United States
 Environmental Protection
 Agency
Office of Air Quality        EPA - 454/R-99-018
Planning and Standards       June 1999
Research Triangle Park, NC 27711
 Air
&EPA
    Secondary Aluminum Industry
    Final Emissions Test Report
   Gulp Aluminum Alloys
   Steele, Alabama

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                                 Table of Contents
                                                                             Page
 1.0    INTRODUCTION	1-1
       1.1    Objectives	1-2
       1.2    Brief Site Discussion		1-3
       1.3    Emissions. Measurements Program		 1-3
             1.3.1  Test Matrix	 1-3
             1.3.2  Test Schedule		1-5
       1.4    Test Report	 1-5

2.0    SUMMARY OF RESULTS	 2-1
       2.1    Emissions Test Log	2-1
       2.2    Dioxin/Furan Results .	2-5
             2.2.1   Overview	 .\	2-5
             2.2.2  Dioxin/Furan Emission Results	2-5
       2.3    HC1 Results  	':....,..	2-18
             2.3.1   Overview	2-18
           '  2.3.2  HC1 Emission Results  	;	2-19
       2.4    Particulate Results			2-23
             2.4.1   Overview	 2-23
       2.5    FTIR Results  . .		2-26
             2.5.1   Overview  . .	.	;. .	2-26
             2.5.2   FTIR Emission Results	2-27
                   2.5.2.1 EPA Method 301 FTIR Validation Results for HC1  	2-28
                   2.5.2.2 FTIR HC1 Test Results	2-28
                   2.5.2.3 FTIR Process Optimization		2-32
                   2.5.2.4 FTIR Screening Results ..		2-33
                   2.5.2.5 FTIR Sampling and Measurement System Response
                                Time Measurement	2-39
                   2.5.2.6 Comparison of FTIR and Method 26A Results for HC1 	2-41

3.0    DESCRIPTION OF FACILITY	3-1

4.0    SAMPLING LOCATIONS	4-1

5.0    SAMPLING AND ANALYTICAL PROCEDURES BY ANALYTE	   . 5-1
       5.1     Chlorinated Dibenzo-^-Dioxin and Chlorinated Dibenzofuran Emissions Testing
                   Using EPA Method 23	5-1
             5.1.1   Method 23  Sampling Equipment	5-1
             5.1.2   Method 23  Equipment Preparation  	5-1

                                        iii

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                     Table of Contents (Continued)
                                                                          Page

              5.1.2.1 Glassware Preparation	5-3
              5.1.2,2 XAD-2® Resin and Filter Preparation	,	5-3
              5.1.2.3 Method 23 Sampling Train Preparation	'..'	5-5
       5.1.3   Method 23 Sampling Operations	•	5-6
              5.1.3.1 Preliminary Measurements  ..........\.'	5-6
              5.1.3.2 Assembling the Train	5-6
              5.1.3.3 Sampling Procedures	5-7
       5.1.4   CDD/CDF Sample Recovery		.'........	 5-12
       5.1.5   CDD/CDF Analytical Procedures  	..:....'.		5-15
              5.1.5.1 Preparation of Samples for Extraction ...:-....	5-18
              5.1.5.2 Calibration of GC/MS System	5-18
       5.1.6   CDD/CDF Analytical Quality Control..-.."	5-18
              5.1.6.1 CDD/CDF Quality Control Blanks,	5-19
              5.1.6.2 Quality Control Standards and Duplicates .	 5-20
       5.1.7   Analytes and Detection Limits for Method 23 .V	5-21
5.2    Hydrochloric Acid/Particulate Matter Emissions Testing Using EPA
              Method 26A	 5-23
       5.2.1   Method 26A Sampling Equipment	.".. • '5-23
       5.2.2   Method 26A Sampling Equipment Preparation	5-25
              5.2.2.1 Glassware Preparation	5-25
              5.2.2.2 Reagent Preparation	5-25
              5.2.2.3 Equipment Preparation	5-26
       5.2.3   Method 26A Sampling Operations  	5-28
              5.2.3.1 Preliminary Measurements	5-28
              5.2.3.2 Assembling the Train		5-28
              5.2.3.3 Sampling Procedures	5-29
       5.2.4   Method 26A Sample Recovery	5-30
       5.2.5   HC1  Analytical Procedures  .	5-37
       5.2.6   HC1  Analytical Quality Control	5-38
       5.2.7   Particulate Analysis	5-38
       5.2.8   Quality Control for Gravimetric Procedures  	5-40
5.3    FTIR EPA Method 320  	5-40
       5.3.1   FTIR Sampling Equipment	5-40
       5.3.2   Preparation for Sampling	5-43
       5.3.3   Sampling.	'.	5-45
       5.3.4   FTIR Method Data Review, Validation, and Verification
                    Requirements	5-48
       5.3.5   QC for the FTIR	5-51
                                   IV

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                           Table of Contents (Continued)
                                                                               Page

6.0   QUALITY ASSURANCE/QUALITY CONTROL	6-1
      6.1    Sampling QC Results	6-1
             6.1.1  .Leak Checks	'.".	'.	...6-1
             6.1.2  Percent Isokinetics	..6-4
             6.1.3  Meter Box Calibrations	6-5
             6.1,4  Field Blank Results	6-5
             6.1.5  FTIR Sampling Quality Control	6-7
      6.2    Analytical Quality Control Results	6-9
             6.2,1   D/F Analytical Quality Control	6-9
                   6.2.1.1 D/F Quality Control Blanks	6-9
                   6.2.1.2 Quality Control Standards	6-10
             6.2.2  HC1 Analytical Quality Control	6-10
             6.2.3  Quality Control for Gravimetric Procedures  	6-11
             6.2.4  FTIR Analytical Quality Control	6-11

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                                   List of Figures









                                                                                Page






 2-1    FTIR System Response Profile (Measured on 7 December 1997)	2-40




 4-1    El, Chip Dryer Baghouse Inlet	4-2




 4-2    E2, Chip Dryer Baghouse Outlet	4-3




 4-3    E3, Reverberatory Furnace #1  Baghouse Inlet	4-4




 4-4    E4, Reverberatory Furnace #1  Baghouse Outlet  	4-5




 4-5    Chip Dryer Baghouse Inlet, Traverse Points	4-6.




 4-6    Chip Dryer Baghouse Outlet, Traverse Points	4-7




 4-7    Reverberatory Furnace #1 Baghouse Inlet Traverse Points	4-8




4-8    Reverberatory Furnace #1 Baghouse Outlet Traverse Points	4-9




5-1    Method 23 Sampling Train Configuration	5-2




5-2    Method 23 Field Recovery Scheme	5-13




5-3    Extraction and Analysis Schematic for Method 23 Samples-	5-17




5-4    Schematic of Method 26A Sampling Train	5-24




5-5    Method 26A Sample Recovery Scheme	5-34




5-6    Method 5 Preparation and Analysis Scheme (Integral Part of Method 26A)	5-39




5-7    FTIR Sampling and Measurement System  	5-42
                                         VI

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                                     List of Tables




                                                                                 Page




 1-1    Gulp Aluminum Alloys Facility (Steele, Alabama) Test Matrix	  1-4




 2-1    Emissions Test Log	2-2




 2-2    Sample Volume Collected, dscm	2-4




 2-3    Flue Gas Volumetric Flow Rate, dscmm	2-4




 2-4    Chip Dryer, Inlet D/F Stack Gas Concentration, ng/dscm	  2-6




 2-5    Chip Dryer, Outlet D/F Stack Gas Concentration, ng/dscm  	2-7




 2-6    Chip Dryer, Outlet D/F Emission Rate, ug/Mg Feed	  2-9




 2-7    Chip Dryer, 2,3,7,8-TCDD Toxicity Equivalent Concentrations  	2-11




 2-8    Reverberator}' Furnace #1, Inlet D/F Concentration, ng/dscm  	2-13




 2-9    Reverberatory Furnace #1, Outlet D/F Concentration, ng/dscm	2-14




 2-10   Reverberatory Furnace #1, Outlet D/F Emission Rate, ug/Mg Feed	2-16




 2-11   Reverberatory Furnace #1, 2,3,7,8-TCDD Toxicity Equivalent Concentrations	. 2-17




 2-12   HC1 and C12 Concentration, ug/dscm	2-20




 2-13   HC1 and C12 Concentration, ppm	2-20




 2-14   HC1 and C12 Emission Rate, Ibs/hour	2-21




 2-15   HC1 Removal Efficiency	2-21




 2-16   HC1 and C12 Emission Rate, Ibs/Ton of Feed		2-22




 2-17   Stack Gas Paniculate Matter Concentration, gr/dscm	2-24




 2-18   Particulate Matter Emission Rate, Ibs/hour .. .'.	2-24




2-19   Baghouse Particulate Removal Efficiency,%	2-24




2-20   Particulate Matter Emission Rate, Ibs/Ton of Feed	2-25




                                          vii

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                             List of Tables (Continued)



                                                                               Page


2-21   Summary of EPA Method 301 FTIR Validation Results for HC1	2-28

2-22   Chip Dryer FTIR HC1 Results, ppmv	 2-30

2-23   Reverberatory Furnace #1 Baghouse FTIR HC1 Results During Charging, ppmv  ... 2-30

2-24   Reverberatory Furnace #1 Baghouse FTIR HC1 Results During Tapping, ppmv .... 2-31

2-25   Combined Charging and Tapping Reverberatory Furnace #1 Baghouse FTIRHC1 .
             Results, ppmv	2-32

2-26   Reverberatory Furnace #1 Baghouse FTIR HC1 Results - Grand Average, ppmv  . . .2-32

2-27   Reverberatory Furnace #1 Hood Baghouse Outlet HC1 Results - Overnight, ppmv ... 2-33

2-28   Other Species Detected by FTIR - Chip Dryer Inlet	2-34

2-29   Other Species Detected by FTIR - Chip Dryer Outlet	2-35

2-30   Other Species Detected by FTIR - Reverberatory Furnace #1 Inlet	2-36

2-31   Other Species Detected by FTIR - Reverberatory Furnace #1 Outlet 	2-38

2-32   Comparison of FTIR and Method 26A results for HC1, ppm 	2-41

5-1    Method 23 Glassware Cleaning Procedure (Train Components, Sample Containers
             and Laboratory Glassware)  	5-4

5-2    CDD/CDF Sampling Checklist		5-9

5-3    Method 23 Sample Fractions Shipped To Analytical Laboratory	5-15

5-4    CDD/CDF Congeners To Be Analyzed	5-16

5-5    Method 23 Blanks Collected	5-19

5-6    Analytical Detection Limits For Dioxins/Furans	5-22
                                        vm

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                              List of Tables (Continued)




                                                                                Page

5-7    CDD/CDF Method Detection Limits	5-22

                                                                                f
5-8    Glassware Cleaning Procedure (Method 26A Train Components)	5-26.

5-9    Sampling Checklist for EPA Method 26A	5-31

5-10.  Typical FTIR Operating Parameters	 .5-45


5-11   Compounds for Which Reference FTIR Spectra Are Available in the ERG Spectral
             Library	5-49


6-1    Summary of Dioxin/Furan Test Leak Check Results  	:	6-2

6-2    Summary of HC1/PM Test Leak Check Results  	6-3

6-3    Summary of Isokinetic Percentages	6-4


6-4    Dry Gas Meter Post-Test Calibration Results  	6-5


6-5    Method 26A Field Blank Analysis Results, ug Detected	6-6

6-6    Method 23 Field Blank Analysis Results, ng Detected	6-7

6-6    QC Spiking Results	6-13

6-7    HC1 Gas Standard Analysis Results	6-14

6-8    CO Gas Standard Analysis Results  	:	 6-15

6-9    CH4, NOX, and CO2 Gas Standard Analysis Results 	6-16

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 1.0    INTRODUCTION

       The purpose of this testing program was to obtain emissions data for uncontrolled and
 controlled hydrochloric acid (HCl), paniculate matter (PM) and speciated hydrocarbon
 Hazardous Air Pollutants (HAPs) from a secondary aluminum processing plant to support a
 national emission standard for hazardous air pollutants (NESHAP).

       The Gulp Aluminum Alloys facility in Steele, Alabama, is a secondary aluminum
 reclamation facility. The Gulp facility accepts many different forms of scrap aluminum
 feedstock, and operates a chip dryer to volatilize oils and lubricants from scrap aluminum chips
 prior to the remelting operation. The chip dryer emissions are captured by closed hoods and are
 ducted to a lime injected baghouse. There is a side-well reverberatory furnace that is used to
 remelt, flux, and alloy aluminum scrap that has been pre-processed in the chip dryer operation in
 addition to non-processed purchased aluminum scrap. The side-well reverberatory furnace
 emissions are captured by a canopy hood located above the charging and refluxing side-well and
 ducted to a lime injected baghouse. Emissions from the hearth stack are uncontrolled.

       The existing total  hydrocarbons (THC) emissions test data from secondary aluminum
 smelting plants had not been  speciated to determine HAP content. Additional data were needed
 to identify HAPs emitted  and their respective emission rates from melting furnace and chip
 drying operations at secondary aluminum smelting plants. Also, information on the HCl, PM,
 and dioxin/furan (D/F) removal efficiency of baghouses with dry lime injection was needed.

       Source tests were required to quantify and characterize the HCl, PM, D/F, and HAP
 emissions and to assess control device performance from chip drying and side-well reverberatory
 furnace #1 operations, and to identify, quantify, and assess the performance of a lime  injected
baghouse at two lime injection rates for HCl from the side-well reverberatory furnace #1
operations. Application of the following stationary source test methods was required to
adequately characterize these processes:
                                          1-1

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       •      Determination of D/F using EPA Method 23;
              Determination of HC1 and PM using EPA Method 26A and EPA Method 320; and
              Screening for speciated hydrocarbon HAPs using EPA Method 320.

       The objective of this work assignment was to perform all activities necessary to
characterize specified point sources for the parameters listed above. The facility selected for
testing, the Gulp Aluminum Alloys Plant located in  Steele, Alabama, has lime injected baghouses
as control technology.

1.1    Objectives

       The objective of the testing at the Gulp Aluminum Alloys facility, in Steele, Alabama,
was to perform all activities necessary to characterize the lime injected baghouses for the
following emission components:

       •       Determination of D/F using EPA Method 23;
              Determination of HC1/PM using EPA Method 26A and EPA Method 320; and
       •       Screening for speciated hydrocarbon  HAPs using EPA Method 320.

       For the manual methods, testing was performed simultaneously at the inlet and outlet of
the chip dryer lime injected baghouse and simultaneously at the reverberatory furnace #1 lime
injected baghouse. FTIR testing was not simultaneous at inlet/outlet; the FTIR alternated
between inlet/outlet (for example, ten minutes inlet/ten minutes outlet).  In addition, a day of
testing was performed using EPA Method 320 to identify, quantify, and assess the performance
of the lime injected baghouse associated with the reverberatory furnace #1 for HC1 removal at
two injection rates of lime.  Two additional days were required to perform a Method 301
validation of FTIR for HC1: one day each for the two baghouses.
                                          1-2

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 1.2   Brief Site Discussion

       The Gulp Aluminum Alloys Plant is located in Steele, Alabama, approximately 4 miles
 south of Gadsden, Alabama. The plant is a secondary aluminum plant, primarily smelting
 recycled aluminum. Gulp Aluminum Alloys primarily recycles aluminum parts to create a
 secondary aluminum alloy which is used in cast aluminum.  The plant operates 24 hours per day,
 but the chip dryer process is down Monday from 7 AM to 4 PM, except for the furnaces.

       The Gulp Aluminum Alloys Plant has two baghouses associated with the furnaces as
 control devices: the first baghouse is the original one while the second is newer. The exhaust
 stacks on both are approximately the same size. Furnace #1 and Furnace #2 differ in that
 Furnace #2 has an additional exhaust from the sweat furnace. The sweat furnace is used to
 separate plastic parts and metals of higher melting points from the aluminum prior to placing the
 aluminum into the furnace.

 1.3    Emissions Measurements Program

       This section provides an overview of the emissions measurement program conducted at
 the Gulp Aluminum Alloys Plant in  Steele, Alabama. Included in this section are summaries  of
 the test matrix, sampling locations,.sampling  methods, and laboratory analysis. Additional detail
 on these topics are provided in the sections that follow.

 1.3.1  Test Matrix

       The sampling and analytical matrix that was performed at Gulp Aluminum Alloys is
presented in Table l-l, with the schedule that was followed in the field. Manual and Fourier
Transform Infrared  (FTIR) instrumental emissions tests were performed, with detailed
descriptions of these sampling and analytical procedures provided in Section 5.0 of this
document.
                                          1-3

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Table 1-1. Gulp Aluminum Alloys Facility (Steele, Alabama) Test Matrix
           Industry:  Secondary Aluminum
           Process:  Aluminum Chip Drying and  Smelting
Sampling
Location
E2
Chip Dryer
Lime Injected
Baghouse
Outlet
E1/E2
Chip Dryer
Lime Injected
Baghouse
Inlet/Outlet

E3/E4
Reverberatory
Furnace #l
Lime Injected
Baghouse
E3/E4
Reverberatory
Furnace # 1
Lime Injected
Baghouse
E3/E4
Reverberatory
Furnace #1
Lime Injected
Baghouse
Inlet/Outlet



Runs/
Date
1 day
12/03/97



3
Run 1
12/05/97

Runs 2,3
12/06/97
1 day
12/07/97



1 day
12/07/97



6:
Run 1
12/08/97
Run 2
12/09/97
Run 3
12/10/97
Run 4
12/11/97

Sample Type
HC1 Validation




HC1/PM

Dioxins/Furans

All species
detected by FTIR1
HC1 Removal
efficiency study



HC1 Validation




HC1/PM

Dioxins/Furans

All species
detected by FTIR1



Reference
Method
Method 320




Method 26A

Method 23

Method 320

Method 320




Method 320




Method 26A

Method 23

Method 320




Sampling
Duration
4-8 hours




4 hours





4-8 hours




8-10
hours



4 hours








Analysis
Method
FTIR




Method 26A

Method 8290

Method 320

FTIR




FTIR




Method 26A

Method 8290

Method 320





Laboratory
ERG




Triangle Labs

Triangle Labs

ERG

ERG




ERG




Triangle Labs

Triangle Labs

ERG




' All species detected by FTIR includes all gaseous HAPs (i.e.. HC1), as well as criteria pollutants (i.e., NO,,
 S0:, CO).
2Work Assignment Manager elected to perform four test runs in the field.
                                        1-4

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 1.3.2 Test Schedule

       The daily test schedule is shown in Table 1-1. The test required one day of set-up at the
 chip dryer lime injected baghouse, two test days at the inlet/outlet of the chip dryer lime injected
 baghouse, one day of process operating parameter optimization using FTIR, and five test days at
 the inlet/outlet of the reverberatory furnace #1 lime injected baghouse. One day was allowed  as
 contingency/tear-down. The facility did not operate on Mondays from 7 AM to 4 PM, except for
 the furnaces; allowance was made for the plant schedule in the test schedule. Each test day was
 12 to 16 hours in length. Set-up and tear-down days were 8 to 10 hours in length.

 1.4    Test Report

       This final report, presenting all data collected and the results of the analyses, has been
prepared in six sections and two volumes, as described below:
              Section 1 provides an introduction to the testing effort and includes a brief
              description of the test site and an overview of the emissions measurements
              program;
              Section 2 gives a summary of the test results for the PM, HC1, D/F tests, and the
              FTIR results for HC1 and selected HAPs;
              Section 3 provides a description of the process and plant operation during the field
              test.  These data are to be supplied by EPA through Research Triangle Institute to
              be included at a later date;
              Section 4 gives a discussion of the sampling locations;
              Section 5 presents detailed descriptions of the sampling and analysis procedures;
              and
              Section 6 provides details of the quality assurance/quality control procedures used
              on this program and the QC results.
       The appendices containing copies of the actual field data sheets and the results of the
laboratory analyses are contained in Volume 2.
                                           1-5

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2.0    SUMMARY OF RESULTS

       This section provides the results of the emissions test program conducted at the Gulp
Aluminum Alloys plant from December 2 to December 11, 1997. Included in this section are the
results for the manual tests conducted for PM, HC1, CU, dioxin and furan and for the extractive
FTIR test conducted for HC1 and screening for selected HAPs.  Testing was performed at the
inlet and outlet of the baghouse associated  with the chip dryer and at the inlet and outlet of the
baghouse associated with the reverberatory furnace number 1.

2.1    Emissions Test Log

       Twenty eight manual tests were performed over a nine day period (14 D/F and  14
HC1/PM). Table 2-1 presents the emissions test log which shows the test date, location, run
number, test type and run times for each method. Concurrent with the manual testing at each
location were extractive FTBR measurements for HC1.

       Table 2-2 shows the volume of stack gas sampled for each run in dry standard cubic
meters (dscm) and Table 2-3 shows the stack gas volumetric flow rate during each run  in dry
standard cubic meters per minute (dscmm).  The percent relative  standard deviation (%RSD)
calculated for the stack flow rates (shown in Table 2-3) was less than  10 % indicating that each
process flow was maintained at a fairly constant rate over the respective test days.  All  related
field data sheets are given in Appendix A.
                                         2-1

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Table 2-1.  Emissions Test Log

Date
12/3/97
12/4/97
12/5/97







12/6/97















12/7/97
12/8/97










Location
Chip Dryer Outlet
Chip Dryer
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Run
Number
NA
Plant Down
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
NA
1
1
1
1
1
1
1
1
1
1

Test Type
FTIR HC1 Validation
NA
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HCI
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HCI
D/F.
FTIR (unconditioned)
FTIR (conditioned)
FTIR HC1 Validation
PM/HCI
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HCI
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3

Run Time
10:00-15:00
NA
08:00-14:40
08:00-14:40
08:00-11:30
12:40-14:30
10:20-14:40
08:00-14:40
08:00-11:30
12:40-14:30
08:34-13:20
08:34-13:30
08:35-10:40
11:20-13:20
08:34-13:20
08:34-13:30
08:34-10:34
11:20-13:20
15:45-20:03
15:45-20:03
15:46-17:46
18:10-20:03
15:45-20:03
15:45-20:03
15:45-18:03
18:10-20:03
12:00-17:00
09:48-15:42
09:48-15:42
09:45-12:00
12:00-13:20
13:20-15:42
09:48-15:42
09:48-15:42
09:45-12:00
12:00-13:20
13:20-15:42
                                   2-2

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Table 2-1.  (Continued)

Date
12/9/97









12/10/97









12/11/97










Location
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Run
Number
2
2
2
2
2
2
2
.2
2
2
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4

Test Type
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)'
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3

Run Time
12:10-18:18
12:10-18:18
12:20-14:20
14:15-15:50
15:50-18:15
12:11-18:37
12:10-18:18
12:20-14:20
14:15-15:50
15:50-18:15
11:16-17:03
11:15-17:03
11:14-13:34
13:30-14:16
14:16-17:03
11:16-17:03
11:15-17:03
11:14-13:34
13:30-14:16
14:16-17:03
06:20-12:55
06:21-12:56
06:18-08:48
08:45-10:05
10:05-12:55
06:20-12:55
06:21-12:56
06:18-08:48
08:45-10:05
10:05-12:55
'Sample not conditioned (moisture not removed) during first half of furnace charging
2Sample conditioned (moisture removed) during second half of furnace charging
3Sample unconditioned during mixing and tap out
                                         2-3

-------
Table 2-2. Sample Volume Collected, dscm
Baghouse Location
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
"urnace 1 Inlet
-urnace 1 Inlet
'urnace 1 Outlet
Furnace 1 Outlet
Parameter
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
Run!
1.98
4.38
2.78
2.81
4.01 .
3.85
7.34
7.22
Run 2
2.16
4.66
3.06
3.04
3.90
3.72
7.54
7.03
Run 3
2.22
4.2
2.9
2.86
3.74
3.9
7.05
6.95
Run 4
NA
NA
NA
NA
3.72
3.87
7.47
7.58
Average
2.12
4.41
2.91
2.90
3.84
3.84
7.35
7.20
%RSD
5.89
5.25
4.82
4.17
3.58
2.07
2.95
3.90
Table 2-3.  Flue Gas Volumetric Flow Rate, dscmm
Baghouse Location
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Outlet
"urnace 1 Outlet
Parameter
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
Runl
142
156
153
153
720
689
835
807
Run 2
162
160
171
174
666
642
753
736
Run 3
143
- 148
159
166
674
688
723
748
Run 4
NA
NA
NA
NA
579
603
674
722
Average
149
155
161
164
660 .
656
746
753
%RSD
7.56
3.95
5.69
6.4
8.92
6.30
9.05
.4.96
                                  2-4

-------
 2.2   Dioxin/Furan Results

 2.2.7  Overview

       Three 4-hour D/F tests were performed at the inlet and outlet of the baghouse associated
 with the chip dryer operation (total of 6) and four 6-hour tests were performed at the inlet and
 outlet of the baghouse associated with the reverberatory furnace number 1 (total of 8). The
 sampling and analysis procedures followed EPA Method 23 protocol. All results except for the
 2,3,7,8-tetrachlorodibenzofuran (2,3,7,8-TCDF) were determined by high resolution gas
 chromatography (HRGC)/high  resolution mass spectrometry (HRMS) using a DB-5 capillary gas
 chromatographic column. The  2,3,7,8-TCDF was determined by HRGC/HRMS  using a DB-225
 column which gives improved chromatographic resolution for this compound over the DB-5 and
 thus a more accurate quantitation. Any compound that was not detected is reported as a "less
 than" value with this value being the instrument detection limit.  A "less than" value rather than a
 "0" is used in all appropriate calculations. All D/F raw data can  be found in Appendix B of this
 report.

 2.2.2  Dioxin/Furan Emission Results

       Chip Drver

       Tables 2-4 and 2-5 present the concentration, in nanograms per dry standard cubic meter
 (ng/dscm), of the selected D/F congeners by run number, the average concentration over the three
 runs and the %RSD for the chip dryer inlet and outlet, respectively. These values were
calculated by dividing the reported analytical results, in ng, by the appropriate sample volume
collected, in dscm, from Table 2-2.  As indicated in Table 2-4 (dryer inlet), the concentration
values of several congeners in Runs 1 and 2 are presented as "greater than" values and should be
considered estimates. The amount of these analytes detected in the sample extracts exceeded the
calibration curve.  The observed concentrations for Run 3 are generally lower by a factor of two
than those observed for Runs 1  and 2, causing the %RSDs for most analytes to be in the 40 to

                                          2-5

-------
 Table 2-4.  Chip Dryer, Inlet D/F Stack Gas Concentration, ng/dscm
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6.7.8-HxCDD
1,2,3,7,8,9-HxCDD
1.2,3,4,6.7,8-HpCDD

OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2.3.4.7,8-HxCDF
1,2,3,6.7,8-HxCDF

2.3,4,6,7,8-HxCDF

1.2^3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF

1.2,3,4,7.8,9-HpCDF

OCDF
Runl
0.457
3.74
4.29
9.18
14.9
>29.9*

24.7
14.3
10.1
>18.4*
>22.1*
>13.5*

>18.8*

1.14
>28.8*

7.21

11.3
Inlet
Run 2
0.536
3.07
3.65
6.70
11.9
21.2

17.1
18.2
>14.48*
>20.9*
>27.3*
>17.0*

>23.0*

1.55
>32.6*

8.56

11.2
Run 3
0.205
1.50
1.43
2.86
4.48
9.60

8.21
4.17
' 4.55
8.40
15.4
6.43

8.19

0.357
18.5

2.17

4.14
Average
0.399
2:77
3.12
6.24
10.4
20.2

16.7
12.2
9.72
15.9
21.6
12.3

16.6

1.01
26.6

5.98

8.90
%RSD
43.4
41.6
48.1
51.0
51.4
50.4

49.4
59.3
51.3
41.6
27.6
43.7

45.7

59.5
27.5

56.4

46.3
*Sienal above calibration range
                                       2-6

-------
Table 2-5. Chip Dryer, Outlet D/F Stack Gas Concentration, ng/dscm
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3.4,6,7, 8-HpCDD

OCDD
2,3,7,8-TCDF
1.2,3,7.8-PeCDF
2.3,4,7, 8-PeCDF
1,2.3.4,7,8-HxCDF

1,2,3,6,7,8-HxCDF
2.3,4,6,7,8-HxCDF
1. 2,3,7, 8.9-HxCDF

1.2.3,4,6,7.8-HpCDF
1, 2.3,4,7, 8,9-HpCDF
OCDF
Runl
0.890
3.63
1.21
1.60
2.63
1.92

1.14
17.6
18.8
24.2
15.3

7.01
4.38
0.242

4.16
0.498
0.605
Outlet
Run 2
0.461
2.17
0.559
0.888
1.25
0.855

0.493
8.62
10.8
14.4
9.54

4.21
2.73 .
0.122

2.37
0.257
0.270
Run 3
0.524
2.66
0.839
1.15
1.75
0.874

0.455
9.93
13.1
17.8
12.3

5.73
3.32
0.161

2.87
0.266
0.255
Average
0.625
2.82
0.869
1.21
1.88
1.22

0.696
12.0
14.2
18.8
12.4

5.65
3.48
0.175

3.13
0.340
0.377
%RSD
37.1
26.3
37.5
29.7
37.3
50.1

55.3
40.2
28.9
26.3
23.1

24.8
24.0
35.1

29.6
40.3
52.5
                                   2-7

-------
 50 range. The fact that different feed stocks or combinations of feed stocks were used for each of
 the runs is the most probable explanation for this. The feed stock for Run 1 was continuous
 during the run. The feed stock for Run 2 was the remainder of the feed stock used during Run 1
 (depleted after approximately the first half of Run 2) plus a portion of a new feed stock of
 different material and different oily coating. The feed stock for Run 3 was a combination of the
 remainder of the second feed stock from Run 2 plus a third feed stock material with yet another
 different oily coating.  Each lot of feed stock material used during the testing was added to the
 loading hopper as needed until it was depleted, followed by the next lot until it was depleted and
 so on. Each lot of material was processed as a discrete material type and oily coating with no
 mixing or blending of the three lots. Table 2-5 (dryer outlet) shows concentrations considerably
 lower than the inlet for Runs 1 and 2, whereas for Run 3 the inlet and outlet values are similar.
 The %RSDs generally  in the 20 to 30 range still reflect the use of three different lots of feed
 stock.

       Table 2-6 shows the D/F stack emission rate from the chip dryer outlet in micrograms of
 analyte per megagram (jag/Mg) of feed stock for each of the three runs, the average and the
 %RSD.  These values were calculated using standard conversion factors (i.e., pounds to grams)
 and from the concentrations given in Table 2-5, the stack flow rates given in Table 2-3 and the
 number of pounds of each feed stock consumed during the test period as supplied by the facility.
 The latter data set (pounds of feed stock consumed) for each of the three runs was not a
 straightforward calculation. Mitigating factors included:

       •       Each lot of feed was processed at a different rate;
       •       Combinations of feed stock were used during two of the runs; and
       •       Two of the feed stocks were processed beginning on one day, finishing on the
              next day with the process shut down over night.

For run number one a single lot of feed stock was used, but it was processed over a two day
period (32,000 pounds  in 8 hours on the first day during Run  1 and 4,740  pounds in 3.5 hours on
the  next day during the  first part of Run 2). The feed rate of feed stock consumed during Run 1

                                          2-8

-------
Table 2-6. Chip Dryer, Outlet D/F Emission Rate, ug/Mg Feed
Congener
2,3,7,8-TCDD
1,2,3,7.8-PeCDD
1,2,3.4,7,8-HxCDD

1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD

1, 2,3,4,6,7, 8-HpCDD
OCD'D
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7, 8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3.4,6,7, 8-HxCDF

1,2,3,7,8,9-HxCDF

1. 2.3.4,6,7. 8-HpCDF

1.2,3.4,7.8.9-HpCDF

OCDF
Runl
4.50
18.3
6.12

8.10
13.3

9.71
5.76
88.9
94.8
122
77.2
35.4
22.1

1.22

21.0

2.52

3.06
Outlet
Run 2
5.41
25.5 .
6.56

10.4
14.7

10.0
5.79
101.2
126
170
112
49.4
32.0

1.43

27.8

3.01

3.17
Run 3
3.79
19.2
6.07

8.35
12.6

6.32
3.29
71.8
94.9
129
89.3
41.5
24.0

1.16

20.7

1 92

1.85
Average
4.57
21.0
6.25

8.96
13.5

8.69
4.95
87.3
105
140
92.8
42.1
26.1

1.27

232

248

2.69
%RSD
17.7
18.5
4.36

14.3
7.62

23.7
29.0
16.9
17.2
18.3
19.0
16.7
20.2

10.9

172

220

27.2
                                   2-9

-------
 was therefore calculated by dividing 32,000 by 8. The same logic was followed for Runs 2 and
 3, except that two different lots were used during each run and the average feed rate was
 therefore determined. The feed rate calculations are summarized below:
Run No.
1
2
2
3
3
Lot
1
1
2
2
3
Feed Time-Date
8 hrs- 12/5/97
3. 5 hrs- 12/6/97
8 hrs- 12/6/97
8 hrs- 12/6/97
2 hrs- 12/6/97
Pounds of Feed
32,000
4,740
20,500
20,500
7,000
Feed Rate
4,000 Ibs/hr
1,354
2,563
2,563
3,500
Avg. Feed Rate. Ibs/hr
4,000
1,959
3,032
       Table 2-7 shows the D/F congener concentrations in ng/dscm converted to 2,3,7,8-TCDD
toxicity equivalents as well as a summation of the values presented as total chlorinated dioxins
and total chlorinated furans.

       Reverberatorv Furnace #1

       A total of four tests was performed collecting samples simultaneously at the inlet and
outlet of the baghouse associated with furnace number 1. Each test was performed over the
duration of a batch cycle starting at the time of the first furnace charge and ending at the time of
the last tap out, a period ranging from approximately five and one-half hours to six and one-half
hours.  The same product was produced during each of the four tests. Each batch followed a
three stage process: charging, mixing and tap-out. Charging required approximately four hours
to complete, mixing one hour and tap-out one hour.  The highest emissions were observed during
the charging process (as observed from the real time FTIR data for HC1).  A "front-end loader"
Caterpillar tractor was used to charge feed stock or flux to the furnace approximately every ten
minutes during the charging stage. As each load was added emissions were  visible in the form of
clouds of black smoke/soot which were captured by an overhead hood and directed to the
baghouse.
                                          2-10

-------
Table 2-7. Chip Dryer, 2,3,7,8-TCDD Toxicity Equivalent Concentrations
Congener
2,3,7,8
TCDD
TEF1
ng/dscm
Run 1
Run 2
Run 3
Average
Inlet
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1.2,3,4,7,8-HxCDD
1,2,3,6,7.8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD

OCDD
Total PCDD
2.3,7,8-TCDF
1.2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF

1,2,3,6,7,8-HxCDF "
2,3,4.6,7,8-HxCDF
1,2,3,7,8.9-HxCDF
1.2,3.4,6,7,8-HpCDF

1,2,3,4,7,8.9-HpCDF

OCDF
Total PCDF
1.0
0.5
0.1
0.1
0.1
0.01
0.001

0.1
0.05
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.001

0.457
1.87
0.429
0.918
1.49
0.299
0.0247

1.43
0.506
9.18
2.21
1.35
1.88
0.114
0.288
0.0721
0.0113

0.536
1.53
0.365
0.670
1.19
0.212
0.0171

1.82
0.724
10.5
2.73
1.70
2.30
0.155
0.326
0.0856
0.0112

0.205
0.750
0.143
0.286
0.448
0.0960
0.00821

0.417
0.227
4.20
1.54
0.643
0.819
0.0357
0.185
0.0217
0.00414

0.399
1.39
0.312
0.624
1.04
0.202
0.0167
3.98
1.22
0.486
7.95
2.16
1.23
1.66
0.101
0.266
0.0598
0.00890
15.1
Outlet
2,3,7,8-TCDD
1,2.3,7,8-PeCDD
1,2,3,4,7,8-HxCDD

1,2,3,6.7,8-HxCDD
1, 2.3,7, 8.9-HxCDD

1.2,3,4,6,7,8-HpCDD
1.0
0.5
0.1
0.1
0.1
0.01
0.890
1.81
0.121
0.160
0.263
0.0192
0.461
1.09
0.0559
0.0888
0.125
0.00855
0.524
1.33
0.0839
0.115
0.175
0.00874
0.625
1.41
0.0869
0.121
0.188
0.0122
                                   2-11

-------
Table 2-7. (Continued)
Congener
OCDD
Total PCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1. 2.3.4,6.7. 8-HpCDF

1.2.3,4,7,8,9-HpCDF

OCDF
Total PCDF
2,3,7,8
TCDD
TEF1
0.001

0.1
0.05
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.001

ng/dscm
Runl
0.00114

1.76
0.94
12.1
1.53
0.701
0.438
0.0242
0.0416
0.00498
0.000605

Run 2
0.000493

0.862
0.538
7.22
0.954
0.421
0.273
0.0122
0.0237
0.00257
0.000270

Run 3
0.000455

0.993
0.656
8.90
1.23
0.573
0.332
0.0161
0.0287
0.00266
0.000255

Average
0.000696
2.44
1.20
. 0.710
9.40
1.24
0.565
0.348
0.0175
0.0313
0.00340
0.000377
13.5
'Toxicity Equivalence Factor

       Tables 2-8 and 2-9 present the concentration, in ng/dscm, of the selected D/F congeners
by run number, the average concentration over the three runs and the %RSD for the reverberatory
furnace No. 1 inlet and outlet, respectively.  These values were calculated by dividing the
reported analytical results, in ng, by the appropriate sample volume collected, in dscm, from
Table 2-2.  As indicated in Table 2-8 (furnace inlet) the concentration value of the
octachlorofuran in Run 2 is presented as a "greater than" value and should be considered an
estimate. The amount of this analyte detected in the sample extract exceeded the calibration
curve.
                                           2-12

-------
Table 2-8. Reverberatory Furnace #1, Inlet D/F Concentration, ng/dscm
Congener
2.3,7,8-TCDD
1,2,3,7,8-PeCDD
L2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD

1,2,3,7,8,9-HxCDD

1,2,3,4,6,7,8-HpCDD
OCDD
2.3,7,8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
1.2.3,4,7,8-HxCDF

1,2,3,6,7,8-HxCDF

2,3,4,6.7,8-HxCDF
1,2,3,7,8.9-HxCDF

1,2.3,4,6,7,8-HpCDF
1.2,3,4,7,8,9-HpCDF
OCDF
Runl
0.177
1.04
1.17
1.90

2.68

11.2
18.1
3.01
4.05
7.64
26.2

9.06

13.8
0.805

42.3
•6.44
37.4
Inlet
Run 2
0.191
1.34
1.45
2.18

3.20

14.9
23.4
4.33
4.22
8.58
26.6

9.54

14.5
0.833

53.8
9.27
177*
Run 3
0.156
0.872
0.949
1.46

2.13

8.44
12.1
2.69
3.54
6.10
18.7

6.64

9.87
0.641

27.4
4.38
20.4
Run 4
0.132
0.930
1.21
1.91 '

2.66

10.3
16.3
3.46
4.08
7.42
25.2

8.40

12.2
0.724

40.1
6.61
41.3
Average
0.164
1.05
1.20
1.86

2.67

11.2
17.5
3.37
3.97
7.43
24.2

8.41

12.6
0.751

40.9
6.68
68.9
%RSD
15.7
20.1
17.2
15.9

16.4

24.2
26.9
21.0
7.53
13.7
15.4

15.1

16.3
11.6

26.4
30.0
104.9
*Si«nal above calibration range
                                      2-13

-------
Table 2-9.  Reverberatory Furnace #1, Outlet D/F Concentration, ng/dscm
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD

1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1.2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4.7,8-HxCDF

1, 2,3.6 J,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Runl
0.00554*
0.0249
-0.0235
0.0374

0.0568
0.166
0.249
0.115
0.126
0.222
0.485

0.180
0.235
0.0125*
0.665
0.120
0.554
Outlet
Run 2
0.00284*
0.00711*
0.00284*
0.00569*

0.00853*
0.0228
0.0384
0.08 1 1
0.0413
0.0569
0.0768

0.0299
0.0327
0.00142*
0.0967
0.0156
0.171
Run 3
0.00576
0.00863*
0.00288*
0.00719*

0.00863*
0.0173
0.0230*
0.0993
0.0547
0.0734
0.0806

0.0302
0.0317
0.00144*
0.0590
0.00719*
0.0345
Run 4
0.00264*
0.00396*
0.00264*
0.00528*

0.00528*
0.0198
0.0317
0.0356
0.0198
0.0290 .
0.0580

0.0198
0.0264
0.00264*
0.0818
0.0106*
0.0607
Average
0.00419
0.0112
0.0080
0.0139

0.0198
0.0565
0.0856
0.0827
0.0604
0.0952
0.175

0.0650
0.0816
0.00449
.0.226
0.0385
0.205
%RSD
40.1
84.1
130
113

125
129
128
41.5
76.2
90.5
118

118
126
119
130
142
117
*Values below calibration curve and/or less than 5 x MDL; should be considered estimates
                                         2-14

-------
        The observed concentrations for the four runs at the inlet are generally of the same
 magnitude as indicated by the low %RSDs. Table 2-9 (furnace outlet) shows the concentrations
 to be considerably lower than those at the inlet by a factor of 10 to 100. Several of the analytes
 exhibited a concentration level below the calibration curve, less than 5 times the detection limit
 or not detected. These factors contribute to the high %RSD observed, not unusual in this
 situation.

        Table 2-10 shows the D/F stack emission rate from the furnace number 2 outlet in
 jnicrograms of analyte per megagram (ug/Mg) of feed stock for each of the four runs, the average
 and the %RSD. These values were calculated using standard conversion factors (i.e., pounds to
 grams), the concentrations given in Table 2-9, the stack flow rates given in Table 2-3 and the
 number of pounds of feed stock consumed during the test period as supplied by the facility.
 Although the feed stock was added only during the first four hours of each batch, the feed rate
 was calculated using the total pounds consumed divided by the length of the total batch process.
 This calculation process was necessary to correspond with the emissions collected  by the
 integrated sample over the duration of the entire batch process including charging,  mixing and
 tap-out. The latter data set (pounds of feed stock consumed) for each of the four runs is given
 below:
    Run No.
        1
       2
       3
       4
Lot
	    Batch Time-Date
 1     6 hrs-12/8/97
 2     6.5 hrs-12/9/97
 3     5.75 hrs-12/10/97
 4     6.5 hrs-12/11/98
Feed Consumed. Ibs.
      70,200
      70,200
      75,600
      81,000
Feed Rate. lbs./hr
     11,700
     10,800
     13,148
     12,462
       Table 2-11 shows the congener concentrations in ng/dscm converted to 2,3,7,8-TCDD
toxicity equivalents  as well as a summation of the values presented as total chlorinated dioxins
and total chlorinated furans.
                                           2-15

-------
Table 2-10. Reverberatory Furnace #1, Outlet D/F Emission Rate, ug/Mg Feed
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD

1,2,3,6,7,8-HxCDD

1,2,3,7,8,9-HxCDD
1, 2,3,4,6,7, 8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4.7.8-HxCDF

1,2,3,6,7,8-HxCDF

2,3,4,6,7,8-HxCDF

1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1. 2,3.4,7. 8,9-HpCDF

OCDF
Runl
0.0505
0.227
0.215

0.341

0.518
1.52
2.27
1.05
1.15
2.02
4.42

1.64

2.15

0.114
6.06
1.10

5.05
Outlet
Run 2
0.0256
0.0648
0.0259

0.0519

0.0778
0.207
0.350
0.739
0.376
0.519
0.700

0.272

0.298

0.0130
0.882
0.143

1.56
Run 3
0.0433
0.0649
0.0216

0.0541

0.0649
0.130
0.173
0.746
0.411
0.552
0.606

0.227 .

0.238

0.0108
0.444
0.0541

0.260
Run 4
0.0202
0.0303
0.0202

0.0404

0.0404
0.152
0.242
0.273
0.152
0.222
0.444

0.152

0.202

0.0202
0.626
0.0808

0.465
Average
0.0349
0.0968
0.0706

0.122

0.175
0.501
0.760
0.702
0.522
0.828
1.54

0.573

0.721

0.0394
2.00
0.344

1.83
%RSD
41.0
91.4
136

120

131
135
133
45.6
83.1
97.6
125

125

132

126
135
147

121
                                  2-16

-------
Table 2-1.1. Reverberatory Furnace #1, 2,3,7,8-TCDD Toxicity Equivalent
Concentrations

Congener
Inlet
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1, 2,3,4.7, 8-HxCDD

1,2,3,6,7.8-HxCDD
1,2,3,7,8.9-HxCDD

1,2,3,4,6.7,8-HpCDD

OCDD
Total PCDD
2.3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7, 8-PeCDF
1,2,3,4,7.8-HxCDF
1,2,3, 6.7. 8-HxCDF
2.3,4.6.7,8-HxCDF
1, 2,3,7, 8.9-HxCDF

1. 2,3.4.6,7, 8-HpCDF
1.2,3.4.7,8.9-HpCDF
OCDF
Total PCDF
Outlet
2,3,7,8-TCDD
1.2.3,7,8-PeCDD
1,2,3.4,7.8-HxCDD

1,2,3,6.7,8-HxCDD
1, 2,3.7. 8,9-HxCDD

2,3,7,8-
1(_L)L>
TEF'

1.0
0.5
0.1

0.1
0.1

0.01

0.001

0.1
0.05
0.5
0.1
0.1
0.1
0.1

0.01
0.01
0.00 1


1.0
0.5
0.1

O.I
0 1


Run 1

0.177
0.519
0.117

0.190
0.268

0.112

0.0181

0.301
0.203
3.82
2.62
0.906
1.38
0.0805

0.423
0.0644
0.0374


0.00554
0.0125
0.00235

0.00374
0 00568


Run 2

0.191
0.672
0.145

0.218
0.320

0.149

0.0234

0.433
0.211
4.29
2.66
0.954
1.45
0.0833

0.538
0.0927
0.177


0.00284
0.00356
0 000284

0.000569
0 000853

ng/dscm
Run 3

0.156
0.436
0.095

0.146
0.213

0.084

0.0121

0.269
0.177
3.05
1.87
0.664
0.987
0.0641

0.274
0.0438
0.0204


0.00576
0.00432
0 000^88

0.000719
0 000863


Run 4

0.132
0.465
0.121

0.191
0.266

0.103

0.0163

0.346
0.204
3.71
2.52
0.840
1.22
0.0724

0.401
0.0661
0.0413


0.00264
0.00198
0 000264

0.000528
0 000528


Average

0.164
0.523
0.120

0.186
0.267

0.112

0.0175
1.39
0.337
0.199
3.72
2.42
0.841
1.26
0.075 1

0.409
0.0668
0.0689
9.39

0.00419
0.00558
0 000798

0.00139
0 00198

                                    2-17

-------
 Table 2-11.  (Continued)

Congener
1,2,3,4,6,7,8-HpCDD

OCDD
Total PCDD
2,3,7.8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7, 8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF

2,3,4,6,7,8-HxCDF

1, 2,3.7, 8,9-HxCDF
1,2,3,4,6,7,8-HpCDF

1.2,3,4,7,8.9-HpCDF

OCDF
Total PCDF
2,3,7,8-
T/T\rfc
1CUU
TEF1
0.01

0.001

0.1
0.05
0.5
0.1
0.1

0.1

0.1
0.01

0.01

0.001


Run 1
0.00166

0.000249

0.0115
0.00630
0.111
0.0485
0.0180

0.0235

0.00125
0.00665

0.00120

0.000554


Run 2
0.000228

0.000038

0.00811
0.00206
0.0284
0.00768
0.00299

0.00327

0.000142
0.000967

0.000156

0.000171

ng/dscm
Run 3
0.000173

0.000023

0100993
0.00273
0.0367
0.00806
0.00302

0.003' 17

0.000144
0.000590

0.000072

0.000035


Run 4
0.000198

0.000032

0.00356
0.000989
0.0145
0.00580
0.00198

0.00264

0.000264
0.000818

0.000106

0.000061


Average
0.000565

0.0000856
0.0146
0.00827
0.00302
0.0476
0.0175
0.00650

0.00816

0.000449
0.00226

0.000385

0.000205
0.0944
'Toxicity Equivalence Factor

2.3    HCI Results

2.3.7  Overview

       Three 4-hour HC1/C1-, tests were performed at the inlet and outlet of the baghouse
associated with the chip dryer operation (total of 6) and four 6-feour tests were performed at the
inlet and outlet of the baghouse associated with the reverberatory furnace number 1 (total of 8).
The sampling and analysis procedures followed EPA Method 26A protocol  Prior to testing, the
plant personnel replaced all fabric filters in the baghouse with new ones and performed the
appropriate leak checks.  All analyses were performed by ion chromatography using the samples
as received from the field.  Any compound that was not detected is reported as a "less than"
                                         2-18

-------
 value with this value being the instrument detection limit.  A "less than" value rather than a "0" is
 used in all appropriate calculations.  All HC1/C1, raw data can be found in Appendix C of this
 report.

 2.3.2   HCI Emission Results

        Chip Dryer

       The baghouse associated with the chip dryer is injected with lime (hydrated calcium
 hydroxide) for the purpose of reducing HCI emissions.  The reaction between the two compounds
 forms calcium chloride and water. The lime injection to the baghouse was continuous at a feed
 rate of approximately 50 pounds per hour. Table 2-12 gives the concentration, in micrograms per
 dry standard cubic meters (^g/dscm), the average concentration over the three runs and the
 %RSD for the inlet and outlet, respectively.  The results for Run 3  inlet are invalid as the sample
 was compromised during sample recovery in the field.  Chlorine was not detected (at the
 instrument detection  limit) in  any samples at either the inlet or the outlet. The HCI results for
 Runs 1 and 2 inlet and Runs 1 and 2 outlet are very consistent among themselves with the outlet
 concentrations representing about 3% of the amount entering the baghouse.   Table 2-13 gives the
 concentrations in parts per million (ppm) in order to provide an easy comparison to the FTIR
 results which are also presented in ppm and provided in Section 2.5 of this report.

       The emission rate of HC1/C12, in pounds/hour (Ibs/hr), was calculated using the
 concentration results  from Table 2-12 and the stack flow rate data from Table 2-3 and is
 presented in Table 2-14. Using the average emission rates calculated for the inlet and the outlet,
 a baghouse percent removal efficiency for HCI was determined to be 96.9%, as shown in
Table 2-15. The emission rate of HC1/CU was also determined as pounds per ton of feed stock
using the data given in Table 2-14 and the feed stock feed rates for  the chip dryer given in
Section 2.2.2  above.  These results are given in Table 2-16.
                                          2-19

-------
Table 2-12.  HCI and CI2 Concentration, |jg/dscm
Location
Chip Dryer Inlet1

Chip Dryer Outlet

Furnace 1 Inlet

Furnace 1 Outlet

Parameter
HCI
Cl,
HCI
Cl,
HCI
Cl,
HCI
Cl,
Runl
43704
<191
1367
<123
119887
188*
689
<66.2
Run 2
37254
<198
1899
<137
119768
4305
764
129*
Run 3
6102
<179
202
<168
66034
783
2379
<62.4
Run 4
NA
NA
NA
NA
109455
231*
1262
<45.6
*Less than 5 x MDL
'Run 3 compromised during sample recovery
Table 2-13. HCI and CI2 Concentration, ppm
Location
Chip Dryer Inlet1

Chip Dryer Outlet

Furnace 1 Inlet

Furnace 1 Outlet

Parameter
HCI
Cl:
HCI
C!2
HCI
Cl,
HCI
Cl,
Runl
29.6
<0.067
0.927
<0.043
81.3
0.066*
0.467
<0.023
Run 2
25.3
<0.069
1.288
<0.048
81.2
1.50
0.518
0.045*
Run 3
4.14
0.062
0.137
<0.058
44.8
0.273
1.61
<0.022
Run 4
NA
NA
NA
NA
74.2
0.081*
0.856
<0.016
*Less than 5 x MDL
'Run 3 compromised during sample recovery
                                    2-20

-------
Table 2-14.  HCI and Cl, Emission Rate, Ibs/hour
Location
Chip Dryer Inlet'

Chip Dryer Outlet

Furnace 1 Inlet

Furnace 1 Outlet

Parameter
HCI
C12
HCI
C12
HCI
C12
HCI
Cl,
Runl
0.820
<0.00359
0.0276
<0.00249
11.4
0.0179*
0.0760
<0.00731
Run 2
0.798
<0.00423
0.0429
<0.00310
10.5
0.379
0.0760
0.0128*
Run 3
0.115
<0.00338
0.00424
<0.00352
5.88
0.0698
0.227
<0.00596
Run 4
NA2
NA
NA
NA
8.38
0.0177*
0.112
<0.00407
Average
0.809
0.00391
0.0249
0.00304
9.05
0.121
0.123
0.00754
%RSD
NA
NA
78.1
17.1
27.3
143.4
58.3
50.0
*Less than 5 x MDL; should be considered an estimate
'Run 3 compromised during sample collection; Runs 1 and 2 used to calculate average
2NA=Not Applicable
Table 2-15. HCI Removal Efficiency
Location
Chip Dryer
Furnace #1, Cond. l'
Furnace #l,Cond. 22
Average Emission Rate, Ibs/hour
Inlet
0.809
10.97
7.13
Outlet
0.0249
0.0760
0.170
Removal
Efficiency, %3
96.9
99.3
97.6
Condition 1 = continuous lime feed, Runs 1 and 2
Condition 2 = 50 Ibs. lime every 2 hours, Runs 3 and 4
'Average of runs 1 and 2
2Average of runs 3 and 4
3Removal Efficiency = (inlet-outlet/inlet) x 100
                                       2-21

-------
Table 2-16. HCI and CI2 Emission Rate, Ibs/Ton of Feed
Location
Chip Dryer Inlet'

Chip Dryer Outlet

-urnace 1 Inlet

Furnace 1 Outlet

Parameter
HCI
C12
HCI
C12
HCI
C12
HCI
Clr
Runl
0.410
0.00180
0.0138
0.00124
1.95
0.00305
0.0130
0.00125
Run 2
0.814
0.00432
0.0438
0.00317
1.95
0.0702
0.0141
0.00238
Run 3
0.0759
0.00222
0.00279
0.00232
0.895
0.0106
0.0346
0.000908
Run 4
NA2
• NA
NA
NA
1.34
0.00284
0.0180
0.000653
Average
0.612
0.00306
0.0201
0.00224
1.54
0.0217
0.0199
0.00130
%RSD
NA
NA
105
42.9
33.5
150
50.3
58.7
'Run 3 compromised during sample collection, Runs 1 and 2 used to calculate average
2NA, Not Applicable

       Reverberatorv Furnace Number 1

       The results for the reverberatory furnace #1 are given in Tables 2-12 through 2-16
following the same sequence as the chip dryer.  During Test Runs 1 and 2, lime was fed
continuously to the baghouse (Condition 1). During Test Runs 3 and 4, lime was added to the
lime feed hopper at the rate of one 50 Ib bag every two hours (Condition 2). Lime was consumed
at the rate of approximately 50 pounds per 30 minutes during the test period.  The concentration
results  presented in Tables 2-12 and 2-13 for HCI for Runs 1 and 2 are consistent among
themselves for both the inlet and outlet.  Run 4 inlet results were consistent with Runs 1 and 2.
However, the outlet results were approximately a factor of 2 higher than for Runs 1 and 2. The
fact that one of the four baghouse modules (module 4) had developed a leak and was off-line
could be a possible explanation for this observation.  The Run 3 inlet HCI concentration was
observed to be approximately half that for the other runs, possibly because furnace C12 flow
supply  was not turned on until at least an hour into the test.
                                         2-22

-------
       The baghouse removal efficiency for HC1 was determined for Condition  1 using the
average of the emission rate results from Runs 1 and 2 and for Condition 2 using the average of
Runs 3 and 4.  The results are presented in Table 2-15. The removal efficiency for Condition 2
was slightly less than that for Condition 1, with both well above 95%. The emission rate of
HC1/C12 was also determined as pounds per ton of feed stock using the data given in Table 2-14
and the feed stock feed rates for the furnace given  in Section 2.2.2, above.  These results are
given in Table 2-16.

2.4   Participate Results

2.4.7  Overview

       Paniculate matter emissions were determined from the same sampling trains used for the
determination of HC1 emissions.  PM collected on the filter and in the front half acetone rinse
(nozzle, probe, front-half filter holder) was analyzed gravimetrically.  PM stack concentrations in
grains per dry standard cubic meter (gr/dscm), PM emission rate in pounds  per ton of feed
(Ibs/Ton) and pounds per hour (Ibs/Hr), and the PM removal efficiency of each baghouse as a
percent (%) for the chip dryer and furnace number 1 operations are presented below.  The results
of the PM testing are  presented in Tables 2-17 through 2-20.  All  raw  data for the PM
determinations can be found in  Appendix D.

2.4.2  Particulate Emission Results

       Chip Dryer

      Table 2-17 gives the concentration, in gr/dscm, the average concentration over the three
runs and the %RSD for the inlet and outlet.  The average of the three runs was 20.3 and 0.778 for
the inlet and outlet, respectively.
                                          2-23

-------
Table 2-17. Stack Gas Particulate Matter Concentration, gr/dscm
Baghouse Location
Chip Dryer Inlet
Chip Dryer Outlet
:urnace 1 Inlet
nirnace 1 Outlet
gr/dscm
Runl
27.8
2.07
7.33
0.142
Run 2
19.3
0.529
5.06
0.0242
Run 3
13.9
1.10
3.21
0.0103
Run 4
NA
NA
3.86
0.00599
Average
20.3
1.23
4.86
0.0455
%RSD
34.5
63.2
37.3
142
Table 2-18. Particulate Matter Emission Rate, Ibs/hour
Baghouse Location
Chip Dryer Inlet
Chip Dryer Outlet
Furnace 1 Inlet
-urnace 1 Outlet
Ibs/hour
Runl
33.8
2.71
45.2
1.01
Run 2
26.8
0.775
28.9
0.156
Run 3
17.0
1.49
18.5
0.0637
Run 4
NA
NA
19.1
0.0346
Average
25.9
1.66
27.9
0.317
%RSD
32.6
59.0
44.6
147
Table 2-19. Baghouse Particulate Removal Efficiency,%
Location
Chip Dryer Baghouse
:urnace 1 Baahouse
Ibs/hr
Avg. Inlet
Rate
25.9
27.9
Avg. Outlet
Rate
1.66
0.317
Removal
Efficiency %
93.6
98.9
                                    2-24

-------
 Table 2-20.  Particulate Matter Emission Rate, Ibs/Ton of Feed
Baghouse Location
Chip Dryer Inlet
Chip Dryer Outlet
*urnace 1 Inlet
•urnace 1 Outlet
Ibs/ton of Feed
Run 1
16.9
1.35
7.73
0.173
Run 2
27.3
0.791
5.35
0.0289
Run 3
11.190
0.982
2.82
0.00970
Run 4
NA
NA
3.07
0.00555
Average
18.5
1.04
4.74
0.0543
%RSD
44.3
27.5
48.3
147
       The emission rate of PM, in Ibs/hr, was calculated using the concentration results from
Table 2-17 and the stack flow rate data from Table 2-3 and is presented in Table 2-18. Using the
average emission rates calculated for the inlet and the outlet, a baghouse percent removal
efficiency for PM was determined to be 93.6%, as shown in Table 2-19. The emission rate of
PM was also determined as pounds per ton of feed stock using the data given in Table 2-18 and
the feed stock feed rates for the chip dryer given in Section 2.2.2 above.   These results are given
in Table 2-20.

       Reverberatorv Furnace Number 1

       Table 2-17 gives the concentration, in gr/dscm, the average concentration over the four
runs and the %RSD for the inlet and outlet. The average of the four runs was 4.68 and 0.0455 for
the inlet and outlet respectively.  The inlet PM concentrations for Runs 1 and 2 (condition 1) are
noticeably higher than for Runs 3 and 4 (condition 2), possibly due to the lower lime injection
rate that occurred during Runs 3 and 4.  The high variability between the outlet results is due to
the low mass of PM present on the filters. Values near the limit of detection have inherent
increased variability.

       The emission rate of PM, in Ibs/hr, was calculated using the concentration results from
Table 2-17 and the stack flow rate data from Table 2-3 and is presented in Table 2-18. Using the
                                          2-25

-------
 average emission rates calculated for the inlet and the outlet, a baghouse percent removal
 efficiency for PM was determined to be 98.9%, as shown in Table 2-19. The emission rate of
 PM was also determined as pounds per ton of feed stock using the data given in Table 2-18 and
 the feed stock feed rates for furnace number 2 given in Section 2.2.2 above.  These results are
 given in Table 2-20.

 2.5    FTIR Results

 2.5.1   Overview

        FTIR data for HCl and other species were collected at the inlet and outlet of the
.baghouses associated with the chip dryer and reverberatory furnace 1.  FTIR data collection was
 synchronized with manual HCl and dioxin/furan testing to allow semi-quantitative comparison of
 the FTIR and manual HCl results. Due to partitioning of FTIR analysis time  between
 unconditioned and conditioned inlet/outlet samples, only 25% of FTIR data during a given run on
 the chip dryer and 38% on the furnace were collected simultaneously with the corresponding
 inlet or outlet manual train sampling.

       FTIR data were collected at each location by alternating sample analysis between inlet
 and outlet every 10 minutes. Both inlet and outlet sampling systems continuously withdrew
 sample  from their respective location. Each 10 minute measurement period contained ten 1
 minute average data points. The first two data points  from each period were discarded to
 eliminate data for samples containing both inlet and outlet sample  gas.  Two  data points
 correspond to the  measured response time of the complete FTIR sampling and analysis system
 (see below for details on measurement of system response time) A 1 minute average data point
 is generated  by analysis of a composite spectrum consisting of an average of 43  FTIR spectra
 collected over the 1 minute time period.

       Section 2.1 gives the schedule of the tests performed at the Gulp facility.  Both
unconditioned samples and conditioned samples were analyzed. Conditioned samples were

                                          2-26

-------
 generated by passing the raw sample gas through a water vapor/carbon dioxide scrubbing system
 (See Section 5.3 for details). Unconditioned and conditioned samples extracted from the chip
 dryer baghouse were measured during the first and last two-hour periods for each four hour run,
 respectively. At the reverberatory furnace #1, the sampling order went as follows: 2 hours
 unconditioned, 1 hour conditioned, and 2 hours unconditioned.  Two unattended unconditioned
 overnight runs were also conducted to look continuously at reverberatory furnace #1 hood
 baghouse outlet emissions. Those results are reported in Section 2.5.2.2.

       Baghouse removal efficiency for HC1 was measured from the inlet/outlet data from each
 location and is reported in Section 2.5.2.2.  Optimization of the reverberatory furnace 1 baghouse
 for HC1 removal was also carried out.  The removal efficiency was found to exceed 90% for all
 tests at all lime injection rates tested.

       EPA Method 301 validation tests for HC1 were carried out on the chip dryer baghouse
 outlet, and reverberatory furnace #1 baghouse inlet and outlet. In all three tests, the Method 301
 statistical calculations showed that the FTIR method demonstrated acceptable precision and no
 statistically significant bias for HC1.  Details of the validation results can be found in
 Section 2.5.2.1.

       A comparison of the FTIR and Method 26A results for both the chip dryer and furnace
 tests are presented in Section 2.5.2.6

 2.5.2  FTIR Emission Results

      This section contains the FTIR EPA Method 301 HC1 validation results, HC1 test results,
 and screening results for the chip dryer and reverberatory furnace #1 hood baghouse inlet and
outlet. Also included are results for the reverberatory furnace #1 hood baghouse HC1 removal
efficiency optimization tests.
                                          2-27

-------
 2.5.2.1  EPA Method 301 FTIR Validation Results for HCI

       EPA Method 301 validation testing for HCI was performed on the chip dryer outlet, and
 reverberatory furnace #1 hood inlet/outlet. The spiking procedure is given in Section 5.3.2. Five-
 minute measurement periods were used for the chip dryer outlet, while 1-minute measurement
 periods for both inlet and outlet of the reverberatory furnace #1 were used. The 1-minute periods
 were used because of the rapidly fluctuating nature of the furnace emissions. Table 2-21
 summarizes the validation results.

 Table 2-21.  Summary of EPA Method 301 FTIR Validation Results for HCI
Location
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
Date
12/03/97
12/07/97
12/07/97
Spiked/Unspiked
Precision
Acceptable?
Yes/Yes
Yes/Yes
Yes/Yes
Statistically
Significant
Bias?
No
No
No
Note: Acceptable precision is equal to or less than 50% RSD.

Detailed results of the validation testing can be found in Appendix E.

2.5.2.2 FTIR HCI Test Results

       The estimated FTIR HCI detection limit for this study is 0.05 ppmv.

       While it is instructive to compare HCI results from both FTIR and manual methods, care
must be taken in interpreting the two sets of results. The FTIR system measured HCI at a given
inlet or outlet only 25 % of the time; the corresponding manual method was integrated over the
entire sampling period. Half of the FTIR instrument analysis time was split equally between inlet
and outlet as unconditioned and conditioned samples.  Since HCI was measured only in
                                         2-28

-------
unconditioned samples, this sampling scheme results in a 25% duty cycle for the total run for
HC1 measurement at a given inlet or outlet.  The potential difference between FTIR and manual
results will increase with greater fluctuations in the HC1 concentration during the run, since the
FTIR captures 25% of the manual method sample for a given inlet or outlet run. Greatest
fluctuation in HG1 was observed during charging operations on the furnace #1 inlet to the
baghouse.

       Results given below are organized by location. HC1 removal efficiency was also
calculated for each run.

       Chip Dryer Baghouse Outlet/Inlet HC1 Results—Table 2-22 gives a summary of the
chip dryer baghouse outlet/inlet FTIR HC1 results.  The average inlet concentrations were
consistent between runs, but the outlet concentrations varied by a factor of 10.

       During Run  1, a large slug of particulate matter filled the FTIR inlet heated filter
assembly which prevented sampling of the inlet gas. The FTIR system was allowed to measure
the outlet while the inlet filter system was cleaned; thirty more data points  were therefore
measured on the outlet versus the inlet.  These extra 30 data points were reported in the
preliminary data, but they are not included in the results presented in Table 2-22.  The removal of
the extra 30  data points does not cause any significant changes in the Run 1 results, however.

       Reverberatory Furnace 1 Baghouse Outlet/Inlet HC1 Results—Table 2-23 gives the
FTIR HC1 results for the reverberatory furnace baghouse inlet and outlet during charging of the
furnace with scrap aluminum. Table 2-24 shows the FTIR HC1 results for the reverberatory
furnace #1 hood baghouse inlet and outlet during tapping operations. In all cases, HC1 removal
efficiency due to the lime-injected baghouse was greater than 90 percent.
                                          2-29

-------
 Table 2-22. Chip Dryer FTIR HCI Results, ppmv

Date
Time
Location
Average
SD
Maximum
Minimum
NDP
RE
Runl
12/05/97
0800 - 0900
0930 - 1130
inlet
8.91
6.42
22.89
2.11
72
outlet
0.65
0.54
2.54
0.10
72
92.7
Run 2
12/06/97
0835 - 1040
inlet
8.25
11.67
52.05
1.22
48
outlet
5.30
4.17
19.28
1.16
48
35.8
Run 3
12/06/97
1546 - 1746
inlet
6.79
4.44
20.40
0.77
48
outlet
2.42
2.72
13.37
0.86
48
64.4
SD - Standard Deviation
NDP - Number of data points measured
RE-  Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet

Table 2-23. Reverberatory Furnace #1 Baghouse FTIR HCI Results During
Charging, ppmv

Date
Time
Location
Average
SD
Maximum
Minimum
NDP
RE
Run 1
12/08/97
945 - 1200
inlet
136.94
145.00
645.4
9.80
51
outlet
5.20
4.80
21.50
0.73
56
96.2
Run 2
12/09/97
1220-1420
inlet
58.48
122.37
756.72
7.59
48
outlet
2.72
1.15
6.76
1.14
48
95.3
Run 3
12/10/97
1114-1334
inlet
42.27
71.67
330.79
4.07
56
outlet
3.64
1.65
9.40
1.59
56
91.4
Run 4
12/11/97
0618 - 0848
inlet
132.42
159.55
634.60
12.25
64
outlet
4.57
3.46
14.39
1.36
56
96.6
SD - Standard Deviation
NDP - Number of data points measured
RE-Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
                                      2-30

-------
 Table 2-24. Reverberatory Furnace #1  Baghouse FTIR HCI Results During
 Tapping, ppmv

Date
Time
Location
Average
SD
Maximum
Minimum
NDP
RE
Runl
12/08/97

inlet
57.95
19.84
89.16
.13.83
56
outlet
2.17
0.66
3.85
1.30
64
96.3
Run 2
12/09/97
1555 - 1825
inlet
54.54
34.67
155.58
0.93
64
outlet
1.96
0.68
3.85
1.06
56
96.4
Run 3
12/10/97
1430 - 1710
inlet
46.84
21.47
84.51
2.27
64
outlet
1.59
0.48
3.07
0.94
64
96.6
Run 4
12/11/97
0958 - 1258
inlet
41.09
15.57
63.45
0.94
72
outlet
1.58
0.58
3.59
0.72
72
96.2
SD - Standard deviation
NDP - Number of data points measured
RE-Removal Efficiency percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet

       Tables 2-23 and 2-24 clearly show that the respective inlet and outlet concentrations
during charging are somewhat higher on average than during tapping.  This result is expected,
due to the nature of the loading process, where hydrocarbons from oils coated on the charge
material provide  the source of hydrogen for HCI production.  Tapping operations do not involve
the addition of any material to the furnace, so the HCI levels would be expected to be lower.

       Further examination of the data shows that the standard deviation of HCI inlet and outlet
levels during loading is significantly higher than during tapping. This variation stems from the
greater variation  in the HCI emissions during loading due to the periodic addition of hydrocarbon
material to the furnace. During tapping operations, the furnace is not charged, and less  variation
is expected.

       Tables 2-25 and 2-26  are the combined loading and tapping results and a grand average of
all 4 runs, respectively. The combined results were generated by an average of the respective
                                         2-31

-------
 Table 2-25. Combined Charging and Tapping Reverberatory Furnace #1
 Baghouse FTIR HCI Results, ppmv

Date
Location
Average
RE
Run 1
12/08/97
Inlet
95.60
Outlet
3.58
96.25
Run 2
12/09/97
Inlet
56.23
Outlet
2.31
95.89
Run 3
12/10/97
Inlet
44.71
Outlet
2.55
94.30
Run 4
12/11/97
Inlet
84.07
Outlet
2.89
96.56
 RE- Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
Table 2-26.  Reverberatory Furnace #1 Baghouse FTIR HCI Results -
Grand Average, ppmv
Location
Average
RE
Inlet
70.15
Outlet
2.83
95.96
RE- Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet

data in Tables 2-23 and 2-24 weighted by the number of sample points. Computation of the
grand average was a simple unweighted average of the 4 runs.

      Table 2-27 gives the FTIR HCI results of the unconditional reverberatory furnace 1
baghouse outlet during two overnight periods.. Five minute averages were collected for each data
point, instead of the usual 1 minute average collected in all other tests.

2.5.2.3  FTIR Process Optimization

      The reverberatory furnace #1 hood baghouse HCI destruction efficiencies were measured
as a function of lime injection rate. Examination of Table 2-23 shows there is no apparent effect
of lime injection rate on the measured removal efficiency. Runs  1 and 2 utilized a continuous
lime injection  at a rate of 50 Ibs per half hour.  Runs 3 and 4 examined the emissions during a
lime
                                        2-32

-------
 Table 2-27. Reverberatory Furnace #1 Hood Baghouse Outlet HCI Results
 Overnight, ppmv

Date
Time
Location
Average
Standard
Deviation
Maximum
Minimum
Number of
Data Points
Runl
12/(09-10)/97
1947 - 1015
Outlet
0.40
0.44
2.09
0.00
174
Run 2
12/(10-ll)/97
1815-0415
Outlet
0.45
0.48
2.60
0.00
120
injection rate of 50 Ibs per half hour period with 50 Ib being added every 2 hours.  In all cases,
90+ percent HCI removal efficiency was obtained.

2.5.2.4 FTIR Screening  Results

       Screening data for species other than HCI were collected concurrently with the HCI data.
FTIR spectral data were examined for any other species present in the samples.  Conditioned
samples were measured to estimate concentrations of aromatic and some hydrocarbon species.
Unconditioned samples were analyzed for other hydrocarbon and criteria species.

       Tables 2-28 and 2-29 give summary statistics on the dominant species detected besides
HCI for the chip dryer inlet and outlet, respectively. Tables 2-30 and 2-31 are the screening
results  for the furnace  1 inlet and outlet, respectively.  In addition to  HAP species, non-HAP
species are also reported to aid in understanding of the process chemistry, if desired.
                                         2-33

-------
       Table 2-28. Other Species Detected by FTIR - Chip Dryer Inlet

2
1
2


u/c
Average
Std.
Dev.
Max.
Min.
NDP
EDL

8
0>
W

c
5.97
4.25

17.15
<0.2
144
0.2


•*•*


C
0.86
0.60

2.03
0.11
144
0.05

V
g
i
u
CO

C
0.74
0.47

1.87
<0.1
144
O.I
•
g
.c
Ol
s

C
3.51
4.00

18.46
<0.2
144
0.2
u
•a
j;
2
u
0
ta.
U
3.12
8.63

59.64
0.25
168
0.1
u
•a
JS
ai
•d
2
u
"*'•
U
2.49
9.77

56.14
<0.5
168
0.5

'£-
O
(J

U
1.66
0.39

2.48
0.04
168
0.04


0
U


U
184.47
90.81

391.87
49.14
168
0.08


0


U
13.22
4.52

23.95
<3.5
168
3.5


O
z


u
4.16
4.67

14.63
<0.8
168
0.8


33
U


•U
12.08
16.15

125.62
4.45
168
2.0


q,


u
4.53
1.94

10.32
<0.8
168
0.8
+'
(j



U
1.99
5.81

33.32
<0.1
168
O.I
^
•— •
O
£


U
6.86
1.65

10.44
3.18
168
0.0001
to
       All values are estimated ppmv, except CO2 and H2O in percent
       Statistics of three runs combined
       U/C - Unconditioned (U) or Conditioned (C) Sample
       C4+  - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
       NDP - Number of data points
       EDL - Estimated detection limit for spectral region used for analysis

-------
       Table 2-29. Other Species Detected by FTIR - Chip Dryer Outlet
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ethylene
C
5.99
4.05
17.50
0.42
142
0.2
Acetylene
C
0.87
0.59
2.19
0.09
142
0.05
Benzene
C
0.76
0.48
2.06
<0.1
142
0.1
Methanol
C
3.45
4.59
20.84
<0.2
142
0.2
Formaldehyde
U
1.35
0.76
4.65
0.37
198
O.I
Acetaldehyde
U
0.49
0.62
4.39
<0.5
198
0.5
2
6'
u
u
1.64
0.27
2.35
0.89
198
0.04
O
U
u
174.31
84.61
355.41
8.41
198
0.08
O
z
u
14.49
3.09
22.53
8.37
198
3.5
ft
o
z
u
1.17
2:23
8.06
<0.8
198
0.8
af
u
u
8.16
3.07
19.37
<2.0
198
2.0
O
r«
Z
U
4.30
1.69
9.01
<0.8
198
0.8
+
U
U
0.96
1.47
11.50
<0.1
198
0.1
8
o
r»
U
6.73
1.71
10.17
2.97
198
0.0001
10
       All values are estimated ppmv, except CO2 and H2O in percent
       Statistics of three runs combined
       U/C - Unconditioned (U) or Conditioned (C) Sample
       C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
       NDP - Number of data points
       EDL - Estimated detection limit lor spectral region used for analysis

-------
       Table 2-30a. Other Species Detected by FTIR - Reverberatory Furnace #1  Inlet
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ethylene
C
2.16
3.34
17.17
<0.2
104
0.2
Acetylene
C
4.08
7.74
39.16
<0.05
104
0.05
Benzene
C
1.73
2.87
12.48
<0.1
104
0.1
Methanol
C
0.48
0.62
3.76
<0.2
104
0.2
Formaldehyde
U
0.46
1.10
9.66
<0.1
473
O.I
Acetaldehyde
U
0.05
0.39
6.79
<.5
473
0.5
S
«•»
O
U
U
0.14
0.23
1.96
<0.04
473
0.04
O
u
u
45.01
73.88
425.92
1.76
473
0.08
O
Z
U
2.18
5.77
48.90
<2.0
473
2.0
1,3 - butadiene
C
0.17
0.64
6.01
<0.8
104
0.8
SB
U
U
12.25
12.49
91.75
<2.0
473
2.0
O
ft
Z
U
0.84
0.57
5.92
<0.3
473
0.3
+
U
U
0.61
0.80
15.02
<0.1
473
0.1
S
O
»•»
SB
U
1.43
0.59
4.58
0.49
473
0.0001
O\
       All values are estimated ppmv, except CO2 and H2O in percent
       Statistics of four runs during loading and tapping combined
       U/C - Unconditioned (U) or Conditioned (C) Sample
       .C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
       NDP - Number of data points
       EDL - Estimated detection limit for spectral region used for analysis

-------
      Table 2-30b. Other Species Detected by FTIR - Reverberatory Furnace #1 Inlet, continued
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ammonia
U
0.04
O.I6
3. 15
<0.1
473
0.1
Propylene
C
0.39
1.63
16.01
<0.4
104
0.4
Sulfur dioxide
U
6.10
10.79
74.85
<1.2
473
1.2
to
OJ
-J
      All values are estimated ppmv
      Statistics of four runs during loading and tapping combined
      U/C - Unconditioned (U) or Conditioned (C) Sample
      NDP - Number of data points
      EDL - Estimated detection limit for spectral region used for analysis

-------
       Table 2-31 a. Other Species Detected by FTIR - Reverberatory Furnace #1 Outlet


L.
Ol
2
K)
Ou
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL


Ol
Ol
W

C
2.51
3.00
13.50
<0.2
88
0.2


Ol
Ol
t
^ji

C
4.82
7.44
31.31
<0.05
88
0.05


Ol
Ol
N
Ol
ca

C
1.58
2.30
9.57
<0.l
88
O.I


o
a
^

C
0.49
0.64
2.24
<0.2
88
0.2
Ol
•a

01
2
g
o
U
0.32
0.37
2.71
<0.l
477
O.I


;*,
01
2
Ol

U
0.15
1.46
31.26
<0.4
477
0.5


/— S
6*
o

u
0.13
0.18
1.20
<0.04
477
0.04



O
U


U
46.34
71.04
385.37
0.99
477
0.06



O
z


u
1.83
4.11
24.72
<2.0
477
0.8
01
C
Ol
•a .
3
s
i
rf)
C
0.15
0.50
3.03
<0.6
88
0.6



X
U


u
11.14
9.70
86.53
<0.6
477
2.0



O,
z'


U
0.82
0.49
4.08
<0.1
477
0.1


U



U
0.52
0.64
13.07
<0.04
477
0.04
, — .
^
•-^
0
3G


U
1.44
0.65
3.84
0.42
477
0.0001
NJ
i
U)
oo
       All values are estimated ppmv, except CO2 and H2O in percent
       Statistics of four runs during loading and lapping combined
       U/C - Unconditioned (U) or Conditioned (C) Sample
       C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
       NDP - Number of data points
       EDL - Estimated detection limit for spectral region used for analysis

-------
Table 2-31 b. Other Species Detected by FTIR - Reverberatory Furnace #1  Outlet,
continued
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ammonia
U
0.06
0.17
2.92
<0.1
477
0.1
Propylene
C
0.55
1.77
12.96
<0.4
88
0.4
Sulfur dioxide
U
0.91
2.84
24.88
<.1.2
477
1.2
All values are estimated ppmv
Statistics of four runs during loading and tapping combined
U/C - Unconditioned (U) or Conditioned (C) Sample
NDP - Number of data points
EDL - Estimated detection limit for spectral region used for analysis
2.5.2.5 FTIR Sampling and Measurement System Response Time Measurement

       FTIR system sampling and measurement system response time was determined by
measurement of concentration versus time of a dynamic spike of the sample gas. HC1 and SF6
spike gas were introduced via a remote-controlled solenoid valve located upstream of the heated
probe filter. The time required to obtain 90 percent response was measured three times.
Figure 2-1 illustrates data gathered on-site which show the three measurements. It is clear from
the figure that the 90 percent response time is approximately 2 minutes (i.e., two data points).
The figure also shows that the SF6 and HC1 response times are approximately the same, with HC1
slightly lagging relative to SF6.
                                        2-39

-------
to

i-
o
                        FTIR System Response


                               (3 measurements)
             15.00
        o

        1    10.00

        •s f
        o>
§ ~
5.00
              0.00
                  19:19
        1 minute data points
                 19:24
                                    19:29
                                     Time
                      HC1
                                    SF6
                                                0.00
19:34
     Figure 2-1. FTIR System Response Profile (Measured on 7 December 1997)

-------
 2.5.2.6 Comparison of FTIR and Method 26A Results for HCI

       Table 2-32 shows the comparison between the two sets of results for both the chip dryer
 and furnace.

 Table 2-32. Comparison of FTIR and Method 26A results for HCI, ppm1
Location
Chip Dryer Inlet
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
FTIR
8.12
2.48
70.15
2.83
Method 26A
27.45.
1.10
70.37
0.862
'Average of test runs at each location

       While it is instructive to compare HCI results from both FTIR and manual methods, care
must be taken in interpreting the two sets of results. For the chip dryer, the FTIR system
measured HCI at a given inlet or outlet only 25  % of the time compared to the corresponding
manual method which was integrated over the entire sampling period, due to splitting half of the
FTIR instrument analysis time equally between inlet and outlet as unconditioned and conditioned
samples.  Since HCI was measured only in unconditioned samples, this sampling scheme results
in a 25% duty cycle for the total run for HCI measurement at either the chip dryer inlet or outlet.
The corresponding FTIR data capture for either the furnace inlet #1 or outlet was approximately
38%.

       Future testing which incorporates both FTIR and Method 26A should include full
concurrent sampling to facilitate unbiased comparison between the two methods.
                                        2-41

-------
3.0   DESCRIPTION OF FACILITY





      (To be supplied by Research Triangle Institute).
                                    3-1

-------
4.0   SAMPLING LOCATIONS

       The sampling locations that were used during the emissions testing program at Gulp
Aluminum Alloys are described in this section. Flue gas samples were collected at the inlet and
at the outlet of the lime-injected baghouses using manual methods and FTIR, with two 4" ID
ports to allow for the operation of two manual sampling methods and one 3" ID port for the
FTIR.  The configurations of the sampling locations are shown in Figures 4-1 (El, chip dryer
baghouse inlet), 4-2 (E2, chip dryer baghouse outlet), 4-3 (E3, reverberatory furnace #1 baghouse
inlet), and 4-4 (E4, reverberatory furnace #1 baghouse outlet).

       The chip dryer operated at  approximately 150° F, with a slightly negative pressure at the
fan inlet and a slightly positive pressure at the outlet. At the inlet and outlet of the reverberatory
furnace #1 baghouse, 4" ports were available.  FTIR ports were installed horizontally and
upstream from manual ports.  The baghouse operated at approximately 175° F, with a slightly
positive pressure.

       The inlet of the lime-injected baghouse for the chip dryer was a circular duct 18" in
diameter, and the outlet was a circular duct 25" in diameter. Two 4" ID ports were installed at
90 degrees to each other, one horizontally and one vertically on top of the duct, and a third 3" ID
port was installed upstream of the  other ports for the FTIR  sampling probe.

       The inlet to the reverberatory furnace #1 baghouse was a circular duct 42"  in diameter.
Two 4" ports and one 3" port were installed; the two 4" ports were 90 degrees to each other. The
outlet was an exhaust stack 48" in  diameter, approximately 30 feet above the ground. The outlet
had two 4" ports; a third port (3" ID) was installed for the FTIR upstream of the other two ports.
The position and number of traverse points for each location are shown in Figures 4-5 through
4-8.  For stacks having diameters greater than 0.61 m (24 in.), no traverse points were located
within 2.5 cm (1.00 in.) of the stack walls.
                                           4-1

-------
   To Baghouse
1 Inlet, Dryer Baghouse








\

Building
Wall
A
\
18"


^ riow
"TpW' ^/


Fan

\
I ^

55" 48"
, •„
i


                           Ground
•figure 4-1. E1, Chip Dryer Baghouse Inlet

-------
                        Outlet
        Chip Dryer
        Baghouse
                                          4" ID Manual
                                          Ports
                                           3" ID FTIR
                                           Port
                                                  Lime Injection
Figure 4-2. E2, Chip Dryer Baghouse Outlet

-------
 Reverberatory
 Furnace
3" ID FTIR
Port
                                         4" ID Ports
      Flow
      To Baghouse
        20'
                    48'
                          Lime shed
                       w
                           *S^W* -J  " j t.   1 s  '
                          •*^v;\.
                                                 Flame Arrester
Figure 4-3. E3, Reverberatory Furnace Bagho^fie Inlet

-------
                      Exhaust
   Handrail
      Catwallc
                           48"
                                                            6'
3" FTIR
Port
                                                            24'
                              Fan
                       Ground
                                                            10'
Figure 4-4. E4, Reverberatory Furnace Baghouse Outlet

-------
                          O€
                                           18"
                                                                               17.2
ooo
Figure 4-5. Chip Dryer Baghouse Inlet, Traverse Points

-------
Figure 4-6.  Chip Dryer Baghouse Outlet, Traverse Points

-------
oo
  Figure 4-7.  Reverberatory Furnace Baghouse Inlet Traverse Points

-------
Figure 4-8.  Reverberatory Furnace Baghouse Outlet Traverse Points

-------
       For stack diameters equal to or less than 0.61 m (24 in.), no traverse points was located
within 1.3 cm (0.50 in.) of the stack walls. When any of the traverse points fell within 2.5 cm
(1.00 in.) of the stack walls, they were relocated to a distance of 2.5 cm (1.00 in.) or a distance
equal to the nozzle inside diameter, whichever was larger.

       All test ports and their locations met the requirements of EPA Method I.
                                          4-10

-------
 5.0     SAMPLING AND ANALYTICAL PROCEDURES BY ANALYTE

        The sampling and analytical procedures used for the Gulp Aluminum Alloys plant test
 program are the most recent revisions of the published EPA methods. In this section,
 descriptions of each sampling and analytical method by analyte are provided.

 5.1     Chlorinated Dibenzo-p-Dioxin and Chlorinated Dibenzofuran Emissions
        Testing Using EPA Method 23

        The sampling and analytical method for determining flue gas emissions of
 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans (CDD/CDF) is EPA
 Method 23.                                             .

 5.1.1   Method 23 Sampling Equipment

        The method uses the sampling train shown in Figure 5-1. The Method  23 sampling
 system is similar to a Method 5 train with the following exceptions:

        •     All components (glass probe/nozzle liner, all other glassware, filters) are pre-
             cleaned using solvent rinses and extraction techniques; and
        •     A condensing coil and XAD-2®  resin absorption module are located between
             the filter and impinger train.

 5.1.2   Method 23 Equipment Preparation

        In addition to the standard EPA Method 5 requirements, Method 23 includes several
unique preparation steps which ensure that the sampling train components are not contaminated
with organics that may interfere with analysis. The glassware, glass fiber filters and absorbing
resin are cleaned and the filters and resin are checked for 42 residuals before they are packed.
                                        5-1

-------
                                  stack wall
          Gas Flow
 Ul
 to
                                                     temperature
                                                        sensor
1 Ir
—
heated glass liner
> 	 n_
1 c 	 ' I
1
heat
r
L
]
1
id
~1
J
i
cc

                                                                     condenser
                                                          filter
                                                         holder
                                "S" type
                                  pilot
                                       manometer
                                                                                  temperature
                                                                                    sensor
                                                                                            XAD-2 trap
temperature
   sensor
      t
                                                     recirculation
                                                         pump
                                                     calibrated
                                                       orifice
                                    gas exit
                                    manometer
L
ifyg
met
T,
r
c

as
sr
H
Zl
;
empty
•
-"
^
r
1
KJ rtJ |tJ ftJ mJ
ice
bath
^ ^ A i
x A A
100ml ^^ .,~
HPLC Water empty SI"C,a
gel
fine
Mr —^ vacuum
Y I 9aU9e
V
^ coarse
( ) -^^t- vacuum pump
Figure 5-1.  Method 23 Sampling Train Configuration

-------
 5.1.2.1  Glassware Preparation

         The glassware preparation procedure is shown in Table 5-1.  Glassware is washed in
 soapy water, rinsed with distilled water, baked and then rinsed with acetone followed by
 methylene chloride.  Clean glassware is allowed to dry under a hood loosely covered with foil to
 prevent laboratory contamination. Once the glassware is dry, the air exposed ends are sealed
 with methylene chloride rinsed aluminum foil. All the glass components of the sampling train
 including the glass nozzles plus any flasks,  petri dishes, graduated cylinders and pipets that are
 used during sampling and recovery will be cleaned according to this procedure. Non-glass
 components (such as the Teflon  -coated filter screens and seals, tweezers, Teflon  squeeze
 bottles. Nylon® probe brushes and Nylon  nozzle brushes) are cleaned following the same
 procedure except that no baking is performed.

 5.1.2.2  XAD-2® Resin and Filter  Preparation

         XAD-2® absorbing resin and glass fiber filters are pre-cleaned by separate procedures
 according to the specified  method.  Only pesticide grade solvents and HPLC grade water are used
 to prepare for organic sampling, and to  recover these samples. The lot number, manufacturer and
 grade of each reagent used are recorded in the laboratory notebook.

         To prepare the filters, a batch  of 50 is placed in a Soxhlet extractor pre-cleaned by
extraction with toluene. The Soxhlet is charged with fresh toluene and refluxes for 16 hours.
After the extraction, the toluene is analyzed as described in Sections 5.1 and 5.3 of the reference
method (EPA Method 23)  for the presence of tetrachlorodibenzo-p-dioxins (TCDD) and
tetrachlorodibenzofurans (TCDF). If these analytes are found, the filters are re-extracted until  the
analyte is not detected. The filters are then dried completely under a clean nitrogen (N2) stream.
Each filter is individually checked for holes, tears, creases or discolorations, and if any are found,
the filter  is discarded. Acceptable filters are stored in a pre-cleaned petri dish, labeled by date of
analysis and sealed with Teflon® tape.
                                           5-3

-------
Table 5-1.  Method 23 Glassware Cleaning Procedure
(Train Components, Sample Containers and Laboratory Glassware)
NOTE:  USE VTTON® GLOVES AND ADEQUATE VENTILATION WHEN RINSING
         WITH SOLVENTS
         1.    Soak all glassware in hot soapy water (laboratory detergent).

        2.    Rinse with tap water to remove soap.

        3.    Rinse with HPLC-grade H2O, three times

        4.    Bake at 450° F for 2 hours.3

        5.    Rinse with acetone (pesticide grade), three times.

        6.    Rinse with methylene chloride (pesticide grade), three times.

        7.    Cap glassware with clean glass plugs or methylene chloride rinsed aluminum foil.

        8.    Mark cleaned glassware with color-coded identification sticker.

        9.    Rinse glassware immediately before using with acetone and methylene chloride
             (laboratory proof)-
a Step (4) has been added to the cleanup procedure to replace the dichromate soak specified in the
reference method. ERG has demonstrated in the past that baking glassware sufficiently removes
organic artifacts.  Step 4 is not used for probe liners and non-glass components of the train that
cannot withstand 450° F (i.e., Teflon®-coated filter screen and seals, tweezers, Teflon® squeeze
bottles, Nylon  probe and nozzle brushes).
                                        5-4

-------
         To prepare the absorbing resin, the XAD-2  resin is cleaned in the following sequential
 order:

         •    Rinse with HPLC grade water, discard water;
         •    Soak in HPLC grade water overnight, discard water;
         •    Extract in Soxhlet with HPLC grade water for 8 hours, discard water;
         •    Extract with methanol for 22 hours, discard solvent;
         •    Extract with methylene chloride for 22 hours, discard solvent;
         •    Extract with methylene chloride for 22 hours, retain an aliquot of solvent for
              analysis of CDDs and CDFs by HRGC/HRMS; and
         •    Dry resin under a clean N2 stream.

         Once the resin is completely dry, it is checked for the presence of methylene chloride,
CDDs and CDFs as described in Section 3.1.2.3.1  of the reference method.  If any analytes are
found, the resin is re-extracted.  If methylene chloride is found, the resin is dried until the excess
solvent is removed.  The absorbent is to be used within four weeks of cleaning.

         The cleaned XAD-2® resin is spiked before shipment to the field with five CDD/CDF
internal standards. Due to the special handling considerations required for the internal standards,
the spiking is performed by Triangle Laboratories.  For convenience and to minimize
contamination, Triangle Laboratories also performs the resin and filter cleanup procedures and
loads the resin into the glass traps.

5.1.2.3  Method 23 Sampling Train Preparation

         The remaining preparation includes calibration and leak checking of all sampling train
equipment, including meter boxes, thermocouples, nozzles, pitot tubes, and umbilicals.
                                           5-5

-------
 Referenced calibration procedures are followed when available.  The results are properly
 documented in a laboratory notebook or project file and retained.

 5.1.3   Method 23 Sampling Operations

 5.1.3.1  Preliminary Measurements

         Prior to sampling (data collected during presurvey), preliminary measurements are
 required to ensure isokinetic sampling. These measurements include determining the traverse
 point locations, performing a preliminary velocity traverse, cyclonic flow check and moisture
 determination.  These measurements are used to calculate a "K factor."  The K factor is used to
 determine an isokinetic sampling rate from stack gas flow readings taken during sampling.

         Measurements are then made of the duct inside diameter, port nozzle length, and the
 distances to the nearest upstream and downstream flow disturbances. These measurements are
 then used to determine sampling point locations by  following EPA Reference Method 1
 guidelines. The distances are then marked on the sampling probe using an indelible marker.

 5.1.3.2  Assembling the Train

         Method 23 sampling train components are collected in the recovery trailer and final
 train assembly is performed at the stack location. First, the empty, clean impingers are
 assembled and laid out in the proper order in the recovery trailer.  Each ground glass joint is
 carefully inspected for hairline cracks. The first impinger is a knockout impinger which has a
 short tip. The purpose of this impinger is to collect  condensate which forms in the coil and
 XAD-2® resin trap.  The next two impingers are modified tip impingers which each contain
 100 mL of HPLC grade water. The fourth impinger is empty, and the fifth impinger contains 200
 to 300 grams of blue indicating silica gel. After the impingers are loaded each impinger is
 weighed, the initial weight and contents of each impinger are recorded on a recovery data sheet.
The heights of all the impingers are approximately the same to obtain a leak free seal. The open

                                          5-6

-------
ends of the train are sealed with methylene chloride-rinsed aluminum foil, or clean ground glass
caps.

       :  The second step is to load the filter into the filter holder in the recovery trailer.  The
filter holder is then capped off and placed with the resin trap and condenser coil (capped) into the
impinger bucket. A supply of precleaned foil and socket joints is also placed in the bucket in a
clean plastic bag for the convenience of the samplers.  Sealing greases are not used to avoid
contamination of the sample.  The train components are transferred to the sampling location and
assembled as previously shown in Figure 5-1. The heated probe and filter box will be a single
                                                                                      ®
unit mounted on a vertical monorail. The chilled impinger box with the condenser and XAD-2
trap will be placed on the floor of the scaffolding.

5.1.3.3  Sampling Procedures

         After the train is assembled, the heaters for the probe liner and heated filter box are
turned on and the sorbent module/condenser coil recirculating pump is turned on.  When the
system reaches the appropriate temperatures, the sampling train is ready for pre-test leak
checking. The temperature of the sorbent module resin must not exceed 50° C (120° F) at any
time and during testing it must not exceed 20° C (68° F).  The filter temperature is maintained at
120 ±14° F (248 ±25° F).  The probe temperature is maintained above 100° C (212° F).

        The sampling trains  are leak checked at the start and finish of sampling. (Method 5/23
protocol only requires post-test leak checks and  recommends pre-test leak checks.) ERG
protocol also incorporates leak checks before and after every port change. An acceptable pre-test
leak rate is less than 0.02 acfm (ft3/min) at approximately 15 inches of Hg, If during testing, a
piece of glassware needs to be emptied or replaced, a leak check is performed before the
glassware piece is removed, and after the train is re-assembled.

        To leak check the assembled train, the  nozzle end is capped off and a vacuum of
15 inches Hg is pulled in the system. When the  system is evacuated, the volume of gas flowing

                                          5-7

-------
 through the system is timed for 60 seconds. After the leak rate is determined, the cap is slowly
 removed from the nozzle end until the vacuum drops off, and then the pump is turned off.  If the
 leak rate requirement is not met, the train is systematically checked by first capping the train at
 the filter, at the first impinger, etc., until the leak is located and corrected.

         After a successful pre-test leak check has been conducted, all train components are at
 their specified temperatures and initial data are recorded (DGM reading), the test can be initiated.
 Sampling train data are recorded periodically on standard data forms. A checklist for CDD/CDF
 sampling is included in Table 5-2. A sampling operation that is unique to CDD/CDF sampling is
 that the gas temperature entering the resin trap must be below 20° C (68° F).  The gas is cooled
 by a water jacket condenser through which ice water is circulated.

         The leak rates and sampling start and stop times are recorded on the sampling  task log.
 Also, any other events that occur during sampling are recorded on the task log such as sorbent
 module heat excursions, pitot cleaning, thermocouple malfunctions, heater malfunctions or any
 other unusual occurrences.

         If the probe liner breaks while DGM is not running (i.e., during port changes or after the
 run is completed), the probe liner is replaced, the run is completed, and sample recovery done on
 both the broken sections of the glass liner and the replacement liner. If the break occurs while
 the DGM is running and the exact time of the break is noted, the test is stopped so that the probe
 liner can  be replaced.  The run is then completed and sample recovery done on all liner sections.
 If the recovered sample appears unusual, the sample is discarded and an additional run is
performed later. If the recovered sample appears normal, the run is tentatively acceptable.

         At the conclusion of the test run, the sample pump (or flow) is turned off, the probe is
removed  from the duct, a final DGM reading is taken, and a post-test leak check is completed.
The procedure is identical to the pre-test procedure.  However, the vacuum should be at  least
one inch Hg higher than the highest vacuum attained during sampling. An acceptable leak rate is
less than 4% of the average sample rate or 0.02 acfm (whichever is lower).

                                           5-8

-------
Table 5-2.  CDD/CDF Sampling Checklist
Before test starts:

1.  Check impinger set to verify the correct order, orientation and number of impingers. Verify
    probe markings, and remark if necessary.

2.  Check that you have all the correct pieces of glassware.  Have a spare probe liner, probe
    sheath, meter box and filter ready to go at location.

3.  Check for data sheets and barometric pressure.

4.  Prepare bag sampling equipment for CO2/O2, except when using CEMs for CO2/O2
    determinations.

5.  Examine meter box - level it, zero the manometers and confirm that the pump is operational.

6.  Verify the filter is loaded correctly and as tightly as  possible; place filter in line with the
    train and leak check at 15 inches Hg.

7.  Add probe to train.

8.  Check thermocouples - make sure they are reading correctly.

9.  Conduct pitot leak check, recheck manometer zero.

10.  Do final leak check; record leak rate and vacuum on sampling log.

11.  Turn on variacs and check to see that the heat is increasing.

12.  Check that cooling water is on and flowing. Add ice to impinger buckets.

13.  Check isokinetic K-factor - make sure it is correct.  (Refer to previous results to confirm
    assumptions. Two people should calculate this independently to double check it.)
                                          5-9

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Table 5-2.  COD/CDF Sampling Checklist (continued)
During Test:

1.  Notify field task leader of any sampling problems ASAP. Train operator should fill in
    sampling log and document any abnormalities.

2.  Perform simultaneous/concurrent testing with other locations (if applicable). Maintain filter
    temperature between 248 ° F ±25 ° F. Keep temperature as steady as possible.  Maintain the
    resin trap and impinger temperatures below 68° F. Maintain probe temperature above
    212° F.

3.  Leak check between ports and record on data sheet. Leak check if the test is stopped to
    change silica gel, to decant condensate, or to change filters.

4.  Record sampling times, rate, and location for the fixed gas bag sampling (CO, CO2, O2), if
    applicable.

5.  Blow back pitot tubes periodically if moisture entrapment is expected.

6.  Change filter if vacuum suddenly increases or exceeds 15 inches Hg.

7.  Check impinger solutions every ¥2 hour; if the knockout impinger is approaching full, stop
    test and empty it into a pre-weighed bottle and replace it in the train.

8.  Check impinger silica gel every Vi hour; if indicator color begins to fade, request a prefilled,
    preweighed impinger from the recovery trailer.

9.  Check the ice in the impinger bucket frequently. If the stack gas temperatures are high, the
    ice will melt at the bottom rapidly. Maintain condenser coil and silica gel impinger gas
    temperatures below 20° C (68° F).

After test is completed:

1.  Record final meter reading.

2.  Do final leak check of sampling train at maximum vacuum during test.
                                         5-10

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Table 5-2. CDD/CDF Sampling Checklist (continued)
3.   Do final pitot leak check.

4.   Check completeness of data sheet. Verify the impinger bucket identification is recorded on
     the data sheets. Note any abnormal conditions.

5.   Leak check, check functions (level, zero, etc.) of pitot tubes and inspect for tip damage.

6.   Disassemble train, cap  sections, and take each section and all data sheets down to recovery
     trailer.

7.   Probe recovery (use 950 mL bottles)
     a)   Bring probes into recovery trailer (or other enclosed area).
     b)   Wipe the exterior of the probe to remove any loose material that could contaminate the
         sample.
     c)   Carefully remove the nozzle/probe liner and cap it off with prerinsed aluminum foil.
     d)   For acetone rinses  (all trains)
            Attach precleaned cyclone flask to probe to catch rinses
            Wet all sides of probe interior with acetone
         -   While holding  the probe in an inclined position, put precleaned probe brush down
            into probe and  brush it in and out
         -   Rinse the brush, while in the probe, with acetone
         -   Do this at least 3 times until all the particulate has been recovered.
            Recover acetone into a preweighed, prelabeled sample container
     e)   Follow the procedure outlined in (d) using methylene chloride. Recover the solvent
         into the same acetone recovery bottle.
     f)   Follow the procedure outlined in (d) using toluene. Recover this solvent into a separate
         preweighed prelabeled sample container.

8.   Cap both ends of nozzle/probe liner for the next day, and store in dry safe place.

9.   Make sure data sheets are completely filled out, legible, and give them to the field task
     leader.
                                          5-11

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 5.1.4    CDD/CDF Sample Recovery

         To facilitate transfer from the sampling location to the recovery trailer, the sampling
 train is disassembled into the following sections: the probe liner, filter holder, filter to condenser
 glassware, condenser and sorbent module, and the impingers in their bucket.  Each of these
 sections is capped with methylene chloride rinsed aluminum foil or ground glass caps before
 removal to the recovery trailer. Once in the trailer, field recovery follows the scheme in
 Figure 5-2.  The samples are recovered and stored in cleaned amber glass bottles to prevent light
 degradation.

         The probe and nozzle are first rinsed with approximately 100 mL of acetone and
 brushed to remove any paniculate. This first rinse is followed with a rinse of methylene
 chloride.  Both of these rinses  are collected in the same bottle. The same two solvents are used
 to rinse the cyclone, front/back half filter holder, filter support, connecting glassware and
 condenser. These rinses are added to the probe rinse bottle. All of the components listed above
 are again rinsed with toluene, but collected in a separate container. In addition, the Teflon®
 transfer line used with the vertical sampler will be filled with toluene and allowed to stand for
 5 minutes before adding to the toluene rinses. The filter is carefully removed from the filter
 holder, placed in a pre-labeled petri dish and sealed with Teflon® tape for transport to the
 laboratory.

         The contents of impingers  1-4 (H2O) and impinger 5 (silica gel) are weighed to 0.5 mg
 and then discarded.

         The solvents used for train recovery are all pesticide grade. The use of the highest
grade reagents for train recovery is essential to prevent the introduction of chemical impurities
which interfere with the quantitative analytical determinations.
                                          5-12

-------
Probe Probe Cyclone Front Half of Filler Back Half of Connecting Condenser
N
Rinse w
ozzle L
th Acetone A
ner
tach
Filler 1

Housing Sup

port Filter H

jusing Lii

ie



Until all Paniculate 250 mL flask Brush and Brush and
is Removed to Ball Joint rinse with rinse with Rinse with Rinse with Rinse with Rinse with
acetone (3x) acetone (3x) acetoi












Rinse wi
Rinse with
Acetone
Empty Flask
into 950 mL
Bottle

Brush Liner and Rinse
with 3 Aliquols of
Acetone
Check Liner to see if
Paniculate is
removed; if not, repeat
h 3 Aliquots Rin
se with R












nse with Rins












e with
.ofMethylene 3 Aliquots 3 Aliquots 3 Aliquols
Chloride ofMelhylene ofMelhylene ofMethylene
Chloride Chloride Chloride



Rinse



with Rin



se with Rin



se with Rin<
Rcco
ic (3x) acetone (3x) acelon
e (3x) acetone (3x)
Rinse with melhylene Rinse with Rinse with
chloride (3x) (at least methylene melhylene
once let the rinse stand chloride chloride (3x)
5 min in unit) (3x) (at least once let
the rinse stand











ver into
pieweighed
b(
Mile
PR














5 min in unit)




























e with Rinse with Toluene (3x) Rinse with Toluene (3x) (at
Toluene (3x)* Toluene (3x) Toluene (3x) Toluene (3x) (at least once let the rinse Toluene (3x) least once let the
stand 5 min in unit) rinse stand 5 inin




*This fraction should not be combined with the other toluene
fractions


I'RT/CRT

in uni
)

Figure 5-2. Method 23 Field Recovery Scheme

-------
u»
Fil
ter
Carefully
remove filler
from support
with tweezers
Brush loose
Paniculate
onlo Tiller
Seal in
pelri
dish
F' . .„ .

Resin
Trap Istlm
(knoc
jinger 2nd Itn
kout)
pinger 3rd Im
pinger 4lh Im
pinger 5th Im
(silic
•
pinger
a gel)
Secure XAD Weigh Weigh Weigh Weigh Weigh
trap openings Impingcr Impingcr Impinger linpinger . Impinger
with glass balls
and clamps
Place in cooler Record weigh! Record weigh! Record weight Record weight Record weight
for storage and and and • and and
calculate gain calculate gain calculate gain calculate gain calculate gain




i'SM 1






Discard
Note: See Table 5-3 for Sample Fractions Identification
Sav
efor
regeneration


    Figure 5-2.  Method 23 Field Recovery Schedule (continued)

-------
         The train components recovered in the field are listed in Table 5-3. All recovered
 samples are stored in coolers on ice at all times. The samples will be delivered to the analytical
 laboratory upon return to ERG accompanied by written information designating target analytes.

 Table 5-3. Method 23 Sample Fractions Shipped To Analytical Laboratory
Container/
Component
1
2
3
4
Code
F
PRa
PRT
CRT
SM
Fraction
Filter(s)
Acetone and methylene chloride rinses of
nozzle/probe, cyclone, front half/back filter
holder, filter support, connecting
glassware, condenser
Toluene rinse of nozzle/probe, cyclone,
front half/back half filter holder, filter
support, connecting line and condenser
®
XAD-2 resin trap (sorbent module)
"Rinses include acetone and methylene chloride recovered into the same sample bottle.

5.1.5    CDD/CDF Analytical Procedures

         The analytical procedure used to obtain analyte concentrations from a single flue gas
sample is high resolution gas chromatography (HRGC) and high resolution mass spectrometry
(HRMS)  (resolution from 8000-10000 m/z).  The target CDD/CDF congeners are listed in
Table 5-4. The analysis was performed by Triangle Laboratories, Inc., by Method 23/8290.

         The Method 23 samples are prepared and analyzed according to the scheme in
                      (R)
Figure 5-3. The XAD-2   and filter (along with the concentrated acetone/methylene chloride
rinses) are placed in a Soxhlet extractor and extracted with toluene. This extract is added to the
toluene train rinses and then concentrated by rotary evaporation.  This concentrated sample
extract is added to the toluene train rinses and then concentrated by rotary evaporation. This
concentrated sample is subjected to a sample cleanup procedure before analysis. For the
                                         5-15

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Table 5-4.  CDD/CDF Congeners To Be Analyzed
DIQXINS:
   2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD)
   Total tetrachlorinated dibenzo-p-dioxins (TCDD)
   i,2,3,7,8-pentachlorodibenzo-/?-dioxin(l,2,3,7,8-PeCDD)
   Total pentachlorinated dibenzo-p-dioxins (PeCDD)
   1,2,4,5,7,8-hexachlorodibenzo-p-dioxin (1,2,3,4,7,8-HxCDD)
   l,2,3,6,7,8-hexachlorodibenzo-/7-dioxin(l,2,4,5,7,8-HxCDD)
   l,2,3,7,8,9-hexachlorodibenzo-p-dioxin(l,2,3,7,8,9-HxCDD)
   Total hexachlorinated dibenzo-p-dioxins (HxCDD)
   l,2,3,4,6,7,8-heptachlorodibenzo-p-dioxin(l,2,3,4,6,7,8-HpCDD)
   Total heptachlorinated dibenzo-p-dioxins (HpCDD)
   Total octachlorinated dibenzo-p-dioxin (OCDD)

FURANS:
   2,3,7,8-tetrachlorodibenzofurans(2,3,7,8-TCDF)
   Total tetrachlorinated dibenzofurans (TCDF)
   1,2,3,7,8-pentachlorodibenzofuran (1,2,3,7,8-PeCDF)
   2,3,4,7,8-pentachlorodibenzofuran(2,3,4,7,8-PeCDF)
   Total pentachlorinated dibenzofurans (PeCDF)
   l,2,3,4,7,8-hexachlorodibenzofuran(l,2,3,4,7,8-HxCDF)
   1,2,3,6,7,8-hexachlorodibenzofuran (1,2,3,6,7,8-HxCDF)
   2,3,4,6,7,8-hexachlorodibenzofuran(2,3,4,6,7,8-HxCDF)
   l,2,3,7,8,9-hexachlorodibenzofuran(l,2,3,7,8,9-HxCDF)
   Total hexachlorinated dibenzofuran (HxCDF)
   l,2,3,4,6,7,8-heptachlorodibenzofuran(l,2,3,4,6,7,8-HpCDF)
   1,2,3,4,7,8,9-heptachlorodibenzofuran (1,2,3,4,7,8,9-HpCDF)
   Total heptachlorinated dibenzofurans (HpCDF)
   Total octachlorinated dibenzofuran (OCDF)
                                        5-16

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              Toluene
               Rinses
              Rotovap
              to 1 mL
             Add to SOX
             for Toluene
             Extraction
      AC/MeCl2
       Rinses
       KDto
        1 mL
Add to SOX for Toluene
      Extraction
                                         Spike with
                                    PCDD/PCDF Standards
                                       Soxhlet in Toluene
  XAD-2®
Prespiked with
     5
PCDD/PCDF
  Standards
  Filter +
XAD-2® Add
  to Soxhlet
                                           Split 1:1
                                     50% Toluene Extract to
                                           Dioxins
                                     Do PCDDs/Fs Cleanup
                               Analyze for PCDDs/Fs Method 8290X
Figure 5-3. Extraction and Analysis Schematic for Method 23 Samples
                                         5-17

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 CDD/CDF analysis, isotopically-labeled surrogate compounds and internal standards and
 surrogates that are used are described in detail in EPA Method 23.

         Data from the mass spectrometer are recorded and stored on a computer file as well as
 printed on paper. Results such as amount detected, detection limit, retention time, and internal
 standard and surrogate standard recoveries are calculated by computer.  The chromatograms are
 retained by the analytical laboratory and also included in the analytical report delivered to ERG.

 5.1.5.1  Preparation of Samples for Extraction

         Upon receiving the sample shipment, the samples are checked against the chain-of
 custody forms and then assigned an analytical laboratory sample number. Each sample
 component is reweighed to determine if leakage occurred during travel. Color, appearance, and
 other particulars of the samples are noted. Samples are extracted within 21 days of collection
 and processed through cleanup procedures before concentration and analysis.

 5.1.5.2  Calibration of GC/MS System

         A five-point calibration of the GC/MS system is performed to demonstrate instrument
 linearity over the concentration range of interest. Relative response factors are calculated for
 each dioxin/furan congener or compound of interest. The response factors are verified on a daily
 basis using a continuing calibration standard consisting of a mid-level standard.  The instrument
 performance is acceptable only if the measured response factors for the labeled and unlabeled
 compounds and the ion-abundance ratios are within the allowable limits specified in the method.

 5.1.6    CDD/CDF Analytical Quality Control

         All quality control procedures specified in the test method are followed. Blanks are
used to determine analytical contamination, calibration standards are used for instrument
calibration and linearity checks, internal standards are used  to determine isomer recoveries and
                                          5-18

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 adjust response factors for matrix effects, surrogate standards are used to measure the collection
 efficiency of the sampling methodology and an alternate standard is used as a column efficiency
 check.

 5.1.6.1  CDD/CDF Quality Control Blanks

         Four different types of sample blanks are collected for CDD/CDF analysis. The types
 of blanks that are required are shown in Table 5-5.
 Table 5-5. Method 23 Blanks Collected
Blank
Field Blanks
Glassware Proof Blank
Method Blank
Reagent Blanks
Collection
One run collected for each
sample location) and
analyzed
Each train to be used (2) will
be loaded and quantitatively
recovered prior to sampling
At least one for each
analytical batch (laboratory
generated)
One 500 mL sample for each
reasent and lot
Analysis
Analyze with field samples
Archive for potential analysis
Analyze with each analytical
batch of field samples
Archive for potential analysis
         Reagent blanks of 500 mL of each reagent used at the test site are saved for potential
analysis. Each reagent blank is of the same lot as was used during the sampling program:  Each
lot number and reagent grade is recorded on the field blank label and in the laboratory notebook
                                               ®
(acetone, methylene chloride, toluene, filter. XAD-2).
         A glassware blank (proof blank) is recovered from each set of sample train glassware
that is used to collect the organic samples. The precleaned glassware, which consists of a probe
liner, filter holder, condenser coil,  and impinger set, is loaded as if for sampling and then
quantitatively recovered exactly as the samples will be. Analysis of the generated fractions will
be used to check the effectiveness of the glassware cleaning procedure only if sample analysis
indicates a potential contamination problem.
                                          5-19

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         A field blank is collected from a set of CDD/CDF glassware that has been used to
 collect at least one sample and has been recovered. The train is re-loaded, leak checked and left
 at a sampling location during a test run. The train is then recovered.  The purpose of the field
 blank is to measure the level of contamination that occurs from handling, loading, recovering,
 leak checking, and transporting the sampling train. The field blanks are analyzed with the flue
 gas samples. If they are unsatisfactory in terms of contamination, reagent blanks may be
 analyzed to determine the specific source of contamination.

         In addition to the three types of blanks that are required for the sampling program, the
 analytical laboratory will analyze  a method blank with each set of flue gas samples. This method
 blank will consist of preparing and analyzing an aliquot of toluene by the exact procedure used
 for the samples analysis.  The purpose of this method blank is to verify that there is no
 laboratory contamination of the field samples.

 5.1.6.2  Quality Control Standards and Duplicates

         Recoveries of the internal standards must be between 40 to 130% for the tetra- through
 hexachlorinated compounds and in the range of 25 to 130% for the hepta- and octachlorinated
 homologs.  If these requirements are not met, the data will be  acceptable if the signal to noise
 ratio is greater than or equal to ten. If these  requirements are met, the results for the native
 (sampled) species are adjusted according to the internal standard recoveries.

         Surrogate standard recoveries must be between 70 to 130%.  If the recoveries of all
 standards are less than 70%, the project director will be notified immediately to determine if the
 surrogate results will be used to adjust the results of the native species.

        Duplicate analysis is performed for every ten samples.  The purpose of this duplicate
analysis is to evaluate the precision of the combined sample preparation and analytical
methodology.
                                          5-20

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 5.1.7   Analytes and Detection Limits for Method 23

         The target analytes are the tetra- through octachlorinated dibenzodioxins and
 chlorinated dibenzofurans.  The detection limit of the individual compounds is dependent on the
 detection limit of the analytical method, the volume of the final extract and the total volume of
 gaseous sample collected in the sampling trains.  Following the protocol of Method 23, the
 fractions to be collected for analysis from each train are:

         •      Fraction I—Filter;
         •      Fraction 2—XAD-2  sorbent module;
         •      Fraction 3—Acetone  and methylene chloride rinses of all train components prior
               to sorbent module and;
         •      Fraction 4—Toluene  rinses of all train components prior to the sorbent module.

         Following the sample preparation protocol outlined in Method 23, a single combined
sample is presented for analysis for D/F by high resolution gas chromatography/high resolution
mass spectrometry. (The individual samples will no longer be available for analysis.)  The final
volume of this sample is 200 fu.L of which a 2 /J.L aliquot is injected into the instrument.  Using
an instrument detection limit of 50 pg for tetra-, 250 pg for penta- through hepta-, and 500 pg for
octachlorinated D/F, the total minimum detectable amounts can be calculated and are given in
Table 5-6.

         Using a four hour sampling time at an assumed sampling rate of 0.65 to 0.75 cfm, the
MDLs shown in Table 5-7 are possible. The sampling flow rate at the outlet location will be
dictated by the flow rate of the stack gas since isokinetic sampling will be performed.
                                          5-21

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Table 5-6. Analytical Detection Limits For Dioxins/Furans
Analyte
Tetra CDDs
PentaCDDs
Hexa CDDs
Hepta CDDs
Octa CDD
Tetra CDFs
Penta CDFs
Hexa CDFs
Hepta CDFs '
Octa CDF
Total Detectable Amount, ng
"5
25
25
25
50
5
25
25
25
50
NOTE: D/F analysis by High Resolution Mass Spectrometry assumes a 2 /uL injection of a 200 /uL sample
extract.

Table 5-7. CDD/CDF Method Detection Limits
Sampling Time, Hours
Sampling Rate, cfm
Sample Volume, nv1

Tetra CDDs
PentaCDDs
Hexa CDDs
Hepta CDDs
Octa CDD
Tetra CDFs
Penta CDFs
Hexa CDFs
Hepta CDFs
Octa CDF
4
0.75
5.1
MDL, ng/m3
0.98
4.9
4.9
4.9
9.8
0.98
4.9
4.9
4.9
9.8
                                       5-22

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 5.2     Hydrochloric Acid/Particulate Matter Emissions Testing Using EPA
         Method 26A
         Hydrogen chloride (HC1) sampling is accomplished using EPA Method 26A,
 Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources - Isokinetic
 Method. Method 26A is particularly suited for sampling at sources emitting acid particulate
 matter (i.e., hydrogen chloride dissolved in water droplets).  In this method, a gas sample is
 extracted isokinetically from the stationary source and passed through acidified water. In
 acidified water, HC1 solubilizes and forms chloride (CI~) ions.  Ion chromatography (1C) is  used
 to detect the chloride ions present in the sample. In addition, sampling for Particulate Matter
 (PM) is also performed according to the EPA Method 26A protocol. This method is applicable
 to the determination of particulate mass emissions collected on a glass fiber filter and any
 material that condenses at or above the filter temperature of 120±14°C (248±25°F) from various
 types of process controls and combustion sources. The particulate mass, which includes any
 material that condenses at or above the filter temperature, is determined gravimetrically after
 removal of uncombined water.

        Particulate concentrations are based on the weight gain of the filter and any condensible
 PM recovered from the acetone rinses of the probe, nozzle, and front half of the filter.

 5.2.1   Method 26A Sampling Equipment

        The EPA Method 26A methodology uses the sampling train shown in Figure 5-4.  The
 5-impinger train consists of a borosilicate glass nozzle/probe liner followed by a heated filter
assembly with a Teflon"  filter support, a series of impingers and a meter box and vacuum pump
as specified in EPA Method 5.  The sample is not exposed to any metal surfaces in this train.
                                         5-23

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 to
                               Slack
                      Temperature /a
                        Sensor
                Gooseneck
                 Nozzle
                                           Thermometer
Glass Filter Holder
X
                                                                                                  Thermometer
               S-Type Pilot Tube
                                                                    Impingers with Absorbing Solution
                                                                            (see below)
                        Manometer
Figure 5-4. Schematic of Method 26A Sampling Train

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         The contents of the sequential impingers are:

         •      Impinger #1 (Greenburg-Smith) and Impinger #2 (Greenburg-Smith), known
               volumes of 0. IN H2SO4 (nominal 100 mL);
         •      Impinger #3 (modified Greenburg-Smith) and Impinger #4 (modified Greenburg-
               Smith), known volumes of 0.1 N NaOH;
         •      Impinger #5 (modified Greenburg-Smith), indicating silica gel.

5.2.2    Method 26A Sampling Equipment Preparation

5.2.2.1  Glassware Preparation

         Glassware is washed in soapy water, rinsed with hot tap water, rinsed with Type n
water, rinsed with acetone to remove the water, rinsed three times with acetone and then air
dried. This procedure is used on all the glass components of the sampling train including the
glass nozzles plus any sample bottles, Erlenmeyer flasks, petri dishes, and graduated cylinders.
Non-glass components (such as the Teflon®-coated filter screens and seals, tweezers, Teflon®
squeeze bottles, Teflon" probe brushes) are cleaned following the same procedure. The cleaning
procedure is summarized in Table 5-8.

5.2.2.2  Reagent Preparation

        The sample train filters are Pallflex® TX40HI45 Teflon® mat filters that meet the
criteria specified in Section 3.1.1 of EPA Method 5. These filters are used as received from the
vendor. The acetone is purchased  as HPLC grade to ensure a low residue after evaporation. The
reagent water is distilled/deionized grade that meets the requirements of ASTM Type 3 water or
equivalent.  The lot number, manufacturer and grade of each  reagent that is used are recorded in
the laboratory notebook.
                                         5-25

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 Table 5-8. Glassware Cleaning Procedure
 (Method 26A Train Components)
  NOTE: USE DISPOSABLE GLOVES AND ADEQUATE VENTILATION
  1.   Soak all glassware in hot soapy water (laboratory detergent).
  2.   Rinse with tap water to remove soap.
  3.   Rinse with HPLC grade water (three times).
  4.   Rinse with acetone (three times).
  5.   Air dry.
  6.   Cap glassware with clean glass plugs or Parafilm.®
  7.   Mark cleaned glassware with color-coded identification sticker.
        The analyst wears both safety glasses and protective gloves when the reagents are
mixed or handled. Each reagent has its own designated transferTeflon® squeeze bottle and is
marked for identification and used only for the reagent for which it is designated.

5.2.2.3  Equipment Preparation

        The remaining preparation includes calibration and leak checking of all of the train
equipment, including meter boxes, thermocouples, nozzles, pitot tubes, and umbilicals.
Referenced calibration procedures are followed when available, and the results are properly
documented and retained.  A discussion of the techniques used to calibrate this equipment is
presented below.

        Type-S Pitot Tube Calibration. The EPA has specified guidelines concerning the
construction and geometry of an acceptable Type-S pitot tube.  If the specified design and
                                         5-26

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 construction guidelines are met, a pitot tube coefficient of 0.84 is used.  Information pertaining to
 the design and construction of the Type-S pitot tube is presented in detail in Section 3.1.1 of EPA
 Document 600/4-77-0275. Only Type-S pitot tubes meeting the required EPA specifications are
 used.  Pitot tubes are inspected and documented as meeting EPA specifications prior to field
 sampling.

         Sampling Nozzle Calibration.  Glass nozzles are used for isokinetic sampling.
 Calculation of the isokinetic sampling rate requires that the cross sectional area of the sampling
 nozzle be accurately and precisely known.  All nozzles are thoroughly cleaned, visually inspected
 and calibrated according to the procedure outlined in Section 3.4.2 of EPA Document 600/4-77-
 027b.

         Temperature Measuring Device Calibration.  Accurate temperature measurements
 are required during source sampling.  Bimetallic stem thermometers and thermocouple
 temperature sensors are calibrated using the procedure described in Section 3.4.2 of EPA
 Document 600/4-77-027b.  Each temperature sensor is calibrated at a minimum of two points
 over the anticipated range of use against a NIST-traceable mercury-in-glass thermometer.  All
 sensors are calibrated prior to field sampling.

         Drv Gas Meter Device Calibration.  Dry gas meters (DGMs) are used in the Method 5
 sampling trains to monitor the sampling rate and to measure the sample volume. All DGMs are
 calibrated to document the volume correction factor just prior to shipping of the equipment to the
 field. Post-test calibration checks are performed as soon as possible after the equipment has been
 returned to the ERG Laboratpry. Pre- and post-test calibration should agree to within 5%.

         Prior to calibration, a positive pressure leak check of the system is performed using the
procedure outlined in Section 3.3.2 of EPA Document 600/4-77-237b.  The system is placed
under approximately 10 inches of water pressure and a gauge oil manometer is used to determine
if a pressure decrease can be detected over a one-minute period. If leaks are detected, they are
eliminated before actual calibration are performed.

                                          5-27

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         After the sampling console is assembled and leak checked, the pump is to run for
 15 minutes, to allow the pump and DGM to warm up. The valve is then adjusted to obtain the
 desired flow rate. For the pre-test calibration, data are collected at orifice manometer settings
 (AH) of 0.5, 1.0, 1.5, 2.0, 3.0 and 4.0 in H20. Gas volumes of 5 ft3 are used for the two lower
 orifice settings, and volumes of 10 ft3 are used for the higher settings. The individual gas meter
 correction factors (Yj) are calculated for each orifice setting and averaged.  The method requires
 that each of the individual correction factors fall within ±2% of the average correction factor or
 the meter is cleaned, adjusted, and recalibrated.  In addition, ERG requires that the average
 correction factor be within 1.00 ±1%. For the post-test calibration, the meter is calibrated three
 times at the average orifice setting and vacuum which were used during the actual test.

 5.2.3    Method 26A Sampling Operations

 5.2.3.1  Preliminary Measurements

         Prior to sampling, preliminary measurements are required to ensure isokinetic sampling.
 These preliminary measurements include determining the traverse point locations, performing a
 preliminary velocity traverse and a cyclonic flow check. These measurements are used to
 calculate a "K factor." The K factor is used to determine an isokinetic sampling rate from stack
 gas flow readings taken during sampling.

         Measurements are then made of the duct inside diameter, port nozzle length, and the
 distances to the nearest upstream and downstream flow disturbances.  These measurements are
 then used to determine sampling point locations by following EPA Reference Method 1
 guidelines.  The distances are then marked on the sampling probe using an indelible marker.

 5.2.3.2 Assembling the Train

        Assembling the Method 26A sampling train components is begun in the recovery trailer
and final train assembly is performed at the stack location. First, the empty, clean impingers are
                                          5-28

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 assembled and laid out in the proper order in the recovery trailer. Each ground glass joint is
 carefully inspected for hairline cracks. After the impingers are loaded, each impinger is weighed,
 and the initial weight and contents of each impinger are recorded on a recovery data sheet.  The
 impingers are connected together using clean glass U-tube connectors and arranged in the
 impinger bucket.  The height of all the impingers is approximately the same to obtain a leak free
 seal. The open ends of the train are sealed with Parafilm® or clean ground glass caps.

         The second step is to  load the filter into the filter holder in the recovery trailer. The
 filter holder is then capped off  and placed into the impinger bucket. To avoid contamination of
 the sample, sealing greases are not used.  The train components are transferred to the sampling
 location and assembled as previously shown in Figure 5-4.

 5.2.3.3  Sampling Procedures

        After the train is assembled, the heaters are turned on for the probe liner and heated
filter box. When the system  reaches the appropriate temperatures, the sampling train is ready for
pre-test leak checking. The gas stream exiting the heated filter is maintained at a temperature of
 120 ±14°C (248 ±25°F). The filter temperature is initially set at 120 ±14°C (248 ±25°F) and the
probe temperature at 100°C (212°F). The temperature of these two heated zones will be
regulated as necessary to maintain the proper temperature of the gas exiting the filter.

        The sampling trains are leak checked at the start and finish of sampling. (Method 26A
protocol requires post-test leak checks and recommends pre-test leak checks.) ERG protocol also
incorporates leak checks before and after every port change.  An  acceptable pre-test leak rate is
less than 0.02 acfm (ftVmin)  at approximately  15 inches of mercury (in. Hg). If, during testing, a
piece of glassware needs to be emptied or replaced, a leak check  is performed before the
glassware piece is removed, and after the train is re-assembled.

        To leak check the assembled train, the nozzle end is capped off and a vacuum of
15 in. Hg is pulled in the system. When the system is evacuated, the volume of gas flowing

                                          5-29

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 through the system is timed for 60 seconds. After the leak rate is determined, the cap is slowly
 removed from the nozzle end until the vacuum drops off, and then the pump is turned off.  If the
 leak rate requirement is not met, the train is systematically checked by first capping the train at
 the filter, at the first impinger, etc., until the leak is located and corrected.

         After a successful pre-test leak check has been conducted, all train components are at
 their specified temperatures and initial data are recorded (dry gas meter (DGM) reading), the test
 can be initiated.  Sampling train data are recorded periodically (specific interval to be
 determined) on standard data forms. A checklist for sampling is included in Table 5-9.

         The leak rates and sampling start and stop times are recorded on the sampling task log.
 Also, any other events that occur during sampling are recorded on the task log, such as pitot
 cleaning, thermocouple malfunctions, heater malfunctions, or any other unusual occurrences.

         At the conclusion of the test run, the sample pump (or flow) is turned off, the probe is
 removed from the duct, a final  DGM reading is taken,  and a post-test leak check is completed.
 The procedure is identical  to the pre-test procedure; however, the vacuum should be at least
 one inch Hg higher than the highest vacuum attained during sampling. An acceptable leak rate is
 less than 4% of the average sample rate or 0.02 acfm (whichever is lower).  If a final leak rate
 on-site does not meet the acceptance criterion,  the test  run may still be accepted upon approval of
 the EPA test administrator. If so, the measured leak rate is reduced by subtracting the allowable
 leak rate from it and then multiplied for the period of time in which the leak occurred. This
 "leaked volume" is then subtracted from the measured gas volume in order to determine the final
 gas sample volume.

 5.2.4   Method 26A Sample Recovery

        Recovery procedures begin as soon as the probe is removed from the stack and the post-
test leak check is completed.
                                          5-30

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Table 5-9.  Sampling Checklist for EPA Method 26A
Before Test Starts:
         1.    Check impinger set (right order and number). Verify probe markings, and re-
              mark if necessary.

        2.    Check that you have all the correct pieces of glassware.

        3.    Check for data sheets and barometric pressure.

        4.    Sampling equipment needs to be ready for Method 3 analysis.

        5.    Leak check pitot tubes.

        6.    Examine meter box - level it and confirm that the pump is operational.

        7.    Assemble train to the filter and leak check at 15 in. Hg. Attach probe to train
            .  and do final leak check; record leak rate and pressure on sampling log.

        8.    Check out thermocouples - make sure they are reading correctly.

        9.    Turn on heaters and check to see that their temperatures are increasing.

        10.   Check that  cooling water is on and flowing (if required).  Add ice to impinger
              buckets.

        11.   Check isokinetic K-factor - make sure it is correct. (Refer to previous results to
              confirm assumptions).  (Two people should calculate this  independently to
              double check it).

        12.   Have a spare probe liner, probe sheath, meter box and filter ready to go at
              location.
                                         5-31

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Table 5-9.  Sampling Checklist for EPA Method 26A (continued)
During Test:

         1.     Notify crew chief of any sampling problems ASAP. Train operator should fill in
               sampling log.

         2.     Perform simultaneous/concurrent testing with other locations (if applicable).
               Maintain filter temperature at 120 ±14° C (248 ±25° F). Keep temperature as
               steady as possible. Maintain impinger temperatures below 68° F. Maintain
               probe temperature above 100° C (212° F) or as required to maintain the proper
               filter temperature.

         3.     Leak check between ports and record on sampling log.

         4.     Record sampling rate times and location for the fixed gas (CO2, O2) sample
               (if applicable).

         5.     Blow back pitot tubes at inlet location every 15 minutes.

         6.     Change filter if pressure drop exceeds 20 in. Hg.

        7.     Check  impinger silica gel every '/2 hr; if indicator changes color request a pre-
               filled impinger from van lab and replace.

        8.     Check  manometer fluid levels and zero every hour.

After Test is Completed:

         1.     Record final meter reading.

        2.     Check completeness of data sheet.

        3.     Do final leak check of sampling train at maximum vacuum during test.

        4.     Leak check each leg of pitot tubes.

        5.     Disassemble train. Cap sections. Take sections to recovery trailer.
                                         5-32

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 Table 5-9. Sampling Checklist for EPA Method 26A (continued)
         6.    Probe/cyclone recovery (use 500 mL bottles)
                      For acetone rinses (all trains)
                             Attach flask to end of probe (separate recovery containers will be
                             used for each sampling location)
                             Add 50 mL of acetone
                             Put a brush down probe, and brush back and forth
                             Rinse back and forth in probe
                             Empty out acetone in sample jar
                             Do this 3 times so that the final combined acetone rinse volume is
                             < 150 mL.

         7.    Reattach nozzle and cap for next day, store in dry safe place.

         8.    Make sure data sheets are completely filled out and give to location leader.	
         To facilitate transfer from the sampling location to the recovery trailer, the sampling
train is disassembled into three sections: the nozzle/probe liner, filter holder and impingers in
their bucket.  Each of these sections is capped with Teflon® tape or Parafilm® before removal to
the recovery trailer. All train components are rinsed and the samples collected in separate,
prelabeled, precleaned sample containers to avoid cross contamination of inlet and outlet
samples. Trains of each type are recovered in separate areas of the mobile laboratory to avoid
cross contamination or mistakes in recovery sequences.

         Once in the trailers, the sampling train is recovered as separate front and back half
fractions. A diagram illustrating front half and back half sample recovery procedures is shown in
Figure 5-5. No equipment with exposed metal surfaces is used in the sample recovery
procedures.  The weight gain in each of the impingers is recorded to determine the moisture
content in the flue gas.  Following weighing of the impingers, the front half of the train is
recovered, which includes the filter and all sample-exposed surfaces forward of the filter.  The
                                          5-33

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   Probe Liner &
      Nozzle
    Rinse with
      acetone
  Brush liner with
   Teflon  brush
   and rinse with
      acetone
    Rinse with
      acetone
 Front Half of
 Filter Housing
Rinse 3x with
    acetone
       Filter
                F. H.
             Container #2
Remove filter from
support with tweezers
  and place in petri
        dish
                        Brush loose
                    paniculate onto filter
                     Seal petri dish with
                             ®
                       Teflon  tape
                                                   Container #1
Impingers 1 & 2
 (0.1 NH2SO4)
Measure volume
in impingers 1-2
                             Rinse with
                              D.I. water
                                                Container #3
Impingers 3 & 4
   (0.1 NaOH)
 Measure volume
 in impingers 3-4
                       Rinse with
                        D.I. water
                                                  Add 25mg
                                                   Sodium
                                                  thiosulfate
                                                 Container #4
Silica Gel
  Measure
  weight
    gain
                        Discard
Figure 5-5.  Method 26A Sample Recovery Scheme

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 probe liner is rinsed with acetone by tilting and rotating the probe while squirting acetone into its
 upper end so that all inside surfaces are wetted. The acetone will be quantitatively collected into
 the appropriate bottle. This rinse is followed by additional brush/rinse procedures using a non-
 metallic brush; the probe is held in an inclined position and acetone is squirted into the upper end
 as the brush is pushed through with a twisting action. All of the acetone and particulate will be
 caught in the sample container. This procedure is repeated until no visible particulate remains
 and finished with a final acetone rinse of the probe and brush.  The front half of the glass filter
 holder is also rinsed with acetone until all visible particulate is removed.  These rinses are added
 to the probe rinses.  After all front half acetone washes are collected, the cap is tightened, the
 liquid level marked and the bottle weighed to determine the acetone rinse volume.  This sample
 is Container #2. The method specifies that a nominal volume "of 100 mL of acetone must be used
 for rinsing these components.  For blank correction purposes, the exact weight or volume of
 acetone used is measured. An acetone reagent blank of approximately the same volume as the
 acetone rinses is analyzed with the samples.

        The filter is carefully removed from the filter support and placed in a clean,  well-
 marked glass petri dish (Container #  1) and sealed with Teflon® tape.

        After measuring the volume of liquid  in the first four impingers and determining the
 weight gain of the desiccant in the fifth impinger the contents of the first four impingers are
 recovered.

        The contents of the first and second impingers (0.1  N H2SO4) and the water rinses of the
 impingers and connecting glassware are transferred to a separate container labeled "Container
No. 3."  The contents of the third and fourth impingers (0.1 N NaOH) and the water rinses of the
impingers and connecting glassware are transferred to a separate container labeled "Container
No. 4."  Add 25 mg of sodium thiosulfate to Container No. 4 and mix well.  Seal the sample
bottles and package for transport to the laboratory for analysis.
                                          5-35

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         A reagent blank is recovered in the field for each of the following reagents:

         •     Acetone—200 mL sample size;
         •     Filter blank—one each;
               0.1 N H2SO4 - 200 mL sample size; and
         •     0.1 N NaOH - 200 mL sample size, containing 50 mg of sodium thiosulfate.

         Each reagent blank is of the same lot as was used during the sampling program. The
 volumes collected are greater than that required for sample preparation in order to provide
 sufficient amounts in case of sample loss during preparation or to compensate for larger volumes
 of train rinses. Each lot number and reagent grade is recorded on the reagent blank label.

         One field blank was collected at each lime-injected baghouse inlet, and one at each
 lime-injected baghouse outlet. A field blank is generated by preparing a sampling train as if for
 actual sample collection, performing a leak check at the sampling location, then sealing the inlet
 and outlet of the train and leaving it at the sampling location during the length of an actual test
 run.

         One glassware proof blank will  be collected for each train prior to sampling.  A proof
 blank is generated by rinsing the components of a train, prior to use, with the recovery solvent(s)
 specified in the method.

         The liquid level of each sample  container is marked on the bottle in order to determine
 if any sample loss occurred during shipment. If sample loss has occurred, the sample may be
 voided or a method may be used to incorporate a correction factor to scale the final results
depending on the volume of the loss.
                                          5-36

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         Following the protocol of Method 26A, the fractions to be collected for analysis from
 each train are:

         •     Fraction  1—Filter;
         •     Fraction  2—Probe/nozzle/cyclone and filter front half acetone rinses;
         •     Fraction  3 - Contents of Impingers 1 and 2 plus water rinses; and
         •     Fraction  4 - contents of Impingers 3 and 4 plus water rinses.

 5.2.5    HCI Analytical Procedures

         Before analysis, the samples are checked against the chain of custody forms, logged into
 the laboratory sample tracking system, and assigned a laboratory sample number. Each sample is
 then examined to determine  if any leakage occurred and any color or other particulars of the
 samples are noted.

         The samples are analyzed using ion chromatography (1C).  Analytical conditions are
 determined by the type  of analytical column used and whether suppressed or nonsuppressed 1C is
 used. Prior to-sample analysis, a stable baseline is established and water samples are injected
 until no chloride, bromide, or fluoride appears in the chromatogram. The 1C is then calibrated
 using standards spanning  the appropriate concentration range, starting with the standard at the
 lowest concentration. Next,  a check sample is injected in duplicate, followed by a water blank
 and field samples.  The calibration standards are re-injected at the end of the analyses to allow
compensation for any drift in the instrument response during analysis of the field samples.  The
chloride sample concentrations are calculated from either the ion peak area or the peak height
and the calibration curve.
                                          5-37

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 5.2.6   HCI Analytical Quality Control

         The 1C is calibrated with a minimum of three concentrations, not including zero.  A
 correlation coefficient of greater than or equal to 0.995 must be achieved to have an acceptable
 calibration.  At least 10 percent of the total number of samples are analyzed in duplicate. Ion
 concentrations in the duplicates must agree to within ± 20 percent.

 5.2.7   Particulate Analysis

         The general gravimetric procedure described in Method 5, Section 4.3 is followed.
 Both filters and precleaned beakers are weighed to a constant weight before use.  The same
 balance used for taring  is used for weighing the samples. The balance room is maintained at a
 constant temperature and humidity. The preparation and analysis scheme for Method 5 is shown
 in Figure 5-6.  The particulate was determined as part of the Method 26A Train samples.

         The filter (Container #1) is desiccated to a constant weight for a minimum of 24 hours
 and then an initial weighing is performed.  Weight gain is reported to the nearest 0.1 mg. A
 second weight determination is made after again desiccating for a minimum of 6 hours.
 "Constant weight" means a difference of no more than 0.5 mg or 1% of the total weight less tare
 weight,  whichever is greater, between two consecutive weighings made 6 hours apart. Report the
 final weight as the average of these two  values. The filter tare and final weights will be
 determined under the same conditions of temperature and humidity.

        The acetone rinses (Container #2) are transfer to a tared beaker, along with three
 acetone  rinses of Container #2, and evaporated to dryness at ambient temperature, placed in a
 desiccator for 24 hours and weighed to a constant weight. The total volume of acetone used in
preparation of the sample is duplicated for the preparation of a reagent blank.
                                          5-38

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                 Container #1
                  Container #2
                    Filter
        Transfer to tared glass weighing dish
           Desiccate to constant weight
         Determine particulate filter weight
                 Front half rinses
Evaporate to dryness at ambient temperature and pressure
                 in a Tared heaker
                                                                                         I
            Desiccate to constant weight
                                                                                   Determine PM weight
Figure 5-6. Method 5 Preparation and Analysis Scheme (Integral Part of Method 26A)

-------
 5.2.8   Quality Control for Gravimetric Procedures

         All quality control procedures specified in the test method are followed. All field
 reagent blanks are processed and analyzed as specified in the test method. Prior to each
 gravimetric determination, the balance calibration is verified using a series of certified weights
 covering the range of weights encountered for the samples.

 5.3      FTIR EPA Method 320

         The extractive FTIR measurement method is based on continuous extraction of sample
 gas from the stack, transporting the sample to the FTIR spectrometer and performing real-time
 spectral measurement of the sample gas. The sample gas spectra are analyzed in real-time for
 target analytes, archived and possibly re-analyzed at a later date for other target analytes.

 5.3.1    FTIR Sampling Equipment

        The FTIR measurement system met the sampling and analysis requirements set forth in
EPA Draft Method 320, "Measurement of Vapor Phase Organic and Inorganic Emissions By
Extractive Fourier Transform Infrared Spectroscopy". This system has been used with complete
success with many source categories, and can also be adapted to switch quickly between two
sources (i.e., inlet and outlet) with a single FTIR spectrometer.

        The sampling and measurement system consists of the following components:

        •     Heated probe;
        •     Heated filter;
        •     Heat-traced Teflon sample line;
        •     Teflon® coated, heated-head sample pump;
        •     FTIR spectrometer;
                                         5-40

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         •     FTIR sample conditioning system; and
               QA/QC apparatus.

         Figure 5-7 illustrates the FTIR sampling and measurement system. In operation at a
 stationary source, the sample is continuously extracted from the stack through the heated probe.
 Sample gas is then sent into a heated filter assembly which will remove any particulate matter
 from the sample stream to protect the remainder of the sampling and analysis system. The probe
 liner and filter body are made of glass, and the filter element is polytetrafluoroethylene (PTFE or
 Teflon®). In  addition to providing an inert surface, the glass body filter allows the operator to
 observe the filter loading during sampling operations. The probe and filter are contained in a
 heated box which is mounted on the stack and maintained at a temperature of 121 ° C (250° F).

         After passing through the filter assembly, the sample gas is  transported to the FTIR
 spectrometer  by a primary heat-traced PTFE sample line maintained at 149° C (300° F) driven
 by a heated- PTFE head sample pump maintained at 204° C (400° F). The sampling flow rate
 through the probe, filter, and sampling line is a nominal 20 liters per minute (Lpm). Sample gas
 then enters an atmospheric pressure heated PTFE distribution manifold where it is sent to the
 FTIR spectrometer via a slipstream flowing at 9 Lpm. Other slipstreams can be sent to other
 instruments, if necessary. Excess sample gas not used by instruments is vented to atmosphere.

         FTIR spectrometer sample gas is taken from the distribution manifold by a secondary
 heated  PTFE  head sample pump maintained at 204° C (400° F) and directed into the FTIR
 sample cell maintained at 185° C (365° F) for real-time analysis.  The cell is made of nickel-
 plated aluminum,  with gold-plated glass substrate mirrors and potassium chloride windows.
 Exhaust gas from  the cell is vented to the atmosphere.

        Sample conditioning (when  required) is achieved by passing raw sample gas through a
PermaPure® drier  and a series of impingers filled with sodium (or lithium) hydroxide pellets. The
PermaPure® drier  selectively removes water vapor and the sodium hydroxide pellets remove CO2
and other acid gases. The sample conditioning apparatus is switched  into the FTIR sample
                                         5-41

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N)
                                          Heat-traced line
      Sample
      Gas In
                      Spike or QA/QC Gas
                                                                Vaporization
                                                                   block
                                 I
                                                         QA/QC Gas Standard Manifold
                 Main Sample Pump
       Heated Flow Meter
                 Legend
  Bold text and lines = Heated

Normal text and lines = Unheated
                                        Heat-traced line
                                        (up to 100 feet)
6
                                 FPIR
                                 Sample
                                 Pump/
                                 Flowmeter^
                                                                       QA/QC Gas Standards
                                                       Sample Distribution Manifold
                             To Other Instruments
                                                                FTIR Sample Cell
                                                                                                Spiking Solution
                                                                Excess sample to
                                                                atmosphere
                                                                  Exhaust to atmosphere
    Fio"re 5-7. FTIR Sampling and Measurement System

-------
 path by a valving system.  Lower detection limits for some compounds can be achieved with a

 conditioned sample.


 5.3.2   Preparation for Sampling


         The heated sampling lines, probes, and heated filter were positioned at the inlet and

 outlet locations. All heated components were brought to operating temperature, and a leak check

 of both inlet and outlet sampling systems was performed.  The leak check was performed by

 plugging the end of the probe and watching the main sample rotameter to see that the value goes

 to zero.


         A background spectrum was measured using zero air or zero nitrogen through the cell.

 Next the QC gases were measured by flushing the cell and they must agree to  within ±10% of

 target value. The QC gases used for this program included:
               Halocarbon 22, used to calibrate the pathlength. Halocarbon 22 is used for its
               highly linear response due to the lack of sharp spectral features, and is an
               extremely stable compound.

               Carbon monoxide (CO); used for frequency calibration.  Carbon monoxide is
               directly injected into the sample cell to measure photometric accuracy, validity
               of the non-linear correction algorithm  and serve as a frequency (i.e., wavelength)
               calibration. Acceptable limits for CO  standard analysis are ±5 percent of
               certified concentration;

               Methane/nitric oxide/carbon dioxide mixture, used for overall system
               performance check (calibration  transfer standard) (acceptance limits are ±5% of
               the certified concentration); and

               Hydrogen chloride standard, analyzed  to verify the instrumental response of HC1,
               a key target analyte (acceptance limits  are ±10% of certified concentration).
        The sampling and measurement system spike test was used to perform validation and
directly challenge the complete system and provide information on system accuracy and bias.

This test is conducted to satisfy the requirements set in EPA Draft Method 320 entitled


                                          5-43

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 "Measurement of Vapor Phase Organic and Inorganic Emissions By Extractive Fourier
 Transform Infrared Spectroscopy". Section B. l.C of Method 320 gives a description of the
 dynamic spiking apparatus.

         The FTIRS spiking procedure used was the following:

         •      Measure native stack gas for a 5 minute period;
         •      Start spike gas flow into sample stream, upstream of the heated filter;
         •      Let system equilibrate for 5 minutes;
         •      Measure spiked sample stream for 5 minutes;
         •      Turn off spike gas flow;
         •      Let system equilibrate with native stack gas for 5 minutes; and
         •      Repeat cycle, two more times.

         The above procedure produces 3  spiked/unspiked sample pairs per hour. Spike
recovery and three relative standard deviations for 3  spiked/unspiked sample pairs were
computed from the procedure given in Section 8.6.2  of EPA Draft Method 320. The recovery
must be 70-130% and the Percent Relative Standard  Deviation must be less than or equal to 50%
for the method to be valid for this source category.

         The spiked/unspiked pairs are not simultaneously recorded, since only one FTIRS
system will be available, but due to the expected steady nature of the source, this procedure
produced acceptable results.

         The FTIR sampling and analysis system was validated for HCI at the outlet of the chip
dryer baghouse and the  inlet and outlet of the reverberatory furnace #1  and was used as a
screening tool for the other HAPs.
                                          5-44

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 5.3.3   Sampling
         FTIR sampling was performed simultaneously with the manual testing. The start and
 stop times, as well as port change times, were coordinated with the bilk operator, so that FTIR
 data files could be coordinated with manual method start and stop times. FTIR inlet/outlet
 sampling was accomplished using two heated transfer lines, using a valving system to switch
 from one to the other.

        Table 5-10 gives typical FTIR operating conditions. These parameters provide detection
 limits of 0.1-1 ppm for typical FTIR analytes, while providing adequate dynamic range
 (nominally 1-1000 ppm).  Some of these parameters are sample matrix dependent.

 Table 5-10.  Typical FTIR Operating Parameters
Parameter
Spectral Range (cm"1) "
Spectral Resolution (cm"1)
Optical Cell Pathlength (m)
Optical Cell Temperature (° C)
Sample Flow Rate (liters/minute)
Integration Time (minutes)
Value
400 - 4000
0.5 (or better)
3.2 (variable-- 1-10)
185
9 (3.0 optical cell volumes/minute)
1 (Average of 40 spectra)
        Sample flow rate was determined by the data averaging interval and FTIR spectrometer
sample cell volume.  A minimum of 3 sample cell volumes of gas must flow through the system
to provide a representative sample during a single integration period. Typically, a 1 minute
averaging period with a 3 liter volume sample cell gives a minimum flow rate of 9 liters per
minute (LPM). Typically a flow rate of 20 standard Lpm is used to accommodate the FTIR and
other instrumentation on-site, and to minimize sample residence time in the sampling system.
                                         5-45

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         The temperature of all sampling system components were nominally 221-204° F (250-
 400° C) to prevent condensation of water vapor or other analytes in the sampling system.  The
 Kl'lR sample cell temperature was maintained at 365° F (185° C) to ensure that condensation of
 high-boiling point analytes on the cell optics is minimized.

         FTIR sample cell pressure was monitored in real-time in order to calculate analyte
 concentration in parts-per-million. It is normally operated near atmospheric pressure with the
 cell pressure continuously monitored.

         Stack gas temperature was also be monitored to provide information on potential
 sample analyte condensation in the sampling system.  If the stack gas temperature is higher than
 the lowest sampling system component temperature, then an assessment by the spectroscopist or
 field team leader must be made whether any analytes of interest may condense within the
 sampling system, resulting in measurement bias.

         Sampling probe location was determined by the requirements set in EPA Method 1 in
 terms of duct diameters upstream and downstream of disturbances. Concurrent EPA Method 2
 velocity measurements were carried out at the same process stream location as the FTIR
 sampling point to provide mass emission rate determination. The stack gas velocity and flow
 rate were determined by the manual test methods.

         Before testing, sample matrix effects were assessed on-site by the spectroscopist and
 adjustments to the optical pathlength and spectral analysis regions  were made. Once the
 adjustments have been made, they rarely need to be further refined at a given source type.

         Sampling and analysis procedures are straightforward for a single-source measurement.
Once QA/QC procedures have been completed for a given test day, the sample is allowed to flow
continuously through the FTIR spectrometer cell and the software is instructed to start spectral
data collection.  Usually, the spectrometer collects one interferogram per second and averages a
number of interferograms to form a time-integrated interferogram.  Typical averaging times

                                          5-46

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range from 1 to 5 minutes.  The interferogram is converted into a spectrum and analyzed for the
target analytes. After spectral analysis, the spectrum is stored on the computer and later
permanently archived. Spectral data collection is stopped after a pre-determined time,
corresponding to a "run".. Typical runs were 4 hours long, giving 240 one-minute  averaged
points for each target analyte. At the end of the test day, the end-of-day QA/QC procedures were
conducted.

         Before any testing is started at a given site, an initial "snapshot" of the  stack gas is
taken with the FTIR measurement and analysis system to determine the true sample matrix.  If
any target analytes are present at significantly higher levels than expected, adjustments will be
made to the cell pathlength  and/or the spectral analysis regions used for quantitative analysis.
These adjustments will minimize interferences due to  unexpectedly high levels of detected
analytes.
         Since sample conditioning was required for certain analytes, the FTIR spectrometer
divided its analysis time between conditioned and unconditioned samples.  Usually, the analysis
time is split into blocks to minimize dead time due to switching between sample types. For
example, the first half of the run period is dedicated to conditioned samples, and the last half of
the run is committed to unconditioned samples. The order used at Gulp Aluminum Alloys is
shown in the table below.
Sampling
Conditions
Chip Dryer
Unconditioned
Chip Dryer
Conditioned
Furnace
Unconditioned
Furnace
Conditioned
Furnace
Unconditioned
Sampling Time
First half of Test
Second half of
Test
First half of
Charging
Second half of
Charging
Duration of
Mixing Top Out
Inlet
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
Outlet
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
                                          5-47

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         The sample being delivered to the FTIR cell alternated between the inlet and the outlet.
 The switching valve, located just upstream of the common manifold, was manually activated
 every 10 minutes to provide twelve ten-minute sample collections during each two-hour period.

         FTIR method performance is gauged from the results of the QA/QC procedures given in
 Section B5 of Draft EPA Method 320. Acceptable spiking tests must meet acceptance criteria of
 50 percent relative standard deviation (RSD) and accuracy of within ± 30 percent. The
 acceptable instrument diagnostic and system response check accuracy must be within ± 5 percent
 of target. Acceptable system response check precision was 5 percent RSD.

         The ERG validated spectral database includes the compounds shown in Table 5-11.
 These spectra were validated in the laboratory at a cell temperature of 185° C against certified
 gaseous standards.  Any compounds identified in the stack gas and not included in the ERG
 database can be quantified if necessary after subsequent laboratory spectral acquisition.

 5.3.4  FTIR Method Data Review, Validation, and Verification Requirements

       Quantitative analysis is performed by a mathematical method called multi-variate least
squares (commonly known as Classical Least Squares or CLS). CLS  constructs an optimized
linear combination  (or 'fit') of the reference spectra to duplicate the sample spectrum,  utilizing
the Beer-Lambert Law. The Beer-Lambert Law states that the absorbance of a particular spectral
feature due to a single  analyte is  proportional to  its concentration.  This relationship is  the basis
of FTIR quantitative analysis.  The coefficients of each compound in the linear fit yield the
concentration of that compound. If it is found that the quantitative analysis of a given compound
responds non-linearly to concentration, a calibration curve is developed by measuring a series of
reference spectra with  differing optical depths (concentration times pathlength) and using them
in the linear fit. Low molecular weight species such as water vapor and carbon monoxide
require non-linear correction, possibly even at levels as low as 100  ppm-meters (concentration
times pathlength). Analytes greater than 50-60 amu molecular weight usually do not require non-
                                          5-48

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Table 5-11.  Compounds for Which Reference FTIR Spectra Are Available in the
ERG Spectral Library3
1,3-butadiene
1-butene
2-methyl-2-propanol
2-methylbutane
2-methoxyethanol
2-methyIpropane
2-propanol
4-vinylcyclohexane
acetic acid
acetone
acrolein
benzene
acetylene
c/.y-2-butene
fra/i5-2-butene .
ethylene
ethane
propylene
propane
chlorobenzene
acetaldehyde
methanol
methane
carbon monoxide
carbon dioxide
cyclopropane
cvclopentane
cyclohexane
ethylbenzene
formaldehyde
water vapor
hydrogen chloride
hydrogen fluoride
isobutylene
methylene chloride
methyl ethyl ketone
m-xylene
p-xylene
o-xylene
phenol
o-cresol
m-cresol
/7-cresol
nitrous oxide
n-butane
/i-butanol
ammonia
nitric oxide
nitrogen dioxide
H-pentane
carbonyl sulfide
sulfur dioxide
styrene
toluene
' Spectra were collected at a cell temperature of 185° C.
                                     5-49

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linear corrections. An experienced spectroscopist can determine whether non-linear corrections

are necessary for an analyte in a given source testing scenario.


       The following procedures were conducted to review the FTIR data:

A.     Post-test Data Review procedure (on-site)

       1.      Examine the concentration vs. time series plot for each compound of interest, and
              identify regions with the following characteristics:

              •       sudden change in concentration;

              •       unrealistic concentration values;

              •       significant changes in 95 percent confidence intervals reported by
                     software; and

              •       sudden increase of noise in data.

       2.      Select representative spectra from the time periods indicated from Step 1.

       3.      Subtract from each representative spectrum chosen in Step 2 a spectrum which
              was taken immediately prior in time to the indicated time region.

       4.      Manually quantitate (including any non-linear corrections) for the species in
              question and compare the result to. the difference in software-computed
              concentrations for respective spectra.

       5.      If concentration values in Step 4 do not agree to within 5 percent, determine
              whether the difference is due to a recoverable or non-recoverable error.

       6 (i).   If the error is non-recoverable, the spectra in the indicated time region are
              declared invalid.

       6 (ii).   If the error is recoverable, and time permits, determine possible source(s) of error
              and attempt to correct. If time is critical, proceed with measurement. If
              correction is achieved, conduct QA/QC checks before continuing.

       7.      Determine the peak-to-peak scatter or the root mean square (RMS) noise-
              equivalent-absorbance (NEA) for the representative spectra.

       8.      If the NEA exceeds 1  x 10"3 absorbance units, the spectra in the time region are
              declared invalid (due to non-recoverable error).

       9.      Data found invalid are subject to re-measurement.

                                          5-50

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 B.    Final Data Review (off-site)

       The procedures for final data review included those given above; however, if a non-
 recoverable error was found during this phase, the data were considered invalid. In addition, the
 following procedures were carried out by the spectroscopist to perform a final data validation:
        1.     If any recoverable data errors are detected from the procedure, determine the
              cause and perform any necessary corrections.
       2.     For analytes which were not detected or detected at low levels:
              a) estimate detection limits from validated data;
              b) check for measurement bias.
 5.3.5 QCfortheFTIR

       The FTIR QA/QC apparatus was used to perform two functions:

       •      Dynamic analyte spiking; and
       •      Instrumental performance checks.

       Dynamic analyte spiking is used for quality control/quality assurance of the complete
sampling and analysis system. Dynamic spiking is continuous spiking of the sample gas to
provide information on system response, sample matrix effects, and potential sampling system
biases. Spiking is accomplished by either:

       •       Direct introduction of a certified gas standard; or
              Volatilization of a spiking solution.

       Certified gas standards are preferred due to simplicity of use, but many target analytes
cannot be obtained as certified gas standards, and must be spiked using standards generated by
volatilized solutions.
                                          5-51

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       Gaseous spiking is carried out by metering the spike gas into the sample stream at a
known rate. Spike levels are calculated from mass balance principles.  When certified gas
standards are used, a dilution tracer, such as sulfur hexafluoride, is used to directly measure the
fraction of spike gas spiked into the sample. This technique can be used instead of mass balance
calculations.                                                               .       "

       Before any testing is started at a given site, an initial "snapshot" of the stack gas is taken
with the FTIRS measurement and analysis system to determine the true sample matrix. If any
target analytes are present at significantly higher levels than expected, adjustments will be made
to the cell pamlength and/or the spectral analysis regions used for quantitative analysis.  These
adjustments will minimize interferences due to unexpectedly high levels of detected analytes.

       FTIRS method performance is gauged from the results of the  QA/QC. Acceptable
spiking tests will meet Method 301 criteria (i.e., 50 percent relative standard deviation (RSD)
and accuracy of within ± 30 percent) or a statistical equivalent when less than 12 spiked/unspiked
pairs are collected. The acceptable instrument diagnostic and system response check accuracy
will be within ± 5 percent of target. Acceptable system response check precision will be
5 percent RSD.
                                          5-52

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6.0    QUALITY ASSURANCE/QUALITY CONTROL

       Specific Quality Assurance/Quality Control (QA/QC) procedures were strictly followed
during this test program to ensure the production of useful and valid data throughout the course
of the project. A detailed presentation of QC procedures for all sampling and analysis activities
can be found in the Site Specific Test Plan and Quality Assurance Project Plan for this project.
This section reports all QC results so that the data quality can be ascertained.

       In summary, a high degree of data quality was maintained throughout the project.  All
train leak checks met the QC criteria as specified in the methods. Isokinetic sampling rates were
kept within 10% of 100% for all test runs. Acceptable spike recoveries and close agreement
between duplicate analyses were shown for the sample analyses: The data completeness was
better than 95%.                             .

6.1    Sampling QC Results

       The following sections discuss the QC results of the sampling methods employed during
this project.

6.1.1  Leak Checks

       Tables 6-1 and 6-2 list the pre- and post-test and port change leak checks results for the
chip dryer and furnace tests. The acceptance criterion that all post-test leak checks must be less
than 0.02 cfm or 4 percent of the average sampling rate (which ever is less) at the highest
vacuum achieved during sampling was met for all test runs.
                                         6-1

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Table 6-1.  Summary of Dioxin/Furan Test Leak Check Results
Location
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
Run#/
Port
I/A
1/B
I/A
1/B
2/A
2/B
2/A
2/B
3/A
3/B
3/A
3/B
I/A
1/B
I/A
1/B
2/A
2/B
2/A
2/B
3/A
3/B
3/A
3/B
4/A
4/B
4/A
4/B
Initial Leak
Check
0.018@15"

0.006@15"

0.02@15"

0.016@23"

0.00@10"

0.00@14"

0.01 @ 10"

0.018@16"

0.01 @ 12

0.018@15"

0.01 @ 11"

0.015@ll"

0.01 @ 10"

0.01 1@ 10"

Port
Change
0.01 @ 10"
0.01 @ 10"
0.008 @23"
0.01 @23"
0.01 @ 10"
0.01 @ 10"
0.016@21"
0.018@18"
0.01 @ 10"
0.01 @ 10"
0.00@11"
0.00@H"
Not Recorded
Not Recorded
0.008® 8"
0.008 @8"
Not Recorded
Not Recorded
0.005 @ 10"
0.005 @ 10"
Not Recorded
Not Recorded
0.00@7"
0.00@7"
0.015@15"
0.015@15" .
0.006@5"
0.006@5"
Final Leak
Check

0.01 @ 15"

0.005 @ 8"

0.01 @ 15"

0.01 @8"

0.01 @ 10"

0.003 @ 10"

0.00@10"

0.006@7"

0.005@11"

0.00@10"

0.005@5"

0.00@6"

0.005® 10"

0.004® 8"
                                   6-2

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Table 6-2. Summary of HCI/PM Test Leak Check Results
Location
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
Run#/
Port
I/A
1/B
I/A
1/B
2/A
2/B
2/A .
2/B
3/A
3/B
3/A
3/B
I/A
1/B
I/A
1/B
2/A
2/B
2/A
2/B
3/A
3/B
3/A
3/B
4/A
4/B
4/A
4/B
Initial Leak
Check
0.01@10"

0.01 1@ 13"

0.01 @ 15"

0.01 @ 15"

0.01 @ 10"

0.005 @ 14"

0.01 @ 10"

0.02@15"

0.01 @9"

0.005 @ 10"

0.01 @ 10"

0.004@ 10"

0.02 @ 12"

0.012@9"

Port
Change
0.01@10"
0.01 @ 10"
Not Recorded
Not Recorded
0.01 @ 10"
0.01 @ 10"
0.009@7"
0.009@7"
0.01 @ 10"
0.01 @ 10"
0.00@6"
0.00@6"
0.01 @ 10"
0.01 @ 10"
0.016@6"
0.016@6"
Not Recorded
Not Recorded
0.00@8"
0.00@ 10"
Not Recorded
Not Recorded
0.00@5"
0.00@5"
0.01 @ 10"
0.01 @ 10"
0.009@9"
0.009@9"
Final Leak
Check

0.01 @ 15"

0.00@13"

0.01@10"

0.007@11"

0.01 @ 10"

0.0046® 8"

0.00@12"

0.004 @ 8"

0.01 @ 10" •

0.008@8"

0.005 @ 10"

0.00@5"

O.OI5@12"

0.00@7"
                                  6-3

-------
6.1.2  Percent Isokinetics

       Table 6-3 presents the isokinetic sampling rates percentages for the D/F and HC1/PM
sampling runs.  The acceptance criteria that the average sampling rate must be within 10% of
100% isokinetic was met for all sampling runs.

Table 6-3. Summary of Isokinetic Percentages
Location/Method
CD Inlet D/F


CD Outlet D/F


CD Inlet HC1/PM


CD Outlet HC1/PM


RF Outlet D/F



RF Inlet D/F



RF Outlet HC1/PM



RF Inlet HC1/PM



Run#
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
Percent Isokinetic
97.5
101
98.4
102
98.5
96.9
104
100
101
102
101
103
97.9
98.3
98.5
96.9
101
102
101
101
96
103
103
102
102
102
101
106
                                        6-4

-------
 6.1.3 Meter Box Calibrations

       All dry gas meters are fully calibrated every six months against an EPA approved
 intermediate standard. The full calibration is used to correct the actual metered sample volume
 to the true sample volume.  To verify the full calibration, a post-test calibration is performed.
 The full and post-test calibrations must be within 5% to meet ERG's internal QA/QC acceptance
 criterion.  As shown in Table 6-4, the dry gas meters used for this testing met this criterion.

 Table 6-4. Dry Gas Meter Post-Test Calibration Results
Sampling
Train1
D/F CD Outlet
D/F CD Inlet
HC1 CD Outlet
HC1 CD Inlet
D/F RF Outlet
D/F RF Inlet
HC1 RF Outlet
HC1 RF Inlet
Meter Box #
A-38
A-40
A-37
A-39
A-37
A-39
A-38
A-40
Full Calibration
Factor
0.981
0.98
0.988
0.994
0.988
0.994
0.981
0.98
Post-Test
Calibration
Factor
0.978
0.979
0.995
0.974
0.995
0.974
0.978
0.979
Post-Test2
Deviation, %
-0.30
-0.10
-0.70
-2.00
-0.70
-2.00
-0.30
-0.10
'CD=Chip Dryer, RF=Reverberatory Furnace
2Post-Full x  100
  Full

6.1.4  Field Blank Results

       Field Blanks are collected to determine the level, if any, of sample contamination
resulting from the exposure of the sampling train to ambient conditions in the vicinity of the
sampling locations or to sample "carry over" from one run to the next. A field blank train for
each test method and for each location was assembled as if for sampling, leak checked at the
                                          6-5

-------
 sampling location, left at the sampling location for the duration of a test run and then recovered.
 The samples were returned to the laboratory for analysis along with the test samples. The results
 of the analysis for the Method 26A field blanks are shown in Table 6-5. A small amount of HC1
 was detected in the Chip Dryer field blank, but represents less than 1% of the amount detected in
 most of the test samples and less than 5% of that detected in all samples. Because the level of
 contamination was so low, no blank corrections were made on the emission results.  No HC1
 above the instrument detection  limit was detected in  the furnace field blanks.

 Table 6-5.  Method 26A Field Blank Analysis  Results, |jg Detected
Location
Chip Dryer Inlet
Chip Dryer Outlet
Reverberatory Furnace Inlet
Reverberatory Furnace Outlet
Mg HC1 Detected
20.0
Not Required
< 14.0
< 14.0
       Table 6-6 shows the results of the analysis of the D/F field blanks.  The levels detected in
the blank are less than 1% of that detected for any congener in the chip dryer inlet samples and
less than 1% for most and less than 5% for all detected in the chip dryer outlet samples except for
OCDD and OCDF. The levels detected in the furnace inlet field blank were less than 1% for
most congeners and less than 5% for all except for 2,3,7,8-TCDD and 1,2,3,7,8-TCDD which
were less than  10%. Trace amounts of all but three congeners were detected in the furnace outlet
field blank.  Of the ones detected all but seven were less than 5 times the detection limit and the
others were less than 10 times  the detection limit. All but six of the congeners were at levels
equivalent to those found in the furnace outlet samples and all were detected at levels less than
one nanogram.. Since the levels detected were insignificant, no blank correction to the data was
performed.                                     .
                                          6-6

-------
Table 6-6.  Method 23 Field Blank Analysis Results, ng Detected
Congener
2,3,7,8 -TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD

2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2.3,7.8.9-HxCDF

1,2,3,4,6,7,8-HpCDF

1,2,3,4,7,8,9-HpCDF

1,2,3,4.6,7,8,9-OCDF
Chip Dryer Inlet
<0.006
0.04
0.02
0.04
0.05
0.12
0.25

0.45
0.14
0.22
0.31
0.12
0.14
0.02

1.2

0.17

0.41
Furnace Inlet
0.07
0.48
0.26
0.46
0.57
1.2
0.65

7.6
1.7
2.9
6.0
2.3
2.4
0.15

6.1

0.72

1.5
Furnace Outlet
<0.004
0.02
<0.01
0.02
0.03
<0.09
0.16

0.29
0.07
0.12
0.23
0.09
0.12
<0.007

0.43

<0.05

0.31
6.1.5 FTIR Sampling Quality Control






      FTER sampling system quality control procedures used in this test program were:






      •      Sampling system leak check;




      •      Dynamic spiking (also analytical quality control); and




      •      Monitoring of all pertinent system temperatures and flow rates.
                                        6-7

-------
 Sampling system leak checks were carried out before and after each run.  The leak check
 procedure used is identical to that given in EPA Method 320.  The sample gas inlet to the probe
 was covered and the total sample flow rate rotameter was monitored to observe zero flow
 (i.e., indicator ball sits on bottom of scale). In all cases in this program, the system passed both
 before and after run leak checks for all runs performed.

       Dynamic spiking was carried out to test the complete FTIR sampling and analysis system.
 Spiking was carried out twice daily on both inlet and outlet for HC1, and three EPA Method 301
 validation tests were carried out.  The Method 301 tests were carried out on the following
 locations:

       •       Chip dryer outlet;
       •       Furnace hood inlet; and  ,
       •    .   outlet.

Method 301 validation results are given in Section 2.5.2.1. Daily spiking results are given below
in Section 6.2.4.

       To insure that the sampling system was performing correctly during all measurement
operations, selected temperatures and flows were monitored during each run. Temperature data
were recorded every 15 minutes on a data sheet. Sample flows were monitored but not recorded.
The following data were monitored or recorded:

       •      Inlet/outlet stack temperature;                                 .
       •      Inlet/outlet probe temperature;
       •      Inlet/outlet filter temperature;
       •      Inlet/outlet heat-traced sample line temperature;
       •      Inlet/outlet main sample pump head temperature;
                                          6-8

-------
       •      FTIR sample pump head temperature;
       •      Sample pump enclosure temperature;
       •      Sample manifold temperature;
       •      Controller electronics box temperature;
       •      Heated sample line jumper temperature(2);
       •      Main sample flow rate;
       •      FTIR sample flow rate; and
       •      Excess sample flow rate.

FTIR cell temperature was controlled at 185°C sample gas temperature (not cell wall
temperature), and cell  pressure was recorded. No unusual readings of any parameter were found
during testing.

6.2    Analytical Quality Control Results

6.2.1  D/F Analytical Quality Control

       All quality control procedures specified in the test method were followed. Blanks were
used to determine analytical contamination, calibration standards were used for instrument
calibration and linearity checks, internal standards were used to determine isomer recoveries and
adjust response factors for matrix effects, surrogate standards were used to measure the
collection efficiency of the sampling methodology and an alternate standard was used as a
column efficiency check.

6.2.1.1 D/F Quality Control Blanks

       Reagent blanks of 500 mL of each liquid reagent used at the test site were saved for
analysis.  Each reagent blank was of the same lot as was used during the sampling program.

                                         6-9

-------
 Each lot number and reagent grade was recorded on the field blank label and in the laboratory
 notebook (acetone, methylene chloride, toluene, filter, XAD-2®). Two reagent blanks were
 collected in the field. The analysis results showed the absence of any analytes, at the detection
 limit, for approximately half of the congeners with the remaining being detected at less than 5
 times the detection limit. These insignificant amounts are most likely due to laboratory
 contamination.

 6.2.1.2  Quality Control Standards

       Recoveries of the internal standards must be between 40 to 130% for the tetra- through.
 hexachlorinated compounds and in the range of 25 to 130% for the hepta- and octachlorinated
 homologs. These requirements were met for all of the D/F samples except for  the following:
 chip dryer inlet Run 1,  isotopically labeled HpCDD (134%).

       Surrogate standard recoveries must be between 70 to 130%. The recoveries of all
 standards met this requirement except for the following: isotopically labeled HxCDD for chip
 dryer outlet run 1 (158%), chip dryer outlet run 2 (137%) and chip dryer outlet  run 3 (142%).
 These % recoveries were all just outside of the recovery limits and will not have an effect on the
 analysis results.

 6.2.2  HCI Analytical Quality Control

       The IG is calibrated with a minimum of three concentrations, not including zero.  A
 correlation coefficient of greater than or equal to 0.995 must be achieved to have an acceptable
 calibration. At least 10 percent of the total number of samples are analyzed in duplicate. Ion
 concentrations in the duplicates must agree to within ± 20 percent.  All QC results were within
 the acceptance criteria

       Reagent blanks  were collected in the field and returned to the laboratory for analysis.
HCI, as Cl'1, was not detected in any of the blanks at the detection limit.

                                          6-10

-------
       Every sample was analyzed in duplicated with the relative percent difference for every
sample duplicate less than 5.

       A matrix spike  and matrix spike duplicate analysis was performed on the chip dryer outlet
run 1 sample. The percent recoveries were  106 and 104, respectively.

6.2.3 Quality Control for Gravimetric Procedures

       All quality control procedures specified in-the test method are followed. All field reagent
blanks were processed  and analyzed as specified in the test method. Prior to each gravimetric
determination, the balance calibration was verified using a series of certified weights covering
the range of weights encountered for the samples.

6.2.4 FTIR Analytical Quality Control

       Dynamic analyte spiking was used for quality control/quality assurance of the complete
sampling and analysis system. Dynamic spiking is continuous spiking of the sample gas to
provide information on system response, sample matrix effects, and potential sampling system
biases. Spiking was accomplished by direct introduction of a certified gas standard.

       Gaseous spiking was carried out by metering the spike gas into the sample stream at a
known rate. A sulfur hexafluoride dilution tracer was used to directly measure the fraction of
spike gas spiked into the sample. EPA Method 320 limits the dilution of the sample gas to
10 percent.

       Before any testing was started at a given site, an initial "snapshot" of the stack gas is
taken with the FTIR measurement and analysis system to determine the true sample matrix. If
any target analytes are present at significantly higher levels than expected, adjustments were
made to the cell pathlength and/or the spectral analysis  regions used for quantitative analysis.
These adjustments minimized interferences due to unexpectedly high levels of detected analytes.

                                          6-11

-------
       FTIR method performance is gauged from the results of the QA/QC.  All spiking tests
met Method 301 criteria (i.e., 50 percent relative standard deviation (RSD) and accuracy of
within ± 30 percent). The acceptable instrument diagnostic and system response check accuracy
will be within ± 6 percent of target.

       Analytical QC checks for the FTIR system consisted of the following:

       •      Dynamic spiking of HC1;
       •      direct measurement of a HC1 gas standard;
       •      direct measurement of a CO gas standard; and
       •      direct measurement of a CH4, NOX, and CO2 standard.

Dynamic spiking runs were conducted twice daily: before and after testing. Three
spiked/unspiked data pairs were collected. Statistical calculations consistent with EPA Method
301 were performed on the data. Recovery of 70-130 percent and less than 50 percent RSD were
the acceptance criteria.  Table 6-6 summarizes the dynamic spiking results. All dynamic spiking
tests met the above acceptance criteria. In all runs, sample gas was  diluted 10 percent or less.

       Direct instrumental measurement of HC1, CO, and a CH4, NOX and CO2  mixture was
conducted before and after daily testing activities.  Acceptance criteria are normally ±6 percent of
target, using EPA protocol gases.  However, since the HC1 standard was  obtained at a ±5 percent
analytical tolerance, the acceptance criteria was set at ±10 percent. FTIR NOX is measured as NO
+ NO2. Examination of Tables 6-7 through 6-9 shows that all QC checks met the above criteria.
                                         6-12

-------
Table 6-6.  QC Spiking Results
Run
1
1
2
2
3
3
4
5
6
6
7
7
8
8
9
9
10
10
11
12
13
13
14
14
Date
12/5/97
12/5/97
12/5/97
12/5/97
12/6/97
12/6/97
12/6/97
12/6/97
12/8/97
12/8/97
12/8/97
12/8/97
12/9/97
12/9/97
12/9/97
12/9/97
12/10/97
12/10/97
12/10/97
12/10/97
12/11/97
12/11/97
12/11/97
12/11/97
Time
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
Inlet/outlet
outlet
inlet
outlet
inlet
inlet
outlet
outlet
inlet
outlet
inlet
outlet
inlet
inlet
outlet
inlet
outlet
inlet
outlet
inlet
outlet
inlet
outlet
inlet
outlet
% Recovery
97.61
112.85
102.62
98.09
93.71
101.91
105.34
103.53
99.97
96.34
95.40
89.50
94.54
100.85
106.45
103.16
96.21
103.44
104.00
110.78
101.36
102.84
107.16
118.67
Sample gas dilution was held to 10 percent or less in all runs.
                                        6-13

-------
 Table 6-7. HCI Gas Standard Analysis Results
Date
. 12/3/97
12/3/97
12/4/97
12/5/97
12/5/97
12/6/97
12/6/97
12/6/97
12/7/97
12/7/97
12/8/97
12/8/97
12/9/97
12/9/97
12/10/97
12/10/97
12/11/97
12/11/97
Time
9:38:24
14:52:23
7:26:33
7:27:29
15:45:50
7:04:56
14:13:21
21:16:03
12:25:31
20:15:53
8:21:37
16:41:13
8:27:25
19:32:06
10:42:01
18:11:01
4:54:59
13:41:01
Result(ppm)
219.7
222.0
217.3
220.5
223.1
224.5
222.9
218.8
216.3
217.0
221.7
218.3
222.1
221.2
215.3
221.4
221.0
212.9
% Recovery
104.6
105.7
103.5
105.0
106.3
106.9
106.1
104.2
103.0
103.3
105.6
104.0
105.8
105.3
102.5
105.4
105.2
101.4
Comments


no testing on
12/4/97















HCI Target: 210ppm
Gas Standard Accuracy: ±5 percent
Acceptance Criteria: ±10 percent of target
                                       6-14

-------
Table 6-8. CO Gas Standard Analysis Results
Date
12/3/97
12/3/97
12/4/97
12/5/97
12/5/97
12/6/97
12/6/97
12/7/97
\2I1 191
12/8/97
12/8/97
12/9/97
12/9/97
12/10/97
12/10/97
12/11/97 -
12/11/97
Time
9:32:55
14:47:42
7:21:45
7:23:00
15:38:26
7:02:07
21:13:08
12:21:32
20:12:12
8:18:46
16:37:33
8:21:25
19:28:43
10:39:04
18:08:03
4:53:14
13:38:05
Result(ppm)
103.0
103.2
101.8
102.5
103.5
104.0
102.3
100.8
100.8
103.5
101.5
101.2
102.8
101.3
102.9
104.2
99.9
% Recovery
100.6
100.8
99.5
100.2
101.2
101.7
100.0
98.6
98.5
101.2
99.2
99.0
100.4
99.0
100.6
101.9
97.6
Comments


no testing on
12/4/97














CO Target: 102.3 ppm
Gas Standard Accuracy: ±1 percent
Acceptance Criteria: ±6 percent of target
                                       6-15

-------
Table 6-9.  CH4, NOX, and CO2 Gas Standard Analysis Results
Date
12/3/97
12/3/97
12/4/97
12/5/97
12/5/97
12/6/97
12/6/97
12/7/97
12/7/97
12/8/97
12/8/97
12/9/97
12/9/97
12/10/97
12/10/97
12/11/97
12/11/97
Time
9:28:22
14:40:13
7:17:04
7:15:23
15:34:43
6:58:08
21:09:53
12:15:26
20:09:07
8:14:50
16:31:29
8:17:58
19:25:11
10:37:01
18:06:04
4:51:19
13:36:01
CH4
Result
(ppm)
488.0
488.4
485.0
488.3
492.4
491.6
489.7
490.7
485.9
491.0
489.2
485.0
486.7
482.6
485.9
489.4
488.7
CH4
% Recovery
99.4
99.5
98.8
99.5
100.3
100.1 .
99.7
99.9
99.0
100.0
99.6
98.8
99.1
98.3
99.0
99.7
99.5
No,
Result
(ppm)
503.3
500.0
492.5
498.9
503.3
505.9
493.9
492.3
487.6
499.8
492.5
488.9
498.5
492.4
496.2
503.4
472.6
No,
% Recovery
100.1
99.4
97.9
99.2
100.1
100.6
98.2
97.9
96.9
99.4
97.9
97.2
99.1
97.9
98.6
100.1
94.0
NO
Result
(ppm)
463.8
499.6
492.1
498.9
503.3
505.9
493.9
492.3
487.6
499.8
492.5
488.9
498.5
492.4
496.2
503.4
472.6
NO,
Result
(ppm)
39.4
0.4
0.3
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
CO,
Result(%)
4.88
4.74
4.73
4.88
4.81
4.85
4.93
4.97
4.69
4.97
4.93
4.83
4.76
4.73
4.67
4.86
4.84
CO,
% Recovery
97.8
95.1
94.8
97.9
96.4
97.2
98.7
99.5
94.0
99.6
98.9
96.9
95.5
94.8
93.5
97.4
97.0
Comments


no testing
on 12/4/97














 CH4 Target=    491 ppm
 NO, Target=    503 ppm
 CO2Target=    4.99%
 Gas Standard Accuracy: ±1 percent
 Acceptance Criteria: ±6 percent of target

-------
                                Appendix A



                             Field Data Sheets
cah/A:\APPX-CVRWP6

-------
Facility:          Gulp Alum. Alloy
Date:            12/05/97
Location:        Dryer In
Run Number:              1
Sample Type:    M26	
Total Sampling Time (min)                                                   240.0
Corrected Barometric Pressure (in Hg)                                        29.39
Absolute Stack Pressure (in Hg)                                              29.02
Stack Static Pressure (in H2O)                                                -5.00
Average Stack Temperature (°F)                                            244.13
Stack Area (sq in)                                                          240.53
Actual Meter Volume (cu ft)                                                 70.339
Average Meter Pressure (in H2O)                                             0.24
Average Meter Temperature (°F)                                             60.00
Moisture Collected (g)                                                      110.10
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   20.0
Nitrogen Concentration (%V)                                                  79.5
Dry Gas Meter Factor                                                      0.9940
Nozzle Diameter (in)                                                        0.131
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.291
Standard Metered Volume (dscf)                                          - 69.785
Standard Metered Volume (dscm)                                         ..  1.976
Stack Moisture (%V)                                                         6.92
Mole Fraction Dry Stack Gas                                                 0.931
Dry Molecular Weight                                                       28.88
Wet Molecular Weight                                                       28.13
Stack Gas Velocity (fpm)                                                  4428.45
Stack Gas Velocity (mpm)                                                 1349.79
Volumetric Flow Rate (acfm)                                               7396.99
Volumetric Flow Rate (acmm)                                               209.48
Volumetric Flow Rate (dscfm)                                              5007.09
Volumetric Flow Rate (dscmm)                                              141.80
Percent Isokinetic                                                          103.63
Percent Excess Air                                                       1992.23
 Concentration (g/dscm)                                                      0.00
 Concentration (kg/hr)                                                        0.00
 Concentration (ppmv)                                                        0.00
 Emissions (Ib/hr)	                              0.00

-------
         Eastern Research Group. Inc.
                                             MODIFIED METHOD 5 DATASHEET
                                                                                                                         Run
                                                                                                                         Page 1 of
Plant tio.ll)
Date
Operator
Sampling Location T>UV£>
' i?jwcw/w (in
UoL
\
2rt" -•£.&
7-4, '*?
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
«S\
rg *ju
H-'6Llrt5
">VZ>
NlA


61
Meter Box Number
Meter delta H @
PGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A^l
1-TZ-
• ^V^t
«i^5\
M *r
t;n >
^^n
.,,v
r?.~s/ A- ii-LO^I.^L^ DlagramofDud
                                                       Schematic of Traverse Point Layout
                                                        Read and record all data every ^S__ minutes
 Traverse
   Point
 Number
      Sampling
        Time
        (mln)
            0
Clock
Time
(24hr)
   Gas
  Meter
 Reading
 ((Vm).ft3)
 Velocity
  Head
((delta Ps).
 in.H20)
Stack
 Ts
 CF)
 Orifice Pressure
   Differential
 (delta H. in.H2O)
Desired    Actual
Probe
Temp.
 (•F)
 Filter
Temp.
 (•F)
Adsorbent
  Trap
 Temp.
                                                                                                              Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  CF)
 Pump
Vacuum
 (in.Hg)
     '
                     it
                                                                            •3- "50
                                                                                                                      ST3
                                                                                                                           ac-
            /r
               aO^O
                                            .3
                                             3
                                          \
                                                Z3S

                                                                                                                               ^
           HfO
                                                                                                  ft
                                           (1,
                                                                                                                            H-7
ji
                              42-.
                                                                         2-?
                                                                                                                   SN
                                                                        .2.3
                                                                                                                                       i-
           L/"
                                                                                                                                    v-s
                    \\3
-------
                    Plant
                    Date
                                 Location
                                 Sample Type
                                                                             Run Number
                                                                             Operator
                                                                                                                                    Page
 Traverse
   Point
 Number
Sampling
 .Time
  (min)
                Clotk
                Time
                (24hr)
 Meter
Reading
 Velocity
  Head
((delta Ps),
 in.H20)
Stack
 Ts
 (T)
Orifice Pressure
  Differential
(delta H, in.H2O)
                                Desired
Actual
Probe
Temp.
 (•F)
 Filter
Temp.
•CF)
                            Adsorbent
                              Trap
                             Temp.
                                                                                                                     Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  (eF)
 Pump
Vacuum
 (in.Hg)
  B 1
                                                                 ."Z.
                                                                                                                                      S/
                                    IL
                                                                  11
                     no*
                                                                 .IB
                                                                                                                      si
                                  LLL
                                                                            -TA
                                                                            .-7,1
             LOT
                                   \-\
                                                                                                                                SI
                                              l-l
                                                                            :T,\
                                                                                    -Z.
                                                                                                                    c-0-
                                                                                                                                               / .
                                               (1
                                                                                                         I5"
                                                                                                                                           -r
                                               10
                                                                                                                                      /.r
                                                                                                                                                rr
                                                                                                 ? T
                                                                                                                                      t-r-
                                                                                                                             (O
                                                                                                                                     (.5-
                                                                                                                                                \ ,
J5
                                                                            -Z
                                                                                                                   UO
                        *
                                                                                      25
                                                                                                                    GO
            -2.40
                                                                                    ./TD.C
Comments:

-------
                                  frt
    :n Group, inc.
           MOISTURE RECOVERY FORM FOR METRO
Plant
Date
Sampling Location
SampleType
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P.I Q 1 ' Q ii
^ -IxJrt M \\: _IY\ i fS i Lf-rA I*11lnV5

r> L' /\ Ti L ~t— ^f
L ./i '.^ / JA ji°r- • no/?rvv i<*» i r\ (^ 1

^P1 ' *

no.rr AJnU /Tt^V C,.wi<'.n
7

//q'(^97-jQ

Impinger
Number
Impinger
Solution
Amount of
 Solution
   (g)
Impinger Tip
Configuration
                                                Impinger Weight
Final
Initial
 (9)
Weight
 Gain
            O.i V
              Hf r~\
            z.^^n
                                                             31.3
           /S/c^CH
                                                     77..T
                     (CD
                            0"
                                 Total Weight Gain (g)

-------
Facility:          Gulp Alum. Alloy
Date:            12/06/97
Location:         Dryer In
Run Number:             2
Sample Type:     M26    	
Total Sampling Time (min)                                                   240.0
Corrected Barometric Pressure (in Hg)                                        29.51
Absolute Stack Pressure (in Hg)                                              29.14
Stack Static Pressure (in H2O)                                               -5.00
Average Stack Temperature (°F)                                             238.46
Stack Area (sq in)                                                         240.53
Actual Meter Volume (cu ft)                                                 74.692
Average Meter Pressure (in H20)                                              1.22
Average Meter Temperature (°F)                                              47.94
Moisture Collected (g)                                                       60.70
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   20.0
Nitrogen Concentration (%V)                                                  79.5
Dry Gas Meter Factor                                                      0.9940
Nozzle Diameter (in)                                                        0.130
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.318
Standard Metered Volume (dscf)                                             76.206
Standard Metered Volume (dscm)        .                                     2.158
Stack Moisture (%V)                                                         3.62
Mole Fraction Dry Stack Gas                                                 0.964
Dry Molecular Weight                                                       28.88
Wet Molecular Weight                                                       28.49
Stack Gas Velocity (fpm)                                                  4833.21
Stack Gas Velocity (mpm)                                                  1473.16
Volumetric Flow Rate (acfm)                                               8073.08
Volumetric Flow Rate (acmm)                                               228.63
Volumetric Flow Rate (dscfm)                                              5728.25
Volumetric Flow Rate (dscmm)                                              162.22
Percent Isokinetic                       ,                                  100.45
Percent Excess Air                                                        1992.23
Concentration (g/dscm)                                                      0.00
Concentration (kg/hr)                                                        0.00
Concentration (ppmv)                                                        0.00
Emissions (Ib/hr)	    	 	0.00

-------
         Eastern Research Group. Inc.
                                     MODIFIED METHOD 5 DATA SHEET
                                                            «i •
                                                                                                                                    Run      0*2-
                                                                                                                                    Page 1 of  2,
Plant OuLf
Date
Operator
Sampling Location <)ry-«v b
Sample Type
Run Number
StatitrPreSsure (±) (in. H2O)
Barometric Pressure (in. H2O)
qiu/nnvj^ «
t9--l*- 17
«*/4-O
}rVi>i<* 10
/Wit-L
oz.
- i
t1.£i
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (*F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak CheCk
fJlA
O^b
<4'£l(4,.y
Z^D
Ma
.Oio^jS1

' ' * * Q
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (In.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Eactor
A- 31
\.Ti-
-!<*«/
.(?0
3  I
                                                                 .ZH
                                              13
                                                                                                                             24.
                                                                                                                                      1 -
                                              I.
                                                                                                                                      f
 ^.
                                                                                                                                       36
                                              l-H
                                            SH&
                                                                                                                            Mo..
                                                                                                                          1.5-
                                                       a 3-1
                                                                  2*
                                                                         ^4-7
                                                                                                                 SC
                                                                                                                                                     -
                                              1-3
                                                                 .2.*
                                                                                                        M-B
                                                                                                                          1-S
                                                                                              fr
             Lo
           0*134
             L-T
                                   1--7
                                                                                                        Ml,
                                                                                                                             2 e
                                                                            .32-
                                               ."7
              6D
                                                                             38
                                                                                                         "Tts
                                                      i:
              It/T?
                                   a. i
                                                                                                                   So
             vio
                                                                  73
                                                                                                        Hz,
                                             «£>.<>
Comments:

-------
                                                                                                                                           if :.-7_ ^
 Traverse
   Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
  Gas
 Meter
 Reading
((Vm).tt3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
 cn
Orifice Pressure
  Differential
(delta H, in.H2O)
Desired
• Actual
Probe
Temp.
 C-F)
                              Filter
                             Temp.
                            Adsorbent
                               Trap
                              Temp.
                                                                                                                  , Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
    A  1
                                  _Lk.
                                                     Ji-
             to
                                            •2.^0
                      11*6"-
                                   l.C
                               MS .en
                                                                                               2-St
                                                                                                                          3-?
                                                                                                     «•
              as
            USSL
                                                       2-3 <&
                                                       338  '
                                                                        -a£l
                                                                                                                           t/
                                              \ -Z-
                                             2 Ho
               o
                                                                                                                          HI
                                                                                                                        2-2-
                                                                                                                           51
             10
                                    1.3
                                              1-3
                                                                            5 1
              90
              ftC
                                                                                                                 s>
                                              1.3
                                                                  25-
                                    SC,
                                    1-3  .
                                                      .2.5"
              tub
                                                                  23
                                                                                           •51
                                                                                                                            ret
              xoS
                                                                                                      5-7
             US'
                                           :  T.M»
                                                                                                                          ''4
Comments:

-------
EcBtem 0«a*arcn GfOup. ire.
              MOISTURE RECOVERY FORM FOR METHOD 4
            Plant
                                    L*J |>  l~\ \ \ ! I*\ 1 f\ L L ;
                                                        Uuf-
            Date
            Sampling Location
            Sample Type
            Run Number
            Impinger Box Number
            Recovery Person
            'Recovery" Rinses
            Sample Identification
            XAD Number
    Impinger
    Number
Impinger
Solution
Amount of
 Sofution
   (g)
Impinger Tip
Configuration
                                                    Impinger Weight
Final
 (g)
Initial
 (g)
Weight
 Gain
  fg)
               O.i
                         \CC
                C.ih/
                         JOG
               /S/a-CH
                         |C&
                                                     0
                                                      '767.7
                                     Total Weight Gain (g)
                                                   (,0
                                                                    °

-------
Facility:          Gulp Alum. Alloy
Date:           12/06/97
Location:        Dryer In
Run Number:              3
Sample Type:    M26

Total Sampling Time (min)                                                   240.0
Corrected Barometric Pressure (in Hg)                                        29.51
Absolute Stack Pressure (in Hg)                                              29.14
Stack Static Pressure (in H20)                                                -5.00
Average Stack Temperature (°F)                                            235.63
Stack Area (sq in)                                                         240.53
Actual Meter Volume (cu ft)                                                 77.350
Average Meter Pressure (in H2O)                                               1.11
Average Meter Temperature (°F)                                             51.47
Moisture Collected (g)                                                      136.80
Carbon Dioxide Concentration (%V)                                              0.0
Oxygen Concentration (%V)                                                    20.0
Nitrogen Concentration (%V)                                                   80.0
Dry Gas Meter Factor                                                      0.9940
Nozzle Diameter (in)                                                        0.140
Pitot Constant                                                                0.84
Average Sampling Rate (dscfm)                                              0.326
Standard Metered Volume (dscf)                                            78.344
Standard Metered Volume (dscm)                                             2.219
Stack Moisture (%V)                                                          7.61
Mole Fraction  Dry Stack Gas                                                 0.924
Dry Molecular Weight                                                       28.80
Wet Molecular Weight                                                       27.98
Stack Gas Velocity (fpm)                                                   4426.55
Stack Gas Velocity (mpm)                                                 1349.21
Volumetric Flow Rate (acfm)                                               7393.83
Volumetric Flow Rate (acmm)                                               209.39
Volumetric Flow Rate (dscfm)                                              5049.75
Volumetric Flow Rate (dscmm)                                              143.01
Percent Isokinetic                                                         101.01
Percent Excess Air                                                        1760.56
 Concentration (g/dscm)                                                       0.00
 Concentration (kg/hr)                                                         0.00
 Concentration (ppmv)                                                         0.00
 Emissions (Ib/hr)	0.00

-------
         Eastern Research Group. Inc.
                                              MODIFIED METHOD 5 DATA SHEET
Plant (LuAf /V]
Date
Operator
Sampling Location TVo*/- V
Sample Type
Run Number
Static Pressure (±) (in. H20)
Barometric Pressure (in. H2O)
kj»'Vllnv»Tl
(•3,-^^")
NtAi& •
WyW^L, toVl>
^4^*-
ft


XAD Trap Number
Filter Heater SettingJ°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
Nfl
a£fc
«4'   mlnirtei
 Traverse
   Point
 Number
 Sampling
.  Time
  (min)
             icr
                Clock
                Time
                (24hr)
  Gas
 Meter
Reading
((Vm).tt3)
 Velocity
,  Head
((delta Ps).
 in.H2O)
Stack
 Ts
 CF)
 Orifice Pressure
    Differential
 (delta H, in.H2O)
Desired  .  Actual
  Probe
\  Temp.
 Filter
Temp.
Adsorbent
  Trap
 Temp.
  (•F)
                                                                                                               Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
                                                                         31T
                                                                                                                      So
  1 )
                                                    a-*,
                                                                                                                                         /.t
                                                                                                                       vlt>
                    lltl*
                      6. 01
                                     T^U
                                                    37-7
                    l(,30
                                                                                T.tf-7
                    tuns
 ^tb.
                                                    218
                                                                                 2 s
4
                                                                                 ^s\
                                                                                                             tf «
  ,i>-i6
  it
                              /os:
                                                               33
                                                                         -53
                                                                                                                                .-•41
                                                  ?•
                                                                       .3
                                                                                 74-7
                                           (.Z
                                                                       'ZT^f
                                            -"2-
                                                                                 -2S3
             I'LO
                                                    Z3G
                                                                                                                  «f8
                                                                                                                       31
                                  -fr
                                                                       1,1*0
                                                    •Z-3
                                                                                                              'SO
                                                                                                             sr
                                                     •231
                                           /« I
                                                             .20:3
             / 00
                                                                                                                                ±
       <^S
                                                                                                                                   6?
                                           -L4-
Comments:

-------
                    Plant
                    Date
Location
Sample Type
Run Number
Operator
                                                                                                                                    Page
Traverse
Point
Number

0 L
& 7






»
' • »



"
; • •



• «
4 4
• -


• . .

. *•

•*





Sampling
Time
(min)
•ZOZ-.TT
-2. to
•z.n-5-
zz/r
Z.12..F
2,4rO













*





.
".




-



Clock
Time
(24hr)
i^zr.T
c<733
mo,r
^a
ffifrE
•d&o*









*»
w




•
" *

^


i
*





t
- G3s
• _ Mefer
. Reading
«Vrrt),ft3)
»HtoS2
iHl 4 o
As*i
iH^.Mr
l^-fl-7
iss. r-»1



• C

^ ,•«


J



•f-
*
••^


\
: .


. • '
' ''• ^
.


.


Velocity
Head
((delta Ps),
in.H2O)

\,«4
\\k
••\A
L($l
V6






-.

'
f
r






•
-

-








Stack
Ts
(°F)

a**i/j
taaA
Z^O
^o
^4-0




"". *
..
i •

»""

. *
• •


*.'
•









.



Orifice F
Ditto
(delta H,
Desired

NA>




f
yn
.oe>f^


t

^

• •


-

•


• .



-.

%






'ressure
ential
4n.H2O)
Actual

. **
i *

*


•







Pump
Vacuum
(in.Hg)

°\
X
_^v
^
^




••j





»

• ;
'*







.







Comments:

-------
E
                               Q
                                   
-------
Facility:           Gulp Alum. Alloy
Date:            12/05/97
Location:         Dryer In
Run Number:      1
Sample Type:     M23	
Total Sampling Time (min)                                             240.0
Corrected Barometric Pressure (in Hg)                                  29.39
Absolute Stack Pressure (in Hg)                                        29.02
Stack Static Pressure (in H2O)                                         -5.00
Average Stack Temperature (°F)                                      236.29
Stack Area (sq in)                                                   240.53
Actual Meter Volume (cu ft)                                          157.093
Average Meter Pressure (in H2O)                                        1.36
Average Meter Temperature (°F)                                       58.28
Moisture Collected (g)                                                216.90
Carbon Dioxide Concentration (%V)                                       0.5
Oxygen Concentration (%V)                                             20.0
Nitrogen Concentration (%V)                                            79.5
Dry Gas Meter Factor                                                0.9800
Nozzle Diameter (in)                                                  0.192
Pitot Constant                                                         0.84
Average Sampling Rate (dscfm)                                        0.644
Standard Metered Volume (dscf)                                     154.653
Standard Metered Volume (dscm)                                       4.380
Stack Moisture (%V)                                                   6.20
Mole Fraction Dry Stack Gas                                           0.938
Dry Molecular Weight                                                 28.88
Wet Molecular Weight                                                 28.21
Stack Gas Velocity (fpm)                                            4765.28
Stack Gas Velocity (mpm)                                            1452.46
Volumetric Flow Rate (acfm)                                         7959.61
Volumetric Flow Rate (acmm)                                         225.42
Volumetric Flow Rate (dscfm)                                        5490.84
Volumetric Flow Rate (dscmm)                                        155.50
Percent Isokinetic                                                    97.50
Percent Excess Air                                                  1992.23
Concentration (g/dscm)                                                0.00
Concentration (kg/hr)                                                  0.00
Concentration (ppmv)                                                  0.00
Emissions (Ib/hr)  	  	       0.00

-------
         Eastern Rewirch Group. Inc.
                                               MODIFIED METHOD 5 DATA SHEET
                                                                                                                      Run     \n-oi
                                                                                                                      Page 1 of   2.
Plant
Date nkfll
Operator '
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
C-AA _
ilJMl'V'l
piO£VOi6
o.cy^)»Yl
Meter Box Number
Meter delta H @
DGM Factor (Y)
Noz2le Type & ID (in.)
Ambient TemperatureJ'F)
Assumed Moisture (% H2O)
K-Factor
44O
I™jO /I
• / Or
JJftO
t\Q2_
>S

_v 1 ,

•4^
K - JVtfc- 1 * V~" ^ ,*. Diagram of Duct
                                                        Schematic of Traverse Point Layout
                                                          Read and record all data every     minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
            e
                      Clock
                      Time
                      (24hr)
  Gas
 Meter
Reading
((Vm).ft3)
 Velocity
  Head
((delta Ps).
 in.H2O)
Stack
 Ts
Orifice Pressure
  Differental
(delta H. in.H2O)
         Desired
Actual
          Probe
          Temp.
 Filter
Temp.
 (•F)
Adsorbent
  Trap
  Temp.
                                                                                                                 Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  (T)
 Pump
Vacuum
 (in.Hg)
                                            \,c\
                                                                                           HO
                                                                                                                                    38
            ib
                                  \f\
                                                                                                       '/Q
                                                                                                   3ft
                                                                                   Zl
   6-1
                                  \r\
                                                                                                                                             (a
                                                                                                                          Ml
                                                                                                                         40
                                IOL -
                                                               -LO-
                                                                                            m
                                                                                          41
                                                                                                                                    Ul
                                                                                                      Ml
                                                                                                                                  U
            Uo
                                                                                            m
                                                                                                                           M8
                                                                                                                Ll-
                                                                                                                          4^
                                                                                                                                  \2-
            Ml
                                   ''
                                                                                                               ^f
                                                                                                                                             11
                                            -t-.O
                                          7,*
                                                                                                                                    SO
                                             1.1
                                                                                                                                  Ifc
             ••\\p
                                                      \.
                                                                                                                                     *-i_
'f
                                                                                                                                             if
               C.
                                         I" JU
            <«*
          I'll
                     Kit
                                           ^^\
                                                                                                                                               '1
                     IVJJ
                                           •2,33
                                                                                                                 LS
                                                                                                              S"
                                                                                                       M3
                                                                                                                         Ml-
                                                                                                                                   MM
            loU
                                   I.M
                                                               _u2>-
                                                                                                                                 Ji2_
                                                                                                       M2,
                                            04-
                                                                                                     -W4-
Comments:
                                                   liAi*-^1 cx^4(g> r^"

-------
                     Plant
                     Date
                      Ill-Cm
                                  Location
                      Sample Type
                                                               Run Number
                                                    Operator
 Traverse
   Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
  Gas
  Meter
Reading
((Vm),ft3)
 Velocity
  Head
((delta Ps),
 in.H20)
Stack
 Ts
 CF)
  Orifice Pressure
    Differential
  (delta H, in.H20)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
  Temp.
  Dry Gas Meter

 Inlet     Outlet
(Tm in)    (Tm out)
Impinger
  Exit
 Temp.
  CF)
 Pump
Vacuum
 (in.Hg)
                                < -72
                                                          /.
                                                                                     Ml
       i
                                      1.4
                                                                                                Q-1
                                                                                                  -Hi,-
     (Ski,
                                    1.4
                                                                    i a
       V
                                                                                                            w

                                                                                                                      L U
             MO
                                     1.1
                                             i.O
                                    -U-
                                                                    1-0
                                                                                                                            •tf-
                                                         O-Hb
                                                                     \.o
                                                                                                                                           Wi
              tfO
                                                                                        ,1*0
                                                                                     4U
                                                                                                                       Ul
                                   ill.
                                     I.O
                                                                                                to
                                                  C.MO-
                                                                 *O. oo Ci
                       c-til
                                                Jli
            'UO
                                                         1.0
       '1
              J-4-
                                                         1.0
                                                                2-3?
                                               _b£-
                                                CVU
                                                         ,c
                                                                                                  7X^"
              -•As
                        i»40
             040
                                                                                                                                       -y-
                                                           0.0<
                                                              &
Comments:

-------
          MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f ,i lr\ . hi \ ii IVN, CMirrN H Hi»5\/
rt--*f-
-------
Facility: :Culp Alum. Alloy 1
Date: 1 12/06/97
Location: i Dryer In
Run Number: i 2 !
Sample Type: IM23

Total Sampling Time (min) ; \
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O) ;
Average Stack Temperature (°F) |
Stack Area (sq in) ! i !
Actual Meter Volume (cu ft) i
Average Meter Pressure (in H20) ;
Average Meter Temperature J°F)
Moisture Collected (g) i
Carbon Dioxide Concentration (%V)
Oxygen Concentration! (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling; Rate (dscfm)
Standard Metered Volume (dscf) '••
Standard Metered Volume (dscm)
Stack Moisture (%V) i '••
Mole Fraction Dry Stack Gas ;
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm) ;
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic '
Percent Excess Air j
Concentration (g/dscm) :
Concentration (kg/hr) :
Concentration (ppmv)
Emissions (Ib/hr)
|
i



i \
240.0
! 29.51
29.14
i -5.00
i 236.91
240.53
163.784
1.24
49.86
119.50
; 0.5
20.0
79.5
0.9800
0.192
i 0.84
: 0.686
164.544
i 4.660
6.98
0.930
28.88
28.12
; 4932.08
1503.30
8238.23
233.31
5654.20
160.13
100.73
i 1992.23
0.00
0.00
0.00
0.00

-------
         Ejjtem Retcarch Group. Inc.
                                                MODIFIED METHOD 5 DATA SHEET
                                                                                                                        Run   //; CfjQ" ° 2-:"
                                                                                                                        Page 1 of   2^
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
(>w piu ftL-
U.|taJr»
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

2<
| 7*H
.1*0
,R2-
i<*
6.2-

>t*~ ,1^^. 1 M PC/Ati
Diagram of Duct
                                                         Schematic of Traverse Point Layout
                                                          Read and record all data every	minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
            Clock
            Time
            (24hr)
  Gas
  Meter
Reading
((Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
  Orifice Pressure
    Differential
 (delta H. in.H2O)
Desired    Actual
Probe
Temp.
 CF)
 Filter
Temp.
 CF)
Adsorbent
  Trap
  Temp.
                                                                                                                   Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
                                                                          A.o
                                                                                                      -%-
                                             7- •'
                                                                                              "L.M/1
                                                                                                                  Vl
                                                                                                                 i£
                                                                                                                                      Hi
                                                                                                                                               10
                                 ¥.1 .of-7
                                                                                                                 Wo
                                                                                                                            wo
                                                                                                               it
                                                      •L»K
                                                                                                                           VD
                                                                                                                                    (I
                                                                                                        MO
                                                                                                        MP,
                                                                                                                            40
                                                       I'M-
                                                                 l.'T
                                                                                                                  MO
                                                                                                        MO
                                                                                                                                    -U-
L^fj j
                      (Oil?
                                                                                              HO
                                                                                                                             Jo
                                                                        y» 0.
            f\o
                                                                                                        AC?
                                                                                                                 a;
                                                                                                                            MT-
                                ^^•I).o\
                                                                                              MS"
                                              \.V
                                                                \.\
                                                                                                                  M1-
                       ^M^.^^
                                                                                                                                      Ul
                                                                                                                   s'n
                                                                                                                            ML*
             \sl-i
                                                                                                                  Mb
                                                                            \.-z-
                                      I -
                                                                                                        v,t
                                                                                                                                               iv
Comments:

-------
Plant
Date
C,7.<
7|^
xvr:f
irs~
7Ai,<
•7^0



























Clock
Time
(24hr)
Hl^.S"
fl?0.
i^.^V^
\iX>
it^«6
\*>OU
^05
\M,\



























Gas
Meter
Reading
((Vm).ft3)
ns-,9
140 -i\
|9< MV
i<\l.Ui
111. D
U>£.(j,
10«.«|
I" J,U>5*



























Velocity
Head
((delta Ps),
in.H20)
\.?>
\ ^
\,-v
I.L-
'•%
\.f
\.'
\.v,
\.LB
;.v«
I.U
L14K


























Probe
Temp.
CF)
23Z_
•\^-o
•m\
.L^*»
IV^
Lu<
i-MS
Is,'^.
,/s £» i?li;


























Filter
Temp.
CF)
z-c/3
LS\B
1^
1^1
l\0\
•LU\
^i.',
'Lt.U
6>S"


























Adsorbent
Trap
Temp.
CF)
WZ-
M9To-
>AV
^\
.Mb
MH
M.i
^^



























DryGa
Inlet
(Tm in)
(.0
(aO
Uo
bl
L/^-
Vff'J^-
t^
ua
i


























s Meter
Outlet
(Tm out)
•46
4*?
gis
*<\w
^
<>"&
5Z>
^2>



























Impinger
Exit
Temp.
CF)
5"«-
q
L>
1
1
7



























Comments:

-------
Ecjtefn Se»earcn Greco, 'nc.
              MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run' Number '*m?>'^--.:-~
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number ;
1 : . 1 p • M 1 ,i MK, fiLVf^PN H U r>\J
/^L/5-/9>
Cb<ca (j
          •lOG-360
                                    Total Weight Gain (g)

-------
Facility:           Gulp Alum. Alloy
Date:            12/06/97
Location:         Dryer In
Run Number:      3
Sample Type:     M23

Total Sampling Time (min)                                             240.0
Corrected Barometric Pressure (in Hg)                                  29.51
Absolute Stack Pressure (in Hg)                                        29.14
Stack Static Pressure (in H2O)                                          -5.00
Average Stack Temperature (°F)                                      236.41
Stack Area (sq in)                                                   240.53
Actual Meter Volume (cu ft)                                          148.612
Average Meter Pressure (in H2O)                                        1.14
Average Meter Temperature (°F)                                       52.30
Moisture Collected (g)                                                202.90
Carbon Dioxide Concentration (%V)                                       0.0
Oxygen Concentration  (%V)                                             20.0
Nitrogen Concentration (%V)                                            80.0
Dry Gas Meter Factor                                                0.9800
Nozzle Diameter (in)                                                  0.192
Pitot Constant                                                         0.84
Average Sampling Rate (dscfm)                                        0.619
Standard Metered Volume (dscf)                                     148.463
Standard Metered Volume (dscm)                                       4.204
Stack Moisture (%V)                                                   6.05
Mole Fraction Dry Stack Gas                                           0.939
Dry Molecular Weight                                                 28.80
Wet Molecular Weight                                                 28.15
Stack Gas Velocity (fpm)                                             4506.95
Stack Gas Velocity (mpm)                                            1373.72
Volumetric Flow Rate (acfm)                                          7528.11
Volumetric Flow Rate (acmm)                                          213.20
Volumetric Flow Rate (dscfm)                                         5222.01
Volumetric Flow Rate (dscmm)                                        147.89
Dercent Isokinetic                                                    98.41
3ercent Excess Air                                                  1760.56
Concentration (g/dscm)                                                0.00
Concentration (kg/hr)                                                  0.00
Concentration (ppmv)                                                  0.00
Emissions (Ib/hr)    	                                0.00

-------
         Eiilern Research Group. Inc.
                                              MODIFIED METHOD 5 DATA SHEET
                                                                                                                          Run
                                                                                                                          Page-1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure{±) (in. H2O)
Barometric Pressure (in. H2O)
(.uV Ai. AC.
izltri-7
Dtt/y/t,
UUA
»vi5-S
•4
•-"i

XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

2-Hc?
VYrH^
Z-^S

& do&[4
fl.rAooSfSio1
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A<+rv
I.-154
.'Wo
.ITJ-
4tT
U>. J-
*-.^2-

/-) . 2<3 Diagram of Duct
                                                       Schematlc of Traverse Point Layout
 Traverse
   Point
 Number
       Sampling
         Time
         (min)
Clock
Time
(24hr)
  Gas
  Meter
Reading
((Vm).ft3)
 Velocity
  Head
((delta Ps).
 in.H20)
                                                        Read and record all data uvery ±
Stack
 Ts
Orifice Pressure
  Differential
(delta H, in.H?O)
         Desired
Actual
                                                                               minutes
                                                                                               CGt-°      ^/Vll^
         Probe
         Temp.
 Filter
Temp.
Adsorbent
  Trap
 Temp.
  (•F)
                                                                                                               Dry Gas Meter
Inlet      Outlet
                  (Tm in)
                                                       (Tm out)
Impinger
  Exit
 Temp.
  (•F)
 Pump
Vacuum
 (in.Hg)
                                                                         .1
                                                                                                 43
                                                                                                            37
       ft
         \5.0
\uoO
                                          ,1
                                                                                      IS

                               -SI.
                                                                                                                   3SL
      ISi
                            "Sw.iu
                                                                                         bO
                                                                                                                       Ml
             v,o
                                                                                                                            Vi
                       AA.
                                                                                                    40
                                                                                                           bo
                                                                    •ft
                                                                               4o
                                                                                                                         -7
                                                                                                    41
                                                                                                    ao
                                                                        l.U
                                                                                                                   tfi
           r».t.
                                                                        l.U
                                                                                                                    41
                                   iai
                                           44-

            'L-S""
                               .. 2.1
                                                            5.3
                                                                                                                                 so
                    1  -
                               MI.
                                            t.M
    45
                                                  __L3_
                                                                                                 H\
                                        1.3
                                                                                U-O
                               /tl.ifc.
                                                                        I'D
                                                                              IfS
                                                                      S
                                                                                          'S
                                            I.I
                                                                     t.o
                                                                                                                     9)
JL£
                                                                        ,32

                                                                                 L-Slo
Comments:

-------
                                                                                                                                     Pagl
                                                                                                 of
                    Plant
                    Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
A-G.
i*
^ 7
7
flj?
£





























Sampling
Time
(min)
^OZ.i>~
2.16-
ill.*"
i^5T~
-z.it.s-
-MjO





























Clock
Time
(24hr)
\'\l±'.^~
iflS^
iH^.b"
1^4'X
mc-sT.^"
lisQS





























Gas
Meter
Reading
((Vm).n3)
/Vt.Coif
\MU,%
\ S>0.-)
Kg.«\
f^.Sv
/bl.-7JO





























Velocity
Head
((delta Ps).
in.H2O)
\ .\
I.I
W
^
2^^
2.3^
tSq
Z3T





























Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual






i.jiA\*-




























*.O
/,o
,3?U
•*1
^7
.^L.
/- ^>.^l.t




























Probe
Temp.
CF)
•i4/
^-SV
£SS~
23 W
•z-V«^
250
4G,P/t^"




























Fitter
Temp.
(°F)
•Z±*
;xuo
•^^n
•i.^i-
1L.O






























Adsorbent
Trap
Temp.
(°F)
((V
^i
'-i'4
HV
Wi~"
%





























Dry Gas
Inlet
(Tm in)
s •/
^"2-
S'.S^
s"^:
<7j
\> /
^1





























> Meter
Outlet
(Tm out)
V.-s-
>V5""

-------
Eastern Qeaaarcn G«sco. '-r\c.
               MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
/":. i> . ftV.^'.r^tVN R lUx,
/^J^/T-
Cft(\ /Wl€l
rv++-v^ ,03
^^

/qo^ fy.i4e. / P ~^.\ ^,.i-Vci5. (rei
          ZCC -3
                                      Total Weight Gain (g)

-------
Facility:           Gulp Alum. Alloy
Date:            12/05/97
Location:         Dryer Out
Run Number:             1
Sample Type:     M26	
Total Sampling Time (min)                                                   240.0
Corrected Barometric Pressure (in Hg)                                        29.38
Absolute Stack Pressure (in Hg)                                              29.30
Stack Static Pressure (in H2O)                                                -1.00
Average Stack Temperature (°F)                                            186.44
Stack Area (sq in)                                                         490.87
Actual Meter Volume (cu ft)                                                 98.879
Average Meter Pressure (in H2O)                                              0.56
Average Meter Temperature (°F)                                             59.04
Moisture Collected (g)                                                      133.90
Carbon Dioxide Concentration (%V)                                              1.0
Oxygen Concentration (%V)                                                   19.0
Nitrogen Concentration (%V)                                                .  80.0
Dry Gas Meter Factor                                                      0.9880
Nozzle Diameter (in)                                                        0.215
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.409
Standard Metered Volume (dscf)                                            98.146
Standard Metered Volume (dscm)                                             2.779
Stack Moisture (%V)                                                         6.04
Mole Fraction Dry Stack Gas                                                 0.940
Dry Molecular Weight                                                       28.92
Wet Molecular Weight                                                       28.26

Stack Gas Velocity (fpm)                                                  2112.59
Stack Gas Velocity (mpm)                                                   643.92
Volumetric Flow Rate (acfm)                                               7201.48
Volumetric Flow Rate (acmm)                                               203.95
Volumetric Flow Rate (dscfm)                                              5411.99
Volumetric Flow Rate (dscmm)                                              153.27
Percent Isokinetic                                                         102.17
Percent Excess Air                                                         889.51
 Concentration (g/dscm)                                                      0.00
 Concentration (kg/hr)                                                        0.00
 Concentration (ppmv)                                                        0.00
 Emissions (Ib/hr)	     0.00

-------
         Eastern ftneinh Group. Inc.
                                            MODIFIED METHOD 5 DATA SHEET
                                                                                                CO 1  -
                                                                                                                Run
                                                                                                                Page 1 of
Plant
Date
Operator
Sampling Location \&\ < K.
Sample Type
Run Number
Static Pressurejt) (in. H2O)
Barometric Pressure (in. H2O)
CwJ> M/ A
'2/ffa*
Alum / 3"S
€H ooT
Pm/H^L
1
-1-0 "
2.9 .-S 3ct
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
	
ZSO
G'iNflt*
150
feo
• OI^IO"
.C)@ IS"'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H20)
K-Factor
d-3>
l.m
O,q&£
O.l\$
3o*
8%
|,(,i_

Diagram of Duct
                                                     Schematic of Traverse Point Layout
                                                       Read and record all data every _^_ minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
 Clock
 Time
 (24hr)
  Gas
 Meter
Reading
«Vm).ft3)
            Velocity
             Head
           ((delta Ps),
           ' in.H2O)
     Stack
      Ts
 Orifice Pressure
   Differential
 (delta H, in.H2O)
Desired    Actual
Probe
Temp.
 (T)
 Filter
Temp.
Adsorbent
  Trap
 Temp.
                                                                                                            Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
    -r
   A-V
                  1ft. 0
                      i .3
                     "LOT
                                       7 H
       i
         OS :
                                        2 .
                                                                                                        M-
                   0%
                                         loi
                                                  \ , >M
                                                                                      H
            40
                                        l.jd.
                                                                              iMO
                              Sb.Y2.0-?-
                                                                                                  V
                                                                                                                    . O
      £
 6 O
                                                                                                (,0
                                                                                                                   3.
                       33
                                                                              7.4 I
                                                                                                                  2-0
              10
                    6, \ ,
                   \6 "
                                                  C ,
                                Qv(_
                                                                                                                    O

                                                            O. G
                                                                    Z-s O
                                                                                                                    O
      '
           r.\i
                       O.C'L
                      1ST-
                              o.os'
                                                                                                           6 i
             10
         \\
          fo >  b
                                       n-01/
                                                          2-5 2-
                                         Ii±
                                                          5H
                                                                                                                                       O
                                                                              J  C '  <
                                                                                / o
                     i : <>" o
•K-O
frl.l.
^
                                                                                                                             S-o
       H
               Q
                      o.i
                                                                                      £,0
                                                                                                                                       JO
              SO
          11: fco
                                ZOO
                                        1.04
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             ILO
                                                                                                          (n 1
                                          0
                                         tsv
                                                                                                fo
                                                                                               AE
                                                                                                        :>-.£
             iVfi
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                                                      *
                                                  n.i i
                                                                                      60
                                                                                                           O
                       00
                               fi.  IV
                                                                    14,1
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               to
          IS
          io~v -
                                                                                                  q
                                                                                                        Z-0
                   H  "
                   \il-C?
                                         0 MS
H  30
                               S,  0
                                        o^o
                                                                                                                  3Z
                                                                                                                           2 -S
       t
Comments:

-------
Plant
Date


Location
Sample Type


Run Number
Operator


Traverse
Point
Number



















-















Sampling
Time
(min)



































Clock
Time
(24hr)



































Gas
Meter
Reading
((Vm).ft3)



































Velocity
Head
((delta Ps),
in.H2O)
















—


















Stack
Ts
CF)



































Orifice F
Differ
(delta H.
Desired



































'reusure
ential
in.H2O)
Actual













\





















Probe
Temp.
(°F)



































Filter
Temp.
(°F)



































Adsorbent
Trap
Temp.
(°F)



































Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)






































































Implnger
Exit
Temp.
(°F)





Xj

,



























Pump
Vacuum
(in.Hg)







i



























Comments:

-------
 .G
        . inc.
           MOISTURE RECOVERY FORM FOR METHO
                                                                      C
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
C ^ LjJ (> R \ 1 i Tr\ i (\ i ^~»-\ M 1 1 n V 5

*Y / " 11 fjt ^ ^V ^0-*K*
^\,p Jrv<"-F J/5 ^rT1 LL^ (Jj-^
^44^^^ ^/nA " ~~
/

rOd-r,- r^uJoV**. / 1 ^Ct-^-n V (-Ti^V-k'i.1
7

ill ^?^i( 'v — /

Impinger
Number
Impinger
Solution
Amount of
 Sofution
   (g)
Impinger Tip
Configuration
                                               Impinger Wefght
Final
 (g)
                                                  '
Initial
 (g)
Weight
 Gain
  (g)
           o.i
                              
-------
Facility:           Gulp Alum. Alloy
Date:             12/06/97
Location:         Dryer Out
Run Number:              2
Sample Type:     M26	
Total Sampling Time (min)                                                   240.0
Corrected Barometric Pressure (in Hg)                                        29.50
Absolute Stack Pressure (in Hg)                                              29.42
Stack Static Pressure (in H2O)                                                -1.00
Average Stack Temperature (°F)                                            181.83
Stack Area (sq in)                                                         490.87
Actual Meter Volume (cu ft)                                                108.753
Average Meter Pressure (in H2O)                                             0.14
Average Meter Temperature (°F)                                             57.27
Moisture Collected (g)                                                       80.00
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   19.5
Nitrogen Concentration (%V)                                                  80.0
Dry Gas Meter Factor                                                      0.9880
Nozzle Diameter (in)                                                        0.215
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.451
Standard Metered Volume (dscf)                                           108.124
Standard Metered Volume (dscm)                                            3.062
Stack Moisture (%V)                                        .                 3.37
Mole Fraction Dry Stack Gas                                                 0.966
Dry Molecular Weight                                                       28.86
Wet Molecular Weight                                                       28.49
Stack Gas Velocity (fpm)                                                  2270.87
Stack Gas Velocity (mpm)                                                  692.16
Volumetric Flow Rate (acfm)                                               7741.05
Volumetric Flow Rate (acmm)                                               219.23
Volumetric Flow Rate (dscfm)     '                                         6050.61
Volumetric Flow Rate (dscmm)                                              171.35
Percent Isokinetic                                                         100.67
Percent Excess Air                                                       1191.93
 Concentration (g/dscm)                                                      0.00
 Concentration (kg/hr)                                                        0.00
 Concentration (ppmv)                                                        0.00
 Emissions (Ib/hr)	  0.00

-------
                     ..Inc.
                                            MODIFIED METHOD 5 DATASHEET
                                                                                                                Run
                                                                                                                Page 1 of
Plant
Date
Operator
Sampling Location ""bft-f'et^-
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
|lv /\i_
<\^.
SS
fyv<^K)*AOUT
HCL,L.TKVN
•^_
-l-oo"
^liSl
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
	
2.SG
rVN^t*
2^0
6iO
• Oi/OiV
,0|£jO''
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
ft-l^-
l.£]3
o 1^8
0 !XlS
30°
%**
1 iCjT-
i T ^ ^
~IQ i t
1 F^
Diagram of Duct
                                                     Schematic of Traverse Point Layout
                                                      Read and record all data every I P  minutes
 Traverse
  Point
 Number
Sampling
  Time
  (min)
             0
Clock
Time
(24hr
         (7 S3
£
    Gas
   Meter
  Reading
  ((Vm).tt3
 Velocity
  Head
((delta Ps),
 in.H20)
                   Stack
                    Ts
Orifice Pressure
  Differential
(delta H, in.H2O)
                           Desired
         Probe
         Temp.
Actual
 Filter
Temp.
 CF)
                                                                        Adsorbent
                                                                          Trap
                                                                         Temp.
                                                                                                           Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
  B-
  /o
             7_
                                                 2V
                                                                                             20
            2«3
±t
                                         HZ-
                                        0,5-3
                                           V3
                                     2.3V
                                                                                               O
            JO
         on
                                                 ft
                                                                             S
            40
                               0 ,
                                         O-SE
                                                                                                                  ,, S
           SO
                               O, Xf.
                                                                                                                  / o
                                                            0.2.G
                                                           o.xt,
                                                                                                                  r-o
      '9-
                                 .V
                                         o,
                   /o '
                   ILO
                                        1.7,$
                                         /.2.S
           /oo
         /o:
                                                 /.ffc
                                                                                       -TV/
                                                                                             "3 o
           HO
         /o:
                                                         25C,
                                                                                               yt,
    4^
                                IIP
                                                                     0. O/
                                                                      /0i-
                   u:io
           1*0
                   i  I -O
                     I.ZO
                                         I9
                                      ^
                                                                                            V 0
      it
  ISO
                              70 1
                                                                                                        V-0
      (0
  ICO
n  to
T.C.V/.O
                              l.oA
                                                                                                    3 .0
                    II'OG
                     ft.-f-S
                                                                                                                             o
                    iv./o
                                                                                                70
            ISO
                                                                             1-C.CJ
                                                                                                                   r
                    42 ' J>0
                                                                                                                            1C
                                  -5
                                                                                                                            / 0
                                           0
                                         0,07.
                                          Uo
                                        .<3.o V
                                                                                                vc,
                                                                                             i  a
                        l o
                                                  O.o1/
                                                                                       60
                                                                                                                                     /. o
                                                    i <;
                                                                                                Lo
                                                                                                                /. o
                                                                                 (0
Comments:

-------
Plant
Date


Location
Sample Type


Run Number
Operator


Traverse
Point
Number



































Sampling
Time
(min)



































Clock
Time
(24hr)



































Gas
Meter
Reading
((Vm),fl3)



































Velocity
Head
((delta Ps),
in.H2O)



































Stack
Ts
CF)



































Orifice F
Differ
(delta H,
Desired



































ressure
entia!
in.H2O)
Actual



































Probe
Temp.
CF)



































Filter
Temp.
CF)



































Adsorbent
Trap
Temp.
CF)



































Dry Gas
Inlet
(Tm in)



































3 Meter
Outlet
(Tm out)



































Impinger
Exit
Temp.
CF)



































Pump
Vacuum
(in.Hg)



































Comments:

-------
        ire.
           MOISTURE RECOVERY FORM FOR METHOD*
Plant
Date
Sampling Location
Sampfe Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XADNumber
duJ^ RL^'.CS,^ ftiUy*


r^M^\ 3j A
A
^"^
rO^r,- A.JnU / T c.^cv C, vk'.n
'

II 1 ft^l "3.

Impinger
Number
Impinger
Solution
Amount of
 Sofution
   (g)
Impinger Tip
Configuration
                                                Impinger Weight
Final
 (g)
Initial
 (g)
Weight
 Gain
  (9)
            o.i
                      \Cfi
                     ICC
                    
-------
Facility:           Gulp Alum. Alloy
Date:             12/06/97
Location:         dryer out
Run Number:              3
Sample Type:     M26   	
Total Sampling Time (min)                                                   240.0
Corrected Barometric Pressure (in Hg)                                        29.35
Absolute Stack Pressure (in Hg)                                              29.28
Stack Static Pressure (in H20)                                               -1.00
Average Stack Temperature (°F)                                            187.92
Stack Area (sq in)                                                         490.87
Actual Meter Volume (cu ft)                                                102.267
Average Meter Pressure (in H2O)                                              0.58
Average Meter Temperature (°F)                                             51.52
Moisture Collected (g)                                                      151.40
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   20.0
Nitrogen Concentration (%V)                                                  79.5
Dry Gas Meter Factor                                                      0.9880
Nozzle Diameter (in)                                                        0.215
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.427
Standard Metered Volume (dscf)                                           102.390
Standard Metered Volume (dscm)                                             2.900
Stack Moisture (%V)                                                         6.52
Mole Fraction Dry Stack Gas                                                 0.935
Dry Molecular Weight                                                       28.88
Wet Molecular Weight                                                       28.17
Stack Gas Velocity (fpm)                                                  2212.16
Stack Gas Velocity (mpm)                                                   674.27
Volumetric Flow Rate (acfm)                                               7540.91
Volumetric Flow Rate (acmm)                                               213.56
Volumetric Flow Rate (dscfm)                                              5620.93
Volumetric Flow Rate (dscmm)                                              159.18
Percent Isokinetic                                                         102.62
Percent Excess Air                                                        1992.23
 Concentration (g/dscm)                                                      0.00
 Concentration (kg/hr)                                                        0.00
 Concentration (ppmv)                                                        0.00
 Emissions (Ib/hr)	0.00

-------
        Extern Research Group, Inc.
                                           MODIFIED METHOD 5 DATA SHEET
                                                                                                            Run
                                                                                                            Page 1 of
Plant
Date
Operator ,
Sampling Location ^bV-it £-
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
C<,ur* fo.flL
Mt.ll*
m«)>(/^rS
*AH oJT
rvta_/?n
3 '
- |,oo"
ZS.3G
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check ,
Final Leak Check
*-
•2,^0°
6'N/acy
2^0°
CoO
0,0l@/o"
O.Oltfio'1
Meter Box Number
Meter delta H @
DGM Factor (Y) l
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
d-3v
l.frl^
o.«ttS
oa\S
3£»
**%
1 ,k2-

Diagram of Duct
                                                    Schematic of Traverse Point Layout
                                                     Read and record all data every _j_j_ minutes
 Traverse
   Point
 Number
Sampling
  Time
  (minf
Clock
Time
 Gas
 Meter
Reading
                                  Velocity
                                   Head
                                 ((delta Ps),
                                  in.H2O)
Stack
 Ts
 CF)
 Orifice Pressure
   Differential
 (delta H. iri.H2Oj
Desired   Actual
Probe
Temp.
 Filter
Temp.
 CF)
Adsorbent
  Trap
 Temp.
                                                                                                        Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in-Hg)
    ft-12-
                                     SL
                                                                                                               43
                                                                                                              S.O
            10
                  2.HI.-V
                                                        zss
                   IL' K
                                               fl .<
                                                                                                                .0
             o
         It. '
             .>
                                                                                            V?
                                                                                                                                  4-0
                                                                                                                                  S.o
                                                                                                                                   2.0
            30
                                               0.
                                                                                                               J^o.
            80
                               .0 b
                                              0. fG
                                                                                                                  -ia.
                                                                                                      10
*
                          •2.0 -
                                OH
                                      0, Ot>
                                                                                                      1.0
                  IV:
                                                                                                                          .O
       1
   D
                                . 1
                                                                    OCi
                                                                                                               1 0
           iio
                                                6-OO
                                               O.ec
                                                                                                     1-0
                                                                                   10"
            VTO
                  132 .8*0
             no
                                                                                                                        1 0
             iHo
             ISO
            . 33
                                        > 2-
             (Go
                                                 .SS
                                                                                                      MS
             >o
                                                                                             5*4
                                                                                                              ^•s
                                                           ,3?
                                                                           -*ia.
            loo
                                        Zoo
                                                                                                              5-ci
            XI 0
                                                          (•of
                                                                     .Z.C
                                                                                             feO
                                                                    -40
                                                                                             c 1
                                                                                                              6/0
            ISO
                                                                   2S2.
                                                                 263
                                                                     •  0
                                                                o|
                                                                ID"
Comments:

-------
Plant
Date


Location
Sample Type


Run Number
Operator


Traverse
Point
Number



































Sampling
Time
(min)



































Clock
Time
(24hr)



































Gas
Meter
Reading
((Vm).ft3)



































Velocity
Head
((delta Ps),
in.H2O)



































Stack
Ts
(°F)



































Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual






































































Probe
Temp.
(°F)



































Filter
Temp.
m



































Adsorbent
Trap
Temp.
(°F)



































Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)






































































Impinger
Exit
Temp.
(°F)



































Pump
Vacuum
(in.Hg)



































Comments:

-------
Eawem Ow*orcn G/oco.
               MOISTURE RECOVERY FORM FOR METHOD
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery' Person
Recovery Rinses
Sample identification
Fitter Number
XAD Number
r* .1 Q i . • r\ i i

C^'.D \V^
-------
Facility:           Gulp Alum. Alloy
Date:            12/05/97
Location:         Dryer Out
Run Number:             1
Sample Type:     M23	
Total Sampling Time (min)                                                    240.0
Corrected Barometric Pressure (in Hg)                                         29.38
Absolute Stack Pressure (in Hg)                                               29.30
Stack Static Pressure (in H2O)                                                -1.00
Average Stack Temperature (°F)                                             193.16
Stack Area (sq in)                                                          490.87
Actual Meter Volume (cu ft)                                                  99.354
Average Meter Pressure (in H2O)                                              0.56
Average Meter Temperature (°F)                                              54.78
Moisture Collected (g)                                                       122.50
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen  Concentration (%V)                                                    20.0
Nitrogen Concentration (%V)                                                   79.5
Dry Gas Meter Factor                                                       0.9810
Nozzle Diameter (in)                                                         0.215
Pitot Constant                                                                0.84
Average Sampling Rate (dscfm)                                               0.414
Standard Metered Volume (dscf)                                             99.258
Standard Metered Volume (dscm)                                             2.811
Stack Moisture (%V)                                                          5.50
Mole Fraction Dry Stack Gas                                                  0.945
Dry Molecular Weight                                                        28.88
Wet Molecular Weight                                                        28.28

Stack Gas Velocity (fpm)                                                  2142.78
Stack Gas Velocity (mpm)                                                   653.12
Volumetric Flow Rate (acfm)                                               7304.40
Volumetric Flow Rate (acmm)                                                206.86
Volumetric Flow Rate (dscfm)                                              5464.34
Volumetric Flow Rate (dscmm)                                               154.75
Percent  Isokinetic                                                          102.33
Percent  Excess Air                                                        1992.23
 Concentration (g/dscm)                                                       0.00
 Concentration (kg/hr)                                                         0.00
 Concentration (ppmv)                                                         0.00
 Emissions (Ib/hr)                      	0.00

-------
         Eastern Research Group. Inc.
                                             MODIFIED METHOD 5 DATA SHEET
                                                                                                                  Run
                                                                                                                  Page 1 of  	I
Plant
Date
Operator
Sampling Location "^ fl^€ Vt_
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Coi> rt/fl
p_ltf K H-
rtvul^ /TS
Brt abT
"bi'Of iVJ
1
- t-0"
7.4 J^"^9
XAD Trap Number &vjT - (
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting ("F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

t J (i
^° P/ftt.^
1$^
(t>0
• OI&QCi'
• tj ^? iS'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
rt-'Sfe
l,SilC
c>i^fi I
0,2, i^
^&-?°
g
1-C.Z
>*
Diagram of Duct
                                                      Schematic of Traverse Point Layout
                                                       Read and record all d«ta every	minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
  Clock
  Time
  (24hr)
  Gas
 Meter
Reading
((Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H20)
Stack
 Ts
 (•F)
 Orifice Pressure
    Differential
 (delta H. in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
 CF)
Adsorbent
  Trap
 Temp.
                                                                                                             Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pwmp
Vacuum
 (in.Hg)
             O
         OKOQ
             /O
         0% vo
              y o
                                          6 ,
                                        o
                                                                  vs
                                                                                   3 S
             2.0
                                                    2.OL-,
                                                                     Zfrl
                                                                     7.51
                                                                                  i
            VO
                      . 3
                                                   .<><&
                                                                                     v
                                                                                    Ql
          t£L
                                                             .5,0
                                                                    a on
                                                         liii
                                                                                    Jj^-
                   (Ja -PPt)*
                                                            ,JJL
                                                                                                 WL
                                                                                                          5o
                                                             .3H
                                                                                                          Si
                                                                                                           Hi.
                               . ji
                                                           . V3
                                                                               sr
                                                                             st,
                     . o3
                                                  y 11
                                                                     7.6
                                                                   HI
                                                                                    VI.
                                                                                  4.5"
    10
                   Bfe.2.
                                         (ft)
                                                                      l.feT.
                                                                              151
    It
         l  33
                       1. 1
                    LOO
                                                                 60
                                                                                   . e
          no
         IT. i
 A- B.
                   JOl'rS?
                                                            ISO
                                                                                                         .,0
                                                   IUD
                                                  O.ciM
                                                   0.0^-1
                                                                                              MS-
                                          .01
                                                  o oM
                                                            153
                                                         2S5"
                            I Ok .
                                                                    7SS
                                                                     TXS
                                                                                                 ST.
                                                                                              H9-
                                                                                             7.0
                                          .07.
                                                           0.04
                                                            IS*)
                                                                                                       T..O
                                                                                                 SO
                                                                                                Bl
                                                                                                                    2.0
                             n? .1
                                 /S"
                                                                     aso
                                                                   S3
                                                                          51
                                                                                  10.
          7 OO
        / V.ao
                                           31"!
    10  <\
•2.10
/M'ro
          •LT-O
                  ^/:^>
                   11
                   z*.l
         Iffi
                                                                           LI,
    - "
                                                            .33
                                                                              Hlo
                                                                           CL
      IT
                                                                              1ST-
Comments:

-------
Plant
Date


Location
Sample Type


Run Number
Operator


Traverse
Point
Number



































Sampling
Time
(min)



































Clock
Time
(24hr)



































Gas
Meter
Reading
((Vm).tt3)



































Velocity
Head
((delta Ps),
in.H2O)



































Stack
Ts
(•F)



































Orifice F
Differ
(delta H,
Desired



































'ressure
ential
in.H20)
Actual



































Probe
Temp.
CF)



































Filter
Temp.
CF)



































Adsorbent
Trap
Temp.
(°F)



































Dry .Gas Meter
Inlet Outlet
(Tm in) (Tm out)






































































Impinger
Exit
Temp.
CF)'




i






























Pump
Vacuum .
(in.Hg) '



































Comments:

-------
Eastern S«eorcn Grci-o. .'nc.
               MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number ^-^ !
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number '^:-^^
XAD Number f ;
( . , 1 A . M \ . i p
                                                  loo. I
                         ICC
               I4PLC
                                                                    O
              E/^P TV
                                                    -.3
                                     Total Weight Gain (g)

-------
Facility:           Gulp Alum. Alloy
Date:            12/06/97
Location:         Dryer Out
Run  Number:      2
Sample Type:     M23	
Total Sampling Time (min)                                             240.0
Corrected Barometric Pressure (in Hg)                                  29.50
Absolute Stack Pressure (in Hg)                                        29.42
Stack Static Pressure (in H2O)                                         -1.00
Average Stack Temperature (°F)                                       188.29
Stack Area (sq in)                                                   490.87
Actual Meter Volume (cu ft)                                          107.848
Average Meter Pressure (in H2O)                                        0.83
Average Meter Temperature (°F)                                        55.38
Moisture Collected (g)                                                 74.70
Carbon Dioxide Concentration (%V)                                       0.5
Oxygen Concentration (%V)                                             19.5
Nitrogen Concentration (%V)                                            80.0
Dry Gas Meter Factor                                                0.9810
Nozzle Diameter (in)                                                  0.215
Pitot Constant                                                         0.84
Average Sampling Rate (dscfm)                                        0.447
Standard Metered Volume (dscf)                                      107.267
Standard Metered Volume (dscm)                                       3.038
Stack Moisture (%V)                                                   3.18
Mole Fraction Dry Stack Gas                                           0.968
Dry Molecular Weight                                                 28.86
Wet Molecular Weight                                                 28.51
Stack Gas Velocity (fpm)                                            2321.94
Stack Gas Velocity (mpm)                                             707.73
Volumetric Flow Rate (acfm)                                         7915.15
Volumetric Flow Rate (acmm)                                         224.16
Volumetric Flow Rate (dscfm)                                        6137.20
Volumetric Flow Rate (dscmm)                                        173.81
Percent Isokinetic                                                    98.47
Percent Excess Air                                                  1191.93
 Concentration (g/dscm)                                                0.00
 Concentration (kg/hr)                                                  0.00
 Concentration (ppmv)                                                  0.00
 Emissions (Ib/hr)	0.00

-------
         Eastern Reiearch Croup. Inc.
                                            MODIFIED METHOD 5 DATASHEET
                                                                                                                 Run
                                                                                                                 Page 1 of
Plant
Date
Operator
Sampling Location T>f*-yt! fl_
Sample Type
Run Number
Static Pressure (±l(in. H2O)
Barometric Pressure (in. H2O)
£wU> AL rt<-
l2.|fel4?-
ftV*^ /"ys •
iSliJ o'OT"
^ mX. / A^
"2_-
- /-Ob"
2£l«^l
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
-
2SO
G;>/fUy
t$O
C?O
lO^Jj^'1
iO i(£*i£ "
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (T)
Assumed Moisture (% H2O)
K-Factor
A "3?
1 1£(6
0 ftb^
0(2-\£
30°
&
\t(o'l~

Diagram of Duct
                                            Schematic of Traverse Point Layout
                                             Read and record all data every _j_O_ minute*
                                                                                                «VJX
 Traverse
   Point
 Number
 Sampling
  Time
  (min)
             Clock
             Time
             (24hr)
  Gas
  Meter
Reading
((Vm).ft3)
 Velocity
  Head
((delta Ps).
 in.H2O)
Stack
 Ts
 CF)
 Orifice Pressure
   Differential
 (delta H. in.H2O)
Desired   Actual
Probe
Temp.
 Filter
Temp.
 CF)
Adsorbent
  Trap
  Temp.
  (•F)
                                                                                                            Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
           iO
                                                           3
   il
                                        7,0 >
                                                                                      7.*, 3
   10
                                                                    1ML
                                                                             1-SH
                                                                                                                  42-
                      iv
                                                                                       MO
                                                                                                 S.M
                                                                                              Ml
                                                            .1?
          30
                                                                             IS'L
                                                                                        HO
                                                                           S3
                                                                                   Mo
         •80
         OT. b'S
                                 ,02-
                              .oH
                                                                ST.
                                                                        3-8
          no
                                                                             1MO
                                                                                        HO
                                                                                    Si
                  10  if
                                                   .o^
                                                              o^
                                                                  MO
                                                                          £2.
         I/C)
                                                                                      so
                               . HO?
                               .01.
                                                                              •LS
                                     ^
                                                                 MO
                                                                         53
                                                    1^.
                                                                             01
          11,0
         H.T.O
                                 ..ML
                                                ICO
                                                       "VH
                                                     t-t
                                   St
          llfl
                                                                    ZbO
                                                                               LbS"
          • SO
                                         I93
                                                     •SI.
                                               7.t>L
                                                                 Li
  3
          , J . 50
                                   T.
                              . «, 7.
                                     2 GO
                                                              SI
          1L J
          It 00
                                 .•LI
                                                                                                      3
                   ft. f O
                                                   , 2/S
                                                                     T-53
                                         .11
                                                                    ISt
                                                                              -LSI
                                                                           feV
          ilO
         i l.J
                         -sro
                                                                 Ml
                                                                6
                                                                        V3
         loo
                             LO . 1
                                                                    -IMS"
                                                                               IH'i
                                                                  HI
                                                                43

          T-l 0
                  T.LG .
                                          -to 2.
                                                                           44
                                                                                            H.t
 iO
Z70
                                                                     153
                                                                  HO
 /i
I 130
                                         1.2.
                                        T.03
 a
         il.
                                                                             Tm-
Comments:

-------
Plant
Date


Location
Sample Type


Run Number
Operator


                                                                                                                            Page*
of
Traverse
Point
Number



































Sampling
Time
(min)



































Clock
Time
(24hr)



































Gas
Meter
Reading
((Vm),tt3)



































Velocity
Head
((delta Ps),
in.H2O)



































Stack
Ts
CF)



































Orifice F
Differ
(delta H,
Desired



































'ressure
ential
in.H20)
Actual



































Probe
Temp.
CF)



































Filter
Temp.
CF)



































Adsorbent
Trap
Temp.
CF)



































DryGa
Inlet
(Tm in)



































s Meter
Outlet
(Tm out)



































Impinger
Exit
Temp.
CF)



































Pump
Vacuum
(in.Hg)



































Comments:

-------
Eastern Rejaorcn Graup. Inc.
            MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
FilterNumber
XAD Number
1 ; i -V r\ PI In rrviryvfyv H llftxV
ft/Tp^
C,k\5
I ^brvis
-^
•7.00-360^.


Impinger Tip
Configuration
K^ocKouL
CsKart hp)
/AeaK-iect
/HaS'^el
r^ocXf^ai.
AcJ!,4i'&i.


Impinger Weight
:Final
(9)
530;.^
5213
5X3.^-
^SS.g
7?5?
rt°oofe

Initial
(g)
4«.r
5^,1
6^3. >
4*3.3
7)s;K
^^.i

Total Weight Gain (g)
Weight
Gain
(g)
;T3,7
- 1
<9
. 5^
^o.S/


Tf'.l

-------
Facility:           Gulp Alum. Alloy
Date:            12/06/97
Location:         dryer out
Run Number:      3
Sample Type:     M23   	
Total Sampling Time (min)                                             240.0
Corrected Barometric Pressure (in Hg)                                  29.35
Absolute Stack Pressure (in Hg)                                        29.28
Stack Static Pressure (in H2O)                                          -1.00
Average Stack Temperature (°F)                                      191.00
Stack Area (sq in)                                                   490.87
Actual Meter Volume (cu ft)                                          101.063
Average Meter Pressure (in H2O)                                        0.60
Average Meter Temperature (°F)                                       49.60
Moisture Collected (g)                                                114.00
Carbon Dioxide Concentration (%V)                                       0.5
Oxygen Concentration (%V)                                             20.0
Nitrogen Concentration (%V)                                            79.5
Dry Gas Meter Factor                                                0.9810
Nozzle Diameter (in)                                                  0.215
Pitot Constant                                                         0.84
Average Sampling Rate (dscfm)                                        0.420
Standard Metered Volume (dscf)                                     100.847
Standard Metered Volume (dscm)                                       2.856
Stack Moisture (%V)                                                   5.06
Mole Fraction Dry Stack Gas                                           0.949
Dry Molecular Weight                                                 28.88
Wet Molecular Weight                                                 28.33
Stack Gas Velocity (fpm)                                            2282.33
Stack Gas Velocity (mpm)                                             695.65
Volumetric Flow Rate (acfm)                                         7780.10
Volumetric Flow Rate (acmm)                                          220.33
Volumetric Flow Rate (dscfm)                                         5861.72
Volumetric Flow Rate (dscmm)                                        166.00
Percent Isokinetic                                                    96.92
Percent Excess Air                                                  1992.23
 Concentration  (g/dscm)                                                0.00
 Concentration  (kg/hr)                                                  0.00
 Concentration  (ppmv)                                                  0.00
 Emissions (Ib/hr)	0.00

-------
         Eastern Research Croup. Inc.
                                              MODIFIED METHOD 5 DATA SHEET
                                                                                                                    Run
                                                                                                                    Page 1 of
Plant
Date
Operator
Sampling Location TW-f ft*-
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
( .-if /SJ A*.
il/t/o*
r^^fi/ T*
i)wjji»> .ajrU'T
P.uX,r\
3
I./NS'1'
I^.M.
XAD Trap Number.
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
—
T.V>
i-' f\^-X
2 SO
fcO
ourW
.f\f(Q(0"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-3-S
!.•*&
.^tfl
o.ll5"
36-
«
i.fel
•>
Diagram of Duct
                                                       Schematic of Traverse Point Layout
                                                        Read and record all data every	minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
                       Gas
                       Meter
                      Reading
                     ((Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
 Orifice Pressure
    Differential
 (delta H, in.H2O)
Desired ,   Actual
Probe
Temp.
 (•F)
 Filter
Temp.
Adsorbent
  Trap
 Temp.
  (•F)
                                                                                                               Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  (QF)
 Pump
Vacuum
 (in.Hg)
          10
                                                             .13
                                                           2VO
                                                                                                                      MO
         •1.0
                                    n
                                                                                                           49
                                                                                         £,«•»
                   /(,. 25*
                                                                                                                                .r
                   1C.
                  Zt *.i .
                     .. zz
                                                                                                                     Vo
                   It ••
                  7.-1
                                                           L-MO
                                                                               1H2.
                                                                               -7
                                                                                                   52-
                                          ,5"
                                                                                                  5.1
                                                                                                                    3.5'
         V;
         ft: if
                                                            .75
                                                                                                                     Ml
100
                                                   7.07.
                                                   1 . SI
                                                  I..SI
                                                   20 H
                                                            t.5-1
                                                                             3
   n
rw
                      I.I
                                         205"
     13.
•30
                              •Z.O'/
                                                   l-l?-
                                      iss"
                                              MO
                                    ST.
                   151 .
                       .. 3
                              toiT
                                                                               T-M5"
                                                                                                                     ft
                                                                                                                   *
                                                   •LOJ
                                                                                                  2L
                                                                                                  HS
                                                                                                  53
                                          -S"
                                                                                                                     HO
      f>
                                          m.
                                                                                       50
                   •^ : 33
                                                                                                                     H/
                   JHS
      5
                                .0?)
                                         . oi'
                                                                                         Ml-
                                          , OH
                                                              01,
                                                                    IMS'
                                                                                         HI
                                                                                                                     Ml
                   70
                                                            -=_0jz_
                                                                              BO.
                                                    .&(£>!&
Comments:

-------
Plant
Date


Location
Sample Type


Run Number
Operator


Traverse
Point
Number













/



<


-•-'














Sampling
Time
(min)





















»













Clock
Time
(24hr)



































Gas
Meter
Reading
((Vm).ft3)



































Velocity
Head
((delta Ps),
in.H2O)



































Stack
Ts
(°F)



































Orifice F
Differ
(delta H,
Desired



































'ressure
ential
in.H2O)
Actual



































Probe
Temp.
(°F)



































Filter
Temp.
(°F)



































Adsorbent
Trap
Temp.
(•F)



































Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)






































































Impinger
Exit
Temp.
(•F)



































Pump
Vacuum
(in.Hg)



































Comments:

-------
Eastern (-,- (^,.hlG. / (^.v^A (^..r-K^




    Impinger
    Number
Impinger
Solution
Amount of
 Solution
   (9)
Impinger Tip
Configuration
                                                    Impinger Wefght
Final
 (9)
Initial
 (3)
Weight
 Gafn
  (g)
                                      r^ Hp)
                                                   ^3.7
                         I CC
                                  2 . 5"
                                                                    » 7
                   Gel
                                     Total Weight Gain (g)
                                                 JS3-7

-------
Facility:          Gulp Alum. Alloy
Date:           12/8/97
Location:        Furnace Inlet
Run  Number:              1
Sample Type:    M26  	
Total Sampling Time (min)                                                    327.0
Corrected Barometric Pressure (in Hg)                                         29.33
Absolute Stack Pressure (in Hg)                                               29.20
Stack Static Pressure (in H20)                                                -1.70
Average Stack Temperature (°F)                                              95.39
Stack Area (sq in)                                                          1134.11
Actual Meter Volume (cu ft)                                                 143.623
Average Meter Pressure (in H2O)                                              0.54
Average Meter Temperature (°F)                                              54.71
Moisture Collected (g)                                                        31.50
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   20.0
Nitrogen Concentration (%V)                                                   79.5
Dry Gas Meter Factor                                                       0.9800
Nozzle Diameter (in)                                                         0.155
Pitot Constant                                                                0.84
Average Sampling Rate (dscfm)                                               0.433
Standard Metered Volume (dscf)                                            141.734
Standard Metered Volume (dscm)                                             4.014
Stack Moisture (%V)                                                          1.04
Mole Fraction  Dry Stack Gas                                                  0.990
Dry Molecular Weight                                                        28.88
Wet Molecular Weight                                                        28.77
Stack Gas Velocity (fpm)                                                   3515.91
Stack Gas Velocity (mpm)                                                  1071.65
Volumetric Flow Rate (acfm)                                              27690.62
Volumetric Flow Rate (acmm)                                                784.20
Volumetric Flow Rate (dscfm)                                             25425.75
Volumetric Flow Rate (dscmm)                                               720.06
Percent Isokinetic                                                           102.46
Percent Excess Air                                                         1992.23
 Concentration (g/dscm)                                                       0.00
 Concentration (kg/hr)                                            .             0.00
 Concentration (ppmv)                                                         0.00
 Emissions (Ib/hr)	    	            0.00

-------
        Eastern Research Group. Inc.
                                           MODIFIED METHOD 5 DATA SHEET
[Run   i|,>J
 Page 1 of
Plant
MDate
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
l\u\f ALtiLU,^
iilSKn

CLM*. Ul<-\
AOL
I
- \-~\
^.^•>>
XAD Trap Number ^
Filter Heater Setting ("F) .
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

-i H k
MV'iM<'i
14%


\Cfl<£pfe"
Meter Box N',;nber
Meter delta H ©
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (CF)
Assumed Moisture (% H2O)
K-Factor
A-vo
i.TJi'f
.'XSn
.u>r^7->"



^*f **i * / ^S ^ '
>-
Diagram of Duct
                                                    Schematic of Traverse Point Layout
                                                     Read and record all data evary iQ  minutes
Traverse
Point
Number
fit
P
%
si
t
T\
ft^
/
£
ftf
I
i
M
«
3
/SI
I
I










Sampling
Time .
(min)
O
d iO
o iU
, "?o
r -\o
r st>
^ 1*0
^ 'To
< <3o
- lV^
\ IMO
^ iT^
IU)
lOD
i*D










Clock
Time
(24hr)
oS1^?
-lj* — _^*i
tx^Ti^Dc-^
/£>08
/oi8
It'tS
10 'iS
IftMS
iofiR
\>o-si
\nX
\\iS
,v^
•»n^
i\S»
\1C#
>Z|>
Lo.TL.
t-S ,?>(x.,
T D . ( f,
1 5".^-! .
8^ -TM
SS-.o
«^.a/i
^:i ss-
SI.UR
lol-S^
/C^.V^.
1 o^ . ^ r/»
U*-\
t|lo."7o










Velocity
Head
((delta Ps).
in.H2O)
!,?>
i ,\
1.)
1.?.
\ -^~
i.A.
»iV\
\-H-
\.y
i-tj
>. o
..o
.950
.xo
,«2-
;-)^
.1 rST
.l»1










Stack
Ts
CF)
2-oo
1(3
'AT
«8
lsfc
i5"0
So
1-t-,
IOQ
f^C^
\^C>
5tT
°ih
S':-T
T?
11
I '2.0
So
LiiM4-









Orifice F
Differ
(delta H,
Desired


















J ~ o 01









'ressure
ential
in.H2O)
Actual
^z-
.--T3
. u-i
,44.72-
•^C)
.ss'
.T£>
,-)8
.14
.S^
,M^
• S^T
-HL\
M^
•MS"
^^
.?*S
.'i7
U Q ( , "









Probe
Temp.
'CF)
i.-i~3
iz-t,
±1-1
<5-SO>
^-c.
^*~^>
AM?i
^^4
•^~»
Z52_
5.MU
X'-l'y
^^>('-)
•^lc.5,
2-Ua.
2t>(y
2^
•ili







f
/

Filter
Temp.
CF)
-32-
22f,
•^5V
•il-l
D->^\
^3")
3-^Jl
•«s
^3f
.^^i
2^ l
'^V
JL^
aT^(r
^S-)
2^-7
^7
2 si




^
•>




Adsorbent
Trap
Temp.
CF)




























DryGa
Inlet
(Tm in)
Si
T.3
^"•7
L.O
CoO
U,
(o-l
U'i
U
(*;<
L>I
^>JK
U>i
U,l
Ui
tp|
C,\
L,i










s Meter
Outlet
(Tm out)
M"1-
M2_
•A\
H^
MU
Hb
77
Ml
^
S*
M?
M*i
M^
N^?
W»
g« '
g^
MR










Impinger
Exit
Temp.
CF)
}3
5 >>
"W
7,
Si/)
s?
^^
^
so
Vn
31
"SSf
=5S>
•5C/
?9
^9
^
^










Pump
Vacuum
(in.Hg)
^S
f.l
.i*
Jf
r?
^
^
5T-
ST

-------
Plant
Date


Location
Sample Type


Run Number
Operator


                                                                                                                            PagdHbf	
Traverse
Point
Number





























s
s




Sampling
Time
(min)
ISO


























..
s






Clock
Time
(24hr)
l^MVfcT






















."'
s










Gas
Meter
Reading
((Vm).ft3)
vVL'Vlo

















*
,.-•
s
x
,''













Velocity
Head
((delta Ps).
in.H2O)

,S1















.•
-"
















Stack
Ts
(°F)

l-Zo

































Orifice F
Differ
(delta H,
Desired










r.'"
..'•'























'ressure
ential
in.H2O)
Actual

iMJ?





