose and the
fan inlet.  The  sampling train, which is operated  at  34 m3/hr (20 cfra),
consists of a  tapered probe,  cyclone precollector, parallel-slot cascade
impactor,  back-up  filter,  and high volume motor.   Interchangeable  probe
tips are  sized for isokinetic  sampling  at  predetermined cross-sectional
average velocities within the tunnel test section.

4.2.3  Site/Process Conditions

     In addition  to the  measurements of wind speed  obtained  at two heights
on the profiling tower, a meteorological instrument will also be located at
the background monitoring  station.   Continuous  measurements of wind speed
and direction  at  a height of 4 m will be recorded at  the  upwind  site.
                                   37

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U)
oo
                                                                                     Schedule 40 Pipe

                                                                                     20cm I.D.

                                                                                     (Aluminum)
                                                            — Toil Section
                                                    Figure 4.   MRI  portable  and  tunnel.

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     In order to determine the properties of aggregate materials being dis-
trubed by the  action of machinery or wind, representative samples of the
materials will be obtained for analysis in the laboratory.  Unpaved and paved
roads will be sampled by vacuuming and broom sweeping to remove loose material
from lateral  strips  of  road  surface extending across  the  traveled portion.
Storage piles will be sampled  to  a depth exceeding the  size of  the largest
aggregate pieces.  If possible, samples of  conveyed material will be taken
directly from the  conveyer upstream  of the transfer station being tested.
Additional detail on the sampling methods is provided elsewhere.2

     Throughout a test of traffic-generated emissions, a vehicle count will
be maintained by a pneumatic-tube traffic counter.  Periodically (e.g.,  dur-
ing  15 min of each hour) vehicle  mix will be determined by compiling a  log
of vehicles  passing  the test point segregated by  vehicle  type  (usually  the
number of axles  and  wheels).   Vehicle speeds will be  measured with a radar
gun.  Data on vehicle weight will be obtained from plant personnel.

4.2.4  Sample Handling and Analysis

     To prevent  dust losses, the collected samples of dust emissions will
carefully be  transferred  at the end of each run  to protective  containers
within the MRI  instrument  van.  Glass fiber filters from the MRI exposure
profiler and  from  standard Hi-Vol units and impaction  substrates will  be
folded and placed in individual envelopes.   Dust that collects on the inte-
rior surfaces  of each exposure probe will  be rinsed  with distilled water
into separate glass jars.   Dust will be transferred from the cyclone precol-
lector in a similar manner.

     Dust samples from the field tests will be returned to MRI and analyzed
gravimetrically  in the  laboratory.  Glass  fiber filters and impaction sub-
strates will  be  conditioned at constant temperature and relative humidity
for  24 hr prior to weighing,  the  same  conditioning procedure used before
taring.  Water  washes  from the exposure profiler  intakes and the cyclone
precollectors will be filtered after which the tared filters will be dried,
conditioned at constant humidity, and reweighed.

                                   39

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     After the gross samples of surface particulate are taken to the labora-
tory, they are prepared for moisture and silt analysis.  The first step con-
sists of  reducint the  sample to a workable size.  A riffle  sample splitter
should be used for  this purpose, following ASTM Method D2013-72, "Standard
Method of Preparing Coal Samples for Analysis."  The final split should pro-
duce a sample mass not exceeding 1,000 g.

     The  reduced samples of surface particulate will be dried to determine
moisture  content and  screened  to  determine the weight fraction passing a
200 mesh  screen, which gives the silt  content.  A conventional shaker will
be used for this purpose.   That portion of the material passing through the
200 mesh  screen  will  be analyzed to determine the density  of potentially
suspendable particules.  The procedures for moisture and silt analysis, which
comform to ASTM Method C136-76, are summarized in Tables 11 and 12.

4.3  QUALITY ASSURANCE PROGRAM

4.3.1  Sampling and Analysis of Airborne Particulate

     The  quality assurance  program  for particulate sampling and analysis
will include  (a)  activities designed to demonstrate that measurements are
made within  acceptable control conditions,  and (b) assessment of sampling
and analysis data for precision and accuracy.  The QA program for quantifi-
cation of fugitive particulate emissions meets or exceeds requirements speci-
fied in  "Quality Assurance  Handbook  for  Air  Pollution  Measurement Systems,
Volume II -Ambient  Air Specific Methods" (EPA 600/4-77-027a) and "Ambient
Monitoring  Guidelines  for Prevention  of Significant  Deterioration" (EPA
450/2-78-019).

     A variety of particulate  sampling devices will be utilized in the study
to quantify fugitive emissions by exposure profiling.   Sampling devices in-
clude:  standard Hi-Vol air sampling units (with and without 15 |Jm inlets),
exposure  profiling  systems,  and Hi-Vol cascade impactors.  These sampling
devices utilize filter media,  impaction substrates, and cyclone catch cham-
bers to  collect  the sampled particulate.  A certain amount of particulate

                                   40

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                   TABLE 11.  MOISTURE ANALYSIS PROCEDURES
1.  Preheat the oven to approximately 110°C (230°F).  Record oven tempera-
      ture.

