United States
Environmental Protection
Agency
Office of Air Quality EPA - 454/R-99-018
Planning and Standards June 1999
Research Triangle Park, NC 27711
Air
&EPA
Secondary Aluminum Industry
Final Emissions Test Report
Gulp Aluminum Alloys
Steele, Alabama
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Table of Contents
Page
1.0 INTRODUCTION 1-1
1.1 Objectives 1-2
1.2 Brief Site Discussion 1-3
1.3 Emissions. Measurements Program 1-3
1.3.1 Test Matrix 1-3
1.3.2 Test Schedule 1-5
1.4 Test Report 1-5
2.0 SUMMARY OF RESULTS 2-1
2.1 Emissions Test Log 2-1
2.2 Dioxin/Furan Results . 2-5
2.2.1 Overview .\ 2-5
2.2.2 Dioxin/Furan Emission Results 2-5
2.3 HC1 Results ':....,.. 2-18
2.3.1 Overview 2-18
' 2.3.2 HC1 Emission Results ; 2-19
2.4 Particulate Results 2-23
2.4.1 Overview 2-23
2.5 FTIR Results . . 2-26
2.5.1 Overview . . . ;. . 2-26
2.5.2 FTIR Emission Results 2-27
2.5.2.1 EPA Method 301 FTIR Validation Results for HC1 2-28
2.5.2.2 FTIR HC1 Test Results 2-28
2.5.2.3 FTIR Process Optimization 2-32
2.5.2.4 FTIR Screening Results .. 2-33
2.5.2.5 FTIR Sampling and Measurement System Response
Time Measurement 2-39
2.5.2.6 Comparison of FTIR and Method 26A Results for HC1 2-41
3.0 DESCRIPTION OF FACILITY 3-1
4.0 SAMPLING LOCATIONS 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES BY ANALYTE . 5-1
5.1 Chlorinated Dibenzo-^-Dioxin and Chlorinated Dibenzofuran Emissions Testing
Using EPA Method 23 5-1
5.1.1 Method 23 Sampling Equipment 5-1
5.1.2 Method 23 Equipment Preparation 5-1
iii
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Table of Contents (Continued)
Page
5.1.2.1 Glassware Preparation 5-3
5.1.2,2 XAD-2® Resin and Filter Preparation , 5-3
5.1.2.3 Method 23 Sampling Train Preparation '..' 5-5
5.1.3 Method 23 Sampling Operations • 5-6
5.1.3.1 Preliminary Measurements ..........\.' 5-6
5.1.3.2 Assembling the Train 5-6
5.1.3.3 Sampling Procedures 5-7
5.1.4 CDD/CDF Sample Recovery .'........ 5-12
5.1.5 CDD/CDF Analytical Procedures ..:....'. 5-15
5.1.5.1 Preparation of Samples for Extraction ...:-.... 5-18
5.1.5.2 Calibration of GC/MS System 5-18
5.1.6 CDD/CDF Analytical Quality Control..-.." 5-18
5.1.6.1 CDD/CDF Quality Control Blanks, 5-19
5.1.6.2 Quality Control Standards and Duplicates . 5-20
5.1.7 Analytes and Detection Limits for Method 23 .V 5-21
5.2 Hydrochloric Acid/Particulate Matter Emissions Testing Using EPA
Method 26A 5-23
5.2.1 Method 26A Sampling Equipment .".. • '5-23
5.2.2 Method 26A Sampling Equipment Preparation 5-25
5.2.2.1 Glassware Preparation 5-25
5.2.2.2 Reagent Preparation 5-25
5.2.2.3 Equipment Preparation 5-26
5.2.3 Method 26A Sampling Operations 5-28
5.2.3.1 Preliminary Measurements 5-28
5.2.3.2 Assembling the Train 5-28
5.2.3.3 Sampling Procedures 5-29
5.2.4 Method 26A Sample Recovery 5-30
5.2.5 HC1 Analytical Procedures . 5-37
5.2.6 HC1 Analytical Quality Control 5-38
5.2.7 Particulate Analysis 5-38
5.2.8 Quality Control for Gravimetric Procedures 5-40
5.3 FTIR EPA Method 320 5-40
5.3.1 FTIR Sampling Equipment 5-40
5.3.2 Preparation for Sampling 5-43
5.3.3 Sampling. '. 5-45
5.3.4 FTIR Method Data Review, Validation, and Verification
Requirements 5-48
5.3.5 QC for the FTIR 5-51
IV
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Table of Contents (Continued)
Page
6.0 QUALITY ASSURANCE/QUALITY CONTROL 6-1
6.1 Sampling QC Results 6-1
6.1.1 .Leak Checks '.". '. ...6-1
6.1.2 Percent Isokinetics ..6-4
6.1.3 Meter Box Calibrations 6-5
6.1,4 Field Blank Results 6-5
6.1.5 FTIR Sampling Quality Control 6-7
6.2 Analytical Quality Control Results 6-9
6.2,1 D/F Analytical Quality Control 6-9
6.2.1.1 D/F Quality Control Blanks 6-9
6.2.1.2 Quality Control Standards 6-10
6.2.2 HC1 Analytical Quality Control 6-10
6.2.3 Quality Control for Gravimetric Procedures 6-11
6.2.4 FTIR Analytical Quality Control 6-11
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List of Figures
Page
2-1 FTIR System Response Profile (Measured on 7 December 1997) 2-40
4-1 El, Chip Dryer Baghouse Inlet 4-2
4-2 E2, Chip Dryer Baghouse Outlet 4-3
4-3 E3, Reverberatory Furnace #1 Baghouse Inlet 4-4
4-4 E4, Reverberatory Furnace #1 Baghouse Outlet 4-5
4-5 Chip Dryer Baghouse Inlet, Traverse Points 4-6.
4-6 Chip Dryer Baghouse Outlet, Traverse Points 4-7
4-7 Reverberatory Furnace #1 Baghouse Inlet Traverse Points 4-8
4-8 Reverberatory Furnace #1 Baghouse Outlet Traverse Points 4-9
5-1 Method 23 Sampling Train Configuration 5-2
5-2 Method 23 Field Recovery Scheme 5-13
5-3 Extraction and Analysis Schematic for Method 23 Samples- 5-17
5-4 Schematic of Method 26A Sampling Train 5-24
5-5 Method 26A Sample Recovery Scheme 5-34
5-6 Method 5 Preparation and Analysis Scheme (Integral Part of Method 26A) 5-39
5-7 FTIR Sampling and Measurement System 5-42
VI
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List of Tables
Page
1-1 Gulp Aluminum Alloys Facility (Steele, Alabama) Test Matrix 1-4
2-1 Emissions Test Log 2-2
2-2 Sample Volume Collected, dscm 2-4
2-3 Flue Gas Volumetric Flow Rate, dscmm 2-4
2-4 Chip Dryer, Inlet D/F Stack Gas Concentration, ng/dscm 2-6
2-5 Chip Dryer, Outlet D/F Stack Gas Concentration, ng/dscm 2-7
2-6 Chip Dryer, Outlet D/F Emission Rate, ug/Mg Feed 2-9
2-7 Chip Dryer, 2,3,7,8-TCDD Toxicity Equivalent Concentrations 2-11
2-8 Reverberator}' Furnace #1, Inlet D/F Concentration, ng/dscm 2-13
2-9 Reverberatory Furnace #1, Outlet D/F Concentration, ng/dscm 2-14
2-10 Reverberatory Furnace #1, Outlet D/F Emission Rate, ug/Mg Feed 2-16
2-11 Reverberatory Furnace #1, 2,3,7,8-TCDD Toxicity Equivalent Concentrations . 2-17
2-12 HC1 and C12 Concentration, ug/dscm 2-20
2-13 HC1 and C12 Concentration, ppm 2-20
2-14 HC1 and C12 Emission Rate, Ibs/hour 2-21
2-15 HC1 Removal Efficiency 2-21
2-16 HC1 and C12 Emission Rate, Ibs/Ton of Feed 2-22
2-17 Stack Gas Paniculate Matter Concentration, gr/dscm 2-24
2-18 Particulate Matter Emission Rate, Ibs/hour .. .'. 2-24
2-19 Baghouse Particulate Removal Efficiency,% 2-24
2-20 Particulate Matter Emission Rate, Ibs/Ton of Feed 2-25
vii
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List of Tables (Continued)
Page
2-21 Summary of EPA Method 301 FTIR Validation Results for HC1 2-28
2-22 Chip Dryer FTIR HC1 Results, ppmv 2-30
2-23 Reverberatory Furnace #1 Baghouse FTIR HC1 Results During Charging, ppmv ... 2-30
2-24 Reverberatory Furnace #1 Baghouse FTIR HC1 Results During Tapping, ppmv .... 2-31
2-25 Combined Charging and Tapping Reverberatory Furnace #1 Baghouse FTIRHC1 .
Results, ppmv 2-32
2-26 Reverberatory Furnace #1 Baghouse FTIR HC1 Results - Grand Average, ppmv . . .2-32
2-27 Reverberatory Furnace #1 Hood Baghouse Outlet HC1 Results - Overnight, ppmv ... 2-33
2-28 Other Species Detected by FTIR - Chip Dryer Inlet 2-34
2-29 Other Species Detected by FTIR - Chip Dryer Outlet 2-35
2-30 Other Species Detected by FTIR - Reverberatory Furnace #1 Inlet 2-36
2-31 Other Species Detected by FTIR - Reverberatory Furnace #1 Outlet 2-38
2-32 Comparison of FTIR and Method 26A results for HC1, ppm 2-41
5-1 Method 23 Glassware Cleaning Procedure (Train Components, Sample Containers
and Laboratory Glassware) 5-4
5-2 CDD/CDF Sampling Checklist 5-9
5-3 Method 23 Sample Fractions Shipped To Analytical Laboratory 5-15
5-4 CDD/CDF Congeners To Be Analyzed 5-16
5-5 Method 23 Blanks Collected 5-19
5-6 Analytical Detection Limits For Dioxins/Furans 5-22
vm
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List of Tables (Continued)
Page
5-7 CDD/CDF Method Detection Limits 5-22
f
5-8 Glassware Cleaning Procedure (Method 26A Train Components) 5-26.
5-9 Sampling Checklist for EPA Method 26A 5-31
5-10. Typical FTIR Operating Parameters .5-45
5-11 Compounds for Which Reference FTIR Spectra Are Available in the ERG Spectral
Library 5-49
6-1 Summary of Dioxin/Furan Test Leak Check Results : 6-2
6-2 Summary of HC1/PM Test Leak Check Results 6-3
6-3 Summary of Isokinetic Percentages 6-4
6-4 Dry Gas Meter Post-Test Calibration Results 6-5
6-5 Method 26A Field Blank Analysis Results, ug Detected 6-6
6-6 Method 23 Field Blank Analysis Results, ng Detected 6-7
6-6 QC Spiking Results 6-13
6-7 HC1 Gas Standard Analysis Results 6-14
6-8 CO Gas Standard Analysis Results : 6-15
6-9 CH4, NOX, and CO2 Gas Standard Analysis Results 6-16
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1.0 INTRODUCTION
The purpose of this testing program was to obtain emissions data for uncontrolled and
controlled hydrochloric acid (HCl), paniculate matter (PM) and speciated hydrocarbon
Hazardous Air Pollutants (HAPs) from a secondary aluminum processing plant to support a
national emission standard for hazardous air pollutants (NESHAP).
The Gulp Aluminum Alloys facility in Steele, Alabama, is a secondary aluminum
reclamation facility. The Gulp facility accepts many different forms of scrap aluminum
feedstock, and operates a chip dryer to volatilize oils and lubricants from scrap aluminum chips
prior to the remelting operation. The chip dryer emissions are captured by closed hoods and are
ducted to a lime injected baghouse. There is a side-well reverberatory furnace that is used to
remelt, flux, and alloy aluminum scrap that has been pre-processed in the chip dryer operation in
addition to non-processed purchased aluminum scrap. The side-well reverberatory furnace
emissions are captured by a canopy hood located above the charging and refluxing side-well and
ducted to a lime injected baghouse. Emissions from the hearth stack are uncontrolled.
The existing total hydrocarbons (THC) emissions test data from secondary aluminum
smelting plants had not been speciated to determine HAP content. Additional data were needed
to identify HAPs emitted and their respective emission rates from melting furnace and chip
drying operations at secondary aluminum smelting plants. Also, information on the HCl, PM,
and dioxin/furan (D/F) removal efficiency of baghouses with dry lime injection was needed.
Source tests were required to quantify and characterize the HCl, PM, D/F, and HAP
emissions and to assess control device performance from chip drying and side-well reverberatory
furnace #1 operations, and to identify, quantify, and assess the performance of a lime injected
baghouse at two lime injection rates for HCl from the side-well reverberatory furnace #1
operations. Application of the following stationary source test methods was required to
adequately characterize these processes:
1-1
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• Determination of D/F using EPA Method 23;
Determination of HC1 and PM using EPA Method 26A and EPA Method 320; and
Screening for speciated hydrocarbon HAPs using EPA Method 320.
The objective of this work assignment was to perform all activities necessary to
characterize specified point sources for the parameters listed above. The facility selected for
testing, the Gulp Aluminum Alloys Plant located in Steele, Alabama, has lime injected baghouses
as control technology.
1.1 Objectives
The objective of the testing at the Gulp Aluminum Alloys facility, in Steele, Alabama,
was to perform all activities necessary to characterize the lime injected baghouses for the
following emission components:
• Determination of D/F using EPA Method 23;
Determination of HC1/PM using EPA Method 26A and EPA Method 320; and
• Screening for speciated hydrocarbon HAPs using EPA Method 320.
For the manual methods, testing was performed simultaneously at the inlet and outlet of
the chip dryer lime injected baghouse and simultaneously at the reverberatory furnace #1 lime
injected baghouse. FTIR testing was not simultaneous at inlet/outlet; the FTIR alternated
between inlet/outlet (for example, ten minutes inlet/ten minutes outlet). In addition, a day of
testing was performed using EPA Method 320 to identify, quantify, and assess the performance
of the lime injected baghouse associated with the reverberatory furnace #1 for HC1 removal at
two injection rates of lime. Two additional days were required to perform a Method 301
validation of FTIR for HC1: one day each for the two baghouses.
1-2
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1.2 Brief Site Discussion
The Gulp Aluminum Alloys Plant is located in Steele, Alabama, approximately 4 miles
south of Gadsden, Alabama. The plant is a secondary aluminum plant, primarily smelting
recycled aluminum. Gulp Aluminum Alloys primarily recycles aluminum parts to create a
secondary aluminum alloy which is used in cast aluminum. The plant operates 24 hours per day,
but the chip dryer process is down Monday from 7 AM to 4 PM, except for the furnaces.
The Gulp Aluminum Alloys Plant has two baghouses associated with the furnaces as
control devices: the first baghouse is the original one while the second is newer. The exhaust
stacks on both are approximately the same size. Furnace #1 and Furnace #2 differ in that
Furnace #2 has an additional exhaust from the sweat furnace. The sweat furnace is used to
separate plastic parts and metals of higher melting points from the aluminum prior to placing the
aluminum into the furnace.
1.3 Emissions Measurements Program
This section provides an overview of the emissions measurement program conducted at
the Gulp Aluminum Alloys Plant in Steele, Alabama. Included in this section are summaries of
the test matrix, sampling locations,.sampling methods, and laboratory analysis. Additional detail
on these topics are provided in the sections that follow.
1.3.1 Test Matrix
The sampling and analytical matrix that was performed at Gulp Aluminum Alloys is
presented in Table l-l, with the schedule that was followed in the field. Manual and Fourier
Transform Infrared (FTIR) instrumental emissions tests were performed, with detailed
descriptions of these sampling and analytical procedures provided in Section 5.0 of this
document.
1-3
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Table 1-1. Gulp Aluminum Alloys Facility (Steele, Alabama) Test Matrix
Industry: Secondary Aluminum
Process: Aluminum Chip Drying and Smelting
Sampling
Location
E2
Chip Dryer
Lime Injected
Baghouse
Outlet
E1/E2
Chip Dryer
Lime Injected
Baghouse
Inlet/Outlet
E3/E4
Reverberatory
Furnace #l
Lime Injected
Baghouse
E3/E4
Reverberatory
Furnace # 1
Lime Injected
Baghouse
E3/E4
Reverberatory
Furnace #1
Lime Injected
Baghouse
Inlet/Outlet
Runs/
Date
1 day
12/03/97
3
Run 1
12/05/97
Runs 2,3
12/06/97
1 day
12/07/97
1 day
12/07/97
6:
Run 1
12/08/97
Run 2
12/09/97
Run 3
12/10/97
Run 4
12/11/97
Sample Type
HC1 Validation
HC1/PM
Dioxins/Furans
All species
detected by FTIR1
HC1 Removal
efficiency study
HC1 Validation
HC1/PM
Dioxins/Furans
All species
detected by FTIR1
Reference
Method
Method 320
Method 26A
Method 23
Method 320
Method 320
Method 320
Method 26A
Method 23
Method 320
Sampling
Duration
4-8 hours
4 hours
4-8 hours
8-10
hours
4 hours
Analysis
Method
FTIR
Method 26A
Method 8290
Method 320
FTIR
FTIR
Method 26A
Method 8290
Method 320
Laboratory
ERG
Triangle Labs
Triangle Labs
ERG
ERG
ERG
Triangle Labs
Triangle Labs
ERG
' All species detected by FTIR includes all gaseous HAPs (i.e.. HC1), as well as criteria pollutants (i.e., NO,,
S0:, CO).
2Work Assignment Manager elected to perform four test runs in the field.
1-4
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1.3.2 Test Schedule
The daily test schedule is shown in Table 1-1. The test required one day of set-up at the
chip dryer lime injected baghouse, two test days at the inlet/outlet of the chip dryer lime injected
baghouse, one day of process operating parameter optimization using FTIR, and five test days at
the inlet/outlet of the reverberatory furnace #1 lime injected baghouse. One day was allowed as
contingency/tear-down. The facility did not operate on Mondays from 7 AM to 4 PM, except for
the furnaces; allowance was made for the plant schedule in the test schedule. Each test day was
12 to 16 hours in length. Set-up and tear-down days were 8 to 10 hours in length.
1.4 Test Report
This final report, presenting all data collected and the results of the analyses, has been
prepared in six sections and two volumes, as described below:
Section 1 provides an introduction to the testing effort and includes a brief
description of the test site and an overview of the emissions measurements
program;
Section 2 gives a summary of the test results for the PM, HC1, D/F tests, and the
FTIR results for HC1 and selected HAPs;
Section 3 provides a description of the process and plant operation during the field
test. These data are to be supplied by EPA through Research Triangle Institute to
be included at a later date;
Section 4 gives a discussion of the sampling locations;
Section 5 presents detailed descriptions of the sampling and analysis procedures;
and
Section 6 provides details of the quality assurance/quality control procedures used
on this program and the QC results.
The appendices containing copies of the actual field data sheets and the results of the
laboratory analyses are contained in Volume 2.
1-5
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2.0 SUMMARY OF RESULTS
This section provides the results of the emissions test program conducted at the Gulp
Aluminum Alloys plant from December 2 to December 11, 1997. Included in this section are the
results for the manual tests conducted for PM, HC1, CU, dioxin and furan and for the extractive
FTIR test conducted for HC1 and screening for selected HAPs. Testing was performed at the
inlet and outlet of the baghouse associated with the chip dryer and at the inlet and outlet of the
baghouse associated with the reverberatory furnace number 1.
2.1 Emissions Test Log
Twenty eight manual tests were performed over a nine day period (14 D/F and 14
HC1/PM). Table 2-1 presents the emissions test log which shows the test date, location, run
number, test type and run times for each method. Concurrent with the manual testing at each
location were extractive FTBR measurements for HC1.
Table 2-2 shows the volume of stack gas sampled for each run in dry standard cubic
meters (dscm) and Table 2-3 shows the stack gas volumetric flow rate during each run in dry
standard cubic meters per minute (dscmm). The percent relative standard deviation (%RSD)
calculated for the stack flow rates (shown in Table 2-3) was less than 10 % indicating that each
process flow was maintained at a fairly constant rate over the respective test days. All related
field data sheets are given in Appendix A.
2-1
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Table 2-1. Emissions Test Log
Date
12/3/97
12/4/97
12/5/97
12/6/97
12/7/97
12/8/97
Location
Chip Dryer Outlet
Chip Dryer
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Outlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Inlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Run
Number
NA
Plant Down
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
NA
1
1
1
1
1
1
1
1
1
1
Test Type
FTIR HC1 Validation
NA
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HC1
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HCI
D/F
FTIR (unconditioned)
FTIR (conditioned)
PM/HCI
D/F.
FTIR (unconditioned)
FTIR (conditioned)
FTIR HC1 Validation
PM/HCI
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HCI
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
Run Time
10:00-15:00
NA
08:00-14:40
08:00-14:40
08:00-11:30
12:40-14:30
10:20-14:40
08:00-14:40
08:00-11:30
12:40-14:30
08:34-13:20
08:34-13:30
08:35-10:40
11:20-13:20
08:34-13:20
08:34-13:30
08:34-10:34
11:20-13:20
15:45-20:03
15:45-20:03
15:46-17:46
18:10-20:03
15:45-20:03
15:45-20:03
15:45-18:03
18:10-20:03
12:00-17:00
09:48-15:42
09:48-15:42
09:45-12:00
12:00-13:20
13:20-15:42
09:48-15:42
09:48-15:42
09:45-12:00
12:00-13:20
13:20-15:42
2-2
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Table 2-1. (Continued)
Date
12/9/97
12/10/97
12/11/97
Location
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Inlet
Run
Number
2
2
2
2
2
2
2
.2
2
2
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
Test Type
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)'
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
PM/HC1
D/F
FTIR (unconditioned)1
FTIR (conditioned)2
FTIR (unconditioned)3
Run Time
12:10-18:18
12:10-18:18
12:20-14:20
14:15-15:50
15:50-18:15
12:11-18:37
12:10-18:18
12:20-14:20
14:15-15:50
15:50-18:15
11:16-17:03
11:15-17:03
11:14-13:34
13:30-14:16
14:16-17:03
11:16-17:03
11:15-17:03
11:14-13:34
13:30-14:16
14:16-17:03
06:20-12:55
06:21-12:56
06:18-08:48
08:45-10:05
10:05-12:55
06:20-12:55
06:21-12:56
06:18-08:48
08:45-10:05
10:05-12:55
'Sample not conditioned (moisture not removed) during first half of furnace charging
2Sample conditioned (moisture removed) during second half of furnace charging
3Sample unconditioned during mixing and tap out
2-3
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Table 2-2. Sample Volume Collected, dscm
Baghouse Location
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
"urnace 1 Inlet
-urnace 1 Inlet
'urnace 1 Outlet
Furnace 1 Outlet
Parameter
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
Run!
1.98
4.38
2.78
2.81
4.01 .
3.85
7.34
7.22
Run 2
2.16
4.66
3.06
3.04
3.90
3.72
7.54
7.03
Run 3
2.22
4.2
2.9
2.86
3.74
3.9
7.05
6.95
Run 4
NA
NA
NA
NA
3.72
3.87
7.47
7.58
Average
2.12
4.41
2.91
2.90
3.84
3.84
7.35
7.20
%RSD
5.89
5.25
4.82
4.17
3.58
2.07
2.95
3.90
Table 2-3. Flue Gas Volumetric Flow Rate, dscmm
Baghouse Location
Chip Dryer Inlet
Chip Dryer Inlet
Chip Dryer Outlet
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Inlet
Furnace 1 Outlet
"urnace 1 Outlet
Parameter
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
PM/HC1
D/F
Runl
142
156
153
153
720
689
835
807
Run 2
162
160
171
174
666
642
753
736
Run 3
143
- 148
159
166
674
688
723
748
Run 4
NA
NA
NA
NA
579
603
674
722
Average
149
155
161
164
660 .
656
746
753
%RSD
7.56
3.95
5.69
6.4
8.92
6.30
9.05
.4.96
2-4
-------
2.2 Dioxin/Furan Results
2.2.7 Overview
Three 4-hour D/F tests were performed at the inlet and outlet of the baghouse associated
with the chip dryer operation (total of 6) and four 6-hour tests were performed at the inlet and
outlet of the baghouse associated with the reverberatory furnace number 1 (total of 8). The
sampling and analysis procedures followed EPA Method 23 protocol. All results except for the
2,3,7,8-tetrachlorodibenzofuran (2,3,7,8-TCDF) were determined by high resolution gas
chromatography (HRGC)/high resolution mass spectrometry (HRMS) using a DB-5 capillary gas
chromatographic column. The 2,3,7,8-TCDF was determined by HRGC/HRMS using a DB-225
column which gives improved chromatographic resolution for this compound over the DB-5 and
thus a more accurate quantitation. Any compound that was not detected is reported as a "less
than" value with this value being the instrument detection limit. A "less than" value rather than a
"0" is used in all appropriate calculations. All D/F raw data can be found in Appendix B of this
report.
2.2.2 Dioxin/Furan Emission Results
Chip Drver
Tables 2-4 and 2-5 present the concentration, in nanograms per dry standard cubic meter
(ng/dscm), of the selected D/F congeners by run number, the average concentration over the three
runs and the %RSD for the chip dryer inlet and outlet, respectively. These values were
calculated by dividing the reported analytical results, in ng, by the appropriate sample volume
collected, in dscm, from Table 2-2. As indicated in Table 2-4 (dryer inlet), the concentration
values of several congeners in Runs 1 and 2 are presented as "greater than" values and should be
considered estimates. The amount of these analytes detected in the sample extracts exceeded the
calibration curve. The observed concentrations for Run 3 are generally lower by a factor of two
than those observed for Runs 1 and 2, causing the %RSDs for most analytes to be in the 40 to
2-5
-------
Table 2-4. Chip Dryer, Inlet D/F Stack Gas Concentration, ng/dscm
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6.7.8-HxCDD
1,2,3,7,8,9-HxCDD
1.2,3,4,6.7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2.3.4.7,8-HxCDF
1,2,3,6.7,8-HxCDF
2.3,4,6,7,8-HxCDF
1.2^3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1.2,3,4,7.8,9-HpCDF
OCDF
Runl
0.457
3.74
4.29
9.18
14.9
>29.9*
24.7
14.3
10.1
>18.4*
>22.1*
>13.5*
>18.8*
1.14
>28.8*
7.21
11.3
Inlet
Run 2
0.536
3.07
3.65
6.70
11.9
21.2
17.1
18.2
>14.48*
>20.9*
>27.3*
>17.0*
>23.0*
1.55
>32.6*
8.56
11.2
Run 3
0.205
1.50
1.43
2.86
4.48
9.60
8.21
4.17
' 4.55
8.40
15.4
6.43
8.19
0.357
18.5
2.17
4.14
Average
0.399
2:77
3.12
6.24
10.4
20.2
16.7
12.2
9.72
15.9
21.6
12.3
16.6
1.01
26.6
5.98
8.90
%RSD
43.4
41.6
48.1
51.0
51.4
50.4
49.4
59.3
51.3
41.6
27.6
43.7
45.7
59.5
27.5
56.4
46.3
*Sienal above calibration range
2-6
-------
Table 2-5. Chip Dryer, Outlet D/F Stack Gas Concentration, ng/dscm
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3.4,6,7, 8-HpCDD
OCDD
2,3,7,8-TCDF
1.2,3,7.8-PeCDF
2.3,4,7, 8-PeCDF
1,2.3.4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2.3,4,6,7,8-HxCDF
1. 2,3,7, 8.9-HxCDF
1.2.3,4,6,7.8-HpCDF
1, 2.3,4,7, 8,9-HpCDF
OCDF
Runl
0.890
3.63
1.21
1.60
2.63
1.92
1.14
17.6
18.8
24.2
15.3
7.01
4.38
0.242
4.16
0.498
0.605
Outlet
Run 2
0.461
2.17
0.559
0.888
1.25
0.855
0.493
8.62
10.8
14.4
9.54
4.21
2.73 .
0.122
2.37
0.257
0.270
Run 3
0.524
2.66
0.839
1.15
1.75
0.874
0.455
9.93
13.1
17.8
12.3
5.73
3.32
0.161
2.87
0.266
0.255
Average
0.625
2.82
0.869
1.21
1.88
1.22
0.696
12.0
14.2
18.8
12.4
5.65
3.48
0.175
3.13
0.340
0.377
%RSD
37.1
26.3
37.5
29.7
37.3
50.1
55.3
40.2
28.9
26.3
23.1
24.8
24.0
35.1
29.6
40.3
52.5
2-7
-------
50 range. The fact that different feed stocks or combinations of feed stocks were used for each of
the runs is the most probable explanation for this. The feed stock for Run 1 was continuous
during the run. The feed stock for Run 2 was the remainder of the feed stock used during Run 1
(depleted after approximately the first half of Run 2) plus a portion of a new feed stock of
different material and different oily coating. The feed stock for Run 3 was a combination of the
remainder of the second feed stock from Run 2 plus a third feed stock material with yet another
different oily coating. Each lot of feed stock material used during the testing was added to the
loading hopper as needed until it was depleted, followed by the next lot until it was depleted and
so on. Each lot of material was processed as a discrete material type and oily coating with no
mixing or blending of the three lots. Table 2-5 (dryer outlet) shows concentrations considerably
lower than the inlet for Runs 1 and 2, whereas for Run 3 the inlet and outlet values are similar.
The %RSDs generally in the 20 to 30 range still reflect the use of three different lots of feed
stock.
Table 2-6 shows the D/F stack emission rate from the chip dryer outlet in micrograms of
analyte per megagram (jag/Mg) of feed stock for each of the three runs, the average and the
%RSD. These values were calculated using standard conversion factors (i.e., pounds to grams)
and from the concentrations given in Table 2-5, the stack flow rates given in Table 2-3 and the
number of pounds of each feed stock consumed during the test period as supplied by the facility.
The latter data set (pounds of feed stock consumed) for each of the three runs was not a
straightforward calculation. Mitigating factors included:
• Each lot of feed was processed at a different rate;
• Combinations of feed stock were used during two of the runs; and
• Two of the feed stocks were processed beginning on one day, finishing on the
next day with the process shut down over night.
For run number one a single lot of feed stock was used, but it was processed over a two day
period (32,000 pounds in 8 hours on the first day during Run 1 and 4,740 pounds in 3.5 hours on
the next day during the first part of Run 2). The feed rate of feed stock consumed during Run 1
2-8
-------
Table 2-6. Chip Dryer, Outlet D/F Emission Rate, ug/Mg Feed
Congener
2,3,7,8-TCDD
1,2,3,7.8-PeCDD
1,2,3.4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1, 2,3,4,6,7, 8-HpCDD
OCD'D
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7, 8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3.4,6,7, 8-HxCDF
1,2,3,7,8,9-HxCDF
1. 2.3.4,6,7. 8-HpCDF
1.2,3.4,7.8.9-HpCDF
OCDF
Runl
4.50
18.3
6.12
8.10
13.3
9.71
5.76
88.9
94.8
122
77.2
35.4
22.1
1.22
21.0
2.52
3.06
Outlet
Run 2
5.41
25.5 .
6.56
10.4
14.7
10.0
5.79
101.2
126
170
112
49.4
32.0
1.43
27.8
3.01
3.17
Run 3
3.79
19.2
6.07
8.35
12.6
6.32
3.29
71.8
94.9
129
89.3
41.5
24.0
1.16
20.7
1 92
1.85
Average
4.57
21.0
6.25
8.96
13.5
8.69
4.95
87.3
105
140
92.8
42.1
26.1
1.27
232
248
2.69
%RSD
17.7
18.5
4.36
14.3
7.62
23.7
29.0
16.9
17.2
18.3
19.0
16.7
20.2
10.9
172
220
27.2
2-9
-------
was therefore calculated by dividing 32,000 by 8. The same logic was followed for Runs 2 and
3, except that two different lots were used during each run and the average feed rate was
therefore determined. The feed rate calculations are summarized below:
Run No.
1
2
2
3
3
Lot
1
1
2
2
3
Feed Time-Date
8 hrs- 12/5/97
3. 5 hrs- 12/6/97
8 hrs- 12/6/97
8 hrs- 12/6/97
2 hrs- 12/6/97
Pounds of Feed
32,000
4,740
20,500
20,500
7,000
Feed Rate
4,000 Ibs/hr
1,354
2,563
2,563
3,500
Avg. Feed Rate. Ibs/hr
4,000
1,959
3,032
Table 2-7 shows the D/F congener concentrations in ng/dscm converted to 2,3,7,8-TCDD
toxicity equivalents as well as a summation of the values presented as total chlorinated dioxins
and total chlorinated furans.
Reverberatorv Furnace #1
A total of four tests was performed collecting samples simultaneously at the inlet and
outlet of the baghouse associated with furnace number 1. Each test was performed over the
duration of a batch cycle starting at the time of the first furnace charge and ending at the time of
the last tap out, a period ranging from approximately five and one-half hours to six and one-half
hours. The same product was produced during each of the four tests. Each batch followed a
three stage process: charging, mixing and tap-out. Charging required approximately four hours
to complete, mixing one hour and tap-out one hour. The highest emissions were observed during
the charging process (as observed from the real time FTIR data for HC1). A "front-end loader"
Caterpillar tractor was used to charge feed stock or flux to the furnace approximately every ten
minutes during the charging stage. As each load was added emissions were visible in the form of
clouds of black smoke/soot which were captured by an overhead hood and directed to the
baghouse.
2-10
-------
Table 2-7. Chip Dryer, 2,3,7,8-TCDD Toxicity Equivalent Concentrations
Congener
2,3,7,8
TCDD
TEF1
ng/dscm
Run 1
Run 2
Run 3
Average
Inlet
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1.2,3,4,7,8-HxCDD
1,2,3,6,7.8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
Total PCDD
2.3,7,8-TCDF
1.2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF "
2,3,4.6,7,8-HxCDF
1,2,3,7,8.9-HxCDF
1.2,3.4,6,7,8-HpCDF
1,2,3,4,7,8.9-HpCDF
OCDF
Total PCDF
1.0
0.5
0.1
0.1
0.1
0.01
0.001
0.1
0.05
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.001
0.457
1.87
0.429
0.918
1.49
0.299
0.0247
1.43
0.506
9.18
2.21
1.35
1.88
0.114
0.288
0.0721
0.0113
0.536
1.53
0.365
0.670
1.19
0.212
0.0171
1.82
0.724
10.5
2.73
1.70
2.30
0.155
0.326
0.0856
0.0112
0.205
0.750
0.143
0.286
0.448
0.0960
0.00821
0.417
0.227
4.20
1.54
0.643
0.819
0.0357
0.185
0.0217
0.00414
0.399
1.39
0.312
0.624
1.04
0.202
0.0167
3.98
1.22
0.486
7.95
2.16
1.23
1.66
0.101
0.266
0.0598
0.00890
15.1
Outlet
2,3,7,8-TCDD
1,2.3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6.7,8-HxCDD
1, 2.3,7, 8.9-HxCDD
1.2,3,4,6,7,8-HpCDD
1.0
0.5
0.1
0.1
0.1
0.01
0.890
1.81
0.121
0.160
0.263
0.0192
0.461
1.09
0.0559
0.0888
0.125
0.00855
0.524
1.33
0.0839
0.115
0.175
0.00874
0.625
1.41
0.0869
0.121
0.188
0.0122
2-11
-------
Table 2-7. (Continued)
Congener
OCDD
Total PCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1. 2.3.4,6.7. 8-HpCDF
1.2.3,4,7,8,9-HpCDF
OCDF
Total PCDF
2,3,7,8
TCDD
TEF1
0.001
0.1
0.05
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.001
ng/dscm
Runl
0.00114
1.76
0.94
12.1
1.53
0.701
0.438
0.0242
0.0416
0.00498
0.000605
Run 2
0.000493
0.862
0.538
7.22
0.954
0.421
0.273
0.0122
0.0237
0.00257
0.000270
Run 3
0.000455
0.993
0.656
8.90
1.23
0.573
0.332
0.0161
0.0287
0.00266
0.000255
Average
0.000696
2.44
1.20
. 0.710
9.40
1.24
0.565
0.348
0.0175
0.0313
0.00340
0.000377
13.5
'Toxicity Equivalence Factor
Tables 2-8 and 2-9 present the concentration, in ng/dscm, of the selected D/F congeners
by run number, the average concentration over the three runs and the %RSD for the reverberatory
furnace No. 1 inlet and outlet, respectively. These values were calculated by dividing the
reported analytical results, in ng, by the appropriate sample volume collected, in dscm, from
Table 2-2. As indicated in Table 2-8 (furnace inlet) the concentration value of the
octachlorofuran in Run 2 is presented as a "greater than" value and should be considered an
estimate. The amount of this analyte detected in the sample extract exceeded the calibration
curve.
2-12
-------
Table 2-8. Reverberatory Furnace #1, Inlet D/F Concentration, ng/dscm
Congener
2.3,7,8-TCDD
1,2,3,7,8-PeCDD
L2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2.3,7,8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
1.2.3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6.7,8-HxCDF
1,2,3,7,8.9-HxCDF
1,2.3,4,6,7,8-HpCDF
1.2,3,4,7,8,9-HpCDF
OCDF
Runl
0.177
1.04
1.17
1.90
2.68
11.2
18.1
3.01
4.05
7.64
26.2
9.06
13.8
0.805
42.3
•6.44
37.4
Inlet
Run 2
0.191
1.34
1.45
2.18
3.20
14.9
23.4
4.33
4.22
8.58
26.6
9.54
14.5
0.833
53.8
9.27
177*
Run 3
0.156
0.872
0.949
1.46
2.13
8.44
12.1
2.69
3.54
6.10
18.7
6.64
9.87
0.641
27.4
4.38
20.4
Run 4
0.132
0.930
1.21
1.91 '
2.66
10.3
16.3
3.46
4.08
7.42
25.2
8.40
12.2
0.724
40.1
6.61
41.3
Average
0.164
1.05
1.20
1.86
2.67
11.2
17.5
3.37
3.97
7.43
24.2
8.41
12.6
0.751
40.9
6.68
68.9
%RSD
15.7
20.1
17.2
15.9
16.4
24.2
26.9
21.0
7.53
13.7
15.4
15.1
16.3
11.6
26.4
30.0
104.9
*Si«nal above calibration range
2-13
-------
Table 2-9. Reverberatory Furnace #1, Outlet D/F Concentration, ng/dscm
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1.2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4.7,8-HxCDF
1, 2,3.6 J,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Runl
0.00554*
0.0249
-0.0235
0.0374
0.0568
0.166
0.249
0.115
0.126
0.222
0.485
0.180
0.235
0.0125*
0.665
0.120
0.554
Outlet
Run 2
0.00284*
0.00711*
0.00284*
0.00569*
0.00853*
0.0228
0.0384
0.08 1 1
0.0413
0.0569
0.0768
0.0299
0.0327
0.00142*
0.0967
0.0156
0.171
Run 3
0.00576
0.00863*
0.00288*
0.00719*
0.00863*
0.0173
0.0230*
0.0993
0.0547
0.0734
0.0806
0.0302
0.0317
0.00144*
0.0590
0.00719*
0.0345
Run 4
0.00264*
0.00396*
0.00264*
0.00528*
0.00528*
0.0198
0.0317
0.0356
0.0198
0.0290 .
0.0580
0.0198
0.0264
0.00264*
0.0818
0.0106*
0.0607
Average
0.00419
0.0112
0.0080
0.0139
0.0198
0.0565
0.0856
0.0827
0.0604
0.0952
0.175
0.0650
0.0816
0.00449
.0.226
0.0385
0.205
%RSD
40.1
84.1
130
113
125
129
128
41.5
76.2
90.5
118
118
126
119
130
142
117
*Values below calibration curve and/or less than 5 x MDL; should be considered estimates
2-14
-------
The observed concentrations for the four runs at the inlet are generally of the same
magnitude as indicated by the low %RSDs. Table 2-9 (furnace outlet) shows the concentrations
to be considerably lower than those at the inlet by a factor of 10 to 100. Several of the analytes
exhibited a concentration level below the calibration curve, less than 5 times the detection limit
or not detected. These factors contribute to the high %RSD observed, not unusual in this
situation.
Table 2-10 shows the D/F stack emission rate from the furnace number 2 outlet in
jnicrograms of analyte per megagram (ug/Mg) of feed stock for each of the four runs, the average
and the %RSD. These values were calculated using standard conversion factors (i.e., pounds to
grams), the concentrations given in Table 2-9, the stack flow rates given in Table 2-3 and the
number of pounds of feed stock consumed during the test period as supplied by the facility.
Although the feed stock was added only during the first four hours of each batch, the feed rate
was calculated using the total pounds consumed divided by the length of the total batch process.
This calculation process was necessary to correspond with the emissions collected by the
integrated sample over the duration of the entire batch process including charging, mixing and
tap-out. The latter data set (pounds of feed stock consumed) for each of the four runs is given
below:
Run No.
1
2
3
4
Lot
Batch Time-Date
1 6 hrs-12/8/97
2 6.5 hrs-12/9/97
3 5.75 hrs-12/10/97
4 6.5 hrs-12/11/98
Feed Consumed. Ibs.
70,200
70,200
75,600
81,000
Feed Rate. lbs./hr
11,700
10,800
13,148
12,462
Table 2-11 shows the congener concentrations in ng/dscm converted to 2,3,7,8-TCDD
toxicity equivalents as well as a summation of the values presented as total chlorinated dioxins
and total chlorinated furans.
2-15
-------
Table 2-10. Reverberatory Furnace #1, Outlet D/F Emission Rate, ug/Mg Feed
Congener
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1, 2,3,4,6,7, 8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4.7.8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1. 2,3.4,7. 8,9-HpCDF
OCDF
Runl
0.0505
0.227
0.215
0.341
0.518
1.52
2.27
1.05
1.15
2.02
4.42
1.64
2.15
0.114
6.06
1.10
5.05
Outlet
Run 2
0.0256
0.0648
0.0259
0.0519
0.0778
0.207
0.350
0.739
0.376
0.519
0.700
0.272
0.298
0.0130
0.882
0.143
1.56
Run 3
0.0433
0.0649
0.0216
0.0541
0.0649
0.130
0.173
0.746
0.411
0.552
0.606
0.227 .
0.238
0.0108
0.444
0.0541
0.260
Run 4
0.0202
0.0303
0.0202
0.0404
0.0404
0.152
0.242
0.273
0.152
0.222
0.444
0.152
0.202
0.0202
0.626
0.0808
0.465
Average
0.0349
0.0968
0.0706
0.122
0.175
0.501
0.760
0.702
0.522
0.828
1.54
0.573
0.721
0.0394
2.00
0.344
1.83
%RSD
41.0
91.4
136
120
131
135
133
45.6
83.1
97.6
125
125
132
126
135
147
121
2-16
-------
Table 2-1.1. Reverberatory Furnace #1, 2,3,7,8-TCDD Toxicity Equivalent
Concentrations
Congener
Inlet
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1, 2,3,4.7, 8-HxCDD
1,2,3,6,7.8-HxCDD
1,2,3,7,8.9-HxCDD
1,2,3,4,6.7,8-HpCDD
OCDD
Total PCDD
2.3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7, 8-PeCDF
1,2,3,4,7.8-HxCDF
1,2,3, 6.7. 8-HxCDF
2.3,4.6.7,8-HxCDF
1, 2,3,7, 8.9-HxCDF
1. 2,3.4.6,7, 8-HpCDF
1.2,3.4.7,8.9-HpCDF
OCDF
Total PCDF
Outlet
2,3,7,8-TCDD
1.2.3,7,8-PeCDD
1,2,3.4,7.8-HxCDD
1,2,3,6.7,8-HxCDD
1, 2,3.7. 8,9-HxCDD
2,3,7,8-
1(_L)L>
TEF'
1.0
0.5
0.1
0.1
0.1
0.01
0.001
0.1
0.05
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.00 1
1.0
0.5
0.1
O.I
0 1
Run 1
0.177
0.519
0.117
0.190
0.268
0.112
0.0181
0.301
0.203
3.82
2.62
0.906
1.38
0.0805
0.423
0.0644
0.0374
0.00554
0.0125
0.00235
0.00374
0 00568
Run 2
0.191
0.672
0.145
0.218
0.320
0.149
0.0234
0.433
0.211
4.29
2.66
0.954
1.45
0.0833
0.538
0.0927
0.177
0.00284
0.00356
0 000284
0.000569
0 000853
ng/dscm
Run 3
0.156
0.436
0.095
0.146
0.213
0.084
0.0121
0.269
0.177
3.05
1.87
0.664
0.987
0.0641
0.274
0.0438
0.0204
0.00576
0.00432
0 000^88
0.000719
0 000863
Run 4
0.132
0.465
0.121
0.191
0.266
0.103
0.0163
0.346
0.204
3.71
2.52
0.840
1.22
0.0724
0.401
0.0661
0.0413
0.00264
0.00198
0 000264
0.000528
0 000528
Average
0.164
0.523
0.120
0.186
0.267
0.112
0.0175
1.39
0.337
0.199
3.72
2.42
0.841
1.26
0.075 1
0.409
0.0668
0.0689
9.39
0.00419
0.00558
0 000798
0.00139
0 00198
2-17
-------
Table 2-11. (Continued)
Congener
1,2,3,4,6,7,8-HpCDD
OCDD
Total PCDD
2,3,7.8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7, 8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1, 2,3.7, 8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1.2,3,4,7,8.9-HpCDF
OCDF
Total PCDF
2,3,7,8-
T/T\rfc
1CUU
TEF1
0.01
0.001
0.1
0.05
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.001
Run 1
0.00166
0.000249
0.0115
0.00630
0.111
0.0485
0.0180
0.0235
0.00125
0.00665
0.00120
0.000554
Run 2
0.000228
0.000038
0.00811
0.00206
0.0284
0.00768
0.00299
0.00327
0.000142
0.000967
0.000156
0.000171
ng/dscm
Run 3
0.000173
0.000023
0100993
0.00273
0.0367
0.00806
0.00302
0.003' 17
0.000144
0.000590
0.000072
0.000035
Run 4
0.000198
0.000032
0.00356
0.000989
0.0145
0.00580
0.00198
0.00264
0.000264
0.000818
0.000106
0.000061
Average
0.000565
0.0000856
0.0146
0.00827
0.00302
0.0476
0.0175
0.00650
0.00816
0.000449
0.00226
0.000385
0.000205
0.0944
'Toxicity Equivalence Factor
2.3 HCI Results
2.3.7 Overview
Three 4-hour HC1/C1-, tests were performed at the inlet and outlet of the baghouse
associated with the chip dryer operation (total of 6) and four 6-feour tests were performed at the
inlet and outlet of the baghouse associated with the reverberatory furnace number 1 (total of 8).
The sampling and analysis procedures followed EPA Method 26A protocol Prior to testing, the
plant personnel replaced all fabric filters in the baghouse with new ones and performed the
appropriate leak checks. All analyses were performed by ion chromatography using the samples
as received from the field. Any compound that was not detected is reported as a "less than"
2-18
-------
value with this value being the instrument detection limit. A "less than" value rather than a "0" is
used in all appropriate calculations. All HC1/C1, raw data can be found in Appendix C of this
report.
2.3.2 HCI Emission Results
Chip Dryer
The baghouse associated with the chip dryer is injected with lime (hydrated calcium
hydroxide) for the purpose of reducing HCI emissions. The reaction between the two compounds
forms calcium chloride and water. The lime injection to the baghouse was continuous at a feed
rate of approximately 50 pounds per hour. Table 2-12 gives the concentration, in micrograms per
dry standard cubic meters (^g/dscm), the average concentration over the three runs and the
%RSD for the inlet and outlet, respectively. The results for Run 3 inlet are invalid as the sample
was compromised during sample recovery in the field. Chlorine was not detected (at the
instrument detection limit) in any samples at either the inlet or the outlet. The HCI results for
Runs 1 and 2 inlet and Runs 1 and 2 outlet are very consistent among themselves with the outlet
concentrations representing about 3% of the amount entering the baghouse. Table 2-13 gives the
concentrations in parts per million (ppm) in order to provide an easy comparison to the FTIR
results which are also presented in ppm and provided in Section 2.5 of this report.
The emission rate of HC1/C12, in pounds/hour (Ibs/hr), was calculated using the
concentration results from Table 2-12 and the stack flow rate data from Table 2-3 and is
presented in Table 2-14. Using the average emission rates calculated for the inlet and the outlet,
a baghouse percent removal efficiency for HCI was determined to be 96.9%, as shown in
Table 2-15. The emission rate of HC1/CU was also determined as pounds per ton of feed stock
using the data given in Table 2-14 and the feed stock feed rates for the chip dryer given in
Section 2.2.2 above. These results are given in Table 2-16.
2-19
-------
Table 2-12. HCI and CI2 Concentration, |jg/dscm
Location
Chip Dryer Inlet1
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
Parameter
HCI
Cl,
HCI
Cl,
HCI
Cl,
HCI
Cl,
Runl
43704
<191
1367
<123
119887
188*
689
<66.2
Run 2
37254
<198
1899
<137
119768
4305
764
129*
Run 3
6102
<179
202
<168
66034
783
2379
<62.4
Run 4
NA
NA
NA
NA
109455
231*
1262
<45.6
*Less than 5 x MDL
'Run 3 compromised during sample recovery
Table 2-13. HCI and CI2 Concentration, ppm
Location
Chip Dryer Inlet1
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
Parameter
HCI
Cl:
HCI
C!2
HCI
Cl,
HCI
Cl,
Runl
29.6
<0.067
0.927
<0.043
81.3
0.066*
0.467
<0.023
Run 2
25.3
<0.069
1.288
<0.048
81.2
1.50
0.518
0.045*
Run 3
4.14
0.062
0.137
<0.058
44.8
0.273
1.61
<0.022
Run 4
NA
NA
NA
NA
74.2
0.081*
0.856
<0.016
*Less than 5 x MDL
'Run 3 compromised during sample recovery
2-20
-------
Table 2-14. HCI and Cl, Emission Rate, Ibs/hour
Location
Chip Dryer Inlet'
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
Parameter
HCI
C12
HCI
C12
HCI
C12
HCI
Cl,
Runl
0.820
<0.00359
0.0276
<0.00249
11.4
0.0179*
0.0760
<0.00731
Run 2
0.798
<0.00423
0.0429
<0.00310
10.5
0.379
0.0760
0.0128*
Run 3
0.115
<0.00338
0.00424
<0.00352
5.88
0.0698
0.227
<0.00596
Run 4
NA2
NA
NA
NA
8.38
0.0177*
0.112
<0.00407
Average
0.809
0.00391
0.0249
0.00304
9.05
0.121
0.123
0.00754
%RSD
NA
NA
78.1
17.1
27.3
143.4
58.3
50.0
*Less than 5 x MDL; should be considered an estimate
'Run 3 compromised during sample collection; Runs 1 and 2 used to calculate average
2NA=Not Applicable
Table 2-15. HCI Removal Efficiency
Location
Chip Dryer
Furnace #1, Cond. l'
Furnace #l,Cond. 22
Average Emission Rate, Ibs/hour
Inlet
0.809
10.97
7.13
Outlet
0.0249
0.0760
0.170
Removal
Efficiency, %3
96.9
99.3
97.6
Condition 1 = continuous lime feed, Runs 1 and 2
Condition 2 = 50 Ibs. lime every 2 hours, Runs 3 and 4
'Average of runs 1 and 2
2Average of runs 3 and 4
3Removal Efficiency = (inlet-outlet/inlet) x 100
2-21
-------
Table 2-16. HCI and CI2 Emission Rate, Ibs/Ton of Feed
Location
Chip Dryer Inlet'
Chip Dryer Outlet
-urnace 1 Inlet
Furnace 1 Outlet
Parameter
HCI
C12
HCI
C12
HCI
C12
HCI
Clr
Runl
0.410
0.00180
0.0138
0.00124
1.95
0.00305
0.0130
0.00125
Run 2
0.814
0.00432
0.0438
0.00317
1.95
0.0702
0.0141
0.00238
Run 3
0.0759
0.00222
0.00279
0.00232
0.895
0.0106
0.0346
0.000908
Run 4
NA2
• NA
NA
NA
1.34
0.00284
0.0180
0.000653
Average
0.612
0.00306
0.0201
0.00224
1.54
0.0217
0.0199
0.00130
%RSD
NA
NA
105
42.9
33.5
150
50.3
58.7
'Run 3 compromised during sample collection, Runs 1 and 2 used to calculate average
2NA, Not Applicable
Reverberatorv Furnace Number 1
The results for the reverberatory furnace #1 are given in Tables 2-12 through 2-16
following the same sequence as the chip dryer. During Test Runs 1 and 2, lime was fed
continuously to the baghouse (Condition 1). During Test Runs 3 and 4, lime was added to the
lime feed hopper at the rate of one 50 Ib bag every two hours (Condition 2). Lime was consumed
at the rate of approximately 50 pounds per 30 minutes during the test period. The concentration
results presented in Tables 2-12 and 2-13 for HCI for Runs 1 and 2 are consistent among
themselves for both the inlet and outlet. Run 4 inlet results were consistent with Runs 1 and 2.
However, the outlet results were approximately a factor of 2 higher than for Runs 1 and 2. The
fact that one of the four baghouse modules (module 4) had developed a leak and was off-line
could be a possible explanation for this observation. The Run 3 inlet HCI concentration was
observed to be approximately half that for the other runs, possibly because furnace C12 flow
supply was not turned on until at least an hour into the test.
2-22
-------
The baghouse removal efficiency for HC1 was determined for Condition 1 using the
average of the emission rate results from Runs 1 and 2 and for Condition 2 using the average of
Runs 3 and 4. The results are presented in Table 2-15. The removal efficiency for Condition 2
was slightly less than that for Condition 1, with both well above 95%. The emission rate of
HC1/C12 was also determined as pounds per ton of feed stock using the data given in Table 2-14
and the feed stock feed rates for the furnace given in Section 2.2.2, above. These results are
given in Table 2-16.
2.4 Participate Results
2.4.7 Overview
Paniculate matter emissions were determined from the same sampling trains used for the
determination of HC1 emissions. PM collected on the filter and in the front half acetone rinse
(nozzle, probe, front-half filter holder) was analyzed gravimetrically. PM stack concentrations in
grains per dry standard cubic meter (gr/dscm), PM emission rate in pounds per ton of feed
(Ibs/Ton) and pounds per hour (Ibs/Hr), and the PM removal efficiency of each baghouse as a
percent (%) for the chip dryer and furnace number 1 operations are presented below. The results
of the PM testing are presented in Tables 2-17 through 2-20. All raw data for the PM
determinations can be found in Appendix D.
2.4.2 Particulate Emission Results
Chip Dryer
Table 2-17 gives the concentration, in gr/dscm, the average concentration over the three
runs and the %RSD for the inlet and outlet. The average of the three runs was 20.3 and 0.778 for
the inlet and outlet, respectively.
2-23
-------
Table 2-17. Stack Gas Particulate Matter Concentration, gr/dscm
Baghouse Location
Chip Dryer Inlet
Chip Dryer Outlet
:urnace 1 Inlet
nirnace 1 Outlet
gr/dscm
Runl
27.8
2.07
7.33
0.142
Run 2
19.3
0.529
5.06
0.0242
Run 3
13.9
1.10
3.21
0.0103
Run 4
NA
NA
3.86
0.00599
Average
20.3
1.23
4.86
0.0455
%RSD
34.5
63.2
37.3
142
Table 2-18. Particulate Matter Emission Rate, Ibs/hour
Baghouse Location
Chip Dryer Inlet
Chip Dryer Outlet
Furnace 1 Inlet
-urnace 1 Outlet
Ibs/hour
Runl
33.8
2.71
45.2
1.01
Run 2
26.8
0.775
28.9
0.156
Run 3
17.0
1.49
18.5
0.0637
Run 4
NA
NA
19.1
0.0346
Average
25.9
1.66
27.9
0.317
%RSD
32.6
59.0
44.6
147
Table 2-19. Baghouse Particulate Removal Efficiency,%
Location
Chip Dryer Baghouse
:urnace 1 Baahouse
Ibs/hr
Avg. Inlet
Rate
25.9
27.9
Avg. Outlet
Rate
1.66
0.317
Removal
Efficiency %
93.6
98.9
2-24
-------
Table 2-20. Particulate Matter Emission Rate, Ibs/Ton of Feed
Baghouse Location
Chip Dryer Inlet
Chip Dryer Outlet
*urnace 1 Inlet
•urnace 1 Outlet
Ibs/ton of Feed
Run 1
16.9
1.35
7.73
0.173
Run 2
27.3
0.791
5.35
0.0289
Run 3
11.190
0.982
2.82
0.00970
Run 4
NA
NA
3.07
0.00555
Average
18.5
1.04
4.74
0.0543
%RSD
44.3
27.5
48.3
147
The emission rate of PM, in Ibs/hr, was calculated using the concentration results from
Table 2-17 and the stack flow rate data from Table 2-3 and is presented in Table 2-18. Using the
average emission rates calculated for the inlet and the outlet, a baghouse percent removal
efficiency for PM was determined to be 93.6%, as shown in Table 2-19. The emission rate of
PM was also determined as pounds per ton of feed stock using the data given in Table 2-18 and
the feed stock feed rates for the chip dryer given in Section 2.2.2 above. These results are given
in Table 2-20.
Reverberatorv Furnace Number 1
Table 2-17 gives the concentration, in gr/dscm, the average concentration over the four
runs and the %RSD for the inlet and outlet. The average of the four runs was 4.68 and 0.0455 for
the inlet and outlet respectively. The inlet PM concentrations for Runs 1 and 2 (condition 1) are
noticeably higher than for Runs 3 and 4 (condition 2), possibly due to the lower lime injection
rate that occurred during Runs 3 and 4. The high variability between the outlet results is due to
the low mass of PM present on the filters. Values near the limit of detection have inherent
increased variability.
The emission rate of PM, in Ibs/hr, was calculated using the concentration results from
Table 2-17 and the stack flow rate data from Table 2-3 and is presented in Table 2-18. Using the
2-25
-------
average emission rates calculated for the inlet and the outlet, a baghouse percent removal
efficiency for PM was determined to be 98.9%, as shown in Table 2-19. The emission rate of
PM was also determined as pounds per ton of feed stock using the data given in Table 2-18 and
the feed stock feed rates for furnace number 2 given in Section 2.2.2 above. These results are
given in Table 2-20.
2.5 FTIR Results
2.5.1 Overview
FTIR data for HCl and other species were collected at the inlet and outlet of the
.baghouses associated with the chip dryer and reverberatory furnace 1. FTIR data collection was
synchronized with manual HCl and dioxin/furan testing to allow semi-quantitative comparison of
the FTIR and manual HCl results. Due to partitioning of FTIR analysis time between
unconditioned and conditioned inlet/outlet samples, only 25% of FTIR data during a given run on
the chip dryer and 38% on the furnace were collected simultaneously with the corresponding
inlet or outlet manual train sampling.
FTIR data were collected at each location by alternating sample analysis between inlet
and outlet every 10 minutes. Both inlet and outlet sampling systems continuously withdrew
sample from their respective location. Each 10 minute measurement period contained ten 1
minute average data points. The first two data points from each period were discarded to
eliminate data for samples containing both inlet and outlet sample gas. Two data points
correspond to the measured response time of the complete FTIR sampling and analysis system
(see below for details on measurement of system response time) A 1 minute average data point
is generated by analysis of a composite spectrum consisting of an average of 43 FTIR spectra
collected over the 1 minute time period.
Section 2.1 gives the schedule of the tests performed at the Gulp facility. Both
unconditioned samples and conditioned samples were analyzed. Conditioned samples were
2-26
-------
generated by passing the raw sample gas through a water vapor/carbon dioxide scrubbing system
(See Section 5.3 for details). Unconditioned and conditioned samples extracted from the chip
dryer baghouse were measured during the first and last two-hour periods for each four hour run,
respectively. At the reverberatory furnace #1, the sampling order went as follows: 2 hours
unconditioned, 1 hour conditioned, and 2 hours unconditioned. Two unattended unconditioned
overnight runs were also conducted to look continuously at reverberatory furnace #1 hood
baghouse outlet emissions. Those results are reported in Section 2.5.2.2.
Baghouse removal efficiency for HC1 was measured from the inlet/outlet data from each
location and is reported in Section 2.5.2.2. Optimization of the reverberatory furnace 1 baghouse
for HC1 removal was also carried out. The removal efficiency was found to exceed 90% for all
tests at all lime injection rates tested.
EPA Method 301 validation tests for HC1 were carried out on the chip dryer baghouse
outlet, and reverberatory furnace #1 baghouse inlet and outlet. In all three tests, the Method 301
statistical calculations showed that the FTIR method demonstrated acceptable precision and no
statistically significant bias for HC1. Details of the validation results can be found in
Section 2.5.2.1.
A comparison of the FTIR and Method 26A results for both the chip dryer and furnace
tests are presented in Section 2.5.2.6
2.5.2 FTIR Emission Results
This section contains the FTIR EPA Method 301 HC1 validation results, HC1 test results,
and screening results for the chip dryer and reverberatory furnace #1 hood baghouse inlet and
outlet. Also included are results for the reverberatory furnace #1 hood baghouse HC1 removal
efficiency optimization tests.
2-27
-------
2.5.2.1 EPA Method 301 FTIR Validation Results for HCI
EPA Method 301 validation testing for HCI was performed on the chip dryer outlet, and
reverberatory furnace #1 hood inlet/outlet. The spiking procedure is given in Section 5.3.2. Five-
minute measurement periods were used for the chip dryer outlet, while 1-minute measurement
periods for both inlet and outlet of the reverberatory furnace #1 were used. The 1-minute periods
were used because of the rapidly fluctuating nature of the furnace emissions. Table 2-21
summarizes the validation results.
Table 2-21. Summary of EPA Method 301 FTIR Validation Results for HCI
Location
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
Date
12/03/97
12/07/97
12/07/97
Spiked/Unspiked
Precision
Acceptable?
Yes/Yes
Yes/Yes
Yes/Yes
Statistically
Significant
Bias?
No
No
No
Note: Acceptable precision is equal to or less than 50% RSD.
Detailed results of the validation testing can be found in Appendix E.
2.5.2.2 FTIR HCI Test Results
The estimated FTIR HCI detection limit for this study is 0.05 ppmv.
While it is instructive to compare HCI results from both FTIR and manual methods, care
must be taken in interpreting the two sets of results. The FTIR system measured HCI at a given
inlet or outlet only 25 % of the time; the corresponding manual method was integrated over the
entire sampling period. Half of the FTIR instrument analysis time was split equally between inlet
and outlet as unconditioned and conditioned samples. Since HCI was measured only in
2-28
-------
unconditioned samples, this sampling scheme results in a 25% duty cycle for the total run for
HC1 measurement at a given inlet or outlet. The potential difference between FTIR and manual
results will increase with greater fluctuations in the HC1 concentration during the run, since the
FTIR captures 25% of the manual method sample for a given inlet or outlet run. Greatest
fluctuation in HG1 was observed during charging operations on the furnace #1 inlet to the
baghouse.
Results given below are organized by location. HC1 removal efficiency was also
calculated for each run.
Chip Dryer Baghouse Outlet/Inlet HC1 Results—Table 2-22 gives a summary of the
chip dryer baghouse outlet/inlet FTIR HC1 results. The average inlet concentrations were
consistent between runs, but the outlet concentrations varied by a factor of 10.
During Run 1, a large slug of particulate matter filled the FTIR inlet heated filter
assembly which prevented sampling of the inlet gas. The FTIR system was allowed to measure
the outlet while the inlet filter system was cleaned; thirty more data points were therefore
measured on the outlet versus the inlet. These extra 30 data points were reported in the
preliminary data, but they are not included in the results presented in Table 2-22. The removal of
the extra 30 data points does not cause any significant changes in the Run 1 results, however.
Reverberatory Furnace 1 Baghouse Outlet/Inlet HC1 Results—Table 2-23 gives the
FTIR HC1 results for the reverberatory furnace baghouse inlet and outlet during charging of the
furnace with scrap aluminum. Table 2-24 shows the FTIR HC1 results for the reverberatory
furnace #1 hood baghouse inlet and outlet during tapping operations. In all cases, HC1 removal
efficiency due to the lime-injected baghouse was greater than 90 percent.
2-29
-------
Table 2-22. Chip Dryer FTIR HCI Results, ppmv
Date
Time
Location
Average
SD
Maximum
Minimum
NDP
RE
Runl
12/05/97
0800 - 0900
0930 - 1130
inlet
8.91
6.42
22.89
2.11
72
outlet
0.65
0.54
2.54
0.10
72
92.7
Run 2
12/06/97
0835 - 1040
inlet
8.25
11.67
52.05
1.22
48
outlet
5.30
4.17
19.28
1.16
48
35.8
Run 3
12/06/97
1546 - 1746
inlet
6.79
4.44
20.40
0.77
48
outlet
2.42
2.72
13.37
0.86
48
64.4
SD - Standard Deviation
NDP - Number of data points measured
RE- Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
Table 2-23. Reverberatory Furnace #1 Baghouse FTIR HCI Results During
Charging, ppmv
Date
Time
Location
Average
SD
Maximum
Minimum
NDP
RE
Run 1
12/08/97
945 - 1200
inlet
136.94
145.00
645.4
9.80
51
outlet
5.20
4.80
21.50
0.73
56
96.2
Run 2
12/09/97
1220-1420
inlet
58.48
122.37
756.72
7.59
48
outlet
2.72
1.15
6.76
1.14
48
95.3
Run 3
12/10/97
1114-1334
inlet
42.27
71.67
330.79
4.07
56
outlet
3.64
1.65
9.40
1.59
56
91.4
Run 4
12/11/97
0618 - 0848
inlet
132.42
159.55
634.60
12.25
64
outlet
4.57
3.46
14.39
1.36
56
96.6
SD - Standard Deviation
NDP - Number of data points measured
RE-Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
2-30
-------
Table 2-24. Reverberatory Furnace #1 Baghouse FTIR HCI Results During
Tapping, ppmv
Date
Time
Location
Average
SD
Maximum
Minimum
NDP
RE
Runl
12/08/97
inlet
57.95
19.84
89.16
.13.83
56
outlet
2.17
0.66
3.85
1.30
64
96.3
Run 2
12/09/97
1555 - 1825
inlet
54.54
34.67
155.58
0.93
64
outlet
1.96
0.68
3.85
1.06
56
96.4
Run 3
12/10/97
1430 - 1710
inlet
46.84
21.47
84.51
2.27
64
outlet
1.59
0.48
3.07
0.94
64
96.6
Run 4
12/11/97
0958 - 1258
inlet
41.09
15.57
63.45
0.94
72
outlet
1.58
0.58
3.59
0.72
72
96.2
SD - Standard deviation
NDP - Number of data points measured
RE-Removal Efficiency percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
Tables 2-23 and 2-24 clearly show that the respective inlet and outlet concentrations
during charging are somewhat higher on average than during tapping. This result is expected,
due to the nature of the loading process, where hydrocarbons from oils coated on the charge
material provide the source of hydrogen for HCI production. Tapping operations do not involve
the addition of any material to the furnace, so the HCI levels would be expected to be lower.
Further examination of the data shows that the standard deviation of HCI inlet and outlet
levels during loading is significantly higher than during tapping. This variation stems from the
greater variation in the HCI emissions during loading due to the periodic addition of hydrocarbon
material to the furnace. During tapping operations, the furnace is not charged, and less variation
is expected.
Tables 2-25 and 2-26 are the combined loading and tapping results and a grand average of
all 4 runs, respectively. The combined results were generated by an average of the respective
2-31
-------
Table 2-25. Combined Charging and Tapping Reverberatory Furnace #1
Baghouse FTIR HCI Results, ppmv
Date
Location
Average
RE
Run 1
12/08/97
Inlet
95.60
Outlet
3.58
96.25
Run 2
12/09/97
Inlet
56.23
Outlet
2.31
95.89
Run 3
12/10/97
Inlet
44.71
Outlet
2.55
94.30
Run 4
12/11/97
Inlet
84.07
Outlet
2.89
96.56
RE- Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
Table 2-26. Reverberatory Furnace #1 Baghouse FTIR HCI Results -
Grand Average, ppmv
Location
Average
RE
Inlet
70.15
Outlet
2.83
95.96
RE- Removal Efficiency in percent: 100 X (Avg. inlet- Avg. outlet)/Avg. inlet
data in Tables 2-23 and 2-24 weighted by the number of sample points. Computation of the
grand average was a simple unweighted average of the 4 runs.
Table 2-27 gives the FTIR HCI results of the unconditional reverberatory furnace 1
baghouse outlet during two overnight periods.. Five minute averages were collected for each data
point, instead of the usual 1 minute average collected in all other tests.
2.5.2.3 FTIR Process Optimization
The reverberatory furnace #1 hood baghouse HCI destruction efficiencies were measured
as a function of lime injection rate. Examination of Table 2-23 shows there is no apparent effect
of lime injection rate on the measured removal efficiency. Runs 1 and 2 utilized a continuous
lime injection at a rate of 50 Ibs per half hour. Runs 3 and 4 examined the emissions during a
lime
2-32
-------
Table 2-27. Reverberatory Furnace #1 Hood Baghouse Outlet HCI Results
Overnight, ppmv
Date
Time
Location
Average
Standard
Deviation
Maximum
Minimum
Number of
Data Points
Runl
12/(09-10)/97
1947 - 1015
Outlet
0.40
0.44
2.09
0.00
174
Run 2
12/(10-ll)/97
1815-0415
Outlet
0.45
0.48
2.60
0.00
120
injection rate of 50 Ibs per half hour period with 50 Ib being added every 2 hours. In all cases,
90+ percent HCI removal efficiency was obtained.
2.5.2.4 FTIR Screening Results
Screening data for species other than HCI were collected concurrently with the HCI data.
FTIR spectral data were examined for any other species present in the samples. Conditioned
samples were measured to estimate concentrations of aromatic and some hydrocarbon species.
Unconditioned samples were analyzed for other hydrocarbon and criteria species.
Tables 2-28 and 2-29 give summary statistics on the dominant species detected besides
HCI for the chip dryer inlet and outlet, respectively. Tables 2-30 and 2-31 are the screening
results for the furnace 1 inlet and outlet, respectively. In addition to HAP species, non-HAP
species are also reported to aid in understanding of the process chemistry, if desired.
2-33
-------
Table 2-28. Other Species Detected by FTIR - Chip Dryer Inlet
2
1
2
u/c
Average
Std.
Dev.
Max.
Min.
NDP
EDL
8
0>
W
c
5.97
4.25
17.15
<0.2
144
0.2
•*•*
C
0.86
0.60
2.03
0.11
144
0.05
V
g
i
u
CO
C
0.74
0.47
1.87
<0.1
144
O.I
•
g
.c
Ol
s
C
3.51
4.00
18.46
<0.2
144
0.2
u
•a
j;
2
u
0
ta.
U
3.12
8.63
59.64
0.25
168
0.1
u
•a
JS
ai
•d
2
u
"*'•
U
2.49
9.77
56.14
<0.5
168
0.5
'£-
O
(J
U
1.66
0.39
2.48
0.04
168
0.04
0
U
U
184.47
90.81
391.87
49.14
168
0.08
0
U
13.22
4.52
23.95
<3.5
168
3.5
O
z
u
4.16
4.67
14.63
<0.8
168
0.8
33
U
•U
12.08
16.15
125.62
4.45
168
2.0
q,
u
4.53
1.94
10.32
<0.8
168
0.8
+'
(j
U
1.99
5.81
33.32
<0.1
168
O.I
^
•— •
O
£
U
6.86
1.65
10.44
3.18
168
0.0001
to
All values are estimated ppmv, except CO2 and H2O in percent
Statistics of three runs combined
U/C - Unconditioned (U) or Conditioned (C) Sample
C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
NDP - Number of data points
EDL - Estimated detection limit for spectral region used for analysis
-------
Table 2-29. Other Species Detected by FTIR - Chip Dryer Outlet
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ethylene
C
5.99
4.05
17.50
0.42
142
0.2
Acetylene
C
0.87
0.59
2.19
0.09
142
0.05
Benzene
C
0.76
0.48
2.06
<0.1
142
0.1
Methanol
C
3.45
4.59
20.84
<0.2
142
0.2
Formaldehyde
U
1.35
0.76
4.65
0.37
198
O.I
Acetaldehyde
U
0.49
0.62
4.39
<0.5
198
0.5
2
6'
u
u
1.64
0.27
2.35
0.89
198
0.04
O
U
u
174.31
84.61
355.41
8.41
198
0.08
O
z
u
14.49
3.09
22.53
8.37
198
3.5
ft
o
z
u
1.17
2:23
8.06
<0.8
198
0.8
af
u
u
8.16
3.07
19.37
<2.0
198
2.0
O
r«
Z
U
4.30
1.69
9.01
<0.8
198
0.8
+
U
U
0.96
1.47
11.50
<0.1
198
0.1
8
o
r»
U
6.73
1.71
10.17
2.97
198
0.0001
10
All values are estimated ppmv, except CO2 and H2O in percent
Statistics of three runs combined
U/C - Unconditioned (U) or Conditioned (C) Sample
C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
NDP - Number of data points
EDL - Estimated detection limit lor spectral region used for analysis
-------
Table 2-30a. Other Species Detected by FTIR - Reverberatory Furnace #1 Inlet
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ethylene
C
2.16
3.34
17.17
<0.2
104
0.2
Acetylene
C
4.08
7.74
39.16
<0.05
104
0.05
Benzene
C
1.73
2.87
12.48
<0.1
104
0.1
Methanol
C
0.48
0.62
3.76
<0.2
104
0.2
Formaldehyde
U
0.46
1.10
9.66
<0.1
473
O.I
Acetaldehyde
U
0.05
0.39
6.79
<.5
473
0.5
S
«•»
O
U
U
0.14
0.23
1.96
<0.04
473
0.04
O
u
u
45.01
73.88
425.92
1.76
473
0.08
O
Z
U
2.18
5.77
48.90
<2.0
473
2.0
1,3 - butadiene
C
0.17
0.64
6.01
<0.8
104
0.8
SB
U
U
12.25
12.49
91.75
<2.0
473
2.0
O
ft
Z
U
0.84
0.57
5.92
<0.3
473
0.3
+
U
U
0.61
0.80
15.02
<0.1
473
0.1
S
O
»•»
SB
U
1.43
0.59
4.58
0.49
473
0.0001
O\
All values are estimated ppmv, except CO2 and H2O in percent
Statistics of four runs during loading and tapping combined
U/C - Unconditioned (U) or Conditioned (C) Sample
.C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
NDP - Number of data points
EDL - Estimated detection limit for spectral region used for analysis
-------
Table 2-30b. Other Species Detected by FTIR - Reverberatory Furnace #1 Inlet, continued
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ammonia
U
0.04
O.I6
3. 15
<0.1
473
0.1
Propylene
C
0.39
1.63
16.01
<0.4
104
0.4
Sulfur dioxide
U
6.10
10.79
74.85
<1.2
473
1.2
to
OJ
-J
All values are estimated ppmv
Statistics of four runs during loading and tapping combined
U/C - Unconditioned (U) or Conditioned (C) Sample
NDP - Number of data points
EDL - Estimated detection limit for spectral region used for analysis
-------
Table 2-31 a. Other Species Detected by FTIR - Reverberatory Furnace #1 Outlet
L.
Ol
2
K)
Ou
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ol
Ol
W
C
2.51
3.00
13.50
<0.2
88
0.2
Ol
Ol
t
^ji
C
4.82
7.44
31.31
<0.05
88
0.05
Ol
Ol
N
Ol
ca
C
1.58
2.30
9.57
<0.l
88
O.I
o
a
^
C
0.49
0.64
2.24
<0.2
88
0.2
Ol
•a
01
2
g
o
U
0.32
0.37
2.71
<0.l
477
O.I
;*,
01
2
Ol
U
0.15
1.46
31.26
<0.4
477
0.5
/— S
6*
o
u
0.13
0.18
1.20
<0.04
477
0.04
O
U
U
46.34
71.04
385.37
0.99
477
0.06
O
z
u
1.83
4.11
24.72
<2.0
477
0.8
01
C
Ol
•a .
3
s
i
rf)
C
0.15
0.50
3.03
<0.6
88
0.6
X
U
u
11.14
9.70
86.53
<0.6
477
2.0
O,
z'
U
0.82
0.49
4.08
<0.1
477
0.1
U
U
0.52
0.64
13.07
<0.04
477
0.04
, — .
^
•-^
0
3G
U
1.44
0.65
3.84
0.42
477
0.0001
NJ
i
U)
oo
All values are estimated ppmv, except CO2 and H2O in percent
Statistics of four runs during loading and lapping combined
U/C - Unconditioned (U) or Conditioned (C) Sample
C4+ - Total aliphatic hydrocarbons larger than 3 carbons (ppmv hexane equivalent)
NDP - Number of data points
EDL - Estimated detection limit for spectral region used for analysis
-------
Table 2-31 b. Other Species Detected by FTIR - Reverberatory Furnace #1 Outlet,
continued
Parameter
U/C
Average
Std. Dev.
Max.
Min.
NDP
EDL
Ammonia
U
0.06
0.17
2.92
<0.1
477
0.1
Propylene
C
0.55
1.77
12.96
<0.4
88
0.4
Sulfur dioxide
U
0.91
2.84
24.88
<.1.2
477
1.2
All values are estimated ppmv
Statistics of four runs during loading and tapping combined
U/C - Unconditioned (U) or Conditioned (C) Sample
NDP - Number of data points
EDL - Estimated detection limit for spectral region used for analysis
2.5.2.5 FTIR Sampling and Measurement System Response Time Measurement
FTIR system sampling and measurement system response time was determined by
measurement of concentration versus time of a dynamic spike of the sample gas. HC1 and SF6
spike gas were introduced via a remote-controlled solenoid valve located upstream of the heated
probe filter. The time required to obtain 90 percent response was measured three times.
Figure 2-1 illustrates data gathered on-site which show the three measurements. It is clear from
the figure that the 90 percent response time is approximately 2 minutes (i.e., two data points).
The figure also shows that the SF6 and HC1 response times are approximately the same, with HC1
slightly lagging relative to SF6.
2-39
-------
to
i-
o
FTIR System Response
(3 measurements)
15.00
o
1 10.00
•s f
o>
§ ~
5.00
0.00
19:19
1 minute data points
19:24
19:29
Time
HC1
SF6
0.00
19:34
Figure 2-1. FTIR System Response Profile (Measured on 7 December 1997)
-------
2.5.2.6 Comparison of FTIR and Method 26A Results for HCI
Table 2-32 shows the comparison between the two sets of results for both the chip dryer
and furnace.
Table 2-32. Comparison of FTIR and Method 26A results for HCI, ppm1
Location
Chip Dryer Inlet
Chip Dryer Outlet
Furnace 1 Inlet
Furnace 1 Outlet
FTIR
8.12
2.48
70.15
2.83
Method 26A
27.45.
1.10
70.37
0.862
'Average of test runs at each location
While it is instructive to compare HCI results from both FTIR and manual methods, care
must be taken in interpreting the two sets of results. For the chip dryer, the FTIR system
measured HCI at a given inlet or outlet only 25 % of the time compared to the corresponding
manual method which was integrated over the entire sampling period, due to splitting half of the
FTIR instrument analysis time equally between inlet and outlet as unconditioned and conditioned
samples. Since HCI was measured only in unconditioned samples, this sampling scheme results
in a 25% duty cycle for the total run for HCI measurement at either the chip dryer inlet or outlet.
The corresponding FTIR data capture for either the furnace inlet #1 or outlet was approximately
38%.
Future testing which incorporates both FTIR and Method 26A should include full
concurrent sampling to facilitate unbiased comparison between the two methods.
2-41
-------
3.0 DESCRIPTION OF FACILITY
(To be supplied by Research Triangle Institute).
3-1
-------
4.0 SAMPLING LOCATIONS
The sampling locations that were used during the emissions testing program at Gulp
Aluminum Alloys are described in this section. Flue gas samples were collected at the inlet and
at the outlet of the lime-injected baghouses using manual methods and FTIR, with two 4" ID
ports to allow for the operation of two manual sampling methods and one 3" ID port for the
FTIR. The configurations of the sampling locations are shown in Figures 4-1 (El, chip dryer
baghouse inlet), 4-2 (E2, chip dryer baghouse outlet), 4-3 (E3, reverberatory furnace #1 baghouse
inlet), and 4-4 (E4, reverberatory furnace #1 baghouse outlet).
The chip dryer operated at approximately 150° F, with a slightly negative pressure at the
fan inlet and a slightly positive pressure at the outlet. At the inlet and outlet of the reverberatory
furnace #1 baghouse, 4" ports were available. FTIR ports were installed horizontally and
upstream from manual ports. The baghouse operated at approximately 175° F, with a slightly
positive pressure.
The inlet of the lime-injected baghouse for the chip dryer was a circular duct 18" in
diameter, and the outlet was a circular duct 25" in diameter. Two 4" ID ports were installed at
90 degrees to each other, one horizontally and one vertically on top of the duct, and a third 3" ID
port was installed upstream of the other ports for the FTIR sampling probe.
The inlet to the reverberatory furnace #1 baghouse was a circular duct 42" in diameter.
Two 4" ports and one 3" port were installed; the two 4" ports were 90 degrees to each other. The
outlet was an exhaust stack 48" in diameter, approximately 30 feet above the ground. The outlet
had two 4" ports; a third port (3" ID) was installed for the FTIR upstream of the other two ports.
The position and number of traverse points for each location are shown in Figures 4-5 through
4-8. For stacks having diameters greater than 0.61 m (24 in.), no traverse points were located
within 2.5 cm (1.00 in.) of the stack walls.
4-1
-------
To Baghouse
1 Inlet, Dryer Baghouse
\
Building
Wall
A
\
18"
^ riow
"TpW' ^/
Fan
\
I ^
55" 48"
, •„
i
Ground
•figure 4-1. E1, Chip Dryer Baghouse Inlet
-------
Outlet
Chip Dryer
Baghouse
4" ID Manual
Ports
3" ID FTIR
Port
Lime Injection
Figure 4-2. E2, Chip Dryer Baghouse Outlet
-------
Reverberatory
Furnace
3" ID FTIR
Port
4" ID Ports
Flow
To Baghouse
20'
48'
Lime shed
w
*S^W* -J " j t. 1 s '
•*^v;\.
Flame Arrester
Figure 4-3. E3, Reverberatory Furnace Bagho^fie Inlet
-------
Exhaust
Handrail
Catwallc
48"
6'
3" FTIR
Port
24'
Fan
Ground
10'
Figure 4-4. E4, Reverberatory Furnace Baghouse Outlet
-------
O€
18"
17.2
ooo
Figure 4-5. Chip Dryer Baghouse Inlet, Traverse Points
-------
Figure 4-6. Chip Dryer Baghouse Outlet, Traverse Points
-------
oo
Figure 4-7. Reverberatory Furnace Baghouse Inlet Traverse Points
-------
Figure 4-8. Reverberatory Furnace Baghouse Outlet Traverse Points
-------
For stack diameters equal to or less than 0.61 m (24 in.), no traverse points was located
within 1.3 cm (0.50 in.) of the stack walls. When any of the traverse points fell within 2.5 cm
(1.00 in.) of the stack walls, they were relocated to a distance of 2.5 cm (1.00 in.) or a distance
equal to the nozzle inside diameter, whichever was larger.
All test ports and their locations met the requirements of EPA Method I.
4-10
-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES BY ANALYTE
The sampling and analytical procedures used for the Gulp Aluminum Alloys plant test
program are the most recent revisions of the published EPA methods. In this section,
descriptions of each sampling and analytical method by analyte are provided.
5.1 Chlorinated Dibenzo-p-Dioxin and Chlorinated Dibenzofuran Emissions
Testing Using EPA Method 23
The sampling and analytical method for determining flue gas emissions of
Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans (CDD/CDF) is EPA
Method 23. .
5.1.1 Method 23 Sampling Equipment
The method uses the sampling train shown in Figure 5-1. The Method 23 sampling
system is similar to a Method 5 train with the following exceptions:
• All components (glass probe/nozzle liner, all other glassware, filters) are pre-
cleaned using solvent rinses and extraction techniques; and
• A condensing coil and XAD-2® resin absorption module are located between
the filter and impinger train.
5.1.2 Method 23 Equipment Preparation
In addition to the standard EPA Method 5 requirements, Method 23 includes several
unique preparation steps which ensure that the sampling train components are not contaminated
with organics that may interfere with analysis. The glassware, glass fiber filters and absorbing
resin are cleaned and the filters and resin are checked for 42 residuals before they are packed.
5-1
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stack wall
Gas Flow
Ul
to
temperature
sensor
1 Ir
—
heated glass liner
> n_
1 c ' I
1
heat
r
L
]
1
id
~1
J
i
cc
condenser
filter
holder
"S" type
pilot
manometer
temperature
sensor
XAD-2 trap
temperature
sensor
t
recirculation
pump
calibrated
orifice
gas exit
manometer
L
ifyg
met
T,
r
c
as
sr
H
Zl
;
empty
•
-"
^
r
1
KJ rtJ |tJ ftJ mJ
ice
bath
^ ^ A i
x A A
100ml ^^ .,~
HPLC Water empty SI"C,a
gel
fine
Mr —^ vacuum
Y I 9aU9e
V
^ coarse
( ) -^^t- vacuum pump
Figure 5-1. Method 23 Sampling Train Configuration
-------
5.1.2.1 Glassware Preparation
The glassware preparation procedure is shown in Table 5-1. Glassware is washed in
soapy water, rinsed with distilled water, baked and then rinsed with acetone followed by
methylene chloride. Clean glassware is allowed to dry under a hood loosely covered with foil to
prevent laboratory contamination. Once the glassware is dry, the air exposed ends are sealed
with methylene chloride rinsed aluminum foil. All the glass components of the sampling train
including the glass nozzles plus any flasks, petri dishes, graduated cylinders and pipets that are
used during sampling and recovery will be cleaned according to this procedure. Non-glass
components (such as the Teflon -coated filter screens and seals, tweezers, Teflon squeeze
bottles. Nylon® probe brushes and Nylon nozzle brushes) are cleaned following the same
procedure except that no baking is performed.
5.1.2.2 XAD-2® Resin and Filter Preparation
XAD-2® absorbing resin and glass fiber filters are pre-cleaned by separate procedures
according to the specified method. Only pesticide grade solvents and HPLC grade water are used
to prepare for organic sampling, and to recover these samples. The lot number, manufacturer and
grade of each reagent used are recorded in the laboratory notebook.
To prepare the filters, a batch of 50 is placed in a Soxhlet extractor pre-cleaned by
extraction with toluene. The Soxhlet is charged with fresh toluene and refluxes for 16 hours.
After the extraction, the toluene is analyzed as described in Sections 5.1 and 5.3 of the reference
method (EPA Method 23) for the presence of tetrachlorodibenzo-p-dioxins (TCDD) and
tetrachlorodibenzofurans (TCDF). If these analytes are found, the filters are re-extracted until the
analyte is not detected. The filters are then dried completely under a clean nitrogen (N2) stream.
Each filter is individually checked for holes, tears, creases or discolorations, and if any are found,
the filter is discarded. Acceptable filters are stored in a pre-cleaned petri dish, labeled by date of
analysis and sealed with Teflon® tape.
5-3
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Table 5-1. Method 23 Glassware Cleaning Procedure
(Train Components, Sample Containers and Laboratory Glassware)
NOTE: USE VTTON® GLOVES AND ADEQUATE VENTILATION WHEN RINSING
WITH SOLVENTS
1. Soak all glassware in hot soapy water (laboratory detergent).
2. Rinse with tap water to remove soap.
3. Rinse with HPLC-grade H2O, three times
4. Bake at 450° F for 2 hours.3
5. Rinse with acetone (pesticide grade), three times.
6. Rinse with methylene chloride (pesticide grade), three times.
7. Cap glassware with clean glass plugs or methylene chloride rinsed aluminum foil.
8. Mark cleaned glassware with color-coded identification sticker.
9. Rinse glassware immediately before using with acetone and methylene chloride
(laboratory proof)-
a Step (4) has been added to the cleanup procedure to replace the dichromate soak specified in the
reference method. ERG has demonstrated in the past that baking glassware sufficiently removes
organic artifacts. Step 4 is not used for probe liners and non-glass components of the train that
cannot withstand 450° F (i.e., Teflon®-coated filter screen and seals, tweezers, Teflon® squeeze
bottles, Nylon probe and nozzle brushes).
5-4
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To prepare the absorbing resin, the XAD-2 resin is cleaned in the following sequential
order:
• Rinse with HPLC grade water, discard water;
• Soak in HPLC grade water overnight, discard water;
• Extract in Soxhlet with HPLC grade water for 8 hours, discard water;
• Extract with methanol for 22 hours, discard solvent;
• Extract with methylene chloride for 22 hours, discard solvent;
• Extract with methylene chloride for 22 hours, retain an aliquot of solvent for
analysis of CDDs and CDFs by HRGC/HRMS; and
• Dry resin under a clean N2 stream.
Once the resin is completely dry, it is checked for the presence of methylene chloride,
CDDs and CDFs as described in Section 3.1.2.3.1 of the reference method. If any analytes are
found, the resin is re-extracted. If methylene chloride is found, the resin is dried until the excess
solvent is removed. The absorbent is to be used within four weeks of cleaning.
The cleaned XAD-2® resin is spiked before shipment to the field with five CDD/CDF
internal standards. Due to the special handling considerations required for the internal standards,
the spiking is performed by Triangle Laboratories. For convenience and to minimize
contamination, Triangle Laboratories also performs the resin and filter cleanup procedures and
loads the resin into the glass traps.
5.1.2.3 Method 23 Sampling Train Preparation
The remaining preparation includes calibration and leak checking of all sampling train
equipment, including meter boxes, thermocouples, nozzles, pitot tubes, and umbilicals.
5-5
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Referenced calibration procedures are followed when available. The results are properly
documented in a laboratory notebook or project file and retained.
5.1.3 Method 23 Sampling Operations
5.1.3.1 Preliminary Measurements
Prior to sampling (data collected during presurvey), preliminary measurements are
required to ensure isokinetic sampling. These measurements include determining the traverse
point locations, performing a preliminary velocity traverse, cyclonic flow check and moisture
determination. These measurements are used to calculate a "K factor." The K factor is used to
determine an isokinetic sampling rate from stack gas flow readings taken during sampling.
Measurements are then made of the duct inside diameter, port nozzle length, and the
distances to the nearest upstream and downstream flow disturbances. These measurements are
then used to determine sampling point locations by following EPA Reference Method 1
guidelines. The distances are then marked on the sampling probe using an indelible marker.
5.1.3.2 Assembling the Train
Method 23 sampling train components are collected in the recovery trailer and final
train assembly is performed at the stack location. First, the empty, clean impingers are
assembled and laid out in the proper order in the recovery trailer. Each ground glass joint is
carefully inspected for hairline cracks. The first impinger is a knockout impinger which has a
short tip. The purpose of this impinger is to collect condensate which forms in the coil and
XAD-2® resin trap. The next two impingers are modified tip impingers which each contain
100 mL of HPLC grade water. The fourth impinger is empty, and the fifth impinger contains 200
to 300 grams of blue indicating silica gel. After the impingers are loaded each impinger is
weighed, the initial weight and contents of each impinger are recorded on a recovery data sheet.
The heights of all the impingers are approximately the same to obtain a leak free seal. The open
5-6
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ends of the train are sealed with methylene chloride-rinsed aluminum foil, or clean ground glass
caps.
: The second step is to load the filter into the filter holder in the recovery trailer. The
filter holder is then capped off and placed with the resin trap and condenser coil (capped) into the
impinger bucket. A supply of precleaned foil and socket joints is also placed in the bucket in a
clean plastic bag for the convenience of the samplers. Sealing greases are not used to avoid
contamination of the sample. The train components are transferred to the sampling location and
assembled as previously shown in Figure 5-1. The heated probe and filter box will be a single
®
unit mounted on a vertical monorail. The chilled impinger box with the condenser and XAD-2
trap will be placed on the floor of the scaffolding.
5.1.3.3 Sampling Procedures
After the train is assembled, the heaters for the probe liner and heated filter box are
turned on and the sorbent module/condenser coil recirculating pump is turned on. When the
system reaches the appropriate temperatures, the sampling train is ready for pre-test leak
checking. The temperature of the sorbent module resin must not exceed 50° C (120° F) at any
time and during testing it must not exceed 20° C (68° F). The filter temperature is maintained at
120 ±14° F (248 ±25° F). The probe temperature is maintained above 100° C (212° F).
The sampling trains are leak checked at the start and finish of sampling. (Method 5/23
protocol only requires post-test leak checks and recommends pre-test leak checks.) ERG
protocol also incorporates leak checks before and after every port change. An acceptable pre-test
leak rate is less than 0.02 acfm (ft3/min) at approximately 15 inches of Hg, If during testing, a
piece of glassware needs to be emptied or replaced, a leak check is performed before the
glassware piece is removed, and after the train is re-assembled.
To leak check the assembled train, the nozzle end is capped off and a vacuum of
15 inches Hg is pulled in the system. When the system is evacuated, the volume of gas flowing
5-7
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through the system is timed for 60 seconds. After the leak rate is determined, the cap is slowly
removed from the nozzle end until the vacuum drops off, and then the pump is turned off. If the
leak rate requirement is not met, the train is systematically checked by first capping the train at
the filter, at the first impinger, etc., until the leak is located and corrected.
After a successful pre-test leak check has been conducted, all train components are at
their specified temperatures and initial data are recorded (DGM reading), the test can be initiated.
Sampling train data are recorded periodically on standard data forms. A checklist for CDD/CDF
sampling is included in Table 5-2. A sampling operation that is unique to CDD/CDF sampling is
that the gas temperature entering the resin trap must be below 20° C (68° F). The gas is cooled
by a water jacket condenser through which ice water is circulated.
The leak rates and sampling start and stop times are recorded on the sampling task log.
Also, any other events that occur during sampling are recorded on the task log such as sorbent
module heat excursions, pitot cleaning, thermocouple malfunctions, heater malfunctions or any
other unusual occurrences.
If the probe liner breaks while DGM is not running (i.e., during port changes or after the
run is completed), the probe liner is replaced, the run is completed, and sample recovery done on
both the broken sections of the glass liner and the replacement liner. If the break occurs while
the DGM is running and the exact time of the break is noted, the test is stopped so that the probe
liner can be replaced. The run is then completed and sample recovery done on all liner sections.
If the recovered sample appears unusual, the sample is discarded and an additional run is
performed later. If the recovered sample appears normal, the run is tentatively acceptable.
At the conclusion of the test run, the sample pump (or flow) is turned off, the probe is
removed from the duct, a final DGM reading is taken, and a post-test leak check is completed.
The procedure is identical to the pre-test procedure. However, the vacuum should be at least
one inch Hg higher than the highest vacuum attained during sampling. An acceptable leak rate is
less than 4% of the average sample rate or 0.02 acfm (whichever is lower).
5-8
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Table 5-2. CDD/CDF Sampling Checklist
Before test starts:
1. Check impinger set to verify the correct order, orientation and number of impingers. Verify
probe markings, and remark if necessary.
2. Check that you have all the correct pieces of glassware. Have a spare probe liner, probe
sheath, meter box and filter ready to go at location.
3. Check for data sheets and barometric pressure.
4. Prepare bag sampling equipment for CO2/O2, except when using CEMs for CO2/O2
determinations.
5. Examine meter box - level it, zero the manometers and confirm that the pump is operational.
6. Verify the filter is loaded correctly and as tightly as possible; place filter in line with the
train and leak check at 15 inches Hg.
7. Add probe to train.
8. Check thermocouples - make sure they are reading correctly.
9. Conduct pitot leak check, recheck manometer zero.
10. Do final leak check; record leak rate and vacuum on sampling log.
11. Turn on variacs and check to see that the heat is increasing.
12. Check that cooling water is on and flowing. Add ice to impinger buckets.
13. Check isokinetic K-factor - make sure it is correct. (Refer to previous results to confirm
assumptions. Two people should calculate this independently to double check it.)
5-9
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Table 5-2. COD/CDF Sampling Checklist (continued)
During Test:
1. Notify field task leader of any sampling problems ASAP. Train operator should fill in
sampling log and document any abnormalities.
2. Perform simultaneous/concurrent testing with other locations (if applicable). Maintain filter
temperature between 248 ° F ±25 ° F. Keep temperature as steady as possible. Maintain the
resin trap and impinger temperatures below 68° F. Maintain probe temperature above
212° F.
3. Leak check between ports and record on data sheet. Leak check if the test is stopped to
change silica gel, to decant condensate, or to change filters.
4. Record sampling times, rate, and location for the fixed gas bag sampling (CO, CO2, O2), if
applicable.
5. Blow back pitot tubes periodically if moisture entrapment is expected.
6. Change filter if vacuum suddenly increases or exceeds 15 inches Hg.
7. Check impinger solutions every ¥2 hour; if the knockout impinger is approaching full, stop
test and empty it into a pre-weighed bottle and replace it in the train.
8. Check impinger silica gel every Vi hour; if indicator color begins to fade, request a prefilled,
preweighed impinger from the recovery trailer.
9. Check the ice in the impinger bucket frequently. If the stack gas temperatures are high, the
ice will melt at the bottom rapidly. Maintain condenser coil and silica gel impinger gas
temperatures below 20° C (68° F).
After test is completed:
1. Record final meter reading.
2. Do final leak check of sampling train at maximum vacuum during test.
5-10
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Table 5-2. CDD/CDF Sampling Checklist (continued)
3. Do final pitot leak check.
4. Check completeness of data sheet. Verify the impinger bucket identification is recorded on
the data sheets. Note any abnormal conditions.
5. Leak check, check functions (level, zero, etc.) of pitot tubes and inspect for tip damage.
6. Disassemble train, cap sections, and take each section and all data sheets down to recovery
trailer.
7. Probe recovery (use 950 mL bottles)
a) Bring probes into recovery trailer (or other enclosed area).
b) Wipe the exterior of the probe to remove any loose material that could contaminate the
sample.
c) Carefully remove the nozzle/probe liner and cap it off with prerinsed aluminum foil.
d) For acetone rinses (all trains)
Attach precleaned cyclone flask to probe to catch rinses
Wet all sides of probe interior with acetone
- While holding the probe in an inclined position, put precleaned probe brush down
into probe and brush it in and out
- Rinse the brush, while in the probe, with acetone
- Do this at least 3 times until all the particulate has been recovered.
Recover acetone into a preweighed, prelabeled sample container
e) Follow the procedure outlined in (d) using methylene chloride. Recover the solvent
into the same acetone recovery bottle.
f) Follow the procedure outlined in (d) using toluene. Recover this solvent into a separate
preweighed prelabeled sample container.
8. Cap both ends of nozzle/probe liner for the next day, and store in dry safe place.
9. Make sure data sheets are completely filled out, legible, and give them to the field task
leader.
5-11
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5.1.4 CDD/CDF Sample Recovery
To facilitate transfer from the sampling location to the recovery trailer, the sampling
train is disassembled into the following sections: the probe liner, filter holder, filter to condenser
glassware, condenser and sorbent module, and the impingers in their bucket. Each of these
sections is capped with methylene chloride rinsed aluminum foil or ground glass caps before
removal to the recovery trailer. Once in the trailer, field recovery follows the scheme in
Figure 5-2. The samples are recovered and stored in cleaned amber glass bottles to prevent light
degradation.
The probe and nozzle are first rinsed with approximately 100 mL of acetone and
brushed to remove any paniculate. This first rinse is followed with a rinse of methylene
chloride. Both of these rinses are collected in the same bottle. The same two solvents are used
to rinse the cyclone, front/back half filter holder, filter support, connecting glassware and
condenser. These rinses are added to the probe rinse bottle. All of the components listed above
are again rinsed with toluene, but collected in a separate container. In addition, the Teflon®
transfer line used with the vertical sampler will be filled with toluene and allowed to stand for
5 minutes before adding to the toluene rinses. The filter is carefully removed from the filter
holder, placed in a pre-labeled petri dish and sealed with Teflon® tape for transport to the
laboratory.
The contents of impingers 1-4 (H2O) and impinger 5 (silica gel) are weighed to 0.5 mg
and then discarded.
The solvents used for train recovery are all pesticide grade. The use of the highest
grade reagents for train recovery is essential to prevent the introduction of chemical impurities
which interfere with the quantitative analytical determinations.
5-12
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Probe Probe Cyclone Front Half of Filler Back Half of Connecting Condenser
N
Rinse w
ozzle L
th Acetone A
ner
tach
Filler 1
Housing Sup
port Filter H
jusing Lii
ie
Until all Paniculate 250 mL flask Brush and Brush and
is Removed to Ball Joint rinse with rinse with Rinse with Rinse with Rinse with Rinse with
acetone (3x) acetone (3x) acetoi
Rinse wi
Rinse with
Acetone
Empty Flask
into 950 mL
Bottle
Brush Liner and Rinse
with 3 Aliquols of
Acetone
Check Liner to see if
Paniculate is
removed; if not, repeat
h 3 Aliquots Rin
se with R
nse with Rins
e with
.ofMethylene 3 Aliquots 3 Aliquots 3 Aliquols
Chloride ofMelhylene ofMelhylene ofMethylene
Chloride Chloride Chloride
Rinse
with Rin
se with Rin
se with Rin<
Rcco
ic (3x) acetone (3x) acelon
e (3x) acetone (3x)
Rinse with melhylene Rinse with Rinse with
chloride (3x) (at least methylene melhylene
once let the rinse stand chloride chloride (3x)
5 min in unit) (3x) (at least once let
the rinse stand
ver into
pieweighed
b(
Mile
PR
5 min in unit)
e with Rinse with Toluene (3x) Rinse with Toluene (3x) (at
Toluene (3x)* Toluene (3x) Toluene (3x) Toluene (3x) (at least once let the rinse Toluene (3x) least once let the
stand 5 min in unit) rinse stand 5 inin
*This fraction should not be combined with the other toluene
fractions
I'RT/CRT
in uni
)
Figure 5-2. Method 23 Field Recovery Scheme
-------
u»
Fil
ter
Carefully
remove filler
from support
with tweezers
Brush loose
Paniculate
onlo Tiller
Seal in
pelri
dish
F' . .„ .
Resin
Trap Istlm
(knoc
jinger 2nd Itn
kout)
pinger 3rd Im
pinger 4lh Im
pinger 5th Im
(silic
•
pinger
a gel)
Secure XAD Weigh Weigh Weigh Weigh Weigh
trap openings Impingcr Impingcr Impinger linpinger . Impinger
with glass balls
and clamps
Place in cooler Record weigh! Record weigh! Record weight Record weight Record weight
for storage and and and • and and
calculate gain calculate gain calculate gain calculate gain calculate gain
i'SM 1
Discard
Note: See Table 5-3 for Sample Fractions Identification
Sav
efor
regeneration
Figure 5-2. Method 23 Field Recovery Schedule (continued)
-------
The train components recovered in the field are listed in Table 5-3. All recovered
samples are stored in coolers on ice at all times. The samples will be delivered to the analytical
laboratory upon return to ERG accompanied by written information designating target analytes.
Table 5-3. Method 23 Sample Fractions Shipped To Analytical Laboratory
Container/
Component
1
2
3
4
Code
F
PRa
PRT
CRT
SM
Fraction
Filter(s)
Acetone and methylene chloride rinses of
nozzle/probe, cyclone, front half/back filter
holder, filter support, connecting
glassware, condenser
Toluene rinse of nozzle/probe, cyclone,
front half/back half filter holder, filter
support, connecting line and condenser
®
XAD-2 resin trap (sorbent module)
"Rinses include acetone and methylene chloride recovered into the same sample bottle.
5.1.5 CDD/CDF Analytical Procedures
The analytical procedure used to obtain analyte concentrations from a single flue gas
sample is high resolution gas chromatography (HRGC) and high resolution mass spectrometry
(HRMS) (resolution from 8000-10000 m/z). The target CDD/CDF congeners are listed in
Table 5-4. The analysis was performed by Triangle Laboratories, Inc., by Method 23/8290.
The Method 23 samples are prepared and analyzed according to the scheme in
(R)
Figure 5-3. The XAD-2 and filter (along with the concentrated acetone/methylene chloride
rinses) are placed in a Soxhlet extractor and extracted with toluene. This extract is added to the
toluene train rinses and then concentrated by rotary evaporation. This concentrated sample
extract is added to the toluene train rinses and then concentrated by rotary evaporation. This
concentrated sample is subjected to a sample cleanup procedure before analysis. For the
5-15
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Table 5-4. CDD/CDF Congeners To Be Analyzed
DIQXINS:
2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD)
Total tetrachlorinated dibenzo-p-dioxins (TCDD)
i,2,3,7,8-pentachlorodibenzo-/?-dioxin(l,2,3,7,8-PeCDD)
Total pentachlorinated dibenzo-p-dioxins (PeCDD)
1,2,4,5,7,8-hexachlorodibenzo-p-dioxin (1,2,3,4,7,8-HxCDD)
l,2,3,6,7,8-hexachlorodibenzo-/7-dioxin(l,2,4,5,7,8-HxCDD)
l,2,3,7,8,9-hexachlorodibenzo-p-dioxin(l,2,3,7,8,9-HxCDD)
Total hexachlorinated dibenzo-p-dioxins (HxCDD)
l,2,3,4,6,7,8-heptachlorodibenzo-p-dioxin(l,2,3,4,6,7,8-HpCDD)
Total heptachlorinated dibenzo-p-dioxins (HpCDD)
Total octachlorinated dibenzo-p-dioxin (OCDD)
FURANS:
2,3,7,8-tetrachlorodibenzofurans(2,3,7,8-TCDF)
Total tetrachlorinated dibenzofurans (TCDF)
1,2,3,7,8-pentachlorodibenzofuran (1,2,3,7,8-PeCDF)
2,3,4,7,8-pentachlorodibenzofuran(2,3,4,7,8-PeCDF)
Total pentachlorinated dibenzofurans (PeCDF)
l,2,3,4,7,8-hexachlorodibenzofuran(l,2,3,4,7,8-HxCDF)
1,2,3,6,7,8-hexachlorodibenzofuran (1,2,3,6,7,8-HxCDF)
2,3,4,6,7,8-hexachlorodibenzofuran(2,3,4,6,7,8-HxCDF)
l,2,3,7,8,9-hexachlorodibenzofuran(l,2,3,7,8,9-HxCDF)
Total hexachlorinated dibenzofuran (HxCDF)
l,2,3,4,6,7,8-heptachlorodibenzofuran(l,2,3,4,6,7,8-HpCDF)
1,2,3,4,7,8,9-heptachlorodibenzofuran (1,2,3,4,7,8,9-HpCDF)
Total heptachlorinated dibenzofurans (HpCDF)
Total octachlorinated dibenzofuran (OCDF)
5-16
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Toluene
Rinses
Rotovap
to 1 mL
Add to SOX
for Toluene
Extraction
AC/MeCl2
Rinses
KDto
1 mL
Add to SOX for Toluene
Extraction
Spike with
PCDD/PCDF Standards
Soxhlet in Toluene
XAD-2®
Prespiked with
5
PCDD/PCDF
Standards
Filter +
XAD-2® Add
to Soxhlet
Split 1:1
50% Toluene Extract to
Dioxins
Do PCDDs/Fs Cleanup
Analyze for PCDDs/Fs Method 8290X
Figure 5-3. Extraction and Analysis Schematic for Method 23 Samples
5-17
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CDD/CDF analysis, isotopically-labeled surrogate compounds and internal standards and
surrogates that are used are described in detail in EPA Method 23.
Data from the mass spectrometer are recorded and stored on a computer file as well as
printed on paper. Results such as amount detected, detection limit, retention time, and internal
standard and surrogate standard recoveries are calculated by computer. The chromatograms are
retained by the analytical laboratory and also included in the analytical report delivered to ERG.
5.1.5.1 Preparation of Samples for Extraction
Upon receiving the sample shipment, the samples are checked against the chain-of
custody forms and then assigned an analytical laboratory sample number. Each sample
component is reweighed to determine if leakage occurred during travel. Color, appearance, and
other particulars of the samples are noted. Samples are extracted within 21 days of collection
and processed through cleanup procedures before concentration and analysis.
5.1.5.2 Calibration of GC/MS System
A five-point calibration of the GC/MS system is performed to demonstrate instrument
linearity over the concentration range of interest. Relative response factors are calculated for
each dioxin/furan congener or compound of interest. The response factors are verified on a daily
basis using a continuing calibration standard consisting of a mid-level standard. The instrument
performance is acceptable only if the measured response factors for the labeled and unlabeled
compounds and the ion-abundance ratios are within the allowable limits specified in the method.
5.1.6 CDD/CDF Analytical Quality Control
All quality control procedures specified in the test method are followed. Blanks are
used to determine analytical contamination, calibration standards are used for instrument
calibration and linearity checks, internal standards are used to determine isomer recoveries and
5-18
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adjust response factors for matrix effects, surrogate standards are used to measure the collection
efficiency of the sampling methodology and an alternate standard is used as a column efficiency
check.
5.1.6.1 CDD/CDF Quality Control Blanks
Four different types of sample blanks are collected for CDD/CDF analysis. The types
of blanks that are required are shown in Table 5-5.
Table 5-5. Method 23 Blanks Collected
Blank
Field Blanks
Glassware Proof Blank
Method Blank
Reagent Blanks
Collection
One run collected for each
sample location) and
analyzed
Each train to be used (2) will
be loaded and quantitatively
recovered prior to sampling
At least one for each
analytical batch (laboratory
generated)
One 500 mL sample for each
reasent and lot
Analysis
Analyze with field samples
Archive for potential analysis
Analyze with each analytical
batch of field samples
Archive for potential analysis
Reagent blanks of 500 mL of each reagent used at the test site are saved for potential
analysis. Each reagent blank is of the same lot as was used during the sampling program: Each
lot number and reagent grade is recorded on the field blank label and in the laboratory notebook
®
(acetone, methylene chloride, toluene, filter. XAD-2).
A glassware blank (proof blank) is recovered from each set of sample train glassware
that is used to collect the organic samples. The precleaned glassware, which consists of a probe
liner, filter holder, condenser coil, and impinger set, is loaded as if for sampling and then
quantitatively recovered exactly as the samples will be. Analysis of the generated fractions will
be used to check the effectiveness of the glassware cleaning procedure only if sample analysis
indicates a potential contamination problem.
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A field blank is collected from a set of CDD/CDF glassware that has been used to
collect at least one sample and has been recovered. The train is re-loaded, leak checked and left
at a sampling location during a test run. The train is then recovered. The purpose of the field
blank is to measure the level of contamination that occurs from handling, loading, recovering,
leak checking, and transporting the sampling train. The field blanks are analyzed with the flue
gas samples. If they are unsatisfactory in terms of contamination, reagent blanks may be
analyzed to determine the specific source of contamination.
In addition to the three types of blanks that are required for the sampling program, the
analytical laboratory will analyze a method blank with each set of flue gas samples. This method
blank will consist of preparing and analyzing an aliquot of toluene by the exact procedure used
for the samples analysis. The purpose of this method blank is to verify that there is no
laboratory contamination of the field samples.
5.1.6.2 Quality Control Standards and Duplicates
Recoveries of the internal standards must be between 40 to 130% for the tetra- through
hexachlorinated compounds and in the range of 25 to 130% for the hepta- and octachlorinated
homologs. If these requirements are not met, the data will be acceptable if the signal to noise
ratio is greater than or equal to ten. If these requirements are met, the results for the native
(sampled) species are adjusted according to the internal standard recoveries.
Surrogate standard recoveries must be between 70 to 130%. If the recoveries of all
standards are less than 70%, the project director will be notified immediately to determine if the
surrogate results will be used to adjust the results of the native species.
Duplicate analysis is performed for every ten samples. The purpose of this duplicate
analysis is to evaluate the precision of the combined sample preparation and analytical
methodology.
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5.1.7 Analytes and Detection Limits for Method 23
The target analytes are the tetra- through octachlorinated dibenzodioxins and
chlorinated dibenzofurans. The detection limit of the individual compounds is dependent on the
detection limit of the analytical method, the volume of the final extract and the total volume of
gaseous sample collected in the sampling trains. Following the protocol of Method 23, the
fractions to be collected for analysis from each train are:
• Fraction I—Filter;
• Fraction 2—XAD-2 sorbent module;
• Fraction 3—Acetone and methylene chloride rinses of all train components prior
to sorbent module and;
• Fraction 4—Toluene rinses of all train components prior to the sorbent module.
Following the sample preparation protocol outlined in Method 23, a single combined
sample is presented for analysis for D/F by high resolution gas chromatography/high resolution
mass spectrometry. (The individual samples will no longer be available for analysis.) The final
volume of this sample is 200 fu.L of which a 2 /J.L aliquot is injected into the instrument. Using
an instrument detection limit of 50 pg for tetra-, 250 pg for penta- through hepta-, and 500 pg for
octachlorinated D/F, the total minimum detectable amounts can be calculated and are given in
Table 5-6.
Using a four hour sampling time at an assumed sampling rate of 0.65 to 0.75 cfm, the
MDLs shown in Table 5-7 are possible. The sampling flow rate at the outlet location will be
dictated by the flow rate of the stack gas since isokinetic sampling will be performed.
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Table 5-6. Analytical Detection Limits For Dioxins/Furans
Analyte
Tetra CDDs
PentaCDDs
Hexa CDDs
Hepta CDDs
Octa CDD
Tetra CDFs
Penta CDFs
Hexa CDFs
Hepta CDFs '
Octa CDF
Total Detectable Amount, ng
"5
25
25
25
50
5
25
25
25
50
NOTE: D/F analysis by High Resolution Mass Spectrometry assumes a 2 /uL injection of a 200 /uL sample
extract.
Table 5-7. CDD/CDF Method Detection Limits
Sampling Time, Hours
Sampling Rate, cfm
Sample Volume, nv1
Tetra CDDs
PentaCDDs
Hexa CDDs
Hepta CDDs
Octa CDD
Tetra CDFs
Penta CDFs
Hexa CDFs
Hepta CDFs
Octa CDF
4
0.75
5.1
MDL, ng/m3
0.98
4.9
4.9
4.9
9.8
0.98
4.9
4.9
4.9
9.8
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5.2 Hydrochloric Acid/Particulate Matter Emissions Testing Using EPA
Method 26A
Hydrogen chloride (HC1) sampling is accomplished using EPA Method 26A,
Determination of Hydrogen Halide and Halogen Emissions from Stationary Sources - Isokinetic
Method. Method 26A is particularly suited for sampling at sources emitting acid particulate
matter (i.e., hydrogen chloride dissolved in water droplets). In this method, a gas sample is
extracted isokinetically from the stationary source and passed through acidified water. In
acidified water, HC1 solubilizes and forms chloride (CI~) ions. Ion chromatography (1C) is used
to detect the chloride ions present in the sample. In addition, sampling for Particulate Matter
(PM) is also performed according to the EPA Method 26A protocol. This method is applicable
to the determination of particulate mass emissions collected on a glass fiber filter and any
material that condenses at or above the filter temperature of 120±14°C (248±25°F) from various
types of process controls and combustion sources. The particulate mass, which includes any
material that condenses at or above the filter temperature, is determined gravimetrically after
removal of uncombined water.
Particulate concentrations are based on the weight gain of the filter and any condensible
PM recovered from the acetone rinses of the probe, nozzle, and front half of the filter.
5.2.1 Method 26A Sampling Equipment
The EPA Method 26A methodology uses the sampling train shown in Figure 5-4. The
5-impinger train consists of a borosilicate glass nozzle/probe liner followed by a heated filter
assembly with a Teflon" filter support, a series of impingers and a meter box and vacuum pump
as specified in EPA Method 5. The sample is not exposed to any metal surfaces in this train.
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to
Slack
Temperature /a
Sensor
Gooseneck
Nozzle
Thermometer
Glass Filter Holder
X
Thermometer
S-Type Pilot Tube
Impingers with Absorbing Solution
(see below)
Manometer
Figure 5-4. Schematic of Method 26A Sampling Train
-------
The contents of the sequential impingers are:
• Impinger #1 (Greenburg-Smith) and Impinger #2 (Greenburg-Smith), known
volumes of 0. IN H2SO4 (nominal 100 mL);
• Impinger #3 (modified Greenburg-Smith) and Impinger #4 (modified Greenburg-
Smith), known volumes of 0.1 N NaOH;
• Impinger #5 (modified Greenburg-Smith), indicating silica gel.
5.2.2 Method 26A Sampling Equipment Preparation
5.2.2.1 Glassware Preparation
Glassware is washed in soapy water, rinsed with hot tap water, rinsed with Type n
water, rinsed with acetone to remove the water, rinsed three times with acetone and then air
dried. This procedure is used on all the glass components of the sampling train including the
glass nozzles plus any sample bottles, Erlenmeyer flasks, petri dishes, and graduated cylinders.
Non-glass components (such as the Teflon®-coated filter screens and seals, tweezers, Teflon®
squeeze bottles, Teflon" probe brushes) are cleaned following the same procedure. The cleaning
procedure is summarized in Table 5-8.
5.2.2.2 Reagent Preparation
The sample train filters are Pallflex® TX40HI45 Teflon® mat filters that meet the
criteria specified in Section 3.1.1 of EPA Method 5. These filters are used as received from the
vendor. The acetone is purchased as HPLC grade to ensure a low residue after evaporation. The
reagent water is distilled/deionized grade that meets the requirements of ASTM Type 3 water or
equivalent. The lot number, manufacturer and grade of each reagent that is used are recorded in
the laboratory notebook.
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Table 5-8. Glassware Cleaning Procedure
(Method 26A Train Components)
NOTE: USE DISPOSABLE GLOVES AND ADEQUATE VENTILATION
1. Soak all glassware in hot soapy water (laboratory detergent).
2. Rinse with tap water to remove soap.
3. Rinse with HPLC grade water (three times).
4. Rinse with acetone (three times).
5. Air dry.
6. Cap glassware with clean glass plugs or Parafilm.®
7. Mark cleaned glassware with color-coded identification sticker.
The analyst wears both safety glasses and protective gloves when the reagents are
mixed or handled. Each reagent has its own designated transferTeflon® squeeze bottle and is
marked for identification and used only for the reagent for which it is designated.
5.2.2.3 Equipment Preparation
The remaining preparation includes calibration and leak checking of all of the train
equipment, including meter boxes, thermocouples, nozzles, pitot tubes, and umbilicals.
Referenced calibration procedures are followed when available, and the results are properly
documented and retained. A discussion of the techniques used to calibrate this equipment is
presented below.
Type-S Pitot Tube Calibration. The EPA has specified guidelines concerning the
construction and geometry of an acceptable Type-S pitot tube. If the specified design and
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construction guidelines are met, a pitot tube coefficient of 0.84 is used. Information pertaining to
the design and construction of the Type-S pitot tube is presented in detail in Section 3.1.1 of EPA
Document 600/4-77-0275. Only Type-S pitot tubes meeting the required EPA specifications are
used. Pitot tubes are inspected and documented as meeting EPA specifications prior to field
sampling.
Sampling Nozzle Calibration. Glass nozzles are used for isokinetic sampling.
Calculation of the isokinetic sampling rate requires that the cross sectional area of the sampling
nozzle be accurately and precisely known. All nozzles are thoroughly cleaned, visually inspected
and calibrated according to the procedure outlined in Section 3.4.2 of EPA Document 600/4-77-
027b.
Temperature Measuring Device Calibration. Accurate temperature measurements
are required during source sampling. Bimetallic stem thermometers and thermocouple
temperature sensors are calibrated using the procedure described in Section 3.4.2 of EPA
Document 600/4-77-027b. Each temperature sensor is calibrated at a minimum of two points
over the anticipated range of use against a NIST-traceable mercury-in-glass thermometer. All
sensors are calibrated prior to field sampling.
Drv Gas Meter Device Calibration. Dry gas meters (DGMs) are used in the Method 5
sampling trains to monitor the sampling rate and to measure the sample volume. All DGMs are
calibrated to document the volume correction factor just prior to shipping of the equipment to the
field. Post-test calibration checks are performed as soon as possible after the equipment has been
returned to the ERG Laboratpry. Pre- and post-test calibration should agree to within 5%.
Prior to calibration, a positive pressure leak check of the system is performed using the
procedure outlined in Section 3.3.2 of EPA Document 600/4-77-237b. The system is placed
under approximately 10 inches of water pressure and a gauge oil manometer is used to determine
if a pressure decrease can be detected over a one-minute period. If leaks are detected, they are
eliminated before actual calibration are performed.
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After the sampling console is assembled and leak checked, the pump is to run for
15 minutes, to allow the pump and DGM to warm up. The valve is then adjusted to obtain the
desired flow rate. For the pre-test calibration, data are collected at orifice manometer settings
(AH) of 0.5, 1.0, 1.5, 2.0, 3.0 and 4.0 in H20. Gas volumes of 5 ft3 are used for the two lower
orifice settings, and volumes of 10 ft3 are used for the higher settings. The individual gas meter
correction factors (Yj) are calculated for each orifice setting and averaged. The method requires
that each of the individual correction factors fall within ±2% of the average correction factor or
the meter is cleaned, adjusted, and recalibrated. In addition, ERG requires that the average
correction factor be within 1.00 ±1%. For the post-test calibration, the meter is calibrated three
times at the average orifice setting and vacuum which were used during the actual test.
5.2.3 Method 26A Sampling Operations
5.2.3.1 Preliminary Measurements
Prior to sampling, preliminary measurements are required to ensure isokinetic sampling.
These preliminary measurements include determining the traverse point locations, performing a
preliminary velocity traverse and a cyclonic flow check. These measurements are used to
calculate a "K factor." The K factor is used to determine an isokinetic sampling rate from stack
gas flow readings taken during sampling.
Measurements are then made of the duct inside diameter, port nozzle length, and the
distances to the nearest upstream and downstream flow disturbances. These measurements are
then used to determine sampling point locations by following EPA Reference Method 1
guidelines. The distances are then marked on the sampling probe using an indelible marker.
5.2.3.2 Assembling the Train
Assembling the Method 26A sampling train components is begun in the recovery trailer
and final train assembly is performed at the stack location. First, the empty, clean impingers are
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assembled and laid out in the proper order in the recovery trailer. Each ground glass joint is
carefully inspected for hairline cracks. After the impingers are loaded, each impinger is weighed,
and the initial weight and contents of each impinger are recorded on a recovery data sheet. The
impingers are connected together using clean glass U-tube connectors and arranged in the
impinger bucket. The height of all the impingers is approximately the same to obtain a leak free
seal. The open ends of the train are sealed with Parafilm® or clean ground glass caps.
The second step is to load the filter into the filter holder in the recovery trailer. The
filter holder is then capped off and placed into the impinger bucket. To avoid contamination of
the sample, sealing greases are not used. The train components are transferred to the sampling
location and assembled as previously shown in Figure 5-4.
5.2.3.3 Sampling Procedures
After the train is assembled, the heaters are turned on for the probe liner and heated
filter box. When the system reaches the appropriate temperatures, the sampling train is ready for
pre-test leak checking. The gas stream exiting the heated filter is maintained at a temperature of
120 ±14°C (248 ±25°F). The filter temperature is initially set at 120 ±14°C (248 ±25°F) and the
probe temperature at 100°C (212°F). The temperature of these two heated zones will be
regulated as necessary to maintain the proper temperature of the gas exiting the filter.
The sampling trains are leak checked at the start and finish of sampling. (Method 26A
protocol requires post-test leak checks and recommends pre-test leak checks.) ERG protocol also
incorporates leak checks before and after every port change. An acceptable pre-test leak rate is
less than 0.02 acfm (ftVmin) at approximately 15 inches of mercury (in. Hg). If, during testing, a
piece of glassware needs to be emptied or replaced, a leak check is performed before the
glassware piece is removed, and after the train is re-assembled.
To leak check the assembled train, the nozzle end is capped off and a vacuum of
15 in. Hg is pulled in the system. When the system is evacuated, the volume of gas flowing
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through the system is timed for 60 seconds. After the leak rate is determined, the cap is slowly
removed from the nozzle end until the vacuum drops off, and then the pump is turned off. If the
leak rate requirement is not met, the train is systematically checked by first capping the train at
the filter, at the first impinger, etc., until the leak is located and corrected.
After a successful pre-test leak check has been conducted, all train components are at
their specified temperatures and initial data are recorded (dry gas meter (DGM) reading), the test
can be initiated. Sampling train data are recorded periodically (specific interval to be
determined) on standard data forms. A checklist for sampling is included in Table 5-9.
The leak rates and sampling start and stop times are recorded on the sampling task log.
Also, any other events that occur during sampling are recorded on the task log, such as pitot
cleaning, thermocouple malfunctions, heater malfunctions, or any other unusual occurrences.
At the conclusion of the test run, the sample pump (or flow) is turned off, the probe is
removed from the duct, a final DGM reading is taken, and a post-test leak check is completed.
The procedure is identical to the pre-test procedure; however, the vacuum should be at least
one inch Hg higher than the highest vacuum attained during sampling. An acceptable leak rate is
less than 4% of the average sample rate or 0.02 acfm (whichever is lower). If a final leak rate
on-site does not meet the acceptance criterion, the test run may still be accepted upon approval of
the EPA test administrator. If so, the measured leak rate is reduced by subtracting the allowable
leak rate from it and then multiplied for the period of time in which the leak occurred. This
"leaked volume" is then subtracted from the measured gas volume in order to determine the final
gas sample volume.
5.2.4 Method 26A Sample Recovery
Recovery procedures begin as soon as the probe is removed from the stack and the post-
test leak check is completed.
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Table 5-9. Sampling Checklist for EPA Method 26A
Before Test Starts:
1. Check impinger set (right order and number). Verify probe markings, and re-
mark if necessary.
2. Check that you have all the correct pieces of glassware.
3. Check for data sheets and barometric pressure.
4. Sampling equipment needs to be ready for Method 3 analysis.
5. Leak check pitot tubes.
6. Examine meter box - level it and confirm that the pump is operational.
7. Assemble train to the filter and leak check at 15 in. Hg. Attach probe to train
. and do final leak check; record leak rate and pressure on sampling log.
8. Check out thermocouples - make sure they are reading correctly.
9. Turn on heaters and check to see that their temperatures are increasing.
10. Check that cooling water is on and flowing (if required). Add ice to impinger
buckets.
11. Check isokinetic K-factor - make sure it is correct. (Refer to previous results to
confirm assumptions). (Two people should calculate this independently to
double check it).
12. Have a spare probe liner, probe sheath, meter box and filter ready to go at
location.
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Table 5-9. Sampling Checklist for EPA Method 26A (continued)
During Test:
1. Notify crew chief of any sampling problems ASAP. Train operator should fill in
sampling log.
2. Perform simultaneous/concurrent testing with other locations (if applicable).
Maintain filter temperature at 120 ±14° C (248 ±25° F). Keep temperature as
steady as possible. Maintain impinger temperatures below 68° F. Maintain
probe temperature above 100° C (212° F) or as required to maintain the proper
filter temperature.
3. Leak check between ports and record on sampling log.
4. Record sampling rate times and location for the fixed gas (CO2, O2) sample
(if applicable).
5. Blow back pitot tubes at inlet location every 15 minutes.
6. Change filter if pressure drop exceeds 20 in. Hg.
7. Check impinger silica gel every '/2 hr; if indicator changes color request a pre-
filled impinger from van lab and replace.
8. Check manometer fluid levels and zero every hour.
After Test is Completed:
1. Record final meter reading.
2. Check completeness of data sheet.
3. Do final leak check of sampling train at maximum vacuum during test.
4. Leak check each leg of pitot tubes.
5. Disassemble train. Cap sections. Take sections to recovery trailer.
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Table 5-9. Sampling Checklist for EPA Method 26A (continued)
6. Probe/cyclone recovery (use 500 mL bottles)
For acetone rinses (all trains)
Attach flask to end of probe (separate recovery containers will be
used for each sampling location)
Add 50 mL of acetone
Put a brush down probe, and brush back and forth
Rinse back and forth in probe
Empty out acetone in sample jar
Do this 3 times so that the final combined acetone rinse volume is
< 150 mL.
7. Reattach nozzle and cap for next day, store in dry safe place.
8. Make sure data sheets are completely filled out and give to location leader.
To facilitate transfer from the sampling location to the recovery trailer, the sampling
train is disassembled into three sections: the nozzle/probe liner, filter holder and impingers in
their bucket. Each of these sections is capped with Teflon® tape or Parafilm® before removal to
the recovery trailer. All train components are rinsed and the samples collected in separate,
prelabeled, precleaned sample containers to avoid cross contamination of inlet and outlet
samples. Trains of each type are recovered in separate areas of the mobile laboratory to avoid
cross contamination or mistakes in recovery sequences.
Once in the trailers, the sampling train is recovered as separate front and back half
fractions. A diagram illustrating front half and back half sample recovery procedures is shown in
Figure 5-5. No equipment with exposed metal surfaces is used in the sample recovery
procedures. The weight gain in each of the impingers is recorded to determine the moisture
content in the flue gas. Following weighing of the impingers, the front half of the train is
recovered, which includes the filter and all sample-exposed surfaces forward of the filter. The
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Probe Liner &
Nozzle
Rinse with
acetone
Brush liner with
Teflon brush
and rinse with
acetone
Rinse with
acetone
Front Half of
Filter Housing
Rinse 3x with
acetone
Filter
F. H.
Container #2
Remove filter from
support with tweezers
and place in petri
dish
Brush loose
paniculate onto filter
Seal petri dish with
®
Teflon tape
Container #1
Impingers 1 & 2
(0.1 NH2SO4)
Measure volume
in impingers 1-2
Rinse with
D.I. water
Container #3
Impingers 3 & 4
(0.1 NaOH)
Measure volume
in impingers 3-4
Rinse with
D.I. water
Add 25mg
Sodium
thiosulfate
Container #4
Silica Gel
Measure
weight
gain
Discard
Figure 5-5. Method 26A Sample Recovery Scheme
-------
probe liner is rinsed with acetone by tilting and rotating the probe while squirting acetone into its
upper end so that all inside surfaces are wetted. The acetone will be quantitatively collected into
the appropriate bottle. This rinse is followed by additional brush/rinse procedures using a non-
metallic brush; the probe is held in an inclined position and acetone is squirted into the upper end
as the brush is pushed through with a twisting action. All of the acetone and particulate will be
caught in the sample container. This procedure is repeated until no visible particulate remains
and finished with a final acetone rinse of the probe and brush. The front half of the glass filter
holder is also rinsed with acetone until all visible particulate is removed. These rinses are added
to the probe rinses. After all front half acetone washes are collected, the cap is tightened, the
liquid level marked and the bottle weighed to determine the acetone rinse volume. This sample
is Container #2. The method specifies that a nominal volume "of 100 mL of acetone must be used
for rinsing these components. For blank correction purposes, the exact weight or volume of
acetone used is measured. An acetone reagent blank of approximately the same volume as the
acetone rinses is analyzed with the samples.
The filter is carefully removed from the filter support and placed in a clean, well-
marked glass petri dish (Container # 1) and sealed with Teflon® tape.
After measuring the volume of liquid in the first four impingers and determining the
weight gain of the desiccant in the fifth impinger the contents of the first four impingers are
recovered.
The contents of the first and second impingers (0.1 N H2SO4) and the water rinses of the
impingers and connecting glassware are transferred to a separate container labeled "Container
No. 3." The contents of the third and fourth impingers (0.1 N NaOH) and the water rinses of the
impingers and connecting glassware are transferred to a separate container labeled "Container
No. 4." Add 25 mg of sodium thiosulfate to Container No. 4 and mix well. Seal the sample
bottles and package for transport to the laboratory for analysis.
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A reagent blank is recovered in the field for each of the following reagents:
• Acetone—200 mL sample size;
• Filter blank—one each;
0.1 N H2SO4 - 200 mL sample size; and
• 0.1 N NaOH - 200 mL sample size, containing 50 mg of sodium thiosulfate.
Each reagent blank is of the same lot as was used during the sampling program. The
volumes collected are greater than that required for sample preparation in order to provide
sufficient amounts in case of sample loss during preparation or to compensate for larger volumes
of train rinses. Each lot number and reagent grade is recorded on the reagent blank label.
One field blank was collected at each lime-injected baghouse inlet, and one at each
lime-injected baghouse outlet. A field blank is generated by preparing a sampling train as if for
actual sample collection, performing a leak check at the sampling location, then sealing the inlet
and outlet of the train and leaving it at the sampling location during the length of an actual test
run.
One glassware proof blank will be collected for each train prior to sampling. A proof
blank is generated by rinsing the components of a train, prior to use, with the recovery solvent(s)
specified in the method.
The liquid level of each sample container is marked on the bottle in order to determine
if any sample loss occurred during shipment. If sample loss has occurred, the sample may be
voided or a method may be used to incorporate a correction factor to scale the final results
depending on the volume of the loss.
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Following the protocol of Method 26A, the fractions to be collected for analysis from
each train are:
• Fraction 1—Filter;
• Fraction 2—Probe/nozzle/cyclone and filter front half acetone rinses;
• Fraction 3 - Contents of Impingers 1 and 2 plus water rinses; and
• Fraction 4 - contents of Impingers 3 and 4 plus water rinses.
5.2.5 HCI Analytical Procedures
Before analysis, the samples are checked against the chain of custody forms, logged into
the laboratory sample tracking system, and assigned a laboratory sample number. Each sample is
then examined to determine if any leakage occurred and any color or other particulars of the
samples are noted.
The samples are analyzed using ion chromatography (1C). Analytical conditions are
determined by the type of analytical column used and whether suppressed or nonsuppressed 1C is
used. Prior to-sample analysis, a stable baseline is established and water samples are injected
until no chloride, bromide, or fluoride appears in the chromatogram. The 1C is then calibrated
using standards spanning the appropriate concentration range, starting with the standard at the
lowest concentration. Next, a check sample is injected in duplicate, followed by a water blank
and field samples. The calibration standards are re-injected at the end of the analyses to allow
compensation for any drift in the instrument response during analysis of the field samples. The
chloride sample concentrations are calculated from either the ion peak area or the peak height
and the calibration curve.
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5.2.6 HCI Analytical Quality Control
The 1C is calibrated with a minimum of three concentrations, not including zero. A
correlation coefficient of greater than or equal to 0.995 must be achieved to have an acceptable
calibration. At least 10 percent of the total number of samples are analyzed in duplicate. Ion
concentrations in the duplicates must agree to within ± 20 percent.
5.2.7 Particulate Analysis
The general gravimetric procedure described in Method 5, Section 4.3 is followed.
Both filters and precleaned beakers are weighed to a constant weight before use. The same
balance used for taring is used for weighing the samples. The balance room is maintained at a
constant temperature and humidity. The preparation and analysis scheme for Method 5 is shown
in Figure 5-6. The particulate was determined as part of the Method 26A Train samples.
The filter (Container #1) is desiccated to a constant weight for a minimum of 24 hours
and then an initial weighing is performed. Weight gain is reported to the nearest 0.1 mg. A
second weight determination is made after again desiccating for a minimum of 6 hours.
"Constant weight" means a difference of no more than 0.5 mg or 1% of the total weight less tare
weight, whichever is greater, between two consecutive weighings made 6 hours apart. Report the
final weight as the average of these two values. The filter tare and final weights will be
determined under the same conditions of temperature and humidity.
The acetone rinses (Container #2) are transfer to a tared beaker, along with three
acetone rinses of Container #2, and evaporated to dryness at ambient temperature, placed in a
desiccator for 24 hours and weighed to a constant weight. The total volume of acetone used in
preparation of the sample is duplicated for the preparation of a reagent blank.
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Container #1
Container #2
Filter
Transfer to tared glass weighing dish
Desiccate to constant weight
Determine particulate filter weight
Front half rinses
Evaporate to dryness at ambient temperature and pressure
in a Tared heaker
I
Desiccate to constant weight
Determine PM weight
Figure 5-6. Method 5 Preparation and Analysis Scheme (Integral Part of Method 26A)
-------
5.2.8 Quality Control for Gravimetric Procedures
All quality control procedures specified in the test method are followed. All field
reagent blanks are processed and analyzed as specified in the test method. Prior to each
gravimetric determination, the balance calibration is verified using a series of certified weights
covering the range of weights encountered for the samples.
5.3 FTIR EPA Method 320
The extractive FTIR measurement method is based on continuous extraction of sample
gas from the stack, transporting the sample to the FTIR spectrometer and performing real-time
spectral measurement of the sample gas. The sample gas spectra are analyzed in real-time for
target analytes, archived and possibly re-analyzed at a later date for other target analytes.
5.3.1 FTIR Sampling Equipment
The FTIR measurement system met the sampling and analysis requirements set forth in
EPA Draft Method 320, "Measurement of Vapor Phase Organic and Inorganic Emissions By
Extractive Fourier Transform Infrared Spectroscopy". This system has been used with complete
success with many source categories, and can also be adapted to switch quickly between two
sources (i.e., inlet and outlet) with a single FTIR spectrometer.
The sampling and measurement system consists of the following components:
• Heated probe;
• Heated filter;
• Heat-traced Teflon sample line;
• Teflon® coated, heated-head sample pump;
• FTIR spectrometer;
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• FTIR sample conditioning system; and
QA/QC apparatus.
Figure 5-7 illustrates the FTIR sampling and measurement system. In operation at a
stationary source, the sample is continuously extracted from the stack through the heated probe.
Sample gas is then sent into a heated filter assembly which will remove any particulate matter
from the sample stream to protect the remainder of the sampling and analysis system. The probe
liner and filter body are made of glass, and the filter element is polytetrafluoroethylene (PTFE or
Teflon®). In addition to providing an inert surface, the glass body filter allows the operator to
observe the filter loading during sampling operations. The probe and filter are contained in a
heated box which is mounted on the stack and maintained at a temperature of 121 ° C (250° F).
After passing through the filter assembly, the sample gas is transported to the FTIR
spectrometer by a primary heat-traced PTFE sample line maintained at 149° C (300° F) driven
by a heated- PTFE head sample pump maintained at 204° C (400° F). The sampling flow rate
through the probe, filter, and sampling line is a nominal 20 liters per minute (Lpm). Sample gas
then enters an atmospheric pressure heated PTFE distribution manifold where it is sent to the
FTIR spectrometer via a slipstream flowing at 9 Lpm. Other slipstreams can be sent to other
instruments, if necessary. Excess sample gas not used by instruments is vented to atmosphere.
FTIR spectrometer sample gas is taken from the distribution manifold by a secondary
heated PTFE head sample pump maintained at 204° C (400° F) and directed into the FTIR
sample cell maintained at 185° C (365° F) for real-time analysis. The cell is made of nickel-
plated aluminum, with gold-plated glass substrate mirrors and potassium chloride windows.
Exhaust gas from the cell is vented to the atmosphere.
Sample conditioning (when required) is achieved by passing raw sample gas through a
PermaPure® drier and a series of impingers filled with sodium (or lithium) hydroxide pellets. The
PermaPure® drier selectively removes water vapor and the sodium hydroxide pellets remove CO2
and other acid gases. The sample conditioning apparatus is switched into the FTIR sample
5-41
-------
N)
Heat-traced line
Sample
Gas In
Spike or QA/QC Gas
Vaporization
block
I
QA/QC Gas Standard Manifold
Main Sample Pump
Heated Flow Meter
Legend
Bold text and lines = Heated
Normal text and lines = Unheated
Heat-traced line
(up to 100 feet)
6
FPIR
Sample
Pump/
Flowmeter^
QA/QC Gas Standards
Sample Distribution Manifold
To Other Instruments
FTIR Sample Cell
Spiking Solution
Excess sample to
atmosphere
Exhaust to atmosphere
Fio"re 5-7. FTIR Sampling and Measurement System
-------
path by a valving system. Lower detection limits for some compounds can be achieved with a
conditioned sample.
5.3.2 Preparation for Sampling
The heated sampling lines, probes, and heated filter were positioned at the inlet and
outlet locations. All heated components were brought to operating temperature, and a leak check
of both inlet and outlet sampling systems was performed. The leak check was performed by
plugging the end of the probe and watching the main sample rotameter to see that the value goes
to zero.
A background spectrum was measured using zero air or zero nitrogen through the cell.
Next the QC gases were measured by flushing the cell and they must agree to within ±10% of
target value. The QC gases used for this program included:
Halocarbon 22, used to calibrate the pathlength. Halocarbon 22 is used for its
highly linear response due to the lack of sharp spectral features, and is an
extremely stable compound.
Carbon monoxide (CO); used for frequency calibration. Carbon monoxide is
directly injected into the sample cell to measure photometric accuracy, validity
of the non-linear correction algorithm and serve as a frequency (i.e., wavelength)
calibration. Acceptable limits for CO standard analysis are ±5 percent of
certified concentration;
Methane/nitric oxide/carbon dioxide mixture, used for overall system
performance check (calibration transfer standard) (acceptance limits are ±5% of
the certified concentration); and
Hydrogen chloride standard, analyzed to verify the instrumental response of HC1,
a key target analyte (acceptance limits are ±10% of certified concentration).
The sampling and measurement system spike test was used to perform validation and
directly challenge the complete system and provide information on system accuracy and bias.
This test is conducted to satisfy the requirements set in EPA Draft Method 320 entitled
5-43
-------
"Measurement of Vapor Phase Organic and Inorganic Emissions By Extractive Fourier
Transform Infrared Spectroscopy". Section B. l.C of Method 320 gives a description of the
dynamic spiking apparatus.
The FTIRS spiking procedure used was the following:
• Measure native stack gas for a 5 minute period;
• Start spike gas flow into sample stream, upstream of the heated filter;
• Let system equilibrate for 5 minutes;
• Measure spiked sample stream for 5 minutes;
• Turn off spike gas flow;
• Let system equilibrate with native stack gas for 5 minutes; and
• Repeat cycle, two more times.
The above procedure produces 3 spiked/unspiked sample pairs per hour. Spike
recovery and three relative standard deviations for 3 spiked/unspiked sample pairs were
computed from the procedure given in Section 8.6.2 of EPA Draft Method 320. The recovery
must be 70-130% and the Percent Relative Standard Deviation must be less than or equal to 50%
for the method to be valid for this source category.
The spiked/unspiked pairs are not simultaneously recorded, since only one FTIRS
system will be available, but due to the expected steady nature of the source, this procedure
produced acceptable results.
The FTIR sampling and analysis system was validated for HCI at the outlet of the chip
dryer baghouse and the inlet and outlet of the reverberatory furnace #1 and was used as a
screening tool for the other HAPs.
5-44
-------
5.3.3 Sampling
FTIR sampling was performed simultaneously with the manual testing. The start and
stop times, as well as port change times, were coordinated with the bilk operator, so that FTIR
data files could be coordinated with manual method start and stop times. FTIR inlet/outlet
sampling was accomplished using two heated transfer lines, using a valving system to switch
from one to the other.
Table 5-10 gives typical FTIR operating conditions. These parameters provide detection
limits of 0.1-1 ppm for typical FTIR analytes, while providing adequate dynamic range
(nominally 1-1000 ppm). Some of these parameters are sample matrix dependent.
Table 5-10. Typical FTIR Operating Parameters
Parameter
Spectral Range (cm"1) "
Spectral Resolution (cm"1)
Optical Cell Pathlength (m)
Optical Cell Temperature (° C)
Sample Flow Rate (liters/minute)
Integration Time (minutes)
Value
400 - 4000
0.5 (or better)
3.2 (variable-- 1-10)
185
9 (3.0 optical cell volumes/minute)
1 (Average of 40 spectra)
Sample flow rate was determined by the data averaging interval and FTIR spectrometer
sample cell volume. A minimum of 3 sample cell volumes of gas must flow through the system
to provide a representative sample during a single integration period. Typically, a 1 minute
averaging period with a 3 liter volume sample cell gives a minimum flow rate of 9 liters per
minute (LPM). Typically a flow rate of 20 standard Lpm is used to accommodate the FTIR and
other instrumentation on-site, and to minimize sample residence time in the sampling system.
5-45
-------
The temperature of all sampling system components were nominally 221-204° F (250-
400° C) to prevent condensation of water vapor or other analytes in the sampling system. The
Kl'lR sample cell temperature was maintained at 365° F (185° C) to ensure that condensation of
high-boiling point analytes on the cell optics is minimized.
FTIR sample cell pressure was monitored in real-time in order to calculate analyte
concentration in parts-per-million. It is normally operated near atmospheric pressure with the
cell pressure continuously monitored.
Stack gas temperature was also be monitored to provide information on potential
sample analyte condensation in the sampling system. If the stack gas temperature is higher than
the lowest sampling system component temperature, then an assessment by the spectroscopist or
field team leader must be made whether any analytes of interest may condense within the
sampling system, resulting in measurement bias.
Sampling probe location was determined by the requirements set in EPA Method 1 in
terms of duct diameters upstream and downstream of disturbances. Concurrent EPA Method 2
velocity measurements were carried out at the same process stream location as the FTIR
sampling point to provide mass emission rate determination. The stack gas velocity and flow
rate were determined by the manual test methods.
Before testing, sample matrix effects were assessed on-site by the spectroscopist and
adjustments to the optical pathlength and spectral analysis regions were made. Once the
adjustments have been made, they rarely need to be further refined at a given source type.
Sampling and analysis procedures are straightforward for a single-source measurement.
Once QA/QC procedures have been completed for a given test day, the sample is allowed to flow
continuously through the FTIR spectrometer cell and the software is instructed to start spectral
data collection. Usually, the spectrometer collects one interferogram per second and averages a
number of interferograms to form a time-integrated interferogram. Typical averaging times
5-46
-------
range from 1 to 5 minutes. The interferogram is converted into a spectrum and analyzed for the
target analytes. After spectral analysis, the spectrum is stored on the computer and later
permanently archived. Spectral data collection is stopped after a pre-determined time,
corresponding to a "run".. Typical runs were 4 hours long, giving 240 one-minute averaged
points for each target analyte. At the end of the test day, the end-of-day QA/QC procedures were
conducted.
Before any testing is started at a given site, an initial "snapshot" of the stack gas is
taken with the FTIR measurement and analysis system to determine the true sample matrix. If
any target analytes are present at significantly higher levels than expected, adjustments will be
made to the cell pathlength and/or the spectral analysis regions used for quantitative analysis.
These adjustments will minimize interferences due to unexpectedly high levels of detected
analytes.
Since sample conditioning was required for certain analytes, the FTIR spectrometer
divided its analysis time between conditioned and unconditioned samples. Usually, the analysis
time is split into blocks to minimize dead time due to switching between sample types. For
example, the first half of the run period is dedicated to conditioned samples, and the last half of
the run is committed to unconditioned samples. The order used at Gulp Aluminum Alloys is
shown in the table below.
Sampling
Conditions
Chip Dryer
Unconditioned
Chip Dryer
Conditioned
Furnace
Unconditioned
Furnace
Conditioned
Furnace
Unconditioned
Sampling Time
First half of Test
Second half of
Test
First half of
Charging
Second half of
Charging
Duration of
Mixing Top Out
Inlet
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
Outlet
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
2 minute cell purge
8 minute sample collection
5-47
-------
The sample being delivered to the FTIR cell alternated between the inlet and the outlet.
The switching valve, located just upstream of the common manifold, was manually activated
every 10 minutes to provide twelve ten-minute sample collections during each two-hour period.
FTIR method performance is gauged from the results of the QA/QC procedures given in
Section B5 of Draft EPA Method 320. Acceptable spiking tests must meet acceptance criteria of
50 percent relative standard deviation (RSD) and accuracy of within ± 30 percent. The
acceptable instrument diagnostic and system response check accuracy must be within ± 5 percent
of target. Acceptable system response check precision was 5 percent RSD.
The ERG validated spectral database includes the compounds shown in Table 5-11.
These spectra were validated in the laboratory at a cell temperature of 185° C against certified
gaseous standards. Any compounds identified in the stack gas and not included in the ERG
database can be quantified if necessary after subsequent laboratory spectral acquisition.
5.3.4 FTIR Method Data Review, Validation, and Verification Requirements
Quantitative analysis is performed by a mathematical method called multi-variate least
squares (commonly known as Classical Least Squares or CLS). CLS constructs an optimized
linear combination (or 'fit') of the reference spectra to duplicate the sample spectrum, utilizing
the Beer-Lambert Law. The Beer-Lambert Law states that the absorbance of a particular spectral
feature due to a single analyte is proportional to its concentration. This relationship is the basis
of FTIR quantitative analysis. The coefficients of each compound in the linear fit yield the
concentration of that compound. If it is found that the quantitative analysis of a given compound
responds non-linearly to concentration, a calibration curve is developed by measuring a series of
reference spectra with differing optical depths (concentration times pathlength) and using them
in the linear fit. Low molecular weight species such as water vapor and carbon monoxide
require non-linear correction, possibly even at levels as low as 100 ppm-meters (concentration
times pathlength). Analytes greater than 50-60 amu molecular weight usually do not require non-
5-48
-------
Table 5-11. Compounds for Which Reference FTIR Spectra Are Available in the
ERG Spectral Library3
1,3-butadiene
1-butene
2-methyl-2-propanol
2-methylbutane
2-methoxyethanol
2-methyIpropane
2-propanol
4-vinylcyclohexane
acetic acid
acetone
acrolein
benzene
acetylene
c/.y-2-butene
fra/i5-2-butene .
ethylene
ethane
propylene
propane
chlorobenzene
acetaldehyde
methanol
methane
carbon monoxide
carbon dioxide
cyclopropane
cvclopentane
cyclohexane
ethylbenzene
formaldehyde
water vapor
hydrogen chloride
hydrogen fluoride
isobutylene
methylene chloride
methyl ethyl ketone
m-xylene
p-xylene
o-xylene
phenol
o-cresol
m-cresol
/7-cresol
nitrous oxide
n-butane
/i-butanol
ammonia
nitric oxide
nitrogen dioxide
H-pentane
carbonyl sulfide
sulfur dioxide
styrene
toluene
' Spectra were collected at a cell temperature of 185° C.
5-49
-------
linear corrections. An experienced spectroscopist can determine whether non-linear corrections
are necessary for an analyte in a given source testing scenario.
The following procedures were conducted to review the FTIR data:
A. Post-test Data Review procedure (on-site)
1. Examine the concentration vs. time series plot for each compound of interest, and
identify regions with the following characteristics:
• sudden change in concentration;
• unrealistic concentration values;
• significant changes in 95 percent confidence intervals reported by
software; and
• sudden increase of noise in data.
2. Select representative spectra from the time periods indicated from Step 1.
3. Subtract from each representative spectrum chosen in Step 2 a spectrum which
was taken immediately prior in time to the indicated time region.
4. Manually quantitate (including any non-linear corrections) for the species in
question and compare the result to. the difference in software-computed
concentrations for respective spectra.
5. If concentration values in Step 4 do not agree to within 5 percent, determine
whether the difference is due to a recoverable or non-recoverable error.
6 (i). If the error is non-recoverable, the spectra in the indicated time region are
declared invalid.
6 (ii). If the error is recoverable, and time permits, determine possible source(s) of error
and attempt to correct. If time is critical, proceed with measurement. If
correction is achieved, conduct QA/QC checks before continuing.
7. Determine the peak-to-peak scatter or the root mean square (RMS) noise-
equivalent-absorbance (NEA) for the representative spectra.
8. If the NEA exceeds 1 x 10"3 absorbance units, the spectra in the time region are
declared invalid (due to non-recoverable error).
9. Data found invalid are subject to re-measurement.
5-50
-------
B. Final Data Review (off-site)
The procedures for final data review included those given above; however, if a non-
recoverable error was found during this phase, the data were considered invalid. In addition, the
following procedures were carried out by the spectroscopist to perform a final data validation:
1. If any recoverable data errors are detected from the procedure, determine the
cause and perform any necessary corrections.
2. For analytes which were not detected or detected at low levels:
a) estimate detection limits from validated data;
b) check for measurement bias.
5.3.5 QCfortheFTIR
The FTIR QA/QC apparatus was used to perform two functions:
• Dynamic analyte spiking; and
• Instrumental performance checks.
Dynamic analyte spiking is used for quality control/quality assurance of the complete
sampling and analysis system. Dynamic spiking is continuous spiking of the sample gas to
provide information on system response, sample matrix effects, and potential sampling system
biases. Spiking is accomplished by either:
• Direct introduction of a certified gas standard; or
Volatilization of a spiking solution.
Certified gas standards are preferred due to simplicity of use, but many target analytes
cannot be obtained as certified gas standards, and must be spiked using standards generated by
volatilized solutions.
5-51
-------
Gaseous spiking is carried out by metering the spike gas into the sample stream at a
known rate. Spike levels are calculated from mass balance principles. When certified gas
standards are used, a dilution tracer, such as sulfur hexafluoride, is used to directly measure the
fraction of spike gas spiked into the sample. This technique can be used instead of mass balance
calculations. . "
Before any testing is started at a given site, an initial "snapshot" of the stack gas is taken
with the FTIRS measurement and analysis system to determine the true sample matrix. If any
target analytes are present at significantly higher levels than expected, adjustments will be made
to the cell pamlength and/or the spectral analysis regions used for quantitative analysis. These
adjustments will minimize interferences due to unexpectedly high levels of detected analytes.
FTIRS method performance is gauged from the results of the QA/QC. Acceptable
spiking tests will meet Method 301 criteria (i.e., 50 percent relative standard deviation (RSD)
and accuracy of within ± 30 percent) or a statistical equivalent when less than 12 spiked/unspiked
pairs are collected. The acceptable instrument diagnostic and system response check accuracy
will be within ± 5 percent of target. Acceptable system response check precision will be
5 percent RSD.
5-52
-------
6.0 QUALITY ASSURANCE/QUALITY CONTROL
Specific Quality Assurance/Quality Control (QA/QC) procedures were strictly followed
during this test program to ensure the production of useful and valid data throughout the course
of the project. A detailed presentation of QC procedures for all sampling and analysis activities
can be found in the Site Specific Test Plan and Quality Assurance Project Plan for this project.
This section reports all QC results so that the data quality can be ascertained.
In summary, a high degree of data quality was maintained throughout the project. All
train leak checks met the QC criteria as specified in the methods. Isokinetic sampling rates were
kept within 10% of 100% for all test runs. Acceptable spike recoveries and close agreement
between duplicate analyses were shown for the sample analyses: The data completeness was
better than 95%. .
6.1 Sampling QC Results
The following sections discuss the QC results of the sampling methods employed during
this project.
6.1.1 Leak Checks
Tables 6-1 and 6-2 list the pre- and post-test and port change leak checks results for the
chip dryer and furnace tests. The acceptance criterion that all post-test leak checks must be less
than 0.02 cfm or 4 percent of the average sampling rate (which ever is less) at the highest
vacuum achieved during sampling was met for all test runs.
6-1
-------
Table 6-1. Summary of Dioxin/Furan Test Leak Check Results
Location
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
Run#/
Port
I/A
1/B
I/A
1/B
2/A
2/B
2/A
2/B
3/A
3/B
3/A
3/B
I/A
1/B
I/A
1/B
2/A
2/B
2/A
2/B
3/A
3/B
3/A
3/B
4/A
4/B
4/A
4/B
Initial Leak
Check
0.018@15"
0.006@15"
0.02@15"
0.016@23"
0.00@10"
0.00@14"
0.01 @ 10"
0.018@16"
0.01 @ 12
0.018@15"
0.01 @ 11"
0.015@ll"
0.01 @ 10"
0.01 1@ 10"
Port
Change
0.01 @ 10"
0.01 @ 10"
0.008 @23"
0.01 @23"
0.01 @ 10"
0.01 @ 10"
0.016@21"
0.018@18"
0.01 @ 10"
0.01 @ 10"
0.00@11"
0.00@H"
Not Recorded
Not Recorded
0.008® 8"
0.008 @8"
Not Recorded
Not Recorded
0.005 @ 10"
0.005 @ 10"
Not Recorded
Not Recorded
0.00@7"
0.00@7"
0.015@15"
0.015@15" .
0.006@5"
0.006@5"
Final Leak
Check
0.01 @ 15"
0.005 @ 8"
0.01 @ 15"
0.01 @8"
0.01 @ 10"
0.003 @ 10"
0.00@10"
0.006@7"
0.005@11"
0.00@10"
0.005@5"
0.00@6"
0.005® 10"
0.004® 8"
6-2
-------
Table 6-2. Summary of HCI/PM Test Leak Check Results
Location
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
CD Outlet
CD Outlet
CD Inlet
CD Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
RF Outlet
RF Outlet
RF Inlet
RF Inlet
Run#/
Port
I/A
1/B
I/A
1/B
2/A
2/B
2/A .
2/B
3/A
3/B
3/A
3/B
I/A
1/B
I/A
1/B
2/A
2/B
2/A
2/B
3/A
3/B
3/A
3/B
4/A
4/B
4/A
4/B
Initial Leak
Check
0.01@10"
0.01 1@ 13"
0.01 @ 15"
0.01 @ 15"
0.01 @ 10"
0.005 @ 14"
0.01 @ 10"
0.02@15"
0.01 @9"
0.005 @ 10"
0.01 @ 10"
0.004@ 10"
0.02 @ 12"
0.012@9"
Port
Change
0.01@10"
0.01 @ 10"
Not Recorded
Not Recorded
0.01 @ 10"
0.01 @ 10"
0.009@7"
0.009@7"
0.01 @ 10"
0.01 @ 10"
0.00@6"
0.00@6"
0.01 @ 10"
0.01 @ 10"
0.016@6"
0.016@6"
Not Recorded
Not Recorded
0.00@8"
0.00@ 10"
Not Recorded
Not Recorded
0.00@5"
0.00@5"
0.01 @ 10"
0.01 @ 10"
0.009@9"
0.009@9"
Final Leak
Check
0.01 @ 15"
0.00@13"
0.01@10"
0.007@11"
0.01 @ 10"
0.0046® 8"
0.00@12"
0.004 @ 8"
0.01 @ 10" •
0.008@8"
0.005 @ 10"
0.00@5"
O.OI5@12"
0.00@7"
6-3
-------
6.1.2 Percent Isokinetics
Table 6-3 presents the isokinetic sampling rates percentages for the D/F and HC1/PM
sampling runs. The acceptance criteria that the average sampling rate must be within 10% of
100% isokinetic was met for all sampling runs.
Table 6-3. Summary of Isokinetic Percentages
Location/Method
CD Inlet D/F
CD Outlet D/F
CD Inlet HC1/PM
CD Outlet HC1/PM
RF Outlet D/F
RF Inlet D/F
RF Outlet HC1/PM
RF Inlet HC1/PM
Run#
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
Percent Isokinetic
97.5
101
98.4
102
98.5
96.9
104
100
101
102
101
103
97.9
98.3
98.5
96.9
101
102
101
101
96
103
103
102
102
102
101
106
6-4
-------
6.1.3 Meter Box Calibrations
All dry gas meters are fully calibrated every six months against an EPA approved
intermediate standard. The full calibration is used to correct the actual metered sample volume
to the true sample volume. To verify the full calibration, a post-test calibration is performed.
The full and post-test calibrations must be within 5% to meet ERG's internal QA/QC acceptance
criterion. As shown in Table 6-4, the dry gas meters used for this testing met this criterion.
Table 6-4. Dry Gas Meter Post-Test Calibration Results
Sampling
Train1
D/F CD Outlet
D/F CD Inlet
HC1 CD Outlet
HC1 CD Inlet
D/F RF Outlet
D/F RF Inlet
HC1 RF Outlet
HC1 RF Inlet
Meter Box #
A-38
A-40
A-37
A-39
A-37
A-39
A-38
A-40
Full Calibration
Factor
0.981
0.98
0.988
0.994
0.988
0.994
0.981
0.98
Post-Test
Calibration
Factor
0.978
0.979
0.995
0.974
0.995
0.974
0.978
0.979
Post-Test2
Deviation, %
-0.30
-0.10
-0.70
-2.00
-0.70
-2.00
-0.30
-0.10
'CD=Chip Dryer, RF=Reverberatory Furnace
2Post-Full x 100
Full
6.1.4 Field Blank Results
Field Blanks are collected to determine the level, if any, of sample contamination
resulting from the exposure of the sampling train to ambient conditions in the vicinity of the
sampling locations or to sample "carry over" from one run to the next. A field blank train for
each test method and for each location was assembled as if for sampling, leak checked at the
6-5
-------
sampling location, left at the sampling location for the duration of a test run and then recovered.
The samples were returned to the laboratory for analysis along with the test samples. The results
of the analysis for the Method 26A field blanks are shown in Table 6-5. A small amount of HC1
was detected in the Chip Dryer field blank, but represents less than 1% of the amount detected in
most of the test samples and less than 5% of that detected in all samples. Because the level of
contamination was so low, no blank corrections were made on the emission results. No HC1
above the instrument detection limit was detected in the furnace field blanks.
Table 6-5. Method 26A Field Blank Analysis Results, |jg Detected
Location
Chip Dryer Inlet
Chip Dryer Outlet
Reverberatory Furnace Inlet
Reverberatory Furnace Outlet
Mg HC1 Detected
20.0
Not Required
< 14.0
< 14.0
Table 6-6 shows the results of the analysis of the D/F field blanks. The levels detected in
the blank are less than 1% of that detected for any congener in the chip dryer inlet samples and
less than 1% for most and less than 5% for all detected in the chip dryer outlet samples except for
OCDD and OCDF. The levels detected in the furnace inlet field blank were less than 1% for
most congeners and less than 5% for all except for 2,3,7,8-TCDD and 1,2,3,7,8-TCDD which
were less than 10%. Trace amounts of all but three congeners were detected in the furnace outlet
field blank. Of the ones detected all but seven were less than 5 times the detection limit and the
others were less than 10 times the detection limit. All but six of the congeners were at levels
equivalent to those found in the furnace outlet samples and all were detected at levels less than
one nanogram.. Since the levels detected were insignificant, no blank correction to the data was
performed. .
6-6
-------
Table 6-6. Method 23 Field Blank Analysis Results, ng Detected
Congener
2,3,7,8 -TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2.3,7.8.9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4.6,7,8,9-OCDF
Chip Dryer Inlet
<0.006
0.04
0.02
0.04
0.05
0.12
0.25
0.45
0.14
0.22
0.31
0.12
0.14
0.02
1.2
0.17
0.41
Furnace Inlet
0.07
0.48
0.26
0.46
0.57
1.2
0.65
7.6
1.7
2.9
6.0
2.3
2.4
0.15
6.1
0.72
1.5
Furnace Outlet
<0.004
0.02
<0.01
0.02
0.03
<0.09
0.16
0.29
0.07
0.12
0.23
0.09
0.12
<0.007
0.43
<0.05
0.31
6.1.5 FTIR Sampling Quality Control
FTER sampling system quality control procedures used in this test program were:
• Sampling system leak check;
• Dynamic spiking (also analytical quality control); and
• Monitoring of all pertinent system temperatures and flow rates.
6-7
-------
Sampling system leak checks were carried out before and after each run. The leak check
procedure used is identical to that given in EPA Method 320. The sample gas inlet to the probe
was covered and the total sample flow rate rotameter was monitored to observe zero flow
(i.e., indicator ball sits on bottom of scale). In all cases in this program, the system passed both
before and after run leak checks for all runs performed.
Dynamic spiking was carried out to test the complete FTIR sampling and analysis system.
Spiking was carried out twice daily on both inlet and outlet for HC1, and three EPA Method 301
validation tests were carried out. The Method 301 tests were carried out on the following
locations:
• Chip dryer outlet;
• Furnace hood inlet; and ,
• . outlet.
Method 301 validation results are given in Section 2.5.2.1. Daily spiking results are given below
in Section 6.2.4.
To insure that the sampling system was performing correctly during all measurement
operations, selected temperatures and flows were monitored during each run. Temperature data
were recorded every 15 minutes on a data sheet. Sample flows were monitored but not recorded.
The following data were monitored or recorded:
• Inlet/outlet stack temperature; .
• Inlet/outlet probe temperature;
• Inlet/outlet filter temperature;
• Inlet/outlet heat-traced sample line temperature;
• Inlet/outlet main sample pump head temperature;
6-8
-------
• FTIR sample pump head temperature;
• Sample pump enclosure temperature;
• Sample manifold temperature;
• Controller electronics box temperature;
• Heated sample line jumper temperature(2);
• Main sample flow rate;
• FTIR sample flow rate; and
• Excess sample flow rate.
FTIR cell temperature was controlled at 185°C sample gas temperature (not cell wall
temperature), and cell pressure was recorded. No unusual readings of any parameter were found
during testing.
6.2 Analytical Quality Control Results
6.2.1 D/F Analytical Quality Control
All quality control procedures specified in the test method were followed. Blanks were
used to determine analytical contamination, calibration standards were used for instrument
calibration and linearity checks, internal standards were used to determine isomer recoveries and
adjust response factors for matrix effects, surrogate standards were used to measure the
collection efficiency of the sampling methodology and an alternate standard was used as a
column efficiency check.
6.2.1.1 D/F Quality Control Blanks
Reagent blanks of 500 mL of each liquid reagent used at the test site were saved for
analysis. Each reagent blank was of the same lot as was used during the sampling program.
6-9
-------
Each lot number and reagent grade was recorded on the field blank label and in the laboratory
notebook (acetone, methylene chloride, toluene, filter, XAD-2®). Two reagent blanks were
collected in the field. The analysis results showed the absence of any analytes, at the detection
limit, for approximately half of the congeners with the remaining being detected at less than 5
times the detection limit. These insignificant amounts are most likely due to laboratory
contamination.
6.2.1.2 Quality Control Standards
Recoveries of the internal standards must be between 40 to 130% for the tetra- through.
hexachlorinated compounds and in the range of 25 to 130% for the hepta- and octachlorinated
homologs. These requirements were met for all of the D/F samples except for the following:
chip dryer inlet Run 1, isotopically labeled HpCDD (134%).
Surrogate standard recoveries must be between 70 to 130%. The recoveries of all
standards met this requirement except for the following: isotopically labeled HxCDD for chip
dryer outlet run 1 (158%), chip dryer outlet run 2 (137%) and chip dryer outlet run 3 (142%).
These % recoveries were all just outside of the recovery limits and will not have an effect on the
analysis results.
6.2.2 HCI Analytical Quality Control
The IG is calibrated with a minimum of three concentrations, not including zero. A
correlation coefficient of greater than or equal to 0.995 must be achieved to have an acceptable
calibration. At least 10 percent of the total number of samples are analyzed in duplicate. Ion
concentrations in the duplicates must agree to within ± 20 percent. All QC results were within
the acceptance criteria
Reagent blanks were collected in the field and returned to the laboratory for analysis.
HCI, as Cl'1, was not detected in any of the blanks at the detection limit.
6-10
-------
Every sample was analyzed in duplicated with the relative percent difference for every
sample duplicate less than 5.
A matrix spike and matrix spike duplicate analysis was performed on the chip dryer outlet
run 1 sample. The percent recoveries were 106 and 104, respectively.
6.2.3 Quality Control for Gravimetric Procedures
All quality control procedures specified in-the test method are followed. All field reagent
blanks were processed and analyzed as specified in the test method. Prior to each gravimetric
determination, the balance calibration was verified using a series of certified weights covering
the range of weights encountered for the samples.
6.2.4 FTIR Analytical Quality Control
Dynamic analyte spiking was used for quality control/quality assurance of the complete
sampling and analysis system. Dynamic spiking is continuous spiking of the sample gas to
provide information on system response, sample matrix effects, and potential sampling system
biases. Spiking was accomplished by direct introduction of a certified gas standard.
Gaseous spiking was carried out by metering the spike gas into the sample stream at a
known rate. A sulfur hexafluoride dilution tracer was used to directly measure the fraction of
spike gas spiked into the sample. EPA Method 320 limits the dilution of the sample gas to
10 percent.
Before any testing was started at a given site, an initial "snapshot" of the stack gas is
taken with the FTIR measurement and analysis system to determine the true sample matrix. If
any target analytes are present at significantly higher levels than expected, adjustments were
made to the cell pathlength and/or the spectral analysis regions used for quantitative analysis.
These adjustments minimized interferences due to unexpectedly high levels of detected analytes.
6-11
-------
FTIR method performance is gauged from the results of the QA/QC. All spiking tests
met Method 301 criteria (i.e., 50 percent relative standard deviation (RSD) and accuracy of
within ± 30 percent). The acceptable instrument diagnostic and system response check accuracy
will be within ± 6 percent of target.
Analytical QC checks for the FTIR system consisted of the following:
• Dynamic spiking of HC1;
• direct measurement of a HC1 gas standard;
• direct measurement of a CO gas standard; and
• direct measurement of a CH4, NOX, and CO2 standard.
Dynamic spiking runs were conducted twice daily: before and after testing. Three
spiked/unspiked data pairs were collected. Statistical calculations consistent with EPA Method
301 were performed on the data. Recovery of 70-130 percent and less than 50 percent RSD were
the acceptance criteria. Table 6-6 summarizes the dynamic spiking results. All dynamic spiking
tests met the above acceptance criteria. In all runs, sample gas was diluted 10 percent or less.
Direct instrumental measurement of HC1, CO, and a CH4, NOX and CO2 mixture was
conducted before and after daily testing activities. Acceptance criteria are normally ±6 percent of
target, using EPA protocol gases. However, since the HC1 standard was obtained at a ±5 percent
analytical tolerance, the acceptance criteria was set at ±10 percent. FTIR NOX is measured as NO
+ NO2. Examination of Tables 6-7 through 6-9 shows that all QC checks met the above criteria.
6-12
-------
Table 6-6. QC Spiking Results
Run
1
1
2
2
3
3
4
5
6
6
7
7
8
8
9
9
10
10
11
12
13
13
14
14
Date
12/5/97
12/5/97
12/5/97
12/5/97
12/6/97
12/6/97
12/6/97
12/6/97
12/8/97
12/8/97
12/8/97
12/8/97
12/9/97
12/9/97
12/9/97
12/9/97
12/10/97
12/10/97
12/10/97
12/10/97
12/11/97
12/11/97
12/11/97
12/11/97
Time
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
AM
AM
PM
PM
Inlet/outlet
outlet
inlet
outlet
inlet
inlet
outlet
outlet
inlet
outlet
inlet
outlet
inlet
inlet
outlet
inlet
outlet
inlet
outlet
inlet
outlet
inlet
outlet
inlet
outlet
% Recovery
97.61
112.85
102.62
98.09
93.71
101.91
105.34
103.53
99.97
96.34
95.40
89.50
94.54
100.85
106.45
103.16
96.21
103.44
104.00
110.78
101.36
102.84
107.16
118.67
Sample gas dilution was held to 10 percent or less in all runs.
6-13
-------
Table 6-7. HCI Gas Standard Analysis Results
Date
. 12/3/97
12/3/97
12/4/97
12/5/97
12/5/97
12/6/97
12/6/97
12/6/97
12/7/97
12/7/97
12/8/97
12/8/97
12/9/97
12/9/97
12/10/97
12/10/97
12/11/97
12/11/97
Time
9:38:24
14:52:23
7:26:33
7:27:29
15:45:50
7:04:56
14:13:21
21:16:03
12:25:31
20:15:53
8:21:37
16:41:13
8:27:25
19:32:06
10:42:01
18:11:01
4:54:59
13:41:01
Result(ppm)
219.7
222.0
217.3
220.5
223.1
224.5
222.9
218.8
216.3
217.0
221.7
218.3
222.1
221.2
215.3
221.4
221.0
212.9
% Recovery
104.6
105.7
103.5
105.0
106.3
106.9
106.1
104.2
103.0
103.3
105.6
104.0
105.8
105.3
102.5
105.4
105.2
101.4
Comments
no testing on
12/4/97
HCI Target: 210ppm
Gas Standard Accuracy: ±5 percent
Acceptance Criteria: ±10 percent of target
6-14
-------
Table 6-8. CO Gas Standard Analysis Results
Date
12/3/97
12/3/97
12/4/97
12/5/97
12/5/97
12/6/97
12/6/97
12/7/97
\2I1 191
12/8/97
12/8/97
12/9/97
12/9/97
12/10/97
12/10/97
12/11/97 -
12/11/97
Time
9:32:55
14:47:42
7:21:45
7:23:00
15:38:26
7:02:07
21:13:08
12:21:32
20:12:12
8:18:46
16:37:33
8:21:25
19:28:43
10:39:04
18:08:03
4:53:14
13:38:05
Result(ppm)
103.0
103.2
101.8
102.5
103.5
104.0
102.3
100.8
100.8
103.5
101.5
101.2
102.8
101.3
102.9
104.2
99.9
% Recovery
100.6
100.8
99.5
100.2
101.2
101.7
100.0
98.6
98.5
101.2
99.2
99.0
100.4
99.0
100.6
101.9
97.6
Comments
no testing on
12/4/97
CO Target: 102.3 ppm
Gas Standard Accuracy: ±1 percent
Acceptance Criteria: ±6 percent of target
6-15
-------
Table 6-9. CH4, NOX, and CO2 Gas Standard Analysis Results
Date
12/3/97
12/3/97
12/4/97
12/5/97
12/5/97
12/6/97
12/6/97
12/7/97
12/7/97
12/8/97
12/8/97
12/9/97
12/9/97
12/10/97
12/10/97
12/11/97
12/11/97
Time
9:28:22
14:40:13
7:17:04
7:15:23
15:34:43
6:58:08
21:09:53
12:15:26
20:09:07
8:14:50
16:31:29
8:17:58
19:25:11
10:37:01
18:06:04
4:51:19
13:36:01
CH4
Result
(ppm)
488.0
488.4
485.0
488.3
492.4
491.6
489.7
490.7
485.9
491.0
489.2
485.0
486.7
482.6
485.9
489.4
488.7
CH4
% Recovery
99.4
99.5
98.8
99.5
100.3
100.1 .
99.7
99.9
99.0
100.0
99.6
98.8
99.1
98.3
99.0
99.7
99.5
No,
Result
(ppm)
503.3
500.0
492.5
498.9
503.3
505.9
493.9
492.3
487.6
499.8
492.5
488.9
498.5
492.4
496.2
503.4
472.6
No,
% Recovery
100.1
99.4
97.9
99.2
100.1
100.6
98.2
97.9
96.9
99.4
97.9
97.2
99.1
97.9
98.6
100.1
94.0
NO
Result
(ppm)
463.8
499.6
492.1
498.9
503.3
505.9
493.9
492.3
487.6
499.8
492.5
488.9
498.5
492.4
496.2
503.4
472.6
NO,
Result
(ppm)
39.4
0.4
0.3
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
CO,
Result(%)
4.88
4.74
4.73
4.88
4.81
4.85
4.93
4.97
4.69
4.97
4.93
4.83
4.76
4.73
4.67
4.86
4.84
CO,
% Recovery
97.8
95.1
94.8
97.9
96.4
97.2
98.7
99.5
94.0
99.6
98.9
96.9
95.5
94.8
93.5
97.4
97.0
Comments
no testing
on 12/4/97
CH4 Target= 491 ppm
NO, Target= 503 ppm
CO2Target= 4.99%
Gas Standard Accuracy: ±1 percent
Acceptance Criteria: ±6 percent of target
-------
Appendix A
Field Data Sheets
cah/A:\APPX-CVRWP6
-------
Facility: Gulp Alum. Alloy
Date: 12/05/97
Location: Dryer In
Run Number: 1
Sample Type: M26
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.39
Absolute Stack Pressure (in Hg) 29.02
Stack Static Pressure (in H2O) -5.00
Average Stack Temperature (°F) 244.13
Stack Area (sq in) 240.53
Actual Meter Volume (cu ft) 70.339
Average Meter Pressure (in H2O) 0.24
Average Meter Temperature (°F) 60.00
Moisture Collected (g) 110.10
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9940
Nozzle Diameter (in) 0.131
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.291
Standard Metered Volume (dscf) - 69.785
Standard Metered Volume (dscm) .. 1.976
Stack Moisture (%V) 6.92
Mole Fraction Dry Stack Gas 0.931
Dry Molecular Weight 28.88
Wet Molecular Weight 28.13
Stack Gas Velocity (fpm) 4428.45
Stack Gas Velocity (mpm) 1349.79
Volumetric Flow Rate (acfm) 7396.99
Volumetric Flow Rate (acmm) 209.48
Volumetric Flow Rate (dscfm) 5007.09
Volumetric Flow Rate (dscmm) 141.80
Percent Isokinetic 103.63
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATASHEET
Run
Page 1 of
Plant tio.ll)
Date
Operator
Sampling Location T>UV£>
' i?jwcw/w (in
UoL
\
2rt" -•£.&
7-4, '*?
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
«S\
rg *ju
H-'6Llrt5
">VZ>
NlA
61
Meter Box Number
Meter delta H @
PGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A^l
1-TZ-
• ^V^t
«i^5\
M *r
t;n >
^^n
.,,v
r?.~s/ A- ii-LO^I.^L^ DlagramofDud
Schematic of Traverse Point Layout
Read and record all data every ^S__ minutes
Traverse
Point
Number
Sampling
Time
(mln)
0
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps).
in.H20)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
(•F)
Filter
Temp.
(•F)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
'
it
•3- "50
ST3
ac-
/r
aO^O
.3
3
\
Z3S
^
HfO
ft
(1,
H-7
ji
42-.
2-?
SN
.2.3
i-
L/"
v-s
\\3
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page
Traverse
Point
Number
Sampling
.Time
(min)
Clotk
Time
(24hr)
Meter
Reading
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
(T)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired
Actual
Probe
Temp.
(•F)
Filter
Temp.
•CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(eF)
Pump
Vacuum
(in.Hg)
B 1
."Z.
S/
IL
11
no*
.IB
si
LLL
-TA
.-7,1
LOT
\-\
SI
l-l
:T,\
-Z.
c-0-
/ .
(1
I5"
-r
10
/.r
rr
? T
t-r-
(O
(.5-
\ ,
J5
-Z
UO
*
25
GO
-2.40
./TD.C
Comments:
-------
frt
:n Group, inc.
MOISTURE RECOVERY FORM FOR METRO
Plant
Date
Sampling Location
SampleType
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
P.I Q 1 ' Q ii
^ -IxJrt M \\: _IY\ i fS i Lf-rA I*11lnV5
r> L' /\ Ti L ~t— ^f
L ./i '.^ / JA ji°r- • no/?rvv i<*» i r\ (^ 1
^P1 ' *
no.rr AJnU /Tt^V C,.wi<'.n
7
//q'(^97-jQ
Impinger
Number
Impinger
Solution
Amount of
Solution
(g)
Impinger Tip
Configuration
Impinger Weight
Final
Initial
(9)
Weight
Gain
O.i V
Hf r~\
z.^^n
31.3
/S/c^CH
77..T
(CD
0"
Total Weight Gain (g)
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: Dryer In
Run Number: 2
Sample Type: M26
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.51
Absolute Stack Pressure (in Hg) 29.14
Stack Static Pressure (in H2O) -5.00
Average Stack Temperature (°F) 238.46
Stack Area (sq in) 240.53
Actual Meter Volume (cu ft) 74.692
Average Meter Pressure (in H20) 1.22
Average Meter Temperature (°F) 47.94
Moisture Collected (g) 60.70
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9940
Nozzle Diameter (in) 0.130
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.318
Standard Metered Volume (dscf) 76.206
Standard Metered Volume (dscm) . 2.158
Stack Moisture (%V) 3.62
Mole Fraction Dry Stack Gas 0.964
Dry Molecular Weight 28.88
Wet Molecular Weight 28.49
Stack Gas Velocity (fpm) 4833.21
Stack Gas Velocity (mpm) 1473.16
Volumetric Flow Rate (acfm) 8073.08
Volumetric Flow Rate (acmm) 228.63
Volumetric Flow Rate (dscfm) 5728.25
Volumetric Flow Rate (dscmm) 162.22
Percent Isokinetic , 100.45
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
«i •
Run 0*2-
Page 1 of 2,
Plant OuLf
Date
Operator
Sampling Location <)ry-«v b
Sample Type
Run Number
StatitrPreSsure (±) (in. H2O)
Barometric Pressure (in. H2O)
qiu/nnvj^ «
t9--l*- 17
«*/4-O
}rVi>i<* 10
/Wit-L
oz.
- i
t1.£i
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (*F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak CheCk
fJlA
O^b
<4'£l(4,.y
Z^D
Ma
.Oio^jS1
' ' * * Q
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (In.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Eactor
A- 31
\.Ti-
-!<*«/
.(?0
3 I
.ZH
13
24.
1 -
I.
f
^.
36
l-H
SH&
Mo..
1.5-
a 3-1
2*
^4-7
SC
-
1-3
.2.*
M-B
1-S
fr
Lo
0*134
L-T
1--7
Ml,
2 e
.32-
."7
6D
38
"Tts
i:
It/T?
a. i
So
vio
73
Hz,
«£>.<>
Comments:
-------
if :.-7_ ^
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).tt3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
cn
Orifice Pressure
Differential
(delta H, in.H2O)
Desired
• Actual
Probe
Temp.
C-F)
Filter
Temp.
Adsorbent
Trap
Temp.
, Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
A 1
_Lk.
Ji-
to
•2.^0
11*6"-
l.C
MS .en
2-St
3-?
«•
as
USSL
2-3 <&
338 '
-a£l
t/
\ -Z-
2 Ho
o
HI
2-2-
51
10
1.3
1-3
5 1
90
ftC
s>
1.3
25-
SC,
1-3 .
.2.5"
tub
23
•51
ret
xoS
5-7
US'
: T.M»
''4
Comments:
-------
EcBtem 0«a*arcn GfOup. ire.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
L*J |> l~\ \ \ ! I*\ 1 f\ L L ;
Uuf-
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
'Recovery" Rinses
Sample Identification
XAD Number
Impinger
Number
Impinger
Solution
Amount of
Sofution
(g)
Impinger Tip
Configuration
Impinger Weight
Final
(g)
Initial
(g)
Weight
Gain
fg)
O.i
\CC
C.ih/
JOG
/S/a-CH
|C&
0
'767.7
Total Weight Gain (g)
(,0
°
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: Dryer In
Run Number: 3
Sample Type: M26
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.51
Absolute Stack Pressure (in Hg) 29.14
Stack Static Pressure (in H20) -5.00
Average Stack Temperature (°F) 235.63
Stack Area (sq in) 240.53
Actual Meter Volume (cu ft) 77.350
Average Meter Pressure (in H2O) 1.11
Average Meter Temperature (°F) 51.47
Moisture Collected (g) 136.80
Carbon Dioxide Concentration (%V) 0.0
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 80.0
Dry Gas Meter Factor 0.9940
Nozzle Diameter (in) 0.140
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.326
Standard Metered Volume (dscf) 78.344
Standard Metered Volume (dscm) 2.219
Stack Moisture (%V) 7.61
Mole Fraction Dry Stack Gas 0.924
Dry Molecular Weight 28.80
Wet Molecular Weight 27.98
Stack Gas Velocity (fpm) 4426.55
Stack Gas Velocity (mpm) 1349.21
Volumetric Flow Rate (acfm) 7393.83
Volumetric Flow Rate (acmm) 209.39
Volumetric Flow Rate (dscfm) 5049.75
Volumetric Flow Rate (dscmm) 143.01
Percent Isokinetic 101.01
Percent Excess Air 1760.56
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Plant (LuAf /V]
Date
Operator
Sampling Location TVo*/- V
Sample Type
Run Number
Static Pressure (±) (in. H20)
Barometric Pressure (in. H2O)
kj»'Vllnv»Tl
(•3,-^^")
NtAi& •
WyW^L, toVl>
^4^*-
ft
XAD Trap Number
Filter Heater SettingJ°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
Nfl
a£fc
«4' mlnirtei
Traverse
Point
Number
Sampling
. Time
(min)
icr
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).tt3)
Velocity
, Head
((delta Ps).
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired . Actual
Probe
\ Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
31T
So
1 )
a-*,
/.t
vlt>
lltl*
6. 01
T^U
37-7
l(,30
T.tf-7
tuns
^tb.
218
2 s
4
^s\
tf «
,i>-i6
it
/os:
33
-53
.-•41
?•
.3
74-7
(.Z
'ZT^f
-"2-
-2S3
I'LO
Z3G
«f8
31
-fr
1,1*0
•Z-3
'SO
sr
•231
/« I
.20:3
/ 00
±
<^S
6?
-L4-
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page
Traverse
Point
Number
0 L
& 7
»
' • »
"
; • •
• «
4 4
• -
• . .
. *•
•*
Sampling
Time
(min)
•ZOZ-.TT
-2. to
•z.n-5-
zz/r
Z.12..F
2,4rO
*
.
".
-
Clock
Time
(24hr)
i^zr.T
c<733
mo,r
^a
ffifrE
•d&o*
*»
w
•
" *
^
i
*
t
- G3s
• _ Mefer
. Reading
«Vrrt),ft3)
»HtoS2
iHl 4 o
As*i
iH^.Mr
l^-fl-7
iss. r-»1
• C
^ ,•«
J
•f-
*
••^
\
: .
. • '
' ''• ^
.
.
Velocity
Head
((delta Ps),
in.H2O)
\,«4
\\k
••\A
L($l
V6
-.
'
f
r
•
-
-
Stack
Ts
(°F)
a**i/j
taaA
Z^O
^o
^4-0
"". *
..
i •
»""
. *
• •
*.'
•
.
Orifice F
Ditto
(delta H,
Desired
NA>
f
yn
.oe>f^
t
^
• •
-
•
• .
-.
%
'ressure
ential
4n.H2O)
Actual
. **
i *
*
•
Pump
Vacuum
(in.Hg)
°\
X
_^v
^
^
••j
»
• ;
'*
.
Comments:
-------
E
Q
-------
Facility: Gulp Alum. Alloy
Date: 12/05/97
Location: Dryer In
Run Number: 1
Sample Type: M23
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.39
Absolute Stack Pressure (in Hg) 29.02
Stack Static Pressure (in H2O) -5.00
Average Stack Temperature (°F) 236.29
Stack Area (sq in) 240.53
Actual Meter Volume (cu ft) 157.093
Average Meter Pressure (in H2O) 1.36
Average Meter Temperature (°F) 58.28
Moisture Collected (g) 216.90
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9800
Nozzle Diameter (in) 0.192
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.644
Standard Metered Volume (dscf) 154.653
Standard Metered Volume (dscm) 4.380
Stack Moisture (%V) 6.20
Mole Fraction Dry Stack Gas 0.938
Dry Molecular Weight 28.88
Wet Molecular Weight 28.21
Stack Gas Velocity (fpm) 4765.28
Stack Gas Velocity (mpm) 1452.46
Volumetric Flow Rate (acfm) 7959.61
Volumetric Flow Rate (acmm) 225.42
Volumetric Flow Rate (dscfm) 5490.84
Volumetric Flow Rate (dscmm) 155.50
Percent Isokinetic 97.50
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Rewirch Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run \n-oi
Page 1 of 2.
Plant
Date nkfll
Operator '
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
C-AA _
ilJMl'V'l
piO£VOi6
o.cy^)»Yl
Meter Box Number
Meter delta H @
DGM Factor (Y)
Noz2le Type & ID (in.)
Ambient TemperatureJ'F)
Assumed Moisture (% H2O)
K-Factor
44O
I™jO /I
• / Or
JJftO
t\Q2_
>S
_v 1 ,
•4^
K - JVtfc- 1 * V~" ^ ,*. Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
Point
Number
Sampling
Time
(min)
e
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps).
in.H2O)
Stack
Ts
Orifice Pressure
Differental
(delta H. in.H2O)
Desired
Actual
Probe
Temp.
Filter
Temp.
(•F)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(T)
Pump
Vacuum
(in.Hg)
\,c\
HO
38
ib
\f\
'/Q
3ft
Zl
6-1
\r\
(a
Ml
40
IOL -
-LO-
m
41
Ul
Ml
U
Uo
m
M8
Ll-
4^
\2-
Ml
''
^f
11
-t-.O
7,*
SO
1.1
Ifc
••\\p
\.
*-i_
'f
if
C.
I" JU
<«*
I'll
Kit
^^\
'1
IVJJ
•2,33
LS
S"
M3
Ml-
MM
loU
I.M
_u2>-
Ji2_
M2,
04-
-W4-
Comments:
liAi*-^1 cx^4(g> r^"
-------
Plant
Date
Ill-Cm
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H, in.H20)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
< -72
/.
Ml
i
1.4
Q-1
-Hi,-
(Ski,
1.4
i a
V
w
L U
MO
1.1
i.O
-U-
1-0
•tf-
O-Hb
\.o
Wi
tfO
,1*0
4U
Ul
ill.
I.O
to
C.MO-
*O. oo Ci
c-til
Jli
'UO
1.0
'1
J-4-
1.0
2-3?
_b£-
CVU
,c
7X^"
-•As
i»40
040
-y-
0.0<
&
Comments:
-------
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f ,i lr\ . hi \ ii IVN, CMirrN H Hi»5\/
rt--*f-
-------
Facility: :Culp Alum. Alloy 1
Date: 1 12/06/97
Location: i Dryer In
Run Number: i 2 !
Sample Type: IM23
Total Sampling Time (min) ; \
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O) ;
Average Stack Temperature (°F) |
Stack Area (sq in) ! i !
Actual Meter Volume (cu ft) i
Average Meter Pressure (in H20) ;
Average Meter Temperature J°F)
Moisture Collected (g) i
Carbon Dioxide Concentration (%V)
Oxygen Concentration! (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling; Rate (dscfm)
Standard Metered Volume (dscf) '••
Standard Metered Volume (dscm)
Stack Moisture (%V) i '••
Mole Fraction Dry Stack Gas ;
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm) ;
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic '
Percent Excess Air j
Concentration (g/dscm) :
Concentration (kg/hr) :
Concentration (ppmv)
Emissions (Ib/hr)
|
i
i \
240.0
! 29.51
29.14
i -5.00
i 236.91
240.53
163.784
1.24
49.86
119.50
; 0.5
20.0
79.5
0.9800
0.192
i 0.84
: 0.686
164.544
i 4.660
6.98
0.930
28.88
28.12
; 4932.08
1503.30
8238.23
233.31
5654.20
160.13
100.73
i 1992.23
0.00
0.00
0.00
0.00
-------
Ejjtem Retcarch Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run //; CfjQ" ° 2-:"
Page 1 of 2^
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
(>w piu ftL-
U.|taJr»
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
2<
| 7*H
.1*0
,R2-
i<*
6.2-
>t*~ ,1^^. 1 M PC/Ati
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
A.o
-%-
7- •'
"L.M/1
Vl
i£
Hi
10
¥.1 .of-7
Wo
wo
it
•L»K
VD
(I
MO
MP,
40
I'M-
l.'T
MO
MO
-U-
L^fj j
(Oil?
HO
Jo
y» 0.
f\o
AC?
a;
MT-
^^•I).o\
MS"
\.V
\.\
M1-
^M^.^^
Ul
s'n
ML*
\sl-i
Mb
\.-z-
I -
v,t
iv
Comments:
-------
Plant
Date
C,7.<
7|^
xvr:f
irs~
7Ai,<
•7^0
Clock
Time
(24hr)
Hl^.S"
fl?0.
i^.^V^
\iX>
it^«6
\*>OU
^05
\M,\
Gas
Meter
Reading
((Vm).ft3)
ns-,9
140 -i\
|9< MV
i<\l.Ui
111. D
U>£.(j,
10«.«|
I" J,U>5*
Velocity
Head
((delta Ps),
in.H20)
\.?>
\ ^
\,-v
I.L-
'•%
\.f
\.'
\.v,
\.LB
;.v«
I.U
L14K
Probe
Temp.
CF)
23Z_
•\^-o
•m\
.L^*»
IV^
Lu<
i-MS
Is,'^.
,/s £» i?li;
Filter
Temp.
CF)
z-c/3
LS\B
1^
1^1
l\0\
•LU\
^i.',
'Lt.U
6>S"
Adsorbent
Trap
Temp.
CF)
WZ-
M9To-
>AV
^\
.Mb
MH
M.i
^^
DryGa
Inlet
(Tm in)
(.0
(aO
Uo
bl
L/^-
Vff'J^-
t^
ua
i
s Meter
Outlet
(Tm out)
•46
4*?
gis
*<\w
^
<>"&
5Z>
^2>
Impinger
Exit
Temp.
CF)
5"«-
q
L>
1
1
7
Comments:
-------
Ecjtefn Se»earcn Greco, 'nc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run' Number '*m?>'^--.:-~
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number ;
1 : . 1 p • M 1 ,i MK, fiLVf^PN H U r>\J
/^L/5-/9>
Cb<ca (j
•lOG-360
Total Weight Gain (g)
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: Dryer In
Run Number: 3
Sample Type: M23
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.51
Absolute Stack Pressure (in Hg) 29.14
Stack Static Pressure (in H2O) -5.00
Average Stack Temperature (°F) 236.41
Stack Area (sq in) 240.53
Actual Meter Volume (cu ft) 148.612
Average Meter Pressure (in H2O) 1.14
Average Meter Temperature (°F) 52.30
Moisture Collected (g) 202.90
Carbon Dioxide Concentration (%V) 0.0
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 80.0
Dry Gas Meter Factor 0.9800
Nozzle Diameter (in) 0.192
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.619
Standard Metered Volume (dscf) 148.463
Standard Metered Volume (dscm) 4.204
Stack Moisture (%V) 6.05
Mole Fraction Dry Stack Gas 0.939
Dry Molecular Weight 28.80
Wet Molecular Weight 28.15
Stack Gas Velocity (fpm) 4506.95
Stack Gas Velocity (mpm) 1373.72
Volumetric Flow Rate (acfm) 7528.11
Volumetric Flow Rate (acmm) 213.20
Volumetric Flow Rate (dscfm) 5222.01
Volumetric Flow Rate (dscmm) 147.89
Dercent Isokinetic 98.41
3ercent Excess Air 1760.56
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eiilern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page-1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure{±) (in. H2O)
Barometric Pressure (in. H2O)
(.uV Ai. AC.
izltri-7
Dtt/y/t,
UUA
»vi5-S
•4
•-"i
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
2-Hc?
VYrH^
Z-^S
& do&[4
fl.rAooSfSio1
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A<+rv
I.-154
.'Wo
.ITJ-
4tT
U>. J-
*-.^2-
/-) . 2<3 Diagram of Duct
Schematlc of Traverse Point Layout
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps).
in.H20)
Read and record all data uvery ±
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H?O)
Desired
Actual
minutes
CGt-° ^/Vll^
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet Outlet
(Tm in)
(Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
.1
43
37
ft
\5.0
\uoO
,1
IS
-SI.
3SL
ISi
"Sw.iu
bO
Ml
v,o
Vi
AA.
40
bo
•ft
4o
-7
41
ao
l.U
tfi
r».t.
l.U
41
iai
44-
'L-S""
.. 2.1
5.3
so
1 -
MI.
t.M
45
__L3_
H\
1.3
U-O
/tl.ifc.
I'D
IfS
S
'S
I.I
t.o
9)
JL£
,32
L-Slo
Comments:
-------
Pagl
of
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
A-G.
i*
^ 7
7
flj?
£
Sampling
Time
(min)
^OZ.i>~
2.16-
ill.*"
i^5T~
-z.it.s-
-MjO
Clock
Time
(24hr)
\'\l±'.^~
iflS^
iH^.b"
1^4'X
mc-sT.^"
lisQS
Gas
Meter
Reading
((Vm).n3)
/Vt.Coif
\MU,%
\ S>0.-)
Kg.«\
f^.Sv
/bl.-7JO
Velocity
Head
((delta Ps).
in.H2O)
\ .\
I.I
W
^
2^^
2.3^
tSq
Z3T
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
i.jiA\*-
*.O
/,o
,3?U
•*1
^7
.^L.
/- ^>.^l.t
Probe
Temp.
CF)
•i4/
^-SV
£SS~
23 W
•z-V«^
250
4G,P/t^"
Fitter
Temp.
(°F)
•Z±*
;xuo
•^^n
•i.^i-
1L.O
Adsorbent
Trap
Temp.
(°F)
((V
^i
'-i'4
HV
Wi~"
%
Dry Gas
Inlet
(Tm in)
s •/
^"2-
S'.S^
s"^:
<7j
\> /
^1
> Meter
Outlet
(Tm out)
V.-s-
>V5""
-------
Eastern Qeaaarcn G«sco. '-r\c.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
/":. i> . ftV.^'.r^tVN R lUx,
/^J^/T-
Cft(\ /Wl€l
rv++-v^ ,03
^^
/qo^ fy.i4e. / P ~^.\ ^,.i-Vci5. (rei
ZCC -3
Total Weight Gain (g)
-------
Facility: Gulp Alum. Alloy
Date: 12/05/97
Location: Dryer Out
Run Number: 1
Sample Type: M26
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.38
Absolute Stack Pressure (in Hg) 29.30
Stack Static Pressure (in H2O) -1.00
Average Stack Temperature (°F) 186.44
Stack Area (sq in) 490.87
Actual Meter Volume (cu ft) 98.879
Average Meter Pressure (in H2O) 0.56
Average Meter Temperature (°F) 59.04
Moisture Collected (g) 133.90
Carbon Dioxide Concentration (%V) 1.0
Oxygen Concentration (%V) 19.0
Nitrogen Concentration (%V) . 80.0
Dry Gas Meter Factor 0.9880
Nozzle Diameter (in) 0.215
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.409
Standard Metered Volume (dscf) 98.146
Standard Metered Volume (dscm) 2.779
Stack Moisture (%V) 6.04
Mole Fraction Dry Stack Gas 0.940
Dry Molecular Weight 28.92
Wet Molecular Weight 28.26
Stack Gas Velocity (fpm) 2112.59
Stack Gas Velocity (mpm) 643.92
Volumetric Flow Rate (acfm) 7201.48
Volumetric Flow Rate (acmm) 203.95
Volumetric Flow Rate (dscfm) 5411.99
Volumetric Flow Rate (dscmm) 153.27
Percent Isokinetic 102.17
Percent Excess Air 889.51
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern ftneinh Group. Inc.
MODIFIED METHOD 5 DATA SHEET
CO 1 -
Run
Page 1 of
Plant
Date
Operator
Sampling Location \&\ < K.
Sample Type
Run Number
Static Pressurejt) (in. H2O)
Barometric Pressure (in. H2O)
CwJ> M/ A
'2/ffa*
Alum / 3"S
€H ooT
Pm/H^L
1
-1-0 "
2.9 .-S 3ct
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
ZSO
G'iNflt*
150
feo
• OI^IO"
.C)@ IS"'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H20)
K-Factor
d-3>
l.m
O,q&£
O.l\$
3o*
8%
|,(,i_
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every _^_ minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
«Vm).ft3)
Velocity
Head
((delta Ps),
' in.H2O)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(T)
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
-r
A-V
1ft. 0
i .3
"LOT
7 H
i
OS :
2 .