/
S
S''
/

























Probe
Temp.
CF)





^
/'




























Filter
Temp.
CF)




..-'•






























Adsorbent
Trap
Temp.
CF)



































Dry Gas Meter
Inlet Outlet
(Tm in) I -(Tm out)
^__ .- "
. ^*




































































Impinger
ExA
Temp.
CF)



































Pump
Vacuum
(in.Hg)



































Comments:

-------
Plant
Date
£uup
li_m<}T
Location
Sample Type
£v««v».C•/
                                               "7S
       V
                                                                                                                          In
     A 3
                                               -71
                                                          •11
       3
                                               IT
                                                                                                                       Ml
     (VM
                                               So
                                                                                Lit
            •300
                                     LOST
                                                                                                                                  c2-
    A  *5
                                                                              Z'S'
               2. -1
Comments:

-------
                                          MODIFIED METHOD 5 DATASHEET
Ru
Page
bf
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure^) (in. H2O)
Barometric Pressure (in. H2O)








XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check







Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor








Diagram of Duct
                                                   Schematic of Traverse Point Layout
                                                    Read and record all data every	minutes
Traverse
Point
Number




























Sampling
Time
(min)





























Clock
Time
(24hr)





























Gas
Meter
Reading
((Vm).ft3)





























Velocity
Head
((delta Ps).
in.H2O)




























Stack
Ts
<°F)




























Orifice F
Differ
(delta H,
Desired




























'ressure
entJal
in.H20)
Actual




























Probe
Temp.
(°F)




























Filter
Temp.
(°F)




























Adsorbent
Trap
Temp.
(°F)




























DryGa
Inlet
(Tm in)




























s Meter
Outlet
(Tm out)




























Impinger
Exit
Temp.
(°F)




























Pump
Vacuum
(in.Hg)




























Comments:

-------
Facility:          Gulp Alum. Alloy
Date:            12/9/97
Location:        Furnace Inlet
Run Number:              2
Sample Type:    m26	
Total Sampling Time (min)                                                   340.0
Corrected Barometric Pressure (in Hg)                                         29.29
Absolute Stack Pressure (in Hg)                                              29.19
Stack Static Pressure (in H20)                                               -1.40
Average Stack Temperature (°F)                                             113.15
Stack Area (sq in)                                                         1134.11
Actual Meter Volume (cu ft)                                                141.637
Average Meter Pressure (in H2O)                                              0.95
Average Meter Temperature (°F)                                              62.09
Moisture Collected (g)                                                       40.80
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   20.0
Nitrogen Concentration (%V)                                                  79.5
Dry Gas Meter Factor                                                      0.9800
Nozzle Diameter (in)                                                        0.156
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.405
Standard Metered Volume (dscf)                                            137.578
Standard Metered Volume (dscm)                                             3.896
Stack Moisture (%V)                                                         1.38
Mole Fraction Dry Stack Gas                                                 0.986
Dry Molecular Weight                                                       28.88
Wet Molecular Weight                                                       28.73
Stack Gas Velocity (fpm)                                                  3369.28
Stack Gas Velocity (mpm)                                                 1026.96
Volumetric Flow Rate (acfm)                                              26535.74
Volumetric Flow Rate (acmm)                                               751.49
Volumetric Flow Rate (dscfm)                                             23518.44
Volumetric Flow Rate (dscmm)                                              666.04
Percent Isokinetic                                                          102.09
Percent Excess Air                                                        1992.23
 Concentration (g/dscm)                                                      0.00
 Concentration (kg/hr)                                                        0.00
 Concentration (ppmv)                                                        0.00
 Emissions (Ib/hr)	    0.00

-------
         Eastern Research Group. Inc.
                                                MODIFIED METHOD 5 DATASHEET
                                                                                                                         Run    F
                                                                                                                         Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
C'-av.r (\L. Aii-i>^
.MlNTi
^Orf-iiS
^-u-tvx. 1*\
-------
Plant
Date
CoA.f
10-\dt^~_
 Traverse
   Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
  Gas
 Meter
Reading
«V").n3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
Orifice Pressure
  Differential
(delta H, in.H2O)
         Desired
Actual
          Probe
          Temp.
 Filter
Temp.
 CF)
Adsorbent
  Trap
  Temp.
   CF)
  Dry Gas Meter

 Inlet     Outlet
(Tm in)    (Tm out)
Impinger
  Exit
 Temp.
  CF?
 Pump
Vacuum
 fln-Hfl)
            VXO
            KS1
         ii°o.
                                1 1
                                                         1 1 O
                                                                                                           I.T
                                                                                                                                                 cs
                                                                                      T-S1
                                                                                                           10
                                                                                                                     "70
     (Sr
             2 2-
                                                                   H5T"
                                                                                                                  Ml
                                                                                                                     7|
                                                                                                                             Mi
                                                                                                                                        Hi
            Z-SO
                                                                                                           10
                                               AT—
                      no 7
                                                                                     O U O
                                                                                               10
                                                                     ST7
                                       .O
                                    •l-z-
                                                       • Tl
                                                             -70
                        ar?
                                    n.
                                     ,7
      .-31
                                                                                                                              * JC
Comments:

-------
Facility:           Gulp Alum. Alloy
Date:            12/10/97
Location:         Furnace Inlet
Run  Number:              3
Sample Type:     M26	
Total Sampling Time (min)                                                    332.0
Corrected Barometric Pressure (in Hg)                                         29.32
Absolute Stack Pressure (in Hg)                                               29.22
Stack Static Pressure (in H2O)                                                -1.40
Average Stack Temperature (°F)                                             114.85
Stack Area (sq in)                                                        1134.11
Actual Meter Volume (cu ft)                                                138.653
Average Meter Pressure (in H2O)                                             0.96
Average Meter Temperature (°F)                                              73.00
Moisture Collected (g)                                                        42.20
Carbon Dioxide Concentration (%V)                                             0.5
Oxygen Concentration (%V)                                                   20.0
Nitrogen Concentration (%V)                                                  79.5
Dry Gas Meter Factor      "                                                 0.9800
Nozzle Diameter (in)                                                         0.155
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                               0.398
Standard Metered Volume (dscf)                                           132.051
Standard Metered Volume (dscm)                                             3.740
Stack Moisture (%V)                                                         1.48
Mole Fraction Dry Stack Gas                                                  0.985
Dry Molecular Weight                                                        28.88
Wet Molecular Weight                                                        28.72
Stack Gas Velocity (fpm)                                                  3417.98
Stack Gas Velocity (mpm)                                                 1041.80
Volumetric Flow Rate (acfm)                                              26919.36
Volumetric Flow Rate (acmm)                                                762.36
Volumetric Flow Rate (dscfm)                                             23786.58
Volumetric Flow Rate (dscmm)                                               673.64
Percent Isokinetic                                                          100.50
Percent Excess Air                                                        1992.23
Concentration (g/dscm)                                                      0.00
Concentration (kg/hr)                                                        0.00
Concentration (ppmv)                                                        0.00
Emissions (Ib/hr)	  	       0.00

-------
         Extern Rnearch Group. Inc.
                                              MODIFIED METHOD 5 DATASHEET
                                                                                                                     Run    E
                                                                                                                     Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Cidf AUIW,
a\»o\^-7
\i**tt**-ic. —
t-LLLvt . L*V\ •
*c£
3,
-\.vjl

XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

•2J$
VGl+**>
2M-S'

o.ooVfelO
•oor
                                                                         ,  vz.
                                                                                                      o
                                                                                                    -7C
                                100. IZ-
                                                                                                               Wi
            Ikn
                                                                                                       °
                                                                                                    70
                                                              0 , CO <
                                                                                             u~7
                                                                                                     •-/I
                                                                                                    fci'
                     NCI
                      112
                                             /.i •>
                                                                                                    feifl
                               •UL&-
                                 I00_
                                                                                                                .
                                                                                                   J£_
                                                                                                                        iTl
                                                                                                                                          .vi.
                                  _^lLL
                                                     -XLL
                                                                                                               .57
                                             .MIU
                                            fHO
           l^
iSHL
                               f ••%=!> .T
                                                                                  7.S7T
                                                                                                             .TV
                    j^i
                                  jis:
                                                                      -24^
Comments:

-------
Plant
Date
(jLLLp"
)£r/
V£0
"W-.
WHXV
->0>
"?)/>0


























Clock
Time
(24hr)
(bit
|id'2i
IV^>'
/^^/
nAn
Gas
Meter
Reading
((Vm),tt3)
NU,^(/
/ ^7) . K3.
/\^to\
/JT9.9
;b5i">S
1-70 / p/ia-^r—
po?. I luA.^i'ri
\
l\l&.(* ^


























•

























Velocity
Head
((delta Ps),
in.H20)
.
cfZ-




























Orifice F
Differ
(delta H,
Desired
8*o
.5t>
,^7)
.s"
..a-sT^




























Adsorbent
Trap
Temp.
CF)



































DryGa
Inlet
(Tm in)
£-76
r.
-] L-
-7^-"
ir
1^
-1(4
"?4




























s Meter
Outlet
(Tm out)
M
(a'<
d> ?.
(*-L-
L>-2~-
(*/
(ni




























Impinger
Exit
Temp.
(°F)
,C2_
^<
?;?j
^5~/
s-/
T/
3~l




























Pump
Vacuum
(in.Hg)
^^
^
^
c^
3
^
^\




























Comments:

-------

Facility: iCulp Alum. Alloy
Date: ! 12/11/97
Location: ; Furnace Inlet
Run Number: ! 4 1
Sample Type: im26 i

Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H20)
Average Meter Temperature (°'F)
Moisture Collected (g)
Carbon Dioxide Concentrationi(%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V) :
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling: Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V) :
Mole Fraction Dry Stack Gas '
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr) '.
Concentration (ppmv) ;
Emissions (Ib/hr) :


,.

















































































j





\
i 380.0
29.99
29.87
-1.70
106.66
! 1134.11
! 130.367
! 0.82
54.59
: 79.30
0.5
20.0
i 79.5
; 0.9800
0.152
0.84
0.346
; 131.501
3.724
2.76
0.972
28.88
28.58
2870.78
875.01
22609.70
640.31
20447.60
579.08
: 105.78
I 1992.23
0.00
0.00
! 0.00
0.00

-------
        Eastern Research Group, Inc.
                                            MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant ft|,Jlp
Date '
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Alij i/rj/ilL/*
Id- lUS^
M/HFs
fT_kff\ l/TU>f
fii.',c
<4
-*/-•)
,50
LXAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
INA
;^s-^
4-' C'-ilA.)
3<.L>
^|
PClZfr:' 'l
,o*.-.<97
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
r\ -^o
/ "7^3
!*7&r
.(s^
'#£,'
• **f


Diagram of Duct
                                                     Schematic of Traverse Point Layout
                                                      Read and record all data every  V O  minutes
Comments:

-------
Plant
Date
(LuJ^o
/3 -'/'-<} -7
Location
Sample Type
flX/^W _^J
A/ 24?
Run Number
Operator
-& 	
ACrG?
Traverse
Point
Number

*r '-/
i -»

,5"


U



























Sampling
Time
(min)
vPTO
3-&U
>V
ik/r
O / c;
3Z^;
330
:J «*.l>
.3 .Y2J
^kC>

1^
fd^ir-






















Clock
Time
(24hr)
(/Cf>
II/L,
n&l*
! i &..
/nJ-L,
/n'Z
i.U)L>
I&H»
iT^L
ISM,
f^Rjf
i.'^t
-i3 0 a






















Gas
Meter
Reading
((Vm),ft3)
/L~i_0l-
fo'/.L^
iiln
1 7v. 7;?
/ "vtf.i;
/^/.«/U
/flf-.-fr
/b^-7z_-
/O/. e'"^
/ '//37f























Velocity
Head
((delta Pe),
ln.H20)

. t»0
/:-6
.(^^
.fe.fc
. '
. J
, ^J-'j
—7-t?6) 	






















Stack
Ts
CF)

^t'
Br
«'->
^
^
&?.3
•^^
43 ;>
q/
^?
t'i»


U&ttC-




















Orifice F
Differ
(delta H.
Desired
l 	 • 	
A/Al





















( £«_




















'ressure
ential
ln.H20)
Actual

.&
,.^r
. ,a-^>
••'T"
.,^7
,,>9
..->c
, ^'7
.-z.'?
7-4-
.J>


JO. &




















Probe
Temp.
(*F)

r^«CT
-3TY-
-J)T3
?-jy
,9^-^
A7?
,ac/
•^S'C-
p>"d_
c^SV
^S7


7''^/v
k
v/


















Filter
Temp.
CF)

-9vn-
/5t/6
:?f7
2V/6
f-=5rf2.*
&T~f
pt5S
.5V/
•#S"2
^5^
-.^.S'2-























Adsorbent
Trap
Temp.
L ('F)

^^
V-:T,
*f-.a>
v/

41
•J.J























DryGa
Inlet
(Tmln)

f^:-?
<^3
(^;3'
L-->
C^.3
.r^-j
/
<*'
>~u
'*Z>
ST-
5Z;
STj
<"-f























Impinger
Exit
Temp.
(•F)

<1
j s
C* s—
3 T
3 N-
3 •>-
? r























Comments:

-------
Facility:           Gulp Alum. Alloy
Date:             12/8/97
Location:         Furnace Inlet
Run Number:       1
Sample Type:     M23	
Total Sampling Time (min)                                             327.0
Corrected Barometric Pressure (in Hg)                                  29.33
Absolute Stack Pressure (in Hg)                                        29.20
Stack Static Pressure (in H2O)                                         -1.70
Average Stack Temperature (°F)                                      101.76
Stack Area (sq in)                                                  1134.11
Actual Meter Volume (cu ft)                                          135.625
Average Meter Pressure (in H2O)                                        0.50
Average Meter Temperature (°F)                                       53.92
Moisture Collected (g)                                                 30.10
Carbon Dioxide Concentration (%V)                                       0.5
Oxygen  Concentration (%V)                                             20.0
Nitrogen Concentration (%V)                                            79.5
Dry Gas Meter Factor                                                0.9940
Nozzle Diameter (in)                                                  0.156
Pitot Constant                                                         0.84
Average Sampling Rate (dscfm)                                        0.416
Standard Metered Volume (dscf)                                     135.966
Standard Metered Volume (dscm)                                       3.851
Stack Moisture (%V)                                                   1.03
Mole Fraction Dry Stack Gas                                           0.990
Dry Molecular Weight                                                 28.88
Wet Molecular Weight                                                 28.77
Stack Gas Velocity (fpm)                                            3404.80
Stack Gas Velocity (mpm)                                           1037.78
Volumetric Flow Rate (acfm)                                        26815.50
Volumetric Flow Rate (acmm)                                         759.41
Volumetric Flow Rate (dscfm)                                       24344.11
Volumetric Flow Rate (dscmm)                                        689.43
Percent  Isokinetic                                                   101.35
Percent  Excess Air                                                  1992.23
 Concentration (g/dscm)                                                0.00
 Concentration (kg/hr)                                                  0.00
 Concentration (ppmv)                                                 0.00
 Emissions (Ib/hr)	                 	   0.00

-------
        Eaitem Research Group. Inc.
                                            MODIFIED METHOD 5 DATA SHEET
Run   \ruriA. \*\ -<3|
Page 1 of   2~
Plant
jDate
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) Jin. H2O)
Barometric Pressure (in. H2O)
tu If At M
i->\x\ca
\ ic>f^u£~
Fu.t.-o \*\
^vH

i.Cv't'Wll*
.00k$>"
Meter Box Number
Meter delta H @^
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
i&AVI
1. 12-'
•.°*"
b
— •
^v
^
fc
0










Sampling
Time
"1[min)
t>
it
1-o
'i«.
vo
TO
\>0
10
^
^
\ DO
\\0
\T-0
\^o
\^0
iSt>
UpO
i->0
fio










Clock
TlWe
(24hr)
cf\^
ei.^7
i"o1
101-7
( on
i <->»^~)
1^141
IQV1
no 1
iM T
\M,1
\\^T
>>M1
U=»l
11^1
\7-\'l
ILL?
l^n
ii-M-7
'••:



»





Gas
Meter
Reading
((Vm).ft3)
^ij.0oi_

Itl'.Ttp
So. i 7,
SH.U'Z-
S1.1-
^Xi.vi
Si.o-
I^J-.t,!
i oi.fc^
U\,u«-^
\A\,..^-\
• tO.T^
1 I f. v^-
\^-S.T-
m i4^~










Velocity
Head
((delta Ps),
in.H2O)
1 ,V
.^U-
i ,\
/.7^
1 >\
1 4
I.I
1 .\
\.(
\.1—
\,2-
\,\
\.\
t,\
\. \
.£/^
(.0
,x*










Stack
Ts
(°F)
-t-o«o
<\^-
'MU
cl?
^*t5(f,
' i Z^
?^
|CXj
LHh










Orifice F
Differ
(delta H,
Desired




0 .V3













C'/Ht









'ressure
ential
inH2O)
Actual
• ^
.Mo
•^.3
.u-
.^v*r
. -i"^~
,S"V
••S7
. ;T5"
.\,"l~.
,.-i.f-
. ;J«i
.^"'1
.^
•^1
.^i
•^
.MT
L,''-^.00









Probe
Temp.
(•F)
i3ft
^-so
A^VI
X^H
JL^S
12^}
^2F
2>f
LT-^i
\^
'¥*\
b^CL-
6±\^
^HS"
iKM-^
>IT_
T-ST_
^>'-^
6S









Filter
Temp.
CF)
7H2-
a^^
^.-•^
VMJ-
.XH^
-i^U
:Xu~\
r*-Mu
.>ss-
^•\l.
i^
;IYJ
^3CP
x^fc.
•J3\
l^u
.XUI
.Am a










Adsorbent
Trap
Temp.
(°F)
-//
H/
HT—
sr^/J^
^T-
^2_
M7-
m_
4^
su
H^
Mi
^
Hs^
M^
H.\
M2_
SX










DryGa
Inlet
(Tmin)
Hi
S"!
S" j~
$<*
•Ci
iTT
b"S>
i"y

«•«?
WV
M










Impinger
Exit
Temp.
'(•F)
1
^
3L
'il
^
4i
^i
H|
42--
W3
<-V^|
S^j
MM
Mi-
Mu
VL
^L
^/.s—
v.^










Pump
Vacuum
(in.Hg)
3
i.
-5
S
M
i
J^
:-i
'j)
5~
•5j~-
G
u
1
(/,
I
k'
c/,
L










Comments:

-------
                    Plant
                    [Date
                            CjULUf
Location
                                         Sample Type
        Run Number
                                       Operator
                                                                                  1
 Traverse
   Point
 Number
        Sampling
          Time
          (mm)
Clock
Time
(24hr)
  Gas
  Meter
Reading
«V"i).lt3)
 Velocity
  Head
((delta Ps),
 in.H2O)
 Stack
  Ts
_m_
                       Orifice Pressure
                         Differential
                       (delta H, in.H2O)
                     Desired
Actual
Probe
Temp.
 CF)
 Filter
 Temp.
_CD_
Adsorbent
  Trap
  Temp.
  CF)
  Dry Gas Meter

 Inlet      Outlet
(Tm in)    (Tm out)
Impinger
  Exit
 Temp.
  CF)
 Pump
Vacuum
 Cn.Hg)
             M180
            10
                                                       12-0
                                                                        -L\0
                                        -ZSD
            to
                                           .11
       la
                                                                                 JkHl
            HO
                                                                        .•m.
                                                                                                                                     Vo
            1,0
                             I "\Li.ra
                                                  XML.
                                                                                                                                    W 1
                                                                   I A
Ai
                                 IV?.
            So
                                           1.0
                                                   7.S)
            So
                                               ,19s
      3
            \u>
                                                                                                     VA
                                                                                                       Mi
                                                                                                               (H
           ISO
                                     .<» u ^
          t
                                                        *-*¥-
                                                                            7"
Comments:

-------
Eostarn Raseorcn Gfcco. !nc
               MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number ; :
XAD Number
i .1 lp M 1 ,1 MX, (^tiixx v~t HC-.U
/a 2 ^
fcf.i. JAJU&T
r>s4-v^. ^
**±

/Ho^ ft.,U^ / r*^^\ (^,,r-K^
M^cL /Ac^
J /


    Impinger
    Number
Impinger
Solution
Amount of
 Solution
   (9)
Impinger Tip
Configuration
                                                    Impinger Wefght
Final
 (g)
Initial
 (9)
Weight
 Gain
  (g)
                                                       $00%
                                                    /
                         I CO
               \-\2p
                    ~y
               i I, ca Gel
          •IOC -360
                                hX
                                      Total Weight Gain (g)

-------
Facility:          Gulp Alum. Alloy
Date:            12/9/97
Location:         Furnace Inlet
Run Number:      2
Sample Type:     M23	
Total Sampling Time (min)                                             342.0
Corrected Barometric Pressure (in Hg)                                  29.32
Absolute Stack Pressure (in Hg)                                        29.22
Stack Static Pressure (in H20)                                          -1.40
Average Stack Temperature (°F)                                       114.14
Stack Area (sq in)                                                  1134.11
Actual Meter Volume (cu ft)                                          134.327
Average Meter Pressure (in H2O)                                        0.91
Average Meter Temperature (°F)                                        59.53
Moisture Collected (g)                                                 42.20
Carbon Dioxide Concentration (%V)                                        0.5
Oxygen  Concentration (%V)                                             20.0
Nitrogen Concentration (%V)                                            79.5
Dry Gas Meter Factor                                                0.9940
Nozzle Diameter (in)                                                  0.155
Pitot Constant                                                         0.84
Average Sampling Rate (dscfm)                                        0.384
Standard Metered Volume (dscf)                                      131.206
Standard Metered Volume (dscm)                             .          3.716
Stack Moisture (%V)                                          .1.49
Mole Fraction Dry Stack Gas                                           0.985
Dry Molecular Weight                                                 28.88
Wet Molecular Weight                                                 28.72
Stack Gas Velocity (fpm)                                            3255.36
Stack Gas Velocity (mpm)                                             992.23
Volumetric Flow Rate (acfm)                                        25638.52
Volumetric Flow Rate (acmm)                                         726.08
Volumetric Flow Rate (dscfm)                                       22680.61
Volumetric Flow Rate (dscmm)                                        642.31
Percent  Isokinetic                                                   101.67
Percent  Excess Air                                                  1992.23
Concentration (g/dscm)                                                0.00
Concentration (kg/hr)                                                  0.00
Concentration (ppmv)                                                  0.00
Emissions (Ib/hr)	                      0.00

-------
         Eastern Research Group. Inc.
                                               MODIFIED METHOD 5 DATASHEET
                                                                                                                       Run    P
                                                                                                                       Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (t) (in. H2O)
Barometric Pressure (in. H2O)
/'L,^//Hlt/C1
ii-l ^ 11 -1
I)d-t44t^
fU^rt l^ict
^tStti'c-AF
1_
- m
-LVbO
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

^^

-we

O OltifJif
0.00010"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A ST(
1. T2-
•m
• ir^->



/
Diagram of Duct
                                                         Schematic of Traverse Point Layout
                                                          Read and record all data every	minutes
 Traverse
 . Point
 Number
Sampling
  Time
  (min)
            JL
Clock
Time
(24hr)
                            Gas
                           Meter
                          Reading
                          <(Vm),ft3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
  Orifice Pressure
    Differential
 (delta H, in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
  Temp.
                                                                                                                  Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  (•F)
 Pump
Vacuum
 (in.Hg)
             |0
           7.20
                         /
            It)
                                                                                   -2. Si
                                                       no
                                                                 .5ft
                                                                                             bl
      61
                                                                                                                           4V
i
                                                      10 >
                                                                                                                           HM
                                                                                                                         IP
            Oo
                                                                                                                           Mi
            no
                                                                                                                          •&-
                                             ^
     fet
                                   .'i -s
            \\o
                                                                                             zr-?
            l'1-O
                                                                                                        MT
            \MO
                                             .?§
                                < V.
                                                                          - "JO
                                                                                                     X*
            no
                                                                            fT
                                                                                  •r\
                               11,1.
                                                                         2.-JG
                                                                                   16"
     ft t
                                                                         i CM
           -Z.ee,
                                             •"
                                                                                                                  u?
                                                                                                                                    13
    A3
      -V
                                                                    3$
                                                                    TTi
                                                                                             HO
                                                                                                      SS
Comments:
                                                                                                                 Iff!
                                                                                                                                       •r  '   7

-------
                    Plant
                   (Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number

3H°
•ZS&ly
'itfO













•'












Clock
Time
(24hr)^
Hie
VTZ-'o
I'liCp
n«4u
nf^v
\so^-
i^/U-
isu



























<,< Gas
^P Meter
Reading
((Vm).tt3)
^ol
z-os-,^
^ol •S')
A'^.T^
£zj-r^2'6.^
•7.Z' ,O
t ir,19)
\ z <* . az.^



























Velocity
Head
((delta Ps).
in.H2O)
.v4-
.50
.SO
,80
,So
,8'i-
,^/D
.?0



























Stack
Ts
&}
61-
^^
5?^
Kt:\
«?ri/
iS^3-
^/'/
2WY
.D'-


























Firter
Temp.
(°F)
T-S"1?
1^5
7.S1
'iSb
z^rv
7JTZ-
Z.\7
-r.S"7_



























Adsorbent
Trap
Temp.
(°F)
M^
M"\
^
S~\
^3
STS-
•r<^
5n



























DryGa
Inlet
(Tm in)
ok
(oU .
on
«p"7
Lp~l
Ul
CP?
fc7



























> Meter
Outlet
(Tm out)
S'6
S^
^6>
^
s;£
Z8
^x
±-£



























Impinger
Exit
Temp.
CF)
H&
^M
5C>
S"^-
4T^
^i
A"<^
i-7
'


























Pump
Vacuum
(in.Hg)e.
f.r"


<^
9
&
X
X



























Comments:

-------
"?e*eorcn Gf
           MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number ;
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number ;
XAD Number
r,, V^ . ft^^.r^vNN R \UV
• - t T
R'Y'L /A/ LET
n.fU^. -Q/5
&$,

tf}nt~S f^,iie_ / (\f\\.r~\ (a,iLl-\
-------
Facility:          Gulp Alum. Alloy
Date:            12/10/97
Location:         Furnace Inlet
Run Number:      3
Sample Type:     M23	
Total Sampling Time (min)                                              333.0
Corrected Barometric Pressure (in Hg)                                   29.32
[Absolute Stack Pressure (in Hg)                                         29.22
Stack Static Pressure (in H2O)                                          -1.40
[Average Stack Temperature (°F)                                      116.47
Stack Area (sq in)                                                  1134.11
Actual Meter Volume (cu ft)                                          142.514
Average Meter Pressure (in H2O)                                         0.98
Average Meter Temperature (°F)                                        72.44
Moisture Collected (g)                                                  32.30
Carbon Dioxide Concentration (%V)                                        0.5
Oxygen Concentration (%V)                                              20.0
Nitrogen Concentration (%V)                                             79.5
Dry Gas Meter Factor                                                0.9940
Nozzle Diameter (in)                                                   0.156
Pitot Constant                                                          0.84
Average Sampling Rate (dscfm)                             ,            0.414
Standard Metered Volume (dscf)                                     137.833
Standard Metered Volume (dscm)                                        3.903
Stack Moisture (%V)                                                    1.09
Mole Fraction Dry Stack Gas                                            0.989
Dry Molecular Weight                                                  28.88
Wet Molecular Weight                                                  28.76
Stack Gas Velocity (fpm)                                            3486.72
Stack Gas Velocity (mpm)                                            1062.75
Volumetric Flow Rate (acfm)                                        27460.70
Volumetric Flow Rate (acmm)                                         777.69
Volumetric Flow Rate (dscfm)                                       24293.10
Volumetric Flow Rate (dscmm)                                        687.98
Percent Isokinetic                                                   101.10
Percent Excess Air                                                  1992.23
 Concentration (g/dscm)                                                 0.00
 Concentration (kg/hr)                                                   0.00
 Concentration (ppmv)                                                  0.00
 Emissions (Ib/hr)	'   	Q.QQ

-------
         Eaitcm Research Group. Inc.
                                               MODIFIED METHOD 5 DATA SHEET
                                                                                                                              Run
                                                                                                                              Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
CuAP
i-2i,om
^b^c^ 	
VLLC*\ (A\
-
2>
-u<\

XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°FJ^
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

T-W
^£H*s
OU.S

Q_.O 1 5
                                                                                                                                s-T
                     -iiiCiL
                                          XL
                                                                                                               4T
Comments:

-------
                    Plant
                    Date
Location
Sample Type
                                                                                   Run Number
Operator
Traverse
Point
Number
AM
H
*•(
4 £
^
f
A (,
(,
k>







"-,

, •,,
•.'-,




S,.-










Sampling
Time
(min)
zyo-
t^o
'}oc>
IIG
"^'Z.U
~yr>.->
'3>'5>3*











-." ..*=A.
•"^•^ '















Clock
Time
(24hr)
1 
)U2o
1 (p'^Q
/tcH^5
Jto ^
rtcc
C7O-3»




























Gas
Meter
Reading
((Vm),n3)

1 S" 1 . V T^
i Cr/iS"~
/ L>O. 7.%
l(pU, (,v
(U'liS-
l9o>J5~7v/




























Velocity
Head
((delta Ps),
in.H2O)
I.I
/. /
/ o<>"
/ . C5
l-i'i
l.o <*'"
; nT




























Stack
Ts
CF)

3 0
'7
i S"~1
,5—)
S^o^.f



























'ressure
ential
in.H20)
Actual






.5
iy*6»'''


•^ >• .,
>
-;.




1 '
J
.--*• i



t
I
,.
j,
_» ; .
\
'









1


i

.,.
1'





1,
Probe
Temp.
CF)
Z.5TI
2_y 2_
zVs^
2^5"
'2. V /^
*7 ^/*(/
^.<>^-




























Filter
Temp.
CF)

Z-t/s^
'2U/f^
2^*7
^"VS
"^-ji^f^j
a 4-\




























Adsorbent
Trap
Temp.
CF)

5^-f

4:^~-
6-^ —
(fH




























Impinger
Exit
Temp.
.C7
."V1?
6?ts
t^jj
.r<^
^\"^-
^r~ <,J




























Pump
Vacuum
(in.Hg)


-------
Pesaorcn G'Ouo. :nc.
          MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f ; i-Ap,. rl 1 ,i MS.. f-iii.fVN H Ufty
/.i //»/«* 7-
£
-------
Facility:
Gulp Alum.
Mloy
Date:
  12/11/97
Location:
Furnace Inlet
Run Number:
Sample Type:    IM23
Total Sampling Time (min)
                                                          380.0
Corrected Barometric Pressure (in Hg)
                                                          29.99
Absolute Stack Pressure (in Hg)
                                                          29.87
Stack Static Pressure (in
                                                          -1.70
Average Stack Temperature (°F)
                                                         101.08
Stack Area (sq in)',
                                                       1134.11
Actual Meter Volume (cu ft)
                                                       133.655
Average Meter Pressure (in H2O)
                                                           0.83
Average Meter Temperature (°F)
                                                          55.03
Moisture Collected (g)
                                                          23.70
Carbon Dioxide Concentration!(%V)
                                                            0.5
Oxygen Concentration (%V)
                                                           20.0
Nitrogen Concentration (%V)
                                                           79.5
Dry Gas Meter Factor
                                                         0.9940
Nozzle Diameter (tn)
                                                          0.155
Pitot Constant
                                                           0.84
Average Sampling Rate (dscfm)
                                                          0.360
Standard Metered Volume (dscf)
                                                       136.643
Standard Metered Volume (dscm)
                                                          3.870
Stack Moisture (%V)
                                                           0.81
Mole Fraction Dry Stack Gas
                                                          0.992
Dry Molecular Weight
                                                          28.88
Wet Molecular Weight
                                                          28.79
Stack Gas Velocity (fpm)
                                                       2902.14
Stack Gas Velocity (mpm)
                                                         884.57
Volumetric Flow Rate (acfm)
                                                      22856.65
Volumetric Flow Rate (acmm)
                                                        647.30
Volumetric Flow Rate (dscfm)
                                                      21296.01
Volumetric Flow Rate (dscmm)
                                                        603.10
Percent Isokinetic
Percent Excess Air
                                                         101.49
                                                       1992.23
                                                           0.00
 Concentration (g/dscm)
 Concentration (kg/hr)
                                                           0.00
 Concentration (pprnv)
                                                           0.00
 Emissions (Ib/hr)
                                                           0.00

-------
        Eailern Research Group. Inc.
                                          MODIFIED METHOD 5 DATA SHEET
                                                                                                            Run
                                                                                                            Page 1 of
Plant C.o-l/'
Date
Operator
Sampling Location f~u /
Sample Type
Run Number
Static Pressure (i) (in. H2O)
Barometric Pressure (in. H2O)
A-VX.*, 1^1^
\* ~ 11-1 ">
iV/f/*O
n/vcf (1 IfJ
MT_ -^
4


XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check

&^T~b
4' C7lA
3 fl)
fsrt,
O.O1'*?'0
.bdfc) "&'
t
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
fef-Factor
A _^S
' •'?2'
..<^;4
I5X"
•^,^
.. H


•' Diagram of Duct
                                                   Schematic of Traverse Point Layout
                                                    Read and record all data every t '    minutes
 Traverse
  Point
 Number
Sampling
  Time
  (min)
            o
         Clock
         Time
         (24hr)
                  CU3-O
  Gas
 Meter
Reading
((Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
 CF)
 Orifice Pressure
   Differential
 (delta H. in.H2O)
Desired   Actual
Probe
Temp.
 CF)
 Filter
Temp.
 CF)
Adsorbent
  Trap
 Temp.
                                                                                                       Dry Gas Meter
Inlet     Outlet
          (Tmin),
       (Tm out)
Impinger
  Exit
 Temp.
  (T)
 Pump
Vacuum
 (in.Hg)
                                                         /S/A
                                                                                                                       O
          .90
         HLHO
                                                                PTC,
                                                 tfc'-V
                                                                                   4?)
           40
                                                                                            S3
                                                                                                  S
                                        1.0
 -ft
                    t I
                                                                         14-U
                                                                                 4^
                                                                                 ^F
                                                                                                                       MH
                            (I'D O~7
                                                                                     a.
                                                    *
                                     -wa
                                     fee
                                                                                               2.
           \\j\j
                  in"7
             °
                  I 10.
                   otio
                  Li-i^
                                                 k
                                                                                                              •41-
                                                 1 OO
                                                                                            LsC
 Jv^O.
                                 i '3
                                                        3i
                                                                                  -^^
           IUD
                               • U.-
                                                         3 3
                                                                                                                                  .
m
                           1 3 1 .
                                                                                                      5"3
                                                                                                               C3
                                                           ~nz
 Tro
 _^3s3^o
                   CRSV
                                                        -^r
      
-------
                      Plant.
                      Date
                    4
^  T   7fc"
5VM7
                                 Location
                                 Sample Type
                                                               un Number
                                                             Operator
                                                                                                                                      Page
   Traverse
     Point
   Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
    Gas
    Meter
   Reading
  ((Vm),tt3)
 Velocity
  Head
((delta Ps).
 in.H20)
Stack
 Ts
 (T)
  Orifice Pressure
    Differential
 (delta H, ln.H2O)
Desired    Actual
Probe
Temp.
 (•F)
 Filter
Temp.
Adsorbent
  Trap
  Temp.
                                                                                                                       Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
                                 /6>
    (p.l
    vTg
                       //'
                                                                 . i
                                                                                                       5'
                                                                                                                     C,/

                                                                                                                                          S-3
                        n +G
                                                                                                         , /
                                                                                                                                                  3 ->
                                                                                                                               43,
                                                                                                                            _12_
                                                                                                                      ,/
                                                                                                                                     "3 .-
                                                  L>(o
                                                                                                                   S'/
                          i>4-
                                    33:
                                 -stf%-
                                              **
                                                                                                            v 
-------
Eastern Raieorcn G'Ot-p. Inc.
              MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
« * | • ......
Run Number : ;; < >
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f :, \r\ • r\\.t r^iC*, Q.MN R H ft \/
/ajjairf
R
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/08/97
Furnace out
  1
m26
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant  .
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
 Concentration (g/dscm)
 Concentration (kg/hr)
 Concentration (ppmv)
 Emissions (Ib/hr)	___
                                                    321.5
                                                    29.32
                                                    29.29
                                                    -0.30
                                                    89.35
                                                 1809.56
                                                 264.338
                                                     0.73
                                                    60.55
                                                    91.50
                                                      0.0
                                                     21.0
                                                     79.0
                                                  0.9810
                                                    0.256
                                                     0.84
                                                    0.807
                                                 259.294
                                                    7.343
                                                     1.64
                                                    0.984
                                                    28.84
                                                    28.66
                                                 2535.47
                                                  772.81
                                                31861.67
                                                  902.32
                                                29491.94
                                                  835.21
                                                    96.14
                                               -16380.66
                                                     0.00
                                                     0.00
                                                     0.00
                                                     0.00

-------
iaitem Rewirch Group, Inc.
                                                           OU  i
                                              MODipiED METHOD s DATASHEET
                                                                                                    yV-
                                                                                                     Run
                                                                                                     Page 1 of
Plant
Date • S.
Operator!
BampjjngiLocation FOtiJWHL
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O) *\<\!
CUe^ W_ 3 .
XAD Trap Number ;
Filter Heater Setting (*F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
—
•xco
6,'tyCtf
xca
<>D
.OtfQlO"
vftftii*
Met^Box Number^
Meter delta H @ • •
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (*F)
Assumed Moisture (% H2O)
K-Factor
A-38
\ &«C,
o.lfrl
o.-LSC
30 *
f).
H-\U

v ^ ,. . Diagram of Duct
   Traverse
     Point
   Number
 Sampling
  Time
  (min)
              O
Clock
Time
(24hr)
  Gas
 Meter
Reading
 Velocity
  Head
tfdelta Ps),
 in.H2O)
Stack
 Ts
Orifice Pressure
  Differential &'
(delta H in.H,2O)
                             Desired
                  Actual
Temp.
 Filter
^Temp.
Adsorbent
  Trap
 Temp.
  ('F)  .
                                                                                                            Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tmout)
Impinger
  Exit
 Temp.
  (T)
    r*'
 Pump
Vacuum
 (in.Hg)
   B-r*-
                                                  2-0
                                                30
                                                                                                      5-0
      ti-
  K
                              1 °O
                                                             3-D
                                      •J-o
                                                                                                                6.0
                    lo *d
                                                  ViV
      il
   30
                                                                                                               L.O
      ro
      t o
                                                  7-0
                                                                                                               Jo
                                                    100
                                                                             il
                                                                                                       Vo
                                                                                                     S-o
               bo
                   MvM
                                                             3.00
                                                            X 00
                                                                                                                SO
                     II '.i
                                                              10
                                                                                     foV
                                                                                                                                      v  o
                                             53
                                             *-
                                                              i  20
                                                   2-O
                                                Mo
                                                                                             VO
                      ! ( : -i
                                                           1-2-0
                     \ V:
                                                                             214
                     II- *K
                                                                                        'ISO
                                                                                                                          V 0
             •IH1S
          12
                                                 7ry*
                                                "rh
                                                            ji
                                                                            ^^^
                                                                                                     JLP_

                                                                                                                                       Y o
                     a. -
fc.
                                                                                                                              So
                                                                                                         - rz-
                                                                                                        Co
                                                                • o
                                                             /O
  Comments:

-------
                    Plant
                    Date
                   Mr*
                                 flc
             Location
                                Sample Type
                                                          ttcu -
                                      Run Number
                                                   Operator
 Traverse
   Point
 Number
Sampling
  Time
  (min)
                 Clock
                 Time
                 (24hr)
    Gas
   Meter
  Reading
  (Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H20)
Stack
 Ts
  Orifice Pressure
    Differential
 (delta H, in H20)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
  Temp.
                                                                                                                 Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
         13: i*..
                              Mi. 3k
                                   - V
                                           I 0-L.
                                 Z OH
                                 1 -QC-/
                              I.c-f
                                                                             U6O
                                                                         XO
                                                                                                      0
_a
                                                              T-iV
                                                                                 TI-
                                                                                                              ST.
S3fa.
                                            ,57,
                                                                                 2,$*
                                                                                                                   53
                                                                                               LL
      10
                                                                       it,
                                  . /
                                  , s /
                                                  SI
                                           1 1
                                        iSS
                                                         13
                           S
                                                    '1- ( 2.
                                                                    2-.il.
                                                                                  Ti,
                                                                                                                                  50
                                                                                                                               3-8
                                             ,4V
                                                                        •240
                    fft7^5
                                                                         l.Vi
                                                                                                                                  51
                                                                                                                                          3-2,
                                                                 J^k.
                                                                                                                      ^!L
                                                                                            7-tO
                                                                          t
                                                                                                                                          3.0
                                                                                            ifeO
                                                                                                      3 2-
           345
                                                                         I '.
Comments:

-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
  2
m26
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H20)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
vlole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
3ercent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)	
                                                    341.5
                                                    29.29
                                                    29.26
                                                    -0.30
                                                    99.91
                                                 1809.56
                                                 254.658
                                                     0.67
                                                    70.20
                                                  130.80
                                                      0.0
                                                     21.0
                                                     79.0
                                                  0.9880
                                                    0.256
                                                     0.84
                                                    0.780
                                                 266.319
                                                    7.542
                                                     2.26
                                                    0.977
                                                    28.84
                                                    28.59
                                                 2346.44
                                                  715.20
                                                29486.27
                                                  835.05
                                                26580.24
                                                  752.75
                                                  103.15
                                               -16380.66
                                                     0.00
                                                     0.00
                                                     0.00
                                                     0.00

-------
   i •' f:...  Eaitem Research Group. Inc.
                                              MODIFIED METHOD 5 DATASHEET
                                                                                                                   Run
                                                                                                                   Page 1 of
                                                                                                '•V, .
[plant ' C-Uwt>
Date
Operator v
Sampling Location FoftWfVic. ft
Sample Type
Run Number
Static Pressure (t) (in. H2O)
Barometric Pressure (in. H2O)
At— f\L--
i2-/q/f>
touif/TS
fOlhM-T
?rri/d
'o'tytoM
I£Q
C,o
.ol#9"
• HI&I0"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A "3V
i;s<3
o,9fe&
O.ZS&
Yo°
I?..
•:
                            TV
                                          .,  Schematic of Traverse Point Layout
                                              Read and record all data every  /• ^  minutes
 Traverse
   Point
 Number
Sampling'
  Time:
  (min)';-
Clock
Time
(24hr)
                              Gas.
                              Meter
                             Reading
                            ((Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
. Ts
  Orifice Pressure
i-   Differential
: (delta H. in. H20)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
 Temp.
 .'(T)
  Dry Gas Meter

 (Inlet";   Outlet
(Tminj  7  (Tmout)
Impinger
  Exit
 Temp.'
 Pump
Vacuum
 (ln.Hg)
          "VS
                                         l OS"
                                                 1.30
                                                                                                                                      fi
                                                                                                                               Ht
          T2...C
                      /• 2-
                              ITS'
                          1&
                           •xl
                                                                                      ISM
                                                                                     M1-
^
          30
         rt '
                                        3.1
                                                                                                                     0,1
                                                                                                                              7- 1
          52.
                                                                               7.S7-
                                                                                                           fL
                                                                              T.HS-
                      : oo
                                                                                                                    ST-
                                            Vo
                                         107.
                                                                                                 61.
                                                   Ill
                                                  2..03
          Vl.5-
                                         1 0(o
                                                          TH3
                                                                                                                                      fT
          qo
        /3.30
                              II.C
                                                                                                                                      S"
                   13: 3
                                 Mt
                              lo°
                                                                                                                                      S.o
                                                                      1. ft
                                                                     •5,
                                               M
                                                                                                          5?
                                                                                                                                     r-o
          IIT.5
                                                                                                                     C&
                                                                                                                   CO
                                          .MM
                                                 4Jib-
                                                                                                                      62
                                                                                                                              r.o
                                                             l.fcl
                       27, S
                                                                                                            feT.
   |0
ISO
 ^?^
 TW^
 TTlr
                                        I.STl
                                                                     . STl
                                                                                   m
   u
   it
                     34
                                                                                                                      63
          ITL.-S"
                S
                               joH.
                                                                       I. V*
                                                                                                i?y_
                                                                                                                              M. a
Comments:

-------

Comments:

-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
         3
m26
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction  Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
 Concentration (g/dscm)
 Concentration (kg/hr)
 Concentration (ppmv)
 Emissions (Ib/hr)	
                                                          331.5
                                                          29.20
                                                          29.17
                                                          -0.30
                                                         108.18
                                                        1809.56
                                                        261.702
                                                           1.84
                                                          77.58
                                                          88.60
                                                            0.0
                                                           21.0
                                                           79.0
                                                         0.9880
                                                          0.256
                                                           0.84
                                                          0.751
                                                        248.892
                                                          7.049
                                                           1.65
                                                          0.983
                                                          28.84
                                                          28.66
                                                        2280.82
                                                         695.19
                                                      28661.64
                                                         811.70
                                                      25541.80
                                                         723.34
                                                         103.34
                                                      -16380.66
                                                           0.00
                                                           0.00
                                                           0.00
                                                           0.00

-------
        Eastern Research Group. Inc.
                                           MODIFIED METHOD 5 DATA SHEET
                                                                                                            Run
                                                                                                            Page 1 of
Plant .',.- .J^T C+J\.
Date Q^i^fe*
Operator T
Sampling Location F 0 (LtU .
Sample Type
Run Number
Static Pressure (±J (in. H2O)
Barometric Pressure (in. H2O)
£> fiu At-
(iiiQ/q^
Aviiif 35.
'SvTcJr
V«v\Ucx-
i
-n.^'-xUo
23,2.1
XAD Trap Number
Filter Heater Setting (T)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
•' — . •
zso
&'*Ntef
7£0
(e~b
•oUUib"
,oo$&0"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-33-
\&\3
fl.
-------
                   Plant
                   Date
                                    Location
                                    Sample Type
                                                                   OUT
                                 HcJL VWruCOlKiaOperator
                                                           Run Number
                                                            1
                                                                             M.A.A.H
 Traverse
  Point
 Number
     Sampling
      Time
      (min)
Clock
Time
(24hr)
    Gas
   Meter
  Reading
  ((Vm).ft3)
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
 (•F)
  Orifice Pressure
    Differential
 (delta H, in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
 Temp.
                                                                                                               Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
            IVO, -
                        ^013 .20?
  fi-l-L
               -H£L
                                                         1 V3-
                                                            XHo
                    M :
                                                                                                                                  %
      11
      10
                    16";
                                            -
                                         %
                                                                  3k, IS
     J0_
              15". 15
IS
                      ^
                    15
                                                                                                                          5- t
                    l£  3D
                        / o f-,
                              / 6
                                                           .I
                                                       \9r
                                     , I
                    L(o \
                        to
      In
                                                                                     1U2
41
                                                                                          0.50
                    {I, '.30
                                                 ft.
                             ±a
                                                                      1 SD
                                                                                                  5fT
                                                                                                                                5*5-
             •S 15"
                                         ^
                                                           -51
                    ft,; 55"
                                  1,  \
                                                                   1.5-1
                                                               l.HV
             <5toO
                                                                            0 • O 0 :
                                                                         /o
Comments:

-------
Facility:           Gulp Alum. Alloy
Date:            12/09/97
Location:         Furnace out
Run Number:              4
Sample Type:     rn26	
Total Sampling Time (min)                                                   381.5
Corrected Barometric Pressure (in Hg)                                        29.32
Absolute Stack Pressure (in Hg)                                              29.29
Stack Static Pressure (in H20)                                                -0.30
Average Stack Temperature (°F)                                             93.69
Stack Area (sq in)                                                        1809.56
Actual Meter Volume (cu ft)                                                268.961
Average Meter Pressure (in H2O)                                              1.56
Average Meter Temperature (°F)                                             63.24
Moisture Collected (g)                                                       76.60
Carbon Dioxide Concentration (%V)                                             0.0
Oxygen Concentration (%V)                                                   21.0
Nitrogen Concentration (%V)                                                  79.0
Dry Gas Meter Factor                                                      0.9880
Nozzle Diameter (in)                                                        0.256
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.691
Standard Metered Volume (dscf)                                           263.800
Standard Metered Volume (dscm)                                             7.471
Stack Moisture (%V)                                                         1.35
Mole Fraction  Dry Stack Gas                                                 0.986
Dry Molecular Weight                                                       28.84
Wet Molecular Weight                                                       28.69
Stack Gas Velocity (fpm)                                                  2055.67
Stack Gas Velocity (mpm)                                                   626.57
Volumetric Flow Rate (acfm)                                              25832.33
Volumetric Flow Rate (acmm)                                               731.57
Volumetric Flow Rate (dscfm)                                             23792.76
Volumetric Flow Rate (dscmm)                                              673.81
Percent Isokinetic                                                         102.17
Percent Excess Air                                                      -16380.66
Concentration (g/dscm)                                                      0.00
Concentration (kg/hr)                                                        0.00
Concentration (ppmv)                                                        0.00
Emissions (Ib/hr)	                                0.00

-------
         Eastern Retcanch Group. Inc.
                                              MODIFIED METHOD 5 DATA SHEET
                                                                                                                      Run
                                                                                                                      Page 1 of
Plant £0u?>
Date
Operator
Sampling Location f o? (vAc<
Samgle Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O) ^3
AL \AL-
l^hita*
VW*A| /Ti
rti/TC^T"
Met-
4
-0-?t>
"xq . ^
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
*r
ICQ
b'tyfc*
zj-6
(pO
'OutllV'
xOtf€V'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-3*
( SI3
.Mi
O.^l>
Hf
/•?»
HMZ

Diagram of Duct
                                                        Schematic of Traverse Point Layout
                                                         Read and record all data every 1 • ~> minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
  Gas
  Meter
 Reading
((Vm).tt3
 Velocity
  Head
((delta Ps),
 in.H2O)
Stack
 Ts
 CF)
  Orifice Pressure
    Differential
 (delta H, in.H2O)
Desired    Actual
Probe
Temp.
 CF)
 Filter
Temp.
 (T)
Adsorbent
  Trap
  Temp.
  CF)
                                                                                                                 Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  (•F)
 Pump
Vacuum
 (in.Hg)
                                           .33
                                                                      -Z-50
                                                                     ST
                             144 •/
                                                                                                                       HO
               . JT
                                 ,-40
                                UT,
                                                               •
     11
  30
                       ,i-\t
    1(3
    ta
                                                                       .1*3 C>
                                                                                                                      Q.7D
            SVsT
                                                                                                                       ^ 1
                                                                                                               •-1
            tfl.lf
                            110 .U
            111 .
     
-------
Comments:

-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/08/97
Furnace out
         1
M23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
 Concentration (g/dscm)
 Concentration (kg/hr)
 Concentration (ppmv)
 Emissions (Ib/hr)	
                                                          321.5
                                                          29.32
                                                          29.29
                                                          -0.30
                                                          88.14
                                                        1809.56
                                                        257.992
                                                           0.70
                                                          60.03
                                                          48.50
                                                            0.0
                                                           21.0
                                                           79.0
                                                         0.9880
                                                          0.256
                                                           0.84
                                                          0.793
                                                        254.874
                                                          7.218
                                                           0.89
                                                          0.991'
                                                          28.84
                                                          28.74
                                                        2424.85
                                                         739.10
                                                      30471.60
                                                         862.96
                                                      28482.29
                                                         806.62
                                                          97.85
                                                      -16380.66
                                                           0.00
                                                           0.00
                                                           0.00
                                                           0.00

-------
                                             MODIFIED METHOD 5 DATASHEET*   -
                                                                             Meter Box Number.
                                                                             Meter delt
                                                                             PGM Factor (Y)
                                        Minimum Sample Volume (ft3)
                                                                                                       Run •"
                                                                                                       Page"'! of
                                                        Amfciem Temperature (*F),  "'' '-^
                                                                             Assumed Moisture. (%.H2(3)
                                                             •  .            •        •'!•'»••         a?-''^y*   A       '   •      	'
                                                           fiatjc of Ttgverse PolntiJaydut* .'    i^,'tt *  ^   '"  • •''. '.•.  . .' *.
                                                           ntf record all datVeVerv  •'  nilnutes '      i ''.;'.'•*'".••' :  \        *'     .:
                                                                                      •;V9^  _  -  .        • •*•  - .. '
                                                                                     «/.)-y I     • .  *•    :-  •  .  •
                                                                                       •*    ' t ^^^     JUBnaarn *f Plimt
                                                                                                                        	Diagram •( Duct \
                                                           .i.*?, .
                                                                              2.5 «•!
                                                                    Rlter,,,M
                                                                       $c
                                                                                        •233-
                                                                                                .Adsorbent
                                                                                                a-.: Trap
                                                                  Dry Gas Meter.  H
                                                                 •             ' •
                                                                 Inlet  ' ^ Outlef
                                                                        *(Tm o'utf •
                                                                                                             ' ••*.
                                                                          knpinger.
                                                                           .Exit-'
                                                                           Temp. ..
  pump
 \tecu'urtt
.  (in-Hg)'
                                                                                                                                      >',o   "
                                                                                                                                     :>
                                                                                                          fa 5'
                                •±
        3Qu>.'L   .
        ^Vf,>l
                                                            Loo
          .10
,H*
                                                7TOD
                      ,4^.
 ^
^i-
                                                            "200
                    \\.
                               1
-------
                  Plant
                  Date
                 oo i
                     Location
                              Sample Type
                                             Run Number
                                                        Operator
                                                         ;T
                                                                                                                       Pagefpbf	
 Traversa
  Point
 : Number
Sampling
  Tjme
  (min)
  Clock
  Time
  (24hr)
  Gas
 Meter
Reading
((Vm).tt3)
 Velocity
  Head
((delta Ps),
 in.H20)
Stack
 Ts
 Orifice Pressure
   Differential
 (delta H, in.H2O)
Desired   Actual
Probe
Temp.
 Fitter
Temp.
Adsorbent
  Trap
 Temp.
  CF)
                                                                                                        Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp!
 Pump
Vacuum
 (in.Hg)
                   i I- 12.5
      i
                                                         \.c-j
                                                                 4J-
                                                                                                1
                                                                                                                                   O
                                                                                                               ST.
                                                                                                              S3
                                                                                                              .5"
          110
JL
                   £00 r
                                                                            "IX b
                                                                            2S3
                                                                                              S/
                            cn •  «
                                                "2. TO
                                                                 T.SL
                                                                43
                                                                   -7 7.0
                                                                                             nl
                                                                                                     yv
                                                                                                      -70
                                                                                                              vr
                                                                                     ZM3.
                                                                                    sr
                                                                                            S3
                                                                                     •2.S3
                                                                                                     £3
                                                                                        -it
                                                                           1ST-
                                                                                     2X2-
                                                                                                                       SO
                                                                    i vr
                                                                                                              Si
                                                                                              50
                  is. zo
                                       1Q

                                      "5
                                                                                            -73
                                                                                                     S3
                                         . 5*0
                                                                                                                       .S'
    ID
    ll
                                                                     OO (
Comments:

-------
Etatetn .Pweorcn G'Ouo. .'nc.
               MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number : :
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
i ; . lp M 1; i wv.f^ivrrx H U f~>\J
rij&fii
£•£'!- 'OUTLET
ru*ko^. -Q3
^ 1

m«^ ^...vlc. / /V*-^A ^..i-V
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
         2
m23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter.Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon  Dioxide Concentration (%V)
Oxygen  Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction  Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent  Isokinetic
Percent  Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)	
                                                          341.5
                                                          29.29
                                                          29.26
                                                          -0.30
                                                          99.80
                                                        1809.56
                                                        243.113
                                                           0.65
                                                          70.61
                                                          72.20
                                                            0.0
                                                           21.0
                                                           79.0
                                                         0.9810
                                                          0.256
                                                           0.84
                                                          0.727
                                                        248.281
                                                          7.031
                                                           1.35
                                                          0.986
                                                          28.84
                                                          28.69
                                                        2272.85
                                                         692.76
                                                      28561.48
                                                         808.86
                                                      25991.57
                                                         736.08
                                                          98.34
                                                     -16380.66
                                                           0.00
                                                           0.00
                                                           0.00
                                                           0.00

-------
         Eaitem Rnearch Group. Inc.
                                             MODIFIED METHOD 5 DATA SHEET
                                                                                                                  Run
                                                                                                                  Page 1 of
Plant £.l/j-.^
Date'
Operator
Sampling Location "Fuft-AJ • fSH
Sample Type
Run Number
Static Pressure (*) (in. H2O)
Barometric Pressure (in. H2O)
Ac - r\<-
li/*»H>
rv\u) H fS^
Ov/TkAlT
35«o>,lfJ
2.
-0.3">/tO
a<\,3o
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
—
2£0
(o'Wfr*
2SO
fco
,Ot£/2"
.c£>&0 Hv
Meter Box Number
Meter delta H @
DGM FactorJY)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
/1-3K
I-&I&
o.q&i
,a£G
ft>°
/,6 ?o
*H3

Diagram of Duct
                                                      Schematic of Traverse Point Layout
                                                       Read and record all data tvery I' 5>  minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
                  ll-oVS'
   Gas
  Meter
 Reading
'((Vm).n3)
 Velocity
  Head
((delta Ps).
 in.H2O)
Stack
 Ts
 Orifice Pressure
    Differential
 (delta H, in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
 CF)
                                                                                        lit,
Adsorbent
  Trap
  Temp.
  .(•F)
                                                                                                             Dry Gas Meter
 Inlet
(Tm In)
                                                                                                 To
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
           K
                                                                                                                             6-0  T
                                                    I7-O
                                                                                                            VL
           30
                        C
                       32,
                                                                                        4,0
                             C.4V.I
                                 .40
                                                                               Ho
                                                                                         to
                                                                                                . o
                                           .3C,
                                           ItS.
                                                    (OH
                                           , 2C,
                                                                                                  •7S-
                    a-,
                                          loo
                       37 C
                                           101.
                                                          0-3S
                                                                                                  ess
                                                                                               t-o
                                                                                                             So
                                                                                                                              60
            So
                                                                                                   fro
                                                    10
                                                   1. <\0
                                                   I qo
                                                                                                            .o
                                                                                         •2-Mi
                                                                                                                      56
                                                                                                                      •0
                    H'.oo
                       - V
                       . MS
                                I
                                                                                                                                           0
            110
                                                            z.
                                                             -4 "i
                                                                                         fal
                                                                                               C.O
                                                                                                                       (,1
                                           .MC
                                                                                                                              i.O
     10
                                                    .q o
                                                                                         80
     \o
  (So
                                                     riv
      U
                                           (IT-
                       00
                                                                                                                     •&
     It.
Comments:

-------
                   Plant
                   Date
                                Location
                                Sample Type
                                                                 oirr
                                                Run Number
                                                                          Operator
 Traverse
   Point
 Number
Sampling
  Time
  (min)
                Clock
                Time
                (24hr)
  Gas
 Meter
Reading
((Vm).tt3)
 Velocity
  Head
((delta Pa),
 in.H20)
St
tack'
Ts*
CF)
  Orifice Pressure
    Differential
 (delta H. in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
 Temp.
                                                                                                               Dry Gas Meter
                                                         Inlet
                                                       (Tm in)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
   6-1
 \
                IS
                                                 1.7. 9
                                              _U_
                                                                             u
                              TM-S
                                                                       •2.2-1
                                                                                     2.0, S
                                                      » o
                                                    \ s
                     u:
                              £L
                                                                                iJlb (
                                                                                                                                         u-o
                                   - 2,
                                  .40
                                                                                      •2-S7-
                                                                                                          C.-0
           921-C
                                                              ( 5s t,
           iMO
                                   HZ-
           1-S.S
                     Vt U .
                                       .HI
                                   .- 1
                                                      .£(
                                                                                      2-X C
                                                                        &
±
                                               Ml
                        ll
                                             •
                                              2S1
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                                                      .vc
                                                                i.QS
       fr
                          -I
                                         Mi
                                                                                                  SO
                                                                                                                                             0
                                                               2.0
                                                                                 ^3o
                                                                                                2
                                                                                                                                     s
                                                                                                              £
                                                                                                                  O
     /o
330
                                                                                                                 8-1
                                                                                                                               ./•O
      If
                                                                                             Sb
                                                                                                                                      ,0
     llr
          -5tm
Comments:

-------
Ecjfem Qevoorcn Group. Inc.
             MOISTURE RECOVERY FORM,FOR METHOD 4
Plant
Date
Sampling Location
Sample Type •^/'-•- -^-:.
Run Number ;
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
r :..Vp . ftV.^.r^rw RlUu
MLya/9*
£^L ' 0in L?7
r)^oA. ,03
**a

n0^ ^.H& / (Vv^A ^,.r-K^
(\^v>/ A-ut£;
1 • ••-

i
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
tf\?Tf
. tfilC
V^v.0
I4PLC
Wjp
EMP ry
$ 1 1 >ca Ge.1


Amount of
Solution
(9)
/
i CC rr»\$
1 ^OMs
--
•ZOC-3tO^.
t

Impinger Tip
Configuration
Kr\ccKcui,
CsKsrt njT)
Meclifiecl
A\J^ieA.
r^oii^ecL
McdL^i'ecL


ImpingerWefght
Final
(9)
5-30,^
5*55
s^:\e
454.5"
SS^tP


Initial
(g)
5MD
5(LZ.*}
S5S4
45^?
?(/T.O


Total Weight Gain (g)
Weight
Gain
(g)
IDul
— .-;• 't
f
f ' '"' - fo2y
- 5
_ § J
^
• -*.—

7^-^>

-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
         3
m23      	
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
 Concentration (g/dscm)
 Concentration (kg/hr)
 Concentration (ppmv)
 Emissions (Ib/hr)	
                                                         331.5
                                                         29.20
                                                         29.17
                                                          -0.30
                                                        107.27
                                                       1809.56
                                                       258.286
                                                           1.95
                                                         74.50
                                                         53.50
                                                            0.0
                                                           21.0
                                                           79.0
                                                        0.9810
                                                         0.256
                                                           0.84
                                                         0.740
                                                       245.451
                                                         6.951
                                                           1.02
                                                         0.990
                                                         28.84
                                                         28.73
                                                       2340.11
                                                        713.27
                                                      29406.74
                                                        832.80
                                                      26416.98
                                                        748.13
                                                         98.54
                                                     -16380.66
                                                           0.00
                                                           0.00
                                                           0.00
                                                           0.00

-------
         Eastern Research Croup. Inc.
                                             MODIFIED METHOD 5 DATASHEET
                                                                                                                   Run
                                                                                                                   Page 1 of
Plant C-OuP
Date
Operator
Sampling Location £\MLtJp>Ct,
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Al_ A<~-
/2Jlb/&S>S"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-38
AiL
0.1AI
0,7.Sjb
.SO*
l*o
^,43

Diagram of Duel
                                                       Schematic of Traverse Point Layout
                                                        Read and record all data every	minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
             O
          Clock
          Time
          (24hr)
         II.'IS
  Gas
 Meter
Reading
«Vm).ft3)
                                      Velocity
                                       Head
                                     ((delta Ps),
                                      in.H2O)
Stack
 Ts
 (•F)
 Orifice Pressure
    Differential
 (delta H. in.H2O)
Desired    Actual
Probe
Temp.
 (•F)
 Filter
Temp.
 (•F)
Adsorbent
  Trap
 Temp.
                                                                                                              Dry Gas Meter
Inlet      Outlet
           (Tm In)
        (Tm out)
Impinger
  Exit
 Temp.
  (•F)
 Pump
Vacuum
 (in.Hg)
  G- 1
                                                             LS
                                                                                                 _1±
JL
 I
           IS
         (C.30
                                                                     2.57,
                                                                                2^(0
           30
                                             31
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                      . '
                                                                      2-4 b
                                                              • sq
                                                     no
                                                      V2.
                                                                                                   i
                       255
                                                                                                                              2,5
4%
 
-------
                   Plant
                   Date
                               Location
                               Sample Type
                                              fiJ
                                                         Run Number
                                                Operator
                                                                    3
                                                               WUJI//TS
                                                                                                                                   •••••-••:*•«-.
 Traverse
  Point
 Number
Sampling
  Time
  (min)
Clock
Time
(24hr)
  Gas
  Meter
/Reading
((Vm,ft3)
         Velocity
          Head
        ((delta Ps),
         in.H2O)
                                         Stack
                                          Ts
                                          (•F)
 Orifice Pressure
   Differential
 (delta H, in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
 (•F)
Adsorbent
  Trap
 Temp.
                                                                                                             Dry Gas Meter
 Inlet
(Tm in)
 Outlet
(Tm out)
Impinger
  E»t|
 Temp.
   mp
Vacuum
 (in.Hg)
                                                     IOVD
%JCL.<
                                                              i.qn
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                                                                                                                 it
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Comments:

-------
        . 'r.c.
           MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
/':. lp . ft\,._rv^ R1UV

tf ^p** /^ U "^~ ^"-£»**T^
n^ ^^ y$
4^5

(q0^ P^;.l4^ / r >y^,\ (i,,,r-K^




Impinger
Number
Impinger
Solution
Amount of
 Solution
   (9)
Impinger Tip
Configuration
                                               •Impinger Wefght
Final
 fg)
Initial
 (3)
Weight
 Gain
  (a)
                                  rt Hp)
           HvtC
                     I CC
                    •ZCG -3(1
                                 Total Weight Gain (g)

-------
Facility:          Gulp Alum. Alloy
Date:            12/09/97
Location:         Furnace out
Run Number:             4
Sample Type:     m23   	
Total Sampling Time (min)                                                   381.0
Corrected Barometric Pressure (in Hg)                                        29.32
Absolute Stack Pressure (in Hg)                                              29.29
Stack Static Pressure (in H2O)                                               -0.30
Average Stack Temperature (°F)                                              93.47
Stack Area (sq in)                                                        1809.56
Actual Meter Volume (cu ft)                                                274.335
Average Meter Pressure (in H2O)                                              1.79
Average Meter Temperature (°F)                                              61.97
Moisture Collected (g)                                                       43.40
Carbon Dioxide Concentration (%V)                                             0.0
Oxygen  Concentration (%V)                                                   21.0
Nitrogen Concentration (%V)                                                  79.0
Dry Gas Meter Factor                                                      0.9810
Nozzle Diameter (in)                                                        0.256
Pitot Constant                                                               0.84
Average Sampling Rate (dscfm)                                              0.703
Standard Metered Volume (dscf)                                            267.746
Standard Metered Volume (dscm)                                             7.583
Stack Moisture (%V)             ,                                            0.76
Mole Fraction Dry Stack Gas                                                 0.992
Dry Molecular Weight                                                       28.84
Wet Molecular Weight                                                       28.76
Stack Gas Velocity (fpm)                                                  2188.59
Stack Gas Velocity (mpm)                                                   667.08
Volumetric Flow Rate (acfm)                                              27502.66
Volumetric Flow Rate (acmm)                                               778.88
Volumetric Flow Rate (dscfm)                                             25493.20
Volumetric Flow Rate (dscmm)                                              721.97
Percent  Isokinetic                                                          96.91
Percent  Excess Air                                                      -16380.66
Concentration (g/dscm)                                                      0.00
Concentration (kg/hr)                                                        0.00
Concentration (ppmv)                                                        0.00
Emissions (Ib/hr)	  	       0.00

-------
         Eastern Research Group. Inc.
                                              MODIFIED METHOD 5 DATA SHEET
                                                                                                                     Run
                                                                                                                     Page 1 of
Plant . COU
Date
Operator
Sampling Location f 0 ci(J
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Wu )*«_
n-|i%l«i>
WsjOi^ ( SS
OlfiU-f~
"*> v o-* ) fJ
cl
- O-^L)
•i-q.si
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
__
2,50
k'HiU.-*-
•LSO
fcT)
'0\Ato"
• oo$£t o'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature ("F)
Assumed Moisture (% H2O)
K-Factor
fl-3&
KfcfG
,&
^0

H.H3

Diagram of Duct
                                                       Schematic of Traverse Point Layout
                                                         Read and record all data every	minutes
 Traverse
   Point
 Number
Sampling
  Time
  (min)
           Clock
           Time
           (24hr)
  Gas
  Meter
Reading
((Vm),ft3)
         Velocity
          Head
        ((delta Ps).
         in.H2O)
Stack
 Ts
 CF)
  Orifice Pressure
    Differential
 (delta H. in.H2O)
Desired    Actual
Probe
Temp.
 Filter
Temp.
Adsorbent
  Trap
  Temp,
  (T)
                                                                                                                Dry Gas Meter
 Inlet
(Tm In)
 Outlet
(Tm out)
Impinger
  Exit
 Temp.
  (CF)
 Pump
Vacuum
 (in.Hg)
                                                                                                                                           2.
                                           .  "2,0
                                                                                                              S 1
                                           -  20
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Comments:

-------
Plant
Date
CUV-F ft/A
IM1I ««-
Location 'FOJLK
Sample Type
OVTUJT
4*1 t> >C iW
Run Number
Operator
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                                                                                                                        Paae^Bf *~
 Traverse
  Point
 Number
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 Velocity
  Head
((delta Ps),
 in.H2O)
           Stack
            Ts
Orifice Pressure
  Differential-  ''*
(delta H, in.H2O).••'
                   Desired
Actual
Probe
Temp.
 (•F)
 Filter
Temp.
 CF)
                         Adsorbent
                           Trap
                          Temp.
                                                                                                          Dry Gas Meter
 Inlet
(Tm in)
 Oudet
(Tm out)
Impinger
  Exit
 Temp.
 Pump
Vacuum
 (in.Hg)
          _LiO_
  A-l
                                                           1-02-
                                                                    1.
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Comments:

-------
           MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f •. . 1 A - M 1 ,1 Mv.rvirrs R \(f^\j
/^|/n/9^
Ak> / (^/>v^,\ (i,ur-ki-.




Impinger
Number
Impinger
Solution
Amount of
 Solution
   (9)
Impinger Tip
Configuration
                                               Imjainger Weight
Final
"(9)
Initial
 (g)
Weight
 Gain
  (g)
                     1 CO
                                 Total Weight Gain (g)
                                                 43.

-------
                              Appendix B

                              Dioxin/Furan
                        Laboratory Analysis Data
cah/A:\APPX-CVR.WP6

-------
                             CASE NARRATIVE
                      Analysis of Samples for the Presence of

             Polychlorinated Dibenzo-p-Dioxins and Dibenzoforans by

      High-Resolution Chromatography / High-Resolution Mass Spectrometry
                                Method 23 (6/93)
             Date:
             Client ED:
             P.O. Number:
             TLI Project Number:
January 12, 1998


Eastern Research Group




44376A
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 11/19/97
                                             Triangle Laboratories, Inc.
                                  801 Cap/to/a Drive              P.O. Box 13485
                                  Durham, NC 27713-4411         Research Triangle Park, NC 27709-3485
                                  919-544-5729                  Fax #919-544-5491             -j

-------
Triangle Laboratories, Inc.                                               January 12, 1998
Case Narrative                                                               44376A
Overview

The samples and associated QC samples were extracted and analyzed according to
procedures described in Method 23 (6/93). Any particular difficulties encountered during
the sample handling by Triangle Laboratories will be discussed in the QC Remarks section
below. This report contains results only from the Method 23 dioxin/furan analyses of ten
M23 samples.
                 i                      •               .     •
Quality Control Samples

A laboratory method blank,  identified as the TLI Blank, was prepared along with the
samples. A TLI Cleanup Blank was also processed along with the  samples to prove that
contamination was not introduced during the cleanup procedures.

Quality Control Remarks

This release of this particular set of Eastern Research Group analytical data by Triangle
Laboratories was authorized by the Quality Control Chemist who has reviewed each
sample data package following a series of inspections/reviews. When applicable, general
deviations from acceptable QC requirements are identified below and comments are made
on the effect of these deviations upon the validity and reliability of the results. Specific QC
issues associated with this particular project are:

Sample receipt:  Twenty-five M23 samples were received from Eastern Research Group
in good condition on December 17, 1997 at ambient temperature and stored in a
refrigerator at 4 °C. Samples CAA-206 and CAA-207 were not included in the shipment.
                                        \     •    _.
Sample Preparation Laboratory: None     y j,\<  *" ~

Mass Spectrometry: None

Data Review: Due to the limitations of the software, the "CAA" portion of the sample
identification numbers was not listed on the reports.

The ion abundance ratios for the  1234678-HpCDF internal standards and 1234789-
HpCDF surrogate standards in samples 177/182-184/209 and 193-196 were outside QC
limits, most likely due to matrix-related interferents in these samples. The percent
recovery of the 1234678-HpCDF internal standard is significantly lower than the
recoveries of the other internal standards. However, the percent recoveries for all internal
standards are sufficient to quantitate the associated analyte concentrations in the samples.

-------
Triangle Laboratories, Inc.                                                January 12, 1998
Case Narrative                                                                44376A
Other Comments: No 2,3,7,8-substituted target analytes were detected in the TLI Blank
or TLI Cleanup Blank above the target detection limit (TDL).

The analytical data presented in this report are consistent with the guidelines of EPA
Method 23 (6/93).  Any exceptions have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Eastern Research
Group have any questions or comments regarding this data package, please feel free to
contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Released By,
Kenneth Varley
Report Preparation Chemist
     The total number of pages in the data package is:   \[j  '   .

-------
                     TRIANGLE LABORATORIES, INC.

                LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American Association for Laboratory  Accreditation.  Accreditation pending.   Certificate
Number 0226-01.  Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz  Waste,  Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of Environmental Management. Expires December 31, 1998.
Laboratory I.D. #40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation.  Expires December 21, 1998.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department of Health Services.  Expires May 26, 1998. Certificate #AZ0423.
Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology.  Expires February 18, 1998.
Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX, Volatiles, Semi-
v'olatiles, and Metals.

State of California,  Department of Health Services.  Expires August 31,  1999.  Certificate
#1922.  Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.                .

State of Connecticut, Department  of  Health  Services.   Expires September  30,  1999.
Registration # PH-0117. Dioxin in drinking water.

Delaware Health and Social Services.  Expires December 31, 1998. Certificate #NC 140. Dioxin
in drinking water.

Florida  Department of Health and Rehabilitative  Services.  Expires June 30, 1998. Dioxin in
DW. Drinking Water ID HRS# 87424.  Metals, Extractable Organics  (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS# E87411.
Revised 1/6/98 RM                                  Triangle Laboratories, Inc.
y:certific\certlist.mem               soi Capitoia Drive            P.O. BOX 13435
                                   Durham, NC 27713-4411        Research Triangle Park, NC 27709-3485
                                   919-544-5729                Fax #919-544-5491                 A

-------
Hawaii Department of Health.  Expires March  1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .

Idaho Department of Health  and Welfare.   Expires December 31, 1998. Dioxin in  drinking
water.

State of Kansas,  Department of Health and  Environment  Expires January  31, 1998.
Environmental Analyses/Non portable Water and Solid and Hazardous Waste.  Method 1613 for
drinking water. ID #s - Drinking water and/or pollution control - E-215. Solid or Hazardous Waste -
E-1209.

Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31, 1998. ID#90060. Dioxin in drinking water.

Maryland Department  of Health and  Mental  Hygiene.   Expires September 30,  1998.
Certification #235.  Drinking water by Method 1613A.

State of  Michigan,  Department of Public Health.  Expires June  3, 19S8. Drinking water by
Method 1613.

Mississippi State Department of Health.  No expiration date.  Dioxin in drinking water.

Montana Department of Health  and Environmental  Services.  Expires December 31, 1998.
Dioxin in drinking water.

State of New Jersey, Department of Environmental Protection and Energy.  Expires June 30,
1998. ID #67851. BNAs and Vclatiles. Dioxin in  drinking water.

State of New Mexico, Environment Department.  Recertification pending. Dioxin in  drinking
water.

New York State  Department of Health.  Expires April 1,  1998. ID  #11026.  Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.

State of North Carolina,  Department of Environment Health and Natural Resources  Expires
August 31, 1999.  Certificate # 37751. Dioxin in drinking water.

State of  North  Carolina, Department  of  Environment, Health,  and Natural  Resources,
Division of Environmental Management.  Expires  December  31, 2000. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.

North  Dakota  State Department of Health  and  Consolidated Laboratories.   Expires
December 31, 1998. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 1/6/98 RM
y:certific\certlist.mem

-------
Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory #9612.
Dioxin by 1613A, 8290 and 8280.

State of South Carolina, Department of Health and Environmental Control. Expires
April 1, 1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters).  Dioxin/Furans,  SNA, Volatiles, and  PCBs/pesticides
under Clean Water Act,  2,3,7,8-TCDD for Drinking Water,  and Organic extractables for Solid and
Hazardous Waste.

State of Tennessee. Department of Environment and Conservation.  Expires
February 5, 1999. ID #02992.   Method 1613 Drinking water only.
                                                           •
                                                         •
U.S. Department of Agriculture Soil  Permit  Expires September 30, 2001. Permit No.  S-3790.
Under the authority of the Federal Plant Pest Act, permission is  granted to receive foreign soil
samples for use in laboratory analysis.

U.S. Army Corps of Engineers.  Recertification Pending.  Validated to perform methods
8280 & 82SO for Lockbourne Landfill Site Investigation, Defense Distribution  Depot Projects, and
assorted projects for the USAGE North Pacific Division Laboratory.

U.S. EPA  Region V. Expires November 14, 199S. Dioxin in drinking water.

U.S. EPA Region  VIII, for the  State of  Wyoming.  Expires November  12, 1998. Dioxin  in
drinking water.

State of Utah, Department of Health. Expires December 31, 1998. Certificate Number E-166.
Certification  for the following  parameters:  Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method 1613;
Metals including Mercury and Microwave Digestion.

Commonwealth of Virginia,  Department of General Services,  Division of  Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.

State of Washington, Department of Ecology.  Expires September 11, 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for  Polychlorinated Dibenzo-p-
dioxins and  Polychlorinated Dibenzofurans, BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.

State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking  water.
Labl.D, 129

State of  West Virginia, Department of Health.   Expires December 31, 1998. Certificate No.
9923(C). Dioxin in drinking water.
Revised 1/6/98 RM
y:certific\certlist.mem

-------
State of Wisconsin, Department of Natural Resources.  Expires August 31, 1998.  Laboratory
ID Number  999869530. Certification for  the  following  categories  of Organics:  Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin. Expires  November 14, 1999. Laboratory ID 999869530.
Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement Agency  (DEA).   Expires  November 30, 1998. Registration  number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources. Expires October 31, 1998.  Registration number
NC-PT 0000 0031. North Carolina controlled substances  registration. Application  submitted for
renewal.

Food & Drug Administration (FDA) Registration.  Expires June 1998.  ID #'s 001500 1053481.
Annual registration of drug establishment. Annual registration of drug establishment.

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration.  Expires May 30, 1999.
ID # 34D0705123.   Department  of  Health  &  Human Services.  Health  Care  Financing
Administration.

U.S. EPA Large  Quantity Hazardous Waste Generator.    No  expiration date.   EPA ID
#NCD982156879.  Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina General License for Radiation Protection.  No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 1/6/98 RM
y:certific\certlist.mem

-------
DOCUMENT
 CONTROL
         Triangle Laboratories, Inc.
    801 Cap/to/a Drive      P.O. Box 13485
    Durham, NC 27713-4411    Research Triangle Park, NC 27709-348i>~
    919-544-5729        Fax # 919-544-5491
                              8

-------
Gulp Aluminum Alloys
                                                            Eastern Research Group   COC
CHAIN OF CUSTODY ' / /I
RELINQUISHED BY " ^/rlrtur LsLuJ^
RELINQUISHED BY «=
SAMPLE
CAA-1 05
CAA-1 06
CAA-1 07
CAA-1 08
CAA-1 09
CAA-1 10
CAA-1 1 1
CAA-1 12
CAA-1 13
CAA-1 14
CAA-1 15
CAA-1 16
CAA-1 17
CAA-1 18
CAA-1 19
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CAA-1 21
CAA-1 22
CAA-1 23
CAA-1 24
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CAA-125
CAA-1 26
CAA-1 27
CAA-1 28
CAA-1 29
CAA-1 30
CAA-1 31
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-------
Eastern Research Group   COC
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CAA-132
CAA-133
CAA-134
CAA-135
CAA-136
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CAA-139
CAA-140
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CAA-142
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CAA-
CAA-
CAA-
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CAA-
CAA-
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CAA-
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CAA-
CAA-
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CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
120997 M23-
120997 M23-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
121197 M23-
121197 M23-
120797 M23-
121597 M23-
121597 M23-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
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METHOD 23. RF1-OUT, RUN 1
METHOD 23. RF1-OUT. RUN 2
METHOD 23. RF1-OUT. RUN 2
METHOD 23, RF1-OUT, RUN 2
METHOD 23. RF1-OUT, RUN 2
METHOD 23, RF1-CO T. RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF2-OUT. RUN 4
METHOD 23. RF2-OUT. RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN, RUN 1
METHOD 23. RF1-IN. RUN 2
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METHOD 23, RF1-IN. RUN 2 t^"
METHOD 23. RF1-IN. RUN 2 \
METHOD 23, RF1-IN, RUNS
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METHOD 23. RF2-IN. RUN 4
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METHOD 23. REAGENT BLANK
METHOD 23, REAGENT BLANK
METHOD 23. REAGENT BLANK
                       XAD TRAP
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                       TOLUENE RINSE
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DIOXIN / FURAN
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DIOXIN / FURAN
DIOXIN/FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN/FURAN
DIOXIN / FURAN
DIOXIN / FURAN
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DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
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DIOXIN / FURAN
DIOXIN / FURAN
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DIOXIN / FURAN
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             Page 2

-------
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METHOD 23, REAGENT BLANK
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DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
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-------
                                                                   Eastern Research Group  COG


CAA-218    CAA-      120597 M23-     CDBIN      PR      1       M23 CDBIN RUN 1  (PR 2 OF 2)       ACETONE/MECL RINSE                          DIOXIN / FURAN
CAA-219    CAA-      120697 M23-     CDBIN      FILTER  2       M23 CDBIN RUN 2  (FILTER 2 OF 2)   FILTER                                      DIOXIN / FURAN
CAA-225    CAA-      121197M23-     RF1 IN      PR      4       Melhod23 RF1 INLET RUN 4         ACETONE/MECL RINSE                          DIOXIN / FURAN
CAA-226    CAA-      121597 M23-     REAGENT BL   MeCL  2       M23 REAGENT BLANK 2 (MeCL)      REAGENT BLANK (MeCL)                         DIOXIN / FURAN
                                                                                Page 4

-------
                                                      -TRIANGI.fi LABORATORIES. INC.  --  UX3  IN RECORD/CHAIN OF CUSTODY=
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I   59
||TLI Number.. . . Client Sample ID 	 ... .Matrix) To LAI
JmR/H-CPM Client COC ID • Locatlqn . j Date/1
n 1
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' 1 M
||l94-59-15A CAA-177 FILTER||UrV •j-'V'*-
0 CAA-177 C02 ^f *v' I
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jj CAA-178 ' C02 .A
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(1 CAA-182 C02 ^/\
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1 • ; CAA-183 C02 */ \
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|| CAA-196 C02 ^J,,
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   Receiving Remarks:  NO COOLANT.  CAA-206 AND CAA207 ARE NOT PRESENT.
U  Archive Remarks:
                                                                =Form Revised 05/27/1997 -- Page 5 OF 6=

-------
                                                                                                                                                                     oo
Custody Seal : Absent Sample Seals: Absent
Chain of Custody : Present Container...! Intact
Sample Tags : Absent
Sample Tag Ifunbers: Not Listed on Chain of Custody
SMO Forms : N/A
n
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DTLI Number. . Client Sample ID Matrix) To L
jjmR/H'CPM . Client COC ID • Location j Date

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Di
1
||194-59-19D • CAA-204 XAD) /
1) CAA-204 C02 I/
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1) CAA-205 C02 , 	 )'
1
|194-S9-20B CAA-208 XAD|
I) CAA-208 C02 ., -|
I) 1
1)194-59-21 CAA-209 REAOENT BLANK MECL2 1
0« . ' CAA-209 C02 }f
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IJ194-S9-22A CAA-216 FILTER)
fl CAA-216 C02 Vxf
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/Init | Date/lnit
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I
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Tl,I Project Number 44376 j Book |j
Client: ELS 01 - Eastern Laboratory Services, Inc. J
Date Received | 12/17/97 | By /^JJ^^^ZsSo X P*9e "
Carrier and Number j HAND DELIVERED ^^ ^'^ | 59 jj
TO STORAGE)
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Date/lnit j Date/Inlt ||
D
II
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n
fl
B
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B
n
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fl
B
B
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D
B
B
B
B
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n
n
n
n
B
n
8
n
n
0
B
I  Receiving Remarks:   NO COOLANT.  CAA-206 AND CAA207 ARE NOT PRESENT.
I  Archive Remarks:
                                                                =Form Revised 05/27/1997  -- Page 6 OF 6=

-------
                       TRIANGLE LABORATORIES,  INC.
               SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
		-	ADMINISTRATIVE INFORMATION			
 TLI  Proj#:  44376-A     Samples: 10          TurnAround.:  21 Day(s)
 Prod Code:  D23061      Matrix.: M23Train    Hold Time..:  30 Day(s)
 DetectLim:  .05  ng      Type...: A           Start Date.:  12/17/97
                        Recvd..: 12/17/97    Ship By....:  01/05/98
                                             DWL Due Dt.:  12/24/97

 Analyte  List.:  Method 23:T-0 (Toluene combined

 Method.	:  Method 23 :Tetra-Octa (Tol Combined)
 Client Proj..:  Gulp Aluminum Alloys
 Client	:  Eastern Research Group (ERG02)
 P.O.  No	:  Signed OA                    Collect Dt/Tm:  SeeCOC
 Contact. .....:  Jim McGaughey                Phone	:  919/461-1209
 Proj . Mgr. . . . :  Amy J.  Boehm                 Fax	:  919/461-1579
                                             Sample  Origin:  NC
                 •SPECIAL INSTRUCTIONS / QA REQUIREMENTS	
                                         Prespike Standard:  USD-C, USD-S
                                         Prespike Amount..:  4.Ong
	REPORTING REQUIREMENTS •
 Reporting  Format:  Report Option II

 See MILES  for  Instructions/Communications.
 Completed by:  	  DATE:
Reviewed by:      /U&	  DATE:   iW.?J-W-    (PMGT0197)
                  .p-.

-------
                          PROJECTCOMMUNICAT10N TRACKING FORM
                                                                       page	'of'	
                    'tU Project Number:
                                                    LIM
     Use this'form' to record ail exchanges of information between production units as we!! as-personnel
     •handling this project. Decisions, corrective actions and recommendations must also appear on this
                                       tracking document                  .             .
Date -
Name [ Comment / Decision / Resolution / Action / Observation
                     TriangTelaborataries, Inc
                    -TLI PROJECT* 0404-7 ~
                     DATE  t1725/97  TLI BLANK
                     SPIK£-4.Qng USF-C USF-S
                     PREPAR
                             EASTERN RES.GRP.

-------
Date: 12/29/97
Time: 16:13
 Sample
 It  crd TLI_Number.. Customer .Sample. Id

 020    TLI LCS      TLI LCS

 021    TLI LCSD     TLI LCSD

 000    TLI Blank    TLI M23 Blank

 001    194-59-10A-D 141-144

 002    194-59-11A-D 153-156

 003    194-59-12A-E 157-160/166

 004    194-59-13A-E 161-164

 005    194-59-14ACD 165,167,168/225

 006    194-59-15A   177/182-184/209

 007    194-59-15B-D 178-181/226

 008    194-S9-17A-D 193-196

 009    194-59-19A-D 201-204

 010    194-59-18A/B 198/199/305/208
TRIANGLF. LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Project: 44376-A
F.
No
0
0
0
1
1
1
1
1
1
1
1
1
1
XAD
Color
LOT P-1078
LOT P-1078
WHITE
WHITE
WHT./YELLO
WHT/YELLOW
WHT/YELLOW
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
Filter
Color
NA
NA
NA
GRAY
BLACK
BLACK
BLACK
BLACK
WHITE
WHITE
WHITE
WHITE
WHITE
Glass Wool
Color
NA
NA
NA
WHITE
WHT./YELLO
WHT/YELLOW
WHT/YELLOW
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
PUF
Color
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Odor
NA
NA
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
Air
.. Q.No.
NA
NA
04047
04047
04047
04047
04047
04047
04047
04047
04047
04047
04047
Entered By
HILLKT
HILLKT
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIOHAM
Date
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
PRDPERC V4.01
Page : 2
. . . Time 	 S
13:45 F
13:45
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16 1 13
F
F
F
F
F
F
F
F
F
F
F
F
   •• End of Report  *•*

-------
 I Project: 44376A
                                                     •TRIANGLE LABORATORIES,  INC.                                    PAGE  1  OF  2
                                        Dioxin Sample Preparation Tracking & Management Form
                                                                              Client: Eastern Research Group  (ERGO21
                                                                  	-^	1
                                                                    Method: Method  23 :Tetra-Octa (Tol Combined)   Matrix: ft\.?5 ((U\     |
                                                                  Extraction Date:
|  Solvent (3)/Acid (s) :  \Clu£VlZ  /
|  Lot  Numbers:
I is ipixe: »u u± cone: u.iuuu ng/M-L
1 SS Spike: ul cone: . nq/wl
| MS Spike: 0 ul cone: 0.0000 ng/ul
| LCS Spike: 0 ul cone: 0.0000 ng/ul
| OPR Spike: 20 ul cone: 0.01 ng/ul .
| | TLI / . I GROSS |. SI
|S#.crd| SAMPLE / CLIENT | WEIGHT | £
1 | ID / SAMPLE ID | Before After | 9
|A | TLI Blank | , , | A|
|000 | TLI M23 Blank | .' J ^\ \ (^ ^ \
|A | 194-S9-10A-D | '1 1
|001 | 141-144 | j\||V | ^$r 1
|A | 194-59-11A-D 1 . , 1 A 1
|002 | 153-156 | J|f.j^' 1 Mp !
|A 1 194-59-12A-E | , I A |
|003 | 157-160/166 | |\| <\ \ ft • ) |
|A | 194-59-13A-S | . | . I A, |
|004 | 161-164 | f\J f\ I 'V 1
|005 | 165,167,163/225 | ^ ' ) | P fT 1
. -. _,. 	 4£&)J?\^\T* 	 	 » 	 » 	 + 	
|A | 194-59-1SA /It ^ -"Pi 2.1 1 i\|A 1 fit /V- 1
|006 | 177/182-184/209 | '»H | ( \( {] |
„ 	 . dSb.ialf&l^ 	 +...' 	 + 	 *-..
|A | 194-59-15B-0/ /UA/if I -A 1 A/A 1
|007 | ' 178-181/226 1 I V U 1 /I/M I
&) '•*/2*/T5 "
|A | 194-59-17A-D | » | r A |
IOOB i 193-196 1 W li i r* r\ i
|A | 194-59-19A-D ' \{ t\ ' i\f fV '
|009 | 201-204 | jlj }\ 1 1 \P 1
1 jL^' 1 Jffi^ ' IChemist 1
i <5t?'S~C i 5^5X i
i ££-1' . i tL5f-/4 i
'fclv.* Tt / z^ /t^ i t? / Sb/ 9*7 ~ / ~ /~
WPLE | )S. : M. 1 / .*tyA6L 	 : 	
SIZE 1 0-1 nq/wl I O.I ng/M'l 1 ng/jil
/ ml I . ^(7 ul 1 ^TLJ ul 1 ul

1 '-I* \j£ \
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_/_/_! " Date
	 : 	 | " Time
nq/ul 1 • Cone .
ul 1 " Vol.

|Any Left!/
| g^s/no i
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1 <5y*s/no i
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1 ts*/no 1
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Initials: Dace: / / -^^-
|  Initials of  both  SPIKER  AND OBSERVER must be entered.
                                                                              XXXXX  * Gross  Weight  not  provided for WATER Samples.  |
                                                                             	REV 05/27/97 (PSTMF 7)--.
                                                                                                                                    9

-------
  Project:  44376A
                                                     TRIANGLE LABORATORIES, INC.                                    PAGE 2  OF 2
                                        Dioxin Sample Preparation Tracking 4 Management Form.
                                                                              Client: Eastern Research Group  (E3G02I
                     -/- ""-/,
  solvent (s)/Acid (s) :  \fllW\lV   /
|  Lot  Numbers:
  Method: Method 23 :Tetra-Octa  (Tol Combined)  Matrix:/l(T5llft;Aj '
Extraction Date:
| IS Spike: 40 M! cone: o.iooo ng/yi » 	 	 	 • 	 —y 	
1 SS Spike: Ml cone: . ng/Ml 1 L-K 1 J ^)
\ MS SpiVe: 0 |*1 con^- 0.0000 nq/Ml | J*f& ' ~_,.__ 1 L)O l3/l
| ^rs Spilc«. 0 fil cone; 0.0000 ng/Ml 1 klE- ^ ' l.ii)^"r\
\ OPR Spike: _20 M! cone: _0.01_ ng/Ml I i? / £/ / J? 1 JJ 1 fa. /~L
	 ... 	 .., 	 ,. 	 .., \Z / 71 fV> \ leil 3&£)'
* 	 » 	 	 — - * * ir ' ^_i. 'A3 1 iSy *£!*JJ-
| | TLI / 1 GROSS | SAMPLE | |S : 30 | ^/ : Y^1
|S*.crd| SAMPLE / CLIENT | WEIGHT | SIZE | D . 1 ng/Ml I _fl • / ng/M]
| | TD / SAMPLE ID | Before After 1 g / ml | M[) M! 1 {J-LJ MJ

|A | 194-59-18A/B 1 20 40 \ ./> 1 A / /I 1 . 1 -<\>J I ^*Z~~
|010 | 198/199/205/208 | (\J tt I 'V/| | ' | ' I"*T/
j^iiL^/ia . . ,-- 	 * 	 « 	 -, 	 .J^f.h: 	
'O'/ ^iCltywjfy^ ' | 1^0^1I^^*JX%^
ii ii ii ' W ^*i //v^ J
II 1 1 1 1 0.^ 1 j5->7
II 1 1 1 1 1
II 1 1 1 1 1
1 1 1 I 1 1
1 1 1 1 1 1
II 1 1 1 1 1
II 1 1 1 1 1
II 1 1 1 1 1
II ll-ll 1
11 1 1 1 1 . 1
, I 1 1 1 • i
II I I I 1 1
II 1 1 1 1 1
II 1 1 1 1 1
II I I 1 1 1
I Gross weight of sample container + sample before/after aliquot removal.
1 Comments: •D^'fcxW U/7M f»"o , Ld fl&'*=>e
1 1 •
I LvtJlPfi" ft~ '^rZT'&fi t^CL^-th-Z- "ff 3-— QjCuA v a^uzf \*)a^> $*
I /. J ' ' 1 ^J
..« 	 „ 	 ,. 	 |
I I I Chemist |
I I ISpike * \
.1 1 1 " ID 1
%\ — 1 — /_ 1 _ / _ /_ 1 " Expirj
'fiH* : 	 | 	 : 	 | " Time |
L | 	 ng/Ml I 	 ng/Ml | " Cone. |
.1 M! 1 ul | " Vol. i

| I |Any Left!
1 1 1 yes/no ;
1 1 . |Any Lefrj
• 1 1 1 yes/no i
0&&J?
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| . | | yes/no i
| | (Any Left!
1 1 ' 1 yes/no i
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| 1 • 1 yes/no !
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1 1 1 yes/no |
1 1 |Any Left]
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| | |Any Left|
1 . 1 1 yes/no |.
| | • |Any Leftj
1 1 1 yes/no |
| | |Any Left|
1 1 1 yes/no |
1
f
1

U 9 \
i
                                                                                             Initials:
                                                                                                                 Date:
  Initials of both SPIKER AND OBSERVER must be entered.
                                                                               XXXXX - Gross Weight not provided  for WATER Samples.
                                                                              	REV 05/27/97  (PSTMF  7)-

-------
        PAGE 1 OF 2
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM |
TLI Project No.: 44376 A
Ext SO.crd and | I. | | n \ . \ \ \ \ ^ | 1' £&l /Ofi >-
TLI Number | ' | ^~ \ 'n \ & \ ^> \ ]j) \ 7 \ Q C\ J | .p?/ol Qi
TLIBlan* | £ ||l /f^jCTL \^~' ' WL \ WL l' WC l^3^> ^ ' • !/?/,,l ,_ >
A 001 | J ^"l |
194-59-10A-D 1 * ,' „• 1 1
. A 002 I .-_v; 3\ 1
194-59-11A-D 1 ~i 1 1
+ -, * +
A 003 |" .| C£ | |
194-59-12A-E I ^ -* 1 1
A 004 | \ | |
194-59-13A-E | >J | |
.... 	 i-^"> 	 *-- 	 .--J.----L
+. •* + + -t-
A 005 | ? | | 1
194-59-14ACD | ~ | |
A 006 • . |. -^ | |
194-59-15A | V~ | | 1
1
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1 1 \ 1
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1 1
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A 007 | jf^ | | I |
194-59-15B-D 1^. | ill
	 	 + _-^ 	 + 	 + .J..... + ...
A 008 |^| | |
194-S9-17A-D | ^ | | 1 |
A 009 | I | | L
194-59-19A-D | ^Un^ , ^ | \]3\*£
Enter the procedure number below into the
Initial and date each sample for each numb
0 . . . . PROCEDURE SOP # "V . DETAILS
' 1?\ EXTRACTION | ) 1 » Time On
v^ .-• ^*~ -^^
^oxhlep
(^) SPIKE AFTER EXT'N
( . 3?) ADD TRIDECANE ^ Lot#T^>
(I) ROTOVAP ^T^PiaM V- % 40mL f
S) COMBINE ^
§DIV./LIP. DETERM. 'JSP /// ^-S 20%/80%
v \ v
BlijLfcf
box at t
ered pro
(circle)
/B-:IS~
1 1
1 1
1 / 1
1 1
' i 4/ i <
ii
1
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1
1
1
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1
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i ii
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•"-+""r"*"1 	 + 	
/ i i i
i 1 i i
[T f 1 **\ * Ir
he top of each column to signify the ctep performed.
:edure performed.
Time Off *3 : IS" *»*-
/ Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
s 	 ""*
<5^%/50> 5mL/20mL Other
SOLVENT EXCHANGE Iso-Octane Lot# ^ "77/£'/ _Hfintane Lot#
f CLEANUP CSSP 263±
TRANSFER 2^-X ^- *"
ADDITIONAL CLEANUP 	 god . DSP
11) FINAL TRANSFER 	
, / DSP 225 /^DSP Iis9/ DSP 215 / DSP
26p /
DSP 225 / DSP 115 / DSP 215 /
267 / Other
DSP 267 / DSP260(10g)
Cements: 7/L'/ f tf m> .L{jt "7^ Q'7bD5(j U AJLH -fa Lt ! rV\jL i&U n//'Vl3iirKj
L^ - CWLlLl^ /.l/?/J fO •? f O - f
; 1 u ~
11/25/97 (PSTMF 4)»=
             24

-------
                                                                                                           PAGE  2 OF 2
                                             TRIANGLE LABORATORIES,  INC.
                                  DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
                                               TLI Project No.:  44376 A
Ext S#.crd  and
TLI Number         |

                  I
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each  sample for each numbered procedure performed.

#	PROCEDURE....  SOP.#. .v..  DETAILS (circle)
/!)/EXTRACTION          l\ I   *&   Time On to  Jj   Time Off % : I * «*•*-
^—^                    	 	 -—     s—   —           —   —
                                  QSoxhlet, / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Haste Dilution
    SPIKE AFTER EXT'N
    ADD TRIDECANE             .     Lot# TRI' I - 3 ~H»
  V ROTOVAP
 5) COMBINE
     IV./LIP. DETERM.  &%P  1)1
'1\ SOLVENT EXCHANGE               Iso-Octane Lot* ^Tl '(,-{    Heptane Lot#_
 8> CLEANUP                   	^                                                                  	
 9? TRANSFER           $.•$-'  !L
10) ADDITIONAL CLEANUP        	  Mod.  DSP  260   /  DSP 225   /  DSP  115  /  DSP 215  /  DSP 267  /  DSP260(10g)
    FINAL TRANSFER            	
SmL/20mL
Other
                                  20%/80%
                                  Iso-Octane Lot*
                                  JSP"T60N /  DSP 225  I  DSP 115  /  DSP 21S  /  DSP 267  /  Other
  „%
                         .Rev 11/25/97  (PSTMF
                                                                                                               25

-------
                                                                  PAGE 1 OF 1
                         TRIANGLE LABORATORIES, INC.
                        Transfer Chain-of-Custody Form
                               Project 44376-A

                     Transfer  From: DWLH5     To: DMS5

                            Initials. .     Date	     Time

              Released by:       '-^    J_/^L_/J^    \0 ••

              Accepted by:
MILES . ID
44376-A
44376-A
44376-A
44376-A
44376-A
44376-A
44376-A
44376-A .
44376-A
44376-A
44376-A
44376-A

-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
. TLI No 	
TLI Blank
194-59-10A-D
194-59-11A-D
194-59-12A-E
194-59-13A-E
194-59-14ACD
194-59-15A
194-59-15B-D
194-59-17A-D
194-59-19A-D
194-59-18A/B
.TLI Clean-Up
Cust .Id 	
TLI M23 Blank
141-144
153-156
157-160/166
161-164
165,167,168/225
177/182-184/209
178-181/226
193-196
201-204
198/199/205/208
Cleanup Blk
	 xf-r-roc: (RRV 11/01/94)--+
Additional comments or instructions:

-------
                                                                                                                PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Method: Method 23 :Tetra-Octa (Tol Combined) HR GC/HRMS ANALYSIS
Required Detection Limit : . 05 ng
1
| PROJECT: 44376A |
SAMPLE INFORMATION RS Cone |
1ST COLOMN 2ND COLOMN 20 fil « 100.0 K/pi 1
| TLI / I GC/MS FILENAME) CONFIJ
S».crd| SAMPLE ID / CLIENT | COLUMN: Qftj |
| / SAMPLE ID | I
A | TLI Blank I 1 f
000 | TLI M23 Blank | - ¥00^£>' \
A | 194-59-10A-D 1 1 |
ooi | 141-144 | f C£yv37Ii ' I
A | 194-59-11A-D I . ' \/
002 ' 1S3-156 I j0.a,/y^ -? CC^,\ | V
»| 165,167,168/225 | |
| 194-59-15A ICtft^^-^S- 1 /
006 | 177/182-184/209 | | ^j
A | 194-59-15B-D (Lift <-.°^ J^ |
007 | 178-181/226 | | \l
A | 194-S9-17A-D | \J&^) OS^>\ \ .
008 | 193-196 | | V
A | 194-59-19A-D | 1
009 | 201-204 \\jjtylty^>3 \ V
	 |
A | 194-59-18A/B | I
010 | 198/199/205/208 | |/^^£/0^6 | \/
\}\ I
iM | CONFIRM FILENAME |USF-
1 COLUMN: 'pfl'^tf' IVOLD1
I ISOLN
RS |nSF-RS | ANALYSIS |
ME |INIT. (COMMENTS }
ID (DATE | j
| V^^ JW**^ I \fJ ^&+. j j
1 1 .
1 1
1 1
1 ^ 1
1 1
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1 1
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i *& //^/9 8"" i
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Comments:
                                                                                                            Type: A
                                                                                                      Spike File: SPX23704

                                                                                                      Amc of Extract: 50*
                                                                                                     	REV 03/07/95  (PSTMF

-------
                                                         Triangle Labc

                                                                 Rum
                                                                        i, Inc.
                                                                                                                                    C«J
Instrument ID Column Type Column ID

Plot Name Ini. Vol. Acquisition QIC
&«^ Aw^ ,M,
' Slgnaturft ' 'Date
Filename
                Dele*
Time*
Projedff
Sample/?
                                       ^7-7-7-)
No.
Client Sample ID
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      Transcribed from chromatographlc data

*     Dated Initials required



irvtl/qa/fotmt/hmmlofldoc (02/D5/97)
                                                        ConCal Due:

                                                        ConCal Due:
                                                                                                                   Page:

-------
                                                          Triangle Labc    Mes, Inc.
                                                                  Run L
                                                                                                                                     O)
                                                                                                                                     CvJ
Instrument ID Column Type Column ID Plot Name

Inl. Vol. Acquisition
j&fc/L^ fc*W-^
' /Signature «
QIC
/6/fSJ
'Dale
Filename
                 Dale*
Time4
Project*
Sampleff
                                           17-fl-i.
No.
                                                     5
Client Sample ID
8yr
332
                                                                                         3-3
                                                                                             lu.
Opeialor/Dale
Comments*
                                                     7
                                                                                                #51/6/»
                                                                                         /•*»
                                                                                         £1
                                                     o

      Transcribed from chromatographlo data
      Dated hillials required

tivil/qa/roims/tmunloodoo (02/05/97)
                                                        ConCal Due:
                                                        ConCalDue:
                                                                                                                    Pa

-------
                                                          Triangle LaHRtories, Inc.
                                                                 Run Log
Instrument ID       Column Type         Column ID
                                                                 Plot Name
                                                                    Inl. Vol.
                                                                                    Acquisition
                                                                                             Signature
                                                                                           G/C
                                                                                                        '  Date
    Filename
Dale*
      Time*
Project #
                                       Sample*
No.
Client Sample ID
Syr
332
Operator/Dale
Comments*
                                                                                    3A_
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                        Zlcfc
>|$0
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                                               la
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      Transcribed from chromalographic data
**     Dated initials required

sm1/qa/rorms/hrnjnlog.doc (02/05/97)
                                          ConCal Due:
                                          ConCal Due:

-------
                                                  Triangle Laboratories, Inc.
                                                          Run Log
Instrument ID : Column Tvpe Column ID Plot Name
v£o ^ £)t O-VT VS'sf^'V^*'" TT'f

Ini. Vol. Acquisition
• ^ ^ v>_
Signature
M
1-

G/C
*-l^
Date
Filename
                Date*
Time*
Project #
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
                                                                                  L'i
                                                                                  K-C
                                                  0
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                                                         V-r
                                                                                                       4-9-U
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      Transcribed from diromatographic data
"     Dated initials required

sr/r1/qa/(orms/htmnlog.doc (02/05/97)
                                                    ConCal Due:
                                                    ConCal Due:
                                                                                                           Pa

-------
SAMPLE
  DATA
         Triangle Laboratories, Inc.
  801 Capftola Drive        P.O. Box 13485
  Durham, NC 27713-4411      Research Triangle Park, NC 27709-3485
  919-544-5729           Fax # 919-544-5491
                                   1 O
                                   o U

-------
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HXCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
U980026
TLI M23 Blan
ng
12/29/97
01/06/98
U
XAD
Soxhlet

(0.004)
(0.006)
(0.01)
(0.008)
(0/008)
(0.01)
0.03 J
0.02
(0.005)
(0.005)
(0.006)
(0.005)
(0.006)
(0.007)
(0.008)
(0.01)
(0-01)
(0.004)
(0.006)
(0.008)
(0.01)
0.04
(0.005)
(0.006)
(0.008)
                                              PRJ
                                              J
                                              J
                                              J
                            TRIANGLE LABORATORIES,  INC.
                     Sample Result Sunmary for Project 44376A
                            Method MIT2 Analysis (DB-5)
                                                         0980028
                                                         153-156

                                                           ng
                                                        12/29/97
                                                        01/06/98
                                                            O
                                                        M23TRAIN
                                                         Soxhlet
  0.68  PR
  4.0
  4.5
  7.3
 10.3
 43.1   E
 69.6
 65.2   E
.15.6
 29.4
101     E
 34.9
 53.2
  3.1
163
 24.8
144
 72.0
 65.7
 93.7
 86.7   E
364     E
398     E
413     E
270     E
                                                PRJ
                                       O980027
                                       141-144

                                         ng
                                      12/29/97
                                      01/06/98
                                          0
                                      M23TRAIN
                                       Soxhlet
  0.02
  0.03
  0.02
  0.04
 {0.04}  J
  0.15
  0.24  B
  1.5
  0.15
  0.22
  0.44
  0.15
-0.20
  0.02
  0.62
  0.08
  0.46
  2.8
  0.47
  0.37
  0.31
 12.8
  3.7
  1.8
  0.98
Other Standards Percent Recovery Summary  (% Rec)
37C1-TCDD             85.7             84.8

Other Standards Percent Recovery Summary  (% Rec).
13C12-PeCDF 234       99.5             89.0
13C12-HXCDF 478       84.0             98.1
13C12-HXCDD 478       89.8             90.8
13C12-HpCDF 789       84.3             84.9

Other Standards Percent Recovery Summary  (% Rec)
13C12-HXCDF 789       52.6             73.2
13C12-HXCDF 234       60.7             73.1

Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF       46.0             64.4
13C12-2378-TCDD       51.1             64.1
                                                                       Page   1
                                                                        01/10/98
                  0980029
                157-160/166
                  A ""  _  .-.    v
                    ng
                 12/29/97
                 01/06/98
                     O
                 M23TRAIN
                  Soxhlet
                                                          87.9
                                                          90.7
                                                         109
                                                          93.8
                                                          97.7
                                                          65.0
                                                          63.5
                                                          61.0
                                                          53.3
                                                                E
                                                                PR
                                                                E

                                                                E
                                                                E
  0.71
  5.0
  5.4
  8.1
 11.9
 55.4
 87.1
 76.6
 15.7
 31.9
 98.8
 35.5
 53.9
  3.1
200
 34.5
>40.0
143
103
154
114
441
419
417
346
                   80.6
                   91.2
                   99.2
                   96.7
                   97.9
                   72.1
                   75.0
                   62.7
                   63.2
                                                                                   PR
                                                                                   E
                                                                                   E
                                                                                   E
E
PRX
E

SE
QE
E
E
E
E
E
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                         Printed: 12:21 01/10/98
                                                                                         
-------
                           TRIANGLE LABORATORIES,  INC.
                     Sample Result  Summary for Project 44376A
                           Method MIT2 Analysis (DB-5)
  Data File
  Sample 10

  Units
  Extraction Date
  Analysis Date
  Instrument
  Matrix
  Extraction Type
                    U980026
                 TLI M23  Blank

                      ng
                   12/29/97
                   01/06/98
                       U
                      XAD
                    Soxhlet
 U980027
 141-144

   ng
12/29/97
01/06/98
    D
M23TRAIN
 Soxhlet
  Internal Standards Percent Recovery  Summary (% Rec)
  13C12-PeCDF 123      45.2              69.9
  13C12-PeCDD 123      50.6              66.9
                       55.3              70.
13C12-HXCDF 678
13C12-HXCDD 678      59.4
13C12-HpCDF 678      49.9
13C12-HpCDD 678      56.5
13C12-OCDD           48.8
                                         80
                                         73
                                         75
    .9
    .0
    .3
    .4
                                         66.1
 O980028
 153-156

   ng
12/29/97
01/06/98
    U
M23TRAIN
 Soxhlet
  59.1
  50.0
  58.4
  74.3
  69.6
  68.7
  61.3
                                                                       Page  2
                                                                        01/10/98
  U980029
157-160/166

    ng
 12/29/97
 01/06/98
     U
 M23TRAIN
  Soxhlet
   66.4
   63.0
   67.6
   77.1
   77.2
   74.0
   78.3
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                        Printed: 12:21 01/10/98
                                                                                       24

-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method MIT2 Analysis (DB-5)
iData File
(Sample ID

Onits
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378 -PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
123467 8 -HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HXCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
fcOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
0980030 1^-^^0980031
161-164 / 165\ 167, 168/225
*''-';
ng
12/29/97
01/06/98
O
M23TRAIN
Soxhlet

0.61 PR
3.4
3.7
5.7
8.3
32.9
47.1
53.8 E
13.8
23.8
72.8 E
25.9
38.5
2.5 PR
107 E
17.1
79.7
68.1 E
55.0
92.0 E
68.8
288 E
324 E
300 E
180 E
k" - •*"/
ng ' /
12/29/97
01/06/98
O
M23TRAIN
Soxhlet

0.51 PR
3.6
4.7
7.4
10.3
40.0 E
63.1
64.6 E
15.8
28.7
97.5 E
32.5
47.4 E
2.8 PR
155 E
25.6
160 E
76.5 E
58.1
114 E
80.3 E
370 E
391 E
403 E
262 E
Page 3
01/10/98
0980032 O980033
177/182-184/209 178-181/226
^(t. ^f"- Df \ /
"ji <•"- ng
,vJ. 12/29/97
' 01/06/98
O
M23TRAIN
Soxhlet

(0.004)
(0.006)
(0.007)
(0.006)
(0.006)
0.02 J
0.06 JB
{0.03} B
0.01 J
0.01 J
0.03 J
0.01 J
0.02 J
(0.006)
0.13
(0.01)
0.11 J
0.01
0.01
0.02
0.02
0.05
0.07
0.11
0.13
£f.1 ff'i -rv '
ng "" .:•<••
12/29/97
01/06/98
O
M23TRAIN
Soxhlet

(0.005)
(0.008)
(0.01)
0.01 J
{0.01} J
0.04 J
0 . 14 JB
0.07 B
{0.02} J
0.03 J
0.08 J
0.03 J
0.04 J
(0.009)
0.14
(0.01)
0.10 J
0.04
0.01
0.03
0.08
0.30
0.36
0.28
0.18
 Other  Standards Percent Recovery Summary (% Rec)
 37C1-TCDD            79.4              82.9             82.4

 Other  Standards Percent Recovery Summary (% Rec)
 13C12-P6CDF 234      85.6              85.5             93.9
 13C12-HXCDF 478      99.9             104               92.5
 13C12-HXCDD 478      84.6              97.1             90.3
 13C12-HpCDF 789     100                93.7             95.1

 Other  Standards Percent Recovery Summary (% Rec)
 13C12-HXCDF 789      53.0              80.7             77.7
 13C12-HXCDF 234      54.7              79.9             78.0

 Internal  Standards Percent Recovery Summary (% Rec)
 13C12-2378-TCDF      46.2              75.3             62.5
 13C12-2378-TCDD      44.7              68.4             68.1
RO
           83.1
98.4
92.4
97.0
85.2
           63.
           68.
          60.5
          63.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
          Printed: 12:21 01/10/98
                        35

-------
                            TRIANGLE LABORATORIES,  INC.
                     Sample Result Summary for  Project  44376A
                            Method MIT2 Analysis (DB-5)
                                                                        Page  4
                                                                         01/10/98
  Data Pile
  Sample ID
                     0980030
                     161-164
   0980031
165,167,168/225
Onits
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
=taS=SS3333S = = S3:3 = SS
ng
12/29/97
01/06/98
0
M23TRAIN
Soxhlet
ng
12/29/97
01/06/98
0
M23TRAIN
Soxhlet
B3=3S= = ==rS=SS5:=3»3IS53
   0980032
177/182-184/209

     ng
  12/29/97
  01/06/98
      U
  M23TRAIN
   Soxhlet
  0980033
178-181/226

    ng
 12/29/97
 01/06/98
     0
 M23TRAIN
  Soxhlet
  Internal Standards Percent  Recovery Summary  (% Rec)
  13C12-PeCDP 123      46.1              74.6
13C12-PeCDD 123       44.1
13C12-HXCDF 678       50.6
13C12-HXCDD 678       66.3
13C12-HpCDF 678       61.4
13C12-HpCDD 678       64.3
13C12-OCDD            61.7
                                         71.4
                                         77.0
                                         80.8
                                         85.0
                                         88.5
                                         80.0
                      72.1
                      79.7
                      73.9
                   ,—22.1	:_,.
                   ', _39.7    RO
                      8774	-"
                      86.9
                      59.5
                      67.7
                      64.3
                      75.3
                      63.2
                      76 .3
                      75.6
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                          Printed: 12:21 01/10/98
                                                                                       o ^
                                                                                       3o

-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method MIT2 Analysis (DB-5)
Data File
Sample ID

Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HXCDF
123789-HXCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total MCDD
Total DCDD
Total TriCDD
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
Total MCDF
Total DCDF
Total TriCDF
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
O980034
193-196/
ftX~- //
ng
12/29/97
01/06/98
D
M2 3 TRAIN
Soxhlet

{0.006}PRJ
0.04 J
0.02 J
0.04 J
0.05 J
0.12
0.25 B
0.45 B
0.14
0.22
0.31
0.12
0.14
0.02 J
1.2
0.17
0.41



0.31
0.52
0.53
0.23



2.2
2.9
1.4
1.9
O980036
198/199/205/208
^ / --
ng ir-r
12/29/97
01/07/98
U
M23TRAIN
Soxhlet

0.07 PR
0.48
0.26
0.46
0.57
1.2
0.65
7.6
1.7
2.9
6.0
2.3
2.4
0 . 15 PR
6.1
0.72
1.5



13.2
11.0
9.2
2.8



41.5
44.2
25.8
10.3
U980035
201-204
. .fVKi-'O '
ng
12/29/97
01/07/98
U
M23TRAIN
Soxhlet

(0.004)
0.02 J
(0.01)
0.02 J
0.03 J
{0.09} J
0.16 JB
0.29 B
0.07 J
0.12
0.23
0.09 J
0.12
(0.007)
0.43
{0.05} J
0.31



0.22
0.24
0.33
{0.18}



1.5
1.6
0.96
0.65
Page 5
01/10/98
D980037
Cleanup Blk

ng
01/05/98
01/07/98
U
SOLVENT
Soxhlet
— ,-f.JT -| _J — f— ^•••y-»T^.!..»»j.(...g^-i_Ji-— -—

(0.002)
(0.004)
(0.005)
(0.004)
(0.004)
(0.005)
0.01 J
(0.002)
(0.002)
(0.002)
(0.004)
(0.003)
(0.004)
(0.004)
(0.004)
(0.004)
(0.005)
(0.0)
(0.0)
(0.0)
(0.002)
(0.004)
(0.005)
(0.005)
(0.0)
(0.0)
(0.0)
(0.002)
(0.002)
(0.003)
(0.004)
 Other Standards Percent Recovery Summary  (%  Rec)
 37C1-TCDD            85.2              79.1

 Other Standards Percent Recovery Summary  (%  Rec)
 13C12-PeCDF 234      93.6              86.9
 13C12-HXCDF 478      92.8              79.7
 13C12-HXCDD 478      98.0              78.9
 13C12-HpCDF 789     107     RO         88.3

 Other Standards Percent Recovery Summary  (%  Rec)
 13C12-HXCDF 789      79.0              84.6
82.8
92.0
82.6
86.8
93.8
81.4
80.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                 Printed: 12:21 01/10/98
                              07
                              o i

-------



Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Method MIT2 Analysis (DB-5)
U980034 U980036
193-196 198/199/205/208
ng ng
12/29/97 12/29/97
01/06/98 01/07/98
U D
M23TRAIN M23TRAIN
Soxhlet Soxhlet

44376A

U980035
201-204
ng
12/29/97
01/07/98
U
M23TRAIN
Soxhlet
Page 6
01/10/98

U980037
Cleanup Blk
ng
01/05/98
01/07/98
D
SOLVENT
Soxhlet
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 234
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
13C12-HXCDF 678
13C12-HXCDD 678
13C12-HpCDF 678
13C12-HpCDD 678
13C12-OCDD
77.2 85.6
Percent Recovery Summary (% Rec)
60.0 82.3
79.6 81.4
78.7 86.0
86.0 66.4
72.7 90.4
85.3 98.6
40.6 RO 80.7
95.1 80.9
92.1 73.2
82.8

73.1
75.1
76.4
68.3
85.4
89.4
79.9
86.7
81.3
=s:s=3sss = s:s:s== = s:
84.4

66.8
68.8
76.3
59.6
68.7
78.9
81.0
87.2
84.3
  {Estimated  Maximum Possible Concentration),   (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1251 01/10/98
                38

-------


TRIANGLE
Sample Result
LABORATORIES, INC.
Summary for Project

44376A
Page i
01/09/98
Method 23X (DB-225)
Data Pile
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
P980094
TLI M23 Blank
ng
12/29/97
01/06/98
P
XAD
Soxhlet

0.02
P980095
141-144
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet

0.27 B
P980096
153-156
ng
12/29/97
01/07/98
P
M2 3 TRAIN
Soxhlet

11.6
P980097
157-160/166
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet

16.1
  Internal Standards Percent Recovery Summary (% Rec)
  13C12-2378-TCDF       63.6              78.9
65.5
71.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                  Printed: 10:2301/09/98
                                  29

-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A

Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF

P980098
161-164
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet

10.5
Method 23X (DB-225)
P980099
165,167,168/225
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet

13.4

P980100
177/182-184/209
ng
12/29/97
01/07/98
P
M2 3 TRAIN
Soxhlet

0.02 B
Page 2
01/09/98

P980101
178-181/226
ng
12/29/97
01/07/98
P
M2 3 TRAIN
Soxhlet

0.03 B
  Internal  Standards  Percent Recovery Summary  (% Rec)
  13C12-2378-TCDF       48.9              79.8
72.0
76 . 5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                  Printed: 10:2301/09/98
                                                                                               40

-------
                            TRIANGLE  LABORATORIES,  INC.
                      Sample Result Summary for Project 44376A
                                Method  23X (DB-225)
                                                   Page   3
                                                    01/09/98
  Data File
  Sample ID
P980102
193-196
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet
0.10 B
   P980104
198/199/205/208

     ng
  12/29/97
  01/07/98
      P
  M23TRAIK
   Soxhlet
 P980103
 201-204

   ng
12/29/97
01/07/98
    P
M2 3TRAIN
 Soxhlet
                                           1.4
                                     0.07   B
  Internal Standards Percent Recovery  Summary  (%  Rec)
  13C12-2378-TCDF       93.9              92.1
                                    89.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                      Printed: 10:2301/09/98
                                                                                           41

-------
 Method 23 Sample Calculations:

 Analyte Concentration

 The concentration or amount of any analyte is calculated using the following expression.
 Where:
                           At*RRF(a)*W
       Amt(a) -   amount of a given analyte, expressed in nanograms (ng) or picograms
                  (pg).
       AO     -   integrated current for the characteristic ions of the analyte
       A0     -   integrated current of the characteristic ions of the corresponding
                  internal standard
       Qp     -   amount of internal standard added to the sample before extraction
       RRF(0) -   mean analyte relative response factor from the initial calibration
       W     -   sample weight or volume (W - 1 .0 for Method 23 samples)
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor.  The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
Where:
       2.5
       F

     - H
       03
       RRF(0)
       W
                    DL(a> =
                              2*2.5*(F*H)*
                                            w
estimated detection limit for a target analyte, expressed in ng or pg
minimum response required for a GC signal
an empirical number that approximates the area to height ratio for a
GC signal. (F - 3.7 for all dioxin/furan analyses)
height of the noise
integrated current of the characteristic ions of the corresponding
internal standard
amount of internal standard added to the sample before extraction
   mean analyte relative response factor from the initial calibration
sample weignt or volume
Rev. 11/19/97

-------
 Data Flags

 In order to assist with data interpretation, data qualifier flags are used on the final reports.
 Please note that all data qualifier flags are subjective and are applied as consistently as
 possible.  Each flag has been reviewed by two independent demists and the impact of the
 data qualifier flag on the quality of the data discussed above. The most commonly used
 flags are:

 A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
 blank as well as in an associated field sample.  The 'B' flag is used only when the
 concentration of analyte found in the sample is less than 20 times that found in the
 associated blank. This flag denotes possible contribution of background laboratory
 contamination to the concentration or amount of that analyte detected in the field sample.

 An '£' flag is used to indicate a concentration based on an analyte to internal standard
 ratio which exceeds the range of the calibration curve. Values which are outside the
 calibration curve are estimates only.

 An T flag is used to indicate labeled standards have been interfered with on the GC
 column by coeluting, interferent peaks.  The interference may have caused the standard's
 area to be overestimated.. All quantitations relative to this standard, therefore, may be
 underestimated.

 A ' J' flag is used to indicate a concentration based on an analyte to internal standard ratio
 which is below the calibration curve. Values which are outside the calibration curve are
 estimates only.

 A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
 may be seen as two closely eluting peaks without a reasonable valley between the peak
 tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
 The concentrations or amounts reported for such peaks are most likely overestimated.

 A 'Q' flag is  used to indicate the presence of QC ion instabilities caused by quantitative
 interferences.

 An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
 outside of the acceptable QC limits, most likely due to a coeluting interference. This may
 have caused the percent recovery of the standard to be overestimated. All quantitations
 versus this standard, therefore, may be underestimated.

 An 'S' flag indicates that the response of a specific PCDD/PCDF isomer has exceeded the
 normal dynamic range of the mass spectrometer detection system.  The corresponding
 signal is saturated and the reported analyte concentration is a 'minimum estimate'.  When
 the 'S' qualifier is used in the reporting of 'totals', there is saturation of one (not
 necessarily from a specific  isomer) or more saturated signals for a given class of
Data Flags                                                                    Page 1 of 2
Rev. 11/19/97
                                                                                         43

-------
 compounds. Results for saturated analytes are reported as greater than the upper
 calibration limit

 A 'U' flag is used to indicate that a specific isomer cannot be resolved from a large, co-
 eluting interferent GC peak. The specific isomer is reported as not detected as a valid
 concentration cannot be determined. The calculated detection limit, therefore, should be
 considered an underestimated value.

 A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
 be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
 one.  The standard is considered reliably quantifiable. All quantitations derived from the
 standard are considered valid as well.

 An 'X' flag is used to indicate that a polychlorodibenzofuran (PCDF) peak has eluted at
 the same time as the associated diphenyl ether (DPE) and that the DPE peak intensity is at
 least  ten percent of the  total PCDF peak intensity. Total PCDF values are flagged 'X' if
 the total DPE contribution to the total PCDF value is greater than ten percent. All PCDF
 peaks that are significantly influenced by the presence of DPE peaks are either reported as
 "estimated maximum possible concentration (EMPC) values without regard to the isotopic
 abundance ratio, or are  included in the detection limit value depending on the analytical
 method
DaaFlags                                                                    Page 2 of 2
Rev. 11/19/97
                                                                                          44

-------
 TLI Project:     44376A
 Client Sample:   TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U980026
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
XAD Date Received:
TLI Blank Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor
Blank File:
Analyst
II
12/29/97
01/06/98
n/a
U980026
KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1.2.3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2.3.7.8,9-HxCDD
1,2,3.4,6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2.3.7,8-PeCDF
2.3.4,7,8-PeCDF
| 2J,4.7,8-HxCDF
.,2.3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1.2.3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2.3,4,7,8.9-HpCDF
1.2.3,4,6.7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Arm. (ng)
ND
ND
ND
ND
ND
ND
0.03
0.02
ND
ND
ND
ND
ND
ND
ND
ND
ND

An*L,(«gJ
ND
ND
ND
ND
0.04
ND
ND
. . ND
VWL EMPC \ Ratto RT
0.004
0.006
0.01
0.008
0.008
0.01
0.76 39:37
0.87 24:39
0.005
0.005
0.006
0.005
0.006
0.007
0.008
0.01
0.01

Number DL EMPC
0.004
0.006
0.008
0.01
2
0.005
0.006
0.008 . .. . _ 	 	
Flags






j







	



Flags



—




                                      Page 1 of 2
                                                                       MTTZ.PSR i\St\. LARS 6.1OBSI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:1501/10/98
                                45

-------
 TLI Project     44376A
 Client Sample:   TLI M23 Blank
Method 23 PCDD/PGDF Analysis (a)
            Analysis File:  U980026.
_
Internal 5&ftdard&
13C,2-2J,7,8-TCDF
3Cl2-2,3,7,8-TCDD
13C,2-U^,7,8-PeCDF
13Ci2-U,3,7,8-PeCDD
13CiZ-lA3,6,7,8-HxCDF
13C12-U3.6,7,8-HxCDD
13C12-U,3,4,6,7,8-HpCDF
I3C,z-l,2,3,4,6.7,8-HpCDD
13C,2-1.2,3,4,6,7,8,9-OCDD

Surrogate Standards {type A>
13C,r2,3,4,7(8-PeCDF
13C12-1 A3,4.7,8-HxCDF .
13Ci2-l,2,3,4,7,8-HxCDD
13C,2-U,3,4,7,8.9-HpCDF

Surrogate Standards (Type A)
"CLr2,3,7,8-TCDD
Alternata Standards (Type A)
13C,2-U,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1A3,4-TCDD
I3C,2-lA3,7,8,9-HxCDD
v>' A-mf- &>*&•-•**• *
' ^~ ^P^ *^ ' '
1.8
2.0
1.8
2.0
2.2
2.4
2.0
2.3
3.9

Amt fng)
4.0
3.4
3.6
3.4

Arnt$»§)
3.4
Aim. 
-------
                          Initial
                                       .Date.
  Data Review By:
                                                Calculated Noise Area:
  The Total Area for each peak with an  ion  abundance ratio outside
  ratio limits has been recalculated according  to method requirements.
                                                                         3.33
  Page No.
  .01/10/98
Listing of 09800268.dbf
Matched GC Peaks / Ratio  /  Ret. Time
  Compound/
  M_Z....  QC.Log Omit Why
  TCDF
  304-306
  304-306

  13C12-TCDF
  316-318
.RT.  OK Ratio Total. Area. .. Area. PeaJc. 1..  Area. Peak. 2. . Rel.RT Compound. Name. .  ID.. Flags.
  316-318
  TCDD
  320-322
 320-322

 37C1-TCDD
 328

DC




DC
DC




DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

DC






NL


2

NL
WL




WH
WH
4

NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
0
NL






0
24
24
Pe

0
23
23
24
24
25
26
26
Pei

0
22:
23:
23:
23:
24:
24:
24:
25:
25:
25:
25:
26:
26:
26:
Pea
0:
24:
25:
25:
25:
25:

:00
:16
:39
aks

:00
:36
:53
:15
:38
:34
:12
:26
1X3

:00
:49
:25
;33
:41
04
14
38
00
23
32
37
01
17
51
:ks
00
01
22
45
53
53
0
RO



0


RO


RO
RO
RO

0.
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO

RO
RO








.65
1
0
0

.65
0
0
0
0
0
0.
2.
3.

65-
1.
0.
2.
1.
0.
1.
2.
5.
1.
0.
1.
0.
0.
0.
0.







-0.89
.14
.68
.87

-0.89
.84
.69
.57'
.74
.74
.44
.18
.39
• L
- - Al
•0.89
05
42
88
30
76
17
38
14
00
42
15
87
54
34
72






- •
                                                14.37
                                                39.12         15.80
                                                64.58         30.03
                                               103.70
                     12. 68
                     220.36
                     22.80          9.92
                     67.57         28.78
                  8,771.67      3,743.99
                     24.64         10.72
                      5.19
                      3.40
                  8,886.68

             Above: TCDF / TCDD Follows -
                                                   0.867-1.079
                                                       0.000
                                                23.32  0.985
                                                34.55  1.001 2378-TCDF
                                                                             AN
      0.959-1.041
          0.000
          0.958
   17.26  0.970
   38.79  0.984
5,027.68  1.000 13C12-2378-TCDF  ISO
   24.29  1.038
          1.064
          1.073
                      3.43
                      3.52
                      2.09
                      3.58
                      2.08
                      3.35
                      1.27
                      2.87
                      4 . 44
                      9.10
                      1.63
                      5.30
                      2.18
                      3.45
                      6.17
                      0.00
                                                1.99
                                               38.33
                                             6,364.27
                                               45.79
                                               16.95
                                             '  3T. 57-
                                  38.33
                               6,364.27
                                  45.79
                                  16.95
                                  37. ST
       .895-1.047
          0.000
          0.900
          0.924
          0.929
          0.934
          0.949
          0.956
          0.972
          0.986
          1.001 2378-TCDD
          1.007
          1.011
          1.026
          1.037
          1.059
     0.921-1.079
         0.000
         0.947
         1.001 37C1-TCDD
         1.016
         1.021
         1.021  ~    	
                                                                                                       AN
CLS
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 10:16 01/10/98
                                                                                                                 47

-------
 \Page No.
  01/10/98
Listing  of U980026B.dbf
Matched  GC Peaks / Ratio / Ret. Time
  Compound/

  M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
  328
                       5 Peaks
                                           6,502.91
13C12-TCDD
332-334



332-334
PeCDF
. 340-342

0
340-342
13C12- PeCDF
352-354






352-354
PeCDD
356-358



D





356-358
13C12- PeCDD
368-370






•


DC





DC
DC
D


DC








DC
DC
DC
DC
D
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC

DC
DC
DC

NL



3

NL
SN
SN
0

NL






6

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL
SN
SN
SN
SN

SN
SN
SN

0:00
25:10
25:21
25:41
Peaks

0:00
26:37
27:46
Peaks

0:00
27:43
28:34
28:52
29:01
29:16
29:45
Peaks

0:00
27:46
28 : 20
28:26
28:34
28:53
29:09
29:37
29:57
30:07
Peaks

0:00
27:44
27:48
28:02
28:32
28:40
28:54
29:13
29:20
0
RO


RO
.65-0.89
2
0
0
1
.99
.82
.80
.03
15
12,991
7,420
248
.49
.13 5,864.48
.26 3,308.59
.58 145.33
0.921
0
7,126.65 0
4,111.67 1
140.44 1
-1.079
.000
.993 13C12-1234-TCDD
.000 13C12-2378-TCDD
.013


RSI
IS1

20,659.97
1
RO

RO

1.
RO
.32-1.78
0
1
1

.58
.34
.18

3
6
12
0
.80
.70
.08
.00
.32-1.78
1.21
1.62
1.48
RO
RO
1.03
1.16
1.55
RO

1.
RO
RO
RO
RO
RO
RO

RO
RO
RO

1.
RO

RO
RO
RO

RO
RO
RO
1.

79

32-1.78
4.
0.
1.
7.
1.
0.
1.
0.
2.
0.

32-
5.
1.
3.
4.
2:
1.
2.
1.
2.
15
18
13
00
26
93
54
38
57
49

1.78
09
75
68
67
63
67
10
30
19
1
355
6,703
124
.33
.95 219.85
.64 3,995.19
.42 75.63
38.17 23.20
6,444,
47.
.78 3,916.29
.40 33.25
0.925
0
0
0

-1.065
.000
.932
.972






0.860-1.140
0
136.10 0
2,708.45 1
73.17 1
20.01 1
2,528.49 1
18.59 1
.000
.970
.000 13C12- PeCDF 123
.011
.016
.025 13C12- PeCDF 234
.041


IS2


SUR1

13,714.36
: PeCDF / PeCDD Follows —
1.
3.
1.
0.
9.
1.
3.
2.
2.
1.
0.
02
01
86
43
69
55
60
32
75
43
00
0.935-1.022
0.
.000

0.938
0.957
0.960
0.965
0.
0.
1.
1.
1.

975
984
000 12378-PeCDD
Oil
017



AN



0.865-1.135
0.
2.
1.
1.
8.
14.
4.
1.
2.
89
20
28
94
70
16 8.85
00
84
70 • — -
0.
0.
0.
0.
0.
5.31 0.
0.
0.
0.
000
936
939
947
963
968
976
986
990









Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 10:16 01/10/98
                                                                                  48

-------
   Page No.      3
   01/10/98


   Compound/
   M_Z.... QC.Log Omit why
Listing  of U980026B.dbf
Matched  GC Peaks / Ratio / Het.  Tiae
.RT.  OK  Ratio Total.Area... Area.Peak.1. .  Area.Peak. 2. . Rel.RT Compound.Name..  ID.. Flags.
368-370
HxCDF
374-376


















374-376
13C12-HXCDF
384-386








384-386
HxCDD
390-392



29:37 1.48 3,875.54 2,311.28
29:44 1.59 596.05 366.33
29:55 1.65 33.82 21.04
30:00 1.43 35.75 21.06
30:07 RO 2.06 36.82 29.76
- 30:21 RO 1.30 9.51 5.78
30:25 RO 2.88 13.39 15.13
8 Peaks 4,615.04

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC


DC







DC
DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL


SN





7

NL
SN
SN
SN

0:00
31:05
31:17
31:19
32:04
32:07
32:15
32:19
32:26
32:36
32:50
32:58
33:02
33:09
33:18
33:24
33:39
33:43
33:53
Peaks

0:00
31:05
31:12
31:19
32:03
32:09
32:37
32:57
33:23
Peaks

0:00
31:52
31:57
32:14
1

RO
RO
RO


RO
RO

RO
RO

RO
RO
RO

RO
RO
RO

0.
RO
RO

RO



SO


1.
RO
RO
RO

.05
1
1
2
0
1
1
0
1
1
2
0
1
0
4
12
1
nuu vc . r^^-wu / njLi*ur ruj..Luws - -•
-1.43
.38
.01
.09
.86
.37
.17
.98
.52
.25
.14
.93
.33
.73
.35
.76
.10
1.53
5.73
1.

,70

3
2
5
1
8
5
2
2
1
5
0
1
0
1
0
3
1.
0
1.
0,
.93
• 82
.20
.82
• 29
.24
.15
.91
.73
.44
.98
.61
.96
.48
.38
.62
.75
.58
.34
,00
43-0.59
0.
0.
0.
0.
0.
0.
0.
0.
0.

05-
0.
0.
0.
1.
75
41
46
24
51
50
48
29
50
Above
1.43
67
78
94
24
5.35
33.
86.
2.
3,963.
5,720.
5,659.
66.
3,778.
78 . 11.41
40 27.11
61
06 1,343.56
12 1,900.96
83 1,845.34
50 22.46
14 1,261.42
1,564.26 1.000 13C12-PeCDD 123 IS3
229.72 1.004
12.78 1.010
14.69 1.013
14.44 1.017
4.44 1.025
5.25 1.027
0.962-1.047
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
.000
.967
.973
.974
.997 123478-HxCDF
.999 123678-HxCDF
.003
.005
.009
.014 234678-HxCDF
.021
.025
.027
.031
.036
.039 123789-HxCDF




AN
AN



AN





AN
1.047
1.049
1.054



0.876-1.124
0.000
28.11 0.
59.29 0.
0.
2,619.50 0.
3,819.16 1.
3,814.49 1.
77.17 1.
2,516.72 1.
967
970
974
997 13C12-HXCDF 478
000 13C12-HXCDF 678
015 13C12-HXCDF 234
025
038 13C12-HXCDF 789



SUR2
1S4
ALT 2

ALT1
19,307.83

2.
1.
0.
3.
31
45
83
04 ." "
0.958-1.014
0.
0.
0.
0.
000
971
974
982 	 "



	 _.
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola'Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 10:16 01/10/98
                                                                                 49

-------
   Page No.
   01/10/98
Listing of  tJ980026B.dbf
Matched GC  Peaks / Ratio / Ret. Tiae
  Compound/
  M_Z....  QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak.1. .. Area.Peak. 2. .  Rel.RT Compound.Name.. ID.. Flags.



390-392
13C12-HXCDD
402-404





402-404
HpCDF
408-410
DC SN 33
DC SN 33
DC SN 33
:03
:11
:30
RO
RO
RO
0
0
0
.54
.81
.37
0 Peaks

DC NL 0
32
32
32
33
33

:00
:14
:44
:49
:07
:32
1
RO
RO



RO
0
3
0
0
.52
.38
.76
.00
.05-1.43
1
1
1
1
1
3
5 Peaks

DC NL 0

:00
DC SN 35:03
0,
RO
RO
DC SN 35:16
DC SN 36:03

408-410
13C12-HpCDF'
418-420




418-420
HpCDD
424-426





424-426
DC SN 36:
:24
RO
RO
.47
.57
.22
.22
.20
.03

.88-1.20
77
.00
0.25
1.02
0.
1.
,65
.61
0 Peaks

DC NL 0 :
35:
36:
36:
37:

00
01
33
55
00
0.
RO


RO
RO
6
14
2,984
4,541
7,683
42
.63
.54 10.17
.31 1,638.26
.57 2,496.74
.47 4,188.38
.76 57.79
1
1
1

.007
.011 123789-HxCDD
.021


AN


0.970-1.030
0
6.49 0
1,346.05 0
2,044.83 1
3,495.09 1
19.09 1
.000
.982
.997 13C12-HXCDD 478
.000 13C12-HXCDD 678
.009 13C12-HXCDD 789
.022


SOR3
IS5
RS2

15,266.65
* HxCDD / HoCDP Fo Hows • •

0
.06
2.55
4 ,
1.
1.
0.
,02
,04
.80
00
37-0.51
0.
0.
0.
0.
0.
4 Peaks

DC NL 0:
DC SN 35:
DC SN 35:
DC SN 36:
DC SN 36 :
DC SN 36:

00
19
27
03
21
30
0.

RO
RO
RO
RO
RO
88-
1.
1.
0.
2.
1.
0.
82
43
44
35
70

1.20
00
28
80
16
97
27
0 Peaks
8.
3,153.
2,130.
27.
24.
02
18 ; 942.30
88 652.89
16 8.30
35 11.79
0.996-1.049
0
.000
1.001 1234678-HpCDF
1.
,007

AN

1.030
1.040



0.943-1.114
0.
2,210.88 1.
1,477.99 1.
23.43 1.
16.91 1.
000
000 13C12-HpCDF 678
044 13C12-HpCDF 789
054
057

IS6
SOE4


5,335.57
; HpCDF / HpCDD Follows * - •
0.
3.
2.
4.
0.
1.
0.
04
86
79
49
61
49
00
0.975-
0.
0.
0.
1.
1.
1.

1.005
000
980
983
000 1234678-HpCDD
008
012





AN



  13C12-HpCDD
  436-438
 436-438
DC



NL 0:00 RO
35:17 RO
36:03
2 Peaks
2.16
0.71
0.98

6.06
17.30
3,149.06
3,166.36
tr* • IJnS*TM1 / l~lf

8.82
1,557.61

                                                 0.972-1.028
                                                     0.000
                                              12.36   0.979
                                           1,591.45   1.000 13C12-HpCDD  678 IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 10:16 01/10/98
                                                                                        50

-------
  Page No.
  01/10/98
          Listing of  0980026B.dbf
          Matched GC  Peaks  /  Ratio /  Ret. Time
  Compound/
  M_Z....  QC.Log Omit Why ..RT.  OK Ratio  Total.Area.
  OCDF
  442-444
  442-444

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


HL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

0
34
34
35
35
36
36:
36:
37:
37:
37:
37:
37:
38:
38:
38:
38:
39:
39:
40:
40:
40:
40:

:00
:35
:50
:15
:43
:03
:13
:53
:10
:19
34
41
53
03
19
26
36
29
39
00
03
23
29
0.
RO

RO
RO
RO
RO

RO
RO

RO
RO
RO
RO
RO
RO
RO

RO
RO

RO
RO
76-1.02
1.
0.
0.
2.
0.
0.
0.
1.
3.
0.
0.
0.
1.
3.
0.
0.
0.
0.
0.
0.
0.
1.
0.
.75
85
73
87
07
55
87
36
24
78
34
35
20
10
73
37
27
91
58
39
91
41
57
Peaks
0
3
1
0
0
1
3
1.
0,
1.
2.
0.
2.
1.
2.
0.
1.
2.
4.
0.
0.
1.
1.
0.
.08
.41
.64
.87
.36
.78
.48
.80
.62
.35
.78
87
97
57
53
98
47
20
06
68
86
55
66
00
                                     Area.Peax.1.. Area.Peak.2. .  Rel.RT  Compound.Name..  ID..  Flags.

                                                              0.899-1.101
                                                                  0.000
                                                                  0.873
                                                                  0.880
                                                                  0.890
                                                                  0.902
                                                                  0.910
                                                                  0.915
                                                                  0.931
                                                                  0.939
                                                                  0.942
                                                                  0.949
                                                                  0.952
                                                                  0.957
                                                                  0.961
                                                                  0.968
                                                                  0.971
                                                                  0.975
                                                                  0.997
                                                                  1.001
                                                                  1.010
                                                                  1.011
                                                                  1.020
                                                                  1.022
  OCDD
  458-460

  1.58-460
               0.76-1.02
DC  NL   0:00     1.00          0.08
        39:37     0.76         17.82
      1 Peak                   17.82
                                                             7.72
                                                                             0.899-1.101
                                                                                 0.000
                                                                          10.10  1.000 OCDD
                                                                                                       AN
13C12-OCDD                     0.76-1.02
470-472         DC  NL   0:00     1.00           0.06
                        39:36     0.84       4,083.66
                        39:58     0.88          76.37
470-472               2  Peaks               4,160.03
                                          1,868.54
                                             35.66
                                                                               0.996-1.004
                                                                                   0.000
                                                                         2,215.12   1.000 13C12-OCDD
                                                                            40.71   1.009
                                                                                       IS8
 Column Description	  "Why" Code Description	   QC Log  Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO-Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report ***
                WL-Below Retention  Time  Window
                WH-Above Retention  Time  Window
                SN-Belov signal  to  Noise Level
                
-------
 Tile:0980026 #1-724 Acq: S-JZX-lSSa 17:15:57 SC £1+ Voltage SIS  70S Noises4632
 303.3016 T:2 BSOB(256, 30, -3.0) rXD(9,5,3, 0.10%, 18528.0,1.00\,f,T) Ezp:SDB5OS
 XSIAWSLE LABS  Taxt:tl±#44376m ILI BLANK
 1004
             23:00            23100            24:00             25:00
 f±le,0380026 H-724  Acqt 6-JZS-1998 17:15:57 SC KI+ Voltage SIS  70S Noise:4060
 305.3987 f:2 BSUB(256,30,-3.0) rXD(9,5,3, 0.10\,16240.0,1.00\,r,T) SxpiSDSSUS
 XSIANELS LASS   Tartstlif 44376m TLI BLANK
                                                          A3.45X5
                                                   A2.33X5
26100
   OEO
    Tia
             22:00             23:00            24:00            25:00
rile:U980026 tl-724 Acq:  S-JZJT-199B 17:15:57 SC SI+ Voltage 5X5 70S Xoiae:2B91
315.9419 T:2 SSUS(2S6,30,-3.0) PXD(9,5, 3, 0. 10\,11S64. 0,1. 00\,T,T) Ezp:SDS5US
TSXANSLS LASS  Taxt:tllt44376a fLI BLANK
1001

  aol
 40:

 201

  ol
26:00
-.0.0X0
    Tin



 8.8E6

.7.1X6

.5.3X6

.3.5X6

.1.8X6
             22:00        '     23:00             24:00            25:00
r±la:U9S0026 tl-724 Acq:  6-JAB-1998  17:15:57 SC XI+ Voltage SIS 70S Xoiao:3450
317.3389 T:2 BSUB(256r30f-3.0) fKD(9f5,3,0.10\,13800.0,1.00\,T,T) Kxp:SDB5US
TBIANGLE LABS  TBJCt:tlJ.t44376m TLI BLANK
1003.                                                      AS. 93X7

 80.

 sol

 401

 ao:
                                                                                   26:00
                  .0.0X0
                      Time
  o:
                 -1.2E7

                  .9.4X6

                  •-7.1S6

                  .4.7X6

                  .2.4X6
             22:00             23:00             24:00            25:00
Tile:U980026 tl-724 Acq:  6-JZS-1998 17:15:57 SC XI+ Voltage SIS 70S
330.9792 T:2 Xip:NDB5VS
TSIANSLX LABS  Text:tli«44376a TLI BLANK
1004         21:58        22:43       23:27            24:26    24:55   25:25
                                                                                  26:00
                   0.0X0
                      Time
 50

 40.

 201
                  .9.8X7

                  7.9X7

                  5.9X7

                  .3.9X7

                  2.0X7
             22:00             23:00             24:00            25:00
Tile:C980026 tl-724 Acq:  6-JZX-1S98 17:15:57 SC XI+ Voltage 5X2 70S
375.8364 F:2 SzptXDBSUS
TBIANGLZ LABS  Tetxtttl±f44376u TLI BLANK
                                                                                  26:00
                                                                                                     0.0X0
                                                                                                        Time
             22:00
                              23:00
                                                24:00
                                                                 35.00
                                                                                  26:00

-------
r±le:U980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC EI+ Voltage SIS 70S Noi.aetl013
319.8965 T:2 BSUB(256, 30, -3.0) PED(7 ,5,3,0 .10\,40S3. 0,1. 00\,T,T) SxpiNDBSUS
TRIANGLE LABS Taxt:tllt44376m TLI BLABS
100}
80.
60.
40.
20.
0




4i

At. 33X4


,j
N
23



A3.40E4 J|j|
A3.52X4\
AH.AA-1
fWJ

•00 ' ' .
j*.oi*3 ^.^i;
W^vM

' 24 tOO '
ll ..1 1 L
Wv



-1.8X4

A3. 96X4
Al . 78X4 1
A lt/1 1 Jl
Awv

35*00
1.46X4 A9.53X3 1
JLM ill (1 V\ i
y^MwAf

' 26:00 	
.1 . 4X4
.1.1X4
.7.2X3
.3.6X3
0.0X0
Tlae
rlle:U980026 tl-724 Acq; 6-JZB-1998 17:15:57 GC XZ+ Voltage SIS 70S Boiae:971 N . * •*
321.8936 r:2 BSOB(256, 30, -3.0) PXD(7,5r3,0.10\,3884.0,1.00\,r,T) XxptBDBSUS ^ r"l£>yfc\> '
TSIANGLX LABS Teit:tlit44376a TLI BLABS l5") L
1004 A9.43X4 . fti— ^3.0X4
80.
60.
40.
0



•jjw






k ILAMA/U*
23\00


A1.21X4
A2.4jX4\ (
ta/VW'AJlJW
24(:00


A2.74X4t |
\A/vLr«yk



A3. 4 6X4
WvJV'VV^


Mi
1
25iOO '
^*L'?^

A3. 37X4 A4.38X4 1
VTM/^HM A n/ ^vi/n M/v
.2.4X4
Ll . 8X4
'•.1.2X4

36': 00 ' ' ' Time
rlle:U980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC XI+ Voltage SIS 70S Soiae:13099
331.9368 T:2 BSUB(256, 30, -3.0) PSD(7,5,3,0.10\,52396.0,1.00*,r,T) Xxp:NDB5US
TRIANGLE LABS Taxt:tlit44376a XLI BLABS
1001
80-
60:
40:
20:
o-















' 23:00'





' 24:00 '






AS.B6X7
ft
L, m
A
)l/v
25:00
_1 . 5X7




'26:00 	
.1.2X7
.9 . 1X6
-.6.0X6
.3 . 0X6
'• o . oxo
Time
f±le:U980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC XH- Voltage SIS 70S Wo±ae:4374
333.9338 T>2 BSVB(2S6,30,-3.0) PSD(7,5,3,0.10\r17496.0r1.00\rT,T) Xzp:SDB5US
TRIANGLE LABS Tejct:tlit44376a TLI BLABS
100J
80:
60:
40:
20:















23:00 '





24\00






A7.13E7
\
1 \L4.11X7
\ A
ll/l
25 1 00
1 . 9X7




'26:00 	
.1 . 5X7
.1.1X7
.7.4X6
-3 . 7X6
0.0X0
T±me
rlla:0980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC XH- Voltage SIS 70S Soiae:996
327.8847 T:2 BSVB(256, 30, -3. 0) rSD(7,S,3f 0.10%,3984 .0,1 . 00\rr,T) Xxp:NDB5US
TRIANGLE LABS TeJCt:tlJLt44376a TLI BLABS
1001
80:
60:
40:
20:
0:















23 tOO





24:00






A6..



i
6X7



\
25: 00





'26:00
.1.5X7
.1.2X7
.9.0X6
.6.0X6
.3 . 0X6
0.0X0
Time
rlla:O980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC EH- Voltage SIS 70S
330.9792 Ti2 XxptKDBSVS
TSIANGLX LABS Text:tULt44376m TLI BLABS
1001
so:
60:
40:
20:
o:
_ 22:57 33:27 33,49 24:1124:26












33\00




24:00





24:55 25:25




25:00
26jJ>4 26:35




'26:00 	
.9.8X7
.7.9X7
.5.9X7
.3.9X7
.2.0X7
0.0X0
Time
53

-------
 rila:U980026  tl-724  Acq:  6-JXS-1998 17ti5tS7 GC XH- Voltage SIX 70S Soia*:1156
 339.8597 T:2  3303(256,30, -3.0) ?Kn(7,5,J,0.10\,4624.0,1.00\,r,T) SrptHDBSVS
 TXIASGLX LASS  Tmxt:tU.t44376* TLI BLAST
 100*                           A7.34X4             A9.84X4
  ao:
  eo:
  40:
  20:
   oj
                                                                A6.64E4
     A3.84X4
                                                                                            A1.31X4
              27i00                  28*00                 29:00
Tila,0930026 tl-724 Acq: 6-JAS-1998 17:15:57 GC XH- Voltage SIS 705 Noiae:2006
341.8567 r:2 3SUS(256,30, -3.0) PTB(7,5,3,0.10\,8024.0,1.00\,r,T)
TSIASSLX LABS  Text:tU.t44376m TLI BLAST
i00*                                                    AS.66X4
 flflH                          A6.22X4                      '
 80-          A2.231
 SO.

 40:
 20:
  o:
                                                                                 30,00
                                                                                            A .OtX
               27:00
m.ai0980026 tl-724 Acq:  S-JAK-
351.9000 T:2 3SU3(256,30, -3.0)
XBIANGLZ LASS  TOJCt.:tJJ.t44376a
1001
  80:
  sol
  40:
  20:
  o:
                                     28:00                 29100
                               1998  17:15:57 GC EI+ Voltage 512  705 Noiaei40S
                               PXD(7,5,3,0.10\,1620.0,l.QO\,r,T) SxpsNDBSUS
                               TLI BLAOK
                                                A4.00S7
                                                                                 301 00
              27:00
rila:O980026 tl-724 Acq:  6-JUt-
353.8970 T:2 3SUB(256,30,-3.0)
TSIANGLE LABS  Text:tli*44376a
1001
                                     28:00                29:00
                               •1998  17:15:57  GC EI+  Voltage SIS 70S Noise1335
                               PKD(7,5t3,0.10\,1340.0,1.00\rr,T) Elp-.NDBSUS
                               TLI BLASX
                                                                                 30:00
  OJ
              27:00
rileiU980026 tl-724 Acq: S-JKH-
409.7974 r:2 ZxptBDBSUS-
TSIASSLE LABS  Text:t-LL»44376a
1001 ,
                                    .28:00                 29:00
                               1998 17:15:57 GC EH- Voltage SIS 70S

                               TT.T
                                                                                 30:00
-2.0X4

'.1. 6X4

.1.2X4

.8.1X3

.4.0X3

 0.0X0
 .2.1X4

 .1. 7X4

 ,1.3X4

 .9.5X3

 .4.2X3

 .0.0X0
    Tim.



 .1.1X7

 8.5X6

 6.4X6

 4.2E6

 2.1X6

 0.0X0
    Time
1 1
L
27't 00 28:00 29:00 30:00
IU98Q02S tl-724 Acq: 6-JXK-1998 17:15:57 GC.XH- Voltage SIS 70S
9792 T:2 XzpiXDBSVS
[OGLE LABS Text:tl±t44376a TLI BLAST
26:35 27:02 27:3827:53 28:12 38i42 29:16 _ 29:52 30^19

                                                                                                     6.9X6

                                                                                                    is.5X6

                                                                                                    .4.2X6

                                                                                                    .2.8X6

                                                                                                    .1. 4X6

                                                                                                     0.0X0
                                                                                                        Time



                                                                                                     9.9X7

                                                                                                     7.9X7

                                                                                                     6.0X7

                                                                                                     4.0X7

                                                                                                     2.0X7

                                                                                                     0.0X0
                                                                                                        Time
              27:00
                                     28100
                                                           29100
                                                                                 30100
                                                                                                            54

-------
fHa:US80036  tl-724  Acq: 6-J&K-1998 17:15:57 SC SI* Voltage SIS  70S JfOiaei 831
355.8546 f:2  BSVB(256,30, -3.0) PXD(S,5,3,O.OS\r3324.0,1.00\,T,T)  XxptHOBSUS
TSIAKSLE LABS  Text,tlit44376a TLI BLAHX
1004                                                                A2.61E4
                                                                                               -2.7S4
      27:48 28,00  28', 12 28:24 28,36  28,48  29,00  29,12  29:24  29:36
rU.»:U980026 tl-724 Acq,  6-JAN-1998 17,15,57 SC XI* Voltage SIS 70S So±ae,201
357.8516 r,2 BSU3(256,30, -3.0) PXD(5,5,3,0.05\,804.0,1.00\,r,T) XzptSDBSUS
TSIASGLX LABS  Text:tU.t44376a TLI BLAST
1001A1  2E5
  80.

  60.

  40.

  20.
                                                                                       3024
                                                            A3.72E4
                                                                 VyvJ^jwk^
-2.8X4

.2.3X4

.1.7X4

.1.1X4

-5.7E3
                                                                                                .0.0X0
      27:48 28,00  28:12 28:24 28:36  28:48  29:00  29,12  29,24  29,36 29:48 30:00  30:12 30:24       Time
r±le:U980026 tl-724 Acq:  6-J7OT-1998 17:15:57 SC XI* Voltage SIS 70S Soiae:889
367.8949 T:2 BSUB(256,30, -3. 0)  PU>(5,5,3,0.05\,3556.0,1.00\,T,T) XxptHDBSUS
TSIAKSLE LABS  TB5US
TBIANGLE LABS  Toxtttl±t44376a TLI BLAHX
1001                                                         A1.56E7

 80.

 60.

 40.

 20:

  o:
                                                                   .30E6
                  28,12  28,24 28:36 28:48 29,00 29,12 29,24 29,36 29:48 30,00 30:12  30,24
r±le,U980026 tl-724 Acqt 6-JAH-1998 17,15,57 SC XI* Voltage SIS 70S
330.9792 r,2 XxpiJWBSUS
TSIAHSLX LABS  TeitttU.t44376a  TLI BLAST
                                                                                                5.3X6

                                                                                               .4.0X6

                                                                                               .2. 7X6

                                                                                                1.3E6
                                                                                                0.0X0
                                                                                                   life
OOJ
80.
60.
40.
20.
0

27,53 2BsLa — .^jyjf 38:54 29:0529,16 ^_ 29:52 30±19





27:48 28,00 28\12 28', 24 2S\36 2a',48 29:00 '29:12 29', 24 29\ 36 ' 29,48 ' 3o', o6' jfliiJ ' 30:24 "
.4.4X6

.3.5X6

.2.6X6

.1.8X6

.8.8X5

 0.0X0
    Time



9.9X7

 7.9X7

 6.0X7

4.0X7

2.0X7

 0.0X0
    Time
                                                                                                             c r
                                                                                                             o J

-------
 rila:U980026 tl-384 Acqi 6-JXN-1998 17:15:57 SC EI+ Voltage SIS 70S Noiaatll39
 373.8208 T:3 BSOB(256,30,-3.0) ?XD(7,S,3,0.10\,45S6.Q,1.00\,rrT)  ExpsSDBSOS
 TSIAHSLX LABS  Tmxt:tU.t44376* TLI BLANK
                                                                                                        0X0
     31tOO 31:12  31i24  31t36 31t48  32tOO  32:12 32:24 32i36  32't4a' 33:66 33:12' 33V24' jji 36 33: 48
 rlla:U980026 H-384 Acq: 6-J3UT-1998 17tl5tS7 GC EI+ Voltage  SIS  70S Nolae:B24
 375.8178 f:3 BSOB(256,30, -3.0) PXD(7,5,3,0.10\,3296.0,1.00\,r,T) SxptODBSUS
 TSIASSUS LABS  Text:tlit44376a TLI BLANK
                                         0X4                                                         .1.5X4
                                                                                                         T±ae
     31iOO 31:12 31:24  31:36 31:48 32:00  32:12 32:24 32:36 32:48  33:66' 33:12'33i24'33:36 33:48
ttJ.e:U9S0026 tl-384 Acqi 6-J7OT-1998 17:15:57 GC ZI+ Voltage SIX 70S Noises 1336
383.8639  T:3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,S344.0,1.00\,T,T) Xip:tlDB5US
TRIANGLZ  LABS  Tejctitlit44376a XLI BLANK
 1001

  00:

  601

  40.

  201
                                       A1.90E7
                                                       A1.BSE7
                                                                              A1.26E7
                                                                                                        Tiffl
-4.3E6

.3. 9E6

.3.0X6

.2.0X6

-.9.8E5
     31:00  31:12 31:24  31:36 31:48 32:00 32:12  32:24  32:36 32:48 33:00  33:12 33:24  33:36 33:48
rile:US80026  tl-384 Acq:  6-J3UT-1998 17:15:57 GC KH- Voltage SIS 70S Noise: 1769
385.8610 r:3  BSOB(256,30,-3.0)  PXD(7,5,3,0.10*r7076~.0,1.00\,r,X) Kxp:KDB5US
T&IANSLZ LABS  Text:tld.t44376a  TLI BLANK
                                                                                                     .0.0X0
                                                                                                        Time
                                       A3.82E7
1001

 80:
  40.

  20:

  ol
    31:00  31:12 31:24 31:36  31:48 32:00 32:12 32:24  32:36 32:48 33:00  33:12 33:24 33:36  33:48
rlla:V980Q26 tl-384 Acq:  6-J7UT-1998 17:15:57 GC XH- Voltage SIX 70S
392.9760 T:3 Erp:NDB5US
TRIANGLE LABS   Text:tl±f44376a  TLI BLASX
               31:20   _      ,-**-£--. J?l™     I?-'-3 33^35  3*'*  33i01 _ 33'-4-    33:42
 SO

 50J

 40:

 201
                                                                                                     4.5E7

                                                                                                    •.3.6X7

                                                                                                    '•.2.7X7

                                                                                                    -.1.8X7

                                                                                                    '.9.0X6
    31:00  31:12 31:24 31:36  31:48  32:00 32:12 32:24 32:36  32:48 33:00 33:12  33:24 33:36 33:48
rile:0980026 tl-384 Acq:  6-JXK-1998 17:15:57 GC XH- Voltage  SIS 70S
 45.7555" f:3 Eip:NDB5US
TRIANGLE LABS  Textttlit44376a  TLI  BLANK
1001                                                                               33 30
                                                                                                    ".0.0X0
                                                                                                        Time
    31:00 31:12  31:24 31:36 31:48  32:00 32:12 32:24 32:36  32:48 33:00 33:12  33:24 33:36 33:48

-------
         31:36    31:48   32:00    32:12    32:24    32:36   32:48   33:00    33:12
r±le:0980026 tl-384 Acq:  S-JMr-1998 17:15:57 GC XH- Voltage SIX 70S Noiao:2181
401.8558 T:3 BSUB(256,30, -3.0) ?KD(7,5,3,0.10\,8724.0,1.00\,r,T) Xxp:XDB5US
TSIANSLE LABS  T&zt:tJJ.t44376a TLI BLANK
1001                                                                    A4.19E7
 rila:u980026  tl-384 Acq: o-uJUi-iyyU J./:±3:3/  GC Sir  Voltage SLM 70S lfoj.a»:oJS
 389.8156 T:3  BSUB(256,30, -3. 0) fXD(7,5,3,0.10%,2S52.0,1.00\,r,T) Xrp:SDB5US
 TSIASSLX LABS  Toxt:tlit44376a TLI BLANK
 1001                                               AS. 20X4
         31:36    31:48   32:00    32:12   32:24    32:36    32:48    33:00   33:12
File,0980026 fl-384 Acq: 6-JAN-1998 17:15:57 GC XX + Vbltage SIS 70S No±ae:954
391.8127 r:3 BSUB(256,30, -3.0) PXD(7,S,3,0.10\,3816.0,1.00\,r,X)  Xrp:HDB5US
TBIAXOLX LABS  T*xt:tlit44376a TLI BLANK
                                                                                     33124
                                                                               .0.0X0
                                                                            33 36  Tim.
                                                                                     33s 24
  80.

  60.

  40.

  20.
                                         A2.50X7
         31:36    31:48   32:00    32:12   32:24    32:36    32:48   33:00    33:12
rile:O980026 tl-384 Acq:  6-JAN-1998 17:15:57 GC XH- Voltage SIS 703 Noiae:1479
403.8529 T:3 BSV3(256,30,-3.0)  fKD(7,S,3,0.10\,S916.0,l.QO\,T,T) XzptNDBSUS
TBIANGLX LABS  Teit:tl±t44376a  TLI BLANK
1004                                                                    A3.50X7
 80.


 60.


 40.


 20.


  0.
                                                                                     33:24
         31:36    31:48   32:00    32:12   32:24    32:36    32:48    33:00
rllet0980026 tl-384 Acqt  6-J7UT-1998 17:15:57 GC XH- Voltage SIS 70S
392.9760 r:3 KipiNDBSUS
TRIANGLE LASS  TertltHi44376a  TLI BLANK
                                                          33:12
100S,
 80.

 eo:

 40.

 20.

  0.
31:48
           32:04
                                           32:23
                                                           32:48
                                                   33:01
                                                                                     33:24
                                                                                     33:24
                                                                            33 36
                                                                               0.0X0
                                                                                  Tin.
                                                                                              33  36
                                                                              .0.0X0
                                                                              36  Time
                                                                                                 4.5X7

                                                                                                .3.6X7

                                                                                                .2.7X7

                                                                                                .1.8X7

                                                                                                '.9.0X6
         31:36
                  31:48
                          32:00
                                   32:12   32:24   32:36   32:48
                                                                    33:00
                                                                              .0.0X0
                                                          33:12    33:24   33 36  Tiae

-------
\Til*tO960026 #1-545 Acqt 6-JKH-1998 17,15,57 SC EI+ Voltage 5X2 705 Noiaa:1156
407.7818 f:4 3503(256,30, -3.0) PKD(7,S,3, 0.10\,4624.0,1.00\,rfT) XiptSDBSOS
TBIANGLZ LASS  Text:tlJ.*44376a TLI BLANK
IOCS
         35,00    35il2    35:24    35:36    35,48    36,00    36,12    36,24    36,36
rU»:O980026 91-545 Acqi  6-J7Ur-1998 17,15,57 SC XH- Voltage SIX 70S flbi*«>15
409.7789 T:4 3SU3(256,30,-3.0) Pja>(7,5,3,0.10\,64.0,1.00\rrrl)  SxptUDBSOS
XBIASGLX LABS   Text:tl±t44376a TLI 3LAOX
         36,48
                  37 tOO
                                                                                                        Urn
        35,00    35,12    35:24    35,36   35:48    36:00   36:12    36:24    36:36
rile,0980026 fl-545 Aaj:  6-JZS-1998 17:15:57 SC XH- Vtoltagra SIX  705 Hoiae,2276
417.8253 T:4 BSOB(256,30,-3.0)  PXD(7,5,3,0.101,9104.0,1.00*,f,T) Xxp:SDB5US
T&IANGLZ LABS  Taxt:tU.t44376a  TLI BLANK
1004    A9.42E6
                                                                          A6.53E6
         36:48
                  37:00
                         .0X0
                           Tlae
        35:00    35,12    35:24   35:36    35:48    36:00   36:12    36:24   36:36
rHe:0980026 tl-545 Acq,  6-JAS-1998  17:15:57 GC XI+ Voltage SIS  70S Noise,27B6
419.8220 F,4 BSVB(256,30,-3.0) PXD(7,5,3, 0.101,11144.0,1.OQ\,r,T) Kxp:lWB5US
TXIAKSLX LABS  Xextstl±t44376a TLI BLAST
100%    A2.21X7
                                                                          A1.4SE7
                                                                                      36:48
                                                                                               37:00
                                                                                                      .0X0
                                                                                                        Tiae
        35:00    35,12    35,24    35:36    35,48    36:00    36,12    36:24
r±lo,U980026 tl-545 Acq:  6-JAK-1998 17:15:57 GC XI+ Voltage SIS 70S
430.9729 Tit XxptXDBSUS
TRIANGLE LABS  Taxt:tli#44376» TLI BLANK
1004,              35,14      35JL?8      35:42        36,01        36,20 36,27
 50:

 40:
  OJ
                                                                             36:36
                                                                               36,38
                                                                                      36:48
                                                                                               37:00
        35,00    35:12    35:24    35:36    35:48    36:00    36:12    36,24
Tila,0380026 tl-545 Acq:  6-JJOT-1998 17:15:57 GC XH- Voltaga SIB 705
479.7165 T:4 ExptNDBSUS           ......
TSIAHGLX LABS  Text:tlJLt44376f TLI BLANK
1004
36,36
         36:48
                                                                                               37:00
                         ,2X7

                         ,6X7

                         ,9X7

                         .3X7

                         4X6

                         0X0
                           Time
        35,00
                 35,12
                         35:24
                                  35,36
                                           35:49
                                                   36:00
                                                            36:12
                                                                    36:24
                                                                             36,36
                                                                                      36:48
                                                                                               37,00
                                                                                                             58

-------
ru.aiU3ao026  il-545 Acqi o-JAa-lyyo  i/siiiaJ SC Sir voJitfyf SIM 70S Noj.amiJ.0
423.7766 T:4  8303(356,30, -3. 0) PXD(7,S,3, 0.10\,40.0,1. 00\,f,T) Kxp:SDB5OS
TSIAKSLX LABS  Text.-tl±*44376* TLI BLANK
1004
                                                             A4.76X4
  80.
      35:12  35:18 35:24  35:30  35:36 35t42  35:48 35:54  36:00  36t06 36:12  36:18  36:24 36:30
r±l»:a980026 H-545 Actj: 6-J3UT-1998 17:15:57 SC XI+ Voltage SIX 70S So±aeil2
425.7737 T:4 3SVB(2S6,30,-3.0) tJO)(7,5,3,0.10\r48.0,1.00\,T,I)  XxpiSDBSUS
TB.IAXGLX LASS  Text:tlll44376* TLI BLAXX
 1001
    Time
                                                                                                  O.OEO
      35,12  35:18 35:24  35:30 35:36 35:42  35:48 35:54 36:00  36:06 36:12  36:18 36:24  36:30
rlle,V980026 41-545 Acq:  6-JKH-1998  17:15:57 SC EH- Voltage SIS 70S Ho±ae:3204
435.8169 T:4  BSOB(256,30,-3.0) PXD(7,5,3,0.10\,12816.0,1.00*,r,X) EzptXDBSUS
TRIANGLE LABS Tej[titli*44376a TLI SLANT
1004                                                        A1.5.6X7


 80.

 60.

 40.

 20.



    "~35:12' 35:18 35:24  35:30 35:36 35:42  35:48 35:54 36:00  36:06 36:12  36:18 36:24  36:30
rlla:a9B0026  tl-545 Acq:  6-JAN-1998  17:15:57 SC EI+ Voltage SIS 70S Hoiaetl484
437.8140 T:4  BSUB(256,30, -3. 0) PKD(7, 5,3, 0.10\,5936. 0,1. 00\,T, T) XxpsSDBSUS
TRIANGLE LABS Text: tlif 44376* TLI BLANK
100J>                                                        A1.59K7


 80.

 60.


 40.

 20.
                                                                                                     Tiae
      35:12 35:18  35:24  35:30 35:36  35:42  35:48  35:54 36:00  36:06 36:12  36:18 36:24  36:30
r±le»0980026 tl-545 Acq:  6-JXK-1998 17:15:57 SC EH- Voltage SIX 70S
430.9729 T:4 ExptNVBSUS
TRIANGLE LABS  Text: tl±f 44376* TLI BLANK
1004    35jl4	    _  35j^a	35_^42  ^SjJ9	^   jf^^1   36:08           -

 80.

 50.


 40.

 20:
      35:12 35:18  35:24 35:30 35:36  35:42 35:48  35:54 36:00  36t06  36:12 36:1836:24  36:30
.3.1Z7

.2.SE7

.1.9E7

1.3E7

6.316

,0.0X0
   Tiae

-------
Til*:O980026  tl-545 Acq:o^JAN-1998 17:15:57 GC EI+ Voltage SIS 70S NoiaetjS
441.7438 r:4  BSUB(256,30, -3.0) rKD(7,S,3,0.10\,144.0t1.00\,T,T)
TRIANGLE LABS  Text:tlit44376* TLI BLANK
loot
 aoj
 flflj
 70.
 60;
                                                 A1.31Z4
                                                        A3.57X4
 401
                                                                                 A3.87X4
               35:00         36:00         37:00        38:00         39:00
file:0980026 tl-545 Acq:  6-JAW-1998  17:15:57 GC XH- Voltage SIS 70S Soiaet21
443.7399 Tt4 BSUB(256,30, -3. 0) PXS(7,5,3,0.10\, 84.0,1.00\,r,T)  XxptHDBSUS
TSIANGLX LABS  Tezt:tlit44376a TLI BLANK
J 001
 903
                                                                                    40,00
                                                                                                    -1.5X4
                                                                                                     .1.4X4
                                                                                                     .1.3X4
                                                                                                     .1.1X4
                                                                                                     .9.3X3
                                                                                                     .7.6X3
                                                                                                     .6.1X3
                                                                                                     .4.6X3
                                                                                                     .3.1X3
                                                                                                     11.5X3
                                                                                                     .0.0X0
                                                                                                  41  00 Tia
               35:00         36:00         37:00        38:00         39:00
Til»tU980026 tl-545 Acq,  6-JAN-199S  17:15:57 GC XH- Voltage SIR 70S
430.9729 T:4 Xlp:SDB5US
TSIANGLX LABS  Text:tllt44376* TLI BLANK
"°*  34,30 34,47     35i"         ">»   "'^
     J^^^ill^^^^^
 80.
 so
 20-
 JOJ
  0.
                                                                                    40:00
               35,00         36:00         37:00        38:00         39:00
 •ila,U980026 tl-545 Acq:  6-JXK-1998  17:15:57 GC XI+ Voltage SIX 70S
 •13.6775 F,4 ExpiNDBSUS
TSIANGLX LABS  Text:tlit44376a  TLI BLANK
100,
 90^
                                               37:19
                                                                                    40:00
                                                                                                 41:00
                                                                                                     3.2X7
                                                                                                    13.9X7
                                                                                                    '.3.6E7
                                                                                                    12.3X7
                                                                                                    '•.1.9E7
                                                                                                    ll. 6X7
                                                                                                    -.1.3X7
                                                                                                    19.7X6
                                                                                                    -.6.5X6
                                                                                                    .3.2X6
                                                                                                    lo.oxo
                                                                                                 41:00  Tine
               35,00
                             36:00
                                          37:00
                                                        38:00
                                                                      39:00
                                                                                   40:00
                                                                                                    .0.0X0
                                                                                                 41:00  Time
                                                                                                            60

-------
                              73X4
ri-La:O9U001& tl-545 Acq:  6-JAn-lSSa  -l/i-iSO/ SC SI+ voltage SIM 70S lioiae
457.7377 r-.4 BSOB(356,30,-3.0)  PXO(7,5,3, 0.iO\, 84. 0,1.00\,T,T) SxptHDBSUS
TRIANGLE LASS  TfJCt:tLH44376t  TLI BLASK
100*                      A7.J
  80.

  so:

  40.

  30.
                                                                   A9.76X3
                                                                                   AA7
           39:30         39:36         39t43         39:48         39:54
TileiO9BOO26 11-545 Acq: 6-JMT-1998 17il5i57 SC XI+ Voltage SIS 703 Noise:20
459.7348  Ti4 B3VB(356,30f-3.0) PXD(7,5,3,0.10\,80.0,1.00\,r,T)  XxptSDBSVS
TRIANGLE  LABS  TaxtitLH44376m TLI BLAST
1004                            A1.01X5
                                                                                40:00
_1. 4X4

.1.1X4

.8.3X3

.5.6X3

'.3.8X3

'.0.0X0
                                                                                              40 06  Tine
                                                                                                -3.1X4
           39:30         39:36         39:43         39:48        39:54
rila: 0980026  tl-545 Acqs  6 -JAN- 1993 17:15:57 SC EH- Voltage SIS  70S Noise -.16
469.7779 t:4  BSnS(356, 30, -3.0)  PKD(7,5,3, 0.10%, 64. 0,1. 00\,r, T) Kxp:ltoB5US
TSIANSLX LABS  Text: tli*44376*  TLI BLANK
                                                                               40:00
1003,

  80.

  60.

  40.

  30.
                         Al.
           39', 30         39:36         39:43        39:48         39': 54
rllatO980036  tl-545 Acq:  6-JX1T-1998 17:15:57 SC XI+ Voltage SIR 70S Noiae:13
471.7750 r:4  BSUB(356,30,-3.0)  fXD(7,S, 3, 0 .10\, 53.0,1. 00\,r,T) Xxp:NDB5US
TBIANSLX LABS  Taxt:tlit44376t  TLI BLANK
1001                    A3. 33X7


 80.

 SO.

 40.

 30.


  OJ
           39\30      '   39:36         39:43        39:48         39i54
T±lai0980036  H-545 Acq:  6-JAN-1993 17:15:57 SC EH- Volt aye 3IS 70S
430.9739 f:4  Eip:NVB5US
TSIASSLX LABS  Text:tlit44376a  TLI BLARX
1001 _ ____ . ____ 24*45 ______ -^ ___   _39j54

 80.

 60.

 40.

 30.

  0.
                                                                               40:00
                                                                                              40:06  Time
                                                                                                -3.9X6

                                                                                                .3.3X6

                                                                                                .1. 7X6

                                                                                                .1.3X6

                                                                                                .5.8X5

                                                                                                .0.1
                                                                                             40:06
                                                                               40:00
                                                                                                .0.0X0
                                                                                             40 06  Tiae
           39:30
                         39:36
                                      39:43
                                                    39:48
                                                                  39:54
                                                                                                 0.0X0
                                                                                40:00
                                                                                             40 06  Tiae

-------
                                                                                   CJ
                                                                                   CO
Peak Locate Examination: 6-JAN-1998:17:12 File:U980026
      Experiment:NDB5US Function:2 Reference:PFK

-------
TLI Project      44376A
Client Sample:   TLI M23 Blank
           Method 23 TCDD/TCDF Analysis (DB-225)
                                Analysis File:   P980094
Client Project
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight
GC Column:
Gulp Aluminum Alloys
XAD
TLI Blank

1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
/ /
12/29/97
01/06/98
n/a
P980094
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
                                                                           FTT   \FJa$5
2J.7.8-TCDF
                              0.02
                                    0.65
                     23:06
                                                                 ftatfo"
                                             RT
                                                                                 Flags
l3Cu-2,3,7,8-TCDF
15
                                            63.6
40%-130%
0.76
23:05
 Rfecoyery Stancterd
                                   Ratio
                                                                          RT
                             Flags
                                                                  0.82
                                            21:55
                      Data Reviewer.
                                         PA/V
                               01/09/98
                                        Page 1 of 1
                                             C2NF.PSR .2.01. LARS 6. IO.UXI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                         Printed: 10:14 01/ft9/88
                                                      bo

-------
                          Initial    	Date...
  Data Review By:
                      Calculated  Noise Area:
                                              1.00
  The Total Area for each peak  with an ion abundance ratio outside
  ratio liaita haa been  recalculated according to method requirements.
  Page No.     1
  01/07/98
Listing of P980094B.dbf
Hatched GC Peak* / Ratio  / Ret. Tiae
  Compound/
  M_Z	QC.Log  Omit Why  ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags
  TCDF
  304-306
  304-306

  13C12-TCDF
  316-318
  316-318
  13C12-TCDD
  332-334

DC
DC
DC
DC

DC

DC
DC

XL 0
SN 18
SN 20
SN 21
21
SN 21
23
SN 25
WH 25

:00
:42
:40
:16
:37
:46
:06
:17
:40
0
RO

RO
RO

RO

RO
RO
.65-0.89
0
0
0
0
0
1
0
.91
.88
.53
.26
.83
.32
.65
0.37
0.52
2 Peaks

DC
DC
DC
DC


DC

ML 0
WL 21
WL 21;
WL 21:
23:
23:

:00
:08
:36
:51
:05
:42
WH 25:10
0.
RO
RO


65-0.89
1.04
0.49
0
0.
.80
.81
0.76
0.74
RO
0.99
2 Peaks

DC





DC
DC
DC

NL 0:
20:
21:
21:
22:
23:
WH 24:
WH 24:
WH 24:

00
30
37
55
41
14
10
27
47
0.
RO
RO



RO
RO
RO
RO
65-0.89
1.
0.
0.
0.
0.
2.
0.
0.
1.
82
47
79
82
77
15
52
52
56
                      1.61
                      0.96
                      0.69
                      0.39
                      7.82          3.54
                      0.44
                      9.74          3.85
                      0.76
                      1.10
                     17.56
                      2.09
                      3.08
                     13.44
                     42.85
                  1,564.48        674.65
                      5.77          2.45
                     18.67
                  1,570.25

             Above:  TCDF / TCDD Follows -
 332-334
                       5  Peaks
                      1.38
                      3.61
                  1,110.48
                  1,771.78
                     15.06
                      2.28
                      3.10
                      6.53
                      0.97
                  2,903.21
                                                              1.57
                                                            490.07
                                                            796.54
                                                              6.55
                                                              2.77
     0.792-1.101
        0.000
        0.810
        0.895
        0.921
  4.28  0.936
        0.943
  5.89  1.001 2378-TCDF       AN
        1.095
        1.112
    0.957-1.043
        0.000
        0.916
        0.936
        0.947
889.83  1.000 13C12-2378-TCDF ISO
  3.32  1.027
        1.090
    0.908-1.092
        0.000
  3.37  0.948
620.41  1.000 13C12-2378-TCDD  IS1
975.24  1.014 13C12-1234-TCDD  RSI
  8.51  1.049
  1.29  1.075
        1.118
        1.131
        1.146
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 01:14 01/07/98
                                                                                      64

-------
  Page No.     2           Listing of P980094B.dbf
  01/07/98                 Matched GC Peaks / Ratio / Rat. Ti»e

  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
 Column Description	   'Why'  Code Description	   QC Log Desc.
 M_2   -Nominal Ion Mass(es)      WL-Below  Retention Time Window   A-Peak Added
  ..RT. -Retention Time (mm:as)    WH-Above  Retention Tine Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions       SN-Below  Signal to Noise Level   D-Peak Deleted
 OK    -RO-Ratio Outside  Limits   
-------
ru.*iP9aoos4 91-932 Acq:o-jAn-ya 23:*y.m EI+ voJ-taga six /OP
303.9016 Sxp:DB335
XRIJOtSLX LASS TazttZCX M23 BLAST TLIM4376A
1001
95.
90.
85.
80.
75.
70.

65.
60.
55.

50.
45.
40.
35.
30.
25.
20.
15j
10:
5:
0

33:06
i

\





32:45

\




25,17


« J
25:12\
23:33 1
1 il I . 1 II
1 ill 1 W HAITI d"« "i'l 34>3a 1 IJI 1
\rn\M V lj nrl^ H/i
V ' j( \j fV V

-,/A//r")- l-rf
**-"^ Lw*
Or* '
I


33\ 36 "22\ 48' 231: bo' 23\'l2 23:24 23:36 2J>4s' 24':6o' 24:1^' 24\24' 34': 36' 34:48' 25ib6' 25*: 12' 25.-J4
-1.5X4
L1.5X4
Ll.414
.1.3X4
.1.2X4
J..3X4
'-.1.1X4

.1 . 0X4
J.3X3
'.8.5X3

.7.7X3
17.0X3
-.6.2X3
.5.4X3
'-.4.6X3
'-.3.9X3
-.3.1X3
-.2.3X3
'.1.5X3
'.7.7X2
'• 0 . 0X0
Time
rila IPS 80094 tl-933 Acq:6-JXH-98 23:49:01 XX+ Voltage SIR 70S
315.9419 Ezp:DB335
TBXANSLX LABS T&xtiTLI M33 BLAXX TLH44376A
100]
55.
90:
85:
80:
75:
70:
65:
60:
55:
SO:
45:
40:
35:
30:
25:
20.
15:
1
-------
fiJ.a:P9ao094  #1-922 Acq: 6-JAH-yo JJ:4y:tll £1+  vo-icaye  SIM  sur HoiaestiJ
303.9016 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,1652.0,0.00\,r,r) Xxp:DB22S
TRIASSLX LASS  Taxt.-ZZJ H23 BLAST TLH4437SA
 1003

  80.

  SO.

  40.

  20.

   0.
                                                     A3.85X4
                                                                                A3.26X3
          19:00        20:00       21:00        22:00       23:00       24>QO
T±le:P980094 tl-922 Acq:6-J7Or-98 23:49i01 XI* Voltage SIS  70P Noise:457
305.8987 BSUB(256,30,-3.0)  PXX>(5,3,1, 0.10\,182B.O,0.00\,TtT) Xxp:DB225
XSIANSLS LABS  TttrtJUJ K23 BLAKX TLH44376A
1001                                                        AS.89X4
                                                                                     25:00
          19:00        20:00       21:00        22:00       23:00       24:00
r±letP980094 tl-922 Acq:6-JKS-96 23:49:01 EI+ Voltage SIS  70P Soiae:61S
315.9419 BSUB(2S6,30,-3.0)  PKD(5,3,1, 0.10*,2460. 0,0.00\,r,T) Xzp:DB225
         LABS  Text:TLI M23 BLANK TLI»44376A
1004                                                        A6.75E6
 80.

 60.

 40.

 20.
                                                                                     25:00
          19:00        20:00       21:00       22:00        23:00       24:00
Tile:P980094 tl-922 Acq:6-JKK-9B  23:49:01 ZI+ Voltage SIS  70P Koiao:589
317.9389 BSUB(256,JO,-3.0)  PKD(5, 3,1, 0.10^,2356.0, 0.00\,r,f) Krp:OB225
TSIANSLS LABS  Teit:TLI H23 BLAXX TLI»44376A
1003,                                                        A8.90Z6
 80.

 60.

 40.

 20.
                                                                                     25:00
          19:00        20:00        21:00       22:00        23:00
r±le:P980094 tl-923 Acqt6-JXX-98  23:49:01 £2> VoltMge SIS 70P
375.8364 Ezp:DB225
TKIANGLZ LABS  Tejct:TLI M23 BLABX TLH44376A
100118  32
                                                                 24:00
                                                                                    25:00
-1.2X4

.9.6X3

.7.2X3

.4.8X3

'.2.4X3

 0.0X0
                                                                                              Tiae
                                                                                                     Time
                                                                                          .1. 8X6

                                                                                          .1.5X6

                                                                                          ,1.1X6

                                                                                          7.3X5

                                                                                          3.7X5

                                                                                          .0.0X0
                                                                                             Xlae
                                                                                          2.5X6

                                                                                          2.0X6

                                                                                          1.5X6

                                                                                          9.9X5

                                                                                          4.9X5
                                                                                                  0.0X0
                                                                                                     Time
 ao:

 6QL

 40:

 20:

  01
                                                                                                -1.2X4
^^
'.9.7X3

.7.2X3

.4.8X3

.2.4X3
          19:00
                      20100
                                   21:00
                                               22:00
                                                            23:00
                                                                        24:00
                                                                                    25:00
                                                                                         '-0.0X0
                                                                                             T±ae
                                                                                                           67

-------
 ril«:P9BuoS4  #1-922 Acqsf-JAN-9B JJ:49:01 EI+ Voltage SIS 70P Noiea:J97
 319,8365 BSUB(256,30,-3.0) PKD<5,3,l,0.10\,158a.OrO.OO\rT,T) XrptDB225
 TSIANGLX LASS  TmrttTLI H23 BLAST  TLIt44376A
                20'tOO            ai'iOO            23:00           23*00
\r±J.*tP980094  tl-922 Acqt6-JJOT-98 23*49,01  XI+ Voltage SIS 70P Boiae>465
321.8936 BSVB(256,30r-3.0) PKD(S,3,1,0.10\,1B60.0,0.00\,T,T) XxptOB22S
TRUUKLX LASS  TerttTLI H23 BLANK TLH44376A
       ,      A2.15X3
24100
                                                             0.0X0
                                                         '2S\ 00  Ma
                20:00            21:00           22:00            23'tOO
\rHasP980094  tl-922 Acqs6-JKHt-98 23t49s01 EI+  Voltage SIX  70P Soiae:498
327.8847 3SUB(256,30,-3.0)  PXD(5,3rl,0.10\,1992.0,0.00\,T,r) EzptDB225
T3IANGLX LABS  TexttTLI H23 BLANK TLH44376A
100\                                      A1.Q6E7
  801

  60.

  40.

  20.
                                        24100
                    O.OEO
                25i00  T±me
                                                            -2.9ES

                                                            [.2.3E6

                                                            1.1.726

                                                            .1.1X6

                                                            -S.7ES
                20', 00            21:00           22'tOO           23tOO
\TiletP980094 tl-922 Acqt6-JTUl-9S 23i49t01 Eli- Volfcsffe SIS 70P Soiaet710
331.9368 BSVB(256,30r-3.0)  PXD(S,3,l,0.10\r2840.0,0.00\,TfT) XxpiDB225
TSIANGLX LABS  TextsTLI M23 BLANK TLIt44376A
1003,                                           A7.97E6
  BO.

  60.

  40.

  20.
                                        241 00
                                                            '.O.OEO
                                                         25100  T±ae\
                                                           -.2.1X6

                                                            .1. 7X6

                                                            J..3E6

                                                           .8.3X5

                                                           -4.2X5
                20:00            21:00           22:00           23:00
T±letP980094 tl-922 Acqt6-J7ur-98 23:49:01 XII- Voltage SIS 70P Ho±aes388
333.9338 BSUB(256,30, -3.0)  PXS(S,3,1,0.10\,1552.0,0.00\,F,T) SrptDB225
TRIAJKLS LABS  TartiTLX H23 BLANK TLIt44376A
1004                                           A9.75E6
                                                                                  24 tOO
                                                            '.0.0X0
                                                         25100 Mae
 so:

 so:

 40:

 201

  0.
A6.20X6
                201 00
                                 21:00
                                                 22,00
                                                                 23100
                                                                                  24100
                   .2.6X6
                   -

                   .2.1X6

                   .1.6X6

                   .1.0X6

                   .5.2X5
                                                           '.0.0X0
                                                         25100 Mae|
                                                                                                           63

-------
rile:P980094 #1-922 Acq: 6-JAK-98 23:49:01 XI+ Voltage
303.9016 Xxp:DB225
TRIANGLE LABS TeJCt:TLI M23 BLANK TLI444376A
1001 21.-J7
80.
60.
40.
20.
0
rile
315.
TBIJt
1001
80.
60.
40.
20.
o-
rile
319.
TSIA
1003
30:
4 0 '
20:
o'-
File
331.
TSIA
1001
80:
40:
o-
rile
292.
TSIA
1001
ao:
60:
40:
20:
o-
rile
330.
TSIA
1001
ao:
60:
40:
20:
o-
19:04 19:43 20:38 31:08 (I
^r^^^f^iUfJ^J^ W/V"MRi*

19:00 20:00 21:00 22:00
:P980094 #1-922 Actji6-JAN-98 23:49:01 EH- Voltage
9419 E*p:DB225
\KSLX LABS Text:TLI M23 BLANK TLH44376A
-




19:00 20:00 21:00 22:00
IP980094 #1-922 Acq:6-JAN-98 23:49:01 XI+ Voltage
8965 Xxp:DB225
NGLE LABS Text:TLI M23 BLANK TLI#44376A
18:45
1 19:11 19:53 21:17 22:03
\MvljlJ&jiMj|j^^ ,ij
v Y i^ft/TV '^ T[l IM^YW^r^V^ Wy |U^

' is',00 ' 20:00 21:00 J2.-00
:P980094 #1-922 Acq: 6 -JAN- 9 8 23:49:01 XI+ Voltage
9368 Xxp:DB225
NGLE LABS TeitzTLI H23 BLANK TLH44376A
21:55
Tl
1
III!
SIS 70P
23:06
22,45 33f33 "\i7

23:00 24'tOb 25:00
SIS 70P
23:05



II
2J:00 24:00 25:00
SIS 70P
25 07
23,14 33:51 ||
^&faUU^\^?'&dffil iMdflLJ
INpVvt^vVrilT^ Vr'jliyv

2jioo ' ' 24:00 ' 25:00
sja 7op



19:00 20:00 21:00 22:00 23': 00 24:00 25:00
:P980094 #1-922 Acqs 6-JZN-9a 23:49:01 XI+ Voltage SIS TOP
9825 Xxp:DB225
NGLZ LABS Text:TLI H23 BLANK TLH44376A
19:1019:35 20:14 21:11 21:56 22:31 23:18 24:01 24:54 25:24 „
>r^Sk^*>V*\ /VMkA»xiTW*vwx i/w -A"\ /lAj»NA /\Aj^^«V^>M/*Mrtrl)^"*v*A*U^M>/-'N * o^wMArVS ^»"^y\r*yA/v-rt ^WWtr




19:00 20:00 21:00 22:00
:P980094 #1-922 Jicq-: S-J3UT-98 25:49:01 £T^- Volta?a
9792 Xxp:DB225 	
NGUT LABS Text:TLI H23 BLANK TLII44376A
19:29 20:17 31jll 21:43
^^>YVvV*yvv^rV>'~V^*('Y^^*V^(**'Vw>s'^^



19:00 20:00 21:00 22:00




2J:00 24:00 25:00
SJfi 70P
"W- VY-— v% ^v ^^wv^v^^



2J>00 '' 24:00 25:00
-1 . $£4
-.1.3X4
'-.9.9X3
'-.6.6X3
-.3.3X3
•o.oxo
Time
-1 . 8X6
.1.5X6
.1.1X6
.7.4X5
LJ.7I5
O.OEO
Time
_9.2rJ
:7.4t3
L5.5EJ
.3.7X3
.1.8X3
0.0X0
Time
-2.1X6
.1 . 7X6
.1.3X6
.8.4X5
-4.2X5
0.0X0
Tiae
.1.5X7
.1.2X7
.8.7X6
-5.8X6
.2.9X6
0.0X0
Tiae
.1.3X7
.1.0X7
.7.9X6
.5.2X6
.2.6X6
0.0X0
Time
69

-------
Channel   I  338.3792     Peak top
Height 2,82 volts Span   298 ppi
Systei file naie
Data   fiienaie
Resolution
Groupnuiber
lonizatlon lode
Switching
tef, lasses
fl   292.3825         J
B   383.3616         K
C   385.8987         L
D   315.9419         1
E   317.9389
F   319.8965
G   321.8936
H   327.8847
I   338.3792
tef. iass    388.3761     Peak top
Height   .94 volts Span   288 ppi
       1
     D*
 mm
388.3761
338.3792
331.3368
333.3338
Xfi.8364
                                                            70

-------
 TLI Project      44376A
 Client Sample:   141-144
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U980027
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-10A-D Date Extracted: 12/29/97
Date Analyzed: 01/06/98
1.000 Dilution Factor n/a
n/a Blank File: U980026
DB-5 Analyst: KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7.8-PeCDD
1,2,3.4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1.2J,7,8,9-HxCDD
1,2,3,4.6,7,8-HpCDD
1.2,3,4.6,7,8.9-OCDD
2,3,7.8-TCDF.
1,2,3,7.8-PeCDF
2.3,4,7,8-PeCDF
'.,2,3,4,7,8-HxCDF
1,2^,6,7,8-HxCDF
2,3,4,6,7.8-HxCDF
1,2^,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4.7,8.9-HpCDF
1,2.3,4,6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Ait $l& |l! " PL , " SMPC
0.02
0.03
0.02
0.04
EMPC 0.04
0.15
0.24
1.5
0.15
0.22
0.44
0.15
0.20
0.02
0.62
0.08
0.46

Amt (ng) number m. EMPC
2.8 9 2.9
0.47 7 0.85
0.37 5 0.51
OJ1 2
12.8 16
3.7 13 3.7
1.8 11 1.9
0.98 4
Ratto
0.73
1.32
1.09
1.31

1.17
0.84
0.75
1.60
1.57
1.23
1.33
1.20
1.05
1.02
1.03
0.93










RT
25:21
29:37
32:45
32:49

36:03
39:36
24:41
28:35
29:17
32:02
32:09
32:37
33:22
35:01
36:33
39:49










Flags
PRJ
J_
J_
J_
J_

iZ






PRJ
	
J_


Flags



—




                                      Page 1 of 2
                                                                       MTT2.PSR v1.01. LAJtS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:16 01/10/98
                                    71

-------
 TLI Project:      44376A
 Client Sample:   141-144
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980027
.
Uiv*xi*Br j^c*nnflnn!!t
•«.***•* • ITJB. 'W^««*» •^•••K »U ..,••, \ fff ff f
13C1r2,3.7,8-TCDF
"Ca-^J.S-TCDD
l3C12-l,2,3,7,8-PeCDF
13C12-U,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13Cl2-lA3,6,7,8-HxCDD
13C,rlA3,4,6,7.8-HpCDF
13Clrl.2,3,4,6,7,8-HpCDD
I3C I2- 1 A3 ,4,6,7,8 ,9-OCDD

Surrogate Standards (type A)
13C12-2^,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13C,2-U,3,4,7,8-HxCDD
I3C,2-U,3,4,7,8,9-HpCDF
Surrogate Standards {Type A)
37CU-2,3,7,8-TCDD
Alternate Standards (Type A)
13C,2-U,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13Ci2-lA3,4-TCDD
13C,2-lA3,7,8,9-HxCDD
" fnfA ~" '
-^/wH^lPSl ,,^V
2.6
2.6
2.8
2.7
2.8
3^
2.9
3.0
53

AIJ& ^ng) -
3.6
3.9
3.6
3.4
AmfcSfigJ ;
3.4
, Ana. (fig) t
2.9
2.9
•• '- •;,,



'v"rf ^ffecovwy
64.4
64.1
69.9
66.9
70.9
80.0
73.3
75.4
66.1

% Recovery
89.0
98.1
90.8
84.9
%Recwery
84.8
'% Recovery
73.2
73.1
' •"<



,vv^* •„
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%- 130%

-
40%-130%
40%-130%
40%-130%
40%-130%



40%-130%
40%-130%



Ba*tn.
, 0,**»& ,
0.75
0.81
1.50
1.46
0.51
1.20
0.44
1.05
0.87

Ratio
1.50
0.51
1.21
0.44


Ratio
0.50
0.51
Ratio
0.82
1.21

»,«,*" *,"
24:38
25:21
28:34
29:36
32:09
32:48
35:00
36:03
39:36

RT
29:16
32:02
32:44
36:32
RT
.25:22
RT
33:23
32:37
RT
25:10
33:07

- ,rja^ „







	


FJags



—
Flags
—
Flags

—
Flags


                     Data Reviewer
            01/10/98
                                       Page 2 of 2
                         Mm.PSR v 1.01. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 10:16 01/10/98 ^
                                        i

-------
  Data Review By.
Initial
_o
                                     .Date.
                                              Calculated Moise Area:
  The Total Area for each peak with an ion abundance ratio outside
  Iratio  limits has been recalculated according to method requirements.
                                                                     3.00
  Page No.
  01/10/98
 Listing of O980027B.dbf
 Matched GC Peaks / Ratio /  Ret. Tine
  Compound/
  M_Z.. .. QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area. Peak.1. . Area.Peak.2..  Rel.RT  Compound.Name. .  ID.
                                                                               Flags.
TCDF
304-306
KN
K
K
K .
K
K
K









304-306
LL3C12-TCDF
J.16-318





316-318
TCDD
320-322 .
KN
KN
K
K


M
AN


D

DC NL 0
21
22
22
22
22
23
23
23
24
24
24
24
25
25
25
26
0
:00
:30
:01
:14
:38
:57
:21
:.37
:56
:04
:14
:29
:41
:05
:17
:33
:23
.65-0.89
0.81
0.77
0.74
0.76
0.74
0.74
0.73
0.73
0.73
0.75
0.72
0.75
0.75
0.72
0.73
0.70
0.78
16 Peaks

DC NL 0:
DC ML 22:
DC WL 23 :
24:
24:
25:
0.
:00 RO
26 RO
01
13 RO
38
04 RO
3 Peaks

DC NL 0:
22:
23:
23:
24:
24:
24:
25:
25:
25:
25:
D SN 25 :
0.
00 RO
49
13
30
12
26
51
14
21
32 RO
42
53 RO
.65-0.89
1.19
1.43
0.36
0.37
0.75
0.26
0.867
125
3,102
2,589
1,998
12,407
7,660
7,082
4,393
5,303
8,779
2,545
2,597
7,981
1,704
1,460
317
207
70,131.
.83
.66
.17
.81
.67
.13
.06
.62
.84
.06
.21
.34
.71
.17
.68
.56
.51
.20
-1.079

0.000
1,347.18
1,104.95
861.72
5,263.06
3,264.01
2,977.47
1,849.50
2,233.61
3,757.28
1,062.80
1,110.82
3,408.46
714.97
617.82
130.77
91.01

1,755
1,484
1,137
7,144
4,396
4,104
2,544
3, 070
5,021
1,482
1,486
4,573
989
842
186
116

.48
.22
.09
.61
.12
.59
.12
.23
.78
.41
.52
.25
.20
.36
.79
.50

0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1

0.959
16.
13.
41.
72.
17,628.
69.
21
33
84
55
79
83
17,771.17
65-0.89
0.38
0.78
0.78
0.70
0.76
0.75
0.82
0.77
0.73
0.60
0.80
1.10
9.
5,487.
3,130.
336.
951.
517.
218.
939.
65.
86.
96.
27.
24
47
87
73
42
65
99
00
50
11
75
05



31.56
7,570.49
30.38
Vr+ 1 1 nua - - —


2,412.32
1,369.82
138.81
411.12
221.37
98.44
408.00
27.60
37.46
43.10




85.
10,058.
117.




.62
.30
.68

0
0
0
0
1
1

.873
.894
.903
.919
.932
.948
.959
.972
.977
.984
.994
,002 2378-TCDF AN
.018
.026
.037
.071

-1.041
.000
.911
.934
.983
.000 13C12-2378-TCDF ISO
.018
















J









0.895-1.047

3,075.
1,761.
197.
540.
296.
120.
531.
37.
62.
53.


15
05
92
30
28
55
00
90
79
65

0
0
0
.000
.900
.916



0.927
0.955
0.964
0.980
J
0.995
1.000 2378 -TCDD AN
1.
1.
1.
007
014
021
PRJ
J
J

Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 10:16 01/10/98
                                                                                                               t

-------
Page No.
01/10/98
                         Listing of CJ980027B.dbf
                         Matched GC Peaks /  Ratio / Ret. Tine
Compound/

H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.
D
D
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334



332-334
PeCDF
340-342

D
D
D
D
D





M
AN





D

340-342
13C12- PeCDF
352-354

D SN 26:09 RO 1
D SN 26 : 21 RO 1
10 Peaks
DC NL 0:00
DC WL 22:50
DC WL • 22:59
DC WL 23:07
24:00
24:13
24:41
25:22
25:45
5 Peaks
0.65
DC NL 0
25
25
25
:00
:10
:21
:41
RO 2
0
0
0
3 Peaks
.84
.00
-0.89
.88
.82
.81
.89
9
27
11,830
7
33
8
204
1,668
41
11
11,362
482
13,566
18
18,667
13,386
380
.77
.24
.49
.49
.91
.84
.08
.99
.00
.17
.90
.43
.49
.25
.15
.86
.66
32,434.67
1.32-1.78
DC NL 0
26
D SN 26
D SN 26
D SN 27
D SN 27:
D .SN 27:
27:
27:
27:
28:
28:
28:
28:
28:
28:
29:
29:
29:
D SN 30:
30:
:00
:36
:52
:56
:04
:14
:21
:36
:43
:53
12
18
30
35
45
52
17
25
45
01
15
RO 0.
1,
RO 0,
RO 1.
RO 0.
1.
1.
1.
1.
1.
"l.
1.
1.
1.
1.
1.
1.
1.
1.
RO 0.
RO 1.
.80
.49
,43
,81
.78
57
74
54
52
56
52
47
54
60
50
53
57
45
32
63
15
14 Peaks

DC NL 0:
27:

00
44
1.32-
RO 2.
.1.
1.78
20
57
6.
1,836.
18.
30.
21.
30.
29.
562.
3,502.
805.
1,116.
1,629.
716.
579.
518.
844.
821.
1,071.
205.
22.
87.
14,297.
.12
.97
72
98
68
62
31
S5
29
11
79
08
00
00
48
84
24
84
97
80
26
42
1,668
41
11
11,362
482

8,431
6,010
179
.99
.00
.17
.90
.43

.25
.87
.02


10,235
7,375
201
0.
0.

.90
.99
.64
1.032
1.039
921-1.079
0.000
0.901
0.907
0.912
0.947
0.955
0.974
1.001 37C1-TCDD CLS
1.016
921-1.079
0.000
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
PeCDF Fa 1 1 awn ————————


1,099.





340.
2,114.
490.
673.
969.
434.
356.
311.
510.
501.
635.
117.

53.


,71





72
09
52
40
35
00
00
36
75
37
13
07

04


737





221.
1,388.
314.
443.
659.
282.
223.
207.
334.
319.
436.
88.

46.

0.

.26





,83
20
59
39
73
00
00
12
09
87
71
90

28

925-1.065
0.000
0.931
0.940
0.943
0.947
0.953
0.957
0.966
0.970
0.976
0.987
0.991
0.998
1.001 12378-PeCDF AN
1.006
1.011
1.025 23478- PeCDF AN
1.030
1.041 J
1.051
1.059 J

0.860-1.140
2.
70.
37
25

42.

94

27.

31
0.000
0.971
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                       Printed: 10:16 01/10/98
                                                                                                              74

-------
  Page  No.
  01/10/98
Listing of CJ980027B.dbf
Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak . 1. .  Area.Peak. 2. .  Rel.RT Compound.Name.. ID..  Flags.






352-354
PeCDD
356-358

D •




D









356-358
13C12- PeCDD
368-370








368-370
HxCDF
374-376






28:34
28:51
29:01
29:16
29:45
29:56
7 Peaks

DC NL 0:00
27:49
D SN 28:05
28:18
28:33
28:41
28:53
D SN 29:02
29:07
29:19
29:27
29:37
29:45
DC SN 29:59
30:05
DC SN 30:17
DC SN 30:21
11 Peaks

DC NL 0:00
27:42
DC SN 28:33
29:36.
29:44
29:56
30:05
30:15
DC SN 30:28
6 Peaks

DC NL 0:00
31:05
31:14
31:23
31:31
31:41
32:02


RO

RO


1
RO
RO
RO

1
1
5
1
3
1

.50
.66
.26
.50
.37
.72

14,902.92
274.02
29.20
12,815.90
28.64
25.51
28,146.44
.32-1.78
0
0
0
1
.85
.59
.04
.49
1.54


RO
RO

RO


RO
RO
RO
RO

1.
RO

RO



RO
RO


1.
RO


RO



1.
1.
0.
.54
,65
92
2.06
1.
0.
1.
1.
2.
1.
0.
0.

32-
0.
1.
1.
1.
1.
1.
2.
1.
1.

05-
1.
1.
1.
1.
1.
1.
1.
38
66
32
47
39
83
99
24

1.78
81
33
28
46
57
43
30
04
36

1.43
62
23
31
02
26
32
23
3.14
754.32
9.84
53.38
477.26
90.57
285.96
35.17
80.12
130.21
56.36
72.94
47.53
5.23
35.39
3.88
1.23
2, 084 .04
8,950
171
60
7,693
37
16
.65
.03
.28
.92
.85
.14
5,952.27 1
102.99
11.45
5,121.98
11.23
9.37
1
1
1
1
1
.000 13C12-PeCDF
.010
.016
.025 13C12-PCCDF
.041
.048
123 IS2


234 SOR1





458

31
289
54
178

64
75
34
41
28


.51

.98
.19
.90
.09

.78
.60
.26
.51
.31

25.43






0.

779.27

21.40
188.07
35.67
107.87

31.42
54.61
51.90
31.43
19.22

13.88



935
0
0
0
0
0
0
0
0
0
-1.022
.000
.940
.949
.956
.965
.969
.976
.981
.984
0.990
0.995
1.001 12378- PeCDD
1.
1.
1,
1.
1.

.005
.013
.016
,023
.025





J

J


J
J
J
AM J
J

J



0.865-1.135
0.63
37.28
5.63
7,368.03
1, 073.94
83.42
23.92
18.75
8.04
8, 605.34

21.

4,375.
655.
49.
21.
11.


30

81
84
14
57
40


15.98

2,992.22
418.10
34.28
9.38
10.93

0.
0.
0.
1.
1.
1.
1.
1.
1.
000
936
965
000 13C12-PeCDD
005
Oil
016
022
029



123 IS3






PeCDD / njii»ur TOJ..I.OWS --•
21.97
625.75
1,369.52
98.58
166.25
88.38
1,154.34

344.
776.
54.
92.
50.
637.

90
48
57
60
29
82
0.962-

280.85
593.04
53.46
73.65
38.09
516.52
0.
0.
0.
0.
0.
0.
0.
1.047
000
967
971
976
980
985
996 123478-HxCDF




J
J
J
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                     Property Cf
                                     EPA ["    .?
                                   RTP ICJ  L. - 11
Printed: 10:1601/10/98

-------
  Page No.     4
  01/10/98

  Compound/
  M_Z.... QC.Log Omit Why
Listing  of  CJ980027B.dbf
Matched  GC  Peaks / Ratio  /  Ret. Tine
.RT.  OK  Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.




AN
M
374-376
13C12-HxCDF
384-386







384-386
HxCDD
390-392


32
32
32
32
33
33
:09
:15
:26
:37
:22
:28






1.33
1.35
1.21
1.20
1.05
1.33
12 Peaks

DC NL 0
31
32
32
32
33
33
33

:00
:04
:02
:09
:37
:OS
:14
:23
0
RO




RO
RO

7 Peaks


DC NL 0:00
31:
32:
34
:01
32:13
1,
RO


RO
32:22
DC SN 32:37




390-392
13C12- HxCDD
402-404




402-404
HpCDF
408-410



D


32:
32:
33:
DC SN 33:
45
49
07
26
RO


RO
RO
.43-0.59
0.88
0.44
0.51
0.51
0.51
0.26
1.56
0.50
495.90
129.03
197.98
506.44
34.10
117.30
4,983.57
282
74
108
275
17
67

.71
.05
.59
.86
.50
.00

213
54
89
230
16
50

.19
.98
.39
.58
.60
.30

1.000 123678-HxCDF AN
1.003
1.009
1.015 234678-HxCDF AN
1.038 123789-HxCDF AN
1.041


J
J

PRJ
J

0.876-1.124
5.84
20.73
8,412.04
10,390.38
9,665.99
27.92
6.51
7,458.64
35,982.21
.05-1.43
0.70
1.22
1.22
1.48
1.37
4.95
1.09
1.31
1.50
1.71
7 Peaks

DC NL 0:
32:
32:
32:
33:

00
13
44
48
07
1.
RO
RO



4 Peaks

DC NL 0:
35:
35:
35:
D SN 35:
DC SN 35:
DC SN 35:

00
01
18
26
40
46
59
0.
RO



RO
RO
RO
05-1.43
1.60
1.02
1.21
1.20
1.21

88-1.20
1.38
1.02
1.01
1.11
0.54
2.70
1.70
6.97
90.71
478.41
197.79
30.51
4.48
31.21
77.92
86.24
5.53
992.79

6
2,835
3,516
3,266
9
6
2,493

.30
.75
.05
.71
.43
.73
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14
5,576
6,874
6,399
36
4
4,965

.43
.29
.33
.28
.73
.31
.52
0.000
0.966
0.996 13C12-HXCDF 478 SOR2
1.000 13C12-HXCDF 678 IS4
1.015 13C12-HXCDF 234 ALT2
1.029
1.034
1.038 13C12-HXCDF 789 ALT1












49.89
263.12
131.09
17.65

16.
44.
57.



31
17
63



40,
0.958-1.014

,82
215.29
88.30
12.86

14.
33.
38.



90
75
50


0.000
0.962
0.976
0.982
0.987
0.994
0.998 123478-HxCDD AN
1.001 123678-HxCDD AN
1.010 123789-HxCDD AN
1.019


J


J

J
J
J


0.970-1.030
7.68
18.82
5,765.04
8,672.25
10,895.05
25,351.16

10.
3,158.
4,729.
5,960.

42
14
10
87

10.
2,606.
3,943.
4,934.

18
90
15
18
0.000
0.982
0.998 13C12-HXCDD 478 SDR3
1.000 13C12-HXCDD 678 IS5
1.010 13C12-HXCDD 789 RS2







7.38
1,443.50
273.19
304.94
9.96
4.45
6.63

727.
136.
160.




74
99
71




715.
136.
144.



0.996-1.049

76
20
23



0.000
1.000 1234678-HpCDF AN
1.009
1.012
1.019
1.022
1.028







Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 10:16 01/10/98

-------
 Page No.
 01/10/98
                          Listing  of CJ980027B.dbf
                          Matched  GC Peaks / Ratio  /  Ret..Time
 Compound/
 M_2....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.



408-410
13C12-HpCDF
418-420


418-420
HpCDD
424-426


36
DC SN 36
DC SN 36
:33
:46
:55
1.
RO 0.
RO 0.
03
55
48
4 Peaka

DC NL 0
35
36

:00
:00
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0.37-
RO 0.
0.
0.
2 Peaka

DC NL 0:
35:
36:

00
17
03
0.88-
RO 0.
1.
1.
0.51
66
44
44

1.20
02
13
17
136
5
2
2,157

10
6,563
4,469.
11,032.
. npv^JJi
0.
229.
225.
.05 69.11
.02
.49
.68

.79
.47 2,002.40
.51 1,370.05
.98
/Ur^*nn Vf\ l i f\uo - _

06
68 121.98
52 121.39
66.94



0.

4,561.07
3,099.46

1.
1.
1.

943-
0.
.044
050
055

1234789-HpCDF



AN



1.114
000
1.000
1.

0.975-

107.70
104 . 13
0.
0.
1.
044


13C12-HpCDF 678
13C12-HpCDF 789


IS6
SOH4

1.005
000
979
000


1234678-HpCDD


AN
  424-426

  13C12-HpCDD
  436-438

  436-438
OCDF
442-444
442-444

OCDD
458-460
458-460
                      2 Peaks
                                            455.20
                              0.88-1.20
                                                                          0.972-1.028
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC


DC

DC
DC

NL

1

NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN


SN
SN
SN
SN
2

NL

SN
SN
1
0
36
:00
:03


1
1
Peak

0
34
34
35
35
36
36;
37:
37:
38:
38:
39:
40:
40:
40:
40:
40:

:00
:22
:31
:44
:53
:17
:40
:07
:57
:08
:32
:49
04
13
20
26
37
0

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO



RO
RO
RO
.02
.05

.76-1.02
0.
0.
1.
1.
1.
0.
0.
0.
0.
0.
1.
0.
0.
0.
2.
1.
1.
.98
,22
.31
82
12
35
14
59
47
71
05
93
76
77
35
18
36
Peaks

0:
39:
39:
39:

00
36
52
57
0.
RO

RO
RO
76-
1.
0.
0.
4.
1.02
20
84
43
08
Peak
13
5,964
.88
.62 3,054.56
5,964.62
; HpCDD / Octa*CDD clod CDF
3
1
2
1
1
1
o
1.
6,
2.
3.
614.
16.
a.
1.
3.
3.
630.
.07
.19
.34
.78
.98
.00
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.36
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76 295.87
14 6.98
60
95
76
67
90
0
2,910.06 1

0.899
0
0
0
0
0
0
0
0
0
0
0
318.89 1
9.16 1
1
1,
1.
1.

.000
.000 13C1

-1.101
.000
.868
.872
.902
.906
.916
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.937
.958
.963
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.016
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0.899-1.101
0.
260.
3.
2.
260.
09
87 119.05
82
17
87
0.
000
141.82 1.000 OCDD
1.
1.

007
009

                                                                                                  AN
                                                                                                  AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                          Printed: 10:1601/10/98
                                                                                                                    *• 7

-------
Page No.
01/10/98
                          Listing of 0980027B.dbf
                          Matched GC Peaks / Ratio / Ret.  Time
Compound/
M_Z....  QC.Log Omit Why  .:RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Conpoand.Name..  10..  Flags.
13C12-OCDD                    0.76-1.02
470-472         DC  NL   0:00 RO 39.25          0.08
                        39:36     0.87      7,849.13
470-472              1  Peak                7,849.13
                                                           3,641.39
             0.996-1.004
                 0.000
       4,207.74  1.000 13C12-OCDD
                                                                                                       IS8
Column Description	  "Why" Code Description	  QC Log Desc.
M_2   -Nominal  Ion Masa(es)
..RT.  -Retention Time  (mm:as)
Rat.l -Ratio  of M/M+2  Ions
OK    -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
•«« End of  Report •»•
                                 WL-Below Retention  Time Window
                                 WH-Above Retention  Time Window
                                 SN-Below Signal  to  Noise Level
                                 Ol-Below Method  Detection Limit
                                 HL-Channel  Specific Noise Level
A-Peak Added
K-Peak Kept
D-Peak Deleted   . ,
T-Time Changed
M-Peak Area Changed
N-Name Changed
X-Ether Interference
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                             Printed: 10:16 01/10/98

-------
rile:U980027 tl-724 Acq: 6-JAN-199B 18:07:52 SC XI+ Voltage SIS 70S Itoiaai 23116
303.9016 F:2 BSUB(2S6 ,30, -3.0) ?TD(9, 5,3, 0.10\,112464.0,1.00\,T,T) XxptODBSUS
TRIANGLE LASS Text:tlit44376a HIT nriWF \^\— |HM
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AA1.10I7
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305.8987 T:2 BSUB(256r 30, -3.0) PTD(9,5,3,0.10\,139200.0,1.00\,r,X) XxptSDBSUS
TRIANGLE LABS Text:tJJ.t44376a TLI BLAST
1003
80.
60.
40.
20.
o-
A7.


AA1.4BX7
AA /
22: 00
14X7 A5-'
A f
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23:00 24:00 25-00 26: 00
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lime
rile:U980027 tl-724 Acq: 6-J7UT-1998 18:07:52 SC XI+ Voltage SIS 70S Noiae:S428
315.9419 T:2 BSOB(256, 30, -3.0) PTD(9, 5, 3,0. 101,21712. 0,1.00\,r,T) Xxp:NDB5US
TRIANGLE LASS Text: tli*44375a TLI BLAST
1001
aol
sol
401
o:





'22:00'





A7.S7E7 1.8X7
1


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23:00 24:00 ' ' ' '.25:00 	 25:00 	
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rile:U9a0027 tl-724 Acq: 6-JXN-1998 18:07:52 SC EH- Voltage SIS 70S Noiae:457B
317.9389 F:2 BSUB(356, 30, -3.0) PXD(9,5,3,0.10\,18312.0,1.00\,r,T) Exp:NDB5US
TRIANGLE LASS Text:tli.t44376a TLI BLAST
1001
aol
sol
40l
201
Q-





'22^00'





Al.Oira 2.4E7
i


11
2J.-00 24lflO 	 25:00 	 25:00 	
fila:U980027 tl-724 Acq: 6-JXK-1998 18:07:52 SC EH-
330.9792 T:2 Ezp:NDB5US
TRIANGLE LASS Tejrt:tlit44376a TLI BLAST
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rile:O9a0027 tl-724 Acq: 6 -JAN- 19 9 8 18:07:52 SC EH-
375.8364 Ts2 ExpiNDBSUS
TRIANGLE LABS Text:tlit44376a TLI BLAST
1001
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601
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79

-------
rila:D9B0027 tl-724 Acq: 6-JAK-1998 18:07:52 GC EH- Voltage SIS 70S Noiae:2012
319.8965 f:2 BSUB(256,30,-3.0) PXS( 7,5,3,0.10\,8048. 0,1 .00\,T,S) Xxp:XDB5US
TSIANSLX LABS Texts tlit44376a TLI BLAST
100:
80.
60.
40.
20.
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A1.37X7
A
A
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26\00 	 Time
Tile:U980027 tl-724 Acq: 6- JAW- 1998 18:07:52 GC XI* Voltage SIS 70S Soiam:5307
321.8936 t:2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,21228.0,1.00\,r,T) Kxp:SDB5US
XSIABGLX LABS Tezt:tlit44376a TLI BLAST
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0
A3. 08X7
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26':00 	 Tiae
File :O9 800 27 tl-724 Acqs 6-JAS-1998 18:07:52 GC 11+ Voltage SIS 70S Soiae:14867
331.9368 T:2 3SO3(256,30,-3.0) PTD(7,S,3,0.10\,59468.0,1.00\,T,T) Xxp:XDB5US
TRIANGLE LABS Text:tlit44376a TLI BLAST
1003
80:
'
50:
40:
ao:
0:
AS. 43X7
([

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H5.01iT7
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\

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35:00 Mae
rile:O980027 tl-724 Acq: 6-JXK-1998 18:07:52 GC EH- Voltage SIS 70S lToiae:5153
333.9338 f:2 BSUB(256,30,-3.0) PTD( 7,5, 3,0. 101,20612. 0,1.00\,r,T) Xxp:SDB5US
TRIANGLE LABS Tert:tlit44376a TLI BLAST
1001
80:

50:
40:
30J
0:
A1.02X8
(l

-.2.6X7

K7.38E7
1 f


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23\00 	 24:00 	 25:00 '
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0.0X0
26:00 Time
Tlle:U980027 tl-724 Acq: 6-JAN-1998 18:07:52 GC XI+ Voltage SIS 70S SOiae:3744
327.8847 Ts2 BSUB(256, 30, -3.0) PTD(7, 5, 3,0. 101,14976. 0,1.00\,f,T) ExptNDBSUS
TRIANGLE LABS Teit:tl±t44376a TLI BLAST
1003
80:
60-
40J
201
oj
Al.



A1.67X7
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23\00 24:00 25:00

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Tile,OS80027 tl-724 Acq: 6-J3UT-1998 18:07:52 GC EH- Voltage SIS 70S
330.9792 r:2 SxpiKDBSUS • -•
TRIANGLE LABS Textstl±t44376» TLI BLAST
1001
80:
50:
40:
20:.
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23:16 23^3ta 23:53 24:33 25:09





23\00 ' ' 24:00 25:00


25:42 26j05 26:24 ^-9.8X7





.7.9X7
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.2.0X7
0.0X0
26:00 Tiae

-------
Tila:U980027 #1-724 Acq: 6-J7tS-1998 18:07:52 GC XI+ Voltage SIS 70S Noia«:1862
339.8597 T:2 BSOB(2S6,30,-3 .0) PKD(7,5,3,0 .10\,7448.0,1.QO\,T,T) Xxp:NDB5DS
TRIANGLE LASS Text:tlit44376a TLI SLANT
100J
80.
50.

40.
20.
0
A2.1ir7
A
A
A1.10E7 I
A j A9.69E6
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F±le:O980027 #1-724 Acq: 6-JUT-1998 18:07:52 GC EI+ Voltage SIS 70S Soiao:2313
341.8567 It2 BSUB<256, 30, -3.0) PXD(7,5,3,0.10\,9252.0,1.00\rT,T) ExptSDSSUS
TRIANGLE LABS Text; tii#44J7S« TLI SLANT
100J
80:
50.

40:
20:
a-
A1.39X7
ft
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27:00 28:00
T±lesO980027 #1-724 Acq: 6-J7UT-199S 18:07:52 GC EH-
351.9000 T:2 BSVB(256, 30, -3.0) PKD(7,5,3,0.10\,4092
TRIANGLE LABS Tezt:Cll#44J75a TLI SLANT
1001

80:
50:
40.
20:

Ad
.





27:00 ' 28:00
f±loiU980027 #1-724 Acq: 6-JAS-1998 18:07:52 GC EH-
353.8970 T»2 BSUB(256, 30, -3.0) PKD(7,5, 3, 0.101,1852
TRIANGLE LASS Text:tl±#44376a TLI BLANK
1001

80:
so:
40:
20:
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AS.
,
.



/
27:00 28:00
rileiU980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EH-
330.9792 r:2 XxpiNDBSOS
TRIANGLE LABS Text:tl±t44376a TLI BLANK
1003i
80:
50:
40:
20:
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25:48 27:17 27:4538:01 28:25

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37X6
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29:00 30:00 Time
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28:43 29:06 29:42 30^19 30:37^9.9X7

27:00 28iOO ' ' '
fllet0980027 #1-724 Acq: 6 -JAN- 19 9 8 18:07:52 GC EH-
409.7974 n2 ExptNDBSUS 	
TRIANGLE LABS Tert:tU.t44376a TLI BLANK
1001
80:

50:

40:
20:
0:

27:13
1

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81

-------
rue:(79800.27  tl-724  Acq:  6-JAN-199S 18:07:52 GC £I> Voltage SIS 70S NOJ.se:955
355.8546 f:2  BSUB(256, 30, -3. 0) PXS(5,5,3r0.05\,3B20.0,1.00\rT,T) XxpsNDBSUS
TSIAOSLX LABS  Text:tlit44376a TLI BLANK
100^  A4.59X6
     ' 27\4a' '2aVoO  28:12 28:24  28t36 28t48 29tOO  29:12' '29\24 ' 29*: 36' 29': 4 a' 30: 00 ' 3oVl2 ' 30': 24 '
rile:U980027  tl-724  Acq:  6-JAN-1998 18:07:52 SC XH- Voltage SIS 70S Noiaet 1126
357.8516 r:2  BSUB(256,30, -3.0) PKD(S,5,3,0.05\r4S04.0,1.00\,r,T) Xxp:NBBSUS
TSIANSLX LABS Text:tl±t44376a TLI BLANK
1001 A7.79X6

  80.

  601
  401
  201
   0.
                            A1.38E6
               A
                 v
                                         A
                                           **-
                                                    *5-"™
                                                              A3.14S5
      27:48 28:00 28:12  28:24 28:36  28:48 29:00 29:12 29:24 29:36  29:48 30:00 30:12 30:24
rlle:U980027 tl-724 Acq:  6-JZN-199S 18:07:52 SC XI+ Voltage SIS 70S Noise: 192
367.8949 T:2 BSUB(256,30, -3.0)  PKD(5,St3,O.QS\r768.0r1.0Q\,T,T) Xxp:NDB5US
TRIANGLE LABS  Text: tl±f 44376*  TLI BLANK
1001                                                         A4.38E7

 80.

 601

 401

 201

  01
                                                                    .56E6
      27:48 28:00 28:12  28:24 28:36  28:48 29:00 29:12 29:24 29:36  29:48 30:00 30:12 30:24
r±le:O980027 tl-724 Acq:  6-JAN-1998 18:07:52 SC XH- Voltage SIS 70S Noise:333
369.8919 T:2 BSOB(256,30, -3.0)  PKD(SrS,3,0.05\,932.0,1.00\,r,T) ExpiNDBSUS
TSIANGLX LABS  Text:tlit44376a  TLI BLANK
1001
 80.
 601
 401
 201
  0'
                                                             A2.99E7
                                                                  4.18X6
      27:48 28:00 28:12  28:24 28:36  28:48 29:00 29:12 29:24 29:36  29:48 30:00 30:12  30:24
rila:U980027 tl-724 Acq:  6-J3UT-1998 18:07:52 SC XH- Voltage SIS 70S
330.9792 Ti2 Exp:KDB5US
HIANSLX LABS  Teitttlit44376a  TLI BLANK
1004

 80.

 60.

 40.

 20.

  0.
     27:46   38:01
                                               29t06
                                                           29:29 29:42
                                                                               30:07
                                                                                                 -1.2X6
                                                                                                  0.0X0
                                                                                                     Hm<
                                                                                                -1.9E6

                                                                                                .1. 6X6

                                                                                                .1.2X6

                                                                                                .7.8X5

                                                                                                .3.9E5
                                                                                                 0.0X0
                                                                                                     Time
                                                                                                 1.3X7

                                                                                                 11. OE7

                                                                                                 .7.7X6

                                                                                                 '.5.1E6

                                                                                                 .2.6X6
                                                                                                 .O.OEO
                                                                                                     Time
                                                                                                -9.1E6

                                                                                                '.7.3X6

                                                                                                '.5.5X6

                                                                                                .3.6X6

                                                                                                .1. 8X6
                                                                                                 0.0X0
                                                                                                    Tine
-9.9X7

.7.9X7

.6.0X7

.4.0X7

.2.0X7
                                                                                                 0.0X0
                                                                                                    Time

-------
Tila:D980027  tl-384 Acq:  6-JAN-1998 18:07:52 SC XI+  Voltage SIS  703 Noise17945
373.8308 T:3  3303(256,30, -3. 0) PXD(7,5,3,0.10\,31780.0,1.00\,T,T) XxptSDBSUS
TSIANSLE LASS Text.-tli*44376a TLI BLANK
 low
  80:
  60:
  40:
  20:
           A7.76X6
                               AS.38X6
A3. 4SE\
                    A9.26XS
                                                 A2.76X6
                                                                                 AS.10X5
     31:00  31s13 31:24 31:36 31,48 33:00  33:13 33:34 33:36 33:48  33:00 33:12 33:24  33:36 33:48
TiletU980027 tl-384 Acq:  6-JKK-1998 18i07:52 SC XH- Voltage SIX 70S Noise:4906
375.8178 f:3 3303(256,30, -3.0) PKD(7,5, 3, 0.10\, 19624.0,1.00\,T,T) ErptSDBSUS
TS.IANSLX LASS   Text:tll*44376a TLI BLANK
100\      AS.93X6
  g(H        A                      AS.17X6
  60:
  40:
  20:
A3.31E6
         \    A7.37X5
      J   V-^-v^y^v
                                                 A3.31X6
                                                                                 AS.05X5
    31:00  31:12 31:24 31:36  31:48 32:00  32:12 32:24 32:36 32:48  33:00  33:12 33:24  33:36 33:48
rile:U980027 fl-384 Acq:  6-JZN-1998 18:07:52 SC EI+ Voltage SIS 70S Hoiae:1703
383.8639 f:3 BSUB(256,30, -3. 0)  PKD(7,5,3,0.10\,6812.0,1.00\,T,T) Xzp:NDB5US
TSIAKSLS LABS   Text:tli»44376a  TLI BLANK
                                                       A3.27X7
  80:
  60:
  40:
  20:
  0:
                                                                        A3.49X7
    31:00 31:12  31:34 31:36  31:48 32:00  32:12  32:24 32:36 32:48 33:00  33:12 33:24 33:36 33:48
T±la:U9B0027 tl-384 Acq:  6-JA1T-1998 18:07:52 SC XI+ Voltage SIS 70S Koiae:1935
385.8610 F:3 BSU3(256,30,-3 .0)  PXD(7,5,3, 0.10\, 7740.0,1. 00\,T,T) Xzp:BDB5US
TSIANSLX LASS  Taxt:tlit44376a  TLI BLANK
1001                                   A6.87S7       A6.40X7
 80:
 60:
 40:
 20:
                                                                        A4.97X7
    31:00 31:13  31:24 31:36  31:48 32:00 32:12  32:24 32:36 32:48 33:00  33:12 33:24 33:36 33:48
Tlle:0980027 tl-384 Acq: 6-JAN-199S 18:07:52 SC XI + Voltage SIS 70S
392.9760 f:3 Eip:NI>B5aS
TRIANSLE LABS  Text:tli#44376a  TLI BLANK
1001	31jjj8	31s42   31:58 32:10	   32j33    3^50     33:09.      33:3233:43
 ao:
 60:
 40:
 20:
    31:00 31:12  31:24 31:36 31:48  32:00 32:12  32:24  32,36 32:48 33:00  33,12 33:24 33:36  33,48
Tile:U980027 tl-384 Acq: 6-J3UT-1998  18:07,52 SC XH- Voltage SIS 70S
445.7555 r:3 XxptSDBSUS  ~  ~     -   ••  - •  -	           	
TSIANSLX LABS  Text:tlli44376a  TLI BLANK
1001
.2.3X6

.1. 8X6

.1. 4X6

.9.1X5

.4.5X5

.0.0X0
    Time



1.8X6

1.4X6

.1.1X6

7.1X5

3.5X5

.0.0X0
    Time



9. 4X6

7.5X6

5.7E6

3. BE6

1.9X6
.1. 8X7

.1.5X7

.1.1X7

.7.4X6

.3.7X6

.0.0X0
   Time



.4.4X7

3.6X7

.2.7X7

1.8X7

8.9X6

0.0X0
   Time
    31:00 31:12  31:24  31:36 31:48  32:00 32:12  32:24  32:36 32:48 33:00  33:12 33:24 33:36  33:48

-------
Tl±e:U9B0017 tl-384 Acq:  6-JAK-199B 18,07:52 SC SI+ Voltage SIM 70S Hoiaa:1932
389.8156 Ts3 BSOB(256,30,-3.0)  rXD(7,5,3,0.lO\,7728.Q,1.00\,T,T) ExptSDSSUS
T&IASGLX LABS  Text:tli*44376a  TLI BLANK
100\                      A3.6316
 80.

 60.

 40.
 30.
       A4.99X5
         A
                                         A1.76X5
                                                           A4.42X5
                                                                        AS.76X5
 8.4X5

'.6.7X5

.5.0X5

.3.4X5

'.1.7X5
         31:36    31:48   32:00    32:12   32:24   32,36    32:48   33:00   33:12
r±le:O980027 tl-384 Acq: 6-J7OT-1998  18:07:52 GC XH- Voltage SIS 70S Soiae,2759
391.8127 T:3 BSOS(256,30, -3.0) PKD(7 ,5,3 ,0.10\,11036.0,1.00\,T,T)  XxpiSDBSOS
TSIANSLX LABS  Text:tlit44376a TLI BLANK
100\                     A2.15X6
 80.
 so:
                                                                                     33124
                                                                                                 0.0X0
 40.
 20:
       A4.OSES
        A
                                                           A3.38X5
                                         A1.29X5
                                                                        A3.85X5
                                                                                              33 36 Time
 6.8X5

.5.5X5

.4.1X5

.2.7X5

.1. 4X5
         31:36    31:48   32:00    32:12   32,24    32,36   32:48   33:00   33:12
rile:U980027 tl-384 Acq:  6-J7UT-1998 18,07:52 SC XI+ Voltage SIS 70S Soiae:2739
401.8558 T:3 BSDB(256,30, -3.0) PXD(7,S,3,0.10\,10956.0r1.00\,T,T) Sxp-.SDBSUS
TSIANSLZ LABS  Text:tli.t44376a TLI BLANK
100$                                                                    A5.96E7
                                                           A4.73X7
  80.

  60.

  40.

  20.

  OJ
         '31:36   '31:48   ' 32\00   '32:12   32:24    32,36   32:48   33:00   33:12
Tile,US80027 tl-384 Acq:  6-J7UT-1998 18:07:52 SC XH- Voltage SIS 70S Noi8o:1717
403.8529 T:3 BSOS(256,30,-3.0) tKD(7,5,3, 0.10\,686a.O,1.00\tTrT) XxptHDBSUS
TSIXKSLX LABS  Teit:tl±#44376a TLI BLANK
100$                                                                    A4.93X7

  gg,                                                       A3.94X7


  60.

  40.

  20.

  OJ
       ''31:36    31:48    32:00    32:12   32:24    32:36   32,48   33:00
rile,O980027 tl-384 Acq:  6-J3UT-1998 18,07,52 SC XI* Voltage SIS 70S
392.9760 r,3 XzptHDBSUS
TRIANGLE LABS  Text:tl±t44376a TLI BLANK
1003{        .31:42     31±58    32:1032,17

  ao:

  60.

  40.

 20:
                                                                                    33:24
                                                                                             33 36
                                                                                                 0.0X0
                                                                                                    Time
                                                                                    33:24
                                                                                             33 36
                                                                            33:12
                                                                                    33124
                                                                                             33  36
                                                                                   33,22  33:32
                                                                                               -4.4X7

                                                                                               .3.5X7

                                                                                               .2.7X7

                                                                                               .1. 8X7

                                                                                               .8.9X6
         31:36
                 31:48
                         32:00
                                  32:12   32:24    32,36   32,48   33:00    33:12   33:24
                                                                                            33
                                                                                               .0.0X0
                                                                                               36 T±ae

-------
rila:U980027 tl-545 Acq: 6 -JAN- 19 9 8 18:07:52 SC EH- Voltage SIS 70S Noiaa:2496
407.7818 T:4 BSUB(256,30, -3 .0) PKD(7,5,3,0.10\,9984.0,1.00\,f,T) Xxp:KDB5nS
TSIAKGLX LABS Text:tlit44376a TLI BLANK
1003
80.
SO.
40.
20.


A7.28X6
A
\

/ \ Al . 61X6
J ^- .^rV -/ ^ S — ^^
1.9X6
.1.5X6
.1.1X6
.7.4X5
.3.7X5

F J5«00 '' ' 35\12 '' ' 35lt24 35:36 35:48 36:00 36:12 36:24' '36:36 36:48 37': 00 Time
r±le:0980027 tl-545 Acq: 6-J7OT-1998 18:07:52 SC XI+ Voltage SIX 70S Soiae:1811
409.7789 t:4 BSUB(256, 30, -3.0) PKD(7,5,3,0.10\,7244.0,1.00\,r,T) Kxp:SDB5US
TSIANOLX LABS Text:tlit44376a TLI BLANK
1001
80.
60:
40:
20:

A7.16K6
\
A


/ \ A1.36E6
J X 	 /\^_/^^ S*~^
-1.9X6
.1.5X6
.1.1X6
.7.5X5
.3.7X5
0.0X0
35:00 35:12 35:24 35:36 3S':48 36:00 36:12 36:24 36:36 36:48 .37:00 Mae
rile:U980027 tl-545 Acq: 6-JAJT-1998 18:07:52 SC XI+ Voltage SIS 70S Koiae:2459
417.8253 T:4 BSUB(256, 30, -3.0) PKD(7,5,3, 0.10\,9836.0,1.00\,r,T) Xxp:KDB5US
TSIAHSLX LABS Text:tlit44376a TLI BLANK
1001
80:
60:
40:
20:
0:
A2.00X7
A
(1 . A1.37E7
II /N
A
/ V / V
y ^> — / ^ —
4.9X6
.4.0X6
.3.0X6
.2.0X6
.9.9X5
0.0X0
35:00 35\12 35:24 35:36 35^48 36:00 36*112 36\24 36\36 36:48 37:00 Time
rila:O9a0027 tl-545 Acq: 6-JKK-1998 18:07:52 SC XI+ Voltage SIR 70S Noiaa:3744
419.8220 T:4 BSUB(256f 30, -3. 0) PKD(7, 5, 3,0. 101,14976. 0,1.00\,f,T) Xzp:KDB5US
TSIAKGLX LABS Tait:tlli44376a TLI BLANK
1001
80:
60:
40:
20:
o:
A4.56E7

I \ A3. 10X7
1 \ f\
A
/ V / V
/ v — j ^^
-1.1X7
.8.8X6
.6.6X6
.4.4X6
-.2.2X6
' 0 . 0X0
3S\00 35:12 35:24 35:36 35:48 36:00 36\12 36:24 36\36 36:48 37\00 Tlae
r Ha: 09800 27 tl-545 Acq: 6 -JAN- 19 9 8 18:07:52 SC XI+ Voltage SIS 70S
430.9729 T:4 ElptNDBSUS
TSIAKGLX LABS Teit:tlit44376a TLI BLANK
ion
SO:
60:
40:
20:
o:
34:55 35:13 35:27 35:49 36:29 36^39^ _36:50 36:59
"^^




-3.1X7
^.5X7
-1.9X7
J..2X7
.6.2X6
0.0X0
J5iOO 35\12 35\24 35:36 35:48 36:6o' ' ' 36\12 ' '36:24' ' ' 36*:36 ' ' 36\48 'j7»00 Time
r±la:O980027 11-545 Acq: 6 -JAN- 19 9 8 18:07:52 SC XI+ Voltage SIS 70S
479.7165 T:4 Xxp:SDBSBS ......
TSIAKGLX LABS Text :tlit4 4376* TLI BLANK
100]
80:

60:
40:
20:
0:
35 16

M 35:50
1 1 1
js,»7 1 1 ";" | »«,«"!*, i'i" IWf "i" ui"
MMA A jy H . /W AAW TlUk A MT^A MM i!(J\*
.1.8X4
.1.4X4

.1.1X4
.7.2X3
.3.6X3
0.0X6
J5>00 35:12 35:24 35:36 35:48 36:00 36\12 36:24 36\36 36\48 37-00 T±me

-------
File:uyao027  tl-545 Acq:  o-JAu-1998 18:07:52 SC XI+ Voltage SIS 70S none114
423.7766 f:4  BSOB(256,30, -3.0)  PKD(7,5,3,0.10\,56.0,1.00\rT,T) KxptSDBSUS
TSIAHSLX LABS  Taxt:tlit44376a  TLI BLANK
100^       A1.22X6
                                                             A1.21X6
                                                                                                '.6.1X4

                                                                                                 0.0X0
      35:12  35:18  35:24 35:30  35:36  35:42 35:48  35:54  36:00 36',06  36', 12 36\18  36\24 36',30     Tlx
rile:U980027 tl-545 Acq: 6-JAN-1998 18:07:52 SC XI+ Voltage SIS 70S So±fe:847
425.7737 T:4 BSUB(256,30, -3.0)  PXD(7,5,3,0.10\,3388.0,1.00\,r,T) XxptSDBSUS
TSIANSLX LABS  Text:tlit44376a  TLI BLANK
1001       A1.08X6                                           A1.04X6                             ..2.5X5
     ' 35112' 35':ia' 35s24' J5«JO  35s 36 3Si42  35:48 35t54  36100 36s 06 ' 36-12 ' 36tia'
ttle:O980027 tl-545 Acq: 6 -JAN- 19 98  18:07:52 SC XI+ Voltage SIS 70S Soiae:350Q
435.8169 Ti4 BSUB(256r 30, -3. 0) PXD(7, 5,3,0. 10\,14000. 0,1. 00\,r,T) Sxp:JWB5US
TSJAWSLZ LABS  Tart: tli*44376a TLI BLANK
lOOi                                                        A3+05X7
  80.

  60.

  40.

  20.
             0.0X0
36:24 36:30     Time
      35:12 35:18  35:24 35:30  35:36 35:42  35:48 35:54  36:00 36:06
rl2e:OS80027 tl-545 Acq: 6-JAN-1998  18:07:52 SC EI+  Voltage SIS 70S So±ee,3438
437.8140 T:4 BSUB(256,30, -3.0) PKD(7,5,3, 0.10\,13752.0,1.00\,f,T)  ElptNDBSOS
TSIANSLE LABS  Tejct:tJJ.t44376a TLI BLANK
1001
 80.

 60.

 40.

 20.
                   35:24  35:30  35:36 35:42  35:48 35:54  36:00  36:06 36:12  36:18 36:24  36:30
r±le:U980027 tl-545 Acq: 6-JAN-1998 18:07:52 SC EI+  Voltage SIS 70S
430.9729 Ti4 XxpiSDBSVS
TSIANSLX LABS  Text:tULt44376a TLI BLANK
100JL  35:13          35:27	35:49     ^
                                              	  •'	^^Xl'^IHI-llli! I .^N,^!!!^^1 ' . ^l»
 80.

 60.

 40.

 20.
            -3.0X7

            .2.4X7

            .1.8X7

            .1.2X7

            .6.1X6
      35,12 35,18  35:24  35:30  35:36 35:42  35:48 35:54  36:00  36:06 36:12  36:18 36:24  36:30
                                                                                                 0.0X0
                                                                                                    T±a<
                                                                                                             o
                                                                                                             o

-------
rile:09'80027  tl-545 Acq:  S-JJOt-1998 18:07:52 SC EH- Voltage  SIS 70S HOiae:762
441.7428 r:4  BSUB(256,30,-3.0) PKD(7,5,3, 0.10\,3048.0,1.00\,r,T)  SrptSDBSUS
TRIANGLE LABS  Text:tllt44376a TLI BLANK
1001
  90.
  801
  701
  sol
  sol
  401
  3ol
  20.
  101
01
                                                                               A2.96X6
               35,00         36:00         37:00         38:00         39:00
Tile,a980027  tl-545 Acq:  6-JXB-1998 18,07:52 SC XI + Voltage  SIS  70S Noiet>:776
443.7399 r,4  BSUB(256r 30, -3. 0)  PKD(7,5,3,0.101,3104.0,1.00\,r,T) XxptSDBSVS
TRIABGLX LABS Text:tl±f44376a  TLI BLANK
1004                                                                             A3.
 901
 801
 701
 601
 sol
 401
 30^
 201
 101
  0\,  .,  .,.		'., . -•-,-,-	,—,	, ... ., •».., ., ff>	  „. .  ... ,  , n ... .
                                                                                  40:00
                                                                                   9X6
               35:00         36:00         37:00         38,00         39:00         40:00
me:0980027 tl-545 Acq:  6-J7UT-1998 18:07:52 SC SI+ Voltage SIS  70S
430.9729 T:4 Zxp:XDB5US
TRIANGLE LABS  Text.;tl±t44376a  TLI BLANK
100*         34:50   35:27            36lJ?  «    37:27     38:09  3a'*°    39:18  39.40
 90l
 aol
 701
 sol
 sol
 401
 301
 201
 101
  0.
               35,00         36,00         37:00         38,00
r±le,U980027 H-54S Acq:  6-JZX-1998 18,07:52 SC XH- Voltage SIS 70S
513.6775 r,4 XxptKDBSUS
TRIANGLE LABS  Textstlit44376a  TLI BLANK
1001
                                                                    39100
                                                                                  40:00
                                                                                                    5.4X5
                                                                                                   .4.8X5
                                                                                                   .4.3X5
                                                                                                   .3.7X5
                                                                                                   .3.2X5
                                                                                                   .2.7X5
                                                                                                   J.1X5
                                                                                                   .1.6X5
                                                                                                   .1.1X5
                                                                                                   .5.4X4
   .0.0X0
41.00  Tiae
                                                                                                  fS.9XS
                                                                                                   '.5.3X5
                                                                                                   14. 7X5
                                                                                                   '.4.1X5
                                                                                                   .3.5X5
                                                                                                   .2.9X5
                                                                                                   .2.4X5
                                                                                                   .1. 8X5
                                                                                                  -1.2X5
                                                                                                  -5.9X4
                                                                                                    0.0X0
                                                                                                41:00  Tine
                                                                                                  -3.1X7
                                                                                                  ''-.2.0X7
                                                                                                   '-.2.5X7
                                                                                                   -.2.2X7
                                                                                                   '-.1.9X7
                                                                                                   11.5X7
                                                                                                   11.2X7
                                                                                                   19.3X6
                                                                                                   Is.2X6
                                                                                                   -.3.1X6
                                                                                               ^	Lo.oro
                                                                                                41.00 Time
            J5; 00
                          3S:00
                                        37:00
                                                      3S00
                                                                    39:00
                                                                                  40:00
                                                                                                41:00 Time
                                                                                                           87

-------
\fUesU9u0027 41-545 Acq: S-JZy-199B 18:07:52 SC £1± Voltage six JUa
 457.7377 Ti4 BSBB<256,30,-3.0) fKO(7,5,3,0.10\,112.0,1.00\,r,T) SzpiODBSUS
 TRIANGLE LASS  T*rt:t±it44376m TLI BLANK
 100\                    A1.19E6
           39:30         39': 36         39:42        39:48         39:54
 rila:098Q027 tl-545 Acq:  6-JAS-1998 IS,07,52 SC EH- Voltago SIR 70S Noiae.,37
 459.7348 T:4 BSUS(256,30,-3.0) TXD(7,5r3t0.10\r10a.Or1.00\,T,I)
 TRIANGLE LASS  TAZtitHf44376m TLI BLASX
 1004                     A1.42XS
 40tOO
           39:30         39:36        39:42         39:48         39:54        40:00
\rile:O980027  tl-545 Acq:  6-JAN-1998  18:07:52 SC EI+ Voltage SIR 70S Noiae:786
469.7779 f:4  BSUB(256,30,-3.0) PXD( 7,5,3, 0.10%, 3144. 0,1. 00\,r,T)  Exp:NDB5aS
TRIANGLE LABS  Text:tlH44376* TLI BLANK
           39:30         39:36        39:42         39:48        39:54
file:O980027 tl-545 Acqs  6-JXB-1998 18t07:52 SC Eli-  Voltage  SIR  70S Noise-.20
471.7750 F:4 BSVB(256,30, -3.0) fKD(7,5r3, 0.10\,80.0,1. 00\,f,T) EzptODBSUS
TRIANGLE LABS  T&rt:tJJ.t44376a TLI BLANK
1004
 80J
40:00
           39:30         39:36         39i42         39:48        39:54
Tlle:U980027 tl-545 Acq: 6-JJOT-1998 18:07:52 SC EH- Voltage SIS  70S
430.9729 Ti4 ExptSDBSUS
XSIANGLE LABS  Ta*t:tlit44376t TLI BLANK
100H 	     _    _ 39jJ5^ 	     	39:48  39:51  	
40100
 aoj

 60.

 40:

 20:

  o:
              40:06
                                                                                             40
                 -2.BE5

                 \-2.2ES

                 -.1.7E5

                 [.1.1E5

                 -5.5E4

                 .O.OEO
                 06  Tine



                 -6.0E6

                 '.4.8E6

                 .3. 6E6

                 '.2.4E6

                 -1.2E6
                                                                                                 O.OEO
                                                                                             40:06  Time!
                -6.9E6

                '-5.5E6

                r4.1E6

                -2.7E6
                 .O.OEO
              40:06  Timel
           39130
                        39:36
                                      39142
                                                    39:48
                                                                 39:54
                                                                               40:00
                -3.0E7

                L.2.4E7

                ti.ar?

                -1.2E7

                -5.9X6
                .O.OEO
              40:06 Tlae\
                                                                                                             88

-------
                                                                                  CD
                                                                                  OJ
Peak Locate Examination: 6-JAN-1998:18:06 File:U980027
      Experiment:NDB5US Function:2 Reference:PFK

-------
                                                                                                       o
                                                                                                       CO
File:U980027 #1-724 Acq: 6-JAN-1998  18:07:52  GC  EI+
319.8965 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK  File  Text:TRIANGLE
100%               A4.
                                                     25:48      26:00
                                                     Voltage SIR 70S
      25:00       25:12       25:24       25:36
File:U980027 #1-724 Acq:  6-JAN-1998  18:07:52  GC  EI+
321.8936 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK  File  Text:TRIANGLE LABORATORIES,  INC
100%                A5.31E6
                                                    Voltage  SIR  70S

                                                    LABORATORIES,  INC,
       25:00       25tl2       25:24       25:36       25:48       26:00
File:U980027  #1-724  Acq:  6-JAN-1998  18:07:52 GC EH- Voltage SIR 70S
331.9368 F:2  Exp:NDB5US
Sample Text:tli#44376a TLI  BLANK File Text:TRIANGLE LABORATORIES,  INC.
100%,             25; 10
                           25:21
                                              26:12
                                                                            26:12
       25:00
                  25:12
25:24
25:36
25:48
26:00
26:12
                                                5.2E5

                                                4.1E5

                                                3.1E5

                                                2.1E5

                                                1.0E5

                                                .O.OEO
                                                   Time
                                                           .O.OEO
                                                               Time
2.2E7

.1.8E7

.1.3E7

.8.8E6

.4.4E6

.O.OEO
   Time

-------
 ile:U980027 #1-724 Acq:  6-JAN-1998  18:07:52  GC  EI+  Voltage SIR 70S
339.8597 F:2 Exp:NDB5US
 ample Text:tli#44376a TLI BLANK  File Text:TRIANGLE  LABORATORIES,  INC.
100%
    28:06     28:12     28:18     28:24     28:30     28:36     28:42     28:48
File:U980027 #1-724 Acq:  6-JAN-1998  18:07:52  GC  EI+ Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
 ample Text:tli#44376a TLI  BLANK  File  Text:TRIANGLE LABORATORIES,  INC.
1004,
                                                                            28:54
    28:06     28:12    28:18    28:24    28:30    28:36    28:42     28:48
File:U980027 #1-724 Acq:  6-JAN-1998 18:07:52 GC El-f Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
lOOi                                          28;34

  80J

  60J

  40

  20^

   0
                                                                            28:54
    28:06
 i I  i i
28:12
 • I  i
28:18
— i — j— i — i — r~ i — r  Y i —
 28:24    28:30
                                                — i — | — i — r-
                                                 28:36
 i i  i i  i i  i |—r l
28:42    28:48
28:54
                                                              29:00
                                                                                Time
                                                              29:00
                                                                                Time
                                                                                         _2.4E7

                                                                                         L1.9E7

                                                                                         Ll.4E7

                                                                                         L9.6E6

                                                                                         L4.8E6
29:00
• OEO
  Time

-------
File:U980027 #1-384 Acq:  6-JAN-1998  18:07:52  GC  EI + Voltage SIR 70S
373.8208 F:3 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK  File  Text:TRIANGLE LABORATORIES,  INC.
100%                                          A6.70E5
                                  I  ' '  '
                                33:18
                                                     i—I	1—I—r-
                                                       33:42
    33:00     33:06    33:12     33:18     33:24    33:30    33:36
File:U980027 #1-384 Acq:  6-JAN-1998 18:07:52  GC EI+ Voltage  SIR 70S
375.8178 F:3 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK  File  Text:TRIANGLE LABORATORIES,  INC.
100*                                          A5.03E5
    33:00    33:06     33:12     33:18    33:24    33:30     33:36     33:42
File:U980027 Sl-384  Acq:  6-JAN-1998 18:07:52 GC EI+ Voltage SIR 70S
383.8639  F:3 Exp:NDB5US
Sample Text:tli«44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
100%                                    33i23
  80 j
  60 j
  40J
  20_
   0
    33:00
33:06
                       33:12
33:18
                                              •i **y i—i	r-
                                              33:48
                                                                33:48
33:24
33:30
33:36
33:42
33:48
                                                 2.0E5
                                                 1.6E5
                                                 1.2E5
                                                 8.2E4
                                                 4 . 1E4
                                                .O.OEO
                                                   Time
                                                          1.5E5
                                                          1.2E5
                                                          8.8E4
                                                          5.9E4
                                                          2.9E4
                                                         .O.OEO
                                                             Time
 6.0E6
L4.8E6
Z.3.6E6
L2.4E6
11.2E6
.O.OEO
    Time

-------

TLI Project
Client Sample:
                  44376A
                  141-144
Method 23 TCDD/TCDF Analysis (DB-225)
                    Analysis File:  P980095
Client Project:
Sample Matrix:
TLIID:
Sample Size:
Dry Weight:
GC Column:
Culp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-10A-D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: P980094
DB-225 Analyst: JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
|»^S^v"; '^' V;H
2,3,7,8-TCDF
?toieifialj$^darcf ' :^
13C,r 2,3,7,8-TCDF
^Recovery Staitcfard, \ -— ••
^^1^3,4-TCDD
»thtt 015)V ' ®*~ '- -^ EMPC Ratio
0.27 0.73
fcnt (ng) % Recovery acifcnfts Ralo
3.2 78.9 40%-130% 0.77
r,t s *' '* BStlO
0.82
RT
23:06
RT
23:06
' RT ,
21:55
Flags
B_
Flags
—
Flags

                     Data Reviewer
                                                           01/09/98
                                       Page 1 of 1
                                                                       C3NF PSR v2.0l. LARS 6. m.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 10:1401/09/98
                                                                                  03

-------
                         Initial
                                  	Date.
  Data Review By:
                                              Calculated Noise Area:
                                                                      1.00
  The  Total Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
  Page No.
  01/07/98
Listing of P980095B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why  ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2. .  Rel.RT Compound.Name..  ID..  Flags.
TCDP
304-306 DC NL 0:00
18:29
18:46
DC SN 18:55
19:
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
20:
21:
DC SN 21 :
21:
21:
21:
22:
22:
22:
22:
23:
23:
23:
23:
24:
25:
00
05
28
36
44
55
01
10
20
29
38
48
11
22
36
43
53
07
21
32
59
06
19
37
44
32
17
0.65-0.89
RO 0.64
0.80
RO 1.51
RO 0.58
RO 1.83
RO 0.97
0.79
0.70
0.76
0.83
0.73
0.77
0.87
0.
81
0.77
0.73
0.
RO 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
76
07
77
79
74
77
73
78
73
73
75
75
74
78
68
304-306 28 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL 20:
DC WL 21:
23:
DC SN 23 :
DC SN 23 :
DC WH 24:
DC WH 25:
2.55
208.64
5.54
92.
4.
,91
,72
115.
3.
0.792-1.101
0.000
73
13
2.78
2.
,99
13.72
179.35
189.
358.
141.
13.
165.
372.
184.
456.
152.
964.
1.
170.
40.
.158.
174.
38.
176.
134.
86.
148.
164.
125.
71.
12.
4,913.
42
26
48
36
82
82
64
74
00
84
27
81
87
90
91
22
65
51
23
46
74
38
83
37
50
3.
7.
79.
78.
154.
64.
5.
72.
173.
82.
198.
64.
417.

74.
18.
67.
75.
16.
77.
56.
36.
,10
48
17
08
98
08
65
38
19
47
71
30
38

09
09
60
93
12
37
94
31
63.47
70.
53.
31.
5.

56
18
41
02

1.
7.
100.
111.
203.
77.
7.
93.
199.
69
75
18
34
28
40
71
44
63
102.17
258.
87.
547.

96.
22.
91.
98.
22.
99.
77.
49.
84.
94.
72.
40.
7.

0.65-0.89
00
33
36
06
14
44
19
10
RO 1.
RO 0.
RO 0.
0.
RO 1.
RO 0.
RO 0.
RO 0.
IS
37
42
77
09
5«
55
6O
316-318 1 Peak
2.
1.
3.
1,249.
0.
1.
1.
9.
1,249.
30
40
08
63
83
88
56
45
63



543.








79








705.





03
70
46

72
78
30
98
10
28
57
92
99
18
20
42
35

0.300
0.812 J
0.819
0.823 J
0.826
0.843
0.348
0.854
0.862
0.867
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.

873
880
887
893
900
917
925
935
940
947
957
968
975
995
000 2378 -TCDF AN
009
022
027
062
095

0.957-1.043



84





0.
0.
0.
1.
1.
1.
1.
1.

000
890
935
000 13C12-2378-TCDF ISO
006
027
053
089

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 02:42 01/07/98
                                                                                      04

-------
  Page No.
  01/07/98
Listing of P980095B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_2....  QC.Log Omit Why  ..RT.  OK Ratio Total.Area... Area.Peak.1. .  Area.Peak.2.. Rel.RT Compound.Nome.. ID.. Flags.
  13C12-TCDD
  333-334
  332-334

DC
DC




DC
DC
DC
DC


HL
SN




WH
WH
WH
WH
4

0:
19:
20:
21:
21:
22:
23:
23:
24:
24:

00
51
30
38
55
40
47
52
16
27
0.
RO
RO
RO



RO
RO
RO
RO
----- AJ
65-0.89
1
2
0
0
0
0
3
0
2
1
.71
.17
.54
.30
.82
.78
.52
.55
.51
.57
Peaks
                                        Above: TCDF / TCDD Follows
                       1.54
                       0.92
                       3.33
                     827.44
                   1,141.58
                      10.38
                       1.12
                       1.61
                       2.11
                       2.78
                   1,982.73
                                                               1.45
                                                             367.56
                                                             513.50
                                                               4.55
             0.908-1.092
                 0.000
                 0.918
           2.70
         459.88
         628.08
           5.83
0.948
1.000 13C12-2378-TCDD IS1
1.013 13C12-1234-TCDD RSI
1.048
1.099
1.103
1.122
1.130
  Column Description	  'Why' Code Description	  QC Log Desc.
 M_Z    -Nominal Ion Mass(es)
  ..RT.  -Retention Time (mm:as)
 Rat.l  -Ratio of M/M+2 Ions
 OK     -RO-Ratio Outside Limits
 Rel.RT-Relative Retention Time
  *•• End of Report •••
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
                                       33*37
Fi±a:P9800S5tl-922 AC(j:7-J3Uf-Ha  00:57:56 Sir Valtaga SIR 70P
303.9016 XzptDB225
XSIASSLX LASS  Text:It 1-144 TLH44376A
1001
 95.
 90.
 85.
 80.
 75.
 70.
 65.
 SO.
 55.
 50.
 45.
 40.
 35~
 JO:
 25.
 30-
 15J
 10.
  5.
  Oj
                                                                    24:32
-2.1X5
'.2.0X5
':1.9X5
'.1. 8X5
':!. 7X5
.1. 6X5
-.1.5X5
.1.4X5
'.1. 3X5
'.1.2X5
'.1.1X5
.9.6X4
.8.5X4
'•.7.5X4
-.6.4X4
'.S. 3X4
.4.3X4
'.3.2X4
.2.1X4
'•.1.1X4
 0.0X0
     22:36  32:48 23:00  23:12 23:24  23:36 23:48  24:00 24:12  24:24 24:36
r±la:P980095  tl-922 Aotjt7-JZS-98  00:57:56 XH- Voltage SIX 70P
315.9419 Xrp:DB225
TRIANGLE LABS  Textsl41-144 TLH44376A
                                                                             24:48 25:00  25:12  25:24
1001
 95.
 90.
 85.
 80.
 75.
 70.
 65.
 60.
 55.
 50.
 45:
 40.
 J5:
 30:
 25.
 20.
 IS.
 101
  5j
                     23:06
                                                                                                        1.5X6
                                                                                                       ':!. 4X6
                                                                                                       .1.4X6
                                                                                                       .1.3X6
                                                                                                       '•.1.2X6
                                                                                                       .1.1X6
                                                                                                       .1.1X6
                                                                                                       .9. 9X5
                                                                                                       .9.2X5
                                                                                                       .8.4X5
                                                                                                       17.6X5
                                                                                                       ':6.9X5
                                                                                                       .6.1X5
                                                                                                       .5.3X5
                                                                                                       .4. 6X5
                                                                                                       .3.8X5
                                                                                                       '-.3.1X5
                                                                                                       .2.3X5
                                                                                                       -.1.5X5
                                                                                                       .7.6X4
    '22\36' 221:48  23:00 23:12 23:24  23*36 23:48 24*00  24*12 24*24 24*36  24*48  25*00 25:12  25*24
                                                                                                        0.0X0
                                                                                                          Time,
                                                                                                                 o

-------
 fHa:P980095 #1-922 Acqi7-JMf-3B 00:57:56 Sir  Voltage sis  70P aoiae:557
 303.3016 BSUB(256,30r-3.0) PXD( 5,3,1, 0.10\,2238.0,0.00\,r,T) Xxp,DB225
 3SIAHSLX LASS  Tert:141-144 XLIH4376A
 1001                                A4.J.7Z6
  80.