2.  Tare the laboratory sample containers which will be placed in the oven.
      Tare the containers with the lids on if they have lids.  Record the
      tare weight(s).  Check zero before weighing.

3.  Record the make, capacity, smallest division, and accuracy (if dis-
      played) of the scale.

4.  Weigh the laboratory sample in the container(s).  Record the combined
      weight(s).  Check zero before weighing.

5.  Place sample in oven and dry overnight.

6.  Remove sample container from oven and (a) weigh immediately if uncovered,
      being careful of the hot container; or (b) place tight-fitting lid on
      the container and let cool before weighing.  Record the combined sample
      and container weight(s).  Check zero before weighing.

7.  Calculate the moisture as the initial weight of the sample and container .
      minus the oven-dried weight of the sample and container divided by the
      initial weight of the sample alone.  Record the value.

8.  Calculate the sample weight as the oven-dried weight of the sample and
      container minus the weight of the container.  Record the value.
                                     41

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                    TABLE 12.  SILT ANALYSIS PROCEDURES
1.  Select the appropriate 8-in. diameter, 2-in. deep sieve sizes.  Rec-
      ommended U.S. Standard Series sizes are:  3/8 in., No. 4, No. 20,
      No. 40, No. 100, No. 140, No. 200, and a pan.  Comparable Tyler
      Series sizes can also be utilized.  .The No. 20 and the No. 200 are
      mandatory.  The others can be varied if the recommended sieves are
      not available or if buildup on one particular sieve during sieving
      indicates that an intermediate sieve should be inserted.

2.  Obtain a mechanical sieving device such as a vibratory shaker or a
      Roto-Tap.

3.  Clean the sieves with compressed air and/or a soft brush.  Material
      lodged in the sieve openings or adhering to the sides of the sieve
      should be removed (if possible) without handling the screen roughly.

4.  Attain a scale (capacity of at least 1,600 g) and record make, capac-
      ity, smallest division, date of last calibration, and accuracy (if
      available).

5.  Tare sieves and pan.  Check the zero before every weighing.  Record
      weights.

6.  After nesting the sieves in decreasing order with pan at the bottom,
      dump dried laboratory sample (probably immediately after moisture
      analysis) into the top sieve.  Brush fine material adhering to the
      sides of the container into the top sieve and cover the top sieve
      with a special lid normally purchased with the pan.

7.  Place nested sieves into the mechanical device and sieve for 20 min.
      Remove pan containing minus No. 200 and weigh.  Replace pan beneath
      the sieves and sieve for another 10 min.  Remove pan and weigh.
      When the difference between two successive pan sample weighings
      (where the tare of the pan has been subtracted) is less than 3.0%,
      the sieving is complete.

8.  Weigh each sieve and its contents and record the weight.  Check the zero
      before every weighing.

9.  Collect the laboratory sample and place the sample in a separate con-
      tainer if further analysis is expected.
                                     42

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is also collected  on  interior surfaces of the sampling probe and connect
tubing which must be rinsed and filtered.

     There are six main categories which a QA program for fugitive particu-
late sampling must address.  They are:

     *  Calibration of equipment

     *  Filter and impaction substrate selection and preparation

     *  Sampling procedures

     *  Sampling equipment maintenance

     *  Laboratory analysis procedures

     *  Calculations and data reporting

A series of tables in EPA 600/4-77-027a presents a matrix of activities which
should be performed to satisfy the QA aspects within each of the above cate-
gories .

     Tables 13 through 16 list the adaptations of the EPA requirements which
will be adopted  to improve the QA aspects above minimum EPA requirements.
For example,  electronic  flow controllers  will be used in all air sampling
devices to minimize excursions from preset flow rates.

     As part  of  the QA program for  the study, routine audits of  sampling
activities will  be performed.  The purpose of the audits will be  to demon-
strate that measurements  are  made within  acceptable  control  conditions for
particulate source sampling and to assess the source testing data for preci-
sion and accuracy.  Examples of items to be audited include filter weighing,
flow rate calibration, data processing and calculations.   The mandatory use
of specially designed reporting forms for sampling and analysis data obtained
in the field and laboratory aid in the auditing procedure.

                                   43

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         TABLE 13.  QUALITY ASSURANCE PROCEDURES FOR SAMPLING FLOW RATES
Activity
          QA Check/Requirement
Calibration

     Profilers, hi-vols, and
       impactors
     Dichotomous samplers
Single-Point Checks

     Profilers, hi-vols, and
       impactors
     Dichotomous samplers
     Alternative
Orifice Calibration
Calibrate flows in operating ranges
using calibration orifice every two
weeks at each regional site prior to
testing.