M-
0%
loi
\ , >M
H
40
l.jd.
iMO
Sb.Y2.0-?-
V
. O
£
6 O
(,0
3.
33
7.4 I
2-0
10
6, \ ,
\6 "
C ,
Qv(_
O
O. G
Z-s O
O
'
r.\i
O.C'L
1ST-
o.os'
6 i
10
\\
fo > b
n-01/
2-5 2-
Ii±
5H
O
J C ' <
/ o
i : <>" o
•K-O
frl.l.
^
S-o
H
Q
o.i
£,0
JO
SO
11: fco
ZOO
1.04
S'f
ILO
(n 1
0
tsv
fo
AE
:>-.£
iVfi
0
O.tS
T--O
U v -H
*
n.i i
60
O
00
fi. IV
14,1
r/
to
IS
io~v -
q
Z-0
H "
\il-C?
0 MS
H 30
S, 0
o^o
3Z
2 -S
t
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
-
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
—
Stack
Ts
CF)
Orifice F
Differ
(delta H.
Desired
'reusure
ential
in.H2O)
Actual
\
Probe
Temp.
(°F)
Filter
Temp.
(°F)
Adsorbent
Trap
Temp.
(°F)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Implnger
Exit
Temp.
(°F)
Xj
,
Pump
Vacuum
(in.Hg)
i
Comments:
-------
.G
. inc.
MOISTURE RECOVERY FORM FOR METHO
C
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
C ^ LjJ (> R \ 1 i Tr\ i (\ i ^~»-\ M 1 1 n V 5
*Y / " 11 fjt ^ ^V ^0-*K*
^\,p Jrv<"-F J/5 ^rT1 LL^ (Jj-^
^44^^^ ^/nA " ~~
/
rOd-r,- r^uJoV**. / 1 ^Ct-^-n V (-Ti^V-k'i.1
7
ill ^?^i( 'v — /
Impinger
Number
Impinger
Solution
Amount of
Sofution
(g)
Impinger Tip
Configuration
Impinger Wefght
Final
(g)
'
Initial
(g)
Weight
Gain
(g)
o.i
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: Dryer Out
Run Number: 2
Sample Type: M26
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.50
Absolute Stack Pressure (in Hg) 29.42
Stack Static Pressure (in H2O) -1.00
Average Stack Temperature (°F) 181.83
Stack Area (sq in) 490.87
Actual Meter Volume (cu ft) 108.753
Average Meter Pressure (in H2O) 0.14
Average Meter Temperature (°F) 57.27
Moisture Collected (g) 80.00
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 19.5
Nitrogen Concentration (%V) 80.0
Dry Gas Meter Factor 0.9880
Nozzle Diameter (in) 0.215
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.451
Standard Metered Volume (dscf) 108.124
Standard Metered Volume (dscm) 3.062
Stack Moisture (%V) . 3.37
Mole Fraction Dry Stack Gas 0.966
Dry Molecular Weight 28.86
Wet Molecular Weight 28.49
Stack Gas Velocity (fpm) 2270.87
Stack Gas Velocity (mpm) 692.16
Volumetric Flow Rate (acfm) 7741.05
Volumetric Flow Rate (acmm) 219.23
Volumetric Flow Rate (dscfm) ' 6050.61
Volumetric Flow Rate (dscmm) 171.35
Percent Isokinetic 100.67
Percent Excess Air 1191.93
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
..Inc.
MODIFIED METHOD 5 DATASHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location ""bft-f'et^-
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
|lv /\i_
<\^.
SS
fyv<^K)*AOUT
HCL,L.TKVN
•^_
-l-oo"
^liSl
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
2.SG
rVN^t*
2^0
6iO
• Oi/OiV
,0|£jO''
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
ft-l^-
l.£]3
o 1^8
0 !XlS
30°
%**
1 iCjT-
i T ^ ^
~IQ i t
1 F^
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every I P minutes
Traverse
Point
Number
Sampling
Time
(min)
0
Clock
Time
(24hr
(7 S3
£
Gas
Meter
Reading
((Vm).tt3
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired
Probe
Temp.
Actual
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
B-
/o
7_
2V
20
2«3
±t
HZ-
0,5-3
V3
2.3V
O
JO
on
ft
S
40
0 ,
O-SE
,, S
SO
O, Xf.
/ o
0.2.G
o.xt,
r-o
'9-
.V
o,
/o '
ILO
1.7,$
/.2.S
/oo
/o:
/.ffc
-TV/
"3 o
HO
/o:
25C,
yt,
4^
IIP
0. O/
/0i-
u:io
1*0
i I -O
I.ZO
I9
^
V 0
it
ISO
70 1
V-0
(0
ICO
n to
T.C.V/.O
l.oA
3 .0
II'OG
ft.-f-S
o
iv./o
70
ISO
1-C.CJ
r
42 ' J>0
1C
-5
/ 0
0
0,07.
Uo
.<3.o V
vc,
i a
l o
O.o1/
60
/. o
i <;
Lo
/. o
(0
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),fl3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice F
Differ
(delta H,
Desired
ressure
entia!
in.H2O)
Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
CF)
Dry Gas
Inlet
(Tm in)
3 Meter
Outlet
(Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
ire.
MOISTURE RECOVERY FORM FOR METHOD*
Plant
Date
Sampling Location
Sampfe Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XADNumber
duJ^ RL^'.CS,^ ftiUy*
r^M^\ 3j A
A
^"^
rO^r,- A.JnU / T c.^cv C, vk'.n
'
II 1 ft^l "3.
Impinger
Number
Impinger
Solution
Amount of
Sofution
(g)
Impinger Tip
Configuration
Impinger Weight
Final
(g)
Initial
(g)
Weight
Gain
(9)
o.i
\Cfi
ICC
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: dryer out
Run Number: 3
Sample Type: M26
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.35
Absolute Stack Pressure (in Hg) 29.28
Stack Static Pressure (in H20) -1.00
Average Stack Temperature (°F) 187.92
Stack Area (sq in) 490.87
Actual Meter Volume (cu ft) 102.267
Average Meter Pressure (in H2O) 0.58
Average Meter Temperature (°F) 51.52
Moisture Collected (g) 151.40
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9880
Nozzle Diameter (in) 0.215
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.427
Standard Metered Volume (dscf) 102.390
Standard Metered Volume (dscm) 2.900
Stack Moisture (%V) 6.52
Mole Fraction Dry Stack Gas 0.935
Dry Molecular Weight 28.88
Wet Molecular Weight 28.17
Stack Gas Velocity (fpm) 2212.16
Stack Gas Velocity (mpm) 674.27
Volumetric Flow Rate (acfm) 7540.91
Volumetric Flow Rate (acmm) 213.56
Volumetric Flow Rate (dscfm) 5620.93
Volumetric Flow Rate (dscmm) 159.18
Percent Isokinetic 102.62
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Extern Research Group, Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator ,
Sampling Location ^bV-it £-
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
C<,ur* fo.flL
Mt.ll*
m«)>(/^rS
*AH oJT
rvta_/?n
3 '
- |,oo"
ZS.3G
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check ,
Final Leak Check
*-
•2,^0°
6'N/acy
2^0°
CoO
0,0l@/o"
O.Oltfio'1
Meter Box Number
Meter delta H @
DGM Factor (Y) l
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
d-3v
l.frl^
o.«ttS
oa\S
3£»
**%
1 ,k2-
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every _j_j_ minutes
Traverse
Point
Number
Sampling
Time
(minf
Clock
Time
Gas
Meter
Reading
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H. iri.H2Oj
Desired Actual
Probe
Temp.
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in-Hg)
ft-12-
SL
43
S.O
10
2.HI.-V
zss
IL' K
fl .<
.0
o
It. '
.>
V?
4-0
S.o
2.0
30
0.
J^o.
80
.0 b
0. fG
-ia.
10
*
•2.0 -
OH
0, Ot>
1.0
IV:
.O
1
D
. 1
OCi
1 0
iio
6-OO
O.ec
1-0
10"
VTO
132 .8*0
no
1 0
iHo
ISO
. 33
> 2-
(Go
.SS
MS
>o
5*4
^•s
,3?
-*ia.
loo
Zoo
5-ci
XI 0
(•of
.Z.C
feO
-40
c 1
6/0
ISO
2S2.
263
• 0
o|
ID"
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(°F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
(°F)
Filter
Temp.
m
Adsorbent
Trap
Temp.
(°F)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
(°F)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eawem Ow*orcn G/oco.
MOISTURE RECOVERY FORM FOR METHOD
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery' Person
Recovery Rinses
Sample identification
Fitter Number
XAD Number
r* .1 Q i . • r\ i i
C^'.D \V^
-------
Facility: Gulp Alum. Alloy
Date: 12/05/97
Location: Dryer Out
Run Number: 1
Sample Type: M23
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.38
Absolute Stack Pressure (in Hg) 29.30
Stack Static Pressure (in H2O) -1.00
Average Stack Temperature (°F) 193.16
Stack Area (sq in) 490.87
Actual Meter Volume (cu ft) 99.354
Average Meter Pressure (in H2O) 0.56
Average Meter Temperature (°F) 54.78
Moisture Collected (g) 122.50
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9810
Nozzle Diameter (in) 0.215
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.414
Standard Metered Volume (dscf) 99.258
Standard Metered Volume (dscm) 2.811
Stack Moisture (%V) 5.50
Mole Fraction Dry Stack Gas 0.945
Dry Molecular Weight 28.88
Wet Molecular Weight 28.28
Stack Gas Velocity (fpm) 2142.78
Stack Gas Velocity (mpm) 653.12
Volumetric Flow Rate (acfm) 7304.40
Volumetric Flow Rate (acmm) 206.86
Volumetric Flow Rate (dscfm) 5464.34
Volumetric Flow Rate (dscmm) 154.75
Percent Isokinetic 102.33
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of I
Plant
Date
Operator
Sampling Location "^ fl^€ Vt_
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Coi> rt/fl
p_ltf K H-
rtvul^ /TS
Brt abT
"bi'Of iVJ
1
- t-0"
7.4 J^"^9
XAD Trap Number &vjT - (
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting ("F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
t J (i
^° P/ftt.^
1$^
(t>0
• OI&QCi'
• tj ^? iS'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
rt-'Sfe
l,SilC
c>i^fi I
0,2, i^
^&-?°
g
1-C.Z
>*
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all d«ta every minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pwmp
Vacuum
(in.Hg)
O
OKOQ
/O
0% vo
y o
6 ,
o
vs
3 S
2.0
2.OL-,
Zfrl
7.51
i
VO
. 3
.<><&
v
Ql
t£L
.5,0
a on
liii
Jj^-
(Ja -PPt)*
,JJL
WL
5o
.3H
Si
Hi.
. ji
. V3
sr
st,
. o3
y 11
7.6
HI
VI.
4.5"
10
Bfe.2.
(ft)
l.feT.
151
It
l 33
1. 1
LOO
60
. e
no
IT. i
A- B.
JOl'rS?
ISO
.,0
IUD
O.ciM
0.0^-1
MS-
.01
o oM
153
2S5"
I Ok .
7SS
TXS
ST.
H9-
7.0
.07.
0.04
IS*)
T..O
SO
Bl
2.0
n? .1
/S"
aso
S3
51
10.
7 OO
/ V.ao
31"!
10 <\
•2.10
/M'ro
•LT-O
^/:^>
11
z*.l
Iffi
LI,
- "
.33
Hlo
CL
IT
1ST-
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).tt3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice F
Differ
(delta H,
Desired
'ressure
ential
in.H20)
Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
(°F)
Dry .Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)'
i
Pump
Vacuum .
(in.Hg) '
Comments:
-------
Eastern S«eorcn Grci-o. .'nc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number ^-^ !
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number '^:-^^
XAD Number f ;
( . , 1 A . M \ . i p
loo. I
ICC
I4PLC
O
E/^P TV
-.3
Total Weight Gain (g)
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: Dryer Out
Run Number: 2
Sample Type: M23
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.50
Absolute Stack Pressure (in Hg) 29.42
Stack Static Pressure (in H2O) -1.00
Average Stack Temperature (°F) 188.29
Stack Area (sq in) 490.87
Actual Meter Volume (cu ft) 107.848
Average Meter Pressure (in H2O) 0.83
Average Meter Temperature (°F) 55.38
Moisture Collected (g) 74.70
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 19.5
Nitrogen Concentration (%V) 80.0
Dry Gas Meter Factor 0.9810
Nozzle Diameter (in) 0.215
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.447
Standard Metered Volume (dscf) 107.267
Standard Metered Volume (dscm) 3.038
Stack Moisture (%V) 3.18
Mole Fraction Dry Stack Gas 0.968
Dry Molecular Weight 28.86
Wet Molecular Weight 28.51
Stack Gas Velocity (fpm) 2321.94
Stack Gas Velocity (mpm) 707.73
Volumetric Flow Rate (acfm) 7915.15
Volumetric Flow Rate (acmm) 224.16
Volumetric Flow Rate (dscfm) 6137.20
Volumetric Flow Rate (dscmm) 173.81
Percent Isokinetic 98.47
Percent Excess Air 1191.93
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Reiearch Croup. Inc.
MODIFIED METHOD 5 DATASHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location T>f*-yt! fl_
Sample Type
Run Number
Static Pressure (±l(in. H2O)
Barometric Pressure (in. H2O)
£wU> AL rt<-
l2.|fel4?-
ftV*^ /"ys •
iSliJ o'OT"
^ mX. / A^
"2_-
- /-Ob"
2£l«^l
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
-
2SO
G;>/fUy
t$O
C?O
lO^Jj^'1
iO i(£*i£ "
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (T)
Assumed Moisture (% H2O)
K-Factor
A "3?
1 1£(6
0 ftb^
0(2-\£
30°
&
\t(o'l~
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every _j_O_ minute*
«VJX
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps).
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
iO
3
il
7,0 >
7.*, 3
10
1ML
1-SH
42-
iv
MO
S.M
Ml
.1?
30
IS'L
HO
S3
Mo
•80
OT. b'S
,02-
.oH
ST.
3-8
no
1MO
HO
Si
10 if
.o^
o^
MO
£2.
I/C)
so
. HO?
.01.
•LS
^
MO
53
1^.
01
11,0
H.T.O
..ML
ICO
"VH
t-t
St
llfl
ZbO
LbS"
• SO
I93
•SI.
7.t>L
Li
3
, J . 50
T.
. «, 7.
2 GO
SI
1L J
It 00
.•LI
3
ft. f O
, 2/S
T-53
.11
ISt
-LSI
feV
ilO
i l.J
-sro
Ml
6
V3
loo
LO . 1
-IMS"
IH'i
HI
43
T-l 0
T.LG .
-to 2.
44
H.t
iO
Z70
153
HO
/i
I 130
1.2.
T.03
a
il.
Tm-
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Page*
of
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),tt3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice F
Differ
(delta H,
Desired
'ressure
ential
in.H20)
Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm in)
s Meter
Outlet
(Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern Rejaorcn Graup. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
FilterNumber
XAD Number
1 ; i -V r\ PI In rrviryvfyv H llftxV
ft/Tp^
C,k\5
I ^brvis
-^
•7.00-360^.
Impinger Tip
Configuration
K^ocKouL
CsKart hp)
/AeaK-iect
/HaS'^el
r^ocXf^ai.
AcJ!,4i'&i.
Impinger Weight
:Final
(9)
530;.^
5213
5X3.^-
^SS.g
7?5?
rt°oofe
Initial
(g)
4«.r
5^,1
6^3. >
4*3.3
7)s;K
^^.i
Total Weight Gain (g)
Weight
Gain
(g)
;T3,7
- 1
<9
. 5^
^o.S/
Tf'.l
-------
Facility: Gulp Alum. Alloy
Date: 12/06/97
Location: dryer out
Run Number: 3
Sample Type: M23
Total Sampling Time (min) 240.0
Corrected Barometric Pressure (in Hg) 29.35
Absolute Stack Pressure (in Hg) 29.28
Stack Static Pressure (in H2O) -1.00
Average Stack Temperature (°F) 191.00
Stack Area (sq in) 490.87
Actual Meter Volume (cu ft) 101.063
Average Meter Pressure (in H2O) 0.60
Average Meter Temperature (°F) 49.60
Moisture Collected (g) 114.00
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9810
Nozzle Diameter (in) 0.215
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.420
Standard Metered Volume (dscf) 100.847
Standard Metered Volume (dscm) 2.856
Stack Moisture (%V) 5.06
Mole Fraction Dry Stack Gas 0.949
Dry Molecular Weight 28.88
Wet Molecular Weight 28.33
Stack Gas Velocity (fpm) 2282.33
Stack Gas Velocity (mpm) 695.65
Volumetric Flow Rate (acfm) 7780.10
Volumetric Flow Rate (acmm) 220.33
Volumetric Flow Rate (dscfm) 5861.72
Volumetric Flow Rate (dscmm) 166.00
Percent Isokinetic 96.92
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Croup. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location TW-f ft*-
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
( .-if /SJ A*.
il/t/o*
r^^fi/ T*
i)wjji»> .ajrU'T
P.uX,r\
3
I./NS'1'
I^.M.
XAD Trap Number.
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
—
T.V>
i-' f\^-X
2 SO
fcO
ourW
.f\f(Q(0"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-3-S
!.•*&
.^tfl
o.ll5"
36-
«
i.fel
•>
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired , Actual
Probe
Temp.
(•F)
Filter
Temp.
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(QF)
Pump
Vacuum
(in.Hg)
10
.13
2VO
MO
•1.0
n
49
£,«•»
/(,. 25*
.r
1C.
Zt *.i .
.. zz
Vo
It ••
7.-1
L-MO
1H2.
-7
52-
,5"
5.1
3.5'
V;
ft: if
.75
Ml
100
7.07.
1 . SI
I..SI
20 H
t.5-1
3
n
rw
I.I
205"
13.
•30
•Z.O'/
l-l?-
iss"
MO
ST.
151 .
.. 3
toiT
T-M5"
ft
*
•LOJ
2L
HS
53
-S"
HO
f>
m.
50
•^ : 33
H/
JHS
5
.0?)
. oi'
Ml-
, OH
01,
IMS'
HI
Ml
70
-=_0jz_
BO.
.&(£>!&
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
/
<
-•-'
Sampling
Time
(min)
»
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(°F)
Orifice F
Differ
(delta H,
Desired
'ressure
ential
in.H2O)
Actual
Probe
Temp.
(°F)
Filter
Temp.
(°F)
Adsorbent
Trap
Temp.
(•F)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
Comments:
-------
Eastern (-,- (^,.hlG. / (^.v^A (^..r-K^
Impinger
Number
Impinger
Solution
Amount of
Solution
(9)
Impinger Tip
Configuration
Impinger Wefght
Final
(9)
Initial
(3)
Weight
Gafn
(g)
r^ Hp)
^3.7
I CC
2 . 5"
» 7
Gel
Total Weight Gain (g)
JS3-7
-------
Facility: Gulp Alum. Alloy
Date: 12/8/97
Location: Furnace Inlet
Run Number: 1
Sample Type: M26
Total Sampling Time (min) 327.0
Corrected Barometric Pressure (in Hg) 29.33
Absolute Stack Pressure (in Hg) 29.20
Stack Static Pressure (in H20) -1.70
Average Stack Temperature (°F) 95.39
Stack Area (sq in) 1134.11
Actual Meter Volume (cu ft) 143.623
Average Meter Pressure (in H2O) 0.54
Average Meter Temperature (°F) 54.71
Moisture Collected (g) 31.50
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9800
Nozzle Diameter (in) 0.155
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.433
Standard Metered Volume (dscf) 141.734
Standard Metered Volume (dscm) 4.014
Stack Moisture (%V) 1.04
Mole Fraction Dry Stack Gas 0.990
Dry Molecular Weight 28.88
Wet Molecular Weight 28.77
Stack Gas Velocity (fpm) 3515.91
Stack Gas Velocity (mpm) 1071.65
Volumetric Flow Rate (acfm) 27690.62
Volumetric Flow Rate (acmm) 784.20
Volumetric Flow Rate (dscfm) 25425.75
Volumetric Flow Rate (dscmm) 720.06
Percent Isokinetic 102.46
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) . 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
[Run i|,>J
Page 1 of
Plant
MDate
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
l\u\f ALtiLU,^
iilSKn
CLM*. Ul<-\
AOL
I
- \-~\
^.^•>>
XAD Trap Number ^
Filter Heater Setting ("F) .
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
-i H k
MV'iM<'i
14%
\Cfl<£pfe"
Meter Box N',;nber
Meter delta H ©
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (CF)
Assumed Moisture (% H2O)
K-Factor
A-vo
i.TJi'f
.'XSn
.u>r^7->"
^*f **i * / ^S ^ '
>-
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data evary iQ minutes
Traverse
Point
Number
fit
P
%
si
t
T\
ft^
/
£
ftf
I
i
M
«
3
/SI
I
I
Sampling
Time .
(min)
O
d iO
o iU
, "?o
r -\o
r st>
^ 1*0
^ 'To
< <3o
- lV^
\ IMO
^ iT^
IU)
lOD
i*D
Clock
Time
(24hr)
oS1^?
-lj* — _^*i
tx^Ti^Dc-^
/£>08
/oi8
It'tS
10 'iS
IftMS
iofiR
\>o-si
\nX
\\iS
,v^
•»n^
i\S»
\1C#
>Z|>
Lo.TL.
t-S ,?>(x.,
T D . ( f,
1 5".^-! .
8^ -TM
SS-.o
«^.a/i
^:i ss-
SI.UR
lol-S^
/C^.V^.
1 o^ . ^ r/»
U*-\
t|lo."7o
Velocity
Head
((delta Ps).
in.H2O)
!,?>
i ,\
1.)
1.?.
\ -^~
i.A.
»iV\
\-H-
\.y
i-tj
>. o
..o
.950
.xo
,«2-
;-)^
.1 rST
.l»1
Stack
Ts
CF)
2-oo
1(3
'AT
«8
lsfc
i5"0
So
1-t-,
IOQ
f^C^
\^C>
5tT
°ih
S':-T
T?
11
I '2.0
So
LiiM4-
Orifice F
Differ
(delta H,
Desired
J ~ o 01
'ressure
ential
in.H2O)
Actual
^z-
.--T3
. u-i
,44.72-
•^C)
.ss'
.T£>
,-)8
.14
.S^
,M^
• S^T
-HL\
M^
•MS"
^^
.?*S
.'i7
U Q ( , "
Probe
Temp.
'CF)
i.-i~3
iz-t,
±1-1
<5-SO>
^-c.
^*~^>
AM?i
^^4
•^~»
Z52_
5.MU
X'-l'y
^^>('-)
•^lc.5,
2-Ua.
2t>(y
2^
•ili
f
/
Filter
Temp.
CF)
-32-
22f,
•^5V
•il-l
D->^\
^3")
3-^Jl
•«s
^3f
.^^i
2^ l
'^V
JL^
aT^(r
^S-)
2^-7
^7
2 si
^
•>
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm in)
Si
T.3
^"•7
L.O
CoO
U,
(o-l
U'i
U
(*;<
L>I
^>JK
U>i
U,l
Ui
tp|
C,\
L,i
s Meter
Outlet
(Tm out)
M"1-
M2_
•A\
H^
MU
Hb
77
Ml
^
S*
M?
M*i
M^
N^?
W»
g« '
g^
MR
Impinger
Exit
Temp.
CF)
}3
5 >>
"W
7,
Si/)
s?
^^
^
so
Vn
31
"SSf
=5S>
•5C/
?9
^9
^
^
Pump
Vacuum
(in.Hg)
^S
f.l
.i*
Jf
r?
^
^
5T-
ST
-------
Plant
Date
Location
Sample Type
Run Number
Operator
PagdHbf
Traverse
Point
Number
s
s
Sampling
Time
(min)
ISO
..
s
Clock
Time
(24hr)
l^MVfcT
."'
s
Gas
Meter
Reading
((Vm).ft3)
vVL'Vlo
*
,.-•
s
x
,''
Velocity
Head
((delta Ps).
in.H2O)
,S1
.•
-"
Stack
Ts
(°F)
l-Zo
Orifice F
Differ
(delta H,
Desired
r.'"
..'•'
'ressure
ential
in.H2O)
Actual
iMJ?
/
S
S''
/
Probe
Temp.
CF)
^
/'
Filter
Temp.
CF)
..-'•
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet Outlet
(Tm in) I -(Tm out)
^__ .- "
. ^*
Impinger
ExA
Temp.
CF)
Pump
Vacuum
(in.Hg)
Comments:
-------
Plant
Date
£uup
li_m<}T
Location
Sample Type
£v««v».C•/
"7S
V
In
A 3
-71
•11
3
IT
Ml
(VM
So
Lit
•300
LOST
c2-
A *5
Z'S'
2. -1
Comments:
-------
MODIFIED METHOD 5 DATASHEET
Ru
Page
bf
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure^) (in. H2O)
Barometric Pressure (in. H2O)
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps).
in.H2O)
Stack
Ts
<°F)
Orifice F
Differ
(delta H,
Desired
'ressure
entJal
in.H20)
Actual
Probe
Temp.
(°F)
Filter
Temp.
(°F)
Adsorbent
Trap
Temp.
(°F)
DryGa
Inlet
(Tm in)
s Meter
Outlet
(Tm out)
Impinger
Exit
Temp.
(°F)
Pump
Vacuum
(in.Hg)
Comments:
-------
Facility: Gulp Alum. Alloy
Date: 12/9/97
Location: Furnace Inlet
Run Number: 2
Sample Type: m26
Total Sampling Time (min) 340.0
Corrected Barometric Pressure (in Hg) 29.29
Absolute Stack Pressure (in Hg) 29.19
Stack Static Pressure (in H20) -1.40
Average Stack Temperature (°F) 113.15
Stack Area (sq in) 1134.11
Actual Meter Volume (cu ft) 141.637
Average Meter Pressure (in H2O) 0.95
Average Meter Temperature (°F) 62.09
Moisture Collected (g) 40.80
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9800
Nozzle Diameter (in) 0.156
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.405
Standard Metered Volume (dscf) 137.578
Standard Metered Volume (dscm) 3.896
Stack Moisture (%V) 1.38
Mole Fraction Dry Stack Gas 0.986
Dry Molecular Weight 28.88
Wet Molecular Weight 28.73
Stack Gas Velocity (fpm) 3369.28
Stack Gas Velocity (mpm) 1026.96
Volumetric Flow Rate (acfm) 26535.74
Volumetric Flow Rate (acmm) 751.49
Volumetric Flow Rate (dscfm) 23518.44
Volumetric Flow Rate (dscmm) 666.04
Percent Isokinetic 102.09
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATASHEET
Run F
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
C'-av.r (\L. Aii-i>^
.MlNTi
^Orf-iiS
^-u-tvx. 1*\
-------
Plant
Date
CoA.f
10-\dt^~_
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
«V").n3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired
Actual
Probe
Temp.
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF?
Pump
Vacuum
fln-Hfl)
VXO
KS1
ii°o.
1 1
1 1 O
I.T
cs
T-S1
10
"70
(Sr
2 2-
H5T"
Ml
7|
Mi
Hi
Z-SO
10
AT—
no 7
O U O
10
ST7
.O
•l-z-
• Tl
-70
ar?
n.
,7
.-31
* JC
Comments:
-------
Facility: Gulp Alum. Alloy
Date: 12/10/97
Location: Furnace Inlet
Run Number: 3
Sample Type: M26
Total Sampling Time (min) 332.0
Corrected Barometric Pressure (in Hg) 29.32
Absolute Stack Pressure (in Hg) 29.22
Stack Static Pressure (in H2O) -1.40
Average Stack Temperature (°F) 114.85
Stack Area (sq in) 1134.11
Actual Meter Volume (cu ft) 138.653
Average Meter Pressure (in H2O) 0.96
Average Meter Temperature (°F) 73.00
Moisture Collected (g) 42.20
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor " 0.9800
Nozzle Diameter (in) 0.155
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.398
Standard Metered Volume (dscf) 132.051
Standard Metered Volume (dscm) 3.740
Stack Moisture (%V) 1.48
Mole Fraction Dry Stack Gas 0.985
Dry Molecular Weight 28.88
Wet Molecular Weight 28.72
Stack Gas Velocity (fpm) 3417.98
Stack Gas Velocity (mpm) 1041.80
Volumetric Flow Rate (acfm) 26919.36
Volumetric Flow Rate (acmm) 762.36
Volumetric Flow Rate (dscfm) 23786.58
Volumetric Flow Rate (dscmm) 673.64
Percent Isokinetic 100.50
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Extern Rnearch Group. Inc.
MODIFIED METHOD 5 DATASHEET
Run E
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Cidf AUIW,
a\»o\^-7
\i**tt**-ic. —
t-LLLvt . L*V\ •
*c£
3,
-\.vjl
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
•2J$
VGl+**>
2M-S'
o.ooVfelO
•oor
, vz.
o
-7C
100. IZ-
Wi
Ikn
°
70
0 , CO <
u~7
•-/I
fci'
NCI
112
/.i •>
feifl
•UL&-
I00_
.
J£_
iTl
.vi.
_^lLL
-XLL
.57
.MIU
fHO
l^
iSHL
f ••%=!> .T
7.S7T
.TV
j^i
jis:
-24^
Comments:
-------
Plant
Date
(jLLLp"
)£r/
V£0
"W-.
WHXV
->0>
"?)/>0
Clock
Time
(24hr)
(bit
|id'2i
IV^>'
/^^/
nAn
Gas
Meter
Reading
((Vm),tt3)
NU,^(/
/ ^7) . K3.
/\^to\
/JT9.9
;b5i">S
1-70 / p/ia-^r—
po?. I luA.^i'ri
\
l\l&.(* ^
•
Velocity
Head
((delta Ps),
in.H20)
.
cfZ-
Orifice F
Differ
(delta H,
Desired
8*o
.5t>
,^7)
.s"
..a-sT^
Adsorbent
Trap
Temp.
CF)
DryGa
Inlet
(Tm in)
£-76
r.
-] L-
-7^-"
ir
1^
-1(4
"?4
s Meter
Outlet
(Tm out)
M
(a'<
d> ?.
(*-L-
L>-2~-
(*/
(ni
Impinger
Exit
Temp.
(°F)
,C2_
^<
?;?j
^5~/
s-/
T/
3~l
Pump
Vacuum
(in.Hg)
^^
^
^
c^
3
^
^\
Comments:
-------
Facility: iCulp Alum. Alloy
Date: ! 12/11/97
Location: ; Furnace Inlet
Run Number: ! 4 1
Sample Type: im26 i
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H20)
Average Meter Temperature (°'F)
Moisture Collected (g)
Carbon Dioxide Concentrationi(%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V) :
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling: Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V) :
Mole Fraction Dry Stack Gas '
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr) '.
Concentration (ppmv) ;
Emissions (Ib/hr) :
,.
j
\
i 380.0
29.99
29.87
-1.70
106.66
! 1134.11
! 130.367
! 0.82
54.59
: 79.30
0.5
20.0
i 79.5
; 0.9800
0.152
0.84
0.346
; 131.501
3.724
2.76
0.972
28.88
28.58
2870.78
875.01
22609.70
640.31
20447.60
579.08
: 105.78
I 1992.23
0.00
0.00
! 0.00
0.00
-------
Eastern Research Group, Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant ft|,Jlp
Date '
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Alij i/rj/ilL/*
Id- lUS^
M/HFs
fT_kff\ l/TU>f
fii.',c
<4
-*/-•)
,50
LXAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
INA
;^s-^
4-' C'-ilA.)
3<.L>
^|
PClZfr:' 'l
,o*.-.<97
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
r\ -^o
/ "7^3
!*7&r
.(s^
'#£,'
• **f
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every V O minutes
Comments:
-------
Plant
Date
(LuJ^o
/3 -'/'-<} -7
Location
Sample Type
flX/^W _^J
A/ 24?
Run Number
Operator
-&
ACrG?
Traverse
Point
Number
*r '-/
i -»
,5"
U
Sampling
Time
(min)
vPTO
3-&U
>V
ik/r
O / c;
3Z^;
330
:J «*.l>
.3 .Y2J
^kC>
1^
fd^ir-
Clock
Time
(24hr)
(/Cf>
II/L,
n&l*
! i &..
/nJ-L,
/n'Z
i.U)L>
I&H»
iT^L
ISM,
f^Rjf
i.'^t
-i3 0 a
Gas
Meter
Reading
((Vm),ft3)
/L~i_0l-
fo'/.L^
iiln
1 7v. 7;?
/ "vtf.i;
/^/.«/U
/flf-.-fr
/b^-7z_-
/O/. e'"^
/ '//37f
Velocity
Head
((delta Pe),
ln.H20)
. t»0
/:-6
.(^^
.fe.fc
. '
. J
, ^J-'j
—7-t?6)
Stack
Ts
CF)
^t'
Br
«'->
^
^
&?.3
•^^
43 ;>
q/
^?
t'i»
U&ttC-
Orifice F
Differ
(delta H.
Desired
l •
A/Al
( £«_
'ressure
ential
ln.H20)
Actual
.&
,.^r
. ,a-^>
••'T"
.,^7
,,>9
..->c
, ^'7
.-z.'?
7-4-
.J>
JO. &
Probe
Temp.
(*F)
r^«CT
-3TY-
-J)T3
?-jy
,9^-^
A7?
,ac/
•^S'C-
p>"d_
c^SV
^S7
7''^/v
k
v/
Filter
Temp.
CF)
-9vn-
/5t/6
:?f7
2V/6
f-=5rf2.*
&T~f
pt5S
.5V/
•#S"2
^5^
-.^.S'2-
Adsorbent
Trap
Temp.
L ('F)
^^
V-:T,
*f-.a>
v/
41
•J.J
DryGa
Inlet
(Tmln)
f^:-?
<^3
(^;3'
L-->
C^.3
.r^-j
/
<*'
>~u
'*Z>
ST-
5Z;
STj
<"-f
Impinger
Exit
Temp.
(•F)
<1
j s
C* s—
3 T
3 N-
3 •>-
? r
Comments:
-------
Facility: Gulp Alum. Alloy
Date: 12/8/97
Location: Furnace Inlet
Run Number: 1
Sample Type: M23
Total Sampling Time (min) 327.0
Corrected Barometric Pressure (in Hg) 29.33
Absolute Stack Pressure (in Hg) 29.20
Stack Static Pressure (in H2O) -1.70
Average Stack Temperature (°F) 101.76
Stack Area (sq in) 1134.11
Actual Meter Volume (cu ft) 135.625
Average Meter Pressure (in H2O) 0.50
Average Meter Temperature (°F) 53.92
Moisture Collected (g) 30.10
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9940
Nozzle Diameter (in) 0.156
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.416
Standard Metered Volume (dscf) 135.966
Standard Metered Volume (dscm) 3.851
Stack Moisture (%V) 1.03
Mole Fraction Dry Stack Gas 0.990
Dry Molecular Weight 28.88
Wet Molecular Weight 28.77
Stack Gas Velocity (fpm) 3404.80
Stack Gas Velocity (mpm) 1037.78
Volumetric Flow Rate (acfm) 26815.50
Volumetric Flow Rate (acmm) 759.41
Volumetric Flow Rate (dscfm) 24344.11
Volumetric Flow Rate (dscmm) 689.43
Percent Isokinetic 101.35
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eaitem Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run \ruriA. \*\ -<3|
Page 1 of 2~
Plant
jDate
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) Jin. H2O)
Barometric Pressure (in. H2O)
tu If At M
i->\x\ca
\ ic>f^u£~
Fu.t.-o \*\
^vH
i.Cv't'Wll*
.00k$>"
Meter Box Number
Meter delta H @^
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
i&AVI
1. 12-'
•.°*"
b
— •
^v
^
fc
0
Sampling
Time
"1[min)
t>
it
1-o
'i«.
vo
TO
\>0
10
^
^
\ DO
\\0
\T-0
\^o
\^0
iSt>
UpO
i->0
fio
Clock
TlWe
(24hr)
cf\^
ei.^7
i"o1
101-7
( on
i <->»^~)
1^141
IQV1
no 1
iM T
\M,1
\\^T
>>M1
U=»l
11^1
\7-\'l
ILL?
l^n
ii-M-7
'••:
»
Gas
Meter
Reading
((Vm).ft3)
^ij.0oi_
Itl'.Ttp
So. i 7,
SH.U'Z-
S1.1-
^Xi.vi
Si.o-
I^J-.t,!
i oi.fc^
U\,u«-^
\A\,..^-\
• tO.T^
1 I f. v^-
\^-S.T-
m i4^~
Velocity
Head
((delta Ps),
in.H2O)
1 ,V
.^U-
i ,\
/.7^
1 >\
1 4
I.I
1 .\
\.(
\.1—
\,2-
\,\
\.\
t,\
\. \
.£/^
(.0
,x*
Stack
Ts
(°F)
-t-o«o
<\^-
'MU
cl?
^*t5(f,
' i Z^
?^
|CXj
LHh
Orifice F
Differ
(delta H,
Desired
0 .V3
C'/Ht
'ressure
ential
inH2O)
Actual
• ^
.Mo
•^.3
.u-
.^v*r
. -i"^~
,S"V
••S7
. ;T5"
.\,"l~.
,.-i.f-
. ;J«i
.^"'1
.^
•^1
.^i
•^
.MT
L,''-^.00
Probe
Temp.
(•F)
i3ft
^-so
A^VI
X^H
JL^S
12^}
^2F
2>f
LT-^i
\^
'¥*\
b^CL-
6±\^
^HS"
iKM-^
>IT_
T-ST_
^>'-^
6S
Filter
Temp.
CF)
7H2-
a^^
^.-•^
VMJ-
.XH^
-i^U
:Xu~\
r*-Mu
.>ss-
^•\l.
i^
;IYJ
^3CP
x^fc.
•J3\
l^u
.XUI
.Am a
Adsorbent
Trap
Temp.
(°F)
-//
H/
HT—
sr^/J^
^T-
^2_
M7-
m_
4^
su
H^
Mi
^
Hs^
M^
H.\
M2_
SX
DryGa
Inlet
(Tmin)
Hi
S"!
S" j~
$<*
•Ci
iTT
b"S>
i"y
«•«?
WV
M
Impinger
Exit
Temp.
'(•F)
1
^
3L
'il
^
4i
^i
H|
42--
W3
<-V^|
S^j
MM
Mi-
Mu
VL
^L
^/.s—
v.^
Pump
Vacuum
(in.Hg)
3
i.
-5
S
M
i
J^
:-i
'j)
5~
•5j~-
G
u
1
(/,
I
k'
c/,
L
Comments:
-------
Plant
[Date
CjULUf
Location
Sample Type
Run Number
Operator
1
Traverse
Point
Number
Sampling
Time
(mm)
Clock
Time
(24hr)
Gas
Meter
Reading
«V"i).lt3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
_m_
Orifice Pressure
Differential
(delta H, in.H2O)
Desired
Actual
Probe
Temp.
CF)
Filter
Temp.
_CD_
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet Outlet
(Tm in) (Tm out)
Impinger
Exit
Temp.
CF)
Pump
Vacuum
Cn.Hg)
M180
10
12-0
-L\0
-ZSD
to
.11
la
JkHl
HO
.•m.
Vo
1,0
I "\Li.ra
XML.
W 1
I A
Ai
IV?.
So
1.0
7.S)
So
,19s
3
\u>
VA
Mi
(H
ISO
.<» u ^
t
*-*¥-
7"
Comments:
-------
Eostarn Raseorcn Gfcco. !nc
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number ; :
XAD Number
i .1 lp M 1 ,1 MX, (^tiixx v~t HC-.U
/a 2 ^
fcf.i. JAJU&T
r>s4-v^. ^
**±
/Ho^ ft.,U^ / r*^^\ (^,,r-K^
M^cL /Ac^
J /
Impinger
Number
Impinger
Solution
Amount of
Solution
(9)
Impinger Tip
Configuration
Impinger Wefght
Final
(g)
Initial
(9)
Weight
Gain
(g)
$00%
/
I CO
\-\2p
~y
i I, ca Gel
•IOC -360
hX
Total Weight Gain (g)
-------
Facility: Gulp Alum. Alloy
Date: 12/9/97
Location: Furnace Inlet
Run Number: 2
Sample Type: M23
Total Sampling Time (min) 342.0
Corrected Barometric Pressure (in Hg) 29.32
Absolute Stack Pressure (in Hg) 29.22
Stack Static Pressure (in H20) -1.40
Average Stack Temperature (°F) 114.14
Stack Area (sq in) 1134.11
Actual Meter Volume (cu ft) 134.327
Average Meter Pressure (in H2O) 0.91
Average Meter Temperature (°F) 59.53
Moisture Collected (g) 42.20
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9940
Nozzle Diameter (in) 0.155
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.384
Standard Metered Volume (dscf) 131.206
Standard Metered Volume (dscm) . 3.716
Stack Moisture (%V) .1.49
Mole Fraction Dry Stack Gas 0.985
Dry Molecular Weight 28.88
Wet Molecular Weight 28.72
Stack Gas Velocity (fpm) 3255.36
Stack Gas Velocity (mpm) 992.23
Volumetric Flow Rate (acfm) 25638.52
Volumetric Flow Rate (acmm) 726.08
Volumetric Flow Rate (dscfm) 22680.61
Volumetric Flow Rate (dscmm) 642.31
Percent Isokinetic 101.67
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATASHEET
Run P
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (t) (in. H2O)
Barometric Pressure (in. H2O)
/'L,^//Hlt/C1
ii-l ^ 11 -1
I)d-t44t^
fU^rt l^ict
^tStti'c-AF
1_
- m
-LVbO
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
^^
-we
O OltifJif
0.00010"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A ST(
1. T2-
•m
• ir^->
/
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
. Point
Number
Sampling
Time
(min)
JL
Clock
Time
(24hr)
Gas
Meter
Reading
<(Vm),ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
|0
7.20
/
It)
-2. Si
no
.5ft
bl
61
4V
i
10 >
HM
IP
Oo
Mi
no
•&-
^
fet
.'i -s
\\o
zr-?
l'1-O
MT
\MO
.?§
< V.
- "JO
X*
no
fT
•r\
11,1.
2.-JG
16"
ft t
i CM
-Z.ee,
•"
u?
13
A3
-V
3$
TTi
HO
SS
Comments:
Iff!
•r ' 7
-------
Plant
(Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
3H°
•ZS&ly
'itfO
•'
Clock
Time
(24hr)^
Hie
VTZ-'o
I'liCp
n«4u
nf^v
\so^-
i^/U-
isu
<,< Gas
^P Meter
Reading
((Vm).tt3)
^ol
z-os-,^
^ol •S')
A'^.T^
£zj-r^2'6.^
•7.Z' ,O
t ir,19)
\ z <* . az.^
Velocity
Head
((delta Ps).
in.H2O)
.v4-
.50
.SO
,80
,So
,8'i-
,^/D
.?0
Stack
Ts
&}
61-
^^
5?^
Kt:\
«?ri/
iS^3-
^/'/
2WY
.D'-
Firter
Temp.
(°F)
T-S"1?
1^5
7.S1
'iSb
z^rv
7JTZ-
Z.\7
-r.S"7_
Adsorbent
Trap
Temp.
(°F)
M^
M"\
^
S~\
^3
STS-
•r<^
5n
DryGa
Inlet
(Tm in)
ok
(oU .
on
«p"7
Lp~l
Ul
CP?
fc7
> Meter
Outlet
(Tm out)
S'6
S^
^6>
^
s;£
Z8
^x
±-£
Impinger
Exit
Temp.
CF)
H&
^M
5C>
S"^-
4T^
^i
A"<^
i-7
'
Pump
Vacuum
(in.Hg)e.
f.r"
<^
9
&
X
X
Comments:
-------
"?e*eorcn Gf
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number ;
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number ;
XAD Number
r,, V^ . ft^^.r^vNN R \UV
• - t T
R'Y'L /A/ LET
n.fU^. -Q/5
&$,
tf}nt~S f^,iie_ / (\f\\.r~\ (a,iLl-\
-------
Facility: Gulp Alum. Alloy
Date: 12/10/97
Location: Furnace Inlet
Run Number: 3
Sample Type: M23
Total Sampling Time (min) 333.0
Corrected Barometric Pressure (in Hg) 29.32
[Absolute Stack Pressure (in Hg) 29.22
Stack Static Pressure (in H2O) -1.40
[Average Stack Temperature (°F) 116.47
Stack Area (sq in) 1134.11
Actual Meter Volume (cu ft) 142.514
Average Meter Pressure (in H2O) 0.98
Average Meter Temperature (°F) 72.44
Moisture Collected (g) 32.30
Carbon Dioxide Concentration (%V) 0.5
Oxygen Concentration (%V) 20.0
Nitrogen Concentration (%V) 79.5
Dry Gas Meter Factor 0.9940
Nozzle Diameter (in) 0.156
Pitot Constant 0.84
Average Sampling Rate (dscfm) , 0.414
Standard Metered Volume (dscf) 137.833
Standard Metered Volume (dscm) 3.903
Stack Moisture (%V) 1.09
Mole Fraction Dry Stack Gas 0.989
Dry Molecular Weight 28.88
Wet Molecular Weight 28.76
Stack Gas Velocity (fpm) 3486.72
Stack Gas Velocity (mpm) 1062.75
Volumetric Flow Rate (acfm) 27460.70
Volumetric Flow Rate (acmm) 777.69
Volumetric Flow Rate (dscfm) 24293.10
Volumetric Flow Rate (dscmm) 687.98
Percent Isokinetic 101.10
Percent Excess Air 1992.23
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) ' Q.QQ
-------
Eaitcm Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant
Date
Operator
Sampling Location
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
CuAP
i-2i,om
^b^c^
VLLC*\ (A\
-
2>
-u<\
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°FJ^
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
T-W
^£H*s
OU.S
Q_.O 1 5
s-T
-iiiCiL
XL
4T
Comments:
-------
Plant
Date
Location
Sample Type
Run Number
Operator
Traverse
Point
Number
AM
H
*•(
4 £
^
f
A (,
(,
k>
"-,
, •,,
•.'-,
S,.-
Sampling
Time
(min)
zyo-
t^o
'}oc>
IIG
"^'Z.U
~yr>.->
'3>'5>3*
-." ..*=A.
•"^•^ '
Clock
Time
(24hr)
1
)U2o
1 (p'^Q
/tcH^5
Jto ^
rtcc
C7O-3»
Gas
Meter
Reading
((Vm),n3)
1 S" 1 . V T^
i Cr/iS"~
/ L>O. 7.%
l(pU, (,v
(U'liS-
l9o>J5~7v/
Velocity
Head
((delta Ps),
in.H2O)
I.I
/. /
/ o<>"
/ . C5
l-i'i
l.o <*'"
; nT
Stack
Ts
CF)
3 0
'7
i S"~1
,5—)
S^o^.f
'ressure
ential
in.H20)
Actual
.5
iy*6»'''
•^ >• .,
>
-;.
1 '
J
.--*• i
t
I
,.
j,
_» ; .
\
'
1
i
.,.
1'
1,
Probe
Temp.
CF)
Z.5TI
2_y 2_
zVs^
2^5"
'2. V /^
*7 ^/*(/
^.<>^-
Filter
Temp.
CF)
Z-t/s^
'2U/f^
2^*7
^"VS
"^-ji^f^j
a 4-\
Adsorbent
Trap
Temp.
CF)
5^-f
4:^~-
6-^ —
(fH
Impinger
Exit
Temp.
.C7
."V1?
6?ts
t^jj
.r<^
^\"^-
^r~ <,J
Pump
Vacuum
(in.Hg)
-------
Pesaorcn G'Ouo. :nc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f ; i-Ap,. rl 1 ,i MS.. f-iii.fVN H Ufty
/.i //»/«* 7-
£
-------
Facility:
Gulp Alum.
Mloy
Date:
12/11/97
Location:
Furnace Inlet
Run Number:
Sample Type: IM23
Total Sampling Time (min)
380.0
Corrected Barometric Pressure (in Hg)
29.99
Absolute Stack Pressure (in Hg)
29.87
Stack Static Pressure (in
-1.70
Average Stack Temperature (°F)
101.08
Stack Area (sq in)',
1134.11
Actual Meter Volume (cu ft)
133.655
Average Meter Pressure (in H2O)
0.83
Average Meter Temperature (°F)
55.03
Moisture Collected (g)
23.70
Carbon Dioxide Concentration!(%V)
0.5
Oxygen Concentration (%V)
20.0
Nitrogen Concentration (%V)
79.5
Dry Gas Meter Factor
0.9940
Nozzle Diameter (tn)
0.155
Pitot Constant
0.84
Average Sampling Rate (dscfm)
0.360
Standard Metered Volume (dscf)
136.643
Standard Metered Volume (dscm)
3.870
Stack Moisture (%V)
0.81
Mole Fraction Dry Stack Gas
0.992
Dry Molecular Weight
28.88
Wet Molecular Weight
28.79
Stack Gas Velocity (fpm)
2902.14
Stack Gas Velocity (mpm)
884.57
Volumetric Flow Rate (acfm)
22856.65
Volumetric Flow Rate (acmm)
647.30
Volumetric Flow Rate (dscfm)
21296.01
Volumetric Flow Rate (dscmm)
603.10
Percent Isokinetic
Percent Excess Air
101.49
1992.23
0.00
Concentration (g/dscm)
Concentration (kg/hr)
0.00
Concentration (pprnv)
0.00
Emissions (Ib/hr)
0.00
-------
Eailern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant C.o-l/'
Date
Operator
Sampling Location f~u /
Sample Type
Run Number
Static Pressure (i) (in. H2O)
Barometric Pressure (in. H2O)
A-VX.*, 1^1^
\* ~ 11-1 ">
iV/f/*O
n/vcf (1 IfJ
MT_ -^
4
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
&^T~b
4' C7lA
3 fl)
fsrt,
O.O1'*?'0
.bdfc) "&'
t
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
fef-Factor
A _^S
' •'?2'
..<^;4
I5X"
•^,^
.. H
•' Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every t ' minutes
Traverse
Point
Number
Sampling
Time
(min)
o
Clock
Time
(24hr)
CU3-O
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
CF)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet Outlet
(Tmin),
(Tm out)
Impinger
Exit
Temp.
(T)
Pump
Vacuum
(in.Hg)
/S/A
O
.90
HLHO
PTC,
tfc'-V
4?)
40
S3
S
1.0
-ft
t I
14-U
4^
^F
MH
(I'D O~7
a.
*
-wa
fee
2.
\\j\j
in"7
°
I 10.
otio
Li-i^
k
•41-
1 OO
LsC
Jv^O.
i '3
3i
-^^
IUD
• U.-
3 3
.
m
1 3 1 .
5"3
C3
~nz
Tro
_^3s3^o
CRSV
-^r
-------
Plant.
Date
4
^ T 7fc"
5VM7
Location
Sample Type
un Number
Operator
Page
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),tt3)
Velocity
Head
((delta Ps).
in.H20)
Stack
Ts
(T)
Orifice Pressure
Differential
(delta H, ln.H2O)
Desired Actual
Probe
Temp.
(•F)
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
/6>
(p.l
vTg
//'
. i
5'
C,/
S-3
n +G
, /
3 ->
43,
_12_
,/
"3 .-
L>(o
S'/
i>4-
33:
-stf%-
**
v
-------
Eastern Raieorcn G'Ot-p. Inc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
« * | • ......
Run Number : ;; < >
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f :, \r\ • r\\.t r^iC*, Q.MN R H ft \/
/ajjairf
R
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/08/97
Furnace out
1
m26
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant .
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr) ___
321.5
29.32
29.29
-0.30
89.35
1809.56
264.338
0.73
60.55
91.50
0.0
21.0
79.0
0.9810
0.256
0.84
0.807
259.294
7.343
1.64
0.984
28.84
28.66
2535.47
772.81
31861.67
902.32
29491.94
835.21
96.14
-16380.66
0.00
0.00
0.00
0.00
-------
iaitem Rewirch Group, Inc.
OU i
MODipiED METHOD s DATASHEET
yV-
Run
Page 1 of
Plant
Date • S.
Operator!
BampjjngiLocation FOtiJWHL
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O) *\<\!
CUe^ W_ 3 .
XAD Trap Number ;
Filter Heater Setting (*F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
—
•xco
6,'tyCtf
xca
<>D
.OtfQlO"
vftftii*
Met^Box Number^
Meter delta H @ • •
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (*F)
Assumed Moisture (% H2O)
K-Factor
A-38
\ &«C,
o.lfrl
o.-LSC
30 *
f).
H-\U
v ^ ,. . Diagram of Duct
Traverse
Point
Number
Sampling
Time
(min)
O
Clock
Time
(24hr)
Gas
Meter
Reading
Velocity
Head
tfdelta Ps),
in.H2O)
Stack
Ts
Orifice Pressure
Differential &'
(delta H in.H,2O)
Desired
Actual
Temp.
Filter
^Temp.
Adsorbent
Trap
Temp.
('F) .
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tmout)
Impinger
Exit
Temp.
(T)
r*'
Pump
Vacuum
(in.Hg)
B-r*-
2-0
30
5-0
ti-
K
1 °O
3-D
•J-o
6.0
lo *d
ViV
il
30
L.O
ro
t o
7-0
Jo
100
il
Vo
S-o
bo
MvM
3.00
X 00
SO
II '.i
10
foV
v o
53
*-
i 20
2-O
Mo
VO
! ( : -i
1-2-0
\ V:
214
II- *K
'ISO
V 0
•IH1S
12
7ry*
"rh
ji
^^^
JLP_
Y o
a. -
fc.
So
- rz-
Co
• o
/O
Comments:
-------
Plant
Date
Mr*
flc
Location
Sample Type
ttcu -
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
(Vm).ft3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
Orifice Pressure
Differential
(delta H, in H20)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
13: i*..
Mi. 3k
- V
I 0-L.
Z OH
1 -QC-/
I.c-f
U6O
XO
0
_a
T-iV
TI-
ST.
S3fa.
,57,
2,$*
53
LL
10
it,
. /
, s /
SI
1 1
iSS
13
S
'1- ( 2.
2-.il.
Ti,
50
3-8
,4V
•240
fft7^5
l.Vi
51
3-2,
J^k.
^!L
7-tO
t
3.0
ifeO
3 2-
345
I '.
Comments:
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
2
m26
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H20)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
vlole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
3ercent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
341.5
29.29
29.26
-0.30
99.91
1809.56
254.658
0.67
70.20
130.80
0.0
21.0
79.0
0.9880
0.256
0.84
0.780
266.319
7.542
2.26
0.977
28.84
28.59
2346.44
715.20
29486.27
835.05
26580.24
752.75
103.15
-16380.66
0.00
0.00
0.00
0.00
-------
i •' f:... Eaitem Research Group. Inc.
MODIFIED METHOD 5 DATASHEET
Run
Page 1 of
'•V, .
[plant ' C-Uwt>
Date
Operator v
Sampling Location FoftWfVic. ft
Sample Type
Run Number
Static Pressure (t) (in. H2O)
Barometric Pressure (in. H2O)
At— f\L--
i2-/q/f>
touif/TS
fOlhM-T
?rri/d
'o'tytoM
I£Q
C,o
.ol#9"
• HI&I0"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A "3V
i;s<3
o,9fe&
O.ZS&
Yo°
I?..
•:
TV
., Schematic of Traverse Point Layout
Read and record all data every /• ^ minutes
Traverse
Point
Number
Sampling'
Time:
(min)';-
Clock
Time
(24hr)
Gas.
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
. Ts
Orifice Pressure
i- Differential
: (delta H. in. H20)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
.'(T)
Dry Gas Meter
(Inlet"; Outlet
(Tminj 7 (Tmout)
Impinger
Exit
Temp.'
Pump
Vacuum
(ln.Hg)
"VS
l OS"
1.30
fi
Ht
T2...C
/• 2-
ITS'
1&
•xl
ISM
M1-
^
30
rt '
3.1
0,1
7- 1
52.
7.S7-
fL
T.HS-
: oo
ST-
Vo
107.
61.
Ill
2..03
Vl.5-
1 0(o
TH3
fT
qo
/3.30
II.C
S"
13: 3
Mt
lo°
S.o
1. ft
•5,
M
5?
r-o
IIT.5
C&
CO
.MM
4Jib-
62
r.o
l.fcl
27, S
feT.
|0
ISO
^?^
TW^
TTlr
I.STl
. STl
m
u
it
34
63
ITL.-S"
S
joH.
I. V*
i?y_
M. a
Comments:
-------
Comments:
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
3
m26
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
331.5
29.20
29.17
-0.30
108.18
1809.56
261.702
1.84
77.58
88.60
0.0
21.0
79.0
0.9880
0.256
0.84
0.751
248.892
7.049
1.65
0.983
28.84
28.66
2280.82
695.19
28661.64
811.70
25541.80
723.34
103.34
-16380.66
0.00
0.00
0.00
0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant .',.- .J^T C+J\.
Date Q^i^fe*
Operator T
Sampling Location F 0 (LtU .
Sample Type
Run Number
Static Pressure (±J (in. H2O)
Barometric Pressure (in. H2O)
£> fiu At-
(iiiQ/q^
Aviiif 35.
'SvTcJr
V«v\Ucx-
i
-n.^'-xUo
23,2.1
XAD Trap Number
Filter Heater Setting (T)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
•' — . •
zso
&'*Ntef
7£0
(e~b
•oUUib"
,oo$&0"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-33-
\&\3
fl.
-------
Plant
Date
Location
Sample Type
OUT
HcJL VWruCOlKiaOperator
Run Number
1
M.A.A.H
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
IVO, -
^013 .20?
fi-l-L
-H£L
1 V3-
XHo
M :
%
11
10
16";
-
%
3k, IS
J0_
15". 15
IS
^
15
5- t
l£ 3D
/ o f-,
/ 6
.I
\9r
, I
L(o \
to
In
1U2
41
0.50
{I, '.30
ft.
±a
1 SD
5fT
5*5-
•S 15"
^
-51
ft,; 55"
1, \
1.5-1
l.HV
<5toO
0 • O 0 :
/o
Comments:
-------
Facility: Gulp Alum. Alloy
Date: 12/09/97
Location: Furnace out
Run Number: 4
Sample Type: rn26
Total Sampling Time (min) 381.5
Corrected Barometric Pressure (in Hg) 29.32
Absolute Stack Pressure (in Hg) 29.29
Stack Static Pressure (in H20) -0.30
Average Stack Temperature (°F) 93.69
Stack Area (sq in) 1809.56
Actual Meter Volume (cu ft) 268.961
Average Meter Pressure (in H2O) 1.56
Average Meter Temperature (°F) 63.24
Moisture Collected (g) 76.60
Carbon Dioxide Concentration (%V) 0.0
Oxygen Concentration (%V) 21.0
Nitrogen Concentration (%V) 79.0
Dry Gas Meter Factor 0.9880
Nozzle Diameter (in) 0.256
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.691
Standard Metered Volume (dscf) 263.800
Standard Metered Volume (dscm) 7.471
Stack Moisture (%V) 1.35
Mole Fraction Dry Stack Gas 0.986
Dry Molecular Weight 28.84
Wet Molecular Weight 28.69
Stack Gas Velocity (fpm) 2055.67
Stack Gas Velocity (mpm) 626.57
Volumetric Flow Rate (acfm) 25832.33
Volumetric Flow Rate (acmm) 731.57
Volumetric Flow Rate (dscfm) 23792.76
Volumetric Flow Rate (dscmm) 673.81
Percent Isokinetic 102.17
Percent Excess Air -16380.66
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Retcanch Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant £0u?>
Date
Operator
Sampling Location f o? (vAc<
Samgle Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O) ^3
AL \AL-
l^hita*
VW*A| /Ti
rti/TC^T"
Met-
4
-0-?t>
"xq . ^
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
*r
ICQ
b'tyfc*
zj-6
(pO
'OutllV'
xOtf€V'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-3*
( SI3
.Mi
O.^l>
Hf
/•?»
HMZ
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every 1 • ~> minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).tt3
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
CF)
Filter
Temp.
(T)
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
.33
-Z-50
ST
144 •/
HO
. JT
,-40
UT,
•
11
30
,i-\t
1(3
ta
.1*3 C>
Q.7D
SVsT
^ 1
•-1
tfl.lf
110 .U
111 .
-------
Comments:
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/08/97
Furnace out
1
M23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
321.5
29.32
29.29
-0.30
88.14
1809.56
257.992
0.70
60.03
48.50
0.0
21.0
79.0
0.9880
0.256
0.84
0.793
254.874
7.218
0.89
0.991'
28.84
28.74
2424.85
739.10
30471.60
862.96
28482.29
806.62
97.85
-16380.66
0.00
0.00
0.00
0.00
-------
MODIFIED METHOD 5 DATASHEET* -
Meter Box Number.
Meter delt
PGM Factor (Y)
Minimum Sample Volume (ft3)
Run •"
Page"'! of
Amfciem Temperature (*F), "'' '-^
Assumed Moisture. (%.H2(3)
• . • •'!•'»•• a?-''^y* A ' • '
fiatjc of Ttgverse PolntiJaydut* .' i^,'tt * ^ '" • •''. '.•. . .' *.
ntf record all datVeVerv •' nilnutes ' i ''.;'.'•*'".••' : \ *' .:
•;V9^ _ - . • •*• - .. '
«/.)-y I • . *• :- • . •
•* ' t ^^^ JUBnaarn *f Plimt
Diagram •( Duct \
.i.*?, .
2.5 «•!
Rlter,,,M
$c
•233-
.Adsorbent
a-.: Trap
Dry Gas Meter. H
• ' •
Inlet ' ^ Outlef
*(Tm o'utf •
' ••*.
knpinger.
.Exit-'
Temp. ..
pump
\tecu'urtt
. (in-Hg)'
>',o "
:>
fa 5'
•±
3Qu>.'L .
^Vf,>l
Loo
.10
,H*
7TOD
,4^.
^
^i-
"200
\\.
1
-------
Plant
Date
oo i
Location
Sample Type
Run Number
Operator
;T
Pagefpbf
Traversa
Point
: Number
Sampling
Tjme
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).tt3)
Velocity
Head
((delta Ps),
in.H20)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
Fitter
Temp.
Adsorbent
Trap
Temp.
CF)
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp!
Pump
Vacuum
(in.Hg)
i I- 12.5
i
\.c-j
4J-
1
O
ST.
S3
.5"
110
JL
£00 r
"IX b
2S3
S/
cn • «
"2. TO
T.SL
43
-7 7.0
nl
yv
-70
vr
ZM3.
sr
S3
•2.S3
£3
-it
1ST-
2X2-
SO
i vr
Si
50
is. zo
1Q
"5
-73
S3
. 5*0
.S'
ID
ll
OO (
Comments:
-------
Etatetn .Pweorcn G'Ouo. .'nc.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number : :
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
i ; . lp M 1; i wv.f^ivrrx H U f~>\J
rij&fii
£•£'!- 'OUTLET
ru*ko^. -Q3
^ 1
m«^ ^...vlc. / /V*-^A ^..i-V
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
2
m23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H20)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter.Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
341.5
29.29
29.26
-0.30
99.80
1809.56
243.113
0.65
70.61
72.20
0.0
21.0
79.0
0.9810
0.256
0.84
0.727
248.281
7.031
1.35
0.986
28.84
28.69
2272.85
692.76
28561.48
808.86
25991.57
736.08
98.34
-16380.66
0.00
0.00
0.00
0.00
-------
Eaitem Rnearch Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant £.l/j-.^
Date'
Operator
Sampling Location "Fuft-AJ • fSH
Sample Type
Run Number
Static Pressure (*) (in. H2O)
Barometric Pressure (in. H2O)
Ac - r\<-
li/*»H>
rv\u) H fS^
Ov/TkAlT
35«o>,lfJ
2.
-0.3">/tO
a<\,3o
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
—
2£0
(o'Wfr*
2SO
fco
,Ot£/2"
.c£>&0 Hv
Meter Box Number
Meter delta H @
DGM FactorJY)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
/1-3K
I-&I&
o.q&i
,a£G
ft>°
/,6 ?o
*H3
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data tvery I' 5> minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
ll-oVS'
Gas
Meter
Reading
'((Vm).n3)
Velocity
Head
((delta Ps).
in.H2O)
Stack
Ts
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
CF)
lit,
Adsorbent
Trap
Temp.
.(•F)
Dry Gas Meter
Inlet
(Tm In)
To
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
K
6-0 T
I7-O
VL
30
C
32,
4,0
C.4V.I
.40
Ho
to
. o
.3C,
ItS.
(OH
, 2C,
•7S-
a-,
loo
37 C
101.
0-3S
ess
t-o
So
60
So
fro
10
1. <\0
I qo
.o
•2-Mi
56
•0
H'.oo
- V
. MS
I
0
110
z.
-4 "i
fal
C.O
(,1
.MC
i.O
10
.q o
80
\o
(So
riv
U
(IT-
00
•&
It.
Comments:
-------
Plant
Date
Location
Sample Type
oirr
Run Number
Operator
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm).tt3)
Velocity
Head
((delta Pa),
in.H20)
St
tack'
Ts*
CF)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
6-1
\
IS
1.7. 9
_U_
u
TM-S
•2.2-1
2.0, S
» o
\ s
u:
£L
iJlb (
u-o
- 2,
.40
•2-S7-
C.-0
921-C
( 5s t,
iMO
HZ-
1-S.S
Vt U .
.HI
.- 1
.£(
2-X C
&
±
Ml
ll
•
2S1
.47-
.vc
i.QS
fr
-I
Mi
SO
0
2.0
^3o
2
s
£
O
/o
330
8-1
./•O
If
Sb
,0
llr
-5tm
Comments:
-------
Ecjfem Qevoorcn Group. Inc.
MOISTURE RECOVERY FORM,FOR METHOD 4
Plant
Date
Sampling Location
Sample Type •^/'-•- -^-:.
Run Number ;
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
r :..Vp . ftV.^.r^rw RlUu
MLya/9*
£^L ' 0in L?7
r)^oA. ,03
**a
n0^ ^.H& / (Vv^A ^,.r-K^
(\^v>/ A-ut£;
1 • ••-
i
Impinger
Number
1
2
3
4
5
6
7
Impinger
Solution
tf\?Tf
. tfilC
V^v.0
I4PLC
Wjp
EMP ry
$ 1 1 >ca Ge.1
Amount of
Solution
(9)
/
i CC rr»\$
1 ^OMs
--
•ZOC-3tO^.
t
Impinger Tip
Configuration
Kr\ccKcui,
CsKsrt njT)
Meclifiecl
A\J^ieA.
r^oii^ecL
McdL^i'ecL
ImpingerWefght
Final
(9)
5-30,^
5*55
s^:\e
454.5"
SS^tP
Initial
(g)
5MD
5(LZ.*}
S5S4
45^?
?(/T.O
Total Weight Gain (g)
Weight
Gain
(g)
IDul
— .-;• 't
f
f ' '"' - fo2y
- 5
_ § J
^
• -*.—
7^-^>
-------
Facility:
Date:
Location:
Run Number:
Sample Type:
Gulp Alum. Alloy
12/09/97
Furnace out
3
m23
Total Sampling Time (min)
Corrected Barometric Pressure (in Hg)
Absolute Stack Pressure (in Hg)
Stack Static Pressure (in H2O)
Average Stack Temperature (°F)
Stack Area (sq in)
Actual Meter Volume (cu ft)
Average Meter Pressure (in H2O)
Average Meter Temperature (°F)
Moisture Collected (g)
Carbon Dioxide Concentration (%V)
Oxygen Concentration (%V)
Nitrogen Concentration (%V)
Dry Gas Meter Factor
Nozzle Diameter (in)
Pitot Constant
Average Sampling Rate (dscfm)
Standard Metered Volume (dscf)
Standard Metered Volume (dscm)
Stack Moisture (%V)
Mole Fraction Dry Stack Gas
Dry Molecular Weight
Wet Molecular Weight
Stack Gas Velocity (fpm)
Stack Gas Velocity (mpm)
Volumetric Flow Rate (acfm)
Volumetric Flow Rate (acmm)
Volumetric Flow Rate (dscfm)
Volumetric Flow Rate (dscmm)
Percent Isokinetic
Percent Excess Air
Concentration (g/dscm)
Concentration (kg/hr)
Concentration (ppmv)
Emissions (Ib/hr)
331.5
29.20
29.17
-0.30
107.27
1809.56
258.286
1.95
74.50
53.50
0.0
21.0
79.0
0.9810
0.256
0.84
0.740
245.451
6.951
1.02
0.990
28.84
28.73
2340.11
713.27
29406.74
832.80
26416.98
748.13
98.54
-16380.66
0.00
0.00
0.00
0.00
-------
Eastern Research Croup. Inc.
MODIFIED METHOD 5 DATASHEET
Run
Page 1 of
Plant C-OuP
Date
Operator
Sampling Location £\MLtJp>Ct,
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Al_ A<~-
/2Jlb/&S>S"
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature (°F)
Assumed Moisture (% H2O)
K-Factor
A-38
AiL
0.1AI
0,7.Sjb
.SO*
l*o
^,43
Diagram of Duel
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
Point
Number
Sampling
Time
(min)
O
Clock
Time
(24hr)
II.'IS
Gas
Meter
Reading
«Vm).ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
(•F)
Filter
Temp.
(•F)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet Outlet
(Tm In)
(Tm out)
Impinger
Exit
Temp.
(•F)
Pump
Vacuum
(in.Hg)
G- 1
LS
_1±
JL
I
IS
(C.30
2.57,
2^(0
30
31
VO
. '
2-4 b
• sq
no
V2.
i
255
2,5
4%
-------
Plant
Date
Location
Sample Type
fiJ
Run Number
Operator
3
WUJI//TS
•••••-••:*•«-.
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
/Reading
((Vm,ft3)
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
(•F)
Orifice Pressure
Differential
(delta H, in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
(•F)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Outlet
(Tm out)
Impinger
E»t|
Temp.
mp
Vacuum
(in.Hg)
IOVD
%JCL.<
i.qn
_LM.
it
10-5^-3
Mr I.
SO
<*<<
M-0
Q-to
VM
_LR.
<.te
224
_&s_
^V
^so.
IS:
•
y o
-
O-O-l
/0
s /
s -o
2-oSf
\oSO-i
23?
0
SI
: 00
1.8-1-
Sd
M -o
2.S2.
JUL
U
"Z-12.
7.4 <
^
8-
22-*
. Si
C.C,
n
.5-
-O
Z-M ?
/
w.r
10
\ \ "^ fo .0
Oil
(0
Vl
OO'
to
V
Comments:
-------
. 'r.c.
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
/':. lp . ft\,._rv^ R1UV
tf ^p** /^ U "^~ ^"-£»**T^
n^ ^^ y$
4^5
(q0^ P^;.l4^ / r >y^,\ (i,,,r-K^
Impinger
Number
Impinger
Solution
Amount of
Solution
(9)
Impinger Tip
Configuration
•Impinger Wefght
Final
fg)
Initial
(3)
Weight
Gain
(a)
rt Hp)
HvtC
I CC
•ZCG -3(1
Total Weight Gain (g)
-------
Facility: Gulp Alum. Alloy
Date: 12/09/97
Location: Furnace out
Run Number: 4
Sample Type: m23
Total Sampling Time (min) 381.0
Corrected Barometric Pressure (in Hg) 29.32
Absolute Stack Pressure (in Hg) 29.29
Stack Static Pressure (in H2O) -0.30
Average Stack Temperature (°F) 93.47
Stack Area (sq in) 1809.56
Actual Meter Volume (cu ft) 274.335
Average Meter Pressure (in H2O) 1.79
Average Meter Temperature (°F) 61.97
Moisture Collected (g) 43.40
Carbon Dioxide Concentration (%V) 0.0
Oxygen Concentration (%V) 21.0
Nitrogen Concentration (%V) 79.0
Dry Gas Meter Factor 0.9810
Nozzle Diameter (in) 0.256
Pitot Constant 0.84
Average Sampling Rate (dscfm) 0.703
Standard Metered Volume (dscf) 267.746
Standard Metered Volume (dscm) 7.583
Stack Moisture (%V) , 0.76
Mole Fraction Dry Stack Gas 0.992
Dry Molecular Weight 28.84
Wet Molecular Weight 28.76
Stack Gas Velocity (fpm) 2188.59
Stack Gas Velocity (mpm) 667.08
Volumetric Flow Rate (acfm) 27502.66
Volumetric Flow Rate (acmm) 778.88
Volumetric Flow Rate (dscfm) 25493.20
Volumetric Flow Rate (dscmm) 721.97
Percent Isokinetic 96.91
Percent Excess Air -16380.66
Concentration (g/dscm) 0.00
Concentration (kg/hr) 0.00
Concentration (ppmv) 0.00
Emissions (Ib/hr) 0.00
-------
Eastern Research Group. Inc.
MODIFIED METHOD 5 DATA SHEET
Run
Page 1 of
Plant . COU
Date
Operator
Sampling Location f 0 ci(J
Sample Type
Run Number
Static Pressure (±) (in. H2O)
Barometric Pressure (in. H2O)
Wu )*«_
n-|i%l«i>
WsjOi^ ( SS
OlfiU-f~
"*> v o-* ) fJ
cl
- O-^L)
•i-q.si
XAD Trap Number
Filter Heater Setting (°F)
Probe Length & Type
Probe Heater Setting (°F)
Minimum Sample Volume (ft3)
Initial Leak Check
Final Leak Check
__
2,50
k'HiU.-*-
•LSO
fcT)
'0\Ato"
• oo$£t o'
Meter Box Number
Meter delta H @
DGM Factor (Y)
Nozzle Type & ID (in.)
Ambient Temperature ("F)
Assumed Moisture (% H2O)
K-Factor
fl-3&
KfcfG
,&
^0
H.H3
Diagram of Duct
Schematic of Traverse Point Layout
Read and record all data every minutes
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3)
Velocity
Head
((delta Ps).
in.H2O)
Stack
Ts
CF)
Orifice Pressure
Differential
(delta H. in.H2O)
Desired Actual
Probe
Temp.
Filter
Temp.
Adsorbent
Trap
Temp,
(T)
Dry Gas Meter
Inlet
(Tm In)
Outlet
(Tm out)
Impinger
Exit
Temp.
(CF)
Pump
Vacuum
(in.Hg)
2.
. "2,0
S 1
- 20
• sr
IMC
rtlr
.XO
"2-M L
1C
/.td
2-3C
_ds.
2,3 *
It.
2.0
HO
SC
0
&•*.<;
MC
rv
lol
1ST-
v <;
"TO
~^T
JOS
OS
."Vs-
1. '5
<;
MM
2-Ofc
c)
T.S
£5
8- >S
:Jr
"ZOO
fr
to
i.lo
2-2
$-.
voH
s.-o
.4,
.
107-
2.-CS
,1.
-4V
10
-1.43
*'',r>-.
Comments:
-------
Plant
Date
CUV-F ft/A
IM1I ««-
Location 'FOJLK
Sample Type
OVTUJT
4*1 t> >C iW
Run Number
Operator
*.
fAtft]
>»
Paae^Bf *~
Traverse
Point
Number
Sampling
Time
(min)
Clock
Time
(24hr)
Gas
Meter
Reading
((Vm),ft3
Velocity
Head
((delta Ps),
in.H2O)
Stack
Ts
Orifice Pressure
Differential- ''*
(delta H, in.H2O).••'
Desired
Actual
Probe
Temp.
(•F)
Filter
Temp.
CF)
Adsorbent
Trap
Temp.
Dry Gas Meter
Inlet
(Tm in)
Oudet
(Tm out)
Impinger
Exit
Temp.
Pump
Vacuum
(in.Hg)
_LiO_
A-l
1-02-
1.
W
/of
XIO
4£
V
•
I 0 I
27.
.IS
1.15
2,.0
"W-.i
JLLL
JU.
UL
2.H1-
6- -
2-3
? o
3
1-2*1
ZSO
1.33
1.33
"LST.
MM
. o
v^q.T
i S
13
Zfcl
MH
MU
0
Of
TO
as
H'.HLT
.3
2. IS
^
56
,53.
so
to
***!
(0
330
is.
o,
H
3^!
•2.-S
Hi
£
woo.c
. ^ t,
i a.*.
^5
MM
vrs
I
M--T
143
';-• .1:.-
Comments:
-------
MOISTURE RECOVERY FORM FOR METHOD 4
Plant
Date
Sampling Location
Sample Type
Run Number
Impinger Box Number
Recovery Person
Recovery Rinses
Sample Identification
Filter Number
XAD Number
f •. . 1 A - M 1 ,1 Mv.rvirrs R \(f^\j
/^|/n/9^
Ak> / (^/>v^,\ (i,ur-ki-.
Impinger
Number
Impinger
Solution
Amount of
Solution
(9)
Impinger Tip
Configuration
Imjainger Weight
Final
"(9)
Initial
(g)
Weight
Gain
(g)
1 CO
Total Weight Gain (g)
43.
-------
Appendix B
Dioxin/Furan
Laboratory Analysis Data
cah/A:\APPX-CVR.WP6
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzoforans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ED:
P.O. Number:
TLI Project Number:
January 12, 1998
Eastern Research Group
44376A
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 11/19/97
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491 -j
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Triangle Laboratories, Inc. January 12, 1998
Case Narrative 44376A
Overview
The samples and associated QC samples were extracted and analyzed according to
procedures described in Method 23 (6/93). Any particular difficulties encountered during
the sample handling by Triangle Laboratories will be discussed in the QC Remarks section
below. This report contains results only from the Method 23 dioxin/furan analyses of ten
M23 samples.
i • . •
Quality Control Samples
A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples. A TLI Cleanup Blank was also processed along with the samples to prove that
contamination was not introduced during the cleanup procedures.
Quality Control Remarks
This release of this particular set of Eastern Research Group analytical data by Triangle
Laboratories was authorized by the Quality Control Chemist who has reviewed each
sample data package following a series of inspections/reviews. When applicable, general
deviations from acceptable QC requirements are identified below and comments are made
on the effect of these deviations upon the validity and reliability of the results. Specific QC
issues associated with this particular project are:
Sample receipt: Twenty-five M23 samples were received from Eastern Research Group
in good condition on December 17, 1997 at ambient temperature and stored in a
refrigerator at 4 °C. Samples CAA-206 and CAA-207 were not included in the shipment.
\ • _.
Sample Preparation Laboratory: None y j,\< *" ~
Mass Spectrometry: None
Data Review: Due to the limitations of the software, the "CAA" portion of the sample
identification numbers was not listed on the reports.
The ion abundance ratios for the 1234678-HpCDF internal standards and 1234789-
HpCDF surrogate standards in samples 177/182-184/209 and 193-196 were outside QC
limits, most likely due to matrix-related interferents in these samples. The percent
recovery of the 1234678-HpCDF internal standard is significantly lower than the
recoveries of the other internal standards. However, the percent recoveries for all internal
standards are sufficient to quantitate the associated analyte concentrations in the samples.
-------
Triangle Laboratories, Inc. January 12, 1998
Case Narrative 44376A
Other Comments: No 2,3,7,8-substituted target analytes were detected in the TLI Blank
or TLI Cleanup Blank above the target detection limit (TDL).
The analytical data presented in this report are consistent with the guidelines of EPA
Method 23 (6/93). Any exceptions have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Eastern Research
Group have any questions or comments regarding this data package, please feel free to
contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Released By,
Kenneth Varley
Report Preparation Chemist
The total number of pages in the data package is: \[j ' .
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TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accreditation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management. Expires December 31, 1998.
Laboratory I.D. #40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1998.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate #AZ0423.
Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18, 1998.
Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX, Volatiles, Semi-
v'olatiles, and Metals.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water. .
State of Connecticut, Department of Health Services. Expires September 30, 1999.
Registration # PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1998. Certificate #NC 140. Dioxin
in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998. Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS# E87411.
Revised 1/6/98 RM Triangle Laboratories, Inc.
y:certific\certlist.mem soi Capitoia Drive P.O. BOX 13435
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491 A
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Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Idaho Department of Health and Welfare. Expires December 31, 1998. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment Expires January 31, 1998.
Environmental Analyses/Non portable Water and Solid and Hazardous Waste. Method 1613 for
drinking water. ID #s - Drinking water and/or pollution control - E-215. Solid or Hazardous Waste -
E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31, 1998. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires June 3, 19S8. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1998.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
1998. ID #67851. BNAs and Vclatiles. Dioxin in drinking water.
State of New Mexico, Environment Department. Recertification pending. Dioxin in drinking
water.
New York State Department of Health. Expires April 1, 1998. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources Expires
August 31, 1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 2000. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1998. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 1/6/98 RM
y:certific\certlist.mem
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Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory #9612.
Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires
April 1, 1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, SNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid and
Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires
February 5, 1999. ID #02992. Method 1613 Drinking water only.
•
•
U.S. Department of Agriculture Soil Permit Expires September 30, 2001. Permit No. S-3790.
Under the authority of the Federal Plant Pest Act, permission is granted to receive foreign soil
samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Recertification Pending. Validated to perform methods
8280 & 82SO for Lockbourne Landfill Site Investigation, Defense Distribution Depot Projects, and
assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 199S. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 12, 1998. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1998. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method 1613;
Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for Polychlorinated Dibenzo-p-
dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Labl.D, 129
State of West Virginia, Department of Health. Expires December 31, 1998. Certificate No.
9923(C). Dioxin in drinking water.
Revised 1/6/98 RM
y:certific\certlist.mem
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State of Wisconsin, Department of Natural Resources. Expires August 31, 1998. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID 999869530.
Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1998. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1998. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500 1053481.
Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services. Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 1/6/98 RM
y:certific\certlist.mem
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DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-348i>~
919-544-5729 Fax # 919-544-5491
8
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Gulp Aluminum Alloys
Eastern Research Group COC
CHAIN OF CUSTODY ' / /I
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SAMPLE
CAA-1 05
CAA-1 06
CAA-1 07
CAA-1 08
CAA-1 09
CAA-1 10
CAA-1 1 1
CAA-1 12
CAA-1 13
CAA-1 14
CAA-1 15
CAA-1 16
CAA-1 17
CAA-1 18
CAA-1 19
'cAA-120
CAA-1 21
CAA-1 22
CAA-1 23
CAA-1 24
X
CAA-125
CAA-1 26
CAA-1 27
CAA-1 28
CAA-1 29
CAA-1 30
CAA-1 31
S
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-------
Eastern Research Group COC
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CAA-132
CAA-133
CAA-134
CAA-135
CAA-136
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CAA-138
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CAA-140
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CAA-142
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CAA-154
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CAA-156
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CAA-158
CAA-159
CAA-160
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CAA-162
CAA-163
CAA-164
CAA-165
CAA-166
CAA-167
CAA-168
CAA-177
CAA-178
CAA-179
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
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CAA-
CAA-
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CAA-
CAA-
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CAA-
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CAA-
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CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
120997 M23-
120997 M23-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
121197 M23-
121197 M23-
120797 M23-
121597 M23-
121597 M23-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
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RBLK1
RBLK2
RBLK2
XAD 1
FILTER 2
PR 2
PRT/CRT 2
XAO 2
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PR 3
PRT/CRT 3
XAD 3
FILTER 4
PR 4
PRT/CRT 4
XAD 4
FILTER 1
PR 1
PRT/CRT 1
XAD 1
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PR 2
PRT/CRT 2
XAO 2
FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 4
PR 2
PRT/CRT 4
XAD 4
FILTER 1
PR 2
PRT/CRT 2
METHOD 23. RF1-OUT, RUN 1
METHOD 23. RF1-OUT. RUN 2
METHOD 23. RF1-OUT. RUN 2
METHOD 23, RF1-OUT, RUN 2
METHOD 23. RF1-OUT, RUN 2
METHOD 23, RF1-CO T. RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF2-OUT. RUN 4
METHOD 23. RF2-OUT. RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN, RUN 1
METHOD 23. RF1-IN. RUN 2
M 23. RF1-IN. RUN 2 (Bottle 1 of 2)
METHOD 23, RF1-IN. RUN 2 t^"
METHOD 23. RF1-IN. RUN 2 \
METHOD 23, RF1-IN, RUNS
METHOD 23, RF1-IN, RUN 3
METHOD 23. RF1-IN, RUN 3
METHOD 23. RF1-IN. RUN 3
METHOD 23, RF2-IN. RUN 4 /
(M23, RF 1 -IN. RUN 2(Bottle 2 of fjY
METHOD 23. RF2-IN. RUN 4
METHOD 23. RF2-IN. RUN 4
METHOD 23. REAGENT BLANK
METHOD 23, REAGENT BLANK
METHOD 23. REAGENT BLANK
XAD TRAP
FILTER
ACETONBMECL RINSE
TOLUENE RINSE
XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XAD TRAP
FILTER
ACETONE/MECL RINSE(1o(2)
TOLUENE RINSE
XAD TRAP
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ACETONE/MECL RINSE
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DIOXIN / FURAN
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DIOXIN/FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN/FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
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Page 2
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METHOD 23, REAGENT BLANK
METHOD 23, REAGENT BLANK
METHOD 23. REAGENT BLANK
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GLASSWARE BLK CDBOUTLET
GLASSWARE BLK CDBOUTLET
GLASSWARE BLK CDBOUTLET
GLASSWARE BLK RFOUTLET
GLASSWARE BLK RFINLET
GLASSWARE BLK CDBINLET
GLASSWARE BLK CDBINLET
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M23 FIELD BLANK CDBOUTLET
M23 FIELD BLANK CDBOUTLET
M23 FIELD BLANK CDBOUTLET
M23 FIELD BLANK CDBOUTLET
M23 FIELD BLANK CDBINLET
M23 FIELD BLANK RF1 INLET ••
M23 FIELD BLANK RF1 INLET
M23 FIELD BLANK CDBINLET
M23 FIELD BLANK RFOUTLET
M23 FIELD BLANK RFOUTLET
M23 FIELD BLANK RFOUTLET
M23 FIELD BLANK RFOUTLET
M23 FIELD BLANK RFINLET
M23 FIELD BLANK RFINLET
M23 FIELD BLANK RFINLET
M23 FIELD BLANK RFINLET
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DIOXIN / FURAN
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DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
-------
Eastern Research Group COG
CAA-218 CAA- 120597 M23- CDBIN PR 1 M23 CDBIN RUN 1 (PR 2 OF 2) ACETONE/MECL RINSE DIOXIN / FURAN
CAA-219 CAA- 120697 M23- CDBIN FILTER 2 M23 CDBIN RUN 2 (FILTER 2 OF 2) FILTER DIOXIN / FURAN
CAA-225 CAA- 121197M23- RF1 IN PR 4 Melhod23 RF1 INLET RUN 4 ACETONE/MECL RINSE DIOXIN / FURAN
CAA-226 CAA- 121597 M23- REAGENT BL MeCL 2 M23 REAGENT BLANK 2 (MeCL) REAGENT BLANK (MeCL) DIOXIN / FURAN
Page 4
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-TRIANGI.fi LABORATORIES. INC. -- UX3 IN RECORD/CHAIN OF CUSTODY=
Custody Seal :
Chain of Custody :
Sample Tags :
Snmple Tag Numbers:
SMO Forms :
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NO COOLANT
TLI Project Number 44376
Client: ELS01 - Eastern Laboratory Services, Inc.
Date Received
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II
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=Form Revised 05/27/1997 -- Page 1 OF 6=
-------
=TRIANGl,E LABORATORIES. INC. -- LOO IN RECORD/CHAIN OF CUSTODY=
|| Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container. . . : Intact
Sample Tags : Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A
Ice Chest NO COOLANT
TLI Number Client Sample ID Matrix) To LAB
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-------
(I Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container. . . : Intact
|| Sample Tags : Absent
|| SMO Forms : N/A
|| Ice Chest NO COOLANT
TLI Project Number 44376 | Book ||
Client i ELS 01 - Eastern Laboratory Services, Inc. \ fl
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NO COOLANT. CAA-206 AND CAA207 ARE NOT PRESENT.
Archive Remarks:
=Form Revised 05/27/1997 -- Page 3 OF 6=
-------
CO
=TRIANGLE LABORATORIES, INC. -- LOO IN RECORD/CHAIN OF CUSTODY=
H Custody Seal i Absent Sample Seals: Absent
H Chain of Custody : Present Container...: Intact
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Client: ELS01 - Eastern Laboratory Services, Inc. | |
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Date Received | 12/17/97 | By/^O*^?^ S\ Pa9e II
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Client: ELS01 - Eastern Laboratory Services, Inc.
Date Received
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| Book 0
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Receiving Remarks: NO COOLANT. CAA-206 AND CAA207 ARE NOT PRESENT.
U Archive Remarks:
=Form Revised 05/27/1997 -- Page 5 OF 6=
-------
oo
Custody Seal : Absent Sample Seals: Absent
Chain of Custody : Present Container...! Intact
Sample Tags : Absent
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Date Received | 12/17/97 | By /^JJ^^^ZsSo X P*9e "
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I Receiving Remarks: NO COOLANT. CAA-206 AND CAA207 ARE NOT PRESENT.
I Archive Remarks:
=Form Revised 05/27/1997 -- Page 6 OF 6=
-------
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
- ADMINISTRATIVE INFORMATION
TLI Proj#: 44376-A Samples: 10 TurnAround.: 21 Day(s)
Prod Code: D23061 Matrix.: M23Train Hold Time..: 30 Day(s)
DetectLim: .05 ng Type...: A Start Date.: 12/17/97
Recvd..: 12/17/97 Ship By....: 01/05/98
DWL Due Dt.: 12/24/97
Analyte List.: Method 23:T-0 (Toluene combined
Method. : Method 23 :Tetra-Octa (Tol Combined)
Client Proj..: Gulp Aluminum Alloys
Client : Eastern Research Group (ERG02)
P.O. No : Signed OA Collect Dt/Tm: SeeCOC
Contact. .....: Jim McGaughey Phone : 919/461-1209
Proj . Mgr. . . . : Amy J. Boehm Fax : 919/461-1579
Sample Origin: NC
•SPECIAL INSTRUCTIONS / QA REQUIREMENTS
Prespike Standard: USD-C, USD-S
Prespike Amount..: 4.Ong
REPORTING REQUIREMENTS •
Reporting Format: Report Option II
See MILES for Instructions/Communications.
Completed by: DATE:
Reviewed by: /U& DATE: iW.?J-W- (PMGT0197)
.p-.
-------
PROJECTCOMMUNICAT10N TRACKING FORM
page 'of'
'tU Project Number:
LIM
Use this'form' to record ail exchanges of information between production units as we!! as-personnel
•handling this project. Decisions, corrective actions and recommendations must also appear on this
tracking document . .
Date -
Name [ Comment / Decision / Resolution / Action / Observation
TriangTelaborataries, Inc
-TLI PROJECT* 0404-7 ~
DATE t1725/97 TLI BLANK
SPIK£-4.Qng USF-C USF-S
PREPAR
EASTERN RES.GRP.
-------
Date: 12/29/97
Time: 16:13
Sample
It crd TLI_Number.. Customer .Sample. Id
020 TLI LCS TLI LCS
021 TLI LCSD TLI LCSD
000 TLI Blank TLI M23 Blank
001 194-59-10A-D 141-144
002 194-59-11A-D 153-156
003 194-59-12A-E 157-160/166
004 194-59-13A-E 161-164
005 194-59-14ACD 165,167,168/225
006 194-59-15A 177/182-184/209
007 194-59-15B-D 178-181/226
008 194-S9-17A-D 193-196
009 194-59-19A-D 201-204
010 194-59-18A/B 198/199/305/208
TRIANGLF. LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Project: 44376-A
F.
No
0
0
0
1
1
1
1
1
1
1
1
1
1
XAD
Color
LOT P-1078
LOT P-1078
WHITE
WHITE
WHT./YELLO
WHT/YELLOW
WHT/YELLOW
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
Filter
Color
NA
NA
NA
GRAY
BLACK
BLACK
BLACK
BLACK
WHITE
WHITE
WHITE
WHITE
WHITE
Glass Wool
Color
NA
NA
NA
WHITE
WHT./YELLO
WHT/YELLOW
WHT/YELLOW
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
PUF
Color
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Odor
NA
NA
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
Air
.. Q.No.
NA
NA
04047
04047
04047
04047
04047
04047
04047
04047
04047
04047
04047
Entered By
HILLKT
HILLKT
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIGHAM
WHIOHAM
Date
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
PRDPERC V4.01
Page : 2
. . . Time S
13:45 F
13:45
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16:13
16 1 13
F
F
F
F
F
F
F
F
F
F
F
F
•• End of Report *•*
-------
I Project: 44376A
•TRIANGLE LABORATORIES, INC. PAGE 1 OF 2
Dioxin Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERGO21
-^ 1
Method: Method 23 :Tetra-Octa (Tol Combined) Matrix: ft\.?5 ((U\ |
Extraction Date:
| Solvent (3)/Acid (s) : \Clu£VlZ /
| Lot Numbers:
I is ipixe: »u u± cone: u.iuuu ng/M-L
1 SS Spike: ul cone: . nq/wl
| MS Spike: 0 ul cone: 0.0000 ng/ul
| LCS Spike: 0 ul cone: 0.0000 ng/ul
| OPR Spike: 20 ul cone: 0.01 ng/ul .
| | TLI / . I GROSS |. SI
|S#.crd| SAMPLE / CLIENT | WEIGHT | £
1 | ID / SAMPLE ID | Before After | 9
|A | TLI Blank | , , | A|
|000 | TLI M23 Blank | .' J ^\ \ (^ ^ \
|A | 194-S9-10A-D | '1 1
|001 | 141-144 | j\||V | ^$r 1
|A | 194-59-11A-D 1 . , 1 A 1
|002 | 153-156 | J|f.j^' 1 Mp !
|A 1 194-59-12A-E | , I A |
|003 | 157-160/166 | |\| <\ \ ft • ) |
|A | 194-59-13A-S | . | . I A, |
|004 | 161-164 | f\J f\ I 'V 1
|005 | 165,167,163/225 | ^ ' ) | P fT 1
. -. _,. 4£&)J?\^\T* » » +
|A | 194-59-1SA /It ^ -"Pi 2.1 1 i\|A 1 fit /V- 1
|006 | 177/182-184/209 | '»H | ( \( {] |
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|A | 194-59-15B-0/ /UA/if I -A 1 A/A 1
|007 | ' 178-181/226 1 I V U 1 /I/M I
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|A | 194-59-17A-D | » | r A |
IOOB i 193-196 1 W li i r* r\ i
|A | 194-59-19A-D ' \{ t\ ' i\f fV '
|009 | 201-204 | jlj }\ 1 1 \P 1
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Initials: Dace: / / -^^-
| Initials of both SPIKER AND OBSERVER must be entered.
XXXXX * Gross Weight not provided for WATER Samples. |
REV 05/27/97 (PSTMF 7)--.
9
-------
Project: 44376A
TRIANGLE LABORATORIES, INC. PAGE 2 OF 2
Dioxin Sample Preparation Tracking 4 Management Form.
Client: Eastern Research Group (E3G02I
-/- ""-/,
solvent (s)/Acid (s) : \fllW\lV /
| Lot Numbers:
Method: Method 23 :Tetra-Octa (Tol Combined) Matrix:/l(T5llft;Aj '
Extraction Date:
| IS Spike: 40 M! cone: o.iooo ng/yi » • —y
1 SS Spike: Ml cone: . ng/Ml 1 L-K 1 J ^)
\ MS SpiVe: 0 |*1 con^- 0.0000 nq/Ml | J*f& ' ~_,.__ 1 L)O l3/l
| ^rs Spilc«. 0 fil cone; 0.0000 ng/Ml 1 klE- ^ ' l.ii)^"r\
\ OPR Spike: _20 M! cone: _0.01_ ng/Ml I i? / £/ / J? 1 JJ 1 fa. /~L
... .., ,. .., \Z / 71 fV> \ leil 3&£)'
* » — - * * ir ' ^_i. 'A3 1 iSy *£!*JJ-
| | TLI / 1 GROSS | SAMPLE | |S : 30 | ^/ : Y^1
|S*.crd| SAMPLE / CLIENT | WEIGHT | SIZE | D . 1 ng/Ml I _fl • / ng/M]
| | TD / SAMPLE ID | Before After 1 g / ml | M[) M! 1 {J-LJ MJ
|A | 194-59-18A/B 1 20 40 \ ./> 1 A / /I 1 . 1 -<\>J I ^*Z~~
|010 | 198/199/205/208 | (\J tt I 'V/| | ' | ' I"*T/
j^iiL^/ia . . ,-- * « -, .J^f.h:
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II 1 1 1 1 1
1 1 1 I 1 1
1 1 1 1 1 1
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II 1 1 1 1 1
II 1 1 1 1 1
II ll-ll 1
11 1 1 1 1 . 1
, I 1 1 1 • i
II I I I 1 1
II 1 1 1 1 1
II 1 1 1 1 1
II I I 1 1 1
I Gross weight of sample container + sample before/after aliquot removal.
1 Comments: •D^'fcxW U/7M f»"o , Ld fl&'*=>e
1 1 •
I LvtJlPfi" ft~ '^rZT'&fi t^CL^-th-Z- "ff 3-— QjCuA v a^uzf \*)a^> $*
I /. J ' ' 1 ^J
..« „ ,. |
I I I Chemist |
I I ISpike * \
.1 1 1 " ID 1
%\ — 1 — /_ 1 _ / _ /_ 1 " Expirj
'fiH* : | : | " Time |
L | ng/Ml I ng/Ml | " Cone. |
.1 M! 1 ul | " Vol. i
| I |Any Left!
1 1 1 yes/no ;
1 1 . |Any Lefrj
• 1 1 1 yes/no i
0&&J?
I . I |Any Left]
| . | | yes/no i
| | (Any Left!
1 1 ' 1 yes/no i
| | |Any Left]
| 1 • 1 yes/no !
1 1 |Any Left]
1 1 1 yes/no |
1 1 |Any Left]
| | | yes/no |
| | |Any Left|
1 . 1 1 yes/no |.
| | • |Any Leftj
1 1 1 yes/no |
| | |Any Left|
1 1 1 yes/no |
1
f
1
U 9 \
i
Initials:
Date:
Initials of both SPIKER AND OBSERVER must be entered.
XXXXX - Gross Weight not provided for WATER Samples.
REV 05/27/97 (PSTMF 7)-
-------
PAGE 1 OF 2
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM |
TLI Project No.: 44376 A
Ext SO.crd and | I. | | n \ . \ \ \ \ ^ | 1' £&l /Ofi >-
TLI Number | ' | ^~ \ 'n \ & \ ^> \ ]j) \ 7 \ Q C\ J | .p?/ol Qi
TLIBlan* | £ ||l /f^jCTL \^~' ' WL \ WL l' WC l^3^> ^ ' • !/?/,,l ,_ >
A 001 | J ^"l |
194-59-10A-D 1 * ,' „• 1 1
. A 002 I .-_v; 3\ 1
194-59-11A-D 1 ~i 1 1
+ -, * +
A 003 |" .| C£ | |
194-59-12A-E I ^ -* 1 1
A 004 | \ | |
194-59-13A-E | >J | |
.... i-^"> *-- .--J.----L
+. •* + + -t-
A 005 | ? | | 1
194-59-14ACD | ~ | |
A 006 • . |. -^ | |
194-59-15A | V~ | | 1
1
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+ _-^ + + .J..... + ...
A 008 |^| | |
194-S9-17A-D | ^ | | 1 |
A 009 | I | | L
194-59-19A-D | ^Un^ , ^ | \]3\*£
Enter the procedure number below into the
Initial and date each sample for each numb
0 . . . . PROCEDURE SOP # "V . DETAILS
' 1?\ EXTRACTION | ) 1 » Time On
v^ .-• ^*~ -^^
^oxhlep
(^) SPIKE AFTER EXT'N
( . 3?) ADD TRIDECANE ^ Lot#T^>
(I) ROTOVAP ^T^PiaM V- % 40mL f
S) COMBINE ^
§DIV./LIP. DETERM. 'JSP /// ^-S 20%/80%
v \ v
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box at t
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1 1
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•"-+""r"*"1 +
/ i i i
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[T f 1 **\ * Ir
he top of each column to signify the ctep performed.
:edure performed.
Time Off *3 : IS" *»*-
/ Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
s ""*
<5^%/50> 5mL/20mL Other
SOLVENT EXCHANGE Iso-Octane Lot# ^ "77/£'/ _Hfintane Lot#
f CLEANUP CSSP 263±
TRANSFER 2^-X ^- *"
ADDITIONAL CLEANUP god . DSP
11) FINAL TRANSFER
, / DSP 225 /^DSP Iis9/ DSP 215 / DSP
26p /
DSP 225 / DSP 115 / DSP 215 /
267 / Other
DSP 267 / DSP260(10g)
Cements: 7/L'/ f tf m> .L{jt "7^ Q'7bD5(j U AJLH -fa Lt ! rV\jL i&U n//'Vl3iirKj
L^ - CWLlLl^ /.l/?/J fO •? f O - f
; 1 u ~
11/25/97 (PSTMF 4)»=
24
-------
PAGE 2 OF 2
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 44376 A
Ext S#.crd and
TLI Number |
I
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
# PROCEDURE.... SOP.#. .v.. DETAILS (circle)
/!)/EXTRACTION l\ I *& Time On to Jj Time Off % : I * «*•*-
^—^ -— s— — — —
QSoxhlet, / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Haste Dilution
SPIKE AFTER EXT'N
ADD TRIDECANE . Lot# TRI' I - 3 ~H»
V ROTOVAP
5) COMBINE
IV./LIP. DETERM. &%P 1)1
'1\ SOLVENT EXCHANGE Iso-Octane Lot* ^Tl '(,-{ Heptane Lot#_
8> CLEANUP ^
9? TRANSFER $.•$-' !L
10) ADDITIONAL CLEANUP Mod. DSP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 / DSP260(10g)
FINAL TRANSFER
SmL/20mL
Other
20%/80%
Iso-Octane Lot*
JSP"T60N / DSP 225 I DSP 115 / DSP 21S / DSP 267 / Other
„%
.Rev 11/25/97 (PSTMF
25
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 44376-A
Transfer From: DWLH5 To: DMS5
Initials. . Date Time
Released by: '-^ J_/^L_/J^ \0 ••
Accepted by:
MILES . ID
44376-A
44376-A
44376-A
44376-A
44376-A
44376-A
44376-A
44376-A .
44376-A
44376-A
44376-A
44376-A
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
. TLI No
TLI Blank
194-59-10A-D
194-59-11A-D
194-59-12A-E
194-59-13A-E
194-59-14ACD
194-59-15A
194-59-15B-D
194-59-17A-D
194-59-19A-D
194-59-18A/B
.TLI Clean-Up
Cust .Id
TLI M23 Blank
141-144
153-156
157-160/166
161-164
165,167,168/225
177/182-184/209
178-181/226
193-196
201-204
198/199/205/208
Cleanup Blk
xf-r-roc: (RRV 11/01/94)--+
Additional comments or instructions:
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Method: Method 23 :Tetra-Octa (Tol Combined) HR GC/HRMS ANALYSIS
Required Detection Limit : . 05 ng
1
| PROJECT: 44376A |
SAMPLE INFORMATION RS Cone |
1ST COLOMN 2ND COLOMN 20 fil « 100.0 K/pi 1
| TLI / I GC/MS FILENAME) CONFIJ
S».crd| SAMPLE ID / CLIENT | COLUMN: Qftj |
| / SAMPLE ID | I
A | TLI Blank I 1 f
000 | TLI M23 Blank | - ¥00^£>' \
A | 194-59-10A-D 1 1 |
ooi | 141-144 | f C£yv37Ii ' I
A | 194-59-11A-D I . ' \/
002 ' 1S3-156 I j0.a,/y^ -? CC^,\ | V
»| 165,167,168/225 | |
| 194-59-15A ICtft^^-^S- 1 /
006 | 177/182-184/209 | | ^j
A | 194-59-15B-D (Lift <-.°^ J^ |
007 | 178-181/226 | | \l
A | 194-S9-17A-D | \J&^) OS^>\ \ .
008 | 193-196 | | V
A | 194-59-19A-D | 1
009 | 201-204 \\jjtylty^>3 \ V
|
A | 194-59-18A/B | I
010 | 198/199/205/208 | |/^^£/0^6 | \/
\}\ I
iM | CONFIRM FILENAME |USF-
1 COLUMN: 'pfl'^tf' IVOLD1
I ISOLN
RS |nSF-RS | ANALYSIS |
ME |INIT. (COMMENTS }
ID (DATE | j
| V^^ JW**^ I \fJ ^&+. j j
1 1 .
1 1
1 1
1 ^ 1
1 1
1 1
1 1
1 1
1 \ 0 • 1 •
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1 1
1 t
1 1
1 I
1 t.
1 1'
i *& //^/9 8"" i
i i
Comments:
Type: A
Spike File: SPX23704
Amc of Extract: 50*
REV 03/07/95 (PSTMF
-------
Triangle Labc
Rum
i, Inc.
C«J
Instrument ID Column Type Column ID
Plot Name Ini. Vol. Acquisition QIC
&«^ Aw^ ,M,
' Slgnaturft ' 'Date
Filename
Dele*
Time*
Projedff
Sample/?
^7-7-7-)
No.
Client Sample ID
//»•/•/ //
i 4-
Syr
332
•S4-
P.
Operator/Dale
>M
*
66
Commenls*
/>
flt
fxc
10
KC (|i
(0
26
:n±
TV-t >v\r-^,
A
Transcribed from chromatographlc data
* Dated Initials required
irvtl/qa/fotmt/hmmlofldoc (02/D5/97)
ConCal Due:
ConCal Due:
Page:
-------
Triangle Labc Mes, Inc.
Run L
O)
CvJ
Instrument ID Column Type Column ID Plot Name
Inl. Vol. Acquisition
j&fc/L^ fc*W-^
' /Signature «
QIC
/6/fSJ
'Dale
Filename
Dale*
Time4
Project*
Sampleff
17-fl-i.
No.
5
Client Sample ID
8yr
332
3-3
lu.
Opeialor/Dale
Comments*
7
#51/6/»
/•*»
£1
o
Transcribed from chromatographlo data
Dated hillials required
tivil/qa/roims/tmunloodoo (02/05/97)
ConCal Due:
ConCalDue:
Pa
-------
Triangle LaHRtories, Inc.
Run Log
Instrument ID Column Type Column ID
Plot Name
Inl. Vol.
Acquisition
Signature
G/C
' Date
Filename
Dale*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Dale
Comments*
3A_
f
Zlcfc
>|$0
O
la
lut-
it'
y A-
ny-
10 >
fiC
Transcribed from chromalographic data
** Dated initials required
sm1/qa/rorms/hrnjnlog.doc (02/05/97)
ConCal Due:
ConCal Due:
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID : Column Tvpe Column ID Plot Name
v£o ^ £)t O-VT VS'sf^'V^*'" TT'f
Ini. Vol. Acquisition
• ^ ^ v>_
Signature
M
1-
G/C
*-l^
Date
Filename
Date*
Time*
Project #
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
L'i
K-C
0
S/S 1 (1
V-r
4-9-U
I .of.
1.1
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2.
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il
1 1
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1^,
M
fkiL
Ml
i'
2.C
Transcribed from diromatographic data
" Dated initials required
sr/r1/qa/(orms/htmnlog.doc (02/05/97)
ConCal Due:
ConCal Due:
Pa
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Capftola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491
1 O
o U
-------
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HXCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
U980026
TLI M23 Blan
ng
12/29/97
01/06/98
U
XAD
Soxhlet
(0.004)
(0.006)
(0.01)
(0.008)
(0/008)
(0.01)
0.03 J
0.02
(0.005)
(0.005)
(0.006)
(0.005)
(0.006)
(0.007)
(0.008)
(0.01)
(0-01)
(0.004)
(0.006)
(0.008)
(0.01)
0.04
(0.005)
(0.006)
(0.008)
PRJ
J
J
J
TRIANGLE LABORATORIES, INC.
Sample Result Sunmary for Project 44376A
Method MIT2 Analysis (DB-5)
0980028
153-156
ng
12/29/97
01/06/98
O
M23TRAIN
Soxhlet
0.68 PR
4.0
4.5
7.3
10.3
43.1 E
69.6
65.2 E
.15.6
29.4
101 E
34.9
53.2
3.1
163
24.8
144
72.0
65.7
93.7
86.7 E
364 E
398 E
413 E
270 E
PRJ
O980027
141-144
ng
12/29/97
01/06/98
0
M23TRAIN
Soxhlet
0.02
0.03
0.02
0.04
{0.04} J
0.15
0.24 B
1.5
0.15
0.22
0.44
0.15
-0.20
0.02
0.62
0.08
0.46
2.8
0.47
0.37
0.31
12.8
3.7
1.8
0.98
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 85.7 84.8
Other Standards Percent Recovery Summary (% Rec).
13C12-PeCDF 234 99.5 89.0
13C12-HXCDF 478 84.0 98.1
13C12-HXCDD 478 89.8 90.8
13C12-HpCDF 789 84.3 84.9
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 789 52.6 73.2
13C12-HXCDF 234 60.7 73.1
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 46.0 64.4
13C12-2378-TCDD 51.1 64.1
Page 1
01/10/98
0980029
157-160/166
A "" _ .-. v
ng
12/29/97
01/06/98
O
M23TRAIN
Soxhlet
87.9
90.7
109
93.8
97.7
65.0
63.5
61.0
53.3
E
PR
E
E
E
0.71
5.0
5.4
8.1
11.9
55.4
87.1
76.6
15.7
31.9
98.8
35.5
53.9
3.1
200
34.5
>40.0
143
103
154
114
441
419
417
346
80.6
91.2
99.2
96.7
97.9
72.1
75.0
62.7
63.2
PR
E
E
E
E
PRX
E
SE
QE
E
E
E
E
E
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:21 01/10/98
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method MIT2 Analysis (DB-5)
Data File
Sample 10
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
U980026
TLI M23 Blank
ng
12/29/97
01/06/98
U
XAD
Soxhlet
U980027
141-144
ng
12/29/97
01/06/98
D
M23TRAIN
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 123 45.2 69.9
13C12-PeCDD 123 50.6 66.9
55.3 70.
13C12-HXCDF 678
13C12-HXCDD 678 59.4
13C12-HpCDF 678 49.9
13C12-HpCDD 678 56.5
13C12-OCDD 48.8
80
73
75
.9
.0
.3
.4
66.1
O980028
153-156
ng
12/29/97
01/06/98
U
M23TRAIN
Soxhlet
59.1
50.0
58.4
74.3
69.6
68.7
61.3
Page 2
01/10/98
U980029
157-160/166
ng
12/29/97
01/06/98
U
M23TRAIN
Soxhlet
66.4
63.0
67.6
77.1
77.2
74.0
78.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:21 01/10/98
24
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method MIT2 Analysis (DB-5)
iData File
(Sample ID
Onits
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378 -PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
123467 8 -HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HXCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
fcOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
0980030 1^-^^0980031
161-164 / 165\ 167, 168/225
*''-';
ng
12/29/97
01/06/98
O
M23TRAIN
Soxhlet
0.61 PR
3.4
3.7
5.7
8.3
32.9
47.1
53.8 E
13.8
23.8
72.8 E
25.9
38.5
2.5 PR
107 E
17.1
79.7
68.1 E
55.0
92.0 E
68.8
288 E
324 E
300 E
180 E
k" - •*"/
ng ' /
12/29/97
01/06/98
O
M23TRAIN
Soxhlet
0.51 PR
3.6
4.7
7.4
10.3
40.0 E
63.1
64.6 E
15.8
28.7
97.5 E
32.5
47.4 E
2.8 PR
155 E
25.6
160 E
76.5 E
58.1
114 E
80.3 E
370 E
391 E
403 E
262 E
Page 3
01/10/98
0980032 O980033
177/182-184/209 178-181/226
^(t. ^f"- Df \ /
"ji <•"- ng
,vJ. 12/29/97
' 01/06/98
O
M23TRAIN
Soxhlet
(0.004)
(0.006)
(0.007)
(0.006)
(0.006)
0.02 J
0.06 JB
{0.03} B
0.01 J
0.01 J
0.03 J
0.01 J
0.02 J
(0.006)
0.13
(0.01)
0.11 J
0.01
0.01
0.02
0.02
0.05
0.07
0.11
0.13
£f.1 ff'i -rv '
ng "" .:•<••
12/29/97
01/06/98
O
M23TRAIN
Soxhlet
(0.005)
(0.008)
(0.01)
0.01 J
{0.01} J
0.04 J
0 . 14 JB
0.07 B
{0.02} J
0.03 J
0.08 J
0.03 J
0.04 J
(0.009)
0.14
(0.01)
0.10 J
0.04
0.01
0.03
0.08
0.30
0.36
0.28
0.18
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 79.4 82.9 82.4
Other Standards Percent Recovery Summary (% Rec)
13C12-P6CDF 234 85.6 85.5 93.9
13C12-HXCDF 478 99.9 104 92.5
13C12-HXCDD 478 84.6 97.1 90.3
13C12-HpCDF 789 100 93.7 95.1
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 789 53.0 80.7 77.7
13C12-HXCDF 234 54.7 79.9 78.0
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 46.2 75.3 62.5
13C12-2378-TCDD 44.7 68.4 68.1
RO
83.1
98.4
92.4
97.0
85.2
63.
68.
60.5
63.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:21 01/10/98
35
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method MIT2 Analysis (DB-5)
Page 4
01/10/98
Data Pile
Sample ID
0980030
161-164
0980031
165,167,168/225
Onits
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
=taS=SS3333S = = S3:3 = SS
ng
12/29/97
01/06/98
0
M23TRAIN
Soxhlet
ng
12/29/97
01/06/98
0
M23TRAIN
Soxhlet
B3=3S= = ==rS=SS5:=3»3IS53
0980032
177/182-184/209
ng
12/29/97
01/06/98
U
M23TRAIN
Soxhlet
0980033
178-181/226
ng
12/29/97
01/06/98
0
M23TRAIN
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-PeCDP 123 46.1 74.6
13C12-PeCDD 123 44.1
13C12-HXCDF 678 50.6
13C12-HXCDD 678 66.3
13C12-HpCDF 678 61.4
13C12-HpCDD 678 64.3
13C12-OCDD 61.7
71.4
77.0
80.8
85.0
88.5
80.0
72.1
79.7
73.9
,—22.1 :_,.
', _39.7 RO
8774 -"
86.9
59.5
67.7
64.3
75.3
63.2
76 .3
75.6
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:21 01/10/98
o ^
3o
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method MIT2 Analysis (DB-5)
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HXCDF
123789-HXCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total MCDD
Total DCDD
Total TriCDD
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
Total MCDF
Total DCDF
Total TriCDF
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
O980034
193-196/
ftX~- //
ng
12/29/97
01/06/98
D
M2 3 TRAIN
Soxhlet
{0.006}PRJ
0.04 J
0.02 J
0.04 J
0.05 J
0.12
0.25 B
0.45 B
0.14
0.22
0.31
0.12
0.14
0.02 J
1.2
0.17
0.41
0.31
0.52
0.53
0.23
2.2
2.9
1.4
1.9
O980036
198/199/205/208
^ / --
ng ir-r
12/29/97
01/07/98
U
M23TRAIN
Soxhlet
0.07 PR
0.48
0.26
0.46
0.57
1.2
0.65
7.6
1.7
2.9
6.0
2.3
2.4
0 . 15 PR
6.1
0.72
1.5
13.2
11.0
9.2
2.8
41.5
44.2
25.8
10.3
U980035
201-204
. .fVKi-'O '
ng
12/29/97
01/07/98
U
M23TRAIN
Soxhlet
(0.004)
0.02 J
(0.01)
0.02 J
0.03 J
{0.09} J
0.16 JB
0.29 B
0.07 J
0.12
0.23
0.09 J
0.12
(0.007)
0.43
{0.05} J
0.31
0.22
0.24
0.33
{0.18}
1.5
1.6
0.96
0.65
Page 5
01/10/98
D980037
Cleanup Blk
ng
01/05/98
01/07/98
U
SOLVENT
Soxhlet
— ,-f.JT -| _J — f— ^•••y-»T^.!..»»j.(...g^-i_Ji-— -—
(0.002)
(0.004)
(0.005)
(0.004)
(0.004)
(0.005)
0.01 J
(0.002)
(0.002)
(0.002)
(0.004)
(0.003)
(0.004)
(0.004)
(0.004)
(0.004)
(0.005)
(0.0)
(0.0)
(0.0)
(0.002)
(0.004)
(0.005)
(0.005)
(0.0)
(0.0)
(0.0)
(0.002)
(0.002)
(0.003)
(0.004)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 85.2 79.1
Other Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 234 93.6 86.9
13C12-HXCDF 478 92.8 79.7
13C12-HXCDD 478 98.0 78.9
13C12-HpCDF 789 107 RO 88.3
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 789 79.0 84.6
82.8
92.0
82.6
86.8
93.8
81.4
80.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:21 01/10/98
07
o i
-------
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Method MIT2 Analysis (DB-5)
U980034 U980036
193-196 198/199/205/208
ng ng
12/29/97 12/29/97
01/06/98 01/07/98
U D
M23TRAIN M23TRAIN
Soxhlet Soxhlet
44376A
U980035
201-204
ng
12/29/97
01/07/98
U
M23TRAIN
Soxhlet
Page 6
01/10/98
U980037
Cleanup Blk
ng
01/05/98
01/07/98
D
SOLVENT
Soxhlet
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 234
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
13C12-HXCDF 678
13C12-HXCDD 678
13C12-HpCDF 678
13C12-HpCDD 678
13C12-OCDD
77.2 85.6
Percent Recovery Summary (% Rec)
60.0 82.3
79.6 81.4
78.7 86.0
86.0 66.4
72.7 90.4
85.3 98.6
40.6 RO 80.7
95.1 80.9
92.1 73.2
82.8
73.1
75.1
76.4
68.3
85.4
89.4
79.9
86.7
81.3
=s:s=3sss = s:s:s== = s:
84.4
66.8
68.8
76.3
59.6
68.7
78.9
81.0
87.2
84.3
{Estimated Maximum Possible Concentration), (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1251 01/10/98
38
-------
TRIANGLE
Sample Result
LABORATORIES, INC.
Summary for Project
44376A
Page i
01/09/98
Method 23X (DB-225)
Data Pile
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
P980094
TLI M23 Blank
ng
12/29/97
01/06/98
P
XAD
Soxhlet
0.02
P980095
141-144
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet
0.27 B
P980096
153-156
ng
12/29/97
01/07/98
P
M2 3 TRAIN
Soxhlet
11.6
P980097
157-160/166
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet
16.1
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 63.6 78.9
65.5
71.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:2301/09/98
29
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
P980098
161-164
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet
10.5
Method 23X (DB-225)
P980099
165,167,168/225
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet
13.4
P980100
177/182-184/209
ng
12/29/97
01/07/98
P
M2 3 TRAIN
Soxhlet
0.02 B
Page 2
01/09/98
P980101
178-181/226
ng
12/29/97
01/07/98
P
M2 3 TRAIN
Soxhlet
0.03 B
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 48.9 79.8
72.0
76 . 5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:2301/09/98
40
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376A
Method 23X (DB-225)
Page 3
01/09/98
Data File
Sample ID
P980102
193-196
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
ng
12/29/97
01/07/98
P
M23TRAIN
Soxhlet
0.10 B
P980104
198/199/205/208
ng
12/29/97
01/07/98
P
M23TRAIK
Soxhlet
P980103
201-204
ng
12/29/97
01/07/98
P
M2 3TRAIN
Soxhlet
1.4
0.07 B
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 93.9 92.1
89.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:2301/09/98
41
-------
Method 23 Sample Calculations:
Analyte Concentration
The concentration or amount of any analyte is calculated using the following expression.
Where:
At*RRF(a)*W
Amt(a) - amount of a given analyte, expressed in nanograms (ng) or picograms
(pg).
AO - integrated current for the characteristic ions of the analyte
A0 - integrated current of the characteristic ions of the corresponding
internal standard
Qp - amount of internal standard added to the sample before extraction
RRF(0) - mean analyte relative response factor from the initial calibration
W - sample weight or volume (W - 1 .0 for Method 23 samples)
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
Where:
2.5
F
- H
03
RRF(0)
W
DL(a> =
2*2.5*(F*H)*
w
estimated detection limit for a target analyte, expressed in ng or pg
minimum response required for a GC signal
an empirical number that approximates the area to height ratio for a
GC signal. (F - 3.7 for all dioxin/furan analyses)
height of the noise
integrated current of the characteristic ions of the corresponding
internal standard
amount of internal standard added to the sample before extraction
mean analyte relative response factor from the initial calibration
sample weignt or volume
Rev. 11/19/97
-------
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports.
Please note that all data qualifier flags are subjective and are applied as consistently as
possible. Each flag has been reviewed by two independent demists and the impact of the
data qualifier flag on the quality of the data discussed above. The most commonly used
flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag is used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
An '£' flag is used to indicate a concentration based on an analyte to internal standard
ratio which exceeds the range of the calibration curve. Values which are outside the
calibration curve are estimates only.
An T flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated.. All quantitations relative to this standard, therefore, may be
underestimated.
A ' J' flag is used to indicate a concentration based on an analyte to internal standard ratio
which is below the calibration curve. Values which are outside the calibration curve are
estimates only.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
An 'S' flag indicates that the response of a specific PCDD/PCDF isomer has exceeded the
normal dynamic range of the mass spectrometer detection system. The corresponding
signal is saturated and the reported analyte concentration is a 'minimum estimate'. When
the 'S' qualifier is used in the reporting of 'totals', there is saturation of one (not
necessarily from a specific isomer) or more saturated signals for a given class of
Data Flags Page 1 of 2
Rev. 11/19/97
43
-------
compounds. Results for saturated analytes are reported as greater than the upper
calibration limit
A 'U' flag is used to indicate that a specific isomer cannot be resolved from a large, co-
eluting interferent GC peak. The specific isomer is reported as not detected as a valid
concentration cannot be determined. The calculated detection limit, therefore, should be
considered an underestimated value.
A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
An 'X' flag is used to indicate that a polychlorodibenzofuran (PCDF) peak has eluted at
the same time as the associated diphenyl ether (DPE) and that the DPE peak intensity is at
least ten percent of the total PCDF peak intensity. Total PCDF values are flagged 'X' if
the total DPE contribution to the total PCDF value is greater than ten percent. All PCDF
peaks that are significantly influenced by the presence of DPE peaks are either reported as
"estimated maximum possible concentration (EMPC) values without regard to the isotopic
abundance ratio, or are included in the detection limit value depending on the analytical
method
DaaFlags Page 2 of 2
Rev. 11/19/97
44
-------
TLI Project: 44376A
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980026
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
XAD Date Received:
TLI Blank Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor
Blank File:
Analyst
II
12/29/97
01/06/98
n/a
U980026
KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1.2.3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2.3.7.8,9-HxCDD
1,2,3.4,6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2.3.7,8-PeCDF
2.3.4,7,8-PeCDF
| 2J,4.7,8-HxCDF
.,2.3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1.2.3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2.3,4,7,8.9-HpCDF
1.2.3,4,6.7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Arm. (ng)
ND
ND
ND
ND
ND
ND
0.03
0.02
ND
ND
ND
ND
ND
ND
ND
ND
ND
An*L,(«gJ
ND
ND
ND
ND
0.04
ND
ND
. . ND
VWL EMPC \ Ratto RT
0.004
0.006
0.01
0.008
0.008
0.01
0.76 39:37
0.87 24:39
0.005
0.005
0.006
0.005
0.006
0.007
0.008
0.01
0.01
Number DL EMPC
0.004
0.006
0.008
0.01
2
0.005
0.006
0.008 . .. . _
Flags
j
Flags
—
Page 1 of 2
MTTZ.PSR i\St\. LARS 6.1OBSI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1501/10/98
45
-------
TLI Project 44376A
Client Sample: TLI M23 Blank
Method 23 PCDD/PGDF Analysis (a)
Analysis File: U980026.
_
Internal 5&ftdard&
13C,2-2J,7,8-TCDF
3Cl2-2,3,7,8-TCDD
13C,2-U^,7,8-PeCDF
13Ci2-U,3,7,8-PeCDD
13CiZ-lA3,6,7,8-HxCDF
13C12-U3.6,7,8-HxCDD
13C12-U,3,4,6,7,8-HpCDF
I3C,z-l,2,3,4,6.7,8-HpCDD
13C,2-1.2,3,4,6,7,8,9-OCDD
Surrogate Standards {type A>
13C,r2,3,4,7(8-PeCDF
13C12-1 A3,4.7,8-HxCDF .
13Ci2-l,2,3,4,7,8-HxCDD
13C,2-U,3,4,7,8.9-HpCDF
Surrogate Standards (Type A)
"CLr2,3,7,8-TCDD
Alternata Standards (Type A)
13C,2-U,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1A3,4-TCDD
I3C,2-lA3,7,8,9-HxCDD
v>' A-mf- &>*&•-•**• *
' ^~ ^P^ *^ ' '
1.8
2.0
1.8
2.0
2.2
2.4
2.0
2.3
3.9
Amt fng)
4.0
3.4
3.6
3.4
Arnt$Ȥ)
3.4
Aim.
-------
Initial
.Date.
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
3.33
Page No.
.01/10/98
Listing of 09800268.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why
TCDF
304-306
304-306
13C12-TCDF
316-318
.RT. OK Ratio Total. Area. .. Area. PeaJc. 1.. Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
316-318
TCDD
320-322
320-322
37C1-TCDD
328
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
2
NL
WL
WH
WH
4
NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
0
24
24
Pe
0
23
23
24
24
25
26
26
Pei
0
22:
23:
23:
23:
24:
24:
24:
25:
25:
25:
25:
26:
26:
26:
Pea
0:
24:
25:
25:
25:
25:
:00
:16
:39
aks
:00
:36
:53
:15
:38
:34
:12
:26
1X3
:00
:49
:25
;33
:41
04
14
38
00
23
32
37
01
17
51
:ks
00
01
22
45
53
53
0
RO
0
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65
1
0
0
.65
0
0
0
0
0
0.
2.
3.
65-
1.
0.
2.
1.
0.
1.
2.
5.
1.
0.
1.
0.
0.
0.
0.
-0.89
.14
.68
.87
-0.89
.84
.69
.57'
.74
.74
.44
.18
.39
• L
- - Al
•0.89
05
42
88
30
76
17
38
14
00
42
15
87
54
34
72
- •
14.37
39.12 15.80
64.58 30.03
103.70
12. 68
220.36
22.80 9.92
67.57 28.78
8,771.67 3,743.99
24.64 10.72
5.19
3.40
8,886.68
Above: TCDF / TCDD Follows -
0.867-1.079
0.000
23.32 0.985
34.55 1.001 2378-TCDF
AN
0.959-1.041
0.000
0.958
17.26 0.970
38.79 0.984
5,027.68 1.000 13C12-2378-TCDF ISO
24.29 1.038
1.064
1.073
3.43
3.52
2.09
3.58
2.08
3.35
1.27
2.87
4 . 44
9.10
1.63
5.30
2.18
3.45
6.17
0.00
1.99
38.33
6,364.27
45.79
16.95
' 3T. 57-
38.33
6,364.27
45.79
16.95
37. ST
.895-1.047
0.000
0.900
0.924
0.929
0.934
0.949
0.956
0.972
0.986
1.001 2378-TCDD
1.007
1.011
1.026
1.037
1.059
0.921-1.079
0.000
0.947
1.001 37C1-TCDD
1.016
1.021
1.021 ~
AN
CLS
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
47
-------
\Page No.
01/10/98
Listing of U980026B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
5 Peaks
6,502.91
13C12-TCDD
332-334
332-334
PeCDF
. 340-342
0
340-342
13C12- PeCDF
352-354
352-354
PeCDD
356-358
D
356-358
13C12- PeCDD
368-370
•
DC
DC
DC
D
DC
DC
DC
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
3
NL
SN
SN
0
NL
6
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
SN
SN
SN
SN
0:00
25:10
25:21
25:41
Peaks
0:00
26:37
27:46
Peaks
0:00
27:43
28:34
28:52
29:01
29:16
29:45
Peaks
0:00
27:46
28 : 20
28:26
28:34
28:53
29:09
29:37
29:57
30:07
Peaks
0:00
27:44
27:48
28:02
28:32
28:40
28:54
29:13
29:20
0
RO
RO
.65-0.89
2
0
0
1
.99
.82
.80
.03
15
12,991
7,420
248
.49
.13 5,864.48
.26 3,308.59
.58 145.33
0.921
0
7,126.65 0
4,111.67 1
140.44 1
-1.079
.000
.993 13C12-1234-TCDD
.000 13C12-2378-TCDD
.013
RSI
IS1
20,659.97
1
RO
RO
1.
RO
.32-1.78
0
1
1
.58
.34
.18
3
6
12
0
.80
.70
.08
.00
.32-1.78
1.21
1.62
1.48
RO
RO
1.03
1.16
1.55
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
1.
79
32-1.78
4.
0.
1.
7.
1.
0.
1.
0.
2.
0.
32-
5.
1.
3.
4.
2:
1.
2.
1.
2.
15
18
13
00
26
93
54
38
57
49
1.78
09
75
68
67
63
67
10
30
19
1
355
6,703
124
.33
.95 219.85
.64 3,995.19
.42 75.63
38.17 23.20
6,444,
47.
.78 3,916.29
.40 33.25
0.925
0
0
0
-1.065
.000
.932
.972
0.860-1.140
0
136.10 0
2,708.45 1
73.17 1
20.01 1
2,528.49 1
18.59 1
.000
.970
.000 13C12- PeCDF 123
.011
.016
.025 13C12- PeCDF 234
.041
IS2
SUR1
13,714.36
: PeCDF / PeCDD Follows —
1.
3.
1.
0.
9.
1.
3.
2.
2.
1.
0.
02
01
86
43
69
55
60
32
75
43
00
0.935-1.022
0.
.000
0.938
0.957
0.960
0.965
0.
0.
1.
1.
1.
975
984
000 12378-PeCDD
Oil
017
AN
0.865-1.135
0.
2.
1.
1.
8.
14.
4.
1.
2.
89
20
28
94
70
16 8.85
00
84
70 • — -
0.
0.
0.
0.
0.
5.31 0.
0.
0.
0.
000
936
939
947
963
968
976
986
990
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
48
-------
Page No. 3
01/10/98
Compound/
M_Z.... QC.Log Omit why
Listing of U980026B.dbf
Matched GC Peaks / Ratio / Het. Tiae
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
29:37 1.48 3,875.54 2,311.28
29:44 1.59 596.05 366.33
29:55 1.65 33.82 21.04
30:00 1.43 35.75 21.06
30:07 RO 2.06 36.82 29.76
- 30:21 RO 1.30 9.51 5.78
30:25 RO 2.88 13.39 15.13
8 Peaks 4,615.04
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
7
NL
SN
SN
SN
0:00
31:05
31:17
31:19
32:04
32:07
32:15
32:19
32:26
32:36
32:50
32:58
33:02
33:09
33:18
33:24
33:39
33:43
33:53
Peaks
0:00
31:05
31:12
31:19
32:03
32:09
32:37
32:57
33:23
Peaks
0:00
31:52
31:57
32:14
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
SO
1.
RO
RO
RO
.05
1
1
2
0
1
1
0
1
1
2
0
1
0
4
12
1
nuu vc . r^^-wu / njLi*ur ruj..Luws - -•
-1.43
.38
.01
.09
.86
.37
.17
.98
.52
.25
.14
.93
.33
.73
.35
.76
.10
1.53
5.73
1.
,70
3
2
5
1
8
5
2
2
1
5
0
1
0
1
0
3
1.
0
1.
0,
.93
• 82
.20
.82
• 29
.24
.15
.91
.73
.44
.98
.61
.96
.48
.38
.62
.75
.58
.34
,00
43-0.59
0.
0.
0.
0.
0.
0.
0.
0.
0.
05-
0.
0.
0.
1.
75
41
46
24
51
50
48
29
50
Above
1.43
67
78
94
24
5.35
33.
86.
2.
3,963.
5,720.
5,659.
66.
3,778.
78 . 11.41
40 27.11
61
06 1,343.56
12 1,900.96
83 1,845.34
50 22.46
14 1,261.42
1,564.26 1.000 13C12-PeCDD 123 IS3
229.72 1.004
12.78 1.010
14.69 1.013
14.44 1.017
4.44 1.025
5.25 1.027
0.962-1.047
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
.000
.967
.973
.974
.997 123478-HxCDF
.999 123678-HxCDF
.003
.005
.009
.014 234678-HxCDF
.021
.025
.027
.031
.036
.039 123789-HxCDF
AN
AN
AN
AN
1.047
1.049
1.054
0.876-1.124
0.000
28.11 0.
59.29 0.
0.
2,619.50 0.
3,819.16 1.
3,814.49 1.
77.17 1.
2,516.72 1.
967
970
974
997 13C12-HXCDF 478
000 13C12-HXCDF 678
015 13C12-HXCDF 234
025
038 13C12-HXCDF 789
SUR2
1S4
ALT 2
ALT1
19,307.83
2.
1.
0.
3.
31
45
83
04 ." "
0.958-1.014
0.
0.
0.
0.
000
971
974
982 "
_.
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola'Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
49
-------
Page No.
01/10/98
Listing of tJ980026B.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. .. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
DC SN 33
DC SN 33
DC SN 33
:03
:11
:30
RO
RO
RO
0
0
0
.54
.81
.37
0 Peaks
DC NL 0
32
32
32
33
33
:00
:14
:44
:49
:07
:32
1
RO
RO
RO
0
3
0
0
.52
.38
.76
.00
.05-1.43
1
1
1
1
1
3
5 Peaks
DC NL 0
:00
DC SN 35:03
0,
RO
RO
DC SN 35:16
DC SN 36:03
408-410
13C12-HpCDF'
418-420
418-420
HpCDD
424-426
424-426
DC SN 36:
:24
RO
RO
.47
.57
.22
.22
.20
.03
.88-1.20
77
.00
0.25
1.02
0.
1.
,65
.61
0 Peaks
DC NL 0 :
35:
36:
36:
37:
00
01
33
55
00
0.
RO
RO
RO
6
14
2,984
4,541
7,683
42
.63
.54 10.17
.31 1,638.26
.57 2,496.74
.47 4,188.38
.76 57.79
1
1
1
.007
.011 123789-HxCDD
.021
AN
0.970-1.030
0
6.49 0
1,346.05 0
2,044.83 1
3,495.09 1
19.09 1
.000
.982
.997 13C12-HXCDD 478
.000 13C12-HXCDD 678
.009 13C12-HXCDD 789
.022
SOR3
IS5
RS2
15,266.65
* HxCDD / HoCDP Fo Hows • •
0
.06
2.55
4 ,
1.
1.
0.
,02
,04
.80
00
37-0.51
0.
0.
0.
0.
0.
4 Peaks
DC NL 0:
DC SN 35:
DC SN 35:
DC SN 36:
DC SN 36 :
DC SN 36:
00
19
27
03
21
30
0.
RO
RO
RO
RO
RO
88-
1.
1.
0.
2.
1.
0.
82
43
44
35
70
1.20
00
28
80
16
97
27
0 Peaks
8.
3,153.
2,130.
27.
24.
02
18 ; 942.30
88 652.89
16 8.30
35 11.79
0.996-1.049
0
.000
1.001 1234678-HpCDF
1.
,007
AN
1.030
1.040
0.943-1.114
0.
2,210.88 1.
1,477.99 1.
23.43 1.
16.91 1.
000
000 13C12-HpCDF 678
044 13C12-HpCDF 789
054
057
IS6
SOE4
5,335.57
; HpCDF / HpCDD Follows * - •
0.
3.
2.
4.
0.
1.
0.
04
86
79
49
61
49
00
0.975-
0.
0.
0.
1.
1.
1.
1.005
000
980
983
000 1234678-HpCDD
008
012
AN
13C12-HpCDD
436-438
436-438
DC
NL 0:00 RO
35:17 RO
36:03
2 Peaks
2.16
0.71
0.98
6.06
17.30
3,149.06
3,166.36
tr* • IJnS*TM1 / l~lf
8.82
1,557.61
0.972-1.028
0.000
12.36 0.979
1,591.45 1.000 13C12-HpCDD 678 IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
50
-------
Page No.
01/10/98
Listing of 0980026B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area.
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
HL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0
34
34
35
35
36
36:
36:
37:
37:
37:
37:
37:
38:
38:
38:
38:
39:
39:
40:
40:
40:
40:
:00
:35
:50
:15
:43
:03
:13
:53
:10
:19
34
41
53
03
19
26
36
29
39
00
03
23
29
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
1.
0.
0.
2.
0.
0.
0.
1.
3.
0.
0.
0.
1.
3.
0.
0.
0.
0.
0.
0.
0.
1.
0.
.75
85
73
87
07
55
87
36
24
78
34
35
20
10
73
37
27
91
58
39
91
41
57
Peaks
0
3
1
0
0
1
3
1.
0,
1.
2.
0.
2.
1.
2.
0.
1.
2.
4.
0.
0.
1.
1.
0.
.08
.41
.64
.87
.36
.78
.48
.80
.62
.35
.78
87
97
57
53
98
47
20
06
68
86
55
66
00
Area.Peax.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
0.899-1.101
0.000
0.873
0.880
0.890
0.902
0.910
0.915
0.931
0.939
0.942
0.949
0.952
0.957
0.961
0.968
0.971
0.975
0.997
1.001
1.010
1.011
1.020
1.022
OCDD
458-460
1.58-460
0.76-1.02
DC NL 0:00 1.00 0.08
39:37 0.76 17.82
1 Peak 17.82
7.72
0.899-1.101
0.000
10.10 1.000 OCDD
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.06
39:36 0.84 4,083.66
39:58 0.88 76.37
470-472 2 Peaks 4,160.03
1,868.54
35.66
0.996-1.004
0.000
2,215.12 1.000 13C12-OCDD
40.71 1.009
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Belov signal to Noise Level
-------
Tile:0980026 #1-724 Acq: S-JZX-lSSa 17:15:57 SC £1+ Voltage SIS 70S Noises4632
303.3016 T:2 BSOB(256, 30, -3.0) rXD(9,5,3, 0.10%, 18528.0,1.00\,f,T) Ezp:SDB5OS
XSIAWSLE LABS Taxt:tl±#44376m ILI BLANK
1004
23:00 23100 24:00 25:00
f±le,0380026 H-724 Acqt 6-JZS-1998 17:15:57 SC KI+ Voltage SIS 70S Noise:4060
305.3987 f:2 BSUB(256,30,-3.0) rXD(9,5,3, 0.10\,16240.0,1.00\,r,T) SxpiSDSSUS
XSIANELS LASS Tartstlif 44376m TLI BLANK
A3.45X5
A2.33X5
26100
OEO
Tia
22:00 23:00 24:00 25:00
rile:U980026 tl-724 Acq: S-JZJT-199B 17:15:57 SC SI+ Voltage 5X5 70S Xoiae:2B91
315.9419 T:2 SSUS(2S6,30,-3.0) PXD(9,5, 3, 0. 10\,11S64. 0,1. 00\,T,T) Ezp:SDS5US
TSXANSLS LASS Taxt:tllt44376a fLI BLANK
1001
aol
40:
201
ol
26:00
-.0.0X0
Tin
8.8E6
.7.1X6
.5.3X6
.3.5X6
.1.8X6
22:00 ' 23:00 24:00 25:00
r±la:U9S0026 tl-724 Acq: 6-JAB-1998 17:15:57 SC XI+ Voltage SIS 70S Xoiao:3450
317.3389 T:2 BSUB(256r30f-3.0) fKD(9f5,3,0.10\,13800.0,1.00\,T,T) Kxp:SDB5US
TBIANGLE LABS TBJCt:tlJ.t44376m TLI BLANK
1003. AS. 93X7
80.
sol
401
ao:
26:00
.0.0X0
Time
o:
-1.2E7
.9.4X6
•-7.1S6
.4.7X6
.2.4X6
22:00 23:00 24:00 25:00
Tile:U980026 tl-724 Acq: 6-JZS-1998 17:15:57 SC XI+ Voltage SIS 70S
330.9792 T:2 Xip:NDB5VS
TSIANSLX LABS Text:tli«44376a TLI BLANK
1004 21:58 22:43 23:27 24:26 24:55 25:25
26:00
0.0X0
Time
50
40.
201
.9.8X7
7.9X7
5.9X7
.3.9X7
2.0X7
22:00 23:00 24:00 25:00
Tile:C980026 tl-724 Acq: 6-JZX-1S98 17:15:57 SC XI+ Voltage 5X2 70S
375.8364 F:2 SzptXDBSUS
TBIANGLZ LABS Tetxtttl±f44376u TLI BLANK
26:00
0.0X0
Time
22:00
23:00
24:00
35.00
26:00
-------
r±le:U980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC EI+ Voltage SIS 70S Noi.aetl013
319.8965 T:2 BSUB(256, 30, -3.0) PED(7 ,5,3,0 .10\,40S3. 0,1. 00\,T,T) SxpiNDBSUS
TRIANGLE LABS Taxt:tllt44376m TLI BLABS
100}
80.
60.
40.
20.
0
4i
At. 33X4
,j
N
23
A3.40E4 J|j|
A3.52X4\
AH.AA-1
fWJ
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j*.oi*3 ^.^i;
W^vM
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ll ..1 1 L
Wv
-1.8X4
A3. 96X4
Al . 78X4 1
A lt/1 1 Jl
Awv
35*00
1.46X4 A9.53X3 1
JLM ill (1 V\ i
y^MwAf
' 26:00
.1 . 4X4
.1.1X4
.7.2X3
.3.6X3
0.0X0
Tlae
rlle:U980026 tl-724 Acq; 6-JZB-1998 17:15:57 GC XZ+ Voltage SIS 70S Boiae:971 N . * •*
321.8936 r:2 BSOB(256, 30, -3.0) PXD(7,5r3,0.10\,3884.0,1.00\,r,T) XxptBDBSUS ^ r"l£>yfc\> '
TSIANGLX LABS Teit:tlit44376a TLI BLABS l5") L
1004 A9.43X4 . fti— ^3.0X4
80.
60.
40.
0
•jjw
k ILAMA/U*
23\00
A1.21X4
A2.4jX4\ (
ta/VW'AJlJW
24(:00
A2.74X4t |
\A/vLr«yk
A3. 4 6X4
WvJV'VV^
Mi
1
25iOO '
^*L'?^
A3. 37X4 A4.38X4 1
VTM/^HM A n/ ^vi/n M/v
.2.4X4
Ll . 8X4
'•.1.2X4
36': 00 ' ' ' Time
rlle:U980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC XI+ Voltage SIS 70S Soiae:13099
331.9368 T:2 BSUB(256, 30, -3.0) PSD(7,5,3,0.10\,52396.0,1.00*,r,T) Xxp:NDB5US
TRIANGLE LABS Taxt:tlit44376a XLI BLABS
1001
80-
60:
40:
20:
o-
' 23:00'
' 24:00 '
AS.B6X7
ft
L, m
A
)l/v
25:00
_1 . 5X7
'26:00
.1.2X7
.9 . 1X6
-.6.0X6
.3 . 0X6
'• o . oxo
Time
f±le:U980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC XH- Voltage SIS 70S Wo±ae:4374
333.9338 T>2 BSVB(2S6,30,-3.0) PSD(7,5,3,0.10\r17496.0r1.00\rT,T) Xzp:SDB5US
TRIANGLE LABS Tejct:tlit44376a TLI BLABS
100J
80:
60:
40:
20:
23:00 '
24\00
A7.13E7
\
1 \L4.11X7
\ A
ll/l
25 1 00
1 . 9X7
'26:00
.1 . 5X7
.1.1X7
.7.4X6
-3 . 7X6
0.0X0
T±me
rlla:0980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC XH- Voltage SIS 70S Soiae:996
327.8847 T:2 BSVB(256, 30, -3. 0) rSD(7,S,3f 0.10%,3984 .0,1 . 00\rr,T) Xxp:NDB5US
TRIANGLE LABS TeJCt:tlJLt44376a TLI BLABS
1001
80:
60:
40:
20:
0:
23 tOO
24:00
A6..
i
6X7
\
25: 00
'26:00
.1.5X7
.1.2X7
.9.0X6
.6.0X6
.3 . 0X6
0.0X0
Time
rlla:O980026 tl-724 Acq: 6-JAB-1998 17:15:57 GC EH- Voltage SIS 70S
330.9792 Ti2 XxptKDBSVS
TSIANGLX LABS Text:tULt44376m TLI BLABS
1001
so:
60:
40:
20:
o:
_ 22:57 33:27 33,49 24:1124:26
33\00
24:00
24:55 25:25
25:00
26jJ>4 26:35
'26:00
.9.8X7
.7.9X7
.5.9X7
.3.9X7
.2.0X7
0.0X0
Time
53
-------
rila:U980026 tl-724 Acq: 6-JXS-1998 17ti5tS7 GC XH- Voltage SIX 70S Soia*:1156
339.8597 T:2 3303(256,30, -3.0) ?Kn(7,5,J,0.10\,4624.0,1.00\,r,T) SrptHDBSVS
TXIASGLX LASS Tmxt:tU.t44376* TLI BLAST
100* A7.34X4 A9.84X4
ao:
eo:
40:
20:
oj
A6.64E4
A3.84X4
A1.31X4
27i00 28*00 29:00
Tila,0930026 tl-724 Acq: 6-JAS-1998 17:15:57 GC XH- Voltage SIS 705 Noiae:2006
341.8567 r:2 3SUS(256,30, -3.0) PTB(7,5,3,0.10\,8024.0,1.00\,r,T)
TSIASSLX LABS Text:tU.t44376m TLI BLAST
i00* AS.66X4
flflH A6.22X4 '
80- A2.231
SO.
40:
20:
o:
30,00
A .OtX
27:00
m.ai0980026 tl-724 Acq: S-JAK-
351.9000 T:2 3SU3(256,30, -3.0)
XBIANGLZ LASS TOJCt.:tJJ.t44376a
1001
80:
sol
40:
20:
o:
28:00 29100
1998 17:15:57 GC EI+ Voltage 512 705 Noiaei40S
PXD(7,5,3,0.10\,1620.0,l.QO\,r,T) SxpsNDBSUS
TLI BLAOK
A4.00S7
301 00
27:00
rila:O980026 tl-724 Acq: 6-JUt-
353.8970 T:2 3SUB(256,30,-3.0)
TSIANGLE LABS Text:tli*44376a
1001
28:00 29:00
•1998 17:15:57 GC EI+ Voltage SIS 70S Noise1335
PKD(7,5t3,0.10\,1340.0,1.00\rr,T) Elp-.NDBSUS
TLI BLASX
30:00
OJ
27:00
rileiU980026 tl-724 Acq: S-JKH-
409.7974 r:2 ZxptBDBSUS-
TSIASSLE LABS Text:t-LL»44376a
1001 ,
.28:00 29:00
1998 17:15:57 GC EH- Voltage SIS 70S
TT.T
30:00
-2.0X4
'.1. 6X4
.1.2X4
.8.1X3
.4.0X3
0.0X0
.2.1X4
.1. 7X4
,1.3X4
.9.5X3
.4.2X3
.0.0X0
Tim.
.1.1X7
8.5X6
6.4X6
4.2E6
2.1X6
0.0X0
Time
1 1
L
27't 00 28:00 29:00 30:00
IU98Q02S tl-724 Acq: 6-JXK-1998 17:15:57 GC.XH- Voltage SIS 70S
9792 T:2 XzpiXDBSVS
[OGLE LABS Text:tl±t44376a TLI BLAST
26:35 27:02 27:3827:53 28:12 38i42 29:16 _ 29:52 30^19
6.9X6
is.5X6
.4.2X6
.2.8X6
.1. 4X6
0.0X0
Time
9.9X7
7.9X7
6.0X7
4.0X7
2.0X7
0.0X0
Time
27:00
28100
29100
30100
54
-------
fHa:US80036 tl-724 Acq: 6-J&K-1998 17:15:57 SC SI* Voltage SIS 70S JfOiaei 831
355.8546 f:2 BSVB(256,30, -3.0) PXD(S,5,3,O.OS\r3324.0,1.00\,T,T) XxptHOBSUS
TSIAKSLE LABS Text,tlit44376a TLI BLAHX
1004 A2.61E4
-2.7S4
27:48 28,00 28', 12 28:24 28,36 28,48 29,00 29,12 29:24 29:36
rU.»:U980026 tl-724 Acq, 6-JAN-1998 17,15,57 SC XI* Voltage SIS 70S So±ae,201
357.8516 r,2 BSU3(256,30, -3.0) PXD(5,5,3,0.05\,804.0,1.00\,r,T) XzptSDBSUS
TSIASGLX LABS Text:tU.t44376a TLI BLAST
1001A1 2E5
80.
60.
40.
20.
3024
A3.72E4
VyvJ^jwk^
-2.8X4
.2.3X4
.1.7X4
.1.1X4
-5.7E3
.0.0X0
27:48 28,00 28:12 28:24 28:36 28:48 29:00 29,12 29,24 29,36 29:48 30:00 30:12 30:24 Time
r±le:U980026 tl-724 Acq: 6-J7OT-1998 17:15:57 SC XI* Voltage SIS 70S Soiae:889
367.8949 T:2 BSUB(256,30, -3. 0) PU>(5,5,3,0.05\,3556.0,1.00\,T,T) XxptHDBSUS
TSIAKSLE LABS TB5US
TBIANGLE LABS Toxtttl±t44376a TLI BLAHX
1001 A1.56E7
80.
60.
40.
20:
o:
.30E6
28,12 28,24 28:36 28:48 29,00 29,12 29,24 29,36 29:48 30,00 30:12 30,24
r±le,U980026 tl-724 Acqt 6-JAH-1998 17,15,57 SC XI* Voltage SIS 70S
330.9792 r,2 XxpiJWBSUS
TSIAHSLX LABS TeitttU.t44376a TLI BLAST
5.3X6
.4.0X6
.2. 7X6
1.3E6
0.0X0
life
OOJ
80.
60.
40.
20.
0
27,53 2BsLa — .^jyjf 38:54 29:0529,16 ^_ 29:52 30±19
27:48 28,00 28\12 28', 24 2S\36 2a',48 29:00 '29:12 29', 24 29\ 36 ' 29,48 ' 3o', o6' jfliiJ ' 30:24 "
.4.4X6
.3.5X6
.2.6X6
.1.8X6
.8.8X5
0.0X0
Time
9.9X7
7.9X7
6.0X7
4.0X7
2.0X7
0.0X0
Time
c r
o J
-------
rila:U980026 tl-384 Acqi 6-JXN-1998 17:15:57 SC EI+ Voltage SIS 70S Noiaatll39
373.8208 T:3 BSOB(256,30,-3.0) ?XD(7,S,3,0.10\,45S6.Q,1.00\,rrT) ExpsSDBSOS
TSIAHSLX LABS Tmxt:tU.t44376* TLI BLANK
0X0
31tOO 31:12 31i24 31t36 31t48 32tOO 32:12 32:24 32i36 32't4a' 33:66 33:12' 33V24' jji 36 33: 48
rlla:U980026 H-384 Acq: 6-J3UT-1998 17tl5tS7 GC EI+ Voltage SIS 70S Nolae:B24
375.8178 f:3 BSOB(256,30, -3.0) PXD(7,5,3,0.10\,3296.0,1.00\,r,T) SxptODBSUS
TSIASSUS LABS Text:tlit44376a TLI BLANK
0X4 .1.5X4
T±ae
31iOO 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:66' 33:12'33i24'33:36 33:48
ttJ.e:U9S0026 tl-384 Acqi 6-J7OT-1998 17:15:57 GC ZI+ Voltage SIX 70S Noises 1336
383.8639 T:3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,S344.0,1.00\,T,T) Xip:tlDB5US
TRIANGLZ LABS Tejctitlit44376a XLI BLANK
1001
00:
601
40.
201
A1.90E7
A1.BSE7
A1.26E7
Tiffl
-4.3E6
.3. 9E6
.3.0X6
.2.0X6
-.9.8E5
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rile:US80026 tl-384 Acq: 6-J3UT-1998 17:15:57 GC KH- Voltage SIS 70S Noise: 1769
385.8610 r:3 BSOB(256,30,-3.0) PXD(7,5,3,0.10*r7076~.0,1.00\,r,X) Kxp:KDB5US
T&IANSLZ LABS Text:tld.t44376a TLI BLANK
.0.0X0
Time
A3.82E7
1001
80:
40.
20:
ol
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rlla:V980Q26 tl-384 Acq: 6-J7UT-1998 17:15:57 GC XH- Voltage SIX 70S
392.9760 T:3 Erp:NDB5US
TRIANGLE LABS Text:tl±f44376a TLI BLASX
31:20 _ ,-**-£--. J?l™ I?-'-3 33^35 3*'* 33i01 _ 33'-4- 33:42
SO
50J
40:
201
4.5E7
•.3.6X7
'•.2.7X7
-.1.8X7
'.9.0X6
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rile:0980026 tl-384 Acq: 6-JXK-1998 17:15:57 GC XH- Voltage SIS 70S
45.7555" f:3 Eip:NDB5US
TRIANGLE LABS Textttlit44376a TLI BLANK
1001 33 30
".0.0X0
Time
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
-------
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
r±le:0980026 tl-384 Acq: S-JMr-1998 17:15:57 GC XH- Voltage SIX 70S Noiao:2181
401.8558 T:3 BSUB(256,30, -3.0) ?KD(7,5,3,0.10\,8724.0,1.00\,r,T) Xxp:XDB5US
TSIANSLE LABS T&zt:tJJ.t44376a TLI BLANK
1001 A4.19E7
rila:u980026 tl-384 Acq: o-uJUi-iyyU J./:±3:3/ GC Sir Voltage SLM 70S lfoj.a»:oJS
389.8156 T:3 BSUB(256,30, -3. 0) fXD(7,5,3,0.10%,2S52.0,1.00\,r,T) Xrp:SDB5US
TSIASSLX LABS Toxt:tlit44376a TLI BLANK
1001 AS. 20X4
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
File,0980026 fl-384 Acq: 6-JAN-1998 17:15:57 GC XX + Vbltage SIS 70S No±ae:954
391.8127 r:3 BSUB(256,30, -3.0) PXD(7,S,3,0.10\,3816.0,1.00\,r,X) Xrp:HDB5US
TBIAXOLX LABS T*xt:tlit44376a TLI BLANK
33124
.0.0X0
33 36 Tim.
33s 24
80.
60.
40.
20.
A2.50X7
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
rile:O980026 tl-384 Acq: 6-JAN-1998 17:15:57 GC XH- Voltage SIS 703 Noiae:1479
403.8529 T:3 BSV3(256,30,-3.0) fKD(7,S,3,0.10\,S916.0,l.QO\,T,T) XzptNDBSUS
TBIANGLX LABS Teit:tl±t44376a TLI BLANK
1004 A3.50X7
80.
60.
40.
20.
0.
33:24
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00
rllet0980026 tl-384 Acqt 6-J7UT-1998 17:15:57 GC XH- Voltage SIS 70S
392.9760 r:3 KipiNDBSUS
TRIANGLE LASS TertltHi44376a TLI BLANK
33:12
100S,
80.
eo:
40.
20.
0.
31:48
32:04
32:23
32:48
33:01
33:24
33:24
33 36
0.0X0
Tin.
33 36
.0.0X0
36 Time
4.5X7
.3.6X7
.2.7X7
.1.8X7
'.9.0X6
31:36
31:48
32:00
32:12 32:24 32:36 32:48
33:00
.0.0X0
33:12 33:24 33 36 Tiae
-------
\Til*tO960026 #1-545 Acqt 6-JKH-1998 17,15,57 SC EI+ Voltage 5X2 705 Noiaa:1156
407.7818 f:4 3503(256,30, -3.0) PKD(7,S,3, 0.10\,4624.0,1.00\,rfT) XiptSDBSOS
TBIANGLZ LASS Text:tlJ.*44376a TLI BLANK
IOCS
35,00 35il2 35:24 35:36 35,48 36,00 36,12 36,24 36,36
rU»:O980026 91-545 Acqi 6-J7Ur-1998 17,15,57 SC XH- Voltage SIX 70S flbi*«>15
409.7789 T:4 3SU3(256,30,-3.0) Pja>(7,5,3,0.10\,64.0,1.00\rrrl) SxptUDBSOS
XBIASGLX LABS Text:tl±t44376a TLI 3LAOX
36,48
37 tOO
Urn
35,00 35,12 35:24 35,36 35:48 36:00 36:12 36:24 36:36
rile,0980026 fl-545 Aaj: 6-JZS-1998 17:15:57 SC XH- Vtoltagra SIX 705 Hoiae,2276
417.8253 T:4 BSOB(256,30,-3.0) PXD(7,5,3,0.101,9104.0,1.00*,f,T) Xxp:SDB5US
T&IANGLZ LABS Taxt:tU.t44376a TLI BLANK
1004 A9.42E6
A6.53E6
36:48
37:00
.0X0
Tlae
35:00 35,12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
rHe:0980026 tl-545 Acq, 6-JAS-1998 17:15:57 GC XI+ Voltage SIS 70S Noise,27B6
419.8220 F,4 BSVB(256,30,-3.0) PXD(7,5,3, 0.101,11144.0,1.OQ\,r,T) Kxp:lWB5US
TXIAKSLX LABS Xextstl±t44376a TLI BLAST
100% A2.21X7
A1.4SE7
36:48
37:00
.0X0
Tiae
35:00 35,12 35,24 35:36 35,48 36:00 36,12 36:24
r±lo,U980026 tl-545 Acq: 6-JAK-1998 17:15:57 GC XI+ Voltage SIS 70S
430.9729 Tit XxptXDBSUS
TRIANGLE LABS Taxt:tli#44376» TLI BLANK
1004, 35,14 35JL?8 35:42 36,01 36,20 36,27
50:
40:
OJ
36:36
36,38
36:48
37:00
35,00 35:12 35:24 35:36 35:48 36:00 36:12 36,24
Tila,0380026 tl-545 Acq: 6-JJOT-1998 17:15:57 GC XH- Voltaga SIB 705
479.7165 T:4 ExptNDBSUS ......
TSIAHGLX LABS Text:tlJLt44376f TLI BLANK
1004
36,36
36:48
37:00
,2X7
,6X7
,9X7
.3X7
4X6
0X0
Time
35,00
35,12
35:24
35,36
35:49
36:00
36:12
36:24
36,36
36:48
37,00
58
-------
ru.aiU3ao026 il-545 Acqi o-JAa-lyyo i/siiiaJ SC Sir voJitfyf SIM 70S Noj.amiJ.0
423.7766 T:4 8303(356,30, -3. 0) PXD(7,S,3, 0.10\,40.0,1. 00\,f,T) Kxp:SDB5OS
TSIAKSLX LABS Text.-tl±*44376* TLI BLANK
1004
A4.76X4
80.
35:12 35:18 35:24 35:30 35:36 35t42 35:48 35:54 36:00 36t06 36:12 36:18 36:24 36:30
r±l»:a980026 H-545 Actj: 6-J3UT-1998 17:15:57 SC XI+ Voltage SIX 70S So±aeil2
425.7737 T:4 3SVB(2S6,30,-3.0) tJO)(7,5,3,0.10\r48.0,1.00\,T,I) XxpiSDBSUS
TB.IAXGLX LASS Text:tlll44376* TLI BLAXX
1001
Time
O.OEO
35,12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
rlle,V980026 41-545 Acq: 6-JKH-1998 17:15:57 SC EH- Voltage SIS 70S Ho±ae:3204
435.8169 T:4 BSOB(256,30,-3.0) PXD(7,5,3,0.10\,12816.0,1.00*,r,X) EzptXDBSUS
TRIANGLE LABS Tej[titli*44376a TLI SLANT
1004 A1.5.6X7
80.
60.
40.
20.
"~35:12' 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
rlla:a9B0026 tl-545 Acq: 6-JAN-1998 17:15:57 SC EI+ Voltage SIS 70S Hoiaetl484
437.8140 T:4 BSUB(256,30, -3. 0) PKD(7, 5,3, 0.10\,5936. 0,1. 00\,T, T) XxpsSDBSUS
TRIANGLE LABS Text: tlif 44376* TLI BLANK
100J> A1.59K7
80.
60.
40.
20.
Tiae
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
r±le»0980026 tl-545 Acq: 6-JXK-1998 17:15:57 SC EH- Voltage SIX 70S
430.9729 T:4 ExptNVBSUS
TRIANGLE LABS Text: tl±f 44376* TLI BLANK
1004 35jl4 _ 35j^a 35_^42 ^SjJ9 ^ jf^^1 36:08 -
80.
50.
40.
20:
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36t06 36:12 36:1836:24 36:30
.3.1Z7
.2.SE7
.1.9E7
1.3E7
6.316
,0.0X0
Tiae
-------
Til*:O980026 tl-545 Acq:o^JAN-1998 17:15:57 GC EI+ Voltage SIS 70S NoiaetjS
441.7438 r:4 BSUB(256,30, -3.0) rKD(7,S,3,0.10\,144.0t1.00\,T,T)
TRIANGLE LABS Text:tlit44376* TLI BLANK
loot
aoj
flflj
70.
60;
A1.31Z4
A3.57X4
401
A3.87X4
35:00 36:00 37:00 38:00 39:00
file:0980026 tl-545 Acq: 6-JAW-1998 17:15:57 GC XH- Voltage SIS 70S Soiaet21
443.7399 Tt4 BSUB(256,30, -3. 0) PXS(7,5,3,0.10\, 84.0,1.00\,r,T) XxptHDBSUS
TSIANGLX LABS Tezt:tlit44376a TLI BLANK
J 001
903
40,00
-1.5X4
.1.4X4
.1.3X4
.1.1X4
.9.3X3
.7.6X3
.6.1X3
.4.6X3
.3.1X3
11.5X3
.0.0X0
41 00 Tia
35:00 36:00 37:00 38:00 39:00
Til»tU980026 tl-545 Acq, 6-JAN-199S 17:15:57 GC XH- Voltage SIR 70S
430.9729 T:4 Xlp:SDB5US
TSIANGLX LABS Text:tllt44376* TLI BLANK
"°* 34,30 34,47 35i" ">» "'^
J^^^ill^^^^^
80.
so
20-
JOJ
0.
40:00
35,00 36:00 37:00 38:00 39:00
•ila,U980026 tl-545 Acq: 6-JXK-1998 17:15:57 GC XI+ Voltage SIX 70S
•13.6775 F,4 ExpiNDBSUS
TSIANGLX LABS Text:tlit44376a TLI BLANK
100,
90^
37:19
40:00
41:00
3.2X7
13.9X7
'.3.6E7
12.3X7
'•.1.9E7
ll. 6X7
-.1.3X7
19.7X6
-.6.5X6
.3.2X6
lo.oxo
41:00 Tine
35,00
36:00
37:00
38:00
39:00
40:00
.0.0X0
41:00 Time
60
-------
73X4
ri-La:O9U001& tl-545 Acq: 6-JAn-lSSa -l/i-iSO/ SC SI+ voltage SIM 70S lioiae
457.7377 r-.4 BSOB(356,30,-3.0) PXO(7,5,3, 0.iO\, 84. 0,1.00\,T,T) SxptHDBSUS
TRIANGLE LASS TfJCt:tLH44376t TLI BLASK
100* A7.J
80.
so:
40.
30.
A9.76X3
AA7
39:30 39:36 39t43 39:48 39:54
TileiO9BOO26 11-545 Acq: 6-JMT-1998 17il5i57 SC XI+ Voltage SIS 703 Noise:20
459.7348 Ti4 B3VB(356,30f-3.0) PXD(7,5,3,0.10\,80.0,1.00\,r,T) XxptSDBSVS
TRIANGLE LABS TaxtitLH44376m TLI BLAST
1004 A1.01X5
40:00
_1. 4X4
.1.1X4
.8.3X3
.5.6X3
'.3.8X3
'.0.0X0
40 06 Tine
-3.1X4
39:30 39:36 39:43 39:48 39:54
rila: 0980026 tl-545 Acqs 6 -JAN- 1993 17:15:57 SC EH- Voltage SIS 70S Noise -.16
469.7779 t:4 BSnS(356, 30, -3.0) PKD(7,5,3, 0.10%, 64. 0,1. 00\,r, T) Kxp:ltoB5US
TSIANSLX LABS Text: tli*44376* TLI BLANK
40:00
1003,
80.
60.
40.
30.
Al.
39', 30 39:36 39:43 39:48 39': 54
rllatO980036 tl-545 Acq: 6-JX1T-1998 17:15:57 SC XI+ Voltage SIR 70S Noiae:13
471.7750 r:4 BSUB(356,30,-3.0) fXD(7,S, 3, 0 .10\, 53.0,1. 00\,r,T) Xxp:NDB5US
TBIANSLX LABS Taxt:tlit44376t TLI BLANK
1001 A3. 33X7
80.
SO.
40.
30.
OJ
39\30 ' 39:36 39:43 39:48 39i54
T±lai0980036 H-545 Acq: 6-JAN-1993 17:15:57 SC EH- Volt aye 3IS 70S
430.9739 f:4 Eip:NVB5US
TSIASSLX LABS Text:tlit44376a TLI BLARX
1001 _ ____ . ____ 24*45 ______ -^ ___ _39j54
80.
60.
40.
30.
0.
40:00
40:06 Time
-3.9X6
.3.3X6
.1. 7X6
.1.3X6
.5.8X5
.0.1
40:06
40:00
.0.0X0
40 06 Tiae
39:30
39:36
39:43
39:48
39:54
0.0X0
40:00
40 06 Tiae
-------
CJ
CO
Peak Locate Examination: 6-JAN-1998:17:12 File:U980026
Experiment:NDB5US Function:2 Reference:PFK
-------
TLI Project 44376A
Client Sample: TLI M23 Blank
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P980094
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
Gulp Aluminum Alloys
XAD
TLI Blank
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
/ /
12/29/97
01/06/98
n/a
P980094
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
FTT \FJa$5
2J.7.8-TCDF
0.02
0.65
23:06
ftatfo"
RT
Flags
l3Cu-2,3,7,8-TCDF
15
63.6
40%-130%
0.76
23:05
Rfecoyery Stancterd
Ratio
RT
Flags
0.82
21:55
Data Reviewer.
PA/V
01/09/98
Page 1 of 1
C2NF.PSR .2.01. LARS 6. IO.UXI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:14 01/ft9/88
bo
-------
Initial Date...
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio liaita haa been recalculated according to method requirements.
Page No. 1
01/07/98
Listing of P980094B.dbf
Hatched GC Peak* / Ratio / Ret. Tiae
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
XL 0
SN 18
SN 20
SN 21
21
SN 21
23
SN 25
WH 25
:00
:42
:40
:16
:37
:46
:06
:17
:40
0
RO
RO
RO
RO
RO
RO
.65-0.89
0
0
0
0
0
1
0
.91
.88
.53
.26
.83
.32
.65
0.37
0.52
2 Peaks
DC
DC
DC
DC
DC
ML 0
WL 21
WL 21;
WL 21:
23:
23:
:00
:08
:36
:51
:05
:42
WH 25:10
0.
RO
RO
65-0.89
1.04
0.49
0
0.
.80
.81
0.76
0.74
RO
0.99
2 Peaks
DC
DC
DC
DC
NL 0:
20:
21:
21:
22:
23:
WH 24:
WH 24:
WH 24:
00
30
37
55
41
14
10
27
47
0.
RO
RO
RO
RO
RO
RO
65-0.89
1.
0.
0.
0.
0.
2.
0.
0.
1.
82
47
79
82
77
15
52
52
56
1.61
0.96
0.69
0.39
7.82 3.54
0.44
9.74 3.85
0.76
1.10
17.56
2.09
3.08
13.44
42.85
1,564.48 674.65
5.77 2.45
18.67
1,570.25
Above: TCDF / TCDD Follows -
332-334
5 Peaks
1.38
3.61
1,110.48
1,771.78
15.06
2.28
3.10
6.53
0.97
2,903.21
1.57
490.07
796.54
6.55
2.77
0.792-1.101
0.000
0.810
0.895
0.921
4.28 0.936
0.943
5.89 1.001 2378-TCDF AN
1.095
1.112
0.957-1.043
0.000
0.916
0.936
0.947
889.83 1.000 13C12-2378-TCDF ISO
3.32 1.027
1.090
0.908-1.092
0.000
3.37 0.948
620.41 1.000 13C12-2378-TCDD IS1
975.24 1.014 13C12-1234-TCDD RSI
8.51 1.049
1.29 1.075
1.118
1.131
1.146
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 01:14 01/07/98
64
-------
Page No. 2 Listing of P980094B.dbf
01/07/98 Matched GC Peaks / Ratio / Rat. Ti»e
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description 'Why' Code Description QC Log Desc.
M_2 -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:as) WH-Above Retention Tine Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO-Ratio Outside Limits
-------
ru.*iP9aoos4 91-932 Acq:o-jAn-ya 23:*y.m EI+ voJ-taga six /OP
303.9016 Sxp:DB335
XRIJOtSLX LASS TazttZCX M23 BLAST TLIM4376A
1001
95.
90.
85.
80.
75.
70.
65.
60.
55.
50.
45.
40.
35.
30.
25.
20.
15j
10:
5:
0
33:06
i
\
32:45
\
25,17
« J
25:12\
23:33 1
1 il I . 1 II
1 ill 1 W HAITI d"« "i'l 34>3a 1 IJI 1
\rn\M V lj nrl^ H/i
V ' j( \j fV V
-,/A//r")- l-rf
**-"^ Lw*
Or* '
I
33\ 36 "22\ 48' 231: bo' 23\'l2 23:24 23:36 2J>4s' 24':6o' 24:1^' 24\24' 34': 36' 34:48' 25ib6' 25*: 12' 25.-J4
-1.5X4
L1.5X4
Ll.414
.1.3X4
.1.2X4
J..3X4
'-.1.1X4
.1 . 0X4
J.3X3
'.8.5X3
.7.7X3
17.0X3
-.6.2X3
.5.4X3
'-.4.6X3
'-.3.9X3
-.3.1X3
-.2.3X3
'.1.5X3
'.7.7X2
'• 0 . 0X0
Time
rila IPS 80094 tl-933 Acq:6-JXH-98 23:49:01 XX+ Voltage SIR 70S
315.9419 Ezp:DB335
TBXANSLX LABS T&xtiTLI M33 BLAXX TLH44376A
100]
55.
90:
85:
80:
75:
70:
65:
60:
55:
SO:
45:
40:
35:
30:
25:
20.
15:
1
-------
fiJ.a:P9ao094 #1-922 Acq: 6-JAH-yo JJ:4y:tll £1+ vo-icaye SIM sur HoiaestiJ
303.9016 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,1652.0,0.00\,r,r) Xxp:DB22S
TRIASSLX LASS Taxt.-ZZJ H23 BLAST TLH4437SA
1003
80.
SO.
40.
20.
0.
A3.85X4
A3.26X3
19:00 20:00 21:00 22:00 23:00 24>QO
T±le:P980094 tl-922 Acq:6-J7Or-98 23:49i01 XI* Voltage SIS 70P Noise:457
305.8987 BSUB(256,30,-3.0) PXX>(5,3,1, 0.10\,182B.O,0.00\,TtT) Xxp:DB225
XSIANSLS LABS TttrtJUJ K23 BLAKX TLH44376A
1001 AS.89X4
25:00
19:00 20:00 21:00 22:00 23:00 24:00
r±letP980094 tl-922 Acq:6-JKS-96 23:49:01 EI+ Voltage SIS 70P Soiae:61S
315.9419 BSUB(2S6,30,-3.0) PKD(5,3,1, 0.10*,2460. 0,0.00\,r,T) Xzp:DB225
LABS Text:TLI M23 BLANK TLI»44376A
1004 A6.75E6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23:00 24:00
Tile:P980094 tl-922 Acq:6-JKK-9B 23:49:01 ZI+ Voltage SIS 70P Koiao:589
317.9389 BSUB(256,JO,-3.0) PKD(5, 3,1, 0.10^,2356.0, 0.00\,r,f) Krp:OB225
TSIANSLS LABS Teit:TLI H23 BLAXX TLI»44376A
1003, A8.90Z6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23:00
r±le:P980094 tl-923 Acqt6-JXX-98 23:49:01 £2> VoltMge SIS 70P
375.8364 Ezp:DB225
TKIANGLZ LABS Tejct:TLI M23 BLABX TLH44376A
100118 32
24:00
25:00
-1.2X4
.9.6X3
.7.2X3
.4.8X3
'.2.4X3
0.0X0
Tiae
Time
.1. 8X6
.1.5X6
,1.1X6
7.3X5
3.7X5
.0.0X0
Xlae
2.5X6
2.0X6
1.5X6
9.9X5
4.9X5
0.0X0
Time
ao:
6QL
40:
20:
01
-1.2X4
^^
'.9.7X3
.7.2X3
.4.8X3
.2.4X3
19:00
20100
21:00
22:00
23:00
24:00
25:00
'-0.0X0
T±ae
67
-------
ril«:P9BuoS4 #1-922 Acqsf-JAN-9B JJ:49:01 EI+ Voltage SIS 70P Noiea:J97
319,8365 BSUB(256,30,-3.0) PKD<5,3,l,0.10\,158a.OrO.OO\rT,T) XrptDB225
TSIANGLX LASS TmrttTLI H23 BLAST TLIt44376A
20'tOO ai'iOO 23:00 23*00
\r±J.*tP980094 tl-922 Acqt6-JJOT-98 23*49,01 XI+ Voltage SIS 70P Boiae>465
321.8936 BSVB(256,30r-3.0) PKD(S,3,1,0.10\,1B60.0,0.00\,T,T) XxptOB22S
TRUUKLX LASS TerttTLI H23 BLANK TLH44376A
, A2.15X3
24100
0.0X0
'2S\ 00 Ma
20:00 21:00 22:00 23'tOO
\rHasP980094 tl-922 Acqs6-JKHt-98 23t49s01 EI+ Voltage SIX 70P Soiae:498
327.8847 3SUB(256,30,-3.0) PXD(5,3rl,0.10\,1992.0,0.00\,T,r) EzptDB225
T3IANGLX LABS TexttTLI H23 BLANK TLH44376A
100\ A1.Q6E7
801
60.
40.
20.
24100
O.OEO
25i00 T±me
-2.9ES
[.2.3E6
1.1.726
.1.1X6
-S.7ES
20', 00 21:00 22'tOO 23tOO
\TiletP980094 tl-922 Acqt6-JTUl-9S 23i49t01 Eli- Volfcsffe SIS 70P Soiaet710
331.9368 BSVB(256,30r-3.0) PXD(S,3,l,0.10\r2840.0,0.00\,TfT) XxpiDB225
TSIANGLX LABS TextsTLI M23 BLANK TLIt44376A
1003, A7.97E6
BO.
60.
40.
20.
241 00
'.O.OEO
25100 T±ae\
-.2.1X6
.1. 7X6
J..3E6
.8.3X5
-4.2X5
20:00 21:00 22:00 23:00
T±letP980094 tl-922 Acqt6-J7ur-98 23:49:01 XII- Voltage SIS 70P Ho±aes388
333.9338 BSUB(256,30, -3.0) PXS(S,3,1,0.10\,1552.0,0.00\,F,T) SrptDB225
TRIAJKLS LABS TartiTLX H23 BLANK TLIt44376A
1004 A9.75E6
24 tOO
'.0.0X0
25100 Mae
so:
so:
40:
201
0.
A6.20X6
201 00
21:00
22,00
23100
24100
.2.6X6
-
.2.1X6
.1.6X6
.1.0X6
.5.2X5
'.0.0X0
25100 Mae|
63
-------
rile:P980094 #1-922 Acq: 6-JAK-98 23:49:01 XI+ Voltage
303.9016 Xxp:DB225
TRIANGLE LABS TeJCt:TLI M23 BLANK TLI444376A
1001 21.-J7
80.
60.
40.
20.
0
rile
315.
TBIJt
1001
80.
60.
40.
20.
o-
rile
319.
TSIA
1003
30:
4 0 '
20:
o'-
File
331.
TSIA
1001
80:
40:
o-
rile
292.
TSIA
1001
ao:
60:
40:
20:
o-
rile
330.
TSIA
1001
ao:
60:
40:
20:
o-
19:04 19:43 20:38 31:08 (I
^r^^^f^iUfJ^J^ W/V"MRi*
19:00 20:00 21:00 22:00
:P980094 #1-922 Actji6-JAN-98 23:49:01 EH- Voltage
9419 E*p:DB225
\KSLX LABS Text:TLI M23 BLANK TLH44376A
-
19:00 20:00 21:00 22:00
IP980094 #1-922 Acq:6-JAN-98 23:49:01 XI+ Voltage
8965 Xxp:DB225
NGLE LABS Text:TLI M23 BLANK TLI#44376A
18:45
1 19:11 19:53 21:17 22:03
\MvljlJ&jiMj|j^^ ,ij
v Y i^ft/TV '^ T[l IM^YW^r^V^ Wy |U^
' is',00 ' 20:00 21:00 J2.-00
:P980094 #1-922 Acq: 6 -JAN- 9 8 23:49:01 XI+ Voltage
9368 Xxp:DB225
NGLE LABS TeitzTLI H23 BLANK TLH44376A
21:55
Tl
1
III!
SIS 70P
23:06
22,45 33f33 "\i7
23:00 24'tOb 25:00
SIS 70P
23:05
II
2J:00 24:00 25:00
SIS 70P
25 07
23,14 33:51 ||
^&faUU^\^?'&dffil iMdflLJ
INpVvt^vVrilT^ Vr'jliyv
2jioo ' ' 24:00 ' 25:00
sja 7op
19:00 20:00 21:00 22:00 23': 00 24:00 25:00
:P980094 #1-922 Acqs 6-JZN-9a 23:49:01 XI+ Voltage SIS TOP
9825 Xxp:DB225
NGLZ LABS Text:TLI H23 BLANK TLH44376A
19:1019:35 20:14 21:11 21:56 22:31 23:18 24:01 24:54 25:24 „
>r^Sk^*>V*\ /VMkA»xiTW*vwx i/w -A"\ /lAj»NA /\Aj^^«V^>M/*Mrtrl)^"*v*A*U^M>/-'N * o^wMArVS ^»"^y\r*yA/v-rt ^WWtr
19:00 20:00 21:00 22:00
:P980094 #1-922 Jicq-: S-J3UT-98 25:49:01 £T^- Volta?a
9792 Xxp:DB225
NGUT LABS Text:TLI H23 BLANK TLII44376A
19:29 20:17 31jll 21:43
^^>YVvV*yvv^rV>'~V^*('Y^^*V^(**'Vw>s'^^
19:00 20:00 21:00 22:00
2J:00 24:00 25:00
SJfi 70P
"W- VY-— v% ^v ^^wv^v^^
2J>00 '' 24:00 25:00
-1 . $£4
-.1.3X4
'-.9.9X3
'-.6.6X3
-.3.3X3
•o.oxo
Time
-1 . 8X6
.1.5X6
.1.1X6
.7.4X5
LJ.7I5
O.OEO
Time
_9.2rJ
:7.4t3
L5.5EJ
.3.7X3
.1.8X3
0.0X0
Time
-2.1X6
.1 . 7X6
.1.3X6
.8.4X5
-4.2X5
0.0X0
Tiae
.1.5X7
.1.2X7
.8.7X6
-5.8X6
.2.9X6
0.0X0
Tiae
.1.3X7
.1.0X7
.7.9X6
.5.2X6
.2.6X6
0.0X0
Time
69
-------
Channel I 338.3792 Peak top
Height 2,82 volts Span 298 ppi
Systei file naie
Data fiienaie
Resolution
Groupnuiber
lonizatlon lode
Switching
tef, lasses
fl 292.3825 J
B 383.3616 K
C 385.8987 L
D 315.9419 1
E 317.9389
F 319.8965
G 321.8936
H 327.8847
I 338.3792
tef. iass 388.3761 Peak top
Height .94 volts Span 288 ppi
1
D*
mm
388.3761
338.3792
331.3368
333.3338
Xfi.8364
70
-------
TLI Project 44376A
Client Sample: 141-144
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980027
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-10A-D Date Extracted: 12/29/97
Date Analyzed: 01/06/98
1.000 Dilution Factor n/a
n/a Blank File: U980026
DB-5 Analyst: KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7.8-PeCDD
1,2,3.4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1.2J,7,8,9-HxCDD
1,2,3,4.6,7,8-HpCDD
1.2,3,4.6,7,8.9-OCDD
2,3,7.8-TCDF.
1,2,3,7.8-PeCDF
2.3,4,7,8-PeCDF
'.,2,3,4,7,8-HxCDF
1,2^,6,7,8-HxCDF
2,3,4,6,7.8-HxCDF
1,2^,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4.7,8.9-HpCDF
1,2.3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Ait $l& |l! " PL , " SMPC
0.02
0.03
0.02
0.04
EMPC 0.04
0.15
0.24
1.5
0.15
0.22
0.44
0.15
0.20
0.02
0.62
0.08
0.46
Amt (ng) number m. EMPC
2.8 9 2.9
0.47 7 0.85
0.37 5 0.51
OJ1 2
12.8 16
3.7 13 3.7
1.8 11 1.9
0.98 4
Ratto
0.73
1.32
1.09
1.31
1.17
0.84
0.75
1.60
1.57
1.23
1.33
1.20
1.05
1.02
1.03
0.93
RT
25:21
29:37
32:45
32:49
36:03
39:36
24:41
28:35
29:17
32:02
32:09
32:37
33:22
35:01
36:33
39:49
Flags
PRJ
J_
J_
J_
J_
iZ
PRJ
J_
Flags
—
Page 1 of 2
MTT2.PSR v1.01. LAJtS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
71
-------
TLI Project: 44376A
Client Sample: 141-144
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980027
.
Uiv*xi*Br j^c*nnflnn!!t
•«.***•* • ITJB. 'W^««*» •^•••K »U ..,••, \ fff ff f
13C1r2,3.7,8-TCDF
"Ca-^J.S-TCDD
l3C12-l,2,3,7,8-PeCDF
13C12-U,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13Cl2-lA3,6,7,8-HxCDD
13C,rlA3,4,6,7.8-HpCDF
13Clrl.2,3,4,6,7,8-HpCDD
I3C I2- 1 A3 ,4,6,7,8 ,9-OCDD
Surrogate Standards (type A)
13C12-2^,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13C,2-U,3,4,7,8-HxCDD
I3C,2-U,3,4,7,8,9-HpCDF
Surrogate Standards {Type A)
37CU-2,3,7,8-TCDD
Alternate Standards (Type A)
13C,2-U,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13Ci2-lA3,4-TCDD
13C,2-lA3,7,8,9-HxCDD
" fnfA ~" '
-^/wH^lPSl ,,^V
2.6
2.6
2.8
2.7
2.8
3^
2.9
3.0
53
AIJ& ^ng) -
3.6
3.9
3.6
3.4
AmfcSfigJ ;
3.4
, Ana. (fig) t
2.9
2.9
•• '- •;,,
'v"rf ^ffecovwy
64.4
64.1
69.9
66.9
70.9
80.0
73.3
75.4
66.1
% Recovery
89.0
98.1
90.8
84.9
%Recwery
84.8
'% Recovery
73.2
73.1
' •"<
,vv^* •„
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%- 130%
-
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
Ba*tn.
, 0,**»& ,
0.75
0.81
1.50
1.46
0.51
1.20
0.44
1.05
0.87
Ratio
1.50
0.51
1.21
0.44
Ratio
0.50
0.51
Ratio
0.82
1.21
»,«,*" *,"
24:38
25:21
28:34
29:36
32:09
32:48
35:00
36:03
39:36
RT
29:16
32:02
32:44
36:32
RT
.25:22
RT
33:23
32:37
RT
25:10
33:07
- ,rja^ „
FJags
—
Flags
—
Flags
—
Flags
Data Reviewer
01/10/98
Page 2 of 2
Mm.PSR v 1.01. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98 ^
i
-------
Data Review By.
Initial
_o
.Date.
Calculated Moise Area:
The Total Area for each peak with an ion abundance ratio outside
Iratio limits has been recalculated according to method requirements.
3.00
Page No.
01/10/98
Listing of O980027B.dbf
Matched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z.. .. QC.Log Omit Why ..RT. OK Ratio Total.Area... Area. Peak.1. . Area.Peak.2.. Rel.RT Compound.Name. . ID.
Flags.
TCDF
304-306
KN
K
K
K .
K
K
K
304-306
LL3C12-TCDF
J.16-318
316-318
TCDD
320-322 .
KN
KN
K
K
M
AN
D
DC NL 0
21
22
22
22
22
23
23
23
24
24
24
24
25
25
25
26
0
:00
:30
:01
:14
:38
:57
:21
:.37
:56
:04
:14
:29
:41
:05
:17
:33
:23
.65-0.89
0.81
0.77
0.74
0.76
0.74
0.74
0.73
0.73
0.73
0.75
0.72
0.75
0.75
0.72
0.73
0.70
0.78
16 Peaks
DC NL 0:
DC ML 22:
DC WL 23 :
24:
24:
25:
0.
:00 RO
26 RO
01
13 RO
38
04 RO
3 Peaks
DC NL 0:
22:
23:
23:
24:
24:
24:
25:
25:
25:
25:
D SN 25 :
0.
00 RO
49
13
30
12
26
51
14
21
32 RO
42
53 RO
.65-0.89
1.19
1.43
0.36
0.37
0.75
0.26
0.867
125
3,102
2,589
1,998
12,407
7,660
7,082
4,393
5,303
8,779
2,545
2,597
7,981
1,704
1,460
317
207
70,131.
.83
.66
.17
.81
.67
.13
.06
.62
.84
.06
.21
.34
.71
.17
.68
.56
.51
.20
-1.079
0.000
1,347.18
1,104.95
861.72
5,263.06
3,264.01
2,977.47
1,849.50
2,233.61
3,757.28
1,062.80
1,110.82
3,408.46
714.97
617.82
130.77
91.01
1,755
1,484
1,137
7,144
4,396
4,104
2,544
3, 070
5,021
1,482
1,486
4,573
989
842
186
116
.48
.22
.09
.61
.12
.59
.12
.23
.78
.41
.52
.25
.20
.36
.79
.50
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
0.959
16.
13.
41.
72.
17,628.
69.
21
33
84
55
79
83
17,771.17
65-0.89
0.38
0.78
0.78
0.70
0.76
0.75
0.82
0.77
0.73
0.60
0.80
1.10
9.
5,487.
3,130.
336.
951.
517.
218.
939.
65.
86.
96.
27.
24
47
87
73
42
65
99
00
50
11
75
05
31.56
7,570.49
30.38
Vr+ 1 1 nua - - —
2,412.32
1,369.82
138.81
411.12
221.37
98.44
408.00
27.60
37.46
43.10
85.
10,058.
117.
.62
.30
.68
0
0
0
0
1
1
.873
.894
.903
.919
.932
.948
.959
.972
.977
.984
.994
,002 2378-TCDF AN
.018
.026
.037
.071
-1.041
.000
.911
.934
.983
.000 13C12-2378-TCDF ISO
.018
J
0.895-1.047
3,075.
1,761.
197.
540.
296.
120.
531.
37.
62.
53.
15
05
92
30
28
55
00
90
79
65
0
0
0
.000
.900
.916
0.927
0.955
0.964
0.980
J
0.995
1.000 2378 -TCDD AN
1.
1.
1.
007
014
021
PRJ
J
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
t
-------
Page No.
01/10/98
Listing of CJ980027B.dbf
Matched GC Peaks / Ratio / Ret. Tine
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
D
D
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
D
D
D
D
M
AN
D
340-342
13C12- PeCDF
352-354
D SN 26:09 RO 1
D SN 26 : 21 RO 1
10 Peaks
DC NL 0:00
DC WL 22:50
DC WL • 22:59
DC WL 23:07
24:00
24:13
24:41
25:22
25:45
5 Peaks
0.65
DC NL 0
25
25
25
:00
:10
:21
:41
RO 2
0
0
0
3 Peaks
.84
.00
-0.89
.88
.82
.81
.89
9
27
11,830
7
33
8
204
1,668
41
11
11,362
482
13,566
18
18,667
13,386
380
.77
.24
.49
.49
.91
.84
.08
.99
.00
.17
.90
.43
.49
.25
.15
.86
.66
32,434.67
1.32-1.78
DC NL 0
26
D SN 26
D SN 26
D SN 27
D SN 27:
D .SN 27:
27:
27:
27:
28:
28:
28:
28:
28:
28:
29:
29:
29:
D SN 30:
30:
:00
:36
:52
:56
:04
:14
:21
:36
:43
:53
12
18
30
35
45
52
17
25
45
01
15
RO 0.
1,
RO 0,
RO 1.
RO 0.
1.
1.
1.
1.
1.
"l.
1.
1.
1.
1.
1.
1.
1.
1.
RO 0.
RO 1.
.80
.49
,43
,81
.78
57
74
54
52
56
52
47
54
60
50
53
57
45
32
63
15
14 Peaks
DC NL 0:
27:
00
44
1.32-
RO 2.
.1.
1.78
20
57
6.
1,836.
18.
30.
21.
30.
29.
562.
3,502.
805.
1,116.
1,629.
716.
579.
518.
844.
821.
1,071.
205.
22.
87.
14,297.
.12
.97
72
98
68
62
31
S5
29
11
79
08
00
00
48
84
24
84
97
80
26
42
1,668
41
11
11,362
482
8,431
6,010
179
.99
.00
.17
.90
.43
.25
.87
.02
10,235
7,375
201
0.
0.
.90
.99
.64
1.032
1.039
921-1.079
0.000
0.901
0.907
0.912
0.947
0.955
0.974
1.001 37C1-TCDD CLS
1.016
921-1.079
0.000
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
PeCDF Fa 1 1 awn ————————
1,099.
340.
2,114.
490.
673.
969.
434.
356.
311.
510.
501.
635.
117.
53.
,71
72
09
52
40
35
00
00
36
75
37
13
07
04
737
221.
1,388.
314.
443.
659.
282.
223.
207.
334.
319.
436.
88.
46.
0.
.26
,83
20
59
39
73
00
00
12
09
87
71
90
28
925-1.065
0.000
0.931
0.940
0.943
0.947
0.953
0.957
0.966
0.970
0.976
0.987
0.991
0.998
1.001 12378-PeCDF AN
1.006
1.011
1.025 23478- PeCDF AN
1.030
1.041 J
1.051
1.059 J
0.860-1.140
2.
70.
37
25
42.
94
27.
31
0.000
0.971
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
74
-------
Page No.
01/10/98
Listing of CJ980027B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak . 1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
352-354
PeCDD
356-358
D •
D
356-358
13C12- PeCDD
368-370
368-370
HxCDF
374-376
28:34
28:51
29:01
29:16
29:45
29:56
7 Peaks
DC NL 0:00
27:49
D SN 28:05
28:18
28:33
28:41
28:53
D SN 29:02
29:07
29:19
29:27
29:37
29:45
DC SN 29:59
30:05
DC SN 30:17
DC SN 30:21
11 Peaks
DC NL 0:00
27:42
DC SN 28:33
29:36.
29:44
29:56
30:05
30:15
DC SN 30:28
6 Peaks
DC NL 0:00
31:05
31:14
31:23
31:31
31:41
32:02
RO
RO
1
RO
RO
RO
1
1
5
1
3
1
.50
.66
.26
.50
.37
.72
14,902.92
274.02
29.20
12,815.90
28.64
25.51
28,146.44
.32-1.78
0
0
0
1
.85
.59
.04
.49
1.54
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
1.
RO
RO
1.
1.
0.
.54
,65
92
2.06
1.
0.
1.
1.
2.
1.
0.
0.
32-
0.
1.
1.
1.
1.
1.
2.
1.
1.
05-
1.
1.
1.
1.
1.
1.
1.
38
66
32
47
39
83
99
24
1.78
81
33
28
46
57
43
30
04
36
1.43
62
23
31
02
26
32
23
3.14
754.32
9.84
53.38
477.26
90.57
285.96
35.17
80.12
130.21
56.36
72.94
47.53
5.23
35.39
3.88
1.23
2, 084 .04
8,950
171
60
7,693
37
16
.65
.03
.28
.92
.85
.14
5,952.27 1
102.99
11.45
5,121.98
11.23
9.37
1
1
1
1
1
.000 13C12-PeCDF
.010
.016
.025 13C12-PCCDF
.041
.048
123 IS2
234 SOR1
458
31
289
54
178
64
75
34
41
28
.51
.98
.19
.90
.09
.78
.60
.26
.51
.31
25.43
0.
779.27
21.40
188.07
35.67
107.87
31.42
54.61
51.90
31.43
19.22
13.88
935
0
0
0
0
0
0
0
0
0
-1.022
.000
.940
.949
.956
.965
.969
.976
.981
.984
0.990
0.995
1.001 12378- PeCDD
1.
1.
1,
1.
1.
.005
.013
.016
,023
.025
J
J
J
J
J
AM J
J
J
0.865-1.135
0.63
37.28
5.63
7,368.03
1, 073.94
83.42
23.92
18.75
8.04
8, 605.34
21.
4,375.
655.
49.
21.
11.
30
81
84
14
57
40
15.98
2,992.22
418.10
34.28
9.38
10.93
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
936
965
000 13C12-PeCDD
005
Oil
016
022
029
123 IS3
PeCDD / njii»ur TOJ..I.OWS --•
21.97
625.75
1,369.52
98.58
166.25
88.38
1,154.34
344.
776.
54.
92.
50.
637.
90
48
57
60
29
82
0.962-
280.85
593.04
53.46
73.65
38.09
516.52
0.
0.
0.
0.
0.
0.
0.
1.047
000
967
971
976
980
985
996 123478-HxCDF
J
J
J
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Property Cf
EPA [" .?
RTP ICJ L. - 11
Printed: 10:1601/10/98
-------
Page No. 4
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of CJ980027B.dbf
Matched GC Peaks / Ratio / Ret. Tine
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
AN
M
374-376
13C12-HxCDF
384-386
384-386
HxCDD
390-392
32
32
32
32
33
33
:09
:15
:26
:37
:22
:28
1.33
1.35
1.21
1.20
1.05
1.33
12 Peaks
DC NL 0
31
32
32
32
33
33
33
:00
:04
:02
:09
:37
:OS
:14
:23
0
RO
RO
RO
7 Peaks
DC NL 0:00
31:
32:
34
:01
32:13
1,
RO
RO
32:22
DC SN 32:37
390-392
13C12- HxCDD
402-404
402-404
HpCDF
408-410
D
32:
32:
33:
DC SN 33:
45
49
07
26
RO
RO
RO
.43-0.59
0.88
0.44
0.51
0.51
0.51
0.26
1.56
0.50
495.90
129.03
197.98
506.44
34.10
117.30
4,983.57
282
74
108
275
17
67
.71
.05
.59
.86
.50
.00
213
54
89
230
16
50
.19
.98
.39
.58
.60
.30
1.000 123678-HxCDF AN
1.003
1.009
1.015 234678-HxCDF AN
1.038 123789-HxCDF AN
1.041
J
J
PRJ
J
0.876-1.124
5.84
20.73
8,412.04
10,390.38
9,665.99
27.92
6.51
7,458.64
35,982.21
.05-1.43
0.70
1.22
1.22
1.48
1.37
4.95
1.09
1.31
1.50
1.71
7 Peaks
DC NL 0:
32:
32:
32:
33:
00
13
44
48
07
1.
RO
RO
4 Peaks
DC NL 0:
35:
35:
35:
D SN 35:
DC SN 35:
DC SN 35:
00
01
18
26
40
46
59
0.
RO
RO
RO
RO
05-1.43
1.60
1.02
1.21
1.20
1.21
88-1.20
1.38
1.02
1.01
1.11
0.54
2.70
1.70
6.97
90.71
478.41
197.79
30.51
4.48
31.21
77.92
86.24
5.53
992.79
6
2,835
3,516
3,266
9
6
2,493
.30
.75
.05
.71
.43
.73
.12
14
5,576
6,874
6,399
36
4
4,965
.43
.29
.33
.28
.73
.31
.52
0.000
0.966
0.996 13C12-HXCDF 478 SOR2
1.000 13C12-HXCDF 678 IS4
1.015 13C12-HXCDF 234 ALT2
1.029
1.034
1.038 13C12-HXCDF 789 ALT1
49.89
263.12
131.09
17.65
16.
44.
57.
31
17
63
40,
0.958-1.014
,82
215.29
88.30
12.86
14.
33.
38.
90
75
50
0.000
0.962
0.976
0.982
0.987
0.994
0.998 123478-HxCDD AN
1.001 123678-HxCDD AN
1.010 123789-HxCDD AN
1.019
J
J
J
J
J
0.970-1.030
7.68
18.82
5,765.04
8,672.25
10,895.05
25,351.16
10.
3,158.
4,729.
5,960.
42
14
10
87
10.
2,606.
3,943.
4,934.
18
90
15
18
0.000
0.982
0.998 13C12-HXCDD 478 SDR3
1.000 13C12-HXCDD 678 IS5
1.010 13C12-HXCDD 789 RS2
7.38
1,443.50
273.19
304.94
9.96
4.45
6.63
727.
136.
160.
74
99
71
715.
136.
144.
0.996-1.049
76
20
23
0.000
1.000 1234678-HpCDF AN
1.009
1.012
1.019
1.022
1.028
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
-------
Page No.
01/10/98
Listing of CJ980027B.dbf
Matched GC Peaks / Ratio / Ret..Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
36
DC SN 36
DC SN 36
:33
:46
:55
1.
RO 0.
RO 0.
03
55
48
4 Peaka
DC NL 0
35
36
:00
:00
:32
0.37-
RO 0.
0.
0.
2 Peaka
DC NL 0:
35:
36:
00
17
03
0.88-
RO 0.
1.
1.
0.51
66
44
44
1.20
02
13
17
136
5
2
2,157
10
6,563
4,469.
11,032.
. npv^JJi
0.
229.
225.
.05 69.11
.02
.49
.68
.79
.47 2,002.40
.51 1,370.05
.98
/Ur^*nn Vf\ l i f\uo - _
06
68 121.98
52 121.39
66.94
0.
4,561.07
3,099.46
1.
1.
1.
943-
0.
.044
050
055
1234789-HpCDF
AN
1.114
000
1.000
1.
0.975-
107.70
104 . 13
0.
0.
1.