  SO.

  40.

  20.
A1.55X6    JU..99X6

       A1.73X6.
                       A7.41X5
                                  A7.74X5
                                                A7.06X5
                                                                              A3.14X5
           19100       20:00       21:00        22iOO       23:00       24:00
T±1»,P9B009S tl-922 Acq:7-JJOt-98 00:57:56 £Z> Voltaga SIS  70P XoiBa:865
305.8987 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,3460.0,0.00\,r,T) ExpiDB225
XXIASGLX LASS   Tait: 141-144 TLI944376A
100*                               AS.47X6
                                                                                     25100
          19:00        20:00       21:00       22:00        23:00       24:00
r±le:P98009S fl-922 Acq:7-JAlT-98 00:57:56 SH- Voltage SIX 70P lToiae:77S
315.9419 BSUB(256,30,-3.0)  PXD(5,3,1, 0.10%,3104.0, 0.00\,T,r) SxptDB225
TSIAXGLE LABS  Text: 141-144 TLH44376A
1004                                                        A5.44E6
 80.
 60.
 40.
 20.
                                                                                    25:00
          19:00        20:00       21:00       22:00       23:00        24:00
TilatP9B0095 fl-922 A€sqi7-JAS-98 00:57:56 EH- Voltage SIS 70P JToiae>649
317.9389 BSVB(2S6,30,-3.0)  PXD(S,3,1, 0.10\,2596.0, 0.00\,r,T) Exp:DB225
TSIASSLS LABS  Text! 141-144 TLH44376A
100\                                                       A7  6E6
  80.

  60.

  40.

  20:

  0.
                                                                                    25:00
          19:00        20:00       21:00       22:00       23:00
r±la:P98009S fl-922 Acq:7-JAS-98 00:57156 EH- Voltage SIS 70P
375.8364 Sxp:OB225
TSIAOSU: LABS  Teztl 141-144 TLIf44376A
100*18:33
 80.

 60.

 40.

 20.

  0.
                                                     24:00
                                                                  25:00
 6.6X5

'.5.3X5

.4.0X5

.2.7X5

.1.3X5
                                                                                                  0.0X0
                                                                                                     Tia
                                                     A9.93X5
                                                          A7.76X5 A9.42E5
                                                                              -1.5E6

                                                                              .1.2X6

                                                                              .9.1E5

                                                                              '.6.1X5

                                                                              .3.0E5
                                                                                                  0.0X0
                                                                                                     TJjae
.1.9E6

1.5X6

1.1X6

7.7X5

3.8X5

0.0X0
    Time
                              "I05      32,5623,24   a4>05
          19:00
                      20,00
                                   21:00
                                               22,00
                                                           23,00
                                                                        24,00
                                                                                    25,00
.2.8X4

.2.2X4

.1.7X4


.1.1X4

.5.5X3

.0.0X0
    Time
                                                                                                           07
                                                                                                           o I

-------
FiJ.*iP9a0095 tl-Ull Acqt7-JAN-9B 00:57:56 SI+ Voltage SIX 70P None 1 4 79
319.8965 BSUB(256,30,-3.0) PXD(5 ,3,1,0. 10\,1916. 0,0 .00\,T,r) XxpsDB225
TRIANGLE LABS Text: 141-144 TLIt44376A
ion
80.
60.
40.
'20.

0
1'

A9.22E5
t


1 1 A1.44X5 A3. 35X5

	 20*00 21*00 22*00' ' ' ' '23*00 	 24*00 	 25
-.5.3X5
.4.2X5
.3.2X5
.2.1X5
J..1XS


1 00 Mae
flle:P9B0095 tl-922 Aeq:7-JJOT-98 00i57i56 XH- Voltage SIB 70P Boisot661
321.8936 BSVB(256t30,-3.0) PKD(5,3,1,0.10\,2644.0,0 .00\,F,r) XxptDB225
TRIANGLE LABS Text: 14 1-144 TUt44376A
100S
80.
60.
40.
20.

0.


A1.21X6
|


1 1 A1.80X5 A2.97X5
1 1 A /v A xv ^^*J\^
	 20*00 	 21*00 	 22*00 	 23*00 24.-00 	 25
-6.7X5
.5.3X5
.4.0X5
.2.7X5
.1.3X5

0.0X0
: 00 Mae
T±latP98009S tl-922 Acqi7-J3UT-98 00t57i56 XI+ Voltage SIS 70P Soiaei726
327.8847 BSUB<256, 30, -3. 0) PKD( 5 ,3,1,0.10\,2904 .0,0.00\,T,T) XxptDB225
TRIANGLE LABS Text:141-144 TLH44376A
1001
80.

60.
40.
20.
0.
A7.95X6

A5.06E6
I

T
_^y\_>^ 1 \ / \ y^
	 20*00 21*00 22*00 ' ' ' '23*00' ' 24*00 25
_2.3r5
.1 . 8X6

.1.4X6
.9.2X5
.4.6X5
0.0X0
00 Mae
rileiP980095 tl-922 Acq:7-JKK-96 00*57*5* XH- Voltage SIX 70P Noise 1 745
331.9368 BSUB(256, 30, -3.0) PKD(5 ,3,1, 0.10\, 2980 .0,0. 00\,T,T) Exp;DB225
TRIANGLE LABS Text: 141-144 TLH44376A
1003
80J

60.
40.
20.

AS. 14X6

*
A3. 68X6 II
1 1 1



H l\
20*00 21*00 22 i 00 23*00 24*00 25i
_1 . 4X6
.1.1X6

.8.5X5
.5.7X5
.2.8X5
0.0X0
00 Mae
File:P9B009S tl-922 Acqt7-JXK-98 00*57*56 EH- Voltage SIX 70P Hoiaei434
333.9338 BSUB(2S6,30, -3.0 ) PJO3( 5,3,1, 0.10\,1736. 0,0. 00\,r,f) XxpiDB225
TRIANGLE LABS Tmxtl 141-144 TLIt44376A
1001
80.
60.
40.
20.
0.
A6.28X6
A
A4.IS0XSJI



l\ l\
20*00 21.-00 22*00 	 23*00 	 24*00 25
_1 . 715
.1.4X6
.1 . 0X6
.6.8X5
.3.4X5
0.0X0
00 Mae

-------
rilo:P980095 #1-922 Acq:7-J7UT-98 00:57:56
303.9016 Xxp:DB22S
ZXZAMCLX LABS Taxt:141-144 1XJ#4437S.»
1003
80.

50.
40.
20.
ii
fl
15:44 ^0:38 1
1 20*20 1 1 1
, fl ii fl 1
11 W\LN^\J[ 1 1
19:00 20:00 21:00
rilaiP980095 11-922 Aexj:7-JXH-98 00:57:55
315.5415 Xxp.££225
TSIASSLX LABS Text: 141-144 TLH44376A
1001
80.
SO.
40.
20:







19:00 20:00 21:00
rila:P980095 #1-522 Acq: 7- JAR-98 00:57:56
319.8965 Exp:DB225
TRIANGLE LABS Text: 14 1-144 TLH44376A
1001
80:
50:
40:
20:
•

15:17

15:51


20:30 ^j.j
11 ] \ A_ /^J\ •'^
15:00 201ob 21.-00
rile:P980095 #1-522 Acq: 7-JAK-98 00:57:56
331.9368 Zxp«DB225
IEJAMELS IABS Tart:141-144 TLIf44376A
1001
80:
50:
40:
20:
o:






15:00 20.' 00 21:00
riIa:P980095 #1-522 Acq:7-JAX-9S 00:57:56
252.5825 Elp:DB225
TXIASGLE LABS Text:141-144 TLIt44376A
1001
80.
50:
40:
20:
0:
19:0319:30 20:07 20:38 21:11
r-H vVv»y\ -.j^ "^^ u^-WN^T~^r-yv~**~~
-------
.  tass    292.9825
    2.42 volts
                        Peak top
Systa file naie
Data   fllenaie
Resolution
Group nutter
lonlzatlon lode
Switching
   . lasses   292.9825;
fl   292.9825
8   383.9816
D   315.9419
E   317.9389
F   319.8965
6   321.8936
H   327.8847
    338.9792
                 J
                 K
                 L
                 H
       1
     El*
 VOL1RGE
388.9761
38,9732
331.9368
333.9338
375.8364
Channel   I  338.97%    Peak top
Height  1.73 volts  Span   288 ppi
                                                         100

-------
 TLI Project:     44376A
 Client Sample:   153-156  '
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U980028
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received:
194-59-11A-D Date Extracted:

1.000
n/a
DB-5
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
KAS
Spike File:
ICal:
ConCaL
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1.2J.7.8-PCCDD
l,Z3,4,7,8-HxCDD
1.2.3,6,7,8-HxCDD
1,2.3,7,8,9-HxCDD
1,2.3,4.6,7,8-HpCDD
1,2.3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
|2J,4,7,8-HxCDF
K23,6,7,8-HxCDF
2.3,4,6,7,8-HxCDF
1,2.3,7.8,9-HxCDF
1.2^,4,6.7,8-HpCDF
1.2J.4,7,8.9-HpCDF
1,2^,4,6.7,8,9-OCDF

Totals
Total TCDD •
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
AW^;|»g) Bt;, £MPC
0.68
4.0
4^
13
103
43.1
69.6
65.2
15.6
29.4
101
34.9
53.2
3.1
163
24.8
144

Amt M Number Dt EMPC ,
.v f "•
72.0 12
65.7 10 97.8
93.7 7
86.7 2
364 16
398 17 399
413 13
270 4
Ratio
0.79
1.61
1.20
1.25
1.23
1.03
0.84
0.75
1.59
1.51
1.24
1.25
1.26
1.29
1.05
1.04
0.87










FTT
25:21
29:36
32:44
32:49
33:06
36:03
39:36
24:40
28:35
29:16
32:02
32:09
32:37
33:22
35:01
36:33
39:49










Ftags
PR-




ill

E_


E~
iZ
PR_
E_

E_

.Flags
E_


iZ
E
E_
E
E_
                                       Page 1 of 2
                                                                       MIT2_PSRvl.OUlARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:17 01/10/98

                                 101

-------
 TLI Project      44376A
 Client Sample:   153-156
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:   U980028
_, ^
; Internal Standards
I3C12-2,3,7,8-TCDF
I3C,r2,3,7,8-TCDD
13C,rU,3,7,8-PeCDF
13C,rU,3,7,8-PeCDD
13C,rl^3,6,7,8-HxCDF
13C,rU,3,6,7,8-HxCDD
13C12-U^,4,6.7,8-HpCDF
13Cl2-U,3,4,6,7,8-HpCDD

Surrogate Standards {Type A)
13C12-2,3,4,7,8-PeCDF
13C12-U,3,4,7,8-HxCDF
IJC,2-U,3,4,7,8-HxCDD

Surrogate Standards {type A>
37CL,-2,3,7,8-TCDD
Alternate Standards {Type A)
13C12-U,3,7,8.9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
Recovery Standards
I3C12-1Z3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
' « r-.J*
Affl€< {p0c ..
.2.4
2.1
2.4
2.0
13.
3.0
2.8
2.7
4.9

An&fcigJ5
3.6
4.4
3.8
3.9

An&fcigl
3.5
Amt. (rJ9^
2.6
2J
V \i Av '

...i\. «>, >.
J;ff^ ^BePVfif^
61.0
53.3
59.1
50.0
58.4
74.3
69.6
68.7
61.3

v, ^Recovery
90.7
109
93.8
97.7

';f>fcecwery
87.9
^ % Recovery
65.0
63.5
^ , -



40%-130%
40%-130%
40%-130%
40%-130%
40%-1309fc
40%-130%
25%-130%
25%-130%
25%-130%


40%-130%
40%-130%
40%-130%
40%-130%

%

-
40%-130%
40%-130%



•"BaHO
0.75
0.80
1.49
1.49
0.51
1.20
0.45
1.04
0.86

Ratto
1.53
0.51
1.20
0.44



Ratio
0.51
OJ1
Ratio
0.82
1.18

- -RT
24:38
25:20
28:34
29:35
32:08
32:48
35:01
36:02
39:36

RT
29:15
32:02
32:44
36:32

nrr
25:21
RT
33:22
32:37
RT
25:09
33:07
f
Flags
—

Ffags
—

Ftags
—
Ffags
—
Flags
—
                     Data Reviewer
            01/10/98
                                        Page 2 of 2
                         MTT2_PSRvl.01,LARi 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 10:17 01/10/98
                                   10°
                                   J_ L/ •-»

-------
                         Initial
                                     ..Date.
  Data Review By:
                                              Calculated Noise Area:
  The Total  Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according  to method requirements.
                                                                      2.00
  Page No.     1
  01/10/98

  Compound/
  M_Z.... QC.Log Omit Why
Listing  of 0"980028B.dbf
Matched  GC Peaks / Ratio  /  Ret. Tine
.RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
KN
K
K
K
K
K
K









304-306
13C12-TCDF
316-318










316-318
TCDD
320-322
KN
NK
K
K



DC NL 0
21
21
22
22
22
23
23
. 23
24
24
24
24
25
25
25
26
0
:00
:29
:59
:13
:37
:56
:20
:36
:50
:03
.65-0.89
0
0
0
0
0
0
0
0
0
.77
.74
.76
.75
.75
.74
.75
.74
.74
0.74
:14 0.75
:28
:40
:04
:17
:32
:23
0
.74
0.75
0.
0.
0.
0.
16 Peaks

DC NL 0:
DC WL 22 ;
DC WL 22 :
23:
24:
24:
25:
DC WH 26 :
DC WH 26:
DC WH 26 :
DC WH 26:
0
:00 RO
:25 RO
:59
53
04
38
17
10
38
47
56
,75
,74
,79
74
1,
2,630.52
50,196.40
48,271.20
49,955.70
251,645.00
154,767.30
166,704.30
118,319.60
.163, 606.00
201,437.50
66,543.00
65, 614.80
325,383.00
71,034.80
65,011.50
11,106.90
8,372.51
817,969.51

21
20
21
107
65
71
50
69
85
28
27
139
30
27
4
3


,398
,851
,396
,507
,946
,219
,474
,813
,969
,536
,935
,111
,362
,682
,905
,565


.50
.30
.90
.00
.20
.60
.70
.10
.50
.10
.40
.00
.20
.00
.08
.69


28,797
27,419
28,558
144,138
88,821
95,484
67,844
93,792
115,468
38,006
37,679
186,272
40,672
37,329
6,201
4,806

.65-0.89
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4 Peaks

DC NL 0:
22:
23:
23:
24:
24:
24:
0.
00 RO
49
11
30
10
26
50
65-
0.
0.
0.
0.
0.
0.
0.
34
98
81
74
87
75
67
84
82
73
65
61.61
261.41
653.35
. 72.73
537.38
16,107.16
303.79
217.36
803.61
164.10
' 31.62
17,021.06
0.89
24
77
77
79
77
80
81
24.67
86,137.90
56,734.10
7,285.58
26,419.10
15,780.03
7,408.23








30
249
6,904





122







.94
.75
.38
.02







41
287
9,202.
181,




0.867-1.079

.90
.90
.80
.00
.10
.70
.90
.90
.00
.90
.40
.00
.60
.50
.82
.82

0.000
0.872
0.892
0.902
0.918
0.931
0.947
0.958
0.968
0.976
0.984
0.993
1.001 2378-TCDF AN
1.018
1.026
1.037
1.071

0.959-1.041



.79
.63
.78
.77




0.000
0.910
0.933
0.970
0.977
1.000 13C12-2378-TCDF ISO
1.026
1.062
1.081
1.087
1.093



37,
24,
3,
11,
7,
3,

506.
721.
219.
473.
017.
324.

60
90
40
80
40
43

48,631.
32,012.
4,066.
14,945.
8,762.
4,083.
0.895-1.047

30
20
18
30
63
80
0.000
0.901
0.915
0.928
0.954
0.964
0.980
                                                                                                         E
                                                                                                         E
                                                                                                         E
                                                                                                         E
                                                                                                         E
                                                                                                         E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 10:1701/10/98
                                                                                    103

-------
  Page No.     2
  01/10/98

  Compound/
  M_Z.... QC.Log Omit Why
Listing of U980028B.dbf
Matched GC Peaks / Ratio / Ret. Ti»e
.RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
M
AN




320-322
37C1-TCDD
328














328
13C12-TCDD
332-334




332-334
PeCDF
340-342









M
AN



25:15
25:21
25:31
25:41
25:54
26:20
12 Peaks

DC NL 0:00
DC ML 22:48
DC WL 23:06
DC WL 23:12
23:25
23:59
24:11
24:19
24:39
24:51
25:21
25:45
26:34
26:39
26:47
11 Peaks
0.
DC NL 0:00 RO
25:09
25:20
25:39 RO
25:51 RO
4 Peaks
1.
DC NL 0:00 RO
26:35
27:03 RO
27:13
27 : 20
27:35
27:43
27:53
28:12
28:18
28:30
28:35
28:44
28:51
29:16
0.77
0.79
0.79
0.79
0.86
0.76


















.65-0.89
1.51
0.82
0.80
0.94
1.15
26,800.00
2,255.00
3,594.40
3,957.14
1,387.98
1,360.13
239,119.59

48.70
447.36
522.57
418.96
173.49
17,808.20
457.32
220 . 65
457.92
147.39
9,435.46
10,441.10
46.89
84.66
71.47
39,344.55
11,700.00
995.00
1.589.40
1,750.86
640.69
586.35






173.49
17,808.20
457.32
220.65
457.92
147.39
9,435.46
10,441.10
46.89
84.66
71.47

15,100.00
1,260.00
2,005.00
2,206.28
747.29
773.78

0.
















0.997
1.001 2378 -TCDD AN PR
1.007
1.014
1.022
1.039

921-1.079
0.000
0.900
0.912
0.916
0.924
0.947
0.955
0.960
0.973
0.981
1.001 37C1-TCDD CLS
1.016
1.049
1.052
1.057

0.921-1.079
25.75
18,000.51
10,720.27
387.77
64.92
29,173.47
32-1.78
0.96
1.54
0.87
1.51
1.53
1.51
1.51
1.52
1.50
1.51
1.56
1.59
1.50
1.52
1.51
10.74
116,622.40
1,999.02
3,176.74
3,233.73
40,046.10
272,815.00
65,871.20
107,989.30
142,981.10
59,600.00
49,700.00
46,647.40
78,599.60
90,819.20

8,102.57
4,777.34
205.03
42.16

PeCDF Follows -

70,759.50
1,215.09
1,909.19
1,953.87
24,081.60
164,272.00
39,732.10
64,849.80
86,000.20
36,300.00
30,500.00
28,015.10
47,360.10
54,641.80

9,897.94
5,942.93
219 . 08
36.68

0.000
0.993 13C12- 1234 -TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.020

0.925-1.065

45,862.90
1,391.10
1,267.55
1,279.86
15,964.50.
108,543.00
26,139.10
43,139.50
56,980.90
23,300.00
19,200.00
18,632.30
31,239.50
36,177.40
0.000
0.931
0.947
0.953
6.957
0.966
0.970 E
0.976
0.987
0.991 E
0.998
1.001 12378-PeCDF AN
1.006
1.010
1.025 23478- PeCDF AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:17 01/10/98
                                                                                104

-------
  Page  Ho.     3
  01/10/98

  Compound/
  M_Z.... QC.Log Omit why
Listing of 0980028B.dbf
Matched GC Peaks / Ratio / Ret. Tine
.RT.  OR Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.




340-342
13C12-PeCDF
352-354













29
29
30
30
:25
:44
:07
:15




1.51
1.50
1.39
1.52
18 Peaks

DC ML 0
26
26
26
27
27
27
27
28
28
28
28
29
29

:00
:24
:37
:47
:14
:26
:47
:56
:11
:18
:34
:51
:03
:15
29:52


352-354
PeCDD
156-358
D












356-358
13C12- PeCDD
368-370





30
30:
:06
:15
1
RO
RO





RO

RO


RO

RO
RO

16 Peaks

DC NL 0:
DC WL 27 :
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:

00
35
49
18
32
40
51
01
07
19
27
36
44
04
1.
RO
RO
RO







RO



.32-1.78
1.20
1.10
1.47
1.48
1.67
1.39
1.45
1.24
1.37
3.81
1.49
1.48
1.26
1.53
0.90
0.94
1.69
130,996
29,270
324
10,891
1,251,584

10
28
130
54
15
66
174
367
42
95
12,138
272
100
10,638
53
35
123
.70
.60
.47
.45
.01

.51
.66
.94
.98
.70
.77
.21
.46
.78
.80
.84
.09
.96
.24
.39
.68
.08
24,339.58
32-1.78
1.14
0.88
1.19
1.32
1.56
1.61
1.57
1.61
1.58
1.57
0.84
1.61
1.60
1.69
12 Peaks

DC NL 0:
27:
27:
DC SN 27:
28:
28:

00
43
48
58
17
32
1.
RO
RO
RO
RO
RO
RO
32-1.78
1.98
1.31
3.02
0.58
2.46
1.24
78,741
17,542
188
6,577



17
78
32
9
38
103
223
24
143
7,264
162
61
6,432
32
.50
.00
.39
.74



.42
.01
.77
.83
.89
.05
.36
.70
.28
.06
.59
.37
.31
.45
21.69
77
.27
52,255
11,728
135
4,313



15
52
22
5
27
71
180
18
37
4,874
109
48
4,205
36
23
45
.20
.60
.58
.71

0.

.82
.93
.21
.87
.88
.16
.41
.08
.57
.78
.50
.62
.93
.00
.00
.81
1.030
1.041
1.054
1.059

860-1.140
0.000
0.924
0.932
0.938
0.953
0.960
0.973
0.978
0.987
0.991
1.000 13C12-PeCDF 123 IS2
1.010
1.017
1.024 13C12-PeCDF 234 SUR1
1.046
1.054
1.059


0.935-1.022
7.35
425.31
51,633.22
4,247.
38,427.
7,969.
24,756.
4,087.
9,159.
10,217.
5,226.
7,022.
5,582.
4,798.
173,129.
52
00
85
16
86
61
95
58
96
53
56
80
31,384.
90
2,419.07
23,428.
4,914.
15,138.
2,519.
5,606.
6,238.
3,176.
4,335.
3,438.
3,013.

70
28
50
35
93
38
94
08
36
61

26,426.
1,828.
14,998.
3,055.
9,617.
1,568.
3,552.
3,979.
3,764.
2,687.
2,144.
1,784.

90
45
30
57
66
51
68
57
62
88
17
95

0.000
0.932
0.940
0.957
0.965
0.969
0.975
0.981
0.984
0.991
0.995
1.001 12378-PeCDD AN
1.005
1.016

0.865-1.135
3.
32.
24.
3.
30.
37.
67
97
89
54
06
21

20.
29.

29.
22.

04
46

04
62

15.
9.

11.
18.

33
76

79
17
0.000
0.937
0.940
0.945
0.956
0.965
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:17 01/10/98
                                                                                105

-------
  Page  No.
  01/10/98
Listing  of (J980028B.dbf
Matched  GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak. 1.. Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.











368-370
HxCDF
374-376
DC SN 28
28
28
DC SN 29
29
29
29
29
29
30
30
:40
:48
:50
:07
:17
•26
:35
:43
:57
:07
:18
1
RO 4
RO 1
RO 5
RO 3
RO 1
1
1
RO 3
1
RO 5
13 Peaks
.53
.10
.05
.70
.82
.04
.49
.51
.96
.42
.02
4.95
7.93
18.85
3.80
12.06
11.70
5,311.54
922.58
22.57
15.61
14.41
6,462.38
1.05-1.43
DC ML 0
:00
31:05
31:13
31:23
31:31







AN
M
374-376
13C12- HxCDF
384-386







384-386
HxCDD
390-392





31:
31:
32:
32:
32:
32:
32:
33:
33:
:41
:51
:02
09
:15
26
37
22
28
1.26
1.24
1.23
1,
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
.31
,23
,22
24
24
25
26
23
26
29
24
13 Peaks
2,385.35
91,814.00
218,055.60
18,173.42
28,238.70
15,040.77
2,443.34
207,127.80
89,263.20
25,468.60
38,349.70
107,065.70
5,450.00
27,100.00
873,590.83

12.76
11.46

18.07
7.11
3,175.06
555.36
35.09
9.15
28.39

HxCDF Follows -

50,882.00
120,371.00
10,298.30
15,563.60
8,259.31
1,352.36
114,716.00
49,531.70
14,178.00
21,184.50
59,699.30
3,070.00
15,000.00


3
10

4
6
2,136
367
a
6
5


.11
.93

.73
.82
.48
.22
.85
.46
.65

0
0
0
0
0
0
1
1
1
1
1

.969
.974
.975
.984
.990
.995
.000 13C12-PeCDD 123 IS3
.005
.012
.018
.024













0.962-1.047


40,932.00
97,684,
7,875.
12,675.
6,781.
1,090.
92,411.
39,731.
11,290.
17,165.
47,366.
2,380.
12,100.

0.43-0.59
DC NL 0:
31:
31:
32:
32:
32:
32:
33:
00
13
49
02
08
37
55
22
RO 1.
RO 0.
RO 1.
0.
0.
0.
RO 1.
0.
7 Peaks

DC NL 0:
31:
32:
32:
32:
32:

00
34
01
13
23
44
1.05-
RO 0.
1.
1.
1.
1.
1.
78
83
57
51
51
51
26
51
45.39
243.20
48.06
7,363.14
8,165.43
8,009.52
136.17
6,321.05
30,286.57
- Above : HxCDF /•
1.43
71
28
22
23
09
20
342.86
15,273.11
65,269.00
36,447.40
5,933.51
6,621.84

133.86
49.32
2,499.07
2,744.46
2,711.19
113.37
2,129.77



8,582.45
35,910.10
20,074.60
3,093.97
3,611.36

161.
31.
4,864.
5,420.
5,298.
90.
4,191.

,60
,12
10
46
98
80
50
60
20
40
00
00

0
.000
0.967
0.971

E
E
0.977
0.981
0.986
0,
0.
1.
1.
1.
1.
1.
1.

0.876-

06
83
07
97
33
18
28

0.
0.
0.
0.
1.
1.
1.
1.

,991
,997 123478-HxCDF AN
,001 123678-HxCDF AN
004
009
015 234678-HxCDF AN
038 123789-HxCDF AN
041

•1.124
000
971
990
997 13C12-HXCDF 478 SCTR2
000 13C12-HXCDF 678 IS4
015 13C12-HXCDF 234 ALT2
024
038 13C12-HXCDF 789 ALT1


E



E
PR












0.958-1.014

6,690.
29,358.
16,372.
2,839.
3,010.

66
90
80
54
48
0.
0.
0.
0.
0.
0.
000
962
976
982
987
998 123478-HxCDD AN






Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:17 01/10/98
                                                                                106

-------
  Page No.     5
  01/10/98

  Compound/
  M_Z.... QC.Log Omit why
Listing  of  0980028B.dbf
Matched  GC  Peaks / Ratio /  Ret. Tine
.RT.  OK  Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. .  Rel.RT Compound.Name..  ID.. Flags.


390-392
13C12-HXCDD
402-404




402-404
HpCDF
408-410



D

408-410
13C12-HpCDF
418-420


418-420
HpCDD
424-426
D


424-426
13C12-HpCDD
436-438



436-438
OCDF
442-444

442-444
32:49
33:06
7 Peaks
1
DC ML 0:00 RO
32:02
32:44
32:48
33:07
4 Peaks
0
DC NL 0:00
35:01
35:17
35:27
DC NH 35:55 RO
36:33
4 Peaks
0.
DC NL 0:00 RO
35:01
36:32
2 Peaks
0.
DC NL 0:00 RO
DC WL 35:09 RO
35:18
36:03
2 Peaks
0.
DC NL 0:00
35:18 RO
35:32 RO
36:02
3 Peaks
0.
DC NL 0:00 RO
39:49
1 Peak
1.25
1.23

.05-1.43
2.20
1.05
1.20
1.20
1.18
13,637.12
18,619.27
161,801.25

15.03
38.07
5,273.12
7,681.27
10,392.68
23,385.14
.88-1.20
1.01
1.05
1.05
1.05
0.54
1.04

.37-0.51
1.95
0.45
0.44
96.36
341,420.00
69,346.40
84,856.20
340.41
40,502.50
536,125.10

19.54
5,949.70
4,660.82
10,610.52
88-1.20
1.37
0.45
1.01
1.03

88-1.20
1.06
0.72
3.80
1.04
43.86
1,026.39
56,202.30
55,523.30
111,725.60

19.54
51.02
8.59
5,180.07
5,239.68
76-1.02
4.73
0.87

28.10
171,627.70
171,627.70
7,586.71
10,251.40



19.48
2,875.21
4,196.41
5,623.36



174,926.00
35,498.90
43,549.30

20,652.40



1,836.50
1,432.01




28,303.50
28,199.40



26.01
15.99
2,635.16

Octa-CDD and CDF

80,077.40

6,050.41 1.001 123678-HxCDD AN
8,367.87 1.009 123789-HxCDD AN

0.970-1.030
0.000
18.59 0.977
2,397.91 0.998 13012-HxCDD 478 SUR3
3,484.86 1.000 13C12-HXCDD 678 IS5
4,769.32 1.010 13C12-HXCDD 789 RS2

0.996-1.049
0.000
166,494.00 1.000 1234678-HpCDF AN
33,847.50 1.008
41,306.90 1.012
1.026
19,850.10 1.044 1234789-HpCDF AN

0.943-1.114
0.000
4,113.20 1.000 13C12-HpCDF 678 IS6
3,228.81 1.043 13C12-HpCDF 789 SOR4

0.975-1.005
0.000
0.975
27,898.80 0.980
27,323.90 1.000 1234678-HpCDD AN

0.972-1.028
0.000
36.28 0.980
4.21 0.986
2,544.91 1.000 13C12-HpCDD 678 IS7

Follows 	
0.899-1.101
0.000
91,550.30 1.005 OCDF AN













E

E











E
E









E

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 10:17 01/10/98
                                                                                  107

-------
  Page No.
  01/10/98
         Listing of  0980028B.dbf
         Matched GC  Peaks  / Ratio /  Ret. Time
  Compound/
  M_Z....  QC.Log Omit Why . .RT. OK Ratio Total.Area...  Area.Peak. 1. . Area.Peak. 2. .  Rel.RT Compound.Name..  ID..  Flags.
  OCDD
  458-460

  4S8-460
               0.76-1.02
DC  NL   0:00     1.00          11.06
        39:36     0.84      66,941.80
                       1 Peak
                                            66,941.80
                                        30,632.60
             0.899-1.101
                 0.000
      36,309.20  1.000 OCDD
                                                                                     AN
  13C12-OCDD                    0.76-1.02
  470-472        DC  NL   0:00 RO  2.02          3.57
                         39:36     0.86      6,941.79
  470-472              1 Peak                6,941.79
                                         3,215.80
             0.996-1.004
                 0.000
       3,725.99   1.000 13C12-OCDD
                                                                                     IS8
  Column  Description	   "Why"  Code Description	  QC Log Desc.
  M_Z   -Nominal Ion Mass(es)
  ..RT.  -Retention Time (mm:38)
  Rat.l  -Ratio of M/M+2 Ions
  OK    -RO-Ratio Outside Limits
  Rel.RT-Relative Retention Time
      End of Report *•*
               WL-Below Retention Time Window
               WH-Above Retention Time Window
               SN-Below Signal to Noise Level
               
-------
r±le:O98002S tl-723 Acq: 6-JKN-1996 18:57:10 GC EI+ Voltage SIS 70S Soiae:571803
303.9016 T:2 BSUB(256, 30, -3.0) PXD(9,5,3,0.10\,23a7313.0,1.00\,r,T) SxptSDBSUS
TRIANGLE LASS TeJCt:TLIt44376A 153-156
1001

ao.
60.
40.
20.
Al.
•

A3.60E8
A
A1.0SE9 AS. OSES l\
A2.14E8 /SA A A /W\A 'A
A /\ /V / V^JVJ^J 1 V/VA/
'22:00 	 23:00 ' ' ' 24:00

9E9 ,.3.3X8



A3. 04X8
I A/v r

L2.528
Li. 0*8
Li.3r»
Ls.sr?
25 loo ' ' '25:00' Time
rila:USa0028 tl-723 Acq: 6- JAN- 19 9 8 10:57:18 GC EI+ Voltage SIS 70S Soiae:743456
305.8987 Ti2 BSOB(256,30,-3.0) PXD(9, 5, 3,0 .101,3973824. 0,1. 00\rf,T) SxpiSDBSUS
TRIANGLE LASS Teit:TLIt44376A 153-156
loot
80.
SOJ
40:

20:
o'-
Al.t

A1.15E9 1
A1.44X9 A
A AW • /OJStS 1 1 1

/ \X\ ^\ ft l\ h I I 1
'22:00 ' ' 23:00 . 24:00

1X9



A4 . 07X8
A/\ .
_4.
-------
 rila:U9a0028 tl-733 Acqt  6-J3Ul-1998 18,57:18 GC XI+ Voltage SIS 70S Hoiae:5363
 319.8965 Ts3 BSOB(356r30, -3.0) PXD(7,5,3,0.10\e314S2.0t1.00\,TtT) XxptUDBSUS
 TRIANGLE LASS  Teit:TLIt44376A 153-156
 1001
  80.

  60:

  40:

  30:

   0.
             A3.4 7X8
                   A3.33X7
                                  41.1520
                                                         A1.29X8
                                       A7.03X7 A3.32X7    V\
                                   J..±3f
                                   A
         23,00                 34,00                 35,00                36,00
riletO980038  tl-733 Acqt  6-JAN-1998 19,57*18 GC SI+ Voltage SIS 70S Soiae,22793
331.8936 f:3  BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,9il73.0,1.00*,T,T) XxptBDBSOS
TSIANGLE LASS  Text:TLIt44376A 153-156
1001
  00:
  60:

  40:
  30:

   ol
             A3.30X8
                                 A1.49X8
                   A4.07E7
                                   A
                                       A8.76X7  A4.08E7
                                                         Al.S5E8
         23:00                 34,00                 35,00                36,00
Tlle,U980038 tl-733 Acqt  6-J2OT-1998 18,57:18  SC EI+ Voltage SIS 70S Noise: 10992
331.9368 T,3 3SVB(356,30,-3.0) tXD(7,5r3,0.10\,4396a.O,1.00*,T,X)
TRIANGLE LASS  Text:TLIt44376A 153-156
1001                                                   A8.10E7
  80:
  60:
  40:
  so:
                                                           \4. 7SE7
         33:00                 34>00                 35:00                 36:00
T±la,0980038 tl-733 Acq: 6-JAH-1S98 18,57:18 GC EI+  Voltage  SIS  70S Soiae:7374
333.9338 T:3 SSU3(356,30,-3.0) ?XD(7,5,3,0.10\,39096.0,1.00\rT,X) Exp-.HDBSUS
TRIANGLE LASS  Text:TLH44376A 153-156
1001                                                   A9.90E7
 80:
 60:
 40:
 30:
  0:
                                                            5.94X7
         33:00                 24,00                 25:00                 36:00
r±J.e:U980028 H-733 Acq: 6-JMT-1998 18,57,18 GC XI+ Voltage SIS  70S Soiae,24352
337.8847 T:2 SSU3(356,30, -3.0) PXD(7,5,3,Q.10\,97408.0,1.00\,T,T) EzptNDBSUS
TRIANGLE LASS  Text:TLIt44376A 153-156
1001                         Al. 8X8
 80:
 60:
 40:
 20:
                                                                    Al.04X8
                                                           A9.44X7
         33:00                34,00                 25:00
r±le:0980038 tl-723 Acqt 6-JXS-1998 18,57,18 GC XH- Voltage SIS  70S
 30.9793 T,3 Xxp,NDB5US
TRIANGLE LASS  Tert,TLIt44376A 153-156
100*
 80.

 60:

 40:

 30:

  o:
           33:06 23:24
                             23:5524:11
                                                   24,55
                                                             35:34
                                                                          26,00
                                                                       35L52 _ 26ijL5_
 -7.8X7

 .6.3X7

 .4.7X7

 .3.1X7

 -1.6X7

  0.0X0
 -1.0X8

 .8.0X7

 -6.0X7

 '-4.0X7

 •-3.0X7
                                                                                                .0.0X0
                                                                                                    Time
                                                                                               -3.0X7

                                                                                                .1.6E7

                                                                                                .1.3X7

                                                                                                .8.1X6

                                                                                                .4.0X6
                                                                                                 0.0X0
                                                                                                    Time
                                                                                               -3.4X7

                                                                                               .1.9X7

                                                                                               -1.5X7

                                                                                               .9. 7X6

                                                                                               '-4. 8X6
                                                                                                .0.0X0
                                                                                                   Time
                                                                                               -4.0X7

                                                                                               .3.2X7

                                                                                               .2.4X7

                                                                                                 .6X7

                                                                                               -7.9X6
                                                                                                .0.0X0
                                                                                                   Time
-9.1X7

-.7.3X7

-.5.5X7

.3.7X7

:i. ax?
         33:00
                              34,00
                                                    35:00
                                                                          26:00
                                                                                               to. oxo
                                                                                                   Time
                                                                                                        110

-------
Fila:O980028 tl-723 Acq: 6-JAK-1998 18:57:18 SC EH- Voltage SIS 70S Koia»s3267
339.8597 f:2 BSUB(256, 30, -3.0) PXD(7,5,3,0.10\,13068.0,1.00\,r,T) Xlp:SDB5US
XSIANSLX LABS Text:TLIt44376A 153-156
1001
80.
60.

40.
20.

0
A1.64X9
n
I
11 AS. 60X8
A7.08X8 A A7.87Z8
A 1 l\*7 30X8 M 74E8 A A
l\ MA A/\AAAA /\/\
/\ A/lA /V\/V\A/\ \ \ **• 7Ssa
v A/ \/\^J TWWVv /vv /\
27:00 ' ' 28:00 25:00 J0:00
rilatU980028 tl-723 Acq: 6-JUT-1998 18:57:18 SC EH- Voltage SIS 70S Noiaa:3393
341.8567 T:2 BStJB(256f30r-3.0) PXD( 7,5, 3,0. 101,13572. 0,1.00\,r,T) XzptODBSUS
TSIAHSLX LABS Text:TLIt44376A 153-156
1001
80.
60.

40.
20.


Al. 139X9

AS. 70X8
A4.59X8 «.7BW AS. 23X8
Aft / IA4 . 83X8 A3 . 12X8 A 1 1
A / \ -w-rf*»w n^.j*+ao n II
A /\/ \ AA A A /\ I \
A/\A /V\/V\A/\ / \ \ &1.17X8
/ V v V_x-^ TwWvv /vv/x
27:00 29:00 25:00 JO: 00
r±la:U980028 tl-723 Acq: 6-JAX-199S 18:57:18 SC EH- Voltage SIS 70S Hoiee>3196
351.9000 f:2 BSUB(256,30,-3.0) PKD(7,5, 3,0.10\,12784 .0,1 .00\,T,T) XxpsSDBSVS
TRIANGLE LABS Text:TLIt44376A 153-156
1001

80-.
60:
40:
20.

A 7 26X7
{\ A6.43X7





27:00 ' ' 28:00 . ' ' ' ' 25:00 	 J0:00 '
T±loiU980028 tl-723 Acq: 6-JZK-1998 18:57:18 SC EH- Voltage SIS 70S Noiae:2655
353.8970 T:2 BSUB(2S6,30,-3.0) PED(7,S,3,0.10\,10620.0,1.00\,r,X) XzptRDBSVS
TSIASGLX LABS Text:TLIt44376A 153-156
1001
80:
60:
40:
20:
0'
A4.87E7
n A4.21E7
A
A


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.2.3X8

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'-.2.0X8
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-.5.1X7

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.1.1X7
.8.5X6
.5.7X6
.2.8X6
0.0X0
27:00 	 28.' 00 ' ' '25:00 	 JO: 00 i' Time
rlle:U9S0028 tl-723 Acq: 6-JXH-199S 18:57:18 SC EH- Voltage SIS 70S
330.9792 T:2 ElpiNDBSUS
TRIANGLE LABS Text:TLIt44376A 153-156
1001
80:
60:
40:
20:
o:
2ff:54 27:12 27:47 28j_10 2&i26^28^42 28:59 3^4J: 30:033°.
v V — — - ^^~




27:00 28:00 25:00 JO: 00
rllaiD9S0028 tl-723 Acq: 6-J3OT-1998 18:57:18 SC EH- Voltage 522 70S
405.7574 Tt2 ExptNDBSUS
TRIANGLE LABS Text:TLIt44376A 153-156
1001
80:
60:
40:
20:

o:
JO



15 JO:J7





.9.1X7
.7.3X7
.5.5X7
.3.7X7
.1 . 8X7
0.0X0
Time



19



n
27:55 28:17 38,33 29:27 25:58 1
"*• - **- - - i " 	 .-^-.A A- _*^«^^^. j^^— ^ MII-^ M n -^^ r^V A^h_ fS*^~ f**\f*~*
27:00 28:00 25:00 	 JO: 00

L 30:33
*AA-^W.
.6. 7X5
.5.4X5
.4.0X5
.2.7X5
.1.3X5

o.or.o
i , ™ 'i ' 	
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11

-------
 rU.a:(JSUOOja tJ.-lll Acq: 6-JAN-J.99B 18,57,18 SC £1+ Voltage SXB  70S Jfoj.ae,22JS
 355.8546 T,2 BSU3<256, 30, -3.0) PKD(5, 5,3, 0.05\,8940.0,1.00\,r,T) XxptSDBSDS
 TRIASSZX IA3S  TextsTLH44376A 153-156
 1001 A3.14X8                A3.34X8
  80.

  60.

  40.

  20.
A1.51X8
              A6.24X7
        AS. 61X7
A
                                                              A4.34X7
                                                                            A3.01X7
                                                                               /Y
      27i48  23:00  28tl2 2B>24 28,36  28,48 29,00 29tl2 29:24  29,36 29:48' jOsOO  30,12 30,24
nj.e,O980028 tl-723 Acqi 6-JAK-1993 18:57,18 GC XH- Voltage SIS 70S SOiae,196S
357.8516 Ti2 BSU3(256,30,-3.0) PKD(5,5,3, 0.051,7860.0,1.00\,r,T) XxpiSDBSOS
TRUOXXJS IAS3  Teit:TLIt44376A 153-156
1004 A2.64X8
      27: IB 28,00  28,12 28,24 28,36 28,48  29,00  29,12' 29V24' 29i36' 29', 4a' 30,00 30,12  30,24
r±le,a980028  tl-723 Acq:  6-JAS-1998 18,57,18 GC XH- Voltage SIS 70S Hoise: 1423
367.8949 T,2  BSUS(256,30, -3.0)  PXB(S,5,3,O.OS\,S692.0,1.00\,T,T) XjcptSDSSUS
TXIANGLX LASS Text:TLH44376A  153-156
1004                                        .                 A3.J.3E7

  80.

  60.

  40.

  20.
      27\48' Moo' 2 B': 12 28,24 28,36 28,48  29,00  29'sii' 29V24 ' 29,36' 29:48 30,00 ' 30,12 30,24 '
r±2e,a980028 tl-723 Acq:  6-J3OT-1998  18,57,18  GC XI+ Voltage  SIS 70S Soife:721
369.8919 r,2 BSUB(256,30, -3.0) PXD(5,5,3,0.05\,2884.0,l.QO\,r,T)  XxpsXDBSOS
TRIANGLE LABS  Tart*TZ.I§44376A 153-156
1001
 80.
 60.
 40.
 20:
                                                             A2.14X7
                                                                   .67X6
      27,48 28,00 28,12  28,24 28,36 28,48 29,00 29>12  29:24 29,36 29,48  30,00 30,12 30:24
rUa,U980028 91-723 Acq,  6-JJUi-199S 18,57,18 GC XH- Voltage  SIX  70S
330.9792 Tt2 XzptSDSSOS
TSIANGLX LABS  TexttTLIt44376A 153-156
1001.

 00.

 60.

 40.

 20.

  0.
    28,59
                   29,28
                                              30,19
                                           -7.4X7

                                           .5.9X7

                                           .4.4X7

                                           .3.0X7

                                           -L.5X7
                                                           0.0X0
                                                              Tlfl
                                                           0.0X0
                                                              Tlae
                                                         -9.4X6

                                                          .7.5X6

                                                          .5.6X6

                                                          .3.7X6

                                                          .1.9X6
                                                          0.0X0
                                                             Time
                                                          6.5E6

                                                         .5.2X6

                                                         .3.9X6

                                                         .2.6X6

                                                         J..3X6
                                                          0.0X0
                                                             Zlae
                                          .9.1X7

                                          .7.3X7

                                          .5.5X7

                                          .3.7X7

                                          .1.8X7
      27,48 28,00 28,12  28,24  28,36 28,48 29,00 29:12  29',24  29,36' 29:48  30:00 30:12 30,24
                                                          .0.0X0
                                                             TiMe\
                                                                                                           112

-------
\rile-0980028 ti-lSS Acq:  6^JXJr-1998 18:57:18 SC XI+ Voltage SIS 70S soiae:664910
373.8308 Tt3 BSUB(256,30, -3.0) PKD(7,5,3,0.iO\,265964Q.O,1.00\,r, T) ZxpiJOJBSOS
TSIAIKLX LABS  TaxtiXZ.H14376A 153-156
 1001

  80:
  40
   OJ
                                    A1.15X9
      A5.09X,
                    A1.56X8
                                                      AS.97X8
                                                                                 Al.63X8
     31:00 31', 12 31,34  31',36 31',48 32,00 32,12 32',24  32,36 32',48 33',00  33', 12 33',24 33:36 33:48
\ril»,O980028  tl-385 Acqt  6-J3UT-1998 18:57:18 SC XH-  Voltage SIS 70S Soiae,528014
375.8178  ri3  BSUB(256,30, -3.0) PXD(7,S,3,0.10\,2U2Q56.0,1.00\,r,T) XxptSDBSUS
TRIANGLX  lASS  T*xt:TLH44376A 153-156
1004     A9.77X8
                                    A9.24X8
  so
  40:
  201
      A4.09X\
                                                      A4.74X8
                                                                                A1.30E8
     JliOO  31:12 31,24 31,36  31:48 33',00 32', 12 32*24 32i36  33t48 33tOO 33sl2  33,34  33',36 33',48
file,0980038  tl-385 Acqi  6-JXK-1998 18,57:18 SC XH-  Voltage  SIS 70S Soiae,36734
383.8639 T:3  BSOB(356,30, -3. 0)  PXD(7,5,3,0.10\,106936.0,1.00\,r,T)  ExptlOJBSas
TRIANGLE LABS  XextsXLIt44376A  153-156
100$                               A2.fOX7           A3.71X7
  601

  401

  201
                                                                              A3.13X7

    3l':00  31:12 31:24 31:36  31:48 32:00 32:12 32:24 32s36  32:48 33:00 33:12  33:24  33:36 33:48
file,0980028 01-385 Acq:  6-JXX-1998 18:57:18  SC XH- Voltage  SIS  70S Soiae:15030
\38S.8610 r-.3 BSUB(2S6,30,-3.0)  PXD(7,5,3,0.10\,60130.0,1.00\,r,T)  Xxp:SDBSOS
TRIANGLE LABS   Tert:XLIt44376A  153-156
                                    A4.86X7
  SOJ

  50J

  401

  201
                                                      AS.30X7
                                                                             A4.19X7
    31:00  31': 12 31:24 31:36 31:48  32:00 32:12 32:24 32:36  32':48  33:00 33:13 33:24  33:36 33:48
r±letU980028 tl-385 Atxj: 6-JAS-1998 18,57:13 SC XH- Voltage  SIS 70S
393.9760 Ti3 XxpiNDBSUS
TRIANGLE LABS   Tert:TLH44376A 153-156
1001
  aol

  601
 20.

  0.
    ,311 00  31,12
                        31,37
33,17
                                                                        33,09
33,33^ 33,46
    31:00 31,12  31:24 31:36 31,48  32,00  32:12 32:24 32:36 32:48  33,00 33:12 33:24  33,36 33:48
File,0980038 tl-385 Acq, 6-JAN-1998 18,57:18 SC XH- Voltage SIS 70S
445.7555 r,3 XxpiODBSOS
                                                        -3.7X8

                                                        -.2.9X8

                                                        '•.2.2X8

                                                        '-.1.5X8

                                                        '-.7.4X7
                                                                                                    -.0.0X0
                                                                                                        Zlaal
                                                       -3.0X8

                                                        '-.2.4X8

                                                        li.axa

                                                        il.2E8

                                                        is.9X7
                                                                                                     0.0X0
                                                                                                        Time'
                                                                                                     8.2X6

                                                                                                    £.6.6X6

                                                                                                    L4.9X6

                                                                                                    ^.3.3X6

                                                                                                      .6X6
                                                                                                     0.0X0
                                                                                                        Tiae
                                                          .6X7

                                                        U..3X7

                                                        .9.9X6

                                                        '-.6.6X6

                                                        13.3X6
                                                                                                     0.0X0
                                                                                                        Time,
 4.4X7

'-.3.5X7

'-.2.6X7

.1.8X7

'-.8.8X6

 0.0X0
TRIANGLE LABS
ion
 flOj

 ffflj

 401

 201

  0.
               TexttTLI*44376A 153-156
                                                      33:35
                         :5
                                    32Yob' 32:12' 32:24 ' '32\36' 32i48r33'sb6 33': 12 33't24
                                                                                                        113

-------
f3.J.e>O98Q028 tl-385 Acqi 6-JAN-199B 18,57,18 SC £1+ Voltage SIS 70S Soia»,94901
389.8156 Ti3 BSUS(256, 30, -3.0) fXD( 7,5, 3,0.iO\, 379604.0, 1.00\,T,T) XxpiSDBSUS
TSIASSLX LABS Texts TLH44376A 153-156
1001
80.
60.

40.

20.
A3. 59 f 8
(1
1
1 1 A2.01X8
A
A8.58X7 11 / \
A / I / \ A7.59E7 JU..03X8
/V 1 w V-^ /W f^
31i36 '31\48 ' 33100 32\12 32\24 32i36 ' 32\48 ' ' 33\00 ' ' 33\12 ' '33i24 ' ' 33
1.2X8
.9.3X7
.7.0X7

.4.6X7

L3.JZ7
36 Time
rlleiU980028 tl-385 Acqs 6-JUT-1998 18t57,lB SC XH- Voltage SIS 70S Soiatt 133652
391.8127 Ts3 BSUB(256,30,-3.0) PKD(7 , 5,3,0 .10\,534608. 0,1. 00\,T,T) SxptBOBSUS
TSIASSLX LABS Tarts XLIt44376A 153-156
1001
80.
60.

40.

20.
A2.94E3
M
'
I 1 A1.64X8
1 \ A
A6.69E7 11 / \
A/ \ / \ A6.05E7 A8.37S7
1 w W^7 /v\ r^
31>36 31\4a 32>00 32sl2 32:34 32s36 32\4S 33\00 33\12 33\24 33
-9.5X7
.7.6X7
.5.7X7

.3 . SE7

'.1.9E7
36 Time
ttletoaaooaa tl-SSS Acq: 6-fflI-199a 18i57iia SC SH- Voltage SIS 70S So±aes7374
401.8558 Ts3 BSOB(256,30,-3.0) PKD(7,S,3,0.10\,29496.0,1.00\,r,T) SzptSDBSOS
TSIAXSLE LABS Text:TLIt44376A 153-156
1001
80.
60.
40.
20.
0.
A5.62E7
A
A4.20X7 l\
A


/ll ^
j \ \ — y v —
31>36 31t48 32sOO 32tl2 32s24 32s36 32i48 ' ' 33tOO ' 'j'jiiz' ' ' 33\24 ' ' 33\
1.5X7
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.8.9E6
.5.9X6
_J . 0X6
'.0.0X0
36 Time
r±J.asa98002B 91-385 Acqt 6-JJUT-1998 18s57tl8 GC XH- Voltage SIS 70S Soiaas3353
403.8539 Ts3 BSOB(256, 30, -3.0) PKD(7,5, 3, 0 .10\,13412.0,1.00\,T,T) XxptSDBSaS
TBIANGLX LABS TaxtiTLIt44376A 153-156
1003
80.

60.
40.
20.

A4 . 77E7
A
A3.4BE7 (1
A 1 1
A2.40ZH
AM

IV V
J 1 V — _7 v^^
31\36 31 t 48 32iOO 32\12 32i34 32t36 32s48 33tOO 33\12 33t24 33
.1.2X7
.9.7X6

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.4.8X6
.2.4X6
.0.0X0
36 Time
Tila, 0980028 tl-385 Acqi 6-J3UT-1998 13,57,18 SC KH- Voltage SIS 70S
392.9760 Ti3 EiptNDBSUS
TSIASGLE LABS TextiTLI*44376A 153-156
1001
ao.
60.
40.
20.
0.
3i>37 X^_ 32r03 33, 17 32s34 ^i^J^7^ 33,09 33,24 33,32





3l'i36 31s48 32tOO 32112 32', 24 32i36 32\48 33\00 33\12 33\24 33
.4.4X7
.3.5E7
.2.617
.1.8X7
.8.8X6
0.0X0
36 Time
114

-------
 Tila:O98002B  #1-545 Acq:  6-JAN-199B 13:57:13 GC £T+ Voltagw SIS 70S Ifoiaa:24356
 407.7818  r>4  BSOB(256,30,-3.0) PKD(7,5,3,0.10\,97424.0,1.00\,T,T) XxptSDBSUS
 TSIAOSLE  LASS  Taxt:TLIt44376A 153-156
 100$   A1.75E9

  80:

  60:
  40:

  20:
                          A4.35E8
                                                                         A2.07E8
        35tOO    35i12    35:24    35:36    35:48   36:00    36:12    36i24    36i36
THat098002S fl-545 Acq:  6-JJOT-1998  18:57:18 GC XH- Voltaffa SIS 70S Noiaa:24075
409.7789 T:4 BSV3(256,30,-3.0)  PKD(7,5,3,0.10\,96300.0,1.00\,f,T)  XxptUDSSOS
TRIANSLX LASS  Taxt:TLIt44376A  153-156
1001    A1.66X9

  80:

  60:
                                                                                     36:48
  40:

  20:
                          A4.13E8
                    yvyv
                                                                         A1.99E8
        J5iOO    35:12   35:24    35:36   35:48    36:00    36:12    36:24   36:36
rilo:0980028 tl-545 Acq: 6-JKN-199B 18:57:18 SC EH- Voltage SIS 70S Koiaa:13250
417.8253 T:4 BSUB(256,30,-3.0) PKD(7,S,3, 0.10\,S3000.0,1. 00\,T,X) Exp:SDB5OS
TSIASSLS LASS  Taxt:TLIt44376A 153-156
        Al.84E7
                                                                        A1.43E7
                                                                                     36:48
  80:

  60:

  40:

  20:
        35:00    35:12    35:24    35:36    35:48    36:00   36:12    36:24    36:36
TilatU98002B tl-S4S Acq:  6-JAK-1998 18:57:18 SC KH- Voltage SIS  70S Noise:6787
419.8220 T>4 BSUB(256,30,-3.0) PXD<7,5,3,0.10\,27148.0,1.00\,r,T) Eip:SDB5US
TRIANGLE LASS  Text:TLIf44376A 153-156
10 0\    A4.J.1Z7
                                                                                     36:48
 80:

 60:
 40:
 20:
                                                                        A3.23E7
        35:00    35:12    35:24    35:36    35:48    36:00    36:12    36:24
TilatU98002B fl-54S Acq:  6-JAN-199B 18:57:18 SC EI+ Voltaya SIS  70S
430.9729 r:4 Zxp:NI)B5US
TRIANGLE LABS  TextsTLII44376A 153-156
                                                                             36:36
                                                                                     36:48
     -4.6EB

     -.3.7X8

     -.2.8E8

     li.asa

     '.9.2E7
     h fl nrn
 37:00    Mae
     -4.418

     '•.3.5X8

     .2.7E8

     .1. 8E8

     -8.9E7
                                                                                                   .O.OEO
                                                                                              37:00   Time
      4.8E6

     '-.3.3S6

     -.2.9E6



     '-.9.6ES

      O.OEO
                                                                                              37iOO
     -1.1E7

     .8.5E6

     .6.3E6

     .4.216

     .2.1X6
                                                                                                  .O.OEO
                                                                                              37:00    Time
1003
 80:
 60:
 40:
 20:
  oj
                                       35:43
                                                   36:00
                                                           36:13 36:20
                                                                          36:33
                                                                                                  .2.4X7

                                                                                                  il.8S7

                                                                                                  \J..2E7

                                                                                                  '.5.9X6
        35:00    35:12   35:24    35:36   35:48    36:00    36:12    36:24
Tila:U9B002B tl-545 Acq: 6-J3OT-1998 18:57:18 GC XI+ Voltaga SIS 70S
479.7165 Ti4 ExpiNDBSUS
TRIANGLE LASS  Tert:TLIt44376A 153-156
                                                                            36:36
                                                                                     36:48
    1-0,ago
37:00    Hoe
1001

 80:
                    35:17
        35:00
                35:12
                         35:24
                                  35:36
                                          35:48
                                                  36:00
                                                           36:12    36:24
                                                                            36:36    36:48
     -.0.0X0
37:00   Time
                                                                                                         115

-------
              tl-545 Acq:  S-JZlt-lSSB 1B:57:1S SC EH- Voltage SIR 70S Koiae:14723
 433.7766  T>4  8SO3(256,30e-3.0) PXD(7,5,3,0.101,58888.0,1.00\rf,T)  KxptXDBSUS
 TXIAOSLX  LABS  Text:TLIt44376A 153-156
 1003

  80.

  60.

  40.

  20.
            A2.B3E8
                                                           A2.B2X8
      35:12  35:18 35:24  35:30 35:36  35:42  35:48 35:54  36:00  36:06 36:12
Tile:U980028 tl-545 Acq:  6-JJOT-1998 18:57:18 SC XI+ Voltage  SIX  70S  Soiae:107SO
425.7737 T:4 BSO3(256,30, -3.0) PKD(7,5,3,0.10\,43000.0,1.00\,T,T) Rrp,HDB5VS
TXIASSLE LABS  Text:TLIt44376A 153-156
1001       A2.79E8
      35:12 35:18  35:24 35:30  35:36 35:42  35:48  35:54 36:00  36:06  36:12 36:18
r±le:O980028 tl-545 Acq: 6-J7OT-1998  18:57:18 SC EI+ Voltage SIX 70S Noise-.5033
435.8169 f:4 3303(256,30,-3.0) PXD(7,5,3,0.10\,20132.0,1.00\,r,T) Exp:HDB5US
TXIASSLE LASS  Text:TLIt44376A 153-156
1004                                                      A2.64X7
  80.

  eo:

  4 a:

  20:
                                                                                               '.1.3X7

                                                                                               '.O.OEO
                                                                                   36:24 36:30     T±me
                                                                                               -6.1X6
      35:12 35:18  35:24 35:30  35:36 35:42  35:48  35:54 36:00  36:06  36:12  36:18  36:24 36:30
T±la:n98002B tl-545 Acq: 6-JMT-1998  18:57:18 SC EH- Voltage SIX 70S Soiae:4736
437.8140 T:4 3SU3(256,30,-3.0) PKD(7,5,3, 0.10\, 18944.0,1.00\,f,T) Kzp:KD35US
TXIASSLE LABS  Text:TLIt44376A 153-156
1004                                                      A2.54E7                              -6.1X6
 ao:
 eo:
 40:
 20:
                                                                                               .4.8X6

                                                                                               .3.6X6

                                                                                               .2.4X6

                                                                                               -1.2X6
      35:12 35:18  35:24 35:30  35:36 35:42 35:48  35:54 36:00 36:06  36:12 36:18  36:24 36:30
Tile: US BOO 28 tl-545 Acq: 6-J3Of-1998  18:57:18 SC XI+ Voltage SIX 70S
430.9729 T:4 SxptBDBSUS
TB.IXNSLX LABS  TaxtiTLIt44376A 153-156
       35:13     -- ~~J5l27
                                                                                                0.0X0
                                                                                                   Time
100\

 80.

 60.

 40.

 20.
                35:22/
35:43 35:49
                                                         36:00
                               36:13   36:20
-2.9X7


.2.4X7


'.1.8X7


'.1.2X7


J.9X6
      35:12 35:18  35:24  35:30  35:36  35:42 35:48  35:54  36:00 36:06  36:12 36:18  36:24 36:30
                                                                                                0.0X0
                                                                                                   Time
                                                                                                           116

-------
441.7428 Ti4 BSOB(256, 30, -3.0) PXD(7,5,3,0.10\,140580.0,1.00\,r,T) XxpiODBSaS
TXIASSLX LASS T*xt:TLI*44376A 153-156
1001 AS. 01X8 -.1.4X8
901
801
7ol
60.
501
401
301
201
lo-






-

1^
J5ioO jff.-OO 37sOO 38:00 ' ' 39,00 ' ' 40:00 ' ' ' 41
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443.7399 T:4 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,29744 .0,1.00\,T,X) XxpsSDSSUS
TXIASSLX LASS Text:TLI*44376A 153-156
1001 A9.16E8
90^
80.
70.
60-
501
40.
301
201
101
a:
Jsioo 36-00 37.' 00
rile, 0980028 41-545 Acqs 6-JZ1T-1998 18:57:18 SC
430.9729 Ts4 Xip:HDB5US
TSIAOSLX LASS Text:TLI*44376A 153-156
1001 35 1 02 35/27 36f,59
3L^^^^^
801
701
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-------
                                                                                 CD
Peak Locate Examination: 6-JAN-1998:18:55 File:U980028
      Experiment:NDB5US Function:2 Reference:PFK
     Volts
    1.0420
                                                         Volts
                                                        0.7997
                                                        Volts
                                                        0.1663
                                            416.93435  416.97604  417.01774
292.95315  292.98245  293.01175
330.94615  330.97925  331.01235

-------
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-------
                                                                                                      04
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-------


TLI Project: 44376A
Client Sample: 153-156
_«, t: Jh^, ,^ s^^^lii^ss^vlit
Li X <«l C«V«M*MM Tr rtrft rt rtH*S'iirEEif^r'**fciiifc^M*in^Trn
ENfi^SfiftBSH^Hw
$^^C.J~'-
£*™?-$\ " ^
Method 23 TCDD/TCDF Analysis (DB-225)
f ' '. I. Analysis File: P980096
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-11A-D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000
Dry Weight n/a
GC Column: DB-225
Dilution Factor n/a
Blank File: P980094
Analyst JM
Spike File: SPC2NF04
ICal: PF22206
ConCal: P980092
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

g^iiS^tv^^'''^ '~?*mt
m v " v ^^^^s^f; > r
2^,7,8-TCDF 11.6
p|em^$^ri^rd * ' ** -Amt
13C,2-2,3.7,8-TCDF. 2
^Recovery Standard
v RT Ftegs
0.76 23:07 	
Ratk> RT Flags
0.75 23:06 	
Ratio RT Flags
13^* i o T >i TfT"NT"^ r\ y^ *} i • ^A
IJV-,i2-ItZ,J,4-iCJJU . I),o2 ^l.^o 	
                         Data Reviewer
01/09/98
                                                Page 1 of 1
                ONP_PSR vlOl. LAM 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 10:1501/09/98
                           123

-------
                        Initial
                                   ..Date.
  Data Review By:
        LI
                                             Calculated Noise Area:
                                                                    1.00
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
  Page No.
  01/07/98
Listing of P980096B.dbf

Matched GC Peaks / Ratio / Ret.  Time
 Compound/
 M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2..  Rel.RT Compound.Name..  ID..  Flags.
TCDF 0
304-306 DC ML 0:00
DC WL 18
IS
18
18
19
19
19
19
19
19
20
20
20
20
20
20
21
21
21
21
21
21
22
22
22
22
22
23
23
23
23
23
24
24
25
DC WH 25
:15
:29
:45 RO
:56
:00 RO
:07
:29
:36
:44
:55
:01
:11
:20
:29
:38
:48
:11
:23 RO
:29
:37
:43
:53
:07
:21
:32
:41
:59
:07
:20
:37
:44
:56
:16 RO
:32
:17
:43
.65-0.89
0.76
0.66
0.82
1.31
0.83
1.00
0.84
0.76
0.76
0.75
0.76
0.76
0.77
0.81
0.78
0.75
0.76
0.76
0.63
0.87
0.75
0.74
0.76
0.74
0.75
0.76
0.67
0.76
0.76
0.75
0.75
0.75
0.66
0.97
0.76
0.74
0.66
304-306 34 Peaks
13C12-TCDF
316-318 DC NL 0
DC WL 18
DC WL 19
0.
:00 RO
:32 RO
:18 RO
65-0.89
1.39
1.30
0.22
5.
45.
3,551.
76.
81.
70.
278.
3,941.
3,923.
7,249.
3,091.
510.
3,572.
7,729.
4,205.
11,217.
4 , 118 .
24,265.
33.
45.
4,817.
1,115.
5,398.
5,101.
1,234.
6,779.
40.
5,401.
3,150.
6,047.
7,197.
5,725.
33.
14.
4,161.
729.
43.
134,908.
59
83
20
98
23
45
28
29
45
42
35
71
80
53
00
29
15
40
52
19
35
26
78
22
28
13
75
94
19
59
14
97
08
62
33
02
30
89
0.792-1.101
0.000

1,597
56
36
39
127
1,700
1,688
3,105
1,337
220
1,549
3,470
1,843
4,813
1,772
10,460
14
20
2,065
475
2,323
2,176
528
2,927
16
2,332
1,355
2,599
3,075
2,459
13
8
1,794
310



.23
.95
.78
.65
.12
.87
.13
.33
.56
.62
.54
.36
.23
.21
.12
.30
.58
.97
.19
.99
.21
.95
.81
.28
.31
.77
.56
.99
.43
.30
.11
.04
.70
.35



1,953
43
44
39
151
2,240
2,235
4,144
1,753
290
2,023
4,259
2,361
6,404
2,346
13,805
23
24
2,752

.97
.49
.45
.80
.16
.42
.32
.09
.79
.09
.26
.17
.77
.08
.03
.10
.06
.22
.16
639.27
3,075
2,924
705
3,851
24
3,069
1,794
3,447
4,121
. 3,266
19
8
2,366
418


.57
.27
.47
.85
.44
.17
.63
.60
.71
.67
.97
.26
.63
.67


0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.

0.957-
3.
3.
7.
31
72
06












0.
0.
0.
790
800
812
820
823
828
843
848
854
862
867
874
880
887
893
900
917
926
930
936
940
947
957
968
975
982
995
001 2378-TCDF
010
022
027
036
051
062
095
113

1.043
000
802
835








E



E

E

E







E


AM
E
E
E










Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 02:43 01/07/98
                                                                            124

-------
  Page Ho.
  01/07/98
Listing of P980096B.dbf
Matched GC Peaks / Ratio / Ret.  Time
  Compound/
       -- QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2..  Rel.BT Compound.Dame.. ID.. Flags.
  316-318
 13C12-TCDD
 332-334
DC
DC
DC
DC
DC
DC
DC






DC
DC
DC
DC
DC
DC
DC

WL
WL
WL
WL
WL
WL
WL






WH
WH
WH
WH
WH
WH
WH
6
20:10
30:23
20:33
20:44
21:20
21:33
21:49
22:17
22:24
23:06
23:27
23:42
24:03
24:37
24:42
24:50
25:10
25:15
25:32
25:45
Peaks
RO
RO
RO
RO

RO
RO




RO
RO
RO
RO


RO

0.84
0.60
1.00
0.37
0.74
1.51
0.33
0.39
1.11
0.75
0.74
0.67
0.74
1.36
6.33
2.12
0.57
0.69
0.76
1.86

28.
2.
53.
5.
25.
9.
51.
5.
6.
1,043.
78.
4.
15.
2.
0.
2.
6.
6.
14.
4.
1,154.
23
53
45
38
67
70
90
95
05
58
49
63
72
60
53
27
94
86
96
81
42


2
3
448
33
1
6










.59
.80
.04
.47
.86
.67










6.
3.
595.
45.
2.
9.










58
42
54
02
77
05








0.873
0.882
0.890
0.898
0.924
0.933
0.944
0.965
0.970
1.000
1.015
1.026
1.041
1.066
1.069
1.075
1.089
1.093
1.105
1.115

                                        Above:  TCDF / TCDD Follows
                                0.65-0.89
 332-334
DC
DC
DC



DC
DC

DC
DC
DC

ML
SN
SN



SN
SN

WH
WH
WH
4
0:
20:
20:
21:
21:
21:
22:
22:
22:
23:
24:
24:
00
06
30
38
47
56
08
30
42
41
30
40
RO
RO
RO

RO

RO


RO
RO
RO
1.
1.
0.
0.
0.
0.
3.
0.
0.
0.
0.
1.
36
07
61
81
99
32
97
68
74
05
91
13
Peaks
1.
0.
2.
681.
3.
1,148.
0.
1.
8.
0.
3.
2.
1,842.
89
99
23
35
17
77
57
38
82
83
75
80
11
                                                            303.92
                                                              1.77
                                                            516.84
                                                              3.76
                                                                                       13C12-2378-TCDF ISO
0.908-1.092
0.000
0.929

377.
1.
631.


5.




43
79
93


06



0.
1.
1.
1.
' 1.
1.
1.
1.
1.
1.
948
000
007
014
023
040
049
095
133
140

13C12-2378-TCDD IS1

13C12-1234-TCDD RSI






 Column Description	   'Why*  Code  Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 loos
 OK    -RO-Ratio Outside  Limits
 Rel.RT-Relative Retention Time
 ••• End of Report *••
      WL-Below Retention Time Window
      WH-Above Retention Time Window
      SN-Belov Signal to Noise Level
      
-------
flla :P9ao096  tl-92
303.9016 Xxp:DB225
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  15J
  Iflj
  5j
  Oj
                                      23 ! 37
                 22159
                                                                                                     -7.6X6
                                                                   24 i 32
                                                                                           25:1.7
     22i36 22t4B  23tOO  23:12 23:24 23,36  23:48 24:00  24:12 '24\24  '24:36'
Tile,P980096 91-922 Ac
-------
 rile:P9ao096 tl-931 Acq:7-JAH-Ha Olstlsui E1+ vox cage SIM /OP SOJ.ae:l^J.
 303.9016 BSVB(256r30f-3.0) PXD(5,3,1, 0.10%,4840.0, 0. 00\,T,T) Xxp:DB225
 TSVUtSLX LASS  Taxt:153-156 TLH44376A
           19»00        20:00       21:00       23:00        23tOO       24:00
Tila:P9a0096 tl-922 Acq:7-JAK-98 01:44,01 XH- Voltage 315 70P Soiae:1586
305.8937 BSUS(256,30,-3.0) PKD(5, 3,1,0.10\,6344.0,0.00\rr,f) Exp:DB225
TSIABSLX LASS Text: 153-156 TLH44376A
100*                                A1.38X8
                     25100
          19,00        20': 00       21:00       22:00       23:00        24:00
rile:P980096 tl-922 Acq: 7-JJUT-98 01:44:01 SH- Voltage SIS 70P Xoiaa>1302
315.9413 BSUB(256,30,-3.0)  PXD(5,3,1, 0.10\,5208.0, 0.00\,r,f) Exp:DB225
TSIAKSLE LABS  Text:153-156 TLH44376A
                     25:00
lOOi
  ao.
 so.
 40.
 20.
                                                           A4.48ES
                            A3.04X5
                                            A2.3SE5
                                         ^  _  A
\A3.35E5
   A
          15:00        20:00       21:00       22:00       23:00        24:00
Tila:P980096 tl-922 Acq: 7-JJOT-98 01:44:01  XH- Voltage SIR 70P Koiae:937
317.9389 BSUB(256f30f-3.0)  PU>(S,3,1, 0.10\, 3748.0,0.00\,T,T) Exp:DB225
TBIAXGLE LABS  Text: 153-156 TLH44376A
1001                                                       AS  6E6
  80.

  SO.

  40.
                    25:00
 20.
                            A3.02X5
                               A  _
                                                                A4.50E5
          19>00        20:00       21:00       22:00       23:00
TiletP980096 H-922 Acqi7-JAK-98  01:44:01 XH-  Voltage SIS  70P
375.8364 Elp,DB225
TBIANGLZ LABS  Text: 153-156 TLH44376A
1001                                                        23:04
50.

40.

20.
        24:00
                                                                                    25:00
                                                                                                    Tiae
                                                     A3.85E7      A4.12E7
                                     T±mo
                                                                                               .1.2E6

                                                                                               .9.9X5

                                                                                               .7.4X5

                                                                                               .4.9X5

                                                                                               .2.5X5

                                                                                               .0.0X0
                                                                                                   Time



                                                                                               .1.7X6

                                                                                               .1.3X6

                                                                                               .9.9X5

                                                                                               .6.6X5

                                                                                               .3.3X5

                                                                                               .0.0X0
                                                                                                   Tlae
                                                                                                 3.6E4
                                                                                                '.2.9X4
                                                                                                '.2.2X4
                                                                                           25:33.
     18:34
                                '.1 . 4X4

                                '.7.2X3
          19:00
                      20:00
                                   21:00
                                               22:00
                                                           23:00
                                                                       24:00
                                                                                    25:00
                                Lo.oro
                                    Tlae
                                                                                                         27

-------
TJJ.»:P9BOQ96  il-922 Actj: 7-JAN-SB 01:44:01 EI+ Voltage SIS 70P
319.8965 BSVB(256e30r-3.0) PKD(S,3,1, 0.10\,2888.0,0.00\,T,r) Exp,DB225
XSIASGLX LASS  Text: 153-156 TLH44376A
1001
  80.

  60.

  40.

  20.

   0.
             A1.80X7
                        A4.20X6
                           fol.94BS
                           \  A7V
                                     1.33X6
                                      A	
                                               A7.55X6
                20:00            21:00           22:00           23:00
r±la:P980096 tl-922 Acq:7-JZIT-98 01:44,01 XH- Voltage SIS 70P Noiaes2705
321.8936 aSU3(256,30,-3.0)  PKD(S,3,1, 0.10%, 10820.0,0.00\,r,T) XzptD322S
TXIASSLS LASS  T&rtj 153-156 TLH44376A
1001
                                                                                 24,00
  80.

  60.

  40.

  20.
             A2.32E7
                        AS.16E6
                                    A3.02X6
                                       A ._
                                               A9.SSX6
                20:00           21:00            22:00            23:00
rile:P980096 tl-922 Acqs7-JAN-98  01:44:01  XH- Voltage SXB  70P NoiB»,aiO
327.8847 3SVS(256f30,-3.0) PKD(5,3,l,0.10\,3240.0,0.00\,r,r) Xxp:DB225
TSIAHSZX LASS  Text: 153-156 TLH44376A
                                                                                  24:00
1001

 80.

 60.

 40.

 20.
                 AJ..59B7
                                               A1.92X7
                                                                              Al. 09E7
                                          A6.77I6
                20:00           21:00            22:00            23:00
F±le:P980096 tl-922 Ac*j:7-JAIT-98  01:44:01 SH- Voltige  SIS 70P Noise: 730
331.9368 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,2920.0,0.00\,r,r)  Sxp:DB225
TSIASGLX LASS  Tart: 153-156 TLH44376A
1001                                           AS. 17X6
                                                                                 24:00
 80.

 60.

 40.

 20.
                                         A3.04X6
                20,00           21:00            22', 00            23:00
ril»tP980096 tl-922 Aoq,7-JAR-98  01,44,01  SH- Voltaga SIS  70P Hoie»,535
333.9338 BSUS(256,30f-3.0) PKDfS,3,1, 0.10\,2140.0,0.00\,T,T) Erp,DB225
TSIASSLX LABS  Tarti 153-156 TLXt44376A
1001                                           A6.32X6
                                                                                 24:00
 80.

 SOL

 401

 20:

  0.
                                         A3.77X6
                20:00
                                21:00
                                                22s 00
                                                                 23:00
                                                                                 24:00
                                                                                                    -8.7X6

                                                                                                     .6.9X6

                                                                                                     .5.2X6

                                                                                                    .3.5X6
                                                                                                      o.oro
                                                                                                  25 00 Tiae
                                                                                                    -1.1*7

                                                                                                    .8.9X6

                                                                                                    .6. 7X6

                                                                                                    .4.5X6

                                                                                                    '.2.2X6
                                                                                                  25
                                                                                                      0.0X0
                                                                                                     00  Tia.
                                                                                                     5.0X6

                                                                                                    .4.0X6

                                                                                                    .3. 0X6

                                                                                                    .2.0X6

                                                                                                    -1.0X6
                                                                                                    .0.0X0
                                                                                                 25  00  Time
                                                                                                 25
                                                                                                    .1.1X6


                                                                                                    .8.3X5


                                                                                                    '.5.5X5


                                                                                                    .2.8X5
                                                                                                     0.0X0
                                                                                                     00  T±m>
                                                                                                   -1.7X6

                                                                                                    .1. 4X6

                                                                                                    .1. 0X6

                                                                                                   -6.9X5

                                                                                                   -3.4X5
                                                                                                    .0.0X0
                                                                                                 25:00  Time
                                                                                                       123

-------
r±leiP980096 tl-922 Acq:7-JAK-9a 01:44:01 SI+ Voltage SIX 70P
303.9016 KxpiSB225
TSIAHSZX LABS Text: 153-156 TLH44376A
ion
80.
SO.
40.

20.

0.
k 31; 11
A
1 1 1
19:44 fl 1 i 22*32 23.37
19t29\\ A * 11 II A A A 11 A A llA 24 1 32
A A A 11 A A /I A /• 1 A II A ii A fl /I A 11 ft/l A
A '/\/\il A A/ v/v 1/1 11 l\ l\ l\ l\ l\l\ l\ /I/I A
/ L_ _j » V v / \yv 7 v v V / V ] *^.7 V 7 \ y\ /V /VVyV/v 7V ^^
-1.717
Ll . 4JT7
.1 . 017
.5.8W

.3.4X6


15(00 30:06 21:00 22:00 23:00 34:00 35:00 Time
Tile:P9a0096 tl-922 Acq:7-JAH-98 01:44:01 EH- Voltage SIX 70P
315.9419 XxptDB225
TRIASSLX LABS Text: 153-156 TLIt44376A
1001
80.
SO.
40.
20.


33:05




20'33 31,49 1
"* •*^- i~i r i IA J *- A.
-1.2X6
.9.9X5
.7.5X5
.5.0X5
-.2.5X5


15:00 30:00 31:00 22:00 ' 33:06 ' 24:00 ' 25:00 Tiae
r±letP980096 tl-922 Ac17

15:53
1

1 30:31 31:55
A A 31il6 \
\ \ A A A A _ ^W V ^ . 	
8.7X6
-.6.9X6

-.5.2X6
'-.3.5X6
.1 . 7X6
'• o.oxo
15:00 30:00 31:00 33:00 3J:00 34:00 35:00 Tiae
rlleiP980096 tl-922 Acq:7-JJOt-98 01:44:01 XX+ Voltage SIX 70P
331.9368 Xxp:DB225
TSIAJKLX LABS Text: 153-156 TLH44376A
1001
80:
50:
40:
30:

31:55

T


/i n
1 . 4X6
'•.1.1X6
.8.3X5
.5.5X5
.2.8X5
0.0X0
15:00 30:00 31:00 33:06 33:06 34:06 35:06 Tiae
rllosP9B0096 tl-922 Adj:7-JXS-98 01:44:01 XH- Voltage SIX 70P
292.9825 XipiDB225
TXIAKSLX LABS Text: 153-156 TUt44376A
1002
80:
50:
40:
30:
0:
l^:4S15«33 15:55 30:38 31:3531:51 23^38 33:14 24j22 35:30
N^^f^^^^^^ -vr^.tf^ .v, . YV^^_r^v^v^^7^rv^r^
1



.1.2X7
.9.7X6
.7.3X6
.4.9X6
.2.4X6
0.0X0
15:06 3oio6 3lio6 331-06 ' ' 33:06 ' ' 34:06 ' 35:06 ' Time
r±le:P9B0096 tl-922 Acqt7-JJUT-98 01:44:01 XH- Voltage SIX 70P
330.9792 XxpiDB225
TXIABGLX LABS Text: 153-156 XLIt44376A
1001
80:
50:
40:
30:
o:
15:37 *ii°S. aiifA^ 22 1 36 23 1 05 23 1 33 34:3334:4535:15
VM)|(w^Vvl/vu/w«-^V^4y->>^VYT^^




.1.1X7
.8.6X6
.6.4X6
.4.3X6
.2.1X6
0.0X0
15:00 30:00 31:00 33:00 33:00 34:00 35:00 Time
129

-------
Ref. lass    232.9825    Peak top
HelpJ*  2.18 volts  Span   208 ppi
Systei f lie naie
Data  fUenaie
Resolution
Group nmter
lonlzatlon Nde
Pitching
Ref. lasses   292.9825,
fl   292.9825
B   383,9818
D   315.9419
E   317.9389
F   319.8965
G   321.8938
H   327.8847
    338.9792
J
K
L
H
   ft;
       1
     El*
 VOLTAGE
388.9761
338.9792
331.9368

375.8364
Channel   I  338.9792    Peak top
Height  1.68 volts Span   288 opt
                                                         130)

-------
 TLI Project:      44376A
 Client Sample:   157-160/166  f-
r
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980029
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-12A-E Date Extracted: 12/29/97
DateAnalyzei 01/06/98
1.000 Dilution Factor n/a
n/a Blank File: U980026
DB-5 Analyst: BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U98002S
n/a
n/a
n/a
Anaiytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3.7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2.3,4,6,7,8.9-OCDD
2,3,7.8-TCDF
1,2,3,7,8-PeCDF
2,3.4.7.8-PeCDF
1 2J,4.7,8-HxCDF
".2,3.6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8.9-HxCDF
l,2J,4,6,7,8-HpCDF
1,2.3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
*>
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
AWt, {ng} Dfc. "1EMPC
0.71
5.0
5.4
8.1
11.9
55.4
87.1
76.6
15.7
31.9
98.8
35.5
53.9
3.1
200
34.5 i .
-^\-LQ fifi7 ~ CA^- II ' '

Amt (ng) Number m. EMPC
143 12
103 9 161
154 6 160
114 2
441 16
419 14 423
417 12
346 4
'? ' ftetto
0.74
1.55
1.24
• 1.27
1.25
1.02
0.84
0.75
1.61
1.58
1.26
1.26
1.26
1.30
1.04
1.04
0.91

- ,








RT
25:21
29:37
32:45
32:50
33:07
36:03
39:38
24:41
28:35
29:17
32:02
32:09
32:38
33:23
35:02
36:34
39:50










Ffags
PR_



	
E_
E_
E_


E_

E_
PRX
E_

SE_

Flags
QE_
E_
E_
E_
E_
E_
E_
E_
                                       Page 1 of 2
                                  Mn7.PSRvl.01.LARS6.ia08I
Triangle Laboratories, lnc.3
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                               Printed: 10:1801/10/98
                                          131

-------
 TLI Project      44376 A
 Client Sample:    157-160/166
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980029
\tatern&Standard» ->— - •*<*
13C,2-2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13C,2-U,3,7,8-PeCDD
13C,rU^,6,7,8-HxCDF
l3C,2-l,2,3,6,7,8-HxCDD
13C,2-lA3,4,6,7,8-HpCDF
13C,2-1^3,4,6,7,8-HpCDD
I3C 12- 1 ,2,3 ,4,6.7,8 ,9-OCDD

Surrogat&StendaKJs {type A)
13C,2-2,3.4,7,8-PeCDF
13C12-U,3,4,7,8-HxCDF
13C12-l,2.3,4,7,8-HxCDD
13Ci2-U,3,4,7,8,9-HpCDF

Surrogate Standards (Type A)
"CU-2,3,7,8-TCDD
Alternate Standards {Type A}
13Ca-l,2,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
uCu-lA3,7,8,9-HxCDD
r»AML-fr&~
2.7
2.5
2.7
3.1
3.1
3.0
63

Afl*£»S)
3.6
4.0
3.9
3.9

Aflttv §!§}
3.2
Aim.$i^
2.9
3.0
-;-

-:T^RBcOvfflT~
62.7
63.2
66.4
63.0
67.6
77.1
77.2
74.0
78.3

% Recovery
91.2
99.2
96.7
97.9

% Recovery
80.6
% Recovery
72.1
75.0


«0«v ,,, 	 .v
40%-130%
40%- 130%
40%-130%
40%-130%
40%- 130%
40%-130%
25%-130%
25%-130%
25%- 130%


40%- 130%
40%- 130%
40%-130%
40%- 130%




40%- 130%
40%- 130%


';'~8*to^:
0.75
0.81
1.57
1.52
0.53
1.21
0.45
1.07
0.87

Ratio
1.45
0.53
1.20
0.44



Ratio
0.52
0.56
Ratio
0.81
1.21
^jn^-jRags ^
24:39 	
25:20 	
28:35 	
29:36 	
32:09 	
32:48 	
35:01 	
36:03 	
39:37

RT ftegs
29:16 	
32:03 __
32:44 	
36:33

RT Bags ,
25:21 	
RT Flags
33:23 	
32:38 	
RT Flags
25:10 	
33:08 	
                     Data Reviewer
            01/10/98
                                        Page2of2
                         MTn_PSR »1.01, LARS & 10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:18JD1/10798
                               i. o i-

-------
Data Review'By:
                      Initial
                       fy.
                                  . .Date..
                                            Calculated Noise Area:
                                                                   1.00
The Total Area for  each peak with an ion abundance ratio outside
ratio  limits has been recalculated according to  method requirements.
Page No.

01/10/98
                         Listing  of O980029B.dbf
                         Matched  GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT.  OK  Ratio Total.Area... Area.Peak. 1..  Area.Peak. 2. .  Rel.RT Compound.Name.. ID.. Flags.
TCDF 0
304-306 OC NL 0:00 RO
KN 21:29
K 22:00
K 22:14
K 22:37
K 22:56
K 23:20
K 23:36
23:50
24 :03
24:15
24:28
24 :41
25:04
25:17
25:33
26:23
304-306 16 Peaks
|l3C12-TCDF 0.
316-318 DC NL 0:00 RO
DC WL 23:00
24 : 05 RO
24:39
316-318 2 Peaks
.65-0.89
0.59
0.75
0.74
0.74
0.75
0.75
0.73
0.75
0.75
0.79
0.75
0.75
0.75
0.75
0.74
0.73
0.77
2,
65-0.89
1.34
0.66
1.04
0.75

0.867
4,654
70,734
71,500
74,434
374,158
231,515
243,962
174,584
222,451
275,262
113,621
.53
.70
.80
.60
.00
.70
.00
.70
.50
.00
.60
101,101.90
460,610
113,330
96,909
14,998
12,461
651,637
.00
.40
.60
.69
.11
.30

30,424
30,447
31,535
160,127
99,151
102,610
74,746
95,642
121,763.
48,611.
43,196,
197,948.
48,408.
41,308.
6,335.
5,408.


.20
.40
.90
.00
.70
.00
.50
.50
,00
.50
,00
.00
90
.10
38
43


40,
41,
42,
214,
132,
141,
99,
126,
153,
65,
57,
262,
64,
55,
8,
7,


310
053
898
031
364
352
838
809.
499.
010.
905,
662.
921.
601.
662.
052.


.50
.40
.70
.00
.00
.00
.20
.00
.00
.10
.90
.00
.50
50
81
68

0
0
0
0
0
0
0
0
0
0
0
0.
1.
1.
1.
1.
1.

-1.079
.000
.872
.892
.902
.918
.930
.947
.957
.967
.976
.984
.993
.001 2378 -TCDF AN
.017
.026
037
070






E
'E
QE
E
E
E


E





0.959-1.041
92
550
351
19,404
19,755
.48
.81
.73
.20
.93


206.
8,293.



74
10




11,



198.
111.



72
10

0.
0.
0.
1.

000
933
977
000 13C12-2378-TCDF ISO






                                    Above: TCDF / TCDD Follows
TCDD
320-322 DC NL 0
NK 22
NK 23
K 23
D D SN 23
D D SN 23:
D D SN 23:
D D SN 23:
K 24:
24:
24:
M 25:
AN 25:
25:
0.
:00 RO
:48
:12
:29
:43 RO
:52 RO
:52 RO
:58 RO
ill
:27
:50
;15
:21
32
65-0.89
0.05
0.70
0.78
0.74
1.63
1.18
1.13
2.31
0.82
0.75
0.80
0.75
0.74
0.73
0.895-
37
282,030
163,874
20,505
1,147
464
609
320
63,021
32,116
15,186
60,400
3,280
7,033
.54
.00
.80
.63
.51
.20
.80
.39
.90
.10
.02
.00
.00
.78

116,595
71,703
8,742




28,386.
13,789,
6,744.
25,900.
1,400.
2,969.
	
.00
.20
.13




.10
,60
,66
,00
00
55
V.
165,
92,
11,




34,
18,
8,
34,
1,
*,

435
171
763




635.
326.
441.
500.
880.
064.

.00
.60
.50




80
50
36
00
00
23
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
•1.047
000
900
916
927
936
942
942
946
955
965
980
997
001 2378 -TCDD
008
                                                                                                    E

                                                                                                    QE
                                                                                               AN   PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                        Printed: 10:18 01710/98
                                                                                                       133

-------
  Page No.     2
  01/10/98

  Compound/
  M_Z.... QC.Log Omit Why
Listing of 0980029B.dbf
Matched GC Peaks / Ratio / Bet. Time
.RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name. .  10..  Flags.



320-322
37C1-TCDD
328













328
13C12-TCDD
332-334
25
25
26
:40
:54
:20
0.73
0.66
0.74
12 Peaks

DC ML 0
DC WL 22
DC WL 22
. DC WL 23
DC WL 23
23
23
24
24
24
24
24
25
25:

:00
:39
:49
:05
:12
:25
:58
:11
:19
:27
:40
:50
:21
44















9 Peaks

0
DC NL 0:00 RO
24:11

24:
42 RO
25:10




332-334
PeCDF
340-342










M
AN



25:
25:
25:
25:
20
39
53 RO
56 RO
7 Peaks

DC NL 0:
26:
26:
27:
27:
27:
27:
27:
27:
28:
28:
28:
28:
28:
28:
29:
1.
00 RO
36
48 RO
04 RO
14 RO
22 RO
36
44
55
12
19
30
35
45
52
17
.65-0.89
1.63
0.67
1.22
0.81
0.81
0.77
1.05
1.51
6,746.39
2,589.37
2,162.91
658,946.90

164.66
65.15
1,517.08
640.72
966 . 28
274.46
19,256.70
537.07
372.94
157.60
556.72
218.26
12,032.60
14,645.30
48,051.65
2,850
1,032
917







274
19,256
537
372
157
556
218
12,032
14,645

.86
.12
.71







.46
.70
.07
.94
.60
.72
.26
.60
.30

3,895
1,557
1,245

















.53
.25
.20

0.















1
1
1

921
0
0
0
0
0
0
0
0
0
0
0
0
1
1

.013
.022
.039

-1.079
.000
.894
.901
.911
.916
.924
.946
.955
.960
.965
.974
.980
.001 37C1-TCDD
.016


















CLS


0.921-1.079
29.95
Il5 . 17
41.63
21,107.87
14,916.33
1,003.84
73.79
181.46
37,440.09
32-1.78
0.76
1.53
0.77
4.35
6.54
4.88
1.71
1.55
1.66
1.61
1.57
1.57
1.61
1.66
1.66
1.58
24.07
169,674.90
9,224.95
2,553.29
1,345.56
1,878.79
53,521.80
368,690.00
88,383.70
158,042.20
198,580.30
87,800.00
66,200.00
62,253.60
112,576.90
130,284.70

46
28
9,471,
6,681.
437.
43.
154.

.05
.77
.57
.33
.57
.70
.49

69.
23.
11,636.
8,235.
566.
41.
102.

.12
.52
30
00
27
69
52
0
0
0
0
1.
1,
1,
1.
.000
.955
.975
.993 13C12-1234-TCDD
.000 13C12-2378-TCDD
.013
.022
.024



RSI
IS1






102,544.
5,607.
4,356.
3,449.
3,594.
33,770.
223,864.
55,159.
97,398.
121,294.
53,600.
40,800.
38,813.
70,277.
79,692.

00
32
90
71
19
00
00
20
20
00
00
00
00
20
00

67,130.
7,279.
1,001.
527.
736.
19,751.
144,826.
33,224.
60,644.
77,286.
34,200.
25,400.
23,440.
42,299.
50,592.
0.925-1.065

90
42
29
67
78
80
00
50
00
30
00
00
60
70
70
0.
0.
0.
0.
. 0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
000
931
938
947
953
957
966
970
977
987
991
997
000 12378-PeCDF
006
010
024 23478-PeCDF












AN


AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:18 01/10/98
                                                                            134

-------
  Page No.
  01/10/98
Listing of 0980029B.dbf
Matched GC Peaks / Ratio / Ret.  Ti
  Compound/
  M_Z....  QC.Log Omit Why
,RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.
  340-342

  13C12-PeCDF
  352-354
  352-354
  PeCDD
  356-358
  356-358

  13C12-PeCDD
  368-370
29
29
30
30
:26
:44
:07
:15


RO

1
1
4
1
.54
.71
.46
.60
19 Peaks

DC NL 0
26
26
27
27
28
28
28
29
29
29
29
29
30

:00
:36
:47
:46
:56
:19
:35
:52
:04
:16
:35
:42
:52
:06
30:16
1
RO
RO



RO

RO
RO


RO
RO
RO
RO
.32
1
1
1
1
1
30
1
1
1
1
1
1
0
1
0
14 Peaks.

DC NL 0:
DC WL 27:
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:

00
36
51
19
32
41
52
02
08
19
28
37
45
05
1.
RO
RO
RO




RO


RO



-1.78
.08
.80
.58
.40
.43
.76
.57
.15
.97
.45
.58
.07
.67
.89
.75
181
44

15
1,751







16


14,





,151.70
,196.70
392.83
,235.04
,986.96

33.36
97.08
133.58
265.72
739.35
396.65
,016.44
649.58
145.40
.107.16
459.85
234.90
130.28
80.94
111.99
33,568.92
32-1.78
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
.92
69
31
36
53
60
57
79
44
56
98
55
60
62
12 Peaks

DC NL 0:
27:
28:
28:
28:
28:
29:
29:

00
48
17
33
42
52
03
20
1.
RO
RO
RO

RO

RO
RO
32-
1.
4.
2.
1.
1.
1.
0.
0.
1.78
15
30
73
71
09
58
32
34


131,
10,
98,
15,
68,
7,
17,
26,
12,
13,
10,
8,
420,
12.77
983.28
094.84
440.93
612.70
436.68
591.40
989.76
334.86
946.10
093.58
177.15
543.65
107.54
369.19
109,717
27,915
686
9,386



68
81
155
435
4,783
9,791
394
112
8,338
281
142
79
60
68
.00
.10
.87
.42



.51
.80
.14
.24
.95
.10
.84
.21
.52
.76
.78
.19
.02
.07
71,434
16,281
154
5,848



38
51
110
304
155
6,225
344
57
5,768
178
133
118
31
90
.70
.60
.05
.62

0.

.07
.78
.58
.11
.55
.34
.47
.02
.64
.09
.88
.35
.74
.85
1.030
1.040
1.054
1.058

860-1.140
0.000
0.931
0.937
0.971
0.977
0.991
1.000 13C12-PeCDF 123 IS2
1.010
1.017
1.024 13C12-PeCDF 234 SOR1
1.035
1.039
1.045
1.053
1.059






79,685.10
6,012.81
59,647.60
9,502.
.51
41,949.10
5,593.
.27
10,240.20
16,428.
90
7,351.00
8,002.41
6,485.
5,009.

96
36



60,994.
4,428.
38,965.
5,934.
26,642.
3,133.
7,094.
10,517.
7,514.
5,174.
4,057.
3,097.

0.935-1.022


.20
,12
10
17
30
24
66
20
00
74
69
68

0.000
0.932
0.941
0.957
0.964
0.969
0.975
0.981
0.984
0.990
0.995
1.001 12378-PeCDD AN
1.005
1.016

0.865-1.135








12.63
72.27
39.17
56.01
14.54
19.37
20.53
61.91

121.
41.
35.
8.
11.
12.
37.

73
97
34
84
87
48
63

28.
15.
20.
8.
7.
38.
111.

34
36
67
13
50
63
26
0.000
0.939
0.956
0.965
0.970
0.975
0.981
0.991
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:1801/10/98
                                                                                 125

-------
  Page So.     4
  01/10/98

  Compound/
  M_Z.... QC.Log Omit Why
Listing of 0980029B.dbf
Matched GC Peaks /  Ratio / Ret. Time
.RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.







368-370
HxCDF
374-376










AN
M
374-376
13C12-HXCDF
384-386









384-386
HxCDD
390-392
D







29
29
30
30
30
30
30
:36
:44
:05
:17
:24
:29
:36
1
1
RO 0
RO 1
RO 1
RO 0
RO . 0
14 Peaks
.52
.65
.45
.86
.09
.33
.30
7,848.71
1,355.30
141.37
97.41
132.44
225.12
324.18
10,408.33
	 nw_..._. . n^f+nn / u
1.05-1.43
DC NL 0
31
31
31
31
'31
32
32
32
32
32
X 33
33
:00
:06
:14
:24
:32
:41
:02
:09
1
1
1
1
1
1
1
.25
.26
.26
.30
.23
.27
.26
1.26
:16 1.29
:26
:38
:23
:28
1,
1.
1.
1.
12 Peaks
.24
.26
.30
,25
1
7,026.95
140,660.80
317,799.00
31,584.30
45,572.90
25,270.90
297,473.00
133,092.30
39,335.70
56,792.90
158,650.30
8,080.00
36,600.00
,290,912.10
4,730
843
85
71
80
136
197
.01
.18
.93
.02
.50
.34
.05
3,118
512
192
38
74
420
647
.70
.12
.81
.20
.10
.41
.30
1.000 13C12-PeCDD 123 IS3
1.005
1.016
1.023
1.027
1.030
1.034










78,431
177,313
17,851
25,150
14,132
165,937
74,104
22,160
31,387
88,494
4,570
20,300


.80
.00
.70
.20
.90
.00
.50
.50
.20
.50
.00
.00


62,229
140,486
13,732
20,422
11,138
131,536
58,987
17,175
25,405
70,155
3,510
16,300

0.43-0.59
DC NL 0:
31:
31:
31:
32:
32:
32:
32:
32:
33:
00
13
31
50
03
09
26
38
55
23
RO 0.
RO 1.
RO 1.
RO 1.
0.
0.
RO 0.
0.
RO 2.
0.
9 Peaks

DC NL 0:
D SN 31:
31:
32:
32:
32:
32:
32:
33:

00
26
35
01
14
24
45
50
07
1.05-
RO 0.
RO 0.
1.
1.
1.
RO 1.
1.
1.
1.
77
07
61
75
53
53
36
56
15
52
115.38
452.88
154.52
93.36
9,790.49
11,961.66
471.12
11,966.56
303.92
8,871.10
44,065.61
— &H/MTA • Hvf*mi* / It'
AJjOVe . nXL.L/£ / HJ
1.43
63
49
26
22
24
00
24
27
25
1,296.83
1,066.98
25,794.00
194,623.70
69,233.30
12,414.51
10,433.29
20,048.12
28,354.00

319,
164.
108.

.68
,29
,15
3,395.73
4,138.
,76
159.12
4,307.
433.
3,023.
66
32
48

299.
102.
61.
6,394.
7,822.
438.
7,658.
201.
5,847.
0.962-1.047

.00
.00
.60
.70
.00
.00
.80
.20
.70
.80
.00
.00

0.000
0.967
0.971
0.977
0.981
0.985
0.996 123478-HxCDF AN
1.000 123678-HxCDF AN
1.004
1.009
1.015 234678-HxCDF AN
1.038 123789-HxCDF AN
1.041


E
E



E



E
PR


0.876-1.124

.92
.33
,83
76
90
99
90
27
62
0.000
0.971
0.980
0.990
0.997 13C12-HXCDF 478 SOR2
1.000 13C12-HXCDF 678 IS4
1.009
1.015 13C12-HXCDF 234 ALT2
1.024
1.038 13C12-HXCDF 789 ALT1














14,395.
107,046.
38,268.
6,872.
5,774.
11,199.
15,777.


80
00
90
32
74
00
10


11,398.
87,577.
30,964.
6,890.
4,658.
8,349.
12,576.
0.958-1.014


20
70
40
22
55
12
90
0.000
0.958
0.963
0.976
0.983
0.988
0.998 123478-HxCDD AN
1.001 123678-HxCDD AN
1.010 123789-HxCDD AN



E





Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:1801/10/98
                                                                               136

-------
  Page No.
  01/10/98
Listing of  (J980029B.dbf
Matched GC  Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio  Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
  390-392
                       7 Peaks
                                          360,900.92
  13012-HxCDD
  402-404
  402-404
  HpCDF
  408-410
  408-410
       r HpCDF
  418-420
  418-420
  HpCDD
  424-426
         D

         D

  424-426

  13C12-HpCDD
  436-438

  436-438
 OCDF
 442-444

 442-444

 OCDD
 458-460

DC





NL 0:00
32:44
32:48
33:08
3 Peaks
1.05-1.43
1.28
1.20
1.21
1.21

49.51
7,138.51 3,892.28
10,086.19 5,527.69
13,149.04 7,205.62
0.970-1.030
0.000
3,246.23 0.998 13C12-HXCDD 478 SOR3
4,558.50 1.000 13C12-HXCDD 678 IS5
5,943.42 1.010 13C12-HXCDD 789 RS2





30,373.74
0.88-1.20
DC



DC
DC



DC



NL 0:00
35:02
35:18
35:27
NH 35:55
NH 36:00
36:34
4 Peaks

NL 0:00
35:01
36:33
2 Peaks
RO 1.25
1.04
1.05
1.06
0.97
RO 1.40
1.04

0.37-0.51
RO 1.80
0.45
0.44
388.62
588,703.00 300,809.00
125,484.30 64,195.70
165,389.90 84,938.20
2,430.58
2,241.33
78,802.90 40,254.30
958,380.10

54.16
8,347.82 2,582.48
6,553.21 2,009.07
0.996-1.049
0.000
287,894.00 1.000 1234678-HpCDF AN
61,288.60 1.008
80,451.70 1.012
1.026
1.028
'38,548.60 1.044 1234789-HpCDF AN

0.943-1.114
0.000
5,765.34 1.000 13C12-HpCDF 678 IS6
4,544.14 1.044 13C12-HpCDF 789 SOR4


E
E
E








14,901.03
0.88-1.20
DC
DC

DC



DC


NL 0:00
WL 35:10
35:18
NH 35:35
36:03
2 Peaks

NL 0:00
36:03
1 Peak
RO 1.53
RO 0.44
0.97
RO 0.60
1.02

0.88-1.20
1.10
1.07
75.56
29,813.03
103,113.80 50,872.60
7,956.96
97,271.20 49,025.30
200,385.00

53.36
7,059.90 3,641.62
7,059.90
0.76-1.02
DC



DC

NL 0:00
39:50
1 Peak

NL 0:00
39:38
RO 4.34
0.91 1,
1,
0.76-1.02
0.77
0.84
66.19
268,705.00 604,537.00
268,705.00

21.91
135,424.50 61,921.40
0.975-1.005
0.000
0.975
52,241.20 0.979
0.987
48,245.90 1.000 1234678-HpCDD AN

0.972-1.028
0.000
3,418.28 1.000 13C12-HpCDD 678 IS7

0.899-1.101
0.000
664,168.00 1.005 OCDF AN

0.899-1.101
0.000
73,503.10 1.000 OCDD AN



E

E







SE



E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 10:18 01/10/98

-------
  Page No.      6           Listing of 0980029B.dbf
  01/10/98                  Matched GC Peaks / Ratio / Ret.  Time

  Compound/
  M_Z.... QC.Log Omit  Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.

  458-460                1  Peak              135,424.50

  13C12-OCDD                    0.76-1.02                                     0.996-1.004
  470-472          DC   NL    0:00 RO  1.42         15.01                             0.000
                          39:37     0.87     11,219.87      5,204.93      6,014.94  1.000 13C12-OCDD      IS8
  470-472                1  Peak               11,219.87
  Column Description	  "Why" Code Description	  QC Log Desc.
  M_Z   -Nominal  Ion Masa(es)     WL-Below Retention Time  Window   A-Peak Added
  ..RT.  -Retention Time  (mm:as)   WH-Above Retention Time  Window   K-Peak Kept
  Rat.l  -Ratio of M/M+2  Ions      SN-Below Signal to Noise Level   D-Peak Deleted
  OR    -RO-Ratio Outside Limits  
-------
rilo:O980029 tl-724 Acq: 6-JKS-1998 19:43:44 GC EH- Voltage 515 705 Boiamtl012427
303.9016 T:2 BSUBf 256, 30, -3. 0) PXD(9,5,3,0.10\,4049708.0,1.00\,T,T) XxpiSDBSVS
TRIANGLE LABS Text: 157-160/166 TLIt44376A
1001
80.
60.

40.

20.

A1.98E9


A1.22E9
A1.60E9 _ t_ „ A
A A7.47S8 l\
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22:00 23:00 24:00 ' 25:00 25:00 Mae
File iU9 30029 tl-724 Acq: 6-JJUT-1998 19:43:44 GC XI+ Voltage SIS 70S OoJLafs 1724910
J05.W87 T:2 BSUB(256,30,-3.0) PXD(9,5,3,0.10\,6899640.0,1.00\,F,T) XxpiNDBSUS
TRIANGLE LASS Text: 157-160/166 TUt44376A
1001
80.
60.

40.
20:

A2.S3E9


A1.53E9
A2.14E9 aaro A 11
r\ Ay.yottO \\ it
A A. AAl.27E^V _L A6.49X8
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22:00 23:00 24:00 25:00 25:00 liae
Tile:U980029 tl-724 Acq: 6-JZX-1998 19:43:44 GC EI+ Voltage SIS 70S Soiae: 34904
315.9419 f:2 BSUB(256, 30, -3.0) PKD(9, 5, 3,0. 101,139616. 0,1.00\,f,T) ExpsSDBSOS
TRIANGLE LABS Text: 157-160/166 TLI044376A
looa
80:
50:
40:
20:
o-

A8.29E7




- . J L
-2.1X7
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r±J.e:a980029 tl-724 Acq: 6-JKN-1998 19:43:44 GC EI+ Voltage SIS 70S SOiae>26124
317.9389 f:2 BSUB(256, 30, -3. 0) PKD(9,5,3,0.10\,104496.0,1.00\,r,T) XxpsNDBSOS
TRIANGLE LASS Text: 157 -160/166 TLH44376A
1001
80:
50:
40:
20:
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ju.ilza
I



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,2.8X7
.2.3X7
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r±le:0980029 tl-724 Acq: 6-J3UT-1998 19:43:44 GC EH- Voltage SIR 70S
330.9792 7:2 ExpiNDBSOS
TRIANGLE LABS Text: 157-160/166 TLH44376A
1001
80:
50:
40:
20:
o'-

21^48 22:50 23:2823:48 24^10^ 24:57 35,19 25:4426:0426:24
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22:00 23:00 24:00 25:00 35:00 Xiae
Mle: 0980025 tl-724 Acq: 6-JZ1T-1998 19:43:44 GC EH- Voltage SIS 70S
375.8364 7:2 ExpiNDBSUS
TRIANGLE LASS Taxtt 157 -160/166 TLH44376A
1001
80:
50:

-------
 Fila:0980029 tl-724 Acq: 6-JAN-1998 19:43:44 SC XH- Voltage SIS 70S tfoiae:8164
 319.8965 r:2 SSUB(256,30, -3.0) PXD(7,5,3,0.10\,32656.0,1.00\,r,T) XxpsKDBSVS
 TSIANGLX LABS  Text: 157-160/166  TLIt44376A
 1004
80:
50:
40:
20:
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             A7.17X8
                   A8.74X7
                                 A2.84EB
                                   /\A1.38*8 A6.7417
                                     ^X"^^       •S^
         23:00                 24:00                 25:00                 26:00
 rU.e:0980029 tl-724 Acq: 6-JZJT-1998 19:43:44 SC XH- Voltage SIS 70S Noiae:167392
 321.8936 Ti2 SSUS(256,30,-3.0) PXB(7,5,3,0.101,669568.0,1.00\,f,T) Xxp:ODB5US
 TSIANGLX LABS  Text: 157-160/166  TLH44376A
 100\
80:
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40:
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             A9.22X8
                                  A3. 46X8         .
                                        A1.83X8 A8.44X7
                                   f\
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         23:00                 24:00                 25:00                26:00
File10980029  tl-724  Acq:  6-JZN-1998 19:43:44 SC XH- Voltage SIS 70S JToiaet 13785
331.9368 T:2  BSUB(256,30,-3.0)  PKD(7,S,3,0.10\,55140.0,1.00\,r,T)  Xxp:SDB5US
TSIAXGZE LASS  Text: 157-160/166  TLIt44376A
100*                                                   A9.47X7
  80.
  60:
  40:
  20:
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                                                           6.68X7
         23:00                 24:00                 25:00                26:00
rile:OSa0029 tl-724 Acq:  6-J7OT-1998 19:43:44  SC XH- Voltage SIS 70S Soiae:8460
333.9338 F:2 BSUS(256,30, -3.0)  PKD(7,5,3, 0.10%,33840.0,1.00\,T,T)  XxpsSDBSUS
TSIANGLX LASS  Text: 157-160/166  TLIt44376A
1001                                                   Al.i6E8
80:
60:
40:
20:
                                                            B. 23X7
         23:00                 24:00                 25:00                 26:00
rile:U980029 tl-724 Acq:  6-JJOT-1998 19:43:44  SC XH-  Voltage  SIS  70S B6lae:82332
327.8847 T:2 BSO3(256,30,-3.0)  PKD(7,5,3,0.10\,329328.0,1.00\,f,T) Xxp:SDB5US
TRIANGLE LABS  Text:157-160/166  TLIt44376A
1001
 so:
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                             Al . 93X8
                                                                  A1.46X8
                                                          A1.20X8
                               24:00                25:00
Tlle>O9B0029 tl-724 Acq: 6-JAK-1998 19:43:44 SC XI+ Voltage SIS  70S
330.9792 Ti2 XxpiRDBSUS
TRIANGLE LABS  Text: 157-160/166  TLIt44376A
                                                                          26:00
1001
 80:
 sol
 40:
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  0.
     22:50
                                         4:27
                                                  24:5725:13
                                                                  25:44   36:04 .26:24
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                                                    25:00
                                                                          26:00
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                                                                                              .9. 0X6
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                                                                                               2.8X7
                                                                                              '•.2.2X7
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                                                                                                  Time
                                                                                                       140

-------
rilesa980029 tl-724 Acqs 6-JXX-1998 19:43:44 SC Eli
Voltage SIR 70S Hoiae:7317
339.8597 Ts2 BSUS(256, 30, -3.0) na>(7r5,3,0.10\f29268.0,1.00\,r,T)
XRIASSLX LABS Texts 157-160/166
100.
80.
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341.8567 ts2 BSUB(256,30,-3.0) PXD(7t5,3,0.10\,3a568.0,1.00\,r,T) XxpsSBBSUS
TRIASSLX LABS Text: 157-160/166
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351.9000 Ts2 BSUB(256,30,-3.0) rXD(7,5,3,0.10\,40568.0,1.00\,T,T) XxpsSDBSOS
TRIASSLX LABS Texts 157 -160/166 TLIt44376A
1003
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353.8970 T:2 3SUB(2S6,30,-3.0y PXD(7,S,3,0.10*,37448.0,1.00\,T,T) ExpsSDBSUS
TRIANGLE LABS Texts 157-160/166 TLIt44376A
100J

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330.9792 f:2 XxptSDBSOS

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TRIASSLX LABS Texts 157 -160/166 TLH44376A
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26±54 27:20 27:40 28:05 28:34^ 29:03 _J9_sJ7 31





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409.7974 rt2 ExpiNDBSUS






25:00





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TRIASSLX LABS Text: 157-160/166 TLI044376A
1001
80:
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25:48 ,, „-, r?.
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-------
 f3-La:OSaooS3 il-714 Acq: 6-JAK-199S IS:43144 SC EI+ Voltage SIS 70S Noiae:JB80
 355.8546 F:2 BSOB(256,30, -3.0) ?XB(5,5,3,O.OS\, 15520.0,1.00\,T,T) XxpiHDBSOS
 TSIAHSLX LASS  Text: 157-160/166  TLH44376A
 100$  A7.97X8               AS. 96ft
  80.

  60.

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      27:48  26100  28,12  28t24  28i36  28t48 29:00 29:12 29:24 29:36  29i48 30:00 30:12  30:24
rile:0980029 fl-724 Acq:  6-JAW-1998 19:43:44 GC EI+ Voltage SIX 70S N6±a»:4208
357.8516  Ti2 SSVB(256,30,-3.0) rXD<5,5,3,0.05\,16832.0t1.00\,r,T) XxptODBSUS
XSIANGZX  LASS  left: 157-160/166  TLH44376A
      A6.10X8
                                       A2.66E8
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                                                                 \A4.06E7   A3.10X7
      27:48 28:00  28:12 28:24 28:36  28:48  29:00 29:12 29:24 29:36  29:48  30:00 30:12 30:24
r±le:O980029 tl-724 Acq:  6-JJOT-1998 19:43:44 GC EI+ Voltage SIS 70S lToiaa:3842
367.8949 T:2 SSUS(256,30, -3.0) PXD(S,5,3,0.05\,15368.0,1.00\,T,T)  Xxp:SDS5US
TRIANGLE LASS  Text: 157-160/166  XLH44376A
10M                                                         A4.73X7

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      27:48 28:00 28:12 28:24 28:36 28:48  29:00  29:12 29:24 29:36 29:48  30:00 30:12 30:24
rlle:a980029 tl-724 Acq:  6-JXK-1999 19:43:44  GC EH- Voltage  SIS  70S So±ae:3330
369.8919 T:2 3SUB(256,30,-3.0)  PXD(5,5,3,0.05\,13320.0,1.00\,TrT) Xxp:SDS5US
TSIAKGLX LASS  Text: 157-160/166  TLH44376A
1001                                                         A3.12X7

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330.9792 T:2 Sxp:«DS5aS
TBXANGLX LASS  Text: 157-160/166  TLH44376A
                                                                                                0.0X0
                                                                                                   Time
1001

 80.

 60.

 40.

 20.

  0.
         27:54 28:05 28:16
                              28:34
                                                                                    30:19
     27I:48' 28:00' 28:12  28:24 28:36 28:48 29:00 29:12  29:24' 29':36 29:48 30:00  30:12 30:24
.8.8X7

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1.8X7

0.0X0
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                                                                                                         142

-------
Tlle:O9S0029 tl-385 Acq:  6-JZS-1998 19:43:44 GC XH- Voltage SIX 70S Noiae: 1950039
373.8208 T:3 BSU3(256,30, -3. 0)  ?KD(7,5,3,0.10\,7t00116.0,1.00\,T,T) ExpiNDBSUS
TSIAHSLX LASS  Text: 157-160/166  TLH44376A
100J

  80.

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  40:

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          Al
       A7.84XS
              77X9
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    31tOO 31:12  31:24 31,36 31:48  32:00 33:13 32:24 32:36  32:48  33,00 33,12 33:24  33:36 33:48
rile:U9B0029 tl-385 Acq: 6-JAN-1998  19:43:44  CC IT* Voltage  SIS  70S Noiae, 1563444
375.8178 Ti3 BSUB(256,30, -3.0) fXD(7,5,3,0.10\r6353776.0,1.00\,T,T) XxpiSDBSOS
         LASS  Text: 157-160/166  TLIt44376A

                                    A1.32X9
ion
 so:
 50:
 40:
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      A6.22X&
                                                      A7.02X8
                    A2.04X8
                                                                                 A1.65E8
    31:00 31:12  31:24 31:36 31:48  32:00 32,12 32:24 32:36  32:48  33,00 33:12 33:24  33:36 33:48
r±lo:O9S0029 tl-385 Acq: 6-JXH-1998  19:43,44  SC XZ+ Voltage  SIS  70S Noise:29516
383.8639 Ts3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\r118064.0,1.00\,r,T) ExpiHDBSUS
ZBXAXSZX LASS  Text: 157-160/166  TLH44376A
lOOi

 80:

 60:
          A3.20E6
  40:

  20:

  ol
    31:00 31:12  31:24 31:36  31:48 32:00 32':12 32:24 32:36  32:48 33:00 33:12  33:24  33:36 33:48
TileiU980029 tl-385 Acq: 6-JZJT-1998 19:43:44 GC XX+ Voltage  SIS 70S lToiae:38205
385.8610 T:3 3SV3(2S6,30, -3. 0)  PKD(7,5,3,0.10\r152820.0,1.00\rrrT)  XxpiNDBSUS
TBIANGLX LASS  Text: 157-160/166  TLIt44376A
100$                                   A7.82X7       A7.66E7

  80:

  60:

  40:

  20:
    31:00 31:12  31:24 31:36 31:48  32:00 32:13 32:24 32:36  32:48 33:00 33:12  33:24  33:36 33:48
rile:U980029 tl-385 Acq: 6-JAS-1998 19:43,44 GC XH-  Voltage  SIS  70S
392.9760 f:3 Xxp:NDB5VS
TBXASGZX LABS  Text: 157-160/166   TLH44376A
100*^^31:13 31,24        ^JL/JL-?3^0.3 32:13     32:34^   _ _J2ji56       33:1933:29

 80.

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 40:

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                                                                                                     0.0X0
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                                                                                                     0.0X0
                                                                                                        Tiae
                                                                                                     4.1X7

                                                                                                    .3.2X7

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    31:00 31:12  31:24 31:36 31:48  32:00 32:13 32:24 32:36 32:48  33:00 33:12 33:24  33:36  33:48
r±lei0980029 tl-385 Acq: 6-JAN-1993 19t43:44  GC XH- Voltage SIS  70S
445.7555 T:3 XxptKDBSUS
TBIAHGZX LABS  Text: 157-160/166  TLIt44376A
1001
                                                                                                    0.0X0
                                                                                                       Tine
 80:
 50:

 40:
 20:
  oj
                                                      3
                                      33:05
                                                        : 36
    31:00  31:12 31:24 31:36  31:48 32:00 3213  32i 24  32': 36 ' 32'i48'
                                                                         33:12 33:24 33: 36
                                                                                                       143

-------
         31': 36    31:48   33:00    32il2   32:24   32:36   32:48    33:00   33:12
\rUa:0980029 #1-385 Actj:  6-JXB-1998 19,43,44 SC XX* Voltage  SI*  70S Koiaeil3917
401.8558 r>3 BSOB(256e30,-3.0)  PXn(7,S,3,0.10\,5S668.0r1.00\,r,T)  XrptSDBSaS
TSIASSLX LABS  Texts 157-160/166  TLX944376A
100\                                                                    A7.21X7
 rU.a,U9U(JUjy  IU-.J85 Acq: 6-JAN-1S9B 13,41,44 SC EI+ voltage SIR 70S Noiaa,J5aS4J
 389.8156 T:3  BSUB(256,30,-3.0) PXB(7,5,3,0.10\,143S772.0,1.00\fr,T) XxpiODBSUS
 TSIAKSLX LABS  Text: 157-160/166  TLXI44376A
                           A1.07E9
  so:
  eo:
        A1.44X8
                                                            AJ..12XS
                                                                       AJ..38E8
          31:36   31:48    32:00   32:12   32:24   32:36    32', 48   33tOO   33:12
r±I»>US80029  tl-385 Acqs  6-JAV-1998 19t43,44 SC KT+ Voltage SIX 70S Soiat»572134
391.8127  Ti3  B3U3(256,30,-3.0) PXD(7,5,3,0.10\,22S8536.Q,1.00*,r,T) SzptlWBSUS
TBIAXGLX  LABS TextilS7-160/166  TLH44376A
100\                      AS.26X8
  so:

  50-
                                                                              .O.OEO
                                                                   33:24    33',36 Ha>
        A1.14E8
                                                           A8.85E7
                                                                        A1.26E8
  80.

  60.

  40.

  20.

  0.
                                                           A5.53S7
         31:36    31:48   32:00    32:12   32:24   32:36   32': 48    33:00   33:12
\rilaiO980029 fl-385 Actj:  6-JKK-1998 19,43:44 SC ZH- Voltage SIS 70S Noise: 10842
403.8529 T:3 BSOB(256,30,-3.0) PXD(7,S,3r0.10\r43368.0,1.00\,r,T) EzptUDBSUS
XRIAHGLX LABS  Texts 157-160/166   TLI944376A
                                                                        AS.94X7
                                                                   33124
lOOi

  80.

  60.

  40.

  20.

  0.
                                         A4.56X7
         31:36   31:48   32:00   32:12   32:24   32:36   32', 4 8   33': 00
rile I0980029 H-385 Acq: 6-JAH-1998 19143144 SC XH- Voltage SIS 70S
392.9760 T,3 XxptSDSSUS
TRIASGLX LABS  Text 1157-160/166  TLH44376A
                                                                            33', 12   33:24
                                                                              -3.4X8

                                                                              '.2.8X8

                                                                              '.2.1X8

                                                                              11.4X8

                                                                              '.6.9X7
                                                                              -2.8X8

                                                                              12.2X8

                                                                              11.718

                                                                              11.128

                                                                              '.5.6X7
                                                                              '.0.0X0
                                                                   33:24   33:36  Time
                                                                              .0.0X0
                                                                           33',36  Tioel
                                                                              '.0.0X0
                                                                           33136  T±*e\
  80J

  SO.

  40.

  20.

  0.
       31,32
                                                                                 33il9  33i29
         31,36
                                                                              .3.2X7

                                                                              .2.4X7

                                                                              .1.6X7

                                                                              .8.1X6

                                                                              .0 . 010
31t48    32:00   32:12   32s24   32i36    32i48    33iOO   33il2    33:24    33t36  Mae]
                                                                                                       144

-------
 rile:D9B0029  ti-S4S Acqs  6-JAN-1993  19,43,44 SC BI+ Voltage SIX 703 Noiaes119081
 407.7818  T:4  BSUB(2S6,30,-3.0) PXD(7,S,3,0.10\,476334.0r1.00\,T,T) Exp:HDB5OS
 TXIASSLS  LABS  Texts 157-160/166   TLH44376A
 10M    A3. Q1X9

  80:

  60:

  40:
                           AB.49EB
                     y\yv
                                                                          A4.03X8
         35,00    35,12    35,24   35,36    35,48   36*00    36,12   36,24    36,36
rile,0980029 tl-545 Acq,  6-JJM-1998 19,43,44 CC JET* Voltage SIS 70S Solae>95351
409.7789 Ti4 BSUB(356,30,-3.0) PXD(7,5,3,0.10\,381004.0,1.00\,f,T)  SxpiNDBSUS
TSIAHSZX LABS  Texts 157-160/166  TLIt44376A
IOCS    A3.98X9

  80.

  60:
                                                                                     36,48
  40:

  20:
                          A3.05X3
                                                                         A3.asxa
        35,00    35,12    35,24    35,36    35,48   36:00    36,12    36,24    36,36
f±la:U980029 tl-545 Ac?:  6-JAH-1998 19,43,44 GC JET* Voltage SIS 70S Noise:33935
417.8353 T:4 BSUB(256,30, -3. 0) PXD(7,5,3, 0.10\,135740.0,1.00\,TrT)  ExptSDBSUS
TRIASSLZ LABS  TextslS7-160/166  TUt44376A
1004    A2.S.8E7
                                                                                     36,48
  80:
  60:
  40:
  so:
                                                                         A2.01E7
        35,00    35,12   35:24    35:36    35:48    36:00   36:13    36,24    36:36
rilaiO980029 tl-545 Acq: 6-JAS-1998 19:43:44 SC SH- Voltage SIX 70S  Noine: 18803
419.8220 Ti4 BSDB(256, 30, -3.0) PXD(7,5,3,0.10\,75212.0,1.00\,r,T) Sxp:SDB5US
         LABS  Text: 157-160/166  TLIt44376A
        AS.77E7
                                                                         A4.54E7
                                                                                     36:48
        35,00    35',12   35:24    35:36    35:48    36-00   36,12    36:24
Flla,0980029 tl-545 Acqs 6-JAN-1999 19,43:44 GC XI + Voltage SIX  70S
430.9729 F:4 ExpsSDBSUS
TRIANGLE LABS  Text: 157-160/166  TLIt44376A
         35,01       35,18 3Zi27_         3S.4S         36,0436,12
1001

 80:

 60:

 40:

 20:
                                                                            36:36
                                                                                     36,48
36:38 36,46
                                                                                                  -.8.3X8

                                                                                                   .6.7E8

                                                                                                   .5.0X8

                                                                                                   .3.3X8
                     .O.OEO
                37100    Ha,
        35,00    35,12    35,24    35,36   35,48    36-00   36,12    36,24
Tile,U980029 tl-545 Acq: 6-JOOT-1998 19:43:44 GC XI+ Voltage SIX  70S
479.7165 f:4 ExpiRDBSUS
TXIASSLX LABS  Text: 157-160/166  TLIt44376A
                                                         36:08
                                                     36*04
                                                                            36:36
                                                                                     36,48
        35:00
                35:12
                         35:24
                                  35:36
                                          35:48
                                                   36:00
                     -8.0X8

                     '.6.4X8

                     '-.4.8X8

                     .3.3X8

                     ia.sza
                                                                                                  F o.oiro
                                                                                              37:00    Time
                    -.6.6X6

                     '•.5.3X6

                     -.3.9X6

                     .2.6X6

                     •-1.3E6
                                                                                             37:00
                                                                                                      Tiae
                                                                                                   0.0X0
                                                                                             37:00    Tiae
                                                                                                   -.2.2X7

                                                                                                   Li.717

                                                                                                   L1.1J57

                                                                                                   1.5.6X6
                                                                                                  \-g.Ofo
                                                                                             37:00    Time
                                                           36:13    36:34
                                                                            36:36    36:48
                                                                                                  .0.0X0
                                                                                             37:00    Tiae
                                                                                                       145

-------
Fj-La>O980029  tl-545 Acqi  6-JAa-199S 19t43t44 SC sir Voltage SIS 70S
433.7766 Ti4  BSUi(256,30, -3. 0)  PXD(7,5,3,0.10\,113316.0/1.00\,r,T)  XzptJWBSUS
TSIAOSLX LASS Tmxt: 157-160/166  TLI944376A
            AS. 09X8
                                                            A4.90X8
                                                                                                .0.0X0
      15:12  35', 18  35',24 35',30  35,36 35',42  35',48 35',54 36',00  36:06 36:12  36:18 36:24  36:30    T±M»
rllmtU980029 tl-545 Acq: 6-JMT-1998  19,43:44  SC SH- Voltage SIX  70S Kola*,18519
425.7737 Ti4 BSU3(256,30,-3.0) PSD(7,5,3,0.10\,74Q76.0,1.00\,r,X) SxptBDBSUS
TSIANGLX LASS  Torts 157-160/166  TLH44376A
100\       A5.22X8
                                                           A4.82K8
      35:12 35:18  35:24 35:30  35:36 35:42 35:48  35:54 36:00  36:06 36:12 36:18 36:24
Tile:0930029 tl-545 Actf. 6-JAN-1998 19:43:44 SC XH- Voltage SIS 70S Soiae,13981
435.8169 F:4 BSUB(356,30, -3.0) PXS(7,5,3,0.10\,S5924,0,1.00\,r,T) Xxp:SDBSUS
TRIASSLX LABS  Text: 157-160/166  TLIt44376A
100\                                                       A3.64X7

 80.

 60.

 40.

 20:
                                                                                                jJ-.SXS

                                                                                                J..OX8

                                                                                                .7. 7X7

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                                                                                                 0.0X0
                                                                                                    Tin
      35:12 35:18  35:24 35:30  35:36 35:42  35:48  35:54 36:00  36:06 36:12  36:18 36:24
rilat0980029 tl-545 Actj: 6-J7Uf-1998  19,43:44 SC XX+ Voltage SIS 70S Noiaa: 13702
437.8140 Ti4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,S0808.0,1.00\,T,T) Kxp:NDBSas
TSIAHSZX LABS  Text: 157-160/166  TLIt44376A
1001                                                       A3.42E7

 80.

 60.

 40.

 20.

  0.
                                                                                                8.2X6

                                                                                                6.6X6

                                                                                                4.9X6

                                                                                               .3.3X6

                                                                                               .1.6X6
                                                             36:04    36:12
                                                                                                0.0X0
      35:12 35:18  35:24 35:30  35:36 35:42 35:48  35:54 36:00  36:06 36:12  36:18 36:24  36:30     T±ae
Tila,0980029 tl-545 Acq: 6-JAN-1998 19:43:44 SC XI+ Voltage SIS 70S
 30.9729 T:4 SrpiNDBSOS
TRIASSLX LABS  Text! 157-160/166  TLXt44376A
i00*        l*JLi*_

 80.

 60.

 40.

 301

  o:	
     35:12  35:18 35:24  35:30 35:36 35:42  35:48 35:54 36:00  36:06 36:12  36:18 36:24  36:30
                                                                                               -2.8X7

                                                                                               ^.2X7

                                                                                               -1.7X7

                                                                                               -1.1X7

                                                                                               .5.6X6

                                                                                                0.0X0
                                                                                                   Time
                                                                                                      14G

-------
rila:U980029 tl-545 Acq: 6-JAK-1998 19:43:44 SC XI+ Voltage SIX 70S Hoi.ee: 75923
441.7428 T:4 BSOB(256,30, -3 .0) PKB(7,5,3,0.10\,303692.0,1.00\,T,I) Xxp:XDBSaS
XSIANGLX LABS Text: 157-160/166 XLH44376A
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7399 r:4 BSVB(256, 30, -3.0) fXD(7,5,3, 0.10%, 70044. 0,1. 00\,r,T) Xxp:NDB5US
WSZX LASS Tart:157-160/166 TLIt44376A
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J5>00 36(:00 37's 00 38:00 39:00 40: 00 41
,0330023 tl-545 Acq: 6-JMT-199B 19, 43:44 SC KI+ Voltaye SIX 703
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MCLZ LABS Tart: 157 -160/166 TLIt44376A
J4-J/4A" J5A57 36:04 36,38 38:41 39:50
































35:00 ' ' ' 36:00 ' 37:00 ' ' ' 38:00 ' ' ' 39^.00
IO980029 tl-545 Acq: 6-J7OT-1998 19:43:44 SC XI+ Voltage SIX 70S
6775 T:4 X3Cp:SDB5US
HGLX LABS fort: 157-160/166 TLH44376A
35:00








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147

-------
 FlJ.aiU9aoOJ9  #1-545 Acq:  6-JAN-1999 19:43:44 SC Elf Voltage SIM 70S Noiaa:4750
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 TBIANGLX LASS  Tart: 157-160/166  TLH44376A
 IOCS
           39', 30         39t36         39>42        39:48        39:54         40:00
r±lfi0980029  H-S45 Acq:  S-JJOt-1998 19i43>44 SC XH- Voltage SIB 70S Hoiao:6204
459.7348 T:4  3SUB(256,30,-3.0)  PKD(7,5,3,0.10\,24816.0,1.00\,T,T) XxptXDBSUS
TBIANGLX LASS Text: 157-160/166  TLH44376A
1003,                       A7.3Jf8
  80.
           39,30         39:36         39:42        39:48        39:54         40:00
r±le:U980029 tl-545 Acq:  6-JAN-1998 19:43:44 SC XI+ Voltage SIS  703 Noiao:562S
469.7779 T:4 BSUB(256,30, -3.0)  PXD(7,5,3,0.10\r22SOO.O,1.00\,T,T) Szp:BDS5US
XSIAKSLS LASS  Tost.: 157-160/166  TZIt44376A
10 0\                       A5.20E7
           39:30         39:36         39:42         39:48        39:54         40:00
r±le:a980029 tl-545 Acq: 6-JMT-1998  19:43:44 SC ZT* Voltage SIS 70S Noise:3970
471.7750 T:4 SSOS(256,30, -3.0} PKD(7,5,3,0.10\,15880.0,1.00\,r,T) Xxp:BDBSUS
XXIANGLZ LASS  Text:157-160/166  TLH44376A
100\
           39:30         39:36         39:42         39:48        39:54
ttlaiO980029 tl-545 Acq: 6-J3OT-1998 19:43:44  GC XX+ Voltayv SIX 70S
430.9729 Ti4 XxpilWSSaS
TBIAXGUS LASS  Text: 157-160/166  TLH44376A
                                                                          40:00
1004

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39:27
                             39:38
                                                                      39:58
                                                                                           -1.2E8

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                                                                                            1.1X7

                                                                                           .8.7X6

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                                                                                        40:06  T±mt
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                                      39:42
                                                    39:48
                                                                 39:54
                                                                               40:00
-.2.7X7

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                                                                                               .0.0X0
                                                                                             40 06 Time
                                                                                                       148

-------
                                                                                  CD
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Peak Locate Examination: 6-JAN-1998:19:42  File:U980029
      Experiment:NDB5US Function:2 Reference:PFK

-------
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Sample Text:157-160/166  TLI#44376A  File  Text:TRIANGLE LABORATORIES,  INC.
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  24:54   25:00  25:06  25:12  25:18  25:24  25:30  25:36  25:42  25:48  25:54  26:00  26:06
File:U980029 #1-724 Acq:  6-JAN-1998  19:43:44  GC EI+ Voltage SIR 70S
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Sample Text:157-160/166   TLI#44376A  File  Text:TRIANGLE LABORATORIES/  INC.
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Sample Text:157-160/166  TLI#44376A  File Text:TRIANGLE LABORATORIES, INC.
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-------
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Sample Text:157-160/166   TLI#44376A
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           28:12    28:18     28:24
File:U980029 #1-724 Acq:  6-JAN-1998
341.8567 F:2 Exp:NDB5US
Sample Text:157-160/166   TLI#44376A
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           28:12     28:18     28:24
File:U980029  #1-724  Acq:  6-JAN-1998
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Sample Text:157-160/166  TLI#44376A
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-------




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~_
1 — r— 1 — i — i — i — 1 — i — I — i — i — i — 1 — i — i — i — I — i — 1 — i — r— i — i — i — 1 — i — i — r— i — i — 1 — i — i — i — i — i — 1 — i — I — i — I — i — I — i — i — i — i — i — 1 	 1 — I — I — i — i — [• — 1 — r-1
33:06 33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54
_7.4E6
L5.9E6
_4.5E6
_3.0E6
_1.5E6
• 0 OEO
Time

-------
 TLI Project      44376A
 Client Sample:   157-160/166 '
Method 23 TCDD/TCDF Analysis (DB-225)
                    Analysis File:   P980097
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97 Spike File:
TLI ID: 194-59-12A-E Date Extracted: 12/29/97 ICal:
Date Analyzed: 01/07/98 ConCal:
Sample Size: 1.000
Dry Weight n/a
GC Column: DB-225
Dilution Factor n/a % Moisture
Blank File: P980094 %Lipi±
Analyst JM % Solids:
SPC2NF04
PF22206
P980092
: n/a
n/a
n/a


glay^;43~rr * ; *
2J.7.8-TCDF
ph^^eferT
13C12-2A7,8-TCDF
iBeebterySteiuiartl s , "
£\V..,W. "^ .-A \ f
"C,rlA3,4-TCDD
Amt £19} DL EMPC Ratio
16.1 0.75
Amt (ngj % Recovery GCtfonfts ftalta
2.8 71.0 40%-130% 0.74
(Xv- ^V
0.79
RT
23:08
BT
23:07
BT
21:56
Flags
—
Flags
—
Flags ,

                    Data Reviewer.
                   01/09/98
                                       Page 1 of 1
                               C1NF CSR . Mil. LAKSn Ilium
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                            Printed: 10:1501/09/98

                                       153

-------
                        Initial
                                    , .Date..
  Data Review By:
                     Calculated Noise Area:
                                            1.00
  The Total Area for each peak with an ion abundance ratio outside
  ratio liaits ha* been recalculated according to method requirements.
  Page No.
  01/07/98
Listing of P980097B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Co •pound/
  H_2	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Home..  ID..  Flags.
TCDF
304-306 DC ML 0:00
DC WL 18:17
18:29
18:47
18:57
19:02
19:09
19:30
19:37
19:45
19:56
20:03
20:12
20:21
20:30
20:39
20:48
21:11
21:24
21:28
21:38
21:44
21:53
22:08
22:22
22:33
22:43
23:00
23:08
23:21
23:37
23:44
23:57
24:32
25:17
DC WH 25:44
304-306 33 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 20:10
DC WL 20:23
DC WL 20:33
0.65-0.89
RO 1.75
0.82
RO 0.90
RO 1.05
RO 0.64
RO 1.45
0.78
0.75
0.75
0.76
0.76
0.76
0.76
0.81
0.77
0.75
0.75
0.76
0.65
RO 1.02
0.75
0.75
0.75
0.75
0.75
0.75
RO 0.48
0.75
0.75
0.75
0.75
0.76
0.68
0.75
0.77
0.85

0.65-0.89
RO 1.76
0.68
RO 1.21
0.75


5,




7,
6,
11,
5,

5,
11,
6,
18,
6,
38,


8,
1,
8,
8,
1,
10,

8,
6,
9,
11,
9,

6,
1,

217,
6
77
442
149
123
101
376
176
298
023
591
727
663
786
406
980
462
781
50
76
916
589
728
731
770
442
35
268
183
478
235
612
50
155
230
58
649
.25
.20
.84
.44
.03
.42
.96
.25
.27
.69
.09
.20
.59
.43
.99
.25
.59
.10
.50
.75
.28
.96
.95
.18
.81
.90
.95
.36
.94
.24
.67
.86
.11
.15
.58
.81
.33
0.792-1.101
0.000
0.791
2,755.
88.
53.
83.
164.
3,077.
2,689.
4,744.
2,407.
313.
2,441.
5,264.
2,796.
8,107.
2,772.
16,734.
19.
44.
3,815.
678.
3,754.
3,746.
756.
4,479.
15.
3,549.
2,647.
4,064.
4,832.
4,140.
20.
2,643.
534.


,79
66
52
22
90
92
80
96
14
90
53
23
76
25
45
90
84
15
37
85
20
66
98
98
64
66
64
54
54
58
25
77
76


3,075.
84.
84.
57.
212.
4,098.
3,608.
6,278.
3,183.
413.
3,222.
6,522.
3,610.
10,873.
3,690.
,05
,43
,12
30
06
33
47
73
95
30
06
20
23
00
14
22,046.20
30.
43.
5,100.
911.
4,974.
4,984.
1,013.
5,962.
32.
4,718.
3,536.
5,413.
6,403.
5,472.
29.
3,511.
695.


66
36
91
11
75
52
83
92
75
70
30
70
13
28
86
38
82


0.800
0.813
0.820
0.823
0.828
0.844
0.849
0.854
E
0.862
0.867
0.874
0.880
0.
0.
887
893
E

E
0.900
0.916
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.

926
929
936
940
947
957
968
975
983
995
001 2378 -TCDF
010
022
027
036
061
094
113

E


E

E
E

E

E
AN
E
E
E





0.957-1.043




4
31
3,
64
.99
.96
.54
.14
















0.
0.
0.
0.
000
872
882
889




Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-6729 • Fax: (919) 544-5491
                                                                  Printed: 03:34 01/07/98
                                                                                154

-------
  Page No.     2
  01/07/98

  Compound/
  M_Z	QC. Log Omit Why
  316-318
  13C12-TCDD
  332-334.
Listing of P980097B.dbf
Matched GC Peak* / Ratio / Ret.  Time
.RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Home..  ID..  Flags.
                                                                                  0.911
                                                                                  0.923
                                                                                  0.933
                                                                                  0.944
                                                                                  0.965
                                                                                    000
                                                                                    015
                                                                                    040
                                                                                    045
                                                                                    052
                                                                                    076
DC
DC
DC
DC




DC
DC
DC
DC

WL
WL
WL
WL




WH
WH
WH
WH
4
21:
21:
21:
21:
22:
23:
23:
24:
24:
24:
24:
25:
03
20
34
49
18
07
28
02
09
19
52
13


RO

RO

RO

RO


RO
0
0
0
0
0
0
0
0
2
0
0
0
.65
.78
.39
.73
.42
.74
.21
.83
.45
.86
.79
.40
Peaks
8.
41.
12.
58.
6.
1,473.
8.
33.
4.
11.
44.
16.
1,521.
57
82
50
77
57
98
00
20
85
35
01
30
75
                                    2.86
                                   628.78
                                    3.48
                                   15.01
           6.81
         845.20
          16.55
          18.19
13C12-2378-TCDP ISO
                                                                                  1.091
                                        Above: TCDF / TCDD Follows
 332-334

DC
DC
DC
DC


DC

DC
DC
DC
DC
DC
DC
DC


NL
WL
SN
SN


SN

SN
WH
WH
WH
WH
WH
WH
3

0
19
20:
20:
21:
21:
22:
22:
23:
23:
24:
24:
24:
24:
24:

:00
:07
:31
:38
;38
:56
:19
43
:10
45
03
14
28
40
47
0.
RO
RO
RO
RO


RO

RO
RO
RO

RO
RO
RO
65-0.89
1
0
1
2
0
0
'1
0
1
0
2
0
0
0
3
.68
.98
.81
.07
.79
.79
.07
.76
.39
.48
.38
.31
.50
.27
.59
Peaks
1.
2.
2.
1.
984.
1,496.
1.
11.
0.
10.
0.
4.
5.
1.
1.
2,492.
77
27
00
77
02
30
20
98
67
76
80
70
34
68
20
30
                                                            433.06
                                                            659.49

                                                              5.19
0.908-1.092




550.96
836.81

6.79







0.000
0.884
0.948
0.954
1.000 I!
1.014 i:
1.032
1.050
1.071
1.098
1.112
1.120
1.131
1.140
1.146
                                                              13C12-2378-TCDD  IS1
                                                              13C12-1234-TCDD  RSI
 Column Description	   'Why* Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time  (mm:as)
 Rat.l -Ratio of M/M+2  Ions
 OK    -RO-Ratio Outside  Limits
 Rel.RT-Relative Retention Time
     End of Report •••
      WL-Below Retention Time Window
      WH-Above Retention Time Window
      SN-Below Signal to Noise Level
      
-------
ri-Laif9800S7 #1-922 Acq: 7-JAlf-ltf
303.9016 Sip, 03225
XSIAHSLX LASS  Taxttl57-160/166  TLH44376A
                                      23i37
                                               Voltage SIS 70P
                                                                   24:32
                                                                                           25tl7
                                                                                                    -1.2X7
                                                                                                    '•.1.1X7
                                                                                                    '•.1.1X7
                                                                                                    ':!. 0X7
                                                                                                    '•.9.6X6
                                                                                                    .9.016
                                                                                                    .8.4X6
                                                                                                    '•.7.8X6
                                                                                                    17.2X6
                                                                                                    '•.6.6X6
                                                                                                    '.6.0E6
                                                                                                    '•.5.4X6
                                                                                                    '-.4.8X6
                                                                                                    .4.2X6
                                                                                                    '.3.6X6
                                                                                                    '•.3.0X6
                                                                                                    '•.2.4X6
                                                                                                    :1. 8X6
                                                                                                    .1.2X6
                                                                                                    .6.0X5
     22:36 22:48  23:00 23:12 23:24  23s36 23:48 24:00  24:12 24:24  24:36 24:48  25:00 25:12  25:24
r±lo:P980097 tl-922 Acq:7-J7Ol-9»  02:28:58 XH- Voltage SIS  70P
315.9419 KrptDB22S
TRIANGLE LABS  Text: 157-160/166 TLH44376A
ion
 95.
 90.
 85.
 80.
 75.
 70.
 65.
 60.
 55.
 50:
 45:
 40:
 35.
 30:
 25.
 20.
 15:
 10:
  5j
  OJ
                     23; 07
                                                                                                     1
    22:36  22:48 23:00  23:12 23*24  23:36  23:48 24:00 24:12  24:24 24:36  24:48 25:00  25:12 25:24
.8X6
.7X6
.6E6
.5X6
.5X6
.4X6
.3X6
.2X6
.1X6
.0X6
.1X5
.2X5
.3X5
.3X5
.4X5
.5X5
.6X5
.7X5
.8X5
.1X4
.0X0
  Hue
                                                                                                       156

-------
fiJ.a:PS80097 #1-922 Acq: 7-JAK-98 02:28:38 EI+ Vodugra SIS 70P aoiae:j095
303.9016 BSUB(2S6,30,-3.0) PXD( 5, 3,1, 0.10\,12380.0,0.00\,T,T) Xxp:DB225
TSIAXGLE LASS  Text: 157-160/166 TLH44376A
100*                               Al  ( X8
           19:00        20', 00       21iOO       23:00       33:00       24': 00
riletP980097 tl-922 Acq:7-JAN-98 02:28:58 XH- Voltage SIS 70P Boise: 1763
305.8987  BSUB(256,30,-3.0)  tKD(5,3,1,0.10\,70S2.0,0.00\,T,T)  StptOB225
TRIJOKLX  LASS Texts 157-160/166 TLIH4376A
1003k                                A3.20X8
             25:00
          19:00        20:00       21iOO       22:00       23:00       24:00
r±la:P980097 tl-922 Acqt7-JJOt-98  02:28:58 EH- Voltage SIS  70P Xo±aes2480
315.9419 BSUS(256,30,-3.0)  PXD(S,3rl,0.10\,9920.0,0.00\,r,T)  Szp:DB225
TBIASGZE LABS  Text: 157-160/166 TLH44376A
1QQ1                                                       A6.29Z6
 80.

 60.

 40.

 20.
             25:00
          15:00       20:00        21:00       22:00       23:00       24:00
Tile:P980097 tl-922 Aeqt 7-JAN-98  02:28:58  XI+ Voltage SIS  70P Noiae:1412
317.9389 BSUB(2S6,30,-3.0) PKB<5,3,l,0.10\,5648.0,O.OQ\rT,r) Xxp:DB225
TXIAKGLX LABS  Text: 157-160/166 XLXt44376A
                                                           AS.45X6
                                                                                    25100
                         .1.8H6

                         .1.4E6

                         .1.1X6

                         .7.2X5

                         .3. 6X5

                         O.OEO
                             rime
 80.

 60.

 40.

 20.

  0.
                        -2.4E6

                         .1.9X6

                         .1. 4E6

                         .9.5X5

                         '.4.8X5
          19iOO       20:00        21:00       22:00       23:00
F±J.»,P980097 H-922 Acqi7-J7Uf-98  02:28:58 XI+ Voltage SIS  70P
375.8364 Xip:DB225
TRIANGLE LABS  Text* 157-160/166 TLH44376A
24:00
            25:00
                          0.0X0
                             Time
1001
                                                            23:05
          19:00
                      20:00
                                  21:00
                                               22:00
                                                           23100
                                                                       24:00
                                                                                   25:00
                                                                                                        157

-------
 THOIP9SOOS7 tL-922 Acqi 7-JAK-9S  02i2Bt58 EI+  Voltage SIS 70P Nona 1139 2
 319.8965 BSV3(256,30,-3.0) Pn>(5 ,3,1,0.10\,516B.0,0.00\,T,T) KxpiOB225
 TRIASSLX LASS  Text.: 157-160/166 TLH44376A
 1001
  80.

  SO.

  40.

  20.
A6.69X7
                        Al.00X7
                           A  /v A
                                               A1.92X7
                20100            21100           32:00           23:00
 rLlm:P980097 tl-922 Acq:7-JAN-98 02i28i5B KH- Voltage 5X8 7OP Holme: 7310
 321.8936 BSUB(256,30,-3.0) PKE( 5,3,1, 0.10\,29240.0,0.00\,r,f) SzptOB225
 XSiASSLX LABS  Tttrt: 157-160/166 TU944376A
 100\
                                                                    241 00
  80.

  60.

  40.

  20.
A8.44E7
                        A1.26E7
                           A   xv A
                                               A2.44E7
                20100            21:00           22:00           23:00
f±latP9S0097  tl-922 Acq: 7-J7HT-9B 02t28t58 EH- Voltage SIS 70P Noiaeill54
327.8847 BSUB(256,30,-3.0)  PKD(5,J,l,0.10\,4616.0,0.aO\,T,T)  SxptDB225
TSIANGLZ LABS  Text: 157-160/166 TLH44376A
1001             A2.40E7
  80.
  eo:
  40.
 20.
                                               A2.45Z7
                                                                              A2.26E7
                                          A9.67X6
                        A2.73E6
                                          A
                20:00            21:00           22:00            23:00
riletP980097 tl-922 Acq: 7-JAN-9S 02:28:58 EI+ Voltagre 5X5  70P lToiae:840
331.9368 BSUB(256,30,-3.0)  PXD(5,3,1,0.10\,3360.0,0.00\,T,T) Exp:DB225
TSIANGLX LABS  Text: 157-160/166 TLH44376A
1001                                           A6.59Z6
                                                                    24:00
 80.

 60.

 40.

 20.
                             A4.33X6
                20:00           21:00            22:00            23:00
TiletP980097 tl-922 Acq:7-JJUr-98  02:28:58 EI+ Voltage SIX 70P XoiaetSOO
333.9338 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,2000.0rO.OO\,T,T) Xxp:DB225
T&IAHGLE LABS  Text: 157-160/166 TLI944376A.
1001                                           A8.37X6
                                                                                 24:00
 80.

 601

 40.

 20.

  0.
                            AS. 51X6
  3.1X7

 .2.5X7

 .1.9X7

 .1.2X7

 '.6.2X6
                                                                                        '.0.0X0
                                                                                     25 00  Tiat
                                                                                     25
  4.0X7

 .3.2X7

 .2.4E7

 _1.6X7

 '.8.0E6
                                                                                        .0.0X0
                                                                                        00 T±ae
                                                                                        7.4X6

                                                                                        .6.0X6

                                                                                        '.4.5X6

                                                                                        .3. OE6

                                                                                        .1.5E6
                                                                                       .O.OEO
                                                                                     25  00  T±ae
 1. 8E6

 .1. 4X6

 .1.1X6

.7.2X5

.3.6X5
                                                                                                    .0.0X0
                                                                                                  25 00 Time
                20:00
                                21:00
                                                22:00
                                                                23:00
                                                                                 24:00
-2.3X6

.1.8X6

.1.4X6

'.9.2X5

.4.6X5
                                                                                       .0.0X0
                                                                                    25:00  Tiae
                                                                                                     153

-------
rile:P980097 tl-922 Acg: 7-JAW-98 02:28:58 EI+ Voltage SIS 70P
303.9016 Xxp:DB225
XSIAXSLX LABS Text: 157-160/166 TLIt44376A
1001
80.

60.
40.
20.
o
21:11
ft
20:39 1
T O • A < A I -*^ -w
i,, »»A s^3 aT »i"h
i A.i/UlyL)l MJiM T .
2.6X7
-.2.1X7
;
;l . 6X7
'.1 . 0X7
'•.5.2X6
'• o . oxo
19\00 ' ' ' 20:00 2l':00 22:00 23:00 ' 24:00 ' ' 25:00 Tina
rila:P980097 tl-922 Acq:7-JJOT-98 02:28:58 XI+ Voltage SIS 70P
315.9419 KrpiDB22S
TSIAHGLX LABS Text: 157-160/166 TLIt44376A
1001
80.
60.
40.
20.
Q
23:07




20:33 21:49 1 1
j-.^ «- -A- 1 \. .—, J*
_1 . 8X6
.1.5X6
.1.1X6
.7.3X5
.3.6X5

19:00 ' ' 20:00 ' 21.00 22:00 ' ' 23:00 ' ' ' 24:00 ' ' ' 25:00 ' ' ' Time
W.e:P980097 tl-922 Atxj:7-J3UT-98 02:28:58 XI+ Voltage SIS 70P
319.8965 Sxp:DB225
TSIANGLX LABS Text: 157-160/166 TLIt44376A
1003
80:

60:
40:
201

0.
15, -15

19:53
i


, „
31 A" /» 21i17 A
1 \ 1 \ A/vAy\ ^sJ\^
3.1X7
.2.5X7

.1.9X7
.1.2X7
.6.2X6

0.0X0
' 15.00 ' ' ' joiob ' ' 21:00 ' 22:00 ' ' ' 23:00 ' ' ' 24 1 00 ' ' ' .25.00 ' ' Mae
rilo:P980097 tl-922 Acq:7-jyur-98 02:28:58 EH- Voltage SIS 70P
331.9368 Xxp:DB225
TSIAXSLX LABS Text: 157 -160/166 TLIt44376A
1001
80:
•
60:
40:
20:
«•
21:56

21:38\\
1


/I l\
_1 . 8X6
'•.1.5X6

.1.1X6
.7.3X5
.3.6X5
0.0X0
19:00 ' ' ' 20\00 51:00 22:00 ' ' ijioo ' ' ' 24\00 ' ' ' 25.00 ' ' Time
r±J.eiP980097 tl-922 Acq:7-J3Ol-9a 02:28:58 XI+ Voltage SIS 70P
292.9825 ExptDB225
TSIAXGLX LABS Text.: 157-160/166 TLIt44376A
1001
80:
60:
40:
20:
o-
18:59 19:35 20:47 21:18 21:48 22:26 23:02 23:39 24 138^^25^27^
(V^^-w^-«VwVVV ^ -vy^-^ -^-^^-^r^^^v^r^^^^ ^T^'




.1.1X7
.8.5X6
.6.4X6
.4.3X6
.2.1X6
0.0X0
15.00 20.00 21:00 22:00 ' 23': 00 ' ' 24\00 ' ' 25:00 ' ' Time
TiletP980097 tl-922 Acq:7-JAN-98 02:28:58 XI+ Voltage SIS 70P
330.9792 XxptDB22S
TBIAXGLX LABS Text.: 157 -160/166 TLIt44376A
1001
80:
60:
40:
20:
0'
lyS&^.j+Jfcj^




.9.3X6
-.7.4X6
'.5.6X6
-.3 . 7X6
-.1.9X6
0.0X0
19l: 00 20:00 21:00 22\00 23:00 ' ' ' 24': 00 ' ' ' 25:00 Tiae
159

-------
f)   232.385
B   3016
C   385,8987
D   315,9419
E   317,9389
F   319,8965
6   321,8936
H   327,8847
I   338,3782
J
K
L
n
Ref, lass    292,9825     Peak top
Height  1,95 wits  Span  288 ppi
Systa file naie
Data  fdenaie
ResoLutun
Gro^ruter
lonizatun lode
Svitching
   , lasses  292,9^5)
       1
    EI+
 VOLTAGE
388.9761
338,9792
JU14 JUUUK
331,9368
333,9338
£5,3364
Chamel   I  338,9732     Peak top
Height  1,58 volts  Span   296 ppt
                                                        IGO

-------
 TLI Project:      44376A
 Client Sample:    161-164
Method 23 PCDD/PGDF Analysis (a)
            Analysis File:  U980030
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN DateReceive± 12/17/97
194-59-13A-E Date Extracted: 12/29/97
Date Analyzed: 01/06/98
1.000 Dilution Factor n/a
n/a Blank File: U980026
DB-5 Analyse BB
Spike File:
ICal:
ConCal:
% Moisture:
%lApi±
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a

Analytes
2.3,7.8-TCDD
1,2,3.7.8-PeCDD
1.2,3,4.7,8-HxCDD
1,2,3,6,7,8-HxCDD
1.2,3,7.8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2.3,7,8-PeCDF
2,3,4,7,8-PeCDF
L2J.4,7.8-HxCDF
12.3.6.7,8-HxCDF
2,3,4.6,7,8-HxCDF
1.2,3,7,8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF-

4|,AWt'p8)
0.61
3.4
3.7
5.7
8.3
32.9
47.1
53.8
13.8
23.8
72.8
25.9
38.5
2.5
107
17.1
79.7

;Hr*tnt ##
68.1
55.0
92.0
68.8
288
324
300
180

ftt tSftC^k^^*** ^^^0c^*-
<._ l««.^ cnlrv-' •'f-tt&SKf •
0.75
1^3
1J3
1.21
1.27
0.96
0.85
0.74
. 1.57
1JO
1^7
1.19
1J2
1.15
1.05
1.04
0.88

Number Dt S«PC
11 68.4
9 88.7
7
2
16
15 326
13
4

RT
25:20
29:36
32:44
32:49
33:06
36:02
39:36
24:38
28:34
29:15
32:02
32:08
32:37
33:23
35:01
36:32
39:49











,Fla$s
PR_




	
	
E_


E—
PR!
E_



Flags
E_

E
—
E_
E
E
E
                                       Page 1 of 2
                        Mm _PSR»I.OI. LARS d.io.081
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:1801/10/98
                                 161

-------
 TLI Project:      44376A
 Client Sample:   161-164
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980030


13C,2-2,3,7.8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-U,3,6,7,8-HxCDF
"C,2-l,2,3,6,7,8-HxCDD
13C,2-U,3,4,6,7,8-HpCDF
13C,2-U.3.4,6,7,8-HpCDD
I3C ,2-U,3,4,6.7,8,9-OCDD

Surrogate Standards {Type A}
13C,2-2,3,4,7,8-PeCDF
13C,2-U,3,4,7,8-HxCDF
IJCirlA3.4,7.8-HxCDD
13Ci2-l,2,3.4,7,8.9-HpCDF

Surrogate Standards {Type A)
37Cl4-2,3,7,8-TCDD
Alternate Standards {Type A)
13Ci2-l,2,3,7,8,9-HxCDF
13Ci2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
I3C12-U,3,7,8,9-HxCDD
Amt (fiel
-ifVtit J j. f^ fff. .
1.8
1.8
1.8
1.8
2.0
2.7
2.5
2.6
4.9

Aink £»oj
3.4
4.0
3.4
4.0

" f
3.2
Amt 
-------
                       Initial
                                   .Date.
Data Review By:
                                            Calculated Noise Area:
                                                                    1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according  to method requirements.
Page No.
01/10/98
                         Listing of O980030B.dbf
                         Matched GC Peaks  / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak. 2..  Rel.RT Compound.Name..  ID.. Flags.
TCDF
304-306
K
K
K
K
K
K
K









304-306
13C12-TCDF
316-318









316-318
TCDD
320-322
KK
NK
K
R


H

DC KL 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
25
26
0
:00
:27
:58
:11
:35
:54
:18
:34
:49
:02
:13
:26
:38
:03
:16
:31
:22
16 Peaks

DC NL 0:
DC WL 22 ;
DC WL 22 :
24:
24:
24:
25:
DC WH 26:
DC WH 26:
DC WH 26 :
0
:00 RO
;23 RO
:59
04 RO
ill RO
:37
02 RO
10
45
54 RO
4 Peaks

DC NL 0:
22:
23:
23:
24:
24:
24:
25:
0.
00 RO
47
10
28
09
24
49
14-
.65-0.89
0.80
0.74
0.74
0.75
0.75
0.73
0.73
0.74
0.78
0.71
0.74
0.73
0.74
0.78
0.75
0.79
0.72 .
1,
.65-0.89
1.96
0.91
0.75
1.71
1.11
0.74
1.79
0.75
0.74
0.99
0.867-1.079
2,170.31
30,416.60
30,893.70
35,673.50
169,571.50
104,955.70
113,286.80
85,763.70
125,186.40
156,541.20
52,006.50
49,115.30
245,942.00
51,065.90
53,291.70
8,762.02
5,969.33
318,441.85

12,946
13,143
15,327
72,625
44,338
47,800
36,381
54,757
64,941
22,038
20,751
104,635
22,455
22,788
3,863
2,508


.60
.90
.10
.00
.10
.50
.50
.60
.20
.80
.80
.00
.60
.20
.68
.15


17,470
17,749
20,346
96,946
60,617
65,486
49,382
70,428
91,600
29, 967
28,363
141,307
28,610
30,503
4,898
3,461


.00
.80
.40
.50
.60
.30
.20
.80
.00
.70
.50
.00
.30
.50
.34
.18

0
.000

0.871
0.892
0.901
0.917
0.930
0.947
E
E
E
0.957
0.968
0.976
E
E
0.984
0.993
1.001 2378-TCDF AN
1.
1.
1.
1.

018
026
037
071

E





0.959-1.041
34.39
200.01
344.15
101.33
141.58
14,758.64
59.65
137.47
61.24
42.13
15,061.20
65-0.89
0.07
0.76
0.77
0.79
0.76
0.80
0.79
0.77
16.21
87,999.10
55,623.10
7,335.49
23,306.00
14,392.98
6,595.16
24,800.00



98
88
6,260
60






.08
.88
.48
.36






57;
79.
8,498.
33.






:25
.99
.16
70



0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
909
934
978
982
000 13C12-2378-TCDF ISO
017
063
087
093














38,001.20
24,216.20
3,245.
10,056.
6,408.
2,920.
10,800.
22
00
92
49
00

49,997.
31,406.
4,090.
13,250.
7,984.
3,674.
14,000.
0.895-

90
90
27
00
06
67
00
0.
0.
0.
0.
0.
0.
0.
0.
1.047
000
901
916
928
955
964
981
997


E






Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                         Printed: 10:19 01/10/98
                                                                                                         163

-------
  Page No.
  01/10/98
Listing  of 0980030B.dbf
Matched  GC Peaks / Ratio / Ret. Tine
  Compound/
  M_Z.... QC.Log Omit Why . .RT.  OK Ratio Total. Area. .. Area. PeaJc. 1. .  Area. Peak. 2. . Rel.RT Compound. Name. .  ID..  Flags.
         AN
  320-322

  37C1-TCDD
  328
  328

  13C12-TCDO
  332-334
  332-334
  PeCDF
  340-342
         M
         AN







DC
DC
DC
DC








25:20
25:30
25:39
25:53
26:19
12 Peaks

NL 0:00
WL 22:47
WL 23:05
WL 23 : 10
23:58
24:09
24:38
r 24:49
25:09
25:20
25:44
7 Peaks
0
0
0
0
RO 0














.75
.76
.79
.81
.96














2
3
3
1

230





14




8;
8,
32,
,070.00
,171.29
,527.63
,167.97
995.77
,984.49

84.86
458.03
310.32
423.61
,710.40
354.82
268.18
83.54
32.21
,667.13
,225.28
,341.56

1
1








14




890.00
,369.84
,555.13
522.37
539.76






,710.40
354.82
268.18
83.54
32.21
1,180.00
1,801
1,972
645
562











.45
.50
.60
.58

0.









8,667.13
8,225.28



0.65-0.89
DC






NL 0:00
25:08
25:18
25:39
26:08
26:20
5 Peaks
HO 1.84
0.82
0.79
21,
10,
0.81
RO 1.38
RO 1.06
33,
1.32-1.78
DC


















NL 0:00
26:34
27:02
27:13
27:20
27:34
27:42
27:52
28:11
28:18
28:29
28:34
28:43
28:51
29:15
29:24
29:44
29:53
30:14
RO 1.
1.
RO 1.
1.
RO 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
RO 3.
1.
08
54
21
37
25
50
53
52
53
52
59
57
52
56
50
55
49
33
51

92,
1,
1,
1,
29,
218,
49,
79,
109,
43,
41,
35,
61,
69,
104,
17,

9,
20.00
,792.63
,900.64
396.22
18.76
39 . 40
147.65
TCDD /
21.12
578.80
360.02
730.49
313.64
676.90
160.40
830.50
564.40
126.50
500.00
700.00
110.30
103.00
662.20
642.80
180.14
568.80
021.70


9,849.83
4,796.51



176.92
14.62
23.64

11,942.
6,104.
219.
10.
22.

1.001 2378-TCDD
1.008
1.014
1.023
1.040

921-1.079
0.000
0.901
0.912
0.916
0.947
0.955
0.974
0.981
0.994
1.001 37C1-TCDD
1.017

AN















CLS


0.921-1.079

,80
13
30
60
26
0.000
0.993 13C12-1234-TCDD
1.000 13C12-2378-TCDD
1.014
1.033
1.041

RSI
IS1






56,



17,
131,
30,
48,
65,
26,
25,
21,
37,
41,
63,
10,

5,

158.90
826.68
999.40
798.49
790.70
891.00
089.50
087.80
836.30
700.00
500.00
162.50
209.40
750.20
574.00
285.80
742.75
433.11

36,419.
0.925-1.065

90
682.62
731.
637.
11,886.
86,269.
19,741.
31,476.
43,290.
16,800.
16,200.
13,947.
23,893.
27,912.
41,068.
6,894.
223.
3,588.
09
20
20
40
00
60
20
00
00
80
60
00
80
34
06
59
0.000
0.930
0.946
0.953
0.957
0.965
0.970
0.975
0.987
0.991
0.997
1.000 12378-PeCDF
1.005
1.010
1.024 23478-PeCDF
1.029
1.041
1.046
1.058











AN


AN




Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:19 01710/98
                                                                                 164

-------
  Page No.
  01/10/98
Listing of a980030B.dbf
Matched GC Peaks /  Ratio / Ret. Ti
  Compound/
  M_Z.... QC.Log Omit Why . . RT. OK Ratio  Total. Area... Area. PeaJc. 1. .  Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
  340-342
                     18 Peaks
                                        965,830.59
13C12-PeCDF
352-354









N





352-354
PeCDD
356-358












356-358
13C12- PeCDD
368-370










368-370

DC NL 0
26
26
27
27
28
28
28
28
29
29
29
29
29
30
30

:00
:25
:35
:43
:55
:11
:18
:34
:51
:03
:14
:29
:40
:51
:15
:27
1
RO


RO

RO
RO


RO

RO

RO

RO
15 Peaks

DC NL 0:
27;
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:

:00
49
:18
:31
40
50
01
06
18
26
36
44
04
1.
RO
RO
RO






RO



.32-1.78
0.96
1.38
1.71
1.05
1.52
2.32
1.99
1.51
1.57
1.94
1.57
1.17
1.47
0.94
1.39
0.50
0.860-1.140
23
43
67
168
334
23
109
11,471
404
96
9,483
318
128
64
122
13
.95
.71
.62
.53
.92
.72
.32
.75
.58
.87
.27
.17
.93
.47
.66
.61
22,852.13
32-1.78
1.11
1.20
1.21
1.58
1.52
1.54
1.54
1.55
1.47
1.09
1.53
1.60
1.59
12 Peaks

DC NL 0:
27:
27:
28:
28:
29:
29:
29:
29:
29:
30:

00
42
48
18
30
07
35
42
49
59
05
1.
RO
RO
RO
RO




RO
RO
RO
32-1.78
1.17
2.33
3.83
0.76
1.48
1.69
1.51
1.37
5.03
2.17
1.13
10 Peaks
9.
55,113.
3,666.
35,938.
7,219.
23,679.
3,486.
8,227.
9,656.
4,951.
6,431.
4,696.
4,547.
167,616.
,59
.56
.98
.40
99
52
53
41
81
49
72
85
50
76

25
42
102
202
21
85
6,902
247
73
5,787
193
76
39
71
8

.38
.71
.44
.24
.59
.10
.78
.12
.71
.10
.40
.73
.19
.37
.27

18
24
97
132
9
42
4,568
157
37
3,696
164
52
41
51
16

.33
.91
.84
.68
.30
.87
.97
.46
.99
.17
.98
.20
.56
.29
.67
0.000
0.925
0.931
0.970
0.977
0.987
0.991
1.000 13C12-PeCDF 123 IS2
1.010
1.017
1.023 13C12-PCCDF 234 SOR1
1.032
1.039
1.045
1.059
1.066



33,500.

.40
2,228.95
21,996.
4,354.
14,351.
2,111.
5,006.
5,754.
3,009.
3,893.
2,892.
2,794.

50
.29
.90
75
SO
76
73
72
28
02


28,010.
1,849.
13,941.
2,865.
9,327.
1,374.
3,220.
3,902.
2,769.
2,538.
1,804.
1,753.

0.935-1.022

80
48
90
70
62
78
81
05
48
00
57
48

0.000
0.940
0.957
0.964
0.969
0.975
0.981
0.984
0.990
0.995
1.001 12378 -PeCDD AN
1.005
1.016

0.865-1.135
8.
17.
25.
14.
59.
20.
5,672.
774.
37.
50.
20.
6,693.
82
31
73
20
44
46
58
58
69
97
22
18

15.
38.
8.
35.
12.
3,413.
447.
74.
43.
12.


85
61
63
48
84
92
69
36
31
29


6.
10.
11.
23.
7.
2,258.
326.
14.
19.
10.


79
09
42
96
62
66
89
78
99
83

0.000
0.936
0.940
0.957
0.963
0.984
1.000 13C12-PeCDD 123 IS3
1.004
1.008
1.014
1.017

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 10:1901/10/98
                                                                                165

-------
  Page No.
  01/10/98
Listing  of 09800308.dbf
Matched  GC Peaks / Ratio / Ret. Tiae
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak. 1.. Area.Peak. 2. .  Rel.RT Compound.Name..  ID..  Flags:
HxCDF
374-376
.










AN
M
374-376
13C12-HXCDF
384-386










384-386
HxCDD
390-392







390-392
13C12-HXCDD
402-404



402-404
1.05-1.43
DC NL 0:00
31:04
31:13
31:22
31:31
31:40
31:51
32:02
32:08
32:15
32:25
32:37
33:23
33:27
13 Peaks
1
1
1
1
1
1
1
1
1
1
1
1
1
1

.33
.24
.25
.17
.22
.36
.21
.27
.19
.35
.25
.32
.15
.15

1,154.72
77,351.50
174,348.40
18,587.28
23,228.90
14,751.59
1,639.55
169,496.20
74,959.40
20,727.18
31,775.90
87,560.70
5,060.00
19,260.00
718,746.60

42
97
10
12
8

94
40
11
17
49
2
10


,744.90
,007.30
,034.50
,785.50
,499.68
898.73
,940.20
,675.20
,894.80
,655.10
,873.10
,710.00
,300.00


34
77
8
10
6

74
34
8
14
37
2
8

0.43-0.59
DC NL 0:00
31-: 13
31:30
31:35
31:49
32:02
32:08
32:25
32:36
32:54
33:22
10 Peaks

DC NL 0:00
31:34
32:00
32:12
32:22
32:44
32:49
33:06
7 Peaks

DC NL 0:00
32:43
32:48
33:07
3 Peaks
RO 0.90
RO 0.76
RO 1.91
RO 1,
RO 1.
0.
0.
RO 0.
0.
RO 1.
0.

1.05-
1.
1.
1.
1.
1.
1.
1.
1.

1.05-
1.
1.
1.
1.

,08
,32
,50
51
61
52
71
51
» L-__
1.43
41
18
22
19
14
33
21
27

1.43
23
23
21
20

47.58
196.87
32.95
13.82
49.33
7,621.28
9,244.28
268.76
9,013.19
101.26
6,726.35
33,268.09
re : HxCDF /
384.09
16,079.72
89,918.40
36,291.10
6,329.26
6,253.39
12,376.73
17,442.07
184,690.67





2
3,

3,

2,

99.07
41.58
9.84
43.08
,552.25
,120.20
108.96
,084.23
114.40
,262.79





5
6

5,

4,
0.962

,606.60
,341.10
,552.78
,443.40
,251.91
740.82
,556.00
,284.20
,832.38
,120.80
,687.60
,350.00
,960.00

0
0
0
0
0
0
0
0
1
1
1
1
1
1

-1.047
.000
.967
.971
.976
.981
.985
.991
.997 123478-HxCDF
.000 123678-HxCDF
.004
.009
.015 234678-HxCDF
.039 123789-HxCDF
.041









AN
AN


AN
AN


0.876-1.124

130.38
21.82
9.15
32.67
,069.03
, 124 . 08
177.99
,928.96
67.06
,463.56
0
0
0
0
.000
.971
.980
.983




0.990
0.997 13C12- HxCDF 478
1.000 13C12-HXCDF 678
1.
1.
1.
1.
,009
,015 13C12-HXCDF 234
024
038 13C12-HXCDF 789
STO2
IS4

ALT2

ALT1



8,
49,
19,
3,
3,
6,
9,


695.27
458.40
721.40
366.61
572.42
776.18
754.45


7,
40,
16,
2,
2,
5,
7,

0.958-1.014

384.45
460.00
569.70
962.65
680.97
600.55
687.62

0.
0.
0.
0.
0.
0.
1.
1.

0.970-
50.24
5,538.31
8,940.53
13,562.19
28,041.03

3,
4,
7,


049.96
897.56
411.28


2,
4,
6,


488.35
042.97
150.91

0.
0.
1.
1.

000
962
976
982
987
998 123478-HxCDD
001 123 678 -HxCDD
009 123789-HxCDD

1.030
000
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789






AN
AN
AN



SUR3
IS5
RS2

                                                                                                     PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:19 01/10/98
                                                                              166

-------
  Page No.
  01/10/98
          Listing  of  U980030B.dbf
          Matched  GC  Peaks /  Ratio / Ret. Tiae
  Compound/
  M_2....  QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
HpCDF
408-410




408-410
13C12- HpCDF
418-420


418-420
HpCDD
424-426
D



DC NL 0
35
35
35
36
0
:00 RO
:01
:17
:26
:32
.88-1.20
2.81
1.05
0.97
1.07
1.04
4 Peaks

DC NL 0
35:
36;
0
:00 RO
:00
32
2 Peaks

DC NL 0:
DC WL 35:
35:
36:
0.
00 RO
09 RO
18
02
.37-0.51
1.53
0.44
0.43
ve : nxi-ui
58
257,682
50,073
70,998
32,059
410,813

28
6,848,
5,504,
u /
.87
.00
.60
.30
.50
.40

,70
,81
.47
12,353.28
88-1.20
1.21
0.45
1.02
0.96
47.
882.
56,558.
51,793.
29
08
10
10
npi.ur toj.j.i

131,853
24,647
36,622
16,331



2,096
1,649,


.00
.90
.50
.40



.17
.00
0.

125,829.00
25,425.70
34,375.80
15,728.10

0.

4,752.64
3,855.47
996-1.049
0
1
1
1
1

943
0
1
1
.000
.000 1234678-HpCDF
.008
.012
.044 1234789-HpCDF

-1.114
.000
.000 13C12-HpCDF 678
.044 13C12-HpCDF 789

AN


AN



IS6
SUR4

HpCDD Follows - • --


28,577.
25,417.


10
50
0.975-1.005


27,981.00
26,375.60
0
0
0
1
.000
.975
.980
.000 1234678-HpCDD



AN
  424-426
                       2 Peaks
                                           108,351.20
  13C12-HpCDD
  436-438

  436-438
  OCDF
  442-444

  442-444

  OCDD
  458-460

  458-460

  13C12-OCDD
  470-472

  470-472
                                0.88-1.20
DC


NL 0:00
36:02
1 Peak
1,17
1.02

43.82
6,328.37
6,328.37
                                         3,202.07
                                              0.972-1.028
                                                 0.000
                                        3,126.30  1.000 13C12-HpCDD 678  IS7
                                             HpCDD / Octa-CDD and  CDF Follows
               0.76-1.02
DC  NL   0:00 RO  2.53
        39:49     0.88
      1 Peak
DC  NL
         0:00
        39:36
      1 Peak
0.76-1.02
   0.98
   0.85
               0.76-1.02
DC  NL   0:00  RO   1.34
        39:35      0.86
      1 Peak
                37.03
           125,087.40
           125,087.40
    13.81
59,562:90
59,562.90
                16.93
             9,121.26
             9,121.26
                                  0.899-1.101
                                     0.000
              58,422.20     66,665.20  1.006 OCDF
                    0.899-1.101
                        0.000
27,361.30     32,201.60  1.000 OCDD
                                 0.996-1.004
                                     0.000
              4,222.49      4,898.77  1.000 13C12-OCDD
                                                           AN
                                                                      AN
                                                           IS8
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                             Printed: 10:19 01/10/98
                                                                                             167

-------
  Page No.
  01/10/98
Listing of O980030B.dbf
Hatched GC Peaks / Ratio  /  Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK Ratio  Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT  Compound.Name..  ID..  Flags.
  Column Description	   "Why"  Code Description	   QC Log Desc.
  M_Z   -Nominal Ion Mass(es)
  ..RT.  -Retention Tine (mm:as)
  Rat.l  -Ratio of M/M+2 Ions
  OK    -RO-Ratio Outside Limits
  Rel.RT-Relative Retention Time
 •••• End of Report •••
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
r±le-.a980030 tl-723 Acq: 6-JAK-199S 20:29:20 SC EH- Voltage
SIS 70S Noiae: 481530
303.9016 T:2 BSUB(256r30, -3 .0) PKD(9,5,3r0.10\,1926120.0,1.00\,r,T) Exp:SDS5OS
TSIAUSZE LABS Text:161-164 TLI»44376A
100.
80.
SO.
40.

20.
Al

A6.49E8
A
A7.26B8 A3. 64X8 \
A A4.7axan. \
Ai.s3xa /HA r\ \ /M I A A
/\ /\/\ /Vv/v/V/lVyvAJ
22:00 	 23\00 24:00
r±le:O9a0030 tl-723 Acq: 6-J7UT-1998 20:29:20 GC JET* VoZtag»

.05E9 -2.3X8
n r
n


1 A2.25X8
'I A/\ .
.1 . 8X8
'.1.4E8
.9.2X7

.4.6X7
35 100 26\00 Time
SIX 70S Noiaes 603623
305.8987 r:2 BSUS(256,30,-3 .0) PXD(9,5, 3, 0.10\,2414492.0, 1.00\,r,T) Xxp:JO>B5US
TSIAHGLX LASS Text: 161-164 TLIt44376A
lOOi
80.
60.
40.
20.
Al

A9.16E8
A
A9.69IB A4.94X8 l\
A A6.55E8I\ /
A2.03X8 /HA /A A /H* I A A
/\ /\/\ /vv/v/v/i \J\A]
22:00 ' 23:00 24:00
rlle:CT980030 tl-723 Acq: 6-J3UT-1998 20:29:20 GC XI+ Voltage

41X9 3.1X8
fl ^
|


' 1 A2.86XS
'I AA .
.2.5X8
.1.9X8
.1.2X8
.6.2X7
25:00 26:00 T±me
SIS 70S Noiao: 19022
315.9419 T:2 BSU3( 256,30, -3 .0) PXD(9,5,3,0.10\,76088.0,1.00\,r,T) XxptSDBSUS
TSIAXSLX LASS Text:161-164 TLIt44376A
1001
ao:
60:
40:
20:

A6.




^^ _J
'22:00 	 23:00' 24:00
rile:O980030 tl-723 Acq: . 6-J3OT-1998 20:29:20 GC XH- Voltage

6E7




V
1.4X7
.1.1X7
.8.5X6
.5.7X6
.2.8X6

25:00 	 26\00 ' Time
SIS 70S X0±ae:9716
317.9389 T:2 BSUB(256, 30, -3. 0) PXD(9,S, 3,0.10\, 38864.0, 1.00\,T,T) XxpsSDBSUS
TRIANGLE LABS Text:161-164 TLIt44376A
1003
ao:
60:
40:
20:
o:
AB.




	 _j
'22:00 	 23:00 24:00
rila:O980030 tl-723 Acq: 6-JXS-1998 20:29:20 GC XH- Voltage
330.9792 T:2 Elp:SDB5US
TSIASGLX LASS Text: 161-164 TLIt44376A
1003
ao:
60:
40:
20:
oj
21:49 22:46 23:26 24

'0X7 1.9X7




\^
.1.5X7
'•.1.2X7
'•.7.7X6
.3.9X6
0.0X0
25:00 ' '26:00 ' Time
SIS 70S


l37 25:14 25:51 26:13 -7.9X7
^Aipvy^f if^ — *^ ~^v^' — y yy"v^^v^Yv^j^l^l^v'"^sw\ — "*'"
22:00 ' ' 23:00 24:00
r±le:U980030 tl-723 Acq: 6-JA1T-1998 20:29:20 GC XI+ Voltage
375.8364 Ft 2 ExptXDBSUS
TSIAHGLX LASS Text: 161-164 TLH44376A
ion
ao:
60:
40:
20:



.6.3X7
.4.7X7
.3.2X7
.1 . 6X7
o.oto
25:00 26:00 Time
SIS 70S


25:58 -4.5X5
A

24:44 f \
23:20
22:00 23:00 24:00
A V —
/ wV^^^lL^ly V^V^^VU^-AV
.3.6X5
.3.7X5
.1.8X5
.8.9X4
O.OTO
'a5«00 	 26]tOO 	 Time
163

-------
r±J.*sO980030 tl-723 Acq, 6- JAN- 19 9 8 20(29(20 SC XI+ Voltage SIS 70S Noim»,3526
319.8965 f:2 BSUS(256,30,-3.0) PXS(7,5,3,0.10\r14104.0,1.00\,r,T) ExpsNDBSOS
TRIANGLE LABS Text (151 -154 TLIt44376A
1002
80.

60.
40.

20.
0







1

\ r

A2.42E3


Al . 01X8
A AJ..19X8
>>^ y \^^\^ yv ^s \ 	 ^^ ^^
.5.2r7

.4 . 6X7
.3.1X7

.1.5X7
• o . oxo
' 23(00 ' ' 24,00 25(00 ' ' ' 26(00 ' ' ' Mae
rlle>O980030 tl-723 Acq: 6 -JAN- 19 9 8 20t29s20 SC XI + Voltage SIS 70S Sbi*e: 50415
321.8936 Ti2 BSUB(256,30,-3.0) PXD( 7,5,3, 0 .10\, 201660. 0,1. 00\,T,T) ExpiBDSSOS
TRIANGLE LABS Toit: 161-164 TLH44376A
1001
80.
60.
40.

20.
0
1




1



A3.14E8

A1.33SS
A A1.52JT8
A4.09E7 /\ A7.98X7 A3. 67X7 .j\
^ s*^ y v^-XN^ yv s \ — ^^ ^ n
-1.0X8
.8.2X7
.6.1X7
.4.1X7

.2.0X7
0.0X0
23(00 ' 24(00 25(00 	 25>00 ' Mae
Tilei0980030 tl-723 Acq: 6-JAN-1998 20(25(20 SC XI+ Voltage SIS 70S Soiae>10393
331.9368 Ti2 BSUB(256,30, -3.0) PKD(7,5,3,0.10\,41572.0f1.00\,r,T) ExpsKDBSUS
TRIANGLE LABS Text: 161-164 TLH44376A
1003.
80J
50.

40:
20:
0








A9.j»5*7 -2.4X7
ft

I.,4.80E7
A
A
} v V
'•.1.9X7
Ll . 4r7

.9.5X6
-.4.8E6
0.0X0
23(00 	 24(00 	 25(00 ' 25(00 	 Mae
Tila^yv^^v^-^nipwv^>^yYJ-v^^



.7.9X7
.6.3X7
.4.7X7
.3.1X7
J..6X7
0.0X0
23(00 24(00 25^00 ' 25(00 Mae
*'  ^ n
i *  0

-------
.Tile: (75 8 00 JO tl-723 Acq: 6-JAN-199B 20:29:20 GC EH- Voltage SIS 70S SOia»:6420
339.8597 Ti2 3SQB(2S6e30,-3.0) PB>(7,5,3r0.10\t25680.0r1.00\,T,T)
XxptHDBSUS
TSIAOGLX LABS Text: 161-164 TLIt44376A
10 Voltage SIS 70S Xoia»:5946
341.8567 T:2 BSVB<256,30,-3.0) PO)(7,S, 3,0.10\,23784 .0,1.00\,T,T) XxptBDBSOS
TSIAHGLX LABS Text .-151-1 54 TLIt44376A
1003
80.
60:
40J
"
20:

o:
A8.


A'


A/
J V
27i 00 '
3X8

A4.33X8
A
1 97E8 A / W-ff
-------
      27:48 28:00 38:13  38:34  28t36 28:48 29:00 29:13 29:24
r±lt:O980030 tl-723 Acq: 6-JAN-1998 20:39:20 GC XH- Volttgm SIX 70S So±aa:2619
357.8516 T»2 BSU3(2S6,30,-3.0) PXD(5,5,3,O.OS\,10476.0,1.00\,f,T) ExptKDBSUS
TRIANGLE LABS  Imxt: 161-164  TLI944376*
100\A2.80X8
|*ila»PgflOOJO  il-733 Acq:  S-JAK-1S9B 20i29:20 SC £1+ Voltage SIS 70S Noia»>2913
355.8546 Ti2  3303(356,30,-3.0) PKD(5,5,3,0.05\,11652.0,1.00\,r,T) ZxpiXDBSUS
TRIANGLE LABS T*rt: 161-164   TLXM4376&
 1001

  80.

  60.

  40.

  30.
      A3.35X8
                           A3.20X8
                                     A1.44E8
                                                   AS. 75X7
                                             A3.01X7  A     A3.89X7
                                                '   7VyY/W
                                                                          A3.79X7
                                                                            /\
                                                                                      30:34
  so:

  60.

  40.

  20.
                           A1.39X8
                                     AS. 33X7
                                                   A3.90X7
                                             A3.23X7
                                                    J fJVAf
                                                    AA
A2.54X7
.  /w
                                                                          Al. 75X7
                                                                            /v
      27i48 38tOO 38:12 28:24  28:36  38i48  29:00 39:13 39:24 29:36 29:48 30:00  30:12 30:24
\rilaiO980030 tl-723 Acq: 6-JXB-1998 20:29:20 SC XI+ Voltage  SIS  70S Soiae:2679
367.8949 t:2 BSUB(256,30,-3.0) PXD(S,5,3,0.05\,10716.0,1.00\,r,T) S3Cp:lO)B5US
TRIANGLE LABS  Tart:161-164  XLI944376A
1001                                                        A3.41S7

  80.

  60.

  40.

  20.
                                                                  48X6
      37:48 28:00 28:12 28:24 28:36  28:48  39:00  39:13  39:24  29:36 29:48 30:00 30:12  30:24
r±la:0980030 tl-723 Acq: 6-JZX-1998 20:29,20 GC XI+  VoltJtgo SIS 70S Xolae:2294
369.8919 r:2 BSU3(256,30,-3.0) fXD(5,S,3r0.05\,9176.0,1.00\,r,T) Xxp:X3BSUS
TBIANGLS LABS  Tort: 161-164  TLXt44376A
1004                                                       A2.26X7

 80.

 60.

 40.
                                                                 .37X6
      27i48  28:00 28:12 28:24 28:36 28*48 29:00  2S:12  29:24  29:36  29:48 30:00 30:12 30:34
rJHe:U980030 91-733 Acq:  6-JMJ-1998 20:29:20 GC EI+ Voltage SIX 70S
330.9792 r:2 Elp:HHBSU3
TRIANGLE LABS  Text: 161-164  TLH44376A
100\
 801

 60.

 40.

 30.

  0.
    27:46
                                                     29:21
                                                                     39:53
                                                                                     30:22
                                    8.2X7

                                   1.6.6X7

                                   .4.9X7

                                   .3.3X7

                                   .1.6X7
                                                                                               0.0X0
                                                                                                  Tim,
                                    6.6X7

                                   .5.3X7

                                   .4.0X7
                                   r
                                   \.2.6X7
                                   h
                                   ^1.3X7
                                                                                               0.0X0
                                                                                                  Tia
                                                                                              -9.8X6

                                                                                              .7.8X6

                                                                                              .5.9X6

                                                                                              .3.9X6

                                                                                              .2.0X6
                                                                                               O.OEO
                                                                                                  Tlae
                                                                                               6.6E6

                                                                                              \.5.3X6

                                                                                               4.0X6

                                                                                               .2.7X6

                                                                                               1.3X6
                                                                                               .0.0X0
                                                                                                  Timel
                                                                              ' JO»Ji' 30:24
                                                                                              .7.9X7

                                                                                              .6.3X7

                                                                                              .4.7X7

                                                                                              .3.1X7

                                                                                              .1. 6X7

                                                                                              .0.0X0
                                                                                                  Tlae
                                                                                                      172

-------
rila:U980030 tl-385 Acq: 6 -JAN- 19 9 8 20:29:20 GC ET+ Voltage SIS 70S Noiae: 329400
373.8208 F:3 BSOB(256, 30, -3.0) ?XD(7,5,3,0.10\,1317600.0,1.0Q\,r,T) Kxp:HD35US
TXIAHSLX LABS
1001 A9

80.
60.

40.
20.



A4.27X8
A/
Text: 161-164 TLIt44376A
'OE8 ,„ ...

2.9X8
, A9.49EU
A


L"*- 1
'

A4.99X8
V \ AJ-'7» /\ A1.26X8
T V^- /\~J ^- ^~/^
•
'•.3.3E8
ll . 8X8

-.1.2X8
-.5.9X7
Jiibb Jiiij 3l':34 31:36 31:48 32*00 33', 12 32: 24 32:36 32:48 33:00 33,12 33:34 33:36 33:48 Time
nj.»,O980030 tl-385 Acq: 6 -JAN- 19 9 8 20:29:20 GC XX+ Voltage 5JX 705 Noise, 247961
375.8178 T:3 1
i. rme7.5.3
0 2. 0 % 991 844 0 J. 00 % f T ) g»*n tJlDSSUS
TSIAUGZX LABS Text;151*l£4 TLIt44376A
1001 A7.7

80.
ffOj

40^
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f
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A3.46ZS
A)

2 3X8
Ca A7.46X8
A

1 1
Al . 04X8 I
'
'
A3.77»a
\J \ A1.41X8 \ A1.07X8
r \^LJ^J \ 	 ^/^

.1.9X8
'•-1.4S8

.9.4X7
.4.7X7
Jiioo' 31:12' 31:24' 31:36' 31:48 32:00 32:12 32,24 32': 36 32:48 ' 33:b6 ' 33\J.2 ' 33:24 JJiJff 33': 4 8 Time
rile >U9 80030 tl-385 Aoj: 6 -JAN- 19 9 8 20:29:20 GC XT* Voltage SIS 70S Noise: 14130
383.8639 T:3 BSU3(256e 30, -3.0) tXD(7,5,3
XSIANGZX LABS
1001
80:
SO:
40:
20:
oj






T*xt:161-164 TLH44376A
AJ
1




Jitbb 31:12 '31:24 3l':36 31:48 32:00
,0.10\,56S20.0,1.00\rr,T) ExpiNDBSUS

•I2*7 A3. 08X7




' Wr-,^

A2.26E7
A
A
I \

9.1X6
'.7.3X6
.5.4X6
.3.6X6
ll . 8E6
0.0X0
331, 12 3 21: 24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 Time
riletU980030 tl-385 Actj: 6-JAK-1998 20:29:20 GC XI+ Voltage SIS 70S Noiaei 15755
385.8610 Fi3 BSVB(256,30,-3.0) tXD(7,5,3
TXIANGLX LABS
1001)
.
aoj

soj
40:
201
oj






^^~
Tart «1 51 -1 64 TLIt44376A
A6






1
JltOO 31:12 31:24 31:36 31:48 32:00
,0.10\,63030.0f1.00\re,T) Sips HUBS US

'.1317 AS. 93X7 ^1.7X7






^^ 1
,

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A
A
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-.6.9E6
-.3.5X6
' 0 . 0X0
32:12 32:24 32:36 32\4a 33': 00 33\12 33\24 33': 3 6 33': 4 8 T±me
riletU980030 tl-385 Acq: 6 -JAN- 19 9 8 20:29:20 GC ZZ> Voltage SIS 70S
392.9760 T:3 ElptNOBSUS
TSIASSLX LABS
1001
80:
60:
40:
20:
oj
.» .^AN^^,




Text., 161-164 TLIt44376A

r — • 	 ^nc ~^ r ^ Ir"




Jiibb 31:12' 31:24 3i':36 31:48 33:00

Sl^^v^^JlJ^l^p^-v^^




.3.6X7
.2.9X7
.2.2X7
JL.5X7
.7.3X6
0.0X0
3 2': 12 32:24 32:36 33:48 33:00 33:12' 33:24' 33: 36 33': 48' ' Time
rile, 0980030 tl-385 Acq: 6-JAN-1998 20:29:20 GC XH- Voltage -4TS 705
445.7555 r:3 XxptHDBSVS y fO^/ft
TSIAXSLX LABS Toxt:161-164 XLIt44376A *— \ V l
1001
aoj
60:

401
30:
o-













32:0
3l',bb 31:12 3l': 24 31:36 31:48 32:00
32





2
35 ^..1X6
£.\W

33:22
/i

v^-^__ __ ) \_ .. _ _ . _ yv_
.8.6X5
.6.4X5

.4.3X5
.2.1X5
O.OEO
32:12 32:24 32: 36 ' 32i48' 33:00 33:12 JJi 24 '33: 36 33\48 Time
-,         »
i    <

-------
         31,36    31:48   32:00    32:12   32:24   32:36   32:48   33:00    33:12
f±le:U980030 tl-385 Acq:  6-JJOT-1998  20,29:20 GC XH- Voltage SIS 703 Noiae: 13852
401.8558 F,3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\rS54Q8.0,1.00\,T,T) Xxp:KDB5US
TRIASGLX LABS  Text,161-164   XLH44376A
1004                                                                   A7.41E7
rU.a:uSuOOJO  tl-JSi Acq:  0-JAH-J.99O ivsjysju sc KH- Voltage SIS 70S Noiae: 111137
389.8156 Ti3  BSUB(256,30, -3.0) PXD(7,5,3,0.10\r448788.0,1.00\,r,T) KxptNDBSUS
XSIASSLX LABS  Text: 161-164  TLI944376A
1001                     A4.?5X8
  80.
  60.
  40.

  20.
      A8.70X7
       A
                                                           A6.78X7
                                                                       AS. 75X7
         31,36    31:48   32:00    32:12   32:24   32,36   32', 4 8   33,00    33,12
fU.e:U980030 41-305 Acq:  6-JXB-199B 20,29,20 SC XX+ Voltage SIS 70S Soiaet 79851
391.8127 Ti3 3303(256,30,-3.0)  PXO(7,5,3,0.10\,319404.0,1.00\,T,T) XxpiBDBSUS
XBIARGLX LASS  Text: 161-164   TLH44376A
1001                     A4.05X8
  80.
  60.
                                                                                   33124
  40.

  20.
       A7.38E7
        A
                                                          S. 60X7
                                                                     A7.69E7
                                                                                    33:24
 80.

 60.

 40.

 20.
                                                        A4.90X7
         31:36    31:48   32:00   32:12    32:24    32:36   32:48   33:00    33:12
riletU980030 H-385 Acq: 6-JJOT-1998 20:29:20 GC XX+ Voltage SIS 70S Nolae:11268
403.8529 T:3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,45072.0,1.00\,r,T) EzpiNDBSUS
TSIASGLX LASS  Text, 161-164  XLH44376A
1001                                                                  A6.15E7
                                                                                    33:24
80.

60.

40.

20.

 0.
                                                         A4 . 04X7
                                                                                           33
                                                                                                1.6X8

                                                                                                .1.3X8

                                                                                                .9.6X7

                                                                                               .6.4X7

                                                                                               .3.2X7
                                                                                              .0.0X0
                                                                                              36  T±me
                                                                                              -1.3X8

                                                                                              .1.1X8

                                                                                              '.7.9X7

                                                                                              .5.3X7

                                                                                              .2.6X7
                                                                                               .0.0X0
                                                                                             33 36  T±ae
                                                                                            33 36
         31:36    31:48   32:00   32:12    32:24    32:36    32:48   33:00
rlle:D980030 fl-385 Acq: 6-JAW-1998 20:29:20 GC XH- Voltage SIS 70S
392.9760 T:3 Xxp:JO3B5US
TSIAJKLX LABS  Text,161-164  TLI944376A
100a\        31:39  3it*9     32:03           32:25
    	^V—nrOm/—*	-y/^V^V
 00:

 60.
 40.

 20.

  0.
                                                                           33:12    33:24   33 36
                                                                              33:15  33:25
                                                                                             -3.6X7

                                                                                             '.2.9X7

                                                                                             .2.2X7

                                                                                             .1.5X7

                                                                                             .7.3X6
                                                                                               .0.0X0
         31:36  ' '31\48   32:00   32112   '32:24  ' 32^36    32\48  '  33:00   JjilS  ' '33\24 '  33 36  Time
                                                                                                       174

-------
 Tila:a980030  11-545 Acq: 6-JAS-1998 30:29:20 SC EI+  Vbltagv SIS  70S Noise:40567
 407.7818 T:4  BSOB(256,30, -3. 0) PXD(7,5,3, 0.10\,162268.0,1.00\,e,T) Ixp:SDB5VS
 TXIAHGLX LASS  Tax^: 161-164  XX,It44376A
 1001    A1.32X9

  SO:

  50:
  20:
   oj
                          A3.66ES
                                                                           Al.63X8
         35100    35,12    35,24    35,36    35,48   36,00    36,12    36,24   36,36
 rila:O980030 H-545 Acq: 6-JJOT-1998 20:29:20 SC fZ> Voltmgu SIX 70S Hois ft 144 32
 409.7789 T:4 BSOB(256,30,-3.0) PKJ}(7,5,3,0.10\,57728.0,1.00\rT,T) Exp,XDBSUS
 TSIASGLX LASS   Tazt) 161-164  TLH44376A
 1001   A1.26X9

  80:

  50:
                                                                                       36,48
  40.
  20:
   o:
                          A3.44E8
                                                                          AJ..S7K8
     1""rT*"r i i  i
        35,00
                                             -r
                                                              -r
                 35:12    35:24    35,36   35:48    36:00   36',12    36':24    36:36
r±la:O980030 tl-545 Acq:  6-JAN-199S 20:29:20 SC SI+ Voltago SIX 70S Ifoiae: 15253
417.8253 T:4 SSUS(256f 30, -3. 0) PKD(7,5,3,0.10\,61012.0,1.00\,r,X)  Szp:NDB5US
TSIAMSLS LASS  Text:161-164  TLI#44376A
1003,   A2.10E7
                                                                          Al. 65E7
                                                                                       36:48
        35',00    35:12    35:24    35:36    35:48    36:00    36:12   36:24    36:36
Tlla:O980030 tl-545 Acq:  6-JAN-1998 20:29:20 SC EI+ Voltage SIX 70S Soiae:9965
419.8220 T:4 SSUS(256,30,-3.0) PKD(7,5,3,0.10\,39a60.0,1.00\,T,T)
TB.IASSLZ LASS  Text.: 161-164   TLH44376A
1001   A4.75E7
                                                                          A3.86E7
                                                                                       36:48
        35:00    35:12    35:24    35,36    35,48    36:00    36:12   36:24
rila,a980030 tl-545 Acq:  6-JAK-1998 20:29:20 SC EI+ Voltage SIX 70S
430.9729 T:4 Hlp:NDB5DS
TBIAWCTJT LASS  Tait:161-164   TLII44376A
                                                                              36,36
                                                                                       36,48
                                                                                                     3.SK8

                                                                                                     .2.8X8

                                                                                                     .2.1X8

                                                                                                     .1. 4X8

                                                                                                     .6.9X7
      .0.0X0
 37:00    -KLae
      -3.3X8

      .2.6X8

      '-2.0X8

      '-1.3X8

      '-6.6X7
'37:00
                                                                                                     .0.0X0
                                                                                                         Time
      .0.0X0
'37:00    X±ae
                                                                                                37:00
                                                                                                        Tiae
1001
 80:
 50:
 40:
 20:
                            35:27
                                                       36:04   36:14
                                                                                   36:
        35:00    35:12    35:24   35:36   35:48    36:00   36,12    36,24
nieiO980030 tl-545 Acq:  6-JAK-1998 20:29:20 SC XH- Voltugm SIX 70S
479.7165 r:4Kxp:BBB5CS
TRIANGLE LASS  Text.: 161-164   TLIt44376A
                                                                             36:36
                                                                                       36:48
                                                                                                    -0.0X0
                                                                                               37:00    Time
1001
 80:
 50:
 40:
 20.
  oj
                   35:16
                                                                                              36:59
     _1. 0X5

     .8.2X4

     .6.2X4

     .4.1X4

     .2.1X4
        35:00
                 35:12
                          35:24
                                  35:36
                                           35:48
                                                    36:00
                                                            36:12
                                                                     36:24
                                                                              36:36
                                                                                       36,48
                                                                                                     0.0X0
                                                                                               371:00    Tiaa
                                                                                                         175

-------
     -.OS80030  il-545 Acqi  6-JAK-J.SStt JUtiyssv CC EI+ Voltage SIX 70S Noiae:j.iv03
 433.7766 T:4  BSUB(356,30,-3.0) PXD(7,5,3,0.10\,56013.0,1.00\,T,T) XxptSDBSUS
 TRIASGLX LABS  Textj 161 -164  TLIt44376A
 100*      A3.96K8
      35113  35,18  35,34  35,30 35,36  35,43 35,48  35,54  36,00 36,06 36>13  36,18  36,34 36,30
\rilet09i0030 #1-545 Acqi  6-JAN-1998 30,39,30 GC XH- Voltage SIS 70S Boiaei 11589
425.7737 T*4 BSVB(356,30, -3.0)  PKD(7,5,3,0.10\,463S6.0,1.00\,T,T)  XxpiNDBSUS
TRIASGLX LABS  Text,161-164  TLH44376A
           A3.80X8
                                                           A3.64X8
                                                                                                ^6.7X7
                                                                                                15.3X7
                                                                                                ^4.0X7
                                                                                                '^3.7X7
                                                                                                '.1.3X7
\r±J.aiU980030 tl-545 Acqt  6-JAN-1998 30,39:30 SC XI* Voltage SIX  70S SoiaeillB33
435.8169 Tt4 BSUB(3S6,30, -3.0)  PXV(7,5,3, 0.101,47338.0,1.00\,T,T) XxptSDBSUS
TXZABGLX LABS  Texts 161 -164   TZH44376A
100\                                                      A3.30X7
  ao:

  60.

  40.

  30.
                                                                                                ,.7.6X6

                                                                                                L6.1X6

                                                                                                14.5X6

                                                                                                '.3.0X6

                                                                                                '.1.5X6
                                                                                                .0. 0X0
      35', 12 35', 13  35',24 35',30  35-36 35',42  35',48 35:54 36',00  36',06 36', 12  36-18 36',24  36',30     Tlae\
rileiO980030 #1-545 Acq: 6-JAN-1998  20*29*20 SC XH- Voltage SIX 70S Noiaes 10081
437.8140 t*4 3SVB(3S6,30,-3.0) PKD(7,5,3,0.101,40324.0,1.00\,f,T) ExptKDBSUS
TRIASGLX LABS  Tetxt: 161-164  TLH44376A
1001                                                      A3.13X7

 ao\
                                                                                                .7.4X6
      35*12 35*18  35*34 35*30  35*36 35',42  35*48 35',54 36*00  36*06 36*12  36*18 36*24  36*30
rile,U980030 #1-545 Acq: 6-JAN-1998  20*39*20 GC XH-  Voltage SIX 70S
430.9729 T*4 XxptNDBSUS
TRIASGLX LABS  Text, 161-164  TLIt44376A

                             3S*33   35,41                    36*04      36*14
 aoj
    .
 60.

 40.

 20.

  0.
                                                                                         36,39
                                                                                                '.0.0X0
                                                                                                    Time
                                                                                                2.6X7

                                                                                               r
                                                                                               '.2.1X7

                                                                                               -1.5X7

                                                                                               .1.0X7

                                                                                               .5.1X6
      35', 13 35', 18 35,34  35',30  35,36 35',43  35',48 35',54 36100  36,06  36,12 36', 18  36',34  36',30
                                                                                                0.0X0
                                                                                                   Time\
                                                                                                        76

-------
filetO980030tl-545 Acqi  S-JAJf-1998 20,29,30 CC El-r Voltage SIS 703 aoiao,24761
441.7428 r,4  BSOB(256,30, -3. 0) PXD(7,5,3, 0.10\,99044.0,1.00\,T,T) KzpiSDBSOS
TRIANGLE LASS  Tejct,161-l64  TLIt44376A
10Q\                                                                           AS.84X8
  901
  801
  701
  sol
  501
  401
  301
  201
  101
                                                                                                    -1.0X8
                                                                                                    -.9.4X7
                                                                                                    IS. 4X7
                                                                                                    17.3X7
                                                                                                    16.3X7
                                                                                                    15.2X7
                                                                                                    .4.2X7
                                                                                                    .3.1X7
                                                                                                    .2.1X7
                                                                                                    J..OX7
                                                                                                     0.0X0
               35100         36,00         37:00        38,00         39,00
rile,U980030 tl-545 Acq: 6-JAN-1998  20,29,20 GC EH- Voltage SIS 70S Noise,9797
443.7399 Tt4 BSUB(256,30, -3.0) PXZ>(7,5,3,0.10\,39188.0r1.00\,r,T)  XxptSDBSUS
TBIASSLX LABS  Text: 161-164  TLH44376A
  901
  801
  701
  601
  501
  401
  301
  201
  101
                                                                                    40,00
                                                                                     7E8
               35,00         36:00         37:00        38tOO         39:00
r±J.e:0980030 tl-545 Acqi  6-JAW-1998 20i29i20 GC EI+ Voltage SIS 70S
430.9729 t:4 SxptSDBSUS
TSIASSLX IA3S  Taxt:161-164   TLH44376A
                     35,27                 36,59                 38,39
      34,20    34:^9f_  f\^_   36,04    /\.jY   37,29     38,11
                                                                                    40:00
                                                                                                  41 00
                                                                                                    -1.2X8
                                                                                                    J..1X8
                                                                                                    .9.6X7
                                                                                                    .8.4X7
                                                                                                    .7.2X7
                                                                                                    .6.0X7
                                                                                                    .4. 8X7
                                                                                                    .3.6X7
                                                                                                    .2.4X7
                                                                                                    .1.2X7
                                                                                                 .,	0.0X0
                                                                                                  41100  Time
               35100         36,00         37,00        38,00
Tile,0980030 tl-545 Acqt  6-JAH-1998  20,29,20 SC XI+• Voltage SIX 70S
513.6775 T,4 XxptSDBSOS
TSIASSLX LABS  Teit.,161-164  TLXt44376A
100\
                                                                      39,00
                                                                                   40,00
                                                                                                     0.0X0
                                                                                                 41 00  Time
               35,00
                             36,00
                                          37,00
                                                        38,00
                                                                      39,00
                                                                                    40,00
                                                                                                     0.0X0
                                                                                                 41t00  Time
                                                                                                       177

-------
              01-345 AOJ,6-JAN-in a a 20119120 sc KC+ voltage sis 70s soiaos 3417
 457.7377 T,4 BSO3(256,30, -3.0) PKD(7,5,3, 0.10\,13668.0,1.00\,T,T) XxptSDBSOS
 TB.XANSLX LASS  T*xt: 161-164  TLI444376A
 1001                   A3.74K8
           39t30         39', 36         39t42         39', 48         39', 54        40', 00
rila,O9 80030  tl-545 Aoqt  6-JAN-19 9 8 20,29,20 SC EC* Voltag* SIX 70S Boim*,3492
459.7348 T:4  3303(256,30,-3.0)  PKD(7,5,3,0.101,13968.0,1.00\,T,T) KxpiBDBSOS
         LASS  T*tt:161-164   TLH44376A
100*                   A3.32X8
           39', 30         39', 36        39:42         39,48         39:54         40,00
Tile,0980030  tl-545 Acq: 6-J3UT-1998  20,29,20 SC EI+ Voltage SIR 70S Roiae,602L
469.7779 T:4  SSUS(256,30,-3.0) tXD(7,5,3, 0.10%,24084.0,1.00\,r,T) ErpsXDBSUS
TSIANGLZ LABS  Text: 161-164   TLIf44376A
1001                  A4.)2£7
  80.
           39', 30        39,36         39,42         39,48        39,54         40,00
rila,O9S0030 H-545 Aoq, 6-J7OT-1998 20,29,20 SC EH- Voltage  SIS  70S Soiae,4482
471.7750 T,4 BSUS(256,30, -3.0) PKD(7,5,3, 0.10\,17928.0,1.00\,r,T) Xxp,BDBSOS
XSIABGZX LABS  Text-.161-164  TLIt44376A
iOO\                  A4.SOX7
           39,30        39,36         39,42         39,48        39:54
nie,O980030 tl-545 Acq: 6-JJUT-1998 20,29,20 SC XI + Voltage SIX  70S
430.9729 T,4 XxpiSDBSVS
XSIAOSLX LASS  Text: 161-164  TLH44376A
1001
 80.

 60.

 40.

 20:

  0.
39159
                    -4.9X7

                    '.4.0X7

                    13.0X7

                    L3.0Z7

                    ^.9X6

                    .0.0X0
                  40106 T±M,
                    -5.8X7

                    .4.7X7

                    '.3.5X7

                    .2.3X7

                    .1.2X7
                 _,	O.OSO
                  40  06  T±a
                     7.8X6

                    .6.2X6

                    .4.7X6

                    .3.1X6

                    .1.6X6

                    10.0X0
                 40>0«
                     8.6X6

                    .6.9X6

                    .5.2X6

                    .3.5X6
                                                                                            _,	o.oro
                                                                                             40,06 Time
          39130
                        39,36
                                      39142
                                                    39,48
                                                                 39 > 54
                                                                               40100
                   11.9X7

                   11.4X7

                   L9.JW

                   .4.6X6
                                                                                            40,06
                    0.0X0
                       Time
                                                                                                         178

-------
                                                                                 CD
                                                                                 r-
Peak Locate Examination: 6-JAN-1998:20:28 File:U980030
      Experiment:NDB5US Function:2 Reference:PFK

-------
File:U980030 #1-723 Acq: 6-JAN-1998  20:29:20  GC  EH-  Voltage  SIR  70S
319.8965 F:2 Exp:NDB5US
Sample Text:161-164  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC,
100%.                 A1.D8E8
      25:00  25:06  25:12   25:18   25:24   25:30   25:36   25:42   25:48
File:U980030 #1-723 Acq: 6-JAN-1998  20:29:20 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:161-164  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC
100%                 A1.JOE8

 80j
25:54  26:00  26:06
LO.OEO
    Time
   0
      25lOO   25:06   25il2   25il8   25i24   25i30  25i36  25i42  25i48
File:U980030  tl-723  Acq:  6-JAN-1998 20:29:20 GC EI + Voltage SIR 70S
331.9368  F:2  Exp:NDB5US
Sample Text:161-164   TLI#44376A File Text:TRIANGLE LABORATORIES,  INC
100%.            25^08
25:54  26:00  26:06
LO.OEO
    Time
                   _2.4E7

                   _1.9E7

                   _1.4E7

                   _9.6E6

                   L4.8E6
       25:00   25:06  25:12  25:18  25:24  25:30  25:36  25:42  25:48  25:54  26:00  26:06
                   LO.OEO
                       Time
                                                                                                       O
                                                                                                       CO
                                                                                                       vH

-------
1ile:U980030 #,1-723 Acq:  6-JAN-1998  20:29:20  GC  EI + Voltage SIR 70S
 39.8597 F:2 Exp:NDB5US
>ample Text:161-164  TLI#44376A  File Text:TRIANGLE  LABORATORIES,  INC.
100%,
                                                                                                        CO
                                                                                                        vH
                      -i	1	1	1	r
                       28:18
                                        I  '  • •
                                      28:36
    28:06    28:12     28:18    28:24     28:30    28:36     28:42
File:U980030 fljl-723 Acq:  6-JAN-1998  20:29:20 GC El-f Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
Sample Text:161-164   TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%
                                    i	1	1	1	1	r-
                                     28:48
                                                                               28:54
 80j
 60 j
 40J
 20j
  Oj
                          A1.68E8 A1.62E8
      T
—i—(—i—r-
28:12
                      -i	1—|	r—
                       28:18
    28:06    28:12     28:18    28:24     28:30    28:36     28:42     28:48
File:U980030 #1-723 Acq:  6-JAN-1998  20:29:20 GC El-f Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:161-164  TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%                                            28;34

 80J

 60J

 40J

 20 j
                                                                                28:54
    28:06
 28:12
                       28:18
28:24
                                          28:30
28:36
28:42
28:48
28:54
                                      .O.OEO
                                          Time
                                                         .1.1E8
                                                         .8.7E7
                                                         .6.5E7
                                                         .4.3E7
                                                         .2.2E7
                                                         .O.OEO
                                                             Time
.O.OEO
   Time

-------
                                                                                                      CO
 •ile:U980030 #1-385 Acq :  6-JAN-1998  20:29:20 GC EI + Voltage SIR 705
 73.8208 F:3 ExptNDBSUS
Sample Text: 161-164  TLI#44376A File Text: TRIANGLE LABORATORIES,  INC.
lOOi                                     A1.Q3E8
 80 j
 60 1
 40_
 20_
  0
 ile:U980030 #lr385 Acq:  6-JAN-1998  20:29:20 GC EI + Voltage SIR 70S
375.8178 F:3 Exp:NDB5US
Sample Text:16l|-164  TLI#44376A File Text : TRIANGLE LABORATORIES,  INC.
 lOOi            i                         A8.96E7
 60j
 40J
 20 j
  OJ
          33:061     33:12     33:18     33:24    33:30    33:36    33:42
File:U980030 #l|-385 Acq: 6-JAN-1998  20:29:20  GC  EI+ Voltage SIR 70S
383.8639 F:3 Exp:NDB5US
Sample Text: 1611-164  TLI844376A  File Text:TRIANGLE LABORATORIES,  INC.
100*.           i                    33;22
                                                               33:54
                                                                           33:48
                                                               33:54
  80J
  60 j
  40J
  20j
   0
           33:06
33:12
                                                            _3.3E7
                                                            _2.6E7
                                                            _2.0E7
                                                            _1.3E7
                                                            16.5E6
                                                            lO.OEO
                                                                Time
                                                            _2.6E7
                                                            _2.1E7
                                                            _1.6E7
                                                            _1.0E7
                                                            _5.2E6
                                                             O.OEO
                                                                Time
                                                                     _5.8E6
                                                                     L4.7E6
                                                                     _3.5E6
                                                                     _2.3E6
                                                                     -1.2E6
33:18
                                      33:24
33:30
33:36
33:42
33:48
33:54
LO.OEO
    Time

-------
: *"?*
TLI Project:
Client Sample:
Client Project
Sample Matrix: ~
TLI ID:
Sample Size:
Dry Weight
GC Column:
•.' ••••••^
44376A , Method 23 TCDD/TCDF Analysis (DB-225)
161-164 K - - 5 Analysis File: P980098
Gulp Aluminum Alloys
M23TRAIN ~— " Date Received: "12/17/97 	
194-59-13A-E Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: P980094
DB-225 Analyst JM
~ Spike File':
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
SPC2NF04 •-
PF22206
P980092
: n/a
n/a
n/a

8S5?S§^f
2,3,7,8-TCDF
t$^8m&ae$\.
l3Ciri3,7,8-TCDF
'Recovery stancterd
"CO-1.2A4-TCDD
r^ .:? ;^%nC^" ^jacr^'fe > ;'aw»c^
-------
                        Initial
                                     , .Date.
  Data Review By:
                  .A/11*
                                               Calculated Noise Area:
  the  Total Area for each peak with an ion abundance  ratio outside
  ratio liaits baa been recalculated according to method requirements.
                                                                      1.00
  Page No.
  01/07/98

  Compound/
  TCDF
  304-306
         Listing of P980098B.dbf
         Hatched GC Peaks / Ratio / Ret. Tine
                 DC  NL
                DC  WH
               0.
         0:00
        18:29
        18:45 RO
        18:56 RO
        19:02 RO
        19:08 RO
        19:29
        19:37
        19:45
        19:55
        20:02
        20:11
        20:20
        20:30
        20:39
        20:48
        21:11
        21:38
        21:44
        21:53
        22:08
        22:22
        22:33
        22:41 RO
        22:46
        23:00
        23:07
        23:20
        23:37
        23:44
        23:57 RO
        24:17 RO
        24:32
        25:17
        25:43
65-0.89
 0.65
 0.77
 1.55
 0.61
 1.11
 0.98
 0.77
 0.77
 0.76
 0.77
 0.78
 0.76
 0.79
 0.79
 0.75
 0.76
 0.75
 0.74
 0.76
 0.76
 0.76
 0.74
 0.76
 0.57
 0.79
 0.75
 0.76
 0.75
 0.75
 0.75
 0.59
 0.58
 0.76
 0.73
 0.75
 304-306

 13C12-TCDF
 316-318
                     33 Peaks
               0.65-0.89
DC  NL   0:00  RO  1.21
DC  WL  18:32  RO  0.64
DC  WL  20:10     0.70
DC  WL  20:33  RO  0.60
DC  WL  20:43  RO  1.44
      2.94
  2,308.95
     39.31
     23.75
     28.62
    105.63
  2,436.80
  2,591.56
  5,168.45
  2,100.11
    167.27
  2,576.52
  6,085.44
  3,377.06
  9,073.85
  3,139.90
 20,021.06
  4,195.80
    847.14
  4,342.05
  4,165.30
  1,006.07
  5,558.11
     22.18
     17.30
    357.40
    985.88
    982.85
    460.08
    017.66
     27.03
     19.81
  3,732.70
    640.95
     30.57
107,622.59
                                               4.44
                                               5.84
                                              19.67
                                              29.63
                                               3.43
.Peak.


1,007




1,
1,
2,


1,
2,
1,
3,
1,
8,
1,

1,
1,

2,


1,
1,
2,
2,
2,


1,


34
10
17
58
058
125
227
911
73
112
678
486
892
358
547
789
366
871
799
426
397
9
7
870
289
134
760
156
11
8
606
270

1. . Area. Peak. 2. . Rel.RT Conpound . Name . . ID.. Flaga.
0.792-1.101

.96
.40
.33
.87
.48
.70
.25
.46
.66
.48
.22
.99
.07
.77
.38
.76
.85
.60
.69
.66
.90
.54
.65
.64
.05
.08
.19
.68
.12
.76
.62
.27
.59


1,




300.
22.
16.
16.

99
21
96
17
59.68
1,
1,
2,
1,

1,
3,
1,
5,
1,
11,
2,

2,
2,

3,


2,
I,
2,
3,
2,


2,


378.
466.
940.
188.
93.
464.
406.
890.
181.
781.
473.
405.
480.
470.
365.
579.
160.
16.
9.
487.
696.
848.
699.
861.
19.
14.
126.
370.

10
31
99
45
79
30
45
99
08
52
30
95
54
36
64
17
57
88
66
35
80
66
40
54
80
92
43
36

0.
0.
0.
0.
0.
0.
,000
800
812
820
824
828
0.843
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
849
855
862
867
874
880 E
887
894 E
900
917 E
937
941
947
958
968
976
982
986
996
001 2378 -TCDF AN
010
022 E
027
037
051
062
095
113
0.957-1.043






























0.
0.
0.
0.
0.
000
802
873
890
897
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                            Printed: 04:49 01/07/98
                                                                                         184

-------
  Page No.      2   '        Listing of P980098B.dbf
  01/07/98                 Matched GC Peaks / Ratio / Ret. Time

  Compound/
  M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.

                                                                                  0.924
                                                                                  0.933
                                                                                  0.944
                                                                       	-  613; 46  -1.000 --13C12-33-78-TCDF- ISO	
                                                                            9.72  1.041
                                                                                  1.077
                                                                                  1.082
                                                                                  1.089
                                                                                  1.105
  316-318               2 Peaks               1,104.05
DC
DC
DC

DC
DC
DC
DC
WL
WL
WL

WH
WH
WH
WH
21:
21:
21:
«»^
23 :
24:
24:
24:
25:
25:
21
33
49
rt IS
06
03
53
59
10
32

RO

RO
RO
RO

RO
0
0
0
0
0
.0
0
0
.73
.41
.70
.62
.37
.36
.80
.52
15.
9.
23.
Irtnn
t U5rv .
13.
1.
1.
9.
7.
14
70
44
i A i7fi ca
J.4 4 /O .'00'
91 6.05
91
72
03
42
                                        Above: TCDF / TCDD Follows
  13C12-TCDD                     0.65-0.89                                     0.908-1.092
  332-334         DC  HL   0:00 RO  1.04          2.55                             0.000
                 DC  SN  20:30 RO  0.40          2.87                             0.948
                         21:38     0.81        722.82        323.94        398.88  1.000 13C12-2378-TCDD IS1
                         21:56     0.82      1,605.03        723.03        882.00  1.014 13C12-1234-TCDD RSI
                         22:43 RO  0.97          7.97          4.36          4.50  1.050
                 DC  WH  23:44 RO  0.44          3.86                             1.097
                 DC  WH  23:52 SO  1.14          1.26                             1.103
                 DC  WH  24:29 RO  0.17          1.91                             1.132
  332-334               3 Peaks               2,335.82
 Column Description	   'Why' Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)      WL-Below Retention Time Window  A-Peak Added
   RT. -Retention Time (ma:as)    WH-Above Retention Time Window  K-Peak Kept
   t.1 -Ratio of M/M+2 Ions       SN-Below Signal to Noise Level  D-Peak Deleted
 OK    -RO-Ratio Outside Limits   
-------
              tl-922
 303.9016 XzptDB325
 XBIAHSLX LASS  Tmxtsl61-164 TLIH437SA
t,i+ vo.icag'e SIS  70P
                                      23137
     33:36 22:48 33iOO  23tL2 23s24  23s36 23,48 24:00 24:12  24:24 24:36 24:43  25:00 25:12 25:24
r±lesP980098 tl-933 Acqt7-JSS-98 03:33tl9 KI+ Voltage SIS 70P
315.9419 Xxp,DS335
TRIANSLX LASS  Texts 161-164 TLH44376A
1003

 95.

 90.

 85.

 30.

 75.

 70.

 65.

 50:

 55.

 50.

 45.

 40.

 35.

 30.

 35.

 30.

 15.

 10.

  5J
                     23:06
                                                          '-.1.3S6

                                                          '•.1.2X6

                                                          '•.1.1X6

                                                          '-.1.1S6

                                                          '•.9.9E5

                                                          19.3S5

                                                          '•.8.6Z5

                                                          '.7.9K5

                                                          .7.3SS

                                                          '.6.6S5

                                                          .5.9X5

                                                          .5.3X5

                                                          .4.6X5

                                                          .3.9X5

                                                          .3.3X5

                                                          '.3.6X5

                                                          .3.0X5

                                                          .1.3X5

                                                          .6.6X4
                                                                                                     .0.0X0
     m    ';•, •,',.. ~	,	~V. ......,......'.,  	". 77. ...... 7 .'		 .... , . . I    "*"
     22:36  33»48 33*00  23:12 23:24  23:36 33:48  24:00 24:12  24s24  24:36 24:48  35>00 25tl2  35:34      Time
                                                                                                       186

-------
 Tila:P9HOQ98 #1-932 Acq:/-JAa-Sa OjtlJilS Elf Voltage SIXTOP ooiaa:5U1
 303.9016 BSUB(256,30,-3.0) PXD(S, 3,1, 0.10\, 2324 .0, 0. 00\,T,f) Sxp:DB225
 TXIANGLZ LASS  Text: 161-164 TLH44376A
 100\                               A8.5.5X7
           19t00       20:00       21:00       33,00       33:00        24:00
rtle:P980098 tl-922 Acq:7-JXK-98 03:23:13 XX+ Voltaga SIX 70P Xoia»t888
305.8987 BSUB(256,30,-3.0)  PKD(S,3,1,0.10\,3552.0,0.00\,r,T) KzpiDB225
TXIANSLX LABS   Text: 161-164 TL1H4376A
10 0\                               AJ..JJX8
                                                                                    25,00
          19:00        20:00       21:00       22:00       23:00       24:00
rile:P980098 il-922 Acq:7-J7Ol-9a 03:23:19 SH- Voltage SIX 70P Koiao:1517
315.9419 3SUB(256,30,-3.0)  PKD(S,3,1, 0.10\, 6068.0, O.QO\,T,r)  Sxp:D3225
TZIANGLX LASS  Text: 161-164 TLH4437SA
10 0\                                                       A4.77E6
  80.

  SO.

  40.

  20:
                                                                                    25:00
          19:00        20:00       21,00       22:00       23:00       24:00
riletP980098 tl-922 Acq:7-JZUt-98  03:23:19  ZI+ Voltaye SIS 70P Xoiao:1257
317.9389 BSVB(256,30,-3.0)  PKD(5,3,l,0.10\,5028.0,0.00\,r,r) Sxp:DB225
TRIASSLX LABS  Text: 161-164 TLIt44376A
100S,                                                       A6.13E6
 80.

 SOL

 40.

 20:
                                                                                   25:00
          19:00       20:00        21:00       33:00       23:00
rile:P980098 tl-922 Acq:7-JXK-98 03:23:19 KI+  Voltage SIX  70P
375.8364 Xxp:DB225
XSIANSLS LABS  Text,161-164 TLH44376A
10 0\                                                        23t04
 80:

 so:

 40.

 20:

  o:
                                                                  24:00
                                                                               25:00
18:34
         19:18      20,13  30>"  31:15
                                      21:39
                                                                                            1.3X6

                                                                                           '.1. 0X6

                                                                                           .7.9X5

                                                                                           .5.2X5

                                                                                           .2.6X5

                                                                                            0.0X0
,1. 7X6

,1.3X6

9.9X5

6.6X5

3.3X5

0.0X0
   lime
          19:00
                      20:00
                                  21:00
                                               22:00
                                                           23:00
                                                                       24:00
                                                                                   25:00
                                                                                                        IS7

-------
               l-922 Acqi 7-JAN-98  03s2J>19 EI+ Voltago SIR  7 OP NoimmsSSO
 319.8965 3303(356,30,-3.0) PXD(S,3,1,0.10%,3560.0,0.00\,T,I) Xzp,DB225
 TRIANGLE ZJUS  T*xt:161-164 TLH44376A
 1001
  80.

  SO.

  40.

  20.
A1.87X7
                        A4.04X6
                                               A7.30X6
                 20.00           21:00           22,00           23,00
 Tlle,P980098 tl-922 Acq:7-J7UT-98 03:23,19 EH- Voltaga SIS 70P ltoiam,3644
 331.8936 3303(356,30,-3.0) PXD(5,3,l,0.10\,14576.0,0.00\,r,r) XxptDB22S
 TSIASGLX LASS  Taxtt 161-164 TLIH4376A
 1001
                                                                     34100
  80.

  60.

  40.

  30:

   o:
A3.38X7
           A5.26Z6
             A
A2.90Z6
   A  .
                                  A9.34X6
                70:00            21:00           22:00           23,00
r±latP980098 tl-922 Acq, 7-JJOT-98 03,23,19 XH- Voltage SIS 70P HOiao>842
337.8847 3SU3(256,30,-3.0)  PXD(5,3,l,0.10\,3368.0,0.00\,r,r) XxptDB225
TRIANGLE LASS  Tait: 161-164 TLH44376A
1001                                            A1.98E7
  80.

  60:
  40.
 20;
                 A6.26X6
           A1.11X6
              /\ Lr*.
                        A1.54X6
                                          A7.06X6
                             A
                20:00            21:00           22,00           23:00
rilaiP980098  tl-922 Acqt7-JJUT-98 03:23,19 XH- Voltage SIX 70P Abide: 752
331.9368 BSVB(256,30,-3.0)  PXD(5,3,l,0.10\,3008.0,0.00\,r,r)  Exp:DB225
TRIANGLE LASS TOXt,161-164 TU944376A
1001                                           A7.23X6
 80.

 eo:

 40.
 20J
                             A3.24X6
                20:00            21:00           22:00            23,00
T±letP9B009B tl-922 Acqt7-J3UT-98 03,23,19 XH- Vbltaga SIS  70P Nolae,718
333.9338 BSUS(256,30, -3.0) PKD(5,3,1, 0.10\,2S72.0,0.00\,F,r)  XxptDS235
TRIANGLE LASS  Text, 161-164  TLII44376A
1001                                           AS. 82X6
 80.

 60.

 40.

 20.

  0.
                            A3.99X6\
                20100
                                21:00
                                                22:00
                                                                 23100
                                                                                  24:00
                                                                 A1.39X7
                                                                                  24,00
                                                                                 24100
                                                                                 24,00
                                                                 C9.3X6

                                                                 '.7.4X6

                                                                 -.5.6X6

                                                                 .3.7X6

                                                                 H.9X6
                                                             ^	'.0.0X0
                                                              25 00  tta<
                                                                -1.2X7

                                                                 J.2X6

                                                                 .6.9X6

                                                                 .4.6X6

                                                                 ,2.3X6
                                                                                                  25
                                                                                         0.0X0
                                                                                        00  Time
                                                                 5.6X6

                                                                 .4.5X6

                                                                 .3. 4X6

                                                                .2.3X6

                                                                .1.1X6
                                                                                                     .0.0X0
                                                                                                  25100  T±me
                                                                _1. 8X6

                                                                 J..4E6

                                                                 .1.1X6

                                                                 '.7.1X5

                                                                 .3.6X5
                                                                                                     .0.0X0
                                                                                                  25 00  T±me
                                                                 2.3X6

                                                                .1.8X6

                                                                '.1.4X6

                                                                .9.2X5

                                                                .4.6X5
                                                                                       .0.0X0
                                                                                     25  00  T±a>
                                                                                                        183

-------
r±J.a:P980098 tl-922 Acqi7-J3ur-98 03:23:19 XI+ Voltage SIS 70P
303.9016 Kxp:DB22S
TSIANSLX LABS Text:161-164 TLH44376A
1001 31:11
ao: 1
,-: 20:39 \\
60: ill
: 19tts \
40' *.»<••-' 30:20 11 1 1
" A ' A 1 A
TA mw\i\ l\ 1
19 1 00 20 1 00 21 • 00
rile:P980098 tl-922 Acq:7-JJX-98 03:23:19 XH-
315.9419 Xxp:DB225
XBIA1KLX LABS Text: 161-164 TLIt44376A
1001
80:
60:
40:
20J

19\ob 20(00 21:00
rile:P980098 tl-922 Acq:7-JMl-98 03:23:19 XH-
319.8965 Xxp:DB22S
TRIANGLE LABS text.: 161-164 TLH44376A
100S 15(18
•«!
60: ».«
'"
30- 20:32 3i:17
o- 1 v 1 \ AyvA/\-*
19iOO 30(00 ' 3lioO
fJJ.e:P980098 tl-922 Actj:7-JSS-98 03:23:19 XX+
331.9368 Exp:DB225
TRIANGLE LABS Text: 161-164 TLH44376A
1001
80:
60-
<°i |
-
n. l\
19tOO 20:00 21:00
rlle:P980098 tl-922 Acq:7-JJOT-98 03:23:19 XH-
292.9825 Sxp:DB225
TRIANGLE LABS Text: 161-164 TLIt44376A





22:33


_i . 4r7
.1.1J7
.8.1E6
23:37
21:53 l 23(20 A . £5.4*5
A . A A ji
Jt Jl M/
32(00 3J(00
Voltxg* SIS 70P


23:06




\ I
33:00 ' ' 2.3(00
Voltage 512 70P






21:57
•+S>f\n. ^ —-
33i 00 ' 23:00
Voltage SIS 70P


21:56

38\


\\
22:00 23:00
Voltage SIS 70P


1004 ^ii/5 1S±36 20:1320:38 3J-:1£ 21:49 22:24 32(54
00:
60:
40:
20:
o'-
19\00 20(00 21(00
rile:P980098 tl-922 Acq:7-JAIt-98 03:23:19 XH-
330.9792 Xrp:DB225
TRIASGLX LABS Text: 161-164 TLIt44376A
1004 15,03 19:33 20:31 21:0021:27
so: 'rTT ^*
60.
40:
20:
o-
19:00 20:00 21(00





22:00 23:00
Voltage SIS 70P


-^Y-V^^^^^^^V





32(00 23(00
A 24: 32
\m 1 -"7W
V / v \ 7V ^ o.ato
24:00 ' 25(00 Time



1.3X6
'.1.1X6
'-.7.9X5
.5.3X5
.2.6X5

24:00 ' ' 25(00 ' ' Time



9.3X6
'-.7.4X6
'•.5.6X6
.3 . 7X6
-.1 . 9X6
T r o.oxo
24(00 ' 25(00 ' Mae



1 . 8X6
.1.4X6
.1.1X6
.7.2X5
.3 . 6X5
: a . oro
24:00 25:00 ' ' Time



24:01 ._24^47_25;J.3 ^9.1X6
.7.3X6
.5.5X6
.3.7X6
.1.8X6
.0.0*0
34(00 35(00 Mae



_^ ^. 34U5 25;13 7. 7X6
/K^k^VVVV-T »>«•• ^•w>*w^v»>>y
.6.2X6
.4.6X6
.3.1X6
.1.5X6
O.OKO
24(00 25(00 Mae

-------
Ref, uss    292,9825     Pe* top
Height  1,88 wits Spa   288 opt
Systet file naie
Resolution
Group niter
lonization lode
Switching
Ref. lasses   292,9825,
fl   232.9825
6   383,8618
    COK 0001
    OWiWQ/
D   315,3419
E   317,9389
F   319,8985
6   321,3936
H   327,8847
I   338,9792
J
K
L
I
       1
     El*
 VOLTAGE
388,9761
338,9792
331,9368
Oral   I  338,9792    Pe*top
Height  1,18 volts  Spa   288 ppi
                                                            •> r> n
                                                            JL JU

-------
 TLI Project:     44376A
 Client Sample:   165,167,168/225
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980031

Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:

Gulp Aluminum
M23TRAIN
194r59-14ACD
1.000
n/a
DB-5

Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst

12/17/97
12/29/97
01/06/98
n/a
U980026
BB

Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:

SPMTT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2.3.7.8-PeCDD
1.2.3,4,7,8-HxCDD
1^3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2.3,7,8-TCDF
1A3.7.8-PCCDF
Z3,4J,8-PeCDF
1 ,2.3,4,7,8-HxCDF
1.2,3,6.7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1.23.4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2^,4,6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDE)
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt $tg) ^ QL mpG
0.51
3.6
4.7
7.4
10.3
40.0
63.1
64.6
15.8
28.7
97.5
32.5
47.4
2.8
155
25.6
160

Amt {ng} Mumber DL EMPC
76.5 12
58.1 9 92.2
114 7
80.3 2
370 16
391 14 393
403 13
262 4
Ratto
0.77
1.51
1.23
1.26
1.28
1.01
0.85
0.74
1.61
1.55
1.27
1.20
1.25
1.26
1.07
1.06
0.89

-








RT
25:20
29:38
32:44
32:49
33:07
36:03
39:37
24:39
28:34
29:18
32:02
32:09
32:39
33:23
35:02
36:33
39:50










Frags
PR_




iZ

E_

iZ

iZ
PR_
E_

iZ

Flags
E_

iZ
E_
E_
E_
E_
E_
                                       Page 1 of 2
                        MTT2.PSR 11.01. LARS 6. laogi
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:19 01/10/98
                                131

-------
TLI Project:
Client Sample:
                   44376A
                   165,167,168/225
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980031

; mtenra S&rtdards '
I3Cir2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,2-12,3,7,8-PeCDF
13G1J-12,3.7.8-PeCDD
13Cl2-12,3,6,7,8-HxCDF
13C,2-12.3,6,7,8-HxCDD
13C,2-12^,4,6,7,8-HpCDF
l3C12-12,3,4,6,7,8-HpCDD
I3C ,2- 1 2,3,4,6,7,8 ,9-OCDD

Surrogate Standards fType A)
I3C,2-2,3,4,7,8-PeCDF
13C,2-12,3,4,7,8-HxCDF
13C12-1.2,3,4,7,8-HxCDD
3Clrl,2,3,4,7,8,9-HpODF
Surrogate Standards {Type A)
"CU-2,3,7,8-TCDD
Alternate Standards {Type A>
13C,2-12,3,7,8,9-HxCDF
13C12-2,3,4,6.7,8-HxCDF
:; Recovery Standards
13C,2-1A3,4-TCDD
l3C12-U,3,7,8,9-HxCDD
,
$i$a$'****
3.0
2.7
3.0
2.9
3.1
3.2
3.4
3J
6.4

,^i»t frgl
3.4
4.1
3.9
3.7
f£ff(&, §1§)
3J
Ana. (ng)
32
32
^ '



-;^ >« Recover^
75.3
68.4
74.6
71.4
77.0
80.8
85.0
88.5
80.0

% Recovery
85.5
104
97.1
93.7
, %Becovery
82.9
% Recovery
80.7
79.9
-



', •'
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%


40%-130%
40%-130%
40%-130%
40%- 130%



40%- 130%
40%- 130%



"•- Bbtt
7 %%£. **&*&'', ,
0.75
0.80
1.56
1.49
OJ2
124
0.44
1.03
0.87

Ratfe
1.54
0.52
1.23
0.44


Ratio
OJl
0.55
Ratio
0.82
124

;%- -ffT -- '""JFiS^s- -
24:37 	
25:19 	
28:34 	
29:37 	
32:09 	
32:48 	
35:01 	
36:03 	
39:36

flnr Ptags
29:17 	
32:03 	
32:44
36:32 	
RT Ftegs
25:20 	
BT Flags
33:23 	
32:38 	
RT Flags
25:09 	
33:07 	
                     Data Reviewer.
                                                          01/10/98
                                       Page 2 of 2
                                                                       MTTZ.PSRvlJ)!, LARS&10.0S1
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 10:19 01/10/98
                                                                             192

-------
                         Initial
                                    ..Date.
  Data Review By:
                                              Calculated Noise Area:
                                                                     1.00
  The Total Area for  each peak with an  ion abundance  ratio outside
  ratio  limits has been recalculated according to nethod requirements.
  Page No.
  01/10/98

  Compound/
  M_Z.... QC
  TCDF
  304-306
         K
         K
         K
         K
         K
         K
         K
  304-306

  J.3C12-TCDF
  &16-318
  316-318
 TCDD
 320-322
         NK
         NK
         K
         K
        M
        AN
Hatched GC Peaks / Ratio /
Omit Why ..RT. OK Ratio Total. Area. ..
0.65-0.89
DC
















NL 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
25
26:
:00 RO
:27
:58
:12
:35
:55
:19
:35
:49
:02
:13
:27
:39
:03
:16
:32
22
16 Peaks

DC
DC
DC



DC
DC
DC

NL 0:
WL 22:
WL 22:
24:
24:
25:
WH 26:
WH 26:
WH 26:
0
:00 RO
24
:59
03
37
17
09
45 RO
54
3 Peaks

DC









NL 0:
22:
23:
23:
24:
24:
24:
25:
25:
0.
00 RO
48
11
28
09
25
49
14
20
0.59
0.75
0.74
0.74
0.74
0.74
0.73
0.74
0.74
0.75
0.74
0.75
0.74
0.75
0.75
0.73
0.74
3
.65-0.89
1.27
0.82
0.84
0.80
0.75
0.76
0.85
0.93
0.86
6,422.82
81,985.40
79,054.70
87,376.20
451,067.00
291,646.00
322,976.00
223,884.70
267,897.00
356,664.00
136,966.90
126,685.20
576,292.00
141,772.10
115,529.70
21,012.72
14,968.77
,295,778.39
Ret. Time
Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound. Name. . ID.
0.867-1.079

35
33
37
192
124
136
95
114
152
58
54
245
60
49
8
6


,099.80
,749.00
,269.40
,246.00
,256.00
,663.00
,304.70
,147.00
,480.00
,449.90
,168.60
,114.00
,686.30
,697.50
,867.82
,388.32


46
45
50
258
167
186
128
153
204
78
72
331
81
65
12
8


,885.60
,305.70
,106.80
,821.00
,390.00
,313.00
,580.00
,750.00
,184.00
,517.00
,516.60
,178.00
,085.80
,832.20
, 144 . 90
,580.45

0
0
0
0
0
0
0
0
0
0
0
0
1
.000
.871
.892
.902
.917
.931
.947
.958
.968
.976
.984
.993
.001 2378-TCDF AN
. Flags .




E
E
E
E
E
E


E
1.018
1.
.026

1.037
1.071



0.959-1.041
79.86
598.41
953.20
378.73
28,763.40
481.83
520.21
175.85
106.79
29,623.96
65-0.89
0.49
0.77
0.77
0.81
0.76
0.78
0.79
0.77
0.77
177.34
188,101.40
123,705.30
12,374.19
45,571.30
24,302.90
12,193.61
46,900.00
3,120.00
0.000
0.910


12,





168.43
,283.10
207.64





16





210.30
,480.30
274.19



0.
0.
1.
1.
1.
1.
1.
934
977
000 13C12-2378-TCDF ISO
027
062
087
093










82,
53,
5,
19,
10,
5,
20,
1,

050.40
974.40
541.73
743.60
684.90
382.70
400.00
360.00

106,
69,
6,
25,
13,
6,
26,
1,
0.895-

051.00
730.90
832.46
827.70
618.00
810.91
500.00
760.00
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.047
000
901
916
927
954
964
980
997
001 2378 -TCDD AN


E






PR
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01710/98
            193

-------
  Page No.     2
  01/10/98


  Compound/

  M_Z	 QC.Log Omit Why
Listing of 0980031B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT.  OK Ratio Total. Area. .. Area.Peak.1.. Area. Peak. 2. . Rel.RT Compound. Name. .  ID.. Flags.


25
25
:30
:40
25:53
	
320-322
37C1-TCDD
328
	 - - . - 26. 	
0.77
0.77
0.
.74
. 1
-------
  Page No.     3
  01/10/98


  Compound/
  M_Z.... QC.Log Omit why
Listing of 0980031B.dbf
Matched.GC Peaks / Ratio / Ret. Time
.RT.  OK  Ratio Total.Area... Area.Peak. 1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.






340-342
13C12-PeCDF
352-354
















352-354
PeCDD
356-358
D












356-358
13C12- PeCDD
368-370



28
28
	 29
29
29
30
:44
:52
-:.18
:27
:46
:14






18 Peaks

DC NL 0
26
26
26
27
27
27
27
28
28
28
29
29
29
29
29
30:

:00
:24
:36
:46
:08
:22
:43
:55
:18
:34
:51
:03
:17
:33
:52
:59
:16
1
RO
RO
RO





RO


RO


RO
RO
RO
16 Peaks

DC NL 0:

00
DC WL 27:35
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
50
18
32
41
52
02
07
20
30
38
45
05
1.
RO
RO
RO
RO






RO



1.59
1.65
...1..55 	
1.55
1.67
1.56
2
.32-1.78
1.20
1.16
1.93
1.54
1.46
1.73
1.60
1.53
32.58
1.56
1.59
3.04
1.54
1.66
1.19
3.16
1.03
78
135
_162
230
46
21
,253
,573.30
,871.70
,442.80
,219.10
,447.90
, 294 . 15
,659.25
48
84
	 98
139
29
12

,282.90
,681.20
,842.50—
,783.00
,036.80
,979.70

30,290
51,190
	 63,600
90,436
17,411
8,314

.40
.50
.30-
.10
.10
.45

1.006
1.011
- 1. 026 23478- PeCDF -AN
1.031
1.042
1.058

0.860-1.140









22,


18,




30.44
116.56
103.50
135.65
12.28
149.18
260.33
958.40
504.77
,191.91
754.48
140.17
,338.70
675.57
232.95
51.20
185.77
44,811.92
32-1.78
1.02
0.75
1.07
1.25
1.53
1.53
1.58
1.58
1.55
1.53
0.83
1.51
1.56
1.58
12 Peaks

DC NL 0:
27:
28:
28:

00
48
06
15
1.
RO
RO
RO

32-1.78
0.94
3.43
2.01
1.58

1,
107,
7,
76,
13,
50,
7,
15,
18,
9,
13,
8,
7,
336,
14.13
032.72
958.12
456.68
190.60
846.01
543.60
218.33
000.66
970.71
212.00
287.99
999.70
994.83
679.23








6,
13,


11,





70.85
78.21
82.28
7.28
94.45
160.54
580.33
,449.74
,517.80
463.36
167 . 23
, 127 . 20
422.07
141.60
63.39
112.92

60
40
53
5
54
100
378
197
8,674
291
54
7,211
253
119
20
109

.86
.59
.37
.00
.73
.29
.07
.95
.11
.12
.97
.50
.50
.09
.08
.30
0.000
0.924
0.931
0.937
0.950
0.958
0.970
0.977
0.991
1.000 13C12- PeCDF 123 IS2
1.010
1.017
1.025 13C12-PCCDF 234 STO1
1.034
1.046
1.050
1.060




65,
4,
46,
8,
30,
4,
9,
11,
5,
7,
5,
4,



621.60
532.49
099.70
374.55
962.40
419.59
126.47
485.80
599.45
991.37
478.95
893.29



61,210.
3,619.
30,090.
5,471.
19,581.
2,798.
5,874.
7,484.
6,707.
5,296.
3,520.
3,101.

0.935-1.022


00
39
90
46
20
74
19
91
67
62
75
54

0.000
0.931
0.940
0.956
0.963
0.968
0.975
0.980
0.983
0.990
0.996
1.001 12378-PeCDD AN
1.005
1.016

0.865-1.135




9.34
97.36
17.90
79.72





130.93
14.12
48.80

38.
7.
30.

18
02
92
0.000
0.939
0.949
0.954
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:20 01/10/98

                                                                             195

-------
  Page No.
  01/10/98
Listing  of 0980031B.dbf
Matched  GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why . .RT. OK Ratio Total.Area...  Ar ea. Peak.1.. Area.Peak.2..  Rel.RT  Compound.Name.
                                                                         ID.. Flags.








368-370
HxCDF
374-376




28
29
29
	 29
29
30
30
30
:32
-.20
:37
:44
:S6
:02
:17
:37
RO
RO


RO
RO
RO
RO
11 Peaks

DC NL 0
31
31
31
31

:00
:05
:14
:23
:32
1
RO




31:41
31:52
32:02
32:09
32:16
32:26
32:39
AN
M
374-376
13C12- HxCDF
384-386











384-386
HxCDD
390-392
D



33:23
33:
28

13 Peaks

DC NL 0:
31:
31:
31:
31:
31:
32:
32:
32:
32:
32:
33:

00
05
13
30
33
50
03
09
24
38
55
23
0.
RO
RO
RO
RO
RO
RO




RO

11 Peaks

DC NL 0:
D SN 31:
31:
32:
32:

00
26
35
01
14
1.
RO
RO



1.24
0.62
1.49
...1.41 .
2.37
0.33
6.82
0.34
60.20
19.59
10,959.04
	 1,571.16
45.01
28.92
43.63
78.80
13,001.33
.05-1.43
0.92
1.26
1.26
1.20 '
1.26
1.26
1.34
1.27
1.20
1.26
1.26
1.25
1.26
1.25
1
43-0.59
1.32
1.81
0.80
1.13
1.60
1.82
0.52
0.52
0.51
0.55
1.76
0.51
4,978.94
194,950.10
417,152.00
36,091.60
53,322.20
29,294.80
5,044.60
391,030.00
162,153.10
48,434.80
75,865.00
185,974.20
9,560.00
50,900.00
,659,772.40
36.59
11.91
6,565.88
	 	 918.59..
41.90
17.58
116.63
47.90

HxCDF Follows -

108,558.00
232,369.00
19,695.90
29,695.60
16,336.60
2,892.35
218,602.00
88,312.10
27,010.50
42,277.40
103,229.00
5,330.00
28,300.00

29
19
4,393
. 652
17
52
17
142

.42
.36
.16
.^7
.65
.80
.11
.27

0
0
1
1
1
1
1
1

.963
.990
.000 13C12-PeCDD 123 IS3
.004
.011
.014
.023
.034










0.962-1.047

86,392
184,783
16,395
23,626
12,958
2,152
172,428
73,841
21,424
33,587

.10
.00
.70
.60
.20
.25
.00
.00
.30
.60
82,745.20
4,230.00
22,600

.00

0
0
0
0
0
0.
.000
.967
.971
.976
.981
.985

E
E



0.991
0.996 123478-HxCDF AN
E
1.000 123678-HxCDF AN
1,
,004

1.009
1.016 234678-HxCDF AN
1.038 123789-HxCDF AN
E
PR
1.041



0.876-1.124
65.79
46.27
595.03
127.07
26.67
120.20
13,621.10
15,925.09
663.29
14,896.82
217.11
11,596.17
57,834.82
05-1.43
0.42
0.45
1.25
1.22
1.22
417.85
539.64
27,935.00
147,092.10
67,560.90

55.52
315.47
95.44
28.19
144.53
4,653.76
5,440.09
223 . 94
5,295.11
253.48
3 , 917 . 11

HxCDD Follows - -


15,540.20
80,941.80
37,122.10


30.64
394.
84.
,06
.15
17.66
79.60
8,967.
10,485.
439.
9,601.
143.
7,679.

34
00
35
71
78
06

0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.

0.958-


12,394.
66,150.
30,438.


80
30
80
0.
0.
0.
0.
0.
000
967
971
980
981
990
997 13C12-HXCDF 478 SOT2
000 13C12-HXCDF 678 IS4
008
015 13C12- HxCDF 234 ALT2
024
038 13C12-HXCDF 789 ALII

1.014
000
958
963
976
983

















E

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:20 01710/98
                                                                              < n *"•
                                                                              ib'o

-------
  Page No.
  01/10/98
                         Listing of  (J980031B.dbf
                         Matched GC  Peaks  /  Ratio / Ret. Tiae
  Compound/
  M_Z....  QC.Log  Omit Why  ..RT. OK Ratio Total. Area. ..  Ar ea. PeaJc. 1. .  Area. Peak. 2. .  Rel.RT Compound. Name. .  ID.. Flags.



390-392
13C12-HXCDD
402-404




402-404
HpCDF
408-410



D
D

408-410
13C12- HpCDF
418-420


418-420
HpCDD
424-426
D


32:24
32:44
-. • • - - 33. 49
33:07
7 Peaks

DC NL 0:00
32:03
32:44
32:48
33:07
4 Peaks
1.18
1.23
~: 1 . 26
1.28

1.05-1.43
RO 2 . 18
RO 0.88
1.23
1.24
1.24
10,722.53
11,056.60
~" 227430/44
30,024.80
316,822.37

41.46
54.21
8,772.48
12,341.48
15,357.72
36,525.89
0.88-1.20
DC NL 0:00
35:02
35:17
35:27
DC NH 35:55
DC NH 36:01
36:33
4 Peaks

DC NL 0:00
35:01
36:32
2 Peaks
RO 0.77
1.07
1.04
1.06
RO 1.73
RO 3.39
1.06

0.37-0.51
RO 2.66
0.44
0.44
111.02
585,811.00
118,835.20
154,379.50
1,117.51
716.92
75,223.70
934,249.40

71.22
10,726.26
8,063.95
18,790.21
0.88-1.20
DC NL 0:00
DC WL 35:10
35:18
36:03
0.91
RO 0.43
1.00
1.01
90.06
1,890.28
98,857.60
98,139.60
5,810.30
6,101.00
~ ' ~~12", 517 :'00
16,831.50



30.01
4,841.31
6,842.51
8,497.16



302,399.00
60,588.10
79,478.80


38,661.30



3,255.06
2,444.77




49,385.70
49,229.30
4,912.23 0.988
4,955.60 0.998 123478-HxCDD AN
9,913.'44 '1T001 123678-HxCDD 	 AN 	 -••
13,193.30 1.010 123789-HxCDD AN

0.970-1.030
0.000
34.06 0.977
3,931.17 0.998 13C12-HXCDD 478 SUR3
5,498.97 1.000 13012-HxCDD 678 IS5
6,860.56 1.010 13C12-HXCDD 789 RS2

0.996-1.049
0.000
283,412.00 1.000 1234678-HpCDF AN E
58,247.10 1.008
74,900.70 1.012 E
1.026
1.029
36,562.40 1.044 1234789-HpCDF AN

0.943-1.114
0.000
7,471.20 1.000 13C12-HpCDF 678 IS6
5,619.18 1.043 13C12-HpCDF 789 SUR4

0.975-1.005
0.000
0.975
49,471.90 0.979 E
48,910.30 1.000 1234678-HpCDD AN E
 424-426
                       2 Peaks
                                          196,997.20
13C12-HpCDD                    0.88-1.20
436-438        DC  NL   0:00     1.03         44.07
                       36:03     1.03      9,863.19
436-438              1 Peak                9,863.19
                                                          5,003.93
                                                            0.972-1.028
                                                                0.000
                                                      4,859.26  1.000 13C12-HpCDD 678  IS7
                                                     Octa-CDD and CDF Follows
 OCDF
 442-444

 442-444
               0.76-1.02
DC  NL   0:00  RO   4.74         53.73
        39:50      0.89    368,276.00
      1 Peak             368,276.00
                                                      173,289.00
        0.899-1.101
            0.000
194,987.00   1.006 OCDF
                                                                                                     AN
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                             Printed: 10:20 01/10/98
                                                                                                         .  1 Q 7
                                                                                                           JL w I

-------
  Page  No.
  01/10/98
Listing of 0980031B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK  Ratio Total.Area... Area.Peak. 1. .  Area.Peak.2. . Rel.RT Compound.Name..  10..  Flags.
OCDD
458-460

458-460
13C12-OCDD
470-472

470-472

DC ML 0:00
39:37
1 Peak
DC NL 0:00
39:36
1 Peak
0.
RO

0.
RO


.76
0
0
-1.02
.66
.85
76-1.02
1
0

.26
.87



117,
' 117,

13,
13,

19
123
123.
17.
394.
394.

.24
.00
. 00 "
46
37
37
0.

53,705.10 63,417.90
0.

6,222.20 7,172.17

899-1.101
0.
1.
996-
0.
1.

000
000 OCDD
1.004
000
000 13C12-OCDD


AN


IS8

  Column Description	   'Why' Code Description	  QC Log Desc.
  M_Z   -Nominal Ion Masa(es)
  ..RT. -Retention Time  (mm:38)
  Rnt.l -Ratio of M/M+2  Ions
  OK    -RO-Ratio Outside Limits
  Rel.RT-Relative Retention Time
  *•• End of Report
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
rila:U980031 tl-724 Acq: 6-JZS-1998 21:15:02 SC EI+ Voltaga SIX 70S Noiae: 1397054
303.9016 F:2 BSUB(256, 30, -3. 0) PXD(9, 5, 3,0 .101,5588216. 0,1. 00\,r,T) Ezp:NDB5OS
TXIAOGXX LASS Taxt: 165, 167, 168/225 TLIt44376A
1001
80.
60.

40.

20.

A2.45X9
A
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305.8987 T:2 SSUB(256, 30, -3.0) PXD(9,5, 3, 0 .10^, 9450624 .0,1. 00\,T,T) XxptXDSSUS
TRIASGLX LASS Text: 165, 167 ,168/225 TLIt44376A
1001
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Tila:O980031 tl-724 Acq: 6-JJOT-1998 21:15:02 SC XI+ Voltaga SIX 70S Noise: 2 85 80
315.9419 T:2 SSUS(256,30, -3 .0) PKD(9,5,3,0.10\,114320.0,1.00\,r,T) XzpsKDSSnS
TXIAXGLX LASS Text:165, 167, 168/225 TUt44376A
ion
80:
60:
40:
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' 22\00 23:00 24:00 25:00
Tila:U980031 tl-724 Acq: 6-JAN-1998 21:15:02 SC XI+ Voltaga SIX 70S Soiae:22559
317.9389 r:2 BSUS(256, 30, -3.0) PXD(9, 5, 3,0. 101,90236. 0,1.00\,r,T) Xxp:SDS5US
TXIASGLX LASS Tart; 165,167, 168/225 TLIt44376A
1001
ao:
60:
40:
20:
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Al . S5E8




1 L
22\00 	 23\00 24:00 ' ' ' ' 25\00
Tila:U980031 tl-724 Acq: S-JAN-19S8 21:15:02 SC EH- Voltage SIX 70S
330.9792 T>2 XxpiNDBSUS
TBIAHGLX LASS Tait:165, 167, 168/225 TLIt44376A
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90.
so:
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rilaiO980031 tl-724 Acq: 6 -JAN- 19 9 6 21:15:02 SC EH- Voltaga SIX 70S
375.8364 Ti2 Exp:NDB5US
TRIASGLX LASS Tart: 165, 167, 168/225 TLIt44376A
1001
80:
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-------
rile:09a0031 tl-724 Acq: 6-JXK-1998 21:15:02 GC XI+ Voltage SIS 703 Noiaa: 38573
319.8965 T:2 3SUB(256, 30, -3.0) ?XB(7,5,3,0.10\,154292.0,1.00\tr,X) XxptSDBSUS
TRIANGLE LABS Text: 165 ,167,168/225 TLIt44376A
10K
80.

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331.8936 Tt2 BSO3(256,30,-3.0) PKD(7,5r3,0.10\,317632.0,1.00\,r,T) Eip:mB5O3
TRIANGLE LABS Text: 165, 16 7, 168/225 TLH44376A
1001
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file:O980031 tl-724 Acq: 6-JJOT-1998 21:15:02 GC EH- Voltage SIS 70S IToiae: 13041
331.9368 7:2 BSO3(256,30,-3.0) PKO(7,5,3,0.10\,53164.0,1.
TRIANGLE LABS Text: 165 ,167,168/225 TLH44376A
1001
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333.9338 t:2 BSUB(2S6,30,-3.0) PXD( 7,5, 3, 0.10%, 39564. 0,1.
TRIANGLE LABS Text: 165 ,167,168/225 TLH44376A
1001
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40:
20:
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327.8847 T:2 BSUS(256,30,-3.0) PKD(7,5,3,0.10\,144012.0,1
TRIANGLE LABS Teit:165, 167, 168/225 TLH44376A
1001

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60:
40:
20:
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23:00 	 24:00 25:00
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' 25:00 Time
rile :U9 80031 tl-724 Acq: 6-0X11-1998 21:15:02 GC EH- Voltage SIS 70S
330.9792 T:2 ExptWDBSUS
TRIANGLE LABS Tarti 165, 167, 168/335 TLIt44376A
1001
80:
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40:
30:
ol


22.v52^_u_ 23:41 24:08 3&^0 35:08 25:30 ~J?$Z13 _n_T7>iS7
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-------
FileiU3B0031 tl-724 Acq: 6-J3OT-1998 21:15:02 SC EI+ Voltage 5X2 705 Noiaai3006
339.8597 Ts2 BSUB(256, 30, -3.0) PXD( 7,5, 3, 0.10%, J7074. 0,1. 00\,r,T) ZrpiKDBSUS
TSIASSLX LABS Text: 165 ,167 ,168/225 TLIt44376A
1001
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60.

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TSIASSLX LABS Taxt, 165, 167, 168/225 XLIt44376A
1001
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40:

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A1.93E9
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Voltage 5X2 705 Soiaes 9250
351.9000 T:2 BSUB(256, 30, -3.0) PXD(7,5, 3, 0.10%, J7000. 0,1. 00\,f,T) XxptSDBSUS
TSIASSLX LABS Text: 16 5 ,167, 168/225 TLIt44376A
1001
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50'
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TSIASSLX LABS Text! 165, 167, 168/225 TLIt44376A
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TRIANGLE LABS Text:165, 167, 168/225 TLIt44376A
1001
00:
50:
40:
70:
0:
26:57 97* T T 37:33 27t51 28t 06^8120





77:00 70:00
rilatU3B003i tl-724 Acq: 6-JAX-L99B 21,15,02 SC SI+
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TSIASSLX LABS Text: 165, 167, 16 8/225 TLIt44376A
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355.8546 Tt2 BSUB(256, 30, -3.0) PXD(5,5, 3,0.051,17184 .0,1. 00\,r,T) XxptHDBSUS
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r±lat0980031 #1-724 Acqt 6-J7UT-1998 21:15:02 SC EH- Voltage SIS 70S
357.8516 rt2 BSUB(256,30,-3.0) HD(5,5, 3,0.05\,16800.0,1.00\,r,T) Ex
TSIAHSLX LABS Textt 165 ,167 ,168/223 TLH44376A
1001
80.