Calibrate flows in operating ranges
with displaced volume test meters
every two weeks at each regional site
prior to testing.
Check 25% of units with rotameter
calibration orifice or electronic
calibrator once at each site prior to
testing (different units each time).
If any flows deviate by more than 7%,
check all other units of same type and
recalibrate non-:complying units. (See
alternative below.)

Check 25% of unit with calibration
orifice once at each site prior to
testing (different units each time).
If any flows deviate by more than 5%,
check all other units and recalibrate
noncomplying units.

If flows cannot be checked at test
site, check all units every two weeks
and recalibrate units which deviate
by more than 7% (5% for dichots).

Calibrate against displaced volume
test meter annually.
                                       44

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          TABLE 14.  QUALITY ASSURANCE PROCEDURES FOR SAMPLING MEDIA
Activity
          QA Check/Requirement
Preparation
Inspect and imprint glass fiber media
with ID numbers.
                                          Inspect and place teflon media (dichot
                                          filters) in petri dishes labeled with
                                          ID numbers.
Conditioning
Weighing
Auditing of weights
  (Tare and Final)
Correction for Handling
  Effects
Prevention of Handling
  Losses
Calibration of
  Balance
Equilibrate media for 24 hr in clean
controlled room with relative humidity
of less than 50% (variation of less
than + 5%) and with temperature bet-
ween 20 C + and 25 C (variation of
less than + 3%).

Weigh hi-vol filters and impactor
substrates to nearest 0.1 mg and weigh
dichot filters to nearest 0.01 mg.

Independently verify weights of 7% of
filters and substrates (at least 4
from each batch).  Reweigh batch if
weights of any hi-vol filters or sub-
strates deviate by more than +_ 3.0 mg
or if weights of any dichot filters
deviate by more than + 0.05 mg.

Weigh and handle at least one blank
for each 1 to 10 filters or substrates
of each type for each test.

Transport dichot filters upright in
filter cassettes placed in protective
petri dishes.

Balance to be calibrated once per
year by certified manufacturer's
representative check prior to each
use with laboratory Class S weights.
                                       45

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        TABLE 15.  QUALITY ASSURANCE PROCEDURES FOR SAMPLING EQUIPMENT
Activity
      QA Check/Requirements
Maintenance

     All samplers



     Dichotomous samplers


Equipment Siting


Operation

  .   Timing
     Isokinetic sampling
       (profilers only)
     Prevention of Static
       Mode Deposition
Check motors, gaskets, timers, and
flow measuring devices at each re-
gional site prior to testing.

Check and clear inlets and nozzles
between regional sites.

Separate colocated samplers by 3 to
10 equipment widths.
Start and stop all samplers during
time spans not exceeding 1 minute.

Adjust sampling intake orientation
whenever mean (15 min. average) wind
direction changes by more than 30 deg.

Adjust sampling rate whenever mean
(15. min. average) wind speed
approaching sampler changes by more
than 20%.

Cap sampler inlets prior to and imme-
diately after sampling.
                                       46

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TABLE 16.  QUALITY ASSURANCE PROCEDURES FOR DATA PROCESSING AND CALCULATIONS
Activity        '                                 QA Check/Requirements
Data Recording                           Use specially designed data forms to
                                         assure all necessary data are
                                         recorded.  All data sheets must be
                                         initialed and dated.

Calculations                             Independently verify 10% of calcu-
                                         lations of each type.  Recheck all
                                         calculations if any value audited
                                         deviates by more +_ 3%.
                                      47

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4.3.2  Meteorological Monitoring

     The primary meteorological parameters  to  be monitored during source
testing are  wind  speed and direction.  Precipitation  (important  in  open
source fugitive assessments), temperature, and relative humidity will also
be observed.  Atmospheric  stability will be determined from wind direction
fluctuations.  Raw field data will be recorded on a continuous strip chart
and stored on magnetic tape at the site.   Parameters will be sampled  at in-
tervals no longer  than 60  sec.   The magnetic tape will be used primarily
for data analysis, with the strip chart as back-up.

     QA procedures to be used during meteorological  sampling follow federal
EPA guidelines.  Each  instrument  will be sited  to produce representative
samples of the meteorological parameters  observed.   For instance,  wind moni-
tors will be sited away from buildings,  trees,  and other substantial  obstacles.
Rainfall measurements will  be made to avoid the effects of wind on precipita-
tion catch.

     Wind  speed and  direction sensors will exhibit a starting threshold of
less than 0.5 m/sec.   Anemometers will be accurate to ± 0.25 m/sec at speeds
below 5 m/sec.  At high velocities, the  error will  not exceed ± 5% of the
speed, with  no errors  greater than 2.5 m/sec.  The wind vane damping ratio
will be between 0.4  and 0.65.  Wind vane errors will not exceed 3 degrees
for 10-min averages.