044
13C12-HpCDF 678
13C12-HpCDF 789
IS6
SOH4
1.005
000
979
000
1234678-HpCDD
AN
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
2 Peaks
455.20
0.88-1.20
0.972-1.028
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
1
NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
1
0
36
:00
:03
1
1
Peak
0
34
34
35
35
36
36;
37:
37:
38:
38:
39:
40:
40:
40:
40:
40:
:00
:22
:31
:44
:53
:17
:40
:07
:57
:08
:32
:49
04
13
20
26
37
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.02
.05
.76-1.02
0.
0.
1.
1.
1.
0.
0.
0.
0.
0.
1.
0.
0.
0.
2.
1.
1.
.98
,22
.31
82
12
35
14
59
47
71
05
93
76
77
35
18
36
Peaks
0:
39:
39:
39:
00
36
52
57
0.
RO
RO
RO
76-
1.
0.
0.
4.
1.02
20
84
43
08
Peak
13
5,964
.88
.62 3,054.56
5,964.62
; HpCDD / Octa*CDD clod CDF
3
1
2
1
1
1
o
1.
6,
2.
3.
614.
16.
a.
1.
3.
3.
630.
.07
.19
.34
.78
.98
.00
.59
.87
,77
.36
.04
76 295.87
14 6.98
60
95
76
67
90
0
2,910.06 1
0.899
0
0
0
0
0
0
0
0
0
0
0
318.89 1
9.16 1
1
1,
1.
1.
.000
.000 13C1
-1.101
.000
.868
.872
.902
.906
.916
.926
.937
.958
.963
.973
.005 OCDF
.012
.016
.019
.021
.026
0.899-1.101
0.
260.
3.
2.
260.
09
87 119.05
82
17
87
0.
000
141.82 1.000 OCDD
1.
1.
007
009
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1601/10/98
*• 7
-------
Page No.
01/10/98
Listing of 0980027B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why .:RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpoand.Name.. 10.. Flags.
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 39.25 0.08
39:36 0.87 7,849.13
470-472 1 Peak 7,849.13
3,641.39
0.996-1.004
0.000
4,207.74 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_2 -Nominal Ion Masa(es)
..RT. -Retention Time (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
•«« End of Report •»•
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
Ol-Below Method Detection Limit
HL-Channel Specific Noise Level
A-Peak Added
K-Peak Kept
D-Peak Deleted . ,
T-Time Changed
M-Peak Area Changed
N-Name Changed
X-Ether Interference
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/10/98
-------
rile:U980027 tl-724 Acq: 6-JAN-199B 18:07:52 SC XI+ Voltage SIS 70S Itoiaai 23116
303.9016 F:2 BSUB(2S6 ,30, -3.0) ?TD(9, 5,3, 0.10\,112464.0,1.00\,T,T) XxptODBSUS
TRIANGLE LASS Text:tlit44376a HIT nriWF \^\— |HM
1001
80.
SO.
40.
20.
J15.
AA1.10I7
. AA /
• • • i * ' '
*5jCS*T P AA 1 J 4 1 T V «J •
26E7 t/W ifll /O
i
A3. 26X7 A1.8SE7
\ Si ft k
V\A/lrl
SS7 A3.41E7
fl
A A I 1 A7.1SE6
Will A/w
23': 00 34:00 25\00 26:00
_7.5r5
:5.1£6
:4.ffr5
.J.1E5
.1.515
Tile:U980027 tl-724 Acq: 6-JXS-199B 18t07t52 SC XI* Voltage SIS 70S Bo±ae:34800
305.8987 T:2 BSUB(256r 30, -3.0) PTD(9,5,3,0.10\,139200.0,1.00\,r,X) XxptSDBSUS
TRIANGLE LABS Text:tJJ.t44376a TLI BLAST
1003
80.
60.
40.
20.
o-
A7.
AA1.4BX7
AA /
22: 00
14X7 A5-'
A f
1 At. 40X7 &2. 54X7
\ J\ A A
WAU
2E7 A4.57S7
A
fl
lA^/rFr.
23:00 24:00 25-00 26: 00
_1 . OZ7
-.8.1X6
.6.1X6
.4.1X6
.2.0X6
O.OEO
lime
rile:U980027 tl-724 Acq: 6-J7UT-1998 18:07:52 SC XI+ Voltage SIS 70S Noiae:S428
315.9419 T:2 BSOB(256, 30, -3.0) PTD(9, 5, 3,0. 101,21712. 0,1.00\,r,T) Xxp:NDB5US
TRIANGLE LASS Text: tli*44375a TLI BLAST
1001
aol
sol
401
o:
'22:00'
A7.S7E7 1.8X7
1
11
23:00 24:00 ' ' ' '.25:00 25:00
'.1.5X7
.1.1X7
.7.3X6
.3.7X6
0.0X0
rile:U9a0027 tl-724 Acq: 6-JXN-1998 18:07:52 SC EH- Voltage SIS 70S Noiae:457B
317.9389 F:2 BSUB(356, 30, -3.0) PXD(9,5,3,0.10\,18312.0,1.00\,r,T) Exp:NDB5US
TRIANGLE LASS Text:tli.t44376a TLI BLAST
1001
aol
sol
40l
201
Q-
'22^00'
Al.Oira 2.4E7
i
11
2J.-00 24lflO 25:00 25:00
fila:U980027 tl-724 Acq: 6-JXK-1998 18:07:52 SC EH-
330.9792 T:2 Ezp:NDB5US
TRIANGLE LASS Tejrt:tlit44376a TLI BLAST
1004
80.
60.
40:
201
o:
21s 29 31:53 J^-8 33'33 ":53
""^^^ " » "' ' '* *^* *" «*• W "
22:00
-1.9E7
.1.5X7
-9.7X6
-4.9X6
0.0X0
Time
Voltage SIS 70S
24:33 25:09 25:42 26^0526:24
-J--T ^>- «w • 'M^iMy r- - — V'I*M ~ — "-
23:00 24:00 25^00 25:00
rile:O9a0027 tl-724 Acq: 6 -JAN- 19 9 8 18:07:52 SC EH-
375.8364 Ts2 ExpiNDBSUS
TRIANGLE LABS Text:tlit44376a TLI BLAST
1001
aol
601
40:
-7.9X7
.5.9X7
-3.9X7
.2.0X7
0.0X0
Tdae
Voltage 5J£ 705
26:02 4.7E4
i
24,44 V .^.'^
20' 21:49 22:301 24:00 1 • 25:36 f\ » 1 |A II
22:00
2J:00 24.-00 25:00 25:00
.3.8X4
.2.8X4
.1.9X4
.9.4X3
0.0X0
T±ae
79
-------
rila:D9B0027 tl-724 Acq: 6-JAK-1998 18:07:52 GC EH- Voltage SIS 70S Noiae:2012
319.8965 f:2 BSUB(256,30,-3.0) PXS( 7,5,3,0.10\,8048. 0,1 .00\,T,S) Xxp:XDB5US
TSIANSLX LABS Texts tlit44376a TLI BLAST
100:
80.
60.
40.
20.
0.
W2.4 X7
A1.37X7
A
A
/ \ a4.iuw
/ V / \A1.39X6 /\A2.21X6 U^\.
23:00 ' ' ' 24:00 ' .25:00
-5.2X6
?5
L4.3X5
.3.1X6
.2.1X6
.1 . 0X6
26\00 Time
Tile:U980027 tl-724 Acq: 6- JAW- 1998 18:07:52 GC XI* Voltage SIS 70S Soiam:5307
321.8936 t:2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,21228.0,1.00\,r,T) Kxp:SDB5US
XSIABGLX LABS Tezt:tlit44376a TLI BLAST
100]
80.
60.
40.
20.
0
A3. 08X7
ft
I 1 Al. 76X7
1 \ A
A
-.6.8X6
1 1 I \ "r?*L.,,K "•>!"
J \- 1 V ^>-«^ / V _<-^^ ^N. ^S~*\_
23:00 24:00 ' 25:00 '
.5.4X6
.4.1X6
.2. 7X6
.1.4X6
0.0X0
26':00 Tiae
File :O9 800 27 tl-724 Acqs 6-JAS-1998 18:07:52 GC 11+ Voltage SIS 70S Soiae:14867
331.9368 T:2 3SO3(256,30,-3.0) PTD(7,S,3,0.10\,59468.0,1.00\,T,T) Xxp:XDB5US
TRIANGLE LABS Text:tlit44376a TLI BLAST
1003
80:
'
50:
40:
ao:
0:
AS. 43X7
([
-.2.2X7
H5.01iT7
f /
/ \J
33:00 ' ' ' ' 24:00 ' 25:00 '
\
\
V
'-.1.8E7
.1.3X7
.8.8X6
.4.4E6
35:00 Mae
rile:O980027 tl-724 Acq: 6-JXK-1998 18:07:52 GC EH- Voltage SIS 70S lToiae:5153
333.9338 f:2 BSUB(256,30,-3.0) PTD( 7,5, 3,0. 101,20612. 0,1.00\,r,T) Xxp:SDB5US
TRIANGLE LABS Tert:tlit44376a TLI BLAST
1001
80:
50:
40:
30J
0:
A1.02X8
(l
-.2.6X7
K7.38E7
1 f
/ \J
23\00 24:00 25:00 '
\
V r
.2.1E7
-1 . 6E7
-1.1X7
-5.3X6
0.0X0
26:00 Time
Tlle:U980027 tl-724 Acq: 6-JAN-1998 18:07:52 GC XI+ Voltage SIS 70S SOiae:3744
327.8847 Ts2 BSUB(256, 30, -3.0) PTD(7, 5, 3,0. 101,14976. 0,1.00\,f,T) ExptNDBSUS
TRIANGLE LABS Teit:tl±t44376a TLI BLAST
1003
80:
60-
40J
201
oj
Al.
A1.67X7
/V /
23\00 24:00 25:00
4X8 2.8X7
V
'-2.2X7
'.1 . 7X7
U..1X7
Is. 5X6
'• o.oxo
26:00 Mae
Tile,OS80027 tl-724 Acq: 6-J3UT-1998 18:07:52 GC EH- Voltage SIS 70S
330.9792 r:2 SxpiKDBSUS • -•
TRIANGLE LABS Textstl±t44376» TLI BLAST
1001
80:
50:
40:
20:.
oj
23:16 23^3ta 23:53 24:33 25:09
23\00 ' ' 24:00 25:00
25:42 26j05 26:24 ^-9.8X7
.7.9X7
.5.9X7
.3.9X7
.2.0X7
0.0X0
26:00 Tiae
-------
Tila:U980027 #1-724 Acq: 6-J7tS-1998 18:07:52 GC XI+ Voltage SIS 70S Noia«:1862
339.8597 T:2 BSOB(2S6,30,-3 .0) PKD(7,5,3,0 .10\,7448.0,1.QO\,T,T) Xxp:NDB5DS
TRIANGLE LASS Text:tlit44376a TLI SLANT
100J
80.
50.
40.
20.
0
A2.1ir7
A
A
A1.10E7 I
A j A9.69E6
A
-5.1Z5
. /\A8.J5r5A5.11Z5 A6.3SX6
A/IA^VVI/VVAA A/W*« .
27:00 28tOO
.4.1Z5
.J.1B5
.2 . 1X6
.1 . 0X6
0.0X0
2$ioO JO: 00 T±me
F±le:O980027 #1-724 Acq: 6-JUT-1998 18:07:52 GC EI+ Voltage SIS 70S Soiao:2313
341.8567 It2 BSUB<256, 30, -3.0) PXD(7,5,3,0.10\,9252.0,1.00\rT,T) ExptSDSSUS
TRIANGLE LABS Text; tii#44J7S« TLI SLANT
100J
80:
50.
40:
20:
a-
A1.39X7
ft
A7.J7r5
A| A6.60X6
t\A5 5J
A/IAJVIA
27:00 28:00
T±lesO980027 #1-724 Acq: 6-J7UT-199S 18:07:52 GC EH-
351.9000 T:2 BSVB(256, 30, -3.0) PKD(7,5,3,0.10\,4092
TRIANGLE LABS Tezt:Cll#44J75a TLI SLANT
1001
80:
50:
40.
20:
Ad
.
27:00 ' 28:00
f±loiU980027 #1-724 Acq: 6-JAS-1998 18:07:52 GC EH-
353.8970 T»2 BSUB(256, 30, -3.0) PKD(7,5, 3, 0.101,1852
TRIANGLE LASS Text:tl±#44376a TLI BLANK
1001
80:
so:
40:
20:
o:
AS.
,
.
/
27:00 28:00
rileiU980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EH-
330.9792 r:2 XxpiNDBSOS
TRIANGLE LABS Text:tl±t44376a TLI BLANK
1003i
80:
50:
40:
20:
oj
25:48 27:17 27:4538:01 28:25
-.3.3X6
37X6
VwV A/V *°-j!>*5
'-.2.6X6
'•.2.0X6
-.1.3X6
-.6.5X5
• 0 . OEO
29:00 30:00 Time
Voltage SIS 70S Noiae:1023
.0,1.00\,r,T) Exp:NDB5US
5X7 -2.4X7
A7.69E7
\
v_
'.1.9X7
'-.1.4X7
.9 . 6X6
.4.8X6
23:00 ' ' ' JO: 00 ' T±me
Voltage SIS 70S Noiae:463
.0,1.00\,T,T) Exp-.NDBSUS
tff 1 . 6X7
AS. 12X7
1
v^
.1.3X7
.9 . 8X6
.6.5X6
.3.3X6
O.OEO
29:00 30:00 Time
Voltage SIS 70S
28:43 29:06 29:42 30^19 30:37^9.9X7
27:00 28iOO ' ' '
fllet0980027 #1-724 Acq: 6 -JAN- 19 9 8 18:07:52 GC EH-
409.7974 n2 ExptNDBSUS
TRIANGLE LABS Tert:tU.t44376a TLI BLANK
1001
80:
50:
40:
20:
0:
27:13
1
25, 38 37'°\
.7.9X7
.6.0X7
.4.0X7
.2.0X7
0.0X0
29\00 JO: 00 ' Mae
Voltage SIR 70S
- -• - - -- ...
JO 00 J.2Z4
25:15 I) i 30:20
1 1 1 27- 31 37:59 28*33
jjlli IL 1 1 \ k j?7*5fAi M A n III
IVJiVVAJjuJ wMl/UA-A/VJWVAtA/nAAJV Wu r
27:00 28:00
25:05
WlJMJiUi
1 1
111 , 1
111 Mil 1 fl 30,35
i II |25:J7 1 » Jj| Jl 1 1 .
Jl/iwrV/Uv/UllI Wr r^ WJuA
-.2.5X4
.1.9X4
.1 . 3X4
.6.4X3
o.oxo
25:00 JO: 00 Mae
81
-------
rue:(79800.27 tl-724 Acq: 6-JAN-199S 18:07:52 GC £I> Voltage SIS 70S NOJ.se:955
355.8546 f:2 BSUB(256, 30, -3. 0) PXS(5,5,3r0.05\,3B20.0,1.00\rT,T) XxpsNDBSUS
TSIAOSLX LABS Text:tlit44376a TLI BLANK
100^ A4.59X6
' 27\4a' '2aVoO 28:12 28:24 28t36 28t48 29tOO 29:12' '29\24 ' 29*: 36' 29': 4 a' 30: 00 ' 3oVl2 ' 30': 24 '
rile:U980027 tl-724 Acq: 6-JAN-1998 18:07:52 SC XH- Voltage SIS 70S Noiaet 1126
357.8516 r:2 BSUB(256,30, -3.0) PKD(S,5,3,0.05\r4S04.0,1.00\,r,T) Xxp:NBBSUS
TSIANSLX LABS Text:tl±t44376a TLI BLANK
1001 A7.79X6
80.
601
401
201
0.
A1.38E6
A
v
A
**-
*5-"™
A3.14S5
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rlle:U980027 tl-724 Acq: 6-JZN-199S 18:07:52 SC XI+ Voltage SIS 70S Noise: 192
367.8949 T:2 BSUB(256,30, -3.0) PKD(5,St3,O.QS\r768.0r1.0Q\,T,T) Xxp:NDB5US
TRIANGLE LABS Text: tl±f 44376* TLI BLANK
1001 A4.38E7
80.
601
401
201
01
.56E6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
r±le:O980027 tl-724 Acq: 6-JAN-1998 18:07:52 SC XH- Voltage SIS 70S Noise:333
369.8919 T:2 BSOB(256,30, -3.0) PKD(SrS,3,0.05\,932.0,1.00\,r,T) ExpiNDBSUS
TSIANGLX LABS Text:tlit44376a TLI BLANK
1001
80.
601
401
201
0'
A2.99E7
4.18X6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rila:U980027 tl-724 Acq: 6-J3UT-1998 18:07:52 SC XH- Voltage SIS 70S
330.9792 Ti2 Exp:KDB5US
HIANSLX LABS Teitttlit44376a TLI BLANK
1004
80.
60.
40.
20.
0.
27:46 38:01
29t06
29:29 29:42
30:07
-1.2X6
0.0X0
Hm<
-1.9E6
.1. 6X6
.1.2X6
.7.8X5
.3.9E5
0.0X0
Time
1.3X7
11. OE7
.7.7X6
'.5.1E6
.2.6X6
.O.OEO
Time
-9.1E6
'.7.3X6
'.5.5X6
.3.6X6
.1. 8X6
0.0X0
Tine
-9.9X7
.7.9X7
.6.0X7
.4.0X7
.2.0X7
0.0X0
Time
-------
Tila:D980027 tl-384 Acq: 6-JAN-1998 18:07:52 SC XI+ Voltage SIS 703 Noise17945
373.8308 T:3 3303(256,30, -3. 0) PXD(7,5,3,0.10\,31780.0,1.00\,T,T) XxptSDBSUS
TSIANSLE LASS Text.-tli*44376a TLI BLANK
low
80:
60:
40:
20:
A7.76X6
AS.38X6
A3. 4SE\
A9.26XS
A2.76X6
AS.10X5
31:00 31s13 31:24 31:36 31,48 33:00 33:13 33:34 33:36 33:48 33:00 33:12 33:24 33:36 33:48
TiletU980027 tl-384 Acq: 6-JKK-1998 18i07:52 SC XH- Voltage SIX 70S Noise:4906
375.8178 f:3 3303(256,30, -3.0) PKD(7,5, 3, 0.10\, 19624.0,1.00\,T,T) ErptSDBSUS
TS.IANSLX LASS Text:tll*44376a TLI BLANK
100\ AS.93X6
g(H A AS.17X6
60:
40:
20:
A3.31E6
\ A7.37X5
J V-^-v^y^v
A3.31X6
AS.05X5
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rile:U980027 fl-384 Acq: 6-JZN-1998 18:07:52 SC EI+ Voltage SIS 70S Hoiae:1703
383.8639 f:3 BSUB(256,30, -3. 0) PKD(7,5,3,0.10\,6812.0,1.00\,T,T) Xzp:NDB5US
TSIAKSLS LABS Text:tli»44376a TLI BLANK
A3.27X7
80:
60:
40:
20:
0:
A3.49X7
31:00 31:12 31:34 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
T±la:U9B0027 tl-384 Acq: 6-JA1T-1998 18:07:52 SC XI+ Voltage SIS 70S Koiae:1935
385.8610 F:3 BSU3(256,30,-3 .0) PXD(7,5,3, 0.10\, 7740.0,1. 00\,T,T) Xzp:BDB5US
TSIANSLX LASS Taxt:tlit44376a TLI BLANK
1001 A6.87S7 A6.40X7
80:
60:
40:
20:
A4.97X7
31:00 31:13 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
Tlle:0980027 tl-384 Acq: 6-JAN-199S 18:07:52 SC XI + Voltage SIS 70S
392.9760 f:3 Eip:NI>B5aS
TRIANSLE LABS Text:tli#44376a TLI BLANK
1001 31jjj8 31s42 31:58 32:10 32j33 3^50 33:09. 33:3233:43
ao:
60:
40:
20:
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32,36 32:48 33:00 33,12 33:24 33:36 33,48
Tile:U980027 tl-384 Acq: 6-J3UT-1998 18:07,52 SC XH- Voltage SIS 70S
445.7555 r:3 XxptSDBSUS ~ ~ - •• - • -
TSIANSLX LABS Text:tlli44376a TLI BLANK
1001
.2.3X6
.1. 8X6
.1. 4X6
.9.1X5
.4.5X5
.0.0X0
Time
1.8X6
1.4X6
.1.1X6
7.1X5
3.5X5
.0.0X0
Time
9. 4X6
7.5X6
5.7E6
3. BE6
1.9X6
.1. 8X7
.1.5X7
.1.1X7
.7.4X6
.3.7X6
.0.0X0
Time
.4.4X7
3.6X7
.2.7X7
1.8X7
8.9X6
0.0X0
Time
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
-------
Tl±e:U9B0017 tl-384 Acq: 6-JAK-199B 18,07:52 SC SI+ Voltage SIM 70S Hoiaa:1932
389.8156 Ts3 BSOB(256,30,-3.0) rXD(7,5,3,0.lO\,7728.Q,1.00\,T,T) ExptSDSSUS
T&IASGLX LABS Text:tli*44376a TLI BLANK
100\ A3.6316
80.
60.
40.
30.
A4.99X5
A
A1.76X5
A4.42X5
AS.76X5
8.4X5
'.6.7X5
.5.0X5
.3.4X5
'.1.7X5
31:36 31:48 32:00 32:12 32:24 32,36 32:48 33:00 33:12
r±le:O980027 tl-384 Acq: 6-J7OT-1998 18:07:52 GC XH- Voltage SIS 70S Soiae,2759
391.8127 T:3 BSOS(256,30, -3.0) PKD(7 ,5,3 ,0.10\,11036.0,1.00\,T,T) XxpiSDBSOS
TSIANSLX LABS Text:tlit44376a TLI BLANK
100\ A2.15X6
80.
so:
33124
0.0X0
40.
20:
A4.OSES
A
A3.38X5
A1.29X5
A3.85X5
33 36 Time
6.8X5
.5.5X5
.4.1X5
.2.7X5
.1. 4X5
31:36 31:48 32:00 32:12 32,24 32,36 32:48 33:00 33:12
rile:U980027 tl-384 Acq: 6-J7UT-1998 18,07:52 SC XI+ Voltage SIS 70S Soiae:2739
401.8558 T:3 BSDB(256,30, -3.0) PXD(7,S,3,0.10\,10956.0r1.00\,T,T) Sxp-.SDBSUS
TSIANSLZ LABS Text:tli.t44376a TLI BLANK
100$ A5.96E7
A4.73X7
80.
60.
40.
20.
OJ
'31:36 '31:48 ' 32\00 '32:12 32:24 32,36 32:48 33:00 33:12
Tile,US80027 tl-384 Acq: 6-J7UT-1998 18:07:52 SC XH- Voltage SIS 70S Noi8o:1717
403.8529 T:3 BSOS(256,30,-3.0) tKD(7,5,3, 0.10\,686a.O,1.00\tTrT) XxptHDBSUS
TSIXKSLX LABS Teit:tl±#44376a TLI BLANK
100$ A4.93X7
gg, A3.94X7
60.
40.
20.
OJ
''31:36 31:48 32:00 32:12 32:24 32:36 32,48 33:00
rile,O980027 tl-384 Acq: 6-J3UT-1998 18,07,52 SC XI* Voltage SIS 70S
392.9760 r,3 XzptHDBSUS
TRIANGLE LABS Text:tl±t44376a TLI BLANK
1003{ .31:42 31±58 32:1032,17
ao:
60.
40.
20:
33:24
33 36
0.0X0
Time
33:24
33 36
33:12
33124
33 36
33,22 33:32
-4.4X7
.3.5X7
.2.7X7
.1. 8X7
.8.9X6
31:36
31:48
32:00
32:12 32:24 32,36 32,48 33:00 33:12 33:24
33
.0.0X0
36 T±ae
-------
rila:U980027 tl-545 Acq: 6 -JAN- 19 9 8 18:07:52 SC EH- Voltage SIS 70S Noiaa:2496
407.7818 T:4 BSUB(256,30, -3 .0) PKD(7,5,3,0.10\,9984.0,1.00\,f,T) Xxp:KDB5nS
TSIAKGLX LABS Text:tlit44376a TLI BLANK
1003
80.
SO.
40.
20.
A7.28X6
A
\
/ \ Al . 61X6
J ^- .^rV -/ ^ S — ^^
1.9X6
.1.5X6
.1.1X6
.7.4X5
.3.7X5
F J5«00 '' ' 35\12 '' ' 35lt24 35:36 35:48 36:00 36:12 36:24' '36:36 36:48 37': 00 Time
r±le:0980027 tl-545 Acq: 6-J7OT-1998 18:07:52 SC XI+ Voltage SIX 70S Soiae:1811
409.7789 t:4 BSUB(256, 30, -3.0) PKD(7,5,3,0.10\,7244.0,1.00\,r,T) Kxp:SDB5US
TSIANOLX LABS Text:tlit44376a TLI BLANK
1001
80.
60:
40:
20:
A7.16K6
\
A
/ \ A1.36E6
J X /\^_/^^ S*~^
-1.9X6
.1.5X6
.1.1X6
.7.5X5
.3.7X5
0.0X0
35:00 35:12 35:24 35:36 3S':48 36:00 36:12 36:24 36:36 36:48 .37:00 Mae
rile:U980027 tl-545 Acq: 6-JAJT-1998 18:07:52 SC XI+ Voltage SIS 70S Koiae:2459
417.8253 T:4 BSUB(256, 30, -3.0) PKD(7,5,3, 0.10\,9836.0,1.00\,r,T) Xxp:KDB5US
TSIAHSLX LABS Text:tlit44376a TLI BLANK
1001
80:
60:
40:
20:
0:
A2.00X7
A
(1 . A1.37E7
II /N
A
/ V / V
y ^> — / ^ —
4.9X6
.4.0X6
.3.0X6
.2.0X6
.9.9X5
0.0X0
35:00 35\12 35:24 35:36 35^48 36:00 36*112 36\24 36\36 36:48 37:00 Time
rila:O9a0027 tl-545 Acq: 6-JKK-1998 18:07:52 SC XI+ Voltage SIR 70S Noiaa:3744
419.8220 T:4 BSUB(256f 30, -3. 0) PKD(7, 5, 3,0. 101,14976. 0,1.00\,f,T) Xzp:KDB5US
TSIAKGLX LABS Tait:tlli44376a TLI BLANK
1001
80:
60:
40:
20:
o:
A4.56E7
I \ A3. 10X7
1 \ f\
A
/ V / V
/ v — j ^^
-1.1X7
.8.8X6
.6.6X6
.4.4X6
-.2.2X6
' 0 . 0X0
3S\00 35:12 35:24 35:36 35:48 36:00 36\12 36:24 36\36 36:48 37\00 Tlae
r Ha: 09800 27 tl-545 Acq: 6 -JAN- 19 9 8 18:07:52 SC XI+ Voltage SIS 70S
430.9729 T:4 ElptNDBSUS
TSIAKGLX LABS Teit:tlit44376a TLI BLANK
ion
SO:
60:
40:
20:
o:
34:55 35:13 35:27 35:49 36:29 36^39^ _36:50 36:59
"^^
-3.1X7
^.5X7
-1.9X7
J..2X7
.6.2X6
0.0X0
J5iOO 35\12 35\24 35:36 35:48 36:6o' ' ' 36\12 ' '36:24' ' ' 36*:36 ' ' 36\48 'j7»00 Time
r±la:O980027 11-545 Acq: 6 -JAN- 19 9 8 18:07:52 SC XI+ Voltage SIS 70S
479.7165 T:4 Xxp:SDBSBS ......
TSIAKGLX LABS Text :tlit4 4376* TLI BLANK
100]
80:
60:
40:
20:
0:
35 16
M 35:50
1 1 1
js,»7 1 1 ";" | »«,«"!*, i'i" IWf "i" ui"
MMA A jy H . /W AAW TlUk A MT^A MM i!(J\*
.1.8X4
.1.4X4
.1.1X4
.7.2X3
.3.6X3
0.0X6
J5>00 35:12 35:24 35:36 35:48 36:00 36\12 36:24 36\36 36\48 37-00 T±me
-------
File:uyao027 tl-545 Acq: o-JAu-1998 18:07:52 SC XI+ Voltage SIS 70S none114
423.7766 f:4 BSOB(256,30, -3.0) PKD(7,5,3,0.10\,56.0,1.00\rT,T) KxptSDBSUS
TSIAHSLX LABS Taxt:tlit44376a TLI BLANK
100^ A1.22X6
A1.21X6
'.6.1X4
0.0X0
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36',06 36', 12 36\18 36\24 36',30 Tlx
rile:U980027 tl-545 Acq: 6-JAN-1998 18:07:52 SC XI+ Voltage SIS 70S So±fe:847
425.7737 T:4 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,3388.0,1.00\,r,T) XxptSDBSUS
TSIANSLX LABS Text:tlit44376a TLI BLANK
1001 A1.08X6 A1.04X6 ..2.5X5
' 35112' 35':ia' 35s24' J5«JO 35s 36 3Si42 35:48 35t54 36100 36s 06 ' 36-12 ' 36tia'
ttle:O980027 tl-545 Acq: 6 -JAN- 19 98 18:07:52 SC XI+ Voltage SIS 70S Soiae:350Q
435.8169 Ti4 BSUB(256r 30, -3. 0) PXD(7, 5,3,0. 10\,14000. 0,1. 00\,r,T) Sxp:JWB5US
TSJAWSLZ LABS Tart: tli*44376a TLI BLANK
lOOi A3+05X7
80.
60.
40.
20.
0.0X0
36:24 36:30 Time
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06
rl2e:OS80027 tl-545 Acq: 6-JAN-1998 18:07:52 SC EI+ Voltage SIS 70S So±ee,3438
437.8140 T:4 BSUB(256,30, -3.0) PKD(7,5,3, 0.10\,13752.0,1.00\,f,T) ElptNDBSOS
TSIANSLE LABS Tejct:tJJ.t44376a TLI BLANK
1001
80.
60.
40.
20.
35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
r±le:U980027 tl-545 Acq: 6-JAN-1998 18:07:52 SC EI+ Voltage SIS 70S
430.9729 Ti4 XxpiSDBSVS
TSIANSLX LABS Text:tULt44376a TLI BLANK
100JL 35:13 35:27 35:49 ^
•' ^^Xl'^IHI-llli! I .^N,^!!!^^1 ' . ^l»
80.
60.
40.
20.
-3.0X7
.2.4X7
.1.8X7
.1.2X7
.6.1X6
35,12 35,18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
0.0X0
T±a<
o
o
-------
rile:09'80027 tl-545 Acq: S-JJOt-1998 18:07:52 SC EH- Voltage SIS 70S HOiae:762
441.7428 r:4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10\,3048.0,1.00\,r,T) SrptSDBSUS
TRIANGLE LABS Text:tllt44376a TLI BLANK
1001
90.
801
701
sol
sol
401
3ol
20.
101
01
A2.96X6
35,00 36:00 37:00 38:00 39:00
Tile,a980027 tl-545 Acq: 6-JXB-1998 18,07:52 SC XI + Voltage SIS 70S Noiet>:776
443.7399 r,4 BSUB(256r 30, -3. 0) PKD(7,5,3,0.101,3104.0,1.00\,r,T) XxptSDBSVS
TRIABGLX LABS Text:tl±f44376a TLI BLANK
1004 A3.
901
801
701
601
sol
401
30^
201
101
0\, ., .,. '., . -•-,-,- ,—, , ... ., •».., ., ff> „. . ... , , n ... .
40:00
9X6
35:00 36:00 37:00 38,00 39:00 40:00
me:0980027 tl-545 Acq: 6-J7UT-1998 18:07:52 SC SI+ Voltage SIS 70S
430.9729 T:4 Zxp:XDB5US
TRIANGLE LABS Text.;tl±t44376a TLI BLANK
100* 34:50 35:27 36lJ? « 37:27 38:09 3a'*° 39:18 39.40
90l
aol
701
sol
sol
401
301
201
101
0.
35,00 36,00 37:00 38,00
r±le,U980027 H-54S Acq: 6-JZX-1998 18,07:52 SC XH- Voltage SIS 70S
513.6775 r,4 XxptKDBSUS
TRIANGLE LABS Textstlit44376a TLI BLANK
1001
39100
40:00
5.4X5
.4.8X5
.4.3X5
.3.7X5
.3.2X5
.2.7X5
J.1X5
.1.6X5
.1.1X5
.5.4X4
.0.0X0
41.00 Tiae
fS.9XS
'.5.3X5
14. 7X5
'.4.1X5
.3.5X5
.2.9X5
.2.4X5
.1. 8X5
-1.2X5
-5.9X4
0.0X0
41:00 Tine
-3.1X7
''-.2.0X7
'-.2.5X7
-.2.2X7
'-.1.9X7
11.5X7
11.2X7
19.3X6
Is.2X6
-.3.1X6
^ Lo.oro
41.00 Time
J5; 00
3S:00
37:00
3S00
39:00
40:00
41:00 Time
87
-------
\fUesU9u0027 41-545 Acq: S-JZy-199B 18:07:52 SC £1± Voltage six JUa
457.7377 Ti4 BSBB<256,30,-3.0) fKO(7,5,3,0.10\,112.0,1.00\,r,T) SzpiODBSUS
TRIANGLE LASS T*rt:t±it44376m TLI BLANK
100\ A1.19E6
39:30 39': 36 39:42 39:48 39:54
rila:098Q027 tl-545 Acq: 6-JAS-1998 IS,07,52 SC EH- Voltago SIR 70S Noiae.,37
459.7348 T:4 BSUS(256,30,-3.0) TXD(7,5r3t0.10\r10a.Or1.00\,T,I)
TRIANGLE LASS TAZtitHf44376m TLI BLASX
1004 A1.42XS
40tOO
39:30 39:36 39:42 39:48 39:54 40:00
\rile:O980027 tl-545 Acq: 6-JAN-1998 18:07:52 SC EI+ Voltage SIR 70S Noiae:786
469.7779 f:4 BSUB(256,30,-3.0) PXD( 7,5,3, 0.10%, 3144. 0,1. 00\,r,T) Exp:NDB5aS
TRIANGLE LABS Text:tlH44376* TLI BLANK
39:30 39:36 39:42 39:48 39:54
file:O980027 tl-545 Acqs 6-JXB-1998 18t07:52 SC Eli- Voltage SIR 70S Noise-.20
471.7750 F:4 BSVB(256,30, -3.0) fKD(7,5r3, 0.10\,80.0,1. 00\,f,T) EzptODBSUS
TRIANGLE LABS T&rt:tJJ.t44376a TLI BLANK
1004
80J
40:00
39:30 39:36 39i42 39:48 39:54
Tlle:U980027 tl-545 Acq: 6-JJOT-1998 18:07:52 SC EH- Voltage SIS 70S
430.9729 Ti4 ExptSDBSUS
XSIANGLE LABS Ta*t:tlit44376t TLI BLANK
100H _ _ 39jJ5^ 39:48 39:51
40100
aoj
60.
40:
20:
o:
40:06
40
-2.BE5
\-2.2ES
-.1.7E5
[.1.1E5
-5.5E4
.O.OEO
06 Tine
-6.0E6
'.4.8E6
.3. 6E6
'.2.4E6
-1.2E6
O.OEO
40:06 Time!
-6.9E6
'-5.5E6
r4.1E6
-2.7E6
.O.OEO
40:06 Timel
39130
39:36
39142
39:48
39:54
40:00
-3.0E7
L.2.4E7
ti.ar?
-1.2E7
-5.9X6
.O.OEO
40:06 Tlae\
88
-------
CD
OJ
Peak Locate Examination: 6-JAN-1998:18:06 File:U980027
Experiment:NDB5US Function:2 Reference:PFK
-------
o
CO
File:U980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EI+
319.8965 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE
100% A4.
25:48 26:00
Voltage SIR 70S
25:00 25:12 25:24 25:36
File:U980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EI+
321.8936 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC
100% A5.31E6
Voltage SIR 70S
LABORATORIES, INC,
25:00 25tl2 25:24 25:36 25:48 26:00
File:U980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EH- Voltage SIR 70S
331.9368 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
100%, 25; 10
25:21
26:12
26:12
25:00
25:12
25:24
25:36
25:48
26:00
26:12
5.2E5
4.1E5
3.1E5
2.1E5
1.0E5
.O.OEO
Time
.O.OEO
Time
2.2E7
.1.8E7
.1.3E7
.8.8E6
.4.4E6
.O.OEO
Time
-------
ile:U980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:NDB5US
ample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
100%
28:06 28:12 28:18 28:24 28:30 28:36 28:42 28:48
File:U980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
ample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
1004,
28:54
28:06 28:12 28:18 28:24 28:30 28:36 28:42 28:48
File:U980027 #1-724 Acq: 6-JAN-1998 18:07:52 GC El-f Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
lOOi 28;34
80J
60J
40
20^
0
28:54
28:06
i I i i
28:12
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28:18
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28:24 28:30
— i — | — i — r-
28:36
i i i i i i i |—r l
28:42 28:48
28:54
29:00
Time
29:00
Time
_2.4E7
L1.9E7
Ll.4E7
L9.6E6
L4.8E6
29:00
• OEO
Time
-------
File:U980027 #1-384 Acq: 6-JAN-1998 18:07:52 GC EI + Voltage SIR 70S
373.8208 F:3 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
100% A6.70E5
I ' ' '
33:18
i—I 1—I—r-
33:42
33:00 33:06 33:12 33:18 33:24 33:30 33:36
File:U980027 #1-384 Acq: 6-JAN-1998 18:07:52 GC EI+ Voltage SIR 70S
375.8178 F:3 Exp:NDB5US
Sample Text:tli#44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
100* A5.03E5
33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42
File:U980027 Sl-384 Acq: 6-JAN-1998 18:07:52 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:NDB5US
Sample Text:tli«44376a TLI BLANK File Text:TRIANGLE LABORATORIES, INC.
100% 33i23
80 j
60 j
40J
20_
0
33:00
33:06
33:12
33:18
•i **y i—i r-
33:48
33:48
33:24
33:30
33:36
33:42
33:48
2.0E5
1.6E5
1.2E5
8.2E4
4 . 1E4
.O.OEO
Time
1.5E5
1.2E5
8.8E4
5.9E4
2.9E4
.O.OEO
Time
6.0E6
L4.8E6
Z.3.6E6
L2.4E6
11.2E6
.O.OEO
Time
-------
TLI Project
Client Sample:
44376A
141-144
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P980095
Client Project:
Sample Matrix:
TLIID:
Sample Size:
Dry Weight:
GC Column:
Culp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-10A-D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: P980094
DB-225 Analyst: JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
|»^S^v"; '^' V;H
2,3,7,8-TCDF
?toieifialj$^darcf ' :^
13C,r 2,3,7,8-TCDF
^Recovery Staitcfard, \ -— ••
^^1^3,4-TCDD
»thtt 015)V ' ®*~ '- -^ EMPC Ratio
0.27 0.73
fcnt (ng) % Recovery acifcnfts Ralo
3.2 78.9 40%-130% 0.77
r,t s *' '* BStlO
0.82
RT
23:06
RT
23:06
' RT ,
21:55
Flags
B_
Flags
—
Flags
Data Reviewer
01/09/98
Page 1 of 1
C3NF PSR v2.0l. LARS 6. m.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1401/09/98
03
-------
Initial
Date.
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/07/98
Listing of P980095B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306 DC NL 0:00
18:29
18:46
DC SN 18:55
19:
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
20:
21:
DC SN 21 :
21:
21:
21:
22:
22:
22:
22:
23:
23:
23:
23:
24:
25:
00
05
28
36
44
55
01
10
20
29
38
48
11
22
36
43
53
07
21
32
59
06
19
37
44
32
17
0.65-0.89
RO 0.64
0.80
RO 1.51
RO 0.58
RO 1.83
RO 0.97
0.79
0.70
0.76
0.83
0.73
0.77
0.87
0.
81
0.77
0.73
0.
RO 1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
76
07
77
79
74
77
73
78
73
73
75
75
74
78
68
304-306 28 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL 20:
DC WL 21:
23:
DC SN 23 :
DC SN 23 :
DC WH 24:
DC WH 25:
2.55
208.64
5.54
92.
4.
,91
,72
115.
3.
0.792-1.101
0.000
73
13
2.78
2.
,99
13.72
179.35
189.
358.
141.
13.
165.
372.
184.
456.
152.
964.
1.
170.
40.
.158.
174.
38.
176.
134.
86.
148.
164.
125.
71.
12.
4,913.
42
26
48
36
82
82
64
74
00
84
27
81
87
90
91
22
65
51
23
46
74
38
83
37
50
3.
7.
79.
78.
154.
64.
5.
72.
173.
82.
198.
64.
417.
74.
18.
67.
75.
16.
77.
56.
36.
,10
48
17
08
98
08
65
38
19
47
71
30
38
09
09
60
93
12
37
94
31
63.47
70.
53.
31.
5.
56
18
41
02
1.
7.
100.
111.
203.
77.
7.
93.
199.
69
75
18
34
28
40
71
44
63
102.17
258.
87.
547.
96.
22.
91.
98.
22.
99.
77.
49.
84.
94.
72.
40.
7.
0.65-0.89
00
33
36
06
14
44
19
10
RO 1.
RO 0.
RO 0.
0.
RO 1.
RO 0.
RO 0.
RO 0.
IS
37
42
77
09
5«
55
6O
316-318 1 Peak
2.
1.
3.
1,249.
0.
1.
1.
9.
1,249.
30
40
08
63
83
88
56
45
63
543.
79
705.
03
70
46
72
78
30
98
10
28
57
92
99
18
20
42
35
0.300
0.812 J
0.819
0.823 J
0.826
0.843
0.348
0.854
0.862
0.867
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
873
880
887
893
900
917
925
935
940
947
957
968
975
995
000 2378 -TCDF AN
009
022
027
062
095
0.957-1.043
84
0.
0.
0.
1.
1.
1.
1.
1.
000
890
935
000 13C12-2378-TCDF ISO
006
027
053
089
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 02:42 01/07/98
04
-------
Page No.
01/07/98
Listing of P980095B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Nome.. ID.. Flags.
13C12-TCDD
333-334
332-334
DC
DC
DC
DC
DC
DC
HL
SN
WH
WH
WH
WH
4
0:
19:
20:
21:
21:
22:
23:
23:
24:
24:
00
51
30
38
55
40
47
52
16
27
0.
RO
RO
RO
RO
RO
RO
RO
----- AJ
65-0.89
1
2
0
0
0
0
3
0
2
1
.71
.17
.54
.30
.82
.78
.52
.55
.51
.57
Peaks
Above: TCDF / TCDD Follows
1.54
0.92
3.33
827.44
1,141.58
10.38
1.12
1.61
2.11
2.78
1,982.73
1.45
367.56
513.50
4.55
0.908-1.092
0.000
0.918
2.70
459.88
628.08
5.83
0.948
1.000 13C12-2378-TCDD IS1
1.013 13C12-1234-TCDD RSI
1.048
1.099
1.103
1.122
1.130
Column Description 'Why' Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
*•• End of Report •••
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
33*37
Fi±a:P9800S5tl-922 AC(j:7-J3Uf-Ha 00:57:56 Sir Valtaga SIR 70P
303.9016 XzptDB225
XSIASSLX LASS Text:It 1-144 TLH44376A
1001
95.
90.
85.
80.
75.
70.
65.
SO.
55.
50.
45.
40.
35~
JO:
25.
30-
15J
10.
5.
Oj
24:32
-2.1X5
'.2.0X5
':1.9X5
'.1. 8X5
':!. 7X5
.1. 6X5
-.1.5X5
.1.4X5
'.1. 3X5
'.1.2X5
'.1.1X5
.9.6X4
.8.5X4
'•.7.5X4
-.6.4X4
'.S. 3X4
.4.3X4
'.3.2X4
.2.1X4
'•.1.1X4
0.0X0
22:36 32:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24 24:36
r±la:P980095 tl-922 Aotjt7-JZS-98 00:57:56 XH- Voltage SIX 70P
315.9419 Xrp:DB225
TRIANGLE LABS Textsl41-144 TLH44376A
24:48 25:00 25:12 25:24
1001
95.
90.
85.
80.
75.
70.
65.
60.
55.
50.
45:
40.
J5:
30:
25.
20.
IS.
101
5j
23:06
1.5X6
':!. 4X6
.1.4X6
.1.3X6
'•.1.2X6
.1.1X6
.1.1X6
.9. 9X5
.9.2X5
.8.4X5
17.6X5
':6.9X5
.6.1X5
.5.3X5
.4. 6X5
.3.8X5
'-.3.1X5
.2.3X5
-.1.5X5
.7.6X4
'22\36' 221:48 23:00 23:12 23:24 23*36 23:48 24*00 24*12 24*24 24*36 24*48 25*00 25:12 25*24
0.0X0
Time,
o
-------
fHa:P980095 #1-922 Acqi7-JMf-3B 00:57:56 Sir Voltage sis 70P aoiae:557
303.3016 BSUB(256,30r-3.0) PXD( 5,3,1, 0.10\,2238.0,0.00\,r,T) Xxp,DB225
3SIAHSLX LASS Tert:141-144 XLIH4376A
1001 A4.J.7Z6
80.
SO.
40.
20.
A1.55X6 JU..99X6
A1.73X6.
A7.41X5
A7.74X5
A7.06X5
A3.14X5
19100 20:00 21:00 22iOO 23:00 24:00
T±1»,P9B009S tl-922 Acq:7-JJOt-98 00:57:56 £Z> Voltaga SIS 70P XoiBa:865
305.8987 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,3460.0,0.00\,r,T) ExpiDB225
XXIASGLX LASS Tait: 141-144 TLI944376A
100* AS.47X6
25100
19:00 20:00 21:00 22:00 23:00 24:00
r±le:P98009S fl-922 Acq:7-JAlT-98 00:57:56 SH- Voltage SIX 70P lToiae:77S
315.9419 BSUB(256,30,-3.0) PXD(5,3,1, 0.10%,3104.0, 0.00\,T,r) SxptDB225
TSIAXGLE LABS Text: 141-144 TLH44376A
1004 A5.44E6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23:00 24:00
TilatP9B0095 fl-922 A€sqi7-JAS-98 00:57:56 EH- Voltage SIS 70P JToiae>649
317.9389 BSVB(2S6,30,-3.0) PXD(S,3,1, 0.10\,2596.0, 0.00\,r,T) Exp:DB225
TSIASSLS LABS Text! 141-144 TLH44376A
100\ A7 6E6
80.
60.
40.
20:
0.
25:00
19:00 20:00 21:00 22:00 23:00
r±la:P98009S fl-922 Acq:7-JAS-98 00:57156 EH- Voltage SIS 70P
375.8364 Sxp:OB225
TSIAOSU: LABS Teztl 141-144 TLIf44376A
100*18:33
80.
60.
40.
20.
0.
24:00
25:00
6.6X5
'.5.3X5
.4.0X5
.2.7X5
.1.3X5
0.0X0
Tia
A9.93X5
A7.76X5 A9.42E5
-1.5E6
.1.2X6
.9.1E5
'.6.1X5
.3.0E5
0.0X0
TJjae
.1.9E6
1.5X6
1.1X6
7.7X5
3.8X5
0.0X0
Time
"I05 32,5623,24 a4>05
19:00
20,00
21:00
22,00
23,00
24,00
25,00
.2.8X4
.2.2X4
.1.7X4
.1.1X4
.5.5X3
.0.0X0
Time
07
o I
-------
FiJ.*iP9a0095 tl-Ull Acqt7-JAN-9B 00:57:56 SI+ Voltage SIX 70P None 1 4 79
319.8965 BSUB(256,30,-3.0) PXD(5 ,3,1,0. 10\,1916. 0,0 .00\,T,r) XxpsDB225
TRIANGLE LABS Text: 141-144 TLIt44376A
ion
80.
60.
40.
'20.
0
1'
A9.22E5
t
1 1 A1.44X5 A3. 35X5
20*00 21*00 22*00' ' ' ' '23*00 24*00 25
-.5.3X5
.4.2X5
.3.2X5
.2.1X5
J..1XS
1 00 Mae
flle:P9B0095 tl-922 Aeq:7-JJOT-98 00i57i56 XH- Voltage SIB 70P Boisot661
321.8936 BSVB(256t30,-3.0) PKD(5,3,1,0.10\,2644.0,0 .00\,F,r) XxptDB225
TRIANGLE LABS Text: 14 1-144 TUt44376A
100S
80.
60.
40.
20.
0.
A1.21X6
|
1 1 A1.80X5 A2.97X5
1 1 A /v A xv ^^*J\^
20*00 21*00 22*00 23*00 24.-00 25
-6.7X5
.5.3X5
.4.0X5
.2.7X5
.1.3X5
0.0X0
: 00 Mae
T±latP98009S tl-922 Acqi7-J3UT-98 00t57i56 XI+ Voltage SIS 70P Soiaei726
327.8847 BSUB<256, 30, -3. 0) PKD( 5 ,3,1,0.10\,2904 .0,0.00\,T,T) XxptDB225
TRIANGLE LABS Text:141-144 TLH44376A
1001
80.
60.
40.
20.
0.
A7.95X6
A5.06E6
I
T
_^y\_>^ 1 \ / \ y^
20*00 21*00 22*00 ' ' ' '23*00' ' 24*00 25
_2.3r5
.1 . 8X6
.1.4X6
.9.2X5
.4.6X5
0.0X0
00 Mae
rileiP980095 tl-922 Acq:7-JKK-96 00*57*5* XH- Voltage SIX 70P Noise 1 745
331.9368 BSUB(256, 30, -3.0) PKD(5 ,3,1, 0.10\, 2980 .0,0. 00\,T,T) Exp;DB225
TRIANGLE LABS Text: 141-144 TLH44376A
1003
80J
60.
40.
20.
AS. 14X6
*
A3. 68X6 II
1 1 1
H l\
20*00 21*00 22 i 00 23*00 24*00 25i
_1 . 4X6
.1.1X6
.8.5X5
.5.7X5
.2.8X5
0.0X0
00 Mae
File:P9B009S tl-922 Acqt7-JXK-98 00*57*56 EH- Voltage SIX 70P Hoiaei434
333.9338 BSUB(2S6,30, -3.0 ) PJO3( 5,3,1, 0.10\,1736. 0,0. 00\,r,f) XxpiDB225
TRIANGLE LABS Tmxtl 141-144 TLIt44376A
1001
80.
60.
40.
20.
0.
A6.28X6
A
A4.IS0XSJI
l\ l\
20*00 21.-00 22*00 23*00 24*00 25
_1 . 715
.1.4X6
.1 . 0X6
.6.8X5
.3.4X5
0.0X0
00 Mae
-------
rilo:P980095 #1-922 Acq:7-J7UT-98 00:57:56
303.9016 Xxp:DB22S
ZXZAMCLX LABS Taxt:141-144 1XJ#4437S.»
1003
80.
50.
40.
20.
ii
fl
15:44 ^0:38 1
1 20*20 1 1 1
, fl ii fl 1
11 W\LN^\J[ 1 1
19:00 20:00 21:00
rilaiP980095 11-922 Aexj:7-JXH-98 00:57:55
315.5415 Xxp.££225
TSIASSLX LABS Text: 141-144 TLH44376A
1001
80.
SO.
40.
20:
19:00 20:00 21:00
rila:P980095 #1-522 Acq: 7- JAR-98 00:57:56
319.8965 Exp:DB225
TRIANGLE LABS Text: 14 1-144 TLH44376A
1001
80:
50:
40:
20:
•
15:17
15:51
20:30 ^j.j
11 ] \ A_ /^J\ •'^
15:00 201ob 21.-00
rile:P980095 #1-522 Acq: 7-JAK-98 00:57:56
331.9368 Zxp«DB225
IEJAMELS IABS Tart:141-144 TLIf44376A
1001
80:
50:
40:
20:
o:
15:00 20.' 00 21:00
riIa:P980095 #1-522 Acq:7-JAX-9S 00:57:56
252.5825 Elp:DB225
TXIASGLE LABS Text:141-144 TLIt44376A
1001
80.
50:
40:
20:
0:
19:0319:30 20:07 20:38 21:11
r-H vVv»y\ -.j^ "^^ u^-WN^T~^r-yv~**~~
-------
. tass 292.9825
2.42 volts
Peak top
Systa file naie
Data fllenaie
Resolution
Group nutter
lonlzatlon lode
Switching
. lasses 292.9825;
fl 292.9825
8 383.9816
D 315.9419
E 317.9389
F 319.8965
6 321.8936
H 327.8847
338.9792
J
K
L
H
1
El*
VOL1RGE
388.9761
38,9732
331.9368
333.9338
375.8364
Channel I 338.97% Peak top
Height 1.73 volts Span 288 ppi
100
-------
TLI Project: 44376A
Client Sample: 153-156 '
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980028
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received:
194-59-11A-D Date Extracted:
1.000
n/a
DB-5
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
KAS
Spike File:
ICal:
ConCaL
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1.2J.7.8-PCCDD
l,Z3,4,7,8-HxCDD
1.2.3,6,7,8-HxCDD
1,2.3,7,8,9-HxCDD
1,2.3,4.6,7,8-HpCDD
1,2.3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
|2J,4,7,8-HxCDF
K23,6,7,8-HxCDF
2.3,4,6,7,8-HxCDF
1,2.3,7.8,9-HxCDF
1.2^,4,6.7,8-HpCDF
1.2J.4,7,8.9-HpCDF
1,2^,4,6.7,8,9-OCDF
Totals
Total TCDD •
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
AW^;|»g) Bt;, £MPC
0.68
4.0
4^
13
103
43.1
69.6
65.2
15.6
29.4
101
34.9
53.2
3.1
163
24.8
144
Amt M Number Dt EMPC ,
.v f "•
72.0 12
65.7 10 97.8
93.7 7
86.7 2
364 16
398 17 399
413 13
270 4
Ratio
0.79
1.61
1.20
1.25
1.23
1.03
0.84
0.75
1.59
1.51
1.24
1.25
1.26
1.29
1.05
1.04
0.87
FTT
25:21
29:36
32:44
32:49
33:06
36:03
39:36
24:40
28:35
29:16
32:02
32:09
32:37
33:22
35:01
36:33
39:49
Ftags
PR-
ill
E_
E~
iZ
PR_
E_
E_
.Flags
E_
iZ
E
E_
E
E_
Page 1 of 2
MIT2_PSRvl.OUlARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/10/98
101
-------
TLI Project 44376A
Client Sample: 153-156
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980028
_, ^
; Internal Standards
I3C12-2,3,7,8-TCDF
I3C,r2,3,7,8-TCDD
13C,rU,3,7,8-PeCDF
13C,rU,3,7,8-PeCDD
13C,rl^3,6,7,8-HxCDF
13C,rU,3,6,7,8-HxCDD
13C12-U^,4,6.7,8-HpCDF
13Cl2-U,3,4,6,7,8-HpCDD
Surrogate Standards {Type A)
13C12-2,3,4,7,8-PeCDF
13C12-U,3,4,7,8-HxCDF
IJC,2-U,3,4,7,8-HxCDD
Surrogate Standards {type A>
37CL,-2,3,7,8-TCDD
Alternate Standards {Type A)
13C12-U,3,7,8.9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
Recovery Standards
I3C12-1Z3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
' « r-.J*
Affl€< {p0c ..
.2.4
2.1
2.4
2.0
13.
3.0
2.8
2.7
4.9
An&fcigJ5
3.6
4.4
3.8
3.9
An&fcigl
3.5
Amt. (rJ9^
2.6
2J
V \i Av '
...i\. «>, >.
J;ff^ ^BePVfif^
61.0
53.3
59.1
50.0
58.4
74.3
69.6
68.7
61.3
v, ^Recovery
90.7
109
93.8
97.7
';f>fcecwery
87.9
^ % Recovery
65.0
63.5
^ , -
40%-130%
40%-130%
40%-130%
40%-130%
40%-1309fc
40%-130%
25%-130%
25%-130%
25%-130%
40%-130%
40%-130%
40%-130%
40%-130%
%
-
40%-130%
40%-130%
•"BaHO
0.75
0.80
1.49
1.49
0.51
1.20
0.45
1.04
0.86
Ratto
1.53
0.51
1.20
0.44
Ratio
0.51
OJ1
Ratio
0.82
1.18
- -RT
24:38
25:20
28:34
29:35
32:08
32:48
35:01
36:02
39:36
RT
29:15
32:02
32:44
36:32
nrr
25:21
RT
33:22
32:37
RT
25:09
33:07
f
Flags
—
Ffags
—
Ftags
—
Ffags
—
Flags
—
Data Reviewer
01/10/98
Page 2 of 2
MTT2_PSRvl.01,LARi 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/10/98
10°
J_ L/ •-»
-------
Initial
..Date.
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
2.00
Page No. 1
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of 0"980028B.dbf
Matched GC Peaks / Ratio / Ret. Tine
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
KN
K
K
K
K
K
K
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
KN
NK
K
K
DC NL 0
21
21
22
22
22
23
23
. 23
24
24
24
24
25
25
25
26
0
:00
:29
:59
:13
:37
:56
:20
:36
:50
:03
.65-0.89
0
0
0
0
0
0
0
0
0
.77
.74
.76
.75
.75
.74
.75
.74
.74
0.74
:14 0.75
:28
:40
:04
:17
:32
:23
0
.74
0.75
0.
0.
0.
0.
16 Peaks
DC NL 0:
DC WL 22 ;
DC WL 22 :
23:
24:
24:
25:
DC WH 26 :
DC WH 26:
DC WH 26 :
DC WH 26:
0
:00 RO
:25 RO
:59
53
04
38
17
10
38
47
56
,75
,74
,79
74
1,
2,630.52
50,196.40
48,271.20
49,955.70
251,645.00
154,767.30
166,704.30
118,319.60
.163, 606.00
201,437.50
66,543.00
65, 614.80
325,383.00
71,034.80
65,011.50
11,106.90
8,372.51
817,969.51
21
20
21
107
65
71
50
69
85
28
27
139
30
27
4
3
,398
,851
,396
,507
,946
,219
,474
,813
,969
,536
,935
,111
,362
,682
,905
,565
.50
.30
.90
.00
.20
.60
.70
.10
.50
.10
.40
.00
.20
.00
.08
.69
28,797
27,419
28,558
144,138
88,821
95,484
67,844
93,792
115,468
38,006
37,679
186,272
40,672
37,329
6,201
4,806
.65-0.89
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4 Peaks
DC NL 0:
22:
23:
23:
24:
24:
24:
0.
00 RO
49
11
30
10
26
50
65-
0.
0.
0.
0.
0.
0.
0.
34
98
81
74
87
75
67
84
82
73
65
61.61
261.41
653.35
. 72.73
537.38
16,107.16
303.79
217.36
803.61
164.10
' 31.62
17,021.06
0.89
24
77
77
79
77
80
81
24.67
86,137.90
56,734.10
7,285.58
26,419.10
15,780.03
7,408.23
30
249
6,904
122
.94
.75
.38
.02
41
287
9,202.
181,
0.867-1.079
.90
.90
.80
.00
.10
.70
.90
.90
.00
.90
.40
.00
.60
.50
.82
.82
0.000
0.872
0.892
0.902
0.918
0.931
0.947
0.958
0.968
0.976
0.984
0.993
1.001 2378-TCDF AN
1.018
1.026
1.037
1.071
0.959-1.041
.79
.63
.78
.77
0.000
0.910
0.933
0.970
0.977
1.000 13C12-2378-TCDF ISO
1.026
1.062
1.081
1.087
1.093
37,
24,
3,
11,
7,
3,
506.
721.
219.
473.
017.
324.
60
90
40
80
40
43
48,631.
32,012.
4,066.
14,945.
8,762.
4,083.
0.895-1.047
30
20
18
30
63
80
0.000
0.901
0.915
0.928
0.954
0.964
0.980
E
E
E
E
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1701/10/98
103
-------
Page No. 2
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of U980028B.dbf
Matched GC Peaks / Ratio / Ret. Ti»e
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
M
AN
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
M
AN
25:15
25:21
25:31
25:41
25:54
26:20
12 Peaks
DC NL 0:00
DC ML 22:48
DC WL 23:06
DC WL 23:12
23:25
23:59
24:11
24:19
24:39
24:51
25:21
25:45
26:34
26:39
26:47
11 Peaks
0.
DC NL 0:00 RO
25:09
25:20
25:39 RO
25:51 RO
4 Peaks
1.
DC NL 0:00 RO
26:35
27:03 RO
27:13
27 : 20
27:35
27:43
27:53
28:12
28:18
28:30
28:35
28:44
28:51
29:16
0.77
0.79
0.79
0.79
0.86
0.76
.65-0.89
1.51
0.82
0.80
0.94
1.15
26,800.00
2,255.00
3,594.40
3,957.14
1,387.98
1,360.13
239,119.59
48.70
447.36
522.57
418.96
173.49
17,808.20
457.32
220 . 65
457.92
147.39
9,435.46
10,441.10
46.89
84.66
71.47
39,344.55
11,700.00
995.00
1.589.40
1,750.86
640.69
586.35
173.49
17,808.20
457.32
220.65
457.92
147.39
9,435.46
10,441.10
46.89
84.66
71.47
15,100.00
1,260.00
2,005.00
2,206.28
747.29
773.78
0.
0.997
1.001 2378 -TCDD AN PR
1.007
1.014
1.022
1.039
921-1.079
0.000
0.900
0.912
0.916
0.924
0.947
0.955
0.960
0.973
0.981
1.001 37C1-TCDD CLS
1.016
1.049
1.052
1.057
0.921-1.079
25.75
18,000.51
10,720.27
387.77
64.92
29,173.47
32-1.78
0.96
1.54
0.87
1.51
1.53
1.51
1.51
1.52
1.50
1.51
1.56
1.59
1.50
1.52
1.51
10.74
116,622.40
1,999.02
3,176.74
3,233.73
40,046.10
272,815.00
65,871.20
107,989.30
142,981.10
59,600.00
49,700.00
46,647.40
78,599.60
90,819.20
8,102.57
4,777.34
205.03
42.16
PeCDF Follows -
70,759.50
1,215.09
1,909.19
1,953.87
24,081.60
164,272.00
39,732.10
64,849.80
86,000.20
36,300.00
30,500.00
28,015.10
47,360.10
54,641.80
9,897.94
5,942.93
219 . 08
36.68
0.000
0.993 13C12- 1234 -TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.020
0.925-1.065
45,862.90
1,391.10
1,267.55
1,279.86
15,964.50.
108,543.00
26,139.10
43,139.50
56,980.90
23,300.00
19,200.00
18,632.30
31,239.50
36,177.40
0.000
0.931
0.947
0.953
6.957
0.966
0.970 E
0.976
0.987
0.991 E
0.998
1.001 12378-PeCDF AN
1.006
1.010
1.025 23478- PeCDF AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/10/98
104
-------
Page Ho. 3
01/10/98
Compound/
M_Z.... QC.Log Omit why
Listing of 0980028B.dbf
Matched GC Peaks / Ratio / Ret. Tine
.RT. OR Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
29
29
30
30
:25
:44
:07
:15
1.51
1.50
1.39
1.52
18 Peaks
DC ML 0
26
26
26
27
27
27
27
28
28
28
28
29
29
:00
:24
:37
:47
:14
:26
:47
:56
:11
:18
:34
:51
:03
:15
29:52
352-354
PeCDD
156-358
D
356-358
13C12- PeCDD
368-370
30
30:
:06
:15
1
RO
RO
RO
RO
RO
RO
RO
16 Peaks
DC NL 0:
DC WL 27 :
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
00
35
49
18
32
40
51
01
07
19
27
36
44
04
1.
RO
RO
RO
RO
.32-1.78
1.20
1.10
1.47
1.48
1.67
1.39
1.45
1.24
1.37
3.81
1.49
1.48
1.26
1.53
0.90
0.94
1.69
130,996
29,270
324
10,891
1,251,584
10
28
130
54
15
66
174
367
42
95
12,138
272
100
10,638
53
35
123
.70
.60
.47
.45
.01
.51
.66
.94
.98
.70
.77
.21
.46
.78
.80
.84
.09
.96
.24
.39
.68
.08
24,339.58
32-1.78
1.14
0.88
1.19
1.32
1.56
1.61
1.57
1.61
1.58
1.57
0.84
1.61
1.60
1.69
12 Peaks
DC NL 0:
27:
27:
DC SN 27:
28:
28:
00
43
48
58
17
32
1.
RO
RO
RO
RO
RO
RO
32-1.78
1.98
1.31
3.02
0.58
2.46
1.24
78,741
17,542
188
6,577
17
78
32
9
38
103
223
24
143
7,264
162
61
6,432
32
.50
.00
.39
.74
.42
.01
.77
.83
.89
.05
.36
.70
.28
.06
.59
.37
.31
.45
21.69
77
.27
52,255
11,728
135
4,313
15
52
22
5
27
71
180
18
37
4,874
109
48
4,205
36
23
45
.20
.60
.58
.71
0.
.82
.93
.21
.87
.88
.16
.41
.08
.57
.78
.50
.62
.93
.00
.00
.81
1.030
1.041
1.054
1.059
860-1.140
0.000
0.924
0.932
0.938
0.953
0.960
0.973
0.978
0.987
0.991
1.000 13C12-PeCDF 123 IS2
1.010
1.017
1.024 13C12-PeCDF 234 SUR1
1.046
1.054
1.059
0.935-1.022
7.35
425.31
51,633.22
4,247.
38,427.
7,969.
24,756.
4,087.
9,159.
10,217.
5,226.
7,022.
5,582.
4,798.
173,129.
52
00
85
16
86
61
95
58
96
53
56
80
31,384.
90
2,419.07
23,428.
4,914.
15,138.
2,519.
5,606.
6,238.
3,176.
4,335.
3,438.
3,013.
70
28
50
35
93
38
94
08
36
61
26,426.
1,828.
14,998.
3,055.
9,617.
1,568.
3,552.
3,979.
3,764.
2,687.
2,144.
1,784.
90
45
30
57
66
51
68
57
62
88
17
95
0.000
0.932
0.940
0.957
0.965
0.969
0.975
0.981
0.984
0.991
0.995
1.001 12378-PeCDD AN
1.005
1.016
0.865-1.135
3.
32.
24.
3.
30.
37.
67
97
89
54
06
21
20.
29.
29.
22.
04
46
04
62
15.
9.
11.
18.
33
76
79
17
0.000
0.937
0.940
0.945
0.956
0.965
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/10/98
105
-------
Page No.
01/10/98
Listing of (J980028B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
DC SN 28
28
28
DC SN 29
29
29
29
29
29
30
30
:40
:48
:50
:07
:17
•26
:35
:43
:57
:07
:18
1
RO 4
RO 1
RO 5
RO 3
RO 1
1
1
RO 3
1
RO 5
13 Peaks
.53
.10
.05
.70
.82
.04
.49
.51
.96
.42
.02
4.95
7.93
18.85
3.80
12.06
11.70
5,311.54
922.58
22.57
15.61
14.41
6,462.38
1.05-1.43
DC ML 0
:00
31:05
31:13
31:23
31:31
AN
M
374-376
13C12- HxCDF
384-386
384-386
HxCDD
390-392
31:
31:
32:
32:
32:
32:
32:
33:
33:
:41
:51
:02
09
:15
26
37
22
28
1.26
1.24
1.23
1,
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
.31
,23
,22
24
24
25
26
23
26
29
24
13 Peaks
2,385.35
91,814.00
218,055.60
18,173.42
28,238.70
15,040.77
2,443.34
207,127.80
89,263.20
25,468.60
38,349.70
107,065.70
5,450.00
27,100.00
873,590.83
12.76
11.46
18.07
7.11
3,175.06
555.36
35.09
9.15
28.39
HxCDF Follows -
50,882.00
120,371.00
10,298.30
15,563.60
8,259.31
1,352.36
114,716.00
49,531.70
14,178.00
21,184.50
59,699.30
3,070.00
15,000.00
3
10
4
6
2,136
367
a
6
5
.11
.93
.73
.82
.48
.22
.85
.46
.65
0
0
0
0
0
0
1
1
1
1
1
.969
.974
.975
.984
.990
.995
.000 13C12-PeCDD 123 IS3
.005
.012
.018
.024
0.962-1.047
40,932.00
97,684,
7,875.
12,675.
6,781.
1,090.
92,411.
39,731.
11,290.
17,165.
47,366.
2,380.
12,100.
0.43-0.59
DC NL 0:
31:
31:
32:
32:
32:
32:
33:
00
13
49
02
08
37
55
22
RO 1.
RO 0.
RO 1.
0.
0.
0.
RO 1.
0.
7 Peaks
DC NL 0:
31:
32:
32:
32:
32:
00
34
01
13
23
44
1.05-
RO 0.
1.
1.
1.
1.
1.
78
83
57
51
51
51
26
51
45.39
243.20
48.06
7,363.14
8,165.43
8,009.52
136.17
6,321.05
30,286.57
- Above : HxCDF /•
1.43
71
28
22
23
09
20
342.86
15,273.11
65,269.00
36,447.40
5,933.51
6,621.84
133.86
49.32
2,499.07
2,744.46
2,711.19
113.37
2,129.77
8,582.45
35,910.10
20,074.60
3,093.97
3,611.36
161.
31.
4,864.
5,420.
5,298.
90.
4,191.
,60
,12
10
46
98
80
50
60
20
40
00
00
0
.000
0.967
0.971
E
E
0.977
0.981
0.986
0,
0.
1.
1.
1.
1.
1.
1.
0.876-
06
83
07
97
33
18
28
0.
0.
0.
0.
1.
1.
1.
1.
,991
,997 123478-HxCDF AN
,001 123678-HxCDF AN
004
009
015 234678-HxCDF AN
038 123789-HxCDF AN
041
•1.124
000
971
990
997 13C12-HXCDF 478 SCTR2
000 13C12-HXCDF 678 IS4
015 13C12-HXCDF 234 ALT2
024
038 13C12-HXCDF 789 ALT1
E
E
PR
0.958-1.014
6,690.
29,358.
16,372.
2,839.
3,010.
66
90
80
54
48
0.
0.
0.
0.
0.
0.
000
962
976
982
987
998 123478-HxCDD AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/10/98
106
-------
Page No. 5
01/10/98
Compound/
M_Z.... QC.Log Omit why
Listing of 0980028B.dbf
Matched GC Peaks / Ratio / Ret. Tine
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
D
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
D
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
32:49
33:06
7 Peaks
1
DC ML 0:00 RO
32:02
32:44
32:48
33:07
4 Peaks
0
DC NL 0:00
35:01
35:17
35:27
DC NH 35:55 RO
36:33
4 Peaks
0.
DC NL 0:00 RO
35:01
36:32
2 Peaks
0.
DC NL 0:00 RO
DC WL 35:09 RO
35:18
36:03
2 Peaks
0.
DC NL 0:00
35:18 RO
35:32 RO
36:02
3 Peaks
0.
DC NL 0:00 RO
39:49
1 Peak
1.25
1.23
.05-1.43
2.20
1.05
1.20
1.20
1.18
13,637.12
18,619.27
161,801.25
15.03
38.07
5,273.12
7,681.27
10,392.68
23,385.14
.88-1.20
1.01
1.05
1.05
1.05
0.54
1.04
.37-0.51
1.95
0.45
0.44
96.36
341,420.00
69,346.40
84,856.20
340.41
40,502.50
536,125.10
19.54
5,949.70
4,660.82
10,610.52
88-1.20
1.37
0.45
1.01
1.03
88-1.20
1.06
0.72
3.80
1.04
43.86
1,026.39
56,202.30
55,523.30
111,725.60
19.54
51.02
8.59
5,180.07
5,239.68
76-1.02
4.73
0.87
28.10
171,627.70
171,627.70
7,586.71
10,251.40
19.48
2,875.21
4,196.41
5,623.36
174,926.00
35,498.90
43,549.30
20,652.40
1,836.50
1,432.01
28,303.50
28,199.40
26.01
15.99
2,635.16
Octa-CDD and CDF
80,077.40
6,050.41 1.001 123678-HxCDD AN
8,367.87 1.009 123789-HxCDD AN
0.970-1.030
0.000
18.59 0.977
2,397.91 0.998 13012-HxCDD 478 SUR3
3,484.86 1.000 13C12-HXCDD 678 IS5
4,769.32 1.010 13C12-HXCDD 789 RS2
0.996-1.049
0.000
166,494.00 1.000 1234678-HpCDF AN
33,847.50 1.008
41,306.90 1.012
1.026
19,850.10 1.044 1234789-HpCDF AN
0.943-1.114
0.000
4,113.20 1.000 13C12-HpCDF 678 IS6
3,228.81 1.043 13C12-HpCDF 789 SOR4
0.975-1.005
0.000
0.975
27,898.80 0.980
27,323.90 1.000 1234678-HpCDD AN
0.972-1.028
0.000
36.28 0.980
4.21 0.986
2,544.91 1.000 13C12-HpCDD 678 IS7
Follows
0.899-1.101
0.000
91,550.30 1.005 OCDF AN
E
E
E
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/10/98
107
-------
Page No.
01/10/98
Listing of 0980028B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
OCDD
458-460
4S8-460
0.76-1.02
DC NL 0:00 1.00 11.06
39:36 0.84 66,941.80
1 Peak
66,941.80
30,632.60
0.899-1.101
0.000
36,309.20 1.000 OCDD
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 2.02 3.57
39:36 0.86 6,941.79
470-472 1 Peak 6,941.79
3,215.80
0.996-1.004
0.000
3,725.99 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:38)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report *•*
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
r±le:O98002S tl-723 Acq: 6-JKN-1996 18:57:10 GC EI+ Voltage SIS 70S Soiae:571803
303.9016 T:2 BSUB(256, 30, -3.0) PXD(9,5,3,0.10\,23a7313.0,1.00\,r,T) SxptSDBSUS
TRIANGLE LASS TeJCt:TLIt44376A 153-156
1001
ao.
60.
40.
20.
Al.
•
A3.60E8
A
A1.0SE9 AS. OSES l\
A2.14E8 /SA A A /W\A 'A
A /\ /V / V^JVJ^J 1 V/VA/
'22:00 23:00 ' ' ' 24:00
9E9 ,.3.3X8
A3. 04X8
I A/v r
L2.528
Li. 0*8
Li.3r»
Ls.sr?
25 loo ' ' '25:00' Time
rila:USa0028 tl-723 Acq: 6- JAN- 19 9 8 10:57:18 GC EI+ Voltage SIS 70S Soiae:743456
305.8987 Ti2 BSOB(256,30,-3.0) PXD(9, 5, 3,0 .101,3973824. 0,1. 00\rf,T) SxpiSDBSUS
TRIANGLE LASS Teit:TLIt44376A 153-156
loot
80.
SOJ
40:
20:
o'-
Al.t
A1.15E9 1
A1.44X9 A
A AW • /OJStS 1 1 1
/ \X\ ^\ ft l\ h I I 1
'22:00 ' ' 23:00 . 24:00
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A/\ .
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-------
rila:U9a0028 tl-733 Acqt 6-J3Ul-1998 18,57:18 GC XI+ Voltage SIS 70S Hoiae:5363
319.8965 Ts3 BSOB(356r30, -3.0) PXD(7,5,3,0.10\e314S2.0t1.00\,TtT) XxptUDBSUS
TRIANGLE LASS Teit:TLIt44376A 153-156
1001
80.
60:
40:
30:
0.
A3.4 7X8
A3.33X7
41.1520
A1.29X8
A7.03X7 A3.32X7 V\
J..±3f
A
23,00 34,00 35,00 36,00
riletO980038 tl-733 Acqt 6-JAN-1998 19,57*18 GC SI+ Voltage SIS 70S Soiae,22793
331.8936 f:3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,9il73.0,1.00*,T,T) XxptBDBSOS
TSIANGLE LASS Text:TLIt44376A 153-156
1001
00:
60:
40:
30:
ol
A3.30X8
A1.49X8
A4.07E7
A
A8.76X7 A4.08E7
Al.S5E8
23:00 34,00 35,00 36,00
Tlle,U980038 tl-733 Acqt 6-J2OT-1998 18,57:18 SC EI+ Voltage SIS 70S Noise: 10992
331.9368 T,3 3SVB(356,30,-3.0) tXD(7,5r3,0.10\,4396a.O,1.00*,T,X)
TRIANGLE LASS Text:TLIt44376A 153-156
1001 A8.10E7
80:
60:
40:
so:
\4. 7SE7
33:00 34>00 35:00 36:00
T±la,0980038 tl-733 Acq: 6-JAH-1S98 18,57:18 GC EI+ Voltage SIS 70S Soiae:7374
333.9338 T:3 SSU3(356,30,-3.0) ?XD(7,5,3,0.10\,39096.0,1.00\rT,X) Exp-.HDBSUS
TRIANGLE LASS Text:TLH44376A 153-156
1001 A9.90E7
80:
60:
40:
30:
0:
5.94X7
33:00 24,00 25:00 36:00
r±J.e:U980028 H-733 Acq: 6-JMT-1998 18,57,18 GC XI+ Voltage SIS 70S Soiae,24352
337.8847 T:2 SSU3(356,30, -3.0) PXD(7,5,3,Q.10\,97408.0,1.00\,T,T) EzptNDBSUS
TRIANGLE LASS Text:TLIt44376A 153-156
1001 Al. 8X8
80:
60:
40:
20:
Al.04X8
A9.44X7
33:00 34,00 25:00
r±le:0980038 tl-723 Acqt 6-JXS-1998 18,57,18 GC XH- Voltage SIS 70S
30.9793 T,3 Xxp,NDB5US
TRIANGLE LASS Tert,TLIt44376A 153-156
100*
80.
60:
40:
30:
o:
33:06 23:24
23:5524:11
24,55
35:34
26,00
35L52 _ 26ijL5_
-7.8X7
.6.3X7
.4.7X7
.3.1X7
-1.6X7
0.0X0
-1.0X8
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-6.0X7
'-4.0X7
•-3.0X7
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Time
-3.0X7
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0.0X0
Time
-3.4X7
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-1.5X7
.9. 7X6
'-4. 8X6
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Time
-4.0X7
.3.2X7
.2.4X7
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-7.9X6
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-.7.3X7
-.5.5X7
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:i. ax?
33:00
34,00
35:00
26:00
to. oxo
Time
110
-------
Fila:O980028 tl-723 Acq: 6-JAK-1998 18:57:18 SC EH- Voltage SIS 70S Koia»s3267
339.8597 f:2 BSUB(256, 30, -3.0) PXD(7,5,3,0.10\,13068.0,1.00\,r,T) Xlp:SDB5US
XSIANSLX LABS Text:TLIt44376A 153-156
1001
80.
60.
40.
20.
0
A1.64X9
n
I
11 AS. 60X8
A7.08X8 A A7.87Z8
A 1 l\*7 30X8 M 74E8 A A
l\ MA A/\AAAA /\/\
/\ A/lA /V\/V\A/\ \ \ **• 7Ssa
v A/ \/\^J TWWVv /vv /\
27:00 ' ' 28:00 25:00 J0:00
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341.8567 T:2 BStJB(256f30r-3.0) PXD( 7,5, 3,0. 101,13572. 0,1.00\,r,T) XzptODBSUS
TSIAHSLX LABS Text:TLIt44376A 153-156
1001
80.
60.
40.
20.
Al. 139X9
AS. 70X8
A4.59X8 «.7BW AS. 23X8
Aft / IA4 . 83X8 A3 . 12X8 A 1 1
A / \ -w-rf*»w n^.j*+ao n II
A /\/ \ AA A A /\ I \
A/\A /V\/V\A/\ / \ \ &1.17X8
/ V v V_x-^ TwWvv /vv/x
27:00 29:00 25:00 JO: 00
r±la:U980028 tl-723 Acq: 6-JAX-199S 18:57:18 SC EH- Voltage SIS 70S Hoiee>3196
351.9000 f:2 BSUB(256,30,-3.0) PKD(7,5, 3,0.10\,12784 .0,1 .00\,T,T) XxpsSDBSVS
TRIANGLE LABS Text:TLIt44376A 153-156
1001
80-.
60:
40:
20.
A 7 26X7
{\ A6.43X7
27:00 ' ' 28:00 . ' ' ' ' 25:00 J0:00 '
T±loiU980028 tl-723 Acq: 6-JZK-1998 18:57:18 SC EH- Voltage SIS 70S Noiae:2655
353.8970 T:2 BSUB(2S6,30,-3.0) PED(7,S,3,0.10\,10620.0,1.00\,r,X) XzptRDBSVS
TSIASGLX LABS Text:TLIt44376A 153-156
1001
80:
60:
40:
20:
0'
A4.87E7
n A4.21E7
A
A
i v_ y L_
3.9X8
.3.1X8
.2.3X8
.1 . 6X8
.7.8X7
0.0X0
ttaa
-2.6X8
'-.2.0X8
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.1.0X8
-.5.1X7
o.oxo
Tiae
-2.0E7
.1 . 6E7
.1.2X7
.8.2X6
.4.1E6
Tloe
.1.4X7
.1.1X7
.8.5X6
.5.7X6
.2.8X6
0.0X0
27:00 28.' 00 ' ' '25:00 JO: 00 i' Time
rlle:U9S0028 tl-723 Acq: 6-JXH-199S 18:57:18 SC EH- Voltage SIS 70S
330.9792 T:2 ElpiNDBSUS
TRIANGLE LABS Text:TLIt44376A 153-156
1001
80:
60:
40:
20:
o:
2ff:54 27:12 27:47 28j_10 2&i26^28^42 28:59 3^4J: 30:033°.
v V — — - ^^~
27:00 28:00 25:00 JO: 00
rllaiD9S0028 tl-723 Acq: 6-J3OT-1998 18:57:18 SC EH- Voltage 522 70S
405.7574 Tt2 ExptNDBSUS
TRIANGLE LABS Text:TLIt44376A 153-156
1001
80:
60:
40:
20:
o:
JO
15 JO:J7
.9.1X7
.7.3X7
.5.5X7
.3.7X7
.1 . 8X7
0.0X0
Time
19
n
27:55 28:17 38,33 29:27 25:58 1
"*• - **- - - i " .-^-.A A- _*^«^^^. j^^— ^ MII-^ M n -^^ r^V A^h_ fS*^~ f**\f*~*
27:00 28:00 25:00 JO: 00
L 30:33
*AA-^W.
.6. 7X5
.5.4X5
.4.0X5
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.1.3X5
o.or.o
i , ™ 'i '
Tlae
11
-------
rU.a:(JSUOOja tJ.-lll Acq: 6-JAN-J.99B 18,57,18 SC £1+ Voltage SXB 70S Jfoj.ae,22JS
355.8546 T,2 BSU3<256, 30, -3.0) PKD(5, 5,3, 0.05\,8940.0,1.00\,r,T) XxptSDBSDS
TRIASSZX IA3S TextsTLH44376A 153-156
1001 A3.14X8 A3.34X8
80.
60.
40.
20.
A1.51X8
A6.24X7
AS. 61X7
A
A4.34X7
A3.01X7
/Y
27i48 23:00 28tl2 2B>24 28,36 28,48 29,00 29tl2 29:24 29,36 29:48' jOsOO 30,12 30,24
nj.e,O980028 tl-723 Acqi 6-JAK-1993 18:57,18 GC XH- Voltage SIS 70S SOiae,196S
357.8516 Ti2 BSU3(256,30,-3.0) PKD(5,5,3, 0.051,7860.0,1.00\,r,T) XxpiSDBSOS
TRUOXXJS IAS3 Teit:TLIt44376A 153-156
1004 A2.64X8
27: IB 28,00 28,12 28,24 28,36 28,48 29,00 29,12' 29V24' 29i36' 29', 4a' 30,00 30,12 30,24
r±le,a980028 tl-723 Acq: 6-JAS-1998 18,57,18 GC XH- Voltage SIS 70S Hoise: 1423
367.8949 T,2 BSUS(256,30, -3.0) PXB(S,5,3,O.OS\,S692.0,1.00\,T,T) XjcptSDSSUS
TXIANGLX LASS Text:TLH44376A 153-156
1004 . A3.J.3E7
80.
60.
40.
20.
27\48' Moo' 2 B': 12 28,24 28,36 28,48 29,00 29'sii' 29V24 ' 29,36' 29:48 30,00 ' 30,12 30,24 '
r±2e,a980028 tl-723 Acq: 6-J3OT-1998 18,57,18 GC XI+ Voltage SIS 70S Soife:721
369.8919 r,2 BSUB(256,30, -3.0) PXD(5,5,3,0.05\,2884.0,l.QO\,r,T) XxpsXDBSOS
TRIANGLE LABS Tart*TZ.I§44376A 153-156
1001
80.
60.
40.
20:
A2.14X7
.67X6
27,48 28,00 28,12 28,24 28,36 28,48 29,00 29>12 29:24 29,36 29,48 30,00 30,12 30:24
rUa,U980028 91-723 Acq, 6-JJUi-199S 18,57,18 GC XH- Voltage SIX 70S
330.9792 Tt2 XzptSDSSOS
TSIANGLX LABS TexttTLIt44376A 153-156
1001.
00.
60.
40.
20.
0.
28,59
29,28
30,19
-7.4X7
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0.0X0
Tlfl
0.0X0
Tlae
-9.4X6
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.5.6X6
.3.7X6
.1.9X6
0.0X0
Time
6.5E6
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.3.9X6
.2.6X6
J..3X6
0.0X0
Zlae
.9.1X7
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27,48 28,00 28,12 28,24 28,36 28,48 29,00 29:12 29',24 29,36' 29:48 30:00 30:12 30,24
.0.0X0
TiMe\
112
-------
\rile-0980028 ti-lSS Acq: 6^JXJr-1998 18:57:18 SC XI+ Voltage SIS 70S soiae:664910
373.8308 Tt3 BSUB(256,30, -3.0) PKD(7,5,3,0.iO\,265964Q.O,1.00\,r, T) ZxpiJOJBSOS
TSIAIKLX LABS TaxtiXZ.H14376A 153-156
1001
80:
40
OJ
A1.15X9
A5.09X,
A1.56X8
AS.97X8
Al.63X8
31:00 31', 12 31,34 31',36 31',48 32,00 32,12 32',24 32,36 32',48 33',00 33', 12 33',24 33:36 33:48
\ril»,O980028 tl-385 Acqt 6-J3UT-1998 18:57:18 SC XH- Voltage SIS 70S Soiae,528014
375.8178 ri3 BSUB(256,30, -3.0) PXD(7,S,3,0.10\,2U2Q56.0,1.00\,r,T) XxptSDBSUS
TRIANGLX lASS T*xt:TLH44376A 153-156
1004 A9.77X8
A9.24X8
so
40:
201
A4.09X\
A4.74X8
A1.30E8
JliOO 31:12 31,24 31,36 31:48 33',00 32', 12 32*24 32i36 33t48 33tOO 33sl2 33,34 33',36 33',48
file,0980038 tl-385 Acqi 6-JXK-1998 18,57:18 SC XH- Voltage SIS 70S Soiae,36734
383.8639 T:3 BSOB(356,30, -3. 0) PXD(7,5,3,0.10\,106936.0,1.00\,r,T) ExptlOJBSas
TRIANGLE LABS XextsXLIt44376A 153-156
100$ A2.fOX7 A3.71X7
601
401
201
A3.13X7
3l':00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32s36 32:48 33:00 33:12 33:24 33:36 33:48
file,0980028 01-385 Acq: 6-JXX-1998 18:57:18 SC XH- Voltage SIS 70S Soiae:15030
\38S.8610 r-.3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,60130.0,1.00\,r,T) Xxp:SDBSOS
TRIANGLE LABS Tert:XLIt44376A 153-156
A4.86X7
SOJ
50J
401
201
AS.30X7
A4.19X7
31:00 31': 12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32':48 33:00 33:13 33:24 33:36 33:48
r±letU980028 tl-385 Atxj: 6-JAS-1998 18,57:13 SC XH- Voltage SIS 70S
393.9760 Ti3 XxpiNDBSUS
TRIANGLE LABS Tert:TLH44376A 153-156
1001
aol
601
20.
0.
,311 00 31,12
31,37
33,17
33,09
33,33^ 33,46
31:00 31,12 31:24 31:36 31,48 32,00 32:12 32:24 32:36 32:48 33,00 33:12 33:24 33,36 33:48
File,0980038 tl-385 Acq, 6-JAN-1998 18,57:18 SC XH- Voltage SIS 70S
445.7555 r,3 XxpiODBSOS
-3.7X8
-.2.9X8
'•.2.2X8
'-.1.5X8
'-.7.4X7
-.0.0X0
Zlaal
-3.0X8
'-.2.4X8
li.axa
il.2E8
is.9X7
0.0X0
Time'
8.2X6
£.6.6X6
L4.9X6
^.3.3X6
.6X6
0.0X0
Tiae
.6X7
U..3X7
.9.9X6
'-.6.6X6
13.3X6
0.0X0
Time,
4.4X7
'-.3.5X7
'-.2.6X7
.1.8X7
'-.8.8X6
0.0X0
TRIANGLE LABS
ion
flOj
ffflj
401
201
0.
TexttTLI*44376A 153-156
33:35
:5
32Yob' 32:12' 32:24 ' '32\36' 32i48r33'sb6 33': 12 33't24
113
-------
f3.J.e>O98Q028 tl-385 Acqi 6-JAN-199B 18,57,18 SC £1+ Voltage SIS 70S Soia»,94901
389.8156 Ti3 BSUS(256, 30, -3.0) fXD( 7,5, 3,0.iO\, 379604.0, 1.00\,T,T) XxpiSDBSUS
TSIASSLX LABS Texts TLH44376A 153-156
1001
80.
60.
40.
20.
A3. 59 f 8
(1
1
1 1 A2.01X8
A
A8.58X7 11 / \
A / I / \ A7.59E7 JU..03X8
/V 1 w V-^ /W f^
31i36 '31\48 ' 33100 32\12 32\24 32i36 ' 32\48 ' ' 33\00 ' ' 33\12 ' '33i24 ' ' 33
1.2X8
.9.3X7
.7.0X7
.4.6X7
L3.JZ7
36 Time
rlleiU980028 tl-385 Acqs 6-JUT-1998 18t57,lB SC XH- Voltage SIS 70S Soiatt 133652
391.8127 Ts3 BSUB(256,30,-3.0) PKD(7 , 5,3,0 .10\,534608. 0,1. 00\,T,T) SxptBOBSUS
TSIASSLX LABS Tarts XLIt44376A 153-156
1001
80.
60.
40.
20.
A2.94E3
M
'
I 1 A1.64X8
1 \ A
A6.69E7 11 / \
A/ \ / \ A6.05E7 A8.37S7
1 w W^7 /v\ r^
31>36 31\4a 32>00 32sl2 32:34 32s36 32\4S 33\00 33\12 33\24 33
-9.5X7
.7.6X7
.5.7X7
.3 . SE7
'.1.9E7
36 Time
ttletoaaooaa tl-SSS Acq: 6-fflI-199a 18i57iia SC SH- Voltage SIS 70S So±aes7374
401.8558 Ts3 BSOB(256,30,-3.0) PKD(7,S,3,0.10\,29496.0,1.00\,r,T) SzptSDBSOS
TSIAXSLE LABS Text:TLIt44376A 153-156
1001
80.
60.
40.
20.
0.
A5.62E7
A
A4.20X7 l\
A
/ll ^
j \ \ — y v —
31>36 31t48 32sOO 32tl2 32s24 32s36 32i48 ' ' 33tOO ' 'j'jiiz' ' ' 33\24 ' ' 33\
1.5X7
.1.2E7
.8.9E6
.5.9X6
_J . 0X6
'.0.0X0
36 Time
r±J.asa98002B 91-385 Acqt 6-JJUT-1998 18s57tl8 GC XH- Voltage SIS 70S Soiaas3353
403.8539 Ts3 BSOB(256, 30, -3.0) PKD(7,5, 3, 0 .10\,13412.0,1.00\,T,T) XxptSDBSaS
TBIANGLX LABS TaxtiTLIt44376A 153-156
1003
80.
60.
40.
20.
A4 . 77E7
A
A3.4BE7 (1
A 1 1
A2.40ZH
AM
IV V
J 1 V — _7 v^^
31\36 31 t 48 32iOO 32\12 32i34 32t36 32s48 33tOO 33\12 33t24 33
.1.2X7
.9.7X6
.7.3X6
.4.8X6
.2.4X6
.0.0X0
36 Time
Tila, 0980028 tl-385 Acqi 6-J3UT-1998 13,57,18 SC KH- Voltage SIS 70S
392.9760 Ti3 EiptNDBSUS
TSIASGLE LABS TextiTLI*44376A 153-156
1001
ao.
60.
40.
20.
0.
3i>37 X^_ 32r03 33, 17 32s34 ^i^J^7^ 33,09 33,24 33,32
3l'i36 31s48 32tOO 32112 32', 24 32i36 32\48 33\00 33\12 33\24 33
.4.4X7
.3.5E7
.2.617
.1.8X7
.8.8X6
0.0X0
36 Time
114
-------
Tila:O98002B #1-545 Acq: 6-JAN-199B 13:57:13 GC £T+ Voltagw SIS 70S Ifoiaa:24356
407.7818 r>4 BSOB(256,30,-3.0) PKD(7,5,3,0.10\,97424.0,1.00\,T,T) XxptSDBSUS
TSIAOSLE LASS Taxt:TLIt44376A 153-156
100$ A1.75E9
80:
60:
40:
20:
A4.35E8
A2.07E8
35tOO 35i12 35:24 35:36 35:48 36:00 36:12 36i24 36i36
THat098002S fl-545 Acq: 6-JJOT-1998 18:57:18 GC XH- Voltaffa SIS 70S Noiaa:24075
409.7789 T:4 BSV3(256,30,-3.0) PKD(7,5,3,0.10\,96300.0,1.00\,f,T) XxptUDSSOS
TRIANSLX LASS Taxt:TLIt44376A 153-156
1001 A1.66X9
80:
60:
36:48
40:
20:
A4.13E8
yvyv
A1.99E8
J5iOO 35:12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
rilo:0980028 tl-545 Acq: 6-JKN-199B 18:57:18 SC EH- Voltage SIS 70S Koiaa:13250
417.8253 T:4 BSUB(256,30,-3.0) PKD(7,S,3, 0.10\,S3000.0,1. 00\,T,X) Exp:SDB5OS
TSIASSLS LASS Taxt:TLIt44376A 153-156
Al.84E7
A1.43E7
36:48
80:
60:
40:
20:
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
TilatU98002B tl-S4S Acq: 6-JAK-1998 18:57:18 SC KH- Voltage SIS 70S Noise:6787
419.8220 T>4 BSUB(256,30,-3.0) PXD<7,5,3,0.10\,27148.0,1.00\,r,T) Eip:SDB5US
TRIANGLE LASS Text:TLIf44376A 153-156
10 0\ A4.J.1Z7
36:48
80:
60:
40:
20:
A3.23E7
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24
TilatU98002B fl-54S Acq: 6-JAN-199B 18:57:18 SC EI+ Voltaya SIS 70S
430.9729 r:4 Zxp:NI)B5US
TRIANGLE LABS TextsTLII44376A 153-156
36:36
36:48
-4.6EB
-.3.7X8
-.2.8E8
li.asa
'.9.2E7
h fl nrn
37:00 Mae
-4.418
'•.3.5X8
.2.7E8
.1. 8E8
-8.9E7
.O.OEO
37:00 Time
4.8E6
'-.3.3S6
-.2.9E6
'-.9.6ES
O.OEO
37iOO
-1.1E7
.8.5E6
.6.3E6
.4.216
.2.1X6
.O.OEO
37:00 Time
1003
80:
60:
40:
20:
oj
35:43
36:00
36:13 36:20
36:33
.2.4X7
il.8S7
\J..2E7
'.5.9X6
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24
Tila:U9B002B tl-545 Acq: 6-J3OT-1998 18:57:18 GC XI+ Voltaga SIS 70S
479.7165 Ti4 ExpiNDBSUS
TRIANGLE LASS Tert:TLIt44376A 153-156
36:36
36:48
1-0,ago
37:00 Hoe
1001
80:
35:17
35:00
35:12
35:24
35:36
35:48
36:00
36:12 36:24
36:36 36:48
-.0.0X0
37:00 Time
115
-------
tl-545 Acq: S-JZlt-lSSB 1B:57:1S SC EH- Voltage SIR 70S Koiae:14723
433.7766 T>4 8SO3(256,30e-3.0) PXD(7,5,3,0.101,58888.0,1.00\rf,T) KxptXDBSUS
TXIAOSLX LABS Text:TLIt44376A 153-156
1003
80.
60.
40.
20.
A2.B3E8
A2.B2X8
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12
Tile:U980028 tl-545 Acq: 6-JJOT-1998 18:57:18 SC XI+ Voltage SIX 70S Soiae:107SO
425.7737 T:4 BSO3(256,30, -3.0) PKD(7,5,3,0.10\,43000.0,1.00\,T,T) Rrp,HDB5VS
TXIASSLE LABS Text:TLIt44376A 153-156
1001 A2.79E8
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18
r±le:O980028 tl-545 Acq: 6-J7OT-1998 18:57:18 SC EI+ Voltage SIX 70S Noise-.5033
435.8169 f:4 3303(256,30,-3.0) PXD(7,5,3,0.10\,20132.0,1.00\,r,T) Exp:HDB5US
TXIASSLE LASS Text:TLIt44376A 153-156
1004 A2.64X7
80.
eo:
4 a:
20:
'.1.3X7
'.O.OEO
36:24 36:30 T±me
-6.1X6
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
T±la:n98002B tl-545 Acq: 6-JMT-1998 18:57:18 SC EH- Voltage SIX 70S Soiae:4736
437.8140 T:4 3SU3(256,30,-3.0) PKD(7,5,3, 0.10\, 18944.0,1.00\,f,T) Kzp:KD35US
TXIASSLE LABS Text:TLIt44376A 153-156
1004 A2.54E7 -6.1X6
ao:
eo:
40:
20:
.4.8X6
.3.6X6
.2.4X6
-1.2X6
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
Tile: US BOO 28 tl-545 Acq: 6-J3Of-1998 18:57:18 SC XI+ Voltage SIX 70S
430.9729 T:4 SxptBDBSUS
TB.IXNSLX LABS TaxtiTLIt44376A 153-156
35:13 -- ~~J5l27
0.0X0
Time
100\
80.
60.
40.
20.
35:22/
35:43 35:49
36:00
36:13 36:20
-2.9X7
.2.4X7
'.1.8X7
'.1.2X7
J.9X6
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
0.0X0
Time
116
-------
441.7428 Ti4 BSOB(256, 30, -3.0) PXD(7,5,3,0.10\,140580.0,1.00\,r,T) XxpiODBSaS
TXIASSLX LASS T*xt:TLI*44376A 153-156
1001 AS. 01X8 -.1.4X8
901
801
7ol
60.
501
401
301
201
lo-
-
1^
J5ioO jff.-OO 37sOO 38:00 ' ' 39,00 ' ' 40:00 ' ' ' 41
ril»:U980028 tl-545 Acqs 6-JZ1T-1998 18:57:18 SC EH- Voltage SIX 70S Boise: 7436
443.7399 T:4 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,29744 .0,1.00\,T,X) XxpsSDSSUS
TXIASSLX LASS Text:TLI*44376A 153-156
1001 A9.16E8
90^
80.
70.
60-
501
40.
301
201
101
a:
Jsioo 36-00 37.' 00
rile, 0980028 41-545 Acqs 6-JZ1T-1998 18:57:18 SC
430.9729 Ts4 Xip:HDB5US
TSIAOSLX LASS Text:TLI*44376A 153-156
1001 35 1 02 35/27 36f,59
3L^^^^^
801
701
601
sol
40.
301
201
101
o:
35\00 36tOO 37:00
rila:0980028 tl-545 Acqi 6-J3UT-1998 13:57:18 SC
513.6775 Ti4 BxptXDBSOS
TSIAWSZX LASS Text:TLH44376A 153-156
1001 35:02
901 1
801 1
™
601 I 36,01
[
<* fti
H fl \r«
iv_.:ip L^ ^Lm
35:00 36:00 37:00
IV
38:00 '39:00 40:00 41
EH- Voltage SIX 70S
37-53 10, *U 40:34
»W^W^—?L;'" wXW»_— -??J ?•£. /»vv._ *®siy\^
3S\00 ' 39:00 ' 40iOO ' 41 1
EI+ Voltage SIX 70S
37:25
j JP»50
1 1 ia if 39tl8 I J
Jw^M^'K8 I 1 JkJIl IU -A 1 fl LilJlMM^JIlL jl jlJ\ J
JfliflO ' J9iOO ' 40>00 41 1
.1.3X8
.1.1X8
.1.0X8
.8.6X7
.7.1X7
.5.7X7
.4.3X7
.2.9X7
.1.4X7
0.0X0
00 Tiae
_1 . 6X8
.1.5X8
.1.3X8
.1.1X8
.9.8X7
.8.2X7
.6.6X7
.4.9X7
.3.3X7
.1 . 6X7
O.OEO
00 Time
.2. 7X7
.2.4X7
.2.1X7
.1 . 8E7
.1.5X7
.1.2X7
.8.8E6
.5.9X6
.2.9X6
0.0X0
00 Time
.1.2X5
.1.1X5
.9.5X4
.8.3X4
.7.1X4
.5.9X4
.4.8X4
.3.6X4
.2.4X4
.1.2X4
0.0X0
00 Tiae
•!
I
-------
39:30 39': 36 39:42 39:48 39*54 40:00
rila:U98Q028 ti-545 Acq: 6-JZJT-1998 18:57:18 GC XX+ Voltage SIS 70S Nolae*1911
469.7773 Tt4 BSVS(256,30,-3.0) fXD(7,5,3, 0.10%, 7644. 0,1.00\,r,T) XzpiHDBSUS
TSIAJKLX LABS Tert:TLIt44376A 153-156
10 OS. A3.12X7
80.
file*OS80028 #1-545 Acq:6-JAN-±y98 18:57:19 SC EI+ Voltage SIS 70S Hoiae*i7oe
457.7377 T>4 3SUB(2S6,30, -3.0) PXD(7,5,3, 0.10\,11064.0,1.00\,r,T) XzpiBDBSUS
TSIAXLX LASS Tmxt:TLH44376A 153-156
100\
39:30 39s36 39:43 39*48 39:54 40:00
ril»*U980028 fl-545 Acqi 6-JXX-1998 18:57:18 GC SH- Voltage SIS 70S Noise:2767
459.7348 Tt4 3SUB(256,30,-3.0) ?XD<7,5,3,0.10\,11068.0,1.00\,T,T) SxpiSDBSUS
T&IASSLX LABS Text:TLIt44376A 153-156
100$
39': 30 39:36 39*43 39:48 39*54 40:00
tl-545 Actj: 6-JJOt-199a 18*S7tl8 GC EI+ Voltage SIS 70S S0±aei944
471.7750 T:4 3SUB(2S6,30,-3.0) PKD(7,5,3,0.101,3776.0,1.00\rf,r) XxptUDBSUS
TBJANGXJ LASS TextiTLI*44376A 153-156
1003, A3.7JZ7
80.
60.
40.
ao:
0.
39:30 39:36 39:42 39*48 39:54
Tile:U980028 tl-545 Acq: 6-JAJf-1998 18:57:18 GC EI+ Voltage SIX 70S
430.9729 Tit ExpiSDBSUS
TBIANGLS LABS TextiTLIt44376A 153-156
100*, 39t33 39,43
40:00
80.
60.
40.
20.
0.
-5.4X7
.4.3X7
.3.2X7
.2.1X7
.1.1X7
.0.0X0
40 06 T±ma
6.3X7
.5.1X7
.3.8X7
.2.5X7
'.1.3X7
40
'.0.0X0
06 Time
5.8X6
'.4.6X6
'.3.5X6
.2.3X6
.1.2X6
40
.0.0X0
06 Time
6.7X6
.5.3X6
.4.0X6
.2.7X6
.1.3X6
.0.0X0
40 06 Time
-2.8X7
.2.2X7
J..7X7
.1.1X7
.5.5X6
0.0X0
39*30
39*36
39*42
39*48
39:54
40100
40 06
118
-------
CD
Peak Locate Examination: 6-JAN-1998:18:55 File:U980028
Experiment:NDB5US Function:2 Reference:PFK
Volts
1.0420
Volts
0.7997
Volts
0.1663
416.93435 416.97604 417.01774
292.95315 292.98245 293.01175
330.94615 330.97925 331.01235
-------
o
C J
File:U980028 #1-723 Acq: 6-JAN-1998 18:57:18 GC EI+ Voltage SIR 70S
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100% A1.17E8
80J
60J
40j
201
_1. 6E7
_1.3E7
_9.7E6
_3.2E6
O.OEO
25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48 25:54 26:00 26:06 26:12 Time
File:U980028 #1-723 Acq: 6-JAN-1998 18:57:18 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100% A1.51E8
0
25:66 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48 25:54 26:00
File:U980028 #1-723 Acq: 6-JAN-1998 18:57:18 GC EI + Voltage SIR 70S
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100%, 25^09
. . , , , r, - O.OEO
26:06 26:12
Time
I ' ' ' T"' i • '
25:00 25:06
I ' • ' • ' I
25:12 25:18
25:30 25:36 25:42 25:48
26:00
26:06 26:12
_2.0E7
Ll.6E7
Ll.2E7
18.1E6
L4.0E6
LO.OEO
Time
-------
Ci
Ile:U980028 #1-723 Acq: 6-JAN-1998 16:57:16 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:NDB5US
ample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100%
80 j
601
40J
20J
0
28:06 28:12 28:18 28:24 28:30 28:36 28:42 28
ile:U980028 #1-723 Acq: 6-JAN-1998 18:57:18 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100%
80J
60 j
40J
20J
OJ
28:06 28:12 28:18 28:24 28:30 28:36 28:42 28:48
File:U980028 #1-723 Acq: 6-JAN-1998 18:57:18 GC EI+ Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100% 28;34
80j
60 j
40_
20_
0_
I '"' '—' ' | '—
28:06 28:12
28:18
' I '
28:24
28:30
i — I — i —
28:36
28 : 42
_2.1E8
_1.7E8
1.3E8
L4.3E7
LO.OEO
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1.4E8
Ll.lEB
L8.4E7
L5.6E7
L2.8E7
LO.OEO
28:54 29:00 Time
_2.1E7
_1.6E7
_1.2E7
L8.2E6
L4.1E6
28:48
' ' I ' '
28:54
LO.OEO
-i—r
29:00 Time
-------
04
File:U980028 #1-385 Acq:6-JAN-1998 18:57:18 GC EI + Voltage SIR 70S
373.8208 F:3 Exp:NDB5US
ample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
100S. A1.50E8
0
33:06 33:12 33:18 33:24 33:30 33:36 33:42
File:U980028 #1-385 Acq: 6-JAN-1998 18:57:18 GC EI + Voltage SIR 70S
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
lOOi A1.2J.E8
80J
60 j
40J
20 j
Oj
33:48
33:06 33:12 33:18 33:24 33:30 33:36 33:42
File:U980028 #1-385 Acq: 6-JAN-1998 18:57:18 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376A 153-156 File Text:TRIANGLE LABORATORIES, INC.
1004 33^22
80J
60J
40j
20 j
Oj
33:48
33:06
33:12
33:18
33:24
33:30
33:36
33:42
33:48
33:54
Time
33:54 Time
_5.3E6
_4.2E6
_3.2E6
_2.1E6
L1.1E6
LO.OEO
33i54 Time
-------
TLI Project: 44376A
Client Sample: 153-156
_«, t: Jh^, ,^ s^^^lii^ss^vlit
Li X <«l C«V«M*MM Tr rtrft rt rtH*S'iirEEif^r'**fciiifc^M*in^Trn
ENfi^SfiftBSH^Hw
$^^C.J~'-
£*™?-$\ " ^
Method 23 TCDD/TCDF Analysis (DB-225)
f ' '. I. Analysis File: P980096
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-11A-D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000
Dry Weight n/a
GC Column: DB-225
Dilution Factor n/a
Blank File: P980094
Analyst JM
Spike File: SPC2NF04
ICal: PF22206
ConCal: P980092
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
g^iiS^tv^^'''^ '~?*mt
m v " v ^^^^s^f; > r
2^,7,8-TCDF 11.6
p|em^$^ri^rd * ' ** -Amt
13C,2-2,3.7,8-TCDF. 2
^Recovery Standard
v RT Ftegs
0.76 23:07
Ratk> RT Flags
0.75 23:06
Ratio RT Flags
13^* i o T >i TfT"NT"^ r\ y^ *} i • ^A
IJV-,i2-ItZ,J,4-iCJJU . I),o2 ^l.^o
Data Reviewer
01/09/98
Page 1 of 1
ONP_PSR vlOl. LAM 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1501/09/98
123
-------
Initial
..Date.
Data Review By:
LI
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/07/98
Listing of P980096B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF 0
304-306 DC ML 0:00
DC WL 18
IS
18
18
19
19
19
19
19
19
20
20
20
20
20
20
21
21
21
21
21
21
22
22
22
22
22
23
23
23
23
23
24
24
25
DC WH 25
:15
:29
:45 RO
:56
:00 RO
:07
:29
:36
:44
:55
:01
:11
:20
:29
:38
:48
:11
:23 RO
:29
:37
:43
:53
:07
:21
:32
:41
:59
:07
:20
:37
:44
:56
:16 RO
:32
:17
:43
.65-0.89
0.76
0.66
0.82
1.31
0.83
1.00
0.84
0.76
0.76
0.75
0.76
0.76
0.77
0.81
0.78
0.75
0.76
0.76
0.63
0.87
0.75
0.74
0.76
0.74
0.75
0.76
0.67
0.76
0.76
0.75
0.75
0.75
0.66
0.97
0.76
0.74
0.66
304-306 34 Peaks
13C12-TCDF
316-318 DC NL 0
DC WL 18
DC WL 19
0.
:00 RO
:32 RO
:18 RO
65-0.89
1.39
1.30
0.22
5.
45.
3,551.
76.
81.
70.
278.
3,941.
3,923.
7,249.
3,091.
510.
3,572.
7,729.
4,205.
11,217.
4 , 118 .
24,265.
33.
45.
4,817.
1,115.
5,398.
5,101.
1,234.
6,779.
40.
5,401.
3,150.
6,047.
7,197.
5,725.
33.
14.
4,161.
729.
43.
134,908.
59
83
20
98
23
45
28
29
45
42
35
71
80
53
00
29
15
40
52
19
35
26
78
22
28
13
75
94
19
59
14
97
08
62
33
02
30
89
0.792-1.101
0.000
1,597
56
36
39
127
1,700
1,688
3,105
1,337
220
1,549
3,470
1,843
4,813
1,772
10,460
14
20
2,065
475
2,323
2,176
528
2,927
16
2,332
1,355
2,599
3,075
2,459
13
8
1,794
310
.23
.95
.78
.65
.12
.87
.13
.33
.56
.62
.54
.36
.23
.21
.12
.30
.58
.97
.19
.99
.21
.95
.81
.28
.31
.77
.56
.99
.43
.30
.11
.04
.70
.35
1,953
43
44
39
151
2,240
2,235
4,144
1,753
290
2,023
4,259
2,361
6,404
2,346
13,805
23
24
2,752
.97
.49
.45
.80
.16
.42
.32
.09
.79
.09
.26
.17
.77
.08
.03
.10
.06
.22
.16
639.27
3,075
2,924
705
3,851
24
3,069
1,794
3,447
4,121
. 3,266
19
8
2,366
418
.57
.27
.47
.85
.44
.17
.63
.60
.71
.67
.97
.26
.63
.67
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.957-
3.
3.
7.
31
72
06
0.
0.
0.
790
800
812
820
823
828
843
848
854
862
867
874
880
887
893
900
917
926
930
936
940
947
957
968
975
982
995
001 2378-TCDF
010
022
027
036
051
062
095
113
1.043
000
802
835
E
E
E
E
E
AM
E
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 02:43 01/07/98
124
-------
Page Ho.
01/07/98
Listing of P980096B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
-- QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.BT Compound.Dame.. ID.. Flags.
316-318
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
WL
WL
WL
WL
WH
WH
WH
WH
WH
WH
WH
6
20:10
30:23
20:33
20:44
21:20
21:33
21:49
22:17
22:24
23:06
23:27
23:42
24:03
24:37
24:42
24:50
25:10
25:15
25:32
25:45
Peaks
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.84
0.60
1.00
0.37
0.74
1.51
0.33
0.39
1.11
0.75
0.74
0.67
0.74
1.36
6.33
2.12
0.57
0.69
0.76
1.86
28.
2.
53.
5.
25.
9.
51.
5.
6.
1,043.
78.
4.
15.
2.
0.
2.
6.
6.
14.
4.
1,154.
23
53
45
38
67
70
90
95
05
58
49
63
72
60
53
27
94
86
96
81
42
2
3
448
33
1
6
.59
.80
.04
.47
.86
.67
6.
3.
595.
45.
2.
9.
58
42
54
02
77
05
0.873
0.882
0.890
0.898
0.924
0.933
0.944
0.965
0.970
1.000
1.015
1.026
1.041
1.066
1.069
1.075
1.089
1.093
1.105
1.115
Above: TCDF / TCDD Follows
0.65-0.89
332-334
DC
DC
DC
DC
DC
DC
DC
DC
ML
SN
SN
SN
SN
WH
WH
WH
4
0:
20:
20:
21:
21:
21:
22:
22:
22:
23:
24:
24:
00
06
30
38
47
56
08
30
42
41
30
40
RO
RO
RO
RO
RO
RO
RO
RO
1.
1.
0.
0.
0.
0.
3.
0.
0.
0.
0.
1.
36
07
61
81
99
32
97
68
74
05
91
13
Peaks
1.
0.
2.
681.
3.
1,148.
0.
1.
8.
0.
3.
2.
1,842.
89
99
23
35
17
77
57
38
82
83
75
80
11
303.92
1.77
516.84
3.76
13C12-2378-TCDF ISO
0.908-1.092
0.000
0.929
377.
1.
631.
5.
43
79
93
06
0.
1.
1.
1.
' 1.
1.
1.
1.
1.
1.
948
000
007
014
023
040
049
095
133
140
13C12-2378-TCDD IS1
13C12-1234-TCDD RSI
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 loos
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
••• End of Report *••
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Belov Signal to Noise Level
-------
flla :P9ao096 tl-92
303.9016 Xxp:DB225
ISIASSZS LASS Taxt: 153-156 VLH44376A
01 ;44:01 £1+ Voltage SIS 7 OP
1001
95.
90.
as:
80:
75:
70:
:
65:
SO:
55:
50:
45:
40.
35.
30:
25:
20:
15J
Iflj
5j
Oj
23 ! 37
22159
-7.6X6
24 i 32
25:1.7
22i36 22t4B 23tOO 23:12 23:24 23,36 23:48 24:00 24:12 '24\24 '24:36'
Tile,P980096 91-922 Ac
-------
rile:P9ao096 tl-931 Acq:7-JAH-Ha Olstlsui E1+ vox cage SIM /OP SOJ.ae:l^J.
303.9016 BSVB(256r30f-3.0) PXD(5,3,1, 0.10%,4840.0, 0. 00\,T,T) Xxp:DB225
TSVUtSLX LASS Taxt:153-156 TLH44376A
19»00 20:00 21:00 23:00 23tOO 24:00
Tila:P9a0096 tl-922 Acq:7-JAK-98 01:44,01 XH- Voltage 315 70P Soiae:1586
305.8937 BSUS(256,30,-3.0) PKD(5, 3,1,0.10\,6344.0,0.00\rr,f) Exp:DB225
TSIABSLX LASS Text: 153-156 TLH44376A
100* A1.38X8
25100
19,00 20': 00 21:00 22:00 23:00 24:00
rile:P980096 tl-922 Acq: 7-JJUT-98 01:44:01 SH- Voltage SIS 70P Xoiaa>1302
315.9413 BSUB(256,30,-3.0) PXD(5,3,1, 0.10\,5208.0, 0.00\,r,f) Exp:DB225
TSIAKSLE LABS Text:153-156 TLH44376A
25:00
lOOi
ao.
so.
40.
20.
A4.48ES
A3.04X5
A2.3SE5
^ _ A
\A3.35E5
A
15:00 20:00 21:00 22:00 23:00 24:00
Tila:P980096 tl-922 Acq: 7-JJOT-98 01:44:01 XH- Voltage SIR 70P Koiae:937
317.9389 BSUB(256f30f-3.0) PU>(S,3,1, 0.10\, 3748.0,0.00\,T,T) Exp:DB225
TBIAXGLE LABS Text: 153-156 TLH44376A
1001 AS 6E6
80.
SO.
40.
25:00
20.
A3.02X5
A _
A4.50E5
19>00 20:00 21:00 22:00 23:00
TiletP980096 H-922 Acqi7-JAK-98 01:44:01 XH- Voltage SIS 70P
375.8364 Elp,DB225
TBIANGLZ LABS Text: 153-156 TLH44376A
1001 23:04
50.
40.
20.
24:00
25:00
Tiae
A3.85E7 A4.12E7
T±mo
.1.2E6
.9.9X5
.7.4X5
.4.9X5
.2.5X5
.0.0X0
Time
.1.7X6
.1.3X6
.9.9X5
.6.6X5
.3.3X5
.0.0X0
Tlae
3.6E4
'.2.9X4
'.2.2X4
25:33.
18:34
'.1 . 4X4
'.7.2X3
19:00
20:00
21:00
22:00
23:00
24:00
25:00
Lo.oro
Tlae
27
-------
TJJ.»:P9BOQ96 il-922 Actj: 7-JAN-SB 01:44:01 EI+ Voltage SIS 70P
319.8965 BSVB(256e30r-3.0) PKD(S,3,1, 0.10\,2888.0,0.00\,T,r) Exp,DB225
XSIASGLX LASS Text: 153-156 TLH44376A
1001
80.
60.
40.
20.
0.
A1.80X7
A4.20X6
fol.94BS
\ A7V
1.33X6
A
A7.55X6
20:00 21:00 22:00 23:00
r±la:P980096 tl-922 Acq:7-JZIT-98 01:44,01 XH- Voltage SIS 70P Noiaes2705
321.8936 aSU3(256,30,-3.0) PKD(S,3,1, 0.10%, 10820.0,0.00\,r,T) XzptD322S
TXIASSLS LASS T&rtj 153-156 TLH44376A
1001
24,00
80.
60.
40.
20.
A2.32E7
AS.16E6
A3.02X6
A ._
A9.SSX6
20:00 21:00 22:00 23:00
rile:P980096 tl-922 Acqs7-JAN-98 01:44:01 XH- Voltage SXB 70P NoiB»,aiO
327.8847 3SVS(256f30,-3.0) PKD(5,3,l,0.10\,3240.0,0.00\,r,r) Xxp:DB225
TSIAHSZX LASS Text: 153-156 TLH44376A
24:00
1001
80.
60.
40.
20.
AJ..59B7
A1.92X7
Al. 09E7
A6.77I6
20:00 21:00 22:00 23:00
F±le:P980096 tl-922 Ac*j:7-JAIT-98 01:44:01 SH- Voltige SIS 70P Noise: 730
331.9368 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,2920.0,0.00\,r,r) Sxp:DB225
TSIASGLX LASS Tart: 153-156 TLH44376A
1001 AS. 17X6
24:00
80.
60.
40.
20.
A3.04X6
20,00 21:00 22', 00 23:00
ril»tP980096 tl-922 Aoq,7-JAR-98 01,44,01 SH- Voltaga SIS 70P Hoie»,535
333.9338 BSUS(256,30f-3.0) PKDfS,3,1, 0.10\,2140.0,0.00\,T,T) Erp,DB225
TSIASSLX LABS Tarti 153-156 TLXt44376A
1001 A6.32X6
24:00
80.
SOL
401
20:
0.
A3.77X6
20:00
21:00
22s 00
23:00
24:00
-8.7X6
.6.9X6
.5.2X6
.3.5X6
o.oro
25 00 Tiae
-1.1*7
.8.9X6
.6. 7X6
.4.5X6
'.2.2X6
25
0.0X0
00 Tia.
5.0X6
.4.0X6
.3. 0X6
.2.0X6
-1.0X6
.0.0X0
25 00 Time
25
.1.1X6
.8.3X5
'.5.5X5
.2.8X5
0.0X0
00 T±m>
-1.7X6
.1. 4X6
.1. 0X6
-6.9X5
-3.4X5
.0.0X0
25:00 Time
123
-------
r±leiP980096 tl-922 Acq:7-JAK-9a 01:44:01 SI+ Voltage SIX 70P
303.9016 KxpiSB225
TSIAHSZX LABS Text: 153-156 TLH44376A
ion
80.
SO.
40.
20.
0.
k 31; 11
A
1 1 1
19:44 fl 1 i 22*32 23.37
19t29\\ A * 11 II A A A 11 A A llA 24 1 32
A A A 11 A A /I A /• 1 A II A ii A fl /I A 11 ft/l A
A '/\/\il A A/ v/v 1/1 11 l\ l\ l\ l\ l\l\ l\ /I/I A
/ L_ _j » V v / \yv 7 v v V / V ] *^.7 V 7 \ y\ /V /VVyV/v 7V ^^
-1.717
Ll . 4JT7
.1 . 017
.5.8W
.3.4X6
15(00 30:06 21:00 22:00 23:00 34:00 35:00 Time
Tile:P9a0096 tl-922 Acq:7-JAH-98 01:44:01 EH- Voltage SIX 70P
315.9419 XxptDB225
TRIASSLX LABS Text: 153-156 TLIt44376A
1001
80.
SO.
40.
20.
33:05
20'33 31,49 1
"* •*^- i~i r i IA J *- A.
-1.2X6
.9.9X5
.7.5X5
.5.0X5
-.2.5X5
15:00 30:00 31:00 22:00 ' 33:06 ' 24:00 ' 25:00 Tiae
r±letP980096 tl-922 Ac17
15:53
1
1 30:31 31:55
A A 31il6 \
\ \ A A A A _ ^W V ^ .
8.7X6
-.6.9X6
-.5.2X6
'-.3.5X6
.1 . 7X6
'• o.oxo
15:00 30:00 31:00 33:00 3J:00 34:00 35:00 Tiae
rlleiP980096 tl-922 Acq:7-JJOt-98 01:44:01 XX+ Voltage SIX 70P
331.9368 Xxp:DB225
TSIAJKLX LABS Text: 153-156 TLH44376A
1001
80:
50:
40:
30:
31:55
T
/i n
1 . 4X6
'•.1.1X6
.8.3X5
.5.5X5
.2.8X5
0.0X0
15:00 30:00 31:00 33:06 33:06 34:06 35:06 Tiae
rllosP9B0096 tl-922 Adj:7-JXS-98 01:44:01 XH- Voltage SIX 70P
292.9825 XipiDB225
TXIAKSLX LABS Text: 153-156 TUt44376A
1002
80:
50:
40:
30:
0:
l^:4S15«33 15:55 30:38 31:3531:51 23^38 33:14 24j22 35:30
N^^f^^^^^^ -vr^.tf^ .v, . YV^^_r^v^v^^7^rv^r^
1
.1.2X7
.9.7X6
.7.3X6
.4.9X6
.2.4X6
0.0X0
15:06 3oio6 3lio6 331-06 ' ' 33:06 ' ' 34:06 ' 35:06 ' Time
r±le:P9B0096 tl-922 Acqt7-JJUT-98 01:44:01 XH- Voltage SIX 70P
330.9792 XxpiDB225
TXIABGLX LABS Text: 153-156 XLIt44376A
1001
80:
50:
40:
30:
o:
15:37 *ii°S. aiifA^ 22 1 36 23 1 05 23 1 33 34:3334:4535:15
VM)|(w^Vvl/vu/w«-^V^4y->>^VYT^^
.1.1X7
.8.6X6
.6.4X6
.4.3X6
.2.1X6
0.0X0
15:00 30:00 31:00 33:00 33:00 34:00 35:00 Time
129
-------
Ref. lass 232.9825 Peak top
HelpJ* 2.18 volts Span 208 ppi
Systei f lie naie
Data fUenaie
Resolution
Group nmter
lonlzatlon Nde
Pitching
Ref. lasses 292.9825,
fl 292.9825
B 383,9818
D 315.9419
E 317.9389
F 319.8965
G 321.8938
H 327.8847
338.9792
J
K
L
H
ft;
1
El*
VOLTAGE
388.9761
338.9792
331.9368
375.8364
Channel I 338.9792 Peak top
Height 1.68 volts Span 288 opt
130)
-------
TLI Project: 44376A
Client Sample: 157-160/166 f-
r
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980029
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-12A-E Date Extracted: 12/29/97
DateAnalyzei 01/06/98
1.000 Dilution Factor n/a
n/a Blank File: U980026
DB-5 Analyst: BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U98002S
n/a
n/a
n/a
Anaiytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3.7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2.3,4,6,7,8.9-OCDD
2,3,7.8-TCDF
1,2,3,7,8-PeCDF
2,3.4.7.8-PeCDF
1 2J,4.7,8-HxCDF
".2,3.6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8.9-HxCDF
l,2J,4,6,7,8-HpCDF
1,2.3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
*>
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
AWt, {ng} Dfc. "1EMPC
0.71
5.0
5.4
8.1
11.9
55.4
87.1
76.6
15.7
31.9
98.8
35.5
53.9
3.1
200
34.5 i .
-^\-LQ fifi7 ~ CA^- II ' '
Amt (ng) Number m. EMPC
143 12
103 9 161
154 6 160
114 2
441 16
419 14 423
417 12
346 4
'? ' ftetto
0.74
1.55
1.24
• 1.27
1.25
1.02
0.84
0.75
1.61
1.58
1.26
1.26
1.26
1.30
1.04
1.04
0.91
- ,
RT
25:21
29:37
32:45
32:50
33:07
36:03
39:38
24:41
28:35
29:17
32:02
32:09
32:38
33:23
35:02
36:34
39:50
Ffags
PR_
E_
E_
E_
E_
E_
PRX
E_
SE_
Flags
QE_
E_
E_
E_
E_
E_
E_
E_
Page 1 of 2
Mn7.PSRvl.01.LARS6.ia08I
Triangle Laboratories, lnc.3
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1801/10/98
131
-------
TLI Project 44376 A
Client Sample: 157-160/166
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980029
\tatern&Standard» ->— - •*<*
13C,2-2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13C,2-U,3,7,8-PeCDD
13C,rU^,6,7,8-HxCDF
l3C,2-l,2,3,6,7,8-HxCDD
13C,2-lA3,4,6,7,8-HpCDF
13C,2-1^3,4,6,7,8-HpCDD
I3C 12- 1 ,2,3 ,4,6.7,8 ,9-OCDD
Surrogat&StendaKJs {type A)
13C,2-2,3.4,7,8-PeCDF
13C12-U,3,4,7,8-HxCDF
13C12-l,2.3,4,7,8-HxCDD
13Ci2-U,3,4,7,8,9-HpCDF
Surrogate Standards (Type A)
"CU-2,3,7,8-TCDD
Alternate Standards {Type A}
13Ca-l,2,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
uCu-lA3,7,8,9-HxCDD
r»AML-fr&~
2.7
2.5
2.7
3.1
3.1
3.0
63
Afl*£»S)
3.6
4.0
3.9
3.9
Aflttv §!§}
3.2
Aim.$i^
2.9
3.0
-;-
-:T^RBcOvfflT~
62.7
63.2
66.4
63.0
67.6
77.1
77.2
74.0
78.3
% Recovery
91.2
99.2
96.7
97.9
% Recovery
80.6
% Recovery
72.1
75.0
«0«v ,,, .v
40%-130%
40%- 130%
40%-130%
40%-130%
40%- 130%
40%-130%
25%-130%
25%-130%
25%- 130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
';'~8*to^:
0.75
0.81
1.57
1.52
0.53
1.21
0.45
1.07
0.87
Ratio
1.45
0.53
1.20
0.44
Ratio
0.52
0.56
Ratio
0.81
1.21
^jn^-jRags ^
24:39
25:20
28:35
29:36
32:09
32:48
35:01
36:03
39:37
RT ftegs
29:16
32:03 __
32:44
36:33
RT Bags ,
25:21
RT Flags
33:23
32:38
RT Flags
25:10
33:08
Data Reviewer
01/10/98
Page2of2
MTn_PSR »1.01, LARS & 10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:18JD1/10798
i. o i-
-------
Data Review'By:
Initial
fy.
. .Date..
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/10/98
Listing of O980029B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF 0
304-306 OC NL 0:00 RO
KN 21:29
K 22:00
K 22:14
K 22:37
K 22:56
K 23:20
K 23:36
23:50
24 :03
24:15
24:28
24 :41
25:04
25:17
25:33
26:23
304-306 16 Peaks
|l3C12-TCDF 0.
316-318 DC NL 0:00 RO
DC WL 23:00
24 : 05 RO
24:39
316-318 2 Peaks
.65-0.89
0.59
0.75
0.74
0.74
0.75
0.75
0.73
0.75
0.75
0.79
0.75
0.75
0.75
0.75
0.74
0.73
0.77
2,
65-0.89
1.34
0.66
1.04
0.75
0.867
4,654
70,734
71,500
74,434
374,158
231,515
243,962
174,584
222,451
275,262
113,621
.53
.70
.80
.60
.00
.70
.00
.70
.50
.00
.60
101,101.90
460,610
113,330
96,909
14,998
12,461
651,637
.00
.40
.60
.69
.11
.30
30,424
30,447
31,535
160,127
99,151
102,610
74,746
95,642
121,763.
48,611.
43,196,
197,948.
48,408.
41,308.
6,335.
5,408.
.20
.40
.90
.00
.70
.00
.50
.50
,00
.50
,00
.00
90
.10
38
43
40,
41,
42,
214,
132,
141,
99,
126,
153,
65,
57,
262,
64,
55,
8,
7,
310
053
898
031
364
352
838
809.
499.
010.
905,
662.
921.
601.
662.
052.
.50
.40
.70
.00
.00
.00
.20
.00
.00
.10
.90
.00
.50
50
81
68
0
0
0
0
0
0
0
0
0
0
0
0.
1.
1.
1.
1.
1.
-1.079
.000
.872
.892
.902
.918
.930
.947
.957
.967
.976
.984
.993
.001 2378 -TCDF AN
.017
.026
037
070
E
'E
QE
E
E
E
E
0.959-1.041
92
550
351
19,404
19,755
.48
.81
.73
.20
.93
206.
8,293.
74
10
11,
198.
111.
72
10
0.
0.
0.
1.
000
933
977
000 13C12-2378-TCDF ISO
Above: TCDF / TCDD Follows
TCDD
320-322 DC NL 0
NK 22
NK 23
K 23
D D SN 23
D D SN 23:
D D SN 23:
D D SN 23:
K 24:
24:
24:
M 25:
AN 25:
25:
0.
:00 RO
:48
:12
:29
:43 RO
:52 RO
:52 RO
:58 RO
ill
:27
:50
;15
:21
32
65-0.89
0.05
0.70
0.78
0.74
1.63
1.18
1.13
2.31
0.82
0.75
0.80
0.75
0.74
0.73
0.895-
37
282,030
163,874
20,505
1,147
464
609
320
63,021
32,116
15,186
60,400
3,280
7,033
.54
.00
.80
.63
.51
.20
.80
.39
.90
.10
.02
.00
.00
.78
116,595
71,703
8,742
28,386.
13,789,
6,744.
25,900.
1,400.
2,969.
.00
.20
.13
.10
,60
,66
,00
00
55
V.
165,
92,
11,
34,
18,
8,
34,
1,
*,
435
171
763
635.
326.
441.
500.
880.
064.
.00
.60
.50
80
50
36
00
00
23
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
•1.047
000
900
916
927
936
942
942
946
955
965
980
997
001 2378 -TCDD
008
E
QE
AN PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:18 01710/98
133
-------
Page No. 2
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of 0980029B.dbf
Matched GC Peaks / Ratio / Bet. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name. . 10.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
25
25
26
:40
:54
:20
0.73
0.66
0.74
12 Peaks
DC ML 0
DC WL 22
DC WL 22
. DC WL 23
DC WL 23
23
23
24
24
24
24
24
25
25:
:00
:39
:49
:05
:12
:25
:58
:11
:19
:27
:40
:50
:21
44
9 Peaks
0
DC NL 0:00 RO
24:11
24:
42 RO
25:10
332-334
PeCDF
340-342
M
AN
25:
25:
25:
25:
20
39
53 RO
56 RO
7 Peaks
DC NL 0:
26:
26:
27:
27:
27:
27:
27:
27:
28:
28:
28:
28:
28:
28:
29:
1.
00 RO
36
48 RO
04 RO
14 RO
22 RO
36
44
55
12
19
30
35
45
52
17
.65-0.89
1.63
0.67
1.22
0.81
0.81
0.77
1.05
1.51
6,746.39
2,589.37
2,162.91
658,946.90
164.66
65.15
1,517.08
640.72
966 . 28
274.46
19,256.70
537.07
372.94
157.60
556.72
218.26
12,032.60
14,645.30
48,051.65
2,850
1,032
917
274
19,256
537
372
157
556
218
12,032
14,645
.86
.12
.71
.46
.70
.07
.94
.60
.72
.26
.60
.30
3,895
1,557
1,245
.53
.25
.20
0.
1
1
1
921
0
0
0
0
0
0
0
0
0
0
0
0
1
1
.013
.022
.039
-1.079
.000
.894
.901
.911
.916
.924
.946
.955
.960
.965
.974
.980
.001 37C1-TCDD
.016
CLS
0.921-1.079
29.95
Il5 . 17
41.63
21,107.87
14,916.33
1,003.84
73.79
181.46
37,440.09
32-1.78
0.76
1.53
0.77
4.35
6.54
4.88
1.71
1.55
1.66
1.61
1.57
1.57
1.61
1.66
1.66
1.58
24.07
169,674.90
9,224.95
2,553.29
1,345.56
1,878.79
53,521.80
368,690.00
88,383.70
158,042.20
198,580.30
87,800.00
66,200.00
62,253.60
112,576.90
130,284.70
46
28
9,471,
6,681.
437.
43.
154.
.05
.77
.57
.33
.57
.70
.49
69.
23.
11,636.
8,235.
566.
41.
102.
.12
.52
30
00
27
69
52
0
0
0
0
1.
1,
1,
1.
.000
.955
.975
.993 13C12-1234-TCDD
.000 13C12-2378-TCDD
.013
.022
.024
RSI
IS1
102,544.
5,607.
4,356.
3,449.
3,594.
33,770.
223,864.
55,159.
97,398.
121,294.
53,600.
40,800.
38,813.
70,277.
79,692.
00
32
90
71
19
00
00
20
20
00
00
00
00
20
00
67,130.
7,279.
1,001.
527.
736.
19,751.
144,826.
33,224.
60,644.
77,286.
34,200.
25,400.
23,440.
42,299.
50,592.
0.925-1.065
90
42
29
67
78
80
00
50
00
30
00
00
60
70
70
0.
0.
0.
0.
. 0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
000
931
938
947
953
957
966
970
977
987
991
997
000 12378-PeCDF
006
010
024 23478-PeCDF
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:18 01/10/98
134
-------
Page No.
01/10/98
Listing of 0980029B.dbf
Matched GC Peaks / Ratio / Ret. Ti
Compound/
M_Z.... QC.Log Omit Why
,RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
29
29
30
30
:26
:44
:07
:15
RO
1
1
4
1
.54
.71
.46
.60
19 Peaks
DC NL 0
26
26
27
27
28
28
28
29
29
29
29
29
30
:00
:36
:47
:46
:56
:19
:35
:52
:04
:16
:35
:42
:52
:06
30:16
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
.32
1
1
1
1
1
30
1
1
1
1
1
1
0
1
0
14 Peaks.
DC NL 0:
DC WL 27:
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
00
36
51
19
32
41
52
02
08
19
28
37
45
05
1.
RO
RO
RO
RO
RO
-1.78
.08
.80
.58
.40
.43
.76
.57
.15
.97
.45
.58
.07
.67
.89
.75
181
44
15
1,751
16
14,
,151.70
,196.70
392.83
,235.04
,986.96
33.36
97.08
133.58
265.72
739.35
396.65
,016.44
649.58
145.40
.107.16
459.85
234.90
130.28
80.94
111.99
33,568.92
32-1.78
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
.92
69
31
36
53
60
57
79
44
56
98
55
60
62
12 Peaks
DC NL 0:
27:
28:
28:
28:
28:
29:
29:
00
48
17
33
42
52
03
20
1.
RO
RO
RO
RO
RO
RO
32-
1.
4.
2.
1.
1.
1.
0.
0.
1.78
15
30
73
71
09
58
32
34
131,
10,
98,
15,
68,
7,
17,
26,
12,
13,
10,
8,
420,
12.77
983.28
094.84
440.93
612.70
436.68
591.40
989.76
334.86
946.10
093.58
177.15
543.65
107.54
369.19
109,717
27,915
686
9,386
68
81
155
435
4,783
9,791
394
112
8,338
281
142
79
60
68
.00
.10
.87
.42
.51
.80
.14
.24
.95
.10
.84
.21
.52
.76
.78
.19
.02
.07
71,434
16,281
154
5,848
38
51
110
304
155
6,225
344
57
5,768
178
133
118
31
90
.70
.60
.05
.62
0.
.07
.78
.58
.11
.55
.34
.47
.02
.64
.09
.88
.35
.74
.85
1.030
1.040
1.054
1.058
860-1.140
0.000
0.931
0.937
0.971
0.977
0.991
1.000 13C12-PeCDF 123 IS2
1.010
1.017
1.024 13C12-PeCDF 234 SOR1
1.035
1.039
1.045
1.053
1.059
79,685.10
6,012.81
59,647.60
9,502.
.51
41,949.10
5,593.
.27
10,240.20
16,428.
90
7,351.00
8,002.41
6,485.
5,009.
96
36
60,994.
4,428.
38,965.
5,934.
26,642.
3,133.
7,094.
10,517.
7,514.
5,174.
4,057.
3,097.
0.935-1.022
.20
,12
10
17
30
24
66
20
00
74
69
68
0.000
0.932
0.941
0.957
0.964
0.969
0.975
0.981
0.984
0.990
0.995
1.001 12378-PeCDD AN
1.005
1.016
0.865-1.135
12.63
72.27
39.17
56.01
14.54
19.37
20.53
61.91
121.
41.
35.
8.
11.
12.
37.
73
97
34
84
87
48
63
28.
15.
20.
8.
7.
38.
111.
34
36
67
13
50
63
26
0.000
0.939
0.956
0.965
0.970
0.975
0.981
0.991
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1801/10/98
125
-------
Page So. 4
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of 0980029B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
AN
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
D
29
29
30
30
30
30
30
:36
:44
:05
:17
:24
:29
:36
1
1
RO 0
RO 1
RO 1
RO 0
RO . 0
14 Peaks
.52
.65
.45
.86
.09
.33
.30
7,848.71
1,355.30
141.37
97.41
132.44
225.12
324.18
10,408.33
nw_..._. . n^f+nn / u
1.05-1.43
DC NL 0
31
31
31
31
'31
32
32
32
32
32
X 33
33
:00
:06
:14
:24
:32
:41
:02
:09
1
1
1
1
1
1
1
.25
.26
.26
.30
.23
.27
.26
1.26
:16 1.29
:26
:38
:23
:28
1,
1.
1.
1.
12 Peaks
.24
.26
.30
,25
1
7,026.95
140,660.80
317,799.00
31,584.30
45,572.90
25,270.90
297,473.00
133,092.30
39,335.70
56,792.90
158,650.30
8,080.00
36,600.00
,290,912.10
4,730
843
85
71
80
136
197
.01
.18
.93
.02
.50
.34
.05
3,118
512
192
38
74
420
647
.70
.12
.81
.20
.10
.41
.30
1.000 13C12-PeCDD 123 IS3
1.005
1.016
1.023
1.027
1.030
1.034
78,431
177,313
17,851
25,150
14,132
165,937
74,104
22,160
31,387
88,494
4,570
20,300
.80
.00
.70
.20
.90
.00
.50
.50
.20
.50
.00
.00
62,229
140,486
13,732
20,422
11,138
131,536
58,987
17,175
25,405
70,155
3,510
16,300
0.43-0.59
DC NL 0:
31:
31:
31:
32:
32:
32:
32:
32:
33:
00
13
31
50
03
09
26
38
55
23
RO 0.
RO 1.
RO 1.
RO 1.
0.
0.
RO 0.
0.
RO 2.
0.
9 Peaks
DC NL 0:
D SN 31:
31:
32:
32:
32:
32:
32:
33:
00
26
35
01
14
24
45
50
07
1.05-
RO 0.
RO 0.
1.
1.
1.
RO 1.
1.
1.
1.
77
07
61
75
53
53
36
56
15
52
115.38
452.88
154.52
93.36
9,790.49
11,961.66
471.12
11,966.56
303.92
8,871.10
44,065.61
— &H/MTA • Hvf*mi* / It'
AJjOVe . nXL.L/£ / HJ
1.43
63
49
26
22
24
00
24
27
25
1,296.83
1,066.98
25,794.00
194,623.70
69,233.30
12,414.51
10,433.29
20,048.12
28,354.00
319,
164.
108.
.68
,29
,15
3,395.73
4,138.
,76
159.12
4,307.
433.
3,023.
66
32
48
299.
102.
61.
6,394.
7,822.
438.
7,658.
201.
5,847.
0.962-1.047
.00
.00
.60
.70
.00
.00
.80
.20
.70
.80
.00
.00
0.000
0.967
0.971
0.977
0.981
0.985
0.996 123478-HxCDF AN
1.000 123678-HxCDF AN
1.004
1.009
1.015 234678-HxCDF AN
1.038 123789-HxCDF AN
1.041
E
E
E
E
PR
0.876-1.124
.92
.33
,83
76
90
99
90
27
62
0.000
0.971
0.980
0.990
0.997 13C12-HXCDF 478 SOR2
1.000 13C12-HXCDF 678 IS4
1.009
1.015 13C12-HXCDF 234 ALT2
1.024
1.038 13C12-HXCDF 789 ALT1
14,395.
107,046.
38,268.
6,872.
5,774.
11,199.
15,777.
80
00
90
32
74
00
10
11,398.
87,577.
30,964.
6,890.
4,658.
8,349.
12,576.
0.958-1.014
20
70
40
22
55
12
90
0.000
0.958
0.963
0.976
0.983
0.988
0.998 123478-HxCDD AN
1.001 123678-HxCDD AN
1.010 123789-HxCDD AN
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1801/10/98
136
-------
Page No.
01/10/98
Listing of (J980029B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
390-392
7 Peaks
360,900.92
13012-HxCDD
402-404
402-404
HpCDF
408-410
408-410
r HpCDF
418-420
418-420
HpCDD
424-426
D
D
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
DC
NL 0:00
32:44
32:48
33:08
3 Peaks
1.05-1.43
1.28
1.20
1.21
1.21
49.51
7,138.51 3,892.28
10,086.19 5,527.69
13,149.04 7,205.62
0.970-1.030
0.000
3,246.23 0.998 13C12-HXCDD 478 SOR3
4,558.50 1.000 13C12-HXCDD 678 IS5
5,943.42 1.010 13C12-HXCDD 789 RS2
30,373.74
0.88-1.20
DC
DC
DC
DC
NL 0:00
35:02
35:18
35:27
NH 35:55
NH 36:00
36:34
4 Peaks
NL 0:00
35:01
36:33
2 Peaks
RO 1.25
1.04
1.05
1.06
0.97
RO 1.40
1.04
0.37-0.51
RO 1.80
0.45
0.44
388.62
588,703.00 300,809.00
125,484.30 64,195.70
165,389.90 84,938.20
2,430.58
2,241.33
78,802.90 40,254.30
958,380.10
54.16
8,347.82 2,582.48
6,553.21 2,009.07
0.996-1.049
0.000
287,894.00 1.000 1234678-HpCDF AN
61,288.60 1.008
80,451.70 1.012
1.026
1.028
'38,548.60 1.044 1234789-HpCDF AN
0.943-1.114
0.000
5,765.34 1.000 13C12-HpCDF 678 IS6
4,544.14 1.044 13C12-HpCDF 789 SOR4
E
E
E
14,901.03
0.88-1.20
DC
DC
DC
DC
NL 0:00
WL 35:10
35:18
NH 35:35
36:03
2 Peaks
NL 0:00
36:03
1 Peak
RO 1.53
RO 0.44
0.97
RO 0.60
1.02
0.88-1.20
1.10
1.07
75.56
29,813.03
103,113.80 50,872.60
7,956.96
97,271.20 49,025.30
200,385.00
53.36
7,059.90 3,641.62
7,059.90
0.76-1.02
DC
DC
NL 0:00
39:50
1 Peak
NL 0:00
39:38
RO 4.34
0.91 1,
1,
0.76-1.02
0.77
0.84
66.19
268,705.00 604,537.00
268,705.00
21.91
135,424.50 61,921.40
0.975-1.005
0.000
0.975
52,241.20 0.979
0.987
48,245.90 1.000 1234678-HpCDD AN
0.972-1.028
0.000
3,418.28 1.000 13C12-HpCDD 678 IS7
0.899-1.101
0.000
664,168.00 1.005 OCDF AN
0.899-1.101
0.000
73,503.10 1.000 OCDD AN
E
E
SE
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:18 01/10/98
-------
Page No. 6 Listing of 0980029B.dbf
01/10/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
458-460 1 Peak 135,424.50
13C12-OCDD 0.76-1.02 0.996-1.004
470-472 DC NL 0:00 RO 1.42 15.01 0.000
39:37 0.87 11,219.87 5,204.93 6,014.94 1.000 13C12-OCDD IS8
470-472 1 Peak 11,219.87
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Masa(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:as) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OR -RO-Ratio Outside Limits
-------
rilo:O980029 tl-724 Acq: 6-JKS-1998 19:43:44 GC EH- Voltage 515 705 Boiamtl012427
303.9016 T:2 BSUBf 256, 30, -3. 0) PXD(9,5,3,0.10\,4049708.0,1.00\,T,T) XxpiSDBSVS
TRIANGLE LABS Text: 157-160/166 TLIt44376A
1001
80.
60.
40.
20.
A1.98E9
A1.22E9
A1.60E9 _ t_ „ A
A A7.47S8 l\
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J05.W87 T:2 BSUB(256,30,-3.0) PXD(9,5,3,0.10\,6899640.0,1.00\,F,T) XxpiNDBSUS
TRIANGLE LASS Text: 157-160/166 TUt44376A
1001
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A1.53E9
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315.9419 f:2 BSUB(256, 30, -3.0) PKD(9, 5, 3,0. 101,139616. 0,1.00\,f,T) ExpsSDBSOS
TRIANGLE LABS Text: 157-160/166 TLI044376A
looa
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20:
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317.9389 f:2 BSUB(256, 30, -3. 0) PKD(9,5,3,0.10\,104496.0,1.00\,r,T) XxpsNDBSOS
TRIANGLE LASS Text: 157 -160/166 TLH44376A
1001
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r±le:0980029 tl-724 Acq: 6-J3UT-1998 19:43:44 GC EH- Voltage SIR 70S
330.9792 7:2 ExpiNDBSOS
TRIANGLE LABS Text: 157-160/166 TLH44376A
1001
80:
50:
40:
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o'-
21^48 22:50 23:2823:48 24^10^ 24:57 35,19 25:4426:0426:24
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375.8364 7:2 ExpiNDBSUS
TRIANGLE LASS Taxtt 157 -160/166 TLH44376A
1001
80:
50:
-------
Fila:0980029 tl-724 Acq: 6-JAN-1998 19:43:44 SC XH- Voltage SIS 70S tfoiae:8164
319.8965 r:2 SSUB(256,30, -3.0) PXD(7,5,3,0.10\,32656.0,1.00\,r,T) XxpsKDBSVS
TSIANGLX LABS Text: 157-160/166 TLIt44376A
1004
80:
50:
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A7.17X8
A8.74X7
A2.84EB
/\A1.38*8 A6.7417
^X"^^ •S^
23:00 24:00 25:00 26:00
rU.e:0980029 tl-724 Acq: 6-JZJT-1998 19:43:44 SC XH- Voltage SIS 70S Noiae:167392
321.8936 Ti2 SSUS(256,30,-3.0) PXB(7,5,3,0.101,669568.0,1.00\,f,T) Xxp:ODB5US
TSIANGLX LABS Text: 157-160/166 TLH44376A
100\
80:
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40:
20:
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A9.22X8
A3. 46X8 .
A1.83X8 A8.44X7
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23:00 24:00 25:00 26:00
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331.9368 T:2 BSUB(256,30,-3.0) PKD(7,S,3,0.10\,55140.0,1.00\,r,T) Xxp:SDB5US
TSIAXGZE LASS Text: 157-160/166 TLIt44376A
100* A9.47X7
80.
60:
40:
20:
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6.68X7
23:00 24:00 25:00 26:00
rile:OSa0029 tl-724 Acq: 6-J7OT-1998 19:43:44 SC XH- Voltage SIS 70S Soiae:8460
333.9338 F:2 BSUS(256,30, -3.0) PKD(7,5,3, 0.10%,33840.0,1.00\,T,T) XxpsSDBSUS
TSIANGLX LASS Text: 157-160/166 TLIt44376A
1001 Al.i6E8
80:
60:
40:
20:
B. 23X7
23:00 24:00 25:00 26:00
rile:U980029 tl-724 Acq: 6-JJOT-1998 19:43:44 SC XH- Voltage SIS 70S B6lae:82332
327.8847 T:2 BSO3(256,30,-3.0) PKD(7,5,3,0.10\,329328.0,1.00\,f,T) Xxp:SDB5US
TRIANGLE LABS Text:157-160/166 TLIt44376A
1001
so:
60:
40:
20:
Al . 93X8
A1.46X8
A1.20X8
24:00 25:00
Tlle>O9B0029 tl-724 Acq: 6-JAK-1998 19:43:44 SC XI+ Voltage SIS 70S
330.9792 Ti2 XxpiRDBSUS
TRIANGLE LABS Text: 157-160/166 TLIt44376A
26:00
1001
80:
sol
40:
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0.
22:50
4:27
24:5725:13
25:44 36:04 .26:24
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0.0X0
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140
-------
rilesa980029 tl-724 Acqs 6-JXX-1998 19:43:44 SC Eli
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339.8597 Ts2 BSUS(256, 30, -3.0) na>(7r5,3,0.10\f29268.0,1.00\,r,T)
XRIASSLX LABS Texts 157-160/166
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A1.03X9 1
A
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341.8567 ts2 BSUB(256,30,-3.0) PXD(7t5,3,0.10\,3a568.0,1.00\,r,T) XxpsSBBSUS
TRIASSLX LABS Text: 157-160/166
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351.9000 Ts2 BSUB(256,30,-3.0) rXD(7,5,3,0.10\,40568.0,1.00\,T,T) XxpsSDBSOS
TRIASSLX LABS Texts 157 -160/166 TLIt44376A
1003
sol
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27:00
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TRIANGLE LABS Texts 157-160/166 TLIt44376A
100J
80:
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40:
20:
27:00
A6.
A3. 04X6 ,
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28:00
rilatO9a0029 tl-724 Acq: 6-JXM-1998 19:43:44 SC XI+
330.9792 f:2 XxptSDBSOS
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25:00
v
J0:00
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TRIASSLX LABS Texts 157 -160/166 TLH44376A
ion
ao:
60:
40:
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26±54 27:20 27:40 28:05 28:34^ 29:03 _J9_sJ7 31
27:00
V
28:00
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409.7974 rt2 ExpiNDBSUS
25:00
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TRIASSLX LABS Text: 157-160/166 TLI044376A
1001
80:
50:
40:
20:
25:48 ,, „-, r?.
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19 -8.6X5
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141
-------
f3-La:OSaooS3 il-714 Acq: 6-JAK-199S IS:43144 SC EI+ Voltage SIS 70S Noiae:JB80
355.8546 F:2 BSOB(256,30, -3.0) ?XB(5,5,3,O.OS\, 15520.0,1.00\,T,T) XxpiHDBSOS
TSIAHSLX LASS Text: 157-160/166 TLH44376A
100$ A7.97X8 AS. 96ft
80.
60.
40.
20.
A4.19X8
A6.01X7
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357.8516 Ti2 SSVB(256,30,-3.0) rXD<5,5,3,0.05\,16832.0t1.00\,r,T) XxptODBSUS
XSIANGZX LASS left: 157-160/166 TLH44376A
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27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
r±le:O980029 tl-724 Acq: 6-JJOT-1998 19:43:44 GC EI+ Voltage SIS 70S lToiaa:3842
367.8949 T:2 SSUS(256,30, -3.0) PXD(S,5,3,0.05\,15368.0,1.00\,T,T) Xxp:SDS5US
TRIANGLE LASS Text: 157-160/166 XLH44376A
10M A4.73X7
80.
60.
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rlle:a980029 tl-724 Acq: 6-JXK-1999 19:43:44 GC EH- Voltage SIS 70S So±ae:3330
369.8919 T:2 3SUB(256,30,-3.0) PXD(5,5,3,0.05\,13320.0,1.00\,TrT) Xxp:SDS5US
TSIAKGLX LASS Text: 157-160/166 TLH44376A
1001 A3.12X7
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•U»:O980029 tl-724 Acq: 6-JAB-1998 19:43:44 GC EI+ Voltage SIX 70S
330.9792 T:2 Sxp:«DS5aS
TBXANGLX LASS Text: 157-160/166 TLH44376A
0.0X0
Time
1001
80.
60.
40.
20.
0.
27:54 28:05 28:16
28:34
30:19
27I:48' 28:00' 28:12 28:24 28:36 28:48 29:00 29:12 29:24' 29':36 29:48 30:00 30:12 30:24
.8.8X7
.7.0X7
.5.3X7
.3.5X7
1.8X7
0.0X0
Time
142
-------
Tlle:O9S0029 tl-385 Acq: 6-JZS-1998 19:43:44 GC XH- Voltage SIX 70S Noiae: 1950039
373.8208 T:3 BSU3(256,30, -3. 0) ?KD(7,5,3,0.10\,7t00116.0,1.00\,T,T) ExpiNDBSUS
TSIAHSLX LASS Text: 157-160/166 TLH44376A
100J
80.
so:.
40:
20:
Al
A7.84XS
77X9
A3.. 66X3
AS. 85X8
A3.10X8
31tOO 31:12 31:24 31,36 31:48 32:00 33:13 32:24 32:36 32:48 33,00 33,12 33:24 33:36 33:48
rile:U9B0029 tl-385 Acq: 6-JAN-1998 19:43:44 CC IT* Voltage SIS 70S Noiae, 1563444
375.8178 Ti3 BSUB(256,30, -3.0) fXD(7,5,3,0.10\r6353776.0,1.00\,T,T) XxpiSDBSOS
LASS Text: 157-160/166 TLIt44376A
A1.32X9
ion
so:
50:
40:
20:
A6.22X&
A7.02X8
A2.04X8
A1.65E8
31:00 31:12 31:24 31:36 31:48 32:00 32,12 32:24 32:36 32:48 33,00 33:12 33:24 33:36 33:48
r±lo:O9S0029 tl-385 Acq: 6-JXH-1998 19:43,44 SC XZ+ Voltage SIS 70S Noise:29516
383.8639 Ts3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\r118064.0,1.00\,r,T) ExpiHDBSUS
ZBXAXSZX LASS Text: 157-160/166 TLH44376A
lOOi
80:
60:
A3.20E6
40:
20:
ol
31:00 31:12 31:24 31:36 31:48 32:00 32':12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
TileiU980029 tl-385 Acq: 6-JZJT-1998 19:43:44 GC XX+ Voltage SIS 70S lToiae:38205
385.8610 T:3 3SV3(2S6,30, -3. 0) PKD(7,5,3,0.10\r152820.0,1.00\rrrT) XxpiNDBSUS
TBIANGLX LASS Text: 157-160/166 TLIt44376A
100$ A7.82X7 A7.66E7
80:
60:
40:
20:
31:00 31:12 31:24 31:36 31:48 32:00 32:13 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rile:U980029 tl-385 Acq: 6-JAS-1998 19:43,44 GC XH- Voltage SIS 70S
392.9760 f:3 Xxp:NDB5VS
TBXASGZX LABS Text: 157-160/166 TLH44376A
100*^^31:13 31,24 ^JL/JL-?3^0.3 32:13 32:34^ _ _J2ji56 33:1933:29
80.
60:
40:
20:
o:
-5.4X8
.4. 4X8
'•.3.3X8
'.2.2X8
.1.1X8
0.0X0
T±a
-4.3X8
'-.3.5X8
12.6X8
'•-1.7X8
Is.7X7
-.0.0X0
Time
0.0X0
Time
0.0X0
Tiae
4.1X7
.3.2X7
J.4X7
-1.6X7
-8.1X6
31:00 31:12 31:24 31:36 31:48 32:00 32:13 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
r±lei0980029 tl-385 Acq: 6-JAN-1993 19t43:44 GC XH- Voltage SIS 70S
445.7555 T:3 XxptKDBSUS
TBIAHGZX LABS Text: 157-160/166 TLIt44376A
1001
0.0X0
Tine
80:
50:
40:
20:
oj
3
33:05
: 36
31:00 31:12 31:24 31:36 31:48 32:00 3213 32i 24 32': 36 ' 32'i48'
33:12 33:24 33: 36
143
-------
31': 36 31:48 33:00 32il2 32:24 32:36 32:48 33:00 33:12
\rUa:0980029 #1-385 Actj: 6-JXB-1998 19,43,44 SC XX* Voltage SI* 70S Koiaeil3917
401.8558 r>3 BSOB(256e30,-3.0) PXn(7,S,3,0.10\,5S668.0r1.00\,r,T) XrptSDBSaS
TSIASSLX LABS Texts 157-160/166 TLX944376A
100\ A7.21X7
rU.a,U9U(JUjy IU-.J85 Acq: 6-JAN-1S9B 13,41,44 SC EI+ voltage SIR 70S Noiaa,J5aS4J
389.8156 T:3 BSUB(256,30,-3.0) PXB(7,5,3,0.10\,143S772.0,1.00\fr,T) XxpiODBSUS
TSIAKSLX LABS Text: 157-160/166 TLXI44376A
A1.07E9
so:
eo:
A1.44X8
AJ..12XS
AJ..38E8
31:36 31:48 32:00 32:12 32:24 32:36 32', 48 33tOO 33:12
r±I»>US80029 tl-385 Acqs 6-JAV-1998 19t43,44 SC KT+ Voltage SIX 70S Soiat»572134
391.8127 Ti3 B3U3(256,30,-3.0) PXD(7,5,3,0.10\,22S8536.Q,1.00*,r,T) SzptlWBSUS
TBIAXGLX LABS TextilS7-160/166 TLH44376A
100\ AS.26X8
so:
50-
.O.OEO
33:24 33',36 Ha>
A1.14E8
A8.85E7
A1.26E8
80.
60.
40.
20.
0.
A5.53S7
31:36 31:48 32:00 32:12 32:24 32:36 32': 48 33:00 33:12
\rilaiO980029 fl-385 Actj: 6-JKK-1998 19,43:44 SC ZH- Voltage SIS 70S Noise: 10842
403.8529 T:3 BSOB(256,30,-3.0) PXD(7,S,3r0.10\r43368.0,1.00\,r,T) EzptUDBSUS
XRIAHGLX LABS Texts 157-160/166 TLI944376A
AS.94X7
33124
lOOi
80.
60.
40.
20.
0.
A4.56X7
31:36 31:48 32:00 32:12 32:24 32:36 32', 4 8 33': 00
rile I0980029 H-385 Acq: 6-JAH-1998 19143144 SC XH- Voltage SIS 70S
392.9760 T,3 XxptSDSSUS
TRIASGLX LABS Text 1157-160/166 TLH44376A
33', 12 33:24
-3.4X8
'.2.8X8
'.2.1X8
11.4X8
'.6.9X7
-2.8X8
12.2X8
11.718
11.128
'.5.6X7
'.0.0X0
33:24 33:36 Time
.0.0X0
33',36 Tioel
'.0.0X0
33136 T±*e\
80J
SO.
40.
20.
0.
31,32
33il9 33i29
31,36
.3.2X7
.2.4X7
.1.6X7
.8.1X6
.0 . 010
31t48 32:00 32:12 32s24 32i36 32i48 33iOO 33il2 33:24 33t36 Mae]
144
-------
rile:D9B0029 ti-S4S Acqs 6-JAN-1993 19,43,44 SC BI+ Voltage SIX 703 Noiaes119081
407.7818 T:4 BSUB(2S6,30,-3.0) PXD(7,S,3,0.10\,476334.0r1.00\,T,T) Exp:HDB5OS
TXIASSLS LABS Texts 157-160/166 TLH44376A
10M A3. Q1X9
80:
60:
40:
AB.49EB
y\yv
A4.03X8
35,00 35,12 35,24 35,36 35,48 36*00 36,12 36,24 36,36
rile,0980029 tl-545 Acq, 6-JJM-1998 19,43,44 CC JET* Voltage SIS 70S Solae>95351
409.7789 Ti4 BSUB(356,30,-3.0) PXD(7,5,3,0.10\,381004.0,1.00\,f,T) SxpiNDBSUS
TSIAHSZX LABS Texts 157-160/166 TLIt44376A
IOCS A3.98X9
80.
60:
36,48
40:
20:
A3.05X3
A3.asxa
35,00 35,12 35,24 35,36 35,48 36:00 36,12 36,24 36,36
f±la:U980029 tl-545 Ac?: 6-JAH-1998 19,43,44 GC JET* Voltage SIS 70S Noise:33935
417.8353 T:4 BSUB(256,30, -3. 0) PXD(7,5,3, 0.10\,135740.0,1.00\,TrT) ExptSDBSUS
TRIASSLZ LABS TextslS7-160/166 TUt44376A
1004 A2.S.8E7
36,48
80:
60:
40:
so:
A2.01E7
35,00 35,12 35:24 35:36 35:48 36:00 36:13 36,24 36:36
rilaiO980029 tl-545 Acq: 6-JAS-1998 19:43:44 SC SH- Voltage SIX 70S Noine: 18803
419.8220 Ti4 BSDB(256, 30, -3.0) PXD(7,5,3,0.10\,75212.0,1.00\,r,T) Sxp:SDB5US
LABS Text: 157-160/166 TLIt44376A
AS.77E7
A4.54E7
36:48
35,00 35',12 35:24 35:36 35:48 36-00 36,12 36:24
Flla,0980029 tl-545 Acqs 6-JAN-1999 19,43:44 GC XI + Voltage SIX 70S
430.9729 F:4 ExpsSDBSUS
TRIANGLE LABS Text: 157-160/166 TLIt44376A
35,01 35,18 3Zi27_ 3S.4S 36,0436,12
1001
80:
60:
40:
20:
36:36
36,48
36:38 36,46
-.8.3X8
.6.7E8
.5.0X8
.3.3X8
.O.OEO
37100 Ha,
35,00 35,12 35,24 35,36 35,48 36-00 36,12 36,24
Tile,U980029 tl-545 Acq: 6-JOOT-1998 19:43:44 GC XI+ Voltage SIX 70S
479.7165 f:4 ExpiRDBSUS
TXIASSLX LABS Text: 157-160/166 TLIt44376A
36:08
36*04
36:36
36,48
35:00
35:12
35:24
35:36
35:48
36:00
-8.0X8
'.6.4X8
'-.4.8X8
.3.3X8
ia.sza
F o.oiro
37:00 Time
-.6.6X6
'•.5.3X6
-.3.9X6
.2.6X6
•-1.3E6
37:00
Tiae
0.0X0
37:00 Tiae
-.2.2X7
Li.717
L1.1J57
1.5.6X6
\-g.Ofo
37:00 Time
36:13 36:34
36:36 36:48
.0.0X0
37:00 Tiae
145
-------
Fj-La>O980029 tl-545 Acqi 6-JAa-199S 19t43t44 SC sir Voltage SIS 70S
433.7766 Ti4 BSUi(256,30, -3. 0) PXD(7,5,3,0.10\,113316.0/1.00\,r,T) XzptJWBSUS
TSIAOSLX LASS Tmxt: 157-160/166 TLI944376A
AS. 09X8
A4.90X8
.0.0X0
15:12 35', 18 35',24 35',30 35,36 35',42 35',48 35',54 36',00 36:06 36:12 36:18 36:24 36:30 T±M»
rllmtU980029 tl-545 Acq: 6-JMT-1998 19,43:44 SC SH- Voltage SIX 70S Kola*,18519
425.7737 Ti4 BSU3(256,30,-3.0) PSD(7,5,3,0.10\,74Q76.0,1.00\,r,X) SxptBDBSUS
TSIANGLX LASS Torts 157-160/166 TLH44376A
100\ A5.22X8
A4.82K8
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24
Tile:0930029 tl-545 Actf. 6-JAN-1998 19:43:44 SC XH- Voltage SIS 70S Soiae,13981
435.8169 F:4 BSUB(356,30, -3.0) PXS(7,5,3,0.10\,S5924,0,1.00\,r,T) Xxp:SDBSUS
TRIASSLX LABS Text: 157-160/166 TLIt44376A
100\ A3.64X7
80.
60.
40.
20:
jJ-.SXS
J..OX8
.7. 7X7
.5.1X7
-3.6X7
0.0X0
Tin
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24
rilat0980029 tl-545 Actj: 6-J7Uf-1998 19,43:44 SC XX+ Voltage SIS 70S Noiaa: 13702
437.8140 Ti4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,S0808.0,1.00\,T,T) Kxp:NDBSas
TSIAHSZX LABS Text: 157-160/166 TLIt44376A
1001 A3.42E7
80.
60.
40.
20.
0.
8.2X6
6.6X6
4.9X6
.3.3X6
.1.6X6
36:04 36:12
0.0X0
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30 T±ae
Tila,0980029 tl-545 Acq: 6-JAN-1998 19:43:44 SC XI+ Voltage SIS 70S
30.9729 T:4 SrpiNDBSOS
TRIASSLX LABS Text! 157-160/166 TLXt44376A
i00* l*JLi*_
80.
60.
40.
301
o:
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
-2.8X7
^.2X7
-1.7X7
-1.1X7
.5.6X6
0.0X0
Time
14G
-------
rila:U980029 tl-545 Acq: 6-JAK-1998 19:43:44 SC XI+ Voltage SIX 70S Hoi.ee: 75923
441.7428 T:4 BSOB(256,30, -3 .0) PKB(7,5,3,0.10\,303692.0,1.00\,T,I) Xxp:XDBSaS
XSIANGLX LABS Text: 157-160/166 XLH44376A
100JJ A6.
90.
80.
70.
60.
50.
40.
30.
20.
10.
0
Tile
443.
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90.
80.
70.
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501
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20^
101
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430.
TRIA
1001
901
801
701
601
501
401
301
201
101
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1001
901
801
701
60.
501
401
301
201
101
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1
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35:00 ' 36:00 37:00 ' 38\00 ' 39\00 ' ' 4o':06 ' 41
,0980029 tl-545 Acq: 6-JAK-1998 19:43:44 SC EI+ Voltage SIX 70S Soiae:17511
7399 r:4 BSVB(256, 30, -3.0) fXD(7,5,3, 0.10%, 70044. 0,1. 00\,r,T) Xxp:NDB5US
WSZX LASS Tart:157-160/166 TLIt44376A
A6 64X9
J
V
J5>00 36(:00 37's 00 38:00 39:00 40: 00 41
,0330023 tl-545 Acq: 6-JMT-199B 19, 43:44 SC KI+ Voltaye SIX 703
9729 r:4 XxptHBBSUS
MCLZ LABS Tart: 157 -160/166 TLIt44376A
J4-J/4A" J5A57 36:04 36,38 38:41 39:50
35:00 ' ' ' 36:00 ' 37:00 ' ' ' 38:00 ' ' ' 39^.00
IO980029 tl-545 Acq: 6-J7OT-1998 19:43:44 SC XI+ Voltage SIX 70S
6775 T:4 X3Cp:SDB5US
HGLX LABS fort: 157-160/166 TLH44376A
35:00
t
34:24
36
\\JJS: 28 I
10:00 ' ' 41:
,03
39:50
I
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1 37'21 37-45 flj
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.7.3X8
.6.3X8
.5.2X8
.4.2X8
.3.1X8
.2.1X8
.1.0X8
0.0X0
,00 Tiae
-1.1X9
'-.9.6X8
.8.5X8
.7.5X8
.6.4X8
.5.3X8
'-.4.3X8
13.2X8
.2.1X8
.1.1X8
0.0X0
00 Time
2.8X7
.2.5X7
.2.2X7
12.0X7
ll.7X7
ll.4X7
.1.1X7
.8.4X6
.5.6X6
.2.8X6
'•0.0X0
00 Tiae
.2.1X5
-1.5S5
-1.715
-1.5S5
^1.3X5
.1.0X5
.8.3X4
.6.3X4
.4.2X4
.2.1X4
0.0X0
35:00 36:00 37:00 38:00 ' ' 39:00 40:00 41:00 Tiae
147
-------
FlJ.aiU9aoOJ9 #1-545 Acq: 6-JAN-1999 19:43:44 SC Elf Voltage SIM 70S Noiaa:4750
457.7377 f:4 BSUB(256,30, -3. 0) PXD(7,5,3, 0.101,19000.0,1.00\,r,S) XxptHDBSUS
TBIANGLX LASS Tart: 157-160/166 TLH44376A
IOCS
39', 30 39t36 39>42 39:48 39:54 40:00
r±lfi0980029 H-S45 Acq: S-JJOt-1998 19i43>44 SC XH- Voltage SIB 70S Hoiao:6204
459.7348 T:4 3SUB(256,30,-3.0) PKD(7,5,3,0.10\,24816.0,1.00\,T,T) XxptXDBSUS
TBIANGLX LASS Text: 157-160/166 TLH44376A
1003, A7.3Jf8
80.
39,30 39:36 39:42 39:48 39:54 40:00
r±le:U980029 tl-545 Acq: 6-JAN-1998 19:43:44 SC XI+ Voltage SIS 703 Noiao:562S
469.7779 T:4 BSUB(256,30, -3.0) PXD(7,5,3,0.10\r22SOO.O,1.00\,T,T) Szp:BDS5US
XSIAKSLS LASS Tost.: 157-160/166 TZIt44376A
10 0\ A5.20E7
39:30 39:36 39:42 39:48 39:54 40:00
r±le:a980029 tl-545 Acq: 6-JMT-1998 19:43:44 SC ZT* Voltage SIS 70S Noise:3970
471.7750 T:4 SSOS(256,30, -3.0} PKD(7,5,3,0.10\,15880.0,1.00\,r,T) Xxp:BDBSUS
XXIANGLZ LASS Text:157-160/166 TLH44376A
100\
39:30 39:36 39:42 39:48 39:54
ttlaiO980029 tl-545 Acq: 6-J3OT-1998 19:43:44 GC XX+ Voltayv SIX 70S
430.9729 Ti4 XxpilWSSaS
TBIAXGUS LASS Text: 157-160/166 TLH44376A
40:00
1004
80.
60.
40.
20.
39:27
39:38
39:58
-1.2E8
.9.4X7
.7.0X7
.4.7X7
'.2.3X7
.0.0X0
40:06 T±m
,.1.4X8
1.1X8
8.4X7
5.6X7
2.8E7
40
0.0X0
06 Tim.
..9.7X6
.7.7X6
.5.8X6
.3.9X6
'.1.9X6
40:06 Time
1.1X7
.8.7X6
.6.6X6
.4.4X6
.2.2X6
.0.0X0
40:06 T±mt
39130
39:36
39:42
39:48
39:54
40:00
-.2.7X7
.2.2X7
.1.6X7
.1.1X7
.5.5X6
.0.0X0
40 06 Time
148
-------
CD
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Peak Locate Examination: 6-JAN-1998:19:42 File:U980029
Experiment:NDB5US Function:2 Reference:PFK
-------
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^ile:U980029 #1-724 Acq: 6-JAN-1996 19:43:44 GC EI+ Voltage SIR 7US
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Sample Text:157-160/166 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%, A2.59E8
24:54 25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48 25:54 26:00 26:06
File:U980029 #1-724 Acq: 6-JAN-1998 19:43:44 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:157-160/166 TLI#44376A File Text:TRIANGLE LABORATORIES/ INC.
100%, A3.45E8
24 54 25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48 25:54 26:00
File:U980029 #1-724 Acq: 6-JAN-1998 19:43:44 GC EI+ Voltage SIR 70S
331.9368 F:2 Exp:NDB5US
Sample Text:157-160/166 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% 25^10
26:06
80j
60 j
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25:20
0.
24 54 25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48 25:54 26:00 26:06
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2.9E7
.2.1E7
.1.4E7
.7.1E6
.O.OEO
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4.8E7
3.8E7
2.9E7
1.9E7
9.6E6
.O.OEO
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2.3E7
L1.8E7
1.4E7
L9.1E6
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339.8597 F:2 Exp:NDB5US
Sample Text:157-160/166 TLI#44376A
1004
80j
60J
40j
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0
19:43:44 GC EI+ Voltage SIR 70S
File Text:TRIANGLE LABORATORIES, INC
28:12 28:18 28:24
File:U980029 #1-724 Acq: 6-JAN-1998
341.8567 F:2 Exp:NDB5US
Sample Text:157-160/166 TLI#44376A
100%
80J
60J
40J
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28:30 28:36 28:42 28:48
19:43:44 GC EI+ Voltage SIR 70S
File Text:TRIANGLE LABORATORIES, INC
Oj
28:12 28:18 28:24
File:U980029 #1-724 Acq: 6-JAN-1998
351.9000 F:2 Exp:NDB5US
Sample Text:157-160/166 TLI#44376A
100%
28:30 28:36 28:42 28:48
19:43:44 GC EI+ Voltage SIR 70S
File Text:TRIANGLE LABORATORIES, INC,
28:35
28:54
_3.2E8
_2.5E8
_1.9E8
_1.3E8
L6.3E7
LO.OEO
28:54 29:00 Time
_2.1E8
L1.7E8
L1.3E8
L8.4E7
L4.2E7
LO.OEO
29:00 Time
28:24 28:30
28:42
28:48
28:54
JlO.OEO
29:00 Time
to
vH
-------
ile:U980029 #1-385 Acq : 6-JAN-1998 19:43:44 GG EI + Voltage SIR 70S
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.OOi A2.03E8 5
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75.8178 F:3 Exp:NDB5US
lample Text : 157-160/166 TLI#44376A File Text :TRIANGLE LABORATORIES, INC.
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80 1
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Sample Text: 157-160/166 TLI#44376A File Text-.TRIANGLE LABORATORIES, INC.
LOO*
80J
60 j
40j
20J
0 -
'
~_
1 — r— 1 — i — i — i — 1 — i — I — i — i — i — 1 — i — i — i — I — i — 1 — i — r— i — i — i — 1 — i — i — r— i — i — 1 — i — i — i — i — i — 1 — i — I — i — I — i — I — i — i — i — i — i — 1 1 — I — I — i — i — [• — 1 — r-1
33:06 33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54
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L5.9E6
_4.5E6
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_1.5E6
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Time
-------
TLI Project 44376A
Client Sample: 157-160/166 '
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P980097
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97 Spike File:
TLI ID: 194-59-12A-E Date Extracted: 12/29/97 ICal:
Date Analyzed: 01/07/98 ConCal:
Sample Size: 1.000
Dry Weight n/a
GC Column: DB-225
Dilution Factor n/a % Moisture
Blank File: P980094 %Lipi±
Analyst JM % Solids:
SPC2NF04
PF22206
P980092
: n/a
n/a
n/a
glay^;43~rr * ; *
2J.7.8-TCDF
ph^^eferT
13C12-2A7,8-TCDF
iBeebterySteiuiartl s , "
£\V..,W. "^ .-A \ f
"C,rlA3,4-TCDD
Amt £19} DL EMPC Ratio
16.1 0.75
Amt (ngj % Recovery GCtfonfts ftalta
2.8 71.0 40%-130% 0.74
(Xv- ^V
0.79
RT
23:08
BT
23:07
BT
21:56
Flags
—
Flags
—
Flags ,
Data Reviewer.
01/09/98
Page 1 of 1
C1NF CSR . Mil. LAKSn Ilium
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1501/09/98
153
-------
Initial
, .Date..
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio liaits ha* been recalculated according to method requirements.
Page No.
01/07/98
Listing of P980097B.dbf
Matched GC Peaks / Ratio / Ret. Time
Co •pound/
H_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Home.. ID.. Flags.
TCDF
304-306 DC ML 0:00
DC WL 18:17
18:29
18:47
18:57
19:02
19:09
19:30
19:37
19:45
19:56
20:03
20:12
20:21
20:30
20:39
20:48
21:11
21:24
21:28
21:38
21:44
21:53
22:08
22:22
22:33
22:43
23:00
23:08
23:21
23:37
23:44
23:57
24:32
25:17
DC WH 25:44
304-306 33 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 20:10
DC WL 20:23
DC WL 20:33
0.65-0.89
RO 1.75
0.82
RO 0.90
RO 1.05
RO 0.64
RO 1.45
0.78
0.75
0.75
0.76
0.76
0.76
0.76
0.81
0.77
0.75
0.75
0.76
0.65
RO 1.02
0.75
0.75
0.75
0.75
0.75
0.75
RO 0.48
0.75
0.75
0.75
0.75
0.76
0.68
0.75
0.77
0.85
0.65-0.89
RO 1.76
0.68
RO 1.21
0.75
5,
7,
6,
11,
5,
5,
11,
6,
18,
6,
38,
8,
1,
8,
8,
1,
10,
8,
6,
9,
11,
9,
6,
1,
217,
6
77
442
149
123
101
376
176
298
023
591
727
663
786
406
980
462
781
50
76
916
589
728
731
770
442
35
268
183
478
235
612
50
155
230
58
649
.25
.20
.84
.44
.03
.42
.96
.25
.27
.69
.09
.20
.59
.43
.99
.25
.59
.10
.50
.75
.28
.96
.95
.18
.81
.90
.95
.36
.94
.24
.67
.86
.11
.15
.58
.81
.33
0.792-1.101
0.000
0.791
2,755.
88.
53.
83.
164.
3,077.
2,689.
4,744.
2,407.
313.
2,441.
5,264.
2,796.
8,107.
2,772.
16,734.
19.
44.
3,815.
678.
3,754.
3,746.
756.
4,479.
15.
3,549.
2,647.
4,064.
4,832.
4,140.
20.
2,643.
534.
,79
66
52
22
90
92
80
96
14
90
53
23
76
25
45
90
84
15
37
85
20
66
98
98
64
66
64
54
54
58
25
77
76
3,075.
84.
84.
57.
212.
4,098.
3,608.
6,278.
3,183.
413.
3,222.
6,522.
3,610.
10,873.
3,690.
,05
,43
,12
30
06
33
47
73
95
30
06
20
23
00
14
22,046.20
30.
43.
5,100.
911.
4,974.
4,984.
1,013.
5,962.
32.
4,718.
3,536.
5,413.
6,403.
5,472.
29.
3,511.
695.
66
36
91
11
75
52
83
92
75
70
30
70
13
28
86
38
82
0.800
0.813
0.820
0.823
0.828
0.844
0.849
0.854
E
0.862
0.867
0.874
0.880
0.
0.
887
893
E
E
0.900
0.916
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
926
929
936
940
947
957
968
975
983
995
001 2378 -TCDF
010
022
027
036
061
094
113
E
E
E
E
E
E
AN
E
E
E
0.957-1.043
4
31
3,
64
.99
.96
.54
.14
0.
0.
0.
0.
000
872
882
889
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-6729 • Fax: (919) 544-5491
Printed: 03:34 01/07/98
154
-------
Page No. 2
01/07/98
Compound/
M_Z QC. Log Omit Why
316-318
13C12-TCDD
332-334.
Listing of P980097B.dbf
Matched GC Peak* / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Home.. ID.. Flags.
0.911
0.923
0.933
0.944
0.965
000
015
040
045
052
076
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
WL
WH
WH
WH
WH
4
21:
21:
21:
21:
22:
23:
23:
24:
24:
24:
24:
25:
03
20
34
49
18
07
28
02
09
19
52
13
RO
RO
RO
RO
RO
0
0
0
0
0
0
0
0
2
0
0
0
.65
.78
.39
.73
.42
.74
.21
.83
.45
.86
.79
.40
Peaks
8.
41.
12.
58.
6.
1,473.
8.
33.
4.
11.
44.
16.
1,521.
57
82
50
77
57
98
00
20
85
35
01
30
75
2.86
628.78
3.48
15.01
6.81
845.20
16.55
18.19
13C12-2378-TCDP ISO
1.091
Above: TCDF / TCDD Follows
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
SN
SN
SN
WH
WH
WH
WH
WH
WH
3
0
19
20:
20:
21:
21:
22:
22:
23:
23:
24:
24:
24:
24:
24:
:00
:07
:31
:38
;38
:56
:19
43
:10
45
03
14
28
40
47
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
1
0
1
2
0
0
'1
0
1
0
2
0
0
0
3
.68
.98
.81
.07
.79
.79
.07
.76
.39
.48
.38
.31
.50
.27
.59
Peaks
1.
2.
2.
1.
984.
1,496.
1.
11.
0.
10.
0.
4.
5.
1.
1.
2,492.
77
27
00
77
02
30
20
98
67
76
80
70
34
68
20
30
433.06
659.49
5.19
0.908-1.092
550.96
836.81
6.79
0.000
0.884
0.948
0.954
1.000 I!
1.014 i:
1.032
1.050
1.071
1.098
1.112
1.120
1.131
1.140
1.146
13C12-2378-TCDD IS1
13C12-1234-TCDD RSI
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report •••
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
ri-Laif9800S7 #1-922 Acq: 7-JAlf-ltf
303.9016 Sip, 03225
XSIAHSLX LASS Taxttl57-160/166 TLH44376A
23i37
Voltage SIS 70P
24:32
25tl7
-1.2X7
'•.1.1X7
'•.1.1X7
':!. 0X7
'•.9.6X6
.9.016
.8.4X6
'•.7.8X6
17.2X6
'•.6.6X6
'.6.0E6
'•.5.4X6
'-.4.8X6
.4.2X6
'.3.6X6
'•.3.0X6
'•.2.4X6
:1. 8X6
.1.2X6
.6.0X5
22:36 22:48 23:00 23:12 23:24 23s36 23:48 24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24
r±lo:P980097 tl-922 Acq:7-J7Ol-9» 02:28:58 XH- Voltage SIS 70P
315.9419 KrptDB22S
TRIANGLE LABS Text: 157-160/166 TLH44376A
ion
95.
90.
85.
80.
75.
70.
65.
60.
55.
50:
45:
40:
35.
30:
25.
20.
15:
10:
5j
OJ
23; 07
1
22:36 22:48 23:00 23:12 23*24 23:36 23:48 24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24
.8X6
.7X6
.6E6
.5X6
.5X6
.4X6
.3X6
.2X6
.1X6
.0X6
.1X5
.2X5
.3X5
.3X5
.4X5
.5X5
.6X5
.7X5
.8X5
.1X4
.0X0
Hue
156
-------
fiJ.a:PS80097 #1-922 Acq: 7-JAK-98 02:28:38 EI+ Vodugra SIS 70P aoiae:j095
303.9016 BSUB(2S6,30,-3.0) PXD( 5, 3,1, 0.10\,12380.0,0.00\,T,T) Xxp:DB225
TSIAXGLE LASS Text: 157-160/166 TLH44376A
100* Al ( X8
19:00 20', 00 21iOO 23:00 33:00 24': 00
riletP980097 tl-922 Acq:7-JAN-98 02:28:58 XH- Voltage SIS 70P Boise: 1763
305.8987 BSUB(256,30,-3.0) tKD(5,3,1,0.10\,70S2.0,0.00\,T,T) StptOB225
TRIJOKLX LASS Texts 157-160/166 TLIH4376A
1003k A3.20X8
25:00
19:00 20:00 21iOO 22:00 23:00 24:00
r±la:P980097 tl-922 Acqt7-JJOt-98 02:28:58 EH- Voltage SIS 70P Xo±aes2480
315.9419 BSUS(256,30,-3.0) PXD(S,3rl,0.10\,9920.0,0.00\,r,T) Szp:DB225
TBIASGZE LABS Text: 157-160/166 TLH44376A
1QQ1 A6.29Z6
80.
60.
40.
20.
25:00
15:00 20:00 21:00 22:00 23:00 24:00
Tile:P980097 tl-922 Aeqt 7-JAN-98 02:28:58 XI+ Voltage SIS 70P Noiae:1412
317.9389 BSUB(2S6,30,-3.0) PKB<5,3,l,0.10\,5648.0,O.OQ\rT,r) Xxp:DB225
TXIAKGLX LABS Text: 157-160/166 XLXt44376A
AS.45X6
25100
.1.8H6
.1.4E6
.1.1X6
.7.2X5
.3. 6X5
O.OEO
rime
80.
60.
40.
20.
0.
-2.4E6
.1.9X6
.1. 4E6
.9.5X5
'.4.8X5
19iOO 20:00 21:00 22:00 23:00
F±J.»,P980097 H-922 Acqi7-J7Uf-98 02:28:58 XI+ Voltage SIS 70P
375.8364 Xip:DB225
TRIANGLE LABS Text* 157-160/166 TLH44376A
24:00
25:00
0.0X0
Time
1001
23:05
19:00
20:00
21:00
22:00
23100
24:00
25:00
157
-------
THOIP9SOOS7 tL-922 Acqi 7-JAK-9S 02i2Bt58 EI+ Voltage SIS 70P Nona 1139 2
319.8965 BSV3(256,30,-3.0) Pn>(5 ,3,1,0.10\,516B.0,0.00\,T,T) KxpiOB225
TRIASSLX LASS Text.: 157-160/166 TLH44376A
1001
80.
SO.
40.
20.
A6.69X7
Al.00X7
A /v A
A1.92X7
20100 21100 32:00 23:00
rLlm:P980097 tl-922 Acq:7-JAN-98 02i28i5B KH- Voltage 5X8 7OP Holme: 7310
321.8936 BSUB(256,30,-3.0) PKE( 5,3,1, 0.10\,29240.0,0.00\,r,f) SzptOB225
XSiASSLX LABS Tttrt: 157-160/166 TU944376A
100\
241 00
80.
60.
40.
20.
A8.44E7
A1.26E7
A xv A
A2.44E7
20100 21:00 22:00 23:00
f±latP9S0097 tl-922 Acq: 7-J7HT-9B 02t28t58 EH- Voltage SIS 70P Noiaeill54
327.8847 BSUB(256,30,-3.0) PKD(5,J,l,0.10\,4616.0,0.aO\,T,T) SxptDB225
TSIANGLZ LABS Text: 157-160/166 TLH44376A
1001 A2.40E7
80.
eo:
40.
20.
A2.45Z7
A2.26E7
A9.67X6
A2.73E6
A
20:00 21:00 22:00 23:00
riletP980097 tl-922 Acq: 7-JAN-9S 02:28:58 EI+ Voltagre 5X5 70P lToiae:840
331.9368 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,3360.0,0.00\,T,T) Exp:DB225
TSIANGLX LABS Text: 157-160/166 TLH44376A
1001 A6.59Z6
24:00
80.
60.
40.
20.
A4.33X6
20:00 21:00 22:00 23:00
TiletP980097 tl-922 Acq:7-JJUr-98 02:28:58 EI+ Voltage SIX 70P XoiaetSOO
333.9338 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,2000.0rO.OO\,T,T) Xxp:DB225
T&IAHGLE LABS Text: 157-160/166 TLI944376A.
1001 A8.37X6
24:00
80.
601
40.
20.
0.
AS. 51X6
3.1X7
.2.5X7
.1.9X7
.1.2X7
'.6.2X6
'.0.0X0
25 00 Tiat
25
4.0X7
.3.2X7
.2.4E7
_1.6X7
'.8.0E6
.0.0X0
00 T±ae
7.4X6
.6.0X6
'.4.5X6
.3. OE6
.1.5E6
.O.OEO
25 00 T±ae
1. 8E6
.1. 4X6
.1.1X6
.7.2X5
.3.6X5
.0.0X0
25 00 Time
20:00
21:00
22:00
23:00
24:00
-2.3X6
.1.8X6
.1.4X6
'.9.2X5
.4.6X5
.0.0X0
25:00 Tiae
153
-------
rile:P980097 tl-922 Acg: 7-JAW-98 02:28:58 EI+ Voltage SIS 70P
303.9016 Xxp:DB225
XSIAXSLX LABS Text: 157-160/166 TLIt44376A
1001
80.
60.
40.
20.
o
21:11
ft
20:39 1
T O • A < A I -*^ -w
i,, »»A s^3 aT »i"h
i A.i/UlyL)l MJiM T .
2.6X7
-.2.1X7
;
;l . 6X7
'.1 . 0X7
'•.5.2X6
'• o . oxo
19\00 ' ' ' 20:00 2l':00 22:00 23:00 ' 24:00 ' ' 25:00 Tina
rila:P980097 tl-922 Acq:7-JJOT-98 02:28:58 XI+ Voltage SIS 70P
315.9419 KrpiDB22S
TSIAHGLX LABS Text: 157-160/166 TLIt44376A
1001
80.
60.
40.
20.
Q
23:07
20:33 21:49 1 1
j-.^ «- -A- 1 \. .—, J*
_1 . 8X6
.1.5X6
.1.1X6
.7.3X5
.3.6X5
19:00 ' ' 20:00 ' 21.00 22:00 ' ' 23:00 ' ' ' 24:00 ' ' ' 25:00 ' ' ' Time
W.e:P980097 tl-922 Atxj:7-J3UT-98 02:28:58 XI+ Voltage SIS 70P
319.8965 Sxp:DB225
TSIANGLX LABS Text: 157-160/166 TLIt44376A
1003
80:
60:
40:
201
0.
15, -15
19:53
i
, „
31 A" /» 21i17 A
1 \ 1 \ A/vAy\ ^sJ\^
3.1X7
.2.5X7
.1.9X7
.1.2X7
.6.2X6
0.0X0
' 15.00 ' ' ' joiob ' ' 21:00 ' 22:00 ' ' ' 23:00 ' ' ' 24 1 00 ' ' ' .25.00 ' ' Mae
rilo:P980097 tl-922 Acq:7-jyur-98 02:28:58 EH- Voltage SIS 70P
331.9368 Xxp:DB225
TSIAXSLX LABS Text: 157 -160/166 TLIt44376A
1001
80:
•
60:
40:
20:
«•
21:56
21:38\\
1
/I l\
_1 . 8X6
'•.1.5X6
.1.1X6
.7.3X5
.3.6X5
0.0X0
19:00 ' ' ' 20\00 51:00 22:00 ' ' ijioo ' ' ' 24\00 ' ' ' 25.00 ' ' Time
r±J.eiP980097 tl-922 Acq:7-J3Ol-9a 02:28:58 XI+ Voltage SIS 70P
292.9825 ExptDB225
TSIAXGLX LABS Text.: 157-160/166 TLIt44376A
1001
80:
60:
40:
20:
o-
18:59 19:35 20:47 21:18 21:48 22:26 23:02 23:39 24 138^^25^27^
(V^^-w^-«VwVVV ^ -vy^-^ -^-^^-^r^^^v^r^^^^ ^T^'
.1.1X7
.8.5X6
.6.4X6
.4.3X6
.2.1X6
0.0X0
15.00 20.00 21:00 22:00 ' 23': 00 ' ' 24\00 ' ' 25:00 ' ' Time
TiletP980097 tl-922 Acq:7-JAN-98 02:28:58 XI+ Voltage SIS 70P
330.9792 XxptDB22S
TBIAXGLX LABS Text.: 157 -160/166 TLIt44376A
1001
80:
60:
40:
20:
0'
lyS&^.j+Jfcj^
.9.3X6
-.7.4X6
'.5.6X6
-.3 . 7X6
-.1.9X6
0.0X0
19l: 00 20:00 21:00 22\00 23:00 ' ' ' 24': 00 ' ' ' 25:00 Tiae
159
-------
f) 232.385
B 3016
C 385,8987
D 315,9419
E 317,9389
F 319,8965
6 321,8936
H 327,8847
I 338,3782
J
K
L
n
Ref, lass 292,9825 Peak top
Height 1,95 wits Span 288 ppi
Systa file naie
Data fdenaie
ResoLutun
Gro^ruter
lonizatun lode
Svitching
, lasses 292,9^5)
1
EI+
VOLTAGE
388.9761
338,9792
JU14 JUUUK
331,9368
333,9338
£5,3364
Chamel I 338,9732 Peak top
Height 1,58 volts Span 296 ppt
IGO
-------
TLI Project: 44376A
Client Sample: 161-164
Method 23 PCDD/PGDF Analysis (a)
Analysis File: U980030
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN DateReceive± 12/17/97
194-59-13A-E Date Extracted: 12/29/97
Date Analyzed: 01/06/98
1.000 Dilution Factor n/a
n/a Blank File: U980026
DB-5 Analyse BB
Spike File:
ICal:
ConCal:
% Moisture:
%lApi±
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2.3,7.8-TCDD
1,2,3.7.8-PeCDD
1.2,3,4.7,8-HxCDD
1,2,3,6,7,8-HxCDD
1.2,3,7.8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2.3,7,8-PeCDF
2,3,4,7,8-PeCDF
L2J.4,7.8-HxCDF
12.3.6.7,8-HxCDF
2,3,4.6,7,8-HxCDF
1.2,3,7,8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF-
4|,AWt'p8)
0.61
3.4
3.7
5.7
8.3
32.9
47.1
53.8
13.8
23.8
72.8
25.9
38.5
2.5
107
17.1
79.7
;Hr*tnt ##
68.1
55.0
92.0
68.8
288
324
300
180
ftt tSftC^k^^*** ^^^0c^*-
<._ l««.^ cnlrv-' •'f-tt&SKf •
0.75
1^3
1J3
1.21
1.27
0.96
0.85
0.74
. 1.57
1JO
1^7
1.19
1J2
1.15
1.05
1.04
0.88
Number Dt S«PC
11 68.4
9 88.7
7
2
16
15 326
13
4
RT
25:20
29:36
32:44
32:49
33:06
36:02
39:36
24:38
28:34
29:15
32:02
32:08
32:37
33:23
35:01
36:32
39:49
,Fla$s
PR_
E_
E—
PR!
E_
Flags
E_
E
—
E_
E
E
E
Page 1 of 2
Mm _PSR»I.OI. LARS d.io.081
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1801/10/98
161
-------
TLI Project: 44376A
Client Sample: 161-164
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980030
13C,2-2,3,7.8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-U,3,6,7,8-HxCDF
"C,2-l,2,3,6,7,8-HxCDD
13C,2-U,3,4,6,7,8-HpCDF
13C,2-U.3.4,6,7,8-HpCDD
I3C ,2-U,3,4,6.7,8,9-OCDD
Surrogate Standards {Type A}
13C,2-2,3,4,7,8-PeCDF
13C,2-U,3,4,7,8-HxCDF
IJCirlA3.4,7.8-HxCDD
13Ci2-l,2,3.4,7,8.9-HpCDF
Surrogate Standards {Type A)
37Cl4-2,3,7,8-TCDD
Alternate Standards {Type A)
13Ci2-l,2,3,7,8,9-HxCDF
13Ci2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
I3C12-U,3,7,8,9-HxCDD
Amt (fiel
-ifVtit J j. f^ fff. .
1.8
1.8
1.8
1.8
2.0
2.7
2.5
2.6
4.9
Aink £»oj
3.4
4.0
3.4
4.0
" f
3.2
Amt
-------
Initial
.Date.
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/10/98
Listing of O980030B.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
K
K
K
K
K
K
K
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
KK
NK
K
R
H
DC KL 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
25
26
0
:00
:27
:58
:11
:35
:54
:18
:34
:49
:02
:13
:26
:38
:03
:16
:31
:22
16 Peaks
DC NL 0:
DC WL 22 ;
DC WL 22 :
24:
24:
24:
25:
DC WH 26:
DC WH 26:
DC WH 26 :
0
:00 RO
;23 RO
:59
04 RO
ill RO
:37
02 RO
10
45
54 RO
4 Peaks
DC NL 0:
22:
23:
23:
24:
24:
24:
25:
0.
00 RO
47
10
28
09
24
49
14-
.65-0.89
0.80
0.74
0.74
0.75
0.75
0.73
0.73
0.74
0.78
0.71
0.74
0.73
0.74
0.78
0.75
0.79
0.72 .
1,
.65-0.89
1.96
0.91
0.75
1.71
1.11
0.74
1.79
0.75
0.74
0.99
0.867-1.079
2,170.31
30,416.60
30,893.70
35,673.50
169,571.50
104,955.70
113,286.80
85,763.70
125,186.40
156,541.20
52,006.50
49,115.30
245,942.00
51,065.90
53,291.70
8,762.02
5,969.33
318,441.85
12,946
13,143
15,327
72,625
44,338
47,800
36,381
54,757
64,941
22,038
20,751
104,635
22,455
22,788
3,863
2,508
.60
.90
.10
.00
.10
.50
.50
.60
.20
.80
.80
.00
.60
.20
.68
.15
17,470
17,749
20,346
96,946
60,617
65,486
49,382
70,428
91,600
29, 967
28,363
141,307
28,610
30,503
4,898
3,461
.00
.80
.40
.50
.60
.30
.20
.80
.00
.70
.50
.00
.30
.50
.34
.18
0
.000
0.871
0.892
0.901
0.917
0.930
0.947
E
E
E
0.957
0.968
0.976
E
E
0.984
0.993
1.001 2378-TCDF AN
1.
1.
1.
1.
018
026
037
071
E
0.959-1.041
34.39
200.01
344.15
101.33
141.58
14,758.64
59.65
137.47
61.24
42.13
15,061.20
65-0.89
0.07
0.76
0.77
0.79
0.76
0.80
0.79
0.77
16.21
87,999.10
55,623.10
7,335.49
23,306.00
14,392.98
6,595.16
24,800.00
98
88
6,260
60
.08
.88
.48
.36
57;
79.
8,498.
33.
:25
.99
.16
70
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
909
934
978
982
000 13C12-2378-TCDF ISO
017
063
087
093
38,001.20
24,216.20
3,245.
10,056.
6,408.
2,920.
10,800.
22
00
92
49
00
49,997.
31,406.
4,090.
13,250.
7,984.
3,674.
14,000.
0.895-
90
90
27
00
06
67
00
0.
0.
0.
0.
0.
0.
0.
0.
1.047
000
901
916
928
955
964
981
997
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:19 01/10/98
163
-------
Page No.