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40.
20.

0

A6.12X8
A
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27:48 28:00 28:12 28.-24 28:J5 2S>48 25:00 25:12 25:24 25:J$ J
r±letU980031 #1-724 Acq: 6-JA1T-1998 21:15.02 SC EH- Voltage SIS 70S
367.8949 fi2 BSUB(256,30,-3.0) PXn(5,5,3,0.05\,11364 .0,1.00\,r,T) Xx
TSIANSLX LABS Text: 165 ,167 ,168/225 XLIt44376A
1001

80.
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A6 S7E7





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r±lo: OS 80031 #1-724 Acqs 6 -JAR- 199 8 21:15:02 SC Eli- Voltaga SIS 70S Ko±ae:3017
369.8919 Tt2 BSUB(256,30,-3.0) fXD(5,5, 3, 0.051,12068. 0,1.00\,T,T) KxpsSDBSVS
TSIAHSLX LABS Taxtsl65, 167, 168/325 TLIt44376A
1001
80.
60.
40.
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TileiO9B0031 #1-724 Acqt 6-JOT-1998 21:15>02 SC Eli- Voltage SIS 70S
330.9792 Tt2 XxptSDBSUS
TSIAHSLX LABS Tmxtt 165, 167, 168/335 XLIt44376A
1001
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28:05 3Siv2__-A»3fl'*'1 28:58 ^—^^\8








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-------
rHa:O980031  H-384  Acqt  6-JAN-1998 21:15:02 SC EI+ Voltage SIS 70S Noiae,1378101
373.8208  ri3  BSUB(256,30,-3.0)  PXD(7,S,3,0.10\,5512404.0t1.00\rrfT) Zrp-.HDJSSUS
TSIASGLX  LASS  Text: 165,167,168/225  OIt44376A
1001
80:
50:
40:
20.
 o:
                                    A3.1919
      A1.09X9
                                                       Al. 03X9
                                                                                 A3;oixa
     31,00  31,12 31,24  31,36  31,48 32tOO 32,12 32,24  32,36 32,48 33,00 33,12  33,24 33,36 33:48
r±Ie:O980031  tl-384 Aoq:  6-JAS-199m 21,15,02 CC XI+ Voltage SIS 70S Soiaut 1501133
375.8178 T,3  BSUB(256,30,-3.0)  PKD(7,S,3,0.10\,6004532.0,1.00\,r,T) XzpiXDBSUS
TSIASSLX LABS  Textt!65,167,168/235  SLIt44376A
 1001

  30:

  50:

  40:
  20.
           A1.95S9
AS. 64X8
                              A1.72X9
                                                AS.27X8
                    A2.36X8
                                                                                 A2.26Z8
     31:00  31,12 31,24 31:36  31,48 32,00 32:12 32:24 32:36  32:48 33:00 33:12  33:24 33:36 33:48
T±leiO980031 tl-384 Acqs  6-J3UT-1998 21,15,02  SC XI+  Voltage  SIS  70S Noise,28701
383^8639 Tt3 3SUS(256,30,-3.0)  PKD(7,5,3,0.10\,114804.0,1.00\,r,T)  ExptlWBSUS
TSZAHSLX LABS   Text: 165,167,168/225  XLH44376A
100\                                  A5.44E7        AS.30X7

  ao:
  50:

  40:
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    A3.15E6
    31:00  31,12 31:24 31:36  31:48  32:00 32,12 32,34 32:36  32:48 33:00 33:12  33:24  33:36 33:48
r±lo:O980031 tl-384 Acqi  6-JXN-L998 21:15:02  SC EH-  Voltaye  313  70S Noise121784
385.8610 r,3 BSUB(256,30,-3.0) PXD( 7,5, 3, 0.10\, 87136. 0,1. 00\er,T)  Elp:NDB5U3
TSIANGZE LABS   Text.-165,167,168/225 XLIt44376A
J001                                AB.97X7           A9.60E7
 80:
 50:
 40:
 201
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                                                                        A7.68X7
    31:00  31:12 31:24 31:36 31:48  32:00 32:12 32:24 32:36  32:48 33:00 33:12  33:24  33:36 33:48
ril«iO980031 tl-384 Acq: 6-J7OT-1998 21:15:02 SC XI+ Voltage  SIS  70S
392.9760 F,3 XiptNDBSVS
TSIAHGLX LABS   Text:165,167,168/225  TLIt44376A
 80:
 50:
 40:
 20:
  o:
                  31:26 31,38 31:4913:05
                                                                                               6.9X8

                                                                                              .5.6X8

                                                                                              -4.2X8

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                                                                                                  Time
                                                                                                   5.6X8

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                                                                                                   .2.2X8

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                                                                                                     0.0X0
                                                                                                        Time
                                                                                    33:32
                                                                                              -3.3S7

                                                                                              .2.6X7

                                                                                              .2.0X7

                                                                                              J..3S7

                                                                                              .6.6X6
    31:00  31:12  31:24 31:36 31:48  32:00  32:12 32:24'32:36' 32:48'JJioO'33:12'33:24'33:36 33,48
rilo:O980031 tl-384 Acqi 6-JJOT-1998 21s 15:02 SC XI+ Voltage SIS  70S
445.7555 Tt3 XxpiUDBSUS
XSIASSLX LABS  Tert: 165,167,168/225  TLH44376A
                                                                                               o.oeo
                                                                                                  Hae
1001

 80:

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                                                      32135
                               32:03
    31:00 31:12' 31:24' 31:36 31:48 32:00  32:12' 32:24 ' 32', 36' 32':4a' jjioo' 33:12' 33':24 ' 33: J6 ' 33:48
                                                                                                       203

-------
 r±J.a:Uyuo031 tl-384 Acqt 6-JAN-iyHB J±:±5tUJ SC BI+ voltage SIS 703 Noiae:11565J
 389.3156 Ti3 3303(256,30,-3.0) PXS(7,5,3,0.10\,462612.0,1.00\,r,T) EzpiHDBSUS
 TSIAOSLX LA33  Texts 165,167,168/335  TLIt44376A
 1001                     A8.09X8
  80.

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          31:36    31:48   33:00    32:13   33:24   32:36   32,48    33:00   33:13
rile:O980031 tl-384 Acqi  6-JAJT-1998 31:15:03  SC tt+  Voltage SIS  70S Koine:20215
401.8558 T:3 BSUB(256,30, -3.0) tXD(7,5,3,0.10\,80860.0,1.00\,T,T)  Xxp:SDBSUS
TSIANSLE IA3S  Text: 165,167,168/335   TLIt44376A
100*                                                                    A8.50E7
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       A1.55X8

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          31136   31:48    32:00    32:12   32:24   33:36    32:48   33:00   33:12
              tl-384 Acq:  6-JJOT-1998 21:15:02 SC XH- Voltage SIS 70S Boiaot378539
391.8137  T:3  BSUB(356,30,-3.0) PXD(7,5,3,0.10\,1114156.0,1.00\fT,T) Xxp:«DB5US
TSIASSLX  LABS  Text: 165,167,168/325  TLH44376A
1001                     A6.62X8
  80.

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                                                                                    33:24   33 36  Tla<
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                                                          A6.84E7
         '31:36  ' '3l':48   32:00   33:12    32:24   32:36   32:48    33:00   33:12
rila:U980031 tl-384 Acq: 6-JAX-1998 21:15:02 SC EI+ Voltage SIS  70S Noiae:9255
403.8529 Ts3 BSVB(256,30, -3.0) PXD(7,5,3,0.10\,37020.0,1.00\,T,T) Xxp:KDB5US
XSIASSLX LABS  Text: 165,167,168/335  TLH44376A
J004                                                                   A6.36E7
                                                                                   33:34    33.:
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                                                          AS.50X7
         31:36    31:48   32:00   32:12    32:24    32:36   32:48    33:00
Tile:O980031 tl-384 Actji 6-JAB-1998 21:15:02 SC XH- Voltage SIS 70S
392.9760 T:3 XxptODBSUS
TSIAHSLX LABS  Text: 165,167,168/225  TLH44376A
                                                                           33:12   33:24
                                                                                            33  36
601

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                                                                                               .0.0X0
                                                                                    33:24    33 36 Timt
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                                                                                               16.6X6
                                                                                                     .204

-------
 rdJ.a,O980031 #1-545 Acq:  6-JAK-1998 21:15:02 SC SI+ Voltage SIS 70S Noise,28302
 407.7818 T:4 BSUB(2S6,30, -3.0) PKD(7,5,3,0.10\,113208.0,1.00\,f,T) XxpiNDBSUS
 TSIAHSLX LASS  Text: 165,167,168/225  TLIM4376A
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                                                                           A3.87X8
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         35:00    35,12    35,34    35,36    35t48    36:00    36,12   36,24    36:36
File,0980031 tl-545 Acq:  6-J7OT-1998 21tl5t02 SC XI* Voltage SIS 703 IToiae: 36788
409.7789 T:4 BSUB(256,30,-3.0) PXD(7,3,3,0.101,147152.0,1.00\rT,T)  SxptKDBSUS
TSIAaSZX LASS   Texts 165,167,168/225  TLH44376A
1001    A2.S3X9
                                                                                       36,48
                                                                                                37:00
       0.0X0
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        35,00    35,13    35', 34    35,36   35,48    36', 00   36:12    36', 34    36:36    36:48
nj.e:0980031 tl-545 Acq:  6-JXS-1998 21:15,02 SC XH- Voltage SIS 70S Noiee:65675
417.8253 f:4 BSUB(256,30, -3.0)  tXD(7,5,3,0.10\r262700.0,1.00\,T,T)
TSIAHSLX LABS  Text: 165,167,168/225  XLIt44376A
1001    A3.36Z7
                                                                                                    r o-or.o
                                                                                                37:00    T±ae
  00:

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        35,00    35:12    35:24    35:36    35:48    36:00   36:12    36:24    36:36
rilei0980031 tl-545 Acq:  6-JZJT-1998  21:15:02 GC ZI+ Voltage SIS  70S  Noiae:34731
419.8220 T:4 BSUB(256,30,-3.0)  PKD(7,5,3,0.10\,98924.0,1.00\,f,T)  Xxp:lO>S5US
TSIANGLX LABS  Text: 165,167,168/225   TLH44376A
1001    A7.47X7
                                                                          AS.62X7
       8.8X6

      .7.0X6

      .5.3X6

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        JS.-00    35:12    35:24    35:36    35:48    36:00    36:12    36:24
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430.9729 T:4 Eip,NI3B5O3
TSIANGLX LABS  Text: 165,167,168/225   TLH44376A
                                                                              36,36
                                                                                       36,48
                                                                                               37:00
                                                                                                        Time
1001

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 40:

 20:

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                                                              36:14
                                                                                  36:43
36:58  3.3X7

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        35,00    35:12    35:24    35:36    35:48    36:00    36:12    36:24
rile,0380031 tl-545 Acq:  6-JAN-IS98 21:15:02 SC XI + Voltage SIS 70S
479.7165 F:4 Kxp:NDB5OS
TSIAHSLX LABS  Text: 165,167,168/225  XLIt44376A
1001
                                                                              36,36
                                                                                      36:48
      tQ.OfO
 37:00    MJM
        35:00
                 35:12
                         35:24
                                  35,36
                                           35:48
                                                   36:00
                                                            36:12
                                                                     36:24
                                                                              36:36
                                                                                      36:48
                                                                                                    ic.oro
                                                                                               37', 00    TlMt
                                                                                                     205

-------
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433.7766 T>4  BSU3(256,30,-3.0) PKD(7,5,3,0.10\,85864.0,1.00\,T,T)  SxpiXDBSUS
TB.IANGLX LASS Texts 165,167,168/335  TLH44376A
 1001
                                                            A4.92X8
                                                                                                -1.3X8


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425.7737 Ti4 3SV*(256,30, -3.0)  PXD(7,5,3,0.10\,94264.0,1.00\,T,T) ExptXDBSVS
TRIANGLE LABS  Texts 165,167,168/335  TLH44376A
1001
      35:12 35:18  35:24 35:30  35:36 35:42  35:48  35:54 36:00  36:06 36:12 36:18  36:34  36:30
Tile:CTS80031 tl-545 Aexj:  6-JAR-1998 21:15:02 SC SI+ Voltage SIS 70S Noiset 11160
435.8169 T:4 BSUS(256, 30, -3.0) PKD(7, 5,3, 0.10\,44640.0,1.00\,r,T) XxptNDBSUS
TRIASGLX LASS  Texts 165,167,168/225  TLH44376A
1004                                                       AS. 00X7
 80.

 60.

 40.

 20.
                                                                                                1.3X7


                                                                                                .9.5X6


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                                                                                                0 . 0X0
      35:12 35:18  35:34 35:30  35:36 35:43  35:48  35:54 36:00 36:06  36:12 36:18  36:24 36:30
T±la:U980031 tl-545 Acqs 6-JAB-1998  21:15:02 SC XI+ Voltage SIX 70S Noise110875
437.8140 ts4 BSOB(356,30,-3.0) PXD(7,S,3,0.10\,43500.0,1.00\,T,T) Szp:SDB5US
TXXANSLE LABS  Text. 165,167,168/235  TLIt44376A
1004                                                       A4.86X7

 80.

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                                                                                                   Tine
                                                                                                  3X7
                                                                                                .0.0X0
      35:13 35:18  35-24 35:30  35:36 35:43  35:48  35:54 36':00 36:06  36:12 36:18  36:24 36:30     Tine
Tila:US80031 tl-545 Acq: 6-JAS-1998  21:15:02 SC EI+ Voltage SXS 70S
430.9729 t:4 XxptSDBSUS
TRIANGLE LASS  Tart: 165,167,168/225  TLH44376A
1004




 60.

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 20.

  0.
                                                                                   36:24
                                                                                               -.3.3X7

                                                                                               .1. 8X7
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     35:12  35:18 35:24 35:30  35:36  35:42 35:48  35:54  36:00 36:06  36:13 36:18  36:34 36:30
                                                                                                   Mae
                                                                                                       206

-------
rIlei09S6d3i'~fF-S45 Acqs S-JAX-1998 21: 15 t 02  SC XH- Voltfye  SIX  70S Noise: 67395
441.7438 Fi4  BSUB(256,30f -3.0) PXJ>(7rS,3,0.10\r269S80.0t1.00\,T,t) Xxf:ODB5VS
TXIAHGLX LABS  Text: 165 ,167 ,168/225   XLIf44376A
 30.
 801
 701
 601
 501
 401
 3ol
 201
 101
               '35:00         36:00         37:00         38:00        39:00         40:00
rile:O9a0031  fl-545 Acqi  6-JAN-1998 21:15:02 SC XI* Voltage SIX 70S IToiaet 14216
443.7399 ft4  BSVB(256,30r-3.0) tXD(7,5r3,0.10\r56864.0,1.00\,r,T) XxptXDBSUS
TSIASGLX LABS Text:165,167,168/225  TLH44376A
100*                                                                            A1.95X9
 90.
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 601
 501
 401
 301
 201
 101
  01  _________
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               35-00         36:00         37:00
rilotU980031  #1-545 Actj: 6-JMT-199B 21:15:03 SC
430.9729 F:4  ExptXDSSUS
TSIANSLS LABS Text: 165,167,168/225  TLH44376A
100*           35:0135:25                 36:58
          34 -Jfl
 90l
 801
 701
 601
 501
 401
 301
 101
  0
                                                                      39OQ
                                                                                    40:00
                                                                                                   41:00 Time
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                                                                                                         Time
                                                 ZI+ Voltayo SIX 703
                                                    37:37
                                                    ~-W-
                                                                  38:41
                                                                                            *0t34


               35:00         36:00         37:00
FileiO980031  tl-545 Actjt  6-J3UT-1998 21:15:02 GC
513.6775 r:4  KxpiJWBSVS
TXIAXGLX LABS Text: 165,167,168/225  XLH44376A
               35:00
-2.3S7
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                                                         38:00
                                                 SH- Voltags SIS 70S
                                                                      39:00
                                                                                    4000
                                                                                  390
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                                                           ^l^J^^^
                                                                                                  41:00  Time
-.6.2X5
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               J5«00
                             J5»00
                                           J7flO
                                                         38:00
                                                                      39:00
                                                                                    40:00
                                                                                                      0.0X0
                                                                                                  41:00  Time

-------
\H1*:B9B0031 tl-545 Acg.  <,-JAH-199B-SITlSiOS SC £f+ Voifcjg. Sit 703 iKiaS:4539
457.7377 f:4 3SUB(256, 30, -3. 0)  PKD(7,5,3,0.10\,iail6.0,1.00\,r,T)  XxpiSDBSUS
TSXAirSZZ LASS  Text: 165,167,168/225  TLIt44376A
1004                       A5J7X8
           39:30         39:36        39:42         39:48        39:54         40': 00
rila:0980031 #l-545 Acq:  6-JAIT-1998 21:15:02 GC XH-  Voltaye SIS  70S Boise:6865
459.7348 ft4 BSaB(3S6,30,-3.Q)  PXD(7,5,3,0.10\,27460.0,l.QO*,r,T) KxptSDBSUS
         LASS  Textiles,167,168/225  TZI944376A
10IA                      A6.J4K8
           39-30         39*36        39:42         39:48         39:54         40:00
TiletU9B0031 tl-545 Aeqt  6-J7W-1998  21:15:02  SC EJ+ Voltage SIS 70S Noiae:5807
469.7779 T:4 3SVB(256,30,-3.0) PKD(7,5,3,0.10\,2322B.O,1.00\,F,T) SxptXDBSaS
TXIA2tSLS LABS  Tart: 165,167,168/225   -SLH44376A
100\                     A6.J2E7
           39:30         39:36        39:42         39:48         39:54         40:00
TiletU98Q031 tl-545 Actj:  6-JAN-1998 21:15:02 SC EI+ Voltage SIS 70S No±ae:4618
471.7750 T:4 BSV3(256,30,-3.0) PKD(7,5,3, 0.10%, 18472.0,1.00\,r,T) Sxp:BDBSVS
         LABS  Taxt:155,167,168/225  TLH4437SA
100\
           39:30         39:36        39:42         39:48         39:54
Tile, O9 80031 tl-545 Acqt  6-JZX-1998 21:15:02 SC XH- Voltage SIS 705
430.9729 r:4 Xxp:XDB5OS
TBIANSLK LASS  Text: 165,167,168/225  TLIt44376A
lOOi,    ,„.,„              39:37                  39i47_	
                                                                               40:00
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                                                                                                      203

-------
                                                                                 en
                                                                                 o
Peak Locate Examination: 6-JAN-1998:21:14 File:U980031
      Experiment:NDB5US Function:2 Reference:PFK

-------
                                                                                                       CD
File:U980031 #lj724 Acq:  6-JAN-1998  21:15:02 GC EI+ Voltage SIR 70S
119.8965 F:2 ExprNDBSUS
Jample Textr165^167,168/225   TLI#44376A File TextrTRIANGLE LABORATORIES, INC.
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321.8936 F:2 Exp:NDB5US
Sample Text : 165,; 167 , 168/225  TLI#44376A File Text rTRIANGLE LABORATORIES, INC.
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331.9368 F:2 ExprNDBSUS
Sample Text:165;167,166/225   TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%            :    25j09
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-------
 ile:U980031 #1-724 Acq:  6-JAN-1998  21:15:02 GC EI+ Voltage  SIR  70S
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Sample Text:165,167,168/225  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
100%
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341.8567 F:2  Exp:NDB5US
Sample Text : 165, 167, 168/225   TLI#44376A File  Text : TRIANGLE LABORATORIES,  INC.
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File:U980031  #1-724  Acq:  6-JAN-1998 21:15:02 GC EI+ Voltage  SIR 70S
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                                                                                                       Csl
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100%            !                          A2.JB3E8

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383.8639 F:3  Exp:NDB5US
Sample Text:165,167,168/225   TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
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-------
TLI Project      44376A
Client Sample:   165,167,168/225
            Method 23 TCDD/TCDF Analysis (DB-225)
           -  : -                 Analysis File:   P980099
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-14ACD Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: P980094
DB-225 Analyst: JM

Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:

SPC2NF04
PF22206
P980092
n/a
n/a
n/a



                                          Bt
                    EMPC-
                     Ratfo
                                                                           RT
                Flags
2,3,7,8-TCDF
                              13.4
                                    0.75
                              23:06
                                                                           RT     Ftegsr
"C12-2^,7,8-TCDF
3.2
79.8
                                                     40%-130%
0.78
23:06
 Recovery Standard
                                   ftetto
                               RT
                                                                                  Flags
                                                                   0.82
                                             21:55
                      Data Reviewer
                                01/09/98
                                         Page 1 of 1
                                             CNF.PSR .2.01. LARS 6. lOOtl
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                          Printed: 10:1601/09/98
                                                     <-. : o
                                                     t, j. u

-------
                        Initial
                                    . .Date.
  Data Review By:
        -111'
Calculated Noise Area:
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
                       1.00
  Page No.
  01/07/98

  Compound/
  TCDP
  304-306
Listing of P980099B.dbf
 304-306

 13C12-TCDP
 316-318
Matched GC Peaks '/Ratio
Omit Why . .RT. OK Ratio Total. Area
0.65-0.89
DC ML 0:00 0.67 8
DC WL 18
18
18:
:14
:28
:45
18:55
19:00
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
20:
21:
21:
21:
21:
21:
21:
22:
22:
22:
22:
22:
23:
23:
23:
23:
23:
24:
24:
25:
DC WH 25:
:07
28
36
44
54
01
10
20
28
38
47
10
23
28
37
43
52
06
21
31
40
59
06
19
36
44
56
15
31
16
43
0.77
0.80
RO 1.31
0.71
RO 1.07
0.83
0.75
0.76
0.76
0.77
0.77
0.75
0.79
0.78
0.76
0.75
0.76
0.68
0.74
0.75
0.74
0.75
0.77
0.74
0.75
RO 0.59
0.75
0.75
0.76
0.75
0.76
0.65
0.80
0.75
0.78
0.86
34 Peaks

DC NL 0:
DC WL 20:
DC WL 20:

00
08.
33
0.65-0.89
RO 1.21
0.74
0.66

29
3,686
/Ret; Tine " 	 " " •" " ~ "" 	 ~
. .. Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound.
0.792-1.101
.81 0.000
.25
.03
91.24
60.27
76.38
222.15
4,
4,
7,
3,

3,
8,
4,
13,
4,
26,


6,
1,
5,
5,
1,
7,

5,
3,
6,
7,
6,


4,


148,
594.42
539.08
964.10
642.65
359.
809.
034.
316.
396.
468.
200.
39.
34.
116.
098.
972.
963.
300.
070.
41.
755.
940.
400.
404.
682.
32.
15.
166.
789.
42.
287.
,52
43
,10
42
14
25
80
69
97
07
71
88
45
70
54
95
54
87
09
69
69
54
90
02
63
39
91


1,638.93

2,
67.48
25.
46.
101.
1,975.
1,959.
3,445.
1,583.
156.
1,636.
3,547.
1,891.
5,763.
1,910.
11,316.
16.
14.
2,623.
467.
2,558.
2,594.
554.
3,034.
18.
2,463.
1,689.
2,762.
3,163.
2,875.
12.
7.
1,782.
345.


,09
,37
,01
87
16
30
78
55
29
26
99
78
85
00
04
86
33
19
71
36
23
65
25
23
95
06
73
23
85
07
76
48




047.10
51.55
35.18


2,
2,
4,
2,

2,
4,
2,
7,
2,
14,


3,

3,
3,

4,

3,
2,
3,
4,
3,


2,



43:
121.
618.
579.
518.
058.
202.
173.
486.
424.
632.
557.
884.
23.
20.
492.
631.
414.
369.
746.
035.
30.
292.
250.
638.
240.
807.
19.
8.
383.
444.


15
14
55
92
80
87
87
14
84
43
36
40
80
65
11
74
52
17
09
47
89
79
31
92
03
96
46
69
83
26
15


0.789
0.799
0 . 812
0.819
0.823
0.828
0.843
0.848
0.854
0.861
0.867
0.873
0.880
0.886
0.893
0.900
0.916
0.926
0.929
0.936
0.940
0.947
0.957
0.968
0.975
0.981
0.995
1.000 2378-TCDF
1.009
1.022
1.027
1.036
1.050
1.061
1.094
1.113

0.957-1.043



3.
34.
48.
84
12
54















0.000
0.872
0.890
                                                                                                      E

                                                                                                      E

                                                                                                      E
                                                                                                 AN
Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 04:57 01707/98
                                                                               214

-------
  Page No.
  01/07/98
Listing of P980099B.dbf
Hatched GC Peaks / Hatio / Ret. Tiae
  Compound/
  M_Z	 QC.Log Omit why . .RT.  OK Ratio Total.Area...  Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID..
                                                                                  Flags.
  316-318
  13C12-TCDD
  332-334
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC

WL
WL
WL"
WL
WL
WL


WH
WH
WH
WH
WH
WH
4
20
21
21
21
21
22
22
22
23
24
24:
24:
24:
25:
25:
25:
:43
:33
:43
:48
:02
:24
:06
:02
:18
:28
:50
:10
:34
45
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO

0.98
0.77
0.65
1.07
0.86
0.90
0.29
0.75
0
0
3
2
0
0
0
0
.78
-94
.20
.21
.99
.33
.51
.72
Peaks
9.
31.
17.
2.
36.
2.
5.
9.
1,134.
25.
20
58
56
00
41
21
01 2.18
81 4.19
89 495.74
45 13.45
1.93
1.
12.
8.
21.
8.
1.175.
96
81
48
63
09
16
0.897
0.923
0
0
0
0
7.52 0
5.62 0
639.15 1
14 . 38 1
1
1
. 1
1
1
1

.933
.940
.944
.954
.964
.970
.000 13C12-2378-TCDF ISO
.040
.052
.059
.075
.089
.107
.115

  332-334

DC

DC

DC
DC



DC

DC
DC
DC
DC
DC


NL

SN

SN
SN



SN

SN
WH
WH
WH
WH
6

0:
20:
20:
20:
20:
21:
21:
21:
21:
22:
22:
22:
23:
24:
24:
24:

00
18
24
30
55
16
37
46
55
24
41
59
44
14
28
38
0.
RO

RO
RO
RO


RO

RO

RO
RO
RO
RO

..... K
65-0.89
1.
0.
1.
1.
0.
0.
0.
0.
0.
5.
0.
1.
0.
0.
0.
0.
14
72
00
51
34
75
79
58
82
00
71
31
43
58
38
74
Peaks
                                        Above:  TCDF / TCDD Follows
                                                 2.23
                                                 3.26
                                                 0.90
                                                 2.78
                                                 0.55
                                                 2.83
                                               745.90
                                                 5.20
                                             1, 024.97
                                                 0.32
                                                10.22
                                                 0.62
                                                 7.70
                                                 3.86
                                                 4.21
                                                 2.72
                                             1,792.33
                                    1.36

                                    2.37
                                  329.78
                                    2.26
                                  462.03

                                    4.24


1.

1.


416.
3.
562.

5.





0.908-1.092
0.000
.90 0.939
0.944
.57 0.948
0.968
0.984
12 1.000 13C12-2378-TCDD IS1
91 1.007
94 1.014 13C12-1234-TCDD RSI
1.036
98 1.049
1.063
1.098
1.121
1.132
1.140
 Column Description. . .	   'Why*  Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time (mm:as)
 Rat.l -Ratio of M/M+2 Ions
 OK    -R0-Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report *••
      WL-Below Retention Time Window
      WH-Above Retention Time Window
      SM-Below Signal to Noise Level
      
-------
 fl±a:P980099 ii-323 Acq:7-JAH
 303.9016 SzpiDB225
 XBIABCLX LASS  Text: 165,167,168/225  TLII44376A
 100*
                                      23,36
J sn- voltage SIS /of
     22:36 22:49  23:00 23s12  23:24 23:36 23:48 24:00  24:12 24:24  24:36 24:48  25:00 25:12 25:24
T±la:P980099 tl-923 Acq:7-J3Ot-98 04:09:43 XH- Voltage SIS  70P
315.9419 Xxp:DB225
IRIAWSLX LABS  Text: 16'5,167,168/225 TLH44376A
1001
 95.
 90.
 as.
 80.
 7S.
 70.
 65.
 60.
 55:
 50^
 45:
 40:
 35.
 30.
 25.
 20.
 i5:
 101
                     23:06
                                                            _I.4E6
                                                            '•.1.3X6
                                                            '-.1.2E6
                                                            '•.1.216
                                                            '.1.1E6
                                                            ':!. OE6
                                                            .9. 6E5
                                                            .8.9X5
                                                            '-.8.2X5
                                                            .7.5X5
                                                            .6.9X5
                                                            .6.2X5
                                                            .5.5X5
                                                            .4.8X5
                                                            .4.1X5
                                                            .3.4X5
                                                            .2. 7X5
                                                            .2.1X5
                                                            '.1. 4X5
                                                            '.6.9X4
    22:36 22:48 23:00 23:12  23:24  23,36  23:48 24:00 24:12  24:24 24:36
                                                            .0.0X0
                                  24:48  25:00 25': 12  25:24     Tine

-------
 rid.esf 980099 tl-323 Acqt 7-JMI-ya  vnuynj JSfr  vo±taye SIS  70P aoiae:1772
 303.3016 BSUB(256,30,-3.0) PXO(5,3,l,0.10\,7088.0,0.00\,r,e) Szp:DB225
 TSIAHSLS LASS  Texts 165,167,168/325 TLIt44376A
 lOOi

  80.

  SO.

  40.

  SOI

   o:
      Jl
                   A3.45X7
                                          A2.62X7    *3-03X7      A3.16X7
                                                                             Al. 78X7
              A
           19:00       20iOO        21:00       23tOO        23iOO       24iOO
riIe:P980099 tl-923 Acq:7-J3UT-98 04>09t43 SX+ Voltage SIS 70P So±me:2637
305.8987 3303(256,30r-3.0) PXD(5,3,l,0.10\,10S4a.O,0.00\,T,T) XxpiDB225
TSIAWSLX LA33  Text: 165,167,168/225 XLII44376A
100«                                AJ..49X8
  ao:

  60.

  40.

  20.

   0.
                                                                                    25100
                   A4.52E7
                                          A3.49K7    A4.04S7
                                                  .37f!
A4.24E7
                                                                             A2.38E7
                                                                                A
          19:00        20:00       21:00        22:00        23:00        24:00
rilaiP980099  tl-923  Acqs7-JJOr-98 04:09:43 fH- Voltage SIS 70P lfo±Ba:1316
315.9419 BSOB(256,30,-3.0)  PXD(5,3,1,0.10\,5264.0,0.00\,T,T) Zxp:DB225
TSIAHSZX LABS Text:165,167,168/225 TLH44376A
IOCS                                                        A4.96E6
 80.

 60.

 40.

 20.
                                                                                    25:00
          19:00        20:00       21:00       22:00       23:00        24:00
r±laiP980099 tl-923 Acq:7-JXa-98 04:09:43 XH- Voltage SIS 70P Ooiae:1087
317.9389 BSUB(256,30,-3.0)  PKD(S,3,1,0.10\,434B.0,0.00\,T,F)  Xxp:DB225
  IASGLX LABS  Text: 165,167,168/225 XLIt44376A
1001                                                       A6.39E6
 80.

 60.

 40.

 20.
                                                                                    25:00
                            A2.92E5
                               A
          19:00        20:00       21:00       22:00       23:00
rile:P980099 tl-923 Actj: 7-JKK-98 04:09:43 XH- Voltage SIS 70P
375.8364 Xxp:DB225
XXXAXGLZ LABS  Text: 165,167,168/225 XLIt44376A
1001                                                        23,03
                                                                       24:00
                                                                                    25:00
_1. 8X7

.1.4X7

.1.1X7

,7.0X6

.3.5X6

 0.0X0
  .3X7

  .9X7

  .4X7

  .3X6

  .6X6

  .0X0
    Time



  ,4X6

  .1X6

   2X5

   5£5

   7X5

   0X0
    Tine



   7X6

   4X6

   0X6

   9X5

  .4X5

  .0X0
    Time
          19:00
                      20:00
                                   21:00
                                               22100
                                                           23:00
                                                                       24:00
                                                                                    25:00
                                                                                                      r. 1 n
                                                                                                      (- JL t

-------
fllesP9B0099 #1-923 Acqs 7-JXN-9B 04:09:4J EX+ Voltage SIS 7OP Noiae:69J
319.8965 BSOB(356,30,-3.0) PXS(5,3,l,0.10\,3773.0,0.00\rr,T) S*p:BB335
TSIAHSLX LABS Text: 165, 167 ,168/335 TLI944376A
1001
80.

60.
40.
20.
0.

|
A2.27X7


1 1 A4.43X6 A7.84X6
11 11 A1-1-**^ A »/\
/ V / V l\ A 7\ A _ ^VV V~ ^ ^^_
	 20»00' 2lioO '33:00 	 33:00 	 24.-00 	 35
-1.0X7
.8.3X6

.6.3X6
.4.1X6
^.1X6
0.0X0
00 T±ae
TUe:P980099 91-933 Acq:7-JAS-98 04,09:43 H+ Voltage SIS 70P So±aetl742
321.8936 BSUS(356,30,-3.0) PKD(5r 3,1,0. 10\,696e. 0,0. 00\,f,f) Xxp:DB335
TSIASSLX LABS Text: 165, 167, 168/335 XLH44376A
100J
80.

60.
401
301

0'
1
1
A3. 93X7
A


1 1 AS. 59X6 A9.8BX6
\\ \\ l^'f31^ A *_ ^-WV ^ __
	 30':00 	 .21:00 22:00 ' 23:00 	 24:00 25
-1.3X7
.1.1X7

.7.9X6
.5.3X6
.3.6X6

0.0X0
00 Time
Tile:P980099 tl-933 Acq:7-JAS-98 04:09:43 XH- Voltage SIS 70P Soiae:154S
337.8847 BSUB(256,30,-3.0) PXD(5,3,lr0.10\,6180 .0,0.00\,r,T) Xxp:DB225
TSIASSLX LABS Text: 165 ,167,168/335 XLIf44376A
100J
80.

60.
40.

201
0.
AS. 70X7

A3. 61X7


A1.46X7
(\
l\
	 20\00 ' ' ' 21:00 ' ' ' '22:00 ' ' ' ' 23\00 	 24:00 	 25
-1.6X7
'.1.3X7

.9.6X6
.6.4X6

.3.3X6
0.0X0
00 Tiae
r±letP980099 91-923 Acqt 7-JAB-9S 04:09:43 KH- Voltage SIS 70P Koine i 7 IS
331.9368 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,2873.0,0.00\,r,r) Xxp>DB335
TSIAlfSLX LABS Text: 165, 167, 168/225 TLX944376A
1001
80.

60.
40.
20.
0.
A4.63X6
A
A3. 30X6 [I



/I /I
20 1 00 21:00 22:00 23tOO 34:00 25
_1 . 3X6
_1 . 0X6

.7.6X5
.5.1X5
.3.5X5
0.0X0
00 Time
HJ.e:P980099 91-923 Aoji7-JJOT-9B 04 1 09:43 EH- Voltage SIS 70P Soiaet633
333.9338 BSUB(356f30r-3.0) PXD(S, 3,l,0.10\,2528.0rO.OO\rrrT) XxpiDBSSS
TSIASSLX LABS Textt 165, 167, 168/335 XLI944376A
1001
80.
60.
40.
30.
01
AS. 63X6
I
A
A4.16K6\\
I



l\ l\
	 30:00 21:00 22:00 	 3JiOO 24\00 25
.1.5X6
J..3X6
.9.1X5
.6.1X5
.3.0X5
0.0X0
00 Tiae























































213

-------
r±le:P980099 tl-923 Acq: 7-JAK-98 04:09:43 XI+ Voltage SIS 70P
303.9016 Xxp>DB225
TSIASSLX LASS Tuxt-,165, 167 , 168/225 TLIt44376A
100.
80.

60.

40.
20.
0.
21: 0

20:38
1
19( 44 11
19,2s! aoj\ao\\ ^TV2'0*"^1
A . ... . -.jJAi-l-A- -1\ A/1/ 1 A 	 --li--H-A---ll 	 A'A-f
j\_ j \j \j \j \^j\] v/* \j\ I \ /W/\/VA/I /vw
19:00 20(00 21(00 22(00 23(00
Fila,P980099 tl-923 Acqt7-J3UT-98 04(09:43 XH- Voltage SIS 70t
315.9419 Sxp:DB225
TSIASSLX LASS Texts 165, 167, 168/225 XLH44376A
ion
80.
60.
40.
20.


23 (Off
1




^ a°J.33 ^ 1 [

15)00 ' ' 20:00 21:00 22:00 ' 23:00
rile:P980099 tl-923 Acq:7-J3UT-98 04:09:43 XI+ Voltage SIS 70P
319.8965 Exp:DB225
TSIASSLX LABS Text:165, 167 , 168/225 TLH44376A
1001
80.

60:
40:
20:

o:
19; 17

19(51
1

20:30 21.-5S
It ft A n 21:16 A,
/I 1 \ A /vA A ^WV^ ^
15:00 20:00 21:00 ' ' 22:00 ' 23:00
f±lesP9 80099 tl-923 Acq:7-JJOT-98 04:09:43 XI+ Voltage SIS 70P
331.9368 Xxp:DB225
TSIASSLX LABS Text: 165 , 167, 168/225 TLIt44376A
1001
80:
60:
40:
20:
o:
21:55
1
1


n M
19:00 ' '.' 20:00 ' ' ' 21:00 ' ' ' 22(00 ' ' ' 23(00
TiletP980099 tl-923 Acq:7-JXH-98 04:09:43 XI* Voltage SIX 70P
292.9825 Xfp:DB225
TSIASSLX LABS Text: 165 , 167, 168/225 TLIt44376A
ion
80:
60:
40:
20:
o:
^1^57 19133 SOilO 30i5a^ 23il« 2J(00
^/^~~1-** | V**VJ1"^^^^V^* "'w" •^/O*/*^V' tJ^~~^**V*++1'** u *^^** ~^ ffv^J^tr^fV~^m





14:00 20:00 21:00 22(00 23(00
Tile i P9 80099 tl-923 Acqt7-JJOr-98 04:09:43 EH- Voltage SIS 70P
330.9792 XxpiDB225
TSIASSLX LABS Textt 165, 167, 168/225 TLH44376A
100]
80:
60:
40:
20:
o:








23,36
	 ^A''1 	 	 _.
/v
1 . 8X7
.1.4X7

'•.1.1X7

.7.0X6
.3.5X6 _
0.0X0
24:00 ' ' ' 25(00 ' ' Time



-.1.4X6






.1.1X6
.8.2X5
.5.5X5
.2.7X5


24\00 35\00 T±ae



_1 . Or7







'-.8.2X6

'-.6.2X6
'.4.1X6
.2.1X6

0.0X0
24(00 25:00 ' ' T±ae



_1 .'3JT5





':! . 0X6
'.7.7X5
.5.1X5
.2.6X5
0.0X0
'24:00 25:00 Tlao



23:35 24 {31 25:13
*rV*v~V1^^"^^'^1^ *fYV^*'^JY w^l**'*^1^^*





.7.8X6
.6.3X6
.4.7X6
.3.1X6
.1.6X6
0.0X0
24:00 25:00 Time



18(53 19:53 21(13 21:51 22:2722:54 23:32 24(0724(35 25:15 -6.6X6





19(00 20(00 21(00 22(00 23(00
* - y- -y v- -y v • T » » »•




.5.3X6
.4.0X6
.2.6X6
.1.3X6
0.0X0
24:00 25:00 Time
219

-------
tef, tass   232,3825     Peak top
Height  1,39 volts  Span   296 ppi
Systa file naie
Oka   fllenaie
Resolution
Group nuiber
Ionlatlon lode
Switching
Ref. lasses  292.9825,
A   292.9825
8   383.9816
C   385.8987
D   315.9419
E   317.9389
F   319.8965
6   321.8936
H   327.8847
I   338.9792
J
K
L
I
       1
     El*
 VOLTAGE
388.9781
338.9792
331.9368
333.9338
375.8364
Channel   I  338.9792    Peak top
Helcjit  1.84 volts  Spai  288 ppi
                                                          220

-------
 TLI Project:       44376A
 Client Sample:    177/182-184/209
                                                      Method 23 PCDD/PCDF Analysis (a)
                                                                    Analysis File:   U980032

Client rroject
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:

i_uip AiuHLLnun
M23TRAIN
194-59-15A
1.000
n/a
DB-5

i AWjyo
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst

12/17/97
12/29/97
01/06/98
n/a
U980026
B8

Spike File:
ICal:
ConCal:
% Moisture:
% Lipi±
% Solids:

SPMIT204
UF51058
U98002S
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1,2.3,7,8-PeCDD
l,Z3,4,7,8-HxCDD
1.23,6,7,8-HxCDD
1,23,7,8.9-HxCDD
1,2.3.4.6,7,8-HpCDD
1.2J,4.6,7.8.9-OCDD
Arctsigf
ND
ND
ND
ND
ND
0.02
0.06
PL"' - -< EMPC
0.004
0.006
0.007
0.006
0.006


« Ratio RT Flags



(
	
0.96 36:02 J
0.92 39:37 IB
2.3,7,8-TCDF
!A3,7,8-PeCDF
2,3,4,7,8-PeCDF
12,3,4,7,8-HxCDF
T.2J,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2^,7,8,9-HxCDF
l,2J,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2J,4,6,7,8.9-OCDF
EMPC
 0.01
 0.01
 0.03
 0.01
 0.02
 ND
 0.13
 ND
 0.11
                                                         0.03
                                              0.006

                                              0.01
                 1.43
                 1.36
                 1.37
                 1.11
                 1.11

                 1.04

                 0.87
28:34
29:16
32:01
32:08
32:37

35:00

39:49
B_
J_
J_
J_
J_
J_
rotate
Amt
^«
fftiraber?
DL
EMPC
F&3S
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD

Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
                                 0.01
                                 0.01
                                 0.02
                                 0.02

                                 0.05
                                 0.07
                                 0.11
                                 0.13
            1
            1
            1
            1

            3
            5
            5
            1
0.02
0.02

0.04

0.13
0.13

0.15
                                             Page 1 of2
                                                                                  MTT2.PSR»I.01. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                              Printed: 10:2001/10/98
                                                                                            *") 1 1
                                                                                            CC J.

-------
 TLI Project:      44376A
 Client Sample:   177/182-184/209
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980032

: internal SCmdards
13C,rZ3.7.8-TCDF
13C12-2J,7.8-TCDD
13C,rlA3.7,8-PeCDF
1JC,rl.2,3.7.8-PeCDD
13C,2-lA3.6,7,8-HxCDF
13C,2-lZ3,6,7,8-HxCDD
I3CirlZ3,4,6,7,8-HpCDF
13C,2-U.3.4,6,7,8-HpCDD
13Ca-U,3,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
i3C12-2,3.4.7,8-PeCDF
13Cirl,2,3,4,7,8-HxCDF
l3C,2-UJ,4,7,8-HxCDD
13C12-U,3.4.7,8,9-HpCDF
Surrogate Standards {Type A>
37CL,-2,3,7,8-TCDD
Alternate Standards {Type A>
I3C,2-li3.7.8,9-HxCDF
"C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
"C,rlA3,4-TCDD
13C,2-lA3,7,8,9-HxCDD

Amt. $0} -,
2.5
2.7
2.9
3.2
3.0
3.7
1.6
3.5
7.0
Ami. $tg)
3.8
3.7
3.6
3.8
Amt #»§}
3.3
1 Amt. $19}
3.1
3.1




^fffAr4vf ^%J JUJH
f\ : \.->\ v.
62
68
72
79
73
92
39
87
86
' ^/n ftttt
93
92
90
95
' , fatffH
82
%Rec
77
78
-



EG vfify A /•"¥ * ^ * *
,2 40%-130%
.1 40%-130%
.1 40%-130%
.7 40%-130%
.9 40%-130%
,1 40%-130%
.7 25%-130%
.4 25%-130%
.9 25%-130%
iovery
.9 40%- 130%
.5 40%-130%
.3 40%-130%
.1 40%-130%

.4
«very
7 40%-130%
0 40%-130%




,^^HD, :
0.76
0.81
1.49
1.50
0.50
1.21
0.35
1.05
0.86
Ratio
1.46
0.50
1.20
0.35
;

Ra«k>
0.51
0.48
Ratio
0.81
1.21

•••• •: KT •• FEaos
24:36 	
25:18 	
28:33 	
29:35 	
32:08 ; 	
32:48 	
35:00 RO 	
36:02 	
39:36 	
FIT Flags
29:14 	
32:01 	
32:43 	
36:32 RO 	
ITT Flags {
25:20 	
RT Flags
33:22 	
32:36 	
RT Flags
25:08
33:07 	

















                    Dara Reviewer.
            01/10/98
                                       Page 2 of 2
                         Mm.PSRvl.OI. LARS 6.10.08
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:20 01710/98
                                 222

-------
                        Initial
  Data Review By:
                                    . .Date.
                                              Calculated Noise Area:
                                                                    7.03
  The Total Area for  each peak with an ion abundance ratio outside
  ratio limits has been recalculated according  to method requirements.
Page' No. ~ ."1 ' • •-•• 'Listing"
01/10/98 Matched
Compound/
M_Z .... QC . Log Omit Why . . RT . OK
TCDF
304-306
K
D
K
K

A

D
M

304-306
13C12-TCDF
316-318




DC NL 0
22
D SN 22
23
23
23
24
24
D SN 24
24
25

:00
:36
:54
:18
:35
:53
:00
:13
:26
:38
:03
0

RO
RO
RO

RO


RO
RO
RO
"of" 098003237 dbf
GC Peaks / Ratio
Ratio Total. Area
.65
0
0
0
1
0
0
0
0
1
0
0
-0.89
.89
.30
.40
.04
.75
.64
.75
.89
.13
.63
.52
8 Peaks

DC NL 0
DC WL 23
24
24

:00
:34
:11
:36
25:02

25
:33
DC WH 25:39
316-318
TCDD
320-322
KN
KN
D








320-322
37C1-TCDD
328

0.
RO

RO

RO

RO
/ Ret. Time
. . . Area . Peak . 1 . . Area . Peak . 2 . .
Rel.RT Compound. Name. . ID.
. Flags.
0.867-1.079
29
50
50
74
62
81
103
.101
32
193
38
705
.06
.23 21.85
.96
.27 43.82
.85 26.96
.65 35.52
.40 44.40
.59 47.84
.66
.32 84.10
.20 16.62
.51
65-0.89
1
0
0
0
.70
.76
.50
.76 17
0.62
0
.85
5.93
4 Peaks

DC NL 0:
22:
23:
D SN 23 :
DC SN 24 :
DC SN 24 :
DC SN 24 :
DC SN 24 :
DC SN 25:
DC SN 25:
DC SN 26 :
DC SN 26 :

00
46
10
47
25
35
47
55
13
18
30
44
0.

RO

RO
RO
RO
RO
RO
RO
RO

RO
18
65-0.89
0.
0.
0.
0.
0.
4.
0.
3.
0.
0.
0.
0.
89
59
89
36
93
18
20
90
47
45
72
40
2 Peaks
16
413
85
,972
.80
.05
.95 37.39
.16 7,785.96
340.69 148.21
52.88 24.27
8.
.76

73.91

41.96
35.89
55.59
59.00
53.75

133.00
31.77

0
0
0
0
0
0
0
0
0
1
1

.000
.919
.931
.947
.959
.971
.976
.984
.993
.001 2378-TCDF AN
.018


J

J
J
J
J
J


J

0.959-1.041


75.43
10,186.20
238.69
28.61

0
0
0
1
1
1
1
.000
.958
.983
.000 13C12-2378-TCDF ISO
.018
.039
.043







,451.68

8.
58.
43.
3.
10.
7.
2.
1.
15.
15.
7.
6.
101.
13
94 25.64
05 20.22
08
12
98
39
75
63
91
78
97
99
0.895-1.047
0.000
43.35
22.83
0.900
0.916
J
J
0.940









0.
0.
0.
0.
0.
1.
1.
1.

965
972
980
985
997
000 2378 -TCDD AN
047
057










0.921-1.079
DC NL 0:
23:
00
57






5.
95.
73
45 95.45


0.
0.
000
947


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
                                                                                                      223

-------
01/10/98


Compound/
M_Z.... QC.Log Omit Why
                         Listing of O980032B.dbf
                         Matched GC Peaks / Ratio / Ret. Time
                         .RT. OK Ratio  Total.Area... Area.Peak.1. .  Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.

328
13C12-TCDD
332-334





332-334
PeCDF
340-342



D


M
D
D
H


D

340-342
13C12- PeCDF
352-354








25
25
25
:20
:50
:58
26:01
26:03
26:09
26:09
26:21
26:38
26:46
DC SN 26:51
11 Peaks
0
DC NL 0
24
25
25
25
25
:00 RO
:08
:08
12,297.60
52.49
35.38
12
.65-0.89
1
.86
0.34
0.81 19
:18 0.81 14
:38
:50 RO
0.
.76
4.90
5 Peaks

DC NL 0
26
27
27
D SN 27
28:
28:
28:
D SN 28:
D SN 28:
29:
29:
DC SN 29:
D SN 30:
DC SN 30 :
1
:00 RO
:34
:34 RO
142 RO
:52 RO
:10
;17
:34
42 RO
:51
:16
24 RO
43 RO
14 RO
34 RO
35
.32-1.78
0.
1.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
2.
0.
0.
90
73
45
88
54
33
66
43
28
65
36
17
88
72
35
8 Peaks

DC NL 0:
27:
27:
27:
DC SN 28 :
28:
28:
28:
29:
1.
00 RO
15 RO
29 RO
42
01 RO
10
33
50 RO
14
32-
0.
0.
0.
1.
0.
1.
1.
1.
1.
1.78
88
61
23
55
38
56
49 16,
27
46 14,
12.38
31.01
56.59
23.43
48.49
27.17
8.90
6.28
,688.89
16.55
85.01
,596.91
,912.62
680.28
48.82
,323.64

11.80
59.20
24.97
133.39
32.33
55.91
83.18
49. 90
37.89
47.95
59.70
68.62
11.04
16.01
3.09
534.87
12,297
52
35
12
31
56
23
48
27
8

38
8,779
6,690
294
135
.60
.49
.38
.38
.01
.59
.43
.49
.17
.90

.69
.31
.82
.57
.18



46
10,817
8,221
385
27

0.

.32
.60
.80
.71
.58
1.001 37C1-TCDD CLS
1.021
1.026
1.028
1.030
1.034
1.034
1.042
1.053
1.058
1.061
921-1.079
0.000
0.954
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.021











37,
15,
81.

31.
51.
29.


34.
41.





.55
.18
.08

,91
91
40


40
71





21.
33.
92.

24.
31.
20.


25.
35.




0.

.65
.93
,01

,00
27
50


30
56




925-1.065
0.000
0.931
0.966
0.970
0.976
0.987
0.991
1.001 12378-PeCDF AN
1.005
1.011
1.025 23478-PeCDF AN
1.030
1.041
1.059
1.071



J
J
J

J
J
J


J
J




0.860-1.140
18.05
18.48
18 . 85
585.52
10.66
41.54
135.84
603.20
633.01

11.
11.
356.

25.
9,645.
366.
8,687.

23
46
22

32
30
65
17

18.
48.
229.

16.
6,490.
287.
5,945.

42
99
30

22
54
96
84
0.000
0.954
0.963
0.970
0.981
0.987
1.000 13C12-PeCDF 123 IS2
1.010
1.024 13C12- PeCDF 234 SOR1









Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                       Printed: 10:20 01710/98
                                                                                                    224

-------
  Page No.
  01/10/98
Listing of  0980032B.dbf
Matched GC  Peaks / Ratio / Ret.  Time
  Compound/
  M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area. .. Area.Peak.1..  Area.Peak.2..  Rel.RT  Compound.Name..  ID..  Flags.
  352-354
  PeCDD
  356-358
  356-358

  13C12-PeCDD
  368-370
  368-370
 HxCDF
 374-376
         M
         M

 374-376

 13C12-HXCDF
 384-386
                         30:13  RO  1.02         46.56         28.30        27.85  1.058
                       -30:20  R0._0.38    	17..87  	..__10...8.6	28..53_.1.062_


DC

DC

DC
D
DC
DC
DC
DC


DC
DC
DC

DC




DC


DC







DC







9 Peaks

NL 0:00
27:48
SN 28 : 26
28:31
SN 28:40
SN 28:50
SN 29:07
SN 29:25
SN 29:38
SN 29:45
2 Peaks

NL 0:00
SN 27:44
SN 27 : 54
28:30
SN 28:38
29:35
29:43
30:04
30:15
SN 30:31
5 Peaks

NL 0:00
31:03
31:12
32:01
32:08
32:37
5 Peaks

NL 0:00
31:03
31:11
32:01
32:08
32:36
33:04
33:22
32,100.87
1
RO
RO


RO
RO
RO

RO
RO

1.
RO
RO
RO
RO
RO


RO
RO
RO
.32-1.78
0.45
0.75
1.76
1.69
0.23
1.10
0.34
1.36
1.12
0.89

32-1.78
0.56
0.53
0.45
0.92
1.28
1.50
1.61
1.09
3.47
2.01
3
32
6
43
4
23
4
11
12
8
75

3
3
4
26
17
9,216
1,462
79
26
7.
.41
.41
.04
.44
.54
.18
.69
.87
.54
.54
.85

.27
.75
.39
.49
.90
.67
.72
.81
.75
.68
10,812.44
1.
RO






0.
RO





RO

05-1.43
0.87
1.28
1.27
1.37
1.11
1.11

43-0.59
0.72
0.59
0.47
0.50
0.50
0.48
1.91
0.51
19.
44 .
107.
114.
54.
60.
380.
73
70
10
40
io
05
35



19

27











16

5,530
902
48
36


.70

.27











.10

.36
.71
.51
.35


26

16











17

3,686
560
44
10

0.

935-1.022
0.000
.40 0.940

.17







0.



.51

.31
.01
.54
.49

0.961
0.964
0.969
0.975
0.984
0.994
1.002
1.006

865-1.135
0.000
0.937
0.943
0.963
0.968
1.000 13C12- PeCDD 123 IS3
1.005
1.016
1.023
1.032


J

J





















25.
59.
66.
28.
31.


07
91
10
40
64


19.
47.
48.
25.
28.

0.962-1.047

63
19
30
70
41

0.000
0.966
0.971
0.996 123478-HxCDF AN
1.000 123678-HxCDF AN
1.015 234678-HxCDF AN


J
J
J
J
J

0.876-1.124
17.
88.
161.
10,277.
13,473.
12,827.
25.
9,854.
52
88
16
07
70
57
01
68

33.
51.
3,447.
4,493.
4,150.
31.
3,329.

04
22
68
05
67
70
97

55.
109.
6,829.
8,980.
8, 676.
16.
6,524.

84
94
39
65
90
56
71
0.000
0.966
0.970
0.996 13C12-HXCDF 478 SUR2
1.000 13C12-HXCDF 678 IS4
1.015 13C12-HXCDF 234 ALT2
1.029
1.038 13C12-HXCDF 789 ALT1








Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 10:20 01/10/98
                                                                                                            225

-------
Page So. 4 Listing of 09800328. dbf
01/10/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total. Area. . . Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound. Name. . ID.. Flags
33:43 0.53 56.30 19.59 36.71 1.049
384-386 8 Peaks 46,764.37

HxCDD
390-392
M
0

390-392
13C12- HxCDD
402-404



402-404
HpCDF
408-410
M
D



DC NL 0
32
D SN 32
DC SN 33



:00
:00
:12
:35


1
RO


RO




:: RxCDF / HxCDD Follows -
.05-1.43
0
1
1
0
.67
.13
.25
.30
1 Peak

DC NL 0
32
32
33

:00
:43
:48
:07
1
RO



11
67
30
4
67
.71
.30 35.70
.08
.52
.30
.05-1.43
0
1
1
1
3 Peaks

DC NL 0:
35;
D SN 35:

:00
:00
;16
35:26
D
408-410
13C12-HpCDF
418-420
M

M
418-420
HpCDD
424-426
M



424-426
13C12-HpCDD
436-438

436-438
D SN 36:34
0
RO

RO
RO
RO
.86
.20
.21
.21

42
8,203
12,414
13,554
34,172
.88-1.20
1
1,
.39
.04
0.76
0.
.55
0.75
2 Peaks


DC NL 0:00
35:00
35:
36:
28
32
0.
RO
RO
RO
RO
.42
.44 4,480.50
.95 6,796.24
.21 7,417.33
.60
3 / HpCDF Follows • •
17.97
200.
.00 102.00
36.84
32.
26.
232.
.40 16.52
.74
40
37-0.51
0.
0.
0.
0.
3 Peaks

DC NL 0:
35:
DC SN 35:
36:
DC SN 36:

00
17
44
02
32
0.
RO
RO
RO

RO
88-
1.
0.
0.
0.
1.
60
35
76
35

1.20
62
81
31
96
65
2 Peaks

DC NL 0:
36:

00
02
0.
RO

88-
0.
1.
1.20
86
05
1 Peak
26.
4,418.
39.
3,370.
87
18 1,350.00
63 20.93
91 1,030.00




0.958-1.014
0
31.60 0
0
1

.000
.976 J
.982
.024

0.970-1.030
0
3,722.94 0
5,618.71 1
6,136.88 1

.000
.997 13C12-HXCDD 478 SOK3
.000 13C12-HXCDD 678 IS5
.010 13C12- HxCDD 789 RS2

0.996-1.049
0.000
98.00 1.000 1234678-HpCDF AN
1,
30.16 1.
.008
.012 J
1.045 1234789-HpCDF AN


0.943-1.114
0.000
3,890.00 1.
27.52 1.
2,950.00 1.
000 13C12-HpCDF 678 IS6
013
044 13C12-HpCDF 789 SOR4
7,828.72
i HpCDF / HpCDD Follows • -
6.
32.
3.
43.
16.
76.

37.
8,602.
8,602.
57
95 16.80
45
12 21.09
38
07

49
80 4,401.91
80
0.975-
0.
20.70 0.
0.
22.03 1.
1.

0.972-
0.
4,200.89 1.

1.005
000
979 J
992
000 1234678-HpCDD AN J
014

1.028
000
000 13C12-HpCDD 678 IS7

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
              226

-------
  Page No.
  01/10/98

  Compound/
  M_Z.... QC.
  OCDF
  442-444

  442-444

  OCDD
  458-460
  458-460
              Listing of  O980032B.dbf
              Matched GC  Peaks / Ratio / Bet. Time
Log Omit Why ,.RT.  OK Ratio  Total.Area... Area.Peak.1..  Area.Peak.2. . Rel.RT Compound.Name..  ID..  Flags.

    	 Above: HpCDD / Octa-CDD and CDF Follows  	
       '" 	"	  0.76-1". 02"
     DC  NL   0:00  RO   2.20
             39:49      0.87
           1 Peak
  9.87
252.00
252.00
                    0.76-1.02
     DC  NL    0:00  RO   0.71          6.43
             39:37      0.92        102.13
     DC  SN   39:51  RO   0.45          2.51
          1  Peak                  102.13
  13C12-OCDD                    0.76-1.02
  470-472         DC  NL   0:00 RO  1.07         14.91
                         39:36     0.86     12,336.23
  470-472               1 Peak               12,836.23
.— .	0789'9-r.lO'l          	~
                      0.000
 117.00        135.00  1.005 OCDF            AN
                               0.899-1.101
                                   0.000
              48.94         53.19  1.000  OCDD            AN
                                   1.006
                                                                 0.996-1.004
                                                                     0.000
                                              5,930.35      6,905.88  1.000 13C12-OCDD      IS8
  Column  Description	  "Why" Code Description	  QC Log Desc.
  M_Z    -Nominal Ion Mass(es)
  ..RT.  -Retention Time (mm:ss)
  Rat.l  -Ratio of M/M+2 Ions
  OK     -RO-Ratio Outside Limits
  Rel.RT-Relative Retention Time
  «»• End of Report •«•
                    WL-Below Retention Ti»e Window
                    WH-Above Retention Time Window
                    SN-Below Signal to Noise Level
                    
-------
r±la:09a0032 #1-724 Acq: 6-JAH-1998 22:01*41 SC SI+ Voltaga SIS 70S JToiae:6838
303.9016 T:2 BSUB(256,30,-3.0) PXO(9,5,3,0.10\,27352.0r1.00\rT,T) ExptHDBSUS
TSIAKSZX LABS Taxt,177/182-184/209 TLH4437SA
1001 A3. 1X5 1.8X5
80.
60.
40.
20.
0
r±2e
305.
TSU
1001
80.
SO.
40.
20:
o-
File
315.
TSIA
1003
ao:
60:
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20:
o-
r±ie
317.
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sol
40:
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330.
TSIA
1003,
ao:
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40:
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rile
375.
TSIA
1001
ao:
50:
40:
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oj

A4.
A2.19X5
A A2.22X5

38X5 A4.78X5
A2.70JT5 A A J
'22iOO 23:00 24 t 00
t:O980033 tl-724 Acq: 6-JKS-1998 22:01:41 SC XI + Voltage
8987 T:2 BSU3(2S6,30,-3.0) PXD(9,5,3,0.10\,30768.0,i:00\
OGLE LABS Text: 177/182-184/209 TLIt44376A
Al.


A7.39XS A4
^^^Wwv^Av^SrVL-Jt^
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AS. 38X5 1
fiC*AJU

f
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V
22:00 23*00 24*00 25*00 ' '25*00
IU980032 tl-724 Acqs S-J3X-1998 22:01:41 SC EH- Voltage SIS 70S Soiae:4747
9389 T:2 BSUB(256,30,-3.0) PEB(9,5,3,0.10\r18988.0,1.00\,r,T) Xxp:XDB5US
KSLX LABS Text: 177/182-184/209 TLIt44376A
A1.02E8







1



i
'22»00 '2J«00 24:00 	 25*00 	 25*00
>O980032 tl-724 Acq: 6-JXH-1998 22:01:41 SC XI+ Voltage SIS 70S
9792 7*2 Sxp:HHB5nS
SSLE LABS Text: 177/182-184/209 TLIt44376A
21,38 22:27 23:35 23:58 24:46 25j37 26^03

22*00 23:00 24*00 25*00 	 25*00
:0980032 tl-724 Acq: S-J3OI-1998 23:01:41 SC XI+ Voltage SIS 70S
8364 T:2 KxpiNDBSUS
NGLX LABS Texts 177/182-184/209 XLX944376A
26 25

31 !34 22:58
A 1 31i" a\a'\ y
\dW\iyfV/M^AlAJ^ulJJ\AJU\l^lJ^
22:00 23:00

a3'.4f 24:12
23:27 njl j\ li 11 i 1 1
24*00

25* 30
24:49 1 25'58 , 1
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m^LAmJMwm
25*00 25*00
Ll.5r5
.1.1X5
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'-.1 . 7X5
'-.1.1X5
-.5.7X4
'• o.oxo
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1 . 8X7
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.7.1E6
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•o.oxo
Time
.2.3X7
.1.9X7
.1.4X7
.9.4X6
.4.7X6
0.0X0
Tine
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228

-------
rila:U980033 tl-724 Acq: 6-JAS-1998 22:01:41 SC ZI+ Voltage
SIS 70S NoiM»tl911
319.8965 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.10\r7644.0,1.00\,F,T) XxptKDBSUS
TSIANGLX LABS Text: 177/182-184/209 TLH44376A
100.

80
60.
40.
20.
0
\ J
A A3. 03X5
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' 33:00 ' 24\00 25:00 '
T±la:U980032 tl-724 Acqs 6 -JAN- 19 9 8 22:01:41 SC XX+ Voltage
321.8936 r:2 BSUB(256, 30, -3.0) PXD(7,5, 3,0 .10\, 8616. 0,1. 00\,
TSIAlfSLX LABS Text: 177/182-184/209 TLXt44376A
1001
80.
60.
40.
20.


« A3. 28X5
h
1
1 \ I \ AS. 48X4 ,j 27X4s\l, ** A3. 33X4 . J«
; v>wv WvlA- .."J^%^^fSJLiMJ^
23:00 24:00 25:00

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1 	 	 A2j_36X4 	
n ^yY^^yV^A/^A-i>^JK/y^Aj\j^^

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'.3 . 8X4
.2.6X4
_:TJM

26:00 ' ' ' ' ' Time
SIS 70S Noia»:21S4
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Al
m A6.61E4
ll A • •*» • •' **™ i
.a. iz4
.6.1X4
.4.1X4
.2. 0X4

36:00 ' Time
ttle:D980032 tl-724 Acq: 6- JAN- 1998 22:01:41 SC XI+ Voltage SIS 70S Noiae:8684
331.9368 r:2 BSD3(256, 30, -3.0) PXD(7,5,3f0.10\,34736.0,1.00\rr,T) Xxp:SDB5US
TSIANSLE LABS Text: 177/182-184/209 TLIt44376A
ion
BO:

sol
40:
20:
o:
A8.78E

l\6


\l
1 \J
23:00 24:00 25:00 '

7 2.2X7

69X7
A

l\
V
.1 . 8X7

ll . 3X7
.9.0X6
.4.5X6

.25.00 	 Time
rile:U980033 tl-724 Acq: 6-JXK-1998 33:01:41 SC XH- Voltage SIS 70S Noise 1 4675
333.9338 T:2 BSO3(2S6,30, -3.0) PKD(7,5,3,0.10\,18700.0e1.00\fr,T) Xxp:SDB5US
TSIANGLX LABS Text: 177/182-184/209 TLIt44376A
1001
80:

SO:
40:
20:
ol

A1.08X8 2.8X7
fl.
Ua.
1

J
/ \J
23:00 24:00 ' 25:00 '

22X7
A

'
V
-.2.2X7

.1.7X7
'.1.1X7
-.5.6X6
'• a. or a
26: 00 Time
Tile:U980032 tl-724 Acq: 6-JAN-1998 22:01:41 SC KX+ Voltage SIS 70S Soiae:2866
327.8847 r:2 BSDB(256,30r-3.0) PJOJ(7, 5,3,0 .10\,11464. 0,1. 00\,f,T) Xxp:HDB5US
TRIANGLE LABS Text: 177/182-184/309 TLH44376A
1001
80:
60:
40:
30:
o:
Al




1
33:00 24:00 25:00

.33X8 3.1X7




\_
.2.5X7
.1.3X7
.1.2X7
.6.2X6
o.axa
26:00 Time
File 1 0980032 tl-724 Acq: 6-JAN-199S 22:01:41 SC XH- Voltage SIS 70S
330.9792 T:2 XxptSDBSVS
TRIANGLE LABS Texts 177/102-184/209 TLH44376A
1001
00:
60:
40:
20:
oj
23:2133:35 23:58 24:15 24:46^25:03





33iOO 24:00 35:00


25j37 26} 03 26:19 26:37 6.2X7





.5.0X7
.3.7X7
.3.5X7
.1.3X7
a . ova
26: 00 Time
229

-------
 r±2aiO9 80033 #1-724 Acqi 6-JAH-1998 22,01:41 GC XI* Voltage SIS 703 Hoife:3583
 339.8597 f,3 3SOB(256,30,-3.0) ?XD(7,5,3,0.10\,14332.0,1.00\,r,T) XrpiHDSSUS
 TSIASSLX LASS  Text.-177/183-184/309  TLI944376A
 100*                         A8.J.1X5
               27100                 28,00                 23>00
 rlla:U980032 H-724 Acq, 6-J1UT-1998 22i01>41 GC XH- Voltage SIS 70S JK>ifa:3981
 341.8567 Ti2 BSU3(256,30, -3.0) PXD(7,5,3r0.10\,15924.0t1.00\,T,X) XrpiSDBSOS
 TSIANSLX LASS  Text: 177/182-184/209  TLH44376A
 1004                         A9.20XS
                                                                                 30100
               27t00                 28tOO                 35i00                 JO.00
r±le:O980032  91-724 Acqs 6-JXK-1998 22:01:41 GC XI + Voltage SIS 70S Boloet54B7
351.9000 T:2  3303(256,30,-3.0) PXD(7,5,3,0.10\,21948.0r1.00\,T,T)  XxpiXDBSUS
TSIANSLE LASS  Tarts 177/182-184/209  TLH44376A
lOOi,                                            A3.65X7        A8.69X7
                                                   A
  so:
  60:
  40:
  20!
               27:00                 28i00                 23:00                 30:00
TlletU980032 tl-724 Acqi  6-J3UT-1998 22:01:41 GC XH- Voltage SIS 70S JToiaet6221
353.8970 r>2 3SU3(256,30,-3.0) PKD(7,5,3,0.10\,24SS4.0,1.00\,r,T)  XxptSDBSUS
TSIAKGLE LASS  Text: 177/182-184/209  TLIf44376A
1004                                            A6.49E7        A5.95E7

  80:

  sol

  40:

  30:

  0.
               27,00                 28,00                29:00
rile:U980033 il-724 Acq:  6-JJOT-1998  23:01,41  GC XH- Voltage SIS  70S
330.9793 T:2 XxpiSDSSUS
TSIANGLX LABS  Text: 177/182-184/209   TLH44376A
 80:
 50:
 40:
 20:
  o:
                  27:10
                            37:3527:50
                                                               29 > 13
                                                                                 30:00
                                                                           29:44   30:06  30:35
               37:00                 38:00                 39:00
r±lmtU980032 tl-724 Aoqi  6-JAN-1998  22:01:41  GC EH- Voltage SIS  70S
409.7974 T:3 XxpiSDSSUS
TSIAHSLX LABS  Tarti 177/182-184/309   XLH44376A
                                              38,36
 SO.
                                                                                 30,00
 
-------
rjJ.a:U9UOOJ3 #1-724 Acq:6-J3ul-199e J2:01s41 SC Sir VoJ.taga SIS 70S Noi.aaiJ.QJ4
355.8546 f:2 BSVB(256f30e-3.0) PXD(5,S,3,O.OS*,4136.0,1.00\fr,T) KxpiXDBSUS
TSIAOGLX LASS  Taxtt 177/182-184/209  XLH4437SA
100* A3.32X5
                            A3. 73X5
      37,48 28:00  23:12 28:24 29*36  23,48 29:00 29:13 29,24 29,36 39:48  30:00 30,12 30,24
rila,O980032 tl-724 Acq:  6-JZS-199B 22:01t41 SC XX* Voltage  SIS  70S HOiae,2313
357.8516 Ti2 BSVB(2S6,30t-3.0)  PXD(5,5,3,0.05\,9252.0r1.00\,r,T) XxptSDBSUS
TSIASGLX LASS  Taxti 177/182-184/209  TLH44376A
ion
                                                                                             Time
                                                                                         -8.3X4
                                                                                                 0.0X0
      27:43 28:00 38:12  38:34 38:36 28:48 39:00 29:13 39:34 39:36 39:48  30:00 30:13 30:34
T±leiU980032 tl-724 Aoj: 6-J7OT-1998 32:01:41 SC XI+ Voltage  SIS  70S Noiae:996
367.8949 T:2 BSUB(256,30,-3.0)  PXD<5tSf3,O.OS\,3984.0,1.00\,r,X) Xxp:KDB5US
TSIASSLX LASS  Text: 177/183-184/209  TLH44376A
100\                                                         AS. 53X7

 80.

 60.

 40.

 20.
                                                                                                    Titte
                                                                                        ^1•6X7

                                                                                         ,1.3X7

                                                                                         9.9X6

                                                                                         .6.6X6

                                                                                         .3.3X6

                                                                                         ,0.0X0
      27,48 28:00 28:12  28:34 28:36 28:48  29,00  29:12 29:24  29:36 29:48  30:00  30:12 30:24
rile:V980033 tl-724 Acq: 6-JJOT-1998  22:01,41 SC XI+ Voltage SIX 70S Koiae:1775
369.8919 T:2 BSUB(256,30,-3.0) PXD(S,5,3,O.OS\,7100.0,1.00\,TrS) XxptSDSSUS
TRIANGLE LASS  Taxt:177/182-184/209   XLIt44376A
100*                                                        A3.69X7

 80.

 $0.

 40.

 20:
                                                                   . 60X6
                                                                                         .1.1X7

                                                                                         8.9X6

                                                                                         6.7X6

                                                                                        ,4.5X6

                                                                                         .2.2X6
      27:48 28,00 28:12  28,24  28,36 28,48  29:00  29,12  29,34  39,36 39,48 30,00  30,13 30,34
rile,0980033 tl-724 Acq, 6-JA1T-1998  22:01,41 GC XZ+ Voltage SIX 70S
330.9792 F,2 XxptSDBSUS
TSIASSLX LASS  Tmxtt 177/182-184/209  TLXt4437SA
                                                                                         0.0X0
                                                                                            Time
10K

 80.

 60.

 40.

 20.

  0.
27:50
                                  29155
                                                           29,44
                                                                      30:06
                                                                                  30,28
-6.5X7

.5.2X7

.3.9X7

.2.6X7

.1.3X7
                                                                                                0.0X0
      27,48  28,00 28,12 28,24  28,36 28,48  29,00  29,12  29,24  29,36 29,48 30,00  30,12 30,24
                                                                                                        231

-------
 TileiU9a0032 tl-384 Acq: 6^JAN-1998 22:01:41 GC EI+ Voltage SIX 70S Hoiae:5462
 373.8308 t:3 BSVB(256,30,-3.0) PXD(7r5,3,0.10\r21848.0,1.00\,r,T) ExpiXDBSOS
 TSIASSLX LABS  Text: 177/182-184/209  TLH44376A
 1001

  aol
     31,00 31,12 31,24 31:36 31,48 32,00  32,12  32,24  32,36 32,48 33,00 33,12  33,24  33,36 33,48
nj.e:O980032  tl-384 Acq:  6-J3Or-1998 22101 >41 GC XH- Voltage SIX 703 Soitei6344
375.8178  T,3  33UB(2S6,30,-3.0) PXD(7,5,3, 0.10\, 24976.0,1.00\,T,T)  XxptttDBSUS
TBXANSLX  LASS  Tart: 177/182-184/209  TLIt44376A
1001

  80:
     31,00  31,12 31,24 31,36  31:48 32,00 32:12  32,24  32:36  32:48 33:00 33:12 33:24  33:36 33:48
Tile,U9BOO32  tl-384 Acqs  6-J3OT-1998 22:01:41 GC EI+ Voltage  SIS  70S Noiae:4190
383.8639 T:3  BSUB(256,30, -3.0)  tXD(7,S,3,0.10\,16760.0,1.00\,T,T)  Sxp:SDB5US
TBIABGLE LASS  Tart: 177/182-184/309  TLH44376A
1004                                  A4.49X7

  aol

  601
    31:00  31:12 31:24 31:36  31:48 32:00 32:12 32:24 32:36  32:48  33:00 33:12 33:24  33:36 33,48
rtj.a, 0980032 tl-384 Acq:  6-JJOT-1998 22:01:41 GC EH- Voltage  SIS  70S Noise, 5800
385.8610 Tt3 BSDB(2S6,30,-3.0)  PXD(7,5,3,0.10\,23200.0,1.00\,r,T) Srp:SDB5US
TSIASSLS LABS   Text: 177/182-184/209  TLH44376A
1001

  aol
 401
  O
                                                                      33:06
                                                                               ^33,26
                                                                                         33143
    31,00 31:12  31:24 31:36 31:48  32:00 32,12 32:24 32:36 32:48  33:00  33:12 33:24 33:36  33,48
Tilei0980032 tl-384 Acq: 6-J7UT-1998 22:01:41  GC EH-  Voltage SIX 70S
392.9760 Ti3 Exp:KDB5US
TXIASSLE LABS  Text: 177/182-184/209   TLIt44376A

        ___.-^^^.--	31:5832:0932:19  32:34
 80- «T<

 601

 401

 201
 0.0X0
    Tiae
                                                                                                     O.OEO
                                                                                                        Time
 3.0E7

.2.4E7

.1. 8E7

J..2X7

.6.0E6
    31:00 31:12  31:24 31:36 31:48  32:00 32:12 32:24 32:36 32:48  33:00  33:12 33:24 33:36  33:48
rile:O980032 tl-384 Acq: 6-J3Ot-1998 22:01:41  GC EI+  Voltage SIX 70S
445.7555 F,3 SxpiSOBSUS
TRIANGLE LABS  Texti 177/182-184/309  TLH44376A
                                                                                                     0. OEO
                                                                                                        Time
    31:66 3lYl2  3l',24 31:36 31:48  32:00 32:13 32:24 32i36 32>48  33:00  33:12 33:24 33:36  33:48
 O.OEO
    Tiae
                                                                                                        232

-------
             H-JB4 Acq:  6-JAa-J.yye  utu±:iJ. <»c. AJ.f voicage SIS /us ifoiaetjjt
389.8156 T-.3 BSVB(256,30, -3.0) PXD(7,5,3,0.10\,12960.0,1.00\,r,T) XxptHBBSUS
TXIASGLX LABS  Text: 177/182-184/209   XLIt44376A
1001                     A3 96X5
         31', 36    31:48   32:00   32:12   32i24   32,36    32:48   33:00   33', 12
Fil»,U980032 tl-384 Acq: 6-JZOT-1998 22,01,41 SC EH- Voltaya SIX 70S Hoiae,4860
391.8127 Ti3 BSOS(256,30, -3.0) PKD(7,5,3, 0.10%, 19440.0,1.00\,T,T)
TRIXHSZX LASS  Text: 177/182-184/209   TLH44376A
1001                     A2.43X5
                                                                                     33:24   33 36
         31:36    31:48   32:00   32:12    32:24   32:36    32:48    33:00   33:12
HJ.atO980032 tl-384 Acqi 6-JXB-1998 22:01:41  SC XI*  Voltage SIS 70S Hoiae: 11739
401.8558 T:3 aSUB(256,30,-3.0) PXD(7,5,3,0.10\,46956.0,1.00\,T,T)  Zxp:SDB5US
XSIANGLX ZABS  Text, 177/182-184/209  TLIt44376A
100*                                                      A6.80X7      A7.42E7
                                                                                    33:24
                                                       A4.48E
 80.

 eo:

 40.

 20:

  OJ
         3l',36    31:48   32:00   32:12    32:34   32', 36    32:48    33:00   33:12
rileiO930032 tl-384 Acqi 6-JJOT-1998 22:01:41  SC EI+  Voltage SIS 70S Noise, 13573
403.8529 Ti3 BSUB(256,30,-3.0) PXD(7,5,3, 0.10*, 54292.0,1.00\,f,T)  Exp:KDB5aS
T&IANSLZ LABS  Text: 177/182-184/209  TLII44376A
                                                          A5.62E7
                                                       A3.72E,
1001

 80.

 60.

 40.

 20:

  oi.
         3l',36    31:48   32:00   32:12    32:24   32:36    32:48    33:00
ril»:O980032 tl-384 Acqt 6-JAS-1998 22:01,41  SC KI+  Voltage SIX 70S
392.9760 Ti3 KxptNDBSUS
TSIABCLX LABS  Text: 177/182-184/209  TLIt44376A
                                                                       A6.14E7
                                                                                                '.O.OEO
                                                                                                36  Time
                                                                                    33:24    33:36
                                                                            33:12   33:24
                                                                                             33:36
1001

 80.

 60.

 40.

 20.

  0.
                31:45
                         31,58  32:09
                                                                        33106
                                                                                      33126
-3.0X7

'.2.4X7

-1.8X7

.1.2X7

.6.0X6
                                                                                               .0.0X0
         31:36   31:48    32tOO   32:12    32:24    32:36   32:48    33:00   'h': 12   33:24    33 36 Timi
                                                                                                         233

-------
 Tila:a9B0032 tl-545 Acq: 6-JXH-1998 22:01:41 GC SI+ Voltage SIS  70S Hoiaes6140
 407.7818 T:4 BSOB(256,30,-3.0) PXS(7,5,3,0.10\,24560.0,1.00\,TtX) Srp:XDBSUS
          LABS  Taxt: 177/182-184/209  TLXt44376A
        A1.Q6X6
         35:00    35il2    35*24    35,36    3St48   36,00    36,13   36,24    36,36
ril»:0980032 tl-545 Acq: S-JMT-1998 22,01,41 GC XI* Voltage SIX 70S Boi,4407
409.7789 T:4 BSUB(256,30, -3.0) PXD(7f 5,3,0.101,17628.0,1.00\,r,T) XxptUOBSUS
TSIASSLX LABS   Text: 177/183-184/209  TLH44376A
100\   A1.Q1X6

  80.

  60.
                                                                                     36,48
  40:
                          A3.02X5
                                                                                                   .0.0X0
                                                                                              37:00    TiM<
                                                                                                   -2.9X5

                                                                                                   '•.2.3X5

                                                                                                   .1.8X5

                                                                                                   '•.1.2X5
  20:
            \A4.78X4^\.  A
            ^***J~**^S+/~**'f^Cr^^^^ \
                                                                             A
                                                                                                    -.5.8X4
        35:00    35', 12    35,24    35:36   35:48    36', 00    36', 12   36:24    36:36
TilatU980032 H-545 Acq:  6-J2UT-1998 22:01:41 SC EI+ Voltage SIS 70S Soiaet5597
417.8253 T,4 BSVB(256,30, -3.0) PXD(7,5,3, 0.10\,22388.0,1.00\,T,T) XxpsSDBSVS
TSIASGLX LABS  Text: 177/183-184/209  TLII44376A
1001   A1.4.1S7
                                                                          Al.06X7
                                                                                     36,49
                                                                                                  £.0.0X0
                                                                                              37:00    Time
        35:00    35:12    35:24   35:36   35:48    36:00    36:12    36:24    36:36
rile:£79800J2 tl-545 Acq:  6-JJOT-1998  22:01:41 SC XI+ Voltage SIX 70S So±ae:9330
419.8220 T:4 BSU3(256,30,-3.0) fXD(7,5t3,0.10\r37320.0,1.00\,T,T)  XxptSDBSVS
TSIASSLX LASS  Text; 177/182-184/209   TLI944376A
100&   A3.98X7
                                                                          A2.98X7
                                                                                     36:48
                                                                                                   -.0.0X0
                                                                                              37:00    ZLae
        35:00    35:12    35:24    35:36    35:48    36:00   36:12    36:24
rila:a980032 tl-545 Acq:  6-JAN-1998  22:01:41  GC XI+ Voltage SIS 70S
430.9729 T:4 EipiKDBSUS
TSIANSLX LABS  Text: 177/182-184/209   TLIt44376A

                                                       36,04
                                                                              36:36
                                                                                      36:48
60:

40:
20:

 o:
                                                                                                    0.0X0
                                                                                              37:00    Time
                                                                                                    -2.0X7

                                                                                                    '.1.6X7

                                                                                                    .1.2X7

                                                                                                    -8.2X6

                                                                                                    -4.1X6
        35:00    35,12    35:24    35:36    35:48    36:00   36,12    36:24
rileiU980032 tl-545 Acq:  6-JJUT-1998 22:01:41  GC XI+ Voltage SIX 70S
 79.7165 T:4 KipiHUBSUS
TSIASSLX LABS  Textt 177/182-184/209  TLH44376A
1004
                                                                            36:36
                                                                                     36:48
                                                                                                    .0.0X0
                                                                                               37:00    Tim,
        35:00
                 35:12
                          35*24
                                  35:36
                                           35:48
                                                    36:00
                                                            36:12
                                                                     36:24
                                                                             36:36
                                                                                      36,48
                                                                                                   0.0X0
                                                                                              37:00   Time
                                                                                                            234

-------
 rile,B930032 il-545 AOJ, S-JUI-1S9B '12,01:41 &C £1± Voltage SIS 70S y0i.ae,2606
 433.7766 Tt4 3SUB(356,30, -3.0) PKD<7,5,3,0.10\, 10424.0,1.00\,r,T) XxptSDSSOS
 XXIAHGLX ZABS  Text, 177/183-184/309  TLH44376A
 100*
  80.

  60.

 -40.

  30.
           A1.83X5
      35il3  35tl8  35t34 3Si30  35t36 35i43  35t48  35tS4 36iOO  36t06 36:12  36:18 ' 36,24 ' 36t 30
Tile, 0980032 fl-545 Acq, 6-JAH-1998  22t01t41 GC XX+ VoJLtxgm SIX 70S Boise, 1609
435.7737 Ti4 8SOB(256,30,-3.0) ?RD(7,5,3,0.10\r6436.0,1.00\rr,T) EzptNDBSUS
XXIAOGLX LABS  Tmxt, 177/183-184/309   TLH44376A
100\      A3. 43X5                                          A3. 30X5
                                                                                               .5.4X4

                                                                                               .4.3X4

                                                                                               .3.3X4

                                                                                               '.3.3X4

                                                                                               .1.1X4
                                                                                                 0.0X0
                                                                                                    T±m*
                                                                                               -5.9X4
      35,12 35,18  35,24 35,30  35,36 35,42 35,48  35,54  36,00 36,06  36,12' jtfiifl' 36':24
rU.a,U9S0032 tl-545 Acq, 6-JOT-1998 22,01,41 GC SI+ Voltage SIS 70S Soiaes9S56
435.8169 f,4 BSUB(256,30,-3.0) PXD(7,S,3r0.10\,38334.0,1.00\,r,T) XxpsSDBSVS
TSIASSLX LASS  Text: 177/183-184/309  TLH44376A
1001                                                      A4.40X7

 ao:

 60.

 40:

 20:
36,30
                                                                                                0.0X0
                                                                                                   Time
                                                                                               -1.0X7

                                                                                               .8.3X6

                                                                                               .6.2X6

                                                                                               -4.1E6

                                                                                               .2.1X6
      35,12 35,18  35,24 35,30  35,36 35,42  35,48  35,54 36,00  36,06 36,12  36,18 36,24
TUa,0980033 tl-545 Acq, 6-JXB-1998  32,01,41 GC XI+ Voltage SIS 703 Noise: 11071
437.8140 f,4 BSUB(356,30,-3.0) PXD(7,5,3,0.10\r44384.0,1.00\fT,X) XxpiKDSSUS
TRIAXGHS LASS  Text. 177/182-184/309  TLH44376A
1001

  80.

  60.

  40.

  20:
                                                                                                0.0X0
                                                                                                   Mae
      35,13 35,18  35,24 35,30  35,36 35,42 35,48  35,54  36,00 36,06  36,12 36',IS  36',34 36',30
rile,0380033 tl-545 Acq, 6-JAH-1998 22,01,41 GC XX+ Voltage SIX 70S
430.9739 T,4 XxpiUDBSOS
TBIANGLX LASS  Text,177/183-184/209  TLH44376A
100\
 80.

 60.

 40.

 20.
                      35,37
                                 35,37^
                                                  35,53
                                                              36,04

                                              '
                                                     '
      s 13  35ia 35,24  3S 30 35,36 3542  35',48 35',54
                                                            00  36 , 06
                                                                           ' 36 ',18 ' 36\24 ' 36>36
     -.1.9X7

     .1.5X7

     .1.1X7

     .7.6X6

     .3.8X6
      .0.0X0
         Mae
                                                                                                          235

-------
 ril»:O980032 41-545 Acqt  6-JAV-1998 33101141  SC SI+  Voltage  SIS 703 Noiae:5741
 441.7428 T:4 BSU3(256,30,-3.0)  PKD(7,5,3,0.10\,22964.0,1.00\,f,T)  SxptXDBSUS
 TSIAHGLX LASS  Text: 177/182-184/209  TLXM4376A
 100S
               35,00         36:00         37:00         38:00        39:00
r±le:O980032 tl-545 Acq:  6-JX1T-1998 22:01:41 GC XH- Voltage SIS 70S Noiaa,2610
443.7399 Tt4 BSVB(256r30,-3.0) tXD(7,5,3,0.10\,10440.0,1.00\,T,T) XxpiSDBSOS
TSZAXSLX LAB3  Text: 177/182-184/209  TLH44376A
1004
                                                                                    40,00
               35s00        36:00         37:00        38:00         39:00
 'ileiO980032 tl-545 Acq: 6-JZ1T-1998 22:01:41 GC EI+ Voltage SIS 70S
430.9729 Ts4 Sxp:XDB5US
TSIASSLX LABS  Text: 177/182-184/209  TLIM4376A
1004                                 36, J9
 901
 801
 701
 SOI
 501
 401
 301
 201
 101
  Oj
                                                                                   40:00
                                                                                        40:22
               35:00        36tOO         37:00        38:00
Tilm»U980032 #1-545 Acqt 6-JXB-1998 22i01i41 GC EH- Voltage STB 705
513.6775 T:4 SxpiHDBSUS
TSIAOSLS LABS  Text: 177/182-184/209  TLIt44376A
1001
                                                                     39100
                                                                                   40:00
                                                                                                 41:00
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TSIANGLX LASS  Text.: 177/182-184/209   TLH44376A
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TSIAHSLS LABS  Text: 177/182-184/209  XLII44376A
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-------
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Sample Text:177/182-184/209  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
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Sample Text:177/182-184/209  TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
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File:U980032 #1-724 Acq: 6-JAN-1998  22:01:41 GC  EH- Voltage SIR 70S
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Sample Text:177/182-184/209   TLI#44376A  File Text:TRIANGLE LABORATORIES,  INC,
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Sample Text:177/182-184/209  TLI#44376A File Text:TRIANGLE LABORATORIES, INC
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Sample Text:177/182-184/209   TLI844376A File Text:TRIANGLE LABORATORIES, INC.
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File:U980032 #l|-545 Acq: 6-JAN-1998 22:01:41 GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:NDB5US
Sample Text : 177/182-184/209 TLI#44376A File Text : TRIANGLE LABORATORIES, INC.
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Sample Text:177/182-184/209  TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
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'ile:U980032 #l-:545 Acq: 6-JAN-1998  22:01:41 GC  EI+  Voltage  SIR  70S	
 41.7428 F:4 Exp:NDB5US
Sample Text:177/182-184/209  TLI#44376A  File Text:TRIANGLE LABORATORIES,  INC.
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-------
 TLI Project:      44376A              Method 23 TCDD/TCDF Analysis (DB-225)
 Client Sample:   177/182-184/209  £ £), i                 Analysis File:  P980100
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
Culp Aluipinum Alloys
M23TRAIN Date Received:
194-59-15A Date Extracted:
Date Analyzed
1.000 Dilution Factor
n/a Blank File:
DB-225 Analyst

12/17/97
12/29/97
01/07/98
n/a
P980094
JM

Spike File:
ICal:
ConCal:


SPC2NF04
PF22206
P980092
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

%' :\ Awt/pr -% ot
0.02
EMPC

;|ntemiE$Janefarti ?;~--Amt jjufc % Recovery QC limits
13C,r2^,7,8-TCDF
f Recovery Standard
13C,rU,3,4-TCDD
2.9 72.0
-° ' **S'

40%- 130%


' Ratio
0.80
Ratio
0.79
Ratio
0.80
RT
23:06
RT
23:05
RT
21:55
Ftegs
B_
Flags
—
Flags



                    Data Reviewer
    \^^

Page 1 of 1
                    01/09/98
                                                                       aNF.FSRvUI.LAlU6.ia.OU
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                             Printed: 10:1601/09/98
                                                                                249

-------
                        Initial
                                    . .Dace.
  Data Review By:
Calculated Noise Area:
  The Total Area for each peak with an  ion abundance ratio outside
  ratio linits has been recalculated according to method requirements.
                                                                     1.22
Page No. 1
Listing
01/09/98 Matched
Compound/
M_Z 	 QC. Log Omit Why ..RT. OK
TCDF
304-306 DC
DC
DC
DC
DC



DC
DC
DC
M
DC

DC.
304-306
13C12-TCDF
316-318 DC
DC
DC
DC

DC
DC

DC
DC
316-318
13C12-TCDD
332-334 DC

DC



332-334

HL
SN
SN
SN
SN



SN
SN
SN

SN

SN
5

NX,
WL
WL
WL

SN
SN

WH
WH
2

NL

SN



4

0
19
20
20
20
20
21
21
22
22
22
23
23
23
24

:00
:27
:08
:20
:29
:36
:10
:36
:08
:21
:59
:06
:19
:36
:32
0
RO
RO
RO
RO
RO
RO


RO
RO
RO

RO
RO
RO
of P980100B.dbf
GC Peaks / Ratio
Ratio Total. Area
.65
1
1
2
1
2
0
0
0
0
1
1
0
0
0
0
-0.89
.01
.45
.05
.29
.34
.99
.89
.84
.38
.10
.54
.80
.99
.96
.43
Peaks

0:
21:
21;
22:
23:

00
:35
;51
:03
:05
23:18
23:
23:
24:
25:
22
42
09
09
0.
RO
RO

RO

RO

RO
RO
RO
65
1
0
0
0
0.
3
0.
0.
2.
0.
Peaks

0:
20:
20:
21:
21:
22:

00
28
35
37
SS
40
0.
RO

RO


RO
•0.89
.01
.63
:78
.52
.79 1,
.80
.67
.93
48
53
1,
65-0.89
1.
0.
0.
0.
0.
1.
Peaks
53
69
34
79
80 1,
07
2,

1
1
0
/ Ret. Tine
... Area. Peak. 1 .. Area . Peak . 2 . . Re I . RT Compound HUMP in

.79
.42
.76
2.46
1
3
10
5
1
0
1
7
2
3
1
29

3.
8.
32.
0.
340.
0.
0.
6.
1.
8.
.20
.08 1.72
.60 4.99
.39 2.46
.91
.73
.65
.60 3.37
.19
.17 1.71
.10
.84

.12
.09
.58
.94
,63 590.39
73
97
39 3.34
61
11
0.7Q2
o
0
n
0
0
1.74 0
5.61 0
2.93 0
0
0
0
4.23 1
1
1.79 1
1.

0.957-
0.
0.
0.
0.
750.24 1.
1 .
1 .
3.61 I .
1 .
1 .
•1.101
DIII'I
.843
872
.881
.887
.892
.917
.936
.959
.968
.996
.001 2378 -TCDF AN
.010
.022
.063

•1.043
000
935
947
955
000 13C12-2378-TCDF ISO
009
012
027
1)46
OCiti
347.02
TCDF / TCDD Follows ----
1.
6.
1.
982.
342.
11.
342.
58
22 2.53
15
64 434.10
00 597.84
29 6.80
15
0.908-
0.
3.69 0.
0.
548.54 1.
744.16 1.
6.38 1.

1.092
000
947
952
000 13C12-2378-TCDD IS1
014 13C12- 1234 -TCDD RSI
049

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                            Printed: 10:16 01/09/98

                                                         250

-------
  Page  No.     2           Listing of P980100B.dbf
  01/09/98                 Matched GC Peaks / Ratio / Ret.  Time

  Compound/
  H_Z.... QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rei.RT  Compound Name   ID   Flaps
  Column Description	 . . .   "WnY^_ 9ode_Des5riP5ion.- •_• -^•_!•_•_ _QC Log Desc.
 M_2   -Nominal Ion Masa(es)     ML-Below Retention Time Window   A-Peak Added
  ..RT. -Retention Time (raise)   MR-Above Retention Time Window   K-Penk Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below signal to Hoise Level   D-Peak Deleted
 OK    -RO-Ratio Outside  Limits  
-------
rilmitsaoioo ti-933 Acq:/-JAH-ya ui:a*:jj sn-
303.9016 Kzp,DS225
TSXJUfSLX LASS  I*tt: 177/182-184/209 TLH44376A
                     23 • 06
                                                                                                     ,1.5X4
  04	
     22:36' 32i48' 2Jlo0  23:12 23:24  23:36 23:48 24:00  24:12 24:24 24:36
rile:P980100 tl-922 Acq:7-J3UT-98 04:54:32 EH- Voltage SIX 70P
315.9419 Ezp:DS225
TZXAXGLX LASS  Text: 177/182-184/209  TLH44376A
1001
 95.
 90.
 85.
 80.
 75.
 70:
 65:
 60:
 55:
 50:
 45:
 40:
 35:
 30:
 25:
 20:
 15J
 10:
  5j
                    23; OS
                                                                                                     O.OEO
                                                                           24:48  25:00 25:12  25:24     T±ae
                                                                                                     1. 6E6
                                                                                                    '•.1.SE6
                                                                                                    .1.4E6
                                                                                                    .1.3E6
                                                                                                    .1.3X6
                                                                                                    .1.2E6
                                                                                                    J..1E6
                                                                                                    .1. OE6
                                                                                                    J.SES
                                                                                                    .8.7X5
                                                                                                    .7.9X5
                                                                                                    .7.1X5
                                                                                                    .6.3X5
                                                                                                    .5.5X5
                                                                                                    .4.7X5
                                                                                                    .4.0X5
                                                                                                    .3.2X5
                                                                                                    .2.4X5
                                                                                                    '.1.6X5
                                                                                                    .7.9X4
    22:36  22:48 23:00 23:12 23:24 23:36  23:48 24:00 24:12 24:24  24:36 24:48  25:00 25:12 25:24
                                                                                                    .0. 0X0
                                                                                                       Hat
                                                                                                    252

-------
 FU.aiP9UOJ.00 ti-932 Acq:7-JMi-Sa 04:3f,J4 AJT voxcaye SIM /op Noiaetsua
 303.9016 BSUB(256,30,-3.0) PXD(Se3,l,0.10\,2032.0,0.00\,T,r) Xxp,Dtt22S
 TXIANGIX LABS  Text: 177/182-184/209 TLH4437SA
 100*
           19': 00        20:00       21,00       22sOO       23'tOO        24:00
r±le,P980100  fl-922 Acq:7-J3UT-98 04t54t32 £Z> Voltage SIX 70P Soiae,507
305.8987 BSVB(256,30,-3.0)  PXD(5,3,1,0.10\,2028.0,0.00\,r,T) KlpiDB225
XSIASSZX LASS  Text: 177/182-184/209 XLH44376A
100*                               AS. f 1X4
             25100
          19:00        20:00       21:00       22:00       23:00        24:00
Tile>P980100 fl-922 Acqt7-JJOr-98 04t54i32 XI+ Voltage SXZ 70P No±aot889
315.9419 B3UB(256,30,-3.0)  PKS(5, J, 1, 0.10\,3556.0,0.00\,rrr)  ZzptDB22S
TSIANSLX LAB3  Text: 177/182-184/209 XLH44376A
100*                                                       A5.90ES
 80.
  SO.
 40.
 20.
                                                                                    25100
          19:00        30:00       21:00       22:00       23:00       24:00
rilaiP980100 H-922 Acq>7-JKN-98 04:54:32 EH- Voltage SIS  70P Noise:882
317.9389 BSUB(256,30,-3.0)  PKD(5,3,1,0.10\,3538.0rO.OO\,r,r)  Exp:DB225
   ANSH: LABS  Text: 177/182-184/209 TLH44376A
100*                                                       A7.SOSS
 80.

 SO.

 40.

 20.

  0.
             25:00
          19:00       20:00        21:00       22>00       23:00
Tilo:P9B0100 91-922 Adjt7-J3OT-98  04:54:32 XI+ Voltage SIS  70P
375.8364 Sxp:DB225
TSIAKSLX LASS  Text: 177/182-184/209  TLIt44376A
100*18:32
24:00
            25100
                                                              33,14 23,46 24:I*!3" t    35,14
                         -1. 6X6

                         '.1.3E6

                         .9.5X5

                         -6.3XS

                         .3.2X5
                          0.0X0
                            Time
                        -2.0X6

                        '.1.6X6

                        .1.2X6

                        '.8.2X5

                        .4.1X5
                          0.0X0
                            Time
          19,00       20,00        21:00       22,00       33':00       24,00      '  25':00
                        -9.4X3

                         .7.5X3

                         .3.6X3

                         3.7X3

                        ^1.9X3

                         .0.0X0
                            Time
                                                                                                      253

-------
 FU.mtP9oQl.QQ  ti-922 Acqi 7-JJUI-Sa C«»5««JW £1+ Voltage SIS  70f Soj.fei410
 319.8965  BSUB(256,30,-3.0) PXD(5,.3,1,0.10%, 1640.0, 0.00\,f,r) XxpiDB225
 TSIASGLX  LABS  Tmzt,177/182-184/209 XLH44376A
 1001
                20:00            31:00           22:00           23:00
rLL»:P980100  tl-922 Acqi7-JJUT-98 04,54,32 SI+ Volt*?* SIX 70P Xo±**i442
321.8936 BSUB(256,30,-3.0)  ra>(5,3,1,0.10\r1768.0,0.00\,T,T) XrptDB223
TXIASGLS IA3S T&ctt 177/182-184/209 TLH44376A
ion
                20', 00            21:00           22iOO           23tOO
rile,P9B0100 tl-922 Acq:7-J3OT-9B 04,54,32 EH- Voltage SIS 70P SOifmtSOS
327.8847 BSVS(256,30, -3.0)  PXD(S,3,lr0.10\,2020.Q,0.00\,r,T) XxpiDB225
ISIANSLZ LABS  Tort: 177/182-184/209 TLH44376A
1001                                      A8.98S6
 80.
 60.
 40.
 20.
                20100            21:00            22:00           23:00
r±J.e,P980100 tl-922 Acqt7-JJOt-98 04,54:32 ZI+ Voltage SIS 70P Noiae,678
331.9368 BSUB(256,30,-3.Q) PKD(5,3,1,0.10\,2712.0,0.00\,T,T) SxptDB225
TBIANGLX LABS  Text:177/182-184/209 TLH44376A
1001                                          AS. 98X6
 80.

 60.

 40.

 20.
  0.
A4.34X6
                20100           21:00            22:00            23:00
ril»:P980100 tl-922 Acq:7-JXJT-98  04:54:32 £Z> Volttgu  SIS 70P Soimmt447
333.9338 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,1788.0,0.00\,r,r) Xxp:JJB225
TSIANCLS LABS  Text: 177/182-184/209  XLIt44376A
1001                                          AT. 4416
 80.

 SO.

 40.

 20.

  0.
AS.49X6
                                         24:00
                                         24:00
                                        24:00
                                        24:00
                                                         25 00
 .0.0X0
     T±ma
                                                             0.0X0
                                                         25 00  Time
                                                             2.4E6

                                                            .1.9X6

                                                            J..4X6

                                                            J.6X5

                                                            L4. 8E5
                                                         25
                                                            .0.0X0
                                                            00 Time
_1.6X6

.1.3X6

'.9.4X5

.6.3X5

.3.1X5
                                                           .0.0X0
                                                         25 00 lime
                20:00
                                21:00
                                                22:00
                                                                 23:00
                                                                                  24:00
-.2.0X6

'.1. 6X6

.1.2X6

.7.9X5

.3.9X5
                                                           .0.0X0
                                                         25 00  T±ae
                                                                                                       254

-------
              tl-922 Acq:7-JAlf-98 04:54:32 EH-  Voltage SIS 70f
 303.9016 Exp:DS225
 TSIASSLX LASS  Tmxt:177/182-184/209 TLIt44376A
           IS I 00       20tOO        21100       22100
Til*sP980100 tl-922 Acq:7-JAS-98 04:54t32 XX*  Voltage
315.9419  Xzp:DS225
TSIASSLX  LASS   T«rt» 177/182-184/209 TLIt44376A
1003
  ao:
  sol
  40:
  20:
                                                            23 tOO
                                                       SIS 70P

                                                             231 OS
                                                                        24100
                                                                                    25100
          19:00        20:00       21tOO       22tOO       23:00
TilatP9S01QO tl-922 Acq:7-JJOT-98 04:54:32 EI+ Voltage SIS 70P
319.8965 Xxp:DS225
TSIASSLX LABS  Text: 177/182-184/209 TLH44376A
                                                                        24 s 00
                                                                                    25:00
          19100        20s00       21:00       23s 00
F±latPS80100 tl-922 Acq:7-J7Ur-9a 04:54:32 EI+ Voltage
331.9368 Kxp:DB225
TSIASKLX LASS  Text: 177/182-184/209 TLXt44376A
1001
 SO:
 60:
 40:
 20:
                                                           23 s 00
                                                       SIS 70P
                                                                        24:00
                                                                                    25:00
          19:00        20:00       21:00       22:00
r±latP980100 tl-922 Acq:7-JJOT-9S 04:54:32 EH- Voltage
292.9825 Exp:DB225
TSIASSLX LASS  Taxt:177/182-184/209 TLH44376A
1003L.	lfljjfl_  .19j2^19j56	  20.
 80:
 60:
 40:
 20:
  0.
                                                           23:00
                                                       SIS 70P
                                                                        24:00
                                                                                    25:00
                                                             33:10    23:5434:32   24:59
                                                                        •• --
                                                                                                   6X6
                                                                                                   3X6
                                                                                                   5XS
                                                                                                   3X5
                                                                                                   2X5
                                                                                                   OEO
                                                                                                    Time
                                                                                                  .OEO
                                                                                                    T±ae
                                                                                                   6E6
                                                                                                   3X6
                                                                                                   4X5
                                                                                                   3X5
                                                                                                   1X5
                                                                                                   0X0
                                                                                                 7.
                                                                                                .4.
          19:00        20:00       21:00       22:00
rile:P980100 tl-922 Acqi7-JZK-98 04:54:32 SI+ Voltage
330.9792 XxpiDS225
TRIANGLE LASS  Text: 177/182-184/209 TLIt44376A
100\              19:37    20:20          . 21t39
    ~*-*ff\,S*bf~»fi\j>
 80.
 60:
 40:
 20:
  o.
                                                           23:00
                                                       SIS 70P
                                                                       24:00
                                                                                    25:00
                                                                               24:39
                                                                                           "V^^f
          19:00
                       20:00
                                   21:00
                                               22 tOO
                                                           23:00
                                                                       24:00
                                                                                    25:00
                                                                                                   3X6
                                                                                                   9X6
                                                                                                   4X6
                                                                                                  .9X6
                                                                                                  .5X6
                                                                                                  .0X0
                                                                                                    Mae

                                                                                                   9X6
                                                                                                  .7X6
                                                                                                  .5X6
                                                                                                  .3X6
                                                                                                  .2X6
                                                                                                  .0X0
                                                                                                    Hue
                                                                                                      255

-------
Ref, tass    292,9825     Peak top
Height  1,23 volts  Span   288 ppi

Systet file naie  	
Data  filenaie
Resolution
Groupruber
lonization Kde
Switching
Ref, lasses   292,9825,
R   292,9825         J
8   383,9816         K

D   3&9419         H
E   317,9389
F   319,8965
6   321,8936
H   327,8847
I   338,9792

Channel   I  338,9792     Peak top
Height  1,85 volts  Span   288 ppi
       1
     El*
 VOGE
388,3761
338,9792
331,9368
333,9338
375,8364
                              256

-------
Frie:P98010()
303.9016 Exp:
Sample Text:177/182
100%
 60 j

 40J

 20J

  Oj
  -922 Acq:7-JAN-98 04:54:32 EH- Voltage SIR 7OP
DB225
      -184/209 TLI#44376A File Text:177/182-184/209 TLI#44376A
                     A3.37E4
     22:12  22
                                                                                                        CM
                                                                                     1.5E4

                                                                                    L1.2E4

                                                                                    18.7E3

                                                                                    L5.8E3

                                                                                    L2.9E3
                                                                            LO.OEO
 •24  22:36  22:48  23:00  23i12  23i24  23:36  23i48  24iOO 24i12  24:24  24:36  Time
File:P980100 #1-922 Acq:7-JAN-98  04:54:32  EI+  Voltage  SIR 70P
305.8987 Exp:DB225
Sample Text:177/182-184/209  TLI#44376A  File  Text:177/182-184/209  TLI#44376A
100%                               A4.23E4

 80J

 60 j

 40J

 20 j

  OJ
     22:12  22:24  22:36  22:48  23:00  23:12  23:24  23:36  23:48
File:P980100  #1-922 Acq:7-JAN-98  04:54:32  EI+ Voltage SIR  70P
315.9419  Exp:DB225
Sample Text : 177/182-184/209  TLI»44376A File Text : 177/102-104/209 TLIH44376A
100%          i                     23;05

  80J
                                                                            _1.6E4

                                                                            Ll.3E4

                                                                            19.9E3
                                                                            L6.6E3

                                                                            L3.3E3

                                                                            LO.OEO
                                                     24 S 66 ' 24!12 ' 24124 ' 24:36  Time
  20_:
   0.
                                                                            _1.6E6

                                                                            L1.3E6

                                                                            19.5E5

                                                                            L6.3E5

                                                                            L3.2E5
22:12  22:24  22:36  22:48  23:00  23:12  23:24  23:36  23:48  24:00  24:12  24:24
                                                                                      24:
                                                                            I- n . OEO
                                                                            36  Time

-------
 TLI Project:
 Client Sample:
44376A
178-181/226
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U98003
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAJN
194-59-15B-D
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst

12/17/97
12/29/97
01/06/98
n/a
U980026
BB

Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:

SPMIT204
UF51058
U980025
n/a
n/a
n/a



Analytes
2.3,7,8-TCDD
1,2,3,7.8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
l,2J,4,6,7,8-HpCDD
1,2.3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2^,7,8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
1,2^,4,7,8.9-HpCDF
1,2.3,4,6,7,8.9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt fng)
ND
ND
ND
0.01
EMPC
0.04
0.14
0.07
EMPC
0.03
0.08
0.03
0.04
ND
0.14
ND
0.10

Amt {ngj
0.04
0.01
0.03
0.08
0.30
0.36
0.28
0.18
-.' "-WL ^EMPC " ' -•'..
0.005
0.008
0.01

0.01



,0-02




0.009

0.01


fiumber DL EMPC
2 0.04
1 0.06
2 0.10
2
10 0.35
10 0.40
6 0.31
2 0.22
Ra*K>



1.16

0.93
0.93
0.76

1.42.
1.36
1.32
1.36

0.88

0.83










RT



32:49

36:03
39:36
24:39

29:16
32:02
32:09
32:37

35:01

39:48










Flags



j 	
j_
j_
JB_
B_
J_
J_
J_
J_
J_



T

Flags



—



	
                                      Page 1 of 2
                                                    MTT7_PSR »I jOI. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                 Printed: 10:21 01/10/98
                                                              238

-------
 TLI Project     44376A
 Client Sample:   178-181/226
        Method 23 PCDD/PCDF Analysis (a)
                    Analysis File:   U980033

^brti^ Standard^
13C,2-2.3,7,8-TCDF
"CB-W.7.8-TCDD
°CirlA3,7.8-PbCDF
l3Ct2-U,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,rlA3,6,7,8-HxCDD
13C,2-U,3.4,6J,8-HpCDF
13C a- 1 .2.3 ,4,6,7,8-HpCDD
13C ,2- 1 A3 ,4,6,7,8 ,9-OCDD

SariogateStaiwteKte {type A)
13C12-2.3,4,7,8-PeCDF
13C,2-U.3,4,7,8-HxCDF
13C,2-U,3,4,7,8-HxCDD
13C,2-U,3,4,7,8,9-HpCDF
; Surrogate Standards {Type A>
37CL,-2.3.7,8-TCDD
Alternate Standards {Type A)
13C,2-U,3,7,8,9-HxCDF
13C12-2,3.4.6,7,8-HxCDF
Recovery Standards
13C,rU.3,4-TCDD
13C12-lA3,7,8,9-HxCDD

Amt. ^1;^"^
2.4
2.4
2.7
2.6
3.0
2.5
3.1
6.0

Amt. fci$
3.9
3.7
3.9
. 3.4
ArraX ^jFi0)
3.3
Arm. ||Bcov«y~x'
60.5
63.7
59.5
67.7
64.3
75.3
63.2
76.3
75.6

^Recovery
98.4
92.4
97.0
85.2
; %Recweiy
83.1
%fiecovery
63.7
68.9



SV. \ V f
40%-130%
40%-130%
40%-130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%


40%- 130%
40%- 130%
40%- 130%
40%-130%



40%-130%
40%-130%



^4lMfc>.- •
0.76
0.80
1.50
1.48
0.49
1.18
0.42
1.02
0.85

Ratto
1.53
0.48
1.30
0.41


Ratio
0.49
0.48
Ratio
0.81
1.22

^..m-^
24:36
25:19
28:34
29:35
32:08
32:48
35:00
36:02
39:36

RT
29:15
32:02
32:43
36:32
RT
25:20
RT
33:23
32:36
RT
25:09
33:07

••<•••••• Flags-: '
—


Ftegs
—
Ftegs
—
Ffegs
—
Flags
—
                    Data Reviewer
                    01/10/98
Page 2 of 2
                                                                        MTn_PSRvl.OI,LARS &IO.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                              Printed: 10:21 01/10/98

                                           259

-------
                         Initial
                                     . . Date...
   Data  Review By:
                                               Calculated Noise Area:
                                            8.88
   The Total Area for each peak with an  ion abundance ratio outside
   ratio limits ha a been recalculated according to method requirements.
   Page No.
   01/10/98
Listing of  0980033B.dbf
Matched GC  Peaks / Ratio / RetT ~Time
   Compound/
   M_Z	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. .
                                                                              Rel.RT Compound.Name..  10..  Flags.
TCOF
304-306
ND
K
K
K
K
K
N
M






304-306
13C12-TCDF
316-318
DC NL 0
D SN 21
22
22
22
23
23
23
24
24
24
24
25
25
26
0
:00
:27 RO
:12 RO
:36
:56 RO
:19
:35
:48
:01
:14
:27 RO
:39
:04
:16
:22
.65
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
13 Peaks

0.
DC NL 0:00 RO
DC ML 23:35
23:51





316-318
TCDD
320-322
KN
KN
D
K
D
D

D


320-322
24:
24:
25:
DC WH 25:
DC WH 25:
:13
36
04 RO
:37
58
-0.89
•81
.12
.59
.70
.57
.72
.81
.81
.77
.89
.60
.76
.81
.77
.70
2
24.71
46.78
67.90
218.84
122.11
176.24
164.62
177.80
196.60
155.96
76.34
436.37
109.81
84.33
46.91
,033.83
0.867-1.079
0.000

29
90
53
73
73
79
85
73
33
188
49
36
19


.54
.35
.12
.55
.48
.80
.60
.58
.21
.41
.28
.76
.30


50
128
92
102
91
98
111
82
55
247
60
47
27,

65-0.89
1.28
0.
0.
0.
0.
1.
0.
0.
4 Peaks

DC NL 0:
22:
23:
D SN 23:
24:
D SN 24 :
D SN 24 :
DC SN 24 :
D SN 25 :
DC SN 25 :
DC SN 25 :
0.
00 RO
47
11
23 RO
08 RO
27
35 RO
48 RO
13
20 RO
41 RO
65-
1.
0.
0.
1.
0.
0.
2.
1.
0.
0.
1.
.74
.71
82
76 19
94
75
89
19
0.89
18
79
71
58
64
69
41
22
73
22
36
3 Peaks
12.64
416.06
44.54
147.67
,017.23
120.29
15.52
13.23
,329.73
TCDF / TCDD
5.12
109.60
69.15
3.24
29.98
11.78
10.58
6.11
38.61
6.39
3.59
208.73


18.
66.
8,205.
131.




.51
56
13
98




26.
81.
10,812.
67.



.34
.49
.73
.69
.14
.00
.00
.38
.63
.96
.53
.57
.61

0.872
0.902
0.919
0.932
0.948
0.959
0.967
0.976
0.985
0.994
1.002 2378 -TCDF AN
1.019
1.027
1.072


J
J
J
J
J
J
J
J
J

J
J
J

0.959-1.041


03
11
10
96


0.000
0.959
0.970
0.984
1.000 13C12-2378-TCDF ISO
1.019
1.041
1.056











48.
28.

13.








49
74

04








61.
40.

20.







0.895-1.047

11
41

33







0.000
0.900
0.916
0.924
0.953
0.966
0.971
0.980
0.996
1.001 2378 -TCDD AN
1.014


J
J

J







.Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 10:21 01/10/98
                                                                                                          280

-------
   Page No.     2
   01/10/98

   Compound/
   M_Z.... QC.Log Omit Why
Listing of (J980033B.dbf
Matched GC Peaks / Ratio / Ret.  Time
.RT.  OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
37C1-TCDD
328
328
13C12-TCDD
332-334





332-334
PeCDF
340-342




D
M

M
AN


D
DC NL 0:00
23:58
25:20
25:35
25:42
25:49
25:59
26:04
26:38
26:51
9 Peaks
0.65
DC NL 0:00 RO 2
24
25
25
25
25
:09
:09
:19
:39
:50
RO 1
0
0
0
RO 1
5 Peaks
1.81
254.56
12,670.80
110.58
130.90
104.66
22.08
43.97
12.24
17.32
13,367.11
-0.89
.19 14.53
.08
.81 21
.80 15
.82
.02
37
77.24
,411.05
,239.33
602.63
146.11
,476.36
mr*r\r\ /
1.32-1.78
DC NL 0
26
27
27
27
D SN 28
28
28
28
28
28
28
D SN 28:
:00
:35
:34
:43
:52
:02
RO 0
.78
1.52
1.
.32
1.39
RO 1.31
RO 0.48
:11 1.51
:18 1.55
:30
:35
:44
:52
:59
29:16
29:24
D

D
340-342
13C12- PeCDF
352-354





D SN 29:44
DC SN 29 :
D SN 30:
55
14
1.55
RO 1.
1.
1.
RO 0.
1.
1.
RO 1.
RO 0.
1.
12 Peaks
27
33
52
51
42
70
23
22
33
1,
5.53
163.33
58.77
322.20
67.35
19.03
99.50
187.95
76.80
60.71
60.44
102.27
8.34
126.65
166.85
36.90
3.06
22.62
492.82



254.56
12,670.80
110.58
130.90
104.66
22.08
43.97
12.24
17.32
47
9,574
6,793
270
83
.15
.65
.46
.80
.82
43
11,836
8,445
331
82
0.
0.
.64
.40
.87
.83
.55
.921-1.079
0.000
0.947
1.001 37C1-TCDD CLS
1.011
1.015
1.020
1.026
1.030
1.052
1.061
921-1.079
0.000
0.954
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.020










98
33
187
40

59
114
46
36.
34.
61.

74.
104.





.60
.46
.23
.94

.80
.28
.70
.90
.53
,75

21
99





64
25
134
31

39
73
30.
29.
25.
40.

52.
61.




1.32-1.78
DC NL 0:
27:
28:
28:
29:
29:
00
42
34
50
03
15
RO 11.
1.
1.
RO 1.
RO 1.
1.
55
54
50 14,
86
86
53 13,
0.56
588.08
537.90
385.25
79.84
822.53

356.
8,715.
281.
58.
8,351.

51
04
03
15
70

231.
5,822.
151.
31.
5,470.
0.

.73
.31
.97
.24

.70
.67
.10
.10
.91
.52

.44
86




925-1.065
0.000
0.931
0.965
0.970
0.975
0.981
0.987
0.991
0.998
1.001 12378-PeCDF AN
1.006
1.011
1.015
1.025 23478-PeCDF AN
1.029
1.041
1.047
1.058



J
J
J
J

J
J
J
J
J
J

J
J




0.860-1.140

57
86
08
31
83
0.000
0.970
1.000 13C12-PeCDF 123 IS2
1.009
1.017
1.024 13C12- PeCDF 234 SUR1






Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 10:21 01/10/98
                                                                             261

-------
Page No.
01/10/98
Compound/
M_Z .... QC .
3 Listing
Matched


Log Omit why . .RT.

OK
29:35 RO
29:45
30:13 RO
352-354
PeCDD
356-358
of U980033B.dbf
GC Peaks / Ratio /



Ratio Total. Area. . .
1.04
1.62
1.26
8 Peaks

DC NL 0

:00
27:49






D
D
D
D

356-358
13C12- PeCDD
368-370

DC SN 27
28
DC SN 28
28
DC SN 29
DC SN 29
D SN 29
D SN 29
D SN 29
D SN 29
DC SN 30
:57
:31
:42
:51
:00
:06
:17
:27
:36
:43
:05
1
RO
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
RO

.32-1.78
1
0
0
1
1
1
1
1
2
0
1
1
3
.27
.95
.65
.83
.11
.78
.26
.18
.08
.85
.22
.25
.32
3 Peaks

DC NL 0
28

:00
:31
28:39


DC SN 29
29
:00
:35
1.
RO
RO
RO
RO
194 . 29
65.28
39.93
29,713.10
• Dm fonts' /
reujr /
0.46
68.98
1.96
55.08
7.65
42.25
7.78
6.38
19.56
8.54
10.91
10.22
4.00
166.31
Ret. Time

Area . Peak .


.1. .
118.10
40.34
24.27




Area . Peak . 2 . .
113.27
24.94
19.33


Rel.RT Compound. Name. . ID.. Flags
1.036
1.041
1.058
D«f*nn Bfc* 1 1 nua _ •



41.93

39

27









.49

.06









44

21

15








32-1.78
1.16
2.25
0.97
2.30
1.48
29:43
30:10
RO
30:20

368-370
HxCDF
374-376
30:
28
RO
1.72
1.
02
1.46
0.
7 Peaks
1. OS-
DC NL 0:
00

31:04

D







M

D
31:
D SN 31:
31:
31:
DC SN 31:
32:
32:
32:
32:
32:
DC SN 32:
D SN 33:
13
23
30
41
47
02
09
16
25
37
53
27

RO
RO

RO


RO
RO

RO
RO
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
6.
98

1.43
39
14
17
89
64
13
76
36
32
45
03
36
12
2.08
0.36
14.79
10.58
5.69
8,550.21
1,242.39
29.83
18.92
16.16
9,882.88
PeCDD /
17.96
123.45
247.83
14.89
20.32
23.05
3.32
228.93
92.41
24.57
36.92
114.70
2.67
18.48

13
6


.05
.43

5,099.89
784.
18.
11.
9.
.80
,13
.24
.82

0.935-1.022

.22

.60

.19








0.000
0.940 j
0.945
0.964 J
0.970
0.975 J
0.980
0.984
0.990
0.995
1.001 12378- PeCDD AN
1.005
1.017

0.865-1.135

5.80
6.63

3,450.

,32
457.59
17.72
7.
10.
68
00
0.000
0.964
0.968
0.980
1.000 13C12- PeCDD 123 IS3
1.005
1.020
1.025
1.030



65.
133.

14.
12.

131.
52.
15.
20.
66.



88
83

92
25

74
59
88
44
00



57.
114.

9.
10.

97.
39.
10.
19.
0.962-1.047

57
00

07
80

19
82
97
87
48.70




0.000
0.967 J
0.971 J
0.977
0.980 J
0.986 J
0.989
0.997 123478-HxCDF AM J
1.001 123678-HxCDF AN J
1.004 J
1.009 J
1.015 234678-HxCDF AN J
1.023
1.041
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 017,

-------
  Page No.
  01/10/98
Listing  of 098003361dbf
Matched  GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Hel.RT Compound.Name..  ID..  Flags.
  374-376
                       9  Peaks
                                              912.18
13C1J-HXCDF
384-386








384-386
HxCDD
390-392





•
M
390-392
PL3C12- HxCDD
402-404





402-404
HpCDF
408-410



D
DC NL 0
31
31
DC SN 31
32
32
32
33
33
33
DC SN 33
:00
:04
:16
:02
:08
:36
:12
:23
:47
:49
--U.-4J
RO 1
0
0
RO 0
0
0
0
0
0
RO 1
RO 0
-0 . 39 •- -
.27
.43
.46
.78
.48
.49
.48
.47
.49
.45
.65
8 Peaks

DC NL 0
31
32:
DC SN 32:
32:
. 32:
DC SN 32:
33;

:00
:34
:01
:08
:13
:49
:59
:07
1.05
RO 0
RO 0
RO 1
RO 4
1
1
RO 0
RO 1
-1.43
.97
.95
.45
.07
.39
.16
.43
.02
5 Peaks

DC NL 0:
32:
32:
32:
33:
33:

00
12
43
48
07
33
1.05-
RO 1
1,
1,
1.
1,
RO 7.
5 Peaks
-1.43
.63
,24
,30
,18
,22
.69

0.88-1.20
DC NL 0:
35:
35:
35:
D SN 36:
00
01
17
26
33
RO 0.
0.
0.
RO 1.
1.
72
88
93
24
07
8.08
74.28
151.45
6.54
8,645.83
11,340.31
10,964.58
32.04
7,803.98
7.40
9.88
39,019.87

9.19
21.71
97.48
5.82
45.64
22.83
2.19
24.39
212.05
22
47

2,806
.29
.67

.69
3,716.34
3,575
10
2,566
7

.22
.23
.97
.11

51
103

5,839
7,623
7,389
21
5,237
4

•-W.8VO--l.-iJ4-- - 	 	 -"-
0.000
.99 0.967
.78 0.971

.14
.97
.36
.81
.01
.90

0.973
0.997 13C12-HXCDF 478
1.000 13C12-HXCDF 678
1.015 13C12-HXCDF 234
1.033
1.039 13C12-HXCDF 789
1.051
1.052

SOT2
IS4
ALT2

ALT1


HxCDD F*o 1 T nwn ————————— -.-


12.
63,

26.
12.

13.


.02
.08

.54
.28

.50


0.

12.62
43.

19.
10.

13.

.52

.10
.55

.30

958-1.014
0.000
0.962
0.976
0.980
0.982
1.001 123678-HxCDD
1.006
1.010 123789 -HxCDD



J
J

J
AN J

AN J

0.970-1.030
11.22
47.12
6,971.88
9,821.98
13,104.52
14.60
29, 960.10
: HxCDD /
13.20
342.48
78.89
81.13
52.14

26.
3,936.
5,313.
7,214.
50.

06
17
82
47
17

21.
3,035.
4,508.
5,890.
6.

06
71
16
05
52
0.000
0.982
0.997 13C12-HXCDD 478
1.000 13C12-HXCDD 678
1.010 13C12-HXCDD 789
1.023


SOR3
IS5
RS2




160.
38.
49.


10
01
14


182.
40.
39.

0.996-1.049

38
88
77

0.000
1.000 1234678-HpCDF
1.008
1.012
1.044 1234789-HpCDF

AN
J
J
AN
 408-410
                      3 Peaks
 13C12-HpCDF                  0.37-0.51
 418-420        DC  NL   0:00 RO  0.92
                        35:00     0.42
                        35:25 RO  0.80
                                             502.50
                    14.66
                 6,810.63
                    49.54
2,017.35
   27.50
     0.943-1.114
         0.000
4,793.28  1.000 13C12-HpCDF 678 IS6
   34.40  1.012
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 10:21 01/10/98
                                                                                                           263

-------
  Page No.
  01/10/98
         Listing of O980033B.dbf
         Matched OC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z....  QC.Log Omit Why ..RT.  OK  Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
  418-420
  HpCDD
  424-426
  424-426

  13C12-HpCDD
  436-438
  436-438
  OCDF
  442-444
  442-444

  OCDD
  458-460
 458-460

 13C12-OCDD
 470-472

 470-472
DC



DC


DC
DC


DC






DC
DC
DC
DC

DC
DC


DC

DC

36:32
SN 36:59
3 Peaks



NL 0:00
35:17
36:03
SN 36 : 19
NH 36:32
2 Peaks

NL 0:00
35:17
36:02
36:26
36:33
4 Peaks

NL 0:00
SN 36:03
SN 36:24
SN 36:39
39:48
SN 40:26
SN 40:35
1 Peak

NL 0:00
39:36
SN 40:07
1 Peak
0.41
RO 0.14


0.88-1.20
RO 0.82
1.02
0.93
RO 1.67
RO 1.79

0.88-1.20
0.96
0.97
1.02
1.05
1.01

0.76-1.02
1.02
0.99
0.92
RO 0.44
0.83
RO 0 . 13
RO 0.66

0.76-1.02
RO 0.04
0.93
0.89

4,653.39 1,358.87
14.01
11,513.56
• UrW*niP / Ur^T^n C*« 1 1 siua ~ •
. np^ue / npuju r ox .LOWS *

4.30
77.15 38.88
75.31 36.26
3.12
10.53
152.46

19.18
48.62 23.93
7,263.48 3,664.67
68.88 35.32
57.06 28.62
7,438.04
: HpCDD / Octa-CDD and CDF
5.00
7.50
2.78
2.31
189.54 85.98
1.72
2.38
189.54

0.13
207.89 100.13
5.49
207.89
3,294.52 1.044 13C12-HpCDF 789 SOR4
1.057


0.975-1.005
0.000
38.27 0.979 J
39.05 1.000 1234678-HpCDD AN J
1.008
1.014

0.972-1.028
0.000
24.69 0.979
3,598.81 1.000 13C12-HpCDD 678 IS7
33.56 1.011
28.44 1.014

Follows -•- 	 	
0.899-1.101
0.000
0.910
0.919
0.926
103.56 1.005 OCDF AN J
1.021
1.025

0.899-1.101
0.000
107.76 1.000 OCDD AN J
1.013

              0.76-1.02
DC  NL   0:00 RO  1.10         8.47
        39:36     0.85     10,793.67
      1  Peak               10,793.67
4,944.64
      0.996-1.004
         0.000
5,849.03  1.000 13C12-OCDD
                                           IS8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                           Printed: 10:21 01/10/98
                                                                                                          264

-------
  Page No.
  01/10/98
Listing of O980033B.dbf
Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z....  QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
  Column  Description. . .	_ .•Why.'.Code Description.
                                    .. -QC Log .Desc...
  M_Z   -Nominal Ion Mass(es)
  ..RT.  -Retention Time (mm:SB)
  Rat.l  -Ratio of M/M+2 Ions
  OK    -RO-Ratio Outside Limits
  Rel.RT-Relative Retention Time
  «••  End of Report ••»
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       •CM- Below Method Detection Limit
       NL-Channel Specific Noise Level
A-Peak Added
K-Peak Kept
0-Peak Deleted
T-Time Changed
M-Peak Area Changed
N-Name Changed
X-Ether Interference
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 10:21 01/10/98
                                                                                  265

-------
rila:O980033 tl-724 Acq: 6-JAN-1998 22:51:54 GC EH- Volts ye SIS 70S Hoiao:5542
303.9016 rt2 BSOB(256,30,-3.0) PXD(9,5, 3,0 .10\, 22168. 0,1. 00\,r,T) ExpiUDBSUS
TSIASSLX LABS Text :1 78 -1 81/226 TLH44376A
1001
80.
60.
40.
20.
Q
Al


A9.04X5 A1.19X6
1 A5.26E5M7.36E5
. ^_'"E5 TLyA -J\- .-A...Lj/_[_/\..

•22:00 23:00 24:00

8X6 3.6X5


A4.93X5
At a f Olrf
f\ AJi • yjcy
A « 	 .../**•««
'•.2.9ES
'-.2.1X5
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-.7.1X4 	
• n nrn
25:00 ' ' ' 26\00 ' Time
rilet0980033 tl-724 Acq: 6-J3OT-1998 22:51:54 GC KI+ Voltage SIS 70S JToJ.ami6813
305.8987 T:2 B8OS(256,30,-3.0) PXD(9,5,3,0.10\,27252.0,1.00\,
TSIAOGLS LABS Text: 178-181/226 TLIt44376A
1003,
80.
60.
40.

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A2.4


,, ,__, A9.11E5 A1.0BE6 1
Al • 2 OEQ i n t I
A A A nA9 SSri\ f\ 1
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^ . ,w yv. „ / ^V V-./' \ ,/ \y V v VJ\y
'22:00 ' 23:00 24:00
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A A A2.76E5
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.3.1X5
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.1 . 0X5

'^5.-00 	 26:00 	 Tine
fila: 0980033 tl-724 Acq: 6-JAH-1998 22:51:54 GC XX* Voltage SIS 70S Soiae:4S71
315.9419 f:2 3SUS(256,30,-3.0) PKH(9,5,3, 0 .10\,1B2B4 .0,1 .00\,
TRIANGLE LABS Text: 17 8-181/226 TLIt44376A
1001
80:
60:
40:
20:
0'
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A8.21E7 ^2.0X7
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'22:00' ' ' ' ' 23^:00 ' ' '24:00




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.25:00 	 26: 00 	 Tlae
F±J.e:O980033 tl-724 Acq: 6-JZS-1998 22:51:54 GC EH- Voltage SIS 70S Noiae:3S71
317.9389 f:2 BSUB(256,30,-3.0) PXD(9,5, 3,0.10\,14284 .0,1.00\,r,T) Exp-.SDBSVS
TRIANGLE LABS Text: 178-181/226 TLH44376A
1001
80:
60:
40:
20:
0'

Al.OBEB 2.6X7
\



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22:00 ' 23\00 ' ' 24\00




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25\00 ' '26:00 Tlae
rileiU980033 tl-724 Acq: 6-JAS-199B 22:51:54 GC tt+ Voltage SIS 70S
330.9792 t:2 Exp:lO)B5US
TRIANGLE LABS Text: 178-181/226 TLIt44376A
1001
80:
60:
40:
20:
0'
22:26 23:07 23:33 23:55 _-*-,,


25:08 „_ 26±03 26:26 ^5.7X7

22:00 23:00 24:00
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.3.4X7
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0.0X0
' 2S\00 ' '• ' '26:00 ' ' Mac
rn.»:0980033 tl-724 Acq: 6 -JAB- 19 9 8 22:51:54 GC EH- Voltage SIS 70S
375.8364 Ti2 SxptSDBSUS
TSIASGLE LABS Text: 178-181/226 TLIt44376A
1001

80.
60.

40:
20:
0'

22:39 1

1
23:B8
21:3721:57 1. 33\OS if 23:55


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1 I Mil in ill 3*s^93\>57 35 jo i| ^6!je I
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0.0X0
'25)00' ' ' 26:00 Tlae
266

-------
Tilesa980033 tl-724 Acqs 6-JAS-1998 22:51*54 SC XH- Voltage SIS 70S Xoi*esl702 (^-f'&)
319.8965 r:2 BSU3(256, 30, -3.0) PXD(7,5,3,0.10\,6808.0,1.00\,r,T) XxpiNBBSUS {Jz^fa tf
TSIAKSLX LASS Texts 178-181/226 TLH44376A
1001
80.

60.
40.
20.
A
fl
A2.87X5
\ I
/ r\ A1.JOS5 -U.440
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36(00 Time
Tile>0980033 tl-724 Acqs 6 -JAN- 19 9 8 22:51:54 SC D> Voltage SIS 70S Noiae:1445
321.8936 T>2 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,5780.0,1.00\,r,T) XxptXDBSUS
TSIAKSLX LABS Text: 178-181/226 TLII44376A
lOOi
80.

60.

40.
20.

. - .. n
A C-IVrl'
I) A4 . 04X5
A
/ / A2.03X5
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1 \ / \ JA HIM A M-9k5" A3. 45X4
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A1.28X5
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.9.7X4

.7.3X4

.4.9X4
-.2.4X4

36:00 	 Time
TU.esU980033 tl-724 Acqs 6-J7UT-1998 22:51:54 SC XH- Voltage SIS 70S Noises 8986
331.9368 Ts2 BSU3( 256, 30, -3.0) PKD(7,5, 3,0.10%, 35944 .0,1. 00\,T,T) XxpsSDBSUS
TSIANSLX LABS Texts 178-181/226 TLH44376A
1001

80:

50:
40:
30:
0:
»o
1





J
33:00 	 34:00 ' ' 35^00

7X7 -2.6X7


57Q*»7
• / y ft /
A*


.

.2.0X7

.1.5X7
.1 . 0X7
.5.1X6
' 0 . 0X0
' 36:00 	 Time
rile: OS 30033 tl-724 Acqs 6-JJOT-1998 22:51:54 SC EH- Voltage SIS 70S Koiaes4106
333.9338 Ts2 SSUB(256, 30, -3.0) PXD(7,5,3,0.10\,16424 .0,1.00\,r,T) XxpsSDBSBS
TSIANGLX LABS Text: 178-181/226 TLIt44376A
1003
so:

50:
40:
30:
o:
AI.J





y
33:00 34:00 35:00

8X8 3.1X7

US. 45X7



_
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.6.2X6
• o . oxo
'36:00 	 Time
Tile, 0980033 tl-724 Acqs S- JAN- 1998 22:51:54 SC XH- Voltage SIS 70S Noises 906
327.8847 T:2 BSUB(256, 30, -3 . 0) PXD(7,5, 3, 0.10%, 3624 .0,1. 00\,T,T) ElptNDBSUS
TRIANGLE LABS Text: 178-181/226 TLIt44376A
1001
80:
60:
40:
30:
oj






33:00 34 .-00 ' 35:00

A1.27X8 3.2X7
ft



/ V.
.2.6X7
J..9X7
.1.3X7
.6.4X6
O.or.o
' 36:00 	 Time
Tile :U9 800 3 3 tl-724 Acq: 6-JAN-1998 22:51:54 SC XH- Voltage SIS 70S
330.9792 F:2 KxptODBSUS
TSIANGLE LABS Text: 178-181/226 TLIt44376A
1001
80.
60.
40:
20:
o:


33:07 23:33 23:55 _ *<±Si 35±°* 25,23 ^, 	 35^03 ^6:36 r5.7r7





23\00 34:00 35:00





.4.6X7
.3.4X7
.2.3X7
.1.1X7
0.0X0
36:00 	 Time

































































267

-------
FU.», US 80033 tl-724 Acqt 6 -JAN- 19 9 8 22:51:54 SC XI+ Voltage SIS 70S Noil* t 16 80
339.8597 tt2 SSUB(256,30,-3.0) fXO(7,5,3,0.10\,6720.0,1.00\,r,T) XxptSDBSUS
TXIANGZX LABS Tert: 17 8 -181/226 TLH44376A
10K
80.
60.
40.

20.
0
A1.87X6
|l
A9.86X5 II A1.14X6
All \ II
1 A \\A9.07X5 A6.17X5
Jv-\AjJy\J^J(A* j

27\00 ' 28iOO ' ' ' 33:00 '

4.515

41.0525
(1
i A
A /
•\l\ A3. 24X5
y - V^fA: . -j^- 	
LJ.525
'•.2.7X5
'• 1 BfS
r '
13.024

' J0:00 ' ' Mae
Til9tO980033 tl-724 Acqt 6-JJOT-1998 22i51t54 SC XH- Voltage SIX 70S Sola* 1 2144
341.8567 n2 3SUB(256,30,-3.0) PKD(7, 5,3, 0 .10\,B576 .0,1.00\,f,T) XxptODBSUS
TSIASSZX LASS Tart: 178-181/226 TLIt44376A
1001
80.
60.
40.
20.

Al .35X6

A7.37XS
A6.47X5 A
A A \\JL3.65X5 M-05*5
\ A/ 1 A /V \ M /\A
J W ^^-^-, ,—,,-, A-I/V Y K V\^"T 1 VX l \-S V V^A ///
' ,27:00 	 .28:00 ' ' ' .23:00 '

J.U5

45.1325
A 1

V \A^-/V\^^v_^^^A^~. .^
12.425
11.825
Ll. 225
15.124

30:00 Tlae
rile:t»800JJ #1-724 Acqt 6-JAS-1998 22:51:54 SC JET* Voltage SIS 70S Noiae:1272
351.9000 f:2 BSU3(256,30,'3.0) PXD(7,5,3,0.10\,5088.0,1.00\,r,T) XxptSDBSUS
TRIANGLX LABS Taxt: 178-1 81/226 TLIt44376A
ion
80:
50:
40:
20:


A8.72X7 AS. 35X7 -2.4X7
ft « (T
I



_ / v_ . /
37:00 28ioO 23:00




\^_
-.1.9X7
11.427
13.425
14.725

JO: 00 ' Tlae
T±lattJ980033 tl-724 Acqt 6-JXK-1998 22t51t54 SC XI+ Voltage SIS 70S NoiaetllO
353.8970 T,2 BSUB(256, 30, -3.0) PXD(7,5,3,0.10\,440.0,1.00\,r,T) Xrp,SDB5US
TRIASSLX LABS Text, 178-181/226 TLIt44376A
1001
80:
60:
40:
20:

'""I2*7 " V"
1


11 J




_1 . 527
.1.3X7
.9.5X6
.6.3X6
.3.2X6
O.OEO
27:00 28:00 25 1 00 J0:00 Time
r±la, 0980033 tl-724 Acqt 6-JAS-1998 22:51:54 SC KH- Voltage SIR 70S
330.9792 Ti2 XxptODBSUS
TSIAJTELX LABS Tert: 17 8-181/226 TLH44376A
1004
80:
50:
40:
20:
o:
-n?5^5 26'51 a7J$? "'"wfv^ ..^^ ?5^ 	 *$*& 	 -r-r





27:00 ' ' 28:00 25:00 '


29t29 29:49 30*18 5.727





.4.6X7
.3.4X7
.2.3X7
.1.127
0.020
JO: 00 Time
r±le:0980033 tl-724 Acqt 6-JAK-1998 22:51:54 SCSI-1- Voltage SIR 70S
409.7974 Tt2 KxptODBSUS
ZXXAME&f LASS Text: 178-181/226 TLH44376A
1001
80:

60.

40:
20:
o:


i

27 t 20 1 2tt41

35:44 1 Jj II 28:17 t |ln| 1 lAi.JI
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27:00 2flioO 29:00


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29:36

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.J.024

.2.224

.1.524
.7.4X3
0.0X0
JO: 00 Tt«e
268

-------
 fHaiasaoOJJ #1-724 Acq: S-JMf-lSSa 22:51:54  SC EI+  Voltage SIS 70S Koi.ae:142
 355.8546 T:2 3SOB(256,30, -3.0) PKD(S,5,3,0.05\,568.0,1.00\,r,T) ExpittoBSUS
 XSIAHGLS LASS  Text.-178-181/226  TLH44376A
 10n A4.19XS
      27:48  28:00 28:12 28:24  28:36 28:48 29:00 29:12  29:24  29:36  29:48 30:00 30:12 30:24
ril«iU9B0033 tl-724 Acq: 6-JAK-1998 22:51:54 GC EH- Voltage SIX 70S Soia»:112
357.8516 T:2 SSUB(256,30, -3.0) PKD(5,5,J,0.05*,448.0,1.00\,r,T)
TXIA1KLX LASS  Text: 178-181/226  TLH44376A
100\ A4.42XS


  80.
      27:48 28:00  28:12 28:24  28:36 28:48 29:00 29:12 29:24 29:36  29:48 30:00 30:12  30:24
Tile:U980033 tl-724 Acq:  6-JKK-1998 22:51:54 GC EI+ Voltage SIS 70S Noises 108
367.8949 f:2 BSUB(256,30, -3.0) PXD<5,S,3,0.05\,432.0,1.00\,T,X) S*p:lO}B5US
ISIANSLS LASS  Text:178-181/226  TLI»44376A
100*                                                         AS.10X7


  80.


  60.


  40.


  20.
                                                                  7.8SX6
                                                                                                 0.0X0
                                                                                                    Tine
                                                                                                 1. 6X7


                                                                                                '.1.3X7


                                                                                                .9.7X6


                                                                                                '.6.5X6


                                                                                                .3.2X6
      27i48 28:00  28:12 28:24 28:36  28:48 29:00 29:12 29:24 29:36 29:48  30:00 30:12  30:24
rJULe:0980033 tl-724 Acq:  6-JMT-1998 22:51:54 GC EI+ Voltag» SIB 70S S6iaa>95
369.8919 F:2 BSUB(256,30, -3.0) PJO3(5,5,3, 0.05%,380.0,1.00\,r,T) ExpiNDBSUS
ISIAKSLE LABS  Tart: 178-181/226  TLIt44376A
                                                             A3.45X7
                                                                                                 0.0X0
                                                                                                    Tine
 80.

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      27:48 28:00 28:12 28:24 28:36  28:48 29:00 29:12 29:24' 29:36 29't48  30166 3o':12 30:24
File:O980033 tl-724 Acq:  6-JMT-1998 22:51:54 GC EI+ Voltage SIX  70S
330.9792 T:2 ExpiHDSSDS
TSIAXSLE LABS  Tert: 178-181/226  TLIt44376A
                                  28i_42                    29:29 29:41)  	^-^^-ZS^iSL^—
                                                                                                .8.6X6

                                                                                                .6.4X6


                                                                                                .4.3X6


                                                                                                J1.1X6
                                                                                                 0.0X0
                                                                                                    Time
1001


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 60.

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  0.
r5.7X7


.4.6X7


.3.4X7


.2.3X7


kJ-iB7
      27:48  28:    28:12  28:24 28:36 2a':48  29:00  29\12 2»\24 29\36 29:48
                                                                                 30:12 3024
                                                                                                 0.0Z0
                                                                                                    WJM>
                                                                                                         269

-------
 rile:O980033 tl-385 Acq: 6-JJOT-1998 32:51:54 SC XI+ Voltage SIS 70S Boise:5220
 373.8208 Tt3 SSUB(256r30, -3. 0) PKD(7,5,3, 0.10\,208SO .0,1.00\,f,T) XzptSDBSUS
 TSIAHGLX LABS  Text: 178-181/226  TLH44376A
 1003
  00:
  sol

  40J
           A1.34X6
                                    A1.32X6
      A6.S9XS
                   A1.49X5
                                                      A7.52XS
           31tl2 31:24  31:36 31:48 32:00  32tl2 32:24 32s36 32:48 jjloo' 33112'33:24'33t36'jj;40'
 ril»:0980033  tl-385  Acq:  6-JXK-199B 22:51:54 ISC XH- Voltage SIS 70S Soi.au-.3760
 375.8178 T:3  BSUB(256,30, -3.0) PXD(7,5,3,0.10\,15040.0,1.00\,r,T) XxptSDBSUS
 XXIASSLX LABS  Tazt:178-181/226  TLH44376A
 1003,     A1.J.4X6
      A5.76E51
                                                      AS.14X5
  00J         I                       AS. 72X5

  50:

  40:



  o:
    3l'iOO 31:12  31:24 31:36 31:48 32:00 32:12 32:24 32:36  32:48  33:00 33:12  33:24 33:36 33:48
r±le:0980033 tl-385 Acq: 6-JRS-1998 22:51:54 GC XH- Voltage  SIS  70S So±aet3388
383.8639 T:3 BSVB(2S6,30,-3.0) PXD(7,S,3,0.10\,13S52.0,1.00\,T,T) Xxp:SDB5US
TSIAHGLX LABS  Tert: 178-181/226   TLH44376A
1003k                                   A3.72X7       A3.58X7
                                                                                A8.25X4
  80.
  40:

  70:
                                                                              A2.57X7
    31:00  31:12  31:24 31:36  31:48 32:00 32:12  32:24  32:36  32:48 33:00 33:12  33:24 33:36  33:48
rile:U980033 tl-385 Acq:  S-JAfT-1998 22:51:54 GC XH- Voltage  SIB  70S Noise12677
385.8610 T:3 BSVB(256,30,-3.0)  PXD(7,5,3,0.10\,10708.0,1.00\,r,T)  Xxp:SDB5US
TBIAHSLX LABS  Tart* 170-1 SI/775  TLIt44376A
1001                                   A7.62X7        A7.} X7

 00:

 50:

 40:

 70:

  OJ
    31:00  31:12  31:24 31:36  31:48 32:00 32:12  32:24  32:36  32:48 33:00 33:12  33:24 33:36  33:48
 'LLo,0980033 H-385 Acq:  6-J3UT-1998 22:51:54 GC XH- Voltage  SIS  70S
392.9760 T:3 XxptXDBSUS
TSLAKSU: LABS  Text: 178-181/226  TLH44376A
100\    31^07^:17 _^4JLJL   ._ jj,« 5j.—__     J3^*    3a/*24 J^illL- -   _J-U?8         33:34 33:46
 00;

 50:

 40:

 70:
    31:00 31:12  31:24 31:36 31:48  32:00 32:12 32:24 32:36  32:48  33:00 33:12  33:24 33:36 33:48
Tile,0980033 tl-385 Acq: 6-J3UT-1998 22:51:54 GC XH- Voltage  SIS  70S
445.7555 T>3 KxpiHDBSUS
XRIAHGLX LABS  Tmrt: 178-181/226   TLH44376A
                31 23
                                           32:14
_4.J*5

Lj.4r5

'•.2.6X5

'.1.7X5

'•.a.5X4_

'.O.OEO
 3.5X5

.2.8X5

.2.1X5

J..4XS

.7.0X4
                                                                                                     0.0X0
                                                                                                        T±ae
                                                                                                    -2.6X7

                                                                                                    '•.2.1X7

                                                                                                    '.1.6X7

                                                                                                    -.1.1X7

                                                                                                    '.5.3X6
                                                                                                     .0.0X0
                                                                                                        T±ae
    31:00 31:12 31:24  31:36 31:48  32:00 32:12 32:24 32:36 32:48  33:00 33:12 33:24  33:36 33:48
                                                                                                     270

-------
























































389.8156 f:3 BSOB(256,30, -3.0) PaO(7,5,3,0.10\,10188.0,1.00\,r,T) XxptSDBSUS
TXIASGLX LABS Text: 178-181/226 TLH44376A
100.
80.
60.

~~40.

20.
\
A6.31X5
A
fl

/ A2.65X5
	 "• T — A ~" ""
A1.20X5 \







j\ \ ./\ A8.73X4 A1.23X5 ".5™ ., „„
J\t. . . M. - 'V Y L^ ^ _rV,vAT
Tft* . tf OJV« r Si AA*A
3l':36 ' '31:48 32:00 32:12 32:24 32:36 '32:48 ' '33:00 '33': 12 '33:24 33
-1.9X5
.1 . 6X5
.1.2X5

.7.8X4

.3.9X4

36 Tiae
r±la, 0980033 tl-385 Acq: 6-JAJT-1998 22:51:54 GC XX* Voltage SIX 70S B6iae:2616
391.8127 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\f 10464 .0,1. 00\,r,T) XxpsBDBSOS
TXIASGLX LABS Text: 178-181/226 TLH44376A
1001
80.
60.
40.

20^

A4.35ZS
A
I

1 A1.91ES
1 A,
A1.26X5 1 \ \ ,. ,
M 1 1 SCJ \ A1-l>





iCvc
'5X5 A1.06X5
1 \ / T A V V A ' N\ M3 79fSf24 32:36 32':48 ' 33\00 ' '33:12 ' ' 33\24 33:36 Time























































271

-------
rile:U980033 tl-545 Acq: 6 -JAN- 19 9 8 22,51:54 SC EH- Voltage SIS 70S Hoiae,3367
407.7818 f:4 BSUB(256r30,-3.0) PXB(7,5,3t0.10\r13468.0,1.00\,T,T) XxpsSDBSHS
TRIANGLE LABS Text -.178-181/226 TLH44376A
100.
80.
60.
40.

20.
i Al . 60X6
A
/ \
/I
/ 1 A4.91XS
	 	 / 1 AJ.aO*5 A 	 ....._.._. _ A3. 69X5
J X — ~ -S \-^J V_ 	 ^__ 	 .^-A-^^.
-5.2X5
.4.1X5
.3.1X5
.2.1X5

.1 . 0X5

35,00 35', 12 35,24 35:36 35i4B 36\00 36', 12 36', 24 36:36 36\48 37\00 Time
T He > 09 800 3 3 tl-545 Acq: 6 -JAW- 19 9 8 22:51:54 SC SI+ Voltage SIS 70S Soiae:4650
409.7789 f:4 BSUB(256,30,-3.0) PKD(7,5, 3, 0 ,10\,18600 .0,1 .00\,r,T) XxptSDBSOS
TSIASSLX LABS Texts 178-181/226 TLIt44376A
1001
80.
60.
40.

20.
~~

A1.B2E6
A
A


j 1 A3.9BE5
I \ ,-, /\ 47 t-jfff
J V* J~ V / \ ^^V.
-4.9X5
'.3.9X5
.2.9X5
12.0X5

.9.BE4

'35i6o' ' 35\12 35:24 3S':36 3S':48 36'tOO ' 36\12 '36:24 ' ' 36:36 36:48 37'tOO Tiae
rila, 0980033 tl-545 Acqt 6-JAS-1998 22:51:54 SC EI+ Voltage SIS 70S Noiaes4667
417.8253 Tt4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,18668.0,1.00\,r,T) Exp:SDB5US
TSIAHSZX LASS Texts 178-181/226 TLH44376A
1003,
80-
60:
40:
20:
0:
A2.02E7

1 \ A1.36E7
1 \ - /N
A
\ / V
/ v — y v__
-4.9E6
'.4.0E6
''.3.0E6
.2.0E6
.9.9X5
O.OEO
35\00 35:12 35:24 35:36 35\48 36:00 36:12 36:24 36:36 36:48 37\OQ Time
Tile, U9 800 3 3 tl-545 Acq, 6-JJOT-1998 22:51:54 SC EI+ Voltage SIS 70S Soiae:5092
419.8220 r,4 3SOB<256,30,-3.0) PXD(7,5,3,0.10\,20368.0,1.00\,r,T) Exp:HDB5VS
TSIABGLX LABS Text, 178-181/226 TLIt44376A
1001
ao:
60:
40:
20:
o:
A1.JSS7
A
A
A3.29E7
A
{ \
I \ — / v —
-1.2E7
.9.8E6
-7.3E6
-4.9E6
-2.4E6
O.OEO
35:00 35:12 35:24 35:36 35:48 36\00 36:12 36:24 36:36 36:48 J7sOO Tine
Tile:U980033 tl-545 Acq: 6-JZS-1998 22:51:54 SC EH- Voltage SIS 70S
430.9729 Tt4 ExpiSDBSUS
TRIANGLE LABS Texts 178-181/226 TLIt44376A
1004
so:
60:
40:
20:
o:
34:59 35, 07 35: 17 ^^35:33 35:41 35,55 36:22 36,37 36:46 36/^t
~^-^s*-v-^^ ^




.1 . 8X7
-1.5E7
-L.1X7
.7.3X6
.3.7X6
O.OEO
35:00 35\12 35:24 35:36 35:48 36\00 36', 12 36:24 36:36 36:48 37:00 Time
Tile ,0980033 tl-545 Acqt 6-J3UT-1998 22,51:54 SC EH- Voltage SIS 70S
479.7165 r, 4 Eip,SDB5U3
TRIABSLX LASS Text: 178-181/226 TLH44376A
10 0\
ao:
60:
40:
20:
oj
35:09
I

I "j"

•JA/^A /* I/ ^A A rAx A AA/ /^A A/\A^A ^V\A\AA A/AA./VA. A A^A^yv

.3.5E4
.2.8X4
.2.124
.1.4X4
.6.9X3
0.0X0
35:00 ' 35\12 35:24 35\36 35:48 36\00 '36:12 ' ' 36\24' ' ' 36,36' ' '36:48 37:00 Time






























































272

-------
 rULe:U98Q033 tl-545 Acq: o-JAa-iyyo 44:31:31 (.c EI+ voltage SIS 70S noiaoslQSo
 423.7766 T:4 BSOB(256,30, -3.0) PXO(7,S,3, 0.10\f 4384.0,1.00\rr,T) KxpiNDBSOS
 TSIAOSLX LASS  Taxts 178-LSI/326  TLH44376A
 1001      A3.89X5
                                                                                                -1.1X5
      35:12  35ia 35:24  35»30 35i36  35i42 35i48  35S4   ffsOo 36:06  36:12 36ia  36124 36t3o
 rll»,0980033 tl-545 Acq:  S-J2JT-1998 22t51»54 SC XX+ Voltayu SIS 70S Koiaotl338
 425.7737 T>4 BSO3(256,30,-3.0) PXD(7,5,3,0.10\,53S2.0,1.00\,T,T) SzpiXDBStrS
 TBIASGLS LASS  Taxt 1178-181/226  TLH44376A
 1004

  so:
                                    0X0
                                     Time
                                 ^9.3X4
                                 '.7.4X4
                                    0X0
                                     Time
      35:12  35tl8 35:24  35>30 35:36  35:42  35:48 35:54  36:00 36:06  36:12 36:18  36:24  36:30
r±la:U980033 tl-545 Acq:  6-JHT-1998 22:51:54 SC BI+ Voltage SIX 70S Hoiae:4692
435.8169 T:4 BSOB(256,30,-3.0) PXD(7,S,3,0.10\,ia76a.O,1.00\,T,T) XxptXDBSUS
XRIANGLX LABS  Text: 178-181/226  TLH44376A
                                                           A3.f6E7                             -8.9X6
  80.

  60.

  40.

  20.
                                                                                                .0.0X0
      35:12 35:18  35:24  35',30  35:36 35',42  35',48 35:54 36:00  36:06  36', 12 36-18 36:24  36:30    Tiae
r±la:U980033 tl-545 Acq,  S-JKK-1998  22:51:54  SC XI+ Voltage SIS 70S Koine:490L
437.8140 Ti4 BSttB(256,30,-3.0) PXZ>(7,5,3,0.10\,19604.0,1.00\,r,T)  Xzp:SDB5US
TSIASSLE LABS  Text: 178-181/226  TLIt44376A
1001                                                      A3.60X7
  80.

  60.

  40.

  20.
      35:12 35:18  35:24 35:30  35:36 35:42  35:48  35:54 36:00  36,06 36:12  36-18 36:24  36:30
File,0980033 tl-545 Acq: 6-JUT-1998  22:51:54 GC KZ+ Voltaga SIS  70S
430.9729 r>4 KzpiKDBSUS
TBIAHGZX LABS  Text,178-181/226  TZIt44376A
1001
 80.

 60.

 40.

 20.

  0.
            35,17
                     35i
                                                                                 36,22
                                  8.9X6

                                 .7.1X6

                                 .5.3X6

                                 .3.6X6

                                 ^1.8X6

                                 '.0.0X0
                                    Tim»



                                 -1.8X7

                                 .1.5X7

                                 .1.1X7

                                 .7.3X6

                                 .3.6X6
35: 12 35:18  35:24
                         ' 35\ 36 '
' 35',48 ' 3s':54
' jififlff ' 36',12 '
                                                                                  ' 36:24 ' 36\36
0.0X0
   Tia
                                                                                                       273

-------
 rllaiOSS0033  tl-545 Acqt  S-JAS-1998 22t51i54 SC EH- VoltigtJ 5X2 70S KoiaoilJSJ
 441.7438 f.4  3303(356,30, -3.0) tXS(7,5,3,0.10\,5052.0,1.00\,T,'l) SxptXDBSOS
 TSIANSLX LABS  Toxtt 17 8-181/226  TLXt44376A
                             36i00         37i00        38:00         39tOO
Til»tU980033  tl-545 Acqt  6-JXX-1998 22:51,54 SC XH- Voltage SIS 70S Xoiae,1234
443.7399 ft4  BSUB(256,30,-3.0)  PXD(7,5,3,0.10\,4936.0,1.00\,r,T) XxptODSSUS
         LASS Tort: 178-181/226  TLH44376A
               35,00         36,00        37:00         38:00
rU.e,aSB0033 tl-545 Acqt 6-JXM-1998 23:51,54 SC XI+  Voltaffe  SIS  70S
430.9729 r>4 XrptSDBSVS
TRIANGLE LASS  Tart, 178-181/226   TLH44376A
                                                                      39100
                                                                                    40tOO
                                                                                                        T±ae
                                                                                                    -1.7S5
                                                                                                     .1.6KS
                                                                                                     11.4B
                                                                                                     11.2X5
                                                                                                     '-.1.0X5
                                                                                                     .8.7X4
                                                                                                     '.7.0X4
                                                                                                     .5.2X4
                                                                                                     .3.5X4
                                                                                                    \1.7E4
                                                                                                    '.0.0X0
                                                                                                  41i00 Tine
100}
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 401
 301
 201
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                     35t26
                                          36158
           34143
                                                                 38s 40
                                                                                            40:34
               35tOO         36>00        37:00         38tOO
 'ilaiU980033 tl-545 Acqt 6-JUT-1998 22:51:54 SC XI + Voltage  SIS  70S
513.6775 Ti4 XxptBDBSUS
TSIANGLX LASS  T9It.il78-L81/226   TLH44376A
100*                                                 37148
 901,
                       35>36
                                                                      39100
                                                                                    40:00
   -.1.8X7
   11.6X7
   11.5X7
   11.3X7
   -.1.1X7
   19.2X6
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                                                                 38t37
                                                                              39135
               35100
                            36100
                                          37100
                                                        38iOO
                                                                      39100
                                                                                    40,00
                                                                                                 41100
                                                                                                        274

-------
Hle:09B0033  91-545 \cq:  t>-JA*f-1999 23:51:54 tt JST4- Volt*?* 4IB 703
457.7377 Tt4  BSUB(256,30, -3.0) PXS(7,S,3,0.10\,116.0,1.00\,r, T) SxpiSDBSOS
TSIAVGLX LASS  Text: 178-181/226  TLH44376A
100\                    Al. QOX6
  80.

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           39s30         39:36         39:42        39:48         39:54
r±l»:0980033  tl-545 Acq:  6-JZN-1998 22:51:54 GC EC+ Voltage SIX 703 Koiae:696
459.7348 Tl4  BSUB(256,30,-3.0) PXD(7,5r3,O.U\r2784.0,1.00\,r,X) XzpiBDBSUS
TBIABGLX LASS  text: 178-181/226  XLH44376A
loo*
  80.
  60.
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40:00
                -2.1X5

                 .1.7X5

                .1.3X5

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40106  Tla«
           39>30         39:36         39:42        39:48         39:54         40:00
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469.7779 T:4 BSUB(256, 30,-3.0)  PXD( 7,5,3, 0.10%,3864. 0,1. QO\,T, T) SxpiUDBSOS
TRIASGLX LABS  Taxt:178-181/226  TLIt44376A
100\                   A4.$4E7
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                 '.1.6X5

                 .1.2X5

                ".8.2E4

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                -9.4E6

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           39:30         39:36         39:42        39:48         39:54         40:00
File:0980033 tl-545 Acq:  6-JAN-1998 22:51:54 GC SH- Voltage SIS 70S lToiae:2242
471.7750 T:4 BSUB(256,30,-3.0)  Pia>(7,5,3,0.10%r8968.0,1.00*,rrT) Xzp:NDBSVS
XSIAXGLX LABS  Text:178-181/226  TLIt44376A
J004                   AS.8JX7
             ^_ .0. 0X0
              40106  Time
           39:30         39:36         39:42        39:48         39:54
T±le:O980033 tl-545 Acq:  6-JJUt-1998 22:51:54 GC XH- Voltage SIS 70S
430.9729 Fi4 ElpiKDBSUS
XXIANSLX LABS  Tort: 178-181/226  TLH44376A
100\	        	     3?jJ9      39*43    39,47
                                                                                40:00
                -.1.1X7

                .8.9X6

                .6.7X6

                .4.4X6

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                .0.0X0
             40 06  T±ae
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           39:30
                        39:36
                                      39:42
                                                    39:48
                                                                 39:54
                                                                               40:00
                .0.0X0
             40:06  TJJM,
                                                                                                      275

-------
                                                                                 CD
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Peak Locate Examination: 6-JAN-1998:22:50 File:U980033
      Experiment:NDB5US Function:2 Reference:PFK

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TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
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TLI844376A File Text:TRIANGLE LABORATORIES,  INC.
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32:54
                                     33:
                           LO.OEO
                           00  Time
                                            i	1	1	r—i	1	1	1
                                                   LO.OEO
                                                   00  Time
                                                                1.8.4E6

                                                                L6.3E6

                                                                L4.2E6

                                                                L2.1E6

                                                                LO.OEO
33:00  Time

-------
 ile:U980033 #1-385 Acq
389.8156 F:3 Exp:NDB5US
Sample Text: 178;-181/226
100*.
                      6-JAN-1998 22:51:54 GC  EI +  Voltage SIR 70S

                      TLI#44376A File  Text:TRIANGLE LABORATORIES,  INC.
                                       A1,35E5
      i — i — | — i — i — i — i — i — I — i — i — i — i — i — r
      32:36 !32:42  32:
File:U980033 #1-385 Acq:
391.8127 F:3 Exp:NDB5US
Sample Text:178-181/226
100%,
                          i — i — i — i — i — I — i — i — i — r1! — I — r-"i — i — i — i — i — i — i — i — i — i — f i i — i — i — i — r-1 — i — i — i — i — I — i — i — i — i — i — p— i — i — i — i — r"-| — n — i — I — i — I — i — r
                          48  32:54  33:00  33:06  33:12  33:18  33:24  33:30   33:36  33:42
                          6-JAN-1998 22:51:54 GC EI+ Voltage  SIR 70S

                          TLI#44376A File Text : TRIANGLE LABORATORIES, INC.

                                         A1.33E5
                          48 32:54  33:00 33:06  33:12 33:18  33:24  33:30 33:36  33:42
  OJ
   32:30 32:36 !32:42  32:
File:U980033 #lj-385  Acq:
401.8558 F:3 Exp:NDB5US
Sample Text:178-181/226
100*.
                                                                                          O.OEO
                                                                                             Time
                                                                                       .3.4E4

                                                                                       .2.7E4

                                                                                       .2.0E4

                                                                                       .1.4E4

                                                                                       .6.8E3

                                                                                       O.OEO
                                                                                          Time
                          6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S

                          TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
                                           33:07
32:30  32:36  32:42  32
                          48  32:54  33:00 33:06  33:12 33:18  33:24  33:30  33:36  33:42
                                                                                           O.OEO
                                                                                              Time
                                                                                                       O
                                                                                                       CO
                                                                                                       C\J

-------
TLI Project
  lient Sample:
 C
                   44376A
                   178-181/226
                                         Method 23 TCDD/TCDF Analysis (DB-225)
                                          ^                   Analysis File:   P980101
Client Project
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight
GC Column:
Gulp Aluminm
M23TRAIN
194-59-15B-D
1.000
n/a
DB-225
n Alloys
Date Received: 12/17/97
Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Dilution Factor: n/a
Blank File: P980094
Analyst JM

Spike File:
ICaJ:
ConCal:
% Moisture:
% Lipid:
% Solids:

SPC2NF04
PF22206
P980092
n/a
n/a
n/a



                                                                           RT
2,3,7,8-TCDF
                              0.03
                                                                  0.78
        23:06
                                                                                   B
 tleirjial Standard
                                                    .actimtts.
                                                                 Ratio
                                                                           RT
13Cir2,3,7,8-TCDF
                              3.1
                                            76.5
                                                     40%- 130%
0.77
23:05
^Recovery Standard
                                                                 Ratio
                                                                           RT
                                                                                  Flags
I3C,2-U,3,4-TCDD
                                                                   0.80
                                                                          21:54
                     Data Reviewer
                                                             01/09/98
                                         Page 1 ol"
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                       Printed: 10:1601/09/98
                                                                                      281

-------
                         Initial
                                     ..Date.
  Data Review By:
                      Calculated Noise Area:
                                             O.S3
  The Total Area for each peak with an ion abundance  ratio outside
  ratio liaits has been recalculated according to aethod requirements.
  Page No..
  01/07/98
.Listing of P980101B,dbf __
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z....  QC.Log Onit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
TCDF
304-306 DC NL 0:00
18:27
DC SN 18:40
19:27
19:35
19:42
19:53
DC SN 20:09
20:19
20:28
20:37
20:47
21:09
DC SN 21 : 21
21:36
DC SN 21:42
21:51
22:06
DC SN 22:13
DC SN 22:20
22:31
DC SN 22:40
22:58
23:06
23:19
23:36
23:44
24:31
DC SN 25 : OS
DC SN 25:07
DC SN 25:15
304-306 20 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 21:24
DC WL 21:36
DC WL 21:51
23:05
23:42
DC WH 25:09
316-318 2 Peaks
0
RO

RO
RO
RO



RO

RO


RO

RO

RO
RO
RO
RO




RO
RO
RO
RO
RO

0.
RO
RO



RO
RO

.65-0.89
0.71
1.03
0.71
0.63
1.31
0.92
0.80
0.74
0.78
0.56
0.71
1.00
0.70
0.68
0.99
0.89
1.29
0.66
0.19
0.33
0.59
0.38
0.81
0.78
0.83
0.72
0.50
0.54
1.00
1.25
0.62

65-0.89
0.96
2.31
0.65
0.81
0.77
0.93
0.64

1.59
3,35
0
5
2
5
3
2
7
3
12
3
.70
.01
.50
.84
.00
.30
.84
.10
.75
.86
23.52
1

2
1
3
1

3
1
5
2
9
.94

.18
.85
.03
.33

.43
.35
.28
.17
.70
1

3
1
3
1

4
2
7
2
13
0.792-1.101
0.000
.89 0.799

.48
.41
.30
.67

.41
.43
.47
.18
.82
0.74
8
.32
4
.63
4
.70
1.51
4.27
6.11
3
2
.11
.44
2
3
.41
.67
0.14
0.44
6.
34
2
.76
4
.66
0.48
5.15
9.
7.
8.
5.
3.
0.
0.
1.
134.
49
20
00
77
17
27
35
10
59
2,
4.
.31
.17
3.26
3.35
2.51
1.38








2
5.
3,
4,
.84
.32
.94
.65
4.99
2.56








0
0
0
.809
.843
.848
0.853
0.861
0
.873
J

J
J
J
J

0.880
0.887
J
0.893
0.900
J
0.916
0.925
0.936
0.940
0.947
0.957
J
J
0.962
0.968
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.

975
982
995
001 2378 -TCDF AN
010
022
028
062
087
088
094

J

J



J
J




0.957-1.043
2.
0.
10.
34.
1,333.
3.
11.
1,337.
66
57
56
03
50
77
84
27




579.
1.






79
99






753.
2.






71
13


0.
0.
0.
0.
1.
1.
1.

000
927
936
947
000 13C12-2378-TCDF ISO
027
090









Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 06:39 01/07/98
                                                                                   282

-------
  Page No.
  01/07/98
Listing of P980101B.dbf
Matched GC Peaks  / Ratio /
Ret.  Tiae
  Compound/
  M_Z	 QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
13C12-TCDD
333-334








332-334

DC




DC
DC
DC
DC


ML




SN
WH
WH
WH
4

0:
20:
21:
21:
22:
22:
24:
24:
24:

00
29
37
54
41
52
09
29
58
n
RO
DO




RO
RO
RO
----- ADOVI
65-0.89
1.
0.
0.
0.
0.
0.
1.
0.
1.
84
48
80
80
74
83
01
39
24
Peaks
:: n_uc / iv-uu roX-LOwa ----------------------
	 	 	 0.908-1.093- . .. 	 .. 	 	 	



1,





2,
1
5
913
255
13
1
1
3
2
187
.20
.20 2.26
.31 406.07
.82 559.54
.35 5.69
.06
.59
.33
.99
.68
0.
4.69 0.
507.24 1.
696.28 1.
7.66 1.
1.
1.
1.
1.

000
948
000
013
049
058
117
133
155



13C12-2378-TCDD 131
13C12-1234-TCDD RSI






  Column Description	   'Why* Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time (mm:as)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO-Ratio Outside  Limits
 Rel.RT-Relative Retention  Time
  • •• End of Report
       WL-Below Retention Tiae Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
303.9016 Szp ,00225
TBIANSLS LABS Texts 178-181/226 TLH44376A
1004 23:06
95.
90.
85.
80.
75.
70.
65.
60.
55.
50.
45.
40.
35.
30:
25.
15:
10:
5:
o-
rUa
315.
TRIA
1001
95:
90:
85:
80.
75:
70:
65:
60:
55:
50:
45.
40.
35.
30.
25.
20.
15:
10:
5:

I
1


1 i
i
i
J
T 	 	 	 ._
1 :"
"'" ,
.
i 1 \3i
i in «i in


T
in
w>y »
1
'•"
i
U 33:55 \
T 1 Ml 21:48 I 24:15 L
F 1 M ilnl ^ik T-"J\
V W wms> WMMlU/i

^^(.u)"-^^
j^C-c ' ._ l- T*»
T
22:36 22:48 23': 00 23:12 23:24 23': 36 23:48 34:00 24:12 24:24 24:36' 24\ 4 8 ii.-OO ' '25,12 ' 25:24
,P980101 H-923 Acq:7-JZa-9a 05:43:24 XI+ Voltage 5X5 70P
9419 Xxp,DB225
BGUS LAB3 Tart: 178-181/226 TLH44376A
23:05
I
n


































23\36 22:48 33': 00 23': 12 23': 24 23:36 23:48 34:00 24:12 24\24 24:36 24:48 25:00 25:12 25:24
-.1 . 6E4
Lt.SM
\1.4X4
'•.1.3X4
.1.3X4
'\.I~.~2X4~
ll.lX4
'•.1.0X4
.9.4X3
.8.7X3
.7.9X3
.7.1X3
'-.6.3X3
.5.5X3
•4.7X3
.3.9X3
'•.3.1X3
-.2.4X3
JL.6X3
'-.7.9X2
' 0 . 0X0
T±me
-1.6X6
'•.1.5X6
'.1 . 4X6
.1.3X6
.1.3X6
.1.2X6
'-1.1X6
'.1 . 0X6
-9.5X5
.8.7X5
-7.9X5
.7.1X5
.6.3X5
.5.6X5
.4.8X5
.4.0X5
.3.2X5
.2.4X5
.1.6X5
.7.9X4
.0.0X0
Time
284

-------
\Kla:P9B0101  41-923 Acq:J-JAH-SB 05:43:24 EH- Voltay* as 70P
303.9016 BSUB(2S6,30,-3.0)  PXD(5,3,1, 0.10\r1313.0,Q.OQ\,r,T)  Xlp:DB22S
TBIANGLX LABS  Tart.-178-181/226 TLH44376A
                                    A9  0X4
                                                           A4.17X4

                                                                 A3.35X4
                                                                             A3.. 38X4
                                                                                      A4.83S3
          19:00        20:00       21:00       22:00       23:00        24:00
ttla:P9S0101 tl-933 Aeqi7-JJOt-98 05i43t24 XH- Voltayu SIX 70f So±f»i46S
305.8987 BSUa(256,30,-3.0)  PXD(S,3,l,0.10\,1860.0tO.OO\tr,r)  KxptDB225
XSIAHGLX LABS  Text: 178-181/226 TLH44376A
100*                                A1.38XS
             35100
          19:00       20:00       21:00       22:00       23:00       24:00
rila:P980101 tl-923 Acq:7-JJUT-98 05:43:24 XH- Voitago SIX  70V Stiiao:720
315.9419 BSUB(256,30,-3.0)  PKD(S,3fl,0.10\,28aO.O,0.00\,r,T)  XxptDB225
TSIANGLX LABS  Tart: 178-181/326 TLH44376A
1004                                                       AS  OE6
 80.
 60.
 40.
 20.
             25:00
          19:00       20:00        21:00       22:00       23  0       24:00
rl2e:P980101 tl-923 Acq: 7-JZN-9S  05:43:24 XI+ Voltaye SIS  70P Ooiae:750
317.9389 BSUB(2S6,30,-3.0) PXD(S,3,l,0.10\,3000.0,0.00\,r,T) Xxp:DB225
XRIANGLX LABS  Text: 178-181/226 TLIt44376A
100\                                                       A7.54X6
 80.

 60.

 40.

 20.

  0.
             25:00
          19:00       20:00        21:00       22,00       23:00
rila:P980101 tl-923 Acqi7-JJUT-9S  05:43:24  XX* Vbltaga SIS  70P
375.8364 Xxp:DB225
TXIAHSLX LABS  Ttortt 173-131/226 TLIt44376A
100*18:32   .
24,00
             25:00
                          .1.9X4


                          .1. 6X4

                          1.2X4
                         ,7~.8X3~

                         .3.9X3

                          0.0X0
                             T±m,
.1. 6S6

.1.3X6

.9.5X5

.6.3X5

3.2X5

.0.0X0
   Tiaa



.2.0X6

.1.6X6

1.2X6

8.2X5

.4.1X5

0.0X0
   Tine
          19:00
                      20:00
                                   21:00
                                               22:00
                                                           23:00
                                                                       24:00
                                                                                    25:00
                                                                                                         285

-------
 rU.»:P9BUlUl  tl-923 Acqi7-JZir-98 05,43,24 EI+ Voltage SIS 70P Hoj.t«,321
 319.8965 BSU*(256,30,-3.0) PXD( S ,3,1,0.10\, 1284.0,0.00\rr,P)  Xxp,DB225
 XSIAXSLX LASS  Text, 178-181/226 XLH44376A
 100*       A2.66X4
                20:00            21', 00            22,00            23', 00
 riletP980101  91-923 Acqt7-JUT-98 05,43,24 ZT+  Voltaya SIX  70P Soit»,375
 321.8936 BSU3(256,30,-3.0)  PXD(S, 3,1,0.10\,1500.0,0.00\,r,T) Xxp,DS22S
 TBIASGLX LASS Texts 178-181/226 TLH44376A
 100\  .
                                                                                  24100
                20', 00            21,00           22',00           23:00
\T±2aiP980101 tl-923 Acq,7-JJUt-98 05,43124 XI+ VoltAge SIS 70P Soiae,417
1327.8847 SSUS(256,30,-3.0) PXD(5,3,l,0.10\,1668.0,0.00\,rrT) Xxp:DS225
TSIABSLX LASS  Texts 178-181/226 XLH44376A
                                          AB.56X6
  80.

  60.

  40.

  20.
                20', 00            21,00           22,00           23', 00
r±letP980101 tl-923 Acq,7-J7Ut-9B 05,43,24 SI+ Voltage SIS 70P SOia«,623
331.9368 SSUS(256,30,-3.0) PXO(5, 3,1, 0.10\f 2492.0,0.00\,rrf) Erp,DS225
TXIANGLZ LASS  Text, 178-181/226  TLIt44376A
100}                                          AS.f0X6
 80.

 60.

 40.

 20.
                                          A4.06E6
                20', 00           21', 00            22', 00           23', 00
rlle,P980101 tl-923 Acq,7-JXN-98  05,43,24 KH- Voltaye SIS 70V SolBe,338
333.9338 SSUS(256,30,-3.0) PKD(5,3,1,0.10\,1352.0,0.00\,F,r) XxptDS225
TXIAIKLX LABS  Tortt 178-181/226 TLH44376A
10 0\                                          A6.96S6
 801

 601

 401

 201

  0.
                                         AS.07X6
                                                                                  24100
                                                                                  24100
                                                                                  24100
   '.0.0X0
25100  Tim.
                                                                                                   25,00
                                                                                                      0.0X0
                                                                                                         rise
                                                                                                     -2.SE6

                                                                                                     '.2.0E6

                                                                                                     '.1.5X6

                                                                                                     ".9.8X5

                                                                                                     '.4.3X5
   .0.0X0
25100  T±jn
  rl.SX6

   J..2X6

   .9.1X5

   .6.1X5

   .3.0X5
                                                                                                     '.0.0X0
                                                                                                  25100  Ha,
  -1.9X6

   '.1.5X6

   11.1X6

   '.7.6X5

  '3.8X5
                20100
                                21:00
                                                 22:00
                                                                 23:00
                                                                                  24:00
                                                                                                     '.0.0X0
                                                                                                  25,00  Urn,
                                                                                                       286

-------
rile:P980101 tl-923 Acq:7-JAJf-98 05:43:24 XI+ Voltage SIS 70P
303.9016 Xxp:DB22S
TRIAKSLX LASS Text: 178-181/226 TLH44376A
1001 21 -.09 21 1 36
80.
60.
40.
20.
0
Tilt
315.
TSIt
lOOi
80.
60.
40.
201
Tile
319.
TSIA
1003
sol
60.
40:
20:
o-
rile
331.
TRIA
1004
80:
«o:
40:
20:
o-
Tile
292.
TRIA
100}
80:
50:
40:
20:
o:
File
330.
TRIA
1003
so:
60.
40:
20:
o:
"I" \ 33,06
A A a/uXAlrl lnTALJK---r 	 --
jH^jiA^iJM/ u/iL-A/ iiir vV",j UuJvL/Y 11 /y\Aj\/\»j 3~»^^K%^**»"'<\^»<1V'"*TV1^<%*^^ Hp^^v.nM^^-wY'



15:00 20:00 21:00 22:00 2J: 00 24:00 25<00
IP980101 fl-923 Acq:7-JJur-98 05:43:24 EH- Voltage SIS 70P
9792 Exp:DB225
NGLX LABS Text 1 178-181/226 TLH44376A
19:0519:3420:00 20:37 21:17 21:59 .32:50 23t33 24:05 24:40 25:18 .
/•^>|.y*VT^<••'•YSfV••>^/Yl^vlAYv"'%tyf>A^y'^^



19', 00 20:00 21> 00 22', 00 23:00 24': 00 25:00
2.J1T4
.1 . SSI
.1.4X4
.9.1X3
.4.6X3
0.0X0
TiMe-
-1 . 6X6
ll.3X6
19.5X5
-.6.3X5
-.3.2X5
'• o.oxo
Time
-1.4X4
'.1.2X4
-.8.7X3
'-.5.8X3
-.2.9X3
'•o.oxo
Time
-1.5X6
.1.2X6
.9.1X5
-.6.1X5
.3 . 0X5
0 . 0X0
Time
,.6.0X6
.4.8X6
.3.6X6
.2.4X6
.1.2X6
0.0X0
Time
.4.9X6
.3.9X6
.2.9X6
.2. 0X6
.9.8X5
0.0X0
Time


















287

-------
Ref, tass    292.9825    Peak top
Height  1,85 volts  Span   286 ppi
Systei f lie naie
Data   file naie
Resolution
Group mater
lonlzatlon lode
Switching
Ref. lasses   292.9825,
A   292.9825
B   383.9816
C   385.8987
D   315.9419
E   317.9389
F   319.8965
G   321.8936
H   327.8847
I   338.9792
J
K
L
1
       1
     El*
 HUME
388.9761
338.9792
331.9368
333.9338
375.8364
Channel   I  338.9792    Peak top
Height   .81 volts  Span  288 ppi
                                                         288

-------
 TLI Project:
 Client Sample:
44376A
193-196
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980034
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-17A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a


Analytes
2,3.7.8-TCDD
1,23,7,8-PeCDD
1.23,4.7,8-HxCDD
1,23,6,7,8-HxCDD
l,2J,7,8,9-HxCDD
1,23,4,6,7,8-HpCDD
1,2,3.4,6,7,8,9-OCDD
2,3.7,8-TCDF
1.23.7,8-PeCDF
23,4,7,8-PeCDF
*23,6,7,8-HxCDF
2.3,4,6J,8-HxCDF
1.23,7,8,9-HxCDF
1,23,4,6,7,8-HpCDF
1,23.4,7,8.9-HpCDF
1,2,3,4.6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Attlti fjffif} s Bt,.-. ;•;•• ^ '•V'JEJUPO ''
EMPC 0.006
0.04
0.02
0.04
0.05
0.12
0.25
0.45
0.14
0.22
0.31
0.12
0.14
0.02
1.2
0.17
0.41

Amt {ng) Number DL pipe
0.31 9 031
0.52 9 0.81
0.53 7
0.23 2
2.2 15 12.
2.9 14 2.9
1.4 12
1.9 4
Ratfo

1.69
1.07
1.28
1.17
0.94
0.81
0.78
1.52
1.48
1.28
1.23
1.32
1.36
1.05
1.20
0.87










prr

29:35
32:44
32:49
33:06
36:03
39:36
24:39
28:35
29:15
32:01
32:08
32:37
33:23
35:01
36:33
39:49










Flags
PRJ
J_
J_
J_
J_
	
B_
B_


	

j^

	


Flags



—




                                        Page 1 of 2
                                                     MTn_PSRvlXlI.LARS6.ia081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
.Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                  Printed: 10:

-------
 TLI Project:      44376A
 Client Sample:    193-196
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980034
internal Standards . •'•;
13C,r2.3,7,8-TCDF
13C12-2,3,7,8-TCDD
13Cl2-U,3,7,8-PeCDF
13C,rU,3,7,8-PeCDD
I3C12-U,3,6,7,8-HxCDF
13C12-lA3,6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
I3C12-U,3,4,6,7,8-HpCDD
13C12-U^,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
13C.2-2,3,4,7,8-PeCDF
13C,rU,3,4,7,8-HxCDF
l3Ci2-U,3,4J,8-HxCDD
13Ci2-U,3,4,7,8.9-HpCDF
Surrogate Standards {Type A)
37CU-2,3,7,8-TCDD
Alternate Standards {Type A)
l3C,2-U,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
13C12-U,3,7,8,9-HxCDD
Amt (ng}
2.4
3.2
3.1
3.4
2.9
3.4
1.6
3.8
7.4
Amt. {jng)
3.7
3.7.
3.9
4.3
Amt $i0)
3.4
Amt: (tig)
3.2
3.1



/ 4«MBMf
60.0
79.6
78.7
86.0
72.7
85.3
40.6
95.1
92.1
^Recovery
93.6
92.8
98.0
107
-% Recovery
85.2
^Recovery
79.0
77.2
,


U'^,T™
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%

40%-130%
40%-130%
40%-130%
40%- 130%



40%- 130%
40%-130%



V^IWfc;/;
0.75
0.81
1.49
1.48
0.48
1.28
0.36
1.04
0.87
R330
1.46
0.47
1.28
0.35


Ratio
0.47
0.48
Ratio
0.82
1.26
^m^
24:36
25:19
28:33
29:35
32:08
32:48
35:00
36:02
39:36
RT
29:15
32:02
32:43
36:32
RT
25:20
RT
33:22
32:36
RT
25:08
33:07
-r-f^r






RO 	
	
—
ftags



RO 	
Flags ^
—
Flags

—
Flags


                     Data Reviewer
           01/10/98
                                       Page 2 of 2
                         MTT2 J>SR v 1J01. LARS «. 10
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:22

-------
                        Initial
  Data Review By:
                                    .Date
                                      C
_L\o,T(
                                            Calculated Noise Area:
                                                                   1.00
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits  has been recalculated according to method requirements.
Page No .
1 Liatina of O980034B.dbf
01/10/98 Matched GC Peaks / Ratio
Compound/
M_Z 	 QC.Log Omit Why . .RT. OK Ratio Total. Area
TCDF 0.65-0.89
304-306
NK
K
K
K
K
K
K







DC (JL, 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
:00 RO
:27
:58
:11
:35
:55
:19
:35
:48
:02
:12
:27
:39
:03
:16
25:31
26:23 RO
304-306
13C12-TCDF
316-318







316-318
TCDD
320-322
NK
NK
K
D
K


M
AN
0.54
0.81
0.82
0.77
0.78
0.79
0.75
0.75
0.80
0.79
0.78
0.82
0.78
0.72
0.79
0.88
0.95
16 Peaks

DC NL 0:
DC WL 23:
23:
24:
24:
25:
DC WH 26 :
DC WH 26:
0.
00 RO
:33
53 RO
12 RO
36
02 RO
04 RO
11 RO
4 Peaks

DC NL 0:
22:
23:
23:
D SN 23:
24:
24:
24:
25:
25:
0.
00
47
11
27
49 RO
10
26
48
15
20 RO
.65-0.89
1.32
0.72
1.27
1.10
0.75
0.92
0.98
0.62
25
312
334
366
1,614
1,037
1,094
924
1, 223
1,130
573
484
2,760
/ Ret. Time
... Area . Peak . 1 .. Area. Peak.
.08
.29
.60
.98
.93
.30
.23
.14
.48
.48
.27
.69
.78
751.82
640
110
98
13,457
.63
.01
.20
.83

139.92
150.48
159.62
707.63
458.58
470.30
396.17
542.62
498.90
250.50
218.34
1,207.35
315.47
283.44
51.52
52.61


172
184
207
907
578
623
527
680
631
2.. Rel.RT Compound. Name. . ID.
0.867-1.079

.37
.12
.36
.30
.72
.93
.97
.86
.58
322.77
266
.35
1,553.43
436
.35
357.19
58.49
55.48


0
0
0
0
0
0
0
0
0
0
0
0
1
1
.000
.872
.893
.902
.918
.932
.948
.959
.967
.977
.984
.994
.002 2378-TCDF AN
.018
. Flags.














1.027
1.037
1.072


J
J

0.959-1.041
14.35
413.
34.
121.
19,665.
277.
16.
11.
.45
.52
,79
36
29
83
10
20, 098.96
65-0.89
0.66
0.69
0.71
0.69
1.05
0.71
0.73
0.67
0.68
O.S2
8.
532.
343.
93.
5.
250.
184.
91.
279.
34.
07
64
42
85
04
37
25
48
00
94

24.80
75.73
8,406.96
143.63





217.62
142.48
38.28

104.16
77.76
36.58
113.00
15.20


19.50
68.81
11,258.
156.



40
66



0.
0.
0.
0.
000
957
,971
984




1.000 13C12-2378-TCDF ISO
1.
1.
1.

0.895-

315.
200.
55.


02
94
57

146.21
106.
54.
166.
29.
49
90
00
40
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
018
060
064

1.047
000
900
916
926
941
955
965
980
997
001 2378 -TCDD AN







J
J

J
J
J
J
PRJ
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                      Printed: 10:22 01710/98
                                                                   291

-------
  Page No.      2
  01/10/98


  Compound/
  M_Z.:.. QC.Log Omit Why
Listing of 0980034B.dbf
Hatched GC Peaks /  Ratio / Ret.  Time
.RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.


D
D
320-322
37C1-TCDD
328








328
13C12-TCDD
332-334




332-334
PeCDF
340-342

D
O



M

A
M


0





340-342
13C12- PeCDF
352-354
25:29
25:39
D SN 25:53
0 SN 26:19
10 Peaks

DC NL 0:00
23:58
25:20
25:44
25:55
26:03
26 : 23
26:28
26:28
8 Peaks

DC NL 0:00
24:09
25:08
25:19
25:38
4 Peaks

DC NL 0:00
26:35
D SN 27 : 12
D SN 27:19
27:35
27:43
27:53
28:11
28:17
28:29
28:35
28:43
28:51
D SN 29 : 05
29:15
29:24
29:44
23:59
30:14
15 Peaks

DC NL 0:00
0.72
0.76
SO 0.62
"0.69












0.65-0.89
RO 2.24
RO 1.01
0.82
0.81
0.69

1.32-1.78
RO 0.88
1.53
RO 2.38
RO 1.30
1.60
1.54
1.54
1.49
1.56
1.48
1.52
1.52
1.57
1.51
1.48
1.66
1.48
RO 2.10
1.76

1.32-1.78
1.38
46.96
59.18
14.50
19.56
1,916.09

0.19
439.39
16,955.30
342.17
65.37
59.30
24.50
12.34
4.42
17,902.79

13.74
105.46
22,343.10
19,872.67
632.46
42,953.69
jve : TCOO /
4.49
1,539.34
29.78
30.47
645.99
3,695.81
883.12
962.00
1,603.48
611.00
740.00
675.38
962.81
26.13
1,106.61
1,329.21
214.69
42.41
105.01
15,116.86

0.62
19.59
25.61





439.39
16,955.30
342.17
65.37
59.30
24.50
12.34
4.42



60.27
10,049.70
8,899.07
257.32



931.57


397.42
2,239.53
535.12
575.00
978.07
365.00
446.00
407.32
588.43

660.41
829.14
127.95
34.98
66.97



27.37 1.007
33.57 1.013
1.022
" -""•1.039 	 	

0.921-1.079
0.000
0.947
1.001 37C1-TCDD CLS
1.016
1.024
1.029
1.042
1.045
1.045

0.921-1.079
0.000
59.58 0.954
12,293.40 0.993 13C12-1234-TCDD RSI
10,973.60 1.000 13C12-2378-TCDD IS1
375.14 1.013

0.925-1.065
0.000
607.77 0.931
0.953
0.957
248.57 0.966
1,456.28 0.971
348.00 0.977
387.00 0.987
625.41 0.991
246.00 0.998
294.00 1.001 12378-PeCDF AN
268.06 1.006
374.38 1.011
1.019
446.20 1.025 23478-PeCDF AN
500.07 1.030
86.74 1.041
16.63 1.050
38.04 1.059

0.860-1.140
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:22fl1ZJOJ98
                                                                             (L\j(~

-------
  Page No.     3
  01/10/98

  Compound/
  M_Z	 QC.Log Omit Why
Listing of 0980034B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.




352-3S4
PeCDD
3S6-3S8













356-358
13C12- PeCDD
368-370






368-370
27
28
28
28
29
30
:42
:11
:33
:51
:15
:14 RO
6 Peaks

DC NL 0
27
28
28:
28
28:
29:
29:
29:
29:
29:
29:
30:
DC SN 30:
1
:00 RO
:48 RO
:17 RO
:31
:40
:51
:01
06
19
26 RO
35
44
04
26
12 Peaks

DC NL 0:
28:
28:
29:
29:
30:
30:
1.
00 RO
31
39 RO
35
43
10 RO
13 RO
6 Peaks
1.48
1.44
1.49 20
1.59
1.46 18
2.50
717.62
22.60
,072.79
527.63
,154.55
27.41
39,522.60
.32-1.78
0.64
1.31
1.22
1.S6
1.73
1.47
1.57
l.SO
1.70
0.73
1.69
1.60
1.72
1.42
3,
32-1.78
0.75
1.77
1.03
1.48 11,
1.47 1,
1.23
3.40
13,
0.23
947.32
98.38
658.66
167.91
404.12
93.98
162.88
167.45
72.01
135.32
86.87
70.26
2.03
065.16
427
13
12,018
323
10,782
26
.95
.32
.00
.69
.30
.83
289
9
8,054
203
7,372
10
.67 0
.28 0
.79 1
.94
.25
.75
1
.970
.987
.000 13C12-PCCDF 123
.011
1.025 13C12-PeCDF 234
IS2

SOH1
1.059


0.
935-1.022
0.000
575
59
401
106
240
57
97
105
43
85
53
44


.82
.80
.06
.34
.23
.47
.64
.39
.77
.00
.46
.41


440
48
257.
61,
163,
36,
65.
62.
59.
50.
33.
25.


.90
.90
.60
.57
.89
,51
.24
06
91
32
41
as


0.940
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.

0.865-
0.20
29. S5
26.06
332.56
680.86
29.66
15.89
114.58

18.
15.
6,755.
1,000.
18.
21.


87
84
44
26
03
20


10.
15.
4,577.
680.
14.
6.


68
32
12
60
69
23

0.
0.
0.
1.
1.
1.
1.

956
964
969
975
981
984
991
995
000 12378-PeCDD
005
016
029

1.135
000
964
968
000 13C12- PeCDD 123
005
020
021

J

J

J
J
. J
J
AN J
J
J






IS3




                                    Above: PeCDD / HxCDF Follows
 HxCDF
 374-376
                DC  NL
1.05-1.43
0:00
31:04
31:13
31:23
31:31
31:41
32:01
32:08
32:14
32:26
32:37
33:23
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
41
37
30
27
28
27
28
23
43
08
32
36
26
671
1,583
157
197
96
1,134.
568.
137.
231.
490.
62.
.48
.79
.81
.30
.10
.03
.29
.03
.55
.49
65
10

388
895
87
110
53
637
313
80
120
279
35

.00
.23
.89
.48
.80
.24
.47
.83
.12
.37
.80

283
688
69
86
42
497
254.
56.
111.
211.
26.
0.962-1.047

.79
.58
.41
.62
.23
.05
.56
.72
.37
28
30
0
0
0
0.
0.
0.
0.
1.
1.
1.
.000
.967
.971
.977
.981
.986
.996 123478-HxCDF
.000 123678-HxCDF
.003
009
1.015 234678-HxCDF
1.
039 123789-HxCDF



J
J
J
AN
AN
J
J
AN
AN J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:22 01/10/98
                                                                      -      293

-------
  Page No.
  01/10/98
Listing  of 0980034B.dbf
Matched  GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total,Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name. .  ID.. Flags.

374-376
13C12-HXCDF
384-386







384-386
HxCDD
390-392

D








390-392
13C12-HXCDD.
402-404




402-404
HpCDF
408-410



D
D

D
408-410
33:27
DC SN 33:44
DC SN 33:46
12 Peaks
1
RO 0
RO 0

.24
.18
.45

118.74
0.74
2.26
5,448.88
65

.76

52

0.43-0.59
DC NL 0:00
31:03
31:12
32:02
32:08
32:36
33:07
33:22
7 Peaks
RO 0
0
0
0
0
0
RO 2
0
.41
.49
.53
.47
.48
.48
.01
.47
7.17
84.01
157.69
11,171.99
14,599.00
13,994.99
22.09
11,024.27
51,054.04
1.05-1.43
DC NL 0:00
31:33
D SN 31:43
DC SN 31:52
32:00
32:13
32:22
DC SN 32:36
32:44
32:49
33:06
7 Peaks
RO 0.71
1.22
1.20
RO 2.22
1.34
1.18
1.15
RO 12.58
1.07
1.28
1.

17

8.42
174.40
4.15
2.26
602.43
364.54
58.41
2.49
50.91
123.14
141.27
1,515.10

27
54
3,593
4,719
4,526
29
3,541

.74
.30
.18
.22
.81
.34
.35

56
103
7,578
9,879
9,468
14
.98

1
1
1

.041
.050
.051

J

0.876-1.124

.27
.39
.81
.78
.18
.63
7,482.92
0
0
0
0
1
1
1
1
.000
.966
.971
.997 13C12-HXCDF 478 SOE2
.000 13C12-HXCDF 678 IS4
.015 13C12-HXCDF 234 ALT2
.031
.038 13C12-HXCDF 789 ALT1










0.958-1.014
0.000
95
.95
78.
45
0.962
J
0.967
0.972
345.08
197.24
31.

26.
69.
76.

.18

.26
,13
05

257.
167.
27.

24.
54.
65.

1.05-1.43
DC NL 0:00
32:12
32:43
32:48
33:07
4 Peaks
1.
1.
1.
1.
1.

35
42
28
28
26

9.50
57.49
9,090.18
12,670.09
14,924.29
36,742.05
0.88-1.20
DC NL 0:00
35:01
35:17
35:26
D SN 35:36
D SN 35:41
36:33
D SN 36:40
4 Peaks
RO 1.
1.
1.
1.
RO 0.
RO 1.
1.
RO 1.

28
05
01
04
80
24
20
92

12.44
2,030.19
442.15
456.68
17.93
16.36
231.09
8.91
3,160.11

33.
5,107.
7,123.
8,308.

76
57
21
36

23.
3,982.
5,546.
6,615.
35
30
23

65
01
22

0.976
0.982
0.987
0.
0.
1.
i!

994
998 123478-HXCDD AN
001 123678-HxCDD AN
009 123789-HxCDD AN

J

J
J
J

0.970-1.030

73
61
88
93
0.
0.
0.
1.
1.
000
982
997 13C12-HXCDD 478 SOR3
000 13C12-HXCDD 678 IS5
010 13C12-HXCDD 789 RS2








1,040.
222.
233.


126.



91
40
17


04



989.
219.
223.


105.


0.996-

28
75
51


05


0.
1.
1.
1.
1.
1.
1.
1.

1.049
000
000 1234678-HpCDF AN
008
012
017
020
044 1234789-HpCDF AN
048











Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 10:22 01/10/98
                                                                            294

-------
Page No. 5
01/10/98
Compound/
M_Z .... QC . Log
13C12-HpCDF
418-420
.. - - 	 M. :

M
418-420
HpCDD
424-426
D

D

D
D
424-426
13C12-HpCDD.
436-438


436-438
OCDF
|42-444
f











442-444
OCDD
458-460



458-460
13C12-OCDD
470-472
Listing of 09800348. dbf
Matched GC Peaks / Ratio /

Omit why ..RT. OK Ratio Total. Area. ..
0.37-0.51
DC NL 0:00 RO 1.06 8.86
	 	 35:00 RO- 0.36 	 4,974.55
35:21 RO 0.14 15.71
36:32 RO 0.35 4,254.55
3 Peaks 9,244.81
0.88-1.20
DC NL 0:00 1.04 3.80
DC WL 35:09 RO 0.32 5.12
35:18 1.05 291.54
D SN 35:33 1.00 12.24
36:03 0.94 308.00
DC NH 36:16 RO 1.45 5.39
DC NH 36:32 RO 4 . 07 7.75
2 Peaks 599.54
0.88-1.20
DC NL 0:00 1.11 15.79
35:17 0.95 75.03
36:02 1.04 10,309.02
2 Peaks 10,384.05
0.76-1.02
DC NL 0:00 RO 1.73 2.40
DC WL 35:11 0.88 5.61
DC WL 35:29 RO 0.40 3.50
35:59 RO 0.61 2.97
DC SN 36:11 RO 1.57 1.78
36:17 RO 1.29 3.95
DC SN 37:18 RO 2.93 0.87
DC SN 38:21 RO 0.53 2.21
38:31 RO 0.18 2.93
38:40 RO 1.15 3.95
38:53 RO 1.80 2.72
39:49 0.87 1,068.35
40:14 RO 1.09 6.56
7 Peaks 1,091.43
0.76-1.02
DC NL 0:00 RO 0.03 0.13
39:36 0.81 512.93
39:54 RO 2.10 4.20
DC SN 40:04 RO 0.48 2.42
2 Peaks 517.13
0.76-1.02
DC NL 0:00 RO 24.20 0.09

Ret. Time

Area . Peak . 1 .. Area . Peak . 2 . . Rel.RT Compound. Name. . ID.. Flags
0.943-1.114
0.000
	 l,520rOO 	 4-, -280. -00- 1.000 13C12-HpCDF 678 IS6 	
4.80 34.83 1.010
1,300.00 3,680.00 1.044 13C12-HpCDF 789 SUR4

0.975-1.005
0.000
0.975
149.11 142.43 0.980
0.987
148.96 159.04 1.000 1234678-HpCDD AN
1.006
1.014

0.972-1.028
0.000
36.54 38.49 0.979
5,253.24 5,055.78 1.000 13C12-HpCDD 678 IS7

Oota-CDD and CDF Follows 	
0.899-1.101
0.000
0.888
0.896
1.40 2.30 0.909
0.914
2.70 2.09 0.916
0.942
0.968
1.38 7.82 0.973
2.40 2.09 0.976
2.59 1.44 0.982
497.25 571.10 1.005 OCDF AN
3.78 3.47 1.016

0.899-1.101
0.000
229.74 283.19 1.000 OCDD AN
4.66 2.22 1.008
1.012

0.996-1.004
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:2201/10/98
             295

-------
  Page No.      6           Listing of 09800348.dbf
  01/10/98                  Matched GC Peaks / Ratio / Ret.  Time

  Compound/
  M_Z.... QC.Log Omit why  ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.

                          39:36     0.87     14,978.56       6,952.25      8,026.31  1.000 13C12-OCDD      IS8
                          40:01 RO  3.36         40.24         71.44         21.29  1.011
  470-472                2  Peaks              15,018.80
  Column Description	 .  'Why' Code Description	  QC Log Desc.
  H_Z   -Nominal  Ion Hass(es)     WL-Below Retention Time Window   A-Peak Added
  ..RT.  -Retention Time  (mm:as)   WH-Above Retention Time Window   K-Peak Kept
  Rat.l -Ratio  of M/M+2  Ions      SN-Below signal to Noise Level   D-Peak Deleted
  OK    -RO-Ratio Outside Limits  
-------
f±le:U9 80034 tl-724 Acq: 6-JAN-1998 23:38:14 SC EH- Voltage SIS 703 Noise: 54 5 5
303.9016 f,2 3303(256, 30, -3.0) PXD(9,S,3,0.10\f21830.0,1.00\,r,T) XxptSDBSOS
TSIAKSLX LASS Tmrt:193-196 TLH44376A
1001
80.
SO.
40.
20.


A1.21X7
\


A1.SOX6 /V\/\ *'lA*6/\ M\ A A / \ *A A
^\^ y\_ j\^. / Y \- 9J V. / \ 7 1 W \ ^ vv V / V^y v ^*. s*_
-.2.7X6
-.2.1X6
Ll . 6X6
.1.1X6
.5.3X5
0.0X0
33:00 ' ' 23,00 24\00 ' ' 35:00 ' ' ' 36,00 ' TJLme
r±le,U980034 tl-724 Acq, 6-JAS-1998 23,38,14 SC XH- Voltage SIX 70S Boiae:10036
305.8987 r,2 3303(256,30, -3.0) PXD(9,5,3,0.10\,40144.0,1.00\,T,T) XxpiUDBSOS
TRIANGLE LABS Text:193-196 TLIt4437SA
1003
80.
60.
40.
20.

Al.


AS. 38X6 A6. 32X6
, .-AT Av\ AWA AA A/
5X7



A4.36X6
fA3.57E6
-3.3X6
.2.6X6
.2.0X6
.1.3X6
.6.6X5
22': 00 23,00 24\00 2s':00 26\00 Time
rlle:O980034 tl-724 Acq: 6-JJOT-1998 23,38,14 SC ET> Voltage SIS 70S Soiae:S337
315.9419 T:2 BSOB(256, 30, -3.0) PXD(9,5,3,0.10\,31348.0,1.00\,rrT) XipsSDSSUS
TSIAKSLX LASS Text:193-19S TLIt44376A
1001
30.
so:
40:
20:
o-

A3.'




_ 1
1X7




V^
2.0X7
.1 . 6X7
.1.2X7
.7.9X6
.3.9X6
O.OEO
' 33\00 	 33:00 ' '34:00 ' ' ' ' 3S\00 	 .25:00 	 Mae
T±letU980034 tl-724 Acq, 6 -JAN- 19 9 8 33,38:14 SC XI + Voltage SIS 70s Itoiae:40SS
317.9389 T:2 3SUB(256,30, -3.0) PKD(9,5,3,0.10\,16220.0,1.00\,T,T) Xxp:KDBSUS
TRIANGLE LABS Teit:193-196 TLH44376A
1003
aol
so:
40:
20:
0:

A1.13X8
n
I



/ V.
-2.6X7
.2.1X7
.1 . 6X7
.1.1X7
.5 . 3X6
O.OEO
' 22\00 	 23:00 ' ' ' '24:00 	 3S\00 	 36\00 	 Time
F±le,U980034 tl-724 Acq, 6-JAN-1998 23,38,14 SC XH- Voltage SIS 70S
330.9792 r,2 XxpiSDBSOS
TRIANGLE LABS Text: 193-196 TLIt44376A
1001
80:
so:
40:
20:
o-

32,03 33,4523,0733,3523,4324,04 ***** 34:51 ^. 3^33^5 ,4436^04_n ^36,42.
I




.5.1X7
.4.1X7
.3.1X7
.2.0X7
.1.0X7
O.OEO
23,00 	 23,00 24',00 	 2S',00 	 26\00 ' ' ' ' ' Time
rile, 0980034 tl-724 Acq: 6 -JAN- 19 9 8 33,38,14 SC EH- Voltage SIX 70S
375.8364 T-,2 XrptSDBSOS
TRIANGLE LABS Text: 193-196 TLIt44376A
1001
80:
60:

40:

20:
o:

26 22


,23,50 23,10
22, 07 32,27 . I , 33,55
II , 1 i i U I 1 1 II 1 34,33 at
i lit h L 1 U , L MM\M 11 if
JuUOIJlAJllliLJI WUUJoilAjnMM^^JL^^
, 35'31 \16,03
1 • O * V J
">0\ 1,1 1
ll II Illli L 1
• ' 3 1 u Mil ill 1 i n 1 Jl i
ir Ml fill IM. m\\t\ U li Ifll
iAi JPiAlLJUJUwIL II IMA JU yiuL
-1.4E4
.1.1X4
.8.3X3

.5.5X3

.2.8X3
-O.OEO
22:00 23:00 24:00 25:00 26,00 Time





























































297

-------
Til»:a980034 tl-734 Acq: 6- JAN- 1998 23:38:14 SC XH- Voltage SIX 70S Bairn* : 16 00
319.8965 T:2 3SUB(356, 30, -3.0) PXD( 7,5, 3,0 .10\,6400.0,1.00\,r,T) Sxp:SDB5US
TXIAHSLX LABS T»xt: 193-196 TLH44376A
10K

80.
60.

40.
30.
a
1





j

_<.7Z5
I
A1.43X6
A'
Al . 04X6
A A1.30X6
A3. 83X5 I A7.7SXS A3. 66X5 M
j\_ J WV^i'VE/\ 'y^ W^V/V^
•
'.3.8X5
-.3.8X5

.1.9X5
-.9.4X4
23:00 34:00 35:00 ' 36:00 	 Time
Til»:O980034 tl-734 Acq: 6-J3UT-1998 33:38:14 SC XH- Voltage SIS 703 Soia»:2434
331.8936 r:2 BSU3(356,30,-3.0) fXD(7,5,3,0.10\,9736.0,1.00\,T,T) KxptBDBSOS
TSIAKSLX LABS Text! 193 -196 TLH44376A
lOOi
80.

60.
40.
30.
n




,

6.4X5

A3. 01X6

A1.46X6 A1.93X6
"/r AXM."ABA^"5_ .
•.5. 1X5
'
-.3.8X5
''.3.6X5
.1.3X5
23[,00 34:00 35:00 26\00 Time
rile:O990034 tl-734 Acq: 6-JAH-1998 33:38:14 SC XH- Voltage SIS 70S Noise: 8674
331.9368 T:2 BSOB(256, 30, -3.0) PXD(7,S,3,0.10\,34696.0,1.00\,r,T) Xxp:SDB5US
TSIAKSLX LABS Text: 193-196 TLII44376A
100]
80.
60:
40:
30:
o-







Al 00X8 C3.6X7
\8.



1 V
9017




.3.0X7
.1 . 5X7
:i . 0x7
'-.5.1X6
0.0X0
' 23\00 ' • ' ' 34:00 ' ' 35:00 	 36:00 	 Time
Tile :U9 800 3 4 tl-734 Acq: 6-JZX-1998 33:38:14 SC XH- Voltage SIS 70S Noiae:3882
333.9338 Ts3 BSVB(256, 30, -3.0) PIO>(7,5,3,0.10\,1553a.O,1.00\,r,T) JExp«JOJB5as
TSIAKSLX LABS Text: 193-196 TLIt44376A
1001

80:
60:
40:
20:
o'-








Al 2 X8 -3.0X7
u.ioxa

.


/ V
\



V

'•.3.4X7
ll . 8E7
ll.3X7
'.6.1X6
" 0.0X0
33:00 ' 24:00 25:00 ' 26tOO ' ' Time
TiletU980Q34 tl-734 Acq: 6-JXS-1998 33:38:14 SC XH- Voltage SIS 70S Noiae:97
337.8847 T>2 BSOB(256, 30, -3.0) PKD(7,5,3,0.10\,388.0,1.00\,F,T) Zxp:HDB5US
TSIAKSLX LABS Text: 193-196 TLH44376A
1001
soj
60:
40:
20:
o:







Al.




"T ^
701T8




^
.4 . 0X7
.3.3X7
-2.4X7
-1 . 6X7
-8.1X6
0.0X0
33': 00 34:00 25:00 	 26:00 Time
Tilu:U980034 tl-734 Acq: 6-J3UT-1998 33:38:14 SC XZ+ Voltage SIS 70S
330.9733 Ft3 XxptODSSUS
TSXAOSLX LABS Text: 19 3 -19 6 XLIt44376A
1004
80.
60.
40:
20:
oj







33:07 33:35 23,43 24:04^ «f«3«f«7 ^^5,33^5:44 _26^04_ 	 ^ ^^ji^S . 1X7
.— ^-^ y




.4.1X7
.3.1X7
.2.0X7
.1.0X7
0.0X0
33:00 ' ' ' 34^00 • • • • 35\tQO 	 36\00 	 Mae
298

-------
Tile>O980034 tl-724 Acqi 6-J3Of-1998 23t38il4
SC EI+ Vbltaga SIS 70S Soia»il364
339.8597 Tt3 BSUB(256, 30, -3.0) PXD( 7,5, 3,0 .10\,5456.0,1.0Q\,T,I) KzptXDBSUS
IXIAHGLX LABS Tart: 193-196 TLH44376A
1001
80.
60.

40.
30.




A3.

1
/

A3.


32X6
A
\
I A
v /v
' 77.00
74*7


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\
-AS'. 3 5X6 l\
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W^w i
78.00
rile r 0980034 01-774 Acq: 6-J3UT-1998 7J.JS.-14



78X6
l\
<\ N
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AS 88X6 *6'
\ A A j
v/\Jv I
29,00
-5.4*5



60X6

\J \^ A1.28X6
'-.4.3X6
'•.3.2X6

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'.1.1X6
0.0X0
JO. 00 Tint
SC EH- Voltaoa SIX 70S Noia»:lS48
J41.8557 n2 BSOB(2S6,30,-3.0) PXD(7,S,3,0.10\,6192.0,1.00\,r,T) XxptODBSUS
TXIASSLX LABS Text:193-196 TLH44376A
1001
80.
60.
•
40:

70:
a-



A5.




Al.


OSES
(\
\
I A/
77^00
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25X6
A
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A A
UJVlMAA /WV-x- .
28iOO
TiletO980034 tl-724 Acq: 6-JA1T-1998 23>38:14

SC EI+
351.9000 T:2 BSVB(256,30,-3.0) PKD(7r5,3,0.10\,724.
29 1 00
-.3.5X6
.2.8X6
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• o . oxo
JO .00 Tina
Voltaya SIX 70S HoiaatlBl
Q,1.00\,r,T) XxftODBSUS
TXIASSLX LABS Tart:193-196 TLIt44376A
1001
80:
50:
40:
70:














' 77.100 '






78:00
T±letO980034 tl-724 Acq, 6-JXK-1998 23i38il4
Al.j




/

SC XI+
353.8970 Ti2 BSUB(256,30,-3.0) PXD(7,S,3,0.10\f524.
['•* A1.08E8




1
29 tOO




\_
3.3X7
-.2.6X7
.3.0E7
'.1.3X7
.6.6X6
O.OEO
J0:00 Time
Voltage SIX 70S Noise -.131
0,1.00\,r,T) XxpiSDBSUS
TXIASSLX LABS Textsl93-196 TLIt44376A
ion
ao:
50:
40:
70:














77l 00 '






78.00
TilotU980034 tl-724 Acqi 6-JZS-1998 7J.J8.14
A8




i

SC XI+
SX7 A7.37X7




^ ,
29\ 00




\_
-.2.2X7
.1 . 8X7
.1.3X7
.8.8X6
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O.OEO
JO: 00 ' Tiae
Voltage SIS 70S
330.9792 T>2 KxptXDBSOS
TRIANGLE LABS Text.: 193-196 TLII44376A
1004
80:
50:
40:
70:
0:

*/~v





26:43 27:23
-V ^ -IT




77:00 '
77.5J7S.07





78^00 '
rU.eiU980034 tl-724 Acqi 6 -JAN- 19 9 8 7J.J8.14
28 1 25






SC XI+
-£K!J





79:00 '
29>30 30:18 C5.3E7
>S*^»^ n "^ AM"" y »*-*V " ^»l* • "^«l . i '«' •*




-4.3X7
.3.2X7
.2.1X7
-1.1X7
0.0X0
JO. 00 ' Tiae
Voltage SIX 70S
409.7974 Tt2 XzptBDBSUS
TRIANGLE LABS Tmxt.il93-196 TLH44376A
ion

80.
50:

40:
70:
0:

26



A,


iJ5


— .
1 I 77:J5
i Vf6'f? ft, i
77.00
78




77.51 ,
78:00
16

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28,39



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79.00 '

29 1 59 ,„ .„
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1 A 30,33
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.1 . 0X4
.5.2X3
0.0X0
J0:00 ' ' Timt
299

-------
 eU.»lU9UOOJ4  tl-72f Acqt  6-JJUI-lyya JJUOlJ.4 GC &I+ Voltage SIS 70S Hoiae: 73
 355.8546 T:2  BSUB<256,30,-3.0) PXD(5,3,3,O.OS\,28a.O,1.00\,r,T)
 TSXAHSLS LABS  Tmxt: 193-196  TLIH4376A
 100\A5.76X6
      27:48 28iOO  28tl2 28t24 28:36  28,48 29tOO 29:12 29i24 29:36'29148' 30>00 30:12'36:24'
TU.esU980034  H-724 Acq:  6-JAS-1998 23:38:14 GC XH- Voltage SIX 70S Noiaetlll
357.8516 f:2  BSVB(256, 30, -3.0)  PXO(5,5,3, 0.05\,444.0,1.00\,r,T) XscptSDSSUS
XSIAOGLX LABS TfJCtt 193-196  XLH44376A
100i.A4.41X6
  801


  60.

  40.

  20.
                   A2.58X6
             A4.48X5A4.89E5
              /A	A  ^
                                                        A5.99ES
                                                        ^A3.34XS   A2.59X5
      27i48 28:00 28:12  28:24 28:36 28:48  29:00 29:12 29:24 29:36 29:48  30:00 30:12 30:24
rlle:O980034 tl-724 Acq: 6-JZK-1998 23:38:14 GC XH- Voltage SIX 70S Uoiae:62
367.8949 Ti2 BSUB(256,30,-3.0)  PXD(5,5,3, O.OS\,248.0,1.00\,f,T)  XzpsSDBSUS
TSIASSLE LABS  Taxt: 193-196   TLIt44376A
lOOi,                                                         A6.76X7


 80.

 60.

 40.

 20.
                                                                  ,1.00X7
      27:48 28,00 28:12  28:24  28:36 28:48  29:00  29:12 29:24 29:36 29:48 30:00  30:12 30:24
rdJ.e,O9S0034 tl-724 Acq: 6-JKK-1998  23:38:14  GC tt+ Voltage  SIX 70S Noise, 78
369.8919 T:2 3SOB(2S6,30,-3.0) PXD(5,5,3, 0.05%,312.0,1.00\,T,T) Exp:lO>B5BS
XXIASGZX LABS  Text: 193-196  TLH44376A
100*                                                         A4.58X7

 80.

 60.

 40.

 20.
                                                                  6.81X6
      27:48 28:00 28:12 28:24  28:36 28:48 29:00  29:12  29:24 29:36 29:48 30:00  30:12 30:24
 •±1»:0980034 tl-724 Acq: 6-J3UT-1998 23:38:14 GC XX* Voltage  SIX 70S
330.9792 T:2 Klp:SDB5US
2SZAMCXS LABS  Tmxt: 193-196  TLH44376A
1004

 80.

 60.

 40.

 20.

  0.
27:53  28:07
 28:25
~~-v~
                                             29:19
                                                                           30:18
                                                                                        .0.0X0
                                                                                            HMO
-1.1X6

 .8.5X5

.6.4X5

.4.2X5

.2.1E5
                                                                                                .0.0X0
                                                                                                    T±ae
                                                                                        2.1X7

                                                                                       .1. 7X7

                                                                                       .1.2X7

                                                                                       .8.3X6

                                                                                       .4.1X6
                                                                                        .0.0X0
                                                                                           Tlae
                                                                                       -1.4X7


                                                                                       .1.1X7


                                                                                       .8.5X6


                                                                                       '.5.7X6


                                                                                       .2.8X6


                                                                                        0.0X0
-5.3X7

'.4.2X7

.3.2X7

.2.1X7

.1.1X7
     27:48  28:00 28:12 28:24  28:36 28:48 29:00  29:12  29:24  29:36 29:48 30:00.30:12  30:24
                                                                                        0.0X0
                                                                                           Tlae
                                                                                                      300

-------
rila:a980034  #1-385 Acq:  6-JXH-1998 23,38:14 SC EH- Voltage SIS 70S SOim»:7755
373.8208 Ti3  3303(356,30, -3.0) PXD(7,5,3, 0.10%,31020.0,1.00\,r,T) XxptXJBSUS
ySIANSZX LASS  Tart: 193-196  TLI944376A
1001     AS. 95X6
  80.
  60:

  40:

  sol
                              A6.37X6
A3.88X
                                                 A3. 79X6
                                                                                AS.58X5
     31,00  31,12 31,24 31,36  31,48 32,00 32,12  32,24  32,36 32,48 33,00  33,12  33,24 33,36 33,48
ril»,U980034 tl-385 Aeqi  6-JAB-1998 23,39,14 SC XI* Voltaye SIS 70S BO±aat5484
375.8178 Tt3 BSUB(256,30, -3.0)  PXD(7,5,3,0.10\,31936.0,1.00\,T,T) XxptBDBSUS
XBIAXGLX LASS   TarC, 133-196  TLH44376A
1001     A6.89X6
  80.

  60:

  4.0:

  20:
                              A4.97X6
A3.84Xi
                   AS. 66X5
                                                A3.11X6
                                                                                AS.30X5
           31il2 31:34 31,36  31,48 32>00 33,12  32t24  32t36 32:48 33,00 33,12  33,24  33,36 33,48
rile»WflOO34 tl-385 Acq:  6-JXK-1998 23,38,14 SC EI+ Voltage SIX 70S Xoieetl310
383.8639 T:3 BSUS(256,30, -3.0) PXD<7,5,3,0.10\,4840.0,1.00\,T,T) XxpiUDBSOS
ZBIASGLZ LABS   Toft: 193-196   TLH44376A
1004                                   A4.72X7
  80:

  60:

  40.

  20:
  oj
                                                      A4.53X7
                                                                        A3.54X7
    31,00 31,12  31:24 31,36 31,48  33,00 32,12 32:24  33:36 32:48 33:00 33,12 33:24  33,36 33:48
Tila:0980034 fl-385 Acq,  6-JJUT-1998 23,38:14  SC XI+ Voltaye SIS 70S Xoiao,29Sl
385.8610 T,3 BSUB(256,30,-3.0) rXD(7,5,3,0.10\,11804.0,1.00\,r,T) Xxp:KDB5OS
TSIASSLX LABS  T&zt,193-196  TUf44376A
100*                                   A9. 8X7        A9.47X7
 80:
 60:
 40:
 20:
  o:
                                                                        A7.48X7
    31:00 31,13  31,24 31,36 31,48  33:00 32:13 32:24 32:36  32:48 33:00 33:12 33:24  33:36 33,48
rile:U980034 tl-385 Acq: 6-JAS-1998 23,38,14  SC EI+ Voltage  SIS  70S
393.9760 T:3 XxptNDBSUS
TSIANGLX LABS  Taxt: 193-196  TLH44376A
        31:07  31:31   31:35    31:51 32,03    32:20   ":34	J2tfp_  _  33^,07  33.23    33l38
10 Oi
 80:
 60:
 40:
 20:
  oj
    31,00 31,12  31,24 31:36 31:48  33:00 32:12 32:24 32,36  32,48 33,00 33:12 33,24 33:36 33,48
rila,U980034 tl-385 Acq: 6-JXS-1998 23,38,14 SC EI+ Voltage  SIS  70S
445.7555 T,3 SxptXDBSOS
TRIANGLE LABS  Tart:193-196  TLH44376A
                                                      33:35                   33:31
                                                                                                    -2.7X6

                                                                                                    '.2.1SS

                                                                                                    .1.6X6
                                                                                                    -.0.0X0
                                                                                                    -2.3X6

                                                                                                    .1.7X6



                                                                                                    .8.7X5

                                                                                                    .4.3X5

                                                                                                     0.0X0
                                                                                                    -1.5X7

                                                                                                    '•.1.2X7

                                                                                                    .8.8X6

                                                                                                    .5.8X6

                                                                                                    '•.2.9X6
                                                                                               0.0X0
                                                                                                  Time
                                                                                                    -2.9X7

                                                                                                    -.2.3X7

                                                                                                    '-.1.7X7

                                                                                                    '•.1.2X7

                                                                                                    .5.8X6
                                                                                              -O.OEO
                                                                                                  S±ae
                                                                                              -3.4X7

                                                                                              -.1.9X7

                                                                                              J..4X7

                                                                                              \-9.6XC

                                                                                              •.4.8XS

                                                                                               0.0X0
    31,00 31,12  31:24 31:36 31:48  33:00  32:12 32:24 33:36  33:48 33,00 33:13 33:24 33:36  33,48
                                                                                               0.0X0
                                                                                                  £!•«
                                                                                                     301

-------
 rU.m,USauOJ4  tl-jas Acqi  6-JAU-1998 JJ:JO:14 CC EI+ Voltage SIS 70S
 389.8156 Ti3  BSVB(256,30,-3.0) PXS(7,5,3r0.10\,9316.0,1.00\rr,T) XxpiSDBSUS
 XSIASSLX LASS  T»xtt 193-196  TLH44376A
 100\                     A3.
  80.
  60.
  40.
  20.
     A9.S9X5
       A
                                                           A6.91X5
                                                                       A7.60X5
                                                                        r\
                                                                                                   .216

                                                                                                 .9.3X5

                                                                                                 .6.9X5

                                                                                                 4.6X5

                                                                                                L2.3X5
          31,36    31>48   32,00    32,13   32:24    32:36    32,48   33,00    33,12
ril»:0980034  tl-385 Acqi  6-JAS-1998 23,38,14 GC KI+ Voltaga SIX 70S Holme,3270
391.8137  Ti3  BSOB(256,30,-3.0) PXB(7,5,3,0.101,13080.0,1.00\,T,T)  XxpiSDBSUS
ZBXAHGU  LASS Text, 193-196   TLH44376A
1001                     A2.57E6
  80.

  60.

  40.

  20.

   0.
                                                                                               .0.0X0
                                                                                    33124   33 36  Time
     A7.8SXS
                                 Al.67X6
                                                          AS.40X5
                                                                      A6.52X5
                                        A2.72ES
         31,36    31:48   32,00    32,12   32,24   32,36   32,43    33:00   33:12
File,0980034 tl-385 Acq: 6-J7UT-1998  23,38,14 GC CI+  Voltage SIR 70S Noise,2729
401.8558 F,3 3SUB(256,30,-3.0) P1O>(7,5,3, 0.10\,10916.0,1.00\,T,X) XxptXDBSOS
TXIAXGLX LASS  Text, 193-196  TLH44376A
10M
                                                                                                -.8.9X5

                                                                                                .7.2X5

                                                                                                .5.4X5

                                                                                                .3.6X5

                                                                                                11. 8X5
                                                                                   33,24    33 36
                                                                                               .0.0X0
                                                                                                  Tin.
00.

60.

40.

20.

 0.
                                                          A7.12X7
                                                       AS.l
         31,36   31:48    32,00   32,12    32:24   32', 36   32', 4 8   33', 00   33', 12
Tlla,0980034 tl-385 Acqs 6-JJOT-1998 23:38,14 GC XH- Voltage SIS 70S Noise,2018
403.8529 Ti3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,B072.0,1.00\,T,T) ElpiSDSSUS
TXIAXGLX LABS  Text, 193-196  TLH44376A
100\                                                                   A6.62X7
                                                          AS.55X7
 80.

 60.

 40.

 20.

  0.
                                                                                   33:24
                                                                                            33:36
         31,36   31:48    32:00   32:12    32:24
Tilu,0980034 tl-385 Aoq, 6-JAS-1998 23:39:14 GC
 92.9760 T:3 SxpiSDBSOS
TRIAHGLX LABS  Text,193-196  TLI944376A
1001
   *"-"     31:
 80.

 60.

 40.

 20.

  0.
                                                                                               1. 8X7

                                                                                              .1.5X7

                                                                                              '.1.1X7

                                                                                              .7.3X6

                                                                                              .3.6X6
                                                   32,36   32:48   33,00
                                                    Voltage SIX 70S
                                                                          33:12   33:24
                                                                                   33,22
                                                                                     ~
                                                                                           33:36
                                                                                               0.0X0
                                                                                                  Time
         31:36   31:48
                         32:00
                                                                                              .0.0X0
                                 32:12   32:24   32',36   32',48    33:00   33:12    33:24   33 36  Timt
                                                                                              -2.4X7

                                                                                              J..9X7

                                                                                              ^..4X7

                                                                                              '.9.6X6

                                                                                              .4.8X6
                                                                                                     302

-------
rila,a980034 tl-545 Acq: 6-JAS-1999 23:38:14 SC EI+ Voltage SIX 70S No±aat3889
407.7818 T:4 BSOB(256,30, -3.0) PKD(7,5,3,0.10\, 15556.0,1.00\,f,T) XxpiNDBSaS
TXIASGLX LABS  Taxt:193-196  TLIt44376A
100S    A1.04X7
 ao:
 50:
 40:
-20:
   o:
                       _  -A3.33X6-
                                                                          A1.26E6
         35,00   35,12    35,24    35,36   35,48    36,00    36,12   36,24    36,36
 rile,U980034 tl-545 Acq: 6-JAN-1998 23,38,14 SC £Z> Voltage SIS 70S Noiae:3049
 409.7789 f:4 SSUB(256, 30, -3.0) fXJ><7,5,3,0.10\,12196.0,1.00\,T,T) XxptXDBSUS
 TSIASSU! LABS  Text: 193-196  TLIt44376A
                                                                                       36,48
ion
 80:


 40:
 20:
        AS.
                    A2.20X6
                                                                          A1.0SX6
        35,00    35:12    35,24   35,36    35,48    36:00    36,12    36,24    36,36
rile:U980034 tl-545 Acq:  6-JAN-1998 23,38:14 SC SI+ Voltage SIS  70S Koiae:3243
417.8253 Fi4 BSUS(256,30,-3.0) ?XD(7,5,3,0.10\,12972.0,1.00*,r,X) XxptSDBSUS
        : LABS  Taxti 193-196  XLH44376A
1004   A1.53E7

                                                                         A1.33E7
                                                                                       36,48
        35', 00    35',12    35:24    35,36    35:48   36:00    36', 12    36:24    36', 36
Tlle,U9a0034 tl-545 Acqt  6-JKK-1998 23,38,14 SC XH- Voltage SIS 70S Noise:3076
419.3220 r,4 BSOS(256,30,-3.0) PKD(7,S,3,0.10\,12304.0,1.00\rf,T) Sxp,XDB5US
TRIANSLS LASS  Textil93-lS6  TLIt44376A
100A   A4.33E7
          A
                                                                         A3.73S7
                                                                                       36:48
        35,00    35,12    35,24    35,36    35,48    36,00    36:12    36:24
rlla,0980034 H-545 Acq:  6-JAK-199B 23,38,14 SC EI+ Voltage SIS 70S
430.9729 r,4 ExptSDSSUS
TRIANGLE LABS  Text: 193-196  TLH44376A
                                                                              36,36
                                                                                      36,48
1001

 80.

 60.

 40:

 201

  0:
                                                35,56    36,07 36,16 36,24 36,32_3&ifjl
                                                                                                    -2.6X6

                                                                                                    '•.2.1S6

                                                                                                    '•.1.6X6

                                                                                                    '.1.0E6

                                                                                                    '.S.~2XS
                                                                                               37, 00
        35,00    35,12    35,24    35,36    35,48    36,00    36,12    36,24
ril»iO980034 tl-545 Acqt  6-JAN-1998 23,38:14 SC XI+ Voltage SIX 70S
'79.7165 Ti4 XxpiSDBSOS
TRIANGLE LABS  Toft,193-196  TLH44376A
100\
                                                                             36,36
                                                                                      36,48
                                                                                                    -2.6X6

                                                                                                    :.2.1Z6

                                                                                                    '•J..6X6

                                                                                                    .1.1X6

                                                                                                    '.5.3X5
                                                                                                   •.o.oxo
                                                                                              37s 00    T±me
                                                                                                   .0.0X0
                                                                                              37:00    Time
                                                                                                    0.0X0
                                                                                              37:00    Time
                                                                                                   -1.6X7

                                                                                                   '•.1.3X7

                                                                                                   '.9.4X6

                                                                                                   -.6.3X6

                                                                                                   .3.1X6
                                                                                               J7.-00
                                                                                                       T±me
        35,00
                35t12    35,24
                                  3St36
                                          35,48
                                                   36,00
                                                            36,12
                                                                    36,24
                                                                             36,36
                                                                                      36:48    37:00
                                                                                                    0.0X0
                                                                                                       Time
                                                                                                      303

-------
ril»,U380034  41-545 Acxjs  6-JAB-1998  23,3t,14 SC XH- Voltmge SIX  705 Koiaas930
425.7737 Ti4  BSOB(256,30,-3.0) ra>(7,S,3,0.10\,3720.0,1.00\,r,T)
TXIASSLS LASS  Taxt:193-lS6   TLH44376A
100$                                                      A1.?9X6
      35,12  35,18  35,24 35,30  35,36 35,42  35:48  35,54 36tOO  36,06 36,12  36,18 36,24  36,30
Tila,U980034 il-545 Acqi 6-JKB-199B  23,38,14 SC XI+ Voltage SIS 70S Koiae,4149
435.8169 Ti4 BSUB(256,30,-3.0) fKD(7,5,3,0.10^,16596.0,1.00\rr,T) Xxp:XDB5US
XSIAKSLX LASS  Text: 193-196  TLH44376A
1001                                                      AS.25X7                              ..1.3X7
 riJ.a,USaOOJ4  #1-545 Acq:  6-JAa-iynu JJUHiJ.4 GC BI+ VoJ-tage SIX 70S Noiaa,969
 433.7766 F,4  SSUS(256,30, -3 . 0)  PKD(7 ,5,3,0. 10\, 3876.0, 1.00\,f,T)  KlptUDBSOS
 TXXAHGLX LASS  T*zt,193-196  TLH44376A
1001

 80.

 60.

 40.

 20.
            A1.49Z6
                                                           A1.49S6
 3.9X3

'.3.1X5

.2.3X5

.1.6X5

.7.8X4
                                                                                                .0.0X0
      35:13  35:18 35:24  35:30  35:36 35:43  35:48  35:54 36:00  36:06 36:13  36:18 36:34  36\30     Urn,
                                                                                               -4.0X5
 80.

 60.

 40.

 20.
      35,12 35,18  35,24 35:30  35:36 35:42 35:48  35:54  36:00 36:06  36,12 36:18  36,24 36:30
Tila,U980034 tl-545 Acqt 6-J3UT-1998  23:38:14 GC KI+ Voltage SIS 70S Noise,3745
437.8140 r:4 BSUS(256,30,-3.0) PXD(7,S,3,0.10\,149aO.O,1.00\,T,T) XxpsSDBSVS
TRIANGLE LABS  Text, 193-196  XLH44376A
1001                                                      A5.06E7

 80.

 60.

 40.

 20.
                                                                                               .1. 0X7

                                                                                               .7.6X6

                                                                                               15.0X6

                                                                                               -2.5E6

                                                                                               .0.0X0
                                                                                                   Time



                                                                                               -1.2X7

                                                                                               .1. 0X7

                                                                                               .7.5X6

                                                                                               .5.0X6

                                                                                               .2.5X6
      35:12 35:18  35:24  35:30 35:36  35:42 35:48  35:54  36:00 36:06  36,12 36,18  36:24 36:30
T±la,U980034 H-545 Acq:  6-JAB-1998 23:38:14 GC XH- Voltage SIS 70S
430.9729 T:4 KlptSDBSVS
XXIAHGLX LABS  Tuxt, 193-196  TLXt44376A
L00\ _35jil3                _   35:36               35:56        36,O7     36:16   36:24
 80.

 60.

 40.

 30.

  0.
                                                                                              -1.6X7

                                                                                              .1.3X7

                                                                                              '.9.4X6

                                                                                              .6.3X6

                                                                                              .3.1X6
      35:12 35:18 35:24  35:30 35:36  35:42 35:48 35:54  36:00 36:06  36,12 36,18  36:24
                                                                                               0.0X0
                                                                                                  Time
                                                                                                      304

-------
Tile, 0960034 tl-545 AC?> 6-JAN-1993 23,38:14 ec EH- voitag* sis  76s Hoimmild9a
  1.7428 Ti4 SSUS(256, 30, -3.0) PKD<7, 3,3,0. 10\,4392.0,1.00\,T,T) XxpiNDBSUS
TSIAXGLX LASS  Taxttl93-196  TLIt44376A
1001
 901
 801
 701
 60.
 sol
 401
 301
 20.
 101
                                                                               A4.97X6
               35,00        36,00         37,00        38:00         39,00
rila.O9800.J4 tl-545 Acqs 6-JA1T-1998 23,38,14 SC XH- Voltage SIS  70S Hoia»i634
443.7399 Tt4 BSUB(256,30,-3.0) PXD(7,5,3, 0.10\,2536.0,1.00\,T,T) Xxp:«DS5US
TSIJUIGLX LASS  Text:193-196  XLH44376A
1001                                                                          AS.
 901
 80.
 70.
 SOI
 30-
 40.
 30\
 201
 101
  03.
                                                                                  40,00
                                                                                  71S6
               .35.00         36:00         -37:00        38:00
r±le:O980034 tl-545 Acqt 6-JXS-199S 33:38:14 GC tt+ Voltage  SIX  70S
430.9729 T:4 XxptSDSSUS
TSIANGLX LASS  Text: 193-196  TLIt44376A
                                                                                  40:00
1003

 aoi
 701
 601
 501
 401
 301
 201
 101
  0.
                                                              38:30
                                                                                       40:22
                  35'13    35:56      J5i." i       37:43       n.        39:18  39:49
    Yt^Y^^^i^i^^^^r^^
               35,00         36,00         37,00        38,00
File,0980034 tl-545 Aoqi 6-JJUT-1998 23,38,14 SC SH- Voltage SIS 70S
513.6775 T,4 XxptSDSSUS
TXUOKLS LASS  Text: 193-196  TLII44376A
1004
                                                                    39.00
                                                                                  40.00
                                                                                                41  00
                                                                                                  -9.2X5
                                                                                                   .8.3X5
                                                                                                   .7.4X5
                                                                                                   .6.4X5
                                                                                                   .5.5X5
                                                                                                   .4.6X5
                                                                                                   .3.7X5
                                                                                                   .2.3X5
                                                                                                   .1.8X5
                                                                                                   .9.2X4
                                                                                                   0.0X0
                                                                                                      tta>
                                                                                                  -1.1X6
                                                                                                  19.6X5
                                                                                                  .8.5X5
                                                                                                  .7.4X5
                                                                                                  .6.4X5
                                                                                                  .5.3X5
                                                                                                  .4.2X5
                                                                                                  .3.2X5
                                                                                                  .2.1X5
                                                                                                  .1.1X5
                                                                                                  .0.0X0
                                                                                                41 00  TLme
                                                                                                  ^1.7X7
                                                                                                   .1.5X7
                                                                                                  11.3X7
                                                                                                  .1.2X7
                                                                                                  .1.0X7
                                                                                                  .8.3X6
                                                                                                   .6.7X6
                                                                                                  .5.0X6
                                                                                                  .3.3X6
                                                                                                  .1.7X6
                                                                                                  .0.0X0
                                                                                               41100  Time
              35100
                            36:00
                                          37:00
                                                       38:00
                                                                    39s 00
                                                                                  40100
                                                                                                41100
                                                                                                      305

-------
 fHa:a9800J4U-545 Acq I6-JAS-i9SS  JJlJotli  ic SI+ Voltage SIX 70S HOimmiSS
 457.7377 Tt4 BSUB(256,30, -3. 0) PXD(7,5,3,0.10\,116.0,1.00\,r,T) XxptUDBSOS
 TSIANSLX LABS  Tmrtil93-196  TLH44376A
 1001                    A3.30X6
           39:30         39i36         39:43        39,4B         39t54         40:00
 Til»:U980034  U-545 Acq> f-JJOr-1998 23,38:14 GC EH- Voltage SIX 70S Haifa:868
 459.7348 Tt4  9309(356,30,-3.0) rXD<7,S,3,Q.iO\r3472.0,l.OQ\,r,T) SxptKDBSUS
   XAOSLX LABS  Tmxt.1193-196  TLH44376A
 1001                    A2.81S6
  80.

  60.

  40.

  20.
           39t30         39:36         39:42        39:48         39,54          40:00
rilaiO9a0034  fl-545 Acq:  6-J1UT-1998 23,33:14 GC SH- Voltaga SIS 70S Koine:604
469.7779 Tt4  BSUB(256,30, -3.0) rXD(7,5,3,0.10\,24l6.0,l.OO\,T,T)  XxpiNDBSUS
TSZAHSLS LABS Toft,193-196  TLH44376A
1001                   A6.9JS7
  80.

  60.

  40.

  20:
           39:30         39,36         39:42        39:48        39', 54
rile:0980034 U-545 Acq:  6-J7UT-1998 23:38:14 GC XH- Voltage  512  70S No±ae:27
471.7750 rt4 BSUB(256r30,-3.0)  PXD<7r5r3,0.10\,108.0,1.00\,T,T)  Sxp:HDB5US
XSIASSLS LABS  Taxtsl93-196  TLH44376A
1001                   AS. 0.3X7
 80.

 60.

 40.

 20.
40:00
           39,30         39:36        39:42         39:48        39:54
FiletU980034 fl-545 Acq:  6-JAK-1998 23:38:14 GC XH- Voltage 5X5 705
 30.9729 Tt4 SzpiXDBSUS
TXIAJKLX LABS  Tart: 193-196   TLH44376A
             39,31
 80.

 so:

 40.

 20.

  0.
40100
                                                                                 40:01
               40106
                 -5.2X5

                 .4.1X5

                 '.3.1X5

                 .2.1X5

                 .1. 0X5
                 .0.0X0
              40 06  Tim.
                 -1.3X7

                 .1.1X7

                 .7.9X6

                 .5.3X6

                 .2.6X6
^-.'.0.0X0
 40 06 Tiae
                 -1.5X7

                 .1.2X7

                 .9.2X6

                 .6.2X6

                 -3.1X6
              40:06  Time
                -1.5X7

                .1.2X7

                .9.2X6

                -6.1X6

                '.3.1X6
          39130
                        39136
                                      39142
                                                    39:48
                                                                 39154
                                                                               40:00
                                                                                             40 06
                 0.0X0
                    Mao
                                                                                                      306

-------
Peak Locate Examination: 6-JAN-1998:23:37 File:U980034
      Experiment:NDB5US Function:2 Reference:PFK
                                                                                 O
                                                                                 CO

-------
 ile:U980034 #1
319.8965 F:2 Exp:NDB5US
 ample Text:193
-724 Acq: 6-JAN-1998 23:38:14 GC EI + Voltage SIR 70S
-196  TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
         24:48     25:00     25:12     25:24     25:36     25:48     26:00
File:U980034 #1-724 Acq:  6-JAN-1998  23:38:14  GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:193-196  TLI#44376A  File Text:TRIANGLE LABORATORIES,  INC.
lOOi           :              A1.66E6
 80j
 60 j
 40J
 20J
                                                              26:12
         24:48 t    25:00     25:12     25:24     25:36     25:48    26:00
File:U980034  #li-724  Acq:  6-JAN-1998 23:38:14 GC EI+ Voltage SIR 70S
331.9368 F:2  Exp:NDB5US
Sample Text:193-196   TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%.           '           25:08
                                  25:19
                                                              26:12
         24:48
    25:00
25:12
25:24
25:36
25:48
26:00
26:12
                                                            JiO.OEO
                                                             24  Time
                                                                          r_2.3E5
                                                                          _1.9E5
                                                                          _1.4E5
                                                                          _9.3E4
                                                                          L4.6E4
                                                          26
26
                                                    O.OEO
                                                   24 Time
                                                                          _2.6E7
                                                                          _2.1E7
                                                                          _1.5E7
                                                                          L1.0E7
                                                                          _5.1E6
LO.OEO
24  Time

-------
File:U980034 #1-724 Acq: "6-JAN-1998  23:38:14  GC  EI+ Voltage SIR 70S
339.8597 F:2 Exp:NDB5US
Sample Text:193-196  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC
100%,
                   A5.75E6
  28:00     28:06      28:12     28:18      28:24      28:30     28:36
File:U980034 #1-724 Acq:  6-JAN-1998  23:38:14  GC EI+  Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
Sample Text:193-196  TLI#44376A  File Text:TRIANGLE LABORATORIES,  INC.
100%
 20 j
  0-
 601
 40j
 20J
  OJ
                                                   A2.46E6   A2.94E6
  28:00      28:06      28:12     28:18      28:24      28:30     28:36
File:U980034 #1-724 Acq:  6-JAN-1998  23:38:14  GC EI + Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:193-196  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
100%,          I                                              28^33
  60:
  40J
  20 j
   0_:
   28:00
             28:06
28:12
28:18
28:24
28:30
28:36
                                                                           28:42
28:42
                                                                                         _2.3E6
                                                                                         11.8E6
                                                                                         Ll.4E6
                                                                                         L9.1E5
                                                                                         L4.6E5
                                                                                         LO.OEO
                                                                           28:42     28:48   Time
                                                                   1.7E6
                                                                  Ll.3E6
                                                                  Ll.OE6
                                                                  i.6.7E5
                                                                  L3.3E5
                                                                  LO.OEO
                                                              28:48    Time
    C.O.OEO
28:48   Time
                                                                                                      O
                                                                                                      CO

-------
                                                        A1.30E7
File:U980034 #11-545 Acq:  6- JAN-1998  23 : 38 :14  GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:NDB5US
Sample Text:193hl96  TLI#44376A  File Text:TRIANGLE LABORATORIES,  INC.
100%                A1.52E7
    :           i
 90 j
 80J
 70 j
 60 j
 50J
 40J
 30J
 20 j
 10J
  01
               |      35:00                   36:00                   37:00
File:U980034 #1L545 Acq:  6-JAN-1998  23:38:14 GC EI+ Voltage SIR 70S
419.8220 F:4 Exp:NDB5US
Sample Text:193-196  TLI#44376A  File Text:TRIANGLE LABORATORIES,  INC.
100%           !     A4.28E7
 90 j
 80 j
 70J
 60 j
 50 j
 40J
 30J
 20J
 10J
  OJ
                                                        A3.68E7
                                                                                         L7
                     _4.OE6
                     _3.6E6
                     3.2E6
                     2.8E6
                     2.4E6
                     2.0E6
                     1.6E6
                     1.2E6
                       9E5
                     4.0E5
                     O.OEO
                        Time
                      1.1E7
                      1.0E7
                      9 . OE6
                        9E6
                      6.8E6
                      5.6E6
                      4.5E6
                        4E6
                                                                                         L7
                                                                                          _3
                                                                                          L2.3E6
                     35:00
                                             36:00
37:00
O.OEO
   Time
                                                                                                       O
                                                                                                       TH
                                                                                                       CO

-------
TLI Project
Client Sample:
                  44376A
                  193-196
Method 23 TCDD/TCDF Analysis (DB-225)
  c                 Analysis File:   P980102
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-17A-D
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor.
Blank File:
Analyst:
12/17/97
12/29/97
01/07/98
n/a
P980094
JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
|%^v^;r- /
2,3,7,8-TCDF
^foSffl^Slartarrf
13Cl2-2,3,7,8-TCDF
^Recovery Standard
I3C12-1.Z3,4-TCDD
Amt{B8) 'VDL* EMPC Ratio
0.10 0.75
-Amt (ngj % Recovery 'delimits Ratio
3.8 93.9 40%- 130% 0.78
Ratio
0.84
RT
23:06
RT
23:05
RT
21:54
iii!*' •
B_
Flags
—
Flags

                    Data Reviewer
                                                          01/09/98
                                      Page 1 of 1
                                                                      ONFJSR vrfll. LARS 6. iaO»l
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 -Fax: (919) 544-5491
                                                                   Printed: 10:1701/09/98
                                                                               311

-------
                         Initial
                                     ,.Date.,
  Data Review By:
                                               Calculated Noise Area:
                                                                       1.00
  The Total Area for each peak with an ion  abundance ratio outside
  ratio liaits ha* been recalculated according to aethod requirements.
  Page No.
  01/07/98
Listing of P980103B.dbf
Matched GC Peaks / Ratio
/Ret. -Ti«e
  Co•pound/

  H_Z	QC.Log Oait Why ..RT.  OK Ratio Total.Area...  Area.Peak.1..  Area.Peak.2..  Rel.RT  Compound.Name..  ID..  Flags.
TCDF
304-306 DC NL 0
18
DC SN 18
DC SN 18
DC SN 19
19
19
19
19
19
DC SN 20
20
20
20
20
20:
21:
0
:00
:27
:48
:52
:00 RO
:07 RO
:28
:35
:43
:53
:00 RO
:10
:18
:28
:38
:47
:10
21:36
21:43 RO
21:
33:
22:
22:
22:
.65-0.89
0
0
0
0
0
1
0
0
0
0
1
0
0
0
.79
.84
.67
.82
.60
.24
.87
.75
.74
.78
.81
.77
.75
.71
0.75
0
0
.71
.74
0.74
0.99
:51 0.71
06
0.80
21 0.69
31 0.73
59
23:06
23:
23:
23:
24:
DC SN 24 :
DC SN 24 :
25:
19
36
43
30
39
47 RO
16 RO
0.81
0.
75
0.76
0.
0.
0.
0.
1.
1.
75
77
76
89
08
30
304-306 25 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL 21:
DC WL 21:
DC WL 31:
33:
33:
DC WH 24 :
DC WH 24:
0.
00 RO
07 RO
35
51
OS
44 RO
07 RO
52 RO
1
21
0
0
1
2
24
32
46
22
1
19
43
23
80
30
151
45
5
44
.88
.38
.75
.71
.20
.92
.96
.90
.42
.10
.04
.08
.34
.19
.43
.59
.66
.49
.56
.06
40.41
8.75
55.17
52.05
43.67
52.48
60.03
57.70
36.05


9.77





11


0.792-1.101

.61


0
0
0
0
.000
.799
.814
.817
0.823
2
11
9
19
9
.05
.59
.78
.73
.68
1.65
13.37
13.13
36.70
13.43
0.828
0.843
0.848
0.854
0.861
0.866
8
18
9
34
12
64
19
3
18
17
3
23
23
18
.39
.57
.64
.53
.75
.30
.39
.11
.30
.99
.57
.36
.34
.30
23.63
35.69
35.11
15.57
10.
34.
13.
45.
17.
87.
36.
3.
35.
33.
5.
31.
38.
34.
29.
34.
32.
20.
,79
,77
55
89
84
36
10
14
76
42
18
81
81
37
85
34
59
48
0.85
0.64
4.
994.
93
30
3,

.61

2.

65-0.89
1.
1.
0.
0.
0.
1.
3.
1.
08
30
70
89
78
18
21
66
2.
2.
11.
35.
1,620.
2.
1.
1.
11
74
59
67
48
37
30
08




710.
1.






33
51






910.
1.


78

0.874
0.879
0.887
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.

894
900
917
936
941
947
957
968
975
996
001 2378 -TCDF AN
010
022
027
061
068
074
095

0.957-1.043




15
28


0.
0.
0.
0.
1.
1.
1.
1.
000
915
935
947
000 13C12-2378-TCDF ISO
028
045
077
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 07:48 01/07/98
                                                                                 312

-------
  Page  Ho.     2           Listing of P980102B.dbf
  01/07/98                 Matched GC Peaks / Ratio / Ret. Tine

  Compound/
  M_Z	QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2..  Rel.RT  Compound.Name.. ID.. Flags.


  316-318
  13C12-TCDD
  332-334
DC

DC




DC
DC
DC
WH 25:09
2 Peaks

ML 0
20
21
21
22
WH 23
WH 24
WH 24

:00
:29
:37
:S4
:41
:38
:25
:58
0.
RO
HO


RO
RO

RO
0.65
13.
1,622.
22
75
--•--"Above: TCDF / TCDD Follows 	
S5-0.89
1
1
0
0
0
1
0
1
.74
.05
.79
.84
.95
.52
.81
.73
4 Peaks
1.
4.
1,127.
1,243.
14.
1.
7.
2.
2,390.
15
78 2.84
78 498.71
79 567.80
21 7.61
45
01
81
56
1.
090

0.908-1.092
0.
2.70 0.
629.07 1.
675.99 1.
8.03 1.
1.
1.
1.

000
948
000
013
049
093
130
155



13C12-2378-TCDD IS1
13C12- 1234 -TCDD RSI





  332-334
 Column Description	   'Why*  Code  Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)      WL-Below  Retention Time Window   A-Peak Added
 ..RT. -Retention Time (mm:ss)    WH-Above  Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions       SN-Below  Signal to Noise Level   D-Peak Deleted
 OK    -RO-Ratlo Outside Limits   
-------
fU.eiP9UOJ.OJ tl-923 Acqi7-JXN-y»  06:29i27 EH-
303.9016 Sxp, 03225
XSIAKGLX LABS  TfJCti 193-196    XLH44376A
                                         23:43
                                                       SIS 70 f
     22:36 22:48  23:00 23:12  23:24  23:36 23:48  24:00 24:12 24:24
Tilast9B0102 tl-923 Acqs7-JXN-98  06:29:27 XI+ Voltage SIX 70P
315.9419 Eip:DB225
XBIABGLX LABS  Text: 193-196    TLH4437SA
IOCS                23  05
 95.
 90:
 85:
 70.
 65.
 60:
 "-
 50:
 45.
 40:
 3S.
 30:
 25.
 20:
 15.
 10:
  5l
                                                                                                    .0.0X0
                                                                                                        Time
                                                                                                   -2.0X6
                                                                                                    il.9E6
                                                                                                    -.1. 8K6
                                                                                                    11.7X6
                                                                                                    :1. 6X6
                                                                                                    '•.1.5X6
                                                                                                    .1.4X6
                                                                                                    '.1.3X6
                                                                                                    il.2X6
                                                                                                      .1X6
                                                                                                      .0X6
                                                                                                    J.OXS
                                                                                                    .8.0X5
                                                                                                    .7.0X5
                                                                                                    -.6.0X5
                                                                                                    .5.0X5
                                                                                                    .4.0X5
                                                                                                    .3.0X5
                                                                                                     .0X5
                                                                                                     .0X5
    22:36' 22:48' 23ib6' 23:12 23:24  23i36 23t48  24*:00  24:12' 24:24' 24i36
                                                                                                    .0.0X0
                                                                          24:48  25:00 25:12 25:24     Hme\
                                                                                                       314

-------
\Kl*,f980103  K-923  Acq,7-MN-DU 06,39:27 EH- Voltage 31* 70P Xoim.,417
303.3016 BSUB(256r30,-3.0)  PXD(5,3,1,0.10%, 1668.0,0.00\,r,f)  Xxp,DB225
TRIAHGLX LASS  Text, 193-196   TLH44376A
100*                                A6.43X5
  BO.


  SO.


  40.


  20.
                             A3.45X5
                                                                   A3.51X5
                                               A2.34X5
                                       A1.B3XS    |  A3.32X5
                                                                       JU..56X5
                                                                                      A3.61X4
                                                                                       •A.
           15.00        20.00       21:00       22,00       23iOO       24iOO
ril»,P980102  tl-923 Acqi7-JJUT-98  06i29t27 XX+ Voltage SIS 70P Boiae,52S
305.8987 B30S(256,30,-3.0)  PKD(5,3,l,0.10\,2100.0,0.00\,r,r)  XxptDB225
TSIASSLX LASS Tart 1193-196   TLH44376A
100\                                AS  4X5
                                                                                   25100
  so:

  60.

  40.

  20:
                        A4.59X5
             A2.67X5
A
           A3.1BX5      A3.43X5

A2.61X5       I   A1.44X5

       ,2.24X5
                                                     A
                                                                       A2.05X5
                                                                                     A2. 78X4
          J5iOO        20>00        21i00       22.00       2J.OO       2<.00
rila*P9B0102 tl-923 Acqt7-J7OT-98  06i29t27 XI+ Voltage  SIS  70P ffoitet643
315.9419 BSUB(256,30,-3.0) PXD(S,3,l,0.10\,2572.0,0.00\rr,T) Kxp,DB22S
ZBXANBZZ LASS  Tart;193-196    TLIt44376A
J004                                                       A7.}OX6
 80.

 60.


 40.


 20.
                                                                              25100
          19,00        20,00        21:00       22.00       23.00       24.00
r±letP980102 tl-923 Acqi7-JAS-9B  06,29,27 EH-  Voltage 5X8  70P Soiaet594
317.9389 BSUB(256,30,-3.0) PKB(5,3,l,0.10\,2376.0,0.00\,r,r) XxptDB225
TRIANGLE LABS  Tejct: 193-196   TLH44376A
100*                                                       A9.10X6
 80.

 60.


 40.

 20.
                                                                                   25.00
          15.00       20.00        21 .-00       22.00       2JiOO
F±J.»,P980102 tl-923 Acq,7-JXX-98 06,29,27 XH- Voltage SIS  70P
375.8364 XxftDB225
TRIAHSLE LABS  Toxt,193-196   TLH44376A
                                                                 24,00
                                                                              25,00
                                                      -9.6X4


                                                      .7.7X4


                                                      .5.7X4


                                                      -3.8X4-


                                                      .1.9X4
                                                                                           0.0X0
                                                                                              Time
-1.3X5


'.1.1X5


.7.9X4

-5.3X4


-2.6X4
                                                                                           0.0X0
                                                                                              Time
                                                                                          -2.0X6


                                                                                          '.1.6X6

                                                                                          .1.2X6


                                                                                          .7.9X5


                                                                                          .4.0X5
                                                                                           0.0X0
                                                                                              Time
                                                                                         -2.4X6


                                                                                          .1.9X6

                                                                                         -1.4X6


                                                                                          .9.7X5

                                                                                         -4.8X5
                                                       0.0X0
                                                          Time
                                                                                   25,00
                                                                                                     315

-------

319.8965 BSVB(256,30,-3.0) PXD(5r3,l,0.10\,1376.0,0.00\,T,T) Xxp,DS225
TSIAIISLX LABS Text: 193-196 TLI944376A
lOOi
80.
60.
40.

20.

I

jl A1.05E5
H
1 A4.29X4 «« »„_,
II ' I ».-»» ----- - 	 A8.59X4 " 	 ' •
JUa.74J* A3. 38X4 M,
ll-J\.' -A A A _A7-f"3WV U ^ULJ^^^^^I^
20:00 21:00 22:00 ' ' '23:00 ' ' '24': 00 ' ' ' 25
5.7X4
.4.6X4
.3.4X4
.2.3X4

JL.1X4
00 Tiae
rile,P980102 91-923 Acq,7-J3Ur-98 06:29:27 XI+ Voltage SIS 70P Noise, 4 09
321.8936 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,1636.0,0.00\,T,T) XxpiDB225
TSIAWGLX LABS Text, 193-196 TLH44376A
ion
80.
60.
40.

20.
J
1 AI-l"'rS

I
II A1.07X5
UL4.19X4 ^-30X4 A
Jl 11 .. .OH L«W\. ".-ftfL .«•«« . . _H-»«.
'20:00 ' 21:00 '22:00 	 23:00 	 24:00 ' ' ' 25
6.8X4
.5.4X4
.4.1X4
.2.7X4

.1.4X4
00 Time
rile:P980102 H-923 Acq:7-J3UT-98 06:29:27 EI+ Voltage SIS 70P Noise, 388
327.8847 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,15S2.0,0.00\rr,r) Xxp:DB225
TRIANGLE LABS Text: 193-196 TLH44376A
ion
80.
60.
40.
20.

0.
A1.06X7
n




I \ A7.02X5
1 \ A
20:00 21:00 22:00 ' ' ' '23:00 ' ' '24:00 ' 25
3.0X6
.2.4X6
.1 . 8X6
.1.2X6
'.5.9X5

0.0X0
00 Time
rile:P980102 91-923 Acq,7-JAB-98 06:29:27 EI+ Voltage SIS 70P Noise, 56 5
331.9368 BSUB(256,30,-3.0) PXD(S,3,1,0.10\,2260 .0,0 .00\,r,T) Xxp:DB225
TSIAIISLX LABS Text: 193-196 TLI944376A.
1001
80.
60.
40.
20.
0.
AS




1
<8E6





'20:00 ' ' 21:00 ' ' '22:00 	 23:00 	 24:00 	 25:
.1.4X6
.1.2X6
.8.6X5
.5.8X5
.2.9X5
0.0X0
00 Time
rlle,P9S0102 91-923 Actj:7-JUr-98 06:29:27 XH- Voltage SIS 70P Noise: 326
333.9338 BSUS(2S6, 30, -3.0) PKD(5,3, 1,0.10\, 1304 .0,0. 00\,T,T) Xxp:DB22S
TSIAIISLX LABS Tort: 193-196 TLH44376A
100\

80.
60.
40.
20:
o:
A6.29X6 -1.7X6
I




l\ 1
•





20:00 21:00 22:00 ' ~23:00 	 2t\OQ 25

.1.4X6
J..OX6
.6.9X5
.3.4X5
0.0X0
00 Time
316

-------
rileiP980102 tl-923 Acq:7-JXK-98 06:29:27 XI+ Voltage SIS 70P
303.9016 Szp:DB225

TSIAHGLX LASS Taxt:193-196 TLH44376A
1001

80.