     Temperature will be measured to ± 1.0°C.   Relative humidity error will
not exceed an equivalent dew point error  of 1.0°C.   The rain guage will have
an accuracy of 0.25 mm/hr at a precipitation rate of 7.6 cm/hr.

     Each instrument will be calibrated at least every 6 months at MRI facil-
ities and weekly in the field.  Field calibration will also be employed when-
ever the instrument is tranported long distances.

     Wind  speed monitors (cup and warm wire anemometers) will be calibrated
at least every 6 months against known flows in a wind tunnel.  In the field,

                                   48

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the instruments will be calibrated either by visual observation of wind speed
or by  comparison with  co-located anemometers.  Field calibration will also
include adjustment of the zero and span levels on the cup anemometer signal
processor.

     Correct operation of  the wind direction sensor will be determined in
the field and at MRI by observing the instrument output while manually adjust-
ing the vane heading.  In addition, zero and span settings for the wind vane
signal processor will be set at every field and MRI calibration.

     Temperature and relative humidity sensors will be calibrated, in-house
and in the field, by comparison with measurements from a sling psychrometer.
Adjustments to  the  signal  processor will be made by setting zero and span
levels.

     Rain gauge  calibrations  will  be made by pouring specified volumes of
water  into the intake funnel.  The signal processor for this instrument will
be calibrated by setting zero and span levels.

4.4  STATISTICAL BASIS FOR SAMPLING PLAN

     This section presents  statistical  analysis to determine the expected
reliability of  the  emission factors developed from  replicate  sampling at
each site.  For purposes of this analysis, it is assumed that in the absence
of significant precipitation or other events which might irreversibly alter
the source condition, particulate emission rates vary about a constant mean
for a  given  test  site  during  the period  of  replicate testing  (usually less
than 1 week).

     Based on the detailed error analysis for the exposure profiling method,
it is  shown that a typical emission rate can be expected to have a random 1
a  error  of  ± 10%.  An additional error due to linear extrapolation of the
particle  size distribution will be encountered in calculating emission rates
for particles  larger than  15 |Jm diameter.  This  factor  may  contribute an
additional ±  10% random  1  a error  to  a  typical  emission  rate  for  suspended
                                   49 -

-------
particulate.  A combination of these two errors with the natural variability
of the daytime source condition (a = ± 10%) gives an estimate of the standard
deviation, a, of the total population of possible measured values, expressed
as a percentage:

               a =   (10)2 + (10)2 + (ia)2 = 17.3%                    (7)

The sample size, n, needed to achieve an expected standard deviation of the
sample mean,  S,,  that  is less than  10% of  the mean of  the population,  is
given by:
Consequently, a  sample  of  three  replicate  tests will  achieve an expected  1
a error  of  less  than  10% for  the  sample  emission  rate mean  in  relationship
to the true emission rate.

4.5  DISTRIBUTION OF TESTS

     The proposed distribution of tests over the source categories of interest
is based on the following considerations:

     1.  The number of control measures tested for a particular source type
should reflect the importance of the source based on uncontrolled emissions,
but may be limited by the number of candidate "best controls" that are avail-
able.

     2.  All control measures must be referenced to an uncontrolled condition.

     3.  Triplicate tests are needed to characterize an uncontrolled or con-
trolled condition at any point in time.

     4.  Long-term control measures must be tested at least twice after appli-
cation to establish control efficiency decay curve.
                                   50

-------
     5.  Short-term control measures (e.g., watering) will usually show loss
of efficiency during back-to-back testing.

     6.  Testing  of wind erosion must quantify decay of emission  rate with
time so that loss potential can be quantified.

The proposed distribution of tests is shown in Table 17.

4.6  PROPOSED TEST SITES

     Test sites with  established  control programs are preferable to those
where  control must  be applied for the  first  time.  This  helps to provide
credibility that  the  program  for  application of  the control technique is
realistic.  For the  same  reason,  chemical dust suppressants and  watering
will be tested at typical application densities rather than those which may
be purported to improve performance.  All of this  will ensure that the his-
torical cost and  performance  data which have  been compiled at a particular
site apply to the control measure as tested.

     At the time  of this writing, it is envisioned  that the first plant to
be tested will be Armco's Middletown Works.  The sources  proposed for test-
ing at Middletown are given in Table 18.  The remainder  of the field test
program,  which  is targeted  for completion by  the  end of October 1980, will
take place at two additional sites,  yet to be selected.