01/10/98
Listing of 0980030B.dbf
Matched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total. Area. .. Area. PeaJc. 1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
AN
320-322
37C1-TCDD
328
328
13C12-TCDO
332-334
332-334
PeCDF
340-342
M
AN
DC
DC
DC
DC
25:20
25:30
25:39
25:53
26:19
12 Peaks
NL 0:00
WL 22:47
WL 23:05
WL 23 : 10
23:58
24:09
24:38
r 24:49
25:09
25:20
25:44
7 Peaks
0
0
0
0
RO 0
.75
.76
.79
.81
.96
2
3
3
1
230
14
8;
8,
32,
,070.00
,171.29
,527.63
,167.97
995.77
,984.49
84.86
458.03
310.32
423.61
,710.40
354.82
268.18
83.54
32.21
,667.13
,225.28
,341.56
1
1
14
890.00
,369.84
,555.13
522.37
539.76
,710.40
354.82
268.18
83.54
32.21
1,180.00
1,801
1,972
645
562
.45
.50
.60
.58
0.
8,667.13
8,225.28
0.65-0.89
DC
NL 0:00
25:08
25:18
25:39
26:08
26:20
5 Peaks
HO 1.84
0.82
0.79
21,
10,
0.81
RO 1.38
RO 1.06
33,
1.32-1.78
DC
NL 0:00
26:34
27:02
27:13
27:20
27:34
27:42
27:52
28:11
28:18
28:29
28:34
28:43
28:51
29:15
29:24
29:44
29:53
30:14
RO 1.
1.
RO 1.
1.
RO 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
RO 3.
1.
08
54
21
37
25
50
53
52
53
52
59
57
52
56
50
55
49
33
51
92,
1,
1,
1,
29,
218,
49,
79,
109,
43,
41,
35,
61,
69,
104,
17,
9,
20.00
,792.63
,900.64
396.22
18.76
39 . 40
147.65
TCDD /
21.12
578.80
360.02
730.49
313.64
676.90
160.40
830.50
564.40
126.50
500.00
700.00
110.30
103.00
662.20
642.80
180.14
568.80
021.70
9,849.83
4,796.51
176.92
14.62
23.64
11,942.
6,104.
219.
10.
22.
1.001 2378-TCDD
1.008
1.014
1.023
1.040
921-1.079
0.000
0.901
0.912
0.916
0.947
0.955
0.974
0.981
0.994
1.001 37C1-TCDD
1.017
AN
CLS
0.921-1.079
,80
13
30
60
26
0.000
0.993 13C12-1234-TCDD
1.000 13C12-2378-TCDD
1.014
1.033
1.041
RSI
IS1
56,
17,
131,
30,
48,
65,
26,
25,
21,
37,
41,
63,
10,
5,
158.90
826.68
999.40
798.49
790.70
891.00
089.50
087.80
836.30
700.00
500.00
162.50
209.40
750.20
574.00
285.80
742.75
433.11
36,419.
0.925-1.065
90
682.62
731.
637.
11,886.
86,269.
19,741.
31,476.
43,290.
16,800.
16,200.
13,947.
23,893.
27,912.
41,068.
6,894.
223.
3,588.
09
20
20
40
00
60
20
00
00
80
60
00
80
34
06
59
0.000
0.930
0.946
0.953
0.957
0.965
0.970
0.975
0.987
0.991
0.997
1.000 12378-PeCDF
1.005
1.010
1.024 23478-PeCDF
1.029
1.041
1.046
1.058
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:19 01710/98
164
-------
Page No.
01/10/98
Listing of a980030B.dbf
Matched GC Peaks / Ratio / Ret. Ti
Compound/
M_Z.... QC.Log Omit Why . . RT. OK Ratio Total. Area... Area. PeaJc. 1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
340-342
18 Peaks
965,830.59
13C12-PeCDF
352-354
N
352-354
PeCDD
356-358
356-358
13C12- PeCDD
368-370
368-370
DC NL 0
26
26
27
27
28
28
28
28
29
29
29
29
29
30
30
:00
:25
:35
:43
:55
:11
:18
:34
:51
:03
:14
:29
:40
:51
:15
:27
1
RO
RO
RO
RO
RO
RO
RO
RO
15 Peaks
DC NL 0:
27;
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
:00
49
:18
:31
40
50
01
06
18
26
36
44
04
1.
RO
RO
RO
RO
.32-1.78
0.96
1.38
1.71
1.05
1.52
2.32
1.99
1.51
1.57
1.94
1.57
1.17
1.47
0.94
1.39
0.50
0.860-1.140
23
43
67
168
334
23
109
11,471
404
96
9,483
318
128
64
122
13
.95
.71
.62
.53
.92
.72
.32
.75
.58
.87
.27
.17
.93
.47
.66
.61
22,852.13
32-1.78
1.11
1.20
1.21
1.58
1.52
1.54
1.54
1.55
1.47
1.09
1.53
1.60
1.59
12 Peaks
DC NL 0:
27:
27:
28:
28:
29:
29:
29:
29:
29:
30:
00
42
48
18
30
07
35
42
49
59
05
1.
RO
RO
RO
RO
RO
RO
RO
32-1.78
1.17
2.33
3.83
0.76
1.48
1.69
1.51
1.37
5.03
2.17
1.13
10 Peaks
9.
55,113.
3,666.
35,938.
7,219.
23,679.
3,486.
8,227.
9,656.
4,951.
6,431.
4,696.
4,547.
167,616.
,59
.56
.98
.40
99
52
53
41
81
49
72
85
50
76
25
42
102
202
21
85
6,902
247
73
5,787
193
76
39
71
8
.38
.71
.44
.24
.59
.10
.78
.12
.71
.10
.40
.73
.19
.37
.27
18
24
97
132
9
42
4,568
157
37
3,696
164
52
41
51
16
.33
.91
.84
.68
.30
.87
.97
.46
.99
.17
.98
.20
.56
.29
.67
0.000
0.925
0.931
0.970
0.977
0.987
0.991
1.000 13C12-PeCDF 123 IS2
1.010
1.017
1.023 13C12-PCCDF 234 SOR1
1.032
1.039
1.045
1.059
1.066
33,500.
.40
2,228.95
21,996.
4,354.
14,351.
2,111.
5,006.
5,754.
3,009.
3,893.
2,892.
2,794.
50
.29
.90
75
SO
76
73
72
28
02
28,010.
1,849.
13,941.
2,865.
9,327.
1,374.
3,220.
3,902.
2,769.
2,538.
1,804.
1,753.
0.935-1.022
80
48
90
70
62
78
81
05
48
00
57
48
0.000
0.940
0.957
0.964
0.969
0.975
0.981
0.984
0.990
0.995
1.001 12378 -PeCDD AN
1.005
1.016
0.865-1.135
8.
17.
25.
14.
59.
20.
5,672.
774.
37.
50.
20.
6,693.
82
31
73
20
44
46
58
58
69
97
22
18
15.
38.
8.
35.
12.
3,413.
447.
74.
43.
12.
85
61
63
48
84
92
69
36
31
29
6.
10.
11.
23.
7.
2,258.
326.
14.
19.
10.
79
09
42
96
62
66
89
78
99
83
0.000
0.936
0.940
0.957
0.963
0.984
1.000 13C12-PeCDD 123 IS3
1.004
1.008
1.014
1.017
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1901/10/98
165
-------
Page No.
01/10/98
Listing of 09800308.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags:
HxCDF
374-376
.
AN
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
1.05-1.43
DC NL 0:00
31:04
31:13
31:22
31:31
31:40
31:51
32:02
32:08
32:15
32:25
32:37
33:23
33:27
13 Peaks
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.33
.24
.25
.17
.22
.36
.21
.27
.19
.35
.25
.32
.15
.15
1,154.72
77,351.50
174,348.40
18,587.28
23,228.90
14,751.59
1,639.55
169,496.20
74,959.40
20,727.18
31,775.90
87,560.70
5,060.00
19,260.00
718,746.60
42
97
10
12
8
94
40
11
17
49
2
10
,744.90
,007.30
,034.50
,785.50
,499.68
898.73
,940.20
,675.20
,894.80
,655.10
,873.10
,710.00
,300.00
34
77
8
10
6
74
34
8
14
37
2
8
0.43-0.59
DC NL 0:00
31-: 13
31:30
31:35
31:49
32:02
32:08
32:25
32:36
32:54
33:22
10 Peaks
DC NL 0:00
31:34
32:00
32:12
32:22
32:44
32:49
33:06
7 Peaks
DC NL 0:00
32:43
32:48
33:07
3 Peaks
RO 0.90
RO 0.76
RO 1.91
RO 1,
RO 1.
0.
0.
RO 0.
0.
RO 1.
0.
1.05-
1.
1.
1.
1.
1.
1.
1.
1.
1.05-
1.
1.
1.
1.
,08
,32
,50
51
61
52
71
51
» L-__
1.43
41
18
22
19
14
33
21
27
1.43
23
23
21
20
47.58
196.87
32.95
13.82
49.33
7,621.28
9,244.28
268.76
9,013.19
101.26
6,726.35
33,268.09
re : HxCDF /
384.09
16,079.72
89,918.40
36,291.10
6,329.26
6,253.39
12,376.73
17,442.07
184,690.67
2
3,
3,
2,
99.07
41.58
9.84
43.08
,552.25
,120.20
108.96
,084.23
114.40
,262.79
5
6
5,
4,
0.962
,606.60
,341.10
,552.78
,443.40
,251.91
740.82
,556.00
,284.20
,832.38
,120.80
,687.60
,350.00
,960.00
0
0
0
0
0
0
0
0
1
1
1
1
1
1
-1.047
.000
.967
.971
.976
.981
.985
.991
.997 123478-HxCDF
.000 123678-HxCDF
.004
.009
.015 234678-HxCDF
.039 123789-HxCDF
.041
AN
AN
AN
AN
0.876-1.124
130.38
21.82
9.15
32.67
,069.03
, 124 . 08
177.99
,928.96
67.06
,463.56
0
0
0
0
.000
.971
.980
.983
0.990
0.997 13C12- HxCDF 478
1.000 13C12-HXCDF 678
1.
1.
1.
1.
,009
,015 13C12-HXCDF 234
024
038 13C12-HXCDF 789
STO2
IS4
ALT2
ALT1
8,
49,
19,
3,
3,
6,
9,
695.27
458.40
721.40
366.61
572.42
776.18
754.45
7,
40,
16,
2,
2,
5,
7,
0.958-1.014
384.45
460.00
569.70
962.65
680.97
600.55
687.62
0.
0.
0.
0.
0.
0.
1.
1.
0.970-
50.24
5,538.31
8,940.53
13,562.19
28,041.03
3,
4,
7,
049.96
897.56
411.28
2,
4,
6,
488.35
042.97
150.91
0.
0.
1.
1.
000
962
976
982
987
998 123478-HxCDD
001 123 678 -HxCDD
009 123789-HxCDD
1.030
000
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
AN
AN
AN
SUR3
IS5
RS2
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:19 01/10/98
166
-------
Page No.
01/10/98
Listing of U980030B.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HpCDF
408-410
408-410
13C12- HpCDF
418-420
418-420
HpCDD
424-426
D
DC NL 0
35
35
35
36
0
:00 RO
:01
:17
:26
:32
.88-1.20
2.81
1.05
0.97
1.07
1.04
4 Peaks
DC NL 0
35:
36;
0
:00 RO
:00
32
2 Peaks
DC NL 0:
DC WL 35:
35:
36:
0.
00 RO
09 RO
18
02
.37-0.51
1.53
0.44
0.43
ve : nxi-ui
58
257,682
50,073
70,998
32,059
410,813
28
6,848,
5,504,
u /
.87
.00
.60
.30
.50
.40
,70
,81
.47
12,353.28
88-1.20
1.21
0.45
1.02
0.96
47.
882.
56,558.
51,793.
29
08
10
10
npi.ur toj.j.i
131,853
24,647
36,622
16,331
2,096
1,649,
.00
.90
.50
.40
.17
.00
0.
125,829.00
25,425.70
34,375.80
15,728.10
0.
4,752.64
3,855.47
996-1.049
0
1
1
1
1
943
0
1
1
.000
.000 1234678-HpCDF
.008
.012
.044 1234789-HpCDF
-1.114
.000
.000 13C12-HpCDF 678
.044 13C12-HpCDF 789
AN
AN
IS6
SUR4
HpCDD Follows - • --
28,577.
25,417.
10
50
0.975-1.005
27,981.00
26,375.60
0
0
0
1
.000
.975
.980
.000 1234678-HpCDD
AN
424-426
2 Peaks
108,351.20
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
0.88-1.20
DC
NL 0:00
36:02
1 Peak
1,17
1.02
43.82
6,328.37
6,328.37
3,202.07
0.972-1.028
0.000
3,126.30 1.000 13C12-HpCDD 678 IS7
HpCDD / Octa-CDD and CDF Follows
0.76-1.02
DC NL 0:00 RO 2.53
39:49 0.88
1 Peak
DC NL
0:00
39:36
1 Peak
0.76-1.02
0.98
0.85
0.76-1.02
DC NL 0:00 RO 1.34
39:35 0.86
1 Peak
37.03
125,087.40
125,087.40
13.81
59,562:90
59,562.90
16.93
9,121.26
9,121.26
0.899-1.101
0.000
58,422.20 66,665.20 1.006 OCDF
0.899-1.101
0.000
27,361.30 32,201.60 1.000 OCDD
0.996-1.004
0.000
4,222.49 4,898.77 1.000 13C12-OCDD
AN
AN
IS8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:19 01/10/98
167
-------
Page No.
01/10/98
Listing of O980030B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Tine (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
•••• End of Report •••
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
r±le-.a980030 tl-723 Acq: 6-JAK-199S 20:29:20 SC EH- Voltage
SIS 70S Noiae: 481530
303.9016 T:2 BSUB(256r30, -3 .0) PKD(9,5,3r0.10\,1926120.0,1.00\,r,T) Exp:SDS5OS
TSIAUSZE LABS Text:161-164 TLI»44376A
100.
80.
SO.
40.
20.
Al
A6.49E8
A
A7.26B8 A3. 64X8 \
A A4.7axan. \
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/\ /\/\ /Vv/v/V/lVyvAJ
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n r
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1 A2.25X8
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.1 . 8X8
'.1.4E8
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SIX 70S Noiaes 603623
305.8987 r:2 BSUS(256,30,-3 .0) PXD(9,5, 3, 0.10\,2414492.0, 1.00\,r,T) Xxp:JO>B5US
TSIAHGLX LASS Text: 161-164 TLIt44376A
lOOi
80.
60.
40.
20.
Al
A9.16E8
A
A9.69IB A4.94X8 l\
A A6.55E8I\ /
A2.03X8 /HA /A A /H* I A A
/\ /\/\ /vv/v/v/i \J\A]
22:00 ' 23:00 24:00
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SIS 70S Noiao: 19022
315.9419 T:2 BSU3( 256,30, -3 .0) PXD(9,5,3,0.10\,76088.0,1.00\,r,T) XxptSDBSUS
TSIAXSLX LASS Text:161-164 TLIt44376A
1001
ao:
60:
40:
20:
A6.
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'22:00 23:00' 24:00
rile:O980030 tl-723 Acq: . 6-J3OT-1998 20:29:20 GC XH- Voltage
6E7
V
1.4X7
.1.1X7
.8.5X6
.5.7X6
.2.8X6
25:00 26\00 ' Time
SIS 70S X0±ae:9716
317.9389 T:2 BSUB(256, 30, -3. 0) PXD(9,S, 3,0.10\, 38864.0, 1.00\,T,T) XxpsSDBSUS
TRIANGLE LABS Text:161-164 TLIt44376A
1003
ao:
60:
40:
20:
o:
AB.
_j
'22:00 23:00 24:00
rila:O980030 tl-723 Acq: 6-JXS-1998 20:29:20 GC XH- Voltage
330.9792 T:2 Elp:SDB5US
TSIASGLX LASS Text: 161-164 TLIt44376A
1003
ao:
60:
40:
20:
oj
21:49 22:46 23:26 24
'0X7 1.9X7
\^
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0.0X0
25:00 ' '26:00 ' Time
SIS 70S
l37 25:14 25:51 26:13 -7.9X7
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r±le:U980030 tl-723 Acq: 6-JA1T-1998 20:29:20 GC XI+ Voltage
375.8364 Ft 2 ExptXDBSUS
TSIAHGLX LASS Text: 161-164 TLH44376A
ion
ao:
60:
40:
20:
.6.3X7
.4.7X7
.3.2X7
.1 . 6X7
o.oto
25:00 26:00 Time
SIS 70S
25:58 -4.5X5
A
24:44 f \
23:20
22:00 23:00 24:00
A V —
/ wV^^^lL^ly V^V^^VU^-AV
.3.6X5
.3.7X5
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.8.9X4
O.OTO
'a5«00 26]tOO Time
163
-------
r±J.*sO980030 tl-723 Acq, 6- JAN- 19 9 8 20(29(20 SC XI+ Voltage SIS 70S Noim»,3526
319.8965 f:2 BSUS(256,30,-3.0) PXS(7,5,3,0.10\r14104.0,1.00\,r,T) ExpsNDBSOS
TRIANGLE LABS Text (151 -154 TLIt44376A
1002
80.
60.
40.
20.
0
1
\ r
A2.42E3
Al . 01X8
A AJ..19X8
>>^ y \^^\^ yv ^s \ ^^ ^^
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rlle>O980030 tl-723 Acq: 6 -JAN- 19 9 8 20t29s20 SC XI + Voltage SIS 70S Sbi*e: 50415
321.8936 Ti2 BSUB(256,30,-3.0) PXD( 7,5,3, 0 .10\, 201660. 0,1. 00\,T,T) ExpiBDSSOS
TRIANGLE LABS Toit: 161-164 TLH44376A
1001
80.
60.
40.
20.
0
1
1
A3.14E8
A1.33SS
A A1.52JT8
A4.09E7 /\ A7.98X7 A3. 67X7 .j\
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Tilei0980030 tl-723 Acq: 6-JAN-1998 20(25(20 SC XI+ Voltage SIS 70S Soiae>10393
331.9368 Ti2 BSUB(256,30, -3.0) PKD(7,5,3,0.10\,41572.0f1.00\,r,T) ExpsKDBSUS
TRIANGLE LABS Text: 161-164 TLH44376A
1003.
80J
50.
40:
20:
0
A9.j»5*7 -2.4X7
ft
I.,4.80E7
A
A
} v V
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Ll . 4r7
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0.0X0
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.7.9X7
.6.3X7
.4.7X7
.3.1X7
J..6X7
0.0X0
23(00 24(00 25^00 ' 25(00 Mae
*' ^ n
i * 0
-------
.Tile: (75 8 00 JO tl-723 Acq: 6-JAN-199B 20:29:20 GC EH- Voltage SIS 70S SOia»:6420
339.8597 Ti2 3SQB(2S6e30,-3.0) PB>(7,5,3r0.10\t25680.0r1.00\,T,T)
XxptHDBSUS
TSIAOGLX LABS Text: 161-164 TLIt44376A
10 Voltage SIS 70S Xoia»:5946
341.8567 T:2 BSVB<256,30,-3.0) PO)(7,S, 3,0.10\,23784 .0,1.00\,T,T) XxptBDBSOS
TSIAHGLX LABS Text .-151-1 54 TLIt44376A
1003
80.
60:
40J
"
20:
o:
A8.
A'
A/
J V
27i 00 '
3X8
A4.33X8
A
1 97E8 A / W-ff
-------
27:48 28:00 38:13 38:34 28t36 28:48 29:00 29:13 29:24
r±lt:O980030 tl-723 Acq: 6-JAN-1998 20:39:20 GC XH- Volttgm SIX 70S So±aa:2619
357.8516 T»2 BSU3(2S6,30,-3.0) PXD(5,5,3,O.OS\,10476.0,1.00\,f,T) ExptKDBSUS
TRIANGLE LABS Imxt: 161-164 TLI944376*
100\A2.80X8
|*ila»PgflOOJO il-733 Acq: S-JAK-1S9B 20i29:20 SC £1+ Voltage SIS 70S Noia»>2913
355.8546 Ti2 3303(356,30,-3.0) PKD(5,5,3,0.05\,11652.0,1.00\,r,T) ZxpiXDBSUS
TRIANGLE LABS T*rt: 161-164 TLXM4376&
1001
80.
60.
40.
30.
A3.35X8
A3.20X8
A1.44E8
AS. 75X7
A3.01X7 A A3.89X7
' 7VyY/W
A3.79X7
/\
30:34
so:
60.
40.
20.
A1.39X8
AS. 33X7
A3.90X7
A3.23X7
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\rilaiO980030 tl-723 Acq: 6-JXB-1998 20:29:20 SC XI+ Voltage SIS 70S Soiae:2679
367.8949 t:2 BSUB(256,30,-3.0) PXD(S,5,3,0.05\,10716.0,1.00\,r,T) S3Cp:lO)B5US
TRIANGLE LABS Tart:161-164 XLI944376A
1001 A3.41S7
80.
60.
40.
20.
48X6
37:48 28:00 28:12 28:24 28:36 28:48 39:00 39:13 39:24 29:36 29:48 30:00 30:12 30:24
r±la:0980030 tl-723 Acq: 6-JZX-1998 20:29,20 GC XI+ VoltJtgo SIS 70S Xolae:2294
369.8919 r:2 BSU3(256,30,-3.0) fXD(5,S,3r0.05\,9176.0,1.00\,r,T) Xxp:X3BSUS
TBIANGLS LABS Tort: 161-164 TLXt44376A
1004 A2.26X7
80.
60.
40.
.37X6
27i48 28:00 28:12 28:24 28:36 28*48 29:00 2S:12 29:24 29:36 29:48 30:00 30:12 30:34
rJHe:U980030 91-733 Acq: 6-JMJ-1998 20:29:20 GC EI+ Voltage SIX 70S
330.9792 r:2 Elp:HHBSU3
TRIANGLE LABS Text: 161-164 TLH44376A
100\
801
60.
40.
30.
0.
27:46
29:21
39:53
30:22
8.2X7
1.6.6X7
.4.9X7
.3.3X7
.1.6X7
0.0X0
Tim,
6.6X7
.5.3X7
.4.0X7
r
\.2.6X7
h
^1.3X7
0.0X0
Tia
-9.8X6
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O.OEO
Tlae
6.6E6
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4.0X6
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1.3X6
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Timel
' JO»Ji' 30:24
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.6.3X7
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.3.1X7
.1. 6X7
.0.0X0
Tlae
172
-------
rila:U980030 tl-385 Acq: 6 -JAN- 19 9 8 20:29:20 GC ET+ Voltage SIS 70S Noiae: 329400
373.8208 F:3 BSOB(256, 30, -3.0) ?XD(7,5,3,0.10\,1317600.0,1.0Q\,r,T) Kxp:HD35US
TXIAHSLX LABS
1001 A9
80.
60.
40.
20.
A4.27X8
A/
Text: 161-164 TLIt44376A
'OE8 ,„ ...
2.9X8
, A9.49EU
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Jiibb Jiiij 3l':34 31:36 31:48 32*00 33', 12 32: 24 32:36 32:48 33:00 33,12 33:34 33:36 33:48 Time
nj.»,O980030 tl-385 Acq: 6 -JAN- 19 9 8 20:29:20 GC XX+ Voltage 5JX 705 Noise, 247961
375.8178 T:3 1
i. rme7.5.3
0 2. 0 % 991 844 0 J. 00 % f T ) g»*n tJlDSSUS
TSIAUGZX LABS Text;151*l£4 TLIt44376A
1001 A7.7
80.
ffOj
40^
h
f
I
A3.46ZS
A)
2 3X8
Ca A7.46X8
A
1 1
Al . 04X8 I
'
'
A3.77»a
\J \ A1.41X8 \ A1.07X8
r \^LJ^J \ ^/^
.1.9X8
'•-1.4S8
.9.4X7
.4.7X7
Jiioo' 31:12' 31:24' 31:36' 31:48 32:00 32:12 32,24 32': 36 32:48 ' 33:b6 ' 33\J.2 ' 33:24 JJiJff 33': 4 8 Time
rile >U9 80030 tl-385 Aoj: 6 -JAN- 19 9 8 20:29:20 GC XT* Voltage SIS 70S Noise: 14130
383.8639 T:3 BSU3(256e 30, -3.0) tXD(7,5,3
XSIANGZX LABS
1001
80:
SO:
40:
20:
oj
T*xt:161-164 TLH44376A
AJ
1
Jitbb 31:12 '31:24 3l':36 31:48 32:00
,0.10\,56S20.0,1.00\rr,T) ExpiNDBSUS
•I2*7 A3. 08X7
' Wr-,^
A2.26E7
A
A
I \
9.1X6
'.7.3X6
.5.4X6
.3.6X6
ll . 8E6
0.0X0
331, 12 3 21: 24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 Time
riletU980030 tl-385 Actj: 6-JAK-1998 20:29:20 GC XI+ Voltage SIS 70S Noiaei 15755
385.8610 Fi3 BSVB(256,30,-3.0) tXD(7,5,3
TXIANGLX LABS
1001)
.
aoj
soj
40:
201
oj
^^~
Tart «1 51 -1 64 TLIt44376A
A6
1
JltOO 31:12 31:24 31:36 31:48 32:00
,0.10\,63030.0f1.00\re,T) Sips HUBS US
'.1317 AS. 93X7 ^1.7X7
^^ 1
,
A4.46E7
A
A
\
L^ / v_
•.1.4E7
.1 . OE7
-.6.9E6
-.3.5X6
' 0 . 0X0
32:12 32:24 32:36 32\4a 33': 00 33\12 33\24 33': 3 6 33': 4 8 T±me
riletU980030 tl-385 Acq: 6 -JAN- 19 9 8 20:29:20 GC ZZ> Voltage SIS 70S
392.9760 T:3 ElptNOBSUS
TSIASSLX LABS
1001
80:
60:
40:
20:
oj
.» .^AN^^,
Text., 161-164 TLIt44376A
r — • ^nc ~^ r ^ Ir"
Jiibb 31:12' 31:24 3i':36 31:48 33:00
Sl^^v^^JlJ^l^p^-v^^
.3.6X7
.2.9X7
.2.2X7
JL.5X7
.7.3X6
0.0X0
3 2': 12 32:24 32:36 33:48 33:00 33:12' 33:24' 33: 36 33': 48' ' Time
rile, 0980030 tl-385 Acq: 6-JAN-1998 20:29:20 GC XH- Voltage -4TS 705
445.7555 r:3 XxptHDBSVS y fO^/ft
TSIAXSLX LABS Toxt:161-164 XLIt44376A *— \ V l
1001
aoj
60:
401
30:
o-
32:0
3l',bb 31:12 3l': 24 31:36 31:48 32:00
32
2
35 ^..1X6
£.\W
33:22
/i
v^-^__ __ ) \_ .. _ _ . _ yv_
.8.6X5
.6.4X5
.4.3X5
.2.1X5
O.OEO
32:12 32:24 32: 36 ' 32i48' 33:00 33:12 JJi 24 '33: 36 33\48 Time
-, »
i <
-------
31,36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
f±le:U980030 tl-385 Acq: 6-JJOT-1998 20,29:20 GC XH- Voltage SIS 703 Noiae: 13852
401.8558 F,3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\rS54Q8.0,1.00\,T,T) Xxp:KDB5US
TRIASGLX LABS Text,161-164 XLH44376A
1004 A7.41E7
rU.a:uSuOOJO tl-JSi Acq: 0-JAH-J.99O ivsjysju sc KH- Voltage SIS 70S Noiae: 111137
389.8156 Ti3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\r448788.0,1.00\,r,T) KxptNDBSUS
XSIASSLX LABS Text: 161-164 TLI944376A
1001 A4.?5X8
80.
60.
40.
20.
A8.70X7
A
A6.78X7
AS. 75X7
31,36 31:48 32:00 32:12 32:24 32,36 32', 4 8 33,00 33,12
fU.e:U980030 41-305 Acq: 6-JXB-199B 20,29,20 SC XX+ Voltage SIS 70S Soiaet 79851
391.8127 Ti3 3303(256,30,-3.0) PXO(7,5,3,0.10\,319404.0,1.00\,T,T) XxpiBDBSUS
XBIARGLX LASS Text: 161-164 TLH44376A
1001 A4.05X8
80.
60.
33124
40.
20.
A7.38E7
A
S. 60X7
A7.69E7
33:24
80.
60.
40.
20.
A4.90X7
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
riletU980030 H-385 Acq: 6-JJOT-1998 20:29:20 GC XX+ Voltage SIS 70S Nolae:11268
403.8529 T:3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,45072.0,1.00\,r,T) EzpiNDBSUS
TSIASGLX LASS Text, 161-164 XLH44376A
1001 A6.15E7
33:24
80.
60.
40.
20.
0.
A4 . 04X7
33
1.6X8
.1.3X8
.9.6X7
.6.4X7
.3.2X7
.0.0X0
36 T±me
-1.3X8
.1.1X8
'.7.9X7
.5.3X7
.2.6X7
.0.0X0
33 36 T±ae
33 36
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00
rlle:D980030 fl-385 Acq: 6-JAW-1998 20:29:20 GC XH- Voltage SIS 70S
392.9760 T:3 Xxp:JO3B5US
TSIAJKLX LABS Text,161-164 TLI944376A
100a\ 31:39 3it*9 32:03 32:25
^V—nrOm/—* -y/^V^V
00:
60.
40.
20.
0.
33:12 33:24 33 36
33:15 33:25
-3.6X7
'.2.9X7
.2.2X7
.1.5X7
.7.3X6
.0.0X0
31:36 ' '31\48 32:00 32112 '32:24 ' 32^36 32\48 ' 33:00 JjilS ' '33\24 ' 33 36 Time
174
-------
Tila:a980030 11-545 Acq: 6-JAS-1998 30:29:20 SC EI+ Vbltagv SIS 70S Noise:40567
407.7818 T:4 BSOB(256,30, -3. 0) PXD(7,5,3, 0.10\,162268.0,1.00\,e,T) Ixp:SDB5VS
TXIAHGLX LASS Tax^: 161-164 XX,It44376A
1001 A1.32X9
SO:
50:
20:
oj
A3.66ES
Al.63X8
35100 35,12 35,24 35,36 35,48 36,00 36,12 36,24 36,36
rila:O980030 H-545 Acq: 6-JJOT-1998 20:29:20 SC fZ> Voltmgu SIX 70S Hois ft 144 32
409.7789 T:4 BSOB(256,30,-3.0) PKJ}(7,5,3,0.10\,57728.0,1.00\rT,T) Exp,XDBSUS
TSIASGLX LASS Tazt) 161-164 TLH44376A
1001 A1.26X9
80:
50:
36,48
40.
20:
o:
A3.44E8
AJ..S7K8
1""rT*"r i i i
35,00
-r
-r
35:12 35:24 35,36 35:48 36:00 36',12 36':24 36:36
r±la:O980030 tl-545 Acq: 6-JAN-199S 20:29:20 SC SI+ Voltago SIX 70S Ifoiae: 15253
417.8253 T:4 SSUS(256f 30, -3. 0) PKD(7,5,3,0.10\,61012.0,1.00\,r,X) Szp:NDB5US
TSIAMSLS LASS Text:161-164 TLI#44376A
1003, A2.10E7
Al. 65E7
36:48
35',00 35:12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
Tlla:O980030 tl-545 Acq: 6-JAN-1998 20:29:20 SC EI+ Voltage SIX 70S Soiae:9965
419.8220 T:4 SSUS(256,30,-3.0) PKD(7,5,3,0.10\,39a60.0,1.00\,T,T)
TB.IASSLZ LASS Text.: 161-164 TLH44376A
1001 A4.75E7
A3.86E7
36:48
35:00 35:12 35:24 35,36 35,48 36:00 36:12 36:24
rila,a980030 tl-545 Acq: 6-JAK-1998 20:29:20 SC EI+ Voltage SIX 70S
430.9729 T:4 Hlp:NDB5DS
TBIAWCTJT LASS Tait:161-164 TLII44376A
36,36
36,48
3.SK8
.2.8X8
.2.1X8
.1. 4X8
.6.9X7
.0.0X0
37:00 -KLae
-3.3X8
.2.6X8
'-2.0X8
'-1.3X8
'-6.6X7
'37:00
.0.0X0
Time
.0.0X0
'37:00 X±ae
37:00
Tiae
1001
80:
50:
40:
20:
35:27
36:04 36:14
36:
35:00 35:12 35:24 35:36 35:48 36:00 36,12 36,24
nieiO980030 tl-545 Acq: 6-JAK-1998 20:29:20 SC XH- Voltugm SIX 70S
479.7165 r:4Kxp:BBB5CS
TRIANGLE LASS Text.: 161-164 TLIt44376A
36:36
36:48
-0.0X0
37:00 Time
1001
80:
50:
40:
20.
oj
35:16
36:59
_1. 0X5
.8.2X4
.6.2X4
.4.1X4
.2.1X4
35:00
35:12
35:24
35:36
35:48
36:00
36:12
36:24
36:36
36,48
0.0X0
371:00 Tiaa
175
-------
-.OS80030 il-545 Acqi 6-JAK-J.SStt JUtiyssv CC EI+ Voltage SIX 70S Noiae:j.iv03
433.7766 T:4 BSUB(356,30,-3.0) PXD(7,5,3,0.10\,56013.0,1.00\,T,T) XxptSDBSUS
TRIASGLX LABS Textj 161 -164 TLIt44376A
100* A3.96K8
35113 35,18 35,34 35,30 35,36 35,43 35,48 35,54 36,00 36,06 36>13 36,18 36,34 36,30
\rilet09i0030 #1-545 Acqi 6-JAN-1998 30,39,30 GC XH- Voltage SIS 70S Boiaei 11589
425.7737 T*4 BSVB(356,30, -3.0) PKD(7,5,3,0.10\,463S6.0,1.00\,T,T) XxpiNDBSUS
TRIASGLX LABS Text,161-164 TLH44376A
A3.80X8
A3.64X8
^6.7X7
15.3X7
^4.0X7
'^3.7X7
'.1.3X7
\r±J.aiU980030 tl-545 Acqt 6-JAN-1998 30,39:30 SC XI* Voltage SIX 70S SoiaeillB33
435.8169 Tt4 BSUB(3S6,30, -3.0) PXV(7,5,3, 0.101,47338.0,1.00\,T,T) XxptSDBSUS
TXZABGLX LABS Texts 161 -164 TZH44376A
100\ A3.30X7
ao:
60.
40.
30.
,.7.6X6
L6.1X6
14.5X6
'.3.0X6
'.1.5X6
.0. 0X0
35', 12 35', 13 35',24 35',30 35-36 35',42 35',48 35:54 36',00 36',06 36', 12 36-18 36',24 36',30 Tlae\
rileiO980030 #1-545 Acq: 6-JAN-1998 20*29*20 SC XH- Voltage SIX 70S Noiaes 10081
437.8140 t*4 3SVB(3S6,30,-3.0) PKD(7,5,3,0.101,40324.0,1.00\,f,T) ExptKDBSUS
TRIASGLX LABS Tetxt: 161-164 TLH44376A
1001 A3.13X7
ao\
.7.4X6
35*12 35*18 35*34 35*30 35*36 35',42 35*48 35',54 36*00 36*06 36*12 36*18 36*24 36*30
rile,U980030 #1-545 Acq: 6-JAN-1998 20*39*20 GC XH- Voltage SIX 70S
430.9729 T*4 XxptNDBSUS
TRIASGLX LABS Text, 161-164 TLIt44376A
3S*33 35,41 36*04 36*14
aoj
.
60.
40.
20.
0.
36,39
'.0.0X0
Time
2.6X7
r
'.2.1X7
-1.5X7
.1.0X7
.5.1X6
35', 13 35', 18 35,34 35',30 35,36 35',43 35',48 35',54 36100 36,06 36,12 36', 18 36',34 36',30
0.0X0
Time\
76
-------
filetO980030tl-545 Acqi S-JAJf-1998 20,29,30 CC El-r Voltage SIS 703 aoiao,24761
441.7428 r,4 BSOB(256,30, -3. 0) PXD(7,5,3, 0.10\,99044.0,1.00\,T,T) KzpiSDBSOS
TRIANGLE LASS Tejct,161-l64 TLIt44376A
10Q\ AS.84X8
901
801
701
sol
501
401
301
201
101
-1.0X8
-.9.4X7
IS. 4X7
17.3X7
16.3X7
15.2X7
.4.2X7
.3.1X7
.2.1X7
J..OX7
0.0X0
35100 36,00 37:00 38,00 39,00
rile,U980030 tl-545 Acq: 6-JAN-1998 20,29,20 GC EH- Voltage SIS 70S Noise,9797
443.7399 Tt4 BSUB(256,30, -3.0) PXZ>(7,5,3,0.10\,39188.0r1.00\,r,T) XxptSDBSUS
TBIASSLX LABS Text: 161-164 TLH44376A
901
801
701
601
501
401
301
201
101
40,00
7E8
35,00 36:00 37:00 38tOO 39:00
r±J.e:0980030 tl-545 Acqi 6-JAW-1998 20i29i20 GC EI+ Voltage SIS 70S
430.9729 t:4 SxptSDBSUS
TSIASSLX IA3S Taxt:161-164 TLH44376A
35,27 36,59 38,39
34,20 34:^9f_ f\^_ 36,04 /\.jY 37,29 38,11
40:00
41 00
-1.2X8
J..1X8
.9.6X7
.8.4X7
.7.2X7
.6.0X7
.4. 8X7
.3.6X7
.2.4X7
.1.2X7
., 0.0X0
41100 Time
35100 36,00 37,00 38,00
Tile,0980030 tl-545 Acqt 6-JAH-1998 20,29,20 SC XI+• Voltage SIX 70S
513.6775 T,4 XxptSDBSOS
TSIASSLX LABS Teit.,161-164 TLXt44376A
100\
39,00
40,00
0.0X0
41 00 Time
35,00
36,00
37,00
38,00
39,00
40,00
0.0X0
41t00 Time
177
-------
01-345 AOJ,6-JAN-in a a 20119120 sc KC+ voltage sis 70s soiaos 3417
457.7377 T,4 BSO3(256,30, -3.0) PKD(7,5,3, 0.10\,13668.0,1.00\,T,T) XxptSDBSOS
TB.XANSLX LASS T*xt: 161-164 TLI444376A
1001 A3.74K8
39t30 39', 36 39t42 39', 48 39', 54 40', 00
rila,O9 80030 tl-545 Aoqt 6-JAN-19 9 8 20,29,20 SC EC* Voltag* SIX 70S Boim*,3492
459.7348 T:4 3303(256,30,-3.0) PKD(7,5,3,0.101,13968.0,1.00\,T,T) KxpiBDBSOS
LASS T*tt:161-164 TLH44376A
100* A3.32X8
39', 30 39', 36 39:42 39,48 39:54 40,00
Tile,0980030 tl-545 Acq: 6-J3UT-1998 20,29,20 SC EI+ Voltage SIR 70S Roiae,602L
469.7779 T:4 SSUS(256,30,-3.0) tXD(7,5,3, 0.10%,24084.0,1.00\,r,T) ErpsXDBSUS
TSIANGLZ LABS Text: 161-164 TLIf44376A
1001 A4.)2£7
80.
39', 30 39,36 39,42 39,48 39,54 40,00
rila,O9S0030 H-545 Aoq, 6-J7OT-1998 20,29,20 SC EH- Voltage SIS 70S Soiae,4482
471.7750 T,4 BSUS(256,30, -3.0) PKD(7,5,3, 0.10\,17928.0,1.00\,r,T) Xxp,BDBSOS
XSIABGZX LABS Text-.161-164 TLIt44376A
iOO\ A4.SOX7
39,30 39,36 39,42 39,48 39:54
nie,O980030 tl-545 Acq: 6-JJUT-1998 20,29,20 SC XI + Voltage SIX 70S
430.9729 T,4 XxpiSDBSVS
XSIAOSLX LASS Text: 161-164 TLH44376A
1001
80.
60.
40.
20:
0.
39159
-4.9X7
'.4.0X7
13.0X7
L3.0Z7
^.9X6
.0.0X0
40106 T±M,
-5.8X7
.4.7X7
'.3.5X7
.2.3X7
.1.2X7
_, O.OSO
40 06 T±a
7.8X6
.6.2X6
.4.7X6
.3.1X6
.1.6X6
10.0X0
40>0«
8.6X6
.6.9X6
.5.2X6
.3.5X6
_, o.oro
40,06 Time
39130
39,36
39142
39,48
39 > 54
40100
11.9X7
11.4X7
L9.JW
.4.6X6
40,06
0.0X0
Time
178
-------
CD
r-
Peak Locate Examination: 6-JAN-1998:20:28 File:U980030
Experiment:NDB5US Function:2 Reference:PFK
-------
File:U980030 #1-723 Acq: 6-JAN-1998 20:29:20 GC EH- Voltage SIR 70S
319.8965 F:2 Exp:NDB5US
Sample Text:161-164 TLI#44376A File Text:TRIANGLE LABORATORIES, INC,
100%. A1.D8E8
25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48
File:U980030 #1-723 Acq: 6-JAN-1998 20:29:20 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:161-164 TLI#44376A File Text:TRIANGLE LABORATORIES, INC
100% A1.JOE8
80j
25:54 26:00 26:06
LO.OEO
Time
0
25lOO 25:06 25il2 25il8 25i24 25i30 25i36 25i42 25i48
File:U980030 tl-723 Acq: 6-JAN-1998 20:29:20 GC EI + Voltage SIR 70S
331.9368 F:2 Exp:NDB5US
Sample Text:161-164 TLI#44376A File Text:TRIANGLE LABORATORIES, INC
100%. 25^08
25:54 26:00 26:06
LO.OEO
Time
_2.4E7
_1.9E7
_1.4E7
_9.6E6
L4.8E6
25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42 25:48 25:54 26:00 26:06
LO.OEO
Time
O
CO
vH
-------
1ile:U980030 #,1-723 Acq: 6-JAN-1998 20:29:20 GC EI + Voltage SIR 70S
39.8597 F:2 Exp:NDB5US
>ample Text:161-164 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%,
CO
vH
-i 1 1 1 r
28:18
I ' • •
28:36
28:06 28:12 28:18 28:24 28:30 28:36 28:42
File:U980030 fljl-723 Acq: 6-JAN-1998 20:29:20 GC El-f Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
Sample Text:161-164 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%
i 1 1 1 1 r-
28:48
28:54
80j
60 j
40J
20j
Oj
A1.68E8 A1.62E8
T
—i—(—i—r-
28:12
-i 1—| r—
28:18
28:06 28:12 28:18 28:24 28:30 28:36 28:42 28:48
File:U980030 #1-723 Acq: 6-JAN-1998 20:29:20 GC El-f Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:161-164 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% 28;34
80J
60J
40J
20 j
28:54
28:06
28:12
28:18
28:24
28:30
28:36
28:42
28:48
28:54
.O.OEO
Time
.1.1E8
.8.7E7
.6.5E7
.4.3E7
.2.2E7
.O.OEO
Time
.O.OEO
Time
-------
CO
•ile:U980030 #1-385 Acq : 6-JAN-1998 20:29:20 GC EI + Voltage SIR 705
73.8208 F:3 ExptNDBSUS
Sample Text: 161-164 TLI#44376A File Text: TRIANGLE LABORATORIES, INC.
lOOi A1.Q3E8
80 j
60 1
40_
20_
0
ile:U980030 #lr385 Acq: 6-JAN-1998 20:29:20 GC EI + Voltage SIR 70S
375.8178 F:3 Exp:NDB5US
Sample Text:16l|-164 TLI#44376A File Text : TRIANGLE LABORATORIES, INC.
lOOi i A8.96E7
60j
40J
20 j
OJ
33:061 33:12 33:18 33:24 33:30 33:36 33:42
File:U980030 #l|-385 Acq: 6-JAN-1998 20:29:20 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:NDB5US
Sample Text: 1611-164 TLI844376A File Text:TRIANGLE LABORATORIES, INC.
100*. i 33;22
33:54
33:48
33:54
80J
60 j
40J
20j
0
33:06
33:12
_3.3E7
_2.6E7
_2.0E7
_1.3E7
16.5E6
lO.OEO
Time
_2.6E7
_2.1E7
_1.6E7
_1.0E7
_5.2E6
O.OEO
Time
_5.8E6
L4.7E6
_3.5E6
_2.3E6
-1.2E6
33:18
33:24
33:30
33:36
33:42
33:48
33:54
LO.OEO
Time
-------
: *"?*
TLI Project:
Client Sample:
Client Project
Sample Matrix: ~
TLI ID:
Sample Size:
Dry Weight
GC Column:
•.' ••••••^
44376A , Method 23 TCDD/TCDF Analysis (DB-225)
161-164 K - - 5 Analysis File: P980098
Gulp Aluminum Alloys
M23TRAIN ~— " Date Received: "12/17/97
194-59-13A-E Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: P980094
DB-225 Analyst JM
~ Spike File':
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
SPC2NF04 •-
PF22206
P980092
: n/a
n/a
n/a
8S5?S§^f
2,3,7,8-TCDF
t$^8m&ae$\.
l3Ciri3,7,8-TCDF
'Recovery stancterd
"CO-1.2A4-TCDD
r^ .:? ;^%nC^" ^jacr^'fe > ;'aw»c^
-------
Initial
, .Date.
Data Review By:
.A/11*
Calculated Noise Area:
the Total Area for each peak with an ion abundance ratio outside
ratio liaits baa been recalculated according to method requirements.
1.00
Page No.
01/07/98
Compound/
TCDF
304-306
Listing of P980098B.dbf
Hatched GC Peaks / Ratio / Ret. Tine
DC NL
DC WH
0.
0:00
18:29
18:45 RO
18:56 RO
19:02 RO
19:08 RO
19:29
19:37
19:45
19:55
20:02
20:11
20:20
20:30
20:39
20:48
21:11
21:38
21:44
21:53
22:08
22:22
22:33
22:41 RO
22:46
23:00
23:07
23:20
23:37
23:44
23:57 RO
24:17 RO
24:32
25:17
25:43
65-0.89
0.65
0.77
1.55
0.61
1.11
0.98
0.77
0.77
0.76
0.77
0.78
0.76
0.79
0.79
0.75
0.76
0.75
0.74
0.76
0.76
0.76
0.74
0.76
0.57
0.79
0.75
0.76
0.75
0.75
0.75
0.59
0.58
0.76
0.73
0.75
304-306
13C12-TCDF
316-318
33 Peaks
0.65-0.89
DC NL 0:00 RO 1.21
DC WL 18:32 RO 0.64
DC WL 20:10 0.70
DC WL 20:33 RO 0.60
DC WL 20:43 RO 1.44
2.94
2,308.95
39.31
23.75
28.62
105.63
2,436.80
2,591.56
5,168.45
2,100.11
167.27
2,576.52
6,085.44
3,377.06
9,073.85
3,139.90
20,021.06
4,195.80
847.14
4,342.05
4,165.30
1,006.07
5,558.11
22.18
17.30
357.40
985.88
982.85
460.08
017.66
27.03
19.81
3,732.70
640.95
30.57
107,622.59
4.44
5.84
19.67
29.63
3.43
.Peak.
1,007
1,
1,
2,
1,
2,
1,
3,
1,
8,
1,
1,
1,
2,
1,
1,
2,
2,
2,
1,
34
10
17
58
058
125
227
911
73
112
678
486
892
358
547
789
366
871
799
426
397
9
7
870
289
134
760
156
11
8
606
270
1. . Area. Peak. 2. . Rel.RT Conpound . Name . . ID.. Flaga.
0.792-1.101
.96
.40
.33
.87
.48
.70
.25
.46
.66
.48
.22
.99
.07
.77
.38
.76
.85
.60
.69
.66
.90
.54
.65
.64
.05
.08
.19
.68
.12
.76
.62
.27
.59
1,
300.
22.
16.
16.
99
21
96
17
59.68
1,
1,
2,
1,
1,
3,
1,
5,
1,
11,
2,
2,
2,
3,
2,
I,
2,
3,
2,
2,
378.
466.
940.
188.
93.
464.
406.
890.
181.
781.
473.
405.
480.
470.
365.
579.
160.
16.
9.
487.
696.
848.
699.
861.
19.
14.
126.
370.
10
31
99
45
79
30
45
99
08
52
30
95
54
36
64
17
57
88
66
35
80
66
40
54
80
92
43
36
0.
0.
0.
0.
0.
0.
,000
800
812
820
824
828
0.843
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
849
855
862
867
874
880 E
887
894 E
900
917 E
937
941
947
958
968
976
982
986
996
001 2378 -TCDF AN
010
022 E
027
037
051
062
095
113
0.957-1.043
0.
0.
0.
0.
0.
000
802
873
890
897
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 04:49 01/07/98
184
-------
Page No. 2 ' Listing of P980098B.dbf
01/07/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.924
0.933
0.944
- 613; 46 -1.000 --13C12-33-78-TCDF- ISO
9.72 1.041
1.077
1.082
1.089
1.105
316-318 2 Peaks 1,104.05
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
WH
WH
WH
WH
21:
21:
21:
«»^
23 :
24:
24:
24:
25:
25:
21
33
49
rt IS
06
03
53
59
10
32
RO
RO
RO
RO
RO
0
0
0
0
0
.0
0
0
.73
.41
.70
.62
.37
.36
.80
.52
15.
9.
23.
Irtnn
t U5rv .
13.
1.
1.
9.
7.
14
70
44
i A i7fi ca
J.4 4 /O .'00'
91 6.05
91
72
03
42
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.89 0.908-1.092
332-334 DC HL 0:00 RO 1.04 2.55 0.000
DC SN 20:30 RO 0.40 2.87 0.948
21:38 0.81 722.82 323.94 398.88 1.000 13C12-2378-TCDD IS1
21:56 0.82 1,605.03 723.03 882.00 1.014 13C12-1234-TCDD RSI
22:43 RO 0.97 7.97 4.36 4.50 1.050
DC WH 23:44 RO 0.44 3.86 1.097
DC WH 23:52 SO 1.14 1.26 1.103
DC WH 24:29 RO 0.17 1.91 1.132
332-334 3 Peaks 2,335.82
Column Description 'Why' Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
RT. -Retention Time (ma:as) WH-Above Retention Time Window K-Peak Kept
t.1 -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO-Ratio Outside Limits
-------
tl-922
303.9016 XzptDB325
XBIAHSLX LASS Tmxtsl61-164 TLIH437SA
t,i+ vo.icag'e SIS 70P
23137
33:36 22:48 33iOO 23tL2 23s24 23s36 23,48 24:00 24:12 24:24 24:36 24:43 25:00 25:12 25:24
r±lesP980098 tl-933 Acqt7-JSS-98 03:33tl9 KI+ Voltage SIS 70P
315.9419 Xxp,DS335
TRIANSLX LASS Texts 161-164 TLH44376A
1003
95.
90.
85.
30.
75.
70.
65.
50:
55.
50.
45.
40.
35.
30.
35.
30.
15.
10.
5J
23:06
'-.1.3S6
'•.1.2X6
'•.1.1X6
'-.1.1S6
'•.9.9E5
19.3S5
'•.8.6Z5
'.7.9K5
.7.3SS
'.6.6S5
.5.9X5
.5.3X5
.4.6X5
.3.9X5
.3.3X5
'.3.6X5
.3.0X5
.1.3X5
.6.6X4
.0.0X0
m ';•, •,',.. ~ , ~V. ......,......'., ". 77. ...... 7 .' .... , . . I "*"
22:36 33»48 33*00 23:12 23:24 23:36 33:48 24:00 24:12 24s24 24:36 24:48 35>00 25tl2 35:34 Time
186
-------
Tila:P9HOQ98 #1-932 Acq:/-JAa-Sa OjtlJilS Elf Voltage SIXTOP ooiaa:5U1
303.9016 BSUB(256,30,-3.0) PXD(S, 3,1, 0.10\, 2324 .0, 0. 00\,T,f) Sxp:DB225
TXIANGLZ LASS Text: 161-164 TLH44376A
100\ A8.5.5X7
19t00 20:00 21:00 33,00 33:00 24:00
rtle:P980098 tl-922 Acq:7-JXK-98 03:23:13 XX+ Voltaga SIX 70P Xoia»t888
305.8987 BSUB(256,30,-3.0) PKD(S,3,1,0.10\,3552.0,0.00\,r,T) KzpiDB225
TXIANSLX LABS Text: 161-164 TL1H4376A
10 0\ AJ..JJX8
25,00
19:00 20:00 21:00 22:00 23:00 24:00
rile:P980098 il-922 Acq:7-J7Ol-9a 03:23:19 SH- Voltage SIX 70P Koiao:1517
315.9419 3SUB(256,30,-3.0) PKD(S,3,1, 0.10\, 6068.0, O.QO\,T,r) Sxp:D3225
TZIANGLX LASS Text: 161-164 TLH4437SA
10 0\ A4.77E6
80.
SO.
40.
20:
25:00
19:00 20:00 21,00 22:00 23:00 24:00
riletP980098 tl-922 Acq:7-JZUt-98 03:23:19 ZI+ Voltaye SIS 70P Xoiao:1257
317.9389 BSVB(256,30,-3.0) PKD(5,3,l,0.10\,5028.0,0.00\,r,r) Sxp:DB225
TRIASSLX LABS Text: 161-164 TLIt44376A
100S, A6.13E6
80.
SOL
40.
20:
25:00
19:00 20:00 21:00 33:00 23:00
rile:P980098 tl-922 Acq:7-JXK-98 03:23:19 KI+ Voltage SIX 70P
375.8364 Xxp:DB225
XSIANSLS LABS Text,161-164 TLH44376A
10 0\ 23t04
80:
so:
40.
20:
o:
24:00
25:00
18:34
19:18 20,13 30>" 31:15
21:39
1.3X6
'.1. 0X6
.7.9X5
.5.2X5
.2.6X5
0.0X0
,1. 7X6
,1.3X6
9.9X5
6.6X5
3.3X5
0.0X0
lime
19:00
20:00
21:00
22:00
23:00
24:00
25:00
IS7
-------
l-922 Acqi 7-JAN-98 03s2J>19 EI+ Voltago SIR 7 OP NoimmsSSO
319.8965 3303(356,30,-3.0) PXD(S,3,1,0.10%,3560.0,0.00\,T,I) Xzp,DB225
TRIANGLE ZJUS T*xt:161-164 TLH44376A
1001
80.
SO.
40.
20.
A1.87X7
A4.04X6
A7.30X6
20.00 21:00 22,00 23,00
Tlle,P980098 tl-922 Acq:7-J7UT-98 03:23,19 EH- Voltaga SIS 70P ltoiam,3644
331.8936 3303(356,30,-3.0) PXD(5,3,l,0.10\,14576.0,0.00\,r,r) XxptDB22S
TSIASGLX LASS Taxtt 161-164 TLIH4376A
1001
34100
80.
60.
40.
30:
o:
A3.38X7
A5.26Z6
A
A2.90Z6
A .
A9.34X6
70:00 21:00 22:00 23,00
r±latP980098 tl-922 Acq, 7-JJOT-98 03,23,19 XH- Voltage SIS 70P HOiao>842
337.8847 3SU3(256,30,-3.0) PXD(5,3,l,0.10\,3368.0,0.00\,r,r) XxptDB225
TRIANGLE LASS Tait: 161-164 TLH44376A
1001 A1.98E7
80.
60:
40.
20;
A6.26X6
A1.11X6
/\ Lr*.
A1.54X6
A7.06X6
A
20:00 21:00 22,00 23:00
rilaiP980098 tl-922 Acqt7-JJUT-98 03:23,19 XH- Voltage SIX 70P Abide: 752
331.9368 BSVB(256,30,-3.0) PXD(5,3,l,0.10\,3008.0,0.00\,r,r) Exp:DB225
TRIANGLE LASS TOXt,161-164 TU944376A
1001 A7.23X6
80.
eo:
40.
20J
A3.24X6
20:00 21:00 22:00 23,00
T±letP9B009B tl-922 Acqt7-J3UT-98 03,23,19 XH- Vbltaga SIS 70P Nolae,718
333.9338 BSUS(256,30, -3.0) PKD(5,3,1, 0.10\,2S72.0,0.00\,F,r) XxptDS235
TRIANGLE LASS Text, 161-164 TLII44376A
1001 AS. 82X6
80.
60.
40.
20.
0.
A3.99X6\
20100
21:00
22:00
23100
24:00
A1.39X7
24,00
24100
24,00
C9.3X6
'.7.4X6
-.5.6X6
.3.7X6
H.9X6
^ '.0.0X0
25 00 tta<
-1.2X7
J.2X6
.6.9X6
.4.6X6
,2.3X6
25
0.0X0
00 Time
5.6X6
.4.5X6
.3. 4X6
.2.3X6
.1.1X6
.0.0X0
25100 T±me
_1. 8X6
J..4E6
.1.1X6
'.7.1X5
.3.6X5
.0.0X0
25 00 T±me
2.3X6
.1.8X6
'.1.4X6
.9.2X5
.4.6X5
.0.0X0
25 00 T±a>
183
-------
r±J.a:P980098 tl-922 Acqi7-J3ur-98 03:23:19 XI+ Voltage SIS 70P
303.9016 Kxp:DB22S
TSIANSLX LABS Text:161-164 TLH44376A
1001 31:11
ao: 1
,-: 20:39 \\
60: ill
: 19tts \
40' *.»<••-' 30:20 11 1 1
" A ' A 1 A
TA mw\i\ l\ 1
19 1 00 20 1 00 21 • 00
rile:P980098 tl-922 Acq:7-JJX-98 03:23:19 XH-
315.9419 Xxp:DB225
XBIA1KLX LABS Text: 161-164 TLIt44376A
1001
80:
60:
40:
20J
19\ob 20(00 21:00
rile:P980098 tl-922 Acq:7-JMl-98 03:23:19 XH-
319.8965 Xxp:DB22S
TRIANGLE LABS text.: 161-164 TLH44376A
100S 15(18
•«!
60: ».«
'"
30- 20:32 3i:17
o- 1 v 1 \ AyvA/\-*
19iOO 30(00 ' 3lioO
fJJ.e:P980098 tl-922 Actj:7-JSS-98 03:23:19 XX+
331.9368 Exp:DB225
TRIANGLE LABS Text: 161-164 TLH44376A
1001
80:
60-
<°i |
-
n. l\
19tOO 20:00 21:00
rlle:P980098 tl-922 Acq:7-JJOT-98 03:23:19 XH-
292.9825 Sxp:DB225
TRIANGLE LABS Text: 161-164 TLIt44376A
22:33
_i . 4r7
.1.1J7
.8.1E6
23:37
21:53 l 23(20 A . £5.4*5
A . A A ji
Jt Jl M/
32(00 3J(00
Voltxg* SIS 70P
23:06
\ I
33:00 ' ' 2.3(00
Voltage 512 70P
21:57
•+S>f\n. ^ —-
33i 00 ' 23:00
Voltage SIS 70P
21:56
38\
\\
22:00 23:00
Voltage SIS 70P
1004 ^ii/5 1S±36 20:1320:38 3J-:1£ 21:49 22:24 32(54
00:
60:
40:
20:
o'-
19\00 20(00 21(00
rile:P980098 tl-922 Acq:7-JAIt-98 03:23:19 XH-
330.9792 Xrp:DB225
TRIASGLX LABS Text: 161-164 TLIt44376A
1004 15,03 19:33 20:31 21:0021:27
so: 'rTT ^*
60.
40:
20:
o-
19:00 20:00 21(00
22:00 23:00
Voltage SIS 70P
-^Y-V^^^^^^^V
32(00 23(00
A 24: 32
\m 1 -"7W
V / v \ 7V ^ o.ato
24:00 ' 25(00 Time
1.3X6
'.1.1X6
'-.7.9X5
.5.3X5
.2.6X5
24:00 ' ' 25(00 ' ' Time
9.3X6
'-.7.4X6
'•.5.6X6
.3 . 7X6
-.1 . 9X6
T r o.oxo
24(00 ' 25(00 ' Mae
1 . 8X6
.1.4X6
.1.1X6
.7.2X5
.3 . 6X5
: a . oro
24:00 25:00 ' ' Time
24:01 ._24^47_25;J.3 ^9.1X6
.7.3X6
.5.5X6
.3.7X6
.1.8X6
.0.0*0
34(00 35(00 Mae
_^ ^. 34U5 25;13 7. 7X6
/K^k^VVVV-T »>«•• ^•w>*w^v»>>y
.6.2X6
.4.6X6
.3.1X6
.1.5X6
O.OKO
24(00 25(00 Mae
-------
Ref, uss 292,9825 Pe* top
Height 1,88 wits Spa 288 opt
Systet file naie
Resolution
Group niter
lonization lode
Switching
Ref. lasses 292,9825,
fl 232.9825
6 383,8618
COK 0001
OWiWQ/
D 315,3419
E 317,9389
F 319,8985
6 321,3936
H 327,8847
I 338,9792
J
K
L
I
1
El*
VOLTAGE
388,9761
338,9792
331,9368
Oral I 338,9792 Pe*top
Height 1,18 volts Spa 288 ppi
•> r> n
JL JU
-------
TLI Project: 44376A
Client Sample: 165,167,168/225
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980031
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
Gulp Aluminum
M23TRAIN
194r59-14ACD
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMTT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2.3.7.8-PeCDD
1.2.3,4,7,8-HxCDD
1^3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2.3,7,8-TCDF
1A3.7.8-PCCDF
Z3,4J,8-PeCDF
1 ,2.3,4,7,8-HxCDF
1.2,3,6.7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1.23.4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2^,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDE)
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt $tg) ^ QL mpG
0.51
3.6
4.7
7.4
10.3
40.0
63.1
64.6
15.8
28.7
97.5
32.5
47.4
2.8
155
25.6
160
Amt {ng} Mumber DL EMPC
76.5 12
58.1 9 92.2
114 7
80.3 2
370 16
391 14 393
403 13
262 4
Ratto
0.77
1.51
1.23
1.26
1.28
1.01
0.85
0.74
1.61
1.55
1.27
1.20
1.25
1.26
1.07
1.06
0.89
-
RT
25:20
29:38
32:44
32:49
33:07
36:03
39:37
24:39
28:34
29:18
32:02
32:09
32:39
33:23
35:02
36:33
39:50
Frags
PR_
iZ
E_
iZ
iZ
PR_
E_
iZ
Flags
E_
iZ
E_
E_
E_
E_
E_
Page 1 of 2
MTT2.PSR 11.01. LARS 6. laogi
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:19 01/10/98
131
-------
TLI Project:
Client Sample:
44376A
165,167,168/225
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980031
; mtenra S&rtdards '
I3Cir2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,2-12,3,7,8-PeCDF
13G1J-12,3.7.8-PeCDD
13Cl2-12,3,6,7,8-HxCDF
13C,2-12.3,6,7,8-HxCDD
13C,2-12^,4,6,7,8-HpCDF
l3C12-12,3,4,6,7,8-HpCDD
I3C ,2- 1 2,3,4,6,7,8 ,9-OCDD
Surrogate Standards fType A)
I3C,2-2,3,4,7,8-PeCDF
13C,2-12,3,4,7,8-HxCDF
13C12-1.2,3,4,7,8-HxCDD
3Clrl,2,3,4,7,8,9-HpODF
Surrogate Standards {Type A)
"CU-2,3,7,8-TCDD
Alternate Standards {Type A>
13C,2-12,3,7,8,9-HxCDF
13C12-2,3,4,6.7,8-HxCDF
:; Recovery Standards
13C,2-1A3,4-TCDD
l3C12-U,3,7,8,9-HxCDD
,
$i$a$'****
3.0
2.7
3.0
2.9
3.1
3.2
3.4
3J
6.4
,^i»t frgl
3.4
4.1
3.9
3.7
f£ff(&, §1§)
3J
Ana. (ng)
32
32
^ '
-;^ >« Recover^
75.3
68.4
74.6
71.4
77.0
80.8
85.0
88.5
80.0
% Recovery
85.5
104
97.1
93.7
, %Becovery
82.9
% Recovery
80.7
79.9
-
', •'
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
40%-130%
40%-130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
"•- Bbtt
7 %%£. **&*&'', ,
0.75
0.80
1.56
1.49
OJ2
124
0.44
1.03
0.87
Ratfe
1.54
0.52
1.23
0.44
Ratio
OJl
0.55
Ratio
0.82
124
;%- -ffT -- '""JFiS^s- -
24:37
25:19
28:34
29:37
32:09
32:48
35:01
36:03
39:36
flnr Ptags
29:17
32:03
32:44
36:32
RT Ftegs
25:20
BT Flags
33:23
32:38
RT Flags
25:09
33:07
Data Reviewer.
01/10/98
Page 2 of 2
MTTZ.PSRvlJ)!, LARS&10.0S1
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:19 01/10/98
192
-------
Initial
..Date.
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to nethod requirements.
Page No.
01/10/98
Compound/
M_Z.... QC
TCDF
304-306
K
K
K
K
K
K
K
304-306
J.3C12-TCDF
&16-318
316-318
TCDD
320-322
NK
NK
K
K
M
AN
Hatched GC Peaks / Ratio /
Omit Why ..RT. OK Ratio Total. Area. ..
0.65-0.89
DC
NL 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
25
26:
:00 RO
:27
:58
:12
:35
:55
:19
:35
:49
:02
:13
:27
:39
:03
:16
:32
22
16 Peaks
DC
DC
DC
DC
DC
DC
NL 0:
WL 22:
WL 22:
24:
24:
25:
WH 26:
WH 26:
WH 26:
0
:00 RO
24
:59
03
37
17
09
45 RO
54
3 Peaks
DC
NL 0:
22:
23:
23:
24:
24:
24:
25:
25:
0.
00 RO
48
11
28
09
25
49
14
20
0.59
0.75
0.74
0.74
0.74
0.74
0.73
0.74
0.74
0.75
0.74
0.75
0.74
0.75
0.75
0.73
0.74
3
.65-0.89
1.27
0.82
0.84
0.80
0.75
0.76
0.85
0.93
0.86
6,422.82
81,985.40
79,054.70
87,376.20
451,067.00
291,646.00
322,976.00
223,884.70
267,897.00
356,664.00
136,966.90
126,685.20
576,292.00
141,772.10
115,529.70
21,012.72
14,968.77
,295,778.39
Ret. Time
Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound. Name. . ID.
0.867-1.079
35
33
37
192
124
136
95
114
152
58
54
245
60
49
8
6
,099.80
,749.00
,269.40
,246.00
,256.00
,663.00
,304.70
,147.00
,480.00
,449.90
,168.60
,114.00
,686.30
,697.50
,867.82
,388.32
46
45
50
258
167
186
128
153
204
78
72
331
81
65
12
8
,885.60
,305.70
,106.80
,821.00
,390.00
,313.00
,580.00
,750.00
,184.00
,517.00
,516.60
,178.00
,085.80
,832.20
, 144 . 90
,580.45
0
0
0
0
0
0
0
0
0
0
0
0
1
.000
.871
.892
.902
.917
.931
.947
.958
.968
.976
.984
.993
.001 2378-TCDF AN
. Flags .
E
E
E
E
E
E
E
1.018
1.
.026
1.037
1.071
0.959-1.041
79.86
598.41
953.20
378.73
28,763.40
481.83
520.21
175.85
106.79
29,623.96
65-0.89
0.49
0.77
0.77
0.81
0.76
0.78
0.79
0.77
0.77
177.34
188,101.40
123,705.30
12,374.19
45,571.30
24,302.90
12,193.61
46,900.00
3,120.00
0.000
0.910
12,
168.43
,283.10
207.64
16
210.30
,480.30
274.19
0.
0.
1.
1.
1.
1.
1.
934
977
000 13C12-2378-TCDF ISO
027
062
087
093
82,
53,
5,
19,
10,
5,
20,
1,
050.40
974.40
541.73
743.60
684.90
382.70
400.00
360.00
106,
69,
6,
25,
13,
6,
26,
1,
0.895-
051.00
730.90
832.46
827.70
618.00
810.91
500.00
760.00
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.047
000
901
916
927
954
964
980
997
001 2378 -TCDD AN
E
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01710/98
193
-------
Page No. 2
01/10/98
Compound/
M_Z QC.Log Omit Why
Listing of 0980031B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total. Area. .. Area.Peak.1.. Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
25
25
:30
:40
25:53
320-322
37C1-TCDD
328
- - . - 26.
0.77
0.77
0.
.74
. 1
-------
Page No. 3
01/10/98
Compound/
M_Z.... QC.Log Omit why
Listing of 0980031B.dbf
Matched.GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
D
356-358
13C12- PeCDD
368-370
28
28
29
29
29
30
:44
:52
-:.18
:27
:46
:14
18 Peaks
DC NL 0
26
26
26
27
27
27
27
28
28
28
29
29
29
29
29
30:
:00
:24
:36
:46
:08
:22
:43
:55
:18
:34
:51
:03
:17
:33
:52
:59
:16
1
RO
RO
RO
RO
RO
RO
RO
RO
16 Peaks
DC NL 0:
00
DC WL 27:35
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
50
18
32
41
52
02
07
20
30
38
45
05
1.
RO
RO
RO
RO
RO
1.59
1.65
...1..55
1.55
1.67
1.56
2
.32-1.78
1.20
1.16
1.93
1.54
1.46
1.73
1.60
1.53
32.58
1.56
1.59
3.04
1.54
1.66
1.19
3.16
1.03
78
135
_162
230
46
21
,253
,573.30
,871.70
,442.80
,219.10
,447.90
, 294 . 15
,659.25
48
84
98
139
29
12
,282.90
,681.20
,842.50—
,783.00
,036.80
,979.70
30,290
51,190
63,600
90,436
17,411
8,314
.40
.50
.30-
.10
.10
.45
1.006
1.011
- 1. 026 23478- PeCDF -AN
1.031
1.042
1.058
0.860-1.140
22,
18,
30.44
116.56
103.50
135.65
12.28
149.18
260.33
958.40
504.77
,191.91
754.48
140.17
,338.70
675.57
232.95
51.20
185.77
44,811.92
32-1.78
1.02
0.75
1.07
1.25
1.53
1.53
1.58
1.58
1.55
1.53
0.83
1.51
1.56
1.58
12 Peaks
DC NL 0:
27:
28:
28:
00
48
06
15
1.
RO
RO
RO
32-1.78
0.94
3.43
2.01
1.58
1,
107,
7,
76,
13,
50,
7,
15,
18,
9,
13,
8,
7,
336,
14.13
032.72
958.12
456.68
190.60
846.01
543.60
218.33
000.66
970.71
212.00
287.99
999.70
994.83
679.23
6,
13,
11,
70.85
78.21
82.28
7.28
94.45
160.54
580.33
,449.74
,517.80
463.36
167 . 23
, 127 . 20
422.07
141.60
63.39
112.92
60
40
53
5
54
100
378
197
8,674
291
54
7,211
253
119
20
109
.86
.59
.37
.00
.73
.29
.07
.95
.11
.12
.97
.50
.50
.09
.08
.30
0.000
0.924
0.931
0.937
0.950
0.958
0.970
0.977
0.991
1.000 13C12- PeCDF 123 IS2
1.010
1.017
1.025 13C12-PCCDF 234 STO1
1.034
1.046
1.050
1.060
65,
4,
46,
8,
30,
4,
9,
11,
5,
7,
5,
4,
621.60
532.49
099.70
374.55
962.40
419.59
126.47
485.80
599.45
991.37
478.95
893.29
61,210.
3,619.
30,090.
5,471.
19,581.
2,798.
5,874.
7,484.
6,707.
5,296.
3,520.
3,101.
0.935-1.022
00
39
90
46
20
74
19
91
67
62
75
54
0.000
0.931
0.940
0.956
0.963
0.968
0.975
0.980
0.983
0.990
0.996
1.001 12378-PeCDD AN
1.005
1.016
0.865-1.135
9.34
97.36
17.90
79.72
130.93
14.12
48.80
38.
7.
30.
18
02
92
0.000
0.939
0.949
0.954
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
195
-------
Page No.
01/10/98
Listing of 0980031B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Ar ea. Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
368-370
HxCDF
374-376
28
29
29
29
29
30
30
30
:32
-.20
:37
:44
:S6
:02
:17
:37
RO
RO
RO
RO
RO
RO
11 Peaks
DC NL 0
31
31
31
31
:00
:05
:14
:23
:32
1
RO
31:41
31:52
32:02
32:09
32:16
32:26
32:39
AN
M
374-376
13C12- HxCDF
384-386
384-386
HxCDD
390-392
D
33:23
33:
28
13 Peaks
DC NL 0:
31:
31:
31:
31:
31:
32:
32:
32:
32:
32:
33:
00
05
13
30
33
50
03
09
24
38
55
23
0.
RO
RO
RO
RO
RO
RO
RO
11 Peaks
DC NL 0:
D SN 31:
31:
32:
32:
00
26
35
01
14
1.
RO
RO
1.24
0.62
1.49
...1.41 .
2.37
0.33
6.82
0.34
60.20
19.59
10,959.04
1,571.16
45.01
28.92
43.63
78.80
13,001.33
.05-1.43
0.92
1.26
1.26
1.20 '
1.26
1.26
1.34
1.27
1.20
1.26
1.26
1.25
1.26
1.25
1
43-0.59
1.32
1.81
0.80
1.13
1.60
1.82
0.52
0.52
0.51
0.55
1.76
0.51
4,978.94
194,950.10
417,152.00
36,091.60
53,322.20
29,294.80
5,044.60
391,030.00
162,153.10
48,434.80
75,865.00
185,974.20
9,560.00
50,900.00
,659,772.40
36.59
11.91
6,565.88
918.59..
41.90
17.58
116.63
47.90
HxCDF Follows -
108,558.00
232,369.00
19,695.90
29,695.60
16,336.60
2,892.35
218,602.00
88,312.10
27,010.50
42,277.40
103,229.00
5,330.00
28,300.00
29
19
4,393
. 652
17
52
17
142
.42
.36
.16
.^7
.65
.80
.11
.27
0
0
1
1
1
1
1
1
.963
.990
.000 13C12-PeCDD 123 IS3
.004
.011
.014
.023
.034
0.962-1.047
86,392
184,783
16,395
23,626
12,958
2,152
172,428
73,841
21,424
33,587
.10
.00
.70
.60
.20
.25
.00
.00
.30
.60
82,745.20
4,230.00
22,600
.00
0
0
0
0
0
0.
.000
.967
.971
.976
.981
.985
E
E
0.991
0.996 123478-HxCDF AN
E
1.000 123678-HxCDF AN
1,
,004
1.009
1.016 234678-HxCDF AN
1.038 123789-HxCDF AN
E
PR
1.041
0.876-1.124
65.79
46.27
595.03
127.07
26.67
120.20
13,621.10
15,925.09
663.29
14,896.82
217.11
11,596.17
57,834.82
05-1.43
0.42
0.45
1.25
1.22
1.22
417.85
539.64
27,935.00
147,092.10
67,560.90
55.52
315.47
95.44
28.19
144.53
4,653.76
5,440.09
223 . 94
5,295.11
253.48
3 , 917 . 11
HxCDD Follows - -
15,540.20
80,941.80
37,122.10
30.64
394.
84.
,06
.15
17.66
79.60
8,967.
10,485.
439.
9,601.
143.
7,679.
34
00
35
71
78
06
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
0.958-
12,394.
66,150.
30,438.
80
30
80
0.
0.
0.
0.
0.
000
967
971
980
981
990
997 13C12-HXCDF 478 SOT2
000 13C12-HXCDF 678 IS4
008
015 13C12- HxCDF 234 ALT2
024
038 13C12-HXCDF 789 ALII
1.014
000
958
963
976
983
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01710/98
< n *"•
ib'o
-------
Page No.
01/10/98
Listing of (J980031B.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total. Area. .. Ar ea. PeaJc. 1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
D
D
408-410
13C12- HpCDF
418-420
418-420
HpCDD
424-426
D
32:24
32:44
-. • • - - 33. 49
33:07
7 Peaks
DC NL 0:00
32:03
32:44
32:48
33:07
4 Peaks
1.18
1.23
~: 1 . 26
1.28
1.05-1.43
RO 2 . 18
RO 0.88
1.23
1.24
1.24
10,722.53
11,056.60
~" 227430/44
30,024.80
316,822.37
41.46
54.21
8,772.48
12,341.48
15,357.72
36,525.89
0.88-1.20
DC NL 0:00
35:02
35:17
35:27
DC NH 35:55
DC NH 36:01
36:33
4 Peaks
DC NL 0:00
35:01
36:32
2 Peaks
RO 0.77
1.07
1.04
1.06
RO 1.73
RO 3.39
1.06
0.37-0.51
RO 2.66
0.44
0.44
111.02
585,811.00
118,835.20
154,379.50
1,117.51
716.92
75,223.70
934,249.40
71.22
10,726.26
8,063.95
18,790.21
0.88-1.20
DC NL 0:00
DC WL 35:10
35:18
36:03
0.91
RO 0.43
1.00
1.01
90.06
1,890.28
98,857.60
98,139.60
5,810.30
6,101.00
~ ' ~~12", 517 :'00
16,831.50
30.01
4,841.31
6,842.51
8,497.16
302,399.00
60,588.10
79,478.80
38,661.30
3,255.06
2,444.77
49,385.70
49,229.30
4,912.23 0.988
4,955.60 0.998 123478-HxCDD AN
9,913.'44 '1T001 123678-HxCDD AN -••
13,193.30 1.010 123789-HxCDD AN
0.970-1.030
0.000
34.06 0.977
3,931.17 0.998 13C12-HXCDD 478 SUR3
5,498.97 1.000 13012-HxCDD 678 IS5
6,860.56 1.010 13C12-HXCDD 789 RS2
0.996-1.049
0.000
283,412.00 1.000 1234678-HpCDF AN E
58,247.10 1.008
74,900.70 1.012 E
1.026
1.029
36,562.40 1.044 1234789-HpCDF AN
0.943-1.114
0.000
7,471.20 1.000 13C12-HpCDF 678 IS6
5,619.18 1.043 13C12-HpCDF 789 SUR4
0.975-1.005
0.000
0.975
49,471.90 0.979 E
48,910.30 1.000 1234678-HpCDD AN E
424-426
2 Peaks
196,997.20
13C12-HpCDD 0.88-1.20
436-438 DC NL 0:00 1.03 44.07
36:03 1.03 9,863.19
436-438 1 Peak 9,863.19
5,003.93
0.972-1.028
0.000
4,859.26 1.000 13C12-HpCDD 678 IS7
Octa-CDD and CDF Follows
OCDF
442-444
442-444
0.76-1.02
DC NL 0:00 RO 4.74 53.73
39:50 0.89 368,276.00
1 Peak 368,276.00
173,289.00
0.899-1.101
0.000
194,987.00 1.006 OCDF
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
. 1 Q 7
JL w I
-------
Page No.
01/10/98
Listing of 0980031B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2. . Rel.RT Compound.Name.. 10.. Flags.
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC ML 0:00
39:37
1 Peak
DC NL 0:00
39:36
1 Peak
0.
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0.
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0
0
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1.004
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AN
IS8
Column Description 'Why' Code Description QC Log Desc.
M_Z -Nominal Ion Masa(es)
..RT. -Retention Time (mm:38)
Rnt.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
*•• End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
rila:U980031 tl-724 Acq: 6-JZS-1998 21:15:02 SC EI+ Voltaga SIX 70S Noiae: 1397054
303.9016 F:2 BSUB(256, 30, -3. 0) PXD(9, 5, 3,0 .101,5588216. 0,1. 00\,r,T) Ezp:NDB5OS
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317.9389 r:2 BSUS(256, 30, -3.0) PXD(9, 5, 3,0. 101,90236. 0,1.00\,r,T) Xxp:SDS5US
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330.9792 T>2 XxpiNDBSUS
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331.8936 Tt2 BSO3(256,30,-3.0) PKD(7,5r3,0.10\,317632.0,1.00\,r,T) Eip:mB5O3
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327.8847 T:2 BSUS(256,30,-3.0) PKD(7,5,3,0.10\,144012.0,1
TRIANGLE LABS Teit:165, 167, 168/225 TLH44376A
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330.9792 T:2 ExptWDBSUS
TRIANGLE LABS Tarti 165, 167, 168/335 TLIt44376A
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FileiU3B0031 tl-724 Acq: 6-J3OT-1998 21:15:02 SC EI+ Voltage 5X2 705 Noiaai3006
339.8597 Ts2 BSUB(256, 30, -3.0) PXD( 7,5, 3, 0.10%, J7074. 0,1. 00\,r,T) ZrpiKDBSUS
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rHa:O980031 H-384 Acqt 6-JAN-1998 21:15:02 SC EI+ Voltage SIS 70S Noiae,1378101
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TSIASSLX LABS Textt!65,167,168/235 SLIt44376A
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TSIANGZE LABS Text.-165,167,168/225 XLIt44376A
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392.9760 F,3 XiptNDBSVS
TSIAHGLX LABS Text:165,167,168/225 TLIt44376A
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XSIASSLX LABS Tert: 165,167,168/225 TLH44376A
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401.8558 T:3 BSUB(256,30, -3.0) tXD(7,5,3,0.10\,80860.0,1.00\,T,T) Xxp:SDBSUS
TSIANSLE IA3S Text: 165,167,168/335 TLIt44376A
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-------
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-------
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100\ A6.J2E7
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-------
en
o
Peak Locate Examination: 6-JAN-1998:21:14 File:U980031
Experiment:NDB5US Function:2 Reference:PFK
-------
CD
File:U980031 #lj724 Acq: 6-JAN-1998 21:15:02 GC EI+ Voltage SIR 70S
119.8965 F:2 ExprNDBSUS
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100%, ! A2.Q4E8
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-------
TLI Project 44376A
Client Sample: 165,167,168/225
Method 23 TCDD/TCDF Analysis (DB-225)
- : - Analysis File: P980099
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-14ACD Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: P980094
DB-225 Analyst: JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
Bt
EMPC-
Ratfo
RT
Flags
2,3,7,8-TCDF
13.4
0.75
23:06
RT Ftegsr
"C12-2^,7,8-TCDF
3.2
79.8
40%-130%
0.78
23:06
Recovery Standard
ftetto
RT
Flags
0.82
21:55
Data Reviewer
01/09/98
Page 1 of 1
CNF.PSR .2.01. LARS 6. lOOtl
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1601/09/98
<-. : o
t, j. u
-------
Initial
. .Date.
Data Review By:
-111'
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
1.00
Page No.
01/07/98
Compound/
TCDP
304-306
Listing of P980099B.dbf
304-306
13C12-TCDP
316-318
Matched GC Peaks '/Ratio
Omit Why . .RT. OK Ratio Total. Area
0.65-0.89
DC ML 0:00 0.67 8
DC WL 18
18
18:
:14
:28
:45
18:55
19:00
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
20:
21:
21:
21:
21:
21:
21:
22:
22:
22:
22:
22:
23:
23:
23:
23:
23:
24:
24:
25:
DC WH 25:
:07
28
36
44
54
01
10
20
28
38
47
10
23
28
37
43
52
06
21
31
40
59
06
19
36
44
56
15
31
16
43
0.77
0.80
RO 1.31
0.71
RO 1.07
0.83
0.75
0.76
0.76
0.77
0.77
0.75
0.79
0.78
0.76
0.75
0.76
0.68
0.74
0.75
0.74
0.75
0.77
0.74
0.75
RO 0.59
0.75
0.75
0.76
0.75
0.76
0.65
0.80
0.75
0.78
0.86
34 Peaks
DC NL 0:
DC WL 20:
DC WL 20:
00
08.
33
0.65-0.89
RO 1.21
0.74
0.66
29
3,686
/Ret; Tine " " " •" " ~ "" ~
. .. Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound.
0.792-1.101
.81 0.000
.25
.03
91.24
60.27
76.38
222.15
4,
4,
7,
3,
3,
8,
4,
13,
4,
26,
6,
1,
5,
5,
1,
7,
5,
3,
6,
7,
6,
4,
148,
594.42
539.08
964.10
642.65
359.
809.
034.
316.
396.
468.
200.
39.
34.
116.
098.
972.
963.
300.
070.
41.
755.
940.
400.
404.
682.
32.
15.
166.
789.
42.
287.
,52
43
,10
42
14
25
80
69
97
07
71
88
45
70
54
95
54
87
09
69
69
54
90
02
63
39
91
1,638.93
2,
67.48
25.
46.
101.
1,975.
1,959.
3,445.
1,583.
156.
1,636.
3,547.
1,891.
5,763.
1,910.
11,316.
16.
14.
2,623.
467.
2,558.
2,594.
554.
3,034.
18.
2,463.
1,689.
2,762.
3,163.
2,875.
12.
7.
1,782.
345.
,09
,37
,01
87
16
30
78
55
29
26
99
78
85
00
04
86
33
19
71
36
23
65
25
23
95
06
73
23
85
07
76
48
047.10
51.55
35.18
2,
2,
4,
2,
2,
4,
2,
7,
2,
14,
3,
3,
3,
4,
3,
2,
3,
4,
3,
2,
43:
121.
618.
579.
518.
058.
202.
173.
486.
424.
632.
557.
884.
23.
20.
492.
631.
414.
369.
746.
035.
30.
292.
250.
638.
240.
807.
19.
8.
383.
444.
15
14
55
92
80
87
87
14
84
43
36
40
80
65
11
74
52
17
09
47
89
79
31
92
03
96
46
69
83
26
15
0.789
0.799
0 . 812
0.819
0.823
0.828
0.843
0.848
0.854
0.861
0.867
0.873
0.880
0.886
0.893
0.900
0.916
0.926
0.929
0.936
0.940
0.947
0.957
0.968
0.975
0.981
0.995
1.000 2378-TCDF
1.009
1.022
1.027
1.036
1.050
1.061
1.094
1.113
0.957-1.043
3.
34.
48.
84
12
54
0.000
0.872
0.890
E
E
E
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 04:57 01707/98
214
-------
Page No.
01/07/98
Listing of P980099B.dbf
Hatched GC Peaks / Hatio / Ret. Tiae
Compound/
M_Z QC.Log Omit why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID..
Flags.
316-318
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL"
WL
WL
WL
WH
WH
WH
WH
WH
WH
4
20
21
21
21
21
22
22
22
23
24
24:
24:
24:
25:
25:
25:
:43
:33
:43
:48
:02
:24
:06
:02
:18
:28
:50
:10
:34
45
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.98
0.77
0.65
1.07
0.86
0.90
0.29
0.75
0
0
3
2
0
0
0
0
.78
-94
.20
.21
.99
.33
.51
.72
Peaks
9.
31.
17.
2.
36.
2.
5.
9.
1,134.
25.
20
58
56
00
41
21
01 2.18
81 4.19
89 495.74
45 13.45
1.93
1.
12.
8.
21.
8.
1.175.
96
81
48
63
09
16
0.897
0.923
0
0
0
0
7.52 0
5.62 0
639.15 1
14 . 38 1
1
1
. 1
1
1
1
.933
.940
.944
.954
.964
.970
.000 13C12-2378-TCDF ISO
.040
.052
.059
.075
.089
.107
.115
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
WH
WH
WH
WH
6
0:
20:
20:
20:
20:
21:
21:
21:
21:
22:
22:
22:
23:
24:
24:
24:
00
18
24
30
55
16
37
46
55
24
41
59
44
14
28
38
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
..... K
65-0.89
1.
0.
1.
1.
0.
0.
0.
0.
0.
5.
0.
1.
0.
0.
0.
0.
14
72
00
51
34
75
79
58
82
00
71
31
43
58
38
74
Peaks
Above: TCDF / TCDD Follows
2.23
3.26
0.90
2.78
0.55
2.83
745.90
5.20
1, 024.97
0.32
10.22
0.62
7.70
3.86
4.21
2.72
1,792.33
1.36
2.37
329.78
2.26
462.03
4.24
1.
1.
416.
3.
562.
5.
0.908-1.092
0.000
.90 0.939
0.944
.57 0.948
0.968
0.984
12 1.000 13C12-2378-TCDD IS1
91 1.007
94 1.014 13C12-1234-TCDD RSI
1.036
98 1.049
1.063
1.098
1.121
1.132
1.140
Column Description. . . 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -R0-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report *••
WL-Below Retention Time Window
WH-Above Retention Time Window
SM-Below Signal to Noise Level
-------
fl±a:P980099 ii-323 Acq:7-JAH
303.9016 SzpiDB225
XBIABCLX LASS Text: 165,167,168/225 TLII44376A
100*
23,36
J sn- voltage SIS /of
22:36 22:49 23:00 23s12 23:24 23:36 23:48 24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24
T±la:P980099 tl-923 Acq:7-J3Ot-98 04:09:43 XH- Voltage SIS 70P
315.9419 Xxp:DB225
IRIAWSLX LABS Text: 16'5,167,168/225 TLH44376A
1001
95.
90.
as.
80.
7S.
70.
65.
60.
55:
50^
45:
40:
35.
30.
25.
20.
i5:
101
23:06
_I.4E6
'•.1.3X6
'-.1.2E6
'•.1.216
'.1.1E6
':!. OE6
.9. 6E5
.8.9X5
'-.8.2X5
.7.5X5
.6.9X5
.6.2X5
.5.5X5
.4.8X5
.4.1X5
.3.4X5
.2. 7X5
.2.1X5
'.1. 4X5
'.6.9X4
22:36 22:48 23:00 23:12 23:24 23,36 23:48 24:00 24:12 24:24 24:36
.0.0X0
24:48 25:00 25': 12 25:24 Tine
-------
rid.esf 980099 tl-323 Acqt 7-JMI-ya vnuynj JSfr vo±taye SIS 70P aoiae:1772
303.3016 BSUB(256,30,-3.0) PXO(5,3,l,0.10\,7088.0,0.00\,r,e) Szp:DB225
TSIAHSLS LASS Texts 165,167,168/325 TLIt44376A
lOOi
80.
SO.
40.
SOI
o:
Jl
A3.45X7
A2.62X7 *3-03X7 A3.16X7
Al. 78X7
A
19:00 20iOO 21:00 23tOO 23iOO 24iOO
riIe:P980099 tl-923 Acq:7-J3UT-98 04>09t43 SX+ Voltage SIS 70P So±me:2637
305.8987 3303(256,30r-3.0) PXD(5,3,l,0.10\,10S4a.O,0.00\,T,T) XxpiDB225
TSIAWSLX LA33 Text: 165,167,168/225 XLII44376A
100« AJ..49X8
ao:
60.
40.
20.
0.
25100
A4.52E7
A3.49K7 A4.04S7
.37f!
A4.24E7
A2.38E7
A
19:00 20:00 21:00 22:00 23:00 24:00
rilaiP980099 tl-923 Acqs7-JJOr-98 04:09:43 fH- Voltage SIS 70P lfo±Ba:1316
315.9419 BSOB(256,30,-3.0) PXD(5,3,1,0.10\,5264.0,0.00\,T,T) Zxp:DB225
TSIAHSZX LABS Text:165,167,168/225 TLH44376A
IOCS A4.96E6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23:00 24:00
r±laiP980099 tl-923 Acq:7-JXa-98 04:09:43 XH- Voltage SIS 70P Ooiae:1087
317.9389 BSUB(256,30,-3.0) PKD(S,3,1,0.10\,434B.0,0.00\,T,F) Xxp:DB225
IASGLX LABS Text: 165,167,168/225 XLIt44376A
1001 A6.39E6
80.
60.
40.
20.
25:00
A2.92E5
A
19:00 20:00 21:00 22:00 23:00
rile:P980099 tl-923 Actj: 7-JKK-98 04:09:43 XH- Voltage SIS 70P
375.8364 Xxp:DB225
XXXAXGLZ LABS Text: 165,167,168/225 XLIt44376A
1001 23,03
24:00
25:00
_1. 8X7
.1.4X7
.1.1X7
,7.0X6
.3.5X6
0.0X0
.3X7
.9X7
.4X7
.3X6
.6X6
.0X0
Time
,4X6
.1X6
2X5
5£5
7X5
0X0
Tine
7X6
4X6
0X6
9X5
.4X5
.0X0
Time
19:00
20:00
21:00
22100
23:00
24:00
25:00
r. 1 n
(- JL t
-------
fllesP9B0099 #1-923 Acqs 7-JXN-9B 04:09:4J EX+ Voltage SIS 7OP Noiae:69J
319.8965 BSOB(356,30,-3.0) PXS(5,3,l,0.10\,3773.0,0.00\rr,T) S*p:BB335
TSIAHSLX LABS Text: 165, 167 ,168/335 TLI944376A
1001
80.
60.
40.
20.
0.
|
A2.27X7
1 1 A4.43X6 A7.84X6
11 11 A1-1-**^ A »/\
/ V / V l\ A 7\ A _ ^VV V~ ^ ^^_
20»00' 2lioO '33:00 33:00 24.-00 35
-1.0X7
.8.3X6
.6.3X6
.4.1X6
^.1X6
0.0X0
00 T±ae
TUe:P980099 91-933 Acq:7-JAS-98 04,09:43 H+ Voltage SIS 70P So±aetl742
321.8936 BSUS(356,30,-3.0) PKD(5r 3,1,0. 10\,696e. 0,0. 00\,f,f) Xxp:DB335
TSIASSLX LABS Text: 165, 167, 168/335 XLH44376A
100J
80.
60.
401
301
0'
1
1
A3. 93X7
A
1 1 AS. 59X6 A9.8BX6
\\ \\ l^'f31^ A *_ ^-WV ^ __
30':00 .21:00 22:00 ' 23:00 24:00 25
-1.3X7
.1.1X7
.7.9X6
.5.3X6
.3.6X6
0.0X0
00 Time
Tile:P980099 tl-933 Acq:7-JAS-98 04:09:43 XH- Voltage SIS 70P Soiae:154S
337.8847 BSUB(256,30,-3.0) PXD(5,3,lr0.10\,6180 .0,0.00\,r,T) Xxp:DB225
TSIASSLX LABS Text: 165 ,167,168/335 XLIf44376A
100J
80.
60.
40.
201
0.
AS. 70X7
A3. 61X7
A1.46X7
(\
l\
20\00 ' ' ' 21:00 ' ' ' '22:00 ' ' ' ' 23\00 24:00 25
-1.6X7
'.1.3X7
.9.6X6
.6.4X6
.3.3X6
0.0X0
00 Tiae
r±letP980099 91-923 Acqt 7-JAB-9S 04:09:43 KH- Voltage SIS 70P Koine i 7 IS
331.9368 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,2873.0,0.00\,r,r) Xxp>DB335
TSIAlfSLX LABS Text: 165, 167, 168/225 TLX944376A
1001
80.
60.
40.
20.
0.
A4.63X6
A
A3. 30X6 [I
/I /I
20 1 00 21:00 22:00 23tOO 34:00 25
_1 . 3X6
_1 . 0X6
.7.6X5
.5.1X5
.3.5X5
0.0X0
00 Time
HJ.e:P980099 91-923 Aoji7-JJOT-9B 04 1 09:43 EH- Voltage SIS 70P Soiaet633
333.9338 BSUB(356f30r-3.0) PXD(S, 3,l,0.10\,2528.0rO.OO\rrrT) XxpiDBSSS
TSIASSLX LABS Textt 165, 167, 168/335 XLI944376A
1001
80.
60.
40.
30.
01
AS. 63X6
I
A
A4.16K6\\
I
l\ l\
30:00 21:00 22:00 3JiOO 24\00 25
.1.5X6
J..3X6
.9.1X5
.6.1X5
.3.0X5
0.0X0
00 Tiae
213
-------
r±le:P980099 tl-923 Acq: 7-JAK-98 04:09:43 XI+ Voltage SIS 70P
303.9016 Xxp>DB225
TSIASSLX LASS Tuxt-,165, 167 , 168/225 TLIt44376A
100.
80.
60.
40.
20.
0.
21: 0
20:38
1
19( 44 11
19,2s! aoj\ao\\ ^TV2'0*"^1
A . ... . -.jJAi-l-A- -1\ A/1/ 1 A --li--H-A---ll A'A-f
j\_ j \j \j \j \^j\] v/* \j\ I \ /W/\/VA/I /vw
19:00 20(00 21(00 22(00 23(00
Fila,P980099 tl-923 Acqt7-J3UT-98 04(09:43 XH- Voltage SIS 70t
315.9419 Sxp:DB225
TSIASSLX LASS Texts 165, 167, 168/225 XLH44376A
ion
80.
60.
40.
20.
23 (Off
1
^ a°J.33 ^ 1 [
15)00 ' ' 20:00 21:00 22:00 ' 23:00
rile:P980099 tl-923 Acq:7-J3UT-98 04:09:43 XI+ Voltage SIS 70P
319.8965 Exp:DB225
TSIASSLX LABS Text:165, 167 , 168/225 TLH44376A
1001
80.
60:
40:
20:
o:
19; 17
19(51
1
20:30 21.-5S
It ft A n 21:16 A,
/I 1 \ A /vA A ^WV^ ^
15:00 20:00 21:00 ' ' 22:00 ' 23:00
f±lesP9 80099 tl-923 Acq:7-JJOT-98 04:09:43 XI+ Voltage SIS 70P
331.9368 Xxp:DB225
TSIASSLX LABS Text: 165 , 167, 168/225 TLIt44376A
1001
80:
60:
40:
20:
o:
21:55
1
1
n M
19:00 ' '.' 20:00 ' ' ' 21:00 ' ' ' 22(00 ' ' ' 23(00
TiletP980099 tl-923 Acq:7-JXH-98 04:09:43 XI* Voltage SIX 70P
292.9825 Xfp:DB225
TSIASSLX LABS Text: 165 , 167, 168/225 TLIt44376A
ion
80:
60:
40:
20:
o:
^1^57 19133 SOilO 30i5a^ 23il« 2J(00
^/^~~1-** | V**VJ1"^^^^V^* "'w" •^/O*/*^V' tJ^~~^**V*++1'** u *^^** ~^ ffv^J^tr^fV~^m
14:00 20:00 21:00 22(00 23(00
Tile i P9 80099 tl-923 Acqt7-JJOr-98 04:09:43 EH- Voltage SIS 70P
330.9792 XxpiDB225
TSIASSLX LABS Textt 165, 167, 168/225 TLH44376A
100]
80:
60:
40:
20:
o:
23,36
^A''1 _.
/v
1 . 8X7
.1.4X7
'•.1.1X7
.7.0X6
.3.5X6 _
0.0X0
24:00 ' ' ' 25(00 ' ' Time
-.1.4X6
.1.1X6
.8.2X5
.5.5X5
.2.7X5
24\00 35\00 T±ae
_1 . Or7
'-.8.2X6
'-.6.2X6
'.4.1X6
.2.1X6
0.0X0
24(00 25:00 ' ' T±ae
_1 .'3JT5
':! . 0X6
'.7.7X5
.5.1X5
.2.6X5
0.0X0
'24:00 25:00 Tlao
23:35 24 {31 25:13
*rV*v~V1^^"^^'^1^ *fYV^*'^JY w^l**'*^1^^*
.7.8X6
.6.3X6
.4.7X6
.3.1X6
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0.0X0
24:00 25:00 Time
18(53 19:53 21(13 21:51 22:2722:54 23:32 24(0724(35 25:15 -6.6X6
19(00 20(00 21(00 22(00 23(00
* - y- -y v- -y v • T » » »•
.5.3X6
.4.0X6
.2.6X6
.1.3X6
0.0X0
24:00 25:00 Time
219
-------
tef, tass 232,3825 Peak top
Height 1,39 volts Span 296 ppi
Systa file naie
Oka fllenaie
Resolution
Group nuiber
Ionlatlon lode
Switching
Ref. lasses 292.9825,
A 292.9825
8 383.9816
C 385.8987
D 315.9419
E 317.9389
F 319.8965
6 321.8936
H 327.8847
I 338.9792
J
K
L
I
1
El*
VOLTAGE
388.9781
338.9792
331.9368
333.9338
375.8364
Channel I 338.9792 Peak top
Helcjit 1.84 volts Spai 288 ppi
220
-------
TLI Project: 44376A
Client Sample: 177/182-184/209
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980032
Client rroject
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
i_uip AiuHLLnun
M23TRAIN
194-59-15A
1.000
n/a
DB-5
i AWjyo
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
B8
Spike File:
ICal:
ConCal:
% Moisture:
% Lipi±
% Solids:
SPMIT204
UF51058
U98002S
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1,2.3,7,8-PeCDD
l,Z3,4,7,8-HxCDD
1.23,6,7,8-HxCDD
1,23,7,8.9-HxCDD
1,2.3.4.6,7,8-HpCDD
1.2J,4.6,7.8.9-OCDD
Arctsigf
ND
ND
ND
ND
ND
0.02
0.06
PL"' - -< EMPC
0.004
0.006
0.007
0.006
0.006
« Ratio RT Flags
(
0.96 36:02 J
0.92 39:37 IB
2.3,7,8-TCDF
!A3,7,8-PeCDF
2,3,4,7,8-PeCDF
12,3,4,7,8-HxCDF
T.2J,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2^,7,8,9-HxCDF
l,2J,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2J,4,6,7,8.9-OCDF
EMPC
0.01
0.01
0.03
0.01
0.02
ND
0.13
ND
0.11
0.03
0.006
0.01
1.43
1.36
1.37
1.11
1.11
1.04
0.87
28:34
29:16
32:01
32:08
32:37
35:00
39:49
B_
J_
J_
J_
J_
J_
rotate
Amt
^«
fftiraber?
DL
EMPC
F&3S
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
0.01
0.01
0.02
0.02
0.05
0.07
0.11
0.13
1
1
1
1
3
5
5
1
0.02
0.02
0.04
0.13
0.13
0.15
Page 1 of2
MTT2.PSR»I.01. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:2001/10/98
*") 1 1
CC J.
-------
TLI Project: 44376A
Client Sample: 177/182-184/209
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980032
: internal SCmdards
13C,rZ3.7.8-TCDF
13C12-2J,7.8-TCDD
13C,rlA3.7,8-PeCDF
1JC,rl.2,3.7.8-PeCDD
13C,2-lA3.6,7,8-HxCDF
13C,2-lZ3,6,7,8-HxCDD
I3CirlZ3,4,6,7,8-HpCDF
13C,2-U.3.4,6,7,8-HpCDD
13Ca-U,3,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
i3C12-2,3.4.7,8-PeCDF
13Cirl,2,3,4,7,8-HxCDF
l3C,2-UJ,4,7,8-HxCDD
13C12-U,3.4.7,8,9-HpCDF
Surrogate Standards {Type A>
37CL,-2,3,7,8-TCDD
Alternate Standards {Type A>
I3C,2-li3.7.8,9-HxCDF
"C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
"C,rlA3,4-TCDD
13C,2-lA3,7,8,9-HxCDD
Amt. $0} -,
2.5
2.7
2.9
3.2
3.0
3.7
1.6
3.5
7.0
Ami. $tg)
3.8
3.7
3.6
3.8
Amt #Ȥ}
3.3
1 Amt. $19}
3.1
3.1
^fffAr4vf ^%J JUJH
f\ : \.->\ v.
62
68
72
79
73
92
39
87
86
' ^/n ftttt
93
92
90
95
' , fatffH
82
%Rec
77
78
-
EG vfify A /•"¥ * ^ * *
,2 40%-130%
.1 40%-130%
.1 40%-130%
.7 40%-130%
.9 40%-130%
,1 40%-130%
.7 25%-130%
.4 25%-130%
.9 25%-130%
iovery
.9 40%- 130%
.5 40%-130%
.3 40%-130%
.1 40%-130%
.4
«very
7 40%-130%
0 40%-130%
,^^HD, :
0.76
0.81
1.49
1.50
0.50
1.21
0.35
1.05
0.86
Ratio
1.46
0.50
1.20
0.35
;
Ra«k>
0.51
0.48
Ratio
0.81
1.21
•••• •: KT •• FEaos
24:36
25:18
28:33
29:35
32:08 ;
32:48
35:00 RO
36:02
39:36
FIT Flags
29:14
32:01
32:43
36:32 RO
ITT Flags {
25:20
RT Flags
33:22
32:36
RT Flags
25:08
33:07
Dara Reviewer.
01/10/98
Page 2 of 2
Mm.PSRvl.OI. LARS 6.10.08
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01710/98
222
-------
Initial
Data Review By:
. .Date.
Calculated Noise Area:
7.03
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page' No. ~ ."1 ' • •-•• 'Listing"
01/10/98 Matched
Compound/
M_Z .... QC . Log Omit Why . . RT . OK
TCDF
304-306
K
D
K
K
A
D
M
304-306
13C12-TCDF
316-318
DC NL 0
22
D SN 22
23
23
23
24
24
D SN 24
24
25
:00
:36
:54
:18
:35
:53
:00
:13
:26
:38
:03
0
RO
RO
RO
RO
RO
RO
RO
"of" 098003237 dbf
GC Peaks / Ratio
Ratio Total. Area
.65
0
0
0
1
0
0
0
0
1
0
0
-0.89
.89
.30
.40
.04
.75
.64
.75
.89
.13
.63
.52
8 Peaks
DC NL 0
DC WL 23
24
24
:00
:34
:11
:36
25:02
25
:33
DC WH 25:39
316-318
TCDD
320-322
KN
KN
D
320-322
37C1-TCDD
328
0.
RO
RO
RO
RO
/ Ret. Time
. . . Area . Peak . 1 . . Area . Peak . 2 . .
Rel.RT Compound. Name. . ID.
. Flags.
0.867-1.079
29
50
50
74
62
81
103
.101
32
193
38
705
.06
.23 21.85
.96
.27 43.82
.85 26.96
.65 35.52
.40 44.40
.59 47.84
.66
.32 84.10
.20 16.62
.51
65-0.89
1
0
0
0
.70
.76
.50
.76 17
0.62
0
.85
5.93
4 Peaks
DC NL 0:
22:
23:
D SN 23 :
DC SN 24 :
DC SN 24 :
DC SN 24 :
DC SN 24 :
DC SN 25:
DC SN 25:
DC SN 26 :
DC SN 26 :
00
46
10
47
25
35
47
55
13
18
30
44
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
18
65-0.89
0.
0.
0.
0.
0.
4.
0.
3.
0.
0.
0.
0.
89
59
89
36
93
18
20
90
47
45
72
40
2 Peaks
16
413
85
,972
.80
.05
.95 37.39
.16 7,785.96
340.69 148.21
52.88 24.27
8.
.76
73.91
41.96
35.89
55.59
59.00
53.75
133.00
31.77
0
0
0
0
0
0
0
0
0
1
1
.000
.919
.931
.947
.959
.971
.976
.984
.993
.001 2378-TCDF AN
.018
J
J
J
J
J
J
J
0.959-1.041
75.43
10,186.20
238.69
28.61
0
0
0
1
1
1
1
.000
.958
.983
.000 13C12-2378-TCDF ISO
.018
.039
.043
,451.68
8.
58.
43.
3.
10.
7.
2.
1.
15.
15.
7.
6.
101.
13
94 25.64
05 20.22
08
12
98
39
75
63
91
78
97
99
0.895-1.047
0.000
43.35
22.83
0.900
0.916
J
J
0.940
0.
0.
0.
0.
0.
1.
1.
1.
965
972
980
985
997
000 2378 -TCDD AN
047
057
0.921-1.079
DC NL 0:
23:
00
57
5.
95.
73
45 95.45
0.
0.
000
947
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
223
-------
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of O980032B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
M
D
D
H
D
340-342
13C12- PeCDF
352-354
25
25
25
:20
:50
:58
26:01
26:03
26:09
26:09
26:21
26:38
26:46
DC SN 26:51
11 Peaks
0
DC NL 0
24
25
25
25
25
:00 RO
:08
:08
12,297.60
52.49
35.38
12
.65-0.89
1
.86
0.34
0.81 19
:18 0.81 14
:38
:50 RO
0.
.76
4.90
5 Peaks
DC NL 0
26
27
27
D SN 27
28:
28:
28:
D SN 28:
D SN 28:
29:
29:
DC SN 29:
D SN 30:
DC SN 30 :
1
:00 RO
:34
:34 RO
142 RO
:52 RO
:10
;17
:34
42 RO
:51
:16
24 RO
43 RO
14 RO
34 RO
35
.32-1.78
0.
1.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
2.
0.
0.
90
73
45
88
54
33
66
43
28
65
36
17
88
72
35
8 Peaks
DC NL 0:
27:
27:
27:
DC SN 28 :
28:
28:
28:
29:
1.
00 RO
15 RO
29 RO
42
01 RO
10
33
50 RO
14
32-
0.
0.
0.
1.
0.
1.
1.
1.
1.
1.78
88
61
23
55
38
56
49 16,
27
46 14,
12.38
31.01
56.59
23.43
48.49
27.17
8.90
6.28
,688.89
16.55
85.01
,596.91
,912.62
680.28
48.82
,323.64
11.80
59.20
24.97
133.39
32.33
55.91
83.18
49. 90
37.89
47.95
59.70
68.62
11.04
16.01
3.09
534.87
12,297
52
35
12
31
56
23
48
27
8
38
8,779
6,690
294
135
.60
.49
.38
.38
.01
.59
.43
.49
.17
.90
.69
.31
.82
.57
.18
46
10,817
8,221
385
27
0.
.32
.60
.80
.71
.58
1.001 37C1-TCDD CLS
1.021
1.026
1.028
1.030
1.034
1.034
1.042
1.053
1.058
1.061
921-1.079
0.000
0.954
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.021
37,
15,
81.
31.
51.
29.
34.
41.
.55
.18
.08
,91
91
40
40
71
21.
33.
92.
24.
31.
20.
25.
35.
0.
.65
.93
,01
,00
27
50
30
56
925-1.065
0.000
0.931
0.966
0.970
0.976
0.987
0.991
1.001 12378-PeCDF AN
1.005
1.011
1.025 23478-PeCDF AN
1.030
1.041
1.059
1.071
J
J
J
J
J
J
J
J
0.860-1.140
18.05
18.48
18 . 85
585.52
10.66
41.54
135.84
603.20
633.01
11.
11.
356.
25.
9,645.
366.
8,687.
23
46
22
32
30
65
17
18.
48.
229.
16.
6,490.
287.
5,945.
42
99
30
22
54
96
84
0.000
0.954
0.963
0.970
0.981
0.987
1.000 13C12-PeCDF 123 IS2
1.010
1.024 13C12- PeCDF 234 SOR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01710/98
224
-------
Page No.
01/10/98
Listing of 0980032B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area. .. Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
M
M
374-376
13C12-HXCDF
384-386
30:13 RO 1.02 46.56 28.30 27.85 1.058
-30:20 R0._0.38 17..87 ..__10...8.6 28..53_.1.062_
DC
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
9 Peaks
NL 0:00
27:48
SN 28 : 26
28:31
SN 28:40
SN 28:50
SN 29:07
SN 29:25
SN 29:38
SN 29:45
2 Peaks
NL 0:00
SN 27:44
SN 27 : 54
28:30
SN 28:38
29:35
29:43
30:04
30:15
SN 30:31
5 Peaks
NL 0:00
31:03
31:12
32:01
32:08
32:37
5 Peaks
NL 0:00
31:03
31:11
32:01
32:08
32:36
33:04
33:22
32,100.87
1
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
0.45
0.75
1.76
1.69
0.23
1.10
0.34
1.36
1.12
0.89
32-1.78
0.56
0.53
0.45
0.92
1.28
1.50
1.61
1.09
3.47
2.01
3
32
6
43
4
23
4
11
12
8
75
3
3
4
26
17
9,216
1,462
79
26
7.
.41
.41
.04
.44
.54
.18
.69
.87
.54
.54
.85
.27
.75
.39
.49
.90
.67
.72
.81
.75
.68
10,812.44
1.
RO
0.
RO
RO
05-1.43
0.87
1.28
1.27
1.37
1.11
1.11
43-0.59
0.72
0.59
0.47
0.50
0.50
0.48
1.91
0.51
19.
44 .
107.
114.
54.
60.
380.
73
70
10
40
io
05
35
19
27
16
5,530
902
48
36
.70
.27
.10
.36
.71
.51
.35
26
16
17
3,686
560
44
10
0.
935-1.022
0.000
.40 0.940
.17
0.
.51
.31
.01
.54
.49
0.961
0.964
0.969
0.975
0.984
0.994
1.002
1.006
865-1.135
0.000
0.937
0.943
0.963
0.968
1.000 13C12- PeCDD 123 IS3
1.005
1.016
1.023
1.032
J
J
25.
59.
66.
28.
31.
07
91
10
40
64
19.
47.
48.
25.
28.
0.962-1.047
63
19
30
70
41
0.000
0.966
0.971
0.996 123478-HxCDF AN
1.000 123678-HxCDF AN
1.015 234678-HxCDF AN
J
J
J
J
J
0.876-1.124
17.
88.
161.
10,277.
13,473.
12,827.
25.
9,854.
52
88
16
07
70
57
01
68
33.
51.
3,447.
4,493.
4,150.
31.
3,329.
04
22
68
05
67
70
97
55.
109.
6,829.
8,980.
8, 676.
16.
6,524.
84
94
39
65
90
56
71
0.000
0.966
0.970
0.996 13C12-HXCDF 478 SUR2
1.000 13C12-HXCDF 678 IS4
1.015 13C12-HXCDF 234 ALT2
1.029
1.038 13C12-HXCDF 789 ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
225
-------
Page So. 4 Listing of 09800328. dbf
01/10/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total. Area. . . Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound. Name. . ID.. Flags
33:43 0.53 56.30 19.59 36.71 1.049
384-386 8 Peaks 46,764.37
HxCDD
390-392
M
0
390-392
13C12- HxCDD
402-404
402-404
HpCDF
408-410
M
D
DC NL 0
32
D SN 32
DC SN 33
:00
:00
:12
:35
1
RO
RO
:: RxCDF / HxCDD Follows -
.05-1.43
0
1
1
0
.67
.13
.25
.30
1 Peak
DC NL 0
32
32
33
:00
:43
:48
:07
1
RO
11
67
30
4
67
.71
.30 35.70
.08
.52
.30
.05-1.43
0
1
1
1
3 Peaks
DC NL 0:
35;
D SN 35:
:00
:00
;16
35:26
D
408-410
13C12-HpCDF
418-420
M
M
418-420
HpCDD
424-426
M
424-426
13C12-HpCDD
436-438
436-438
D SN 36:34
0
RO
RO
RO
RO
.86
.20
.21
.21
42
8,203
12,414
13,554
34,172
.88-1.20
1
1,
.39
.04
0.76
0.
.55
0.75
2 Peaks
DC NL 0:00
35:00
35:
36:
28
32
0.
RO
RO
RO
RO
.42
.44 4,480.50
.95 6,796.24
.21 7,417.33
.60
3 / HpCDF Follows • •
17.97
200.
.00 102.00
36.84
32.
26.
232.
.40 16.52
.74
40
37-0.51
0.
0.
0.
0.
3 Peaks
DC NL 0:
35:
DC SN 35:
36:
DC SN 36:
00
17
44
02
32
0.
RO
RO
RO
RO
88-
1.
0.
0.
0.
1.
60
35
76
35
1.20
62
81
31
96
65
2 Peaks
DC NL 0:
36:
00
02
0.
RO
88-
0.
1.
1.20
86
05
1 Peak
26.
4,418.
39.
3,370.
87
18 1,350.00
63 20.93
91 1,030.00
0.958-1.014
0
31.60 0
0
1
.000
.976 J
.982
.024
0.970-1.030
0
3,722.94 0
5,618.71 1
6,136.88 1
.000
.997 13C12-HXCDD 478 SOK3
.000 13C12-HXCDD 678 IS5
.010 13C12- HxCDD 789 RS2
0.996-1.049
0.000
98.00 1.000 1234678-HpCDF AN
1,
30.16 1.
.008
.012 J
1.045 1234789-HpCDF AN
0.943-1.114
0.000
3,890.00 1.
27.52 1.
2,950.00 1.
000 13C12-HpCDF 678 IS6
013
044 13C12-HpCDF 789 SOR4
7,828.72
i HpCDF / HpCDD Follows • -
6.
32.
3.
43.
16.
76.
37.
8,602.
8,602.
57
95 16.80
45
12 21.09
38
07
49
80 4,401.91
80
0.975-
0.
20.70 0.
0.
22.03 1.
1.
0.972-
0.
4,200.89 1.
1.005
000
979 J
992
000 1234678-HpCDD AN J
014
1.028
000
000 13C12-HpCDD 678 IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:20 01/10/98
226
-------
Page No.
01/10/98
Compound/
M_Z.... QC.
OCDF
442-444
442-444
OCDD
458-460
458-460
Listing of O980032B.dbf
Matched GC Peaks / Ratio / Bet. Time
Log Omit Why ,.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
Above: HpCDD / Octa-CDD and CDF Follows
'" " 0.76-1". 02"
DC NL 0:00 RO 2.20
39:49 0.87
1 Peak
9.87
252.00
252.00
0.76-1.02
DC NL 0:00 RO 0.71 6.43
39:37 0.92 102.13
DC SN 39:51 RO 0.45 2.51
1 Peak 102.13
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.07 14.91
39:36 0.86 12,336.23
470-472 1 Peak 12,836.23
.— . 0789'9-r.lO'l ~
0.000
117.00 135.00 1.005 OCDF AN
0.899-1.101
0.000
48.94 53.19 1.000 OCDD AN
1.006
0.996-1.004
0.000
5,930.35 6,905.88 1.000 13C12-OCDD IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
«»• End of Report •«•
WL-Below Retention Ti»e Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
r±la:09a0032 #1-724 Acq: 6-JAH-1998 22:01*41 SC SI+ Voltaga SIS 70S JToiae:6838
303.9016 T:2 BSUB(256,30,-3.0) PXO(9,5,3,0.10\,27352.0r1.00\rT,T) ExptHDBSUS
TSIAKSZX LABS Taxt,177/182-184/209 TLH4437SA
1001 A3. 1X5 1.8X5
80.
60.
40.
20.
0
r±2e
305.
TSU
1001
80.
SO.
40.
20:
o-
File
315.
TSIA
1003
ao:
60:
40:
20:
o-
r±ie
317.
TSIA
1001
ao:
sol
40:
20:
o:
Tile
330.
TSIA
1003,
ao:
50:
40:
o-
rile
375.
TSIA
1001
ao:
50:
40:
20:
oj
A4.
A2.19X5
A A2.22X5
38X5 A4.78X5
A2.70JT5 A A J
'22iOO 23:00 24 t 00
t:O980033 tl-724 Acq: 6-JKS-1998 22:01:41 SC XI + Voltage
8987 T:2 BSU3(2S6,30,-3.0) PXD(9,5,3,0.10\,30768.0,i:00\
OGLE LABS Text: 177/182-184/209 TLIt44376A
Al.
A7.39XS A4
^^^Wwv^Av^SrVL-Jt^
•]
AS. 38X5 1
fiC*AJU
f
A1.66E5
f I ' A1.00X5
2*\jd-^\st*
,
V
22:00 23*00 24*00 25*00 ' '25*00
IU980032 tl-724 Acqs S-J3X-1998 22:01:41 SC EH- Voltage SIS 70S Soiae:4747
9389 T:2 BSUB(256,30,-3.0) PEB(9,5,3,0.10\r18988.0,1.00\,r,T) Xxp:XDB5US
KSLX LABS Text: 177/182-184/209 TLIt44376A
A1.02E8
1
i
'22»00 '2J«00 24:00 25*00 25*00
>O980032 tl-724 Acq: 6-JXH-1998 22:01:41 SC XI+ Voltage SIS 70S
9792 7*2 Sxp:HHB5nS
SSLE LABS Text: 177/182-184/209 TLIt44376A
21,38 22:27 23:35 23:58 24:46 25j37 26^03
22*00 23:00 24*00 25*00 25*00
:0980032 tl-724 Acq: S-J3OI-1998 23:01:41 SC XI+ Voltage SIS 70S
8364 T:2 KxpiNDBSUS
NGLX LABS Texts 177/182-184/209 XLX944376A
26 25
31 !34 22:58
A 1 31i" a\a'\ y
\dW\iyfV/M^AlAJ^ulJJ\AJU\l^lJ^
22:00 23:00
a3'.4f 24:12
23:27 njl j\ li 11 i 1 1
24*00
25* 30
24:49 1 25'58 , 1
•**,'** 25*10 1 j| ijj. J
m^LAmJMwm
25*00 25*00
Ll.5r5
.1.1X5
.7.4X4
.3.7X4
• o . oxo
TJLae
2.9E5
'.2.3X5
'-.1 . 7X5
'-.1.1X5
-.5.7X4
'• o.oxo
Time
1 . 8X7
.1.4X7
.1.1X7
.7.1E6
.3.6X6
•o.oxo
Time
.2.3X7
.1.9X7
.1.4X7
.9.4X6
.4.7X6
0.0X0
Tine
.6.2X7
-5.0X7
.3.7X7
.2.5X7
.1.2X7
0.0X0
Tlae
.3.1X4
.2.5X4
.1.9X4
.1.3X4
0.0X0
Tine
228
-------
rila:U980033 tl-724 Acq: 6-JAS-1998 22:01:41 SC ZI+ Voltage
SIS 70S NoiM»tl911
319.8965 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.10\r7644.0,1.00\,F,T) XxptKDBSUS
TSIANGLX LABS Text: 177/182-184/209 TLH44376A
100.
80
60.
40.
20.
0
\ J
A A3. 03X5
': | Ai.asxs
U\ ft I
: \ J 1
'• f A7.S9X4 , *6
, Jill 1 ll U I
:-J-\ 1 \ --bir7SX4 - -tfU— A W\k± V -"r/L/A,
:/ \jt^L_\^rjJK{&^r^^ vMVVjn
' 33:00 ' 24\00 25:00 '
T±la:U980032 tl-724 Acqs 6 -JAN- 19 9 8 22:01:41 SC XX+ Voltage
321.8936 r:2 BSUB(256, 30, -3.0) PXD(7,5, 3,0 .10\, 8616. 0,1. 00\,
TSIAlfSLX LABS Text: 177/182-184/209 TLXt44376A
1001
80.
60.
40.
20.
« A3. 28X5
h
1
1 \ I \ AS. 48X4 ,j 27X4s\l, ** A3. 33X4 . J«
; v>wv WvlA- .."J^%^^fSJLiMJ^
23:00 24:00 25:00
^6.4X4
.92X4
1 A2j_36X4
n ^yY^^yV^A/^A-i>^JK/y^Aj\j^^
.5.1X4
'.3 . 8X4
.2.6X4
_:TJM
26:00 ' ' ' ' ' Time
SIS 70S Noia»:21S4
r,T) Xxp:KDB5US
_1 . OJT5
.5515
Al
m A6.61E4
ll A • •*» • •' **™ i
.a. iz4
.6.1X4
.4.1X4
.2. 0X4
36:00 ' Time
ttle:D980032 tl-724 Acq: 6- JAN- 1998 22:01:41 SC XI+ Voltage SIS 70S Noiae:8684
331.9368 r:2 BSD3(256, 30, -3.0) PXD(7,5,3f0.10\,34736.0,1.00\rr,T) Xxp:SDB5US
TSIANSLE LABS Text: 177/182-184/209 TLIt44376A
ion
BO:
sol
40:
20:
o:
A8.78E
l\6
\l
1 \J
23:00 24:00 25:00 '
7 2.2X7
69X7
A
l\
V
.1 . 8X7
ll . 3X7
.9.0X6
.4.5X6
.25.00 Time
rile:U980033 tl-724 Acq: 6-JXK-1998 33:01:41 SC XH- Voltage SIS 70S Noise 1 4675
333.9338 T:2 BSO3(2S6,30, -3.0) PKD(7,5,3,0.10\,18700.0e1.00\fr,T) Xxp:SDB5US
TSIANGLX LABS Text: 177/182-184/209 TLIt44376A
1001
80:
SO:
40:
20:
ol
A1.08X8 2.8X7
fl.
Ua.
1
J
/ \J
23:00 24:00 ' 25:00 '
22X7
A
'
V
-.2.2X7
.1.7X7
'.1.1X7
-.5.6X6
'• a. or a
26: 00 Time
Tile:U980032 tl-724 Acq: 6-JAN-1998 22:01:41 SC KX+ Voltage SIS 70S Soiae:2866
327.8847 r:2 BSDB(256,30r-3.0) PJOJ(7, 5,3,0 .10\,11464. 0,1. 00\,f,T) Xxp:HDB5US
TRIANGLE LABS Text: 177/182-184/309 TLH44376A
1001
80:
60:
40:
30:
o:
Al
1
33:00 24:00 25:00
.33X8 3.1X7
\_
.2.5X7
.1.3X7
.1.2X7
.6.2X6
o.axa
26:00 Time
File 1 0980032 tl-724 Acq: 6-JAN-199S 22:01:41 SC XH- Voltage SIS 70S
330.9792 T:2 XxptSDBSVS
TRIANGLE LABS Texts 177/102-184/209 TLH44376A
1001
00:
60:
40:
20:
oj
23:2133:35 23:58 24:15 24:46^25:03
33iOO 24:00 35:00
25j37 26} 03 26:19 26:37 6.2X7
.5.0X7
.3.7X7
.3.5X7
.1.3X7
a . ova
26: 00 Time
229
-------
r±2aiO9 80033 #1-724 Acqi 6-JAH-1998 22,01:41 GC XI* Voltage SIS 703 Hoife:3583
339.8597 f,3 3SOB(256,30,-3.0) ?XD(7,5,3,0.10\,14332.0,1.00\,r,T) XrpiHDSSUS
TSIASSLX LASS Text.-177/183-184/309 TLI944376A
100* A8.J.1X5
27100 28,00 23>00
rlla:U980032 H-724 Acq, 6-J1UT-1998 22i01>41 GC XH- Voltage SIS 70S JK>ifa:3981
341.8567 Ti2 BSU3(256,30, -3.0) PXD(7,5,3r0.10\,15924.0t1.00\,T,X) XrpiSDBSOS
TSIANSLX LASS Text: 177/182-184/209 TLH44376A
1004 A9.20XS
30100
27t00 28tOO 35i00 JO.00
r±le:O980032 91-724 Acqs 6-JXK-1998 22:01:41 GC XI + Voltage SIS 70S Boloet54B7
351.9000 T:2 3303(256,30,-3.0) PXD(7,5,3,0.10\,21948.0r1.00\,T,T) XxpiXDBSUS
TSIANSLE LASS Tarts 177/182-184/209 TLH44376A
lOOi, A3.65X7 A8.69X7
A
so:
60:
40:
20!
27:00 28i00 23:00 30:00
TlletU980032 tl-724 Acqi 6-J3UT-1998 22:01:41 GC XH- Voltage SIS 70S JToiaet6221
353.8970 r>2 3SU3(256,30,-3.0) PKD(7,5,3,0.10\,24SS4.0,1.00\,r,T) XxptSDBSUS
TSIAKGLE LASS Text: 177/182-184/209 TLIf44376A
1004 A6.49E7 A5.95E7
80:
sol
40:
30:
0.
27,00 28,00 29:00
rile:U980033 il-724 Acq: 6-JJOT-1998 23:01,41 GC XH- Voltage SIS 70S
330.9793 T:2 XxpiSDSSUS
TSIANGLX LABS Text: 177/182-184/209 TLH44376A
80:
50:
40:
20:
o:
27:10
37:3527:50
29 > 13
30:00
29:44 30:06 30:35
37:00 38:00 39:00
r±lmtU980032 tl-724 Aoqi 6-JAN-1998 22:01:41 GC EH- Voltage SIS 70S
409.7974 T:3 XxpiSDSSUS
TSIAHSLX LABS Tarti 177/182-184/309 XLH44376A
38,36
SO.
30,00
-------
rjJ.a:U9UOOJ3 #1-724 Acq:6-J3ul-199e J2:01s41 SC Sir VoJ.taga SIS 70S Noi.aaiJ.QJ4
355.8546 f:2 BSVB(256f30e-3.0) PXD(5,S,3,O.OS*,4136.0,1.00\fr,T) KxpiXDBSUS
TSIAOGLX LASS Taxtt 177/182-184/209 XLH4437SA
100* A3.32X5
A3. 73X5
37,48 28:00 23:12 28:24 29*36 23,48 29:00 29:13 29,24 29,36 39:48 30:00 30,12 30,24
rila,O980032 tl-724 Acq: 6-JZS-199B 22:01t41 SC XX* Voltage SIS 70S HOiae,2313
357.8516 Ti2 BSVB(2S6,30t-3.0) PXD(5,5,3,0.05\,9252.0r1.00\,r,T) XxptSDBSUS
TSIASGLX LASS Taxti 177/182-184/209 TLH44376A
ion
Time
-8.3X4
0.0X0
27:43 28:00 38:12 38:34 38:36 28:48 39:00 29:13 39:34 39:36 39:48 30:00 30:13 30:34
T±leiU980032 tl-724 Aoj: 6-J7OT-1998 32:01:41 SC XI+ Voltage SIS 70S Noiae:996
367.8949 T:2 BSUB(256,30,-3.0) PXD<5tSf3,O.OS\,3984.0,1.00\,r,X) Xxp:KDB5US
TSIASSLX LASS Text: 177/183-184/209 TLH44376A
100\ AS. 53X7
80.
60.
40.
20.
Titte
^1•6X7
,1.3X7
9.9X6
.6.6X6
.3.3X6
,0.0X0
27,48 28:00 28:12 28:34 28:36 28:48 29,00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rile:V980033 tl-724 Acq: 6-JJOT-1998 22:01,41 SC XI+ Voltage SIX 70S Koiae:1775
369.8919 T:2 BSUB(256,30,-3.0) PXD(S,5,3,O.OS\,7100.0,1.00\,TrS) XxptSDSSUS
TRIANGLE LASS Taxt:177/182-184/209 XLIt44376A
100* A3.69X7
80.
$0.
40.
20:
. 60X6
.1.1X7
8.9X6
6.7X6
,4.5X6
.2.2X6
27:48 28,00 28:12 28,24 28,36 28,48 29:00 29,12 29,34 39,36 39,48 30,00 30,13 30,34
rile,0980033 tl-724 Acq, 6-JA1T-1998 22:01,41 GC XZ+ Voltage SIX 70S
330.9792 F,2 XxptSDBSUS
TSIASSLX LASS Tmxtt 177/182-184/209 TLXt4437SA
0.0X0
Time
10K
80.
60.
40.
20.
0.
27:50
29155
29,44
30:06
30,28
-6.5X7
.5.2X7
.3.9X7
.2.6X7
.1.3X7
0.0X0
27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48 30,00 30,12 30,24
231
-------
TileiU9a0032 tl-384 Acq: 6^JAN-1998 22:01:41 GC EI+ Voltage SIX 70S Hoiae:5462
373.8308 t:3 BSVB(256,30,-3.0) PXD(7r5,3,0.10\r21848.0,1.00\,r,T) ExpiXDBSOS
TSIASSLX LABS Text: 177/182-184/209 TLH44376A
1001
aol
31,00 31,12 31,24 31:36 31,48 32,00 32,12 32,24 32,36 32,48 33,00 33,12 33,24 33,36 33,48
nj.e:O980032 tl-384 Acq: 6-J3Or-1998 22101 >41 GC XH- Voltage SIX 703 Soitei6344
375.8178 T,3 33UB(2S6,30,-3.0) PXD(7,5,3, 0.10\, 24976.0,1.00\,T,T) XxptttDBSUS
TBXANSLX LASS Tart: 177/182-184/209 TLIt44376A
1001
80:
31,00 31,12 31,24 31,36 31:48 32,00 32:12 32,24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
Tile,U9BOO32 tl-384 Acqs 6-J3OT-1998 22:01:41 GC EI+ Voltage SIS 70S Noiae:4190
383.8639 T:3 BSUB(256,30, -3.0) tXD(7,S,3,0.10\,16760.0,1.00\,T,T) Sxp:SDB5US
TBIABGLE LASS Tart: 177/182-184/309 TLH44376A
1004 A4.49X7
aol
601
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33,48
rtj.a, 0980032 tl-384 Acq: 6-JJOT-1998 22:01:41 GC EH- Voltage SIS 70S Noise, 5800
385.8610 Tt3 BSDB(2S6,30,-3.0) PXD(7,5,3,0.10\,23200.0,1.00\,r,T) Srp:SDB5US
TSIASSLS LABS Text: 177/182-184/209 TLH44376A
1001
aol
401
O
33:06
^33,26
33143
31,00 31:12 31:24 31:36 31:48 32:00 32,12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33,48
Tilei0980032 tl-384 Acq: 6-J7UT-1998 22:01:41 GC EH- Voltage SIX 70S
392.9760 Ti3 Exp:KDB5US
TXIASSLE LABS Text: 177/182-184/209 TLIt44376A
___.-^^^.-- 31:5832:0932:19 32:34
80- «T<
601
401
201
0.0X0
Tiae
O.OEO
Time
3.0E7
.2.4E7
.1. 8E7
J..2X7
.6.0E6
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rile:O980032 tl-384 Acq: 6-J3Ot-1998 22:01:41 GC EI+ Voltage SIX 70S
445.7555 F,3 SxpiSOBSUS
TRIANGLE LABS Texti 177/182-184/309 TLH44376A
0. OEO
Time
31:66 3lYl2 3l',24 31:36 31:48 32:00 32:13 32:24 32i36 32>48 33:00 33:12 33:24 33:36 33:48
O.OEO
Tiae
232
-------
H-JB4 Acq: 6-JAa-J.yye utu±:iJ. <»c. AJ.f voicage SIS /us ifoiaetjjt
389.8156 T-.3 BSVB(256,30, -3.0) PXD(7,5,3,0.10\,12960.0,1.00\,r,T) XxptHBBSUS
TXIASGLX LABS Text: 177/182-184/209 XLIt44376A
1001 A3 96X5
31', 36 31:48 32:00 32:12 32i24 32,36 32:48 33:00 33', 12
Fil»,U980032 tl-384 Acq: 6-JZOT-1998 22,01,41 SC EH- Voltaya SIX 70S Hoiae,4860
391.8127 Ti3 BSOS(256,30, -3.0) PKD(7,5,3, 0.10%, 19440.0,1.00\,T,T)
TRIXHSZX LASS Text: 177/182-184/209 TLH44376A
1001 A2.43X5
33:24 33 36
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
HJ.atO980032 tl-384 Acqi 6-JXB-1998 22:01:41 SC XI* Voltage SIS 70S Hoiae: 11739
401.8558 T:3 aSUB(256,30,-3.0) PXD(7,5,3,0.10\,46956.0,1.00\,T,T) Zxp:SDB5US
XSIANGLX ZABS Text, 177/182-184/209 TLIt44376A
100* A6.80X7 A7.42E7
33:24
A4.48E
80.
eo:
40.
20:
OJ
3l',36 31:48 32:00 32:12 32:34 32', 36 32:48 33:00 33:12
rileiO930032 tl-384 Acqi 6-JJOT-1998 22:01:41 SC EI+ Voltage SIS 70S Noise, 13573
403.8529 Ti3 BSUB(256,30,-3.0) PXD(7,5,3, 0.10*, 54292.0,1.00\,f,T) Exp:KDB5aS
T&IANSLZ LABS Text: 177/182-184/209 TLII44376A
A5.62E7
A3.72E,
1001
80.
60.
40.
20:
oi.
3l',36 31:48 32:00 32:12 32:24 32:36 32:48 33:00
ril»:O980032 tl-384 Acqt 6-JAS-1998 22:01,41 SC KI+ Voltage SIX 70S
392.9760 Ti3 KxptNDBSUS
TSIABCLX LABS Text: 177/182-184/209 TLIt44376A
A6.14E7
'.O.OEO
36 Time
33:24 33:36
33:12 33:24
33:36
1001
80.
60.
40.
20.
0.
31:45
31,58 32:09
33106
33126
-3.0X7
'.2.4X7
-1.8X7
.1.2X7
.6.0X6
.0.0X0
31:36 31:48 32tOO 32:12 32:24 32:36 32:48 33:00 'h': 12 33:24 33 36 Timi
233
-------
Tila:a9B0032 tl-545 Acq: 6-JXH-1998 22:01:41 GC SI+ Voltage SIS 70S Hoiaes6140
407.7818 T:4 BSOB(256,30,-3.0) PXS(7,5,3,0.10\,24560.0,1.00\,TtX) Srp:XDBSUS
LABS Taxt: 177/182-184/209 TLXt44376A
A1.Q6X6
35:00 35il2 35*24 35,36 3St48 36,00 36,13 36,24 36,36
ril»:0980032 tl-545 Acq: S-JMT-1998 22,01,41 GC XI* Voltage SIX 70S Boi,4407
409.7789 T:4 BSUB(256,30, -3.0) PXD(7f 5,3,0.101,17628.0,1.00\,r,T) XxptUOBSUS
TSIASSLX LABS Text: 177/183-184/209 TLH44376A
100\ A1.Q1X6
80.
60.
36,48
40:
A3.02X5
.0.0X0
37:00 TiM<
-2.9X5
'•.2.3X5
.1.8X5
'•.1.2X5
20:
\A4.78X4^\. A
^***J~**^S+/~**'f^Cr^^^^ \
A
-.5.8X4
35:00 35', 12 35,24 35:36 35:48 36', 00 36', 12 36:24 36:36
TilatU980032 H-545 Acq: 6-J2UT-1998 22:01:41 SC EI+ Voltage SIS 70S Soiaet5597
417.8253 T,4 BSVB(256,30, -3.0) PXD(7,5,3, 0.10\,22388.0,1.00\,T,T) XxpsSDBSVS
TSIASGLX LABS Text: 177/183-184/209 TLII44376A
1001 A1.4.1S7
Al.06X7
36,49
£.0.0X0
37:00 Time
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
rile:£79800J2 tl-545 Acq: 6-JJOT-1998 22:01:41 SC XI+ Voltage SIX 70S So±ae:9330
419.8220 T:4 BSU3(256,30,-3.0) fXD(7,5t3,0.10\r37320.0,1.00\,T,T) XxptSDBSVS
TSIASSLX LASS Text; 177/182-184/209 TLI944376A
100& A3.98X7
A2.98X7
36:48
-.0.0X0
37:00 ZLae
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24
rila:a980032 tl-545 Acq: 6-JAN-1998 22:01:41 GC XI+ Voltage SIS 70S
430.9729 T:4 EipiKDBSUS
TSIANSLX LABS Text: 177/182-184/209 TLIt44376A
36,04
36:36
36:48
60:
40:
20:
o:
0.0X0
37:00 Time
-2.0X7
'.1.6X7
.1.2X7
-8.2X6
-4.1X6
35:00 35,12 35:24 35:36 35:48 36:00 36,12 36:24
rileiU980032 tl-545 Acq: 6-JJUT-1998 22:01:41 GC XI+ Voltage SIX 70S
79.7165 T:4 KipiHUBSUS
TSIASSLX LABS Textt 177/182-184/209 TLH44376A
1004
36:36
36:48
.0.0X0
37:00 Tim,
35:00
35:12
35*24
35:36
35:48
36:00
36:12
36:24
36:36
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File:U980032 #l-r545 Acq: 6-JAN-1998 22:01:41 GC EI+ Voltage SIR 70S
443.7399 F:4 Exp:NDB5US
Sample Text:177/182-184/209 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100* ; A1.J5E6
40:48
39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24
File:U980032 #1-545 Acq: 6-JAN-1998 22:01:41 GC EI+ Voltage SIR 70S
469.7779 F:4 Exp:NDB5US
Sample Text:177/182-184/209 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
lOOi 39j36
80J
60 j
40J
20 j
ol
40:36
40:48
_2.5E5
_2.0E5
_1.5E5
_9.9E4
L5.0E4
i.0. OEO
Time
2.6E5
L2.1E5
L1.6E5
i.l.OE5
L5.2E4
LO.OEO
Time
39:00
39:12
39:24
L9.0E6
L6.7E6
_2.2E6
39:36
39:48
40:00
40:12
40:24
40:36
.O.OEO
40:48 Time
-------
TLI Project: 44376A Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: 177/182-184/209 £ £), i Analysis File: P980100
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight
GC Column:
Culp Aluipinum Alloys
M23TRAIN Date Received:
194-59-15A Date Extracted:
Date Analyzed
1.000 Dilution Factor
n/a Blank File:
DB-225 Analyst
12/17/97
12/29/97
01/07/98
n/a
P980094
JM
Spike File:
ICal:
ConCal:
SPC2NF04
PF22206
P980092
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
%' :\ Awt/pr -% ot
0.02
EMPC
;|ntemiE$Janefarti ?;~--Amt jjufc % Recovery QC limits
13C,r2^,7,8-TCDF
f Recovery Standard
13C,rU,3,4-TCDD
2.9 72.0
-° ' **S'
40%- 130%
' Ratio
0.80
Ratio
0.79
Ratio
0.80
RT
23:06
RT
23:05
RT
21:55
Ftegs
B_
Flags
—
Flags
Data Reviewer
\^^
Page 1 of 1
01/09/98
aNF.FSRvUI.LAlU6.ia.OU
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1601/09/98
249
-------
Initial
. .Dace.
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio linits has been recalculated according to method requirements.
1.22
Page No. 1
Listing
01/09/98 Matched
Compound/
M_Z QC. Log Omit Why ..RT. OK
TCDF
304-306 DC
DC
DC
DC
DC
DC
DC
DC
M
DC
DC.
304-306
13C12-TCDF
316-318 DC
DC
DC
DC
DC
DC
DC
DC
316-318
13C12-TCDD
332-334 DC
DC
332-334
HL
SN
SN
SN
SN
SN
SN
SN
SN
SN
5
NX,
WL
WL
WL
SN
SN
WH
WH
2
NL
SN
4
0
19
20
20
20
20
21
21
22
22
22
23
23
23
24
:00
:27
:08
:20
:29
:36
:10
:36
:08
:21
:59
:06
:19
:36
:32
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
of P980100B.dbf
GC Peaks / Ratio
Ratio Total. Area
.65
1
1
2
1
2
0
0
0
0
1
1
0
0
0
0
-0.89
.01
.45
.05
.29
.34
.99
.89
.84
.38
.10
.54
.80
.99
.96
.43
Peaks
0:
21:
21;
22:
23:
00
:35
;51
:03
:05
23:18
23:
23:
24:
25:
22
42
09
09
0.
RO
RO
RO
RO
RO
RO
RO
65
1
0
0
0
0.
3
0.
0.
2.
0.
Peaks
0:
20:
20:
21:
21:
22:
00
28
35
37
SS
40
0.
RO
RO
RO
•0.89
.01
.63
:78
.52
.79 1,
.80
.67
.93
48
53
1,
65-0.89
1.
0.
0.
0.
0.
1.
Peaks
53
69
34
79
80 1,
07
2,
1
1
0
/ Ret. Tine
... Area. Peak. 1 .. Area . Peak . 2 . . Re I . RT Compound HUMP in
.79
.42
.76
2.46
1
3
10
5
1
0
1
7
2
3
1
29
3.
8.
32.
0.
340.
0.
0.
6.
1.
8.
.20
.08 1.72
.60 4.99
.39 2.46
.91
.73
.65
.60 3.37
.19
.17 1.71
.10
.84
.12
.09
.58
.94
,63 590.39
73
97
39 3.34
61
11
0.7Q2
o
0
n
0
0
1.74 0
5.61 0
2.93 0
0
0
0
4.23 1
1
1.79 1
1.
0.957-
0.
0.
0.
0.
750.24 1.
1 .
1 .
3.61 I .
1 .
1 .
•1.101
DIII'I
.843
872
.881
.887
.892
.917
.936
.959
.968
.996
.001 2378 -TCDF AN
.010
.022
.063
•1.043
000
935
947
955
000 13C12-2378-TCDF ISO
009
012
027
1)46
OCiti
347.02
TCDF / TCDD Follows ----
1.
6.
1.
982.
342.
11.
342.
58
22 2.53
15
64 434.10
00 597.84
29 6.80
15
0.908-
0.
3.69 0.
0.
548.54 1.
744.16 1.
6.38 1.
1.092
000
947
952
000 13C12-2378-TCDD IS1
014 13C12- 1234 -TCDD RSI
049
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:16 01/09/98
250
-------
Page No. 2 Listing of P980100B.dbf
01/09/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rei.RT Compound Name ID Flaps
Column Description . . . "WnY^_ 9ode_Des5riP5ion.- •_• -^•_!•_•_ _QC Log Desc.
M_2 -Nominal Ion Masa(es) ML-Below Retention Time Window A-Peak Added
..RT. -Retention Time (raise) MR-Above Retention Time Window K-Penk Kept
Rat.l -Ratio of M/M+2 Ions SN-Below signal to Hoise Level D-Peak Deleted
OK -RO-Ratio Outside Limits
-------
rilmitsaoioo ti-933 Acq:/-JAH-ya ui:a*:jj sn-
303.9016 Kzp,DS225
TSXJUfSLX LASS I*tt: 177/182-184/209 TLH44376A
23 • 06
,1.5X4
04
22:36' 32i48' 2Jlo0 23:12 23:24 23:36 23:48 24:00 24:12 24:24 24:36
rile:P980100 tl-922 Acq:7-J3UT-98 04:54:32 EH- Voltage SIX 70P
315.9419 Ezp:DS225
TZXAXGLX LASS Text: 177/182-184/209 TLH44376A
1001
95.
90.
85.
80.
75.
70:
65:
60:
55:
50:
45:
40:
35:
30:
25:
20:
15J
10:
5j
23; OS
O.OEO
24:48 25:00 25:12 25:24 T±ae
1. 6E6
'•.1.SE6
.1.4E6
.1.3E6
.1.3X6
.1.2E6
J..1E6
.1. OE6
J.SES
.8.7X5
.7.9X5
.7.1X5
.6.3X5
.5.5X5
.4.7X5
.4.0X5
.3.2X5
.2.4X5
'.1.6X5
.7.9X4
22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24
.0. 0X0
Hat
252
-------
FU.aiP9UOJ.00 ti-932 Acq:7-JMi-Sa 04:3f,J4 AJT voxcaye SIM /op Noiaetsua
303.9016 BSUB(256,30,-3.0) PXD(Se3,l,0.10\,2032.0,0.00\,T,r) Xxp,Dtt22S
TXIANGIX LABS Text: 177/182-184/209 TLH4437SA
100*
19': 00 20:00 21,00 22sOO 23'tOO 24:00
r±le,P980100 fl-922 Acq:7-J3UT-98 04t54t32 £Z> Voltage SIX 70P Soiae,507
305.8987 BSVB(256,30,-3.0) PXD(5,3,1,0.10\,2028.0,0.00\,r,T) KlpiDB225
XSIASSZX LASS Text: 177/182-184/209 XLH44376A
100* AS. f 1X4
25100
19:00 20:00 21:00 22:00 23:00 24:00
Tile>P980100 fl-922 Acqt7-JJOr-98 04t54i32 XI+ Voltage SXZ 70P No±aot889
315.9419 B3UB(256,30,-3.0) PKS(5, J, 1, 0.10\,3556.0,0.00\,rrr) ZzptDB22S
TSIANSLX LAB3 Text: 177/182-184/209 XLH44376A
100* A5.90ES
80.
SO.
40.
20.
25100
19:00 30:00 21:00 22:00 23:00 24:00
rilaiP980100 H-922 Acq>7-JKN-98 04:54:32 EH- Voltage SIS 70P Noise:882
317.9389 BSUB(256,30,-3.0) PKD(5,3,1,0.10\,3538.0rO.OO\,r,r) Exp:DB225
ANSH: LABS Text: 177/182-184/209 TLH44376A
100* A7.SOSS
80.
SO.
40.
20.
0.
25:00
19:00 20:00 21:00 22>00 23:00
Tilo:P9B0100 91-922 Adjt7-J3OT-98 04:54:32 XI+ Voltage SIS 70P
375.8364 Sxp:DB225
TSIAKSLX LASS Text: 177/182-184/209 TLIt44376A
100*18:32
24:00
25100
33,14 23,46 24:I*!3" t 35,14
-1. 6X6
'.1.3E6
.9.5X5
-6.3XS
.3.2X5
0.0X0
Time
-2.0X6
'.1.6X6
.1.2X6
'.8.2X5
.4.1X5
0.0X0
Time
19,00 20,00 21:00 22,00 33':00 24,00 ' 25':00
-9.4X3
.7.5X3
.3.6X3
3.7X3
^1.9X3
.0.0X0
Time
253
-------
FU.mtP9oQl.QQ ti-922 Acqi 7-JJUI-Sa C«»5««JW £1+ Voltage SIS 70f Soj.fei410
319.8965 BSUB(256,30,-3.0) PXD(5,.3,1,0.10%, 1640.0, 0.00\,f,r) XxpiDB225
TSIASGLX LABS Tmzt,177/182-184/209 XLH44376A
1001
20:00 31:00 22:00 23:00
rLL»:P980100 tl-922 Acqi7-JJUT-98 04,54,32 SI+ Volt*?* SIX 70P Xo±**i442
321.8936 BSUB(256,30,-3.0) ra>(5,3,1,0.10\r1768.0,0.00\,T,T) XrptDB223
TXIASGLS IA3S T&ctt 177/182-184/209 TLH44376A
ion
20', 00 21:00 22iOO 23tOO
rile,P9B0100 tl-922 Acq:7-J3OT-9B 04,54,32 EH- Voltage SIS 70P SOifmtSOS
327.8847 BSVS(256,30, -3.0) PXD(S,3,lr0.10\,2020.Q,0.00\,r,T) XxpiDB225
ISIANSLZ LABS Tort: 177/182-184/209 TLH44376A
1001 A8.98S6
80.
60.
40.
20.
20100 21:00 22:00 23:00
r±J.e,P980100 tl-922 Acqt7-JJOt-98 04,54:32 ZI+ Voltage SIS 70P Noiae,678
331.9368 BSUB(256,30,-3.Q) PKD(5,3,1,0.10\,2712.0,0.00\,T,T) SxptDB225
TBIANGLX LABS Text:177/182-184/209 TLH44376A
1001 AS. 98X6
80.
60.
40.
20.
0.
A4.34X6
20100 21:00 22:00 23:00
ril»:P980100 tl-922 Acq:7-JXJT-98 04:54:32 £Z> Volttgu SIS 70P Soimmt447
333.9338 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,1788.0,0.00\,r,r) Xxp:JJB225
TSIANCLS LABS Text: 177/182-184/209 XLIt44376A
1001 AT. 4416
80.
SO.
40.
20.
0.
AS.49X6
24:00
24:00
24:00
24:00
25 00
.0.0X0
T±ma
0.0X0
25 00 Time
2.4E6
.1.9X6
J..4X6
J.6X5
L4. 8E5
25
.0.0X0
00 Time
_1.6X6
.1.3X6
'.9.4X5
.6.3X5
.3.1X5
.0.0X0
25 00 lime
20:00
21:00
22:00
23:00
24:00
-.2.0X6
'.1. 6X6
.1.2X6
.7.9X5
.3.9X5
.0.0X0
25 00 T±ae
254
-------
tl-922 Acq:7-JAlf-98 04:54:32 EH- Voltage SIS 70f
303.9016 Exp:DS225
TSIASSLX LASS Tmxt:177/182-184/209 TLIt44376A
IS I 00 20tOO 21100 22100
Til*sP980100 tl-922 Acq:7-JAS-98 04:54t32 XX* Voltage
315.9419 Xzp:DS225
TSIASSLX LASS T«rt» 177/182-184/209 TLIt44376A
1003
ao:
sol
40:
20:
23 tOO
SIS 70P
231 OS
24100
25100
19:00 20:00 21tOO 22tOO 23:00
TilatP9S01QO tl-922 Acq:7-JJOT-98 04:54:32 EI+ Voltage SIS 70P
319.8965 Xxp:DS225
TSIASSLX LABS Text: 177/182-184/209 TLH44376A
24 s 00
25:00
19100 20s00 21:00 23s 00
F±latPS80100 tl-922 Acq:7-J7Ur-9a 04:54:32 EI+ Voltage
331.9368 Kxp:DB225
TSIASKLX LASS Text: 177/182-184/209 TLXt44376A
1001
SO:
60:
40:
20:
23 s 00
SIS 70P
24:00
25:00
19:00 20:00 21:00 22:00
r±latP980100 tl-922 Acq:7-JJOT-9S 04:54:32 EH- Voltage
292.9825 Exp:DB225
TSIASSLX LASS Taxt:177/182-184/209 TLH44376A
1003L. lfljjfl_ .19j2^19j56 20.
80:
60:
40:
20:
0.
23:00
SIS 70P
24:00
25:00
33:10 23:5434:32 24:59
•• --
6X6
3X6
5XS
3X5
2X5
OEO
Time
.OEO
T±ae
6E6
3X6
4X5
3X5
1X5
0X0
7.
.4.
19:00 20:00 21:00 22:00
rile:P980100 tl-922 Acqi7-JZK-98 04:54:32 SI+ Voltage
330.9792 XxpiDS225
TRIANGLE LASS Text: 177/182-184/209 TLIt44376A
100\ 19:37 20:20 . 21t39
~*-*ff\,S*bf~»fi\j>
80.
60:
40:
20:
o.
23:00
SIS 70P
24:00
25:00
24:39
"V^^f
19:00
20:00
21:00
22 tOO
23:00
24:00
25:00
3X6
9X6
4X6
.9X6
.5X6
.0X0
Mae
9X6
.7X6
.5X6
.3X6
.2X6
.0X0
Hue
255
-------
Ref, tass 292,9825 Peak top
Height 1,23 volts Span 288 ppi
Systet file naie
Data filenaie
Resolution
Groupruber
lonization Kde
Switching
Ref, lasses 292,9825,
R 292,9825 J
8 383,9816 K
D 3&9419 H
E 317,9389
F 319,8965
6 321,8936
H 327,8847
I 338,9792
Channel I 338,9792 Peak top
Height 1,85 volts Span 288 ppi
1
El*
VOGE
388,3761
338,9792
331,9368
333,9338
375,8364
256
-------
Frie:P98010()
303.9016 Exp:
Sample Text:177/182
100%
60 j
40J
20J
Oj
-922 Acq:7-JAN-98 04:54:32 EH- Voltage SIR 7OP
DB225
-184/209 TLI#44376A File Text:177/182-184/209 TLI#44376A
A3.37E4
22:12 22
CM
1.5E4
L1.2E4
18.7E3
L5.8E3
L2.9E3
LO.OEO
•24 22:36 22:48 23:00 23i12 23i24 23:36 23i48 24iOO 24i12 24:24 24:36 Time
File:P980100 #1-922 Acq:7-JAN-98 04:54:32 EI+ Voltage SIR 70P
305.8987 Exp:DB225
Sample Text:177/182-184/209 TLI#44376A File Text:177/182-184/209 TLI#44376A
100% A4.23E4
80J
60 j
40J
20 j
OJ
22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48
File:P980100 #1-922 Acq:7-JAN-98 04:54:32 EI+ Voltage SIR 70P
315.9419 Exp:DB225
Sample Text : 177/182-184/209 TLI»44376A File Text : 177/102-104/209 TLIH44376A
100% i 23;05
80J
_1.6E4
Ll.3E4
19.9E3
L6.6E3
L3.3E3
LO.OEO
24 S 66 ' 24!12 ' 24124 ' 24:36 Time
20_:
0.
_1.6E6
L1.3E6
19.5E5
L6.3E5
L3.2E5
22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24
24:
I- n . OEO
36 Time
-------
TLI Project:
Client Sample:
44376A
178-181/226
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U98003
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAJN
194-59-15B-D
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1,2,3,7.8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
l,2J,4,6,7,8-HpCDD
1,2.3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2^,7,8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
1,2^,4,7,8.9-HpCDF
1,2.3,4,6,7,8.9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt fng)
ND
ND
ND
0.01
EMPC
0.04
0.14
0.07
EMPC
0.03
0.08
0.03
0.04
ND
0.14
ND
0.10
Amt {ngj
0.04
0.01
0.03
0.08
0.30
0.36
0.28
0.18
-.' "-WL ^EMPC " ' -•'..
0.005
0.008
0.01
0.01
,0-02
0.009
0.01
fiumber DL EMPC
2 0.04
1 0.06
2 0.10
2
10 0.35
10 0.40
6 0.31
2 0.22
Ra*K>
1.16
0.93
0.93
0.76
1.42.
1.36
1.32
1.36
0.88
0.83
RT
32:49
36:03
39:36
24:39
29:16
32:02
32:09
32:37
35:01
39:48
Flags
j
j_
j_
JB_
B_
J_
J_
J_
J_
J_
T
Flags
—
Page 1 of 2
MTT7_PSR »I jOI. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
238
-------
TLI Project 44376A
Client Sample: 178-181/226
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980033
^brti^ Standard^
13C,2-2.3,7,8-TCDF
"CB-W.7.8-TCDD
°CirlA3,7.8-PbCDF
l3Ct2-U,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,rlA3,6,7,8-HxCDD
13C,2-U,3.4,6J,8-HpCDF
13C a- 1 .2.3 ,4,6,7,8-HpCDD
13C ,2- 1 A3 ,4,6,7,8 ,9-OCDD
SariogateStaiwteKte {type A)
13C12-2.3,4,7,8-PeCDF
13C,2-U.3,4,7,8-HxCDF
13C,2-U,3,4,7,8-HxCDD
13C,2-U,3,4,7,8,9-HpCDF
; Surrogate Standards {Type A>
37CL,-2.3.7,8-TCDD
Alternate Standards {Type A)
13C,2-U,3,7,8,9-HxCDF
13C12-2,3.4.6,7,8-HxCDF
Recovery Standards
13C,rU.3,4-TCDD
13C12-lA3,7,8,9-HxCDD
Amt. ^1;^"^
2.4
2.4
2.7
2.6
3.0
2.5
3.1
6.0
Amt. fci$
3.9
3.7
3.9
. 3.4
ArraX ^jFi0)
3.3
Arm. ||Bcov«y~x'
60.5
63.7
59.5
67.7
64.3
75.3
63.2
76.3
75.6
^Recovery
98.4
92.4
97.0
85.2
; %Recweiy
83.1
%fiecovery
63.7
68.9
SV. \ V f
40%-130%
40%-130%
40%-130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%-130%
40%-130%
^4lMfc>.- •
0.76
0.80
1.50
1.48
0.49
1.18
0.42
1.02
0.85
Ratto
1.53
0.48
1.30
0.41
Ratio
0.49
0.48
Ratio
0.81
1.22
^..m-^
24:36
25:19
28:34
29:35
32:08
32:48
35:00
36:02
39:36
RT
29:15
32:02
32:43
36:32
RT
25:20
RT
33:23
32:36
RT
25:09
33:07
••<•••••• Flags-: '
—
Ftegs
—
Ftegs
—
Ffegs
—
Flags
—
Data Reviewer
01/10/98
Page 2 of 2
MTn_PSRvl.OI,LARS &IO.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
259
-------
Initial
. . Date...
Data Review By:
Calculated Noise Area:
8.88
The Total Area for each peak with an ion abundance ratio outside
ratio limits ha a been recalculated according to method requirements.
Page No.
01/10/98
Listing of 0980033B.dbf
Matched GC Peaks / Ratio / RetT ~Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. .
Rel.RT Compound.Name.. 10.. Flags.
TCOF
304-306
ND
K
K
K
K
K
N
M
304-306
13C12-TCDF
316-318
DC NL 0
D SN 21
22
22
22
23
23
23
24
24
24
24
25
25
26
0
:00
:27 RO
:12 RO
:36
:56 RO
:19
:35
:48
:01
:14
:27 RO
:39
:04
:16
:22
.65
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
13 Peaks
0.
DC NL 0:00 RO
DC ML 23:35
23:51
316-318
TCDD
320-322
KN
KN
D
K
D
D
D
320-322
24:
24:
25:
DC WH 25:
DC WH 25:
:13
36
04 RO
:37
58
-0.89
•81
.12
.59
.70
.57
.72
.81
.81
.77
.89
.60
.76
.81
.77
.70
2
24.71
46.78
67.90
218.84
122.11
176.24
164.62
177.80
196.60
155.96
76.34
436.37
109.81
84.33
46.91
,033.83
0.867-1.079
0.000
29
90
53
73
73
79
85
73
33
188
49
36
19
.54
.35
.12
.55
.48
.80
.60
.58
.21
.41
.28
.76
.30
50
128
92
102
91
98
111
82
55
247
60
47
27,
65-0.89
1.28
0.
0.
0.
0.
1.
0.
0.
4 Peaks
DC NL 0:
22:
23:
D SN 23:
24:
D SN 24 :
D SN 24 :
DC SN 24 :
D SN 25 :
DC SN 25 :
DC SN 25 :
0.
00 RO
47
11
23 RO
08 RO
27
35 RO
48 RO
13
20 RO
41 RO
65-
1.
0.
0.
1.
0.
0.
2.
1.
0.
0.
1.
.74
.71
82
76 19
94
75
89
19
0.89
18
79
71
58
64
69
41
22
73
22
36
3 Peaks
12.64
416.06
44.54
147.67
,017.23
120.29
15.52
13.23
,329.73
TCDF / TCDD
5.12
109.60
69.15
3.24
29.98
11.78
10.58
6.11
38.61
6.39
3.59
208.73
18.
66.
8,205.
131.
.51
56
13
98
26.
81.
10,812.
67.
.34
.49
.73
.69
.14
.00
.00
.38
.63
.96
.53
.57
.61
0.872
0.902
0.919
0.932
0.948
0.959
0.967
0.976
0.985
0.994
1.002 2378 -TCDF AN
1.019
1.027
1.072
J
J
J
J
J
J
J
J
J
J
J
J
0.959-1.041
03
11
10
96
0.000
0.959
0.970
0.984
1.000 13C12-2378-TCDF ISO
1.019
1.041
1.056
48.
28.
13.
49
74
04
61.
40.
20.
0.895-1.047
11
41
33
0.000
0.900
0.916
0.924
0.953
0.966
0.971
0.980
0.996
1.001 2378 -TCDD AN
1.014
J
J
J
.Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
280
-------
Page No. 2
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of (J980033B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
M
M
AN
D
DC NL 0:00
23:58
25:20
25:35
25:42
25:49
25:59
26:04
26:38
26:51
9 Peaks
0.65
DC NL 0:00 RO 2
24
25
25
25
25
:09
:09
:19
:39
:50
RO 1
0
0
0
RO 1
5 Peaks
1.81
254.56
12,670.80
110.58
130.90
104.66
22.08
43.97
12.24
17.32
13,367.11
-0.89
.19 14.53
.08
.81 21
.80 15
.82
.02
37
77.24
,411.05
,239.33
602.63
146.11
,476.36
mr*r\r\ /
1.32-1.78
DC NL 0
26
27
27
27
D SN 28
28
28
28
28
28
28
D SN 28:
:00
:35
:34
:43
:52
:02
RO 0
.78
1.52
1.
.32
1.39
RO 1.31
RO 0.48
:11 1.51
:18 1.55
:30
:35
:44
:52
:59
29:16
29:24
D
D
340-342
13C12- PeCDF
352-354
D SN 29:44
DC SN 29 :
D SN 30:
55
14
1.55
RO 1.
1.
1.
RO 0.
1.
1.
RO 1.
RO 0.
1.
12 Peaks
27
33
52
51
42
70
23
22
33
1,
5.53
163.33
58.77
322.20
67.35
19.03
99.50
187.95
76.80
60.71
60.44
102.27
8.34
126.65
166.85
36.90
3.06
22.62
492.82
254.56
12,670.80
110.58
130.90
104.66
22.08
43.97
12.24
17.32
47
9,574
6,793
270
83
.15
.65
.46
.80
.82
43
11,836
8,445
331
82
0.
0.
.64
.40
.87
.83
.55
.921-1.079
0.000
0.947
1.001 37C1-TCDD CLS
1.011
1.015
1.020
1.026
1.030
1.052
1.061
921-1.079
0.000
0.954
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.020
98
33
187
40
59
114
46
36.
34.
61.
74.
104.
.60
.46
.23
.94
.80
.28
.70
.90
.53
,75
21
99
64
25
134
31
39
73
30.
29.
25.
40.
52.
61.
1.32-1.78
DC NL 0:
27:
28:
28:
29:
29:
00
42
34
50
03
15
RO 11.
1.
1.
RO 1.
RO 1.
1.
55
54
50 14,
86
86
53 13,
0.56
588.08
537.90
385.25
79.84
822.53
356.
8,715.
281.
58.
8,351.
51
04
03
15
70
231.
5,822.
151.
31.
5,470.
0.
.73
.31
.97
.24
.70
.67
.10
.10
.91
.52
.44
86
925-1.065
0.000
0.931
0.965
0.970
0.975
0.981
0.987
0.991
0.998
1.001 12378-PeCDF AN
1.006
1.011
1.015
1.025 23478-PeCDF AN
1.029
1.041
1.047
1.058
J
J
J
J
J
J
J
J
J
J
J
J
0.860-1.140
57
86
08
31
83
0.000
0.970
1.000 13C12-PeCDF 123 IS2
1.009
1.017
1.024 13C12- PeCDF 234 SUR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
261
-------
Page No.
01/10/98
Compound/
M_Z .... QC .
3 Listing
Matched
Log Omit why . .RT.
OK
29:35 RO
29:45
30:13 RO
352-354
PeCDD
356-358
of U980033B.dbf
GC Peaks / Ratio /
Ratio Total. Area. . .
1.04
1.62
1.26
8 Peaks
DC NL 0
:00
27:49
D
D
D
D
356-358
13C12- PeCDD
368-370
DC SN 27
28
DC SN 28
28
DC SN 29
DC SN 29
D SN 29
D SN 29
D SN 29
D SN 29
DC SN 30
:57
:31
:42
:51
:00
:06
:17
:27
:36
:43
:05
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
1
0
0
1
1
1
1
1
2
0
1
1
3
.27
.95
.65
.83
.11
.78
.26
.18
.08
.85
.22
.25
.32
3 Peaks
DC NL 0
28
:00
:31
28:39
DC SN 29
29
:00
:35
1.
RO
RO
RO
RO
194 . 29
65.28
39.93
29,713.10
• Dm fonts' /
reujr /
0.46
68.98
1.96
55.08
7.65
42.25
7.78
6.38
19.56
8.54
10.91
10.22
4.00
166.31
Ret. Time
Area . Peak .
.1. .
118.10
40.34
24.27
Area . Peak . 2 . .
113.27
24.94
19.33
Rel.RT Compound. Name. . ID.. Flags
1.036
1.041
1.058
D«f*nn Bfc* 1 1 nua _ •
41.93
39
27
.49
.06
44
21
15
32-1.78
1.16
2.25
0.97
2.30
1.48
29:43
30:10
RO
30:20
368-370
HxCDF
374-376
30:
28
RO
1.72
1.
02
1.46
0.
7 Peaks
1. OS-
DC NL 0:
00
31:04
D
M
D
31:
D SN 31:
31:
31:
DC SN 31:
32:
32:
32:
32:
32:
DC SN 32:
D SN 33:
13
23
30
41
47
02
09
16
25
37
53
27
RO
RO
RO
RO
RO
RO
RO
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
6.
98
1.43
39
14
17
89
64
13
76
36
32
45
03
36
12
2.08
0.36
14.79
10.58
5.69
8,550.21
1,242.39
29.83
18.92
16.16
9,882.88
PeCDD /
17.96
123.45
247.83
14.89
20.32
23.05
3.32
228.93
92.41
24.57
36.92
114.70
2.67
18.48
13
6
.05
.43
5,099.89
784.
18.
11.
9.
.80
,13
.24
.82
0.935-1.022
.22
.60
.19
0.000
0.940 j
0.945
0.964 J
0.970
0.975 J
0.980
0.984
0.990
0.995
1.001 12378- PeCDD AN
1.005
1.017
0.865-1.135
5.80
6.63
3,450.
,32
457.59
17.72
7.
10.
68
00
0.000
0.964
0.968
0.980
1.000 13C12- PeCDD 123 IS3
1.005
1.020
1.025
1.030
65.
133.
14.
12.
131.
52.
15.
20.
66.
88
83
92
25
74
59
88
44
00
57.
114.
9.
10.
97.
39.
10.
19.
0.962-1.047
57
00
07
80
19
82
97
87
48.70
0.000
0.967 J
0.971 J
0.977
0.980 J
0.986 J
0.989
0.997 123478-HxCDF AM J
1.001 123678-HxCDF AN J
1.004 J
1.009 J
1.015 234678-HxCDF AN J
1.023
1.041
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 017,
-------
Page No.
01/10/98
Listing of 098003361dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Hel.RT Compound.Name.. ID.. Flags.
374-376
9 Peaks
912.18
13C1J-HXCDF
384-386
384-386
HxCDD
390-392
•
M
390-392
PL3C12- HxCDD
402-404
402-404
HpCDF
408-410
D
DC NL 0
31
31
DC SN 31
32
32
32
33
33
33
DC SN 33
:00
:04
:16
:02
:08
:36
:12
:23
:47
:49
--U.-4J
RO 1
0
0
RO 0
0
0
0
0
0
RO 1
RO 0
-0 . 39 •- -
.27
.43
.46
.78
.48
.49
.48
.47
.49
.45
.65
8 Peaks
DC NL 0
31
32:
DC SN 32:
32:
. 32:
DC SN 32:
33;
:00
:34
:01
:08
:13
:49
:59
:07
1.05
RO 0
RO 0
RO 1
RO 4
1
1
RO 0
RO 1
-1.43
.97
.95
.45
.07
.39
.16
.43
.02
5 Peaks
DC NL 0:
32:
32:
32:
33:
33:
00
12
43
48
07
33
1.05-
RO 1
1,
1,
1.
1,
RO 7.
5 Peaks
-1.43
.63
,24
,30
,18
,22
.69
0.88-1.20
DC NL 0:
35:
35:
35:
D SN 36:
00
01
17
26
33
RO 0.
0.
0.
RO 1.
1.
72
88
93
24
07
8.08
74.28
151.45
6.54
8,645.83
11,340.31
10,964.58
32.04
7,803.98
7.40
9.88
39,019.87
9.19
21.71
97.48
5.82
45.64
22.83
2.19
24.39
212.05
22
47
2,806
.29
.67
.69
3,716.34
3,575
10
2,566
7
.22
.23
.97
.11
51
103
5,839
7,623
7,389
21
5,237
4
•-W.8VO--l.-iJ4-- - -"-
0.000
.99 0.967
.78 0.971
.14
.97
.36
.81
.01
.90
0.973
0.997 13C12-HXCDF 478
1.000 13C12-HXCDF 678
1.015 13C12-HXCDF 234
1.033
1.039 13C12-HXCDF 789
1.051
1.052
SOT2
IS4
ALT2
ALT1
HxCDD F*o 1 T nwn ————————— -.-
12.
63,
26.
12.
13.
.02
.08
.54
.28
.50
0.
12.62
43.
19.
10.
13.
.52
.10
.55
.30
958-1.014
0.000
0.962
0.976
0.980
0.982
1.001 123678-HxCDD
1.006
1.010 123789 -HxCDD
J
J
J
AN J
AN J
0.970-1.030
11.22
47.12
6,971.88
9,821.98
13,104.52
14.60
29, 960.10
: HxCDD /
13.20
342.48
78.89
81.13
52.14
26.
3,936.
5,313.
7,214.
50.
06
17
82
47
17
21.
3,035.
4,508.
5,890.
6.
06
71
16
05
52
0.000
0.982
0.997 13C12-HXCDD 478
1.000 13C12-HXCDD 678
1.010 13C12-HXCDD 789
1.023
SOR3
IS5
RS2
160.
38.
49.
10
01
14
182.
40.
39.
0.996-1.049
38
88
77
0.000
1.000 1234678-HpCDF
1.008
1.012
1.044 1234789-HpCDF
AN
J
J
AN
408-410
3 Peaks
13C12-HpCDF 0.37-0.51
418-420 DC NL 0:00 RO 0.92
35:00 0.42
35:25 RO 0.80
502.50
14.66
6,810.63
49.54
2,017.35
27.50
0.943-1.114
0.000
4,793.28 1.000 13C12-HpCDF 678 IS6
34.40 1.012
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
263
-------
Page No.
01/10/98
Listing of O980033B.dbf
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
36:32
SN 36:59
3 Peaks
NL 0:00
35:17
36:03
SN 36 : 19
NH 36:32
2 Peaks
NL 0:00
35:17
36:02
36:26
36:33
4 Peaks
NL 0:00
SN 36:03
SN 36:24
SN 36:39
39:48
SN 40:26
SN 40:35
1 Peak
NL 0:00
39:36
SN 40:07
1 Peak
0.41
RO 0.14
0.88-1.20
RO 0.82
1.02
0.93
RO 1.67
RO 1.79
0.88-1.20
0.96
0.97
1.02
1.05
1.01
0.76-1.02
1.02
0.99
0.92
RO 0.44
0.83
RO 0 . 13
RO 0.66
0.76-1.02
RO 0.04
0.93
0.89
4,653.39 1,358.87
14.01
11,513.56
• UrW*niP / Ur^T^n C*« 1 1 siua ~ •
. np^ue / npuju r ox .LOWS *
4.30
77.15 38.88
75.31 36.26
3.12
10.53
152.46
19.18
48.62 23.93
7,263.48 3,664.67
68.88 35.32
57.06 28.62
7,438.04
: HpCDD / Octa-CDD and CDF
5.00
7.50
2.78
2.31
189.54 85.98
1.72
2.38
189.54
0.13
207.89 100.13
5.49
207.89
3,294.52 1.044 13C12-HpCDF 789 SOR4
1.057
0.975-1.005
0.000
38.27 0.979 J
39.05 1.000 1234678-HpCDD AN J
1.008
1.014
0.972-1.028
0.000
24.69 0.979
3,598.81 1.000 13C12-HpCDD 678 IS7
33.56 1.011
28.44 1.014
Follows -•-
0.899-1.101
0.000
0.910
0.919
0.926
103.56 1.005 OCDF AN J
1.021
1.025
0.899-1.101
0.000
107.76 1.000 OCDD AN J
1.013
0.76-1.02
DC NL 0:00 RO 1.10 8.47
39:36 0.85 10,793.67
1 Peak 10,793.67
4,944.64
0.996-1.004
0.000
5,849.03 1.000 13C12-OCDD
IS8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
264
-------
Page No.
01/10/98
Listing of O980033B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description. . . _ .•Why.'.Code Description.
.. -QC Log .Desc...
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:SB)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
«•• End of Report ••»
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
•CM- Below Method Detection Limit
NL-Channel Specific Noise Level
A-Peak Added
K-Peak Kept
0-Peak Deleted
T-Time Changed
M-Peak Area Changed
N-Name Changed
X-Ether Interference
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:21 01/10/98
265
-------
rila:O980033 tl-724 Acq: 6-JAN-1998 22:51:54 GC EH- Volts ye SIS 70S Hoiao:5542
303.9016 rt2 BSOB(256,30,-3.0) PXD(9,5, 3,0 .10\, 22168. 0,1. 00\,r,T) ExpiUDBSUS
TSIASSLX LABS Text :1 78 -1 81/226 TLH44376A
1001
80.
60.
40.
20.
Q
Al
A9.04X5 A1.19X6
1 A5.26E5M7.36E5
. ^_'"E5 TLyA -J\- .-A...Lj/_[_/\..
•22:00 23:00 24:00
8X6 3.6X5
A4.93X5
At a f Olrf
f\ AJi • yjcy
A « .../**•««
'•.2.9ES
'-.2.1X5
Ll . 4X5
-.7.1X4
• n nrn
25:00 ' ' ' 26\00 ' Time
rilet0980033 tl-724 Acq: 6-J3OT-1998 22:51:54 GC KI+ Voltage SIS 70S JToJ.ami6813
305.8987 T:2 B8OS(256,30,-3.0) PXD(9,5,3,0.10\,27252.0,1.00\,
TSIAOGLS LABS Text: 178-181/226 TLIt44376A
1003,
80.
60.
40.
20.
A2.4
,, ,__, A9.11E5 A1.0BE6 1
Al • 2 OEQ i n t I
A A A nA9 SSri\ f\ 1
AS. 03X5 AA A A /T/VU I / A
^ . ,w yv. „ / ^V V-./' \ ,/ \y V v VJ\y
'22:00 ' 23:00 24:00
r,T) sxptSDBSns
[!6 C5.2E5
A6.05E5
A A A2.76E5
* ; WV V-S^^^A-^A--^^,
.4.2X5
.3.1X5
.2.1X5
.1 . 0X5
'^5.-00 26:00 Tine
fila: 0980033 tl-724 Acq: 6-JAH-1998 22:51:54 GC XX* Voltage SIS 70S Soiae:4S71
315.9419 f:2 3SUS(256,30,-3.0) PKH(9,5,3, 0 .10\,1B2B4 .0,1 .00\,
TRIANGLE LABS Text: 17 8-181/226 TLIt44376A
1001
80:
60:
40:
20:
0'
r,T) Exp:NDB5US
A8.21E7 ^2.0X7
\
1
'22:00' ' ' ' ' 23^:00 ' ' '24:00
^
.1 . 6X7
.1.2X7
.7.8E6
.3.9E6
.25:00 26: 00 Tlae
F±J.e:O980033 tl-724 Acq: 6-JZS-1998 22:51:54 GC EH- Voltage SIS 70S Noiae:3S71
317.9389 f:2 BSUB(256,30,-3.0) PXD(9,5, 3,0.10\,14284 .0,1.00\,r,T) Exp-.SDBSVS
TRIANGLE LABS Text: 178-181/226 TLH44376A
1001
80:
60:
40:
20:
0'
Al.OBEB 2.6X7
\
} '
22:00 ' 23\00 ' ' 24\00
e. '
.2.1E7
-1 . 6X7
-1 . 0X7
-5.2X6
'• o . OEO
25\00 ' '26:00 Tlae
rileiU980033 tl-724 Acq: 6-JAS-199B 22:51:54 GC tt+ Voltage SIS 70S
330.9792 t:2 Exp:lO)B5US
TRIANGLE LABS Text: 178-181/226 TLIt44376A
1001
80:
60:
40:
20:
0'
22:26 23:07 23:33 23:55 _-*-,,
25:08 „_ 26±03 26:26 ^5.7X7
22:00 23:00 24:00
.4.6X7
.3.4X7
.2.3X7
.1.1X7
0.0X0
' 2S\00 ' '• ' '26:00 ' ' Mac
rn.»:0980033 tl-724 Acq: 6 -JAB- 19 9 8 22:51:54 GC EH- Voltage SIS 70S
375.8364 Ti2 SxptSDBSUS
TSIASGLE LABS Text: 178-181/226 TLIt44376A
1001
80.
60.
40:
20:
0'
22:39 1
1
23:B8
21:3721:57 1. 33\OS if 23:55
r-2.4E4
I 25:51
1 I Mil in ill 3*s^93\>57 35 jo i| ^6!je I
uJ julLuJiL i/¥AjLJlui^
' 22\00 ' ' 23:00 ' 24: 00
.1 . 9X4
.1.4E4
.9.6X3
.4.8X3
0.0X0
'25)00' ' ' 26:00 Tlae
266
-------
Tilesa980033 tl-724 Acqs 6-JAS-1998 22:51*54 SC XH- Voltage SIS 70S Xoi*esl702 (^-f'&)
319.8965 r:2 BSU3(256, 30, -3.0) PXD(7,5,3,0.10\,6808.0,1.00\,r,T) XxpiNBBSUS {Jz^fa tf
TSIAKSLX LASS Texts 178-181/226 TLH44376A
1001
80.
60.
40.
20.
A
fl
A2.87X5
\ I
/ r\ A1.JOS5 -U.440
/I Is 1 l\ Al
J V. I \i*^«. .,A.Mjrrf A
33 too 34»00 35«00
^^f—r- — i 1 • u : C'^
.~rJ~^~jT*r C9.ax4
ic^gff^^- Ajipf
•f*^^ f^O^ff^
J^
~*~9mA^- •-• — - • - —
xv JI3 77K4
.7.8X4
.5.9X4
.3.9X4
'.2.0X4
36(00 Time
Tile>0980033 tl-724 Acqs 6 -JAN- 19 9 8 22:51:54 SC D> Voltage SIS 70S Noiae:1445
321.8936 T>2 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,5780.0,1.00\,r,T) XxptXDBSUS
TSIAKSLX LABS Text: 178-181/226 TLII44376A
lOOi
80.
60.
40.
20.
. - .. n
A C-IVrl'
I) A4 . 04X5
A
/ / A2.03X5
\ J
1 \ / \ JA HIM A M-9k5" A3. 45X4
^ ^*\«/vVv W\y^^/¥*\A /Vwv^> -,,- T— A-./ vW^r VyV^V-^VyV*^*-^
23:00 24\00 35>00
C? ^? Ct 1 . 2X5
ij i * n \
A A/**- 1 / ' '
V.
A1.28X5
/y\A7 84W Mf03s4
T H/ u\JV-N-A>J^-A^s^vv\/^Vjw*>A^vvv A-*Art/^'
.9.7X4
.7.3X4
.4.9X4
-.2.4X4
36:00 Time
TU.esU980033 tl-724 Acqs 6-J7UT-1998 22:51:54 SC XH- Voltage SIS 70S Noises 8986
331.9368 Ts2 BSU3( 256, 30, -3.0) PKD(7,5, 3,0.10%, 35944 .0,1. 00\,T,T) XxpsSDBSUS
TSIANSLX LABS Texts 178-181/226 TLH44376A
1001
80:
50:
40:
30:
0:
»o
1
J
33:00 34:00 ' ' 35^00
7X7 -2.6X7
57Q*»7
• / y ft /
A*
.
.2.0X7
.1.5X7
.1 . 0X7
.5.1X6
' 0 . 0X0
' 36:00 Time
rile: OS 30033 tl-724 Acqs 6-JJOT-1998 22:51:54 SC EH- Voltage SIS 70S Koiaes4106
333.9338 Ts2 SSUB(256, 30, -3.0) PXD(7,5,3,0.10\,16424 .0,1.00\,r,T) XxpsSDBSBS
TSIANGLX LABS Text: 178-181/226 TLIt44376A
1003
so:
50:
40:
30:
o:
AI.J
y
33:00 34:00 35:00
8X8 3.1X7
US. 45X7
_
.2.5X7
.1.9X7
.1.2X7
.6.2X6
• o . oxo
'36:00 Time
Tile, 0980033 tl-724 Acqs S- JAN- 1998 22:51:54 SC XH- Voltage SIS 70S Noises 906
327.8847 T:2 BSUB(256, 30, -3 . 0) PXD(7,5, 3, 0.10%, 3624 .0,1. 00\,T,T) ElptNDBSUS
TRIANGLE LABS Text: 178-181/226 TLIt44376A
1001
80:
60:
40:
30:
oj
33:00 34 .-00 ' 35:00
A1.27X8 3.2X7
ft
/ V.
.2.6X7
J..9X7
.1.3X7
.6.4X6
O.or.o
' 36:00 Time
Tile :U9 800 3 3 tl-724 Acq: 6-JAN-1998 22:51:54 SC XH- Voltage SIS 70S
330.9792 F:2 KxptODBSUS
TSIANGLE LABS Text: 178-181/226 TLIt44376A
1001
80.
60.
40:
20:
o:
33:07 23:33 23:55 _ *<±Si 35±°* 25,23 ^, 35^03 ^6:36 r5.7r7
23\00 34:00 35:00
.4.6X7
.3.4X7
.2.3X7
.1.1X7
0.0X0
36:00 Time
267
-------
FU.», US 80033 tl-724 Acqt 6 -JAN- 19 9 8 22:51:54 SC XI+ Voltage SIS 70S Noil* t 16 80
339.8597 tt2 SSUB(256,30,-3.0) fXO(7,5,3,0.10\,6720.0,1.00\,r,T) XxptSDBSUS
TXIANGZX LABS Tert: 17 8 -181/226 TLH44376A
10K
80.
60.
40.
20.
0
A1.87X6
|l
A9.86X5 II A1.14X6
All \ II
1 A \\A9.07X5 A6.17X5
Jv-\AjJy\J^J(A* j
27\00 ' 28iOO ' ' ' 33:00 '
4.515
41.0525
(1
i A
A /
•\l\ A3. 24X5
y - V^fA: . -j^-
LJ.525
'•.2.7X5
'• 1 BfS
r '
13.024
' J0:00 ' ' Mae
Til9tO980033 tl-724 Acqt 6-JJOT-1998 22i51t54 SC XH- Voltage SIX 70S Sola* 1 2144
341.8567 n2 3SUB(256,30,-3.0) PKD(7, 5,3, 0 .10\,B576 .0,1.00\,f,T) XxptODBSUS
TSIASSZX LASS Tart: 178-181/226 TLIt44376A
1001
80.
60.
40.
20.
Al .35X6
A7.37XS
A6.47X5 A
A A \\JL3.65X5 M-05*5
\ A/ 1 A /V \ M /\A
J W ^^-^-, ,—,,-, A-I/V Y K V\^"T 1 VX l \-S V V^A ///
' ,27:00 .28:00 ' ' ' .23:00 '
J.U5
45.1325
A 1
V \A^-/V\^^v_^^^A^~. .^
12.425
11.825
Ll. 225
15.124
30:00 Tlae
rile:t»800JJ #1-724 Acqt 6-JAS-1998 22:51:54 SC JET* Voltage SIS 70S Noiae:1272
351.9000 f:2 BSU3(256,30,'3.0) PXD(7,5,3,0.10\,5088.0,1.00\,r,T) XxptSDBSUS
TRIANGLX LABS Taxt: 178-1 81/226 TLIt44376A
ion
80:
50:
40:
20:
A8.72X7 AS. 35X7 -2.4X7
ft « (T
I
_ / v_ . /
37:00 28ioO 23:00
\^_
-.1.9X7
11.427
13.425
14.725
JO: 00 ' Tlae
T±lattJ980033 tl-724 Acqt 6-JXK-1998 22t51t54 SC XI+ Voltage SIS 70S NoiaetllO
353.8970 T,2 BSUB(256, 30, -3.0) PXD(7,5,3,0.10\,440.0,1.00\,r,T) Xrp,SDB5US
TRIASSLX LABS Text, 178-181/226 TLIt44376A
1001
80:
60:
40:
20:
'""I2*7 " V"
1
11 J
_1 . 527
.1.3X7
.9.5X6
.6.3X6
.3.2X6
O.OEO
27:00 28:00 25 1 00 J0:00 Time
r±la, 0980033 tl-724 Acqt 6-JAS-1998 22:51:54 SC KH- Voltage SIR 70S
330.9792 Ti2 XxptODBSUS
TSIAJTELX LABS Tert: 17 8-181/226 TLH44376A
1004
80:
50:
40:
20:
o:
-n?5^5 26'51 a7J$? "'"wfv^ ..^^ ?5^ *$*& -r-r
27:00 ' ' 28:00 25:00 '
29t29 29:49 30*18 5.727
.4.6X7
.3.4X7
.2.3X7
.1.127
0.020
JO: 00 Time
r±le:0980033 tl-724 Acqt 6-JAK-1998 22:51:54 SCSI-1- Voltage SIR 70S
409.7974 Tt2 KxptODBSUS
ZXXAME&f LASS Text: 178-181/226 TLH44376A
1001
80:
60.
40:
20:
o:
i
27 t 20 1 2tt41
35:44 1 Jj II 28:17 t |ln| 1 lAi.JI
\$\/W\J(/iwW\r^Wi"hA^ v'"n/'
27:00 2flioO 29:00
30 07 3.7X4
29:36
k 30,33
IH yi J U lAi Jw M/CJ/^
WKv'*' \/VW Mr ^ » » V iMr f
.J.024
.2.224
.1.524
.7.4X3
0.0X0
JO: 00 Tt«e
268
-------
fHaiasaoOJJ #1-724 Acq: S-JMf-lSSa 22:51:54 SC EI+ Voltage SIS 70S Koi.ae:142
355.8546 T:2 3SOB(256,30, -3.0) PKD(S,5,3,0.05\,568.0,1.00\,r,T) ExpittoBSUS
XSIAHGLS LASS Text.-178-181/226 TLH44376A
10n A4.19XS
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
ril«iU9B0033 tl-724 Acq: 6-JAK-1998 22:51:54 GC EH- Voltage SIX 70S Soia»:112
357.8516 T:2 SSUB(256,30, -3.0) PKD(5,5,J,0.05*,448.0,1.00\,r,T)
TXIA1KLX LASS Text: 178-181/226 TLH44376A
100\ A4.42XS
80.
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
Tile:U980033 tl-724 Acq: 6-JKK-1998 22:51:54 GC EI+ Voltage SIS 70S Noises 108
367.8949 f:2 BSUB(256,30, -3.0) PXD<5,S,3,0.05\,432.0,1.00\,T,X) S*p:lO}B5US
ISIANSLS LASS Text:178-181/226 TLI»44376A
100* AS.10X7
80.
60.
40.
20.
7.8SX6
0.0X0
Tine
1. 6X7
'.1.3X7
.9.7X6
'.6.5X6
.3.2X6
27i48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rJULe:0980033 tl-724 Acq: 6-JMT-1998 22:51:54 GC EI+ Voltag» SIB 70S S6iaa>95
369.8919 F:2 BSUB(256,30, -3.0) PJO3(5,5,3, 0.05%,380.0,1.00\,r,T) ExpiNDBSUS
ISIAKSLE LABS Tart: 178-181/226 TLIt44376A
A3.45X7
0.0X0
Tine
80.
eo:
40.
20.
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24' 29:36 29't48 30166 3o':12 30:24
File:O980033 tl-724 Acq: 6-JMT-1998 22:51:54 GC EI+ Voltage SIX 70S
330.9792 T:2 ExpiHDSSDS
TSIAXSLE LABS Tert: 178-181/226 TLIt44376A
28i_42 29:29 29:41) ^-^^-ZS^iSL^—
.8.6X6
.6.4X6
.4.3X6
J1.1X6
0.0X0
Time
1001
80.
60.
40.
20.
0.
r5.7X7
.4.6X7
.3.4X7
.2.3X7
kJ-iB7
27:48 28: 28:12 28:24 28:36 2a':48 29:00 29\12 2»\24 29\36 29:48
30:12 3024
0.0Z0
WJM>
269
-------
rile:O980033 tl-385 Acq: 6-JJOT-1998 32:51:54 SC XI+ Voltage SIS 70S Boise:5220
373.8208 Tt3 SSUB(256r30, -3. 0) PKD(7,5,3, 0.10\,208SO .0,1.00\,f,T) XzptSDBSUS
TSIAHGLX LABS Text: 178-181/226 TLH44376A
1003
00:
sol
40J
A1.34X6
A1.32X6
A6.S9XS
A1.49X5
A7.52XS
31tl2 31:24 31:36 31:48 32:00 32tl2 32:24 32s36 32:48 jjloo' 33112'33:24'33t36'jj;40'
ril»:0980033 tl-385 Acq: 6-JXK-199B 22:51:54 ISC XH- Voltage SIS 70S Soi.au-.3760
375.8178 T:3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,15040.0,1.00\,r,T) XxptSDBSUS
XXIASSLX LABS Tazt:178-181/226 TLH44376A
1003, A1.J.4X6
A5.76E51
AS.14X5
00J I AS. 72X5
50:
40:
o:
3l'iOO 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
r±le:0980033 tl-385 Acq: 6-JRS-1998 22:51:54 GC XH- Voltage SIS 70S So±aet3388
383.8639 T:3 BSVB(2S6,30,-3.0) PXD(7,S,3,0.10\,13S52.0,1.00\,T,T) Xxp:SDB5US
TSIAHGLX LABS Tert: 178-181/226 TLH44376A
1003k A3.72X7 A3.58X7
A8.25X4
80.
40:
70:
A2.57X7
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
rile:U980033 tl-385 Acq: S-JAfT-1998 22:51:54 GC XH- Voltage SIB 70S Noise12677
385.8610 T:3 BSVB(256,30,-3.0) PXD(7,5,3,0.10\,10708.0,1.00\,r,T) Xxp:SDB5US
TBIAHSLX LABS Tart* 170-1 SI/775 TLIt44376A
1001 A7.62X7 A7.} X7
00:
50:
40:
70:
OJ
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
'LLo,0980033 H-385 Acq: 6-J3UT-1998 22:51:54 GC XH- Voltage SIS 70S
392.9760 T:3 XxptXDBSUS
TSLAKSU: LABS Text: 178-181/226 TLH44376A
100\ 31^07^:17 _^4JLJL ._ jj,« 5j.—__ J3^* 3a/*24 J^illL- - _J-U?8 33:34 33:46
00;
50:
40:
70:
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
Tile,0980033 tl-385 Acq: 6-J3UT-1998 22:51:54 GC XH- Voltage SIS 70S
445.7555 T>3 KxpiHDBSUS
XRIAHGLX LABS Tmrt: 178-181/226 TLH44376A
31 23
32:14
_4.J*5
Lj.4r5
'•.2.6X5
'.1.7X5
'•.a.5X4_
'.O.OEO
3.5X5
.2.8X5
.2.1X5
J..4XS
.7.0X4
0.0X0
T±ae
-2.6X7
'•.2.1X7
'.1.6X7
-.1.1X7
'.5.3X6
.0.0X0
T±ae
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
270
-------
389.8156 f:3 BSOB(256,30, -3.0) PaO(7,5,3,0.10\,10188.0,1.00\,r,T) XxptSDBSUS
TXIASGLX LABS Text: 178-181/226 TLH44376A
100.
80.
60.
~~40.
20.
\
A6.31X5
A
fl
/ A2.65X5
"• T — A ~" ""
A1.20X5 \
j\ \ ./\ A8.73X4 A1.23X5 ".5™ ., „„
J\t. . . M. - 'V Y L^ ^ _rV,vAT
Tft* . tf OJV« r Si AA*A
3l':36 ' '31:48 32:00 32:12 32:24 32:36 '32:48 ' '33:00 '33': 12 '33:24 33
-1.9X5
.1 . 6X5
.1.2X5
.7.8X4
.3.9X4
36 Tiae
r±la, 0980033 tl-385 Acq: 6-JAJT-1998 22:51:54 GC XX* Voltage SIX 70S B6iae:2616
391.8127 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\f 10464 .0,1. 00\,r,T) XxpsBDBSOS
TXIASGLX LABS Text: 178-181/226 TLH44376A
1001
80.
60.
40.
20^
A4.35ZS
A
I
1 A1.91ES
1 A,
A1.26X5 1 \ \ ,. ,
M 1 1 SCJ \ A1-l>
iCvc
'5X5 A1.06X5
1 \ / T A V V A ' N\ M3 79fSf24 32:36 32':48 ' 33\00 ' '33:12 ' ' 33\24 33:36 Time
271
-------
rile:U980033 tl-545 Acq: 6 -JAN- 19 9 8 22,51:54 SC EH- Voltage SIS 70S Hoiae,3367
407.7818 f:4 BSUB(256r30,-3.0) PXB(7,5,3t0.10\r13468.0,1.00\,T,T) XxpsSDBSHS
TRIANGLE LABS Text -.178-181/226 TLH44376A
100.
80.
60.
40.
20.
i Al . 60X6
A
/ \
/I
/ 1 A4.91XS
/ 1 AJ.aO*5 A ....._.._. _ A3. 69X5
J X — ~ -S \-^J V_ ^__ .^-A-^^.
-5.2X5
.4.1X5
.3.1X5
.2.1X5
.1 . 0X5
35,00 35', 12 35,24 35:36 35i4B 36\00 36', 12 36', 24 36:36 36\48 37\00 Time
T He > 09 800 3 3 tl-545 Acq: 6 -JAW- 19 9 8 22:51:54 SC SI+ Voltage SIS 70S Soiae:4650
409.7789 f:4 BSUB(256,30,-3.0) PKD(7,5, 3, 0 ,10\,18600 .0,1 .00\,r,T) XxptSDBSOS
TSIASSLX LABS Texts 178-181/226 TLIt44376A
1001
80.
60.
40.
20.
~~
A1.B2E6
A
A
j 1 A3.9BE5
I \ ,-, /\ 47 t-jfff
J V* J~ V / \ ^^V.
-4.9X5
'.3.9X5
.2.9X5
12.0X5
.9.BE4
'35i6o' ' 35\12 35:24 3S':36 3S':48 36'tOO ' 36\12 '36:24 ' ' 36:36 36:48 37'tOO Tiae
rila, 0980033 tl-545 Acqt 6-JAS-1998 22:51:54 SC EI+ Voltage SIS 70S Noiaes4667
417.8253 Tt4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,18668.0,1.00\,r,T) Exp:SDB5US
TSIAHSZX LASS Texts 178-181/226 TLH44376A
1003,
80-
60:
40:
20:
0:
A2.02E7
1 \ A1.36E7
1 \ - /N
A
\ / V
/ v — y v__
-4.9E6
'.4.0E6
''.3.0E6
.2.0E6
.9.9X5
O.OEO
35\00 35:12 35:24 35:36 35\48 36:00 36:12 36:24 36:36 36:48 37\OQ Time
Tile, U9 800 3 3 tl-545 Acq, 6-JJOT-1998 22:51:54 SC EI+ Voltage SIS 70S Soiae:5092
419.8220 r,4 3SOB<256,30,-3.0) PXD(7,5,3,0.10\,20368.0,1.00\,r,T) Exp:HDB5VS
TSIABGLX LABS Text, 178-181/226 TLIt44376A
1001
ao:
60:
40:
20:
o:
A1.JSS7
A
A
A3.29E7
A
{ \
I \ — / v —
-1.2E7
.9.8E6
-7.3E6
-4.9E6
-2.4E6
O.OEO
35:00 35:12 35:24 35:36 35:48 36\00 36:12 36:24 36:36 36:48 J7sOO Tine
Tile:U980033 tl-545 Acq: 6-JZS-1998 22:51:54 SC EH- Voltage SIS 70S
430.9729 Tt4 ExpiSDBSUS
TRIANGLE LABS Texts 178-181/226 TLIt44376A
1004
so:
60:
40:
20:
o:
34:59 35, 07 35: 17 ^^35:33 35:41 35,55 36:22 36,37 36:46 36/^t
~^-^s*-v-^^ ^
.1 . 8X7
-1.5E7
-L.1X7
.7.3X6
.3.7X6
O.OEO
35:00 35\12 35:24 35:36 35:48 36\00 36', 12 36:24 36:36 36:48 37:00 Time
Tile ,0980033 tl-545 Acqt 6-J3UT-1998 22,51:54 SC EH- Voltage SIS 70S
479.7165 r, 4 Eip,SDB5U3
TRIABSLX LASS Text: 178-181/226 TLH44376A
10 0\
ao:
60:
40:
20:
oj
35:09
I
I "j"
•JA/^A /* I/ ^A A rAx A AA/ /^A A/\A^A ^V\A\AA A/AA./VA. A A^A^yv
.3.5E4
.2.8X4
.2.124
.1.4X4
.6.9X3
0.0X0
35:00 ' 35\12 35:24 35\36 35:48 36\00 '36:12 ' ' 36\24' ' ' 36,36' ' '36:48 37:00 Time
272
-------
rULe:U98Q033 tl-545 Acq: o-JAa-iyyo 44:31:31 (.c EI+ voltage SIS 70S noiaoslQSo
423.7766 T:4 BSOB(256,30, -3.0) PXO(7,S,3, 0.10\f 4384.0,1.00\rr,T) KxpiNDBSOS
TSIAOSLX LASS Taxts 178-LSI/326 TLH44376A
1001 A3.89X5
-1.1X5
35:12 35ia 35:24 35»30 35i36 35i42 35i48 35S4 ffsOo 36:06 36:12 36ia 36124 36t3o
rll»,0980033 tl-545 Acq: S-J2JT-1998 22t51»54 SC XX+ Voltayu SIS 70S Koiaotl338
425.7737 T>4 BSO3(256,30,-3.0) PXD(7,5,3,0.10\,53S2.0,1.00\,T,T) SzpiXDBStrS
TBIASGLS LASS Taxt 1178-181/226 TLH44376A
1004
so:
0X0
Time
^9.3X4
'.7.4X4
0X0
Time
35:12 35tl8 35:24 35>30 35:36 35:42 35:48 35:54 36:00 36:06 36:12 36:18 36:24 36:30
r±la:U980033 tl-545 Acq: 6-JHT-1998 22:51:54 SC BI+ Voltage SIX 70S Hoiae:4692
435.8169 T:4 BSOB(256,30,-3.0) PXD(7,S,3,0.10\,ia76a.O,1.00\,T,T) XxptXDBSUS
XRIANGLX LABS Text: 178-181/226 TLH44376A
A3.f6E7 -8.9X6
80.