60.
40.
20.
0
21;
20, 38 A

II
15:43 '
10 1 ^fljl 20 1 19
1. "j^M/ljtAllr W 1
19:00 ' ' 20:00 21:00
10 ,.5.5*4
3.3 ^J
,
22s 31 \
21 : 51 1 22 : 55 1 A
ft i A 1 ii (1 In T"
UWI/IA/I. Jvl/l/VL A. 75A15

.7.5W

.5.5X4
.4.0Z4
L2.0JT4
' 0 . 0*0
22:00 2J:00 24:00 25:00 TdMe
rile:P980102 tl-923 Acq:7-JAS-98 06 1 29 1 27 XH- Voltage SIX 70P
315.9419 Kxp:DS225

XXIAOSLX LASS Text:193-196 TLIt44376A
1001
80.
60.
40.
20.







15:00 20:00 21:00
23 t 05 2.0X6




r l\
Ll.5*5
L1.2Z5
.8.0X5
'-4.0X5
' 0.0X0
22:00 23:00 24:00 25:00 T±me
rile :P9 80102 tl-923 Acq:7-JAS-98 06:29:27 XI* Voltage SIX 70P
319.8965 Xxp:DS225

TSIAtTSLX LASS Tmxtil93-196 ZLIt44376A
ion
sol
50:
40:

20:
0'
15:17

15,50
\ ,n ,„
20:30
II II .
-.6.1X4



21:55
1 Jl /, A alsr15 A -.--«- 	 «-no
.. . ..^.'^ 1 L~J L 	 JUJU/
15ioO 2ol00 21,00
\^jJW U X^ 'l'27 23:54 34:28 JL
U-V** W ". . i . -A ^"n-i --i U*l i_ -Tr-i-ni _ -* .«xn«rji_rs ' . i.
.4.8X4
.3 . 6X4
.2.4X4

.1.2X4
• n nwn
22JOO ' 2J^OO ' 24^00 ' 25,00 Tine
T±letP980102 tl-923 Acq:7-Jlor-98 05,25,27 EH- Voltage SIS 70P
331.9368 Xxp:DS225

TXIANGLZ LASS Text: 193-196 TLXt44376A
ion
80:
50:
40:
20:
0:




•

15,00 2oiob 21:00
21:54
1 A



''/\
-.1.4X6
.1.2X6
.8.7X5
.5.8X5
.2.9X5
0.0X0
22:00 2jiflO 24^00 25,00 T±me
rile:P930102 tl-923 Actj:7-JZN-98 05,25,27 Xl-h Voltage SIS 70P
292.9825 Exp:DB225
TSIAKSLX LASS Text: 193-196 XLIt44376A
1004
80:
50:
40:
20:
o:
^^^8j57 15,25 15,57 20,25 20,54
^V W If-^




19:00 20,00 21:00


21,JO 22,05 22?47 2J/J4 _ 24:07 _24:42 _ .„





.5.0X6
14.0X6
-.3.0X6
.2.0X6
.1.0X6
0.0X0
22iflO 23:00 ' ' 24iob 25^00 Mjie
r±lo:P9B0102 tl-923 Acq:7-J3ur-98 05,25,27 XI+ Voltage SIS 70P
330.9792 Kxp:DS225
TXIAOSLX LASS Text: 193-196 TUt44376A
1001
80:
50:
40:
20:
0:


19:37 20:15 21:12 21,42 22.-J5 23:09 23:5934:24 24:58
i i M- . n«n^i i I, m rJirti^**J*^YT^fn*"^ rtr^r^^^rV**^ -*^i*^*"ift flf*"^nfl i !ll*ii^Mi"* "i ^n i'*i '* nrtrl ^r*^-*™»**inrrtrit*'*i1i ni" *n i*1ff





19:00 20,00 21JOO




.4.2X6
.3.4X6
.2.5X6
.1.7X6
.8.4X5
0.0X0
22^00 2jiflO 24^00 25^00 Ma«




























































317

-------
                       ft'P988182
Ref, lass   292,9825    Peak top
Height    ,95 volts  Span   288 ppi
Systa f He naie	
Data  file naie
Resolution
Groj) niter
lonlzatlon lobe
Switching
   , lasses   292,9825,
f)   292,9825
8   383,9816
C   385,8987
D   315,9419
E   317,3389
F   319,8965
6   321,8936
H   327,8847
I   338,9792
                    J
                    K
                    L
                    H
       1
     El*
 VOLlffiE
388,9761
338,9792
331.9368
333,9338
375,8364
Channel   I  338,9792    Peak top
Height    ,78 wits  Span   288 ppi
                                                        318

-------
 TLI Project:      44376A
 Client Sample:   198/199/205/208  ft.
 Method 23 PCDD/PCDF Analysis (a)
r           Analysis File:  U980036
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAIN
194-59-18A/B
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyse

12/17/97
12/29/97
01/07/98
n/a
U980026
JM

Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:

SPMTT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1A3.7.8-PCCDD
1A3.4.7.8-HXCDD
U,3,6.7,8-HxCDD
l,2J,7,8,9-HxCDD
1.2J,4.6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3.7,8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
^2.3,4,7,8-HxCDF
R2,3,6,7,8-HxCDF
2.3,4,6,7,8-HxCDF
lA3.7.8,9-HxCDF
1,2^,4,6,7,8-HpCDF
1.23,4,7,8.9-HpCDF
1,2^,4,6,7,8.9-OCDF
totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF •
Total PeCDF
Total HxCDF
Total HpCDF
^ •. ^%*- •.•£••; '"• ,' ^
> Aim; pg| 0 £«. '' ^ fcMPC ^' - ^
0.07
0.48
0.26
0.46
0.57
1-2
0.65
7.6
1.7
2.9
6.0
2.3
2.4
0.15
6.1
0.72
1.5
Amt {ng) Number DL EMPC
13.2 11 13.6
11.0 9 17.2
9.2 7
2.8 2
41.5 15 41.8
44.2 16
25.8 10 272
10.3 4
Ratfo
0.65
1.71
1.11
1.12
1.14
0.98
0.77
0.76
1.49
1.51
1.25
1.27
1.24
1.20
1.08
1.06
0.87









";RT" , £&$£ ^'
25:20 PR_
29:37 	
32:44 	
32:50 	
33:08 	
36:04 	
39:37 	
24:41 	
28:35 	
29:17 	
32:03 	
32:09 	
32:38 	
33:24 PR_
35:02 	
36:33 	
39:50 	
, Flags



—




                                      Page 1 of 2
                        MTT2 JSR »ijDl. LAIS 6. KUXI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 11:0301/10/98
                                 319

-------
 TLI Project      44376A
 Client Sample:   198/199/205/208
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980036
"
t.giMl r.^JX
,wtfirtl&S&kadra&
l3C,z-2,3,7,8-TCDF
13C12-2.3,7,8-TCDD
t3C,2-1^3,7,8-PeCDF
13C12-l,Z3.7,8-PeCDD
13Ci2-lA3,6J,8-HxCDF
13C12-l.Z3,6,7,8-HxCDD
13C,2-lA3,4.6,7,8-HpCDF
13C12-l,2,3A6,7,8-HpCDD
13C,rlA3.4,6,7,8,9-OCDD
Surrogate Standards {Type A)
13C,r2,3,4,7,8-PeCDF
13C12-l,2,3A7,8-HxCDF
13C12-U,3,4.7,8-HxCDD
13C12-U,3,4,7,8,9-HpCDF
•te ^ " jit ml ffi At
^iTO9atft€tarjo«H^{rype A|
37CU-2,3,7,8-TCDD
Alternate Standards {Type A}
13C,2-l,2,3,7.8,9-HxCDF
13C12-23,4,6,7,8-HxCDF
Recovery Standards
13C,rl^3,4-TCDD
13C12-lA3,7,8,9-HxCDD

•- a- <" Jrtj^
' **"*»• V*S
3.3
3J
3.4
2.7
3.6
3.9
3.2
3.2
5.9
Amtv&$J
3.5
3.2
3.2
3.5
A * t
- ***"** v'Sl
3.2
Amt (ng]
3.4
3.4
-



l/,,,^^-^.^^ «||»-»r^»
* '^//^^«f'^!r?y*?^
82.3
81.4
86.0
66.4
90.4
98.6
80.7
80.9
73.2
1 .., % Recovery
86.9
79.7
78.9
88.3
•• «/'&
% Recovery
79.1
% Recovery
84.6
85.6
vf



&*(«& \ A-^ ^y
-o^-'rTl<«-«J
409b-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
"
40%-130%
40%-130%
40%-130%
40%-130%
^
'

-
40%-130%
40%-130%
_.



„ ^^•^Whtt l
^i^^^SE;
0.75
0.80
1.55
Ul
OJO
1^0
0.44
1.04
0.85
Ratio
1.52
0.51
1.20
0.39



; Ratio
0.52
0.52
Ratio
0.82
1^3


i^l$*vuiv^ : -xvi \f
24:38
25:21
28:35
29:36
32:09
32:49
35:01
36:03
39:37
^/ tff
29:16
32:03
32:44
36:33
me
nT
25:22
RT
33:24
32:38
RT
25:11
33:08

-
>,jv^E^^v






^^_^^
_
—
Flags



—
c,___ i
Ftass |
—
Ffa^s

—
Flags


                    Data Reviewer
           01/10/98
                                       Page2of2
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 11:03 01/10/98

-------
                        Initial'
                                    .Date.
  Data Review By:
                                             Calculated  Noise Area:
  The Total Area for each peak with an ion abundance ratio outside
  ratio  limits has been recalculated according to method requirements.
                                                                    1.00
01/10/98 Matched GC Peata / Ratio /
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total. Area. ..
TCDF ' 0.65-0.89
304-306 DC NL 0
NK 21
K 22
K 22
K 22
K 22
K 23
K 23
23
24
24
24
24
25
25
25
26
:00 RO
:31
:01
:15
:38
:58
:21
:37
:51
:05
:16
:29
:41
:06
:18
:34 RO
:24
0.57
0.76
0.73
0.74
0.75
0.74
0.73
0.76
0.75
0.76
0.75
0.77
0.76
0.73
0.74
0.64
0.80
304-306 16 Peaks
k'3C12-TCDF
F 16-318 DC NL 0;
DC WL 22:
DC WL 23:
23:
24:
24:
24:
25:
DC WH 25:
DC WH 26:
DC WH 26:
DC WH 26:
0
00 RO
:28 RO
37
53
05 RO
13
38
05
50 RO
09
24 RO
30 RO
316-318 5 Peaks
TCDD
320-322 DC NL 0:
NK 22:
NK 23:
K 23:
K 24:
24:
0.
00 RO
50
13
31 RO
11
28
.65-0.89
1.03
1.46
0.83
0.70
0.42
0.69
0.75
0.70
7.97
0.87
1.49
1.12

4
3
4
19
12
14
10
13
17
6
6
28
6
6


157
282
,063
,831
,466
,441
,692
,662
,358
,940
,640
,717
,075
,671
,986
,201
846
812
,407
.76
.74
.01
.16
.79
.43
.27
.01
.79
.47
.48
.25
.60
.04
.66
.45
.39
.54
Ret. Time
Area . Peak .

1
'1
1
8
5
6
4
5
7
2
2
12
2
2




,753
,616
,897
,306
,404
,197
,487
,958
,611
,885
,650
,359
,947
,627
368
361

1. . Area. Peak.

.59
.08
.27
.09
.45
.96
.46
.37
.67
.23
.85
.70
.67
.79
.23
.55


2,310
2,214
2,568
11,135
7,287
8,464
5,870
7,982
10,028
3,832
3,424
16,311
4,038
3,573
579
450

2.. Rel.RT Compound. Name. . ID.
0.867-1.079

.15
.93
.89
.70
.98
.31
.55
.42
.80
.25
.40
.90
.37
.87
.76
.84

0.000
0.873
0.894
0.903
0.919
0.932
0.948
0.959
0.968
0.978
0.985
0.994
1.002 2378 -TCDF AN
1.019
1.027
1.038
1.072

0.959-1.041






12,





12,
13
18
90.
25,
16,
85.
,159.
215.
11.
41.
9.
9.
,502.
mj»>T\*
.54
.59
.58
.45
.76
.64
.47
,23
13
34
63
75
55
s t
65-0.89
0.14
0.78
0.79
0.94
0.77
0.84

15,
10,
1,
3,
1,
6.
687.
610.
112.
397.
959.
85
02
11
82
69
57






5,








10,
7,
34.
,220.
88.







.50
,29
.97
.14
50







14
17
50
6,939,
126,







.95
.19
.67
.33
.73




0.000
0.912
0.959
0.970
0.978
0.983
1.000 13C12-2378-TCDF ISO
1.018
1.049
1.062
1.072
1.076



6,
4,

1,


885.
676.
592.
476.
894.

29
84
75
47
32

8,801.
5,933.
628.
1,921.
1,065.
0.895-1.047

73
27
71
22
25
0.000
0.901
0.916
0.928
0.954
0.965
                                                                                                       Flags.
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:04 01/10/98
                 321

-------
Page No .
01/10/98
Compound/
2 Listing
Matched
M_Z.... QC.Log Omit Why ..RT. OK

M
AN



D

320-322
37C1-TCOD
328










328
13C12-TCDD
332-334








332-334
PeCDF
340-342

0
0







M
AN
24:50
25:17
25:20
25:33
35:42
25:54
D SN 26:12 BO
26:22
12 Peaks

DC NL 0:00
DC WL 22:43
DC WL 22:50
DC WL 23:07
DC WL 23 : 14
24:01
24:20
25:22
25:46
25:57
26:03
6 Peaks
0.
DC NL 0:00 RO
24:11
24:51 RO
25:11
25 : 21
25:41 RO
25:51 RO
26:05 RO
26:24
8 Peaks
1.
DC NL 0:00
26:36
0 SN 26:52
D SN 27:04 RO
27:14
27:21
27:36
27:44
27:54
28:12
28:19
28:31
28:35
of U980036B.dbf
GC Peaks / Ratio /
Ratio Total. Area. . .
0.86
0.79
0.65
0.81
0.81
0.84
1.27
0.70














65-0.89
2.43
0.74
4.38
0.82
0.80
0.64
0.61
0.27
0.78
918.86
3,500.00
188.30
464.29
427.28
193.86
12.78
158 . 62
38,618.42

39.27
46.06
229 . 28
724.87
343.92
11,516.80
177.87
7,256.94
885.08
43.47
23.06
19,903.22

10.35
62.94
6.30
10,069.98
9,167.93
465.42
144.24
42.02
42.23
20,001.06
32-1.78
1.74
1.56
1.55
2.04
1.68
1.59
1.56
1.52
1.53
1.48
1.52
1.55
1.49
5.59
11,155.56
150.42
310.39
370.11
363.60
3,611.75
24,471.61
6,404.81
10,309.80
12,795.51
5,630.00
4,350.00
Ret. Time

Area . Peak . 1 .. Area . Peak . 2 . . Rel. RT Compound. Name. . ID.. Flags.
425.60
1,540.00
74.30
207.66
191.45
88.49

65.30







11,516.80
177.87
7,256.94
885.08
43.47
23.06



26.71
15.61
4,543.14
4,076.84
202.47
62.75
18.28
18.48



6,793.30


231.78
223 . 34
2,199.59
14,748.60
3,870.62
6,148.96
7,717.79
3,420.00
2,600.00
493.26 0.980
1,960.00 0.997
114.00 0.999 2378 -TCDD AN PR
256.63 1.008
235.83 1.014
105.37 1.022
1.034
93.32 1.040 J

0.921-1.079
0.000
0.896
0.901
0.912
0.917
0.947
0.960
1.001 37C1-TCDD CLS
1.016
1.024
1.028

0.921-1.079
0.000
36.23 0.954
3.56 0.980
5,526.84 0.993 13C12- 1234 -TCDD RSI
5,091.09 1.000 13C12- 2378 -TCDD IS1
315.05 1.013
103.30 1.020
68.19 1.029
23.75 1.041

0.925-1.065
0.000
4,362.26 0.931
0.940
0.947
138.33 0.953
140.26 0.957
1,412.16 0.966
9,723.01 0.970
2,534.19 0.976
4,160.84 0.987
5,077.72 0.991
2,210.00 0.998
1,750.00 1.000 12378-PeCDF AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:04 01/10/98
               322

-------
  Page No.     3
  01/10/98


  Compound/
  M_Z.... QC.Log Omit Why
Listing of 0980036B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT.  OK Ratio Total. Area. .. Area. PeaJc. 1. . Area . Peak. 2. .  Rel.RT Compound. Name. .  ID..  Flags.






340-342
13C12- PeCDF
352-354






352-354
PeCDD
356-358
D
28
28
29
29
29
30
:45
:52
:17
:26
:45
:15
1.62
1.48
1.51
1.51
1.41
1.55
16 Peaks

DC NL 0
27
27
28
29
29
30
1
:00 RO
:43
:57 RO
:35
:16
:59
:16 RO
.32-1.78
0.93
1.51
1.18
1.55
1.52
1.47
0.82
6 Peaks
• l~ —

DC NL 0
DC WL 27
1.
:00 RO
:36 RO
27:50 RO
0



D SN 28:06 RO
28:
28:
28:
:19 RO
:33
41
28:52
29:03
29:08





356-358
13C12- PeCDD
368-370









368-370
29:
29:
29:
29:
30:
19
28 RO
37
45
05
.32-1.78
1.18
1.01
1.11
0.22
1.11
1.56
1.54
1.59
1.40
1.65
1.54
1.06
1.71
1.45
1.73
12 Peaks

DC NL 0:
28:
28:
DC SN 29 :
29:
29:
30:
30:
30:
30:
1.
00 RO
32 RO
40 RO
24
36
44
11
16
25 RO
29 RO
32-1.78
1.00
2.38
2.44
1.62
1.51
1.64
1.53
1.57
4.01
5.20
8 Peaks
4,404.76
7,634.24
7,393.53
11,230.76
2,235.72
670 . 99
113,032.75

0.46
124 . 61
30.76
9,886.79
8,295.52
19.08
17.19
18,373.95

0.33
43.33
7,075.03
266.58
477.24
5,339.74
1,033.63
3,538.58
523.46
1,020.77
1,401.26
664.73
637.41
512.15
412.94
22,636.94
2,723
4,550
4,442
6,747
1,307
408



74
18
6,009
5,003
11
10
.47
.35
.51
.99
.44
.34



.91
.70
.41
.64
.37
.45
1,681.29
3,083
2,951
4,482
928
262



49
15
3,877
3,291
7
12
.89
.02
.77
.28
.65

0.

.70
.79
.38
.88
.71
.68
1
1
1
1
1
1

860
0
0
0
1
1
1
1
.006
.010
.024 23478- PeCDF
.030
.041
.058

-1.140
.000
.970
.978
.000 13C12-PeCDF 123
.024 13C12- PeCDF 234
.049
.059


AN








IS2
SOR1








4,300.51

290.
3,250.
626.
2,171.
305.
635.
848.
404.
402.
303.
261.


.09
.04
17
93
25
00
63
05
46
14
81



3,884

261
2,089
407,
1,366.
218.
0.935-1.022


.25

.68
.70
.46
.65
21
385.77
552.63
381.39
234.
209.
151.

95
01
13

0
0
0
0
0
.000
.932
.940
.949
.957





0.965
0,
0.
0.
.969
.975
.981



0.984
0.990
0.995
1.001 12378-PeCDD
1.
1.

005
016

AN



0.865-1.135
0.26
7.85
4.51
2.54
3,947.50
1,019.94
29.47
27.45
7.52
4.79
5,049.03

7.
4.

2,375.
633.
17.
16.
11.
9.


32
32

84
98
82
75
82
78


3.
1.

1,571.
385.
11.
10.
2.
1.


08
77

66
96
65
70
95
88

0.
0.
0.
0.
1.
1.
1.
1.
1.
1.

000
964
968
993
000 13C12- PeCDD 123
005
020
023
028
030





IS3






Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 11:04 01710/98
                                                                              323

-------
  Page No.
  01/10/98
Listing of  0980036B.dbf
Matched GC  Peaks / Ratio / Ret. Tiae
  Compound/
  M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.
  HxCDF
  374-376
         AN
         M
  374-376

  13C12-HXCDF
  384-386
  384-386
  HxCDD
  390-392
 390-392

 13C12-HXCDD
 402-404
 402-404

DC NL 0
31
31
31
31
31
32
32
32
32
32
33
33
1
:00
:05
:14
:24 RO
:32
:41 RO
:03
:09
:16
:26
:38
:24
:29
----- ADOVC: reuiu /
.05-1.43
1
1
1
1
1
1
1
1
1
1
1
1
1
.21
.24
.24
.46
.26
.76
.25
.27
.29
.22
.24
.20
,28
12 Peaks

DC NL 0
31
32
32
0.
:00 RO
:14 RO
:03
:09
32:38
33
:24
297.45
6,020.36
14,074.33
1,745.52
2,129.23
763.93
10,793.84
5,185.94
1,819.19
2,129.23
4,213.70
233.00
1,053.00
SO, 161. 27
nxuuc follows ----------

3,332
7,785
1,139
1,189
600
5,994
2,901
1,024
1,168
2,329
127
591


.11
.94
.51
.13
.51
.93
.21
.12
.93
.54
.00
.00


2,688
6,288
779
940
341
4,798
2,284
795
960
1,884
106
462

.43-0.59
2.66
0.60
0.
0.
0.
0.
5 Peaks

1.
DC NL 0:00 RO
31:35
D SN 31:
32:
32:
32:
32:
32:
33:
42 RO
01
13
23
44
50
08
,51
50
,52
52
8.34
53.62
4,667.95
7,103.73
6,067.75
4,623.28
22,516.33
05-1.43
0.
1.
1.
1.
1.
1.
1.
1.
1.
87
22
92
24
21
09
11
12
14 .
7 Peaks

DC NL 0 :
32:
32:
32:
32:
32:
32:
33:
1.
00 RO
13
19 RO
26
36 RO
44
49
08
05-
1.
1.
2.
1.
1.
1.
1.
1.
1.43
72
43
02
37
69
20
20
23
7 Peaks
47.22
991.11
47.85
6,242.42
2,395.19
507.45
285.62
644.49
763.94
11,830.22

21
1,582

.16
.28
2,366.84
2,065.04
1,584
.73

35
3,085
4,736
4,002
3,038
0.962-1.047

.25
.39
.25
.10
.04
.91
.73
.07
.30
.16
.00
.00

0.000
0.967
0.971
0.977
0.981
0.985
0.997
1.000
1.004
1.009
1.015
1.039
1.041







123478-HxCDF
123678-HxCDF


234678-HxCDF
123789-HxCDF








AN
AN


AN
AN


0.876-1.124

.51
.67
.89
.71
.55
0.000
0.971
0.997
1.000
1.015
1.039


13C12-HXCDF 478
13C12-HXCDF 678
13C12- HxCDF 234
13C12-HXCDF 789


SCTR2
IS4
ALT 2
ALT1
Uvfnn Vn 1 1 nua .««___


545.

3,456.
1, 310 .
265.
150.
339.
406.


.32

48
99
09
13
85
93


445.

2,785.
1,084.
242.
135.
304.
357.

0.958-1.014

.79

94
20
36
49
64
01

0.000
0.962
0.966
0.976
0.982
0.987
0.997
1.001
1.010







123478-HxCDD
123 67 8 -HxCDD
123789-HxCDD







AN
AN
AN

0.970-1.030
6.41
20.15
3.58
6.73
3.38
3,309.24
5,730.34
5,839.49
14,912.91

11.
3.
3.
2.
1,803.
3,120.
3 , 218 .


85
23
89
55
79
02
81


8.
1.
2.
1.
1,505.
2,610.
2,620.


30
60
84
51
45
32
68

0.000
0.982
0.985
0.988
0.993
0.997
1.000
1.010






13C12-HXCDD 478
13C12-HXCDD 678
13C12-HXCDD 789






SOR3
IS5
RS2

                                                                                                         PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 11:04 01/10/98
                                                                                Q9
                                                                                o
24

-------
   Page No.
   01/10/98
Listing of  O980036B.dbf
Matched GC  Peaks / Ratio / Ret. Tiae
   Compound/
   M_Z.... QC.Log Omit why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.
   HpCDF
   408-410
  408-410

  13C12-HpCDF
  418-420
  418-420
  HpCDD
  424-426
          D
          D
  424-426

  13C12-HpCDD
  436-438
  436-438
  OCDF
  442-444
 442-444

DC





NL 0
35
35
35
36

:00
0
RO
:02
:18
:27
:33



.88-1.20
1
.41
1.08
1
1
1
.15
.02
.06
4 Peaks

DC-



NL 0
35
36

:00
:01
:33
0
RO


.37
1
0
0
2 Peaks

DC
DC


NL 0:00
WL 35:11
0
RO
RO
35:18

DC
DC
36
:04
NH 36:24

RO
NH 36:31
.38
0
0
0
0
1
1
-0.51
.17
.44
.39

-1.20
.30
.58
.98
.98
.56
.04
2 Peaks

DC




NL 0:00
35:
36:
18
03
0.
RO

18.54
8,272.58 4,286.07
1,862.34 995.50
2,357
767
13,259

8
3,872
2,742
6,614
.44 1,189.54
.32 394.21
.68

.67
.29 1,177.52
.35 776.40
.64
f / UK/*VU-I e»— i t _....
0.996-1.049
0.000
3,986.51 1.000 1234678-HpCDF
866.84 1
1,167.90 1
373.11 1

0.943
0
2,694.77 1
1,965.95 1

.008
.012
.044 1234789-HpCDF

-1.114
.000
.000 13C12-HpCDF 678
.044 13C12-HpCDF 789

AN


AN



IS6
3 OH 4

0.975-1.005
2
30
1,333
.16
.17
.09 660.67
1,055.05 522.16
13.12
9.45
2,383
.14
88-1.20
1.66
1.
,04
1.04
2 Peaks

DC
DC
DC
DC
DC
DC

DC
DC
DC
DC




NL 0:
WL 34:
WL 34:
WL 35:
WL 35:
WL 35:
35:
SN 37:
SN 38:
SN 38:
SN 38:
39:
40:
40:

00
41
54
01
13
23
50
24
10
37
47
50
18
18
0.
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO

RO
RO
40:48

76-1.02
3.
3.
1.
1.
17.
1.
2.
13.
0.
5.
5.
0.
0.
2.
0.
03
70
19
59
56
81
04
61
92
71
60
87
69
13
78
5 Peaks
5.67
16,
,44 8.40
3,428.33 1,745.27
3,444.77
: HpCDD / Octa-CDD and CDF
2.
1.
3.
4.
1.
6.
3.
0.
2.
0.
0.
1,242.
82
25
65
16
29
03
59 3.87
43
17
79
47
00 579.00
10.38 4.89
7.
84 8.84
6.46 2.84
0
0
672.42 0
532.89 1
1
.000
.976
.979
.000 1234678-HpCDD
.010



AN

1.013



0.972-1.028
0.000
8.04 0.979
1,683.06 1.000 13C12-HpCDD 678


IS7

Follows 	
0.899-1.101
0.
0.
0.
0.
0.
0.
1.90 0.
0.
0.
0.
0.
663.00 1.
7.11 1.
4.15 1.
3.62 1.
000
875
881
884
389
893
905
944
963
975
979
005 OCDF
017
017
030











AN



1,270.27
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 11 =0401/10/98

-------
  Page No.
  01/10/98
Listing of 09800368.dbf
Hatched GC Peaks  /  Ratio / Ret. Tine
  Compound/
  M_Z....  QC.Log Omit why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
  OCDD                          0.76-1.02
  458-460         DC   NL   0:00 RO  1.67          0.06
                         39:37     0.77        418.68        181.84
                         40:00 RO  1.86          6.05          5.94
  458-460              2 Peaks                 424.73

  13C12-OCDD                    0.76-1.02
  470-472         DC   NL   0:00 RO  1.33          0.06
                         39:37     0.85      4,656.23      2,144.76
  470-472              1 Peak                4,656.23
                                                   0.899-1.101
                                                       0.000
                                               236.84  1.000 OCDD            AN
                                                 3.20  1.010
                                                   0.996-1.004
                                                       0.000
                                             2,511.47  1.000  13C12-OCDD      IS8
  Column Description	  "Why" Code Description	   QC  Log Desc.
  H_Z   -Nominal  Ion Mass(es)
  ..RT.  -Retention Time (mm:ss)
  Rat.l  -Ratio of M/M+2 Ions
  OK    -RO-Ratio Outside Limits
  Rel.RT-Relative Retention Time
      End of Report
      WL-Below Retention Time  Window
      WH-Above Retention Time  Window
      SN-Below Signal to Noise Level
      
-------
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330.9792 Ft2 XxptXDBSUS

A

1
/ V A8.SSE6
1 V^ /^^
.2.1X7

-1.6X7
.1.0X7
.5.2X6

' O.OEO
' aSiOO 	 Time
SIM 70S

TRIANGLE LABS Teiti 198/199/205/208 TLIt44376A
1001
80:
60:
40:
20:
oj
-. ., 24tOO ,. ,. 24:40 34, c?
23 1 15 _^*^ ^^24 1 21 ^s*^*™.!*? ^*-
• • -^^f '** ' 	 » ' *~ » f^




23iOO 	 24>
^V -^^ f*»l M i*-T 	 *WF • 	 «




00 25\00
«^5^^^_>/WN^^A^£ff,Mj^





.4.0X7
.3.2X7
.2.4X7
.1.6X7
.8.0X6
0.0X0
26s 00 	 Time
328

-------
ri2»tU9B0036 tl-724 Acqs 7 -JAN- 1998 01:38:05 CC XI + Voltage SIS 70S Noimesl774
339.8597 tsi BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,7096.0,1.00\,r,X) XxpiSDBSUS
XSIASSLX LABS Texts 198/199/205/208 XLIt44376A
lOOi
80.
60.
40.

20.

Al . 4 7X8
A
I A7.72X7
A6.79E7 1 1 A
Al A 3 . 8 7X7 A / \ "A * A
A/ \ A /V\ M A A j
/V vV^ i \J \J\J v J
37:00 38:00 35:00




A6.75E7
n
A A
\ / V
V/ V^xv"7 _
JOtOO
rll»,U980036 tl-724 Acqs 7 -JAN- 19 9 8 01:38:05 SC XH- Voltage SIS 70S Hoi f», 1021
341.8567 Ts2 BSVB(256e 30, -3.0) PXD(7,5,3r0.10\,4Q84.0r1.00\,TrX) XzpsSDBSUS
XSIASSZX LABS Text: 19 8/199/205/208 XLIt44376A
1001
80.
60.
40.

20:
A9 72X7
1

AS.08E7
An
12 -S3T7 A IVU-56S7 A3. 08X7
Jt/\lM>uA I
27s 00 38:00 29:00




n
A A

J0:00
riIesO980036 tl-724 Acqs 7-JAS-1998 01:38:05 SC XH- Voltage SIS 70S Noiae:139
351.9000 Ts2 BSUB(256r 30, -3. 0) PXD(7,5,3,0.10\r5S6.0,1.00\,T,X) XxpsKDBSUS
XSIASSLX LABS Xext:198/199/205/208 TLIt44376A
ion

80:
60:
40:
20:
o:
AS. 011:7


A AS. 00X7




1 V 	 /
37:00 38:00 35:00




V 	
30:00
riletU980036 tl-724 Acqs 7-JZ1T-1998 01:38:05 SC XI* Voltage SIS 70S Boiaesl4B
353.8970 Ts2 BSU3(256, 30, -3.0) PKD(7,S,3,0 .10\,S92.0,1.00\,r,X) XxpsNDBSUS
XSIASSLX LABS Texts 198/199/205/208 TLIt44376A
1001
80:
50:
to:
20:
0:
A3 . 88X7


A A3.29E7
1



/ v__ /
37:00 ' ' 38:00 ' 3S«00 '








-3.3X7
-.2.6X7
-.2.0X7
'.1.3X7

.6.6X6

Xiae



-2.2X7





.1 . 8X7
.1.3X7
.8.8X6

.4.4X6
Xiae



1.5E7







.1.2E7
.9.3X6
.6.2X6
.3.1X6
O.OEO
Xiae



-1.0X7


1 ;
1 :
V—
.8.3X6
'.6.2E6
'.4.2X6
.2.1X6
O.OEO
30:00 Time
riles0980036 tl-724 Acqs 7-JAJT-1998 01:38:05 SC Eli- Voltage SIS 70S
330.9792 r:2 ExpsSDBSOS
XSIASSZE LABS Texts 198/199/205/208 XLXt44376A
1001
80:
so:
40:

20:
o:
'•'
1
1K,tJ 36,4927,04 27:29 3£<-£?. 38-^6^38f43 29:17 ^^?J-5B - r- r3'9*7
/^.^W-M-V-^^r—V^JUV^-^.





27 tOO 38:00 ... ag\tgg

i
'
1

j
-3.1X7
.2.3X7
_1.5£7

-7.SS6
O.OEO
30iOO Tiae
Tllot0980036 tl-724 Acqs 7-JAS-1998 01:38:05 SC XH- Voltage SIS 70S
409.7974 Tt2 EXpsSDBSUS
XSIASSLX LABS Xaxtt 198/199/205/208 XLIt44376A
lOOi
80:
50:
40:
20:
0:






i
30.
i


.
i "I17 "i"A *»oo |
11 35:51 37>34\ 37s59 A "I33 \*i" A t\2k, 33 29,49 A J
k . ^ A^VA „. ^^ J* Jl ^ ^ A^AAJL ^yV/v UA. . .*l\ I *&A . r*. /Vv A*A/I
37:00 38:00 39:00
20



L?°<"
.7.2X4
'-.5.8X4
.4.3X4
-2.9S4
'-.1.4X4
'• a . ata
30,00 Time
329

-------
              ti-724 Aoq, 7-JAH-j.yyo vj.:je,uo sc EI+  Voltage SIR 70S SoiaetlOZ
 353.8546 r>3 3803(356,30, -3.0) PXD(5,5,3, 0.05\,408.0,1.00\,r,T) XJCpsXDBSUS
          LASS  Tart: 198/199/205/208  TLH44376A
 100*  A4.30X7               A3.25X7
                                                                             A3.62X6
      27:48 28*, 00  38,13 28,24 28,36 28,48  29,00 39,13 29,24 39,36 2948
Tilm,U9a0036  tl-724 Aoq,  7-JAW-1998  01,28,06 CC EI+ Voltage SXX 70S Soite,83
357.8516 r,2  BSOB(256,30,-3.0) rXO(5,5,3,0.05\,332.0,1.00\,T,T) XxptSDBSUS
TStlAIKLX LABS Tort, 198/199/205/308  TLX944376A
1001  A3. 88X7
                                                                                        3o,24
  80.

  60.

  40.

  20.
                            A3.09X7
                                      A1.37X7
                                                    AS.53X6
                                              A3.86X6
      27:48 28,00 28:12  28,24  28,36 28,48 29,00 ' 39', 12' 29,24' 29', 36 ' iii<«
FiloiU98003S tl-724 Aeqt 7-J7Uf-1993 01,28,06 SC EI+ Voltage SIS 70S Noiae,7S
367.8949 Ts2 SSUS(256, 30, -3.0) PXD(Sr5,3,0.05\,312.a,1.00*,T,r) XrpsRDBSUS
TRIAXGLX LABS  Text:198/199/205/208  TLH44376A
100\                                                         A.2.38X7
  80.

  60.

  40.

  20.
                                                                                        30:24
      27,48 28,00 28,12  28,24  28:36 28,48 29,00  29,12 39,24 39,36  29,48 30,00 30,12 30,24
r±2atO980036 tl-724 Acq, 7-JMT-1998  01,28,06 SC £J+ Voltage SIX 70S NoiaatBO
369.8919 f,2 BSUB(2S6,30,-3.0) PXD(5,5,3, 0.05%, 330.0,1.00\,T,T) XxptKDBSUS
TRIAKSLX LABS  Taxt,198/199/205/208  TLH44376A
100\                                                         JU..57X7

 80.

 60.

 40.

 20.
      37148 28,00 28,12  28,24  28,36 28,48 29,o6"39il3"39:34"39,36' 39,48' 30,66' 36,12' 30,24 '
r±la,U980036 tl-724 Aoqt 7-JJOT-1998 01,38,06 SC tt+ Voltage SIS 70S
 30.9792 r,2 XlpiSDBSUS
TBIANGLX LABS  T*xt,198/199/20S/208  XLIt44376A
1004

 80.

 60.

 40.

 20.

  0.
                                                    29,17
                                                                          29,58
                                                                                                -1.0X7

                                                                                                '.8.1X6

                                                                                                .6.1X6

                                                                                                .4.0X6

                                                                                                L3.0Z5
                                                                                                .0.0X0
                                                                                                    Mm.
-9.1X6

 .7.2X6

 .5.4X6

 .3.6X6

.1. 8X6
                                                                                                 O.OEO
                                                                                                    T±ae
-7.0X6

.5.6X6

.4.2X6

.2.8X6

.1.4X6
                                                                                                .0.0X0
                                                                                                    Tlae
                                                                                                4.6X6

                                                                                                '.3.7X6

                                                                                                .2.8X6

                                                                                                .1.8X6

                                                                                                .9.3X5
                                                                                                .0.0X0
                                                                                                   Time
-3.9X7

.3.1X7

.3.3X7

.1.6X7

.7.8X6
      27,48 28,00 28,12 28,24  28,36 28,48 29,00  29,12 23,24 39,36 29,48  30,00  30,12 30,24
                                                                                               '.0.0X0
                                                                                                   Tiae
                                                                                                        33
                                                                                                             0

-------
rJJ.»:O980036  tl-385 Acq:  7-JZJT-1999 01:28:06 GC XI* Voltage SIX 70S Noise, 31471
373.8308 f:3  BSUS(2S6,30, -3.0)  PXS(7,5,3,0.10\,325884.0,1.00\,r,T)  XxpiHDBSUS
TBIANGLX LASS  Text:198/199/205/208  XLIt44376A
1001       A7.79X7
  00:

  50:

  40:

  20:
                                    AS.99X7
      A3.33X
                                                      A2.33X7
                                                                                 A4.81X6
                2.2X7

                .1.8X7

                '•.1.3X7

                '•.8.9X6

                .4.4X6
                                                                                                     0.0X0
                                                                                                        Tine
    31:00 31,12  31t24 31:36 31i4B 32tOO  32tl2 32i24 32,36 32,48  33,00 33,12 33,24 33,36  33,4S
r±let0980036 tl-385 Acq: 7-JUT-1398 01:28,06 GC XI + Voltage STB 70S Hoiae:67253
375.8178 Tt3 SSOS(256, 30, -3.0) PXO(7,5,3,0.10\,269012.0,1.00\,r,T) StptHOBSVS
XSIASGLX LASS  Text: 198/199/205/208  TLH44376A
ion
  30.
  $o:
  40:
  30:
   oj
           A6.29X7
      A2.69X7
                                    A4.BOX7
                   A9.40X6
                                                      A1.38E7
                                                                                A3.85X6
    Jl.-OO  J1.-13  31:24 31:36 31:48  32:00 32:12 32:24 32:36  32:48 33:00 33:12 33:24  33:36 33:48
rl2e:O980036 tl-385 Acq:  7-JAS-1998 01:28:06 GC XI+ Voltage  SIX  70S Koiae:7338
383.8639 T,3 SSUS(256,30, -3.0) fXD(7,5,3,0.10\,29352.0,1.00\,r,T)  XxptSDBSUS
TSIAIfSLX LASS  Text:198/199/205/208  TLIt44376A
1001                                   A2.37X7
    I                                   H  ft           A2.07X7
  aol
 30:
  o:
    Jl-OO 31:12  31:24 31:36 31:48  32:00  32:12 32:24 32:36  32:48  33:00 33:12 33:24 33:36  33,48
    10980036 tl-385 Acq: 7-JZS-1998 01:28:06 SC XI+  Voltage  SIS  70S Koiae:2761
385.8610 T,3 BSUB(256,30,-3.0) fXS(7,5,3, 0.10\,11044 . 0,1. 00\,T,1) Kxp-.SDSSUS
XSIAHGLX LASS  Text: 198/199/205/208  ZLH44376A
ion
 sol
 so:
 40:
 30:
  o.
    Jl.-OO 31:12  31:24 31:36 31:48 32:00  32:12 32:24 32:36 32:48  33:00 33:12 33:24 33:36  33:48
TilaiU980036 tl-385 Acq: 7-JAN-1998 01:28:06 SC XH- Voltage SIS 70S
392.9760 Tt3 EiptlTDBSUS
TRIANGLE LABS  Text: 198/199/205/208  TLIt44376A
100J
 80:
 50:

 40:
 30:

  o.
         31:10 31:21
                                                             32:49
               _1.7X7

               -.1.4X7

               '-.1. 0X7

               '.6.9X6

                3.5X6
                                                                                                    ,0.0X0
                                                                                                       Tine
                                                                           331!6
33:35 33:46
    Jl.OO 31,12  31,24  31,36 31:48 32,00  32:12 32:24 32,36 32,48  33,00  33:12 33:24 33i36  33:48
 •iletU980036 tl-385 Acq, 7-JAB-1998 01:28:06 GC XI+ Voltage SIX 70S
445.7555 Tt3 XxpiSDSSUS
TXIAKSLX LASS  Tart: 198/199/205/208  TLH44376A
J..9X7

,1.5X7

,1.1X7

.7.6X6

3.8X6

0.0X0
   Tiae
    31:00 3l':12 31:24  3l':36 31':48 32:00 32:12  32:24 32:36 32:48 33:00  33:12 33,2433:36
                                                                                                      331

-------
 rHasuSBoojo  fl-jas Acq, 7-JAa-j.yyo umotuo sc sir voltage SIS 70S
 389.8156 n3  3303(356,30, -3.0) PXD(7,S,3,0.10\,52276.0,1.00\,T,X)  XxptNDBSUS
 TSIASSLS LASS  Text:198/199/205/209  OJt44376A
 100*
  80.
  SO.
  40.
  20.
        AS.45X6
         A
                                        A3.65X6
                                                          A3.4 0X6
                                                                      A4.07X6
                                                                                              -.1.0X7
                                                                                                .8.1X6
                                                                                                .6.1X6
                                                                                                .4.1X6
                                                                                                 0.0X0
          31:36   31:48    32:00    32:12   32:24   32:36   32:48    33:00   33:12    33:24    3336
rile,0980036  tl-385 Acq:  7-JAS-1998 01:28:06 SC XI+  Voltage SIS 70S Itoiae, 15018
391.8127  Ti3  BSU3(256,30,-3.0) f*D(7,5,3,0.10%, 60072.0,1.00\,T,T) KxpiHDBSaS
TSIASSLX  LABS Text: 198/199/205/208  TLH44376A
                              '9X7                                                              ^8.4X6

                                                                                                .6.7X6

                                                                                                .5.0X6

                                                                                                .3.4X6

                                                                                               .1.7X6
80.

60.

40.

20.
       A4.46E6
         A
                                           .42X6
                                                         A3.05X6
                                                                      A3.57X6
         31:36    31:48   32:00    32:12   32:24   32:36   32:48    33:00   33:12   33:24
Til»:U980036 tl-385 Acq:  7-JJUT-1998  01:28:06 SC ZI+ Voltage SIS 70S Hoists,2456
401.8558 T,3 BSUB(256,30,-3.0) rXD<7,5,3,0.10\,9824.0,1.00\rT,T) XxpsSDBSVS
XSIANSLX LABS  Text: 198/199/205/208   TLH44376A
1003\                                                       A3.}2X7      A3.22X7
                                                                                             33
                                                                                                 0.0X0
                                                                                                36 Time
  80.

  60.

  40.

  20.
                                                      ALSO
         31:36    31:48   32:00   32:12    32:24    32:36   32:48   33:00    33:12
r±le,OS80036 tl-385 Acq:  7-JAtT-1998  01:28:06 SC XI* Voltage SIS 70S Soiae:1430
403.8529 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.101,5720.0,1.00*,r,T) Xxp:NDB5VS
XRIASSLX LABS  Text: 198/199/205/208  XLIt44376A
1003,                                                       A2 61X7      A2.62X7
 80.

 60.

 40.

 20.
                                                                                    33:24    33 36
         31:36    31:48   32:00   32:12    32:24    32:36   32:48   33:00    33:12   33:24
r±l*:U9B0036 tl-385 Acq:  7-JAH-1998 01:28:06 SC XI* Voltage SIS 70S
392.9760 r,3 ExptHDBSOS
TSIAHOLX LABS  Text: 198/199/205/208  TLII44376A
                                                                                             33:36
lOOi

 80.

 60.

 40.

 20.
   31:28
                    31:51
                                                            32:49
-1.9X7

.1.5X7

'.1.1X7

'.7.6X6

'.3.8X6
         '31:36    31:48   32:00   32:12   32:24    32:36    32:48   33:00    33:12   33:24
                                                                                           33
                                                                                              .0.0X0
                                                                                              36  Tift
                                                                                                        332

-------
 rile,0930036 tl-545 Acq,  7-JMT-1998 01:28:06 SC XH- Voltage SIS 70S Soimet6424
 407.7818 r,4 BSUB(2S6,30,-3.0)  PXD(7,5,3,0.10\,25696.0,l.QO\rTtT) XxpiHDBSUS
 TSIAOSLX LABS  Text ,198/199/205/208  TLH44376A
         A4.29X7
                                                                          A3.94X6
         35', 00    35', 12    35,24    35*36   35,48   36,00    36,12    36,24   36,36
Tile:U980036 tl-S45 Acqt  7-J2OT-1998 01,28,06 CC XX* Voltage SIS 705 Soime:4545
409.7789 r,4 3SUB(256,30,-3.0) PXD(7,5,3,0.10\,lB180.0,1.00\,r,T) XxpiSDBSUS
          LABS   Tart:198/199/205/208  TLH44376A
                                                                          36,48
                                                                          A3. 73X6
        35', 00    35,12    35,24    35,36    35,48   36', 00    36', 12    36': 24    36,36    36', 48
r±la,C980036 tl-545 Acq,  7-JJOT-1998  01,28,06 SC ZH- Voltage SIS 70S Noiaa,3509
417.8253 r>4 BSUB(256,30,-3.0) PKD(7,S,3,0.10\,14036.0,1.00\rT,T) ErpiUDBSUS
TRIANGLE LABS  Text, 198/199/205/208   TLH44376A
IOCS    A1.1SX7
                                                                          A7.76E6
        3S',00    35',12    35,24   35:36    35,48   36,00    36,12   36,24    36,36
rila:U9B0036 tl-545 Acxj:  7-JXJT-1998  01:28*06 CC XH- Voltage SIS 70S Noiee:3009
419.8220 r,4 BSUB(256,30,-3.0} PXD(7,S,3,0.10\r12036.0,1.00\,r,T)
TSIASSLX LABS  Textil98/199/205/208   TLH44376A
10 0\    A2.69X7
                                                                          A1.97E7
                                                                          36,48
        35,00    35:12    35,24    35:36    35,48    36:00    36,12    36,24
rila,0980036 tl-545 Acq:  7-JAS-1998 01:28,06 SC XH- Voltage SIS 70S
430.9729 T:4 XxpiSDBSOS
TSIANSLX LABS  Text: 198/199/205/208  TLIt44376A
                                        J5AH^_^ -Vl"f__    36:17 36:25,
                                                                             36:36
                                                                                      36:48
                                                                                                   -9.8X6

                                                                                                   '•.7.9X6

                                                                                                   .5.9X6

                                                                                                   .3.9X6

                                                                                                   .2.0X6

                                                                                                   .0.0X0
                                                                                              '37100    TLma
                                                                                                   -9.1X6

                                                                                                    .7.3X6

                                                                                                    .5.5X6

                                                                                                    .3.7X6

                                                                                                   .1.8X6
                                                                                       .0.0X0
                                                                                  37:00    T±ae
                                                                                                    O.OEO
                                                                                               37': 00    T±me
                                                                                        O.OEO
                                                                                  37:00    Time
 50:
 40:
  Oj
        35,00    35,12    35,24    35,36    35,48   36,00    36,12    36,24
Tila,U980036 tl-545 Acq:  7-JAS-1998 01:28,06 GC XH- Voltage SIS 70S
479.7165 r,4 XxptKDBSUS
TRIANGLE LABS  Texttl98/199/205/208  TLIt44376A
100$                35; 17

 80:
                                                                 36,36
                                                                         36,48
                                                                                                    0.0X0
                                                                                              37', 00    Time
 60:

 40:
 20:
     34155
35:06
        J5>00
                 35,12
                                                                     36:41
                                                     36:20
                         35124
                                  35:36
                                              "A" 36,01 3S,09
                                             /vy  A ~\^ A
                                           35,48
                                      36*: 00
                                                           36:12
                                                                                                   -3.4X4

                                                                                                   -.2.8X4

                                                                                                   '•.2.1X4

                                                                                                   '.1.4X4

                                                                                                   -.6.9X3
                                                                    36:24
                                                                             36:36
                                                                                      36,48
                                                                                                   .0.0X0
                                                                                              37:00    Time
                                                                                                         333

-------
              il-545 Acgi 7-J3UT-I*** ui-.JtttU* CC SI* Volttyu SIX 70S
 433.7766 Tt4 3SUB(256,30,-3.0) PKD(7,5,3,0.10\,2208.0,1.00\,r,T) XzptSDBSOS
 XSIA1KLX LASS  T»X*il9S/199/20S/2QB  TLH44376A
 100*       AS.
                                                             AS.33X6
      	         ,...  ,,...  ..... ,,-r^r   ,-r-^-T-^T-r-r-r-r-TT-r-r-r-r-r-r^-rT-T-^            10. 0X0
      J5»i.j'J5ii«'35134' J5ijo'35t36'35t43'35t48 J5«54'j«>06' j«ibtf' JSiii'jtfTifl'36^34 36\30     Tl*<
 ril»i0980036 tl-545 Acq,  7-JAN-1998 01,28,06 CC XT* Volttgm SIS 70S Noi*»il845
 ,435.7737 f,4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,7380.0,1.00\,r,T)  XxpiSDBSUS
 XXIAHSLX LASS  Ttat,198/199/305/308  TLH44376A
 100\        A6J2X6
      35,12 35,18  35,24 35',30  35:36 35',42  35',48  35:54 36,00  36:06
rile,0980036 tl-545 Acq: 7-JAH-1998  01:28,06 CC EH- Voltage SIS  70S Noise,2306
435.8169 f,4 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,9224.0,1.0Q\,r,T) EzptXDBSOS
TBIAHGLX LABS  Text, 198/199/305/308  TLH44376A
                                                                                   3624
                                                                                                    Tiae)
 1003

  SO.

  60.

  40.

  30.
                                                            Al.
             Jifl 35 1 24  35,30 35:36 35,42  35,48 35,54
\rilaiU980036 H-545 Acxj:  7-J3OT-1998 01,28,06 CC SH- Voltage SIR 70S lfoiae,13B9
437.8140 Tt4 BSOB(356,30,-3.0) PXO( 7,5, 3, 0.10\rS5S6.0,1.00\,T,X)  XxptSDBSOS
TSIAHSLZ LABS Textt 198/199/305/308  XLXI44376A
100\                                                        Al. 68X7
  80.

  60.

  40.

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                                                                                                 0.0X0
                                                                36',06 36,12  36',IB 36,24  36',30     Tiae\
      35',12 35',ia  35i24 35i30  35t36 3Si43
             H-545 Acq, 7-JZH-1998  01,28:06 CC SI+ Voltagw SIS 70S
430.9739 Ti4 XxptODBSVS
TSIAHSLX LABS  T«rt» 198/199/305/308  TLH44376A
       35,13    SStSl^JZ*38   .          35L44                J6,04
100$

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                    s*  sss   35, 36 35 142
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                                                                                                    TiM€\
                                                                                                        334

-------
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Text: 198/199/205/208 TLIf44376A










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35:00 ' 36:00











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XXIANSXX LABS
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Tart: 198/199/205/208 TLH44376A











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TSIAHGZX LABS Text: 198/199/205/208 TLK44376A
1001
901
801
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sol
sol
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301
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101
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                                                                                                0.0X0
                                                                                                   Time
                                                                                                        336

-------
                                                                                 co
Peak Locate Examination: 7-JAN-1998:01:26 File:U980036
      Experiment:NDB5US Function:2 Reference:PFK

-------
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Sample  Text:198/199/205/208  TLIS44376A File Text:TRIANGLE  LABORATORIES,
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-------
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341.8567 F:2 Exp:NDB5US
Sample Text:198/199/205/208   TLI#44376A File Text:TRIANGLE LABORATORIES, INC
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File:U980036 #1-724  Acq:  7-JAN-1998 01:28:06 GC EI + Voltage SIR 70S
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Sample Text:198/199/205/208  TLI#44376A File Text:TRIANGLE LABORATORIES, INC
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-------
Flle:U980036 #1-385 Acq:  7-JAN-1998 01:26:06 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:NDB5US
Sample Text:198/199/205/208   TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
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Sample Text:198/199/205/208   TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
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File:U980036  Sl-385 Acq:  7-JAN-1998 01:28:06 GC EI+ Voltage SIR 70S
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Sample Text:198/199/205/208   TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
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-------
 ile:U980036 #1-545 Acq:  7-JAN-1998  01:28:06  GC  EI+ Voltage SIR 70S
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Sample Text:198/199/205/208   TLI#44376A  File  Text:TRIANGLE LABORATORIES,  INC.
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File:U980036 #1-545 Acq: 7-JAN-1998  01:28:06  GC  El-f  Voltage SIR 70S
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File:U980036 #1-545 Acq:  7-JAN-1998  01:28:06  GC  EH-  Voltage SIR 70S
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Sample Text:198/199/205/208   TLI#44376A File  Text:TRIANGLE LABORATORIES,  INC.
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-------







TLI Project: 44376A Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: 198/199/205/208 ^; ,A _ Analysis File: P980104
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-18A/B Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000
Dry Weight n/a
GC Column: DB-225
Dilution Factor n/a
Blank File: P980094
Analyst WK
Spike File: SPC2NF04
ICal: PF22206
ConCal: P980092
% Moisture: n/a
% Lipid: n/a
% Solids: n/a


23,7,8-TCDF 1
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0.77 23:05 	

13C,j-1^3.4-TCDD 0.81 21:54 	
                          Dasa Reviewer.
01/09/98
                                                Page 1 of 1
                C^NP.PSR.2.01. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 10:1701/09/98
                           342

-------
                        Initial
                                    , .Date.
  Data Review By:
                                              Calculated Noise Area:
                                                                     1.00
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits haa  been recalculated according to method requirements.
  Page Ho.
  01/07/98
Listing of P980104B.dbf
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio  Total.Area...  Area. Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
TCDF
304-306 DC NL 0
18
18
18
18
19
19
19
19
19
20
20
20
20
20
20
21
21
21
21
21
21
22
22
22
22
22
23
23
23
23
23
24
24
24
25
DC WH 25
0
:00
:27
:43 RO
:55
:59 RO
:05
:27
:35
:42
:53
:00
:10
:19
:28
:37
:46
:10
:21 RO
:27 RO
:36
:43
:51
:06
:20
:31
:44
:58
:06
:19
:35
:42
:55
:16 RO
:30
:40
:15
:42
.65-0.89
0
0
1
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
.77
.79
.06
.69
.34
.72
.75
.78
.77
.78
.78
.77
.77
.78
.76
.75
.76
.53
.21
.75
.75
.76
.75
.77
.76
.75
.75
.77
.75
.76
.76
.83
.20
.74
.84
.75
.77
304-306 35 Peaks
13C12-TCDF
316-318 DC NL 0
DC WL 18
DC WL 20
0.
:00
:31
:07 RO
0.792-1.101
2.95
627.
47
20.36
16.79
17.
48.
902.
765.
1,388.
701.
110.
720.
1,520.
862.
2,531.
907.
5,246.
9.
20.
1,246.
220.
1,304.
1,243.
262.
1,539.
8.
1,275.
955.
1,471.
1,689.
1,548.
8.
2.
1,002.
24.
204.
17.
30,426.
17
91
06
41
68
16
52
47
23
72
77
79
57
77
36
01
26
22
40
66
40
52
94
12
99
13
87
23
53
81
86
37
92
53
276.
12.
6.
13.
20.
388.
334.
602.
307.
48.
312.
660.
376.
1,092.
388.
2,270.
4.
13.
533.
94.
562.
534.
114.
664.
3.
548.
414.
629.
731.
669.
3.
1.
427.
11.
87.


94
,24
as
04
48
06
61
65
26
53
65
68
91
61
98
75
25
89
16
29
50
02
06
60
66
58
23
98
64
49
74
71
67
35
43


350.
11.
9.
9.
28.
514.
430.
786.
393.
61.
407.
859.
485.
1,439.
518.
2,975.
8.
11.
712.
125.
741.
709.
148.
874.
4.
727.
540.
842.
957.
879.
4.
1.
575.
13.
116.


65-0.89
0
0
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1.49
2.
3.
4.
46
94
64









53
50
94
70
43
00
80
03
90
99
82
55
31
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81
32
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85
97
72
38
60
80
86
36
89
01
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38
49
43
14
51
94


0.
0.
0.
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0.
0.
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0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

0.957-



0.
0.
0.
000
799
811
819
822
827
843
848
853
861
866
874
880
887
893
900
917
925 J
929
936
941
947
957
968
975
985 J
995
001 2378-TCDF AN
010
022
027
036 J
051 J
061
069
094
113

1.043
000
802
871
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 10:26 01/07/98

                                                                                343

-------
  Page No.
  01/07/98
Listing of P980104B.dbf
Matched GC Peaks / Ratio /
                                                  Ret. Tlae
Compound/
H_2	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.

                                                                               0.890
                                                                               0.924
                                                                               0.935
                                                                               0.946
                                                                               1.000 13C12-2378-TCDF ISO
                                                                               1.027
                                                                               1.042
                                                                               1.045
                                                                               1.090
                                                                               1.106
  316-318
  13C12-TCDD
  332-334
DC
DC
DC
DC



DC
DC
DC
DC

WL
WL
WL
WL



WH
WH
WH
WH
3
20:
21:
21:
21:
23:
23:
24:
24:
25:
25:
25:
33
20
35
50
05
42
03
08
10
32
38
RO
RO
RO


RO

RO

RO
RO
0
1
0
0
0
1
0
0
0
0
0
.37
.66
.58
.78
.77
.17
.71
.94
.73
.59
.95
Peaks
5
4
12
29
2,584
6
4
3
30
3
2
2,594
.10
.50
.11
.42
.39
.18
.00
.68
.47
.95
.27
.57
                                                          1,127.12
                                                             4.08
                                                             1.66
                                             1,457.27
                                                 3.49
                                                 2.34
                                                                                1.110
                                       Above: TCDF / TCDD Follows
  332-334
DC




DC
DC
DC

0.
NL 0:00 RO
20:29 RO
21:37
21:54
22:39
WH 24:24 RO
WH 24:30 RO
WH 24:58 RO
4 Peaks
65-0.89
1.59
0.92
0.77
0.81
0.67
1.47
0.40
0.55

0.96
6 . 07
1,705.95
2,020.85
21.53
5.42
3.10
3.29
3,754.40
0.908-1.092
0.000
3.16 3.43 0.948
744.78 961.17 1.000
903.66 1,117.19 1.013
8.63 12.90 1.048
1.129
1.133
1.155


13C12-2378-TCDD IS1
13C12- 1234 -TCDD RSI





 Column Description	  "Why* Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time  (mm:as)
 Rat.l -Ratio of M/M+2  Ions
 OK    -RO-Ratio Outside Limits
 Rel.RT-Relative Retention Time
  ••• End of Report
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SM-Below Signal to Noise Level
       
-------
TlJ.asP9B0104  tl-922 Acq: /-JAa-yo OU:JJ.iJS Sir voltage SIS 70P
303.9016 BSUB(256,30,-3.0)  PXD( 5, 3, i, 0.10\,2564.0,0.00\rr,r) Erp:DB225
TSIAOGLX LASS  Taxt:198/199/205/208   TLH44376A
1001                               A2.27X7
                                            AS.62X6 AS.65X6      A7.32X6
          19:00        30:00       21:00       22:00       33:00       24:00
F±J.e:P980104  H-922 Acq: 7-JZN-98 08:31:29 XH- Voltage SZS 70P Soiae:837
305.8987 3SVS(25S,30,-3.0)  rKD(5,3,l, 0.10%, 3348.0,0.00\,r,f)  XxptDS225
TSIASGZf LABS T«rt.-198/199/205/208   TLII44376A
1001                                A2.98X7
             25100
          19': 00        20:00       21:00       22:00       23:00       24:00
T±letP980104  tl-922 Acq:7-J7OT-98  08:31:29 KC+ Voltage 5XS 70P SOiaet578
315.9419 BSVB(2S6,30,-3.0)  PXB(S,3,l,0.10\,2312.0,0.00\,T,r)  Sxp:DB22S
TBIJUIGZS LABS  Text! 198/199/205/208    TLH44376A
1003i                                                       A1.}3E7
  80.
  60.
 40.
 20.
             25100
          19:00        20:00        21:00       22:00       23:00       24:00
rile:P980104 tl-922 Acqt7-J7Ur-98  08:31:29 SH- Voltage SIB  70P Noise: 652
317.9389 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,3608.0,0.00\,rrr) EzptDB225
TRIXHGLE LABS  Tart: 198/199/205/208    TLXM4376A
1001                                                       A1.46E7
 80.

 60.

 40.

 20.

  0.
             25:00
          19:00       20:00        21:00       22:00       23:00
F±latP980104 tl-922 Acq:7-JXN-98  08:31,29 XH-  Voltage SIX  70P
375.8364 SzpiDB225
IJtlAKOLE LABS  Ttxtt 198/199/205/208   TLIt44376A
100\
24: 00
                                                                                   25100
                          3.1X6

                         '.2.4E6

                         .1. 8X6

                         .1.2X6

                         .6.1X5
                          0.0X0
                             X±me
                         3.9X6

                         '.3.1X6

                         .2.3X6

                         '.1.6X6

                         .7.8X5
0.0X0
   T±me\
          19:00
                      20:00
                                   21100
                                               22:00
                                                           23:00
                                                                       24:00
                                                                                   25100
                                                                                                     345

-------
                30,00            21:00           33:00           33:00
rUa:P980104 tl-922 Actj:7-J3UT-98 08:31:29 EH- VoJtaya SIK 70S Hoiae:648
327.8847 BSOB(256,30,-3.0)  PXD(S,3,l,0.10\,2593.0,0.00\rT,T)  Xxp:DB335
TSXAXKLX LASS  Tart: 198/199/305/308   TLH44376A
 rn.atP9a0104 il-922 Acq: 7-JAN-9B  08:31:29  EI+  VOltagra SIS  70P Ntij.aa:405
 319.8965 BSUB(256,30,-3.0) PKV( 5,3,1, 0.10\,1620.0,0.00\,r,f) XxptDB235
   iASeZX LASS  Taxt: 198/199/305/308    TLH44376A
 ion
  80.

  SO.

  40.

  20.
A9.83X6
                        AJ..57X6
                          A  xvA
                                    AS.07S3
                                               A2.99Z6
                20:00            31:00           32:00           33s 00
 Til»tt980104  11-922 Acq:7-J7UT-98 08:31:29 XI+ Voltmgm SIS 70P Soiamtl451
 321.8936 3303(356,30,-3.0) PKD(S,3,1,0.10\,5B04.0,0.00\,T,T) Kxp:DB335
 XXIAHOJS LASS  Tmit: 198/199/205/208   TLH44376A
 100\
                                                                     24:00
  80.

  60.

  40.

  20.
A1.35S7
                       A3.OOE6
                          A  ^  A
                       Al.04E6
                                               A3.85S6
                                                                     34:00
 100)

  80.

  60.

  40.

  20:
                 A4.48Z7
                                   A4.83E7
                              A1.53X7
                        A3.60X6
                           y\
                                                                              A3.36E6
                30:00            31:00           33:00           33:00
 'LLa:P980104 il-922 Acqi7-JJOT-98 08:31:29 KH- Voltage SIS 70P Soiaei431
 '31.9368 BSUS(256,30,-3.0)  PXD(S,3,1,0.10\r1724.0,0.00\,T,T)  Sxp:DS335
 SIAWCLI LABS  Text:198/199/305/308   TLH44376A
 ,00\                                          AS. Q4Z6
                                                                                 34:00
 80.

 60.

 40.

 20.
                                          A7.45E6
                20:00           21:00           22:00            23:00
r±J.a:P980104 tl-923 Acqi7-JJW-98  08:31:29 XX* Volt*g*  SIX  70P Jtoltt>i270
 33.9338 BSUB(356,30,-3.0) PKD(5,3,1,0.10\,1080.0,0.00\,r,T) Xxp:DB335
 TtlAMSLS LABS  Text: 198/199/305/308   TLH44376A
100\
                                         A9.61X6
 80.

 60.

 40.

 30.

  0.
                                                                                 24:00
                20100
                                21:00
                                                 22:00
                                                                23:00
                                                                                 24:00
-4.4X6

 .3.5X6

 .2. 7X6

.1. 8X6

.8.9X5
                                                                                        .0.0X0
                                                                                     25 00 Tia,
-5.SX6

'.4.5X6

.3.4X6

.2.3X6

.1.1X6
                                                                                        .0.0X0
                                                                                     25 00  Time
-1.4X7

.1.1X7

.8.3X6

.5.6X6

'.2.8X6
                                                                                        '.0.0X0
                                                                                     35 00  Time
                                                                                        -2.5X6

                                                                                        .2.0X6

                                                                                        .1.5X6

                                                                                        .9.8X5

                                                                                        .4.9X5
                                                                                        .0.0X0
                                                                                     25 00  Time
                                                                                                 25
                                                                                        -2.9X6

                                                                                        .3.4X6

                                                                                        .1.8X6

                                                                                        .1.2X6

                                                                                        .5.9X5

                                                                                        .0.0X0
                                                                                        00  Time
                                                                                                    346

-------
r±le:P980104 tl-922 Acq s 7 -JAN- 9 8 08:31:29 XH- Voltage SIS
303.9016 Xxp:DS225
TSIASGLX LASS Text: 198/199/205/208 TLIt44376A
1001
ao.

SO.
40.

20.
0
21:10
ft
20:J7 1
1 \
15:42 B 1 21:51 22:J1
i 20:15 i i A
19l37h A , ft ft A rt
A MAj/lVlA 11 JUIL/I
15:00 20:00 21:00 22:00
rile:P980104 tl-922 Acqi7-JAN-98 08:31:29 XH- Voltage SIS
315.9419 Xxp:DS225
TSIAJKLX LASS Text: 198/199/205/208 TZH44376A
1001
ao.
60.
40.
20.
0






19\00 ' ' ' 20106 ' ' 21:00 ' 22:00
r±le:P980104 tl-922 Acq:7-J3UT-98 08:31:29 XI+ Voltage SIS
319.8965 Xxp:DS235
TSIANSLX LASS Text:198/199/205/208 TLIt44376A
1003
ao-.
so-.
40:
20:
o:
S" 16
15-50


1 20: 30 21:54
l\ A ^ A 21A15 ^>/V
15:00 ' ' ' 20:00 ' ' 21:00 ' ' 22:00
TLLatP9a0104 tl-922 Acq : 7 -JAN- 9 B 08:31:29 XI+ Voltage SIS
331.9368 ExptDB225
TSIASSLX LASS Text: 198/199/205/208 TLIt44376A
1003
80:
50:
40:
20:
0:
21:54
T



/I /I
15:00 20:00 21:00 22:00
TU.e:P980104 tl-922 Acqt7-JAN-98 08:31:29 XI* Voltage SIS
252.5825 Xxp:DB225
TSIASGLX LASS Text: 198/199/205/208 TLIt44376A
1001
80:
50:
40:
20:
o:
, 	 19*09 19 1 57 20:26 20t58 21:43 22:14
*"*^l1**rfcUinj*~'.i-n-«liiJ^_r i — VfX-H 	 -L'^^mtf JrV~Ti^*"^>ji_ruA. *A *^iA^kX>rsA\J
1 ^ »1p J • ' ^ • JV^^f |W ^•MP*» ' *^f * ^r' ^T^^T T»VA/^ TT *^TT ¥"•*«




15:00 20:00 21:00 22:00
Tile iP9 80104 tl-922 Acqi7-JAN-98 08:31:29 EH- Voltage SIS
330.9792 Xxp:DS225
TSIAHSZX LASS Text: 198/199/205/208 TLIt44376A
1001
80:
50:
40:
20:
o:
18:42 15:55 20:27 20:58 21:J2 22:25
70J»


_J.7*ff



2J:J5
MA A
24. -JO
M A ,
.2.9X6

.2.2X6
.1 . 5X6

.7.3X5
0.0X0
23:00 24:00 25:00 Mjie
70J>


2J:05 J.UT5




H
.2.4X6
.1 . 8X6
.1.3X6
.6.1X5
0.0X0
23:00 24:00 25:00 Tiae
70P


4.4X6





.3.5X6
.2.7X6
.1 . 8X6
.8.9X5
O.OEO
23:00 24:00 25lo0 Tiae
70P


-2.5X6





.2.0X6
.1.5X6
.9.8X5
.4.9X5
O.OEO
23:00 24:00 ' ' ' 25:06 Tiae
70P


_^2J:12_ ^J.19 25^02 25 :^32C2. 7X6
V^VV^^^"^JJ^^^^




-2.2X6
.1 . 5Z5
.1.1X6
.5.4X5
0.0X0
2J:00 ' ' ' 24106 ' ' ' 25:06 ' ' ' Tiae
70P


23:38 24:14 25:03 -2.1X6

15100 20:00 21:06 22', 00
'.1 . 7X6
.1.3X6
.8.5X5
.4.3X5
O.OEO
23:00 24:00 ' 25:00 ' Time
347

-------
tef, tass    292,9825     Peak top
Height   ,51 volts Span   298 ppi
Systai file nae
Data  fllenaie
Resolution
Grotpfxitef
loniiatlon nde
Switching
tef, lasses   292,9825,
R   232.9825
B   383,9816
C   365,8987
D   315,9419
E   317,9389
F   319,8965
G   321,8936
H   327,8847
I   338,9792
J
K
L
H
       1
     El*
 VOICE
388,9761
338,9792
331,9368
333,9338
375,8364
Channel   I  338,9792     Peak top
Height    ,36 volts  Span   288 ppi
                                                      343

-------
TLI Project:
Client Sample:
                  44376A
                  201-204
O
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980035
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAIN
194-59-19A-D
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/07/98
n/a
U980026
JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a

AnaJytes
2,3.7,8-TCDD
1.2,3,7,8-PeCDD
1,23,4,7.8-HxCDD
l,2J,6J,8-HxCDD
1.2,3,7,8,9-HxCDD
l,Z3,4.6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2.3,7,8-PeCDF
2,3,4,7,8-PeCDF
1 2J ,4,7,8-HxCDF
*.2J,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1.2,3,4,6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

•"%£«&. $»g) -OL - EMPC
ND 0.004
0.02
ND 0.01
0.02
0.03
EMPC 0.09
0.16
0.29
0.07
0.12
0.23
0.09
0.12
ND 0.007
0.43
EMPC 0.05
0.31

yH&nt #ug , number Bt - EMPC
0.22 5
0.24 6 0.42
0.33 5
EMPC 0.18
15 13 • 1.5
1.6 12 1.6
0.96 8 1.0
0.65 3 0.70
'•^ ""


1.58

1.12
1.20

0.91
0.76
1.73
1.65
1.23
1.22
1.27

1.10

0.83

i









RT

29:36

32:50
33:07

39:37
24:40
28:35
29:16
32:02
32:08
32:37

35:01

39:49











Flags

j 	

j 	
J
J_
JB_
B_
J_


J 	



J 	


Flags



—




                                       Page 1 of 2
                                                                       MTI2_PSR v 1 JO I. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                            Printed: 10:51 01/10/98
                                      349

-------
 TLI Project     44376A
 Client Sample:   201-204
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980035
internal S&BK&R& •• ••

13Cir2^J,8-TCDF
13C 12-2^,7 ,8-TCDD
l3C,2-1^3,7,8-PeCDF
13C,2-U,3,7,8-PeCDD
1JC,2-1.2,3,6.7.8-HxCDF
l3C,2-1.2,3,6,7,8-HxCDD
l3C,2-U.3,4.6,7,8-HpCDF
13C,2-l,2,3A6,7,8-HpCpD
13C ,2-1 ,2,3,4,6,7,8,9-OCDD

Surroo^ Standards {Type A}

IJCir2JA7.8-PtCDF
13C,2-U,3,4,7,8-HxCDF
IJCn-lA3.4.7,8-HxCDD
13Ci2-l,2,3,4.7,8.9-HpCDF

Surrogate Standards (Type AJ
37CL,-2,3,7,8-TCDD
Alternate Standards (Type A>
13C,2-l,2,3,7.8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C12-1,Z3,4-TCDD
l3Cu.lA3,7.85-HxCDD
AmMMfc*-' -»*^J!
SSfSSf***. f. P*^f ffff V>
2.9
3.0
3.1
2.7
3.4
3.6
3.2
3_5
6.5

Amt |f>s} 9

3.7
3.3
3J
3.8

Amt §19) ^
3J
Amt. $19} .• ^
3.3
3J
> '


fcRecova
% v A \ ^ \ v
73.1
75.1
76.4
68.3
85.4
89.4
79.9
86.7
81.3

»Becove»

92.0
82.6
86.8
93.8

» Recover
82.8
^Recover
81.4
82.8



__ \
jwv "• A >
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%

y
c
40%-130%
40%-130%
40%- 130%
40%-130%

y


40%-130%
40%-130%



— f^io
^.'^ , • : '
0.75
.0.80
1.47
1.49
0.50
1.23
0.44
1.04
0.85

Ratio

1.51
0.52
1.22
0.42



Ratio
0.50
0.51
Ratio
0.83
1.26
Off ^'
"<*<, rVI -,;x£t.>

24:37
25:20
28:34
29:36
32:08
32:48
35:00
36:03
39:36

RT

29:15
32:02
32:43
36:32

RT 1
25:21
, RT :-'"
33:23
32:37
RT
25:09
33:07
Flags
t f- f






	
	


Flags

	




Ftags
—
Flags

—
Flags


                    Data Reviewer
           01/10/98
                                                                        Mm_PS* • I a I. LARS 4.10.031
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 10:51 01/10/98
                              330

-------
                         Initial
                                   ... Date...
  Data Review By:
                                              Calculated Noise Area:
                                                                     6.44
  The Total Area for each peak with an ion  abundance ratio outside
  ratio limits has been  recalculated according to method requirements.
Page No. 1 Listing
01/10/98 Matched
Compound/
M_2.... QC.Log Omit Why ..RT. OK
TCDF 0
304-306
NK
K
K
K
K
K
K








304-306
13C12-TCDF
316-318








316-318
TCDD
320-322
NK
NK
D
K
D


D
D
DC NL 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
26
:00
:28 RO
:58
:13
:37
:57
:21
:36
:50
:02
of 09800358. dbf
GC Peaks / Ratio / Ret.
Ratio Total. Area. . . Area
.65-0.89
0
0
0
0
0
0
0
.83
.61
.85
.85
.75
.81
.74
0.75
0
.75
0.74
:13 0.76
:28
:40
:05
:17
:23 RO
0.70
0.76 1
0.77
0,
0.
15 Peaks

DC NL 0
DC WL 23:
24:
24:
25:
25:
25:
DC WH 25:
DC WH 25:
0.
:00 RO
:35
:14
37
03 RO
20 RO
33 RO
41
55 RO
,70
.90
7
42.23
162.22
197.45
222.91
859.68
574 . 89
682.02
504.63
651.63 .
797.03
338.58
277.03
,416.06
350.18
312.13
69.77
,416.21
TUne
. Peak .

70
90
102
367
256
290
216
278
339
146
113
610
152
128
35

1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.
0.867-1.079

.57
.49
.59
.39
.77
.28
.22
.55
.00
.19
.73
.62
.10
.53
.42


116
106
120
492
318
391
288
373.
458.
192,
163.
805.
198.
183.
39.

65-0.89
1.
0.
0.
0.
1.
0.
2.
0.
2.
5 Peaks

DC NL 0:
22:
23:
D SN 23:
24:
D SN 24 :
24:
25:
D SN 25 :
D SN 25 :
0.
00
48
12
29
10
37 RO
49
15
21 RO
31 RO
65-
0.
0.
0.
0.
0.
1.
0.
0.
0.
1.
08
82
75
75 15
00
41
00
76
99
16
0.89
79
78
77
80
85
96
81
70
46
05
13.10
192.25
96.67
,930.94
287.45
101.21
32.13
51.33
18.39
,448.40
TCDF / TCDD
8.10
327.67
215.09
44.08
114 . 27
12.44
44.33
135.20
22.23
14.44


41,
6,807,
161.
44.
36.




,33
,62
,66
.03
35




55.
9,123.
162.
107.
18.



.53
.96
.32
.29
.12
.74
.41
.08
.03
,39
.30
.44
08
60
42

0.000
0.872
0.892
0.903
0.919
0.932
0.949
0.959
0.968
0.976
0.984
0.994
1.002 2378 -TCDF AN
1.019
1.027
1.072 .

. Flags

J
J
J











J

0.959-1.041


34
32
40
09
15


0.000
0.958
0.984
1.000 13C12-2378-TCDF ISO
1.018
1.029
1.038
1.043
1.053












143.
93.

52.

19.
55.



23
88

44

81
56



184.
121.

61.

24.
79.


0.895-1.047

44
21

83

52
64


0.000
0.900
0.916
0.927
0.954
0.972
0.980
0.997
1.001 2378 -TCDD AH
1.007


J

J

J
J


Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 Q1

-------
  Page No.
  01/10/98
Listing of O980035B.dbf
Hatched GC Peaks / Ratio  / Ret. Tine
  Compound/
  M_2....  QC.Log Omit Why ..RT. OK Ratio Total. Area. ... Area.Peak.1. .  Area. Peak. 2. .  Rel.RT Compound, Name. .  ID..  Flags.
D D SN 25:41
D D SN 25:53 RO
D D SN 26:11 RO
0 D SN 26:19 RO
320-322 5 Peaks
37C1-TCDD
328 DC NL 0:00
DC WL 23:05
DC WL 23:13
23:58
25:21
25:45
25:57
26:00
26:02
26:05
26:13
26 : 28
26:34
26:40
328 11 Peaks
13C12-TCDD 0
332-334 DC NL 0:00 RO
24
25
25
25:
:11
:09
: 20
:40 RO
0.66 19.92
0.43 6.87
1.20 2.99
0.59 11.65
836.56
4.38
30.68
13.26
371.58 371.58
10,346.40 10,346.40
232.04 232.04
14.36 14.36
25.95 25.95
25.66 25.66
39.74 39.74
53.49 53.49
6.94 6.94
22.76 22.76
10.68 10.68
11,149.60
.65-0.89
2.48 12.50
0
.84
0.83 14
0.80 12
1.19
332-334 4 Peaks
PeCDF
340-342 DC NL 0:
26:
D D SN 26:
D D SN 27:
27:
27:
27:
28:
28:
M 28:
AN 28:
28:
28:
D D SN 29:
29:
29:
29:
29:
1.
00 RO
35
53 RO
13 RO
34
43
53
12
17
29
35
44
52
01 RO
16
25
44 RO
59 RO
27
32-1.78
0.
1.
0.
3.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
74
56
28
27
48
53 1
50
42
54
66
73
40
46
95
65
49
90
23
79.48
,863.24
,486.81
428.43
,857.96

. 3.36
539.70
3.65
15.05
180.42
,196.09
291.05
490.70
589.59
229.10
228.80
214.30
328.52
17.37
388.97
526.09
70.51
25.24
36
.36
6,726.10
5,539.70
287.59
43
8,137
6,947
242
0.
0.
.12
.14
.11
.05
1.014
1.022
1.034
1.039
.921-1.079
0.000
0.911
0.916
0.946
1.001 37C1-TCDD CLS
1.016
1.024
1.026
1.028
1.030
1.035
1.045
1.049
1.053
921-1.079
0.000
0
.955

0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013



328.


107.
724.
174.
288.
357.
143.
145.
124.
195.

242.
315.
52.
15.

93


54
00
51
30
34
00
00
95
00

46
23
61
34

210


72
472
116
202
232
86
83
89
133

146
210.
27.
12.
0.

.77


.88
.09
.54
.40
.25
.10
.80
.35
.52

.51
.86
.65
.48
925-1.065
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
r.
000
931
941
953
965
970
976
987
990
997
001 12378 -PeCDF AN
006
Oil
016
025 23478-PeCDF AN
030
041
050




J

J


J
J
J
J



J
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 10:51
1/38

-------
  Page No.
  01/10/98
Listing  of a980035B.dbf
Matched  GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area. Peak.1..  Area.Peak. 2. . Rel.RT Compound.Name. .  ID.. Flags.

340-342
13C12-PeCDF
352-354







352-354
PeCDD
356-358

D







M

D


356-358
13C12- PeCDD
368-370









368-370
HxCDF
374-376

30:14
15 Peaks

DC NL 0:00
27:42
28:10
28:34
28:51
29:15
29:46
29:56
7 Peaks

DC NL 0:00
27:49
D SN 28:17
28:33
28:41
28:51
29:01
29:05
29:18
29:27-
29:36
29:44
D SN 30:05
DC SN 30:15
DC SN 30:31
10 Peaks

DC NL 0:00
28:31
28:39
DC SN 29:01
29:36
29:44
30:08
30:20
30:28
30:30
8 Peaks

DC NL 0:00
31:04
RO

1
RO

RO

RO

RO
RO

1
RO
RO
RO



RO

RO
RO


RO

RO

1.
RO
RO
RO
RO

RO
RO
RO
RO
RO

1.


1.88

.32-1.78
1.28
1.58
1.27
1.47
2.34
1.51
1.11
0.46

.32-1.78
1.31
0.94
0.94
1.57
1.55
1.49
2.53
1.36
1.79
1.03
1.58
1.48
1.87
1.66
0.97

32-1.78
1.08
1.05
0.73
0.40
1.49
1.97
0.96
3.69
0.32
1.27

05-1.43
1.16
1.22
34.55
5,333.63

0.38
249.75
8.87
12,959.42
364.57
11,517.03
75.81
8.57
25,184.02
• PC CDF /
0.28
275.70
21.50
198.31
47.29
120.28
19.41
45.76
54 .80
25.85
35.80
23.04
18.74
2.93
1.63
846.24
25



153
5
7,720
.50



.10
.39
.06
334.43
6,920
46
5
.75
.08
.21
13



96
4
5,239
142
4,596
41
11
.55

0.

.65
.25
.36
.97
.28
.70
.38
1

860
0
0
0
1
1
1
1
1
.058

-1.140
.000
.970
.986
.000 13C12-PeCDF 123
.010
.024 13C12-PeCDF 234
.042
.048
J





IS2

SCR1





167

121
28
72
19
26
38
15
21
13





.58

.08
.71
.07
.23
.40
.51
.71
.90
.74





179

77
18
48
7
19
21.
15.
13.
9.




0.935-1.022

.01

.23
.58
.21
.61
.36
.49
.27
.90
.30




0
.000

0.940
0
0
0
.956
.965
.969
0.975
0
0.
0.
0.
1.
1.
1.
1.
1.

0.865-
0.21
10.10
7.70
2.02
5,985.74
946.18
28.43
13.87
5.03
13.90
7,010.95
PeCDD /
23.81
313.97


6.14
4.68


3,586.44
731.60
17.
28
20.07
3.
8.
06
45

5.
6.

2,399.
371.
17.
5.
9.
6.

87
42

30
05
91
44
46
63
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
.980
983
990
995
000 12378-PeCDD
005
016
022
031

1.135
000
963
968
980
000 13C12- PeCDD 123
005
018
025
029
030

J
J
J
J
J
J
J
AN J
J









IS3








172.

68

141.
0.962-

29
0.
0.
1.047
000
967



Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 10:51 01/10/98
                                                                             353

-------
  .Page No.
  01/10/98
Listing of 0980035B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z....  QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.







A

0

374-376
13C12-HXCDF
384-386






384-386
HxCDD
390-392

0


0
D
D

M
390-392
13C12- HxCDD
402-404




402-404
HpCDF
408-410


31:13
31:22
31:31
31:40
32:02
32:08
32:16
32:24
32:37
D SN 33:23
33:28
11 Peaks

DC NL 0:00
31:05
31:12
32:02
32:08
32:37
33:23
6 Peaks

DC NL 0:00
31:34
D SN 31:51
32:01
32:13
D SN 32:23
D SN 32:37
D SN 32:45
32:50
33:07
5 Peaks

DC NL 0:00
32:13
32:43
32:48
33:07
4 Peaks

DC NL 0:00
35:01
35:17
1.27
RO 0.84
' 1.21
RO 1.00
1.23
1.22
RO 0.92
1.38
1.27
RO 1.69
1.18

0.43-0.59
RO 0.68
0.52
0.51
0.52
0.50
0.51
0.50

1.05-1.43
RO 1.02
1.18
RO 1.52
1.28
1.30
1.09
RO 2.21
RO 1.62
1.12
1.20

1.05-1.43
1.28
1.37
1.22
1.23
1.26

0.88-1.20
1.16
1.10
1.06
741.24
64.40
101.98
50.89
589.83
272.50
62.05
103.50
293.93
16.26
59.80
2,654.09

6.93
37.54
66.54
6,804.29
9,982.93
8,723.69
6,607.26
32,222.25
t : HxCDF /
6.97
61.00
3.32
276.41
136.48
29.36
7.73
16.40
45.83
52.70
572.42

7.50
25.59
4,904.99
7,721.36
8,680.94
21,332.88
: HxCDD /
9.81
867.57
186.41
414.36
35.65
55.76
28.17
324.84
149.77
34.35
60.00
164.31

32.36



12.90
22.47
2,322.38
3,328.07
2,941.31
2,188.08



33.03

155 . 17
77 . 15



24.20
28.70



14.80
2,692.26
4,252.55
4,832.80



453.76
95.91
326.88 0.971
42.24 0.976
46.22 0.981
28.26 0.985
264.99 0.997 123478-HxCDF AN
122.73 1.000 123678-HxCDF AN
37.44 1.004
43.50 1.008
129.62 1.015 234678-HxCDF AN
1.039 123789-HxCDF AN
27.44 1.041

0.876-1.124
0.000
24.64 0.967
44.07 0.971
4,481.91 0.997 13C12-HxCDF 478 SDR2
6,654.86 1.000 13C12-HXCDF 678 IS4
5,782.38 1.015 13C12-HxCDF 234 ALT2
4,419.18 1.039 13C12-HXCDF 789 ALT1

0.958-1.014
0.000
27.97 0.962
0.971
121.24 0.976
59.33 0.982
0.987
0.994
0.998 123478-HxCDD AN
21.63 1.001 123678-HxCDD AN
24.00 1.010 123789-HxCDD AN

0.970-1.030
0.000
10.79 0.982
2,212.73 0.997 13C12-HXCDD 478 SOT3
3,468.81 1.000 13C12-HXCDD 678 IS5
3,848.14 1.010 13C12-HXCDD 789 RS2

0.996-1.049
0.000
413.81 1.000 1234678-HpCDF AN
90.50 1.008

J
J
J

J
J
J


J












J


J



J
J












Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 10:51 01/10/98
                                                                             354

-------
  Page No.
  01/10/98
Listing of 0980035B.dbf
Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_2....  QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak. 1. . Area.Peak. 2. .  Rel.RT Compound.Name.. ID..
                                                                             Flags.

0
D
M
D
408-410
13C12-HpCDF
418-420




418-420
HpCDD
424-426
D
M
D
M
D
424-426
13C12-HpCDD
436-438


436-438
OCDF
442-444














M


0
D

0


DC






DC
DC

SN
SN

SN
4

NL




4

NL
ML
35
36
36
36
36
:26
:17
:23
:33
:53

RO
RO
RO

0
0
2
1
1
.97
.53
.06
.24
.00
Peaks

0
35
35
36
36

:00
:00
:30
:32
:55
0
RO

RO


211.28 104.16
3
2
78
8
1,344
.94
.92
.95 48.10
.25
.21
.37-0.51
0
0
1
0
0
Peaks

0

:00
35:09
35:18
D

DC


DC




DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC



SN

NH
2

NL


2

NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN



35
36:
36;
:26
;03
:33
0.
RO
RO
RO

RO
RO
.52
.44
.52
.42
.37

88-1.20
1
0
1
1
0
3
.36
.66
.22
.14
.86
.03
Peaks

0:
35:
36:

00
16
03
0.
RO
14
5,704
11
4,289
63
.54
.28 1,736.88
.84 12.49
.75 1,279.16
.97 17.19
107.12 1.012
1.037
1.040
38.70 1.044 1234789-HpCDF
1.054

0.943-1.114
0.000
3,967.40 1.000 13C12-HpCDF 678
8.22 1.014
3,010.59 1.044 13C12-HpCDF 789
46.78 1.055



AN




IS6

SUR4

10,069.84
: HpCDF / HpCDD Follows --
2
8
125
16
.86
.30
.87 75.40
.01
119.26 60.80
7.20
0.975-1.005
0.000
0.975
61.70 0.979
0.983
70.30 1.000 1234678-HpCDD
1.014





AN

245.13
88-1.20
0.83
1.02
1.04
Peaks

0:
34:
35:
36:
36:
37:
37:
37:
37:
37:
38:
38:
38:
38:
39:
39:
40:

00
43
33
22
37
10
26
31
39
53
11
19
36
41
18
49
18
0.
RO

RO
RO
RO

RO
RO
RO
RO
RO
RO
RO

RO

RO

76-1.02
0.
0.
1.
0.
1.
1.
1.
0.
1.
0.
0.
1.
1.
0.
1.
0.
1.
04
83
31
55
17
01
34
51
07
58
47
60
20
88
06
83
43
7.79
27.75 14.01
5,466.
45 2,786.97
5,494.20
: HpCDD / Octa-CDD and CDF
0.
0.
0.
1.
1.
2.
1.
1.
1.
1.
2.
1.
1..
1.
3.
412.
2.
13
53
96
83
98
23
29
95
87
70
27
42
87
45
61 2.02
00 187.00
59 1.96
0.972-1.028
0.000
13.74 0.978
2,679.48 1.000 13C12-HpCDD 678

Follows 	 	
0.899-1.101
0.000
0.877
0.898
0.918
0.925
0.939
0.945
0.947
0.951
0.957
0.964
0.968
0.975
0.977
1.91 0.992
225.00 1.005 OCDF
1.37 1.018



IS7

















AN

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 10:51 01/10/98
                                                                            355

-------
  Page No.
  01/10/98
Listing of U980035B.dbf
Matched GC Peaks / Ratio / Ret. Tine
  Compound/
  M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area...  Area.Peak.1..

                                                 2.51
                                                 O.S1
  442-444               3  Peaks                 418.20
  OCDD
  458-460
  458-460

  13C12-OCDD
  470-472

  470-472
DC
DC
SN 40
SN 40
:22
:52
RO
RO
0
2
.46
.44


3 Peaks

DC
DC


DC

NL 0
SN 39
39
39.
SN 40:

:00
:25
:37
;56
:04
0.
RO
RO

RO
RO
.76
1
0
0
0
0
-1.
.67
.38
.91
.41
.26
02





2 Peaks

DC


NL 0:
39:

00
36
0.


76
1
0
-1.02
.00
.85


1 Peak
                       0.06
                       0.59
                     167.97
                       3.76
                       0.81
                     171.73
                      0.08
                   7,695.65
                   7,695.65
                                         Area.Peak.2.. Rel.RT Compound.Nome..  ID..  Flags.

                                                       1.019
                                                       1.032
                                                             80.05
                                                              1.77
                87.92
                 4.33
      0.899-1.101
          0.000
          0.995
          1.000 OCDD
          1.008
          1.012
AN
3,526.36
      0.996-1.004
         .0.000
4,169.29  1.000  13C12-OCDD
                                            IS8
  Column Description	   "Why"  Code Description	   QC Log Desc.
  M_Z    -Nominal Ion Mass(es)
  ..RT.  -Retention Tine (mn:ss)
  Rat.l  -Ratio of M/M+2'Ions
  OK     -RO"Ratio Outside Limits
  Rel.RT-Relative Retention Time
  ••• End of Report ••«
       WL-Below Retention Time Window
       WH-Above Retention Tine Window
       SN-Below Signal to Noise Level
       
-------
Fila:O980035 tl-724 Acq: 7-JXH-1998 00:29:17 SC EI+ Voltage SIS 70S Noiae:9553
303.9016 F:2 BSO3(256,30, -3.0) PKD(9,5,3,0.10\,38212.0,1.00\,f,T) Xxp:HDB5OS
TSIASGLX LASS Text: 201-204 TLIt44376A
1003
80.
60.

40.
20.
A6


A3. 39X6
A3. 67X6 A2.16X6 A
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25:00 	 25:00 Time
rile:P980035 tl-724 Acq: 7-JXX-1998 00:29:17 GC XI* Voltage SIS 70S BOiae:11558
305.8987 F:2 BSUS(256,30,-3.0) PXD(9,5, 3, 0 .10\,46232.0,1.00\,T,T) KxptNDBSOS
TSIABGLE LABS Text: 201-204 TLIt44376A
100J
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.3.1X5

25:00 25>00 Time
rile: 0980035 tl-724 Acq: 7-J3OT-1998 00:29:17 GC EI+ Voltage SIS 70S SOiae:3990
315.9419 F:2 BSUB(2S6, 30, -3.0) PKD(9, 5, 3,0. 101,15960. 0,1.00\,F,T) ErpsSDSSm
TRIANGLE LASS Text: 20 1-204 XLIt44376A
1001
80:
60:
40:
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1
'22:00 	 2.3:00 ' ' 24:00

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F±Jioi0980035 tl-724 Acq: 7-JZS-1998 00:29:17 GC XI+ Voltage SIS 70S Hoiae,3699
317.9389 F:2 BSUB(256,30,-3.0) PKD(9,5, 3, 0.10\,14796.0,1.00\,
TSIASGLE LASS Text: 201-204 TLIt44376A
1003
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so:
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'22:00 	 23:00 	 2
-------
rile,O980035 tl-724 Acqs 7-JAW-1998 00,29,17 GC XI+ Voltage SIX 70S Xoiaesl788
319.8965 T:2 BSUB(356, 30, -3.0) PXD(7,5,3,0.10\,7152.0,1.00\rf,T) XxptSDBSUS
XBIAHSLX LABS Text, 201-204 TLH44376A
10
23\00 24 1 00 25,00
r \ *"'.f«*«
-3.4X5
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-.2.0X5
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26,00 HM
rile:0980035 tl-724 Acqs 7-JJOT-1998 00,29:17 GC SI+ Voltage SIX 70S Soimes2261
321.8936 f,2 aSUB(256,30,-3.0) PXD(7,S,3, 0.10%, 9044. 0,1. 00\,T,T) XxptSDBSUS
TSIANGLX LABS Text 1 301-304 TLIt44376A
1001
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20.
0
1
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A1.21X6 .
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26:00 T±ae
rile:O980035 tl-724 Acqi 7-JJOT-1998 00,29:17 GC XH- Voltage SIX 70S Soiaes8772
331.9368 Ts2 BSUB(256, 30, -3.0) PXD(7,5, 3, 0.10%, 35038.0, 1.00\,T,T) XxptSDBSUS
TSIAHSZX LABS Text:201-204 TLIt44376A
1003
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A6.J




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23:00 	 24:00 	 25«00 '

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26:00 	 T±ae
tile, 0980035 tl-724 Acqs 7-3XX-1998 00,29,17 GC XI+ Voltage SIS 70S Soiae,3528
333.9338 Ts2 BSOB(256, 30, -3.0) PXD<7,S,3,0.10\,14112.0,l.OO\,T,T) XxpsBDBSUS
TXIANSLX LABS Text: 201-204 TLH44376A
1001
80:
60:
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201

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327.8847 f,2 SSUB(256,30,-3.0) PXD(7,5,3,0.10\rB768.0,1.00\,r,T) XxptXDBSaS
TRIANGLE LABS Texts 201-204 TLXI44376A
1001
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330.9792 r,2 XxptNOBSUS
TXIASSLX LABS Text: 201-204 XLIt44376A
1001
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60:
40:
20:
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22,57 23,29 24,02 	 ^l^,^^*!^^^^!^^5^^^^*^!--^ 	 ^f4'517
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-------
rU.e:O980035 tl-724 Acq: 7-J2UT-1998 00:29:17 SC XH-
339.8597 f:2 BSUB(25S, 30, -3.0) PXD(7,5,3,0.10\,4080
Voltage SIS 70S Noise: 1030
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TSIANSLX LABS Text:201-204 XLIt44376A
1001
80.
SO.

40.

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38:00
TUet0980035 tl-724 Acq: 7-J3UT-1998 00:29*17 SC XH-
341.8567 T:2 BSUB(256,30,-3.0) PXD(7, 5, 3, 0.10%, 5515





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TSIASSLX LABS Text: 201-204 TLH44376A
1003
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401

201

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351.9000 T:2 3SUB(2SS,30,-3.0) PXD(7,5,3,0.10\,460.0,1.00*,f,T) Xxp-.mBSUS
TRIASSLX LABS Text:201-204 TLXt44376A
1001

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353.8970 T:2 BSUB(256,30,-3.0) PXD(7,S,3,0.10\,360.0,1.00\,T,T) Xxp:KDB5US
TSIASSLX LABS Text:201-204 TLIt44376A
1001

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330.9792 F:2 Sxp:lO3B5US


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1001
80.
$0:
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26:53 27:11 27:36
27:51 28:19
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ttlei0980035 tl-724 Acq: 7-J3UT-1998 00:29:17 SC XI+
409.7974 F:2 XxptNDBSUS

29:00
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'-2.8X7
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1001
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40:
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27:56

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| 28: 39

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-------
 f2j.a:U9 80035  iI-724Jicq:  7-JAX-199O QOtJSil/ GC SH- VoJLtage SIX 70S tiaia»:S4
 355.8546  f,2  BSVB(256,30, -3.0) PXD(5,5,3,0.05\,336.0,1.00\rT,X) Exp:SDB5US
 XXIASSLX  LABS  Text:201-204  TZJ#44376A
 1001
  80.

  60.

  40.

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                            A1.21Z6
                                                                            Al.
                                                                                                -4.1X5

                                                                                                .3.3X5

                                                                                                 .2.4X5

                                                                                                 1.6X5

                                                                                                 8.2X4
      27:48 28,00  28,12 28,24 28*36 28,48  29,00 29,12 29,24 29,36  29,48 30,00 30,12
r±le>U980035 #1-724 Acq:  7-JAN-1998 00,29,17 GC XH- Voltage SIS 70S SOiae,66
357.8516 r,2 BSO3(256,30,-3.0) PXD(5,5,3, 0.05\,264.0,1.00\,F,T) XxptSDBSUS
TRIANGLE LASS  Text,201-204   TLI#44376A
                                                                                                 0.0X0
                                                                                                    T±me
 1001

  80.

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      27,48 28,00 28,12  28,24 28*36 28,48 29,00  29,12 29,24 29,36 29,48  30:00 30,12 30,24
rila,U9a0035 #1-724 Acq:  7-JAS-1998  00,29*17 GC EH-  Voltage  SIX 70S Hoiae,6S
367.8949 Ts2 BSUB(256, 30, -3.0) PXO(5,5,3,0.05\r260.0,1.00\,T,T)  XzpsHDBSOS
TSIANGLE LABS  Text:201-204   TLI#44376A
1001                                                         A3.59X7

 80.

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                                                                                                    T±me



                                                                                                 1.1X7

                                                                                                .8.5E6

                                                                                                '.6.3X6

                                                                                                .4.2X6

                                                                                                 2.1X6
      27,48 28,00 28,12  28,24  28,36 28,48 29,00  29,12  29,24 29,36 29,48  30,00 30,12 30,24
r±J.a,U980035 #1-724 Aeq, 7-JMT-1998 00,29,17 GC Eli- Voltage  SIX  70S Hoiae,61
369.8919 r,2 BSVB(256r30r-3.0) PXD(S,S,3,O.OS\,244.0,1.00\,r,X)  XxptBDBSVS
TSIANGLE LABS  Text:201-204  TLH44376A
1001                                                         A2.40E7
                                                                                                .0.0X0
                                                                                                    Tiae
      27,48 28,00 28,12  28,24  28,36 28,48 29,00 29,12  29:24 29,36 29,48  30,00 30,12 30,24
r±lo,O980035 #1-724 Acqi 7-JMT-1998 00,29,17 GC XI + Voltage  SIX  70S
330.9792 T,2 XzpiHDBSOS
rXIABGLX LABS  Text,201-204  TLH44376A
 • 00^   „_  ,.          in, 10       2t,i42      ta.ni   10. f7        29,42  23 55
 80.

 60.

 40.

 20.
       37.51
                                                                                30 ill
     27\48  2a',00 2a'il2 28,24  28', 36 28,48 29\00 29,12  29,24  29', 36 29', 48' 3o'i 00  3o':12 30':24
                                                                                                0.0X0
                                                                                                   Time
                                                        .4.7X7

                                                        .3.8X7

                                                        .2.8X7

                                                        .1.9X7

                                                        ,9.4X6

                                                        .0.0X0
                                                            Time
                                                                                                      360

-------
\TiIe:a980035 tl-384 Acq: 7-JAK-1998  00,29:17 CC XX+ Voltage SIS  70S Soia*t63~S7~
373.8208 T-.3 BSCB(256,30,-3.0) PXD(7,5,3,0.101,25548.0,1.00\,r,T) XxpiSDBSOS
TRIANGLX LABS  Text:201-204  TLH44376A
 1001
  80:
  60:
  40:
  20:
           A4.14X6
                                     A3.25X6
      A1.73X6\
                    AS. 58X5
                                                       Al . 64X6
                                                                                    . 24X5
     31:00 31': 12 3l':24 31:36 31:48  32',00 32,12 32,24 32:36 32',48  33',00 33': 12 33~,24  33:36 33',48
 TiletU980035 tl-384 Acq: 7-JAN-1998  00,29,17 CC XH- Voltage SIX 70S lToiae:5521
 375.8178 r,3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,22084.0,1.00\,T,T) XxpiNDBSUS
 TXIANGLX LASS  Text:201-204  TLIt44376A
 1003(      A3.27X6
 80:
 60:
 40:
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  oj
      Al . 41X6t
                                     A2.65X6
                    A4 . 62E5
                                                       A1.30E6
                                                A4.35XS
                                                         l\
                                                        y  V
                                                                                 A2.74X5
     31:00 31:12 31:24  31:36 31:48  32:00  32:12 32:24 32,36 32^48 33166' jji 12' jjii* ' jj- 36' 33^48
Tlle,U980035  tl-384 Acq: 7-JAN-1998 00:29,17 GC ZZ> Voltage 5X5 705 Noiae:1560
383.8639  Ti3  BSVB(256,30, -3.0) PXD(7,5,3,0.10\,6240.0,1.00\,r,T) XxpiXDBSUS
TSIAKSLX  LASS  Text:201-204  TLH44376A
1001
  80:
  60:
  40:
  20:
   ol
    31:00  31:12 31:24  31:36 31:48 32,00  32:12  32:24  32:36 32,48 33,00  33:12 33:24 33:36  33:48
riletU980035 41-384 Acq:  7-JAN-1998 00:29,17 GC XH- Voltage SIS 70S Koine:2296
385.8610 r,3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,9184.0,1.00\,r,T) Ex.
TSIAXSLX LABS   Tejct:201-204  TLH44376A
1001
  80:
  60:
  40:
  20:
  o:
                                       A6. 5X7
                                                                              A4.42E7
    31:00  31:12 31:24  31,36 31:48 32:00  32:12  32:24  32^36 32:48 33:00  33:12 33,24  33:
\rilata980035  tl-384  Acq:  7-JXK-1998 00,29,17 GC EH- Voltage SIS 70S
392.9760 r,3  EzptXDBSUS
TSIASGLX LABS  Text:201-204  TLIt44376A
                 31:23             31;S8    33,15             32^49 33,01            33:31
1001
 so:
 60:
 40:
 20:
  oj
                                                                                         36  33: 48
                                                                                           33:44
                                                                                           -  -  - *
    Jlioo  3i',12 3i\24 3l',36  3l',48 32\00 32,12 32,24  32,36  32', 48' jji 00'  33', 12' 33,24 33,36  33,48
Tilm,U980035 tl-384 Acq,  7-JATT-1998 00,29,17 GC EH- Voltage  STB 705
445.7555 Ft3 XXptSDBSUS
TRIANGLE LABS  Text:201-204   TLH44376A
1001
 eo:
 60:
 40:
 20:
  ol
                                                       32
                          31,41
             31,16

                                                          36
                                                                                33:23
                                                             32,49    33,05
    31:00 31:12  3l',24 31,36  31:48 32,66 32,12 32\24 32:36' 32\48
                                                                                         35

                                                                                33,24 33,36 33,48
                                                                                                    -1.2X6
                                                                                                    .9.7X5
                                                                                                    .7.3X5
                                                                                                      4.9X5
                                                                                                      2.4X5
                                                                                                      0.0X0
                                                                                                         TiMe\
 .9.7X5
 7.8X5
 5.8X5
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    Timel
                                                                                                      0.0X0
                                                                                                         Tiael
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                                                                                                     .0.0X0
                                                                                                         T±ae\

                                                                                                    -2.6X4
                                                                                                    '.2.1X4
                                                                                                    .1.5X4
                                                                                                    .1. 0X4
                                                                                                    -.5.1X3
                                                                                                     .0.0X0
                                                                                                        Time\
                                                                                                       361

-------
 file,Q980035 tl-384 Acq, 7-JMi-lHSto ttu:J9:17 SC SH- Voltage SIS 70S Nolle, 19JO
 389.8156 Tt3 BSOB(356,30,-3.0) PXa(7,5,3,0.10\f7730.0,1.00\,T,T) SxptXDBSUS
 TXIAHSZX LABS  Tert,201-204  TLH44376A
 10 0\                     A1.S5X6
  80.

  60.

  40.

  20.
 A3.30X5
 A
                                                            A3. 42X5
                                                                        A3. 08X5
          31>36   31i48    33tOO    32:12   32,24   32:36   32:48    33:00   33:12
TileiU980035  tl-384 Acq:  7-JUT-1998 00,29,17 SC EH-  Voltage  SIS  70S No±ae:18S4
391.8137 ft3  BSUB(256,30,-3.0) PXD(7,5,3,0.10\,7536.0,1.00\,r,T)
TSIASSLX LABS  Tarts301-204  XLH44376A
100\                     A1.21X6
  80.

  60.

  40.

  20.
                                                                              33124
A3.80X5
                           AS.93X5
                                                          A3.16X5
                                                                       A 3.01X5
          31': 36    31:48   32:00    32:12   32:24   32:36   32:48    33': 00    33:12
rilaiO98003S  tl-384 Acq:  7-JXS-1998 00:23:17 SC XH- Voltage SIX 70S Noiae:3103
401.8558  r,3  BSUB(256,30,-3.0) PXD(7,S,3,0.10\,8412.0,1.00\,T,T) XxptSDBSVS
          LABS Tojct:201-204   TLH44376A
100\                                                                   A4.83X7
                                                          A4.25X7
  80.

  60.

  40.

  20.
                                                                              33:24
                                                A2.69X
         31:36    31,48   32:00    32,12    32:24    32:36   32:48   33:00    33:12
rile,U98003S tl-384 Acq:  7-JKR-199S  00,29:17 SC XI+ Voltage SIX 70S Noise: 1644
403.8529 T:3 BSUB(256,30,-3.0) PXO(7,5,3,0.10\,6576.0,1.00\,r,T) EzpiNDBSUS
TRIANGLE LABS  Text:201-204  TLIt44376A
100$                                                                   A3.85E7
                                                          A3.47X7
 80.

 so:

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                                                                              33,24
-4.7X5

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-4.0X5

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                                                                                      33 36
                                                                                          0.0X0
                                                                                             T±a<
                                                                                      33:36
         31:36    31:48   32:00   32:12    32:24    32:36    32:48   33', 00
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 92.9760 Ti3 XxptSDBSUS
TJtlAOSZZ LABS  Textt 201-204  XLIt44376A
10°*              31:48  31:58   '    33,15                   33,49   33t0i     33.13
 80.

 60.

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                                                                     33:12   33:24    33:36
                                                                                        -3.1X7

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                                                                                        .4.1X6
         31:36
                 31:48
                          33:00
                                  32:12   32,24   32:36
                                                           32,48
                                                                   33100
                                                                            33112
                                                                                    33134    33
                                                                                                0.0X0
                                                                                                36 Tia>
                                                                                                      362

-------
 rU.»:O980035 #l-545 Acq: 7-JMT-1998  00:29:17  SC XI* Voltage SIX 70S Hoi fat 3634
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 TSIAHOLX LASS  Text:201-204  TLH44376A
 100\    A4.54X6

  80:

  SO.
  40:

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                                                                           AS.41X5
         35100    35:12    35t34    35:36    35:48   36:00    36,12    36:24    36:36   36:48
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409.7789 T:4 BSVB(256r30, -3.0) PXD(7,5,3, 0.101,9084.0,1.00*,r,T) Sxp:SDS5US
TRIASSLX LASS   Text:201-204  TLH44376A
10 0\   A4.14E6
                                                                           A4.33S5
        35', 00    35:12    35,24    35:36    35:48   36:00    36:12   36:24    36:36    36:48
JNJ.e:0980035 H-545 Acq:  7-JAX-1998 00:29:17 SC XI* Voltage SIS 70S Noise:2620
417.8253 T:4 SSUS<256,30, -3.0) PKD(7,5,3, 0.10\,10480.0,1.00\,r,T) Exp:8DB5US
TSXAKGZX LASS  Text:201-204  TLH44376A
       Al. 74X7
                                                                          A1.28E7
        35:00    35:12.   35:24    35:36    35:48    36:00    36:12   36:24    36:36
r±laiU980035 H-545 Adj:  7-JJUT-199S 00t29:17 SC SH- Voltage SIS 70S SoiaeiSOSO
419.8220 T:4 3SOS(256,30, -3.0) PXD(7,5,3, 0.10\,20200.0,1.00\,T,T) Sxp:KDBSUS
TXIAHSLX LASS  Iexti201-204  TLH44376A
100S   A3.S7E7
                                                                           A3.01E7
                                                                                       36:48
        35:00    35:12    35:24    35:36   35:48    36:00   36:12    36:24
rlla:O980035 H-54S Acq:  7-JAN-1998 00:29:17 SC EH- Voltage SIS 70S
430.9729 T>4 Exp:KDS5US
TSIAHSLS LASS  Text:201-204   XLH44376A

10°*    35:00   35:10 35^19	       __"-S136:0036:12     36:26
 60^

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 20:

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                                                                              36:36
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rila:U980035 tl-545 Acq:  7-JXN-1998 00:29:17 SC XI+ Voltage SIS 70S
479.7165 F:4 Sxp:JO)B5trS
TSIASSLX LASS  Text:201-204   TLH44376A
                                                                              36:36    36:48
                                                                                                     -1.1X6

                                                                                                     '•.8.5X5

                                                                                                     .6.4X5

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                                                                                                37100    T±me
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                                                                                                     16.1X5

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                                                                                                37:00    Time
                                                                                                    ±.0.0X0
                                                                                                37:00    Tlae
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                                                                                                37:00    Tlae
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37:00    Tlae
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-------
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 TSIANGLX VMS  Tuff 1201-204  TLI944376A
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425.7737 T,4 BSUB(256,30, -3.0) PKD(7,5,3,0.10\,2796.0,1.00\,f,T) ExptSDBSUS
         LABS  T*xt: 201-204   TLH44376A
                                                                                                 0.0X0
                                                                                                    Tin
            A6.34X5
                                                           A7.S3X5
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                                                                                                    Tim
      35,12 35,18  35:24 35:30  35,36 35:42  35:48 35:54 36:00  36:06 36:12  36:18  36:24  36,30
Tilt»U98003S tl-545 Acq: 7-J7OT-1998  00,29,17 SC XH-  ValtAye SIX 70S Soiae-,1983
435.8169 Tt4 BSOB(256,30, -3.0)  fXD(7,5,3,0.10\,7932.0,1.00\,TrI) Xxp:KDBSUS
TSIASSLX LABS  Toit.1201-204  TLIt44376A
                                                           A2.J9X7                               5.9X6

                                                                                                .4.7X6

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      35,12 35:18  35:24  35:30 35,36  35:42 35,48 35,54 36,00  36,06 36:12  36:18 36:24  36:30
T±la:O980035 tl-545 Acq:  7-JAN-1998 00,29:17 SC XH-  Voltage SIS  70S  tfoiaa,2379
437.8140 T,4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10\,9516.0,J..OO\,r,T) Xxp:SDB5OS
XSIAHGLX LABS  Texts201-201   TLH44376A
100\                                                      A2.f8X7

 80.

 60.

 40:

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      35,12 35,18  35,24 35,30  35,36  35,42  35,48 35,54 36,00  36,06 36,12  36,18 36,24  36,30
Tll»,0980035 tl-545 Acq, 7-JAH-1998 00129117 SC XH-  Woltigm SIS 70S
 30.9729 Tt4 XxpiKDBSUS
 VIAHGLX LABS  Text,301-204  TLH44376A
                                                         36iOO
 80.

 60.

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                                                                            36,18  36:24  36,30
                                                                                                .0.0X0
                                                                                                   Time
                                                                                                     363

-------
FiJ.a:D9a0035  ti-545 Acq: 7-JAN-199B  00 1 29: 17 GC £I> Voltage SIR 70S Noiae:31
441.7438  T:4  BSUS(256f 30, -3.0) PXO(7,5,3,0.10\,124.0f1.00\,r,T) XxptODSSUS
XSIAKSLX  LABS  Tart -.201-204  TLH44376A
1001
  90.
  80;
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               35100         36:00         37:00        38,00         39*00
\r±l*:Uaa0035  tl-545 Acqt  7-J7UT-1998  00,29,17 SC XI* Voltage SIS 703 Soj.ae.77S
443.7399 Ti4  33UB(2S6,30,-3.0) PXD(7,S,3,0.10\,3104.0,1.00\,r,I) ErpiBDBSUS
TRIANGLX LASS Tart:201-204  TLH44376A
iota
  90\
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               35:00         36:00          37:00        38:00
rlleiU98003S tl-545 Acq:  7-J3UT-1998 00:29:17 SC XH- Voltage SIS 70S
430.3729 fi4 KxpiNDBSDS
TSIAHGZX LASS  Text.:201-204  TX.H44376A
1004                                   36:41
                    35:19  35:51   36:2&\  .  37:12 37:39        38:36
  801
  701
  601
  50J
  40.
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  201
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                                                                                                   41 00  Time
                                                                           39,16
     <°L33 40,48,
               35', 00         36:00          37:00        38iOO         39:00
Tll*tU9B0035 tl-545 Acq:  7-JAJT-1998 00129:17 SC EH- Volt&ga SIS 70S
513.6775 Tt4 XxptOSSSUS
TXIABGLS LASS  Talt.:201-204  TLII44376A
1004
40:00
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                                                                                                       364

-------
 T3-iatOSBOOJ5  tl-545 Acqi 7-J3UI-199B Out IS,17 SC fl+ Voittgrn SIX 70S 2fOif»:J7
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 TBIAHGLX LASS  Text,201-204  TLI944376A
 100*                     AS. 01X5
           39,30         39:36         39:43        39,48         39,54
rll*ia980035  91-545 Acqi  7-JAK-1998 00,29,17 SC JSI+ Voltagu SIS 703 SoimatlS
459.7348 Ti4  3303(356,30, -3.0) PKD(7,5,3,0.10\,60.0,1.00\,r,T)
         LASS  X»rti201-204  XLH44376A
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                                                        A3.38K4 A4.33X4
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469.7779 Ti4 BSUB(356,30, -3.0)  PXD(7,5,3, 0.10\,84.0,1.00\rT,T)  XxpiRDBSUS
TRIASGLE LASS  Text:201-204   TLH44376A
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 80.
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                                                                               40s 00
           39,30         39:36         39:42        39,48        39,54
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TBIANGLX LASS  Toxtt201-204   TLH44376A
100\                    A4.J7Z7
                                                                               40:00
           39', 30         39,36        39,42         39,48        39,54
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TSIANSLE LASS  Text 1301-204   TLIt44376A
                                                                               40,00
lOOi,

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39,33
         39,37
                                                                        39,57
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-------
                                                                                 CD
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      Experiment:NDB5US Function:2 Reference:PFK

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-------
 
-------
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-------
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Sample Text: 201-204 TLI#44376A File Text :TRIANGLE LABORATORIES, INC.
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-------
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File:U980035 #1-545 Acq : 7-JAN-1998 00:29:17 GC EI+ Voltage SIR 70S
441.7428 F:4 Exp:NDB5US
Sample Text: 201-204 TLIS44376A File Text : TRIANGLE LABORATORIES, INC.
100% A1.87E6 3.1E5
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39:36 r5.9E6
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-------
TLI Project
Client Sample:
   44376A
   201-204
       Method 23 TCDD/TCDF Analysis (DB-225)
       ^                   Analysis File:   P980103
 Client Project:
 Sample Matrix:
 TLI ID:
Gulp Aluminum Alloys
M23TRAIN        Date Received:  12/17/97
194-59-19A-D       Date Extracted:  12/29/97
                   Date Analyzed:  01/07/98
                               Spike File:    SPC2NF04
                               ICal:        PF22206
                               ConCal:      P980092
 Sample Size:
 Dry Weight
 GC Column:
1.000
n/a
DB-225
Dilution Factor n/a
Blank File:     P980094
Analyst:       WK
            % Moisture:  n/a
            % Lipid:     n/a
            % Solids:    n/a
                                                                            JR.'T
WJ.S-TCDF
              0.07
                                0.73
                      23:06
                 B
                        \u 'Ami. (ng)
                         % Recovery  QCtlmfts     BatJo
                                         RT
I3C,r^3,7,8-TCDF
              3.6
          89.7
40%-130%
0.76
23:04
 Recovery Stancferd
                                                  Batto
                                         RT
                              Flags
                                                                    0.81
                                                           21:53
                      Data Reviewer
                                              01/09/98
                                          Page 1 of
                                                            11NF PSR i Mil. P.AKNft IIMWI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                        Printed: 10:17 01/09/98
                                                                     374

-------
                         Initial
                                     ..Date..
  Data Review By:
                     Calculated Noise Area:
                                             1.00
  The Total Area  for each peak with an ion abundance ratio outside
  ratio limits  has been recalculated according to method requirements.
  Page No.
  01/07/98
Listing of P980103B.dbf
Matched GC Peaks / Ratio / Ret.
Tlae
  Compound/
  M_Z	QC.Log Omit Why . .RT. OK Ratio Total. Area. ..  Area. PeaJc. 1. . Area. Peak. 2. . Rel.RT Compound. Name. .  ID..  Flags.
TCDF
304-306 DC ML 0:00
18:26
DC SN 18:34
19:03
19:27
19:35
19:42
19: S3
20:00
20:09
20:18
20:27
20:36
20:46
21:09
DC SN 21:19
21:36
21:41
21:51
22:05
22:19
22:30
22:56
23:06
23:18
23:34
23:42
24:30
25:14
DC WH 25:32
304-306 26 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 21:34
DC WL 21:49
23:04
DC SN 23:26
23:41
DC WH 24:07
DC WH 25:08
316-318 2 Peaks
0.65-0.89
RO 0.45
0.69
RO 1.81
RO 1.57
RO 0.97
0.75
0.79
0.79
0.78
0.75
0.75
0.72
0.70
0.77
0.75
0.68
0.71
0.81
0.77
0.87
0.72
0.70
0.78
0.73
0.67
0.74
0.77
0.75
RO 0.93
RO 1.13

0.65-0.89
0.87
0.73
RO 0.90
0.76
0.69
RO 0.46
RO 1.11
RO 0.93

0.792-1.101
1.03
21.93
0.28
2.28
21.33
22.72
49.12
19.40
3.04
22.73
53.58
28.84
81.00
30.97
157.50
1.06
44.36
7.93
42.29
39.46
8.24
55.77
45.55
39.89
49.33
63.86
52.99
34.18
7.88
4.58
1,006.17

8.98

2.02
11.65
9.71
21.65
8.57
1.33
9.71
22.96
12.10
33.23
13.49
67.73.

18.41
3.56
18.42
18.33
3.45
23.06
19.90
16.86
19.83
27.23
22.97
14.66
4.15



12.95

1.29
12.05
13.01
27.47
10.83
1.71
13.02
30.62
16.74
47.77
17.48
89.77

25.95
4.37
23.87
21.13
4.79
32.71
25.65
23.03
29.50
36.63
30.02
19.52
4.45


0.000
0.799
0.805
0.826
0.843
0.849
0.854
0.862
0.867
0.874
0.880
0.887
0.893
0.900
0.917
0.924
0.936
0.940
0.947
0.957
0.967
0.975
0.994
1.001 2378-TCDF AH
1.010
1.022
1.027
1.062
1.094
1.107

0.957-1.043
2.41
13.41
26.00
2,350.41
1.59
5.84
4.23
24.76
2,356.25



1,012.46

2.54






1,337.95

5.58



0.000
0.935
0.946
1.000 13C12-2378-TCDF ISO
1.016
1.027
1.046
1.090

Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 08:49 Q.1/QZ88

-------
  Page No.
  01/07/98
Listing of P980103B.dbf
Matched OC Peaks / Ratio / Ret. Tine
  Compound/
  M_Z....  QC.Log Oait Why  ..RT. OK Ratio Total.Area... Area.Peak. 1. .  Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.
  13C12-TCDD
  332-334
  332-334

DC





DC
DC
DC

0.
NL 0:00 RO
20:28 RO
21:36
21:53
22:39
23:12
WH 24:09 RO
WH 24:24 RO
WH 24:57
5 Peaks
65-0.89
1.61
0.98
0.80
0.81
0.77
0.73
0.42
0.34
0.73

                                        Above:  TCDF / TCDD Follows
                                                 1.10
                                                 7.22
                                             1,648.64
                                             1,888.28
                                                21.41
                                                 3.75
                                                 2.44
                                                 4.78
                                                 4.83
                                             3,569.30
                                                                              0.908-1.092
                                                       0.000
                                    3.99          4.08  0.948
                                  733.76        914.88  1.000 13C12-2378-TCDD IS1
                                  847.43      1,040.85  1.013 13C12-1234-TCDD RSI
                                    9.28         12.13  1.049
                                    1.58          2.17  1.074
                                                       1.118
                                                       1.130
                                                       1.155
 Column Description	  'Why* Code Description	   QC  Log Desc.
 M_Z   -Nominal Ion Hass(es)
  ..RT. -Retention Tine (mm:as)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO-Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report
       WL-Below Retention Tiae Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
eHasP98Q103 tl-923 Acq: 7-JAN-
303.9016 Sxp:DB225
ZBXAMGZZ LASS  Taxti201-204   XLH44376*
                                 07: Jam EI+ Voltage SIS 70P
     22:36 22:48  23:00  23:12 23:24  23:36 23:48 24:00 24:12  24:24 24:36  24:48
T±la:P980103 tl-923 &cq:7-J*N-98  07:36:14 XH- Voltage SIS 70P
315.9419 Sxp:DB225
TRIANGLE LABS  Text:201-204   TLH44376A
100*                23 04
 95:
 90.
 85.
 80:
 75:
65.
60:
55j
50:
45:
40.
35:
30.
25.
20:
15:
10:
 5:
 0:
                                                                                                    O.OEO
                                                                                25:66'25:12'25i24'    lime
                                                                                                   -2.7E6
                                                                                                   '.2.5X6
                                                                                                   '.2.4K6
                                                                                                   .2.3E6
                                                                                                   '•.2.1E6
                                                                                                   '.2.0E6
                                                                                                   '•.1.9X6
                                                                                                     .7X6
                                                                                                   -.1. 6X6
                                                                                                     .5X6
                                                                                                     .3X6
                                                                                                   -.1.2X6
                                                                                                     .1X6
                                                                                                   .9.3X5
                                                                                                   .8.0X5
                                                                                                   '•-6.6X5
                                                                                                   .5.3X5
                                                                                                   '•.4.0X5
                                                                                                   L2.7ZS
                                                                                                     .3X5
    22,36  22:48 23:00  23:12 23:24  23:36  23:48 24:00 24:12  24,24  24:36 24:48
                                                                                                    0.0X0
                                                                                25:00 25:12  25:24     T±me
                                                                                                   377

-------
rU.aify80J.OJ  tl-923 Acq>7-JMf-yo U/:JO:J.« t.j.r v
-------
              tl-923 Acqi7-JAH-yo u/uoiAl sx+ Voltage SIS  70S Hoi**,254
 319.8965 BSU3(256,30,-3.0)  PXD(5,3,l,0.10\,1016.0,0.00\fr,r) Kxp,DB225
 TSIMKLX LABS  Text:201-204   TLH44376A
 100*
  80.

  60.


  40.

  20.
            A1.52XS
                              A4.10X4         A7.95X4
                          i\  A A  "-r ^A.
                50.00           21,00           22,00
Tile,P980103 tl-923 Acq,7-JKS-9S  07,36,14  XH- Voltage SIS 70V Soime,332
321.8936 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,1328.0,O.QO\,T,T) XxptOS225
TSXAHGLX LABS  Tajct: 201-204    XLIt44376A
1004
  00.

  60.

  40.

  20.
            Al . 72X5
                       A4.S1E4
                                             *.98Z4
                                                            *7.99X3
                20:00           21:00           22:00           23:00
riIe:P980103 tl-923 Acq:7-J3UT-98  07:36:14 XH- Voltage SIB 70V Noiae:303
327.8847 BSUB(256,30,-3.0) PKD(5,3,1,0.10\,1212.0,0.00\,T,T) Exp,DB225
TSIASSLX LABS  Text:201-204   TLIt44376A
1004                                     A1.52X7
  80.

  60.

  40.
 20.
                Al.05X6
                   A
                                                =9-
                20,00           21:00           22:00           23:00
TiletV980103 tl-923 Acq,7-J7Oi-98 07:36:14 XI+ Voltage SIS 70V Bolae,498
331.9368 BSU3(256,30,-3.0) PXD(5,3,1,0.10\,1992.0,O.OQ\,T,T) KxptDB225
T&IANGIX LABS  Text:201-204   TLIt44376A
1004                                         AS.47X6
 80.

 60.

 40.

 20.
                                         A7.34X6
                20:00           21:00           22:00           23:00
rlle:P980103 tl-923 Acqt 7-JZ1T-98 07:36:14 XI+ Voltage SIS  70V Boise,309
 33.9338 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,1236.0,0.00\,T,T) Xxp,DB225
TRIANGLE LABS  Text,201-204   TLH44376A
1001

 80.

 60.

 40.

 20:
                                                 4X7
                                                                                24tOO
                                                                               A2.56X3

                                                                                '24'-. oo
                                                                                24tOO
                                                                                24iOO
  7.3X4

 .5.9X4

 .4.4X4

 '.2.9X4

 .1.5X4
                                                                                                    .0.0X0
                                                                                                 25 00 Tim
  8.4X4

 .6.7X4

 .5.0X4

 .3.4X4

 _1. 7X4
                                                                                                   .0.0X0
                                                                                                25 00  Tia
                                                                                                    4.3X6

                                                                                                   .3.5X6

                                                                                                   .2.6X6


                                                                                                   .1. 7X6

                                                                                                   .8.7X5
                                                                                                   .0.0X0
                                                                                                25tOO  Tiae
^2.3X6

  .9X6

_1.4X6

.9.3X5

.4.6X5
                                                                                                   .0.0X0
                                                                                                25 00  Tia,
                20tOO
                                2liOO
                                                22iOO
                                                               2300
                                                                                24iOO
                                                                                                25
                                                                                                  -2.8X6

                                                                                                   .2.2X6

                                                                                                   J..7X6

                                                                                                   .1.1X6

                                                                                                  .5.6X5
                                                                                                   .0.0X0
                                                                                                   00  Tia,
                                                                                                      379

-------
Tila:P9801Q3 tl-923 Acq:7-J&N-98 07:36:14 EI+ Voltage SIS 70P
303.9016 Exp:DB225
TRIAHGLX LABS Text: 201-204 XLIt44376A
1003
80.

SO.

40.
20.
a
21:09
1
20:36 II
19:42 1 \ .... 22:30
1 20:18 n if1 i ":56
19:27^ A 11 1 fliA ft ftftl

19:00 20:00 21:00 22:00 23:00
rile:P980103 tl-923 Acq:7-J3Ur-98 07:36:14 XH- Voltage SIS 70P
315.9419 Kxp:OB225
TSIAXGZX LABS Taxt:201-204 XLIt44376A
1001
80:
601
401
20.

23i04




l\
19:00 ' ' ' 20:00 21:00 22:00 23:00
r±le:P980103 tl-923 Actj:7-JXK-98 07:36:14 XI+ Voltage SIS 70P
319.8965 Xxp:D3225
TBIANGZS LABS Text: 201-204 TLH44376A
1001
aol
60:
40:
201
0'
19-16
I
19:49
fl
20:53 21:54
. . .. 19,oj[ _ J\ iQtlA^AA A, __j^A/V _ ^^^.^JL?!.
19:00 20:00 2l':0b 22:00 23\00
Tile:P980103 tl-923 Acq:7-J3UT-98 07:36:14 XH- Voltage SIS 70P
331.9368 Xxp:DB22S
TSIASSLX LABS Text:201-204 TLH44376A
1001

aol
601
401
201
ol
21:53
21:36 I
I



/I M
19:00 ' ' ' 20:00 ' 2li 00 ' ' ' 22:00 ' ' ' 23^00
Tlle:P980103 tl-923 Acq:7-JMT-98 07:36:14 XI+ Voltage SIS 70P
292.9825 Exp:DB225
TSIAHSLX LABS Text: 201-204 XZ.H44376A
1001
aol
60:
40:
20:
ol
vJS^r^Z^vJly^f^^^^v-^A^2 3^23is48 33iia 23:02
™* W'^T ^^y^^y^^j/^r^^^fftft^^




19:00 20:00 21:00 22:00 ' 23:00
r±latP9B0103 tl-923 Aoq:7-J3OT-98 07:36:14 EI+ Voltage SIS 70P
330.9792 Exp:OB225
TSIASGZX LABS Text: 201-204 TLH44376A
100*
80:
60:
40:
20:
ol



-1.1X5

97 * 7.J
*J t J*
i
A A
ft "h30

'•.9.1X4

.6.8X4

.4.5X4
.2.3X4
O.OEO
24:00 25:00 ' ' Tt««



-2.7X6





'.2.1X6
:1 . 6X6
'•.1.1X6
'•.5.3X5
' 0 . 0X0
24:00 25:00 Time



-7.6X4




23:54 24:30 35j°\
.6.1X4
'.4.SE4
13.1X4
.1 . 5E4
• 0 . OEO
24:00 2S':00 Tiaa



-2.3X6







.1.9X6
.1.4X6
.9.3X5
.4.6X5
O.OEO
24:00 25:00 Time



23:35 24:31 24:59
•^,-»YV>'VV'YV*"''*VVIr**~*Y^




.3.7X6
.2.9X6
.2.2X6
.1.5X6
.7.3X5
0.0X0
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in •• ..1i rt u^~> rtjr^LJWVufWV^l/W mJ4 lVj~*VTll lA^lm> JUIftr\f*j4t*Jlft ^>.^« f-US*Ak^ *A . J*n^ A . /^«m Al*« n i~kta 1 i ft n an • m» i lA
W*+>t'*r*w~ **v* W*^*Y*r^^fw -T lY^^r*1! yH r v^y-y** i\aY*y^^v^*^*wW/^FV> /TV*»T*'*%/V^/>/^^**^r rt^^f^f^*'1t^




19:00 20:00 21:00 22:00 ' 23': 00




.2.9X6
.2.3X6
J..7X6
.1.1X6
.5.7X5
O.OEO
24\00 ' ' ' 25:00 ' ' ' Time
330

-------
Ref, lass    292.9825     Peak top
Height   ,78 volts Span   288 ppi
Systei file naie
Dka  filenaie
Resolution
(tap niter
lonization Mde
Switching
Ref, lasses   292.9825,
fl   292.9825
B   383.9816
D   315.9419
E   317.9389
F   319.8985
6   321.8936
H   327,8847
I   338.9792
J
K
L
H
       1
     El*
 VOLTRGE
388.9761
338.9792
331.9388
333.9338
375,8364
Channel   I  338,9792    Peak top
Height   ,55 volts  Span   288 ppa
                                                        381

-------

 TLI Project:     44376A
 Client Sample:   CleanUp Blk
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   U980037
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
SOLVENT Date Received: 12/17/97
TLI Clean-Up Date Extracted: 01/05/98
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: U980037
DB-5 Analyst JM
Spike File:
ICal:
ConCal:
% Moisture:
%Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3.7,8-PeCDD
1,2.3,4,7,8-HxCDD
l.Z3.6.7,8-HxCDD
1,2,3,7.8,9-HxCDD
l,Z3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
',2,3,4,7,8-HxCDF
.,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2.3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4.7,8.9-HpCDF
1,2,3,4.6,7,8,9-OCDF
ABlL$igt
ND
ND
ND
ND
ND
ND
0.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
d. EMPC
f
0.002
0.004
0.005
0.004
0.004
0.005

0.002
0.002
0.002
0.004
0.003
0.004
0.004
0.004
0.004
0.005
Ratto RT flags





	
0.82 39:36 J_










Totals
Total MCDD
Total DCDD
Total TriCDD
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total MCDF
Total DCDF
Total TriCDF
Total TCDF
Total PeCDF
Total HxCDF


Amt (n^ Number DL EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND


<0.001
<0.001
<0.001
0.002
0.004
0.005
0.005
<0.001
<0.001
<0.001
0.002
0.002
0.003
Continued on next page
Pagel of 2 '
Flags






—







MTRJ>SRvl.01.LA]tt 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                    Printed: 11:07 01/10/98
                                382

-------
 TLI Project     44376A
 Client Sample:   CleanUp Blk
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  U980037
rotate
Total HpCDF
internal Standards
13Cir2,3,7,8-TCDF
13C,2-2^,7,8-TCDD
13C,rl,2,3,7,8-PeCDF
13C,2-U,3.7,8-PeCDD
13C,2-l^,3,6,7,8-HxCDF
l3C,2-U,3,6,7,8-HxCDD .
13C12-l,2,3,4,6.7,8-HpCDF
13C,2-l,Z3,4.6,7,8-HpCDD
13Ci2-l,2v3,4,6J,8,9-OCDD

Alternate Standards {Type A}
13C,2-1.2,3,7,8,9-HxCDF
13Cl2-2,3,4,6,7,8-HxCDF
Recovery Standards
13CI2-U,3,4-TCDD
I3C12-U,3.7,8.9-HxCDD
' Aflit fa$//?2-1tottnts& Dt*.
ND
Atn£. {0
-------
                         Initial
                                     , .Date.
  Data Review By:
                                    111
                                               Calculated Noise Area:
                                                                      2.00
  The Total Area  for each peak with an  ion abundance ratio outside
  ratio limits  has been recalculated according to method requirements.
  Page No.
  01/10/98
Listing of  CJ980037B.dbf
Matched GC  Peaks / Ratio / Ret.  Time
  Compound/
  M_Z....  QC.Log Omit Why ..RT.  OK Ratio Total.Area.,
                           Area.Peak.1..  Area.Peak.2..  Rel.RT  Compound.Name..  ID..  Flags.
TCDF
304-306

0

D
0

0 .
D
304-306
13C12-TCDF
316-318









316-318
TCDD
320-322
N










320-322
13C12-TCDD
332-334

DC
DC
D
DC
D
D
DC
D
D


DC




DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC

NL
WL
SN
SN
SN
SN
SN
SN
SN
0

NL




WH
WH
WH
WH
WH
4

NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
0

NL

0
21
24
24
25
25
25
26
26

:00
:28
:00
:33
:09
:16
:32
:03
:14
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65-0.89
0
1
2
0
0
0
0
0
1
.44
.23
.26
.00
.39
.41
.31
.34
.31
Peaks

0
24
24
25
25:

:00
:13
:38
:00
:31
25:55
25:
26:
26:
26:
:57
:16
;17
:22
0
RO
RO

RO

RO

RO
RO
RO
.65
0
0
0
1
0
1
0
1
0.
0.
Peaks

0:
22:
23:
23:
23:
23:
24:
24:
25:
25:
26:
26:

00
48
14
19
33
47
07
45
19
34
07
33
0.
RO
RO
RO

RO
RO
RO
RO
RO
RO


-0.89
.95
.56
.78 9
.08
.68
.64
.69
.43
.95
.53
10
65-0.89
0.
0.
1.
0.
0.
0.
5.
7.
1.
0.
0.
0.
09
54
52
74
04
58
26
21
32
60
78
75
Peaks

0:

00
0.
RO
8
5
5
0
9
9
2
11
4
0

7
39
,898
170
38
14
24
5
12,
10.
.18
.45
.31
.18
.08
.47
.94
.65
.92
.00

.98
.51 17.19
.83 4,345.47
.36 103.69
.43 15.58
.04
.11
.70
.28
.16
0.867
0
0
0
0
1
1
1
1
1

0.959
0
30.64 0
5,553.36 1
96.25 1
22.85 1
1
1
1
1
1
-1.079
.000
.871
.974
.997
.021
.026
.037
.058
.065

-1.041
.000
.983
.000 13C12-2373-TCDF ISO
.015
.036
.052
.053
.066
.067
.070
,147.13

0.
4.
1.
1.
0.
0.
0.
0.
1.
39
53
95
48
16
97
48
51
31
2.51
1.
2.
0.
41
98
00
65-0.89
2.
40
11.
91
0.895-1.047
0.000
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.

0.921-
0.
900
917
920
930
939
952
977
999 2378 -TCDD AN
009
031
048

1.079
000
Triangle laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 11:08Q4/lp/fl8

-------
  Page No•
  01/10/98
Listing of 0980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z....  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.
                                                                             Rel.RT Compound.Name.. ID..  Flaga.
332-334 •
PeCDF
340-342


D
D






340-342
13C12- PeCDF
352-354







352-354
PeCDD
356-358














DC
DC
DC
D
D
DC
DC
DC
DC
DC
DC


DC









DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
7

KL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL







7

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
24:09 RO
25:10
25:20
25:40
25:49 RO
25:55
26:03 RO
Peaks

0
26
27
27
27
28
28
29
29
29
30

:00
:34
:17
:34
:44
:18
:43
:24
:40
:51
:32
1
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
0.60 25.01 10.88
0.82 10,108.54 4,559.84
0.79 7,774.25 3,440.92
0.69 307.27 125.92
0.20 35.42 15.41
0.71 34.33 14.28
0.48 97.10 42.24
18,381.92
.32-1.78
0
0
0
0
1
0
0
0
0
0
0
.15
.28
.85
.75
.32
.46
.87
.51
.24
.24
.72
Peaks

0:
27
28:
29:
29:
29:
29:
30:

:00
:41
:35
:01
:09
16
35
13
1.
RO
RO

RO
RO
RO
RO

0
0
3
5
9
3
2
3
0
0
3
0
.48
.95
.73
.05
.41
.01
• 16
.83
.87
.97
.26
.00
32-1.78
1,
0,
1.
1.
0.
1.
0.
1.
Peaks

0:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
30:
30:

00
11
34
51
03
23
31
39
45
51
01
19
26
1.

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-
1.
0.
5.
0.
20.
0.
2.
1.
4.
2.
1.
6.
2.
,31
,67
55
17
97
99
54
73

1.78
33
45
54
78
60
75
70
85
16
06
13
29
13
0.28
8
8,807.
91.
50.
90.
9.
20.
9,078.
: PcCDI
0.
0.
2.
1.
0.
1.
1.
2.
1.
1.
1.
0.
2.
.95 5.44
53 5,357.35
,26 55.47
03 30.41
40 70.71
95 6.05
34 12.88
46

28
54
86
02
13
40
17
88
25
20
28
43
35
18.17 0.953
5,548.70 0.993 13C12-1234-TCDD RSI
4,333.33 1.000 13C12-2378-TCDD IS1
181.35 1.013
78.11 1.019
20.05 1.023
88.40 1.028
0.925
0
0
0
0
0
0
1
1
1
1
1

-1.065
.000
.929
.955
.964
.970
.990
.005
.029
.038
.044
.068

0.860-1.140
0
8.17 0
3,450.18 1,
47.25 1.
31.51 1.
35.45 1.
11.11 1.
7.46 1.

.000
.969
,000 13C12- PeCDF 123 IS2
.015
,020
024 13C12- PeCDF 234 SOR1
035
057

0.935-1.. 022
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
952
965
975
981
993
997
002
005
008
014
024
028
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 11:08 01710/98
                                                                             385

-------
  Page No.
  01/10/98
Listing of 0980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.

356-358
13C12-PeCDD
368-370









368-370
HxCDF
374-376









174-376
13C12- HxCDF
384-386





384-386
HxCDD
390-392








DC


DC
DC
DC









DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC







DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
0

NL
SN
SN







7

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL





5

HI
SN
SN
SN
SN
SN
SN
SN
SN
30:32
Peaks

0:00
28 : 12
28:34
29:36
29:43
29:54
30:03
30:10
30:18
30:24
Peaks

0:00
31:05
31:10
31:19
31:41
31:52
32:03
32:11
33:23
33:41
Peaks

0:00
31:04
32:08
32:37
33:12
33:23
Peaks

0:00
31:32
31:35
31:52
32:01
32:08
32:20
32:33
32:37
RO

1
RO
RO
RO


RO
RO
RO


2

.32
1
1
0
1
1
1
0
0
1
1
.58

-1.78
.00
.06
.50
.50
.59
.88
.67
.72
.61
.47
1.40
0
.00
1

.032



0.865-1.135
0
1
2
3,551
614
125
48
20
30
26
.16
.63
.20
.87 2,132.05
.34 377.00
.26 92.56
.29 29.35
.37 12.38
.15 18.58
.73 15.91
0
0
0
1,419.. 82 1
237.34 1
49.12 1
43.95 1
17.09 1
11.57 1
10.82 1
.000
.953
.965
.000 13C12-PeCDD 123
.004
.010
.015
.019
.024
.027



IS3






4,417.01
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

0.
RO
RO


RO


1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
05-1.43
0
0
0
1
1
.87
.83
.87
.82
.54
5.00
4.
0,
.31
,48
3.92
3.15


2
3
2
1
3
.98
.05
.64
.23
.70
1.21
1.52
2.04
0.87
0.74
0.
.00
43-0.59
0.
1.
0.
0.
0.
0.

05-
0.
3.
1.
0.
1.
4.
2.
0.
1.
71
23
50
51
19
50

1.43
80
74
69
54
46
67
80
78
71
4.
5.
5,695.
6,312.
9.
4,656.
26
75 4.68
03 1,909.27
25 2,133.84
15 3.09
05 1,543.48
0.962-1.047
0
0
0
0
0
0
.000
.967
.970
.975
.986
.992
0.997 123478-HxCDF






AN
1.002
1.039 123789-HxCDF
1.

.048

AN


0.876-1.124
0.
3.81 0.
3,785.76 1.
4;i78.41 1.
15.91 1.
3,112.57 1.
000
967
000 13C12-HXCDF 678
015 13C12-HXCDF 234
033
039 13C12-HXCDF 789


IS4
ALT 2

ALT1
16,678.23
: HxCDF / HxCDD Follows --'
0.
0.
1.
0.
3.
2.
1.
0.
4.
07
43
14
89
38
49
23
94
48
0.958-1.014
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
961
963
972
976
980
986
992
994









Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 11:08 01710/98
                                                                              386

-------
  Page No.
  01/10/98
Listing of  U980037B.dbf
Matched GC  Peaks  /  Ratio / Ret. Time
  Compound/
  M_Z....  QC.Log Omit Why
.RT.  OK Ratio  Total.Area... Area.Peak.1.. Area.Peak.2:. Rel.RT Compound. Name. .  ID.. Flags.
  402-404
  HpCDF
  408-410
  408-410

  13C12-HpCDF
  418-420
  418-420
 HpCDD
 424-426
 424-426

 13C12-HpCDD
 436-438

 436-438
DC
DC
DC
DC
DC


DC






DC
DC
DC


DC










DC
DC
DC
DC
DC


DC


SN 32:44 RO 1.72
SN 33:07 RO 0.41
SN 33:09 RO 0.78
SN 33:23 RO 3.62
SN 33:30 RO 1.46
0 Peaks
1.05-1.43
NL 0:00 RO 1.52
32:12 1.30
32:48 1.21
33:07 1.21
33:27 RO 0.80
4 Peaks
0.88-1.20
NL 0:00 RO 1.26
SN 36:36 RO 0.27
SN 36:52 RO 0.29
0 Peaks
0.37-0.51
NL 0:00 RO 0.55
35:01 0.41
35:28 RO 0.86
35:33 RO 0.36
35:47 RO 0.87
35:49 RO 0.62
36:01 RO 1.05
36:23 RO 0.65
36:32 RO 1.07
8 Peaks
0.88-1.20
NL 0:00 1.00
SN 35:07 1.09
SN 35:49 RO 0.75
SN 36:16 RO 2.12
SN 36:30 RO 0.46
0 Peaks
0.88-1.20
NL 0:00 1.00
36:02 1.03
1 Peak
2.20
1.16
0.98
2.20
1.79
0.00

4.12
15.14 8.56
4,832.68 2,642.35
6,159.80 3,378.48
108.64 60.14
11,116.26
• Uvfnn / Urs^T^E1 CV» 1 1 <-iun
HXlfUU / np^Ur rOJL^OwS - -
3.84
1.90
1.94
0.00

8.38
4,102.52 1,201.45
23.56 14.14
39.89 12.19
9.79 5.94
12.97 5.55
6.96 5.07
5.77 2.59
12.70 9.44
4,214.16
: HpCDF / HpCDD Follows —
0.08
3.41
2.02
1.57
0.96
0.00

6.61
3,899.39 1,981.38
3,899.39
Hof^nn / n^t'w-fnn »nH f"HE*
0.998 123478-HxCDD
1.010 123789-HxCDD
1.011
1.018
1.021

0. 970-1. 030
0.000
6.58 0.982
2,190.33 1.000 13C12-HXCDD 678
2,781.32 1.010 13C12-HXCDD 789
75.28 1.020

0.996-1.049
0.000
1.045
1.053

0.943-1.114
0.000
2,901.07 1.000 13C12-HpCDF 678
16.36 1.013
33.78 1.015
6.80 1.022
9.01 1.023
4.83 1.029
4.01 1.039
8.82 1.043 13C12-HpCDF 789

0.975-1.005
0.000
0.975
0.994
1.006
1.013

0.972-1.028
0.000
1,918.01 1.000 13C12-HpCDD 678

AN
AN







IS5
RS2









IS6






SUR4










IS7

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 11:08

-------
   Page Ho.
   01/10/98
                         Listing of O980037B.dbf
                         Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK Ratio  Total.Area... Area.Peak.1. .  Area.Peak. 2. . Rel.RT Compound.Hame..  ID.. Flags.
  OCDF
  442-444
  442-444

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


NL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

0
34
35
35
35
35
36
36
36
37
37:
37:
38:
38:
39:
39:
39:
39:
40:
40:
40:

:00
:26
:01
-.12
:28
:39
:06
:16
:36
:11
:17
:25
:01
48
02
07
22
38
08
18
43
0.

RO
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76
1
1
0
3
2
2
0
2
0
0
0
1
2
0
0
0
4
0
0
2
0
-1.
.00
.81
.33
.33
.09
.32
.83
.42
.25
.02
.07
.88
.07
.74
.23
.64
.73
.48
.13
.24
.63
Peaks
                                                  0.08
                                                  0.40
                                                  0.59
                                                 0.45
                                                 1.00
                                                 0.95
                                                 2.12
                                                 0.59
                                                 0.55
                                                 0.06
                                                 0.06
                                                 0.49
                                                 0.77
                                                 0.74
                                                 0.74
                                                 0.83
                                                 0.28
                                                  .00
                                                  .62
                                                  .64
                                                  .10
                                                                             0.899-1.101
                                                                                 0.000
                                                                                 0.870
                                                                                 0.384
                                                                                 0.889
                                                                                 0.896
                                                                                 0.900
                                                                                 0.912
                                                                                 0.916
                                                                                 0.924
                                                                                 0.939
                                                                                 0.941
                                                                                 0.945
                                                                                 0.960
                                                                                 0.980
                                                                                 0.986
                                                                                 0.988
                                                                                 0.994
                                                                                 1.001
                                                                                 1.013
                                                                                 1.018
                                                                                 1.028
                                                 0.00
OCDD                           0.76-1.02
458-460         DC  NL    0:00  RO   1.33          0.06
        AN              39:36      0.82          9.93
                DC  SN   40:05  RO   0.41          0.59
<58-460              1  Peak                    9.93

13C12-OCDD                     0.76-1.02
470-472         DC  NL    0:00      1.00          0.08
                        39:36      0.87      5,658.40
470-472              1  Peak                5,658.40
                                                                              0.899-1.101
                                                                                  0.000
                                                              4.46          5.47   1.000  OCDD            AN
                                                                                  1.012
                                                                              0.996-1.004
                                                                                  0.000
                                                           2,640.48      3,017.92   1.000  13C12-OCDD       IS8
  Column Description	   "Why"  Code Description	  QC Log Desc.
 M_Z    -Nominal Ion Mass(es)
  ..RT.  -Retention Time (mm:ss)
 Rat.l  -Ratio of M/M+2 lona
 OK     -RO-Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report ••*
                               WL-Below Retention Time Window
                               WH-Above Retention Time Window
                               SN-Below Signal to Noise Level
                               
-------
 ril»tU9a0037 tl-734 Acq:  7-JXN-1998  02:18:30  GC EH- Voltage SIX 70S ltoj.mmtj.779
 303.9016 Ti2 BSUB(2S6,30,-3.0)  PXD(9,5,3,0.10\,7116.0,1.00\,r,T)  SxptSDSSUS
 TRIANGLE LASS  Text-.CLEANUP BLANK TLIH4376A
 100*
                                                                   A3.94X4
              32100            23:00            24',00             25iOO
 rile:U980037 tl-724 Aeqi 7-JJUT-1998 02>18t30 GC XH- Voltage SIS  70S Nolae:4023
 305.8987 T:2 SSUS(256,30, -3.0) PKD(9,5,3 ,0.10\,16092.0,1.00\,T,T) Kxp:NDB5US
 TSIANGZX LASS  Text:CLEANUP BLANK  TLH44376A
 1001
                                                                      26100
              22:00            23t00            24:00            25:00
file:U980037 tl-724 Ac?: 7-JAH-1998 02:18:30 GC XI+ Voltage SIS 705 Noises 2143
315.9419 T:2 BSUB(256,30,-3.0) PXD(9,5,3,0.10\,8572.0,1.00\,r,T) XxpiNDBSUS
TRIANGLE LABS  Text:CLEANUP BLANK  TLH44376A
100*                                                      A4.35E7

  80:

  sol

  40:.

  201
                                                                      26100
             22:00            23:00            24:00            25:00
rilaiO980037 tl-724  Aoqi  7-JAN-1998 02:13:30 SC EH- Voltage SIS 70S Noiae:2256
317.9389 fi2 BSUB(256,30, -3.0) PXD(9,5,3,0.10\,9024.0,1.00\,r,T) SxpsBDBSOS
TBIANGLS LABS   Text!CLEANUP BLANK  TLH44376A
1004                                                     AS. 5^5X7

  80:

  sol

  40:

  20:

                                                            I  V
                                                                                   26100
             22:00             23:00            24:00            25:00
ri!e:U980037 tl-724 Acqi  7-JAN-1998 02:18:30 GC XI+ Voltage SIS 70S
330.9792 T:2 Exp:NDB5US
TRIANGLE LABS  T&rt: CLEANUP BLANK  TLH44376A
1001
                                                                                  26:00
 60:
 40:
 20:
  0:
                                                                        25:24  25:4
             22:00             23:00            24:00            2SsOO
Tile:U980037 tl-724 Aoj:  7-JAN-1998 02:18:30 GC XI+ Voltage SIS 70S
375.8364 F:2 Exp:NDB5US
TRIANGLE LABS  Text:CLEANUP BLANK  TLIt44376A
                                                                                  26100
1001
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  o:\
                                                                  25
                                             24135
21:5\
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                                         24 1 21
                    23108
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                                                                     03
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                                                                                         9.6X6

                                                                                        -.7.7E6

                                                                                        .5.8X6

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                                                                                        il.9E6
                                                                                         0.0X0
                                                                                            Time
             32:00
                               23:00
                                                24:00
                                                                 25:00
                                                                                  26:00
.1.2X7

.9.9X6

.7.4X6

.4.9X6

.2.5X6

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.3.4X7

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.2.1X7

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                                                                                                      389

-------
Tile>a980037  tl-724 Acqt  7-JAK-1998 02113130 GC EI+ Voltage SIS 70S Naif at 34
319.8965 Tt2  BSUB(256,30, -3.0) ?XD(7,5,3,0.10\,336.0,1.00\,r,T) Exp:NDB5US
TRIANGLE LABS T*xt:CLEANUP BIMtf  TLIt44376A
100*                                      A6.47X4
                    A1.23E4

             A1.67X4  I  I A4.24E3
         23,00                 24100                 25100                26:00
rHat0980037 fl-724 Acqt  7-JXK-1998 03tl8i30 SC XH- Voltage SIB 70S Sola*,991
321.8936 Tt2 3SUB(256,30, -3.0) PXD(7,5,3, 0.10%,3964.0,1.00\,r,T) SxptHDBSUS
TSXASGLS LABS  Text:CLEANUP BLAKK  TLH44376A
1001
         23': 00                 24:00                 25,00                26:00
F±l»tU980037 tl-724 Acqt 7-JAN-1998 02il8t30 SC EI+ Volttgm SIS 70S Noia*i8092
331.9368 Ti2 BSUB(256e30,-3.0) fXD(7,S,3t0.10\r32368.0,1.00\rT,T)  ExptSDBSUS
TSIAKSLX LASS  Taxt:CLEANUP BtANX  TLIt44376A
001
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A

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TilatU980037 tl-724 Acqt 7-JAN-1998 02:18,30 SC EH- Voltage SIS 70S Noises3367
333.9338 F,2 BSUB(256,30f-3.0) ?XD(7,5,3rQ.10\r13468.0,1.00\,T,T)  XxpiNDBSUS
TRIANGLE LASS  Texts CLEANUP BLANK  TLH44376A
1001                                                  AS. 55X7

                                                           4.33X7
 40:
 20:
         23:00                24,00                 25,00                26:00
file,0980037 tl-724 Acqt 7-JAN-199S 02,18,30 SC EH- Voltage SIS 70S Soiae,6S
327.8847 Tt2 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,260.0,1.00\rr,T) XxptNDBSUS
TRIANGLE LASS  Text-.CLEANUP SLANX  TLH44376A
1001                          A9.31X4

 80:

 60:

 40:

 20:

  o:
                                                                                                 OEO
                                                                                                  Time
                                                                                                 1X7

                                                                                                 9X6

                                                                                                 6X6

                                                                                                 4X6

                                                                                                 2X6

                                                                                                 0X0
                                                                                                  Time



                                                                                                 4X7

                                                                                                 1X7

                                                                                                 4X6

                                                                                                 6X6

                                                                                                 8X6

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TiletU980037 tl-724 Acqt 7-JAK-1998 02 1 18 1 30 GC XH- Voltage SIS  70S
330.9792 Tt2 XzptKDBSUS
TRIANGLE LABS  Text i CLEANUP BLAST  TLH44376A
                                                                         26:00
001
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                                                                                                 4X7

                                                                                                 9X6

                                                                                                 0X0
                                                                                                  Tiae
                                                                                                   390

-------
TiltiO980037 tl-724 Acq, 7-JAM-1998 02,18,30 SC ZX+ Voltage SIS 70S Hoifet 144
339.8597 T,2 BSUB(25S,30,-3.0) PXD(7,5,3,0.10\,57S.Ot1.00\,T,X) XxptHDBSUS
TXIAHGLX LABS T«Xt : CLXAHOP BUUOC XLIt44376A
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341.8567 Ti2 BSUB(2S6,30,-3 .0) PXD(7,5,3,0.10\,3864.0,1.00\,r,T) XxpiSDBSUS
TSIAHCLX LABS TmxtiCLZASUP BLANK XLIt44376A
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TB.IAXGLX LABS TextlCLXAXUP BLASK XLIt44376A
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Tila,U980037 tl-724 Acq, 7-JXM-199B 02, IB, 30 SC XI* Voltage SIX 70S
409.7974 Tt2 XxptHDBSUS
TXIAOGLX LABS Text. t CLEANUP BUOX TLIt44376A
1001
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-------
fil»:OSB0037  U-734 Acq:  7-J&H-199B 02:111: JO SC a 4- Malaga JH 70S Jtoi««;7JT
355.8546 Ti2  BSOS(256,30r-3.0) PXD(S,5,3, O.fl5%, 316. 0,1. 00\,r,T) Xrp:SDBSUS
TSIAHSZX LASS  Text : CLXANUP BLANK  TLH44376A
 100$
  80.
                                                                  A2.
                                               .0314
                                                  A3.68X3
                                                       AS. 46;
                                                                                       A1.96I4
                         38,24 28i36  28t48  25:00 25»i2 «».« 29t3S 29:48  30tOO 30:12 30:24
rila:O980037 tl-724 Acq:  7-JMT-1998 02tl8i30 SC XX* Voltage SIS 70S Soisai60
357.8516 Ts2 BSUB(256,30, -3.0)  PXB(5,5,3,0.05\,240.0,1.00*,r,T) SzptSDBStJS
TXIAHSLX LASS  TetrtiCLEANUP SLAOX  TLH44376A
100\A2. 5X4
      27t48 28'tOO 28:12 28:24 28:36 28:48  29'tOO 29:12 29:24 29:36 29:48  30:00 30:12 30:24
r±le:U980037 il-724 Acq:  7-JA1T-1998 02:18:30 SC EI+ Voltage SIX  70S Woiae:50
367.8949 T:2 3SUB(256,30, -3.0)  PXD(5,5,3, 0. OS\,200.0,1.00\rf,I)  Xxp-.ODBSUS
XBIAHSLS LASS  Text:CLEANUP BLANK  TLH44376A
100\                                                         A2.J.3X7


 80.

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      27:48 28:00 28:12  28:24 28:36 28:48  29:00  29:12 29:24 29:36 29:48  30:00  30:12 30:24
r±le:ff980037 tl-724 Acqs  7-JAJT-1998 02:18:30 SC ZI+ Voltage SIX  70S SQiae:48
369.8919 f:2 SSUB(256,30, -3.0) PXD(5,5,3,0.05\,192.0,1.00\,r,T)  ExptHDBSUS
TXIASSLX LASS  Teit:CLEANUP BLANK  TLH44376A
100\                                                         A1.42X7

 80.

 60.

 40:

 20.
  0.
                                                                    .37X6
      27:48 28:00 28:12  28:24 28:36 28:48  29:00  29:12 29:24 29:36 29:48 30:00  30:12 30:24
T±la:O980037 tl-724 Aoq:  7-JJOT-1998  02:18:30 GC XI+ VoZtagn  SIX  70S
330.9792 T>2 ExptNDBSUS
TXIANSLX LASS  Texts CLEANUP BLANK TLIt44376A
1001

 80.

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                           28:29  28:42
30:18
             1.5X4

            '.1.2X4

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            .0.0X0
                Time
            -6.2X6

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                                                                                                 0.0X0
                                                                                                    Time
             4.2X6

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            .2.5X6

            .1.7X6

            .8.3X5
             0.0X0
                Time
-3.5X7

.2.8X7

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      27:48 28:00 28:12  28:24  28:36 28:48 29:00  29:12 29:24 29:36 29:48 30:00  30:12 30:24
             0.0X0
                Time
                                                                                                     392

-------
 r±la*a980037  #1-385 Acq:  7-JAN-1998 02118130  GC XI+ Voltag* SIX  70S HoiM»i827
 373.8208 T>3  BSUB<256,30, -3.0)  PXD(7,5,3,0.10\,3308.0,1.00\,rfX): XxptBEBSUS
 TXIANCLX LABS Text: CLEANUP BLANK  TLH44376A
 1004                                A3.93X4
    31',00  31:12  31*24 31*36 31*48  32*00  32*12 32*24 32*36 32:43 33*00 33*12 33*24  33*36 33*48
\r±l«iO980037 tl-385 Acq, 7-JAN-1998 02*18*30 GC XX* Voltage SIS 70S Sa&Mmt950
\375.8178 T*3 BSUB(2S6,30,-3.0) PKD(7,5,3,0.10\,3800.0,1.OQ\,T,T) SzpiSOSSUS
TSIAOSLX LABS  Taxt:CLEANUP BLANK  TLH44376A
100\
                                        A2.37X4
       A2.04X4
                                                     A1.31X4-
                          .65X4       -;;...;             .                     ..  ^M
    31,00  31': 12  31',24 31,36 31:48  32:00  32', 12 32:34  32*36 32*48  33'tOO 33', 12 33:24  33:36 33:48
\r±lo*O980037 tl-385 Acq: 7-J3UT-1998 02:18:30 GC XH- Volt*g* SIT TVS Bairn*,996
,383.8639 T*3 BSU3(256,30, -3.0) PXD(7,S,3,0.10\f3984.0,1.00\,FrT)Sa^>sSSS5US
TSIASSLX LASS  Tax*:CLEANUP BLANK  TLH44376A
1003

  sol

  601

  401

  201

  ol
                                      A1.91X7
    31*00 31': 12  31*24 31:36 31*48 32*00  32*12  32*24  32:36 JE2i48 33iOQ 33', 12 33:24  33:36 33:48
Fila,U980037 tl-385 Acqs 7 -JAN- 19 9 8 02*18:30 SC XH- Voltmfo SIX 703 NO±ae*1409
385.8610 T:3 3SOB(256,30,-3.0) PKD(7r5,3,0.10\,5636.0,1.00\,r,X):
TSIANGLX LABS  Text : CLEANUP BLANK  XLX144376A
100$
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                                       A3.79E7
                                                     A4.18X7?
                                                                              A3.11X7
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 '119*0980037 tl-385 Acqt  7-JX1T-1998  02:18:30 GC XH- Voltago SIS. TOS
392.9760 f*3 XxpiNSBSUS
TSIANSLX LABS  Text:CLEANUP BLANK TLIt44376A
1004    31,07       31,31  31*44  31:58      32*18   32*34   JjJKig33j^gaj3:10^  ___Jt3_i*Lj£i*JL_.._.__
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rlJ.e:U980037 tl-385 Acqt 7-JAN-1998 02*18*30 GC XH- Voltage SXB! TOS
445.7555 T>3 Sxp,NDB5U3
'TSIANSLX LABS  TtxttCLEANUP BLANK  TXII44376A
1004
       31:04
                                         32*11
                                                    .-.-  	   !"""'!.. .,".""."   33'43
                                               32*23.
                                   42<00
                                                                                                     0.0X0
                                                                                                        TLM

                                                                     33,t05
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                                                                                                    \.a.9E6

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                                                                                                    .4.5X6

                                                                                                    .2.2X6
                                                                                                     0.0X0
                                                                                                        Tine
                                                                                                   ,.1.6X7

                                                                                                   ^.1.3X7

                                                                                                   -.9.6X6

                                                                                                   16.4X6

                                                                                                   \.3.2X6
                                                                                                    0.0X0
                                                                                                       Time
      ;0o 31:12
                             3l:48 32s    32*12 322432136
                                                                  33t ®8 " 33 1 12 ' 33:24' 33': 36 ' 33:48'
                                                                                                    6.0X3

                                                                                                   14.8X3
                                                                                                   t
                                                                                                   -.3.6X3

                                                                                                   .2.4X3

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                                                                                                     393

-------
 r3J.a,O98ooj7  il-385 Acq:  7-JAu-iyyo vjnauo ec sx+ voltage SIS 70S
 389.8156 r,3  3303(256,30,-3.0) PXD(7,S,3,0.10\,aa.O,1.00\,T,T) KxptHDBSUS
 TSIAHGLX LASS  TexttCLZAXUP BLAH*  TLH4437SA
          31:36    3l'i48   32', 00    32tl2   32', 24   32', 36    32', 4 8   33', 00    33', 12
rile,0980037 tl-385 Acqt  7-JJOT-1998 02,IS, 30 SC XH- Voltage SIS 70S Hoi fa, 24
391.8127  Ti3 BSU3(256,30,-3.0) PXD(7,5,3,0.10\r96.0,1.00\,r,T)  XxfiHDBSUS
TSIABGLX  LABS  TextiCLXAJTOP BLAST  TLH44376A
106
         33124   33 36  Time
                                                                                                -1.1X4
         31:36    31,48   32,00    32:12   32:24   32:36    32:48    33,00   33:12
rilai0980037 tl-385 Acq:  7-JAB-1998 02:18,30 SC XI+  Voltage SIR 70S Noise, 1401
401.8558 T:3 BSU3(256,30, -3. 0) PXD(7,5,3,0.10\,5604.0,1.00\,r,T)  XxpiSDBSUS
TRIABGLS LABS  Text,CLEANUP  BUOTK  TLH44376A
1001                                                                    A3.38X7
  80.

  eo:

  40.

  20.
                                                           A2.64E7
         31:36    31:48   32:00    32tl2   32:24   32:36   32t48    33:00   33:12
TilatU980037 tl-385 Acq: 7-JZ1T-1998  02il8t30 SC XI+  Voltage  SIS  70S Koine-.920
403.8529 Ts3 BSUB(256,30,-3.0) PXD(7,5,3,0.10%,3680.0,1.00\,T,T)  XxpsSDBSUS
TXIAB5ZS LABS  Text:CLEANUP BLANX XLH44376A
1003,                                                                    A3.78X7
         33:24
                 33:36
 80.

 60.

 40.

 20.
                                                          A2.19S7
         31,36   31,43    32,00   32,12    32,24   32,36   32,48    33,00
File,US80037 tl-385 Acq: 7-J3OT-1998 02:18,30 SC XI + Voltage SIS 70S
392.9760 r,3 XxptSDBSUS
TSIAHGLX LABS  Text:CLEANUP BLASK  TLH44376A
1001
 60.

 40.

 20.

  0.
33 i 12
                                                                           33ilO
        33i24    33
                                                                                        33:29
.0.0X0
36  T±me
                   -1. 6X7

                   .1.3X7

                   .9.6X6

                   .6.4X6

                   .3.2X6
         31,36   31:48    32iOO   32:12    32t24    32:36   32i48  ' '33>00  '  '33:12  ' '33i24
                    0.0X0
                       Time
                                                                                                      394

-------
 rila:a980037 #1-545 Acq:  7-JAJT-1998 02:18:30 SC XH- Voltage SIX 70S Hoitm:1180
 407.7818 T:4 3SUB(256,30,-3.0) PXD(7,5,3,0.10\,4720.0,1.00\rT,iy XxptXDBSOS
 tXIAOGLX LASS  Text:CLXANUP BLANK  TLH44376A
 1004 A1.06X5
                                                                                                       0X0
         35:00    35:12    35:24    35:36    35:49   36:00    36:12   36:24    36:36
 THa:O980037 #1-545 Acq:  7-JXH-1998 02:18:30 SC XH- Vbltagv SIX 70S Xoiaes939
 409.7789 T:4 SSUB(256,30, -3.0)  PKO(7,5,3,0.10\,3756.0,1.00\,T,T) ExptNDBSUS
 TXIANGLX LASS  Text: CLEANUP BLANK  XLH44376A
        A4.S4X4
                                                     36:48    37:00
        33:00    35:12    35:24    35:36    35:48    36:00   36:12    36:24    36:36
rdJ.etO9B0037 tl-545 Acq:  7-JAN-1998 02:18:30 GC XH- Voltaga SIS 70S Noia«:1594
417.8253 T:4 BSU3(256,30,-3.0) PXD(7,5,3,0.10\,6376.0,1.00\,T,T) Ezp:HDB5aS
TRIANGLE LABS  T*rt:CLEANUP BLANK  TLH44376A
1001    A1.20E7
                                                     36:48
                                                             37:00
        J5iOO    35-12    35:24   35:36   35:48    36:00   36:12    36:24    36:36
nie:0980037 tl-545 Acq:  7-JAB-1998 02:18:30 GC KC+ Voltngo SIX  70S Ho±Be:2911
419.3220 Ts4 BSUB(256,30,-3.0) PKD( 7,5, 3,0.10*, 11644 .0,1. 00\,r,T) Erp»JJDB5OS
TSIANGLE LASS  Text: CLEANUP BLANK  TLIf44376A
                                                     36:48
                                                             37:00
1001

  80:
           90I7
        35:00    35:12   35:24    35:36    35:48    36:00    36:12    36:24
r±le:OS80037 #1-545 Acq: 7-J3UT-1998  02:18:30 GC XH- Voltage SIX 70S
430.9729 T:4 XzptSDSSVS
TXIASGLS LASS  Tetxt:CLEANUP BLANK TLH44376A
                                            36:36   36:48    37:00
1001
 80:
 60:

 40:

 20:
                            35:27
        J5tOO    35:12   35:24    35:36    35:48    36:00    36:12    36:24
rile:U980037 #1-545 Acq: 7-JAN-1998  02:18:30 GC XH- Volttgt, SIX 70S
 79.7165 T:4 SxpiNDBSUS
TBXANGLX LASS  Taxt:CLEANUP BLANK  TLH44376A
                                                                             36:36
                                                                                      36:48
                                                             37:00
                                                                      time
 0X6

 4X6

 8X6

 2X6

 0X5

.0X0
  Time



 6X6

 3X6

 9X6

 6X6

 3X6

.0X0
  Time



,1X7

,7X6

.5X6

.3X6

.2X6

.0X0
  Time
        35:00
                35:12
                         35:24
35:36    35:48   36:00    36:12   36:24
                                                                             36:36
                                                                                      36:48
                                                                                               37:00
                                                                                                    395

-------
\rLLe,0980037 U-545 Aeq:  7-JUI-199B 02,13:JO &C SH- Voltage SIS 703 OoiaeilB	
423.7766 T:4 BSOf(256,30,-3.0)  tXD(7,5,3,0.10\,72.0,1.00\,T,T)  SxpilOaSOS
TSIAlfSLX LASS  Text« CtEUTOP BLAB*  XLH44376A
1001                                                                    A1.63X4
  80.

  SO.

  40.

  20.

   o:
                      Al.67X4
                                                         A3.54X4
A3.39X4
                            AS. 97X3
                          A/V
                                     A1.03X4
-1.2X4

'.9.3X3

.6.9X3

.4.6X3

.2.3X3

 0.0X0
      35,12  35t18 35,24 35:30  35,36 35,42  35,48 35,54 36,00  36,06 36,12  36,18 36,24  36,30
f±lf 10980037 tl-545 Acqi 7-J7OT-1998  02,18,30 GC XH- Voltage SIX  703 Soiaa:18
425.7737 Tt4 BSO3(256,30,-3.0) PXO(7,5,3,0.10\,72.0,1.00\,r,X) IxptNDBSUS
TSIAIKZX LASS Tmrt:CZZAllUP BLAST XLH44376A
1001             A1.09Z4                                                                       ..8.1X3
                                                                                            T±me
                                                                                                 0.0X0
                                                                                                   Time
      35,12  35:18  35,24 35:30  35,36 35,42  35:48 35:54 36,00  36:06 36,12  36:18  36:24  36:30
rile:U980037 tl-S4S Acq: 7-JAJT-1998  02:18:30 GC XI* Voltage SIS 70S Miiae:1656
435.8169 r:4 BSUB(256,30r-3.0) PXD(7,5,3,0.10\,6624.0,1.00\rr,X) Xxp:XDB5US
TSIANSU: LASS  Text:CLEANUP BLMIX TLH44376A
1001                                                       A1.?8E7                             ^4.2X6
 80.

 60.

 40.

 20.
Tila,0980037 tl-S4S Aoq: 7-JAN-1998 02:18:30 GC EH- Voltage SIX 70S Noiao:1648
437.8140 T:4 3SUB(2S6,30, -3.0) PKD(7,5,3, 0.10%, 6592.0,1.OQ\,T,T) Xzp:SDB5US
TRIANGLE LABS  Text:CLEANUP BLANK  TLH44376A
1001                                                       A1.92X7
 80.

 60.

 40.

 20.
                                                                                        '.3. 4X6

                                                                                        '.2.5X6

                                                                                        .1. 7X6

                                                                                        .8.4X5
                                                                                               -.4.1X6
      35:12 35:18  35:24  35:30  35:36 35:42 35:48  35:54 36:00
TiletU980037 tl-545 Aesjs 7-J7OT-1998  02:18:30 GC EI+ Voltage SIS 70S
430.9729 7:4 Xxp:NDB5US
XXIAHSLX LABS  Tax t: CLEANUP BLASK  TLH44376A
100*                  35^27
                                               5:49.
    ^  \^, m  Hi ii^                -  f	^^ 'f • 'N —
 80.


 60.
 40.

 20.

  0.
      35:12 35:18 35:24  35:30 35:36  35:42 35:48  35:54  36:66 36',06  36', 12 36tia' 36i24 36:30
                                                                                       -1.1X7

                                                                                        .8.5X6

                                                                                        '.6.4X6

                                                                                        .4.2X6

                                                                                        .2.1X6

                                                                                         0.0X0
                                                                                                      396

-------
 riJ.a:O980037  tl-545 Acq:  7-JMT-1998  02:18:30 SC XI+ Voltaga SIR 703 Hoia»:22
 441.7428 F;4  BSUB(256,30, -3.0) PXD(7,5,3,0.10\,88.0,1.00\rT,T) XzptSDBSOS
 TRUOOLX LASS  TextiCZZAWUP BLANK TLIt44376A
               35', 00         36100         37:00        38:00         39'tOO
rLLa, 09 80037 #1-545 Acqt 7-JUT-1998 03tl8i30 GC XI + Voltage SIX 70S SOim«:22
443.7399 f:4 BSO3(256,30,-3.0) ?XD(7,5,3,0.10\, 38.0,1.00\,r,T)  XzptKDBSVS
TBIANGLX LASS  Taxt-.CLZAXUP BLASX  XLIt44376A
1004
                                                                              401 00
                                                                          A4.93X4
      OBO
41 00  Time
               35,00        36'tOO         37100        38,00
r±letO980037 il-545 Acq: 7-JJOT-1998 02il8:30 GC EI+ Voltage SIX  70S
430.9729 T>4 XzptSDSSUS
TSIAKSLX LABS  TextsCLZAHOP BLAST  TLH44376A
                                                                39:00
                                                                             40:00
                                                                                           41 00 Time
1001
 90.
 ao.
 701
 601
 50J
 40.
 JOJ
 201
 10!
  0.
f^J+JfjtiZjtf^^
               351 00
                            36,00
                                          37,00
                                                       38100
                                                                    39100
                                                                                  40:00
  ,.1.1X7
     8X6
  .8.716
  [.7.6X6
  .6.5X6
  15.4X6
  .4.3X6
  .3.3X6
  .2.2X6
  11.1X6
   .0.0X0
41 00 lima
T±IatO980037 tl-545 Actji 7-J3UT-1998 03:18,30 GC XX* Voltage SIS 70S
 13.6775 Fi4 KxptlOfBSUS
TSIAHSLX LABS  TextiCLXAOUP BZAUX  TLH44376A
IOCS
                   35,18
                        35:42
                                  36,25
                                                               38,35
                                                    37:46
                                            37:11
                                                           38,19
                                     JUIA
              35  00
                            36:00
                                          37,00
                                                                          39:24
                                                                                  40:01
                                                                                            40:46
                                                                                             -1.4X4
                                                                                             .1.3X4
                                                                                             11.1X4
                                                                                             .9.8X3
                                                                                             .8.4X3
                                                                                             .7.0X3
                                                                                             .5.6X3
                                                                                             14.2X3
                                                                                             '-.2.8X3
                                                                                             .1.4X3
                                                       38:00
                                                                    39:00
                                                                                  40:00
                                                                                              0.0X0
                                                                                           41  00  Time
                                                                                                      397

-------
\rLLm,U9B0037  tl-StS Acq,  7-JAN-13SB 02:111,30 SC E1+ Voltage sIS 703 Jto.ua.Jg
437.7377 r>4  3303(356,30,-3.0) PKD(7,S,3,0.10\,80.0,1.0Q\,r,X) XrpiXDBSUS
TBIAHGZX LASS Tazt:CLEANUP BLANK  TLII44376A
100\                       AS. 33X4
  80.

  SO.
  40.
  30:
   o:
     V\
                                                                 A2.13X3
                           ^1.4X4

                            .1.3X4

                            .8.7X3

                           .5.8X3

                           .2.9X3
           39:30        39,36         39i42        39:48         39:54
FiJL»:U980037 tl-545 Aeq: 7-J2UT-1998 02:18,30 SC SI+ Voltag* SIS 703 Noise, 17
459.7348 Ti4 BSUB<256,30, -3.0) PXD(7,5,3,0.10*,68.0,1.00\,r,T) XxptSDBSUS
TSIAOSLX LASS  Taxt:CLZANUP SLASX  TLH44376A
100\              AS. 32X4
  80.
 .                       .
/\      AA  ^ A
                                                                              40:00
   .0.0X0
40:06  Tiae
  SO.
  40.
 20.
                                                         Al.04X4
                                                                                    AS. 88X3
                                                                        A1.35S3
           39:30        39i36         39:42        39:48         39tS4
rile>U980037 tl-545 Acq: 7-J3UT-1998 02:18,30 SC SI+ Voltage SIS 70S NoiaetlO
469.7779 Tt4 BSVB(256,30, -3.0) PKH(7,5,3,0.10\,80.0,1.00\,r,T) XxptXDBSUS
TRIANGLE LABS  Taxt:CLEANUP BLANK  TLIt44376A
1001                    A2.f4X7
 80.
 60.
 40.
 20.
           39:30         39:36         39:42        39:48         39': 54
T±le>a980037 tl-545 Acq: 7-JAN-199S 02:18:30 GC EI+ Voltage SXS 705 Hoiae-.lB
471.7750 Tt4 BSUB(2S6,30, -3.0) PXD(7,5,3,0.10\,72.0,1.00\rr,T) EzptHDBSUS
TBUUfGXJS LABS  Torts CLEANUP BLANK  TLIt44376A
100*                    A3.Q2X7
                                                                              40:00
           40:00
           39,30         39,36         39,42        39', 48         39', 54
Tlla:U980037 tl-545 Actjt 7-JAN-199S 02:18:30 GC XH- Voltaga SIX 70S
430.9729 r,4 XxptXDBSUS
TSIANGUS LABS  TaxttCLXANUP BLANK  TLIt44376A
100*     39129
           40:00
 80.

 60.

 40.

 20.

  0.
          39:30
                        39,36
                                      39:42
                                                   39:48
                                                                39:54
                                                                              40:00
                           _ 1. 7X4

                           '.1.4X4

                           .1. 0X4

                           .6.9X3

                           .3.4X3
                                                                                               .0.0X0
                                                                                            40 06 Tine
                         40 06
                           .0.0X0
                           06  T±me
                           -1.0X7

                           .8.1X6

                           .6. 0X6

                           .4.0X6

                           .2.0X6
                           .0.0X0
                        40 Off  T±me
                                                                                                   398

-------
Peak Locate Examination: 7-JAN-1998:02:17 File:U980037
      Experiment:NDB5US Function:2 Reference:PFK
                                                                                 CD
                                                                                 C7^
                                                                                 CO

-------
 ile:U980037 #1-545 Acq:  7-JAN-1998  02:18:30 CC EI + Voltage SIR 70S	
457.7377 F:4 Exp:NDB5US
 ample Text:CLEANUP BLANK  TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%.                                    A4.46E4
         38:48   39:00   39:12   39:24   39:36   39:48   40:00   40:12   40:24
 ile:U980037  #1-545 Acq:  7-JAN-1998  02:18:30 GC EI+ Voltage SIR 70S
459.7348 F:4  Exp:NDB5US
Sample Text:CLEANUP BLANK  TLI#44376A File Text:TRIANGLE LABORATORIES,  INC.
100%.
                                        A$.47E4
 60j
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                                                                               40:36
                                                        ^
         38:48   39:00   39:12   39:24   39:36   39:48   40:00   40:12   40:24
File:U980037  #1-545  Acq:  7-JAN-1998 02:18:30 GC EI + Voltage SIR 70S
469.7779 F:4  Exp:NDB5US
Sample Text:CLEANUP  BLANK  TLI844376A File Text:TRIANGLE LABORATORIES, INC.
100%,                                    39;36
  60
  40_
  20_
   0
                                                                            K^I
                                                                               40:36
         38:48   39:00   39:12   39:24   39:36   39:48
40:00
                                                                40:12   40:24   40:36
                                  1.4E4
                                  1.2E4
                                  8.7E3
                                  5.8E3
                                  2.9E3
                                  O.OEO
                                     Time
                                  .1.7E4
                                  .1.4E4
                                  .1. OE4
                                  .6.9E3
                                  .3.4E3
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                                     Time
.4.3E6
3.5E6
.2.6E6
.1.7E6
.8.7E5
.O.OEO
   Time

-------
CALIBRATION
      DATA
           Triangle Laboratories, Inc.
      801 Cap/tola Drive      P.O. Box 13485
      Durham, NC 27713-4411     Research Triangle Park, NC 2
      919-544-5729         Fax #919-544-5491

-------
                        TRIANGLE LABORATORIES OF RTF,  INC.
                      Initial Calibration Summary for PF22206
                                             Data:  02/20/96
  Analysis Date	:  02/20/96
  Instrument	:  P
                          Method	: C2NF
                          GC Column...: DB-225
  Analytes
  2378-TCDF
  TOTAL TCDF
  2378-TCDD
  TOTAL TCDD
 RF     SD   %RSD
1.040 0.109   10%
1.040 0.109   10%
0.992 0.101   10%
0.992 0.101   10%
  RT   RT/LO  RT/HI   Ratiol  RaCio2   N
21:32  14:31  25:31    0.767
                      0.767
20:12  16:11  24:11    0.782
                      0.782
10
10
10
10
  Other Standards
  37C1-TCDD
 RF     SD   %RSD  '    RT   RT/LO   RT/HI  Ratiol  Ratio2   N
1.014 0.048    5%    20:12  18:11   22:11                  10
  Internal Standards  RF     SD   %RSD      RT   RT/LO  RT/HI  Ratiol
  13C12-2378-TCDF    1.388 0.062    4%    21:31  20:31  22:31    0.753
  13C12-2378-TCDD    1.067 0.036    3%    20:11  18:11  22:11    0.786
                                                 Ratio2
                                      N
                                     10
                                     10
  Recovery Standards  RF     SD   %RSD
  13C12-1234-TCDD    1.000 0.000    0%
                       RT   RT/LO  RT/HI  Ratiol  Ratio2   N
                     20:27                0.794          10
  »»• End of Report »•*
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                              401
                                                               Printed: 23:10 02/20/96

-------
                            TRIANGLE LABORATORIES,  INC.
                       Initial Calibration Sumnary Cor UF51053
Dace:  01/07/98
Analysis Dace. . .
Instrument 	
Analytas
Total MCDF
Total MCDD
Total DCDF
Total OCDD
Total TriCDF
Total TriCDD
1368-TCDP
2378-TCDP
TOTAL TCDP
1368-TO3D
1379-TCDD
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDP
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HXCDF
123789-HxCDF
TOTAL HxCDP
123478-HxCDD
123678-HXCDD
123789-BxCOD
TOTAL HxCDD
1234678-HpCDF
1234789 -HpCDP
TOTAL HpCDP
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12 -HxCDP 478
13C12-HXCDF 234
13C12-HXCDF 789
13C12-HXCDD 478
13C12-HpCDF 789
• 01/05/98
• 0



RP SD
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
1.298 0.073
1.240 0.132
1.240 0.132
0.715 0.032
0.360 0.021
1.240 0.160
1.240 0.160
1.051 0.090
1.019 0.078
1.035 0.084
1.333 0.125
1.333 0.125
1.007 0.074
1.253 0.089
0.985 0.082
0.870 0.047
1.
0.
0.
0.
0.
1.
1.
1.
0.
0.
1.
1.
029
765
976
941
894
410
096
253
995
995
377
108
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RF
1.
0.
0.
001
966
325
0.902
0.
0.
0.
695
732
802
0.
0.
0.
0.
0.
0.
0.
071
051
079
068
064
098
071
084
051
051
070
080
SD
056
010
042
043
042
024
016

%RSD
100%
100*
100%
100%
100%
100%
6%
11%
11%
4%
6%
13%
13%
9%
8%
8%
9%
9%
7%
7%
8%
5%
7%
. 7%
8%
7%
7%
7%
6%
7%
5%
5%
5%
7%
%RSD
6%
1%
5%
5%
6%
3%
2%
Itathod. 	 •

RT
21:26
24:36
22:46
23:10
25:19
28:33
29:14
29:34
32:01
32:07
32:36
33:22

RT/LO
4:35
5:18
11:35
12:18
15:35
17:18
23:35
24:18
24:32
25:34
28:06
MTT2

RT/HI
13:35
19:18
19:35
20:18
22:35
23:18
30:35
31:18
32:32
33:34
36:06
Ratiol Ratio2.
0.745
0.743
0.744
0.776
0.786
0.787
0.781
1.526
1.530
1.528
1.580
1.580
1.283
1.245
1.262
1.263
1.262
32:43
32:47
33:06

35:00
36:31

36:01

39:47
39:35
RT
25:19
29:14
32:01
32:35
33:21
32:42
36:30
28:47



30:59


32:00

35:34
35:34
RT/LO
23:18
26:32




32:59
36:47



38:59


40:00

43:34
43:34
RT/HI
27:18
30:32




38:59
1
1
1
1
1
1
1
1
1
0
0
.257
.211
.234
.232
.060
..049
.055
.028
.028
.891
.836
Ratiol Ratio2

1
0
0
0
1
0

.498
.509
.508
.504
.214
.431
N
0
0
0
0
0
0
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
N
6
6
6
6
6
6
6
                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                Printed: 13:32 01/07/98
                                402

-------
                           TRIANGLE LABORATORIES,  INC.
                      Initial Calibration smanary for OF5105S
                                             Data: 01/07/9S
  Internal Standards
  13C12-2378-TOJF
  13C12-2378-TCDD
  13C12-PeCDP 123
  13C12-PeCDD 123
  13C12-BXCDF 678
  13C12-BXOJD 678
  13C12-HpCDP 678
  X3C12-HpCDO 678
  13C12-OCDO

  Recovery Standards
  13C12-1234-TCDD
  13C12-HXCDD 789
RF
1.
1.
1.
0.
1.
0.
0.
0.
0.
467
113
142
590
346
995
822
726
545
0.
0.
0.
0.
0.
0.
0.
0.
0.
so
053
049
075
045
038
017
013
Oil
038
%RSO
4%
4%
7%
8%
3%
2*
2%
2%
7*
RT
24:35
25:18
28:32
29:34
32:06
32:47
34:59
36:00
39:34
RT/LO
23:35
23:18
24:32
25:34
28:06
31:47
32:59
35:00
37:34
RT/HI
25:35
27:18
32:32
33:34
36:06
33:47
38:59
37:00
41:34
Ratiol Ratio2 N
0
0
.755
.807
1.478
1
0
1
0
1
0
.506
.506
.216
.434
.018
.361
6
6
6
6
6
6
6
6
S
 RF     SD
1.000 0.000
1.000 0.000
%RSD
  0%
  0%
  »** End o£ Report ***
  RT
25:08
33:05
RT/LO  RT/HI
Ratiol
 0.312
 1.210
Ratio2
N
6
6
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
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                                                              Printed: 13:32 01/07/98
                                                                             4u3

-------
  Date:  01/06/98        TRIANGLE LABORATORIES OF RTF,  ISC.
                         Continuing Calibration for P980092
  Analysis Date	:  01/06/98                  Method	:  C2NF
              	:  BB
Operator	
Init Calibration.:  PF22206
ICal Date	:  02/20/96
Analysis Time	:  22:08
    Instrument..:  P
    Std.Conc	:        5.00

    GC Column...:  db-225
  Analyte Summary
  Name

  2378-TCDF

  TOTAL TCDF

  2378-TCDD

  TOTAL TCDD
                   RF   Ratio
                                  RT
             ICal   Delta
RT   Rel.  RT  RF      RF     %D
                         162    Lo/High
                  0.390  0.68    18:18  23:06 1.0000   1.040 -0.150 -14.4%
                                 25:26
                  0.890  0.68                          1.040 -0.150 -14.4*

                  0.895  0.81    19:07  21:381.0000   0.992-0.097  -9.8%
                                 24:40
                  0.395  0.81                          0.992 -0.097  -9.8%
 Other Standard Summary
 Name                RF    Ratio
                           1&2
 37C1-TCDD         0.912
                                                      ICal   Delta
                                  RT     RT   Rel.  RT  RF      RF    %D
                                Lo/High
                                 19:38  21:38 1.0000   1.014  -0.102  -10.1%
                                 23:38
 Internal Standard Summary
 Name               RF    Ratio
                          IS 2
 13C12-2378-TCDF   1.080  0.77

 13C12-2378-TCDD   1.081  0.76
                                                      ICal    Delta
                                  RT     RT   Rel.  RT  RF      RF     %D
                                Lo/High
                                 22:06  23:06 1.0000   1.388  -0.308  -22.2%
                                 24:06
                                 19:38  21:38 1.0000   1.067   0.014    1.3%
                                 23:38
 Recovery Standard Summary
 Name               RF   Ratio
                          1&2
 13C12-1234-TCDD   1.000  0.78
                                                      ICal   Delta
                                  RT     RT   Rel.  RT  RF      RF     %D
                                Lo/High
                                        21:56 1.0139   1.000  0.000   0.0%
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
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Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                   Printed: 22:49 01/06/98
                                                                                                   404

-------
  Dace:  01/11/98
TRIANGLE LABORATORIES  OF  RTF. INC.
 Continuing Calibration £or 098002S
Operator 	
TfS T. f f*J% 1 1 V^T"S> (* T <•
±£1J* U WAX^0^CLUJ.t
ICal Data 	
..: w i./ v ' / ?o
• MC
*n . TTR5 1 058
til, , \Jff JiVJO
• 01/05/98
Analyce Summary
Name RF

Tocal MCDF

Total MCDD

Total DCDF

Total DCDD

Total TriCDF

Tocal TriCDD

1368-TCDF

2378-TCDF
TOTAL TCDF
1363-TCDD

1379-TCDD
2378-TCDD
J^OTAL TCDD
K2378-PeCDF

23478-PeCDF
TOTAL PeCDF
12378-PeCDD

TOTAL PeCDD
1234-78-HxCDF

123678-HxCDF
234678-HXCDF
123789-HxCDF

0.

0.

0.

0.

0.

0.

1.

1.
1.
0.

0.
1.
1.
1.

1.
1.
1.

1.
1.

1.

,000

000

000

000

000

000

171

197
197
631

337
151
151
006

025
015
419

419
048

244
1.056
0.
975
Ratio
142












0.75

0.75
0.75
0.77

0.77
0.80
0.78
1.51

1.52
1.52
1.59

1.59
1.25

1.25
1.26
1.25
Ins trunenc .
Std.Coac

RT RT Rel. RT
.: U
4> +.&



. . . • 10.00


ICal
RF


Delta
RF


%D
Lo/High
4:
18
5:
19
11
19
12
20
15
22
17
23
21
26


22
26



26
30


27
30

30
33



36
:36
20
:20
:36
:36
:20
:20
:36
:36
:20
:20
:20 21:28 0.3726
:33
24:38 1.0014

:40 22:48 0.9000
:31
23:11 0.9151
25:20 1.0000

:25 28:34 1.0006
:25
29:16 1.0251

:40 29:36 1.0000
:15

:55 32:03 0.9974
:38
32:08 1.0000
32:37 1.0150
33:23 1.0389 •
0.000

0.

0.

0.

0.

0.

1.

1.
1.
0.

0.
1.
1.
1.

1.
1.
1.

1.
1.

1.
0.
0.

.000

.000

,000

000

000

298

240
240
715

360
240
240
051

019
035
333

333
007

253
985
870
0.000

0.

0.

0.

0.

0.

-0.

-0.
-0.
-0.

-0.
-0.
-0.

,000

,000

000

000

000

127

043
043
084

023
089
089
-0.045

0.
-0.
0.

0.
0.

-0.
0.

006
020
086

086
041

009
071
0.105
100

100

100

100

100

100

-9

-3
-3
-11

-6
-7
-7
-4

0
-1
.0%

.0%

.0%

.0%

.0%

.0%

.8%

.5%
.5%
.3%

.5%
.2%
.2%
.3%

.6%
.9%
6.4%


6.4%
4.1%


-0.7%
7.2%
12.1%
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                           Printed: 13:0501/11/98
                                                                             405

-------
Dace: 01/11/98
TRIANGLE
LABORATORIES OF RTP, INC.
Continuing Calibration
TOTAL HxCDF
123478-HxCDD

123678-HxCDD
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF

1234789-HpCDF
TOTAL HpCDF
1234678-HpOJD

TOTAL HpCDD
OCDF

OCDD

Other Standard
Name
1.081
0.771

0.943
0.941
0.385
1.401

1.155
1.278
0.994

0.994
1.307

1.077

Summary
RF
1,
1,

1.
1.
1.
1.

1.
1.
1.

1.
0.

0.


.25
.32

,17
,23
,23
,06

,04
.05
04

04
90

35


Ratio
1&2
37C1-TCDD

13C12-PeCDF 234

13C12-HXCDF 478
13C12-HXO3F 234
13C12 -HxCDF 789
13C12-HXCDD 478
13C12 -HpCDF 789

1.047

1.002

0.883
0.979
0.782
0.751
0.845



1.

0.
0.
0.
1.
0.



51

50
50
50
21
43


31:25
33:15



34:51
36:43


35:08
36:13

35:36
43:36
35:36
43:36

RT
Lo/High
23:20
27:20
24:33
- 32:33




33:00
39:00

32:44

32:49
33:08

35:01

36:32

36:03


39:49

39:37


RT

25:20

29:15

32:02
32:37
33:23
32:43
36:32

£or 0980025

0.9980

1.0005
1.0102

1.0005

1.0438

1.0005


1.0055

1.0004


Rel. RT

1.0000

1. 0245

0.9969
1.0150
1.0389
0.9975
1.0438

Internal Standard Summary
Name
RF
Ratio
1&2
13C12-2378-TCDF

13C12-2378-TCDD

13C12-PeCDF 123


1.444

1.113

1.223


0.

0.

1.


74

30

48


RT
Lo/High
23:36
25:36
23:20
27:20
24:33
32:33
Page 2
RT

24:36

25:20

28:33


Rel. RT

1.0000

1.0000

1.0000


1.029
0.765

0.976
0.941
0.894
1.410

1.096
1.253
0.995

0.995
1.377

1.108

ICal
RF

1.001

0.966

0.825
0.902
0.695
0.732
0.802

ICal
RF

1.467
-
1.118

1.142


0
0

-0
0
-0
-0

0
0
-0

-0
-0

-0

.052
.006

.033
.000
.009
.009

.059
.025
.001

.001
.070

.031

5
0

-3
0
-1
-0.

5.
2.
-0.

-0.
-5.

-2.

.1%
.7%

.4%
.0%
.0%
.6%

.4%
.0%
1%

,1%
1%

3%

Delta
RF

0.

0.

0.
0.
. 0.
0.
0.


.046

.036

,058
,077
,087
019
043

%D

4.

3.

7.
8.
12.
2.
5.



5%

7%

1%
6%
5%
6%
3%

Delta
RF

-0.

-0.

0.



023

005

081


%D

-1.

-0.

7.




5%

4%

1%


Triangle Laboratories, Inc.®  Analytical Services Division
801 CapHola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:05 01/11/98
               406

-------
  Dace: 01/11/98

  13C12-PeCDD 123

  13C12-HXCDF 678

  13C12-HXCDD 678

  13C12-H&CDF 678

  13C12-HpCDD 678

  13C12-OCDD


  Recovery Standard
  Name

  13C12-1234-TCDD

  13C12-HXCDD 789
    TRIANGLE LABORATORIES OF RTF, INC.
     Continuing Calibration for U980025
0.592  1.46    25:36  29:36 1.0000   0.590  0.002   0.4%
               33:36
1.212  0.50    28:08  32:08 1.0000   1.346 -0.134  -9.9%
               36:08
0.972  1.21    31:48  32:48 1.0000   0.995 -0.023  -2.4%
               33:48
0.871  0.43    33:00  35:00 1.0000   0.822  0.049   6.0%
               39:00
0.776  1.02    35:02  36:02 1.0000   0.726  0.050   6.9%
               37:02
0.637  0.36    39:26  39:36 1.0000   0.545  0.092  16.9%
               39:46
Summary                             ICal   Delta
 RF   Ratio     RT     RT   Rel. RT  RF      RF
       142    Lo/High
                                     1.000  0.000
1.000  0.81

1.000  1.20
25:09 0.9928

33:07 1.0097
              %0

               0.0%

1.000  0.000   0.0%
                        QC Front End Check:
                            1.0515
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 13:0501/1

-------
                             CASE NARRATIVE
                      Analysis of Samples for the Presence of

             Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by

      High-Resolution Chromatography / High-Resolution Mass Spectrometry
                                Method 23 (6/93)
             Date:
             Client ID:
             P.O. Number:
             TLI Project Number:
January 15, 1998


Eastern Research Group




44376
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 11/19/97
                                             Triangle Laboratories, Inc.
                                  801 Cap/to/a Drive             P.O. Box 13485
                                  Durham, NC 27713-4411         Research Triangle Park, NC 27709-3485
                                  919-544-5729                 Fax #919-544-5491
                                                                           1     1

-------
 Triangle Laboratories, Inc.                                               January 15, 1998
 Case Narrative                                                                 44376
 Overview

 The samples and associated QC samples were extracted and analyzed according to
 procedures described in Method 23 (6/93). Any particular difficulties encountered during
 the sample handling by Triangle Laboratories will be discussed in the QC Remarks section
 below. This report contains results only from the Method 23 dioxin/furan analysis of nine
 M23 samples.
Quality Control Samples

A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples.

Quality Control Remarks

This release of this particular set of Eastern Research Group analytical data by Triangle
Laboratories was authorized by the Quality Control Chemist who has reviewed each
sample data package following a series of inspections/reviews. When applicable, general
deviations from acceptable QC requirements are identified below and comments are made
on the effect of these deviations upon the validity and reliability of the results. Specific QC
issues associated with this particular project are:

Sample receipt:  Nineteen M23 trains were received from Eastern Research Group in
good condition on December 17, 1997 at ambient temperature and stored in a refrigerator
at 4 °C.

Sample Preparation Laboratory:   Samples 109-112, 113-116, 117-120/216/217/218,
121-124/219, 129-132,  133-136, and 137-140 were processed through additional cleanup
due to a yellow residue  present after concentration.  A cleanup blank, identified as the
CleanUp Blk, was prepared along with the samples.

Mass Spectrometry: None

Data Review:   The analyses of samples 105-108,  109-112,113-116, 121-124/219,
117-120/216/217/218, and 125-128 exhibit the presence of saturated analyte signals
(signals outside the dynamic range of  the instrument). The affected analytes are flagged
"S" on the quantitation  report. The results for these analytes are reported as greater than
the upper calibration limit for that analyte, and should be considered a minimum estimate
of the actual concentration present in the sample.

-------
Triangle Laboratories, Inc.                                                January 15, 1998
Case Narrative                                                                  44376
Other Comments: No 2,3,7,8-substituted target analytes were detected in the TLI Blank
above the target detection limit (TDL).

The analytical data presented in this report are consistent with the guidelines of EPA
Method 23 (6/93). Any exceptions have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Eastern Research
Group have any questions or comments regarding this data package, please feel free to
contact our Project Scientist, Amy J. Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Released by
          Vl'/
Stuart Jefferys
Report Preparation Chemist
The total number of pages in the data package is

-------
                     TRIANGLE LABORATORIES, INC.

                 LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American Association for Laboratory  Accreditation. Accredidation  pending.   Certificate
Number 0226-01.  Accreditation for technical competence in Environmental Testing.(lnc!uding
Waste Water, Sol/Haz Waste,  Pulp/Paper, and Air Matrices) Parameters are AOX/TOX,  and
Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of Environmental Management  Expires December 31, 1S98.
Laboratory I.D. #40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation. Expires  December 21, 19S8.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate 2AZ0423.
Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology. Expires February 18, 1998.
Pulp/paper, soil,  water, and Hazardous Waste for Dioxin/Furan; AOX/TOX, Volatiles,  Semi-
volatiies, and Metals.

State of  California,  Department of Health Services.  Expires August 31,  1999.  Certificate
#1922. Selected Metals in  Waste Water Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut Department of  Health Services.   Expires September  30,  1999.
Registration # PH-0117. Dioxin in drinking water.

Delaware Health and Social Services. Expires December 31,1998. Certificate #NC 140. Dioxin
in drinking water.

Florida Department of Health  and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424.  Metals,  Extractabie Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS# ES7411.
Revised 1/6/98 RM                                  Triangle Laboratories, Inc.                  A
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                                   Durham, NC 27773-4477         Research Triangle Park, NC 27709-3485
                                   919-544-5729                Fax #919-544-5491

-------
Hawaii Department of Health.  Expires  March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .

Idaho Department of Health  and Welfare.  Expires December 31, 1998. Dioxin in  drinking
water.

State of Kansas,  Department of Health  and Environment  Expires January 31. 1998.
Environmental Analyses/Non portable Water and Solid and Hazardous Waste.  Method 1613 for
drinking water. ID #s - Drinking  water and/or pollution control - E-215. Solid or Hazardous Waste -
E-1209.

Commonwealth of Kentucky,  Department for Environmental Protection. Expires
December 31, 1998. ID#90060. Dioxin in drinking water.

Maryland Department of Health and  Mental  Hygiene.   Expires September 30,  1998.
Certification #235.  Drinking water by Method 1613A.

State of Michigan,  Department of Public  Health.  Expires June  3, 1998.  Drinking water by
Method 1613.

Mississippi State Department of Health.  No expiration date.  Dioxin in drinking water.

Montana Department of Health and  Environmental Services.  Expires December 31, 1998.
Dioxin in drinking water.

State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
1998. ID #87851. BNAs and Volatiles.  Dioxin in drinking water.

State of New Mexico, Environment Department  Recertification  pending. Dioxin in  drinking
water.

New  York State  Department of Health.  Expires April 1,  1998.  ID  #11026.  Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.

State of North Carolina, Department of Environment Health and Natural Resources  Expires
August 31,1999. Certificate # 37751. Dioxin in drinking water.

State of North Carolina, Department of Environment, Health, and Natural  Resources,
Division of Environmental Management   Expires  December 31, 2000.  Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiies; TCLP.

North Dakota  State Department  of Health  and  Consolidated Laboratories.    Expires
December 31, 1998. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 1/6/93 RM
y:certific\certlist.mem

-------
Oklahoma Department of Environmental Quality.  Expires August 31,1998. Laboratory #9612.
Dioxin by 1613A, 8290 and 8280.

State of South Carolina, Department of Health and Environmental Control. Expires
April 1, 1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA,  Volatiles, and  PCBs/pesticides
under Clean Water Act,  2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid and
Hazardous Waste.

State of Tennessee. Department of Environment and Conservation. Expires
February 5, 1999. ID #02992.  Method 1613 Drinking water only.
                                                          *
U.S. Department of Agriculture  Soil Permit  Expires Septembe'r 30, 2001. Permit No. S-3790.
Under the authority of the Federal Plant Pest Act, permission is granted to receive foreign soil
samples for use in laboratory analysis.

U.S. Army Corps of Engineers.  Recertificaticn Pending. Validated to perform methods
8280 & 82SO for Lockboume Landfill  Site Investigation. Defense Distribution Depot  Projects, and
assarted projects for the USAGE North Pacific Division Laboratory.

U.S. EPA Region V. Expires November 14, 19S9. Dioxin in drinking water.

U.S. EPA Region  VIII, for the  State of Wyoming.  Expires November 12, 1998.  Dioxin  in
drinking water.

State of Utah, Department of Health.  Expires December 31, 1S98, Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiies under  RCRA; Volatiles
under Clean Water Act Dioxin/furans by Method 8280; Drinking water for Dioxin by Method 1613;
Metals including Mercury and Microwave Digestion.

Commonwealth of Virginia,  Department of General  Services,  Division of Consolidated
Laboratory Services.  Expires June 30, 1998. ID # 00341. Dioxin in drinking water.

State of Washington, Department of Ecology. Expires  September 11, 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for  Polychlorinated Dibenzo-p-
dioxins and Polychlorinated Dibenzofurans,  BNA Extr (Semivolatile) Organics and  Purgeable
(Volatile) Organics.

State of Washington,  Department of Health.  Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129

State of West  Virginia, Department of Health.  Expires  December 31, 1998. Certificate No.
9923(C).  Dioxin in drinking water.
Revised 1/6/93 RM
y:certific\certlist.mem

-------
State of Wisconsin, Department of Natural Resources.  Expires August 31, 1998. Laboratory
ID Number  999869530. Certification for the following  categories  of Organics: Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin.  Expires November 14,  1999. Laboratory ID 999869530.
Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement  Agency (DEA).   Expires  November 30, 1998.  Registration  number
RT01195335. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources.  Expires October 31, 1998.  Registration number
NC-PT 0000 0031. North Carolina controlled substances  registration. Application submitted for
renewal.

Food & Drug Administration (FDA) Registration. Expires June 1998. ID #3 001500  1053481.
Annual registration of drug establishment. Annual registration of drug establishment.

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration.  Expires May 30, 1999.
ID # 34D0705123.   Department  of Health &  Human Services, Health   Care  Financing
Administration.

U.S. EPA Large Quantity Hazardous Waste Generator.    No  expiration  date.   EPA  ID
#NCD982156379. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina General License for Radiation Protection.  No. expiration date. License No.
032-375-OG. The general license applies only to radioactive material contained  in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 1/6/98 RM
y:certific\certiist.mem

-------
DOCUMENT
  CONTROL
          Triangle Laboratories, Inc.
    801 Capitola Drive       P.O. Box 13485
    Durham, NC 27713-4411     Research Triangle Park, NC 27709-3485
    919-544-5729         Fax # 919-544-5491  Q

-------
                                                           Eastern Research Group  COG
Gulp Aluminum Alloys
CHAIN OF
CUSTODY
/
/^ A
A
RELINQUISHED BY = ^V/^rtLT Cx6u3^<-^j2_ DATE =
RELINQUISHED BY = '



[SAMPLE m|
CAA-105
CAA-106
CAA-107
CAA-108
CAA-109
CAA-110
CAA-111
CAA-112
CAA-113
CAA-1M
CAA-115
CAA-116
_^
CAA-117
CAA-11B
CAA-119
CAA-120
CAA-121
CAA-122
CAA-123
CAA-12-1
^f
CAA-125
CAA-126
CAA-127
CAA-128
CAA-129
CAA-130
CAA-131
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
I
CAA-
CAA-
CAA-,
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120597 M23-
120597 M23-
120597 M23-
120597 M23-
120697 M23-
120697 M23-
120697 M23-
120697 M23-
120797 M23-
120797 M23-
120797 M23:
120797 M23-
120597 M23-
120597 M23-
120597 M23-
120597 M23-
120697 M23-
120697 M23-
120697 M23-
120697 M23-
120797 M23-
120797 M23-
120797 M23-
120797 M23-
120897 M23-
120897 M23-
120897 M23-

FIELD ID
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
rtFI-OUT-
RF1-OUT-
RF1-OUT-
DATE =


FILTER 1
PR 1
PRT/CRT 1
XAD 1
FILTER 2
PR 2
PRT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CUT 3
XAD 3
FILTER 1
Pp 1
PRT/CRT 1
XAD 1
FILTER 2
PR 2
PRT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 1
PR 1
PRT/CRT 1
/^ ^h^
•

SAMPLE TYPE
METHOD 23. CDBOUT, RUN 1
METHOD 23. CDBOUT. RUN 1
METHOD 23, CDBOUT. RUN 1
METHOD 23. CDBOUT. RUN 1
METHOD 23. CDBOUT. RUN 2
METHOD 23. CDBOUT. RUN 2
METHOD 23, CDBOUT. RUN 2
METHOD 23. CDBOUT. RUN 2
METHOD 23. CDBOUT, RUN 3
METHOD 23. CDBOUT, RUN 3
METHOD 23. COBOUT. RUN 3
METHOD 23. CDBOUT. RUN 3
METHOD 23, CDBIN, RUN 1
M23, CDBIN. RUN 1 (Bollle 1 ol 2)
METHOD 23. CDBIN. RUN 1
METHOD 23, CDBIN, RUN 1
METHOD 23, CDBIN. RUN 2
METHOD 23. CDBIN, RUN 2
METHOD 23. CDBIN. RUN 2
METHOD 23, CDUIN, RUN 2
METHOD 23, CDBIN, RUN 3
MET HOD 23. CDBIN, RUNS
METHOD 23. CDBIN, RUN 3
METHOD 23. CDBIN. RUN 3
METHOD 23. RF1-OUT. RUN 1
METHOD 23. RF1-OUT. RUN 1
METHOD 23. RF1-OUT. RUN 1
RECEIVED BY: ^"c^V,
RECEIVED BY: S^

\ PRESERVATIVE
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
X-XADTRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
X XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
X'XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XXAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XXAU TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
.e^AD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
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S^ DATE: '

COMMENTS | ANALYSIS |
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN 1 FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN /FURAH
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN

-------
Eastern Research Group  . COG
                                                                                        O
CAA-132
CM-t33
CAA-134
CAA-135
CAA-136
CAA-137
CAA-138
CAA-139
CAA-140
CAA-141
CAA-142
CAA-143
CAA-144
~CAA-153
CAA-154
CAA-155
CAA-156
rcAA-157
CAA-158
CAA-159
CAA-160
CAA-161
CAA-1G2
CAA-163
CAA-1G4
CAA-165
CAA-166
CAA-167
CAA-168
CAA-177
CAA-178
CAA-179
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
, CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
120997 M23-
120997 M23-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
121197 M23-
121197 M23-
120797 M23-
121597 M23-
121597 M23-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RFt-IN-
RF1-IN-
RF2-IN-
RF1-IN-
RF2-IN-
RF2-IN-
RBLK1
RBLK2
RBLK2
XAO 1
FILTER 2
PR 2
PRT/CRT 2
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FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 4
PR 4
PRT/CRT 4
XAD 4
FILTER 1
PR 1
PRT/CRT 1
XAD 1
FILTER 2
PR 2
PrtT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 4
PR 2
PRT/CRT 4
XAD 4
FILTER 1
PR 2
PRT/CRT 2
METHOD 23. RF1-OUT. RUN 1
METHOD 23, RF1-OUT, RUN 2
METHOD 23, RF1-OUT, RUN 2
METHOD 23. RF1-OUT. RUN 2
MET HOD 23, RF1-OUT. RUN 2
METHOD 23. RF1-C:, .'. RUN 3
METHOD 23, RF1-OUT. RUN 3
METHOD 23. RF1-OUT, RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF2-OUT. RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23, RF2-OUT, RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23. RF1-IN, RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23, RF1-IN. RUN 1
METHOD 23, RF1-IN, RUN 2
M 23, DPI IN. RUN 7 (Bollle t of 2)
METHOD 23, RF1-IN, RUN 2 ^
METHOD 23, RF1-IN, RUN 2 \
METHOD 23, RF1-IN. RUN 3
METHOD 23. RF1-IN, RUN 3
METHOD 23, RFMN. RUN 3
METHOD 23, RF1-IN, RUN 3
METHOD 23. RF2-IN. RUN 4 /
f^MT3. nr 1 IN. RUN ?|E)ottle 1 of t)J
METHOD 23. RF2-IN. RUN 4
METHOD 23. RF2-IN. RUN 4
METHOD 23. REAGENT BLANK
METHOD 23. REAGENT BLANK
METHOD 23, REAGENT BLANK
                      XXAD TRAP
                        FILTER
                        ACETONE/MECL RINSE
                        TOLUENE RINSE
                        FILTER
                        ACETONE/MECL RINSE
                        TOLUENE RINSE
                      ffVJ^O TRAP
                        FILTER
                        ACETONE/MECL RINSE
                        TOLUENE RINSE
                        FILTER
                        ACETONE/MECL RINSE
                        TOLUENE RINSE
                      fXAO TRAP
                        FILTER
                        ACETONE/MECL RINSE(1of2)
                        TOLUENE RINSE
                      yXAD TRAP
                        FILTER
                        ACETONE/MECL RINSE
                        TOLUENE RINSE
                      XXAD TRAP
                        FILTER
                        ACETONE/MECL RINSE(2 of 2)
                        TOLUENE RINSE
                        XAD TRAP
                        FILTER
                        ACETONE
                        TOLUENE
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN I FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN /FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN/FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
             Page 2

-------
Eastern Research Group  COC
CAA-180
CAA-181
CAA-1B2
CAA-183
CAA-16-1
""^•••M

-------
                                                                    Eastern Research Group  COG


CAA-218    CAA-      120597 M23-    CDBIN       PR      1      M23 CUDIN RUN 1 (PR 2 OF 2)       ACETONE/MECL RINSE                          DIOXIN / FURAN
CAA-219    CAA-      120697 M23-    COBIN       FIL1F.R   2      M23 CDIJIN RUN 2 (FILTER 2 OF 2)    FILTER                                       DIOXIN / FURAN
CAA-225    CAA-      121197 M23-    RF1 IN       PR      4      Motliod23 RF1 INLET RUN 4          ACETONE/MECL RINSE                          DIOXIN / FURAN
CAA-226    CAA-      121597 M23-    REAGENT BL   MeCL   2      M23 REAGENT BLANK 2 (MeCL)      REAGENT BLANK (MeCL)                         DIOXIN / FURAN
                                                                                 Page 4

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H CAA-178 C02 . A
n i
B194-59-15C CAA-179 TOLUENE]
(I CAA-179 C02 ^^
(194-59-15D :' CAA-1BO -^_XAD|
I) CAA-1BO C02 '^'\
n
II 1
||l94-S9-i6A CAA-181 FILTER)
(I CAA-181 C02 ^\
1 1
||194-S9-16B CAA-182 ACETONE)
|| CAA-182 C02 _/j
n ' 1
n
Inlt
^


1


II . 1
0194-59-16C , CAA-183 TOLUENp) 1
I) i : CAA-1B3 C02 -^ | 1
1
(194-59-16D CAA-184 XAD|
|| CAA-184 C02 JS^ \S\
n
II II
J194-59-17A CAA-193 FILTER]
|| CAA-193 C02 ^ 1
n I
II 1
fll94-S9-17B CAA-194 ACE/MECL2 RINSE]
fl : CAA-194 C02 j 1
n I
II 1 I
||l94-59-17C . CAA-195 TOLUENE)
II , CAA-195 C02 ,_[/
n I
J194-59-17D CAA-196 ?\XAD|
|| CAA-196 C02 .J. 1
ni 1
	 	 • • 1 1
fll94-59-18A CAA-198 ACE/MECL2 RINSE] 1 ,
|| CAA-19B C02 ^//\ \
»' ' i V
TO STORAGE]
Date/Init
W>
C5B



.11




ospp






05>p


1
OSiTO
To I, An
DateAlnit.
^c












1 Xh J vx 'J \
1)194-59-188 CAA-199 TOLUENE] Vj/ V '"A 1 VO -w,
-------
                                                  =TRIANGLE LABORATORIES, INC. --
                                                                                      'IN RECORD/CHAIN OF CUSTODY^
| Custody Sea. : Ab«tnt Sample Seals: Absent
1 Chain of Custody : Present Container...: Intact
I) Sample Tags i Absent
U Sample Tag Numbers: Not Listed on Chain of Custody
0 SMO Forma • N/A
n
R
U Ice Chest NO COOLANT
IJTLI Number 	 Client Sample ID Matrix) To t
||mR/H;CPH. 	 Client COC ID 	 * Location | Date
0 1
fll94-59-19A CAA-201 FILTER) p^7
Q CAA-201 C02 . | >"*
n l/ 1
II 1 •
|194-S9-19B CAA-202 ACE/MECL2 RINSE) .
0 CAA-202 C02 , X
n i
II 1
H194-59-19C CAA-203 TOLUENE)
\ CAA-203 C02 ^\
R\
. 1
(194-59-19D '• CAA-204 \-XAD| .•
D CAA-204 C02 X V
RM^
1
||194-S9-20A CAA-205 FILTER)
|1 CAA-205 C02 ^\'
n i
II 1
|)194-S9-20B CAA-208 ^. XAD)
0 CAA-20B . C02 J*^\,-''l
1
1)194-59-21 CAA-209 REAGENT BLANK MECL2 1
||' : CAA-209 C02 If
n
II 1
||194-S9-22A CAA-216 FILTER)
I) , CAA-216 ' C02 «^f
Bi
An
/Init
?.-o







1 •
H194-S9-22B CAA-217 FILTER)
1) CAA-217 C02 . V 1
B, vi 1
	 	 II
fll94-59-22C CAA-218 ACE/MECL2 RINSE) .- 1
I) CAA-218 . C02 •'j 1
n I
II— II
1)194-59-23 CAA-219 FILTER)
|| CAA-218 • C02 L-^^ 1
n l I
II 	 - - 1 I
1)194-59-24 CAA-22S ACE/MECL2 RINSEl/ 1
|| CAA-225 C02 T/f 1 ;
n I 1 /
II ;• 1 J, I/
1)194-59-25 CAA-226 REAGENT BLANK MECL2 \JgO ^^
g CAA-226 C02 UXVYV'''
n •
II 1
B 1
B 1
TO STORAGE) TO LAB
Date/Init | Date/Init
^





osg


\%&

l*)c \


/



/







h
\w
i
/











TO STORAGE)
Date/Init




"







,

To LAB
Date/Init












'
i
To STORAGE |
Date/Inlt














DISPOSED
Date/Inlt
11
n
n
n
n
n

0
B
n
(1
n
I
n
n
B
B
n
fl
n
B
n
B
B
	 B
fl
B
- n
n
1 a
Receiving Remarks:   NO COOLANT.   CAA-206 AND I.-AA207 ARE NOT PRESENT.
            I
Archive Remarks:
                                                               =Form Revised  05/27/1997  --  Page  6 OF  6=

-------
                       TRIANGLE LABORATORIES,  INC.
               SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
TLI Proj#:
Prod Code :
DetectLim:
44376-
D23061
. 0 5 ng
	 ^Uri-HN AJ -LJ
Samples :
Matrix. :
Type . . . :
Recvd. . :
rwi-i A vc. XIN.
9
M23Train
A
12/17/97
                                             TurnAround.:  21 Day(s)
                                             Hold Time..:  30 Day(s)
                                             Start Date.:  12/17/97
                                             Ship By....:  01/05/98
                                             DWL Due Dt.:  12/24/97

 Analyte  List.:  Method 23:T-0 (Toluene combined

 Method	:  Method 23:Tetra-Octa (Tol Combined)
 Client Proj..:  Culp  Aluminum Alloys
 Client	:  Eastern Research Group (ERG02)
 P.O.  No	:  Signed OA                     Collect Dt/Tm:  SeeCOC
 Contact	:  Jim McGaughey                Phone	:  919/461-1209
 Proj . Mgr. . . . :  Amy J.  Boehm                 Fax	:  919/461-1579
                                             Sample Origin:  NC
                 -SPECIAL  INSTRUCTIONS / QA REQUIREMENTS	
                                         Prespike  Standard:  USD-C,  USD-S
                                         Prespike  Amount..:  4.Ong
	REPORTING REQUIREMENTS•
 Reporting  Format:  Report Option  II

 See MILES  for  Instructions/Communications.
 Completed by:

 Reviewed by:
DATE:

DATE:
(PMGT0197)
                                                                             v
                                                                             V

-------
                     PROJECTCOMMUNICATJON TRACKING FORM
page	of.	
                            Project Number:
Use this form' to record ai! exchanges of information between production units as well as personnel
.handling this project. Decisions, corrective actions and recommendations must also appear on this
                                  tracking .document.
          Comment / Decision / Resolution / Action / Observation


                 Pflt&ctf
            Triangle Laboratories,  Inc
            TLI PP'.DJECT* 04047
               £._ 11/25/97  TLI BLANK
            CSPIKE 4.0ng USF-C USF-S
             PREPARER G.L.
                     EASTERN RES.GRP.

-------
           ELS01-Eastern Laboratory Services, Inc.
                          CAA-106
               Pr-oJ eot :  4-4-37©
                    194-—59— 1 B
'oo*;
            ELS01-Eastern Laboratory Services, Inc.
                          CAA-110
                          o-t. : 4-4-37©
                         4-— 5 9— 2 B
exxs
            ELS01-Eastern Laboratory Services,  Inc.
                           CAA-114
                R r- G- Jjs o -t : 4- ^- 3 7 6
                           —59—^B
             ELS01-Eastern  Laboratory Services,  Inc.
                           CAA-118
                Rr-ojeo-t- : -4-4-3
                     1 9-4-— 5 9 — -4-B
                                                  S01-.
                                                            604
                                                     	. .. _„,„...., .j>,wi f OWf'V
                                                              CAA-218
                                                     r-o j ©Gt : 4-
                                                     1  94-— 5 9 — £ ..••..
toT
            P \S01-Eastern Laboratory Services,  Inc.
                           CAA-1 22
               , R r~ o j o o t : -4- 4- 3 7 e
                     1 9-4-— 59— 5 B
            ELS01-Eastern Laboratory Services,
                           CAA-126
                     1 94-— 59 — ©B
           ELSOl-Eastern  Laboratory Services,  Inc.
                         CAA-1 30
              Rr-ojesct : 4-4-37©
                   194-— 59— 7B
           ELSOl-Eastern Laboratory Services, Inc.
                          CAA-1 34
               Rr-ojoct. : 4-4-37©
                    19 4- — 5 9 — e B a
           ELSOl-Eastern Laboratory Services, Inc.
                         CAA-1 38
              F3r-G.JeGt. : 4-4-37©
                   1 94-— 59 — 9 B

-------
Date: 12/29/97
Time: 13:46
 Sample
 M  crd TLI_Number..  Customer.Sample.Id

 000    TLI Blank    TLI  XAD BLANK

 001    194-S9-1A-1D 105-108

 002    194-59-2A-D  109-112

 003    194-59-3A-3D 113-116

 004    194-59-4A-D/ 117-120/216/217/218

 005    194-59-5A-D/ 121-124/219

 006    194-59-6A-6D 125-128

 007    194-59-7A-7D 129-132

 008    194-S9-8A-BD 133-136

 009    194-59-9A-9D 137-140

 020    TLI LCS      TLI LCS

 021    TLI LCSD     TLI LCSD

 ••• End of Report *•*
TRIANGLE LABORATORIES, INC.
Wet Lab MMS/PUF Observations
Project: 44376
F.
No
0
1
1
1
8 3
2
1
1
1
1
0
0
XAD
Color
WHITE
WHITE
WHITE
WHITE
WHITE
WHITB
WHITE
YELOWWHITE
YELOWWHITE
WHITE
LOT P-1078
LOT P-1078
Filter
Color
NA
BROWN
LT BROWN
LT BROWN
BROWN
BROWN
BROWN
BLACK
BROWN GRAY
LT GRAY
NA
NA
Glass Wool
Color 	
NA
WHITE
WHITE
WHITE
WHITEBROWN
WHITE
WHITE
YELLOW
YELLOW
WHITE
NA
NA
PUF
Color. .
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Odor .
NA
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NA
NA
Air
Q No
04047
04047
04047
04047
04047
04047
04047
04047
04047
04047
NA
NA
Entered . By
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
Date
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
PRDPERC V4.01
Page : 1
. . . Time 	 S
13:45 f
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
F
F
P
F
F
F
F
F
F
F
F
  ro
  ro

-------
           44376
                                                     TRIANGLE LABORATORIES,  INC. '                                   PAGE  1 OF  2
                                        Dioxin Sample Preparation Tracking & Management Form
                                                                             Client: Eastern Research Group  (ERG02)
                                                              i
I  Solvent (s)/Acid (s)'x£
|  Lot  Numbers:
                                              1
  Method:  Method  23:Tetra-Octa  (Tol  Combined)   Matrix:
Extraction Date:   it-/ T
|   IS Spike:    40  M!  cone:    0.1000  ng/Ml
1 SS Spike: Ml cone: . ng/Ml 1 ^^^
\ MS Spike: 0 pi ronr- 0 . 0000 ng/Ml 1 „ ^^J^.^r-,,
\ LTS Spike: 0 ,,1 rnnr- 0.0000 ng/Ml 1 I?S^ "?-..
1 OPR Spike: 20 M! cone: 0.01 ng/Ml 	 ... . \ 1 .L? / ^L /5l
™^~ "" ^^ \ Or^ \\L.\ "
\ «" * ' "VJ | *y / ^ 0» / d~1
| | TLI / | GROSS | SAMPLE | /2. : */1
|000 | TLI XAD BLANK | (VJ ft | AiH 1*1
| | 194-S9-1A-1D 1 1 1 . 1 -jT^'
|001 | 105-108 | )JL | |\jfi 1 1
| | 194-S9-2A-D III fflj*
|002 | 109-112 | N'J\- Lj$ 1 \ 1
| | 194-59-3A-3D I 1 ,» 1 1 1 ' l~**
|003 | 113-116 1 ^fi | ^H - I 1
P| 194-59-4A-D/-U). ^ 'p 1 'a/*4>/^
|006 | 125-128 | CfV 1 A*^ 1 1 1
1 | 194-59-7A-7D | , « I k . I | I <],W
|oo7 | 129-132 i N n i Nkn | | 1
| | 194-59-8A-9D | ' lA ' i ' "1" L^
|008 | 133-136 | fj^ 1 Nn |\| |
| | 194-59-9A-9D ' i 1 A- ' Wfr ' 1 ' ^^ '
|009 | 137-140 | A/ H | 'VX | 1 | |
«"W i —^fjf^\ |
stifle i 55*?5>| i
o'S^-^T i 1(£>F-A i
•f/S^ ^ li',3<$1
fl-0' nq/Ml 1 ^'/ nq/Ml 1
VO Ml 1 //V3 Ml 1
1 -&^~ 1
'Qd1. '
Ucf. '
' .^^v 5^^"
	 jQcL..!

!35"!
'fe '
\h%r-\
' QoT '
• :2^T !
1/1^ !
1 Chemist
1 So ike *
1 " ID
	 / 	 / 	 | " Expir
/ / I " Date
•C 	 : 	 | " Time
_ _rng/Ml 1 " Cone . |

| y'es/r!^ |
lAayLef t |
| yes/no |
!"^LK!
|Anv Left|
|^w Left)
I yesT^no |
|Af>v Left!
| yes/no |
|ASy Left
I yesTsjp
|Any Left
| yesTao
^x
I yes/\> |
|  Gross  weight  of  sample container  « sample  before/after  aliquot removal.
I
   Comments:
                                                                                            initials:
|  Initials of both SPIKER AND OBSERVER must  be  entered.
            XXXXX - Gross Weight not provided for WATER Samples.
           	REV OS/27/97 (PSTMF 7)-
                                                                                                                     23

-------
                     TRIANGLE LABORATORIES,  INC.
        Dioxin Sample Preparation Tracking & Management Form
                                             Client: Eastern Research Group  (ERGO2)
   Project:  44376
   Solvent (3) /Acid(s) i
   Lot Numbers:
                                   Method: Method 23 :Tetra-Octa (Tol Combined)  Matrix
                                  Extraction Date:   C- I ^/
                                                                                                                          I
                                                                                                                          | Any Left |
                                                                                                                          |  yes /no |
                                                                                                                          | Any Left]
                                                                                                                          |  yes/nc |
                                                                                                                          | Any Left]
                                                                                                                          |  yes/no |
                                                                                                                          I Any Left |
                                                                                                                          |  yes/no |
                                                                                                                          I Any Left |
                                                                                                                          |  yes/no |
I  Gross weight of sample  container *  sample  before/after aliquot removal
|
|   Comments:       rT  LvffQjIJf f\  \)\.ULf\ r*~ i
n  nlCLrt
I
                                                                                            Initials

                                                                   : ^Z/^ate:  U^_,^
|  Initials of both SPIKER AND OBSERVER must be entered.
                                             XXXXX » Gross Weight  not provided  for WATER Samples.  |
                                            	REV 05/27/97  (PSTMF  7)--.
                                                                                                                    24

-------
                                                              PAGE 2 OF 2
TRIANGLE LABORATORIES, INC.

Ext Sft.crd and
TLI Number
020
TLI LCS
021
TLI LCSD
IIIIIJ



TLI Project NO. : 44376
! i ! -^ 14*1 u 1 *> ! <&!T ! ? i? i-io i
I^T^i 5^- ! 5i • ! -JL- "-%- \ TL |$m i §£ i j
i^Y^^^M^W,^. i ! !
i i i I l l l l ^/ l . i i l l(^
I i i l l l l 1^1 1.1
I I 1 I.I 1 ! 1 1 1 1
i i i l i l l l i l l
i i i l l l l l l 1 l
i l l l l l l l l l l
l i i l l l l l l l l
l ii l l l l l l l l
l i i l l l l l i l l
| | 1 1 II 1 1 1 1 1
II 1 1 i 1 1 1 • 1 1 1


Enter the proced
Initial and date
$ 	 PROCEDUR
(^J EXTRACTION
(5? SPIKE AFTER
(^ ADD TRIDECAN
^? ROTOVAP
Jai COMBINE
^) DIV./LIP. DE
O) SOLVENT EXCH
01 CLEANUP
f) TRANSFER
10) ADDITIONAL C
FINAL TRANSF
| | ! II 1 I'll 1 1
1 -| 1 1 1 1 1 1 1 1 !
i i i l l l l l l l l
i i i l ill l l l l
ure number below into the box at the top of each column to signify the step performed.
each sample for each numbered procedure performed.
E.... SOP.#. .v.. DETAILS (circler^ \l^c<=("3'
^| 1 ^ Time On .O : °_£ Time Off 0_S : 0_O
SOJch^st / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
EXT'N ^"X\_— l
E . Loti* /A,/* /~xi"*Vv' j--^-.
35Bef£L4(«, / &A.I (^ess^
TERM. JM ^ 20%/BO* /•sUvsljJ) 5mL^20mL Other
4jj 	 x — ^—-^ffflniLLl 	
ANGE jktf?^ Iso-Octane Lotft1? / l/Wi Heptane Lot#
^p/V^'if.j f <^SP 26Q?/ DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
—aQ^i-.^T^T^'l^i /- ^ 	 -v
LEANUP Mod. DS^ZSO; / DSP 225 / DSP 115 / DSP 215 / DSP 267 / ( DSP260 (lOg) )
ER 4^-7 7 ' / ^ ^ 	
i/*jl '• • '•• ... /^s- —
comments ~:W~tiffy Z37 ¥£ Q/7(jfi5(j tJAtd ~fr> A//-VL^ ~J)/\^fr 
-------
                                                                  PAGE 1 OF 1
                        TRIANGLE LABORATORIES,  INC.
                       Transfer Chain-of-Custody Form
                                Project 44376

                    Transfer   From:  DWLH5     To: DMS5

                            Initials. .    Date	    Time. .

             Released by:     ^)C      ' _L/_£1/3L     /£ : o

             Accepted by:     frf ^       -LjSL/3g    [£ '
         MILES.ID,

         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
         44376-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-020
-021
-022
         TLI No	  Cust.Id.
TLI Blank     TLI XAD BLANK
194-59-1A-1D  105-108
194-59-2A-D   109-112
194-59-3A-3D  113-116
194-59-4A-D/  117-120/216/217/218
194-59-5A-D/  121-124/219
194-59-6A-6D  125-128
194-59-7A-7D  129-132
194-59-8A-8D  133-136
194-59-9A-9D  137-140
TLI LCS       TLI LCS
TLI LCSD      TLI LCSD
TLI Clean-Up  Cleanup Blk
Additional comments or instructions:
                                                      -XfrCOC  (Rev 11/01/94)--+
                                                                     26

-------
                                                                                                           PAGE 1 OF 1
thod: Method 23:Tetra-Octa  (Tol Combined)
quired Detection Limit:  .05 ng
                                              TRIANGLE LABORATORIES,  INC.
                                                  HR  GC/HRMS ANALYSIS
I PROJECT:   4437S   |
| SAMPLE INFORMATION RS Cone |
| 1ST COLUMN 2ND COLUMN 20 (il « 100.0 PG/|il |
1 | TLI /
|S#.crd| SAMPLE ID / CLIENT
| | / SAMPLE ID
| | TLI Blank
| | 194-59-1A-1D
|001 | 105-108
| | 194-59-2A-D
|002 | 109-112
| I 194-59-3A-3D
|003 | 113-116
| | 194-59-4A-D/^(4//S '^P
i I
i
| GC/MS FILENAME | CONFIRM [CONFIRM FILENAME |USF-RS |USF-RS (ANALYSIS |
| COLUMN V^*?') 1 1 COLUMN : ^ Vl^* 1 VOLUME UNIT. I COMMENTS 1
| | | ISOLN ID |D ATE | |
iSHiV Ue^v^!11^! !
r2> i y i
f^Soj ' '/7~ f y. "1 ^ '•*-' 5 '
lt*>3b (^ 1 ^ 1 1
l"jzyffl/'#fr ' / ' y^ftco^ '
if3Fci^rv ^ i i
-"""""^-iw . • ^i— . ' i i VT'*"'/ ^ TD <*jfl> ~*
/ £ ^/L*' i_ \*t "v^/ ' )*• (
^ 	 -J^. .,./. - V I v-i I
ip^r^r. 	 [ 	 <>.T. 	
i T$'?CI6^! . , i / i
1--.^ ^.. ,.,.- ' V i T ? I

jT^jf^ ^ i^ ^ .QilR
'ftfuO W(£ ' r ^ vi.<5«\ b^-^-U1
i-f^i^' : \f Woi&^i
;T^^ i^ !^w,^!
I ;9 cTC'( b ^ M i p «3 &-f-\ i ^. Q i
1 ' jUf' ' . !
1 V
1 if! — - — !
1 1 1
1 ' I !
1 1 1
II. 1
1 I 1
1 1 I
1 1 1
1 1 1
II !
1 1 1
o'-fl ' '
1 1 1
1 1 !
1 1 i
1 1 1
1 1 1
I 1 1
1 1 1
1 1 i
1 1 1
'^&\^'^f 1 1<^_ (^ \ ^ i ^ ^ .
'^ •S7tr'c" *• * '
1 '/"/V ,
1 1
I Spike File: SPX23704 i
1
1
i
Ante of Extract: 50% I
» 	 	 	 	 	 	 	 	 	 	 	 REV 03/07/95 (PSTMF 6) --»
                                                                                                                 27

-------
                                                   Triangle Laboratories, Inc.
                                                          Run Log
Instrument ID
     lor
                    Column Type
                                             Column ID
Plot Name
 -763
                                                         Ini. Vol.
                                                                  Acquisition
                                                                    OJ
                                                                             Q/C
                                                                                                                  'Date
Filename
                  Date*
Time*
Project #
Sampled
                                               No.
Client Sample ID
Syr
332
Operator/Date
                                                                                         JM
Comments
                   02 mo
                                                                        ' til
                   lo)lb
             vb
                                                  0
                                                                                 7*
                                                                             M--TVJ
                                                                        m^
       feo
                                    I
                                                          Tt-
                                                                                                                          1
                                                              -   IK/;
                                                                             \y
                                                                                                    vy
  *     Transcribed from chromatographic data
  *'     Dated initials required

^jsrvr1/qa/forms/hrrunlog doc (02/05/97)
CO
                                                    ConCal Due:
                                                    ConCalDue:
                                                                                                                    67

-------
                                                       Triangl^fcboratories, Inc.
                                                             ^Rn Log
Instrument ID Column Tvoe Column ID Plot Name


ink VQJ. Acquisition
ft
Signature
G/C
// o O
IO*' j A
Date
Filename
                   Date*
Time*
Project #
Sample*
NO.
Client Sample ID
Syr
332
Operator/Date
Comments
       60
       6\
                                                                                           2-1-
                                                                                                      /•(l-ff
                                                      0
                                 $J-
                                                       0
                                                                                           3.3
                                                /Alp
                                                                                     u
 *      Transcribed from chromatographic data
 **     Dated initials required

 srvr1/qa/forms/hffunlog doc (02/05/97)
ro
                                                         ConCal Due:
                                                         ConCal Due:
                                                                                                                       Pano:
                                                                                                                             63

-------
                                                      Triangle Laboratories, Inc.
                                                              Run Log
Instrument ID Column TVDO Column ID •* Plot Name
ioT £>fr> lui|i^?> -fez.

in). Vol. Acquisition
z-of^f yr/
/
M.
Signature
QIC
ill>PW$
n-ii
Date
Filename
                  Date*
Time*
Project #
Sample/?
No
Client Sample ID
Syr
332
Operator/Date
Comments
-rno  i<5
        K1
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                                                     Triangle Laboratories, Inc.
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-------
                                                                                                            PAGE 1 OF 2
L
                                             TRIANGLE LABORATORIES,  INC.
                                  DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
                                                TLI Project No.: 44376
Ext S#.crd and |
TLI Number |
000 \d£
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001 |iV?
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                                                                             Mr.iX  +
                                                                             6           "
                                                                                              •Rev 11/25/97 (PSTMF 4)-

-------
SAMPLE
  DATA
          Triangle Laboratories, Inc.
  801 Cap/to/a Drive         P.O. Box 13485
  Durham, NC 27713-4411      Research Triangle Park, NC 27709-3485
  919-544-5729            Fax #919-544-5491   n ~
                                 OD

-------
TRIANGLE LABORATORIES OF RTP,
Sample Result Summary for Project
Method 82 9 OX Full Screen Analyses
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HoCDD
-OCDD
'.. 2378-TCDF
12378-PeCDF
23478-PeCDF
- 123478-HxCDF
- 123678-HxCDF
T 234678-HxCDF
.-•123789 -HxCDF
1234678-HpCDF
' 1234789-HpCDF
— OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HxCDD 478
13C12-HpCDF 789
Other Standards
13C12-HXCDF 789
13C12-HxCDF 234
T980152
TLI XAD BLANK
ng
12/29/97
01/06/98
T
XAD
Soxhlet
(0
(0
(0
(0
<*CSE
PR



E
E
Q

SQE
SE
E
X




Q





Q



5
4*6
31
49
9^7
-£4-7
42-0
~* A /^
K"iJ
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7S.O
.6
.6
? *•
~?£-<3
7^0
7&O
•3437 }>
3-8-6
••t£6
*W

90
115
83
116
126

95
82

52
79
72
106
7<9<7
•7&0
?9-e

.8

.4



.8
.6

.7
.6
.7

PR
SE
<3<

SE
SQE
SQE
SE
SQE
SQE
SQE
SEC?


Q

-------
                        TRIANGLE LABORATORIES OF RTP,  INC.
                     Sample Result Summary  for  Project 44376
                     Method 8290X Full Screen Analyses (DB-5)
Page  2
 01/15/98
Data File
Sample ID

Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
T980152
TLI XAD BLANK

ng
12/29/97
01/06/98
T
XAD
Soxhlet
=================:
T980154
109-112

ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
T980155
113-116

ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
T980156
117-120/216/217
/218
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
 Internal  Standards Percent Recovery Summary  (% Rec)
 13C12-HxCDF 678      64.8              69.7              75.5
 13C12-HXCDD 678      81.9              63.3   Q          62.8
 13C12-HpCDF 678      64.5              77.0              81.2
 13C12-HpCDD 678     100               103               109
 13C12-OCDD          114               112               114
   86.7
   89.7
   85.4
 _L19 -.
  134"
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
  Printed: 14:50 01/15/98
                                                                                    38

-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 44376
Method 8290X Full Screen Analyses (DB-5)
*)ata File
• .ample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378 -TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-KpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
k OTAL HxCDD
F.OTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HxCDD 473
13C12-HpCDF 789
Other Standards
13C12-HxCDF 789
13C12-HxCDF 234
T980157
121-124/219 /
#.^y
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet

2.
14.
17.
31.
55.
98.
79.
t i •**$ ~\
\ ± .J A* j

5
3
0
2
3
8
8
?w-



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SE
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PR
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39.
52.
•*&£•
9
4
7^
•i£47^C
4£2-
196
>tt

30£-7Mr
sa-
-45-i.'
2*9
Percent
96.
103
84.
129
127
Percent
85.
71.
•&•&
•7*0
75^C
<*

SE
SQE
SQE
E
SQE
OSQE
SQE
' SE<£
Recovery
3

2



Q
3?
Q
$
Recovery
3
4
Internal Standards Percent
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
45.
62.
67.
86.
0
2
0
7


T980158
125-128 /
i'o . .,
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet

0
6
6
12
18
40
34

.86
.3
.0
.0
.8
.3
.5





PR
E

•94-7-774- SE
19
35
64
27
34
1
77
9
17
280
260
210
83
-655-
•4i8
270
116
Summary
92
86
103
107
99
Summary
49
45
.1
.3
.6
.0
.4
.5
.6
.1
.4



.1
••Hlf
7<»0


(%
.1
.8


.5
(%
.9
.8
Recovery Summary
Q

Q

41
47
52
56
.3
.3
.0
.6


E


PR
E


E
E
E .
E
SQE
SE
E
E
Rec)





Rec)


(% Rec)
Q



T980159
129-132 /
**•-••• ' v
ng
12/29/97
01/06/98
T
M23TRAIN
Soxhlet

0
0
0
0
0
1
1
4
0
1
3
1
1
0
4
0
4
4
2
4
2
26
21
13
8

82
94
99
104
107

82
76

66
67
76
90

.04
.18
.17
.27
.41 PR
.2
.8
.1
.91
.6
.5
.3
.7
.09 • PRJ
.8
.87
.0
.5
.9
.2
.3
.1 Q
.4
.9 6?


.6
.1
.9



-5
.1

.7
.7
.8
.6
Page 3
01/15/98
T980163
133-136 /
ng
12/29/97
01/07/98
T
M2 3 TRAIN
Soxhlet

0
0
0
0
0
0
0
2
0
0
0
0
0
0
0
0
1
4
0
0
0
24
7
2
1

86
94
97
95
114

82
76

72
73
81
90

.02
.05 J
.02 J
.04 J
.06 PRJ
.16
.27 B
.9
.29
.40
.54
.21
.23
.01 PRJ
.68
.11
.2
.4
.83
.72
.32
.0 Q
.3
.3
.1

.1
.5
.5
.8


.1
.0

.2
.4
.6
.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:50 01/15/98
                                                                                             3S

-------
 Data  File
 Sample  ID
    TRIANGLE  LABORATORIES'OF RTP, INC.
 Sample Result  Summary for Project 44376
 Method 8290X Full  Screen Analyses  (DB-5)

  T980157           T980158          T980159
121-124/219         125-128          129-132
                                                                         Page  4
                                                                          01/15/98
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
                  T980163
                  133-136

                    ng
                 12/29/97
                 01/07/98
                     T
                 M23TRAIN
                  Soxhlet
  Internal  Standards Percent Recovery Summary (% Rec)
  13C12-HxCDF 678      71.9
  13C12-HxCDD 678      69.3
  13C12-HpCDF 678      74.2
  13C12-HpCDD 678     112
  13C12-OCDD          119
                     47
                     53
                     55
                     69,
                     72.3
 75.8
 90.7
 86.6
112
109
 77.1
 95.5
 84.2
110
112
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                       Printed: 14:50 01/15/98
                                                                                   40

-------
TRIANGLE LABORATORIES OF RTP, INC. Page 5
Sample Result Summary for Project 44376 01/15/98
Method 8290X Full Screen Analyses (DB-5)
Oata File
\ jample ID

Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
1 'OTAL HxCDD
L'OTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
T980164
137-140 /
': s .^ . /
f. •- -
ng '
12/29/97
01/07/98
T
M2 3 TRAIN
Soxhlet

0.04
0.06 J
0.02 J
0.05 J
0.06 PRJ
0.12
0.16 JB
4.2
0.38
0.51
0.56
0 .21
0.22
0.01 PRJ
0.41
{0.05} J
0.24
7.4
1.1
0.86
0.26
34.0 Q
9.9
2.4
0.60
T980153 /
lOS-lOa'
Oj -> •

ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet

2.5
10.2
3.4 Q
4.5
7 . 4 QPR
5.4
3-27*
(90. 2-] SE
52.7 E
67.9 E
42.9 E
19.7
12.3
0.68 PR
11.7
1.4
1.7
175 E
t&97£vC7 SE
103 QE
11.0
Jr£W7U- SQE
•&4-1 19-O SE
-&&97<*O SE
15.3 X
T980167
Cleanup Blk

ng
12/31/97
01/07/98
T
XAD
Soxhlet

(0.003)
(0.004)
(0.005)
(0.004)
(0.004)
(0.004)
{0.02} JB
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.004)
(0.004)
(0.003)
(0 .004)
(0.004)
(0.003)
(0.004)
(0.004)
(0.004)
(0.003)
(0.003)
(0.003)
(0.003)
 Other Standards  Percent Recovery Summary (% Rec)
 37C1-TCDD             84.8              92.6
 13C12-PeCDF  234       97.4              99.6
 13C12-HxCDF  478      100              ,--?-4_.4
 13C12-HxCDD  478      101              .158 "    Q
 13C12-HpCDF  789      108               101

 Other Standards  Percent Recovery Summary (% Rec)
 13C12-HxCDF  789       80.0              76.1
 13C12-HXCDF  234       71.7              70.4

 Internal Standards Percent Recovery Summary (% Rec)
 13C12-2378-TCDF       64.1              43.0   Q
 13C12-2378-TCDD       64.3              68.7
 13C12-PeCDF  123       75.6              73.6
 13C12-PeCDD  123       90.9              83.3
74/5
69.2
52.5
54.6
68.7
76.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                 Printed: 14:50 01/15/98
                          41

-------
  Data File
  Sample ID
   TRIANGLE LABORATORIES OF RTF,  INC.              Page   6
Sample  Result Summary for Project 44376             01/15/98
Method  8290X Full Screen Analyses (DB-5)

 T980164           T980153           T980167
 137-140           105-108         Cleanup Blk
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
12/29/97
01/07/98
T
M2 3 TRAIN
Soxhlet
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
ng
12/31/97
01/07/98
T
XAD
Soxhlet
  Internal  Standards Percent  Recovery Summary  (% Rec)
  13C12-HXCDF 678
  13C12-HxCDD 678
  13C12-HpCDF 678
  13C12-HpCDD 678
  13C12-OCDD

  {Estimated Maximum Possible Concentration},   (Detection  Limit)
71.9
90.2
83.4
109
108
71.7
54.3 Q
77.0
102
110
== — '=—======—===—=—
63.7
80.6
84.9
108
115
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                       Printed: 14:50 01/15/98
                                                               42

-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376
Method 23X (DB-225)
lata File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
X980083
TLI XAD BLANK
ng
12/29/97
01/07/98
X
XAD
Soxhlet
0.02
X980084
105-108
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
49.4
X980085
109-112
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
E 26.2 E
Page 1
01/11/98
X980086
113-116
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
28.4 E
  Internal Standards Percent Recovery Summary (% Rec)
  13C12-2378-TCDF       73.0               86.7
83.4
92.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                  Printed: 13:38 01/i 1/93

-------
                            TRIANGLE LABORATORIES, INC.
                     Sample Result Summary for Project  44376
                                Method 23X (DB-225)
               Page   2
                01/11/98
Data File
Sample ID

Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
X980087
117-120/216/217
/218
ng
12/29/97
01/07/98
X
M2 3 TRAIN
Soxhlet

62.8 E
X980088
121-124/219

ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet

85.0 E
P980166
125-128

ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet

17.5
P980167
129-132

ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet

0.83
  Internal Standards Percent Recovery  Summary {% Rec)
  13C12-2378-TCDF      109                 78.8
51.0
74.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                 Printed: 13:38 01/11/98
                               44

-------
                            TRIANGLE LABORATORIES,  INC.                  Page  3
                     Sample Result Summary for Project 44376             01/11/98
                                Method 23X  (DB-225)

 Data  File           P980168          P980169
 Sample ID           133-136          137-140
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet

0.57
ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet

0.69
  Internal Standards Percent Recovery Summary (% Rec)
  13C12-2378-TCDF      73.9              72.5
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713                                    Printed-13-
Phone: (919) 544-5729 • Fax: (919) 544-5491                                           W>

-------
Data Flags

In order to assist with data interpretation, data qualifier flags are used on the final reports.
Please note that all data qualifier flags are subjective and are applied as consistently as
possible.  Each flag has been reviewed by two independent Chemists and the impact of the
data qualifier flag on the quality of the data discussed above.  The most commonly used
flags are:

A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag is used only when the
concentration of analyte found hi the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or  amount of that analyte detected in the field sample.

An 'E'  flag is used to indicate a concentration based on an analyte to internal standard
ratio which exceeds the range of the calibration curve. Values which are outside the
calibration curve are estimates only.

An T flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated.  All quantitations relative to this standard, therefore, may be
underestimated.

A 'J' flag is used to indicate a concentration based on an analyte to  internal standard ratio
which is below the calibration curve. Values which are outside the calibration curve are
estimates only.

A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be  seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely  overestimated.

A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences.

An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside  of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may  be underestimated.

An 'S' flag indicates that the response of a specific PCDD/PCDF isomer has exceeded the
normal dynamic range of the mass spectrometer detection system. The corresponding
signal is saturated and the reported analyte concentration is a 'minimum estimate'.  When
the 'S' qualifier is used in the reporting of 'totals', there is saturation of one (not
necessarily from a specific isomer) or more saturated signals for a given class of
Data Hags                                                                    .  Page 1 of 2
Rev. 11/19/97
                                                                                       46

-------
 compounds.  Results for saturated analytes are reported as greater than the upper
 calibration limit.

 A 'U' flag is used to indicate that a specific isomer cannot be resolved from a large, co-
 eluting interferent GC peak. The specific isomer is reported as not detected as a valid
 concentration cannot be determined.  The calculated detection limit, therefore, should be
 considered an underestimated value.

 A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
 be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
 one.  The standard is considered reliably quantifiable. All quantitations derived from the
 standard are considered valid as well.

 An 'X' flag is used to indicate that a polychlorodibenzofuran (PCDF) peak has eluted at
 the same time as the associated diphenyl ether (DPE) and that the DPE peak intensity is at
 least ten percent of the total PCDF peak intensity. Total PCDF values are flagged 'X' if
 the total DPE contribution to the total PCDF value is greater than  ten percent.  All PCDF
 peaks that are significantly influenced by the presence of DPE peaks are either reported as
 "estimated maximum possible concentration  (EMPC) values without regard  to the isotopic
 abundance ratio, or are included in the detection limit value depending on the analytical
 method
Data Rags                                                                     Page 2 of 2
Rev. 11/19/97
                                                                                      47

-------
Method 23 Sample Calculations:

Analyte Concentration

The concentration or amount of any analyte is calculated using the following expression.
Where:
                              * RRFM * W
       Amt(C)  =   amount of a given analyte, expressed in nanograms (ng) or picograms
                  (pg)-
       A
-------
TLI Project:      44376
|lient Sample:   TLI XAD BLANK
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  T980152
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
XAD Date Received:
TLI Blank Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
II
12/29/97
01/06/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
i&SW:;:W>x&^
2,3,7,8-TCDD
U,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
^,4,7,8-PeCDF
P,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
U,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF


Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

ND
ND
ND
ND
ND
ND
EMPC
0.03
ND
ND
ND
ND
ND
ND
ND
ND
ND


ND
ND
ND
ND
0.04
ND
ND
ND
HSSSSHSiSS-x^
0.007
0.01
0.01
0.01
0.01
0.01
0.02

0.01
0.01
0.01
0.009
0.01
0.01
0.01
0.02.
0.01


0.007
0.01
0.01
0.01
2
0.01
0.01
0.01
^^^^^^^^^^^^^S^^^^^^^^^M





	
J_
0.81 25:40 	

	











	



I .
                                      Page 1 of2
                        X2J7J>SR TZOI. LARS 6.10.08
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 11:48 01710/98
                            4S

-------
TLI Project:     44376
Client Sample:   TLI XAD BLANK
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   T980152
'infernal Standard* ,„,,,
13C12-2,3,7,8-TCDF
l3C12-2,3,7,8-TCDD
13C12-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13CI2-l,2,3,6,7,8-HxCDD
13C12-l,23,4,6,7,8-HpCDF
'3Ci2-l,2,3.4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37a,-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13C12-l,2,3,4,7,8-HxCDD
13CI2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13Ci2-l,2,3,7,8,9-HjcCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
AmLjngJ .:
15
2.6
25
33
2.6
33
2.6
4.0
9.1
Awt (tig)
3.4
3.9
3.4
4.1
3.8
Amt (ng)
2.9
2.8
-


b^*Ha*0f
61.4
65.5
62.3
81.5
64.8
81.9
64.5
100
114
% Recovery
84.4
98.4
85.3
102
95.5
% Recovery
71.7
69.8



QC Limits .
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%-130%
40%- 130%



;%#Wfc£V'
0.75
0.80
1.52
1.49
0.53
1.17
0.45
1.01
0.91
Ratio

1.52
0.49
1.19
0.45
Ratio
0.51
0.52
Ratio
0.81
1.15
ST Flags
25:39 	
26:21 	
29:30 	
30:30 	
32:59 	
33:41 	
35:59 	
37:04 	
40:55 	
RT Flags
26:21 	
30:10 	
32:53 	
33:36 	
37:36 	
8T Flags |
34:18 	
33:29 	
RT Flags
26:10 _
34:01 	
                     Data Reviewer.
            01/10/98
                                       Page 2 of 2
                         X237_PSR V2.01. LARS S.iO.OS
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 11:48 01/10/98
                             50

-------
                         Initial
                                       Data..
  Data  Review By:
                      42_/£2£
                                                Calculated Noise Area:
  The Total Area tor each peak with an ion abundance ratio outside
   atio  limits has been recalculated according to method requirements.
                                                                        2.19
  Page No.
  01/10/98
         Listing of T980152B.dbf
         Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID..  Flags.
  TCDP
  304-306
  304-306

  13C12-TCDF
  316-318
 316-318
  .ODD
 320-322
 320-322

 37C1-TCDD
 328

DC
DC


DC
DC


DC





DC


DC
DC
DC
DC
DC.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


NL
SN


SN
SN
2

NL





SN
5

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0

0:00
23:50
25:17
25:40
26:32
27:12
Peaks

0:00
24:40
24:57
25:15
25:39
26:06
26:20
Peaks

0:00
23:52
24:11
24:16
24:37
24:57
25:26
25:40
26:02
26:21
26:36
26:49
27:02
27:09
27:43
Peaks
0
RO
RO


RO
RO

0.
RO

RO
RO

RO
RO

0.

RO
RO
RO
RO
RO
RO
RO
RO

RO
RO
RO
RO
RO

.65-0.89
1
1
0
0
3
2

.61
.62
.88
.81
.67
.61

65-0.89
1
0
0
0
0
1
0

65
0
1
1
0
0
0
2
1
1
0
4
1
3
0
0

.67
.82
.90
.93
.75
.04
.25
Al
-0.39
.72
.05
.33
.51
.17
.28
.08
.11
.20
.85
.37
.75
.83
.17
.40

                                                 1.72
                                                 2.64
                                                12.98
                                                21.81
                                                 0.37
                                                 2.41
                                                34.79
                                             6.07
                                             9.75
1.67
0.82
0.90
0.93
0.75
1.04
0.25

1.
113
12
27
2.533.
17,
1.
2,704.
.27
.56
.39
.67
.33
.12
.45
,57

51.
6.
14.
1,086.
10.



30
28
61
30
06


                               0.878-1.073
                                   0.000
                                   0.929
                             6.91   0.986
                            12.06   1.001 2378-TCDF       AN
                                   1.034
                                   1.060
                                                             0.961-1.039
                                                                 0.000
                                                          62.26  0.962
                                                           7.00  0.973
                                                          15.63  0.984
                                                        ,447.53  1.000 13C12-2378-TCDF ISO
                                                           9.67  1.018
                                                                 1.027
                 DC
                 DC
    NL   0:00
    SN  24:28
        25:01
DC  SN  25:19
                                       Above: TCDF / TCDD Follows
                                0.36
                                2.99
                                1.45
                                1.61
                                0.28
                                0.85
                                0.42
                                3.29
                                0.27
                                3.55
                                0.53
                                0.57
                                0.51
                                0.78
                                1.20
                                0.00
 0.74
 1.26
11.57        11.57
 0.92
                              0.903-1.045
                                  0.000
                                  0.906
                                  0.918
                                  0.921
                                  0.934
                                  0.947
                                  0.965
                                  0.974
                                  0.988
                                  1.000 2378-TCDD
                                  1.009
                                  1.018
                                  1.026
                                  1.030
                                  1.052
0.924-1.076
    0.000
    0.929
    0.949
    0.961
                                                                                                      AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                             Printed: 11:49 01/10/98
                                                                                         51

-------
  Page Mo.
  01/10/98
Listing  of T980152B.dbf
Mat chad  GC Peaks / Ratio
/ Rat. Tim*
  Compound/
  M_Z	QC.Log Omit Why . .RT.  OX Ratio Total.Area..
                         • Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334






332-334
PeCDF
340-342





















340-342
13C12-PeCDF
352-354






DC
DC
DC

DC
DC
DC






DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC





SN
SN
SN
3

ML
WL
SN




4

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0

NL
SN





26:21
26:43
27:05
27:38
27:47
Peaks

0:
24:
24:
25:
26:
26:
26:

00
02
48
14
10
21
40
0.
RO
RO
RO
RO


RO
1
1
,853.93 1,853.93
5.05 5.05
1.05
2.11
1.50
,870.55
.65-0.89
2
4
1
1
0
0
0
Peaks

0:
27:
27:
28:
28:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
29:
30:
30:
30:
30:
30:
31:

00
32
53
04
08
14
31
41
52
01
08
14
23
31
47
54
12
23
30
35
46
09
1.
RO

RO
RO
RO
RO
RO
RO
RO
RO
RO


RO
RO
RO
RO
RO

RO
RO

.11
.55
.46
.00
.81 2
.30 2
.98
4
32-1.78
0
1
0
0
0
0
0
1
2
1
1
1
1
0
0
0
0
0.
1
0
5
1
.76
.65
.43
.15
.58
.42
.36
.93
•57
.00
.10
.44
.42
.95
.63
.68
.98
.93
.65
.55
.63
.42
Peaks

0:
27:
28:
29:
29:
29:
30:

00
24
38
07
30
47
10
1.

RO

RO


3.42
1.96
3.12
18.62 10.56
,670.14 1,191.70
,183.11 967.35
38.07 21.10
,909.94
Tfnn / P«f HP Prti 1 nura
±\rUU 1 rV\~ijr f OXXOW9 — ~
0.72
3.79
0.64
0.16
0.43
0.43
1.68
4.18
1.30
1.79
2.96
2.73
1.55
1.25
1.09
0.63
1.69
1.74
1.75
0.67
0.61
2.66
0.00
32-1.78
1
3
1.
0,
1,
1.
.47
.75
.59
.92
.52 2,
.45
1.52 2,
0.47
1.4S
165.40 101.52
4.77 2.90
,129.72 1.284.48
26.73 15.81
,079.94 1,253.83
1
1
1
1
1
.000 37C1-TCDD
.014
.028
.049
.054
SUR:
0.924-1.076
0
0
0
10.52 0
1,478.44 0
1,215.76 1
21.51 1

.000
• 912
.941
.958
.993 13C12-1234-TCDD
.000 13C12-2378-TCDD
.012





RSI
IS1


0.931-1.063
0
0
0
0
0
0,
0,
0,
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.