     The schedule proposed for testing  is as follows:

Testing of uncontrolled sources at Armco's        Late  June/early  July
  Middletown Works

Pre-test survey of second and third plant         Late July
  sites
                                   51

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               TABLE 17.   PROPOSED DISTRIBUTION OF TESTS
Source
Unpaved roads (heavy duty)

Paved roads
Storage pile maintenance
Storage pile wind erosion
(active piles)
Moderate winds
High winds
Control measure
Coherex
Lignin sulfonate or
calcium chloride
Watering
Flushing
Vacuuming
Watering
Watering

Test
method"1'
EP
EP
EP
EP
EP
EP
WT

Number of
tests
12
12
12
9
9
9
9
9
Moderate winds
High winds
Unpaved parking lots
Conveyor transfer stations
Exposed area wind erosion
(moderate winds)


Chemical
Enclosure
Chemical
9
9
EP 12
D ' 9
WT 9
EP = Exposure profiling
WT = Wind tunnel testing
D  = Duct sampling
                                 52

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    TABLE 18.  SOURCES PROPOSED FOR TESTING AT ARMCO'S MIDDLETOWN WORKS






           Source                                         Control measure






Unpaved road                                            Coherex application




Paved road                                              Flushing/vacuuming




Coal stockpile - maintenance                            Watering




Coal stockpile - wind erosion                           Watering
                                   53

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Testing of controlled sources at Arraco's
  Middletown Works
Early August
Testing of uncontrolled and controlled
  sources at second plant
Late August/early September
Testing of uncontrolled and controlled
  sources at third plant
Late September/early October
     In addition, it is also recommended that two or three additional plants
with active  control programs be visited during this period to gather addi-
tional data on the cost and performance of control techniques for open dust
sources.

     The total effort (technical person-hours) required for the testing pro-
gram and subsequent evaluation of cost-effectiveness of control techniques
may be estimated from the number of field test performed.   For this purpose,
the number of  test should be multiplied by 80 person-hours.  This estimate
should be  refined based  on final definition of  the scope of the program.
                                   54

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                                REFERENCES
 1.   Bohn,  R.,  T.  Cuscino,  Jr.,  and  C.  Cowherd,  Jr.  Fugitive Emissions  from
     Integrated Iron and Steel  Plants.   Prepared by  Midwest  Research  Institute
     for U.S. Environmental Protection  Agency, Publication No. EPA-600/2-78-
     050,  March 1978.

 2.   Cowherd,  C.,  Jr., R.  Bohn,  and T.  Cuscino,  Jr.   Iron and Steel  Plant
     Open Source Fugitive Emission Evaluation.   Prepared by  Midwest Research
     Institute  for U.S.  Environmental Protection Agency, Publication  No. EPA-
     600/2-79-103, May 1979.

 3.   Cowherd,  C.,  Jr., K. Axetell, Jr., C. M. Guenther, and G.  Jutze.  De-
     velopment  of  Emission Factors for Fugitive Dust Sources.   Prepared by
     Midwest Research Institute  for  U.S.  Environmental Protection Agency,
     Publication No. EPA-450/3-77-027,  July 1977.

 4.   Cowherd,  C.,  Jr., and  C.  M. Guenther.  Development of a Methodology
     and Emission  Inventory for  Fugitive  Dust  for the Regional Air Pollu-
     tion Study.  Prepared by Midwest Research Institute for U.S.  Environ-
     mental Protection Agency,  Publication No.  EPA-450/3-76-003,  January
     1976.

 5.   McCutchen, G.,  and R.  Iversen.   Steel Facility  Factors.  U.S. Environ-
     mental Protection Agency,  Research Triangle Park,  North Carolina.   Pre-
     pared 1975 and revised December 8,  1976.

 6.   American Iron and Steel Institute.   Source  Data for Steel Facility  Fac-
     tors.   Final  prepared  July 13,  1976.

 7.   Speight,  G. E.   Best Practicable Means in  the Iron and  Steel Industry.
     The Chemical  Engineer, (3):132-139,  1973.

 8.   Cuscino,  T. ,  Jr.  Taconite Mining Fugitive Emissions  Study.   Prepared
     by Midwest Research Institute for Minnesota Pollution Control  Agency,
     June 7, 1979.

 9.   Kalika, P. W.,  R. E. Kenson, and P.  T. Bartlett.   Development of Proce-
     dures for  the  Measurement  of Fugitive Emissions.  Prepared for U.S.
     Environmental Protection Agency, Publication No.  EPA-600/2-76-284,  1976.

10.   Cowherd,  C.,  Jr.   Measurement of Fugitive  Particulate.  Second Symposium
     on Fugitive Emissions  Measurement  and Control,  Houston, Texas, May  1977.

11.   Lundgren,  D.  A.,  and H.  J.  Paulus.   The Mass Distribution of Large  At-
     mospheric  Particles.  Paper No. 73-163.  Presented at the 66th Annual
     Meeting of the Air  Pollution Control Association, Chicago, Illinois,
     June 1973.

12.   Turner, D. B.  Workbood of Atmospheric Dispersion Estimates.  AP-26,
     U.S.   Environmental  Protection  Agency,  Research Triangle  Park,
     North Carolina, 1970.