60.
40.
20.
.0.0X0
35:12 35:18 35:24 35',30 35:36 35',42 35',48 35:54 36:00 36:06 36', 12 36-18 36:24 36:30 Tiae
r±la:U980033 tl-545 Acq, S-JKK-1998 22:51:54 SC XI+ Voltage SIS 70S Koine:490L
437.8140 Ti4 BSttB(256,30,-3.0) PXZ>(7,5,3,0.10\,19604.0,1.00\,r,T) Xzp:SDB5US
TSIASSLE LABS Text: 178-181/226 TLIt44376A
1001 A3.60X7
80.
60.
40.
20.
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36,06 36:12 36-18 36:24 36:30
File,0980033 tl-545 Acq: 6-JUT-1998 22:51:54 GC KZ+ Voltaga SIS 70S
430.9729 r>4 KzpiKDBSUS
TBIAHGZX LABS Text,178-181/226 TZIt44376A
1001
80.
60.
40.
20.
0.
35,17
35i
36,22
8.9X6
.7.1X6
.5.3X6
.3.6X6
^1.8X6
'.0.0X0
Tim»
-1.8X7
.1.5X7
.1.1X7
.7.3X6
.3.6X6
35: 12 35:18 35:24
' 35\ 36 '
' 35',48 ' 3s':54
' jififlff ' 36',12 '
' 36:24 ' 36\36
0.0X0
Tia
273
-------
rllaiOSS0033 tl-545 Acqt S-JAS-1998 22t51i54 SC EH- VoltigtJ 5X2 70S KoiaoilJSJ
441.7438 f.4 3303(356,30, -3.0) tXS(7,5,3,0.10\,5052.0,1.00\,T,'l) SxptXDBSOS
TSIANSLX LABS Toxtt 17 8-181/226 TLXt44376A
36i00 37i00 38:00 39tOO
Til»tU980033 tl-545 Acqt 6-JXX-1998 22:51,54 SC XH- Voltage SIS 70S Xoiae,1234
443.7399 ft4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,4936.0,1.00\,r,T) XxptODSSUS
LASS Tort: 178-181/226 TLH44376A
35,00 36,00 37:00 38:00
rU.e,aSB0033 tl-545 Acqt 6-JXM-1998 23:51,54 SC XI+ Voltaffe SIS 70S
430.9729 r>4 XrptSDBSVS
TRIANGLE LASS Tart, 178-181/226 TLH44376A
39100
40tOO
T±ae
-1.7S5
.1.6KS
11.4B
11.2X5
'-.1.0X5
.8.7X4
'.7.0X4
.5.2X4
.3.5X4
\1.7E4
'.0.0X0
41i00 Tine
100}
90\
sol
7ol
60\
sol
401
301
201
101
oi
35t26
36158
34143
38s 40
40:34
35tOO 36>00 37:00 38tOO
'ilaiU980033 tl-545 Acqt 6-JUT-1998 22:51:54 SC XI + Voltage SIS 70S
513.6775 Ti4 XxptBDBSUS
TSIANGLX LASS T9It.il78-L81/226 TLH44376A
100* 37148
901,
35>36
39100
40:00
-.1.8X7
11.6X7
11.5X7
11.3X7
-.1.1X7
19.2X6
.7.3X6
.5.5X6
''.3.7X6
11.8X6
.0.0X0
41100 Mae
38t37
39135
35100
36100
37100
38iOO
39100
40,00
41100
274
-------
Hle:09B0033 91-545 \cq: t>-JA*f-1999 23:51:54 tt JST4- Volt*?* 4IB 703
457.7377 Tt4 BSUB(256,30, -3.0) PXS(7,S,3,0.10\,116.0,1.00\,r, T) SxpiSDBSOS
TSIAVGLX LASS Text: 178-181/226 TLH44376A
100\ Al. QOX6
80.
SO.
40.
20.
39s30 39:36 39:42 39:48 39:54
r±l»:0980033 tl-545 Acq: 6-JZN-1998 22:51:54 GC EC+ Voltage SIX 703 Koiae:696
459.7348 Tl4 BSUB(256,30,-3.0) PXD(7,5r3,O.U\r2784.0,1.00\,r,X) XzpiBDBSUS
TBIABGLX LASS text: 178-181/226 XLH44376A
loo*
80.
60.
40.
20.
40:00
-2.1X5
.1.7X5
.1.3X5
.8.-5X4
.4.3X4
.0.0X0
40106 Tla«
39>30 39:36 39:42 39:48 39:54 40:00
rile:O980033 tl-545 Aoj: 6-JAN-1998 22:51:54 GC XI+ Voltage SIS 70S Soise:2466
469.7779 T:4 BSUB(256, 30,-3.0) PXD( 7,5,3, 0.10%,3864. 0,1. QO\,T, T) SxpiUDBSOS
TRIASGLX LABS Taxt:178-181/226 TLIt44376A
100\ A4.$4E7
80.
60.
40.
20.
-2-.LB5
'.1.6X5
.1.2X5
".8.2E4
'.4.1X4
40 06 Time
-9.4E6
'.7.5X6
•.S.7E6
.3.8X6
J..9X6
39:30 39:36 39:42 39:48 39:54 40:00
File:0980033 tl-545 Acq: 6-JAN-1998 22:51:54 GC SH- Voltage SIS 70S lToiae:2242
471.7750 T:4 BSUB(256,30,-3.0) Pia>(7,5,3,0.10%r8968.0,1.00*,rrT) Xzp:NDBSVS
XSIAXGLX LABS Text:178-181/226 TLIt44376A
J004 AS.8JX7
^_ .0. 0X0
40106 Time
39:30 39:36 39:42 39:48 39:54
T±le:O980033 tl-545 Acq: 6-JJUt-1998 22:51:54 GC XH- Voltage SIS 70S
430.9729 Fi4 ElpiKDBSUS
XXIANSLX LABS Tort: 178-181/226 TLH44376A
100\ 3?jJ9 39*43 39,47
40:00
-.1.1X7
.8.9X6
.6.7X6
.4.4X6
.2.2X6
.0.0X0
40 06 T±ae
80.
60.
40.
20.
0.
-1.7X7
.1.3X7
.1.0Z7
.6.7X6
.3.4X6
39:30
39:36
39:42
39:48
39:54
40:00
.0.0X0
40:06 TJJM,
275
-------
CD
r-
CM
Peak Locate Examination: 6-JAN-1998:22:50 File:U980033
Experiment:NDB5US Function:2 Reference:PFK
-------
Sample Text:178
100%
80J
60 j
40J
20_
0
ile:U980033 ttl
303.9016 F:2 Exp:NDB5US
CM
-724 Acq:6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
-181/226 TLI#44376A File TextrTRIANGLE LABORATORIES, INC.
1 ' I ' '
23:30
T—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r-
123:36 23:42 23:48 23:54 24:00
T
T
24:06 24:12
1 ' i ' ' '
24:18
24:24 24:30
File:U980033 ttl
305.8987 F:2 Exp:NDB5US
Sample Text:178
lOOi
80J
60J
40J
20J
OJ
-724 Acq: 6-JAN-1998. 22:51:54 GC EI+ Voltage SIR 70S
-181/226 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
1 ' ' I ' '
23:30
! ' I ' ' ' ' ' I ' '
23:36 23:42
1 ' I ' '
23:48
"i—i—i—i—i—i—i—i—i—r—i—i—i—i—|—i—i—i—i—i—i—i—r
23:54 24:00 24:06 24:12
1 ' I ' '
24:18
24:24
-i—i—i—i—i—r
24:30
1.9E5
.1.5E5
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.7.4E4
.3.7E4
.O.OEO
Time
2.1E5
1.7E5
1.3E5
8.5E4
4 .3E4
O.OEO
Time
File:U980033 #1-724 Acq: 6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
315.9419 F:2 Exp:NDB5US
Sample Text:178-181/226 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%,
80J 23:35
60 j
40_
20_
ol
24:13
23:51
23:30 23:36 23:42 23:48 23:54 24:00 24:06 24:12 24:18 24:24 24:30
.5.0E5
.4.0E5
.3.0E5
.2.0E5
.9.9E4
.O.OEO
Time
-------
NJ «, (Tl CO O g)
O O O O O 3
I , . . I , . . I , . , I , , , BPT3
1 ' I' • • I' • • I ' ' ' I • • • I
O rf* \O M . M tO
.,.,..,..,.,
278
-------
File:U980033 Sl;-385 Acq
373.8208 F:3 Exp:NDB5US
Sample Text: 178J-181/226
100%
32i:24
File:U980033 #lj-385 Acq
375.8178 F:3 Exp:NDB5US
Sample Text: 1781-181/226
100%
6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
A6.60E5
32:30 32:36 32:42 32:48
6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
TLI844376A File Text:TRIANGLE LABORATORIES, INC.
A4.87E5
32:54
32:24
ile:U980033 #lf385 Acq:
383.8639 F:3 Exp:NDB5US
Sample Text:178r181/226
100%
80j
60_
40_
20_
0
32:30 32:36 32:42 32:48
6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
TLI»44376A File Text:TRIANGLE LABORATORIES, INC.
32:36
32:24
32:30
32:36
-i 1 < r
32:42
32:48
32:54
33:
LO.OEO
00 Time
i 1 1 r—i 1 1 1
LO.OEO
00 Time
1.8.4E6
L6.3E6
L4.2E6
L2.1E6
LO.OEO
33:00 Time
-------
ile:U980033 #1-385 Acq
389.8156 F:3 Exp:NDB5US
Sample Text: 178;-181/226
100*.
6-JAN-1998 22:51:54 GC EI + Voltage SIR 70S
TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
A1,35E5
i — i — | — i — i — i — i — i — I — i — i — i — i — i — r
32:36 !32:42 32:
File:U980033 #1-385 Acq:
391.8127 F:3 Exp:NDB5US
Sample Text:178-181/226
100%,
i — i — i — i — i — I — i — i — i — r1! — I — r-"i — i — i — i — i — i — i — i — i — i — f i i — i — i — i — r-1 — i — i — i — i — I — i — i — i — i — i — p— i — i — i — i — r"-| — n — i — I — i — I — i — r
48 32:54 33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42
6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
TLI#44376A File Text : TRIANGLE LABORATORIES, INC.
A1.33E5
48 32:54 33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42
OJ
32:30 32:36 !32:42 32:
File:U980033 #lj-385 Acq:
401.8558 F:3 Exp:NDB5US
Sample Text:178-181/226
100*.
O.OEO
Time
.3.4E4
.2.7E4
.2.0E4
.1.4E4
.6.8E3
O.OEO
Time
6-JAN-1998 22:51:54 GC EI+ Voltage SIR 70S
TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
33:07
32:30 32:36 32:42 32
48 32:54 33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42
O.OEO
Time
O
CO
C\J
-------
TLI Project
lient Sample:
C
44376A
178-181/226
Method 23 TCDD/TCDF Analysis (DB-225)
^ Analysis File: P980101
Client Project
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight
GC Column:
Gulp Aluminm
M23TRAIN
194-59-15B-D
1.000
n/a
DB-225
n Alloys
Date Received: 12/17/97
Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Dilution Factor: n/a
Blank File: P980094
Analyst JM
Spike File:
ICaJ:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
RT
2,3,7,8-TCDF
0.03
0.78
23:06
B
tleirjial Standard
.actimtts.
Ratio
RT
13Cir2,3,7,8-TCDF
3.1
76.5
40%- 130%
0.77
23:05
^Recovery Standard
Ratio
RT
Flags
I3C,2-U,3,4-TCDD
0.80
21:54
Data Reviewer
01/09/98
Page 1 ol"
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1601/09/98
281
-------
Initial
..Date.
Data Review By:
Calculated Noise Area:
O.S3
The Total Area for each peak with an ion abundance ratio outside
ratio liaits has been recalculated according to aethod requirements.
Page No..
01/07/98
.Listing of P980101B,dbf __
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Onit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC NL 0:00
18:27
DC SN 18:40
19:27
19:35
19:42
19:53
DC SN 20:09
20:19
20:28
20:37
20:47
21:09
DC SN 21 : 21
21:36
DC SN 21:42
21:51
22:06
DC SN 22:13
DC SN 22:20
22:31
DC SN 22:40
22:58
23:06
23:19
23:36
23:44
24:31
DC SN 25 : OS
DC SN 25:07
DC SN 25:15
304-306 20 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 21:24
DC WL 21:36
DC WL 21:51
23:05
23:42
DC WH 25:09
316-318 2 Peaks
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
.65-0.89
0.71
1.03
0.71
0.63
1.31
0.92
0.80
0.74
0.78
0.56
0.71
1.00
0.70
0.68
0.99
0.89
1.29
0.66
0.19
0.33
0.59
0.38
0.81
0.78
0.83
0.72
0.50
0.54
1.00
1.25
0.62
65-0.89
0.96
2.31
0.65
0.81
0.77
0.93
0.64
1.59
3,35
0
5
2
5
3
2
7
3
12
3
.70
.01
.50
.84
.00
.30
.84
.10
.75
.86
23.52
1
2
1
3
1
3
1
5
2
9
.94
.18
.85
.03
.33
.43
.35
.28
.17
.70
1
3
1
3
1
4
2
7
2
13
0.792-1.101
0.000
.89 0.799
.48
.41
.30
.67
.41
.43
.47
.18
.82
0.74
8
.32
4
.63
4
.70
1.51
4.27
6.11
3
2
.11
.44
2
3
.41
.67
0.14
0.44
6.
34
2
.76
4
.66
0.48
5.15
9.
7.
8.
5.
3.
0.
0.
1.
134.
49
20
00
77
17
27
35
10
59
2,
4.
.31
.17
3.26
3.35
2.51
1.38
2
5.
3,
4,
.84
.32
.94
.65
4.99
2.56
0
0
0
.809
.843
.848
0.853
0.861
0
.873
J
J
J
J
J
0.880
0.887
J
0.893
0.900
J
0.916
0.925
0.936
0.940
0.947
0.957
J
J
0.962
0.968
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
975
982
995
001 2378 -TCDF AN
010
022
028
062
087
088
094
J
J
J
J
0.957-1.043
2.
0.
10.
34.
1,333.
3.
11.
1,337.
66
57
56
03
50
77
84
27
579.
1.
79
99
753.
2.
71
13
0.
0.
0.
0.
1.
1.
1.
000
927
936
947
000 13C12-2378-TCDF ISO
027
090
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:39 01/07/98
282
-------
Page No.
01/07/98
Listing of P980101B.dbf
Matched GC Peaks / Ratio /
Ret. Tiae
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-TCDD
333-334
332-334
DC
DC
DC
DC
DC
ML
SN
WH
WH
WH
4
0:
20:
21:
21:
22:
22:
24:
24:
24:
00
29
37
54
41
52
09
29
58
n
RO
DO
RO
RO
RO
----- ADOVI
65-0.89
1.
0.
0.
0.
0.
0.
1.
0.
1.
84
48
80
80
74
83
01
39
24
Peaks
:: n_uc / iv-uu roX-LOwa ----------------------
0.908-1.093- . .. ..
1,
2,
1
5
913
255
13
1
1
3
2
187
.20
.20 2.26
.31 406.07
.82 559.54
.35 5.69
.06
.59
.33
.99
.68
0.
4.69 0.
507.24 1.
696.28 1.
7.66 1.
1.
1.
1.
1.
000
948
000
013
049
058
117
133
155
13C12-2378-TCDD 131
13C12-1234-TCDD RSI
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
• •• End of Report
WL-Below Retention Tiae Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
303.9016 Szp ,00225
TBIANSLS LABS Texts 178-181/226 TLH44376A
1004 23:06
95.
90.
85.
80.
75.
70.
65.
60.
55.
50.
45.
40.
35.
30:
25.
15:
10:
5:
o-
rUa
315.
TRIA
1001
95:
90:
85:
80.
75:
70:
65:
60:
55:
50:
45.
40.
35.
30.
25.
20.
15:
10:
5:
I
1
1 i
i
i
J
T ._
1 :"
"'" ,
.
i 1 \3i
i in «i in
T
in
w>y »
1
'•"
i
U 33:55 \
T 1 Ml 21:48 I 24:15 L
F 1 M ilnl ^ik T-"J\
V W wms> WMMlU/i
^^(.u)"-^^
j^C-c ' ._ l- T*»
T
22:36 22:48 23': 00 23:12 23:24 23': 36 23:48 34:00 24:12 24:24 24:36' 24\ 4 8 ii.-OO ' '25,12 ' 25:24
,P980101 H-923 Acq:7-JZa-9a 05:43:24 XI+ Voltage 5X5 70P
9419 Xxp,DB225
BGUS LAB3 Tart: 178-181/226 TLH44376A
23:05
I
n
23\36 22:48 33': 00 23': 12 23': 24 23:36 23:48 34:00 24:12 24\24 24:36 24:48 25:00 25:12 25:24
-.1 . 6E4
Lt.SM
\1.4X4
'•.1.3X4
.1.3X4
'\.I~.~2X4~
ll.lX4
'•.1.0X4
.9.4X3
.8.7X3
.7.9X3
.7.1X3
'-.6.3X3
.5.5X3
•4.7X3
.3.9X3
'•.3.1X3
-.2.4X3
JL.6X3
'-.7.9X2
' 0 . 0X0
T±me
-1.6X6
'•.1.5X6
'.1 . 4X6
.1.3X6
.1.3X6
.1.2X6
'-1.1X6
'.1 . 0X6
-9.5X5
.8.7X5
-7.9X5
.7.1X5
.6.3X5
.5.6X5
.4.8X5
.4.0X5
.3.2X5
.2.4X5
.1.6X5
.7.9X4
.0.0X0
Time
284
-------
\Kla:P9B0101 41-923 Acq:J-JAH-SB 05:43:24 EH- Voltay* as 70P
303.9016 BSUB(2S6,30,-3.0) PXD(5,3,1, 0.10\r1313.0,Q.OQ\,r,T) Xlp:DB22S
TBIANGLX LABS Tart.-178-181/226 TLH44376A
A9 0X4
A4.17X4
A3.35X4
A3.. 38X4
A4.83S3
19:00 20:00 21:00 22:00 23:00 24:00
ttla:P9S0101 tl-933 Aeqi7-JJOt-98 05i43t24 XH- Voltayu SIX 70f So±f»i46S
305.8987 BSUa(256,30,-3.0) PXD(S,3,l,0.10\,1860.0tO.OO\tr,r) KxptDB225
XSIAHGLX LABS Text: 178-181/226 TLH44376A
100* A1.38XS
35100
19:00 20:00 21:00 22:00 23:00 24:00
rila:P980101 tl-923 Acq:7-JJUT-98 05:43:24 XH- Voitago SIX 70V Stiiao:720
315.9419 BSUB(256,30,-3.0) PKD(S,3fl,0.10\,28aO.O,0.00\,r,T) XxptDB225
TSIANGLX LABS Tart: 178-181/326 TLH44376A
1004 AS OE6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23 0 24:00
rl2e:P980101 tl-923 Acq: 7-JZN-9S 05:43:24 XI+ Voltaye SIS 70P Ooiae:750
317.9389 BSUB(2S6,30,-3.0) PXD(S,3,l,0.10\,3000.0,0.00\,r,T) Xxp:DB225
XRIANGLX LABS Text: 178-181/226 TLIt44376A
100\ A7.54X6
80.
60.
40.
20.
0.
25:00
19:00 20:00 21:00 22,00 23:00
rila:P980101 tl-923 Acqi7-JJUT-9S 05:43:24 XX* Vbltaga SIS 70P
375.8364 Xxp:DB225
TXIAHSLX LABS Ttortt 173-131/226 TLIt44376A
100*18:32 .
24,00
25:00
.1.9X4
.1. 6X4
1.2X4
,7~.8X3~
.3.9X3
0.0X0
T±m,
.1. 6S6
.1.3X6
.9.5X5
.6.3X5
3.2X5
.0.0X0
Tiaa
.2.0X6
.1.6X6
1.2X6
8.2X5
.4.1X5
0.0X0
Tine
19:00
20:00
21:00
22:00
23:00
24:00
25:00
285
-------
rU.»:P9BUlUl tl-923 Acqi7-JZir-98 05,43,24 EI+ Voltage SIS 70P Hoj.t«,321
319.8965 BSU*(256,30,-3.0) PXD( S ,3,1,0.10\, 1284.0,0.00\rr,P) Xxp,DB225
XSIAXSLX LASS Text, 178-181/226 XLH44376A
100* A2.66X4
20:00 21', 00 22,00 23', 00
riletP980101 91-923 Acqt7-JUT-98 05,43,24 ZT+ Voltaya SIX 70P Soit»,375
321.8936 BSU3(256,30,-3.0) PXD(S, 3,1,0.10\,1500.0,0.00\,r,T) Xxp,DS22S
TBIASGLX LASS Texts 178-181/226 TLH44376A
100\ .
24100
20', 00 21,00 22',00 23:00
\T±2aiP980101 tl-923 Acq,7-JJUt-98 05,43124 XI+ VoltAge SIS 70P Soiae,417
1327.8847 SSUS(256,30,-3.0) PXD(5,3,l,0.10\,1668.0,0.00\,rrT) Xxp:DS225
TSIABSLX LASS Texts 178-181/226 XLH44376A
AB.56X6
80.
60.
40.
20.
20', 00 21,00 22,00 23', 00
r±letP980101 tl-923 Acq,7-J7Ut-9B 05,43,24 SI+ Voltage SIS 70P SOia«,623
331.9368 SSUS(256,30,-3.0) PXO(5, 3,1, 0.10\f 2492.0,0.00\,rrf) Erp,DS225
TXIANGLZ LASS Text, 178-181/226 TLIt44376A
100} AS.f0X6
80.
60.
40.
20.
A4.06E6
20', 00 21', 00 22', 00 23', 00
rlle,P980101 tl-923 Acq,7-JXN-98 05,43,24 KH- Voltaye SIS 70V SolBe,338
333.9338 SSUS(256,30,-3.0) PKD(5,3,1,0.10\,1352.0,0.00\,F,r) XxptDS225
TXIAIKLX LABS Tortt 178-181/226 TLH44376A
10 0\ A6.96S6
801
601
401
201
0.
AS.07X6
24100
24100
24100
'.0.0X0
25100 Tim.
25,00
0.0X0
rise
-2.SE6
'.2.0E6
'.1.5X6
".9.8X5
'.4.3X5
.0.0X0
25100 T±jn
rl.SX6
J..2X6
.9.1X5
.6.1X5
.3.0X5
'.0.0X0
25100 Ha,
-1.9X6
'.1.5X6
11.1X6
'.7.6X5
'3.8X5
20100
21:00
22:00
23:00
24:00
'.0.0X0
25,00 Urn,
286
-------
rile:P980101 tl-923 Acq:7-JAJf-98 05:43:24 XI+ Voltage SIS 70P
303.9016 Xxp:DB22S
TRIAKSLX LASS Text: 178-181/226 TLH44376A
1001 21 -.09 21 1 36
80.
60.
40.
20.
0
Tilt
315.
TSIt
lOOi
80.
60.
40.
201
Tile
319.
TSIA
1003
sol
60.
40:
20:
o-
rile
331.
TRIA
1004
80:
«o:
40:
20:
o-
Tile
292.
TRIA
100}
80:
50:
40:
20:
o:
File
330.
TRIA
1003
so:
60.
40:
20:
o:
"I" \ 33,06
A A a/uXAlrl lnTALJK---r --
jH^jiA^iJM/ u/iL-A/ iiir vV",j UuJvL/Y 11 /y\Aj\/\»j 3~»^^K%^**»"'<\^»<1V'"*TV1^<%*^^ Hp^^v.nM^^-wY'
15:00 20:00 21:00 22:00 2J: 00 24:00 25<00
IP980101 fl-923 Acq:7-JJur-98 05:43:24 EH- Voltage SIS 70P
9792 Exp:DB225
NGLX LABS Text 1 178-181/226 TLH44376A
19:0519:3420:00 20:37 21:17 21:59 .32:50 23t33 24:05 24:40 25:18 .
/•^>|.y*VT^<••'•YSfV••>^/Yl^vlAYv"'%tyf>A^y'^^
19', 00 20:00 21> 00 22', 00 23:00 24': 00 25:00
2.J1T4
.1 . SSI
.1.4X4
.9.1X3
.4.6X3
0.0X0
TiMe-
-1 . 6X6
ll.3X6
19.5X5
-.6.3X5
-.3.2X5
'• o.oxo
Time
-1.4X4
'.1.2X4
-.8.7X3
'-.5.8X3
-.2.9X3
'•o.oxo
Time
-1.5X6
.1.2X6
.9.1X5
-.6.1X5
.3 . 0X5
0 . 0X0
Time
,.6.0X6
.4.8X6
.3.6X6
.2.4X6
.1.2X6
0.0X0
Time
.4.9X6
.3.9X6
.2.9X6
.2. 0X6
.9.8X5
0.0X0
Time
287
-------
Ref, tass 292.9825 Peak top
Height 1,85 volts Span 286 ppi
Systei f lie naie
Data file naie
Resolution
Group mater
lonlzatlon lode
Switching
Ref. lasses 292.9825,
A 292.9825
B 383.9816
C 385.8987
D 315.9419
E 317.9389
F 319.8965
G 321.8936
H 327.8847
I 338.9792
J
K
L
1
1
El*
HUME
388.9761
338.9792
331.9368
333.9338
375.8364
Channel I 338.9792 Peak top
Height .81 volts Span 288 ppi
288
-------
TLI Project:
Client Sample:
44376A
193-196
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980034
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-17A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/06/98
n/a
U980026
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3.7.8-TCDD
1,23,7,8-PeCDD
1.23,4.7,8-HxCDD
1,23,6,7,8-HxCDD
l,2J,7,8,9-HxCDD
1,23,4,6,7,8-HpCDD
1,2,3.4,6,7,8,9-OCDD
2,3.7,8-TCDF
1.23.7,8-PeCDF
23,4,7,8-PeCDF
*23,6,7,8-HxCDF
2.3,4,6J,8-HxCDF
1.23,7,8,9-HxCDF
1,23,4,6,7,8-HpCDF
1,23.4,7,8.9-HpCDF
1,2,3,4.6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Attlti fjffif} s Bt,.-. ;•;•• ^ '•V'JEJUPO ''
EMPC 0.006
0.04
0.02
0.04
0.05
0.12
0.25
0.45
0.14
0.22
0.31
0.12
0.14
0.02
1.2
0.17
0.41
Amt {ng) Number DL pipe
0.31 9 031
0.52 9 0.81
0.53 7
0.23 2
2.2 15 12.
2.9 14 2.9
1.4 12
1.9 4
Ratfo
1.69
1.07
1.28
1.17
0.94
0.81
0.78
1.52
1.48
1.28
1.23
1.32
1.36
1.05
1.20
0.87
prr
29:35
32:44
32:49
33:06
36:03
39:36
24:39
28:35
29:15
32:01
32:08
32:37
33:23
35:01
36:33
39:49
Flags
PRJ
J_
J_
J_
J_
B_
B_
j^
Flags
—
Page 1 of 2
MTn_PSRvlXlI.LARS6.ia081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
.Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:
-------
TLI Project: 44376A
Client Sample: 193-196
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980034
internal Standards . •'•;
13C,r2.3,7,8-TCDF
13C12-2,3,7,8-TCDD
13Cl2-U,3,7,8-PeCDF
13C,rU,3,7,8-PeCDD
I3C12-U,3,6,7,8-HxCDF
13C12-lA3,6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
I3C12-U,3,4,6,7,8-HpCDD
13C12-U^,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
13C.2-2,3,4,7,8-PeCDF
13C,rU,3,4,7,8-HxCDF
l3Ci2-U,3,4J,8-HxCDD
13Ci2-U,3,4,7,8.9-HpCDF
Surrogate Standards {Type A)
37CU-2,3,7,8-TCDD
Alternate Standards {Type A)
l3C,2-U,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
13C12-U,3,7,8,9-HxCDD
Amt (ng}
2.4
3.2
3.1
3.4
2.9
3.4
1.6
3.8
7.4
Amt. {jng)
3.7
3.7.
3.9
4.3
Amt $i0)
3.4
Amt: (tig)
3.2
3.1
/ 4«MBMf
60.0
79.6
78.7
86.0
72.7
85.3
40.6
95.1
92.1
^Recovery
93.6
92.8
98.0
107
-% Recovery
85.2
^Recovery
79.0
77.2
,
U'^,T™
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
40%-130%
40%-130%
40%-130%
40%- 130%
40%- 130%
40%-130%
V^IWfc;/;
0.75
0.81
1.49
1.48
0.48
1.28
0.36
1.04
0.87
R330
1.46
0.47
1.28
0.35
Ratio
0.47
0.48
Ratio
0.82
1.26
^m^
24:36
25:19
28:33
29:35
32:08
32:48
35:00
36:02
39:36
RT
29:15
32:02
32:43
36:32
RT
25:20
RT
33:22
32:36
RT
25:08
33:07
-r-f^r
RO
—
ftags
RO
Flags ^
—
Flags
—
Flags
Data Reviewer
01/10/98
Page 2 of 2
MTT2 J>SR v 1J01. LARS «. 10
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:22
-------
Initial
Data Review By:
.Date
C
_L\o,T(
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No .
1 Liatina of O980034B.dbf
01/10/98 Matched GC Peaks / Ratio
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total. Area
TCDF 0.65-0.89
304-306
NK
K
K
K
K
K
K
DC (JL, 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
:00 RO
:27
:58
:11
:35
:55
:19
:35
:48
:02
:12
:27
:39
:03
:16
25:31
26:23 RO
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
NK
NK
K
D
K
M
AN
0.54
0.81
0.82
0.77
0.78
0.79
0.75
0.75
0.80
0.79
0.78
0.82
0.78
0.72
0.79
0.88
0.95
16 Peaks
DC NL 0:
DC WL 23:
23:
24:
24:
25:
DC WH 26 :
DC WH 26:
0.
00 RO
:33
53 RO
12 RO
36
02 RO
04 RO
11 RO
4 Peaks
DC NL 0:
22:
23:
23:
D SN 23:
24:
24:
24:
25:
25:
0.
00
47
11
27
49 RO
10
26
48
15
20 RO
.65-0.89
1.32
0.72
1.27
1.10
0.75
0.92
0.98
0.62
25
312
334
366
1,614
1,037
1,094
924
1, 223
1,130
573
484
2,760
/ Ret. Time
... Area . Peak . 1 .. Area. Peak.
.08
.29
.60
.98
.93
.30
.23
.14
.48
.48
.27
.69
.78
751.82
640
110
98
13,457
.63
.01
.20
.83
139.92
150.48
159.62
707.63
458.58
470.30
396.17
542.62
498.90
250.50
218.34
1,207.35
315.47
283.44
51.52
52.61
172
184
207
907
578
623
527
680
631
2.. Rel.RT Compound. Name. . ID.
0.867-1.079
.37
.12
.36
.30
.72
.93
.97
.86
.58
322.77
266
.35
1,553.43
436
.35
357.19
58.49
55.48
0
0
0
0
0
0
0
0
0
0
0
0
1
1
.000
.872
.893
.902
.918
.932
.948
.959
.967
.977
.984
.994
.002 2378-TCDF AN
.018
. Flags.
1.027
1.037
1.072
J
J
0.959-1.041
14.35
413.
34.
121.
19,665.
277.
16.
11.
.45
.52
,79
36
29
83
10
20, 098.96
65-0.89
0.66
0.69
0.71
0.69
1.05
0.71
0.73
0.67
0.68
O.S2
8.
532.
343.
93.
5.
250.
184.
91.
279.
34.
07
64
42
85
04
37
25
48
00
94
24.80
75.73
8,406.96
143.63
217.62
142.48
38.28
104.16
77.76
36.58
113.00
15.20
19.50
68.81
11,258.
156.
40
66
0.
0.
0.
0.
000
957
,971
984
1.000 13C12-2378-TCDF ISO
1.
1.
1.
0.895-
315.
200.
55.
02
94
57
146.21
106.
54.
166.
29.
49
90
00
40
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
018
060
064
1.047
000
900
916
926
941
955
965
980
997
001 2378 -TCDD AN
J
J
J
J
J
J
PRJ
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:22 01710/98
291
-------
Page No. 2
01/10/98
Compound/
M_Z.:.. QC.Log Omit Why
Listing of 0980034B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
D
D
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
O
M
A
M
0
340-342
13C12- PeCDF
352-354
25:29
25:39
D SN 25:53
0 SN 26:19
10 Peaks
DC NL 0:00
23:58
25:20
25:44
25:55
26:03
26 : 23
26:28
26:28
8 Peaks
DC NL 0:00
24:09
25:08
25:19
25:38
4 Peaks
DC NL 0:00
26:35
D SN 27 : 12
D SN 27:19
27:35
27:43
27:53
28:11
28:17
28:29
28:35
28:43
28:51
D SN 29 : 05
29:15
29:24
29:44
23:59
30:14
15 Peaks
DC NL 0:00
0.72
0.76
SO 0.62
"0.69
0.65-0.89
RO 2.24
RO 1.01
0.82
0.81
0.69
1.32-1.78
RO 0.88
1.53
RO 2.38
RO 1.30
1.60
1.54
1.54
1.49
1.56
1.48
1.52
1.52
1.57
1.51
1.48
1.66
1.48
RO 2.10
1.76
1.32-1.78
1.38
46.96
59.18
14.50
19.56
1,916.09
0.19
439.39
16,955.30
342.17
65.37
59.30
24.50
12.34
4.42
17,902.79
13.74
105.46
22,343.10
19,872.67
632.46
42,953.69
jve : TCOO /
4.49
1,539.34
29.78
30.47
645.99
3,695.81
883.12
962.00
1,603.48
611.00
740.00
675.38
962.81
26.13
1,106.61
1,329.21
214.69
42.41
105.01
15,116.86
0.62
19.59
25.61
439.39
16,955.30
342.17
65.37
59.30
24.50
12.34
4.42
60.27
10,049.70
8,899.07
257.32
931.57
397.42
2,239.53
535.12
575.00
978.07
365.00
446.00
407.32
588.43
660.41
829.14
127.95
34.98
66.97
27.37 1.007
33.57 1.013
1.022
" -""•1.039
0.921-1.079
0.000
0.947
1.001 37C1-TCDD CLS
1.016
1.024
1.029
1.042
1.045
1.045
0.921-1.079
0.000
59.58 0.954
12,293.40 0.993 13C12-1234-TCDD RSI
10,973.60 1.000 13C12-2378-TCDD IS1
375.14 1.013
0.925-1.065
0.000
607.77 0.931
0.953
0.957
248.57 0.966
1,456.28 0.971
348.00 0.977
387.00 0.987
625.41 0.991
246.00 0.998
294.00 1.001 12378-PeCDF AN
268.06 1.006
374.38 1.011
1.019
446.20 1.025 23478-PeCDF AN
500.07 1.030
86.74 1.041
16.63 1.050
38.04 1.059
0.860-1.140
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:22fl1ZJOJ98
(L\j(~
-------
Page No. 3
01/10/98
Compound/
M_Z QC.Log Omit Why
Listing of 0980034B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
352-3S4
PeCDD
3S6-3S8
356-358
13C12- PeCDD
368-370
368-370
27
28
28
28
29
30
:42
:11
:33
:51
:15
:14 RO
6 Peaks
DC NL 0
27
28
28:
28
28:
29:
29:
29:
29:
29:
29:
30:
DC SN 30:
1
:00 RO
:48 RO
:17 RO
:31
:40
:51
:01
06
19
26 RO
35
44
04
26
12 Peaks
DC NL 0:
28:
28:
29:
29:
30:
30:
1.
00 RO
31
39 RO
35
43
10 RO
13 RO
6 Peaks
1.48
1.44
1.49 20
1.59
1.46 18
2.50
717.62
22.60
,072.79
527.63
,154.55
27.41
39,522.60
.32-1.78
0.64
1.31
1.22
1.S6
1.73
1.47
1.57
l.SO
1.70
0.73
1.69
1.60
1.72
1.42
3,
32-1.78
0.75
1.77
1.03
1.48 11,
1.47 1,
1.23
3.40
13,
0.23
947.32
98.38
658.66
167.91
404.12
93.98
162.88
167.45
72.01
135.32
86.87
70.26
2.03
065.16
427
13
12,018
323
10,782
26
.95
.32
.00
.69
.30
.83
289
9
8,054
203
7,372
10
.67 0
.28 0
.79 1
.94
.25
.75
1
.970
.987
.000 13C12-PCCDF 123
.011
1.025 13C12-PeCDF 234
IS2
SOH1
1.059
0.
935-1.022
0.000
575
59
401
106
240
57
97
105
43
85
53
44
.82
.80
.06
.34
.23
.47
.64
.39
.77
.00
.46
.41
440
48
257.
61,
163,
36,
65.
62.
59.
50.
33.
25.
.90
.90
.60
.57
.89
,51
.24
06
91
32
41
as
0.940
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
0.865-
0.20
29. S5
26.06
332.56
680.86
29.66
15.89
114.58
18.
15.
6,755.
1,000.
18.
21.
87
84
44
26
03
20
10.
15.
4,577.
680.
14.
6.
68
32
12
60
69
23
0.
0.
0.
1.
1.
1.
1.
956
964
969
975
981
984
991
995
000 12378-PeCDD
005
016
029
1.135
000
964
968
000 13C12- PeCDD 123
005
020
021
J
J
J
J
. J
J
AN J
J
J
IS3
Above: PeCDD / HxCDF Follows
HxCDF
374-376
DC NL
1.05-1.43
0:00
31:04
31:13
31:23
31:31
31:41
32:01
32:08
32:14
32:26
32:37
33:23
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
41
37
30
27
28
27
28
23
43
08
32
36
26
671
1,583
157
197
96
1,134.
568.
137.
231.
490.
62.
.48
.79
.81
.30
.10
.03
.29
.03
.55
.49
65
10
388
895
87
110
53
637
313
80
120
279
35
.00
.23
.89
.48
.80
.24
.47
.83
.12
.37
.80
283
688
69
86
42
497
254.
56.
111.
211.
26.
0.962-1.047
.79
.58
.41
.62
.23
.05
.56
.72
.37
28
30
0
0
0
0.
0.
0.
0.
1.
1.
1.
.000
.967
.971
.977
.981
.986
.996 123478-HxCDF
.000 123678-HxCDF
.003
009
1.015 234678-HxCDF
1.
039 123789-HxCDF
J
J
J
AN
AN
J
J
AN
AN J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:22 01/10/98
- 293
-------
Page No.
01/10/98
Listing of 0980034B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total,Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name. . ID.. Flags.
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
D
390-392
13C12-HXCDD.
402-404
402-404
HpCDF
408-410
D
D
D
408-410
33:27
DC SN 33:44
DC SN 33:46
12 Peaks
1
RO 0
RO 0
.24
.18
.45
118.74
0.74
2.26
5,448.88
65
.76
52
0.43-0.59
DC NL 0:00
31:03
31:12
32:02
32:08
32:36
33:07
33:22
7 Peaks
RO 0
0
0
0
0
0
RO 2
0
.41
.49
.53
.47
.48
.48
.01
.47
7.17
84.01
157.69
11,171.99
14,599.00
13,994.99
22.09
11,024.27
51,054.04
1.05-1.43
DC NL 0:00
31:33
D SN 31:43
DC SN 31:52
32:00
32:13
32:22
DC SN 32:36
32:44
32:49
33:06
7 Peaks
RO 0.71
1.22
1.20
RO 2.22
1.34
1.18
1.15
RO 12.58
1.07
1.28
1.
17
8.42
174.40
4.15
2.26
602.43
364.54
58.41
2.49
50.91
123.14
141.27
1,515.10
27
54
3,593
4,719
4,526
29
3,541
.74
.30
.18
.22
.81
.34
.35
56
103
7,578
9,879
9,468
14
.98
1
1
1
.041
.050
.051
J
0.876-1.124
.27
.39
.81
.78
.18
.63
7,482.92
0
0
0
0
1
1
1
1
.000
.966
.971
.997 13C12-HXCDF 478 SOE2
.000 13C12-HXCDF 678 IS4
.015 13C12-HXCDF 234 ALT2
.031
.038 13C12-HXCDF 789 ALT1
0.958-1.014
0.000
95
.95
78.
45
0.962
J
0.967
0.972
345.08
197.24
31.
26.
69.
76.
.18
.26
,13
05
257.
167.
27.
24.
54.
65.
1.05-1.43
DC NL 0:00
32:12
32:43
32:48
33:07
4 Peaks
1.
1.
1.
1.
1.
35
42
28
28
26
9.50
57.49
9,090.18
12,670.09
14,924.29
36,742.05
0.88-1.20
DC NL 0:00
35:01
35:17
35:26
D SN 35:36
D SN 35:41
36:33
D SN 36:40
4 Peaks
RO 1.
1.
1.
1.
RO 0.
RO 1.
1.
RO 1.
28
05
01
04
80
24
20
92
12.44
2,030.19
442.15
456.68
17.93
16.36
231.09
8.91
3,160.11
33.
5,107.
7,123.
8,308.
76
57
21
36
23.
3,982.
5,546.
6,615.
35
30
23
65
01
22
0.976
0.982
0.987
0.
0.
1.
i!
994
998 123478-HXCDD AN
001 123678-HxCDD AN
009 123789-HxCDD AN
J
J
J
J
0.970-1.030
73
61
88
93
0.
0.
0.
1.
1.
000
982
997 13C12-HXCDD 478 SOR3
000 13C12-HXCDD 678 IS5
010 13C12-HXCDD 789 RS2
1,040.
222.
233.
126.
91
40
17
04
989.
219.
223.
105.
0.996-
28
75
51
05
0.
1.
1.
1.
1.
1.
1.
1.
1.049
000
000 1234678-HpCDF AN
008
012
017
020
044 1234789-HpCDF AN
048
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:22 01/10/98
294
-------
Page No. 5
01/10/98
Compound/
M_Z .... QC . Log
13C12-HpCDF
418-420
.. - - M. :
M
418-420
HpCDD
424-426
D
D
D
D
424-426
13C12-HpCDD.
436-438
436-438
OCDF
|42-444
f
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
Listing of 09800348. dbf
Matched GC Peaks / Ratio /
Omit why ..RT. OK Ratio Total. Area. ..
0.37-0.51
DC NL 0:00 RO 1.06 8.86
35:00 RO- 0.36 4,974.55
35:21 RO 0.14 15.71
36:32 RO 0.35 4,254.55
3 Peaks 9,244.81
0.88-1.20
DC NL 0:00 1.04 3.80
DC WL 35:09 RO 0.32 5.12
35:18 1.05 291.54
D SN 35:33 1.00 12.24
36:03 0.94 308.00
DC NH 36:16 RO 1.45 5.39
DC NH 36:32 RO 4 . 07 7.75
2 Peaks 599.54
0.88-1.20
DC NL 0:00 1.11 15.79
35:17 0.95 75.03
36:02 1.04 10,309.02
2 Peaks 10,384.05
0.76-1.02
DC NL 0:00 RO 1.73 2.40
DC WL 35:11 0.88 5.61
DC WL 35:29 RO 0.40 3.50
35:59 RO 0.61 2.97
DC SN 36:11 RO 1.57 1.78
36:17 RO 1.29 3.95
DC SN 37:18 RO 2.93 0.87
DC SN 38:21 RO 0.53 2.21
38:31 RO 0.18 2.93
38:40 RO 1.15 3.95
38:53 RO 1.80 2.72
39:49 0.87 1,068.35
40:14 RO 1.09 6.56
7 Peaks 1,091.43
0.76-1.02
DC NL 0:00 RO 0.03 0.13
39:36 0.81 512.93
39:54 RO 2.10 4.20
DC SN 40:04 RO 0.48 2.42
2 Peaks 517.13
0.76-1.02
DC NL 0:00 RO 24.20 0.09
Ret. Time
Area . Peak . 1 .. Area . Peak . 2 . . Rel.RT Compound. Name. . ID.. Flags
0.943-1.114
0.000
l,520rOO 4-, -280. -00- 1.000 13C12-HpCDF 678 IS6
4.80 34.83 1.010
1,300.00 3,680.00 1.044 13C12-HpCDF 789 SUR4
0.975-1.005
0.000
0.975
149.11 142.43 0.980
0.987
148.96 159.04 1.000 1234678-HpCDD AN
1.006
1.014
0.972-1.028
0.000
36.54 38.49 0.979
5,253.24 5,055.78 1.000 13C12-HpCDD 678 IS7
Oota-CDD and CDF Follows
0.899-1.101
0.000
0.888
0.896
1.40 2.30 0.909
0.914
2.70 2.09 0.916
0.942
0.968
1.38 7.82 0.973
2.40 2.09 0.976
2.59 1.44 0.982
497.25 571.10 1.005 OCDF AN
3.78 3.47 1.016
0.899-1.101
0.000
229.74 283.19 1.000 OCDD AN
4.66 2.22 1.008
1.012
0.996-1.004
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:2201/10/98
295
-------
Page No. 6 Listing of 09800348.dbf
01/10/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
39:36 0.87 14,978.56 6,952.25 8,026.31 1.000 13C12-OCDD IS8
40:01 RO 3.36 40.24 71.44 21.29 1.011
470-472 2 Peaks 15,018.80
Column Description . 'Why' Code Description QC Log Desc.
H_Z -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:as) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below signal to Noise Level D-Peak Deleted
OK -RO-Ratio Outside Limits
-------
f±le:U9 80034 tl-724 Acq: 6-JAN-1998 23:38:14 SC EH- Voltage SIS 703 Noise: 54 5 5
303.9016 f,2 3303(256, 30, -3.0) PXD(9,S,3,0.10\f21830.0,1.00\,r,T) XxptSDBSOS
TSIAKSLX LASS Tmrt:193-196 TLH44376A
1001
80.
SO.
40.
20.
A1.21X7
\
A1.SOX6 /V\/\ *'lA*6/\ M\ A A / \ *A A
^\^ y\_ j\^. / Y \- 9J V. / \ 7 1 W \ ^ vv V / V^y v ^*. s*_
-.2.7X6
-.2.1X6
Ll . 6X6
.1.1X6
.5.3X5
0.0X0
33:00 ' ' 23,00 24\00 ' ' 35:00 ' ' ' 36,00 ' TJLme
r±le,U980034 tl-724 Acq, 6-JAS-1998 23,38,14 SC XH- Voltage SIX 70S Boiae:10036
305.8987 r,2 3303(256,30, -3.0) PXD(9,5,3,0.10\,40144.0,1.00\,T,T) XxpiUDBSOS
TRIANGLE LABS Text:193-196 TLIt4437SA
1003
80.
60.
40.
20.
Al.
AS. 38X6 A6. 32X6
, .-AT Av\ AWA AA A/
5X7
A4.36X6
fA3.57E6
-3.3X6
.2.6X6
.2.0X6
.1.3X6
.6.6X5
22': 00 23,00 24\00 2s':00 26\00 Time
rlle:O980034 tl-724 Acq: 6-JJOT-1998 23,38,14 SC ET> Voltage SIS 70S Soiae:S337
315.9419 T:2 BSOB(256, 30, -3.0) PXD(9,5,3,0.10\,31348.0,1.00\,rrT) XipsSDSSUS
TSIAKSLX LASS Text:193-19S TLIt44376A
1001
30.
so:
40:
20:
o-
A3.'
_ 1
1X7
V^
2.0X7
.1 . 6X7
.1.2X7
.7.9X6
.3.9X6
O.OEO
' 33\00 33:00 ' '34:00 ' ' ' ' 3S\00 .25:00 Mae
T±letU980034 tl-724 Acq, 6 -JAN- 19 9 8 33,38:14 SC XI + Voltage SIS 70s Itoiae:40SS
317.9389 T:2 3SUB(256,30, -3.0) PKD(9,5,3,0.10\,16220.0,1.00\,T,T) Xxp:KDBSUS
TRIANGLE LABS Teit:193-196 TLH44376A
1003
aol
so:
40:
20:
0:
A1.13X8
n
I
/ V.
-2.6X7
.2.1X7
.1 . 6X7
.1.1X7
.5 . 3X6
O.OEO
' 22\00 23:00 ' ' ' '24:00 3S\00 36\00 Time
F±le,U980034 tl-724 Acq, 6-JAN-1998 23,38,14 SC XH- Voltage SIS 70S
330.9792 r,2 XxpiSDBSOS
TRIANGLE LABS Text: 193-196 TLIt44376A
1001
80:
so:
40:
20:
o-
32,03 33,4523,0733,3523,4324,04 ***** 34:51 ^. 3^33^5 ,4436^04_n ^36,42.
I
.5.1X7
.4.1X7
.3.1X7
.2.0X7
.1.0X7
O.OEO
23,00 23,00 24',00 2S',00 26\00 ' ' ' ' ' Time
rile, 0980034 tl-724 Acq: 6 -JAN- 19 9 8 33,38,14 SC EH- Voltage SIX 70S
375.8364 T-,2 XrptSDBSOS
TRIANGLE LABS Text: 193-196 TLIt44376A
1001
80:
60:
40:
20:
o:
26 22
,23,50 23,10
22, 07 32,27 . I , 33,55
II , 1 i i U I 1 1 II 1 34,33 at
i lit h L 1 U , L MM\M 11 if
JuUOIJlAJllliLJI WUUJoilAjnMM^^JL^^
, 35'31 \16,03
1 • O * V J
">0\ 1,1 1
ll II Illli L 1
• ' 3 1 u Mil ill 1 i n 1 Jl i
ir Ml fill IM. m\\t\ U li Ifll
iAi JPiAlLJUJUwIL II IMA JU yiuL
-1.4E4
.1.1X4
.8.3X3
.5.5X3
.2.8X3
-O.OEO
22:00 23:00 24:00 25:00 26,00 Time
297
-------
Til»:a980034 tl-734 Acq: 6- JAN- 1998 23:38:14 SC XH- Voltage SIX 70S Bairn* : 16 00
319.8965 T:2 3SUB(356, 30, -3.0) PXD( 7,5, 3,0 .10\,6400.0,1.00\,r,T) Sxp:SDB5US
TXIAHSLX LABS T»xt: 193-196 TLH44376A
10K
80.
60.
40.
30.
a
1
j
_<.7Z5
I
A1.43X6
A'
Al . 04X6
A A1.30X6
A3. 83X5 I A7.7SXS A3. 66X5 M
j\_ J WV^i'VE/\ 'y^ W^V/V^
•
'.3.8X5
-.3.8X5
.1.9X5
-.9.4X4
23:00 34:00 35:00 ' 36:00 Time
Til»:O980034 tl-734 Acq: 6-J3UT-1998 33:38:14 SC XH- Voltage SIS 703 Soia»:2434
331.8936 r:2 BSU3(356,30,-3.0) fXD(7,5,3,0.10\,9736.0,1.00\,T,T) KxptBDBSOS
TSIAKSLX LABS Text! 193 -196 TLH44376A
lOOi
80.
60.
40.
30.
n
,
6.4X5
A3. 01X6
A1.46X6 A1.93X6
"/r AXM."ABA^"5_ .
•.5. 1X5
'
-.3.8X5
''.3.6X5
.1.3X5
23[,00 34:00 35:00 26\00 Time
rile:O990034 tl-734 Acq: 6-JAH-1998 33:38:14 SC XH- Voltage SIS 70S Noise: 8674
331.9368 T:2 BSOB(256, 30, -3.0) PXD(7,S,3,0.10\,34696.0,1.00\,r,T) Xxp:SDB5US
TSIAKSLX LABS Text: 193-196 TLII44376A
100]
80.
60:
40:
30:
o-
Al 00X8 C3.6X7
\8.
1 V
9017
.3.0X7
.1 . 5X7
:i . 0x7
'-.5.1X6
0.0X0
' 23\00 ' • ' ' 34:00 ' ' 35:00 36:00 Time
Tile :U9 800 3 4 tl-734 Acq: 6-JZX-1998 33:38:14 SC XH- Voltage SIS 70S Noiae:3882
333.9338 Ts3 BSVB(256, 30, -3.0) PIO>(7,5,3,0.10\,1553a.O,1.00\,r,T) JExp«JOJB5as
TSIAKSLX LABS Text: 193-196 TLIt44376A
1001
80:
60:
40:
20:
o'-
Al 2 X8 -3.0X7
u.ioxa
.
/ V
\
V
'•.3.4X7
ll . 8E7
ll.3X7
'.6.1X6
" 0.0X0
33:00 ' 24:00 25:00 ' 26tOO ' ' Time
TiletU980Q34 tl-734 Acq: 6-JXS-1998 33:38:14 SC XH- Voltage SIS 70S Noiae:97
337.8847 T>2 BSOB(256, 30, -3.0) PKD(7,5,3,0.10\,388.0,1.00\,F,T) Zxp:HDB5US
TSIAKSLX LABS Text: 193-196 TLH44376A
1001
soj
60:
40:
20:
o:
Al.
"T ^
701T8
^
.4 . 0X7
.3.3X7
-2.4X7
-1 . 6X7
-8.1X6
0.0X0
33': 00 34:00 25:00 26:00 Time
Tilu:U980034 tl-734 Acq: 6-J3UT-1998 33:38:14 SC XZ+ Voltage SIS 70S
330.9733 Ft3 XxptODSSUS
TSXAOSLX LABS Text: 19 3 -19 6 XLIt44376A
1004
80.
60.
40:
20:
oj
33:07 33:35 23,43 24:04^ «f«3«f«7 ^^5,33^5:44 _26^04_ ^ ^^ji^S . 1X7
.— ^-^ y
.4.1X7
.3.1X7
.2.0X7
.1.0X7
0.0X0
33:00 ' ' ' 34^00 • • • • 35\tQO 36\00 Mae
298
-------
Tile>O980034 tl-724 Acqi 6-J3Of-1998 23t38il4
SC EI+ Vbltaga SIS 70S Soia»il364
339.8597 Tt3 BSUB(256, 30, -3.0) PXD( 7,5, 3,0 .10\,5456.0,1.0Q\,T,I) KzptXDBSUS
IXIAHGLX LABS Tart: 193-196 TLH44376A
1001
80.
60.
40.
30.
A3.
1
/
A3.
32X6
A
\
I A
v /v
' 77.00
74*7
A9
\
-AS'. 3 5X6 l\
\ A /v
W^w i
78.00
rile r 0980034 01-774 Acq: 6-J3UT-1998 7J.JS.-14
78X6
l\
<\ N
wv
AS 88X6 *6'
\ A A j
v/\Jv I
29,00
-5.4*5
60X6
\J \^ A1.28X6
'-.4.3X6
'•.3.2X6
.2.1X6
'.1.1X6
0.0X0
JO. 00 Tint
SC EH- Voltaoa SIX 70S Noia»:lS48
J41.8557 n2 BSOB(2S6,30,-3.0) PXD(7,S,3,0.10\,6192.0,1.00\,r,T) XxptODBSUS
TXIASSLX LABS Text:193-196 TLH44376A
1001
80.
60.
•
40:
70:
a-
A5.
Al.
OSES
(\
\
I A/
77^00
46X7
A6.
ft
25X6
A
/\
A4.
A3. 74X6
46X6
A A
UJVlMAA /WV-x- .
28iOO
TiletO980034 tl-724 Acq: 6-JA1T-1998 23>38:14
SC EI+
351.9000 T:2 BSVB(256,30,-3.0) PKD(7r5,3,0.10\,724.
29 1 00
-.3.5X6
.2.8X6
.2.1X6
.1.4X6
.7.0X5
• o . oxo
JO .00 Tina
Voltaya SIX 70S HoiaatlBl
Q,1.00\,r,T) XxftODBSUS
TXIASSLX LABS Tart:193-196 TLIt44376A
1001
80:
50:
40:
70:
' 77.100 '
78:00
T±letO980034 tl-724 Acq, 6-JXK-1998 23i38il4
Al.j
/
SC XI+
353.8970 Ti2 BSUB(256,30,-3.0) PXD(7,S,3,0.10\f524.
['•* A1.08E8
1
29 tOO
\_
3.3X7
-.2.6X7
.3.0E7
'.1.3X7
.6.6X6
O.OEO
J0:00 Time
Voltage SIX 70S Noise -.131
0,1.00\,r,T) XxpiSDBSUS
TXIASSLX LABS Textsl93-196 TLIt44376A
ion
ao:
50:
40:
70:
77l 00 '
78.00
TilotU980034 tl-724 Acqi 6-JZS-1998 7J.J8.14
A8
i
SC XI+
SX7 A7.37X7
^ ,
29\ 00
\_
-.2.2X7
.1 . 8X7
.1.3X7
.8.8X6
.4.4X6
O.OEO
JO: 00 ' Tiae
Voltage SIS 70S
330.9792 T>2 KxptXDBSOS
TRIANGLE LABS Text.: 193-196 TLII44376A
1004
80:
50:
40:
70:
0:
*/~v
26:43 27:23
-V ^ -IT
77:00 '
77.5J7S.07
78^00 '
rU.eiU980034 tl-724 Acqi 6 -JAN- 19 9 8 7J.J8.14
28 1 25
SC XI+
-£K!J
79:00 '
29>30 30:18 C5.3E7
>S*^»^ n "^ AM"" y »*-*V " ^»l* • "^«l . i '«' •*
-4.3X7
.3.2X7
.2.1X7
-1.1X7
0.0X0
JO. 00 ' Tiae
Voltage SIX 70S
409.7974 Tt2 XzptBDBSUS
TRIANGLE LABS Tmxt.il93-196 TLH44376A
ion
80.
50:
40:
70:
0:
26
A,
iJ5
— .
1 I 77:J5
i Vf6'f? ft, i
77.00
78
77.51 ,
78:00
16
_7. 6X4
28,39
/|J
1 h3""\
79.00 '
29 1 59 ,„ .„
M30il9
1 A 30,33
JWik^
-2.1X4
.1.6X4
.1 . 0X4
.5.2X3
0.0X0
J0:00 ' ' Timt
299
-------
eU.»lU9UOOJ4 tl-72f Acqt 6-JJUI-lyya JJUOlJ.4 GC &I+ Voltage SIS 70S Hoiae: 73
355.8546 T:2 BSUB<256,30,-3.0) PXD(5,3,3,O.OS\,28a.O,1.00\,r,T)
TSXAHSLS LABS Tmxt: 193-196 TLIH4376A
100\A5.76X6
27:48 28iOO 28tl2 28t24 28:36 28,48 29tOO 29:12 29i24 29:36'29148' 30>00 30:12'36:24'
TU.esU980034 H-724 Acq: 6-JAS-1998 23:38:14 GC XH- Voltage SIX 70S Noiaetlll
357.8516 f:2 BSVB(256, 30, -3.0) PXO(5,5,3, 0.05\,444.0,1.00\,r,T) XscptSDSSUS
XSIAOGLX LABS TfJCtt 193-196 XLH44376A
100i.A4.41X6
801
60.
40.
20.
A2.58X6
A4.48X5A4.89E5
/A A ^
A5.99ES
^A3.34XS A2.59X5
27i48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rlle:O980034 tl-724 Acq: 6-JZK-1998 23:38:14 GC XH- Voltage SIX 70S Uoiae:62
367.8949 Ti2 BSUB(256,30,-3.0) PXD(5,5,3, O.OS\,248.0,1.00\,f,T) XzpsSDBSUS
TSIASSLE LABS Taxt: 193-196 TLIt44376A
lOOi, A6.76X7
80.
60.
40.
20.
,1.00X7
27:48 28,00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rdJ.e,O9S0034 tl-724 Acq: 6-JKK-1998 23:38:14 GC tt+ Voltage SIX 70S Noise, 78
369.8919 T:2 3SOB(2S6,30,-3.0) PXD(5,5,3, 0.05%,312.0,1.00\,T,T) Exp:lO>B5BS
XXIASGZX LABS Text: 193-196 TLH44376A
100* A4.58X7
80.
60.
40.
20.
6.81X6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
•±1»:0980034 tl-724 Acq: 6-J3UT-1998 23:38:14 GC XX* Voltage SIX 70S
330.9792 T:2 Klp:SDB5US
2SZAMCXS LABS Tmxt: 193-196 TLH44376A
1004
80.
60.
40.
20.
0.
27:53 28:07
28:25
~~-v~
29:19
30:18
.0.0X0
HMO
-1.1X6
.8.5X5
.6.4X5
.4.2X5
.2.1E5
.0.0X0
T±ae
2.1X7
.1. 7X7
.1.2X7
.8.3X6
.4.1X6
.0.0X0
Tlae
-1.4X7
.1.1X7
.8.5X6
'.5.7X6
.2.8X6
0.0X0
-5.3X7
'.4.2X7
.3.2X7
.2.1X7
.1.1X7
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00.30:12 30:24
0.0X0
Tlae
300
-------
rila:a980034 #1-385 Acq: 6-JXH-1998 23,38:14 SC EH- Voltage SIS 70S SOim»:7755
373.8208 Ti3 3303(356,30, -3.0) PXD(7,5,3, 0.10%,31020.0,1.00\,r,T) XxptXJBSUS
ySIANSZX LASS Tart: 193-196 TLI944376A
1001 AS. 95X6
80.
60:
40:
sol
A6.37X6
A3.88X
A3. 79X6
AS.58X5
31,00 31,12 31,24 31,36 31,48 32,00 32,12 32,24 32,36 32,48 33,00 33,12 33,24 33,36 33,48
ril»,U980034 tl-385 Aeqi 6-JAB-1998 23,39,14 SC XI* Voltaye SIS 70S BO±aat5484
375.8178 Tt3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,31936.0,1.00\,T,T) XxptBDBSUS
XBIAXGLX LASS TarC, 133-196 TLH44376A
1001 A6.89X6
80.
60:
4.0:
20:
A4.97X6
A3.84Xi
AS. 66X5
A3.11X6
AS.30X5
31il2 31:34 31,36 31,48 32>00 33,12 32t24 32t36 32:48 33,00 33,12 33,24 33,36 33,48
rile»WflOO34 tl-385 Acq: 6-JXK-1998 23,38,14 SC EI+ Voltage SIX 70S Xoieetl310
383.8639 T:3 BSUS(256,30, -3.0) PXD<7,5,3,0.10\,4840.0,1.00\,T,T) XxpiUDBSOS
ZBIASGLZ LABS Toft: 193-196 TLH44376A
1004 A4.72X7
80:
60:
40.
20:
oj
A4.53X7
A3.54X7
31,00 31,12 31:24 31,36 31,48 33,00 32,12 32:24 33:36 32:48 33:00 33,12 33:24 33,36 33:48
Tila:0980034 fl-385 Acq, 6-JJUT-1998 23,38:14 SC XI+ Voltaye SIS 70S Xoiao,29Sl
385.8610 T,3 BSUB(256,30,-3.0) rXD(7,5,3,0.10\,11804.0,1.00\,r,T) Xxp:KDB5OS
TSIASSLX LABS T&zt,193-196 TUf44376A
100* A9. 8X7 A9.47X7
80:
60:
40:
20:
o:
A7.48X7
31:00 31,13 31,24 31,36 31,48 33:00 32:13 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33,48
rile:U980034 tl-385 Acq: 6-JAS-1998 23,38,14 SC EI+ Voltage SIS 70S
393.9760 T:3 XxptNDBSUS
TSIANGLX LABS Taxt: 193-196 TLH44376A
31:07 31:31 31:35 31:51 32,03 32:20 ":34 J2tfp_ _ 33^,07 33.23 33l38
10 Oi
80:
60:
40:
20:
oj
31,00 31,12 31,24 31:36 31:48 33:00 32:12 32:24 32,36 32,48 33,00 33:12 33,24 33:36 33,48
rila,U980034 tl-385 Acq: 6-JXS-1998 23,38,14 SC EI+ Voltage SIS 70S
445.7555 T,3 SxptXDBSOS
TRIANGLE LABS Tart:193-196 TLH44376A
33:35 33:31
-2.7X6
'.2.1SS
.1.6X6
-.0.0X0
-2.3X6
.1.7X6
.8.7X5
.4.3X5
0.0X0
-1.5X7
'•.1.2X7
.8.8X6
.5.8X6
'•.2.9X6
0.0X0
Time
-2.9X7
-.2.3X7
'-.1.7X7
'•.1.2X7
.5.8X6
-O.OEO
S±ae
-3.4X7
-.1.9X7
J..4X7
\-9.6XC
•.4.8XS
0.0X0
31,00 31,12 31:24 31:36 31:48 33:00 32:12 32:24 33:36 33:48 33,00 33:13 33:24 33:36 33,48
0.0X0
£!•«
301
-------
rU.m,USauOJ4 tl-jas Acqi 6-JAU-1998 JJ:JO:14 CC EI+ Voltage SIS 70S
389.8156 Ti3 BSVB(256,30,-3.0) PXS(7,5,3r0.10\,9316.0,1.00\rr,T) XxpiSDBSUS
XSIASSLX LASS T»xtt 193-196 TLH44376A
100\ A3.
80.
60.
40.
20.
A9.S9X5
A
A6.91X5
A7.60X5
r\
.216
.9.3X5
.6.9X5
4.6X5
L2.3X5
31,36 31>48 32,00 32,13 32:24 32:36 32,48 33,00 33,12
ril»:0980034 tl-385 Acqi 6-JAS-1998 23,38,14 GC KI+ Voltaga SIX 70S Holme,3270
391.8137 Ti3 BSOB(256,30,-3.0) PXB(7,5,3,0.101,13080.0,1.00\,T,T) XxpiSDBSUS
ZBXAHGU LASS Text, 193-196 TLH44376A
1001 A2.57E6
80.
60.
40.
20.
0.
.0.0X0
33124 33 36 Time
A7.8SXS
Al.67X6
AS.40X5
A6.52X5
A2.72ES
31,36 31:48 32,00 32,12 32,24 32,36 32,43 33:00 33:12
File,0980034 tl-385 Acq: 6-J7UT-1998 23,38,14 GC CI+ Voltage SIR 70S Noise,2729
401.8558 F,3 3SUB(256,30,-3.0) P1O>(7,5,3, 0.10\,10916.0,1.00\,T,X) XxptXDBSOS
TXIAXGLX LASS Text, 193-196 TLH44376A
10M
-.8.9X5
.7.2X5
.5.4X5
.3.6X5
11. 8X5
33,24 33 36
.0.0X0
Tin.
00.
60.
40.
20.
0.
A7.12X7
AS.l
31,36 31:48 32,00 32,12 32:24 32', 36 32', 4 8 33', 00 33', 12
Tlla,0980034 tl-385 Acqs 6-JJOT-1998 23:38,14 GC XH- Voltage SIS 70S Noise,2018
403.8529 Ti3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,B072.0,1.00\,T,T) ElpiSDSSUS
TXIAXGLX LABS Text, 193-196 TLH44376A
100\ A6.62X7
AS.55X7
80.
60.
40.
20.
0.
33:24
33:36
31,36 31:48 32:00 32:12 32:24
Tilu,0980034 tl-385 Aoq, 6-JAS-1998 23:39:14 GC
92.9760 T:3 SxpiSDBSOS
TRIAHGLX LABS Text,193-196 TLI944376A
1001
*"-" 31:
80.
60.
40.
20.
0.
1. 8X7
.1.5X7
'.1.1X7
.7.3X6
.3.6X6
32,36 32:48 33,00
Voltage SIX 70S
33:12 33:24
33,22
~
33:36
0.0X0
Time
31:36 31:48
32:00
.0.0X0
32:12 32:24 32',36 32',48 33:00 33:12 33:24 33 36 Timt
-2.4X7
J..9X7
^..4X7
'.9.6X6
.4.8X6
302
-------
rila,a980034 tl-545 Acq: 6-JAS-1999 23:38:14 SC EI+ Voltage SIX 70S No±aat3889
407.7818 T:4 BSOB(256,30, -3.0) PKD(7,5,3,0.10\, 15556.0,1.00\,f,T) XxpiNDBSaS
TXIASGLX LABS Taxt:193-196 TLIt44376A
100S A1.04X7
ao:
50:
40:
-20:
o:
_ -A3.33X6-
A1.26E6
35,00 35,12 35,24 35,36 35,48 36,00 36,12 36,24 36,36
rile,U980034 tl-545 Acq: 6-JAN-1998 23,38,14 SC £Z> Voltage SIS 70S Noiae:3049
409.7789 f:4 SSUB(256, 30, -3.0) fXJ><7,5,3,0.10\,12196.0,1.00\,T,T) XxptXDBSUS
TSIASSU! LABS Text: 193-196 TLIt44376A
36,48
ion
80:
40:
20:
AS.
A2.20X6
A1.0SX6
35,00 35:12 35,24 35,36 35,48 36:00 36,12 36,24 36,36
rile:U980034 tl-545 Acq: 6-JAN-1998 23,38:14 SC SI+ Voltage SIS 70S Koiae:3243
417.8253 Fi4 BSUS(256,30,-3.0) ?XD(7,5,3,0.10\,12972.0,1.00*,r,X) XxptSDBSUS
: LABS Taxti 193-196 XLH44376A
1004 A1.53E7
A1.33E7
36,48
35', 00 35',12 35:24 35,36 35:48 36:00 36', 12 36:24 36', 36
Tlle,U9a0034 tl-545 Acqt 6-JKK-1998 23,38,14 SC XH- Voltage SIS 70S Noise:3076
419.3220 r,4 BSOS(256,30,-3.0) PKD(7,S,3,0.10\,12304.0,1.00\rf,T) Sxp,XDB5US
TRIANSLS LASS Textil93-lS6 TLIt44376A
100A A4.33E7
A
A3.73S7
36:48
35,00 35,12 35,24 35,36 35,48 36,00 36:12 36:24
rlla,0980034 H-545 Acq: 6-JAK-199B 23,38,14 SC EI+ Voltage SIS 70S
430.9729 r,4 ExptSDSSUS
TRIANGLE LABS Text: 193-196 TLH44376A
36,36
36,48
1001
80.
60.
40:
201
0:
35,56 36,07 36,16 36,24 36,32_3&ifjl
-2.6X6
'•.2.1S6
'•.1.6X6
'.1.0E6
'.S.~2XS
37, 00
35,00 35,12 35,24 35,36 35,48 36,00 36,12 36,24
ril»iO980034 tl-545 Acqt 6-JAN-1998 23,38:14 SC XI+ Voltage SIX 70S
'79.7165 Ti4 XxpiSDBSOS
TRIANGLE LABS Toft,193-196 TLH44376A
100\
36,36
36,48
-2.6X6
:.2.1Z6
'•J..6X6
.1.1X6
'.5.3X5
•.o.oxo
37s 00 T±me
.0.0X0
37:00 Time
0.0X0
37:00 Time
-1.6X7
'•.1.3X7
'.9.4X6
-.6.3X6
.3.1X6
J7.-00
T±me
35,00
35t12 35,24
3St36
35,48
36,00
36,12
36,24
36,36
36:48 37:00
0.0X0
Time
303
-------
ril»,U380034 41-545 Acxjs 6-JAB-1998 23,3t,14 SC XH- Voltmge SIX 705 Koiaas930
425.7737 Ti4 BSOB(256,30,-3.0) ra>(7,S,3,0.10\,3720.0,1.00\,r,T)
TXIASSLS LASS Taxt:193-lS6 TLH44376A
100$ A1.?9X6
35,12 35,18 35,24 35,30 35,36 35,42 35:48 35,54 36tOO 36,06 36,12 36,18 36,24 36,30
Tila,U980034 il-545 Acqi 6-JKB-199B 23,38,14 SC XI+ Voltage SIS 70S Koiae,4149
435.8169 Ti4 BSUB(256,30,-3.0) fKD(7,5,3,0.10^,16596.0,1.00\rr,T) Xxp:XDB5US
XSIAKSLX LASS Text: 193-196 TLH44376A
1001 AS.25X7 ..1.3X7
riJ.a,USaOOJ4 #1-545 Acq: 6-JAa-iynu JJUHiJ.4 GC BI+ VoJ-tage SIX 70S Noiaa,969
433.7766 F,4 SSUS(256,30, -3 . 0) PKD(7 ,5,3,0. 10\, 3876.0, 1.00\,f,T) KlptUDBSOS
TXXAHGLX LASS T*zt,193-196 TLH44376A
1001
80.
60.
40.
20.
A1.49Z6
A1.49S6
3.9X3
'.3.1X5
.2.3X5
.1.6X5
.7.8X4
.0.0X0
35:13 35:18 35:24 35:30 35:36 35:43 35:48 35:54 36:00 36:06 36:13 36:18 36:34 36\30 Urn,
-4.0X5
80.
60.
40.
20.
35,12 35,18 35,24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36,12 36:18 36,24 36:30
Tila,U980034 tl-545 Acqt 6-J3UT-1998 23:38:14 GC KI+ Voltage SIS 70S Noise,3745
437.8140 r:4 BSUS(256,30,-3.0) PXD(7,S,3,0.10\,149aO.O,1.00\,T,T) XxpsSDBSVS
TRIANGLE LABS Text, 193-196 XLH44376A
1001 A5.06E7
80.
60.
40.
20.
.1. 0X7
.7.6X6
15.0X6
-2.5E6
.0.0X0
Time
-1.2X7
.1. 0X7
.7.5X6
.5.0X6
.2.5X6
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36,12 36,18 36:24 36:30
T±la,U980034 H-545 Acq: 6-JAB-1998 23:38:14 GC XH- Voltage SIS 70S
430.9729 T:4 KlptSDBSVS
XXIAHGLX LABS Tuxt, 193-196 TLXt44376A
L00\ _35jil3 _ 35:36 35:56 36,O7 36:16 36:24
80.
60.
40.
30.
0.
-1.6X7
.1.3X7
'.9.4X6
.6.3X6
.3.1X6
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00 36:06 36,12 36,18 36:24
0.0X0
Time
304
-------
Tile, 0960034 tl-545 AC?> 6-JAN-1993 23,38:14 ec EH- voitag* sis 76s Hoimmild9a
1.7428 Ti4 SSUS(256, 30, -3.0) PKD<7, 3,3,0. 10\,4392.0,1.00\,T,T) XxpiNDBSUS
TSIAXGLX LASS Taxttl93-196 TLIt44376A
1001
901
801
701
60.
sol
401
301
20.
101
A4.97X6
35,00 36,00 37,00 38:00 39,00
rila.O9800.J4 tl-545 Acqs 6-JA1T-1998 23,38,14 SC XH- Voltage SIS 70S Hoia»i634
443.7399 Tt4 BSUB(256,30,-3.0) PXD(7,5,3, 0.10\,2536.0,1.00\,T,T) Xxp:«DS5US
TSIJUIGLX LASS Text:193-196 XLH44376A
1001 AS.
901
80.
70.
SOI
30-
40.
30\
201
101
03.
40,00
71S6
.35.00 36:00 -37:00 38:00
r±le:O980034 tl-545 Acqt 6-JXS-199S 33:38:14 GC tt+ Voltage SIX 70S
430.9729 T:4 XxptSDSSUS
TSIANGLX LASS Text: 193-196 TLIt44376A
40:00
1003
aoi
701
601
501
401
301
201
101
0.
38:30
40:22
35'13 35:56 J5i." i 37:43 n. 39:18 39:49
Yt^Y^^^i^i^^^^r^^
35,00 36,00 37,00 38,00
File,0980034 tl-545 Aoqi 6-JJUT-1998 23,38,14 SC SH- Voltage SIS 70S
513.6775 T,4 XxptSDSSUS
TXUOKLS LASS Text: 193-196 TLII44376A
1004
39.00
40.00
41 00
-9.2X5
.8.3X5
.7.4X5
.6.4X5
.5.5X5
.4.6X5
.3.7X5
.2.3X5
.1.8X5
.9.2X4
0.0X0
tta>
-1.1X6
19.6X5
.8.5X5
.7.4X5
.6.4X5
.5.3X5
.4.2X5
.3.2X5
.2.1X5
.1.1X5
.0.0X0
41 00 TLme
^1.7X7
.1.5X7
11.3X7
.1.2X7
.1.0X7
.8.3X6
.6.7X6
.5.0X6
.3.3X6
.1.7X6
.0.0X0
41100 Time
35100
36:00
37:00
38:00
39s 00
40100
41100
305
-------
fHa:a9800J4U-545 Acq I6-JAS-i9SS JJlJotli ic SI+ Voltage SIX 70S HOimmiSS
457.7377 Tt4 BSUB(256,30, -3. 0) PXD(7,5,3,0.10\,116.0,1.00\,r,T) XxptUDBSOS
TSIANSLX LABS Tmrtil93-196 TLH44376A
1001 A3.30X6
39:30 39i36 39:43 39,4B 39t54 40:00
Til»:U980034 U-545 Acq> f-JJOr-1998 23,38:14 GC EH- Voltage SIX 70S Haifa:868
459.7348 Tt4 9309(356,30,-3.0) rXD<7,S,3,Q.iO\r3472.0,l.OQ\,r,T) SxptKDBSUS
XAOSLX LABS Tmxt.1193-196 TLH44376A
1001 A2.81S6
80.
60.
40.
20.
39t30 39:36 39:42 39:48 39,54 40:00
rilaiO9a0034 fl-545 Acq: 6-J1UT-1998 23,33:14 GC SH- Voltaga SIS 70S Koine:604
469.7779 Tt4 BSUB(256,30, -3.0) rXD(7,5,3,0.10\,24l6.0,l.OO\,T,T) XxpiNDBSUS
TSZAHSLS LABS Toft,193-196 TLH44376A
1001 A6.9JS7
80.
60.
40.
20:
39:30 39,36 39:42 39:48 39', 54
rile:0980034 U-545 Acq: 6-J7UT-1998 23:38:14 GC XH- Voltage 512 70S No±ae:27
471.7750 rt4 BSUB(256r30,-3.0) PXD<7r5r3,0.10\,108.0,1.00\,T,T) Sxp:HDB5US
XSIASSLS LABS Taxtsl93-196 TLH44376A
1001 AS. 0.3X7
80.
60.
40.
20.
40:00
39,30 39:36 39:42 39:48 39:54
FiletU980034 fl-545 Acq: 6-JAK-1998 23:38:14 GC XH- Voltage 5X5 705
30.9729 Tt4 SzpiXDBSUS
TXIAJKLX LABS Tart: 193-196 TLH44376A
39,31
80.
so:
40.
20.
0.
40100
40:01
40106
-5.2X5
.4.1X5
'.3.1X5
.2.1X5
.1. 0X5
.0.0X0
40 06 Tim.
-1.3X7
.1.1X7
.7.9X6
.5.3X6
.2.6X6
^-.'.0.0X0
40 06 Tiae
-1.5X7
.1.2X7
.9.2X6
.6.2X6
-3.1X6
40:06 Time
-1.5X7
.1.2X7
.9.2X6
-6.1X6
'.3.1X6
39130
39136
39142
39:48
39154
40:00
40 06
0.0X0
Mao
306
-------
Peak Locate Examination: 6-JAN-1998:23:37 File:U980034
Experiment:NDB5US Function:2 Reference:PFK
O
CO
-------
ile:U980034 #1
319.8965 F:2 Exp:NDB5US
ample Text:193
-724 Acq: 6-JAN-1998 23:38:14 GC EI + Voltage SIR 70S
-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
24:48 25:00 25:12 25:24 25:36 25:48 26:00
File:U980034 #1-724 Acq: 6-JAN-1998 23:38:14 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:193-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
lOOi : A1.66E6
80j
60 j
40J
20J
26:12
24:48 t 25:00 25:12 25:24 25:36 25:48 26:00
File:U980034 #li-724 Acq: 6-JAN-1998 23:38:14 GC EI+ Voltage SIR 70S
331.9368 F:2 Exp:NDB5US
Sample Text:193-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%. ' 25:08
25:19
26:12
24:48
25:00
25:12
25:24
25:36
25:48
26:00
26:12
JiO.OEO
24 Time
r_2.3E5
_1.9E5
_1.4E5
_9.3E4
L4.6E4
26
26
O.OEO
24 Time
_2.6E7
_2.1E7
_1.5E7
L1.0E7
_5.1E6
LO.OEO
24 Time
-------
File:U980034 #1-724 Acq: "6-JAN-1998 23:38:14 GC EI+ Voltage SIR 70S
339.8597 F:2 Exp:NDB5US
Sample Text:193-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC
100%,
A5.75E6
28:00 28:06 28:12 28:18 28:24 28:30 28:36
File:U980034 #1-724 Acq: 6-JAN-1998 23:38:14 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
Sample Text:193-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%
20 j
0-
601
40j
20J
OJ
A2.46E6 A2.94E6
28:00 28:06 28:12 28:18 28:24 28:30 28:36
File:U980034 #1-724 Acq: 6-JAN-1998 23:38:14 GC EI + Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:193-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%, I 28^33
60:
40J
20 j
0_:
28:00
28:06
28:12
28:18
28:24
28:30
28:36
28:42
28:42
_2.3E6
11.8E6
Ll.4E6
L9.1E5
L4.6E5
LO.OEO
28:42 28:48 Time
1.7E6
Ll.3E6
Ll.OE6
i.6.7E5
L3.3E5
LO.OEO
28:48 Time
C.O.OEO
28:48 Time
O
CO
-------
A1.30E7
File:U980034 #11-545 Acq: 6- JAN-1998 23 : 38 :14 GC EI+ Voltage SIR 70S
417.8253 F:4 Exp:NDB5US
Sample Text:193hl96 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% A1.52E7
: i
90 j
80J
70 j
60 j
50J
40J
30J
20 j
10J
01
| 35:00 36:00 37:00
File:U980034 #1L545 Acq: 6-JAN-1998 23:38:14 GC EI+ Voltage SIR 70S
419.8220 F:4 Exp:NDB5US
Sample Text:193-196 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% ! A4.28E7
90 j
80 j
70J
60 j
50 j
40J
30J
20J
10J
OJ
A3.68E7
L7
_4.OE6
_3.6E6
3.2E6
2.8E6
2.4E6
2.0E6
1.6E6
1.2E6
9E5
4.0E5
O.OEO
Time
1.1E7
1.0E7
9 . OE6
9E6
6.8E6
5.6E6
4.5E6
4E6
L7
_3
L2.3E6
35:00
36:00
37:00
O.OEO
Time
O
TH
CO
-------
TLI Project
Client Sample:
44376A
193-196
Method 23 TCDD/TCDF Analysis (DB-225)
c Analysis File: P980102
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-17A-D
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor.
Blank File:
Analyst:
12/17/97
12/29/97
01/07/98
n/a
P980094
JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P980092
n/a
n/a
n/a
|%^v^;r- /
2,3,7,8-TCDF
^foSffl^Slartarrf
13Cl2-2,3,7,8-TCDF
^Recovery Standard
I3C12-1.Z3,4-TCDD
Amt{B8) 'VDL* EMPC Ratio
0.10 0.75
-Amt (ngj % Recovery 'delimits Ratio
3.8 93.9 40%- 130% 0.78
Ratio
0.84
RT
23:06
RT
23:05
RT
21:54
iii!*' •
B_
Flags
—
Flags
Data Reviewer
01/09/98
Page 1 of 1
ONFJSR vrfll. LARS 6. iaO»l
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 -Fax: (919) 544-5491
Printed: 10:1701/09/98
311
-------
Initial
,.Date.,
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio liaits ha* been recalculated according to aethod requirements.
Page No.
01/07/98
Listing of P980103B.dbf
Matched GC Peaks / Ratio
/Ret. -Ti«e
Co•pound/
H_Z QC.Log Oait Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC NL 0
18
DC SN 18
DC SN 18
DC SN 19
19
19
19
19
19
DC SN 20
20
20
20
20
20:
21:
0
:00
:27
:48
:52
:00 RO
:07 RO
:28
:35
:43
:53
:00 RO
:10
:18
:28
:38
:47
:10
21:36
21:43 RO
21:
33:
22:
22:
22:
.65-0.89
0
0
0
0
0
1
0
0
0
0
1
0
0
0
.79
.84
.67
.82
.60
.24
.87
.75
.74
.78
.81
.77
.75
.71
0.75
0
0
.71
.74
0.74
0.99
:51 0.71
06
0.80
21 0.69
31 0.73
59
23:06
23:
23:
23:
24:
DC SN 24 :
DC SN 24 :
25:
19
36
43
30
39
47 RO
16 RO
0.81
0.
75
0.76
0.
0.
0.
0.
1.
1.
75
77
76
89
08
30
304-306 25 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL 21:
DC WL 21:
DC WL 31:
33:
33:
DC WH 24 :
DC WH 24:
0.
00 RO
07 RO
35
51
OS
44 RO
07 RO
52 RO
1
21
0
0
1
2
24
32
46
22
1
19
43
23
80
30
151
45
5
44
.88
.38
.75
.71
.20
.92
.96
.90
.42
.10
.04
.08
.34
.19
.43
.59
.66
.49
.56
.06
40.41
8.75
55.17
52.05
43.67
52.48
60.03
57.70
36.05
9.77
11
0.792-1.101
.61
0
0
0
0
.000
.799
.814
.817
0.823
2
11
9
19
9
.05
.59
.78
.73
.68
1.65
13.37
13.13
36.70
13.43
0.828
0.843
0.848
0.854
0.861
0.866
8
18
9
34
12
64
19
3
18
17
3
23
23
18
.39
.57
.64
.53
.75
.30
.39
.11
.30
.99
.57
.36
.34
.30
23.63
35.69
35.11
15.57
10.
34.
13.
45.
17.
87.
36.
3.
35.
33.
5.
31.
38.
34.
29.
34.
32.
20.
,79
,77
55
89
84
36
10
14
76
42
18
81
81
37
85
34
59
48
0.85
0.64
4.
994.
93
30
3,
.61
2.
65-0.89
1.
1.
0.
0.
0.
1.
3.
1.
08
30
70
89
78
18
21
66
2.
2.
11.
35.
1,620.
2.
1.
1.
11
74
59
67
48
37
30
08
710.
1.
33
51
910.
1.
78
0.874
0.879
0.887
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
894
900
917
936
941
947
957
968
975
996
001 2378 -TCDF AN
010
022
027
061
068
074
095
0.957-1.043
15
28
0.
0.
0.
0.
1.
1.
1.
1.
000
915
935
947
000 13C12-2378-TCDF ISO
028
045
077
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 07:48 01/07/98
312
-------
Page Ho. 2 Listing of P980102B.dbf
01/07/98 Matched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
316-318
13C12-TCDD
332-334
DC
DC
DC
DC
DC
WH 25:09
2 Peaks
ML 0
20
21
21
22
WH 23
WH 24
WH 24
:00
:29
:37
:S4
:41
:38
:25
:58
0.
RO
HO
RO
RO
RO
0.65
13.
1,622.
22
75
--•--"Above: TCDF / TCDD Follows
S5-0.89
1
1
0
0
0
1
0
1
.74
.05
.79
.84
.95
.52
.81
.73
4 Peaks
1.
4.
1,127.
1,243.
14.
1.
7.
2.
2,390.
15
78 2.84
78 498.71
79 567.80
21 7.61
45
01
81
56
1.
090
0.908-1.092
0.
2.70 0.
629.07 1.
675.99 1.
8.03 1.
1.
1.
1.
000
948
000
013
049
093
130
155
13C12-2378-TCDD IS1
13C12- 1234 -TCDD RSI
332-334
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO-Ratlo Outside Limits
-------
fU.eiP9UOJ.OJ tl-923 Acqi7-JXN-y» 06:29i27 EH-
303.9016 Sxp, 03225
XSIAKGLX LABS TfJCti 193-196 XLH44376A
23:43
SIS 70 f
22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24
Tilast9B0102 tl-923 Acqs7-JXN-98 06:29:27 XI+ Voltage SIX 70P
315.9419 Eip:DB225
XBIABGLX LABS Text: 193-196 TLH4437SA
IOCS 23 05
95.
90:
85:
70.
65.
60:
"-
50:
45.
40:
3S.
30:
25.
20:
15.
10:
5l
.0.0X0
Time
-2.0X6
il.9E6
-.1. 8K6
11.7X6
:1. 6X6
'•.1.5X6
.1.4X6
'.1.3X6
il.2X6
.1X6
.0X6
J.OXS
.8.0X5
.7.0X5
-.6.0X5
.5.0X5
.4.0X5
.3.0X5
.0X5
.0X5
22:36' 22:48' 23ib6' 23:12 23:24 23i36 23t48 24*:00 24:12' 24:24' 24i36
.0.0X0
24:48 25:00 25:12 25:24 Hme\
314
-------
\Kl*,f980103 K-923 Acq,7-MN-DU 06,39:27 EH- Voltage 31* 70P Xoim.,417
303.3016 BSUB(256r30,-3.0) PXD(5,3,1,0.10%, 1668.0,0.00\,r,f) Xxp,DB225
TRIAHGLX LASS Text, 193-196 TLH44376A
100* A6.43X5
BO.
SO.
40.
20.
A3.45X5
A3.51X5
A2.34X5
A1.B3XS | A3.32X5
JU..56X5
A3.61X4
•A.
15.00 20.00 21:00 22,00 23iOO 24iOO
ril»,P980102 tl-923 Acqi7-JJUT-98 06i29t27 XX+ Voltage SIS 70P Boiae,52S
305.8987 B30S(256,30,-3.0) PKD(5,3,l,0.10\,2100.0,0.00\,r,r) XxptDB225
TSIASSLX LASS Tart 1193-196 TLH44376A
100\ AS 4X5
25100
so:
60.
40.
20:
A4.59X5
A2.67X5
A
A3.1BX5 A3.43X5
A2.61X5 I A1.44X5
,2.24X5
A
A2.05X5
A2. 78X4
J5iOO 20>00 21i00 22.00 2J.OO 2<.00
rila*P9B0102 tl-923 Acqt7-J7OT-98 06i29t27 XI+ Voltage SIS 70P ffoitet643
315.9419 BSUB(256,30,-3.0) PXD(S,3,l,0.10\,2572.0,0.00\rr,T) Kxp,DB22S
ZBXANBZZ LASS Tart;193-196 TLIt44376A
J004 A7.}OX6
80.
60.
40.
20.
25100
19,00 20,00 21:00 22.00 23.00 24.00
r±letP980102 tl-923 Acqi7-JAS-9B 06,29,27 EH- Voltage 5X8 70P Soiaet594
317.9389 BSUB(256,30,-3.0) PKB(5,3,l,0.10\,2376.0,0.00\,r,r) XxptDB225
TRIANGLE LABS Tejct: 193-196 TLH44376A
100* A9.10X6
80.
60.
40.
20.
25.00
15.00 20.00 21 .-00 22.00 2JiOO
F±J.»,P980102 tl-923 Acq,7-JXX-98 06,29,27 XH- Voltage SIS 70P
375.8364 XxftDB225
TRIAHSLE LABS Toxt,193-196 TLH44376A
24,00
25,00
-9.6X4
.7.7X4
.5.7X4
-3.8X4-
.1.9X4
0.0X0
Time
-1.3X5
'.1.1X5
.7.9X4
-5.3X4
-2.6X4
0.0X0
Time
-2.0X6
'.1.6X6
.1.2X6
.7.9X5
.4.0X5
0.0X0
Time
-2.4X6
.1.9X6
-1.4X6
.9.7X5
-4.8X5
0.0X0
Time
25,00
315
-------
319.8965 BSVB(256,30,-3.0) PXD(5r3,l,0.10\,1376.0,0.00\,T,T) Xxp,DS225
TSIAIISLX LABS Text: 193-196 TLI944376A
lOOi
80.
60.
40.
20.
I
jl A1.05E5
H
1 A4.29X4 «« »„_,
II ' I ».-»» ----- - A8.59X4 " ' •
JUa.74J* A3. 38X4 M,
ll-J\.' -A A A _A7-f"3WV U ^ULJ^^^^^I^
20:00 21:00 22:00 ' ' '23:00 ' ' '24': 00 ' ' ' 25
5.7X4
.4.6X4
.3.4X4
.2.3X4
JL.1X4
00 Tiae
rile,P980102 91-923 Acq,7-J3Ur-98 06:29:27 XI+ Voltage SIS 70P Noise, 4 09
321.8936 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,1636.0,0.00\,T,T) XxpiDB225
TSIAWGLX LABS Text, 193-196 TLH44376A
ion
80.
60.
40.
20.
J
1 AI-l"'rS
I
II A1.07X5
UL4.19X4 ^-30X4 A
Jl 11 .. .OH L«W\. ".-ftfL .«•«« . . _H-»«.
'20:00 ' 21:00 '22:00 23:00 24:00 ' ' ' 25
6.8X4
.5.4X4
.4.1X4
.2.7X4
.1.4X4
00 Time
rile:P980102 H-923 Acq:7-J3UT-98 06:29:27 EI+ Voltage SIS 70P Noise, 388
327.8847 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,15S2.0,0.00\rr,r) Xxp:DB225
TRIANGLE LABS Text: 193-196 TLH44376A
ion
80.
60.
40.
20.
0.
A1.06X7
n
I \ A7.02X5
1 \ A
20:00 21:00 22:00 ' ' ' '23:00 ' ' '24:00 ' 25
3.0X6
.2.4X6
.1 . 8X6
.1.2X6
'.5.9X5
0.0X0
00 Time
rile:P980102 91-923 Acq,7-JAB-98 06:29:27 EI+ Voltage SIS 70P Noise, 56 5
331.9368 BSUB(256,30,-3.0) PXD(S,3,1,0.10\,2260 .0,0 .00\,r,T) Xxp:DB225
TSIAIISLX LABS Text: 193-196 TLI944376A.
1001
80.
60.
40.
20.
0.
AS
1
<8E6
'20:00 ' ' 21:00 ' ' '22:00 23:00 24:00 25:
.1.4X6
.1.2X6
.8.6X5
.5.8X5
.2.9X5
0.0X0
00 Time
rlle,P9S0102 91-923 Actj:7-JUr-98 06:29:27 XH- Voltage SIS 70P Noise: 326
333.9338 BSUS(2S6, 30, -3.0) PKD(5,3, 1,0.10\, 1304 .0,0. 00\,T,T) Xxp:DB22S
TSIAIISLX LABS Tort: 193-196 TLH44376A
100\
80.
60.
40.
20:
o:
A6.29X6 -1.7X6
I
l\ 1
•
20:00 21:00 22:00 ' ~23:00 2t\OQ 25
.1.4X6
J..OX6
.6.9X5
.3.4X5
0.0X0
00 Time
316
-------
rileiP980102 tl-923 Acq:7-JXK-98 06:29:27 XI+ Voltage SIS 70P
303.9016 Szp:DB225
TSIAHGLX LASS Taxt:193-196 TLH44376A
1001
80.
60.
40.
20.
0
21;
20, 38 A
II
15:43 '
10 1 ^fljl 20 1 19
1. "j^M/ljtAllr W 1
19:00 ' ' 20:00 21:00
10 ,.5.5*4
3.3 ^J
,
22s 31 \
21 : 51 1 22 : 55 1 A
ft i A 1 ii (1 In T"
UWI/IA/I. Jvl/l/VL A. 75A15
.7.5W
.5.5X4
.4.0Z4
L2.0JT4
' 0 . 0*0
22:00 2J:00 24:00 25:00 TdMe
rile:P980102 tl-923 Acq:7-JAS-98 06 1 29 1 27 XH- Voltage SIX 70P
315.9419 Kxp:DS225
XXIAOSLX LASS Text:193-196 TLIt44376A
1001
80.
60.
40.
20.
15:00 20:00 21:00
23 t 05 2.0X6
r l\
Ll.5*5
L1.2Z5
.8.0X5
'-4.0X5
' 0.0X0
22:00 23:00 24:00 25:00 T±me
rile :P9 80102 tl-923 Acq:7-JAS-98 06:29:27 XI* Voltage SIX 70P
319.8965 Xxp:DS225
TSIAtTSLX LASS Tmxtil93-196 ZLIt44376A
ion
sol
50:
40:
20:
0'
15:17
15,50
\ ,n ,„
20:30
II II .
-.6.1X4
21:55
1 Jl /, A alsr15 A -.--«- «-no
.. . ..^.'^ 1 L~J L JUJU/
15ioO 2ol00 21,00
\^jJW U X^ 'l'27 23:54 34:28 JL
U-V** W ". . i . -A ^"n-i --i U*l i_ -Tr-i-ni _ -* .«xn«rji_rs ' . i.
.4.8X4
.3 . 6X4
.2.4X4
.1.2X4
• n nwn
22JOO ' 2J^OO ' 24^00 ' 25,00 Tine
T±letP980102 tl-923 Acq:7-Jlor-98 05,25,27 EH- Voltage SIS 70P
331.9368 Xxp:DS225
TXIANGLZ LASS Text: 193-196 TLXt44376A
ion
80:
50:
40:
20:
0:
•
15,00 2oiob 21:00
21:54
1 A
''/\
-.1.4X6
.1.2X6
.8.7X5
.5.8X5
.2.9X5
0.0X0
22:00 2jiflO 24^00 25,00 T±me
rile:P930102 tl-923 Actj:7-JZN-98 05,25,27 Xl-h Voltage SIS 70P
292.9825 Exp:DB225
TSIAKSLX LASS Text: 193-196 XLIt44376A
1004
80:
50:
40:
20:
o:
^^^8j57 15,25 15,57 20,25 20,54
^V W If-^
19:00 20,00 21:00
21,JO 22,05 22?47 2J/J4 _ 24:07 _24:42 _ .„
.5.0X6
14.0X6
-.3.0X6
.2.0X6
.1.0X6
0.0X0
22iflO 23:00 ' ' 24iob 25^00 Mjie
r±lo:P9B0102 tl-923 Acq:7-J3ur-98 05,25,27 XI+ Voltage SIS 70P
330.9792 Kxp:DS225
TXIAOSLX LASS Text: 193-196 TUt44376A
1001
80:
50:
40:
20:
0:
19:37 20:15 21:12 21,42 22.-J5 23:09 23:5934:24 24:58
i i M- . n«n^i i I, m rJirti^**J*^YT^fn*"^ rtr^r^^^rV**^ -*^i*^*"ift flf*"^nfl i !ll*ii^Mi"* "i ^n i'*i '* nrtrl ^r*^-*™»**inrrtrit*'*i1i ni" *n i*1ff
19:00 20,00 21JOO
.4.2X6
.3.4X6
.2.5X6
.1.7X6
.8.4X5
0.0X0
22^00 2jiflO 24^00 25^00 Ma«
317
-------
ft'P988182
Ref, lass 292,9825 Peak top
Height ,95 volts Span 288 ppi
Systa f He naie
Data file naie
Resolution
Groj) niter
lonlzatlon lobe
Switching
, lasses 292,9825,
f) 292,9825
8 383,9816
C 385,8987
D 315,9419
E 317,3389
F 319,8965
6 321,8936
H 327,8847
I 338,9792
J
K
L
H
1
El*
VOLlffiE
388,9761
338,9792
331.9368
333,9338
375,8364
Channel I 338,9792 Peak top
Height ,78 wits Span 288 ppi
318
-------
TLI Project: 44376A
Client Sample: 198/199/205/208 ft.
Method 23 PCDD/PCDF Analysis (a)
r Analysis File: U980036
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAIN
194-59-18A/B
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyse
12/17/97
12/29/97
01/07/98
n/a
U980026
JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMTT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2.3,7,8-TCDD
1A3.7.8-PCCDD
1A3.4.7.8-HXCDD
U,3,6.7,8-HxCDD
l,2J,7,8,9-HxCDD
1.2J,4.6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3.7,8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
^2.3,4,7,8-HxCDF
R2,3,6,7,8-HxCDF
2.3,4,6,7,8-HxCDF
lA3.7.8,9-HxCDF
1,2^,4,6,7,8-HpCDF
1.23,4,7,8.9-HpCDF
1,2^,4,6,7,8.9-OCDF
totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF •
Total PeCDF
Total HxCDF
Total HpCDF
^ •. ^%*- •.•£••; '"• ,' ^
> Aim; pg| 0 £«. '' ^ fcMPC ^' - ^
0.07
0.48
0.26
0.46
0.57
1-2
0.65
7.6
1.7
2.9
6.0
2.3
2.4
0.15
6.1
0.72
1.5
Amt {ng) Number DL EMPC
13.2 11 13.6
11.0 9 17.2
9.2 7
2.8 2
41.5 15 41.8
44.2 16
25.8 10 272
10.3 4
Ratfo
0.65
1.71
1.11
1.12
1.14
0.98
0.77
0.76
1.49
1.51
1.25
1.27
1.24
1.20
1.08
1.06
0.87
";RT" , £&$£ ^'
25:20 PR_
29:37
32:44
32:50
33:08
36:04
39:37
24:41
28:35
29:17
32:03
32:09
32:38
33:24 PR_
35:02
36:33
39:50
, Flags
—
Page 1 of 2
MTT2 JSR »ijDl. LAIS 6. KUXI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:0301/10/98
319
-------
TLI Project 44376A
Client Sample: 198/199/205/208
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980036
"
t.giMl r.^JX
,wtfirtl&S&kadra&
l3C,z-2,3,7,8-TCDF
13C12-2.3,7,8-TCDD
t3C,2-1^3,7,8-PeCDF
13C12-l,Z3.7,8-PeCDD
13Ci2-lA3,6J,8-HxCDF
13C12-l.Z3,6,7,8-HxCDD
13C,2-lA3,4.6,7,8-HpCDF
13C12-l,2,3A6,7,8-HpCDD
13C,rlA3.4,6,7,8,9-OCDD
Surrogate Standards {Type A)
13C,r2,3,4,7,8-PeCDF
13C12-l,2,3A7,8-HxCDF
13C12-U,3,4.7,8-HxCDD
13C12-U,3,4,7,8,9-HpCDF
•te ^ " jit ml ffi At
^iTO9atft€tarjo«H^{rype A|
37CU-2,3,7,8-TCDD
Alternate Standards {Type A}
13C,2-l,2,3,7.8,9-HxCDF
13C12-23,4,6,7,8-HxCDF
Recovery Standards
13C,rl^3,4-TCDD
13C12-lA3,7,8,9-HxCDD
•- a- <" Jrtj^
' **"*»• V*S
3.3
3J
3.4
2.7
3.6
3.9
3.2
3.2
5.9
Amtv&$J
3.5
3.2
3.2
3.5
A * t
- ***"** v'Sl
3.2
Amt (ng]
3.4
3.4
-
l/,,,^^-^.^^ «||»-»r^»
* '^//^^«f'^!r?y*?^
82.3
81.4
86.0
66.4
90.4
98.6
80.7
80.9
73.2
1 .., % Recovery
86.9
79.7
78.9
88.3
•• «/'&
% Recovery
79.1
% Recovery
84.6
85.6
vf
&*(«& \ A-^ ^y
-o^-'rTl<«-«J
409b-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
"
40%-130%
40%-130%
40%-130%
40%-130%
^
'
-
40%-130%
40%-130%
_.
„ ^^•^Whtt l
^i^^^SE;
0.75
0.80
1.55
Ul
OJO
1^0
0.44
1.04
0.85
Ratio
1.52
0.51
1.20
0.39
; Ratio
0.52
0.52
Ratio
0.82
1^3
i^l$*vuiv^ : -xvi \f
24:38
25:21
28:35
29:36
32:09
32:49
35:01
36:03
39:37
^/ tff
29:16
32:03
32:44
36:33
me
nT
25:22
RT
33:24
32:38
RT
25:11
33:08
-
>,jv^E^^v
^^_^^
_
—
Flags
—
c,___ i
Ftass |
—
Ffa^s
—
Flags
Data Reviewer
01/10/98
Page2of2
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:03 01/10/98
-------
Initial'
.Date.
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
1.00
01/10/98 Matched GC Peata / Ratio /
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total. Area. ..
TCDF ' 0.65-0.89
304-306 DC NL 0
NK 21
K 22
K 22
K 22
K 22
K 23
K 23
23
24
24
24
24
25
25
25
26
:00 RO
:31
:01
:15
:38
:58
:21
:37
:51
:05
:16
:29
:41
:06
:18
:34 RO
:24
0.57
0.76
0.73
0.74
0.75
0.74
0.73
0.76
0.75
0.76
0.75
0.77
0.76
0.73
0.74
0.64
0.80
304-306 16 Peaks
k'3C12-TCDF
F 16-318 DC NL 0;
DC WL 22:
DC WL 23:
23:
24:
24:
24:
25:
DC WH 25:
DC WH 26:
DC WH 26:
DC WH 26:
0
00 RO
:28 RO
37
53
05 RO
13
38
05
50 RO
09
24 RO
30 RO
316-318 5 Peaks
TCDD
320-322 DC NL 0:
NK 22:
NK 23:
K 23:
K 24:
24:
0.
00 RO
50
13
31 RO
11
28
.65-0.89
1.03
1.46
0.83
0.70
0.42
0.69
0.75
0.70
7.97
0.87
1.49
1.12
4
3
4
19
12
14
10
13
17
6
6
28
6
6
157
282
,063
,831
,466
,441
,692
,662
,358
,940
,640
,717
,075
,671
,986
,201
846
812
,407
.76
.74
.01
.16
.79
.43
.27
.01
.79
.47
.48
.25
.60
.04
.66
.45
.39
.54
Ret. Time
Area . Peak .
1
'1
1
8
5
6
4
5
7
2
2
12
2
2
,753
,616
,897
,306
,404
,197
,487
,958
,611
,885
,650
,359
,947
,627
368
361
1. . Area. Peak.
.59
.08
.27
.09
.45
.96
.46
.37
.67
.23
.85
.70
.67
.79
.23
.55
2,310
2,214
2,568
11,135
7,287
8,464
5,870
7,982
10,028
3,832
3,424
16,311
4,038
3,573
579
450
2.. Rel.RT Compound. Name. . ID.
0.867-1.079
.15
.93
.89
.70
.98
.31
.55
.42
.80
.25
.40
.90
.37
.87
.76
.84
0.000
0.873
0.894
0.903
0.919
0.932
0.948
0.959
0.968
0.978
0.985
0.994
1.002 2378 -TCDF AN
1.019
1.027
1.038
1.072
0.959-1.041
12,
12,
13
18
90.
25,
16,
85.
,159.
215.
11.
41.
9.
9.
,502.
mj»>T\*
.54
.59
.58
.45
.76
.64
.47
,23
13
34
63
75
55
s t
65-0.89
0.14
0.78
0.79
0.94
0.77
0.84
15,
10,
1,
3,
1,
6.
687.
610.
112.
397.
959.
85
02
11
82
69
57
5,
10,
7,
34.
,220.
88.
.50
,29
.97
.14
50
14
17
50
6,939,
126,
.95
.19
.67
.33
.73
0.000
0.912
0.959
0.970
0.978
0.983
1.000 13C12-2378-TCDF ISO
1.018
1.049
1.062
1.072
1.076
6,
4,
1,
885.
676.
592.
476.
894.
29
84
75
47
32
8,801.
5,933.
628.
1,921.
1,065.
0.895-1.047
73
27
71
22
25
0.000
0.901
0.916
0.928
0.954
0.965
Flags.
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:04 01/10/98
321
-------
Page No .
01/10/98
Compound/
2 Listing
Matched
M_Z.... QC.Log Omit Why ..RT. OK
M
AN
D
320-322
37C1-TCOD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
0
0
M
AN
24:50
25:17
25:20
25:33
35:42
25:54
D SN 26:12 BO
26:22
12 Peaks
DC NL 0:00
DC WL 22:43
DC WL 22:50
DC WL 23:07
DC WL 23 : 14
24:01
24:20
25:22
25:46
25:57
26:03
6 Peaks
0.
DC NL 0:00 RO
24:11
24:51 RO
25:11
25 : 21
25:41 RO
25:51 RO
26:05 RO
26:24
8 Peaks
1.
DC NL 0:00
26:36
0 SN 26:52
D SN 27:04 RO
27:14
27:21
27:36
27:44
27:54
28:12
28:19
28:31
28:35
of U980036B.dbf
GC Peaks / Ratio /
Ratio Total. Area. . .
0.86
0.79
0.65
0.81
0.81
0.84
1.27
0.70
65-0.89
2.43
0.74
4.38
0.82
0.80
0.64
0.61
0.27
0.78
918.86
3,500.00
188.30
464.29
427.28
193.86
12.78
158 . 62
38,618.42
39.27
46.06
229 . 28
724.87
343.92
11,516.80
177.87
7,256.94
885.08
43.47
23.06
19,903.22
10.35
62.94
6.30
10,069.98
9,167.93
465.42
144.24
42.02
42.23
20,001.06
32-1.78
1.74
1.56
1.55
2.04
1.68
1.59
1.56
1.52
1.53
1.48
1.52
1.55
1.49
5.59
11,155.56
150.42
310.39
370.11
363.60
3,611.75
24,471.61
6,404.81
10,309.80
12,795.51
5,630.00
4,350.00
Ret. Time
Area . Peak . 1 .. Area . Peak . 2 . . Rel. RT Compound. Name. . ID.. Flags.
425.60
1,540.00
74.30
207.66
191.45
88.49
65.30
11,516.80
177.87
7,256.94
885.08
43.47
23.06
26.71
15.61
4,543.14
4,076.84
202.47
62.75
18.28
18.48
6,793.30
231.78
223 . 34
2,199.59
14,748.60
3,870.62
6,148.96
7,717.79
3,420.00
2,600.00
493.26 0.980
1,960.00 0.997
114.00 0.999 2378 -TCDD AN PR
256.63 1.008
235.83 1.014
105.37 1.022
1.034
93.32 1.040 J
0.921-1.079
0.000
0.896
0.901
0.912
0.917
0.947
0.960
1.001 37C1-TCDD CLS
1.016
1.024
1.028
0.921-1.079
0.000
36.23 0.954
3.56 0.980
5,526.84 0.993 13C12- 1234 -TCDD RSI
5,091.09 1.000 13C12- 2378 -TCDD IS1
315.05 1.013
103.30 1.020
68.19 1.029
23.75 1.041
0.925-1.065
0.000
4,362.26 0.931
0.940
0.947
138.33 0.953
140.26 0.957
1,412.16 0.966
9,723.01 0.970
2,534.19 0.976
4,160.84 0.987
5,077.72 0.991
2,210.00 0.998
1,750.00 1.000 12378-PeCDF AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:04 01/10/98
322
-------
Page No. 3
01/10/98
Compound/
M_Z.... QC.Log Omit Why
Listing of 0980036B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total. Area. .. Area. PeaJc. 1. . Area . Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
340-342
13C12- PeCDF
352-354
352-354
PeCDD
356-358
D
28
28
29
29
29
30
:45
:52
:17
:26
:45
:15
1.62
1.48
1.51
1.51
1.41
1.55
16 Peaks
DC NL 0
27
27
28
29
29
30
1
:00 RO
:43
:57 RO
:35
:16
:59
:16 RO
.32-1.78
0.93
1.51
1.18
1.55
1.52
1.47
0.82
6 Peaks
• l~ —
DC NL 0
DC WL 27
1.
:00 RO
:36 RO
27:50 RO
0
D SN 28:06 RO
28:
28:
28:
:19 RO
:33
41
28:52
29:03
29:08
356-358
13C12- PeCDD
368-370
368-370
29:
29:
29:
29:
30:
19
28 RO
37
45
05
.32-1.78
1.18
1.01
1.11
0.22
1.11
1.56
1.54
1.59
1.40
1.65
1.54
1.06
1.71
1.45
1.73
12 Peaks
DC NL 0:
28:
28:
DC SN 29 :
29:
29:
30:
30:
30:
30:
1.
00 RO
32 RO
40 RO
24
36
44
11
16
25 RO
29 RO
32-1.78
1.00
2.38
2.44
1.62
1.51
1.64
1.53
1.57
4.01
5.20
8 Peaks
4,404.76
7,634.24
7,393.53
11,230.76
2,235.72
670 . 99
113,032.75
0.46
124 . 61
30.76
9,886.79
8,295.52
19.08
17.19
18,373.95
0.33
43.33
7,075.03
266.58
477.24
5,339.74
1,033.63
3,538.58
523.46
1,020.77
1,401.26
664.73
637.41
512.15
412.94
22,636.94
2,723
4,550
4,442
6,747
1,307
408
74
18
6,009
5,003
11
10
.47
.35
.51
.99
.44
.34
.91
.70
.41
.64
.37
.45
1,681.29
3,083
2,951
4,482
928
262
49
15
3,877
3,291
7
12
.89
.02
.77
.28
.65
0.
.70
.79
.38
.88
.71
.68
1
1
1
1
1
1
860
0
0
0
1
1
1
1
.006
.010
.024 23478- PeCDF
.030
.041
.058
-1.140
.000
.970
.978
.000 13C12-PeCDF 123
.024 13C12- PeCDF 234
.049
.059
AN
IS2
SOR1
4,300.51
290.
3,250.
626.
2,171.
305.
635.
848.
404.
402.
303.
261.
.09
.04
17
93
25
00
63
05
46
14
81
3,884
261
2,089
407,
1,366.
218.
0.935-1.022
.25
.68
.70
.46
.65
21
385.77
552.63
381.39
234.
209.
151.
95
01
13
0
0
0
0
0
.000
.932
.940
.949
.957
0.965
0,
0.
0.
.969
.975
.981
0.984
0.990
0.995
1.001 12378-PeCDD
1.
1.
005
016
AN
0.865-1.135
0.26
7.85
4.51
2.54
3,947.50
1,019.94
29.47
27.45
7.52
4.79
5,049.03
7.
4.
2,375.
633.
17.
16.
11.
9.
32
32
84
98
82
75
82
78
3.
1.
1,571.
385.
11.
10.
2.
1.
08
77
66
96
65
70
95
88
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
964
968
993
000 13C12- PeCDD 123
005
020
023
028
030
IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:04 01710/98
323
-------
Page No.
01/10/98
Listing of 0980036B.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HxCDF
374-376
AN
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
DC NL 0
31
31
31
31
31
32
32
32
32
32
33
33
1
:00
:05
:14
:24 RO
:32
:41 RO
:03
:09
:16
:26
:38
:24
:29
----- ADOVC: reuiu /
.05-1.43
1
1
1
1
1
1
1
1
1
1
1
1
1
.21
.24
.24
.46
.26
.76
.25
.27
.29
.22
.24
.20
,28
12 Peaks
DC NL 0
31
32
32
0.
:00 RO
:14 RO
:03
:09
32:38
33
:24
297.45
6,020.36
14,074.33
1,745.52
2,129.23
763.93
10,793.84
5,185.94
1,819.19
2,129.23
4,213.70
233.00
1,053.00
SO, 161. 27
nxuuc follows ----------
3,332
7,785
1,139
1,189
600
5,994
2,901
1,024
1,168
2,329
127
591
.11
.94
.51
.13
.51
.93
.21
.12
.93
.54
.00
.00
2,688
6,288
779
940
341
4,798
2,284
795
960
1,884
106
462
.43-0.59
2.66
0.60
0.
0.
0.
0.
5 Peaks
1.
DC NL 0:00 RO
31:35
D SN 31:
32:
32:
32:
32:
32:
33:
42 RO
01
13
23
44
50
08
,51
50
,52
52
8.34
53.62
4,667.95
7,103.73
6,067.75
4,623.28
22,516.33
05-1.43
0.
1.
1.
1.
1.
1.
1.
1.
1.
87
22
92
24
21
09
11
12
14 .
7 Peaks
DC NL 0 :
32:
32:
32:
32:
32:
32:
33:
1.
00 RO
13
19 RO
26
36 RO
44
49
08
05-
1.
1.
2.
1.
1.
1.
1.
1.
1.43
72
43
02
37
69
20
20
23
7 Peaks
47.22
991.11
47.85
6,242.42
2,395.19
507.45
285.62
644.49
763.94
11,830.22
21
1,582
.16
.28
2,366.84
2,065.04
1,584
.73
35
3,085
4,736
4,002
3,038
0.962-1.047
.25
.39
.25
.10
.04
.91
.73
.07
.30
.16
.00
.00
0.000
0.967
0.971
0.977
0.981
0.985
0.997
1.000
1.004
1.009
1.015
1.039
1.041
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
AN
AN
AN
AN
0.876-1.124
.51
.67
.89
.71
.55
0.000
0.971
0.997
1.000
1.015
1.039
13C12-HXCDF 478
13C12-HXCDF 678
13C12- HxCDF 234
13C12-HXCDF 789
SCTR2
IS4
ALT 2
ALT1
Uvfnn Vn 1 1 nua .««___
545.
3,456.
1, 310 .
265.
150.
339.
406.
.32
48
99
09
13
85
93
445.
2,785.
1,084.
242.
135.
304.
357.
0.958-1.014
.79
94
20
36
49
64
01
0.000
0.962
0.966
0.976
0.982
0.987
0.997
1.001
1.010
123478-HxCDD
123 67 8 -HxCDD
123789-HxCDD
AN
AN
AN
0.970-1.030
6.41
20.15
3.58
6.73
3.38
3,309.24
5,730.34
5,839.49
14,912.91
11.
3.
3.
2.
1,803.
3,120.
3 , 218 .
85
23
89
55
79
02
81
8.
1.
2.
1.
1,505.
2,610.
2,620.
30
60
84
51
45
32
68
0.000
0.982
0.985
0.988
0.993
0.997
1.000
1.010
13C12-HXCDD 478
13C12-HXCDD 678
13C12-HXCDD 789
SOR3
IS5
RS2
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:04 01/10/98
Q9
o
24
-------
Page No.
01/10/98
Listing of O980036B.dbf
Matched GC Peaks / Ratio / Ret. Tiae
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
D
D
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
DC
NL 0
35
35
35
36
:00
0
RO
:02
:18
:27
:33
.88-1.20
1
.41
1.08
1
1
1
.15
.02
.06
4 Peaks
DC-
NL 0
35
36
:00
:01
:33
0
RO
.37
1
0
0
2 Peaks
DC
DC
NL 0:00
WL 35:11
0
RO
RO
35:18
DC
DC
36
:04
NH 36:24
RO
NH 36:31
.38
0
0
0
0
1
1
-0.51
.17
.44
.39
-1.20
.30
.58
.98
.98
.56
.04
2 Peaks
DC
NL 0:00
35:
36:
18
03
0.
RO
18.54
8,272.58 4,286.07
1,862.34 995.50
2,357
767
13,259
8
3,872
2,742
6,614
.44 1,189.54
.32 394.21
.68
.67
.29 1,177.52
.35 776.40
.64
f / UK/*VU-I e»— i t _....
0.996-1.049
0.000
3,986.51 1.000 1234678-HpCDF
866.84 1
1,167.90 1
373.11 1
0.943
0
2,694.77 1
1,965.95 1
.008
.012
.044 1234789-HpCDF
-1.114
.000
.000 13C12-HpCDF 678
.044 13C12-HpCDF 789
AN
AN
IS6
3 OH 4
0.975-1.005
2
30
1,333
.16
.17
.09 660.67
1,055.05 522.16
13.12
9.45
2,383
.14
88-1.20
1.66
1.
,04
1.04
2 Peaks
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL 0:
WL 34:
WL 34:
WL 35:
WL 35:
WL 35:
35:
SN 37:
SN 38:
SN 38:
SN 38:
39:
40:
40:
00
41
54
01
13
23
50
24
10
37
47
50
18
18
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
40:48
76-1.02
3.
3.
1.
1.
17.
1.
2.
13.
0.
5.
5.
0.
0.
2.
0.
03
70
19
59
56
81
04
61
92
71
60
87
69
13
78
5 Peaks
5.67
16,
,44 8.40
3,428.33 1,745.27
3,444.77
: HpCDD / Octa-CDD and CDF
2.
1.
3.
4.
1.
6.
3.
0.
2.
0.
0.
1,242.
82
25
65
16
29
03
59 3.87
43
17
79
47
00 579.00
10.38 4.89
7.
84 8.84
6.46 2.84
0
0
672.42 0
532.89 1
1
.000
.976
.979
.000 1234678-HpCDD
.010
AN
1.013
0.972-1.028
0.000
8.04 0.979
1,683.06 1.000 13C12-HpCDD 678
IS7
Follows
0.899-1.101
0.
0.
0.
0.
0.
0.
1.90 0.
0.
0.
0.
0.
663.00 1.
7.11 1.
4.15 1.
3.62 1.
000
875
881
884
389
893
905
944
963
975
979
005 OCDF
017
017
030
AN
1,270.27
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11 =0401/10/98
-------
Page No.
01/10/98
Listing of 09800368.dbf
Hatched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
OCDD 0.76-1.02
458-460 DC NL 0:00 RO 1.67 0.06
39:37 0.77 418.68 181.84
40:00 RO 1.86 6.05 5.94
458-460 2 Peaks 424.73
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.33 0.06
39:37 0.85 4,656.23 2,144.76
470-472 1 Peak 4,656.23
0.899-1.101
0.000
236.84 1.000 OCDD AN
3.20 1.010
0.996-1.004
0.000
2,511.47 1.000 13C12-OCDD IS8
Column Description "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
nie:O980036 tl-724 Acqi 7-JAK-1998 01:28:06 SC EH- Voltage SIS 70S Koiae:61507
303.9016 T:2 SSUB(256, 30, -3.0) PXD(9,5,3,0.10\,246028.0,1.00\,r,T) SxpiHDBSUS
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341.8567 Ts2 BSVB(256e 30, -3.0) PXD(7,5,3r0.10\,4Q84.0r1.00\,TrX) XzpsSDBSUS
XSIASSZX LABS Text: 19 8/199/205/208 XLIt44376A
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351.9000 Ts2 BSUB(256r 30, -3. 0) PXD(7,5,3,0.10\r5S6.0,1.00\,T,X) XxpsKDBSUS
XSIASSLX LABS Xext:198/199/205/208 TLIt44376A
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353.8970 Ts2 BSU3(256, 30, -3.0) PKD(7,S,3,0 .10\,S92.0,1.00\,r,X) XxpsNDBSUS
XSIASSLX LABS Texts 198/199/205/208 TLIt44376A
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330.9792 r:2 ExpsSDBSOS
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409.7974 Tt2 EXpsSDBSUS
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353.8546 r>3 3803(356,30, -3.0) PXD(5,5,3, 0.05\,408.0,1.00\,r,T) XJCpsXDBSUS
LASS Tart: 198/199/205/208 TLH44376A
100* A4.30X7 A3.25X7
A3.62X6
27:48 28*, 00 38,13 28,24 28,36 28,48 29,00 39,13 29,24 39,36 2948
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357.8516 r,2 BSOB(256,30,-3.0) rXO(5,5,3,0.05\,332.0,1.00\,T,T) XxptSDBSUS
TStlAIKLX LABS Tort, 198/199/205/308 TLX944376A
1001 A3. 88X7
3o,24
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367.8949 Ts2 SSUS(256, 30, -3.0) PXD(Sr5,3,0.05\,312.a,1.00*,T,r) XrpsRDBSUS
TRIAXGLX LABS Text:198/199/205/208 TLH44376A
100\ A.2.38X7
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27,48 28,00 28,12 28,24 28:36 28,48 29,00 29,12 39,24 39,36 29,48 30,00 30,12 30,24
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369.8919 f,2 BSUB(2S6,30,-3.0) PXD(5,5,3, 0.05%, 330.0,1.00\,T,T) XxptKDBSUS
TRIAKSLX LABS Taxt,198/199/205/208 TLH44376A
100\ JU..57X7
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30.9792 r,2 XlpiSDBSUS
TBIANGLX LABS T*xt,198/199/20S/208 XLIt44376A
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33
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373.8308 f:3 BSUS(2S6,30, -3.0) PXS(7,5,3,0.10\,325884.0,1.00\,r,T) XxpiHDBSUS
TBIANGLX LASS Text:198/199/205/208 XLIt44376A
1001 A7.79X7
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r±let0980036 tl-385 Acq: 7-JUT-1398 01:28,06 GC XI + Voltage STB 70S Hoiae:67253
375.8178 Tt3 SSOS(256, 30, -3.0) PXO(7,5,3,0.10\,269012.0,1.00\,r,T) StptHOBSVS
XSIASGLX LASS Text: 198/199/205/208 TLH44376A
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rl2e:O980036 tl-385 Acq: 7-JAS-1998 01:28:06 GC XI+ Voltage SIX 70S Koiae:7338
383.8639 T,3 SSUS(256,30, -3.0) fXD(7,5,3,0.10\,29352.0,1.00\,r,T) XxptSDBSUS
TSIAIfSLX LASS Text:198/199/205/208 TLIt44376A
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10980036 tl-385 Acq: 7-JZS-1998 01:28:06 SC XI+ Voltage SIS 70S Koiae:2761
385.8610 T,3 BSUB(256,30,-3.0) fXS(7,5,3, 0.10\,11044 . 0,1. 00\,T,1) Kxp-.SDSSUS
XSIAHGLX LASS Text: 198/199/205/208 ZLH44376A
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TilaiU980036 tl-385 Acq: 7-JAN-1998 01:28:06 SC XH- Voltage SIS 70S
392.9760 Tt3 EiptlTDBSUS
TRIANGLE LABS Text: 198/199/205/208 TLIt44376A
100J
80:
50:
40:
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31:10 31:21
32:49
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445.7555 Tt3 XxpiSDSSUS
TXIAKSLX LASS Tart: 198/199/205/208 TLH44376A
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389.8156 n3 3303(356,30, -3.0) PXD(7,S,3,0.10\,52276.0,1.00\,T,X) XxptNDBSUS
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391.8127 Ti3 BSU3(256,30,-3.0) f*D(7,5,3,0.10%, 60072.0,1.00\,T,T) KxpiHDBSaS
TSIASSLX LABS Text: 198/199/205/208 TLH44376A
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31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24
Til»:U980036 tl-385 Acq: 7-JJUT-1998 01:28:06 SC ZI+ Voltage SIS 70S Hoists,2456
401.8558 T,3 BSUB(256,30,-3.0) rXD<7,5,3,0.10\,9824.0,1.00\rT,T) XxpsSDBSVS
XSIANSLX LABS Text: 198/199/205/208 TLH44376A
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31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
r±le,OS80036 tl-385 Acq: 7-JAtT-1998 01:28:06 SC XI* Voltage SIS 70S Soiae:1430
403.8529 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.101,5720.0,1.00*,r,T) Xxp:NDB5VS
XRIASSLX LABS Text: 198/199/205/208 XLIt44376A
1003, A2 61X7 A2.62X7
80.
60.
40.
20.
33:24 33 36
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24
r±l*:U9B0036 tl-385 Acq: 7-JAH-1998 01:28:06 SC XI* Voltage SIS 70S
392.9760 r,3 ExptHDBSOS
TSIAHOLX LABS Text: 198/199/205/208 TLII44376A
33:36
lOOi
80.
60.
40.
20.
31:28
31:51
32:49
-1.9X7
.1.5X7
'.1.1X7
'.7.6X6
'.3.8X6
'31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24
33
.0.0X0
36 Tift
332
-------
rile,0930036 tl-545 Acq, 7-JMT-1998 01:28:06 SC XH- Voltage SIS 70S Soimet6424
407.7818 r,4 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,25696.0,l.QO\rTtT) XxpiHDBSUS
TSIAOSLX LABS Text ,198/199/205/208 TLH44376A
A4.29X7
A3.94X6
35', 00 35', 12 35,24 35*36 35,48 36,00 36,12 36,24 36,36
Tile:U980036 tl-S45 Acqt 7-J2OT-1998 01,28,06 CC XX* Voltage SIS 705 Soime:4545
409.7789 r,4 3SUB(256,30,-3.0) PXD(7,5,3,0.10\,lB180.0,1.00\,r,T) XxpiSDBSUS
LABS Tart:198/199/205/208 TLH44376A
36,48
A3. 73X6
35', 00 35,12 35,24 35,36 35,48 36', 00 36', 12 36': 24 36,36 36', 48
r±la,C980036 tl-545 Acq, 7-JJOT-1998 01,28,06 SC ZH- Voltage SIS 70S Noiaa,3509
417.8253 r>4 BSUB(256,30,-3.0) PKD(7,S,3,0.10\,14036.0,1.00\rT,T) ErpiUDBSUS
TRIANGLE LABS Text, 198/199/205/208 TLH44376A
IOCS A1.1SX7
A7.76E6
3S',00 35',12 35,24 35:36 35,48 36,00 36,12 36,24 36,36
rila:U9B0036 tl-545 Acxj: 7-JXJT-1998 01:28*06 CC XH- Voltage SIS 70S Noiee:3009
419.8220 r,4 BSUB(256,30,-3.0} PXD(7,S,3,0.10\r12036.0,1.00\,r,T)
TSIASSLX LABS Textil98/199/205/208 TLH44376A
10 0\ A2.69X7
A1.97E7
36,48
35,00 35:12 35,24 35:36 35,48 36:00 36,12 36,24
rila,0980036 tl-545 Acq: 7-JAS-1998 01:28,06 SC XH- Voltage SIS 70S
430.9729 T:4 XxpiSDBSOS
TSIANSLX LABS Text: 198/199/205/208 TLIt44376A
J5AH^_^ -Vl"f__ 36:17 36:25,
36:36
36:48
-9.8X6
'•.7.9X6
.5.9X6
.3.9X6
.2.0X6
.0.0X0
'37100 TLma
-9.1X6
.7.3X6
.5.5X6
.3.7X6
.1.8X6
.0.0X0
37:00 T±ae
O.OEO
37': 00 T±me
O.OEO
37:00 Time
50:
40:
Oj
35,00 35,12 35,24 35,36 35,48 36,00 36,12 36,24
Tila,U980036 tl-545 Acq: 7-JAS-1998 01:28,06 GC XH- Voltage SIS 70S
479.7165 r,4 XxptKDBSUS
TRIANGLE LABS Texttl98/199/205/208 TLIt44376A
100$ 35; 17
80:
36,36
36,48
0.0X0
37', 00 Time
60:
40:
20:
34155
35:06
J5>00
35,12
36:41
36:20
35124
35:36
"A" 36,01 3S,09
/vy A ~\^ A
35,48
36*: 00
36:12
-3.4X4
-.2.8X4
'•.2.1X4
'.1.4X4
-.6.9X3
36:24
36:36
36,48
.0.0X0
37:00 Time
333
-------
il-545 Acgi 7-J3UT-I*** ui-.JtttU* CC SI* Volttyu SIX 70S
433.7766 Tt4 3SUB(256,30,-3.0) PKD(7,5,3,0.10\,2208.0,1.00\,r,T) XzptSDBSOS
XSIA1KLX LASS T»X*il9S/199/20S/2QB TLH44376A
100* AS.
AS.33X6
,... ,,... ..... ,,-r^r ,-r-^-T-^T-r-r-r-r-TT-r-r-r-r-r-r^-rT-T-^ 10. 0X0
J5»i.j'J5ii«'35134' J5ijo'35t36'35t43'35t48 J5«54'j«>06' j«ibtf' JSiii'jtfTifl'36^34 36\30 Tl*<
ril»i0980036 tl-545 Acq, 7-JAN-1998 01,28,06 CC XT* Volttgm SIS 70S Noi*»il845
,435.7737 f,4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,7380.0,1.00\,r,T) XxpiSDBSUS
XXIAHSLX LASS Ttat,198/199/305/308 TLH44376A
100\ A6J2X6
35,12 35,18 35,24 35',30 35:36 35',42 35',48 35:54 36,00 36:06
rile,0980036 tl-545 Acq: 7-JAH-1998 01:28,06 CC EH- Voltage SIS 70S Noise,2306
435.8169 f,4 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,9224.0,1.0Q\,r,T) EzptXDBSOS
TBIAHGLX LABS Text, 198/199/305/308 TLH44376A
3624
Tiae)
1003
SO.
60.
40.
30.
Al.
Jifl 35 1 24 35,30 35:36 35,42 35,48 35,54
\rilaiU980036 H-545 Acxj: 7-J3OT-1998 01,28,06 CC SH- Voltage SIR 70S lfoiae,13B9
437.8140 Tt4 BSOB(356,30,-3.0) PXO( 7,5, 3, 0.10\rS5S6.0,1.00\,T,X) XxptSDBSOS
TSIAHSLZ LABS Textt 198/199/305/308 XLXI44376A
100\ Al. 68X7
80.
60.
40.
20:
0.0X0
36',06 36,12 36',IB 36,24 36',30 Tiae\
35',12 35',ia 35i24 35i30 35t36 3Si43
H-545 Acq, 7-JZH-1998 01,28:06 CC SI+ Voltagw SIS 70S
430.9739 Ti4 XxptODBSVS
TSIAHSLX LABS T«rt» 198/199/305/308 TLH44376A
35,13 SStSl^JZ*38 . 35L44 J6,04
100$
80.
60.
40.
20.
3. 3X6
'.3.6X6
'.2.0X6
.1.3X6
'.6.6X5
0.0X0
36,24 36t3o
36i25
1.2X7
.9.6X6
.7.2X6
.4.8X6
.2.4X6
s* sss 35, 36 35 142
is I si s'eVob' 's'eVois'
0.0X0
TiM€\
334
-------
rllmiOiiooM
441.7428 F:4
4i-545 Acq: 7-JAH-1998 01:28:06 SC EI+ Voltage SIS 70S Noieas2257
BSO3(256,30,-3.0) PKD(7, 5, 3,0. 101,9028. 0,1.00\,r,T) XzpsXDBSOS
TXIANGUS LABS
lOOi
90.
80.
70.
SO.
30;
40.
30.
20.
10.
n~.
ril«iU980036
443.7399 T:4
Text: 198/199/205/208 TLIf44376A
f- 1L^ _. -
35:00 ' 36:00
J7iob ' 38:00
A6.01X6 -9.1X5
i
I
I
/ \A4.39E4
J ^*%L_A-
.8.2X5
.7.3X5
.6.4X5
.5.5X5
.4.6X5
.3.6X5
.2.7X5
.1 . 8X5
.9.1X4
39\00 40':00 41:00 Tlae
'1-545 Acq: 7-JAK-1998 01:28:06 SC XH- Voltage SIX 70S Seine -.74 5
BSUB(256,30,-3.0) PKD(7,5,3,0.10\,2980.0r1.00\,T,T) XxptXDBSVS
XXIANSXX LABS
1001
901
801
701
601
501
401
301
201
101
Tllai0980036
430.9729 f:4
Tart: 198/199/205/208 TLH44376A
35\00 36:00
37:00 ' 38:00
A6.62X6 9.3X5
\\
j A\28XS
' ^nnr
.8.3X5
.7.4X5
.6.5X5
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.1.9X5
.9.3X4
10. 0X0
'39iOO ' 40:00 ' 41:00 Tlae
tl-545 Actj: 7-JZK-199S 01:28:06 SC SZ+ Voltage SIS 70S
Xxp:HDB5US
TSIAHGZX LABS Text: 198/199/205/208 TLK44376A
1001
901
801
701
sol
sol
401
301
201
101
0-
h^^fl^W?^^
TLLe:U9S0036
513.6775 T>4
35:00 ' 36:00
37:00 ' ' ' '38\00
-.1.2X7
.1.1X7
.9.7X6
.8.5X6
.7.3X6
.6.1X6
.4.9X6
.3.6X6
.2.4X6
.1.2X6
0.0X0
39:00 ' ' ' 40:00 ' ' ' 41<00 Mae
#1-545 Acq: 7-JXS-1998 01:28:06 SC XH- Voltage SIS 70S
XxptSDBSUS
3SIASGLX LABS Texts 198/199/205/208 TLH44376A
1001
90.
801
701
601
501
40.
301
201
•
1
i
1
ll.ll
Hfiiffi
olflilllilpip
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1
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5:00
I 36:
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37:37
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1
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il mm m 41111
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il . 6X4
',
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'•.9.1X3
17.3X3
15.5X3
'•.3.6X3
.1.8X3
39\00 ' 40:00 41 00 Tlae
335
-------
nj.a:O9a0036 tl-545 Actfi7-JMT-19SB 01:28t06 SC £!*• Voltmgm SIX 70S
457.7377 Tt4 BSUBf256,30,-3.0) PXD(7,5,3,0.10\,92.0,1.00\,T,T) KxptNDBSVS
TXIANSLX LASS Taxt, 193/199/205/208 TLH44376A
100* A1.82X6
39,30 39:36 39>42 39i48 39i54
ril»t0980036 41-545 Acqi 7 -JAN- 19 9 8 01:28,06 GC EH- Yoltagm SIX 70S Noiao:17
459.7348 Tt4 BSUB(256,30,-3 .0) PXD(7,5,3,0.10\,S8.a,1.00\rr,T) XxptXDBSUS
TSIAHSLX LABS T«rtj 198/199/205/208 XLH44376A
1001 A3. 37X6
80.
SO.
40.
20.
OJ
'39': 30 ' 39:36 39', 42 39,48 39,54
rtle,O980036 fl-545 Acqt 7-JA1T-1998 01:28i06 CC XI+ Voltage SIX 70S No±aes20
469.7779 f>4 BSUB(256, 30, -3. 0) PXD(7, 5,3,0. 10\, 80.0,1.00\,T,T) SxptODBSUS
XBIASGLS LABS Taxt:19a/199/20S/208 XLH44376A
40100
40:00
A2
1001
80.
SO.
40.
20:
39:30 39:36 39:42 39:48 39:54
T±le>U980036 tl-545 Acq: 7-JAN-1998 01:28:06 SC £Z> Voltage SIS 70S Noiae,16
471.7750 Ts4 BSUB(256,30, -3. 0) tXD(7,5r3,0.10\,64.0,1.00\rT,T) XzpiNDBSUS
TRIANGLE LABS Taxtil98/199/205/208 TLH44376A
1001 A2.5J.E7
40:00
39:30 39:36 39:42 39:48
T±le,U980036 fl-545 Acqi 7-J3UT-1998 01:28:06 GC X+
430.3729 Tt4 XxptXDBSUS
TRIKSSLX LABS Taitt 198/199/205/208 TLH44376A
39,37 ^,___^—^ 39^50
39:54
SIX 70S
40:00
80.
60.
40.
20.
0.
39:57
40 06
.0.0X0
06 Tiae
40 06
3. 6E6
.2.9E6
.2.2E6
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-7.2ES
.0.070
40:06 T±me
39:30
39136
39:42
39:48
39154
40:00
-1.2X7
.9.2X6
,6.9X6
'.4.6X6
'.2.3X6
40 06
0.0X0
Time
336
-------
co
Peak Locate Examination: 7-JAN-1998:01:26 File:U980036
Experiment:NDB5US Function:2 Reference:PFK
-------
'ile:U980036 #1-724 Acq: 7-JAN-1998 01:28:06 GC EI+ Voltage SIR 70S
19.8965 F:2 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES,
100% A1.54E7
80J
60j
40_
20_
0.
INC.
1 1 1 1 1 r-
25:00
T - 1 - 1 - 1 - 1 I - 1 - 1 - 1
25:36
1 - 1 - 1 - 1-
25:48
24:48 25:00 25:12 25:24
'ile:U980036 #1-724 Acq: 7-JAN-1998 01:28:06 GC EI+ Voltage SIR 70S
321.8936 F:2 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES,
100%. A1.96E7
26:00
INC.
24:48 25:00 25:12 25:24 25:36 25:48
File:U980036 #1-724 Acq: 7-JAN-1998 01:28:06 GC EI + Voltage SIR 70S
331.9368 F:2 Exp:NDB5US
Sample Text:198/199/205/208 TLIS44376A File Text:TRIANGLE LABORATORIES,
100%, 25/\1:L
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60 j
40j
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26:00
INC.
0.
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24:48
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25:12
25:24
25:36
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25:48
T I
26:00
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Time
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Time
_8.9E6
_6.7E6
L4.4E6
L2.2E6
LO.OEO
Time
CO
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File:U980036 #1-724 Acq: 7-JAN-1998 01:28:06 GC EI + Voltage SIR 70S
339.8597 F:2 Exp:NDB5US
Sample Text: 198/199/205/208 TLI#44376A File Text .-TRIANGLE LABORATORIES, INC
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28:12 28:18 28:24 28:30 28:36 28:42
File:U980036 #1-724 Acq: 7-JAN-1998 01:28:06 GC EI+ Voltage SIR 70S
341.8567 F:2 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC
100%
80j
60J
40j
201
OJ
28:12 28:18 28:24 28:30 28:36 28:42
File:U980036 #1-724 Acq: 7-JAN-1998 01:28:06 GC EI + Voltage SIR 70S
351.9000 F:2 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC
28:48
28:48
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.1.5E7
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.3.7E6
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Time
1.3E7
1.0E7
7.7E6
5.1E6
2.6E6
O.OEO
Time
100%
80J
60_
40_
20_
0:
28:35
l\
1 \
/ \
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28:12 28:18 28:24 28:30 28:36 28:42 28:48
1.6E7
_1.2E7
_9.3E6
L6.2E6
L3.1E6
" O.OEO
Time
-------
Flle:U980036 #1-385 Acq: 7-JAN-1998 01:26:06 GC EI+ Voltage SIR 70S
373.8208 F:3 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% A5.J1E6
80J
60 j
40_
20_
0
O
•*r
cr>
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33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42
File:U980036 #1-385 Acq: 7-JAN-1998 01:28:06 GC EI + Voltage SIR 70S
375.8178 F:3 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% A4.62E6
60j
20J
Oj
33:48
33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42
File:U980036 Sl-385 Acq: 7-JAN-1998 01:28:06 GC EI+ Voltage SIR 70S
383.8639 F:3 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% 33;24
80 j
60 j
40J
20J
33:06
33:12
33:18
33:24
33:30
33:36
33:42
33:48
_1.7E6
_1.3E6
_1.0E6
_6.7E5
:.3.3E5
33:54
33:54
LO.OEO
Time
1.3E6
_1.0E6
_7.7E5
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LO.OEO
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33:54
_3.6E6
_2.9E6
_2.2E6
L1.4E6
L7.2E5
LO.OEO
Time
-------
ile:U980036 #1-545 Acq: 7-JAN-1998 01:28:06 GC EI+ Voltage SIR 70S
441.7428 F:4 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
lOOi A5.79E6
80 j
60 j
40J
20 j
40:36
39:00 39:12- 39:24 39:36 39:48 40:00 40:12 40:24
File:U980036 #1-545 Acq: 7-JAN-1998 01:28:06 GC El-f Voltage SIR 70S
443.7399 F:4 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100%, A6.J53E6
60J
40J
20 j
OJ
40:48
40:36
39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24
File:U980036 #1-545 Acq: 7-JAN-1998 01:28:06 GC EH- Voltage SIR 70S
469.7779 F:4 Exp:NDB5US
Sample Text:198/199/205/208 TLI#44376A File Text:TRIANGLE LABORATORIES, INC.
100% 39 ;.37
80 j
60 j
40J
20 j
Oj
40:48
39:00
39:12
39:24
9.1E5
7.3E5
5.5E5
3.6E5
1.8E5
O.OEO
Time
.9.3E5
.7.4E5
.5.6E5
.3.7E5
.1.9E5
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Time
39:36
39:48
40:00
40:12
40:24
40:36
40:48
.3.0E6
.2.4E6
.1.8E6
.1.2E6
.6.0E5
.O.OEO
Time
-------
TLI Project: 44376A Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: 198/199/205/208 ^; ,A _ Analysis File: P980104
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-18A/B Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000
Dry Weight n/a
GC Column: DB-225
Dilution Factor n/a
Blank File: P980094
Analyst WK
Spike File: SPC2NF04
ICal: PF22206
ConCal: P980092
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
23,7,8-TCDF 1
Wi^^^^^^SfiSf^^^i^^^^;W^;?ff^x^<^ff^Ki!ii:y^
%MHMtiMBfcB&a&m®mmm$m$^
^SWift^S::*:^
13Cu-2,3,7,8-TCDF 3
S^SS-^SS::^
mmmmmmmmmmmmmmmmmmMmgmm
.4
.7 92.1 40%- 130%
0.77 23:06
iiffllfefe. •: •.s™a:spi> -'v-:;.. ..illfeS?,
0.77 23:05
13C,j-1^3.4-TCDD 0.81 21:54
Dasa Reviewer.
01/09/98
Page 1 of 1
C^NP.PSR.2.01. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:1701/09/98
342
-------
Initial
, .Date.
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits haa been recalculated according to method requirements.
Page Ho.
01/07/98
Listing of P980104B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area. Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC NL 0
18
18
18
18
19
19
19
19
19
20
20
20
20
20
20
21
21
21
21
21
21
22
22
22
22
22
23
23
23
23
23
24
24
24
25
DC WH 25
0
:00
:27
:43 RO
:55
:59 RO
:05
:27
:35
:42
:53
:00
:10
:19
:28
:37
:46
:10
:21 RO
:27 RO
:36
:43
:51
:06
:20
:31
:44
:58
:06
:19
:35
:42
:55
:16 RO
:30
:40
:15
:42
.65-0.89
0
0
1
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
.77
.79
.06
.69
.34
.72
.75
.78
.77
.78
.78
.77
.77
.78
.76
.75
.76
.53
.21
.75
.75
.76
.75
.77
.76
.75
.75
.77
.75
.76
.76
.83
.20
.74
.84
.75
.77
304-306 35 Peaks
13C12-TCDF
316-318 DC NL 0
DC WL 18
DC WL 20
0.
:00
:31
:07 RO
0.792-1.101
2.95
627.
47
20.36
16.79
17.
48.
902.
765.
1,388.
701.
110.
720.
1,520.
862.
2,531.
907.
5,246.
9.
20.
1,246.
220.
1,304.
1,243.
262.
1,539.
8.
1,275.
955.
1,471.
1,689.
1,548.
8.
2.
1,002.
24.
204.
17.
30,426.
17
91
06
41
68
16
52
47
23
72
77
79
57
77
36
01
26
22
40
66
40
52
94
12
99
13
87
23
53
81
86
37
92
53
276.
12.
6.
13.
20.
388.
334.
602.
307.
48.
312.
660.
376.
1,092.
388.
2,270.
4.
13.
533.
94.
562.
534.
114.
664.
3.
548.
414.
629.
731.
669.
3.
1.
427.
11.
87.
94
,24
as
04
48
06
61
65
26
53
65
68
91
61
98
75
25
89
16
29
50
02
06
60
66
58
23
98
64
49
74
71
67
35
43
350.
11.
9.
9.
28.
514.
430.
786.
393.
61.
407.
859.
485.
1,439.
518.
2,975.
8.
11.
712.
125.
741.
709.
148.
874.
4.
727.
540.
842.
957.
879.
4.
1.
575.
13.
116.
65-0.89
0
0
.89
.88
1.49
2.
3.
4.
46
94
64
53
50
94
70
43
00
80
03
90
99
82
55
31
16
81
32
08
50
85
97
72
38
60
80
86
36
89
01
49
38
49
43
14
51
94
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.957-
0.
0.
0.
000
799
811
819
822
827
843
848
853
861
866
874
880
887
893
900
917
925 J
929
936
941
947
957
968
975
985 J
995
001 2378-TCDF AN
010
022
027
036 J
051 J
061
069
094
113
1.043
000
802
871
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:26 01/07/98
343
-------
Page No.
01/07/98
Listing of P980104B.dbf
Matched GC Peaks / Ratio /
Ret. Tlae
Compound/
H_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.890
0.924
0.935
0.946
1.000 13C12-2378-TCDF ISO
1.027
1.042
1.045
1.090
1.106
316-318
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
WL
WH
WH
WH
WH
3
20:
21:
21:
21:
23:
23:
24:
24:
25:
25:
25:
33
20
35
50
05
42
03
08
10
32
38
RO
RO
RO
RO
RO
RO
RO
0
1
0
0
0
1
0
0
0
0
0
.37
.66
.58
.78
.77
.17
.71
.94
.73
.59
.95
Peaks
5
4
12
29
2,584
6
4
3
30
3
2
2,594
.10
.50
.11
.42
.39
.18
.00
.68
.47
.95
.27
.57
1,127.12
4.08
1.66
1,457.27
3.49
2.34
1.110
Above: TCDF / TCDD Follows
332-334
DC
DC
DC
DC
0.
NL 0:00 RO
20:29 RO
21:37
21:54
22:39
WH 24:24 RO
WH 24:30 RO
WH 24:58 RO
4 Peaks
65-0.89
1.59
0.92
0.77
0.81
0.67
1.47
0.40
0.55
0.96
6 . 07
1,705.95
2,020.85
21.53
5.42
3.10
3.29
3,754.40
0.908-1.092
0.000
3.16 3.43 0.948
744.78 961.17 1.000
903.66 1,117.19 1.013
8.63 12.90 1.048
1.129
1.133
1.155
13C12-2378-TCDD IS1
13C12- 1234 -TCDD RSI
Column Description "Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
••• End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SM-Below Signal to Noise Level
-------
TlJ.asP9B0104 tl-922 Acq: /-JAa-yo OU:JJ.iJS Sir voltage SIS 70P
303.9016 BSUB(256,30,-3.0) PXD( 5, 3, i, 0.10\,2564.0,0.00\rr,r) Erp:DB225
TSIAOGLX LASS Taxt:198/199/205/208 TLH44376A
1001 A2.27X7
AS.62X6 AS.65X6 A7.32X6
19:00 30:00 21:00 22:00 33:00 24:00
F±J.e:P980104 H-922 Acq: 7-JZN-98 08:31:29 XH- Voltage SZS 70P Soiae:837
305.8987 3SVS(25S,30,-3.0) rKD(5,3,l, 0.10%, 3348.0,0.00\,r,f) XxptDS225
TSIASGZf LABS T«rt.-198/199/205/208 TLII44376A
1001 A2.98X7
25100
19': 00 20:00 21:00 22:00 23:00 24:00
T±letP980104 tl-922 Acq:7-J7OT-98 08:31:29 KC+ Voltage 5XS 70P SOiaet578
315.9419 BSVB(2S6,30,-3.0) PXB(S,3,l,0.10\,2312.0,0.00\,T,r) Sxp:DB22S
TBIJUIGZS LABS Text! 198/199/205/208 TLH44376A
1003i A1.}3E7
80.
60.
40.
20.
25100
19:00 20:00 21:00 22:00 23:00 24:00
rile:P980104 tl-922 Acqt7-J7Ur-98 08:31:29 SH- Voltage SIB 70P Noise: 652
317.9389 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,3608.0,0.00\,rrr) EzptDB225
TRIXHGLE LABS Tart: 198/199/205/208 TLXM4376A
1001 A1.46E7
80.
60.
40.
20.
0.
25:00
19:00 20:00 21:00 22:00 23:00
F±latP980104 tl-922 Acq:7-JXN-98 08:31,29 XH- Voltage SIX 70P
375.8364 SzpiDB225
IJtlAKOLE LABS Ttxtt 198/199/205/208 TLIt44376A
100\
24: 00
25100
3.1X6
'.2.4E6
.1. 8X6
.1.2X6
.6.1X5
0.0X0
X±me
3.9X6
'.3.1X6
.2.3X6
'.1.6X6
.7.8X5
0.0X0
T±me\
19:00
20:00
21100
22:00
23:00
24:00
25100
345
-------
30,00 21:00 33:00 33:00
rUa:P980104 tl-922 Actj:7-J3UT-98 08:31:29 EH- VoJtaya SIK 70S Hoiae:648
327.8847 BSOB(256,30,-3.0) PXD(S,3,l,0.10\,2593.0,0.00\rT,T) Xxp:DB335
TSXAXKLX LASS Tart: 198/199/305/308 TLH44376A
rn.atP9a0104 il-922 Acq: 7-JAN-9B 08:31:29 EI+ VOltagra SIS 70P Ntij.aa:405
319.8965 BSUB(256,30,-3.0) PKV( 5,3,1, 0.10\,1620.0,0.00\,r,f) XxptDB235
iASeZX LASS Taxt: 198/199/305/308 TLH44376A
ion
80.
SO.
40.
20.
A9.83X6
AJ..57X6
A xvA
AS.07S3
A2.99Z6
20:00 31:00 32:00 33s 00
Til»tt980104 11-922 Acq:7-J7UT-98 08:31:29 XI+ Voltmgm SIS 70P Soiamtl451
321.8936 3303(356,30,-3.0) PKD(S,3,1,0.10\,5B04.0,0.00\,T,T) Kxp:DB335
XXIAHOJS LASS Tmit: 198/199/205/208 TLH44376A
100\
24:00
80.
60.
40.
20.
A1.35S7
A3.OOE6
A ^ A
Al.04E6
A3.85S6
34:00
100)
80.
60.
40.
20:
A4.48Z7
A4.83E7
A1.53X7
A3.60X6
y\
A3.36E6
30:00 31:00 33:00 33:00
'LLa:P980104 il-922 Acqi7-JJOT-98 08:31:29 KH- Voltage SIS 70P Soiaei431
'31.9368 BSUS(256,30,-3.0) PXD(S,3,1,0.10\r1724.0,0.00\,T,T) Sxp:DS335
SIAWCLI LABS Text:198/199/305/308 TLH44376A
,00\ AS. Q4Z6
34:00
80.
60.
40.
20.
A7.45E6
20:00 21:00 22:00 23:00
r±J.a:P980104 tl-923 Acqi7-JJW-98 08:31:29 XX* Volt*g* SIX 70P Jtoltt>i270
33.9338 BSUB(356,30,-3.0) PKD(5,3,1,0.10\,1080.0,0.00\,r,T) Xxp:DB335
TtlAMSLS LABS Text: 198/199/305/308 TLH44376A
100\
A9.61X6
80.
60.
40.
30.
0.
24:00
20100
21:00
22:00
23:00
24:00
-4.4X6
.3.5X6
.2. 7X6
.1. 8X6
.8.9X5
.0.0X0
25 00 Tia,
-5.SX6
'.4.5X6
.3.4X6
.2.3X6
.1.1X6
.0.0X0
25 00 Time
-1.4X7
.1.1X7
.8.3X6
.5.6X6
'.2.8X6
'.0.0X0
35 00 Time
-2.5X6
.2.0X6
.1.5X6
.9.8X5
.4.9X5
.0.0X0
25 00 Time
25
-2.9X6
.3.4X6
.1.8X6
.1.2X6
.5.9X5
.0.0X0
00 Time
346
-------
r±le:P980104 tl-922 Acq s 7 -JAN- 9 8 08:31:29 XH- Voltage SIS
303.9016 Xxp:DS225
TSIASGLX LASS Text: 198/199/205/208 TLIt44376A
1001
ao.
SO.
40.
20.
0
21:10
ft
20:J7 1
1 \
15:42 B 1 21:51 22:J1
i 20:15 i i A
19l37h A , ft ft A rt
A MAj/lVlA 11 JUIL/I
15:00 20:00 21:00 22:00
rile:P980104 tl-922 Acqi7-JAN-98 08:31:29 XH- Voltage SIS
315.9419 Xxp:DS225
TSIAJKLX LASS Text: 198/199/205/208 TZH44376A
1001
ao.
60.
40.
20.
0
19\00 ' ' ' 20106 ' ' 21:00 ' 22:00
r±le:P980104 tl-922 Acq:7-J3UT-98 08:31:29 XI+ Voltage SIS
319.8965 Xxp:DS235
TSIANSLX LASS Text:198/199/205/208 TLIt44376A
1003
ao-.
so-.
40:
20:
o:
S" 16
15-50
1 20: 30 21:54
l\ A ^ A 21A15 ^>/V
15:00 ' ' ' 20:00 ' ' 21:00 ' ' 22:00
TLLatP9a0104 tl-922 Acq : 7 -JAN- 9 B 08:31:29 XI+ Voltage SIS
331.9368 ExptDB225
TSIASSLX LASS Text: 198/199/205/208 TLIt44376A
1003
80:
50:
40:
20:
0:
21:54
T
/I /I
15:00 20:00 21:00 22:00
TU.e:P980104 tl-922 Acqt7-JAN-98 08:31:29 XI* Voltage SIS
252.5825 Xxp:DB225
TSIASGLX LASS Text: 198/199/205/208 TLIt44376A
1001
80:
50:
40:
20:
o:
, 19*09 19 1 57 20:26 20t58 21:43 22:14
*"*^l1**rfcUinj*~'.i-n-«liiJ^_r i — VfX-H -L'^^mtf JrV~Ti^*"^>ji_ruA. *A *^iA^kX>rsA\J
1 ^ »1p J • ' ^ • JV^^f |W ^•MP*» ' *^f * ^r' ^T^^T T»VA/^ TT *^TT ¥"•*«
15:00 20:00 21:00 22:00
Tile iP9 80104 tl-922 Acqi7-JAN-98 08:31:29 EH- Voltage SIS
330.9792 Xxp:DS225
TSIAHSZX LASS Text: 198/199/205/208 TLIt44376A
1001
80:
50:
40:
20:
o:
18:42 15:55 20:27 20:58 21:J2 22:25
70J»
_J.7*ff
2J:J5
MA A
24. -JO
M A ,
.2.9X6
.2.2X6
.1 . 5X6
.7.3X5
0.0X0
23:00 24:00 25:00 Mjie
70J>
2J:05 J.UT5
H
.2.4X6
.1 . 8X6
.1.3X6
.6.1X5
0.0X0
23:00 24:00 25:00 Tiae
70P
4.4X6
.3.5X6
.2.7X6
.1 . 8X6
.8.9X5
O.OEO
23:00 24:00 25lo0 Tiae
70P
-2.5X6
.2.0X6
.1.5X6
.9.8X5
.4.9X5
O.OEO
23:00 24:00 ' ' ' 25:06 Tiae
70P
_^2J:12_ ^J.19 25^02 25 :^32C2. 7X6
V^VV^^^"^JJ^^^^
-2.2X6
.1 . 5Z5
.1.1X6
.5.4X5
0.0X0
2J:00 ' ' ' 24106 ' ' ' 25:06 ' ' ' Tiae
70P
23:38 24:14 25:03 -2.1X6
15100 20:00 21:06 22', 00
'.1 . 7X6
.1.3X6
.8.5X5
.4.3X5
O.OEO
23:00 24:00 ' 25:00 ' Time
347
-------
tef, tass 292,9825 Peak top
Height ,51 volts Span 298 ppi
Systai file nae
Data fllenaie
Resolution
Grotpfxitef
loniiatlon nde
Switching
tef, lasses 292,9825,
R 232.9825
B 383,9816
C 365,8987
D 315,9419
E 317,9389
F 319,8965
G 321,8936
H 327,8847
I 338,9792
J
K
L
H
1
El*
VOICE
388,9761
338,9792
331,9368
333,9338
375,8364
Channel I 338,9792 Peak top
Height ,36 volts Span 288 ppi
343
-------
TLI Project:
Client Sample:
44376A
201-204
O
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980035
Client Project
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAIN
194-59-19A-D
1.000
n/a
DB-5
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
12/17/97
12/29/97
01/07/98
n/a
U980026
JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
AnaJytes
2,3.7,8-TCDD
1.2,3,7,8-PeCDD
1,23,4,7.8-HxCDD
l,2J,6J,8-HxCDD
1.2,3,7,8,9-HxCDD
l,Z3,4.6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2.3,7,8-PeCDF
2,3,4,7,8-PeCDF
1 2J ,4,7,8-HxCDF
*.2J,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1.2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
•"%£«&. $»g) -OL - EMPC
ND 0.004
0.02
ND 0.01
0.02
0.03
EMPC 0.09
0.16
0.29
0.07
0.12
0.23
0.09
0.12
ND 0.007
0.43
EMPC 0.05
0.31
yH&nt #ug , number Bt - EMPC
0.22 5
0.24 6 0.42
0.33 5
EMPC 0.18
15 13 • 1.5
1.6 12 1.6
0.96 8 1.0
0.65 3 0.70
'•^ ""
1.58
1.12
1.20
0.91
0.76
1.73
1.65
1.23
1.22
1.27
1.10
0.83
i
RT
29:36
32:50
33:07
39:37
24:40
28:35
29:16
32:02
32:08
32:37
35:01
39:49
Flags
j
j
J
J_
JB_
B_
J_
J
J
Flags
—
Page 1 of 2
MTI2_PSR v 1 JO I. LARS 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 01/10/98
349
-------
TLI Project 44376A
Client Sample: 201-204
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980035
internal S&BK&R& •• ••
13Cir2^J,8-TCDF
13C 12-2^,7 ,8-TCDD
l3C,2-1^3,7,8-PeCDF
13C,2-U,3,7,8-PeCDD
1JC,2-1.2,3,6.7.8-HxCDF
l3C,2-1.2,3,6,7,8-HxCDD
l3C,2-U.3,4.6,7,8-HpCDF
13C,2-l,2,3A6,7,8-HpCpD
13C ,2-1 ,2,3,4,6,7,8,9-OCDD
Surroo^ Standards {Type A}
IJCir2JA7.8-PtCDF
13C,2-U,3,4,7,8-HxCDF
IJCn-lA3.4.7,8-HxCDD
13Ci2-l,2,3,4.7,8.9-HpCDF
Surrogate Standards (Type AJ
37CL,-2,3,7,8-TCDD
Alternate Standards (Type A>
13C,2-l,2,3,7.8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C12-1,Z3,4-TCDD
l3Cu.lA3,7.85-HxCDD
AmMMfc*-' -»*^J!
SSfSSf***. f. P*^f ffff V>
2.9
3.0
3.1
2.7
3.4
3.6
3.2
3_5
6.5
Amt |f>s} 9
3.7
3.3
3J
3.8
Amt §19) ^
3J
Amt. $19} .• ^
3.3
3J
> '
fcRecova
% v A \ ^ \ v
73.1
75.1
76.4
68.3
85.4
89.4
79.9
86.7
81.3
»Becove»
92.0
82.6
86.8
93.8
» Recover
82.8
^Recover
81.4
82.8
__ \
jwv "• A >
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
y
c
40%-130%
40%-130%
40%- 130%
40%-130%
y
40%-130%
40%-130%
— f^io
^.'^ , • : '
0.75
.0.80
1.47
1.49
0.50
1.23
0.44
1.04
0.85
Ratio
1.51
0.52
1.22
0.42
Ratio
0.50
0.51
Ratio
0.83
1.26
Off ^'
"<*<, rVI -,;x£t.>
24:37
25:20
28:34
29:36
32:08
32:48
35:00
36:03
39:36
RT
29:15
32:02
32:43
36:32
RT 1
25:21
, RT :-'"
33:23
32:37
RT
25:09
33:07
Flags
t f- f
Flags
Ftags
—
Flags
—
Flags
Data Reviewer
01/10/98
Mm_PS* • I a I. LARS 4.10.031
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 01/10/98
330
-------
Initial
... Date...
Data Review By:
Calculated Noise Area:
6.44
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing
01/10/98 Matched
Compound/
M_2.... QC.Log Omit Why ..RT. OK
TCDF 0
304-306
NK
K
K
K
K
K
K
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
NK
NK
D
K
D
D
D
DC NL 0
21
21
22
22
22
23
23
23
24
24
24
24
25
25
26
:00
:28 RO
:58
:13
:37
:57
:21
:36
:50
:02
of 09800358. dbf
GC Peaks / Ratio / Ret.
Ratio Total. Area. . . Area
.65-0.89
0
0
0
0
0
0
0
.83
.61
.85
.85
.75
.81
.74
0.75
0
.75
0.74
:13 0.76
:28
:40
:05
:17
:23 RO
0.70
0.76 1
0.77
0,
0.
15 Peaks
DC NL 0
DC WL 23:
24:
24:
25:
25:
25:
DC WH 25:
DC WH 25:
0.
:00 RO
:35
:14
37
03 RO
20 RO
33 RO
41
55 RO
,70
.90
7
42.23
162.22
197.45
222.91
859.68
574 . 89
682.02
504.63
651.63 .
797.03
338.58
277.03
,416.06
350.18
312.13
69.77
,416.21
TUne
. Peak .
70
90
102
367
256
290
216
278
339
146
113
610
152
128
35
1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.
0.867-1.079
.57
.49
.59
.39
.77
.28
.22
.55
.00
.19
.73
.62
.10
.53
.42
116
106
120
492
318
391
288
373.
458.
192,
163.
805.
198.
183.
39.
65-0.89
1.
0.
0.
0.
1.
0.
2.
0.
2.
5 Peaks
DC NL 0:
22:
23:
D SN 23:
24:
D SN 24 :
24:
25:
D SN 25 :
D SN 25 :
0.
00
48
12
29
10
37 RO
49
15
21 RO
31 RO
65-
0.
0.
0.
0.
0.
1.
0.
0.
0.
1.
08
82
75
75 15
00
41
00
76
99
16
0.89
79
78
77
80
85
96
81
70
46
05
13.10
192.25
96.67
,930.94
287.45
101.21
32.13
51.33
18.39
,448.40
TCDF / TCDD
8.10
327.67
215.09
44.08
114 . 27
12.44
44.33
135.20
22.23
14.44
41,
6,807,
161.
44.
36.
,33
,62
,66
.03
35
55.
9,123.
162.
107.
18.
.53
.96
.32
.29
.12
.74
.41
.08
.03
,39
.30
.44
08
60
42
0.000
0.872
0.892
0.903
0.919
0.932
0.949
0.959
0.968
0.976
0.984
0.994
1.002 2378 -TCDF AN
1.019
1.027
1.072 .
. Flags
J
J
J
J
0.959-1.041
34
32
40
09
15
0.000
0.958
0.984
1.000 13C12-2378-TCDF ISO
1.018
1.029
1.038
1.043
1.053
143.
93.
52.
19.
55.
23
88
44
81
56
184.
121.
61.
24.
79.
0.895-1.047
44
21
83
52
64
0.000
0.900
0.916
0.927
0.954
0.972
0.980
0.997
1.001 2378 -TCDD AH
1.007
J
J
J
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 Q1
-------
Page No.
01/10/98
Listing of O980035B.dbf
Hatched GC Peaks / Ratio / Ret. Tine
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total. Area. ... Area.Peak.1. . Area. Peak. 2. . Rel.RT Compound, Name. . ID.. Flags.
D D SN 25:41
D D SN 25:53 RO
D D SN 26:11 RO
0 D SN 26:19 RO
320-322 5 Peaks
37C1-TCDD
328 DC NL 0:00
DC WL 23:05
DC WL 23:13
23:58
25:21
25:45
25:57
26:00
26:02
26:05
26:13
26 : 28
26:34
26:40
328 11 Peaks
13C12-TCDD 0
332-334 DC NL 0:00 RO
24
25
25
25:
:11
:09
: 20
:40 RO
0.66 19.92
0.43 6.87
1.20 2.99
0.59 11.65
836.56
4.38
30.68
13.26
371.58 371.58
10,346.40 10,346.40
232.04 232.04
14.36 14.36
25.95 25.95
25.66 25.66
39.74 39.74
53.49 53.49
6.94 6.94
22.76 22.76
10.68 10.68
11,149.60
.65-0.89
2.48 12.50
0
.84
0.83 14
0.80 12
1.19
332-334 4 Peaks
PeCDF
340-342 DC NL 0:
26:
D D SN 26:
D D SN 27:
27:
27:
27:
28:
28:
M 28:
AN 28:
28:
28:
D D SN 29:
29:
29:
29:
29:
1.
00 RO
35
53 RO
13 RO
34
43
53
12
17
29
35
44
52
01 RO
16
25
44 RO
59 RO
27
32-1.78
0.
1.
0.
3.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
74
56
28
27
48
53 1
50
42
54
66
73
40
46
95
65
49
90
23
79.48
,863.24
,486.81
428.43
,857.96
. 3.36
539.70
3.65
15.05
180.42
,196.09
291.05
490.70
589.59
229.10
228.80
214.30
328.52
17.37
388.97
526.09
70.51
25.24
36
.36
6,726.10
5,539.70
287.59
43
8,137
6,947
242
0.
0.
.12
.14
.11
.05
1.014
1.022
1.034
1.039
.921-1.079
0.000
0.911
0.916
0.946
1.001 37C1-TCDD CLS
1.016
1.024
1.026
1.028
1.030
1.035
1.045
1.049
1.053
921-1.079
0.000
0
.955
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
328.
107.
724.
174.
288.
357.
143.
145.
124.
195.
242.
315.
52.
15.
93
54
00
51
30
34
00
00
95
00
46
23
61
34
210
72
472
116
202
232
86
83
89
133
146
210.
27.
12.
0.
.77
.88
.09
.54
.40
.25
.10
.80
.35
.52
.51
.86
.65
.48
925-1.065
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
r.
000
931
941
953
965
970
976
987
990
997
001 12378 -PeCDF AN
006
Oil
016
025 23478-PeCDF AN
030
041
050
J
J
J
J
J
J
J
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51
1/38
-------
Page No.
01/10/98
Listing of a980035B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area. Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name. . ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
D
M
D
356-358
13C12- PeCDD
368-370
368-370
HxCDF
374-376
30:14
15 Peaks
DC NL 0:00
27:42
28:10
28:34
28:51
29:15
29:46
29:56
7 Peaks
DC NL 0:00
27:49
D SN 28:17
28:33
28:41
28:51
29:01
29:05
29:18
29:27-
29:36
29:44
D SN 30:05
DC SN 30:15
DC SN 30:31
10 Peaks
DC NL 0:00
28:31
28:39
DC SN 29:01
29:36
29:44
30:08
30:20
30:28
30:30
8 Peaks
DC NL 0:00
31:04
RO
1
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
1.88
.32-1.78
1.28
1.58
1.27
1.47
2.34
1.51
1.11
0.46
.32-1.78
1.31
0.94
0.94
1.57
1.55
1.49
2.53
1.36
1.79
1.03
1.58
1.48
1.87
1.66
0.97
32-1.78
1.08
1.05
0.73
0.40
1.49
1.97
0.96
3.69
0.32
1.27
05-1.43
1.16
1.22
34.55
5,333.63
0.38
249.75
8.87
12,959.42
364.57
11,517.03
75.81
8.57
25,184.02
• PC CDF /
0.28
275.70
21.50
198.31
47.29
120.28
19.41
45.76
54 .80
25.85
35.80
23.04
18.74
2.93
1.63
846.24
25
153
5
7,720
.50
.10
.39
.06
334.43
6,920
46
5
.75
.08
.21
13
96
4
5,239
142
4,596
41
11
.55
0.
.65
.25
.36
.97
.28
.70
.38
1
860
0
0
0
1
1
1
1
1
.058
-1.140
.000
.970
.986
.000 13C12-PeCDF 123
.010
.024 13C12-PeCDF 234
.042
.048
J
IS2
SCR1
167
121
28
72
19
26
38
15
21
13
.58
.08
.71
.07
.23
.40
.51
.71
.90
.74
179
77
18
48
7
19
21.
15.
13.
9.
0.935-1.022
.01
.23
.58
.21
.61
.36
.49
.27
.90
.30
0
.000
0.940
0
0
0
.956
.965
.969
0.975
0
0.
0.
0.
1.
1.
1.
1.
1.
0.865-
0.21
10.10
7.70
2.02
5,985.74
946.18
28.43
13.87
5.03
13.90
7,010.95
PeCDD /
23.81
313.97
6.14
4.68
3,586.44
731.60
17.
28
20.07
3.
8.
06
45
5.
6.
2,399.
371.
17.
5.
9.
6.
87
42
30
05
91
44
46
63
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
.980
983
990
995
000 12378-PeCDD
005
016
022
031
1.135
000
963
968
980
000 13C12- PeCDD 123
005
018
025
029
030
J
J
J
J
J
J
J
AN J
J
IS3
172.
68
141.
0.962-
29
0.
0.
1.047
000
967
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 01/10/98
353
-------
.Page No.
01/10/98
Listing of 0980035B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
A
0
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
0
0
D
D
M
390-392
13C12- HxCDD
402-404
402-404
HpCDF
408-410
31:13
31:22
31:31
31:40
32:02
32:08
32:16
32:24
32:37
D SN 33:23
33:28
11 Peaks
DC NL 0:00
31:05
31:12
32:02
32:08
32:37
33:23
6 Peaks
DC NL 0:00
31:34
D SN 31:51
32:01
32:13
D SN 32:23
D SN 32:37
D SN 32:45
32:50
33:07
5 Peaks
DC NL 0:00
32:13
32:43
32:48
33:07
4 Peaks
DC NL 0:00
35:01
35:17
1.27
RO 0.84
' 1.21
RO 1.00
1.23
1.22
RO 0.92
1.38
1.27
RO 1.69
1.18
0.43-0.59
RO 0.68
0.52
0.51
0.52
0.50
0.51
0.50
1.05-1.43
RO 1.02
1.18
RO 1.52
1.28
1.30
1.09
RO 2.21
RO 1.62
1.12
1.20
1.05-1.43
1.28
1.37
1.22
1.23
1.26
0.88-1.20
1.16
1.10
1.06
741.24
64.40
101.98
50.89
589.83
272.50
62.05
103.50
293.93
16.26
59.80
2,654.09
6.93
37.54
66.54
6,804.29
9,982.93
8,723.69
6,607.26
32,222.25
t : HxCDF /
6.97
61.00
3.32
276.41
136.48
29.36
7.73
16.40
45.83
52.70
572.42
7.50
25.59
4,904.99
7,721.36
8,680.94
21,332.88
: HxCDD /
9.81
867.57
186.41
414.36
35.65
55.76
28.17
324.84
149.77
34.35
60.00
164.31
32.36
12.90
22.47
2,322.38
3,328.07
2,941.31
2,188.08
33.03
155 . 17
77 . 15
24.20
28.70
14.80
2,692.26
4,252.55
4,832.80
453.76
95.91
326.88 0.971
42.24 0.976
46.22 0.981
28.26 0.985
264.99 0.997 123478-HxCDF AN
122.73 1.000 123678-HxCDF AN
37.44 1.004
43.50 1.008
129.62 1.015 234678-HxCDF AN
1.039 123789-HxCDF AN
27.44 1.041
0.876-1.124
0.000
24.64 0.967
44.07 0.971
4,481.91 0.997 13C12-HxCDF 478 SDR2
6,654.86 1.000 13C12-HXCDF 678 IS4
5,782.38 1.015 13C12-HxCDF 234 ALT2
4,419.18 1.039 13C12-HXCDF 789 ALT1
0.958-1.014
0.000
27.97 0.962
0.971
121.24 0.976
59.33 0.982
0.987
0.994
0.998 123478-HxCDD AN
21.63 1.001 123678-HxCDD AN
24.00 1.010 123789-HxCDD AN
0.970-1.030
0.000
10.79 0.982
2,212.73 0.997 13C12-HXCDD 478 SOT3
3,468.81 1.000 13C12-HXCDD 678 IS5
3,848.14 1.010 13C12-HXCDD 789 RS2
0.996-1.049
0.000
413.81 1.000 1234678-HpCDF AN
90.50 1.008
J
J
J
J
J
J
J
J
J
J
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 01/10/98
354
-------
Page No.
01/10/98
Listing of 0980035B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID..
Flags.
0
D
M
D
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
D
M
D
M
D
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
M
0
D
0
DC
DC
DC
SN
SN
SN
4
NL
4
NL
ML
35
36
36
36
36
:26
:17
:23
:33
:53
RO
RO
RO
0
0
2
1
1
.97
.53
.06
.24
.00
Peaks
0
35
35
36
36
:00
:00
:30
:32
:55
0
RO
RO
211.28 104.16
3
2
78
8
1,344
.94
.92
.95 48.10
.25
.21
.37-0.51
0
0
1
0
0
Peaks
0
:00
35:09
35:18
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
NH
2
NL
2
NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
35
36:
36;
:26
;03
:33
0.
RO
RO
RO
RO
RO
.52
.44
.52
.42
.37
88-1.20
1
0
1
1
0
3
.36
.66
.22
.14
.86
.03
Peaks
0:
35:
36:
00
16
03
0.
RO
14
5,704
11
4,289
63
.54
.28 1,736.88
.84 12.49
.75 1,279.16
.97 17.19
107.12 1.012
1.037
1.040
38.70 1.044 1234789-HpCDF
1.054
0.943-1.114
0.000
3,967.40 1.000 13C12-HpCDF 678
8.22 1.014
3,010.59 1.044 13C12-HpCDF 789
46.78 1.055
AN
IS6
SUR4
10,069.84
: HpCDF / HpCDD Follows --
2
8
125
16
.86
.30
.87 75.40
.01
119.26 60.80
7.20
0.975-1.005
0.000
0.975
61.70 0.979
0.983
70.30 1.000 1234678-HpCDD
1.014
AN
245.13
88-1.20
0.83
1.02
1.04
Peaks
0:
34:
35:
36:
36:
37:
37:
37:
37:
37:
38:
38:
38:
38:
39:
39:
40:
00
43
33
22
37
10
26
31
39
53
11
19
36
41
18
49
18
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
0.
0.
1.
0.
1.
1.
1.
0.
1.
0.
0.
1.
1.
0.
1.
0.
1.
04
83
31
55
17
01
34
51
07
58
47
60
20
88
06
83
43
7.79
27.75 14.01
5,466.
45 2,786.97
5,494.20
: HpCDD / Octa-CDD and CDF
0.
0.
0.
1.
1.
2.
1.
1.
1.
1.
2.
1.
1..
1.
3.
412.
2.
13
53
96
83
98
23
29
95
87
70
27
42
87
45
61 2.02
00 187.00
59 1.96
0.972-1.028
0.000
13.74 0.978
2,679.48 1.000 13C12-HpCDD 678
Follows
0.899-1.101
0.000
0.877
0.898
0.918
0.925
0.939
0.945
0.947
0.951
0.957
0.964
0.968
0.975
0.977
1.91 0.992
225.00 1.005 OCDF
1.37 1.018
IS7
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:51 01/10/98
355
-------
Page No.
01/10/98
Listing of U980035B.dbf
Matched GC Peaks / Ratio / Ret. Tine
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1..
2.51
O.S1
442-444 3 Peaks 418.20
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
SN 40
SN 40
:22
:52
RO
RO
0
2
.46
.44
3 Peaks
DC
DC
DC
NL 0
SN 39
39
39.
SN 40:
:00
:25
:37
;56
:04
0.
RO
RO
RO
RO
.76
1
0
0
0
0
-1.
.67
.38
.91
.41
.26
02
2 Peaks
DC
NL 0:
39:
00
36
0.
76
1
0
-1.02
.00
.85
1 Peak
0.06
0.59
167.97
3.76
0.81
171.73
0.08
7,695.65
7,695.65
Area.Peak.2.. Rel.RT Compound.Nome.. ID.. Flags.
1.019
1.032
80.05
1.77
87.92
4.33
0.899-1.101
0.000
0.995
1.000 OCDD
1.008
1.012
AN
3,526.36
0.996-1.004
.0.000
4,169.29 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Tine (mn:ss)
Rat.l -Ratio of M/M+2'Ions
OK -RO"Ratio Outside Limits
Rel.RT-Relative Retention Time
••• End of Report ••«
WL-Below Retention Time Window
WH-Above Retention Tine Window
SN-Below Signal to Noise Level
-------
Fila:O980035 tl-724 Acq: 7-JXH-1998 00:29:17 SC EI+ Voltage SIS 70S Noiae:9553
303.9016 F:2 BSO3(256,30, -3.0) PKD(9,5,3,0.10\,38212.0,1.00\,f,T) Xxp:HDB5OS
TSIASGLX LASS Text: 201-204 TLIt44376A
1003
80.
60.
40.
20.
A6
A3. 39X6
A3. 67X6 A2.16X6 A
4 A2.90X6A f\
A1.03X6 /V-S X\ -/\ /\ /W 1 A A
J\ /\A J V^JVJ\J Y l/VA/
'22:00 ' ' ' 23:00 ' 24:00
11X6 1.2X6
A1.52X6
A A
v \l\ r - . "f5
.9.8X5
.7.3X5
.4.9X5
'•.2.4X5
25:00 25:00 Time
rile:P980035 tl-724 Acq: 7-JXX-1998 00:29:17 GC XI* Voltage SIS 70S BOiae:11558
305.8987 F:2 BSUS(256,30,-3.0) PXD(9,5, 3, 0 .10\,46232.0,1.00\,T,T) KxptNDBSOS
TSIABGLE LABS Text: 201-204 TLIt44376A
100J
80:
soj
401
20:.
A8.
A4.58E6
A4 . 92X6 A3 • f|Jf 7jj j\
A1.20X6 l*\f\ /A l\ /W \ A A
x/v y\ /\- 1 y V_y \ y \J 1 v \^J \j
22:00 23:00 24:00
IE6
A1.98X6
A A
l\ f\ A3. 94X5
1 . 6X6
-.1.2X6
'•.9.3X5
'•.6.2X5
.3.1X5
25:00 25>00 Time
rile: 0980035 tl-724 Acq: 7-J3OT-1998 00:29:17 GC EI+ Voltage SIS 70S SOiae:3990
315.9419 F:2 BSUB(2S6, 30, -3.0) PKD(9, 5, 3,0. 101,15960. 0,1.00\,F,T) ErpsSDSSm
TRIANGLE LASS Text: 20 1-204 XLIt44376A
1001
80:
60:
40:
20:
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U.I
1
'22:00 2.3:00 ' ' 24:00
1E7 1 . 6X7
V
.1.3X7
.9.6X6
.6.4X6
.3.2X6
0.0X0
25:00 2tf:0fl' ' ' Time
F±Jioi0980035 tl-724 Acq: 7-JZS-1998 00:29:17 GC XI+ Voltage SIS 70S Hoiae,3699
317.9389 F:2 BSUB(256,30,-3.0) PKD(9,5, 3, 0.10\,14796.0,1.00\,
TSIASGLE LASS Text: 201-204 TLIt44376A
1003
SO:
so:
40:
20:
F,T) Bxp:SDBSUS
A9.12X7
I
/
'22:00 23:00 2
-------
rile,O980035 tl-724 Acqs 7-JAW-1998 00,29,17 GC XI+ Voltage SIX 70S Xoiaesl788
319.8965 T:2 BSUB(356, 30, -3.0) PXD(7,5,3,0.10\,7152.0,1.00\rf,T) XxptSDBSUS
XBIAHSLX LABS Text, 201-204 TLH44376A
10
23\00 24 1 00 25,00
r \ *"'.f«*«
-3.4X5
.2.7X5
-.2.0X5
.1.3X5
.6.7X4
26,00 HM
rile:0980035 tl-724 Acqs 7-JJOT-1998 00,29:17 GC SI+ Voltage SIX 70S Soimes2261
321.8936 f,2 aSUB(256,30,-3.0) PXD(7,S,3, 0.10%, 9044. 0,1. 00\,T,T) XxptSDBSUS
TSIANGLX LABS Text 1 301-304 TLIt44376A
1001
80.
60.
40.
20.
0
1
f\
A1.21X6 .
\\ A
I 1 / 1 Ml
1 \ 1 \ A6.18X5^ "
I I 11 A2.45X5 r\ A4'?5S5 A2.4SXS .j
J V. . 7 W yv . J vXV^ A^ f
23\00 ' 24:00 25,00
-3.8X5
'?
A A1.30X5
'%Av— ^SirT^» if—, -i Aa^Z4-1*
-.3.0X5
-.2.3X5
-.1.5X5
.7.5X4
26:00 T±ae
rile:O980035 tl-724 Acqi 7-JJOT-1998 00,29:17 GC XH- Voltage SIX 70S Soiaes8772
331.9368 Ts2 BSUB(256, 30, -3.0) PXD(7,5, 3, 0.10%, 35038.0, 1.00\,T,T) XxptSDBSUS
TSIAHSZX LABS Text:201-204 TLIt44376A
1003
80:
60:
40.
20:
A6.J
i
23:00 24:00 25«00 '
3X7
5.54X7
A
\J v_
-1 . 7X7
.1.3X7
.1.0X7
'.6.7X6
-.3 . 4X6
26:00 T±ae
tile, 0980035 tl-724 Acqs 7-3XX-1998 00,29,17 GC XI+ Voltage SIS 70S Soiae,3528
333.9338 Ts2 BSOB(256, 30, -3.0) PXD<7,S,3,0.10\,14112.0,l.OO\,T,T) XxpsBDBSUS
TXIANSLX LABS Text: 201-204 TLH44376A
1001
80:
60:
40:
201
AS..
i
23,00 24:00 2S\00 '
4X7 2.0X7
6.95X7
t
A
\j v _
.1.6X7
-1.3X7
-8.0X6
-4.0X6
26,00 Mae
Tile, 0980035 tl-724 Acq, 7-JAN-1998 00,29,17 GC SH- Voltage SIS 70S «oife:2192
327.8847 f,2 SSUB(256,30,-3.0) PXD(7,5,3,0.10\rB768.0,1.00\,r,T) XxptXDBSaS
TRIANGLE LABS Texts 201-204 TLXI44376A
1001
so:
60:
40:
20:
0:
A1.03X8 -2.5X7
^^_
33,00 ' 24 ',00 25,00
1 V
'-2.0X7
-1.5X7
.9.9X6
.4.9X6
0.0X0
26\ 00 Time
riletU980035 tl-724 Acqs 7-JJUT-1998 00,29,17 GC XH- Voltage SIX 70S
330.9792 r,2 XxptNOBSUS
TXIASSLX LABS Text: 201-204 XLIt44376A
1001
80:
60:
40:
20:
0:
22,57 23,29 24,02 ^l^,^^*!^^^^!^^5^^^^*^!--^ ^f4'517
'Vs^ "+•
S3', 00 ' ' 24:00 35,00
.3.6X7
J2.7X7
.1.8X7
.9.0X6
0.0X0
26, 00 Time
358
-------
rU.e:O980035 tl-724 Acq: 7-J2UT-1998 00:29:17 SC XH-
339.8597 f:2 BSUB(25S, 30, -3.0) PXD(7,5,3,0.10\,4080
Voltage SIS 70S Noise: 1030
.0,1.00\,f,T) 1
IxplHDBSUS
TSIANSLX LABS Text:201-204 XLIt44376A
1001
80.
SO.
40.
20.
A7
A3 . 29X6
A
A
/
H A/
27:00
t4X6
A3. 57X6
l\
A
J..75X6 A \y^3.23
A /\/ l A /
VLJYUV
38:00
TUet0980035 tl-724 Acq: 7-J3UT-1998 00:29*17 SC XH-
341.8567 T:2 BSUB(256,30,-3.0) PXD(7, 5, 3, 0.10%, 5515
%S Al . 95X6
\ A A
\A/V. 1
29 tOO
^..7X6
A3 . 15X6
i
A
A /\
\ /\
W V AS. 26X5
.1.3X6
.1.0X6
.6. 7X5
.3.4X5
0.0X0
30:00 Mae
Voltage SIS 70S Boise: 1379
.0,1.00\,e,T) t
*ptNDB5aS
TSIASSLX LABS Text: 201-204 TLH44376A
1003
80.:
60-.
401
201
Q "
A4..
I
,
A2.11X6 I
I
A
A/
/ V
27:00 '
2X6
A3. 32X6
ft A
pj. 1X6
A2.11X6
. A
11.1715 A \\A1.94J:6 *-L'jl*° l\ l\
A \ \ /\/
\/V _w Y V / v
V V-— ^ 1 VJ
28tOO
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\ A A /
v A/ V /
\s V V _ J
29:00
'\ \
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V X'- ,A- ^ ^
.8.8X5
.6.6X5
.4.4X5
.2.2X5
0.0X0
JO: 00 T±ae
Voltage SIS 70S Noiao:115
351.9000 T:2 3SUB(2SS,30,-3.0) PXD(7,5,3,0.10\,460.0,1.00*,f,T) Xxp-.mBSUS
TRIASSLX LABS Text:201-204 TLXt44376A
1001
80.
SO:
40:
20:
27:00
A7.
28:00
Tile:U9B0035 tl-724 Acq: 7-J7OT-1998 00:29:17 SC XI+
2X7
-2.0X7
A6.92X7
V_ /
29:00
V
ll . 6X7
.1.2X7
.8.0X6
.4.0X6
30:00 Tiae
Voltage SIS 70S Hoiae:90
353.8970 T:2 BSUB(256,30,-3.0) PXD(7,S,3,0.10\,360.0,1.00\,T,T) Xxp:KDB5US
TSIASSLX LABS Text:201-204 TLIt44376A
1001
so:
so:
40:
20:
27:00
AS. 2
fl
ft
/
28:00
T±le:O980035 tl-724 Acq: 7-JAS-1998 00:29:17 SC XI+
330.9792 F:2 Sxp:lO3B5US
-1.3X7
JA4 . 60X7
1
23:00
\^
.1.1X7
.8.0X6
-.5.3X6
_2. 7X6
JO: 00 Time
Voltage SIS 70S
TBIANGLX LABS Text:201-204. TLIt44376A
1001
80.
$0:
40:
20:
o:
26:53 27:11 27:36
27:51 28:19
28^42 39
^17 25:42 J0:ll_ JOjJl C*.7X7
• '---u - '- ~' j- "n ^v»« "; -- — «~>^i»i -- •• — ••• — • — • • — • r~
27:00
28:00
ttlei0980035 tl-724 Acq: 7-J3UT-1998 00:29:17 SC XI+
409.7974 F:2 XxptNDBSUS
29:00
'.3.8X7
'-2.8X7
IJ..9X7
'-9.4X6
•o.oxo
30:00 Tiae
Voltage SIS 70S
TSIAXGLX LABS Text:201-204 XLIt44376A
1001
80.
60.
40:
20:
o:
27:56
-2.7X4
| 28: 39
36 '"" 27:13
27:00
,
^
28:00
A , 38t57\
2^:00 '
30:01
29:46 1 I
29, 30 [ Jll|Ja|jj17
'.2.2X4
.1.6X4
'.1.1X4
.5.5X3
' 0 . OEO
' JO. -00 ' ' T±ae
359
-------
f2j.a:U9 80035 iI-724Jicq: 7-JAX-199O QOtJSil/ GC SH- VoJLtage SIX 70S tiaia»:S4
355.8546 f,2 BSVB(256,30, -3.0) PXD(5,5,3,0.05\,336.0,1.00\rT,X) Exp:SDB5US
XXIASSLX LABS Text:201-204 TZJ#44376A
1001
80.
60.
40.
20.
A1.21Z6
Al.
-4.1X5
.3.3X5
.2.4X5
1.6X5
8.2X4
27:48 28,00 28,12 28,24 28*36 28,48 29,00 29,12 29,24 29,36 29,48 30,00 30,12
r±le>U980035 #1-724 Acq: 7-JAN-1998 00,29,17 GC XH- Voltage SIS 70S SOiae,66
357.8516 r,2 BSO3(256,30,-3.0) PXD(5,5,3, 0.05\,264.0,1.00\,F,T) XxptSDBSUS
TRIANGLE LASS Text,201-204 TLI#44376A
0.0X0
T±me
1001
80.
SO.
40.
20:
A1.79S6
A7.72XS
M.82SS
A2.65E5
k
.f**5.
A
.f \
£C
.4.4X5
3.5X5
2.6X5
1. 8X5
8.8X4
27,48 28,00 28,12 28,24 28*36 28,48 29,00 29,12 29,24 29,36 29,48 30:00 30,12 30,24
rila,U9a0035 #1-724 Acq: 7-JAS-1998 00,29*17 GC EH- Voltage SIX 70S Hoiae,6S
367.8949 Ts2 BSUB(256, 30, -3.0) PXO(5,5,3,0.05\r260.0,1.00\,T,T) XzpsHDBSOS
TSIANGLE LABS Text:201-204 TLI#44376A
1001 A3.59X7
80.
60.
40.
3°1 ' '7.32X6
T±me
1.1X7
.8.5E6
'.6.3X6
.4.2X6
2.1X6
27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48 30,00 30,12 30,24
r±J.a,U980035 #1-724 Aeq, 7-JMT-1998 00,29,17 GC Eli- Voltage SIX 70S Hoiae,61
369.8919 r,2 BSVB(256r30r-3.0) PXD(S,S,3,O.OS\,244.0,1.00\,r,X) XxptBDBSVS
TSIANGLE LABS Text:201-204 TLH44376A
1001 A2.40E7
.0.0X0
Tiae
27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29:24 29,36 29,48 30,00 30,12 30,24
r±lo,O980035 #1-724 Acqi 7-JMT-1998 00,29,17 GC XI + Voltage SIX 70S
330.9792 T,2 XzpiHDBSOS
rXIABGLX LABS Text,201-204 TLH44376A
• 00^ „_ ,. in, 10 2t,i42 ta.ni 10. f7 29,42 23 55
80.
60.
40.
20.
37.51
30 ill
27\48 2a',00 2a'il2 28,24 28', 36 28,48 29\00 29,12 29,24 29', 36 29', 48' 3o'i 00 3o':12 30':24
0.0X0
Time
.4.7X7
.3.8X7
.2.8X7
.1.9X7
,9.4X6
.0.0X0
Time
360
-------
\TiIe:a980035 tl-384 Acq: 7-JAK-1998 00,29:17 CC XX+ Voltage SIS 70S Soia*t63~S7~
373.8208 T-.3 BSCB(256,30,-3.0) PXD(7,5,3,0.101,25548.0,1.00\,r,T) XxpiSDBSOS
TRIANGLX LABS Text:201-204 TLH44376A
1001
80:
60:
40:
20:
A4.14X6
A3.25X6
A1.73X6\
AS. 58X5
Al . 64X6
. 24X5
31:00 31': 12 3l':24 31:36 31:48 32',00 32,12 32,24 32:36 32',48 33',00 33': 12 33~,24 33:36 33',48
TiletU980035 tl-384 Acq: 7-JAN-1998 00,29,17 CC XH- Voltage SIX 70S lToiae:5521
375.8178 r,3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,22084.0,1.00\,T,T) XxpiNDBSUS
TXIANGLX LASS Text:201-204 TLIt44376A
1003( A3.27X6
80:
60:
40:
20:
oj
Al . 41X6t
A2.65X6
A4 . 62E5
A1.30E6
A4.35XS
l\
y V
A2.74X5
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32,36 32^48 33166' jji 12' jjii* ' jj- 36' 33^48
Tlle,U980035 tl-384 Acq: 7-JAN-1998 00:29,17 GC ZZ> Voltage 5X5 705 Noiae:1560
383.8639 Ti3 BSVB(256,30, -3.0) PXD(7,5,3,0.10\,6240.0,1.00\,r,T) XxpiXDBSUS
TSIAKSLX LASS Text:201-204 TLH44376A
1001
80:
60:
40:
20:
ol
31:00 31:12 31:24 31:36 31:48 32,00 32:12 32:24 32:36 32,48 33,00 33:12 33:24 33:36 33:48
riletU980035 41-384 Acq: 7-JAN-1998 00:29,17 GC XH- Voltage SIS 70S Koine:2296
385.8610 r,3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.10\,9184.0,1.00\,r,T) Ex.
TSIAXSLX LABS Tejct:201-204 TLH44376A
1001
80:
60:
40:
20:
o:
A6. 5X7
A4.42E7
31:00 31:12 31:24 31,36 31:48 32:00 32:12 32:24 32^36 32:48 33:00 33:12 33,24 33:
\rilata980035 tl-384 Acq: 7-JXK-1998 00,29,17 GC EH- Voltage SIS 70S
392.9760 r,3 EzptXDBSUS
TSIASGLX LABS Text:201-204 TLIt44376A
31:23 31;S8 33,15 32^49 33,01 33:31
1001
so:
60:
40:
20:
oj
36 33: 48
33:44
- - - *
Jlioo 3i',12 3i\24 3l',36 3l',48 32\00 32,12 32,24 32,36 32', 48' jji 00' 33', 12' 33,24 33,36 33,48
Tilm,U980035 tl-384 Acq, 7-JATT-1998 00,29,17 GC EH- Voltage STB 705
445.7555 Ft3 XXptSDBSUS
TRIANGLE LABS Text:201-204 TLH44376A
1001
eo:
60:
40:
20:
ol
32
31,41
31,16
36
33:23
32,49 33,05
31:00 31:12 3l',24 31,36 31:48 32,66 32,12 32\24 32:36' 32\48
35
33,24 33,36 33,48
-1.2X6
.9.7X5
.7.3X5
4.9X5
2.4X5
0.0X0
TiMe\
.9.7X5
7.8X5
5.8X5
3.9X5
1.9X5
0.0X0
Timel
0.0X0
Tiael
-2.1X7
Ll. 6X7
-.1.2X7
-8.2E6
I
-.4.1X6
.0.0X0
T±ae\
-2.6X4
'.2.1X4
.1.5X4
.1. 0X4
-.5.1X3
.0.0X0
Time\
361
-------
file,Q980035 tl-384 Acq, 7-JMi-lHSto ttu:J9:17 SC SH- Voltage SIS 70S Nolle, 19JO
389.8156 Tt3 BSOB(356,30,-3.0) PXa(7,5,3,0.10\f7730.0,1.00\,T,T) SxptXDBSUS
TXIAHSZX LABS Tert,201-204 TLH44376A
10 0\ A1.S5X6
80.
60.
40.
20.
A3.30X5
A
A3. 42X5
A3. 08X5
31>36 31i48 33tOO 32:12 32,24 32:36 32:48 33:00 33:12
TileiU980035 tl-384 Acq: 7-JUT-1998 00,29,17 SC EH- Voltage SIS 70S No±ae:18S4
391.8137 ft3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,7536.0,1.00\,r,T)
TSIASSLX LABS Tarts301-204 XLH44376A
100\ A1.21X6
80.
60.
40.
20.
33124
A3.80X5
AS.93X5
A3.16X5
A 3.01X5
31': 36 31:48 32:00 32:12 32:24 32:36 32:48 33': 00 33:12
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401.8558 r,3 BSUB(256,30,-3.0) PXD(7,S,3,0.10\,8412.0,1.00\,T,T) XxptSDBSVS
LABS Tojct:201-204 TLH44376A
100\ A4.83X7
A4.25X7
80.