.000
.933
.945
.951
.954
.957
.967
.972
,979
,984
988
991
996
001 12378-PeCDF
010
014
024 23478-PeCDF
030
034
037
043
056














AN


AN






0.864-1.136
0.
0.
63.88 0.
3.14 0.
845.24 1.
10.92 1.
826.11 1.
000
929
971
987
000 13C12-PeCDF 123
010
023 13C12-PeCDF 234




IS2

SDR2
Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 11:49 01/10/98

-------
  Page Ho.
  01/10/98

  Compound/
Listing of T980152B.dbfi
Matched GC Peaks /  Ratio / Ret.  Tim*
  352-354
  PeCDD
  356-358
 356-353

 13C12-PeCDD
 363-370
 368-370
 HxCDF
 374-376
 374-376
Omit Why . .

DC
DC
DC
DC



DC
DC
DC
DC
DC
DC
DC
DC


DC


DC
DC


DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


SN
SN
SN
SN
6


NL
SN
SN
SN
SN
SN
WH
WH
0

NL


SN
SN


SN
SN
SN
4

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
30
30
30
31
31
RT.
:31
:51
:58
:08
:35
OX
RO
RO
RO
RO

Ratio Total. Area. .. Area. Peak. 1. . ATI
1
0
1
1
1
.21
.89
.20
.30
.65
Peaks


0
28
29
29
29
30
31
31


:00
:4S
:38
:47
:56
:04
:16
:32

1
RO
RO


RO
RO
RO
RO

.32
2
0
1
1
0
2
2
0

-1.78
.33
.25
.66
.70
.65
.06
.50
.13
Peaks

0
29
29
29
30
30
30
30
31
31

:00
:28
:35
:54
:13
:30
:38
:49
:00
:08
1

RO

RO
RO


RO
RO
RO
5
1
1
5
1
4,412
.73 3.48
.18
.17
.07
.59
.29
ia.P«ak.2.. Rel.RT Compound . Name .. ID.
2.88 1
1
1
1
1

.034
.046
.050
.055
.071



1
1
2
3
2
1
1
0
0
.10
.46
.55
.08
.01
.63
.28
.38
.00
.32-1.78
1
0
1
2
0
1
1
2
0
1
Peaks

0
32
32
32
32
32
32
32
33
33
33
33:
33:

:00
:01
:12
:16
:27
:38
:53
:56
:07
:11
:29
;38
:47
1
RO

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.42
.87
.61
.75
.97
.49
.41
.36
.24
.06

0
5
8
1
1
1,545
169
3
1
1
1,729
n^/*ni
.05-1.43
1
1
0
2
0
10
1
3
3
0
1
0
1
.61
.13
.48
.21
.81
.31
.46
.66
.00
.54
.56
.32
.02
Peaks
i
0
0
0
.46
.59 3.40
.77 5.41
.53
.63
.28 925.89
.38 99.19
.72
.23
.20
.02

.48
.83
.58
.63
0.79
0
2
0.
0.
0.
2.
.29
.08
.99
.47
.78
.02
0.74
0.
0.
.99
.00
0.939-1.022
0
0
0
0
0
0
•1
1

.000
.943
.972
.977
.981
.986
.025
.034

0.869-1.131
0.
3.93 0,
3.36 0.
.000
.966
.970
0.980
0.
619.39 1.
70.19 1,
1.
1.
1.

.991
.000 13C12-PeCDD 123 IS3
.004
.010
.016
,021

0.964-1.049
0.
0.
0.
000
971
976
0.978
0.
0.
0.
0.
1.
1.
1.
1.
1.

984
989
997
998 123478-HxCDF AN
004
006
015 234678-HXCDF AN
020
024

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 11:49 01/10/98
                                                                            53

-------
  Pago No.
  01/10/98
Listing of T980152B.dbfi
Matched OC Peaks / Ratio / Ret.  Time
  Compound/
  M_2	QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Confound.Name.. ID..  Flags.
13C12-HXCDP
384-386











384-386
-HXCDD
390-392
D






390-392
13C12-HXCDD
402-404






402-404

HpCDF
408-410







408-410

DC


DC



DC

DC
DC
DC


DC
D
DC
DC
DC
DC
DC
DC


DC




DC
DC



DC
DC
DC
DC
DC
DC
DC
DC


NL


SN



SN

SN
SN
SN
6

NL
SN
SN
SN
SN
SN
SN
WH
0

NL




SN
SN
4


NL
SN
SN
SN
SN
SN
SN
WH
0

0:00
31:56
32:03
32:12
32:53
32:59
33:29
34:07
34:18
34:34
34:39
34:39
Peaks

0:00
32:51
33:03
33:14
33:20
33:26
33:51
34:18
Peaks

0:00
33:04
33:36
33:41
34:01
34:14
34:29
Peaks


0:00
36:01
36:15
36:31
36:42
36:55
37:29
38:06
Peaks
0







RO

RO
RO
RO

1


RO
RO

RO
RO
RO

1.
RO
RO



RO
RO
.43-0.59
0
0
0
0
0
0
0
0
0
0
0
0

.59
.57
.53
.54
.49
.53
.52
.72
.51
.28
.76
.32

4
22
42
1
1,489
1,896
1,949
2
1,583
6
2
3
6,984
.05-1.43
1
1
0
0
1
0
0
0

.05
.10
.65
.66
.06
.23
.63
.88

1
6
1
0
0
0
0
1
0
.44
.42 8.16
.13 14.68
.03
.37 491.62
.59 654.96
.81 663.44
.13
.78 533.58
.28
.02
.22
.60

.78
.67
.55
.70
.66
.58
.45
.26
.00
,05-1.43
1
0
1
1
1
4
0
.83
.98
.19
.17
.15
.41
.26
1
13,
1,397,
1,695,
2,073,
.72
.44 7.44
.26 758.52
.05 915.70
.12 1,110.55
5.64
1.
,68
0.879-1.121
0
14.26 0
27.45 0
0
998.25 0
1,241.63 1
1,286.37 1
1
1,050.20 1
1
1
1

.000
.968
.972
.976
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.015 13C12-HXCDF 234
.034
.040 13C12-HXCDP 789
.048
.051
.051





SDR3
IS4
ALT2

ALT1




0.958-1.015
0
0
0
0
0
0
1
1

.000
.975
.981
.987
.990
.993
.005
.013










0.970-1.030
0.000
7.58 0.982
638.74 0.998 13C12-HXCDD 478
779.35 1.000 13C12-HXCDD 678
962.57 1.010 13C12-HXCDD 789
SOR4
IS5
RS2
1.016
1.024
5,178.87

0.
RO
RO

RO
RO
RO
RO
RO



tiv^nr
88-1.20
0
1
0
6
0
3
.84
.24
.93
.03
.36
.45
1.71
0.19




0.90
2.98
1.
99
0.59
0.61
0.78
0.
0.
0.
71
24
00



0.998-1.053
0.000
1.001 1234678-HpCDP
AN
1 . 007
1.
1.
1.
1.
1.

015
020
026
042
059







Triangle Laboratories, Inc.®  Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 11:49 01/10/98
                                                                            54

-------
  Page No.
  01/10/98
Listing o« T980152B.dbf
Hatched OC Peaks / Ratio / Ret.  Time
  Compound/
  H_Z.... QC.Log Omit Why ..RT.
     OK Ratio Total.Area. ..  Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
13C12-HpCDF
418-420








418-420

HpCDD
424-426





424-426
13C12-HpCDD
436-438


436-438
OCDF
442-444




















DC

DC
DC
DC
DC
DC

DC



DC
DC
DC
DC
DC
DC


DC




DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

NL

SN
SN
SN
SN
SN

SN
2


NL
SN
SN
SN
SN
WH
P

NL


,2

NL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN

0:00
35:39
36:22
36:37
36:47
36:51
37:17
37:36
38:12
Peaks


0:00
36:20
36:32
36:59
37:04
37:39
Peaks

0:00
36:17
37:04
Peaks

0:00
35:29
35:37
35:49
36:15
36:39
37:03
37:13
37:39
37:42
37:51
38:08
38:40
39:05
39:32
39:43
40:11
40:38
40:44
40:57
0.
RO

RO
RO
RO
RO
RO




0.
RO
RO
RO
RO
RO
RO
37-0.51
0
0
0
1
0
0
0
0
0


.57
.45
.54
.34
.34
.87
.85
.45
.50


88-1.20
2
4
1
0
1
0
.50
.21
.56
.54
.51
.47
1
1,190
3
0
0
1
1
886
2
2,077
.84
.64 369.83
.21
.92
.56
.25
.14
.66 276.72
.63
.30
0.944-1.111
0
820.81 1
1
1
1
1
1
609.94 1
1

.000
.000 13C12-HpCDF 678
.011
.018
.022
.024
.036
.045 13C12-HpCDF 789
.062


IS6





SUR5


• HpCDF / HpCDD Follows -

0
0
0
0
.29
.39
.84
.55
2.06
0.71
0.976-1.006
0
0
.000
.980


0.986
0
1.
.998
.000 1234678-HpCDD

AN
1.016
0.00
0.
RO



0.
RO
RO

RO
RO
RO
RO
RO

RO
RO
RO
RO

RO
RO
RO
RO

RO
38-1.20
2,
0.
1.

.72
.93
.01

0.38
21.86 10.54
1,499.
1,521.
u^/~nr
.74 752.23
.60
76-1.02
1,
0.
0.
0.
0.
0.
1.
2.
0.
1.
.08
.32
.89
.59
.38
,72
,03
20
.78
73
1.42
0.
2.
1.
0.
1.
0.
0.
0.
5.
52
20
01
40
10
46
55
36
63
0.
0.
1.
1.
0.
0.
3.
1.
2.
1.
1.
1.
0.
1.
0.
1.
0.
0.
1.
0.
.93
74
,02
.08
76 '
91
21
02
14
04
21
19
93
75
89
97
36
66
64
15
0.973-1.027
0.000
11.32 0.979
747.51 1.
U frt 1 1 m~»<*
,000 13C12-HpCDD 678

IS7

0.902-1.098
0.000
0.867
0.870
0.875
0.886
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
896
905
910
920 •
921
925
932
945
955
966
971
982
993
996
001















Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 11:4iCgyi 0/98
                                                                              vJ vJ

-------
 Pag* No.     6           Listing of T9801S2B.db£
 01/10/98                 Matched 
-------
rile:T9B01S2  #1-810 Acq: 6-JAN-98  15:20«28 EH- Voltage  SIS 70T Noise: 780
303.9016 T:2  3SU3(256,30, -3.0) PXD(9,S,5, 0.05%,3120. 0,1.00\,T,T)  Sxp:SDBSUS
TSIANGLE LABS  Text:TLI»44376 TLI XAD BLANK                  Ujj-.  JXME -
i003\                                                      A9.75E4
          23:00             24:00             25,00             25:00
r±la:T930152  #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS  70T Noiaei484
305.8987 F:2  BSUB(2S6,30,-3.0) PXD(9,5,5, 0. 05\r 1936.0,1.00\,r,T)  SxpiNDBSUS
TSIANGLE LABS  Text:TLIt44376 TLI XAD BLANK                 ZKT.  TIME -   15:23
100*                                                      AI.2125
                                                                                    27<00
                               •00             25:00             25:00
rile:T980152  #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage  SIR  70TNoiae:600
315.9419 F:2  BSU3(256, 30,-3.0) PKD(9,5,5, 0. 05\,2400. 0,1.00\,F, T)  Exp:NDBSUS
TRIANGLE LABS  Teit:TLI»44376 TLI XAD BLANK                  I1TJ.  TIME -   15:23
1004                                                      A1.Q9E7

  aol

  60:

  40:

  20:
                                                                                    27-00
  OJ
                            24:00             25:00             25:00
rila.-r580152  #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS  70TNoiae:359
317.9389 F:2  BSUB(256, 30,-3.0) PKD(9,5,5, 0.051,1436.0,1.00\,r,T)  Exp-.NDBSUS
TRIANGLE LABS  Text:TLI»44376 TLI XAD BLANK                 ISJ.  TIME -   15:23
1003,                                                      A1.15E7

 80:

 sol
 20j

   0.
                                                                                    27-00
          23l-00              24iOO             25 .-00             25.-00              271-00
File:T9a0152 #1-810 Acq: S-JAN-98 15:20:28 EI+ Voltage SIR  70T
330.9792 F:2 Exp:NDBSUS
TRIANGLE LABS  Text:TLI»44376 TLI XAD BLANK                 IKT.  TIME -   15:23
J00^-~        'f^2is2t—~^—'-- ---'- ZJ'jSis^-iiS^   _ 3S:-23,   r._r—J-^^3£(*B    26:47 *Zi£?
  80:       —"^                                                            "~   '

  50:

  40:

  20:

   OJ	
          23:00             24:00             25:00             25:00
File:T9801S2  #1-810 Acq:S-JAN-98 15:20:28 EI+ Voltage SIS 70T
375.8364 F:2  Exp:NDB5aS
TRIANGLE LABS  Tftxt:TLIf44376 TLI XAD BLANK                 HKT. TIME
1003\
                                                                   26:06
                                                              25:48
                           «:55  |        34:45       35,33
                                                                                    27:00
                                                                             15:23
1
"
40J
 20:
    22:41
              23 1 1;
                             i    i           •         »^ • »*     i     i

                         1 ita It   Inl iu  1   Hi  n   1 ^^;"il J     i 1 n ll  ill
                                                                                                       _2. 7X4
                                                                                                       .0.020
                                                                                                           Timel
                                                                                                        .2. 725

                                                                                                        .2.225

                                                                                                        .1. 525

                                                                                                        .1.125

                                                                                                        5.525

                                                                                                        0.020
                                                                                                           Time\



                                                                                                        3.725

                                                                                                        3.025

                                                                                                        2.225

                                                                                                        .1.525

                                                                                                        .7.425

                                                                                                        0.020
                                                                                                           Tiae\
          2300
                            241 00
                                               2StOO
                                                                 25oO
                                                                                    27-00
.1.527

.1.127

.7.425

.3.725

.0.020
    Xunel



5.523

.5.323

3.323

.2.523

.1.323

.0.020
    Tlael

-------
rHe:T980153 #1-810 Acq:6-JAN-98 15:30:28  EI+ Voltage SIS 70T NoiaetlSO
319.8965  F:3 BSUB(356, 30, -3. 0) PKD(7,5,3, 0. 05%, 720.0,1. 00\,T,T) ExpiSDBSUS
TSIANGLE  LASS  Text:TLIf44376 TLI XAD BLANK                 uu. TIME
1003k             -     .1   , .                 II          Al. 3E4
                                                                      .91E3
us
15:23
A1.11E4

1 111 JljJjttlJ
JWJWIw
77:00
75
15i33
S4
A2.90E3 A1.15E4
hi i
MJA \h m
WMl/Mh

27:00
SUS
15:33




27:00
SUS
15:23




271-00
SUS
15:33




27:00 	
15:23
7 Z^^-^kZLJZjSijt




37'tOO
7.4E3
'-.5.9X3
.4.4E3
•.1.5E3
Tiae
-5.1E3
.4.1E3
.3 . OE3
.2.013
.1 . OE3
• O.OEO
Tiae
-3.3E6
.2.5E6
.1 . 9E6
.1 . 3ES
.6.3E5
'•O.OEO
Tiae
.4.1E6
.3 . 3E6
-3.SE6
.1 . 6ES
.8.3E5
O.OEO
Tiae
.5.0ES
.4.0E6
.3 . OE6
.3.0ES
.1 . OE6
O.OEO
Tiae
.1 . BE7
.1.5E7
.1.1E7
.7.3X6
.3 . 7X6
O.OEO
Tiae
      34:00                  35:00                  36:00
rile:T980153  tl-810 Acq:6-JAN-98 15:20:38 Eli-  Voltage SIS 70T Noise 124 8
331.8936 f:3  BSU3(356, 30, -3.0) tXD(7,Sf 3, 0. 05\,992.0,1.00\,r, T) EzpiBDBSUS
TRIANGLE LASS  Text:TLIf44376 TLI XAD BLANK                 XK7. Tim
1003,                                        A1.86E4        A1.93E4
      34:00                  35:00                  36:00
rile:T980153  #1-810 Acq:6-JXN-98 15:30:38 EI+ Voltage SIS 70T Koiae:2041
331.9368 T:3  BSUB(356, 30, -3. 0) PKS(7,5,3, 0. OS\,8164.0,1.00\,r,T)  Exp:XDB5US
TRIANGLE LABS  Text:TLH44376 TLI XAD BLANK                  INJ.  TIME
1001

  aol

  601

  401

  301

  OJ
      24:00                  25:00                  25:00
Wle:T5fl0152 #1-810 Act?:6-JAN-98 15:30:38 EI+ Voltage  SIX  70T Noiae:967
333.9338 T:3 BSUB(356,30,-3.0) PKD(7,5,3,0.051,3863.0,1.00\,r,T)  Exp:NDB5US
TRIANGLE LABS  Text:TLI#44376 TLI XAD BLANK                  INJ.  TIME
1003
 aol
 sol

 401
 20:

  OJ
A1.48E7
   \A1.33E7
      J\.
      34:00                  35:00                  36:00
rile:T980152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS  70T Noiae:368
327.8847 T:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1473.0,1. 00\,T, T) Eip-.NDBSUS
TRIANGLE LABS  Text.-TLJ*44376 TLI XAD BLANK                 INJ. TIME
lOOi                                                       A1.85E7

 aol

 sol

 40.

 301

  0.
      34:00                  35:00                  36:00
rile:T980152 # 1-810 Acqs6-JAN-98 15:30:38 EI+ Voltage SIS  70T
330.9793 F:3 Exp:NDS5US
TSIANGLE LASS  Text:TLIf44376 TLI XAD BLANK                 XI
                                     25:22  25:41 25:55  26,13         36:47
                                                             A —— * — -*~
 80.

 60:

 40.

 20:

  0:
      24:00
                             35100
                                                    36s 00
                                                                                                     58

-------
ri2a:T980152 #1-810 Aeq-.S-JJOt-aa 15:20:28  XI+ Voltage SIS 70T Noiaa:221
339.8597 T:2 BSUB(256,30, -3. 0) PKD(7,5,3,0.05\,884.0,1.00\,r,T) Exp:BDB5US
TRIANGLE LASS  Tej[t:TLI#44376 TLI XAD BLANK                 HKT. njJF -   15,23
              28:00                   29:00                  30,00
FU.eiT9S01.53 #1-810  Aeg:6-JJUT-98 15:30:20 SI+ Voltage SIX 70T Noise:283
341.8567 t:2 3SUB(256,30, -3.0) PXD(7,5,3, 0. OS\r1152. 0,1.00\,r,T) Ezp:NDB5US
TRIANGLE LASS  Text:TLIf44376 TLI XAO BLANK                 UKT. TIME -   15:23
IOCS                         A1.64E4
                                                                                   31:00
              28': 00                  29:00                  30:00
File:T980152 #1-810 Acq:S-JAN-98 15:20:28 EI+ Voltage SIR  70T Noise: 139
351.9000 T:2 BSUB(256,30,-3.0)  PKD(7,5, 3, 0. 05\,55S. 0,1. 00\,f,T) Ezp:NDB5US
TRIANGLE LABS  Tezt:TLI»44376 TLI XAD BLANK                  ZKT.  TIKE -   15:23
1004                                   .         A1.28E7        A1.2SE7
 80:
 SO:
 40:
 20:
  ol	i	
                                                                                   31:00
                            Al.OSES
              28:00                  29:00                  30:00
rile:T980152  11-810 Acq:6-JAN-98 15:20:28 EI+ Voltage  SIR  70T Noiaei96
353.8970 T:2  BSU3(256,30,-3 .0) PKD( 7,5, 3, 0. 05%, 384. 0,1. 00%,J, TJ  Exp-.lWBSUS
TRIANGLE LABS  Text:TLI#44376 TLI XAD BLANK                  INJ.  TIKE -   15:23
                                                                                   31: 00
1003
 80J
 sol
 401
 201
  oJ
                                               A3.
                                                   45ES
                                                               A8.26ES
                                                 j  L
              28:00                  29:00                  30:00
rile:T980152  #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR  70T
330.9792 T:2  Ezp-.NDBSVS
TRIANGLE LABS  TeJCt:TLI#44376 TLI XAD BLANK                  JK7.  TIME •
                     8-.1S                          -           3o-.os
                                                                                   31:00
  80:
  60:
  40:
  20:
  ol
                                                                            15:23
                                                                      0:23  30:42
                                                                                             31:26
              28:00                  29:00                  30:00
rile:T980152  #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR  70T
409.7974 f:2  Exp:HDB5OS
TRIANGLE IA3S Text:TLI«44376 TLI XAD BLANK                 HKT.  TIME
1003,
                                                                                   31:00
 80:
 so:
 40:
 20:
  o:
         27:47
                           28:34
                                                                           15:23
                                                                       30:29
                                                                 30:14
                                    28:57
                                                                                           31121
                                                 29:31
                                                          29:54
                                                                                 30:55
              28:00
                                     29\00
                                                            30\QO
31\00
                   .O.OEO
                       Tim:
                   r1.0E4
                   18.1E3
                   '-6.1E3
                   ''.4.0E3
                   '.2.0E3
                   •.O.OEO
                       Time


                    3. 8E6
                   .3.0E6
                   -2.3E6
                   _1.5E6
                   '-7.SES
                                                                                                      .O.OEO
                                                                                                          Time
.2.6E6
.2.0E6
.1. 5E6
.1. OE6
.5.1ES
.O.OEO
    Time


.1. 8E7
.1.4E7
.1. 1E7
.7.0E6
.3. 5E6
.O.OEO
    Tiae


8.4E3
6.7E3
5.0X3
3.3E3
1. 7X3
0.0X0
    T±ae
                                                                                                      5S

-------
r2.J.e:T9B0152 #1-010 Acq:6-JMf-na 15:20:28 SI+ voicag-e SIS 70T HoiaetSOO
355.8546 T:3 BSOB(256,30, -3.0) PXD(7,S,3,0.05\,2000.0,1.00\rr,T)  SxptODBSUS
TRIANGLE LASS  TextsTLH44376 TLI XAD BLANK                 1ST.  TIME -   15t23
1001
       28:43 29:00  29:12 29:24  29:36 29:48  30:00  30:13 30:24 30:36 30:48  31:00  31:12
rile:T9S0152 #1-810 Act;:6-JAN-98 15:20:28 SH- Voltage SIS 70T Wolfe:215
357.8516 T:2 BSUB(256,30, -3. 0) PXD(7,5,3, 0.05%, 8tfO. 0,1.00\,T,T) XxpsODBSUS
TRIANGLE LABS  T&zt:TLH44376 TLI XAD BLANK                 1ST. TIME'    15:23
                                                                                                 2.9E6

                                                                                                 .2.3E6

                                                                                                 '.1. 7E6

                                                                                                 '.1.2E6

                                                                                                 '.5.8E5
       28:48 29:00  29:12 29:24  29:36 29:48 30:00  30:12 30:24 30:36  30:48 31:00  31:12 31:24
TilesT980152 #1-810 Acq: 6-JAJT-98 15:20:28 EI+ Voltage SIS 70T So±ae:13S
367.8949 f:2 BSUB(256,30, -3.0)  PKD(7,5,3,0.05l, 540.0,1.00\,r,TJ Exp:NDBSUS
TRIANGLE LABS  Text:TLI#44376 TLI XAD BLANK                 ISO: TIME -   15:23
IOCS                                           •             A9.26E6

 80.

 60.

 40.

 20.
                                                                  .92E5
                                                                                                .O.OEO
       SB':4a 29:00  29:12 29:24  29':36 29':43 30:00  30:12 30:24 30:36  30:48 31:00  3l':12 31:24'    Time
rila:T980152 #1-810 Actj:6-JAN-98 15:20:28 SI+ Voltage SIS 70T Otaiae:93
369.8919 F:2 BSOB(256, 30,-3.0)  PKD(7,5,3, 0.05%,372.0,1.00\,T,T) Exp:NDB5nS
TRIANGLE LABS  Text:TLI#44376 TLI XAD BLANK                 JJKT.  TIME -   15:23
                                                            A6.J. E6                             _1.8r5

                                                                                                 1.5E6

                                                                                                 1.1E6

                                                                                                 7.4E5

                                                                                                 3.7E5

                                                                                                 O.OEO
 80.

 60.

 40.

 20.
       28:43 29:00  29:12 29:24 29:36 29:48 30:00 30:12  30:24 30:36  30:48 31:00 31:12  31:24
r±latT980152 tl-810 Ac
-------
r±le:T980152 tl-396 Acq:6-JAN-98 I5:20i2a EI+ Voltage SIS 701 Noise1530
373.8208 T:3 BSOB(256, 30, -3. 0)  PKD(7,S,3,0 .OS\,2120.0,1.00\,T,T) Exp-.SDBSOS
TSIANGLE LASS  TuxH:TLH44376 TLI XAD BLANK                 JK7. TIME -   15i23
1003i                              A1.36E4
        32': 00                          33:00                         34:00
rile:T9B01S2 tl-396 Acq:6-JAN-96 15:20:28 EI+ Voltage SIS 70T Sola*1329
375.8178 T:3 BSOB(256,30, -3. 0)  PKD(7,5,3, 0. 05\,1316.0,1. 00%, f,T) Exp:NDB5US
TSIANGLE LABS  Text:TLIf44376 TLI XAD BLANK                 HOT. TIME -   15:23
100*                               A9.27X3
                                                                                                      .5E3

                                                                                                      .8X3

                                                                                                      ,1X3

                                                                                                      .4X3

                                                                                                      .7X3

                                                                                                      .OEO
                                                                                                       Tine
        32:00                          33:00                         34:00
r±le:T980152 tl-396 Acq:6-JAN-98 15:20:28 EH- Voltage SIS 70T No±ae:823
383.8639 F:3 BSUB(256,30,-3.0)  PKD(7,5,3,0.OS\,3292.0,1.00\,r,T) Exp:XDB5US
TRIANGLE LABS  Tejct:TLI#44376 TLI XAD BLANK                 Utt. TIME -   15:23
1001,                                 A6.5SE6         A6.f3E6
 80:

 60:.

 401

 201
                                                                            A5.34E6
        32:00                          33:00                         34:00
rile:T930152 tl-396 Acq: 6-JAN-98  15:20:28 EI+ Voltage SIS 70T Noiae: 1393
385.8610 f:3 BSOB(256,30,-3.0)  PKD( 7, 5, 3, 0. 05\,5572. 0,1. 001,T, T) Exp:NDB5US
TSIANSLE LABS  Text:TLI»44376  TLI XAD BLANK                 IKT. TIME -   15:23
1003

 80:
 40:
 20:
  0:
                                    A1.24E7
                                                    A1.29E7
                                                                             Al.05E7
        32:00                          33:00                         34:00
File:T980152 tl-396 Acq:6-JZN-98  15:20:28 EH- Voltage SIX 70T
392.9760 7:3 Exp-.NDBSUS
TSIANGLE LABS  Text:TLIt44376  TLI XAD BLANK                 ZK7.  TIME "   15:23
100$      32:04 32:16       32:39     32:5733:08            33:_43.  33:59 34jl_Q .

  80J

  50:
 ao:
  o:
                                                                                           34:45
        32:00                          33:00                         34:00
rile:T9801S2 tl-396 Aeq:6-JAS-9B  15:20:28 EI+ Voltage SIS 70T
445.7555 F:3 Exp-.XDBSUS
TSIANGLE LABS  TeJCt:TLIt44376  TLI XAD BLANK                 IRJ.  TIME -   15:23
80:
50:
40:
201
                                                 33
      ""
                    ""
                               "<5
                                        ""
                                                    20
                                                        I  ».«    I   |jj«        I               •
        32:00
                                      JJtOO
                                                                     34:00
                                                                                                        OEO
                                                                                                         Time
OE6

6E6

2E6

9E5

OE5

OEO
 Time



9E6

1E6

3E6

6E6

8E5

OEO
 Time



3E6

6E6

OE6

3E6

7E6

OEO
 Tiae



1E1

7S3

5E3

3E3

2X3

0X0
 Mae

-------
       32:24    32:36    32:48   33:00   33:12    33:24    33:36   33:48   34:00
r±10:T9801S2 #1-396 Actj:6-JAtt-98  15:20:28 EI+ Voltage SIX 701 Noiae:706
401.8558 T:3 BSU3(256,30, -3. 0) PKD(7, 5,3, 0. 05^,2824.0,1.00\,T,T) Eip:HDS5VS
TRIANGLE LASS  Text:TLIt44376 TLI XAO BLANK                 ZK7. TIKE -   15:23
1004                                                                   A1-11E7
              l-lS6 Acq:6-JAH-98 15:20:20 Sir  VoJ.tM3 3SUS(256,30,-3.0)  PXD(7,3,3, 0. 05\,1820.0,1.00\,T,T)  Exp:SDBSUS
TSIASGLS LASS  Taxt:TLH44376 XL! XAD BLANK                  ZK7.  TTHX -   15>23
1001                    A3.49X4
  80.
      32:24   32:36   32:48    33tOO   33tl2    33:24    33:36   33:48   34:00
T±le:T9801S2 tl-396 Acq:6-JXS-98 15:20:28 XI+ Voltago SIX 70T Soiae:435
391.8127 Tt3 aSV3(256,30,-3.0) PKD(7,5,3,0.05\,1740.0,1.00\,r,T) XzpsSDBSOS
TSIANSLX IABS  Teit:TLIf44376 TLI XAO BLANK                 HKf. TIMX -   15:23
1001,                    A3. J.8X4
                                                                                34:12   34:24
  80.

  60.

  40.

  20.
                                                                         A6.48X3
                                                                     AS.16X3
                                                                                    A7.97X3
                                                                                34:12    34:24
 80.

 60.

 40.

 20.
                                                          A9.16E6
        ~r
                T"
                                         ' I
                                                  I
                                                                          i
      32:24    32:36    32':48    33:00   33:12    33:24    33:36    33:48    34:00
r±le:T980152 »l-396 Acq:6-J7OT-98  15:20:28 EI+ Voltage SIX 70T Noiaa:384
403.8529 T:3 BSUS(256, 30, -3. 0) PXD( 7, 5, 3, 0. 051,1536. 0,1 . 00\,T, T) Exp:XDB5US
TRIANGLE LABS  Text:TLI»44376 TLI XAD BLANK                 IXT. TIMX -   15:23
1001                                                                   A9.63E6
                                                                                34:12   34:24
 80.

 60.

 40.

 20.
                                                         A7.79E6
      32:24   32:36    32:48    33:00   33:12   33:24   33:36    33:48    34:00
Tile:T980152 tl-396 Acq:6-JAN-9S 15:20:28 XI+ Voltage SIS 70T
392.9760 P:3 Xxp:m>BSOS
TRIANGLX LASS  Text:TLI144376  TLI XAD BLANK                 XK7. TIME •   15:23
                                                                                34:12   34:24
100%

 80.

 60.

 40.

 20.

  0.
                32:39
                             32:57  33:08
                                                33:25
..9.0X3

.7.2X3

.5.4X3

.3.6X3

.1.8X3
                                                                                                 .0.0X0
                                                                                                     Tia>
                                                                                                  3.2E6

                                                                                                 .2.5E6

                                                                                                 .1. 9E6

                                                                                                 .1.3X6

                                                                                                 '.6.3ES
                                                                                                 O.OEO
                                                                                                    Time
      32:24  ' '32:36  ' '32:48    33:00   33:12   33:24   33:36   33':48   34\6o  '  34:12   34:24
.2.7X6

.2.2X6

.1. 6X6

.1. 1E6

.S.4E5

.0.0X0
    Tiae



.8.2X6

.6.6X6

.4.9X6

.3.3X6

,1. 6X6

.0.0X0
    Tiae
                                                                                                        62

-------
rile:T980152  tl-563 Acq:6-JZN-98 15:20:28 EI+ Voltage SIS 70T Noiaei231
407.7818 f:4  BSOB(256, 30, -3. 0)  ?KD(7,S, 3, 0. 05%, 924. 0,1.00\,r,T) Exp-.BDBSUS
TRIANGLE LASS  Text:TLIi44376 TLI XAD BLANK                 J3K7. TIKE -   15:23
      3S':00   36':12    36:24   36:36    36:48   37:00    37:12   37:24   37:36
rile:T980152  tl-563 Acq:6-JAN-98 15:20:28 XI+ Voltage SIS 70T Noise:273
409.7789 f:4  BSUS(25S,30, -3. 0)  PKD(7,5r3f0.05\r1092.0,1.00\,r,T) Xzp:NDB5US
TRIANGLE LABS  Text:TLI#44376 TLI XAD BLANK                 DCT. HUE -   15:23
1001
                                                                                                       O.OEO
                                                                                 37:48    38:00    38:12  Tiae
      36\00 '  'j'tflii  ' '36':24    36:36   36:48   37:00    37:12   37:24   37:36
rlle:T9801S2  #1-563  Acq:6-JAN-98 15:20:28 EI+  Voltage SIS 7 OT Noise -.36 5
417.8253 F:4  BSUB(256, 30, -3. 0)  PKD(7,5, 3, 0. 051,1460. 0,1. 00*,r,T) Exp:NDB5as
TRIANGLE LABS Text:TLI*44376 TLI XAD BLANK                 JKT. TIME -   15:23
1001A3.70E6
                                                                                 37:48
                                                                                          38:00
 80:

 50:

 40J

 201
                                                                        A2.77E6
                                                                                                   38:12  Tiae
                                                                                                     9. SE5

                                                                                                     •.7.6ES

                                                                                                     '•.5.7E5

                                                                                                     .3.8E5

                                                                                                     .1.9E5
                                                                                                       O.OEO
      36:00   36:12    36:24    36:36    36:48   37:00    37:12   37:24   37:36
Tile:T980152  tl-563 Acq:6-JAN-9S 15:20:28 Eli-  Voltage SIR 70T Noise:638
419.8220 F:4  BSUB(256, 30,-3 . 0 )  PKD(7, 5,3 , 0 . 051,2552.0,1.00\,r,T) Elp:lO3BSUS
TRIANGLE LABS Text:TLI144376 TLI XAD BLANK                 INJ-. TIME -   15:23
100i.Aa.21E6
                                                                                 37:48
                                                                                          38:00
 80:

 SO:

 
-------
   36:12 36:18 36:24  36:30 36:36 36:42  36:48 36:54 37:00 37:06 37:12 37:18 37:24  37:30  37:36
rile:T9801S2  »l-563 Acq:6-JAN-98 15:20:26 EI+ Voltage SIX 70T Noiae:S87
435.8169 F:4  BSUB(256,30,-3.0)  PKD( 7,5,3, 0. 05\,2348. 0,1. 00\,T, T) Ezp:NDB5US
TRIANGLE LASS Teit:TLI»44376 TLI XAJ) BLANK                 UKT. TIME -    15:23
.1004                                                    A7.52E6                                 -1.7E6
rU.otT930152tJ.-56J ACtJlO-JAN-yo 1SUUIJO JUf  VOJ.tagm SIM TOT Sola*! 177
423.7766 T:4  BSUB(256,30,-3.0) PKD(7,5,3,0.03\,70a.O,1.00\tr,T) ExpiBDBSUS
TRIANGLE LABS  Text:TLIt44376 TLI XV) BLANK                 XKT. TINE "   15:23
1001
                                                                                                 -5.4E3
   36-12 36-18 36': 24  36:30  36:36 36:42 36:48  36>54 37:00 37:06 37-12 37:18 37:24 37-30  37-36
TiletT980152 tl-563 Acq:6-JlUT-98 15:20:28 EI+ Voltage SIX TOT Noise: 70
425.7737 r>4 BSDB(256,30r-3.0)  PXD( 7,5, 3, 0. 05\, 280.0, 1.00\,TtT) Xxp:SDB5US
TRIANGLE LABS  Teit-.TLIt 44376 TLI XAD BLANK                 UKT. TIME -   15:23
                                                                                                  O.OEO
                                                                                                     Ida,
100*
  80.
  60.
 40.
 20.
                                                         A1.Q1X4
                                                                                 A9.87EJ
 .2.7E3

 .2.1E3

 .1.6E3

 .1.1E3

 .5.3E2

LO.OEO
    Tia<
 80.
 60.
 40.
 20.
                                                                                                '.1. 4E6

                                                                                                .1.OE6

                                                                                                -6.8E5

                                                                                                '.3. 4E5
   36:12 36:18 36:24  36:30  36:36 36:42 36:48  36:54 37:00 37:06  37:12 37:18 37:24 37:30  37:36
rile:T980152 tl-563 Acq:6-JKN-98 15:20:28 EI+ Voltage SIX 70T Noiae:213
437.8140 T:4 3SUB(256, 30, -3. 0)  PKD(7,5,3, 0. 05*, 852. 0,1. 00\,T, T) Exp-.NDBSUS
TRIANGLE LABS  Teit:TLI»44376 TLI XAD BLANK                 TNJ. TIME -   15:23
lOOi                                                    A7.48E6

 80.

 60.

 40.

 20.
                                                                                                 .O.OEO
                                                                                                    Time
  0.
   36:12 36:18 36:24  36:30  36:36 36:42 36:48  36:54 37:00 37:06 37:12  37:18 37:24 37:30 37:36
rile:T980152 tl-563 Adj:6-JJOT-98 15:20:28 EI+ Voltage SIR 70T
430.9729 T-.4 ExptNDBSUS
TRIANGLE LABS  Toit-.TI.H44376 TLI XAD BLANK                 INJ. TIME -   15:23
1004

 80.

 60.

 40.

 20.

  0.
   36:12 36:18 36:24 36:30  36:36 36:42 36:48  36:54 37:00 37:06 37:12  37:18  37:24 37:30 37:36
                                                                                                .1. 7E6

                                                                                                .1. 4E6

                                                                                                .1. OE6

                                                                                                .6.9E5

                                                                                                .3.5ES

                                                                                                .O.OEO
                                                                                                    Time



                                                                                                .5.9E6

                                                                                                .4.7E6

                                                                                                .3.SE6

                                                                                                .2.4E6

                                                                                                ,1.2X6

                                                                                                 O.OEO
                                                                                                    Time
                                                                                                          64

-------
rila:T980lS3  »i-$63 Acq:6'-JAN-98 13:30:38  EI+ Voltage SIR 70T Soim«i366	
441.7438  F:4  BSUB(356,30, -3. 0) PXD(7,5,3, 0. 05\,1064. 0,1 .OQ\,r,T) XrpiXDBSUS
TRIANGLE  LABS  Text:TLI*44376 TLI XAD BLAHX                 JJKT. TIME -   15:33
IOOA
 901
 SO.
 701
  so
  401
                                                                  A1.94E4
                                                                        .OOE4
                                                                                             15X3
                                                                                              .tAjrtJMlU
              36:00         37': 00         38:00         39:00        40:00
File:T9a0153  tl-563 Ac
-------
rU.aiT3UUJ.5J tl-563 Acq16-JAN-*U  15120:Jo Sl-f Voltage  SIX  701 lfoiae:198
457.7377 fi4 BSVB(256, 30, -3. 0) PXH( 7,5, 3, 0.05%, 793.0, 1.00\,T,T)  ExptSDBSUS
TRIANGLE LABS  TexttTLIt44376 TLI XAD BLAXK                 HU.  HUE -   iSi23
1001         A4.07E4
  80.
  SO.
  40.
  20.
                                                                            A69S.96
         40:54         41:00         41:06         41:12         41ilB         41:24
rileiT980152 tl-563 Acq:6-JAK-9a 15:20t28 SI+ Voltage SIX  70T BOiaeiS7
459.7348  Tt4 BSUB(256,30, -3.0) PKD(7,5,3,0.051,228.0,1.00\,T,T) XxptSDBSUS
TRIANGLE  LASS  Teit:TLH44376 TLI XAD BLANK                 BET. TIME -   15:23
1004          A3.59E4
                                                                                                  -.1.1X4

                                                                                                  '.8.SE3

                                                                                                  .6.3E3

                                                                                                  -4.2E3

                                                                                                  '.2.1X3
                                                                                                  .0.0*0
                                                                                             41:30    Tia.
                                                                               41:24
         40:54         41:00         41:06         41:12         41': 13
rile:T980152  #1-563 Acg:6-JAIf-9a 15:20:28 EI+ Voltage SIX 70T Soiae:49
469.7779 F:4  BSUB(2S6,30, -3. 0) PKD(7,5,3, 0. 05\,196. 0,1. 00\,T, T) Exp:NDB5US
TRIANGLE LABS  Text:TLIf 44376 TLI XAD BLANK                 XK7. TIME -   15:23
          A1.UE7
  80.
  60.
 40.
 20.
                                                                                                  .1. 6E3

                                                                                                  .O.OEO
                                                                                             41:30    Tia
                                                                                                  -2.0E6
                                                                                                  '.1. 6E6
                                                                                                  .1.2E6
                                                                                                  -7.3ES
                                                                                                  '.3. 9E5
                                                                               41:24
         40': 54         41:00         41:06         41:12         41:18
rila:T980152  tl-563 Acq:6-JAN-98 15:20:28  EI+ Voltage SIX 70T Stiiae:50
471.7750 T:4  BSOB(2S6, 30, -3. 0) PKD(7, 5,3, 0.051,200.0,1.00\,f,T) Exp:mB5US
TRIANGLE LABS  Text:TLH44376 TLI XAD BLANK                 X2K7. TIME -   15:23
1001      A1.21E7
 80.
 60.
                                                                                                  .O.OEO
                                                                                             41': 30    Tiae
 40.
 20.
         40': 54         41:00         41:06         41:12         41:18
rile:T980152  tl-563 Acq:6-JAN-98 15:20:23  Eli- Voltage SIS 70T
430.9729 T:4  ExpiUDBSUS
TRIANGLE LABS  TejctsTLH44376 TLI XAD BLANK                 HO.  TIME -
1001                  41:00       
-------
|-U..-.|    T  :*3 •I'TQO     Dj.l. t,.
liisfc!.   i  aws.w X     rSa\ icp
Hsioht  3,59'JOlL-  Span   298 ppa

S^st&a fiis nae
Data   file res         f):
Resolution
Gro^nuater                   2
lonizaticn sode                £1"
Syitching                 VOLIRGE
tef, aasses  292.S8E5,   416,3768
            j   331
            K   332
            L   334
            ft   348
            N   342
            0   &
            P   354
            Q   356
            R   358
S
T   379
U   376
V   418
Ref, wss   416,3768     Peak top
Heicht   ,26 volts  Span   288 jp

-------
    i'TS 80152 #1-563 Acq:6-JAN-9&  15:20:28  El+lteltage  SIR ?OT
457.7377 F:4 Exp:NDB5US
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      A3.54E4                       _1.1E4
                                    _8.8E3
                                    _6.6E3
                                    _4.4E3
                                    L2.2E3
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                                        Time
   39:00                         40:00                         41:00
File:T980152 #1-563 Acq:6-JAN-98 15:20:28  EI+ Voltage SIR 70T
459.7348 F:4 Exp:NDB5US
Sample Text:TLI#44376 TLI XAD  BLANK                 INJ.  TIME =   15:23 File Text:TLI#44376 TLI»
100S.                                                       A3.30E4                       _8.5E3
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File:T980152  #1-563 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70T
469.7779 F:4  Exp:NDB5US
Sample Text:TLI#44376  TLI  XAD BLANK
100%
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       40:55
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                                 40:00
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                      _2.0E6
                      L1.6E6
                      L1.2E6
                      L7.8E5
                      L3.9E5
                      LO.OEO
                          Time
                                                                                                       CO

-------
TLI Project:      44376               Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample:   TLI XAD BLANK                     Analysis File:   X980083
Client Project: Gulp Aluminum Alloys
Sample Matrix: XAD Date Received: / / Spike File:
TLI ID: TLI Blank Date Extracted: 12/29/97 ICal:
Date Analyzed: 01/07/98 ConCal:
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a % Moisture
Blank File: X980083 % Lipid:
Analyst: KAS % Solids:
SPC2NF04
XF24087
X980080
: n/a
n/a
n/a


'Anafcte* \ , ' * '
2^,7,8-TCDF
Internal Standard
13C,2-2,3,7,8-TCDF
Recovery Standard
k'T,j-lA3,4-TCDD
Amt(rig> >^JDt^ :EMPCXvSn,:5fc*fcV ,
0.02 0.69
AitiL (ng> :: % Recovery QC Limits; - Ratio
2.9 73.0 40%-130% 0.79
Ratio
0.78
8T
*
21:29
m
21:28
8T
20:29
Flags
—
Flags
—
Flags

                    Data Reviewer..
01/11/98
                                      Page 1 of 1
             C2NF.PSR fiOl. LARS 4.10.09
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
          Printed: 13:32 01/11/98
              69

-------
  Data Review By:
                         Initial
                         £*?/
                                      Date...
                !_£.  Calculated Noise Area:   4.36
  The Total Area for each peak with an ion abundance ratio outside
  ratio, limits has been recalculated according to method requirements.
  Page Mo.
  01/11/98
Listing of  X980083B.db£
Matched GC  Peaks / Ratio / Rat.  Time
  Compound/
  H_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
TCDP
304-306 DC
DC
DC
DC
DC
DC
DC
' DC
DC
DC
DC
DC
DC

DC
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
304-30$
13C12-TCDF
316-318 DC
DC
DC
DC
DC
DC


DC
DC

DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN

SN
SN

SN
SN
SN
SN
SN
SN
SN
SN
WH
2

NL
WL
WL
WL
WL
WL


SN
SN

SN
SN
WH

0
17
17
17
18
18
18
19
19
19
19
19
19
20
20
20
21
21
21
22
22
22
22
23
23
23

:00
:06
:33
:37
:07
:S4
:S8
:08
:13
:23
:30
:44
:58
:11
:41
:52
:29
:37
:55
:01
:1S
:24
:42
:20
:27
:51
0
RO
RO
RO
RO
RO

RO
RO

RO
RO
RO
RO

RO
RO

RO
RO
RO
RO

RO
RO
RO
RO
.65-0.89
0.24
1.76
1.
35
1.15
1.
0.
1.
2.
0.
0.
0.
0.
2.
0.
1.
0.
0.
0.
4.
0.
3.
0.
0.
2.
0.
1.
05
72
15
06
77
36
96
62
00
80
41
48
69
21
18
44
08
72
43
05
27
66
Peaks

0
17
18
19
20
20
21
21
21
21
22
22
22
22

:00
:29
:29
:45
:09
:25
:28
:43
:47
:S3
:00
:06
:24
:34
0.
RO
RO


RO


RO
RO
RO
RO

RO
RO
65-
1.
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
2.
6.
0.39
16
00
82
69
60
79
79
43
01
28
61
81
30
56
1
2
1
1
6
4
5
2
8
4
3
8
0
29
2
2
33
2
2
9
0
3
4
4
0
2
62
.82
.05
.72
.96
.76
.19
.01
.32
.82
.53
.40
.02
.62
.42 13.10
.48
.28
.30 13.60
.67
.35
.75
.85
.14
.11
.67
.71
.74
.72
0.790-1.095
0
0
0
0
0
0
0
0
0
0
0
0
0
16.32 0
0
0
19.70 1
1
1
1
1
1
1
1
1
1

.000
.797
.818
.821
.844
.880
.884
.891
.895
.903
.908
.919
.930
.940
.964
.972
.001 2378-TCDP AN
.007
.021 • .
.026
.036
.043
.057
.087
.092
.111

0.953-1.047
6,
4.
4.
20,
.05
.02
.99
,42
54.13
311.
,01
6,671.69 2,943.01
16.09 7.00
9.
6.
.31
,78
26.69 11.61
5.
8.
,59
.66
5.49
0,
0.
0.
0.
.000
.814
.861
,920
0.939
0.
3,728.68 1.
16.44 1.
1.
1.
19.04 1.
1.
951
000 13C12-2378-TCDP ISO
012
015
019
025
030
1.043
1.
051
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 13:17 01/11/98
                                                                           70

-------
 Page No.     2          Listing of X980083B.dbf
 01/11/98                Matched CC Peaks  / Ratio  / Ret. Time

 Compound/
 X.Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1..  Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.

                                                                                 1.065
                                                                                 1.078
                                                                                 1.084
                                                                                 1.093
                                                                                 1.106
                                                                                 1.109
 316-318
DC
DC
DC
DC
DC
DC

WH
WH
WH
WH
WH
WH
3
22:52
23:08
23:16
23:28
23:44
23:48
Peaks
RO
RO


RO
RO

1.
3.
0.
0.
0.
2.

66
49
84
81
48
18

5
3
79
3
3
4
6,714
.12
.86
.28
.99
.56
.62
.47
                                       Above: TCDF  / TCDD Follows
 13C12-TCDD                    0.65-0.89                                     0.901-1.099
 332-334
DC
DC



DC


NL 0:00 RO
SN 19:53 RO
20:
20:
21:
SN 21:
21:
21:
12
29
08 RO
14
36 RO
58 RO
1.
1.
0.
0.
0.
0.
1.
1.
73
89
76
78
31
66
10
04
14
7
5,158
6,562
36
9
19
16
.85
.95
.35
.13
.32
.48
.88
.87


2,225.
2,866.
15.

12.
9.


85
51
80

32
94


2,932
3,695
50

11
9


.50
.62
.50

.23
.53
0.000
0.984
1.000
1.014
1.046
1.051
1.069
1.087
                                                                                       13C12-2378-TCDD IS1
                                                                                   014 13C12-1234-TCDD RSI
 332-334               5 Peaks              11,793.55
 Column Description	  "Why" Code Description	   QC  Log Desc.
 M_Z   -Nominal Ion Mass(es)     WL-Below Retention Tims Window   A-Peak Added
 ..RT. -Retention Time  (mm:ss)   WH-Above Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2  Ions      SN-Below signal to Noise Level   D-Peak Deleted
L  C    -RO=Raeio Outside Limits  
-------
             H-9B4 leg*  /-JJLH-1S9B lS,33*Oy X SI* Volbmg* 3IX AutoSpmc Boi*»>39b
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-------
Peak Locate Examination: 7-JAN-1998:16:34 File:X980083
     Experiment:XCONF_TT Function:! Reference:PFK

-------

TLI Project:      44376
Client Sample:   105-108
Cb  0
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   T9801ffc
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-1A-1D Date Extracted: 12729/97
Date Analyzed: 01/06/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF


Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

2.5
10.2
3.4
4.5
7.4
5.4
3.2
'"EMPC 48.2,,'Tv
""" 52.7 " ^*
67.9 ,/tffiy
42.9 .
19.7
12.3
0.68
11.7
1.4
1.7


175 13
469- > 2.0 9 265- 720
103 7
11.0 2
19W- -?-f 16 1260- ?i
5*T 7 Zo 15 795- >J2o
309 7 1o 12 5W > 2c?
15.3 3 19.2 rf^

0.78
1.54
1.24
1.24
1.22
1.01
0.82

1.44
1.47
1.26
1.26
1.26
1.33
1.03
1.09
0.92











26:22
30:34
33:37
33:42
34:01
37:05
40:56

29:32
30:14
32:54
33:00
33:31
34:18
36:00
37:37
41:09










i|||i|s||


oZ

QPR


SE_
E_
E_
E_


PR_





E_
SE_
QE_
	
SQE
SE
SE_
X_
                                       Page 1 of 2
                                         X237.PSR V2.01. LARS 6.10.3
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                      Printed: 09^54)1/15/98
                                              (b

-------
JLI Project:      44376
 I'lient Sample:   105-108
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:   T980153
Internal Standards
I3C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
I3Ci2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13Cn- 1,2,3 ,4,6,7,8-HpCDD
13C,-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
"CL^JJ.S-TCDD
l3C,:-2,3,4,7,8-PeCDF
13C,-l,2,3.4,7,8-HxCDF
l3Cp- 1,2.3,4, 7,8-HxCDD
13Cr-l,2,3,4,7,8,9-HpCDF

Alternate Standards (Type A>
'3C,2-l,2,3,7,8,9-HxCDF
13C,:-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,:-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt (ng)
1.7
2.7
2.9
3.3
2.9
2.2
3.1
4.1
8.8
AmL (ng)
3.7
4.0
3.8
6.3
4.0

Amt. (ng)
3.0
2.8


% Recovery
43.0
68.7
73.6
83.3
71.7
54.3
77.0
102
110
% Recovery
92.6
99.6
94.4
158
101

% Recovery
76.1
70.4


QC Limits
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
25%- 130%
25%-130%
25%- 130%
QC Limits
70%- 140%
70%-140%
70%- 140%
70%- 140%
70%- 140%

QC Limits
40% -130%
40%- 130%


Ratio
0.79
0.80
1.52
1.49
0.51
1.18
0.45
1.01
0.92
Ratio
1.52
0.53
1.19
0:44

Ratio
0.52
0.51
Ratio
0.81
1.17
RT
25:42
26:21
29:31
30:33
32:59
33:42
35:59
37:05
40:55
RT
26:22
30:13
32:53
33:36
37:36

RT
34:18
33:30
RT
26:10
34:01
Hags
Q 	
Q~

—
Flags
—
Q


Flags

—
Flags
—
                     Data Reviewer.
            01/15/98
                                         Page 2 of 2
                         X237.PSR v2.0l. LARS «.lO.OSo
Triangle Laboratories, \nc.s
801 Caprtola Drive • Durham, North Carolina 27T13
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 09:25 01/15/98

-------
Initial    .'. . .Date. . .


          _L/ilZ./£j.  Calculated Noise Area:
  Data Review By:
  The Total Area for each peak with an ion abundance ratio  outside
  ratio limits has been recalculated according to method requirements.
                                              2.00
  Page No.

  01/15/98
 Listing  of T980153B.dbf
 Matched  GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z...; QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak. 1. .  Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC NL 0:00
22:40
23:08
23:21
23:43
24:01
24:25
24:41
24:53
25:06
25:17
25:31
25:43
26:06
26:18
26:33
26:50
27:22
27:35
304-306 18 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 22:40
DC WL 23:08
DC WL 23:21
DC, WL 23:29
DC WL 23:43
DC WL 24:04
DC WL 24:25
DC WL 24:41
24:53
25:30
25:42
26:06
26:18
DC WH 27:05
DC WH 27:35
316-318 5 Peaks
0
RO






RO




RO







0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO
RO
RO

.65-0.89
2.35
0.80
0.31
0.31
0.36
0.30
0.33
0.90
0.82
0.35
0.31
0.30
0.95
0.37
0. 80
0.81
0. 82
0.80
0.79

65-0.39
1.74
2.44
4.43
2.21
1.39
2.54
1.47
2.21
1.77
2.07
1.09
0.79
1.56
1.34
2.35
1.38

0.378-1.073

19
24
24
113
73
83
61
97
63
42
40
63
50
40
7

4
1
813
2.35
,730.66
,624.80
,162.70
,145.70
,975.10
,824.10
,582.73
,515.10
,400.70
,153.30
,473.10
,393.44
,651.20
,702.10
,508.21
311.61
,713.17
,265.07
,137.79

8
11
10
52
32
38
31
43
29
18
13
34
23
13
3

2



,772.36
,028.30
,792.50
,377.40
,989.90
,058.50
,292.20
.928.30
,183.50
,822.30
,010.30
,073.50
,585.80
,132.20
,369.53
140.53
,095.99
559 . 87


10
13
13
60
40
45
34
53
34
23
22
35
27
22
4

2



,958.30
,596.50
,370.20
,768.30
,985.20
.765.60
,792.50
,586.30
,217.20
,336.00
.462.30
,815.50
,065.40
,569.90
.138.63
171.08
,617.18
705.20

0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1,
1.

0.961-











1,




2,
3.45
8.92
10.51
11.03
20.07
51.35
77.81
44.98
49 .42
60.94
69.61
.384.36
42.14
. 45.17
7.65
10.96
,102.72


























71.16
43.01
833.89
37.15
34.21














1,














34.43
39.33
050.97
23. «1
25.52



0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.

.000
.382
.900
.909
.923
.935
.950
.960
.963
.977
.984
.993
.001 2373-TCDF AN
.016
.023
.033
.044
.065
.073

-1.039
,000
382
900
909
914
923
936
950
960
963
992
000 13C12-2378-TCDF ISO
016
023
054
073


QZ
QE
QE
QSE
QE
QSE
QSE
QSE
QSE
QE
QE
' SE
QSE
QE
QE
Q
Q
Q













Q





                                      Above: TCDF / TCDD Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 09:25 01/15/98;
                                                                               78

-------
  Page No.
  01/15/98
Listing  of T980153B.dbf
Matched  GC Peaks / Ratio  / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why


  TCDD
.RT.  OK  Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.
                              0.65-0.89
                                                                          0.903-1.045
320-322













320-322
37C1-TCDD
328

















328
13C12-TCDD
332-334




332-334
PeCDF
340-342


DC NL 0:
23:
24:
24:
25:
25:
25:
26:
26:
26:
26:
26:
26:
27:
00
55
17
34
13
29
52
10
16
22
31
40
53
20
RO 1
0,
0.
0,
0.
0,
0,
0,
0.
0.
0,
0.
0.
0.
.14
.78
.77
.78
.78
.78
.77
,78
,78
,78
.78
,78
78
79
13 Peaks
3
32.139
21,103
9,007
22,731
16,407
8,655
8,081
14,079
2,106
3,636
4,020
1,243
1,217
144,429
.35
.20
.15
.22
.36
.17
.50
.92
.57
.34
.36
.79
.23
.05
.86

14,123
9.188
3,953
9,964
7,203
3,773
3,543
6,179
925
1,595
1,760
546
536


.50
.25
.61
.66
.11
.35
.83
.31
.35
.40
.69
.45
.26


18,015
11,914
5,053
12,767
9,204
4,382
4,538
7,900
1,131
2,040
2,260
696
630


.70
.90
.61
.20
.06
.15
.09
.26
.49
.96
.10
'.78
.79

0.000
0.908
0.922
0.932
0.957
0.967
0.982
0.993
0.997
1.001 2378-TCDD AN
1.006
1.012
1.020
1.037

0.924-1.076
DC NL 0:
DC WL 23:
DC WL 24:
DC WL 24:
24:
25:
25:
25:
25:
25:
' 26:
26:
26:
26:
27:
27:
27:
27:
00
55
09
17
34
01
13
29
45
52
09
22
31
43
20
32
37
43




































14 Peaks

DC NL 0:
' 25:
26:
26:
26:

00
14
10
21
40
0.65-
RO 1.
RO 0.
0.
0.
RO 0.
4 Peaks

DC NL 0:
27:
27:

00
35
51
1.32-
RO 1.
RO 1.
1.
0.89
98
95
81
30
61
3
166
531
287
66
3,263
128
90
32
63.
55.
2,262
77.
5,311.
7.
10.
7.
10.
11,399.
.44
.71
.24
.35
.98
.57
.58
.03
.21
.21
.77
.40
.49
.12
.39
93
,97
92
07




66
3,263
128
90
32
68
55
2,262
77
5,311
7,
10,
7
10.





.93
.57
.53 '
.03
.21
. 21
.77
.40
.49
.12
.39
.93
.97
.92







































0.000
0.903
.0.917
0.922
0.932
0. 949
0.957
0.967
0.977
0.982
0.992
1.001 37C1-TCDD SUR1
1.006
1.014
1.037
1.045
1.048
1.052

0.924-1.076
5.
18.
2,334.
2.428.
34.
73
30
11
19
41
5,315.01
1.78
20
12
43
2.
53,788.
1,540.
62
38
23

9.
1,264.
1,080.
14.

81
87
05
97

10.
1,569.
1,348.
24.

34
24
14
42
0.000
0.958
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.012
tf^Tflf F/-4 1 1 rtf It-


32,694.
906.

90
51

29,186.
633.
0.931-1.063

10
72
0.000
0.935
0.944
                                                                                                      SE
Triangle Laboratories, Inc.®  Analytical Services Division
801 Caphola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 09:25 01/15/98
                                                                            79

-------
  Page No.     3
  01/15/98

  Compound/
  M_2....  QC.Log Omit Why
Listing of T980153B.dbf
Matched GC Peaks /  Ratio
/ Ret. Time
.RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID..  Flags.



















340-342
13C12-PeCDF
352-354


















352-354
PeCDD
356-358





28
28
28
28
28
29
29
29
29
29
29
29
30
30
30
30
30
3.1
DC •' WH 31
:01
:11
:33
:41
:51
:04
:09
:14
:26
:32
:40
:48
:05
:14
:25
:42
:52
:09
:36
RO
RO

RO



RO











1.25
1.08
1.40
1.07
1.38
1.48
1.34
1.20
1.47
1.44
1.48
1.47
1.38
1.47
1.50
1.50
1.48
1.49
1.46
20 Peaks

DC NL 0
27:
DC SN 27:
DC SN 28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
30:
DC SN 30:
DC SN 31:
31:
31:

:00
:35
:43
:11
:33
41
51
:09
15
31
40
47
56
.13
24
53
00
08
26
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO

RO

RO
RO
RO
RO
RO
14 Peaks

DC NL 0:
28:
29:
29:
29:
29:

00
43
14
29
36
48
1.
RO
RO




.32-1.78
1.16
2.63
1.28
0.64
2.06
2.56
1.17
2.57
2.23
1.52
1.90
1.65
1.04
1.52
2.40
2.29
1.14
2.26
0.75
450.39
1.691.39
41,266.30
76,271.82
46,254.00
15,887.94
42,450.40
48,347.34
27,964.40
37,339.20
31,383.90
40,938.10
624.32
48,078.00
41,831.30
2.439.53
1,657.17
3,560.26
54.94
563,765.37

1
24
46
26
9
24
29
16
22
18
24

28
25
1

2


274.07
.028.10
,037.00
,361.30
,837.20
,473.38
,300.60
,387.60
,650.70
,006.40
,715.70
,362.30
361.81
,588.90
,071.20
,464.09
988.45
,128.34


218
952
17,229
43.312
19,416
6.414
18.149
24.530
11,313
15,332
12,668
16,575
263
19,489
16,760
975
663
1,431


.42
.37
.30
.90
.80
.56
.30
.40
.70
.80
.20
.80
.01
.10
.10
.44
.72
.42


0.949
0.955
0.967
0.972
0.977
0.985
0.988
0.990
0.997
1.001 12378-PeCDF
1.005
1.010
1.019
1.024 23478-PeCDF
1.030
1.040
1.046
1.055
1.071



SE
SE
SE

SE
SE

AN E
E
E

AN E
E
Q




0.364-1.136
1.22
50.64
4.69
2.43
28.69
, 130.66
63.32
24V58
44.47
2,670.35
43.76
62.73
5.54
2.641.13
37.54
2.52
3.47
9.77
4.41
' 5,818.14
32-1.78
1.02
1.22
1.55
1.54
1.52
1.55
2.07
49,412.09
4,801.07
29,982.10
7,403.47
20,654.24









1



1,






52.25


23.18
131.00
38.49
24.77
38.39
,609.42
32.58
39.05
3.37
,593.71
35.23


8.64
2.63


19.36




11.25
51.24
32.36
9.
17.
1.061.
17.
23.
3.
1,047.
14.


3.
3.
64
44
43
16
73
23
42
72


33
56
0.000
0.935
0.939
0.955
0.967
0.972
0.977
0.988
0.991
1.000 13C12-PeCDF 123
1.005
1.009
1.014
1.024 13C12-PeCDF 234
1.030
1.046
1.050
1.055
1.065 .









152



SUR2





>^*nn i?rti i CMJO


30,
2,
18.
4,
12,

034.30
916.34
191.90
468.33
560.60

24,660.
1.384.
11,790.
2,935.
8,093.
0.939-1.022

70
73
20
14
64
0.000
0.943
0.957
0.965
0.969
0.975

SE

E


Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:25 01/15/98
                                                                                                     80

-------
  Page No.
  01/15/98
Listing of T980153B.dbf
Matched GC Peaks /  Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log  Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1..  Area.Peak. 2. . Rel.RT Compound.Name..  ID.. Flags.


A



356-358
13C12-PeCDD
368-370












363-370
HXCDF
374-376





X




AX
M
MX
AN
M

374-376
13C12-HXCDF
384-386




30
30
30
30
30
30
:03
:16
:26 RO
:34
:39
:59
1.55
1.58
0.34
1.54
1.55
1.52
11 Peaks

DC NL 0
28
29
29
29
29
DC SN 30:
30:
DC SN 30:
30:
DC SN 30:
31:
DC SN 31:
1
:00 RO
:47 RO
:09 RO
:15 RO
:29 RO
:48 RO
:02 RO
:14 RO
:22 RO
:33
: 53 RO
00 RO
32 RO
8 Peaks

DC NL 0:
31 =
32:
32:
32:
32:
X 32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:
1.
00 RO
57
05
14
22
31'
44 RO
54
00
07
19
26 RO
31 .
14 RO
13
23
47
.32-1.78
1.20
3.01
1.27
1.09
2.10
1.89
4.05
. 2.27
1.92
1.49
5.33
1.29
1.29
12
6
2
5
1
2
143










1



,393.62
,754.91
,615.81
,536.05
,245.36
,525.97
,425.19

0.99
43.73
8.24
7.04
27.57
14.33
6.04
11.55
4.32
.675.27
1.40
5.53
2.98
1,793.26
Ai^ove • PcCDD / H>
05-1.43
1.48
1.26
1.13
1.23
1.24
1.28
1.30
1.26
1.26
1.27
1.24
1.27
1.26
1.23
1.33
1.26
1.27
15 Peaks

DC NL 0:
31:
32:
DC SN 32:
32:
0.
00 RO
56 RO
05 RO
22 RO
S3
43-0.59
1.05
2.06
1.61
3.27
0.53

17,
45,
3,
4,
3,

27,
14,
2,
4,

7.,
1,

1,

133,
133.15
,101.55
,449.20 •
709.53
903 .93
149.19
698.40
385.20
162.63
616.76
266.03
621.00
080.00
155.00
363.00
324.00
302.92
990.52
7,531
4,140
1,590
3,359
756
1,585



51
5
4
22
10

10

1,001

3

r(~T^TT T?i-» 1 1 e
t>— L>±* r Oi .1 <

9, 543.
24,603.
2,044.
2,714.
1,765.
394.
15,260.
7,899.
1,465.
2 , 365 .
347.
3,950.
537.
210.
738.


.10
.58
.00
.42
.37
.56



.67
.01
.28
.68
•54.

.27

.12

.36




13
90
94
S3
64
48
60
76
07
57
00
00
00
00
00


4,362
2,614
1,890
2,176
489
1,040



17
3
3
10
5

4

674

2


.52
.33
.00
.63
.49
.41

0.

.15
.93
.94
.31
.62

.53

.15

.61


0.984
0.991
0.996
1.001 12378-PeCDD AN
1.003
1.014

869-1.131
0.000
0.942
0.954
0.957
0.965
0.975
0.983
0.990
0.994
1.000 13Cl2-PeCDD 123 IS3
1.011
1.015
1.032





a

















0.964-1.049

7,553.
20,345.
1,664.
2,189 .
1,333.
303.
12,124.
6,262.
1,151.
1,900.
274.
3,130.
513.
153.
586.



,52
30
59
30
55
92
60
37
69
46
00
00
00
00
00


0.000
0.969
0.973
0.977
0.981
0.986
0.992
0.997 123473-HxCDF AN
1.001 123678-HXCDF AN
1.004 •
1.010
1.014
1.016 234678-HxCDF AN
1.038
1.040 123789-HxCDF AN
1.042
1.055



SE




E






PR



0.879-1.121




1,
4.58
8.37
26.67
1.45
923.59

11.
•' 28.

663.

40
51

31

5.
17.

1,255.

54
66

23
0.000
0.968
0.973
0.981
0.997 13C12-HXCDF 478 SUR3





Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:25 01/15/98
                                                                             81

-------
  Page No.     5
  01/15/98


  Compound/
  M_2....  QC.Log Omit Why
Listing of T980153B.dbf
Hatched GC Peaks /  Ratio / Ret.  Tinw
.RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.






384-386
32:59
33:30
DC SN 33:46
DC SN 34:02
34:18
DC SN 34:30
6 Peaks


RO
RO

RO

0.51
0.51
0.33
3.55
0.52
0.22

2,213
2,072
2
0
1,773
4
8,017
.12
.07
.40
.63
.53
.62
.35

HxCDD
390-392







390-392
13C12-HXCDD
402-404






402-404
HpCDF
408-410

X

D
D


408-410
13C12-HpCDF
418-420




418-420

DC NL 0:00
32:25
32:52
33:05
33:16
33:37-
33:42
34:01
7 Peaks

DC NL 0:00
33:04
DC SN 33:16
33:36
33:42
34:01
34:11
5 Peaks

DC NL 0:00
36:00
X 36:16
36:26
D NH 37:06
D NH 37:21
37:37
DC WH 38:11
4 Peaks

DC NL 0:00
35:59
DC SN 36:26
37:36
DC SN 37:59
2 Peaks
1
RO








1.
RO
RO
RO



RO

0.
RO

RO

RO
RO



0.
RO

RO



.05-1.43
0.77
1.22
1.21
1.22
1.25
1.24
1.24
1.22

05-1.43
2.14
1.50
2.64
1.19
1.18
1.17
0.78

38-1.20
1.26
1.03
1.08
1.05
1.42
1.67
1.09
1.10

37-0.51
1.07
0.45
1.73
0.44
0.48

8
4,697
11,857
7,632
807
876
1,334
2,187
29,393
.74
.62
.20
.77
.28
.15
.98
.27
.27
751
701


606


.65
.34


.72


1,461
1,370


1,166


.47
.23


.31


1.000 13C12-HXCDF 678 IS4
1.016 13C12-HXCDF 234 ALT2
1.024
1.032
1.040 13C12-HXCDF 789 ALT1
1.046








"COD Frtl 1 rtu/c — _


2,584
6,494
4,187
447
484
737
1.204


.90
.05
.41
.92
.37
.95
.00


2,112
5,363
3,445
359
391
597
983

0.958-1.015

.72
.15
.36
.36
.78
.03
.27

0.000
0.962
0.975
0.982
0.987
0.998 123478-HxCDD AN
1.000 123678-HxCDD AN
1.009 123789-HXCDD AN


Q
OE
Q
Q
Q

QPR

0.970-1.030
3
14
5
1,513
1,134
2,185
10
4,913
• Mvr* n r
.81
.56
.04
.94
.11
.31
.31
.23
"\ / LJv*i

9

823
640
1,177
5

.76

.86
.10
.94
.71

6.

695.
544.
1,007.
7.

.50

.08
.01
.37
.35
0.000
0.981
0.987
0.997 13C12-HXCDD 478 SCJR4
1.000 13C12-HXCDD 578 IS5
1.009 13C12-HXCDD 789 RS2
1.014



Q
Q


f T>^ 1?— 1 1 _..._

6.
6,463.
1,911.
1.049.
15.
14.
582.
.34.
10,012.
43
11
71
37
22
93
52
48
21

3,287.

.09
990.63
536.57


303.




26



3,181.
921.
513.


' 279.


0.998-1.053

02
08
30


26


0.000
1.000 1234678-HpCDF AN
1.008
1.013
1.031
1.038
1.045 -1234789-HpCDF AN
1.061










0.944-1.111
1.
1,499.
1.
1,176.
2.
2,675.
34
56
51
39
72
95

463.

360.



35

30



1,031.

815.



21

59


0.000
1.000 13C12-HpCDF 678 IS6
1.013
1.045 13C12-HpCDF 789 SUR5
1.056







Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:25 01/15/98
                                                                             82

-------
  Page No.
  01/15/93
Listing  of T980153B.dbf
Matched  GC Peaks /  Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omic Why ..RT. OK Ratio Total.Area...  Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
HpCDD
424-426



424-426
13C12-HpCDD
436-438





436-438
OCDF
442-444































DC


DC


DC

DC

DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

DC
DC
DC
DC
DC
DC
DC
DC
DC



NL


WH
2

NL

SN

SN

3

NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN

SN
SN
SN
SN
SN
SN
SN
SN
SN



0
36
37
37

:00
:18
:05
:37
0,
RO



,38-1.20
1
0
1
1
.59
.99
.01
.19
Peaks

0
36
36
37
37
37

:00
:16
:38
:05
:23
:26
0.

RO


RO

,38
1
1
1
1
0
1
Peaks

0;
35:
35:
35:
36:
36:
36:
36:
36:
36:
37:
37:
37:
37:
37:
37:
33:
38:
38:
39:
39:
39:
39:
39:
39:
40:
40:
40:
41:
41:
41:

:00
: 16
:40
:46
02
:15
26
33
39
46
05
12
20
36
43
49
15
31
39
05
15
26
33
39
52
16
20
52
00
09
25
0.

RO
RO
RO


RO
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
RO



RO
RO
RO
RO
RO

RO


-1.20
.06
.22
.01
.01
.79
.17

1
2,335
2,247
6
4.583
.34
.78
.54
.39
.32
0.976-1.006
0
1,161.42 1.174.36 0
1.128.65 1,118.89 1
1

.000
.979
.000 1234678-HpCDD AN
.014

0.973-1.027
2
3
1
1,604
4
6
1,613
Uw/-m
.35
.08
.49
.33
.61
.15
.56
n / r\f
76-1.02
0
0
0
1
0
0
1
1
0
0
1
0
1
0
0
1
1.
1.
1,
o
0.
0.
3.
0.
0.
0.
0.
0.
1.
0.
0.
.96
.63
.42
.76
.30
.33
.12
.50
.53
.34
.21
.36
.11
.28
.26
.62
.67
.48
.07
.94
.79
.98
97
61
25
32
40
97
33
92
93
0
0
0
0
2
18
1
0
0
0
2
0
1.
0.
0.
0.
1.
1.
0.
49.
1.
0.
0.
1.
0.
0.
0.
1.
1.
715.
57.
.38
.64
.72
.64
.21
.47
.08
.72 .
.45
.93
.66
.91
.53
34
47
55
10
66
55 '
16
00
99
55
40
53
39
96
14
53
06
23
0
4.33 3.96 0
0
807.10 797.23 1
1
3.32 2.83 1

.000
.978
.988
.000 13C12-HpCDD 673 IS7
.008
.009

0.902-1.098
0
0
0
0
0
0
0
0'
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
23.82 25.34 0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
343.02 372.04 1.
27.60 29.63 1.
.000
.362
.372
.374
. 381
.886
.390
,393
.396
399
906
909
912
919
922
92-1
935
941
945
955
959
964
967
969
974
934
986
999
002
006 OCDF AN
012
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:25 01/15/98
                                                                                                      83

-------
  Page No.
  01/15/98
         Listing of T980153B.dbf
         Hatched GC P«aks  /  Ratio
/ Ret.  Time
  Compound/
  M_2.... QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak. 1.. Area.Peak.2. .  Rel.RT Compound.Name..  ID.
                                                                                           Flags.
  442-444
                 DC  SN  41:39 RO  0.61
                 DC  SN  41:50 RO  0.49
                 DC  SN  41:56     0.76
                    .   3 Peaks
                                2.06
                                2.51
                                1.37
                              821.45
                               1.018
                               1.022
                               1.025
  OCDD
  458-460
  458-460
               0.76-1.02
DC  NL   0:00 RO  0.73   .        0.34
        40:56     0.82       1,055.02
DC  SN  41:16 RO  1.29           3.57
DC  SN  41:30 RO  0.68           2.48
      1 Peak                1,055.02
                                                            476.03
                           0.902-1.098
                               0.000
                       578.99  1.000 OCDD
                               1.009
                               1.014
                                                                                                       AN
  13C12-OCDD                     0.76-1.02
  470-472         DC  NL   0:00 RO  1.29           0.26
                         40:55     0.92       2.360.58
  470-472.               1 Peak                2,360.58
                                         1,131.89
                                                             0.998-1.006
                                                                0.000
                                                       1.228.59  1.000  13C12-OCDD
                                                                                      I S3
 Column Description.
                "Why" Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time (mm:ss)
 Rai.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
  *** End of Report **"
                WL-Below Retention Time Window
                WH-Above Retention Time Window
                SN-Below Signal to Noise Level
                
-------
riJ.e:T980153 #1-8.10 Acq:6-J3Uf-98 L6sOSs09  EI+ Voltage SIS 701 NO±3fsl895
303.9016 T:2 BSUB(2S6, 30, -3. 0) PKD(9,5,5, 0. 05\, 7580.0,1. 00\,T,T) XxptNDBSOS
TSIANGLE LASS  Text:TLI#44376 105-108                        fcxT. TIME -   16:09
1001
 80:
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 40:
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  OJ
                      A5.24EB
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           A1.10E8
          23:00
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TSIANGZE LASS  Text:TLIt44376 105-108
100}
 80:
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  ol
                      A6. Q.8X8
                           A4.10E8
           A1.36E8
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                                                              f,T) Sxp:XDBSVS
                                                              |HK7. TIME -   161 09
                                                               8E8
                                                                      2.26E8
                                                                          \4.14E7
                                                                                         A2.62E7
                                                                                        	A  _
          23': 00             24:00           .   25': 00          I  2^1-00              27:00
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TRIANGLE LABS  Text:TLI#44376 105-108                        fo*7.  TIKE -   16:09
1003*                                                      A8.?4E6
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          23': 00  '           24':00              25:00
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TRIANGLE LABS  Text:TLI#44376 105-108
1004
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                                                                 26:00
                                                              IT Noise:973
                                                                T) Exp:NDB5US
                                                              INJ-. TIME '   16:09
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                            24': 00
                                               25': 00
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TRIANGLE LABS  Text-.TLIt44376 105-108
1004
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                     23:36
                              24
          23': 00             24:00              25:00
\File:T980153 #1-810 Acq:6'-JAN-98 16:06:09  EI+ Voltage SIS 7i
J75.8J54 F:2 Exp:NDB5aS
TSIANGLE LABS  Tejct:TLIt44376 105-108
  80:
  60:
  40:
  20:
  o:
                                                                26:00
                                                              INJ.  TIME
                                                               25:53
                                                                                   27:00
                                                                  16:09
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                                                                                                       .O.OEO
                                                                                                          Time


                                                                                                       3. OE6
                                                                                                       2.4E6
                                                                                                       1.8E6
                                                                                                       1.2E6
                                                                                                       5.9ES
                                                                                                       O.OEO
                                                                                                          Time
                                                                26:00
                                                              T
                                                              ZKT.  TIME
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                                                                                   27:00
                                                                             ».«
          23 • 00
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                                                                26:00
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                                                                                                        85

-------
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TRIANGLE LASS TextsTLIt44376 105-108
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TRIANGLE LABS Text:TLIf 44376 105-108
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' 27:00 	 Tiae
Wle:T980153 tl-810 Acq:6-JAN-98 16:06:09 EH- Voltage SIR 70T Noise: 3203
331.9368 T:2 BSUB(256, 30, -3. 0) PXD( 7,5, 3, 0. 051,12812. 0,1 . 00\,F,T) Xxp-.NDBSUS
TRIANGLE LABS Text:TLI*44376 105-108
1003
80:
50:
40:
20:
o:
:





INJ. TIME • 15:09
A1.2SE7
Wl . 08E7
ft


/ U I
241-00 ' 25: 00 ' ' 251-00
3.6X6





.2.9X6
'•.2.2X6
.1.4X6
.7 .2X5
O.OEO
27:00 	 Tiae
Wle. -T9 8 01 53 #1-810 Acq:6-JAN-98 16:06:09 El + Voltage SIR 70T Noise: 1619
333.9338 T:2 BSUB(2S6, 30, -3 .0) PKD(7,5, 3, 0. 05%, 5475.
TRIANGLE LABS Text:TLI»44376 105-108 '
1001

80.
50:
40:
20:
o:



1
'


0,1.00%,r, T) Exp:NDBSUS
INJ. TIME
A1.57E7
\A1 .35E7
1



j \i V
241-00 	 251-00 ' 25:00
16:09
4.4E6







.3.6E6
.2.7E6
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.8.9E5
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27.' 00 	 Tiae
rile:T9S015J tl-810 Acq:6-JAN-98 16:06:09 Eli- Voltage SIR 70T Noiae:1719
327.8847 f:2 BSOB(256, 30, -3. 0) fJO>(7, 5,3,0 .05\, 6876.
TRIANGLE LABS Tejct:TLIf 44376 105-108
100A

80:
50:

40:
20:

0:



A3.27E7



•
'241-00 	 251-00 ' 2
rila:T980153 tl-810 Acq:6-JAN-98 16:06:09 EI+ Voltag
330.9792 F:2 XxptNDBSUS
TRIANGLE LABS Text:TLI»44376 105-108 |
1001
80:
50:
40:
20:
0-
0,1.00%,?, T) Exp:NDB5aS
INJ. TIME
AS




A2.26E7


I
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a SJB 70T

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' 16:09
11E7 ..1.5E7







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file:T980153 #1-810 Acq:6-J2UT-9S 16:06:09 XI+  Voltage SIS 70T Soiae: 793
339.8597 f:2 BSCTB(256,30,-3.0)  tXD(7, 5,3,0.05\,3172.0,1.00\,r,T)  XzptXDBSUS
TRIANGLE LASS  Text:TLI*44376 105-108                        XXJ.  TIKE -   16:09
                                                A2.20E8
100]
 80:
 50:
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                                                                 A2.S6E8
                                                                     A2.51X8
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              28:00                  29:00                  30:00
rila:T980153 #1-810 Acq:6-J3UT-98 16:06:09 XI* Voltage SIS 70T NOiae:663
341.3567 Ft2 BSOB(256, 30, -3.0)  ?KD(7,5, 3, 0. 05\,2652. 0,1.00\,f,T)  KxptNDBSUS
TRIANGLE LASS  Text:TLH44376 105-108                        HKT.  TXNZ -   16
1003
 sol
 sol
 40:
 20:
  oj
                             A4.3
                                                                 A1.9SE8
                                                                      I.68EB
              28:00                  29:00                  30:00
File:T980153  #1-810 Acq:6-JZN-98 16:06:09 EI+  Voltage SIX 70T Noiae:372
351.9000 1:2  BSUB(256,30, -3. 0) ?KD(7,5,3,0.05\,1488.0,1.00\,T,T)  Exp:NDBSUS
TRIANGLE LASS Text:TLI»44376 105-108                        IJTJ.  TIME ~   ISl-OS
 [004                                            A1.61E7

 ao-                                                            A1.59E7
 50:

 40:

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  oi_^	
                             A1.31S6
                                                                              46S7   A2.13S7
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                                                                               09
                                                                                     Al.43E7
                                                                                   31:00
              28:00                  29:00                  30:00
rile:T980153 #1-810 Acq: 6 -JAN- 9 8 16:06:09 EI+ Voltage  SIS 70T Noiae:321
353.8970 P:2 BSU3(256, 30, -3. 0) PKD(7,S, 3, 0. 051,1284 . 0,1 . 00%, f, T)  Exp:NDB5DS
TRIANGLE LABS  Text:TLI#44376 105-108                        TJVJ-.  TIME ~
lOOi                                            A1.Q6E7
                                                                                   31:00
                                                                              .- OS
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                                                                Al. 05E7
              28:00                  29:00                  30:00
F±le:T980153 #1-810 Acq: 6-JAN-98 16:06:09 EI+ Voltage SIS  70T
330.9792 T:2 Eip-.NDBSOS
TRIANGLE LABS  Text:TLI#44376 105-108                        IHJ.
                                                                   TIME
1003

 80:

 50:
 20:
  0:
      27:38
              28:00                  29:00                  30:00
Tile:T9801S3  #1-810 Acq-:5-J3UT-S8 16:06:09 XI+ Voltage  SIS  70T
409.7974 T:2  Exp-.NDBSVS
TRIANGLE LABS Text:TLIf44376 105-108                       JWJ.  TIME -
1004
 80:
 50:
 40:
 20.
  oj
                                                                   JO.-IS
              28:00
                              28:41
                                                                            /
                                     29:00
                                                            30:00
                                                                                   31:00
                                                                                   31 s 00
                                                                            15: OS
                                                                                       31:11
                                                                                   31 s 00
                                                                                                       6.3E7

                                                                                                      .5.0X7

                                                                                                      LJ.817

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-------
fU.a-.T9U01.5J #1-810 Acq: 6-JAN-yu ±6:06:09 SI+  Voltage SIS  70T Noiae:62B
355.8546 T:2 BSOB(256,30, -3.0) fXS(7,5,3, 0. 05\,2512.0,1.00\,r,T)  XxptSDBSOS
TSIAKGLS LABS  Tejct:TLIf44376 105-108                        HC7.  TIME -   15:09
1001
  80.
       28:48 25:00  23:12 29:24  29:36 29:48  30,00 30:12 30:24  30 36 30:48  31:00 31:12  31:24
rile:T980153 #1-810 Acq:6-J3UT-98 16:06:09 EI+ Voltage SIS  70T Ooije: 619
357.8516 T:2 BSUB(256r30, -3. 0)  PKD(7,5,3, 0. 05\,2476.0,1.00\,r,T)  SxptXDBSUS
TSIANSLE LABS  Text:TLIi44376 105-108                       ZMT.  TIME -    15:09
1001 A2.47E8


 80.
                                                                                                  O.OEO
                                                                                                     Tine
       28:48 29:00  29:12 29:24  29:36 29:48  30:00  30:12 30:24  30:36 30:48  31:00 31:12 31:24
rile:T980153 #1-810 Acq: 6-J7UT-98 16:06:09 EI+ Voltage SIS 70T Jfoiae:299
367.8949 T:2 BSUB(2S6, 30, -3. 0)  PKD(7, 5,3, 0.051,1196. 0,1. 00\,r,T) Sip:tlDB5as
TRIANGLE LABS  Text:TLI»44376 105-108                       IKT. TIME  »    15:09
1001                                                          A1.00E7

 80:

 50:

 40.

 20.
       28:48 29:00  29:12 29:24  29:36 29:48  30:00  30:12 30:24  30i36 30:48  31:00  31:12 31:24
rile:T9B0153 #1-810 Acq:6-JJOT-98 16:06:09 EH- Voltage SIS 70T Ifoiae:252
369.8919 T:2 BSUB(256, 30,-3.0)  PKD(7, 5,3, 0. 05%,1008. 0,1. 00\,T, T) Bxp:in)B5US
TXIANGLE LABS  Text:TLI#44376 105-108                       INJ. 1IME *    16:09
1001                                                          A6.74Z6

 so:

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 40:

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  o:
                                                                                                  o.oso
                                                                                                     Time
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.8.0E5

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       28:48 29:00  29:12 29:24  29:36 29:48  30:00  30:12 30:24 30,36 30:48 31:00  31:12 31:24
rile:T980153 tl-810 Acq:6-J3OT-98 16:06:09 EI+ Voltage SIS 70T
330.9792 T:2 Eip-.SDBSUS
TRIANGLE LABS  Text:TLIf44376 105-108                       IJTJ. TIME *    16:09
1001        28^57   29:12 29:24      ":43    30^01^30^12 30:24

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-------
File 0980153  #1-396 Acq:6-JAS-98 16:06:09 EI+ Voltage SIS 70T Koiae:43858
373.8208  T:3  BSUS(256,30, -3. 0) PXD(7,5,3,0.05\,175432.0,1.00\,T,T)
TRIANGLE  LASS  Text:TLI»44376 105-108                        ZK7. TIME -   16:09
1005      A2.4.6X8
  30.

  601

  40l

  20:
                                   Al.53X8
     A9.54E
                  A3.71X7
                                                      A4.24E7
                                                A3.37X7 A
        33:00                          33:00                          34:00
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375.8178 T:3 BSUB(256, 30, -3. 0) PXD( 7,5, 3, 0. 051,118884.0,1. 00\,f,T)  Exp-.XDBSVS
TSIANGLE LABS  Teit:TLI#44376 105-108                       ZKJ.  TIME -   16:09
1004     A3. OSES

 sol
  60l

  401
     A7.56E
                  A3.19E7
                /v y\   ^
                                                      A3.34E7
                                                Al. 90E7 /\
        32:00                          33:00                          34,00
F±le:T9a0153  fl-396 Acq:6-JTO?-98 16:06:09  EI+ Voltage SIS 70T Noiae: 1594
383.3639 T:3  BSUB(256, 30,-3 . 0 ) PXD(7,5, 3, 0. 05%, 6376.0,1.00\,F,T)  Exp:NBB5US
TRIANGLE LABS  Teit:TLI#44376 105-108                     .   HKT.  TIKE •   16:09
1003

  801

  50J

  401

  201

  0.
                                      A7.52E6
                                                      A7.02E6
                                                                              A6.07E6
        32:00                          33:00                          34:00
File:T980153  #1-396 Acq: 6-JAIT-98 16:06:09 EI+  Voltage  SIX  70T IToiae: 1514
385.8610 T:3  BSUB(256, 30, -3. 0) PKD(7,5,3, 0. 05%, 5055. 0,1. 00\,T, T)  Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 105-108                        JKJ.  TIME -   16:09
1003

  SOJ

  601

  40.

  201

  0.
                                     A1.46E7
                                         ft
                                                      A1.37E7
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        33:00                          33:00                          34:00
rile:T980153  tl-396 Ac
-------
       32:24    32:36   32:48   33:00   33:12   33:24    33:36  .33:48   34:00   34:12   34:24
rila:T980153 #1-396 Acq:6-JAN-98 16:06:09 EI+ Voltage SIS 70T No±ae:1821
401.8558 F:3 BSUB(256f 30, -3 . 0)  PXX>(7, 5,3, 0. OS\, 7284. 0,1. 00%,T, T) Exp:NDB5BS
TSIANSLE LABS  Text:TLI#44376 105-108                       INJ. TIME -   16:09
riJ.a:T980T5J #1-196 Acq:6-JAH-!tO lt>:UO:UH KI+  Voltage SIS  70T Xoiaas2421
389.8156 F:3 BSOB(256,30, -3. 0)  PXD(7,5,3, 0. 05\,9684.0,1.00\,r, T) Exp:SDBSas
TSIANGLS LABS  Text:TLI#44376 105-108                       ntj. TIME  -    16:09
1004
  80.
60.

40.

20.
A2.58E7
 A
                                 A4.19E7
                                                            7.31E6
       32:24
             32:36   32:48    33:00   33:12   33:24    33:36
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391.8127 F:3 BSOB(256,30, -3. 0) PKD(7,5,3, 0. OS\,12612.0rl .OQ\,F,
                                                                       A1.20E7
                                                                33:48
                                                                                34:12
TSIANSLE LABS  Tejct:TLI#44376 105-108
1004                    A5.36E7
                                                                T) Exp:SDB5US
                                                             1X7. TIMS
                                                                           16:09
80.

60.

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                                                           A5.97E6
                                                                       A9.83E6
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                                                       A8.24ES
       32:24    32:36    32:48   33:00   33:12    33:24    33:36   33:48    34:00   34:12   34:24
rilo:T980153 #1-396 Acq:6-JAN-98  16:06:09 EH- Voltage SIS 70T HoiaesBSl
403.8529 f:3 BSU3(256, 30, -3.0)  PKD(7,5, 3, 0. 05%, 3404.0,1. 00\,T, T) ExpsNDBSUS
TRIANGLE LABS  Text:TLI*44376 105-108                       TJfJ. TIME -   15:05
IOCS                                                                   A1.Q1E7
 80.

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                                                       A6.95E6 ;
       32:24    32:36    32:48   33:00   33:12    33:24    33:36
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392.9760 F:3 Eip:lO>B5US                                    \
TRIANGLE LABS  Teit:TLI#44376 105-108                     \
100*32:21     32,35    3a,49   _   33:04   33,U 33.35 33:34\
                                                               33:48   34:00    34:12   34:24
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                                                                  TIME -   16: 09
                                                                  33:53   34:04
                                                                                                       90

-------
nj.a:T980153 #1-563 Acq: 6 -JAW- 9 8 16:06:09 EH- Voltage
407.7318 T:4 BSUB<356, 30, -3. 0) PE}( 7,5, 3, 0. 05%, 7916.0,
TRIANGLE LABS Text:TLI#44376 105-108
1001
80:
60:
40:
20:
0'
A3 .29E7 .
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36\00 36:12 36:24 36*:36 36\48 37:00
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409.7789 T:4 BSO3(256, 30, -3. 0) PKD( 7,5, 3, 0.05%, 6292.0,
TRIANGLE LABS Text:TLI#44376 105-108
1001
80:
60:
40:
20:
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A3.18E7
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36\00 ' 36\12 ' 36\24 36\36 36:48 37\00
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417.3253 P:4 BSUB(256, 30, -3. 0) PXD( 7, 5, 3, 0. 05\,2748. 0,
TRIANGLE LABS Text:TLI»44376 105-108
1001
80:

60:
40:
20:
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'jtfl-Oo' ' '36\ia ' 36\24 36\36 36:48 37\00
rile:T9a0153 #1-563 Acq:6-JAN-98 16:06:09 EH- Voltage
419.3220 T:4 BSUB(256, 30, -3. 0) PKD(7, 5,3, 0 .051,2564 .0,
TRIANGLE LABS Text: TLI#44376 105-108
1003
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36(:00 ' '36\12 ' 36\24 36\36 36\43 J7.-00
rile:T980153 #1-563 Acq : 6 -JAN- 9 8 16:06:09 EH- Voltage
430.9729 T:4 Exp-.NDBSVS
TRIANGLE LABS Text:TLI#44376 105-108
1001
80:
60:
40:
20:
0'
36^10 36:24 36i43 36jJ3 37^
SIR 701 Soiaetl979
1.00\,f,T) XxptXDBSUS
INJ. TIME - 16:09




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37\12 37:24 37\36
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I2KT. TIME - 16:09





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INJ-. TIHE - 16:09


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TRIANGLE LABS Teit:TLI#44376 105-108
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TRIANGLE LASS Text:TLIt44376 105-109 UtT. TIME « 16:09
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Ref, aasses   292,3825,   416.3768
fl   283     J   331      6  368
B   384
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            L   334
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Sample Text:TLI#44376 105-108                       INJ. TIME =   16:09 File Text:TLI#44376  105»
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Sample Text :TLI#44376 105-108                      . INJ. TIME =
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1004                          34 U4
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1004                                                33.jL.30
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34 :32

-------

TLI Project:      44376
Vlent Sample:   105-108
Method 23 TCDD/TCDF Analysis (DB-225)
                   Analysis File:   X980084
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAIN
194-59-1A-1D
1.000
n/a
DB-225
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01/07/98
n/a
X980083
KAS
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
SPC2NP04
XF24087
X980080
: n/a
n/a
n/a

gSSSSSJSSSSi^JSSiSSSSSSSSSSS
2,3,7,8-TCDF

13C12-2,3,7,8-TCDF

13C12-1,2,3,4-TCDD



49.4

*;:*S;K;:¥*S:S:^
3.5 86.7

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20:28 	
                    Data Reviewer.
                   01/1U98
                                       Page 1 of 1
                                C2NF_PSR vXOI. LAKS S.IO.OS
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                            Printed: 13:3301/11/98
                                105

-------
                         Initial
                                      Data..
  Data Review By:
                     Calculated Noise Area:
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
                                             2.00
  Page No.

  01/11/98
Listing of  X980084B.dbf
Matched OC  Peaks  / Ratio
/ Ret.  Time
  Compound/
  M_Z	 QC.Log Omit Why  . .RT. OK Ratio Total.Area...  Area.Peak. 1..  Area.Peak.2..  Rel.RT Compound.Na
                                                                            ID..  Flags.
TCDP
304-306 DC NL 0:00
17:07
17:45
18:06
18:13
18:21
18:31
18:47
18:56
19:05
19:10
19:14
19:25
19:45
20:10
20:16
20:26
20:37
20:49
21:00
21:23
21:30
21:43
21:57
22:02
22:43
23:19
304-306 26 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 17:14
OC WL 18:49
DC WL 19:13
DC WL -19:44
DC WL 19:58
DC WL 20:10
DC WL 20:25
21:00
21:06
21:30
22:02
DC WH 23:16
0.65-0.89
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

.78
.78
.77
.78
.77
.78
.78
.78
.78
.36
.69
.78
.78
.77
.78
.78
.78
.77
.78
.77
.77
.78
.78
.77
.78
.78
.69
7
0.790-1.095
3,630.14
155,289.90
3,104.58
220,483.60
181,477.60
346,719.00
179,887.50
154,107.80
337,259.
172,637.
166,572.
441,386.
204,266.
994,948.
287,477.
49,475.
312,163.
290,393.
48,539.
409,332.
403,907.
290,292.
368,767.
448,171.
411,603 .
246,237.
42,524.
,167,526.
.00
.50
.40
00
80
00
00
40
00
00
30
00
00
00
00
00
00
00
90
28
67,903
1,352
96,370
79,156
151,477
78,779
67,358
147,338
80,046
67,981
192.338
89,524
434,202
125,570
21,730.
136,429
126,395.
21,205.
178,518.
176,299.
126,997.
161,205.
195,548.
180,201.
107,736.
17,384.

.90
.02
.60
.60
.00
.50
.20
.00
.30
.80
.00
.80
.00
.00
.20
.00
,00
.40
.00
.00
.00
,00
.00
.00
,00
,40

87,386
1,752
124,113
102,321
195,242
101,108
86,749
189,921
92,590
98,590
248,548
114,742
560,746
161,907
27,745
175,739
163,998
27,333
230,314
227,608
163,295
207,562
252,623
231,402
138,501
25,140

0.65-0.89
RO 0
RO 0
0
RO 1
RO 1
0
0
RO 1
RO 1
0
.93
.92
.73
.34
.86
.71
.85
.06
.55
.79
0.81
RO 1.29
RO 0.45
57.
79.
130.
213.
40.
206.
565.
329.
52.
26.
24,298.
80.
60.
06
28
52
81
07
31
33
30
98
87
10
96
98








46.
11.
10,895.
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43
as
00
83









29.
15.
13,403.
45.

.00
.56
.00
.00
.00
.00
.60
.00
.70
.60
.00
.00
.00
.00
.20
.00
.00
.90
.00
.00
.00
.00
.00
.00
.00
.50

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1.
1.
1.
1,
1.
1.

.000
.796
.826
.842
.847
.853
.861
.874
.381
.888
.391
.895
.903
.919
.938
.943
.950
.959
.968
.977
.995
.000 2378-TCDF AN
.010
.021
.025
.057
.084


E

B
B
E
B
E
E
E
B
E
E
E
B

E
E

E
E
E
E
E
B
B


0.953-1.047




•



93
02
10
74

0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
.000
.802
,875
,894
.918
929
938
950
977
981
000 13C12-2378-TCDP ISO
025
082













Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 13:18 01/11/98
                                                                            106

-------
  Page No.     2           Listing of X980084B.dbf
  01/11/98                 Matched OC Peaks / Ratio / Ret.  Time

  Compound/
    !	QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
r
                 DC  WH  23:45 RO  1.37        103.44                             1.105
  316-318               4 Peaks              24,438.91
                                        Above:  TCDF / TCDD Follows
  13C12-TCDD                     0.65-0.89                                     0.901-1.099
  332-334         DC  ML   0:00 RO  1.76         28.59                             0.000
                         20:13     0.79     17,380.86      7,688.81      9,692.05  1.000 13C12-2378-TCDD IS1
                         20:28     0.80     20,140.88      8.942.48     11,198.40  1.012 13C12-1234-TCDD RSI
                         20:42     0.82         30.26         13.59         16.67  1.024
                         20:48 RO  2.24          7.86          9.94          4.44  1.029
                         21:09 RO  1.01        199.59        114.36        112.76  1.046
                 DC  WH  22:44 RO  0.43         81.97                             1.124
                 DC  WH  22:50 RO  1.21         18.28                             1.129
                 DC  WH  23:09 RO  1.07         27.38                             1.145
  332-334               5 Peaks              37,759.45
 Column Description	   "Why*  Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)      WL-Below Retention Time Window   A-Peak Added
 ..RT. -Retention Time (mm:33)    WH-Above Retention Time Window   X-Peak Kept
 Rat.l -Ratio of M/M+2 Ions       SN-Below Signal  to Noise Level   D-Peak Deleted
 OK    -RO=Ratio Outside Limits  * End of Report ***
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713                                             Printed: 13-18 01/11/98
Phone: (919)544-5729* Fax: (919) 544-5491                                                              107

-------
ellatZ980084 tl-884 Acyt  7-*fAa-iyya i/mm w. ju* voicag* six Aucospec UOIM
303.9016 BSUB(256,30,-3.0)  ?KD(3,3,1. 0.10*, 3187832. 0, 0. 00*,?,?) gxpiKOSfJPT
SfOflf T*xtiTLI*44376 105-108 Pll* Tmxti TKLUfOLS LABS
100*                                  JM  4X9
   17:00         laioo        19100         40*00        21100        aa'too         23*00
Pill> 1980084 «l-884 Jkcyt  7-001-1999 17s21i21 OC B> Volttgt SIR AUtoSpma Ifolgft 1018108
305.8987 B3US(256,30,-3.0)  fKD(5,3,lr0.10*,4072432.0,0.00*,P,P) BxptXCONP_TT
     t ToxtiTLI*44376  105-108  Pilf Vmxet TRIANQLS LABS
100H
 80.

 SO.

 40.

 20.
            A2.49S9
A1.95E9
                            A1.7SS9
                                   A2.31S9
                                        A2.28S9
                                                 A2.31S9
                                                          A1.39B9
                                                                                      A2.51SB
                                                                                        /\
  17:00         18:00        15:00         20:00         21:00        22:00         23:00
Pil»sX9800B4 #1-884 Act?:  7-JAN-1998 17:21:21 OC SI+ Voltage SIR AuCoSpac Nolue: 15025
315.9419 BSUB(256,30, -3.0) PKD(5,3, 1, 0.10%, 60100. 0, 0. 00*,P,P) Exp:KONF_TT
Saapl* ToxtiTLI#44376 105-108  Pllf  Tufti  TRIANOLE LABS
100*                                                         A1.09E8

 80.

 60.


 40.

 20.
  17:00         18:00        1*.:00        20:00         21:00        22:00        23:00
P±l»tX980084 01-884 Actj:  7-JAK-199B  17:21:21 OC SI* VolCaga SIR AutoSpac Hols*tl6121
317.9389 BSUB(256,30,-3.0) PKD(S,3, 1, 0.10*, 64484. 0, 0. 00*,P,P)  SxpiKONPJTT
Saapla Text:TLI#44376 105-108 Pil» Toxtt  rRlANQLS LABS
lOOit                                                         A1.34E8

 80.

 60.

 40.

 20.
  17:00         18:00        15:00        20:00         21:00        22:00
Pil»iI980084 tl-884 Acq:  7-JAN-1998  17:21(21 OC ST+ Voltagu SIR AutoSpec
375.8364 SxpIKONP_TT
Saapl* T*xttrLI*44376 105-108 Pllf Tut:  TRIAM3LB LABS
10031
80.

60.

40.

20:

 0.
                                                           21*14
     17/11
                                                                              o.oso
                                                                                 Tim*
                                                                                               _a.asa

                                                                                               .7.0E8

                                                                                               .5.3E8

                                                                                               .3.5E8

                                                                                               .1.3E8
                                                                              O.OEO
                                                                                 Time
                                                                              2. 5E7

                                                                             '.2.0E7

                                                                             '.1.SE7

                                                                             '.1.0E7

                                                                              S.1S6
                                                                                                 O.OEO
                                                                                                    Time
  17,00
               18100
                             19 tOO
                                          20:00
                                                       21100
                                                                     22100
                                                                             .3.2E7

                                                                             .2. 6E7

                                                                             .1.9E7

                                                                             .1.3E7

                                                                             .6.5E6

                                                                             .O.OEO
                                                                                Tlma



                                                                             .2.2E6

                                                                             .1.8E6

                                                                             .1.3S6

                                                                             .9. OSS

                                                                             4.5S5

                                                                             O.OSO
                                                                                Tim*
                                                                                                 108

-------
Pll«tZSBOOB4 I1-9B4 Acq: '/-JJJJ-1S9B 17,31:31 X S1+ Volbagu 3IS AukoSpac Soifa, 3.0978
319.8965 BSHB(256,30,-3.0) tXD(5f 3,1,0, 10*,43913. 0,0. 00*. f,P) SxpiKOaP_TT
Stapl* T»*ttTU»44376 105-108 Pilu Tmxe: TRIABOLS LABS
iocs
BO.
60.
40.

20.

A6.67SB

A3.41S8 A6.07S8
A A A A3.38S8 f\
A A '/W\ «•««
H /I l\ l\l\ /V/v/YiK- A^ ^ _ _
-2.6S8
'.3. IBS
.1.6S8
.1.0S8

.5.3S7
O.OSO
' la'lOO 	 19\00 20'tOO 31\00 23': 00 23\00 Tioa
Pll»tX980084 91-884 Acqt 7 -JAN- 19 9 8 17:21:21 OC ST+ Voltaff* SIR AlltoSptc Sol*»:26374
321.8936 BSUB(3S6,30,'3.0) PXD(5,3,1, 0.10*,105496.0,0.00*,P,P) g*p:KOaP_TT
Saapla T*XttTLI*44376 105-108 P±lu Text: TRIANQLS LABS
100}

80.
60.
40.

20^
Q'

k
A8.55E8
1-

A4.40E8 A7.75E8
h*3'^ A3 03E8 h
II ft II J*W » U JAO / 1
A A A J \ A1.58E8
l\ l\l\ /v/v/Yi K . A^\ ^ _ ^
3.3S8

.3.7E8
'.2.0BB
.1.3E8

'.6.7S7
' O.OEO
'ifliflo' ' ' ' 15«00 20:00 2l':00 ' ' 22:0o' ' ' 23\00 Time
Pll»tX980084 #1-834 Acq: 7-JAH-1998 17:21:21 OC BI+ Volt ay « SIR AutoSpac Holaat 11066
327.8847 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10*, 44264.0, 0.00*,P,P) Exp : XCONP_TT
Saaplf TOXC:TLI»44376 105-108 Pil» Tojef: TRIANGLE LABS
100*
ao:
*o:

40.
20:
Q'
A3.22EB
A2.11EB I
I ' ,
II A1.63EB
I

A
_JlA_^A/l7l 11
B.OE7
.6.4E7
'.4.8E7

.3.2E7
.1.627
O.OEO
'iflioo 	 J^ioo' ' 20'tOO ' ' '31:00 	 33\00 ' ' 23\QO Tiaa
P11»:X980084 91-884 Acqt 7-WS-1998 17:21:21 OC SI* Volt ago SIR AutoSpac Noiaa: 14246
331.9368 BSVB(256,30,-3.0) PXD(5, 3, 1,0.10*. 56984, 0,0. 00*, P,P) ExpsXCONP TT
Saopla Toxt:TLI»44376 105-108 Plla Taxt: TRIANGLE LABS
IOCS

80.
60.
40.
20.
0
A8.94B7
A7.69S7\


'

n
2.4E7

.1.9E7
'.1.4E7
.9.6E6
.4.BE6
O.OSO
18:00 19\00 20:00 21\00 ' 22\00 	 23\00 Time
Pll»:X980084 01-884 Acqt 7-JAH-1998 17:21:21 OC ST* Voltaym SIR AutoSpac Boim»t807S
333.9338 BSVB(256,30, -3 .0) PKD(5,3, 1, 0.10*,33300. 0, 0. 00*,P,P) SxptXCOHP TT
Suapl* T*Xt:TLI#4437S 105-108 Pllf Tvtt: TRIAffOLS LABS
IOC*
80.
60.
40.
20.
a
A1.12E8
A9 OT7fl



l(l\
.3 . OS7
.3.4S7
.1.BS7
-1.2S7
.6.086
O.OSO
iflioo 19tOO 30:00 ' 21:00 	 22': 00 ' 23\00 Timo
109

-------
  27JOO        20iOO        15x00        20:00        31:00       23:00
Plle:Z980084  91-884 Acq: 7-JAB-1998  17:31:31 OC SI+ Voltage SIR AutoSpec
319.8965 Sxp:XCOKP_TT
Sample Text:TLI»44376 105-108  Pile Text: TRIANQLE LABS
20«          27;57

 00:

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 40:

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  0.
Plle:I980084 #2-004 Acq: 7-JAB-1998  17:21:21 OC SI* Voltage SIR AntoSpec
303.9016 Srp:ZCOKP_TT
Sample Text:TLI*44376 105-108 file Text:  TRIASOLS LABS
  17:00        18:00        19:00        SOlOO        31:00       32:00
Pile: 1980084 tl-884 Acqt 7-JAS-1998 17:21:31  OC EH- Voltage SIR AutoSpee
         Sxp:XCQNP_TT
Sample TextiTLIt44376 105-108 Vile  Text:  TRIANQLS LABS
100*
                                                                              23(00
 00:
 60:
 40:
 ao:
                                                           21:30
                                                                              33oo
                     ""
                             19:09
                                              20:28
                               AAAT.A
  17:00        18:00        19:00        30:00        31:00        33:00
Plle:X980084  tl-884 Acq: 7-JAB-1998  17:21:21 OC SIf Voltage SIR AutoSpec
331.9368 Bxp:KONP_TT
Sample Text:TLIS44376 105-108  Pile Text: TRIANOLS LABS
100%                                          30/28

 0oJ                                       "'"'
 60:

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  o.
                                                                              23s 00
  17:00        18:00        19:00        20:00        21:00        22:00
Pile,1980084  *i-884 Acq: 7-JAB-1998 17:31:21 OC SI+ Voltage SIR AutoSpec
292.9825 Exp:XCONP_TT
Sample Text:TLI#44376 105-108 Pile Text: TRIANGLE LABS
100*	17±39 17lS5              •">_L™		   -20-155 2H24 21^S1_23^

 80:

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 ab:

  o:
                                                                                           -2.SE7

                                                                                           .3.0E7

                                                                                           .1.5S7

                                                                                           .1.0E7

                                                                                           -5.1S6
                                                                                            O.OSO
                                                                                               Timi
 2.6S8

.2.1E8

.1.6E8

.1.0E8

.5.2E7
                                                                                            0. OEO
                                                                                               Time
                                                                                            2.4E7

                                                                                           .1.9E7

                                                                                           .1. 4E7

                                                                                           .9.6E6

                                                                                           .4.BE6
                                                                        22
                                                                              2300
                                                                               23:07 23:31
                                                                                            O.OSO
                                                                                               Time
 8.3B8

.6.7E8

.S.OE8

.3. 3E8
                                                                                            O.OEO
  17:00        18:00        19:00        20:00        21:00        22:00
Pile,1980084 11-884 Acq: 7-JAB-1998 17:21:21 OC EI+ Voltage SIR AutoSpec
330.9792 Sxp:KOS?_TT
Sample Text:TLI*44376 105-108 Pile Text: TRIASOLS LABS
                                                                              astoo
100*
 80.
 60:
 40:
 20:
  oj
             17«51
                                                                                            9.0E8

                                                                                           .7.3E8

                                                                                           .5. 4S8

                                                                                           .3.6E8

                                                                                           .2.020
  i7»oo
               a/oo
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                                        20: oo
                                                    aio
                                                                 aao
                                                                              23oo
                                                                                            0.0X0
                                                                                              Time
                                                                                               110

-------
                    Peak Locate Examination:  7-JAN-1998:17:20 File:X980084
                         Experiment:XCONF_TT Function:! Reference:PFK
                                         Volts
                                        5.2592
292.95315
292.98245
293.01175
                                                                      Volts
                                                                     5.6435
330.94615
330.97925
331.01235

-------
TLI Project:     44376
Client Sample:   109-112
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:
Client Project:
Sample Matrix:
TLI ED:

Sample Size: .
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-2A-D

1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01706/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Aralytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
U,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (tig) Di. EMPC
1.4
6.6
1.7
2.7
3.8
2.6
1.5
EMPC 46rO 7 V
32.7 ^
43.9 '/is/
29.0
12.8
8.3
0.37
7.2
0.78
0.82
Amt ing) Number Dt EMPC
. 84.5 13
164 10 167
55.8 7
5.5 2
496- -y "f 15 552- 7 Lf
^29— 72-0 16 -549 720
141 13 143
9.2 3 11.3 ^<£
Ratio
0.79
1.58
1.22
1.24
1.22
1.01
0.83

, 1.50
f/ 1.48
1.26
1.31
1.26
1.24
1.04
1.02
0.85









RT
26:21
30:33
33:37 .
33:42
34:01
37:05
40:56

29:31
30:14
32:53
33:00
33:30
34:17
35:59
37:37
41:09









Flags


oZ

QPR

—
SE_

E_

	
~~1

PR_


	
Flags
E_
E_
Q_
—
SQE
SE_
E_
X_
                                        Page Iof2
                         X237.PSRv2.01. LARS
Triangle Laboratories, lnc.»
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 09:26 £1/15/98

-------

•US
TLI Project: 44376
Client Sample: 109-112
|il^i^^|wiiiil^il^^i88^1
13C12-2,3,7,8-TCDF
l3C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
l3C15-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
I3Cr-l,2,3,4,6,7,8-HpCDF
13C12-l,2,3,4,6,7,8-HpCDD
13Ci2-l,2,3,4,6,7,8,9-OCDD
^HaJii^ii^a^^^mi^^M
•i-:\\\-:-x-\*x:'-.<\^:-y.-\w
37CL-2,3,7,8-TCDD
13C,:-2.3,4,7,8-PeCDF
13C,:- 1,2,3,4. 7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD
l3C,;-l,2.3,4,7,8,9-HpCDF
IKFr^^^n^Kj^^i^P
m^fm^^mmmmfxi^^m^i^^m&mmi
IJCi2-l,2,3.7,8,9-HxCDF
13Cr-2,3,4,6,7,8-HxCDF

|j||c$^
13Cia-l,2,3,4-TCDD
13C,:-l,2,3,7,8,9-HxCDD

2.2
2.8
2.8
3.4
2.8
2.5
3.1
4.1
9.0

3.5
4.1
4.1
5.5
4.0
||iii||i(ng||
3.2
2.9







Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980154

54.5
70.6 .
71.1
85.8
69.7
63.3
77.0
103
112

88.6
101
102
137
99.4

79.7
73.6
imi^piBiiiiii^:

QC Limits
40%- 130%
40%-130%
40%- 130%
40%-130%
40%-130%
40%-130%
25%-130%
25%- 130%
25%-130%
Illliiiti;?
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
liHimftl!
40%- 130%
40%- 130%



0.76
0.79
1.54
1.49
0.52
1.16
0.43
1.04
0.91
llllptiqll
1.52
0.53
1.15
0.42
||||il|ati[<>|
0.51
0.52
||||Ra4io|
0.81.
1.16

25:41
26:21
29:30
30:33
32:59
33:42
35:59
37:04
40:55

26:21
30:13
32:53
33:36
37:36

34:17
33:30

26:10
34:01

Q_
oH
l|l|iipgs|!l:
oIL
111111111
—
::::::::::::-Sx-:iii':'-'---:-':::::::oyV:.:
mmffiaxtsm
v:::::v:x::::::::::::::X::-.*^:.::.:v..:::;X
	
                          Data Reviewer
01/15/98
                                                 Page 2 of 2
                X37.PSR V2.0I.LARS 6.10.080
Triangle Laboratories, Inc.3
801 CapKola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 09:26 01/15/98
                    113

-------
                         Initial
                                     . .Data. .
  Data Review By:
                     Calculaeed Noise Area:
                                             2.00
  The Total Area for each peak with an ion abundance ratio  outside
  ratio  limits has been recalculated according to method requirements.
  Page No.
  01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306

















304-306
13C12-TCDF
316-313















316-318
TCDD
320-322

DC NL 0
22
23
23
23
24
24
24
24
25
25
25:
25:
26:
26:
26:
27:
DC WH 27:
0
:00 RO
:39
:08
:21
:43
:01
:25
:40
:53
:05 .
:17
:30
:42 RO
:06
:13
;32
:22
:35
.65-0.89
1.09
0.30
0.31
0.79
0.80
0.31
0.31
0.30
0.30
0.30
0.30
0.31
0.94
0.30
0.30
0.77
0.33
0.38
16 Peaks

DC NL 0:
DC WL 22:
DC WL 23:
DC WL 23:
DC WL 23:
DC WL 23:
DC WL 24:
DC WL 24:
DC WL 24:
25:
25:
25:
26:
26:
DC WH 27:
DC WH 27:
0
00 RO
40 RO
08 RO
21 RO
30 RO
43 RO
03 RO
25 RO
39 RO
17 RO
30 RO
41
05 RO
13 RO
05 RO
35
5 Peaks

DC NL 0:
0.
00
.65-0.89
1.49
1.36
3.02
2.71
1.47
2.54
1.41
1.84
1.17
0.54
1.25
0.76
1.34
2.16
1.05
0.72
0.878-1.073

12
13
14
69
41
48
42
58
36
23
22
60
32
25
4
3

508
4.51
,646.24
,761.79
,125.51
,194.90
.243.20
,048.70
,448.20
,573.50
,366.10
,120.30
,784,00
,792.77
,740.00
,020.30
,231.63
,316.39
834.92
,464.08

5
6
6
30
18
21
18
25
16
10
10
32
14
11
1
1



,614.06
.144.32
,242.97
,772.50
,400.00
,470.10
,893.40
,972.90
,147.50
,256.90
,180.90
,130.40
,575.90
,142.40
,860.96
,503.55



7
7
7
38
22
26
23
32
20
12
12
34
18
13
2
1



,032.13
,617.47
,882.54
,422.40
,343.20
,578.60
,554.30
,600.60
,218.60
,863.40
,603.10
,346.20
,164.10
,377.90
.420.72
,313.34


0.000
0.882
0.901
0.909
0.923
0.935
0.951
0.960
0.969
0.977
0.984
0.993
1.001 2378-TCDF AN
1.016
1.024
1.033
1.066
1.074


QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
SE
QE
QE
Q
Q


.0.961-1.039











2,




2,
65-0.89
0.86

3.04
9.31
3.46
5.31
13.66
29.28
42.09
27.10
62.22
79.19
33.86
638.50
31.47
13.53
8.53
22.57
851.55
TCDF /

3.64




















34.45
23.82
1,160,50




23.77
22.59













1,













63.36
19.13
528.00
17.78
10.47


0.000
0.883
0.901
0.909
0.915
0.923
0.936
0.951
0.960
0.934
0.993
1.000 13C12-2378-TCDF ISO
1.016
1.024
1.055
1.074











Q









0.903-1.045

0.000

Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed:
01/15/98

-------
  Page No.
  01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.






M
M
AN




320-322
37C1-TCDD
328 .

















328
13C12-TCDD
332-334




332-334
PeCDF
340-342




23
24
24
25
25
25
26
26
26
26
26
26
27
:55
0.78 18
:17 0.79 11
:34
:13
:29
:51
:08
:15
:21
:31
:40
:53
:19
0.
0,
0.
0,
,77 4
,78 12
,77 9
,78 4
0.78 4
0.
0.
0.
0.
0.
0.
13 Peaks
.78 7
,79 1
,77 2
,78 2
80
79
80
.293.32
.344.32
,826.63
,393.57
,000.34
,860.02
,850.00
,960.00
,316.00
,123.64
,412.22
742.93
816.41
,945.90
8,016
5,011
2,100
5,418
3,929
2,125
2,130
.3,490
581
925
1,053
330
361

.72
.46
.19
.78
.63
.26
.00
.00
.00
.05
.87
.60
.21

10,282
6,333
2,726
6,974
5,071
2,734
2,720
4,470
735
1,198
1,358
412
455

.10
.36
.44
.79
.21
.76
.00
.00
.00
.59
.35
.33
.20

0.908
0.922
0.932
0.957
0.967
0.981
0.992
0.996
1.000 2378-TCDD
1.006
1.012
1.020
1.037

E
E

E
E


E
AN





0.924-1.076
DC NL 0
DC WL 23
DC WL 24
DC WL 24
24
25:
• 25:
25:
25:
25:
26:
26:
26:
26:
27:
27:
27:
28:
:00
:55
:09
:17
:34
:01
:13
:29
44
:51
:09
:21
30
43
20
31
42
00


















14 Peaks

DC NL 0:
25:
26:
26:
26:
0.
00 RO
13
10
21
40 RO
,65-
2.
0.
0.
0.
0.
4 Peaks

DC NL 0:
27:
27:
28:
28:
1.
00 RO
35 RO
49
00
11
32-
1.
1.
1.
1.
1.





1





2

3




7
0.39
20
69
31 3
79 2
64
6
1.78
19
24 46,
47
53
57
2.23
94.71
48.71
135.16
31.47
,930.59
75.64
49 .02
21.97
34.43
28.37
,507.66
48.18
,200.31
4.44
3.33
7.23
6.39
,949.53




31
1.930
75
49
21
34
28
2,507
48
3,200,
4.
3.
7,
6.





.47
.59
.64
.02
.97
.43
.37
.66
.13
,31
.44
33
.23
.39







































0.000
0.908
0.917
0.922
0.932
0. 949
0.957
0.967
0.977
0. 931
0.992
1.000 37C1-TCDD
1.006
1.014
1.037
1.044
1.051
1.063












SUR1







0.924-1.076
3.56
17.78
,192.46
,812.06
46.46
,063.76
TCDD /

2.63
,348.47
935.47
266.27
858.53

7.
1,425.
1,241.
20.

28
73
61
21

10.
1,766.
1,570.
31.

50
68
45
63
0.000
0.957
0.993 13C12-1234-TCDD
1.000 13C12-2378-TCDD
1.012


RSI
IS1

P»P ni? c*rti i ni+to


28,172.
556.
161.
524.

60
46
21
40

22,765.
379.
105.
334.
0.931-1.063

20
01
06
13
0.000
0.935
0.943
0.949
0.955

SE



Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/15/98
                                                                        115

-------
  Page No.
  01/15/98
Listing of T980154B.dbf
Matched GC Peaks /  Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why  ..RT.  OK Ratio Total .Area. .. Area. Peak. 1.. Ar ea. Peak. 2. .  Rel.RT Compotmd. Name. . ID.. Flags.






A
M









340-342
13C12-PeCDF
352-354















352-354
PeCDD
356-358







A .


28
28
28
28
29
29
29
29
29
29
30
30
30
30
30
31
DC WH 31
:19
:33
:41
-.50
:09
:14
:26
:31
:40
:47
:04
:14
:24
:41
:51
:09
:36
RO

RO







RO






1.23
1.48
1.10
1.48
1.48
1.43
1.49
1.50
1.43
1.50
1.86
1.48
1.49
1.51
1.46
1.50
1.45
20 Peaks

DC NL 0:
27:
DC SN 27:
DC SN 27:
DC SN 28:
28:
' 28:
28:
29:
29:
29:
29:
29:
30:
30:
31:

:00
:35
42
:52
21
33
41
51
09
14
30
47
57
13
25
08
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO


RO

RO
RO
12 Peaks

DC NL 0:
28:
29:
29:
29:
29:
30:
30:
30:
30:
30:

00
46
14
29
36
47
03
16
26
33
39
1.
RO







RO


32-1.78
1.07
2.28
1.33
2.29
2.09
2.78
2.01
1.18 .
2.14
2.19
1.54
1.53
0.53
1. 52
1.96
1.20
356.16
27,642.60
67,998.14
31,725.10
41,009.60
41,577.00
18,890.00
25,200.00
21,296.35
27,786.80
330.61
33,812.30
31,434.50
1,695.47
941.40
2,183.12
64.67
422,288.39

16
41
18
24
24
11
15
12
16

20
13
1

1


216.49
,494.00
,332.20
,948.30
,491.60
,478.30
,300.00
,100.00
,716.00
,650.20
241.48
,201.40
,825.00
,020.95
558.75
,310.34


176
11,148
37,727
12,776
16.518
17,098
7,590
10,100
8.580
11,136
129
13,611
12,609
674
382
872


.10
.60
.40
.30
.00
.70
.00
.00
.35
.60
.65
.40
.50
.52
.65
.78


0.560
0.968
0.972
0.977
0.983
0.991
0.998
1.001 12373-P>«CDF AN
1.006
1.010
1.019
1.025 23478-BXeCDF AN
1.031
1.040
1.046
1.056
1.071



SE
E
E
E





E
E
Q




0.864-1.136
1.02
37.46
2.45
2.36
2.31
16.27
149.20
40.29
23.87
28.31
2,904.57
53.02
4.75
2,923 .33
31.62
11 .78
6,224.47
32-1.78
1.24
1.47
1. 54
1.53
1.54
1.56
1.54
1.58
0.95
1.58
1.50
1,51
39,331.90
3,236.73
20,725.48
5,069.73
14,407.24
8,609.49
4,683.73
2.056.45
4,148.38
965.12










1,


1,



33.43



17.74
117.52
24.49
20.00
24.31
,762.72
32.09
2.89
.763 .48
24.31
7.16

14.



6.
58.
20.
9.
. 11.
.1,141.
20.
4.
1,159.
12.
5.

,59



38
51
32
36
10
85
93
25
85
40
96
0.000
a. 935 '
0. .939
0.945
0.961
0.963
0.972
0. -978
0.988
0,991
1..000 13C12-P.eCDF 123 IS2
1.010
1.015
1.024 13C12-PfiCDF 234 SUR2
1.031
1.055
















Do<""Tin TTrtT 1 /rue-


23,
1.
12,
3,
8,
5,
2.
1,
2,


389.00
961.96
547.30
076.67
788.04
215.44
866.20
250.00
542 . 12
579.61

15,942.
1,274.
8,178.
1,993.
5,619.
3,394.
1,817.
1,310.
1,606.
385.
0.939-1..022

90
•77
13
06
20
05
53
00
26
51
0.000
0.942
0.957
0,965
0.969
0.975
0..984
a. 991
0.996
1.000 12373-FeCDD AN
1,003

E








Q
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/15/98
                                                                        116

-------
  Page No.
  01/15/98
Listing of T980154B.dbf
Matched GC Peaks /  Ratio / Ret. Time
  Compound/
 ,M_2	QC.Log Omit Why  ..RT.  OK Ratio Total.Area... Area.Peak. 1..  Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.

356-358
13C12-P6CDD
368-370










368-370
HxCOF
374-376










AX
M
MX
AN
M

374-376
13C12-HXCDF
384-336










384-386
30:58
11 Peaks

DC NL 0:00
28:46
29:14
29:28
29:36
29:47
30:04
30:14
DC SN 30:24
30:33
DC SN 31:00
8 Peaks

DC NL 0:00
31:56
32:04
32:14
32:22
32:31
32:44
32:53
33:00
33:07
33:18
X 33:25
33:30
X 34:14
34: 17
34:22
DC WH 34:47
15 Peaks
1

1.32
RO 0
RO 2
RO 1
RO 2
1
1
RO 2
1
1
1
1

1.05
1
1
1
1
1
1
1
1
1
1
1
RO 1
1
RO 1
1
1
1

.57

-1.78
.58
.76
.98
.08
.44
.64
.66
.76
.72
.49
.76
ihft1
-1.43
.11
.27
.24
.27
.24
.26
.32
.26
.31
.28
.26
.22
.26
.29
.24
.25
.26

1,916
105,150

0
23
7
21
3
12
7
3
4
1,945
5
2,040

123
11,144
36,065
2,653
3,522
2,042
390
20.453
10,140
1.967,
3.122,
349.
5,280.
753.
222 .
967.
167.
99,078.
.47
.72

.54
.69
.93
.47
.59
.21
.19
.90
.76
.11
.93
.09
") / M\
*i 1 nj
.98
.59
.00
.64
.63
,01
.24
.37
.65
.41
.90
00
.00
00
30
00
45
79
1











1

,171



31
6
17
5
7
7
5

.164

.04



.05
.17
.49
.07
.53
.51
.68

.58

745



11
3
3
3
4
2
3

780

.43

0.

.25
.11
.42
.52
.63
.32
.22

.53

1.014

369-1.131
0.000
0". 942
0.957
0.965
0.969
0.975
0.984
0.990
0.995
1.000 12C12-PeCDD 123 IS3
1.015



6
19
1
1
1

11
5
1
1

2






,230
,940
,483
,951.
,138,
221
.415
,746,
,104,
,740,
192.
,940.
424.
123 .
537.



.16
.40
.43
.13
.16
.96
. 20
.49
.72
.50
00
00
00
00
00



4,914
16,124
1.170
1.571
903
163
9.043
4.394
862
1.332
157
2,340
329
99
430.


0.43-0.59
DC NL 0:00
31:56
32:04
32:53
32:59
33:15
33:30
DC SN 33:44
DC SN 33:54
DC SN 34:01
34:17
7 Peaks
RO 1
RO 1
RO 1
0
0
0
0
RO 0
0
RO 0
0

.38
.35
.20
.53
.52
.52
.52
.95
.53
.65
.51

3 .
3.
32 .
2,295.
2,444.
3.
2,461.
3 .
3.
4.
2,110.
9,361.
38
98
31
64
39
08
31
52
71
09
03
24'













8.
25.
791.
835.
2.
837.



713.


03
70
71
13
75
73



42


5.
21.
1,503.
1.609.
5.
1.624.



1,396.

0.964-1.049

.43
.60
. 21
.55
.35
.28
.17
.16
.69
.40
.00
.00
.00
.30
.00


0.000
0.963
0.972 E
0.977
0.981
0.936
0.992
0.997 123478-HxCDF AN
1.001 123673-HxCDF AN
1.004
1.010
1.013
1.016 234678-HxCDF AN
1.038
1.039 123789-HxCDF AN PR
1.042
1.055

0.379-1.121

95
40
•93
26
33
03



61

0.000
0.968
0.972
0.997 13C12-HXCDF 478 SUR3
1.000 13C12-HXCDF 578 IS4
1.008
1.016 13C12-HXCDF 234 ALT2
1.023
1.028
1.031
1.039 13C12-HXCDF 789 ALT1

Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/15/98
                                                                        117

-------
  Page No.
  01/15/98
Listing of T980154B.dbf
Matched GC Peaks /  Ratio / Ret. Time
  Compound/
  M_2	 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
HxCDD
390-392







390-392
13C12-HXCDD
402-404





402-404
HpCDF.
408-410

X


D


408-410
13C12-HpCDF
418-420



413-420
HpCDD
424-426



424-426
1
DC NL 0:00
32:25
32:51
33:05
33:15
33:37
33:42
34:01
7 Peaks
1
DC NL 0:00 RO
33:03 RO
DC SN 33:16 RO
33:36
33:42
34:01
4 Peaks
0.
DC NL 0:00
35:59
X 36:16 RO
36:26
DC SN 36:41 RO
D , NH 37:21
37:37
DC WH 38:12 RO
4 Peaks
0.
DC NL 0:00 RO
35:59
DC SN 36:28 RO
37:36
2 Peaks
0.
DC NL 0:00 RO
36:17
37:05
DC WH 37:36 RO
2 Peaks
.05-1.43
1.14
1.21
1.22
1.22
1.24
1.22
1.24
1.22

.05-1.43
1.66
1.00
1.99
1.15
1.16
1.16

38-1.20
1.13
1.04
1.05
1.04
1.55
0.97
1.02
1.27

37-0.51
1.09
.0.43
0.60
0.42

88-1.20
1.78
1.03
1.01
1.78


9.72
3,394.10
8,553.92
5.388.67
553.16
604.09
1,061.66
1,496.43
21,052.03

3.58
12.99
4.05
1,741.18
1,569.35
2,483.98
5,307.50
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4.59
4,510.99
1,171.37
669.12
4.39
9.03
371.32
16.10
6,723.30

1.83
1,704.95
2.29
1,321.35
3,025.30
• Wr^f"* TIP /
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0.32
1,360.92
1,250.84
4.69
2,611:76


1.855.18
4, 693.87
2,962.75
305.72
332.31
587.91
822.70



7.19

929.78
844.15
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2,303.10
. 601.11
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187.37




513.42

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690.51
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1.538.92 0.962
3,860.05 0.975
2,425.92 0.982
247.44 0.987
271.78 0.998 123478-HxCDD AN
473.75 1.000 123678-HxCDD AN
673.73 1.009 123789-HxCDD AN

0.970-1.030
0.000
7.20 0.981
0.987
811.. 40 0.997 13C12-HXCDD 478 SUR4
725.20 1.000 13C12-HXCDD 673 IS5
1,150.43 1.009 13C12-HXCDD 789 RS2

0.998-1.053
0.000
2,207.39 1.000 1234678-HpCDF AN
570.26 1.003
328.63 1^013
1.019
1.038
184.45 1.045. 1234789-HpCDF AN
1.062

0.944-1.111
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1.013
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Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/15/98
                                                                        118

-------
  Page No.
  01/15/98
         Listing of T980154B.dbf
         Matched GC Peaks / Ratio / Ret.  Time
  Compound/
  M_2.... QC.Log Omic Why
         .RT.  OK Ratio Total.Area. ..  Area.Peak.1.. Area.Peak.2..  Rel.RT Compound. Name. .  ID..  Flags.
  13C12-HpCDD
  436-438
  436-433
  OCDF
  442-444
 442-444

DC

DC




DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC


NL

SN


3

NL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN


SN
1 2

0
36
36:
37
37
Pe<

0:
35:
35:
36
35:
37:
38:
38;
39:
39:
39:
39:
40:
41:
41:
41:
Pee

:00
:17
:30
:04
:19
iks

:00
34
:51
:14
:47
:05
:17
;36
:22
39
47
53
:15
09
26
43
iks
0,
RO
RO
RO

RO

0.

RO

RO


RO
RO

RO
RO
RO
RO

RO
RO

,38
1
1
3
1
1

76
0
0
1
1
1
1
1
2
0
1
0
0
0
0
0
0

-1..20
.45
.31
.48
.04
.94

-1.02
.94
.43
.02
.04
.00
.02
.12
.45
.96
.15
.43
.45
.30
.35
.73
.55

                                                 1.88
                                                12.42
                                                 1.26
                                             1,848.56
                                                10.06
                                             1,371.04
                                             7.97

                                           944.06
                                             9.58
             0.973-1.027
                 0.000
           6.09  0.979
                 0.985
         904.50  1.000 13C12-HpCDD 678 IS7
           4.93  1.007
                                       Above:  HpCDD /  Octa-CDD and CDF Follows
                                                 0.99
                                                 1.06
                                                 1.07
                                                 9.03
                                                 1.34
                                                .2.66
                                                 1.13
                                                 0.42
                                                 1.10
                                                 0.64
                                                 0.31
                                                 1.00
                                                 0.76
                                               404.72        186.18        218.54
                                                16.50          7.77         10.66
                                                 0.31
                                               421.22
                                                             0.902-1.098
                                                                 0.000
                                                                 0.369
                                                                 0.876
                                                                 0.386
                                                                 0.399
                                                                 0.906
                                                                 0.936
                                                                 0.943
                                                                   962
                                                                   969
                                                                   972
                                                                   975
                                                                 0.984
                                                                 1.006 OCCF
                                                                 1.013
                                                                 1.020
                                       AN
 JCDD
 453-460
 453-460
               0.76-1.02
DC  NL   0:00  RO  1.09           0.21
        40:56      0.83         559.29
DC  SN  41:16  RO  1.13           2.53
      1  Peak                  559.29
                                                            254.23
             0.902-1.098
                 0.000
         305.06  1.000 OCDD
                 1.009
                                                                                                       AN
  13C12-OCDD               .      0.76-1.02
  470-472         DC  NL'   0:00  RO   1.08           0.25
                         40:55      0.91       2,736.31
                 DC  WH  41:23  RO   0.31           3.14
  470-472               1  Peak                 2,736.31
                                         1,302.66
             0.993-1.006
                 0.000
       1,434.15  1.000 13C12-OCDD
                 1.013
                                                                                      IS8
 Column Description	   "Why" Code  Description	   QC Log  Desc .
 M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time (mm;ss)
 Rat.l -Ratio of M/M+2! Ions
 OK    -RO=Ratio Outside  Limits
 Rel.RT-Relative Retention Time
     End of Report ***
                WL-Below  Retention Time Window
                WH-Above  Retention Time Window
                SN-Below  signal to Noise Level
                
-------
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123

-------
r±latT980154 tl-396 Acq:6-JAlT-98 16:51:52 EI+ Voltage SIS  701 Koiae:32625
373.8208 T:3 BSOB(2S6,30, -3. 0)  HO)(7, 5,3,0. 05\, 130500. 0,1.00\,r,T) XxpstWBSUS
TSIANSLE LASS  Text:TLIf44376 109-113                       ISJ.  TIKE  -   16:54
ion
  aol
  60:.
  40:
  20:
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         A1.99E8
                                 A1.14E8
    A6.23X
                 Al.95E7
                ^ y\  ^
                                                    A3.09E7
        32:00                          33:00                          34:00
rUe:T980154 tl-396 Acq:6-JZN-98 16:51:52 EI+ Voltage SIS 70T Woiae:29366
375.8178 f:3 BSOB(256,30,-3.0)  tXD( 7,5, 3, 0. 05\,117464. 0,1.00\,T,T) Xxp-.JWSSOS
TRIANGLE LABS  Taxt:TLIf44376 109-112               .        OKT. TIKE >   16:54
1003
  80:
  so:
  40:
  20:
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         Al. 61E8
    A4 .91E1
    A
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                    \4.39E7
A1.57E7
A2.45E7
  /\
        32:00                          33:00                         34:00
Tile:T9801S4 tl-396 Acq:6-JAN-98 16:51:52 EH- Voltage SIS 70T Koiae:1771
383.3639 f:3 BSO3(256, 30, -3. 0)  fKD(7, 5,3, 0.051,7084.0,1.00*,f,T) Ezp-.mSSUS
TSIANSLE LABS  Text:TLI#44376 109-112                       IJW. TIME -   15:54
1003

  80:

  60:

  40:

  20:

  o:
                                                     AB.38E6
                                                                            A7.13E6
        32:00                          33:00                         34:00
File:T980154 tl-396 Ac(j:6-JAN-98  16:51:52 EH- Voltage SIS 70T Noise:12S3
385.8610 f:3 SSUB(256,30, -3.0) fJU>(7,5,3,0.05\,5132.0,1.00\,f,T) Eip:«DB5US
TRIANGLE LABS  Text:TLI»44376 109-112                       IK7. TIME -   16:54
10 0$                                 A1.61E7        A1.62E7
  80:
  60:

  40:

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  0:
                                                                            A1.40E7
        32:00  .                        33:00                         34:00
rile:T980154 »l-396 Acq: 6-JZN-98  16:51:52 EI+ Voltage SIS 70T
392.9760 F:3 Exp-.NDBSVS
TSIANSLE LABS  Text:TLH44376 109-112                       UTJ. TIME -   16:54
1004         32:11  32:24              32:58            33:33   33:47   34:04      34:25
        32:00                          33:00
Tile:T980154 tl-396 Acq:6-JAN-98 16:51:52 EH- Voltage SIS 70T
445.7555 Fi3 Exp-.NDBSUS
                                                                     34:00
TSIANSLE LABS  TextsTLH44376 109-112
1001
80:

60:

40:

20:

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                                                            HTJ-.  TIME -   16:54
                                                                              13
                              32:43
                                                    33:25
                                           33:09

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389.8156 T:3 BSOB(256,30, -3. 0)  PlO>(7r 5,3,0.05\,10332.0,1.00\,r,T) EjcptNDBSUS
TRIANGLE LABS  Text:TLIt44376 109-112                       IKT. TIME -   16:54
1001                    A4.69E7
 80.

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                           A3.96X7
Al.86E7
                                        A3.06E6
      32:24    32:36    32:48   33:00   33:12   33:24    33':3,
r±le:T9S0154 tl-396 Acq:6-JAlT-9a  16:51:52 EI+ Voltage SIX
391.8127 F:3 3SUB(256r30,-3.0)  PKD(7,5,3, 0.05\,9108. 0,1. 00
TRIANGLE LABS  TextsTLIt44376 109-112
1004                    A3.S6E7
                                                      6
                                                       O
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A1.54E7
                                                                33:48    34:00
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                                                                  TIME -   15:54
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                                                                       A8.23E6
                                                                                34:12   34:24
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      33\24   32^36    32:48   33:00   33:12   33:24    33:3£   \33s48    34:00    34:12   34:24
Tile:T980154 #1-396 Acq:6-JAN-98  16:51:52 EI+ Voltage SIS 70T Voiae:1324
401.8558 F:3 BSUB(256,30, -3 . 0)  PXD(7, 5,3, 0. 05%, 5296. 0,1. OOl,r,\T) Exp:NDB5US
TRIANGLE LABS  Text:TLIi44376 109-112                     •  IK7. TIME -   16:54
1001                                                       i    i        A1.33E7

 80.

 60.

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      32:24    32:36    32:48   33:00   33:12   33:24    33:36    33:48    34:00    34:12   34:24
rile:T980154 tl-396 Acq: 6-JAN-98  16:51:52 EI+ Voltage SIX 70T Koine: 798
403.8529 t:3 BSUS(256, 30,-3.0)  PKD(7, 5,3, 0. 05%,3192. 0,1. 00\,r,T) Exp:NDB5US
TRIANGLE LABS  Text:TLI#44376 109-112                     j  1X7. TIME -   16:54
1001            ,     .                                      i    '        A1.15E7

 80.

 60.

 40.

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                                                            >OT\'
                                                               i
                                                             XK7.  TIME "
                                                               133:47
                                                                                   34:25
      32:24    32:36    32:48   33:00   33:12   33:24   33:36   ,33:48   34:00    34:12   34:24
rile:T980154 tl-396 Acq:6-JAN-98  16:51:52 EH- Voltage SIR
392.9760 T:3 Exp:NDB5OS
TRIANGLE LABS  Text:TLIt44376 109-112
      32:2432:32       33,5032i58  33:08           33:33
    "V^^-^-^X^^yv^k^.        -^
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                                                                                                     125

-------
rila:T980154 #1-563 Acqs6-JAN-98 16:51:53 XI+
Voltage
SIR 70T Roiaet 1216

407.7818 r>4 SSUB(356,30,-3.0) PXD(7,5,3,0.05\,4864.0,1.00\,rfT) XxpiSDBSOS
TRIANGLE LASS Text :TLI#44 376 109-112
1001
80:
sol
40:
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A2.30E7
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UKT. TOE - 16:54







37\00
Voltage
409.7789 f:4 BSUS(256, 30, -3. 0) PXD(7,5,3,O.OS\,4316.0,
TRIANGLE LASS Text:TLI#44376 109-113
100}
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417.8253 F:4 BSU3(256, 30, -3. 0) PKD(7,5,3,0 .05\,2784 .0,
TRIANGLE LASS Text:TLI#44376 109-112
1003
80:
60:
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A


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'36:00 '36':12 ' 36:24 ' 'j'fil-Jff 36\48
rile:T980154 #1-563 Acq:6-JAN-98 16:51:52 EI+







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Voltage
419.8220 F:4 BSUB( 256 ,30, -3 . 0 ) PKD( 7, 5, 3, 0 . 05\,2536 . 0,
TRIANGLE LABS Teit:TLI#44376 109-112
100}
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430.9729 F:4 ExpiNOBSOS
TRIANGLE LASS Text:TLI#44376 109-112
1003
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TRIANGLE LABS Text:TLI#44376 109-112
100}
80.
60:
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36:13
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file:N80154 tl-563 Acq:6-JAti-S8 15:51:53 BI+ Voltage Six 70T Xoiae:357 	
423.7766 r:4 BSOS(256, 30, -3.0) PKD(7,5, 3,0.05\,1428. 0,1 .00%, r,T) XrpsSDBSUS
TRIANGLE LABS Text:TLI*44376 109-112 HK7. TIME ' 16:54
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80.
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3
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425.7737 T:4 BSUB(256, 30, -3. 0) PXD(7,5,
TRIANGLE LABS TeJCt:TLIt44376 109-112
1003

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52 EI+ Voltage SIS 70T Noia*il99
3,0.05\t796.0,1.00\,r,T) Exp:SDB5US
HTJ. TIKE - 16

A6.23E6
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36:48 36:54 37:00 37:06 37:12 37:18
rile:T980154 #1-563 Acq:6-JAN-98 16:51:52 EH- Voltage SIS 70T Noiaei 664
435.8169 T:4 BSUB(256 , 30 , -3 .0 ) PKD( 7, 5, 3, 0 . 051,2656. 0,1 . 00%, T, T) Eip:NDB5US
TRIANGLE LABS Text.:TLI#44376 109-112 INJ. TIME - IS
1003
30.
60.
40.
20.
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3



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jiii s'eVis' 3-6\24 J6iJO 36\36 36*:42
rile:T9a0154 il-563 Acq: 6 -JAN- 9 8 16:51:
437.8140 F:4 BSU3( 256, 30, -3 . 0) PXD(7,5,
TRIANGLE LABS Text:TLI»44376 109-112
1001
BO.
60.
40.
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3





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BSUS(256,30,-3.0) PKD(7,5,3,0.05\,952.0,1.00\,T,T) XxptODBSUS
TRIANGLE LABS Tajct:TLI#44376 109-112
1001
90.
80;
70;
601
50;
40;
30;
201
10;
0





















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OKT. TIME - 15:54
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#1-563 Acq:6-JAN-98 16:51:52 EI+ Voltage SIS 70T
Exp:NDB5US

TRIANGLE LASS Tejct:TLI#44376 109-112
1001

90.
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80;

701
60;
501
40;
301
201
101
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128

-------
Pila:TSB0154  U-5S3 Acq:6-J3Ut-99 li»Si»53 «> Voltage SIS 70T HoiaeiSS	
457.7377 f:4  BSU3(356, 30, -3. 0) PKD(7,5,3,0.05\,336.0,1.00\,r,T)  ExpsSDBSVS
TRIANGLE LASS TextsTLI*44376 109-112                        JJKT. TIME -   16t54
lOOS,        A3.54X6
                                                                              41134
         40:54         41:00          41:06         41:13        41:18
riletT980154  tl-563 Acq:6-JAS-98 16t51t53 EH- Voltage 31S  70T SoiaatS7
459.7348 T:4  BSU3(2S6,30,-3.0) PKD(7,5,3fO.OS\,338.0,1.00\rT,T)  XxptUDBSOS
TRIANGLE LASS TejCt:TLIf 44376 109-113                        UKT.  TIMS -   16:54
100*        A3. OSES
  30.
  0.
                                                                              41:34
         40:54          41:00          41:06         41:13         41:18
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469.7779 P:4 BSUB(256, 30, -3 . 0)  PKD(7,5,3, 0. 051,388. 0,1.00\,T,T)  Exp:NDBSUS
TRIANGLE LABS  Text:TLI#44376 109-113                        INJ-.  TIME -   16:54
lOOi      A1.JOE7
 so:

 60.

 40.

 30.
                                                                              41:34
         40:54          41:00          41:06         41:13         41:18
F±le:T980154 fl-563 Acq: 6-JZN-98 16:51:53 EH-  Voltage SIS  70TlToiaei66
471.7750 f:4 BSUB(3S6, 30, -3. 0) P1O)(7, 5,3, 0.051,364.0,1.00\,F,T) Exp:lTDB5US
TRIANGLE LABS  Text:TLHf44376 109-113                       IKT.  TIKE -   16:54
100*      A1.J3E7
         40': 54         41:00          41:06         41:13         41:18         41:34
rile:T980154 tl-563 Acq: 6-JAN-98 16:51:53 XI+ Voltage SIR  70T
430.9739 F:4 KxptlHIBSaS
TRIANGLE LABS  Text:TLIf44376 109-113                       JM7. TIME  -    16:54
100%    40sJ4          41:00  -      4JJ.07            41:14
 80.

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-------
Chans!.   I  338,2782     Peak top
Hiight  3,59 golts Span   238 ppa
Systaa file nae
Data   fiLenae
Resolution
Group nuater
Ionlzati.cn acde
Switching
Ref, aasses   232,3825,
fl   293     J   331
8   384
    386
    316
    318
    329
    ^2
    328
    331
K   332
L   334
fl   348
H   342
0   352
P   354
Q   356
R   358
           ft:
      2
    Q*
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415,3768
S   3S8
T   378
U   376
V   418
tef,  aass    416,3768     Peak top
Kelcht    ,36 ^L'  Span   298 ppa
                                                                 13C

-------
File:T980154  #1-810  Acq:6-JAN-98 16:51:52 EI+ Voltage SIR 70T
319.8965 F:2  Exp:NDB5US
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Sample Text :TLI#44376 109-112
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                                                   INJ.  TIME
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Sample Text :TLI#44376  109-112
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Sample Text:TLI#44376  109-112                        INJ. TIME =
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Sample Text:TLI#44376  109-112                        INJ.  TIME =
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Sample Text:TLI#44376 109-112                        INJ. TIME
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File:T980154  #1-396  Acq:6-JAN-98 16:51:52 EI+ Voltage SIR 70T
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                            33:38  33:40  33:42
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                          Time
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-------
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-------


TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
.Sfeg&ljag $ll!£6&$&l$!$&!$$$$S$ffi

44376
109-112


.. 1 Method 23 TCDD/TCDF Analysis (DB-225)
- '- ^ Analysis File: X9800«
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97 Spike File: SPC2NF04
194-59-2A-D Date Extracted: 12/29/97 ICal: XP24087
Date Analyzed: 01/07/98 ConCal: X980080
1.000
n/a
DB-225
Dilution Factor: n/a % Moisture: n/a
Blank File: X980083 % Upid: n/a
Analyst: KAS % Solids: n/a

AnaJytes , ,
2,3,7,8-TCDF
Internal Standard
I3C12-2,3,7,8-TCDF
Recovery Standard
13C12-1,2,3,4-TCDD
- ' A*

nu'ins) ^ro^'V**aiig&\v . ;,u«t»'/*:\;irr " ^iag«'
26.2 0.78 21:29 E_
AmL (ng) % Recovery OC Limits Ratio f)T Flags



3.3 83.4 40%-130% 0.80 21:28 	
Ratio/ ITT Ffegs
0.81 20:28 	
Data Reviewer.
                                                                         01/11/98
                       Page 1 of 1
                                                                                          C3NFJ>SR rUI. LARS (S.lo3P
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                            Printed: 13:33 01/11/98
                                                                144

-------
 Data Review By:
Initial    ....Date...

          ( I \( I VP  Calculated Noise Area:
                                                                      2.00
 The Total Area for each peak with an ion abundance ratio  outside
m atio limits has been recalculated according to method requirements.
 Page Mo.
 01/11/98
 Listing of X980085B.db£
 Matched OC Peaks / Ratio / Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Na
                                                                            ID.. Flags.
TCDP
304-306 DC HL 0
0.
:00 RO
17:06
17
17
17
18
18
•22
:36 RO
:44
:04
:12
18:20
18
. 18
18
1 19
, 19
19
19
19
20
20
20
20
20
• 21
21
21
21
21
21
22
22
23
DC WH 23
:30
:46
-.55
:04
:09
:14
:24
:45
:03
:10
-.26
:37 .
:49
:00
:13
:22
:29
:42
:55
:02
:42
:18
:42
304-306 29 Peaks
13C12-TCDP
316-313 DC NL 0
DC ML 18
DC WL 18
DC WL 19
DC WL 19
DC ML 19
DC WL 20
DC ML i 20
21
0.
:00 RO
:02 RO
:48
:12 RO
:43
:59 RO
:11
:25
:28
.65-0.89
1.15
0.78
0.76
0.58
0.80
0.77
0.79
0.77
0.78
0.78
0.77
0.77
0.77
0.77
0.77
0.78
0.30
0.66
0.78
0.78
0.79
0.78
0.84
0.78
0.78
0.78
0.77
0.78
0.78
0.80
0.72
4
65-0.89
1.35
7.44
0.36
0.95
0.72
0.58
0.83
0.85
0.80
391.
94,061.
1,238.
1,710.
3,613.
124,354.
105,053.
202.710.
102,563.
90.350.
195,943.
101,077.
102,093.
250,452.
123.180.
582,450.
971.
134,623.
193,233.
170,614.
28.984.
248,089.
4.255.
241,364.
181,006.
231,365.
281,883.
260,093.
158,536.
27,650.
1,053.
,293,538.
84
40
83
00
34
10
40
60
70
50
90
00
30
00
30
00
26
10
40
60
70
00
09
00
00
00
00
00
30
90
22
22
0.790-1.095
0.000
41,144
534
743
1,605
54,236
46,282
88.084
44,907
39,464
85,510
43,935
44,502
109.313
53,585
254,315
432
73,606
84.445
74,879
12,804
108,325
1,948
105.566
79,438
101,329
122.884
114,219
69,303
12.297


.90
.32
.90
.07
.70
.70
.60
.00
.60
.90
.30
.40
.00
.80
.00
.41
.10
.40
.00
.40
.00
.28
.00
.00
.00
.00
.00
.30
.70


52,916
704
1,293
2,008
70,117
58,770
114,626
57,656
50,885
110,438
57,141
57.591
141,134
69,594
323,135
538
111.022
108,788
95.735
16,180
139.264
2,306
135,798
101,568
130,036
158,999
145,879
89,233
15,353


.50
.51
.41
.77
.40
.70
.00
.70
.90
.00
.20
.40
.00
.50
.00
.35
.00
.00
.50
.30
.00
.81
.00
.00
.00
.00
.00
.50
.20


0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1

.797
.309
.820
.326
.342
.848
.854
.862
.874
.381
.883
.392
.396
.904
.920
.934
.939
.952
.960
.970
.978
.983
.995
.001 2378-TCDF AW
.011
.021
.026
.057
.085
.104







B


E


E

E

E
Z
B

Z

E
E
E
E
E
E



0.953-1.047
37.
6.
76.
133.
96.
78.
394.
503.
28,533.
51
74
33
09
67
22
33
94
30








12,663,








.10








15,870








.20
0
0
0
0
0
0
0
0
1
.000
.840
.876
.894
.913
.931
.940
.951
.000 13C12-2378-TCDP ISO









Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 13:18 01/11/98
                                                                         145

-------
  Page No.
  01/11/98
         Listing of  X98008SB.db£
         Matched OC  Peaks-/ Ratio / R«t. Tim*
  Compound/
  M_Z	QC.Log Omit why . .RT. OK Ratio Total.Area... Area. Peak. 1..  Area.Peak.2.. Rel.RT Compound. Nan»..  ID..  Flags.
  316-318
        21:51 RO  1.15         67.84
        22:01 RO  1.03        106.77
DC  WH  23:17 RO  0.28         65.35
DC  WH  23:43 RO  4.25         16.73
      3 Peaks             28,707.91
                                                             44.22
                                                             62.05
          38.33  1.018
          60.32  1.026
                 1.085
                 1.105
  13C12-TCDD
  332-334

DC NL








DC WH
DC WH
DC WH

0
19
20
20
21
21
21
22
22
22
22
22

:00
:07
:12
:28
:09
:37
:54
:01
-.10
:14
:29
:34
0.
RO



RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
1
0
0
0
0
2
3
1
1
2
2
1
•52
.73
.78
.81
.95
.08
.34
.60
.21
.54
.26
.10
                                        Above: TCDP  / TCDD Follows
  332-334
                       3 Peaks
                              26.64
                             125.15
                          21,002.45
                          24,576.20
                             282.86
                              30.25
                              13.56
                              35.97
                               9.40
                               6.60
                              36.37
                              11.72
                          46,075.34
                                                             52.93
                                                          9,190.25
                                                         10,977.20
                                                            152.02
                                                             35.47
                                                             25.61
                                                             32.49
                                                              6.41
0.901-1.099


11
13









72
,812
,599
159
17
7
20
5




.22
.20
.00
.81
.09
.66
.32
.31



0
0
1
1
1
1
1
1
1
1
1
1
.000
.946
.000
.013
.047
.070
.084
.090
.097
.101
.113
.117


13C12-2378-TCDD IS1
13C12-1234-TCDD RSI








 Column Description.
                •Why" Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time (mm:33)
 Rat.l -Ratio of M/M+2 Ions
 OX    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
     Rnd of Report
               WL-Below Retention Time Window
               WH-Above Retention Time Window
               SN-Below Signal to Noise Level
               
-------
Pila-TSSOOBS 91-883  Aeqt  J-J1N-1S93 lU>07t24 X gJ* Voltage SIS AutoSpec Holmmtl27777
303.9016 aaVB(356,30,-3.0)  PSD(S,3, i, 0.10*,511108.0,0.00*,?,?) B3CptKOSr_TT
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loon
                                                                                  33 tOO
                                                                                                ,4.038


                                                                                                 .3.250

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                                                                                                 1.6E7

                                                                                                 8. OSS
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   Time
  17*00
                10*00
                             19100
                                          20*00
                                                       21:00
                                                                                                14'

-------
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Sample Text:TLI#44376 105-108 Pile Text: TRIAHOLE LABS
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1003
80.
60.
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A1.36B8
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18/00 	 15/00 70/00 71/00 	 77/00








.3.6E7
.7.857
.7.1S7
.1.457
.7.15^1
0.050 T
'73/00' Time\
148

-------
File:X980085 01-883 Aeq: 7-JAN-1999 18:07:24 OC SX+ Voltage SIR AutoSpec
303.9016 Bxp:XCOSF TT

Sample Text:TLIt44376 105-108 File Text: TRIASOLS LABS
IOCS
SOU
sol

401
201
If
19:14
18,20 |
A
18,0 « "'»
A MA HAM
17:00 18:00 15:00
45
, 21:00 22:02
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10 0*
aol
601
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17:00 ' ' isiflO 15:00
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21:28 3.157




A
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Sample Text:TLI»44376 105-108 File Text: TRIANOLS LASS
100*
aol

sol
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20.
0;
17:56
1
18:25
; (i
19:0819:32
• 11 11 AAA
17:00 ' 18:00 ' 15:00
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15.357
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.1.758
O.OBO
SOiOO 21:00 ' 22:00 ' 23:00 Time
14S

-------
Peak Locate Examination: 7-JAN-1998:18:07 File:X980085
     Experiment:XCONF_TT Function:! Reference:PFK

-------
TLI Project:     44376
Blient Sample:   113-116
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  T980155
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-3A-3D

1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01706/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
^.3,4,7,8-HxCDF
R,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF !
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7.8.9-OCDF


Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

1.5
7.6
2.4
.3.3
5.0
2.5
1.3
EMPC 72:7 r 1
37.5 '*'**,
50.9 ''*/*
35.3
16.4
9.5
0.46
8.2
0.76
0.73


99.1 13
193 10 197
75.8 7
5.4 2
-§54- 7/16 62?- »V
45T ' 2z
-------
TLI Project:      44376
Client Sample:   113-116
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:  T980155
internal Standards
13C12-2,3,7,8-TCDF .
13C,2-2,3,7,8-TCDD
'3C12-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C12-l,2,3.6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
3Ci2-l,2,3,4,6,7,8-HpCDD
13Cu-l,2,3,4,6,7,8,9-OCDD

Surrogate Standards (Type A)
"CL-WJ-S-TCDD
13C,:-2,3,4,7,8-PeCDF
13C12-U,3,4,7,S-HxCDF
13Ci:-l,2,3,4,7,8-HxCDD
13Cp-l,2,3,4,7,8,9-HpCDF

Alternate Standards (Type A)
13Ci:-l,2,3,7,8,9-HxCDF
13Ci:-2,3,4,6,7,8-HxCDF
Recovery Standards
13C12-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt (ng)
2.3
3.0
3.0
3.6
3.0
2.5
3.2
4.3
9.1

AmL (ng)
3.5
3.9
3.9
5.7
3.9

Amt. (ng}
3.3
3.0



% Recovery
57.1
75.7
74.1
90.5
75.5
62.8
81.2
109
114

% Recovery
88.5
97.4
96.6
142
96.9

% Recovery
83.2
76.1



QC Limits
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%

QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%

QC Limits
40%- 130%
40%- 130%



Ratio
0.75
0.80
1.51
1.53
0.51
1.16
0.45
1.04
0.92

Ratio

1.53
0.52
1.17
0.44

Ratio
0.51
0.52
Ratio
0.80
1.15
RT
25:41
26:21
29:31
30:33
33:00
33:42
36:00
37:05
40:57

RT
26:23
30:14
32:54
33:37
37:37

RT
34:18
33:31
RT
26:10
34:02
Flags
Q_
	



Q_
	



Flags



Q_


FtagQ

	
Fiags


                     Data Reviewer.
            01/15/98
                                       Page 2 of 2
                         X37.PSRv2.cn.LARS S.
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 09:26 01/15/98
                            152

-------
Initial    ....Date...

          ^  I (4l £i» Calculated Noise Area:
  Data Review By:
 The Total Area for each  peak with an ion abundance ratio  outside
       limits has been recalculated according to method requirements.
 Listing of T9801S5B.dbf
 Matched GC Peaks / Ratio / Ret.  Time
 Page No.
 01/15/98
                                                                       2.00
 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name..  ID..  Flags.


 TCDF
 304-306
  04-306
 316-313
 316-318
 TCDD
 320-322

DC

















DC

NL 0
22
23
23
23
24
24
24
24
25:
25
25
25:
26:
26:
26:
26:
27:
WH 27
0
:00 RO
:40
:09
:22
:44
:01
:25
:41
:54
:06
:1S
:31
:43 RO
07
:13
:33
:50
:23
:36
.65-0.89
1.59
0.80
0.30
0.79
0.31
0.81
0.80
0.76
0 . 30
0.31
0.31
0.80
0.93
0.31
0.31
0.30
0.66
0.77
0.73
' 17 Peaks

DC
DC
DC
DC
DC
DC
DC






DC
DC

NL, 0;
WL_ 22:
WL 23:
. WL 23:
WL 23:
WL 24:
WL 24:
24:
24:
25:
25:
26:
26:
WH 26:
WH 27:
0.
:00 RO
:41 RO
: 09 RO
31 RO
:43 RO
04 RO
26 RO
41 RO
54 RO
30 RO
41
06 RO
34 RO
52
05 RO
6 Peaks

DC

NL 0:
0.
00 RO
.65-0.89
1.17
2.60
5.82
1.26
2.70
1.46
2.13
1.28
2.24
1.17
0.75
1.56
1.14
0.37
1.08


12
14
14
72
43
51
43
62
38
24
24
61
33
26
4

3

534











2




2
65-0.89
1.03


3.
,709.
.741.
.866.
.910.
,563.
.271.
.809.
,577.
,767.
.794.
.099.
,949.
,303.
,195.
,707.
281.
,370.
849.
,419.

4.
5.
5.
15.
30.
44.
29.
53.
34.
40.
,488.
30.
6.
8.
10.
.659.
TCDF
2.

93
64
61
45
60
90
00
10
30
30
20
90
12
30
30
94
46
51 - .
31
63

04
47
38
24
90
57
10
64
87
21
43
55
96
68
37
66
/ TV
/ k\m
58


5.656
6,555
6,553
32,562
19,456
22,787
13,960
27,817
17,393
11,079
10,716
32,501
15, 110
11.748
2,087
111,
1, 462.










42.
44.
26.
1,063 .
27.
4.




.21
.04
.09
.30
.70
.90
.80
.00
.40
.30
.60
.30
.30
. 90
.46
,59
30










33
19
62
52
01
48




7
3
3
40
24
28
24
34
21
13
13
34
13
14
2

1













1




0.

,053.43
,186.57
.313.36
,348.30
,107.20
,483.10
,348.30
,760.30
,374.40
,714.40
,383.30
,999.50
,693.00
,446.90
,620.48
169.87
,908.21


0.







33.13
19.70
22.72
,424.91
17.26
3.33


378-1.073
0.000
0.383
0.901
0.910
0.924
0.935
0.951
0.961
0.970
0.977 .
0. 985
0.994
1.001 2373-TCDF AN
1.017
1.024
1.034
1.045
1.065
1.075

961-1.039
0.000
0.383
0.901
0.916
0.923
0.937
0.951
0.961
0.970
0.993
1.000 13C12-2378-TCDF ISO
1.016
1.034
1.046
1.055


QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
SE
QE
QE
Q
Q
Q













Q




'Tin T?rtl T otije




0.903-1.045

0.000

Triangle Laboratories, inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed:

-------
  Page No.    2
  01/15/98

  Compound/
  M_Z....  QC.Log Omit Why
Listing of T980155B.dbf
Matched GC Peaks / Ratio / Ret.  Time
.RT.  OK Ratio Total.Area... Ar ea.Peak.i. .  Area.Peak. 2. . Rel.RT Compound.Name..  ID.. Flags.






M
M
AN




320-322
37C1-TCDD
328


















328
13C12-TCDD
332-334












332-334
23
24
24
25
25
25
26
26
26
26
26
26
27
:55
:13
:35
:14
:30
:52
:10
:16
:23
:32
:41
:54
:20
0.78
0.78
0.78
0.78
0.78
0.79
0.79
0.78
0.79
0.76
0.78
0.78
0.75
13 Peaks
20,501
12,997
5.413
14,004
9,398
5,369
5,210
8,720
1,407
2,263
2,572
787
852
90,007
.91
.09
.63
.00
.98
.21
.00
.00
.00
.43
.81
.36
.01
.48
8,966
5,710
2,378
6,149
4,345
2,367
2,300
3,830
620
983
1,127
345
366

.31
.40
.32
.65
.89
.98
.00
.00
.00
.17
.37
.67
.26

11,535
7,286
3,040
7,854
5,553
3,001
2,910
4,390
787
1,285
1.445
441
435

.60
.69
.36
.35
.09
.23
.00
.00
.00
.26
.44
.69
.75

0.908
0.922
0.933
0.958
0.968
0.982
0.993
0.997
1.001 2373-TCDD AN
1.007
1.013
1.021
1.037

E
E

E
E


E






0.924-1.076
DC NL 0
DC WL 23
DC' WL 24
DC WL 24
24:
24:
25:
25:
25:
25:
25:
26:
26:
26:
26:
DC SN 27 :
27:
27:
27:
:00
:55
:10
:17 .
;27
:35
:01
:13
:28
:45
52
10
:23
31 '
44
02
20
33
45



















14 Peaks

DC NL 0:
DC WL 24:
DC SN 24:
DC SN 24:
DC SN 25:
25:
25:
26:
26:
26:
26:
DC SN 26:
27:
0.
00 RO
09 RO
25 RO
50 RO
05 RO
15 RO
47
10
21
40
52 RO
59 RO
40
65-0.39
2.06
1.20
4.67
0.55
0.42
1.10
0.82
0.80
0.80
0.30
0.98
0.96
0.70
7 Peaks
1
116
240
186
10
25
2,106,
77.
59.
28.
42.
31.
2,373.
•54,
3,573.
1.
7.
9.
15.
3,414.
.94
.60
.99
.98
.24
.38
.43
.46
.19
.65
.16
.36
.10
.01
.81
39
01
29
04
13




10,
25,
2,106.
77.
59.
28.
42.
31.
2,373.
54.
3,573.

7.
9.
15.





.24
.33
.43
46
19
65
16
36
10
01
81

01
29
04









































0.000
0.903
0.917
0.922
0.928
0.933
0.949
0.957
0.966
0.977
0.982
0.993
.1.001 37C1-TCDD SUR1
1.006
1.015
1.026
1.037
1.046
1.053





















0.924-1.076
4.
2.
3.
3.
4.
20.
7.
2,821.
2,666.
46.
10.
3.
7.
5,580.
13
30
26
40
11
48
72
01
46
96
02
27
36
01





12.
3.
1,249.
1,182.
20.
5.

3.






75
47
47
78
32
53

03











11. «7
4.
1,571.
1,433.
26.
5.

4.

25
54
63
14
66

33

0.000
0.917
0.927.
0.942
0.952
0.958
0.978
0.993 13C12-1234-TCDD. RSI
1.000 13C12-2378-TCDD IS1
1.012
1.020
1 . 024 '
1.050















Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/15/98
                                                                                                 154

-------
  Page No.
  01/15/98
Listing of T980155B.dbf
Matched GC Peaks  / Ratio
/ Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Ar ea.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
PeCDF
340-342




















340-342
13C12-PeCDF
352-354















352-354
PeCDD
356-358




DC NL 0
27
27
23
28
28
28
28
28
29
29
29
29
29
29
30
30
30
30
30
31

:00
:35
:51
:03
:12
:19
:34
:42
-.52
:10
:15
:27
:32
:41
:49
:05
:15
:24
:42
:52
:09
1

RO





RO













20 Peaks

DC NL 0:
' 27:
DC SN 27:
DC SN 27:
28:
28:
29:
; 29:
29:
29:
30:
30:
DC SN 30:
31:
DC SN 31:
DC SN 31:

:00
:35
:45
:58
:41
:52
:10
:15
:31
43
14
24
35
03
20
26
1.

RO
RO
RO
RO
RO
RO
RO

RO

RO
RO
RO
RO
RO
10 Peaks

DC NL 0:
28:
29:
29:

00
48
15
29
1.
RO



.32-1.78
1.37
1.23
1.50
1.44
1.60
1.37
1.48
1.09
1.47
1.48
1.44
1.48
1.49
•1.48
1.49
1.71
1.48
1.50
1.49
1.50
1.46
0.931-1.063
2.77
47,862.35
1.050.24
324.60
1,127.86
475.67
28,409.50
69,064.53
32,990.00
42,296.30
42,325.90
20,364.50
26,630.30
22.386.99
29.456.90
437.42
36,096.00.
33,304.40
1.962.78
1,025.04
2,635.26

29.092
630
191
694
275
16,967
41.980
19,629
25,220,
24,981.
12,166.
15,942.
13,353.
17,620.
276.
21,524.
19,972.
1,175.
614.
1,593.

.80
.73
.38
.11
.37
.30
.40
.30
.30
.00
.00
.90
•10
.60
16
90
40
00
23
33

23,566
419
133
433
200
11,441
38,418
13,360
17,076
17,344
8,198
10,687
9,033
11.836
161
14,571
13,332
787
410
1.091

.30
.51
.22
.75
.30
.70
.50
.20
.00
.90
.50
.90
.89
.30
.26
.10
.00
.73
.31
.93
0.000
0.935
0.944
0.950
0.955
0.959
0.963
0.972
0.978
0.988
0.991
0.998
1.001 12378-PeCDF
1.006
1.010
1.019
1.025 23478-PeCDF
1.030
1.040
1.046
1.055

SE




E
SE
E
E
E

AN

E

AN E
E
Q


440,277.04
32-1.78
1.34
2.70
3.33
3.03
1.99
1.24
2.20
2.37
1.51
1.92
1.53
2.10
0.52
1.09
1.28
3.20

32-1.73
1.11
1.39
1.53
1.55
0.364-1.136
1.31
32.'21
1.56
2.24
143.38
45.31
22.77
27.92
2.677.40
50.72
2.589 .49
32.59
1.94
9.57
2.65
2.04
5,636.36
PeCDF / PC

1.55
42,912.10
3,359.02
22,841.13

34.


116.
27.
19.
25.
1,612.
38.
1,567.
26.

5.


i(**nn i?rti T f\
H— UL> rOXXO

24.985.
2,031.
13,866.

08


08
54
61
90
63
21
40
90

32





00
35
70

12.


53.
22.
8.
10.
1.064.
19.
1.022.
12.

5.




.63


19
.18
,93
95
72
39
09
78

35



o.ooo ;
0.935
0.940
0.947
0.972
0.978
0.988
0.991
1.000 13C12-P6CDF 123
1.010
1.024 13C12-PeCDF 234
1.030
1.036
1.055
1.062
1.065









IS2

SUR2






0.939-1.022

17,927.
1,327.
8,974.

10
57
43
0.000
0.943
0.957
0.965

E


Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Pfoone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/15/98

                                                                         155

-------
  Page No.     4
  01/15/98


  Compound/
  M_Z.... QC.Log Omit Why
Listing of T980155B.dbf
Matched GC Peaks / Ratio / Ret.  Time
.RT.  OK Ratio Total.Area... Area.Peak.1..  Ar ea.Peak.2. . Rel.RT Confound.Name..  ID.. Flags.




A



356-358
13C12-PeCDD
368-370











363-370
HxCDF
374-376






X




AX
M
MX
AN
M

374-376
13C12-HXCDF
384-336


29
29
30
30
30
30
30
31
:37
:48
:03
:17
:26
:34
:40
:00




RO



1.54
1.55
1.56
1.56
0.93
1.57
1.55
1.58
11 Peaks

DC NL 0
28
DC SN 29
29
29
29
29:
DC SN 30:
30:
DC SN 30:
30:
DC SN 31:

:00
:48
:10
:16
:29
:38
:49
:04
:16
:25
:33
:35
1
RO
RO
RO
RO
RO
RO

RO
RO
RO


.32-1.78
1.25
3.14
1.96
1.11
2.23
1.99
1.63
6.07
1.34
2.34
1.53
1.54
7 Peaks
._. ... *u«

DC NL 0:
DC WL 31:
31:
32:
32:
32:
32:
X 32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:

00
46
57
05
15
23
32
44
54
02
08
20
26
31
15
18
24
48
1.

RO





RO




RO

RO



05-1.43
1.31
1.72
1.26
1.22
. 1.25
1.25
1.23
1.20
1.26
1.25
1.23
1.26
1.26
1.26
1.27
1.30
1.28
1.24
15 Peaks

DC NL 0:
31:
32:

00
57
05
0.
RO
RO
RO
43-0.59
1.27
1.06
1.17
5
15
9
5
2
4
1
2
115











1,

1
ve : i


16,
41,
3,
4,
2,

23,
12,
2,
3,

5,
1,

1,

119,
,488
,780
,721
,443
,336
,447
,078
,198
,607

1
28
6
5
22
7
. 12
4
3
3
,313
2.
,893
3ef**ir
*e*— *JL
107.
65.
599.
725.
213.
264'.
577.
449.
714.
363.
302.
713.
571.
740.
023.
260.
109.
194.
635.
.99
.11
.75
.55
.13
.93
.77
.25
.74

.15
.87
.15
.38
.11
.47
.79
.16
.95
.85
.26
.13
.33
•) / tlv
j I rm
.70
36
49
90
44
13
15
32
00
42
81
12
00 .
00
00
00
00 .
90
33
3,331
9,589
5,928
3,320
1,420
2,718
655
1,346



35

3
19
5
7

6

1,097

.46
.23
.97
.31
.00
.04
.40
.83



.54

.27
.30
.32
. 92

.46

.13

2,157.53
6,190.38
3,792.78
2,122.75
1,520.00
1,729.89
423.37
851.42

0.

11.32

2.95
8.67
2.93
4.87

3.51

716.13

0.969
0.975
0.984
0.991
0.996
1.001 12378-PeCDD AN
1.004 Q
1.015

369-1.131
0.000
0.943
0.955
0.958
0.965
0.970
0.976
0.934
0.991
0.996
1.000 13C12-PeCDD 123 IS3
1.034
*f~r\I? Ti-il 1 ,-it»fe



9,241.
22,942.
1,782.
2,369.
1,420.
245.
13,211.
6,867.
1.272.
2,072.
318.
3,200.
573.
147.
623.




.05
.80
94
63
48
46
90
68
27
'60
00
00
00
00
00


0.964-1.049


7,358.44
18,783.10
1,430.50
1,894.55
1,156.67
203.86
10,502.10
5,500.74
1,030.54
1.645.52
253.00
2,540.00
450.00
113. OO
486.00


0.000
0.963
0.963
0.972 E
0.977
0.981
0.936
0.992
0.997 123478-HxCDF AN
1.001 123678-HxCDF AN
1.004
1.010
1.013
1.016 234678-HxCDF AN
1.038
1.039 123789-HxCDF AN PR
1.042
1.055

0.879-1.121



4.
14.
34.
74
18
34

9.
26.

98
93

9.39
23.07
0.000
0.963
0.972
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:26 01/T5/98
                                                                                                   156

-------
 Page No.
 01/15/98
Listing  of T9801S5B.dbf
Matched  GC Peaks / Ratio /  Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.










384-386

HxCDD
390-392







390-392
i3c 12 -HXCDD
402-404










402-404
HpCDF
408-410

X

D
D
D


408-410



DC SN
DC SN



DC SN
DC SN
8


DC NL







7

DC NL
DC WL
DC SN'
DC SN

DC SN




DC SN
5

DC NL'

X

D NH
D NH
D NH

DC WH
4
32:54
33:00
33:31
33:51 RO
34:00 RO
34:18
34:31 RO
34:35 RO
34:43
34:52 RO
Peaks

1.
0:00 RO
32:26
32:52
33:06
33:17
33:38
33:43
34:02
Peaks
1.
0:00 RO
32:24 RO
32:47
32:53 RO
33:06 RO
33:15 RO
33:37
33:42
33:53
34:02
34:24 RO
Peaks
0.
0:00
36:01
36:18 RO
36:27
36:42 RO
37:05
37:21 RO
37:39
38:13 RO
Peaks
0
0
0
0
1
0
0
1
0
1


05
0
1
1
1
1
1
1
1

05
1
0
1
0
1
2
1
1
1
1
3

.52
.51
.52
.91
.49
.51
.77
.55
.48
.43


-1.43
.94
.21
.22
.22
.23
.31
.18
.22

-1 .43
.73
.81
. 10
.54
.53
.02
.17
.16
.10
.15
.75

2,069.77
2,327.49
2,239.95
3.40
1.31
1,937.10
8.46
4.67
5.12
1.12
8,636.46
: HxCDF /

9.07
4,101.94
10,164.26
6,416.78
661.45
733.20
1,142.21
1,714.13
24,933.97

4.03
2.04
3.02
3.38
15.34
4.66
1,576.14
1.369.08
9.36
2,183 .96
3.18
5,154.38
88-1.20
1
1
1
1
1
0
1
1
1

.13
.04
.04
.04
.64
.39
.27
.05
.44

5.47
4,796.03
1,309.23
683.36
7.10
9.37
12.30
338.12
19.91
7,131.74
712
785
766


654
4
4



.41
.85
.70


.64
.31
.79



1,357
1,541
1,473


1,282
5
3



.36 0.997 13C12-HXCDF 478 SOR3
.64
.25


.46
.60
.09



1.000 13C12-HXCDF 678 IS4
1.016 13C12-HXCDF 234 ALT2
1.026
1.030
1.039 13C12-HXCDF 789 ALT1
1.046
1.048
1.052
1.057














2.246.
5,582,
3,525.
364.
415.
619.
943.






10.

849.
734.
5.
1,168.


.55
,91
.36
70
.14
19
32






48

63
42
16
20


1,855
4,581
2.391
296
318
523
770






6.

726.
634.
4.
1,015.

0.

.39
.35
.42
.75
.06
.02
.31

0.




.85

.46
66
70
76

958-1.015
0.000
0.962
0.975
0.982
0.988
0.998 123478-HXCDD AN
1.000 123678-HxCDD AN
1.010 123739-HxCDD AN

970-1.030
0.000
0.961
0.973
0.976
0.982
0.987
0.998 13C12-HXCDD 473 SUR4
1.000 13C12-HXCDD 678 IS5
1.005
1.010 13C12-HXCDD 739 RS2
1.021


Q
Q
Q
Q
Q

QPR








Q
Q



u«r"^Tr t?*-si i rtue


2,439.
667.
350.



172.



74
28
51



97



2,356.
641.
337.



165.


0.998-1.053

•29
95
85



15


0.000
1.000 1234678-HpCDF AN
1.008
1.013
1 . 019
1.030
1.038
1.046 1234789-HpCDF AN
1.062











Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed:
3^1/15/98
I i

-------
  Page No.
  01/15/98
Listing of  T980155B.dbf
Matched GC  Peaks  / Ratio / Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why '. .RT.  OK Ratio Total .Area. .. Ar ea. Peak. 1. .  Area. Peak. 2. .  Rel. RT Compound. Name.. ID..  Flags.
13C12-HpCDF
418-420




418-420 '
HpCDD
424-426




424-426
13C12-HpCDD
436-438


436-438

OCDF
442-444





















442-444

DC

DC

DC


DC


DC
DC


DC





DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

DC
DC
DC
DC
DC
DC
DC


DC


NL

SN

SN.
2

NL


WH
WH
2

NL


2


NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN

SN
SN
SN
SN
SN
SN
SN


SN
3

0:00
36:00
37:08
37:37
38:01
Peaks

0:00
36:18
37:06
37:28
37:38
Peaks

0:00
36:18
37:05
Peaks


0:00
35:38
36:15
37:16
37:27
37:34
37:44
37:51
38:15
38:22
38:55
39:06
39:34
39:49
40:09
40:31
40:35
40:49
40:54
41:10
41:27
41:50
Peaks
0
RO



RO

0.
RO


RO
RO

0.
RO




0.

RO

RO
RO

RO
RO
RO
RO


RO
RO

RO
RO
RO
RO
.37
0
0
0
0
0

.88
1
1
1
3
2

38
1
1
1


76'
0
1
0
1
1
'o
0
2
0
5
0
1
1.
2.
0.
0,
0,
0.
0.
-0.51
.88
.45
.45
.44
.31

-1.20
.77
.03
.02
.21
.28

-1.20
.40
.07
.04


-1.02
.91
.64
.77 -
.03
.46
.98
.73
.48
.15
.00
.97
.01
.12
.29
.30
,57
.58
.40
.33
0.84
0.36
0.80




1
1,580
1
1,194
4
2,775

.94
.58 487.08
.46
.97 362.89
.22
•55
D / u»*s~nn v+^.^ i »..».
0.944
0
1,093.50 1
1
332.08 1
1

-1.111
.000
.000 13C12-HpCDF 678
.031
.045 13C12-HpCDF 789
.056



IS6

SUR5


0.976-1.006
0
1,285
1,120
2
2
2,406
.98
.41 653.73
.63 566.54
.43
.28
.04
0
631.68 0
554.09 1
• ' 1
1

.000
.979
.000 1234678-HpCDD
.010
.015



AN



0.973-1.027
2
12
1.713
1,726
.12
.58 6.50
.98 .873.72
.56
HpC DD / Oc c a -C DD and C DF

0.
1.
12.
1.
0.
0.
0.
0.
0.
0.
1.
17.
1.
0.
1.
1.
0.
1.
0.
322.
32.
2.
372.
.38
15
21
46
53
93
93
76
42
11
44
38 8.99
23
32
62
02
79
06
76 '
30 147.61
07 . 14.87
68
25
0
6.08 0
840.26 1


.000
.979
.000 13C12-HpCDD 678




IS7


0.902-1.093
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
8.89 0.
0.
0.
0.
0.
0.
0.
0.
174.69 1.
17.20 1.
1.

000
370
885 .
910
915
917
921
924
934
937
950
955
966
972
930
989
991
997
999
005 OCDF
012
022




















AN



Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 09
15/98

-------
 Page No.
 01/15/98
                         Listing of T9801S5B.dbf
                         Hatched OC Peaks / Racio / Ret. Time
Compound/
J1_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area. .. Area.Peak.1.. Area.Peak.2.

FJDD
                                                                                Rel.RT Compound.Name..  ID.. Flags.
 458-460
 453-460
                      :      .  0.76-1.02
                DC  NL   0:00 RO  1.42          0.23
                        40:57     0.81        445.68
                DC  SN  41:17 RO  1.11          3.42
                      1  Peak  .                445.68
                                                            199.35
             0.902-1.098
                 0.000
         246.33   1.000 OCDD
                 1.008
  13C12-OCDD                    0.76-1.02
  470-472         DC  NL   0:00     1.00          0.26
                         40:57     0.92      2,441.31
                 DC  WH  41:29 RO  0.61          3.80
  470-472               1  Peak                2,441.31
                                                         1,168.53
             0.998-1.006
                0.000
       1,272.78  1.000 13C12-OCDD
                1.013
                                                                                                     I S3
 Column Description.
                               "Why" Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time  (mm:ss)
 Rat.l -Ratio of M/M+2  Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report ***
                               WL-Below Retention Time Window
                               WH-Above Retention Time Window
                               SN-Below Signal to Noise Level
                               
-------
                      A3.36X8
r±le:T9801S5 #1-810 Ac~1   _  >\  / k
                                                               26:00
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                                                                  .0.0X0
                                                                      Time



                                                                  .1. 8X7

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                                                                                                 160

-------
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TRIANGLE LASS Tajct:TLIt44376 113-116 ISJ. TIME - 17:40
100J
80:
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40:
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AS. 7 1X7
A AS. 15X7
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TRIANGLE LASS Text: TLH44376 113-116
1001
80:
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-------
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TRIANGLE LABS Text:TLI»44376 113-116
1001

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401
201

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TRIANGLE LABS Text:TLI#44376 113-116
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TRIANGLE LABS Text:TLI#44376 113-116
1001
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Al

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TRIANGLE LABS Text:TLI#44376 113-116
1001
80:
60:
401
20:
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28 1-00







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TRIANGLE LABS Text:TLI#44376 113-116
1001
80.
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40:
20:
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TRIANGLE LABS Text:TLI*44376 113-116
1001
80:

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40:
20:













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-------
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355.8546 T:2 3SUS(256, 30, -3. 0) PXD(7,5,3,0.05\,1876.0,1.00\rr,T) Sxp:SOB5US
TSIASGLE LASS Text:TLI#44376 113-116 JX7. TIMS - 17:40
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357.8516 F:2 SSUS(256, 30, -3. 0) PKS(7,5, 3, 0. 05\,1708. 0,1. 00\,f,T) 1
TRIANGLE LASS Text:TLI#44376 113-116 JKT. :
1001
00.

50.

40.
20J
0

A1.79E8
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A8.97E7
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file:T980155 #1-810 Acg : 6 -JAN- 9 8 17:37:38 EI+ Voltage SIR 70T Noie
367.8949 F:2 SSUS( 256, 30, -3. 0) PXD( 7,5, 3, 0. 051,1396. 0,1 . 00%, T, T) I
TRIANGLE LASS Text:TLI#44376 113-116 XK7. 1
1003
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60.
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201-40 29:00 29:12 29-24 29.' 36 29:40 JO-00 jb.'l2 jbi24 JO
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369.8919 T:2 SSU3(256, 30, -3. 0) PKD(7,5, 3, 0. 05\,1128. 0,1 . 00\,f, T) 1
TRIANGLE LASS Text:TLI#44376 113-116 INJ. 1
1001
80.
60.
40.
20.
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A7.16




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-------
Ti2a:T980155  41-396 Acq:6-J3UT-98 17:37:38 Eli- Voltage  SIS  701 Hoiae:30492
373.8208 Ti3  BSUB(256, 30, -3. 0)  PXD(7,S,3, 0. 05\,121968.0,1.00\,rrT) Exp:HDB5US
TRIANGLE LASS  Text:TLI#44376 113-116                       OKI. TIME  -    17:40
 1003
  80:
  20:
   0:
         A3.
      A9.24X
               X8
                                   A1.32X8
                                        6.87X7
                  A2.37E7
      A3.45X7
A2.07X7  A
        32:00                          33:00
rile:T9801S5 #1-396 Acq:6-JAJT-98  17:37:38 EH- Voltage SIS 70
375.8178 T:3 BSUB(256,30,-3.0) fXD(7,5,3,0.05\,93448.0e1.00\l
TSIANSLE LASS  Text:TLI#44376 113-116
1001     A1.88E8
 ao:
  40
  20:
     A7.36E'.
                   Al.S9E7
                                                      A2.73E7
                                                Al. 65E7 A.
                                                                     34:00
                                                               Xoiaet23362
                                                              T,T) Xxp:SDB5US
                                                                  TIMX -   17«40
        32:00                          33:00                         34:00
Tile:T98015S tl-396 Acqi 6-JAS-98  17:37:38 EI+ Voltage SIS 70T Noina:1990
383.8639 F:3 BSUS(256,30, -3. 0) PXD(7,S,3, 0. 05%, 7960. 0,1.00\,r,T) Exp:NDB5aS
TRIANGLE LASS  Text:TLI»44376 113-116                       XKT. TIME »   17:40
lOOi
  aoj
  50:
  40:
  aoj
  oj
                                      A7.86E6
                                         A
                                       L_L
                                                      A7.67E6
                                                                             A6.55E6
        32:00                          33:00                 |        34:00
rile:T980155 #1-396 Acq:S-JAN-98  17:37:38 EH- Voltage SIS 70T Noise: 1568
385.8610 F:3 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05%, 5272. 0,1.00%,
TRIANGLE LABS
1001
 80.
 60.
 40:
 2ol
  0:
               T&zt:TLI#44376 113-116
                                                                  Exp:NDB5US
                                                              KT.  TIME '   17:40
                                      A1.54E7
                                                     A1.47E7
        32:00                         33:00
File:T980155 #1-396 Acq: 6-JAK-98  17:37:38  EI+ Voltage SIS 70
392.9760 F:3 Exp-.NDBSOS
TSIANGLE LABS  Text:TLI#44376 113-116
1003
 ao:
 «o:
 40:
 30:
  o:
             32:10
                      32:28
                                     32:58  33:10
                                                         33:33
             TTJ.  TIME "
               33:48
        32:00                         33:00
rile:T9801S5 #1-396 Ac
-------
\fiJ.e:T9atH.55  #1-396 Acq:6-JAU-98 17s37:JS Sir Voltage SIS JOT N6J.ae:2510
389.3156  F:3  BSUB(256, 30, -3. 0) PXD(7,S, 3, 0.05%, 10040.0,1.00\,f,T) EzptSDBSUS
TSIANSLX  LABS  Text :TLI #44376 113-116                        J2KT. nxff -   17:40
1001                    A5.58E7
  80.

  50.

  40.

  20.
                                  A3.53X7
       A2.25E7
        ~r
                                          AJ.65E6
                                                            .[6.19E6
                                                  ~T
       32i24   32:36   32:48   33': 00   33:12   33:24   33:3$
rile:T98015S  #1-396 Aoj:6-JAK-98 17:37:38  XI* Voltage SIR
391.8127  F:3  BSUB(256,30,-3.0) PKO(7,5,3, 0. 05\,10724 . 0,1.01
TRIANGLE  LASS  Teit:TLI#44376 113-116
lOOi,                     A4.58E7
  80.
  SO.

  40.

  20.

   OJ
                                  A2.89E7
       A1.S6E7
                                                                         A9.43E6
                                                                  "T
                                                                33:48    34:00
                                                             OT fo±aes2681
                                                                  )  X3CptSDB5US
                                                              ISf.  TIKE -   17:40
                                                                                 34:12   34:24
                                         A2.97E6
                                                               .33E6
                                                                        A7.71E6
       32:24    32:36   32:48   33:00    33:12   33:24   33:3S   \33:48   34:00    34:12   34:24
Tile:T980155  #1-396 Acq:6-J7Ut-98 17:37:38  EI+  Voltage SIR 7,OT Boise: 1575
401.8558 T:3  BSUB(256,30, -3. 0) PXI>(7, 5,3, 0.051,6300.0,1.00*,?, T)  Exp:lO3S5US
TRIANGLE LASS  T&xt:TLI#44376 113-116                      !  TJK7.  TIME -   17:40
1001


  80.


  60.


  40.

  20.
                                                        A8.50E6
                                                                         A1.17E7
       32:24    32:36   32:48   33:00    33:12   33:24   33:36   \33:48   34:00    34:12   34:24
rile:T980155  tl-396 Acq: 6-JAN-98 17:37:38 EH-  Voltage SIS HOT Soise:911
403.8529 T:3  BSOBf 256 ,30,-3 . 0 ) PKD(7, 5, 3, 0. 05\, 3644 . 0,1. 00*,r, T)  Exp:NDB5US
TRIANGLE LABS  Tejct:TLH44376 113-116                      |  IHJT.  TIME -    17:40
1003

  80.

  eo:

  40.

  20.
                                                            I
                                                       A7.26E6
                                                                        Al.02E7
      32:24    32:36   32:48   33:00   33:12   33:24   33:3
rile:T9801SS #1-396 Acq:6-JAK-98 17:37:38 EH- Voltage SIR  7\OT
392.9760 T:3 Exp-.NDBSOS
TRIANGLE LABS  Text:TLI#44376 113-116
lOOi

 80.

 60.

 40.

 20.

  0.
         32:28
32:5032:58   33^10
                                                       33:35\
      32:24    32:36   32:48   33:00   33:12   33:24   33:3
                                                                33:48   34:00    34:12   34:24
                                                              rw.
                                                                '. TIME  -
                                                                13:48
                                                                            17:40
                                                                                34ill 34:20
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-------
rile:T980155 #1-563 ACIJ : 6 -JAN- 9 8 17:37:38 Eli- Voltage
SIS 70T Ooiaa:1452

407.7818 T:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,5808. 0,1 .00\,T,T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 113-116
1001
aol
601
401
201
o:
A2.44E7
A
A

/ .
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1 \ X*\ ^
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35.-00 ' '36ii2 ' '36:24 ' 36:36 36:48 37:oV
rile:T980155 #1-563 Acqs6-JAN-98 17:37:38 EH- Voltage
UKT. TIME - 17:40





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37:12' ' '3'7:24' ' '3'7:35'
SIS 70T Noiae:1285
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37:48 38:00 38:12 lime

409.7789 r:4 BSU3(256,30, -3.0) PXD(7,5,3, 0. 05\,5140. 0,1. 00\,r, T) Exp:XDBSVS
TRIANGLE LABS Text:TLI#44376 113-116
1003.
aol
601
40.
201
'
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A2.36E7
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36\00 ' '36si2 36:24 35:35 351-48 37:00
File:T9a0155 #1-563 Acq:6-JAN-98 17:37:38 EI+ Voltage
417.8253 F:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 051,2372. 0,
TRIANGLE LABS Text:TLI#44376 113-116
1001
80:
60:
40:
201
ol
A4.87E6
A
A

-
/ I
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36:00 36:12 35:24 361-35 35:48 37-00
File:T9S0155 #1-563 Acq:6-JAN-98 17:37:38 EH- Voltage
419.8220 T:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,2696. 0,
TRIANGLE LABS Text:TLI#44376 113-116
1001
aol
sol
401
20:
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U..I3I,
A

'
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35:00' ' 351-12 35^24 ' 35:35 351-48 371-00
File:T980155 #1-563 Acq:6-JAN-98 17:37:38 EI+ Voltage
430.9729 F:4 Exp-.NDBSUS
TRIANGLE LABS Text:TLI#44376 113-116
1001
aol
60:
40:
20:
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36,12 3W 36iS036.-5a J7,
*>-^^^*^h-'*-^'^ ^w-^^^s.^™^11^— ^^^«- v^^-'^N*^N^"*— *"^^™*\^>^*1'





351-00 35:12 35.-24 35.-3S 351-48 371-00
Tile:T980155 #1-563 Acq:6-JAN-98 17:37:38 EI+ Voltage
479.7165 F:4 Exp : NDBSUS
TRIANGLE LABS Text:TLI#44376 113-116
1001
ao:
60:
40:
20:
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35:15
A


\
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36:00 35:12 35«24 351-35 35:48 37:00
DKT. TIME ' 17:40





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37:12 37:24 '371-35
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JKJ. TIKE - 17:40


A3.63E6
A
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'37:12 ' '37\24 ' ' 37\36
SIR 70T Noiae:674
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INJ-. TIME - 17:40


A 8. 32E6
A
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371-12 ' 37.-24 371-35
SIR 70 T

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06 37:2037:28 37:
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-------
file:f9Bai55 tl-5&3 Acq:S-JM-Sa 17:17:38 ES+ Voltage SIR 70V Noiae: 433 	 :
423.7766 T:4 BSO3(256,30, -3 .0) PXO(7,5,3, 0. 05\,1692.0,1.00\,T,T) SxptSDBSUS
TRIANGLE LASS Text:TLIt44376 113-116 UKT. TIME - 17:40
10 OS
80.
60.
40.
20.
0_
A6.54E6
A
\ A5.67E6
\ A

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35:12 36:ia 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:05 37:12 371-18 37:24 37:30 37:35
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rile:W80155 #1-553 Acq:6-JKS-98 17:37:38 EI+ Voltage SIS 70T Soiaes242
425.7737 F:4 BSVB(256,30,-3.0) PKD(7,5,3, 0.051,968.0,1. 00\,T,T) Exp-.HDBSVS
TRIANGLE LABS Text:TLIt44376 113-115 JW7. TUtE - 17:40
1001

80.
50.
40.
20.
0.
A6.32E6 •
/ \ A5.54S6

\ \
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351-12 36':18 35:24 351-30 351-35 351-42 3S.-4S 351-54 371-00 37:05 37:12 37:18 371-24 371-30 37.-35
1 . 6E6

'.1.2E6
.9.3E5
.6.2E5
.3 . 1E5
O.OEO
Time
Tile:T980155 #1-563 A c
-------
ri-Le:T980155 tl-563 Acq:6-JAH-9& 19:37:38 EX+ Voltage SIX 701 Hoiae:20B
441.7428 T:4 BSUB(256, 30, -3. 0) tKD(7,5r 3, 0.05\,832. 0,1. 00\,r,T) StpilWBSaS
TRIANGLE LABS Tejct:TLIf 44376 113-116 UKT. TIMS - 17s40
100]
90.
801
70-.
60.
SOI
401
301
201
101
ol
A1.48E6








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-2.8ES
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Li.^r^l
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ll.lES
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36\00 J7:00 38\00 39:00 40:00 41:00 42\00 Tiae
rile:T980155 fl-563 Acq : 6 -JAN- 9 8 17:37:38 EH- Voltage SIX 70T Xoiae:230
443.7399 T:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0.05\,920 .0,1.00*,r,T) XxpsNDBSUS
TRIANGLE LABS Text:TLI*44376 113-116 IJKT. TIME " 17:40
100*
901
801
70.
sol
SOI
40.
301
201
101
Ol
A1.75E6


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rile:T980155 fl-563 Acq : 6 -JAJT- 9 8 17:37:38 EH- Voltage SIX 70T
430.9729 f:4 Erp:NDB5OS
TRIANGLE LABS Text:TLI»44376 113-116 ZK7V TIME - J7.-40
100*
901
801
701
601
501
401
301
201
101
01
35:20 te ** 36:40 37:28 38:37 39:07 39:40 40:39 41:17 41-53
_. A/U^ 35:55 A»i., «_A* A « JVL tfV. irfV^vM^^AAA^AATAVAiA^^AA/V »JLA .UJU>^. A/V..^
,^/vvvVNv^%^AV^9 1
33,23 38,42 II 39 4i
36:34 l\\
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36'tOO 37\00 38\00 39:00 ' 40s 00 41; 00 42\00
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.4.7X3
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.3.4X3

12.7X3
.2.0X3
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.6.8X2
0.0X0
Time
168

-------
         40:54   ,     41': 00          41:06         41:12         41:18         41':24
rile:T9B01SS  »l-563 Acq:6-JAN-98 17:37:38 EH-  Voltage SIS 70T Soiae:66
469.7779 F:4  BSUB(256, 30, -3 . 0) PJOJf 7, 5, 3, 0. 051,264 . 0, 1. 00\,F, T) Exp:NDB5US
TRIANGLE LABS  Text:TLI»44376 113-116                        XK7. TIME -   17:40
FiJ.a:T980155  tl-563 Acq:6-JAN-9B 17:J7:Ja SZ-f voltage 313 70T Noiae:aj
457.7377 T:4  BSUB(256,30, -3. 0)  PKD(7,5,3, 9.051,332. 0,1.00\,r,T) Xzp:RDB5US
TSIAXSLE LABS  Text:TLIt44376 113-116                        HKT. TIME -   17>40
1004          A1.39E6
  80.

  60.

  40.

  20.
                                                                              41:24
         40:54        41:00       .   41:06         41:12         41:18
rila:T980155  tl-563 Acq: 6-JZN-98 17:37:38 SI+  Voltage SIS 701 Koiae: 62
459.7348 T:4  BSUB(256,30, -3. 0)  PJO3(7,5,3, 0.05%,248.0,1.00\,r,T) ExpiRDBSOS
TRIANGLE LABS  Text:TLI#44376 113-116                        IXT. TIHE -   17:40
1001            A2.J6E6
1003
 80J
 69-
 20.
              Al.
                                                                              41:24
         40:54        41:00          41:06         41:12         41:18
rile:T980155  tl-563 Acq: S-JTUT-98 17:37:38 EI+  Voltage SIB 70T Noise: 64
471.7750 F:4  BSUB(256,30, -3. 0)  PKD(7,5,3, 0.051,256.0,1.00\,f,T) Exp:NDBSUS ,
TRIANGLE LABS  Tejct:TLI#44376 113-116                        XKJ.  TIME -   17:40
1004
         40:54        41:00         41:06         41>12        41:18         41:24
rlle:T980155  tl-563 Acq:6-J7Uf-98 17:37,38 EX+  Voltage SIX 70T
430.9729 T:4  ExpsSDBSVS
TRIANGLE LABS  Text:TLI#44376 113-116                        HIT.  TIKE -   17:40
                                                                                                   3.6ES

                                                                                                  .2.9E5

                                                                                                  .2.2E5

                                                                                                  .1.5E5

                                                                                                  '.7.3E4
                                                                                             41:30
                                                                                                  Lo.oro
                                                                                                      Tiae
                                                                                                 ..4.6E5

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                                                                                                  .2.8E5

                                                                                                 _1. 8E5

                                                                                                 '.9. 2E4
                                                                                                  '.O.OEO
                                                                                            41:30    Tiae
                                                                                                  2.1E6

                                                                                                  '.1. 7E6

                                                                                                  11.3E6

                                                                                                  L8.5£5

                                                                                                  14.2ES
                                                                                                 f n  nvn
                                                                                            41:30     Time
                                                                                                 -2.4E6

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                                                                                            41:30
                                                                                                      168

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                        fl:
          I   ;<8,3732     Peak top
Height  3,59 alts  Span   298 ppa

Systea f iis  nae
Data   file  name
Resoiutlon
Groupnuaber
lonizoticn aode
Syitching
Ref, aasses   292,3825,
R   293   .   J   331
8   384      K   332
                               2
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D   318
E
F
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    329
G   322
H   328
I   331
L   334
R   348
H   342
0   352
P   354
Q   356
R   358
                         S  368
                         T  378
                         II  376
                         V  418
Ref, iass "  416,9768    Peak top
Height   ,36. wits  Span   298 ppa
                                                                170

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file:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI + Voltage SIR 70T
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^K^^l^»^^^^»^#^^^^»i]
TLI Project: 44376 „ . Method 23 TCDD/TCDF Analysis (DB -225)
Client Sample: 113-116 - L: - Analysis File: X9800$i
Client Project: Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-3A-3D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000 Dilution Factor: n/a
Dry Weight: n/a Blank File: X980083
GC Column: DB-225 Analyst KAS
Spike File: SPC2NF04
ICal: XF24087
ConCal: X980080
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

'Anafcte* ', , ; -/- ',/foi*. fr$) r ' * ' Ot ; , £Mf»C -vV ;^^ ^ 'Ral^' ; m ?teg*
2,3,7,8-TCDF
Internal Standard
I3C12-2,3,7,8-TCDF
Recovery Standard
13C12-1,2,3,4-TCDD
28.4
Ami (ng) % Recovery OC Limits
3.7 92.8 40%-130%
.

0.77 21:31 E_
Ratio- 8T Flags
0.80 21:30 	
Ratio ITT Flags
0.80 20:29 	
                         Data Reviewer.
01/11/98
                                                Page 1 of 1
                CNFJ>SR »101. LARS «.10.oS
Triangle laboratories, lnc.9
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 13:34 01/11/98
                   1S2

-------
                                  . . ..Date...
  Data Review By:
                                              Calculated Noise Area:   2.00
^
M
  he Toeal Area for each peak with an ion abundance ratio outside
  atio limits has baeo recalculated according to method requirements.
  Page No.
  01/11/98
                        Listing at X980086B.dbf
                        Hatched CC Peaks  / Racio
                                                 /  Ret. Time
  Compound/
  M_2	QC.Log emit Why . .RT. OX Ratio Total. Area. .. Area.Peak.1.. Area. Peak. 2. . Rel.RT Compound. Name.
                                                                                                   ID..  Flags.
TCDP
0
304-306 DC NL 0:00 RO
17
17
18:
18:
18:
18
18
18:
19:
19:
'. 19:
1 19:
19:
20:
20:
20:
, 20:
• 21:
21:
21:
21:
21:
22:
22:
23:
:07
:4S RO
:06
:14
:22
:32
:48
;56
;05
ill
:15
25
46
11
27
38
51
01
24
31
43
56
03
43
20
304-306 25 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL ' 17:
DC WL 17:
DC WL 18:
DC WL 19:
DC WL 19:
DC WL 19:
DC WL 20:
DC WL 20:
21:
21:
22:
22:
22:
0.
00
15 RO
44 RO
49
14 RO
45
58 RO
11
25
30
41
03 RO
16 RO
23 RO
.65-0.89
3.31
0.77
0.35
0.75
0.76
0.77
0.76
0.77
0.77
0.76
0.78
0.78
0.77
0.77
0.78
0.78
0.78
0.77
0.77
0.76
0.77
0.75
0.76
0.74
0.75
0.65
5
65-0.89
0.87
0.63
0.60
0.85
1.04
0.71
0.98
0.79
0.71
0.80
0.73
1.41
0.35
0.62
0.790-1.095
574
116,025
2,494
161,420
129.175
249,431
129,230
110,073
240,976
120,913
125,140
312,161
148,805
700.501
239,059
228,416
207,795
35,661.
298,266.
286,423.
213,794.
272,057.
334,338.
309,011.
192,220.
34,072.
,202,512.
.90
.40
.02
.90
.10
.00
.30
.20
.00
.50
.90
.00
.30
.00
.00
.70
.60
.20
.00
.00
.00
,00
,00
,00
,50
,30
,42

50,
1,
69,
55,
108,
55,
47,
105,
52,
54,
136.
64,
305,
104,
99,
90,
15,
129,
123,
95,
117,
144,
131,
82,
13,


642
084
328
879
351
900
989
194
364
653
615
840
391
430
850
313
535
730
326,
023,
013.
169,
867,
635,
463.


.20
.97
.50
.00
.00
.30
.90
.00
.50
.30
.00
.90
.00
.00
.70
.60
.50
.00
.00
.00
.00
,00
,00
.50
.30



65,383.20
3,108.52
92,
73,
141,
73,
62,
135,
68,
70,
175,
83,
395,
134,
128,
116,
20,
168,
162,
123,
155,
190,
177,
109,
20,

092.40
296.10
130.00
330.00
083.30
782.00
549.00
487.10
546.00
964.40
110.00
529.00
566.00
982.00
125.70
536.00
597.00
771.00
044.00
169.00
144.00
585.00
604.00

0.000
0.796
0.826
0.842
0.848
0.854
0.862
0 . 874
0.381
0.388
0.392
0.395
0.903
0.919
0.939
0.951
0.960
0.970
0.978
0.995
1.001 2378-TCDP AN
1.010
1.020
1.026
1.057
1.085




B

S


X


E

S
E
E
E

' E
Z
S
S
S
E
3


0.953-1.047
46.
95.
23.
104.
215.
59.
139.
535.
601.
31,912.
117.
88.
37.
54.
.24
19
98
29
.23
04
44
38
12
10
24
46
40
02


















14,224.




49.
70.
16.
23.









70
40
27
27
50














•



17,687.40




67.34
49.98
47.12
38.16
0.000
0.302
0.325
0.875
0.895
0.919
0.929
0.939
0.950
1.000 13C12-2378-TCDP ISO
1.009
1.026
1.036
1.041














Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                          Printed: 13:19 01/11/98
                                                                                                    1S3

-------
  Page  HO.     2           Listing of X980086B.db£
  01/11/98                 Matched GC Peaks / Ratio / Rat.  Tim*

  Compound/
  M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Nam*..  ID.. Flags.

                 DC  WH  23:17 RO  0.97        164.47                             1.083
                 DC  WH  23:45 RO  2.58         81.84                             1.105
  316-318               5 Peaks              32,209.22
                                        Above:  TCDF / TCDD Follows
  13C12-TCDD                     0.65-0.39                                     0.901-1.099
  332-334         DC  NL
0:00 RO 1.55
19:08 RO 0.97
20:13 0.78
20:29 0.80
21:10 0.73
22:40 RO 0.16
46.76
112.98
23.545.00
24,697.60
308.78
33.61

61 . 88
10,341.30
11,005.90
130.24

0.000
63.83 0.946
13,203.20 1.000
13,691.70 1.013
178.54 1.047
1 . 121
                                                                                        13C12-2378-TCDD  131
                                                                                    013  13C12-1234-TCDD  RSI
                 DC  WH
  332-334               4 Peaks              48,664.36
  Column Description	   'Why*  Code  Description	  QC Log Desc.
 M_3   -Nominal Ion Hass(es)      WL-Below Retention Time Window   A-Peak Added
  ..RT. -Retention Time (mm:33)    WH-Above Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below Signal  to Noise Level   D-Peak Deleted
 OK    -RO=Ratio Outside Limits  
-------
Pil»:I9BOOaS H1-3B3 Acyt  V-jAB-iSSB 1D-01,1B OC M* Volttgt SIX Autosptc Holm*,613994
303.9016 SSUB(256t30,-3.0) PXD(5,3,l,0.10*,2475936.0,0.00*tP,r) XxptKOSPJTT
3»apl* T*xt:TLI044376 113-116 P±l» T«JTt»  TRIAKOU XJLB3
 80.
 40.
 70.
                               A1.37B9
                    A1.08B9
                                                       A1.30E9     A1.44S9
                                                            A1.24B9
                                               JL3.99EB
                                                                              A8.26B8
                                                                                      A1.35B8
                                                                                        /V
  17<00         1S>00        19tOO        20,00         41*00        27tOO
Pil*:X980086 #1-883 Aeg> 7-J1S-1998  19s01s48 OC XX+ Volttga SIR AutoSpuc Noiao,162401
305.8987 BSUB(2S6,30,-3.0) PSD(5,3,1,0.10*, 649604.0,0.00\,?,P) S*p:XCOSP_tr
5aapl« T*Xt:TLI*44376 113-116  ttl» Ttort:  TRIANGLE LAB3
J0«                                  A3.95S9
  17:00         13': 00        19:00        20:00         21:00        22:00        23:00
Pll»:X9aOOB6 tl-883 Acy: 7-JAS-1998  19,01,48 OC ST* Voltug* SIR Auto3p»c Soia«tl0746
315.9419 BSUB(256,30,-3.0) PXD(5, 3, 1, 0.10*, 42984.0, 0. OOX,P,P)  SxptKONP_TT
       T»3Ct>TLI#44376 113-116 Pile Toxti  TRIANOLB LASS
10(3

 80.

 60.

 40.

 20.
  17:00         18:00        19,00        20:00         21:00        22:00        23:00
Pll»tX980086 #1-883 Acq: 7-JAN-1998  19:01:48  OC  BI+  Valtago SIR AutoSpac Hoiao:1237S
317.9389 BSUB(256,30,-3.0) PXD(S,3, 1, 0.10%, 49500.0, 0. 00\,P,f)  SxpsXCOSP_TT
Saapl» T*xt:TLI#44376 113-116 Pil» T
-------
flla
319.
Samp
iocs
80.
60^
40.
20.
0
Pila
321.
-gjttfrr
1009
80.
60.
40.
20:
0
Plla
327.
Soap
100*
80.
60.
40.
20:
0'
Pile
331.
Soap
iooa
80.
60.
40.
20.
0
Pila
333.
3aap
10(K
80.
60.
40.
20.
0
8965 B3UB(256,30,-3.0) PXD(5,3,1. 0.10*. 44492.0, 0. OOt.P.P) Sgp t XCOSP_TT
If Taxt:TU944376 113-116 Pila Tmjtfi TRXASQLB LABS
1
A5.17S8
\ \ 1
I
A2.66E8 A4.9SS8
1 1 H A3. 10S6 ,. aci,a t*\
II 11 Ml /A — .
10:00 15>00 20:00 21:00 22:00 23\00
1X980086 91-883 Acqt 7-JAB-1998 19:01:48 OC SI* Voltage SIX AutoSpac SOimm:24010
8936 BSUB(2S6f30, -3.0) PKD(S,3,1.Q.10*,96040.0,0.00\,P,P) Bxp t XCC3KP_TT
If Taxt:TLI944376 113-116 Pila Taxt: TXIABOLB LABS
J-
A6. 65S8
1

A3.44B8 A6.3SS8
1 1 AA2 68SS /S
(1 n T\ A2.38B8 l\ . .
11 f\hT\ A, /A — .. .
18:00 15<00 Zo'tOO 2l':00 22\00 23\00
1X980086 91-883 Aeq: 7-JJLN-199B 19 1 01: 48 OC EH- Voltagt SIR JLutoSpec Solf»:20929
8847 BSUB{256>30,-3.0) PKD(S, 3, 1, 0.10%, 83716. 0, 0. 00*,P,P) Exp:XCONF_TT
la Taxt:TLI#44376 113-116 Pilf Taxt, TRIANQLE LABS
A2.BSE8
A2.22EB 1
A

A1.26E8
"•r i
. .' l\ "-x* , AlUl A
18:00 15:00 So'iOO 21:00 22:00 23:00
1X980086 91-883 Acq: 7-JAN-1998 19:01:48 OC EH- Voltage SIS AutoSpec Soiaf:2048S
9368 BSVB(2S6,30,-3.0) PXD(S,3,1, 0.10%, 81940. 0, 0. OOt,P,P) Bxp:XCOSP TT
la Taxt:TLI944376 113-116 Plla Taxt: TRIAHQLS LABS
A1.10S8
A1.03E8 \
In


•
11
18:00 15:00 70:00 71:00 72:00 23:00
1X980086 91-883 Acq: 7-JAH-1998 19:01:48 OC SIf Voltaga SIX AutoSpac Soitat 13212
9338 BSVB(256,30,-3.0) PXD(5,3, 1. 0.10*,52848. 0, 0. 00*,P,P) SxptXCOUP TT
la TaxtiTLI944376 113-116 Pila Taxt: TRIASOLS LABS
A1.3&f?7S8



All
10:00 15:00 20:00 21<00 22:00 23:00
-2.1B8
.1 . 7E8
.1.250
.8.3E7
.4.2B7
O.OEO
Tima
2.7B8
.2.1E8
'.1.6EB
.1.1S8
.S.3E7
' O.OEO
Tima
6.6B7
.S.3E7
'.4.0E7
'.2.6E7
'.1.3E7
'.O.OEO
Tima
-2.9E7
-2.3E7
-1.8E7
-1.2E7
.5.8E6
O.OEO
Tima
-2.8B7
-2.1E7
-1.4B7
-7.1B6
O.OEO
Tima
186

-------
Pllo:I980086 01-883 Acq, 7-JAN-1998 19,01,48  OC SI*  Voltage SIR AutoSpec
303.9016 SxptXCOHF_TT
Saaple Text,TLI044376 113-116 Pile Text:  TRIANOLS LASS
10031                                   19146

 80:

 60:
40:
20:
 o:
      A
                                                                              ""
                                                                                      .«.
  17:00  '  """    18:00  r '     15:00        20/00        21/00        22/00
Flle,X980086 01-883 Acq, 7-JAN-1998 19,01,48 OC SI* Voltage SIS AutoSpec
315.9419 Sxp,XCOHF_TT
Staple Teate,TLI044376 113-116 file Text: TSIAKOLS LABS
                                                                                  23sOO
1003

  80:

  60:

  40:

  20:
                                                              21t30
  17:00         18/00         15/00        20:00        21:00        22:00
Flle,X980086 01-883 Acq: 7-JAK-1998 15:01/48 OC SI* Voltago SIR AutoSpec
319.8965 S3CpiXCONP_TT
Saaple TexttTLI044376 113-116 Pile Text, TRIAKOLS LASS
100*           17;57
                      18:30
                                                                                  23»o
 ao:
                               15:10
                                                 20:30
  17:00         18:00         15:00        20:00        21:00        22:00
Plle:X9S0086 01-883 Acq: 7-JAN-1998 19:01:48 OC  SI*  Voltage SIR AutoSpec
331.9368 5jrp:XCOMF_rr
Saaple Text:TLI044376 113-116 Pile Text,  TRIANOLS LABS
lOOt

 80:

 60:

 40:

 so:

  o:
                                                                               -F*f
                                                                                  3300
  17:00         18:00         15:00        20:00        21:00        22:00
Wl«:X5800Sff #1-883 Acq, 7-JAN-1998 15:01/48 OC SI* Voltage SIR AutoSpec
252.5825 Bxp, XCONP_TT
Saaple Text,TLI044376 113-116 File Text: TRIAHOLS LASS
100H      17:33 18.-00  lfl:31   15:05          __	2fli5jLZU22__ 33:0033^35
    •         ^->T—	y	~                     V
 80:                        V

 60:

 40.

 20:

  oj	
                                                                                  23«00
                                                                                  33:01
                                          30': 00        21/00        22/00
File, 1980086 01-883 Acq, 7-001-1998 19,01,48 OC SI* Voltage SIR AutoSpec
330.9792 SxpiXCOSF TT
Saaple Text,TLI044376 113-116 File Text, TRIANOLS LABS
10031
 so:
 60:
 40:
 20:
  o.
               17/55
                         18,41
                                               20,23  20J542H18

                                                                       22,12
                                                                                 23:00
                                                                                  23,01 23,31
  17': 00
                             15<00
                                                       21iOO
                                                                    22<00
                                                                                 23:00
                                                                                               ,.4.758
                                                                                               f
                                                                                               1.3.858

                                                                                               •.2.858

                                                                                               Ll.558
                                                                                               t
                                                                                               f.9.5B7
                                                                                                0.050
                                                                                                   Tlae
                                                                                                3.457

                                                                                               1.2.757

                                                                                               12.057

                                                                                               ^.1.357

                                                                                               L*. 75*

                                                                                                0.050
                                                                                                2.158

                                                                                               Ll.758

                                                                                               Ll.258

                                                                                               18.357

                                                                                               14.257
                                                                                                0.050
                                                                                                   Tlae]
                                                                                                2.557

                                                                                               L2.457

                                                                                               .1.857

                                                                                               .1.257

                                                                                               -5.9B6
                                                                                                0.050
                                                                                                   Tlmei
                                                                                             -6.4B8

                                                                                             \-5.1S8
                                                                                             t
                                                                                             13.558

                                                                                             .2. tfSS

                                                                                             .1.358
                                                                                               0.050
                                                                                                 TlMO\
                                                                                               ^7.158

                                                                                               .5. 758

                                                                                               .4.358

                                                                                               .2.858

                                                                                               .1.458
                                                                                                0.050
                                                                                                   Tlam\
                                                                                              1S7

-------
Peak Locate Examination: 7-JAN-1998:19:00 File:X980086
     Experiment:XCONF_TT Function:! Reference:PFK
00
CO

-------

TLI Project:     44376
Client Sample:   121-124/219   -
T
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   T980157
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-5A-D/ Date Extracted: 12/29/97
Date Analyzed: 01/06/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3.4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
^,3,4,7,8-HxCDF
P-,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF :
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3.4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (ng) DL EMPC
2.5
14.3
17.0
31.2
55.3
98.8
79.8
EMPC *33- ?-<
EMPC &?T§ ?zo
EMPC 9*§- 7 Zo
V*2* :> 2 o
7&2- 72,0
107 -72. 0
7.2

39.9
52.4
1 A>
AmL {ng) Number DL EMPC
3-39 ^ 12
YKT 770 8 3S2 72-0
452 '20 7
Ifc*96 '^^ 2
356- "-^ 8 K*T ^^
50^ 72° 6 ttW ^s^
6tt 7^6 12 £&& 7so
239- > 2
-------
TLI Project:      44376
Client Sample:.  121-124/219
                                                Method 23 PCDD/PCDF Analysis (a)
                                                             Analysis File:   T980153^
Internal Standards
13C,2-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13Ci:-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
I3C,2-l,2,3,6,7,8-HxCDD
I3C,2-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
I3C,2-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL.-2,3,7,8-TCDD
13C,2-u]3X7,8-HxCDF
l3Ci:-l,2,3,4,7,8-HxCDD
13Cp-l,2,3,4,7,8,9-HpCDF

Alternate Standards (Type A)
13Ci2-l,2,3,7,8,9-HxCDF
13C,:-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
l3C,2-l,2,3,7,8,9-HxCDD
Amt (ng)
1.8
2.5
2.7
3.5
2.9
2.8
3.0
4.5
9.5
Amt. (ng)
3.9
4.1
3.4
5.2
5.1

Amt. (ng)
3.4
2.9


% Recovery
45.0
62.2
67.0
86.7
71.9
69.3
74.2
112
119
% Recovery
96.3
103
84.2
129
127

% Recovery
85.3
71.4


OC Limits
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
25%- 130%
25%- 130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%

QC Limits
40%- 130%
40%- 130%


Ratio
0.86
0.79
1.51
1.48
0.56
1.15
0.48
1.05
0.90
Ratio
1.47
0.59
1.15
0.46

Ratio
0.51
0.57
Ratio
0.80
1.17
RT
25:43
26:21
29:31
30:31
33:00
33:42
36:00
37:05
40:55
RT
26:22
30:12
32:54
33:37
37:37

RT
34:18
33:30
RT
26:10
34:01
Flags
Q_
. —
Flags
oH
Q_

Flags f
—
Flags
—
                     Data Reviewer.
                                                            01/15/98
                                        Page 2 of 2
                                                                         X337.PSR viOl. LARS 4I0.08O
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                      Printed: 09:27 01/15/98
                                                                            is c

-------
                        Initial
                                    ..Date..
  Dae a Review By.
          {
                                              Calculated Noise Area:
  I
  The Total Area for each peak with an ion abundance ratio outside
  •atio limits has been recalculated according to method requirements.
                                                                     2.00
  Page No.
  01/15/98
Listing  of T980157B.dbf
Matched  GC Peaks / Ratio /  Ret. Time
 Compound/
 M_2.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2. .  Rel.Rt Compound.Name.. ID.. Flags.
TCDP
304-306















304-306
13C12-TCDF
^16-318
*
















316-318
TCDD
320-322


DC NL


1




1 '.



1



15

DC NL
DC WL
DC WL
DC WL
DC WL'
DC WL
DC WL
DC WL
DC WL







DC WH
7

DC NL

0
0:00 RO
.22:40
23:.09
23:22 RO
24:24 RO
24:53 RO
25: 13 RO
25:32
25:43 RO
26:06 RO
26:18 RO
26:33
26:50
27:01
27:22
27:35
Peaks
0.
0 .: 00 RO
22:40 RO
23:09 RO
23:22 RO
23:32 RO
23:45 RO
24:05 RO
24:26 RO
24:42 RO
24:55 RO
25:03 RO
25:17 RO
25:31 RO
25:43
26:07 RO
26:13 RO
27:.43 RO
Peaks
0.
0:00 RO
23:56
.65-0.39
3.18
0.89
0.38
0.90
0.96
0.52
0.93
0.89.
0. 96
0.95
0.91
0.80
0.39
0.30
0. 30
0.31

65-0.39
2.29
1.83
3.09
2.29
1.40
2.74
1.62
1.46
2.52
2.54
2.07
1.68
1.27
0.36
2.32
1.22
1.08
0.878-1.073

64
62
63
128
89
60
82
33
62
65
17

1
9
1
793
4.92
,446.00
,432.60
,674.33
,050.83
,158.58
.397.20
,371.60
,948.45
,754.47
,217.24
,205.51
302.39
,396.99
, 510.50
,432.01
,799.30

30,343
29,149
32,328
69,425
38,786
31,838
39,0.74
45,455
33,589
33,403
7,634
142
340
4,237
639


.60
.20
.20
.00
.50
.30
.20
.60
.40
.80
.63
.42
.75
.30
.40


34
33
35
72
75
34
43
. 47
35
36
9

1
5



,102.40
,283.40
,974.20
,345.10
,119.40
,405.20
,797.40
,428.50
.454.50
,845.90
,570.88
160.47
,056.24
,273 .30
792.61

0.000
0.381
0.900
0.909
0.949
0'.?68 - . '
0.984
. 0.993 • . ' . .
1.000 2378-TCDF AN
1.015
1.023
1.032
1.043
1.051
1.064
1.073


QSE
QSE
QSE
.QSE
QSE
QSE
QSE.
SE
QSE
QSE
QE
Q
Q
QE
Q

0.961-1.039













1



2
65-0.89
1.18
0.89

64
10.48
39.91
40.34
35.22
65.36
140.41
162.45
132.29
89.79
116.17
116.53
67.91
126.34
,362.09
56.53
135.79
18.12
,481.46
TCDF / TC

13.13
,933.80









166
136
64
90
362
.74
93










.70
.62
.30
.73
.57
.25
.23



























65.63
65.89
38.37
71.38
999.52
31.94
76. 12

0.000
0.381
0.900
0.909
0.915
0.924
0.936
0.950
0.960
0.969
0.977
0.983
0.992
1.000 13C12-2373-TCDF ISO
1.016
1.023
1.078













Q



*T}O Prtl 1 fM*/e


30 , 653 .

,60

34,
0.903-1.045

280.20
0.000
0.908

SE
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 09:27 01/15/98
                                                                        191

-------
  Page No.
  01/15/98
Listing of T980157B.dbf
Matched GC Peaks /  Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log OmiC Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.





M
AN




320-322
37C1-TCDD
328













328
13C12-TCDD
332-334













332-334
PeCDF
340-342

24
24
25
25
25
26
26
26
26
26
27
:13 .
:35
:14
:30
:52
:16 .
•22
:32
:41.
:53
:20
0.30
0.77
0.77
0.78
0.78
0.79
0.79
0.77
0.77
0.78
0.77
12 Peaks
47,501
17,252
38,260
25,113
13,685
35,000
1,761
4.390
3,526
1,293
1,365
254,583
.70
.01
.00
.80
.36
.00
.00
.16
.33
.12
.92
.70
21,073
7,523
16,663
10,990
6,017
15,500
779
2,125
1,536
568
595

.60
.17
.30
.20
.66
.00
.00
.31
.40
.04
.00

26,428
9,728
21,596
14,123
7,667
19,500
982
2,764
1,990
725
770

.10
.84
.20
.60
.70
.00
.00
.85
.43
.08
.92

0.922
0.933
0.958
0.968
0.982
0.997
1.001 2378-TCDD . AN
1.007
1.013
1.020
1.037

E
E
E
E
E
E






. 0.924-1.076
DC NL 0;
DC WL 23
DC WL 24
DC WL 24
24:
24:
24:
25:
25:
25:
25:
26:
26:
26:
:00
:56
:10
:17
:28
: 35
:59 -
14
30
41
52
22
31
44














10 Peaks

DC NL 0:
DC WL 24:
24:
DC SN 24:
24:
25:
25:
25:
26:
26:
26:
27:
27:
27:
0
00 RO
19
27
34
42
15 RO
34 RO
46 RO
10
21
40
08 RO
16 RO
33 RO
11 Peaks

DC NL 0:
27:
1.
00 RO
34 RO
.65-0.89
1.87
0.86
0.66
0.69
0. 88
0.42
0.99
1.52
0.30
0.79
0.65
1.97
0.. 34
0.94
1
422
712
447
32
102
7,429
214
133
43
73.
2,014.
41.
12,866.
22,952.
.48
.38
.60
.26
.72
.48
.21
.41
.85
.95
.58
.14
.13
.80
27




32
102
7,429
214
133
43
73 .
2,014,
41.
12,366.





.72
.48
.21
.41
.85
.95
.58
.14
.13
,80































0.000
0.908
0.917
0.922
0.929
0.933
0.943
0.953
0.963
0.975
0.932
1.001 37C1-TCDD SUR1
1.006
1.015
















0.924-1.076
5.
17.
12.
3.
13 .
15.
51.
20.
2,678.
2,073.
50.
8.
6.
8.
34
72 ' •
34
54
30
53
19
62
04
71
16
48
60
57


4.

6.
7.
28.
17.
1.194.
915.
19.
9.
2.
4.
4,944.54
32-1.78
0.77
1.10
3.
60,340.
77
53

36,981.


91

21
19
69
73
31
75
83
45
37
55



50


7.

7.
17.
23.
11.
1,483.
1,162.
30.
4.
8.
4.



43

09
20
92
65
73
96
33
79
36
34

0.000
0.923
0.923
0.932
0.937
0.958
0.970
0.973
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.012
1.030
1.035
1.046
















0.931-1.063

33,574.

30
0.000
0.934

OS]
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:27 01/15/98
                                                                                              1S2

-------
  Paqe No.

  01/15/98
Listing of T980157B.dbf
Hatched GC Peaks / Ratio /  Ret. Time
  Compound/         .        •
  M_2.... QC.Log Omit Why . .RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name..  ID..  Flags.


















340-342
13C12-PeCDF
352-354
















352-354
PeCDD
356-358








27
23
28
28
28
28
28
29
29
29
29
29
29
30
30
30
30.
31
:50
:01
:11
:18
:33
:41
:51
:10
:15
:26
:32
:40
:49
:13
:20
:39
:51
:08
RO



RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO



1.29
1.37
1.50
1.64
1.25
1,05
1.20
1.19
1.11
1.26
1.30
1.26
1.22
1.12
1.16
1.50
1.71
1.49
' 19 Peaks

DC NL 0
27
27
28
28:
t 28:
28
1 29:
29:
' ', 29:
29:
29:
30:
30:
' 30:
31:
31:

:00
:35
:44
:22
:33
:41
:51
:10
:15
:31
:40
43
:12
;21
46
:08
:25
1.
RO
RO
RO
RO

RO

RO
RO

RO
RO

RO

RO
RO
32-1.78
1.18
2.65
1.07
0.60
1.67
2.49
1.51
3.09
2.69
1.51
2.10
2.15
1.47
1.80
1.39
1.91
0.39
16 Peaks
__ ____ \K«

DC NL 0:
28:
29:
29:
29:
29:
30:
30:
30:

00
:47
14
29
36
47
02
14
22
1.
RO
RO

RO




RO
32-1.78
1.15
1.06
1.55
1.26
1.52
1.49
1.54
1.55
0.63
1,078
553
1,518
770
45,396
80,509
49,418
78,182
59,155
40,462
41,090
42,390
54,284
59,293
67,671-
14,588
871
12,456
711,033
.35
.91
.99
.10
.91
.42
.34
.34
.72
.74
.54
.51
.24
.75
.41
.02
.14
.17
.13




27
48
30
47
35
24
24
26
32
36
41
a

7

655.47
320.05
911.79
478.43
,594.20
,937.10
,038.60
,522.60
,957.40
,595.00
,976.60
,070.70
,996.30
,041.30
,133.60
,747.06
549. 54
,453.74

507.73
233.86
607.20
291.67
22,031.40
46,657.10
25,036.60
39.990.50
32,540.30
19,472.10
19,192.90
20,769.60
27,062.60
32,132.30
35,539.70
5,340.96
321.60
5,002.43

0.943
0.949
0.955
0.959
0.967
0.972
0.977
0.988
0.991
0.997
1.001 12378-PeCDF
1.005
1.010
1.024 23478-PeCDF
1.028
1.038
1.045
1.055

Q
Q
Q
Q
QSE
QSE
QSE
QSE
QSE
QSE
AN SE
QSE
QSE
AN QSE
QSE
Q
Q
Q

0.364-1.136
4
71
26
27
. 66
163
115
53
70
2.295
47
149,
2,347.
140.
13,
39.
15.
5,645.
. 71
.33
.93
.97
.33
.43
.14
.17
.56
.93
.33
.07
.72
.02
.60
.93
,99
50
? / Q..









1


1,





74.62
16.37
17.00
41.77
159.38
69.25
64.33
74.47
,381.31
38.91
125.32
,396.47
99.10
7.91
29.34
9.72

28.17
15.36
28.12
25.06
64.11
45.89
20.35
27.67
914.62
18.56
58.46
951.25
54.91
5.69
15.66
10.96
0.000
0.935
0.940
0.961
0.967
0.972
0 . 977
0.988
0.991
1.000 13C12-PeCDF 123
1 . 005
1.010
1.023 13C12-PeCDF 234
1.023
1.042
1.055
1.064









IS2 Q


SUR2 Q




LiT\r^ p>*»1 1 — . . —
V6 : PeCDt / rw.vu r U-LXUWS --
5.
53,890.
5,970.
42,323.
6,785.
35,507.
18,424.
15,174.
5,941.
26
55
75
53
95
10
99
91
04

32,
3,
25,
4,
21,
11,
9,
3,

757.00
624.36
726.10
095.69
251.90
158.90
212.68 .
611.22
0.939-1.022
•
30,909.70
2,345.89
20,378.10
2,690.26
14,255.20
7,266.09
5,962.23
5,738.32
0.000
0.943
0.958
0.966
0.970
0.976
0.984
0.991
0.995

SE

QSE
Q
E



Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 09:27 01/15/98
                                                                         1 Q^
                                                                         J. C o

-------
  Page  Ho.
  01/15/98
Listing of T980157B.dbf
Matched GC Peaks  / Ratio / Rat. Time
  Compound/
  M_Z.... QC.Log Omit Why . .RT. OK Ratio Total .Area. .. Area.Peak. 1.. Area. Peak. 2. .  Rel.RT Compound. Name. . ID..  Flags.



356-358
13C12-PeCDD
368-370
















368-370
30
30
30
:31
:38
:58



1.56
1.53
1.55
11 Peaks

DC NL 0
28
29
29
29
29
29
30
30
30
30
. 30
DC SN 30
30
31
31
31

:00
:47
:09
:15
:29
:41
:47
:03
:14
:20
:31
:38
:53
:53
:10
:25
:33
1
RO
RO


RO
RO
RO
RO





RO
RO
RO
RO
.32-1.78
0.27
1.85
1.63
1.36
2.08
2.21
1.36
1.94
1.58
1.39
1.48
1.43
1.44
1.25
.3.24
0.64
0.39
15 Peaks
7,610.11
5.623.71
6,185.57
203,438.26

1.65
92.34
17.98
18.32
46.28
. 8.03
29.76
48.91
32.34
25.04
1,648.36
• 167.64
'. 5-73
19.13
13.37
7.09
5.40
2,130.99

HxCDF
374-376

I



X




AX
M
AX
AN
M

374-376
13C12-HXCDF
384-386




DC NL 0:
31:
32:
32:
32:
32:
X 32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:

:00
57
07
14
23
32
44
56
02
08
19
26
32
15
13
23
47
1.






RO




RO

RO



05-1.43
1.22
1.16
1.07
1.26
1.25
1.27
1.27
1.07
1.09
1.26
1.26
1.24
1.11
1.26
1.23
1.27
1.25
15 Peaks

DC NL 0:
31:
32:
32:

00
57
06
40
0.
RO
RO
RO
RO
43-0.59
1.44
2.44
3.16
2.71
269.51
46,341.30
71,794.40
10,427.19
17,082.98
8,409.61
641.58
77,283.50
54,328.10
12,573.09 .
25,383.70
2,620.00
58,300.00
2:011.00
3,730.00
14,890.00
913.88
406,316.45
4,633
3,400
3,757



66
11
10
37
6
21
37
19
14
984
98

11
17
4
3

.94
.65
.35



.39
.14
.34
.30
.97
.69
.26
.31
.56
.30
.59

.63
.64
.31
.23

2,976.17
2,223.06
2,423.22

0.

36.21
6.34
7.98
18.15
3.15
11.67
19.18
12.53
10.48
664.06
69.05

9.27
5.44
6.72
8.49

1
1
1

.000 12378-PeCDD AN
.004
.015





869-1.131
0
0
0
0
0
0
0
0
0
0
1
.000
.943
.955 •
.958
.966
.973
.976
.985
.991
.994
.000 13C12-PeCDD 123 IS3











1.004 -.:.-'
I
.012

1.015
1.
1.
1.

.021
.029
034





HvPDF Pnl 1 nu/c


25,110.
37,041.
5,819.
9,493.
4,701.
359.
39,984.
28,377.
7,015.
14,156.
1,450.
30,900.
1 , 120 .
2,060.
8,320.



00
60
79
19
37
36
30
30 '
76
50
00
00
00
00
00


. 0.964-1.049

21,731.30
34.752.30
4.607.40
7,589 .79
3,708.24
282.22
37,299.20
25,950.30
5,557.33
11,227.20
1,170.00
27,900.00
891.00
1,670.00
6, 570. 'DO


0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.

0.379-
12.70
18.30
40.26
9.60

29.
84.
17.

59
23
23

12.12
26.66
6.36
0.
0.
0.
0.
000
968
973
977
981
986
992
998 123473-HxCDF AN
001 123678-HxCDF AN
004
010
013
016 234678-HxCDF AN
038
039 123789-HxCDF AN
042
054

1.121 .
000
968
973
990

SE
SE




QSE
SE

E

SE

PR








Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:27 01/15/98
                                                                        194

-------
  Page No.
  01/15/98
Listing of T980157B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
      ..  QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.






334-386
HxCDD
390-392







390-392
13C12-HXCDD
402-404








402-404
HpCDF
408-410



D

408-410
13C12-HpCDF
413-420
M




418-420
.32:54
33:00
33:30
33:51
33:59
34:18
9 Peaks

DC NL 0:00
32:25
32:52
33:05
33:16
, 33:37
33:43
34:01
. 7 Peaks

DC NL' 0:00
i 32:54
33:04
33:17
33:25
1 33:37
33:42
34:01
DC SN' 34:11
7 Peaks
'
DC NL, 0:00
36:02
36:18
• 36:27
D NH 36:56
, 37:37
4 Peaks

DC NL 0:00
36:00
36:09
36:25
36:33
37:37
5 Peaks



RO
RO


1
RO








1.

RO
RO
RO




RO
0.59
0.56
0.57
4.15
2.58
0.51
	 Abe
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53,726.70
41.368.20
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5.413.55
11,231.51
19,740.06
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Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:27 01/15/98
                                                                        195

-------
  Page No.
  01/15/98
                         Listing  of T980157B.dbf
                         Matched  GC Peaks  / Ratio / Ret. Time
  Compound/
  M_Z.... QC-Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
  HpCDD
  424-426
  424-426

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                        41:10     0.91
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                                                34.09
                                                31.36
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     1.81
    26.72
    29.56
22,899.30
22,929.36
                                                             13.99
                                                         10,382.00
                                                         21,324.10
                                                         21,693.60
                                                            27.32
                                                            23.46

                                                           867.10
                                                            33.35
                                                            34.57
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                                11.83  0.934
                                                                                                        AN
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                                16.71
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             000  13C12-HpCDD  678  IS7
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    15.57  0.955
12,017.30  1.006 OCDF
                                                                                                       AN
 OCDD
 453-460
 458-460
                              0.76-1.02
                DC   NL   0:00  RO  0.62          1.61
                        40:56     0.31     26,985.20
                      1  Peak               26,985.20
                                                         12,096.80
                                  0.902-1.098
                                      0.000
                           14,388.40  1.000 OCDD
                                                                                                       AN
13C12-OCDD                    0.76-1.02
470-472          DC   NL    0:00  RO  1.69          2.14
                        40:55     0.90      2,429.33
470-472               1  Peak                2,429.33
                                                          1,152.03
                                  0.998-1.006
                                      0.000
                            1,277.30  1.000 13C12-OCDD
                                                                                                       IS8
 Column Description	   "Why" Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 . .RT. -Retention Time (mm:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report
                               WL-Below Retention Time  Window
                               WH-Above Retention Time  Window
                               SN-Below Signal to Noise Level
                               
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                               33:00   33:12   33:24   33:36
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TRIANGLE LABS  Text:TLI»443T<
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TRIANGLE LABS Text:TLIt44376 121-124/219 HKT. TIKE - 19:12
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417.8253 f:4 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 051,23316. 0,1 . 00\,T,T) Exp:XDB5as
TRIANGLE LABS Text:TLI»44376 121-124/219 INJ. TIME » 19:12
1003
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TRIANGLE LABS Tejct:TLI#44376 121-124/219 XW7. TIME ' 19:12
1001

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479.7165 r-.4 Exp-.NDBSUS
TRIANGLE LABS Teit:TLI»44376 121-124/219 iyj. TIME - 19:12
1001
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A2.10E8 A2.15E8
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NGLE LASS Text :TLI 94437 6 121-124/219 INJ. TIME - 19:12
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36:41 36:58 37:15 ^^.^37:30^



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441.7428 f:4  BSUB(256,30, -3. 0) ?KD(7,5,3,0.05\,3732.0,1.00\tT,T) Szp:SDB5OS
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TRIANGLE LASS  Text:TLI#44376 121-124/219                   IJTJT. TIKE »   19:12
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18.4ES
-6.3E6
.4.2E6
-2.1S6
 O.OEO
                                        42:00
    Time
                                            -2.3E7
                                             12.1S7
                                             11.9S7
                                             [l. 6E7
                                             ll. 4E7
                                             '•.1.2E7
                                             19.3ES
                                             '.6.9E6
                                             '-.4.SES
                                             12.3ES
              36:00         37:00         38:00         39:00         40:00
rile:T980157 fl-562 Acq: 6-JZN-93 19:09:09 EI+ Voltage SIS 701
430.9729 T:4 Exp:NDB5US
TRIANGLE LASS  Text:TLI»44376 121-124/219                   XK7. TIME -
1001                   ,._,,     37:22  -.T-CT   38:26        39:22
                                             .o.oro
                                        42\00   Time
              36:00         37:00        38:00         39:00
Tile:T9801S7 tl-562 ACIJ:6-JAN-98 19:09:09  EI+ Voltage SIS 70T
513.6775 T:4 Exp:mBSUS
            40:00
TSIANGLE LABS  Text:TLI944376  121-124/219
100$
 90.
 80.
 70.
 601
 SO.
 401
 301
 201
 iol
39
     IJTJ-.  TIME -   19:12
    6
                          41:00
                            41:11
                                       42:00
            40:0
                     40
                 Will
              36s 00
                            37:00
                                         38:00
                                                       39:00
                                                                    40:00
                                                                                               42:00
                                                                                                      205

-------
        40':54         41': 00         41:06         41:12         41:13         41:34
rila:T980157 tl-562 Acq:6-JXN-98 19:09:09 £1+ Voltage SIX 70T Noise:954
469.7773 F:4 SSUB(256,30, -3. 0)  PXS(7,5,3, 0. 05\,3816. 0,1. 00\,T, T) Exp-.NDBSOS
TRIANGLE LABS  Teit:TLI#44376 121-124/219                   INJ. TIME -    19:12
1004      A1.1SE7
riJ.a:T9 80157 11-553 Ac
-------
•MM^
L
L
M^MMM^MH*

f>VafWl I •"'•U 'J"M PS;'- k,.
vnaJ!.. 1 -ww?iv.- wu "Sa\ '.uu
Heloht 3,53 v4L- Span 299 ppa
Systsa file nsae W&
Data file na&e fl:iS89143
Resolution 18888
Group nuaber 2
lonizstion aode El*'
Switching VOLTfiGE
ftef , aasses 292,3825, 416,3768
D 293 J 331 S 368
B 384 K 332 T 378
C 386 L 334 U 376
0 316 II 348 V 418
E 318 N 342
F 329 0 352
0 322 P 354
H 328 8 356
I 331 R 358
tef , iass 416,3768 Peak top
Keicht ,38 wits Span 298 ppa
207

-------
File:T980157 #1-810 Acq:6-JAN-98 19:09:09 EI+
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100%,                                A1.55E8
 60
 40J
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   Voltage SIR 70T~
         INJ.  TIME =   19:12 File Text:TLI»44376 121»
  0.

                     T
                                 26:12   26:18
     25:48  25:54  26:00  26:06
File:T980157 »1-810 Acq:6-JAN-98 19:09:09 EI+
321.8936 F:2 Exp:NDB5US
Sample Text:TLIH44376 121-124/219
100%.                                A1.95E8
  60J
  40J
  20J
                                                       i
                                                                     I
                                I
                                              _2.1E7
                                              _1.5E7
                                              _1.0E7
                                              L5.1E6
                                              LO.OEO
                                              26:24  26:30  26:36  26:42  26:48   26:54
                                              Voltage SIR 70T
                                                  Time
                                                     INJ.  TIME • =
   OJ
                                               82E6
                       19:12 File Text:TLI#44376 121»
                                               3.3E7
                                              L2.7E7
                                              L2.0E7
                                              L1.3E7
                                              L6..6E6
     25:48  25:54  26:00  26:06   26:12  26:18
File:T980157 #1-810 Acq:6-JAN~98 19:09:09 EI+
331.9368 F:2 Exp:NDB5US
Sample Text:TLI»44376 121-124/219
100%.                           26 iJ.0
                                               26:24  26:30  26:36  26:42  26:48  26:54
                                              LO.OEO
                                                  Time
                                               Voltage  SIR 70T
                                                     INJ.  TIME =
  80J
  60 j
  40J
  20J
   0.
26:21
                                                                   19:12 File Text :TLI#44376 121*
                                                                                           3.5E6
                                                                                          L2.8E6
                                                                                          L2.1E6
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                                                                                          L7.0E5
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                                              .O.OEO
                                                  Time
  O
  00

-------
?ile:T980157 #1-396 Acq:6-JAN-98 19:09:09
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100%             32^32
EI+ Voltage SIR 70T

          INJ. TIME =
   32:28   32:30   32:32    32:34    32:36
File:T980157 #1-396 Acq:6-JAN-98 19:09:09
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
lOOi

 80J

 60J
 40J

 20 j

  OJ
                                           32:38    32:40   32:42
                                          El-t- Voltage SIR  70T

                                                    INJ. TIME =
                                                  32:40
                                                                  19:12 File Text:TLI#44376  121*
                                                                                         _1.5E7

                                                                                         Ll.2E7

                                                                                         _8.8E6

                                                                                         _5.9E6

                                                                                         L2.9E6
32:44   32:46   32:48
                                                   Time
                        19:12 File Text:TLI#44376  121»
                                                7.1E4

                                               L5.7E4

                                               L4.3E4

                                               L2.9E4

                                               Ll.4E4
                                               LO.OEO
   32:28   32:30   32:32   32:34   32:36
File:T980157 #1-396 Acq:6-JAN-98 19:09:09
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100%,
 32:38    32:40    32:42
EI+ Voltage SIR 70T

          INJ. TIME =
                                                                   32:44    32:46    32:48      Time
                                                                  19:12 File Text:TLI#44376  121»
                                                                  32^14                  _2.2E5

                                                                                         _1.8E5

                                                                                         _1.3E5
32:44   32:46   32:48
32:28   32:30   32:32   32:34
                                   32:36
 32:38   32:40
                                                           32:42
  ro
   CD

-------
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME =
19:12 File Text:TLI#44376 121»
                 32:54             33:00
File:T980157 #1-396 Acq:6-JAN-98  19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME =
100%.                               33;_QO
 33:12
                                                                                    33:18
         Time
19:12 File Text:TLI#44376  121»
                 32:54            33:00            33:06
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219             /      INJ. TIME =
100*

 80 j

 60 j

 401

 20 j

  0
                                                                   33:12
                       L1.3E6
                       L8.9E5
                       L.4.4E5
                       LO.OEO
                  33:18    Time
                 32:54
19:12 File Text:TLI#44376  121»
                        2.8E4

                       L2.2E4

                       Ll.7E4

                       L1.1E4
                       L5.5E3

                       Lo.OEO
                           Time
                                                                   33:12
33:18
 ro

-------
?lle:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5(JS
Sample Text:TLItJ44376 121-124/219
100%
                                   INJ.  TIME =
           19
 SO.
 60 j
 40_
 20_
  0
12 File Text:TLI#44376 121»
                   _8.9E6
                   L7.1E6
                   15.3E6
                   L3.6E6
                   ;.1.8E6
          T
T
                               ~T
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        33116   33:18   33:20   33:22   33:24   33:26   33:28
File:T980157 ttl-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR  70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLItt44376 121-124/219                   INJ. TIME
100%
 80 j
 60J
 40J
 20 j
  OJ
                                            33:30
                                                                        1
                                                                        .O.OEO
              33:32   33:34   33:36   Time
                                                 19
                        33:25
 33:19
                      Text:TLI#44376
                                  2.2E5
                                 Ll.8E5
                                 Ll.3E5
                                 L8.8E4
                                 L4.4E4
          T
T
                                                                        .O.OEO
        33:16   33:18   33:20   33:22   33:24   33:26   33:28
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR  70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                    INJ. TIME
100S.                                            33^26
 80J
 60 j
 40J
 20_
  0
                                            33J30  ' 33I32 '  33I34 '  33J36    Time
                                                 19:12 File Text:TLIS44376  121»
        33:16   33:18   33:20   33:22   33:24   33:26   33:28   33:30   33:32   33:34
                                                                        L6.7E5
                                                                        L5.0E5
                                                                        L3.4E5
                                                                        L1.7E5
                                                                      1_LO.OEO
                                                                    33:36    Time
   ro

-------
 ile:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME
100%                                                   34_;23
 80J
 601
 40_
 20_
                                                                19:12 File Text:TLIH44376  121*
                                                                                        2.3E7
                                                                                       _1.8E7
                                                                                       _1.4E7
                                                                                       _9.0E6
                                                                                       _4.5E6
   34:00         34:06         34:12         34:18         34:24
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME
100%,                                        34U8
                                                                     34 :30
                                                                                          .O.OEO
                                                                                     34:36   Time
                                                                19:12 File Text :TLI#44376  121»
                                                                                        1.8E6
                                                                                       Ll.4E6
   34:00         34:06         34:12         34:18         34:24
File:T980157 #1-396 Acq:6-JAN~98 19:09:09 El-f Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME
100%                               34^14
 BOl
 60J
 40J
 20J
                                                                       34:30
                                                                                       _7.1E5
                                                                                       _3.6E5
                                                                                        O.OEO
                                                                                   34:36    Time
34:00
                 34 :06
                              34 :12
34
34 :24
19:12 File Text:TLI#44376  121»
                        7.4E5
                       L6.0E5
                       L4.5E5
                       L3.0E5
                       L1.5E5
                       LO.OEO
                           Time
34:30
34 136
ro

-------
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100%.
                           INJ. TIME =   19:12 File Text:TLI#44376  121»
                                                                                         _5.2E7

                                                                                         _3.9E7

                                                                                         L2.6E7

                                                                                         L1.3E7
            33:18        33:24        33:30        33:36        33:42
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME =    19:12
100%.                                   A2L.Z9E8
                                                                           33:48
                                                                lO.OEO
                                                                    Time
                                                                         File  Text:TLI#44376 121»
                                                                                          6.5E7

                                                                                         L5.2E7

                                                                                         13.9E7

                                                                                         L2.6E7

                                                                                         Ll.3E7
            33:18        33:24        33:30        33:36        33:42
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME =    19:12
100%,                                  33;30
                                                                           33:48
                                                                LO.OEO
                                                                    Time
                                                                         File  Text:TLI#44376 121»
                                                                                         _2.1E6
             33:18
33:24
                                     33:30
33:36
33:42
33:48
0 .OEO
   Time
  N>
  v-*
  CO

-------
 ile:T980157  #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
J73.8208  F:3  Exp:NDB5US
 ample Text:TLI#44376 121-124/219                   INJ.  TIME
lOOi

 80J

 60 j

 40J

 20J
  OJ	
  34:06           34:12           34:18           34:24
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME
lOOi                                        A6.52E7

 80J

 60 j

 40j

 20 j

  Oj
  34:06           34:12           34:18           34:24
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME
100%.                             34U.8
                                                19:12  File  Text :TLI#44376 121»
                                                                        .2.3E7

                                                                       _1.8E7

                                                                       -1.4E7
                                               34 :30
                                               34 :36
                                                                       L4.5E6
                                        lO.OEO
                                            Time
                                                 19:12  File Text:TLIK44376 121»
                                                                       _1.9E7

                                                                       L1.5E7

                                                                       L1.1E7
                                                                       L7.4E6
                                                                       L3.7E6
                                               34 :30
                                               34:36
                                        LO.OEO
                                            Time
                                                 19:12  File Text:TLI#44376 121»
                                                                       _1.8E6
  34 :06
34:12
34:18
34 :24
34 :30
34:36
.O.OEO
    Time
  ro

-------
Hle:T980157 #1-562 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR  70T
417.8253 F:4 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME  =
100%                                A4.49E6
 90J
 80J
 70J
 60J
 50 j
 40J
 30J
 20J
 10 j
  0
             35J36       35148       36:00        36:12       36:24
File:T980157 #1-562 Acq:6-JAN-98 19:09:09 EI + Voltage SIR  70T
419.8220 F:4 Exp:NDB5US
Sample Text:TLI#44376 121-124/219                   INJ. TIME  =
100%.                                A9.28E6
 90 J
 80J
 70J
 60 j
 50 j
 40J
 30J
 20 j
 10J
                                         19:12 File Text:TLI#44376 121»
                                                           3^48
                                                         Time
                                          19:12  File  Text:TLI#44376 121»
   0.
                                                                _2.1E6
                                                                _1.8E6
                                                                _1.6E6
                                                                _1.4E6
                                                                _1.2E6
                                                                _9.2E5
                                                                _6.9E5
                                                                L4.6E5
                                                                L2.3E5
                                                                LO.
             35:36
35:48
36:00
36:12
36:24
36:36
36:48
Time
   ro
   H*
   o\

-------
TLI Project:
Client Sample:
44376
121-124/219
Method 23 TCDD/TCDF Analysis (DB-225)
.                  Analysis File:   X98008'i
Client Project: Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-5A-D/ Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000 Dilution Factor: n/a
Dry Weight: n/a Blank File: X980083
GC Column: DB-225 Analyst: KAS
Spike File
ICal:
ConCal:
SPC2NF04
XF24087
X980080
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

^nafrtes % * * : ^' yU-CAfn£fr5> ^<-£ttL^ : •te^'^:^^^ "^ m , ftags
23,7,8-TCDF 85.0
Internal Standard AmL (ng) % Recovery OC Limits
13C,2-2,3,7,8-TCDF . 3.2 78.8 40%-130%
Recovery Standard
13C12-1,2,3,4-TCDD
0.76
Ratio
0.83
Ratio
0.80
21:32
UT
21:31
irr
20:30
E_
Flags
—
Ffags

                    Data Reviewer.
                                         01/11/98
                                       Page 1 of I
                                                      CNF.PSR T2.0I. LARS 6.10.
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                   Printed: 13:3501/11/98

                                                      216

-------
                        Initial
                                     Date..
 Data Review By:
!_/!£
                                        /!/
                                              Calculated Noise Area:
^
I
  he Total Area for each peak with an ion abundance ratio outside
  -atio limits has been recalculated according to method requirements.
                                                                      2.00
  Page No.
  01/11/98
                         Listing  of X980088B.dbf
                         Hatched  CC Peaks / Ratio
               / Ret. Time
 Compound/
 H_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2. .  Rel.RT Compound.N,
                                                                                                    ID..  Flags.
TCDP
304-306 DC NL 0:00
DC WL 16:55
17:08
17:24
17:34
17:39
17:46
18:07
18:15
18:23
: 18:32
18:49
18:57
19:06
19:11
19:16
19:26
19:46
1 20:12
20:17
| 20:27
20:39
20:51
21:01
21:16
21:24
21:32
21:44
21:58
22:04
22:32
1 22:44
23:20
DC WH 23:44
304-306 31 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 17:15
DC WL 17:52
DC WL 18:22
DC WL 18:50
DC WL 18:56
0.65-0.89
RO 0.98
RO 0.
0.
RO 0.
0.
RO 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
RO 0.

58
77
51
81
61
76
77
77
87
77
77
78 1,
76
77
38 1,
77
94 1,
77
78
82
77
76
35
33
81
76
30
84 1,
80
64
76
78
57
17,
1.264.31
0.790-1.095
0.000
1,442.66
538,326.
2,969.
5,030.
2.301.
8,928.
539,425.
549.123.
962,315.
518.081.
472,267.
054.476.
599,259.
396,659.
011,366.
661.386.
786,390.
616,109.
136.404.
876,474.
711,413.
126,062.
977,617.
6,553.
932,170.
455,027.
953,659.
033,853.
882,185.
1,755.
560,577.
77,508.
1,986.
456.171.
00
16
93
15
58
00
00
00
00
00
00
00
00
00
00
20
00
20
00
00
50
00
07
00
00
00
00
00
79
00
90
22
48
235.041
1,291
2.243
1,213
3,859
234,385
238,477
448 , 447
225,706
205,263
461.759
259,708
172,195,
472,870
288,092.
951,853,
267,469.
59,805.
395.983.
308,573.
54.553.
449,765.
2,850.
417.617.
196,847.
423,215.
470,899.
391,964.
763.
242,886.
33,988.


.00
.67
.19
.58
.73
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
,00
.00
60
,00
00
20
00
77
00
00
00
00
00
82
00
30


303,285
2.513
2,782
2,009
5,068
304,540
310,646
513,868
292,375
267,004
592,717
339,551
224,464
538,496
373,294
1,009,260
348,640
76,598
480,491
402,840
71,509
527,852
8,637
514,553
258,180
530,444
562,954
490,221
1,199
317,691
43,520


0.65-0.89
0.
0.
RO 0.
RO 1.
0.
RO 1.
72
84
53
36
86
25
90.
210.
39.
146.
499.
158.
55
64
53
40
36
54


















.00
.94
.74
.65
.35
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.60
.00
.00
.30
.00
.61
.00
.00
.00
.00
.00
.30
.00
.10


0.
0.
0.
0.
786
796
809
816

B


0.820
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.

826
342
848
354
861
875
381
888
392
895
903
919
939
943
950
960
969
977
988
995
001 2378-TCDF
010
021
026
047
057
084
103


E
B
B
E
E
E
E
E
E
B
E
E
E
E
E
E
B

E
AN E
E
B
E

E



0.953-1.047






0.
0.
0.
0.
0.
0.
000
802
830
354
875
380






Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                           Printed: J3:2<^p1/11/98

-------
  Page  No.
  01/11/98
Listing of X980088B.dbC
Matched OC Peaks / Ratio /
                                                     Ret.  Time
  Compound/
  M_Z	QC.Log Omit Why ..RT. OX Ratio Total.Area...  Area.Peak.1.. Area.Peak. 2. .  Rel.RT Compound.Mama..  ID..  Flags.
  316-318
  13C12-TCDD
  332-334
  332-334
DC
DC
DC
DC
DC

ML 19
WL 19
WL 20
WL 20
WL 20
20
:15
:47
:00
:13
:27
:39
20:47







DC
DC
21
21
21
21
22
22
22
WH 23
WH 23
:00
:31
:42
:52
:03
:19
:23
:01
:42
RO
RO
RO
RO
RO
RO
RO


RO
RO
RO
RO
RO
RO

1
2
1
1
1
4
0
0
0
1
1
1
1
0
0
0
.28
.30
.03
.08
.16
.22
.60
.78
.83
.88
.06
.33
.11
.96
.95
.76
9 Peaks

DC






DC

NL 0
19
20
20
21
21
22
WH 23

:00
-.52
:14
:30
:12
:21
:04
.-.14
0.
RO
RO




RO

65-0.89
1
1
0
0
0
0
2
0
.31
.62
.79
.30
.77
.34
.35
.84 .
6 Peaks
                     491.03
                     242.79
                     309.40
                     374.00
                     658.60
                      57.97         138.09
                     470.34         204.61
                     280.44         123.33
                  22,142.30      10,011.00
                      93.46         99.21
                     540.13         322.66
                     257.55         194.07
                     122.71         77.14
                      64.09         34.80
                   1,085.54
                      81.15
                  24,028.99

             Above:  TCDP  / TCDD. Follows
                     43.37
                     63.74
                 15,575.45
                 20,190.79
                    231.56
                    415.61
                     55.47
                    213.56
                 36,532.62
                                                                                  0.895
                                                                                  0.919
                                                                                  0.930
                                                                                  0.940
                                                                                  0.950
                                                                           32.75  0.960
                                                                          340.83  0.966
                                                                          157.11  0.976
                                                                       12,131.30  1.000 13C12-2378-TCDF ISO
                                                                           52.80  1.009
                                                                          305.16  1.016
                                                                          145.51  1.025
                                                                           69.33  1.037
                                                                           36.21  1.040
                                                                                  1.070
                                                                                  1.101
0.901-1.099


6,
8,





58
851
963
100
189
73


.21
.81
.69
.74
.63
.64


36.
8,723,
11,227,
130,
225,
31,


.01
.64
.10
.82
.98
.34

0
0
1
1
1
1.
1
1,
.000
.982
.000 i:
.013 i:
.048
.055
.091
.143
                                                                                   000 13C12-2378-TCDD IS1
                                                                                       13C12-1234-TCDD RSI
 Column Description.
       •Why" Code Description	  QC Log Desc.
 H_2   -Nominal Ion Hassles)
  ..RT. -Retention Time (mtn:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
  *** End of Report ***
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
ffii»:Z9Boo8a ti-aaa AC?»  7-ais-i99S vtitia>07 ac si* Voitmg* jig
303.3016 3303(356,30,-3.0)  PKD(5,3. l,0.10*,1404800.0,0.00*,r,P)
       T**t:TLX*44376 1117-130/216/317/318 Pile TauttJ HUAaOLX LABS
  17:00         10:00        15:00        20:00         21:00        22:00        23:00
             il-883 Aeq: 7-JAN-1998  20:48:07 OC EH- Voltage SIR AatoSpec Soiuei3S7289
303.8987 BSUB(256,30,-3.0) PXD(5,3,1,0.10*,1429156.0,0.00*,PIP
Staple TexttTLI«44376 1117-120/216/217/218  file Itett  TXIABOLB LABS
100H               A5.J.4E9     AS.\8S9   ,_,    A4.gOS9AS 28S9  A5.30S
  80.
  40:
 30:
                                                                              JL3.18E9
                                                                                 I
  17:00        ,18:00        19:00         20:00        21:00        22:00         23:00
Pile:Z980088 #1-883 Actj:  7-JAU-1998 20:48:07 OC SI* Voltage SIR AutoSpeo Solae:18948
315.9419 BSVB(256,30,-3.0)  ?XD(S.3,1.0.10*,75792.0,0.00\,P,P) Bxj?:ZCONP_TT
Saaple Text:TLI#44376 1117-120/216/217/218 Pile Text:  TRZANQLE LABS
10031                                                          A1.00E8

 80.