                                  55

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13.   Blackwood,  T.  R. ,  T. F. Boyle,  T.  L.  Peltier, E. C.  Eimutis, .and
     D. L. Zanders.  Fugitive Dust  from Mining Operations.  Prepared for
     the U.S. Environmental  Protection Agency, Contract  No.  68-02-1320,
     Task 6,  May 1975.

14.   Cowherd, C., Jr., C. M. Maxwell, and D. W. Nelson.  Quantification of
     Dust Entrainment from Paved  Roadways.   Prepared by Midwest Research
     Institute for U.S.  Environmental Protection Agency,  Publication No.  EPA-
     450/3-77-027, July 1977.

15.   SSM.  Inhaled Particulates.   Environmental Science and Technology,  12:13,
     December 1978,  p.  1354.

16.   Wedding, James  B.   Ambient  Aerosol Sampling:   History, Present Thinking
     and a Proposed  Inlet for Inhalable Particulate Matter.  Paper presented
     at the  Air Pollution Control Association Specialty Meeting.  Seattle,
     Washington,  April 1980.

17.   Bagnold, R.  A.   The Physics  of Blown Sand and Desert Dunes,  Methuen,
     London,  1941.

18.   Chepil,  W.  S.,  and  N.  P.  Woodruff.  The Physics of Wind Erosion and
     Its Control.   In:  Advances  in Agronomy, Vol.  15, A.  G. Norman (Ed.),
     Academic Press, New York, NY, 1963.

19.   Cooper,  D.  W.,  et al.  Setting  Priorities  for Control of Fugitive Par-
     ticulate Emissions from Open Sources.  Prepared by Harvard University
     for the U.S. Environmental Protection  Agency.  Publication No. EPA-
     600/7-79-188, August 1979.

20.   Bonn, R., et al.  Dust Control  for Haul Roads--A Manual.   Draft Report
     prepared by  Midwest  Research Institute for the U.S.  Bureau of Mines,
     May 1980.

21.   Anonymous.    Investigation of Fugitive  Dust—Sources, Emissions,  and
     Controls.  Prepared  by  PEDCo  Environmental  for U.S. Environmental
     Protection Agency under Contract No.  68-02-0044, Task 9,  May  1973.

22.   Anonymous.   Evaluation  of Fugitive  Dust  from Mining.  Task 2 Report
     prepared by  PEDCo  Environmental  for U.S.  Environmental Protection
     Agency under Contract No.  68-02-1321, Task 36, June  1976.

23.   Anonymous.   Technical Guidance  for Control of Industrial Process  Fugi-
     tive Particulate Emissions.  Prepared by PEDCo Environmental for U.S.
     Environmental  Protection Agency, Publication  No.  EPA-450/3-77-010,
     March 1977.

24.   Boscak,  V.,  and J. S. Tandon.  Development of  Chemicals from Suppres-
     sion of Coal Dust  Dispersion from Storage Piles.  Paper presented at
     Fourth  Annual  Environmental Engineering  and  Science Conference,
     Louisville,  KY, March 1974.
                                   56

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25.  Currier, E.  L. ,  and B. D. Neal.  Fugitive  Emissions  at Coal-Fired
     Power Plants.  Paper No.  79-11.4  presented  at Annual Meeting of the
     Air Pollution Control Association, June 1979.
                                   57

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                         APPENDIX A
EXAMPLE DATA COMPILATION FROM MATERIALS HANDLING FLOW CHARTS
                             A-l

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                   TABLE A-l.   RAW AND INTERMEDIATE MATERIAL HANDLING AT THE INTERLAKE CHICAGO PLANT IN  1978

Origination
Material Mode
Coal Truck unloaded
(26,000 ST)
Railcar unloaded
by rotary dump
(495,000 ST)
Coke Coke Ovens
(345,000 ST)


Iron Ore Pellets Ship unloaded by
clamshell
(l,20:i,000 ST)

>
1
t-o
Dolomite Truck unloaded
at storage pile
(35,300 ST)


Limestone Ship unloaded by
clamshell
(123,000 ST)


Handling
Transfer Storage
Station Load-in
9 transfer Scraper
stations (495,000 ST)
(521,000 ST)


2 transfer Conveyor
stations stacker
(345.000 ST) (17,000 ST)

None Same clamshell
used to unload
ships
(1,203,000 ST)


None Same truck used
to deliver
material to
plant
(35,300 ST)
None Same clamshell
used to unload
shi ps
(123,000 ST)

Method and Amount of Material Handled
Sto'rage
Open storage
pile
(505,000 ST)


Open storage
pile
(17,000 ST)

Open storage
pile
(1,203,000 ST)



Open storage
pile
(35,300 ST)


Open storage
pile
(123,000 ST)


Storage
Load-out
Scraper
(521,000 ST)