60.
40.
20.
33:24
A2.69X
31:36 31,48 32:00 32,12 32:24 32:36 32:48 33:00 33:12
rile,U98003S tl-384 Acq: 7-JKR-199S 00,29:17 SC XI+ Voltage SIX 70S Noise: 1644
403.8529 T:3 BSUB(256,30,-3.0) PXO(7,5,3,0.10\,6576.0,1.00\,r,T) EzpiNDBSUS
TRIANGLE LABS Text:201-204 TLIt44376A
100$ A3.85E7
A3.47X7
80.
so:
40.
20.
33,24
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92.9760 Ti3 XxptSDBSUS
TJtlAOSZZ LABS Textt 201-204 XLIt44376A
10°* 31:48 31:58 ' 33,15 33,49 33t0i 33.13
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60.
40.
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33:12 33:24 33:36
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31:36
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33:00
32:12 32,24 32:36
32,48
33100
33112
33134 33
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36 Tia>
362
-------
rU.»:O980035 #l-545 Acq: 7-JMT-1998 00:29:17 SC XI* Voltage SIX 70S Hoi fat 3634
407.7813 T:4 asUB(256,30,-3.0) tXD(7,S,3,0.10\,10S36.0,1.00\,f,T) ExptHDBSUS
TSIAHOLX LASS Text:201-204 TLH44376A
100\ A4.54X6
80:
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40:
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AS.41X5
35100 35:12 35t34 35:36 35:48 36:00 36,12 36:24 36:36 36:48
rile:U9a0035 41-545 Acqi 7-J3UT-1998 00:29:17 SC £X> Voltage SIS 70S Xo±ae:2271
409.7789 T:4 BSVB(256r30, -3.0) PXD(7,5,3, 0.101,9084.0,1.00*,r,T) Sxp:SDS5US
TRIASSLX LASS Text:201-204 TLH44376A
10 0\ A4.14E6
A4.33S5
35', 00 35:12 35,24 35:36 35:48 36:00 36:12 36:24 36:36 36:48
JNJ.e:0980035 H-545 Acq: 7-JAX-1998 00:29:17 SC XI* Voltage SIS 70S Noise:2620
417.8253 T:4 SSUS<256,30, -3.0) PKD(7,5,3, 0.10\,10480.0,1.00\,r,T) Exp:8DB5US
TSXAKGZX LASS Text:201-204 TLH44376A
Al. 74X7
A1.28E7
35:00 35:12. 35:24 35:36 35:48 36:00 36:12 36:24 36:36
r±laiU980035 H-545 Adj: 7-JJUT-199S 00t29:17 SC SH- Voltage SIS 70S SoiaeiSOSO
419.8220 T:4 3SOS(256,30, -3.0) PXD(7,5,3, 0.10\,20200.0,1.00\,T,T) Sxp:KDBSUS
TXIAHSLX LASS Iexti201-204 TLH44376A
100S A3.S7E7
A3.01E7
36:48
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24
rlla:O980035 H-54S Acq: 7-JAN-1998 00:29:17 SC EH- Voltage SIS 70S
430.9729 T>4 Exp:KDS5US
TSIAHSLS LASS Text:201-204 XLH44376A
10°* 35:00 35:10 35^19 __"-S136:0036:12 36:26
60^
401
20:
OJ
36:36
36:48
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24
rila:U980035 tl-545 Acq: 7-JXN-1998 00:29:17 SC XI+ Voltage SIS 70S
479.7165 F:4 Sxp:JO)B5trS
TSIASSLX LASS Text:201-204 TLH44376A
36:36 36:48
-1.1X6
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TSIANGLX VMS Tuff 1201-204 TLI944376A
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LABS T*xt: 201-204 TLH44376A
0.0X0
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435.8169 Tt4 BSOB(256,30, -3.0) fXD(7,5,3,0.10\,7932.0,1.00\,TrI) Xxp:KDBSUS
TSIASSLX LABS Toit.1201-204 TLIt44376A
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437.8140 T,4 BSUB(256,30,-3.0) PKD(7,5,3, 0.10\,9516.0,J..OO\,r,T) Xxp:SDB5OS
XSIAHGLX LABS Texts201-201 TLH44376A
100\ A2.f8X7
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60.
40:
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35,12 35,18 35,24 35,30 35,36 35,42 35,48 35,54 36,00 36,06 36,12 36,18 36,24 36,30
Tll»,0980035 tl-545 Acq, 7-JAH-1998 00129117 SC XH- Woltigm SIS 70S
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VIAHGLX LABS Text,301-204 TLH44376A
36iOO
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441.7438 T:4 BSUS(256f 30, -3.0) PXO(7,5,3,0.10\,124.0f1.00\,r,T) XxptODSSUS
XSIAKSLX LABS Tart -.201-204 TLH44376A
1001
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443.7399 Ti4 33UB(2S6,30,-3.0) PXD(7,S,3,0.10\,3104.0,1.00\,r,I) ErpiBDBSUS
TRIANGLX LASS Tart:201-204 TLH44376A
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35:00 36:00 37:00 38:00
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430.3729 fi4 KxpiNDBSDS
TSIAHGZX LASS Text.:201-204 TX.H44376A
1004 36:41
35:19 35:51 36:2&\ . 37:12 37:39 38:36
801
701
601
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40.
301
201
101
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39:00
40:00
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<°L33 40,48,
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513.6775 Tt4 XxptOSSSUS
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1004
40:00
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TBIAHGLX LASS Text,201-204 TLI944376A
100* AS. 01X5
39,30 39:36 39:43 39,48 39,54
rll*ia980035 91-545 Acqi 7-JAK-1998 00,29,17 SC JSI+ Voltagu SIS 703 SoimatlS
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469.7779 Ti4 BSUB(356,30, -3.0) PXD(7,5,3, 0.10\,84.0,1.00\rT,T) XxpiRDBSUS
TRIASGLE LASS Text:201-204 TLH44376A
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r±leiO980035 tl-545 Acqs 7-JZH-1998 00:39,17 SC KH- Voltage SIS 70S Boise122
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TBIANGLX LASS Toxtt201-204 TLH44376A
100\ A4.J7Z7
40:00
39', 30 39,36 39,42 39,48 39,54
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A2.25E6 3.8E5
•A
/ \
/ \
f ^^__
39J12 39:24 39:36 39:48 40:00 4o!l2 40J24 40:36
_3.1E5
_2.3E5
_1.5E5
_7.6E4
_O.OEO
Time
545 Acq: 7-JAN-1998 00:29:17 GC EI+ Voltage SIR 70S
: NDB5US
204 TLI#44376A File Text :TRIANGLE LABORATORIES, INC.
39:36 r5.9E6
A
/ \
/ \
J ^^__ _'
39J12 39:24 39:36 39:48 40:00 4o!l2 40:24 40:36
_4.7E6
_3.5E6
L2.3E6
L1.2E6
: O.OEO
Time
-------
TLI Project
Client Sample:
44376A
201-204
Method 23 TCDD/TCDF Analysis (DB-225)
^ Analysis File: P980103
Client Project:
Sample Matrix:
TLI ID:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-19A-D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Spike File: SPC2NF04
ICal: PF22206
ConCal: P980092
Sample Size:
Dry Weight
GC Column:
1.000
n/a
DB-225
Dilution Factor n/a
Blank File: P980094
Analyst: WK
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
JR.'T
WJ.S-TCDF
0.07
0.73
23:06
B
\u 'Ami. (ng)
% Recovery QCtlmfts BatJo
RT
I3C,r^3,7,8-TCDF
3.6
89.7
40%-130%
0.76
23:04
Recovery Stancferd
Batto
RT
Flags
0.81
21:53
Data Reviewer
01/09/98
Page 1 of
11NF PSR i Mil. P.AKNft IIMWI
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 10:17 01/09/98
374
-------
Initial
..Date..
Data Review By:
Calculated Noise Area:
1.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/07/98
Listing of P980103B.dbf
Matched GC Peaks / Ratio / Ret.
Tlae
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total. Area. .. Area. PeaJc. 1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
TCDF
304-306 DC ML 0:00
18:26
DC SN 18:34
19:03
19:27
19:35
19:42
19: S3
20:00
20:09
20:18
20:27
20:36
20:46
21:09
DC SN 21:19
21:36
21:41
21:51
22:05
22:19
22:30
22:56
23:06
23:18
23:34
23:42
24:30
25:14
DC WH 25:32
304-306 26 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 21:34
DC WL 21:49
23:04
DC SN 23:26
23:41
DC WH 24:07
DC WH 25:08
316-318 2 Peaks
0.65-0.89
RO 0.45
0.69
RO 1.81
RO 1.57
RO 0.97
0.75
0.79
0.79
0.78
0.75
0.75
0.72
0.70
0.77
0.75
0.68
0.71
0.81
0.77
0.87
0.72
0.70
0.78
0.73
0.67
0.74
0.77
0.75
RO 0.93
RO 1.13
0.65-0.89
0.87
0.73
RO 0.90
0.76
0.69
RO 0.46
RO 1.11
RO 0.93
0.792-1.101
1.03
21.93
0.28
2.28
21.33
22.72
49.12
19.40
3.04
22.73
53.58
28.84
81.00
30.97
157.50
1.06
44.36
7.93
42.29
39.46
8.24
55.77
45.55
39.89
49.33
63.86
52.99
34.18
7.88
4.58
1,006.17
8.98
2.02
11.65
9.71
21.65
8.57
1.33
9.71
22.96
12.10
33.23
13.49
67.73.
18.41
3.56
18.42
18.33
3.45
23.06
19.90
16.86
19.83
27.23
22.97
14.66
4.15
12.95
1.29
12.05
13.01
27.47
10.83
1.71
13.02
30.62
16.74
47.77
17.48
89.77
25.95
4.37
23.87
21.13
4.79
32.71
25.65
23.03
29.50
36.63
30.02
19.52
4.45
0.000
0.799
0.805
0.826
0.843
0.849
0.854
0.862
0.867
0.874
0.880
0.887
0.893
0.900
0.917
0.924
0.936
0.940
0.947
0.957
0.967
0.975
0.994
1.001 2378-TCDF AH
1.010
1.022
1.027
1.062
1.094
1.107
0.957-1.043
2.41
13.41
26.00
2,350.41
1.59
5.84
4.23
24.76
2,356.25
1,012.46
2.54
1,337.95
5.58
0.000
0.935
0.946
1.000 13C12-2378-TCDF ISO
1.016
1.027
1.046
1.090
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 08:49 Q.1/QZ88
-------
Page No.
01/07/98
Listing of P980103B.dbf
Matched OC Peaks / Ratio / Ret. Tine
Compound/
M_Z.... QC.Log Oait Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
0.
NL 0:00 RO
20:28 RO
21:36
21:53
22:39
23:12
WH 24:09 RO
WH 24:24 RO
WH 24:57
5 Peaks
65-0.89
1.61
0.98
0.80
0.81
0.77
0.73
0.42
0.34
0.73
Above: TCDF / TCDD Follows
1.10
7.22
1,648.64
1,888.28
21.41
3.75
2.44
4.78
4.83
3,569.30
0.908-1.092
0.000
3.99 4.08 0.948
733.76 914.88 1.000 13C12-2378-TCDD IS1
847.43 1,040.85 1.013 13C12-1234-TCDD RSI
9.28 12.13 1.049
1.58 2.17 1.074
1.118
1.130
1.155
Column Description 'Why* Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Tine (mm:as)
Rat.l -Ratio of M/M+2 Ions
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Tiae Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
eHasP98Q103 tl-923 Acq: 7-JAN-
303.9016 Sxp:DB225
ZBXAMGZZ LASS Taxti201-204 XLH44376*
07: Jam EI+ Voltage SIS 70P
22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24 24:36 24:48
T±la:P980103 tl-923 &cq:7-J*N-98 07:36:14 XH- Voltage SIS 70P
315.9419 Sxp:DB225
TRIANGLE LABS Text:201-204 TLH44376A
100* 23 04
95:
90.
85.
80:
75:
65.
60:
55j
50:
45:
40.
35:
30.
25.
20:
15:
10:
5:
0:
O.OEO
25:66'25:12'25i24' lime
-2.7E6
'.2.5X6
'.2.4K6
.2.3E6
'•.2.1E6
'.2.0E6
'•.1.9X6
.7X6
-.1. 6X6
.5X6
.3X6
-.1.2X6
.1X6
.9.3X5
.8.0X5
'•-6.6X5
.5.3X5
'•.4.0X5
L2.7ZS
.3X5
22,36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24,24 24:36 24:48
0.0X0
25:00 25:12 25:24 T±me
377
-------
rU.aify80J.OJ tl-923 Acq>7-JMf-yo U/:JO:J.« t.j.r v
-------
tl-923 Acqi7-JAH-yo u/uoiAl sx+ Voltage SIS 70S Hoi**,254
319.8965 BSU3(256,30,-3.0) PXD(5,3,l,0.10\,1016.0,0.00\fr,r) Kxp,DB225
TSIMKLX LABS Text:201-204 TLH44376A
100*
80.
60.
40.
20.
A1.52XS
A4.10X4 A7.95X4
i\ A A "-r ^A.
50.00 21,00 22,00
Tile,P980103 tl-923 Acq,7-JKS-9S 07,36,14 XH- Voltage SIS 70V Soime,332
321.8936 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,1328.0,O.QO\,T,T) XxptOS225
TSXAHGLX LABS Tajct: 201-204 XLIt44376A
1004
00.
60.
40.
20.
Al . 72X5
A4.S1E4
*.98Z4
*7.99X3
20:00 21:00 22:00 23:00
riIe:P980103 tl-923 Acq:7-J3UT-98 07:36:14 XH- Voltage SIB 70V Noiae:303
327.8847 BSUB(256,30,-3.0) PKD(5,3,1,0.10\,1212.0,0.00\,T,T) Exp,DB225
TSIASSLX LABS Text:201-204 TLIt44376A
1004 A1.52X7
80.
60.
40.
20.
Al.05X6
A
=9-
20,00 21:00 22:00 23:00
TiletV980103 tl-923 Acq,7-J7Oi-98 07:36:14 XI+ Voltage SIS 70V Bolae,498
331.9368 BSU3(256,30,-3.0) PXD(5,3,1,0.10\,1992.0,O.OQ\,T,T) KxptDB225
T&IANGIX LABS Text:201-204 TLIt44376A
1004 AS.47X6
80.
60.
40.
20.
A7.34X6
20:00 21:00 22:00 23:00
rlle:P980103 tl-923 Acqt 7-JZ1T-98 07:36:14 XI+ Voltage SIS 70V Boise,309
33.9338 BSUB(256,30,-3.0) PXD(5,3,1,0.10\,1236.0,0.00\,T,T) Xxp,DB225
TRIANGLE LABS Text,201-204 TLH44376A
1001
80.
60.
40.
20:
4X7
24tOO
A2.56X3
'24'-. oo
24tOO
24iOO
7.3X4
.5.9X4
.4.4X4
'.2.9X4
.1.5X4
.0.0X0
25 00 Tim
8.4X4
.6.7X4
.5.0X4
.3.4X4
_1. 7X4
.0.0X0
25 00 Tia
4.3X6
.3.5X6
.2.6X6
.1. 7X6
.8.7X5
.0.0X0
25tOO Tiae
^2.3X6
.9X6
_1.4X6
.9.3X5
.4.6X5
.0.0X0
25 00 Tia,
20tOO
2liOO
22iOO
2300
24iOO
25
-2.8X6
.2.2X6
J..7X6
.1.1X6
.5.6X5
.0.0X0
00 Tia,
379
-------
Tila:P9801Q3 tl-923 Acq:7-J&N-98 07:36:14 EI+ Voltage SIS 70P
303.9016 Exp:DB225
TRIAHGLX LABS Text: 201-204 XLIt44376A
1003
80.
SO.
40.
20.
a
21:09
1
20:36 II
19:42 1 \ .... 22:30
1 20:18 n if1 i ":56
19:27^ A 11 1 fliA ft ftftl
19:00 20:00 21:00 22:00 23:00
rile:P980103 tl-923 Acq:7-J3Ur-98 07:36:14 XH- Voltage SIS 70P
315.9419 Kxp:OB225
TSIAXGZX LABS Taxt:201-204 XLIt44376A
1001
80:
601
401
20.
23i04
l\
19:00 ' ' ' 20:00 21:00 22:00 23:00
r±le:P980103 tl-923 Actj:7-JXK-98 07:36:14 XI+ Voltage SIS 70P
319.8965 Xxp:D3225
TBIANGZS LABS Text: 201-204 TLH44376A
1001
aol
60:
40:
201
0'
19-16
I
19:49
fl
20:53 21:54
. . .. 19,oj[ _ J\ iQtlA^AA A, __j^A/V _ ^^^.^JL?!.
19:00 20:00 2l':0b 22:00 23\00
Tile:P980103 tl-923 Acq:7-J3UT-98 07:36:14 XH- Voltage SIS 70P
331.9368 Xxp:DB22S
TSIASSLX LABS Text:201-204 TLH44376A
1001
aol
601
401
201
ol
21:53
21:36 I
I
/I M
19:00 ' ' ' 20:00 ' 2li 00 ' ' ' 22:00 ' ' ' 23^00
Tlle:P980103 tl-923 Acq:7-JMT-98 07:36:14 XI+ Voltage SIS 70P
292.9825 Exp:DB225
TSIAHSLX LABS Text: 201-204 XZ.H44376A
1001
aol
60:
40:
20:
ol
vJS^r^Z^vJly^f^^^^v-^A^2 3^23is48 33iia 23:02
™* W'^T ^^y^^y^^j/^r^^^fftft^^
19:00 20:00 21:00 22:00 ' 23:00
r±latP9B0103 tl-923 Aoq:7-J3OT-98 07:36:14 EI+ Voltage SIS 70P
330.9792 Exp:OB225
TSIASGZX LABS Text: 201-204 TLH44376A
100*
80:
60:
40:
20:
ol
-1.1X5
97 * 7.J
*J t J*
i
A A
ft "h30
'•.9.1X4
.6.8X4
.4.5X4
.2.3X4
O.OEO
24:00 25:00 ' ' Tt««
-2.7X6
'.2.1X6
:1 . 6X6
'•.1.1X6
'•.5.3X5
' 0 . 0X0
24:00 25:00 Time
-7.6X4
23:54 24:30 35j°\
.6.1X4
'.4.SE4
13.1X4
.1 . 5E4
• 0 . OEO
24:00 2S':00 Tiaa
-2.3X6
.1.9X6
.1.4X6
.9.3X5
.4.6X5
O.OEO
24:00 25:00 Time
23:35 24:31 24:59
•^,-»YV>'VV'YV*"''*VVIr**~*Y^
.3.7X6
.2.9X6
.2.2X6
.1.5X6
.7.3X5
0.0X0
24\00 ' ' 25'tOO ' ' ' T±me
in •• ..1i rt u^~> rtjr^LJWVufWV^l/W mJ4 lVj~*VTll lA^lm> JUIftr\f*j4t*Jlft ^>.^« f-US*Ak^ *A . J*n^ A . /^«m Al*« n i~kta 1 i ft n an • m» i lA
W*+>t'*r*w~ **v* W*^*Y*r^^fw -T lY^^r*1! yH r v^y-y** i\aY*y^^v^*^*wW/^FV> /TV*»T*'*%/V^/>/^^**^r rt^^f^f^*'1t^
19:00 20:00 21:00 22:00 ' 23': 00
.2.9X6
.2.3X6
J..7X6
.1.1X6
.5.7X5
O.OEO
24\00 ' ' ' 25:00 ' ' ' Time
330
-------
Ref, lass 292.9825 Peak top
Height ,78 volts Span 288 ppi
Systei file naie
Dka filenaie
Resolution
(tap niter
lonization Mde
Switching
Ref, lasses 292.9825,
fl 292.9825
B 383.9816
D 315.9419
E 317.9389
F 319.8985
6 321.8936
H 327,8847
I 338.9792
J
K
L
H
1
El*
VOLTRGE
388.9761
338.9792
331.9388
333.9338
375,8364
Channel I 338,9792 Peak top
Height ,55 volts Span 288 ppa
381
-------
TLI Project: 44376A
Client Sample: CleanUp Blk
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980037
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
SOLVENT Date Received: 12/17/97
TLI Clean-Up Date Extracted: 01/05/98
Date Analyzed: 01/07/98
1.000 Dilution Factor n/a
n/a Blank File: U980037
DB-5 Analyst JM
Spike File:
ICal:
ConCal:
% Moisture:
%Lipid:
% Solids:
SPMIT204
UF51058
U980025
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3.7,8-PeCDD
1,2.3,4,7,8-HxCDD
l.Z3.6.7,8-HxCDD
1,2,3,7.8,9-HxCDD
l,Z3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
',2,3,4,7,8-HxCDF
.,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2.3.7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4.7,8.9-HpCDF
1,2,3,4.6,7,8,9-OCDF
ABlL$igt
ND
ND
ND
ND
ND
ND
0.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
d. EMPC
f
0.002
0.004
0.005
0.004
0.004
0.005
0.002
0.002
0.002
0.004
0.003
0.004
0.004
0.004
0.004
0.005
Ratto RT flags
0.82 39:36 J_
Totals
Total MCDD
Total DCDD
Total TriCDD
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total MCDF
Total DCDF
Total TriCDF
Total TCDF
Total PeCDF
Total HxCDF
Amt (n^ Number DL EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
<0.001
<0.001
<0.001
0.002
0.004
0.005
0.005
<0.001
<0.001
<0.001
0.002
0.002
0.003
Continued on next page
Pagel of 2 '
Flags
—
MTRJ>SRvl.01.LA]tt 6.10.081
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:07 01/10/98
382
-------
TLI Project 44376A
Client Sample: CleanUp Blk
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980037
rotate
Total HpCDF
internal Standards
13Cir2,3,7,8-TCDF
13C,2-2^,7,8-TCDD
13C,rl,2,3,7,8-PeCDF
13C,2-U,3.7,8-PeCDD
13C,2-l^,3,6,7,8-HxCDF
l3C,2-U,3,6,7,8-HxCDD .
13C12-l,2,3,4,6.7,8-HpCDF
13C,2-l,Z3,4.6,7,8-HpCDD
13Ci2-l,2v3,4,6J,8,9-OCDD
Alternate Standards {Type A}
13C,2-1.2,3,7,8,9-HxCDF
13Cl2-2,3,4,6,7,8-HxCDF
Recovery Standards
13CI2-U,3,4-TCDD
I3C12-U,3.7,8.9-HxCDD
' Aflit fa$//?2-1tottnts& Dt*.
ND
Atn£. {0
-------
Initial
, .Date.
Data Review By:
111
Calculated Noise Area:
2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/10/98
Listing of CJ980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area.,
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
0
D
0
0 .
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
N
320-322
13C12-TCDD
332-334
DC
DC
D
DC
D
D
DC
D
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
SN
SN
SN
SN
SN
SN
0
NL
WH
WH
WH
WH
WH
4
NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
0
NL
0
21
24
24
25
25
25
26
26
:00
:28
:00
:33
:09
:16
:32
:03
:14
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65-0.89
0
1
2
0
0
0
0
0
1
.44
.23
.26
.00
.39
.41
.31
.34
.31
Peaks
0
24
24
25
25:
:00
:13
:38
:00
:31
25:55
25:
26:
26:
26:
:57
:16
;17
:22
0
RO
RO
RO
RO
RO
RO
RO
.65
0
0
0
1
0
1
0
1
0.
0.
Peaks
0:
22:
23:
23:
23:
23:
24:
24:
25:
25:
26:
26:
00
48
14
19
33
47
07
45
19
34
07
33
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
-0.89
.95
.56
.78 9
.08
.68
.64
.69
.43
.95
.53
10
65-0.89
0.
0.
1.
0.
0.
0.
5.
7.
1.
0.
0.
0.
09
54
52
74
04
58
26
21
32
60
78
75
Peaks
0:
00
0.
RO
8
5
5
0
9
9
2
11
4
0
7
39
,898
170
38
14
24
5
12,
10.
.18
.45
.31
.18
.08
.47
.94
.65
.92
.00
.98
.51 17.19
.83 4,345.47
.36 103.69
.43 15.58
.04
.11
.70
.28
.16
0.867
0
0
0
0
1
1
1
1
1
0.959
0
30.64 0
5,553.36 1
96.25 1
22.85 1
1
1
1
1
1
-1.079
.000
.871
.974
.997
.021
.026
.037
.058
.065
-1.041
.000
.983
.000 13C12-2373-TCDF ISO
.015
.036
.052
.053
.066
.067
.070
,147.13
0.
4.
1.
1.
0.
0.
0.
0.
1.
39
53
95
48
16
97
48
51
31
2.51
1.
2.
0.
41
98
00
65-0.89
2.
40
11.
91
0.895-1.047
0.000
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
0.921-
0.
900
917
920
930
939
952
977
999 2378 -TCDD AN
009
031
048
1.079
000
Triangle laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:08Q4/lp/fl8
-------
Page No•
01/10/98
Listing of 0980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.
Rel.RT Compound.Name.. ID.. Flaga.
332-334 •
PeCDF
340-342
D
D
340-342
13C12- PeCDF
352-354
352-354
PeCDD
356-358
DC
DC
DC
D
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
7
KL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
7
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
24:09 RO
25:10
25:20
25:40
25:49 RO
25:55
26:03 RO
Peaks
0
26
27
27
27
28
28
29
29
29
30
:00
:34
:17
:34
:44
:18
:43
:24
:40
:51
:32
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.60 25.01 10.88
0.82 10,108.54 4,559.84
0.79 7,774.25 3,440.92
0.69 307.27 125.92
0.20 35.42 15.41
0.71 34.33 14.28
0.48 97.10 42.24
18,381.92
.32-1.78
0
0
0
0
1
0
0
0
0
0
0
.15
.28
.85
.75
.32
.46
.87
.51
.24
.24
.72
Peaks
0:
27
28:
29:
29:
29:
29:
30:
:00
:41
:35
:01
:09
16
35
13
1.
RO
RO
RO
RO
RO
RO
0
0
3
5
9
3
2
3
0
0
3
0
.48
.95
.73
.05
.41
.01
• 16
.83
.87
.97
.26
.00
32-1.78
1,
0,
1.
1.
0.
1.
0.
1.
Peaks
0:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
30:
30:
00
11
34
51
03
23
31
39
45
51
01
19
26
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-
1.
0.
5.
0.
20.
0.
2.
1.
4.
2.
1.
6.
2.
,31
,67
55
17
97
99
54
73
1.78
33
45
54
78
60
75
70
85
16
06
13
29
13
0.28
8
8,807.
91.
50.
90.
9.
20.
9,078.
: PcCDI
0.
0.
2.
1.
0.
1.
1.
2.
1.
1.
1.
0.
2.
.95 5.44
53 5,357.35
,26 55.47
03 30.41
40 70.71
95 6.05
34 12.88
46
28
54
86
02
13
40
17
88
25
20
28
43
35
18.17 0.953
5,548.70 0.993 13C12-1234-TCDD RSI
4,333.33 1.000 13C12-2378-TCDD IS1
181.35 1.013
78.11 1.019
20.05 1.023
88.40 1.028
0.925
0
0
0
0
0
0
1
1
1
1
1
-1.065
.000
.929
.955
.964
.970
.990
.005
.029
.038
.044
.068
0.860-1.140
0
8.17 0
3,450.18 1,
47.25 1.
31.51 1.
35.45 1.
11.11 1.
7.46 1.
.000
.969
,000 13C12- PeCDF 123 IS2
.015
,020
024 13C12- PeCDF 234 SOR1
035
057
0.935-1.. 022
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
952
965
975
981
993
997
002
005
008
014
024
028
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:08 01710/98
385
-------
Page No.
01/10/98
Listing of 0980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
174-376
13C12- HxCDF
384-386
384-386
HxCDD
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
0
NL
SN
SN
7
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
5
HI
SN
SN
SN
SN
SN
SN
SN
SN
30:32
Peaks
0:00
28 : 12
28:34
29:36
29:43
29:54
30:03
30:10
30:18
30:24
Peaks
0:00
31:05
31:10
31:19
31:41
31:52
32:03
32:11
33:23
33:41
Peaks
0:00
31:04
32:08
32:37
33:12
33:23
Peaks
0:00
31:32
31:35
31:52
32:01
32:08
32:20
32:33
32:37
RO
1
RO
RO
RO
RO
RO
RO
2
.32
1
1
0
1
1
1
0
0
1
1
.58
-1.78
.00
.06
.50
.50
.59
.88
.67
.72
.61
.47
1.40
0
.00
1
.032
0.865-1.135
0
1
2
3,551
614
125
48
20
30
26
.16
.63
.20
.87 2,132.05
.34 377.00
.26 92.56
.29 29.35
.37 12.38
.15 18.58
.73 15.91
0
0
0
1,419.. 82 1
237.34 1
49.12 1
43.95 1
17.09 1
11.57 1
10.82 1
.000
.953
.965
.000 13C12-PeCDD 123
.004
.010
.015
.019
.024
.027
IS3
4,417.01
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
05-1.43
0
0
0
1
1
.87
.83
.87
.82
.54
5.00
4.
0,
.31
,48
3.92
3.15
2
3
2
1
3
.98
.05
.64
.23
.70
1.21
1.52
2.04
0.87
0.74
0.
.00
43-0.59
0.
1.
0.
0.
0.
0.
05-
0.
3.
1.
0.
1.
4.
2.
0.
1.
71
23
50
51
19
50
1.43
80
74
69
54
46
67
80
78
71
4.
5.
5,695.
6,312.
9.
4,656.
26
75 4.68
03 1,909.27
25 2,133.84
15 3.09
05 1,543.48
0.962-1.047
0
0
0
0
0
0
.000
.967
.970
.975
.986
.992
0.997 123478-HxCDF
AN
1.002
1.039 123789-HxCDF
1.
.048
AN
0.876-1.124
0.
3.81 0.
3,785.76 1.
4;i78.41 1.
15.91 1.
3,112.57 1.
000
967
000 13C12-HXCDF 678
015 13C12-HXCDF 234
033
039 13C12-HXCDF 789
IS4
ALT 2
ALT1
16,678.23
: HxCDF / HxCDD Follows --'
0.
0.
1.
0.
3.
2.
1.
0.
4.
07
43
14
89
38
49
23
94
48
0.958-1.014
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
961
963
972
976
980
986
992
994
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:08 01710/98
386
-------
Page No.
01/10/98
Listing of U980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2:. Rel.RT Compound. Name. . ID.. Flags.
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN 32:44 RO 1.72
SN 33:07 RO 0.41
SN 33:09 RO 0.78
SN 33:23 RO 3.62
SN 33:30 RO 1.46
0 Peaks
1.05-1.43
NL 0:00 RO 1.52
32:12 1.30
32:48 1.21
33:07 1.21
33:27 RO 0.80
4 Peaks
0.88-1.20
NL 0:00 RO 1.26
SN 36:36 RO 0.27
SN 36:52 RO 0.29
0 Peaks
0.37-0.51
NL 0:00 RO 0.55
35:01 0.41
35:28 RO 0.86
35:33 RO 0.36
35:47 RO 0.87
35:49 RO 0.62
36:01 RO 1.05
36:23 RO 0.65
36:32 RO 1.07
8 Peaks
0.88-1.20
NL 0:00 1.00
SN 35:07 1.09
SN 35:49 RO 0.75
SN 36:16 RO 2.12
SN 36:30 RO 0.46
0 Peaks
0.88-1.20
NL 0:00 1.00
36:02 1.03
1 Peak
2.20
1.16
0.98
2.20
1.79
0.00
4.12
15.14 8.56
4,832.68 2,642.35
6,159.80 3,378.48
108.64 60.14
11,116.26
• Uvfnn / Urs^T^E1 CV» 1 1 <-iun
HXlfUU / np^Ur rOJL^OwS - -
3.84
1.90
1.94
0.00
8.38
4,102.52 1,201.45
23.56 14.14
39.89 12.19
9.79 5.94
12.97 5.55
6.96 5.07
5.77 2.59
12.70 9.44
4,214.16
: HpCDF / HpCDD Follows —
0.08
3.41
2.02
1.57
0.96
0.00
6.61
3,899.39 1,981.38
3,899.39
Hof^nn / n^t'w-fnn »nH f"HE*
0.998 123478-HxCDD
1.010 123789-HxCDD
1.011
1.018
1.021
0. 970-1. 030
0.000
6.58 0.982
2,190.33 1.000 13C12-HXCDD 678
2,781.32 1.010 13C12-HXCDD 789
75.28 1.020
0.996-1.049
0.000
1.045
1.053
0.943-1.114
0.000
2,901.07 1.000 13C12-HpCDF 678
16.36 1.013
33.78 1.015
6.80 1.022
9.01 1.023
4.83 1.029
4.01 1.039
8.82 1.043 13C12-HpCDF 789
0.975-1.005
0.000
0.975
0.994
1.006
1.013
0.972-1.028
0.000
1,918.01 1.000 13C12-HpCDD 678
AN
AN
IS5
RS2
IS6
SUR4
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:08
-------
Page Ho.
01/10/98
Listing of O980037B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak. 2. . Rel.RT Compound.Hame.. ID.. Flags.
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0
34
35
35
35
35
36
36
36
37
37:
37:
38:
38:
39:
39:
39:
39:
40:
40:
40:
:00
:26
:01
-.12
:28
:39
:06
:16
:36
:11
:17
:25
:01
48
02
07
22
38
08
18
43
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76
1
1
0
3
2
2
0
2
0
0
0
1
2
0
0
0
4
0
0
2
0
-1.
.00
.81
.33
.33
.09
.32
.83
.42
.25
.02
.07
.88
.07
.74
.23
.64
.73
.48
.13
.24
.63
Peaks
0.08
0.40
0.59
0.45
1.00
0.95
2.12
0.59
0.55
0.06
0.06
0.49
0.77
0.74
0.74
0.83
0.28
.00
.62
.64
.10
0.899-1.101
0.000
0.870
0.384
0.889
0.896
0.900
0.912
0.916
0.924
0.939
0.941
0.945
0.960
0.980
0.986
0.988
0.994
1.001
1.013
1.018
1.028
0.00
OCDD 0.76-1.02
458-460 DC NL 0:00 RO 1.33 0.06
AN 39:36 0.82 9.93
DC SN 40:05 RO 0.41 0.59
<58-460 1 Peak 9.93
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.08
39:36 0.87 5,658.40
470-472 1 Peak 5,658.40
0.899-1.101
0.000
4.46 5.47 1.000 OCDD AN
1.012
0.996-1.004
0.000
2,640.48 3,017.92 1.000 13C12-OCDD IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 lona
OK -RO-Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ••*
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
ril»tU9a0037 tl-734 Acq: 7-JXN-1998 02:18:30 GC EH- Voltage SIX 70S ltoj.mmtj.779
303.9016 Ti2 BSUB(2S6,30,-3.0) PXD(9,5,3,0.10\,7116.0,1.00\,r,T) SxptSDSSUS
TRIANGLE LASS Text-.CLEANUP BLANK TLIH4376A
100*
A3.94X4
32100 23:00 24',00 25iOO
rile:U980037 tl-724 Aeqi 7-JJUT-1998 02>18t30 GC XH- Voltage SIS 70S Nolae:4023
305.8987 T:2 SSUS(256,30, -3.0) PKD(9,5,3 ,0.10\,16092.0,1.00\,T,T) Kxp:NDB5US
TSIANGZX LASS Text:CLEANUP BLANK TLH44376A
1001
26100
22:00 23t00 24:00 25:00
file:U980037 tl-724 Ac?: 7-JAH-1998 02:18:30 GC XI+ Voltage SIS 705 Noises 2143
315.9419 T:2 BSUB(256,30,-3.0) PXD(9,5,3,0.10\,8572.0,1.00\,r,T) XxpiNDBSUS
TRIANGLE LABS Text:CLEANUP BLANK TLH44376A
100* A4.35E7
80:
sol
40:.
201
26100
22:00 23:00 24:00 25:00
rilaiO980037 tl-724 Aoqi 7-JAN-1998 02:13:30 SC EH- Voltage SIS 70S Noiae:2256
317.9389 fi2 BSUB(256,30, -3.0) PXD(9,5,3,0.10\,9024.0,1.00\,r,T) SxpsBDBSOS
TBIANGLS LABS Text!CLEANUP BLANK TLH44376A
1004 AS. 5^5X7
80:
sol
40:
20:
I V
26100
22:00 23:00 24:00 25:00
ri!e:U980037 tl-724 Acqi 7-JAN-1998 02:18:30 GC XI+ Voltage SIS 70S
330.9792 T:2 Exp:NDB5US
TRIANGLE LABS T&rt: CLEANUP BLANK TLH44376A
1001
26:00
60:
40:
20:
0:
25:24 25:4
22:00 23:00 24:00 2SsOO
Tile:U980037 tl-724 Aoj: 7-JAN-1998 02:18:30 GC XI+ Voltage SIS 70S
375.8364 F:2 Exp:NDB5US
TRIANGLE LABS Text:CLEANUP BLANK TLIt44376A
26100
1001
80:
so:
40:
20:
o:\
25
24135
21:5\
i
24 1 21
23108
32:38
JUU_
I 23i48
23,361
03
26:03
4QIUJ i
25,24 I ?e*al 11
JJ WJ_J^JLiM
9.6X6
-.7.7E6
.5.8X6
.3.8X6
il.9E6
0.0X0
Time
32:00
23:00
24:00
25:00
26:00
.1.2X7
.9.9X6
.7.4X6
.4.9X6
.2.5X6
.0.0X0
Time
.3.4X7
.2.8X7
.2.1X7
.1.4X7
.6.9X6
.0.0X0
Tiae
.1. 8X4
.1. 4X4
.1.1X4
.7.2X3
.3. 6X3
.0.0X0
Tiae
389
-------
Tile>a980037 tl-724 Acqt 7-JAK-1998 02113130 GC EI+ Voltage SIS 70S Naif at 34
319.8965 Tt2 BSUB(256,30, -3.0) ?XD(7,5,3,0.10\,336.0,1.00\,r,T) Exp:NDB5US
TRIANGLE LABS T*xt:CLEANUP BIMtf TLIt44376A
100* A6.47X4
A1.23E4
A1.67X4 I I A4.24E3
23,00 24100 25100 26:00
rHat0980037 fl-724 Acqt 7-JXK-1998 03tl8i30 SC XH- Voltage SIB 70S Sola*,991
321.8936 Tt2 3SUB(256,30, -3.0) PXD(7,5,3, 0.10%,3964.0,1.00\,r,T) SxptHDBSUS
TSXASGLS LABS Text:CLEANUP BLAKK TLH44376A
1001
23': 00 24:00 25,00 26:00
F±l»tU980037 tl-724 Acqt 7-JAN-1998 02il8t30 SC EI+ Volttgm SIS 70S Noia*i8092
331.9368 Ti2 BSUB(256e30,-3.0) fXD(7,S,3t0.10\r32368.0,1.00\rT,T) ExptSDBSUS
TSIAKSLX LASS Taxt:CLEANUP BtANX TLIt44376A
001
ao:
60:
40:
20:
o:
A4.
J
6E7
H3.44E7
A
III
v V.
_i
.a
.5
.4
.2
0
23100 24:00 25:00 26:00
TilatU980037 tl-724 Acqt 7-JAN-1998 02:18,30 SC EH- Voltage SIS 70S Noises3367
333.9338 F,2 BSUB(256,30f-3.0) ?XD(7,5,3rQ.10\r13468.0,1.00\,T,T) XxpiNDBSUS
TRIANGLE LASS Texts CLEANUP BLANK TLH44376A
1001 AS. 55X7
4.33X7
40:
20:
23:00 24,00 25,00 26:00
file,0980037 tl-724 Acqt 7-JAN-199S 02,18,30 SC EH- Voltage SIS 70S Soiae,6S
327.8847 Tt2 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,260.0,1.00\rr,T) XxptNDBSUS
TRIANGLE LASS Text-.CLEANUP SLANX TLH44376A
1001 A9.31X4
80:
60:
40:
20:
o:
OEO
Time
1X7
9X6
6X6
4X6
2X6
0X0
Time
4X7
1X7
4X6
6X6
8X6
0X0
Ti«e
A1.43E4
A2.18X4
i ^m^*^oA<
!\ LM A j%i
2J>00 24,00 25:00
TiletU980037 tl-724 Acqt 7-JAK-1998 02 1 18 1 30 GC XH- Voltage SIS 70S
330.9792 Tt2 XzptKDBSUS
TRIANGLE LABS Text i CLEANUP BLAST TLH44376A
26:00
001
uo:
60:
40:
20:
o-
L"i£UiO£_^^-v2iill^U21^^
u - r -v-^v- * -»*•
3
.2
.2
-1
-6
0
23:00
24,00
25,00
26:00
4X7
8X7
1X7
4X7
9X6
0X0
Tiae
390
-------
TiltiO980037 tl-724 Acq, 7-JAM-1998 02,18,30 SC ZX+ Voltage SIS 70S Hoifet 144
339.8597 T,2 BSUB(25S,30,-3.0) PXD(7,5,3,0.10\,57S.Ot1.00\,T,X) XxptHDBSUS
TXIAHGLX LABS T«Xt : CLXAHOP BUUOC XLIt44376A
ion
80.
SO.
40.
20.
a
A3. 00X4
ti> §i i
MSIIvvw
A3. 07X4
i 4 1 A3. 89X4
^•f7" km14*4 i> , \lm-jti
u MIL AM ^ii hrtMftflfflBw
iM/Wwr rrvWlnrUtfniw
' 27,00 28,00
A4.60X4
L J ifll"
W JIJ
ff Wll IK
29 tOO '
1 1 AS.92X3 A2.90X41'\6E*
\(A$W7XB\ II iA]| il L||l
iwmJMjfrhknrmt L/Wyr I
-1 . BX4
'•.1.4X4
'•.1.1X4
'.7.0X3
-.3.5X3
0.0X0
JflioO Time
rile,U980037 tl-724 Acq, 7-JAX-1998 02,18,30 SC XT* Voltage SIS 70S Holme, 966
341.8567 Ti2 BSUB(2S6,30,-3 .0) PXD(7,5,3,0.10\,3864.0,1.00\,r,T) XxpiSDBSUS
TSIAHCLX LABS TmxtiCLZASUP BLANK XLIt44376A
ion
80.
SO.
Voltage SIX 70S
330.9792 T,2 XxptSDBSUS
TB.IAXGLX LABS TextlCLXAXUP BLASK XLIt44376A
ion
so:
SO:
40:
so:
0'
27,
•~~~~~^»sf~~~f'
03 wL^ws-^^^v-*^^^^
^y%w**>* *»'\^*/1*v^**^s«v^C^w^^^
27': 00 28\00
29,03
29\00
29135^^^^^°^^^^
.3.5X7
.2.8X7
.2.1X7
J..4X7
.7.1X6
0.0X0
30,00 Time
Tila,U980037 tl-724 Acq, 7-JXM-199B 02, IB, 30 SC XI* Voltage SIX 70S
409.7974 Tt2 XxptHDBSUS
TXIAOGLX LABS Text. t CLEANUP BUOX TLIt44376A
1001
80.
SO:
40:
20:
to - ^f
1 27,02 27,38 ^'f"^i 1
/I A AJI AJl «* * jJlju _J"-iA A fl /VAAsllA
18 41
\u
'27,00 ' ' ' 2a',oo
-1.8X4
\ [29,34 29,51 30,12 1
\a9^7 | AUAJWJL JLIW I1
29\00
'-.1.4X4
'-.1.1X4
'-.7.2X3
-.3.6X3
0 . OTO
391
-------
fil»:OSB0037 U-734 Acq: 7-J&H-199B 02:111: JO SC a 4- Malaga JH 70S Jtoi««;7JT
355.8546 Ti2 BSOS(256,30r-3.0) PXD(S,5,3, O.fl5%, 316. 0,1. 00\,r,T) Xrp:SDBSUS
TSIAHSZX LASS Text : CLXANUP BLANK TLH44376A
100$
80.
A2.
.0314
A3.68X3
AS. 46;
A1.96I4
38,24 28i36 28t48 25:00 25»i2 «».« 29t3S 29:48 30tOO 30:12 30:24
rila:O980037 tl-724 Acq: 7-JMT-1998 02tl8i30 SC XX* Voltage SIS 70S Soisai60
357.8516 Ts2 BSUB(256,30, -3.0) PXB(5,5,3,0.05\,240.0,1.00*,r,T) SzptSDBStJS
TXIAHSLX LASS TetrtiCLEANUP SLAOX TLH44376A
100\A2. 5X4
27t48 28'tOO 28:12 28:24 28:36 28:48 29'tOO 29:12 29:24 29:36 29:48 30:00 30:12 30:24
r±le:U980037 il-724 Acq: 7-JA1T-1998 02:18:30 SC EI+ Voltage SIX 70S Woiae:50
367.8949 T:2 3SUB(256,30, -3.0) PXD(5,5,3, 0. OS\,200.0,1.00\rf,I) Xxp-.ODBSUS
XBIAHSLS LASS Text:CLEANUP BLANK TLH44376A
100\ A2.J.3X7
80.
60.
40.
20.
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
r±le:ff980037 tl-724 Acqs 7-JAJT-1998 02:18:30 SC ZI+ Voltage SIX 70S SQiae:48
369.8919 f:2 SSUB(256,30, -3.0) PXD(5,5,3,0.05\,192.0,1.00\,r,T) ExptHDBSUS
TXIASSLX LASS Teit:CLEANUP BLANK TLH44376A
100\ A1.42X7
80.
60.
40:
20.
0.
.37X6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
T±la:O980037 tl-724 Aoq: 7-JJOT-1998 02:18:30 GC XI+ VoZtagn SIX 70S
330.9792 T>2 ExptNDBSUS
TXIANSLX LASS Texts CLEANUP BLANK TLIt44376A
1001
80.
60.
40.
20.
0.
28:29 28:42
30:18
1.5X4
'.1.2X4
'.9.0X3
'.6.0X3
'.3. 0X3
.0.0X0
Time
-6.2X6
.5.0X6
.3.7X6
.2.5X6
.1.2X6
0.0X0
Time
4.2X6
.3.3X6
.2.5X6
.1.7X6
.8.3X5
0.0X0
Time
-3.5X7
.2.8X7
.2.1X7
.1.4X7
.7.1X6
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
0.0X0
Time
392
-------
r±la*a980037 #1-385 Acq: 7-JAN-1998 02118130 GC XI+ Voltag* SIX 70S HoiM»i827
373.8208 T>3 BSUB<256,30, -3.0) PXD(7,5,3,0.10\,3308.0,1.00\,rfX): XxptBEBSUS
TXIANCLX LABS Text: CLEANUP BLANK TLH44376A
1004 A3.93X4
31',00 31:12 31*24 31*36 31*48 32*00 32*12 32*24 32*36 32:43 33*00 33*12 33*24 33*36 33*48
\r±l«iO980037 tl-385 Acq, 7-JAN-1998 02*18*30 GC XX* Voltage SIS 70S Sa&Mmt950
\375.8178 T*3 BSUB(2S6,30,-3.0) PKD(7,5,3,0.10\,3800.0,1.OQ\,T,T) SzpiSOSSUS
TSIAOSLX LABS Taxt:CLEANUP BLANK TLH44376A
100\
A2.37X4
A2.04X4
A1.31X4-
.65X4 -;;...; . .. ^M
31,00 31': 12 31',24 31,36 31:48 32:00 32', 12 32:34 32*36 32*48 33'tOO 33', 12 33:24 33:36 33:48
\r±lo*O980037 tl-385 Acq: 7-J3UT-1998 02:18:30 GC XH- Volt*g* SIT TVS Bairn*,996
,383.8639 T*3 BSU3(256,30, -3.0) PXD(7,S,3,0.10\f3984.0,1.00\,FrT)Sa^>sSSS5US
TSIASSLX LASS Tax*:CLEANUP BLANK TLH44376A
1003
sol
601
401
201
ol
A1.91X7
31*00 31': 12 31*24 31:36 31*48 32*00 32*12 32*24 32:36 JE2i48 33iOQ 33', 12 33:24 33:36 33:48
Fila,U980037 tl-385 Acqs 7 -JAN- 19 9 8 02*18:30 SC XH- Voltmfo SIX 703 NO±ae*1409
385.8610 T:3 3SOB(256,30,-3.0) PKD(7r5,3,0.10\,5636.0,1.00\,r,X):
TSIANGLX LABS Text : CLEANUP BLANK XLX144376A
100$
so
401
20:.
o
A3.79E7
A4.18X7?
A3.11X7
J1JOO 31:12 3l':24 31:36 31*48 32*00 32:12 32:24 32*36 32:48 33iOtO 33*12 33*24 33:36 33:48
'119*0980037 tl-385 Acqt 7-JX1T-1998 02:18:30 GC XH- Voltago SIS. TOS
392.9760 f*3 XxpiNSBSUS
TSIANSLX LABS Text:CLEANUP BLANK TLIt44376A
1004 31,07 31,31 31*44 31:58 32*18 32*34 JjJKig33j^gaj3:10^ ___Jt3_i*Lj£i*JL_.._.__
ao
eol
o
31:00 31,12 31:24 31*36 31:48 32:00 32:12 32:24 32:36 32*4* 33*00 33*12 33',24 33*36' 33*48'
rlJ.e:U980037 tl-385 Acqt 7-JAN-1998 02*18*30 GC XH- Voltage SXB! TOS
445.7555 T>3 Sxp,NDB5U3
'TSIANSLX LABS TtxttCLEANUP BLANK TXII44376A
1004
31:04
32*11
.-.- !"""'!.. .,".""." 33'43
32*23.
42<00
0.0X0
TLM
33,t05
1.1X7
\.a.9E6
-.6. 7X6
.4.5X6
.2.2X6
0.0X0
Tine
,.1.6X7
^.1.3X7
-.9.6X6
16.4X6
\.3.2X6
0.0X0
Time
;0o 31:12
3l:48 32s 32*12 322432136
33t ®8 " 33 1 12 ' 33:24' 33': 36 ' 33:48'
6.0X3
14.8X3
t
-.3.6X3
.2.4X3
.1.2X3
0.0X0
T±ae\
393
-------
r3J.a,O98ooj7 il-385 Acq: 7-JAu-iyyo vjnauo ec sx+ voltage SIS 70S
389.8156 r,3 3303(256,30,-3.0) PXD(7,S,3,0.10\,aa.O,1.00\,T,T) KxptHDBSUS
TSIAHGLX LASS TexttCLZAXUP BLAH* TLH4437SA
31:36 3l'i48 32', 00 32tl2 32', 24 32', 36 32', 4 8 33', 00 33', 12
rile,0980037 tl-385 Acqt 7-JJOT-1998 02,IS, 30 SC XH- Voltage SIS 70S Hoi fa, 24
391.8127 Ti3 BSU3(256,30,-3.0) PXD(7,5,3,0.10\r96.0,1.00\,r,T) XxfiHDBSUS
TSIABGLX LABS TextiCLXAJTOP BLAST TLH44376A
106
33124 33 36 Time
-1.1X4
31:36 31,48 32,00 32:12 32:24 32:36 32:48 33,00 33:12
rilai0980037 tl-385 Acq: 7-JAB-1998 02:18,30 SC XI+ Voltage SIR 70S Noise, 1401
401.8558 T:3 BSU3(256,30, -3. 0) PXD(7,5,3,0.10\,5604.0,1.00\,r,T) XxpiSDBSUS
TRIABGLS LABS Text,CLEANUP BUOTK TLH44376A
1001 A3.38X7
80.
eo:
40.
20.
A2.64E7
31:36 31:48 32:00 32tl2 32:24 32:36 32t48 33:00 33:12
TilatU980037 tl-385 Acq: 7-JZ1T-1998 02il8t30 SC XI+ Voltage SIS 70S Koine-.920
403.8529 Ts3 BSUB(256,30,-3.0) PXD(7,5,3,0.10%,3680.0,1.00\,T,T) XxpsSDBSUS
TXIAB5ZS LABS Text:CLEANUP BLANX XLH44376A
1003, A3.78X7
33:24
33:36
80.
60.
40.
20.
A2.19S7
31,36 31,43 32,00 32,12 32,24 32,36 32,48 33,00
File,US80037 tl-385 Acq: 7-J3OT-1998 02:18,30 SC XI + Voltage SIS 70S
392.9760 r,3 XxptSDBSUS
TSIAHGLX LABS Text:CLEANUP BLASK TLH44376A
1001
60.
40.
20.
0.
33 i 12
33ilO
33i24 33
33:29
.0.0X0
36 T±me
-1. 6X7
.1.3X7
.9.6X6
.6.4X6
.3.2X6
31,36 31:48 32iOO 32:12 32t24 32:36 32i48 ' '33>00 ' '33:12 ' '33i24
0.0X0
Time
394
-------
rila:a980037 #1-545 Acq: 7-JAJT-1998 02:18:30 SC XH- Voltage SIX 70S Hoitm:1180
407.7818 T:4 3SUB(256,30,-3.0) PXD(7,5,3,0.10\,4720.0,1.00\rT,iy XxptXDBSOS
tXIAOGLX LASS Text:CLXANUP BLANK TLH44376A
1004 A1.06X5
0X0
35:00 35:12 35:24 35:36 35:49 36:00 36:12 36:24 36:36
THa:O980037 #1-545 Acq: 7-JXH-1998 02:18:30 SC XH- Vbltagv SIX 70S Xoiaes939
409.7789 T:4 SSUB(256,30, -3.0) PKO(7,5,3,0.10\,3756.0,1.00\,T,T) ExptNDBSUS
TXIANGLX LASS Text: CLEANUP BLANK XLH44376A
A4.S4X4
36:48 37:00
33:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
rdJ.etO9B0037 tl-545 Acq: 7-JAN-1998 02:18:30 GC XH- Voltaga SIS 70S Noia«:1594
417.8253 T:4 BSU3(256,30,-3.0) PXD(7,5,3,0.10\,6376.0,1.00\,T,T) Ezp:HDB5aS
TRIANGLE LABS T*rt:CLEANUP BLANK TLH44376A
1001 A1.20E7
36:48
37:00
J5iOO 35-12 35:24 35:36 35:48 36:00 36:12 36:24 36:36
nie:0980037 tl-545 Acq: 7-JAB-1998 02:18:30 GC KC+ Voltngo SIX 70S Ho±Be:2911
419.3220 Ts4 BSUB(256,30,-3.0) PKD( 7,5, 3,0.10*, 11644 .0,1. 00\,r,T) Erp»JJDB5OS
TSIANGLE LASS Text: CLEANUP BLANK TLIf44376A
36:48
37:00
1001
80:
90I7
35:00 35:12 35:24 35:36 35:48 36:00 36:12 36:24
r±le:OS80037 #1-545 Acq: 7-J3UT-1998 02:18:30 GC XH- Voltage SIX 70S
430.9729 T:4 XzptSDSSVS
TXIASGLS LASS Tetxt:CLEANUP BLANK TLH44376A
36:36 36:48 37:00
1001
80:
60:
40:
20:
35:27
J5tOO 35:12 35:24 35:36 35:48 36:00 36:12 36:24
rile:U980037 #1-545 Acq: 7-JAN-1998 02:18:30 GC XH- Volttgt, SIX 70S
79.7165 T:4 SxpiNDBSUS
TBXANGLX LASS Taxt:CLEANUP BLANK TLH44376A
36:36
36:48
37:00
time
0X6
4X6
8X6
2X6
0X5
.0X0
Time
6X6
3X6
9X6
6X6
3X6
.0X0
Time
,1X7
,7X6
.5X6
.3X6
.2X6
.0X0
Time
35:00
35:12
35:24
35:36 35:48 36:00 36:12 36:24
36:36
36:48
37:00
395
-------
\rLLe,0980037 U-545 Aeq: 7-JUI-199B 02,13:JO &C SH- Voltage SIS 703 OoiaeilB
423.7766 T:4 BSOf(256,30,-3.0) tXD(7,5,3,0.10\,72.0,1.00\,T,T) SxpilOaSOS
TSIAlfSLX LASS Text« CtEUTOP BLAB* XLH44376A
1001 A1.63X4
80.
SO.
40.
20.
o:
Al.67X4
A3.54X4
A3.39X4
AS. 97X3
A/V
A1.03X4
-1.2X4
'.9.3X3
.6.9X3
.4.6X3
.2.3X3
0.0X0
35,12 35t18 35,24 35:30 35,36 35,42 35,48 35,54 36,00 36,06 36,12 36,18 36,24 36,30
f±lf 10980037 tl-545 Acqi 7-J7OT-1998 02,18,30 GC XH- Voltage SIX 703 Soiaa:18
425.7737 Tt4 BSO3(256,30,-3.0) PXO(7,5,3,0.10\,72.0,1.00\,r,X) IxptNDBSUS
TSIAIKZX LASS Tmrt:CZZAllUP BLAST XLH44376A
1001 A1.09Z4 ..8.1X3
T±me
0.0X0
Time
35,12 35:18 35,24 35:30 35,36 35,42 35:48 35:54 36,00 36:06 36,12 36:18 36:24 36:30
rile:U980037 tl-S4S Acq: 7-JAJT-1998 02:18:30 GC XI* Voltage SIS 70S Miiae:1656
435.8169 r:4 BSUB(256,30r-3.0) PXD(7,5,3,0.10\,6624.0,1.00\rr,X) Xxp:XDB5US
TSIANSU: LASS Text:CLEANUP BLMIX TLH44376A
1001 A1.?8E7 ^4.2X6
80.
60.
40.
20.
Tila,0980037 tl-S4S Aoq: 7-JAN-1998 02:18:30 GC EH- Voltage SIX 70S Noiao:1648
437.8140 T:4 3SUB(2S6,30, -3.0) PKD(7,5,3, 0.10%, 6592.0,1.OQ\,T,T) Xzp:SDB5US
TRIANGLE LABS Text:CLEANUP BLANK TLH44376A
1001 A1.92X7
80.
60.
40.
20.
'.3. 4X6
'.2.5X6
.1. 7X6
.8.4X5
-.4.1X6
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:00
TiletU980037 tl-545 Aesjs 7-J7OT-1998 02:18:30 GC EI+ Voltage SIS 70S
430.9729 7:4 Xxp:NDB5US
XXIAHSLX LABS Tax t: CLEANUP BLASK TLH44376A
100* 35^27
5:49.
^ \^, m Hi ii^ - f ^^ 'f • 'N —
80.
60.
40.
20.
0.
35:12 35:18 35:24 35:30 35:36 35:42 35:48 35:54 36:66 36',06 36', 12 36tia' 36i24 36:30
-1.1X7
.8.5X6
'.6.4X6
.4.2X6
.2.1X6
0.0X0
396
-------
riJ.a:O980037 tl-545 Acq: 7-JMT-1998 02:18:30 SC XI+ Voltaga SIR 703 Hoia»:22
441.7428 F;4 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,88.0,1.00\rT,T) XzptSDBSOS
TRUOOLX LASS TextiCZZAWUP BLANK TLIt44376A
35', 00 36100 37:00 38:00 39'tOO
rLLa, 09 80037 #1-545 Acqt 7-JUT-1998 03tl8i30 GC XI + Voltage SIX 70S SOim«:22
443.7399 f:4 BSO3(256,30,-3.0) ?XD(7,5,3,0.10\, 38.0,1.00\,r,T) XzptKDBSVS
TBIANGLX LASS Taxt-.CLZAXUP BLASX XLIt44376A
1004
401 00
A4.93X4
OBO
41 00 Time
35,00 36'tOO 37100 38,00
r±letO980037 il-545 Acq: 7-JJOT-1998 02il8:30 GC EI+ Voltage SIX 70S
430.9729 T>4 XzptSDSSUS
TSIAKSLX LABS TextsCLZAHOP BLAST TLH44376A
39:00
40:00
41 00 Time
1001
90.
ao.
701
601
50J
40.
JOJ
201
10!
0.
f^J+JfjtiZjtf^^
351 00
36,00
37,00
38100
39100
40:00
,.1.1X7
8X6
.8.716
[.7.6X6
.6.5X6
15.4X6
.4.3X6
.3.3X6
.2.2X6
11.1X6
.0.0X0
41 00 lima
T±IatO980037 tl-545 Actji 7-J3UT-1998 03:18,30 GC XX* Voltage SIS 70S
13.6775 Fi4 KxptlOfBSUS
TSIAHSLX LABS TextiCLXAOUP BZAUX TLH44376A
IOCS
35,18
35:42
36,25
38,35
37:46
37:11
38,19
JUIA
35 00
36:00
37,00
39:24
40:01
40:46
-1.4X4
.1.3X4
11.1X4
.9.8X3
.8.4X3
.7.0X3
.5.6X3
14.2X3
'-.2.8X3
.1.4X3
38:00
39:00
40:00
0.0X0
41 00 Time
397
-------
\rLLm,U9B0037 tl-StS Acq, 7-JAN-13SB 02:111,30 SC E1+ Voltage sIS 703 Jto.ua.Jg
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Peak Locate Examination: 7-JAN-1998:02:17 File:U980037
Experiment:NDB5US Function:2 Reference:PFK
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-------
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100%. A4.46E4
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100%.
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Sample Text:CLEANUP BLANK TLI844376A File Text:TRIANGLE LABORATORIES, INC.
100%, 39;36
60
40_
20_
0
K^I
40:36
38:48 39:00 39:12 39:24 39:36 39:48
40:00
40:12 40:24 40:36
1.4E4
1.2E4
8.7E3
5.8E3
2.9E3
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.8.7E5
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Time
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Cap/tola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 2
919-544-5729 Fax #919-544-5491
-------
TRIANGLE LABORATORIES OF RTF, INC.
Initial Calibration Summary for PF22206
Data: 02/20/96
Analysis Date : 02/20/96
Instrument : P
Method : C2NF
GC Column...: DB-225
Analytes
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
RF SD %RSD
1.040 0.109 10%
1.040 0.109 10%
0.992 0.101 10%
0.992 0.101 10%
RT RT/LO RT/HI Ratiol RaCio2 N
21:32 14:31 25:31 0.767
0.767
20:12 16:11 24:11 0.782
0.782
10
10
10
10
Other Standards
37C1-TCDD
RF SD %RSD ' RT RT/LO RT/HI Ratiol Ratio2 N
1.014 0.048 5% 20:12 18:11 22:11 10
Internal Standards RF SD %RSD RT RT/LO RT/HI Ratiol
13C12-2378-TCDF 1.388 0.062 4% 21:31 20:31 22:31 0.753
13C12-2378-TCDD 1.067 0.036 3% 20:11 18:11 22:11 0.786
Ratio2
N
10
10
Recovery Standards RF SD %RSD
13C12-1234-TCDD 1.000 0.000 0%
RT RT/LO RT/HI Ratiol Ratio2 N
20:27 0.794 10
»»• End of Report »•*
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
401
Printed: 23:10 02/20/96
-------
TRIANGLE LABORATORIES, INC.
Initial Calibration Sumnary Cor UF51053
Dace: 01/07/98
Analysis Dace. . .
Instrument
Analytas
Total MCDF
Total MCDD
Total DCDF
Total OCDD
Total TriCDF
Total TriCDD
1368-TCDP
2378-TCDP
TOTAL TCDP
1368-TO3D
1379-TCDD
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDP
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HXCDF
123789-HxCDF
TOTAL HxCDP
123478-HxCDD
123678-HXCDD
123789-BxCOD
TOTAL HxCDD
1234678-HpCDF
1234789 -HpCDP
TOTAL HpCDP
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12 -HxCDP 478
13C12-HXCDF 234
13C12-HXCDF 789
13C12-HXCDD 478
13C12-HpCDF 789
• 01/05/98
• 0
RP SD
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
1.298 0.073
1.240 0.132
1.240 0.132
0.715 0.032
0.360 0.021
1.240 0.160
1.240 0.160
1.051 0.090
1.019 0.078
1.035 0.084
1.333 0.125
1.333 0.125
1.007 0.074
1.253 0.089
0.985 0.082
0.870 0.047
1.
0.
0.
0.
0.
1.
1.
1.
0.
0.
1.
1.
029
765
976
941
894
410
096
253
995
995
377
108
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RF
1.
0.
0.
001
966
325
0.902
0.
0.
0.
695
732
802
0.
0.
0.
0.
0.
0.
0.
071
051
079
068
064
098
071
084
051
051
070
080
SD
056
010
042
043
042
024
016
%RSD
100%
100*
100%
100%
100%
100%
6%
11%
11%
4%
6%
13%
13%
9%
8%
8%
9%
9%
7%
7%
8%
5%
7%
. 7%
8%
7%
7%
7%
6%
7%
5%
5%
5%
7%
%RSD
6%
1%
5%
5%
6%
3%
2%
Itathod. •
RT
21:26
24:36
22:46
23:10
25:19
28:33
29:14
29:34
32:01
32:07
32:36
33:22
RT/LO
4:35
5:18
11:35
12:18
15:35
17:18
23:35
24:18
24:32
25:34
28:06
MTT2
RT/HI
13:35
19:18
19:35
20:18
22:35
23:18
30:35
31:18
32:32
33:34
36:06
Ratiol Ratio2.
0.745
0.743
0.744
0.776
0.786
0.787
0.781
1.526
1.530
1.528
1.580
1.580
1.283
1.245
1.262
1.263
1.262
32:43
32:47
33:06
35:00
36:31
36:01
39:47
39:35
RT
25:19
29:14
32:01
32:35
33:21
32:42
36:30
28:47
30:59
32:00
35:34
35:34
RT/LO
23:18
26:32
32:59
36:47
38:59
40:00
43:34
43:34
RT/HI
27:18
30:32
38:59
1
1
1
1
1
1
1
1
1
0
0
.257
.211
.234
.232
.060
..049
.055
.028
.028
.891
.836
Ratiol Ratio2
1
0
0
0
1
0
.498
.509
.508
.504
.214
.431
N
0
0
0
0
0
0
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
N
6
6
6
6
6
6
6
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:32 01/07/98
402
-------
TRIANGLE LABORATORIES, INC.
Initial Calibration smanary for OF5105S
Data: 01/07/9S
Internal Standards
13C12-2378-TOJF
13C12-2378-TCDD
13C12-PeCDP 123
13C12-PeCDD 123
13C12-BXCDF 678
13C12-BXOJD 678
13C12-HpCDP 678
X3C12-HpCDO 678
13C12-OCDO
Recovery Standards
13C12-1234-TCDD
13C12-HXCDD 789
RF
1.
1.
1.
0.
1.
0.
0.
0.
0.
467
113
142
590
346
995
822
726
545
0.
0.
0.
0.
0.
0.
0.
0.
0.
so
053
049
075
045
038
017
013
Oil
038
%RSO
4%
4%
7%
8%
3%
2*
2%
2%
7*
RT
24:35
25:18
28:32
29:34
32:06
32:47
34:59
36:00
39:34
RT/LO
23:35
23:18
24:32
25:34
28:06
31:47
32:59
35:00
37:34
RT/HI
25:35
27:18
32:32
33:34
36:06
33:47
38:59
37:00
41:34
Ratiol Ratio2 N
0
0
.755
.807
1.478
1
0
1
0
1
0
.506
.506
.216
.434
.018
.361
6
6
6
6
6
6
6
6
S
RF SD
1.000 0.000
1.000 0.000
%RSD
0%
0%
»** End o£ Report ***
RT
25:08
33:05
RT/LO RT/HI
Ratiol
0.312
1.210
Ratio2
N
6
6
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:32 01/07/98
4u3
-------
Date: 01/06/98 TRIANGLE LABORATORIES OF RTF, ISC.
Continuing Calibration for P980092
Analysis Date : 01/06/98 Method : C2NF
: BB
Operator
Init Calibration.: PF22206
ICal Date : 02/20/96
Analysis Time : 22:08
Instrument..: P
Std.Conc : 5.00
GC Column...: db-225
Analyte Summary
Name
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
RF Ratio
RT
ICal Delta
RT Rel. RT RF RF %D
162 Lo/High
0.390 0.68 18:18 23:06 1.0000 1.040 -0.150 -14.4%
25:26
0.890 0.68 1.040 -0.150 -14.4*
0.895 0.81 19:07 21:381.0000 0.992-0.097 -9.8%
24:40
0.395 0.81 0.992 -0.097 -9.8%
Other Standard Summary
Name RF Ratio
1&2
37C1-TCDD 0.912
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
19:38 21:38 1.0000 1.014 -0.102 -10.1%
23:38
Internal Standard Summary
Name RF Ratio
IS 2
13C12-2378-TCDF 1.080 0.77
13C12-2378-TCDD 1.081 0.76
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
22:06 23:06 1.0000 1.388 -0.308 -22.2%
24:06
19:38 21:38 1.0000 1.067 0.014 1.3%
23:38
Recovery Standard Summary
Name RF Ratio
1&2
13C12-1234-TCDD 1.000 0.78
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
21:56 1.0139 1.000 0.000 0.0%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 22:49 01/06/98
404
-------
Dace: 01/11/98
TRIANGLE LABORATORIES OF RTF. INC.
Continuing Calibration £or 098002S
Operator
TfS T. f f*J% 1 1 V^T"S> (* T <•
±£1J* U WAX^0^CLUJ.t
ICal Data
..: w i./ v ' / ?o
• MC
*n . TTR5 1 058
til, , \Jff JiVJO
• 01/05/98
Analyce Summary
Name RF
Tocal MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Tocal TriCDD
1368-TCDF
2378-TCDF
TOTAL TCDF
1363-TCDD
1379-TCDD
2378-TCDD
J^OTAL TCDD
K2378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
1234-78-HxCDF
123678-HxCDF
234678-HXCDF
123789-HxCDF
0.
0.
0.
0.
0.
0.
1.
1.
1.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
,000
000
000
000
000
000
171
197
197
631
337
151
151
006
025
015
419
419
048
244
1.056
0.
975
Ratio
142
0.75
0.75
0.75
0.77
0.77
0.80
0.78
1.51
1.52
1.52
1.59
1.59
1.25
1.25
1.26
1.25
Ins trunenc .
Std.Coac
RT RT Rel. RT
.: U
4> +.&
. . . • 10.00
ICal
RF
Delta
RF
%D
Lo/High
4:
18
5:
19
11
19
12
20
15
22
17
23
21
26
22
26
26
30
27
30
30
33
36
:36
20
:20
:36
:36
:20
:20
:36
:36
:20
:20
:20 21:28 0.3726
:33
24:38 1.0014
:40 22:48 0.9000
:31
23:11 0.9151
25:20 1.0000
:25 28:34 1.0006
:25
29:16 1.0251
:40 29:36 1.0000
:15
:55 32:03 0.9974
:38
32:08 1.0000
32:37 1.0150
33:23 1.0389 •
0.000
0.
0.
0.
0.
0.
1.
1.
1.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
.000
.000
,000
000
000
298
240
240
715
360
240
240
051
019
035
333
333
007
253
985
870
0.000
0.
0.
0.
0.
0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
,000
,000
000
000
000
127
043
043
084
023
089
089
-0.045
0.
-0.
0.
0.
0.
-0.
0.
006
020
086
086
041
009
071
0.105
100
100
100
100
100
100
-9
-3
-3
-11
-6
-7
-7
-4
0
-1
.0%
.0%
.0%
.0%
.0%
.0%
.8%
.5%
.5%
.3%
.5%
.2%
.2%
.3%
.6%
.9%
6.4%
6.4%
4.1%
-0.7%
7.2%
12.1%
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:0501/11/98
405
-------
Dace: 01/11/98
TRIANGLE
LABORATORIES OF RTP, INC.
Continuing Calibration
TOTAL HxCDF
123478-HxCDD
123678-HxCDD
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpOJD
TOTAL HpCDD
OCDF
OCDD
Other Standard
Name
1.081
0.771
0.943
0.941
0.385
1.401
1.155
1.278
0.994
0.994
1.307
1.077
Summary
RF
1,
1,
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
.25
.32
,17
,23
,23
,06
,04
.05
04
04
90
35
Ratio
1&2
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HXO3F 234
13C12 -HxCDF 789
13C12-HXCDD 478
13C12 -HpCDF 789
1.047
1.002
0.883
0.979
0.782
0.751
0.845
1.
0.
0.
0.
1.
0.
51
50
50
50
21
43
31:25
33:15
34:51
36:43
35:08
36:13
35:36
43:36
35:36
43:36
RT
Lo/High
23:20
27:20
24:33
- 32:33
33:00
39:00
32:44
32:49
33:08
35:01
36:32
36:03
39:49
39:37
RT
25:20
29:15
32:02
32:37
33:23
32:43
36:32
£or 0980025
0.9980
1.0005
1.0102
1.0005
1.0438
1.0005
1.0055
1.0004
Rel. RT
1.0000
1. 0245
0.9969
1.0150
1.0389
0.9975
1.0438
Internal Standard Summary
Name
RF
Ratio
1&2
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
1.444
1.113
1.223
0.
0.
1.
74
30
48
RT
Lo/High
23:36
25:36
23:20
27:20
24:33
32:33
Page 2
RT
24:36
25:20
28:33
Rel. RT
1.0000
1.0000
1.0000
1.029
0.765
0.976
0.941
0.894
1.410
1.096
1.253
0.995
0.995
1.377
1.108
ICal
RF
1.001
0.966
0.825
0.902
0.695
0.732
0.802
ICal
RF
1.467
-
1.118
1.142
0
0
-0
0
-0
-0
0
0
-0
-0
-0
-0
.052
.006
.033
.000
.009
.009
.059
.025
.001
.001
.070
.031
5
0
-3
0
-1
-0.
5.
2.
-0.
-0.
-5.
-2.
.1%
.7%
.4%
.0%
.0%
.6%
.4%
.0%
1%
,1%
1%
3%
Delta
RF
0.
0.
0.
0.
. 0.
0.
0.
.046
.036
,058
,077
,087
019
043
%D
4.
3.
7.
8.
12.
2.
5.
5%
7%
1%
6%
5%
6%
3%
Delta
RF
-0.
-0.
0.
023
005
081
%D
-1.
-0.
7.
5%
4%
1%
Triangle Laboratories, Inc.® Analytical Services Division
801 CapHola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:05 01/11/98
406
-------
Dace: 01/11/98
13C12-PeCDD 123
13C12-HXCDF 678
13C12-HXCDD 678
13C12-H&CDF 678
13C12-HpCDD 678
13C12-OCDD
Recovery Standard
Name
13C12-1234-TCDD
13C12-HXCDD 789
TRIANGLE LABORATORIES OF RTF, INC.
Continuing Calibration for U980025
0.592 1.46 25:36 29:36 1.0000 0.590 0.002 0.4%
33:36
1.212 0.50 28:08 32:08 1.0000 1.346 -0.134 -9.9%
36:08
0.972 1.21 31:48 32:48 1.0000 0.995 -0.023 -2.4%
33:48
0.871 0.43 33:00 35:00 1.0000 0.822 0.049 6.0%
39:00
0.776 1.02 35:02 36:02 1.0000 0.726 0.050 6.9%
37:02
0.637 0.36 39:26 39:36 1.0000 0.545 0.092 16.9%
39:46
Summary ICal Delta
RF Ratio RT RT Rel. RT RF RF
142 Lo/High
1.000 0.000
1.000 0.81
1.000 1.20
25:09 0.9928
33:07 1.0097
%0
0.0%
1.000 0.000 0.0%
QC Front End Check:
1.0515
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:0501/1
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ID:
P.O. Number:
TLI Project Number:
January 15, 1998
Eastern Research Group
44376
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 11/19/97
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
1 1
-------
Triangle Laboratories, Inc. January 15, 1998
Case Narrative 44376
Overview
The samples and associated QC samples were extracted and analyzed according to
procedures described in Method 23 (6/93). Any particular difficulties encountered during
the sample handling by Triangle Laboratories will be discussed in the QC Remarks section
below. This report contains results only from the Method 23 dioxin/furan analysis of nine
M23 samples.
Quality Control Samples
A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples.
Quality Control Remarks
This release of this particular set of Eastern Research Group analytical data by Triangle
Laboratories was authorized by the Quality Control Chemist who has reviewed each
sample data package following a series of inspections/reviews. When applicable, general
deviations from acceptable QC requirements are identified below and comments are made
on the effect of these deviations upon the validity and reliability of the results. Specific QC
issues associated with this particular project are:
Sample receipt: Nineteen M23 trains were received from Eastern Research Group in
good condition on December 17, 1997 at ambient temperature and stored in a refrigerator
at 4 °C.
Sample Preparation Laboratory: Samples 109-112, 113-116, 117-120/216/217/218,
121-124/219, 129-132, 133-136, and 137-140 were processed through additional cleanup
due to a yellow residue present after concentration. A cleanup blank, identified as the
CleanUp Blk, was prepared along with the samples.
Mass Spectrometry: None
Data Review: The analyses of samples 105-108, 109-112,113-116, 121-124/219,
117-120/216/217/218, and 125-128 exhibit the presence of saturated analyte signals
(signals outside the dynamic range of the instrument). The affected analytes are flagged
"S" on the quantitation report. The results for these analytes are reported as greater than
the upper calibration limit for that analyte, and should be considered a minimum estimate
of the actual concentration present in the sample.
-------
Triangle Laboratories, Inc. January 15, 1998
Case Narrative 44376
Other Comments: No 2,3,7,8-substituted target analytes were detected in the TLI Blank
above the target detection limit (TDL).
The analytical data presented in this report are consistent with the guidelines of EPA
Method 23 (6/93). Any exceptions have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Eastern Research
Group have any questions or comments regarding this data package, please feel free to
contact our Project Scientist, Amy J. Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Released by
Vl'/
Stuart Jefferys
Report Preparation Chemist
The total number of pages in the data package is
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accredidation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(lnc!uding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management Expires December 31, 1S98.
Laboratory I.D. #40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 19S8.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate 2AZ0423.
Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18, 1998.
Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX, Volatiles, Semi-
volatiies, and Metals.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut Department of Health Services. Expires September 30, 1999.
Registration # PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31,1998. Certificate #NC 140. Dioxin
in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractabie Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS# ES7411.
Revised 1/6/98 RM Triangle Laboratories, Inc. A
y:certific\certlist.mem aoi Capitoia Drive P.O. BOX 13435 4
Durham, NC 27773-4477 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
-------
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Idaho Department of Health and Welfare. Expires December 31, 1998. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment Expires January 31. 1998.
Environmental Analyses/Non portable Water and Solid and Hazardous Waste. Method 1613 for
drinking water. ID #s - Drinking water and/or pollution control - E-215. Solid or Hazardous Waste -
E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31, 1998. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires June 3, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1998.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
1998. ID #87851. BNAs and Volatiles. Dioxin in drinking water.
State of New Mexico, Environment Department Recertification pending. Dioxin in drinking
water.
New York State Department of Health. Expires April 1, 1998. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources Expires
August 31,1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management Expires December 31, 2000. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiies; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1998. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 1/6/93 RM
y:certific\certlist.mem
-------
Oklahoma Department of Environmental Quality. Expires August 31,1998. Laboratory #9612.
Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires
April 1, 1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid and
Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires
February 5, 1999. ID #02992. Method 1613 Drinking water only.
*
U.S. Department of Agriculture Soil Permit Expires Septembe'r 30, 2001. Permit No. S-3790.
Under the authority of the Federal Plant Pest Act, permission is granted to receive foreign soil
samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Recertificaticn Pending. Validated to perform methods
8280 & 82SO for Lockboume Landfill Site Investigation. Defense Distribution Depot Projects, and
assarted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 19S9. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 12, 1998. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1S98, Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiies under RCRA; Volatiles
under Clean Water Act Dioxin/furans by Method 8280; Drinking water for Dioxin by Method 1613;
Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for Polychlorinated Dibenzo-p-
dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1998. Certificate No.
9923(C). Dioxin in drinking water.
Revised 1/6/93 RM
y:certific\certlist.mem
-------
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID 999869530.
Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1998. Registration number
RT01195335. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1998. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #3 001500 1053481.
Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156379. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-375-OG. The general license applies only to radioactive material contained in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 1/6/98 RM
y:certific\certiist.mem
-------
DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491 Q
-------
Eastern Research Group COG
Gulp Aluminum Alloys
CHAIN OF
CUSTODY
/
/^ A
A
RELINQUISHED BY = ^V/^rtLT Cx6u3^<-^j2_ DATE =
RELINQUISHED BY = '
[SAMPLE m|
CAA-105
CAA-106
CAA-107
CAA-108
CAA-109
CAA-110
CAA-111
CAA-112
CAA-113
CAA-1M
CAA-115
CAA-116
_^
CAA-117
CAA-11B
CAA-119
CAA-120
CAA-121
CAA-122
CAA-123
CAA-12-1
^f
CAA-125
CAA-126
CAA-127
CAA-128
CAA-129
CAA-130
CAA-131
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
I
CAA-
CAA-
CAA-,
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120597 M23-
120597 M23-
120597 M23-
120597 M23-
120697 M23-
120697 M23-
120697 M23-
120697 M23-
120797 M23-
120797 M23-
120797 M23:
120797 M23-
120597 M23-
120597 M23-
120597 M23-
120597 M23-
120697 M23-
120697 M23-
120697 M23-
120697 M23-
120797 M23-
120797 M23-
120797 M23-
120797 M23-
120897 M23-
120897 M23-
120897 M23-
FIELD ID
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBOUT-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
CDBIN-
rtFI-OUT-
RF1-OUT-
RF1-OUT-
DATE =
FILTER 1
PR 1
PRT/CRT 1
XAD 1
FILTER 2
PR 2
PRT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CUT 3
XAD 3
FILTER 1
Pp 1
PRT/CRT 1
XAD 1
FILTER 2
PR 2
PRT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 1
PR 1
PRT/CRT 1
/^ ^h^
•
SAMPLE TYPE
METHOD 23. CDBOUT, RUN 1
METHOD 23. CDBOUT. RUN 1
METHOD 23, CDBOUT. RUN 1
METHOD 23. CDBOUT. RUN 1
METHOD 23. CDBOUT. RUN 2
METHOD 23. CDBOUT. RUN 2
METHOD 23, CDBOUT. RUN 2
METHOD 23. CDBOUT. RUN 2
METHOD 23. CDBOUT, RUN 3
METHOD 23. CDBOUT, RUN 3
METHOD 23. COBOUT. RUN 3
METHOD 23. CDBOUT. RUN 3
METHOD 23, CDBIN, RUN 1
M23, CDBIN. RUN 1 (Bollle 1 ol 2)
METHOD 23. CDBIN. RUN 1
METHOD 23, CDBIN, RUN 1
METHOD 23, CDBIN. RUN 2
METHOD 23. CDBIN, RUN 2
METHOD 23. CDBIN. RUN 2
METHOD 23, CDUIN, RUN 2
METHOD 23, CDBIN, RUN 3
MET HOD 23. CDBIN, RUNS
METHOD 23. CDBIN, RUN 3
METHOD 23. CDBIN. RUN 3
METHOD 23. RF1-OUT. RUN 1
METHOD 23. RF1-OUT. RUN 1
METHOD 23. RF1-OUT. RUN 1
RECEIVED BY: ^"c^V,
RECEIVED BY: S^
\ PRESERVATIVE
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
X-XADTRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
X XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
X'XAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XXAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XXAU TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
.e^AD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
-Z^om. /z/,y/i
S^ DATE: '
COMMENTS | ANALYSIS |
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN 1 FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN /FURAH
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
-------
Eastern Research Group . COG
O
CAA-132
CM-t33
CAA-134
CAA-135
CAA-136
CAA-137
CAA-138
CAA-139
CAA-140
CAA-141
CAA-142
CAA-143
CAA-144
~CAA-153
CAA-154
CAA-155
CAA-156
rcAA-157
CAA-158
CAA-159
CAA-160
CAA-161
CAA-1G2
CAA-163
CAA-1G4
CAA-165
CAA-166
CAA-167
CAA-168
CAA-177
CAA-178
CAA-179
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
, CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
CAA-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
120997 M23-
120997 M23-
120897 M23-
120997 M23-
120997 M23-
120997 M23-
120997 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
121197 M23-
120997 M23-
121197 M23-
121197 M23-
120797 M23-
121597 M23-
121597 M23-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF1-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF2-OUT-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RF1-IN-
RFt-IN-
RF1-IN-
RF2-IN-
RF1-IN-
RF2-IN-
RF2-IN-
RBLK1
RBLK2
RBLK2
XAO 1
FILTER 2
PR 2
PRT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 4
PR 4
PRT/CRT 4
XAD 4
FILTER 1
PR 1
PRT/CRT 1
XAD 1
FILTER 2
PR 2
PrtT/CRT 2
XAD 2
FILTER 3
PR 3
PRT/CRT 3
XAD 3
FILTER 4
PR 2
PRT/CRT 4
XAD 4
FILTER 1
PR 2
PRT/CRT 2
METHOD 23. RF1-OUT. RUN 1
METHOD 23, RF1-OUT, RUN 2
METHOD 23, RF1-OUT, RUN 2
METHOD 23. RF1-OUT. RUN 2
MET HOD 23, RF1-OUT. RUN 2
METHOD 23. RF1-C:, .'. RUN 3
METHOD 23, RF1-OUT. RUN 3
METHOD 23. RF1-OUT, RUN 3
METHOD 23. RF1-OUT. RUN 3
METHOD 23. RF2-OUT. RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23, RF2-OUT, RUN 4
METHOD 23, RF2-OUT. RUN 4
METHOD 23. RF1-IN, RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23. RF1-IN. RUN 1
METHOD 23, RF1-IN. RUN 1
METHOD 23, RF1-IN, RUN 2
M 23, DPI IN. RUN 7 (Bollle t of 2)
METHOD 23, RF1-IN, RUN 2 ^
METHOD 23, RF1-IN, RUN 2 \
METHOD 23, RF1-IN. RUN 3
METHOD 23. RF1-IN, RUN 3
METHOD 23, RFMN. RUN 3
METHOD 23, RF1-IN, RUN 3
METHOD 23. RF2-IN. RUN 4 /
f^MT3. nr 1 IN. RUN ?|E)ottle 1 of t)J
METHOD 23. RF2-IN. RUN 4
METHOD 23. RF2-IN. RUN 4
METHOD 23. REAGENT BLANK
METHOD 23. REAGENT BLANK
METHOD 23, REAGENT BLANK
XXAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
ffVJ^O TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
fXAO TRAP
FILTER
ACETONE/MECL RINSE(1of2)
TOLUENE RINSE
yXAD TRAP
FILTER
ACETONE/MECL RINSE
TOLUENE RINSE
XXAD TRAP
FILTER
ACETONE/MECL RINSE(2 of 2)
TOLUENE RINSE
XAD TRAP
FILTER
ACETONE
TOLUENE
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN I FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN /FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN/FURAN
DIOXIN / FURAN
DIOXIN / FURAN
DIOXIN / FURAN
Page 2
-------
Eastern Research Group COC
CAA-180
CAA-181
CAA-1B2
CAA-183
CAA-16-1
""^•••M
-------
Eastern Research Group COG
CAA-218 CAA- 120597 M23- CDBIN PR 1 M23 CUDIN RUN 1 (PR 2 OF 2) ACETONE/MECL RINSE DIOXIN / FURAN
CAA-219 CAA- 120697 M23- COBIN FIL1F.R 2 M23 CDIJIN RUN 2 (FILTER 2 OF 2) FILTER DIOXIN / FURAN
CAA-225 CAA- 121197 M23- RF1 IN PR 4 Motliod23 RF1 INLET RUN 4 ACETONE/MECL RINSE DIOXIN / FURAN
CAA-226 CAA- 121597 M23- REAGENT BL MeCL 2 M23 REAGENT BLANK 2 (MeCL) REAGENT BLANK (MeCL) DIOXIN / FURAN
Page 4
-------
=TRIANGI.E LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY^
U Custody Seal : Absent Sample Seals: Absent
D Chain of Custody : Present Container. . . : Intact
U Sample Tags : Absent
U Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
n
g Ice Chest NO COOLANT
IJTLI Number Client Sample ID . Matrix) To \,r\
gmR/ll-CPM Client COC ID * Location | DatP/
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=TR I ANGLE .LABORATORIES, INC. -- LO?flN RECORD/CHAIN OF CUSTODY=
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LABORATORIES, INC. -- LOO IN RECORD/CHAIN OF CUSTODY^
|| Custody Seal : Absent Sample Seals: Absent
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jj Receiving Remarks; NO COOLANT. CAA-206 AND CAA207 ARE NOT PRESENT.
|1 Archive Remarks:
=Form Revised 05/27/1997 -- Page 3 OF 6=
-------
=TRIANGLE LABORATORIES, INC. --'
RECORD/CHAIN OF CUSTODY=
(I Custody Seal > Absent Sample Seals: Absent
P Chain of Custody : Present Container...: Intact
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TLI Project Number 44376 Book D
Client: ELS01 - Eastern Laboratory Services, Inc. CJP
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Archive Remarks:
=Form Revised 05/27/1997 -- Page 4 OF 6=
-------
^TRIANGLE LABORATORIES, INC. -- IOG IN RECORD/CHAIN OF CUSTODY=
Custody Seal
Chain of Custody
Absent
Present
Sample Taga : Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A
Sample Seals: Absent
Container...: Intact
TI.I Project Number 44376
Client: ELS01 - Eastern Laboratory Services, Inc.
Date Received
| 12/17/97 | By
-( L-
| Book 0
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NO COOLANT
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=TRIANGLE LABORATORIES, INC. --
'IN RECORD/CHAIN OF CUSTODY^
| Custody Sea. : Ab«tnt Sample Seals: Absent
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0 1
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Receiving Remarks: NO COOLANT. CAA-206 AND I.-AA207 ARE NOT PRESENT.
I
Archive Remarks:
=Form Revised 05/27/1997 -- Page 6 OF 6=
-------
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
TLI Proj#:
Prod Code :
DetectLim:
44376-
D23061
. 0 5 ng
^Uri-HN AJ -LJ
Samples :
Matrix. :
Type . . . :
Recvd. . :
rwi-i A vc. XIN.
9
M23Train
A
12/17/97
TurnAround.: 21 Day(s)
Hold Time..: 30 Day(s)
Start Date.: 12/17/97
Ship By....: 01/05/98
DWL Due Dt.: 12/24/97
Analyte List.: Method 23:T-0 (Toluene combined
Method : Method 23:Tetra-Octa (Tol Combined)
Client Proj..: Culp Aluminum Alloys
Client : Eastern Research Group (ERG02)
P.O. No : Signed OA Collect Dt/Tm: SeeCOC
Contact : Jim McGaughey Phone : 919/461-1209
Proj . Mgr. . . . : Amy J. Boehm Fax : 919/461-1579
Sample Origin: NC
-SPECIAL INSTRUCTIONS / QA REQUIREMENTS
Prespike Standard: USD-C, USD-S
Prespike Amount..: 4.Ong
REPORTING REQUIREMENTS•
Reporting Format: Report Option II
See MILES for Instructions/Communications.
Completed by:
Reviewed by:
DATE:
DATE:
(PMGT0197)
v
V
-------
PROJECTCOMMUNICATJON TRACKING FORM
page of.
Project Number:
Use this form' to record ai! exchanges of information between production units as well as personnel
.handling this project. Decisions, corrective actions and recommendations must also appear on this
tracking .document.
Comment / Decision / Resolution / Action / Observation
Pflt&ctf
Triangle Laboratories, Inc
TLI PP'.DJECT* 04047
£._ 11/25/97 TLI BLANK
CSPIKE 4.0ng USF-C USF-S
PREPARER G.L.
EASTERN RES.GRP.
-------
ELS01-Eastern Laboratory Services, Inc.
CAA-106
Pr-oJ eot : 4-4-37©
194-—59— 1 B
'oo*;
ELS01-Eastern Laboratory Services, Inc.
CAA-110
o-t. : 4-4-37©
4-— 5 9— 2 B
exxs
ELS01-Eastern Laboratory Services, Inc.
CAA-114
R r- G- Jjs o -t : 4- ^- 3 7 6
—59—^B
ELS01-Eastern Laboratory Services, Inc.
CAA-118
Rr-ojeo-t- : -4-4-3
1 9-4-— 5 9 — -4-B
S01-.
604
. .. _„,„...., .j>,wi f OWf'V
CAA-218
r-o j ©Gt : 4-
1 94-— 5 9 — £ ..••..
toT
P \S01-Eastern Laboratory Services, Inc.
CAA-1 22
, R r~ o j o o t : -4- 4- 3 7 e
1 9-4-— 59— 5 B
ELS01-Eastern Laboratory Services,
CAA-126
1 94-— 59 — ©B
ELSOl-Eastern Laboratory Services, Inc.
CAA-1 30
Rr-ojesct : 4-4-37©
194-— 59— 7B
ELSOl-Eastern Laboratory Services, Inc.
CAA-1 34
Rr-ojoct. : 4-4-37©
19 4- — 5 9 — e B a
ELSOl-Eastern Laboratory Services, Inc.
CAA-1 38
F3r-G.JeGt. : 4-4-37©
1 94-— 59 — 9 B
-------
Date: 12/29/97
Time: 13:46
Sample
M crd TLI_Number.. Customer.Sample.Id
000 TLI Blank TLI XAD BLANK
001 194-S9-1A-1D 105-108
002 194-59-2A-D 109-112
003 194-59-3A-3D 113-116
004 194-59-4A-D/ 117-120/216/217/218
005 194-59-5A-D/ 121-124/219
006 194-59-6A-6D 125-128
007 194-59-7A-7D 129-132
008 194-S9-8A-BD 133-136
009 194-59-9A-9D 137-140
020 TLI LCS TLI LCS
021 TLI LCSD TLI LCSD
••• End of Report *•*
TRIANGLE LABORATORIES, INC.
Wet Lab MMS/PUF Observations
Project: 44376
F.
No
0
1
1
1
8 3
2
1
1
1
1
0
0
XAD
Color
WHITE
WHITE
WHITE
WHITE
WHITE
WHITB
WHITE
YELOWWHITE
YELOWWHITE
WHITE
LOT P-1078
LOT P-1078
Filter
Color
NA
BROWN
LT BROWN
LT BROWN
BROWN
BROWN
BROWN
BLACK
BROWN GRAY
LT GRAY
NA
NA
Glass Wool
Color
NA
WHITE
WHITE
WHITE
WHITEBROWN
WHITE
WHITE
YELLOW
YELLOW
WHITE
NA
NA
PUF
Color. .
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Odor .
NA
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NA
NA
Air
Q No
04047
04047
04047
04047
04047
04047
04047
04047
04047
04047
NA
NA
Entered . By
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
Date
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
12/29
PRDPERC V4.01
Page : 1
. . . Time S
13:45 f
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
13:45
F
F
P
F
F
F
F
F
F
F
F
ro
ro
-------
44376
TRIANGLE LABORATORIES, INC. ' PAGE 1 OF 2
Dioxin Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERG02)
i
I Solvent (s)/Acid (s)'x£
| Lot Numbers:
1
Method: Method 23:Tetra-Octa (Tol Combined) Matrix:
Extraction Date: it-/ T
| IS Spike: 40 M! cone: 0.1000 ng/Ml
1 SS Spike: Ml cone: . ng/Ml 1 ^^^
\ MS Spike: 0 pi ronr- 0 . 0000 ng/Ml 1 „ ^^J^.^r-,,
\ LTS Spike: 0 ,,1 rnnr- 0.0000 ng/Ml 1 I?S^ "?-..
1 OPR Spike: 20 M! cone: 0.01 ng/Ml ... . \ 1 .L? / ^L /5l
™^~ "" ^^ \ Or^ \\L.\ "
\ «" * ' "VJ | *y / ^ 0» / d~1
| | TLI / | GROSS | SAMPLE | /2. : */1
|000 | TLI XAD BLANK | (VJ ft | AiH 1*1
| | 194-S9-1A-1D 1 1 1 . 1 -jT^'
|001 | 105-108 | )JL | |\jfi 1 1
| | 194-S9-2A-D III fflj*
|002 | 109-112 | N'J\- Lj$ 1 \ 1
| | 194-59-3A-3D I 1 ,» 1 1 1 ' l~**
|003 | 113-116 1 ^fi | ^H - I 1
P| 194-59-4A-D/-U). ^ 'p 1 'a/*4>/^
|006 | 125-128 | CfV 1 A*^ 1 1 1
1 | 194-59-7A-7D | , « I k . I | I <],W
|oo7 | 129-132 i N n i Nkn | | 1
| | 194-59-8A-9D | ' lA ' i ' "1" L^
|008 | 133-136 | fj^ 1 Nn |\| |
| | 194-59-9A-9D ' i 1 A- ' Wfr ' 1 ' ^^ '
|009 | 137-140 | A/ H | 'VX | 1 | |
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•C : | " Time
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| y'es/r!^ |
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| yes/no |
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| yes/no |
|ASy Left
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|Any Left
| yesTao
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| Gross weight of sample container « sample before/after aliquot removal.
I
Comments:
initials:
| Initials of both SPIKER AND OBSERVER must be entered.
XXXXX - Gross Weight not provided for WATER Samples.
REV OS/27/97 (PSTMF 7)-
23
-------
TRIANGLE LABORATORIES, INC.
Dioxin Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERGO2)
Project: 44376
Solvent (3) /Acid(s) i
Lot Numbers:
Method: Method 23 :Tetra-Octa (Tol Combined) Matrix
Extraction Date: C- I ^/
I
| Any Left |
| yes /no |
| Any Left]
| yes/nc |
| Any Left]
| yes/no |
I Any Left |
| yes/no |
I Any Left |
| yes/no |
I Gross weight of sample container * sample before/after aliquot removal
|
| Comments: rT LvffQjIJf f\ \)\.ULf\ r*~ i
n nlCLrt
I
Initials
: ^Z/^ate: U^_,^
| Initials of both SPIKER AND OBSERVER must be entered.
XXXXX » Gross Weight not provided for WATER Samples. |
REV 05/27/97 (PSTMF 7)--.
24
-------
PAGE 2 OF 2
TRIANGLE LABORATORIES, INC.
Ext Sft.crd and
TLI Number
020
TLI LCS
021
TLI LCSD
IIIIIJ
TLI Project NO. : 44376
! i ! -^ 14*1 u 1 *> ! <&!T ! ? i? i-io i
I^T^i 5^- ! 5i • ! -JL- "-%- \ TL |$m i §£ i j
i^Y^^^M^W,^. i ! !
i i i I l l l l ^/ l . i i l l(^
I i i l l l l 1^1 1.1
I I 1 I.I 1 ! 1 1 1 1
i i i l i l l l i l l
i i i l l l l l l 1 l
i l l l l l l l l l l
l i i l l l l l l l l
l ii l l l l l l l l
l i i l l l l l i l l
| | 1 1 II 1 1 1 1 1
II 1 1 i 1 1 1 • 1 1 1
Enter the proced
Initial and date
$ PROCEDUR
(^J EXTRACTION
(5? SPIKE AFTER
(^ ADD TRIDECAN
^? ROTOVAP
Jai COMBINE
^) DIV./LIP. DE
O) SOLVENT EXCH
01 CLEANUP
f) TRANSFER
10) ADDITIONAL C
FINAL TRANSF
| | ! II 1 I'll 1 1
1 -| 1 1 1 1 1 1 1 1 !
i i i l l l l l l l l
i i i l ill l l l l
ure number below into the box at the top of each column to signify the step performed.
each sample for each numbered procedure performed.
E.... SOP.#. .v.. DETAILS (circler^ \l^c<=("3'
^| 1 ^ Time On .O : °_£ Time Off 0_S : 0_O
SOJch^st / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
EXT'N ^"X\_— l
E . Loti* /A,/* /~xi"*Vv' j--^-.
35Bef£L4(«, / &A.I (^ess^
TERM. JM ^ 20%/BO* /•sUvsljJ) 5mL^20mL Other
4jj x — ^—-^ffflniLLl
ANGE jktf?^ Iso-Octane Lotft1? / l/Wi Heptane Lot#
^p/V^'if.j f <^SP 26Q?/ DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
—aQ^i-.^T^T^'l^i /- ^ -v
LEANUP Mod. DS^ZSO; / DSP 225 / DSP 115 / DSP 215 / DSP 267 / ( DSP260 (lOg) )
ER 4^-7 7 ' / ^ ^
i/*jl '• • '•• ... /^s- —
comments ~:W~tiffy Z37 ¥£ Q/7(jfi5(j tJAtd ~fr> A//-VL^ ~J)/\^fr
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 44376
Transfer From: DWLH5 To: DMS5
Initials. . Date Time. .
Released by: ^)C ' _L/_£1/3L /£ : o
Accepted by: frf ^ -LjSL/3g [£ '
MILES.ID,
44376-
44376-
44376-
44376-
44376-
44376-
44376-
44376-
44376-
44376-
44376-
44376-
44376-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-020
-021
-022
TLI No Cust.Id.
TLI Blank TLI XAD BLANK
194-59-1A-1D 105-108
194-59-2A-D 109-112
194-59-3A-3D 113-116
194-59-4A-D/ 117-120/216/217/218
194-59-5A-D/ 121-124/219
194-59-6A-6D 125-128
194-59-7A-7D 129-132
194-59-8A-8D 133-136
194-59-9A-9D 137-140
TLI LCS TLI LCS
TLI LCSD TLI LCSD
TLI Clean-Up Cleanup Blk
Additional comments or instructions:
-XfrCOC (Rev 11/01/94)--+
26
-------
PAGE 1 OF 1
thod: Method 23:Tetra-Octa (Tol Combined)
quired Detection Limit: .05 ng
TRIANGLE LABORATORIES, INC.
HR GC/HRMS ANALYSIS
I PROJECT: 4437S |
| SAMPLE INFORMATION RS Cone |
| 1ST COLUMN 2ND COLUMN 20 (il « 100.0 PG/|il |
1 | TLI /
|S#.crd| SAMPLE ID / CLIENT
| | / SAMPLE ID
| | TLI Blank
| | 194-59-1A-1D
|001 | 105-108
| | 194-59-2A-D
|002 | 109-112
| I 194-59-3A-3D
|003 | 113-116
| | 194-59-4A-D/^(4//S '^P
i I
i
| GC/MS FILENAME | CONFIRM [CONFIRM FILENAME |USF-RS |USF-RS (ANALYSIS |
| COLUMN V^*?') 1 1 COLUMN : ^ Vl^* 1 VOLUME UNIT. I COMMENTS 1
| | | ISOLN ID |D ATE | |
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Ante of Extract: 50% I
» REV 03/07/95 (PSTMF 6) --»
27
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID
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Column Type
Column ID
Plot Name
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Ini. Vol.
Acquisition
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Q/C
'Date
Filename
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Time*
Project #
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No.
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Syr
332
Operator/Date
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Comments
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-------
Triangl^fcboratories, Inc.
^Rn Log
Instrument ID Column Tvoe Column ID Plot Name
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Signature
G/C
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Date
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332
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Pano:
63
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column TVDO Column ID •* Plot Name
ioT £>fr> lui|i^?> -fez.
in). Vol. Acquisition
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Inbutiment ID Column Type Column ID Plot Name Inj.
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-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Type Column ID
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-------
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Instrument ID Column Type Column ID Plot Name Inj. Vol. Acquisition
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2.1:
Pagi
/«/
-------
PAGE 1 OF 2
L
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 44376
Ext S#.crd and |
TLI Number |
000 \d£
TLI Blank | /
001 |iV?
194-59-1A-1D |
002 |
194-59-2A-D |
003 |
194-59-3A-3D |
004 |
194-59-4A-DA2a-/4/#|
^Vc / T/^-fa/4? *^"
005 |
194-59-5A-D/i23 |
005 | 1
194-59-SA-SD | I
007 |
194-59-7A-7D |
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Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
V
lJP1
# PROCEDURE.... SOP.#. .v.. DETAILS (circle),
EXTRACTION \\\ $. Time On Vll : °— Time Of f 0£ : 0£
^thjCfet / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
SPIKE AFTER EXT'N .
ADD TRIDECANE , LotttTEl'3''
ROTOVAP
COMBINE
DIV./LIP. DETERM. f ( I H 20%/80% (So%/S^r SmL/20mL Other_
SOLVENT EXCHMJC& To?) _ Igaiflc^ane Lott» f^7//6>4 Heptane Lot#_
/DSP 260}
CLEANUP
IQ/T ADDITIONAL CLEANUP
') FINAL TRANSFER
225 / DSP 115 / DSP 215 / DSP 267 / Other
/ DSP 225 / DSP 115 / DSP 215 / DSP 267 /
Mr.iX +
6 "
•Rev 11/25/97 (PSTMF 4)-
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491 n ~
OD
-------
TRIANGLE LABORATORIES OF RTP,
Sample Result Summary for Project
Method 82 9 OX Full Screen Analyses
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HoCDD
-OCDD
'.. 2378-TCDF
12378-PeCDF
23478-PeCDF
- 123478-HxCDF
- 123678-HxCDF
T 234678-HxCDF
.-•123789 -HxCDF
1234678-HpCDF
' 1234789-HpCDF
— OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HxCDD 478
13C12-HpCDF 789
Other Standards
13C12-HXCDF 789
13C12-HxCDF 234
T980152
TLI XAD BLANK
ng
12/29/97
01/06/98
T
XAD
Soxhlet
(0
(0
(0
(0
<*CSE
PR
E
E
Q
SQE
SE
E
X
Q
Q
5
4*6
31
49
9^7
-£4-7
42-0
~* A /^
K"iJ
.0
7S.O
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.6
? *•
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7&O
•3437 }>
3-8-6
••t£6
*W
90
115
83
116
126
95
82
52
79
72
106
7<9<7
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.4
.8
.6
.7
.6
.7
PR
SE
<3<
SE
SQE
SQE
SE
SQE
SQE
SQE
SEC?
Q
-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 44376
Method 8290X Full Screen Analyses (DB-5)
Page 2
01/15/98
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
T980152
TLI XAD BLANK
ng
12/29/97
01/06/98
T
XAD
Soxhlet
=================:
T980154
109-112
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
T980155
113-116
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
T980156
117-120/216/217
/218
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 678 64.8 69.7 75.5
13C12-HXCDD 678 81.9 63.3 Q 62.8
13C12-HpCDF 678 64.5 77.0 81.2
13C12-HpCDD 678 100 103 109
13C12-OCDD 114 112 114
86.7
89.7
85.4
_L19 -.
134"
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:50 01/15/98
38
-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 44376
Method 8290X Full Screen Analyses (DB-5)
*)ata File
• .ample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378 -TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-KpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
k OTAL HxCDD
F.OTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HxCDD 473
13C12-HpCDF 789
Other Standards
13C12-HxCDF 789
13C12-HxCDF 234
T980157
121-124/219 /
#.^y
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
2.
14.
17.
31.
55.
98.
79.
t i •**$ ~\
\ ± .J A* j
5
3
0
2
3
8
8
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fS^-rS };j3CQSE
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•*&£•
9
4
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4£2-
196
>tt
30£-7Mr
sa-
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2*9
Percent
96.
103
84.
129
127
Percent
85.
71.
•&•&
•7*0
75^C
<*
SE
SQE
SQE
E
SQE
OSQE
SQE
' SE<£
Recovery
3
2
Q
3?
Q
$
Recovery
3
4
Internal Standards Percent
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
45.
62.
67.
86.
0
2
0
7
T980158
125-128 /
i'o . .,
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
0
6
6
12
18
40
34
.86
.3
.0
.0
.8
.3
.5
PR
E
•94-7-774- SE
19
35
64
27
34
1
77
9
17
280
260
210
83
-655-
•4i8
270
116
Summary
92
86
103
107
99
Summary
49
45
.1
.3
.6
.0
.4
.5
.6
.1
.4
.1
••Hlf
7<»0
(%
.1
.8
.5
(%
.9
.8
Recovery Summary
Q
Q
41
47
52
56
.3
.3
.0
.6
E
PR
E
E
E
E .
E
SQE
SE
E
E
Rec)
Rec)
(% Rec)
Q
T980159
129-132 /
**•-••• ' v
ng
12/29/97
01/06/98
T
M23TRAIN
Soxhlet
0
0
0
0
0
1
1
4
0
1
3
1
1
0
4
0
4
4
2
4
2
26
21
13
8
82
94
99
104
107
82
76
66
67
76
90
.04
.18
.17
.27
.41 PR
.2
.8
.1
.91
.6
.5
.3
.7
.09 • PRJ
.8
.87
.0
.5
.9
.2
.3
.1 Q
.4
.9 6?
.6
.1
.9
-5
.1
.7
.7
.8
.6
Page 3
01/15/98
T980163
133-136 /
ng
12/29/97
01/07/98
T
M2 3 TRAIN
Soxhlet
0
0
0
0
0
0
0
2
0
0
0
0
0
0
0
0
1
4
0
0
0
24
7
2
1
86
94
97
95
114
82
76
72
73
81
90
.02
.05 J
.02 J
.04 J
.06 PRJ
.16
.27 B
.9
.29
.40
.54
.21
.23
.01 PRJ
.68
.11
.2
.4
.83
.72
.32
.0 Q
.3
.3
.1
.1
.5
.5
.8
.1
.0
.2
.4
.6
.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:50 01/15/98
3S
-------
Data File
Sample ID
TRIANGLE LABORATORIES'OF RTP, INC.
Sample Result Summary for Project 44376
Method 8290X Full Screen Analyses (DB-5)
T980157 T980158 T980159
121-124/219 125-128 129-132
Page 4
01/15/98
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
T980163
133-136
ng
12/29/97
01/07/98
T
M23TRAIN
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 678 71.9
13C12-HxCDD 678 69.3
13C12-HpCDF 678 74.2
13C12-HpCDD 678 112
13C12-OCDD 119
47
53
55
69,
72.3
75.8
90.7
86.6
112
109
77.1
95.5
84.2
110
112
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:50 01/15/98
40
-------
TRIANGLE LABORATORIES OF RTP, INC. Page 5
Sample Result Summary for Project 44376 01/15/98
Method 8290X Full Screen Analyses (DB-5)
Oata File
\ jample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
1 'OTAL HxCDD
L'OTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
T980164
137-140 /
': s .^ . /
f. •- -
ng '
12/29/97
01/07/98
T
M2 3 TRAIN
Soxhlet
0.04
0.06 J
0.02 J
0.05 J
0.06 PRJ
0.12
0.16 JB
4.2
0.38
0.51
0.56
0 .21
0.22
0.01 PRJ
0.41
{0.05} J
0.24
7.4
1.1
0.86
0.26
34.0 Q
9.9
2.4
0.60
T980153 /
lOS-lOa'
Oj -> •
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
2.5
10.2
3.4 Q
4.5
7 . 4 QPR
5.4
3-27*
(90. 2-] SE
52.7 E
67.9 E
42.9 E
19.7
12.3
0.68 PR
11.7
1.4
1.7
175 E
t&97£vC7 SE
103 QE
11.0
Jr£W7U- SQE
•&4-1 19-O SE
-&&97<*O SE
15.3 X
T980167
Cleanup Blk
ng
12/31/97
01/07/98
T
XAD
Soxhlet
(0.003)
(0.004)
(0.005)
(0.004)
(0.004)
(0.004)
{0.02} JB
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.004)
(0.004)
(0.003)
(0 .004)
(0.004)
(0.003)
(0.004)
(0.004)
(0.004)
(0.003)
(0.003)
(0.003)
(0.003)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 84.8 92.6
13C12-PeCDF 234 97.4 99.6
13C12-HxCDF 478 100 ,--?-4_.4
13C12-HxCDD 478 101 .158 " Q
13C12-HpCDF 789 108 101
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 80.0 76.1
13C12-HXCDF 234 71.7 70.4
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 64.1 43.0 Q
13C12-2378-TCDD 64.3 68.7
13C12-PeCDF 123 75.6 73.6
13C12-PeCDD 123 90.9 83.3
74/5
69.2
52.5
54.6
68.7
76.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:50 01/15/98
41
-------
Data File
Sample ID
TRIANGLE LABORATORIES OF RTF, INC. Page 6
Sample Result Summary for Project 44376 01/15/98
Method 8290X Full Screen Analyses (DB-5)
T980164 T980153 T980167
137-140 105-108 Cleanup Blk
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
12/29/97
01/07/98
T
M2 3 TRAIN
Soxhlet
ng
12/29/97
01/06/98
T
M2 3 TRAIN
Soxhlet
ng
12/31/97
01/07/98
T
XAD
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 678
13C12-HxCDD 678
13C12-HpCDF 678
13C12-HpCDD 678
13C12-OCDD
{Estimated Maximum Possible Concentration}, (Detection Limit)
71.9
90.2
83.4
109
108
71.7
54.3 Q
77.0
102
110
== — '=—======—===—=—
63.7
80.6
84.9
108
115
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:50 01/15/98
42
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376
Method 23X (DB-225)
lata File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
X980083
TLI XAD BLANK
ng
12/29/97
01/07/98
X
XAD
Soxhlet
0.02
X980084
105-108
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
49.4
X980085
109-112
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
E 26.2 E
Page 1
01/11/98
X980086
113-116
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
28.4 E
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 73.0 86.7
83.4
92.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:38 01/i 1/93
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 44376
Method 23X (DB-225)
Page 2
01/11/98
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
X980087
117-120/216/217
/218
ng
12/29/97
01/07/98
X
M2 3 TRAIN
Soxhlet
62.8 E
X980088
121-124/219
ng
12/29/97
01/07/98
X
M23TRAIN
Soxhlet
85.0 E
P980166
125-128
ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet
17.5
P980167
129-132
ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet
0.83
Internal Standards Percent Recovery Summary {% Rec)
13C12-2378-TCDF 109 78.8
51.0
74.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:38 01/11/98
44
-------
TRIANGLE LABORATORIES, INC. Page 3
Sample Result Summary for Project 44376 01/11/98
Method 23X (DB-225)
Data File P980168 P980169
Sample ID 133-136 137-140
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet
0.57
ng
12/29/97
01/10/98
P
M23TRAIN
Soxhlet
0.69
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 73.9 72.5
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713 Printed-13-
Phone: (919) 544-5729 • Fax: (919) 544-5491 W>
-------
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports.
Please note that all data qualifier flags are subjective and are applied as consistently as
possible. Each flag has been reviewed by two independent Chemists and the impact of the
data qualifier flag on the quality of the data discussed above. The most commonly used
flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag is used only when the
concentration of analyte found hi the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
An 'E' flag is used to indicate a concentration based on an analyte to internal standard
ratio which exceeds the range of the calibration curve. Values which are outside the
calibration curve are estimates only.
An T flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A 'J' flag is used to indicate a concentration based on an analyte to internal standard ratio
which is below the calibration curve. Values which are outside the calibration curve are
estimates only.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
An 'S' flag indicates that the response of a specific PCDD/PCDF isomer has exceeded the
normal dynamic range of the mass spectrometer detection system. The corresponding
signal is saturated and the reported analyte concentration is a 'minimum estimate'. When
the 'S' qualifier is used in the reporting of 'totals', there is saturation of one (not
necessarily from a specific isomer) or more saturated signals for a given class of
Data Hags . Page 1 of 2
Rev. 11/19/97
46
-------
compounds. Results for saturated analytes are reported as greater than the upper
calibration limit.
A 'U' flag is used to indicate that a specific isomer cannot be resolved from a large, co-
eluting interferent GC peak. The specific isomer is reported as not detected as a valid
concentration cannot be determined. The calculated detection limit, therefore, should be
considered an underestimated value.
A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
An 'X' flag is used to indicate that a polychlorodibenzofuran (PCDF) peak has eluted at
the same time as the associated diphenyl ether (DPE) and that the DPE peak intensity is at
least ten percent of the total PCDF peak intensity. Total PCDF values are flagged 'X' if
the total DPE contribution to the total PCDF value is greater than ten percent. All PCDF
peaks that are significantly influenced by the presence of DPE peaks are either reported as
"estimated maximum possible concentration (EMPC) values without regard to the isotopic
abundance ratio, or are included in the detection limit value depending on the analytical
method
Data Rags Page 2 of 2
Rev. 11/19/97
47
-------
Method 23 Sample Calculations:
Analyte Concentration
The concentration or amount of any analyte is calculated using the following expression.
Where:
* RRFM * W
Amt(C) = amount of a given analyte, expressed in nanograms (ng) or picograms
(pg)-
A
-------
TLI Project: 44376
|lient Sample: TLI XAD BLANK
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980152
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
XAD Date Received:
TLI Blank Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
II
12/29/97
01/06/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
i&SW:;:W>x&^
2,3,7,8-TCDD
U,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
^,4,7,8-PeCDF
P,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
U,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
EMPC
0.03
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.04
ND
ND
ND
HSSSSHSiSS-x^
0.007
0.01
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.009
0.01
0.01
0.01
0.02.
0.01
0.007
0.01
0.01
0.01
2
0.01
0.01
0.01
^^^^^^^^^^^^^S^^^^^^^^^M
J_
0.81 25:40
I .
Page 1 of2
X2J7J>SR TZOI. LARS 6.10.08
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:48 01710/98
4S
-------
TLI Project: 44376
Client Sample: TLI XAD BLANK
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980152
'infernal Standard* ,„,,,
13C12-2,3,7,8-TCDF
l3C12-2,3,7,8-TCDD
13C12-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13CI2-l,2,3,6,7,8-HxCDD
13C12-l,23,4,6,7,8-HpCDF
'3Ci2-l,2,3.4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37a,-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13C12-l,2,3,4,7,8-HxCDD
13CI2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13Ci2-l,2,3,7,8,9-HjcCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
AmLjngJ .:
15
2.6
25
33
2.6
33
2.6
4.0
9.1
Awt (tig)
3.4
3.9
3.4
4.1
3.8
Amt (ng)
2.9
2.8
-
b^*Ha*0f
61.4
65.5
62.3
81.5
64.8
81.9
64.5
100
114
% Recovery
84.4
98.4
85.3
102
95.5
% Recovery
71.7
69.8
QC Limits .
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%-130%
40%- 130%
;%#Wfc£V'
0.75
0.80
1.52
1.49
0.53
1.17
0.45
1.01
0.91
Ratio
1.52
0.49
1.19
0.45
Ratio
0.51
0.52
Ratio
0.81
1.15
ST Flags
25:39
26:21
29:30
30:30
32:59
33:41
35:59
37:04
40:55
RT Flags
26:21
30:10
32:53
33:36
37:36
8T Flags |
34:18
33:29
RT Flags
26:10 _
34:01
Data Reviewer.
01/10/98
Page 2 of 2
X237_PSR V2.01. LARS S.iO.OS
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:48 01/10/98
50
-------
Initial
Data..
Data Review By:
42_/£2£
Calculated Noise Area:
The Total Area tor each peak with an ion abundance ratio outside
atio limits has been recalculated according to method requirements.
2.19
Page No.
01/10/98
Listing of T980152B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306
304-306
13C12-TCDF
316-318
316-318
.ODD
320-322
320-322
37C1-TCDD
328
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
2
NL
SN
5
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
0:00
23:50
25:17
25:40
26:32
27:12
Peaks
0:00
24:40
24:57
25:15
25:39
26:06
26:20
Peaks
0:00
23:52
24:11
24:16
24:37
24:57
25:26
25:40
26:02
26:21
26:36
26:49
27:02
27:09
27:43
Peaks
0
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65-0.89
1
1
0
0
3
2
.61
.62
.88
.81
.67
.61
65-0.89
1
0
0
0
0
1
0
65
0
1
1
0
0
0
2
1
1
0
4
1
3
0
0
.67
.82
.90
.93
.75
.04
.25
Al
-0.39
.72
.05
.33
.51
.17
.28
.08
.11
.20
.85
.37
.75
.83
.17
.40
1.72
2.64
12.98
21.81
0.37
2.41
34.79
6.07
9.75
1.67
0.82
0.90
0.93
0.75
1.04
0.25
1.
113
12
27
2.533.
17,
1.
2,704.
.27
.56
.39
.67
.33
.12
.45
,57
51.
6.
14.
1,086.
10.
30
28
61
30
06
0.878-1.073
0.000
0.929
6.91 0.986
12.06 1.001 2378-TCDF AN
1.034
1.060
0.961-1.039
0.000
62.26 0.962
7.00 0.973
15.63 0.984
,447.53 1.000 13C12-2378-TCDF ISO
9.67 1.018
1.027
DC
DC
NL 0:00
SN 24:28
25:01
DC SN 25:19
Above: TCDF / TCDD Follows
0.36
2.99
1.45
1.61
0.28
0.85
0.42
3.29
0.27
3.55
0.53
0.57
0.51
0.78
1.20
0.00
0.74
1.26
11.57 11.57
0.92
0.903-1.045
0.000
0.906
0.918
0.921
0.934
0.947
0.965
0.974
0.988
1.000 2378-TCDD
1.009
1.018
1.026
1.030
1.052
0.924-1.076
0.000
0.929
0.949
0.961
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:49 01/10/98
51
-------
Page Mo.
01/10/98
Listing of T980152B.dbf
Mat chad GC Peaks / Ratio
/ Rat. Tim*
Compound/
M_Z QC.Log Omit Why . .RT. OX Ratio Total.Area..
• Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
3
ML
WL
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
26:21
26:43
27:05
27:38
27:47
Peaks
0:
24:
24:
25:
26:
26:
26:
00
02
48
14
10
21
40
0.
RO
RO
RO
RO
RO
1
1
,853.93 1,853.93
5.05 5.05
1.05
2.11
1.50
,870.55
.65-0.89
2
4
1
1
0
0
0
Peaks
0:
27:
27:
28:
28:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
29:
30:
30:
30:
30:
30:
31:
00
32
53
04
08
14
31
41
52
01
08
14
23
31
47
54
12
23
30
35
46
09
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.11
.55
.46
.00
.81 2
.30 2
.98
4
32-1.78
0
1
0
0
0
0
0
1
2
1
1
1
1
0
0
0
0
0.
1
0
5
1
.76
.65
.43
.15
.58
.42
.36
.93
•57
.00
.10
.44
.42
.95
.63
.68
.98
.93
.65
.55
.63
.42
Peaks
0:
27:
28:
29:
29:
29:
30:
00
24
38
07
30
47
10
1.
RO
RO
3.42
1.96
3.12
18.62 10.56
,670.14 1,191.70
,183.11 967.35
38.07 21.10
,909.94
Tfnn / P«f HP Prti 1 nura
±\rUU 1 rV\~ijr f OXXOW9 — ~
0.72
3.79
0.64
0.16
0.43
0.43
1.68
4.18
1.30
1.79
2.96
2.73
1.55
1.25
1.09
0.63
1.69
1.74
1.75
0.67
0.61
2.66
0.00
32-1.78
1
3
1.
0,
1,
1.
.47
.75
.59
.92
.52 2,
.45
1.52 2,
0.47
1.4S
165.40 101.52
4.77 2.90
,129.72 1.284.48
26.73 15.81
,079.94 1,253.83
1
1
1
1
1
.000 37C1-TCDD
.014
.028
.049
.054
SUR:
0.924-1.076
0
0
0
10.52 0
1,478.44 0
1,215.76 1
21.51 1
.000
• 912
.941
.958
.993 13C12-1234-TCDD
.000 13C12-2378-TCDD
.012
RSI
IS1
0.931-1.063
0
0
0
0
0
0,
0,
0,
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
.000
.933
.945
.951
.954
.957
.967
.972
,979
,984
988
991
996
001 12378-PeCDF
010
014
024 23478-PeCDF
030
034
037
043
056
AN
AN
0.864-1.136
0.
0.
63.88 0.
3.14 0.
845.24 1.
10.92 1.
826.11 1.
000
929
971
987
000 13C12-PeCDF 123
010
023 13C12-PeCDF 234
IS2
SDR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:49 01/10/98
-------
Page Ho.
01/10/98
Compound/
Listing of T980152B.dbfi
Matched GC Peaks / Ratio / Ret. Tim*
352-354
PeCDD
356-358
356-353
13C12-PeCDD
363-370
368-370
HxCDF
374-376
374-376
Omit Why . .
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
6
NL
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
30
30
30
31
31
RT.
:31
:51
:58
:08
:35
OX
RO
RO
RO
RO
Ratio Total. Area. .. Area. Peak. 1. . ATI
1
0
1
1
1
.21
.89
.20
.30
.65
Peaks
0
28
29
29
29
30
31
31
:00
:4S
:38
:47
:56
:04
:16
:32
1
RO
RO
RO
RO
RO
RO
.32
2
0
1
1
0
2
2
0
-1.78
.33
.25
.66
.70
.65
.06
.50
.13
Peaks
0
29
29
29
30
30
30
30
31
31
:00
:28
:35
:54
:13
:30
:38
:49
:00
:08
1
RO
RO
RO
RO
RO
RO
5
1
1
5
1
4,412
.73 3.48
.18
.17
.07
.59
.29
ia.P«ak.2.. Rel.RT Compound . Name .. ID.
2.88 1
1
1
1
1
.034
.046
.050
.055
.071
1
1
2
3
2
1
1
0
0
.10
.46
.55
.08
.01
.63
.28
.38
.00
.32-1.78
1
0
1
2
0
1
1
2
0
1
Peaks
0
32
32
32
32
32
32
32
33
33
33
33:
33:
:00
:01
:12
:16
:27
:38
:53
:56
:07
:11
:29
;38
:47
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.42
.87
.61
.75
.97
.49
.41
.36
.24
.06
0
5
8
1
1
1,545
169
3
1
1
1,729
n^/*ni
.05-1.43
1
1
0
2
0
10
1
3
3
0
1
0
1
.61
.13
.48
.21
.81
.31
.46
.66
.00
.54
.56
.32
.02
Peaks
i
0
0
0
.46
.59 3.40
.77 5.41
.53
.63
.28 925.89
.38 99.19
.72
.23
.20
.02
.48
.83
.58
.63
0.79
0
2
0.
0.
0.
2.
.29
.08
.99
.47
.78
.02
0.74
0.
0.
.99
.00
0.939-1.022
0
0
0
0
0
0
•1
1
.000
.943
.972
.977
.981
.986
.025
.034
0.869-1.131
0.
3.93 0,
3.36 0.
.000
.966
.970
0.980
0.
619.39 1.
70.19 1,
1.
1.
1.
.991
.000 13C12-PeCDD 123 IS3
.004
.010
.016
,021
0.964-1.049
0.
0.
0.
000
971
976
0.978
0.
0.
0.
0.
1.
1.
1.
1.
1.
984
989
997
998 123478-HxCDF AN
004
006
015 234678-HXCDF AN
020
024
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:49 01/10/98
53
-------
Pago No.
01/10/98
Listing of T980152B.dbfi
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
13C12-HXCDP
384-386
384-386
-HXCDD
390-392
D
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
DC
DC
DC
DC
DC
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
6
NL
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
WH
0
0:00
31:56
32:03
32:12
32:53
32:59
33:29
34:07
34:18
34:34
34:39
34:39
Peaks
0:00
32:51
33:03
33:14
33:20
33:26
33:51
34:18
Peaks
0:00
33:04
33:36
33:41
34:01
34:14
34:29
Peaks
0:00
36:01
36:15
36:31
36:42
36:55
37:29
38:06
Peaks
0
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
.43-0.59
0
0
0
0
0
0
0
0
0
0
0
0
.59
.57
.53
.54
.49
.53
.52
.72
.51
.28
.76
.32
4
22
42
1
1,489
1,896
1,949
2
1,583
6
2
3
6,984
.05-1.43
1
1
0
0
1
0
0
0
.05
.10
.65
.66
.06
.23
.63
.88
1
6
1
0
0
0
0
1
0
.44
.42 8.16
.13 14.68
.03
.37 491.62
.59 654.96
.81 663.44
.13
.78 533.58
.28
.02
.22
.60
.78
.67
.55
.70
.66
.58
.45
.26
.00
,05-1.43
1
0
1
1
1
4
0
.83
.98
.19
.17
.15
.41
.26
1
13,
1,397,
1,695,
2,073,
.72
.44 7.44
.26 758.52
.05 915.70
.12 1,110.55
5.64
1.
,68
0.879-1.121
0
14.26 0
27.45 0
0
998.25 0
1,241.63 1
1,286.37 1
1
1,050.20 1
1
1
1
.000
.968
.972
.976
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.015 13C12-HXCDF 234
.034
.040 13C12-HXCDP 789
.048
.051
.051
SDR3
IS4
ALT2
ALT1
0.958-1.015
0
0
0
0
0
0
1
1
.000
.975
.981
.987
.990
.993
.005
.013
0.970-1.030
0.000
7.58 0.982
638.74 0.998 13C12-HXCDD 478
779.35 1.000 13C12-HXCDD 678
962.57 1.010 13C12-HXCDD 789
SOR4
IS5
RS2
1.016
1.024
5,178.87
0.
RO
RO
RO
RO
RO
RO
RO
tiv^nr
88-1.20
0
1
0
6
0
3
.84
.24
.93
.03
.36
.45
1.71
0.19
0.90
2.98
1.
99
0.59
0.61
0.78
0.
0.
0.
71
24
00
0.998-1.053
0.000
1.001 1234678-HpCDP
AN
1 . 007
1.
1.
1.
1.
1.
015
020
026
042
059
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:49 01/10/98
54
-------
Page No.
01/10/98
Listing o« T980152B.dbf
Hatched OC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT.
OK Ratio Total.Area. .. Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
WH
P
NL
,2
NL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
35:39
36:22
36:37
36:47
36:51
37:17
37:36
38:12
Peaks
0:00
36:20
36:32
36:59
37:04
37:39
Peaks
0:00
36:17
37:04
Peaks
0:00
35:29
35:37
35:49
36:15
36:39
37:03
37:13
37:39
37:42
37:51
38:08
38:40
39:05
39:32
39:43
40:11
40:38
40:44
40:57
0.
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
37-0.51
0
0
0
1
0
0
0
0
0
.57
.45
.54
.34
.34
.87
.85
.45
.50
88-1.20
2
4
1
0
1
0
.50
.21
.56
.54
.51
.47
1
1,190
3
0
0
1
1
886
2
2,077
.84
.64 369.83
.21
.92
.56
.25
.14
.66 276.72
.63
.30
0.944-1.111
0
820.81 1
1
1
1
1
1
609.94 1
1
.000
.000 13C12-HpCDF 678
.011
.018
.022
.024
.036
.045 13C12-HpCDF 789
.062
IS6
SUR5
• HpCDF / HpCDD Follows -
0
0
0
0
.29
.39
.84
.55
2.06
0.71
0.976-1.006
0
0
.000
.980
0.986
0
1.
.998
.000 1234678-HpCDD
AN
1.016
0.00
0.
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
38-1.20
2,
0.
1.
.72
.93
.01
0.38
21.86 10.54
1,499.
1,521.
u^/~nr
.74 752.23
.60
76-1.02
1,
0.
0.
0.
0.
0.
1.
2.
0.
1.
.08
.32
.89
.59
.38
,72
,03
20
.78
73
1.42
0.
2.
1.
0.
1.
0.
0.
0.
5.
52
20
01
40
10
46
55
36
63
0.
0.
1.
1.
0.
0.
3.
1.
2.
1.
1.
1.
0.
1.
0.
1.
0.
0.
1.
0.
.93
74
,02
.08
76 '
91
21
02
14
04
21
19
93
75
89
97
36
66
64
15
0.973-1.027
0.000
11.32 0.979
747.51 1.
U frt 1 1 m~»<*
,000 13C12-HpCDD 678
IS7
0.902-1.098
0.000
0.867
0.870
0.875
0.886
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
896
905
910
920 •
921
925
932
945
955
966
971
982
993
996
001
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:4iCgyi 0/98
vJ vJ
-------
Pag* No. 6 Listing of T9801S2B.db£
01/10/98 Matched
-------
rile:T9B01S2 #1-810 Acq: 6-JAN-98 15:20«28 EH- Voltage SIS 70T Noise: 780
303.9016 T:2 3SU3(256,30, -3.0) PXD(9,S,5, 0.05%,3120. 0,1.00\,T,T) Sxp:SDBSUS
TSIANGLE LABS Text:TLI»44376 TLI XAD BLANK Ujj-. JXME -
i003\ A9.75E4
23:00 24:00 25,00 25:00
r±la:T930152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS 70T Noiaei484
305.8987 F:2 BSUB(2S6,30,-3.0) PXD(9,5,5, 0. 05\r 1936.0,1.00\,r,T) SxpiNDBSUS
TSIANGLE LABS Text:TLIt44376 TLI XAD BLANK ZKT. TIME - 15:23
100* AI.2125
27<00
•00 25:00 25:00
rile:T980152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70TNoiae:600
315.9419 F:2 BSU3(256, 30,-3.0) PKD(9,5,5, 0. 05\,2400. 0,1.00\,F, T) Exp:NDBSUS
TRIANGLE LABS Teit:TLI»44376 TLI XAD BLANK I1TJ. TIME - 15:23
1004 A1.Q9E7
aol
60:
40:
20:
27-00
OJ
24:00 25:00 25:00
rila.-r580152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS 70TNoiae:359
317.9389 F:2 BSUB(256, 30,-3.0) PKD(9,5,5, 0.051,1436.0,1.00\,r,T) Exp-.NDBSUS
TRIANGLE LABS Text:TLI»44376 TLI XAD BLANK ISJ. TIME - 15:23
1003, A1.15E7
80:
sol
20j
0.
27-00
23l-00 24iOO 25 .-00 25.-00 271-00
File:T9a0152 #1-810 Acq: S-JAN-98 15:20:28 EI+ Voltage SIR 70T
330.9792 F:2 Exp:NDBSUS
TRIANGLE LABS Text:TLI»44376 TLI XAD BLANK IKT. TIME - 15:23
J00^-~ 'f^2is2t—~^—'-- ---'- ZJ'jSis^-iiS^ _ 3S:-23, r._r—J-^^3£(*B 26:47 *Zi£?
80: —"^ "~ '
50:
40:
20:
OJ
23:00 24:00 25:00 25:00
File:T9801S2 #1-810 Acq:S-JAN-98 15:20:28 EI+ Voltage SIS 70T
375.8364 F:2 Exp:NDB5aS
TRIANGLE LABS Tftxt:TLIf44376 TLI XAD BLANK HKT. TIME
1003\
26:06
25:48
«:55 | 34:45 35,33
27:00
15:23
1
"
40J
20:
22:41
23 1 1;
i i • »^ • »* i i
1 ita It Inl iu 1 Hi n 1 ^^;"il J i 1 n ll ill
_2. 7X4
.0.020
Timel
.2. 725
.2.225
.1. 525
.1.125
5.525
0.020
Time\
3.725
3.025
2.225
.1.525
.7.425
0.020
Tiae\
2300
241 00
2StOO
25oO
27-00
.1.527
.1.127
.7.425
.3.725
.0.020
Xunel
5.523
.5.323
3.323
.2.523
.1.323
.0.020
Tlael
-------
rHe:T980153 #1-810 Acq:6-JAN-98 15:30:28 EI+ Voltage SIS 70T NoiaetlSO
319.8965 F:3 BSUB(356, 30, -3. 0) PKD(7,5,3, 0. 05%, 720.0,1. 00\,T,T) ExpiSDBSUS
TSIANGLE LASS Text:TLIf44376 TLI XAD BLANK uu. TIME
1003k - .1 , . II Al. 3E4
.91E3
us
15:23
A1.11E4
1 111 JljJjttlJ
JWJWIw
77:00
75
15i33
S4
A2.90E3 A1.15E4
hi i
MJA \h m
WMl/Mh
27:00
SUS
15:33
27:00
SUS
15:23
271-00
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15:33
27:00
15:23
7 Z^^-^kZLJZjSijt
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7.4E3
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.4.1E3
.3 . OE3
.2.013
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-3.3E6
.2.5E6
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.7.3X6
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O.OEO
Tiae
34:00 35:00 36:00
rile:T980153 tl-810 Acq:6-JAN-98 15:20:38 Eli- Voltage SIS 70T Noise 124 8
331.8936 f:3 BSU3(356, 30, -3.0) tXD(7,Sf 3, 0. 05\,992.0,1.00\,r, T) EzpiBDBSUS
TRIANGLE LASS Text:TLIf44376 TLI XAD BLANK XK7. Tim
1003, A1.86E4 A1.93E4
34:00 35:00 36:00
rile:T980153 #1-810 Acq:6-JXN-98 15:30:38 EI+ Voltage SIS 70T Koiae:2041
331.9368 T:3 BSUB(356, 30, -3. 0) PKS(7,5,3, 0. OS\,8164.0,1.00\,r,T) Exp:XDB5US
TRIANGLE LABS Text:TLH44376 TLI XAD BLANK INJ. TIME
1001
aol
601
401
301
OJ
24:00 25:00 25:00
Wle:T5fl0152 #1-810 Act?:6-JAN-98 15:30:38 EI+ Voltage SIX 70T Noiae:967
333.9338 T:3 BSUB(356,30,-3.0) PKD(7,5,3,0.051,3863.0,1.00\,r,T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 TLI XAD BLANK INJ. TIME
1003
aol
sol
401
20:
OJ
A1.48E7
\A1.33E7
J\.
34:00 35:00 36:00
rile:T980152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS 70T Noiae:368
327.8847 T:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1473.0,1. 00\,T, T) Eip-.NDBSUS
TRIANGLE LABS Text.-TLJ*44376 TLI XAD BLANK INJ. TIME
lOOi A1.85E7
aol
sol
40.
301
0.
34:00 35:00 36:00
rile:T980152 # 1-810 Acqs6-JAN-98 15:30:38 EI+ Voltage SIS 70T
330.9793 F:3 Exp:NDS5US
TSIANGLE LASS Text:TLIf44376 TLI XAD BLANK XI
25:22 25:41 25:55 26,13 36:47
A —— * — -*~
80.
60:
40.
20:
0:
24:00
35100
36s 00
58
-------
ri2a:T980152 #1-810 Aeq-.S-JJOt-aa 15:20:28 XI+ Voltage SIS 70T Noiaa:221
339.8597 T:2 BSUB(256,30, -3. 0) PKD(7,5,3,0.05\,884.0,1.00\,r,T) Exp:BDB5US
TRIANGLE LASS Tej[t:TLI#44376 TLI XAD BLANK HKT. njJF - 15,23
28:00 29:00 30,00
FU.eiT9S01.53 #1-810 Aeg:6-JJUT-98 15:30:20 SI+ Voltage SIX 70T Noise:283
341.8567 t:2 3SUB(256,30, -3.0) PXD(7,5,3, 0. OS\r1152. 0,1.00\,r,T) Ezp:NDB5US
TRIANGLE LASS Text:TLIf44376 TLI XAO BLANK UKT. TIME - 15:23
IOCS A1.64E4
31:00
28': 00 29:00 30:00
File:T980152 #1-810 Acq:S-JAN-98 15:20:28 EI+ Voltage SIR 70T Noise: 139
351.9000 T:2 BSUB(256,30,-3.0) PKD(7,5, 3, 0. 05\,55S. 0,1. 00\,f,T) Ezp:NDB5US
TRIANGLE LABS Tezt:TLI»44376 TLI XAD BLANK ZKT. TIKE - 15:23
1004 . A1.28E7 A1.2SE7
80:
SO:
40:
20:
ol i
31:00
Al.OSES
28:00 29:00 30:00
rile:T980152 11-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70T Noiaei96
353.8970 T:2 BSU3(256,30,-3 .0) PKD( 7,5, 3, 0. 05%, 384. 0,1. 00%,J, TJ Exp-.lWBSUS
TRIANGLE LABS Text:TLI#44376 TLI XAD BLANK INJ. TIKE - 15:23
31: 00
1003
80J
sol
401
201
oJ
A3.
45ES
A8.26ES
j L
28:00 29:00 30:00
rile:T980152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70T
330.9792 T:2 Ezp-.NDBSVS
TRIANGLE LABS TeJCt:TLI#44376 TLI XAD BLANK JK7. TIME •
8-.1S - 3o-.os
31:00
80:
60:
40:
20:
ol
15:23
0:23 30:42
31:26
28:00 29:00 30:00
rile:T980152 #1-810 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70T
409.7974 f:2 Exp:HDB5OS
TRIANGLE IA3S Text:TLI«44376 TLI XAD BLANK HKT. TIME
1003,
31:00
80:
so:
40:
20:
o:
27:47
28:34
15:23
30:29
30:14
28:57
31121
29:31
29:54
30:55
28:00
29\00
30\QO
31\00
.O.OEO
Tim:
r1.0E4
18.1E3
'-6.1E3
''.4.0E3
'.2.0E3
•.O.OEO
Time
3. 8E6
.3.0E6
-2.3E6
_1.5E6
'-7.SES
.O.OEO
Time
.2.6E6
.2.0E6
.1. 5E6
.1. OE6
.5.1ES
.O.OEO
Time
.1. 8E7
.1.4E7
.1. 1E7
.7.0E6
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.O.OEO
Tiae
8.4E3
6.7E3
5.0X3
3.3E3
1. 7X3
0.0X0
T±ae
5S
-------
r2.J.e:T9B0152 #1-010 Acq:6-JMf-na 15:20:28 SI+ voicag-e SIS 70T HoiaetSOO
355.8546 T:3 BSOB(256,30, -3.0) PXD(7,S,3,0.05\,2000.0,1.00\rr,T) SxptODBSUS
TRIANGLE LASS TextsTLH44376 TLI XAD BLANK 1ST. TIME - 15t23
1001
28:43 29:00 29:12 29:24 29:36 29:48 30:00 30:13 30:24 30:36 30:48 31:00 31:12
rile:T9S0152 #1-810 Act;:6-JAN-98 15:20:28 SH- Voltage SIS 70T Wolfe:215
357.8516 T:2 BSUB(256,30, -3. 0) PXD(7,5,3, 0.05%, 8tfO. 0,1.00\,T,T) XxpsODBSUS
TRIANGLE LABS T&zt:TLH44376 TLI XAD BLANK 1ST. TIME' 15:23
2.9E6
.2.3E6
'.1. 7E6
'.1.2E6
'.5.8E5
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24
TilesT980152 #1-810 Acq: 6-JAJT-98 15:20:28 EI+ Voltage SIS 70T So±ae:13S
367.8949 f:2 BSUB(256,30, -3.0) PKD(7,5,3,0.05l, 540.0,1.00\,r,TJ Exp:NDBSUS
TRIANGLE LABS Text:TLI#44376 TLI XAD BLANK ISO: TIME - 15:23
IOCS • A9.26E6
80.
60.
40.
20.
.92E5
.O.OEO
SB':4a 29:00 29:12 29:24 29':36 29':43 30:00 30:12 30:24 30:36 30:48 31:00 3l':12 31:24' Time
rila:T980152 #1-810 Actj:6-JAN-98 15:20:28 SI+ Voltage SIS 70T Otaiae:93
369.8919 F:2 BSOB(256, 30,-3.0) PKD(7,5,3, 0.05%,372.0,1.00\,T,T) Exp:NDB5nS
TRIANGLE LABS Text:TLI#44376 TLI XAD BLANK JJKT. TIME - 15:23
A6.J. E6 _1.8r5
1.5E6
1.1E6
7.4E5
3.7E5
O.OEO
80.
60.
40.
20.
28:43 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24
r±latT980152 tl-810 Ac
-------
r±le:T980152 tl-396 Acq:6-JAN-98 I5:20i2a EI+ Voltage SIS 701 Noise1530
373.8208 T:3 BSOB(256, 30, -3. 0) PKD(7,S,3,0 .OS\,2120.0,1.00\,T,T) Exp-.SDBSOS
TSIANGLE LASS TuxH:TLH44376 TLI XAD BLANK JK7. TIME - 15i23
1003i A1.36E4
32': 00 33:00 34:00
rile:T9B01S2 tl-396 Acq:6-JAN-96 15:20:28 EI+ Voltage SIS 70T Sola*1329
375.8178 T:3 BSOB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1316.0,1. 00%, f,T) Exp:NDB5US
TSIANGLE LABS Text:TLIf44376 TLI XAD BLANK HOT. TIME - 15:23
100* A9.27X3
.5E3
.8X3
,1X3
.4X3
.7X3
.OEO
Tine
32:00 33:00 34:00
r±le:T980152 tl-396 Acq:6-JAN-98 15:20:28 EH- Voltage SIS 70T No±ae:823
383.8639 F:3 BSUB(256,30,-3.0) PKD(7,5,3,0.OS\,3292.0,1.00\,r,T) Exp:XDB5US
TRIANGLE LABS Tejct:TLI#44376 TLI XAD BLANK Utt. TIME - 15:23
1001, A6.5SE6 A6.f3E6
80:
60:.
401
201
A5.34E6
32:00 33:00 34:00
rile:T930152 tl-396 Acq: 6-JAN-98 15:20:28 EI+ Voltage SIS 70T Noiae: 1393
385.8610 f:3 BSOB(256,30,-3.0) PKD( 7, 5, 3, 0. 05\,5572. 0,1. 001,T, T) Exp:NDB5US
TSIANSLE LABS Text:TLI»44376 TLI XAD BLANK IKT. TIME - 15:23
1003
80:
40:
20:
0:
A1.24E7
A1.29E7
Al.05E7
32:00 33:00 34:00
File:T980152 tl-396 Acq:6-JZN-98 15:20:28 EH- Voltage SIX 70T
392.9760 7:3 Exp-.NDBSUS
TSIANGLE LABS Text:TLIt44376 TLI XAD BLANK ZK7. TIME " 15:23
100$ 32:04 32:16 32:39 32:5733:08 33:_43. 33:59 34jl_Q .
80J
50:
ao:
o:
34:45
32:00 33:00 34:00
rile:T9801S2 tl-396 Aeq:6-JAS-9B 15:20:28 EI+ Voltage SIS 70T
445.7555 F:3 Exp-.XDBSUS
TSIANGLE LABS TeJCt:TLIt44376 TLI XAD BLANK IRJ. TIME - 15:23
80:
50:
40:
201
33
""
""
"<5
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20
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32:00
JJtOO
34:00
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Time
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Time
9E6
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3E6
6E6
8E5
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Time
3E6
6E6
OE6
3E6
7E6
OEO
Tiae
1E1
7S3
5E3
3E3
2X3
0X0
Mae
-------
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
r±10:T9801S2 #1-396 Actj:6-JAtt-98 15:20:28 EI+ Voltage SIX 701 Noiae:706
401.8558 T:3 BSU3(256,30, -3. 0) PKD(7, 5,3, 0. 05^,2824.0,1.00\,T,T) Eip:HDS5VS
TRIANGLE LASS Text:TLIt44376 TLI XAO BLANK ZK7. TIKE - 15:23
1004 A1-11E7
l-lS6 Acq:6-JAH-98 15:20:20 Sir VoJ.tM3 3SUS(256,30,-3.0) PXD(7,3,3, 0. 05\,1820.0,1.00\,T,T) Exp:SDBSUS
TSIASGLS LASS Taxt:TLH44376 XL! XAD BLANK ZK7. TTHX - 15>23
1001 A3.49X4
80.
32:24 32:36 32:48 33tOO 33tl2 33:24 33:36 33:48 34:00
T±le:T9801S2 tl-396 Acq:6-JXS-98 15:20:28 XI+ Voltago SIX 70T Soiae:435
391.8127 Tt3 aSV3(256,30,-3.0) PKD(7,5,3,0.05\,1740.0,1.00\,r,T) XzpsSDBSOS
TSIANSLX IABS Teit:TLIf44376 TLI XAO BLANK HKf. TIMX - 15:23
1001, A3. J.8X4
34:12 34:24
80.
60.
40.
20.
A6.48X3
AS.16X3
A7.97X3
34:12 34:24
80.
60.
40.
20.
A9.16E6
~r
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32:24 32:36 32':48 33:00 33:12 33:24 33:36 33:48 34:00
r±le:T980152 »l-396 Acq:6-J7OT-98 15:20:28 EI+ Voltage SIX 70T Noiaa:384
403.8529 T:3 BSUS(256, 30, -3. 0) PXD( 7, 5, 3, 0. 051,1536. 0,1 . 00\,T, T) Exp:XDB5US
TRIANGLE LABS Text:TLI»44376 TLI XAD BLANK IXT. TIMX - 15:23
1001 A9.63E6
34:12 34:24
80.
60.
40.
20.
A7.79E6
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
Tile:T980152 tl-396 Acq:6-JAN-9S 15:20:28 XI+ Voltage SIS 70T
392.9760 P:3 Xxp:m>BSOS
TRIANGLX LASS Text:TLI144376 TLI XAD BLANK XK7. TIME • 15:23
34:12 34:24
100%
80.
60.
40.
20.
0.
32:39
32:57 33:08
33:25
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.0.0X0
Tia>
3.2E6
.2.5E6
.1. 9E6
.1.3X6
'.6.3ES
O.OEO
Time
32:24 ' '32:36 ' '32:48 33:00 33:12 33:24 33:36 33':48 34\6o ' 34:12 34:24
.2.7X6
.2.2X6
.1. 6X6
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Tiae
.8.2X6
.6.6X6
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Tiae
62
-------
rile:T980152 tl-563 Acq:6-JZN-98 15:20:28 EI+ Voltage SIS 70T Noiaei231
407.7818 f:4 BSOB(256, 30, -3. 0) ?KD(7,S, 3, 0. 05%, 924. 0,1.00\,r,T) Exp-.BDBSUS
TRIANGLE LASS Text:TLIi44376 TLI XAD BLANK J3K7. TIKE - 15:23
3S':00 36':12 36:24 36:36 36:48 37:00 37:12 37:24 37:36
rile:T980152 tl-563 Acq:6-JAN-98 15:20:28 XI+ Voltage SIS 70T Noise:273
409.7789 f:4 BSUS(25S,30, -3. 0) PKD(7,5r3f0.05\r1092.0,1.00\,r,T) Xzp:NDB5US
TRIANGLE LABS Text:TLI#44376 TLI XAD BLANK DCT. HUE - 15:23
1001
O.OEO
37:48 38:00 38:12 Tiae
36\00 ' 'j'tflii ' '36':24 36:36 36:48 37:00 37:12 37:24 37:36
rlle:T9801S2 #1-563 Acq:6-JAN-98 15:20:28 EI+ Voltage SIS 7 OT Noise -.36 5
417.8253 F:4 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 051,1460. 0,1. 00*,r,T) Exp:NDB5as
TRIANGLE LABS Text:TLI*44376 TLI XAD BLANK JKT. TIME - 15:23
1001A3.70E6
37:48
38:00
80:
50:
40J
201
A2.77E6
38:12 Tiae
9. SE5
•.7.6ES
'•.5.7E5
.3.8E5
.1.9E5
O.OEO
36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36
Tile:T980152 tl-563 Acq:6-JAN-9S 15:20:28 Eli- Voltage SIR 70T Noise:638
419.8220 F:4 BSUB(256, 30,-3 . 0 ) PKD(7, 5,3 , 0 . 051,2552.0,1.00\,r,T) Elp:lO3BSUS
TRIANGLE LABS Text:TLI144376 TLI XAD BLANK INJ-. TIME - 15:23
100i.Aa.21E6
37:48
38:00
80:
SO:
-------
36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30 37:36
rile:T9801S2 »l-563 Acq:6-JAN-98 15:20:26 EI+ Voltage SIX 70T Noiae:S87
435.8169 F:4 BSUB(256,30,-3.0) PKD( 7,5,3, 0. 05\,2348. 0,1. 00\,T, T) Ezp:NDB5US
TRIANGLE LASS Teit:TLI»44376 TLI XAJ) BLANK UKT. TIME - 15:23
.1004 A7.52E6 -1.7E6
rU.otT930152tJ.-56J ACtJlO-JAN-yo 1SUUIJO JUf VOJ.tagm SIM TOT Sola*! 177
423.7766 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.03\,70a.O,1.00\tr,T) ExpiBDBSUS
TRIANGLE LABS Text:TLIt44376 TLI XV) BLANK XKT. TINE " 15:23
1001
-5.4E3
36-12 36-18 36': 24 36:30 36:36 36:42 36:48 36>54 37:00 37:06 37-12 37:18 37:24 37-30 37-36
TiletT980152 tl-563 Acq:6-JlUT-98 15:20:28 EI+ Voltage SIX TOT Noise: 70
425.7737 r>4 BSDB(256,30r-3.0) PXD( 7,5, 3, 0. 05\, 280.0, 1.00\,TtT) Xxp:SDB5US
TRIANGLE LABS Teit-.TLIt 44376 TLI XAD BLANK UKT. TIME - 15:23
O.OEO
Ida,
100*
80.
60.
40.
20.
A1.Q1X4
A9.87EJ
.2.7E3
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LO.OEO
Tia<
80.
60.
40.
20.
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-6.8E5
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36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30 37:36
rile:T980152 tl-563 Acq:6-JKN-98 15:20:28 EI+ Voltage SIX 70T Noiae:213
437.8140 T:4 3SUB(256, 30, -3. 0) PKD(7,5,3, 0. 05*, 852. 0,1. 00\,T, T) Exp-.NDBSUS
TRIANGLE LABS Teit:TLI»44376 TLI XAD BLANK TNJ. TIME - 15:23
lOOi A7.48E6
80.
60.
40.
20.
.O.OEO
Time
0.
36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30 37:36
rile:T980152 tl-563 Adj:6-JJOT-98 15:20:28 EI+ Voltage SIR 70T
430.9729 T-.4 ExptNDBSUS
TRIANGLE LABS Toit-.TI.H44376 TLI XAD BLANK INJ. TIME - 15:23
1004
80.
60.
40.
20.
0.
36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30 37:36
.1. 7E6
.1. 4E6
.1. OE6
.6.9E5
.3.5ES
.O.OEO
Time
.5.9E6
.4.7E6
.3.SE6
.2.4E6
,1.2X6
O.OEO
Time
64
-------
rila:T980lS3 »i-$63 Acq:6'-JAN-98 13:30:38 EI+ Voltage SIR 70T Soim«i366
441.7438 F:4 BSUB(356,30, -3. 0) PXD(7,5,3, 0. 05\,1064. 0,1 .OQ\,r,T) XrpiXDBSUS
TRIANGLE LABS Text:TLI*44376 TLI XAD BLAHX JJKT. TIME - 15:33
IOOA
901
SO.
701
so
401
A1.94E4
.OOE4
15X3
.tAjrtJMlU
36:00 37': 00 38:00 39:00 40:00
File:T9a0153 tl-563 Ac
-------
rU.aiT3UUJ.5J tl-563 Acq16-JAN-*U 15120:Jo Sl-f Voltage SIX 701 lfoiae:198
457.7377 fi4 BSVB(256, 30, -3. 0) PXH( 7,5, 3, 0.05%, 793.0, 1.00\,T,T) ExptSDBSUS
TRIANGLE LABS TexttTLIt44376 TLI XAD BLAXK HU. HUE - iSi23
1001 A4.07E4
80.
SO.
40.
20.
A69S.96
40:54 41:00 41:06 41:12 41ilB 41:24
rileiT980152 tl-563 Acq:6-JAK-9a 15:20t28 SI+ Voltage SIX 70T BOiaeiS7
459.7348 Tt4 BSUB(256,30, -3.0) PKD(7,5,3,0.051,228.0,1.00\,T,T) XxptSDBSUS
TRIANGLE LASS Teit:TLH44376 TLI XAD BLANK BET. TIME - 15:23
1004 A3.59E4
-.1.1X4
'.8.SE3
.6.3E3
-4.2E3
'.2.1X3
.0.0*0
41:30 Tia.
41:24
40:54 41:00 41:06 41:12 41': 13
rile:T980152 #1-563 Acg:6-JAIf-9a 15:20:28 EI+ Voltage SIX 70T Soiae:49
469.7779 F:4 BSUB(2S6,30, -3. 0) PKD(7,5,3, 0. 05\,196. 0,1. 00\,T, T) Exp:NDB5US
TRIANGLE LABS Text:TLIf 44376 TLI XAD BLANK XK7. TIME - 15:23
A1.UE7
80.
60.
40.
20.
.1. 6E3
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40': 54 41:00 41:06 41:12 41:18
rila:T980152 tl-563 Acq:6-JAN-98 15:20:28 EI+ Voltage SIX 70T Stiiae:50
471.7750 T:4 BSOB(2S6, 30, -3. 0) PKD(7, 5,3, 0.051,200.0,1.00\,f,T) Exp:mB5US
TRIANGLE LABS Text:TLH44376 TLI XAD BLANK X2K7. TIME - 15:23
1001 A1.21E7
80.
60.
.O.OEO
41': 30 Tiae
40.
20.
40': 54 41:00 41:06 41:12 41:18
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430.9729 T:4 ExpiUDBSUS
TRIANGLE LABS TejctsTLH44376 TLI XAD BLANK HO. TIME -
1001 41:00
-------
|-U..-.| T :*3 •I'TQO Dj.l. t,.
liisfc!. i aws.w X rSa\ icp
Hsioht 3,59'JOlL- Span 298 ppa
S^st&a fiis nae
Data file res f):
Resolution
Gro^nuater 2
lonizaticn sode £1"
Syitching VOLIRGE
tef, aasses 292.S8E5, 416,3768
j 331
K 332
L 334
ft 348
N 342
0 &
P 354
Q 356
R 358
S
T 379
U 376
V 418
Ref, wss 416,3768 Peak top
Heicht ,26 volts Span 288 jp
-------
i'TS 80152 #1-563 Acq:6-JAN-9& 15:20:28 El+lteltage SIR ?OT
457.7377 F:4 Exp:NDB5US
lample Text :TLI #44376 TLI XAD BLANK
lOOi
60 j
40J
20 j
0
INJ. TIME - 15:23 File Text:TLI#44376 TLI»
A3.54E4 _1.1E4
_8.8E3
_6.6E3
_4.4E3
L2.2E3
LO.OEO
Time
39:00 40:00 41:00
File:T980152 #1-563 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70T
459.7348 F:4 Exp:NDB5US
Sample Text:TLI#44376 TLI XAD BLANK INJ. TIME = 15:23 File Text:TLI#44376 TLI»
100S. A3.30E4 _8.5E3
60J
40j
20 j
OJ
_6.8E3
_5.1E3
L3.4E3
L1.7E3
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-i 1 1 1 1 1 1 1 1 r
39:00 40:00 41:00 Time
File:T980152 #1-563 Acq:6-JAN-98 15:20:28 EI+ Voltage SIR 70T
469.7779 F:4 Exp:NDB5US
Sample Text:TLI#44376 TLI XAD BLANK
100%
80j
60J
40j
20 j
INJ. TIME =
40:55
O
39!00
40:00
41:00
15:23 File Text:TLI#44376 TLI»
_2.0E6
L1.6E6
L1.2E6
L7.8E5
L3.9E5
LO.OEO
Time
CO
-------
TLI Project: 44376 Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: TLI XAD BLANK Analysis File: X980083
Client Project: Gulp Aluminum Alloys
Sample Matrix: XAD Date Received: / / Spike File:
TLI ID: TLI Blank Date Extracted: 12/29/97 ICal:
Date Analyzed: 01/07/98 ConCal:
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a % Moisture
Blank File: X980083 % Lipid:
Analyst: KAS % Solids:
SPC2NF04
XF24087
X980080
: n/a
n/a
n/a
'Anafcte* \ , ' * '
2^,7,8-TCDF
Internal Standard
13C,2-2,3,7,8-TCDF
Recovery Standard
k'T,j-lA3,4-TCDD
Amt(rig> >^JDt^ :EMPCXvSn,:5fc*fcV ,
0.02 0.69
AitiL (ng> :: % Recovery QC Limits; - Ratio
2.9 73.0 40%-130% 0.79
Ratio
0.78
8T
*
21:29
m
21:28
8T
20:29
Flags
—
Flags
—
Flags
Data Reviewer..
01/11/98
Page 1 of 1
C2NF.PSR fiOl. LARS 4.10.09
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:32 01/11/98
69
-------
Data Review By:
Initial
£*?/
Date...
!_£. Calculated Noise Area: 4.36
The Total Area for each peak with an ion abundance ratio outside
ratio, limits has been recalculated according to method requirements.
Page Mo.
01/11/98
Listing of X980083B.db£
Matched GC Peaks / Ratio / Rat. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306 DC
DC
DC
DC
DC
DC
DC
' DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
304-30$
13C12-TCDF
316-318 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
2
NL
WL
WL
WL
WL
WL
SN
SN
SN
SN
WH
0
17
17
17
18
18
18
19
19
19
19
19
19
20
20
20
21
21
21
22
22
22
22
23
23
23
:00
:06
:33
:37
:07
:S4
:S8
:08
:13
:23
:30
:44
:58
:11
:41
:52
:29
:37
:55
:01
:1S
:24
:42
:20
:27
:51
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65-0.89
0.24
1.76
1.
35
1.15
1.
0.
1.
2.
0.
0.
0.
0.
2.
0.
1.
0.
0.
0.
4.
0.
3.
0.
0.
2.
0.
1.
05
72
15
06
77
36
96
62
00
80
41
48
69
21
18
44
08
72
43
05
27
66
Peaks
0
17
18
19
20
20
21
21
21
21
22
22
22
22
:00
:29
:29
:45
:09
:25
:28
:43
:47
:S3
:00
:06
:24
:34
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-
1.
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
2.
6.
0.39
16
00
82
69
60
79
79
43
01
28
61
81
30
56
1
2
1
1
6
4
5
2
8
4
3
8
0
29
2
2
33
2
2
9
0
3
4
4
0
2
62
.82
.05
.72
.96
.76
.19
.01
.32
.82
.53
.40
.02
.62
.42 13.10
.48
.28
.30 13.60
.67
.35
.75
.85
.14
.11
.67
.71
.74
.72
0.790-1.095
0
0
0
0
0
0
0
0
0
0
0
0
0
16.32 0
0
0
19.70 1
1
1
1
1
1
1
1
1
1
.000
.797
.818
.821
.844
.880
.884
.891
.895
.903
.908
.919
.930
.940
.964
.972
.001 2378-TCDP AN
.007
.021 • .
.026
.036
.043
.057
.087
.092
.111
0.953-1.047
6,
4.
4.
20,
.05
.02
.99
,42
54.13
311.
,01
6,671.69 2,943.01
16.09 7.00
9.
6.
.31
,78
26.69 11.61
5.
8.
,59
.66
5.49
0,
0.
0.
0.
.000
.814
.861
,920
0.939
0.
3,728.68 1.
16.44 1.
1.
1.
19.04 1.
1.
951
000 13C12-2378-TCDP ISO
012
015
019
025
030
1.043
1.
051
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:17 01/11/98
70
-------
Page No. 2 Listing of X980083B.dbf
01/11/98 Matched CC Peaks / Ratio / Ret. Time
Compound/
X.Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.
1.065
1.078
1.084
1.093
1.106
1.109
316-318
DC
DC
DC
DC
DC
DC
WH
WH
WH
WH
WH
WH
3
22:52
23:08
23:16
23:28
23:44
23:48
Peaks
RO
RO
RO
RO
1.
3.
0.
0.
0.
2.
66
49
84
81
48
18
5
3
79
3
3
4
6,714
.12
.86
.28
.99
.56
.62
.47
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.89 0.901-1.099
332-334
DC
DC
DC
NL 0:00 RO
SN 19:53 RO
20:
20:
21:
SN 21:
21:
21:
12
29
08 RO
14
36 RO
58 RO
1.
1.
0.
0.
0.
0.
1.
1.
73
89
76
78
31
66
10
04
14
7
5,158
6,562
36
9
19
16
.85
.95
.35
.13
.32
.48
.88
.87
2,225.
2,866.
15.
12.
9.
85
51
80
32
94
2,932
3,695
50
11
9
.50
.62
.50
.23
.53
0.000
0.984
1.000
1.014
1.046
1.051
1.069
1.087
13C12-2378-TCDD IS1
014 13C12-1234-TCDD RSI
332-334 5 Peaks 11,793.55
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Tims Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below signal to Noise Level D-Peak Deleted
L C -RO=Raeio Outside Limits
-------
H-9B4 leg* /-JJLH-1S9B lS,33*Oy X SI* Volbmg* 3IX AutoSpmc Boi*»>39b
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T+rt:RS-100 film ToJCt: TRXANOLB LABS
17:00 IB': 00 19100 30,00 31'tOO 22'tOO 23tOO
Pll»,X9 80083 11-884 Aeqi 7-J3LS-1S98 IS,35109 OC SX+ Voltage SIR AataSpme Solt», 1655
305.8987 BSVB(256,30,-3.0) PXD(5,3,1. 0.10*, 6620.0. 0.00*,?.*) S3cp,KOKP_TT
Soaplt TvctiSS-100 fll» Texti TKULSOLS LABS
lOOil JL1.97S5
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A1.31S4
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315.9419 BSUB(256,30,-3.0) PXD(5,3, 1, 0.10*, 7960. 0, 0. 00*,P,P) Bxp>KOHP_TT
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100*
23:00
7.5E6
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Text! TRIANGLE LABS
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17:00 18:00 15:00 20:00
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-------
Peak Locate Examination: 7-JAN-1998:16:34 File:X980083
Experiment:XCONF_TT Function:! Reference:PFK
-------
TLI Project: 44376
Client Sample: 105-108
Cb 0
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T9801ffc
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-1A-1D Date Extracted: 12729/97
Date Analyzed: 01/06/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
2.5
10.2
3.4
4.5
7.4
5.4
3.2
'"EMPC 48.2,,'Tv
""" 52.7 " ^*
67.9 ,/tffiy
42.9 .
19.7
12.3
0.68
11.7
1.4
1.7
175 13
469- > 2.0 9 265- 720
103 7
11.0 2
19W- -?-f 16 1260- ?i
5*T 7 Zo 15 795- >J2o
309 7 1o 12 5W > 2c?
15.3 3 19.2 rf^
0.78
1.54
1.24
1.24
1.22
1.01
0.82
1.44
1.47
1.26
1.26
1.26
1.33
1.03
1.09
0.92
26:22
30:34
33:37
33:42
34:01
37:05
40:56
29:32
30:14
32:54
33:00
33:31
34:18
36:00
37:37
41:09
i|||i|s||
oZ
QPR
SE_
E_
E_
E_
PR_
E_
SE_
QE_
SQE
SE
SE_
X_
Page 1 of 2
X237.PSR V2.01. LARS 6.10.3
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09^54)1/15/98
(b
-------
JLI Project: 44376
I'lient Sample: 105-108
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980153
Internal Standards
I3C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
I3Ci2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13Cn- 1,2,3 ,4,6,7,8-HpCDD
13C,-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
"CL^JJ.S-TCDD
l3C,:-2,3,4,7,8-PeCDF
13C,-l,2,3.4,7,8-HxCDF
l3Cp- 1,2.3,4, 7,8-HxCDD
13Cr-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A>
'3C,2-l,2,3,7,8,9-HxCDF
13C,:-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,:-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt (ng)
1.7
2.7
2.9
3.3
2.9
2.2
3.1
4.1
8.8
AmL (ng)
3.7
4.0
3.8
6.3
4.0
Amt. (ng)
3.0
2.8
% Recovery
43.0
68.7
73.6
83.3
71.7
54.3
77.0
102
110
% Recovery
92.6
99.6
94.4
158
101
% Recovery
76.1
70.4
QC Limits
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
25%- 130%
25%-130%
25%- 130%
QC Limits
70%- 140%
70%-140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40% -130%
40%- 130%
Ratio
0.79
0.80
1.52
1.49
0.51
1.18
0.45
1.01
0.92
Ratio
1.52
0.53
1.19
0:44
Ratio
0.52
0.51
Ratio
0.81
1.17
RT
25:42
26:21
29:31
30:33
32:59
33:42
35:59
37:05
40:55
RT
26:22
30:13
32:53
33:36
37:36
RT
34:18
33:30
RT
26:10
34:01
Hags
Q
Q~
—
Flags
—
Q
Flags
—
Flags
—
Data Reviewer.
01/15/98
Page 2 of 2
X237.PSR v2.0l. LARS «.lO.OSo
Triangle Laboratories, \nc.s
801 Caprtola Drive • Durham, North Carolina 27T13
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98
-------
Initial .'. . .Date. . .
_L/ilZ./£j. Calculated Noise Area:
Data Review By:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
2.00
Page No.
01/15/98
Listing of T980153B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z...; QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306 DC NL 0:00
22:40
23:08
23:21
23:43
24:01
24:25
24:41
24:53
25:06
25:17
25:31
25:43
26:06
26:18
26:33
26:50
27:22
27:35
304-306 18 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 22:40
DC WL 23:08
DC WL 23:21
DC, WL 23:29
DC WL 23:43
DC WL 24:04
DC WL 24:25
DC WL 24:41
24:53
25:30
25:42
26:06
26:18
DC WH 27:05
DC WH 27:35
316-318 5 Peaks
0
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65-0.89
2.35
0.80
0.31
0.31
0.36
0.30
0.33
0.90
0.82
0.35
0.31
0.30
0.95
0.37
0. 80
0.81
0. 82
0.80
0.79
65-0.39
1.74
2.44
4.43
2.21
1.39
2.54
1.47
2.21
1.77
2.07
1.09
0.79
1.56
1.34
2.35
1.38
0.378-1.073
19
24
24
113
73
83
61
97
63
42
40
63
50
40
7
4
1
813
2.35
,730.66
,624.80
,162.70
,145.70
,975.10
,824.10
,582.73
,515.10
,400.70
,153.30
,473.10
,393.44
,651.20
,702.10
,508.21
311.61
,713.17
,265.07
,137.79
8
11
10
52
32
38
31
43
29
18
13
34
23
13
3
2
,772.36
,028.30
,792.50
,377.40
,989.90
,058.50
,292.20
.928.30
,183.50
,822.30
,010.30
,073.50
,585.80
,132.20
,369.53
140.53
,095.99
559 . 87
10
13
13
60
40
45
34
53
34
23
22
35
27
22
4
2
,958.30
,596.50
,370.20
,768.30
,985.20
.765.60
,792.50
,586.30
,217.20
,336.00
.462.30
,815.50
,065.40
,569.90
.138.63
171.08
,617.18
705.20
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1,
1.
0.961-
1,
2,
3.45
8.92
10.51
11.03
20.07
51.35
77.81
44.98
49 .42
60.94
69.61
.384.36
42.14
. 45.17
7.65
10.96
,102.72
71.16
43.01
833.89
37.15
34.21
1,
34.43
39.33
050.97
23. «1
25.52
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
.000
.382
.900
.909
.923
.935
.950
.960
.963
.977
.984
.993
.001 2373-TCDF AN
.016
.023
.033
.044
.065
.073
-1.039
,000
382
900
909
914
923
936
950
960
963
992
000 13C12-2378-TCDF ISO
016
023
054
073
QZ
QE
QE
QSE
QE
QSE
QSE
QSE
QSE
QE
QE
' SE
QSE
QE
QE
Q
Q
Q
Q
Above: TCDF / TCDD Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98;
78
-------
Page No.
01/15/98
Listing of T980153B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why
TCDD
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.65-0.89
0.903-1.045
320-322
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
DC NL 0:
23:
24:
24:
25:
25:
25:
26:
26:
26:
26:
26:
26:
27:
00
55
17
34
13
29
52
10
16
22
31
40
53
20
RO 1
0,
0.
0,
0.
0,
0,
0,
0.
0.
0,
0.
0.
0.
.14
.78
.77
.78
.78
.78
.77
,78
,78
,78
.78
,78
78
79
13 Peaks
3
32.139
21,103
9,007
22,731
16,407
8,655
8,081
14,079
2,106
3,636
4,020
1,243
1,217
144,429
.35
.20
.15
.22
.36
.17
.50
.92
.57
.34
.36
.79
.23
.05
.86
14,123
9.188
3,953
9,964
7,203
3,773
3,543
6,179
925
1,595
1,760
546
536
.50
.25
.61
.66
.11
.35
.83
.31
.35
.40
.69
.45
.26
18,015
11,914
5,053
12,767
9,204
4,382
4,538
7,900
1,131
2,040
2,260
696
630
.70
.90
.61
.20
.06
.15
.09
.26
.49
.96
.10
'.78
.79
0.000
0.908
0.922
0.932
0.957
0.967
0.982
0.993
0.997
1.001 2378-TCDD AN
1.006
1.012
1.020
1.037
0.924-1.076
DC NL 0:
DC WL 23:
DC WL 24:
DC WL 24:
24:
25:
25:
25:
25:
25:
' 26:
26:
26:
26:
27:
27:
27:
27:
00
55
09
17
34
01
13
29
45
52
09
22
31
43
20
32
37
43
14 Peaks
DC NL 0:
' 25:
26:
26:
26:
00
14
10
21
40
0.65-
RO 1.
RO 0.
0.
0.
RO 0.
4 Peaks
DC NL 0:
27:
27:
00
35
51
1.32-
RO 1.
RO 1.
1.
0.89
98
95
81
30
61
3
166
531
287
66
3,263
128
90
32
63.
55.
2,262
77.
5,311.
7.
10.
7.
10.
11,399.
.44
.71
.24
.35
.98
.57
.58
.03
.21
.21
.77
.40
.49
.12
.39
93
,97
92
07
66
3,263
128
90
32
68
55
2,262
77
5,311
7,
10,
7
10.
.93
.57
.53 '
.03
.21
. 21
.77
.40
.49
.12
.39
.93
.97
.92
0.000
0.903
.0.917
0.922
0.932
0. 949
0.957
0.967
0.977
0.982
0.992
1.001 37C1-TCDD SUR1
1.006
1.014
1.037
1.045
1.048
1.052
0.924-1.076
5.
18.
2,334.
2.428.
34.
73
30
11
19
41
5,315.01
1.78
20
12
43
2.
53,788.
1,540.
62
38
23
9.
1,264.
1,080.
14.
81
87
05
97
10.
1,569.
1,348.
24.
34
24
14
42
0.000
0.958
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.012
tf^Tflf F/-4 1 1 rtf It-
32,694.
906.
90
51
29,186.
633.
0.931-1.063
10
72
0.000
0.935
0.944
SE
Triangle Laboratories, Inc.® Analytical Services Division
801 Caphola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98
79
-------
Page No. 3
01/15/98
Compound/
M_2.... QC.Log Omit Why
Listing of T980153B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
28
28
28
28
28
29
29
29
29
29
29
29
30
30
30
30
30
3.1
DC •' WH 31
:01
:11
:33
:41
:51
:04
:09
:14
:26
:32
:40
:48
:05
:14
:25
:42
:52
:09
:36
RO
RO
RO
RO
1.25
1.08
1.40
1.07
1.38
1.48
1.34
1.20
1.47
1.44
1.48
1.47
1.38
1.47
1.50
1.50
1.48
1.49
1.46
20 Peaks
DC NL 0
27:
DC SN 27:
DC SN 28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
30:
DC SN 30:
DC SN 31:
31:
31:
:00
:35
:43
:11
:33
41
51
:09
15
31
40
47
56
.13
24
53
00
08
26
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
14 Peaks
DC NL 0:
28:
29:
29:
29:
29:
00
43
14
29
36
48
1.
RO
RO
.32-1.78
1.16
2.63
1.28
0.64
2.06
2.56
1.17
2.57
2.23
1.52
1.90
1.65
1.04
1.52
2.40
2.29
1.14
2.26
0.75
450.39
1.691.39
41,266.30
76,271.82
46,254.00
15,887.94
42,450.40
48,347.34
27,964.40
37,339.20
31,383.90
40,938.10
624.32
48,078.00
41,831.30
2.439.53
1,657.17
3,560.26
54.94
563,765.37
1
24
46
26
9
24
29
16
22
18
24
28
25
1
2
274.07
.028.10
,037.00
,361.30
,837.20
,473.38
,300.60
,387.60
,650.70
,006.40
,715.70
,362.30
361.81
,588.90
,071.20
,464.09
988.45
,128.34
218
952
17,229
43.312
19,416
6.414
18.149
24.530
11,313
15,332
12,668
16,575
263
19,489
16,760
975
663
1,431
.42
.37
.30
.90
.80
.56
.30
.40
.70
.80
.20
.80
.01
.10
.10
.44
.72
.42
0.949
0.955
0.967
0.972
0.977
0.985
0.988
0.990
0.997
1.001 12378-PeCDF
1.005
1.010
1.019
1.024 23478-PeCDF
1.030
1.040
1.046
1.055
1.071
SE
SE
SE
SE
SE
AN E
E
E
AN E
E
Q
0.364-1.136
1.22
50.64
4.69
2.43
28.69
, 130.66
63.32
24V58
44.47
2,670.35
43.76
62.73
5.54
2.641.13
37.54
2.52
3.47
9.77
4.41
' 5,818.14
32-1.78
1.02
1.22
1.55
1.54
1.52
1.55
2.07
49,412.09
4,801.07
29,982.10
7,403.47
20,654.24
1
1,
52.25
23.18
131.00
38.49
24.77
38.39
,609.42
32.58
39.05
3.37
,593.71
35.23
8.64
2.63
19.36
11.25
51.24
32.36
9.
17.
1.061.
17.
23.
3.
1,047.
14.
3.
3.
64
44
43
16
73
23
42
72
33
56
0.000
0.935
0.939
0.955
0.967
0.972
0.977
0.988
0.991
1.000 13C12-PeCDF 123
1.005
1.009
1.014
1.024 13C12-PeCDF 234
1.030
1.046
1.050
1.055
1.065 .
152
SUR2
>^*nn i?rti i CMJO
30,
2,
18.
4,
12,
034.30
916.34
191.90
468.33
560.60
24,660.
1.384.
11,790.
2,935.
8,093.
0.939-1.022
70
73
20
14
64
0.000
0.943
0.957
0.965
0.969
0.975
SE
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98
80
-------
Page No.
01/15/98
Listing of T980153B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
A
356-358
13C12-PeCDD
368-370
363-370
HXCDF
374-376
X
AX
M
MX
AN
M
374-376
13C12-HXCDF
384-386
30
30
30
30
30
30
:03
:16
:26 RO
:34
:39
:59
1.55
1.58
0.34
1.54
1.55
1.52
11 Peaks
DC NL 0
28
29
29
29
29
DC SN 30:
30:
DC SN 30:
30:
DC SN 30:
31:
DC SN 31:
1
:00 RO
:47 RO
:09 RO
:15 RO
:29 RO
:48 RO
:02 RO
:14 RO
:22 RO
:33
: 53 RO
00 RO
32 RO
8 Peaks
DC NL 0:
31 =
32:
32:
32:
32:
X 32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:
1.
00 RO
57
05
14
22
31'
44 RO
54
00
07
19
26 RO
31 .
14 RO
13
23
47
.32-1.78
1.20
3.01
1.27
1.09
2.10
1.89
4.05
. 2.27
1.92
1.49
5.33
1.29
1.29
12
6
2
5
1
2
143
1
,393.62
,754.91
,615.81
,536.05
,245.36
,525.97
,425.19
0.99
43.73
8.24
7.04
27.57
14.33
6.04
11.55
4.32
.675.27
1.40
5.53
2.98
1,793.26
Ai^ove • PcCDD / H>
05-1.43
1.48
1.26
1.13
1.23
1.24
1.28
1.30
1.26
1.26
1.27
1.24
1.27
1.26
1.23
1.33
1.26
1.27
15 Peaks
DC NL 0:
31:
32:
DC SN 32:
32:
0.
00 RO
56 RO
05 RO
22 RO
S3
43-0.59
1.05
2.06
1.61
3.27
0.53
17,
45,
3,
4,
3,
27,
14,
2,
4,
7.,
1,
1,
133,
133.15
,101.55
,449.20 •
709.53
903 .93
149.19
698.40
385.20
162.63
616.76
266.03
621.00
080.00
155.00
363.00
324.00
302.92
990.52
7,531
4,140
1,590
3,359
756
1,585
51
5
4
22
10
10
1,001
3
r(~T^TT T?i-» 1 1 e
t>— L>±* r Oi .1 <
9, 543.
24,603.
2,044.
2,714.
1,765.
394.
15,260.
7,899.
1,465.
2 , 365 .
347.
3,950.
537.
210.
738.
.10
.58
.00
.42
.37
.56
.67
.01
.28
.68
•54.
.27
.12
.36
13
90
94
S3
64
48
60
76
07
57
00
00
00
00
00
4,362
2,614
1,890
2,176
489
1,040
17
3
3
10
5
4
674
2
.52
.33
.00
.63
.49
.41
0.
.15
.93
.94
.31
.62
.53
.15
.61
0.984
0.991
0.996
1.001 12378-PeCDD AN
1.003
1.014
869-1.131
0.000
0.942
0.954
0.957
0.965
0.975
0.983
0.990
0.994
1.000 13Cl2-PeCDD 123 IS3
1.011
1.015
1.032
a
0.964-1.049
7,553.
20,345.
1,664.
2,189 .
1,333.
303.
12,124.
6,262.
1,151.
1,900.
274.
3,130.
513.
153.
586.
,52
30
59
30
55
92
60
37
69
46
00
00
00
00
00
0.000
0.969
0.973
0.977
0.981
0.986
0.992
0.997 123473-HxCDF AN
1.001 123678-HXCDF AN
1.004 •
1.010
1.014
1.016 234678-HxCDF AN
1.038
1.040 123789-HxCDF AN
1.042
1.055
SE
E
PR
0.879-1.121
1,
4.58
8.37
26.67
1.45
923.59
11.
•' 28.
663.
40
51
31
5.
17.
1,255.
54
66
23
0.000
0.968
0.973
0.981
0.997 13C12-HXCDF 478 SUR3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98
81
-------
Page No. 5
01/15/98
Compound/
M_2.... QC.Log Omit Why
Listing of T980153B.dbf
Hatched GC Peaks / Ratio / Ret. Tinw
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
32:59
33:30
DC SN 33:46
DC SN 34:02
34:18
DC SN 34:30
6 Peaks
RO
RO
RO
0.51
0.51
0.33
3.55
0.52
0.22
2,213
2,072
2
0
1,773
4
8,017
.12
.07
.40
.63
.53
.62
.35
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
X
D
D
408-410
13C12-HpCDF
418-420
418-420
DC NL 0:00
32:25
32:52
33:05
33:16
33:37-
33:42
34:01
7 Peaks
DC NL 0:00
33:04
DC SN 33:16
33:36
33:42
34:01
34:11
5 Peaks
DC NL 0:00
36:00
X 36:16
36:26
D NH 37:06
D NH 37:21
37:37
DC WH 38:11
4 Peaks
DC NL 0:00
35:59
DC SN 36:26
37:36
DC SN 37:59
2 Peaks
1
RO
1.
RO
RO
RO
RO
0.
RO
RO
RO
RO
0.
RO
RO
.05-1.43
0.77
1.22
1.21
1.22
1.25
1.24
1.24
1.22
05-1.43
2.14
1.50
2.64
1.19
1.18
1.17
0.78
38-1.20
1.26
1.03
1.08
1.05
1.42
1.67
1.09
1.10
37-0.51
1.07
0.45
1.73
0.44
0.48
8
4,697
11,857
7,632
807
876
1,334
2,187
29,393
.74
.62
.20
.77
.28
.15
.98
.27
.27
751
701
606
.65
.34
.72
1,461
1,370
1,166
.47
.23
.31
1.000 13C12-HXCDF 678 IS4
1.016 13C12-HXCDF 234 ALT2
1.024
1.032
1.040 13C12-HXCDF 789 ALT1
1.046
"COD Frtl 1 rtu/c — _
2,584
6,494
4,187
447
484
737
1.204
.90
.05
.41
.92
.37
.95
.00
2,112
5,363
3,445
359
391
597
983
0.958-1.015
.72
.15
.36
.36
.78
.03
.27
0.000
0.962
0.975
0.982
0.987
0.998 123478-HxCDD AN
1.000 123678-HxCDD AN
1.009 123789-HXCDD AN
Q
OE
Q
Q
Q
QPR
0.970-1.030
3
14
5
1,513
1,134
2,185
10
4,913
• Mvr* n r
.81
.56
.04
.94
.11
.31
.31
.23
"\ / LJv*i
9
823
640
1,177
5
.76
.86
.10
.94
.71
6.
695.
544.
1,007.
7.
.50
.08
.01
.37
.35
0.000
0.981
0.987
0.997 13C12-HXCDD 478 SCJR4
1.000 13C12-HXCDD 578 IS5
1.009 13C12-HXCDD 789 RS2
1.014
Q
Q
f T>^ 1?— 1 1 _..._
6.
6,463.
1,911.
1.049.
15.
14.
582.
.34.
10,012.
43
11
71
37
22
93
52
48
21
3,287.
.09
990.63
536.57
303.
26
3,181.
921.
513.
' 279.
0.998-1.053
02
08
30
26
0.000
1.000 1234678-HpCDF AN
1.008
1.013
1.031
1.038
1.045 -1234789-HpCDF AN
1.061
0.944-1.111
1.
1,499.
1.
1,176.
2.
2,675.
34
56
51
39
72
95
463.
360.
35
30
1,031.
815.
21
59
0.000
1.000 13C12-HpCDF 678 IS6
1.013
1.045 13C12-HpCDF 789 SUR5
1.056
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98
82
-------
Page No.
01/15/93
Listing of T980153B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omic Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WH
2
NL
SN
SN
3
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
36
37
37
:00
:18
:05
:37
0,
RO
,38-1.20
1
0
1
1
.59
.99
.01
.19
Peaks
0
36
36
37
37
37
:00
:16
:38
:05
:23
:26
0.
RO
RO
,38
1
1
1
1
0
1
Peaks
0;
35:
35:
35:
36:
36:
36:
36:
36:
36:
37:
37:
37:
37:
37:
37:
33:
38:
38:
39:
39:
39:
39:
39:
39:
40:
40:
40:
41:
41:
41:
:00
: 16
:40
:46
02
:15
26
33
39
46
05
12
20
36
43
49
15
31
39
05
15
26
33
39
52
16
20
52
00
09
25
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
-1.20
.06
.22
.01
.01
.79
.17
1
2,335
2,247
6
4.583
.34
.78
.54
.39
.32
0.976-1.006
0
1,161.42 1.174.36 0
1.128.65 1,118.89 1
1
.000
.979
.000 1234678-HpCDD AN
.014
0.973-1.027
2
3
1
1,604
4
6
1,613
Uw/-m
.35
.08
.49
.33
.61
.15
.56
n / r\f
76-1.02
0
0
0
1
0
0
1
1
0
0
1
0
1
0
0
1
1.
1.
1,
o
0.
0.
3.
0.
0.
0.
0.
0.
1.
0.
0.
.96
.63
.42
.76
.30
.33
.12
.50
.53
.34
.21
.36
.11
.28
.26
.62
.67
.48
.07
.94
.79
.98
97
61
25
32
40
97
33
92
93
0
0
0
0
2
18
1
0
0
0
2
0
1.
0.
0.
0.
1.
1.
0.
49.
1.
0.
0.
1.
0.
0.
0.
1.
1.
715.
57.
.38
.64
.72
.64
.21
.47
.08
.72 .
.45
.93
.66
.91
.53
34
47
55
10
66
55 '
16
00
99
55
40
53
39
96
14
53
06
23
0
4.33 3.96 0
0
807.10 797.23 1
1
3.32 2.83 1
.000
.978
.988
.000 13C12-HpCDD 673 IS7
.008
.009
0.902-1.098
0
0
0
0
0
0
0
0'
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
23.82 25.34 0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
343.02 372.04 1.
27.60 29.63 1.
.000
.362
.372
.374
. 381
.886
.390
,393
.396
399
906
909
912
919
922
92-1
935
941
945
955
959
964
967
969
974
934
986
999
002
006 OCDF AN
012
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:25 01/15/98
83
-------
Page No.
01/15/98
Listing of T980153B.dbf
Hatched GC P«aks / Ratio
/ Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.
Flags.
442-444
DC SN 41:39 RO 0.61
DC SN 41:50 RO 0.49
DC SN 41:56 0.76
. 3 Peaks
2.06
2.51
1.37
821.45
1.018
1.022
1.025
OCDD
458-460
458-460
0.76-1.02
DC NL 0:00 RO 0.73 . 0.34
40:56 0.82 1,055.02
DC SN 41:16 RO 1.29 3.57
DC SN 41:30 RO 0.68 2.48
1 Peak 1,055.02
476.03
0.902-1.098
0.000
578.99 1.000 OCDD
1.009
1.014
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.29 0.26
40:55 0.92 2.360.58
470-472. 1 Peak 2,360.58
1,131.89
0.998-1.006
0.000
1.228.59 1.000 13C12-OCDD
I S3
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rai.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*** End of Report **"
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
riJ.e:T980153 #1-8.10 Acq:6-J3Uf-98 L6sOSs09 EI+ Voltage SIS 701 NO±3fsl895
303.9016 T:2 BSUB(2S6, 30, -3. 0) PKD(9,5,5, 0. 05\, 7580.0,1. 00\,T,T) XxptNDBSOS
TSIANGLE LASS Text:TLI#44376 105-108 fcxT. TIME - 16:09
1001
80:
sol
40:
20:
OJ
A5.24EB
1E8
A1.10E8
23:00
24': 00
25:00
File:T980153 #1-810 Acq:6-J7UT-98 16:06:09 XI+ Voltage SIR 70JT Abide.-665
305.8987 r:2 BSUB(256,30,-3.0) PXD(9,5,5,0.051,2660.0,1.00\,
TSIANGZE LASS Text:TLIt44376 105-108
100}
80:
60:
40:
20:
ol
A6. Q.8X8
A4.10E8
A1.36E8
A3.t8Z8A3.42E8
A3.
1.81E8
A2.10S7
/\ __
26: 00
27:00
f,T) Sxp:XDBSVS
|HK7. TIME - 161 09
8E8
2.26E8
\4.14E7
A2.62E7
A _
23': 00 24:00 . 25': 00 I 2^1-00 27:00
rile:T980153 #1-810 Acq: 6-J3UT-98 16:06:09 EH- Voltage SIS 70? Noise: 1700
315.9419 F:2 BSUS(256, 30, -3. 0) PKD(9, 5,5, 0. 05%, 6800. 0,1. 00\,f,T) Ezp-.NDBSUS
TRIANGLE LABS Text:TLI#44376 105-108 fo*7. TIKE - 16:09
1003* A8.?4E6
80:.
60:
40:
20:
o:
23': 00 ' 24':00 25:00
F±la:TS80153 #1-310 Acq: 6-JAN-98 16:06:09 EI+ Voltage SIS 7(
317.9339 F:2 BSUS(256,30,-3 .0) PKD(9,5,5, 0. 05%, 3892. 0,1. 00%
TRIANGLE LABS Text:TLI#44376 105-108
1004
80:
60:
40:
20:
26:00
IT Noise:973
T) Exp:NDB5US
INJ-. TIME ' 16:09
\SE7
27:00
23': 00
24': 00
25': 00
File:T980153 #1-810 Acq: 6-JKK-98 16:06:09 EH- Voltage SIR 7
330.9792 F:2 Exp:NDB5US
TRIANGLE LABS Text-.TLIt44376 105-108
1004
aoj
23:36
24
23': 00 24:00 25:00
\File:T980153 #1-810 Acq:6'-JAN-98 16:06:09 EI+ Voltage SIS 7i
J75.8J54 F:2 Exp:NDB5aS
TSIANGLE LABS Tejct:TLIt44376 105-108
80:
60:
40:
20:
o:
26:00
INJ. TIME
25:53
27:00
16:09
26:47^05
-6.5E7
.3.9X7
12.6X7
'-.1.3X7
0.0X0
Tine
-6.5X7
'•.S.2E7
'•.3.9X7
•.2.6E7
•.1.3X7
O.OEO
Tiae
.2.3E6
.1.9E6
1. 4E6
,9. 3E5
4.6E5
.O.OEO
Time
3. OE6
2.4E6
1.8E6
1.2E6
5.9ES
O.OEO
Time
26:00
T
ZKT. TIME
16:09
27:00
27:00
».«
23 • 00
24:00
25': 00
26:00
27:00
85
-------
rile:T980153 #1-810 Acq:6-JAN-98 16:06:09 EI+ Voltage SIX 70T Soia*il079
319.8965 t:2 BSUB(256,30,-3.0) PKD(7,S, 3, 0.05\,4316
TRIANGLE LASS TextsTLIt44376 105-108
1001
30:
50J
20.:
ol
A
ft
1 A9.19X7
l\ A3. 96X7
1 A
. 0,1.00%,J-, T; ExpiNDBSOS
XX7. TOa - 16:09
A6.18X7
rJ.4I7
A3.95E7 \ A7.30E7 ^.77X7 l\
A / \ ^-A A/N/l U.7«*7
; v / v /v y V/ v /\ /IUAA ^ «•/«•
24:00 25:00 ' ' 25:00
.2.7X7
.2.0X7
.1 . 4X7
.6.8X6
'• 0 . OEO
27:00 ' ' ' ' ' Tiae
«Ia:r9S015J #1-810 Acq:6-JAN-98 16:06:09 XI* Voltage SIR 70T Noiae:943
321.8936 T:2 SSUB(256, 30, -3. 0) PXD(7,S, 3, 0. 05%, J772
TRIANGLE LABS Text:TLIf 44376 105-108
100]
so:
•
50J
',
40.:
201
o-
A
AJ..19E3
A Ai.2sra
11 A
0,1.00\,F,T) SxpiODBSUS
IIV. TIMS - 15:09
A7.90E7
A5.05E7 \ A9 30E7 A4.88S7 f\
l\ l\ A AX A
/N7 I A2.26X7
f\ U A A ^ *6-£ES
'24:00 25:00 ' ' 25:00
-4.3X7
.3.4X7
.2.6X7
.1 . 7X7
.8.6X6
O.OEO
' 27:00 Tiae
Wle:T980153 tl-810 Acq:6-JAN-98 16:06:09 EH- Voltage SIR 70T Noise: 3203
331.9368 T:2 BSUB(256, 30, -3. 0) PXD( 7,5, 3, 0. 051,12812. 0,1 . 00\,F,T) Xxp-.NDBSUS
TRIANGLE LABS Text:TLI*44376 105-108
1003
80:
50:
40:
20:
o:
:
INJ. TIME • 15:09
A1.2SE7
Wl . 08E7
ft
/ U I
241-00 ' 25: 00 ' ' 251-00
3.6X6
.2.9X6
'•.2.2X6
.1.4X6
.7 .2X5
O.OEO
27:00 Tiae
Wle. -T9 8 01 53 #1-810 Acq:6-JAN-98 16:06:09 El + Voltage SIR 70T Noise: 1619
333.9338 T:2 BSUB(2S6, 30, -3 .0) PKD(7,5, 3, 0. 05%, 5475.
TRIANGLE LABS Text:TLI»44376 105-108 '
1001
80.
50:
40:
20:
o:
1
'
0,1.00%,r, T) Exp:NDBSUS
INJ. TIME
A1.57E7
\A1 .35E7
1
j \i V
241-00 251-00 ' 25:00
16:09
4.4E6
.3.6E6
.2.7E6
.1 . 8E6
.8.9E5
O.OEO
27.' 00 Tiae
rile:T9S015J tl-810 Acq:6-JAN-98 16:06:09 Eli- Voltage SIR 70T Noiae:1719
327.8847 f:2 BSOB(256, 30, -3. 0) fJO>(7, 5,3,0 .05\, 6876.
TRIANGLE LABS Tejct:TLIf 44376 105-108
100A
80:
50:
40:
20:
0:
A3.27E7
•
'241-00 251-00 ' 2
rila:T980153 tl-810 Acq:6-JAN-98 16:06:09 EI+ Voltag
330.9792 F:2 XxptNDBSUS
TRIANGLE LABS Text:TLI»44376 105-108 |
1001
80:
50:
40:
20:
0-
0,1.00%,?, T) Exp:NDB5aS
INJ. TIME
AS
A2.26E7
I
yl-oo
a SJB 70T
INJ. TIME
' 16:09
11E7 ..1.5E7
I
.1.2X7
.9.2X6
.6.2X6
.3.1X6
O.OEO
27:00 ' Tiae
15:09
_^^2i^" 2^:49 25^21^^25:5^35^09 25.-J1 25^7 ^^05 ^?7f**_
^^-^ *^\/"" ^\^"^^^n^-^^J ^\ r \
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24:00 ' 25:00 ' ' 2
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\ \AI \J \
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_1 . 817
.1.517
.1.1*7
.7.JI5
.J.7I5
0.0X0
27:00 ' ' ' ' Tiae
86
-------
file:T980153 #1-810 Acq:6-J2UT-9S 16:06:09 XI+ Voltage SIS 70T Soiae: 793
339.8597 f:2 BSCTB(256,30,-3.0) tXD(7, 5,3,0.05\,3172.0,1.00\,r,T) XzptXDBSUS
TRIANGLE LASS Text:TLI*44376 105-108 XXJ. TIKE - 16:09
A2.20E8
100]
80:
50:
40:
20:
o:
A2.S6E8
A2.51X8
Al.
\ ^^
28:00 29:00 30:00
rila:T980153 #1-810 Acq:6-J3UT-98 16:06:09 XI* Voltage SIS 70T NOiae:663
341.3567 Ft2 BSOB(256, 30, -3.0) ?KD(7,5, 3, 0. 05\,2652. 0,1.00\,f,T) KxptNDBSUS
TRIANGLE LASS Text:TLH44376 105-108 HKT. TXNZ - 16
1003
sol
sol
40:
20:
oj
A4.3
A1.9SE8
I.68EB
28:00 29:00 30:00
File:T980153 #1-810 Acq:6-JZN-98 16:06:09 EI+ Voltage SIX 70T Noiae:372
351.9000 1:2 BSUB(256,30, -3. 0) ?KD(7,5,3,0.05\,1488.0,1.00\,T,T) Exp:NDBSUS
TRIANGLE LASS Text:TLI»44376 105-108 IJTJ. TIME ~ ISl-OS
[004 A1.61E7
ao- A1.59E7
50:
40:
20:
oi_^
A1.31S6
46S7 A2.13S7
Jl.-OO
09
Al.43E7
31:00
28:00 29:00 30:00
rile:T980153 #1-810 Acq: 6 -JAN- 9 8 16:06:09 EI+ Voltage SIS 70T Noiae:321
353.8970 P:2 BSU3(256, 30, -3. 0) PKD(7,S, 3, 0. 051,1284 . 0,1 . 00%, f, T) Exp:NDB5DS
TRIANGLE LABS Text:TLI#44376 105-108 TJVJ-. TIME ~
lOOi A1.Q6E7
31:00
.- OS
80:
50:
40:
20.
Al. 05E7
28:00 29:00 30:00
F±le:T980153 #1-810 Acq: 6-JAN-98 16:06:09 EI+ Voltage SIS 70T
330.9792 T:2 Eip-.NDBSOS
TRIANGLE LABS Text:TLI#44376 105-108 IHJ.