 601           '
 201

                                                         -r
  17:00         18:00        15:00        20:00         21:00        22:00        23:00
P11»:X980088 91-883 Acqs  7-JAK-1998  20:48:07 QC  SI+  Voltag* SIR AutoSpac Hoiaa:26327
317.9389 BSUB(2S6,30,-3.0)  PKD(5,3, 1, 0.10%, 105308. 0, 0. OQ\,V.y)
3oopl« r*xt:TLI*44376 1117-120/216/217/218  Pll»  T«urt»  TRULBBLB LABS
1009t                                                         A1.21S8
 80.
 60.
 40.
 20.
  17:00         18:00        19:00        20:00         21:00        22:00
Pll»:X9800ee 01-883 Aeq:  7-JAH-1998  20:48:07   Voltaffm SIS AutoSptc
375.8364 B3Cp:KONP_TT
Sajoplo Toxt:TLIf44376 1117-130/216/217/218  Pllf tact*  TRIANBLB LABS
                                                                                  23 tOO
                                                                                                 O.OSO
                                                                                                    Tim*
 1.1S9

 8.6EB

.6.4E8

.4.3S8

.2.1S8

.O.OSO
    Time



.2.2E7

.1.8E7

.1.3E7

.8.8E6

.4.4E6

.O.OEO
    Time



2.7E7

2.2E7

.1.6B7

.1.1S7

S.4E6

O.OEO
    Time
1003
80.
60.
40.

20.
21:16
'


\ . 22:09
"•" : 1 A A
A- — — 'V^yLjV






  17:00
               18:00
                             19100
                                          20100
                                                                                                .2.9S6

                                                                                                '.2.2SS

                                                                                                .1.5S6

                                                                                                K7.3S5

                                                                                                O.OSO
                                                       21 tOO
                                                                     22:00
                                                                                  23:00
                                                                                                  219

-------
Flle:X980088 91-893 Acqt 7-*JAN-lySo 2Q:4o:u/ ec SIf Voltage SIR AUCOSpeo Holt
319.8963 BSUB(2S«,30,-3.0) PXD(5,3,l,0.10*,935a4.0,0.00*,P,P)
Sample TextiTLI944376 1117-120/216/217/218 Pile Text: TR1ABOLS LABS
100HA2.72B9
80.

60.

40.

20.
               .62B9
                1
                       A6.02E8
                                             A1.11S9
                          AAA'T'^A
-7.3B8


.5. 7B8

.4.3B8


.2.9B8

-1.4E8
     18,00            19tOO            20,00           21tOO           22:00
Fil»:X980088 91-883 Aeqt 7-001-1998 20t48t07 OC SX+ Voltaff» SIR JLutoOpme Boi*ut62293
331.8936 BSUB(256,30,-3.0) fXD(5,3,1,0.10H.249172.0,0.00*.?.?)  SspiKOSP_rT
Saapl*  Tvrt:TLX*44376 1117-120/216/217/218 Pile Tmxtt TSUUBLB UBS
100\i3.S2B9
                                                                                     23100
 O.OSO
    Time
 80.

 60.

 40.

 20:
           A2.07B9
                      A7.70E8
                                            &1.42E9
                          AAA'T'.v/V
 9.3B8


.7.4E8


'.S.6B8


'.3. 7E8


.1. 9E8
     18,00            19,00            20:00            21:00            22:00
P11»:Z980088 tl-883 ACIJ: 7-JAN-1998 20:48:07 OC SI+ Yoltago SIR AutoSpac Nola»:20654
327.8847 BSUB(256,30,-3.0) PKD(5,3,1,0.10*. 82616.0,0. 00*,P,P) Sxp:XCON?_TT
Sanplo  Tvrt:TLI»44376  1117-120/216/217/218 Pila Tart: TRUUXJLB LABS
100H                                                                     A9.J.6S8
 80.

 60.
                                                                                      23:00
                                                                                             O.OEO
                                                                                                T±ma
 40.
 20.
                 A2.40E8
                                       A2.78E8x2.S3Ea
                        A5.BOB7
                          /\
                                                                                           2.0E8


                                                                                           .1.6E8


                                                                                           .1.2E8


                                                                                           .8.1S7


                                                                                           .4.1S7
     18:00            19:00            20:00            21:00            22:00
Pile:X980088 91-883 Acqt 7-JAH-1998 30:48:07 QC SI* Voltago SIR AutoSpec Soime:16074
331.9368 BSUS(2S6,30,-3.0) PXD(S,3, 1, 0.101, 64296.0, 0.00\,P,P) Bxp:XCONP_TT
Staple  Text:TLI944376 1117-120/216/217/218 Pile Text: TRIANGLE LABS
                                             A8.96E7
                                                                                      23:00
                                                                                             O.OSO
                                                                                               Tins
 80.

 60.

 40.

 20.
                                                                                           3.3E7


                                                                                          '.1.8S7


                                                                                          .1. 4E7


                                                                                          .9.2E6


                                                                                          .4.6B6
     18:00            19:00            20:00            21(00            22:00
Pil«iX380088 tl-883 Acqi 7-JAN-1998  20:48:07 OC SI+ Voltage SIR AutoSpoc Soia»:12248
333.9338 BSUB(2S6,30,-3.0) PXD(5,3,1,0.10*,48992.0,0.00*,P,P) Batp:KOSP_TT
Sample  Text:TLX*44376 1117-120/216/217/218 Pile Text: TRIANOLB LABS
100*                                         A1.12B8
 80.

 60.

 40.

 20.
                                                                                      23:00
                                                                                             O.OEO
                                                                                               Time
                                                                                          -2.9E7

                                                                                          .2.3B7

                                                                                          .1.7B7

                                                                                          .1.1S7

                                                                                          .5.7B6
     18:00
                      19100
                                      20*00
                                                      21100
                                                                      22100
                                                                                      23100
                                                                                            O.OSO
                                                                                               rime
                                                                                        220

-------
   17:00        10:00        15:00         20:00        21:00        22:00
\Pll»:I9800ea  91-883 Acqt  7-JAN-1998 30,48,07 
-------
TLI Project:      44376
Client Sample:   117-120/216/217/218
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  T9801FJ
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-4A-D/

1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01/06/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2.3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2.3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (rig) DL EMPC
2.0
16.4
18.8
40.2
65.1
-Bl— 7^0
108
EMPC 1£3 ? l(
44.3
EMPC 8ft4 t2o
96,3 ?2.O
59-f 7 20
•82^" >2-o
5.0
126. 720
31.6
A
Amt (ng) Number DL EMPC
-9W =1 11 975 ^
1 , 4*7- > 2. /7 Q or* ^ *» *9 / ^
*my ** *^ o jtj4 7 ^ c/ B
-470 > 2o 7
•249 > Zc? 2
-343 7 -f 9 t370 ^^
3*^ ?2,0 10 925 ' 2o
498 ?2C 13 305 ? 2^0 4 x"«
Bat»
0.79
1.54
1.21
1.22
1.22
1.00
0.81

1.46

1.09
1.14
1.13
1.25
1.02
1.04
0.90









HT
26:23
30:32
33:38
33:43
34:02
37:07
40:58

29:32

32:56
33:02
33:31
34:18
36:02
37:38
41:11









Ffags

	 •

£
PRE
SE_
E_
SE_
E_
QSE
QSE
>c
SE_
SE_
PR_
SE_
(S
	 '
Flags
SE_
SQE
SQE
SE_
SQE
SQE
SQE
SE<3
                                       Page 1 of 2
                         X37.PSR V2.01. LARS «. 10.OSo
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Print
22*27
01/15/98

-------
TLI Project:      44376
rlient Sample:   117-120/216/217/218
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:   T980156

13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-U,3,7.8-PeCDD
13Cirl,2,3,6.7,8-HxCDF ,
13C,2-l,2,3,6,7,8-HxCDD
l3C,2-l,2,3,4.6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
I3C,2-1,2,3,4,6,7,8,9-OCDD
|iir|^a^
37CL-2,3,7,8-TCDD
I3C,:-2,3,4,7,3-PeCDF
l3Cr-l,2,3,4,7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD ,
13C,:-l,2,3,4,7,8.9-HpCDF
1

fA1t»|i|al&
13C,:-l,2,3,7,8,9-HxCDF
13Cr-2,3,4,6,7,8-HxCDF


»Ci:-l,2,3,4-TCDD
"Ci:-l,2,3,7,8,9-HxCDD

2.1
3.2
2.9
4.2
3.5
3.6
3.4
4.8
10.7
|;||r|||||||^|||||
3.6
4.6
3.3
4.6
5.0


rfmijiiilillli
3.8
3.3





52.7
79.6
72.7
106
86.7
89.7
85.4
119
134

90.8
115
83.4
116
126



95.8
82.6

illlllSililllllllii



40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%- 130%
25%-130%

70%-140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%


|p5:limitsi|
40%- 130%
40%- 130%

|||:s;|||||lis|l;|||i;



0.82
0.80
1.48
1.50
0.55
1.17
0.51
1.02
0.95


1.50
0.56
1.19
0.43



0.51
0.55


0.80
1.20
:•:•;•:•: -:•:•:•' •:• iiii—i; 'x'X'X':-
liiiiRjIii;
25:44
26:22
29:32
30:31
33:01
33:43
36:01
37:05
40:57
IsSssSD-pHswi
:H*:*:;S:"4i::SSS:
26:23
30:12
32:55
33:37
37:38



34:18
33:31


26:12
34:02
x::::::::::wi:>'::S:^y>:W:>A;X
Q 	

Q_





—


Q

-------
                         Initial
                                    ..Daca..
  Daca  Review By:
                     Calculated Noise Area:
                                             2.00
  The  Total Area Cor each peak with an ion abundance  ratio outside
  ratio  limits has been recalculated according  to  method requirements.
  Page No.
  01/15/98
Listing of T980156B.dbf
Hatched GC Peaks / Ratio /Ret.  Time
  Compound/
  M_Z.... QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2. .  Rel.RT Conpound.Name..  ID..  Flags.
TCDF
304-306 DC ML 0:00
22:42
23:10
23:23
23:44
24:04
24:26
24:41
24:54
25:19
25:33
25:45
26:07
26:19
26:34
26:51
27:01
27:23
27:36
304-306 18 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 22:42
DC WL 23:09
DC WL 23:23
DC WL 23:32
DC WL 23:46
DC WL 24:05
DC WL 24:27
DC WL 24:42
25:08
25:19
25:32
25:44
26:07
26:19
DC WH 27:43
316-318 6 Peaks
0
RO


RO
RO
RO
RO
RO
RO
RO

RO
RO







0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO
RO
.65-0.89
3.28
0.83
0.35
0.90
0.96
0.95
0.94
0.95
0.51
0.90
0.35
0.96
0.94
0.33
0.30
0.31
0.79
0.30
0.80
1
65-0.89
2.78
2.20
3.76
3.23
1. 34
3.07
1.47
1.66
2.21
1.94
1.17
1.14
0.82
1.87
1.36
1.17
0.878-1.073
3.86
49,520.60
54,596.10
62,148.42
150,062.90
104,594.96
121,220.93
80,932.72
85,031.49
58,224.36
73,458.70
80,418.53
59,133 .40
61,190.30
17,367.19
376.55
2,601.44
8,715.21
1,214.24
,070,308.54
0.000
22
25
31
31
55
64
43
36
29
33
43
31
28
7

1
3


,408.00
,158.60
,619.20
,485.70
,982.70
,483.50
,469.30
,991.10
,710.40
,667.70
.424.50
,521.30
,693.60
,705.34
163.08
,152.14
,883.40
533.10

27
29
35
84
59
68
45
73
32
39
. 45
33
32
' 9

1
4


,112
,437
,112
,781
,093
,436
,724
,229
,395
,791
.434
,408
,496
,661
203
,449
,831
676

.60
.50
.10'
.30
.20
.40
.70
.00
.40
.00
.20
.70
.70
.35
.47
.30
.31
.14

0
.382
0.900
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1 .
1.
1.
1.
1.
1.

0.961-
7.04
25.61
31.38
29.49
74.13
98.06
165.43
119.60
80.73
111.67
84.43
116.94
2,287.74
62.23
73.97
21.89
2.737.03
	 I-- Above: TCDF /












1,












122.48
55.94
75.12
029.48
65.60
56.72






















63.
47.
66.
1,258.



35.
41.










09
73
07
26
16
79

0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
.909
,922
935
949
959
963
984
993
001 2373-TCDF AN
015
023
032
043
050
064
073

1.039
000
332
900
909
915
924
936
950
960
977
984
992
000 13C12-2378-TCDF ISO
015
023
077
QE
QSE
QSE
QSE
QSE
QSE
QSE
QSE
QSE
QSE
SE
QSE
QSE
QE
Q
Q
QE
Q














Q



TCDD Follows 	
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 09:27 01/15/98

-------
Page No. 2 Listing of T980156B.db£
01/15/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
X_Z.... QC.Log Omit Why ..RT. OK Ratio Total. Area. .. Area. Peak.
"TCDD 0.55-0.39
320-322






M
AN




320-322
37C1-TCDD
323













328
13C12-TCDD
332-334











332-334
DC NL 0
23
24
24
25
25
25
26
26
26
26
26
27
:00
:57
:19
:35
:15
:31
:53
:17
:23
:32
:42
:54
:20
RO 2
RO 0
0
0
0
0
0
0
0
0
0
0
0
.92
.92
.87
.78
.79
.78
.78
.78
.79
.79
.78
.79
.79
12 Peaks

DC NL 0
DC WL 23
DC WL 24
DC WL 24
24
' 25:
25:
25:
25:
' 25:
I 26:
26:
26:
26:

:00
:53
:11
:19
:35
;00
:15
:30
:43
:53
:10
:23
:32
44






























10 Peaks
8.11
65,379.38
59,733.30
31,221.50
59,531.60
41,619.50
24,108.90
56,700.00
1,916.00
8,622.92
4,560.43
1,903.92
1,939.35
357,286.30

1.55
525.62
161.64
429:36
195.74
7,167.71
328.34
214.57
41.79
129.91
111.22
2,552.42
67.58
13,542.30
24,3.52.08

33,369
27 , 747
13 , 664
26,202
18,188
10,533
24,900
846
3,816
2,002
842
853






195.
7,167.
328,
214.
41.
129.
111.
2,552.
67.
13,542.

1. . Area. Peak.

.60
.10
.70
.30
.90
.50
.00 .
.00
.42
.60
.47
.00






.74
.71
.34
,57
,79
91
22
42
S3
30


36.937
31,986
17,556
33,378
23,430
13.575
31,800
1,070
4,306
2,557
1,061
1,081

















',. 0.65-0.89
DC NL ' 0:
DC WL ' 23:
DC WL 24:
24:
24:
1 24:
25:
25:
25:
26:
26:
1 26:
00
57
21
25
36
42
15
47
52
12
22
40
RO 2.
RO 1.
RO 1.
RO 1.
RO 1.
RO 1.
0.
RO 1.
RO 1.
0.
0.
0.
36
06
30
19
02
21
66
24
35
SO
30
68
9 Peaks
4.57
21.19
11.13
10.35
5.93
11.36
31.96
15.35
10.07
2,310.39
2,793.58
61.57
5.751.16

PeCDF
340-342
1.32-1.78
DC NL , 0:
00
RO 0.
60
2.99



6.
3.
7.
12.
10.
7.
1,252.
1,241.
24.




96
41
75
75
72
69
91
17
86




2. .
0.

.50
.20
.30
.30
.60
.40
.00
.00
.50
.33
.45
.35

0.















Rel.RT Compound . Name .. ID..
903-1.045
0.000
0.908
0.922
0.932
0.958
0.963
0.982
0.997
1.001 2378-TCDD AN
1.006
1.013
1.020
1.037

924-1.076
0.000
0.909
0.917
0.922
0.932
0.943
0.953
0.967
0.975
0.982
0.992
1.001 37C1-TCDD ' SUR1
1.006
1.014

Flags

SE
SE
E
E
E
E
E

E




















0.924-1.076 .



5.85
3.35
6.42
19.21
8.67
5.69
1,557.
1,552.
36.

'98
51
71

0.000
0.903
0.924
0.926
0.933-
0.937
0.953
0.978
0.981
0.994 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.011














PeCDF Follows ---




0.931-1.063

0.000

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98

-------
 Page No.
 01/15/98
Listing of T980156B.dbf
Hatched GC Peaks /  Ratio
/ Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area..,
                          Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID..  Flags.





27:
28:
28:
28:
28:
35
;02
13
19
34
28:43













340-342
13C12-PeCDF
352-354


















352-354
PeCDD
356-358





28:
29:
29:
29:
29:
29:
29:
30:
30:
30:
30:
31:
DC WH 31:
52
10
15
27
32
41
49
13
22
40
53
09
36
RO


RO

RO

RO
RO




RO
RO

RO

RO
1.12
1.49
1.51
1.22
1.42
1.06
1.33
1.18
1.13
1.37
1.46
1.41
1.35
1.14
1.17
1.47
1.14
1.46
1.84
18 Peaks

DC NL 0:
27:
27:
DC SN 28:
28:
28:
28:
29:
29:
29:
29:
DC SN 30:
30:
30:
30:
30:
DC SN 30:
31:
31:

00
35
43
18
34
41
52
10
15
32
49
00
12
21
39
46
54
13
25
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO
RO

RO
RO

RO
RO
RO
15 Peaks

DC NL 0:
28:
29:
29:
29:
29:

00
48
15
29
37
48
1.
RO
RO

RO

RO
,32-1.78
2.07
3.07
2.39
3.06
3.56
2.64
1.17 .
2.74
2.45
1.48
2.23
5.21
1.50
2.28
1.95
1.51
2.76
1.99
• 2.97
55,413.47
155.31
660.35
233.25
39,375.20
73,995.57
46,011.30
72,330.17
53,938.09
38,283.70
30,715.40
37,862.00
50,751.20
55,766.20
60,649.53
14.133.88
349.78
10,758.26
59.85
641,382.66
33



23
44
26
43
32
22
18
22
29
33
36
8

6


,682.70
92.96
397.30
141.78
,104.40
,977.70
,288.10
,965.40
,785.90
,154.60
,253.00
,121.20
,192.10
,897.10
.865.40
,402.58
212.61
,383.54


30,155
62
263
116
16,270
42,337
19,723
37,300
28,987
16,129
12,462
15,740
21,559
29,724
31,522
5,731
186
4,374


.70
.35
.05
.24
.80
.40
.20
.30
.30
.10
.40
.30
.10
.10
•10
.30
.43
.72


0.934
0.949
0.955
0.959
0.967
0.972
0.977
0.988
0.990
0.997
1.000 12378-PeCDF
1.005
1.010
1.023 23478-PeCDF
1.028
1.033
1.046
1.055
1.070

QSE
Q
Q
0.
QE
QSE
QSE
QSE
QSE
QSE
AN E
QE
QSE
AN QSE
QSE
Q
Q
Q


0.364-1.136
1.48
47.33
10.58
4.00
16.40
111.21
97.90
48.36
52.53
2,516.29
122.48
2.45
2,982.32
95.98
3.64
11.10
1.43
39.55
8.03
6.269.70
32-1.78
0.78
1.05
1.56
1.20
1.56
1.30
4.74
61,435.59
9,538.62
46,673.06
9,574.73
43,682.82









1,


1,







56.96
9.93

22.38
115. 14
59.51
52.45
50.41
,563.18
106.91

,788.54
85.69
6.60
6.63

30.92
9.37

13
4

6
43
50
19
20
1,053
48.

1,194
37.
3.
4.

15.
3.

.56
.15

.43
.61
.92
.16
.60
.11
.03

.28
.64
.39
.42

51
.15
0.000
0.934
0.933
0.953
0.967
0.971
0.977
0. 988
0.990
1.000 13C12-PeCDF 123
1.010
1.016
1.023 13C12-PeCDF 234
1.023
1.033
1.042
1.046
1.057
1.064









IS2 Q


SUR2 Q









37,
5,
28,
5,
26,

343.20
811.47
369.90
831.93
552.30

35,473.
3,727.
23,677.
3,742.
20,355.
0.939-1.022

90
15
70
30
50
0.000
0.944
0.958
0.966
0.971
0.977

SE

QSE

SE
Triangle Laboratories, Inc.® Anaiy sal Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:27 01/15/98
                                                                     226

-------
  Page No.
  01/15/98
Listing  of T980156B.dbf
Matched  GC Peaks / Ratio  / Ret. Time
  Compound/
  M_Z	 QC.Log Omit Why ..RT. OK Ratio Total.Area...  Area.Peak.1. . Area.Peak.2. . Rel.RT Compound.Name..  ID.. Flags.







356-358
13C12-PeCDD
368-370













363-370
:CDF
4-376










AX
M
MX
AN
M

374-376
13C12-HXCDF
384-336


29
30
30
30
30
30
30
-.58
:03
:15
:23
:32
:39
:59



RO



1.54
1.56
1.54
0.34
1.54
1.56
1.55
.12 Peaks

DC NL 0
28
DC SN 28
29
29:
29
29:
30:
30:
30:
' 30:
30:
31:
, 31:

:00
:48
:59
:10
:15
:29
:48
:03
:14
:22
:31
:38
;00
32
1

RO
RO

RO
RO
RO
RO
RO
RO


RO
RO
.32-1.78
1.71
2.02
2.38
1.35
1.26
2.15
2.33
2.32
2.10
2.33
1.50
1.51
1.35
0.80
12 Peaks
-. ... ?\u«

DC NL 0:
31:
32:
32:
32:
32:
32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:

00
57
07
15
23
32
45
56
02
08
19
26
31
15
18
24
48
1.
RO










RO

RO



05-1.43
1.61
1.16
1.08
1.26
1.25
1.25
1.18
1.09
1.14
1.26
1.25
1.22
1.13
1.24
1.25
1.25
1.29
15 Peaks

DC NL 0:
31:
32:

00
57
06
0.
RO
RO
RO
43-0.59
1.78
2.95
3.46
12,463
16,824
22,269
9,757
11,213
8.343
9,466
261,743

0
97
2
11
14
47
34
27
26
16
2,110
212
21
4
2,624

113
46,043
65,589
3.046
13,052.
7,623.
474
72,530.
49.359.
11,269.
20,321.
2,970.
55,700.
2,080.
3,130.
12.670.
566.
371,366.
.21
.40
.95
.40
.14
.96
.30
.18

.34
.32
.33
.31
.51
.71
.04
.39
.01
.14
.64
.90
.11
.59
.17
T / «•%
j 1 n>
.61
.60
.40
.26 >
.28
.20
.70
,90
.60
,71
,45
.00
00
00
00
00
03
10
7,563
10,245
13,517
5,930
6,301
5,385
5,749



77

6
3
40
31
24
21
14
1,264
128
15.
2.
.02
.50
.20
.97
.76
.06
.17



.60

.50
.82
.19
.13
.38
.37
.78
.97
.15
.30
.79
. 4.900
6,578
8,752
7,032
4,411
3,458
3,717



38

4
7
18
13
10
10
6
345
34
8
3
.19
.90
.75
.66
.38
.90
.13

0.

.36

.31
.01
.71
.35
.74
.20
.33
.67
.75
.28
.48
0.982
0.985
0.991
0.996
1.001 12378-PeCDD AN
1.004
1.015

869-1.131
0.000
0.944
0.950
0.956
0.958
0.966
0.977
0.985
0.991
0.995
1.000 13C12-PeCDD 123 IS3
1.004
1.016
1 .033
ff^V TTr* 1 1 riufc


24,750.
34,007.
4,433.
7,247.
4,241.
256.
37,874.
26,594.
6,290.
11,278.
1,630.
29,500.
1,150.
1,740.
7,050.



60
30
04
03
09
61
50
30
46
60
00
00
00
00
00



21,293.
31,581.
3,563.
5,805.
3,387.
218.
34,556.
23,264.
4,979.
9,042.
1,340.
26,200.
930.
1,390.
5.620.


6. 964-1. 049

.00
.60
.22
25
11
,09
40
30
25
35
00
00
00
•oo
00


0.000
0.963 QSE
0.973 " QSE
0.977
0.981
0.985
0.992
0.997 123478-HxCDF AN QSE
1.001 123678-HxCDF AN SE
1.004
1.009
1.013
1.015 234678-HxCDF AN SE
1.037
1.039 123739-HxCDF AN PR
1.042
1.054

0.879-1.121
8.
11
15.76
30.
67

30.
70.

78
19

10.
20.

44
31
0.000
0.963
0.972
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 09:27 01/15/98
                                                                      22
                                                                                                   7

-------
  Page No.
  01/15/98
Listing of T980156B.db£
Matched GC Peaks / Ratio / Ret. Tine
  Compound/
  M_2.... QC.Log Omit Why  ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2. . Rel.RT Conpound.Name..  ID.. Flags.





384-386
32
32
33
33
34
:39 RO
:55
:01
:31
:18
2.44
0.56
0.55
0.55
0.51
7 Peaks
7.94
1,995.22
2,596.73
2,361.41
2,166.45
9,174.18

HxCDD
390-392







390-392
13C12-HXCDD
402-404









402-404

DC NL 0
32
32
33
33
33
33
34:
1
:00
:26
:52
:06
:16
:38
:43
:02
.05-1.43
1.26
1.22
1.06
1.10
1.21
1.21
1.22
1.22
7 Peaks

DC NL 0:
32:
33:
33:
33:
33:
33:
34:
34:
DC SN 34:
1
:00 RO
;53
:05
;17 RO
24 RO
:37
:43
;02
12 RO
17 RO
.05-1.43
1.74
1.23
1.40
2.56
0.90
1.19
1.17
1.20
2.58
1.76
8 Peaks
62.38
28,853.00
62,553.40
56,085.40
9,952.74
7,899.32
19,074.39
30,655.00
215,073.25

7.17
30.77
39.57
11.39
4.32
1,792.45
1,399.79
2,121.26
3.44
4.79
5,908.99

HpCDF
408-410




408-410
13C12-HpCDF
418-420


418-420

DC NL 0:
36:
36:
36:
37:
0.
00
02
18
28
38
88-1.20
1.04
1.02
1.03
1.04
1.04
4 Peaks

DC NL 0:
36:
37:
0.
00 RO
01
38
2 Peaks
37-0.51
1.84
0.51
0.43
26.79
74,860.40
20,983.10
20,862.30
14,295.27
131,001.57
12
714
913
333
733

.84
.02
.19
.76
.53

5
1,281
1,678
1,527
1,432

.26 0.989
.20
.54
.65
.92

0
1
1
1

.997 13C12-HXCDF 478 SOR3
.000 13C12-HXCDF 678 IS4
.015 13C12-HXCDF 234 ALT2
.039 13C12-HXCDF 789 ALT1









15,829
32,149
29,366
5,458
4,328
10,486
16,352



16
. 23
13
2
972
1,025
1,155.
9.



.50
.80
.30
.82
.45
.60
.70



.97
.09
.61
.67
.14
.47
.46
.71



13,023
30,403
26,719
4,493
3,570
8,587
•• 13,802



13
16
5
2
820
874
965
3


0.

.50
.60
.10
.92
.87
.79
.30

0.

.30
.48
.31
.98
.31
.32
.80
.77


953
0
0
0
0
0
0
1
1

970
0
0
0
0
0
0
1
1
1
1

-1.015
.000
.962
.975
.982
.987
.998 123478-HXCDD AN
.000 123678-HXCDD AN
.009 123789-HxCDD AN

-1.030
.000
.975
.981
.987
.991
.997 13C12-HXCDD 478 SUR4
.000 13C12-HXCDD 678 IS5
.009 13C12-HXCDD 789 RS2
.014
.017



E
QSE
SE


E
PRE
















37,798.
10, 656.
10.648.
7,303.


90
60
70
63


37,061.
10,326.
0.998-1.053

.50
50
10,214.10
6,991.

64

0
1
1
1
1,

.000
.000 1234678-HpCDF AN
.008
.012
.045 1234739-HpCDF AN


SE
E



"0. 944-1. Ill
3.33
1,614.07
1,585.38

542.
478.
3,199.45
	 Above: HoCDF / HoCDD Follc

38
58


1,071.
1.106.


69
80

0.
,000

1.000 13C12-HpCDF 678 IS6
1.045 13C12-HpCDF 789 SUR5



Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:27 01/15/98
                                                                       228

-------
 Page No.
 01/15/98
Listing of T980156B.dbf
Matched GC Peaks / Ratio / Ret.  Time
 Compound/
 M_2.... QC.Log Omit Why . .RT.  OK Ratio Total .Area. ..  Area. Peak. 1.. Area.Peak.2. .  Rel. RT Compound. Name. .  ID..- Flags.
 HpCDD
 424-426
  424-426

  13C12-HpCDD
  436-438
  436-433
 OCDF
 442-444
 442-444

 OCDD
 453-460

 453-460

 13C12-OCDD
 170-472
 470-472
                                0.88-1.20
DC


NL 0:
• 36:
37:
:00
:19
:07
RO


1
1
1
2 Peaks

DC





NL 0
36:
36;
37:
37:

:00
:16
:32
:05
:19
0.
RO
RO
RO

RO
.24
.00 55
.00 61
117
14
,916
,693
,610
.71
.60
.40
.00
.88-1.20
1
1
1
1
1
4 Peaks


DC




NL 0:
39:
1 41:


.00
06
ill

0.
RO
RO


.87
.95
.70
.02 1
.64
1

.76-1.02
1
0
0
, 2 Peaks

DC


NL 0:
40:

00
58
0.
RO

76
0
0
1 Peak

DC

DC
1
NL 0:
40:
WH 41:

00
57
22
0.
RO


.37
.73
.90 24
24
-1.02
.54
. 31 41
41
4
27
15
,825
33
,902
.94
.99
.22
.51
.58
.30
HpCDD /

1.
41
,908
,950,

0.
,736.
,736.
.87
.83
.70
.53

98
70
.70
76-1.02
1
0
0
1 Peak
.83
.95 2
.32
2
1.
,788.
2.
,738.
76
49
91
49
                                                          28,001.00
                                                          30,901.20
                                                             26.75
                                                             12.71
                                                            920.30
                                                             27.01
                                                    0.976-1.006
                                                        0.000
                                             27,915.60  0.979
                                             30,792.20  1.001 1234678-HpCDD
                                                                                                       AN
                                            SE
                                            SB
                                                    0.973-1.027
                                                        0.000 -
                                                 13.72  0.978
                                                  7.46  0.985
                                                904.71  1.000 13C12-HpCDD 678  IS7
                                                 16.46  1.006
                                                      Octa-CDD and CDF Follows
                                                    0.902-1.098
                                                        0.000
                                   19.70         26.82  0.955
                                11.313.90     13.094.30  1.006 OCDF
                                                    0.902-1.098
                                                        0.000
                                18,575.70     23,061.00  1.000  OCDD
                                                    0.998-1.006
                                                        0 . 000
                                 1,355.47      1.433.02  1.000  13C12-OCDD
                                                        1.010
                                                                                                       AN
                                                                             AN
                                                                                                       I S3
 Column Description. . . :	   "Why"  Code  Description.	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time (rran:ss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Ral.RT-Relative Retention Time
     End of Report ***
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SK-3elow Signal  to Noise Level
       
-------
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Text:TLI»44376 117-120






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Text:TLIt44376 117-120
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Text:TLH44376 117-120




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TSIANGLE LABS Toxt:TLIt44376 117-120/216/217/218 BET. TIMS - 18:26
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401.8558 T:3 SSUS(256, 30, -3. p) PXD( 7,5, 3, 0. 05\, 11120. 0,1 . 00t,>,r; Eip:NDB5nS
TRIANGLE LABS Text:TLI#4437
1003
80.
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40.
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403.8529 T:3 BSU3(256, 30, -3. 0) PKD(7,5, 3, 0. 05%, 6404. 0,1 . 00%,ft, T) Exp:NDB5US
TRIANGLE LABS Text:TLI»44376 117-120/216/217/218
1001

80.
60.
40.
20.
0.







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rile:T9801S6 tl-396 Acqt6-JK
392.9760 T:3 XxpiHDBSUS
TRIANGLE LASS Text:TLI»4437
100*
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32:58 33:11 33:26 jj.?5
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JtJ. TIMX • 18:26
33:53 34:09 34:28





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.5.8X6
.4.4X6
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.1.5X6
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235

-------
Fila:T930156 #1-563 Acq:6-J3Ur-98 18:23:23 EH- Voltage SIR 70T Koiam: 6814
407.7818 T:4 BSOB(356, 30, -3.0) PKD(7,5,3,0.05\,37256.0,1.00*,T,T) XxptXDSSUS
TRIANGLE LABS Text :TLI#4 4376 117-130/316/317/318 IJKT. TltOS - 18:36
1003
aol
60:

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A3fJ8E8
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/ 1 A1.06X8
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36\00 36:12 36:24 36\36 36\48 J7.-00 37': 13 37\34 37\36 37\48 38*: 00 38\13 Tiae
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409.7789 F:4 BSOB(256, 30, -3. 0) PKJ>(7,5,3,0 .05\,36313.0,1.00\,r,T) Xxp:SDB5US
TRIANGLE LABS Text:TLI#44376 117-130/316/317/218 ZK7. TIMX ' 18:36
1003
aoj
SOJ
40:,
aoj

A3JUX8
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1 1 A1.02X8
1 ( AA 7v
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O.OEO
36\00 36':12 36:24 36\36 36\48 37': 00 37\12 37\24 37\36 J7-48 3a':00 38\12 Time
rile:T980156 #1-563 Acq:6-JAJf-98 18:33:33 -EI+ Voltage SIR 70T Koiae:5649
417.8253 F:4 BSUB(256, 30, -3. 0) PKD(7, 5, 3, 0. 05\,32596 . 0,1 .00%, T,T) Xip:NDBSUS
TRIANGLE LABS Teit:TLI#44376 117-130/216/217/218 XJK7. TIME » 18:26
100J
80:
60:
40:
20:

"•I1" A4.71SS
A A
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'36:66 ' 36>:12 ' 36\24 ' 36^36 36\48 37\00 37\12 37\34 37\36 37\48 38\00 38\12 Time
rile:T980156 #1-563 Acq:6-JAlT-98 18:23:23 EI+ Voltage SIR 70T Soiae:3066
419.8220 F:4 BSU3(256, 30, -3. 0) PKD(7,5, 3, 0. 05\, 12264 . 0,1 . 00\,T,T) Xxp-.NSBSUS
TRIANGLE LABS Text:TLIt44376 117-120/316/217/318 im. TIMX - 18:26
1001
SO:
60:
40:
20:


A1.07E7 A1.11E7
An
A


/ V
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.1.515
.9 . 9E5
.5.015

36\66 ' '36:12 ' '36:24 36:36 36\48 37:00 ' ' 37\ 12 37:34 ' ' 37\36 J7:48 Jfl.-OO 38\12 Time
File:T980156 #1-563 Acq:6-JJUT-98 18:23:23 EH- Voltage SIX 70T
430.9729 F:4 Exp-.NDBSVS
TRIANGLE LABS Text:TLI#44376 117-120/216/217/218 IJKT. TIME - 18:26
1001,
80:
so-
40:
20:
o-

,f,n. ,«.,/! 36:4236:50 37:00 37^22 37^3337:4237^5037^5838:07
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rile:T980156 #1-563 Acq:6-JAW-98 18:23:23 XI+ Voltage SIR 70T
479.7165 t:4 XxptSDBSUS
TRIAXGLX LABS Text:TLI#44376 117-120/216/217/218 UKT. TIMX - 18:26
1003
80:
60:
40:
20:


36:14
A


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36':00 36:12 36:24 36': 36 36:48 37:00 37\13 37\34 37*:36 37\48 JSiOO 38:12 Tiae
236

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TfHi
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7755 r-.4 BSOB(256,30, -3.0) PXD(7,5, 3, 0.05\, 17896. 0, 1.00\,T,T) XzpiSDBSUS
JiGLE LABS Text.-TLH44376 117-120/216/217/218 ua. TIKE' 18t26
A2.80E8 A3 .09X8
A f\
A A


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S\12 36\i'a \36t34 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 J7-is 37:24 J7:J0 37:36
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7737 r:4 BSUB(256, 30, -3. 0) PKD( 7,5, 3, 0. 05\,14412.0,1.00\,r,T) SxpsUDBSOS
JfSZS LASS Text:TLI«44376 117-120/216/217/218 UKT. TIME - 18:26
A2.79E8 A3J(8X8
\ \
\ \
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J L J V_
S:12 36:13 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30 37:36
-.1980156 #1-563 Acq : 6 -J7W- 9 8 18:23:23 EI+ Voltage SIS 70T Hoiae:2258
3169 F:4 BSUB(2S6, 30, -3. 0) PKD(7,5, 3, 0 . 051,9032. 0,1 . 00», F, T) Exp:lO>B5US
NGLZ LABS Text.: TLI 94437 6 117-120/216/217/218 JK7. TIME -' 18:26

.


si-lj 36:18 36]:24 Jsi-JO 36*: 36 JS:ii 36^:48 36:54 J7.-00 J7.-05 J7:ii J7:is 37\24 37>:30 37V36
-.T980156 tl-563 Acq:6-JXN-98 18:23:23 EI+ Voltage SIX 70T Hoiae: 1211
8140 T:4 BSUB(256, 30, -3. 0) PTD( 7,5, 3, 0. OS\r4844. 0,1. 00\,r,T) Exp:NDB5US
UGLS LABS TexttTLI#44376 117-120/216/217/218 HKT. TIME - 13:26
' A9.05ES
' \
' / \
\ '
J V
S(:12 jtfsii '36\24 jtfiJO 36I:36 36:42 JtfUs 36\S4 J7:00 37\06 J7: 12 '37\'l8 J7.'ji 37:30 J7.-J5
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9729 r:4 Exp:SDB5OS
NGLE LABS Text:TLI»44376 117-120/216/217/218 HU. TIKE - 18:26
36.3g 36:42 _^J^_^" ^i^^^~~-i^L
i


f:12 36:18 36i24 36:30 36:36 J5«« J5:4(8 35:54 37:00 J7l<>5' 37\12 31\'ia 37:34 ' 37s 30 ' 37: 36
6.3S7
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O.OEO
Time
6.4E7
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' 0 . OEO
Time
2.1E6
'.1 . 7E6
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-4.2E5
-O.OEO
Time
-2.1E6
.1 . 6E6
.1.2E6
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-4.1E5
O.OEO
Time
.5.2E6
-4.2E6
-3.1E6
-2.1E6
.1 . OE6
.O.OEO
Time
237

-------
r±J.a!T980J.5S #1-563 AcqtS-JZlf-98 18:23:23 EI+ Voltage SIS  701 SoiM»:682
441.7428 T:4 3SUB(256, 30, -3. 0)  PXS(7, 5,3,0.05\,2728.0,1.00\,f,T) ExptXDBSUS
TSIAKGLE LABS  Text:TZIt44376 117-120/216/217/218           HfJ. ma •    18i26
1001
 901
 801
 701
 SOI
 SOI
 401
 30.
 20.
 101
                                                                                    A1.18X8
                                                                                                     -2.2X7
                                                                                                     12.0X7
                                                                                                     ll. 8X7}
                                                                                                     ll. 6X7^
                                                                                                     11.3X7
                                                                                                     11.1X7
                                                                                                     18.9X6
                                                                                                     16.7X6
                                                                                                     14.5E6
                                                                                                     12.2X6
              36:00         37:00         38:00        39:00         40:00
Tile:T9801S6 tl-563 Acq:6-JAN-98 18:23:23 EI+ Voltage SIS 70T Noise: 49 5
443.7399 t:4 BSUB(256, 30, -3. 0)  PKD(7,S,3,0 .OS\, 1980 .0,1. 00\,r,T) Exp-.NDBSUS
TRIANGLE LASS  Text:TLIt44376 117-120/216/217/218           XK7. TIME -   18:26
1001
 901
 aol
 so
 sol
 4ol
 301
 201
 101
  01
                                                                                  41:00
                                                                                    A1.31E8
                                                                                                     fO-OfO
                                                                                                42:00    Time
                                                                                                      2.4E7
                                                                                                     '.2.2E7
                                                                                                     L1.9E7
                                                                                                     ll. 7E7
                                                                                                     ll. SE7
                                                                                                     11.3E7
                                                                                                     19.7ES
                                                                                                     •-7.3Z6
                                                                                                     '.4.9E6
                                                                                                     '-.2.4E6
                                                                     40:00
                                                                                  41:00
              36:00         37:00        38:00        39:00
file:T9S0156 tl-563 Acq:6-JAN-98 18:23:23  EH- Voltage SIS 70T
430.9729 F:4 Exp:NDB5US
TRIANGLE LASS  Text:TLI#44376 117-120/216/217/218           IJKT. TIME '   18:26
      35:25               „,,„    37,3337:5838:2238:47      39;33             40:51
     .O.OEO
42': 00    Tine
1001
 901
 801
 701
 601
 501
 401
 301
 201
 101
  0!
                          36:50
                                                                                          41:34
     -5.3E6
     -4.7E6
     .4.2E6
     '.3. 7E6
     .3.2E6
     .2.6E6
     .2.1E6
     '.1. 6E6
     .1.1E6
     .5.3E5
              36:00         37:00        38:00         39:00
Tlla,T9B0156 tl-563 Acq:6-JXK-98 18:23:23  EI+ Voltage SIS 70T
513.6775 f:4 Exp:NDB5VS
                                                                     40:00
                                                                                  41:00
                                                                                                42:00
      O.OEO
         Time
TRIANGLE LABS
1001
               Text:TLI*44376 117-120/216/217/218
                                                             XKT. TIME -   18:26
              36:00
                            37:00
                                         38:00
                                                       39:00
                                                                    40:00
                                                                                  41 tOO
                                                                                                42:00
                                                                                                238

-------
rUa:f530155  #1-563 Acq: 6-Mlt-3 B 18:33:23 £1+ Volh*ga Six 70T
457. 7377 T:4  BSUB(256,30, -3.0) rXD(7,5,3,O.Q5\e912.0,1.00\,T,T) gXpiXDBSUS
TRIANGLE LASS  Taxt:TLI#44376 117-120/316/317/318           XKT. TIME -   18t26
1004
  80.
                     37X8
         40:54          41:00         41:06         41:12         41:18        41:24
rile:T980156 #1-563 Acq:6-J3OT-98 18:23:23 KI+ Voltage SIS 70T Soiae:423
459.7348 T:4 BSUB(256,30, -3.0)  PXD(7,5,3,0.OS\,1692.0,1.00\,r,T) Sxp:SD35US
TRIANGLE LASS  Text:TLI#44376 117-120/316/217/218           1X7. TIME '   18:26
1004             A2.31E8
                                                                                            41:30
                                                                                                 -3.6E7

                                                                                                 .2.3X7

                                                                                                 .2.2X7

                                                                                                 .1.4X7

                                                                                                 '.7.216

                                                                                                 O.OSO
                                                                                                     Tia
                                                                                                 4.4X7

                                                                                                '.3.5E7

                                                                                                .2.6E7

                                                                                                _I.SE7

                                                                                                .3.3E6
         40:54   ,      41:00         41:06         41:12         41:18         41:24
rile:T98015S #1-563 Acq:6-JAK-98  18:23:23  SI+ Voltage SIR 70T Noiae:851
469.7779 F:4 BSUB(2S6, 30, -3. 0) PXD(7,5,3, 0. 05%,3404. 0,1. 00\,T, T) Exp:NDB5US
TRIANGLE LABS  Text:TLI#44376 117-120/216/217/213           XJK7. TIKE -   13:26
1004           AL+J6E7
                                                                                           41:30
                                                                                                 O.OEO
                                                                                                    Time
                                                                                                 2.4E6

                                                                                                '.1.9E6

                                                                                                .1.4E6

                                                                                                .9. 6E5

                                                                                                .4.8E5
                                                                             41:24
         40:54         41:00         41:06         41:12         41:18
File:T980156  #1-563 Acq:6-JAH-98 18:23:23 EI+ Voltage SIS 70T Noise:465
471.7750 F:4  BSU3(256,30,-3.0)  PXD(7,5,3, 0. 05\r1860. 0,1. 00\,T, T) Exp-.XDBSOS
TRIANGLE LABS Text:TLI#44376 117-120/216/217/218           INJ-. TIKE '   18:26
1003,           A1.43E7
                                                                                           41:30
       O.OEO
          Time
         40:54         41:00         41:06         41:12         41:18
Tlle:T9801S6 #1-563 Acq : 6 -J2UT- 9 8  18:23:23  EH- Voltage SIS 70T
430.9729 T:4 ExptSDBSOS
TRIANGLE LASS  Text sTLI 14437 6 117-120/216/217/218           IKT.  TIME -
                             41:03
                                                                             41:24


                                                                           18:26
 00:
 eo:
                                                                                                 2.6E6

                                                                                                .2.1E6

                                                                                                .1. 5E6

                                                                                                .1. OE6

                                                                                                .5.1E5
i—  [-O.OEO
 41:30    Tiae
                                                                                                -5.2E6

                                                                                                .4.2E6

                                                                                                .3.1E6

                                                                                                -2.1E6

                                                                                                11.0X6
        40:54
                      41:00
                                    41:06
                                                               41:13
                                                                             4l':24
       O.OEO
          Time
                                                                                            23'

-------
Cnarral   !  -28,3732     Peak top
Height  3,59 volts  Span   288 ppa
                        ft:
Systaj FILfi
Data   file
Resolution                  18888
Group nuaber                    I
lonlzatien aode               El*
Switching                 YQLTBGE
Ref, sasses  292.3825,   418,3768
fl   293     J   331      S  388
            K   332
            L   334
            I   348
            H   342
            0   352
            P   354
8   384
C   388
0   316
E   318
F   328
G   322
            T   378
            II   376
            V   418
K   328
    331
0   356
R   358
Ref, MSS   416,3768     Peak top
Height   ,36 volts  Span   298 ppa
                                                             240

-------
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI + Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =
100%                                        A2.49E8
    25:54      26100      26:06     , 26:12      26:18
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI»44376 117-120/216/217/218           INJ. TIME =
100%.                                        A3.18E8
  0.
                                                    18:26  File  Text:TLI#44376 117»
                                                                          _4.2E7

                                                                          _3.3E7

                                                                          _2.5E7

                                                                          Ll.7E7

                                                                          L8.4E6

                                                                          LO.OEO
                                                                              Time
                                          I "i—|	1	i-
                                            26:30
                                            26:36
    25:54      26:00      26:06      26:12      26:18      26:24
File:T980156 #1-810 Acq:6-JAN-98 18:23 : 23 EI + Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =
lOOi                                26jl2
                                                    18:26 File Text:TLI#44376 117»
                                                                           5.3E7

                                                                          L4.2E7

                                                                          L3.2E7

                                                                          L2.1E7

                                                                          L1.1E7

                                                                          LO.OEO
                                                                              Time
                                            26:30
                                            26:36
 80^

 60 j

 40J
rOo.
                                                       26:22
    25:54
26:00
                                                    18:26 File Text:TLI#44376 117»
                                                                           3.7E6

                                                                          L3.0E6

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                                                                          L1.5E6

                                                                          L7.5E5
26:06
26:12
26:18
26:24
26:30
26:36
LO.OEO
    Time

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File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI + Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI»44376 117-120/216/217/218           INJ. TIME =
100%
                                                                  18:26 File
 80j
 60 j
 40J
 20 j
  0.
                                  A8.46E6

                                                   Text : TLI844376 117»
                                                              _4 .7E6
                                                              L3.7E6
                                                              L2.8E6
                                                              L1.9E6
                                                              L9.3E5
                                                              LO.OEO
                                                                  Time
                                                                                26:28
        26:20    26121    26:22    26:23    26:24     26:25     26:26    26:27
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI + Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =   18:26 File Text:TLI#44376  117»
lOOi
                                                                       26:27
                                                                                26:28
                                                                  Time
         26:20    26:21    26:22    26:23    26:24     26:25     26:26
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =   18:26 File Text:TLI#44376  117»
100S,
         26:20
                  26:21
26:22
                                   26:23
26:24
26:25
26:26
26:27
26:28
.O.OEO
   Time

-------
'ile:T900156 #1-396 Acq:6-JAN-98 18:23:23 El-f Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =   18
100%
                                                                     26 File Text:TLI#44376 117*
                                                                                        _2.4E7
           32:24            32:30            32:36            32:42
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EH- Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =   18
                                                                               32:48
                                                                                        JiO.OEO
                                                                                             Time
100%,
 80J
 60j
 40J
 20 j
  0
                                                       32:39
        32:23
                                                                     26 File Text:TLI#44376  117»
                                                                                          4.7E4
                                                                                         L3.8E4
                                                                                         L2.8E4
                                                                                         L1.9E4
                                                                                         L9.4E3
                                                                               32:48
                                                                                         lO.OEO
                                                                                             Time
           32:24            32:30            32:36            32:42
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EH- Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME -   18:26 File Text:TLI#44376  117»
100%                                                                 32:44
           32:24
                            32:30
                                             32:36
                                                               32:42
32:48
LO.OEO
    Time
 CO

-------
 ile:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
 ample Text:TLI#44376 117-120/216/217/218           INJ.  TIME =
100%             32:54
                                18:26 File Text:TLI#44376 117»
                                                      _6.6E7
                32:54             33:00             33:06
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =   18
                                     33:01
                                    33:12
                                                                                             Time
                                   26 File Text:TLI#44376  117»
                                                        2.6E6

                                                       L2.0E6

                                                       L1.5E6

                                                       L1.0E6

                                                       L5.1E5
                32:54              33:00              33:06
File:T980156 Sl-396 Acq:6-JAN-98'18:23:23 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376  117-120/216/217/218           INJ.  TIME =   18
lOOi                                                         33;09

 80J

 60 j

 401
                                                                      33:12
                                                       LO.OEO
                                                           Time
   ol
                    32:55
                32154
33:00
                                                    33:06
26 File Text:TLI#44376 117»
                    8.9E4
                    L7.1E4
                    L5.4E4
                    LS.6E4

                    Ll.8E4
          —-—-—~l n.OEO
                       Time
33:12
  ro

-------
Pile:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
100%                                       33:31
       33:18            33:24           33:30            33:36
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
100%                                      33i31
      33:18            33:24            33:30            33:36
File:T980156 #1-396 Acq:6-JAN-98"18:23:23 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
lOOi                         33;26
 80 j
 601
 40J
 20 j
  OJ
       33:18
                                           18:26 File Text :TLI#44376 117»
                                                                                         _5.2E7
                                                                                         _3.9E7
                                                                                         L2.6E7
                                                                                         L1.3E7
                                                 33:42
                                                                                         lO.OEO
                                                                                             Time
                                           18:26 File Text:TLI#44376  117»
                                                                                         .2.OE6
                                                                                         11.5E6
                                                                                         L9.8E5
                                                                                         Z-4.9E5
                                                                        33:42
                                                                  LO.OEO
                                                                      Time
                                                                  18:26 File Text:TLI#44376  117»
33:24
                                       33:30
33:36
33:42
L1.1E6
18.1E5
L5.4E5
L2.7E5
lO.OEO
    Time

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File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
                                                    INJ.  TIME =
                                                   34:24
Sample Text:TLI#44376 117-120/216/217/218
lOOi
 80J
 60 j
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 20 j
  OJ
                 34:12            34:18             34:24
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =
100%                                34
 80 j
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 40J
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  OJ
                 34:12            34:18             34:24
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME =
100%                      34jl5
  80J
  60J
  40J
  20 j
   0.
18:26 File Text : TLI#44376  117»
                                                                                         _1.5E7
                                                                                         _1.2E7
                                                                                         _7.7E6
                                                                                         -3.9E6
                                                                      34 :30
                       lO.OEO
                           Time
                                                                  18:26 File Text :TLI#44376
                                                                                          2.0E6
                                                                                         L1.6E6
                                                                                         L1.2E6
                                                                                         L7.9E5
    34:30
lO.OEO
    Time
18:26 File Text:TLI#44376  117»
                        8.4E5
                       L6.7E5
                       L5.1E5
                       L3.4E5
                       Ll.7E5
                 34:12'
                                   34:18
—T°—r
 34 :24
    34:30
LO.OEO
    Time

-------
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
 ample Text:TLI#44376 117-120/216/217/218           INJ.  TIME
100S,
                                                18:26 File Text : TLI#44376 117»
                                                                                         L5.2E7
                                                                                         L3.9E7
                                                                                         L2.6E7
                                                                                         Ll.3E7
   33:12          33:18          33:24          33:30
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
100%
 80J
 60 j
 40J
 20 j
                                             33:36
                                             33:42
                                        LO.OEO
                                            Time
  OJ
                                                18:26 File Text:TLI#44376 117»
                                                                       6.5E7
                                                                       L5.2E7
                                                                       L3.9E7
                                                                       L2.6E7
                                                                       Ll.3E7
   33:12          33:18          33:24          33i30
File:T980156 #1-396 Acq : 6- JAN-98' 18 : 23 : 23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text :TLI#44376 117-120/216/217/218           INJ. TIME
100%                                              33:31
 80 j
 60j
 20 j
  0
                                             33:36
                                             33:42
                                        LO.OEO
                                            Time
   33:12
33:18
                                                18:26 File Text :TLI#44376 117»
                                                                      .-2.5E6
                                                                      L2.0E6
                                                                       L9.8E5
                                                                       L4.9E5
33:24
33:30
33:36
33:42
LO.OEO
    Time
   o

-------
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
100%,                                           A7.Q5E7
60 j
40J
20 j
     34:06          34:12          34:18          34:24
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
lOOi                                           A5.62E7
 80 j
40J
20 J
 OJ
     34:06          34:12          34:18          34:24
File:T980156 #1-396 Acq:6-JAN-98' 18:23:23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218           INJ. TIME
lOOi                               34 U8
 80J
 60 j
20J
                                                                 18:26 File Text :TLI#44376  117»
                                                                                         _1.5E7
                                                                                         _1.2E7
                                                                                         L7.7E6
                                                                                         E-3.9E6
                                                               34 :30
                                                                                34:36
                                                       LO.OEO
                                                          Time
                                                                   18:26  File Text:TLI#44376 117»
                                                                                          1.5E7
                                                                                         Ll.2E7
                                                                                         L9.3E6
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                                                                                         L3.1E6
                                                               34 :30
                                                                                34:36
                                                      LO.OEO
                                                          Time
 Oj
    34:06
                    34:12
                                                                   18:26  File  Text:TLI#44376 117»
                                                                                         _2.0E6
                                                                                         Z.1.6E6
                                                                                         Ll.2E6
                                                                                         17.9E5
                                                                                         L4.0E5
34:18
                                                 34 :24
34 : 30
34 :36
LO.OEO
    Time
 ro
 ^>
 CO

-------
TLI Project:     44376
Client Sample:   117-120/216/217/218
Method 23 TCDD/TCDF Analysis (DB-225)
                   Analysis File:   X980087
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:


2,3,7,8-TCDF

13C12-2,3,7,8-TCDF
Recovery Standard
mvwmfmvfmmmrtsixtfsf
"C12-1,2,3,4-TCDD
Gulp Aluminum
M23TRAIN
194-59-4A-D/
1.000
n/a
DB-225


62.
r-Si-iSiSvivSvS^
^illlllillPIIIPllsSBsi
4.

I
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst


8'
S>::S:K*:*:W:*:::::S^
|n^;iP;:li»iSI;i|Si!lp
^•>£x>::::>>:'£::::::::::!^
3 109


12/17/97
12/29/97
01/07/98
n/a
X980083
KAS



:::::-:.:;:::-:;^;:-:-:-:-x-:-:.:-:-:-X;:::-:-:-:-:-:-:-:-:-:-:->:;:-:-:-:->:-:-:-:.:.:.
40%- 130%
iii«Plllil;««

Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:


0.77
i^sMSSSSSSiiSiSSiSSS:;
0.78

0.77
SPC2NF04
XF24087
X980080
: n/a
n/a
n/a

s:i^^is!¥K4SSSK»ti^s*S®:
;::;wPi^s;?5;SS*:;lwi|!*sss
®BiffliS^^^3ffi^S4SS?OSS:!:?S;
21:29 E_
SSSSS:SSS'S:S8S-SSg!S!S>SHS«a
21:28 	
S^^^liyS^SSajiiSiaSSSS:;::::;:
liillliliiillagsjll
20:28 	
                    Data Reviewer.
                   01/11/98
                                       Page 1 of 1
                                C2NFJ>SR tun, LARS S.lOOa
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                            Printed: 13:34 01/11/98
                                   24S

-------
                        Initial
                                 	Dace...
  Data Review By:
                                              Calculated Noise Area:
                                                                     2.00
  The Total Area for each peak with an ion abundance  ratio outside
  ratio limits h«q been recalculated according to  method requirements.
  Page No.
  01/11/98
Listing of X980087B.dbf
Hatched CC Peaks / Ratio / Ret. Time
  Compound/
  M_2	 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP 0
304-306 DC ML 0:00 RO
17:06
18:05
18:12
18:20
18:30
18:47
18:56
19:04
19:13
19:24
19:44
20:10
20:16
20:25
20:37
20:49
21:00
21:15
21:22
21:29
21:41
21:55
22:02
22:12
22:42
23:19
304-306 26 Peaks
13C12-TCDF 0.
316-318 DC NL 0:00 RO
DC WL 18:50 RO
DC WL 19:13 RO
DC WL 19:44 RO
DC WL 20:10
DC WL 20:25
21:12 RO
21:20 RO
21:28
22:02 RO
316-318 4 Peaks
.65-0.89
0.93
0.79
0.80
0.75
0.77
0.78
0.78
0.78
0.86
0.75
0.77
0.78
0.80
0.67
0.78
0.78
0.77
0.77
0.66
0.77
0.77
0.78
0.77
0.78
0.76
0.77
0.82
2,
,65-0.89
1.15
0.55
1.11
1.46
0.86
0.85
0.62
1.01
. 0.78
1.19

0.790-1.095

58
49
54
112
49
44
104
54
182
84
327
71
16
109
80
15
113
1
122
63
133
129
102

56
8
,150
508.75
,378.10
,452.80
,172.70
,666.90
,086.50
,818.70
,940.60
.972.50
,254.40
.384.40
,099.00
,047.70
,253.08
,634.70
,041.50
,492.79
,805.00
,170.76
,176.30
,186.20
,985.30
,121.90
,469.40
302.26
,331.60
,455.17
,700.26

25
22
23
49
21
19
45
25
78
36
142
31
6
47
35
6
51

53
27
58
56
44

24
3


,732
,029
,299
,089
,530
,633
,905
,426
,126
,708
,902
.577
,501
,382
,044
,742
,360
467
,235
,570
.567
,156
,833
130
,552
.798


.40
.50
.30
.10
.70
.60
.60
.50
.40
.70
.00
.20
.92
.40
.70
.94
.70
.56
.70
.70
.50
.00
.70
.90
.30
.51


32,645
27,423
30,873
63,577
27,555
25,185
59,035
29,546
104.128
47,675
184,197
39,470
9.751
61,752
44,996
8,749
66,944
703
68,940
35,615
75,417
72,965
57,635
171
31,779
4,656


.70
.30
.40
.80
.80
.10
.00
.00
.00
.70
.00
.50
.16
.30
.30
.85
.30
.20
.60
.50
.30
.90
.70
.36
.30
.66

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1

.000
.797
.842
.348
.854
.362
.875
.882
.888
.895
.904
.919
.939
.944
.951
.960
.970
.978
.990
.995
.001 2378-TCDF AN
.010
.021
.026
.034
.057
.086


E
B
E
E
E
E
E
E
E
E
E
E

E
E

E

E
E
E
E
E

E


0.953-1.047








4

4
29.22
23.49
30.32
16.55
51.38
98.43
24.16
11.40
,162.98
19.31
,217.85








1,








10.
6.
,826.
13.







51
,48
.82
.00







16,
6
2,336
10.





•

.97
.44
.16
.91

0,
0
0,
0.
0.
0.
0.
0.
1.
1.

.000
.877
.895
.919
,939
951
983
,994
000 13C12-2378-TCDP ISO
026












Triangle Laboratories, Inc.®  Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 13:19 01/11/98
                                                                           250

-------
  Page No.
  01/11/98
Listing of I380087B.db£
Matched OC Peaks  /  Ratio  / Rat. Tim*
  Compound/
  M_Z.... QC.Log Omit Why . .RT. OK Ratio Total. Area... Area.Peak.l. . Area. Peak. 2. .  Rel.RT Compound.Nam«..  10..  Flags.
  13C12-TCDD
  332-334
  332-334

DC







OC


NL 0:00
20:13
20:28
21:08
21:17
21:21
21:25
21:37
WH 22:39
7 Peaks
0.
RO



RO
RO
RO
RO


65-0.89
2.04
0.80
0.77
0.77
1.33
1.55
0.35
3.58
0.80

                                       Above: TCDP / TCDD Follows
                                               25.82
                                            3,060.07
                                            2,730.06
                                               37.53
                                               13.06
                                               24.07
                                               12.55
                                                8.64
                                                8.51
                                            5,905.98
0.901-1.099

1,
1.







355.
199.
16.
9.
21.
5.
17.


85
67
38
80
14
46
49


1,704
1,350
21
7
13
IS
4


.22
.39
.15
.38
.60
.66
.88

0
1
1
1
1
1
1
1
1
.000
.000 i:
.012 1:
.045
.053
.056
.059
.069
.120
                                                         000  13C12-2378-TCOO IS1
                                                         012  13C12-1234-TCDO RSI
  Column Description	  'Why Code Description	  QC Log Desc.
  M_Z   -Nominal Ion Hassles)
  ..RT. -Retention Time1 (nm:ss)
  Rat.l -Ratio of M/M+2  Ions
  OK    -RO=Ratio Outside  Limits
  Rel.RT-Relative Retention Time
     End of Report
      WL-Below Retention Time Window
      WH-Above Retention Time Window
      SN-Below Signal to Noise Level
      
-------
flJ.eiI3BOOa7 91-883 Acqi7-JAN-13So  15:47:27 OC ST* VOAtmge SIK AUtOSfoa BOiM9jll33f46
303.9016 BSUB(23e,30,-3.0) PKDfS,3, 1,0.10*,534584.0, O.OO*.P,y) g3tp:XCOSF_TT
Staple Tm*t:TLIt44376 1117-130/316/317/318 Filt TtJCti HECMOEJf LABS
100*                                  Al  3X9
 90.

 60.

 40.

 30.
            A7.81S8
A4.91S8
                                                          A3.46S8
                                                                                A
  17:00         18x0(3        15; 00        20100        21:00        33tOO        23iOO
Fil»iZ980087 91-883 Acqi 7-JAB-1998  19t47>37 OC ZZ> Voltag* SZB AuCo^»«c Solaet 143714
305.8987 BSUB(3S6,30,-3.0) fXD(5,3, 1, 0.10*, 57 4856.0, 0.00\f?,f) BptXCOBP TT
Saoflf T»xtiTLia44376 1117-130/316/317/318  Film T«xC: IKUmU LABS
100*                                  Al. 4S9
  17:00         10:00        15:00        20:00        21:00        22:00        23:00
fil»iX980087 #1-883 Acq: 7-JAS-1998  19t47t37 OC ST* Voltage SIR AUtoSpuc HOia»s9519
315.9419 BSUS(2Sf,30,-3.0) PKD(5,3,1.0.10*,38076.0,0.00*,F,P) SxptICOSP_TT
Saapla ToxttTLX#4437S 1117-130/316/217/318  Pile Toxti TXIANOLE LABS
10091                                                         A1.$3B7

 80.

 60.

 40.

 30.
   17:00         18:00        15:00        20:00         21:00        22:00        22:00
Pile,1980087 #1-883 Acqi  7-JAK-1998  15:47:27 OC BI+ Voltage SIR AutoSpec Holae,8253
317.9389 BSUB(256,30,-3.0) PXD(5,3, 1, 0.10*, 33012.0. 0. 00\,F,F) Sxp:XCCWP_W
Sample Tejct:TLI#44376 1117-130/216/217/218  File Text: TRIASOLS LABS
100H                                                         A2.34E7
  80.

  60.

  40.

  30.
  17:00         18:00        15:00        20:00         21:00        22:00
Pll»tZS80087 91-883 Acqi  7-JAN-1998  15:47:27 OC SI+ Voltage SIR AUtoSpec
375.8364 S*piXCOHP_TT
Sample T*xtiTLI#44376 1117-130/216/317/318  Film Tut: TRlAHOLB LABS
100*                                                       21,14
 80.

 SO.

 40.

 30.

  0.
                                                                                  33:00
18tl7
              19:17
-2.3S8


.1.828

'.1.4S8


-9.0B7

L.4.5S7
                                                                              O.OSO
                                                                                 Time
  17:00
                18:00
                             19:00
                                          20(00
                                                        31100
                                                                     33100
                                                                                  33:00
                                                                                                 O.OEO
                                                                                                    Time
.4.4E6


.3.5E6


.2.7S6


.1.8E6


,8.9E5


.O.OEO
    Time



.5.7E6


.4.6S6


.3.4E6


.3.3E6


.1.1S6


 O.OSO
    Time



 8.2ES


 6.5E5

 4.555


 3.3E5


 1.625


 O.OSO
    Time
                                                                                                 25!

-------
7fIeiXSaOOa7 01-BB3 icqi 7-001-1998 IStWt'J) 
-------
Pile 1 19 80087 01-883 Acq: 7-JAS-1998 15:47:27 OC 5J+ Voltage 313. AutoSpec
303.9016 SxptKOSP TT


Saaple Tmxt:TLX044376 1117-120/216/217/23.8 Pile Tmxt: TRIABBL8 LABS
1003
80.

60.
40.
20.
0
15

15:13
18:20 A
4la'5*
AA/lrUll
17:00 ' 18:00 15:00
44


\ *°t
\ 20tlO\
Ul
20:00
-2.358


" "if0 A "*"i
, \ U h
ywiM T .
.1.858

.1.458
.5.057
.4.557
O.OSO
21:00 22:00 23:00 Time
PilmiX980087 01-883 Acq: 7-J3UT-1558 15:47:27 OC 51+ VolCag* SIR AutoSpec
315.9419 SxpiXCOSP_TT


Saaple TmxttTLI044376 1117-120/216/217/218 film Tmxtt TRIAHOLS LABS
100S
80J
60:.
401
20J







15:13

17;00 ' ' ' 18:00 ' ' ' 15:00







20:00
21:28 4.55*




/ 1
^ ~J \-
.3.6S6
.2.7S6
.1.8S6
.5.055


21:00 ' 22:00 23:00 ' ' ' y^e
PilmiX980087 01-883 Acq: 7-JAH-1998 19 1 47: 27 OC 51+ Voltage SIR AutoSpec
319.8965 SxptXCOSP TT


Saaple Tmxt:TLI044376 1117-120/216/217/218 Pile Tmxt: TRXASOLB LABS
100*
80:
60:
40:

20.
0:
17:5*

"i"
1
15:31
H 11 AAA
17:00 ' 18:00 ' 15:00




-1.458



30»3«
A.y
20:00
\ r I1/!7
i.1.158
.S.1S7
.5.457

.2.757
O.OEO
21:00 ' ' 22:00 23:00 ' ' Tlam
PlleiX980087 01-883 Acq: 7-JAN-1998 15:47:27 OC 51+ Voltage SIR AutoSpec
331.9368 ExptXCOKP TT


Saaple Tmxt:TLI044376 1117-120/216/217/218 Pile Tmxt: TRIAMLS LABS
looV
80j
60:
40:
20J
0'





17:47 18:45
17:00 ' 18:00 ' 15:00
20:13




. / u
20:00
-3.7E6




21:05 21:37 22:03 22:35 23:07
.3.0E6
.2.2E6
-1.5E6
-7.5E5
• n nvn
21:00 ' ' ' 22:00 ' ' 23^00 ' ' ' Time
File, 1980087 01-883 Acq: 7-JAN-1998 15:47:27 OC 5T+ Voltage SIR AutoSpec
292.9825 Sxp:XCOSP TT


Saaple TmxttTLI044376 1117-120/216/217/218 Pile Tmxtt TRIASOLS LABS
100*
801
601
40:
201
oj
17:32 17:58 18:5315:17
20:20 30:51 31, 3* 23:17 23T-12 5.858

17:00 18:00 15:00
20:00
.4.6EB
.3.558
.2.358
.1.258
O.OSO
21:00 ' ' 22:00 ' 23:00 ' Tlam
Pile, 1980087 01-883 Acqi 7 -JAN- 19 9 3 15:47:27 OC 5X+ Voltage SIR AutoSpec
330.9792 SxpiXCOSP_TT


Saaple Tmxt:TLZ044376 1117-120/216/217/218 Pile Tmxtt TRIASOLS LABS
100*
80.
60:
40:
20.
OJ
18:30 18:55 15:37 20,20 31, 3O 11,n* 23:0+23:31 r6.4E8





17:00 ' ' 18:00 15:00





20:00





.5.158
.3.558
.2.C58
.1.358
0.050
21:00 22:00 23:00 Time
254

-------
Peak Locate Examination: 7-JAN-1998:19:43 File:X980087
     Experiment:XCONF_TT Function:! Reference:PFK
10
\n

-------
TLI Project:      44376
Client Sample:   125-128
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   T980151
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-6A-6D Date Extracted: 12/29/97
Date Analyzed: 01706/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6.7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1.2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2.3,4,7,8,9-HpCDF
1,2,3,4,6,7,8.9-OCDF
Totais
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ns) Dt EtfPC
0.86
6.3
6.0
12.0
18.8
40.3
34.5
-O^ 7 "^ (l^ Q /}~
19.1 )/i57^y
35.3
64.6
27.0
34.4
1.5
77.6
9.1
17.4
Amt (ng) Number DL EMPC
280 12
260 10 266
210 7
83.1 2
-&:>7Uc 16
-teS-r&o 16
270 11 276
116 V 4
Ratio
0.75
1.54
1.21
1.20
1.22
1.02
0.82
0.89
1.49
1.48
1.25
1.26
1.27
1.32
1.04
1.06
0.91









RT
26:20
30:31
33:37
33:42
34:00
37:05
40:56
25:42
29:31
30:11
32:53
33:00
33:30
34:18
36:00
37:37
41:09









Ffegs




PR_
E_

SE_
	

E 	


PR!
E_

—
Flags
E_
E_
E_
E_
SQE
SE_
E_
E_
                                       Page 1 of 2
                        X237.PSR vZ.OI. LARS 6.11
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 14:30 01/15/98
                                                                         256

-------
,- .-.> f
/Eastern!
TLI Project: 44376
Client Sample: 125-128
Internal Standards
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
l3C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDb
13Cp-l,2,3,4,6,7,8-HpCbF
l3C,2-l,2,3,4,6,7,8-HpCDD
I3C|2-1,2.3,4,6.7.8.9-OCDD
Surrogate Standards {Type A)
37CL-2,3.7,8-TCDD
13C,:-2.3,4,7,8-PeCDF
13Cr-l,2.3.4,7,8-HxCDF'
13C,:-l,2,3,4,7,8-HxCDD
I3C,2-l,2,3,4J,8,9-HpCl3F
I
k
' Alternate Standards^Type A)
3Cp-l,2.3,7,8,9-HxCDF
'3Ci:-2,3,4.6,7,8-HxCDF
Recovery Standards
13C,:-1,2,3,4-TCDD
13Ci:-l,2,3,7,8,9-HxCDD
Amt (ng)
1.7
1.9
2.1
2.3
1.9
2.1
2.2
2.8
5.8
Amt: (ng)
3.7
3.5
4.1
4.3.
4.0
Amt, (ng)
2.0
1.8


iil£^fc4**i^
•^f^-XXv^J. 	 ^ *
\ss>v<. f^ : Jfc
"'"%X
: ^
*;« -*" ,
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980158
, % Recovery
41.3
47.3
52.0
56.6
47.7
53.5
55.5
69.5
72.3
% Recovery
92.1
86.8
103
107
99.5
% Recovery
49.9
45.8


QC Limits
40%- 130%
40%- 130%
40%-130%
40%-130%
40%- 130%
40%- 130%
25%-130%
25%- 130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%-140%
70%- 140%
QC Limits
40%-130%
40%-130%


Ratio
0.77
0.78
1.49
1.45
0.53
1.20
0.47
1.02
0.95
Ratfo
1.55
0.52
1.20
0.45
Ratio
0.51
0.53
Ratio
0.80
1.19
RT
25:40
26:21
29:30
30:30
32:59
33:41
35:59
37:04
40:54
RT
26:21
30:10
32:53
33:36
37:36
RT
34:18
33:30
RT
26:10
34:01
Flags
Q_
Flags
—
Flags
—
Flags
—
                           Data Reviewer
01/15/98
                                                   Page 2 of 2
                 X237.PSR r2.OI.LARS «.10.0So
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Printed: 14:30 01/15/98

-------
                        Initial
                                   • • -Data. .
  Data Review By:
                                              Calculated Noise Area:   2.00
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
  Page No.
  01/15/98
Listing  of T980158B.dbf
Matched  GC Peaks / Ratio /  Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK  Ratio Total.Area...  Area.Peak.1..  Area.Peak. 2. .  Rel.RT Compound.Name. .  ID.. Flags.
TCDF
304-306

















304-306
13C12-TCDF
316-313







316-318

DC NL 0
22
23
23
23
24
24
24
24
25
25
25
25
26
26
26
27:
DC WH 27:
0
:00 RO
:39
:08
:21
:43
:02
:24
:40.
:53
:05
:17
:30
:42
:-05
:13
:32
:21
:34 RO
.65-0.39
0:99
0.81
0.83
0.30
0.31
0.81
0.31
0.30
0.31
0.32
0.80 •
0.30
0.89
0.30
0.31
0.33
0.31
0.90
16 Peaks

DC NL 0':
DC WL 23:
DC WL 23:
DC WL 24:
24:
25:
26:
26:
- 0.
;00 RO
:04 RO
:30 RO
:04 RO
40 RO
40
05 RO
18 RO
.65-0.39
1.04
4.99
1.94
1.67
2.99
0.77
1.71
1.84
4 Peaks
0.878-1.073

14
13
15
56
35
37
34
40
27
13
14
55
15
10
2
1

387
8.97
,642.18
,402.35
,740.63
,290.40
,494.50
,309.10
,036.90
,230.00
,401.00
,597.35
,126.05
.981.50
,084.16
,120.07
,157.12
,503.54
493.52
,116.35

6,532
6.092
7,016
25,123
15,871
16.651
15,086
18,020
12,347
6,030
6,299
26,393
6,706
4,515
977
671



.63
.42
.94
.00
.40
.00
.40
.40
.40
.46
.90
.30
.62
.96
.23
.97



8,109
7.309
8,723
31,167
19,623
20,653
18,950
22,209
15,053
7,566
7,826
29.588
8,377
5,604.
1,179.
831.



.55
.93
.69
.40
.10
.10
.50
.60
.60
.89
.15
.20
.54
.11
39
.57


0.000
0.382
0.901
0.910
0.924
0.936
0.951
0.961
0.969
0.977
0.985
0.994
1.001 2373-TCDF AN
1.016
1.025
1.034
1.066
1.074


QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
SE
QE
QE
Q
Q


0.961-1.039





1,


1,
»K~,«
TCDD
320-322






M
AN

DC NL 0:
23:
24:
24:
25:
25:
25:
26:
26:
0.
00 RO
55
17
34
13
29
51
15
20
65-0.39
1.27
0.82
0.78
0.77
0.78
0.78
0.78
0.79
0.75

50,
30,
9,
20,
11,
7,
18,

8.11
12.32
15.66
29.36
12.46
,725.13
11.36
11.06
760.06
TCDF / TC

5.06
108.60
946.50
492.08
710.39
734.90
099.05
390.00
470.00




21.
749.
10.
11.





04
07
97
49





7.
976.
6.
6.





04
11
42
25

0.000
0.399
0.916
0.938
0.961
1.000 13C12-2378-TCDF ISO
1.015
1.025






Q



•


22,619.
13,575.
4.138.
9,084.
5,145.
3,113.
8,090.
201.

10
30
55
09
53-
46
00
00
,
27,489.
17,370.
5,353.
11,626.
6,589.
3,980.
10.300.
269.
0.903-1.045

50
70
53
30
37
59
00
00
0.000
0.908
0.922
0.932
0.957
0.967
0.981
0.996
0.999 2378-TCDD AN

E
E •
E
E
E
E
E

Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 14:2701/15/98
                                                                           258

-------
  Page No.
  01/15/98
Listing  of T980158B.dbf
Matched  GC Peaks / Ratio /  Ret. Time
  Compound/
 .M_2.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.
26:31
26:40
26:53
27:19
320-322 12 Peaks
37C1-TCDD
328 DC NL 0:00
DC WL ' 23:55
DC WL 24:09
DC WL 24:17
24:34
25:01
25:12
25:28
25:41
. ' 25:51
26:21
' 26:43
1 27:33
323 9 Peaks
13C12-TCDD
332-334 DC NL 0:00
DC WL . 23:55
DC SN 24:34
' 26:10
26:21
• 26:40
; 27:02
J32-334 - 4 Peaks
PeCDF
340-342 DC NL ' 0:00
27:34
' ' 28:11
28:32.
' 28:40
28:50
! 29:08
29:14
29:25
29:31
, 29:4°
29:47
: 30:11
30:20
, 30:38
30:51
31:08
0.77
0.78
0.74
0.79
0.65-0.39
RO 2.05
RO 1.38
RO 2
0
0
RO 0
RO 1
.19
.30
.78
.58
.22
1,881.20
984.24
356.28
334.48
152,507.72
1.50
278.18
274.45
274.32
55.51
2,462.00
107.11
63.34
9.27
37.08
1,480.87
2,212.36
3.36
6,431.90
3.63
5.31

2,
1.


4,
1.32
RO 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
-1.78
.10
.49
.40
.43
.39
.50
.49
.50
.49
.49
.49
.50
.43
.48
.63
.53
.53

25,

9,
47,
11.
2i'.
19.
9,
9,
7,
11,
16,
16,
1,

1,
1.79
705.24
598.42
25.70
5.15
334.51
TCDD / Pf

5.10
017.40
75.30
084.21
111.70
203.56
518.73
497.95
463.01
114.32
611.16
855.68
837.95
360.27
844.67
461.73
781.13
2
1
2

1.



aPHF ?
-^ur s

14,

5.
27,
6,
12.
11.
5,
5,
4,
7,
10,
9,
1.

1,
818.34
430.61
150.95
147.91
55.51
,462.00
107.11
63.34
9.27
37.08
,480.87
.212.36
3.36

202.91
701.37
11.18
3.55



964.60
43.39
413.30
422.50
713.22
880.70
693.30
667.41
461.14
550.34
112.03
052.70
762.98
143.79
283.11
078.05
1

1.






10,

3,
19,
4,
3.
7.
3.
3,
3.
4,
6.
6,



,062.36 1.006
553.63 1.012
205.33 1.020
186.57 1.037
0.924-1.076
0.000
0.908
0.917
0.922
0.932
0.949
0.956
0.966
0.975
0.981
1.000 37C1-TCDD SUR1
1.014
1.049
0.924-1.076
0.000
0.903

502.33
897.05
19.40
2.91

Q

052.80
31.41
665.41
689.20
490.34
638.03
804.15
795.60
553.18
060.32
743.65
735.25
597.29
700.88
178.62
703.08
0
0
1
1
1

931
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1.
1.
.932
.993 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.012
.026

-1.063
.000
.934
.955
.967
.972
.977
.938
.991
.997
.001 12378-PeCDF AN
.006
.010
.023 23478-PeCDF AN
.028
.038
.046
.055








E


SE

E
E









Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 14:2701/15/98
                                                                             ,C

-------
  Page Mo.
  01/15/98
Listing  of T980158B.dbf
Matched  OC Peaks /  Ratio / Ret.  Time
  Compound/
  M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Arsa.Peak.2.. Rel.RT Compound.Nama..  ID.. Flags.
  340-342
                     16  Peaks
                                        208,838.77
13C12-PeCDF
352-354














352-354
PeCDD
356-358











356-353
13C12-PeCDD
368-370








368-370
DC NL 0
27
28
28
28
28
28
29
29
29
29
29
30
30
31
1
:00 RO
:33 RO
:15 RO
:23 RO
:31 RO
:40 RO
:51 RO
:01
:07
:14
:30
:46
:10
:20 .RO
:03 RO
.32-1.78
0.95
1.
0.
2.
2.
1.
0.
1.
1.
1.
1.
1.
1.
2.
0.
14 Peaks

DC NL 0:
28:
29:
29:
29:
29:
30:
30:
30:
30:
30:
30:
1.
:00 RO
46
14
23
36
47
02
13
20 RO
31
33
58
32-
0.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
12
38
10
67
31
95
62
70 .
37
49
34
55
11
64

1.78
30
42
52
56
53
54
56
55
92
54
52
56
11 Peaks

DC NL 0:
23:
29:
29:
30:
30:
31:
DC SN 31:
31':
1.
00 RO
46 RO
28 RO
47 RO
30
38 RO
00 RO
25 RO
31 RO
32-
0.
3.
2.
2.
1.
1.
0.
0.
0.
1.73
20
00
25
34
45
17
69
97
96
7 Peaks









1,

1,


3,


30,
2,
22,
2,
15,
5,
7,
2,
2,
1,
1,
93,
3.32
61.69
17.01
8.03
9.92
54.52
22.30
6.99
24.04
22.32
799.53
68.74
551.21
13.52
6.53
667.35
iftf^nP / PC
V^LJC / Ff
1.78
596.20
306.30
474.44
204.81
139.80
499.29
484.96
348.62
212.17
690.59
611.89
569.07
0.364-1.136
0.000
37.50
10'
6
10
38
13
4
15
13
1,076
39-
943
11
3

.34
.62
.37
.63
.36
.32
.14
.20
..70
.34
.73
.20
.97

33
27
3
3
21
14
.58
.30
.15
.89
.38
.63
2.67
8
9
722
29
607.
5,
6.

.90
.62
.33
.40
.48
.30
.21

0.934
0.958
0.962
0.967
0.972
0.978
0.984
0.987
0.991
1.000 13C12-PeCDF 123 IS2
1.009
1.023 13C12-P6CDF 234 SUR2
1.028
1.053

0.939-1.022

17' ,.973.
U3;92.
U.,70'8.
I.,334.
S..1S9.
1,352.
4.,. 547.
1,427.
1,.34-1.
L..019.
983.


,.aa
65
,00
,.43'
27
,.07
,2S
59
.20
22
03


12,622.
913.
8,766.
870.
5,950.
2,147.
2,937.
1.556.
870.
671.
628.


40
65
44
38
53
22
70
60
97
37
36

0.000
0.943 . E
0.958
0.966 E
0.970
0.977 E
0.985
0.991
0.995
1.001 12373-PeCDD AN
1.004
1.015

0.869-1.131




1,




1,
1.45
19.56
15.56
9.32
086.71
100.91
7.68
1.65
4.98
245.22
ecnn / HV

23.
13.
9.
643.
61.
4.

3.
Cnp T»<1 T 1 n

03
73
00
.53.
34
67

03


7.
6.
3.
443.
52.
6.

3.


67
10
35
18
56
73

17

0.000
0.943
0. 966
0.977
1.000 13C12-PeCDD 123 IS3
1.004
1.016
1.030
1.033

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 14:27 01/15/98
                                                                   26C

-------
  Pago No.
  Ol/lS/93
Listing of T980158B.dbf
Matched GC Peaks /  Racio / Ret. Time
  Compound/
  M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. .  Rel.RT Compound.Name.. ID..  Flags.
'.1XCDF
374-376




X
X





MX
AN
M

374-376
13C12-HXCDF
334-336








,4-386
HxCDD
390-392







390-392
13C12 -HxCDD
402-404



402-404
1.05-1.43
DC NL 0:00
31:56
32:04
32:14
32:22
X 32:31
X . -32:44
32:53
33:00
33:07
33:18
33:30
X 34:14
34:18
34:23
DC WH 34:43
14 Peaks

DC NL 0:00
' 32:04
32:33
1 32:53
32:59
33:30
DC SN 33:39
\ 33:50
34:13
7 Peaks
i
DC NL 0:00
32:25
32:51
• I 33:04
33:15
33:37
33:42
. 34:00
7 Peaks
1
1
1
1
• 1
RO 1
RO 1
1
1
. 1
1
1
RO 1
1
1
1
.10
."25
.26
.23
.27
.28
.28
.25
.26
.27
.26
.27
.24
.32
.23
.29
25.39
13,317.36
28.940.30
1,807.53
2,837.59
1,688.05
247.49
26,104.20
12,264.65
2,343.51
3,905.04
12,572.83
539.00
497.00
1,960.00
283.60

7,687
16,117
1,013
1,587
948
138
14,493
6,335
1,309
2,174
7,022
298
283
1,100


.10
.70
.16
.90
.63
.94
.00
.32
.14
.34
.16
.00
.00
.00


6,130
12.322
794
1,249
739
108
11,611
5,429
1,034
1.730
5,550
241
214
860

0.964-1.049

.76
.60
.37
.69
.42
.55
.20
.33
.37
.20
.67
.00
.00
.00

0.000
0.963
0.972
0.977
0.981
0.986
0.992
0.997
1.001
1.004
1.010
1.016
1.038
1.040
1.042
1.055







123478-HxCDF AN
123678-HxCDF AN


234678-HXCDF AN

123789-HxCDF AN




E




E





PR


109.525.05
0.43
RO 1
RO 1
RO 2
0
0
0
RO 0
RO 2
0

1.05
1
1
1
1
1
1
1
1

-0.59
. 12
.86
.11
.52
. 53
.53
.35
.15
.51

-1.43
.37
.21
.22
.22
•23
.21
.20
.22

0.879-1.121
7.99
11.87
6.27
1.329.13
1,399.75
1.232.71
4.94
5.03
1,105.75
5.140.51
HxCDF / Hx

14.67
5,062.94
27,314.10
10.931.41
2,155.39
1,474.51
3,332.99
5.167.78
55,939.62

14
8
456
435
444

7.
374,

.59
.74
.95
.96
.11

.13
.73

7
4
872
913
833

3
731,

.86
.15
.13
.79
.60

.33
.02
0.000
0.972
0.989
0.997
1.000
1.016
1.020
1.026
1.040



13C12-HXCDF 473 SUR3
13C12-HXCDF 673 IS4
13C12-HXCDF 234 ALT2


13C12-HXCDF 739 ALT1












2,769.
15,273.
6,018.
1,187.
807.
1,817.
2,841.


65
30
13
98
37
39
90


2.293.
12,540.
4.913.
967.
666.
1,515.
2.325.

1.05-1.43
DC NL 0:00
33:36
33:41
34:01
3 Peaks
RO 0
1
1.
1.

.47
.20
.20
.19

6.56
964.47
1,109.16
2,078.80
4,152.43

525.
604.
1,130.


15
03
32


439.
505.
947.

0.953-1.015

29
30
28
91
64
60
33

0.000
0.962
0.975
0.982
0.987
0.998
1.000
1.009






123473-HxCDD AN
123673-HXCDD AN
123739-HXCDD AN



E
E



PR

0.970-1.030

32
13
98

0.000
0.998
1.000
1.010


13C12-HXCDD 478 SUR4
13C12-HXCDD 678 IS5
13C12-HXCDD 789 RS2






Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 14:2701/15/98
                                                                     261

-------
  Page No.
  01/15/98
Listing of  T980158B.dbf
Matched GC  Peaks  / Ratio / Ret.  Time
  Compound/
  M_2.... QC.Log  Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
  13C12-HpCDF
  418-420
 413-420
 HpCDD
 424-426
 424-426

 13C12-HpCDD
 436-438

 436-438
 OCDF
 442-444
 442-444
 OCDD
 453-460
 453-460
 13C12-OCDD
 470-472

DC




DC

NL 0
36
36
36
37
WH 38

:00
:00
:17
:26
:37
:13
0
RO




RO.
.38-1.20
1.
1.
1.
1.
1.
0.
99
04
05 .
03
06
74
4 Peaks

DC



NL 0
35
37:

:00
:59
:36
0
RO


7
29,367
5,450
4,298
2,616
43
41,732
.57
.20
.49
.34
.20
.45
.73
.37-0.51
1.
0.
0.
01
47
45
2 Peaks


DC


DC


NL 0:
36:
37:
WH 37:


00
13
05
32

0



RO

.88-
0.
1.
1.
1.
Above
1.20
98
01
02
43
2 Peaks

DC


NL 0:
37:

00
04
0.
RO

.88-
0.
1.
1.20
64
02
1 Peak


DC
DC

DC


DC


NL 0:
WL 36:
39:
SN 40:
41:
41:
SN 41:


00
14
04
57
09.
25
53

0.
RO


RO


RO

76-
1.
0.
0.
2.
0.
1.
1.
Ab v
1.02
33
31
33
19
91
01
10
3 Peaks

DC


NL 0:
40:

00
56
0.
RO

76-
0.
0.
1.02
43
32
1 Peak

DC

DC

NL 0:
40:
WH 41:

00
54
11
0.
RO

RO
4
1,027
797
1,324


. 6
11,544
10,389
12
22,434
.59
.56
.30
.36
51 / Wr
r / nj
.52
.15
.39
.06
.04
0.998-1.053
0
14.966.20 14,401.00 1
2.793.58 2,656.91 1
2,178.64 2,120.20 1
1,343.78 1,272.42 1
1

.000
.000 1234678-HpCDF AN E
.003
.013
.045 1234789-HpCDF AN
.062

0.944-1.111
0.000
327.56 700.00 1.000 13C12-HpCDF 678 IS6
246.14 551.16 1,


.045 13C12-HpCDF 789 SUR5


0.976-1.006
0.
5,791.95 5,752.20 0.
5,501.36 5,388.03 1.
1.

000
979 E
000 1234673-HpCDD AN E
013

0.973-1.027
3
1,043
1,043


0.
21.
21.
3.
4.613.
110.
3.
4.746.

0.
7,074.
7,074.
.73
.27
.27


.96
.69
.62
95
,50
.98
53
10

55
10
10
76-1.02
1.
0.
0.
10
95
33 .
1.
1,472.
4.
31
26
74
0.
526.10 517.17 1.

.
0.902-
0.
0.
10.14 11.48 0.
1-
2,195.16 2,413.34 1.
55.83 55.15 1.
1.

•0.902-
0.
3.190.01 3,884.09 1.

0.998-
0.
717.36 754.90 1.
1.
000
000 13C12-HpCDD 573 IS7


•1.098
000
386
955
001
006 OCDF AN
013
024

1.098
000
001 OCDD AN

1.006
000
000 13C12-OCDD IS3
007
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 14:27 01/15/98
                                                                                                 26:

-------
  Page No.     6       :    Listing of  T980158B.dbf
  01/15/98                 Matched OC  Peaks  /  Ratio  / Ret. Time

  Compound/
  M_2.... QC.Log Omit Why ..RT.  OK Ratio  Total.Area... Area.Peak.1.. Area.Peak.2. .  Rel.RT Compound.Name.. ID.. Flags.

                 DC  WH  41:25  RO  0.55          2.82                              1.013
  470-472               1 Peak                1,472.26
  Column Description. . .	   "Why" Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass(es)      WL-Below  Retention Time Window   A-Peak Added
  . .RT. -Retention Time (mm:ss)    WH-Above  Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below  Signal to Noise Level   D-Peak Deleted
 OK    -RO=Ratio Outside Limits  
-------
rile:T9a0158 tl-810 Acq: 6 -JAN- 9 8 19:55:03 BI+ Voltage SIS 70T Noiae:2505
303.9016 t:2 BSU3(25S,30,-3 .0) PKD(9,S,5,
TSIANSLE LABS Text:TLIt44376 125-128
1003
80:
so:
40:
20:
o-


A2.51E8 Al.
A Al . S7E8
A7.02E7 M /-\ AA
A A A /V\ f\l
' 23\00 	 24\00'
Tile:T9801S8 tl-810 Acq:S-JAJt-98 19s55t03
305.8987 T:2 BSUB(256, 30, -3. 0) PKD(9,S,5,
TSIANSLE LABS Text:TLI#44376 125-128
1003
ao:.
so-.

40:
20:
o'-

A3.12E8 Al.
A
(I A2.07S8
A8.72E7 1 /\ .A
A AA ISA/1!]
'2-3:00 	 24:00'
rile:T980158 #1-810 Acq : 6 -JAN- 9 8 19:55:03
315.9419 r-.2 BSUB(256,30,-3.0) PKD(9,S,5,
TSIANSLE LASS Text:TLI#44376 125-128
1003
sol
SO:
40:
20:






"
' 23\00 	 24:00
rile:T9B015a tl-810 Acq:6-JAN-98 19:55:03
317.9389 F:2 BSUS(256, 30, -3. 0) PKD(9,5,5,
TSIANSLE LABS Teit:TLIt44376 125-128
1003
80:
60:
40:
20:
0:
O.OS\,10020.0,1.00\tr,T) EzpiXDBSUS

A2.

51E8
tk
A A1.23E8
11 i A
iwuJ
25:00
IXT. TIKE - 19: 58
4E8



AS.71E7
A4.S2E7
A .
'2ffl-00

6.5E7




L5.2JT7
'•.3.9EUL
':2.6S7^
'.1.3E7
'• 0 . DEO
27:00 Time
EI+ Voltage SIS 70T Noiae:2534
0.05\,10136.0,1.00\,r,T) ExpsUDBSOS

A2
90E8
k
A
1 ' /\
AAA
in\AAl
25 loo
INJ. TIME - 15:58
6E8



A8.3SE7
\ AA.
25:00

6.4E7





.5.1E7
'•.3.9E7

.2.6E7
.1.3E7
O.OEO
"27:00 ' ' ' Time
EI+ Voltage SIS 70T Noiae:2385
0. 051,9540. 0,1.00%,

F,T) Exp:KDB5US
INJ. TIKE ' 19:58
A7.49E6
n

-


^ _• /
251-00



1
V
'251-00'


2.0E6





.1 . 6E6
-1.2ES
.a.OES
.4.0E5

' 271-00 	 Tiffle
EI+ Voltage SIS 70T Noise: 2289
0.05%,5155.0,1.00%,

F, T) Elp:NDB5US
INJ. TIKE - 19:58
A9 . 76E6





23': 00 	 24\00
rile:T980158 #1-810 Acq: 6 -JAN- 9 8 19:55:03
330.9792 T:2 Ezp:NDB5US
TSIANSLE LASS Text:TLI#44376 125-128
1003
80:
so:
40:
20:
o:
22:51 23:22 ^23:46 24:05 ^£i^7





' 23\00 	 24\00~
rile:T9a01S8 #1-810 Acq:S-JAN-98 19:55:03
375.8364 T:2 Eip:SDBSOS
TSIANSLE LABS Text:TLI#44376 125-128
1001
80.
so:
40:
20:
0




23\00 24:00


'

/
25.' 00




I
' 26\00'


2.8E6





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TRIANGLE LABS Text:TLZf 44376 125-128 •
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TRIANGLE LABS Text:TLI#44376 125-128
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40:
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TRIANGLE LABS Text:TLI»44376 125-128
1001
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TRIANGLE LABS Text'.TLIt44376 125-128
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TRIANGLE LABS Text:TLIt44376 125-128 HKT. TIMS - 19:58
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351.9000 r-.2 BSUB(256,30,-3.0) PXD(7,5, 3, 0 .05\,464S.0, 1.0Q\,T,T) Exp:SDB5US
TRIANGLE LABS Text:TLI#44376 125-128 UKT. TIME " 19:58
1003
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TRIANGLE LABS Text:TLIt44376 125-128 TJK7. TIME - 13:58
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TRIANGLE LABS Text:TLI»44376 125-128 IXT. TIME » 13.-58
1003
80:
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409.7974 T:2 Sxp:lO>BSUS
TRIANGLE LABS Text :TLI 14437 6 125-128 XK7. TIME - 19:58
1003
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TRIANGLE LABS Text:TLIt44376 125-128 OKT. TIME - 19:58
1003

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TRIANGLE LABS Text:TLI#44376 125-128 INJ". TIKE - 19:58
1004
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369.8919 r:2 BSUB(256, 30, -3. 0) PJH>(7, 5, 3, 0. 05%, 8680. 0,1 . 00\,T,T) Exp:lO>B5US
TRIANGLE LABS Text:TLI#44376 125-128 IKT. TIME - 15:58
1004
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        \32:00                          33:00                         34:00
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TRIANGLE LABS  Text:TLI#44376 125-128                       JJW. TIKE -   19:58
100$                                 A4.86E6

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TSIANGLX  LABS  T*xt:TLI#44376 125-128                        HfJ. ma -   19:58
100$    I  A1.61E8
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TSIASSLS LABS  Text:TLI#44376 125-128                       IKT. ma -   19:58
100A     A1.2SES

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TSIANSLS LABS  Teit:TLIf44376 125-128                       XJW. TIKE -   13:58
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TRIANSLS LABS  Text:TLH44376 125-128
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TSIANSLS LABS  Text:TLI#44376 125-128
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                                                                                                 268

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TSIAKSLE LASS  Taxt:TLIt44376 125-128                       HKT. TIME -   19:58
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TXIAXGLX LASS Text:TLH44376 125-128                       HKT.  TIKE -   19:58
1001                    A1.25E8

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TRIANGLE LABS Text:TLI*44376 125-128                        INJ.  TIME •    19:58
100*                                                                   A1.13E7
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       32:24    32:36   32:48   33:00   33:12   33:24   33:36   33:48   34:00
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403.8529 T:3 BSUS(256,30, -3. 0) PKD(7,S,3, 0. 051,15432. 0,1. 00\,T,T)  ExpsNDBSBS
TRIANGLE LABS  Text:TLI#44376 125-128                        IMJ. TIKE -    19:58
1001                                                                   A9.48E6
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392.9760 f:3 ExpiNDBSOS
TXIANGLE LABS  Text:TLI»44376 125-128                       HKT. TIKE  »    19:58
                                       34:00    34:12   34:24
1001

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TRIANGLE LABS Text:TLI#44376 125-128
1003
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36:00 36:12 36:24 36:36 36:48 37:00
rile:T9801Sa #1-563 Acq:6-J&y-98 19:55:03 EH- Voltage
HOT. TIME - 19:58





A1.34E7
^s^**^
37:12 37:24 37:36
SIS 70T Soiaetl853
-3.9E7






.3.2E7
.2.4X7
.1.6X7
.7.9X6

'• 0 . OEO
371: 4 3 38:00 38:12 Tiae

409.7789 T:4 BSUB(256, 30, -3.0) PKD( 7,5, 3, 0. 05%, 7412.0 f1.00\,r, T) XxptSDSSUS
TRIANGLE LASS Teit:TLI#44376 125-128
1001
aol
601
40.
20.

o:
A1.44E3
n
A


/ \ A2.66E7

J V_ _xv y^v
36':6o 36:12 36:24 36:36 36:48 37\00
r±le:T980158 #1-563 Acq:6-J7tS-98 19:55:03 EH- Voltage
417.8253 F:4 BSUS(256, 30, -3. 0) PKD(7,5, 3, 0. 05%, 6424. 0,
TRIANGLE LASS Tejct:TLI#44376 125-128
1001
aol

60^
40:
201

A3 .28E6
n



/ \
J v_ • •-
36':00 36\12 36\24 36I:36 36:48 37\00
Tile:T9B0158 #1-563 Acq:6-J7Of-98 19:55:03 EI+ Voltage
419.8220 F:4 BSUB(256,30,-3.0) PKV(7, 5, 3, 0. 05%, 6384. 0,
TRIANGLE LABS Text:TLI#44376 125-128
1003
aoj

6ol
40l
201
0'
A7.00E6
f\
A
/ \


/ \
J V
'36:00 36:12 ' '36\24~ ' 36\ 36 36^:48 ' 37\00
file:T980153 #1-563 Acq:6-JAN-98 19:55:03 EI+ Voltage
430.9729 T:4 Exp:NVB5US
TRIANGLE LASS Teit:TLI#44376 125-128
1001
aol
601
40.
20.
ol
36:08 36:27 36:3736^50^37^00^^
^^•^Nj^^^^^-^S^i^"^^^ ^V^1^^^^*"^ "^^%^ S^f^** ^s^*'




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435.
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1001
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0
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435.
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1001
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7766 r:4 BSUB(256, 30, -3.0) tXD(7,5,3,0.05\,S452.0r1.00\,r,T) SxpsSDBSUS
JTSLS LABS Text:TLI#4437S 125-128 1ST. TIMS - 19:58
A5.79E7
A AS. 50X7
\ A
A
/ \
/V /V
6:12 jtf.'is 3^:24 36:36 36:36 36:42 36:48 jjfijfi 37:66 37:06 '37\12 37:18 37^34 J7:JO 37:36
:T98015a #1-563 Acq:6-JAlT-9a 19:55:03 SI+ Voltage SIS 70T lToiae:1643
7737 r:4 BSUB(256, 30, -3. 0) PXD(7,5,3,0.05\,6573.0,1.00\,r,T) XxptUDBSas
JfSLE LABS Text:TZI#44376 125-128 INT. TIME - 19:58
AS. 75X7
A A5.39E7
\ \
\ , \
J V J V
S:12 'Jifi-ia ' 3.6lt34' 36i 30 36\36 36:42 36:48 J5.-54 37:66 37\06 '37\12 37^18 J7:2<( 37\30 37:36
ST9S01S8 #1-563 Acq:6-JAN-98 19:55:03 EI+ Voltage SIS 70T Koiae:952
8169 T:4 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 05%, 3808. 0, 1 . 00%, T, T) Elp:NDB5US
NSLE LABS Text:TLI#44376 125-128 XW7. TIME - 19:58
A5.26E6
\
\
\
' 7V
sYl2 j'eVia J(J.-i<( j«iJO SeVsS 36\42 36':4a 36V54 37:66 37:0tf 37^12 J7:ifl 37':24 J7:JO 37:36
:T9S0158 #1-563 Acq : 6 -JAN- 9 8 19:55:03 EI+ Voltage SIS 70T Koiae: 1493
8140 r:4 BSOB(2S6,30,-3.0) PKD(7, 5, 3, 0. 05\,5972. 0,1. 00\,r, T) Eip:HDB5US
NGLE LABS Text:TLI#44376 125-128 UfJ. TIME - 15:58
.

.

S':13 Jif.'ia 36I:24"36:36 36\36 36:43 36:48 jtfiii 37:66 ' J7: 06 ' 37\1 2~ 37s 18 '37:24 ' 37.' JO ' 37.: 36
:T9801S8 #1-563 Acq:S-JAlT-9a 19:55:03 EI+. Voltage SIS 70T
OGLE LABS Text:TLI#44376 125-128 JKJ. TIMS " 19:58
36:27 36:37 J5vf^«_v^_iZ
-------
J-L-ie.-rSaO.I5a  tl-563  Acq:S-JAS-98 IS:55:03 XI+  Voltage SJi 70T Noiati340
441.7438 ti4  BSUB(35S, 30, -3. 0) Pa>(7r5,3,0.05\,1360.0,1.00\,T,T) XzpiSDBSOS
TRIANGLE LASS  Taxt:TLI«44376 135-138                        H&. TIKE -   19t38
1001
 9oi
 801
 701
 SO.
 sol
 40.
 301
 301
 10!
  01
                                                                                    A3.30X7
              36:00         37:00         38:00        39:00         40:00
rile:T980158  f1-563 A&J-.6-JZN-98 19:55:03 XI+ Voltage SIS  70T !Toiae>356
443.7399 r:4  3SUB(256, 30, -3. 0)  PKD(7,5,3, 0. 05%, 1034.0,1. 00\,T,T)  SxptSDBSUS
TRIANGLE LASS  TeJCt:TLH44376 135-138                        I2KT.  TIME '   19:58
1003
 90\
 aoj
 70J
 601
 sol
 401
 301
 301
 101
                                                                                   41:00
                                                                                    A3.43E7
                                                                                                 43:00
                                                                                                      ..4.0E6
                                                                                                      .3.6E6
                                                                                                      .3.2X6
                                                                                                      .3.8X6
                                                                                                      -.3.4X6
                                                                                                      .3.0X6
                                                                                                      .1. 6X6
                                                                                                      .1.3X6
                                                                                                      .7.9X5
                                                                                                      .4.0X5
                                                                                                      '•.0.0X0
                                                                                                          Time
                                             38:15   38,49
              36:00         37:00         38:00        39:00
r±le:T980158  #1-563 Acq: 6-JAlf-98 19:55:03 XI+ Voltaye SIS  70T
430.9739 T:4  Exp:NDB5US
TRIANGLE LASS  Tejct:TLI»44376 135-138
             „  „  .      Z6,?50 37:1837:43,
     u AAU     -35?5.3     36:
 901
 801
 701
 601
 sol
 401
 301
 301
 101
        40:00

UKT. TIME »   15:58
 39:33     40:14
                                                                                   41: 00
                                                                                                 43:00
                                                                                                       4.3X6
                                                                                                      .3. 9E6
                                                                                                      .3.4X6
                                                                                                      ':3. 0X6
                                                                                                      .3.6X6
                                                                                                      .3.1X6
                                                                                                      .1. 7X6
                                                                                                      .1.3E6
                                                                                                       8.6E5
                                                                                                      .4.3E5
                                                                                                       O.OEO
                                                                                                          Time
                                                                                          41:31
 5.7X6
15.1E6
.4.5X6
'•.4.0E6
.3.4E6
.3.8X6
.3.3X6
_J. 7X6
.1. 1E6
-S.7E5
 0.0X0
              36:00         37:00         38:00        39:00
rile:T98015a  fl-563 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR  70T
513.6775 F:4  Xxp:NDBSUS
                                                                     40:00
                                                                                   41:00
                                                                                                 43:00
TRIANGLE LABS   Text:TLIt44376 135-138
100*                  36:31
 901
 801
 701
 601
 501
 401
 301
 301
 101
  01
                                                             UKT.  TIMX •   15:58
                                                         39:06
              36:00
                            37:00
                                          38:00
                                                       39:00
                                                                     40:00
                                                                                   41s 00
                                                                                                43:00
                                                                                                  272

-------
              tl-563 Ac-J*N-9B JJ.-33.-OJ  Et-t- Voltage SIS 70T Voia««J3I	
457.7377 T:4  3503(356,30, -3. 0) PXD(7,5,3, 0.05\,524.0,1.00\,r,T) Xxp-.lWBSUS
TRIANGLE LABS  Text :TLH4 4376 125-128                        XKT. TIMS •   19:58
100i        A3.11E7
  30.
                                                                              41:24
         40:54         41:00         41:06         41': 12        41:18
rlletT9B0158  «l-,563 Ae
-------
59

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biiCU!?. 1 vwff,.. -X. 1 53\ '.i;jj
Height 3.59 volts Span 298.ppa
System fits nae N08SJS
Data filename f):TS88148
Resolution 18888
Groflnuiter 2
lonlzatlcn aode El*
Switching VOLTRGE
Ref, lasses 292,3825, 416,3768
fl 293 J 331 S 368
8 384 K 332 T 378
C 386 L 334 U 376
D 316 H 348 V 418
E 318 H 342
F 329 0 352
6 322 P 354
H 328 Q 356
I 331 R 358
Ref, sass 416,3768 Peak top
Height ,36 wits Span 288 ppa
                                                274

-------
?ile:T980158 #1-810 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI»44376 125-128                       INJ. TIME =
100%,                                A8.Q9E7
   19:58  File
                                                                              Text:TLI#44376 125»
                                                                                         _1.4E7
                                                                26:36   26:42    26:48
                                                                                          .O.OEO
                                                                                             Time
File:T980158 #1-810 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR  70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376 125-128                        INJ. TIME
100%                                A1.Q3E8
   19:58 File
                                                                              Text:TLI#44376 125»
                                                                                         _1.8E7
  25:48   25:54   26:00   26:06   26:12    26:18   26:24   26:30
File:T980158 #1-810 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR  70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 125-128                        INJ. TIME
100%                           26_; 10
26:36
26:42   26:48
                                                                                         hO.OEO
                                                                                             Time
                                                                   19:58  File Text : TLI#44376 125»
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File:T980158 #1-810 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME =
1003
                         19:58 File Text:TLI#44376  125»
                                                _2.4E6
                          26:42   26:48  26:54
       -I—i—i—i—i—i—i—i I I I  t i—i—i  | I I—i—I—I—i—i—I—I—I—I—|—I—I—i—I—i—|—r-*i—i—i—i—|—i—i—i—i—i—|—i—r-
        25:54   26:00  26:06   26:12   26:18  26:24   26:30  26:36
File:T980158 #1-810 Acq:6-JAN-98 19:55:03 EI+  Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376 125-128                        INJ.  TIME  =
100!
                           Time
                         19:58 File Text:TLI#44376 125»
                                                _3.1E6
         25:54   26:00  26:06   26:12  26:18   26:24   26:30  26:36
File:T980158 #1-810 Acq:6-JAN-98 19:55:03  EI + Voltage  SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 125-128                        INJ.  TIME  =
100%.
                          26:42   26:48  26:54
                       .O.OEO
                           Time
  80j
  60 j
  40J
  20 j
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                       _2.0E6
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         25:54  26:00   26:06   26:12  26:18   26:24   26:30   26:36   26:42   26:48   26:54
                                                    Time
    ro
    -j
    CD

-------
 Tile:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME =
100%
              19:58 File Text:TLI#44376 125»
                                    _5.0E6
  32:22 32:24  32:26 32:28  32:30 32:32  32:34  32:36  32:38  32:40
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME =
lOOi                                                   32:38

 80 j

 601

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               32:42 32:44  32:46
                        .OEO
                          Time
  32:22 32:24  32:26 32:28  32:30  32:32  32:34  32:36  32:38  32:40
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI + Voltage SIR  70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128
100%.
              19:58 File Text:TLI#44376  125»
                                      3.9E4

                                     L3.1E4

                                     L2.4E4

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                                         Time
32:42 32:44  32:46
INJ.  TIME =   19:58 File Text:TLI#44376 125»
                     32:44
        32:24  32i26  32i28  32i30  32i32  32i34  32.:36 32i38  32i40 32^2  32i44  32J46
                                    ±.O.OEO
                                         Time
  ro

-------
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
 ample Text:TLI#44376 125-128                       INJ. TIME
100%             32^53
                                               19:58  File  Text:TLI#44376 125»
                                                                      _3.8E7
                  32:54            33:00            33:06
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI»44376 125-128                       INJ. TIME
                                 32:59
                                                 33:12
                                                 33:18
                         Time
                   32:54            33:00           33:06
File:T980158 Sl-396 Acq:6-JAN-98 19:55:03 EI + Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME
100%                                                     33;08
                                19:58 File Text:TLI#44376 125»
                                                       1.6E6
                                                      L1.2E6
                                                      L9.3E5
                                                      L6.2E5
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                                                       O.OEO
                                                          Time
                                                 33:12
                33:18
  80j
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                                19:58 File Text:TLI#44376 125»
                                                      _4.4E4
                                     if0               -3 . 5E4
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-------
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128
100%                                      33^30
INJ.  TIME =
19:58
    33:18  33:20  33:22  33:24 33:26 33:28 33:30  33:32  33:34 33:36 33:38
File Text:TLI#44376 125»
                  1.8E7

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383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME =
100%

 80j
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                     33:40  33:42 33:44   Time
              19:58 File Text:TLI#44376  125»
                                      1.3E6

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File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR  70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME =   19:58
100%,                         33:26
                     33:40  33:42 33:44   Time
                    File Text:TLI#44376  125»
                                     ..2.1E5
                     33:405342 3344   Time
     33:18  33:20  33:22 33:24 33:26 33:28  33:30  33:32 33:34 33:36  33:38
  CD

-------
File:T980158 81-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME =
lOOi                                                  34:23
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      34:14
                        19:58  File  Text:TLI#44376 125»
                                              _2.9E6
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File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME  =
1004.                                       34; 18
 80j
 60 j
 40J
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            34:06          34:12           34:18          34:24
File:T980158 #1-396 Acq:6-JAN-98 'l9:55:03 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128
1004                              34;14
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                                              LO.OEO
                                                  Time
                                       19:58 File Text:TLI#44376  125»
                                                               1.1E6
                                                              L8.4E5
                                                              L6.3E5
                                                              _4.2E5
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                                              34 :30
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                                                  Time
                         INJ.  TIME =   19:58 File Text:TLI#44376  125»
            34:06
34:12
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34 :30
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-------
Hle:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME
100%                                          A1.10E7
 80 j
 60j
 40_
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  0
    A2.98E6
                              19:58  File  Text:TLI#44376 125»
                                                    _2.9E6
                                                    _2.3E6
                                                    _1.7E6
                                                    _1.2E6
                                                    ._5.8E5
         34:06         34:12          34:18         34:24
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR  70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                       INJ. TIME
100%                                          A8.60E6
 80J
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 40J
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                                         34:30
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                                          Time
    A2.41E6
                              19:58  File Text:TLI#44376 125»
                                                     2.3E6
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                                                    L1.4E6
                                                    L9.3E5
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         34:06         34:12         34:18          34:24
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage  SIR  70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128                        INJ. TIME
100%                                 34;18
                                         34 :30
                                         34:36
                                       1.0. OEO
                                          Time
                                            19:58  File  Text : TLI#44376 125»
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                                                                                         _8.4E5
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                                                                                         _4 .2E5
                                                                                         _2.1E5
         34 :06
34:12
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34:24
34:30
34:36
lO.OEO
    Time

-------
TLI Project:      44376
Client Sample:   125-128
Method 23 TCDD/TCDF Analysis (DB-225)
                    Analysis File:   P98016
i
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-6A-6D Date Extracted: 12/29/97
Date Analyzed: 01/10/98
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a
Blank File: X980083
Analyst: WK
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
^
SPC2NF04
PF22206
P980164
: n/a
n/a
n/a

;aiw&tte ' ' ', - \-*~ Amktn0> ' ^~Dt aipc '- '~&*i*;^~ m * Flags -
23,7,8-TCDF
17.5
Internal Standard Ami (ng> % Recovery QC Limits
'3C12-^3,7,8-TCDF
Recovery Standard
13C,2-1,2,3,4-TCDD
2.0 51.0 40%-130%


0.73
'R^tto ^
0.77
ftatw |;
0.83
23:05 	
f)T Flags
23:04 	
RT Flags
21:53 	
                    Data Reviewer..
                   01/11/98
                                       Page 1 of 1
                                ONFJ>SR rlOl. LARS&l
Triangle Laboratories, Inc.*
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                             Printed: 13:35 01/11/98

-------
                        Initial
                                     Data..
  Data Review By:
                                   ( I K 1 4?  Calculated Noise
                                                              Area:
 >
be Total Area for each peak with an ion abundance ratio outside
atio limits has been recalculated according to method requirements.
                                                                     2.00
  Page No.
  01/11/98
                       Listing of P980166B.dbf
                       Matched OC Peaks / Ratio / Ret.
Tin
  Compound/
  M_Z	 QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Na
                                                                                                 ID..  Flags.
TCDP 0
304-306 DC NL 0:00 RO
18:27
18:43 RO
19:27
19:34
19:42
19:53
' 20:08
20:18
\ 20:26
20:36
20:45
21:08
21:35
21:41
21:50
22:04
22:13
22:29
22:43
22:56
23:05
. 23:18
' 23:34
' 23:41
24:28
24:37
- 25:13
304-306 27 Peaks
13C12-TCDF , 0.
316-318 DC NL 0:00 RO
DC WL 18:29 RO
DC WL 20:05
DC WL '• 20:30
DC WL 20:42 RO
DC WL 21:09 RO
DC WL 21:37 RO
DC WL ' 21:41 RO
DC WL : 21:47 RO
23:04
DC SN 23:25 RO
DC SN 23:33 RO
.65-0.89
1.06
0.74
1.78
0.75
0.74
0.74
0.72
0.74
0.74
0.78
0.72
0.75
0.73
0.77
0.65
0.75
0.74
0.75
0.73
0.74
0.73
0.73
0.74
0.75
0.76
0.75
0.75
0.65

65-0.89
1.42
0.63
0.33
0.67
5.86
2.92
0.93
1.58
2.37
0.77
0.44
0.18
37
11,333
26
8,793
8,991
21,193
7,603
8,106
17,360
8.336
28,093
13,897
43.066
10,052
1,770
16,304
11,043
1,852
15,609
613
15.663
7,309
16,332
13.248
11,650
6,239
152
985
306.134
.35
.86
.96
.11
.47
.00
.15
.24
.81
.28
.50
.04
.20
.03
.35
.39
.51
.76
.79
.30
.57
.11
.63
.35
.49
.09
.42
.72
.13
4
3
3
9
3
3
7
3
. 11
5
18
4

6
4

6

6
3
7
5
5
2



,833
27
,767
,833
,024
,183
,452
,374
.645
,724
,964
.172
,356
698
,966
,708
791
.584
260
.592
,081
,155
,672
,014
,666
65
387

.58
.17
.20
.80
.90
.68
.17
.85
.30
.30
.00
.30
.33
.61
.95
.93
.50
.47
.66
.85
.06
.62
.93
.18
.72
.23
.76

6,500
15
5,025
5,157
12,168
4,419
4,654
9,985
4,690
16,368
7,933
24,393
5,695
1,071
9,337
6,334
1,061
9,025
352
9,075
4,223
9,677
7.575
6,636.
3,572
87
597

0.793-1.101
0.000
.28 0.800
.23 0.811
.91
.67
.10
.47
.07
.96
.48
.70
.04
.40
.20
.74
.44
.58
.26
.32
.64
.72
.05
.01
.42
.31
.37
.19
.96

0.343
0.348
0.854
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.

0.957-
2
• 7,
9,
16.
5.
1.
9.
0.
5.
1,606.
2.
1.
.73
.01
.85
.13
,75
.82
.29
85
,12
35
28
20





















701.











.05











905.











30


0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
.862
,873
.380
.386
393
900
916
936
940
947
957
967
975
985
994
001 2378-TCDF AN
010
022
027
061
067
093

1.043
000
801
871
889
897
917
937
940
944
000 13C12-2378-TCDF ISO
015
021
E
B
S
E


E

E
E
E
E

E
E

E

E

E
B
E

















Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                        Printed: 13:21 01/11/98
                                                                                                   283

-------
  Page No.
  01/11/98
Listing of P980166B.dbf
Matched 
-------
File:pS301SS  #1-932 Acq:10-JM-199B Us29:50 Bit Voltage SIS  70» Noiae:1116B
303.9016 BSUB(256,30,-3.0)  PKD(5, 3,1, 0.101,44672.0, 0.00\,T,T) Exp:DB225
TRIANGLE LASS  Text.: 125-128   TLI#44376
1004           '                       Al  2E8
            19:00         30:00         21:00        22:00        23': 00        24': 00
rile:P980166  #1-922 Acq: 10-J3OT-1998 12:29:50 EH- Voltage SIS 70P Boiae-.lOSSO
305.8987 BSUB(256,30r-3.0)  PKD(5, 3,1, 0.10\, 42200. 0, 0. 00%,T,r) Kxp:DB225
TRIANGLE LABS Text:125-128   TLI»44376
100*                                  A2.49E8
                                                                                          25:00
  80.

  60.

  40:

  20.
                   A1.22E8
                                               A9.34E7
                                                        A9.03E7
                                                              A9.08E7
                                                                  A9.68E7
                                                                         '
                                                                                 A3.57E7
           19': 00        20': 00        21:00        22:00        23:00        24:00
File:P980166 #1-922 Acq: 10-JAN-1998 12:29:50 EI+ Voltage SIS 70P Hoise:1092
315.9419 BSU3(256,30,-3.0)  PKD(5, 3,1, 0.10%, 4368. 0, 0. 00\,F,F) Eip:DB225
TRIANGLE LABS  Text: 125-12S   TLI#44376
lOOi,           '                                                A7. 1E6
 80.
 60.
 40.
 20.
                                                                                         25:00
           19:00        20:00        21:00        22:00        23:00        24:00
File:P980166 #1-922 Acq:10-J7Uf-199B  12:29:50 EH- Voltage SIS TOP Noise:772
317.9389 BSU3(2S6,30,-3.0) PXD(S, 3, 1, 0.10\, 3088. 0, 0. 00\,F,F) Exp:DB225
TRIANGLE LABS  Text:12S-128    TLI#44376
1004                                                           A9.Q5E6
 so:

 60.

 40.

 20:
                                                                                         1" i   i
                                                                                         25:00
           15:00        20:00        21:00        22:00        2J.-00
File:P980166 #1-922 Acq:10-JAN-1998  12:29:50 EH- Voltage SIR TOP
375.8364 Exp:DB225
TRIANGLE LABS  Text:125-128    TLI#44376
                                                                            24: 00
                                                                                         25:00
1001

 80.

 60.

 40.

 20.

  0.
                                                           22; 42
    18:28
             19:08
                                  20:48
                                                                            : 52
                                                                                   24:36
           19:00
                        20:00
                                     21:00
                                                  22,00
                                                                                                      3.2E7

                                                                                                     '.2.6E7

                                                                                                     .1.9E7

                                                                                                     .1.3E7

                                                                                                     .6.4E6
                                                                                                     .O.OEO
                                                                                                         Tin
                                                                                                      1. 4E6


                                                                                                     .1. 2E6


                                                                                                     .8. 7E5


                                                                                                     -S.8ES


                                                                                                     -2.9ES
                                                                                                      O.OEO
                                                                                                         Time
                                                                                                    _I.8E6

                                                                                                      1.5E6

                                                                                                      1.1E6

                                                                                                      7.3ES

                                                                                                      3.6E5
                                                                                                     O.OEO
                                                                                                        Time
                                                               23:00
                                                                            34:00
                                                                                        251 00
                                                                                                     .1. 8ES

                                                                                                     .1.5E5

                                                                                                     .1.1E5

                                                                                                     .7.3E4

                                                                                                     ,3.7X4

                                                                                                     O.OEO
                                                                                                        Time
                                                                                                 2S5

-------

319.8965 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10\,
0 EI+
2600.
Voltage SIS 70P Hoiae:tit>0
0,0.00\,e,T) Elp:DB225
TRIANGLE LABS Taxt:125-128 TLIV44376
1001
80.
60.
40.
20.
0






11
I
,,

\ 1



19E8

\ TAA*T'
20 : 00 21 : 00








A6.78E7
-/Vf Vv -r^—
-4.6E7
'.3.7E7
.2.8E7
.1 . SE7
.9.2E6
O.OEO
221-00 2J:00 24:00 Time
Tile:P980166 #1-922 Acq:10-JZlT-199a 12:29:50 EI+
321.8936 BSUB(256,30,-3.0) PKD< 5, 3,1, 0.10%,
2S50.
Voltage SIS 70P Noise: 665
Q,0.00\,T,r) Elp:DB22S
TRIANGLE LABS Tert:125-12fl TLH44376
1001
80.

60.
40.
20;
0'















Al . 52E8


i.



A4'ft5E7f\ A A3.61E7
\ AAA A
20 1-00 21 .-00




A8.65E7
/~*J\ Vv ^ x-^_
-6.0E7
'.4.8E7

.3 . 6E7
.2.4E7
.1.2E7
O.OEO
22:00 ' ' '2J1-00' ' ' ' 24:00 	 Time
File:P980166 #1-922 Acq: 10-JAN-1998 12:29:50 EI+
327.8847 BSUB(256, 30, -3 . 0) PKD(5, 3, 1, 0. 10%,
2964 .
Voltage SIR 70P Noise: 741
0,0.001,F,F) Exp:DB22S
TRIANGLE LABS Text: 125-128 TLI#44376
1003

80.
60.
40.
20.
0

















Al.
A6.50E6 .
Ah
A3.04E6 \
, A1.35E^\ A A1.13E6 1 \
y^ ^~yv J \ /V_~A_/L/

20 1-00 ' 21 .-00

A2. E7 4.8E6
A1.66E7

18E7
A


u




I / I

'.3 . 8E6
'.2.9E6
'.1.9E6
'.9.6E5
" 0 . OEO
22 .-00 2-jl-OO 241-00 Time
File:P980166 #1-922 Acq: 10-JAN-1998 12:29:50 EI+
331.9368 BSUB(256,30,-3.0) PKD(5, 3, 1, 0.10%,
Voltage SIR 70P Noise: 691
2754 .0,0.00%, F,F) Exp:DB22S
TRIANGLE LABS Text: 125-128 TLI#44376
1003
80.
60.
40.
20.
0














File:P980166 #1-


AS.
1

1
201-00 ' ' ' 21:00
A1.03E7
n

78E6\
I


1 /



\
\
-2.4E6
.1.9E6
-1.4E6
-9.7E5
.4.8E5
O.OEO
22 .-00 2J.-00 24:00 Tine
922 Acq:10-JAN-1998 12:29:50 EI+
Voltage SIR 70P Noise:363
333.9338 BSUB(256,30, -3.0 ) PKD(5, 3, 1, 0.101,1452. 0, 0. 00*,r,F) Exp:DB22S
TRIANGLE LABS Text:125-128 TLI#44376
1004
80.
60.
40:
20:
o:






A1.24E7


A7.21E6\\
A 1 1










1
20:00 21:00

II'



(
.2.9E6
.2.3E6
.1 . 7E6
.1.2E6
.5 . 8E5
O.OEO
22:00 2J:00 24:00 Tiae
2S.6

-------
rile:P980166 #1-922 AcqtlO-JAN-1998 12:29:50
303.9016 Exp:DB225
TRIANGLE LABS Text:125-12B TLI#44376
1001 20.-J* 31i08
80: 15:42 A \
SO 20:18 II
' ' 18:27 - A i
4°~- l\ A A Al A/

30-: l\ /VviA |yyV I/I j L
15:00 20:00 21:00
rile.-?98015fi #1-522 Ac?:10-J3Ur-1558 12:29:50
315.9419 Exp:DB225
TRIANGLE LASS TeJCt.-125-l.2S TLI144376
1003
so:
50:
40:
20:

151-00 20 1-00 21 loo
rile:P980166 #1-922 Ac 22:56 A
21 • 35 11 A
II (1
A A

IUILO
\A
nil
24:28
/l/«l A -
.1.9E7
.1 . 4E7

.9 . 4E6

.4. 7E6
O.OEO
22:00 2J:00 24:00 25:00 Zloe
TJ* Voltage SXB 70?


33




J



04




L
1 . 4E6
.1.2E6
la.7E5
.5 . 8ES
-2.9E5
O.OEO
221-00 2J.-00 241-00 25:00 Tine
EI+ Voltage SIR TOP






21:54








4.6E7
.3.7E7
.2.8E7
.1 . 8E7
.9.2E6
'•O.OEO
22-00 2J.-00 24-00 25-00 Time
EI+ Voltage SIS 70P


21 : 53




2.4E6

so: ;. 21i36\\
40:
20: i
o1
15:00 20:00 21:00
File:P980166 #1-922 Ac"'^^^"* Nn^jif^'V"*' ' * ' \**\J* >*^ y




-1.1E7
-8.3E6
.5.SE6
.2.816
a nrn
22:00 23:00 24:00 25:00 Time
997
»*•  *—•  I

-------

:n
5
M
JD
5


	

• '-1
A
1
T
M
A


^SB^^JT

lEES^^T
IWST . Mas uttwcu re* up
Helctt 1.63 volts Spat 266 ppi
Systei file naie 06225
Data file naie fl'P988166
Poenji^inn IflflM
nUMULUXI iWUU
Group nuker 1
lonlzatlon Kde El*
Switching VlTflGE
Ref. lasses 292.9825, 386.9761
B 292.9825 J 336.9792
8 363.9616 K 331.9368
C 385.8987 I 333.9338
0 315.9419 H 3E.8364
E 317.9389
F 319.8965
G 321.8936
H 327.8847
I 336.9792
Channel I 336.9792 Peak top
Height 1,99 volts Span 266 ppi

-------
TLI Project:      44376
Client Sample:   129-132
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:  T980159
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received:
194-59-7A-7D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01/06/98
n/a
T980150
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD ,
1,2,3,6,7,8-HxCDD ;
1,2,3,7,8,9-HxCDD ;
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD |
2,3,7,8-TCDF ',
1,2,3,7,8-PeCDF :
2,3,4,7,8-PeCDF '
,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF !
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6.7,8-HpCDF
1,2,3,4,7,8,9-HpCDF '
1,2,3,4,6,7,8,9-OCDF

Totals
Total TCDD i
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF \
Total HpCDF
Amt. (ng) DL EMPC
0.04
0.18
0.17
0.27
0.41
1.2
1.8
4.1
0.91
1.6
3.5
1.3
1.7
0.09
4.8
0.87
4.0

Amt (ng) Number DL EMPC
4.5 11 4.5
2.9 9 4.4
4.2 7
2.3 2
26.1 16 26.1
21.4 15 21.6
13.9 13 13.9
8.1 4
Ratio
0.68
1.52
1.20
1.17
1 22
1.04
0.84
0.81
1.46
1.55
1.25
1.28
1.28
1.05
1.13
1.02
0.89










BT
26:21
30:31
33:36
33:42
34:00
37:05
40:57
25:41
29:29
30:11
32:53
33:00
33:30
34:18
36:00
37:37
41:10










Ffegs




PR_

	






PRJ




Flags



—
Q_

SJ

                                       Page 1 of2
                         X237.PSR Y2.01. LARS & 10.080
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5^91
                      Printed:
01/15/98

-------

TLI Project:     44376
Client Sample:   129-132
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:  T980152
internal Standards
13C,2-2,3,7,8-TCDF
1JCij-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13Cu- 1,2,3,4 A7.8.9-OCDD
Surrogate Standards (Type A)
"CU-W.S-TCDD
13Cir2,3,4t7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-U,3,4,7,8-HxCDD
l3Cr-l,2,3,4,7,8,9-HpCDF

Alternate Standards (Type A)
13Ci2-l,2,3,7,8,9-HxCDF
13Ci2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
"Cu-1.2,3,7.8.9-HxCDD
Amt (rig)
2.7
2.7
3.1
3.6
3.0
3.6
3.5
4.5
.8.8
AntL (ng)
3.3
3.8
4.0
4.1
4.3

Amt. (ng)
3.3
3.0


% Recovery
66.7
67.7'
76.8
90.6
75.8
90.7
86.6
112
109
% Recovery
82.6
94.1
99.9
104
107

% Recovery
82.5
76.1


QC Limits
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%- 130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%

QC Limits
40%- 130%
40%- 130%


Ratio
0.74
0.79
1.55
1.44
0.51
1.18
0.44
1.05
0.91
Ratio
1.51
0.51
1.16
0.44

Ratio
0.51
0.52
Ratio
0.81
1.16
m
25:39
26:20
29:29
30:30
32:59
33:41
36:00
37:05
40:56
RT
26:21
30:10
32:53
33:35
37:37

RT
34:18
33:30
RT
26:10
34:01
Fiags
—
—
Flags
—


FEagsfl

—
Fiags
—
                     Data Reviewer
            01/15/98
                                        Page 2 of 2
                         X237.PSRv2.01. LARS 6.1
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 09:28 01/15/98
                           2SC

-------
                        Initial
                                    • .Date. .
  DaCa Review By:
                                          *J
                                              Calculated Noise Area:   1.72
   he  Total Area for each peak with an ion abundance ratio outside
   •atio limits has been recalculated according to method requirements.
  Page No.
  01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Ratio. / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why . ,RT.  OK Ratio Total.Area...  Area.Peak.1..  Area. Peak.2. . Rel.RT Compound.Name.
                                                                          ID..  Flags.
TCDF
304-306

DC NL 0:
0
:00 RO
22:39

















| 04-306
13C12-TCDF
316-318








316-318
TCDD
320-322






23
23:
23:
24:
24:
1 24:
24:
, 25:
25:
; 25:
25:
26:
' 26:
26:
, 26:
; 26:
27:
:08
:21
:43
:02
:24
40
;53
;05
:16
30
41
05
18
32
49 RO
58 RO
20
.65-0.89
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
18 Peaks
'
DC NL 0:
DC WL 22:
DC WL^ 24:
DC ML' 24:
25:
1 25:
25:
! 26:
DC WH 27:
0.
00 RO
41
04
13
07 RO
15
39
04
35
.23
.82
.32
.78
.81 3
.33 2
.79 2
.78 1
.31 1
.79 4
.30 1
.31 1
.31 4
.30 1
.73
.74
.98
.31
.32
27
5
848
891
756
,488
,474
,723
,893
,272
,270
,079
,083
,247
,071
865
179
11
7
117
,282
.38
.00
.59
.87
.94
.63
.78
.51
.23
.33
.12
.53
.14
.35
.21
.09
.34
.38
.05
.59

382
401
330
1,557
1,124
1,203
831
569
1,891
479
485
1,900
476
373
76.
6.
5
52


.65
.30
.43
.35
.42
.23
.49
.47
.10
.30
.83
.52
.36
.65
.13
. 58
.33
.69


465
490
426
1.931
1,350
1,520
1,062
702
2.379
599
597
2.346
594
436
102
6
4
64

65-0.39
1.
0.
0
0.
1.
0,
0.
0.
0.
4 Peaks

DC NL 0:
23:
i 24:
24:
DC SN 24:
25:
25:
0.
00 RO
54
16
34
55 RO
12
27
.42
.85
.75
.31
.19
.32
.74 3
.69
69
3
65-0.39
0.
0.
0.
0.
1.
0.
0.
57
79 1
30
71
56
78
76
2.
8.
IS.
4.
8.
20.
,049.
19.
11.
.64
.02
.77
.99
,53
61
63
59
63
,098.36
T(" HP 1 TV-
1 V— LIC 1 L\f
2.
,443.
883.
107.
0.
422.
228.
60
87
23
46
97
90
17




5.
9.
1,293.
a.





72
31
10
02





4
11
1.756
11

0.878-1.073

.35
.29
-39
.59
.21
.55
.02
.76
.73
.32
.70
.62
.49
.56
.96
.69
.45
.36

0.000
0.383
0.902
0.910
0.925 Q
0.937
0.951
0.962
0.970
0.973
0.985
0.994
1.001 2373-TCDF AN
1.017
1.025
1.034
1.045 J
1.051 J
1.066

0.961-1.039




.82
.30
.53
.57

0.000
0.384
0.938
0.944
0.979
0.984
1.000 13C12-2378-TCDF ISO
1.016
1 .075



639.
391.
44.

185.
98.

37
55
46

22
89

0.903-1.045

804.50
491.68
63.00


237.68
129.
28
0.000
0.908
0.922
0.933
0.946
0.957
0.966
Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 09:28 01/15/98
                                                                         2S1

-------
  Page No.
  01/15/98
Listing of T980159B.dbf
Matched GC Peaks /  Racio / Ret. Time
  Compound/

  M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.

H
AN
AND
AND




320-322
37C1-TCDD
328

















328
13C12-TCDD
332-334









332-334
PeCDF
340-342






D TE
D TE




12
25
26
26
26
26
26
26
26
27
:51 0.78
:14 0.78
:21 0.68
:21 0.68
:21 0.68
:31 0.70
:40
:52 RO
0.77
0.98
:18 0.34
Peaks
117
434
37
38
38
53
58
17
21
3,824
.34
.00
.50
.90
.90
.40
.24
.06
.27
.44
51
190
15


21
25
9
9

.53
.00
.20


.94
.40
.44
.74

65.31
244.00
22.30


31.46
32.84
9.64
11.53

0.982
0.996
1.001 2378-TCDD AN
1.001
1.001
. 1.007
1.013
1.020
1.037

0.924-1.076
DC NL
DC WL
DC WL
DC WL











DC SN


13

DC NL

DC SN




DC SN
DC SN
DC SN
5

DC NL



0
23
24
24
24
24
25
25
25
25
26:
26:
26
26:
27:
27;
27;
27:
:00
:55
:10
:17
:27
:35
:01
:13
:40
:52
:03
:13
:21
:43
:16
;27
:33
: 46




































Peaks

0:
25:
25:
26:
26:
26:
26:
27:
27:
27:
0.
.00 RO
;14
45 RO
10
20
40
54
08 RO
27 RO
45 RO
65-
2.
0.
3.
0.
0.
0.
0.
5.
1.
2.
Peaks

0:
27:
27:
28:
1.
00
33
53 RO
00 RO
32-
1.
1.
1.
1.
0.39
29
80
00
31
79
78
74
36
04
34

1.78
37
47
80
82
1
8
4
6
.7
2
465
6
11
2
g
3
2,077
262
2.
1.
3.
3.
2,861.
.31
.41
.73
.36
.63
.17
.56
.64
.53
.85
.52
•71
.92
.62
.76
.50
44
19
59




7
2
465
6
11
2,
6.
3.
2,077
262.
2.

3.
3.





.68
.17
.56
.64
.53
.35
.52
.71
.92
.62
.76

44
19




















0.000
0.908
0.913
0.922
0.928
0.934
0.950
0.958
0.975
0.982
0.989
0.996
1.001 37C1-TCDD SUR
1.015
1.035
1.042
1.049
.1.054

0.924-1.076
3.
15.
2.
2,960.
2,499.
.42.
10.
1.
2.
2.
98
59
27
05
33
05
67
33
14
55
5,528.24
• TCDD / Pe<

2.
1,694.
47.
31.
92
23
12
31

6.

1,322.
1,101.
18.
4.




92

69
30
45
54




8.67

1,637.36
1,393.58
23.60
. 6.13



0.000
0.953
0.978
0.994 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.022
1.030
1.042
1.054
~nT? Vnl 1 rtbra


1,007.
33.
22.

39
35
34
0.931-1.063

686.34
13.48
12.28
0.000
0.934
0.946
0.950
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:28 01/15/98
                                                                        2S2

-------
 Page No.
 01/15/98
Listing of T980159B.dbf
Matched GC Peaks /  Ratio / Ret. Time
 Compound/
 M_2....  QC.Log Omit Why  ..RT.  OK Ratio Total.Area... Area.Peak.1. .  Area.Peak. 2. . Rel.RT Compound.Name..  ID.. Flags.





M
M
M
AN








340-342
13C12-PeCDF
352-354








M 2-354
PeCDD
356-353












356-358
13C12-PeCDD
363-370

1 ' 28
28
28
28
28
: 29
29
. 29
29
29
29
30
30
! 30
i 30
31
DC WH 31
:10
:18
:32
:40
:49
:07
:14
:25
:29
:40
:47
:11
:19
:38
:52
:08
:35
RO 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
RO 1.
1.
1.
29
39
50
51
50
47
55
46
46
50
52
55
51
37
01
37
32
19 Peaks

DC NL ' 0:
DC SN ! 28:
28:

DC SN ' 29:
29:
| 29:
30:
•' 1

:00
:20
;37
:49
14
: 29
46
:10
08
1.32-
RO 1.
RO 0.
RO 1.
1.
RO 7.
1.
RO 1.
1.
RO 1 .
6 Peaks
t •

DC NL | 0:
28:
•| 28:
29:
29:
29:
29:
'30:
1 30:
i 30:
i 30:
30:
30:

00
:45
57
14
27
35
46
01
13
20
31
38
57
1.32-
1.
RO 1.
RO 0.
1 .
1.
1.
1.
1.
1.
RO 0.
1.
1.
1.
1.78
18
72
16
73
46
55
23
51
21

1.78
47
16
04
32
53
51
54
50
53
58
52
60
76
12 Peaks
36
39
652
3,887
816
1,412
1,746
798
700
612
962
1,224
1,550
258
6
147
4
16,625
.85
.92
.36
.94
.47
.00
.00
.00
.00
.60
.81
.32
.48
.53
.51
.16
.32
.11
22
23
391
2,339
489
841
1,060
473
416
367
581
744
931
149
3
35


.40
.19
.13
.08
.93
.00
.00
.00
.00
.64
.41
.38
.60
.56
.96
.11


17
.37
16.73
261
1,548
326
571
686
325
284
244
381
479
613
108
3
62


.23
.36
.54
.00
.00
.00
.00
.96
.40
.94
.38
.97
.94
.05


0.955 J
0.960 J
0.963
0.972
0.977
0.983
0.992
0.998
1.000 12373-PeCDF AN
1.006
1.010
1.024 23478-PeCDF AN
1.028
1.039
1.047 J
1.056
1.071

0.364-1.136
1
2
16
9
3
2,910
20
2.720
7
5,635,

1.
892.
4.
64 .
579.
102.
403.
195.
165.
71.
108.
72.
65.
2,727.
.13
.27
.52
.12
.62
.19
.36
.71
.33
.23
r /
/
.21
.93
.24
.97
.55
20
.56
82
33
65
96
31
23
30


10
5

1,767
12
1,633
4


.04
.78

.86
.63
.34
.76


3
3

1,142
10
1.082
3


.62
.34

.33
.29
.37
.93
0.000
0.961
0.971
0.977
0.992
1.000 13C12-PeCDF 123 IS2
1.010
1.023 13C12-PeCDF 234 SUR2
1.056
p— /^rjn Pn 1 1 r»u/o


542
2,
37,
350.
61.
244.
117.
100.
43.
65.
44.
41.


.76
.53
,00
.32
.50
,74
.37
34
55
72
49
66


.469,
66.
27,
228.
40.
153.
78.
65.
75.
43.
27.
23.

1.32-1.78
DC NL 0:
30:
00
30
1.
1.
32
44
0.
1,904.
44
90

1,124.

92

779.
0.939-1.022

.03
.10
.97
73
70
.32
45
49
16
24
82
62

0.000
0.943
0.949 J
0.958
0.966
0.970
0.976
0.934
0.991
0.995
1.001 12378-PeCDD AN
1.004
1.015

0.869-1.131

98
0.000
1.000 13C12-PeCDD 123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:28 01/15/98
                                                                                               2S3

-------
 Page No.
 01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Ratio / Ret.  Time
 Compound/
 M_Z....  QC.Log Omit Why ..RT.  OK  Ratio Total.Area... Area.Peak. 1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.


368-370
HxCDF
374-376











AX
AN
M
374-376
13C12-HXCDF
384-386









384-386

HxCDD
390-392









390-392
30:38
DC SN 31:08
2 Peaks
1
RO 1

.44
.86

1.05-1.43
DC NL 0:00.
31:56
32:04
32:14
32:22
32:31
32:42
32:53
33:00
33:07
33:17
33:30
X 34:14
34:13
34:23
14 Peaks

DC NL 0:00
32:53
32:59
DC SN 33:14
33:30
33:58
DC SN 34:04
DC SN 34:06
34:13
34:32
6 Peaks

RO 2
1
1
1
1
1
1
1
1
1
1
1
RO 0
1
1

0.43
RO 0
0
0
RO 0
0
RO 0
RO 0
RO 0
0
0


.05
.23
.25
.35
.25
.35
.30
.25
.28
.32
.28
,28
.89
,05
.13

-0.59
.69
.51
.51
.28
.52
.36
.36
.35
.51
.45


1.05-1.43
DC NL 0:00
DC SN 32:16
32:25
32:51
33:05
33:14
DC SN 33:25
33:36
33:42
34:00
7 Peaks
RO 0
RO 0
1
1
1
1
RO 0
1
1
1

.63
.40
.20
.21
.22
.18
.97
.20
.17
.22

197.38
3.16
2,102.28
: PeCDD /

15.64
827.01
2,526.81
158.69
294.32
169.30
21.48
2,405.04
1,036.67
203.55
381.82
1,063.71
16.01
51.30
301.00
9,461 .71

6.69
2,212.34
2,404.41
2.99
2,301.46
6.69
1.24
1.92
1,975.42
7.33
8,907.65
Vvc HP /
ruci- uf f
4.06
2.69
215.13
928.63
446.31
48.42
1.28
75.43
134.74
208.77
2,057.43
116
.38
31
.00
1.004
1.021
HxCDF Follows -——

0.
964-1.049
0.000
464
1,403
91
163
97
12
1,338
581
115
214
599
3
26
163



744
309

784
3


665
2

.77
.61
.20
.23
.13
.14
.19
.97
.80
.14
.19
.36
.30
.00



.50
.29

.58
.81


.00
.28

362
1,123
67
131
72
9
1,066
454
87
167
469
10
25
138



1,467
1,595

1,516,
4.


1,310.
5.

.24
.20
.49
.09
.17
.34
.85
.70
.75
.68
.52
.00
.00
.00

0.

.34
.12

.88
.43


;42
05

0.968
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.

379-
0.
0.
1.
1.
1.
1.
1.
1.
1.
1 .

972
977
981
986
991
997 123478-HxCDF AN
001 123678-HxCDF AN
004
009
016 234673-HxCDF AN
038
040 123789-HxCDF AN
042

1.121
000
997 13C12-HXCDF 473 SUR3
000 13C12-HXCDF 678 IS4
008
016 13C12-HXCDF 234 ALT2
030
033
034
040 13C12-HXCDF 789 ALT1
047





J





J
PR,














Wv(™T"M"1 TTrtl 1 /^(jo



117,
508.
245.
26.

41.
72.
114.



,33
66
,57
23

16
63
71



97.
0.958-


80
419. "97
200.
22.

34.
62.
94.

74
19

27
11
06

0.
0.
0.
0.
0.
0.
0.
0.
1.
1.

1.015
000
958
962
975
982
987
992
998 123473-HxCDD AN
000 123678-HxCDD AN
009 123789-HxCDD AN







J



PR

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:28 01/15/98
                                                                        294

-------
  Page No.
  01/15/98
Listing of T980159B.dbf
Matched GC Peaks /  Ratio / Ret.  Time
  Compound/
  M_2.... QC.Log Omit Why ..RT.
    OK Ratio Total.Area... Area.Peak.1..  Area.Peak. 2. . Rel.RT Compound.Name..  ID.. Flags.
Fl3C12-HxCDD
402-404










402-404

HpCDF
408-410



D



408-410

13C12-HpCDF
^ '.3-420
•



413-420
HpCDD
424-426








424-426
13C12-HpCDD
436-438


DC
DC

DC
DC



DC
DC'
DC



DC



D

DC
DC



DC



DC


DC
DC

DC
DC

DC
DC
DC


DC


NL
SN

SN
SN



SN
SN
SN
4


NL
i
1

NH
•
WH
.WH
4
1

NL

I

SN!
3
1
I

NL
WL

SN:
SN

WH
WH
WH1
2

NL


0:00
32:51
33:04
33:12
33:20
33:35
33:41
34:01
34:17
34:23
34:27
Peaks


0:00
36:00
36:17
36:26
36:57
37:37
38:00
38:07
Peaks


0:00
36:00
37:37
37:51
38:13
Peaks

0:00
36:09
36:18
36:36
36:52
37:05
37:26
37:33
37:40
Peaks

0:00
36:18
1

RO
RO
RO
RO
.05-1.43
1
0
0
1
0
.36
.55
.69
.71
.17
1.16

1
.18
1.16
RO
RO
RO


0
RO



RO


RO


0.
RO


RO
RO

0.
RO
RO

RO
RO

RO
RO
RO

0.
RO
RO
2:54
0,
4.


.83
.60


2
1
7
1
0
1,710
2,032
2,245
4
3
2
5,996

.88-1.20
5.
1.
1.
1.
0.
1.
0.
0.


37-
1.
0.
0.
0.
0.

53
13
00
06
66
02
94
83


•0.51
02
44
44
31
69

1
3,070
650
697
6
422
2
2
4.340

.95
.52
.66
.86
.67
.49
.61
.55
.50
.70
.33
.31
D / Hp

.59
.18
.69
.12
.20
.23
.52
.75
.22

0.970-1.030
0
0
4.24 6.17 0
0
0
918.99 791.50 0
1,102.35 930.26 1
1,204.51 1,041.04 1
1
1
1


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.986
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.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
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0.998-1.053
0
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1,627.99 1,442.19 1.000 1234673-HpCDF

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325.41 325.28 1.008
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AN







Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:28 01/15/98
                                                                        2S5

-------
  Page  No.
  01/15/98
Listing of T980159B.dbf
Hatched GC Peaks / Ratio  /  Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why  . .RT. OK  Ratio  Total .Area. .. Area.Peak. 1. .  Area. Peak. 2.., ReL-RT Compound. Name..  ID..  Flags.
  436-438
  OCDF
  442-444
 442-444
 OCDD
 458-460
 458-460

 13C12-OCDD
 470-472

 470-472


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC


DC

DC
DC


DC


3

ML
WL
ML
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN


SN
2

NL

SN
SN
1

NL

1
37:05
37:22
Peaks

0
35:
35
35:
37:
37:
37:
38:
38:
39:
40:
40:
40:
41:
41:
41:

:00
:34
:47
:57
:05
20
:37
:53
;58
48
:02
:08
15
:10
28
49
0
RO
RO
RO
RO
RO
RO

RO
RO

RO
RO
RO

RO
RO
1.
1.
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1.
1.
1.
9.
2.
3.
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1.
1.
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20 5.59
1.824.41
Above • HpCDD /
1.02
95
63
21
75
75
47
95 '
38
15
33
22
14
70
39
33
57
Peaks

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22
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34
63
19
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2,407.
2,407.
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.98
.97
.86
.95
.93
.59
.67
.17
.85
.34

.47
.70
.74
,65
.70

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46
.46
                                    928.65
                                      3.05
                                                                            885.7*  r.OOO 13C12-HpCDD  678  IS7
                                                                              2.54:  E_OQ8
                                                       Octa-CDD and CDF Follows 	
                                                              826.32
                                                                9.61
                                                 92 6.. 35'.
                                                   6:97'
                                                     Q:.9XI2'-:1,,098
                                                         0.-..OOO
                                                         (£..369
                                                         OX ST74
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                 t. 0-2:2
                                                              263.77
                                                                           313..93  E..OOO  OCOD
                                                                                   r.. .028:9-
                                                                                                          AN
                                 1,144.82
                                               1,262 ..64'
                                                         a . .000
                                                         t. OOO 13CT2-OCDD
                                                                                IS3
 Column Description.
       "Why" Code Description	  QC Log Desc.	
 M_Z   -Nominal Ion Mass(es)
 ..RT. -Retention Time  (mm:ss)
 Rat.l -Ratio of M/M+2  Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
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TSIANGLX LASS Text :TLI#44 376 129-132 JK7. TIME - 20:43
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376 129-133 HKT. TIME - 30:43
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TRIANGLE LABS Text:TLI*44376 129-132 XK7. TIKE - 20*43
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TRIANGLE LASS TaxttHJ #44375 129-132 XKJ. TIKE - 20:43
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TRIANGLE LABS Text:TLIf 44376 129-132 HKT. TIKE - 20:43
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TRIANGLE LABS Text :TLI #44376 129-132 INJ. TIKE - 20:43
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TRIANGLE LABS Teit:TLI#44376 129-132 INJ. TIKE - 20:43
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TRIANGLE LASS Text: TLI #44375 125-132 XKT. TIKE - 20:43
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TSIANSLE LABS Text:TLI*44376 129-132                        HKT.  TIME -   30:43
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TSIANSLE LASS  Text:TLI#44376 129-132                       IJKT. TIME -  20:43
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-------
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TRIANGLE LABS Text:TLH44376
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TRIANGLE LABS Text:TLI»44376
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0 31:12 31:24 Tine
300

-------
Tile:T9aoi59  #1-396 Acq:6-J3UT-98 20:40:49 EI+ Voltage SIS  70T Noises 7142
373.8208 F:3  BSUB(256,30,-3.0)  PJO>( 7,5,3, 0.05\,28568. 0,1.00\,F,T) Stp:HDB5US
TRIANGLE LABS Text:TLI#44376 129-132                       UKT. TDOC -   20:43
100^     A1.40E7

                                  A1.34E7
  80:
  so:
  40:
  20:
   o.
A4.65.
  A
        32
                  Al . 63X6
                                                     A5.99E6
                                               A2.14S6
           00
                                       33:00
                                                                     34:00
File:T980159  #1-396 Acqt6-JMT-98 20:40:49 EI+ Voltage SIS  70T Noiae:3488
375.8178 r\:3  BSUB(256,30,-3.0)  fXD(7,5,3, 0,05\,13952.0,1.00\,F,T) EXp:NDB5US
TSIANGLE IAB9 Text:TLH44376 129-132                       XK7. TINE -   20:43
         A1.12E7
1001
  sol
  sol
 20.
     A3.62$
       A
        33
File:
383.8639 F
TSIANGLE
1001
  80.

  60:

  401

  20:

   ol
                                  A1.07E7
                  A1.31S6
                                                                               Al . 69E6
           00                          33:00                          34:00
     19801*59  #1-396 Acq:6-JXN-98 20:40:49 EI+ Voltage SIS  70T Noise: 1520
           3  BSUB(256,30,-3.0) PKD(7,5,3,0.051,6080.0,1.00\,F,T) Exp:NDB5US
                Text:TLI#44376 129-132                       ZJKT. TIKE -   20:43
                                     A8.Q9E6         A7.85E6
    UBS
                                                                             A6.65E6
        33JOO  I                        33:00                         34:00
File:T980159  #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T Noiae-,2217
385.8610 Ft3  BSUB(256,30,-3.0) PKD(7,5,3, 0. 05%, 8868.0,1. 00*,F, T) Eip:SDB50
TXXANGLE TABS \Text.:TLIt44376 129-132                       XK7. TIME »   30:43
100^                                  Al  60E7        A1.52E7
                                      1   \
  aoj

  60:

  40:

  20:

   o.
                                                                             A1.31S7
        32i00                          33:00                         34:00
File:T980159  #1-396 Acq:6-JAN-9a 20:40:49 EI+ Voltage SIS 70T
392.9760 F:3  Exp:NDB5US
TSIANGLE LABS .Text:TLI#44376 129-132                       INJ. TIME "   20:43
lOOlt      I    33:13 33:34 33:35 33:47   ,33j06     33:26                 34:09
                                                                                  34:26 34:38
 4.5E6

.3.SS6

.2.7E6

.1. 8E6

.8.9KS
                                                                                                 O.OEO
                                                                                                    Time
                                                                                                 3.6E6

                                                                                                .2.9E6

                                                                                                '•.2.2E6

                                                                                                .1.SE6

                                                                                                 7.3E5
                                                                                                      O.OEO
                                                                                                         T±xe
                                                                                                .2.5E6

                                                                                                .2.0E6

                                                                                                .1.5E6

                                                                                                .9.8E5

                                                                                                .4.9E5

                                                                                                .O.OEO
                                                                                                    Time



                                                                                                .4.9E6

                                                                                                3.9E6

                                                                                                2.9E6

                                                                                                1.9E6

                                                                                                9. 7E5

                                                                                                O.OEO
                                                                                                    Time
                                                                                                .7_.6E6

                                                                                                .6.1E6

                                                                                                4.6E6

                                                                                                3. OE6

                                                                                                1. 5E6

                                                                                                O.OEO
                                                                                                   Time
 80:
        33}00                          33:00                         34:00
rile:T980159  #1-396 Aeq:6-JAlf-98 20:40:49 EI+ Voltage SIS 70T
445.7555 F
-------
              il-396 Aeq:6-JKS-98  20:40:49 ET+ Voltage 3I& 70T Soia»>1127	
\3B9.8156 T:3  3303(356,30,-3.0) PXO(7,5,3, 0.05%,4508.0,1.00\,r,T) XxptXDBSUS
TSIAHGLX LABS Tfxt:TLH44376 129-133                       XK7. jj^g .   30-43
100$                    AS. 99X8
  aoJ
  50J
  401
      A1.17E6
       A
                                 A3.46E6
                                                     A7.26X5
                                                  WY
                               A1.15E6
       32,34    32:36   32:48   33:00   33tl2   33:24   33:36   33:48    34:00    34:12   34\24
\r±le:T980159  tl-396 Acq: 6-JAlf-9 8  20:40:49 SI+ Voltage SIS 701 Soiat>:1660
391.8127 r:3  BSUB(2S6,30,-3.0) PKD(7,S,3,0.05\,6640.0,1.00\,T,T) Xxp:SDB5VS
XXIAHGZX LABS  Ttat:TLH44376 129-132                       lyj-. TUB .   20-43
1001                    A4.20E6


  80.


  60.
 20:

   0.
A9.78E5
  A
                                A2.01E6
A2.22ES
               A3.
                   A6.21E5
                               A9.41E5
       32:24    32i36   32'i48   33:00   33:12   33:24   33:36   33':43   34': 00    34': 12   34':24
rile:T980159 il-396 Acq:6-Jjat-98 20:40:49  EI+ Voltage SIX 70T Noiae:852
401.8558 F:3 BSUB(256,30, -3.0) PKD(7,5,3, 0. 05*,3408. 0,1. 00%,T, T) Ezp:SDS5nS
TRIANGLE LASS  Text:TLI#44376 129-132                        XK7. TIME -    20:43
1002
  80J
 SOJ
                                                          A1.10E7
                                                                       A1.20E7
                                                      A9.19E>
       32': 24    32': 36   32:48   33:00   33:12   33:24   33:36   33:48   34:00   34': 12    34:24
Tile:T9801S9 tl-396 Acq:6-JAN-98 20:40:49  Eli-  Voltage SIX 70T Noise: 625
403.8529 F:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0.05%,5500. 0,1.00%,F, T)  Exp:«DB5as
TRIANGLE LABS  Text:TLIt44376 129-132                        IK7.  TIME *    20:43

                                                          A9.30E6       A1'04"

  so:

  60.

  40.

  30.
       32:24    33:36   32': 48   33:00   33:12   33:24   33:36   33:48
r±le:T980159  tl-396 Adj:6-J7OT-98 20:40:49  Eli-  Voltage SIX 70T
392.9760 T:3  ExptXDBSVS
TRIANGLE LABS Taxt:TLIf44376  129-132                        IW7.  TIME -   20:43
                                                                 34:00    34': 12    34:24
1001
 ao:

 60.

 40.

 20.

  0.
      33:24   32:35   32:47
                                   33:06
                                             33:2.
                                                 33126
                                                        1:35
                                                              33:55
                                                                             34:09 34:17
                                                                                         34:26
                                                                                          _!.7X6


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.3.5E6


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.2.1E6


.1. 4E6


.6.9E5


O.OEO
    Tim



3. OE6


2.4E6


1. 8E6


1.2X6


6.1E5


0.0X0
    Time
         32:36   3348   33:00
                                               '33:24 '  '33\36 ' '33i4~a~' *"/
-------
Tila:T980159 #1-563 Acq:6-JAlf-9a 20:40:49 EH- Voltage SIS 70T Boia*i21SS
407.7818 f:4 BSUB(2S6, 30, -3. 0) PXS(7,S,3,0 ,05\, 8620.0,1.
TRIANGLE LABS Text:TLIt44376 129-132
1001
00:
60.
40.
20:
o-
Al . 63E7
A
A


/ \ A3.59E6
J v yv/v
00\,r,T) ExptNDBSVS

HU. TIME - 20:43





A2.14E6
^^
36\00 36:12 36\24 36:36 36:48 37:00 37:12 37:24 37\36
4.3E6





.3.4E6
.2.6E6
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37\48 38:00 38:12 Time
rlle:T980159 tl-563 Acq:6-J7OT-98 20:40:49 SI+ Voltage SIS 70T ttoia»:389
409.7789 T:4 BSUB(256, 30, -3. 0) PXO(7,5, 3, 0. 05%, 1556.0,1 .00\,f,T) Sxp:XDB5US
TRIANGLE LABS Text:TLIt44376 129-132
1003
00:
so:
40:
'•
3 0^
0 '
A1.44E7 ;
A


/ \ A3.25E6
1 { A/\
HU. TIME " 20:43





A2.09E6
36':00 36:12 36:24 36:36 36':48 37\00 37\12 37\24 37\36

-3.6E6





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37:48 ' 3 31: 00 ' 38\12 Time
rile:T980159 tl-563 Aeq: 6-JKH-98 20:40:49 EI+ Voltage SIS 70T Koiae: 1057
417.8253 r:4 BSUB(256, 30, -3. 0) PXD( 7, 5, 3,0 .051,4228.0,1.
TRIANGLE LABS Text :TLI §44376 129-132
1001
80:
60:
40:
20:
o:
A5.27E6
A 1
l\ '
\ i

/ \
/ V
00\,r,T) Erp-.NDBSOS
ISJ. TIME - 20:43

A4 . 39E6
A
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37^:48 ' 3S': 00 3a':12 Time
file:T980159 #1-563 Acq:6-JAN-98 20:40:49 EH- Voltage SIS 70T Soiae: 1029
419.8220 F:4 BSUB( 256, 30, -3. 0) PKD( 7,5, 3, 0. 051,4116. 0,1 .
TRIANGLE LABS Teit:TLIi44376 129-132
loot
ao:
'
60:
40.
20:
o:
A1.31E7
A
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36:00' ' '36:12 ' '36:24 36':36 ' 36^48 ' 37\00 ' 3
00\,f,T) Exp:NDBStJS
HKT. TIME - 20:43


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37{:48 ' 38{:6d ' '38':12 Time
rlle:T930159 tl-563 Acq: 6-JAN-98 20:40:49 EH- Voltage SIR 70T
430.9729 r:4 Exp-.XDBSUS
TRIANGLE LABS Text:TLIt44376 129-132
1001
80:
60:
40:
20:
o:
36.0536:12 36:25 ^l^^t^i^^L-^-^.
i/> .s^x-A— -S~\ f/*~^^r^**~*—*+/*^'^ v~^V^>-^^^- \~*-^
\l

-


HKT. TIME - 20:43
':11 37:2237:29 37:38
•r^>*— ^X" 	 *~s^\sv*S^—~ "





36:00 '36:12 36:24 36:36 36:48 J7.-00 37\12 ' '37:24 ' '37\36


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-2.1E6
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37\ 48 ' 38\00 ' '38\12 Time
rlle:T980159 tl-563 Acq:6-J3UT-98 20:40:49 EI+ Voltage SIS 70T
479.7165 r:4 Exp:lO>B5OS
TRIANGLE LABS Text:TLIt44376 129-132
1001
80:
60:

40:

20:
0:

36:10
\ ' i

rt AM K 37 i M I flA i i
A I\ IIU 1 36:21 A IM I l\l\ A I
-JvW U " LA^1^ UWr^ UUvAj


XK7. TIKE - 20:43


,_ ,, 37:28
3.7:16 t
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-4.8E3

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37': 4 8 ' 38:00 3 a': 12 Time
303

-------
rile
423.
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1001
80.
60.
40.
20.
0
3
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425.
TSIA
1001
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50;

-------
Tila:T98dl5$  ti-563 Acii:3-JAlT-9a 36:40:49 SI+  Voltage SIS 70T Hoiaoi£27
441.7438 F:4  BSUB(2S6,30, -3.0) PXD(7,5,3,0.05^,2508.0,1.00\,F,T)  Xzp:SDB5US
TSIAHGLE LABS  Taxt:TLIf44376 129-1.32                        UKT.  TIMS -   20i43
1003
 901
 80J
 7ol
 SO.
 SOI
 401
 301
 201
 102
                                                                     AS.26X6
              36:00         37:00         38:00        39:00         40:00
r±le:T980159  fl-563 Acq:6-JAN-98 20:40:49 XI+ Voltage SIS  70T Koise:319
443.7399 r:4  BSUB(256, 30, -3. 0)  P1O3(7,5, 3, 0. 05%, 1276. 0,1 .00\,f,T)  KipsSDBSUS
TRIANGLE LASS Text:TLH44376 129-132                        OTJ.  TIME -   20:43
1003
 901
 80.
 601
 SOI
 40.
 3ol
 201
 101
  01
                                                                   41:00
                                                                    A9.26E6
                                         _J. 5S6
                                         '•-1.4Z6
                                         11.2X6
                                         11.1E6
                                         '.9.2X5
                                         17.6ES
                                         16.1X5
                                         14.6X5
                                         .3.1X5
                                         .1.5X5
                                        $.0.0X0
                                    42:00    T±a.
                                                                                      -1.7X6
                                                                                      '.1.SE6
                                                                                      .1. 3E6
                                                                                      .1.2E6
                                                                                      .1. OE6
                                                                                      .8.4X5
                                                                                      .6.7X5
                                                                                      .5.0ES
                                                                                      .3.4X5
                                                                                      ll. 7X5
              36:00         37:00         38:00        39:00
Tila:T980159 tl-563 Acq: 6-JZN-98 20:40:49 EI+ Voltage SIR  70T
430.9729 f:4 ExptHDBSUS
                                                                     40:00
                                                                                  41: 00
                                                                                                     .0.0X0
                                                                                                42:00    Tin,
TRIANGLE LABS
1001
 901
 801
T&xt:TLH44376 129-132
                   37:29
  36:12
 INJ.  TIKE -   20:43
39:23.        40:20
         47
41:08 41:34
              36:00         37:00         38:00        39:00
rlle:T980159 #1-563 Acq:6-JAS-98 20:40:49 EI+ Voltage SIR 70T
513.6775 T:4 Exp:KDB5JJS
                                                      40:00
                                                                                  41:00
                                                                                     f.O.OXO
                                                                                 42:00    lime
TRIANGLE LABS
100*
Tejct:TLH44376 129-132
36 05
                                                             JW7. TIME -   20:43
              36:00
                            37:00
                                         38:00
                                                       39:00
                                                                     40:00
                                                                                  41:00
                                                                                      -.0.0X0
                                                                                 421 00    Tlat
                                                                                              305

-------
                                                                              41:24
         40:54          41:00         41:06         41:12         41:18
rile:T9801S9 tl-563 Actj:6-JAS-98 20:40:49 EH- Voltage SIX  70T Soiae:113
469.7779 F:4 BSUB(256,30, -3.0)  P!CD(7,5,3, 0. 051,452. 0,1. 00\,T,T) ExpsNDBSVS
TRIANGLE LASS  Teit:TLI»44376 129-132                       INJ. TIME -   20:43
1004        A1.14E7
fU.e:TyauJ.5S  #1-56J ACIJ s 6-JAa-9 8 20l40i49 Elf Voltage  SIS 70T Hoiae:110
457.7377 Ti4  BSUB(256,30, -3. 0) PXD(7,5,3, 0. 05\,440.0,1. 00\,r,T)  SxptUDBSUS
TBIAHSLX LABS  Text:TLIt44376 129-132                        UU.  TIME '   20:43
100*
  BO.
  60.
  40.
  30.
                                                                                                 -4.9X5

                                                                                                 .3.9E5

                                                                                                 .2.9E5

                                                                                                 .2.015

                                                                                                 .9. 8E4
                                                                              41:24
         40:54         41:00         41:06         41:12         41:18
rile:T980159  tl-563 Acq:6-J1UT-98 20:40:49 XI + Voltage SIS  70T SO±ae:191
459.7348 F:4  BSU3(256, 30, -3.0)  PXD(7,5,3, 0.05%, 754. 0,1.0Q\,T, T) KxpsSDaSUS
TRIANGLE LASS  Text:TLI944376 129-132                       nu. TIKE -   20:43
IOCS          A3.19E6
                                                                                                 .O.OEO
                                                                                            41': 30    Tiae
                                                                                                 .4. SE5

                                                                                                 .3. 6E5

                                                                                                 12.4E5

                                                                                                 -1.2ES
                                                                                                 '.O.OEO
                                                                                            41:30    Tiae
                                                                                                 2.1E6

                                                                                                 .1. 7E6

                                                                                                 '.1.3E6

                                                                                                 .8.6E5

                                                                                                 -4.3E5
         40:54          41': 00         41:06         41:12         41:18         41:24
File:T980159 »l-563 Acq:6-JJOT-98 20:40:49 EH- Voltage SIS  70T Koiae:70
471.7750 f:4 BSUS(256,30,-3.0)  PKD(7, 5, 3, 0. OS\e280. 0,1. 00\,F, T) Exp:»DB5US
TSIANSLE LASS  Text:TLI#44376 129-132                       ZK7. TIME -   20:43
1004         A1J6E7
                                                                                           41:30
                                                                                                 .O.OEO
                                                                                                    Time
                                                                                                 2.4E6

                                                                                                 .1. 9E6

                                                                                                 .1. 4E6

                                                                                                 .9. 4E5

                                                                                                 '.4.7E5
         40:54         41:00         41:06         41:12         41:18
rile:T980159  fl-563 Acq:6-JAir-98 20:40:49 Eli- Voltage SIX 70T
430.9729 T:4  Exp-.SDBSOS
TSIAKSLE LABS  Text:TLH44376 129-132                       HKJ. TIME -
                                                                             41:24
                                                                                           41:30
                                                                                                 O.OEO
                                                                                                    Time
                                                                           20:43
1001

 80.

 60.

 40.

 20.

  0.
                                                                     41:20
                                                                                                _5.4E6

                                                                                                -4.3E6

                                                                                                .3.2E6

                                                                                                .2.2E6

                                                                                                .1.1E6

                                                                                                 O.OEO
         40:54
                       41:00
                                    41:06
                                                  41,12
                                                                41:18
                                                                             41:24
                                                                                           41130
                                                                                                 306

-------
On*   I  338,3792     Peak top
Height  3.59 flits  Span   288 ppa

Systa file nsae
Data  filename         fi:
Resolution                  18888
                              2
                            El*
                         VOLTflGE
loniation tode
Snitching
Ref, lasses  82,3825,   416,3768
A   293     J' 331     6   368
           K   332
           L   334
           fl   348
           H   342
           0   352
           P   354
           Q   356
           R   358
8   384
C   386
D   316
E   318
f   328
6   322
H   328
                        T  378
                        II  376
                        V  418
    331
tef,  ias   416,3768    Peak top
Height   ,36 volts  Span   208 ppa
                                                           307

-------
 ile:T980159 #1-810 Acq:6-JAN-98 20:40:49 Elf- Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
 ample Text:TLI#44376 129-132                       INJ. TIME
100%                                  A1.90E6
     25:42  25:48  25:54 26:00  26:06  26:12 26il8  26:24  26:30
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME
100%                                  A2.44E6
    20:43  File Text:TLI#44376 129»
                          _2.6E5
                          _2.1E5
                          _1.6E5
                          L1.1E5
                          L5.3E4
                          LO.OEO
26i36 26142  26i48 26:54''    Time


    20:43  File Text:TLI#44376 129»
     25:42  25:48  25:54 26:00  26:06  26:12 26:18  26:24  26:30
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME
1004,                               26; 10
26:36  26:42  26:48 26:54
                                                                                   hO.OEO
                                                                                       Time
  60J
  40j
                                              26:20
    20:43 File Text : TLI#44376 129»
                          r_3.7E6
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                                                        26:30  26:36  26:42  26:48  26:54
                              Time
 Tirr

-------
File:T980159 fll-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
339.8597 F:2 Exp:NDB5US
Sample Text:TLIH44376 129-132                       INJ. TIME =   20:43 File Text:TLI#44376 129»
   28:54      29:00      29:06      29:12       29:18       29:24
File:T980159 ttl-810 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
341.8567 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME =   20
                                             29:30
                                             29:36
                                        LO.OEO
                                             Time
                                            43  File Text:TLI#44376 129»
                                                                1.9E6
              29:00      29:06      29:12       29:18       29:24
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
351.9000 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME =
lOOi

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                                             29:30
                                             29:36
                                             Time
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                                 43  File  Text:TLI#44376 129»
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-------
 lle:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text :TLI#44376 129-132                       INJ. TIME =    20:43  File Text :TLI #44376 129»
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                                                                                             Time
      33:54    34:00   34:06   34:12   34:18   34:24   34:30   34:36   34:42   34:48   34:54
File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME =    20:43  File Text:TLI#44376 129»
1004,                                   /"\                                                _1.6E6
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                                                                                             Time
File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME =
100&                             34;15
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                                                                   20:43 File Text : TLI #44376 129*
                                                                                          _1.4E4
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-------
'ile:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
 ample Text:TLI#44376 129-132
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                                       INJ. TIME =
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                                           20:43 File Text:TLI#44376 129»
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File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EH- Voltage SIR  70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME
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File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR  70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132                        INJ. TIME
100%                              34^18
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                                                      34:36
                                                      34:42
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                                                           Time
                                                      20:43 File Text:TLI#44376 129»
  0.
  34:00
34:06
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-------
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME =
                                                                                                   CJ
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                                                                                                   CO
                                                                 20:43 File Text :TLI#44376 129*
                                                                                       _1.3E4
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File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132                       INJ. TIME =
                                                                                        O.OEO
                                                                                    29:00 Time
                                                                 20:43 File Text :TLI#44376 129»
                                                                                       _1.9E5
                                                                                       _1.5E5
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26
                              27:00
28:00
29
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_O.OEO
00  Time

-------
TLI Project:     44376
Client Sample:   129-132
                                         Method 23 TGDD/TCDF Analysis (DB-225)
                                   '                          Analysis File:  P980167
Client Project: Culp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97 Spike File:
TLI ID: 194-59-7A-7D Date Extracted: 12/29/97 ICal:
Date Analyzed: 01/10/98 ConCal:
Sample Size: 1,000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a % Moisture
Blank File: X980083 % Lipid:
Analyst: WK % SoUds:
SPC2NF04
PF22206
P980164
: n/a
n/a
n/a


;Arta*Sffc» v - * *
2^,7,8-TCDF
f \
'Internal Standard
13CI2-2,3,7,8-TCDF
Recovery Standard
•?CU-1A3,4-TCDD
AmM&t) >^-^*^;; -\,ii«|H>^ -:^ mte --,
0.83 0.75
Amt (ng) % Recovery OC Limits '-• Ratio ,
3.0 , 74.3 40%-130% 0.78
Ratio
0.81
81V ,
23:04
RT
23:03
«T
21:53
Ftegs
• — '
Flags
—
Flags

                     Data Reviewer.
                                                            01/11/98
                                        Page 1 of 1
                                                                         C2NFJ>SR rZOI. LARStf.IO.OB
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                      Printed: 13:35 01/11/98

-------
                         Initial
                                  	Date...
  Data Review By:
          I  /tf X#   Calculated Noise Area:   2.00
  The Total Area for each peak with an ion abundance ratio outside
  ratio  limits has been recalculated according to method requirements.
  Page No.
  01/11/98
Listing ot P980167B.dbf
Hatched OC Peaks  /  Ratio / Ret. Time
  Compound/
  H_Z	QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.

  TCDP
  304-306
 304-306
 13C12-TCDP
 316-318
DC
DC
































DC
NL 0:
WL 18:
18:
18:
18:
18:
19:
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
21:
21:
21:
21:
21:
22:
22:
22:
22:
23:
23:
23:
23:
23:
24:
24:
25:
WH 25:
0
00
13 RO
:27
39
43 RO
55 RO
05 RO
27
34
42
53
59
09
18
26
35
45
08
24 RO
34
41
49
03
19
28
56
04
16
32
40
53 RO
27
35
12
38 RO
.65-0.39
0.35
0
0
0
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.64
.82
.75
.46
.03
.10
.73
.74
.75
• 75
.84
.73
.34
.74
.76
.70
.74
.38
.74
.74
.73
.74
.77
.74
.74
.75
.73
.75
.75
.92
.73
.65
.69
.49
32 Peaks

DC
DC
DC
DC
DC

NL 0:
WL 19:
WL 20:
WL 20:
WL 20:
0.
00 RO
17 RO
06
41 RO
44
3
10
572
11
12
11
41
587
556
1,086
458
66
499
1,089
561
1,541
532
3,113
4.
659,
131.
652.
652.
133.
790.
610.
457.
695.
815.
649.
2.
439.
11.
83.
3.
17,535.
.93
.48
.17
.34
.85
.35
.47
.52
.15
.41
.67
.82
.99
.96
.87
.69
.91
.05
.90
.89
.46
,64
50
93
,80
31
56
61
82
00
69
64
58
30
72
85
0.793-1.101
0.000

258
4
10
6
25
247
237
463
197
30
211
498
239
665
218
1,323
2
280
55
275
277
58
336
259
196
292.
350
278
1,
185,
4.
33



.25
.87
.59
.62
.75
.72
.12
.88
.25
.50
.15
.39
.28
.57
.95
.90
.13
.51
.93
.74
.25
.15
.87
.30
.23
.53
.24
,94
.40
.13
.56
.98



313
6
7
6
23
339
319
622
261
36
288
591
322
876
313
1,789
5
379
75
376
375
75
453
351
261
403
465
370
1,
254,
7
49,


65-0.89
1
0
0
2
0,
.30
.31
.85
.16
.79
2.
3.
4.
0.
1.
is
20
87
57
45
















.92
.47
.26
.41
.43
.80
.03
.53
.42
.32
.84
.07
.59
.12
.96
.15
.64
.38
.53
.90
.25
.78
.93
.01
.33
.08
.58
.06
.52
.51
.02
.32
•

0.790
0.800
0.809
0.812
0.821
0.828
0.344
0.349
0.855
0.363
0.867
0.874
0.381
0.386
0.893
0.900
0.917
0.928
0.936
0.941
0.946
0.957
0.968
0.975
0.995
1.001 2378-TCDF
1.009
1.021
1.027
1.036
1.061
1.067
1.093
1.112

0.957-1.043





0.000
0.837
0.872
0.897
0.399
                                                                                                     AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 1
M/11/98

-------
  Page No.
  01/11/98
Listing of P9801S7B.db£
Hatched OC Peaks / Ratio  / Ret. Time
  Compound/
  M_2	  QC.Log Omit why  ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
  316-318
DC
DC
DC
DC
DC




DC
DC
DC

ML
WL
WL
WL
WL



'
WH
WH
WH
4
21:17
21:33
21:46
21:51
21:54
22:14
23:03
23:25
23:41
24:07
25:11
25:30
Peaks
RO
RO

RO
RO
RO

RO
RO
RO

RO

1.
0.
0.
0.
1.
0.
0.
1.
1.
1.
0.
13.

30
49
68
34
17
62
78
08
02
12
32
46

3
9
8
0
1
3
2,129
7
5
3
18
0
2,145
.17
.19
.19
.92
.13
.29
.71
.20
.17
.22
.56
.46
.37


1.43
932.51
4.39
2.99




2.29
1,197.20
4.07
2.92


0.923
0.935
0.944
0.948
0.950
0.965
1.000
1.016
•1.027
1.046
1.093



13C12-2378-TCDF ISO




                                                                                  1.106
  13C12-TCDD
  332-334
  332-334

DC




DC
DC
DC
DC


NL
1
i

I
SN
WH
WH
WH
14

0:
20:
21:
21:
22:
23:
23:
24:
24:

00
23
36
53
40
16
49
15
26
0.
RO
RO



RO
RO
RO
RO
65-0.39
1
0,
0,
0,
0,
0.
1.
2.
0.
.91
.57
.80
.31
.78
.45
,03
,69
.52
Peaks
                                        Above:  TCDP /  TCDD Follows
                      1.33
                      5.95
                  1,601.64
                  2,064.30
                     19.30
                      2.69
                      1.73
                      1.59
                     10.99
                  3,691.69
                                                              2.59
                                                            711.99
                                                            925.16
                                                              8.48
0.
4.53
889.65
1,139.64
10.82
907-1.093
0.000
0.948
1.000 13C12-2378-TCDD
1.013 13C12-1234-TCDD
1.049
1.077
1.103
1.123
IS1
RSI
                                                                                  1.131
  Column Description. . . .1	  'Why Code Description	  QC Log Desc.
  M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time (mm:ss)
  Rat.l -Ratio of M/M+2 |Ions
  OK    -RO=Ratio Outside Limits
  Rel.RT-Relative Retention Time
     End of Report **
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
FlJ.e:P980167  #1-922 Acqi10-JMf-lyHa iJ:JOr«o ij*  Voltage SIR /UP nOlsesHOl
303.9016 BSU3(256,30,-3.0)  PKD( 5, 3,1, 0.10\, 3608. 0, 0. 00\,t, F) Exp:DB225
TRIANGLE LASS  Tejct:129-132   TLH44376
100*                                  Al    E7
  80.

  60.

  40.

  20.
                   A4. 64E6
                               A6.66E6
                           A4.99E6
                                            A2.81E6
                                                        A3.37E6
                                                                      A3.50E6
                                                                                  A1.BSE6
                                                                                    A
            13:00        20:00        21:00        22:00        23:00        24:00
File:P980167  #1-922 AcqilO-JJOT-1998 13:36:48 EH-  Voltage 3IS 70P Soise:1064
305.8987 BSUB(256,30,-3.0)  PKD( 5, 3,1, 0. JO*, 4256. 0, 0.00\,F,F) Exp:DB225
TRIANGLE LASS  Text: 139-132   TLI#44376
1003,                                  A1.79E7
  80.

  60.
                                                                                          25:00
  40.

  20.

   0.
                                                        A4.54E6      A4. 66E6
                                                             A3.51E6 ,
                                                                                 A2.55E6
           19:00        20:00         21:00         22:00        23:00         24:00
File:P980167 #1-922 Acq:10-JAN-1998 13:36:48 EH- Voltage SIR  70P Noise:792
315.9419 BSUB{256,30,-3.0)  PJO3(5, 3,1, 0.10%, 3168. 0, 0 . 00\, F, F)  Ejcp:DB225
TRIANGLE LABS  Text: 129-132   TLI#44376
                                                               A9.33E6
 80.

 60.

 40.

 20.
                                                                                          25:00
           19:00        20:00         21:00         22:00        23:00        24:00
File:P980167 #1-922 Acq: 10-JAN-1998 13:36:48 EI+ Voltage SIR  70P IToise-.Sll
317.9383 BSUB(256,30,-3.0)  PKD(5, 3, 1, 0.10\,2444 . 0, 0 . 00%, F,F)  Exp:DB225
TRIANGLE LABS  Text: 129-132   TLI#44376
IOCS                                                           A1.20E7
 80.

 60.

 40.

 20:

  0.
                                                                                          25:00
           19:00        20:00        21:00        22:00        23:00
File:P980167 #1-922 Acq:10-JAir-1998 13:36:48 EH- Voltage SIR 70P
375.8364 Exp:DB22S
TRIANGLE LABS  Text:129-132    TLU44376
.1001
                                                                            24: 00
                                                                                         25:00
 2.7E6


'.2.1E6

.1. 6E6

.1. 1E6

.5.3E5
                                                                                                       O.OEO
                                                                                                         Time
                                                                                                      O.OEO
                                                                                                         Time
                                                                                                      2.5E6

                                                                                                     ..2.0E6

                                                                                                      1.5E6

                                                                                                      1.0E6

                                                                                                      5.1E5
                                                                                                      O.OEO
                                                                                                         Time
           19:00
                        20100
                                     21:00
                                                  22:00
                                                               2J.-00
                                                                            24:00
                                                                                         25:00
                                                                                                  316

-------
\File:P9BOlS7 #1-922 Acq:10-JAlt-l99a U:3S:4a Et+ Voltage StR 70P ttoiae:531
319.3965 3503(256, 30, -3.0) PKD( 5, 3,1, 0.10\,2124 . 0, 0. 00%, F,F) Exp:DB225
TRIANGLE LABS Text: 129-132 TLI044376
1001
80.
60.

40.
20.
0
|
;
•
A2.66E6


A6.14ES
\\ 11 A AA A .
	 20; 00 ' .21:00






Al . 09E6
yv/V ^^_
1 . 1E6
'.8.6E5
'.6.SE5

.4.3E5
'.2.2ES
' 0 . OEO
22:00 ' 23': 00 ' ' 24:00 Time
File:P980167 #1-922 Acq -.10 -JAN- 1998 13:36:48 EI+ Voltage SIR 70P Soiae:786
321.8936 BSUB(2S6,30,-3.0) PKD( 5,3,1, 0.10%,
TRIANGLE LABS Text:129-132 TLI#44376
1001
80.
so:

40.
20.
0"
\

A3.39E6
ll

3144.0,0.00*,F,F) Sxp:OB22S






A8.10E5 A1.41E6
\\ A A &4.17ES A
/ I / I A A A A X-W V ^ ^
20:00 21 1-00
i . 4r5
11 . 1E6
.8.5E5

.5.7E5
-2.8E5
' 0 . OEO
22:00 2J:00 24:00 Time
File:P980167 #1-922 Acq: 10 -JAN- 1998 13:36:48 EH- Voltage SIR 70P Noiae:398
327.3847 BSUB(256, 30, -3 . 0 ) PKD(5, 3,1, 0.10%,
TRIANGLE LABS Text .-129-1 J2 TLI#44376
1003
80.
60.
401
20.
0.
Al.



'
Al . 02E6 1
.^^S ^» /
20:00 2lioO
1592. 0,0. 00%,f,f; Eip:DB225

(E7



12.57E6
A A1.30E6
J\ /\
3.4E6
.2.7E6
-2.0E6
.1 . 4E6
'.6.8E5
' 0 . OEO
22:00 ' ' '2J:00' ' ' ' ' 24\ 00 ' ' ' Tiae
File:P980167 #1-922 Acq: 10-JAN-1998 13:36:48 EH- Voltage SIR 70P Noiae:714
331.9368 BSUB(25'6,30,-3.0) PKD(5, 3, 1, 0.10%,
TRIANGLE LABS Text : 129-132 TLI#41376
100J
so:
50.
40.
20J
;
o:

2S56.0,0.00\,F,F) Exp:DB225

A9.25E6
i
A7.12£5



i
j
20 1-00 21:00

'


U V
-2.1E6
.1 . 7E6
-1.3E6
-8.4E5
-4.2E5

0. OPO
221-00 ' ' 2jl-0o' ' ' ' '24:00 	 Tiae
File:P980167 #1-922 Acq:10-JAN-1998 13:36:48 EH- Voltage SIR 70P Noiae:377
333.9338 BSUB(256, 30, -3.0) PKD(S, 3, 1,0. 10*, 1508.0,0 .00\,F,F) Exp:DB225
TRIANGLE LABS Text:129-132 TLI044376
1001
80.
60.
40.
20:
o:


J11.14Z7
A3.90E6\\
n I \



1
20:00 21:00



\l I
.2.6E6
.2.1E6
.1 . 6E6
.1 . OE6
.5.215
a nrn
^2l-00 23:00 ' 24.-00 rlae
31'

-------
rile:P9a0167 #1-922 Acq:10-JXlf-l998 1J.-JS.-48 EI+ Voltage SIS 70S
303.9016 Exp:DB22S
TRIANGLE LASS Teit:129-132 TLI044376
1001
80.

SO.
40.
20.
0
21: 08
f\
20:35 \
19:42 20:18 11 1
18:27 ":77(1 (1 I «
/I . M/lA/wlA 1 1 /
'l9\00 20 !• 00 ' 21: 00


1.9E6



,. 22:28 33:32
22 * OJ A A
UAJ MAM T ..
Ll . 6E6
^^k
:i.2^
:7.8Z^P
LJ.5JT5
' 0 . OBO
22:00 33': 00 24:00 25 .-00 Time
file:P980167 #1-922 Acq:10-JRlT-1998 13:36:48 EI+ Voltage SIS 70P
315.9419 Exp:DB22S
TRIANGLE LABS Tezt:129-132 TLH44376
1001
80.
SO.
40.
20.
0
.





19': 00 20': 00 211: 00


23:03 2.0E6




1 \
Ll . 6E6
.1.2E6
.8.2E5
-4.1E5
O.OEO
22:00 2J-00 . 24\ 00 25:00 . Tine
File:P980167 #1-922 Acq:10-JAN-1998 13:36:48 EI+ Voltage SIS 70P
319.3965 Eip:DB225
TRIANGLE LABS Text: 129-132 TLH44376
1003
aol
60.
40.
20:
0:
19:16
1

T°
i
20:53
11 A A^A A.21
IS. -00 20:00 21:00


C1.1E6



21 : 54
:38/\
r^fJ V ^ . 	
.3.6E5
'•.6.5E5
.4.3E5
.2.2E5
O.OEO
22I:00 23(:00 ' 24 1- 00 25:00 Tiae
file:P9a0167 #1-922 Ac?: 10-J7UI-1998 13:36:48 EI + Voltage SIS 70P
331.
TRIA
1003
aol

60:
40:
20:
oj
9368 Exp:DB225
NGLE LABS Text:129-132 TLI#44376
21.
.



1
isl-00 20:00 21 .' 00
21.53
36




V / I ^
_2.1fMl
_1 . 7E6

.1 . 3E6
.3.4E5
.4.2E5
O.OEO
22rOO 23I:00 ' ' ' 24 1-00 251-00 ' Tine
F±le:P9a0167 #1-922 Acq: 10 -JAN- 19 9 8 13:36:48 EH- Voltage SIS 7QP
292.9825 Exp:DB225
TRIANGLE LABS Tezt:129-132 TLI#44376
1001
80:
60:
40:
20:
oj
r\ -i£i.OS 19:35 20:05 20:55
\A w^V*1^ Fv^*i. . -"-^-^<^»**w^v^J%*% w*1/ST^j»A^-l*^/*^^^^/'^.*^A.
vy*^ \A f* \.^Tr>nr' ^M r^Ti YT^< r v^yvN
I



19:00 20:00 21:00


21:55 ^i^J 2J.-1S 23 : 58 24:27 25:14 ..9.1E6
r'**~*f*r*tvJ~~V~°'~r^l('^~*V*ir'l*^r'\fi'**s***^~~f\*r*n^^ '





-7.3E6
.5.4E6
.3.6E6
.1 . 8E6
O.OEO
22:00 23\0(> 24 ': 00 ' ' ' 25: 00 Tiae
File:P9a0167 #1-922 Ac
-------
I
Sfl
*l
5
Kfl
30
1


l
^^^™^^^^^H
^^^^^^^^^^

U

! Mi
M
ll^^^^H
•L


^^^^^^^^^^T

E^ClbZZ
Ref. lass 292.9825 Peak top
Hei# 1,48 wits Sp* 288ppi
Systei file nw 06225
Data file nan R>nOH&
Resolution IfiflfiA
Gnxfnuber 1
lonization lode El*
Suitching VOLTflGE
Ref, lasses 292,9825, 388,9761
ft 292,9825 J 338,9792
8 383.9816 K 331,9368
C 385,8987 L 333,9338
D 315,9419 H 375,8364
E 317,9389
F 319,8965
6 321,8936
H 327,8847
I 338,9792
Channel I 338,9782 Peak top
Height 1,92 volts Span 298 ppa
3V

-------
TLI Project:     44376
Client Sample:   133-136
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  T9801^
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-8A-8D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: CRV
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980160
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ng) DL EMPC
0.02
0.05
0.02
0.04
0.06
0.16
0.27
2.9
0.29
0.40
0.54
0.21
0.23
0.01
0.68
0.11
1.2

Amt {ng} Number Dt EMPC
4.4 10 4.4
0.83 7 1.5
0.72 6 0.74
0.32 2
24.0 16 24.0
7.3 16 7.3
2.3 13 2.3
1.1 4
Ratio
0.84
1.40
1.19
1.21
1.08
1.00
0.76
0.81
1.48
1.43
1.30
1.26
1.30
1.16
1.04
1.07
0.85










HT
26:21
30:30
33:36
33:41
34:00
37:05
40:57
25:41
29:29
30:11
32:53
32:59
33:30
34:18
36:00
37:36
41:10










Flags

;Z
J_
J_
PRJ

B_






PRJ




Flags



—
Q_



                                       Page 1 of 2
                         X237_PSRv2.01. LARS 6.101
Triangle Laboratories, lnc.«
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 09:28 01/15/98,

                         320

-------
TLI Project:      44376
Client Sample:   133-136
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:  T980163

13C,2-2,3,7,8-TCDF
l3C,2-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
I3C,2-l,2,3,6,7,8-HxCDF
13Cl2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
l3Cirl,2,3,4,6,7,8,9-OCDD
i

17CL-2,3,7,8-TC33D
l3C,:-2,3,4,7,8-PeCDF '
13C,2-l,2,3,4J,8-HxCDF '
13C,:-l,2,3,4,7,8-HxCDD!
l3Ci:-l,2,3,4,7,8,9-HpCDF
I
Pilfifr^^
13C,:-l,2,3,7,8,9-HxCDF
13Cr-2,3,4,6,7,8-HxCDF '
I
|||^ii|i|i^nial^s|^^i^^^
13C,2-1,2,3,4-TCDD ;
13C12-l,2,3,7,8,9-HxCDD

2.9
2.9
3.3
3.6
3.1
3.8
3.4
4.4
9.0

3.4
3.8
3.9
3.8
4.6
|||||l|ftg|lii
3.3
3.0




72.2
73.4
81.6
90.0
77.1
95.5
84.2
110
112

86.1
94.5
97.5
95.8
114
Ililli^iiG^^I
82.1
76.0

llllillllllllillllilil


40%-130%
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%-130%
25%- 130%
25%- 130%
25%- 130%
iP^limilill
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%

40%- 130%
40%- 130%

iis^^Swi:JiJ;«™::;ffi«S

iiHliioiil
0.75
0.80
1.41
1.46
0.51
1.20
0.44
1.02
0.90

1.45
0.51
1.23
043
|||l|it|ie>i|||
0.52
0.51


0.79
1.21

25:39 	
26:20 	
29:29 	
30:30 	
32:59 	
33:41 	
35:59
37:04
40:56 	

26:21 	
30:09 	
32:53 	
33:36 	
37:36 	
iiil^iiilliliili^iil
34:17 	
33:29


26:09 	
34:01
                     Data Reviewer
            Ql/15/98
                                        Page 2 of 2
                         X37.PSR vioi. LARS 410.fl»o
Triangle Laboratories, Inc.s
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                      Printed: 09:28 01/15/98;
                          321

-------
  Data Review By:
Initial    ....Date...

            lL$Ll£Z  Calculated Noise Area:
                                             1.20
  The Total Area for each peak with an ion abundance racio ouCside
  ratio limits has been recalculated according to method requirements.
  Page No.
  01/15/98
 Listing of T980163B.dbf
 Hatched OC Peaks / Ratio
                                                 / Ret. Time
  Compound/
  MJ	 QC.Log Omit Why  . .RT. OK Ratio Total.Area. ..  Area.Peak.1. .  Area.Peak.2.
                                                      Rel.RT Compound.Name..  ID.. Flags.
TCDF
304-306


















304-306
13C12-TCDF
316-318







316-313
TCDD
320-322






M

DC NL 0
22
23
23
23
24
24
24
24
25
25:
25
25
26:
26:
26:
26:
27:
DC WH 27:
0
:00 RO
:39
:08
:22
:52
:02
:24
:39
:53
:05
:15
:30
:41
:05
:17
:32
;58 RO
:20
:34
.65-0.89
1.32
0.31
0.79
0.79
0.81
0.31
0.31
0.79
0.82-
0.81
0.34
0.81
0.31
0.83
0.32
0.81
0.55
0.77
0.77
17 Peaks

DC NL 0:
DC WL 23:
24:
25:
25:
26:
26:
DC WH 27:
0.
00 RO
35
56 RO
15 RO
39
03
15
09 RO
5 Peaks

DC NL 0:
23:
24:
24:
25:
25:
25:
26:
0.
00 RO
54
16
32
12
27
50
14
.65-0.89
0.93
0.35
1.33
1.08
0.75
0.35
0.80
0.95
0.876-1.072

1
1

3
3
2
1
1
4
1
1
3






27
3
,246
,150
861
,070
,016
,987
,837
.053
,812
,042
,063
,315
735
605
153
3
76
19
,035.
.13
.28
.27
.92
.26
.27
.14
.91
.71
.22
.55
.94
.12
.27
.09
.13
.41
.03
.12
.62

557
506
381
1,372
1,348
1,335
813
473
2,157
474
475
1,485
333
272.
68.
3.
33.



.54
.64
.63
.73
.38
.89
.18
.25
.71
.90
.50
.24
.32
.33
,62
.66
.08



688
643
480
1,697
1,667
1.651
1,024
530
2,654
567
588
1 , 829
401
332
34
6
43



.74
.63
.29
.53
.39
.25
.73
.46
.51
.65
.44
.38
.95
.26
.56
.57
.00


0.000
0.383
0.902
0.911
0.930
0.937
0.951
0.961
0.970
0.978
0.984
0.994
1.001 2378-TCDF AN
1.017
1.025
1.034
1.051
1.066
1.075

0.961-1.039




3



3,
2.
9.
5.
17.
,293.
20.
13.
6.
,350.
rnrr\T
65-0.39
0.43
0.78
0.78
0.74
0.83
0.76
0.68
0.76

1,
1,





1.
,749.
,019.
110.
403.
207.
98.
375.
.33
.48
.93
03
11
70
36
33
13
r / TV
/ l%»,
49
47
23
63
00
59
36
00


4.
10.
1,408.
9.
5.



44
41
22
52
92



3.
9.
1,884.
11.
7.



35
62
89
18
44

0.000
0.919
0.972
0.984
1.000 13C12-2378-TCDF ISO
1.016
1.023
1.058



768.
446.
47.
183.
89.
39.
162.

13
67
23
05
63
92
00

981.
572.
63.
219.
117.
58.
213.
0. 901-1. 043

34
56
45
95
96
44
00
0.000
0.908
0.922
0.932
0.957
0.966
0.981
0.996
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 09:29 01/15/98
                                                                          322

-------
  Page No.
  01/15/98
Listing  of T980163B.dbf
Matched  GC PeaJcs / Ratio / Ret. Time
  Compound/
 kM_Z.... QC.Log Omit Why ..RT.  OK  Ratio Total.Area...  Area.Peak.1..  Area.Peak. 2. .  Rel.RT Compound.Name..  ID.. Flags.
AN




320-322
37C1-TCDD
328











328
13C12-TCDD
332-334



332-334
PeCDF
340-342









M

M
AN








26:
26:
26:
26:
27:
:21 0.34
:30
;40
:51 RO
:19 RO
0.
0.
74
73
1.04
0.99
12 PeaJcs

DC NL 0:
DC WL 23:
DC WL 24:
- 24:
DC SN 24:
24:
^ 25:
25:
, 26:
' 26:
I 26:
27:

:00
:55
:1S
;27
:35
:59
40
49
08
21
43
16













3 Peaks

DC NL 0:
26:
' 26:
1 26:
0.
00 RO
09
20
40 RO
4










2


2,
21.03
39.69
41.65
13.54
11.22
.090.46

0.75
9.51
8.40
6.56
1.30
100.06
9.01
3.10
2.58
,342.42
167.92
2.22
,633.37
9
16
17
7
6





6

100
9
3
.63
.39
.55
.99
.26





.56

.06
.01
.10
11.40
22.80
24.10
7.65
6.34

0.








2.58
2,342.42
167.92
2.22


65-0.39
2.
0.
0.
0.
i3 Peaks

DC NL 0:
27:
' 27:
27:
1 28:
! 28:
28:
28:
28:
I 28:
29:
29:
1 29:
, 29:
29:
29:
DC SN 29:
30:
1 30:
30:
1
1
1.
00 RO
33
44 RO
49 RO
00
11 RO
19
31
40
49
07
- 1
-3
29
39
47
58 RO
11
19
38


32-
1.
1.
1.
2.
. 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.


93
79 2,
30 2,
54
5,
1.73
04
43
17
72
41
12
60
61
46 1,
49
48
45
46
43
49
47
22
43
45
41


4.31
,953 . 38
,703.38
28.94
.636.20
Tpnn / Po<
1 \fUU f fS'
1.73
825.05
14.63
10.97
23.14
19.05
17.22
262.93
438.46
312.23
442.00
687.41
295.00
239.70
201.95
315.55
1.02
325.01
380.55
78.31



1, 302.
1.200.
12.

.07
.09
.59

1
1
1
1
1

.001 2378-TCDD
.006
.013
.020
.037

AN


J
J

924-1.076
0
0
0
0
0
0
0
0
0
1
1
1

.000
.908
.922
.928
.934
.949
.975
.980
.992
.001 37C1-TCDD
.015
.035










SUR1



0.924-1.076

1,651.31
1.503.79
23.51
0
0.
1.
1,
.000
.993 13C12-1234-TCOD
.000 13C12-2373-TCDD
.013

RSI
IS1

PT°1F Prtl 1 oii»e


492.
8.
11.
13.
11.
10.
162.
382.
186.
264.
406.
175.
143.
120.
188.

191.
225.
45.



96
39
71
55
53
59
17
70
92
00
55
00
00
99
01

48
40
78


0.928-1.061

332.09
7.57
4.30
9.59
10.32
6.63
100.76
605.76
125.31
178.00
280.36
120.00
96.70
80.96
127.54

133.53
155.15
32.53


0.
0.
0.
0.
0.
0.
0.
p.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.


.000
.934
941
,943
950
956
960
967
972
977
988
991
998
000 12378-PeCDF
006
010
016
024 23478-PeCDF
028
039




J
J
J
J
J






AN



AN

J


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed:
/15/98

-------
  Page No.
  01/15/98
Listing of T980163B.dbf
Matched GC Peaks /  Ratio / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.


340-342
13C12-PeCDF
352-354









352-354
PeCDD
356-353












356-353
13C12-?eCDD
368-370


363-370
HXCDF
374-376







DC SN 30:51
31:08
19 Peaks

DC NL 0:00
28:38
28:48
29:14
29:29
29:45
DC SN 29:57
30:09
30:40
31:08
8 Peaks

DC NL 0:00
28:45
29:13
29:27
29:35
29:46
30:01
30:13
30:20
30:30
30:38
30:57
DC WH 31:26
11 Peaks

DC NL 0:00
30:30
30:37
2 Peaks

DC NL 0:00
31:57
32:05
32:14
32:22
32:32
32:42
32:53
RO


1
RO

RO
RO


RO

RO
RO

1,

RO




RO

RO

RO

RO

1.
RO



1.
RO







0.37
1.42

.32-1.78
0.91
1.40
0.33
2.13
1.41
1.63
2.13
1.45
1.10
0.91

.32-1.78
1.71
1.06
1.42
1.70
1.73
1.50
1.95
1.47
0.39
1.40
1.28
1.60
2.24

32-1.78
1.26
1.46
1.44

05-1.43
1.51
1.30
1.28
1.37
1.20
1.32
1.19
1.30
1
39
5,978

0
13
4
4
3,084
29
3
2,894
2
6
6,040

1
343
23
211
34
133
46.
55
20.
28.
16.
16.
1.
929.
.04
.30
.96

.71
.48
.28
.77
.30
.06
.54
.33
.30
.98
.50
P 1 P*»

.03
.05
.09
.55
.91
.33
.05 '
.33
.28
.26
.04
.35
79
24

23



7
2
3
1,304
18

.36



.36
.60
.99
.50
.00

1
16.44 1

0.

5.62
3.13
1.87
1,280.30
11.06

.046
.056


J

364-1.136
0
0
0
0
1
1
.000
.971
.977
.992
.000 13C12-PeCDF
.009




123 IS2 '

1.016
1,713
1
4
.30
.70
.24
1,181.03
1.55
4.65
1.023 13C12-PeCDF
234 SUR2
1.040
1.056
f nn Pol i rtu« --

0.
937-1.021
0.000
208
13
133
22
80
35.
.52
.55
.15
. 13
.30
.13
32.92
12.
16.
9.
10.


33
49
75
38


196.41
9.54
78.40
12.78
53.53
18.06
22.41
31.92
11.77
7.62
6.47


0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.

0.869-
0.
1,338.
215.
2,103.
DeCTir
eG\—LJL
3.
210.
430.
28.
44.
25.
4.
378.
48
03
30
33
\ I llift
i I ruCt
33
98
16
97
91
39
12
42

1,121.
127.

03
14

767.00
88.16
0.
1.
1.
943
953
966
970
976
934
991
995
000 12378-PeCDD
004
015 '
031

1.131
000
000 13C12-PeCDD
004

J

J

J
J
J
AN J
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123 IS3

"*nf U«1 1 rttj*?


119.
241.
16.
24.
14.
2.
213.

39
63
74
43
46
24
34
0.963-

91.59
188.53
12.23
20.43
10.93
1.38
164.58
0.
0.
0.
0.
0.
0.
0.
0.
1.047
000
969
973
977
981
986
991
997 123478-HxCDF




J
J
J
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AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:29 01/15/98
                                                                        324

-------
Page No.     4
01/15/98            !


Compound/
M_2	 QC.Log Omit Why
                         Listing of T980163B.dbf
                         Matched GC Peaks / Ratio  / Ret. Time
                         .RT.  OX Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name..  ID.. Flags.




A
AN
M
374-376
13C12-HXCDF
384-386











384-386
HxCDD
390-392












390-392
13C12-HXCDD
402-404








402-404







14

DC NL





•
DC SN
DC SN
DC SN


• 8
1
DC NL
1

DC SN



DC SN
1


DC SN
DC WH
7
.
DC NL
DC WL





DC SN

6
32:59
33:06
33:17
33:30
34:17 RO
34:18
34:23
Peaks
0.
0:00 RO
31:56 RO
32:53
32:59
33:15 RO
33:29
33:46 RO
33:52 RO
33:59 RO
34:01 RO
34:17
34:41 RO
Peaks
1.
0:00 RO

32:25
32:39 RO
32:51
33:05
33:15 RO
33:30 RO
33:36
33:41
34:00
34:09 RO
34:27 RO
Peaks
1.
0:00 RO
32:21 RO
33:04
33:36
33:41
34:01
34:18 RO
34:24 RO
34:30
Peaks
1.26
1.30
1.32
1.
0,
.30
.95
1.16
1.35


165.86
31.19
50.11
144.37
4.66
8.47
36.00
1,564.11
92
17
28
81
2
4
20

.61
.62
.54
.90
.58
.55
.70

.43-0.59
5.51
0.32
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.

51
51
42
51
31
18
34
90
52
02

05-1.43
0.

1.
2.
1.
1.
1.
2.
1.
1.
1.
0.
0.

05-
2.
2.
1.
1.
1.
1.
1.
2.
1.

31

21
70
23
29
03
52
19
21
08
45
39

1.43
57
03
19
23
20
21
98
87
32

0.56
4.51
2,169.59
2,414.95
6.31
2,269.44
6.22
1.57
1.65
2.37
1,941.22
2.34
8,315.08
: HxC DF /

1.50

36.23
0.60
192.19
74.73
8.44
1.03
10.45
21.91
31.68
0.52
0.35
375.63

2
732
812
2
764
3

.46
.63
.59
.30
.06
.32
73.25
13.57
21.57
62.97
2.73
3.92
15.30

0.

2.99
1,436.91
1,602.36
5.43
1,505.38
4.12
1
1
1
1
1
1
1

.000 123678-HxCDF AN
.004
.009
.016 234678-HxCDF AN
.039
.040 123789-HxCDF AN
.042


J
QJ

J
PRJ
J

879-1.121
0
.000

0.963
0.997 13C12-HXCDF 478 SOR3
1.000 13C12-HXCDF 678 IS4
1.008
1.
1.
,015 13C12-HXCDF 234 ALT2
024


1:027
1.030

660
1

.96
.53

1,280.26
1.55
1.
1.
1.
031
039 13C12-HXCDF 789 ALT1
052



HxCDD '•'ollows -



19.

106.
42.
4.

5.
11.
16.





,32

13
09
67

63
99
47



0.953-1.014


16.41

86.06
32.54
4.52

4.77
9.92
15.21



0.

0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.

0.970-
1.61
1.66
7.38
1,644.40
2,113.04
2,216.98
5.44
2.78
5.75
5.992.99


4.
905.
1,151.
1.215.
4.

3.



01
94
58
11
81

27


•
3.37
738.46
961.46
1,001.87
2.43

2.48

0.
0.
0.
0.
1.
1.
1.
1.
1.

000

962
969
975
982
987
995
998 123473-HxCDD AN
000 123673-HxCDD AN
009 123789-HxCDD AN
014
023

1.030
000
960 .
982
998 13C12-HXCDD 478 SUR4
000 13C12-HXCDD 678 ISS
010 13012-HXCDD 789 RS2
018
021
024



J



J

J
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PRJ














Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                        Printed: 09:29 01/15/98

-------
 Page No.
 01/15/98
Listing of T980163B.dbf
Matched OC Peaks / Ratio /  Ret. Time
 Compound/ -
 M_2....  QC.Log Omic Why ..RT. OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
HpCDF
408-410








408-410
13C12-HpCDF
418-420





413-420
HpCDD
424-426
D





424-426
13C12-HpCDD
436-438



436-438
OCDF
442-444







DC



DC
DC
DC

DC


DC


DC




DC
D

DC

DC
DC


DC
DC




DC
DC
DC
DC
DC
" DC
DC

NL



SN
SN
SN

WH
4

NL


SN


4

NL
NH

SN

WH
WH
2

NL
SN


2

NL
WL
WL
WL
WL
WL
SN

0:00
36:00
36:17
36:25
36:38
36:50
37:11
37:36
37:59
Peaks

0:00
35:59
36:21
36:43
37:36
37:52
Peaks

0:00
36:09
36:18
36:52
37:05
37:13
37:36
Peaks

0:00
36:17-
37:04
37:25
Peaks

0:00
35:34
35:39
35:44
35:59
36:09
37:02
0
RO

.38-1.20
1.
1.
37
04
1 . 11

RO
RO
RO

RO

0
RO

RO




0.
RO
RO

RO

RO
RO

0.

RO

RO

0.
RO
RO
RO
RO
RO

RO
I.
2.
0.
2.
1.
6.

06
41
51
00
07
62

0
416
32
88
1
1
0
51
0
638
.88
.10
.19
.36
.73
.06
.31
.54
.59
.19
.37-0.51
0.
0.
0.
0.
0.
0.

85
44
73
44
43
38

1
1,663
6
2
1,479
12
3,161
.80
.83
.09
.75
.40
.16
.48
C / Uv
.38-1.20
0.
0.
0.
0.
1.
1.
1.

88-
1.
2.
1.
1.

76-
1.
2.
2.
3.
1.
0.
1.
73
47
98
74
00
50
66

1.20
13
76
02
32

1.02
73
00
34
26
83
77
35
0
12
72
0
70
0
1
143
.22
.13
.50
.96
.34
.73
.57
.34
0.996-1.051
0
212.59 203.51 1
43.31 38.38 1
45.50 42.86 1
.000
.000 1234678-HpCDF
.008
.012

AN


1.018
1.
.024

1.033
26.70 24.84 1,
.045 1234739-HpCDF
AN
1.056



0.944-1.111
0,
509.08 1,154.75 1.
3.07 4.23 1.
1.
447.39 1,031.51 1.
3.37 8.79 1.

.000
.000 13C12-HpCDF 678
.010
020
045 13C12-HpCDF 789
052


IS6


SUR5


0.975-1.005
0.
0.
35.93 36.57 0.
0.
35.34 35.50 1.
1.
1.

000
975
979
995
000 1234673-HpCDD
006
014





AN



0.973-1.027
2
1
1,753
6
1,760
HoCOI

0.
0.
0.
0.
0.
1.
1.
.40
.29
.92
.43
.35
-\ / f>—
J 1 VJC
.28
.25
.55
.36
.57
.01
.36
0.
0.
883.93 869.94 1.
5.73 3.15 1.

0.902-
0.
0.
0.
0.
0.
0.
0.
000
979
000 13C12-HpCDD 678
009

1.098
000
869
371
373
379
383
905


137










Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed 30E29 01715/98
                                                                       o — ^

-------
  Page No.     6           Listing of T980163B.dbf
  01/15/98                 Matched GC Peaks / Ratio / Ret.  Time

  Compound/             '
  •'.2.... QC.Log Omit Why . .RT.  OK Ratio Total.Area. ..  Area. Peak. 1. . Area. Peak. 2. .  Rel. RT Compound. Name..  ID..  Flags.

                                                                                  0.910
                                                                                  0.918
                                                                                  0.920
                                                                                  0.925
                                                                                  0.931
                                                                                  0.933
                                                                                  0.936
                                                                                  0.941
                                                                                  0.945
                                                                                  0.951
                                                                                  0.957
                                                                                  0.975
                                                                                  0.985
                                                                                  0.988
                                                                                  0.990
                                                            243.50        285.60   1.006 OCDF             AN
                                                                                  1.013
                                                                                  1.017
  442-444

  OCDD          '                 0.76-1.02                                      0.902-1.098
  453-460         DC  NL '   0:00      0.36          0.26                              0.000
                         40:57      0.76         89.95          38.96   .      50.99   1.000 OCDD             AN
                 DC  SN '  41:10      1.01          2.53                              1.006
  458-460               1  Peak                   89.95
                       I
  13C12-OCDD            ,         0.76-1.02                                      0.997-1.005
  470-472         DC  ML,   0:00  RO  1.08          0.2S                              0.000
                       .  40:56      0.90      2,434.57      1,154.15      1,280.42   1.000 13C12-OCDD       IS3
                       1  Peak                2,434.57
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

DC
DC

SN
m\
SN
SN
SN'
SN
SN
SN
SN
SN,
SN
SN
SN
SN
SN ;

SN
SN
1
37:
37:
37;
37;
38:
38;
38:
38:
38:
38:
39:
39:
40:
40:
40:
41:
41:
41:
;15
:34
:39
;51
;07
ill
20
:31
,40
56
10
54
:18
26
32
10
29
38
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

RO

1.
1.
1.
0.
0.
2.
0.
4.
0.
0.
1.
1.
0.
1.
1.
0.
3.
0.
71
04
50
37
58
40
64
25
52
75
45
06
30
71
81
85
65
97
Peak
0,
1.
0
0.
0,
0.
0.
0.
1.
1.
1 t
0.
0.
0.
0.
529.
1.
1.
529.
.96
.04
.42
.93
.76
.19
.59
,45
.04
,57
,10
66
,49
45
40
10
33
50
10
 Column Description	   •Why"  Code  Description	  QC Log Desc.
 M_2   -Nominal Ion Mass(es)     WL-Below  Retention Time Window   A-Peak Added
  ..RT. -Retention Time (mm:ss)   WH-Above  Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below  Signal  to Noise Level   D-Peak Deleted
 OK    -RO=Ratio Outside  Limits  
-------
File:T980163 ttl-810 Acq:7-JAN-98 00:18:58 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 133-136                       INJ. TIME =
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331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 133-136                       INJ. TIME =
  i—i—i—i—i—i—i—i—i—i—i—i—|—i—i—i—i—i—I—i—i—i—i—i—p
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Oo25:48  26:00  26:12  26:24  26:36  26:48   27:00   27:12   27:24  27:36  27:48  28:00  28:12  Time

-------
                                                     v-i
rile:T980163  #1-910 Acq:7-JAK-9a 00:18:58 EI+  Voltage SIS 70T Koiaetll71
303.9016 f:2  BSUB(256, 30, -3. 0) PXD(9,5,5, 0. 05\,4684.0,1. 00*,T,T)  SxpiODBSUS
TRIANGLE LASS  Text:TLIt44376 133-136                        1X7.  TIME -   00:21
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TRIANGLE LABS  Text:TLH44376 133-136                 .      J3KT. TIME  "    00:21
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TSIASSLE LABS  Taxt:TLI»44376 133-136                        JJ«7.  TIME -   00:21
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TRIANGLE LABS  Text:TLI#44376 133-136                       JJW.  TIME  -   00:21
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TRIASSLE LABS   Text:TLI#44376 133-136
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riJ.e:T980163  H-810 Acq:7-JJUT-98 00:18:58 EH- Voltage SIS 70T
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TRIANGLE LABS  Text:TLH44376 133-136
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                                                                                                5. OE6

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-------
file:T980163 #1-810 Ac?: 7- JAN- 98 00:18:58 EI+ Voltage SIR 70T SOiaei 325
319.8965 T>2 BSUS(256, 30, -3.0) PXD(7,5,3,0.05\,13QO.O,1.00\,r,T) ExpsNDBSUS
TRIANGLE LASS Text: TLIf 44376 133-136 INJ. TIMS * 00:21
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409.7789 T:4 asUB(256, 30, -3. 0) PXO(7,5, 3, 0. 05%, 964.0,1. 00\,F,T) Xzp:SDB5US
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419.8220 F-.4 BSUB(256,30,-3.0) PKS( 7, S, 3, 0. 051,2492. 0,1 . 00\,r, T) Xxp:KDB5US
TRIANGLE LASS \Text:TLI»44376 133-136 . IJfJ'. TIKE - 00:21
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-------
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1001


 80.


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           A3.59Z5
                                                             A3.53X5
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425.7737 Tt4 3SUB(256, 30, -3. 0) PXD(7,St3,O.OS\,304.0,1.00\,T,T) ExpiSDBSUS
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1001      A3.
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435.8169 T:4 BSU3(256, 30, -3. 0) PKD(7,5,3,0.051,2600.0,1. 00\,r,T) Exp:NDB5US
TRIANGLE LABS  Teit:TLIt44376 133-136                       HKT. TIME "    00:21
1001                                                       A3.1,


 80.

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      36:12 36:18  36:24  36:30 36:36  36:42 36:48 36:54  37:00 37:06 37:12  37:18 37:24 37:30
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437.8140 T:4 BSUB(256, 30,-3. 0) PKD(7, 5,3, 0. OS\,2192.0,1. 00\,T, T) EzpiHDBSUS
TRIANGLE LABS  Text:TLIt44376 133-136                       HKT. TIME -    00:^1
1001                                                       A8.\

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      36:12 36:18  36:24  36:30 36:36  36:42 36:48 36:54  37:00 37:06 37:12  37:18  37:24 37:30
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430.9729 T:4 ExptODBSUS
TRIANGLE LABS  TeXt:TLIi44376 133-136                       XKT. TIME -   00:21
1001

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                       36:28
                                     36:41
                                                                          37:17
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                                                                                                    336

-------
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TRIANGLE LABS  Taxt:TLIt44376 133-136                       XK7.  TIME -
1001                     AS.10X5
                                                                            41:18
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TRIANGLE LASS  TaJCt:TLIf44376 133-136                       JKJ.  TIME -    00:21
1001                   A1.J3E7
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                                                                           41:18
      40:48         40:54         41:00         41:06         41:12
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471.7750 T:4 BSUB(256,30, -3. 0)  PKD(7,S,3, 0. 05\,256.0,1. 00\,T, T) Erp:«I>B5US
TRIANGLE LABS  Text:TLI#44376 133-136                       IJKT. TIME -   00:21
1001                   A1.JSE7
      40': 48         40:54         41:00         41:06         41:12         41:18
rile:T980163 tl-563 Acq:7-JAK-98 00:18:58 EI+ Voltage SIS 70T
430.9729 T:4 Exp:SDB5US
TRIANGLE LABS  Text:TLIt44376 133-136                       IJKT. TIME -   00:21
1001              40:53                41:02       41:07

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                                                                                                       338

-------
Ref, 1555    222,3825     Peak top
Height  3.12 volts  Span   290 ppi

Systsi file naae
Data   file nase
Resolution                 10000
uroup nuflber                   2
lonuatlon node               El*
Pitching                 WLTRGE
Ref. lasses  292,385,   416.3760
fl   293      J   331      S  368
B   304      K   332
C   306      I   334
0   316      H   340
E   318      N   342
F   329      0   352
G   322      P   354
H   328      Q   356
I   331      R   358

Channel   I   38,3792.    Peak top
Height  2.34 volts  Span   290 pea
T   370
U   376
V   410
                                                                  338

-------
File:T980163 #1-810 Acq:7-JAN-98 00:18:58 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 133-136
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File:T980163 81-396 Acq:7-JAN-98 00:18:58 EI+ Voltage SIR  70T
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-------
TLI Project:      44376
Client Sample:   133-136
Method 23 TCDD/TCDF Analysis (DB-225)
                   Analysis File:   P980168
Client Project: Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97 Spike File:
TLI ID: 194-59-8A-8D Date Extracted: 12/29/97 ICal:
; Date Analyzed: 01/10/98 ConCal:
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a % Moisture
Blank File: X980083 % Lipid:
Analyst: WK % Solids:
SPC2NF04
PF22206
P980164
: n/a
n/a
n/a


2,3,7,8-TCDF

13Cl2-2,3,7,8-TCDF

i3C12-l,2,3,4-TCDD !
0.57 0.75
:W™::WwSS:S!te^
3.0 73.9 40%-130% 0.77

0.82
23:06 	

23:05 _

21:55 	
                                                          01/11/98
                                      Page 1 of 1
                               C2NP_PSR rlOl. LARS 6.10.08
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                            Printed: 13:36 01/11/98
                                343

-------
                        Initial
                                     Data..
  Data Raviaw By:
                     Calculated Noise Area:
                                            3.00
 The Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according  to method requirements.
  Page Mo.
  01/11/98
Listing  of P980168B.dbf
Matched  OC Peaks / Ratio /  Ret. Time
  Compound/
  M_Z	QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Nama..  ID.. Flags.
TCDF 0
304-306 DC NL 0:00 RO
18:18
18:
32
18:41 RO
18:
18:
19:
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
21:
21:
21:
21:
22:
22:
22:
22:
47
58 RO
03 RO
10
30
38
46
57
17
23 RO
30
39
47
11
36
43
52
06
19
30
57
23:06
23:
23:
23:
24:
25:
18
34
42
30
14 RO
.65-0.89
1.43
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
68
81
15
84
64
28
87
72
76
74
89
73
92
76
72
70
74
74
69
75
74
77
76
75
75
75
75
74
74
59
304-306 30 Peaks
13C12-TCDP
316-318 DC NL 0:
DC HL 20:
DC WL 21:
23:
23:
DC WH 25:
0.
00 RO
33 RO
48 RO
05
42 RO
13 RO
3
17
906
4
25
27
23
90
780
746
1,434
653
568
1,323
717
1,877
601
3,681
653
149
617
667
150
734
532
319
574
639
465
278
37
19,301
.52
.37
.70
.02
.17
.42
.06
.30
.15
.92
.57
.21
.40
.27
.28
.11
.52
.67
.13
.07
.50
.11
.40
.60
.68
.30
.35
.19
.71
.05
.28
.51
0.793-1.101
0.000
7
405
1
11
11
16
42
326
321
608
307
238
689
309
785
247
1,561
279
. 60
264
283
65
317
227
137
245
273
198
113.
16.

.00
.08
.75
.51
.93
.72
.10
.71
.40
.65
.66
.96
.97
.80
.05
.87
.86
.63
.74
.52
.48
.63
.60
.80
.11
.76
.04
.01
.10
.22

10
501
11
13
18
13
48
453
425
825
345
329
747
407
1,092
353
2,119
378
88
352
383
84
417
304
182
328
366
267
159
27

65-0.89
1.
0.
1.
0.
1.
0.
02
64
01
77
07
52
316-318 2 Peaks
3
9
9
2.163
7
11.
2,171
.12
.06
.95
.99
.45
.88
.44



939.
4.





96
49





1.224.
.37
.62
.56
.66
.62
.03
.20
.44
.52
.92
.55
.44
.61
.48
.06
.65
.31
.45
.33
.98
.63
.77
.00
.38
.19
.59
.15
.70
.95
.59

0.793
0.803
0.809
0.
.314
0.822
0.825
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.

0.957-



.03
4.21




0.
0.
0.
1.
1.
1.

830
845
351
356
364
879
383
388
895
900
918
936
941
947
957
967
975
994
001 2378-TCDP AN
009
021
027
061
093

1.043
000
890
944
000 13C12-2378-TCDF ISO
027
092

Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 13:22 01/11/98
                                                                                                     344

-------
  Page No.
  01/11/98
Listing of P980168B.dbf
Matched oc Peaks /  Ratio  / Ret. Time
  Compound/
 k'_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.
  13C12-TCDD
  332-334
  332-334

DC




DC
DC
DC


ML




WH
WH
WH
4

0:
20:
21:
21:
22:
24:
24:
24:

00
33
38
55
41
14
27
32
0.
RO
RO



RO
RO
RO
65-0.89
1.
0.
0.
0.
0.
0.
0.
1.
75
54
80
82
76
47
55
11
Peaks
                                       Above: TCDF / TCDD Follows
                      1.43
                      6.02
                  1,825.45
                  2,109.71
                     21.32
                      5.10
                      3.68
                     10.07
                  3,962.50
                                                    0.907-1.093
                                                       0.000
2.62
810.63
950.17
9.21



4.86
1,014.82
1.159.54
12.11



0
1
1
1
1
1
1
                                                                                   950
                                                                                   000 13C12-2378-TCDD  IS1
                                                                                   013 13C12-1234-TCDD  RSI
                                                                                   049
                                                                                   120
                                                                                   130
                                                                                 1.134
  Column Description. . .	   'Why'  Code Description	   QC Log  Desc.
  M_Z   -Nominal Ion Mass(es)
  ..RT. -Retention Time (mm:ss)
  Rat.l -Ratio of M/M+2 Ions
  OK    -RO=Ratio Outside Limits
  Rel.RT-Relative Retention Time
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
fila:PSS0168#1-922 Acqt lO-JJuf-1998 14:26s52 SI+ Voltage SIS 70P OOl.ae:142J
303.9016 BSUB(256,30,-3.0)  PKD(S,3,1, 0.10\,S692.0, 0.00\,T,T) Ezp:DB225
TRIANGLE LABS  Text:133-136   TLI»44376
1003,
  30.
  S0-
  "
                            A6.90E6    A1.S6E7
    "S
                                                        "•""
                                                                      A3.73E6
                                                                 AA  A  AA
                                                                /VAVV
                                                                                    A
           19:00        20:00        21:00        22:00        23:00        24:00
Wle:J>S80158 #1-522 AcqilO-JJUr-1998  14:26:52 XI* Voltage SIS 70P 8oiae:994
305.8987 BSUB(256,30,-3.0) PKD( 5,3,1, 0.10\, 3976.0, 0. QQ\,T,T) Exp:BB225
TSIANGLE LABS  Text:133-136   TLII44376
1004                                  A2.J.2E7
                                                                                         25 .-00
  80-
  <°-
 "
                            A7.4BE6
                    A8.26E6
                                                                     A3 . 66E6
                                                                                 A1.60E6
                                                                                    A
           19:00        20:00        21:00        22:00        23:00        24:00
File:P980168 #1-922 Acq:10-JAN-1998  14:26:52 EI+ Voltage SIR 70P Noiae:896
315.9419 BSUB(256,30,-3.0) PKD(5, 3,1,0.10\, 3584 .0, 0 .00*, F,F) Exp:DB22S
TRIANGLE LABS  Text:133-136    TLI#44376
1004                                                           A9.40E6
 80.

 60.

 40.
 20.
                                                                   4-
           15:00        20:00        21:00        22:00        2J.-00        24:00
Tile .-PS 8 0158 #1-922 Acq:10-JAN-1998  14:26:52 EI+ Voltage SIR 70P Noise:878
317.9389 BSU3(256,30,-3.0) PKD(5, 3, 1, 0.10%, J512. 0, 0 . 00%, F,F) Exp:DB225
TRIANGLE LABS  Text: 133-136   TLI#44376
1002

 80.

 60.

 40.

 20.
                                                                   12E7
           19:00        20:00        21:00        22:00        23:00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52 EI+ Voltage SIR 70P
375.8364 Exp:DB225
TSIANGLE LABS  Text:133-136   TLI#44376
1004 18.-J1
                                                                            24:00
           15.-00
                         o.o
                                      l ro
                                                  22-00
                                                               23:00
                                                                            24:00
                                                                                         25 -GO
                                                                                         25 1 0/}
                                                                                         25: 00
                                                                                         25:00
                                                                                                     -2.4E6
                                                                                                         Tloe
 3. 3E6

'.2.6E6

.2.0E6

.1.3E6

'.6.6E5
                                                                                                      O.OEO
                                                                                                         Tine
                                                                                                     .2.0E6

                                                                                                     .1. 6E6

                                                                                                     .1.2E6
                                                                                                     '.4.1E5
                                                                                                          «
                                                                                                         Time



                                                                                                     2.8E6

                                                                                                     2.2E6

                                                                                                     1.7E6

                                                                                                     1.1E6

                                                                                                     S.5E5

                                                                                                     O.OEO
                                                                                                         Time
                                                                                                346

-------
Pile:P9B01S8 «U-'il

2 S1+ voltage sXs 70P lioiae:601 :
319.8965 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10\,2404 . 0, 0. 00\,f,F ) Exp:DB225
TRIANGLE LABS Text:133-136 TLH44376
1003
80.
60.
40.
20.

A4 . 66E6 ,
n

"



2


30E6


A5.56E5 ,, .,,-
f\ n A3.15E5
I A A A A, '•
0:00 21:00





A9.71ES
1.3E6
.LIES
.a.OES
'.5.4E5
12. 7ES
' 0 . OEO
22:00 23': 00 24:00 Time
Fil0:P980168 #1^-922 Acq: 10-JAN-1998 14:26:52 EI+ Voltage SIR 70P Noiae:774
321.8936 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10%, 3096 . 0, 0.00\,r,F) Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
1003
80.
60.

40.
20.

0
A6.04E6
ft
;




A4.26E6
\

•
,
11 f



A8.16E5
A A A4.05E5
V A y\/v /\ __
'20:00 21:00



A1.28E6
x-WV.
-1 . 7E6
.1.4E6
'.1 . OE6

.7.0E5
.3.5E5

' 0 . OEO
221-00 2J.-00 241-00 Time
File:P980168 #1-922 Acq: 10-JAN-1998 14:26:52 EH- Voltage SIS 70P Noiae:469
327.8847 BSUS(2S6
, 30, -3.0) PKD(5,3,1,0.10\,1376.0,0.00\,F,F) Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
100$
80.
60.
40.
20.

0



I
1


Al.





~ - ^/
'20:00 	 21 1-00
(E7




A1.48E6
A
r3.9E6
.3.1E6
.2.3E6
.1 . 5E6
'.7.7E5

O.OEO
221-00 	 2-jl-OO 	 241-00 ' Time
File:P980168 #1-922 Acq: 10-JXW-1S98 14:26:52 EH- Voltage SIR 70P Noiae:712
331.9368 BSUB(256,30,-3.0) PKD( 5 , 3, 1, 0 . 101, 2848 . 0, 0 . OOT>, F,PJ Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
lOOJi
•
80.
60.
40.
20J
0.


!





AS.




j
.'20!- 00 ' 21 1-00
A9.50E6 2.1E6
HE6n

\
•

\l {

_1 . 7E6
.1 . 3E6
.8. fi£T5
_4.Jr5
O.OEO
22:00' ' '2J.-00' ' ' ' '24 .-OO' ' ' ' ' Time
File:P980168 #1-922 Acq: lO-JAlf-1998 14:26:52 EI+ Voltage SIR 70P Noiae:404
333.9338 BSUB(256
,30, -3.0) PKD(5,3,1,0.10\,1616.0,0.00\,F,F) Exp:DB225
TRIANGLE LABS Text:133-136 TLIM4376
1001

80.
so:
40.
20:
01


I

1
;
i


A1.16E7 ^2.6E6
Al . 01E7 (1
-



J
20:00 21:00




I/ I

.2.1E6
.1 . 6E6
.1.1E6
.5.3E5
o .oro
22:00 ' '23'i 00 ' ' ' 24:00 ' ' ' Time
347

-------
Tile:P98016B #1-922 Acq:10-JMT-199a 14:26:52
EI+ Voltage SIR 70P

303.9016 Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
1004
80.
50.
40.
20.
o


18:32
A .
' ' ' 19:00
20.-2J 2J.-11
ft
1
15:45 1
A4 Jl 11
20 • 00 21 1- 00
rile:P980168 #1-922 Acq:10-JAN-1998 14:26:52



21:36 22-.0633*30
AJIAJ ^
^2.4E6


\A"M WAJ°
.2.015
Ll.5£6fl
.5.8£5 |
-4.5Z5
O.OEO
22:00 2J.-00 24:00 25-00 . Time
EI+ Voltage SIR 7 OP
315.9419 Exp:DB225
TRIANGLE LABS Text: 133-136 TLIM4376
1001
80:
50.
40.
20J
o-






15:00






20 1-00 21:00
rile:P980168 #1-922 Acq:10-JAN-1998 14:26:52
"l




1
22:00 2J:(
EI+ Voltage SIS 7 OP
319.8965 Exp:DB225
TRIANGLE LABS Text:133-136 TLH44376
1001 19

aol
so:
40:
20:
o:





J
15 1-00
1?0


15-55
|
.







05 2.0S5




I
.1 . 6E6
.1.2E6
.8.2ES
-4.1E5
O.OEO
10 14 \ 00 ISlOO Tia«



^1 • 3E6




20:33 21.17 21:55
11 /\ f\ •* * ^ ' f\
j \ yvwA ^ >-^«/\^
20:00 21:00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52

'•.1.1E6
.8.1E5
'•.5.4E5
.2 . 7E5
O.OEO
22 .-00 2jl-00 241-00 25 1-00 Time
EI+ Voltage SIR 70P

331.9368 Exp:DB225
TRIANGLE LABS Text -.133 -136 TLI#44376
1003 .

ao:
SO:
40:
20:
o:






151-00







20 .-00 ' 21-00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52
21.55
21 .- 38




1 \ 1 I T '•'
-2.1E6







.1 . 7E6
-1.3E6
-8.6E5
.4.3E5
O.OEO
22\00 2J.-00 241-00 251-00 ' Tine
EI+ Voltage SIR 70P ,

292.9825 Exp:DB225 ,
TRIANGLE LABS Text:133-136 TLI#44376 \
1001
SO:
so:
40:
20J
0:
18:43 19.1
AT^^l
* \i



15. -00
1 19:37 20:03 j\18 20:45
,TVVVVVV*V\/ r^nr--v^Y^
f V '



20:00 '21:00
rile:P980168 #1-922 Acq:10-JAN-1998 14:26:52
21:45 ^.-25 23:12 23:52^1^ 3^3^\
•V*^V^r*^>*T^^V^^^Vl /

1


**r~Y^ - "V"^ V




-8.2E6
-6.6E6
-4.9E6
-3.3E6
.1 . 6E6
O.OEO
22:00 ' ' ' 2jl-00 ' ' 24:00 25:00 ' ' ' Time
EH- Voltage SIR 70P

330.9792 Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
1001
80:
50:
40:
20:
o:
18:40 ig • 05
AT""!
V V



15:00
J5.j7 20:4121:05
f>^vvvvrw\ r-v>Avv^Vr"v
» yi



20:00 21:00
21:45 22:33 23
r^S-v*. '^vOVV^ j*^**-*SV**^wv * /•
^^r — f — ^.1 ' ^^M /
u



.-05 24:15 -_^£i22[
•^VVV^^^V-Y^^-^^^A^^^




-1.1E7
.8.6E6
.6.5E6
.4.3E6
.2.2E6
O.OEO
22.-00 2jiflO ' ' ' 24:00 ' ' 25:00 Time
348

-------
58-
ChameL   I
Height  2.8
            336,9792
            volts  Span
                                                                      Peak top
                                                                       288 ppi
Systei file naie
Oka   file naie
Resolution
Group niaber
lonlzatlon lode
Switching
Ref, lasses   292,9825,
    292,9825
    383,9816
    315,9419
    317,9389
    319.8965
    321,8936
    327,8847
    338.9792
                                                                  J
                                                                  K
                                                                  L
                                                                  H
                                1
                              El*
                          VOLTflGE
                         388,9761
                         338,9792
                         331,9388
                         333,9338
                         375,8364
                                             Ref, iass    388,9761     Peak top
                                             Height  1,32 volts  Span   298 ppt
                                                                                                                      313

-------
TLI Project:      44376
Client Sample:   137-140  \
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-9A-9D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: CRV
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
"
SPX23704
TF5D177
T980160
n/a
n/a
n/a
AnaJytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Totals-
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Ami. (ng) Dt EMPC
0.04
0.06
0.02
0.05
0.06
0.12
0.16
4.2
0.38
0.51
0.56
0.21
0.22
0.01
0.41
EMPC 0.05
0.24

AmL (ng) Number DL EMPC
7.4 12
1.1 7 1.9
0.86 7
0.26 2
34.0 14 34.2
9.9 14 10.1
2.4 12 2.5
0.60 3 0.66
Ratio
0.75
1.44
1.23
1.31
1.26
0.92
0.76
0.81
1.50
1.45
1.27
1.37
1.30
1.22
1.08

0.84










«T
26:21
30:31
33:36
33:41
33:59
37:05
40:56
25:41
29:30
30:10
32:52
32:59
33:30
34:18
35:59

41:08










Flags

J_
J_
J_
PRJ
	
JB_






PRJ
	
J_


Flags



—
Q_


	
                                       Page 1 of 2
                        X37.PSR v2.01. LARS 6.10
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 09:29 01/15/98
                        35C

-------

w&pw^s&msm.
TLl Project: 44376
fctient Sample: 137-140
i

13C,2-2,3,7,8-TCDF I
13C,2-Z3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF '
13Cu-l,2,3,7,8-PeCDD f
13C,2-l,2,3,6,7,8-HxCDF
l3C,2-l,2,3,6,7,8-HxCDD '.
'3Cr-l,2,3,4,6,7,8-HpCDF
'3Ci2- 1,2,3,4,6,7,8-HpCDD
13Ci2-l,2,3.4,6,7,8,9-OCDD
i

"CU^JJ.S-TCDD ;
13C,2-2,3,4,7,8-PeCDF i
13Ci2-l,2,3,4,7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD !
13Cr-1.2.3,4,7,8,9-HpCDF
1

13Cr-l,2,3,7,8,9-HxCDF
I3Ci2-2,3,4,6,7,8-HxCDF

13C,2-1,2.3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD

2.6
2.6
3.0
3.6
.2.9-
3.6
3.3
4.4
8.6
|||||||||g|||
3.4
3.9
4.0
4.0
4.3

3.2
2.9
Illilllllllllll


&!mmm®m
••
PS

Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980164

64.1
64.3
75.6
90.9
71.9
90.2
83.4
109
108

84.8
97.4
100
101
108
:illlll|iR^b^iiyi
:::::::::::;:-:::::::^::::::::;::>:;::y-:-:::::-;-;::-:->:-::-;::x-:-:-:-:^::':o:
80.0
71.7
ji^li^lliis^HliSJKsiiiji^


40%-130%
40%- 130%
40%-130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%
illliiiliii
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
liiiiiiiitsi
40%- 130%
40%- 130%



0.73
0.80
1.39
1.46
0.51
1.22
0.43
1.02
0.88

1.43
0.52
1.21
0.44

0.51
0.53

0.81
1.20
:$:3:-:;:;:SiEiiT;-;S
iSiSgigSljEgi;
25:38
26:20
29:29
30:29
32:58
33:40
35:59
37:04
40:55
llliil
26:21
30:09
32:52
33:35
37:36

•34:17
33:29
llliil
26:09
34:00

—
liljliiii
	
||||lifigs|||
—

—
                          Data Reviewer
01/15/98
                                                 Page 2 of 2
                X2J7.PSR v2.0l. LARS «.IO.Ogo
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
            Printed: 09:29 01/15/98
                  351

-------
 Daca Review By:
Initial    ....Dace...

            /L$L/fJ/  Calculated Noise Area:
2.00
 The Total Area  for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to method requirements.
 Page No.      1
 01/15/98

 Compound/
 M_Z.... QC.Log Omit Why
 Listing of T980164B.dbf
 Matched GC Peaks / Ratio /  Ret. Time
 .RT. OK Ratio Total.Area... Area.Peak.l. .  Area.Peak.2. .  Rel.RT Compound.Name..  ID..  Flags.
TCDF
304-306







M









304-306
13C12-TCDF
316-318









316-318

TCDD
320-322







DC NL 0
22
23
23
23
24:
24:
24:
25:
25:
25:
25:
26:
26:
•26:
26:
27:
DC WH 27 :
0
:00 RO
:38
:08
:21
:51
:02
24
;39
:04
:15
;30
41
:05
: 17
32 RO
:59 RO
20
33 RO
.65-0.89
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
• 0.
0.
1 .
16 Peaks

DC NL 0:
DC WL 23:
DC WL 24:
DC WL 24:
25:
25:
25:
26:
26:
DC WH 27:
0.
00
31
04
14 RO
06
14
38
03 RO
16 RO
34 RO
65-
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
5 Peaks


DC NL 0:
23:
24:
24:
25:
25:
. 25:

0.
00 RO
54
16
34
12
28
51

93
32 1
77 1
31 1
31 3
81 3
31 3
32 2
30 7
32 1
79 1
SI 3
31
31
94
64
75
05
32
0.39
76
74
34
18
87
67
73 2
61
43
90
2

65-0.39
0.
0.
0.
0.
0.
0.
0.
15
78 2
76 1
74
30
76
73
4
.452
,320
,030
,821
.572
,527
,196
,090
,206
,302.
,963
896.
706,
160.
13,
91.
19.
,356.
.00
.45
.95
.12
.26
.31
.18
.36
.00
.49
.32
.53
.37
.36
.10
.49
,70
77
.99

654
576
460
1,713
1,598
1,574
991
3,160
543
576
1,781
400
315
85
5
39.



.53
.20
.18
.32
.96
.70
.49
.00
.77
.49
.28
.68
.30
.12
.37
.27



797
744
569
2,107
1,973
1,952
1,204
3,930
662
726
2,137
495
391
90
9.
52,


0.876-1.072

.92
.75
.94
•94
.85
.48
.87
.00
.72
.33
.25
.69
.06
.45
.18
.43


0.000
0.383
0.902
0.911
0.930
0.938
0.952
0.962
0.978
0.985
0.995
1.002 2378-TCDF AN
1.018
1.025
1.035
1.053
1.066
1.075

0.961-1.039
3.
13.
31.
6.
12.
19.
,762.
14.
14.
12.
,823.
.86
.64
18
96
03
97
24
67
44
30
35
TCDF / TCDD

0.
,513.
,492.
138.
507.
276.
119.
90
62
99
63
70
04
50




5.
7.
1,165.
6.
6.






60
98
34
,38
28






6.
11.
1,596.
10.
12.






.43
99
90
.47
96


0.000
0.917
0.939
0.945
0.979
0.984
1.000 13C12-2378-TCDF ISO
1.016
1.025
1.075




1,102.
646.
59.
225.
119.
SO.

87
32
20
30
59
34

1,415.
846.
79.
282.
156.
69.
0.901-1.043

75
67
48
40
45
16
0.000
0.908
0.922
0.933
0.957
0.967
0.982
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 09:29 01/15/98
                                                                              r\
                                                                          35:

-------
  Page No.
  01/15/98
Listing of T980164B.db£
Matched OC Peaks / Ratio  / Ret. Time
  Compound/
  M_2.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak. 1.
                                       Area.Peak.2. . Rel.RT Compound.Name..  ID.. Flags.
M
AN




320-322
37C1-TCDD
328



















.3
13C12-TCDD
332-334




332-334
PeCDF
340-342








AD
' 26
26
1 26
26
26
• 27
:14 0.79
:21
:30
:39
:52
s!7
0.
0.
0.
0.
0.
.75
,74
,65
,66
,30
12 Peaks

DC NL 0
DC WL 23
DC WL 24
DC WL 24
24
, 24
25
i 25
|
1 25
i 25
DC SN 26;
26:
26:
DC SN 26;
DC SN 26;
DC SN 27:
! 27:
1 27:
27:

:00
:54
:10
:16
:27
:35
:00
:12
•16
:4Q
:53
:03
i 21
:43
;55
;59
:03
:13
:36
46










































12 'peaks
1
DC NL 0:
25:
26:
! 26:
26:
0:
00 RO
:12 RO
09
20
39
472
28
45
49
17
13
5,679

1
13
28
13
6
3
861
6
2
10
3
2
1,909
207
1.
1
2
3
11
3
3,030,
.00
.40
.09
.31
.82
.10
.75

.24
.37
.37
.38
.94
.06
.52
.77
.96
.77
.44
.13
.39
.39
.36
.44
.05
.21
.20
.01
,66
209
12
19
19
7
5






6
3
861
6
2
10
3

1,909
207



3
11,
3

.00
.20
.20
.56
.11
.32






.94
.06
.52
.77
.96
.77
.44

.39
.39



.21
.20
.01

,65-0.89
2.
0.
0.
0.
0.
4 Peaks
1
;
DC NL 0:
27:
27:
! 27:
' 28:
i 28:
28:
28:
28:
D EE 23:
1.
00 RO
33
43 RO
53 RO
00 RO
11 RO
16 RO
31
39
46 RO
32-
1.
1.
0.
1.
2.
1.
1.
1.
1.
1.
87
46
81
30
71

1.78
08
52
59
87
06
93
11
53
46
28
4.
9.
2.791.
2,239.
37 .
37
,52
.15
75
56
5,077.98
• TCDD /

i.
1,043.
15.
21.
17.
22.
17.
325.
1,838.
378.
33
72
33
34
65
77
87
97
00
39

4.
1,250.
994.
15.

,14
33
43
59
263.00
16.20
25.39
30.25
10.71
7.28

0.





















0
1
1
1
1
1

924
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1

.996
.001 2378-TCDD AN
.006
.012
.020
.036

-1.076
.000
.908
.918
.922
.928
.934
.949
.957
.959
.975
.983
.989
.001 37C1-TCDD SUR1
.015
.022
.025
.027
.034
.048
.054

0.924-1.076

3.99
1.540.82
1,245.32
21.97
0.
0
0
1.
1.
.'000
.957
.993 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.012


0.923-1.061
0.000
629.
9.
15.
14.
17.
10.
196.
1,091.

11
32
64
26
21
86
99
59

414. 'SI
15.93
8.37
6.92
8.93
9.81
128.98
746.41

0.
0.
0.
0.
0.
0.
0.
0.
0.
934
940
946
950
956
959
967
972 .
976
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 09:29 01/15/98
                                                                       353

-------
 Page No.
 01/15/98
Listing  of T980164B.dbf
Matched  GC Peaks / RaCio  /  Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.












340-342
13C12-PeCDF
352-354








352-354
PeCDD
356-358
^ A












356-358
13C12-PeCDD
368-370




368-370
28:48
.29:07
29:13
29:25
29:30
29:39
29:46
30:10
30:19
30:37
DC SN 30:51
31:08
19 Peaks

DC NL 0:00
28:37
28:49
29:29
29:45
DC SN 29:54
30:09
DC SN 30:25
31:07
6 Peaks

DC NL- 0:00
28:46
DC SN 28:55
29:14
29:27
29:35
29:46
29:59
30:12
30:20
30:31
30:38
30:58
DC WH 31:10
11 Peaks

DC NL 0:00
DC SN 28:45
DC SN 29:25
30:29
30:37
2 Peaks










RO


1





RO

RO
RO

1.

RO
RO
RO





RO


RO
RO

1.
RO
RO




1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

52
43
49
50
50
52
52
45
43
38
05
63

376.33
529.76
830.32
354.28
272.94
237.81
371.00
362.52
429.21
98.62
3.92
44.97
7,210.41
227
312
496
212
163
143
223
214
252
57

27

.05
.00
.78
.50
.59
.30
.53
.47
.86
.23

.35

149
217
333
141
109
94
147
148
176
41

17

.32-1.78
1.
1.
1.
1.
1.
0.
1.
4.
1.

32-
1.
1.
0.
1.
1.
1.
1.
1.
• 1.
0.
1.
1.
1.
2.

32-
1.
5.
1.
1.
1.

41
44
33
39
48
35
43
53
10

1.78
45
28
02
16
56
63
64
49
69
48
44
63
38
37

1.78
12
17
33
46
44

0.99
15.25
6.16
2,699.35
25.95
2.99
2,611.27
3.67
5.23
5,363.21

0.98
373.39
2.99
23.46
266.21
38.31
164.70
65.09
71.19
29.02
35.86
21.13
18.59
1.17
1,112.45

9
3.
1,570,
15,

1,535.

3.

.00
.52
.34
.48

.11

.18

6
2.
1,129
10

1,076,

2.
.28
.76
.54
.78
.35
.51
.42
.05
.35
.39

.12

0.977
0.988
0.991
0.998
1.001 12378-PeCDF
1.006
1.010
1.023 23478-PeCDF
1.028
1.038
1.046
1.056





AN


AN



J

0.864-1.136

.25
.64
.01
.47

.16

.90
0.000
0.971
0.977
1.000 13C12-PeCDF 123
1.009
1.014
1.023 13C12-PeCDF 234
1.032
1.055



1 32


SUR2





230.

14.
162.
24.
102.
38.
44.
17.
21.
13.
13.



00

26
38
35
32
95
74
64
19
10
71



179.

12.
103.
14.
62.
26.
26.
37.
14.
3.
7.


0.937-1.021

00

34
33
46
38
14
45
03
67
03
29


0.000
0.944
0.949
0.959
0.966
0.970
0.976
0.984
0.991
0.995
1.001 12378-PeCDD
1.005
1.016
1.022




J

J



J
AN J
J
J


0.869-1.131
0,46
0.39
1.91
1,801.71
175.87
1,977.58



1,063.
103.




17
71




733.
72.




54
16

0.000
0.943
0.965
1.000 13C12-PCCDD 123
1.004




IS3


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed:
1/15/98

-------
  Page No.
  01/15/98
Listing  of T980164B.dbf
Hatched  GC Peaks / Ratio  / Ret. Time
  Compound/
  M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name..  ID..  Flags.
HxCDF
374-376










M
AN

M
374-376
13C12-HXCDF
384-386









384-386
HxCDD
390-392







M
M


390-392

13C12-HXCDD
402-404
DC NL 0
J 31
32
32
: 32
32
DC SN 32
1 32
32
33
33
1 33
! 34
1 34
!
34
1
:00 RO
:56
:04
.05-1.43
2.06
1.31
1.31
:13 1.42
:22
:31 RO
:41 RO
:52
:59
:07
:16
:30
:14
:18

:22
1.26
1.44
0.66
1.
,27
1.37
1.
1.
1.
1.
1.

1.
.18
,34
,30
.42
22

24
13 Peaks

DC NL 0
DC SN 31
DC SN 32:
: 32:
• 32:
DC SN 33:
33:
DC SN 33:
34:
DC SN 34:
0,
:00 RO
:56
:01
:52
:58
:1S RO
:29
:46 RO
:17
:39 RO
; rv*~w i iw
3.38
228.18
453.50
29.19
52.20
27.19
2.64
366.29
157.23
30.59
54.50
131.32
7.24
7.04

32.00
1,576.47
* uf r w i j.
129
257
17
29
17

205
90
16
31
74
4
3

17

.31
.07
.12
.06
.48

.15
.76
.54
.19
.13
.25
.37

.70

98
196
12
23
12

161
66
14
23
57
2
3

14

.43-0.59
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
4 Peaks
i
•
DC NL 0:
32:
DC SN 32:
32:
33:
33:
DC SN 33:
DC SN 33:
33:
i 33:
: 33:
DC WH 34:
. 1.
:00 RO
24
32 RO
51
04
14
25 RO
29 RO
36
41
59
12 RO
63
57
44
52
51
32
53
37
51
40

05-1.43
0.
1.
0.
1.
1.
1.
0.
2.
1.
1.
1.
1.
40
22
52
22
26
12
83
96
23
31
26
48
7 Peaks


DC NL 0:

1.
00 RO

05-
2.

1.43
24
3.55
4.11
5.54
2,085.20
2,263.25
3.43
2.155.53
2.31
1.903.28
2.66
8,407.26
Wvf ntr / u vf*
rut*— ur i nxu
0.39
41.13
0.54
198.34
100.49
8.70
0.45
1.21
9.05
24.50
30.36
0.52
413.07




715
766.

'745.

641.




.56
.17

.38

.22




1,369
1,497

1,410

1,262

0.963-1.047
0.000
.87 0.969
.43
.07
.14
.14

.14
.47
•05
.31
.19
.99
.17

.30

0.973
0.977
0.982
0.986
0.991
0.997 123478-HxCDF AN
1.001 123678-HxCDF AN
1.005
1.009
1.016 234678-HxCDF AN
1.038
1.040 123789-HXCDF AN

1.042


J
J
J



J
QJ

J
PRJ

J

0.379-1.121



.64
.08

.15

.06

0.000
0.969
0.971
0.997 13C12-HXCDF 473 SUR3
1.000 13C12-HXCDF 678 IS4
1.010
1.016 13C12-HXCDF 234 ALT2
1.024
1.040 13C12-HXCDF 789 ALT1
1.051










*nn i?rti i ?*i*io


22.

109.
56.
4.


4.
13.
16.




59

11
09
59


99
90
95




18.

89.
44.
4.


4.
10.
13.



0.953-1.014

54

73
40
11

•
06
60
41



0.000
0.962
0.966
0.976
0.982
0.987
0.993
0.995
0.993 123478-HxCDD AN
1.000 123678-HxCDD AN
1.009 123789-HXCDD AN
1.016



J



J


J
J
PRJ



0.970-1.030
1.36




0.000

Triangle Laboratories, Inc.®  Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729;* Fax: (919) 544-5491
                                                                 Printed:
W/15/98

-------
  Page No.
  01/15/98
Listing of T980164B.dbf
Matched GC Peaks / Ratio / Ret. Time
  Compound/
  M_2	 QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name.. ID.. Flags.








402-404
HpCDF
403-410







408-410
13C12-HpCDF
413-420




418-420
HpCDD
424-426




424-426
13C12-HpCDD
436-438

436-438
OCDF
442-444


33:03
33:35
33:40
33:53
34:00
34:17
DC SN 34:22
DC SN 34:29
6 Peaks

DC NL 0:00
35:59
36:17
36:26
DC SN 36:38
DC SN 36:48
37:36
DC WH 37:54
4 Peaks

DC NL 0:00
35:59
DC SN 36:29
37:36'
DC SN 38:09
2 Peaks

DC NL 0:00
DC SN 36:09
36:17
DC SN 36:35
37:05
2 Peaks

DC NL 0:00
37:04
1 Peak

DC NL 0:00
DC WL 35:29
DC WL 35:41
RO


RO

RO
RO
RO

0
RO



RO
RO
RO
RO

0.
RO





0.

RO

RO


0.
RO


0.
RO

RO
1.
1.
1.
0.
1.
0.
1.
2.

,57 .
.21
,22
.65
20
,71
76
50

6
1,648
2,007
6
2,230
6
4
1
5,904
.76
.36
.08
.07
.33
.32
.91
.93
.92
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Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 09:<
3U15/98
)D

-------
  Page No.      6          Listing of T980164B.db£
  01/15/98                 Matched GC Peaks / Ratio / Rec.  Time

  Compound/
fcM_Z.... QC.Log Omit  Why  ..RT. OK Ratio Total.Area...  Area.Peak.1.. Area.Peak. 2. .  Rel.RT Compound.Name..  ID..  Flags.

                  --   --   	  -  --          - "                              0.881
                                                                                  0.887
                                                                                  0.893
                                                                                  0.903
                                                                                  0.906
                                                                                  0.918
                                                                                  0.921
                                                                                  0.923
                                                                                  0.925
                                                                                  0.927
                                                                                  0.932
                                                                                  0.934
                                                                                  0.942
                                                                                  0.945
                                                                                  0.951
                                                                                  0.960
                                                                                  0.964
                                                                                  0.973
                                                                                  0.982
                                                                                  0.985
                                                                                  0.985
                                                                                  0.994
                                                                                  0.997
                                                             46.21         54.91   1.005 OCDF            AN
                                                                                  1.011
                                                                                  1.017
                                                                                  1.019
                                                                                  1.027
                                                                                  1.029


                                                                             0.902-1.098
                                                                                  0.000
                                                             23.40         30.60   1.000 OCDD            AN
                                                                                  1.007


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Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713                                             Printed- 09-9Q
Phone: (919) 544-5729 • Fax: (919) 544-5491                                                               3

-------
 Page Ho.
 01/15/98
Listing of T980164B.dbf
Hatched OC teaks  I  Ratio  / Ret. Time
 Compound/
 M_Z....  QC.Log Omit why ..RT.  OK Ratio Total.Area... Area.Peak.1..  Area.Peak.2. .  Rel.RT Compound.Name.. ID.. Flags.
 Column Description	   "Why" Code Description	   QC  Log Desc.
 M_2   -Nominal ton Hass(es)
 ..RT.  -Retention Time (mm:ss)
 Rat.l  -Ratio  of M/M+2 Ions
 OK    -RO=Racio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report *»*
       WL-Below Retention Time Window
       WH-Above Retention Time Window
       SN-Below Signal to Noise Level
       
-------
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TSIANGLE LABS  Text:TLI#44376 137-140                        INJ.  TIME -   01:05
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Text:TLI#44376 137-140
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Text:TLIt44376 137-140
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363

-------
        32:24   32:36   32:48    33:00   33:12   33:24    33:36   33:48   34:00
Tlle:T980164  #1-396 Acq:7-JAN-98 01:07:26 EI+ Voltage SIR  70T Koiee:929
401.8558 T:3  BSU3(2S6,30, -3. 0)  PKB(7, 5,3, 0. 05%,3716. 0,1. 00\,T, T) Eip:NDB5aS
TRIANGLE LASS  Text:TLI*44376  137-140                       INT. TIME -    01:09
1004                                                        ,,  ,rtP7       A1.22E7
riJ.eiTSaOJ.64  91-136 Acq: 7-JXN-Hlt U1:U/:J6 Eli-  Voltage SIX 70T HO3.au: J4J
389.8156 r,3  BSUB(236, 30, -3.0) FXD(7,5,3, 0.05%, 972. 0,1.00\,f,T)  Sip:SDS5US
TRIANGLE LASS  TextiTLH44376 137-140                        1X7. TIMX -   01:09
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        32,24   32:36    32:48   33,00   33,12    33,24   33:36   33:13   34:00
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391.8127 f:3  BSUB(2S6,30,-3.0)  PKD(7,5,3,0.05\,2452.0,1.00\,r,T) XrpiXDBSVS
TSIANSLX LASS  Text:TLH44376 137-140                        XKT. TIMX -   01:0
100A                      AS. 97X5
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403.8529 Ts3  SSUS(256,30, -3. 0) PKD(7, 5,3, 0. 05\,1660. 0,1. 00\,T, T) Xxp:HDB5US
TRIANGLE LASS Text.-TLIf44376 137-140                       UtJ. TIKE -   01:03
•100*                                                        A9.04E6       A1.Q1E7

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        32:24   32:36   32:48    33:00    33:12   33:24   33:36    33:48    34:00
r±le:T980164 fl-396 Acq:7-J2Ut-98 01:07:26 XI+ Voltage SIX 70T.
392.9760 T:3 XxptSDBSVS
TSIANSLX LASS  Text:TLIt44376 137-140                        XK7. TIHX -   01:03
                                                                                  34:12   34:24
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        32,24   32:36   32:48   33:00    33:12   33,24   33:36   33:48    34:00    34:12   34:24
                                                                                          0.0X0
                                                                                             Time

-------
rlle:T980164 #1-563 Acq:7-J7Ur-98 01:07:26 XI+ Voltage SIS 70T No±aei244
407.7818 f:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0.05\,976.0,1.00\,r,T) SxptNDBSOS
TRIANGLE LABS Text: TLIf 44376 137-140 HKT. TIME - 01: 09
1001
80:
60:
40:
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0:
A1.31X6
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409.7789 Ti4 BSUB(256, 30, -3. 0) PKD(7,5,3, 0.05%, 764. 0,1. 00*,r,T) XxptBDBSUS
TRIANGLE LABS Text:TLI#44376 137-140 OKT. TIME - 01:05
1003
80:
50:
40:
20:

A1.21E6
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36:60 ' 36:12 '36:24 36\36 J5-48 37:00 37:12 37:24 37:36
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417.8253 r:4 BSUB(2S6, 30, -3. 0) PKD(7,5, 3, O.OS\,1536. 0,1 . 00\,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 137-140 IKT. TIME - 01:05
1003
80:

50:
40:
20:
0:
AS . 02X6
A i
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A4.24X6
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35:00 , 36>:12 36-24 36:36 36^.48 37\00 37:1.2 37:24 37\ 36
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419.8220 F:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0 .05\,2420 .0,1.00*,F,T) Elp-.NDBSUS
TSIANGLE LABS Teit:TLI#44376 137-140 JKT. TIME - 01:05
100J
80:
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A1.16E7 ,
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F±le:T980164 #1-563 Acq : 7 -JXN- 9 8 01:07:26 EH- Voltage SIS 70T
430.9729 F:4 Elp:in}B5CS
TXIAHGLE LABS Text:TLI#44376 137-140 IJTJ. TIME - 01:05
100J
80J
50:
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TSIAXGLE LABS Text:TLI#44376 137-140 IJKT. TIME - 01:05
1003
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36:52

36:16 ft 37:20 37*36
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TRIANGLE LABS Text:TLI>44376 137-140 HKT. TIMS '01:09
1001
901
801
701
601
501
401
301
201
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A4 . 62X5








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36:00 37:00 38:00 39:00 40:00 41:00 42:0
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TSIAXGLE LABS Text:TLIt44376 137-140 UKT. TIMX - 01:05
1001
901
801
701
601
501
401
301
201
101

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430.9729 f:4 ExpiNDBSUS
TRIANGLE LABS Text:TLI#44376 137-140 Utf. TIME ' 01:09
1001
901
801
701
601
501
40
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301
201
101
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513.6775 T:4 EiptSDBSUS
TRIANGLE LABS Text:TLIt44376 137-140 IJij; TIME - 01:09
1001

90.