Front-end loader
dump into conveyor
hopper/feeder
(17,000 ST)
Bucket wheel
reclaimer onto
underground
conveyor
(1,203,000 ST)

Crane-Clam-
shell bucket
transfer to
conveyor
(35,000 ST)
Crane-Clam-
shell bucket
transfer to
conveyor
(123,000 ST)
Transfer
Station Screening
21 transfer None
stations
(521,000 ST)


2 transfer Screened - 90%
stations to coke oven; 107.
(345,000 ST) to sinter plant
(345,000 ST)
2 transfer None
stations
(1,203,000 ST) '



2 transfer None
stations
(35.300 ST)


2 transfer No"c
stations
(123,000 ST)


Sinter, Nodules
and Briquette
Sinter  Plant
  (302,000 ST)
  transfer
  station
  (302,000 ST)
                                                        None
                                                                           None
                                                                                               None
                        transfer
                        station
                       (302,000 ST)
                   Screened  - 82Z to
                     blast  furnace;
                     18% recycled
                     (272,000 ST)
Sinter  Input
(Flux,  Iron ore
.-ind Coke  fines)
Truck unloaded
  at storage pile
  (398,000 ST)
2 transfer         Same  truck used    Open storage
  stations         to  deliver material   pile
  (199,000 ST)     to  plant             (498,000 ST)
                  (199,000 ST)
                  Conveyor stacker
                  (199,000 ST)
Front-end  loader
dump into  conveyor
hopper/feeder
(398,000 ST)
3 transfer
  stat ions
  (398,000 ST)
                                                                                                                                           None

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              TABLE A-2.  RAW AND INTERMEDIATE MATERIAL HANDLING AT THE  J&L  STEEL ALIQUIPPA PLANT IN 1978
i
u>

Material
Coke


Coa I for bo I lers
and storage







Coal for Coke
Oven






Iron Ore Pellets










Unaggloiuera ted
Iron Ore




Origination
Mode
Railcar unloaded
by bottom dump
(1,465,000 ST)
Ua rge unloaded by
c Inmshel 1
(34,600 ST)
Barge unloaded by
bucket-ladder
conveyor
(1,678,000 ST)
Railcar unloaded
by bottom dump
(17,300 ST)
Ba rge unloaded by
bucket-ladder
conveyor and fed
into bins
(2,358.000 ST)
Railcar unloaded
via rotary dump
(73,000 ST)
Railcar unloaded
to transfer car
via rotary dump
(1,184,000 ST)
Kallcar unloaded
to conveyor via
bottom dump
(1,184,000 ST)



Railcar unloaded
to transfer car
via rotary dump
(62,200 ST)

Handling Method
Transfer Storage
None Conveyors
( 1,465, 000 -ST)

None Conveyor to
temporary storage
pile via clamshell
(623,000 ST)





22 transfer Conveyors to
stations crusher to bins
(2,358,000 ST) (2,431,000 ST)





None Transfer car
to temporary
storage area
to ore yard
pile via
clamshell
(1,184,000 ST)
Conveyors to
cast-house
storage bins
(1,184.000 ST)
None Transfer car to
temporary storage
area to ore yard
via clamshell
(62.200 ST)
and Amount of Material Handled
Storage
Storage bins
(1.465.000 ST)

Open storage
pile
(623.000 ST)






Storage bins
(2.431,000 ST)






Open storage
pile
(1,184.000 ST)
Casthouse
storage bins
(1,184,000 ST)





Open storage
pile
(62,200 ST)


Storage Transfer
Load-out Stations Screening
Conveyors None screened - 95% to
(1,465,000 ST) blast furnaces; 57.
to sinter plants
Clamshell to None None
conveyor
(623,000 ST)






Bins to con- None None
veyor to
crusher to
bins
(2,431,000 ST)



Clamshell to Transfer car Screened
transfer car to cast house (1,018,000 ST)
(1.184.000 ST) storage bin
(1,184,000 ST)







Clamshell Transfer car Screening
bucket to to bin (27,700 ST)
transfer car (62,200 ST)
(62.200 ST)

                                                       '(continued)

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                                TABLE A-2.    (concluded)


Or Igl ii.it ion
Material node
Lliitestone/Dolonii te Railcar unloaded
to transfer car
via rotary dump
(71.000 ST)
RnLlcar unloaded
to conveyor via
bottom dump
(30.000 ST)
Sinter Sinter Plant
(1,548,000 ST)









Sinter Input (Flux, Railcar unloaded
Iron ore and Coke to conveyor via
Fines) rotary dump
Handling Method
Transfer Storage
Stations Load* in
None Transfer car to
temporary storage
area to main
storage area via
clamshell
(71,000 ST)
Conveyor to bins
(30,000 ST)
5 transfer Conveyor to bins
stations (1,548.000 ST)
(1.548,000 ST)