TIME
1003
80:
50:
20:
0:
27:38
28:00 29:00 30:00
Tile:T9801S3 #1-810 Acq-:5-J3UT-S8 16:06:09 XI+ Voltage SIS 70T
409.7974 T:2 Exp-.NDBSVS
TRIANGLE LABS Text:TLIf44376 105-108 JWJ. TIME -
1004
80:
50:
40:
20.
oj
JO.-IS
28:00
28:41
/
29:00
30:00
31:00
31 s 00
15: OS
31:11
31 s 00
6.3E7
.5.0X7
LJ.817
.2.5E7
,1.3X7
O.OEO
Tiae
-6.5E7
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.1.3E7
O.OEO
Tiae
C5.0E6
.4.0E6
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.1.OE6
O.OEO
Time
3.2E6
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-1.9E6
_1. JJST5
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Time
1. 8E7
ll.5E7
.1.1E7
'•.7.3E6
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Time
3. 1E5
12.515
:i.s«
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.6.2X4
.0.0X0
Tia«
87
-------
fU.a-.T9U01.5J #1-810 Acq: 6-JAN-yu ±6:06:09 SI+ Voltage SIS 70T Noiae:62B
355.8546 T:2 BSOB(256,30, -3.0) fXS(7,5,3, 0. 05\,2512.0,1.00\,r,T) XxptSDBSOS
TSIAKGLS LABS Tejct:TLIf44376 105-108 HC7. TIME - 15:09
1001
80.
28:48 25:00 23:12 29:24 29:36 29:48 30,00 30:12 30:24 30 36 30:48 31:00 31:12 31:24
rile:T980153 #1-810 Acq:6-J3UT-98 16:06:09 EI+ Voltage SIS 70T Ooije: 619
357.8516 T:2 BSUB(256r30, -3. 0) PKD(7,5,3, 0. 05\,2476.0,1.00\,r,T) SxptXDBSUS
TSIANSLE LABS Text:TLIi44376 105-108 ZMT. TIME - 15:09
1001 A2.47E8
80.
O.OEO
Tine
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24
rile:T980153 #1-810 Acq: 6-J7UT-98 16:06:09 EI+ Voltage SIS 70T Jfoiae:299
367.8949 T:2 BSUB(2S6, 30, -3. 0) PKD(7, 5,3, 0.051,1196. 0,1. 00\,r,T) Sip:tlDB5as
TRIANGLE LABS Text:TLI»44376 105-108 IKT. TIME » 15:09
1001 A1.00E7
80:
50:
40.
20.
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30i36 30:48 31:00 31:12 31:24
rile:T9B0153 #1-810 Acq:6-JJOT-98 16:06:09 EH- Voltage SIS 70T Ifoiae:252
369.8919 T:2 BSUB(256, 30,-3.0) PKD(7, 5,3, 0. 05%,1008. 0,1. 00\,T, T) Bxp:in)B5US
TXIANGLE LABS Text:TLI#44376 105-108 INJ. 1IME * 16:09
1001 A6.74Z6
so:
so:
40:
20:
o:
o.oso
Time
.4.0E6
.3.2E6
.2.4E6
.1. 6E6
.8.0E5
.O.OEO
Time
.2.7E6
2.2E6
-5.SE5
3123
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30,36 30:48 31:00 31:12 31:24
rile:T980153 tl-810 Acq:6-J3OT-98 16:06:09 EI+ Voltage SIS 70T
330.9792 T:2 Eip-.SDBSUS
TRIANGLE LABS Text:TLIf44376 105-108 IJTJ. TIME * 16:09
1001 28^57 29:12 29:24 ":43 30^01^30^12 30:24
so:
50:
40.
20:
o:
o.oro
Tine
28:48 25:00 29: 12 29:24 29:36 29:48 3o:00 30:12 3ot24 3o,36 30:48 31: 31:12 31:24
.1. 8X7
.1.4X7
.1.1X7
.7.1X5
.3.6E6
.O.OEO
Tiae
88
-------
File 0980153 #1-396 Acq:6-JAS-98 16:06:09 EI+ Voltage SIS 70T Koiae:43858
373.8208 T:3 BSUS(256,30, -3. 0) PXD(7,5,3,0.05\,175432.0,1.00\,T,T)
TRIANGLE LASS Text:TLI»44376 105-108 ZK7. TIME - 16:09
1005 A2.4.6X8
30.
601
40l
20:
Al.53X8
A9.54E
A3.71X7
A4.24E7
A3.37X7 A
33:00 33:00 34:00
rlle:T980153 fl-396 Acqs6-JAN-98 16:06:09 EI+ Voltage SIS 70T Boiae:29721
375.8178 T:3 BSUB(256, 30, -3. 0) PXD( 7,5, 3, 0. 051,118884.0,1. 00\,f,T) Exp-.XDBSVS
TSIANGLE LABS Teit:TLI#44376 105-108 ZKJ. TIME - 16:09
1004 A3. OSES
sol
60l
401
A7.56E
A3.19E7
/v y\ ^
A3.34E7
Al. 90E7 /\
32:00 33:00 34,00
F±le:T9a0153 fl-396 Acq:6-JTO?-98 16:06:09 EI+ Voltage SIS 70T Noiae: 1594
383.3639 T:3 BSUB(256, 30,-3 . 0 ) PXD(7,5, 3, 0. 05%, 6376.0,1.00\,F,T) Exp:NBB5US
TRIANGLE LABS Teit:TLI#44376 105-108 . HKT. TIKE • 16:09
1003
801
50J
401
201
0.
A7.52E6
A7.02E6
A6.07E6
32:00 33:00 34:00
File:T980153 #1-396 Acq: 6-JAIT-98 16:06:09 EI+ Voltage SIX 70T IToiae: 1514
385.8610 T:3 BSUB(256, 30, -3. 0) PKD(7,5,3, 0. 05%, 5055. 0,1. 00\,T, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 105-108 JKJ. TIME - 16:09
1003
SOJ
601
40.
201
0.
A1.46E7
ft
A1.37E7
A1.17E7
I I
33:00 33:00 34:00
rile:T980153 tl-396 Ac
-------
32:24 32:36 32:48 33:00 33:12 33:24 33:36 .33:48 34:00 34:12 34:24
rila:T980153 #1-396 Acq:6-JAN-98 16:06:09 EI+ Voltage SIS 70T No±ae:1821
401.8558 F:3 BSUB(256f 30, -3 . 0) PXX>(7, 5,3, 0. OS\, 7284. 0,1. 00%,T, T) Exp:NDB5BS
TSIANSLE LABS Text:TLI#44376 105-108 INJ. TIME - 16:09
riJ.a:T980T5J #1-196 Acq:6-JAH-!tO lt>:UO:UH KI+ Voltage SIS 70T Xoiaas2421
389.8156 F:3 BSOB(256,30, -3. 0) PXD(7,5,3, 0. 05\,9684.0,1.00\,r, T) Exp:SDBSas
TSIANGLS LABS Text:TLI#44376 105-108 ntj. TIME - 16:09
1004
80.
60.
40.
20.
A2.58E7
A
A4.19E7
7.31E6
32:24
32:36 32:48 33:00 33:12 33:24 33:36
rlle:T9B0153 #1-396 Acq:6-JJOT-98 16:06:09 EI+ Voltage SIS 70T .Joiaoi3153
391.8127 F:3 BSOB(256,30, -3. 0) PKD(7,5,3, 0. OS\,12612.0rl .OQ\,F,
A1.20E7
33:48
34:12
TSIANSLE LABS Tejct:TLI#44376 105-108
1004 A5.36E7
T) Exp:SDB5US
1X7. TIMS
16:09
80.
60.
40.
20.
A2.11E7
A3.45E7
A5.97E6
A9.83E6
1004
80.
60.
40.
20.
A1.1SE7
A8.24ES
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24
rilo:T980153 #1-396 Acq:6-JAN-98 16:06:09 EH- Voltage SIS 70T HoiaesBSl
403.8529 f:3 BSU3(256, 30, -3.0) PKD(7,5, 3, 0. 05%, 3404.0,1. 00\,T, T) ExpsNDBSUS
TRIANGLE LABS Text:TLI*44376 105-108 TJfJ. TIME - 15:05
IOCS A1.Q1E7
80.
60.
40.
20.
A6.95E6 ;
32:24 32:36 32:48 33:00 33:12 33:24 33:36
rlle:T9S01S3 #1-396 Acq:6-JAN-9a 16:06:09 EH- Voltaya SIS 70T
392.9760 F:3 Eip:lO>B5US \
TRIANGLE LABS Teit:TLI#44376 105-108 \
100*32:21 32,35 3a,49 _ 33:04 33,U 33.35 33:34\
33:48 34:00 34:12 34:24
-2.1S7
11 . 7S7
11.3E7
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-4.2E6
O.OEO
Tia
_1 . 7E7
.1.4E7
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.6.SE6
.3.4E6
O.OEO
Time
3.5E6
.2.BE6
.2.1E6
1.4E6
7.0E5
.O.OEO
Tine
3. OE6
2.4E6
1. 8E6
1.2E6
S.9ES
O.OEO
Time
TIME - 16: 09
33:53 34:04
90
-------
nj.a:T980153 #1-563 Acq: 6 -JAW- 9 8 16:06:09 EH- Voltage
407.7318 T:4 BSUB<356, 30, -3. 0) PE}( 7,5, 3, 0. 05%, 7916.0,
TRIANGLE LABS Text:TLI#44376 105-108
1001
80:
60:
40:
20:
0'
A3 .29E7 .
A
/ \ A9.91E6
/ V /\ /\
36\00 36:12 36:24 36*:36 36\48 37:00
Tile:T980153 #1-563 Aeq:6-JAN-98 16:06:09 Eli- Voltage
409.7789 T:4 BSO3(256, 30, -3. 0) PKD( 7,5, 3, 0.05%, 6292.0,
TRIANGLE LABS Text:TLI#44376 105-108
1001
80:
60:
40:
20:
0'
A3.18E7
n
A
/ \ A9.21E6
y V x\ yx
36\00 ' 36\12 ' 36\24 36\36 36:48 37\00
rile:T980153 #1-563 Acq:6-JAN-98 16:06:09 EI+ Voltage
417.3253 P:4 BSUB(256, 30, -3. 0) PXD( 7, 5, 3, 0. 05\,2748. 0,
TRIANGLE LABS Text:TLI»44376 105-108
1001
80:
60:
40:
20:
0'
.
'jtfl-Oo' ' '36\ia ' 36\24 36\36 36:48 37\00
rile:T9a0153 #1-563 Acq:6-JAN-98 16:06:09 EH- Voltage
419.3220 T:4 BSUB(256, 30, -3. 0) PKD(7, 5,3, 0 .051,2564 .0,
TRIANGLE LABS Text: TLI#44376 105-108
1003
80J
60:
40:
20:
0'
.
36(:00 ' '36\12 ' 36\24 36\36 36\43 J7.-00
rile:T980153 #1-563 Acq : 6 -JAN- 9 8 16:06:09 EH- Voltage
430.9729 T:4 Exp-.NDBSVS
TRIANGLE LABS Text:TLI#44376 105-108
1001
80:
60:
40:
20:
0'
36^10 36:24 36i43 36jJ3 37^
SIR 701 Soiaetl979
1.00\,f,T) XxptXDBSUS
INJ. TIME - 16:09
A3.03E6
37\12 37:24 37\36
SIR 70T Noise: 1573
l.QO\,T,T) ExptSDBSUS
I2KT. TIME - 16:09
A2. 79 E6
37\12 37\24 37\36
SIR 70T Noise: 687
1.00\,F,T) Exp:NDB5US
INJ-. TIHE - 16:09
A3 . 61E6
n
/I
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37\12 37\24 37\36
SIR 70T Noise: 641
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36:00 36:12 36':24 36\36 36i48 J7.-00
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479.7165 f:4 ExpsNDBSVS
TRIANGLE LABS Teit:TLI#44376 105-108
lOOi
80:
60:
40:
20.
0'
36:14
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37:48 ' '38:00 ' '38:12 Tiae
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TRIANGLE LASS Text:TLIt44376 105-109 UtT. TIME « 16:09
lOOi A3.4t3E6
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NSLS LABS Text:TLH44376 105-108 HTJ. TIME' 16:09
A3 . 72E6
'
A3.53E5 A2.96E5
A 7 V/V r
JS.-OO ' ' 37': 00 3a':00 391: 00 ' ' ' '40': 00 ' 41[:00 42^00
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9729 F:4 Exp:NDB5US
NGLE LASS Iext:TLIi44376 105-108 INJ. TIME " 16:09
35:16 36:10 36:4337:08 37:53 38:3238-59 39:34 41:10 41:43
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Ref, aasses 292,3825, 416.3768
fl 283 J 331 6 368
B 384
386
D 316
E 318
329
G 322
H 328
331
K 332
L 334
3 348
N 342
0 352
P 354
9 356
R 358
T 379
U 376
V 418
, uass 416,9769 Peak top
Height ,36 volts Span £08ppa
95
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File:T980153 #1-810 Acq:6-JAN-98 16:06:09 EI+ Voltage SIR 70T
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Sample Text:TLI#44376 105-108 INJ. TIME = 16:09 File Text:TLI#44376 105»
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24:25 24:40 24:53 25:05
25:44
26:06
24:00 25:00
File:T980153 #1-810 Acq:6-JAN-98 'l6:06:09 EI+ Voltage SIR 70T
315.9419 F:2 Exp:NDB5US
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Sample Text:TLI#44376 105-108
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Sample Text:TLI#44376 105-108 INJ. TIME =
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TLI#44376 105»
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34 :32
-------
TLI Project: 44376
Vlent Sample: 105-108
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X980084
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum
M23TRAIN
194-59-1A-1D
1.000
n/a
DB-225
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01/07/98
n/a
X980083
KAS
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
SPC2NP04
XF24087
X980080
: n/a
n/a
n/a
gSSSSSJSSSSi^JSSiSSSSSSSSSSS
2,3,7,8-TCDF
13C12-2,3,7,8-TCDF
13C12-1,2,3,4-TCDD
49.4
*;:*S;K;:¥*S:S:^
3.5 86.7
I
40%-130%
0.78
0.81
0.80
:iSlS*:¥™:SSi?::!SijtS^iS¥SS¥
21:30 E_
'^'Li'll'iin''''''0'''^'^^'^'''^''^'^'''''1^^^''^^'''''^''
21:30
20:28
Data Reviewer.
01/1U98
Page 1 of 1
C2NF_PSR vXOI. LAKS S.IO.OS
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:3301/11/98
105
-------
Initial
Data..
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
2.00
Page No.
01/11/98
Listing of X980084B.dbf
Matched OC Peaks / Ratio
/ Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Na
ID.. Flags.
TCDP
304-306 DC NL 0:00
17:07
17:45
18:06
18:13
18:21
18:31
18:47
18:56
19:05
19:10
19:14
19:25
19:45
20:10
20:16
20:26
20:37
20:49
21:00
21:23
21:30
21:43
21:57
22:02
22:43
23:19
304-306 26 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 17:14
OC WL 18:49
DC WL 19:13
DC WL -19:44
DC WL 19:58
DC WL 20:10
DC WL 20:25
21:00
21:06
21:30
22:02
DC WH 23:16
0.65-0.89
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.78
.78
.77
.78
.77
.78
.78
.78
.78
.36
.69
.78
.78
.77
.78
.78
.78
.77
.78
.77
.77
.78
.78
.77
.78
.78
.69
7
0.790-1.095
3,630.14
155,289.90
3,104.58
220,483.60
181,477.60
346,719.00
179,887.50
154,107.80
337,259.
172,637.
166,572.
441,386.
204,266.
994,948.
287,477.
49,475.
312,163.
290,393.
48,539.
409,332.
403,907.
290,292.
368,767.
448,171.
411,603 .
246,237.
42,524.
,167,526.
.00
.50
.40
00
80
00
00
40
00
00
30
00
00
00
00
00
00
00
90
28
67,903
1,352
96,370
79,156
151,477
78,779
67,358
147,338
80,046
67,981
192.338
89,524
434,202
125,570
21,730.
136,429
126,395.
21,205.
178,518.
176,299.
126,997.
161,205.
195,548.
180,201.
107,736.
17,384.
.90
.02
.60
.60
.00
.50
.20
.00
.30
.80
.00
.80
.00
.00
.20
.00
,00
.40
.00
.00
.00
,00
.00
.00
,00
,40
87,386
1,752
124,113
102,321
195,242
101,108
86,749
189,921
92,590
98,590
248,548
114,742
560,746
161,907
27,745
175,739
163,998
27,333
230,314
227,608
163,295
207,562
252,623
231,402
138,501
25,140
0.65-0.89
RO 0
RO 0
0
RO 1
RO 1
0
0
RO 1
RO 1
0
.93
.92
.73
.34
.86
.71
.85
.06
.55
.79
0.81
RO 1.29
RO 0.45
57.
79.
130.
213.
40.
206.
565.
329.
52.
26.
24,298.
80.
60.
06
28
52
81
07
31
33
30
98
87
10
96
98
46.
11.
10,895.
S3.
43
as
00
83
29.
15.
13,403.
45.
.00
.56
.00
.00
.00
.00
.60
.00
.70
.60
.00
.00
.00
.00
.20
.00
.00
.90
.00
.00
.00
.00
.00
.00
.00
.50
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1.
1.
1.
1,
1.
1.
.000
.796
.826
.842
.847
.853
.861
.874
.381
.888
.391
.895
.903
.919
.938
.943
.950
.959
.968
.977
.995
.000 2378-TCDF AN
.010
.021
.025
.057
.084
E
B
B
E
B
E
E
E
B
E
E
E
B
E
E
E
E
E
E
E
B
B
0.953-1.047
•
93
02
10
74
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
.000
.802
,875
,894
.918
929
938
950
977
981
000 13C12-2378-TCDP ISO
025
082
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:18 01/11/98
106
-------
Page No. 2 Listing of X980084B.dbf
01/11/98 Matched OC Peaks / Ratio / Ret. Time
Compound/
! QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
r
DC WH 23:45 RO 1.37 103.44 1.105
316-318 4 Peaks 24,438.91
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.89 0.901-1.099
332-334 DC ML 0:00 RO 1.76 28.59 0.000
20:13 0.79 17,380.86 7,688.81 9,692.05 1.000 13C12-2378-TCDD IS1
20:28 0.80 20,140.88 8.942.48 11,198.40 1.012 13C12-1234-TCDD RSI
20:42 0.82 30.26 13.59 16.67 1.024
20:48 RO 2.24 7.86 9.94 4.44 1.029
21:09 RO 1.01 199.59 114.36 112.76 1.046
DC WH 22:44 RO 0.43 81.97 1.124
DC WH 22:50 RO 1.21 18.28 1.129
DC WH 23:09 RO 1.07 27.38 1.145
332-334 5 Peaks 37,759.45
Column Description "Why* Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:33) WH-Above Retention Time Window X-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits * End of Report ***
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13-18 01/11/98
Phone: (919)544-5729* Fax: (919) 544-5491 107
-------
ellatZ980084 tl-884 Acyt 7-*fAa-iyya i/mm w. ju* voicag* six Aucospec UOIM
303.9016 BSUB(256,30,-3.0) ?KD(3,3,1. 0.10*, 3187832. 0, 0. 00*,?,?) gxpiKOSfJPT
SfOflf T*xtiTLI*44376 105-108 Pll* Tmxti TKLUfOLS LABS
100* JM 4X9
17:00 laioo 19100 40*00 21100 aa'too 23*00
Pill> 1980084 «l-884 Jkcyt 7-001-1999 17s21i21 OC B> Volttgt SIR AUtoSpma Ifolgft 1018108
305.8987 B3US(256,30,-3.0) fKD(5,3,lr0.10*,4072432.0,0.00*,P,P) BxptXCONP_TT
t ToxtiTLI*44376 105-108 Pilf Vmxet TRIANQLS LABS
100H
80.
SO.
40.
20.
A2.49S9
A1.95E9
A1.7SS9
A2.31S9
A2.28S9
A2.31S9
A1.39B9
A2.51SB
/\
17:00 18:00 15:00 20:00 21:00 22:00 23:00
Pil»sX9800B4 #1-884 Act?: 7-JAN-1998 17:21:21 OC SI+ Voltage SIR AuCoSpac Nolue: 15025
315.9419 BSUB(256,30, -3.0) PKD(5,3, 1, 0.10%, 60100. 0, 0. 00*,P,P) Exp:KONF_TT
Saapl* ToxtiTLI#44376 105-108 Pllf Tufti TRIANOLE LABS
100* A1.09E8
80.
60.
40.
20.
17:00 18:00 1*.:00 20:00 21:00 22:00 23:00
P±l»tX980084 01-884 Actj: 7-JAK-199B 17:21:21 OC SI* VolCaga SIR AutoSpac Hols*tl6121
317.9389 BSUB(256,30,-3.0) PKD(S,3, 1, 0.10*, 64484. 0, 0. 00*,P,P) SxpiKONPJTT
Saapla Text:TLI#44376 105-108 Pil» Toxtt rRlANQLS LABS
lOOit A1.34E8
80.
60.
40.
20.
17:00 18:00 15:00 20:00 21:00 22:00
Pil»iI980084 tl-884 Acq: 7-JAN-1998 17:21(21 OC ST+ Voltagu SIR AutoSpec
375.8364 SxpIKONP_TT
Saapl* T*xttrLI*44376 105-108 Pllf Tut: TRIAM3LB LABS
10031
80.
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17/11
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_a.asa
.7.0E8
.5.3E8
.3.5E8
.1.3E8
O.OEO
Time
2. 5E7
'.2.0E7
'.1.SE7
'.1.0E7
S.1S6
O.OEO
Time
17,00
18100
19 tOO
20:00
21100
22100
.3.2E7
.2. 6E7
.1.9E7
.1.3E7
.6.5E6
.O.OEO
Tlma
.2.2E6
.1.8E6
.1.3S6
.9. OSS
4.5S5
O.OSO
Tim*
108
-------
Pll«tZSBOOB4 I1-9B4 Acq: '/-JJJJ-1S9B 17,31:31 X S1+ Volbagu 3IS AukoSpac Soifa, 3.0978
319.8965 BSHB(256,30,-3.0) tXD(5f 3,1,0, 10*,43913. 0,0. 00*. f,P) SxpiKOaP_TT
Stapl* T»*ttTU»44376 105-108 Pilu Tmxe: TRIABOLS LABS
iocs
BO.
60.
40.
20.
A6.67SB
A3.41S8 A6.07S8
A A A A3.38S8 f\
A A '/W\ «•««
H /I l\ l\l\ /V/v/YiK- A^ ^ _ _
-2.6S8
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321.8936 BSUB(3S6,30,'3.0) PXD(5,3,1, 0.10*,105496.0,0.00*,P,P) g*p:KOaP_TT
Saapla T*XttTLI*44376 105-108 P±lu Text: TRIANQLS LABS
100}
80.
60.
40.
20^
Q'
k
A8.55E8
1-
A4.40E8 A7.75E8
h*3'^ A3 03E8 h
II ft II J*W » U JAO / 1
A A A J \ A1.58E8
l\ l\l\ /v/v/Yi K . A^\ ^ _ ^
3.3S8
.3.7E8
'.2.0BB
.1.3E8
'.6.7S7
' O.OEO
'ifliflo' ' ' ' 15«00 20:00 2l':00 ' ' 22:0o' ' ' 23\00 Time
Pll»tX980084 #1-834 Acq: 7-JAH-1998 17:21:21 OC BI+ Volt ay « SIR AutoSpac Holaat 11066
327.8847 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10*, 44264.0, 0.00*,P,P) Exp : XCONP_TT
Saaplf TOXC:TLI»44376 105-108 Pil» Tojef: TRIANGLE LABS
100*
ao:
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40.
20:
Q'
A3.22EB
A2.11EB I
I ' ,
II A1.63EB
I
A
_JlA_^A/l7l 11
B.OE7
.6.4E7
'.4.8E7
.3.2E7
.1.627
O.OEO
'iflioo J^ioo' ' 20'tOO ' ' '31:00 33\00 ' ' 23\QO Tiaa
P11»:X980084 91-884 Acqt 7-WS-1998 17:21:21 OC SI* Volt ago SIR AutoSpac Noiaa: 14246
331.9368 BSVB(256,30,-3.0) PXD(5, 3, 1,0.10*. 56984, 0,0. 00*, P,P) ExpsXCONP TT
Saopla Toxt:TLI»44376 105-108 Plla Taxt: TRIANGLE LABS
IOCS
80.
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0
A8.94B7
A7.69S7\
'
n
2.4E7
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'.1.4E7
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.4.BE6
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Pll»:X980084 01-884 Acqt 7-JAH-1998 17:21:21 OC ST* Voltaym SIR AutoSpac Boim»t807S
333.9338 BSVB(256,30, -3 .0) PKD(5,3, 1, 0.10*,33300. 0, 0. 00*,P,P) SxptXCOHP TT
Suapl* T*Xt:TLI#4437S 105-108 Pllf Tvtt: TRIAffOLS LABS
IOC*
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20.
a
A1.12E8
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.3.4S7
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109
-------
27JOO 20iOO 15x00 20:00 31:00 23:00
Plle:Z980084 91-884 Acq: 7-JAB-1998 17:31:31 OC SI+ Voltage SIR AutoSpec
319.8965 Sxp:XCOKP_TT
Sample Text:TLI»44376 105-108 Pile Text: TRIANQLE LABS
20« 27;57
00:
60:
40:
30:
0.
Plle:I980084 #2-004 Acq: 7-JAB-1998 17:21:21 OC SI* Voltage SIR AntoSpec
303.9016 Srp:ZCOKP_TT
Sample Text:TLI*44376 105-108 file Text: TRIASOLS LABS
17:00 18:00 19:00 SOlOO 31:00 32:00
Pile: 1980084 tl-884 Acqt 7-JAS-1998 17:21:31 OC EH- Voltage SIR AutoSpee
Sxp:XCQNP_TT
Sample TextiTLIt44376 105-108 Vile Text: TRIANQLS LABS
100*
23(00
00:
60:
40:
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21:30
33oo
""
19:09
20:28
AAAT.A
17:00 18:00 19:00 30:00 31:00 33:00
Plle:X980084 tl-884 Acq: 7-JAB-1998 17:21:21 OC SIf Voltage SIR AutoSpec
331.9368 Bxp:KONP_TT
Sample Text:TLIS44376 105-108 Pile Text: TRIANOLS LABS
100% 30/28
0oJ "'"'
60:
40:
20:
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23s 00
17:00 18:00 19:00 20:00 21:00 22:00
Pile,1980084 *i-884 Acq: 7-JAB-1998 17:31:21 OC SI+ Voltage SIR AutoSpec
292.9825 Exp:XCONP_TT
Sample Text:TLI#44376 105-108 Pile Text: TRIANGLE LABS
100* 17±39 17lS5 •">_L™ -20-155 2H24 21^S1_23^
80:
60:
40:
ab:
o:
-2.SE7
.3.0E7
.1.5S7
.1.0E7
-5.1S6
O.OSO
Timi
2.6S8
.2.1E8
.1.6E8
.1.0E8
.5.2E7
0. OEO
Time
2.4E7
.1.9E7
.1. 4E7
.9.6E6
.4.BE6
22
2300
23:07 23:31
O.OSO
Time
8.3B8
.6.7E8
.S.OE8
.3. 3E8
O.OEO
17:00 18:00 19:00 20:00 21:00 22:00
Pile,1980084 11-884 Acq: 7-JAB-1998 17:21:21 OC EI+ Voltage SIR AutoSpec
330.9792 Sxp:KOS?_TT
Sample Text:TLI*44376 105-108 Pile Text: TRIASOLS LABS
astoo
100*
80.
60:
40:
20:
oj
17«51
9.0E8
.7.3E8
.5. 4S8
.3.6E8
.2.020
i7»oo
a/oo
?»oo
20: oo
aio
aao
23oo
0.0X0
Time
110
-------
Peak Locate Examination: 7-JAN-1998:17:20 File:X980084
Experiment:XCONF_TT Function:! Reference:PFK
Volts
5.2592
292.95315
292.98245
293.01175
Volts
5.6435
330.94615
330.97925
331.01235
-------
TLI Project: 44376
Client Sample: 109-112
Method 23 PCDD/PCDF Analysis (a)
Analysis File:
Client Project:
Sample Matrix:
TLI ED:
Sample Size: .
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-2A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01706/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Aralytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
U,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (tig) Di. EMPC
1.4
6.6
1.7
2.7
3.8
2.6
1.5
EMPC 46rO 7 V
32.7 ^
43.9 '/is/
29.0
12.8
8.3
0.37
7.2
0.78
0.82
Amt ing) Number Dt EMPC
. 84.5 13
164 10 167
55.8 7
5.5 2
496- -y "f 15 552- 7 Lf
^29— 72-0 16 -549 720
141 13 143
9.2 3 11.3 ^<£
Ratio
0.79
1.58
1.22
1.24
1.22
1.01
0.83
, 1.50
f/ 1.48
1.26
1.31
1.26
1.24
1.04
1.02
0.85
RT
26:21
30:33
33:37 .
33:42
34:01
37:05
40:56
29:31
30:14
32:53
33:00
33:30
34:17
35:59
37:37
41:09
Flags
oZ
QPR
—
SE_
E_
~~1
PR_
Flags
E_
E_
Q_
—
SQE
SE_
E_
X_
Page Iof2
X237.PSRv2.01. LARS
Triangle Laboratories, lnc.»
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 £1/15/98
-------
•US
TLI Project: 44376
Client Sample: 109-112
|il^i^^|wiiiil^il^^i88^1
13C12-2,3,7,8-TCDF
l3C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
l3C15-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
I3Cr-l,2,3,4,6,7,8-HpCDF
13C12-l,2,3,4,6,7,8-HpCDD
13Ci2-l,2,3,4,6,7,8,9-OCDD
^HaJii^ii^a^^^mi^^M
•i-:\\\-:-x-\*x:'-.<\^:-y.-\w
37CL-2,3,7,8-TCDD
13C,:-2.3,4,7,8-PeCDF
13C,:- 1,2,3,4. 7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD
l3C,;-l,2.3,4,7,8,9-HpCDF
IKFr^^^n^Kj^^i^P
m^fm^^mmmmfxi^^m^i^^m&mmi
IJCi2-l,2,3.7,8,9-HxCDF
13Cr-2,3,4,6,7,8-HxCDF
|j||c$^
13Cia-l,2,3,4-TCDD
13C,:-l,2,3,7,8,9-HxCDD
2.2
2.8
2.8
3.4
2.8
2.5
3.1
4.1
9.0
3.5
4.1
4.1
5.5
4.0
||iii||i(ng||
3.2
2.9
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980154
54.5
70.6 .
71.1
85.8
69.7
63.3
77.0
103
112
88.6
101
102
137
99.4
79.7
73.6
imi^piBiiiiii^:
QC Limits
40%- 130%
40%-130%
40%- 130%
40%-130%
40%-130%
40%-130%
25%-130%
25%- 130%
25%-130%
Illliiiti;?
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
liHimftl!
40%- 130%
40%- 130%
0.76
0.79
1.54
1.49
0.52
1.16
0.43
1.04
0.91
llllptiqll
1.52
0.53
1.15
0.42
||||il|ati[<>|
0.51
0.52
||||Ra4io|
0.81.
1.16
25:41
26:21
29:30
30:33
32:59
33:42
35:59
37:04
40:55
26:21
30:13
32:53
33:36
37:36
34:17
33:30
26:10
34:01
Q_
oH
l|l|iipgs|!l:
oIL
111111111
—
::::::::::::-Sx-:iii':'-'---:-':::::::oyV:.:
mmffiaxtsm
v:::::v:x::::::::::::::X::-.*^:.::.:v..:::;X
Data Reviewer
01/15/98
Page 2 of 2
X37.PSR V2.0I.LARS 6.10.080
Triangle Laboratories, Inc.3
801 CapKola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
113
-------
Initial
. .Data. .
Data Review By:
Calculaeed Noise Area:
2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-313
316-318
TCDD
320-322
DC NL 0
22
23
23
23
24
24
24
24
25
25
25:
25:
26:
26:
26:
27:
DC WH 27:
0
:00 RO
:39
:08
:21
:43
:01
:25
:40
:53
:05 .
:17
:30
:42 RO
:06
:13
;32
:22
:35
.65-0.89
1.09
0.30
0.31
0.79
0.80
0.31
0.31
0.30
0.30
0.30
0.30
0.31
0.94
0.30
0.30
0.77
0.33
0.38
16 Peaks
DC NL 0:
DC WL 22:
DC WL 23:
DC WL 23:
DC WL 23:
DC WL 23:
DC WL 24:
DC WL 24:
DC WL 24:
25:
25:
25:
26:
26:
DC WH 27:
DC WH 27:
0
00 RO
40 RO
08 RO
21 RO
30 RO
43 RO
03 RO
25 RO
39 RO
17 RO
30 RO
41
05 RO
13 RO
05 RO
35
5 Peaks
DC NL 0:
0.
00
.65-0.89
1.49
1.36
3.02
2.71
1.47
2.54
1.41
1.84
1.17
0.54
1.25
0.76
1.34
2.16
1.05
0.72
0.878-1.073
12
13
14
69
41
48
42
58
36
23
22
60
32
25
4
3
508
4.51
,646.24
,761.79
,125.51
,194.90
.243.20
,048.70
,448.20
,573.50
,366.10
,120.30
,784,00
,792.77
,740.00
,020.30
,231.63
,316.39
834.92
,464.08
5
6
6
30
18
21
18
25
16
10
10
32
14
11
1
1
,614.06
.144.32
,242.97
,772.50
,400.00
,470.10
,893.40
,972.90
,147.50
,256.90
,180.90
,130.40
,575.90
,142.40
,860.96
,503.55
7
7
7
38
22
26
23
32
20
12
12
34
18
13
2
1
,032.13
,617.47
,882.54
,422.40
,343.20
,578.60
,554.30
,600.60
,218.60
,863.40
,603.10
,346.20
,164.10
,377.90
.420.72
,313.34
0.000
0.882
0.901
0.909
0.923
0.935
0.951
0.960
0.969
0.977
0.984
0.993
1.001 2378-TCDF AN
1.016
1.024
1.033
1.066
1.074
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
SE
QE
QE
Q
Q
.0.961-1.039
2,
2,
65-0.89
0.86
3.04
9.31
3.46
5.31
13.66
29.28
42.09
27.10
62.22
79.19
33.86
638.50
31.47
13.53
8.53
22.57
851.55
TCDF /
3.64
34.45
23.82
1,160,50
23.77
22.59
1,
63.36
19.13
528.00
17.78
10.47
0.000
0.883
0.901
0.909
0.915
0.923
0.936
0.951
0.960
0.934
0.993
1.000 13C12-2378-TCDF ISO
1.016
1.024
1.055
1.074
Q
0.903-1.045
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
01/15/98
-------
Page No.
01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
M
M
AN
320-322
37C1-TCDD
328 .
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
23
24
24
25
25
25
26
26
26
26
26
26
27
:55
0.78 18
:17 0.79 11
:34
:13
:29
:51
:08
:15
:21
:31
:40
:53
:19
0.
0,
0.
0,
,77 4
,78 12
,77 9
,78 4
0.78 4
0.
0.
0.
0.
0.
0.
13 Peaks
.78 7
,79 1
,77 2
,78 2
80
79
80
.293.32
.344.32
,826.63
,393.57
,000.34
,860.02
,850.00
,960.00
,316.00
,123.64
,412.22
742.93
816.41
,945.90
8,016
5,011
2,100
5,418
3,929
2,125
2,130
.3,490
581
925
1,053
330
361
.72
.46
.19
.78
.63
.26
.00
.00
.00
.05
.87
.60
.21
10,282
6,333
2,726
6,974
5,071
2,734
2,720
4,470
735
1,198
1,358
412
455
.10
.36
.44
.79
.21
.76
.00
.00
.00
.59
.35
.33
.20
0.908
0.922
0.932
0.957
0.967
0.981
0.992
0.996
1.000 2378-TCDD
1.006
1.012
1.020
1.037
E
E
E
E
E
AN
0.924-1.076
DC NL 0
DC WL 23
DC WL 24
DC WL 24
24
25:
• 25:
25:
25:
25:
26:
26:
26:
26:
27:
27:
27:
28:
:00
:55
:09
:17
:34
:01
:13
:29
44
:51
:09
:21
30
43
20
31
42
00
14 Peaks
DC NL 0:
25:
26:
26:
26:
0.
00 RO
13
10
21
40 RO
,65-
2.
0.
0.
0.
0.
4 Peaks
DC NL 0:
27:
27:
28:
28:
1.
00 RO
35 RO
49
00
11
32-
1.
1.
1.
1.
1.
1
2
3
7
0.39
20
69
31 3
79 2
64
6
1.78
19
24 46,
47
53
57
2.23
94.71
48.71
135.16
31.47
,930.59
75.64
49 .02
21.97
34.43
28.37
,507.66
48.18
,200.31
4.44
3.33
7.23
6.39
,949.53
31
1.930
75
49
21
34
28
2,507
48
3,200,
4.
3.
7,
6.
.47
.59
.64
.02
.97
.43
.37
.66
.13
,31
.44
33
.23
.39
0.000
0.908
0.917
0.922
0.932
0. 949
0.957
0.967
0.977
0. 931
0.992
1.000 37C1-TCDD
1.006
1.014
1.037
1.044
1.051
1.063
SUR1
0.924-1.076
3.56
17.78
,192.46
,812.06
46.46
,063.76
TCDD /
2.63
,348.47
935.47
266.27
858.53
7.
1,425.
1,241.
20.
28
73
61
21
10.
1,766.
1,570.
31.
50
68
45
63
0.000
0.957
0.993 13C12-1234-TCDD
1.000 13C12-2378-TCDD
1.012
RSI
IS1
P»P ni? c*rti i ni+to
28,172.
556.
161.
524.
60
46
21
40
22,765.
379.
105.
334.
0.931-1.063
20
01
06
13
0.000
0.935
0.943
0.949
0.955
SE
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
115
-------
Page No.
01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total .Area. .. Area. Peak. 1.. Ar ea. Peak. 2. . Rel.RT Compotmd. Name. . ID.. Flags.
A
M
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
A .
28
28
28
28
29
29
29
29
29
29
30
30
30
30
30
31
DC WH 31
:19
:33
:41
-.50
:09
:14
:26
:31
:40
:47
:04
:14
:24
:41
:51
:09
:36
RO
RO
RO
1.23
1.48
1.10
1.48
1.48
1.43
1.49
1.50
1.43
1.50
1.86
1.48
1.49
1.51
1.46
1.50
1.45
20 Peaks
DC NL 0:
27:
DC SN 27:
DC SN 27:
DC SN 28:
28:
' 28:
28:
29:
29:
29:
29:
29:
30:
30:
31:
:00
:35
42
:52
21
33
41
51
09
14
30
47
57
13
25
08
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
12 Peaks
DC NL 0:
28:
29:
29:
29:
29:
30:
30:
30:
30:
30:
00
46
14
29
36
47
03
16
26
33
39
1.
RO
RO
32-1.78
1.07
2.28
1.33
2.29
2.09
2.78
2.01
1.18 .
2.14
2.19
1.54
1.53
0.53
1. 52
1.96
1.20
356.16
27,642.60
67,998.14
31,725.10
41,009.60
41,577.00
18,890.00
25,200.00
21,296.35
27,786.80
330.61
33,812.30
31,434.50
1,695.47
941.40
2,183.12
64.67
422,288.39
16
41
18
24
24
11
15
12
16
20
13
1
1
216.49
,494.00
,332.20
,948.30
,491.60
,478.30
,300.00
,100.00
,716.00
,650.20
241.48
,201.40
,825.00
,020.95
558.75
,310.34
176
11,148
37,727
12,776
16.518
17,098
7,590
10,100
8.580
11,136
129
13,611
12,609
674
382
872
.10
.60
.40
.30
.00
.70
.00
.00
.35
.60
.65
.40
.50
.52
.65
.78
0.560
0.968
0.972
0.977
0.983
0.991
0.998
1.001 12373-P>«CDF AN
1.006
1.010
1.019
1.025 23478-BXeCDF AN
1.031
1.040
1.046
1.056
1.071
SE
E
E
E
E
E
Q
0.864-1.136
1.02
37.46
2.45
2.36
2.31
16.27
149.20
40.29
23.87
28.31
2,904.57
53.02
4.75
2,923 .33
31.62
11 .78
6,224.47
32-1.78
1.24
1.47
1. 54
1.53
1.54
1.56
1.54
1.58
0.95
1.58
1.50
1,51
39,331.90
3,236.73
20,725.48
5,069.73
14,407.24
8,609.49
4,683.73
2.056.45
4,148.38
965.12
1,
1,
33.43
17.74
117.52
24.49
20.00
24.31
,762.72
32.09
2.89
.763 .48
24.31
7.16
14.
6.
58.
20.
9.
. 11.
.1,141.
20.
4.
1,159.
12.
5.
,59
38
51
32
36
10
85
93
25
85
40
96
0.000
a. 935 '
0. .939
0.945
0.961
0.963
0.972
0. -978
0.988
0,991
1..000 13C12-P.eCDF 123 IS2
1.010
1.015
1.024 13C12-PfiCDF 234 SUR2
1.031
1.055
Do<""Tin TTrtT 1 /rue-
23,
1.
12,
3,
8,
5,
2.
1,
2,
389.00
961.96
547.30
076.67
788.04
215.44
866.20
250.00
542 . 12
579.61
15,942.
1,274.
8,178.
1,993.
5,619.
3,394.
1,817.
1,310.
1,606.
385.
0.939-1..022
90
•77
13
06
20
05
53
00
26
51
0.000
0.942
0.957
0,965
0.969
0.975
0..984
a. 991
0.996
1.000 12373-FeCDD AN
1,003
E
Q
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
116
-------
Page No.
01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
,M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
356-358
13C12-P6CDD
368-370
368-370
HxCOF
374-376
AX
M
MX
AN
M
374-376
13C12-HXCDF
384-336
384-386
30:58
11 Peaks
DC NL 0:00
28:46
29:14
29:28
29:36
29:47
30:04
30:14
DC SN 30:24
30:33
DC SN 31:00
8 Peaks
DC NL 0:00
31:56
32:04
32:14
32:22
32:31
32:44
32:53
33:00
33:07
33:18
X 33:25
33:30
X 34:14
34: 17
34:22
DC WH 34:47
15 Peaks
1
1.32
RO 0
RO 2
RO 1
RO 2
1
1
RO 2
1
1
1
1
1.05
1
1
1
1
1
1
1
1
1
1
1
RO 1
1
RO 1
1
1
1
.57
-1.78
.58
.76
.98
.08
.44
.64
.66
.76
.72
.49
.76
ihft1
-1.43
.11
.27
.24
.27
.24
.26
.32
.26
.31
.28
.26
.22
.26
.29
.24
.25
.26
1,916
105,150
0
23
7
21
3
12
7
3
4
1,945
5
2,040
123
11,144
36,065
2,653
3,522
2,042
390
20.453
10,140
1.967,
3.122,
349.
5,280.
753.
222 .
967.
167.
99,078.
.47
.72
.54
.69
.93
.47
.59
.21
.19
.90
.76
.11
.93
.09
") / M\
*i 1 nj
.98
.59
.00
.64
.63
,01
.24
.37
.65
.41
.90
00
.00
00
30
00
45
79
1
1
,171
31
6
17
5
7
7
5
.164
.04
.05
.17
.49
.07
.53
.51
.68
.58
745
11
3
3
3
4
2
3
780
.43
0.
.25
.11
.42
.52
.63
.32
.22
.53
1.014
369-1.131
0.000
0". 942
0.957
0.965
0.969
0.975
0.984
0.990
0.995
1.000 12C12-PeCDD 123 IS3
1.015
6
19
1
1
1
11
5
1
1
2
,230
,940
,483
,951.
,138,
221
.415
,746,
,104,
,740,
192.
,940.
424.
123 .
537.
.16
.40
.43
.13
.16
.96
. 20
.49
.72
.50
00
00
00
00
00
4,914
16,124
1.170
1.571
903
163
9.043
4.394
862
1.332
157
2,340
329
99
430.
0.43-0.59
DC NL 0:00
31:56
32:04
32:53
32:59
33:15
33:30
DC SN 33:44
DC SN 33:54
DC SN 34:01
34:17
7 Peaks
RO 1
RO 1
RO 1
0
0
0
0
RO 0
0
RO 0
0
.38
.35
.20
.53
.52
.52
.52
.95
.53
.65
.51
3 .
3.
32 .
2,295.
2,444.
3.
2,461.
3 .
3.
4.
2,110.
9,361.
38
98
31
64
39
08
31
52
71
09
03
24'
8.
25.
791.
835.
2.
837.
713.
03
70
71
13
75
73
42
5.
21.
1,503.
1.609.
5.
1.624.
1,396.
0.964-1.049
.43
.60
. 21
.55
.35
.28
.17
.16
.69
.40
.00
.00
.00
.30
.00
0.000
0.963
0.972 E
0.977
0.981
0.936
0.992
0.997 123478-HxCDF AN
1.001 123673-HxCDF AN
1.004
1.010
1.013
1.016 234678-HxCDF AN
1.038
1.039 123789-HxCDF AN PR
1.042
1.055
0.379-1.121
95
40
•93
26
33
03
61
0.000
0.968
0.972
0.997 13C12-HXCDF 478 SUR3
1.000 13C12-HXCDF 578 IS4
1.008
1.016 13C12-HXCDF 234 ALT2
1.023
1.028
1.031
1.039 13C12-HXCDF 789 ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
117
-------
Page No.
01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF.
408-410
X
D
408-410
13C12-HpCDF
418-420
413-420
HpCDD
424-426
424-426
1
DC NL 0:00
32:25
32:51
33:05
33:15
33:37
33:42
34:01
7 Peaks
1
DC NL 0:00 RO
33:03 RO
DC SN 33:16 RO
33:36
33:42
34:01
4 Peaks
0.
DC NL 0:00
35:59
X 36:16 RO
36:26
DC SN 36:41 RO
D , NH 37:21
37:37
DC WH 38:12 RO
4 Peaks
0.
DC NL 0:00 RO
35:59
DC SN 36:28 RO
37:36
2 Peaks
0.
DC NL 0:00 RO
36:17
37:05
DC WH 37:36 RO
2 Peaks
.05-1.43
1.14
1.21
1.22
1.22
1.24
1.22
1.24
1.22
.05-1.43
1.66
1.00
1.99
1.15
1.16
1.16
38-1.20
1.13
1.04
1.05
1.04
1.55
0.97
1.02
1.27
37-0.51
1.09
.0.43
0.60
0.42
88-1.20
1.78
1.03
1.01
1.78
9.72
3,394.10
8,553.92
5.388.67
553.16
604.09
1,061.66
1,496.43
21,052.03
3.58
12.99
4.05
1,741.18
1,569.35
2,483.98
5,307.50
Hv/-nn /
ruiwL'u i
4.59
4,510.99
1,171.37
669.12
4.39
9.03
371.32
16.10
6,723.30
1.83
1,704.95
2.29
1,321.35
3,025.30
• Wr^f"* TIP /
: npt_ur /
0.32
1,360.92
1,250.84
4.69
2,611:76
1.855.18
4, 693.87
2,962.75
305.72
332.31
587.91
822.70
7.19
929.78
844.15
1,333.55
2,303.10
. 601.11
340.44
187.37
513.42
393.79
Wn^nn Prtl 1 rOfic
690.51
628.04
0.958-1.015
0.000
1.538.92 0.962
3,860.05 0.975
2,425.92 0.982
247.44 0.987
271.78 0.998 123478-HxCDD AN
473.75 1.000 123678-HxCDD AN
673.73 1.009 123789-HxCDD AN
0.970-1.030
0.000
7.20 0.981
0.987
811.. 40 0.997 13C12-HXCDD 478 SUR4
725.20 1.000 13C12-HXCDD 673 IS5
1,150.43 1.009 13C12-HXCDD 789 RS2
0.998-1.053
0.000
2,207.39 1.000 1234678-HpCDF AN
570.26 1.003
328.63 1^013
1.019
1.038
184.45 1.045. 1234789-HpCDF AN
1.062
0.944-1.111
0 . 000
1,191.53 1.000 13C12-HpCDF 678 IS6
1.013
928.06 1.045 13C12-HpCDF 789 SUR5
0.976-1.006
0.000
670.41 0.979
622.80 1.000 1234678-HpCDD AN
1.014
<3
<2
Q
Q
Q
QPR
Q
Q
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
118
-------
Page No.
01/15/98
Listing of T980154B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omic Why
.RT. OK Ratio Total.Area. .. Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name. . ID.. Flags.
13C12-HpCDD
436-438
436-433
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
3
NL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
1 2
0
36
36:
37
37
Pe<
0:
35:
35:
36
35:
37:
38:
38;
39:
39:
39:
39:
40:
41:
41:
41:
Pee
:00
:17
:30
:04
:19
iks
:00
34
:51
:14
:47
:05
:17
;36
:22
39
47
53
:15
09
26
43
iks
0,
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
,38
1
1
3
1
1
76
0
0
1
1
1
1
1
2
0
1
0
0
0
0
0
0
-1..20
.45
.31
.48
.04
.94
-1.02
.94
.43
.02
.04
.00
.02
.12
.45
.96
.15
.43
.45
.30
.35
.73
.55
1.88
12.42
1.26
1,848.56
10.06
1,371.04
7.97
944.06
9.58
0.973-1.027
0.000
6.09 0.979
0.985
904.50 1.000 13C12-HpCDD 678 IS7
4.93 1.007
Above: HpCDD / Octa-CDD and CDF Follows
0.99
1.06
1.07
9.03
1.34
.2.66
1.13
0.42
1.10
0.64
0.31
1.00
0.76
404.72 186.18 218.54
16.50 7.77 10.66
0.31
421.22
0.902-1.098
0.000
0.369
0.876
0.386
0.399
0.906
0.936
0.943
962
969
972
975
0.984
1.006 OCCF
1.013
1.020
AN
JCDD
453-460
453-460
0.76-1.02
DC NL 0:00 RO 1.09 0.21
40:56 0.83 559.29
DC SN 41:16 RO 1.13 2.53
1 Peak 559.29
254.23
0.902-1.098
0.000
305.06 1.000 OCDD
1.009
AN
13C12-OCDD . 0.76-1.02
470-472 DC NL' 0:00 RO 1.08 0.25
40:55 0.91 2,736.31
DC WH 41:23 RO 0.31 3.14
470-472 1 Peak 2,736.31
1,302.66
0.993-1.006
0.000
1,434.15 1.000 13C12-OCDD
1.013
IS8
Column Description "Why" Code Description QC Log Desc .
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm;ss)
Rat.l -Ratio of M/M+2! Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below signal to Noise Level
-------
rile:T980154 #1-810 Acq:
303.9016 F:2 BSOB(256,30
6-J7UI-98 16:51:52
BI+ Voltage SIS 70T Noiae:1390
,-3.0) PKD(9,5,5,0.05\,5560.0,1.00\,r,T) ExpsSDBSUS
TRIANGLE LABS Teit:TLIt44376 109-112
100J
80:
60.
40.
20'.
0
A3.
A6.14E7
A AA /
23\00
riJ.e:T980154 #1-810 Acq:
A3
08Z8 Al . B9E8
A _ .. -
n *2-*sza\
] \A1.84Sa A
'HA/U
24 ': 00
6-JAN-9B 16:51:52
\A2.60E8
A .
\ /kl . 03E8
1 1 A n n
IrMA
25-00
EI+ Voltage SIS 7
305.8987 F:2 BSUS(256,30, -3 .0) PXD(9,5,5, 0. 051,5092.0,1 . 00%
TRIANGLE LASS Teit:TLIf44376 109-112
100S
80:
60:
40:
20:
o-
A3.
A7.62E7
A AA /
'23-00'
A3.
84E8 A2.36E8
A
A2.66E8
\ A
A2.28E8 l\
U A I
M / \ A*
V\/U
24 : 00
rile:T9B01S4 #1-810 Acq : 6 -JAN- 9 8 16:51:52
A3.26E8
(\ 11
A1.29E8
\ . I I A
Al A .
vy\l\ A
11 ll/lAi
25:00
EI+ Voltage SIS 7
315.9419 r:2 BSUB(256, 30, -3. 0) PKD(9,5,5, 0. 05%,5128. 0,1. 00%
TRIANGLE LABS Text:TLI#44376 109-112
100^
ao:
60:
40:
20:
0
' 23\00'
File :T9 80154 # 1-810 Acq:
v*
'24:00'
6-JZN-98 16:51:52
Al.
- - - r '
251-00
EI+ Voltage SIS 7
317.9389 F:2 BSUS(256, 30, -3 .0) PKD(9,5,5, 0. 05%, 3440. 0,1 . 00*
TRIANGLE LASS Text:TLI»44376 109-112
1001
80:
60:
40:
20:
o'
23 1- 00
' 24\00
rile:T980154 #1-810 Acq: 6-JAN-98 16:51:52
330.9792 P:2 Exp:NDB5US
Al.
1
' 25\00'
El + Voltage SIS 7
TRIANGLE LABS Text:TLIf 44376 109-112
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1001
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TSIANGLE LABS Text:TLI»44376 109-113
38:15 38:35 38:5729:li
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TSIANSLE LABS Text:TLI#44376 109-112 IJW. TIME - 15:54
1003
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TRIANGLE LABS Text:TLI»44376 109-112 IK7. TIME - 16:54
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392.9760 F:3 Exp-.NDBSVS
TSIANSLE LABS Text:TLH44376 109-112 UTJ. TIME - 16:54
1004 32:11 32:24 32:58 33:33 33:47 34:04 34:25
32:00 33:00
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TSIANSLE LABS TextsTLH44376 109-112
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392.9760 T:3 Exp:NDB5OS
TRIANGLE LABS Text:TLIt44376 109-112
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Voltage
SIR 70T Roiaet 1216
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TRIANGLE LASS Text :TLI#44 376 109-112
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TRIANGLE LASS Text:TLI#44376 109-113
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417.8253 F:4 BSU3(256, 30, -3. 0) PKD(7,5,3,0 .05\,2784 .0,
TRIANGLE LASS Text:TLI#44376 109-112
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TRIANGLE LABS Text:TLI#44376 109-112
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TRIANGLE LABS Text:TLI*44376 109-112 HK7. TIME ' 16:54
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TRIANGLE LABS Text.:TLI#44376 109-112 INJ. TIME - IS
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TRIANGLE LABS Text:TLI»44376 109-112
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TRIANGLE LABS Tajct:TLI#44376 109-112
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TRIANGLE LASS Tejct:TLI#44376 109-112
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TRIANGLE LASS TextsTLI*44376 109-112 JJKT. TIME - 16t54
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TRIANGLE LASS TejCt:TLIf 44376 109-113 UKT. TIMS - 16:54
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TRIANGLE LABS Text:TLI#44376 109-113 INJ-. TIME - 16:54
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TRIANGLE LABS Text:TLHf44376 109-113 IKT. TIKE - 16:54
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TRIANGLE LABS Text:TLIf44376 109-113 JM7. TIME - 16:54
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File:T980154 #1-810 Acq:6-JAN-98 16:51:52 EI+ Voltage SIR 70T
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F*ile:S980014 #1-465 Acq:l-JAN-98 11:12:02 EI+ Voltage SIR 70S
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-------
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
.Sfeg&ljag $ll!£6&$&l$!$&!$$$$S$ffi
44376
109-112
.. 1 Method 23 TCDD/TCDF Analysis (DB-225)
- '- ^ Analysis File: X9800«
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97 Spike File: SPC2NF04
194-59-2A-D Date Extracted: 12/29/97 ICal: XP24087
Date Analyzed: 01/07/98 ConCal: X980080
1.000
n/a
DB-225
Dilution Factor: n/a % Moisture: n/a
Blank File: X980083 % Upid: n/a
Analyst: KAS % Solids: n/a
AnaJytes , ,
2,3,7,8-TCDF
Internal Standard
I3C12-2,3,7,8-TCDF
Recovery Standard
13C12-1,2,3,4-TCDD
- ' A*
nu'ins) ^ro^'V**aiig&\v . ;,u«t»'/*:\;irr " ^iag«'
26.2 0.78 21:29 E_
AmL (ng) % Recovery OC Limits Ratio f)T Flags
3.3 83.4 40%-130% 0.80 21:28
Ratio/ ITT Ffegs
0.81 20:28
Data Reviewer.
01/11/98
Page 1 of 1
C3NFJ>SR rUI. LARS (S.lo3P
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:33 01/11/98
144
-------
Data Review By:
Initial ....Date...
( I \( I VP Calculated Noise Area:
2.00
The Total Area for each peak with an ion abundance ratio outside
m atio limits has been recalculated according to method requirements.
Page Mo.
01/11/98
Listing of X980085B.db£
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Na
ID.. Flags.
TCDP
304-306 DC HL 0
0.
:00 RO
17:06
17
17
17
18
18
•22
:36 RO
:44
:04
:12
18:20
18
. 18
18
1 19
, 19
19
19
19
20
20
20
20
20
• 21
21
21
21
21
21
22
22
23
DC WH 23
:30
:46
-.55
:04
:09
:14
:24
:45
:03
:10
-.26
:37 .
:49
:00
:13
:22
:29
:42
:55
:02
:42
:18
:42
304-306 29 Peaks
13C12-TCDP
316-313 DC NL 0
DC ML 18
DC WL 18
DC WL 19
DC WL 19
DC ML 19
DC WL 20
DC ML i 20
21
0.
:00 RO
:02 RO
:48
:12 RO
:43
:59 RO
:11
:25
:28
.65-0.89
1.15
0.78
0.76
0.58
0.80
0.77
0.79
0.77
0.78
0.78
0.77
0.77
0.77
0.77
0.77
0.78
0.30
0.66
0.78
0.78
0.79
0.78
0.84
0.78
0.78
0.78
0.77
0.78
0.78
0.80
0.72
4
65-0.89
1.35
7.44
0.36
0.95
0.72
0.58
0.83
0.85
0.80
391.
94,061.
1,238.
1,710.
3,613.
124,354.
105,053.
202.710.
102,563.
90.350.
195,943.
101,077.
102,093.
250,452.
123.180.
582,450.
971.
134,623.
193,233.
170,614.
28.984.
248,089.
4.255.
241,364.
181,006.
231,365.
281,883.
260,093.
158,536.
27,650.
1,053.
,293,538.
84
40
83
00
34
10
40
60
70
50
90
00
30
00
30
00
26
10
40
60
70
00
09
00
00
00
00
00
30
90
22
22
0.790-1.095
0.000
41,144
534
743
1,605
54,236
46,282
88.084
44,907
39,464
85,510
43,935
44,502
109.313
53,585
254,315
432
73,606
84.445
74,879
12,804
108,325
1,948
105.566
79,438
101,329
122.884
114,219
69,303
12.297
.90
.32
.90
.07
.70
.70
.60
.00
.60
.90
.30
.40
.00
.80
.00
.41
.10
.40
.00
.40
.00
.28
.00
.00
.00
.00
.00
.30
.70
52,916
704
1,293
2,008
70,117
58,770
114,626
57,656
50,885
110,438
57,141
57.591
141,134
69,594
323,135
538
111.022
108,788
95.735
16,180
139.264
2,306
135,798
101,568
130,036
158,999
145,879
89,233
15,353
.50
.51
.41
.77
.40
.70
.00
.70
.90
.00
.20
.40
.00
.50
.00
.35
.00
.00
.50
.30
.00
.81
.00
.00
.00
.00
.00
.50
.20
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
.797
.309
.820
.326
.342
.848
.854
.862
.874
.381
.883
.392
.396
.904
.920
.934
.939
.952
.960
.970
.978
.983
.995
.001 2378-TCDF AW
.011
.021
.026
.057
.085
.104
B
E
E
E
E
Z
B
Z
E
E
E
E
E
E
0.953-1.047
37.
6.
76.
133.
96.
78.
394.
503.
28,533.
51
74
33
09
67
22
33
94
30
12,663,
.10
15,870
.20
0
0
0
0
0
0
0
0
1
.000
.840
.876
.894
.913
.931
.940
.951
.000 13C12-2378-TCDP ISO
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:18 01/11/98
145
-------
Page No.
01/11/98
Listing of X98008SB.db£
Matched OC Peaks-/ Ratio / R«t. Tim*
Compound/
M_Z QC.Log Omit why . .RT. OK Ratio Total.Area... Area. Peak. 1.. Area.Peak.2.. Rel.RT Compound. Nan».. ID.. Flags.
316-318
21:51 RO 1.15 67.84
22:01 RO 1.03 106.77
DC WH 23:17 RO 0.28 65.35
DC WH 23:43 RO 4.25 16.73
3 Peaks 28,707.91
44.22
62.05
38.33 1.018
60.32 1.026
1.085
1.105
13C12-TCDD
332-334
DC NL
DC WH
DC WH
DC WH
0
19
20
20
21
21
21
22
22
22
22
22
:00
:07
:12
:28
:09
:37
:54
:01
-.10
:14
:29
:34
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
1
0
0
0
0
2
3
1
1
2
2
1
•52
.73
.78
.81
.95
.08
.34
.60
.21
.54
.26
.10
Above: TCDP / TCDD Follows
332-334
3 Peaks
26.64
125.15
21,002.45
24,576.20
282.86
30.25
13.56
35.97
9.40
6.60
36.37
11.72
46,075.34
52.93
9,190.25
10,977.20
152.02
35.47
25.61
32.49
6.41
0.901-1.099
11
13
72
,812
,599
159
17
7
20
5
.22
.20
.00
.81
.09
.66
.32
.31
0
0
1
1
1
1
1
1
1
1
1
1
.000
.946
.000
.013
.047
.070
.084
.090
.097
.101
.113
.117
13C12-2378-TCDD IS1
13C12-1234-TCDD RSI
Column Description.
•Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:33)
Rat.l -Ratio of M/M+2 Ions
OX -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
Rnd of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Pila-TSSOOBS 91-883 Aeqt J-J1N-1S93 lU>07t24 X gJ* Voltage SIS AutoSpec Holmmtl27777
303.9016 aaVB(356,30,-3.0) PSD(S,3, i, 0.10*,511108.0,0.00*,?,?) B3CptKOSr_TT
Sanple Textsttl#44376 105-100 Pile Textt TRXANOLB UBS
100*
A1.09S9 A1.14S9
A1.06E9
17*00 10>00 19100 30 tOO 21*00 22:00 23:00
PiletX980085 tl-883 Acyi 7-JAS-1998 18107:34 OC BI+ Voltage SIR JiutoSptc Sol*»t 110690
305.8987 BSUB(336,30,-3.0) PXD(5,3,1, 0.10*. 442760.0, 0.00*,?,?) SxpiXCOKP TT
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Sample TextiTLIt(44376 105-100 Pile Textt TRIAXOLS LABS
100* A1.S9S8
80.
60.
40.
20.
17:00 10:00 15:00 20:00 21/00 22:00
?ll»tX98008S 01-883 Ac?: 7-JAN-1998 18:07:24 OC SI* Voltage SIS AutoSpec
375.8364 BxptXCOtl?_TT
Saxple TextsTLI*44376 105-108 Pile Texti TXXABOLB LAB3
loon
33 tOO
,4.038
.3.250
.2.450
1.SS8
0.057
.5.1E8
.4.150
.3.133
.3.1S8
.1.0E8
.O.OEO
Time
.3.1S7
.3.5E7
.1.9E7
.1.3E7
.6.3E6
.O.OEO
Time
,_4.0S7
3.3E7
3.4E7
1.6E7
8. OSS
O.OEO
Time
17*00
10*00
19100
20*00
21:00
14'
-------
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319.8965 BSUB(256,30,-3.0) VKD(5,3, 1,0. 10*, 39056.0, 0.00\,pfg) SxptKOltP_TT
Sample Text:TLI044376 105-108 Pile Textt TRXASQLS LABS
100)
80.
60.
40.
70.
0
ft
A379E8
A3.03E8 A3.83B8
A*a'Frfl A1.43S8 ft
A A A A /W \ "'H*
l\ l\ - l\l\l\ A/v/TT Y\ . AAx ^
18/00 15/00 70/00 71/00 77/00
-1.5E8
.1.758^
.5.3^9
.6.3S7
.3.1S7
' ' ' 73/Oo' Time
PiletZSBOOaS tl-883 Acq: 7-JAH-1998 18 / 07 / 74 OC SH- Voltage SIS AutoSpeo Boiiet 16386
331.8936 BSU3(356,30,-3.0) tXD(5,3,l, 0.10*, 65144.0, 0. 00\,P,P) Bxp:KQRP_TT
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File:X980085 01-883 Aeq: 7-JAN-1999 18:07:24 OC SX+ Voltage SIR AutoSpec
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Sample Text:TLI«44376 105-108 file Text: TSXAOQUS LASS
100*
80:
60.
401
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17:29 18:10 18:59 19:2719:51 20:19 20:47 21:58 22^43 23:£2 ^8.3SS
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.5.558
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14S
-------
Peak Locate Examination: 7-JAN-1998:18:07 File:X980085
Experiment:XCONF_TT Function:! Reference:PFK
-------
TLI Project: 44376
Blient Sample: 113-116
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980155
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-3A-3D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01706/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
^.3,4,7,8-HxCDF
R,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF !
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7.8.9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
1.5
7.6
2.4
.3.3
5.0
2.5
1.3
EMPC 72:7 r 1
37.5 '*'**,
50.9 ''*/*
35.3
16.4
9.5
0.46
8.2
0.76
0.73
99.1 13
193 10 197
75.8 7
5.4 2
-§54- 7/16 62?- »V
45T ' 2z
-------
TLI Project: 44376
Client Sample: 113-116
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980155
internal Standards
13C12-2,3,7,8-TCDF .
13C,2-2,3,7,8-TCDD
'3C12-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C12-l,2,3.6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
3Ci2-l,2,3,4,6,7,8-HpCDD
13Cu-l,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
"CL-WJ-S-TCDD
13C,:-2,3,4,7,8-PeCDF
13C12-U,3,4,7,S-HxCDF
13Ci:-l,2,3,4,7,8-HxCDD
13Cp-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13Ci:-l,2,3,7,8,9-HxCDF
13Ci:-2,3,4,6,7,8-HxCDF
Recovery Standards
13C12-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt (ng)
2.3
3.0
3.0
3.6
3.0
2.5
3.2
4.3
9.1
AmL (ng)
3.5
3.9
3.9
5.7
3.9
Amt. (ng}
3.3
3.0
% Recovery
57.1
75.7
74.1
90.5
75.5
62.8
81.2
109
114
% Recovery
88.5
97.4
96.6
142
96.9
% Recovery
83.2
76.1
QC Limits
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%- 130%
40%- 130%
Ratio
0.75
0.80
1.51
1.53
0.51
1.16
0.45
1.04
0.92
Ratio
1.53
0.52
1.17
0.44
Ratio
0.51
0.52
Ratio
0.80
1.15
RT
25:41
26:21
29:31
30:33
33:00
33:42
36:00
37:05
40:57
RT
26:23
30:14
32:54
33:37
37:37
RT
34:18
33:31
RT
26:10
34:02
Flags
Q_
Q_
Flags
Q_
FtagQ
Fiags
Data Reviewer.
01/15/98
Page 2 of 2
X37.PSRv2.cn.LARS S.
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
152
-------
Initial ....Date...
^ I (4l £i» Calculated Noise Area:
Data Review By:
The Total Area for each peak with an ion abundance ratio outside
limits has been recalculated according to method requirements.
Listing of T9801S5B.dbf
Matched GC Peaks / Ratio / Ret. Time
Page No.
01/15/98
2.00
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
04-306
316-313
316-318
TCDD
320-322
DC
DC
NL 0
22
23
23
23
24
24
24
24
25:
25
25
25:
26:
26:
26:
26:
27:
WH 27
0
:00 RO
:40
:09
:22
:44
:01
:25
:41
:54
:06
:1S
:31
:43 RO
07
:13
:33
:50
:23
:36
.65-0.89
1.59
0.80
0.30
0.79
0.31
0.81
0.80
0.76
0 . 30
0.31
0.31
0.80
0.93
0.31
0.31
0.30
0.66
0.77
0.73
' 17 Peaks
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL, 0;
WL_ 22:
WL 23:
. WL 23:
WL 23:
WL 24:
WL 24:
24:
24:
25:
25:
26:
26:
WH 26:
WH 27:
0.
:00 RO
:41 RO
: 09 RO
31 RO
:43 RO
04 RO
26 RO
41 RO
54 RO
30 RO
41
06 RO
34 RO
52
05 RO
6 Peaks
DC
NL 0:
0.
00 RO
.65-0.89
1.17
2.60
5.82
1.26
2.70
1.46
2.13
1.28
2.24
1.17
0.75
1.56
1.14
0.37
1.08
12
14
14
72
43
51
43
62
38
24
24
61
33
26
4
3
534
2
2
65-0.89
1.03
3.
,709.
.741.
.866.
.910.
,563.
.271.
.809.
,577.
,767.
.794.
.099.
,949.
,303.
,195.
,707.
281.
,370.
849.
,419.
4.
5.
5.
15.
30.
44.
29.
53.
34.
40.
,488.
30.
6.
8.
10.
.659.
TCDF
2.
93
64
61
45
60
90
00
10
30
30
20
90
12
30
30
94
46
51 - .
31
63
04
47
38
24
90
57
10
64
87
21
43
55
96
68
37
66
/ TV
/ k\m
58
5.656
6,555
6,553
32,562
19,456
22,787
13,960
27,817
17,393
11,079
10,716
32,501
15, 110
11.748
2,087
111,
1, 462.
42.
44.
26.
1,063 .
27.
4.
.21
.04
.09
.30
.70
.90
.80
.00
.40
.30
.60
.30
.30
. 90
.46
,59
30
33
19
62
52
01
48
7
3
3
40
24
28
24
34
21
13
13
34
13
14
2
1
1
0.
,053.43
,186.57
.313.36
,348.30
,107.20
,483.10
,348.30
,760.30
,374.40
,714.40
,383.30
,999.50
,693.00
,446.90
,620.48
169.87
,908.21
0.
33.13
19.70
22.72
,424.91
17.26
3.33
378-1.073
0.000
0.383
0.901
0.910
0.924
0.935
0.951
0.961
0.970
0.977 .
0. 985
0.994
1.001 2373-TCDF AN
1.017
1.024
1.034
1.045
1.065
1.075
961-1.039
0.000
0.383
0.901
0.916
0.923
0.937
0.951
0.961
0.970
0.993
1.000 13C12-2378-TCDF ISO
1.016
1.034
1.046
1.055
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
SE
QE
QE
Q
Q
Q
Q
'Tin T?rtl T otije
0.903-1.045
0.000
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
Page No. 2
01/15/98
Compound/
M_Z.... QC.Log Omit Why
Listing of T980155B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Ar ea.Peak.i. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
M
M
AN
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
23
24
24
25
25
25
26
26
26
26
26
26
27
:55
:13
:35
:14
:30
:52
:10
:16
:23
:32
:41
:54
:20
0.78
0.78
0.78
0.78
0.78
0.79
0.79
0.78
0.79
0.76
0.78
0.78
0.75
13 Peaks
20,501
12,997
5.413
14,004
9,398
5,369
5,210
8,720
1,407
2,263
2,572
787
852
90,007
.91
.09
.63
.00
.98
.21
.00
.00
.00
.43
.81
.36
.01
.48
8,966
5,710
2,378
6,149
4,345
2,367
2,300
3,830
620
983
1,127
345
366
.31
.40
.32
.65
.89
.98
.00
.00
.00
.17
.37
.67
.26
11,535
7,286
3,040
7,854
5,553
3,001
2,910
4,390
787
1,285
1.445
441
435
.60
.69
.36
.35
.09
.23
.00
.00
.00
.26
.44
.69
.75
0.908
0.922
0.933
0.958
0.968
0.982
0.993
0.997
1.001 2373-TCDD AN
1.007
1.013
1.021
1.037
E
E
E
E
E
0.924-1.076
DC NL 0
DC WL 23
DC' WL 24
DC WL 24
24:
24:
25:
25:
25:
25:
25:
26:
26:
26:
26:
DC SN 27 :
27:
27:
27:
:00
:55
:10
:17 .
;27
:35
:01
:13
:28
:45
52
10
:23
31 '
44
02
20
33
45
14 Peaks
DC NL 0:
DC WL 24:
DC SN 24:
DC SN 24:
DC SN 25:
25:
25:
26:
26:
26:
26:
DC SN 26:
27:
0.
00 RO
09 RO
25 RO
50 RO
05 RO
15 RO
47
10
21
40
52 RO
59 RO
40
65-0.39
2.06
1.20
4.67
0.55
0.42
1.10
0.82
0.80
0.80
0.30
0.98
0.96
0.70
7 Peaks
1
116
240
186
10
25
2,106,
77.
59.
28.
42.
31.
2,373.
•54,
3,573.
1.
7.
9.
15.
3,414.
.94
.60
.99
.98
.24
.38
.43
.46
.19
.65
.16
.36
.10
.01
.81
39
01
29
04
13
10,
25,
2,106.
77.
59.
28.
42.
31.
2,373.
54.
3,573.
7.
9.
15.
.24
.33
.43
46
19
65
16
36
10
01
81
01
29
04
0.000
0.903
0.917
0.922
0.928
0.933
0.949
0.957
0.966
0.977
0.982
0.993
.1.001 37C1-TCDD SUR1
1.006
1.015
1.026
1.037
1.046
1.053
0.924-1.076
4.
2.
3.
3.
4.
20.
7.
2,821.
2,666.
46.
10.
3.
7.
5,580.
13
30
26
40
11
48
72
01
46
96
02
27
36
01
12.
3.
1,249.
1,182.
20.
5.
3.
75
47
47
78
32
53
03
11. «7
4.
1,571.
1,433.
26.
5.
4.
25
54
63
14
66
33
0.000
0.917
0.927.
0.942
0.952
0.958
0.978
0.993 13C12-1234-TCDD. RSI
1.000 13C12-2378-TCDD IS1
1.012
1.020
1 . 024 '
1.050
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
154
-------
Page No.
01/15/98
Listing of T980155B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Ar ea.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
DC NL 0
27
27
23
28
28
28
28
28
29
29
29
29
29
29
30
30
30
30
30
31
:00
:35
:51
:03
:12
:19
:34
:42
-.52
:10
:15
:27
:32
:41
:49
:05
:15
:24
:42
:52
:09
1
RO
RO
20 Peaks
DC NL 0:
' 27:
DC SN 27:
DC SN 27:
28:
28:
29:
; 29:
29:
29:
30:
30:
DC SN 30:
31:
DC SN 31:
DC SN 31:
:00
:35
:45
:58
:41
:52
:10
:15
:31
43
14
24
35
03
20
26
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
10 Peaks
DC NL 0:
28:
29:
29:
00
48
15
29
1.
RO
.32-1.78
1.37
1.23
1.50
1.44
1.60
1.37
1.48
1.09
1.47
1.48
1.44
1.48
1.49
•1.48
1.49
1.71
1.48
1.50
1.49
1.50
1.46
0.931-1.063
2.77
47,862.35
1.050.24
324.60
1,127.86
475.67
28,409.50
69,064.53
32,990.00
42,296.30
42,325.90
20,364.50
26,630.30
22.386.99
29.456.90
437.42
36,096.00.
33,304.40
1.962.78
1,025.04
2,635.26
29.092
630
191
694
275
16,967
41.980
19,629
25,220,
24,981.
12,166.
15,942.
13,353.
17,620.
276.
21,524.
19,972.
1,175.
614.
1,593.
.80
.73
.38
.11
.37
.30
.40
.30
.30
.00
.00
.90
•10
.60
16
90
40
00
23
33
23,566
419
133
433
200
11,441
38,418
13,360
17,076
17,344
8,198
10,687
9,033
11.836
161
14,571
13,332
787
410
1.091
.30
.51
.22
.75
.30
.70
.50
.20
.00
.90
.50
.90
.89
.30
.26
.10
.00
.73
.31
.93
0.000
0.935
0.944
0.950
0.955
0.959
0.963
0.972
0.978
0.988
0.991
0.998
1.001 12378-PeCDF
1.006
1.010
1.019
1.025 23478-PeCDF
1.030
1.040
1.046
1.055
SE
E
SE
E
E
E
AN
E
AN E
E
Q
440,277.04
32-1.78
1.34
2.70
3.33
3.03
1.99
1.24
2.20
2.37
1.51
1.92
1.53
2.10
0.52
1.09
1.28
3.20
32-1.73
1.11
1.39
1.53
1.55
0.364-1.136
1.31
32.'21
1.56
2.24
143.38
45.31
22.77
27.92
2.677.40
50.72
2.589 .49
32.59
1.94
9.57
2.65
2.04
5,636.36
PeCDF / PC
1.55
42,912.10
3,359.02
22,841.13
34.
116.
27.
19.
25.
1,612.
38.
1,567.
26.
5.
i(**nn i?rti T f\
H— UL> rOXXO
24.985.
2,031.
13,866.
08
08
54
61
90
63
21
40
90
32
00
35
70
12.
53.
22.
8.
10.
1.064.
19.
1.022.
12.
5.
.63
19
.18
,93
95
72
39
09
78
35
o.ooo ;
0.935
0.940
0.947
0.972
0.978
0.988
0.991
1.000 13C12-P6CDF 123
1.010
1.024 13C12-PeCDF 234
1.030
1.036
1.055
1.062
1.065
IS2
SUR2
0.939-1.022
17,927.
1,327.
8,974.
10
57
43
0.000
0.943
0.957
0.965
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Pfoone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/15/98
155
-------
Page No. 4
01/15/98
Compound/
M_Z.... QC.Log Omit Why
Listing of T980155B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Ar ea.Peak.2. . Rel.RT Confound.Name.. ID.. Flags.
A
356-358
13C12-PeCDD
368-370
363-370
HxCDF
374-376
X
AX
M
MX
AN
M
374-376
13C12-HXCDF
384-336
29
29
30
30
30
30
30
31
:37
:48
:03
:17
:26
:34
:40
:00
RO
1.54
1.55
1.56
1.56
0.93
1.57
1.55
1.58
11 Peaks
DC NL 0
28
DC SN 29
29
29
29
29:
DC SN 30:
30:
DC SN 30:
30:
DC SN 31:
:00
:48
:10
:16
:29
:38
:49
:04
:16
:25
:33
:35
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
1.25
3.14
1.96
1.11
2.23
1.99
1.63
6.07
1.34
2.34
1.53
1.54
7 Peaks
._. ... *u«
DC NL 0:
DC WL 31:
31:
32:
32:
32:
32:
X 32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:
00
46
57
05
15
23
32
44
54
02
08
20
26
31
15
18
24
48
1.
RO
RO
RO
RO
05-1.43
1.31
1.72
1.26
1.22
. 1.25
1.25
1.23
1.20
1.26
1.25
1.23
1.26
1.26
1.26
1.27
1.30
1.28
1.24
15 Peaks
DC NL 0:
31:
32:
00
57
05
0.
RO
RO
RO
43-0.59
1.27
1.06
1.17
5
15
9
5
2
4
1
2
115
1,
1
ve : i
16,
41,
3,
4,
2,
23,
12,
2,
3,
5,
1,
1,
119,
,488
,780
,721
,443
,336
,447
,078
,198
,607
1
28
6
5
22
7
. 12
4
3
3
,313
2.
,893
3ef**ir
*e*— *JL
107.
65.
599.
725.
213.
264'.
577.
449.
714.
363.
302.
713.
571.
740.
023.
260.
109.
194.
635.
.99
.11
.75
.55
.13
.93
.77
.25
.74
.15
.87
.15
.38
.11
.47
.79
.16
.95
.85
.26
.13
.33
•) / tlv
j I rm
.70
36
49
90
44
13
15
32
00
42
81
12
00 .
00
00
00
00 .
90
33
3,331
9,589
5,928
3,320
1,420
2,718
655
1,346
35
3
19
5
7
6
1,097
.46
.23
.97
.31
.00
.04
.40
.83
.54
.27
.30
.32
. 92
.46
.13
2,157.53
6,190.38
3,792.78
2,122.75
1,520.00
1,729.89
423.37
851.42
0.
11.32
2.95
8.67
2.93
4.87
3.51
716.13
0.969
0.975
0.984
0.991
0.996
1.001 12378-PeCDD AN
1.004 Q
1.015
369-1.131
0.000
0.943
0.955
0.958
0.965
0.970
0.976
0.934
0.991
0.996
1.000 13C12-PeCDD 123 IS3
1.034
*f~r\I? Ti-il 1 ,-it»fe
9,241.
22,942.
1,782.
2,369.
1,420.
245.
13,211.
6,867.
1.272.
2,072.
318.
3,200.
573.
147.
623.
.05
.80
94
63
48
46
90
68
27
'60
00
00
00
00
00
0.964-1.049
7,358.44
18,783.10
1,430.50
1,894.55
1,156.67
203.86
10,502.10
5,500.74
1,030.54
1.645.52
253.00
2,540.00
450.00
113. OO
486.00
0.000
0.963
0.963
0.972 E
0.977
0.981
0.936
0.992
0.997 123478-HxCDF AN
1.001 123678-HxCDF AN
1.004
1.010
1.013
1.016 234678-HxCDF AN
1.038
1.039 123789-HxCDF AN PR
1.042
1.055
0.879-1.121
4.
14.
34.
74
18
34
9.
26.
98
93
9.39
23.07
0.000
0.963
0.972
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:26 01/T5/98
156
-------
Page No.
01/15/98
Listing of T9801S5B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
HxCDD
390-392
390-392
i3c 12 -HXCDD
402-404
402-404
HpCDF
408-410
X
D
D
D
408-410
DC SN
DC SN
DC SN
DC SN
8
DC NL
7
DC NL
DC WL
DC SN'
DC SN
DC SN
DC SN
5
DC NL'
X
D NH
D NH
D NH
DC WH
4
32:54
33:00
33:31
33:51 RO
34:00 RO
34:18
34:31 RO
34:35 RO
34:43
34:52 RO
Peaks
1.
0:00 RO
32:26
32:52
33:06
33:17
33:38
33:43
34:02
Peaks
1.
0:00 RO
32:24 RO
32:47
32:53 RO
33:06 RO
33:15 RO
33:37
33:42
33:53
34:02
34:24 RO
Peaks
0.
0:00
36:01
36:18 RO
36:27
36:42 RO
37:05
37:21 RO
37:39
38:13 RO
Peaks
0
0
0
0
1
0
0
1
0
1
05
0
1
1
1
1
1
1
1
05
1
0
1
0
1
2
1
1
1
1
3
.52
.51
.52
.91
.49
.51
.77
.55
.48
.43
-1.43
.94
.21
.22
.22
.23
.31
.18
.22
-1 .43
.73
.81
. 10
.54
.53
.02
.17
.16
.10
.15
.75
2,069.77
2,327.49
2,239.95
3.40
1.31
1,937.10
8.46
4.67
5.12
1.12
8,636.46
: HxCDF /
9.07
4,101.94
10,164.26
6,416.78
661.45
733.20
1,142.21
1,714.13
24,933.97
4.03
2.04
3.02
3.38
15.34
4.66
1,576.14
1.369.08
9.36
2,183 .96
3.18
5,154.38
88-1.20
1
1
1
1
1
0
1
1
1
.13
.04
.04
.04
.64
.39
.27
.05
.44
5.47
4,796.03
1,309.23
683.36
7.10
9.37
12.30
338.12
19.91
7,131.74
712
785
766
654
4
4
.41
.85
.70
.64
.31
.79
1,357
1,541
1,473
1,282
5
3
.36 0.997 13C12-HXCDF 478 SOR3
.64
.25
.46
.60
.09
1.000 13C12-HXCDF 678 IS4
1.016 13C12-HXCDF 234 ALT2
1.026
1.030
1.039 13C12-HXCDF 789 ALT1
1.046
1.048
1.052
1.057
2.246.
5,582,
3,525.
364.
415.
619.
943.
10.
849.
734.
5.
1,168.
.55
,91
.36
70
.14
19
32
48
63
42
16
20
1,855
4,581
2.391
296
318
523
770
6.
726.
634.
4.
1,015.
0.
.39
.35
.42
.75
.06
.02
.31
0.
.85
.46
66
70
76
958-1.015
0.000
0.962
0.975
0.982
0.988
0.998 123478-HXCDD AN
1.000 123678-HxCDD AN
1.010 123739-HxCDD AN
970-1.030
0.000
0.961
0.973
0.976
0.982
0.987
0.998 13C12-HXCDD 473 SUR4
1.000 13C12-HXCDD 678 IS5
1.005
1.010 13C12-HXCDD 739 RS2
1.021
Q
Q
Q
Q
Q
QPR
Q
Q
u«r"^Tr t?*-si i rtue
2,439.
667.
350.
172.
74
28
51
97
2,356.
641.
337.
165.
0.998-1.053
•29
95
85
15
0.000
1.000 1234678-HpCDF AN
1.008
1.013
1 . 019
1.030
1.038
1.046 1234789-HpCDF AN
1.062
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
3^1/15/98
I i
-------
Page No.
01/15/98
Listing of T980155B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why '. .RT. OK Ratio Total .Area. .. Ar ea. Peak. 1. . Area. Peak. 2. . Rel. RT Compound. Name.. ID.. Flags.
13C12-HpCDF
418-420
418-420 '
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN.
2
NL
WH
WH
2
NL
2
NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
0:00
36:00
37:08
37:37
38:01
Peaks
0:00
36:18
37:06
37:28
37:38
Peaks
0:00
36:18
37:05
Peaks
0:00
35:38
36:15
37:16
37:27
37:34
37:44
37:51
38:15
38:22
38:55
39:06
39:34
39:49
40:09
40:31
40:35
40:49
40:54
41:10
41:27
41:50
Peaks
0
RO
RO
0.
RO
RO
RO
0.
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.37
0
0
0
0
0
.88
1
1
1
3
2
38
1
1
1
76'
0
1
0
1
1
'o
0
2
0
5
0
1
1.
2.
0.
0,
0,
0.
0.
-0.51
.88
.45
.45
.44
.31
-1.20
.77
.03
.02
.21
.28
-1.20
.40
.07
.04
-1.02
.91
.64
.77 -
.03
.46
.98
.73
.48
.15
.00
.97
.01
.12
.29
.30
,57
.58
.40
.33
0.84
0.36
0.80
1
1,580
1
1,194
4
2,775
.94
.58 487.08
.46
.97 362.89
.22
•55
D / u»*s~nn v+^.^ i »..».
0.944
0
1,093.50 1
1
332.08 1
1
-1.111
.000
.000 13C12-HpCDF 678
.031
.045 13C12-HpCDF 789
.056
IS6
SUR5
0.976-1.006
0
1,285
1,120
2
2
2,406
.98
.41 653.73
.63 566.54
.43
.28
.04
0
631.68 0
554.09 1
• ' 1
1
.000
.979
.000 1234678-HpCDD
.010
.015
AN
0.973-1.027
2
12
1.713
1,726
.12
.58 6.50
.98 .873.72
.56
HpC DD / Oc c a -C DD and C DF
0.
1.
12.
1.
0.
0.
0.
0.
0.
0.
1.
17.
1.
0.
1.
1.
0.
1.
0.
322.
32.
2.
372.
.38
15
21
46
53
93
93
76
42
11
44
38 8.99
23
32
62
02
79
06
76 '
30 147.61
07 . 14.87
68
25
0
6.08 0
840.26 1
.000
.979
.000 13C12-HpCDD 678
IS7
0.902-1.093
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
8.89 0.
0.
0.
0.
0.
0.
0.
0.
174.69 1.
17.20 1.
1.
000
370
885 .
910
915
917
921
924
934
937
950
955
966
972
930
989
991
997
999
005 OCDF
012
022
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09
15/98
-------
Page No.
01/15/98
Listing of T9801S5B.dbf
Hatched OC Peaks / Racio / Ret. Time
Compound/
J1_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area. .. Area.Peak.1.. Area.Peak.2.
FJDD
Rel.RT Compound.Name.. ID.. Flags.
458-460
453-460
: . 0.76-1.02
DC NL 0:00 RO 1.42 0.23
40:57 0.81 445.68
DC SN 41:17 RO 1.11 3.42
1 Peak . 445.68
199.35
0.902-1.098
0.000
246.33 1.000 OCDD
1.008
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.26
40:57 0.92 2,441.31
DC WH 41:29 RO 0.61 3.80
470-472 1 Peak 2,441.31
1,168.53
0.998-1.006
0.000
1,272.78 1.000 13C12-OCDD
1.013
I S3
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
A3.36X8
r±le:T9801S5 #1-810 Ac~1 _ >\ / k
26:00
37:00
.3.9X6
.3. 1E6
.2.4X6
.1. 6E6
.7.8E5
.0.0X0
Time
.1. 8X7
.1.4E7
.1.1X7
7.3X6
3.6X6
.0.0X0
Tiae
1. 7X5
1.3X5
1.0X5
6.7X4
3.4X4
0.0X0
Tiae
160
-------
rile. -1980155 #1-810 Acq:6-JAlT-98 17.-J7.-J8 EH- Voltage SIS 70T Hoiaa: 752
319.8965 T:2 BSUB(256, 30, -J. 0) PKD(7,S,3,0.05\,3008.Q,1.00\rr,T) XxpiXDBSUS
TRIANGLE LASS Tajct:TLIt44376 113-116 ISJ. TIME - 17:40
100J
80:
SO:
40:
20:
0
AS. 7 1X7
A AS. 15X7
M A2.38S7 \ A4.3SE7
A A AA
24:00 25:00
rile:TS80155 #1-810 AcqsS-JKK-98 17.-J7.-J8 XI+
321.8936 r:2 BSUS(256, 30, -3. 0) PXD(7,5,3,0.05*
TRIANGLE LASS Text: TLH44376 113-116
1001
80:
so:
40:
20:
0
ft
ft
A7.29X7
\ A A7.85E7
\ \\ A3. 04X7 \A5.55E7
l\ A A AA
24\00 25:00
F±J.e:T980155 #1-810 Ac
-------
rLle:T980155 #1-810 Acq : 6 -JAN- 9 8
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TRIANGLE LABS Text:TLI»44376 113-116
1001
80:
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401
201
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TRIANGLE LABS Text:TLI#44376 113-116
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TRIANGLE LABS Text:TLI#44376 113-116
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TRIANGLE LABS Text:TLI#44376 113-116
1001
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TRIANGLE LABS Text:TLI*44376 113-116
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TRIANGLE LASS Text:TLI#44376 113-116 OKI. TIME - 17:40
1003
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375.8178 T:3 BSUB(256,30,-3.0) fXD(7,5,3,0.05\,93448.0e1.00\l
TSIANSLE LASS Text:TLI#44376 113-116
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383.8639 F:3 BSUS(256,30, -3. 0) PXD(7,S,3, 0. 05%, 7960. 0,1.00\,r,T) Exp:NDB5aS
TRIANGLE LASS Text:TLI»44376 113-116 XKT. TIME » 17:40
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TRIANGLE LABS
1001
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60.
40:
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392.9760 F:3 Exp-.NDBSOS
TSIANGLE LABS Text:TLI#44376 113-116
1003
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40:
30:
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32:10
32:28
32:58 33:10
33:33
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32:00 33:00
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TSIANSLX LABS Text :TLI #44376 113-116 J2KT. nxff - 17:40
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401.8558 T:3 BSUB(256,30, -3. 0) PXI>(7, 5,3, 0.051,6300.0,1.00*,?, T) Exp:lO3S5US
TRIANGLE LASS T&xt:TLI#44376 113-116 ! TJK7. TIME - 17:40
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TRIANGLE LABS Tejct:TLH44376 113-116 | IHJT. TIME - 17:40
1003
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392.9760 T:3 Exp-.NDBSOS
TRIANGLE LABS Text:TLI#44376 113-116
lOOi
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TRIANGLE LABS Text:TLI#44376 113-116
1001
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TRIANGLE LABS Text:TLI#44376 113-116
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417.8253 F:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 051,2372. 0,
TRIANGLE LABS Text:TLI#44376 113-116
1001
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419.8220 T:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,2696. 0,
TRIANGLE LABS Text:TLI#44376 113-116
1001
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430.9729 F:4 Exp-.NDBSUS
TRIANGLE LABS Text:TLI#44376 113-116
1001
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479.7165 F:4 Exp : NDBSUS
TRIANGLE LABS Text:TLI#44376 113-116
1001
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60:
40:
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35:15
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TRIANGLE LASS Text:TLIt44376 113-116 UKT. TIME - 17:40
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TRIANGLE LABS Text:TLIt44376 113-115 JW7. TUtE - 17:40
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441.7428 T:4 BSUB(256, 30, -3. 0) tKD(7,5r 3, 0.05\,832. 0,1. 00\,r,T) StpilWBSaS
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TRIANGLE LABS Text:TLI*44376 113-116 IJKT. TIME " 17:40
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.6.0E4
'-.3.0X4
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rile:T980155 fl-563 Acq : 6 -JAJT- 9 8 17:37:38 EH- Voltage SIX 70T
430.9729 f:4 Erp:NDB5OS
TRIANGLE LABS Text:TLI»44376 113-116 ZK7V TIME - J7.-40
100*
901
801
701
601
501
401
301
201
101
01
35:20 te ** 36:40 37:28 38:37 39:07 39:40 40:39 41:17 41-53
_. A/U^ 35:55 A»i., «_A* A « JVL tfV. irfV^vM^^AAA^AATAVAiA^^AA/V »JLA .UJU>^. A/V..^
,^/vvvVNv^%^AV^9 1
33,23 38,42 II 39 4i
36:34 l\\
1 11 ^ Q . J ff
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36'tOO 37\00 38\00 39:00 ' 40s 00 41; 00 42\00
6.8E3
'-.6.1X3
15 . 4E3
.4.7X3
'.4.1E3
.3.4X3
12.7X3
.2.0X3
.1.4X3
.6.8X2
0.0X0
Time
168
-------
40:54 , 41': 00 41:06 41:12 41:18 41':24
rile:T9B01SS »l-563 Acq:6-JAN-98 17:37:38 EH- Voltage SIS 70T Soiae:66
469.7779 F:4 BSUB(256, 30, -3 . 0) PJOJf 7, 5, 3, 0. 051,264 . 0, 1. 00\,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI»44376 113-116 XK7. TIME - 17:40
FiJ.a:T980155 tl-563 Acq:6-JAN-9B 17:J7:Ja SZ-f voltage 313 70T Noiae:aj
457.7377 T:4 BSUB(256,30, -3. 0) PKD(7,5,3, 9.051,332. 0,1.00\,r,T) Xzp:RDB5US
TSIAXSLE LABS Text:TLIt44376 113-116 HKT. TIME - 17>40
1004 A1.39E6
80.
60.
40.
20.
41:24
40:54 41:00 . 41:06 41:12 41:18
rila:T980155 tl-563 Acq: 6-JZN-98 17:37:38 SI+ Voltage SIS 701 Koiae: 62
459.7348 T:4 BSUB(256,30, -3. 0) PJO3(7,5,3, 0.05%,248.0,1.00\,r,T) ExpiRDBSOS
TRIANGLE LABS Text:TLI#44376 113-116 IXT. TIHE - 17:40
1001 A2.J6E6
1003
80J
69-
20.
Al.
41:24
40:54 41:00 41:06 41:12 41:18
rile:T980155 tl-563 Acq: S-JTUT-98 17:37:38 EI+ Voltage SIB 70T Noise: 64
471.7750 F:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0.051,256.0,1.00\,f,T) Exp:NDBSUS ,
TRIANGLE LABS Tejct:TLI#44376 113-116 XKJ. TIME - 17:40
1004
40:54 41:00 41:06 41>12 41:18 41:24
rlle:T980155 tl-563 Acq:6-J7Uf-98 17:37,38 EX+ Voltage SIX 70T
430.9729 T:4 ExpsSDBSVS
TRIANGLE LABS Text:TLI#44376 113-116 HIT. TIKE - 17:40
3.6ES
.2.9E5
.2.2E5
.1.5E5
'.7.3E4
41:30
Lo.oro
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..4.6E5
.3.7E5
.2.8E5
_1. 8E5
'.9. 2E4
'.O.OEO
41:30 Tiae
2.1E6
'.1. 7E6
11.3E6
L8.5£5
14.2ES
f n nvn
41:30 Time
-2.4E6
.1.9E6
.1.4E6
.9.5E5
.4.8E5
41:30
O.OEO
Time
1001
80.
60.
40.
20.
0.
40:55
41^28
S.6E6
.4.SE6
.3.3E6
.2.2X6
.1.1X6
0.0X0
40:54
41:00
41:06
41:12
41:18
41s 24
41:30
168
-------
fl:
I ;<8,3732 Peak top
Height 3,59 alts Span 298 ppa
Systea f iis nae
Data file name
Resoiutlon
Groupnuaber
lonizoticn aode
Syitching
Ref, aasses 292,3825,
R 293 . J 331
8 384 K 332
2
El*
VOLTflGE
D 318
E
F
318
329
G 322
H 328
I 331
L 334
R 348
H 342
0 352
P 354
Q 356
R 358
S 368
T 378
II 376
V 418
Ref, iass " 416,9768 Peak top
Height ,36. wits Span 298 ppa
170
-------
file:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI + Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
iample Text:TLI#44376 113-116
INJ. TIME =
17:40 File Text:TLI#44376 113»
_9.6E6
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25:48 25:54 26:00 26:06 26:12 26:18 26:24 26:30 26:36
INJ. TIME =
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116
100% A4.89E7
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File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EH- Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100%, 26L10
80
60 j
40J
20 j
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26:21
26:42 26:48 26:54 27:00 Time
17:40 File Text :TLI#44376 113s>
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26:42 26:48 26:54 27:00 Time
-------
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
339.8597 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100%, 2&U.2 „„ _29:15
17:40 File Text:TLI#44376 113»
_6.3E7
0
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28:48 29:00 29:12 29:24
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351.9000 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100% 29
80J
60 j
40J
20J
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29:36
29:48
Time
28:41
17:40 File Text:TLI#44376 113»
4.6E6
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L2.8E6
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;L9.2E5
28:36 28:48 29:00 29:12 29:24
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
409.7974 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100%,
80J 29:27
60 j
40J
20 j
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29:36
17:40
29:33
29:48
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28:34
File Text:TLI#44376 113»
.-3.5E4
29:44 f\(fi fi2.8E4
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-------
me:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
339.8597 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100% 30jl5
80J
60J
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201
0
17:40 File Text:TLI#44376 113»
_4.7E7
30:00 30:06 30:12 30:18 30
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
351.9000 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME
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80J
60J
40j
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30:30
Time
Oj
17:40 File Text:TLI#44376 113»
3.7E6
L2.9E6
L2.2E6
L1.5E6
L7.3E5
30:00 30:06 30:12 30:18 30
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 El-f Voltage SIR 70T
409.7974 F:2 Exp:NDB5US
Sample Text:TLItt44376 113-116 INJ. TIME =
100%, 30.; 20
=T==T - .
24
30:30
LO.OEO
Time
80j
60J
40J
20j
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30:05
File Text :TLI#44376 113»
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30:18
30:24
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Time
-------
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
339.8597 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100% 30:42 31;09
17:40 File
Text:TLI#44376 113»
_4.2E6
17:40 File
30:36 30:42 30i48 30:54 31:00 31:06 31:12 31:
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
351.9000 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
1001 31j08
80 j
60 j
40J
20 j
OJ
T
T
~1 1 1 1 1"
30:36 30:42 30:48 .30:54 31:00 31:06 31:12 31:
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
409.7974 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME = 17:40 File
100% 30j53
:.O.OEO
31:24 Time
Text:TLI#44376 113»
2.0E4
11.6E4
L1.2E4
i.8.1E3
L4.0E3
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Time
18
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Time
-------
?-ile:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
355.8546 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116
100%
INJ. TIME =
17:40 File Text:TLI#44376 113»
29:36 29:48 30:00 30:12 30:24 30:36
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI + Voltage SIR 70T
357.8516 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100%
30:48
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31:00
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Time
17:40 File Text:TLI#44376 113»
..1.9E7
29:36 29:48 30iOO 30il2 30i24 30:36
File:T980155 #1-810 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
367.8949 F:2 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
1004 30:33
80J
eol
40J
20 j
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30:48
31:00
Time
29:36
29148
30:00
30:12
30:24
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_4 .1E6
_3.2E6
30:36
30:48
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11.6E6
L8.1E5
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Time
Ul
-------
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116
100% 32;32
60j
40J
20j
Oj
INJ. TIME = 17:40 File Text:TLI#44376 113»
_4.5E6
_3.6E6
_2.7E6
1.8E6
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32:26 32:28 32:30 32:32 32:34
File:T980155 #1-396 Acq:6-JAN-98 17:37
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116
10 0%
80J
40J
20 j
32:36 32:38 32:40 32:42 32:44 32:46 32:48
38 EI + Voltage SIR 70T
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INJ. TIME = 17:40 File Text:TLI#44376 113»
32;39 _1.6E4
32:44
32:48
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L9.7E3
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32126 32:28 32:30 32:32 32:34
File:T980155 #1-396 Acq:6-JAN-98 17:37
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116
100%
80j
32:36 32:38 32:40 32:42 32:44 32:46 32:48 Time
38 EI+ Voltage SIR 70T
INJ. TIME = 17:40 File Text:TLI#44376 113»
32;44
32:26 32:28 32:30 32:32 32:34
32:36 32:38 32:40 32:42 32:44 32:46 32:48
0
-------
Flle:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
32:54
17:40 File
Text : TLI#44376 113»
_3.5E7
32:54 33:00 33:06
Pile:T980155 #1-396 Acq:6-JAN-98 17:37:38 EH- Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
33 :12
17:40 File
32:54
33:00
Time
Text:TLI#44376 113»
r2.3E6
Ll.8E6
L1.4E6
L9.2E5
C.4.6E5
33:12
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Time
32:54 33:00 33:06
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text :TLI»44376 113-116 INJ. TIME = 17:4.0 File Text: TLI#44376 113»
lOOi 33;09
60
40J
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32:54
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33:00
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33:06
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L2.8E4
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Time
-------
ile:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME
100% 33j31
80J
60J
40J
201
33:20
33:18 33:24 33:30 33:36
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME
100% 33j.31
80J
60J
40J
20J
0
33:18 33:24 33:30 33:36
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME
100% 33;26
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60J
40J
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17:40 File Text : TLI#44376 113»
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33:42
lO.OEO
Time
17:40 File Text:TLIS44376 113»
2.5E6
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L1.5E6
L9.9E5
L4.9E5
33:42
LO.OEO
Time
17:40 File Text :TLI#44376 113»
33:18
33124'
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33:30
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33:36
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33:42
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L4.6E4
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Time
OO
-------
File:T9B0155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI»44376 113-116 INJ. TIME
100% 34:15 34:24
34:06 34:12 34:18 34:24
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME
100% 34 iJ.8
80J
60J
40J
20 j
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17:40 File Text:TLI#44376 113»
_1.7E6
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34:30 Time
17:40 File Text:TLI#44376 113»
Ll.4E6
11.1E6
L7.1E5
L3.5E5
34:06 34:12 34:18 34:24
File:T980155 »l-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME
100% 34jl5
80J
60 j
40J
34:30
LO.OEO
Time
17:40 File Text :TLI#44376 113»
OJ
L3.1E5
L2.4E5
L1.6E5
L7.9E4
34:06
34:12
34 :18
34 :24
34 :30
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Time
CD
-------
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100*. A3.20E7
17:40 File Text:TLI#44376 113»
_9.8E6
0
i i I i i i i i
33124
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100*. A2.54E7
17:40 File Text:TLI#44376 113»
7.6E6
L6.1E6
L4.6E6
L3.0E6
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33:18 33:24 33:30 33:36
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
33:31
33:42
33:48 Time
17:40 File Text :TLI#44376 113»
80J
601
40J
20 j
"• 1 r
33:18
33:24
33:36
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33:42
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L1.5E6
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33:48 Time
on
-------
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI»44376 113-116 INJ. TIME =
100%, A5.73E6 A6.23E6
17:40 File Text:
TLI#44376 113»
_1.7E6
34:06 34:12 34:18 34:24 34
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI + Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text :TLI#44376 113-116 INJ. TIME =
100%. A4.__.
A4 .86E6
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34:36
17:40 File Text
34:06 34:12 34:18 34:24 34
File:T980155 #1-396 Acq:6-JAN-98 17:37:38 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 113-116 INJ. TIME =
100% 34^18
80J
60J
40J
20 J
34:36
LO.OEO
Time
TLI#44376 113»
1.4E6
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L2.8E5
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Time
17:40 File Text:TLI#44376 113»
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34:06
34 :12
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34:18
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34 :24
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34 :30
34:36
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Time
r/5
-------
^K^^l^»^^^^»^#^^^^»i]
TLI Project: 44376 „ . Method 23 TCDD/TCDF Analysis (DB -225)
Client Sample: 113-116 - L: - Analysis File: X9800$i
Client Project: Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-3A-3D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000 Dilution Factor: n/a
Dry Weight: n/a Blank File: X980083
GC Column: DB-225 Analyst KAS
Spike File: SPC2NF04
ICal: XF24087
ConCal: X980080
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
'Anafcte* ', , ; -/- ',/foi*. fr$) r ' * ' Ot ; , £Mf»C -vV ;^^ ^ 'Ral^' ; m ?teg*
2,3,7,8-TCDF
Internal Standard
I3C12-2,3,7,8-TCDF
Recovery Standard
13C12-1,2,3,4-TCDD
28.4
Ami (ng) % Recovery OC Limits
3.7 92.8 40%-130%
.
0.77 21:31 E_
Ratio- 8T Flags
0.80 21:30
Ratio ITT Flags
0.80 20:29
Data Reviewer.
01/11/98
Page 1 of 1
CNFJ>SR »101. LARS «.10.oS
Triangle laboratories, lnc.9
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:34 01/11/98
1S2
-------
. . ..Date...
Data Review By:
Calculated Noise Area: 2.00
^
M
he Toeal Area for each peak with an ion abundance ratio outside
atio limits has baeo recalculated according to method requirements.
Page No.
01/11/98
Listing at X980086B.dbf
Hatched CC Peaks / Racio
/ Ret. Time
Compound/
M_2 QC.Log emit Why . .RT. OX Ratio Total. Area. .. Area.Peak.1.. Area. Peak. 2. . Rel.RT Compound. Name.
ID.. Flags.
TCDP
0
304-306 DC NL 0:00 RO
17
17
18:
18:
18:
18
18
18:
19:
19:
'. 19:
1 19:
19:
20:
20:
20:
, 20:
• 21:
21:
21:
21:
21:
22:
22:
23:
:07
:4S RO
:06
:14
:22
:32
:48
;56
;05
ill
:15
25
46
11
27
38
51
01
24
31
43
56
03
43
20
304-306 25 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL ' 17:
DC WL 17:
DC WL 18:
DC WL 19:
DC WL 19:
DC WL 19:
DC WL 20:
DC WL 20:
21:
21:
22:
22:
22:
0.
00
15 RO
44 RO
49
14 RO
45
58 RO
11
25
30
41
03 RO
16 RO
23 RO
.65-0.89
3.31
0.77
0.35
0.75
0.76
0.77
0.76
0.77
0.77
0.76
0.78
0.78
0.77
0.77
0.78
0.78
0.78
0.77
0.77
0.76
0.77
0.75
0.76
0.74
0.75
0.65
5
65-0.89
0.87
0.63
0.60
0.85
1.04
0.71
0.98
0.79
0.71
0.80
0.73
1.41
0.35
0.62
0.790-1.095
574
116,025
2,494
161,420
129.175
249,431
129,230
110,073
240,976
120,913
125,140
312,161
148,805
700.501
239,059
228,416
207,795
35,661.
298,266.
286,423.
213,794.
272,057.
334,338.
309,011.
192,220.
34,072.
,202,512.
.90
.40
.02
.90
.10
.00
.30
.20
.00
.50
.90
.00
.30
.00
.00
.70
.60
.20
.00
.00
.00
,00
,00
,00
,50
,30
,42
50,
1,
69,
55,
108,
55,
47,
105,
52,
54,
136.
64,
305,
104,
99,
90,
15,
129,
123,
95,
117,
144,
131,
82,
13,
642
084
328
879
351
900
989
194
364
653
615
840
391
430
850
313
535
730
326,
023,
013.
169,
867,
635,
463.
.20
.97
.50
.00
.00
.30
.90
.00
.50
.30
.00
.90
.00
.00
.70
.60
.50
.00
.00
.00
.00
,00
,00
.50
.30
65,383.20
3,108.52
92,
73,
141,
73,
62,
135,
68,
70,
175,
83,
395,
134,
128,
116,
20,
168,
162,
123,
155,
190,
177,
109,
20,
092.40
296.10
130.00
330.00
083.30
782.00
549.00
487.10
546.00
964.40
110.00
529.00
566.00
982.00
125.70
536.00
597.00
771.00
044.00
169.00
144.00
585.00
604.00
0.000
0.796
0.826
0.842
0.848
0.854
0.862
0 . 874
0.381
0.388
0.392
0.395
0.903
0.919
0.939
0.951
0.960
0.970
0.978
0.995
1.001 2378-TCDP AN
1.010
1.020
1.026
1.057
1.085
B
S
X
E
S
E
E
E
' E
Z
S
S
S
E
3
0.953-1.047
46.
95.
23.
104.
215.
59.
139.
535.
601.
31,912.
117.
88.
37.
54.
.24
19
98
29
.23
04
44
38
12
10
24
46
40
02
14,224.
49.
70.
16.
23.
70
40
27
27
50
•
17,687.40
67.34
49.98
47.12
38.16
0.000
0.302
0.325
0.875
0.895
0.919
0.929
0.939
0.950
1.000 13C12-2378-TCDP ISO
1.009
1.026
1.036
1.041
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:19 01/11/98
1S3
-------
Page HO. 2 Listing of X980086B.db£
01/11/98 Matched GC Peaks / Ratio / Rat. Tim*
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Nam*.. ID.. Flags.
DC WH 23:17 RO 0.97 164.47 1.083
DC WH 23:45 RO 2.58 81.84 1.105
316-318 5 Peaks 32,209.22
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.39 0.901-1.099
332-334 DC NL
0:00 RO 1.55
19:08 RO 0.97
20:13 0.78
20:29 0.80
21:10 0.73
22:40 RO 0.16
46.76
112.98
23.545.00
24,697.60
308.78
33.61
61 . 88
10,341.30
11,005.90
130.24
0.000
63.83 0.946
13,203.20 1.000
13,691.70 1.013
178.54 1.047
1 . 121
13C12-2378-TCDD 131
013 13C12-1234-TCDD RSI
DC WH
332-334 4 Peaks 48,664.36
Column Description 'Why* Code Description QC Log Desc.
M_3 -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:33) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
Pil»:I9BOOaS H1-3B3 Acyt V-jAB-iSSB 1D-01,1B OC M* Volttgt SIX Autosptc Holm*,613994
303.9016 SSUB(256t30,-3.0) PXD(5,3,l,0.10*,2475936.0,0.00*tP,r) XxptKOSPJTT
3»apl* T*xt:TLI044376 113-116 P±l» T«JTt» TRIAKOU XJLB3
80.
40.
70.
A1.37B9
A1.08B9
A1.30E9 A1.44S9
A1.24B9
JL3.99EB
A8.26B8
A1.35B8
/V
17<00 1S>00 19tOO 20,00 41*00 27tOO
Pil*:X980086 #1-883 Aeg> 7-J1S-1998 19s01s48 OC XX+ Volttga SIR AutoSpuc Noiao,162401
305.8987 BSUB(2S6,30,-3.0) PSD(5,3,1,0.10*, 649604.0,0.00\,?,P) S*p:XCOSP_tr
5aapl« T*Xt:TLI*44376 113-116 ttl» Ttort: TRIANGLE LAB3
J0« A3.95S9
17:00 13': 00 19:00 20:00 21:00 22:00 23:00
Pll»:X9aOOB6 tl-883 Acy: 7-JAS-1998 19,01,48 OC ST* Voltug* SIR Auto3p»c Soia«tl0746
315.9419 BSUB(256,30,-3.0) PXD(5, 3, 1, 0.10*, 42984.0, 0. OOX,P,P) SxptKONP_TT
T»3Ct>TLI#44376 113-116 Pile Toxti TRIANOLB LASS
10(3
80.
60.
40.
20.
17:00 18:00 19,00 20:00 21:00 22:00 23:00
Pll»tX980086 #1-883 Acq: 7-JAN-1998 19:01:48 OC BI+ Valtago SIR AutoSpac Hoiao:1237S
317.9389 BSUB(256,30,-3.0) PXD(S,3, 1, 0.10%, 49500.0, 0. 00\,P,f) SxpsXCOSP_TT
Saapl» T*xt:TLI#44376 113-116 Pil» T
-------
flla
319.
Samp
iocs
80.
60^
40.
20.
0
Pila
321.
-gjttfrr
1009
80.
60.
40.
20:
0
Plla
327.
Soap
100*
80.
60.
40.
20:
0'
Pile
331.
Soap
iooa
80.
60.
40.
20.
0
Pila
333.
3aap
10(K
80.
60.
40.
20.
0
8965 B3UB(256,30,-3.0) PXD(5,3,1. 0.10*. 44492.0, 0. OOt.P.P) Sgp t XCOSP_TT
If Taxt:TU944376 113-116 Pila Tmjtfi TRXASQLB LABS
1
A5.17S8
\ \ 1
I
A2.66E8 A4.9SS8
1 1 H A3. 10S6 ,. aci,a t*\
II 11 Ml /A — .
10:00 15>00 20:00 21:00 22:00 23\00
1X980086 91-883 Acqt 7-JAB-1998 19:01:48 OC SI* Voltage SIX AutoSpac SOimm:24010
8936 BSUB(2S6f30, -3.0) PKD(S,3,1.Q.10*,96040.0,0.00\,P,P) Bxp t XCC3KP_TT
If Taxt:TLI944376 113-116 Pila Taxt: TXIABOLB LABS
J-
A6. 65S8
1
A3.44B8 A6.3SS8
1 1 AA2 68SS /S
(1 n T\ A2.38B8 l\ . .
11 f\hT\ A, /A — .. .
18:00 15<00 Zo'tOO 2l':00 22\00 23\00
1X980086 91-883 Aeq: 7-JJLN-199B 19 1 01: 48 OC EH- Voltagt SIR JLutoSpec Solf»:20929
8847 BSUB{256>30,-3.0) PKD(S, 3, 1, 0.10%, 83716. 0, 0. 00*,P,P) Exp:XCONF_TT
la Taxt:TLI#44376 113-116 Pilf Taxt, TRIANQLE LABS
A2.BSE8
A2.22EB 1
A
A1.26E8
"•r i
. .' l\ "-x* , AlUl A
18:00 15:00 So'iOO 21:00 22:00 23:00
1X980086 91-883 Acq: 7-JAN-1998 19:01:48 OC EH- Voltage SIS AutoSpec Soiaf:2048S
9368 BSVB(2S6,30,-3.0) PXD(S,3,1, 0.10%, 81940. 0, 0. OOt,P,P) Bxp:XCOSP TT
la Taxt:TLI944376 113-116 Plla Taxt: TRIAHQLS LABS
A1.10S8
A1.03E8 \
In
•
11
18:00 15:00 70:00 71:00 72:00 23:00
1X980086 91-883 Acq: 7-JAH-1998 19:01:48 OC SIf Voltaga SIX AutoSpac Soitat 13212
9338 BSVB(256,30,-3.0) PXD(5,3, 1. 0.10*,52848. 0, 0. 00*,P,P) SxptXCOUP TT
la TaxtiTLI944376 113-116 Pila Taxt: TRIASOLS LABS
A1.3&f?7S8
All
10:00 15:00 20:00 21<00 22:00 23:00
-2.1B8
.1 . 7E8
.1.250
.8.3E7
.4.2B7
O.OEO
Tima
2.7B8
.2.1E8
'.1.6EB
.1.1S8
.S.3E7
' O.OEO
Tima
6.6B7
.S.3E7
'.4.0E7
'.2.6E7
'.1.3E7
'.O.OEO
Tima
-2.9E7
-2.3E7
-1.8E7
-1.2E7
.5.8E6
O.OEO
Tima
-2.8B7
-2.1E7
-1.4B7
-7.1B6
O.OEO
Tima
186
-------
Pllo:I980086 01-883 Acq, 7-JAN-1998 19,01,48 OC SI* Voltage SIR AutoSpec
303.9016 SxptXCOHF_TT
Saaple Text,TLI044376 113-116 Pile Text: TRIANOLS LASS
10031 19146
80:
60:
40:
20:
o:
A
""
.«.
17:00 ' """ 18:00 r ' 15:00 20/00 21/00 22/00
Flle,X980086 01-883 Acq, 7-JAN-1998 19,01,48 OC SI* Voltage SIS AutoSpec
315.9419 Sxp,XCOHF_TT
Staple Teate,TLI044376 113-116 file Text: TSIAKOLS LABS
23sOO
1003
80:
60:
40:
20:
21t30
17:00 18/00 15/00 20:00 21:00 22:00
Flle,X980086 01-883 Acq: 7-JAK-1998 15:01/48 OC SI* Voltago SIR AutoSpec
319.8965 S3CpiXCONP_TT
Saaple TexttTLI044376 113-116 Pile Text, TRIAKOLS LASS
100* 17;57
18:30
23»o
ao:
15:10
20:30
17:00 18:00 15:00 20:00 21:00 22:00
Plle:X9S0086 01-883 Acq: 7-JAN-1998 19:01:48 OC SI* Voltage SIR AutoSpec
331.9368 5jrp:XCOMF_rr
Saaple Text:TLI044376 113-116 Pile Text, TRIANOLS LABS
lOOt
80:
60:
40:
so:
o:
-F*f
3300
17:00 18:00 15:00 20:00 21:00 22:00
Wl«:X5800Sff #1-883 Acq, 7-JAN-1998 15:01/48 OC SI* Voltage SIR AutoSpec
252.5825 Bxp, XCONP_TT
Saaple Text,TLI044376 113-116 File Text: TRIAHOLS LASS
100H 17:33 18.-00 lfl:31 15:05 __ 2fli5jLZU22__ 33:0033^35
• ^->T— y ~ V
80: V
60:
40.
20:
oj
23«00
33:01
30': 00 21/00 22/00
File, 1980086 01-883 Acq, 7-001-1998 19,01,48 OC SI* Voltage SIR AutoSpec
330.9792 SxpiXCOSF TT
Saaple Text,TLI044376 113-116 File Text, TRIANOLS LABS
10031
so:
60:
40:
20:
o.
17/55
18,41
20,23 20J542H18
22,12
23:00
23,01 23,31
17': 00
15<00
21iOO
22<00
23:00
,.4.758
f
1.3.858
•.2.858
Ll.558
t
f.9.5B7
0.050
Tlae
3.457
1.2.757
12.057
^.1.357
L*. 75*
0.050
2.158
Ll.758
Ll.258
18.357
14.257
0.050
Tlae]
2.557
L2.457
.1.857
.1.257
-5.9B6
0.050
Tlmei
-6.4B8
\-5.1S8
t
13.558
.2. tfSS
.1.358
0.050
TlMO\
^7.158
.5. 758
.4.358
.2.858
.1.458
0.050
Tlam\
1S7
-------
Peak Locate Examination: 7-JAN-1998:19:00 File:X980086
Experiment:XCONF_TT Function:! Reference:PFK
00
CO
-------
TLI Project: 44376
Client Sample: 121-124/219 -
T
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980157
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-5A-D/ Date Extracted: 12/29/97
Date Analyzed: 01/06/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3.4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
^,3,4,7,8-HxCDF
P-,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF :
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3.4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (ng) DL EMPC
2.5
14.3
17.0
31.2
55.3
98.8
79.8
EMPC *33- ?-<
EMPC &?T§ ?zo
EMPC 9*§- 7 Zo
V*2* :> 2 o
7&2- 72,0
107 -72. 0
7.2
39.9
52.4
1 A>
AmL {ng) Number DL EMPC
3-39 ^ 12
YKT 770 8 3S2 72-0
452 '20 7
Ifc*96 '^^ 2
356- "-^ 8 K*T ^^
50^ 72° 6 ttW ^s^
6tt 7^6 12 £&& 7so
239- > 2
-------
TLI Project: 44376
Client Sample:. 121-124/219
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980153^
Internal Standards
13C,2-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13Ci:-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
I3C,2-l,2,3,6,7,8-HxCDD
I3C,2-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
I3C,2-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL.-2,3,7,8-TCDD
13C,2-u]3X7,8-HxCDF
l3Ci:-l,2,3,4,7,8-HxCDD
13Cp-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13Ci2-l,2,3,7,8,9-HxCDF
13C,:-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
l3C,2-l,2,3,7,8,9-HxCDD
Amt (ng)
1.8
2.5
2.7
3.5
2.9
2.8
3.0
4.5
9.5
Amt. (ng)
3.9
4.1
3.4
5.2
5.1
Amt. (ng)
3.4
2.9
% Recovery
45.0
62.2
67.0
86.7
71.9
69.3
74.2
112
119
% Recovery
96.3
103
84.2
129
127
% Recovery
85.3
71.4
OC Limits
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
25%- 130%
25%- 130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%- 130%
40%- 130%
Ratio
0.86
0.79
1.51
1.48
0.56
1.15
0.48
1.05
0.90
Ratio
1.47
0.59
1.15
0.46
Ratio
0.51
0.57
Ratio
0.80
1.17
RT
25:43
26:21
29:31
30:31
33:00
33:42
36:00
37:05
40:55
RT
26:22
30:12
32:54
33:37
37:37
RT
34:18
33:30
RT
26:10
34:01
Flags
Q_
. —
Flags
oH
Q_
Flags f
—
Flags
—
Data Reviewer.
01/15/98
Page 2 of 2
X337.PSR viOl. LARS 4I0.08O
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
is c
-------
Initial
..Date..
Dae a Review By.
{
Calculated Noise Area:
I
The Total Area for each peak with an ion abundance ratio outside
•atio limits has been recalculated according to method requirements.
2.00
Page No.
01/15/98
Listing of T980157B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2. . Rel.Rt Compound.Name.. ID.. Flags.
TCDP
304-306
304-306
13C12-TCDF
^16-318
*
316-318
TCDD
320-322
DC NL
1
1 '.
1
15
DC NL
DC WL
DC WL
DC WL
DC WL'
DC WL
DC WL
DC WL
DC WL
DC WH
7
DC NL
0
0:00 RO
.22:40
23:.09
23:22 RO
24:24 RO
24:53 RO
25: 13 RO
25:32
25:43 RO
26:06 RO
26:18 RO
26:33
26:50
27:01
27:22
27:35
Peaks
0.
0 .: 00 RO
22:40 RO
23:09 RO
23:22 RO
23:32 RO
23:45 RO
24:05 RO
24:26 RO
24:42 RO
24:55 RO
25:03 RO
25:17 RO
25:31 RO
25:43
26:07 RO
26:13 RO
27:.43 RO
Peaks
0.
0:00 RO
23:56
.65-0.39
3.18
0.89
0.38
0.90
0.96
0.52
0.93
0.89.
0. 96
0.95
0.91
0.80
0.39
0.30
0. 30
0.31
65-0.39
2.29
1.83
3.09
2.29
1.40
2.74
1.62
1.46
2.52
2.54
2.07
1.68
1.27
0.36
2.32
1.22
1.08
0.878-1.073
64
62
63
128
89
60
82
33
62
65
17
1
9
1
793
4.92
,446.00
,432.60
,674.33
,050.83
,158.58
.397.20
,371.60
,948.45
,754.47
,217.24
,205.51
302.39
,396.99
, 510.50
,432.01
,799.30
30,343
29,149
32,328
69,425
38,786
31,838
39,0.74
45,455
33,589
33,403
7,634
142
340
4,237
639
.60
.20
.20
.00
.50
.30
.20
.60
.40
.80
.63
.42
.75
.30
.40
34
33
35
72
75
34
43
. 47
35
36
9
1
5
,102.40
,283.40
,974.20
,345.10
,119.40
,405.20
,797.40
,428.50
.454.50
,845.90
,570.88
160.47
,056.24
,273 .30
792.61
0.000
0.381
0.900
0.909
0.949
0'.?68 - . '
0.984
. 0.993 • . ' . .
1.000 2378-TCDF AN
1.015
1.023
1.032
1.043
1.051
1.064
1.073
QSE
QSE
QSE
.QSE
QSE
QSE
QSE.
SE
QSE
QSE
QE
Q
Q
QE
Q
0.961-1.039
1
2
65-0.89
1.18
0.89
64
10.48
39.91
40.34
35.22
65.36
140.41
162.45
132.29
89.79
116.17
116.53
67.91
126.34
,362.09
56.53
135.79
18.12
,481.46
TCDF / TC
13.13
,933.80
166
136
64
90
362
.74
93
.70
.62
.30
.73
.57
.25
.23
65.63
65.89
38.37
71.38
999.52
31.94
76. 12
0.000
0.381
0.900
0.909
0.915
0.924
0.936
0.950
0.960
0.969
0.977
0.983
0.992
1.000 13C12-2373-TCDF ISO
1.016
1.023
1.078
Q
*T}O Prtl 1 fM*/e
30 , 653 .
,60
34,
0.903-1.045
280.20
0.000
0.908
SE
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
191
-------
Page No.
01/15/98
Listing of T980157B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log OmiC Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
M
AN
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
24
24
25
25
25
26
26
26
26
26
27
:13 .
:35
:14
:30
:52
:16 .
•22
:32
:41.
:53
:20
0.30
0.77
0.77
0.78
0.78
0.79
0.79
0.77
0.77
0.78
0.77
12 Peaks
47,501
17,252
38,260
25,113
13,685
35,000
1,761
4.390
3,526
1,293
1,365
254,583
.70
.01
.00
.80
.36
.00
.00
.16
.33
.12
.92
.70
21,073
7,523
16,663
10,990
6,017
15,500
779
2,125
1,536
568
595
.60
.17
.30
.20
.66
.00
.00
.31
.40
.04
.00
26,428
9,728
21,596
14,123
7,667
19,500
982
2,764
1,990
725
770
.10
.84
.20
.60
.70
.00
.00
.85
.43
.08
.92
0.922
0.933
0.958
0.968
0.982
0.997
1.001 2378-TCDD . AN
1.007
1.013
1.020
1.037
E
E
E
E
E
E
. 0.924-1.076
DC NL 0;
DC WL 23
DC WL 24
DC WL 24
24:
24:
24:
25:
25:
25:
25:
26:
26:
26:
:00
:56
:10
:17
:28
: 35
:59 -
14
30
41
52
22
31
44
10 Peaks
DC NL 0:
DC WL 24:
24:
DC SN 24:
24:
25:
25:
25:
26:
26:
26:
27:
27:
27:
0
00 RO
19
27
34
42
15 RO
34 RO
46 RO
10
21
40
08 RO
16 RO
33 RO
11 Peaks
DC NL 0:
27:
1.
00 RO
34 RO
.65-0.89
1.87
0.86
0.66
0.69
0. 88
0.42
0.99
1.52
0.30
0.79
0.65
1.97
0.. 34
0.94
1
422
712
447
32
102
7,429
214
133
43
73.
2,014.
41.
12,866.
22,952.
.48
.38
.60
.26
.72
.48
.21
.41
.85
.95
.58
.14
.13
.80
27
32
102
7,429
214
133
43
73 .
2,014,
41.
12,366.
.72
.48
.21
.41
.85
.95
.58
.14
.13
,80
0.000
0.908
0.917
0.922
0.929
0.933
0.943
0.953
0.963
0.975
0.932
1.001 37C1-TCDD SUR1
1.006
1.015
0.924-1.076
5.
17.
12.
3.
13 .
15.
51.
20.
2,678.
2,073.
50.
8.
6.
8.
34
72 ' •
34
54
30
53
19
62
04
71
16
48
60
57
4.
6.
7.
28.
17.
1.194.
915.
19.
9.
2.
4.
4,944.54
32-1.78
0.77
1.10
3.
60,340.
77
53
36,981.
91
21
19
69
73
31
75
83
45
37
55
50
7.
7.
17.
23.
11.
1,483.
1,162.
30.
4.
8.
4.
43
09
20
92
65
73
96
33
79
36
34
0.000
0.923
0.923
0.932
0.937
0.958
0.970
0.973
0.993 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.012
1.030
1.035
1.046
0.931-1.063
33,574.
30
0.000
0.934
OS]
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
1S2
-------
Paqe No.
01/15/98
Listing of T980157B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/ . •
M_2.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
27
23
28
28
28
28
28
29
29
29
29
29
29
30
30
30
30.
31
:50
:01
:11
:18
:33
:41
:51
:10
:15
:26
:32
:40
:49
:13
:20
:39
:51
:08
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.29
1.37
1.50
1.64
1.25
1,05
1.20
1.19
1.11
1.26
1.30
1.26
1.22
1.12
1.16
1.50
1.71
1.49
' 19 Peaks
DC NL 0
27
27
28
28:
t 28:
28
1 29:
29:
' ', 29:
29:
29:
30:
30:
' 30:
31:
31:
:00
:35
:44
:22
:33
:41
:51
:10
:15
:31
:40
43
:12
;21
46
:08
:25
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-1.78
1.18
2.65
1.07
0.60
1.67
2.49
1.51
3.09
2.69
1.51
2.10
2.15
1.47
1.80
1.39
1.91
0.39
16 Peaks
__ ____ \K«
DC NL 0:
28:
29:
29:
29:
29:
30:
30:
30:
00
:47
14
29
36
47
02
14
22
1.
RO
RO
RO
RO
32-1.78
1.15
1.06
1.55
1.26
1.52
1.49
1.54
1.55
0.63
1,078
553
1,518
770
45,396
80,509
49,418
78,182
59,155
40,462
41,090
42,390
54,284
59,293
67,671-
14,588
871
12,456
711,033
.35
.91
.99
.10
.91
.42
.34
.34
.72
.74
.54
.51
.24
.75
.41
.02
.14
.17
.13
27
48
30
47
35
24
24
26
32
36
41
a
7
655.47
320.05
911.79
478.43
,594.20
,937.10
,038.60
,522.60
,957.40
,595.00
,976.60
,070.70
,996.30
,041.30
,133.60
,747.06
549. 54
,453.74
507.73
233.86
607.20
291.67
22,031.40
46,657.10
25,036.60
39.990.50
32,540.30
19,472.10
19,192.90
20,769.60
27,062.60
32,132.30
35,539.70
5,340.96
321.60
5,002.43
0.943
0.949
0.955
0.959
0.967
0.972
0.977
0.988
0.991
0.997
1.001 12378-PeCDF
1.005
1.010
1.024 23478-PeCDF
1.028
1.038
1.045
1.055
Q
Q
Q
Q
QSE
QSE
QSE
QSE
QSE
QSE
AN SE
QSE
QSE
AN QSE
QSE
Q
Q
Q
0.364-1.136
4
71
26
27
. 66
163
115
53
70
2.295
47
149,
2,347.
140.
13,
39.
15.
5,645.
. 71
.33
.93
.97
.33
.43
.14
.17
.56
.93
.33
.07
.72
.02
.60
.93
,99
50
? / Q..
1
1,
74.62
16.37
17.00
41.77
159.38
69.25
64.33
74.47
,381.31
38.91
125.32
,396.47
99.10
7.91
29.34
9.72
28.17
15.36
28.12
25.06
64.11
45.89
20.35
27.67
914.62
18.56
58.46
951.25
54.91
5.69
15.66
10.96
0.000
0.935
0.940
0.961
0.967
0.972
0 . 977
0.988
0.991
1.000 13C12-PeCDF 123
1 . 005
1.010
1.023 13C12-PeCDF 234
1.023
1.042
1.055
1.064
IS2 Q
SUR2 Q
LiT\r^ p>*»1 1 — . . —
V6 : PeCDt / rw.vu r U-LXUWS --
5.
53,890.
5,970.
42,323.
6,785.
35,507.
18,424.
15,174.
5,941.
26
55
75
53
95
10
99
91
04
32,
3,
25,
4,
21,
11,
9,
3,
757.00
624.36
726.10
095.69
251.90
158.90
212.68 .
611.22
0.939-1.022
•
30,909.70
2,345.89
20,378.10
2,690.26
14,255.20
7,266.09
5,962.23
5,738.32
0.000
0.943
0.958
0.966
0.970
0.976
0.984
0.991
0.995
SE
QSE
Q
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
1 Q^
J. C o
-------
Page Ho.
01/15/98
Listing of T980157B.dbf
Matched GC Peaks / Ratio / Rat. Time
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total .Area. .. Area.Peak. 1.. Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
356-358
13C12-PeCDD
368-370
368-370
30
30
30
:31
:38
:58
1.56
1.53
1.55
11 Peaks
DC NL 0
28
29
29
29
29
29
30
30
30
30
. 30
DC SN 30
30
31
31
31
:00
:47
:09
:15
:29
:41
:47
:03
:14
:20
:31
:38
:53
:53
:10
:25
:33
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
0.27
1.85
1.63
1.36
2.08
2.21
1.36
1.94
1.58
1.39
1.48
1.43
1.44
1.25
.3.24
0.64
0.39
15 Peaks
7,610.11
5.623.71
6,185.57
203,438.26
1.65
92.34
17.98
18.32
46.28
. 8.03
29.76
48.91
32.34
25.04
1,648.36
• 167.64
'. 5-73
19.13
13.37
7.09
5.40
2,130.99
HxCDF
374-376
I
X
AX
M
AX
AN
M
374-376
13C12-HXCDF
384-386
DC NL 0:
31:
32:
32:
32:
32:
X 32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:
:00
57
07
14
23
32
44
56
02
08
19
26
32
15
13
23
47
1.
RO
RO
RO
05-1.43
1.22
1.16
1.07
1.26
1.25
1.27
1.27
1.07
1.09
1.26
1.26
1.24
1.11
1.26
1.23
1.27
1.25
15 Peaks
DC NL 0:
31:
32:
32:
00
57
06
40
0.
RO
RO
RO
RO
43-0.59
1.44
2.44
3.16
2.71
269.51
46,341.30
71,794.40
10,427.19
17,082.98
8,409.61
641.58
77,283.50
54,328.10
12,573.09 .
25,383.70
2,620.00
58,300.00
2:011.00
3,730.00
14,890.00
913.88
406,316.45
4,633
3,400
3,757
66
11
10
37
6
21
37
19
14
984
98
11
17
4
3
.94
.65
.35
.39
.14
.34
.30
.97
.69
.26
.31
.56
.30
.59
.63
.64
.31
.23
2,976.17
2,223.06
2,423.22
0.
36.21
6.34
7.98
18.15
3.15
11.67
19.18
12.53
10.48
664.06
69.05
9.27
5.44
6.72
8.49
1
1
1
.000 12378-PeCDD AN
.004
.015
869-1.131
0
0
0
0
0
0
0
0
0
0
1
.000
.943
.955 •
.958
.966
.973
.976
.985
.991
.994
.000 13C12-PeCDD 123 IS3
1.004 -.:.-'
I
.012
1.015
1.
1.
1.
.021
.029
034
HvPDF Pnl 1 nu/c
25,110.
37,041.
5,819.
9,493.
4,701.
359.
39,984.
28,377.
7,015.
14,156.
1,450.
30,900.
1 , 120 .
2,060.
8,320.
00
60
79
19
37
36
30
30 '
76
50
00
00
00
00
00
. 0.964-1.049
21,731.30
34.752.30
4.607.40
7,589 .79
3,708.24
282.22
37,299.20
25,950.30
5,557.33
11,227.20
1,170.00
27,900.00
891.00
1,670.00
6, 570. 'DO
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.379-
12.70
18.30
40.26
9.60
29.
84.
17.
59
23
23
12.12
26.66
6.36
0.
0.
0.
0.
000
968
973
977
981
986
992
998 123473-HxCDF AN
001 123678-HxCDF AN
004
010
013
016 234678-HxCDF AN
038
039 123789-HxCDF AN
042
054
1.121 .
000
968
973
990
SE
SE
QSE
SE
E
SE
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
194
-------
Page No.
01/15/98
Listing of T980157B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
.. QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
334-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
D
408-410
13C12-HpCDF
413-420
M
418-420
.32:54
33:00
33:30
33:51
33:59
34:18
9 Peaks
DC NL 0:00
32:25
32:52
33:05
33:16
, 33:37
33:43
34:01
. 7 Peaks
DC NL' 0:00
i 32:54
33:04
33:17
33:25
1 33:37
33:42
34:01
DC SN' 34:11
7 Peaks
'
DC NL, 0:00
36:02
36:18
• 36:27
D NH 36:56
, 37:37
4 Peaks
DC NL 0:00
36:00
36:09
36:25
36:33
37:37
5 Peaks
RO
RO
1
RO
1.
RO
RO
RO
RO
0.59
0.56
0.57
4.15
2.58
0.51
Abe
.05-1.43
0.99
1.21
1.08
1.20
1.21
1'. 21
1.22
1.22
05-1.43
1.42
1.64
1.66
2.33
1.21
1.15
1.15
1.17
1.96
1,639.47
2,114.29
2,001.34
13.02
12.68
1.393.09
7,742.05
42.99
19,116.21
53,726.70
41.368.20
6.335.02
5.413.55
11,231.51
19,740.06
156,931.25
14.77
20.70
35.39
18.77
15.37
1,510.38
1,440.65
2,081.64
5.20
5,122.90
0.
RO
' ,
0.
RO
RO
RO
RO
38-1.20
1.22
1.02
1.04
1.06
1.19
1.04
37-0.51
1.66
0.48
1.40
2.20
1.43
0.46
27.23
77,066.10
25,034.40
22,919.70
74.52
15,408.25
140.428.45
607
760
728
35
' 21
642
.70
.49
.47
.76
.68
.15
1,031
1,353
1,272
8
3
1,250
.77
.80
.87
.62
.40
.94
0.997
1.000
1.015
1.026
1.030
1.039
13C12-HXCDF 478 SUR3
13C12-HXCDF 678 IS4
13C12-HXCDF 234 ALT2
13C12-HXCDF 789 ALT1
HvCDD Pol 1 ciU7« - — '
10,483
27,945
22,559
3,463
2,959
6,167.
10,342
15.
26.
19.
3.
80S.
771.
1,123.
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38.393.
12,783.
11,776.
7,865.
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29
54
40
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72
15
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8.632
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123478-HXCDD AN
123678-HxCDD AN
123789-HxCDD AN
QE
QSE
QE
Q
Q
QPRE
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0.000
0.976
0.981
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0.998
1.000
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13C12-HXCDD 473 SUR4
13C12-HXCDD 678 IS5
13C12-HXCDD 789 RS2
Q
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33,172.
12,245.
11.143.
7.542.
30
70
10
55
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1.001
1.008
1.013
1.026
1.045
1234673-HpCDF AN
1234789-HpCDF AN
SE
E
E
0.944-1.111
10.12
1,377.00
13.62
10.60
12.38
1,359.65
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13C12-HpCDF 673 IS6
13C12-HpCDF 789 SUR5
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
195
-------
Page No.
01/15/98
Listing of T980157B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC-Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HpCDD
424-426
424-426
13C12-HpCDD
436-433
436-438
OCDF
442-444
442-444
DC
NL 0:
36:
37:
:00
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0.
RO
,38-1.20
1
1
1
.42
.02
.01
2 Peaks
DC
DC
NL 0:
36:
36;
SN 36;
37:
37:
37:
:00
:16
:30
:46
;05
;17
26
0.
RO
RO
RO
RO
RO
RO
.88-1.20
1
1
1
1
1
2
2
.46
.43
.98
.60
.05
.00
.21
5 Peaks
H V»*
DC
DC
NL 0:
ML 36:
00
14
0.
RO
RO
76
1
1
-1.02
.95
.38
Above: HpCDF / HpCDD Follows
39:05 0.90
41:10 0.91
2 Peaks
9.73
42.282.40
43,210.20
85,492.60
4.20
39.00
24.13
2.75
1,689.52
34.09
31.36
1.318.60
/ Octa-C
1.81
26.72
29.56
22,899.30
22,929.36
13.99
10,382.00
21,324.10
21,693.60
27.32
23.46
867.10
33.35
34.57
0.976-1.006
0.000
20,958.30 0.979
21,516.60 1.000 1234678-HpCDD
0.973-1.027
0.000
19.12 0.978
11.83 0.934
AN
0.991
322.42
16.71
15.62
000 13C12-HpCDD 678 IS7
005
1.009
Follows
0.902-1.098
0.000
0.386
15.57 0.955
12,017.30 1.006 OCDF
AN
OCDD
453-460
458-460
0.76-1.02
DC NL 0:00 RO 0.62 1.61
40:56 0.31 26,985.20
1 Peak 26,985.20
12,096.80
0.902-1.098
0.000
14,388.40 1.000 OCDD
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.69 2.14
40:55 0.90 2,429.33
470-472 1 Peak 2,429.33
1,152.03
0.998-1.006
0.000
1,277.30 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
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417.8253 f:4 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 051,23316. 0,1 . 00\,T,T) Exp:XDB5as
TRIANGLE LABS Text:TLI»44376 121-124/219 INJ. TIME » 19:12
1003
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601
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419.8220 T:4 BSOB(2S6, 30, -3. 0) PXD(7, 5, 3, 0. 05\, 14060. 0, 1 . OOt, r,T) Exp:NDB5OS
TRIANGLE LABS Tejct:TLI#44376 121-124/219 XW7. TIME ' 19:12
1001
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TRIANGLE LABS Text:TLI# 44376 121-124/219 XK7. TIME ' 19:12
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Tile:T980157 tl-562 Acq:6-JMt-98 19:09:09 EH- Voltage SIS 70T
479.7165 r-.4 Exp-.NDBSUS
TRIANGLE LABS Teit:TLI»44376 121-124/219 iyj. TIME - 19:12
1001
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A2.10E8 A2.15E8
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NGLE LASS Text :TLI 94437 6 121-124/219 INJ. TIME - 19:12
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TRIANGLE LASS Text:TLI»44376 121-124/219 XK7. TIME -
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TRIANGLE LABS Teit:TLI#44376 121-124/219 INJ. TIME - 19:12
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Resolution 18888
Group nuaber 2
lonizstion aode El*'
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ftef , aasses 292,3825, 416,3768
D 293 J 331 S 368
B 384 K 332 T 378
C 386 L 334 U 376
0 316 II 348 V 418
E 318 N 342
F 329 0 352
0 322 P 354
H 328 8 356
I 331 R 358
tef , iass 416,3768 Peak top
Keicht ,38 wits Span 298 ppa
207
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Sample Text:TLI»44376 121-124/219
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?ile:T980157 #1-396 Acq:6-JAN-98 19:09:09
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100% 32^32
EI+ Voltage SIR 70T
INJ. TIME =
32:28 32:30 32:32 32:34 32:36
File:T980157 #1-396 Acq:6-JAN-98 19:09:09
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
lOOi
80J
60J
40J
20 j
OJ
32:38 32:40 32:42
El-t- Voltage SIR 70T
INJ. TIME =
32:40
19:12 File Text:TLI#44376 121*
_1.5E7
Ll.2E7
_8.8E6
_5.9E6
L2.9E6
32:44 32:46 32:48
Time
19:12 File Text:TLI#44376 121»
7.1E4
L5.7E4
L4.3E4
L2.9E4
Ll.4E4
LO.OEO
32:28 32:30 32:32 32:34 32:36
File:T980157 #1-396 Acq:6-JAN-98 19:09:09
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100%,
32:38 32:40 32:42
EI+ Voltage SIR 70T
INJ. TIME =
32:44 32:46 32:48 Time
19:12 File Text:TLI#44376 121»
32^14 _2.2E5
_1.8E5
_1.3E5
32:44 32:46 32:48
32:28 32:30 32:32 32:34
32:36
32:38 32:40
32:42
ro
CD
-------
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME =
19:12 File Text:TLI#44376 121»
32:54 33:00
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME =
100%. 33;_QO
33:12
33:18
Time
19:12 File Text:TLI#44376 121»
32:54 33:00 33:06
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 / INJ. TIME =
100*
80 j
60 j
401
20 j
0
33:12
L1.3E6
L8.9E5
L.4.4E5
LO.OEO
33:18 Time
32:54
19:12 File Text:TLI#44376 121»
2.8E4
L2.2E4
Ll.7E4
L1.1E4
L5.5E3
Lo.OEO
Time
33:12
33:18
ro
-------
?lle:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5(JS
Sample Text:TLItJ44376 121-124/219
100%
INJ. TIME =
19
SO.
60 j
40_
20_
0
12 File Text:TLI#44376 121»
_8.9E6
L7.1E6
15.3E6
L3.6E6
;.1.8E6
T
T
~T
T
33116 33:18 33:20 33:22 33:24 33:26 33:28
File:T980157 ttl-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLItt44376 121-124/219 INJ. TIME
100%
80 j
60J
40J
20 j
OJ
33:30
1
.O.OEO
33:32 33:34 33:36 Time
19
33:25
33:19
Text:TLI#44376
2.2E5
Ll.8E5
Ll.3E5
L8.8E4
L4.4E4
T
T
.O.OEO
33:16 33:18 33:20 33:22 33:24 33:26 33:28
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME
100S. 33^26
80J
60 j
40J
20_
0
33J30 ' 33I32 ' 33I34 ' 33J36 Time
19:12 File Text:TLIS44376 121»
33:16 33:18 33:20 33:22 33:24 33:26 33:28 33:30 33:32 33:34
L6.7E5
L5.0E5
L3.4E5
L1.7E5
1_LO.OEO
33:36 Time
ro
-------
ile:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME
100% 34_;23
80J
601
40_
20_
19:12 File Text:TLIH44376 121*
2.3E7
_1.8E7
_1.4E7
_9.0E6
_4.5E6
34:00 34:06 34:12 34:18 34:24
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME
100%, 34U8
34 :30
.O.OEO
34:36 Time
19:12 File Text :TLI#44376 121»
1.8E6
Ll.4E6
34:00 34:06 34:12 34:18 34:24
File:T980157 #1-396 Acq:6-JAN~98 19:09:09 El-f Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME
100% 34^14
BOl
60J
40J
20J
34:30
_7.1E5
_3.6E5
O.OEO
34:36 Time
34:00
34 :06
34 :12
34
34 :24
19:12 File Text:TLI#44376 121»
7.4E5
L6.0E5
L4.5E5
L3.0E5
L1.5E5
LO.OEO
Time
34:30
34 136
ro
-------
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219
100%.
INJ. TIME = 19:12 File Text:TLI#44376 121»
_5.2E7
_3.9E7
L2.6E7
L1.3E7
33:18 33:24 33:30 33:36 33:42
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME = 19:12
100%. A2L.Z9E8
33:48
lO.OEO
Time
File Text:TLI#44376 121»
6.5E7
L5.2E7
13.9E7
L2.6E7
Ll.3E7
33:18 33:24 33:30 33:36 33:42
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME = 19:12
100%, 33;30
33:48
LO.OEO
Time
File Text:TLI#44376 121»
_2.1E6
33:18
33:24
33:30
33:36
33:42
33:48
0 .OEO
Time
N>
v-*
CO
-------
ile:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
J73.8208 F:3 Exp:NDB5US
ample Text:TLI#44376 121-124/219 INJ. TIME
lOOi
80J
60 j
40J
20J
OJ
34:06 34:12 34:18 34:24
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME
lOOi A6.52E7
80J
60 j
40j
20 j
Oj
34:06 34:12 34:18 34:24
File:T980157 #1-396 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME
100%. 34U.8
19:12 File Text :TLI#44376 121»
.2.3E7
_1.8E7
-1.4E7
34 :30
34 :36
L4.5E6
lO.OEO
Time
19:12 File Text:TLIK44376 121»
_1.9E7
L1.5E7
L1.1E7
L7.4E6
L3.7E6
34 :30
34:36
LO.OEO
Time
19:12 File Text:TLI#44376 121»
_1.8E6
34 :06
34:12
34:18
34 :24
34 :30
34:36
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Time
ro
-------
Hle:T980157 #1-562 Acq:6-JAN-98 19:09:09 EI+ Voltage SIR 70T
417.8253 F:4 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME =
100% A4.49E6
90J
80J
70J
60J
50 j
40J
30J
20J
10 j
0
35J36 35148 36:00 36:12 36:24
File:T980157 #1-562 Acq:6-JAN-98 19:09:09 EI + Voltage SIR 70T
419.8220 F:4 Exp:NDB5US
Sample Text:TLI#44376 121-124/219 INJ. TIME =
100%. A9.28E6
90 J
80J
70J
60 j
50 j
40J
30J
20 j
10J
19:12 File Text:TLI#44376 121»
3^48
Time
19:12 File Text:TLI#44376 121»
0.
_2.1E6
_1.8E6
_1.6E6
_1.4E6
_1.2E6
_9.2E5
_6.9E5
L4.6E5
L2.3E5
LO.
35:36
35:48
36:00
36:12
36:24
36:36
36:48
Time
ro
H*
o\
-------
TLI Project:
Client Sample:
44376
121-124/219
Method 23 TCDD/TCDF Analysis (DB-225)
. Analysis File: X98008'i
Client Project: Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-5A-D/ Date Extracted: 12/29/97
Date Analyzed: 01/07/98
Sample Size: 1.000 Dilution Factor: n/a
Dry Weight: n/a Blank File: X980083
GC Column: DB-225 Analyst: KAS
Spike File
ICal:
ConCal:
SPC2NF04
XF24087
X980080
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
^nafrtes % * * : ^' yU-CAfn£fr5> ^<-£ttL^ : •te^'^:^^^ "^ m , ftags
23,7,8-TCDF 85.0
Internal Standard AmL (ng) % Recovery OC Limits
13C,2-2,3,7,8-TCDF . 3.2 78.8 40%-130%
Recovery Standard
13C12-1,2,3,4-TCDD
0.76
Ratio
0.83
Ratio
0.80
21:32
UT
21:31
irr
20:30
E_
Flags
—
Ffags
Data Reviewer.
01/11/98
Page 1 of I
CNF.PSR T2.0I. LARS 6.10.
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:3501/11/98
216
-------
Initial
Date..
Data Review By:
!_/!£
/!/
Calculated Noise Area:
^
I
he Total Area for each peak with an ion abundance ratio outside
-atio limits has been recalculated according to method requirements.
2.00
Page No.
01/11/98
Listing of X980088B.dbf
Hatched CC Peaks / Ratio
/ Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.N,
ID.. Flags.
TCDP
304-306 DC NL 0:00
DC WL 16:55
17:08
17:24
17:34
17:39
17:46
18:07
18:15
18:23
: 18:32
18:49
18:57
19:06
19:11
19:16
19:26
19:46
1 20:12
20:17
| 20:27
20:39
20:51
21:01
21:16
21:24
21:32
21:44
21:58
22:04
22:32
1 22:44
23:20
DC WH 23:44
304-306 31 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 17:15
DC WL 17:52
DC WL 18:22
DC WL 18:50
DC WL 18:56
0.65-0.89
RO 0.98
RO 0.
0.
RO 0.
0.
RO 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
0.
0.
0.
RO 0.
0.
0.
RO 0.
58
77
51
81
61
76
77
77
87
77
77
78 1,
76
77
38 1,
77
94 1,
77
78
82
77
76
35
33
81
76
30
84 1,
80
64
76
78
57
17,
1.264.31
0.790-1.095
0.000
1,442.66
538,326.
2,969.
5,030.
2.301.
8,928.
539,425.
549.123.
962,315.
518.081.
472,267.
054.476.
599,259.
396,659.
011,366.
661.386.
786,390.
616,109.
136.404.
876,474.
711,413.
126,062.
977,617.
6,553.
932,170.
455,027.
953,659.
033,853.
882,185.
1,755.
560,577.
77,508.
1,986.
456.171.
00
16
93
15
58
00
00
00
00
00
00
00
00
00
00
20
00
20
00
00
50
00
07
00
00
00
00
00
79
00
90
22
48
235.041
1,291
2.243
1,213
3,859
234,385
238,477
448 , 447
225,706
205,263
461.759
259,708
172,195,
472,870
288,092.
951,853,
267,469.
59,805.
395.983.
308,573.
54.553.
449,765.
2,850.
417.617.
196,847.
423,215.
470,899.
391,964.
763.
242,886.
33,988.
.00
.67
.19
.58
.73
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
,00
.00
60
,00
00
20
00
77
00
00
00
00
00
82
00
30
303,285
2.513
2,782
2,009
5,068
304,540
310,646
513,868
292,375
267,004
592,717
339,551
224,464
538,496
373,294
1,009,260
348,640
76,598
480,491
402,840
71,509
527,852
8,637
514,553
258,180
530,444
562,954
490,221
1,199
317,691
43,520
0.65-0.89
0.
0.
RO 0.
RO 1.
0.
RO 1.
72
84
53
36
86
25
90.
210.
39.
146.
499.
158.
55
64
53
40
36
54
.00
.94
.74
.65
.35
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.60
.00
.00
.30
.00
.61
.00
.00
.00
.00
.00
.30
.00
.10
0.
0.
0.
0.
786
796
809
816
B
0.820
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
826
342
848
354
861
875
381
888
392
895
903
919
939
943
950
960
969
977
988
995
001 2378-TCDF
010
021
026
047
057
084
103
E
B
B
E
E
E
E
E
E
B
E
E
E
E
E
E
B
E
AN E
E
B
E
E
0.953-1.047
0.
0.
0.
0.
0.
0.
000
802
830
354
875
380
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: J3:2<^p1/11/98
-------
Page No.
01/11/98
Listing of X980088B.dbC
Matched OC Peaks / Ratio /
Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OX Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Mama.. ID.. Flags.
316-318
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
DC
ML 19
WL 19
WL 20
WL 20
WL 20
20
:15
:47
:00
:13
:27
:39
20:47
DC
DC
21
21
21
21
22
22
22
WH 23
WH 23
:00
:31
:42
:52
:03
:19
:23
:01
:42
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
2
1
1
1
4
0
0
0
1
1
1
1
0
0
0
.28
.30
.03
.08
.16
.22
.60
.78
.83
.88
.06
.33
.11
.96
.95
.76
9 Peaks
DC
DC
NL 0
19
20
20
21
21
22
WH 23
:00
-.52
:14
:30
:12
:21
:04
.-.14
0.
RO
RO
RO
65-0.89
1
1
0
0
0
0
2
0
.31
.62
.79
.30
.77
.34
.35
.84 .
6 Peaks
491.03
242.79
309.40
374.00
658.60
57.97 138.09
470.34 204.61
280.44 123.33
22,142.30 10,011.00
93.46 99.21
540.13 322.66
257.55 194.07
122.71 77.14
64.09 34.80
1,085.54
81.15
24,028.99
Above: TCDP / TCDD. Follows
43.37
63.74
15,575.45
20,190.79
231.56
415.61
55.47
213.56
36,532.62
0.895
0.919
0.930
0.940
0.950
32.75 0.960
340.83 0.966
157.11 0.976
12,131.30 1.000 13C12-2378-TCDF ISO
52.80 1.009
305.16 1.016
145.51 1.025
69.33 1.037
36.21 1.040
1.070
1.101
0.901-1.099
6,
8,
58
851
963
100
189
73
.21
.81
.69
.74
.63
.64
36.
8,723,
11,227,
130,
225,
31,
.01
.64
.10
.82
.98
.34
0
0
1
1
1
1.
1
1,
.000
.982
.000 i:
.013 i:
.048
.055
.091
.143
000 13C12-2378-TCDD IS1
13C12-1234-TCDD RSI
Column Description.
•Why" Code Description QC Log Desc.
H_2 -Nominal Ion Hassles)
..RT. -Retention Time (mtn:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*** End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
ffii»:Z9Boo8a ti-aaa AC?» 7-ais-i99S vtitia>07 ac si* Voitmg* jig
303.3016 3303(356,30,-3.0) PKD(5,3. l,0.10*,1404800.0,0.00*,r,P)
T**t:TLX*44376 1117-130/216/317/318 Pile TauttJ HUAaOLX LABS
17:00 10:00 15:00 20:00 21:00 22:00 23:00
il-883 Aeq: 7-JAN-1998 20:48:07 OC EH- Voltage SIR AatoSpec Soiuei3S7289
303.8987 BSUB(256,30,-3.0) PXD(5,3,1,0.10*,1429156.0,0.00*,PIP
Staple TexttTLI«44376 1117-120/216/217/218 file Itett TXIABOLB LABS
100H A5.J.4E9 AS.\8S9 ,_, A4.gOS9AS 28S9 A5.30S
80.
40:
30:
JL3.18E9
I
17:00 ,18:00 19:00 20:00 21:00 22:00 23:00
Pile:Z980088 #1-883 Actj: 7-JAU-1998 20:48:07 OC SI* Voltage SIR AutoSpeo Solae:18948
315.9419 BSVB(256,30,-3.0) ?XD(S.3,1.0.10*,75792.0,0.00\,P,P) Bxj?:ZCONP_TT
Saaple Text:TLI#44376 1117-120/216/217/218 Pile Text: TRZANQLE LABS
10031 A1.00E8
80.
601 '
201
-r
17:00 18:00 15:00 20:00 21:00 22:00 23:00
P11»:X980088 91-883 Acqs 7-JAK-1998 20:48:07 QC SI+ Voltag* SIR AutoSpac Hoiaa:26327
317.9389 BSUB(2S6,30,-3.0) PKD(5,3, 1, 0.10%, 105308. 0, 0. OQ\,V.y)
3oopl« r*xt:TLI*44376 1117-120/216/217/218 Pll» T«urt» TRULBBLB LABS
1009t A1.21S8
80.
60.
40.
20.
17:00 18:00 19:00 20:00 21:00 22:00
Pll»:X9800ee 01-883 Aeq: 7-JAH-1998 20:48:07 Voltaffm SIS AutoSptc
375.8364 B3Cp:KONP_TT
Sajoplo Toxt:TLIf44376 1117-130/216/217/218 Pllf tact* TRIANBLB LABS
23 tOO
O.OSO
Tim*
1.1S9
8.6EB
.6.4E8
.4.3S8
.2.1S8
.O.OSO
Time
.2.2E7
.1.8E7
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-------
Flle:X980088 91-893 Acqt 7-*JAN-lySo 2Q:4o:u/ ec SIf Voltage SIR AUCOSpeo Holt
319.8963 BSUB(2S«,30,-3.0) PXD(5,3,l,0.10*,935a4.0,0.00*,P,P)
Sample TextiTLI944376 1117-120/216/217/218 Pile Text: TR1ABOLS LABS
100HA2.72B9
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327.8847 BSUB(256,30,-3.0) PKD(5,3,1,0.10*. 82616.0,0. 00*,P,P) Sxp:XCON?_TT
Sanplo Tvrt:TLI»44376 1117-120/216/217/218 Pila Tart: TRUUXJLB LABS
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Staple Text:TLI944376 1117-120/216/217/218 Pile Text: TRIANGLE LABS
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Sample Text:TLX*44376 1117-120/216/217/218 Pile Text: TRIANOLB LABS
100* A1.12B8
80.
60.
40.
20.
23:00
O.OEO
Time
-2.9E7
.2.3B7
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-------
17:00 10:00 15:00 20:00 21:00 22:00
\Pll»:I9800ea 91-883 Acqt 7-JAN-1998 30,48,07
-------
TLI Project: 44376
Client Sample: 117-120/216/217/218
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T9801FJ
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN
194-59-4A-D/
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01/06/98
n/a
T980152
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2.3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2.3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (rig) DL EMPC
2.0
16.4
18.8
40.2
65.1
-Bl— 7^0
108
EMPC 1£3 ? l(
44.3
EMPC 8ft4 t2o
96,3 ?2.O
59-f 7 20
•82^" >2-o
5.0
126. 720
31.6
A
Amt (ng) Number DL EMPC
-9W =1 11 975 ^
1 , 4*7- > 2. /7 Q or* ^ *» *9 / ^
*my ** *^ o jtj4 7 ^ c/ B
-470 > 2o 7
•249 > Zc? 2
-343 7 -f 9 t370 ^^
3*^ ?2,0 10 925 ' 2o
498 ?2C 13 305 ? 2^0 4 x"«
Bat»
0.79
1.54
1.21
1.22
1.22
1.00
0.81
1.46
1.09
1.14
1.13
1.25
1.02
1.04
0.90
HT
26:23
30:32
33:38
33:43
34:02
37:07
40:58
29:32
32:56
33:02
33:31
34:18
36:02
37:38
41:11
Ffags
•
£
PRE
SE_
E_
SE_
E_
QSE
QSE
>c
SE_
SE_
PR_
SE_
(S
'
Flags
SE_
SQE
SQE
SE_
SQE
SQE
SQE
SE<3
Page 1 of 2
X37.PSR V2.01. LARS «. 10.OSo
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Print
22*27
01/15/98
-------
TLI Project: 44376
rlient Sample: 117-120/216/217/218
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980156
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-U,3,7.8-PeCDD
13Cirl,2,3,6.7,8-HxCDF ,
13C,2-l,2,3,6,7,8-HxCDD
l3C,2-l,2,3,4.6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
I3C,2-1,2,3,4,6,7,8,9-OCDD
|iir|^a^
37CL-2,3,7,8-TCDD
I3C,:-2,3,4,7,3-PeCDF
l3Cr-l,2,3,4,7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD ,
13C,:-l,2,3,4,7,8.9-HpCDF
1
fA1t»|i|al&
13C,:-l,2,3,7,8,9-HxCDF
13Cr-2,3,4,6,7,8-HxCDF
»Ci:-l,2,3,4-TCDD
"Ci:-l,2,3,7,8,9-HxCDD
2.1
3.2
2.9
4.2
3.5
3.6
3.4
4.8
10.7
|;||r|||||||^|||||
3.6
4.6
3.3
4.6
5.0
rfmijiiilillli
3.8
3.3
52.7
79.6
72.7
106
86.7
89.7
85.4
119
134
90.8
115
83.4
116
126
95.8
82.6
illlllSililllllllii
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%- 130%
25%-130%
70%-140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
|p5:limitsi|
40%- 130%
40%- 130%
|||:s;|||||lis|l;|||i;
0.82
0.80
1.48
1.50
0.55
1.17
0.51
1.02
0.95
1.50
0.56
1.19
0.43
0.51
0.55
0.80
1.20
:•:•;•:•: -:•:•:•' •:• iiii—i; 'x'X'X':-
liiiiRjIii;
25:44
26:22
29:32
30:31
33:01
33:43
36:01
37:05
40:57
IsSssSD-pHswi
:H*:*:;S:"4i::SSS:
26:23
30:12
32:55
33:37
37:38
34:18
33:31
26:12
34:02
x::::::::::wi:>'::S:^y>:W:>A;X
Q
Q_
—
Q
-------
Initial
..Daca..
Daca Review By:
Calculated Noise Area:
2.00
The Total Area Cor each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/15/98
Listing of T980156B.dbf
Hatched GC Peaks / Ratio /Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Conpound.Name.. ID.. Flags.
TCDF
304-306 DC ML 0:00
22:42
23:10
23:23
23:44
24:04
24:26
24:41
24:54
25:19
25:33
25:45
26:07
26:19
26:34
26:51
27:01
27:23
27:36
304-306 18 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC WL 22:42
DC WL 23:09
DC WL 23:23
DC WL 23:32
DC WL 23:46
DC WL 24:05
DC WL 24:27
DC WL 24:42
25:08
25:19
25:32
25:44
26:07
26:19
DC WH 27:43
316-318 6 Peaks
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.65-0.89
3.28
0.83
0.35
0.90
0.96
0.95
0.94
0.95
0.51
0.90
0.35
0.96
0.94
0.33
0.30
0.31
0.79
0.30
0.80
1
65-0.89
2.78
2.20
3.76
3.23
1. 34
3.07
1.47
1.66
2.21
1.94
1.17
1.14
0.82
1.87
1.36
1.17
0.878-1.073
3.86
49,520.60
54,596.10
62,148.42
150,062.90
104,594.96
121,220.93
80,932.72
85,031.49
58,224.36
73,458.70
80,418.53
59,133 .40
61,190.30
17,367.19
376.55
2,601.44
8,715.21
1,214.24
,070,308.54
0.000
22
25
31
31
55
64
43
36
29
33
43
31
28
7
1
3
,408.00
,158.60
,619.20
,485.70
,982.70
,483.50
,469.30
,991.10
,710.40
,667.70
.424.50
,521.30
,693.60
,705.34
163.08
,152.14
,883.40
533.10
27
29
35
84
59
68
45
73
32
39
. 45
33
32
' 9
1
4
,112
,437
,112
,781
,093
,436
,724
,229
,395
,791
.434
,408
,496
,661
203
,449
,831
676
.60
.50
.10'
.30
.20
.40
.70
.00
.40
.00
.20
.70
.70
.35
.47
.30
.31
.14
0
.382
0.900
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1 .
1.
1.
1.
1.
1.
0.961-
7.04
25.61
31.38
29.49
74.13
98.06
165.43
119.60
80.73
111.67
84.43
116.94
2,287.74
62.23
73.97
21.89
2.737.03
I-- Above: TCDF /
1,
122.48
55.94
75.12
029.48
65.60
56.72
63.
47.
66.
1,258.
35.
41.
09
73
07
26
16
79
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
.909
,922
935
949
959
963
984
993
001 2373-TCDF AN
015
023
032
043
050
064
073
1.039
000
332
900
909
915
924
936
950
960
977
984
992
000 13C12-2378-TCDF ISO
015
023
077
QE
QSE
QSE
QSE
QSE
QSE
QSE
QSE
QSE
QSE
SE
QSE
QSE
QE
Q
Q
QE
Q
Q
TCDD Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
-------
Page No. 2 Listing of T980156B.db£
01/15/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
X_Z.... QC.Log Omit Why ..RT. OK Ratio Total. Area. .. Area. Peak.
"TCDD 0.55-0.39
320-322
M
AN
320-322
37C1-TCDD
323
328
13C12-TCDD
332-334
332-334
DC NL 0
23
24
24
25
25
25
26
26
26
26
26
27
:00
:57
:19
:35
:15
:31
:53
:17
:23
:32
:42
:54
:20
RO 2
RO 0
0
0
0
0
0
0
0
0
0
0
0
.92
.92
.87
.78
.79
.78
.78
.78
.79
.79
.78
.79
.79
12 Peaks
DC NL 0
DC WL 23
DC WL 24
DC WL 24
24
' 25:
25:
25:
25:
' 25:
I 26:
26:
26:
26:
:00
:53
:11
:19
:35
;00
:15
:30
:43
:53
:10
:23
:32
44
10 Peaks
8.11
65,379.38
59,733.30
31,221.50
59,531.60
41,619.50
24,108.90
56,700.00
1,916.00
8,622.92
4,560.43
1,903.92
1,939.35
357,286.30
1.55
525.62
161.64
429:36
195.74
7,167.71
328.34
214.57
41.79
129.91
111.22
2,552.42
67.58
13,542.30
24,3.52.08
33,369
27 , 747
13 , 664
26,202
18,188
10,533
24,900
846
3,816
2,002
842
853
195.
7,167.
328,
214.
41.
129.
111.
2,552.
67.
13,542.
1. . Area. Peak.
.60
.10
.70
.30
.90
.50
.00 .
.00
.42
.60
.47
.00
.74
.71
.34
,57
,79
91
22
42
S3
30
36.937
31,986
17,556
33,378
23,430
13.575
31,800
1,070
4,306
2,557
1,061
1,081
',. 0.65-0.89
DC NL ' 0:
DC WL ' 23:
DC WL 24:
24:
24:
1 24:
25:
25:
25:
26:
26:
1 26:
00
57
21
25
36
42
15
47
52
12
22
40
RO 2.
RO 1.
RO 1.
RO 1.
RO 1.
RO 1.
0.
RO 1.
RO 1.
0.
0.
0.
36
06
30
19
02
21
66
24
35
SO
30
68
9 Peaks
4.57
21.19
11.13
10.35
5.93
11.36
31.96
15.35
10.07
2,310.39
2,793.58
61.57
5.751.16
PeCDF
340-342
1.32-1.78
DC NL , 0:
00
RO 0.
60
2.99
6.
3.
7.
12.
10.
7.
1,252.
1,241.
24.
96
41
75
75
72
69
91
17
86
2. .
0.
.50
.20
.30
.30
.60
.40
.00
.00
.50
.33
.45
.35
0.
Rel.RT Compound . Name .. ID..
903-1.045
0.000
0.908
0.922
0.932
0.958
0.963
0.982
0.997
1.001 2378-TCDD AN
1.006
1.013
1.020
1.037
924-1.076
0.000
0.909
0.917
0.922
0.932
0.943
0.953
0.967
0.975
0.982
0.992
1.001 37C1-TCDD ' SUR1
1.006
1.014
Flags
SE
SE
E
E
E
E
E
E
0.924-1.076 .
5.85
3.35
6.42
19.21
8.67
5.69
1,557.
1,552.
36.
'98
51
71
0.000
0.903
0.924
0.926
0.933-
0.937
0.953
0.978
0.981
0.994 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.011
PeCDF Follows ---
0.931-1.063
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
-------
Page No.
01/15/98
Listing of T980156B.dbf
Hatched GC Peaks / Ratio
/ Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area..,
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
27:
28:
28:
28:
28:
35
;02
13
19
34
28:43
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
28:
29:
29:
29:
29:
29:
29:
30:
30:
30:
30:
31:
DC WH 31:
52
10
15
27
32
41
49
13
22
40
53
09
36
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.12
1.49
1.51
1.22
1.42
1.06
1.33
1.18
1.13
1.37
1.46
1.41
1.35
1.14
1.17
1.47
1.14
1.46
1.84
18 Peaks
DC NL 0:
27:
27:
DC SN 28:
28:
28:
28:
29:
29:
29:
29:
DC SN 30:
30:
30:
30:
30:
DC SN 30:
31:
31:
00
35
43
18
34
41
52
10
15
32
49
00
12
21
39
46
54
13
25
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
15 Peaks
DC NL 0:
28:
29:
29:
29:
29:
00
48
15
29
37
48
1.
RO
RO
RO
RO
,32-1.78
2.07
3.07
2.39
3.06
3.56
2.64
1.17 .
2.74
2.45
1.48
2.23
5.21
1.50
2.28
1.95
1.51
2.76
1.99
• 2.97
55,413.47
155.31
660.35
233.25
39,375.20
73,995.57
46,011.30
72,330.17
53,938.09
38,283.70
30,715.40
37,862.00
50,751.20
55,766.20
60,649.53
14.133.88
349.78
10,758.26
59.85
641,382.66
33
23
44
26
43
32
22
18
22
29
33
36
8
6
,682.70
92.96
397.30
141.78
,104.40
,977.70
,288.10
,965.40
,785.90
,154.60
,253.00
,121.20
,192.10
,897.10
.865.40
,402.58
212.61
,383.54
30,155
62
263
116
16,270
42,337
19,723
37,300
28,987
16,129
12,462
15,740
21,559
29,724
31,522
5,731
186
4,374
.70
.35
.05
.24
.80
.40
.20
.30
.30
.10
.40
.30
.10
.10
•10
.30
.43
.72
0.934
0.949
0.955
0.959
0.967
0.972
0.977
0.988
0.990
0.997
1.000 12378-PeCDF
1.005
1.010
1.023 23478-PeCDF
1.028
1.033
1.046
1.055
1.070
QSE
Q
Q
0.
QE
QSE
QSE
QSE
QSE
QSE
AN E
QE
QSE
AN QSE
QSE
Q
Q
Q
0.364-1.136
1.48
47.33
10.58
4.00
16.40
111.21
97.90
48.36
52.53
2,516.29
122.48
2.45
2,982.32
95.98
3.64
11.10
1.43
39.55
8.03
6.269.70
32-1.78
0.78
1.05
1.56
1.20
1.56
1.30
4.74
61,435.59
9,538.62
46,673.06
9,574.73
43,682.82
1,
1,
56.96
9.93
22.38
115. 14
59.51
52.45
50.41
,563.18
106.91
,788.54
85.69
6.60
6.63
30.92
9.37
13
4
6
43
50
19
20
1,053
48.
1,194
37.
3.
4.
15.
3.
.56
.15
.43
.61
.92
.16
.60
.11
.03
.28
.64
.39
.42
51
.15
0.000
0.934
0.933
0.953
0.967
0.971
0.977
0. 988
0.990
1.000 13C12-PeCDF 123
1.010
1.016
1.023 13C12-PeCDF 234
1.023
1.033
1.042
1.046
1.057
1.064
IS2 Q
SUR2 Q
37,
5,
28,
5,
26,
343.20
811.47
369.90
831.93
552.30
35,473.
3,727.
23,677.
3,742.
20,355.
0.939-1.022
90
15
70
30
50
0.000
0.944
0.958
0.966
0.971
0.977
SE
QSE
SE
Triangle Laboratories, Inc.® Anaiy sal Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
226
-------
Page No.
01/15/98
Listing of T980156B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
356-358
13C12-PeCDD
368-370
363-370
:CDF
4-376
AX
M
MX
AN
M
374-376
13C12-HXCDF
384-336
29
30
30
30
30
30
30
-.58
:03
:15
:23
:32
:39
:59
RO
1.54
1.56
1.54
0.34
1.54
1.56
1.55
.12 Peaks
DC NL 0
28
DC SN 28
29
29:
29
29:
30:
30:
30:
' 30:
30:
31:
, 31:
:00
:48
:59
:10
:15
:29
:48
:03
:14
:22
:31
:38
;00
32
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
1.71
2.02
2.38
1.35
1.26
2.15
2.33
2.32
2.10
2.33
1.50
1.51
1.35
0.80
12 Peaks
-. ... ?\u«
DC NL 0:
31:
32:
32:
32:
32:
32:
32:
33:
33:
33:
X 33:
33:
X 34:
34:
34:
DC WH 34:
00
57
07
15
23
32
45
56
02
08
19
26
31
15
18
24
48
1.
RO
RO
RO
05-1.43
1.61
1.16
1.08
1.26
1.25
1.25
1.18
1.09
1.14
1.26
1.25
1.22
1.13
1.24
1.25
1.25
1.29
15 Peaks
DC NL 0:
31:
32:
00
57
06
0.
RO
RO
RO
43-0.59
1.78
2.95
3.46
12,463
16,824
22,269
9,757
11,213
8.343
9,466
261,743
0
97
2
11
14
47
34
27
26
16
2,110
212
21
4
2,624
113
46,043
65,589
3.046
13,052.
7,623.
474
72,530.
49.359.
11,269.
20,321.
2,970.
55,700.
2,080.
3,130.
12.670.
566.
371,366.
.21
.40
.95
.40
.14
.96
.30
.18
.34
.32
.33
.31
.51
.71
.04
.39
.01
.14
.64
.90
.11
.59
.17
T / «•%
j 1 n>
.61
.60
.40
.26 >
.28
.20
.70
,90
.60
,71
,45
.00
00
00
00
00
03
10
7,563
10,245
13,517
5,930
6,301
5,385
5,749
77
6
3
40
31
24
21
14
1,264
128
15.
2.
.02
.50
.20
.97
.76
.06
.17
.60
.50
.82
.19
.13
.38
.37
.78
.97
.15
.30
.79
. 4.900
6,578
8,752
7,032
4,411
3,458
3,717
38
4
7
18
13
10
10
6
345
34
8
3
.19
.90
.75
.66
.38
.90
.13
0.
.36
.31
.01
.71
.35
.74
.20
.33
.67
.75
.28
.48
0.982
0.985
0.991
0.996
1.001 12378-PeCDD AN
1.004
1.015
869-1.131
0.000
0.944
0.950
0.956
0.958
0.966
0.977
0.985
0.991
0.995
1.000 13C12-PeCDD 123 IS3
1.004
1.016
1 .033
ff^V TTr* 1 1 riufc
24,750.
34,007.
4,433.
7,247.
4,241.
256.
37,874.
26,594.
6,290.
11,278.
1,630.
29,500.
1,150.
1,740.
7,050.
60
30
04
03
09
61
50
30
46
60
00
00
00
00
00
21,293.
31,581.
3,563.
5,805.
3,387.
218.
34,556.
23,264.
4,979.
9,042.
1,340.
26,200.
930.
1,390.
5.620.
6. 964-1. 049
.00
.60
.22
25
11
,09
40
30
25
35
00
00
00
•oo
00
0.000
0.963 QSE
0.973 " QSE
0.977
0.981
0.985
0.992
0.997 123478-HxCDF AN QSE
1.001 123678-HxCDF AN SE
1.004
1.009
1.013
1.015 234678-HxCDF AN SE
1.037
1.039 123739-HxCDF AN PR
1.042
1.054
0.879-1.121
8.
11
15.76
30.
67
30.
70.
78
19
10.
20.
44
31
0.000
0.963
0.972
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
22
7
-------
Page No.
01/15/98
Listing of T980156B.db£
Matched GC Peaks / Ratio / Ret. Tine
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Conpound.Name.. ID.. Flags.
384-386
32
32
33
33
34
:39 RO
:55
:01
:31
:18
2.44
0.56
0.55
0.55
0.51
7 Peaks
7.94
1,995.22
2,596.73
2,361.41
2,166.45
9,174.18
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
DC NL 0
32
32
33
33
33
33
34:
1
:00
:26
:52
:06
:16
:38
:43
:02
.05-1.43
1.26
1.22
1.06
1.10
1.21
1.21
1.22
1.22
7 Peaks
DC NL 0:
32:
33:
33:
33:
33:
33:
34:
34:
DC SN 34:
1
:00 RO
;53
:05
;17 RO
24 RO
:37
:43
;02
12 RO
17 RO
.05-1.43
1.74
1.23
1.40
2.56
0.90
1.19
1.17
1.20
2.58
1.76
8 Peaks
62.38
28,853.00
62,553.40
56,085.40
9,952.74
7,899.32
19,074.39
30,655.00
215,073.25
7.17
30.77
39.57
11.39
4.32
1,792.45
1,399.79
2,121.26
3.44
4.79
5,908.99
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
DC NL 0:
36:
36:
36:
37:
0.
00
02
18
28
38
88-1.20
1.04
1.02
1.03
1.04
1.04
4 Peaks
DC NL 0:
36:
37:
0.
00 RO
01
38
2 Peaks
37-0.51
1.84
0.51
0.43
26.79
74,860.40
20,983.10
20,862.30
14,295.27
131,001.57
12
714
913
333
733
.84
.02
.19
.76
.53
5
1,281
1,678
1,527
1,432
.26 0.989
.20
.54
.65
.92
0
1
1
1
.997 13C12-HXCDF 478 SOR3
.000 13C12-HXCDF 678 IS4
.015 13C12-HXCDF 234 ALT2
.039 13C12-HXCDF 789 ALT1
15,829
32,149
29,366
5,458
4,328
10,486
16,352
16
. 23
13
2
972
1,025
1,155.
9.
.50
.80
.30
.82
.45
.60
.70
.97
.09
.61
.67
.14
.47
.46
.71
13,023
30,403
26,719
4,493
3,570
8,587
•• 13,802
13
16
5
2
820
874
965
3
0.
.50
.60
.10
.92
.87
.79
.30
0.
.30
.48
.31
.98
.31
.32
.80
.77
953
0
0
0
0
0
0
1
1
970
0
0
0
0
0
0
1
1
1
1
-1.015
.000
.962
.975
.982
.987
.998 123478-HXCDD AN
.000 123678-HXCDD AN
.009 123789-HxCDD AN
-1.030
.000
.975
.981
.987
.991
.997 13C12-HXCDD 478 SUR4
.000 13C12-HXCDD 678 IS5
.009 13C12-HXCDD 789 RS2
.014
.017
E
QSE
SE
E
PRE
37,798.
10, 656.
10.648.
7,303.
90
60
70
63
37,061.
10,326.
0.998-1.053
.50
50
10,214.10
6,991.
64
0
1
1
1
1,
.000
.000 1234678-HpCDF AN
.008
.012
.045 1234739-HpCDF AN
SE
E
"0. 944-1. Ill
3.33
1,614.07
1,585.38
542.
478.
3,199.45
Above: HoCDF / HoCDD Follc
38
58
1,071.
1.106.
69
80
0.
,000
1.000 13C12-HpCDF 678 IS6
1.045 13C12-HpCDF 789 SUR5
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:27 01/15/98
228
-------
Page No.
01/15/98
Listing of T980156B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why . .RT. OK Ratio Total .Area. .. Area. Peak. 1.. Area.Peak.2. . Rel. RT Compound. Name. . ID..- Flags.
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-433
OCDF
442-444
442-444
OCDD
453-460
453-460
13C12-OCDD
170-472
470-472
0.88-1.20
DC
NL 0:
• 36:
37:
:00
:19
:07
RO
1
1
1
2 Peaks
DC
NL 0
36:
36;
37:
37:
:00
:16
:32
:05
:19
0.
RO
RO
RO
RO
.24
.00 55
.00 61
117
14
,916
,693
,610
.71
.60
.40
.00
.88-1.20
1
1
1
1
1
4 Peaks
DC
NL 0:
39:
1 41:
.00
06
ill
0.
RO
RO
.87
.95
.70
.02 1
.64
1
.76-1.02
1
0
0
, 2 Peaks
DC
NL 0:
40:
00
58
0.
RO
76
0
0
1 Peak
DC
DC
1
NL 0:
40:
WH 41:
00
57
22
0.
RO
.37
.73
.90 24
24
-1.02
.54
. 31 41
41
4
27
15
,825
33
,902
.94
.99
.22
.51
.58
.30
HpCDD /
1.
41
,908
,950,
0.
,736.
,736.
.87
.83
.70
.53
98
70
.70
76-1.02
1
0
0
1 Peak
.83
.95 2
.32
2
1.
,788.
2.
,738.
76
49
91
49
28,001.00
30,901.20
26.75
12.71
920.30
27.01
0.976-1.006
0.000
27,915.60 0.979
30,792.20 1.001 1234678-HpCDD
AN
SE
SB
0.973-1.027
0.000 -
13.72 0.978
7.46 0.985
904.71 1.000 13C12-HpCDD 678 IS7
16.46 1.006
Octa-CDD and CDF Follows
0.902-1.098
0.000
19.70 26.82 0.955
11.313.90 13.094.30 1.006 OCDF
0.902-1.098
0.000
18,575.70 23,061.00 1.000 OCDD
0.998-1.006
0 . 000
1,355.47 1.433.02 1.000 13C12-OCDD
1.010
AN
AN
I S3
Column Description. . . : "Why" Code Description. QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (rran:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Ral.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SK-3elow Signal to Noise Level
-------
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TRIANGLE LABS Text:TLI#44376 117-120/216/217/218 INJ. TIME - 1.8:25
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TSIANGLE LABS Text:TLI#44376 117-120/216/217/218 JK7. TIKE - .2,8:25
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.1.3X7
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36\00 36':12 36:24 36\36 36\48 37': 00 37\12 37\24 37\36 J7-48 3a':00 38\12 Time
rile:T980156 #1-563 Acq:6-JAJf-98 18:33:33 -EI+ Voltage SIR 70T Koiae:5649
417.8253 F:4 BSUB(256, 30, -3. 0) PKD(7, 5, 3, 0. 05\,32596 . 0,1 .00%, T,T) Xip:NDBSUS
TRIANGLE LABS Teit:TLI#44376 117-130/216/217/218 XJK7. TIME » 18:26
100J
80:
60:
40:
20:
"•I1" A4.71SS
A A
'•
/ \
/ L • 1 V
1.2X6
-.9 . 6E5
.7.2X5
.4.8X5
.2.4X5
'36:66 ' 36>:12 ' 36\24 ' 36^36 36\48 37\00 37\12 37\34 37\36 37\48 38\00 38\12 Time
rile:T980156 #1-563 Acq:6-JAlT-98 18:23:23 EI+ Voltage SIR 70T Soiae:3066
419.8220 F:4 BSU3(256, 30, -3. 0) PKD(7,5, 3, 0. 05\, 12264 . 0,1 . 00\,T,T) Xxp-.NSBSUS
TRIANGLE LABS Text:TLIt44376 117-120/316/217/318 im. TIMX - 18:26
1001
SO:
60:
40:
20:
A1.07E7 A1.11E7
An
A
/ V
J ^
..2.5E6
.2.0E6
.1.515
.9 . 9E5
.5.015
36\66 ' '36:12 ' '36:24 36:36 36\48 37:00 ' ' 37\ 12 37:34 ' ' 37\36 J7:48 Jfl.-OO 38\12 Time
File:T980156 #1-563 Acq:6-JJUT-98 18:23:23 EH- Voltage SIX 70T
430.9729 F:4 Exp-.NDBSVS
TRIANGLE LABS Text:TLI#44376 117-120/216/217/218 IJKT. TIME - 18:26
1001,
80:
so-
40:
20:
o-
,f,n. ,«.,/! 36:4236:50 37:00 37^22 37^3337:4237^5037^5838:07
-A r~^~\rf' — ^-^ ~^~ ^\y~^- . x/
\/
_5 . 2E6
.4.2X6
3-^1X6
-2.1X6
_1 . 0£S
" 0 . OZO
Jtf.'do ' '36:12 ' ' 36\24 ' 36\36 36\48 37\66 ' ' 37\12 ' ' 37\34 ' '37:36 '37:48 'jfl:00 38:12 Time
rile:T980156 #1-563 Acq:6-JAW-98 18:23:23 XI+ Voltage SIR 70T
479.7165 t:4 XxptSDBSUS
TRIAXGLX LABS Text:TLI#44376 117-120/216/217/218 UKT. TIMX - 18:26
1003
80:
60:
40:
20:
36:14
A
\
/ V . ^
.4.8X5
-.3 . 8X5
'-.3.9X5
.1.9X5
-.9.5X4
'• o . oxo
36':00 36:12 36:24 36': 36 36:48 37:00 37\13 37\34 37*:36 37\48 JSiOO 38:12 Tiae
236
-------
TfHi
423.
TSIA
1003
80.
SO.
40.
30.
0.
3
Tile
425.
TSIA
1001
80.
SO.
40.
20.
0.
3
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435.
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80.
SO.
40.
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3
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437.
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40.
20.
0
3
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430.
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1001
80.
SO.
40.
20.
0
31
,1980156 fl-563 Acq:6-JAtf-JJ X1+ Volt*?. 31S 701 Soiae: 4474
7755 r-.4 BSOB(256,30, -3.0) PXD(7,5, 3, 0.05\, 17896. 0, 1.00\,T,T) XzpiSDBSUS
JiGLE LABS Text.-TLH44376 117-120/216/217/218 ua. TIKE' 18t26
A2.80E8 A3 .09X8
A f\
A A
y \ j i
S\12 36\i'a \36t34 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 J7-is 37:24 J7:J0 37:36
:T980156 il-563 Adj:6-J7OT-9a 18:23:23 EH- Voltage SIS 70T Hoiae:3603
7737 r:4 BSUB(256, 30, -3. 0) PKD( 7,5, 3, 0. 05\,14412.0,1.00\,r,T) SxpsUDBSOS
JfSZS LASS Text:TLI«44376 117-120/216/217/218 UKT. TIME - 18:26
A2.79E8 A3J(8X8
\ \
\ \
\ \
J L J V_
S:12 36:13 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30 37:36
-.1980156 #1-563 Acq : 6 -J7W- 9 8 18:23:23 EI+ Voltage SIS 70T Hoiae:2258
3169 F:4 BSUB(2S6, 30, -3. 0) PKD(7,5, 3, 0 . 051,9032. 0,1 . 00», F, T) Exp:lO>B5US
NGLZ LABS Text.: TLI 94437 6 117-120/216/217/218 JK7. TIME -' 18:26
.
si-lj 36:18 36]:24 Jsi-JO 36*: 36 JS:ii 36^:48 36:54 J7.-00 J7.-05 J7:ii J7:is 37\24 37>:30 37V36
-.T980156 tl-563 Acq:6-JXN-98 18:23:23 EI+ Voltage SIX 70T Hoiae: 1211
8140 T:4 BSUB(256, 30, -3. 0) PTD( 7,5, 3, 0. OS\r4844. 0,1. 00\,r,T) Exp:NDB5US
UGLS LABS TexttTLI#44376 117-120/216/217/218 HKT. TIME - 13:26
' A9.05ES
' \
' / \
\ '
J V
S(:12 jtfsii '36\24 jtfiJO 36I:36 36:42 JtfUs 36\S4 J7:00 37\06 J7: 12 '37\'l8 J7.'ji 37:30 J7.-J5
:T980156 tl-563 Acq:6-J3Ur-98 18:23:23 EH- Voltage Sit 70T
9729 r:4 Exp:SDB5OS
NGLE LABS Text:TLI»44376 117-120/216/217/218 HU. TIKE - 18:26
36.3g 36:42 _^J^_^" ^i^^^~~-i^L
i
f:12 36:18 36i24 36:30 36:36 J5«« J5:4(8 35:54 37:00 J7l<>5' 37\12 31\'ia 37:34 ' 37s 30 ' 37: 36
6.3S7
.5.1X7
.3.8E7
.2.5E7
.1.3E7
O.OEO
Time
6.4E7
.5.1E7
.3.8E7
.2.6E7
.1.3E7
' 0 . OEO
Time
2.1E6
'.1 . 7E6
.1.3E6
.8.3E5
-4.2E5
-O.OEO
Time
-2.1E6
.1 . 6E6
.1.2E6
.8.2E5
-4.1E5
O.OEO
Time
.5.2E6
-4.2E6
-3.1E6
-2.1E6
.1 . OE6
.O.OEO
Time
237
-------
r±J.a!T980J.5S #1-563 AcqtS-JZlf-98 18:23:23 EI+ Voltage SIS 701 SoiM»:682
441.7428 T:4 3SUB(256, 30, -3. 0) PXS(7, 5,3,0.05\,2728.0,1.00\,f,T) ExptXDBSUS
TSIAKGLE LABS Text:TZIt44376 117-120/216/217/218 HfJ. ma • 18i26
1001
901
801
701
SOI
SOI
401
30.
20.
101
A1.18X8
-2.2X7
12.0X7
ll. 8X7}
ll. 6X7^
11.3X7
11.1X7
18.9X6
16.7X6
14.5E6
12.2X6
36:00 37:00 38:00 39:00 40:00
Tile:T9801S6 tl-563 Acq:6-JAN-98 18:23:23 EI+ Voltage SIS 70T Noise: 49 5
443.7399 t:4 BSUB(256, 30, -3. 0) PKD(7,S,3,0 .OS\, 1980 .0,1. 00\,r,T) Exp-.NDBSUS
TRIANGLE LASS Text:TLIt44376 117-120/216/217/218 XK7. TIME - 18:26
1001
901
aol
so
sol
4ol
301
201
101
01
41:00
A1.31E8
fO-OfO
42:00 Time
2.4E7
'.2.2E7
L1.9E7
ll. 7E7
ll. SE7
11.3E7
19.7ES
•-7.3Z6
'.4.9E6
'-.2.4E6
40:00
41:00
36:00 37:00 38:00 39:00
file:T9S0156 tl-563 Acq:6-JAN-98 18:23:23 EH- Voltage SIS 70T
430.9729 F:4 Exp:NDB5US
TRIANGLE LASS Text:TLI#44376 117-120/216/217/218 IJKT. TIME ' 18:26
35:25 „,,„ 37,3337:5838:2238:47 39;33 40:51
.O.OEO
42': 00 Tine
1001
901
801
701
601
501
401
301
201
101
0!
36:50
41:34
-5.3E6
-4.7E6
.4.2E6
'.3. 7E6
.3.2E6
.2.6E6
.2.1E6
'.1. 6E6
.1.1E6
.5.3E5
36:00 37:00 38:00 39:00
Tlla,T9B0156 tl-563 Acq:6-JXK-98 18:23:23 EI+ Voltage SIS 70T
513.6775 f:4 Exp:NDB5VS
40:00
41:00
42:00
O.OEO
Time
TRIANGLE LABS
1001
Text:TLI*44376 117-120/216/217/218
XKT. TIME - 18:26
36:00
37:00
38:00
39:00
40:00
41 tOO
42:00
238
-------
rUa:f530155 #1-563 Acq: 6-Mlt-3 B 18:33:23 £1+ Volh*ga Six 70T
457. 7377 T:4 BSUB(256,30, -3.0) rXD(7,5,3,O.Q5\e912.0,1.00\,T,T) gXpiXDBSUS
TRIANGLE LASS Taxt:TLI#44376 117-120/316/317/318 XKT. TIME - 18t26
1004
80.
37X8
40:54 41:00 41:06 41:12 41:18 41:24
rile:T980156 #1-563 Acq:6-J3OT-98 18:23:23 KI+ Voltage SIS 70T Soiae:423
459.7348 T:4 BSUB(256,30, -3.0) PXD(7,5,3,0.OS\,1692.0,1.00\,r,T) Sxp:SD35US
TRIANGLE LASS Text:TLI#44376 117-120/316/217/218 1X7. TIME ' 18:26
1004 A2.31E8
41:30
-3.6E7
.2.3X7
.2.2X7
.1.4X7
'.7.216
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Tia
4.4X7
'.3.5E7
.2.6E7
_I.SE7
.3.3E6
40:54 , 41:00 41:06 41:12 41:18 41:24
rile:T98015S #1-563 Acq:6-JAK-98 18:23:23 SI+ Voltage SIR 70T Noiae:851
469.7779 F:4 BSUB(2S6, 30, -3. 0) PXD(7,5,3, 0. 05%,3404. 0,1. 00\,T, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 117-120/216/217/213 XJK7. TIKE - 13:26
1004 AL+J6E7
41:30
O.OEO
Time
2.4E6
'.1.9E6
.1.4E6
.9. 6E5
.4.8E5
41:24
40:54 41:00 41:06 41:12 41:18
File:T980156 #1-563 Acq:6-JAH-98 18:23:23 EI+ Voltage SIS 70T Noise:465
471.7750 F:4 BSU3(256,30,-3.0) PXD(7,5,3, 0. 05\r1860. 0,1. 00\,T, T) Exp-.XDBSOS
TRIANGLE LABS Text:TLI#44376 117-120/216/217/218 INJ-. TIKE ' 18:26
1003, A1.43E7
41:30
O.OEO
Time
40:54 41:00 41:06 41:12 41:18
Tlle:T9801S6 #1-563 Acq : 6 -J2UT- 9 8 18:23:23 EH- Voltage SIS 70T
430.9729 T:4 ExptSDBSOS
TRIANGLE LASS Text sTLI 14437 6 117-120/216/217/218 IKT. TIME -
41:03
41:24
18:26
00:
eo:
2.6E6
.2.1E6
.1. 5E6
.1. OE6
.5.1E5
i— [-O.OEO
41:30 Tiae
-5.2E6
.4.2E6
.3.1E6
-2.1E6
11.0X6
40:54
41:00
41:06
41:13
4l':24
O.OEO
Time
23'
-------
Cnarral ! -28,3732 Peak top
Height 3,59 volts Span 288 ppa
ft:
Systaj FILfi
Data file
Resolution 18888
Group nuaber I
lonlzatien aode El*
Switching YQLTBGE
Ref, sasses 292.3825, 418,3768
fl 293 J 331 S 388
K 332
L 334
I 348
H 342
0 352
P 354
8 384
C 388
0 316
E 318
F 328
G 322
T 378
II 376
V 418
K 328
331
0 356
R 358
Ref, MSS 416,3768 Peak top
Height ,36 volts Span 298 ppa
240
-------
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI + Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME =
100% A2.49E8
25:54 26100 26:06 , 26:12 26:18
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
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26:36
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File:T980156 #1-810 Acq:6-JAN-98 18:23 : 23 EI + Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME =
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-------
File:T980156 #1-810 Acq:6-JAN-98 18:23:23 EI + Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI»44376 117-120/216/217/218 INJ. TIME =
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26:21
26:22
26:23
26:24
26:25
26:26
26:27
26:28
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'ile:T900156 #1-396 Acq:6-JAN-98 18:23:23 El-f Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME = 18
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32:24 32:30 32:36 32:42
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EH- Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME = 18
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File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EH- Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME - 18:26 File Text:TLI#44376 117»
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32:42
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373.8208 F:3 Exp:NDB5US
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Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME = 18
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Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME = 18
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33:12
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Pile:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
100% 33:31
33:18 33:24 33:30 33:36
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
100% 33i31
33:18 33:24 33:30 33:36
File:T980156 #1-396 Acq:6-JAN-98"18:23:23 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
lOOi 33;26
80 j
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33:18
18:26 File Text :TLI#44376 117»
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33:24
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-------
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
INJ. TIME =
34:24
Sample Text:TLI#44376 117-120/216/217/218
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34:12 34:18 34:24
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME =
100% 34
80 j
60 j
40J
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34:12 34:18 34:24
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME =
100% 34jl5
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18:26 File Text : TLI#44376 117»
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-------
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
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375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
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Sample Text :TLI#44376 117-120/216/217/218 INJ. TIME
100% 33:31
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33:42
LO.OEO
Time
33:12
33:18
18:26 File Text :TLI#44376 117»
.-2.5E6
L2.0E6
L9.8E5
L4.9E5
33:24
33:30
33:36
33:42
LO.OEO
Time
o
-------
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
100%, A7.Q5E7
60 j
40J
20 j
34:06 34:12 34:18 34:24
File:T980156 #1-396 Acq:6-JAN-98 18:23:23 EI+ Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
lOOi A5.62E7
80 j
40J
20 J
OJ
34:06 34:12 34:18 34:24
File:T980156 #1-396 Acq:6-JAN-98' 18:23:23 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 117-120/216/217/218 INJ. TIME
lOOi 34 U8
80J
60 j
20J
18:26 File Text :TLI#44376 117»
_1.5E7
_1.2E7
L7.7E6
E-3.9E6
34 :30
34:36
LO.OEO
Time
18:26 File Text:TLI#44376 117»
1.5E7
Ll.2E7
L9.3E6
L6.2E6
L3.1E6
34 :30
34:36
LO.OEO
Time
Oj
34:06
34:12
18:26 File Text:TLI#44376 117»
_2.0E6
Z.1.6E6
Ll.2E6
17.9E5
L4.0E5
34:18
34 :24
34 : 30
34 :36
LO.OEO
Time
ro
^>
CO
-------
TLI Project: 44376
Client Sample: 117-120/216/217/218
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X980087
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8-TCDF
13C12-2,3,7,8-TCDF
Recovery Standard
mvwmfmvfmmmrtsixtfsf
"C12-1,2,3,4-TCDD
Gulp Aluminum
M23TRAIN
194-59-4A-D/
1.000
n/a
DB-225
62.
r-Si-iSiSvivSvS^
^illlllillPIIIPllsSBsi
4.