80.
70.
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501
401

301
201
101
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36\00 37:00 jfliob 39\00 ' 40»00 41;00 43:00 Tiae
367

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459.7348 T:4  BSUB(256f 30, -3.0)  PXD(7,5,3, 0.05\,248.0r1.00\,T,T) Ezp:SDB5OS
TSIASSLX LASS  Text:TLI#44376 137-140                       IJKT. TXMK -   01:09
1001                    AJ.jSES
      40': IS         40:54         41:00         41:06         41:12
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F 3K 0 252
G 322 P 354
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Height 2,94 ydts Span 288 p
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-------
File:T980164 #1-810 Acq:7-JAN-98  01:07:26  EI+ Voltage SIR 70T
303.9016 F:2 Exp:NDB5US
 ample Text:TLI#44376  137-140                        INJ.  TIME =
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Sample Text:TLI#44376  137-140                        INJ. TIME =
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          24:36     24:42    24:48     24:54     25:00    25:06
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Sample Text:TLI#44376  137-140                        INJ. TIME =
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Sample Text:TLI#44376  137-140
100S,
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       25:48    25:54   26:00    26:06    26:12
File:T980164  #1-810  Acq:7-JAN-98 01:07:26 El-f
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 ample Text:TLI#44376  137-140
1004                                       A2 .
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Sample Text:TLI#44376  137-140
1001                                 26;09
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                                                                                                     CO
File:T980164 #1-810 Acq:7-JAN-98 01:07:26  EI+  Voltage SIR 70T
355.8546 F:2 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ.  TIME
100%.                                          A2.30E6
 60j
 40J
 20j
  OJ
                                                                   01:09  File  Text:TLI#44376  137»
                                                                                         _7.4E5
                                                                                         _5.9E5
                                                                                         _4.4E5
                                                                                         _3.0E5
    28:30             28:36             28:42             28:48
File:T980164 #1-810 Acq:7-JAN-98 01:07:26  EI+  Voltage  SIR  70T
357.8516 F:2 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ. TIME
100%
 80J
 60 j
 40J
 20 j
  OJ
                                                                           28:54
                                                   O.OEO
                                                      Time
                                                                   01:09 File Text:TLI#44376 137>
                                                                                         ..1.0E6
    28:30             28:36             28:42             28:48
File:T980164 #1-810 Acq:7-JAN-98  01:07:26-EI+  Voltage SIR  70T
367.8949 F:2 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ. TIME
                                                                           28:54
                                                      Time
100%
 80 j
 60J
 40J
 20J
  0.
                                                     45
                            01:09  File  Text:TLI#44376  137»
                                                  _4.7E3
                                                                      28:52
        28:31
    28:30
                      1	1	'
                      28:36
1	1	'
 28:42
28:48
                                                  L3.8E3
                                                  12.8E3
                                                  L1.9E3
                                                  L9.5E2
                                                  LO.OEO
28:54
Time

-------
^ile:T980l64 #1-396 Acq:7-JAN-98 01:07:26  EI +  Voltage  SIR  70T
373.8208 F:3 ExprNDBSUS
Sample Text:TLI#44376 137-140                        INJ. TIME  =
100%                                                 A1.77E5
01:09 File Text:TLI#44376 137»
                      r_5.8E4
  OH  --
    34:08  34:10  34:12  34:14   34:16   34:18   34:20   34:22  34:24
File:T980164 #1-396 Acq:7-JAN-98 01:07:26  EI +  Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376  137-140                        INJ.  TIME =
100S.                                               A1.43E5
 80J
 60J
 40J
 20 j
  OJ
 34:26-  34:28   34:30
                     LO.OEO
                         Time
    34:08  34:10  34:12  34:14   34:16   34:18   34:20   34:22  34:24
File:T980164  #1-396 Acq:7-JAN-98 01:07:26  EI+  Voltage SIR 70T
383.8639 F:3  Exp:NDB5US
Sample Text:TLI#44376  137-140                        INJ.  TIME =
100%                                34jLl7
  80 j
  60 j
  40J
  20_
   0
01:09 File Text:TLI#44376 137»
                      _4.8E4
                      L3.8E4
                      L2.9E4
                      L1.9E4
                      L9.5E3
                       .O.OEO
                          Time
34:26  34:28  34:30
01:09 File Text:TLI#44376 137»
                       1.7E6
                      Ll.3E6
                      11.0E6
                      L6.7E5
                      L3.4E5
    34:08  34:10  34:12   34:14   34:16   34:18  34:20  34:22  34:24  34:26  34:28  34:30
                       lO.OEO
                          Time


-------
nile:T980164 #1-396 Acq:7-JAN-98 01:07:26  EI+  Voltage  SIR 70T
389.8156 F:3 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ.  TIME  =
100%                                                   A1.39E5
                                                                 r~
                                                                 oo
 60
 40J
 20 j
A4.99E4
01:09 File Text:TLI#44376 137»
                       _4.5E4
                       L3.6E4
                       L2.7E4
                       L1.8E4
                       L9.0E3
                       LO.OEO
      33:26  33:28  33:30  33:32  33:34   33:36  33:38  33:40  33:42
File:T980164  #1-396 Acq:7-JAN-98  01:07:26  EI + Voltage SIR 70T
391.8127 F:3  Exp:NDB5US
Sample Text:TLI#44376  137-140                        INJ.  TIME =
lOOi                                                     A1.Q6E5
 80J
 60 j
 40J
 201
   0.
                            33:44  33:46 33:48  33:50  Time
                             01:09  File Text:TLI#44376  137»
                                                    3.6E4
                                                   L2.9E4
                                                   L2.2E4
                                                   L1.5E4
                                                   L7.3E3
                                                   LO.OEO
      33:26  33:28  33:30  33:32  33:34  33:36  33:38  33:40  33:42
File:T980164  #1-396  Acq:7-JAN-98 01:07:26 EI + Voltage SIR 70T
401.8558  F:3  Exp:NDB5US
Sample Text:TLI#44376 137-140
100%
               INJ.  TIME
                 33:40
  80j
  60 j
  40_:
  20 j
   0.
                                      33:35
33:44  33:46  33:48  33:50  Time

 01:09  File Text:TLI#44376  137»
                       _3.3E6
                       L2.6E6
                       L2.0E6
                       L1.3E6
                       L6.5E5
      33:26  33:28  33:30  33:32  33:34  33:36  33:38  33:40  33:42

                                                   LO.OEO
                            33:44  33:46  33:48  33:50  Time

-------
 'ile:T980164 #1-563 Acq:7-JAN-98 01:07:26 EI + Voltage  SIR  70T
457.7377 F:4 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ. TIME
100%                              A2.34E5
 80 j
 60 j
 40J
  0:
            -f	1  I
    40:24       40:36      40:48       41:00       41:12       41:24
File:T980164 #1-563 Acq:7-JAN-98 01:07:26 EI+ Voltage  SIR  70T
459.7348 F:4 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ. TIME =
1004                              A3.Q6E5
                                                                  01:09 File Text:TLI#44376  137»
                                                                                         _4.4E4
                                                                                         L3.5E4
                                                                                         L2.6E4
                                                                                         L1.7E4
                                                                                         L8.7E3
                                                                                         LO.OEO
                                                                          41:36
                                                41:48  Time
 80^
 60 j
 40J
 20 j
  Oj
                             01:09 File Text:TLI#44376 137»
                                                    7.1E4
                                                   L5.7E4
                                                   L4.2E4
                                                   L2.8E4
                                                   Ll.4E4
    40:24       40:36      40:48       41:00       41:12       41:24
 ile:T980164 #1-563 Acq:7-JAN-98 01:07:26  EI+ Voltage  SIR  70T
469.7779 F:4 Exp:NDB5US
Sample Text:TLI#44376 137-140                        INJ. TIME =    01:09
1004                               40j55
  60j
  40J
  20J
   Oj
                                                                          41:36
                                                   .^O.OEO
                                                41:48   Time
                                   File Text:TLI#44376 137»
                                                   r_2.0E6
                                                   Ll.6E6
                                                   L1.2E6
                                                   L7.9E5
                                                   L3.9E5
               1 - 1 - 1 - 1
                40:36
                            40:48
1  T - 1 - 1
  41:00
i  i°- |'  i  I  I  i	1	1	1	r
  41:12       41:24
-i	r—,	r-
  41:36
T	1	1	r
      41:48
: O.OEO
    Time

-------
TLI Project:      44376
Client Sample:   137-140
               Method 23 TCDD/TCDF Analysis (DB-225)
                                    Analysis File:  P9801f j
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:

yUtgtb*ag.

Gulp Aluminum Alloys
M23TRAIN Date Received:
194-59-9A-9D Date Extracted:
Date Analyzed:
1.000 Dilution Factor:
n/a Blank File:
DB-225 Analyst:

v " ^''-JkttiL faaV ' "'* ^5fk_ %
l"ar -f ^ -, ,,,
12/17/97
12/29/97
01/10/98
n/a
X980083
WK

*\-./Oyipfj. 0}
V"»« -~ -
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:

ix " <-CV ''".ftrffcj" "f^ '-f'-'i
5; V , >,
SPC2NF04
PF22206
P980164
n/a
n/a
n/a

W''' "' ">'l'la --..__ 	 \' ^^
2J.7.8-TCDF
   0.69
                          0.74
                      23:06     	
 Internal Standard
AmL (ngfr
% Recovery  QCL&nfts     Ratio
                       fiT
13C12-2,3,7(8-TCDF
   2.9
   72.5
40%-130%
0.77
23:04     	
 Recovery Standard
                                       Ratio
                                          Flags
13C12-1,2,3,4-TCDD
                                        0.81
                                  21:54
                      Data Reviewer
                                    01/11/98
                                          Page 1 of 1
                                                  C2NFJ>SR riOl. URS 4.10.03
Triangle Laboratories, lnc.«
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                              Printed: 13:36 01/11/98
                                                                             376

-------
                         Initial    	Date...

                                    I / If /(7   Calculated Noise Area:
  Data  Review By:
  The Total Area for each peak with an ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
                                                                       2.00
  Page Ho.
  01/11/98
Listing of  P980169B.dbf
Hatched 1/1l/98
                                                                           3 e «

-------
  Page No.     2           Listing of  P980169B.dbf
  01/11/98                 Matched GC  Peaks  / Ratio / Ret. Time

  Compound/
  H_Z	QC.Log Omit Why ..RT.  OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID.. Flags.

                                                                                 0.936
                                                                                 0.944
                                                                                 1.000 13C12-2378-TCDF ISO
                                                                                 1.018
                                                                                 1.027
                                                                                 1.092
  316-318               3 Peaks               3,177.02
DC
DC



DC
WL 21:35
WL 21:47
23:04
23:29
23:41
WH 25:12
RO

RO
RO

1.
0.
0.
1.
1.
0.
02
82
77
15
14
65
14
15
3,161
6
9
29
.73
.14
.05
.78
.19
.58

1,372.
4.
5.


31
39
93


1.788.
3.
S.


74
33
19

                                       Above: TCDF / TCDD Follows
  13C12-TCDD                     0.65-0.89                                     0.907-1.093
  332-334
DC





DC
DC
DC
NL 0
20
21
21
22
23
WH 23
:00 RO
:30 RO
:38
:54
:40
:17 RO
:57 RO
WH 24:13 RO
WH 24
:32 RO
2.11
1.00
0.30
0.81
0.80
0.53
0.90
1.21
0.62
1
9
2,519
3,142
26
4
4
11
26
.29
.84
.14
.22
.63
.87
.76
.45
.85

5
1.116
1,409
11
2




.56
.05
.65
.83
.12




5
1.403
1,732
14
4




.56
.09
.57
.80
.03



0.000
0.948
1.000
1.012
1.048
1.076
1.107
1.119
1.134


13C12-2378-TCDD IS1
13C12-1234-TCDD RSI





 332-334               5  Peaks               5,702.70
 Column Description	   "Why" Code Description	   QC Log Desc.
 M_Z   -Nominal Ion Mass(es)     WL-Below Retention Time Window   A-Peak Added
 . .RT. -Retention Time (mn:ss)   WH-Above Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SN-Below Signal to Noise Level   D-Peak Deleted
 OK    -RO-Ratio Outside  Limits  
-------
File:P9Bol6S  41-922  Acq-.10-JAll-l.lM* 15:13:15  21+ Voltage 4I& 70P
303.9016 BSOB(256,30,-3.0) PKD( 5,3,1,0.101,2164 .0, 0.00*,r,f) Sxp:DB225
TRIANGLE LASS  Text:137-140   TLH44376
1003,                                   A2.67E7
   *                         A1.11E7

  804             !
.  so:

  40:

  20:
Al.06E7
                .43E6\  A4.76E6    A5.28E6
                                                         A.
                                  A4.83E6
                                                                                  A2.07ES
                                                                                     A
            19': 00        20': 00        21:00        22:00        23:00        24:00
rile:P980169  #1-922  AdjilO-JTOf-1998 15:13:15 EH- Voltage SIS 70P Soiae:433
305.8987 BSUB(256,30,-3.0)  PKD(5, 3,1, 0.101,1732. 0, 0. 00%,t,T) Exp:DB225
TRIANGLE LABS  Text:137-140   TLI#4437S
IQOi,             i                      A3.f2E7
                                                                      25:00
  80.

  so:

  40.

  20.
                            A1.27E7
.14E6\  A6.30E6    A7.19E6       Ag.S7E6
                                                                                  A2.92E6
            19:00         20:00        21:00        22:00        23:00        24:00
F±le:P9a0169  #1-922 Ac
-------
tile:P9B016S H-9M Acq:LO-Xat-L99B  15,13:15 £1+ Voltage SlS 70P Hloiae:6l9
319.8965 BSOB(256,30r-3.0) PKD(S,3,l,0.10\r2476.0,0.00\,r,T) Sxp:DB225
TRIANGLE LABS  Text:137-140   TLH44376
1001A9.69E6
  BO.

  SO.

  40.

  20.
A7.07E6
                              A1.24E6
                           A y\/V
                                               A2.00E6
                 20:00           21i00           22:00           23:00
File:P980169  tl-922 Acq:10-JAK-199B  15:13:15 EI+ Voltage SIS 70P Hoiae:1255
321.8936  BSUB(256,30,-3.0) PXD(5, 3,1, 0.10\,5020. 0, 0. 00\,T,r) ExpsDB225
TRIANGLE  LABS  Text: 137-140   TLI#44376
100i.Al.24E7
                                                                   24:00
  so:

  60.

  40.

  20.
A8.85E6
                          A
                              Al.66E6
                                              A2.47E6
                20:00            21:00           22:00          23:00
rile:P980169  tl-922 Acq:10-JAN-1998  15:13:15 EI+ Voltage SIR 70P Noise: 614
327.8847 BSUB(256, 30, -3 . 0) PKD(5, 3,1, 0.10%, 2456. 0, 0. 00%,F,F) Exp:DB22S
TRIANGLE LABS  Text:137-140   TLI#44376
1003                                      A2.21E7
                                                                                24 : 00
  80.

  60.

  40.

  20.
    Al.66E7
                                 A1.12E7
                                                                             A2.98E6
                                                                               A
                20:00           21:00           22:00           2J.-00
File:P980169  #1-922 Acq:10-JAN-1998 15:13:15 EH-  Voltage  SIR 70P No±se:770
331.9368 BSUB(256,3Q,-3.0)  PKD(5, 3,1, 0.10%, JOflO. 0, 0. 00%,7,F) Exp:DB225
TRIANGLE LABS  Text: 137-140   TLI#44376
IOCS                                          A1.41E7
 80.

 60:

 40.

 20:
                                                                  24:00
                20:00           21:00           22:00           23:00
Tile:P9aoi69 #1-922 Acq:10-JJOt-1998 15:13:15 EI+ Voltage SIX  70P Noiae:364
333.9338 BSUB(256,30,-3.0)  PKD(S,3, 1,0.101,1456.0,0.00\,r,P)  Exp:DB225
TRIANGLE LABS  Text: 137-140   TLI044376
1003k                                         A1.73E7
                                                                  24:00
 80.

 60.

 40.

 20.

  0.
                                         A1.40E7]
                             J  V
-2.7E6

.2.1E6

.1. 6E6

-1.1E6

-S.4E5

 O.OEO
-3.5E6

'.2.8E6

.2.1E6

.1. 4E6

.7.1E5
                                                                                                   O.OEO
                                                                                                      Tim>
                20:00
                                21:00
                                                22:00
                                                                23:00
                                                                                24 • 00
.4.9E6

'.3.9E6

'.2.9E6

.1 . 9E6

.9 . 7E5

.O.OEO
    Time



.3.2E6

.2.6E6

.1.9E6

.1.3E6

.6.5E5

.O.OEO
    Time



.3.8E6

3 . OE6

2.3E6

.1 . 5E6

7.SE5

O.OEO
    Time
                                                                                                3SO

-------
rila:P980169 #1-522 Acq:10-JAN-1998 15:13>15 EI+  Voltage SIS  70P
303.9016 Exp:DB225
TRIANGLE LABS  Text: 137-140   TLI#44376

                             20:23     2i!U
  SO.
    :
  40'

  >°
     18:30

                                             21.-J6
                                                        22:25
                                                                      "
                                              MAJ    /UAAA
           15-00        20:00        21:00        22:00       2J.-00
rile:P980169 #1-522 AOJ.-10-J3U/-155S 15.-1J.-15 EI+  Voltage SIR 70P
315.9419 Exp:DB325
TRIANGLE LABS  Text: 137-140   TLI#44376
1003,                                                           23; 04
  40

  20J
                                                                           24:00
                                                                                        25 .-00
           15:00,        20:00        21:00        22:00       2J.-00
File:P980169 #1-522 Acq: 10-JAN-1998 15:13:15 EI+  Voltage SIS 70P
319.8965 Exp:DB225
TRIANGLE LABS  Text:137-140   TLI#44376
                                                                           24-00
                                                                                        25:00
1003

 80J


 40J

 20J

  OJ
               15:20
                                A
                                    20:55
                                                 21:56
           15:00,       20:00        21:00        22:00        2J: 00
File:P980169 #1-522 Acq: 10-JAN-1998 15:13:15 EI+ Voltage SIS 70P
331.9368 Exp:DB225
TRIANGLE LABS  Text: 137-140   TLIS801dS #1-522 Acq: 10-JAN-1998 15:13:15 EI+ Voltage SIS 70P
252.5825 £zp:DB225
TRIANGLE LABS  Text:137-140   TLI444376
                            20:15      21:05    21:52      32:4323:09
                                                                           24 .-00
                                                                                        25:00
                                                                                24:27  24 .-
           15:00        20:00        21:00        22:00        2J1-00
rile:P980169 #1-522 Acij:10-J7Ur-1558 15.-1J.-15 EI+ Voltage SIS 70P
330.9792 Exp:DB325
TRIANGLE LABS  Text: 137-140   TLI#44376
1003,       18:57        19:53     20:38     21:21          22:25   2J.-04
    H xv"-v"~^v*>'"\ rwv^^^1^ /*-V~~VY~V^~N<^w-'T'^*^^—^v-««^
 80J

 50J
 20
                                                                           24 .-00
                                                                          33:5734:23
                                                                                       25-00
                                                                                           25:15
                                                                                           /-~~v*r>-
           15^00
                        201- 00
                                    211- 00
                                                 22: 00
                                                              23:00
                                                                          24:00
                                                                                       25:00
                                                                                                     4.1Z5

                                                                                                     J . Jrff

                                                                                                     2.525

                                                                                                     1 . 6E6
                                                                                                       Tia
                                                                                                    3.0E6

                                                                                                   L2.4«

                                                                                                   .1.8,,

                                                                                                   .1.2,,

                                                                                                   ...1,5
                                                                                                    o.oro
                                                                                                       Time
                                                                                                    2.7E6

                                                                                                   '.2.2E6

                                                                                                   -.1.6E6

                                                                                                   .1.1E6

                                                                                                   -.5.4E5
                                                                                                    o.oro
                                                                                                       Time
                                                                                                    3.2E6

                                                                                                   .2.6E6

                                                                                                   .1 . 9E6

                                                                                                   .1.3E6

                                                                                                   .6.SE5
                                                                                                    O.OEO
                                                                                                       Time
                                                                                                  -3.1E6

                                                                                                   .6.5E6

                                                                                                   .4.9E6

                                                                                                   .3.3E6

                                                                                                   .1. 6E6

                                                                                                   O.OEO
                                                                                                      Time



                                                                                                   1.1E7

                                                                                                   .8.6E6

                                                                                                   .6.4E6

                                                                                                   .4.3E6

                                                                                                   .2.1E6
O.OEO
   Tiae
                                                                                             3S1

-------
Ref, lass    292,9825     Peak top
Helojt  1.47 wits  Span   266 ppt
Systea file naie             06225
Data   file naie         fl=P988169
Resolution                   16666
Groupnuiber                     1
loniiatlon aode                El*
Switching                  VOLTfiGE
Ref, lasses   292,9825,   386,9761
                      J   338,9792
                      K   331,9388
                      L   333,9338
    315,9419          I   375,8364
    317,3389
    319,8965
    321,89$
    327,8847
    338,9732
    363,9616
Channel   I  338,9792     Peak top
Height  1,87 volts  Span   266 ppi

-------
TLI Project:
  lient Sample:
44376
CleanUp Blk
        Method 23 PCDD/PCDF Analysis (a)
                      Analysis File:  T980167
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
XAD Date Received: / /
TLIdean-Up Date Extracted: 12/31/97
Date Analyzed: 01/07/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst CRV
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980160
n/a
n/a
n/a

2,3,7,8-TCDD
U,3,7,8-PeCDD '
U,3,4,7,8-HxCDD !
U,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD

ND
ND
ND
ND
ND
ND
EMPC

0.003
0.004
0.005
0.004
0.004
0.004
0.02







JB!
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
  ,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
           ND
           ND
           ND
           ND
           ND
           ND
           ND
           ND
           ND
           ND
0.003
0.003
0.003
0.003
0.003
0.004
0.004
0.003
0.004
0.004
llllllllllll^



S8SSftSSiS8SS^5SSSSi»SSS^S::SJ::
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD

Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
           ND
           ND
           ND
           ND

           ND
           ND
           ND
           ND
    0.003
    0.004
    0.004
    0.004

    0.003
    0.003
    0.003
    0.003
                                            Page 1 of2
                                                            X2J7 _PSR rZOl. LARS 6.10 OS
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                         Printed: 14:06 01/11/98

-------
TLI Project:      44376
Client Sample:   CleanUp Blk
                           Method 23 PCDD/PCDF Analysis (a)
                                       Analysis File:  T980167
"Internal Standards ^ "•"
"• •. *. f v. f <
13C,2-2,3,7,8-TCDF
13C,r2,3,7,8-TCDD
13Cl2-l,2J,7,8-PeCDF
l3Ci2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6J,8-HxCDF
I3C12-l,2,3,6,7,8-HxCDD
uC,2-l,2J,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Alternate Standards (Typo A)
l3Ci2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Amt;(iig| 'fs\ %^>>^>^-ft f tfff -f; jfr SV
52.5
54.6
68.7
76.8
63.7
80.6
84.9
108
115
% Recovery
74.5
69.2
/^•wtitM^?", * ••S
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QC limits
40%-130%
40%-130%
•WpK. s<*vixf}Sfy$?!iy-
0.72
0.82
1.41
1.45
OJ1
123
0.44
1.03
0.89
Ratto
0.52
0.51
tyf\ •• "• f •. \ ^ A ^ ff .;•'•
25:38 	
26:19 	
29:29 	
30:29 	
32:58 	
33:40 	
35:59 	
37:04 	
40:54 	
ITT fHagis
34:17 	
33:29 	
Recovery Standards
13C,2-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
Ratio
0.83
8T
26:08
34:00
flags
—
Data Reviewer
                                   ^" / /
01/1U98
                                       Page 2 of 2
                                                   X2ITJ>SR r2X)I. LARS 4.IO.OS
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                Printed: 14:06 01/11/98
                                                    3S4

-------
  Data Review By:


  "he Total Area for each
   atio limits has been
                        Initial
                                    ..Date..
                                              Calculated Noise Area:
  peak with an ion abundance ratio outside
recalculated according to method requirements.
                                               0.78
  Page No.
  01/11/98
   Listing  of T980167B.dbf
   Matched  OC Peaks / Ratio
                                                 / Ret.  Time
  Compound/            i
  M_Z.... QC.Log Omit Why ..RT.  OK Ratio Total.Area...  Area.Peak. 1..  Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
TCDF
304-306
D
D
D

304-306
13C12-TCDF
316-318





316-318
"CDD
\ 0-322
D














320-322
37C1-TCDD
328





DC
D
. D
D
DC

NL
SN
SN
SN
SN

0
23
24
24

:00
:45
:03
:39
26:30
0
RO
RO
RO

RO
65-0.39
1
1
0
0
1
.36
.17
.91
.70
.34
0 Peaks

DC
DC





NL
WL





0
22
24
25
25
26

:00
:40
:39
:1S
:38
:03
0

RO
RO



1
5
3
4
0
0
.17
.42
.81
.29
.87
.00
65-0.89
0
0
1
0
0
0
4 Peaks

DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH

0
23
24
24
24
24
24
24
25
25
25
25
26
26
26
27

:00
-.55
:16
:20
:31
:38
:44
-.52
:07
:37
:48
:S6
:09
:30
:S3
:42
0.

RO


RO

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.39
.55
.00
.34
.72 2
.82
2
65-0.39
0
1
0
0
0
0
1
1
0
1
0
1
2
1
2
1
.39
.79
.66
.77
•51
.70
.18
.33
.32
.82
.32
.22
.73
.05
.09
.57
0 Peaks
1
1
4
10
,270
18
.21
.47
.16 2.34
.64 4.86
.60 951.54
.66 8.40
0.876-1.072
0
0
0
0
1

. 000
.927
.938
.962
.034

0.961-1.039
0
0
2.35 0
5.78 0
1.319.06 1
10.26 1
.000
.384
.962
.985
.000 13C12-2378-TCDF ISO
.016
.304.06
TC DF / TC DD Fo 1 1 ows - - —

0
2
2
0
0
0
0
0
1
1
0
1
0
0
0
0
0
34
73
33
53
90
30
30
27
08
58
78
13
85
99
80
65
00
0.901-1.043
0
0
0
0
0
0
0
0
0
0
0.
0
0
1
1.
1.

000
909
922
925
932
936
940
945
954
973
980
985
994
007
022
053

0.924-1.076
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
0
:00



23:33
23:55
24:09
24:16
0
17
1.15
0
1.
0.
60
35
51
0.
0.
0.
0.
0.
000
895
909
918
922
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                     Printed: 12:29 01/11/98
                                                                             355

-------
  Pag* Mo.
  01/11/98
Listing of T980167B.db£
Matched GC P*alcs /  Ratio / R*t.  Tim*
 Compound/
 H_Z	QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2..  Rel.RT Compound.Mama.. ID..  Flags.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
328
13C12-TCDD
332-334 DC
DC








332-334
PeCDP
340-342 DC
DC
DC
DC
D D
DC
DC
D D
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2

NL
WL








8

NL
SN
SN
SN
SN
SN
SN
SN
SN
24:24
24:31
24:38
24:40
24:51
25:00
25:11
25:17
25:37
25:45
25:48
25:55
26:05
26:10
26:18
26:25
26:36
26:43
26:54
27:10
27:16
27:20
27:26
27:42
27:45
Peaks

0
23
25
25
25
26
26
26:
27:
27:

:00
:49
:14
:48
:59
:08
:19
:39
:09
:16
0.
RO
RO
RO
RO
RO



RO
RO
0.47
0.77
0.28
0.30
0.59
31.83 31.83
0.37
0.58
0.41
0.27
0.17
0.27
0.61
0.42
0.76
0.13
0.40
0.47
1.49 1.49
0.16
0.19
0.37
0.23
0.50
0.48
33.32
.65-0.39
1
1
0
3
0
0
0
0
1
2
Peaks

0:
27:
27:
27:
28:
28:
28:
29:
29:

00
43
:51
;55
: 37
48
:57
:13
,22
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
.81'
.48
.64
.11
.58
.83 2
.82 1
.88
.38
.20
4
3
4
9
3
2
,797
,907
35
3
1
,761
m^rv
32-1.78
0
0
0
0
1
1
0
1
0
.81
.82
.54
.11
.95
.08
.94
.13
.78
0
0
0
0
5
1
0
3
0
.34
.18
.63 4.19
.89 6.84
.30 1.00
.47 1,266.48
.62 862.28
.05 16.45
.52 2.74
.98 2.46
.46

.63
.51
.41
.08
.64
.15
.53
.32
.77
0.927
0.932
0.936
0.937
0.944
0.950
0.957
0.961
0.973
0.978
0.980
0.985
0.991
0.994
0.999 37C1-TCDD SOR1
1.004
1.011
1.015
1.022
1.032
1.036
1.039
1.042
1.053
1.054
0.924-1.076
0.
0.
6.58 0.
2.20 0.
1.73 0.
1,530.99 0.
1.045.34 1.
18.60 1.
1.99 1.
1.12 1.

000
905
959
980
987
993 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
013
032
036

0.928-1.061
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
940
945
947
971
977
982
991
996
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 12:29 01/11/98
                                                                     3S6

-------
  Page No.
  01/11/98
Listing  of T9801S7B.db£
Matched  GC Peaks / Ratio /  Rec.
Time
  Compound/
  •  Z.... QC.Log Omit Why .-RT.  OK  Ratio Total.Area... Area.Peak.l.. Area.Peak.2. .  Ral.RT Compound.Nan».. ID.. Flags.
D


D




340-342
13C12-PeCDP
352-354






352-354
PeCDD
356-358

D


D

356-358
13C12-PeCDD
368-370





368-370

HxCDP
374-376







D
DC
DC
D
DC
DC
DC
DC


DC








DC
DC
D
DC
DC
D
DC
SN 29:28
SN 29:40
SN 29:48
RO
RO
RO
SN 30:11
SN
SN
SN
WH
0

NL






6
30:20
30:53
31:08
31:23
RO
RO
RO
RO
1
1
1
1
0
0
0
0
.02
.19
.89
.46
.66
.08
.27
.20
Peaks


0:00
28:37
1
RO
RO
29:29
29
47
29:55
30:10
RO
RO
RO
31:07
32
0
2
1
0
0
1
1
Peaks

NL
0
SN 28:
SN 29:
SN 29:
SN 30:
SN 30:
WH 31:

00
55
29
45
20
30
27
1
RO
RO
RO
RO
RO
RO
RO
-1.78
.91
.16
.41
.85
.77
.23
.46
It WM*M
2
1
1
2
1
0
0
0
0

0
4
2,459
6
5
14
7
2,497
32-1.78
0
0
2
0
1
1
0
.94
.19
.54
.66
.36
.01
.85
0 Peaks

DC




DC

NL 0:
30:
30:
30:
30:
SN 31:

00
29
37
49
54
11
1
RO

RO
RO
RO
RO
32
1
1
1
0
0
5
-1.78
.21
.45
.24
.56
.68
.62
4 Peaks


DC
DC
DC
DC
DC
DC
DC
DC
1
1
1
NL
SN
SN
SN
SN
SN
SN
SN
0:
31:
32:
32:
32:
32:
32:
32:


00
56
04
10
14
31
31
36

1.
RO
RO

RO
RO
RO
RO


.02
.56
.79
.75
.02
.30
.54
.35
.00

.35
.08 3.46
.25 1.440.41
.38 4.18
.49 3.34
.84 9.02
.42 4.40
.96

0.28
0.69
2
0
0
1
0
0

0
1,524
151
1
1
1
1,680
o^/^nr
05-1.43
1
0
1
2
1
1
2
93
.83
19
33
71
67
55
1.30
0
1.
2.
0.
0.
0.
0.
0.
70
74
71
91
36
00

28
95 902.56
19 91.90
99 . 1.21
91 1.16
81
04


60
03
04
40
47
13
25
23
0.999 12378-PeCDP
1.006
1.011
1.024 23478-PeCDP
1.029
1.047
1.056
1.064

0.864-1.136
0.000
1.60 0.971
1,018.34 1.000 13C12-PBCDP 123
4.90 1.010
4.36 1.015
7.36 1.023 13C12-P6CDP 234
3.02 1.055

0.937-1.021
0.000
0.949
0.967
0.976
0.995
1.001 12378-PeCDD
1.032

0.369-1.131
0.000
622.39 1.000 13C12-PeCDD 123
73.99 1.004
2.15 1.011
1.71 1.014
1.023


•0.963-1.047
0.000
0.969
0.973
0.976
0.978
0.986
0.986
0.989
AN


AN








1 32


SUR2








AN




IS3















Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 «|Fax: (919) 544-5491
                                                                  Printed: 12:29 01/11/98

                                                                       QC7

-------
  Page Ho.
  01/11/98
Listing of T980167B.dbf
Hatched OC Peaks / Ratio /  Ret. Time
 Compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..  ID..  Flags.













374-376
13C12-HXCDP
384-386





384-386

HXCDD
390-392














390-392
13C12-HXCDD
402-404




402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC








DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC





SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
0

NL





5


NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0

NL




4
32:52
32:59
33:11
33:16
33:20
33:29
33:35
33:44
33:47
34:32
34:41
34:47
34:51
Peaks

0:00
31:55
32:58
33:29
34:17
34:40
Peaks


0:00
32:17
32:23
32:31
32:58
33:06
33:15
33:19
33:29
33:40
33:54
33:57
34:01
34:13
34:17
Peaks

0:00
33:03
33:40
34:00
34:27
Peaks
RO


RO
RO

RO
RO
RO
RO
RO
RO
RO

0.
RO
RO



RO


1.
RO

RO

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO

1.
RO



RO

3
1
1
7
2
1
2
0
0
0
0
0
0

.38
.41
.33
.75
.10
.05
.78
.36
.62
.21
.25
.56
.53

0
1
0
0
0
1
0
0
0
0
0
0
0
0
.83
.35
.28
.09
•22
.74
.20
.38
.23
.09
.20
.34
.29
.00
43-0.59
1
0
0
0
0
0


.33
.42
.51
.51
.52
.93


05-1.43
0
1
0
1
1
0
1
0
2
1
0
0
1
0
2

.68
.27
.62
.13
.79
.41
.67
.43
.47
.48
.78
.80
.93
.67
.35

1.18
3
2,092
2,166,
1,845
3
6,111
.76 1.27
.55 703.16
.62 735.94
.56 630.45
.44 2.13
.93
0
1
1
1
1
1
1
1
1
1
1
1
1

.997 123478-HxCDF
.001 123678-HxCDF
.007
.009
.011
.016 234678-HXCDF
.019
.023
.025
.048
.052
.055
.057

AN
AN



AN








0.879-1.121
0
2.99 0
l', 389. 39 1
1,430.68 1
1,215.11 1
2.28 1

.000
.968
.000 13C12-HXCDF 678
.016 13C12-HXCDF 234
.040 13C12-HXCDF 789
.052



IS4
ALT2
ALT1




0.
0.
0.
0,
1.
0.
0.
0.
1.
0.
0.
0.
0.
0.
1.
0.
.47
.59
.23
.49
.79
.36
,20
,16
,39
99
25
67
60
29
28
00
05-1.43
3,
1,
1,
1,
.50
.33
.23
.23
0.50


0.
5.
1,869.
2,325.
1.
4,202.
67
49 3.13
57 1,030.31
22 1,283.76
99 1.10
27
0.958-1.014
0
0
0
0
0
0
0
0
0
1.
1,
1,
1.
.000
.959
.962
.966
.979
.983
.988
.990
.995
.000 123678-HxCDD
.007
.008
.010 123789-HXCDD









AN


AN
1.016
1.

.013



0.970-1.030
0.
2.36 0.
839.26 1.
1,041.46 1.
2.19 1.

000
982
000 13C12-HXCDD 678
010 13C12-HXCDD 789
023



IS5
RS2


Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed:
01/11/98

-------
  Page No.
  01/11/98
Listing of T980167B.dbf
Matched OC Peaks / Ratio
/ Ret. Time
  Conpound/
 .M_2	QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.l..  Area.Peak.2..  Rel.RT Compound.Name..  10..  Flags.
HpCDF
408-410






408-410
13C12-HpCDF
418-420





413-420
HpCDD
424-426







424-426

DC
DC
DC
DC
DC
DC
DC


DC


DC
PC
DC


DC
OC
DC
DC
DC
DC
DC
DC

1
NL
SN
SN
SN
SN
WH
WH
0

NL


SN
SN
SN
2
i
NL
WL
SN
SN'
SN|
SN
WH!
WH
0

0
35
36
36
37
37
38

:00
:59
:27
:55
:45
:52
:03
0.
RO
RO
RO
RO
RO
RO
RO
.88-1.20
1
1
0
1
0
1
0
.36
.32
.45
.40
.74
.44
.72
Peaks

0
35
36
36
36
37

:00
:59
:27
:36
:48
:45
0.
RO


RO
RO
RO
0
1
1
0
0
0
0
0
.22
.39
.00
.61
.45
.69
.45
.00
,37-0.51
2
0
0
0
1
0
Peaks

0
36
36
36
36
37
37
37

:00
:05
:17
:27
:S2
:05
:33
:37
0.

RO

RO
RO
RO
RO
RO
.11
.44
.47
.15
.67
.32
*!*.*.•*»* .
0
1,759
6
0
1
1
1,765
UB./TM
.40
.25
.08
.59
.14
.25
.33
E> / UMJ-
88-1.20
1
0
1
1
3
3
2
0
.20
.45
.15
.70
.00
.00
.45
.32
Peaks
0
0
0
0
0
1,
0
0,
0,
.22
.73
.86
.61
.47
.06
.22
.41
.00
0.996-1.051
0
1
1
1
1
1
1

.000
.000 1234678-HpCDF AN
.013
.026
.049
.052
.057

0.944-1.111
0
534.28 1,224.97 1
1.94 4.14 1
1
1
1
*nn 1ff\^ i i*iiij«
.000
.000 13C12-HpCDF 678 IS6
.013
.017
.023
.049

0.975-1.005
0
0
0
0
0
1
1
1

.000
.973
.979
.983
.995
.000 1234678-HpCDD AN
.013
.015

 13C12-HpCDD
 436-438

 436-438
 OCDF
 442-444
                               0.88-1.20
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
1
1

NL
WL:
WL
WL:
SN
SNi
SN
SN
1
SN
0:
37:
00
04
RO

4
1
Peak

0:
35:
36:
36:
37:
37:
38:
38:
38:
38:

00
51
10
46
03
41
00
21
44
49
0.
RO
RO
RO

RO
RO
RO
RO
RO
RO
.52
.03
m V.«.<»* .
0
1,321
1,821
UM.s*n
76-1.02
1
1
0
1
3
1
1
0
3
0
.14
.50
.39
.00
.44
.27
.89
.22
.00
.70
0
0
0
1
0
0
1
0
0
0
.67
.13
.13
n /
U /
.26
.30
.32
.32
.68
.70
.02
.34
.09
.74
                                 923.95
                          0.973-1.027
                              0.000
                      897.18  1.000 13C12-HpCDD 678  IS7
                                                  / Octa-CDD and CDF Follows
                                                   .902-1.098
                                                      0.000
                                                      0.877
                                                      0.884
                                                      0.899
                                                      0.906
                                                      0.921
                                                      0.929
                                                      0.938
                                                      0.947
                                                      0.949
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 12:29 01/11/98
                                                                             G
                                                38

-------
 Page No.
 01/11/98
 Listing of T980167B.dbf
 Matched OC Peaks / Ratio
  / Ret.  Tina
 Compound/
 K_Z	QC.Log Omit Why  ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound.Name..  ID.. Flags.
 442-444
DC
DC
DC
DC
DC
DC
DC
SN
SM
SN
SN
SM
SM
SM
0
39:06
39:11
40:09
40:48
40:57
41:12
41:48
Peaks
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
1.
0.
1.
56
73
48
33
67
90
07
                                                0.49
                                                1.23
                                                0.68
                                                0.34
                                                1.25
                                                1.20
                                                0.51
                                                0.00
                                                         0.956
                                                         0.958
                                                         0.982
                                                         0.998
                                                         1.001
                                                         1.007 OCDF
                                                         1.022
                                                      AM
 OCDD
 458-460
 458-460
                 DC  ML
                 DC  SM
                               0.76-1.02
 0:00 RO
40:54 RO
41:10
Peak
                                  1.08
                                  0.66
                                  0.89
0.23
7.28
0.70
7.28
3.43
                                                                             0.902-1.098
              5.20
0.000
1.000 OCDD
1.007
                                         AN
 13C12-OCDD
 470-472
 470-472
                DC  ML
                DC  WH
                               0.76-1.02
0:00
40:54
41:23
Peak
RO

RO

1
0
1

.08
.89
,74


2,

2,
0,
615.
7,
615,
.23
.72
.45
.72
                                                                             0.997-1.005
                                                         1,232.09
                                                                       1.383.63
                                                         0.000
                                                         1.000  13C12-OCDD
                                                         1.012
                                                                                                      IS8
 Column Description	  "Why Code Description	  QC Log Desc.
 H_Z   -Nominal  Ion Mass(es)
 ..RT. -Retention Time (mm:ss)
 Rat.l -Ratio  of M/M+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel.RT-Relative Retention Time
     End of Report ***
        WL-Below Retention Time Window
        WH-Above Retention Time Window
        SN-Below Signal  to Noise Level
        
-------
File:T980167 #1 + 809 Acq:7-JAN-98 03:23:33 XI+  Voltage SIS 70T Ifoiaei449
303.9016 F:2 BSUB(256,30, -3.0) PKD(9,5,5, 0. OS\,1796.0,1.00\,r,T)  SzpiNDBSUS
TRIANGLE LABS  TeJCt:TLH44376 CLEAN-UP BLANK                HKT.  HUE -   03:26
1001
           23:00             34:00              35:00             36s00
Flle:T980167  tl-809 Acq:7-JAN-98 03t33i33 EH-  Voltage  SIX  70T Noiae:332
305.3987 r:3  BSUB(256,30, -3.0) PKD(9,5,S,0.05\,132a.Or1.00\,F,T)  Exp:NDB5US
TRIANGLE LASS  Taxt:TLH44376 CLEAN-UP BLANK                IJKT.  TIME -   03:36
1001            I                                          A4.24E4
                                                                                    37:00
  80.

  50J

  40J
                I       A3.06E4
      A1.70E4   \A3.33E4  ll A3.15E4
           33:00             34:00             35:00             36:00
rile:T9a0167  tll-809 Acq:7-JAS-9a 03:33:33 EH- Voltage SIS  70T lToiaei384
315.9419 T:2  BSUB(356,30,-3.0) PKD(9,S,5, 0. OS\,1136. 0,1. 00\,F,T) Ezp:XDB5US
TRIANGLE LABS TeJCt:TLI»44376 CLEAN-UP BLANK                HTJ. TIME  -   03:26
100*            I                                         A9.52E6

 aol
 40:
 sol
                                                                                   37: 00
  0-
           23:00             34:00             35:00             36:00
Tile:T980167 #l|-S05 Acq: 7-JAN-98 03:23:33 EI+ Voltage SIS  70T No±ae:331
317.9389 T:2 BSUB(2S6, 30, -3. 0) PKD(9,5,5, 0. 05%, 1284. 0,1.00*,F, T) Exp:NDB5US
TRIANGLE LABS  Text:TLI»44376 CLEAN-UP BLANK                IWJ. TIKE  *    03:26
1001                                                      A1.32E7

 aol

 60:

 40l

 30.
                                                                                   27:00
           23:00             34:00             35:00             36:00
File:T980167  fl-809 Acq: 7-JAN-98 03:33:33 EI+ Voltage SIS  70T
330.9792 F:2  Eip:NDB5US
TRIANGLE LABS  Text:TLI#44376 CLEAN-OP BLANK                INJ. TIME  -
100J»         23:i06   23:32  23:56 24:17 24:37_   35: OZ     ^{j1-,
 aoj            i

 60:

 40:

 20:

  ol
                                                                                   27:00
                                                                            03:26
                                                                             26:41 37: 01
                                                                           ^v	N/~~
           23:00             34:00             35:00
F±le:T980167 H-809 Acq:7-JAN-98 03:23:33 £1+ Voltage SIS 70T
375.8364 F:2 Exp:NDB5US
                                                                 26:00
                                                                                   27:00
TRIANGLE LABS
1001
 80:

 60:

 40:

 20.
  ol
Text:TLI«44376 CLEAN-UP BLANK
            23 54
                                                             INJ. TIME -   03:26
      33:43
               33:14



           33:00
                             34:00
                                               35:00
                                                                 36:00
                                                                                   37:00
                                                                                              3S1

-------
ril«:T980167 tl-809 Acq:7-JAN-98 03i33i33 EH- Voltage SIS 701 tfoisa: 79
319.8965  Ts2 BSUB(256,30, -3.0) PKD(7,S,3,0.05\r316.0,1.00\,r,T) SxptSOBSOS
TRIANGLE  LASS  Text:TLIt44376 CLOUT-UP BLANK                XK7. TIMX -   03,26
 1004
        24:00                  25s00                  26:00
fLla:T980167 #1-809 Acq:7-JKN-98 03:33:33  EH- Voltage SIB 70T Soiae:89
321.8936 T:2 3SUB(256, JO, -3.0) fJO>(7,5,3t 0.05%,356.0,1.00\,r,T) EzpiSDBSUS
TRIANGLE LASS  Text:TLH44376 CLXAX-UP BLANK                ISJ. TIMS -   03:26
1001 A1.54E4
                                                          A4.33E3        A4.50E3
                                                                  Al.08E4
        24:00                  25:00                  26:00                 27:00
riletT980167  tl-809 Acq:7-JAS-98 03:23:33 EI+  Voltage SIS 70T Soiae:1967
331.9368 T:2  BSU3(256,30,-3.0) PKD(7,5,3, 0. 05%, 7868.0,1, 00\,r,T) Xxp-.SDBSUS
TRIANGLE LABS Text:TLIt44376 CLEAN-UP BLANK                JK7. TIME -   03:26
1004                                                    Al  27E7
  80.
  50:
  40:
  20.
  ol
                                                             8.62E6
        24:00                 25:00                  26:00                  27:00
rile:T980167 #1-809 Ac
-------
rila:T980167  tlr809 Acqt7-JJOr-98 03i23i33 XX*  Voltage SIS 70T Soim»:189
339.8597 Ti2  BSUB(256, 30, -3. 0) PKD(7,5,3,0.051,756.0,1.00\,r,T) ExpiNDBSOS
TSIANSLE LASS  Text:TLH44376 CLXAK-OP BLASK                IXJ. TIMS •   03t26
1001
                SS'iOO                  29,00                  30:00
rila:T980167  #1-303 Acq:7-J7OT-98 03i23:33 XI+  Voltage SIS 701 Noiao:235
341.8567 r:2  SSOB(256, 30, -3. 0) PKD( 7,5, 3, 0. 05\,940. 0,1. 00\,f,T)  KxpsHDBSUS
TSIANSLE LASS  Text:TLlt44376 CLEAN-UP BLANK                JK7. TIME '   03s26
1001                         A2.21E4
                                                                                    311 00
                28:00                  29:00                  30:00
Tile:T980167  fl-^809  Acq:7-JAN-98 03:23:33 E1+ Voltage  SIR 70T Noiae:107
351.9000 T:2  BSOB(2S6,30, -3. 0) PKD(7,5,3, 0. 05\,428. 0,1. 00\,T,T)  EzpiNDBSUS
TRIANGLE LABS  Text:TLI#44376 CLEAN-OP BLANK                 HTJ.  TIME "   03:26
100*            '                                 Al 44E7

 30.

 sol

 401

 201

  Oj
                                                                                    31:00
                28s00                  29:00                  30:00
TilesT980167  tl-809  Acq: 7-JAN-98 03:23:33 EI+ Voltage  SIS  70T Noiae:114
353.3970 T:2  SSUB(2S6,30, -3. 0) PKD(7, S,3, 0. 05\,456. 0,1. 00\,f, T)  Exp:NDBSUS
TXIANSLE LASS  Text:TLI#44376 CLEAN-UP BLANK                 INJ~. TIMS -   03:26
10 04                                            Al  02E7

 80:

 60:

 40.

 20.
                                                                                    31: 00
                28:00                  29:00                 30:00
Tile:T980167  91-809  Acq:7-JAN-98 03:23:33 EI+ Voltage SIS  70T
330.9792 T:2  Elp:NDB5VS
TSIANSLE LABS  Text:TLI»44376 CLEAN-OP BLANK                JK7. TIME -   03:26
            27:50  28^09   __  28:37       29:J}7_      29:37   29:JS8      30:24 3Q-.41
                                  -                      -
1002

 SO.

 60:

 40:

 20.

  0:
                                                                                    31:00
                                                                                             31:25
                28:00                  29:00                 30:00
rile:T980167  tl-809  Acq:7-JXH-98 03:23:33 EI+ Voltage SIS  70T
409.7974 T:2  ExptVDBSUS
TSIANSLE LASS  Text:TLIf44376 CLEAN-OP BLANK                IXJ. TIME -   03:26
1001            '
                                                                                    31: 00
 80.

 60:

 40:

 20:

  o:
                                                  29:29
                                                                         30:31
X.O.OEO
     Time
                                                                                                      .1.1E4

                                                                                                      .8.6E3

                                                                                                      .6.4E3

                                                                                                      4.3E3

                                                                                                      2.1E3

                                                                                                     .O.OEO
                                                                                                         Tiae



                                                                                                      4.1E6

                                                                                                      3.3E6

                                                                                                      2.5E6

                                                                                                      1. 6E6

                                                                                                      8.2ES

                                                                                                      O.OEO
                                                                                                         Tiae
                                                                                                     _3.OE6

                                                                                                     .2.4E6

                                                                                                      .1. 8E6

                                                                                                      1.2E6

                                                                                                      6.1E5
                                                                                                      .O.OEO
                                                                                                         Time
                28:00
                                       29:00
                                                             30:00
                                                                                    31100
 .1. 6E7

 .1.3E7

 .9. 8E6

 .6.6E6

 .3.3E6

 .O.OEO
    Time



 .4.2E3

 .3.4E3

 2.5E3

 1. 7E3

 .8.4X2

 O.OEO
    Tiae
                                                                                               393

-------
riJ.e:Tyaoi67  tl-SOS Acqs7-JHf-9S OJ:23:JJ JtT*  Voltage SIS JOT Hoj.ao-.HI
355.8546 F:2  BSUB(256,30,-3.0> FXD(7,5,3,0.05\,348.0r1.06\rT,T)  SxpiHDBSUS
TRIANGLE LABS  Text:TLIt44376 CLXAH-OP BLANK                XW. TTMX -   03:36
lOOi                         A2.69E4
                                                                                                 .O.OEO
  28:36  28:48 29:00 29:12  29:24 29':36  29:48 30:00  30:12 30:24 30:36  30:48 31:00  31:12 31:24    Time
Tile:T980167  tl-809 Acqt 7-JJOT-98 03:23:33 EI+ Voltage SIX  701 Noise189
357.8516 r:2  BSUB(256,30,-3.0)  PlO>(7,5,3,0.05\,356.0,1.00\,r,X) Xxp:NDB5US
TRIANGLE LABS Text:TLI»44376 CLEAN-UP BLANK                UKT. TTMX -   03:26
1001   ,                                                                                          _J.OJM
  80.
  60.
  40.
 20.
            A2.22E4
                                        , -, ,
                                                                 1SK4
                                                                               A5.OOE3
                                                                                    A-
                                                                                                 .2.4E4
                                                                                                 LI . 8X4
                                                                                                 .1.2X4
                                                                                                 .6.0E3
    Tim.
  28:36  28':48 29': 00 29': 12  29': 24 29:36  29': 4 8 30:00  30:12 30:24 30':36  30:48 31:00  3l':12 31:24
rile:T980167  tl-809 Acq:7-JJUf-98 03:23:33 EI+ Voltage SIR  70T Ko±ae:84
367.8949 T:2  BSUB(256, 30, -3. 0)  fXD(7, 5, 3, 0. 05%, 336 . 0,1. 00\,f, T) Exp:NDB5OS
TRIANGLE LABS Teit:TLI#44376 CLEAN-UP BLANK                JK7. TIME '  03:26
100S                                                         A9.03E6                            ..2.7E6
 SO.

 50.

 40.

 20.
                                                                   9.19ES
'.2.1E6

'.1. 6E6

.1.1E6

.5.3ES
                                                                                                  O.OEO
  28:36  28:48  29:00 29:12  29:24 29:36  29:48 30:00 30:12  30:24 30:36  30:48  31:00 31:12  31:24    Time
r±le:T980167 tl-809 Acq: 7-JAN-98 03:23:33 EI+ Voltage SIR  70T Noiae: 69
369.8919 T:2 BSUB(256,30, -3. 0) PKD(7, 5,3, O.OS\,276.0,1.00*,r,T) Exp:NDB5OS
TRIANGLE LABS  Text:TLI#44376 CLEAN-UP BLANK                UKT. TIME -  03:26
100A                                                         A6.22E6                            -1.9E6
 80.

 60.

 40.

 20.

  0.
.1.5E6

_1.1X6

'.7.5E5

'.3.7X5

 O.OEO
  28:36  28:48 29:00 29:12  29:24 29:36  29:48 30:00 30:12  30:24 30:36 30:48  31:00 31:12  31:24
rlle:T980167  tl-809 Acq:7-JAJT-98 03:23:33 XI+ Voltage SIR 70T
330.9792 T:2 Exp:NDB5US
TRIANGLE LABS  Tejct:TLIt44376  CLEAN-OP BLANX                HOT. TIKE -   03:26
                                                                                                     Time
100]
80.
60.
40.
20.
0
\ 29:07 29:37
^Ny-v/i>^/«.....--..^__y-.^'>. . - . .. ^f^^J^f, -




29:58 30:12 30:24 30:3530: 49 31:04 31:15





                                                                                                 1. 6E7

                                                                                                 .1.3X7

                                                                                                .9.8X6

                                                                                                .6.6X6

                                                                                                .3.3X6

                                                                                                 0.0X0
                                                                                                    Time
                                                                                                 394

-------
rile:T980167 tl-396 Aeq:7-JJUr-98 03:23:33 SI+ Voltage SIS 70T Koiae:259
373.3208 F:3 BSOB(256,30, -3. 0)  PXD(7,5,3,0.05\,1036.0,1.00\rF,T) ExptNDBSUS
TRIANGLE LASS  ,Text:TLIt44376 CLZJUT-OP BLASX                Xicr. TIME -   03:26
1001
               A3.59E3
      A5.69E3\\ '   I    A9SS.46
   31:48 32:00 32:12 32:24 32:36  32:48 33:00 33,12 33:24 33:36 33:48  34:00 34:12 34:24 34:36  34:48
rU.e:T980167 tl-396 Acq:7-JAX-98  03:23:33 EH- Voltage SIS 701 Soiae:137
375.8178 T:3 BSUB(256,30, -3. 0)  PXJJ(7,5,3, 0. OS\,548.0,1. 00\,r,T) Exp:NVB5US
TRIANGLE LASS  Text:TLIt44376 CLEAN-UP BLANK                JKT.  TIME -   03:26
100]

  80.
                                                                                                      O.OEO
                                                                                                         Time
   31:48 32:00 32:12 32:24 32:36  32:48 33:00 33:12 33:24 33:36 33:48 34:00  34:12 34:24 34:36 34:48
File:T980167 tl-396 Acq:7-JMT-98  03:23:33 EH- Voltage SIS 70T Hoiae:S19
383.8639 T:3 BSUS(256,30, -3. 0) PKD(7,5,3, 0. OS\,2076. 0,1.00\,r,T)  Exp:SDB5US
TBIANGLZ LABS  Text-.TLIt44376 CLEAS-UP BLANK                XKJ.  TIKE -   03:26
1004                                  A7.03E6         A7.36E6
 80:

 ffOJ

 401

 201

  0.
                                                                              A6.30E6
                                              2.2E6

                                              1. 8E6

                                              1. 3E6
   31:48 32:00 32:12 32:24 32:36  32:48 33:00 33:12 33:24 33:36 33:48.34:00  34:12 34:24 34:36 34:48
rile:T9801S7 fl-396 Acq: 7-JZN-98  03:23:33 EI+ Voltage SIS 70T Woiae;390
385.8610 F:3 BSUS(256, 30, -3. 0) PKD(7, 5,3, 0.051,1560.0,1.00\,f,T)  Exp-.NDBSOS
TRIANGLE LASS  Text:TLI#44376 CLEAlf-OP BLANK                INJ-.  TIME -   03:26
1004           '                       A1.39E7         A1.43E7
                                                                                                       SE5

                                                                                                       4E5

                                                                                                       OEO
                                                                                                        Time
 80:

 50J

 40:

 201

  o:
                                                                              A1.22E7
                                                       I  V,
   31:48 32:00 32:12 32:24 32:36  32:48 33:00 33:12 33:24 33:36 33:48 34:00  34:12 34:24 34:36 34:48
File:T9B0167 tl-396 Acq: 7-JAN-98  03:23:33 EH- Voltage SIS 70T
392.9760 F:3 Exp:NDB5US
TRIANGLE LASS  Text:TLIi44376 CLEAN-UP BLANK                INJ.  TIME -   03:26
 80.
 50:
 40:
 201
  o.
               32:13    32:29 32:40 32:52
                                                 33:17
                                                           33:38  33:52
   31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12  34:24 34:36 34:48
rile:T980167 H-396 Ac
-------
flJ.asTyaoJ.67 il-jyo Acq:7-J7Ql-98 OJ:23:JJ SI+  Voltage SIM /OX
389.8156 ri3 3303(356,30, -3.0) PKD(7,5, 3,0.051,320.0,1.00\,r,T) KrpiBDBSUS
TRIANGLE LASS  Text:TZH44376 CLEAN-UP BLANK                ZK7. TOO '   03:26
1001
  80.

  60.

  40.

  20.

   0.
   A1.34E4
 7.4X3

'.5.9X3

.4.4X3

  .9X3

.1.5X3
        32:24   32:36    32,48    33:00   33,12    33,24   33,36   33:48   34,00
r±le:T980167 tl-396 Acq:7-JJOf-98 03:23:33 XI+ Voltage SIX 70T BaieetlSO
391.8127  T,3 BSUB(256,30,-3.0)  PXS(7,5,3, 0. 05%, 760.0,1.00\,T,T)  XzptSDBSUS
TRIANGLE  LABS  Tert:TLH44376  CLEAN-UP BLANK                 UKT.  TIME -   03,26
JOOi                           A7.98E3
34:12   34:24
 0.0X0
    Time
                                                    A6.22X3
                                                        A4.72X3
                                                            I A4.36E3
        32:24   32:36   32:48    33:00   33:12   33,24    33:36   33': 48   34': 00
rile:T980167  tl-396 Acq:7-JAN-9S 03:23:33 XI* Voltage SIS  70T Noiae:527
401.8558 T:3  BSUB(256, 30, -3. 0)  PKD( 7,5, 3, 0. OS \,2108. 0,1. 00\,f,T) Exp:XDB5US
TRIANGLE LABS  Text:TLH44376 CLEAN-UP BLANK                ZKT. TIME '    03:26
34i12    34:24
1001
  80.
 50.
 40.
 20.
                                                                         A1.2BE7
                                                            Al. 03E7
        32:24   32:36   32:48    33:00    33,12   33:24    33:36    33:48   34:00
f±le:T980167  tl-396 Acq:7-JAN-98 03:23:33 EI+. Voltage SIR  70T «oiae:149
403.8529 T:3  BSUB(2S6, 30, -3. 0) PKD( 7, 5, 3, 0 . OS \,596. 0,1. 00\,T, T) Exp:BDBSas
TRIANGLE LABS  Text:TLII44376 CLEAN-UP BLANK                INJ. TIME -   03:26
34:12   34:24
100*
 80.
 60.
 40.
 20.
                                                                         A1.04E7
                                                           A8.39E6
        32,24   32:36   32:48   33,00    33:12   33:24   33:36    33:48    34:00    34:12   34:24
rile,T980167  tl-396 Acq:7-JAN-98  03:23:33 XH- Voltage SIS 70T
392.9760 r,3  Exp:JO>B5US
TRIANGLE LABS  Text:TLIt44376 CLEAN-UP BLANK                INJ. TIME -   03:26
100*        32;29   33,40   32:5232:59  33:09  33^17         33:38    33:52 34:01  34-^11 34:20
 80.

 eo:

 40.

 20:

  0.
. 3.4E6

.2.7E6

.2.0E6

.1. 4E6

.6.8ES

.O.OEO
   Tine



2.8E6

2.3E6

1. 7E6

1. 1E6

5.6E5

O.OEO
   Tine
        32:24   32i36   32:48   33:00    33:12   33:24   33:36   33':48  ' '34\6o  ' '34*, 12   34:24
               .7.5X6

               .6.0E6

               .4.5X6

               .3.0E6

               .1.5X6

               .0.0X0
                  time
                                                                                                 396

-------
rila:T980167 tH-562 Acq:7-JKS-9»  03:23:33 XI+ Voltage SIX  70T ftoiae:73
407.7813  T:4 BSUB(256,30,-3.0) PKD(7,S,3,0.05\,292.0,1.00\,T,T) Srp:lO)B5US
TSIANSLE  LASS  TextiTLI»44376 CLEAN-UP BLABS                IJKT. TIME -   03:36
100$
                                                                     A7.02E3
                      A3.39E3
                A3. 73S3  1 AS. 10S3
         36:00  j 36:12    36t24   36:36    36:48   37:00    37:12   37:24   37-36
lrila:T980167 tl+562 Acq:7-JZN-98 03:23:33 EI+ Voltage SIS  70T SOiae-57
409.7789 Ti4 BSUB(256,30,-3.0) PXD( 7,5, 3, 0. OS\,238.0, 1.00\,T,T) Exp,NDB5US
TSIANSLE LABS  Text.tTLIt44376 OJMX-UP  BLANK                UKT. TIKE -   03:26
1001           i           Al. 4.3X4

  aol
  40

  201
                                                                                     37:48   38:00
         '36:00 ''7361:12  ' ' 36\24 '  '36:36  '  36:48 '  3?': 00  ' '37:12 '  '37:24
\T±le:T980167 fl-562 Acq: 7-JAN-98 03:23:33 EI+ Voltage SIS 70T Noise:297
417.8253 T:4 BSUB(256,30, -3.0) PKD(7,5,3, 0. 05\,1188. 0,1. 00\,r,T) Exp:NDB5US
TSIANSLE LABS Text:TLH44376 CLEAN-UP .BLANK                INJT. TIME •>    03:26
       AS.34E6   j
                                                                            37:36   ' 17148 '  38: 60'
  90J
  20

   0.
         36':00   \36':12    36:24   36:36    36:48   37:00    37:12   37':24
\Tile:T9a0167 tl-562 Acq: 7-JAN-9B 03:23:33 EI+ Voltage SIS 70T Jfoiae:139
419.8220  T:4 BSUB(256, 30,-3 .0 ) PXD( 7, 5, 3, 0 . 05%, 555. 0, 1. 00\,f, T) Exp:HDB5US
TRIANGLE  LABS  TfJCt:TLI»44376 CXZAW-07 fliAWT                ZJW. TIME -   03:26
                                                                            37:36   37':48
38:00
1001

  80:
  201

   OJ
       A1.22E7
         36':00 '  '36:12"  36:24   36:36   '36': 48   37': 00   ' 37': 12  '37:24 '  J7.-J5   '37:48
rile:T980167  #1-562 Acq:7-JAN-93 03:23:33 EI+ Voltage SIS 70T
430.9729 f:4  Ezp:NDB5US
TSIANSLE LABS  TeXt:TLI»44376 CLEAN-UP BLANK                 INJ.  TIME "
               36:0936jJ.6     .     36jJ7         36^53^  37:11
                                                                                             38:00
                                                                            03:26
  80J

  50:

  401

  201

   0.
         36': 00   36': 12    36:24   36:36    36:48   37:00   37:12
file:T980167 tl-562 Acq:7-JRN-98 03:23:33 EI+ Voltage SIS 70T
479.7165  F:4 ExpiHDBSUS
TSIANSLE  LABS  Text:TLIt44376 CLEAN-UP BLANK                OKT. TIME -
                                                                   37:24    37':36   37:48    38:00
                                                                            03:26
 4.4X3

 3.5E3

 2.6E3

,1. 7E3

 8.7E2

.O.OEO
    Time



.1. 3E6

.1.1E6

.7.9E5

.5. 3E5

.2.6ES

.O.OEO
    Timel



.3.1E6

2.SE6

.1.9E6

1.2E6

6.2ES

O.OEO
    T±jne\



5.3E6

4.2E6

3.2E6

2.1E6

1.1X6

O.OEO
    Tine
                                                                                                      397

-------
riJ.a:Tyau±07 tl-56J Acqi 7-JJUf-yo 03t23t33 SI+  Voltaga 3IR 70T NoiaattiJ
433.7766 T,4 BSUB(256,30, -3.0) PKD(7,5,3r0.05\,24a.O,1.00\,r,T)  Kxp,NDB5US
TSIANSLE LABS  TfXt,TLXf44376 CLEAN-UP BLANK                HET. TIMS •   03i26
1001
  00.
      36:12' 36(:1S' 36':24 36t30  36i36 36i42 36:48  36:54 37:00 37:06' 37,12' J7s 18' 37i24 ' J7j30'
rile:T980167 tl-562 Acq:7-JKS-98 03:23,33 XX+ Voltage  SIS  70T SoiattSO
425.7737 Tt4 BSU3(256,30,-3.0) ?KD(7,5,3,0.05\,200.0,1.00\,T,T) SzptSOBSUS
TRIANGLE LASS  Isit.tTLIt4.4376 CLEAN-OP BLANK                XK7. TTMT -   03s26
1001                                                         A5.23E3
  80.

  60.

  401

  20.
A4.04S3
                                                                             Al. 65X3
      36:12 36:18  36:24 36:30 36:36  36:42 36:48 36:54  37:00 37:06 37:12  37:18 37:24 37:30
rila:T980167 tl-562 Acq:7-JAN-9S 03:23:33 EI+ Voltage SIX 70T Noiee:163
437.8140 T:4 BSUB(256, 30, -3. 0)  PKD<7, 5,3,0.05\,652.0,1.00\,T,T) Exp:NDB5US
TRIANGLE LABS  Text:TLI*44376 CLEAN-UP BLANK                INJ. TIME -   03:26
100S                                                       A3.?7E6

 80.

 60.

 40.

 20.
      36:12 36:18  36:24 36t30 36>36  36:42 36:48 36:54  37:00  37:06 37:12 37:18  37:24 37:30
r±letT980167 tl-562 Acq:7-JAN-98 03:23:33 21+ Voltage SIS 70T
430.9729 r:4 ExpiNDBSUS
TRIANGLE LABS  TaxtiTLIt44376 CLEAN-UP BLANK                XK7. TIME -   03:26
                   36,24^36231  36^37^ _    36t4a	36^8^^      JTrll          37:2*

 80.

 60.

 40.

 20.
      36:12 36:18  36:24 36:30  36:36 36:42 36:48  36:54  37:00 37:06  37:12  37:18 37:24  37:30
rile:T980167  tl-562 Ac
-------
\r£le:T98dl67 *l-5i
2 Acq:7-J3UT-98 03:23:33 XI+ Voltage SIX JOT Noi*9>8l
441.7428 r:4 3SUB(256,30, -3 .0) PKD(7, 5,3, 0 .OS\r 324.0,1.
TXIANSLX LABS Teit:TLI«44376 CLEAN-UP BLANK
100J
901
aol
701
601
sol
401
301
201
101






i

































00\,f,I) SxptNOBSUS
ZKT. TIME -
















03:26








A 7 11S3









II AS.68E3
AS. 57X3 M.69S3 "'I5*3 A6.40X3 AS.S3E3 IJ A2
^^u.«^»VJL «U.»_ jAA ^jJl /\W^(JLAJA^)kA^AMAHNyJw^^^
'36:00 J7:00
3 a': 00
39:00
40:00
41 : 00
_J.ir4








.39E3
JfjUWL
.2.8X4
.2.5E4
.2.2E4
.1 . 8X4
.1.5X4
.1.2X4
.9.2E3
.6.2X3
.3.1E3
42: 00 Time
r±la:T980167 U-,562 Acq: 7-JXN-9S 03:23:33 XI+ Voltage SIR 70T Soi.ae-.69
443.7399 T:4 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 05\,276. 0,1.
TRIANGLE LABS Text:TLI#44376 CLEAN-UP BLANK
1003
901
801
701
601
sol
401
301
:
201
10J
01


I
;
1
1
1
1
1

/LX^AAA/tflA.
































00\,r,T) Ezp-.NDBSUS
nu. TIME -
















03:26
















r2.3E4







A2.62E3
A6'\A%3.44E3 A3.70E3 A7.35E3
kM>^Mi^fl\^JfY^j^f^
36\00 37.' 00 JflioO

\1E A1'tiE4
	 AA\JUWAjl^>JA^UA^J^
J

40:00

41:00
.2.1E4
.1 . 8E4
Ll . 6E4
.1 . 4E4
.1.2E4
.9.2E3
.S.9E3

.4.6E3
.2.3E3
O.OEQ
42:00 Time
rlle:T980167 #1-562 Acq: 7-JAN-98 03:23:33 EH- Voltage SIX 70T
430.9729 T:4 Exp:XDB5US
TRIANGLE LABS Text:TLI#44376 CLEAN-UP BLANK
1001
901
aol
701
601
501
401
301
201
101
01
UK7. TIME -
03:26


35:22 36:37 37:11 37:50 38:35 39:06 39:34 40:31 41:11 41-43
,/v'vW^/^A>/^vy^^Al^^
1
i
















'36\00 J7.-00









3 a': 00



























39\00









40:00



















4lioO









5.3E6
14.8E6
14.2X6
13 . 7E6
.3.2E6
.2.6E6
.2.1E6
Ll . 6E6
"-1.1E6
-.5.3E5
O.OEO
42:00 Time
Tile:T980167 tl-562 Acq:7-JAN-98 03:23:33 EI+ Voltage SIX 70T
513.6775 T:4 Exp:SDBSUS
TRIANGLE LABS Text:TLI»44376 CLEAN-UP BLANK
1001
901
'.
ao.

701

601
'.
50-

40.

301
201
101
01
ISJ. TIME -
03:26

36 : 05
\
\
\



































40

37:45

1

i

i
J5»50
35:33 | ]
*yv-AwV*M/JH





36:47 1
IJjIy^
36':00 37\00






.ijki
3 a', oo






]



J8


A*V



•54








39:42 «'«

Jjfj/JU
J9:00


LL>JKJUIL
40:00


41

•42



41 : 34



41:07
AiUL
41:00

7.0E3

t47










.6.3E3

.5.6E3

.4.9E3

.4.2E3

.3.5E3

.2.8E3

i :2.1X3
[ j|1-«J
ir(Jni.7.ox2
f o otto
42:00 Time

-------
 fHa:T980167 iJL-562 Acq:7-jAJt-yo  OJtJJiJj Elf Voltage sisTut
 457.7377 Ts4 BSUB(256,30,-3.0) PKD(7,S,3,0.05\,26Q.O,l.OQ\,T,T) CtptBDBSOS
 TBIASGLX LASS  Text:TLIt44376 CLEAN-UP BLANK                ZK7. 2TMT •   03:26
 100\                A3.43X4
       40:48         40:54         41:00         41:06         41:12        41:18
rlla:T980167 fl-562 Acq:7-JJUf-98  03:23:33 XI+ Voltage SIS 70T Soiaes59
459.7348 T:4 BSUB(256,30, -3.0) PKO(7,5,3, 0.05\, 236.0,1. 00\,r,T) XxptBDBSUS
TSIANSLX LASS  Text:ZLIt44376 CLEAN-UP BLANK                XK7. TIKE -   03:26
                      A5.20E4
                                                                                           41:24
                                                                                                   7.3X3

                                                                                                   .5.9X3

                                                                                                   .4.4X3

                                                                                                  .2.9X3

                                                                                                  '.1.5X3

                                                                                                   0.0X0
                                                                                                      Tim
       40':48         40:34         41': 00          41:06        41:12         41:18
ttle:T980167 tl-562 Acq: 7-JAN-9B 03:23:33  XI+ Voltage SIX 701 Soiaet 63
469.7779 f:4 BSUB(256,30,-3.0) PJOJf 7,5, 3, 0. 05\,252. 0,1. 00\,T, T) Xxp:HDB5US
TRIANGLE LASS  Text:TLIt44376 CLEAN-OP SLANT                XK7. TIKE -   03:26
10 01                 A1.23E7
                                                                                          41:24
  0.
                                                                            41:18
      40': 48         40:54         41:00         41:06         41:12
Tile:T980167  tl-562 Acq:7-JZN-98 03:23:33 EI+  Voltage  SIS  70T No±ae:61
471.7750 T:4  BSUS( 256, 30, -3 . 0)  PXD( 7, 5, 3, 0. 05\r244 . 0, 1. 00\,T, T)  Exp:NDB5US
TRIANGLE LASS  Text:TLH44376 CLEAN-UP BLANK                 XWJ.  TIKE -   03:26
1001                A1.3BE7
                                                                                          41:24
  2.0E6

 '.1. 6E6

 '.1.2E6

 '.8.1ES

 '.4.1E5

 '.O.OEO
    Tiae



 2.4E6

 .1. 9E6

 '.1. 4E6

 .9.5X5

^4.7X5
      40:48         40:54         41:00         41:06         41:12
rlle:T980167  tl-562 Acq:7-JZN-98 03:23:33 EI+ Voltage SIS  70T
430.9729 f:4  Exp:NDBSUS
TRIANGLE LABS Text:TLH44376 CLEAN-UP BLANK                XK7.  TIKE
100*       40:50                 40:59                       41jLll
                                                                            41:18
                                                                            03:26
                                                                                          41:24
 80.

 60.

 40:

 20:

  o:
                                                                                                 -5.2X6

                                                                                                 '.4.2X6

                                                                                                 .3. 1X6

                                                                                                 '.2.1X6

                                                                                                 '.I. 0X6

                                                                                                  0.0X0
      40:48
                    40:54
                                  41:00
                                                41s OS
                                                              41:12
                                                                            41:18
                                                                                          41124
                                                                                                    40 C

-------
Rtf ,  aass   2S.38S5    Pe-k too
Heiht  3,12 wits Sai  290   a
Systsa file nae
Data  file nae
Resolution
Group maber
lonizatlon aode
                     IMS88161
                            2
                       VOLTRGE
Ref ,  lasses  22,^,  416,3768
fl   293
B   384
C   386
0   316
E   318
F   329
G   322
H   328
I   331
           J   331
           K   332
           L   334
           R   348
           H   342
           0   352
           P   354
           9   3%
           *   358
S   383
T   378
If   376
V   418
Chanel   I  33,3732.   Pesk top
Height  2,94 vdts  Span   88ppa
                                                       4-H

-------
CALIBRATION
       DATA
            Triangle Laboratories, Inc.
       801 Capitola Drive      P.O. Box 13485
       Durham, NC 27713-4411    Research Triangle Park, NC 27709-3485
       919-544-5729        Fax # 919-544-5491
                           P.O
                           J f*.

-------
                       i  TRIANGLE LABORATORIES OP RTF,  INC.
                       !Initial Calibration Stannary  for  PF22206
                                              Date: 02/20/96
   Analysis Date	: 02/20/95
   Instrument	: P
                          Method	: C2NF
                          GC Column...: DB-22S
   Analytes
   2378-TCDF
   TOTAL TCDF
   2378-TCDD
   TOTAL TCDD

   Other Standards
   37C1-TCDD
 RF     SO   %RSD
1.040 0.109   10%
1.040 0.109   10%
0.992 0.101   10%
0.992 0.101   10%
|RF     SD
1.014 0.043
%RSD
  5%
   Internal Standards  !RF     SD   %RSD
   13C12-2373-TCDF    1.388 0.062    4%
   13C12-2378-TCDD    1.067 0.036    3%

   Recovery Standards  |RF     SD   %RSD
   13C12-1234-TC3D    1.000 0.000    0%
                       i
   *** End of Report: ***
          RT   RT/LO
        21:32  14:31

        20:12  16:11
  RT   RT/LO
20:12  18:11

  RT   RT/LO
21:31  20:31
20:11  18:11

  RT   RT/LO
20:27
RT/HI  Ratiol  Ratio2   N
25:31   0.767          10
        0.767          10
24:11   0.782          10
        0.782          10

RT/HI  Ratiol  Ratio2   N
22:11                  10

RT/HI  Ratiol  Ratio2   N
22:31   0.753          10
22:11   0.786          10

RT/HI  Ratiol  Ratio2   N
        0.794          10
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (379) 544-5729 • Fax: (919) 544-5491
                                                              Printed: 23:10 02/20/96

-------
                      Initial Calibration Sumnary Cor XF24087
  Analysis Data	: 04/08/97
  Instrument. ...'...: X
                          Method	:  C2NF
                          GC Column...:  DB-22S
  Analytes
  2378-TCDF
  TOTAL TCTF
  2378-TCDD
  TOTAL TCTD

  Other Standards
  37C1-TCDD

  Internal Standards
  13C12-2378-TCDF
  13C12-2378-TO3D
 RF     SD   %RSD
0.967 0.044    5%
0.967 0.044    5%
1.095 0.097    9%
1.095 0.097    9%
 RF     SD
1.018 0.047
%RSD
  5%
 RF     SD   %RSD
1.392 0.071    5%
1.105 0.037    3%
          RT   RT/LO RT/HI  Ratiol  Ratio2
        21:49  14:49 25:49    0.779
                              0.779
        20:37  16:36 24:36    0.793
                              0.793
  RT
20:37
RT/LO  RT/HI
18:36  22:36
          RT   RT/LO
        21:49  20:49
        20:36  18:36
Ratiol  Ratio2
             RT/HI
             22:49
             22:36
              Ratiol
               0.787
               0.783
        Ratio2
 N
10
10
10
10

 N
10

. N
10
10
  Recovery Standards  RF     SD
  13C12-1234-TCDD    1.000 0.000

  •«• End of Report **»
             %RSD      RT   RT/LO  RT/HI  Ratiol  Ratio2   N
               0%    20:50                0.796          10
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                               Printed: 02:46 04/09/97
                                                              434

-------
                             TRIANGLE LABORATORIES,  INC.
                        Initial Calibration Summary for TP5D177
Date: 12/18/97
                                                   Method.
Instrument .... . :
Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HxCDD
123678-HXCDD
I 23789-HxCDD
^.'OTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HXCDF 234
13C12-HxCDF 789
13C12-HXCDD 478
13C12-HpCDF 789
Internal Standards
13C12-2378-TCDF ',
13C12-2378-TCDD I
13C12-PeCDF 123 ;

T
/ •"- • /

RF
2.
2.
0.
1.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
0.
1.
0.
0.
1.
1.
1.
1.
1.
1.
1.
537
024
705
353
860
444
370
370
363
363
061
060
060
293
293
154
298
043
974
117
883
000
992
959
473
122
297
035
035
440
113
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
1.
0.
0.
0.
0.
0.
0.
006
993
921
954
755
812
780
0
0
0
0
0
0
0
RF
1.
1.
1.

545
248
280

0
0
0


SD
.000
.000
.000
.000
.000
.000
.153
.153
.211
.211
.104
.095
.099
.111
.111
.133
.136
.130
.149
.149
.085
.121
.147
.117
.121
.080
.100
.100
.100
.091
.094
SD
.009
.041
.032
.039
.033
.047
.043
SD
.058
.044
.109


%RSD
0%
0%
0%
0%
0%
0%
11%
11%
15%
15%
10%
9%
9%
9%
9%
12%
14%
12%
15%
13%
10%
12%
15%
12%
8%
7%
8%
10%
10%
6%
8%
%RSD
1%
4%
3%
4%
4%
6%
6%
%RSD
4%
4%
9%
Page

RT
10:19
11:03
14:10
15:02
20:01
20:07
26:06

26:46

29:53
30:33

30:52

33 : 15
33:21
33:52
34:41

33:59
34:03
34:24

36:24
38:03

37:30

41:41
41:27
RT
26:46
30:32
33:14
33:51
34:40
33:58
38:03
RT
26:05
26:45
29:52
1

RT/LO
5:05
6:45
13:05
13:45
17:05
18:45
22:05

22:45

25:52


26:51

29:21.




30:03



32:24


33:30

37:26
37:26
RT/LO
24:45
27:52




34:24
RT/LO
25:05
24:45
25:52


RT/HI
20:05
20:45
21:05
21:45
24:05
24:45
30:05

30:45

33:52
•

34:51

37:21




38:03



40:24


41:30

45:26
45:26
RT/HI
28:45
31:52
*



40:24
RT/HI
27:05
28:45
33:52



Ratiol Ratio2
2
3
5
1
0
1
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
.821
.317
.319
.415
.920
.118
.799
.799
.768
.768
.492
.501
.496
.596
.596
.270
.269
.288
.279
.276
.250
.231
.241
.240
.055
.054
.055
.031
.031
.908
.845
Ratiol Ratio2

1
0
0
0
1
0

.478
.506
.507
.508
.217
.430
Ratiol Ratio2
0.733
0.789
1.458



N
1
1
1
1
1
1
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
N
6
6
6
6
6
6
6
N
6
6
6

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (319} 544-5729 -'Fax: (919) 544-5491
     Printed: 12:47 12/18/97
        405

-------
                            TRIANGLE LABORATORIES,  INC.              Date: 12/18/97
                       Initial Calibration  Summary for TF5D177
  13C12-PeCDD 123     0.710 0.064    9%     30:51  26:51  34:51   1.472            6
  13C12-HXCDF 678     1.412 0.046    3%     33:21  29:21  37:21   0.506            6
  13C12-HXCDD 678     0.998 0.052    5%     34:03  33:03   35:03   1.213            6
  13C12-HpCDF 678     0.891 0.043    5%     36:24  34:24   40:24   0.434            6
  13C12-HpCDD 678     0.722 0.026    4%     37:30  36:30   38:30   1.030            6
  13C12-OCDD         0.490 0.019    4%     41:26  39:26   43:26   0.859            6

  Recovery Standards  RF     SD   %RSD      RT    RT/LO   RT/HI  Ratiol  Ratio2    N
  13C12-1234-TCDD     1.000 0.000    0%     26:35                 0.817            6
  13C12-HXCDD 789     1.000 0.000    0%     34:23                 1.203            6

  *** End  of Report ***
                                   Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713                                    Printed: 12:47 12/18/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                             406

-------
 Date:  01/06/98
  TRIANGLE LABORATORIES,  INC.
Continuing Calibration  for  T98014S
«\uax/aj.a uaue. . . . ; WA/ w/ jv»
Operator1 	 : BRI
Tn i t- P
all KT>S +••!*-.
•LI2J-U Ivfii.k ^M.kQ u^.w
ICal Date
Analyte Summary
Name

Total

Total

Total

Total

Total

Total


MCDF

MCDD

DCDF

DCDD

TriCDF

TriCDD

2378-TCDF

TOTAL

TCDF
2378-TCDD

TOTAL
12378-

23478-
• '"
12373-

TOTAL
123478

123678
234678
123789
TOTAL

TCDD
PeCOF

PeCDF
PeCDF
PeCDD

PeCDD
-HxCDF

-HxCDF
-HxCDF
-HxCDF
HxCDF
123478-HxCDD

123678

-HxCDD
n.
pp«;ni77

. . ^C -IW A 1 t
• 12/17/97
i
i
I
RF Ratio

0

0

0

0

0

0

1

1
1

1
0

0
0
1

1
1

1
1
0
1
0

0
i ls2
.000

.000
I
.000
I
. 000

.000
I
I
.000
I
.155 0.83

.155 0.83
I
1
.161 0.86
1
. I'ei 0.86
.985 1.49
i
.914 1.50
i
.9^9 1.50
1
.2'86 1.58
1
.2!86 1.58
1
.071 1.28

.1190 1.27
.001 1.21
1
.866 1.32
.032 1.27
I
.789 1.28

.885 1.22
t
Instrument.
Std • Cone

RT RT Rel. RT
. : T




. . . • "5.00


ICal
RF


Delta
RF

%D


Lo/High k
5:
19
6:
20
12
20
13
21
16
23
18
24
22
27

23
27

27
31


28
31

31
34




32
34

41
:41
21
:21
:41 .
:41
:21
:21
:41
:41
:21
:21
:33 25:41 1.0000
:34

:4S 26:22 1.0006
:32

:27 29:31 1.0006
:21
30:12 1.0237

:38 30:31 1.0005
:11

:48 32:54 0.9975
:36
33:00 1.0005
33:30 1.0157
34:19 1.0404

:17 33:37 0.9975
:12
33:42 1.0000
2

2

0

1

0

0

1

1
1

1
1

1
1
1

1
1

1
1
0
1
0

1
.537

.024

.705

.353

.860

.444

.370

.370
.363

.363
.061

.060
.060
.293

.293
.154

.298
.043
.974
.117
.883

.000
-2.

-2.

-0.

-1.

-0.

-0.

-0.

-0.
-0.

-0.
-0.

-0.
-0.
-0.

-0.
-0.

-0.
-0.
-0.
-0.
-0.

-0.
537

024

705

353

860

444

215

215
202

202
076

146
111
007

007
083

108
042
108
085
094

115
100.

100.

100.

100.

100.

100.

-15.

-15.
-14.

-14 .
-7.

-13.
-10.
-0.

-0.
-7.

-8.
-4.
-11.
-7.
-10.

-11.
0% |^
X,v\*
0% V^

0%

0%

0%

0%

7%

7%
3%

3%
2%

8%
5%
5%

5%
2%

4%
1%
1%
6%
7%

5*
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                           Printed: 13JD3.01/06/98
                                                                 •4-uv

-------
Date: 01/06/98
TRIANGLE LABORATORIES,
Continuing Calibration
123789 -HxCDD
TOTAL HxCDO
1234678-HpCDF

1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD

TOTAL HpCDD
OCDF

OCDD

0.902
0.859
1.310

0.991
1.151
0.919

0.919
1.233

1.014

1.19
1.23
1.13

1.20
1.16
1.03

1,03
0.87

0.85



35:
37:


36:
37:

36:
44:
36:
44:


54
53


11
19

56
56
56
56
34:

36:

37:

37:


41:

40:

02

01

38

05


10

56

INC.



for T980148
1

1

1

1


1

1

.0099

.0009

.0459

.0000


.0057

.0000

Other Standard Summary
Name

37C1-TCDD

13C12-PeCDF 234

13C12-HXCDF 478
13C12-HXCDF 234
13C12-HXCDF 789
13C12-HxCDD 478
13C12-HpCDF 789

Internal Standard
Name

13C12-2378-TCDF

13C12-2378-TCDD .

13C12-PeCDF 123

13C12-PeCDD 123

13C12-HxCDF 678

13C12-HXCDD 678

RF

0.941

0.912

0.951
0 . 895
0.691
0.788
0.766

Ratio
162


1.47

0.52
0.51
0.51
1.05
0.43

RT

RT
Rel. RT
0.992
0.959
1.473

1.122
1.297
1.035

1.035
1.440

1.113

ICal
RF
-0.090
-0.100
-0.163

-0.131
-0.146
-0.116

-0.116
-0.207

-0.099

Delta
RF
-9.1%
-10.5%
-11.1%

-11.6%
-11.3%
-11.2%

-11.2%
-14.4%

-8.9%


%D
Lo/High
24:
28:
. 25:
33:




33:
39:
21
21
30
30




59
59
26:

30:

32:
33:
34:
33:
37:

22

11

54
30
18
36
37

1

1

0
1
1
0
1

.0006

.0232

.9975
.0157
.0399
.9970
.0454

Summary
RF

1.290

1.098

1.047

0.499

1.256

1.059

Ratio
1&2
0.70

0.81

1.49

1.41

0.52

1.24

RT

RT
Rel . RT
1.0.06

0.993

0.921
0.954
0.755
0.812
0.780

ICal
RF
-0.065

-0.081

0.030
-0.059
-0.064
-0.024
-0.014

Delta
RF
-6.4%

-8.2%

3.2%
-6.1%
-8.5%
-2.9%
-1.8%


%D
Lo/High
24:
26:
24:
28:
25:
33:
26:
34:
28:
36:
32:
34:
41
41
21
21
30
30
30
30
59
59
42
42
25:

26:

29:

30:

32:

33:

41

21

30

30

59

42

1

1

1

1

1

1

.0000

.0000

.0000

.0000

.0000

.0000

1.545

1.248

1.280

0.710

1.412

0.998

-0.255

-0.150

-0.233

-0.211

-0.156

0.061

-16.5%

-12.0%

-18.2%

-29.7%

-11.0%

6.1%

                                Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:03 01/06/98
    408

-------
 Date: 01/06/98       I    TRIANGLE  LABORATORIES,  INC.
                      j  Continuing  Calibration for T980148
 13C12-HpCDF  678   0.821  0.43    33:59  35:59 1.0000    0.891 -0.070  -7.9%
                                  39:59
 13C12-HpCDD  678   0.7^49  1.01    36:05  37:05 1.0000    0.722  0.027   3.7%
                                  ^38:05
    :12-OCDD        0.5J29  0.90    40:51  40:56 1.0000    0.490  0.039   8.0%
                                  41:11
                      I

 Recovery Standard Summary                              ICal   Delta
 Name               RP   Ratio      RT     RT   Rel.  RT  RF      RF    %D
                          162    Lo/High
 13C12-1234-TCDD   1.0^00  0.80            26:10 0.9930    1.000  0.000   0.0%

 13C12-HXCDD  789   l.o'oO  1.15            34:01 1.0094    1.000  0.000   0.0%


                       QC Front End Check:      1.9657
                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713                                         Printed: 13:03 01/06/98
Phone: (9t9f 544^5729 • Fax- (919) 544-5491                                                     AC\Q
                      I                                                                      ^J w* \^/

-------
 Date:  01/07/98
  TRIANGLE LABORATORIES,  INC.
Continuing Calibration for T980160
rkua^jo^^a uctoc. .
Operator 	
Tnit Calihr-nl-ini
^ i*^ u v»a^ xiJx a (• xvji
ICal Date 	
Analyte Summary
Name .

Total MCDF

Total MCDD

Total DCDF

Total DCDD

Total TriCDF

Total TriCDD

2378-TCDF

TOTAL TCDF
2378-TCDD

TOTAL TCDD
12378 -PeCDF

23478-PeCDF
TOTAL PeCDF
12378-PeCDD

TOTAL PeCDD
123478-HxCDF

123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478 -HxCDD

123678-HxCDD

. . . \
• (
D. '
• • .
]

0

0

0

0

0

0

1

1
1

1
0

0
0
1

1
1

1
0
0
1
0

0

J J,/ UO/ JV
2RV
pr»eni77
ir ju± i i
12/17/97
RF Ratio
1&2
.000

.000

.000

.000

.000

.000

.354 0.84

.354 0.84
.159 0.75

.159 0.75
.931 1.42

.953 1.53
.942 1.47
.229 1.62

.229 1.62
.033 1.31

.217 1.26
.951 1.28
.858 1.32
.015 1.29
.765 1.30

.885 1.26

Instrumei
Std Cone

RT RT Rel. RT
to/High
5:40
19:40
6:21
20:21
12:40
20:40
13:21
21:21
16:40
23:40
18:21
24:21
22:29 25:41 1.0006
27:31

23:44 26:21 1.0000
27:29

27:23 29:30 1.0000
31:18
30:11 1.0232

28:35 30:31 1.0005
31:08

31:46 32:53 0.9970
34:33
32:59 1.0000
33:30 1.0157
34:19 1.0404

32:15 33:36 0.9980
34:09
33:42 1.0010
Page 1
it.


1C
R

2

1

0

1

0

0

1

1
1

1
1

i
"i
i

i
i

i
i
0
1
0

1

. : T


al
P

.537

.024

.705

.353

.860

.444

.370

.370
.363

.363
.061

.060
.060
.293

.293
.154

.298
.043
.974
.117
.883

.000

» w »


De

-2

-2

-0

-1

-0

-0

-0

-0
-0

-0
-0

-0
-o
-0

-0
-0

-0
-0
-0
-0
-0

-0


5.(

Ita
RF

.537

.024

.705

.353

.860

.444

.016

.016
.204

.204
.130

.107
.118
.064

.064
.121

.081
.092
.116
.102
.118

.115


)0

%D

100.

100.

100.

100.

100.

100.

-1.

-1.
-14.

-14.
-12.

-10.
-11.
-5.

-5.
-10.

-6.
-8.
-11.
-9.
-13.

-11.






0%

0%

0%

0%

0%

0%

2%

2%
9%

9%
2%

1%
1%
0%

0%
5%

2%
8%
9%
1%
3%

5%

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                           Printeo: 00:13 01/07/98
                                                                  410

-------
Date: 01/07/98

123789-HxCDD
TOTAL HxCDD
^ 4678-HpCDF
w
1234789-HpCDF .
TOTAL HpCDF
1234678-HpCDD

TOTAL HpCDD
OCDF

OCDD



TRIANGLE LABORATORIES,
Continuing Calibration
0.868
I
0.3
1.3
39
57
1
1.030
1.198
0.960

0.9'60
1.283

0.9

Other Standard Summar
Name

.37C1-TCDD

13C12-PeCDF 234

13C12-HxCDF 478
13C12-HXCDF 234
13C12-HXCDF 789
«:i2-HxCDD 478
-12-HpCDF 789

Internal Standard
Name

13C12-2378-TCDF

13C12-2378-TCDD

13C12-PeCDF 123

13C12-PeCDD 123

13C12-HxCDF 678

13C12-HXCDD 678


RF

0.9

1.0

0.9

82

y


35

07

66
0.884
0.695
0.766
i
1
0.845


1.20
1.25
1.07

1.18
1.11
0.93

0.93
0.88

0.34


Ratio
1&2


1.49

0.51
0.51
0.52
1.19
0.42



35:50
37:49


36:08
37:15

36:54
44:54
36:54
44:54

RT
Lo/High
24:21
28:21
25:30
33:30




33:59
39:59
34:01

35:59

37:37

37:05


41:10

40:56


RT

26:21

30:10

32:53
33:29
34:17
33:35
37:36

INC.




for T980160
1.

1.

1.

1.


1.

1.


0104

0000

0454

0004


0065

0008


Rel . RT

1.

1.

0.
1.
1.
0.
1.


0000

0226

9970
0152
0394
9975
0449

Summary
RF
1
1.294
|
1.176

1.218
i
0.631
I
I
1.305
j
1.058


Ratio
1S2
0.73

0.77

1.47

1.50

0.51

1.16


RT
Lo/High
24:40
26:40
24:21
28:21
25:30
33:30
26:30
34:30
28:59
36:59
32:40
34:40
Page
RT

25:40

26:21

29:30

30:30

32:59

33:40

2
Rel. RT

1.

1.

1.

1.

1.

1.



0000

0000

0000

0000

0000

0000


0.992
0.959
1.473

1.122
1.297
1.035

1.035
1.440

1.113

ICal
RF

1.006

0.993

0.921
0.954
0.755
0.812
0.780

ICal
RF

1.545

1.248

1.280

0 . 710

1.412

0.998


-0.124
-0.120
-0.106

-0.092
-0.099
-0.075

-0.075
-0.157

-0.131

Delta
RF

-0.071

0.014

0.045
-0.070
-0.060
-0.046
0.065

Delta
RF

-0.251

-0.072

-0.062

-0.079

-0.107

0.060


-12
-12
-7

-8
-7
-7

-7
-10

-11


%D

-7

1

4
-7
-8
-5
8


%D

-16

-5

-4

-11

•'-7

6


.5%
.5%
.2%

.2%
.64
.2%

.2%
.9%

.3%




.1%

.4%

.9%
.4%
.0%
.7%
.3%




.2%

.8%

.8%

.1%

.6%

.0%


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 -JFax: (919) 544-5491
Printed: 00:13 01/07/98

       411

-------
  Date: 01/07/98

  13C12-HpCDF 678   0.834  0.44

  13C12-HpCDD 678   0.794  1.03

  13C12-OCDD        0.589  0.91
  TRIANGLE LABORATORIES, INC.
Continuing Calibration for T980160
          33:59  35:59 1.0000   0.891 -0.057  -6.4%
          39:59
          36:04  37:04 1.0000   0.722  0.072  10.0%
          38:04
          40:46  40:54 1.0000   0.490  0.099  20.1%
          41:06
  Recovery Standard Summary
  Name           .    RF   Ratio
           RT
             ICal   Delta
RT   Rel. RT  RF      RF
                           1&2     Lo/High
  13C12-1234-TCDD   1.000  0.80

  13C12-HXCDD 789   1.000  1.20
                                                                       %D
                 26:10 0.9930   1.000  0.000   0.0%

                 34:01 1.0104   1.000  0.000   0.0%
                        QC Front  End  Check:
                       1.4346
                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                           Printed:
                                                       1/07/98

-------
 Date: 01/07/98
       TRIANGLE LABORATORIES,  INC.
     Continuing Calibration for X980080
 Analysis Data	:  01/07/98
 Operator	:  BJG
 Init Calibration.:  XF24087
  fal Data	:  04/08/97
    lysis Time	:  11:23
 Analyte Summary
 Name

 2378-TCDF

 TOTAL TCDF

 2378-TCDD

 TOTAL TCDD
 RF   Ratio
RT
    Method	:  C2NF
    Instrument..:  X
    Std.Conc	:        5.00

    GC Column...:  DB-225

             ICal    Delta
RT   Rel. RT  RF      RF    %D
       162    Lo/High
1.113  0.77    16:57  21:28 1.0008   0.967  0.146  15.1%
               23:29
1.113  0.77                          0.967  0.146  15.1%

1.176  0.82    17:46  20:13 1.0017   1.095  0.081   7.4%
               22:51
1.176  0.82                          1.095  0.081   7.4%
 Other Standard Summary                                ICal   Delta
 Name     •          RF   Ratio     RT     RT   Rel. RT  RF      RF    %D
                          162    Lo/High
 37C1-TCDD         1.030          18:11  20:12 1.0008   1.018  0.012   1.1%
                                  22:11

 Internal Standard Summary                             ICal   Delta
 Name               RF   Ratio     RT     RT   Rel. RT  RF      RF    %D
                          142    Lo/High
 13C12-2373-TCDF   1.374  0.30    20:27  21:27 1.0000   1.392 -0.018  -1.3%
                                  22:27
     .2-2378-TCDD   1.106  0.78    18:11  20:11 1.0000   1.105  0.001   0.0%
                                  22 : 11

 Recovery Standard Summary                             ICal   Delta
 Name               RF   Ratio     RT     RT   Rel. RT  RF      RF    %D
                          162    Lo/High
 13C12-1234-TCDD   1.000  0.80           20:27 1.0132   1.000  0.000   0.0%
                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 13:46 01/07/98
                                                                         413

-------
 Data:  01/10/98        TRIANGLE LABORATORIES OP RTP, DC,
                        Continuing Calibration ror P980164
 Analysis Date	:  01/10/98                  Method	: C2NF
             	:  WK
Operator	
Init Calibration.: PF22206
ICal Date	: 02/20/96
Analysis Tine....: 10:22
Instrument..:  P
Std.Conc	:        5.00

CC Column...:  DB-225
 Analyte Summary
 Name

 2378-TCDF

 TOTAL TCDF

 2378-TOJD

 TOTAL TCDD
                                                       ICal   Delta
                   RP   Ratio     RT      RT   Rel.  RT   RP      RF     %D
                         142    Lo/High
                  1.017  0.80    18:15  23:02  1.0007    1.040 -0.023   -2.2%
                                 25:21
                  1.017  0.80                           1.040 -0.023   -2.2%

                  1.062  0.82    19:05  21:36  1.0015    0.992  0.070   7.1%
                                 24:34
                  1.062  0.82                           0.992  0.070   7.1%
 Other Standard Summary                            .    ICal   Delta
 Name               RP   Ratio     RT     RT   Rel. RT  RF      RF    %D
                          Ii2    Lo/High
 37C1-TCDD         0.966          19:34  21:35 1.0008   1.014 -0.048  -4.8%
                                  23:34

 Internal Standard Summary                             ICal   Delta
 Name               RF   Ratio     RT     RT   Rel. RT  RF      RF    %D
                          142    Lo/High
 13C12-2378-TCDF   1.509  0.75    22:01  23:01 1.0000   1.383  0.121   8.7%
                                  24:01
 13C12-2378-TCDD   1.222  0.32    19:34  21:34 1.0000   1.067  0.155  14.5%
                                  23 : 34

 Recovery Standard Summary                             ICal   Delta
 Name               RF   Ratio     RT     RT   Rel. RT  RF      RF    %D
                          142    Lo/High
 13C12-1234-TCDD   1.000  0.80           21:51 1.0131   1.000  0.000   0.0%
                                 Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                    Printeo^-U:*t 01/10/98

-------
                              Appendix C

                                  HCI
                       Laboratory Analysis Data
cah/A:\APPX-CVR.WP6

-------
                             CASE NARRATIVE
                    Analysis of Samples for the Presence of

                                  Chloride by

                              Ion Chromatography
                                 METHOD 26
          Date:
January 27,1998
          Client ID:
Eastern Research Group
          TLI Project Number :    44369
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
                                              Triangle Laboratories, Inc.
                                    801 Capitola Drive            P.O. Box 13485
                                    Durham, NC 27713-4411        Research Triangle Park, NC 27709-3485
                                    919-544-5729                Fax #919-544-5491

-------
Triangle Laboratories, Inc.                                     January 27,1998
Case Narrative                                                            44369

Objective: Analysis of thirty-nine impinger samples for chloride by Method 26
Method:  Thirty-nine impinger samples were received by Triangle Laboratories, Inc. on
December 17,1997 without coolant in good condition.  The samples were stored at 4°C prior to
analysis. This report pertains only to the analysis of two of the samples for chloride. The samples
were analyzed for chloride content by ion chromatography using Method 26 with suppressed
conductivity detection. The results reported relate only to the items tested.

The analysis conditions are listed below:

Instrument:  Dionex DX300 Ion Chromatograph with a PED-II Conductivity Detector
Eluent flow: 1.5 mL/min. (1.8 mM sodium carbonate/1.7mM sodium bicarbonate)
Suppressor:  Anion self-regenerating suppressor-1
Sample Loop: 25 uL
Detection: Conductivity - suppressed ion
Data Recording: Dionex AI450 software
Report:
Enclosed with the case narrative are copies of the client paperwork, sample log-in sheets, and log
book pages.  The data are reported as quantitation reports and chromatograms. A seven point
calibration curve was performed ranging from 0.5 ppm to 100 ppm both before and after sample
analysis.  Reported concentrations are mean values determined from duplicate analyses.
Results:

Due to instrument problems, a six point calibration curve from 1 ppm to 100 ppm was used for
the chlorine analyses. Because of this, chlorine samples whose concentrations were calculated as
beingbelow 1 ppm were reported as lesrilian 1 ppm.  Samples in wliich chloride was not
detected were reported as detection limits.

Due to the levels of chloride present, samples CAA-15, CAA-19, CAA-35, CAA-51, CAA-55,
and CAA-63 were analyzed at dilutions.

Samples CAA-03 and CAA-04 were used to analyze matrix spikes and matrix spike duplicates.
The matrix spike and matrix spike duplicate sample recoveries were within QC criteria for the
chloride spikes.  The high recoveries of the chlorine spikes may be a matrix effect.  Its cause is
being investigated.

-------
Triangle Laboratories, Inc.                                     January 27,1998
Case Narrative                                                          44369

The data in this package has been judged to be valid according to the guidelines of Method 26
except as noted above.  Should you have any questions, please feel free to contact our Project
Scientist, Amy Boehm, at (919)  544-5729, Ext. 268.

For Triangle Laboratories , Inc.,

Report Preparation:                            Quality Control:

          P. l
Sarah A. Hubbard
Report Preparation Chemist                     Report Preparation Chemist
The total number of pages in this data package
ta   116.

-------
                     TRIANGLE LABORATORIES, INC.

                 LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVtRONMENTAL

American Association for Laboratory  Accreditation. Accredidation pending.   Certificate
Number 0226-01.  Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Soi/Haz Waste,  Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of Environmental Management  Expires December 31,  1998.
Laboratory I.D. # 40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation. Expires December 21,  1998.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department of Health Services. Expires May 26,1998. Certificate 3AZQ423.
Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,  1998.
Pulp/paper, soil, water, and Hazardous Waste  for Dioxin/Furan; AOX/TOX, Volatiles,  Semi-
voiatiles, and Metals.

State of  California,  Department of Health Services.  Expires August 31, 1999. Certificate
#1922, Selected Metals in  Waste Water Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut Department of  Health Services.   Expires September 30,   1999.
Registration #PH-0117.  Dioxin in drinking water.

Delaware Health and Social Services. Expires December 31,1998. Certificate #NC 140. Dioxin
in drinking water.

Florida Department of Health and Rehabilitative Services. Expires June 30, 1998. Dioxin in
DW. Drinking Water ID HRS# 87424.  Metals,  Extractable Organics (GOMS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS# E87411.
Revised 1/20/98 RM                                 Triangle Laboratories, Inc.
y:certific\certlist.mem               *w Capitota Drive           P.O. BOX 134S5
                                   Durham, NC 27713-4411        Research Triangle Park, NC 277094485
                                   919-544-5729               Fax f 919-544-5491

-------
 Hawaii Department of Health.  Expires March 1,  1998. Dioxin in drinking water. "Accepted"
 status for regulatory purposes .

 Idaho Department of Health and Welfare.  Expires December 31, 1998. Dioxin in drinking
 water.

 State of Kansas, Department  of Health  and Environment  Expires January 31, 1998.
 Environmental Anaiyses/Ncn portable Water and Solid and Hazardous Waste.  Method 1613 for
 drinking water. ID #*s - Drinking water and/or pollution control - E-215. Solid or Hazardous Waste -
 E-1209.

 Commonwealth of Kentucky, Department for Environmental Protection. Expires
 December 31, 1S98. 103*90060. Dioxin in drinking water.

 Maryland  Department of Health and Mental  Hygiene.   Expires September 30, 1998.
 Certification #235.  Drinking water by Method  1613A.

 State of Michigan, Department of Public  Health.  Expires  June 3, 1998. Drinking water by
 Method 1613.

 Mississippi State Department of Health. No expiration date.  Dioxin in drinking water.

 Montana Department of Health and  Environmental Services.  Expires December 31, 1998.
 Dioxin in drinking water.

 State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
 1998. ID #67851. BNAs and Volatiles.  Dioxin  in drinking water.

 State of New Mexico, Environment Department  Recertification pending. Dioxin in drinking
 water.

 New  York State Department of Health.   Expires  April 1, 1998. ID #11026. Environmental
 Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.

 State of North Carolina, Department of Environment Health  and Natural Resources Expires
 August 31,1999. Certificate # 37751.  Dioxin in drinking water.

 State of North  Carolina, Department of  Environment, Health,  and Natural  Resources,
 Division of EnvironmentaJ  Management  Expires December 31, 2000.  Certificate  # 485.
 Metals, pesticides & PCBs, semi-volatiles and voiatles; TCLP.

 North Dakota  State  Department of  Health  and Consolidated  Laboratories.   Expires
 December 31,1998. Certificate # R-076. Effective October 4,1993. Dioxin in drinking water.
Revised 1/20/98 RM
y:certific\certiist.mem

-------
 Oklahoma Department of Environmental Quality. Expires August 31,1998. Laboratory #9612.
 Dioxin by 1613A, 8290 and 8280.

 State of South Carolina, Department of Health and Environmental Control.  Expires
 April 1,1998. Certificate number #99040001 (drinking water). Expires August 31,1999. Certificate
 number  #99040002  (other parameters).  Dioxin/Furans,  BNA, Volatiles, and RGBs/pesticides
 under Clean Water Act 2,3,7,8-TCDD for Drinking Water,  and Organic extractables for Solid and
 Hazardous Waste.

 State of Tennessee. Department of Environment and Conservation.  Expires
 February 5,1999. ID #02992,  Method 1613 Drinking water only.

 U.S. Department of Agriculture Soil Permit  Expires September 30, 2001. Permit No. S-3790.
 Under the authority of the  Federal Plant Pest  Act, permission is granted to receive foreign soil
 samples for use in laboratory analysis.

 U.S. Army Corps of Engineers.  Recertification Pending.  Validated to perform methods
 8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects, and
 assorted projects for the USAGE North Pacific Division Laboratory.

 U.S. EPA Region V.  Expires November 14,1999.  Dioxin in drinking water.

 U.S. EPA Region VIII, for the  State of  Wyoming.  Expires November 12, 1998. Dioxin  in
 drinking water.

 State of Utah, Department  of  Health.   Extended by  State to  March 31,  1998.  Certificate
 Number  E-166. Certification for the following  parameters:  Semi-Volatiles and Volatiles under
 RCRA; Volatiles under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin
 by Method 1613; Metals including Mercury and Microwave Digestion.

 Commonwealth of Virginia, Department of General Services, Division of Consolidated
 Laboratory Services. Expires June 30,1998. ID # 00341. Dioxin in drinking water.

 State of Washington, Department of Ecology. Expires September 11,1998. Lab Accreditation
 Number  C067.  Scope of Accreditation  applies  to water analyses for Poiychlorinated Dibenzo-p-
 dJoxins  and  Poiychlorinated Dibenzofurans, BNA Extr  (Semivolatfle) Organics and Purgeable
 (Volatile) Organics.

 State of Washington, Department of Health.  Expires April 30, 1998. Dioxin in drinking water.
 Lab I.D. 129
Revood 1/20/98 RM
y;certific\certlist.mem

-------
 State of West Virginia,  Department of Health.  Expires January 31, 1998. Certificate No.
 9923(C). Dioxin in drinking water.
 State of Wisconsin, Department of Natural Resources.  Expires August 31, 1998. Laboratory
 ID Number 999869530.  Certification  for the  following  categories  of Organics: Purgeable,
 Base/Neutrai, Add, PCBs, and Dioxin.  Expires  November 14, 1999. Laboratory ID 999869530.
 Dioxin in drinking water.

 PHARMACEUTICAL

 Drug  Enforcement Agency  (DEA).    Expires  November 30,  1998.  Registration  number
 RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

 N.C. Department of Human Resources.  Expires October 31, 1S9S. Registration number
 NC-PT 0000 0031. North  Carolina controlled substances registration.  Application submitted for
 renewal.

 Food & Drug Administration (FDA) Registration.  Expires June 1998. ID #3 001500 1053481.
 Annual registration of drug  establishment Annual registration of drug establishment.

 OTHER

 Clinical Laboratory Improvement Amendments (CLJA) Registration. Expires May 30, 1999.
 ID  #  34D0705123.   Department  of  Health   &  Human Services,  Health  Care  Financing
 Administration.

 U.S. EPA  Large Quantity  Hazardous Waste Generator.    No expiration date.   EPA ID
 #NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

 North Carolina General License for Radiation Protection.  No. expiration date. License No.
 032-875-OG.  The general license appfies only to radioactive material contained in devices which
 have been manufactured and labeled in accordance with specific requirements.
Rovisad 1/20/98 RM
y:certific\certlist.mem

-------
                                                             Eastern Research Group  COC
Gulp Aluminum Alloys
                                                                                                                                              oo
CHAIN OF CUSTODY , /^ /) /}
/f7//l 1 U U^
RELINQUISHED BY +//VM'L'(,1- I >UvX>U62
RELINQUISHED BY = i

(SAMPLE ID
a*»x-—
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CAA-03 V
CAA-04 y
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i
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CAA-15 '
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-BAAO?

CAA-19/
CAA-20 /
-WWS1
-CAA4*--
CAA-23 r
CAA-24 V/
"CTW^S-
rs^Ste
CAA-27 V
CAA-28 /





DATE =
DATE =
FIELD ID
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120597
120597
120597
120597
120697
120697
120697
120697
120697
120697
120697
120697
120597
120597
120597
120597
120697
120697
120697
120697
120697
120697
120697
120897
120897
120897
120897
M26-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
Al26A-
M26A-
M26A-
r^26A-
y26A-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1 -OUT-
FILTER
FH
IMP1.2
IMP3.4
FJLTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
1
1
1
1
2
2
2
2
3
3
3
3
1
1
1
1
2
2
2
3
3
3
3
1
1
1
1
13-


( T ( V T RECEIVED BY: L/jC£{sbJ%1f#~^ DATE/^^^^T2-
RECEIVEDBY: * *V DATE: ' '


SAMPLE TYPE
METHOD 26A.
METHOD 26A.
METHOD 26A,
METHOD 26A,
METHOD 26A.
METHOD 26A.
METHOD 26A,
METHOD 26A.
METHOD 26A.
METHOD 26A.
METHOD 26A,
METHOD 26A.
METHOD 26A.
METHOD 26A.
METHOD
26A,
METHOD 26A.
METHOD 26A.
METHOD 26A.
METHOD 26A.
METHOD 26A
METHOD 26A
METHOD 26A
METHOD 26A
METHOD 26A
METHOD 26A
METHOD 26A
METHOD 26A
CDBOUT, RUN 1
CDBOUT, RUN 1
CDBOUT. RUN 1
CDBOUT. RUN 1
CDBOUT. RUN 2
CDBOUT. RUN 2
CDBOUT. RUN 2
CDBOUT. RUN 2
CDBOUT, RUN 3
CDBOUT, RUN 3
CDBOUT. RUN 3
CDBOUT. RUN 3
CDBIN, RUN 1
CDBIN, RUN 1
CDBIN, RUN 1
CDBIN. RUN 1
CDBIN. RUN 2
CDBIN, RUN 2
CDBIN, RUN 2
CDBIN. RUN 3
CDBIN. RUN 3
CDBIN. RUN 3
CDBIN. RUN 3
RFI-OUT. RUN 1
RF1-OUT. RUN 1
RFI-OUT. RUN 1
RF1-OUT. RUN 1

PRESERVATIVE | COMMENTS
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2 & H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2 &H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3,4 & H20 RINSE
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE .
IMP 1.2 &H20 RINSE $$¥<. /«/ 2
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2 & H20 RINSE
IMP 3.4 & H20 RINSE

ANALYSIS
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlo
Hydrogen Chloi
Hydrogen Chlo
Hydrogen Chlo
Hydrogen Chlo
Hydrogen Chlo
                                                                                                                                      ( 2
                                                                         Pagel

-------
       Eastern Research Group   COC
                                                                                                      CD
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CAA-32 ^
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CAA-35 •
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CAA-39 V .
CAA-40 I/
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CAA-51 i/
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CAA-63 v
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CAA-75 K
CAA-76 v/

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CAA-
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CAA-
CAA-
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CAA-
CAA-
CAA-
CAA-
CAA-
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,CAA-
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CAA-I
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-

CAA-
CAA-
CAA-
CAA-

W\T3\3I M^6A-
120997 M26A-
120997 M26A-
120997 M26A-
120997 M26A-
121097 M26A-

121097 M26A-
121097 M26A-
121197 M26A-
121197 M26A-
121197 M26A-
121197 M26A-
120897 M26A-
4 onoo? ftjl^CA
1 ZU897 M26A-
120897 M26A-
120897 M26A-
120997 M26A-
120997 M26A-
120997 M26A-
120997 M26A-
121097 M26A-
121097 M26A-
121097 M26A-
121097 M26A-
121197 M26A-
121197 M26A-
121197 M26A-
121197 M26A-
\
120497 (1126A-
120497 M26A-
120497 M26A-
120497 M26A-
i
HH-UUI-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-

RF1-OUT-
RF1-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF1-IN-
DIT4 t U
Rr 1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RFMN-
RF1-IN-
RF1-IN-
RF1-IN-
RFMN-
RF1-IN-
RF2-IN-
RF2-IN-
RF2-IN-
RF2-IN-

RBLK1
RBLK1
RBLK1
RBLK1

MLIbK
FH
IMP1.2
IMP3.4
FILTER
FH

IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FILTER
CLJ
rn
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4

FILTER
Acetone
H2S04
NaOH

i
2
2
2
3
3

3
3
4
4
4
4
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4

1
1
1
1

METHOD 26A. RF1-OUT, RUN 2
METHOD 26A. RF1-OUT, RUN 2
METHOD 26A, RF1-OUT, RUN 2
METHOD 26A, RF1-OUT. RUN 2
METHOD 26A. RF1-OUT, RUN 3
METHOD 26A, RF1-OUT, RUN 3
METHOD 26A. RF1-OUT, RUN 3
METHOD 26A. RF1-OUT. RUN 3
METHOD 26A. RF2-OUT. RUN 4
METHOD 26A. RF2-OUT, RUN 4
METHOD 26A. RF2-OUT. RUN 4
METHOD 26A, RF2-OUT, RUN 4
METHOD 26A. RF1-IN. RUN 1
METHOD 26A. RF1-IN. RUN 1
METHOD 26A. RF1-IN. RUN 1
METHOD 26A. RF1-IN. RUN 1
METHOD 26A, RF1-IN, RUN 2
METHOD 26A, RF1-IN, RUN 2
METHOD 26A. RF1-IN. RUN 2
METHOD 26A. RF1-IN, RUN 2
METHOD 26A. RF1-IN. RUN 3
METHOD 26A, RF1-IN. RUN 3
METHOD 26A. RF1-IN, RUN 3
METHOD 26A, RF1-IN, RUN 3
METHOD 26A, RF2-IN. RUN 4
METHOD 26A, RF2-IN, RUN 4
METHOD 26A. RF2-IN. RUN 4
METHOD 26A, RF2-IN. RUN 4
METHOD 26A. REAGENT BLANK
METHOD 26A. REAGENT BLANK
METHOD 26A. REAGENT BLANK
METHOD 26A. REAGENT BLANK
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2& H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3,4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2& H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2& H20 RINSE
IMP 3,44 H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2& H20 RINSE
IMP 3,4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2& H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
 ACETONE
O.INSulfutic Acid
O.INNaOH
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor

-------
Eastern Research Group  COG
                                                                                           o
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-235
-236
-237
-238
-239
-240
-241
,-242
V-243
-244
-245
CAA-246
CAA-247
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CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120897
120897
120897
120897
120697
120697
120697
120697
121097
121097
121097
121097
120997
120997
120997
120997
120597
120697
120897
120897
120897
120897
120897
120897
120897
120597
120597
120597
120597
120597
120597
120897
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
M26A-
Jfl26A-
M26A-
M26A-
1
RBLK2
RBLK2
RBLK2
RBLK2
FBLKIN
FBLKIN
FBLKIN
FBLKIN
FBLKOUT
FBLKOUT
FBLKOUT
FBLKOUT
FBLKIN
FBLKIN
FBLKIN
FBLKIN
Reagent Blk
Reagent Blk
GBLKOUT
GBLKOUT
GBLKOUT
RBLK2
GBLKIN
GBLKIN
GBLKIN
GBLKIN
GBLKIN
GBLKIN
GBLKOUT
GBLKOUT
GBLKOUT
GBLKOUT
FILTER
Acetone
H2S04
NaOH
FILTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
DIH20
DIH2O
FH •
IMP1.2
IMP3.4
FILTER
FH
IMP1.2
IMP3.4
FH
IMP1.2
IMP3.4
FH
IMP1.2
IMP3.4
FH
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
2
2
2
2
2
2
2
2
2
2
METHOD 26A, REAGENT BLANK
METHOD 26A. REAGENT BLANK
METHOD 26A, REAGENT BLANK
METHOD 26A, REAGENT BLANK
 FIELD BLANK CDBINLET
 FIELD BLANK CDBINLET
 FIELD BLANK CDBINLET
 FIELD BLANK CDBINLET
 FIELD BLANK RFOUTLET
 FIELD BLANK RFOUTLET
 FIELD BLANK RFOUTLET
 FIELD BLANK RFOUTLET
 FIELD BLANK RFINLET
 FIELD BLANK RFINLET
 FIELD BLANK RFINLET
 FIELD BLANK RFINLET
        REAGENT BLANK 1
        REAGENT BLANK 2
 GLASSWARE BLANK RFOUTLET
 GLASSWARE BLANK RFOUTLET
 GLASSWARE BLANK RFOUTLET
        REAGENT BLANK 2
 GLASSWARE BLANK RFINLET
 GLASSWARE BLANK RFINLET
 GLASSWARE BLANK RFINLET
 GLASSWARE BLANK CDBINLET
 GLASSWARE BLANK CDBINLET
 GLASSWARE BLANK CDBINLET
 GLASSWARE BLANK CDBOUTLET
 GLASSWARE BLANK CDBOUTLET
 GLASSWARE BLANK CDBOUTLET
 GLASSWARE BLANK RFOUTLET
FILTER
ACETONE
0.1N Sulfuric Acid
0.1N NaOH
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2 &H20 RINSE
IMP 3,4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP1.2& H20 RINSE
IMP 3,4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2 & H20 RINSE
IMP 3.4 &H20 RINSE
           DIH20
           DIH20
FRONT HALF ACETONE RINSE
IMP 1,2 &H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
FRONT HALF ACETONE RINSE
IMP 1.2 & H20 RINSE
IMP 3,4 & H20 RINSE
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3.4 & H20 RINSE
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3.4 & H20 RINSE
FRONT HALF ACETONE RINSE
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       'Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
                                                                       Hydrogen Chlor
             Page 3

-------
      Eastern Research Group   COC
CAfl-248
CAA-249
I
QAA-250
CAA-251
OAA-252
C\A-253
CAA-
CAA-
1
CAA-
CAA-
CAA-
CAA-
120897
120897

120897
120897
120897
120997
M26A-
M26A-

M26A-
M26A-
M26A-
M26A-
GBLKOUT
GBLKOUT

GBLKIN
GBLKIN
GBLKIN
FILTER
IMP1.2
IMP3.4

FH
IMP1.2
IMP3.4
FILTER
2
2

2
2
2

GLASSWARE BLANK RFOUTLET
GLASSWARE BLANK RFOUTLET
GLASSWARE BLANK RFINLET
GLASSWARE BLANK RFINLET
GLASSWARE BLANK RFINLET
METHOD 26, CDBIN. RUN 2 FILTER
IMP 1.2& 1120 RINSE
IMP 3.4 & H20 RINSE
FRONT HALF ACETONE RINSE
IMP 1,2 & H20 RINSE
IMP 3.4 & H20 RINSE
FILTER
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor
Hydrogen Chlor

-------
                                                                                                                                     U
g Custody Seni^ : Absent Sample Seals: Absent ^^^
| Chain of Custody : Present Container...: Intact
1 Sample Tags : Absent
0 Sample Tag Numbers: Not Listed on Chain of Custody
| SMO Forms : N/A
TLI Project Number 44369 . , j Book
Client: ERG02 - Eastern Research Group j
| 194
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Date Received j 12/17/97 j By ^%L>4/1 ^7^\ '*'**
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U Box NO COOLANT Carrier and Number | CARLILE ' | $2
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                                                             =Form Revised 05/27/1997 -- Page 1 OF 3=

-------

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: N/A


Sample Seals: Absent
Container. . . : Intact
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NO COOLANT

TLI Project Number 44369
Client: ERG02 - Eastern Research Group
Date Received
Carrier and Number
j 12/17/97 j By ^J^tsisi^
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| CARLILE
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                                                              =Form Revised OS/27/
                                                                                       --  Page  2  OF 3=

-------
                                                  =TRIANGLE LABORATORIES, INC.  --
                                                                                         RECORD/CHAIN OF CUSTODY=
II Custody SeaC^^ : Absent Sample Seals: Absent ^•B'
|I Chain of Custody : Present Container...: Intact
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TLI Project Number 44369 Book |P
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194 B
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Date Received | 12/17/97 | By ^^fl^^^^\^~\ P«9«
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1) Receiving Remarks: \
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Archive Remarks:
                                                              =Form Revised  OS/27/1997  --  Page  3 OF  3=

-------
                                                                                                                  PAGE  1 OF 4
         : 443S9
                                                  TRIANGLE LABORATORIES.  INC. (
                                         Sample Preparation Tracking & Management Form

                                                                            Clienc: Eastern Research  Group  (ERG02)
I
I  Method:
|  Solvent/Acids 0 :
Extraction Date:

  Lot:	
ii : I i \Y\
| . | TLI / . 1 Sample (Final | |
[Sample: <5-_,MPLS ID / CLIENT IWat / Vol 1 Volume 1 ,./ / 1
|# crd| / SAMPLE ID | g / ml | ml | |
| | T-,1 Blank III 1
|000 | TLI Blank III 1
I | ^4-52-1 I II 1
|001 | CAA-03 ill 1
1 | 194-52-2 III 1
|002 | CAA-n; III 1
| | 194-52-3 - [ II 1
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1 . 1 194-52-7 III 1
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| | i, 4-52-8 • 'II 1
|008 | . CAA-19 ;. || |
1 1 194-52-9 | || |
|009 | CAA-2< : I 1 1
1 1 194-52-10 III 1
|010 | CAA-23 III I
| | 194-52-11 .11 1
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                                                                                                                            15

-------
                                                                                                                     PAGE 2 OF 4
  Project .  14369
         TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
                                    Client: Eastern Research Group  (ERG02)
                                                                                                                                   I
                                                                     ation
1 Method: f^(f\d\i
| Solvent/Acids 0 :

1 1
1 1 TLI
| Sample | SAMPLE ID.
|tf crd|
| | 194-52-13
|013 |
| | 194-52-14
|014 |
| | 194-52-15
| | 194-52-16
|016 |
| | 1M-52-17
1017 |
| | 194-52-18
|018 |
| | 194-52-19
|019 |
| | 194-52-20
|020 |
| | 194-52-21
|021 |
| | 194-52-22
|.022 |
| | :'r4-52-23
|023 |
| | .--1-52-24
|024 |
| | 194-52-25
|025 |
1
>H Extraction Date: 1/10/51/10
' 1
Lot:

/ | Sample | Final | |
/ CLIENT IWqt / VollVolumel / / 1 / /
/ SAMPLE ID . g / ml | ml [ |
III 1 -
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CAA-3-. : II | /
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|  Comments:
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	 	 REV 07
                                                                                                         REV  07/26/93  (PSTMF 7)--»

-------
                                                                                                                    PAGE 3 OF 4
     ;ect: 44369
                                                   TRIANGLE LABORATORIES, INC.
                                          Sample Preparation Tracking & Management Form
                                                                              Client: Eastern Research Group (ERG02)
  Method:
|  Solvent/Acids (") :
                                                       Sampl
                                     Ex'.raction Date:
|       |    TLI
|Sample|  SAMPLE  ID
|#  crd|
                                         | Sample   |Final  |           |
                           CLIENT        |Wgt / Vol | Volume]	/	/	|
                          SAMPLE ID      ! g  / ml  |  ml   |           |
         U4-52-26  '
1 026
                                 CAA-63
       |  194-52-27
|027
                                 CAA-S4
                                                   I       I
                                                   I       I
                                                                          1.
         194-52-28
1028
                                 CAA-75
                                                   I       I
                                                   I       I
I       |  194-52-29
|029   |
                                 CAA-95  i
I       I
       I  194-52-30
|030
|031
                                  CAA-96  I
                                                   I       I
                                                   I       I
       |  194-52-31
                                  CAA-99  i
I       |  194-52-32
1032   |
                                                   I       I
                                CAA-10!.
         J'4-52-33
|033
                                         I
                                 CAA-103  ;
                                                   I       I
                                                   I       I
I       I  194-52-34
|034   |
                                 CAA-104  |
I       I
I       I

         194-52-35
|035
                                                   I       I
                                 CAA-lji
I       I  194-52-36
1036   |
                                 CAA-23:

         194-52-37
| 037
                                 CAA-2S-;
                                                   I       I
       |  194-52-38
(033
                                  CAA-lc"
                                                                         13
       -.ts,:
                                                                                                        -REV 07/26/93 (PSTMF 7)--«
                                                                                                                               17

-------
PAGE 4 OF 4
1
i
| Project: 44369
1 Met.hod: 0>(a\&(fffr
1 Solvent/Acids 0 :

I.I
I | TLI /
| Sample! SAMPLE ID /
|tt crd| /
| | 194-52-39
|039 |
1 1
II
1 1
1 1
1 1
1 1
1 1
1 1
II
1 1
1 1
1 1
1 1
1 1
1 !
1 !
1 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1
1
1 Comments .- \ t\
\
U)2

TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERG02)
	 . g_£
f?/-lmwt-*tb'L
Extraction Date: / [If I/I It 16 /lU*-'
Lot :
* • ' ""
i i i?jf LEW \$MW\ i
; sample |Final ' ' 'rtic/ni/1 ' '
CLIENT IWct / Voll Volume I / / 1 / / I 'WJW'y-' | / / | / / | / /
SAMPLE ID : g / ml | ml | | | | | |
i ii i q \ */ \ \ \
CAA-76 ! || | 3 | 39 1 1 1
III ! 1 1 1 1
III 1 1 1 1 I
III 1 ! 1 1 1
1 II II 1 1 1
i III II 1 1
ill 1 1 1 1 1
I'll 1 1 1 I.I
III 1 1 1 1 1
. i II II 1 1 '1
III 1 1 1 1 1
11 1 1 1 1 1
III 1 1 1 1
III 1 1 1 1 1
III 1 ! I.I 1
III 1 1 1 1
II 1 1 1 1 1
1 III 1 • 1 1 1
III 1 1 1 1 1
III 1 1 1 1 1
III 1 1 1 1 1
,11 1 1 II 1
III 1 1 1 1 1
1 II II II 1
III 1 I 1 1 1
\,\) (\f\
\\faw
J/w-
	 AA 	 REV m/5
-------
                 TRIANGLE LABORATORIES OF RTF, INC.
                                                     [PS7MF2]
                 PROJECT COMMUNICATION TRACKING FORM
                     TLJ project Number
     Use this form to record ail exchanges of information between production units as
     well as personnel handling tnis project Decisions, corrective actions and
    ^recommendations must also appear on this tracking document
Date  .
         Name
       Comment / Decision / Resolution / Action / Observation
          LDJ
      MS/M.AD  kJcis   trfornwd
                              CM-0&).
                                   IQQ-ppm  C.hknde.
         LKf
                                 -fo/^rtfu-h'cn
                                    3/<) fj'f/utrcn
                                   -fo U c/f"
                 Cind 3ml
/D]
              Ihl,
                           ilih>n
                     f  gf
                        (A
                             ^50/J of
                       o
                          ATTACHMENT I
SOP No. CGN126
         Revision 2.0
                                     28 October 1993
page 3 of 4
                                                                   19

-------
                  DIONEX  SCHEDULE - C:\DX\SCHEDULE\44369HCL.SCH
Inj#
Sample Name
Method
Data File
Vol.
Oil.  Int.Std.
1 STD 0.5 PPM F
2 STD 0.5 PPM F
3 STD 1.0 PPM F
4 STD 1.0 PPM F
5 STD 5.0 PPM F
6 STD 5.^PPM-^P
7 STD 10.0 PPM F
8 STD 10.0 PPM F
9 STD 25.0 PPM F
10 STD 25.0 PPM F
11 STD 50.0 PPM F
12 STD 50.0 PPM F
13 STD 100.0 PPM F
14 STD 100.0 PPM F
15 H2S04 BLANK •
16 H2S04 BLANK
17 QC 20 PPM
18 QC 20 PPM
19 194-52-1
20 194-52-1
21 194-52-3
22 194-52-3
23 194-52-5
24 194-52-5
25 194-52-7
26 194-52-7
27 194-52-8
28 194-52-8
29 194-52-12
30 194-52-12
31 194-52-14
32 194-52-14
33 194-52-16
34 194-52-16
35 194-52-18
36 194-52-18
37 194-52-20
38 194-52-20
39 194-52-22
40 194-52-22
41 194-52-24
42 194-52-24
43 194-52-26
44 194-52-26
45 194-52-28
46 194-52-28
47 194-52-29
48 194-52-29
49 194-52-31
50 194-52-31
51 194-52-33
52 194-52-33
53 194-52-37
54 194-52-37
55 194-52-1 MS
56 194-52-1 MS
57 194-52-1 MSD
58 194-52-1 MSD
. . \CHLORIDE STD005
..\CHLORIDE STD005
..\CHLORIDE STD001
. .\CHLORIDE STD001
..\CHLORIDE STD005
. . \CHLORIDE STD005
..\CHLORIDE STD010
. .\CHLORIDE STD010
. .\CHLORIDE STD025
. . \CHLORIDE . STD025
. .\CHLORIDE STD050
..\CHLORIDE STD050
. . \CHLORIDE STD100
. .\CHLORIDE STD100
..\CHLORIDE H2S04BL
..\CHLORIDE H2S04BL
. .\CHLORIDE QC20PPM
..\CHLORIDE QC20PPM
..\CHLORIDE 1945201
. .\CHLORIDE 1945201
. .\CHLORIDE 1945203
. .\CHLORIDE 1945203
. .\CHLORIDE 1945205
. .\CHLORIDE 1945205
. .\CHLORIDE 1945207
..\CHLORIDE 1945207
. .\CHLORIDE 1945208
. .\CHLORIDE 1945208
. .\CHLORIDE 1945212
. .\CHLORIDE 1945212
. .\CHLORIDE 1945214
. .\CHLORIDE 1945214
. .\CHLORIDE 1945216
. .\CHLORIDE 1945216
. .\CHLORIDE 1945218
..\CHLORIDE 1945218
. .\CHLORIDE 1945220
. .\CHLORIDE 1945220
. .\CHLORIDE 1945222
...\CHLORIDE 1945222
..\CHLORIDE 1945224
. .\CHLORIDE 1945224
..\CHLORIDE 1945226
..\CHLORIDE 1945226
..\CHLORIDE 1945228
..\CHLORIDE 1945228
..\CHLORIDE 1945229
. .\CHLORIDE 1945229
..\CHLORIDE 1945231
..\CHLORIDE 1945231
..\CHLORIDE 1945233
..\CHLORIDE 1945233
..\CHLORIDE 1945237
..\CHLORIDE 1945237
..\CHLORIDE 1945201
..\CHLORIDE 1945201
..\CHLORIDE 1945201
..\CHLORIDE 1945201
1
1
1
1
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i L.
i m
i ^
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
2 1
2 1
2 II
2 m
i i
i i
i i
i i
20 1
20 1
1 1
1 1
20 1
20 1
20 1
20 1
1 1
1 1
20 1
20 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1
i m
1 1
1 OA
2 *-5
2 1*
2 1
2 1

-------
Inj#
Sample Name
Method
Data File
Vol.
Oil.  Int.Stc
59 195-18-1
60 195-18-1
.61 195-18-4
f 195-18-4
195-13-5
195-18-5
65 195-18-7
66 195-18-7
67 195^^-9. .^
68 195-18-9
69 195-18-11
70 195-18-11
71 195-18-4 MS
72 195-13-4 MS
73 195-18-4 MSD
74 195-18-4 MSD
75 195-35-1
76 195-35-1
77 195-35-1 MS
78 195-35-1 MS
79 195-35-1 MSD
80 195-35-1 MSD
81 STD 0.5 PPM B
82 STD 0.5 PPM B
83 STD 1.0 PPM B
84 STD 1.0 PPM B
85 STD 5.0 PPM B
86 STD 5.0 PPM B
«STD 10.0 PPM B
STD 10.0 PPM B
STD 25.0 PPM B
90 STD 25.0 PPM B
91 STD 50.0 PPM B
92 STD 50.0 PPM B
93 STD 100.0 PPM B
94 STD 100.0 PPM B
95 END
. .\CHLORIDE 1951801
. .\CHLORIDE 1951801
. .\CHLORIDE 1951804
..\CHLORIDE 1951804
. .\CHLORIDE 1951805
. .\CHLORIDE 1951805
..\CHLORIDE 1951807
..\CHLORIDE 1951807
..\CHLORIDE 1951809
..\CHLORIDE 1951809
. .\CHLORIDE 1951811
..\CHLORIDE 1951811
. .\CHLORIDE 1951804
. .\CHLORIDE 1951804
. .\CHLORIDE 1951804
..\CHLORIDE 1951804
..\CHLORIDE 1953501
. .\CHLORIDE 1953501
..\CHLORIDE 1953501
. .\CHLORIDE 1953501
..\CHLORIDE 1953501
. .\CHLORIDE 1953501
. .\CHLORIDE STD005
..\CHLORIDE STD005
..\CHLORIDE STD001
. .\CHLORIDE STD001
-..\CHLORIDE STD005
. .\CHLORIDE STD005
. .\CHLORIDE STD010
..\CHLORIDE STD010
. .\CHLORIDE STD025
. .\CHLORIDE STD025
. .\CHLORIDE STD050
..\CHLORIDE STD050
. .\CHLORIDE STD100
. .\CHLORIDE STD100
..\STANDCL. END
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
100
100
1
1
100
100
100
100
100
100
1
1
2
2
2
2
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
     Comment:
     TLI PROJECT,44369,44434,44451,  ANALYZED  ON THIS SCHEDULE FOR (HCL)
     DATE 01-06-98.(STD) USED  FOR  THIS  PROJECT  ARE  ICS3-1-3 THRU 9 QC USED
     LOT #M-ION03141,ANIONpELUENT  USED  LOT  #010698.-  LOOP  SIZE (25uL)  RAN
     BY LESLIE JONES..  •.  [ \(\iVM\^
                                                                            21

-------
                  DIONEX SCHEDULE - C:\DX\SCHEDULE\44369CL2.SCH

Inj#    Sample Name     Method      Data  File             Vol.      Dil.

 1  STD 0.5 PPM F        ..\CHLORIDE STD005                  1        1
 2  STD 0.5 PPM F        ..\CHLORIDE STD005                  1        1
 3  STD 1.0 PPM  F       ..\CHLORIDE STD001                  1        1
 4  STD 1.0 PPM  F       ..\CHLORIDE STD001                  1        1
 5  STD 5.0 PPM  F       ..\CHLORIDE STD005                  1        1
 6  ST&- &XD PPM-- F       ..\CHLORIDE STD005                  1        1
 7  STD 10.0 PPM  F      ..\CHLORIDE STD010                  1        1
 8  STD 10.0 PPM  F      ..\CHLORIDE STD010                  11
 9  STD 25.0 PPM  F      ..\CHLORIDE STD025                  1        1
 10 STD 25.0 PPM  F      ..\CHLORIDE STD025                  11
 11 STD 50.0 PPM  F      ..\CHLORIDE STD050                  1        1
 12 STD 50.0 PPM  F      ..\CHLORIDE STD050                  1        1
 13 STD 100.0 PPM  F     ..\CHLORIDE STD100       ..           1        1
 14 STD 100.0 PPM  F     ..\CHLORIDE STD100                  1        1
 15 NAOH BLANK           ..\CHLORIDE NAOHBL         .        1        1
 16 NAOH BLANK           ..\CHLORIDE NAOHBL                  1        1
 17 QC  30 PPM           ..\CHLORIDE QC30PPM                 1        1
 18 QC  30 PPM           ..\CHLORIDE QC30PPM                 1        1
 19 194-52-2             ..\CHLORIDE 1945202                 1        1
 20 194-52-2             ..\CHLORIDE 1945202                 1        1
 21 194-52-4             ..\CHLORIDE 1945204                 1        1
 22 194-52-4             ..\CHLORIDE 1945204                 11
 23 194-52-6             ..\CHLORIDE 1945206                 1        1
 24 194-52-6             ..\CHLORIDE 1945206                 1        1
 25 194-52-9             ..\CHLORIDE 1945209                 1        2
 26 194-52-9             ..\CHLORIDE 1945209                 1        2
 27 194-52-10            ..\CHLORIDE 1945210                 1        2
 28 194-52-10            ..\CHLORIDE 1945210                 1        2
 29 194-52-11            ..\CHLORIDE 1945211                 111
 30 194-52-11            ..\CHLORIDE 1945211 .                Ill
 31 194-52-13            ..\CHLORIDE 1945213                 111
 32 194-52-13            ..\CHLORIDE 1945213                 111
 33 194-52-15            ..\CHLORIDE 1945215                 111
 34 194-52-15            ..\CHLORIDE 1945215                 11        1
 35 194-52-17            ..\CHLORIDE 1945217                 1        1        1
 36 194-52-17            ..\CHLORIDE 1945217                 1        1        1
 37 194-52-19            ..\CHLORIDE 1945219                 1        11
 38 194-52-19            ..\CHLORIDE 1945219                 111
 39 194-52-21            ..\CHLORIDE 1945221       '111
 40 194-52-21            ..\CHLORIDE 1945221                 111
 41 194-52-23            ..\CHLORIDE 1945223                 11        1
 42 194-52-23            ..\CHLORIDE 1945223                 111
 43 194-52-25            ..\CHLORIDE 1945225                 111
 44 194-52-25            ..\CHLORIDE 1945225                 111
 45 194-52-27            ..\CHLORIDE 1945227                 111
 46 194-52-27            ..\CHLORIDE 1945227                 111
 47 194-52-30            ..\CHLORIDE 1945230                 111
 48 194-52-30            ..\CHLORIDE 1945230                 111
 49 194-52-32            ..\CHLORIDE 1945232                 111
 50 194-52-32            ..\CHLORIDE 1945232                 1        1
 51 194-52-34            ..\CHLORIDE 1945234                 1        1
 52 194-52-34            ..\CHLORIDE 1945234                 1        1
 53 194-52-35            ..\CHLORIDE 1945235                 1        1
 54 194-52-35            ..\CHLORIDE 1945235                 1        1        1
 55 194-52-36            ..\CHLORIDE 1945236                 1        1    ool
 56 194-52-36            ..\CHLORIDE 1945236                 1        1    C. £ 1
 57 194-52-38            ..\CHLORIDE 1945238                 111
 58 194-52-38            ..\CHLORIDE 1945233                 111

-------
Inj#
Sample Name
Method
Data File
Vol.
Oil.  Int.Std
59 194-52-39
60 194-52-39
61 194-52-2 MS
« 194-52-2 MS
194-52-2. MSD
194-52-2 MSD
65 195-18-2
66 195-18-2
67 195-i3~3 . ,--
68 195-13-3
69 195-18-6
70 195-18-6
71 195-18-8
72 195-18-8
73 195-18-10
74 195-18-10
75 195-18-12
76 195-18-12
77 195-18-14
78 195-18-14
79 195-18-2 MS
80 195-18-2 MS
81 195-18-2 MSD
82 195-18-2 MSD
83 195-35-2
84 195-35-2
85 195-35-2 MS
86 195-35-2 MS
» 195-35-2 MSD
195-35-2 MSD
STD 0.5 PPM B
90 STD 0.5 PPM B
91 STD 1.0 PPM B
92 STD 1.0 PPM B
93 STD 5.0 PPM B
94 STD 5.0 PPM B
95 STD 10.0 PPM B
96 STD 10.0 PPM B
97 STD 25.0 PPM B
98 STD 25.0 PPM B
99 END
..\CHLORIDE 1945239
..\CHLORIDE 1945239
..\CHLORIDE 1945202
..\CHLORIDE 1945202 ;
..\CHLORIDE 1945202
..\CHLORIDE 1945202
..\CHLORIDE 1951802
..\CHLORIDE 1951802
..\CHLORIDE 1951803
..\CHLORIDE 1951803
..\CHLORIDE 1951806 .
..\CHLORIDE 1951806
..\CHLORIDE.1951808
..\CHLORIDE 1951808
..\CHLORIDE 1951810
..\CHLORIDE 1951810
..\CHLORIDE 1951812
..\CHLORIDE 1951812
..\CHLORIDE 1951814
..\CHLORIDE 1951814
..\CHLORIDE 1951802
. .\CHLORIDE 1951802
..\CHLORIDE 1951802
..\CHLORIDE 1951802
..\CHLORIDE 1953502
. .\CHLORIDE 1953502
..\CHLORIDE 1953502
. .\CHLORIDE 1953502
. .\CHLORIDE 1953502
..\CHLORIDE 1953502
..\CHLORIDE STD005
. .\CHLORIDE STD005
. .\CHLORIDE STD001
..\CHLORIDE STD001
. .\CHLORIDE STD005
. .\CHLORIDE STD005
. .\CHLORIDE STD010
. .\CHLORIDE STD010
..\CHLORIDE STD025
. .\CHLORIDE STD025
. .\STANDCL. END
1
1
1
1 .
1
1
1
1
1
1
1
1
1
1
1
1
1
1
. 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
•A.
1
1
1
    Comment:
    TLI PROJECT #44369,44434, 44451 ANALYZED ON THIS SCHEDULE FOR  (CL2)
    DATE 01-08-98.(STD) USED FOR THIS PROJECT ARE  ICS3-2-1 THRU 7 QC USED
     ICS3-3-2,ANION ELUENT USED LOT #010898. LOOP  SIZE (25uL)  RAN BY
    LESLIE JONES.
                                                                           23

-------
                  DIONEX SCHEDULE - C:\DX\SCHEDULE\44369R.SCH

Inj#    Sample Name     Method      Data File            Vol.      Dil.  Int.Stc

 1  STD 50.0 PPM  B     ..\CHLORIDE STD050                 1        1
 2  STD 50.0 PPM  B     ..\CHLORIDE STD050                 1        1
 3  STD 100.0 PPM  B    ..\CHLORIDE STD100                 1        1
 4  STD 100.0 PPM  B    ..\CHLORIDE STD100                 1        1
 5  END                 ..\STANDCL.  END                    11

     Comment:
     TLI PROJECT 44369,44434,44451 ,  ANALYZED ON THIS SCHEDULE FOR (CL2)
     DATE 01-08-98.(STD) USED'FOR THIS PROJECT ARE  ICS3-2-1 THRU 7  QC
     USED ICS3-3-2 ,ANION ELUENT USED LOT #010898. LOOP  SIZE  (25uL)
     LESLIE JONES

-------
TRIANGLE LABORATORIES INC.
                TLM44MB-HCL
                CLIENT SAMPLES
                EASTERN RESEARCH GROUP
                OMW-JANUARY-M
                                                                                                                                                                                       CJ
| ni n
1*4-92-1
1*4-92-3
1*4-52-9
194-52-7
1*4-52-8
1*4-52-12
1*4-52-14
1*4-52-16
1*4-52-18
1(4-52-20
1*4-92-22
194-52-24
1*4-52-28
1*4-52-2*
194-52-2*
1*4-52-31
1*4-52-33
1*442-37
1*4-92-1 MS
1*4-92-1 M^O
J
MATRIX SPIKE
1 SAMPLED '
18*92-1 0*5
1*4-52-1 M*0
CLIENT B
CAA-03
CAA-07
CAA-11
CAA-15
CAA-19
CAA-27
CAA-31
CAA-33
CAA-3*
CAA-91
CAA-55
CAA-59
CAA-63
CAA-75
CAA-«5
CAA-M
CAA-103
CAA-254
CAA03
CAA^Jl

CAA-03
CAA-03
RT
195
195
1*3
193
163
1.93
195
1.94
1.94
1.91
1.91
1.91
1.93
1.93
192
1.92
199
1.93
1.94
1.94
1.94
1.94
1.96
1.97
1.86
190
1.94
1.»3
NO
ND
ND
ND
1.99
1 94
1.94
1.94
194
194
NATIVE AMT.
CL(mg)
073
073
ARIA
3832018*
38727*63
61109730
61083245
6489136
643*064
290118387
298089794
371446587
270012082
82246293
62777698
91973976
91333946
204079040
20*724183
187964064
163313702
374089488
374101093
298243419
29324*642
256694761
293097683
455187710
455296*89
9083928
9102827
3999803
3839822
ND
ND
NO
ND
341899117
341359444
383161337
389413634
381923021
360279934
M9 AMT.
CL (mo)
4.14
4.0*
LOO AREA
7.98
73*
7.*1
7.91
881
661
8.46
6.47
643
8.43
7*2
7*2
7.9*
7.06
631
831
827
8.27
697
697
6.47
6.47
841
6.40
688
888
•71
671
6*0
1.56
ND
ND
ND
ND
8.53
6.53
658
6.59
858
8.58
AMT.
8PIKE(mol
3.7
3.7
RUN COMC
ttm
6.20
676
12.66
12.65
1.14
1.11
42.82
43.73
40.01
39.61
12.63
1291
14.27
14.18
30.49
30.7*
26.13
27.61
9430
54.30
4376
43.0*
37.96
37.42
6546
65.47
0.91
091
0.72
0.6*
ND
ND
ND
NO
4981
49.78
55.59
94.42
95.36
99.19
OF
2
2
DILUTION
FACTOR
1
1
1
1
1
1
2
2
2
2
1
1
1
1
20
20
1
1
20
20
20
20
1
1
20
20
1
1
1
1
1
1
1
1
1
1
2
2
2
2
*RECOVERY
108
104
•AMPLE CONC
6.20
6.28
12.6*
12.65
1.14
1.1!
89.29
67.47
80.01
7981
1263
12.91
1427
14.16
60977
619.87
28.13
27.81
1063*4
1046.02
679.1*
•6173
37.9*
37.42
1309.14
1309.33
0.91
091
0.72
0.8*
ND
ND
ND
NO
49.61
49.78
111.11
112.63
110.76
110.31


AVO CONC
623
12.8*
1.14
86.3*
79.41
12.17
14.22
•12.82
27.97
1069.M
6*6.21
37.1*
130*74
0,91
0.71
4.04
4.04
49.7*
111.97
110.54
RPO
1.0
0.0
0.7
2.*
0.5
0.*
0.7
1.0
1.1
0.0'
1.6
1.4
0.0
0.3
4.0
NA
NA
0.1
1.5
0.4
TOTAL
mL
37
37
34
31
40
37
39
40
26
41
17
35
41
39
34
39
36
3*
37
37
TOTAL me
a
073
0.47
0.04
2.M
3.1*
0.4*
030
2431
0.71
44.51
3112
1.33
9368
0.03
0.02
4.014
4.014
1.7*
4.14
4.0*
TOTAL ma
HCL
074
0.46
0.04
2.75
37*
0.4*
031
2971
Oil
49.7*
33.04
1J6
5570
0.03
0.02
4.014
4.014
1.»4
-

PH
1
1
3
1
1
1
I
1
1
1
1
1
1
1
1
1
1
1
-

CTVflMtM*.
mg HCL: (Tl
                              . • Hunt ««x iwte KMT it x 100
                TOTAL mo HCL: (TOTAL mg CL)(FWHCL/MWCL>
                TOTAL mg CL2: TOTAL mg CL > 1
                ND- NOT DETECT
 UI4436»-HCt

-------
                  Data Reprocessed On 01/08/1998  11:36:14
  Sample Name:  194-52-1
  Data File  :  C:\DX\DATA\44369HCL\19452011.D19
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1  Inject#:  19
  Analyst    :                 Column:
                Date:  01/07/1998 02:22:14
                            Detector:PED-Cond.
Calibration — Vo»lume   Dilution Points Rate   Start    Stop Area Reject

External          1          1   3600  5Hz    0.00    5.29         1000

                       component Report: All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.95  CHLORIDE
    US
                       Totals
        0.000    2531346   38320169

        0.000    2531346   38320169
                     1  -9.46
            File:  19452011.D19 Sample: 194-52-1
         30
         20
         10
                          CHLORIDE/ 1.95
           0
   2          3
         Minutes
                                                                            26

-------
                  Data Reprocessed  On  01/08/1998 11:38:07
¥
 IA
   Sample Name:  194-52-1
Data File  :  C:\DX\DATA\44369HCL\19452011.D20
 vthod     :  C:\DX\METHOD\CHLORIDE.met
 JI Address:  1  System:  1  Inject/: 20
Analyst    :                 Column:
                                            Date:  01/07/1998 02:36:00
           Detector:PED-Cond.
 Calibra*i-e«—Voinme   Dilution Points Rate  Start   Stop Area Reject

 External          1           1    3600   5Hz   0.00   5.47        1000

 ********************** component  Report: All Components ***********************
  Pk.    Ret Component
  Hum   Time Name
                            Concentration
 Height
    Area  El. %Delta
         Code
        1.95 CHLORIDE
                       Totals
                                    0.000
                                   f^m^m^m^m^m •

                                    0.000
 2484337
• ^ «• ^m^m^* ^m^m*

 2484337
38727983

38727983
1  -9.46
            File: 19452071.D20 Sample: 194-52-1
         10
     uS
                          CHLORIDE/ 1.95
                                I

                                                       i  i  r
            0
                                        3
                                     Minutes
                                                                            27

-------
                  Data Reprocessed On 01/07/1998  13:35:09
  Sample Name:  194-52-3
  Data File  :  C:\DX\DATA\44369HCL\19452031.D21
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject#:  21
  Analyst    :                 Column:
                Date: 01/07/1998 02:49:45
                            Detector:PED-Cond.
                          ======:
Calibra*ioR••- Voitime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.38        1000

                       Component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
          Height
Area  Bl. %Delta
     Code
       1.93  CHLORIDE
                      Totals
0.000    5100075    81105730

0.000    5100075    81105730
                                       1 -10.39
            File:  19452031.D21 Sample: 194-52-3
         10
    uS
         0
                         CHLORIDE/  1.93
W vx- 	 	
. I I I I 1 1
) 1
-r T | i
2
I I I I I I .1 I 1 I I I I 1
3 4 5
                                       Minutes
                                                                           28

-------
                  Data Reprocessed On 01/07/1998 13:37:02
  Sample Name:  194-52-3
I  Data File  :  C:\DX\DATA\44369HCL\19452031.D22
^'ethod     :  C:\DX\METHOD\CHLORIDE.met
W.tCI Address:  l  System:  1  Inject#: 22
I  Analyst    :                 Column:
                Date:  01/07/1998 03:03:30
                            Detector:PED-Cond.

Calibrarfei-©»•- Voitime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   O.OQ   5.20         1000

********************** component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.93 CHLORIDE
                       Totals
        0.000    5122099   81063245

        0.000    5122099   81063245
                     1 -10.39
            File: 19452031.D22 Sample: 194-52-3
         10
    uS
                          CHLORIDE/  1.93
   I  '   '
                                           1
                                                           1  I	T
                                 2         3
                                       Minutes
                                                                            29

-------
                  Data Reprocessed On 01/07/1998 13:38:37
  Sample Name:  194-52-5
  Data File  :  C:\DX\DATA\44369HCL\19452051.D23
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#: 23
  Analyst    :                 Column:
                                       Date:  01/07/1998 03:17:15
                                                   Detector:PED-Cond
Ca libra* ion - Volume   Dilution Points Rate  Start   Stop Area Reject
External          1          1   3600  5Hz   0.00   5.20        1000
                       Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                       Concentration
Height
   Area  Bl. %Delta
        Code
       1.85 CHLORIDE
                       Totals
                               0.000
                               0.000
961962
961962
6489136
6489136
1 -14.11
    US
            File: 19452051.D23 Sample: 194-52-5
 9.0
 8.0
 7.0
 6.0
 5.0
 4.0
 3.0
 2.0
 1.0
 0.0
-1.0
                         CHLORIDE/  1.85
              \  I  T  T
                                                           I  I  I
                                 2         3
                                       Minutes
                                                                            30

-------
                  Data Reprocessed On 01/07/1998 13:39:45
  Sample Name:  194-52-5
 Data  File   : C:\DX\DATA\44369HCL\19452051.D24
"Method      : C:\DX\METHOD\CHLORIDE.met
  JI Address: 1  System:  1   Inject#:  24
 Analyst     :                 Column:
                                            Date:  01/07/1998  03:31:01
                                                          Detector:PED-Cond.
Calibration .Volume   Dilution Points Rate  Start   Stop Area Reject
External          1          1   3600  5Hz   0.00   5.56        1000
********************** component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                             Concentration
        Height
   Area  Bl. %Delta
        Code
       1.85 CHLORIDE
    US
                       Totals
                                     0.000
                                     0.000
         950632
         950632
6439064
6439064
1 -14.11
            File: 19452051.D24 Sample: 194-52-5
       9.0
       8.0
       7.0
       6.0
       5.0
       4.0
       3.0
       2.0
       1.0
       0.0
      -1.0
           0
                        CHLORIDE/  1.85
              i  i  i  r
                        i  r  i  i
                              2
                                            i  i  i  r
                                                      i  r  i  i
  3
Minutes
                                                                            31

-------
                  Data  Reprocessed On 01/26/1998 14:52:08
  Sample Name:  194-52-7
  Data File  :  C:\DX\DATA\44369HCL\19452071.D25
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject*:  25
  Analyst    :                 Column:
                                      Date:  01/07/1998  03:44:47
                                                 Detector:PED-Cond.
Calibration * Voiume   Dilution Points Rate   Start   Stop Area Reject
External          1           2   3600  5Hz   0.00   5.34         1000
                      component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                      Concentration
Height
Area  Bl. %Delta
     Code
       1.93 CHLORIDE
    US
                      Totals
                              0.000   25116117  290116367
                             m^m^mmm^m^ ^ ^ ^«» ^m^m ^m •* v ^m ^v ^m ^m ^m ^*^m ^m ^H *^*^^m^m
                              0.000   25116117  290116367
                     1 -10.23
 90
 80
 70
 60
 50
 40
 30
 20
 10
  0
-10
            File:  19452071.D25 Sample: 194-52-7
           0
                         CHLORIDE/  1.93
                i  i ~
                                  3
                               Minutes
     4
                                                       i  i  r
   I
   5
                                                                          32

-------
                  Data Reprocessed On 01/07/1998  13:42:08
  Sample Name: 194-52-7
  Data File  :  C:\DX\DATA\44369HCL\19452071.D26
 r lethod     :  C:\DX\METHOD\CHLORIDE.met
 rACI Address:  1  System:  1  Inject#: 26
  Analyst    :                 Column:
                                      Date:  01/07/1998 03:58:32
                                                 Detector:PED-Cond.
Calibra*i-on — Voltime   Dilution Points Rate  Start    Stop Area Reject
External          1          2   3600  5Hz   0.00    5.43        1000
********************** Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                      Concentration
Height
Area  Bl. %Delta
     Code
       1.95 CHLORIDE
    US
                       Totals
                              0.000    25124595  298065754
                             • ^•^^^••»«» ^ «W •»«• ^^^B^«»«*^»^^»^^»«B«* ^^»«* ••
                              0.000    25124595  298065754
                     1  -9.46
            File: 19452071.D26 Sample: 194-52-7
 90
 80
 70
 60
 50
 40
 30
 20
 10
  0
-10
                          CHLORIDE/  1.95
                                        i  I  r i  r »    i  r  i   i
                                          3
                                       Minutes
                                                                           33

-------
                  Data Reprocessed On 01/07/1998  13:42:55
  Sample Name:  194-52-8
  Data File  :  C:\DX\DATA\44369HCL\19452081.D27
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  27
  Analyst    :                 Column:
                Date:  01/07/1998 04:12:17
                            Detector:PED-Cond |
Calibration•- Voiume   Dilution Points  Rate   Start   Stop Area Reject

External          1          2   3600   5Hz    0.00   5.20        1000

********************** component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.94 CHLORIDE
    US
                       Totals
        0.000   23986044   271446567
        • VW»«» ^ •»4W^B^ ^^ ^ •••••••••» ^ ^V ^V ^» ^» ••• ^B •••••» ^B

        0.000   23986044   271446567
                     1  -9.77
            File: 19452081.D27 Sample: 194-52-8
         40
         30
         20
         10
                          CHLORIDE/  1.94
                        i   r  i  i
                                     i  i  i
                                 2          3
                                       Minutes
                                                               1  I  '
                                                                           34

-------
                  Data Reprocessed  On  01/07/1998  13:44:07
  Sample Name:  194-52-8
 Data File   : C:\DX\DATA\44369HCL\19452081.D28
j'ethod      : C:\DX\METHOD\CHLORIDE.met
"id Address: 1  System: 1  Inject/: 28
 Analyst     :                Column:
                                            Date: 01/07/1998 04:26:03
                                                         Detector:PED-Cond.
Calibration - Volnme   Dilution  Points Rate   Start    Stop Area Reject

External          1          2    3600   5Hz    0.00    5.15        1000

                       Component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.94  CHLORIDE
                       Totals
                                    0.000   23949863  270012062
                                    • ^"^•^ ••dM^ ••^•^•^••V^ ^^•^^^••^•^^•^•^•^•^^•^B

                                    0.000   23949863  270012062
                     1  -9.77
            File:  19452081.D28 Sample: 194-52-8
    US
        40
        30
        20
         10
                          CHLORIDE/  1.94
-x, ^
I 1 1 I I I 1 1 I I 1
) 1.2

I i 1 I I I K 1 I 1 I
3 4
Minutes
1 ' 1
5


-------
                  Data Reprocessed On 01/26/1998 14:54:27
  Sample Name:  194-52-12
  Data File  :  C:\DX\DATA\44369HCL\19452121.D29
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  29
  Analyst    :                 Column:
                Date:  01/07/1998 04:39:48
                            Detector:PED-Cond.
Calibration' Voltime   Dilution  Points Rate  Start   Stop Area Reject

External          1           1    3600  5Hz   0.00   5.15        1000

********************** component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
 Height
     Area  Bl.  %Delta
          Code
       1.91  CHLORIDE
                      Totals
        0.000

        0.000
9086889

90,86889
 82248253
m^m^m •• M» ^» ^» ^ ••

 82248253
1 -11.01
           File: 19452121.D29 Sample:  194-52-12
70
60
50
40
uS 30
20
10
0
-10
C



•

CHLORIDE/ 1.91
k^

1 1 1 1 I 1 I 1 1 | 1 1 I 1 I 1 1: k 1 1 1 1 1 1 1
) 1 2 34 5
Minutes

-------
                  Data Reprocessed On 01/26/1998 14:55:34
   Sample Name:  194-52-12
 I  U

f;
Data File  :  C:\DX\DATA\44369HCL\19452121.D30
    od     :  C:\DX\METHOD\CHLORIDE.met
    Address:  1  System:  1  Inject*:  30
Analyst    :                 Column:
                                           Date: 01/07/1998 04:53:36
            Detector:PED-Cond.
 Calibration - Volume   Dilution Points Rate  Start   Stop Area Reject

 External          1          1   3600  5Hz   0.00   5.02        1000

                       component Report: All Components ***********************
  Pk.    Ret Component
  Num    Time Name
                            Concentration
 Height
    Area  Bl.  %Delta
         Code
        1.91 CHLORIDE
                       Totals
                                    0.000
                                   *^m*m*m mm ^m ••

                                    0.000
 9125430
mmff^m^m*^ ^m ^ ^ •

 9125430
82777696


82777696
1 -11.01
            File: 19452121.D30 Sample: 194-52-12
70
60
50
40
uS 30
20
10
n
w
-10
t \*
c





CHLORIDE/ 1.91

/ ^>-_

. . . . | . . . . | . . . . . | , , - , , | , , , , |
) 12 3 4 5
Minutes
                                                                           37

-------
                  Data Reprocessed  On  01/26/1998 14:57:21
  Sample Name  194-52-14
  Data File
  Method
  ACI Address
  Analyst
C:\DX\DATA\44369HCL\19452141.D31
C: \DX\METHOD\CHLORIDE.met
1  System:  1  Inject*:  31
               Column:
                               Date:  01/07/1998 05:07:21
            Detector:PED-Cond.
                                                             I
Calibration•- Vo'ltime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600   5Hz   0.00   5.29        1000

********************** component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
               Concentration
  Height
    Area   Bl.  %Delta
          Code
       1.91 CHLORIDE
                      Totals
                       0.000

                       0.000
 10117422
• ^ ^ ^B «• ^ «v ^» •• m

 10117422
 91973978
• MB ^V ^» «» «W «•• ^» ^B

 91973978
1 -11.01
            f/fe;  19452141.D31 Sample: 194-52-14
70
60
50
40
uS 30
20
10
-10





CHLORIDE/ 1.91
I
I
f\^

— i — i — i — i — i — i — i — i i i i i i i i i i T~^T | i i i i | r~
           0
                            3
                        Minutes
                                                                            38

-------
                  Data Reprocessed On 01/26/1998 14:58:16
  Sample Name:  194-52-14
Data File  :  C:\DX\DATA\44369HCL\19452141.D32
 ethod     :  C:\DX\METHOD\CHLORIDE.met
,*CI Address:  1  System:  1  Inject#:  32
Analyst    :                 Column:
                                            Date:  01/07/1998  05:21:07
                                                         Detector:PED-Cond.
             Voitime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.11        1000

********************** component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.91 CHLORIDE
                       Totals
                                    0.000   10065521   91333946

                                    0.000   10065521   91333946
                     1 -11.01
            File:  19452141.D32 Sample: 194-52-14
70
60
50
40
uS 30
20
10
0
-10
C





CHLORIDE/ 1.91
/L 	

' ' r~~i i ' ' ' ' i i i i i — i — i — i — :i — i — i — i — i — i — i — i—
> 1 2 3 4 5
Minutes
                                                                           39

-------
                  Data Reprocessed On 01/07/1998 13:53:05
  Sample Name:  194-52-16
  Data File  :  C:\DX\DATA\44369HCL\19452161.D33
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1  Inject#:  33
  Analyst    :                 Column:
                Date:  01/07/1998  05:34:52
                            Detector:PED-Cond.
Calibration - Voitime   Dilution Points Rate  Start   Stop Area Reject

External          1         20   3600   5Hz   0.00   5.38        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.93  CHLORIDE
                       Totals
        0.000   23595666   204079040
       • ^» •• ^» ^m ^» ^» ^» ^ «p ^m ^» ^» ^» «w *^ ^m ^BflB ^m ^» ^m ^» ^m ^m mmm»mm

        0.000   23595666   204079040
                     1 -10.39
            File:  19452161.D33 Sample: 194-52-16
80
60
uS 40
20
0
C


CHLORIDE/ 1.93
|
/I

i i i i I i i i i I i i i i i i i i *i I i i i i i i
) 123 4 5
Minutes
                                                                            40

-------
                  Data Reprocessed On 01/07/1998 13:56:29
  Sample Name:  194-52-16
  Data File  :  C:\DX\DATA\44369HCL\19452161.D34
  " ethod     :  C:\DX\METHOD\CHLORIDE.met
   -CI Address:  1  System:  1  Inject#: 34
  Analyst    :                 Column:
                    Date: 01/07/1998 05:48:38
                                Detector:PED-Cond.

Calibration - Vo-lume   Dilution Points Rate  Start   Stop Area Reject

External          1         20   3600  5Hz   0.00   5.43        1000

********************** component Report:  All Components  ***********************
 Pk.    Ret Component
 Num   Time Name
    Concentration
Height
Area  Bl. %Delta
     Code
       1.93 CHLORIDE
                       Totals
             0.000   23564735  206224183

             0.000   23564735  206224183
                     1 -10.39
            File: 19452161.D34 Sample: 194-52-16
         80


         60


    uS   40


         20
CHLORIDE/ 1.93
                    r  i  i  i  i
                                                       i—i—i—i
                                          3         4
                                       Minutes

-------
                  Data Reprocessed On 01/26/1998 15:40:12
  Sample Name:  194-52-18
  Data File  :  C:\DX\DATA\44369HCL\19452181.D35
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  35
  Analyst    :                 Column:
                Date: 01/07/1998 06:02:24
                            Detector:PED-Cond.
Calibration * Voitime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.34         1000

********************** component Report:  All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.92 CHLORIDE
                       Totals
        0.000   22198956   187564064
        • •• ^» ^ «•••«••• ^ ^ •» IV ^^B^»«B^ ••^«»«»^V«*^B WB^B W»^

        0.000   22198956   187564064
                     1 -10.54
            File: 19452181.D35 Sample: 194-52-18
    US
         40
         30
         20
         10
                          CHLORIDE/ 1.92
                                2         3
                                       Minutes

-------
                  Data Reprocessed On 01/26/1998  15:42:10
  Sample Name:  194-52-18
^Data  File   : C:\DX\DATA\44369HCL\19452181.D36
 Tethod      : C:\DX\METHOD\CHLORJDE.met
  :i Address: 1  System: 1  Inject#: 36
 Analyst     :                Column:
                                            Date: 01/07/1998 06:16:10
                                                         Detector:PED-Cond.
Calibration - Voitime   Dilution Points  Rate   Start   Stop Area Reject

External          1          1   3600   5Hz    0.00   5.15        1000

                       Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.92 CHLORIDE
    US
                       Totals
                                    0.000   22155154  185313702
                                    • ^"^"^••^•^^•^^•^ «»^»^^»^^ ^^«*^M^B^B^»^B ^m ^m ^m

                                    0.000   22155154  185313702
                     1 -10.54
            Fife:  19452181.D36 Sample: 194-52-18
       40



       30



       20



       10
                          CHLORIDE/ 1.92
                                                i  i  r
                                                         i  i  i  r
                                 2          3
                                       Minutes
                                                                           43

-------
                  Data Reprocessed On 01/07/1998  13:58:53
  Sample Name:  194-52-20
  Data File  :  C:\DX\DATA\44369HCL\19452201.D37
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1  Inject#:  37
  Analyst    :                 Column:
                Date: 01/07/1998 06:29:56
                            Detector:PED-Cond
Calibration - Voitime   Dilution Points Rate   Start    Stop Area Reject

External          1         20   3600   5Hz    0.00    5.25        1000

********************** Component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.95  CHLORIDE
                       Totals
        0.000   39473334  374069466
       »^»^»M»^ ^ ^» ^B ^ ^» ^» •• «» ^v OHI ^ ^ ^m ^ ^v •» ^v «« •§• ^B ^m *•

        0.000   39473334  374069466
                     1  -9.30
            File: 19452201.D37 Sample: 194-52-20
         80
         60
    uS  40
         20
                          CHLORIDE/  1.95
                                I
              I  I  I  I
                        I  I   I  I
                                2          3
                                       Minutes
                                                                 I  '
                                                                            44

-------
                  Data Reprocessed On 01/07/1998  13:59:57
  Sample Name:  194-52-20
I  J
kData  File   : C:\DX\DATA\44369HCL\19452201.D38
plethod      : C:\DX\METHOD\CHLORIDE.met
  ACI Address: 1  System:  1   Inject#:  38
  Analyst     :                 Column:
Date: 01/07/1998 06:43:42
                                                         Detector:PED-Cond.
Calibration•- Volume   Dilution Points Rate   Start   Stop Area Reject

External          1         20   3600  5Hz    0.00   5.06        1000

********************** Component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                             Concentration
  Height
Area  Bl. %Delta
     Code
       1.93  CHLORIDE
                       Totals
                                     0.000   39370862  374101093

                                     0.000   39370862  374101093
                       1 -10.08
            File:  19452201.D38 Sample: 194-52-20
        80


        60


    uS  40


        20


         0
                           CHLORIDE/  1.93
              I  I  I  I  I   I  I  I
                                            3
                                       Minutes
                                                                          45

-------
                  Data  Reprocessed On 01/26/1998  15:54:46
  Sample Name:  194-52-22
  Data File  :  C:\DX\DATA\44369HCL\19452221.D39
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject/:  39
  Analyst    :                 Column:
                    Date:  01/07/1998  06:57:28
                               Detector:PED-Cond J
                            1
Calibration- Voi-ume   Dilution Points Rate  Start   Stop Area Reject

External          1         20   3600  5Hz   0.00   5.29         1000

********************** component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
    Concentration
Height
Area  Bl. %Delta
     Code
       1.94  CHLORIDE
                       Totals
            0.000    32558757  298243419
           • *»^^^»^ «•»•»•» •»^«V«»^V«V^»^«»«»^«l»«»«»^B ^m ^**^B

            0.000    32558757  298243419
                     1  -9.77
            File:  19452221.D39 Sample: 194-52-22
        80


        60


    uS  40


        20
CHLORIDE/ 1.94
                                           3
                                       Minutes

-------
                  Data Reprocessed On 01/26/1998 15:56:07
  Sample Name:  194-52-22
Data File  :  C:\DX\DATA\44369HCL\19452221.D40
 iethod     :  C:\DX\METHOD\CHLORIDE.met
\CI Address:  1  System:  1  Inject#:  40
Analyst    :                 Column:
                                            Date: 01/07/1998  07:11:13
                                                         Detector:PED-Cond.
Calibration - Voltime   Dilution Points Rate   Start   Stop Area Reject

External          1         20   3600  5Hz    0.00   5.34        1000

********************** Component  Report: All Components **********************:
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.94 CHLORIDE
                      Totals
                                    0.000    32436487  293249642

                                    0.000    32436487  293249642
                     1  -9.92
            File:  19452221.D40 Sample: 194-52-22
80
60
uS 40
20
0
C


CHLORIDE/ 1.94
A
.A.

i i i i i i i i i i i i i i i i i i • i i i i i i i i
) 1 2345
Minutes
                                                                       47

-------
                  Data Reprocessed  On  01/26/1998 15:58:36
  Sample Name:  194-52-24
  Data File  :  C:\DX\DATA\44369HCL\19452241.D41
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject*: 41
  Analyst    :                Column:
                Date:  01/07/1998  07:24:59
                            Detector: PED-Cond .1
Calibration - Volume    Dilution Points Rate  Start   Stop Area Reject

External          1           1    3600  5Hz   0.00   5.20        1000

********************** component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.94  CHLORIDE
                      Totals
        0.000   24252613   256894761

        0.000   24252613   256894761
                     1  -9.92
           File: 19452241. D41 Sample: 194-52-24
80
60
uS 40
20
0
C

•
CHLORIDE/ 1.94
/v

I I i 1 I 1 1 1 1 I 1 1 1 I I i 1 1. 1 I 1 1 I 1 I
) 1 2 34 5
Minutes
                                                                       48

-------
                  Data Reprocessed On 01/26/1998 16:00:16
  Sample Name:  194-52-24
JData File   : C:\DX\DATA\44369HCL\19452241.D42
  sthod      : C:\DX\METHOD\CHLORIDE.met
 .CI Address: 1  System: 1  Inject#: 42
Analyst     :                Column:
                                            Date: 01/07/1998 07:38:45
                                                         Detector:PED-Cond.
Calibration - Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.29         1000

                       Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.94 CHLORIDE
                       Totals
                                    0.000   24142469  253057883
                                    • ••«• •• ^B W ^» ^» «•• ^» ^B ••••«• ^W«B^^^^B^ ^•••l* B^ •• ^m

                                    0.000   24142469  253057883
                     1  -9.92
            File: 19452241. D42 Sample: 194-52-24
         80
         60
    uS   40
         20
          0
                          CHLORIDE/ 1.94
                                2          3
                                       Minutes
                                                                        49

-------
                  Data Reprocessed On 01/26/1998  16:01:44
  Sample Name:  194-52-26
  Data File  :  C:\DX\DATA\44369HCL\19452261.D43
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1  Inject/:  43
  Analyst    :                 Column:
                Date:  01/07/1998 07:52:31
                            Detector: PED-Cond .1
Calibration —Voitune    Dilution Points Rate  Start   Stop Area Reject

External          1          20   3600  5Hz   0.00   5.15        1000

                       Component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.96  CHLORIDE
                      Totals
        0.000   46917783   455187710
       • ••^^^^•^••••^•••^•VB) ^«B^B wt^B^B^ ^m^m^m ^ ^«v ^M

        0.000   46917783   455187710
                     1  -8.68
           File: 19452261. D43 Sample: 794-52-26
        100
    uS
                           CHLORIDE/  1.96
             I   1  I  I    I   I  I  I    I  I  I  T  \  T  II  I     I  I  i  I
                                 2         3
                                       Minutes
                                                                         50

-------
                  Data Reprocessed On 01/26/1998 16:03:09
  Sample Name:  194-52-26
^Data File   : C:\DX\DATA\44369HCL\19452261.D44
  sthod      : C:\DX\METHOD\CHLORIDE.met
F-*CI Address: 1  System: 1  Inject#:  44
Analyst     :                Column:
                                            Date: 01/07/1998 08:06:17
                                                          Detector:PED-Cond.
Calibration - Volume   Dilution Points Rate  Start    Stop Area  Reject

External          1         20   3600  5Hz   0.00    5.38         1000

********************** component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.97 CHLORIDE
                       Totals
                                    0.000   46852353  455256685

                                    0.000   46852353  455256685
                     1  -8.53
            File:  19452261.D44 Sample: 194-52-26
        100
    uS
                          CHLORIDE/ 1.97

I I 1 I I 1 1
) 1

I I 1 I I 1 I I 1 I •! I I I
234
Minutes
1 ' 1 '
5


-------
                  Data Reprocessed On 01/07/1998  14:20:20
  Sample Name:  194-52-28
  Data File  :  C:\DX\DATA\44369HCL\19452281.D46
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  46
  Analyst    :                 Column:
                Date: 01/07/1998 08:33:49
                            Detector:PED-Cond.
Calibration — Volume   Dilution Points Rate  Start    Stop Area Reject

External          1          1   3600  5Hz   0.00    5.20         1000

********************** Component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
 Height
   Area  Bl.  %Delta
         Code
       1.88 CHLORIDE
                       Totals
        0.000
        »•••• v»«»^«

        0.000
 783678
» ^m ••> ^m ^» ^» ^m •

 783678
 5083926
• ^» ^» ^m ^» ^» •• ^B

 5083926
1 -12.71
    US
            File:  19452281.D46 Sample: 194-52-28
         30
         20
         10
                          CHLORIDE/  1.88
              1  I  I  I    1  1   I
   2         3
         Minutes
                                                      |
                                                      4

-------
                  Data Reprocessed On 01/07/1998  14:10:34
  Sample Name: 194-52-28
I  *
  Data File  :  C:\DX\DATA\44369HCL\19452281.D45
W^thod     :  C:\DX\METHOD\CHLORIDE.met
• JI Address:  1   System:  1   Inject#: 45
f Analyst    :                Column:
Date: 01/07/1998 08:20:03
                                                         Detector:PED-Cond.
Calibration• •- Vol*ime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.02         1000

********************** component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                             Concentration
  Height
   Area  Bl. %Delta
        Code
       1.90 CHLORIDE
    US
                       Totals
                                     0.000
                                     • W»^«V«M«W«

                                     0.000
  774789

  774789
5102627

5102627
1 -11.78
            Fife: 1945228 J.D45 Sample: 194-52-28
         30
         20
         10
                           CHLORIDE/  1.90
                                 |   i  i — i — i — i — i
                                 23
                                       Minutes
                                                      i — i — i — i — i — i — r
                                                       45
                                                                           53

-------
                  Data Reprocessed On 01/07/1998  14:27:56
  Sample Name:  194-52-29
  Data File  :  C:\DX\DATA\44369HCL\19452291.D48
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  l  System:  1  Inject/:  48
  Analyst    :                 Column:
                Date:  01/07/1998 09:01:21
                            Detector:PED-Conc
Calibration " Voitime   Dilution Points Rate   Start   Stop Area Reject

External          1          1   3600  5Hz    0.00   5.25         1000

********************** component Report: All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
Concentration
Height
   Area  Bl. %Delta
        Code
       1.94  CHLORIDE
                       Totals
        0.000
       »^^*B*»4Wfl

        0.000
429373

429373
3999603

3999603
1  -9.92
            File:  19452291.D48 Sample: 194-52-29
        20
    uS   10
                          CHLORIDE/ 1.94
	 ^f-^^ — • 	
f i 1 1 1 1 1 I 1 I i 1 i I I 1
) 1 2 3
I I • I I I I f 1 I f
4 5
                                       Minutes

-------
                  Data Reprocessed On 01/07/1998  14:27:01
                                 »'"	— ——!	——
  Sample Name:  194-52-29
L Data  File   : C:\DX\DATA\44369HCL\19452291.D47
m ethod      : C:\DX\METHOD\CHLORIDE.met
WACL Address: 1  System:  1  Inject#:  47
I  Analyst     :                 Column:
Date: 01/07/1998 08:47:36
                                                          Detector:PED-Cond.

Calibration - Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.20        1000

********************** Component Report:  All Components  ***********************
 Pk.    Ret Component
 Num   Time Name
                              Concentration
  Height
   Area  Bl. %Delta
        Code
       1.93  CHLORIDE
    US
                       Totals
                                      0.000

                                      0.000
  430714
 • «•• ^» ^» m* •» •• •

  430714
 3835622
m ••«•«• ^rn^rn***^

 3835622
1 -10.08
            File:  19452291.D47 Sample: 194-52-29
         20
         10
                          CHLORIDE/  1.93
                                 2         3
                                       Minutes

-------
                  Data Reprocessed On 01/27/1998  10:20:30
  Sample Name:  194-52-31
  Data File  :  C:\DX\DATA\44369HCL\19452311.D49
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject/:  49
  Analyst    :                 Column:
                Date:  01/07/1998 09:15:06
                            Detector:PED-Cond.
Calibration-Voltune   Dilution Points Rate  Start   Stop Area Reject

External          11   3600  5Hz   0.00   5.34        1000

********************** Component Report:  All Components ***********************
 PJc.     Ret Component
 Hum   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
    uS
                       Totals
        0.000

        0.000
     0
    »«•••

     0
   0

   0
0.00
            File: 19452311. D49 Sample: 194-52-31
         60
         50
         40
         30
         20
         10
                i—i—r
                          i—i—r
                                  n—i—i—r
                                                         \—i—r
                                2         3
                                       Minutes
                                                                        56-

-------
                  Data  Reprocessed On 01/27/1998 10:21:39
I  Sample Name:  194-52-31
I  Data File  :  C:\DX\DATA\44369HCL\19452311.D50
^ ethod     :  C:\DX\METHOD\CHLORIDE.met
W^CI Address:  1  System:  1   Inject#:  50
j  Analyst    :                 Column:
                                     Date:  01/07/1998 09:28:54
                                                 Detector:PED-Cond.
Calibra*ioR - Volume   Dilution Points  Rate  Start   Stop Area Reject

External          1          1    3600   5Hz   0.00   5.28        1000

********************** component  Report: All Components ***********************
 Pk.    Ret Component
 Hum   Time Name
                     Concentration
        Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
    US
                      Totals
                             0.000

                             0.000
             0

             0
   0

   0
0.00
            File:  19452311. D50 Sample: 194-52-31
60

50

40

30

20

10

 0
           0
              I  I  I  \
                        Till
                        2
                                             i  i  t, r
                                                       i  i  i   r
    3
Minutes
                                                                          57

-------
                  Data Reprocessed On 01/27/1998 10:22:18
  Sample Name:  194-52-33
  Data File  :  C:\DX\DATA\44369HCL\19452331.D51
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1  Inject/: 51
  Analyst    :                Column:
                Date:  01/07/1998  09:42:40
                            Detector:PED-Cond(
Calibration-' Voiume    Dilution Points Rate  Start   Stop Area Reject

External          1           1   3600  5Hz   0.00   5.55        1000

********************** component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentrat ion
Height
Area  Bl. %Delta
     Code
       0.00  CHLORIDE
    US
                      Totals
        0.000
       • ^B ^B •» •• •» m

        0.000
     0
    m^m

     0
   0

   0
0.00
            Fife:  19452331.D51 Sample:  194-52-33
        60
        50
        40
        30
        20
         10
-_ _-
1 1 1 1 1 1 1 1 1 1 1 1
) 1 2

I I I I.I 1 1 • 1 1 1
3 4
Minutes
i i 1 i i
5

                                                                           5 *

-------
                 Data Reprocessed On 01/27/1998 10:22:59
  Sample Name:  194-52-33
Dat
f-5
Ana
  Data File  :  C:\DX\DATA\44369HCL\19452331.D52
   'ethod     :  C:\DX\METHOD\CHLORIDE.met
      Address:  1   System:  1   Inject/: 52
  Analyst    :                Column:
                Date:  01/07/1998  09:56:28
                           Detector:PED-Cond.
Calibration « Voiume   Dilution Points Rate  Start   Stop Area Reject

External          1           1   3600  5Hz   0.00   5.40        1000

********************** component Report: All Components ***********************
 Pk.     Ret  Component
 Hum   Time  Name
Concentration
                                             Height
Area  Bl. %Delta
     Code
       0.00  CHLORIDE
    US
                      Totals
        o.ooo
       • ^»«*OW^»^B«

        0.000
                                                  0
                                                  »•••

                                                  0
   0
   » •»

   0
0.00
           File: 19452331.D52 Sample: 194-52-33
        60
        50
        40
        30
        20
        10
                                                      I  I  I  I
                               2          3
                                      Minutes
                                                                          59

-------
  Sample Name: 194-52-37
                  Data Reprocessed On 01/07/1998 14:48:35
                 - " " — • ^g==ss==asr5====:==-^—————---  ——.—..——_.-_.
  Data File  : C:\DX\DATA\44369HCL\19452371.D54
  Method     : C:\DX\METHOD\CHLORIDE.met
  ACI Address: 1  System: 1  Inject#: 54
  Analyst    :                Column:
                   Date:  01/07/1998  10:24:01
                               Detector:PED-Cond
                            f
  =====
Calibration  Volume   Dilution Points Rate  Start   Stop Area Reject
	.	•r-*«i_s.-_-'tei	
External          1          1   3600  5Hz   0.00   5.25        1000

                       component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
   Concentration
Height
Area  Bl. %Delta
     Code
       1.95 CHLORIDE
                       Totals
            0.000   30711766  341655117
           •^•^^^•••••••^.^•••t^^lB^^^^^BBVW^^

            0.000   30711766  341655117
                     1  -9.46
            File: 19452371.D54 Sample: 194-52-37
         80


         60


    uS   40


         20
CHLORIDE/ 1.95
                                 2         3
                                       Minutes
                                                                         60

-------
                  Data Reprocessed On 01/07/1998  14:47:37
  Sample Name:  194-52-37
  .Data File  :  C:\DX\DATA\44369HCL\19452371.D53
   uthod     :  C:\DX\METHOD\CHLORIDE.met
   JI Address:  1  System:  1  Inject#: 53
  Analyst    :                 Column:
                     Date:  01/07/1998  10:10:14
                                Detector:PED-Cond.
Calibration — Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.56        1000

********************** Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
     Concentration
Height
Area  Bl. %Delta
     Code
       1.94 CHLORIDE
                       Totals
             0.000    30766719  341359444
            • ^m^mm* ^ ^m ^* m* ** ^m ^m ^m v» ^B ^B ^ •• WB ^B ^B ^B MB aw «» i» ^B ^B ^B

             0.000    30766719  341359444
                     1  -9.61
            File:  19452371.D53 Sample: 194-52-37
         80


         60


    uS   40


         20
CHLORIDE/ 1.94
           0
                3         4
              Minutes
                                                                       61

-------
                  Data Reprocessed On 01/07/1998  13:28:42
  Sample Name:  194-52-1 MS
  Data File  :  C:\DX\DATA\44369HCL\19452011.D55
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  55
  Analyst    :                 Column:
                Date:  01/07/1998 10:37:48
                            Detector: PED-Cond .1
Calibra*io» - Vo4*ime   Dilution Points Rate  Start   Stop Area  Reject

External          1          2   3600  5Hz   0.00   5.15         1000

********************** component Report:  All Components ***********************
 Pk.     Ret Component
 Nura   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.94 CHLORIDE
    US
                       Totals
        0.000   36739984   383161337
       • ^m^m^^m ^ ^ •» ^ ^m^m •• ^B ^ ^m ^MBW ^B^M ^» •» •» ^»^» «^ •» ^B •••

        0.000   36739984   383161337
                        -9.77
            File: 19452011.D55 Sample: 194-52-1 MS
         40
         30
         20
         10
          0
                           CHLORIDE/  1.94
              I  I  T
                                 2          3
                                       Minutes
                                                                        62

-------
                  Data Reprocessed On 01/07/1998  13:30:25
  Sample Name:  194-52-1 MS
Data File  :  C:\DX\DATA\44369HCL\19452011.D56
  ithod     :  C:\DX\METHOD\CHLORIDE.met
 CI Address:  1  System:  1  Inject#: 56
Analyst    :                 Column:
                                            Date:  01/07/1998  10:51:34
                                                         Detector:PED-Cond.
Calibra*i<»•- Voitune   Dilution Points Rate  Start    Stop Area Reject

External          1          2   3600  5Hz   0.00    5.20        1000

                       component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.94 CHLORIDE
    US
                       Totals
                                    0.000    36745958  389413634

                                    0.000    36745958  389413634
                        -9.77
            File: 19452011.D56 Sample: 194-52-1 MS
         40
         30
         20
         10
          0
                          CHLORIDE/  1.94
^
III! I 1 1 1 1 I I 	
) 1 2

' I I I I I I. I | T ~T 	 1 	
3 4
Minutes
i i
5

                                                                          63

-------
                  Data Reprocessed On 01/07/1998 13:31:58
  Sample Name:  194-52-1 MSD
  Data File  :  C:\DX\DATA\44369HCL\19452011.D57
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  57
  Analyst    :                 Column:
                              Date:  01/07/1998 11:05:18
                                          Detector:PED-Conc
Calibra*ioR - Volume   Dilution  Points Rate  Start   Stop Area Reject

External          1           2    3600  5Hz    0.00   5.38        1000

                       component Report: All  Components ***********************
 Pk.     Ret Component
 Num   Time Name
              Concentration
Height
Area  Bl. %Delta
     Code
       1.94  CHLORIDE
    US
                      Totals
                      0.000   36520618   381923021
                      » •• ^^» ^ ^ ^B«B ^ •» ^«H» ^ ^ ^ ^»^» •» •» •• «• ^B ^m «•• •• • ^K

                      0.000   36520618   381923021
                     1  -9.77
            File:  19452011.D57 Sample: 194-52-1 MSD
        40
        30
        20
         10
                          CHLORIDE/  1.94
i  i  i    r
      1
                                  i  i  i  i   . i
                                2         3
                                       Minutes

-------
                   Data Reprocessed On 01/07/1998 13:32:43
fi
Sample Name: 194-52-1 MSD
Data File  : C:\DX\DATA\44369HCL\19452011.D58
 lethod     : C:\DX\METHOD\CHLORIDE.met
FACI Address: l  System: 1  Inject#: 58
Analyst    :                Column:
Date: 01/07/1998 11:19:05
            Detector:PED-Cond.
 CalibraVi»» -Voinme   Dilution Points Rate  Start   Stop Area Reject

 External          1          2   3600  5Hz   0.00   5.38        1000

 ********************** component Report: All Components ***********************
  Pk.     Ret Component
  Num   Time Name
                            Concentration
  Height
Area  Bl. %Delta
     Code
        1.94  CHLORIDE
                        Totals
                                    0.000   36414745   380275538
                                   • ^^m^m^m^m^m ^ flv ^m ^m ^m ^m ^•^••B ^m^m ^m ^» ^m ^m ^»^»«» ••«» ^m

                                    0.000   36414745   380275538
                       1  -9.92
     US
             File:  19452011.D58 Sample: 194-52-1 MSD
         40
          30
          20
          10
                           CHLORIDE/  1.94
                 1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	T	1	1	1	1	1	1	T
                       1          2         3       ' 4          5
                                        Minutes

-------
TRIANGLE LABOI^^KS INC.
^^Br
TLW 44369-CL2
CLIENT SAMPLES
EASTERN RESEARCH GROUP
OS-JANUARY/98
TU ID

194-52-2

194-52-4

194-52-6

194-52-9

194-52-10

194-52-11

194-52-13

194-52-15

194-52-17

194-52-19

194-52-21

194-52-23

194-52-25

194-52-27

194-52-30

194-52-32

194-52-34


CLIENT ID

CAA-04

CAA46

CAA-12

CAA-20

*fcAA^)£rWd
	 iJcl
f\0> *-<
CAA-24 '

CAA-28

CAA-32

CAA-36

CAA-40

CAA-52

CAA-56

CAA-60

CAA-64

CAA-96

CAA-100

f CAA-104


RT

1.92
1.90
169
1.69
1.89
1.89
191
1.89
189
1.89
L
1.89
188
1.68
1.89
1.89
1.89
1.88
1.88
1.90
1.68
1.90
189
1.89
1.87
1.87
188
1.88
ND
ND
ND
ND
ND
ND

AREA

783026
759183
693189
706781
569062
566901
656131
616935
290303658
290051032
1190651
1176658
2409554
2369122
5317500
5343789
23515386
23284724
2276446
2210849
3633374
3644451
166547469
166642253
1148613
1146965
5713691
5746518
ND
ND
ND
ND
ND
ND

LOO AREA

.
—
_
—
_
—
_
—
8.46
8.46
_
—
_
—
6.73
6.73
7.37
7.37
__
— •
656
6.56
8.22
8.22
_
—
6.78
6.76
ND
ND
ND
ND
ND
ND

RUN CONC
pptn

-------
tpiANoic LABORATORIES INC.


TLW 44369-CL2
CLIENT SAMPLES
EASTERN RESEARCH GROUP
09-JANUARY/98
                                                                                                                                                                 CD
TU ID
194-52-35
194-52-38
194-52-38
194-52-39
194-52-2 MS
194-52-2 MSO
MATRIX SPIKE
SAMPLE ID
194-52-2 MS
194-52-2 MSO
CLIENT ID
CAA-231
CAA-232
CAA-16
CAA-76
CAA-04
CAA-04


CAA-04
CAA-04
RT
NO
NO
NO
NO
1.87
1.89
NO
NO
1.83
1.85
185
1.85

NATIVE AMT.
CL (mg)
<0.034
<0.034
AREA
NO
NO
NO
NO
648634
695257
NO
NO
330222786
332045428
330095822
330182583

MS AMT.
CL (mg)
5.10
5.08
LOO AREA
NO
NO
NO
NO
_
NO
NO
852
8.52
852
8.52

AMT.
SPIKE (mg)
34
3.4
RUN CONG
ppm
NO
NO
NO
NO
:i
NO
NO
74.78
75.14
74.75
74.78

DF
2
2
DILUTION SAMPLE CONG
FACTOR ppm
1 <1
1 <1
1 <1
1 <1
1 <1
1 <1
1 <1
1 <1
2 14955
2 15028
2 14950
2 149.53

%RECOVERV
150
149
AVOCONC RPD TOTAL
ppm mL
<1 NA 37
<1 NA 40
<1 NA 35
<1 NA 35
149.92 0.5 34
149.52 0.0 34

H

TOTAL mg
Cl
<0.037
<0.040
<0.03S
<0.035
5.10
5.08

TOTAL mg
CLZ
<0.037
<0040
<0.035
<0.035
5.10
5.08

" 1
7
7
13
8
7
7

«itecovtMY4(Ms MOT. • NATIVE AMTK "txc nur.n x 100
TOTAL mo HCL: (TOTAL mg CL)(FWHCUMWCL)
TOTAL mg CL2:  TOTAL mg  CL x 1
NO- NOT DETECT
TLI44369-CL2

-------
                  Data  Reprocessed On 01/12/1998  17:34:35
  Sample Name:  194-52-2
  Data File  :  C:\DX\DATA\44369CL2\19452021.D19
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1  Inject#:  19
  Analyst    :                 Column:
                                     Date:  01/09/1998 03:41:13
                                                 Detector:PED-Cond.
Calibration - Volume    Dilution Points Rate  Start   Stop Area Reject

External          1           1   3600   5Hz   0.00   5.75        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                     Concentration
Height
  Area  Bl. %Delta
       Code
       1.92  CHLORIDE
    US
                       Totals
                             0.000
                            • ••^•VMW^B*

                             0.000
 194252
• ^^ ••^••B^ •

 194252
783026

783026
1 -10.85
            File:  19452021.D19 Sample: 194-52-2
12


10

 8

 6

 4


 2

 0
                        CHLORIDE/ 1.92
                                        3
                                       Minutes
                                                                          68

-------
                  Data Reprocessed On 01/12/1998  17:40:48
  Sample Name:  194-52-2
 fcata File  :  C:\DX\DATA\44369CL2\19452021.D20
           :  C:\DX\METHOD\CHLORIDE.met
    Address:  1  System:  1  Inject#:  20
Analyst    :                 Column:
                                            Date:  01/09/1998  03:54:57
                                                         Detector:PED-Cond.
Calibration -Volume   Dilution Points Rate   Start   Stop Area Reject
External          1          1   3600  5Hz   0.00   5.34        1000
********************** component Report: All Components ***********************
        Ret Component
       Time Name
                            Concentration
Height
  Area  Bl. %Delta
       Code
       1.90 CHLORIDE
    US
                       Totals
                                    0.000
                                    0.000
 194373
• ^» ^» ^» ^B ^» ••• •
 194373
759183
759183
1 -11.78
            File:  19452021.D20 Sample: 194-52-2
       16
       14
       12
       10
        8
        6
        4
        2
        0
       -2
                         CHLORIDE/  1.90
              \  i  i  r
                                          3
                                       Minutes
                                                                          69

-------
                  Data Reprocessed On 01/12/1998 17:43:06
  Sample Name:  194-52-4
  Data File  :  C:\DX\DATA\44369CL2\19452041.D21
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  21
  Analyst    :                 Column:
                Date: 01/09/1998 04:08:42
                            Detector:PED-Cond.
Calibra*i«a ~Voi*me   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.43        1000

                       Component Report:  All Components  ***********************
 Pk.    Ret Component
 Hum   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
1 1.89


16
14
12
10
8
uS 6
4
2
n
. . \J
.2
4»
c

CHLORIDE 0.000 167393 693189 1 -11.94
Totals 0.000 167393 693189
File: 1 9452041. D21 Sample: 194-52-4







A CHLORIDE/ 1.89
/U-LJV

i i i i i i i i i i i i i * i i i ,i i. i i i i i i i i
) 1 2 3 4 5
Minutes

-------
                  Data Reprocessed On 01/12/1998  17:44:55
  Sample Name:  194-52-4
 Data File   : C:\DX\DATA\44369CL2\19452041.D22
Tethod      : C:\DX\METHOD\CHLORIDE.met
 .CI Address: 1  System: 1  Inject#: 22
 Analyst     :                Column:
                                            Date: 01/09/1998 04:22:27
                                                         Detector:PED-Cond.
Calibration. .„ Volume   Dilution  Points  Rate   Start   Stop Area Reject

External          1          1    3600   5Hz    0.00   5.47        1000

********************** Component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
  Area  Bl. %Delta
       Code
       1.89  CHLORIDE
                       Totals
                                    0.000

                                    0.000
 165797
• «• ^ ^* *m «• ^B •

 165797
706781

706781
1 -11.94
            Fife:  19452041.D22 Sample: 794-52-4
         8
     uS   4

1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 II 1 1
) 1 2 3 4
Minutes
i i I i i
5


-------
                  Data Reprocessed On 01/12/1998  17:47:26
  Sample Name:  194-52-6
  Data File  :  C:\DX\DATA\44369CL2\19452061.D23
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject#:  23
  Analyst    :                 Column:
                Date: 01/09/1998 04:36:13
                            Detector:PED-Cond.
                            I
Calibration. -Voiume   Dilution Points Rate   Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.43        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
   Area  Bl.  %Delta
        Code
       1.89 CHLORIDE
                       Totals
        0.000

        0.000
 138618
• ^m ^» ••» ^v «*OB»«

 138618
 569062
• «• ^v •••BOV^M

 569062
1 -11.94
            File:  19452061.D23 Sample: 194-52-6
          8
     uS  4


         2


         0
                                  i  r  i
                                        i    i  i  i  r   i
                                          3        ' 4
                                       Minutes
                                                             i    i

-------
                  Data Reprocessed On 01/13/1998 12:54:45
  Sample Name:  194-52-6
                                            Date: 01/09/1998 04:49:59
 )ata  File   : C:\DX\DATA\44369CL2\19452061.D24
  ethod      : C:\DX\METHOD\CHLORIDE.met
"ACI Address: 1  System: 1   Inject#: 24
 Analyst     :                Column:
                                                         Detector:PED-Cond.
Calibration - Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.70        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
  Area  Bl.  %Delta
       Code
       1.89  CHLORIDE
                       Totals
                                    0.000

                                    0.000
 139271
• ••^ ^m^m ^ ^B •

 139271
566901

566901
1 -12.09
            File:  19452061.D24 Sample: 194-52-6
          8
     uS   4
          0
              i i  i  r
                                           i  i i  i
                                                          ill
                                        3
                                       Minutes
                                                                           73

-------
                  Data  Reprocessed On 01/13/1998 12:57:55
  Sample Name:  194-52-9
                Date:  01/09/1998  05:03:45
  Data File  :  C:\DX\DATA\44369CL2\19452091.D25
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject#:  25
  Analyst    :                 Column:
                            Detector:PED-Cond.
                                              I
Calibration -.VoJrttrae   Dilution Points  Rate  Start   Stop Area Reject

External          1          2   3600   5Hz   0.00   5.61        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
  Area  Bl. %Delta
       Code
       1.91 CHLORIDE
     uS
                       Totals
        0.000

        0.000
171129

171129
656131

656131
1 -11.01
            File: 19452091.D25 Sample: 194-52-9
          8


          6
                                         3         4
                                       Minutes
                                                                       74

-------
                  Data  Reprocessed On 01/13/1998 13:06:20
  Sample Name:  194-52-9
Data File  :  C:\DX\DATA\44369CL2\19452091.D26
'fethod     :  C:\DX\METHOD\CHLORIDE.met
 »CI Address:  1  System: 1  Inject#: 26
Analyst    :                 Column:
                                            Date:  01/09/1998  05:17:30
                                                         Detector:PED-Cond.
Calibrafcioo... VcOume    Dilution  Points  Rate  Start   Stop Area Reject

External          1           2    3600   5Hz   0.00   5.25        1000

                       component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
  Area  Bl. %Delta
       Code
       1.89 CHLORIDE
     uS
                      Totals
                                    0.000
                                   • ••^•••B ^ ^ 1

                                    0.000
 158443
• «v^»«» •• ^m^m i

 158443
616935

616935
1 -12.09
            File:  19452091.D26 Sample: 194-52-9
          8


          6
           0
                I  I  I
                                                        I  T  I  i
                              2          3
                                     Minutes
                                                                            75

-------
                  Data Reprocessed On 01/10/1998  16:34:52
  Sample Name:  194-52-10
  Data File  :  C:\DX\DATA\44369CL2\19452101.D27
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  27
  Analyst    :                 Column:
                Date: 01/09/1998 05:31:15
                            Detector:PED-Cond
                                              1
Calibration..,-Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          2   3600  5Hz   0.00   5.43        1000

                       Component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       1.89 CHLORIDE
                       Totals
        0.000   52590852   290303658

        0.000   52590852   290303658
                     1 -12.25
            File:  19452101.D27 Sample: 194-52-10
        100
    uS
         0
                         CHLORIDE/ 1.89
                i  i  i
                                    I  I  F    I  I  I  [    1  I
                                                          (111
                                2          3
                                       Minutes
                                                                            76

-------
                  Data Reprocessed On 01/10/1998  16:36:01
  Sample Name:  194-52-10
     File  :  C:\DX\DATA\44369CL2\19452101.D28
           :  C:\DX\METHOD\CHLORIDE.met
    Address:  1  System:  1  Inject/: 28
Analyst    :                 Column:
                                            Date:  01/09/1998 05:45:00
                                                          Detector:PED-Cond.
Calibration. , .Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          2   3600  5Hz   0.00   5.66         1000

********************** component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.89 CHLORIDE
                       Totals
                                    0.000   52271810   290051032
                                   • ^» ^» ^» ^» ^» ^» ^» ^» ^» •• ^» ^m ••••» ^* ^» ^B «« ^m ^B ^B ••••••• ^* ^v «•

                                    0.000   52271810   290051032
                     1 -12.09
            File: 19452101.D28 Sample: 194-52-10
        100
    uS
          0
                        CHLORIDE/  1.89

1 i 1 1 1 1 1 1 1 1 1
) 1 2

1 1 1 1 1 1
3
Minutes
i .) i i i i 1 i
4 5

1


                                                                              7'

-------
                  Data  Reprocessed On 01/13/1998 13:08:32
  Sample Name:  194-52-11
  Data File  :  C:\DX\DATA\44369CL2\19452111.D29
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  29
  Analyst    :                 Column:
                Date:  01/09/1998  05:58:46
                            Detector:PED-Cond.
Calibration. .„ Volume   Dilution  Points Rate  Start   Stop Area Reject

External          1           1    3600  5Hz   0.00   5.75        1000

                       Component  Report: All Components ***********************
 Pk.     Ret  Component
 Num   Time  Name
Concentration
Height
   Area  Bl. %Delta
        Code
       1.90  CHLORIDE
                      Totals
        0.000

        0.000
310659

310659
1190651

1190651
1 -11.78
           File: 19452111.D29 Sample:  194-52-11
    uS
                                       Minutes
                                                                           78

-------
                  Data Reprocessed On 01/13/1998 13:09:42
 I  S
ti
Sample Name: 194-52-11
 ata File  : C:\DX\DATA\44369CL2\19452111.D30
 ethod     : C:\DX\METHOD\CHLORIDE.met
    Address: 1  System: 1  Inject#: 30
Analyst    :                Column:
Date: 01/09/1998 06:12:32
                                                          Detector:PED-Cond.
 Calibration...,.Volume   Dilution Points Rate   Start   Stop Area Reject
 External           1           1   3600  5Hz    0.00   5.38        1000
 ********************** component  Report:  All Components ***********************
  Pk.    Ret  Component
  Num   Time  Name
                            Concentration
  Height
   Area  Bl. %Delta
        Code
        1.89  CHLORIDE
                       Totals
                                    0.000
                                    • ^•^ tfm^^mm
                                    0.000
  286453
 • ^ «• «• ^m ^«» 4
  286453
1176658
1176658
1 -12.09
            File: 19452111.D30 Sample: 194-52-11
     uS
      9.0
      8.0
      7.0
      6.0
      5.0
      4.0
      3.0
      2.0
      1.0
      0.0
      -1.0
                 i  i  i
                         r  i  i
                               I
                              2
                                           i
                                           3
                                             i   \ r
                                        Minutes
                                                                            79

-------
                  Data Reprocessed On 01/13/1998  13:11:37
  Sample Name:  194-52-13
  Data File  :  C:\DX\DATA\44369CL2\19452131.D31
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  31
  Analyst    :                 Column:
                                             Date:  01/09/1998  06:26:17
                                                        Detector:PED-Cond.
Calibration••- Vo4«me   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.38         1000

********************** Component Report:  All Components ***********************

                              Concentration    Height
Pk.    Ret Component
Num   Time Name
             Area  Bl. %Delta
                  Code
       1.88 CHLORIDE
                       Totals
                                     0.000

                                     0.000
561012

561012
2409554

2409554
1 -12.56
            File: 19452131.D31 Sample: 194-52-13
          8


          6
     US
                         CHLORIDE/ 1.88
              I  I  I  I
                                  till
                                2         3
                                       Minutes

-------
                  Data Reprocessed On 01/13/1998 13:13:12
  Sample Name: 194-52-13
    Kta File  :  C:\DX\DATA\44369CL2\19452131.D32
    thod     :  C:\DX\METHOD\CHLORIDE.met
   _I Address:  1  System: 1  Inject#: 32
  Analyst    :                 Column:
                Date: 01/09/1998 06:40:03
                            Detector:PED-Cond.
Calibration..-Vojjtune   Dilution Points Rate  Start   Stop Area Reject
M—-^^^ —— — -,	r -•	m -n	1— TW —i	— — — •^••••»«»^»^»»^»»»» —^^•••••^••^^•^^••^••••^^^^^^^•^
External          1          1   3600  5Hz   0.00   5.47        1000

                       component Report: All Components ***********************
 Pk.    Ret Component
 Mum   Time Name
Concentration
Height
   Area  Bl. %Delta
        Code
       1.88 CHLORIDE
                       Totals
        0.000

        0.000
550513

550513
2369122

2369122
1 -12.56
     US
            Fife: 19452131.D32 Sample: 194-52-13
          8
                         CHLORIDE/ 1.88
                               I
             n—i—i—i—i—i—i—i—i—|—i—i—r~i—i—i—i—i—r—i—i—i—i—i—|  r
           0          1          2         3        ' 4          5
                                       Minutes
                                                                            81

-------
                  Data Reprocessed On 01/13/1998  13:18:19
  Sample Name:  194-52-15
                                     Date: 01/09/1998 06:53:49
  Data File  :  C:\DX\DATA\44369CL2\19452151.D33
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  33
  Analyst    :                 Column:
                                                 Detector:PED-Cond.
Calibration.-, VoJ.wme   Dilution Points Rate  Start    Stop Area Reject

External          1          1   3600  5Hz   0.00    5.61         1000

********************** Component Report:  All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
                     Concentration
                       Height
   Area  Bl. %Delta
        Code
       1.89 CHLORIDE
                       Totals
                             0.000
                            • •••W^^V^V

                             0.000
                      1161226
                      m^m^m^m ^ ^^ ^ •

                      1161226
5317500

5317500
1 -12.09
    uS
            File:  19452151.D33 Sample: 194-52-15
12

10

 8

 6

 4

 2

 0

-2

-4
CHLORIDE/ 1.89
                iIIr iiiriiiiiiii.ii.il
                     12         3         4         5
                                       Minutes
                                                                          82

-------
                  Data Reprocessed On 01/13/1998 13:28:11
 Sample Name: 194-52-15
 Data  File   : C:\DX\DATA\44369CL2\19452151.D34
Yethod      : C:\DX\METHOD\CHLORIDE.met
  :i Address: 1  System:  1   Inject#:  34
 Analyst     :                 Column:
                                              Date:  01/09/1998 07:07:35
                                                          Detector:PED-Cond.
Calibra.fcifin-.-VoJ.wme   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.43        1000

********************** component Report:  All Components ***********************
 Pk.    Ret Component
 Hum   Time Name
                             Concentration
 Height
   Area  Bl. %Delta
        Code
       1.89 CHLORIDE
                       Totals
                                     0.000
                                    • •^«» •») ••>•

                                     0.000
 1164815
• ^» ^B ^» •• ^» •»«•»«

 1164815
5343789

5343789
1 -12.09
            File: 19452151.D34 Sample: 194-52-15
        8


        6


   uS   4


        2


        0
           0
                         CHLORIDE/  1.89
                                         3
                                      Minutes
                                                                            83

-------
                  Data Reprocessed tin 01/13/1998 13:29:42
                              =====
  Sample Name:  194-52-17
  Data File  :  C:\DX\DATA\44369CL2\19452171.D35
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject#:  35
  Analyst    :                 Column:
                                     Date:  01/09/1998  07:21:22
                                                 Detector:PED-Cond.
Calibration ~ Volume   Dilution Points  Rate  Start   Stop Area Reject
External          1          1   3600   5Hz   0.00   5.52        1000
********************** Component  Report: All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
                     Concentration
                       Height
    Area   Bl.  %Delta
          Code
       1.89 CHLORIDE
    US
                       Totals
                             0.000
                            m^m ^ <•• ^m^m*
                             0.000
                      4594783
                      4594783
 23515386
»^»^v«i» ^ ^m ^m ^4*
 23515386
1 -11.94
            File: 19452171.D35 Sample: 194-52-17
18
16
14
12
10
 8
 6
 4
 2
 0
-2
           0
CHLORIDE/ 1.89
              I  I  I
                        I  I  I
                               '  I  '
                                 3
                              Minutes
                                                                         84

-------
                  Data Reprocessed On 01/13/1998  13:31:51
  Sample Name:  194-52-17
 Data  File   :  C:\DX\DATA\44369CL2\19452171.D36
^Method      :  C:\DX\METHOD\CHLORIDE.met
 .\CI Address:  1  System: 1  Inject#:  36
 Analyst     :                Column:
                                            Date: 01/09/1998 07:35:07
                                                         Detector:PED-Cond.
Calibration ,-VoJ.ume   Dilution Points Rate  Start   Stop Area Reject
External          1          1   3600  5Hz   0.00   5.70         1000
********************** component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
                        Height
Area  Bl. %Delta
     Code
       1.88 CHLORIDE
    US
                       Totals
                                    0.000    4566748   23284724
                                    • W«_«_*»H.V«M..V«»_^^W»^^flB4B^_^
                                    0.000    4566748   23284724
                                             1 -12.71
            File: 19452171.D36 Sample: 194-52-17
       16
       14
       12
       10
        8
        6
        4
        2
        0
       -2
CHLORIDE/ 1.88
              I I  I  I
                                           ill!
                                                    I  I  I  I
                                                              I  I  t
                                        3
                                       Minutes
                                                                          85

-------
                  Data  Reprocessed On 01/13/1998  13:35:31
  Sample Name:  194-52-19
                Date:  01/09/1998 07:48:52
  Data File  :  C:\DX\DATA\44369CL2\19452191.D37
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  37
  Analyst    :                 Column:
                            Detector:PED-Cond. I
Calibration - Vodume    Dilution Points Rate   Start   Stop Area Reject

External          1           1   3600  5Hz    0.00   5.29         1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
   Area  Bl.  %Delta
         Code
       1.88  CHLORIDE
                       Totals
        0.000

        0.000
 548183
• ^«*«v«»^ ^mm

 548183
 2278446
• ••» ^ ^B^» •» •"• ^»

 2278446
1 -12.40
     US
            File:  19452191.D37 Sample: 194-52-19
          8
                         CHLORIDE/  1.88
                               I
                                           3
                                       Minutes

-------
                  Data Reprocessed On 01/13/1998 13:34:23
  Sample Name:  194-52-19
     File  :  C:\DX\DATA\44369CL2\19452191.D38
           :  C:\DX\METHOD\CHLORIDE.met
 JI Address:  1  System: 1  Inject#: 38
Analyst    :                 Column:
                                            Date:  01/09/1998 08:02:39
                                                          Detector:PED-Cond.
Calibration-- Vevlwme   Dilution Points Rate  Start   Stop Area  Reject

External          1          1   3600  5Hz   0.00   5.43         1000

********************** component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
   Area  Bl. %Delta
        Code
       1.90 CHLORIDE
                       Totals
                                    0.000

                                    0.000
543800

543800
2210849

2210849
                                                                     1 -11.47
            File:  19452191.D38 Sample: 194-52-19
         8
     uS   4


         2
                       CHLORIDE/ 1.90
               iii|iiii[iiii[iii[|iiii|ir
                     1          2345
                                       Minutes
                                                                          87

-------
                  Data Reprocessed On 01/13/1998  13:37:18
  Sample Name:  194-52-21
  Data File  :  C:\DX\DATA\44369CL2\19452211.D39
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject#:  39
  Analyst    :                 Column:
                     Date: 01/09/1998 08:16:25
                                 Detector:PED-Cond
                                                   I
Calibration — Voinme   Dilution  Points  Rate   Start   Stop Area Reject

External          1          1    3600   5Hz    0.00   5.56        1000

                       Component  Report: All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
     Concentration
Height
   Area   Bl.  %Delta
         Code
       1.88 CHLORIDE
                       Totals
             0.000

             0.000
 792388
• *»«B«»^^»^fl

 792388
 3633374
• ^m •» «• ^•^»M»«M

 3633374
1 -12.71
            File: 19452211.D39 Sample: 194-52-21
          8
     uS   4


          2
CHLORIDE/ 1.88
                       I  i  i  i
                                         3         4
                                       Minutes
                                                                           88

-------
                   Data Reprocessed On  01/13/1998 13:38:35
4
Sample Name:  194-52-21
Data File  :  C:\DX\DATA\44369CL2\19452211.D40
Method     :  C:\DX\METHOD\CHLORIDE.met
id Address:  1  System:  1  Inject#:  40
Analyst    :                 Column:
Date: 01/09/1998 08:30:10
            Detector:PED-Cond.
  Calibra*ie»•- Vo4«me   Dilution Points Rate  Start   Stop Area Reject

  External          1          1    3600  5Hz   0.00   5.61        1000

  ********************** Component  Report: All Components ***********************
   Pk.     Ret Component
   Num   Time Name
                            Concentration
  Height
   Area  Bl. %Delta
        Code
         1.90 CHLORIDE
                        Totals
                                    0.000

                                    0.000
  788184
 • mm ^^B^ •» ^ •

  788184
3644451

3644451
1 -11.78
             File: 19452211. D40 Sample: 194-52-21
           8


           6


       US   4


           2
                       CHLORIDE/  1.90
                                           3
                                         Minutes
                                                                            89

-------
                 Data Reprocessed On  01/10/1998 17:09:11
 Sample Name:  194-52-23
 Data File  :  C:\DX\DATA\44369CL2\19452231.D41
 Method     :  C:\DX\METHOD\CHLORIDE.met
 ACI Address:  1  System:  1  Inject?:  41
 Analyst    :                 Column:
                                             Date: 01/09/1998 08:43:56
                                                         Detector:PED-Cond.
External
            Vo4«me   Dilution Points Rate  Start   Stop Area Reject

                 1          1   3600  5Hz   0.00   5.43        1000

                      Component  Report: All Components ***********************
Pk.    Ret Component
Num   Time Name
                              Concentration
Height
Area  Bl. %Delta
     Code
      1.89 CHLORIDE
                      Totals
                                     0.000   34737558  166547469
                                     • l»»«WPM>*»>^»^»^M«a»«»>^B^B^ •• (•» ^B> ^» •• ^» ^» ^B ^B ^» •• ^» •• •*

                                     0.000   34737558  166547469
                     1 -12.09
           File: 19452231.D41 Sample:  194-52-23
        80
60
uS 40
20
0
C

CHLORID

E/ 1.89


1 1 1 1 1 1 1 1 1 I 1 1 1 1 I 1 1 1 1 I I ! 1 1 I 1 1
) 1 2 3 4 5
Minutes
                                                                          90

-------
                  Data Reprocessed On 01/10/1998 17:10:33
  S,

I
  A:
  Sample Name: 194-52-23
   ata File  :  C:\DX\DATA\44369CL2\19452231.D42
             :  C:\DX\METHOD\CHLORIDE.met
      Address:  1  System: 1  Inject#: 42
  Analyst    :                 Column:
Date: 01/09/1998 08:57:42
            Detector:PED-Cond.
External
             Voitune   Dilution Points Rate  Start   Stop Area Reject

                  1          1   3600  5Hz   0.00   5.34        1000

                       Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                              Concentration
  Height
Area  Bl. %Delta
     Code
       1.89 CHLORIDE
                       Totals
                                      0.000   34738893  166842253
                                      • «• «• *• — ^ ^ — • «P • • »••»••» ^ •••« ^ ^ ^ •• ^ ^ •»••

                                      0.000   34738893  166842253
                       1 -12.09
              7e; 19452231.D42 Sample: 194-52-23
         80
         60
     uS   40
         20
                          CHLORIDE/ 1.89
                i  i  i     i  i  i
                                     i  i  i    i   i  r
                                                        i  i  i  r    T
                                 2          3
                                        Minutes
                                                                             91

-------
                  Data Reprocessed On 01/13/1998  13:40:56
  Sample Name:  194-52-25
  Data File  :  C:\DX\DATA\44369CL2\19452251.D43
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  43
  Analyst    :                 Column:
                     Date:  01/09/1998  09:11:30
                                 Detector:PED-Cond.
Calibration-..-..Volume   Dilution Points Rate  Start    Stop Area Reject

External          1          1   3600  5Hz   0.00    5.38         1000

                       Component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
     Concentration
Height
   Area   Bl.  %Delta
         Code
       1.87  CHLORIDE
                       Totals
             0.000

             0.000
 270936
• ^ ^ ^^ ^m^m

 270936
 1148613
m ™» •••«»•» ^ ^m ^m

 1148613
1 -12.87
            File:  19452251.D43 Sample: 194-52-25
          8
     uS   4


         2
CHLORIDE/ 1.87
             I   I  I  1
                                            III ,1

                                          3
                                       Minutes
                                                                           92

-------
                  Data Reprocessed On 01/13/1998  13:42:44
  Sample Name:  194-52-25
 )ata File  :  C:\DX\DATA\44369CL2\19452251.D44
           :  C:\DX\METHOD\CHLORIDE.met
 'JI Address:  1  System:  1  Inject#:  44
Analyst    :                 Column:
                                            Date:  01/09/1998  09:25:16
                                                         Detector:PED-Cond.
Calibration - Volume   Dilution Points Rate   Start   Stop Area Reject

External          1          1   3600  5Hz    0.00   5.61        1000

********************** Component Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
   Area   Bl.  %Delta
         Code
       1.87  CHLORIDE
                       Totals
                                    0.000

                                    0.000
268693

268693
 1146965
• «••«• <•• MM M» «» M»

 1146965
1 -12.87
            Fife:  19452251.D44 Sample: 194-52-25
          8
     uS  4
                        CHLORIDE/ 1.87
                 i  i  i  i  i
                             1  I
                               2
                                       3
                                     Minutes
                                                                           93

-------
                  Data  Reprocessed On 01/13/1998  13:45:04
  Sample Name:  194-52-27
  Data File  :  C:\DX\DATA\44369CL2\19452271.D45
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  45
  Analyst    :                 Column:
                     Date: 01/09/1998 09:39:03
                                 Detector:PED-Cond.
                                                                            i
Calibra*iea - Vo4«me    Dilution  Points  Rate   Start   Stop Area Reject

External          1           1    3600   5Hz    0.00   5.52        1000

                       component  Report: All Components ***********************
 PJc.    Ret Component
 Num   Time Name
     Concentration
 Height
   Area  Bl. %Delta
        Code
       1.88  CHLORIDE
                       Totals
             0.000
             • ^ ^ ^ MB^«

             0.000
 1215165
• •• <•» •• ^^m^m^m*

 1215165
5713691

5713691
1 -12.71
            File:  19452271.D45 Sample: 194-52-27
          8
     uS  4


         2
CHLORIDE/ 1.88

1
D
1 ' ' 1
1
I I I I I I
2
3
I 1 t . 1 t 1 1
4
1 1
5
1 f
                                       Minutes
                                                                           94

-------
                  Data Reprocessed On 01/13/1998  13:46:07
 Sample Name: 194-52-27
kData  File   : C:\DX\DATA\44369CL2\19452271.D46
  ethod      : C:\DX\METHOD\CHLORIDE.met
 iCI Address: 1  System: 1  Inject/: 46
Analyst     :                Column:
                                              Date: 01/09/1998 09:52:48
                                                         Detector:PED-Cond.
Calibration•- Volume   Dilution Points Rate  start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.43        1000

********************** Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
 Height
   Area  Bl. %Delta
        Code
       1.88 CHLORIDE
                       Totals
                                    0.000

                                    0.000
 1224925
• ^ ^ V»M»^^^«

 1224925
5746518

5746518
1 -12.71
            File: 19452271.D46 Sample: 194-52-27
          8
     uS   4


          2


          0
                       CHLORIDE/  1.88
                                2         3
                                       Minutes
                                                                            95

-------
                  Data Reprocessed On 01/10/1998  17:17:51
  Sample Name:  194-52-30
  Data File  :  C:\DX\DATA\44369CL2\19452301.D47
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject*:  47
  Analyst    :                 Column:
                Date:  01/09/1998 10:06:33
                            Detector:PED-Cond,
                                               — ..,.. „, .. „__-- __..-
Calibration-~ Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.28         1000

********************** Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
                       Totals
        0.000

        0.000
     0
    »^»«

     0
   0

   0
0.00
    uS
            File:  19452301.D47 Sample: 194-52-30
         30
         20
         10
              i  i  i  i
                              '   I  '  '  '  '  I
                                2          3
                                       Minutes

-------
                  Data Reprocessed On 01/10/1998  17:18:51
  Sample Name:  194-52-30
 Data File   : C:\DX\DATA\44369CL2\19452301.D48
"jsthod      : C:\DX\METHOD\CHLORIDE.met
 Jci Address: 1  System: 1  Inject#: 48
 Analyst     :                Column:
                                            Date: 01/09/1998 10:20:20
                                                         Detector:PED-Cond.
Calibra*i««---Volame   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.46        1000

                       Component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
    US
                       Totals
                                    0.000
                                    • ^^mi^^m^mm

                                    0.000
     0
    • «»•

     0
   0
   • •V

   0
0.00
            File: 19452301. D48 Sample: 194-52-30
        30
        20
         10
'^^--
I I I 1 I I
D 1

I t I I I I
2

I 1 I 1 I I !• I I I I I I 1 I
345
Minutes
                                                                            97

-------
                  Data Reprocessed On 01/10/1998 17:20:37
  Sample Name:  194-52-32
  Data File  :  C:\DX\DATA\44369CL2\19452321.D49
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  49
  Analyst    :                 Column:
                                     Date:  01/09/1998  10:34:05
                                                 Detector:PED-Cond
Calibration-- Valume    Dilution  Points  Rate  Start   Stop Area Reject
External          1           1    3600   5Hz   0.00   5.43        1000
********************** Component  Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                     Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
    uS
                       Totals
                             0.000
                            • ^^»^»WM*
                             0.000
     0
    • •»«
     0
   0
   0
0.00
            File:  19452321.D49 Sample: 194-52-32
18
16
14
12
10
 8
 6
 4
 2
 0
-2
                i  i  r
                                        1  I  '
                                          3
                                       Minutes
                                                          I   I    I  I
                                                                           8.8

-------
                  Data Reprocessed On 01/10/1998 17:21:37
  Sample Name:  194-52-32
  Data File  :  C:\DX\DATA\44369CL2\19452321.D50
  'lethod     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  50
  Analyst    :                 Column:
                                     Date:  01/09/1998 10:47:51
                                                 Detector:PED-Cond.
Calibration•- Vcrlnme   Dilution Points Rate  Start   Stop Area Reject
External          1          1   3600   5Hz   0.00   5.76        1000
                       Component  Report: All Components ***********************
Pk.
Num
0

Ret Component
Time Name
0.00 CHLORIDE

Concentration
0.000
Totals 0.000
Height
0
0
Area Bl. %Delta
Code
0 0 0.00
0
    US
18
16
14
12
10
 8
 6
 4
 2
 0
-2
           File: 19452321.D50 Sample:  194-52-32
        1—I—I—I—I—I—I—I—I—I—I—I—I—I—I—1—\—p-
            1          2         34
                              Minutes
                                                     i  i  r
                                                             ~\  i  r
                                                                          99

-------
                  Data Reprocessed On 01/10/1998  17:22:53
  Sample Name:  194-52-34
  Data File  :  C:\DX\DATA\44369CL2\19452341.D51
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1   Inject/:  51
  Analyst    :                 Column:
                Date:  01/09/1998 11:01:37
                            Detector:PED-Cond.
Calibration••- Voitune   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.19        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
                       Totals
        0.000
        • •••••••^^a

        0.000
     0

     0
   0
   »^»

   0
0.00
    uS
            File:  19452341.D51 Sample: 194-52-34
         40
         30
         20
         10
                i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—n—i—|—i—i—i—i  [~
                      12345
                                       Minutes
                                                                        100

-------
                   Data Reprocessed On  01/10/1998 17:26:07
 I3'

f
   a
Sample Name:  194-52-34
 ata File  :  C:\DX\DATA\44369CL2\19452341.D52
 ethod     :  C:\DX\METHOD\CHLORIDE.met
    Address:  1  System:  1  Inject#:  52
Analyst    :                 Column:
Date: 01/09/1998 11:15:22
            Detector:PED-Cond.
 Calibra*i-6m•••- Voinme   Dilution  Points Rate  Start   Stop Area Reject

 External          1           1    3600  5Hz   0.00   5.79        1000

                       Component  Report: All Components ***********************
  Pk.     Ret  Component
  Num   Time  Name
                            Concentration
  Height
Area  Bl. %Delta
     Code
        0.00  CHLORIDE
                       Totals
                                    0.000
                                   • ••^••^•B*

                                    0.000
       0

       0
   0

   0
0.00
     uS
            File: 19452341.D52 Sample:  194-52-34
         40
         30
         20
         10
                               2
                                           1  I  I I
                                                      i  i  r
                                                              i  i  i
                                      3
                                     Minutes
                                                                           101

-------
                  Data Reprocessed On 01/10/1998  17:27:59
  Sample Name:  194-52-35
  Data File  :  C:\DX\DATA\44369CL2\19452351.D53
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject/:  53
  Analyst    :                 Column:
                                      Date: 01/09/1998 11:29:07
                                                  Detector:PED-Cond.
Calibration— Voltime   Dilution Points  Rate   Start   Stop Area Reject

External          1          1   3600   5Hz    0.00   5.85        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Hum   Time Name
                      Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
                       Totals
                              0.000

                              0.000
     0

     0
   0
   m^m

   0
0.00
            File:  19452351.D53 Sample: 194-52-35
    uS
 4.0


 3.0


 2.0


 1.0


 0.0


-1.0
             I  I  I  I
                         I  I I
                              2
                                3        4
                               Minutes
                                                                         102

-------
                  Data Reprocessed On 01/10/1998  17:29:27
  Sample Name:  194-52-35
 Data File   : C:\DX\DATA\44369CL2\19452351.D54
Vethod      : C:\DX\METHOD\CHLORIDE.met
  :i Address: 1  System: 1  Inject/: 54
 Analyst     :                Column:
                                            Date: 01/09/1998 11:42:53
                                                         Detector:PED-Cond.
Calibra-fei-oft- Voltime   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.55        1000

                       component Report:  All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
                       Totals
                                    0.000
                                    • ••^••^•^•v

                                    0.000
     0

     0
            File: 19452351. D54 Sample: 194-52-35
    uS
        4.0
        3.0
        2.0
        1.0
        0.0
       -1.0
   0

   0
0.00
v^:
i i i i i t
D 1

I 1 1 I I I
2

i i 1 i i i i • I i i i i 1 i i
345
Minutes
                                                                          103

-------
                  Data Reprocessed On 01/10/1998  17:30:40
  Sample Name:  194-52-36
  Data File  :  C:\DX\DATA\44369CL2\19452361.D55
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  55
  Analyst    :                 Column:
                Date:  01/09/1998 11:56:38
                            Detector:PED-Cond.
                                              I
Calibrartei-oft - Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.67         1000

********************** Component Report:  All Components ***********************
 Pk.    Ret Component
 Hum   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
                       Totals
        0.000
       m^m «••»«•«••

        0.000
     0
    m^m

     0
   0

   0
0.00
            File: 19452361.D55 Sample: 194-52-36
    uS
        4.0
        3.0
        2.0
        1.0
        0.0
       -1.0
             n—i—i—i—[—i—i—i—i—[—i—i—i—i—|—i—i—i—i—:]—i—i—i—i—|—i—i—r
           6         1          2         3         4         5
                                       Minutes
                                                                            10'

-------
                  Data Reprocessed On 01/10/1998 17:31:51
  Sample Name: 194-52-36
*
  A]
 ata File  :  C:\DX\DATA\44369CL2\19452361.D56
 •athod     :  C:\DX\METHOD\CHLORIDE.met
    Address:  1  System: 1  Inject#: 56
Analyst    :                 Column:
                                            Date: 01/09/1998 12:10:24
          Detector:PED-Cond.
Calibration -Voitune   Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.79        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       0.00 CHLORIDE
                       Totals
                                    0.000

                                    0.000
     0
    • •••

     0
   0
   • ••

   0
0.00
            File: 19452361. D56 Sample:  194-52-36
     uS
        4.0
        3.0
        2.0
         1.0
        0.0
        -1.0
              1  I  T T
                                 i  i  i  i
                                      3
                                     Minutes
                                                 i  r. \  i  i  i  r T  i  r
                                                  45
                                                                          f *» r»
                                                                          1   O

-------
                  Data Reprocessed On  01/13/1998 13:49:47
  Sample Name:  194-52-38
  Data File  :  C:\DX\DATA\44369CL2\19452381.D57
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#: 57
  Analyst    :                Column:
                Date:  01/09/1998 12:24:09
                            Detector:PED-Cond
Calibration - Vo4«me    Dilution Points Rate  Start   Stop Area Reject

External          1          1   3600  5Hz   0.00   5.52        1000

                       Component Report: All .Components ***********************
 Pk.     Ret Component
 Num   Time Name
Concentration
Height
  Area  Bl. %Delta
       Code
       1.87  CHLORIDE
     US
                      Totals
        0.000

        0.000
142531
m^m^m ••«••»«••

142531
648634

648634
1 -12.87
            File:  19452381.D57 Sample: 194-52-38
         8


         6
         0
                        CHLORIDE/ 1.87

1,1.1
) 1

I I 1 I 1 1 1 f I I I I
2 3
Minutes
i . p i i i .1 1 i t
4 5

                                                                         106

-------
                 Data Reprocessed On 01/13/1998  13:51:34
 Sample Name:  194-52-38
 Data File  :  C:\DX\DATA\44369CL2\19452381.D58
  'ethod     :  C:\DX\METHOD\CHLORIDE.met
   I Address:  1  System:  1  Inject#:  58
 Analyst    :                 Column:
                                       Date:  01/09/1998  12:37:56
                                                  Detector:PED-Cond.
Calibration - Volume   Dilution Points  Rate   Start   Stop Area Reject

External          1          1   3600   5Hz   0.00   5.38        1000

                       Component  Report: All Components ***********************

                              Concentration     Height
Pk.
Num
 Ret Component
Time Name
             Area  Bl.  %Delta
                  Code
      1.89 CHLORIDE
    uS
                      Totals
                               0.000

                               0.000
155668

155668
                                                          695257
                                                          • ^•^ •• «* ^ M

                                                          695257
1 -12.09
           File: 19452381.D58 Sample: 194-52-38
         8


         6
                        CHLORIDE/ 1.89
                 iii
                                         3
                                      Minutes
                                                                       107

-------
                  Data Reprocessed On 01/10/1998 17:36:03
  Sample Name:  194-52-39
  Data File  :  C:\DX\DATA\44369CL2\19452391.D59
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1   System:  1   Inject#:  59
  Analyst    :                 Column:
                Date:  01/09/1998 12:51:43
                            Detector:PED-Cond
Calibration- Volume    Dilution  Points Rate  Start   Stop Area Reject

External          1           1    3600  5Hz   0.00   5.16        1000

********************** component  Report: All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
Concentration
Height
Area  Bl. %Delta
     Code
       0.00  CHLORIDE
                      Totals
        0.000
       • •• ••^^^Vfl

        0.000
     0

     0
   0

   0
0.00
           File: 19452391.D59 Sample: 194-52-39
    US
        30
        20
        10
"^"~
5 ...... 1 ,
1 1 1 1 1
2
1 1 1 1 1 1
3
•. • | . .
4
1 ' '. 1
5
                                      Minutes
                                                                        108

-------
                  Data Reprocessed On 01/26/1998 11:46:52
  Sample Name:  194-52-39
     File  :  C:\DX\DATA\44369CL2\19452391.D60
           :  C:\DX\METHOD\CHLORIDE.met
    Address:  1  System:  1  Inject#:  60
Analyst    :                 Column:
                                           Date: 01/09/1998 13:05:29
                                                         Detector:PED-Cond.
Calibration-- Vo>lome    Dilution  Points Rate  Start   Stop Area Reject

External          1           1    3600   5Hz   0.00   5.88        1000

********************** Component  Report: All Components ***********************
 Pk.     Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       0.00  CHLORIDE
    uS
                      Totals
                                    0.000

                                    0.000
     0

     0
            File:  19452391.D60 Sample: 194-52-39
        30
        20
         10
                                           1  I  I
                                       3        4
                                       Minutes
   0

   0
0.00
                                                                      109

-------
                  Data Reprocessed On 01/10/1998  15:39:53
  Sample Name:  194-52-2  MS
  Data File  :  C:\DX\DATA\44369CL2\19452021.D61
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject#:  61
  Analyst    :                 Column:
                    Date: 01/09/1998 13:19:14
                                Detector:PED-Cond.
Calibration..-Volume   Dilution Points Rate   Start   Stop Area Reject

External          1          2   3600  5Hz    0.00   5.15        1000

********************** Component Report: All Components ***********************
 Pk.    Ret Component
 Hum   Time Name
    Concentration
Height
Area  Bl. %Delta
     Code
       1.83 CHLORIDE
                       Totals
            0.000   29882611  330222786
            • W»^^«»^H«WWM«^W»^^^«»*W^^^^«>

            0.000   29882611  330222786
                     1 -14.73
            File: 19452021.D61 Sample: 194-52-2 MS
         80


         60


    uS   40


         20
CHLORIDE/ 1.83
              \  i  i  i     i
                                 2         3
                                       Minutes
                                                                          .110

-------
                  Data Reprocessed On 01/10/1998 16:22:08
  Sample Name:  194-52-2 MS
Data File  : C:\DX\DATA\44369CL2\19452021.D62
  :hod     : C:\DX\METHOD\CHLORIDE.met
 'JI Address: 1  System: 1  Inject#: 62
Analyst    :                Column:
                                            Date:  01/09/1998 13:33:00
                                                          Detector:PED-Cond.
Calibration ~ Volume   Dilution Points Rate  Start   Stop  Area  Reject

External          1          2   3600  5Hz   0.00   5.64         1000

********************** Component Report:  All Components ***********************
 PJc.    Ret Component
 Num   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.85 CHLORIDE
                       Totals
                                    0.000   29848773   332045428
                                    »OT^»^B^B«W^»^^«»^^ •*«•••»•••» V» ^» •» ^» •• •» ^» ••^•••^B

                                    0.000   29848773   332045428
                     1 -13.80
            File: 19452021.D62 Sample: 194-52-2 MS
         80


         60


    uS   40


         20
                      CHLORIDE/ 1.85
              I  I T  I  I  i  I  I
                                   I  I  I    I  I
                                         3         4
                                       Minutes
                                                                       lit

-------
                  Data Reprocessed On 01/10/1998  16:21:36
  Sample Name:  194-52-2 MSD
                     Date:  01/09/1998 13:46:46
  Data File  :  C:\DX\DATA\44369CL2\19452021.D63
  Method     :  C:\DX\METHOD\CHLORIDE.met
  ACI Address:  1  System:  1  Inject/:  63
  Analyst    :                 Column:
                                 Detector:PED-Cond.
Calibration -Voiwme   Dilution Points Rate  Start    Stop Area Reject

External          1          2   3600  5Hz   0.00    5.34         1000

********************** Component Report:  All Components ***********************
 Pk.    Ret Component
 Num   Time Name
     Concentration
Height
Area  Bl. %Delta
     Code
       1.85 CHLORIDE
    uS
                       Totals
             0.000    29973868   330095822
            • •»A^«*«^^«W«»^^M^V»^^^^^^^^««>

             0.000    29973868   330095822
                     1 -13.95
            File:  19452021.D63 Sample: 194-52-2 MSD
         80


         60
         20
CHLORIDE/ 1.85

i 1
)
1 1 1 1 1
1
' I '
2
i i i I i i
3
• .1 1 •
4
i i i |
5
t
                                       Minutes
                                                                        11

-------
                  Data Reprocessed On 01/10/1998  16:23:54
  Sample Name:  194-52-2 MSD
Data File  :  C:\DX\DATA\44369CL2\19452021.D64
Method     :  C:\DX\METHOD\CHLORIDE.met
ACI Address:  1  System: 1  Inject#: 64
Analyst    :                 Column:
                                            Date:  01/09/1998  14:00:32
                                                         Detector:PED-Cond.
Calibration..--.Volume   Dilution Points Rate  Start   Stop Area Reject

External          1          2   3600  5Hz   0.00   5.66        1000

********************** Component Report: All Components ***********************
 Pk.     Ret Component
 Hum   Time Name
                            Concentration
Height
Area  Bl. %Delta
     Code
       1.85 CHLORIDE
                       Totals
                                    0.000   29955458   330162583
                                   • ••^M»^»^»^»^»«B^«B f^mm^m ^«»^WR *• •• M* ^» ••• ^m ^» •» ^" v>

                                    0.000   29955458   330162583
                     1 -14.11
            File: 19452021.D64 Sample: 194-52-2 MSD
         80
         60
uS 40
20
0
C
CHLORIDE/ 1.85
I
.l\

i i i i i i i i i i i i i i i i i i i I i i i i i i t i
) 1 2 3 4 5
Minutes
                                                                         113

-------
TRIANGLE LA
TORIES INC.
                       TLI#44369-HCL
                       CALIBRATION
                       06/07-JANUARY-98
CONC RT
(ppm)
100 1
50 1
25
10
5
1
0.5
100
50
25
10
5
1
0.5

.98
.93
.90
.89
.89
.90
.92
.97
.92
.90
.89
.88
.90
1.92
AREA
753611891
351837453
163672444
58156561
28183099
5935843
2838828
750596460
350484618
166792324
58087354
28543971
5844200
2836346
LOG CONC
2.000
1.699
1.398
1.000
0.699
0.000
-0.301
2.000
1.699
1.398
1.000
0.699
0.000
-0.301
LOG AREA
8.877
8.546
8.214
7.765
7.450
6.773
6.453
8.875
8.545
8.222
7.764
7.456 N
6.767
6.453
PREDICTED
(ppm)
105.80
51.22
24.71
9.22
4.63
1.05
0.52
105.40
51.03
25.16
9.21
4.68
1.03
0.52
NDIFF
5.8
2.4
1.2
7.8
7.5
4.9
3.9
5.4
2.1
0.6
7.9
6.3
3.4
3.9
RESPONSE
(CONC/AREA)
1.33E-07
1.42E-07
1.53E-07
1.72E-07
1.77E-07
1.68E-07
1.76E-07
1.33E-O7
1.43E-07
1.50E-07
1.72E-O7
1.75E-07
1.71E-07
1.76E-O7
                       Constant
                       StdErrofYEst
                       R Squared
                       No. of Observations
                       Degrees of Freedom

                       X Coefflclent(s)
                       StdErrofCoef.
                                                  Regression Output:
                                                  1.04994
                                                  0.00855
                                                               6.75154
                                                               0.02535
                                                               0.99920
                                                                   14
                                                                   12
                       EXTERNAL CALIBRATION CHECK
CONC
(ppm)
RT
AREA
LOG AREA
PREDICTED
(ppm)
SDIFF
                                  20.0
                                  20.0
                                    1.86
                                    1.86
128293994
129375831
    8.108
    8.112
19.59
19.75
2.0
1.2
                       BLANKS
                                  TYPE
                                     RT
  AREA
AVERAGE AREA
                                 H2SO4
                                 H2SO4
                                                NO
                                                ND
TLI44369-HCL

-------
 UANGLE LABORATORIES INC.
                     TLM44369-CL2
                     CALIBRATION
                     09/10-JANUARY/98
CONG RT
(ppm)
100 2.04
50 2.03
25 2.03
10 2.03
5 2.03
1 2.05
100 2.03
50 2.05
25 2.02
10 2.03
5 2.05
1 2.04
AREA
441630829
210646738
99024234
34137811
15652645
2459514
445831770
215999081
95997059
33162847
15030202
2408845
LOG CONC
2.000
1.699
1.398
1.000
0.699
0.000
2.000
1.699
1.398
1.000
0.699
0.000
LOG AREA
8.645
8.324
7.996
7.533
7.195
6.391
8.649
8.334
7.982
7.521
7.177
6.382
PREDICTED
(ppm)
96.60
50.33
25.89
10.13
5.10
1.00
97.41
51.45
25.19
9.88 .
4.92
0.98
%DIFF
3.4
0.7
3.5
1.3
2.0
0.1
2.6
2.9
0.8
1.2
1.6
1.9
RESPONSE
(CONC/AREA)
2.26E-07
2.37E-07
2.52E-07
2.93E-07
3.19E-07
4.07E-07
2.24E-07
2.31 E-07
2.60E-07
3.02E-07
3.33E-07
4.15E-07
                     Constant
                     StdErrofYEst
                     R Squared
                     No. of Observations
                     Degrees of Freedom

                     X Coemclent(s)
                     StdErrofCoef.
                                                Regression Output:
               1.13537
               0.00498
                           6.39139
                           0.01142
                           0.99981
                               12
                               10
                     EXTERNAL CALIBRATION CHECK
CONC
(ppm)
RT
AREA
LOG AREA
PREDICTED
(ppm)
SDIFF
                                 30.0
                                 30.0
2.03
2.03
122990563
122820922
    8.090
    8.089
31.33
31.29
4.4
4.3
                     BLANKS
                                TYPE
 RT
  AREA
AVERAGE AREA
i
1


NAOH
NAOH

ND
ND

TLI 44369-CL2

-------
                              Appendix D

                           Particulate Matter
                       Laboratory Analysis Data
cah/A:\APPX-CVR.WP6

-------
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                                                             .60
                                                                      age No.	
Witnessed & Understood by me,
                         Date
nvented by
                                  Recorded b»
                                                            Date

-------
56
       Project M». CuuP A-A ,
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Date
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                            Invented by
                                                  ^- y. *.
Date,

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-------
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                       Book No.
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                                                                   To
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nvented by
                                  Recorded
*
                by   Wl A
                                                            Date

-------
                             Appendix E

                           EPA Method 301
                    FTIR Validation Results for HCI
eah/A:\APPX-CVR.WP6

-------
          £-1
     Table X-l.  Chip Dryer Baghouse Outlet Validation Results
         nVALIDATION OF WiR
 ,Bite^onductedTTDe"cTmbeTlW7~
 1-'
 jANALYTE SPIKING: QUAD tRADsTS      i
 FEDERAL REGISTER CALCULATION METHOD"
                                    )FTJYDROGENCHLORIDE
                       SourceTChjfTDlye r Outle7~~~[         ]~
 IENTER VALUE OF SPIKED LEVEL (cs)=
 jDuution Factor for Unspiked Samples =        ;      0.96j         |          |         I
 ENTER SPIKED AND UNSPIKED CONCENTRATIONS (COMPARABLE UNITS ASSUMED)
          .'CONCENTRATION IN PPM (WET)
            SPIKED SAMPLES !  UNSPIKED SAMPLES
    RUN #•
           B
            C
            D
          A-B|(A-B)A2!
                          (C-D)A2
         i;
9.48;
 9.02:
 0.43;
 0.36
 0.46i
0.21
0.07!
0.00
        2:
7.99i
 8.92i
 0.46^
 0.31
-0.93!
0^67
0.15;
0.02
        3j
9.4 li
 9.04;
 0.30
 0.28;
 0.37i
(U4i
(T02;
0.00
               9798
         10.37
        T072~9~
          0.25
          0.22
         1)723"
         "0729"
         ^0739 i
          0.00:
          0.15)
          O.OOi
         0.03:
         ~0~TT
          0.00
               10.29
              To36"
         10.99
          0.36
         "074T
         -0.43
          0.18;
         0.18
          0.03
  VERAGE:,
Sm=
9.70
Mm=
0.33
j~""        i SPIKED SDs=~ "	'	~	036	"	"	r	\	'""



J	~7RELATIVESTD"RSDs;     3:7% 7 (acceptable)	      \	"	~~j~
,~	             '    """""	     T         '         ~         1     	T
i	~~ RELATIVE STDRSDu"	24:4%:"(acceptabie)	~J	|"
!	"	:	"	!	~	'	"	;	"	I	I"
fBiAS:	"	"	i	'.	:	;	p	~	i	•	:	r
     	Corr¥cTed"U'nspked~Conc"="	'	0.32	"	"	"t	'	"'	"	"	]""
             	i'B=	1	07120	i	I	|	"	"j	
                   !         :         r        "^         i         \-
          STD OF MEAN SDm=;    0.368          :         j         |
                   :                  "                  I         P

                                                        I        __
                                     i         i         ;         i
         TCiaTTC7ii;^\7ALDE=":"	   27201"'"  ~	"	~~         1         |~
         i(n=12, alpha=95%)    ;         '         ;         |         |~
         |Bias not statistically significant, CF not needed.
                                (E987 j(AcceptableT
JEND OF ANAIYTE SPIKING $PR£ADSHEET~PRi:S$ "HOME"-KEY TO RETURN

-------
Table X-2.  Reverbatory Furnace Hood Baghouse Inlet Validation Results

jDate Conducted: 7 December 1997 ! Source: Baghouse Inlet
i ANAL YTE SPIKING: QUAD TRAINS | | j
JFEDERAL REGISTER CALCULATION METHOD |
jENTER VALUE OF SPIKED LEVEL (CS)= j 9.6|
jDQution Factor for UnspDced Samples = j 0.96;




1
! ENTER SPIKED AND UNSPIKED CONCENTRATIONS (COMPARABLE UNITS ASSUMI
I | CONCENTRATION IN PPM (WET) .
: ; SPIKED SAMPLES UNSPIKED SAMPLES
; RUN# A; B C D A-Bi (A-B)A2
; 1 32.77; 34.51 17.91; 18.89; -1.74 3.03
I 2: 24.91, 26.39 8.65| 9.33; -1.48, 2.19
| . 3j 21.37; 23.27 9.82j 9.15J -1.90; 3.61
! 4i 26.9T 28.19 14.70; 15.091 -128; 1.64
i 5. 23.531 18.48 19.80: 20.29! 5.05! 25.50
6 19.39' 19.02 11.61 11.96 0.37! 0.14

VERAGE:: Sm=, 24.90 Mm= 13.93 ;
iSTTijroTaani'EViATro'N: 	



: 	 .SPIKED SE)s= 	 ~ 	 TJ3 	 1 	 ~ 	 ~^~| 	 	
1 • ! I
iUNSPIKED SDu=

; ; RELATIVE STDRSDs

	 "iRELATIVE'STDRSDu

;BIAS: • 	
Corrected Unsplked Co
iB=

: STD OF MEAN SDm=
! " |
|t-VALUE=
;
i
: CRITICAL t-VALUE=
(n=12, alpha=95%)
:
\
0.45 j

7.0%: (acceptable) i

3.2%: (Acceptable)




C-D
-0.98
-0.68
0.67
-0.39
-0.49
-0.35














nc= : 13.32 !
1.978 ; : ""
; : •
1.791 : ! i

1.104 ; i
i i i
2.201: ; ;



'.\it
i • • i • i

Bias not statistically significant, CF not needed. j
; j j |
_ -C-ORREUTID^FACT4
'lEfUHXTlfHX^^
i i i
- ' !
0.829 i(Acceptable)
1 __|



IEADSHEET. PRESS 1
-------
    Table X-3.  Reverbatory Furnace Hood Baghouse Outlet Validation Results
         j VALID ATION OF FTIJRrFOKTHE'AfirAt^SlSr
 Date ConductedT7lDecemberT997
                                                CHLORIDE
                      Source: Baghouse Outlet
 ANAL YTE SPIKING: QUAD TRAINS"
 FEDERAL REGISTER CALCULATION METHOD
jDHufioh Factor for Uns"p3Ted"'Samjpfes"=
ENTERTPr
                          _o___.
                               (COMPARABLE UNITS AS'SUMED)
        "[CONCENTR7ATION IN PPM (WET)       J
        y-^-jKED-s7AMH£S^^
   RUN #|
           B
            C
                              D
                                           A-Bj   (A-B)A2
T2J
               TT757
             11.94
             12.63:
               137167
               T375D7
 4i
37
             12.79!
             11.99
             T2753'
 13.84;
T37T8"
T3734"
 i.os;
"2779~
"2772"
T.297
                  1.54
                 7272T
                                         1.33
                                   -0.64
                                     0.41
                                              C-D;  (C-D)A2
                                             "07257     0706~
                    1.901
                   Trror
 -1.22!
^oTsir
                                             1.49
                                              0.89i
                                                                0.79:
                                             0.76
                                              0.62:
                                                                0.38;
                           1.92
^TTOTF
                    l.lOi
                  -T37T
                                    -1.19!
                                    -0.81!"
 1.10
TA2
"0766
                                              0.37:
                                                                0.14
                                    0.44;
                                   "07857"
                            0.19
                           "0772".
 VERAGE:;
Sm=
12.81
                   Mm=
                                  1.86
STANDARD DEVIATION: "
         SPIKEDSDs=
                 0.70
         JUNSPIKED SDu=
                 0.44
         iRELATIVESTDRSDs.
                 5.4%" (acceptable)"
        7|REL:ffiVE STD RSDTil	-723:5%7TacceptaFley
BH5r__,_^	_	-''''^^2iiir~\	T~TZZ.T
         jCorrect'ed UnspEed! C'oric =~	"7	    1776"" ~"      |~
         i     	~TB=	   	i	"^O4S~~	     r	       r~~    	
         !  	     •   	    • _ __ ..„,.,.   _'     ^_ 	i        	I	
         i      	r     ~ ~ j          ;	I       " r	~
         ]sTDT)FlMEAN"''SDtrFi    D7S2T",     	~~|	       f
         I   _.-	^ 	     	,   	      -.        |         .    	_—
         I	"  	"IFVATOE^	  o:299"'!""	~"	  \        f~~	"	~~
         	~	••	"	"	;	~	I"	:	"	tT~	~	i	~	~
         CRTTICAL t-VALUE=7	  23oT~ " 	 j         j	
         (S=T2T"alpha=95%)   \          i   	   P"      [
	i	•	[	|	|	
         jBias not statistically significant, CF not needed.       i
         !                 .                  :         >
         JCORRECTION FACT:    1.022  .(Acceptable^        i
   _  _  i         :        -          :       ' i  _      i        '
ETTD OF ANALYTETPTlONlJSTREADSHEET. PRESS "HOME"-1TET TO RETURN7
	,	.	1	,	1	,	
	'	'	i'	~	r'	~	~T	       r~    	h       i

-------
                              Appendix F




                         FTIR QC Spike Results
cah/A:\APPX-CVR.WP6

-------
Run
Date Time Inlet/outlet Spiked
1
1
1
1
1
1
2
2
2
2
2
2
3
3
3
3
3
3
4
4
4
5
5
5
6
6
6
6
6
6
7
7
7
7
7
7
8
8
8
8
8
8
9
9
9
9
9
9
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/5/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/6/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/8/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
12/9/97
AM outlet
AM outlet
AM outlet
AM inlet
AM inlet
AM inlet
PM outlet
PM outlet
PM outlet
PM inlet
PM inlet
PM inlet
AM inlet
AM inlet
AM inlet
AM outlet
AM outlet
AM outlet
PM outlet
PM outlet
PM outlet
PM inlet
PM inlet
PM inlet
AM outlet
AM outlet
AM outlet
AM inlet
AM inlet
AM inlet
PM outlet
PM outlet
PM outlet
PM inlet
PM inlet
PM inlet
AM inlet
AM inlet
AM inlet
AM outlet
AM outlet
AM outlet
PM inlet
PM inlet
PM inlet
PM outlet
PM outlet
PM outlet
10.88
10.88
10.12
15.25
15.10
16.89
17.32
15.25
13.15
13.10
12.62
12.49
25.86
24.35
23.83
28.59
25.74
24.74
16.93
17.28
17.23
13.62
13.87
13.62
18.49
20.84
21.02
15.88
16.93
17.23
8.96
9.08
9.33
14.62
14.07
13.88
16.52
14.94
14.22
19.75
20.83
21.62
13.52
14.81
14.79
11.07
11.41
11.57
Spiked Unspiked Avg
0.58

10.63


15.75


15.24


12.74


24.68


26.36


17.15


13.70


20.12


16.68


9.12


14.19


15.23


20.73


14.37


11.35
0.44
0.35
4.97
5.04
4.89
4.03
3.66
3.28
2.90
2.78
2.87
4.06
2.90
2.46
6.31
4.27
3.37
0.83
0.75
1.53
3.83
2.95
2.48
0.83
2.23
1.53
3.26
1.86
3.64
1.15
1.81
1.84
4.82
4.88
4.91
2.10
2.02
1.82
3.47
2.17
1.75
3.10
2.25
1.40
1.40
1.18
1.90
Unspiked Dilution avg dil
0.05

0.46


4.97


3.66


2.85


3.14


4.65


1.04


3.09


1.53


2.92


1.60


4.87


1.98


2.46


2.25


1.49
0.05
0.05
0.04
0.04
0.04
0.06
0.06
0.06
0.06
0.06
0.06
0.11
0.10
0.10
0.09
0.09
0.09
0.08
0.07
0.07
0.06
0.06
0.06
0.09
0.09
0.09
0.08
0.08
0.07
. 0.04
0.04
0.04
0.05
0.05
0.05
0.06
0.06
0.06
0.09
0.09
0.09
0.06
0.06
0.06
0.05
0:05
0.05

. 0


0


0


0


0


0


0


0.


0


0


0


0


0


0


0


0

-------
Run
Date
Time
Inlet/outlet Spiked    Avg Spiked  Unspiked  Avg Unspiked  Dilution   avg dil
10
10
10
10
10
10
11
11
11
12
12
12
13
13
13
13
13
13
14
14
14
14
14
14
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/10/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
12/11/97
AM inlet
AM' inlet
AM inlet
AM outlet
AM outlet
AM outlet
PM inlet
PM inlet
PM inlet
PM outlet
PM outlet
PM outlet
AM inlet
AM inlet
AM inlet
AM outlet
AM outlet
AM outlet
PM inlet
PM inlet
PM inlet
PM outlet
PM outlet
PM outlet
7.22
14.12
14.92
15.28
15.14
9.27
22.19
26.70
27.73
17.24
17.47
17.58
10.14
10.84
11.16
12.30
12.84
13.38
14.67
14.33
14.49
10.04
16.02
17.44
                                                       12.09
                                                       13.23
                                                      25.54
                                                      17.43
                                                      10.71
                                                      12.84
                                                      14.50
                                                      14.50
                                                        3.56
                                                        2.06
                                                        1.74
                                                        3.73
                                                        2.48
                                                        2.02
                                                        9.20
                                                        6.85
                                                        5.71
                                                        2.21
                                                        1.81
                                                        1.48
                                                        0.21
                                                        1.68
                                                        1.38
                                                        1.72
                                                        1.12
                                                        0.98
                                                        3.21
                                                        2.34
                                                        2.01
                                                        2.78
                                                        1.86
                                                        1.72
                                                           2.45
                                                           2.74
                                                           7.25
                                                           1.83
                                                           1.09
                                                           1.27
                                                           2.52
                                                           2.12
                                                         0.05
                                                         0.07
                                                         0.07
                                                         0.07
                                                         0.07
                                                         0.02
                                                         0.11
                                                         0.11
                                                         0.11
                                                         0.07
                                                         0.07
                                                         0.07
                                                         0.05
                                                         0.05
                                                         0.05
                                                         0.06
                                                         0.06
                                                         0.06
                                                         0.05
                                                         0.04
                                                         0.04
                                                         0.05
                                                         0.06
                                                         0.06

-------