2 transfer Conveyor to bins
stations (2.182,000 ST)
(2,182,000 ST)
and Amount of Material Handled
Storage
Open storage
pile
(71,000 ST)
Dins
(30.000 ST)



Bins
(1,548.000 ST)









Bins
(2,182,000 ST)

Storage
Loa d - ou t
Clamshel I
bucket to
transfer car
(71,000 ST)




Bins to trans-
fer car
(1,548,000 ST)








Bins to con-
veyor
(2,182.000 ST)
Transfer
Stations Screening
Transfer car to None
bin
(71.000 ST)





Transfer car Screening
to caschonse (666,000 ST)
bins to skip
cars
(882.000 ST)
Transfer car
to casthouse
bins to 3
transfer
stations
(666,000 ST)
15 transfer None
stations
(2,182,000 ST)
  (1,527.000 ST)
Railcar unloaded Co
  conveyor via
  bottom dump
  (655,000 ST)

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            APPENDIX B






BIBLIOGRAPHY FOR OPEN DUST CONTROL
               B-l

-------
 1.   Anonymous.   Industrial  Ventilation.  American  Conference of Govern-
     mental  Industrial  Hygienists,  Committee  of  Industrial Ventilation,
     Lansing,  Michigan,  1970.

 2.   Manufacturer's  Literature,  Deter  Company, East Hanover, New Jersey.

 3.   Price,  W.  L.  Open Storage  Piles  and Methods of Dust Control.  Paper
     Presented at the October  1972  Meeting  of the American Institute of
     Mining  Engineers,  Birmingham,  Alabama.

 4.   PEDCo Environmental Specialists.   Investigation of Fugitive Dust;
     Volume  I:   Sources, Emissions,  and Control.  EPA-450/3-74-036, U.S.
     Environmental Protection  Agency,  Research Triangle Park, North Carolina,
     1974.

 5.   Handy,  R.  L., J. M. Hoover,  K.  L.  Bergeson, and D. E. Fox.  Unpaved
     Roads as  Sources for Fugitive  Dust.  Transportation Research News,
     (60):6-9,  Autumn 1975.

 6.   Manufacturer's  Literature,  Roscoe Manufacturing Company, Minneapolis,
     Minnesota.

 7.   Carpenter,  B. H. and G. E.  Weant  III.  Particulate Control for Fugitive
     Dust.  EPA-600/7-78-071,  U.S.  Environmental Protection Agency, Research
   .  Triangle  Park,  North Carolina,  April 1978.

 8.   Cooper, D.  W.,  J.  S.  Sullivan,  Margaret  Quinn, R. C. Antonelli, and
     Maria Schneider.   Setting Priorities for Control  of Fugitive Particu-
     late Emissions  from Open  Dust  Sources.   EPA-600/7-79-186, U.S. Environ-
     mental  Protection  Agency, Research Triangle Park, North Carolina,
     August  1979.

 9.   Hoenig, Stuart  A.   Use  of Electrostatically Charged Fog for Control of
     Fugitive  Dust Emissions.  EPA-600/7-77-131, U.S.  Environmental Protec-
     tion Agency,  Research Triangle Park, North  Carolina, November 1977.

10.   Daugherty,  D. P. and D. W.  Coy.   Assessment of the Use of Fugitive
     Emission  Control Devices.  EPA-600/7-79-045, U.S. Environmental Pro-
     tection Agency, Research  Triangle Park,  North  Carolina, February  1979.

11.   Bonn, R.,  T.  Cuscino, Jr.,  and C.  Cowherd,  Jr.  Fugitive Emissions
     from Integrated Iron and  Steel Plants.   EPA-600/2-78-050, U.S. Environ-
     mental  Protection  Agency, Research Triangle Park, North Carolina,
     March 1978.

12.   Seibel, Richard J.  Dust  Control  at a  Transfer Point Using Foam and
     Water Sprays.  Technical  Progress Report 97, U.S. Bureau of Mines,
     Washington, D.C.,  May 1976.

13.   Bonn, Russel.  Dust Control from  Haul  Roads -  Draft Report. U.S.
     Bureau  of Mines, Twin Cities Mining Research Center, Minneapolis,
     Minnesota,  October 1979.
                                   B-2

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14.   Cowherd,  Chatten,  Jr.,  Russel  Bohn,  and  Thomas  Cuscino,  Jr.   Iron  and
     Steel Plant Open Source Fugitive Emission Evaluation.  EPA-600/2-79-
     103,  U.S.  Environmental Protection Agency,  Research Triangle  Park,
     North Carolina,  May 1979.

15.   Sultan,  Hassan A.   Soil Erosion and  Dust Control  on Arizona Highways-
     Part  IV-Final Report on Field  Testing Program.  Report No. ADOT-RS-
     13(l4l)IV, Arizona Department  of Transportation,  Phoenix, Arizona,
     November'1975.
                                   B-3

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