I
Alloys
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst
8'
S>::S:K*:*:W:*:::::S^
|n^;iP;:li»iSI;i|Si!lp
^•>£x>::::>>:'£::::::::::!^
3 109
12/17/97
12/29/97
01/07/98
n/a
X980083
KAS
:::::-:.:;:::-:;^;:-:-:-:-x-:-:.:-:-:-X;:::-:-:-:-:-:-:-:-:-:-:->:;:-:-:-:->:-:-:-:.:.:.
40%- 130%
iii«Plllil;««
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
0.77
i^sMSSSSSSiiSiSSiSSS:;
0.78
0.77
SPC2NF04
XF24087
X980080
: n/a
n/a
n/a
s:i^^is!¥K4SSSK»ti^s*S®:
;::;wPi^s;?5;SS*:;lwi|!*sss
®BiffliS^^^3ffi^S4SS?OSS:!:?S;
21:29 E_
SSSSS:SSS'S:S8S-SSg!S!S>SHS«a
21:28
S^^^liyS^SSajiiSiaSSSS:;::::;:
liillliliiillagsjll
20:28
Data Reviewer.
01/11/98
Page 1 of 1
C2NFJ>SR tun, LARS S.lOOa
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:34 01/11/98
24S
-------
Initial
Dace...
Data Review By:
Calculated Noise Area:
2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits h«q been recalculated according to method requirements.
Page No.
01/11/98
Listing of X980087B.dbf
Hatched CC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP 0
304-306 DC ML 0:00 RO
17:06
18:05
18:12
18:20
18:30
18:47
18:56
19:04
19:13
19:24
19:44
20:10
20:16
20:25
20:37
20:49
21:00
21:15
21:22
21:29
21:41
21:55
22:02
22:12
22:42
23:19
304-306 26 Peaks
13C12-TCDF 0.
316-318 DC NL 0:00 RO
DC WL 18:50 RO
DC WL 19:13 RO
DC WL 19:44 RO
DC WL 20:10
DC WL 20:25
21:12 RO
21:20 RO
21:28
22:02 RO
316-318 4 Peaks
.65-0.89
0.93
0.79
0.80
0.75
0.77
0.78
0.78
0.78
0.86
0.75
0.77
0.78
0.80
0.67
0.78
0.78
0.77
0.77
0.66
0.77
0.77
0.78
0.77
0.78
0.76
0.77
0.82
2,
,65-0.89
1.15
0.55
1.11
1.46
0.86
0.85
0.62
1.01
. 0.78
1.19
0.790-1.095
58
49
54
112
49
44
104
54
182
84
327
71
16
109
80
15
113
1
122
63
133
129
102
56
8
,150
508.75
,378.10
,452.80
,172.70
,666.90
,086.50
,818.70
,940.60
.972.50
,254.40
.384.40
,099.00
,047.70
,253.08
,634.70
,041.50
,492.79
,805.00
,170.76
,176.30
,186.20
,985.30
,121.90
,469.40
302.26
,331.60
,455.17
,700.26
25
22
23
49
21
19
45
25
78
36
142
31
6
47
35
6
51
53
27
58
56
44
24
3
,732
,029
,299
,089
,530
,633
,905
,426
,126
,708
,902
.577
,501
,382
,044
,742
,360
467
,235
,570
.567
,156
,833
130
,552
.798
.40
.50
.30
.10
.70
.60
.60
.50
.40
.70
.00
.20
.92
.40
.70
.94
.70
.56
.70
.70
.50
.00
.70
.90
.30
.51
32,645
27,423
30,873
63,577
27,555
25,185
59,035
29,546
104.128
47,675
184,197
39,470
9.751
61,752
44,996
8,749
66,944
703
68,940
35,615
75,417
72,965
57,635
171
31,779
4,656
.70
.30
.40
.80
.80
.10
.00
.00
.00
.70
.00
.50
.16
.30
.30
.85
.30
.20
.60
.50
.30
.90
.70
.36
.30
.66
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
.000
.797
.842
.348
.854
.362
.875
.882
.888
.895
.904
.919
.939
.944
.951
.960
.970
.978
.990
.995
.001 2378-TCDF AN
.010
.021
.026
.034
.057
.086
E
B
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
0.953-1.047
4
4
29.22
23.49
30.32
16.55
51.38
98.43
24.16
11.40
,162.98
19.31
,217.85
1,
10.
6.
,826.
13.
51
,48
.82
.00
16,
6
2,336
10.
•
.97
.44
.16
.91
0,
0
0,
0.
0.
0.
0.
0.
1.
1.
.000
.877
.895
.919
,939
951
983
,994
000 13C12-2378-TCDP ISO
026
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:19 01/11/98
250
-------
Page No.
01/11/98
Listing of I380087B.db£
Matched OC Peaks / Ratio / Rat. Tim*
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total. Area... Area.Peak.l. . Area. Peak. 2. . Rel.RT Compound.Nam«.. 10.. Flags.
13C12-TCDD
332-334
332-334
DC
OC
NL 0:00
20:13
20:28
21:08
21:17
21:21
21:25
21:37
WH 22:39
7 Peaks
0.
RO
RO
RO
RO
RO
65-0.89
2.04
0.80
0.77
0.77
1.33
1.55
0.35
3.58
0.80
Above: TCDP / TCDD Follows
25.82
3,060.07
2,730.06
37.53
13.06
24.07
12.55
8.64
8.51
5,905.98
0.901-1.099
1,
1.
355.
199.
16.
9.
21.
5.
17.
85
67
38
80
14
46
49
1,704
1,350
21
7
13
IS
4
.22
.39
.15
.38
.60
.66
.88
0
1
1
1
1
1
1
1
1
.000
.000 i:
.012 1:
.045
.053
.056
.059
.069
.120
000 13C12-2378-TCOO IS1
012 13C12-1234-TCDO RSI
Column Description 'Why Code Description QC Log Desc.
M_Z -Nominal Ion Hassles)
..RT. -Retention Time1 (nm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
flJ.eiI3BOOa7 91-883 Acqi7-JAN-13So 15:47:27 OC ST* VOAtmge SIK AUtOSfoa BOiM9jll33f46
303.9016 BSUB(23e,30,-3.0) PKDfS,3, 1,0.10*,534584.0, O.OO*.P,y) g3tp:XCOSF_TT
Staple Tm*t:TLIt44376 1117-130/316/317/318 Filt TtJCti HECMOEJf LABS
100* Al 3X9
90.
60.
40.
30.
A7.81S8
A4.91S8
A3.46S8
A
17:00 18x0(3 15; 00 20100 21:00 33tOO 23iOO
Fil»iZ980087 91-883 Acqi 7-JAB-1998 19t47>37 OC ZZ> Voltag* SZB AuCo^»«c Solaet 143714
305.8987 BSUB(3S6,30,-3.0) fXD(5,3, 1, 0.10*, 57 4856.0, 0.00\f?,f) BptXCOBP TT
Saoflf T»xtiTLia44376 1117-130/316/317/318 Film T«xC: IKUmU LABS
100* Al. 4S9
17:00 10:00 15:00 20:00 21:00 22:00 23:00
fil»iX980087 #1-883 Acq: 7-JAS-1998 19t47t37 OC ST* Voltage SIR AUtoSpuc HOia»s9519
315.9419 BSUS(2Sf,30,-3.0) PKD(5,3,1.0.10*,38076.0,0.00*,F,P) SxptICOSP_TT
Saapla ToxttTLX#4437S 1117-130/316/217/318 Pile Toxti TXIANOLE LABS
10091 A1.$3B7
80.
60.
40.
30.
17:00 18:00 15:00 20:00 21:00 22:00 22:00
Pile,1980087 #1-883 Acqi 7-JAK-1998 15:47:27 OC BI+ Voltage SIR AutoSpec Holae,8253
317.9389 BSUB(256,30,-3.0) PXD(5,3, 1, 0.10*, 33012.0. 0. 00\,F,F) Sxp:XCCWP_W
Sample Tejct:TLI#44376 1117-130/216/217/218 File Text: TRIASOLS LABS
100H A2.34E7
80.
60.
40.
30.
17:00 18:00 15:00 20:00 21:00 22:00
Pll»tZS80087 91-883 Acqi 7-JAN-1998 15:47:27 OC SI+ Voltage SIR AUtoSpec
375.8364 S*piXCOHP_TT
Sample T*xtiTLI#44376 1117-130/216/317/318 Film Tut: TRlAHOLB LABS
100* 21,14
80.
SO.
40.
30.
0.
33:00
18tl7
19:17
-2.3S8
.1.828
'.1.4S8
-9.0B7
L.4.5S7
O.OSO
Time
17:00
18:00
19:00
20(00
31100
33100
33:00
O.OEO
Time
.4.4E6
.3.5E6
.2.7S6
.1.8E6
,8.9E5
.O.OEO
Time
.5.7E6
.4.6S6
.3.4E6
.3.3E6
.1.1S6
O.OSO
Time
8.2ES
6.5E5
4.555
3.3E5
1.625
O.OSO
Time
25!
-------
7fIeiXSaOOa7 01-BB3 icqi 7-001-1998 IStWt'J)
-------
Pile 1 19 80087 01-883 Acq: 7-JAS-1998 15:47:27 OC 5J+ Voltage 313. AutoSpec
303.9016 SxptKOSP TT
Saaple Tmxt:TLX044376 1117-120/216/217/23.8 Pile Tmxt: TRIABBL8 LABS
1003
80.
60.
40.
20.
0
15
15:13
18:20 A
4la'5*
AA/lrUll
17:00 ' 18:00 15:00
44
\ *°t
\ 20tlO\
Ul
20:00
-2.358
" "if0 A "*"i
, \ U h
ywiM T .
.1.858
.1.458
.5.057
.4.557
O.OSO
21:00 22:00 23:00 Time
PilmiX980087 01-883 Acq: 7-J3UT-1558 15:47:27 OC 51+ VolCag* SIR AutoSpec
315.9419 SxpiXCOSP_TT
Saaple TmxttTLI044376 1117-120/216/217/218 film Tmxtt TRIAHOLS LABS
100S
80J
60:.
401
20J
15:13
17;00 ' ' ' 18:00 ' ' ' 15:00
20:00
21:28 4.55*
/ 1
^ ~J \-
.3.6S6
.2.7S6
.1.8S6
.5.055
21:00 ' 22:00 23:00 ' ' ' y^e
PilmiX980087 01-883 Acq: 7-JAH-1998 19 1 47: 27 OC 51+ Voltage SIR AutoSpec
319.8965 SxptXCOSP TT
Saaple Tmxt:TLI044376 1117-120/216/217/218 Pile Tmxt: TRXASOLB LABS
100*
80:
60:
40:
20.
0:
17:5*
"i"
1
15:31
H 11 AAA
17:00 ' 18:00 ' 15:00
-1.458
30»3«
A.y
20:00
\ r I1/!7
i.1.158
.S.1S7
.5.457
.2.757
O.OEO
21:00 ' ' 22:00 23:00 ' ' Tlam
PlleiX980087 01-883 Acq: 7-JAN-1998 15:47:27 OC 51+ Voltage SIR AutoSpec
331.9368 ExptXCOKP TT
Saaple Tmxt:TLI044376 1117-120/216/217/218 Pile Tmxt: TRIAMLS LABS
looV
80j
60:
40:
20J
0'
17:47 18:45
17:00 ' 18:00 ' 15:00
20:13
. / u
20:00
-3.7E6
21:05 21:37 22:03 22:35 23:07
.3.0E6
.2.2E6
-1.5E6
-7.5E5
• n nvn
21:00 ' ' ' 22:00 ' ' 23^00 ' ' ' Time
File, 1980087 01-883 Acq: 7-JAN-1998 15:47:27 OC 5T+ Voltage SIR AutoSpec
292.9825 Sxp:XCOSP TT
Saaple TmxttTLI044376 1117-120/216/217/218 Pile Tmxtt TRIASOLS LABS
100*
801
601
40:
201
oj
17:32 17:58 18:5315:17
20:20 30:51 31, 3* 23:17 23T-12 5.858
17:00 18:00 15:00
20:00
.4.6EB
.3.558
.2.358
.1.258
O.OSO
21:00 ' ' 22:00 ' 23:00 ' Tlam
Pile, 1980087 01-883 Acqi 7 -JAN- 19 9 3 15:47:27 OC 5X+ Voltage SIR AutoSpec
330.9792 SxpiXCOSP_TT
Saaple Tmxt:TLZ044376 1117-120/216/217/218 Pile Tmxtt TRIASOLS LABS
100*
80.
60:
40:
20.
OJ
18:30 18:55 15:37 20,20 31, 3O 11,n* 23:0+23:31 r6.4E8
17:00 ' ' 18:00 15:00
20:00
.5.158
.3.558
.2.C58
.1.358
0.050
21:00 22:00 23:00 Time
254
-------
Peak Locate Examination: 7-JAN-1998:19:43 File:X980087
Experiment:XCONF_TT Function:! Reference:PFK
10
\n
-------
TLI Project: 44376
Client Sample: 125-128
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980151
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-6A-6D Date Extracted: 12/29/97
Date Analyzed: 01706/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6.7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1.2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2.3,4,7,8,9-HpCDF
1,2,3,4,6,7,8.9-OCDF
Totais
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ns) Dt EtfPC
0.86
6.3
6.0
12.0
18.8
40.3
34.5
-O^ 7 "^ (l^ Q /}~
19.1 )/i57^y
35.3
64.6
27.0
34.4
1.5
77.6
9.1
17.4
Amt (ng) Number DL EMPC
280 12
260 10 266
210 7
83.1 2
-&:>7Uc 16
-teS-r&o 16
270 11 276
116 V 4
Ratio
0.75
1.54
1.21
1.20
1.22
1.02
0.82
0.89
1.49
1.48
1.25
1.26
1.27
1.32
1.04
1.06
0.91
RT
26:20
30:31
33:37
33:42
34:00
37:05
40:56
25:42
29:31
30:11
32:53
33:00
33:30
34:18
36:00
37:37
41:09
Ffegs
PR_
E_
SE_
E
PR!
E_
—
Flags
E_
E_
E_
E_
SQE
SE_
E_
E_
Page 1 of 2
X237.PSR vZ.OI. LARS 6.11
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:30 01/15/98
256
-------
,- .-.> f
/Eastern!
TLI Project: 44376
Client Sample: 125-128
Internal Standards
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
l3C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDb
13Cp-l,2,3,4,6,7,8-HpCbF
l3C,2-l,2,3,4,6,7,8-HpCDD
I3C|2-1,2.3,4,6.7.8.9-OCDD
Surrogate Standards {Type A)
37CL-2,3.7,8-TCDD
13C,:-2.3,4,7,8-PeCDF
13Cr-l,2.3.4,7,8-HxCDF'
13C,:-l,2,3,4,7,8-HxCDD
I3C,2-l,2,3,4J,8,9-HpCl3F
I
k
' Alternate Standards^Type A)
3Cp-l,2.3,7,8,9-HxCDF
'3Ci:-2,3,4.6,7,8-HxCDF
Recovery Standards
13C,:-1,2,3,4-TCDD
13Ci:-l,2,3,7,8,9-HxCDD
Amt (ng)
1.7
1.9
2.1
2.3
1.9
2.1
2.2
2.8
5.8
Amt: (ng)
3.7
3.5
4.1
4.3.
4.0
Amt, (ng)
2.0
1.8
iil£^fc4**i^
•^f^-XXv^J. ^ *
\ss>v<. f^ : Jfc
"'"%X
: ^
*;« -*" ,
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980158
, % Recovery
41.3
47.3
52.0
56.6
47.7
53.5
55.5
69.5
72.3
% Recovery
92.1
86.8
103
107
99.5
% Recovery
49.9
45.8
QC Limits
40%- 130%
40%- 130%
40%-130%
40%-130%
40%- 130%
40%- 130%
25%-130%
25%- 130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%-140%
70%- 140%
QC Limits
40%-130%
40%-130%
Ratio
0.77
0.78
1.49
1.45
0.53
1.20
0.47
1.02
0.95
Ratfo
1.55
0.52
1.20
0.45
Ratio
0.51
0.53
Ratio
0.80
1.19
RT
25:40
26:21
29:30
30:30
32:59
33:41
35:59
37:04
40:54
RT
26:21
30:10
32:53
33:36
37:36
RT
34:18
33:30
RT
26:10
34:01
Flags
Q_
Flags
—
Flags
—
Flags
—
Data Reviewer
01/15/98
Page 2 of 2
X237.PSR r2.OI.LARS «.10.0So
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:30 01/15/98
-------
Initial
• • -Data. .
Data Review By:
Calculated Noise Area: 2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/15/98
Listing of T980158B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name. . ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-313
316-318
DC NL 0
22
23
23
23
24
24
24
24
25
25
25
25
26
26
26
27:
DC WH 27:
0
:00 RO
:39
:08
:21
:43
:02
:24
:40.
:53
:05
:17
:30
:42
:-05
:13
:32
:21
:34 RO
.65-0.39
0:99
0.81
0.83
0.30
0.31
0.81
0.31
0.30
0.31
0.32
0.80 •
0.30
0.89
0.30
0.31
0.33
0.31
0.90
16 Peaks
DC NL 0':
DC WL 23:
DC WL 23:
DC WL 24:
24:
25:
26:
26:
- 0.
;00 RO
:04 RO
:30 RO
:04 RO
40 RO
40
05 RO
18 RO
.65-0.39
1.04
4.99
1.94
1.67
2.99
0.77
1.71
1.84
4 Peaks
0.878-1.073
14
13
15
56
35
37
34
40
27
13
14
55
15
10
2
1
387
8.97
,642.18
,402.35
,740.63
,290.40
,494.50
,309.10
,036.90
,230.00
,401.00
,597.35
,126.05
.981.50
,084.16
,120.07
,157.12
,503.54
493.52
,116.35
6,532
6.092
7,016
25,123
15,871
16.651
15,086
18,020
12,347
6,030
6,299
26,393
6,706
4,515
977
671
.63
.42
.94
.00
.40
.00
.40
.40
.40
.46
.90
.30
.62
.96
.23
.97
8,109
7.309
8,723
31,167
19,623
20,653
18,950
22,209
15,053
7,566
7,826
29.588
8,377
5,604.
1,179.
831.
.55
.93
.69
.40
.10
.10
.50
.60
.60
.89
.15
.20
.54
.11
39
.57
0.000
0.382
0.901
0.910
0.924
0.936
0.951
0.961
0.969
0.977
0.985
0.994
1.001 2373-TCDF AN
1.016
1.025
1.034
1.066
1.074
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
QE
SE
QE
QE
Q
Q
0.961-1.039
1,
1,
»K~,«
TCDD
320-322
M
AN
DC NL 0:
23:
24:
24:
25:
25:
25:
26:
26:
0.
00 RO
55
17
34
13
29
51
15
20
65-0.39
1.27
0.82
0.78
0.77
0.78
0.78
0.78
0.79
0.75
50,
30,
9,
20,
11,
7,
18,
8.11
12.32
15.66
29.36
12.46
,725.13
11.36
11.06
760.06
TCDF / TC
5.06
108.60
946.50
492.08
710.39
734.90
099.05
390.00
470.00
21.
749.
10.
11.
04
07
97
49
7.
976.
6.
6.
04
11
42
25
0.000
0.399
0.916
0.938
0.961
1.000 13C12-2378-TCDF ISO
1.015
1.025
Q
•
22,619.
13,575.
4.138.
9,084.
5,145.
3,113.
8,090.
201.
10
30
55
09
53-
46
00
00
,
27,489.
17,370.
5,353.
11,626.
6,589.
3,980.
10.300.
269.
0.903-1.045
50
70
53
30
37
59
00
00
0.000
0.908
0.922
0.932
0.957
0.967
0.981
0.996
0.999 2378-TCDD AN
E
E •
E
E
E
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:2701/15/98
258
-------
Page No.
01/15/98
Listing of T980158B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
.M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
26:31
26:40
26:53
27:19
320-322 12 Peaks
37C1-TCDD
328 DC NL 0:00
DC WL ' 23:55
DC WL 24:09
DC WL 24:17
24:34
25:01
25:12
25:28
25:41
. ' 25:51
26:21
' 26:43
1 27:33
323 9 Peaks
13C12-TCDD
332-334 DC NL 0:00
DC WL . 23:55
DC SN 24:34
' 26:10
26:21
• 26:40
; 27:02
J32-334 - 4 Peaks
PeCDF
340-342 DC NL ' 0:00
27:34
' ' 28:11
28:32.
' 28:40
28:50
! 29:08
29:14
29:25
29:31
, 29:4°
29:47
: 30:11
30:20
, 30:38
30:51
31:08
0.77
0.78
0.74
0.79
0.65-0.39
RO 2.05
RO 1.38
RO 2
0
0
RO 0
RO 1
.19
.30
.78
.58
.22
1,881.20
984.24
356.28
334.48
152,507.72
1.50
278.18
274.45
274.32
55.51
2,462.00
107.11
63.34
9.27
37.08
1,480.87
2,212.36
3.36
6,431.90
3.63
5.31
2,
1.
4,
1.32
RO 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
-1.78
.10
.49
.40
.43
.39
.50
.49
.50
.49
.49
.49
.50
.43
.48
.63
.53
.53
25,
9,
47,
11.
2i'.
19.
9,
9,
7,
11,
16,
16,
1,
1,
1.79
705.24
598.42
25.70
5.15
334.51
TCDD / Pf
5.10
017.40
75.30
084.21
111.70
203.56
518.73
497.95
463.01
114.32
611.16
855.68
837.95
360.27
844.67
461.73
781.13
2
1
2
1.
aPHF ?
-^ur s
14,
5.
27,
6,
12.
11.
5,
5,
4,
7,
10,
9,
1.
1,
818.34
430.61
150.95
147.91
55.51
,462.00
107.11
63.34
9.27
37.08
,480.87
.212.36
3.36
202.91
701.37
11.18
3.55
964.60
43.39
413.30
422.50
713.22
880.70
693.30
667.41
461.14
550.34
112.03
052.70
762.98
143.79
283.11
078.05
1
1.
10,
3,
19,
4,
3.
7.
3.
3,
3.
4,
6.
6,
,062.36 1.006
553.63 1.012
205.33 1.020
186.57 1.037
0.924-1.076
0.000
0.908
0.917
0.922
0.932
0.949
0.956
0.966
0.975
0.981
1.000 37C1-TCDD SUR1
1.014
1.049
0.924-1.076
0.000
0.903
502.33
897.05
19.40
2.91
Q
052.80
31.41
665.41
689.20
490.34
638.03
804.15
795.60
553.18
060.32
743.65
735.25
597.29
700.88
178.62
703.08
0
0
1
1
1
931
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1.
1.
.932
.993 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.012
.026
-1.063
.000
.934
.955
.967
.972
.977
.938
.991
.997
.001 12378-PeCDF AN
.006
.010
.023 23478-PeCDF AN
.028
.038
.046
.055
E
SE
E
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:2701/15/98
,C
-------
Page Mo.
01/15/98
Listing of T980158B.dbf
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Arsa.Peak.2.. Rel.RT Compound.Nama.. ID.. Flags.
340-342
16 Peaks
208,838.77
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-353
13C12-PeCDD
368-370
368-370
DC NL 0
27
28
28
28
28
28
29
29
29
29
29
30
30
31
1
:00 RO
:33 RO
:15 RO
:23 RO
:31 RO
:40 RO
:51 RO
:01
:07
:14
:30
:46
:10
:20 .RO
:03 RO
.32-1.78
0.95
1.
0.
2.
2.
1.
0.
1.
1.
1.
1.
1.
1.
2.
0.
14 Peaks
DC NL 0:
28:
29:
29:
29:
29:
30:
30:
30:
30:
30:
30:
1.
:00 RO
46
14
23
36
47
02
13
20 RO
31
33
58
32-
0.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
12
38
10
67
31
95
62
70 .
37
49
34
55
11
64
1.78
30
42
52
56
53
54
56
55
92
54
52
56
11 Peaks
DC NL 0:
23:
29:
29:
30:
30:
31:
DC SN 31:
31':
1.
00 RO
46 RO
28 RO
47 RO
30
38 RO
00 RO
25 RO
31 RO
32-
0.
3.
2.
2.
1.
1.
0.
0.
0.
1.73
20
00
25
34
45
17
69
97
96
7 Peaks
1,
1,
3,
30,
2,
22,
2,
15,
5,
7,
2,
2,
1,
1,
93,
3.32
61.69
17.01
8.03
9.92
54.52
22.30
6.99
24.04
22.32
799.53
68.74
551.21
13.52
6.53
667.35
iftf^nP / PC
V^LJC / Ff
1.78
596.20
306.30
474.44
204.81
139.80
499.29
484.96
348.62
212.17
690.59
611.89
569.07
0.364-1.136
0.000
37.50
10'
6
10
38
13
4
15
13
1,076
39-
943
11
3
.34
.62
.37
.63
.36
.32
.14
.20
..70
.34
.73
.20
.97
33
27
3
3
21
14
.58
.30
.15
.89
.38
.63
2.67
8
9
722
29
607.
5,
6.
.90
.62
.33
.40
.48
.30
.21
0.934
0.958
0.962
0.967
0.972
0.978
0.984
0.987
0.991
1.000 13C12-PeCDF 123 IS2
1.009
1.023 13C12-P6CDF 234 SUR2
1.028
1.053
0.939-1.022
17' ,.973.
U3;92.
U.,70'8.
I.,334.
S..1S9.
1,352.
4.,. 547.
1,427.
1,.34-1.
L..019.
983.
,.aa
65
,00
,.43'
27
,.07
,2S
59
.20
22
03
12,622.
913.
8,766.
870.
5,950.
2,147.
2,937.
1.556.
870.
671.
628.
40
65
44
38
53
22
70
60
97
37
36
0.000
0.943 . E
0.958
0.966 E
0.970
0.977 E
0.985
0.991
0.995
1.001 12373-PeCDD AN
1.004
1.015
0.869-1.131
1,
1,
1.45
19.56
15.56
9.32
086.71
100.91
7.68
1.65
4.98
245.22
ecnn / HV
23.
13.
9.
643.
61.
4.
3.
Cnp T»<1 T 1 n
03
73
00
.53.
34
67
03
7.
6.
3.
443.
52.
6.
3.
67
10
35
18
56
73
17
0.000
0.943
0. 966
0.977
1.000 13C12-PeCDD 123 IS3
1.004
1.016
1.030
1.033
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 01/15/98
26C
-------
Pago No.
Ol/lS/93
Listing of T980158B.dbf
Matched GC Peaks / Racio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
'.1XCDF
374-376
X
X
MX
AN
M
374-376
13C12-HXCDF
334-336
,4-386
HxCDD
390-392
390-392
13C12 -HxCDD
402-404
402-404
1.05-1.43
DC NL 0:00
31:56
32:04
32:14
32:22
X 32:31
X . -32:44
32:53
33:00
33:07
33:18
33:30
X 34:14
34:18
34:23
DC WH 34:43
14 Peaks
DC NL 0:00
' 32:04
32:33
1 32:53
32:59
33:30
DC SN 33:39
\ 33:50
34:13
7 Peaks
i
DC NL 0:00
32:25
32:51
• I 33:04
33:15
33:37
33:42
. 34:00
7 Peaks
1
1
1
1
• 1
RO 1
RO 1
1
1
. 1
1
1
RO 1
1
1
1
.10
."25
.26
.23
.27
.28
.28
.25
.26
.27
.26
.27
.24
.32
.23
.29
25.39
13,317.36
28.940.30
1,807.53
2,837.59
1,688.05
247.49
26,104.20
12,264.65
2,343.51
3,905.04
12,572.83
539.00
497.00
1,960.00
283.60
7,687
16,117
1,013
1,587
948
138
14,493
6,335
1,309
2,174
7,022
298
283
1,100
.10
.70
.16
.90
.63
.94
.00
.32
.14
.34
.16
.00
.00
.00
6,130
12.322
794
1,249
739
108
11,611
5,429
1,034
1.730
5,550
241
214
860
0.964-1.049
.76
.60
.37
.69
.42
.55
.20
.33
.37
.20
.67
.00
.00
.00
0.000
0.963
0.972
0.977
0.981
0.986
0.992
0.997
1.001
1.004
1.010
1.016
1.038
1.040
1.042
1.055
123478-HxCDF AN
123678-HxCDF AN
234678-HXCDF AN
123789-HxCDF AN
E
E
PR
109.525.05
0.43
RO 1
RO 1
RO 2
0
0
0
RO 0
RO 2
0
1.05
1
1
1
1
1
1
1
1
-0.59
. 12
.86
.11
.52
. 53
.53
.35
.15
.51
-1.43
.37
.21
.22
.22
•23
.21
.20
.22
0.879-1.121
7.99
11.87
6.27
1.329.13
1,399.75
1.232.71
4.94
5.03
1,105.75
5.140.51
HxCDF / Hx
14.67
5,062.94
27,314.10
10.931.41
2,155.39
1,474.51
3,332.99
5.167.78
55,939.62
14
8
456
435
444
7.
374,
.59
.74
.95
.96
.11
.13
.73
7
4
872
913
833
3
731,
.86
.15
.13
.79
.60
.33
.02
0.000
0.972
0.989
0.997
1.000
1.016
1.020
1.026
1.040
13C12-HXCDF 473 SUR3
13C12-HXCDF 673 IS4
13C12-HXCDF 234 ALT2
13C12-HXCDF 739 ALT1
2,769.
15,273.
6,018.
1,187.
807.
1,817.
2,841.
65
30
13
98
37
39
90
2.293.
12,540.
4.913.
967.
666.
1,515.
2.325.
1.05-1.43
DC NL 0:00
33:36
33:41
34:01
3 Peaks
RO 0
1
1.
1.
.47
.20
.20
.19
6.56
964.47
1,109.16
2,078.80
4,152.43
525.
604.
1,130.
15
03
32
439.
505.
947.
0.953-1.015
29
30
28
91
64
60
33
0.000
0.962
0.975
0.982
0.987
0.998
1.000
1.009
123473-HxCDD AN
123673-HXCDD AN
123739-HXCDD AN
E
E
PR
0.970-1.030
32
13
98
0.000
0.998
1.000
1.010
13C12-HXCDD 478 SUR4
13C12-HXCDD 678 IS5
13C12-HXCDD 789 RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:2701/15/98
261
-------
Page No.
01/15/98
Listing of T980158B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-HpCDF
418-420
413-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
453-460
453-460
13C12-OCDD
470-472
DC
DC
NL 0
36
36
36
37
WH 38
:00
:00
:17
:26
:37
:13
0
RO
RO.
.38-1.20
1.
1.
1.
1.
1.
0.
99
04
05 .
03
06
74
4 Peaks
DC
NL 0
35
37:
:00
:59
:36
0
RO
7
29,367
5,450
4,298
2,616
43
41,732
.57
.20
.49
.34
.20
.45
.73
.37-0.51
1.
0.
0.
01
47
45
2 Peaks
DC
DC
NL 0:
36:
37:
WH 37:
00
13
05
32
0
RO
.88-
0.
1.
1.
1.
Above
1.20
98
01
02
43
2 Peaks
DC
NL 0:
37:
00
04
0.
RO
.88-
0.
1.
1.20
64
02
1 Peak
DC
DC
DC
DC
NL 0:
WL 36:
39:
SN 40:
41:
41:
SN 41:
00
14
04
57
09.
25
53
0.
RO
RO
RO
76-
1.
0.
0.
2.
0.
1.
1.
Ab v
1.02
33
31
33
19
91
01
10
3 Peaks
DC
NL 0:
40:
00
56
0.
RO
76-
0.
0.
1.02
43
32
1 Peak
DC
DC
NL 0:
40:
WH 41:
00
54
11
0.
RO
RO
4
1,027
797
1,324
. 6
11,544
10,389
12
22,434
.59
.56
.30
.36
51 / Wr
r / nj
.52
.15
.39
.06
.04
0.998-1.053
0
14.966.20 14,401.00 1
2.793.58 2,656.91 1
2,178.64 2,120.20 1
1,343.78 1,272.42 1
1
.000
.000 1234678-HpCDF AN E
.003
.013
.045 1234789-HpCDF AN
.062
0.944-1.111
0.000
327.56 700.00 1.000 13C12-HpCDF 678 IS6
246.14 551.16 1,
.045 13C12-HpCDF 789 SUR5
0.976-1.006
0.
5,791.95 5,752.20 0.
5,501.36 5,388.03 1.
1.
000
979 E
000 1234673-HpCDD AN E
013
0.973-1.027
3
1,043
1,043
0.
21.
21.
3.
4.613.
110.
3.
4.746.
0.
7,074.
7,074.
.73
.27
.27
.96
.69
.62
95
,50
.98
53
10
55
10
10
76-1.02
1.
0.
0.
10
95
33 .
1.
1,472.
4.
31
26
74
0.
526.10 517.17 1.
.
0.902-
0.
0.
10.14 11.48 0.
1-
2,195.16 2,413.34 1.
55.83 55.15 1.
1.
•0.902-
0.
3.190.01 3,884.09 1.
0.998-
0.
717.36 754.90 1.
1.
000
000 13C12-HpCDD 573 IS7
•1.098
000
386
955
001
006 OCDF AN
013
024
1.098
000
001 OCDD AN
1.006
000
000 13C12-OCDD IS3
007
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 01/15/98
26:
-------
Page No. 6 : Listing of T980158B.dbf
01/15/98 Matched OC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
DC WH 41:25 RO 0.55 2.82 1.013
470-472 1 Peak 1,472.26
Column Description. . . "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
. .RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
rile:T9a0158 tl-810 Acq: 6 -JAN- 9 8 19:55:03 BI+ Voltage SIS 70T Noiae:2505
303.9016 t:2 BSU3(25S,30,-3 .0) PKD(9,S,5,
TSIANSLE LABS Text:TLIt44376 125-128
1003
80:
so:
40:
20:
o-
A2.51E8 Al.
A Al . S7E8
A7.02E7 M /-\ AA
A A A /V\ f\l
' 23\00 24\00'
Tile:T9801S8 tl-810 Acq:S-JAJt-98 19s55t03
305.8987 T:2 BSUB(256, 30, -3. 0) PKD(9,S,5,
TSIANSLE LABS Text:TLI#44376 125-128
1003
ao:.
so-.
40:
20:
o'-
A3.12E8 Al.
A
(I A2.07S8
A8.72E7 1 /\ .A
A AA ISA/1!]
'2-3:00 24:00'
rile:T980158 #1-810 Acq : 6 -JAN- 9 8 19:55:03
315.9419 r-.2 BSUB(256,30,-3.0) PKD(9,S,5,
TSIANSLE LASS Text:TLI#44376 125-128
1003
sol
SO:
40:
20:
"
' 23\00 24:00
rile:T9B015a tl-810 Acq:6-JAN-98 19:55:03
317.9389 F:2 BSUS(256, 30, -3. 0) PKD(9,5,5,
TSIANSLE LABS Teit:TLIt44376 125-128
1003
80:
60:
40:
20:
0:
O.OS\,10020.0,1.00\tr,T) EzpiXDBSUS
A2.
51E8
tk
A A1.23E8
11 i A
iwuJ
25:00
IXT. TIKE - 19: 58
4E8
AS.71E7
A4.S2E7
A .
'2ffl-00
6.5E7
L5.2JT7
'•.3.9EUL
':2.6S7^
'.1.3E7
'• 0 . DEO
27:00 Time
EI+ Voltage SIS 70T Noiae:2534
0.05\,10136.0,1.00\,r,T) ExpsUDBSOS
A2
90E8
k
A
1 ' /\
AAA
in\AAl
25 loo
INJ. TIME - 15:58
6E8
A8.3SE7
\ AA.
25:00
6.4E7
.5.1E7
'•.3.9E7
.2.6E7
.1.3E7
O.OEO
"27:00 ' ' ' Time
EI+ Voltage SIS 70T Noiae:2385
0. 051,9540. 0,1.00%,
F,T) Exp:KDB5US
INJ. TIKE ' 19:58
A7.49E6
n
-
^ _• /
251-00
1
V
'251-00'
2.0E6
.1 . 6E6
-1.2ES
.a.OES
.4.0E5
' 271-00 Tiffle
EI+ Voltage SIS 70T Noise: 2289
0.05%,5155.0,1.00%,
F, T) Elp:NDB5US
INJ. TIKE - 19:58
A9 . 76E6
23': 00 24\00
rile:T980158 #1-810 Acq: 6 -JAN- 9 8 19:55:03
330.9792 T:2 Ezp:NDB5US
TSIANSLE LASS Text:TLI#44376 125-128
1003
80:
so:
40:
20:
o:
22:51 23:22 ^23:46 24:05 ^£i^7
' 23\00 24\00~
rile:T9a01S8 #1-810 Acq:S-JAN-98 19:55:03
375.8364 T:2 Eip:SDBSOS
TSIANSLE LABS Text:TLI#44376 125-128
1001
80.
so:
40:
20:
0
23\00 24:00
'
/
25.' 00
I
' 26\00'
2.8E6
.2.3E6
_1 . 7E6
.1.1E6
.5 . 7E5
O.OEO
271-00 ' ' ' Tiffle
EI+ Voltage SIS 70T
INJ. TIKE - 19:58
24 jje 25jO 8 25:3
,j n in^'n'S^n «A ' ' ii* ~'r'"'«iii\ ^A
\\
V
'251-00'
7 25 -54 _i ,-
I ^V^^T
'2ff:0o'
27:02^_^27^J1_^_^_^1 . 8E7
.1 . 4E7
-1.1E7
-7.1E6
.3.6E6
O.OEO
27:00 Tine
EI+ Voltage SIR 70T
INJ. TIKE - 15:58
3SjJ-/\_ 3Sf
25 loo
V _A _ —
25: 00
27:00 4.4E5
1 27:23
IU J\A^r/
271-00
.3.5E5
.2.6E5
.1 . 8E5 J
.8.8E4M
0.0X0 |
Ti«e|
264
-------
rile:T980158 #1-810 Acq:6-J7Ut-98 19i55t03 EI+ Voltage SIS 70 T »>*«•: 181 4
319.8965 f:2 BSUB(256, 30, -3.0) PXD( 7,5, 3, 0. 05%, 7255.0,1. 00\,r,T) ExptXDBSUS
TSIANGLS LABS Text:TZH44376 125-128
loot
80.
sol
40.
201
o:
,
A1.36E8
A
M A9.08E7
1 \ , A •*'
1 A4.14E7 A &S.1SE7
l\ MA /v^v
24:00 ' ' '25:00
rile:TS80158 #1-810 Acq: S-JAir-98 19t55t03 EI+
321.8936 r-.2 BSUB(25S,30,-3.0) PKD(7, 5, 3,0.05
TSIAKGLE LABS Text:TLH44376 125-128
100]
so;
50.
401
20.
0'
ft
Al . 74E8
A:
I A1.16E8
1 A
A3. 12X7
A /
25:00
INJ. TIME * 19:58
3.24E7
A
_5.7r7
.4.5X7
.3.4E7
.2.3E7
.1.1E7
O.OEO
27:00 ' ... ^^^
Voltage SIS 70T Noise, 1428
,S712.0,1.00\,r,T) XxpsSDBSVS
j»j
A5.35E7 A .s -__, ., 3fl,7 —
fl A I \ AO • 3y£t / • nJ • y O£t /
1 \ 1 \ A /V^V i A /
24:00 ' ' ' 25:00 25:00
XKT. TIME » 15:58
S.3E7
[ . 06E8
A
'•.5.1E7
'-.3 . 8E7
'.2.5E7
'•-1.3E7
• 0 . OEO
271-00 Tine
jrile:T580158 #1-810 Acq : 6 -J7UT- 9 8 19:55:03 EH- Voltage SIS 70T Noise: 2103
331.9368 7:2 BSUB(256, 30, -3. 0) PKD(7, 5, 3, 0 .05\, 8412.0,1 .00*,F,T) Exp:NDB5aS
TRIANGLE LABS Text:TLZf 44376 125-128 •
1001
80:
sol
40:
20:
ol
Al..
1
24 1-00 ' ' ' 251-00 . 25:00
INJ. TIME - 19:58
10E7 3.3E6
H7.01E6
.2.7ES
.2.0E6
il.3E6
.6.6E5
O.OEO
27:00 ' Time
rile:TS80158 #1-810 Acq:6-JAN-98 19:55:03 EI+ Voltage SIS 70T Soi.ae-.lQ2S
333.9338 T-.2 BSUB(256,30, -3 .0) PKD(7,5,3, 0. 05\, 4100. 0,1 . 00*, f, T) Ezp:NDB5US
TRIANGLE LABS Text:TLI#44376 125-128
1001
80:
60.
40:
20:
0:
'
24i 00 251-00
rile:T980158 #1-810 Acq : 6 -JAN- 9 8 19:55:03 EI+
327.8847 T:2 BSU3(256, 30, -3. 0) PXD(7, 5,3,0 .05'
TRIANGLE LABS Text:TLI»44376 125-128
1001
80:
50:
40:
20:
ol
A2.46E7
A
/
A2.74E6 1 \
/\ /\/\ / V _
24:00 ' ' ' 25:00 '
TilesT9801S8 #1-810 Acq:6-JJOT-98 19i55s03 EH-
330.9792 r:2 ExptNDBSUS
TRIANGLE LABS Text'.TLIt44376 125-128
1001
80:
50:
40:
20:
ol
24:05 24:27 24:45 25:08 25:25
*"vy*^-*/~ ' •***^*-*'^ ~~>s**l^. «AJ-^\A^— ^— ^^-^^U J^j.— ..^^ f\
-
1
24:00 25:00
Al.S
1
26:00 '
INJ-. TIME - 15:58
OE7 4.2E6
A3.97E6
A
A
U V
.3.4E6
'.2 . 5E6
'.1 . 7E6
.8.5E5
O.OEO
27.' 00 riffle
Voltage SIS 70T No±ae:751
,3004. 0,1. 00%, T,T) Exp:KDBSUS
25:00
Voltage SIS
25 : 4 7 1*
.— «• • 01
1 \X^*^"^
y
25:00
JK7. TIME - 15:58
A2.21E7 6.7E6
A1.48E7 1
l\ I
A
/ \ / \
_7 I /I
-5.4E6
-4.0E6
-2.7E6
-1.3E6
O.OEO
27:00 ' Tiae
70T
JK7. TTMT - 15:58
25.-J2 26:4727:02 37 ill ..1.8E7
^^^/^^ — ^f V' --VW-V^ *-^-~
V
.1.4E7
-1.1E7
.7.1X6
.3.6E6
O.OEO
27:00 ' ' Mjte
265
-------
ri2eiT930153 #1-310 Acq:6-JXN-9a 19:55:03 EI+ Voltage SIS 70T Hoiae:1549
339.8597 f:2 BSUB(256, 30, -3.0) fXD(7,5, 3, 0. 05%, 6196.0, 1.00\,T,T) XzpiHDBSUS
TSIANGLS LASS Text :TLI 14437 6 125-128 HfJ. TIMS • 19:58
1001
80.
60-
401
20.
o-
A
f
A2.74Z8 6.1X7
A1.29E8
A » A1.01E8
A6.71E7 A \\A5.67S7A7.11E7 A A
1 A/UJVlMAA /VU,~ .
2S\ 00 29\00 JO: 00 Jl-00
.4.9X7
.3.7X7
.2.4X7
.1.2X7
0.0X0
T±ae
rile: 1980158 #1-810 Acg: S-J3Ur-98 19:55:03 XI+ Voltage SIS 70T So±ae:1413
341.8567 T:2 BSUS(25S, 30, -3.0) PXD(7,5,3,0 .05\,5SS2.0,1.00\,T,T) XxpsRDBSUS
TRIANGLE LABS Text:TLIt44376 125-128 HKT. TIMS - 19:58
1001
aol
so:.
40.
20.
o'-
A
1
A1.97ES 5.017
ft
"A!
IA4.49E7 \\A3.80E7A4.74E7 A A
I AMAJVlMAA A/V -
28:00 ' 39': 00 30':00 3l'sOO
.4.0X7
.3 . 0X7
.2.0X7
'•.9.9X6
0.0X0
Time
rile:T98015B #1-810 Acq:6-JAN-9B 19:55:03 XI+ Voltage SIS 70T Hoiae: 1162
351.9000 r-.2 BSUB(256,30,-3.0) PXD(7,5, 3, 0 .05\,464S.0, 1.0Q\,T,T) Exp:SDB5US
TRIANGLE LABS Text:TLI#44376 125-128 UKT. TIME " 19:58
1003
so:
SO:
40:
20:
o'-
Al. 8E7
A9.44ES
f\
A • ft
28:00 29\00 30 :00 Jli-OO
3 . 3X6
'.2.7X6
'•.2.0X6
.1.3X6
.6.7X5
0.0X0
Time
rile:T98015a #1-810 Acq:6-J7UT-98 19:55:03 EH- Voltage SIS 70T Noiae: 1225
353.8970 F:2 BSUB(256, 30, -3. 0) PKD(7, 5,3, 0 .051,4900 .0,1. 00\,F,T) £xp:NDB5US
TRIANGLE LABS Text:TLIt44376 125-128 TJK7. TIME - 13:58
1003
80.:
SO:
40:
20:
o:
A7.23ES 2.3E6
I "T
fl
ft ft
28.-00 29\00 JO.-OO 31:00
Ll . 8E6
.1.4X6
.9 . OE5
.4.SE5
0.0X0
Time
r±le:T9a0153 #1-810 Acq:S-JZjr-98 19:55:03 EI+ Voltage SIS 70T
330.9792 T:2 Eip:SDB5OS
TRIANGLE LABS Text:TLI»44376 125-128 IXT. TIME » 13.-58
1003
80:
so:
40:
20:
0
28:07 28:25 28:55 29:23 30,tflJO:05 30:2730:41 31:03 31:28
28\00 2SI-00 30:00 ' .31:00
_1 . 817
.1 . 4X7
.1.1X7
.7.1X6
.3.6X6
0.0X0
Time
r±le:T98015a #1-810 Acq:S-JAJt-98 19:55:03 EH- Voltage SIS 70T
409.7974 T:2 Sxp:lO>BSUS
TRIANGLE LABS Text :TLI 14437 6 125-128 XK7. TIME - 19:58
1003
80:
60:
40:
20:
31. 11
30:51
30:16 A
T A n
\ ",45 ,
28:55 2*,11 / W A 30>03 \ 30L38 \ /
. ^x^vA-^J^XXj VV_7 V__y\_J v A.J \_^J l_ /
28\00 29\00 30\00 ' 31\00
.1.2X5
.9 . 8X4
.7.4X4
.4.9X4
.2.5X4
0.0X0
Time
266
-------
J55.35.rfiS T:2 BSOS(256, 30, -3.0) PKD(7,5,3,0.05\f2152.0,1.00\,r,T) Xxp:SDB5OS
TSXANGLX LABS Toxt:TLI»44376 125-128 HOT. TXMX - 19:58
1001
80.
60.
40.
20.
0
Ai.sors , ,__a
J A1.37E8
fl I
I (1 A9.19E7
A
A
1 1 I A4.S5X7
\ I A1.39X7 I \1.33X7\ \ A3.35E7 \1.43E7 A103S7 A9.a3s6
J \ /X / v/\j 7 vT^^X 7 Y/X /X /v /\
4.9X7
'.3.9X7
.2.9X7
J..9X7
.9.7X6
0.0X0
28:48 29l:bb 29\12 29:24 29:36 29': 4 8 30:00 30:12 30:34 30:36 3o':48 31:00 31\12 3l':24 Time
r±la:T980158 #1-810 Acq:6-JAS-98 19:55t03 XI+ Voltaffe SIS 70T Soiae: 677
357.8516 T:2 BSOB(256, 30, -3.0) PXD(7,5,3,0 .OS\,2708.0,1.00*,T,T) Xxp:JO3B5US
TRIANGLE LABS Text:TLIt44376 125-128 OKT. TIME - 19:58
1003
80.
60.
40.
20.
0.
A1.26ES -3.2X7
|f "'I7*7
A
AT7
A
i A2.94E7
\ A, « ,
/ \A5.81Z6 A9-"ES / \a-Z°ESl \ AfA5S7/\A ~*6.71E6 A6.29E6
J V^ j/^\^ ./ x J V^/ \^ J V j/ ^^ \^ J V/ v ,/ v /^x v^x
'.2.5X7
.1.9X7
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.6.3X6
O.OEO
ifll-ifl' ~29*:'oo' '29{:'l2' 29\ 24 29\36 29:48 30:00 30\12 JO.-.24I jol- 36 ' Jbl-48 ' ill- 00 ' 31 ': 12 ' 31 :24' Xiae
rile:T980158 #1-810 Acq:6-JAN-98 19:55:03 XI+ Voltage SIX 70T Noiae:442
367.8949 F:2 BSU3(256, 30, -3. 0) PKD( 7, 5, 3, 0. 05%, 1768. 0,1 . 00%, F, T) Eip:SDB5US
TRIANGLE LABS Text:TLI#44376 125-128 INJ". TIKE - 19:58
1004
80.
so:
40.
20:
;
0'
A6.44E6
M
!
-
1 A6.13E5
J V/X
r2.1E6
.1 . 7E6
_1 . 3E6
".8.4E5
-4.2X5
' 0 . OEO
28(:48 29[:bb' '29^:12 29V24 29\36 29':48 30:00 30\12 '30\24 30\36 3Q\48 3lVob 3lVl2 ' 3l':24 Tine
file:T980158 #1-810 Acq : 6 -JTUf- 9 8 19:55:03 EH- Voltage SIS 70T Voiae:2170
369.8919 r:2 BSUB(256, 30, -3. 0) PJH>(7, 5, 3, 0. 05%, 8680. 0,1 . 00\,T,T) Exp:lO>B5US
TRIANGLE LABS Text:TLI#44376 125-128 IKT. TIME - 15:58
1004
80.
60.
40.
20.
0.
A4.43E6
'
:
/ A5.26E5
J V/X
.1.5X6
.1.216
.8.9E5
.6.0E5
.3.0E5
O.OEO
28\4a 29:00 29:12 29\24 29': 36 29:48 30:00 30:12 30:24 30\36 JO-48 Jl.'oo 3lVl2 31:24 Tine
rile:T980158 #1-810 Acq:6-JAlT-98 19:55:03 XI* Voltage SIS 70T
330.9792 T:2 XxptUDBSUS
TRIANGLE LASS TeJCt:TLI»44376 125-128 UU. TIME ' 19:58
1001
ao.
60.
40.
20.
o:
^ ^^t^ 39:10_"i" 39:37 ",50 30:05 3Q^ 16 30j27 30:4^1^ 31 L03 31:18^
'
.1.7X7
.1.4X7
.2.0X7
.7.0X6
.3.5X6
O.OEO
28:48 29:00 29:12 29:24 29:36 29'i4B 30:00 30:12 30:24 30: 36' 30: 48 31:00 3l':12 31:24 Mae
26'
-------
\32:00 33:00 34:00
rile:T980158 #1-396 Acq:6-JJUr-98 19:55:03 EI+ Voltage SIS 70T Soiae:2962
383.8639 f:3 BSUB(256,30, -3. 0) tXD(7,5, 3, 0. 051,11848. 0,1. 00\,r,T) Sip-.SDBSOS
TRIANGLE LABS Text:TLI#44376 125-128 JJW. TIKE - 19:58
100$ A4.86E6
fl 0J I A4.44E6
60:
40:
20:
rileiT9a0158 #1-396 Acq:6-JMT-98 19:55:03 EH- Voltage SIS TOT noiae:6659
373.8208 T:3 BSUS(256,30, -3. 0) PKD(7,5,3, 0.05\,26636.0,1. 00\,T,T) ExptNDBSUS
TSIANGLX LABS T*xt:TLI#44376 125-128 HfJ. ma - 19:58
100$ I A1.61E8
A1.45EB
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A1.59X7
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Al . 36E7
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Tile:T9»01Sa #1-396 Acq:6-JJOt-98 19:55:03 EI+ Voltage SIS 701 Soiae:6036
375.817$ T:3 BSUB(256,30,-3.0) PXD(7,S,3f0.05\,24144.0,1.00\,T,T) XrptXDSSUS
TSIASSLS LABS Text:TLI#44376 125-128 IKT. ma - 19:58
100A A1.2SES
80:
60:
40:
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Al . 07E7
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A3. 75E6
133:00 33:00 34:00
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385.8610 T:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,10580. 0,1. 00\,T,T) EiptKDBSUS
TSIANSLS LABS Teit:TLIf44376 125-128 XJW. TIKE - 13:58
1003* A9 14E6
A8.39E6
80:
60:
40.
20:
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A7.31E6
32:00
rile:T98015a »l-396
392.9760 T:3 Eip-.NUBSUS
TRIANSLS LABS Text:TLH44376 125-128
100$
32:00
80:
33:00
19:55:03 EI+ Voltage SIS 70T
34:00
INJ.
19:58
5.0X7
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2.3E6
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60:
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32:00 33:00
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445.7553 F:3 Exp:HDBSUS
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TSIANSLS LABS Text:TLI#44376 125-128
100$
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2.3E5
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268
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389.9156 T>3 BSOB(256,30, -3. 0) PKD(7,5,3, 0. OS\, 16960.0,1.00\,F,T) BcpiNDBSUS
TSIAKSLE LASS Taxt:TLIt44376 125-128 HKT. TIME - 19:58
lOOi A1.S.3E8
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391.8127 T-.3 BSUB(256,30,-3.0) fXD(7,5,3, 0.05\,12380. Q,1.00\,T,T) ZxpiHDBSUS
TXIAXGLX LASS Text:TLH44376 125-128 HKT. TIKE - 19:58
1001 A1.25E8
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TRIANGLE LABS Text:TLI*44376 125-128 INJ. TIME • 19:58
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32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
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403.8529 T:3 BSUS(256,30, -3. 0) PKD(7,S,3, 0. 051,15432. 0,1. 00\,T,T) ExpsNDBSBS
TRIANGLE LABS Text:TLI#44376 125-128 IMJ. TIKE - 19:58
1001 A9.48E6
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392.9760 f:3 ExpiNDBSOS
TXIANGLE LABS Text:TLI»44376 125-128 HKT. TIKE » 19:58
34:00 34:12 34:24
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TRIANGLE LABS Text:TLI#44376 125-128
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409.7789 T:4 BSUB(256, 30, -3.0) PKD( 7,5, 3, 0. 05%, 7412.0 f1.00\,r, T) XxptSDSSUS
TRIANGLE LASS Teit:TLI#44376 125-128
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417.8253 F:4 BSUS(256, 30, -3. 0) PKD(7,5, 3, 0. 05%, 6424. 0,
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TRIANGLE LABS Text:TLI#44376 125-128
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file:T980153 #1-563 Acq:6-JAN-98 19:55:03 EI+ Voltage
430.9729 T:4 Exp:NVB5US
TRIANGLE LASS Teit:TLI#44376 125-128
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JTSLS LABS Text:TLI#4437S 125-128 1ST. TIMS - 19:58
A5.79E7
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JfSLE LABS Text:TZI#44376 125-128 INT. TIME - 19:58
AS. 75X7
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8169 T:4 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 05%, 3808. 0, 1 . 00%, T, T) Elp:NDB5US
NSLE LABS Text:TLI#44376 125-128 XW7. TIME - 19:58
A5.26E6
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NGLE LABS Text:TLI#44376 125-128 UfJ. TIME - 15:58
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36:27 36:37 J5vf^«_v^_iZ
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441.7438 ti4 BSUB(35S, 30, -3. 0) Pa>(7r5,3,0.05\,1360.0,1.00\,T,T) XzpiSDBSOS
TRIANGLE LASS Taxt:TLI«44376 135-138 H&. TIKE - 19t38
1001
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40.
301
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TRIANGLE LASS TeJCt:TLH44376 135-138 I2KT. TIME ' 19:58
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38:15 38,49
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430.9739 T:4 Exp:NDB5US
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TRIANGLE LABS Text:TLIt44376 135-138
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Height 3.59 volts Span 298.ppa
System fits nae N08SJS
Data filename f):TS88148
Resolution 18888
Groflnuiter 2
lonlzatlcn aode El*
Switching VOLTRGE
Ref, lasses 292,3825, 416,3768
fl 293 J 331 S 368
8 384 K 332 T 378
C 386 L 334 U 376
D 316 H 348 V 418
E 318 H 342
F 329 0 352
6 322 P 354
H 328 Q 356
I 331 R 358
Ref, sass 416,3768 Peak top
Height ,36 wits Span 288 ppa
274
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Pile:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME =
100%
80j
60j
40J
20 j
OJ
33:40 33:42 33:44 Time
19:58 File Text:TLI#44376 125»
1.3E6
L1.0E6
L7.5E5
L5.0E5
L2.5E5
I- n . OEO
33:18 33:20 33:22 33:24 33:26 33:28 33:30 33:32 33:34 33:36 33:38
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME = 19:58
100%, 33:26
33:40 33:42 33:44 Time
File Text:TLI#44376 125»
..2.1E5
33:405342 3344 Time
33:18 33:20 33:22 33:24 33:26 33:28 33:30 33:32 33:34 33:36 33:38
CD
-------
File:T980158 81-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME =
lOOi 34:23
80J
60J
40_
20_
0
34:14
19:58 File Text:TLI#44376 125»
_2.9E6
_2.3E6
_1.7E6
_1.2E6
_5.8E5
34:06 34:12 34:18 34:24
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI + Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME =
1004. 34; 18
80j
60 j
40J
20 j
Oj
34:06 34:12 34:18 34:24
File:T980158 #1-396 Acq:6-JAN-98 'l9:55:03 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128
1004 34;14
80J
60 j
40_!
201
0
34:30
LO.OEO
Time
19:58 File Text:TLI#44376 125»
1.1E6
L8.4E5
L6.3E5
_4.2E5
_2.1E5
34 :30
O.OEO
Time
INJ. TIME = 19:58 File Text:TLI#44376 125»
34:06
34:12
34:18
34 :24
34 :30
lO.OEO
Time
ro
no
o
-------
Hle:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME
100% A1.10E7
80 j
60j
40_
20_
0
A2.98E6
19:58 File Text:TLI#44376 125»
_2.9E6
_2.3E6
_1.7E6
_1.2E6
._5.8E5
34:06 34:12 34:18 34:24
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME
100% A8.60E6
80J
60j
40J
20 j
OJ
34:30
34:36
lO.OEO
Time
A2.41E6
19:58 File Text:TLI#44376 125»
2.3E6
L1.9E6
L1.4E6
L9.3E5
14.7E5
34:06 34:12 34:18 34:24
File:T980158 #1-396 Acq:6-JAN-98 19:55:03 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 125-128 INJ. TIME
100% 34;18
34 :30
34:36
1.0. OEO
Time
19:58 File Text : TLI#44376 125»
OJ
_8.4E5
_6.3E5
_4 .2E5
_2.1E5
34 :06
34:12
34 :18
34:24
34:30
34:36
lO.OEO
Time
-------
TLI Project: 44376
Client Sample: 125-128
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P98016
i
Client Project Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97
TLI ID: 194-59-6A-6D Date Extracted: 12/29/97
Date Analyzed: 01/10/98
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a
Blank File: X980083
Analyst: WK
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
^
SPC2NF04
PF22206
P980164
: n/a
n/a
n/a
;aiw&tte ' ' ', - \-*~ Amktn0> ' ^~Dt aipc '- '~&*i*;^~ m * Flags -
23,7,8-TCDF
17.5
Internal Standard Ami (ng> % Recovery QC Limits
'3C12-^3,7,8-TCDF
Recovery Standard
13C,2-1,2,3,4-TCDD
2.0 51.0 40%-130%
0.73
'R^tto ^
0.77
ftatw |;
0.83
23:05
f)T Flags
23:04
RT Flags
21:53
Data Reviewer..
01/11/98
Page 1 of 1
ONFJ>SR rlOl. LARS&l
Triangle Laboratories, Inc.*
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:35 01/11/98
-------
Initial
Data..
Data Review By:
( I K 1 4? Calculated Noise
Area:
>
be Total Area for each peak with an ion abundance ratio outside
atio limits has been recalculated according to method requirements.
2.00
Page No.
01/11/98
Listing of P980166B.dbf
Matched OC Peaks / Ratio / Ret.
Tin
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Na
ID.. Flags.
TCDP 0
304-306 DC NL 0:00 RO
18:27
18:43 RO
19:27
19:34
19:42
19:53
' 20:08
20:18
\ 20:26
20:36
20:45
21:08
21:35
21:41
21:50
22:04
22:13
22:29
22:43
22:56
23:05
. 23:18
' 23:34
' 23:41
24:28
24:37
- 25:13
304-306 27 Peaks
13C12-TCDF , 0.
316-318 DC NL 0:00 RO
DC WL 18:29 RO
DC WL 20:05
DC WL '• 20:30
DC WL 20:42 RO
DC WL 21:09 RO
DC WL 21:37 RO
DC WL ' 21:41 RO
DC WL : 21:47 RO
23:04
DC SN 23:25 RO
DC SN 23:33 RO
.65-0.89
1.06
0.74
1.78
0.75
0.74
0.74
0.72
0.74
0.74
0.78
0.72
0.75
0.73
0.77
0.65
0.75
0.74
0.75
0.73
0.74
0.73
0.73
0.74
0.75
0.76
0.75
0.75
0.65
65-0.89
1.42
0.63
0.33
0.67
5.86
2.92
0.93
1.58
2.37
0.77
0.44
0.18
37
11,333
26
8,793
8,991
21,193
7,603
8,106
17,360
8.336
28,093
13,897
43.066
10,052
1,770
16,304
11,043
1,852
15,609
613
15.663
7,309
16,332
13.248
11,650
6,239
152
985
306.134
.35
.86
.96
.11
.47
.00
.15
.24
.81
.28
.50
.04
.20
.03
.35
.39
.51
.76
.79
.30
.57
.11
.63
.35
.49
.09
.42
.72
.13
4
3
3
9
3
3
7
3
. 11
5
18
4
6
4
6
6
3
7
5
5
2
,833
27
,767
,833
,024
,183
,452
,374
.645
,724
,964
.172
,356
698
,966
,708
791
.584
260
.592
,081
,155
,672
,014
,666
65
387
.58
.17
.20
.80
.90
.68
.17
.85
.30
.30
.00
.30
.33
.61
.95
.93
.50
.47
.66
.85
.06
.62
.93
.18
.72
.23
.76
6,500
15
5,025
5,157
12,168
4,419
4,654
9,985
4,690
16,368
7,933
24,393
5,695
1,071
9,337
6,334
1,061
9,025
352
9,075
4,223
9,677
7.575
6,636.
3,572
87
597
0.793-1.101
0.000
.28 0.800
.23 0.811
.91
.67
.10
.47
.07
.96
.48
.70
.04
.40
.20
.74
.44
.58
.26
.32
.64
.72
.05
.01
.42
.31
.37
.19
.96
0.343
0.348
0.854
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
0.957-
2
• 7,
9,
16.
5.
1.
9.
0.
5.
1,606.
2.
1.
.73
.01
.85
.13
,75
.82
.29
85
,12
35
28
20
701.
.05
905.
30
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
.862
,873
.380
.386
393
900
916
936
940
947
957
967
975
985
994
001 2378-TCDF AN
010
022
027
061
067
093
1.043
000
801
871
889
897
917
937
940
944
000 13C12-2378-TCDF ISO
015
021
E
B
S
E
E
E
E
E
E
E
E
E
E
E
B
E
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:21 01/11/98
283
-------
Page No.
01/11/98
Listing of P980166B.dbf
Matched
-------
File:pS301SS #1-932 Acq:10-JM-199B Us29:50 Bit Voltage SIS 70» Noiae:1116B
303.9016 BSUB(256,30,-3.0) PKD(5, 3,1, 0.101,44672.0, 0.00\,T,T) Exp:DB225
TRIANGLE LASS Text.: 125-128 TLI#44376
1004 ' Al 2E8
19:00 30:00 21:00 22:00 23': 00 24': 00
rile:P980166 #1-922 Acq: 10-J3OT-1998 12:29:50 EH- Voltage SIS 70P Boiae-.lOSSO
305.8987 BSUB(256,30r-3.0) PKD(5, 3,1, 0.10\, 42200. 0, 0. 00%,T,r) Kxp:DB225
TRIANGLE LABS Text:125-128 TLI»44376
100* A2.49E8
25:00
80.
60.
40:
20.
A1.22E8
A9.34E7
A9.03E7
A9.08E7
A9.68E7
'
A3.57E7
19': 00 20': 00 21:00 22:00 23:00 24:00
File:P980166 #1-922 Acq: 10-JAN-1998 12:29:50 EI+ Voltage SIS 70P Hoise:1092
315.9419 BSU3(256,30,-3.0) PKD(5, 3,1, 0.10%, 4368. 0, 0. 00\,F,F) Eip:DB225
TRIANGLE LABS Text: 125-12S TLI#44376
lOOi, ' A7. 1E6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23:00 24:00
File:P980166 #1-922 Acq:10-J7Uf-199B 12:29:50 EH- Voltage SIS TOP Noise:772
317.9389 BSU3(2S6,30,-3.0) PXD(S, 3, 1, 0.10\, 3088. 0, 0. 00\,F,F) Exp:DB225
TRIANGLE LABS Text:12S-128 TLI#44376
1004 A9.Q5E6
so:
60.
40.
20:
1" i i
25:00
15:00 20:00 21:00 22:00 2J.-00
File:P980166 #1-922 Acq:10-JAN-1998 12:29:50 EH- Voltage SIR TOP
375.8364 Exp:DB225
TRIANGLE LABS Text:125-128 TLI#44376
24: 00
25:00
1001
80.
60.
40.
20.
0.
22; 42
18:28
19:08
20:48
: 52
24:36
19:00
20:00
21:00
22,00
3.2E7
'.2.6E7
.1.9E7
.1.3E7
.6.4E6
.O.OEO
Tin
1. 4E6
.1. 2E6
.8. 7E5
-S.8ES
-2.9ES
O.OEO
Time
_I.8E6
1.5E6
1.1E6
7.3ES
3.6E5
O.OEO
Time
23:00
34:00
251 00
.1. 8ES
.1.5E5
.1.1E5
.7.3E4
,3.7X4
O.OEO
Time
2S5
-------
319.8965 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10\,
0 EI+
2600.
Voltage SIS 70P Hoiae:tit>0
0,0.00\,e,T) Elp:DB225
TRIANGLE LABS Taxt:125-128 TLIV44376
1001
80.
60.
40.
20.
0
11
I
,,
\ 1
19E8
\ TAA*T'
20 : 00 21 : 00
A6.78E7
-/Vf Vv -r^—
-4.6E7
'.3.7E7
.2.8E7
.1 . SE7
.9.2E6
O.OEO
221-00 2J:00 24:00 Time
Tile:P980166 #1-922 Acq:10-JZlT-199a 12:29:50 EI+
321.8936 BSUB(256,30,-3.0) PKD< 5, 3,1, 0.10%,
2S50.
Voltage SIS 70P Noise: 665
Q,0.00\,T,r) Elp:DB22S
TRIANGLE LABS Tert:125-12fl TLH44376
1001
80.
60.
40.
20;
0'
Al . 52E8
i.
A4'ft5E7f\ A A3.61E7
\ AAA A
20 1-00 21 .-00
A8.65E7
/~*J\ Vv ^ x-^_
-6.0E7
'.4.8E7
.3 . 6E7
.2.4E7
.1.2E7
O.OEO
22:00 ' ' '2J1-00' ' ' ' 24:00 Time
File:P980166 #1-922 Acq: 10-JAN-1998 12:29:50 EI+
327.8847 BSUB(256, 30, -3 . 0) PKD(5, 3, 1, 0. 10%,
2964 .
Voltage SIR 70P Noise: 741
0,0.001,F,F) Exp:DB22S
TRIANGLE LABS Text: 125-128 TLI#44376
1003
80.
60.
40.
20.
0
Al.
A6.50E6 .
Ah
A3.04E6 \
, A1.35E^\ A A1.13E6 1 \
y^ ^~yv J \ /V_~A_/L/
20 1-00 ' 21 .-00
A2. E7 4.8E6
A1.66E7
18E7
A
u
I / I
'.3 . 8E6
'.2.9E6
'.1.9E6
'.9.6E5
" 0 . OEO
22 .-00 2-jl-OO 241-00 Time
File:P980166 #1-922 Acq: 10-JAN-1998 12:29:50 EI+
331.9368 BSUB(256,30,-3.0) PKD(5, 3, 1, 0.10%,
Voltage SIR 70P Noise: 691
2754 .0,0.00%, F,F) Exp:DB22S
TRIANGLE LABS Text: 125-128 TLI#44376
1003
80.
60.
40.
20.
0
File:P980166 #1-
AS.
1
1
201-00 ' ' ' 21:00
A1.03E7
n
78E6\
I
1 /
\
\
-2.4E6
.1.9E6
-1.4E6
-9.7E5
.4.8E5
O.OEO
22 .-00 2J.-00 24:00 Tine
922 Acq:10-JAN-1998 12:29:50 EI+
Voltage SIR 70P Noise:363
333.9338 BSUB(256,30, -3.0 ) PKD(5, 3, 1, 0.101,1452. 0, 0. 00*,r,F) Exp:DB22S
TRIANGLE LABS Text:125-128 TLI#44376
1004
80.
60.
40:
20:
o:
A1.24E7
A7.21E6\\
A 1 1
1
20:00 21:00
II'
(
.2.9E6
.2.3E6
.1 . 7E6
.1.2E6
.5 . 8E5
O.OEO
22:00 2J:00 24:00 Tiae
2S.6
-------
rile:P980166 #1-922 AcqtlO-JAN-1998 12:29:50
303.9016 Exp:DB225
TRIANGLE LABS Text:125-12B TLI#44376
1001 20.-J* 31i08
80: 15:42 A \
SO 20:18 II
' ' 18:27 - A i
4°~- l\ A A Al A/
30-: l\ /VviA |yyV I/I j L
15:00 20:00 21:00
rile.-?98015fi #1-522 Ac?:10-J3Ur-1558 12:29:50
315.9419 Exp:DB225
TRIANGLE LASS TeJCt.-125-l.2S TLI144376
1003
so:
50:
40:
20:
151-00 20 1-00 21 loo
rile:P980166 #1-922 Ac 22:56 A
21 • 35 11 A
II (1
A A
IUILO
\A
nil
24:28
/l/«l A -
.1.9E7
.1 . 4E7
.9 . 4E6
.4. 7E6
O.OEO
22:00 2J:00 24:00 25:00 Zloe
TJ* Voltage SXB 70?
33
J
04
L
1 . 4E6
.1.2E6
la.7E5
.5 . 8ES
-2.9E5
O.OEO
221-00 2J.-00 241-00 25:00 Tine
EI+ Voltage SIR TOP
21:54
4.6E7
.3.7E7
.2.8E7
.1 . 8E7
.9.2E6
'•O.OEO
22-00 2J.-00 24-00 25-00 Time
EI+ Voltage SIS 70P
21 : 53
2.4E6
so: ;. 21i36\\
40:
20: i
o1
15:00 20:00 21:00
File:P980166 #1-922 Ac"'^^^"* Nn^jif^'V"*' ' * ' \**\J* >*^ y
-1.1E7
-8.3E6
.5.SE6
.2.816
a nrn
22:00 23:00 24:00 25:00 Time
997
»*• *—• I
-------
:n
5
M
JD
5
• '-1
A
1
T
M
A
^SB^^JT
lEES^^T
IWST . Mas uttwcu re* up
Helctt 1.63 volts Spat 266 ppi
Systei file naie 06225
Data file naie fl'P988166
Poenji^inn IflflM
nUMULUXI iWUU
Group nuker 1
lonlzatlon Kde El*
Switching VlTflGE
Ref. lasses 292.9825, 386.9761
B 292.9825 J 336.9792
8 363.9616 K 331.9368
C 385.8987 I 333.9338
0 315.9419 H 3E.8364
E 317.9389
F 319.8965
G 321.8936
H 327.8847
I 336.9792
Channel I 336.9792 Peak top
Height 1,99 volts Span 266 ppi
-------
TLI Project: 44376
Client Sample: 129-132
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980159
Client Project:
Sample Matrix:
TLI ED:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received:
194-59-7A-7D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
12/17/97
12/29/97
01/06/98
n/a
T980150
BR
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980148
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD ,
1,2,3,6,7,8-HxCDD ;
1,2,3,7,8,9-HxCDD ;
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD |
2,3,7,8-TCDF ',
1,2,3,7,8-PeCDF :
2,3,4,7,8-PeCDF '
,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF !
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6.7,8-HpCDF
1,2,3,4,7,8,9-HpCDF '
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD i
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF \
Total HpCDF
Amt. (ng) DL EMPC
0.04
0.18
0.17
0.27
0.41
1.2
1.8
4.1
0.91
1.6
3.5
1.3
1.7
0.09
4.8
0.87
4.0
Amt (ng) Number DL EMPC
4.5 11 4.5
2.9 9 4.4
4.2 7
2.3 2
26.1 16 26.1
21.4 15 21.6
13.9 13 13.9
8.1 4
Ratio
0.68
1.52
1.20
1.17
1 22
1.04
0.84
0.81
1.46
1.55
1.25
1.28
1.28
1.05
1.13
1.02
0.89
BT
26:21
30:31
33:36
33:42
34:00
37:05
40:57
25:41
29:29
30:11
32:53
33:00
33:30
34:18
36:00
37:37
41:10
Ffegs
PR_
PRJ
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Page 1 of2
X237.PSR Y2.01. LARS & 10.080
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5^91
Printed:
01/15/98
-------
TLI Project: 44376
Client Sample: 129-132
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980152
internal Standards
13C,2-2,3,7,8-TCDF
1JCij-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13Cu- 1,2,3,4 A7.8.9-OCDD
Surrogate Standards (Type A)
"CU-W.S-TCDD
13Cir2,3,4t7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-U,3,4,7,8-HxCDD
l3Cr-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13Ci2-l,2,3,7,8,9-HxCDF
13Ci2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
"Cu-1.2,3,7.8.9-HxCDD
Amt (rig)
2.7
2.7
3.1
3.6
3.0
3.6
3.5
4.5
.8.8
AntL (ng)
3.3
3.8
4.0
4.1
4.3
Amt. (ng)
3.3
3.0
% Recovery
66.7
67.7'
76.8
90.6
75.8
90.7
86.6
112
109
% Recovery
82.6
94.1
99.9
104
107
% Recovery
82.5
76.1
QC Limits
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%- 130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%- 130%
40%- 130%
Ratio
0.74
0.79
1.55
1.44
0.51
1.18
0.44
1.05
0.91
Ratio
1.51
0.51
1.16
0.44
Ratio
0.51
0.52
Ratio
0.81
1.16
m
25:39
26:20
29:29
30:30
32:59
33:41
36:00
37:05
40:56
RT
26:21
30:10
32:53
33:35
37:37
RT
34:18
33:30
RT
26:10
34:01
Fiags
—
—
Flags
—
FEagsfl
—
Fiags
—
Data Reviewer
01/15/98
Page 2 of 2
X237.PSRv2.01. LARS 6.1
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98
2SC
-------
Initial
• .Date. .
DaCa Review By:
*J
Calculated Noise Area: 1.72
he Total Area for each peak with an ion abundance ratio outside
•atio limits has been recalculated according to method requirements.
Page No.
01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Ratio. / Ret. Time
Compound/
M_Z.... QC.Log Omit Why . ,RT. OK Ratio Total.Area... Area.Peak.1.. Area. Peak.2. . Rel.RT Compound.Name.
ID.. Flags.
TCDF
304-306
DC NL 0:
0
:00 RO
22:39
| 04-306
13C12-TCDF
316-318
316-318
TCDD
320-322
23
23:
23:
24:
24:
1 24:
24:
, 25:
25:
; 25:
25:
26:
' 26:
26:
, 26:
; 26:
27:
:08
:21
:43
:02
:24
40
;53
;05
:16
30
41
05
18
32
49 RO
58 RO
20
.65-0.89
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
18 Peaks
'
DC NL 0:
DC WL 22:
DC WL^ 24:
DC ML' 24:
25:
1 25:
25:
! 26:
DC WH 27:
0.
00 RO
41
04
13
07 RO
15
39
04
35
.23
.82
.32
.78
.81 3
.33 2
.79 2
.78 1
.31 1
.79 4
.30 1
.31 1
.31 4
.30 1
.73
.74
.98
.31
.32
27
5
848
891
756
,488
,474
,723
,893
,272
,270
,079
,083
,247
,071
865
179
11
7
117
,282
.38
.00
.59
.87
.94
.63
.78
.51
.23
.33
.12
.53
.14
.35
.21
.09
.34
.38
.05
.59
382
401
330
1,557
1,124
1,203
831
569
1,891
479
485
1,900
476
373
76.
6.
5
52
.65
.30
.43
.35
.42
.23
.49
.47
.10
.30
.83
.52
.36
.65
.13
. 58
.33
.69
465
490
426
1.931
1,350
1,520
1,062
702
2.379
599
597
2.346
594
436
102
6
4
64
65-0.39
1.
0.
0
0.
1.
0,
0.
0.
0.
4 Peaks
DC NL 0:
23:
i 24:
24:
DC SN 24:
25:
25:
0.
00 RO
54
16
34
55 RO
12
27
.42
.85
.75
.31
.19
.32
.74 3
.69
69
3
65-0.39
0.
0.
0.
0.
1.
0.
0.
57
79 1
30
71
56
78
76
2.
8.
IS.
4.
8.
20.
,049.
19.
11.
.64
.02
.77
.99
,53
61
63
59
63
,098.36
T(" HP 1 TV-
1 V— LIC 1 L\f
2.
,443.
883.
107.
0.
422.
228.
60
87
23
46
97
90
17
5.
9.
1,293.
a.
72
31
10
02
4
11
1.756
11
0.878-1.073
.35
.29
-39
.59
.21
.55
.02
.76
.73
.32
.70
.62
.49
.56
.96
.69
.45
.36
0.000
0.383
0.902
0.910
0.925 Q
0.937
0.951
0.962
0.970
0.973
0.985
0.994
1.001 2373-TCDF AN
1.017
1.025
1.034
1.045 J
1.051 J
1.066
0.961-1.039
.82
.30
.53
.57
0.000
0.384
0.938
0.944
0.979
0.984
1.000 13C12-2378-TCDF ISO
1.016
1 .075
639.
391.
44.
185.
98.
37
55
46
22
89
0.903-1.045
804.50
491.68
63.00
237.68
129.
28
0.000
0.908
0.922
0.933
0.946
0.957
0.966
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98
2S1
-------
Page No.
01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Racio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
H
AN
AND
AND
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D TE
D TE
12
25
26
26
26
26
26
26
26
27
:51 0.78
:14 0.78
:21 0.68
:21 0.68
:21 0.68
:31 0.70
:40
:52 RO
0.77
0.98
:18 0.34
Peaks
117
434
37
38
38
53
58
17
21
3,824
.34
.00
.50
.90
.90
.40
.24
.06
.27
.44
51
190
15
21
25
9
9
.53
.00
.20
.94
.40
.44
.74
65.31
244.00
22.30
31.46
32.84
9.64
11.53
0.982
0.996
1.001 2378-TCDD AN
1.001
1.001
. 1.007
1.013
1.020
1.037
0.924-1.076
DC NL
DC WL
DC WL
DC WL
DC SN
13
DC NL
DC SN
DC SN
DC SN
DC SN
5
DC NL
0
23
24
24
24
24
25
25
25
25
26:
26:
26
26:
27:
27;
27;
27:
:00
:55
:10
:17
:27
:35
:01
:13
:40
:52
:03
:13
:21
:43
:16
;27
:33
: 46
Peaks
0:
25:
25:
26:
26:
26:
26:
27:
27:
27:
0.
.00 RO
;14
45 RO
10
20
40
54
08 RO
27 RO
45 RO
65-
2.
0.
3.
0.
0.
0.
0.
5.
1.
2.
Peaks
0:
27:
27:
28:
1.
00
33
53 RO
00 RO
32-
1.
1.
1.
1.
0.39
29
80
00
31
79
78
74
36
04
34
1.78
37
47
80
82
1
8
4
6
.7
2
465
6
11
2
g
3
2,077
262
2.
1.
3.
3.
2,861.
.31
.41
.73
.36
.63
.17
.56
.64
.53
.85
.52
•71
.92
.62
.76
.50
44
19
59
7
2
465
6
11
2,
6.
3.
2,077
262.
2.
3.
3.
.68
.17
.56
.64
.53
.35
.52
.71
.92
.62
.76
44
19
0.000
0.908
0.913
0.922
0.928
0.934
0.950
0.958
0.975
0.982
0.989
0.996
1.001 37C1-TCDD SUR
1.015
1.035
1.042
1.049
.1.054
0.924-1.076
3.
15.
2.
2,960.
2,499.
.42.
10.
1.
2.
2.
98
59
27
05
33
05
67
33
14
55
5,528.24
• TCDD / Pe<
2.
1,694.
47.
31.
92
23
12
31
6.
1,322.
1,101.
18.
4.
92
69
30
45
54
8.67
1,637.36
1,393.58
23.60
. 6.13
0.000
0.953
0.978
0.994 13C12-1234-TCDD RSI
1.000 13C12-2378-TCDD IS1
1.013
1.022
1.030
1.042
1.054
~nT? Vnl 1 rtbra
1,007.
33.
22.
39
35
34
0.931-1.063
686.34
13.48
12.28
0.000
0.934
0.946
0.950
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98
2S2
-------
Page No.
01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
M
M
M
AN
340-342
13C12-PeCDF
352-354
M 2-354
PeCDD
356-353
356-358
13C12-PeCDD
363-370
1 ' 28
28
28
28
28
: 29
29
. 29
29
29
29
30
30
! 30
i 30
31
DC WH 31
:10
:18
:32
:40
:49
:07
:14
:25
:29
:40
:47
:11
:19
:38
:52
:08
:35
RO 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
RO 1.
1.
1.
29
39
50
51
50
47
55
46
46
50
52
55
51
37
01
37
32
19 Peaks
DC NL ' 0:
DC SN ! 28:
28:
DC SN ' 29:
29:
| 29:
30:
•' 1
:00
:20
;37
:49
14
: 29
46
:10
08
1.32-
RO 1.
RO 0.
RO 1.
1.
RO 7.
1.
RO 1.
1.
RO 1 .
6 Peaks
t •
DC NL | 0:
28:
•| 28:
29:
29:
29:
29:
'30:
1 30:
i 30:
i 30:
30:
30:
00
:45
57
14
27
35
46
01
13
20
31
38
57
1.32-
1.
RO 1.
RO 0.
1 .
1.
1.
1.
1.
1.
RO 0.
1.
1.
1.
1.78
18
72
16
73
46
55
23
51
21
1.78
47
16
04
32
53
51
54
50
53
58
52
60
76
12 Peaks
36
39
652
3,887
816
1,412
1,746
798
700
612
962
1,224
1,550
258
6
147
4
16,625
.85
.92
.36
.94
.47
.00
.00
.00
.00
.60
.81
.32
.48
.53
.51
.16
.32
.11
22
23
391
2,339
489
841
1,060
473
416
367
581
744
931
149
3
35
.40
.19
.13
.08
.93
.00
.00
.00
.00
.64
.41
.38
.60
.56
.96
.11
17
.37
16.73
261
1,548
326
571
686
325
284
244
381
479
613
108
3
62
.23
.36
.54
.00
.00
.00
.00
.96
.40
.94
.38
.97
.94
.05
0.955 J
0.960 J
0.963
0.972
0.977
0.983
0.992
0.998
1.000 12373-PeCDF AN
1.006
1.010
1.024 23478-PeCDF AN
1.028
1.039
1.047 J
1.056
1.071
0.364-1.136
1
2
16
9
3
2,910
20
2.720
7
5,635,
1.
892.
4.
64 .
579.
102.
403.
195.
165.
71.
108.
72.
65.
2,727.
.13
.27
.52
.12
.62
.19
.36
.71
.33
.23
r /
/
.21
.93
.24
.97
.55
20
.56
82
33
65
96
31
23
30
10
5
1,767
12
1,633
4
.04
.78
.86
.63
.34
.76
3
3
1,142
10
1.082
3
.62
.34
.33
.29
.37
.93
0.000
0.961
0.971
0.977
0.992
1.000 13C12-PeCDF 123 IS2
1.010
1.023 13C12-PeCDF 234 SUR2
1.056
p— /^rjn Pn 1 1 r»u/o
542
2,
37,
350.
61.
244.
117.
100.
43.
65.
44.
41.
.76
.53
,00
.32
.50
,74
.37
34
55
72
49
66
.469,
66.
27,
228.
40.
153.
78.
65.
75.
43.
27.
23.
1.32-1.78
DC NL 0:
30:
00
30
1.
1.
32
44
0.
1,904.
44
90
1,124.
92
779.
0.939-1.022
.03
.10
.97
73
70
.32
45
49
16
24
82
62
0.000
0.943
0.949 J
0.958
0.966
0.970
0.976
0.934
0.991
0.995
1.001 12378-PeCDD AN
1.004
1.015
0.869-1.131
98
0.000
1.000 13C12-PeCDD 123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98
2S3
-------
Page No.
01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
HxCDF
374-376
AX
AN
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
30:38
DC SN 31:08
2 Peaks
1
RO 1
.44
.86
1.05-1.43
DC NL 0:00.
31:56
32:04
32:14
32:22
32:31
32:42
32:53
33:00
33:07
33:17
33:30
X 34:14
34:13
34:23
14 Peaks
DC NL 0:00
32:53
32:59
DC SN 33:14
33:30
33:58
DC SN 34:04
DC SN 34:06
34:13
34:32
6 Peaks
RO 2
1
1
1
1
1
1
1
1
1
1
1
RO 0
1
1
0.43
RO 0
0
0
RO 0
0
RO 0
RO 0
RO 0
0
0
.05
.23
.25
.35
.25
.35
.30
.25
.28
.32
.28
,28
.89
,05
.13
-0.59
.69
.51
.51
.28
.52
.36
.36
.35
.51
.45
1.05-1.43
DC NL 0:00
DC SN 32:16
32:25
32:51
33:05
33:14
DC SN 33:25
33:36
33:42
34:00
7 Peaks
RO 0
RO 0
1
1
1
1
RO 0
1
1
1
.63
.40
.20
.21
.22
.18
.97
.20
.17
.22
197.38
3.16
2,102.28
: PeCDD /
15.64
827.01
2,526.81
158.69
294.32
169.30
21.48
2,405.04
1,036.67
203.55
381.82
1,063.71
16.01
51.30
301.00
9,461 .71
6.69
2,212.34
2,404.41
2.99
2,301.46
6.69
1.24
1.92
1,975.42
7.33
8,907.65
Vvc HP /
ruci- uf f
4.06
2.69
215.13
928.63
446.31
48.42
1.28
75.43
134.74
208.77
2,057.43
116
.38
31
.00
1.004
1.021
HxCDF Follows -——
0.
964-1.049
0.000
464
1,403
91
163
97
12
1,338
581
115
214
599
3
26
163
744
309
784
3
665
2
.77
.61
.20
.23
.13
.14
.19
.97
.80
.14
.19
.36
.30
.00
.50
.29
.58
.81
.00
.28
362
1,123
67
131
72
9
1,066
454
87
167
469
10
25
138
1,467
1,595
1,516,
4.
1,310.
5.
.24
.20
.49
.09
.17
.34
.85
.70
.75
.68
.52
.00
.00
.00
0.
.34
.12
.88
.43
;42
05
0.968
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
379-
0.
0.
1.
1.
1.
1.
1.
1.
1.
1 .
972
977
981
986
991
997 123478-HxCDF AN
001 123678-HxCDF AN
004
009
016 234673-HxCDF AN
038
040 123789-HxCDF AN
042
1.121
000
997 13C12-HXCDF 473 SUR3
000 13C12-HXCDF 678 IS4
008
016 13C12-HXCDF 234 ALT2
030
033
034
040 13C12-HXCDF 789 ALT1
047
J
J
PR,
Wv(™T"M"1 TTrtl 1 /^(jo
117,
508.
245.
26.
41.
72.
114.
,33
66
,57
23
16
63
71
97.
0.958-
80
419. "97
200.
22.
34.
62.
94.
74
19
27
11
06
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.015
000
958
962
975
982
987
992
998 123473-HxCDD AN
000 123678-HxCDD AN
009 123789-HxCDD AN
J
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98
294
-------
Page No.
01/15/98
Listing of T980159B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT.
OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
Fl3C12-HxCDD
402-404
402-404
HpCDF
408-410
D
408-410
13C12-HpCDF
^ '.3-420
•
413-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
DC
DC
DC
DC
DC
DC'
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
4
NL
i
1
NH
•
WH
.WH
4
1
NL
I
SN!
3
1
I
NL
WL
SN:
SN
WH
WH
WH1
2
NL
0:00
32:51
33:04
33:12
33:20
33:35
33:41
34:01
34:17
34:23
34:27
Peaks
0:00
36:00
36:17
36:26
36:57
37:37
38:00
38:07
Peaks
0:00
36:00
37:37
37:51
38:13
Peaks
0:00
36:09
36:18
36:36
36:52
37:05
37:26
37:33
37:40
Peaks
0:00
36:18
1
RO
RO
RO
RO
.05-1.43
1
0
0
1
0
.36
.55
.69
.71
.17
1.16
1
.18
1.16
RO
RO
RO
0
RO
RO
RO
0.
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
2:54
0,
4.
.83
.60
2
1
7
1
0
1,710
2,032
2,245
4
3
2
5,996
.88-1.20
5.
1.
1.
1.
0.
1.
0.
0.
37-
1.
0.
0.
0.
0.
53
13
00
06
66
02
94
83
•0.51
02
44
44
31
69
1
3,070
650
697
6
422
2
2
4.340
.95
.52
.66
.86
.67
.49
.61
.55
.50
.70
.33
.31
D / Hp
.59
.18
.69
.12
.20
.23
.52
.75
.22
0.970-1.030
0
0
4.24 6.17 0
0
0
918.99 791.50 0
1,102.35 930.26 1
1,204.51 1,041.04 1
1
1
1
.000
.975
.982
.986
.990
.997 13C12-HXCDD, 478
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
.018
.021
.023
SOR4
IS5
RS2
0.998-1.053
0
.000
1,627.99 1,442.19 1.000 1234673-HpCDF
AN
325.41 325.28 1.008
359.46 337.66 1,
1,
213.66 208.57 1.
1.
1.
,012
,026
,045 1234789-HpCDF
.056
059
AN
0.944-1.111
2.
1,732.
1,444.
10.
3 .
3,188.
uv\/*nt
88-1.20
1.
0.
1.
0.
0.
1.
1.
1.
0.
88-
1.
1.
73
59
05
77
42
04
31
34
50
1.20
35
22
i.
15.
541.
3.
0.
550.
2.
2.
1.
1,091.
2.
4.
.97
75
78
60
40
13
* / lfr\{
/ np\
22
14
07
92
77
40
79
37
28
47
45 .
43
0.
526.98 1,205.77 1.
439.29 1,005.49 1.
3.24 10.40 1.
1.
000
000 13C12-HpCDF 678
045 13C12-HpCDF 789
051
062
IS6
SUR5
0.976-1.006
0.
0.
276.94 264.13 0.
0.
0.
280.83 269.57 1.
1.
1.
1.
0.973-
0.
2.64 2.17 0.
000
975
979
987
994
000 1234678-HpCDD
009
013
015
1.027
000
979
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98
2S5
-------
Page No.
01/15/98
Listing of T980159B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total .Area. .. Area.Peak. 1. . Area. Peak. 2.., ReL-RT Compound. Name.. ID.. Flags.
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
3
ML
WL
ML
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
1
NL
1
37:05
37:22
Peaks
0
35:
35
35:
37:
37:
37:
38:
38:
39:
40:
40:
40:
41:
41:
41:
:00
:34
:47
:57
:05
20
:37
:53
;58
48
:02
:08
15
:10
28
49
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
1.
.76-
1.
1.
1.
9.
2.
3.
0.
1.
1.
0.
4.
3.
0.
0.
1.
1.
05 1.814.39
20 5.59
1.824.41
Above • HpCDD /
1.02
95
63
21
75
75
47
95 '
38
15
33
22
14
70
39
33
57
Peaks
0:
40:
41:
41:
00
57
17
22
0 ,
RO
RO
RO
.76-
0.
0.
0.
1.
1.02
58
34
63
19
Peak
0:
40:
00
56
0.
RO
.76-
1.
0.
1.02
64
91
Peak
1
0
1
1
2
2
1
0
1
0
0
0
1.
1.752
13
1
1,765
0.
537.
1.
2,
587.
0.
2,407.
2,407.
.21
.70
.61
.38
.39
.14
.50
.98
.97
.86
.95
.93
.59
.67
.17
.85
.34
.47
.70
.74
,65
.70
.26
46
.46
928.65
3.05
885.7* r.OOO 13C12-HpCDD 678 IS7
2.54: E_OQ8
Octa-CDD and CDF Follows
826.32
9.61
92 6.. 35'.
6:97'
Q:.9XI2'-:1,,098
0.-..OOO
(£..369
OX ST74
OT.. 37 3 .
a\ sos
a. .950
a. 352
a. 972
CC. 978.
OE..S80
X. S83
ia..ocus ocnjp
11. 0:13
t. 0-2:2
263.77
313..93 E..OOO OCOD
r.. .028:9-
AN
1,144.82
1,262 ..64'
a . .000
t. OOO 13CT2-OCDD
IS3
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
r±ie:T980159 #1-810 Acq -.6 -JAN- 9 a 20:40:49 XI + Voltage 572 70T Noiae:186a
303.9016 r:3 BSO3(256,30,-3.0) PXD(9, 5, 5,0. 051,7472. 0,1.00\,f,T) Xxp:SDB5US
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1001
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Al.
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TRIANGLE LABS Text:TLI#4>
100!
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TRIANGLE LABS Text:TLI#4'
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319.8965 Ti2 BSUB(256, 30, -3.0) PKD( 7,5, 3, 0 .05\, 3260 .0,1. 00\,r,T) EtptXDBSOS
TRIANGLE LABS Text:TLI*44376 129-132 XK7. TIKE - 20*43
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TRIANGLE LASS TaxttHJ #44375 129-132 XKJ. TIKE - 20:43
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331.9368 F:2 BSUB(256, 30, -3.0) PXD(7,S,3,0.05\,l6312.0,1.00\,T,T) Xzp:NDBSUS
TRIANGLE LABS Text:TLIf 44376 129-132 HKT. TIKE - 20:43
1001
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333.9338 T:2 BSU3(2S6,30, -3. 0) PXD(7,5,3,0 .05\,4508.0,1.00\,r,T) Xzp:NDBSUS
TRIANGLE LABS Text :TLI #44376 129-132 INJ. TIKE - 20:43
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TRIANGLE LABS Teit:TLI#44376 129-132 INJ. TIKE - 20:43
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TRIANGLE LASS Text: TLI #44375 125-132 XKT. TIKE - 20:43
1001
80:
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-------
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353.8970 F:2 BSO3(256, 30, -3 . 0) PKD(7,5,3, 0. 051,1216. 0,1. 00\,T, T) Exp:NDBSUS
TSIANSLE LABS Text:TLI*44376 129-132 HKT. TIME - 30:43
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330.9792 T:2 Exp,:NDB5US
TSIANSLE LASS Teit:TLI#44376 129-132 IKT. TIME
37j^S 28:08 28:36 28:52 39.. 0729:21 29:36 30:02
80J ~
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40:
20:
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20:43
31:00
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TSIANSLE LASS Text:TLI#44376 129-132 IJKT. TIME - 20:43
lOOSi
31:00
80:
60:
40:
20:
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28:40
27:34
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29:00
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299
-------
Tila:X980159 tl-aiu Acq:6-JAlf-9a 20:40:49 EH- Voltage SIS 70T Hoia«:362
355.8546 T:2 BSUB(256,30,-3.0) PXD(7,5,3,O.OS\r1448.0,1.00\,T,T) XzptSDBSVS
TBIAHSZE LABS T*xt:TLIt44376
1001
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28:48 29:bb 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 3b':48 31:
Tila:T980159 tl-810 Acq:6-JAlT-9B 20:40:49 XI+ Voltage SIS 70T Soiae:24S
357.8516 T: 2 BSUB(256,30, -3.0) PXD(7, 5,3,0. 05\,980. 0,1. 00\,T,T) Xzp:SDB5US
TRIANGLE LABS Text:TLH44376
1003
80.
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40.
20.
0
A4 . 69X6
A
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1 V 7 V A3XES J
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A4.07E5 I \ A7.84E5 A f\ A4.32E5
\S\ J VyN^v A/V A/\ "A5
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Tile:T980159 »1-810 Ac:12 30*: 34 30:36 '30:48 3l':
Tile:T980159 tl-810 Acq:6-JKH-98 20:40:49 EH- Voltage SIS 70T
330.9792 T:2 ExpiXDBSOS
TRIANGLE LABS Text:TLI»44376
1001
80.
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40.
20.
0.
^M5^5V-J^
129-132 ISJ. TIME • 20:43
29:36 29 t 51 30:02 30:15 30:26 30:38 30:56
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300
-------
Tile:T9aoi59 #1-396 Acq:6-J3UT-98 20:40:49 EI+ Voltage SIS 70T Noises 7142
373.8208 F:3 BSUB(256,30,-3.0) PJO>( 7,5,3, 0.05\,28568. 0,1.00\,F,T) Stp:HDB5US
TRIANGLE LABS Text:TLI#44376 129-132 UKT. TDOC - 20:43
100^ A1.40E7
A1.34E7
80:
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A4.65.
A
32
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A5.99E6
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00
33:00
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File:T980159 #1-396 Acqt6-JMT-98 20:40:49 EI+ Voltage SIS 70T Noiae:3488
375.8178 r\:3 BSUB(256,30,-3.0) fXD(7,5,3, 0,05\,13952.0,1.00\,F,T) EXp:NDB5US
TSIANGLE IAB9 Text:TLH44376 129-132 XK7. TINE - 20:43
A1.12E7
1001
sol
sol
20.
A3.62$
A
33
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383.8639 F
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60:
401
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00 33:00 34:00
19801*59 #1-396 Acq:6-JXN-98 20:40:49 EI+ Voltage SIS 70T Noise: 1520
3 BSUB(256,30,-3.0) PKD(7,5,3,0.051,6080.0,1.00\,F,T) Exp:NDB5US
Text:TLI#44376 129-132 ZJKT. TIKE - 20:43
A8.Q9E6 A7.85E6
UBS
A6.65E6
33JOO I 33:00 34:00
File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T Noiae-,2217
385.8610 Ft3 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05%, 8868.0,1. 00*,F, T) Eip:SDB50
TXXANGLE TABS \Text.:TLIt44376 129-132 XK7. TIME » 30:43
100^ Al 60E7 A1.52E7
1 \
aoj
60:
40:
20:
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A1.31S7
32i00 33:00 34:00
File:T980159 #1-396 Acq:6-JAN-9a 20:40:49 EI+ Voltage SIS 70T
392.9760 F:3 Exp:NDB5US
TSIANGLE LABS .Text:TLI#44376 129-132 INJ. TIME " 20:43
lOOlt I 33:13 33:34 33:35 33:47 ,33j06 33:26 34:09
34:26 34:38
4.5E6
.3.SS6
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.1. 8E6
.8.9KS
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Time
.7_.6E6
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4.6E6
3. OE6
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Time
80:
33}00 33:00 34:00
rile:T980159 #1-396 Aeq:6-JAlf-98 20:40:49 EI+ Voltage SIS 70T
445.7555 F
-------
il-396 Aeq:6-JKS-98 20:40:49 ET+ Voltage 3I& 70T Soia»>1127
\3B9.8156 T:3 3303(356,30,-3.0) PXO(7,5,3, 0.05%,4508.0,1.00\,r,T) XxptXDBSUS
TSIAHGLX LABS Tfxt:TLH44376 129-133 XK7. jj^g . 30-43
100$ AS. 99X8
aoJ
50J
401
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A
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32,34 32:36 32:48 33:00 33tl2 33:24 33:36 33:48 34:00 34:12 34\24
\r±le:T980159 tl-396 Acq: 6-JAlf-9 8 20:40:49 SI+ Voltage SIS 701 Soiat>:1660
391.8127 r:3 BSUB(2S6,30,-3.0) PKD(7,S,3,0.05\,6640.0,1.00\,T,T) Xxp:SDB5VS
XXIAHGZX LABS Ttat:TLH44376 129-132 lyj-. TUB . 20-43
1001 A4.20E6
80.
60.
20:
0.
A9.78E5
A
A2.01E6
A2.22ES
A3.
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32:24 32i36 32'i48 33:00 33:12 33:24 33:36 33':43 34': 00 34': 12 34':24
rile:T980159 il-396 Acq:6-Jjat-98 20:40:49 EI+ Voltage SIX 70T Noiae:852
401.8558 F:3 BSUB(256,30, -3.0) PKD(7,5,3, 0. 05*,3408. 0,1. 00%,T, T) Ezp:SDS5nS
TRIANGLE LASS Text:TLI#44376 129-132 XK7. TIME - 20:43
1002
80J
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A1.10E7
A1.20E7
A9.19E>
32': 24 32': 36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34': 12 34:24
Tile:T9801S9 tl-396 Acq:6-JAN-98 20:40:49 Eli- Voltage SIX 70T Noise: 625
403.8529 F:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0.05%,5500. 0,1.00%,F, T) Exp:«DB5as
TRIANGLE LABS Text:TLIt44376 129-132 IK7. TIME * 20:43
A9.30E6 A1'04"
so:
60.
40.
30.
32:24 33:36 32': 48 33:00 33:12 33:24 33:36 33:48
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392.9760 T:3 ExptXDBSVS
TRIANGLE LABS Taxt:TLIf44376 129-132 IW7. TIME - 20:43
34:00 34': 12 34:24
1001
ao:
60.
40.
20.
0.
33:24 32:35 32:47
33:06
33:2.
33126
1:35
33:55
34:09 34:17
34:26
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Tim
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32:36 3348 33:00
'33:24 ' '33\36 ' '33i4~a~' *"/
-------
Tila:T980159 #1-563 Acq:6-JAlf-9a 20:40:49 EH- Voltage SIS 70T Boia*i21SS
407.7818 f:4 BSUB(2S6, 30, -3. 0) PXS(7,S,3,0 ,05\, 8620.0,1.
TRIANGLE LABS Text:TLIt44376 129-132
1001
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37\48 38:00 38:12 Time
rlle:T980159 tl-563 Acq:6-J7OT-98 20:40:49 SI+ Voltage SIS 70T ttoia»:389
409.7789 T:4 BSUB(256, 30, -3. 0) PXO(7,5, 3, 0. 05%, 1556.0,1 .00\,f,T) Sxp:XDB5US
TRIANGLE LABS Text:TLIt44376 129-132
1003
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417.8253 r:4 BSUB(256, 30, -3. 0) PXD( 7, 5, 3,0 .051,4228.0,1.
TRIANGLE LABS Text :TLI §44376 129-132
1001
80:
60:
40:
20:
o:
A5.27E6
A 1
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ISJ. TIME - 20:43
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A
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37^:48 ' 3S': 00 3a':12 Time
file:T980159 #1-563 Acq:6-JAN-98 20:40:49 EH- Voltage SIS 70T Soiae: 1029
419.8220 F:4 BSUB( 256, 30, -3. 0) PKD( 7,5, 3, 0. 051,4116. 0,1 .
TRIANGLE LABS Teit:TLIi44376 129-132
loot
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20:
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A
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HKT. TIME - 20:43
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rlle:T930159 tl-563 Acq: 6-JAN-98 20:40:49 EH- Voltage SIR 70T
430.9729 r:4 Exp-.XDBSUS
TRIANGLE LABS Text:TLIt44376 129-132
1001
80:
60:
40:
20:
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36.0536:12 36:25 ^l^^t^i^^L-^-^.
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479.7165 r:4 Exp:lO>B5OS
TRIANGLE LABS Text:TLIt44376 129-132
1001
80:
60:
40:
20:
0:
36:10
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A I\ IIU 1 36:21 A IM I l\l\ A I
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303
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441.7438 F:4 BSUB(2S6,30, -3.0) PXD(7,5,3,0.05^,2508.0,1.00\,F,T) Xzp:SDB5US
TSIAHGLE LABS Taxt:TLIf44376 129-1.32 UKT. TIMS - 20i43
1003
901
80J
7ol
SO.
SOI
401
301
201
102
AS.26X6
36:00 37:00 38:00 39:00 40:00
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443.7399 r:4 BSUB(256, 30, -3. 0) P1O3(7,5, 3, 0. 05%, 1276. 0,1 .00\,f,T) KipsSDBSUS
TRIANGLE LASS Text:TLH44376 129-132 OTJ. TIME - 20:43
1003
901
80.
601
SOI
40.
3ol
201
101
01
41:00
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36:00 37:00 38:00 39:00
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430.9729 f:4 ExptHDBSUS
40:00
41: 00
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42:00 Tin,
TRIANGLE LABS
1001
901
801
T&xt:TLH44376 129-132
37:29
36:12
INJ. TIKE - 20:43
39:23. 40:20
47
41:08 41:34
36:00 37:00 38:00 39:00
rlle:T980159 #1-563 Acq:6-JAS-98 20:40:49 EI+ Voltage SIR 70T
513.6775 T:4 Exp:KDB5JJS
40:00
41:00
f.O.OXO
42:00 lime
TRIANGLE LABS
100*
Tejct:TLH44376 129-132
36 05
JW7. TIME - 20:43
36:00
37:00
38:00
39:00
40:00
41:00
-.0.0X0
421 00 Tlat
305
-------
41:24
40:54 41:00 41:06 41:12 41:18
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469.7779 F:4 BSUB(256,30, -3.0) P!CD(7,5,3, 0. 051,452. 0,1. 00\,T,T) ExpsNDBSVS
TRIANGLE LASS Teit:TLI»44376 129-132 INJ. TIME - 20:43
1004 A1.14E7
fU.e:TyauJ.5S #1-56J ACIJ s 6-JAa-9 8 20l40i49 Elf Voltage SIS 70T Hoiae:110
457.7377 Ti4 BSUB(256,30, -3. 0) PXD(7,5,3, 0. 05\,440.0,1. 00\,r,T) SxptUDBSUS
TBIAHSLX LABS Text:TLIt44376 129-132 UU. TIME ' 20:43
100*
BO.
60.
40.
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41:24
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459.7348 F:4 BSU3(256, 30, -3.0) PXD(7,5,3, 0.05%, 754. 0,1.0Q\,T, T) KxpsSDaSUS
TRIANGLE LASS Text:TLI944376 129-132 nu. TIKE - 20:43
IOCS A3.19E6
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471.7750 f:4 BSUS(256,30,-3.0) PKD(7, 5, 3, 0. OS\e280. 0,1. 00\,F, T) Exp:»DB5US
TSIANSLE LASS Text:TLI#44376 129-132 ZK7. TIME - 20:43
1004 A1J6E7
41:30
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Time
2.4E6
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40:54 41:00 41:06 41:12 41:18
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430.9729 T:4 Exp-.SDBSOS
TSIAKSLE LABS Text:TLH44376 129-132 HKJ. TIME -
41:24
41:30
O.OEO
Time
20:43
1001
80.
60.
40.
20.
0.
41:20
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40:54
41:00
41:06
41,12
41:18
41:24
41130
306
-------
On* I 338,3792 Peak top
Height 3.59 flits Span 288 ppa
Systa file nsae
Data filename fi:
Resolution 18888
2
El*
VOLTflGE
loniation tode
Snitching
Ref, lasses 82,3825, 416,3768
A 293 J' 331 6 368
K 332
L 334
fl 348
H 342
0 352
P 354
Q 356
R 358
8 384
C 386
D 316
E 318
f 328
6 322
H 328
T 378
II 376
V 418
331
tef, ias 416,3768 Peak top
Height ,36 volts Span 208 ppa
307
-------
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319.8965 F:2 Exp:NDB5US
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25:42 25:48 25:54 26:00 26:06 26:12 26il8 26:24 26:30
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME
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20:43 File Text:TLI#44376 129»
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25:42 25:48 25:54 26:00 26:06 26:12 26:18 26:24 26:30
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME
1004, 26; 10
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26:30 26:36 26:42 26:48 26:54
Time
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File:T980159 fll-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
339.8597 F:2 Exp:NDB5US
Sample Text:TLIH44376 129-132 INJ. TIME = 20:43 File Text:TLI#44376 129»
28:54 29:00 29:06 29:12 29:18 29:24
File:T980159 ttl-810 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
341.8567 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME = 20
29:30
29:36
LO.OEO
Time
43 File Text:TLI#44376 129»
1.9E6
29:00 29:06 29:12 29:18 29:24
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
351.9000 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME =
lOOi
80 j
60:
40J
20J
29:30
29:36
Time
20
0
43 File Text:TLI#44376 129»
29;29 _5.5E6
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29:18
29:24
29:30
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-------
lle:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
373.8208 F:3 Exp:NDB5US
Sample Text :TLI#44376 129-132 INJ. TIME = 20:43 File Text :TLI #44376 129»
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33:54 34:00 34:06 34:12 34:18 34:24 34:30 34:36 34:42 34:48 34:54
File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME = 20:43 File Text:TLI#44376 129»
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File:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME =
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-------
'ile:T980159 #1-396 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
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20:43 File Text:TLI#44376 129»
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375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME
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Sample Text:TLI#44376 129-132 INJ. TIME
100% 34^18
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34:36
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34:18
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-------
File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME =
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File:T980159 #1-810 Acq:6-JAN-98 20:40:49 EI + Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:TLI#44376 129-132 INJ. TIME =
O.OEO
29:00 Time
20:43 File Text :TLI#44376 129»
_1.9E5
_1.5E5
0
26
27:00
28:00
29
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_3.7E4
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00 Time
-------
TLI Project: 44376
Client Sample: 129-132
Method 23 TGDD/TCDF Analysis (DB-225)
' Analysis File: P980167
Client Project: Culp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97 Spike File:
TLI ID: 194-59-7A-7D Date Extracted: 12/29/97 ICal:
Date Analyzed: 01/10/98 ConCal:
Sample Size: 1,000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a % Moisture
Blank File: X980083 % Lipid:
Analyst: WK % SoUds:
SPC2NF04
PF22206
P980164
: n/a
n/a
n/a
;Arta*Sffc» v - * *
2^,7,8-TCDF
f \
'Internal Standard
13CI2-2,3,7,8-TCDF
Recovery Standard
•?CU-1A3,4-TCDD
AmM&t) >^-^*^;; -\,ii«|H>^ -:^ mte --,
0.83 0.75
Amt (ng) % Recovery OC Limits '-• Ratio ,
3.0 , 74.3 40%-130% 0.78
Ratio
0.81
81V ,
23:04
RT
23:03
«T
21:53
Ftegs
• — '
Flags
—
Flags
Data Reviewer.
01/11/98
Page 1 of 1
C2NFJ>SR rZOI. LARStf.IO.OB
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:35 01/11/98
-------
Initial
Date...
Data Review By:
I /tf X# Calculated Noise Area: 2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
01/11/98
Listing ot P980167B.dbf
Hatched OC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDP
304-306
304-306
13C12-TCDP
316-318
DC
DC
DC
NL 0:
WL 18:
18:
18:
18:
18:
19:
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
21:
21:
21:
21:
21:
22:
22:
22:
22:
23:
23:
23:
23:
23:
24:
24:
25:
WH 25:
0
00
13 RO
:27
39
43 RO
55 RO
05 RO
27
34
42
53
59
09
18
26
35
45
08
24 RO
34
41
49
03
19
28
56
04
16
32
40
53 RO
27
35
12
38 RO
.65-0.39
0.35
0
0
0
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.64
.82
.75
.46
.03
.10
.73
.74
.75
• 75
.84
.73
.34
.74
.76
.70
.74
.38
.74
.74
.73
.74
.77
.74
.74
.75
.73
.75
.75
.92
.73
.65
.69
.49
32 Peaks
DC
DC
DC
DC
DC
NL 0:
WL 19:
WL 20:
WL 20:
WL 20:
0.
00 RO
17 RO
06
41 RO
44
3
10
572
11
12
11
41
587
556
1,086
458
66
499
1,089
561
1,541
532
3,113
4.
659,
131.
652.
652.
133.
790.
610.
457.
695.
815.
649.
2.
439.
11.
83.
3.
17,535.
.93
.48
.17
.34
.85
.35
.47
.52
.15
.41
.67
.82
.99
.96
.87
.69
.91
.05
.90
.89
.46
,64
50
93
,80
31
56
61
82
00
69
64
58
30
72
85
0.793-1.101
0.000
258
4
10
6
25
247
237
463
197
30
211
498
239
665
218
1,323
2
280
55
275
277
58
336
259
196
292.
350
278
1,
185,
4.
33
.25
.87
.59
.62
.75
.72
.12
.88
.25
.50
.15
.39
.28
.57
.95
.90
.13
.51
.93
.74
.25
.15
.87
.30
.23
.53
.24
,94
.40
.13
.56
.98
313
6
7
6
23
339
319
622
261
36
288
591
322
876
313
1,789
5
379
75
376
375
75
453
351
261
403
465
370
1,
254,
7
49,
65-0.89
1
0
0
2
0,
.30
.31
.85
.16
.79
2.
3.
4.
0.
1.
is
20
87
57
45
.92
.47
.26
.41
.43
.80
.03
.53
.42
.32
.84
.07
.59
.12
.96
.15
.64
.38
.53
.90
.25
.78
.93
.01
.33
.08
.58
.06
.52
.51
.02
.32
•
0.790
0.800
0.809
0.812
0.821
0.828
0.344
0.349
0.855
0.363
0.867
0.874
0.381
0.386
0.893
0.900
0.917
0.928
0.936
0.941
0.946
0.957
0.968
0.975
0.995
1.001 2378-TCDF
1.009
1.021
1.027
1.036
1.061
1.067
1.093
1.112
0.957-1.043
0.000
0.837
0.872
0.897
0.399
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1
M/11/98
-------
Page No.
01/11/98
Listing of P9801S7B.db£
Hatched OC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
316-318
DC
DC
DC
DC
DC
DC
DC
DC
ML
WL
WL
WL
WL
'
WH
WH
WH
4
21:17
21:33
21:46
21:51
21:54
22:14
23:03
23:25
23:41
24:07
25:11
25:30
Peaks
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
0.
0.
0.
1.
0.
0.
1.
1.
1.
0.
13.
30
49
68
34
17
62
78
08
02
12
32
46
3
9
8
0
1
3
2,129
7
5
3
18
0
2,145
.17
.19
.19
.92
.13
.29
.71
.20
.17
.22
.56
.46
.37
1.43
932.51
4.39
2.99
2.29
1,197.20
4.07
2.92
0.923
0.935
0.944
0.948
0.950
0.965
1.000
1.016
•1.027
1.046
1.093
13C12-2378-TCDF ISO
1.106
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
DC
NL
1
i
I
SN
WH
WH
WH
14
0:
20:
21:
21:
22:
23:
23:
24:
24:
00
23
36
53
40
16
49
15
26
0.
RO
RO
RO
RO
RO
RO
65-0.39
1
0,
0,
0,
0,
0.
1.
2.
0.
.91
.57
.80
.31
.78
.45
,03
,69
.52
Peaks
Above: TCDP / TCDD Follows
1.33
5.95
1,601.64
2,064.30
19.30
2.69
1.73
1.59
10.99
3,691.69
2.59
711.99
925.16
8.48
0.
4.53
889.65
1,139.64
10.82
907-1.093
0.000
0.948
1.000 13C12-2378-TCDD
1.013 13C12-1234-TCDD
1.049
1.077
1.103
1.123
IS1
RSI
1.131
Column Description. . . .1 'Why Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 |Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report **
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
FlJ.e:P980167 #1-922 Acqi10-JMf-lyHa iJ:JOr«o ij* Voltage SIR /UP nOlsesHOl
303.9016 BSU3(256,30,-3.0) PKD( 5, 3,1, 0.10\, 3608. 0, 0. 00\,t, F) Exp:DB225
TRIANGLE LASS Tejct:129-132 TLH44376
100* Al E7
80.
60.
40.
20.
A4. 64E6
A6.66E6
A4.99E6
A2.81E6
A3.37E6
A3.50E6
A1.BSE6
A
13:00 20:00 21:00 22:00 23:00 24:00
File:P980167 #1-922 AcqilO-JJOT-1998 13:36:48 EH- Voltage 3IS 70P Soise:1064
305.8987 BSUB(256,30,-3.0) PKD( 5, 3,1, 0. JO*, 4256. 0, 0.00\,F,F) Exp:DB225
TRIANGLE LASS Text: 139-132 TLI#44376
1003, A1.79E7
80.
60.
25:00
40.
20.
0.
A4.54E6 A4. 66E6
A3.51E6 ,
A2.55E6
19:00 20:00 21:00 22:00 23:00 24:00
File:P980167 #1-922 Acq:10-JAN-1998 13:36:48 EH- Voltage SIR 70P Noise:792
315.9419 BSUB{256,30,-3.0) PJO3(5, 3,1, 0.10%, 3168. 0, 0 . 00\, F, F) Ejcp:DB225
TRIANGLE LABS Text: 129-132 TLI#44376
A9.33E6
80.
60.
40.
20.
25:00
19:00 20:00 21:00 22:00 23:00 24:00
File:P980167 #1-922 Acq: 10-JAN-1998 13:36:48 EI+ Voltage SIR 70P IToise-.Sll
317.9383 BSUB(256,30,-3.0) PKD(5, 3, 1, 0.10\,2444 . 0, 0 . 00%, F,F) Exp:DB225
TRIANGLE LABS Text: 129-132 TLI#44376
IOCS A1.20E7
80.
60.
40.
20:
0.
25:00
19:00 20:00 21:00 22:00 23:00
File:P980167 #1-922 Acq:10-JAir-1998 13:36:48 EH- Voltage SIR 70P
375.8364 Exp:DB22S
TRIANGLE LABS Text:129-132 TLU44376
.1001
24: 00
25:00
2.7E6
'.2.1E6
.1. 6E6
.1. 1E6
.5.3E5
O.OEO
Time
O.OEO
Time
2.5E6
..2.0E6
1.5E6
1.0E6
5.1E5
O.OEO
Time
19:00
20100
21:00
22:00
2J.-00
24:00
25:00
316
-------
\File:P9BOlS7 #1-922 Acq:10-JAlt-l99a U:3S:4a Et+ Voltage StR 70P ttoiae:531
319.3965 3503(256, 30, -3.0) PKD( 5, 3,1, 0.10\,2124 . 0, 0. 00%, F,F) Exp:DB225
TRIANGLE LABS Text: 129-132 TLI044376
1001
80.
60.
40.
20.
0
|
;
•
A2.66E6
A6.14ES
\\ 11 A AA A .
20; 00 ' .21:00
Al . 09E6
yv/V ^^_
1 . 1E6
'.8.6E5
'.6.SE5
.4.3E5
'.2.2ES
' 0 . OEO
22:00 ' 23': 00 ' ' 24:00 Time
File:P980167 #1-922 Acq -.10 -JAN- 1998 13:36:48 EI+ Voltage SIR 70P Soiae:786
321.8936 BSUB(2S6,30,-3.0) PKD( 5,3,1, 0.10%,
TRIANGLE LABS Text:129-132 TLI#44376
1001
80.
so:
40.
20.
0"
\
A3.39E6
ll
3144.0,0.00*,F,F) Sxp:OB22S
A8.10E5 A1.41E6
\\ A A &4.17ES A
/ I / I A A A A X-W V ^ ^
20:00 21 1-00
i . 4r5
11 . 1E6
.8.5E5
.5.7E5
-2.8E5
' 0 . OEO
22:00 2J:00 24:00 Time
File:P980167 #1-922 Acq: 10 -JAN- 1998 13:36:48 EH- Voltage SIR 70P Noiae:398
327.3847 BSUB(256, 30, -3 . 0 ) PKD(5, 3,1, 0.10%,
TRIANGLE LABS Text .-129-1 J2 TLI#44376
1003
80.
60.
401
20.
0.
Al.
'
Al . 02E6 1
.^^S ^» /
20:00 2lioO
1592. 0,0. 00%,f,f; Eip:DB225
(E7
12.57E6
A A1.30E6
J\ /\
3.4E6
.2.7E6
-2.0E6
.1 . 4E6
'.6.8E5
' 0 . OEO
22:00 ' ' '2J:00' ' ' ' ' 24\ 00 ' ' ' Tiae
File:P980167 #1-922 Acq: 10-JAN-1998 13:36:48 EH- Voltage SIR 70P Noiae:714
331.9368 BSUB(25'6,30,-3.0) PKD(5, 3, 1, 0.10%,
TRIANGLE LABS Text : 129-132 TLI#41376
100J
so:
50.
40.
20J
;
o:
2S56.0,0.00\,F,F) Exp:DB225
A9.25E6
i
A7.12£5
i
j
20 1-00 21:00
'
U V
-2.1E6
.1 . 7E6
-1.3E6
-8.4E5
-4.2E5
0. OPO
221-00 ' ' 2jl-0o' ' ' ' '24:00 Tiae
File:P980167 #1-922 Acq:10-JAN-1998 13:36:48 EH- Voltage SIR 70P Noiae:377
333.9338 BSUB(256, 30, -3.0) PKD(S, 3, 1,0. 10*, 1508.0,0 .00\,F,F) Exp:DB225
TRIANGLE LABS Text:129-132 TLI044376
1001
80.
60.
40.
20:
o:
J11.14Z7
A3.90E6\\
n I \
1
20:00 21:00
\l I
.2.6E6
.2.1E6
.1 . 6E6
.1 . OE6
.5.215
a nrn
^2l-00 23:00 ' 24.-00 rlae
31'
-------
rile:P9a0167 #1-922 Acq:10-JXlf-l998 1J.-JS.-48 EI+ Voltage SIS 70S
303.9016 Exp:DB22S
TRIANGLE LASS Teit:129-132 TLI044376
1001
80.
SO.
40.
20.
0
21: 08
f\
20:35 \
19:42 20:18 11 1
18:27 ":77(1 (1 I «
/I . M/lA/wlA 1 1 /
'l9\00 20 !• 00 ' 21: 00
1.9E6
,. 22:28 33:32
22 * OJ A A
UAJ MAM T ..
Ll . 6E6
^^k
:i.2^
:7.8Z^P
LJ.5JT5
' 0 . OBO
22:00 33': 00 24:00 25 .-00 Time
file:P980167 #1-922 Acq:10-JRlT-1998 13:36:48 EI+ Voltage SIS 70P
315.9419 Exp:DB22S
TRIANGLE LABS Tezt:129-132 TLH44376
1001
80.
SO.
40.
20.
0
.
19': 00 20': 00 211: 00
23:03 2.0E6
1 \
Ll . 6E6
.1.2E6
.8.2E5
-4.1E5
O.OEO
22:00 2J-00 . 24\ 00 25:00 . Tine
File:P980167 #1-922 Acq:10-JAN-1998 13:36:48 EI+ Voltage SIS 70P
319.3965 Eip:DB225
TRIANGLE LABS Text: 129-132 TLH44376
1003
aol
60.
40.
20:
0:
19:16
1
T°
i
20:53
11 A A^A A.21
IS. -00 20:00 21:00
C1.1E6
21 : 54
:38/\
r^fJ V ^ .
.3.6E5
'•.6.5E5
.4.3E5
.2.2E5
O.OEO
22I:00 23(:00 ' 24 1- 00 25:00 Tiae
file:P9a0167 #1-922 Ac?: 10-J7UI-1998 13:36:48 EI + Voltage SIS 70P
331.
TRIA
1003
aol
60:
40:
20:
oj
9368 Exp:DB225
NGLE LABS Text:129-132 TLI#44376
21.
.
1
isl-00 20:00 21 .' 00
21.53
36
V / I ^
_2.1fMl
_1 . 7E6
.1 . 3E6
.3.4E5
.4.2E5
O.OEO
22rOO 23I:00 ' ' ' 24 1-00 251-00 ' Tine
F±le:P9a0167 #1-922 Acq: 10 -JAN- 19 9 8 13:36:48 EH- Voltage SIS 7QP
292.9825 Exp:DB225
TRIANGLE LABS Tezt:129-132 TLI#44376
1001
80:
60:
40:
20:
oj
r\ -i£i.OS 19:35 20:05 20:55
\A w^V*1^ Fv^*i. . -"-^-^<^»**w^v^J%*% w*1/ST^j»A^-l*^/*^^^^/'^.*^A.
vy*^ \A f* \.^Tr>nr' ^M r^Ti YT^< r v^yvN
I
19:00 20:00 21:00
21:55 ^i^J 2J.-1S 23 : 58 24:27 25:14 ..9.1E6
r'**~*f*r*tvJ~~V~°'~r^l('^~*V*ir'l*^r'\fi'**s***^~~f\*r*n^^ '
-7.3E6
.5.4E6
.3.6E6
.1 . 8E6
O.OEO
22:00 23\0(> 24 ': 00 ' ' ' 25: 00 Tiae
File:P9a0167 #1-922 Ac
-------
I
Sfl
*l
5
Kfl
30
1
l
^^^™^^^^^H
^^^^^^^^^^
U
! Mi
M
ll^^^^H
•L
^^^^^^^^^^T
E^ClbZZ
Ref. lass 292.9825 Peak top
Hei# 1,48 wits Sp* 288ppi
Systei file nw 06225
Data file nan R>nOH&
Resolution IfiflfiA
Gnxfnuber 1
lonization lode El*
Suitching VOLTflGE
Ref, lasses 292,9825, 388,9761
ft 292,9825 J 338,9792
8 383.9816 K 331,9368
C 385,8987 L 333,9338
D 315,9419 H 375,8364
E 317,9389
F 319,8965
6 321,8936
H 327,8847
I 338,9792
Channel I 338,9782 Peak top
Height 1,92 volts Span 298 ppa
3V
-------
TLI Project: 44376
Client Sample: 133-136
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T9801^
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-8A-8D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: CRV
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF5D177
T980160
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
U,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ng) DL EMPC
0.02
0.05
0.02
0.04
0.06
0.16
0.27
2.9
0.29
0.40
0.54
0.21
0.23
0.01
0.68
0.11
1.2
Amt {ng} Number Dt EMPC
4.4 10 4.4
0.83 7 1.5
0.72 6 0.74
0.32 2
24.0 16 24.0
7.3 16 7.3
2.3 13 2.3
1.1 4
Ratio
0.84
1.40
1.19
1.21
1.08
1.00
0.76
0.81
1.48
1.43
1.30
1.26
1.30
1.16
1.04
1.07
0.85
HT
26:21
30:30
33:36
33:41
34:00
37:05
40:57
25:41
29:29
30:11
32:53
32:59
33:30
34:18
36:00
37:36
41:10
Flags
;Z
J_
J_
PRJ
B_
PRJ
Flags
—
Q_
Page 1 of 2
X237_PSRv2.01. LARS 6.101
Triangle Laboratories, lnc.«
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98,
320
-------
TLI Project: 44376
Client Sample: 133-136
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980163
13C,2-2,3,7,8-TCDF
l3C,2-2,3,7,8-TCDD
13C,2-U,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
I3C,2-l,2,3,6,7,8-HxCDF
13Cl2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
l3Cirl,2,3,4,6,7,8,9-OCDD
i
17CL-2,3,7,8-TC33D
l3C,:-2,3,4,7,8-PeCDF '
13C,2-l,2,3,4J,8-HxCDF '
13C,:-l,2,3,4,7,8-HxCDD!
l3Ci:-l,2,3,4,7,8,9-HpCDF
I
Pilfifr^^
13C,:-l,2,3,7,8,9-HxCDF
13Cr-2,3,4,6,7,8-HxCDF '
I
|||^ii|i|i^nial^s|^^i^^^
13C,2-1,2,3,4-TCDD ;
13C12-l,2,3,7,8,9-HxCDD
2.9
2.9
3.3
3.6
3.1
3.8
3.4
4.4
9.0
3.4
3.8
3.9
3.8
4.6
|||||l|ftg|lii
3.3
3.0
72.2
73.4
81.6
90.0
77.1
95.5
84.2
110
112
86.1
94.5
97.5
95.8
114
Ililli^iiG^^I
82.1
76.0
llllillllllllillllilil
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%-130%
25%- 130%
25%- 130%
25%- 130%
iP^limilill
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
40%- 130%
40%- 130%
iis^^Swi:JiJ;«™::;ffi«S
iiHliioiil
0.75
0.80
1.41
1.46
0.51
1.20
0.44
1.02
0.90
1.45
0.51
1.23
043
|||l|it|ie>i|||
0.52
0.51
0.79
1.21
25:39
26:20
29:29
30:30
32:59
33:41
35:59
37:04
40:56
26:21
30:09
32:53
33:36
37:36
iiil^iiilliliili^iil
34:17
33:29
26:09
34:01
Data Reviewer
Ql/15/98
Page 2 of 2
X37.PSR vioi. LARS 410.fl»o
Triangle Laboratories, Inc.s
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:28 01/15/98;
321
-------
Data Review By:
Initial ....Date...
lL$Ll£Z Calculated Noise Area:
1.20
The Total Area for each peak with an ion abundance racio ouCside
ratio limits has been recalculated according to method requirements.
Page No.
01/15/98
Listing of T980163B.dbf
Hatched OC Peaks / Ratio
/ Ret. Time
Compound/
MJ QC.Log Omit Why . .RT. OK Ratio Total.Area. .. Area.Peak.1. . Area.Peak.2.
Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-313
TCDD
320-322
M
DC NL 0
22
23
23
23
24
24
24
24
25
25:
25
25
26:
26:
26:
26:
27:
DC WH 27:
0
:00 RO
:39
:08
:22
:52
:02
:24
:39
:53
:05
:15
:30
:41
:05
:17
:32
;58 RO
:20
:34
.65-0.89
1.32
0.31
0.79
0.79
0.81
0.31
0.31
0.79
0.82-
0.81
0.34
0.81
0.31
0.83
0.32
0.81
0.55
0.77
0.77
17 Peaks
DC NL 0:
DC WL 23:
24:
25:
25:
26:
26:
DC WH 27:
0.
00 RO
35
56 RO
15 RO
39
03
15
09 RO
5 Peaks
DC NL 0:
23:
24:
24:
25:
25:
25:
26:
0.
00 RO
54
16
32
12
27
50
14
.65-0.89
0.93
0.35
1.33
1.08
0.75
0.35
0.80
0.95
0.876-1.072
1
1
3
3
2
1
1
4
1
1
3
27
3
,246
,150
861
,070
,016
,987
,837
.053
,812
,042
,063
,315
735
605
153
3
76
19
,035.
.13
.28
.27
.92
.26
.27
.14
.91
.71
.22
.55
.94
.12
.27
.09
.13
.41
.03
.12
.62
557
506
381
1,372
1,348
1,335
813
473
2,157
474
475
1,485
333
272.
68.
3.
33.
.54
.64
.63
.73
.38
.89
.18
.25
.71
.90
.50
.24
.32
.33
,62
.66
.08
688
643
480
1,697
1,667
1.651
1,024
530
2,654
567
588
1 , 829
401
332
34
6
43
.74
.63
.29
.53
.39
.25
.73
.46
.51
.65
.44
.38
.95
.26
.56
.57
.00
0.000
0.383
0.902
0.911
0.930
0.937
0.951
0.961
0.970
0.978
0.984
0.994
1.001 2378-TCDF AN
1.017
1.025
1.034
1.051
1.066
1.075
0.961-1.039
3
3,
2.
9.
5.
17.
,293.
20.
13.
6.
,350.
rnrr\T
65-0.39
0.43
0.78
0.78
0.74
0.83
0.76
0.68
0.76
1,
1,
1.
,749.
,019.
110.
403.
207.
98.
375.
.33
.48
.93
03
11
70
36
33
13
r / TV
/ l%»,
49
47
23
63
00
59
36
00
4.
10.
1,408.
9.
5.
44
41
22
52
92
3.
9.
1,884.
11.
7.
35
62
89
18
44
0.000
0.919
0.972
0.984
1.000 13C12-2378-TCDF ISO
1.016
1.023
1.058
768.
446.
47.
183.
89.
39.
162.
13
67
23
05
63
92
00
981.
572.
63.
219.
117.
58.
213.
0. 901-1. 043
34
56
45
95
96
44
00
0.000
0.908
0.922
0.932
0.957
0.966
0.981
0.996
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
322
-------
Page No.
01/15/98
Listing of T980163B.dbf
Matched GC PeaJcs / Ratio / Ret. Time
Compound/
kM_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
AN
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
M
M
AN
26:
26:
26:
26:
27:
:21 0.34
:30
;40
:51 RO
:19 RO
0.
0.
74
73
1.04
0.99
12 PeaJcs
DC NL 0:
DC WL 23:
DC WL 24:
- 24:
DC SN 24:
24:
^ 25:
25:
, 26:
' 26:
I 26:
27:
:00
:55
:1S
;27
:35
:59
40
49
08
21
43
16
3 Peaks
DC NL 0:
26:
' 26:
1 26:
0.
00 RO
09
20
40 RO
4
2
2,
21.03
39.69
41.65
13.54
11.22
.090.46
0.75
9.51
8.40
6.56
1.30
100.06
9.01
3.10
2.58
,342.42
167.92
2.22
,633.37
9
16
17
7
6
6
100
9
3
.63
.39
.55
.99
.26
.56
.06
.01
.10
11.40
22.80
24.10
7.65
6.34
0.
2.58
2,342.42
167.92
2.22
65-0.39
2.
0.
0.
0.
i3 Peaks
DC NL 0:
27:
' 27:
27:
1 28:
! 28:
28:
28:
28:
I 28:
29:
29:
1 29:
, 29:
29:
29:
DC SN 29:
30:
1 30:
30:
1
1
1.
00 RO
33
44 RO
49 RO
00
11 RO
19
31
40
49
07
- 1
-3
29
39
47
58 RO
11
19
38
32-
1.
1.
1.
2.
. 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
93
79 2,
30 2,
54
5,
1.73
04
43
17
72
41
12
60
61
46 1,
49
48
45
46
43
49
47
22
43
45
41
4.31
,953 . 38
,703.38
28.94
.636.20
Tpnn / Po<
1 \fUU f fS'
1.73
825.05
14.63
10.97
23.14
19.05
17.22
262.93
438.46
312.23
442.00
687.41
295.00
239.70
201.95
315.55
1.02
325.01
380.55
78.31
1, 302.
1.200.
12.
.07
.09
.59
1
1
1
1
1
.001 2378-TCDD
.006
.013
.020
.037
AN
J
J
924-1.076
0
0
0
0
0
0
0
0
0
1
1
1
.000
.908
.922
.928
.934
.949
.975
.980
.992
.001 37C1-TCDD
.015
.035
SUR1
0.924-1.076
1,651.31
1.503.79
23.51
0
0.
1.
1,
.000
.993 13C12-1234-TCOD
.000 13C12-2373-TCDD
.013
RSI
IS1
PT°1F Prtl 1 oii»e
492.
8.
11.
13.
11.
10.
162.
382.
186.
264.
406.
175.
143.
120.
188.
191.
225.
45.
96
39
71
55
53
59
17
70
92
00
55
00
00
99
01
48
40
78
0.928-1.061
332.09
7.57
4.30
9.59
10.32
6.63
100.76
605.76
125.31
178.00
280.36
120.00
96.70
80.96
127.54
133.53
155.15
32.53
0.
0.
0.
0.
0.
0.
0.
p.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
.000
.934
941
,943
950
956
960
967
972
977
988
991
998
000 12378-PeCDF
006
010
016
024 23478-PeCDF
028
039
J
J
J
J
J
AN
AN
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
/15/98
-------
Page No.
01/15/98
Listing of T980163B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-353
356-353
13C12-?eCDD
368-370
363-370
HXCDF
374-376
DC SN 30:51
31:08
19 Peaks
DC NL 0:00
28:38
28:48
29:14
29:29
29:45
DC SN 29:57
30:09
30:40
31:08
8 Peaks
DC NL 0:00
28:45
29:13
29:27
29:35
29:46
30:01
30:13
30:20
30:30
30:38
30:57
DC WH 31:26
11 Peaks
DC NL 0:00
30:30
30:37
2 Peaks
DC NL 0:00
31:57
32:05
32:14
32:22
32:32
32:42
32:53
RO
1
RO
RO
RO
RO
RO
RO
1,
RO
RO
RO
RO
RO
1.
RO
1.
RO
0.37
1.42
.32-1.78
0.91
1.40
0.33
2.13
1.41
1.63
2.13
1.45
1.10
0.91
.32-1.78
1.71
1.06
1.42
1.70
1.73
1.50
1.95
1.47
0.39
1.40
1.28
1.60
2.24
32-1.78
1.26
1.46
1.44
05-1.43
1.51
1.30
1.28
1.37
1.20
1.32
1.19
1.30
1
39
5,978
0
13
4
4
3,084
29
3
2,894
2
6
6,040
1
343
23
211
34
133
46.
55
20.
28.
16.
16.
1.
929.
.04
.30
.96
.71
.48
.28
.77
.30
.06
.54
.33
.30
.98
.50
P 1 P*»
.03
.05
.09
.55
.91
.33
.05 '
.33
.28
.26
.04
.35
79
24
23
7
2
3
1,304
18
.36
.36
.60
.99
.50
.00
1
16.44 1
0.
5.62
3.13
1.87
1,280.30
11.06
.046
.056
J
364-1.136
0
0
0
0
1
1
.000
.971
.977
.992
.000 13C12-PeCDF
.009
123 IS2 '
1.016
1,713
1
4
.30
.70
.24
1,181.03
1.55
4.65
1.023 13C12-PeCDF
234 SUR2
1.040
1.056
f nn Pol i rtu« --
0.
937-1.021
0.000
208
13
133
22
80
35.
.52
.55
.15
. 13
.30
.13
32.92
12.
16.
9.
10.
33
49
75
38
196.41
9.54
78.40
12.78
53.53
18.06
22.41
31.92
11.77
7.62
6.47
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
0.869-
0.
1,338.
215.
2,103.
DeCTir
eG\—LJL
3.
210.
430.
28.
44.
25.
4.
378.
48
03
30
33
\ I llift
i I ruCt
33
98
16
97
91
39
12
42
1,121.
127.
03
14
767.00
88.16
0.
1.
1.
943
953
966
970
976
934
991
995
000 12378-PeCDD
004
015 '
031
1.131
000
000 13C12-PeCDD
004
J
J
J
J
J
AN J
J
J
123 IS3
"*nf U«1 1 rttj*?
119.
241.
16.
24.
14.
2.
213.
39
63
74
43
46
24
34
0.963-
91.59
188.53
12.23
20.43
10.93
1.38
164.58
0.
0.
0.
0.
0.
0.
0.
0.
1.047
000
969
973
977
981
986
991
997 123478-HxCDF
J
J
J
J
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
324
-------
Page No. 4
01/15/98 !
Compound/
M_2 QC.Log Omit Why
Listing of T980163B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OX Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
A
AN
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
14
DC NL
•
DC SN
DC SN
DC SN
• 8
1
DC NL
1
DC SN
DC SN
1
DC SN
DC WH
7
.
DC NL
DC WL
DC SN
6
32:59
33:06
33:17
33:30
34:17 RO
34:18
34:23
Peaks
0.
0:00 RO
31:56 RO
32:53
32:59
33:15 RO
33:29
33:46 RO
33:52 RO
33:59 RO
34:01 RO
34:17
34:41 RO
Peaks
1.
0:00 RO
32:25
32:39 RO
32:51
33:05
33:15 RO
33:30 RO
33:36
33:41
34:00
34:09 RO
34:27 RO
Peaks
1.
0:00 RO
32:21 RO
33:04
33:36
33:41
34:01
34:18 RO
34:24 RO
34:30
Peaks
1.26
1.30
1.32
1.
0,
.30
.95
1.16
1.35
165.86
31.19
50.11
144.37
4.66
8.47
36.00
1,564.11
92
17
28
81
2
4
20
.61
.62
.54
.90
.58
.55
.70
.43-0.59
5.51
0.32
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
51
51
42
51
31
18
34
90
52
02
05-1.43
0.
1.
2.
1.
1.
1.
2.
1.
1.
1.
0.
0.
05-
2.
2.
1.
1.
1.
1.
1.
2.
1.
31
21
70
23
29
03
52
19
21
08
45
39
1.43
57
03
19
23
20
21
98
87
32
0.56
4.51
2,169.59
2,414.95
6.31
2,269.44
6.22
1.57
1.65
2.37
1,941.22
2.34
8,315.08
: HxC DF /
1.50
36.23
0.60
192.19
74.73
8.44
1.03
10.45
21.91
31.68
0.52
0.35
375.63
2
732
812
2
764
3
.46
.63
.59
.30
.06
.32
73.25
13.57
21.57
62.97
2.73
3.92
15.30
0.
2.99
1,436.91
1,602.36
5.43
1,505.38
4.12
1
1
1
1
1
1
1
.000 123678-HxCDF AN
.004
.009
.016 234678-HxCDF AN
.039
.040 123789-HxCDF AN
.042
J
QJ
J
PRJ
J
879-1.121
0
.000
0.963
0.997 13C12-HXCDF 478 SOR3
1.000 13C12-HXCDF 678 IS4
1.008
1.
1.
,015 13C12-HXCDF 234 ALT2
024
1:027
1.030
660
1
.96
.53
1,280.26
1.55
1.
1.
1.
031
039 13C12-HXCDF 789 ALT1
052
HxCDD '•'ollows -
19.
106.
42.
4.
5.
11.
16.
,32
13
09
67
63
99
47
0.953-1.014
16.41
86.06
32.54
4.52
4.77
9.92
15.21
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
0.970-
1.61
1.66
7.38
1,644.40
2,113.04
2,216.98
5.44
2.78
5.75
5.992.99
4.
905.
1,151.
1.215.
4.
3.
01
94
58
11
81
27
•
3.37
738.46
961.46
1,001.87
2.43
2.48
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
962
969
975
982
987
995
998 123473-HxCDD AN
000 123673-HxCDD AN
009 123789-HxCDD AN
014
023
1.030
000
960 .
982
998 13C12-HXCDD 478 SUR4
000 13C12-HXCDD 678 ISS
010 13012-HXCDD 789 RS2
018
021
024
J
J
J
J
PRJ
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
-------
Page No.
01/15/98
Listing of T980163B.dbf
Matched OC Peaks / Ratio / Ret. Time
Compound/ -
M_2.... QC.Log Omic Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HpCDF
408-410
408-410
13C12-HpCDF
418-420
413-420
HpCDD
424-426
D
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
" DC
DC
NL
SN
SN
SN
WH
4
NL
SN
4
NL
NH
SN
WH
WH
2
NL
SN
2
NL
WL
WL
WL
WL
WL
SN
0:00
36:00
36:17
36:25
36:38
36:50
37:11
37:36
37:59
Peaks
0:00
35:59
36:21
36:43
37:36
37:52
Peaks
0:00
36:09
36:18
36:52
37:05
37:13
37:36
Peaks
0:00
36:17-
37:04
37:25
Peaks
0:00
35:34
35:39
35:44
35:59
36:09
37:02
0
RO
.38-1.20
1.
1.
37
04
1 . 11
RO
RO
RO
RO
0
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
0.
RO
RO
RO
RO
RO
RO
I.
2.
0.
2.
1.
6.
06
41
51
00
07
62
0
416
32
88
1
1
0
51
0
638
.88
.10
.19
.36
.73
.06
.31
.54
.59
.19
.37-0.51
0.
0.
0.
0.
0.
0.
85
44
73
44
43
38
1
1,663
6
2
1,479
12
3,161
.80
.83
.09
.75
.40
.16
.48
C / Uv
.38-1.20
0.
0.
0.
0.
1.
1.
1.
88-
1.
2.
1.
1.
76-
1.
2.
2.
3.
1.
0.
1.
73
47
98
74
00
50
66
1.20
13
76
02
32
1.02
73
00
34
26
83
77
35
0
12
72
0
70
0
1
143
.22
.13
.50
.96
.34
.73
.57
.34
0.996-1.051
0
212.59 203.51 1
43.31 38.38 1
45.50 42.86 1
.000
.000 1234678-HpCDF
.008
.012
AN
1.018
1.
.024
1.033
26.70 24.84 1,
.045 1234739-HpCDF
AN
1.056
0.944-1.111
0,
509.08 1,154.75 1.
3.07 4.23 1.
1.
447.39 1,031.51 1.
3.37 8.79 1.
.000
.000 13C12-HpCDF 678
.010
020
045 13C12-HpCDF 789
052
IS6
SUR5
0.975-1.005
0.
0.
35.93 36.57 0.
0.
35.34 35.50 1.
1.
1.
000
975
979
995
000 1234673-HpCDD
006
014
AN
0.973-1.027
2
1
1,753
6
1,760
HoCOI
0.
0.
0.
0.
0.
1.
1.
.40
.29
.92
.43
.35
-\ / f>—
J 1 VJC
.28
.25
.55
.36
.57
.01
.36
0.
0.
883.93 869.94 1.
5.73 3.15 1.
0.902-
0.
0.
0.
0.
0.
0.
0.
000
979
000 13C12-HpCDD 678
009
1.098
000
869
371
373
379
383
905
137
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed 30E29 01715/98
o — ^
-------
Page No. 6 Listing of T980163B.dbf
01/15/98 Matched GC Peaks / Ratio / Ret. Time
Compound/ '
•'.2.... QC.Log Omit Why . .RT. OK Ratio Total.Area. .. Area. Peak. 1. . Area. Peak. 2. . Rel. RT Compound. Name.. ID.. Flags.
0.910
0.918
0.920
0.925
0.931
0.933
0.936
0.941
0.945
0.951
0.957
0.975
0.985
0.988
0.990
243.50 285.60 1.006 OCDF AN
1.013
1.017
442-444
OCDD ' 0.76-1.02 0.902-1.098
453-460 DC NL ' 0:00 0.36 0.26 0.000
40:57 0.76 89.95 38.96 . 50.99 1.000 OCDD AN
DC SN ' 41:10 1.01 2.53 1.006
458-460 1 Peak 89.95
I
13C12-OCDD , 0.76-1.02 0.997-1.005
470-472 DC ML, 0:00 RO 1.08 0.2S 0.000
. 40:56 0.90 2,434.57 1,154.15 1,280.42 1.000 13C12-OCDD IS3
1 Peak 2,434.57
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
m\
SN
SN
SN'
SN
SN
SN
SN
SN,
SN
SN
SN
SN
SN ;
SN
SN
1
37:
37:
37;
37;
38:
38;
38:
38:
38:
38:
39:
39:
40:
40:
40:
41:
41:
41:
;15
:34
:39
;51
;07
ill
20
:31
,40
56
10
54
:18
26
32
10
29
38
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
1.
1.
0.
0.
2.
0.
4.
0.
0.
1.
1.
0.
1.
1.
0.
3.
0.
71
04
50
37
58
40
64
25
52
75
45
06
30
71
81
85
65
97
Peak
0,
1.
0
0.
0,
0.
0.
0.
1.
1.
1 t
0.
0.
0.
0.
529.
1.
1.
529.
.96
.04
.42
.93
.76
.19
.59
,45
.04
,57
,10
66
,49
45
40
10
33
50
10
Column Description •Why" Code Description QC Log Desc.
M_2 -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
File:T980163 ttl-810 Acq:7-JAN-98 00:18:58 EI+ Voltage SIR 70T
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TRIANGLE LASS Text:TLIt44376 133-136 1X7. TIME - 00:21
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-------
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TRIANGLE LASS Text:TLH44376 133-136 INJ. TIME - 00:21
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-------
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TRIANGLE LABS Teit:TLIt44376 133-136 HKT. TIME " 00:21
1001 A3.1,
80.
60.
40.
20.
OE6
36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18 37:24 37:30
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437.8140 T:4 BSUB(256, 30,-3. 0) PKD(7, 5,3, 0. OS\,2192.0,1. 00\,T, T) EzpiHDBSUS
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40.
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36:28
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336
-------
fiJ.a:T980163 tl-563 Acq:7-J3Uf-93 00/13:58 EI+ Voltage SIR 70T 9oif»:lJl
441.7428 T:4 BSUB(256, 30, -3 . 0 ) PKD( 7,5, 3, 0.05\,524.0, 1. 00\,T,T) XxpiBDBSUS
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443.7399 T:4 3SUS(2S6, 30, -3. 0) PXD( 7,5, 3, 0. 05%, 300.0, 1.00\,f,T) Xxp:llDBSBS
TSIANSZE LASS Text:TLI#44376 133-136 US7. TIHE - 00:21
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TRIANGLE LABS Taxt:TLIt44376 133-136 XK7. TIME -
1001 AS.10X5
41:18
40': 4 8 40:54 41:00 41:06 41:12 41:18
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TRIANGLE LASS TaJCt:TLIf44376 133-136 JKJ. TIME - 00:21
1001 A1.J3E7
80.
60.
40.
20.
41:18
40:48 40:54 41:00 41:06 41:12
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471.7750 T:4 BSUB(256,30, -3. 0) PKD(7,S,3, 0. 05\,256.0,1. 00\,T, T) Erp:«I>B5US
TRIANGLE LABS Text:TLI#44376 133-136 IJKT. TIME - 00:21
1001 A1.JSE7
40': 48 40:54 41:00 41:06 41:12 41:18
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TRIANGLE LABS Text:TLIt44376 133-136 IJKT. TIME - 00:21
1001 40:53 41:02 41:07
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50.
40.
20.
0.
41:24
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40:48
40:54
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.3.1X6
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.1.0X6
41:06
41:12
41:18
41124
0.0X0
Time
338
-------
Ref, 1555 222,3825 Peak top
Height 3.12 volts Span 290 ppi
Systsi file naae
Data file nase
Resolution 10000
uroup nuflber 2
lonuatlon node El*
Pitching WLTRGE
Ref. lasses 292,385, 416.3760
fl 293 J 331 S 368
B 304 K 332
C 306 I 334
0 316 H 340
E 318 N 342
F 329 0 352
G 322 P 354
H 328 Q 356
I 331 R 358
Channel I 38,3792. Peak top
Height 2.34 volts Span 290 pea
T 370
U 376
V 410
338
-------
File:T980163 #1-810 Acq:7-JAN-98 00:18:58 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:TLI#44376 133-136
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-------
TLI Project: 44376
Client Sample: 133-136
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P980168
Client Project: Gulp Aluminum Alloys
Sample Matrix: M23TRAIN Date Received: 12/17/97 Spike File:
TLI ID: 194-59-8A-8D Date Extracted: 12/29/97 ICal:
; Date Analyzed: 01/10/98 ConCal:
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a % Moisture
Blank File: X980083 % Lipid:
Analyst: WK % Solids:
SPC2NF04
PF22206
P980164
: n/a
n/a
n/a
2,3,7,8-TCDF
13Cl2-2,3,7,8-TCDF
i3C12-l,2,3,4-TCDD !
0.57 0.75
:W™::WwSS:S!te^
3.0 73.9 40%-130% 0.77
0.82
23:06
23:05 _
21:55
01/11/98
Page 1 of 1
C2NP_PSR rlOl. LARS 6.10.08
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:36 01/11/98
343
-------
Initial
Data..
Data Raviaw By:
Calculated Noise Area:
3.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page Mo.
01/11/98
Listing of P980168B.dbf
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Nama.. ID.. Flags.
TCDF 0
304-306 DC NL 0:00 RO
18:18
18:
32
18:41 RO
18:
18:
19:
19:
19:
19:
19:
19:
20:
20:
20:
20:
20:
21:
21:
21:
21:
22:
22:
22:
22:
47
58 RO
03 RO
10
30
38
46
57
17
23 RO
30
39
47
11
36
43
52
06
19
30
57
23:06
23:
23:
23:
24:
25:
18
34
42
30
14 RO
.65-0.89
1.43
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
68
81
15
84
64
28
87
72
76
74
89
73
92
76
72
70
74
74
69
75
74
77
76
75
75
75
75
74
74
59
304-306 30 Peaks
13C12-TCDP
316-318 DC NL 0:
DC HL 20:
DC WL 21:
23:
23:
DC WH 25:
0.
00 RO
33 RO
48 RO
05
42 RO
13 RO
3
17
906
4
25
27
23
90
780
746
1,434
653
568
1,323
717
1,877
601
3,681
653
149
617
667
150
734
532
319
574
639
465
278
37
19,301
.52
.37
.70
.02
.17
.42
.06
.30
.15
.92
.57
.21
.40
.27
.28
.11
.52
.67
.13
.07
.50
.11
.40
.60
.68
.30
.35
.19
.71
.05
.28
.51
0.793-1.101
0.000
7
405
1
11
11
16
42
326
321
608
307
238
689
309
785
247
1,561
279
. 60
264
283
65
317
227
137
245
273
198
113.
16.
.00
.08
.75
.51
.93
.72
.10
.71
.40
.65
.66
.96
.97
.80
.05
.87
.86
.63
.74
.52
.48
.63
.60
.80
.11
.76
.04
.01
.10
.22
10
501
11
13
18
13
48
453
425
825
345
329
747
407
1,092
353
2,119
378
88
352
383
84
417
304
182
328
366
267
159
27
65-0.89
1.
0.
1.
0.
1.
0.
02
64
01
77
07
52
316-318 2 Peaks
3
9
9
2.163
7
11.
2,171
.12
.06
.95
.99
.45
.88
.44
939.
4.
96
49
1.224.
.37
.62
.56
.66
.62
.03
.20
.44
.52
.92
.55
.44
.61
.48
.06
.65
.31
.45
.33
.98
.63
.77
.00
.38
.19
.59
.15
.70
.95
.59
0.793
0.803
0.809
0.
.314
0.822
0.825
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
0.957-
.03
4.21
0.
0.
0.
1.
1.
1.
830
845
351
356
364
879
383
388
895
900
918
936
941
947
957
967
975
994
001 2378-TCDP AN
009
021
027
061
093
1.043
000
890
944
000 13C12-2378-TCDF ISO
027
092
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:22 01/11/98
344
-------
Page No.
01/11/98
Listing of P980168B.dbf
Matched oc Peaks / Ratio / Ret. Time
Compound/
k'_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
ML
WH
WH
WH
4
0:
20:
21:
21:
22:
24:
24:
24:
00
33
38
55
41
14
27
32
0.
RO
RO
RO
RO
RO
65-0.89
1.
0.
0.
0.
0.
0.
0.
1.
75
54
80
82
76
47
55
11
Peaks
Above: TCDF / TCDD Follows
1.43
6.02
1,825.45
2,109.71
21.32
5.10
3.68
10.07
3,962.50
0.907-1.093
0.000
2.62
810.63
950.17
9.21
4.86
1,014.82
1.159.54
12.11
0
1
1
1
1
1
1
950
000 13C12-2378-TCDD IS1
013 13C12-1234-TCDD RSI
049
120
130
1.134
Column Description. . . 'Why' Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
fila:PSS0168#1-922 Acqt lO-JJuf-1998 14:26s52 SI+ Voltage SIS 70P OOl.ae:142J
303.9016 BSUB(256,30,-3.0) PKD(S,3,1, 0.10\,S692.0, 0.00\,T,T) Ezp:DB225
TRIANGLE LABS Text:133-136 TLI»44376
1003,
30.
S0-
"
A6.90E6 A1.S6E7
"S
"•""
A3.73E6
AA A AA
/VAVV
A
19:00 20:00 21:00 22:00 23:00 24:00
Wle:J>S80158 #1-522 AcqilO-JJUr-1998 14:26:52 XI* Voltage SIS 70P 8oiae:994
305.8987 BSUB(256,30,-3.0) PKD( 5,3,1, 0.10\, 3976.0, 0. QQ\,T,T) Exp:BB225
TSIANGLE LABS Text:133-136 TLII44376
1004 A2.J.2E7
25 .-00
80-
<°-
"
A7.4BE6
A8.26E6
A3 . 66E6
A1.60E6
A
19:00 20:00 21:00 22:00 23:00 24:00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52 EI+ Voltage SIR 70P Noiae:896
315.9419 BSUB(256,30,-3.0) PKD(5, 3,1,0.10\, 3584 .0, 0 .00*, F,F) Exp:DB22S
TRIANGLE LABS Text:133-136 TLI#44376
1004 A9.40E6
80.
60.
40.
20.
4-
15:00 20:00 21:00 22:00 2J.-00 24:00
Tile .-PS 8 0158 #1-922 Acq:10-JAN-1998 14:26:52 EI+ Voltage SIR 70P Noise:878
317.9389 BSU3(256,30,-3.0) PKD(5, 3, 1, 0.10%, J512. 0, 0 . 00%, F,F) Exp:DB225
TRIANGLE LABS Text: 133-136 TLI#44376
1002
80.
60.
40.
20.
12E7
19:00 20:00 21:00 22:00 23:00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52 EI+ Voltage SIR 70P
375.8364 Exp:DB225
TSIANGLE LABS Text:133-136 TLI#44376
1004 18.-J1
24:00
15.-00
o.o
l ro
22-00
23:00
24:00
25 -GO
25 1 0/}
25: 00
25:00
-2.4E6
Tloe
3. 3E6
'.2.6E6
.2.0E6
.1.3E6
'.6.6E5
O.OEO
Tine
.2.0E6
.1. 6E6
.1.2E6
'.4.1E5
«
Time
2.8E6
2.2E6
1.7E6
1.1E6
S.5E5
O.OEO
Time
346
-------
Pile:P9B01S8 «U-'il
2 S1+ voltage sXs 70P lioiae:601 :
319.8965 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10\,2404 . 0, 0. 00\,f,F ) Exp:DB225
TRIANGLE LABS Text:133-136 TLH44376
1003
80.
60.
40.
20.
A4 . 66E6 ,
n
"
2
30E6
A5.56E5 ,, .,,-
f\ n A3.15E5
I A A A A, '•
0:00 21:00
A9.71ES
1.3E6
.LIES
.a.OES
'.5.4E5
12. 7ES
' 0 . OEO
22:00 23': 00 24:00 Time
Fil0:P980168 #1^-922 Acq: 10-JAN-1998 14:26:52 EI+ Voltage SIR 70P Noiae:774
321.8936 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10%, 3096 . 0, 0.00\,r,F) Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
1003
80.
60.
40.
20.
0
A6.04E6
ft
;
A4.26E6
\
•
,
11 f
A8.16E5
A A A4.05E5
V A y\/v /\ __
'20:00 21:00
A1.28E6
x-WV.
-1 . 7E6
.1.4E6
'.1 . OE6
.7.0E5
.3.5E5
' 0 . OEO
221-00 2J.-00 241-00 Time
File:P980168 #1-922 Acq: 10-JAN-1998 14:26:52 EH- Voltage SIS 70P Noiae:469
327.8847 BSUS(2S6
, 30, -3.0) PKD(5,3,1,0.10\,1376.0,0.00\,F,F) Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
100$
80.
60.
40.
20.
0
I
1
Al.
~ - ^/
'20:00 21 1-00
(E7
A1.48E6
A
r3.9E6
.3.1E6
.2.3E6
.1 . 5E6
'.7.7E5
O.OEO
221-00 2-jl-OO 241-00 ' Time
File:P980168 #1-922 Acq: 10-JXW-1S98 14:26:52 EH- Voltage SIR 70P Noiae:712
331.9368 BSUB(256,30,-3.0) PKD( 5 , 3, 1, 0 . 101, 2848 . 0, 0 . OOT>, F,PJ Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
lOOJi
•
80.
60.
40.
20J
0.
!
AS.
j
.'20!- 00 ' 21 1-00
A9.50E6 2.1E6
HE6n
\
•
\l {
_1 . 7E6
.1 . 3E6
.8. fi£T5
_4.Jr5
O.OEO
22:00' ' '2J.-00' ' ' ' '24 .-OO' ' ' ' ' Time
File:P980168 #1-922 Acq: lO-JAlf-1998 14:26:52 EI+ Voltage SIR 70P Noiae:404
333.9338 BSUB(256
,30, -3.0) PKD(5,3,1,0.10\,1616.0,0.00\,F,F) Exp:DB225
TRIANGLE LABS Text:133-136 TLIM4376
1001
80.
so:
40.
20:
01
I
1
;
i
A1.16E7 ^2.6E6
Al . 01E7 (1
-
J
20:00 21:00
I/ I
.2.1E6
.1 . 6E6
.1.1E6
.5.3E5
o .oro
22:00 ' '23'i 00 ' ' ' 24:00 ' ' ' Time
347
-------
Tile:P98016B #1-922 Acq:10-JMT-199a 14:26:52
EI+ Voltage SIR 70P
303.9016 Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
1004
80.
50.
40.
20.
o
18:32
A .
' ' ' 19:00
20.-2J 2J.-11
ft
1
15:45 1
A4 Jl 11
20 • 00 21 1- 00
rile:P980168 #1-922 Acq:10-JAN-1998 14:26:52
21:36 22-.0633*30
AJIAJ ^
^2.4E6
\A"M WAJ°
.2.015
Ll.5£6fl
.5.8£5 |
-4.5Z5
O.OEO
22:00 2J.-00 24:00 25-00 . Time
EI+ Voltage SIR 7 OP
315.9419 Exp:DB225
TRIANGLE LABS Text: 133-136 TLIM4376
1001
80:
50.
40.
20J
o-
15:00
20 1-00 21:00
rile:P980168 #1-922 Acq:10-JAN-1998 14:26:52
"l
1
22:00 2J:(
EI+ Voltage SIS 7 OP
319.8965 Exp:DB225
TRIANGLE LABS Text:133-136 TLH44376
1001 19
aol
so:
40:
20:
o:
J
15 1-00
1?0
15-55
|
.
05 2.0S5
I
.1 . 6E6
.1.2E6
.8.2ES
-4.1E5
O.OEO
10 14 \ 00 ISlOO Tia«
^1 • 3E6
20:33 21.17 21:55
11 /\ f\ •* * ^ ' f\
j \ yvwA ^ >-^«/\^
20:00 21:00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52
'•.1.1E6
.8.1E5
'•.5.4E5
.2 . 7E5
O.OEO
22 .-00 2jl-00 241-00 25 1-00 Time
EI+ Voltage SIR 70P
331.9368 Exp:DB225
TRIANGLE LABS Text -.133 -136 TLI#44376
1003 .
ao:
SO:
40:
20:
o:
151-00
20 .-00 ' 21-00
File:P980168 #1-922 Acq:10-JAN-1998 14:26:52
21.55
21 .- 38
1 \ 1 I T '•'
-2.1E6
.1 . 7E6
-1.3E6
-8.6E5
.4.3E5
O.OEO
22\00 2J.-00 241-00 251-00 ' Tine
EI+ Voltage SIR 70P ,
292.9825 Exp:DB225 ,
TRIANGLE LABS Text:133-136 TLI#44376 \
1001
SO:
so:
40:
20J
0:
18:43 19.1
AT^^l
* \i
15. -00
1 19:37 20:03 j\18 20:45
,TVVVVVV*V\/ r^nr--v^Y^
f V '
20:00 '21:00
rile:P980168 #1-922 Acq:10-JAN-1998 14:26:52
21:45 ^.-25 23:12 23:52^1^ 3^3^\
•V*^V^r*^>*T^^V^^^Vl /
1
**r~Y^ - "V"^ V
-8.2E6
-6.6E6
-4.9E6
-3.3E6
.1 . 6E6
O.OEO
22:00 ' ' ' 2jl-00 ' ' 24:00 25:00 ' ' ' Time
EH- Voltage SIR 70P
330.9792 Exp:DB225
TRIANGLE LABS Text:133-136 TLI#44376
1001
80:
50:
40:
20:
o:
18:40 ig • 05
AT""!
V V
15:00
J5.j7 20:4121:05
f>^vvvvrw\ r-v>Avv^Vr"v
» yi
20:00 21:00
21:45 22:33 23
r^S-v*. '^vOVV^ j*^**-*SV**^wv * /•
^^r — f — ^.1 ' ^^M /
u
.-05 24:15 -_^£i22[
•^VVV^^^V-Y^^-^^^A^^^
-1.1E7
.8.6E6
.6.5E6
.4.3E6
.2.2E6
O.OEO
22.-00 2jiflO ' ' ' 24:00 ' ' 25:00 Time
348
-------
58-
ChameL I
Height 2.8
336,9792
volts Span
Peak top
288 ppi
Systei file naie
Oka file naie
Resolution
Group niaber
lonlzatlon lode
Switching
Ref, lasses 292,9825,
292,9825
383,9816
315,9419
317,9389
319.8965
321,8936
327,8847
338.9792
J
K
L
H
1
El*
VOLTflGE
388,9761
338,9792
331,9388
333,9338
375,8364
Ref, iass 388,9761 Peak top
Height 1,32 volts Span 298 ppt
313
-------
TLI Project: 44376
Client Sample: 137-140 \
Method 23 PCDD/PCDF Analysis (a)
Analysis File:
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Gulp Aluminum Alloys
M23TRAIN Date Received: 12/17/97
194-59-9A-9D Date Extracted: 12/29/97
Date Analyzed: 01/07/98
1.000 Dilution Factor: n/a
n/a Blank File: T980152
DB-5 Analyst: CRV
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
"
SPX23704
TF5D177
T980160
n/a
n/a
n/a
AnaJytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals-
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Ami. (ng) Dt EMPC
0.04
0.06
0.02
0.05
0.06
0.12
0.16
4.2
0.38
0.51
0.56
0.21
0.22
0.01
0.41
EMPC 0.05
0.24
AmL (ng) Number DL EMPC
7.4 12
1.1 7 1.9
0.86 7
0.26 2
34.0 14 34.2
9.9 14 10.1
2.4 12 2.5
0.60 3 0.66
Ratio
0.75
1.44
1.23
1.31
1.26
0.92
0.76
0.81
1.50
1.45
1.27
1.37
1.30
1.22
1.08
0.84
«T
26:21
30:31
33:36
33:41
33:59
37:05
40:56
25:41
29:30
30:10
32:52
32:59
33:30
34:18
35:59
41:08
Flags
J_
J_
J_
PRJ
JB_
PRJ
J_
Flags
—
Q_
Page 1 of 2
X37.PSR v2.01. LARS 6.10
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
35C
-------
w&pw^s&msm.
TLl Project: 44376
fctient Sample: 137-140
i
13C,2-2,3,7,8-TCDF I
13C,2-Z3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF '
13Cu-l,2,3,7,8-PeCDD f
13C,2-l,2,3,6,7,8-HxCDF
l3C,2-l,2,3,6,7,8-HxCDD '.
'3Cr-l,2,3,4,6,7,8-HpCDF
'3Ci2- 1,2,3,4,6,7,8-HpCDD
13Ci2-l,2,3.4,6,7,8,9-OCDD
i
"CU^JJ.S-TCDD ;
13C,2-2,3,4,7,8-PeCDF i
13Ci2-l,2,3,4,7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD !
13Cr-1.2.3,4,7,8,9-HpCDF
1
13Cr-l,2,3,7,8,9-HxCDF
I3Ci2-2,3,4,6,7,8-HxCDF
13C,2-1,2.3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
2.6
2.6
3.0
3.6
.2.9-
3.6
3.3
4.4
8.6
|||||||||g|||
3.4
3.9
4.0
4.0
4.3
3.2
2.9
Illilllllllllll
&!mmm®m
••
PS
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T980164
64.1
64.3
75.6
90.9
71.9
90.2
83.4
109
108
84.8
97.4
100
101
108
:illlll|iR^b^iiyi
:::::::::::;:-:::::::^::::::::;::>:;::y-:-:::::-;-;::-:->:-::-;::x-:-:-:-:^::':o:
80.0
71.7
ji^li^lliis^HliSJKsiiiji^
40%-130%
40%- 130%
40%-130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%-130%
illliiiliii
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
liiiiiiiitsi
40%- 130%
40%- 130%
0.73
0.80
1.39
1.46
0.51
1.22
0.43
1.02
0.88
1.43
0.52
1.21
0.44
0.51
0.53
0.81
1.20
:$:3:-:;:;:SiEiiT;-;S
iSiSgigSljEgi;
25:38
26:20
29:29
30:29
32:58
33:40
35:59
37:04
40:55
llliil
26:21
30:09
32:52
33:35
37:36
•34:17
33:29
llliil
26:09
34:00
—
liljliiii
||||lifigs|||
—
—
Data Reviewer
01/15/98
Page 2 of 2
X2J7.PSR v2.0l. LARS «.IO.Ogo
Triangle Laboratories, Inc.*
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
351
-------
Daca Review By:
Initial ....Dace...
/L$L/fJ/ Calculated Noise Area:
2.00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
01/15/98
Compound/
M_Z.... QC.Log Omit Why
Listing of T980164B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.l. . Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
M
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
DC NL 0
22
23
23
23
24:
24:
24:
25:
25:
25:
25:
26:
26:
•26:
26:
27:
DC WH 27 :
0
:00 RO
:38
:08
:21
:51
:02
24
;39
:04
:15
;30
41
:05
: 17
32 RO
:59 RO
20
33 RO
.65-0.89
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
• 0.
0.
1 .
16 Peaks
DC NL 0:
DC WL 23:
DC WL 24:
DC WL 24:
25:
25:
25:
26:
26:
DC WH 27:
0.
00
31
04
14 RO
06
14
38
03 RO
16 RO
34 RO
65-
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
5 Peaks
DC NL 0:
23:
24:
24:
25:
25:
. 25:
0.
00 RO
54
16
34
12
28
51
93
32 1
77 1
31 1
31 3
81 3
31 3
32 2
30 7
32 1
79 1
SI 3
31
31
94
64
75
05
32
0.39
76
74
34
18
87
67
73 2
61
43
90
2
65-0.39
0.
0.
0.
0.
0.
0.
0.
15
78 2
76 1
74
30
76
73
4
.452
,320
,030
,821
.572
,527
,196
,090
,206
,302.
,963
896.
706,
160.
13,
91.
19.
,356.
.00
.45
.95
.12
.26
.31
.18
.36
.00
.49
.32
.53
.37
.36
.10
.49
,70
77
.99
654
576
460
1,713
1,598
1,574
991
3,160
543
576
1,781
400
315
85
5
39.
.53
.20
.18
.32
.96
.70
.49
.00
.77
.49
.28
.68
.30
.12
.37
.27
797
744
569
2,107
1,973
1,952
1,204
3,930
662
726
2,137
495
391
90
9.
52,
0.876-1.072
.92
.75
.94
•94
.85
.48
.87
.00
.72
.33
.25
.69
.06
.45
.18
.43
0.000
0.383
0.902
0.911
0.930
0.938
0.952
0.962
0.978
0.985
0.995
1.002 2378-TCDF AN
1.018
1.025
1.035
1.053
1.066
1.075
0.961-1.039
3.
13.
31.
6.
12.
19.
,762.
14.
14.
12.
,823.
.86
.64
18
96
03
97
24
67
44
30
35
TCDF / TCDD
0.
,513.
,492.
138.
507.
276.
119.
90
62
99
63
70
04
50
5.
7.
1,165.
6.
6.
60
98
34
,38
28
6.
11.
1,596.
10.
12.
.43
99
90
.47
96
0.000
0.917
0.939
0.945
0.979
0.984
1.000 13C12-2378-TCDF ISO
1.016
1.025
1.075
1,102.
646.
59.
225.
119.
SO.
87
32
20
30
59
34
1,415.
846.
79.
282.
156.
69.
0.901-1.043
75
67
48
40
45
16
0.000
0.908
0.922
0.933
0.957
0.967
0.982
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
r\
35:
-------
Page No.
01/15/98
Listing of T980164B.db£
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak. 1.
Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
M
AN
320-322
37C1-TCDD
328
.3
13C12-TCDD
332-334
332-334
PeCDF
340-342
AD
' 26
26
1 26
26
26
• 27
:14 0.79
:21
:30
:39
:52
s!7
0.
0.
0.
0.
0.
.75
,74
,65
,66
,30
12 Peaks
DC NL 0
DC WL 23
DC WL 24
DC WL 24
24
, 24
25
i 25
|
1 25
i 25
DC SN 26;
26:
26:
DC SN 26;
DC SN 26;
DC SN 27:
! 27:
1 27:
27:
:00
:54
:10
:16
:27
:35
:00
:12
•16
:4Q
:53
:03
i 21
:43
;55
;59
:03
:13
:36
46
12 'peaks
1
DC NL 0:
25:
26:
! 26:
26:
0:
00 RO
:12 RO
09
20
39
472
28
45
49
17
13
5,679
1
13
28
13
6
3
861
6
2
10
3
2
1,909
207
1.
1
2
3
11
3
3,030,
.00
.40
.09
.31
.82
.10
.75
.24
.37
.37
.38
.94
.06
.52
.77
.96
.77
.44
.13
.39
.39
.36
.44
.05
.21
.20
.01
,66
209
12
19
19
7
5
6
3
861
6
2
10
3
1,909
207
3
11,
3
.00
.20
.20
.56
.11
.32
.94
.06
.52
.77
.96
.77
.44
.39
.39
.21
.20
.01
,65-0.89
2.
0.
0.
0.
0.
4 Peaks
1
;
DC NL 0:
27:
27:
! 27:
' 28:
i 28:
28:
28:
28:
D EE 23:
1.
00 RO
33
43 RO
53 RO
00 RO
11 RO
16 RO
31
39
46 RO
32-
1.
1.
0.
1.
2.
1.
1.
1.
1.
1.
87
46
81
30
71
1.78
08
52
59
87
06
93
11
53
46
28
4.
9.
2.791.
2,239.
37 .
37
,52
.15
75
56
5,077.98
• TCDD /
i.
1,043.
15.
21.
17.
22.
17.
325.
1,838.
378.
33
72
33
34
65
77
87
97
00
39
4.
1,250.
994.
15.
,14
33
43
59
263.00
16.20
25.39
30.25
10.71
7.28
0.
0
1
1
1
1
1
924
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
.996
.001 2378-TCDD AN
.006
.012
.020
.036
-1.076
.000
.908
.918
.922
.928
.934
.949
.957
.959
.975
.983
.989
.001 37C1-TCDD SUR1
.015
.022
.025
.027
.034
.048
.054
0.924-1.076
3.99
1.540.82
1,245.32
21.97
0.
0
0
1.
1.
.'000
.957
.993 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.012
0.923-1.061
0.000
629.
9.
15.
14.
17.
10.
196.
1,091.
11
32
64
26
21
86
99
59
414. 'SI
15.93
8.37
6.92
8.93
9.81
128.98
746.41
0.
0.
0.
0.
0.
0.
0.
0.
0.
934
940
946
950
956
959
967
972 .
976
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:29 01/15/98
353
-------
Page No.
01/15/98
Listing of T980164B.dbf
Matched GC Peaks / RaCio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
^ A
356-358
13C12-PeCDD
368-370
368-370
28:48
.29:07
29:13
29:25
29:30
29:39
29:46
30:10
30:19
30:37
DC SN 30:51
31:08
19 Peaks
DC NL 0:00
28:37
28:49
29:29
29:45
DC SN 29:54
30:09
DC SN 30:25
31:07
6 Peaks
DC NL- 0:00
28:46
DC SN 28:55
29:14
29:27
29:35
29:46
29:59
30:12
30:20
30:31
30:38
30:58
DC WH 31:10
11 Peaks
DC NL 0:00
DC SN 28:45
DC SN 29:25
30:29
30:37
2 Peaks
RO
1
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
1.
RO
RO
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
52
43
49
50
50
52
52
45
43
38
05
63
376.33
529.76
830.32
354.28
272.94
237.81
371.00
362.52
429.21
98.62
3.92
44.97
7,210.41
227
312
496
212
163
143
223
214
252
57
27
.05
.00
.78
.50
.59
.30
.53
.47
.86
.23
.35
149
217
333
141
109
94
147
148
176
41
17
.32-1.78
1.
1.
1.
1.
1.
0.
1.
4.
1.
32-
1.
1.
0.
1.
1.
1.
1.
1.
• 1.
0.
1.
1.
1.
2.
32-
1.
5.
1.
1.
1.
41
44
33
39
48
35
43
53
10
1.78
45
28
02
16
56
63
64
49
69
48
44
63
38
37
1.78
12
17
33
46
44
0.99
15.25
6.16
2,699.35
25.95
2.99
2,611.27
3.67
5.23
5,363.21
0.98
373.39
2.99
23.46
266.21
38.31
164.70
65.09
71.19
29.02
35.86
21.13
18.59
1.17
1,112.45
9
3.
1,570,
15,
1,535.
3.
.00
.52
.34
.48
.11
.18
6
2.
1,129
10
1,076,
2.
.28
.76
.54
.78
.35
.51
.42
.05
.35
.39
.12
0.977
0.988
0.991
0.998
1.001 12378-PeCDF
1.006
1.010
1.023 23478-PeCDF
1.028
1.038
1.046
1.056
AN
AN
J
0.864-1.136
.25
.64
.01
.47
.16
.90
0.000
0.971
0.977
1.000 13C12-PeCDF 123
1.009
1.014
1.023 13C12-PeCDF 234
1.032
1.055
1 32
SUR2
230.
14.
162.
24.
102.
38.
44.
17.
21.
13.
13.
00
26
38
35
32
95
74
64
19
10
71
179.
12.
103.
14.
62.
26.
26.
37.
14.
3.
7.
0.937-1.021
00
34
33
46
38
14
45
03
67
03
29
0.000
0.944
0.949
0.959
0.966
0.970
0.976
0.984
0.991
0.995
1.001 12378-PeCDD
1.005
1.016
1.022
J
J
J
AN J
J
J
0.869-1.131
0,46
0.39
1.91
1,801.71
175.87
1,977.58
1,063.
103.
17
71
733.
72.
54
16
0.000
0.943
0.965
1.000 13C12-PCCDD 123
1.004
IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
1/15/98
-------
Page No.
01/15/98
Listing of T980164B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
HxCDF
374-376
M
AN
M
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
M
M
390-392
13C12-HXCDD
402-404
DC NL 0
J 31
32
32
: 32
32
DC SN 32
1 32
32
33
33
1 33
! 34
1 34
!
34
1
:00 RO
:56
:04
.05-1.43
2.06
1.31
1.31
:13 1.42
:22
:31 RO
:41 RO
:52
:59
:07
:16
:30
:14
:18
:22
1.26
1.44
0.66
1.
,27
1.37
1.
1.
1.
1.
1.
1.
.18
,34
,30
.42
22
24
13 Peaks
DC NL 0
DC SN 31
DC SN 32:
: 32:
• 32:
DC SN 33:
33:
DC SN 33:
34:
DC SN 34:
0,
:00 RO
:56
:01
:52
:58
:1S RO
:29
:46 RO
:17
:39 RO
; rv*~w i iw
3.38
228.18
453.50
29.19
52.20
27.19
2.64
366.29
157.23
30.59
54.50
131.32
7.24
7.04
32.00
1,576.47
* uf r w i j.
129
257
17
29
17
205
90
16
31
74
4
3
17
.31
.07
.12
.06
.48
.15
.76
.54
.19
.13
.25
.37
.70
98
196
12
23
12
161
66
14
23
57
2
3
14
.43-0.59
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
4 Peaks
i
•
DC NL 0:
32:
DC SN 32:
32:
33:
33:
DC SN 33:
DC SN 33:
33:
i 33:
: 33:
DC WH 34:
. 1.
:00 RO
24
32 RO
51
04
14
25 RO
29 RO
36
41
59
12 RO
63
57
44
52
51
32
53
37
51
40
05-1.43
0.
1.
0.
1.
1.
1.
0.
2.
1.
1.
1.
1.
40
22
52
22
26
12
83
96
23
31
26
48
7 Peaks
DC NL 0:
1.
00 RO
05-
2.
1.43
24
3.55
4.11
5.54
2,085.20
2,263.25
3.43
2.155.53
2.31
1.903.28
2.66
8,407.26
Wvf ntr / u vf*
rut*— ur i nxu
0.39
41.13
0.54
198.34
100.49
8.70
0.45
1.21
9.05
24.50
30.36
0.52
413.07
715
766.
'745.
641.
.56
.17
.38
.22
1,369
1,497
1,410
1,262
0.963-1.047
0.000
.87 0.969
.43
.07
.14
.14
.14
.47
•05
.31
.19
.99
.17
.30
0.973
0.977
0.982
0.986
0.991
0.997 123478-HxCDF AN
1.001 123678-HxCDF AN
1.005
1.009
1.016 234678-HxCDF AN
1.038
1.040 123789-HXCDF AN
1.042
J
J
J
J
QJ
J
PRJ
J
0.379-1.121
.64
.08
.15
.06
0.000
0.969
0.971
0.997 13C12-HXCDF 473 SUR3
1.000 13C12-HXCDF 678 IS4
1.010
1.016 13C12-HXCDF 234 ALT2
1.024
1.040 13C12-HXCDF 789 ALT1
1.051
*nn i?rti i ?*i*io
22.
109.
56.
4.
4.
13.
16.
59
11
09
59
99
90
95
18.
89.
44.
4.
4.
10.
13.
0.953-1.014
54
73
40
11
•
06
60
41
0.000
0.962
0.966
0.976
0.982
0.987
0.993
0.995
0.993 123478-HxCDD AN
1.000 123678-HxCDD AN
1.009 123789-HXCDD AN
1.016
J
J
J
J
PRJ
0.970-1.030
1.36
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729;* Fax: (919) 544-5491
Printed:
W/15/98
-------
Page No.
01/15/98
Listing of T980164B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
402-404
HpCDF
403-410
408-410
13C12-HpCDF
413-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
33:03
33:35
33:40
33:53
34:00
34:17
DC SN 34:22
DC SN 34:29
6 Peaks
DC NL 0:00
35:59
36:17
36:26
DC SN 36:38
DC SN 36:48
37:36
DC WH 37:54
4 Peaks
DC NL 0:00
35:59
DC SN 36:29
37:36'
DC SN 38:09
2 Peaks
DC NL 0:00
DC SN 36:09
36:17
DC SN 36:35
37:05
2 Peaks
DC NL 0:00
37:04
1 Peak
DC NL 0:00
DC WL 35:29
DC WL 35:41
RO
RO
RO
RO
RO
0
RO
RO
RO
RO
RO
0.
RO
0.
RO
RO
0.
RO
0.
RO
RO
1.
1.
1.
0.
1.
0.
1.
2.
,57 .
.21
,22
.65
20
,71
76
50
6
1,648
2,007
6
2,230
6
4
1
5,904
.76
.36
.08
.07
.33
.32
.91
.93
.92
n /
.88-1.20
1.
1.
1.
1.
2.
1.
1.
1.
.37-
0.
0.
0.
0.
0.
88-
0.
0.
0.
0.
0.
88-
1.
1.
76-
1.
0.
1.
29
08
06
10
03
71
36
49
•0.51
64
43
44
44
50
1.20
92
58
96
36
92
1.20
53
02
1.02
75
93
54
0
252
48
53
0
1
25
1
379
.78
.56
.56
.32
.71
.59
.01
.63
.95
4.75
901.76
1,103.20
3.36
1,215.36
3.50
3.02
0
746.60 0
903.88
5.18
1,014.47
4.96
1
1
1
1
.982
.998 13C12-HXCDD 473
.000 13C12-HXCDD 678
.006
.010 13C12-HXCDD 789
.013
SOR4
IS5
RS2
1.021
HrrfTll? TTrtl 1 /lure
131.26
25.00
28.24
16.72
0.
121.30
23.56
25.58
12.26
1.
.024
996-1.051
0.
1.
1.
1.
1.
1.
1.
1.
.000
000 1234678-HpCDF
008
013
013
023
045 1234789-HpCDF
053
AN
AN
0.944-1.111
1
1,657
6
1,397
2
3.054
HnPTTf
np\-ut
0.
2.
62.
0.
56.
118.
.74
.50
.59
.20
.29
.70
r /
* /
.25
,20
,47
53
22
69
501.36
423.94
30.63
26.98
1,155.64
973.26
0.
1.
1.
1.
1.
0.975-
31.34
29.24
0.
0.
0.
0.
1.
0.973-
1.
1,759.
1,759.
Wrsf^nr
np\~UL
0.
0.
0.
59
67
67
38
29
49
887.38
Octa— CDD and CDF
872.29
0.
1.
Follows
0.902-
0.
0.
0.
000
000 13C12-HpCDF 673
014
045 13C12-HpCDF 789
060
1.005
000
975
979
987
000 1234678-HpCDD
1.027
000
000 13C12-HpCDD 673
1.098
000
367
372
IS6
SUR5
AN
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:<
3U15/98
)D
-------
Page No. 6 Listing of T980164B.db£
01/15/98 Matched GC Peaks / Ratio / Rec. Time
Compound/
fcM_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
-- -- - -- - " 0.881
0.887
0.893
0.903
0.906
0.918
0.921
0.923
0.925
0.927
0.932
0.934
0.942
0.945
0.951
0.960
0.964
0.973
0.982
0.985
0.985
0.994
0.997
46.21 54.91 1.005 OCDF AN
1.011
1.017
1.019
1.027
1.029
0.902-1.098
0.000
23.40 30.60 1.000 OCDD AN
1.007
0.997-1.005
0.000
1,107.31 . 1,253.03 1.000 13C12-OCDD IS8
1.011
1.013
N
^42-444
OCDD
458-460
M
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN'
SN
SN
1
SN
SN1
SN|
SN
SN1
SN1
i
SN,
i
NL|
I
SN!
i
i
NL
1
WH
WH
1
36
36
36
36
37
37
37
37
37
37
38
38
38
38
33
39:
39:
39:
40:
40:
40:
40:
40:
41:
41:
41:
41:
42:
42:
:02
:13
:33
:56
:05
:33
:42
:4S
:51
:56
:07
:14
:32
:40
:54
:16
:27
49
:11
:19
19
41
48
08
22
37
42
01
05
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
3
0
4
1
2
0
1
1
2
0
0
3
3
0
0
1.
1.
0.
0.
0.
3.
0.
0.
0.
0.
1.
0.
0.
.15
.00
.73
.92
.51
.07
.94
.65
.71
.32
.31
.66
.44
.03
.08
.74 '
.28
.69
.35
56
63
30
16
34
56
65
40
18
02
Peak
0:
40:
41:
00
56
12
0.
RO
RO
0
0
0
0
1
0
0
0
0
0
0
1
0
0
0
0
.62
.53
.68
.25
.47
.57
.64
.49
.79
.42
.47
.68
.17
.55
.11
.53
0.95
0.
0,
0.
0.
0.
0.
101.
1.
1.
0.
0.
0.
101.
.49
.47
.31
57
28
34
12
42
23
38
36
02
12
76-1.02
1.
0.
2.
08
76
38
Peak
0:
40:
41:
41:
00
55
22
26
0.
RO
RO
76-
1.
0.
0.
0.
1.02
30
38
81
53
Peak
0.
54.
0.
54.
0.
2,360.
6.
4.
2,360.
23
00
98
00
19
34
58
69
34
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713 Printed- 09-9Q
Phone: (919) 544-5729 • Fax: (919) 544-5491 3
-------
Page Ho.
01/15/98
Listing of T980164B.dbf
Hatched OC teaks I Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_2 -Nominal ton Hass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Racio Outside Limits
Rel.RT-Relative Retention Time
End of Report *»*
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
*iIa:TSS0154 #1-810 Acq:7-J2UT-98 01:07:26 SI+ Voltaga SIR 70T Noiamtl049
303.9016 T:2 BSUB(25S,30e-3.0) PXD(9,5,5,0.05\,4196.0,1.00\fr,T) ExptSDBSUS
TRIANGLE LABS
1001
23:00
rile:T9801S4 #1-810 Acq: 7-J1
305.8987 P:2 BSUB(256,30,-3,
TRIANGLE LABS \Text:TLH443'.
1002
so:
50:
40:
201
23:00
File:T980164 #1-810 Acq:7-J)
315.9419 T:2 BSUS(256,30,-3.
TRIANGLE LABS ,Text:TLI#443'.
1001
80:
60:
40:
20:
oJ
23:00
File:T980164 #l!-810 Ac
-------
rile:T9a0164 #1-810 Acq: 7-JAN-98 01:07:25 EI+ Voltage SIS 70T Hoia«il97
319.8965 Ti2 BSUB(256,30,-3.0) PB>(7,5,3,0.05%, 788.0,1.00\,f,T) SxpiHDBSUS
TRIANGLE LABS TejctsTLH44376 137-140 UtJ. TIME - 01:09
OOJ
80:
60:
40:
20:
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Al.
1
A6.46X6
A
A
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24:00 25:00 25:00 27:00
rile:T980164 #1-810 Acq: 7-J7UT-98 01:07:26 XI+ Voltage SIS 70T Noia»:1272
321.8936 Ti2 BSUB(256,30, -3. 0) PXD(7lS,3,0.05\,50aa.O,1.00\rT,T) KxpiNDBSOS
TSIANGLE LABS Text:TLIi44376 137-140 IXJ. TIME - 01:0*
1001
SO:
so:
20:
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331.9368 f:2 BSUB(256,30, -3 . 0) PXD(7,5,3,0.05^,1576a.O,1.00^rr,T) Exp:NDBSUS
TRIANGLE LABS Text-.TLIf44376 137-140 INJ. TIME • 01:09
1004 A1.25E7
80:
so:
40:
20:
A9.94E6
24:00 25:00 2S.-00 27:00
rile.-T580154 #1-810 Acq: 7-JAN-98 01:07:26 EI+ Voltage SIS 701 Noiae:1375
333.9338 T:2 BSUB(256,30, -3. 0) PXD(7,5,3, 0. 05%,5500. 0,1.00%,T, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 137-140 ZK7. TIME - 01:09
10 Oil A1.54E7
80:
60:
40:
20:
1.2SE7
24:00 25100 26:00 27:00
Tile:T980164 #1-810 Acq: 7-JAN-98 01:07:26 EI+ Voltage SIS 70T Noiae: 621
327.8847 f:2 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. 05\,2484. 0,1. 00\,T,T) Exp-.NDBSUS
TSIANGLE LABS Text:TLI#44376 137-140 INJ. TIME - 01:05
1004
80:
SOJ
40J
20J
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A8.63E6
A2.08E6
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24:00 25:00 25:00 27:00
rile:T980164 #1-810 Acqi7-J7Uf-98 01:07:26 XI+ Voltage SIS 70T
330.9792 F:2 Exp:lO3B5US
TRIANGLE LABS TeittTLIt44376 137-140 HKT. TIME - 01:09
1004 24:02 24:_2JL _24:45 25:25 25:52 26:18 25:52 27s08
80.
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0.0X0
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3.6E6
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24:00
25:00
2S:00
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36G
-------
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339.8597 T:2 BSUB(256, 30, -3. 0) PXD(7,5,3,0 .Q5\,2276.0,1.00\,T,T) SxpiNDBSUS
TSIANSLX LABS Text :TLI §44376 137-140 HU. TIMS - 01:09
1004 A1.09X7 -.2.7X6
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341.8567 T:2 BSUB(2S6,30r -3 .0) PXD(7,5, 3, 0.05\,2116. 0,1.00\,F,T) Xxp-.SDBSOS
TSIANSLX LABS Text:TLIf 44376 137-140 HKT. TIKE - 01:09
1001 A7.46X6
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351.9000 r:2 BSUB(256, 30, -3. 0) PKD(7,5, 3, 0. OS\,1164. 0,1 . 00\,F,T) Exp:NDBSUS
TSIANSLE LABS Text:TLIf 44376 137-140 13K7. TIME - 01:09
1004 1 A1.S7E7 A1.54E7
aol
60:
40: '
20:
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ft
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28\00 29\00 3o':00 3l':00
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353.8970 F:2 BSU3(256, 30, -3 .0) ?XD(7 ,5,3,0 .05\, 824 .0,1. 00\,T,T) Exp-.NDBSOS
TSIANSLE LABS Text:TLI#44376 137-140 XJKT. TIME - 01:09
.1004 ' A1.13E7 A1.0BE7
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330.9792 f:2 Exp^NDBSUS
TSIANSLE LABS Text:TLIt44376 137-140 UV. TIME " 01:09
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TSIANSLE LABS Text:TLH44376 137-140 XK7. TTHE - 01:09
1004 31 30
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361
-------
rU.a:Tyu0164 tl-SlO AcqsJ-JAV-ya 01i07:J6 SI+ Voltage SIS 70T Noiae:J92
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TRIANGLE LABS TextiTLH44376 137-140 ZK7. TIME - 01:09
1001
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TRIANGLE LABS Text:TLIt44376 137-140 BW. TIME » 01:09
1003
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28:J5 28:48 23. -00 29': 12 29:24 29:36 29:48 30:00 30:12 Jbl-24 3o':36 3o':48 Jl-00 3l':12 3l':24 Time
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TRIANGLE LABS Text:TLIt44376 137-140 INJ. TIME - 01:09
100}
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28:36 28:48 29:00 29:12 29:24 29': 36 29:48 J0:00 30:12 30s24 3o':36 jol-48 3l':00 31il2 31i24 Time
r±le:T980164 tl-810 Acqt7-JAN-98 01:07:25 EI+ Voltage SIS 70T
330.9792 T:2 ExpiNDSSUS
TRIANGLE LABS Text:TLH44376 137-140 INJ. TIME - 01:09
1001
80.
50.
40.
20.
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28:50 29:08 29:21 30, 3g 39,47 30:07 30:24 I/J.IT 30:54 31-16
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Time
362
-------
rile: T9 a 01 54
373.8208 T:3
TRIANGLE LASS
1003
80:
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40:
20.
A3
A1.39X6
1
tl-396 Acq:7-JAH-98 01:07:36 XI* Voltage SIS 70T No±a«tl553
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Text:TLI#44376 137-140
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Text:TLIt44376 137-140
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363
-------
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
Tlle:T980164 #1-396 Acq:7-JAN-98 01:07:26 EI+ Voltage SIR 70T Koiee:929
401.8558 T:3 BSU3(2S6,30, -3. 0) PKB(7, 5,3, 0. 05%,3716. 0,1. 00\,T, T) Eip:NDB5aS
TRIANGLE LASS Text:TLI*44376 137-140 INT. TIME - 01:09
1004 ,, ,rtP7 A1.22E7
riJ.eiTSaOJ.64 91-136 Acq: 7-JXN-Hlt U1:U/:J6 Eli- Voltage SIX 70T HO3.au: J4J
389.8156 r,3 BSUB(236, 30, -3.0) FXD(7,5,3, 0.05%, 972. 0,1.00\,f,T) Sip:SDS5US
TRIANGLE LASS TextiTLH44376 137-140 1X7. TIMX - 01:09
1001
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391.8127 f:3 BSUB(2S6,30,-3.0) PKD(7,5,3,0.05\,2452.0,1.00\,r,T) XrpiXDBSVS
TSIANSLX LASS Text:TLH44376 137-140 XKT. TIMX - 01:0
100A AS. 97X5
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TRIANGLE LASS Text.-TLIf44376 137-140 UtJ. TIKE - 01:03
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TSIANSLX LASS Text:TLIt44376 137-140 XK7. TIHX - 01:03
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-------
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TRIANGLE LABS Text: TLIf 44376 137-140 HKT. TIME - 01: 09
1001
80:
60:
40:
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0:
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TRIANGLE LABS Text:TLI#44376 137-140 OKT. TIME - 01:05
1003
80:
50:
40:
20:
A1.21E6
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417.8253 r:4 BSUB(2S6, 30, -3. 0) PKD(7,5, 3, O.OS\,1536. 0,1 . 00\,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#44376 137-140 IKT. TIME - 01:05
1003
80:
50:
40:
20:
0:
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419.8220 F:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0 .05\,2420 .0,1.00*,F,T) Elp-.NDBSUS
TSIANGLE LABS Teit:TLI#44376 137-140 JKT. TIME - 01:05
100J
80:
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40:
20:
0-
A1.16E7 ,
A :
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430.9729 F:4 Elp:in}B5CS
TXIAHGLE LABS Text:TLI#44376 137-140 IJTJ. TIME - 01:05
100J
80J
50:
B5US
TSIAXGLE LABS Text:TLI#44376 137-140 IJKT. TIME - 01:05
1003
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36:16 ft 37:20 37*36
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TRIANGLE LABS Text:TLI>44376 137-140 HKT. TIMS '01:09
1001
901
801
701
601
501
401
301
201
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36:00 37:00 38:00 39:00 40:00 41:00 42:0
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443.7399 f:4 BSUB(256, 30, -3. 0) PKS( 7,5, 3, 0.05%, 396. 0,1. 00\,T,T) ErptHDBSUS
TSIAXGLE LABS Text:TLIt44376 137-140 UKT. TIMX - 01:05
1001
901
801
701
601
501
401
301
201
101
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430.9729 f:4 ExpiNDBSUS
TRIANGLE LABS Text:TLI#44376 137-140 Utf. TIME ' 01:09
1001
901
801
701
601
501
40
'
301
201
101
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TRIANGLE LABS Text:TLIt44376 137-140 IJij; TIME - 01:09
1001
90.
80.
70.
60.
501
401
301
201
101
01
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36\00 37:00 jfliob 39\00 ' 40»00 41;00 43:00 Tiae
367
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40:48 40:54 41:00 41:06 41,12 41:18
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459.7348 T:4 BSUB(256f 30, -3.0) PXD(7,5,3, 0.05\,248.0r1.00\,T,T) Ezp:SDB5OS
TSIASSLX LASS Text:TLI#44376 137-140 IJKT. TXMK - 01:09
1001 AJ.jSES
40': IS 40:54 41:00 41:06 41:12
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8 384 K 332 T 378
C 386 I 334 U 376
0 316 H 346 V 418
E 318 N 342
F 3K 0 252
G 322 P 354
H 328 Q 366
I 331 R 358
Charrel I 33,3782'. Peak top
Height 2,94 ydts Span 288 p
369
-------
File:T980164 #1-810 Acq:7-JAN-98 01:07:26 EI+ Voltage SIR 70T
303.9016 F:2 Exp:NDB5US
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Sample Text:TLI#44376 137-140 INJ. TIME =
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315.9419 F:2 Exp:NDB5US
Sample Text:TLI#44376 137-140 INJ. TIME =
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Sample Text:TLI#44376 137-140
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Sample Text:TLI#44376 137-140
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Sample Text:TLI#44376 137-140 INJ. TIME
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Sample Text:TLI#44376 137-140 INJ. TIME =
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375.8178 F:3 Exp:NDB5US
Sample Text:TLI#44376 137-140 INJ. TIME =
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File:T980164 #1-396 Acq:7-JAN-98 01:07:26 EI+ Voltage SIR 70T
383.8639 F:3 Exp:NDB5US
Sample Text:TLI#44376 137-140 INJ. TIME =
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-------
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Sample Text:TLI#44376 137-140 INJ. TIME =
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391.8127 F:3 Exp:NDB5US
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Sample Text:TLI#44376 137-140
100%
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-------
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Sample Text:TLI#44376 137-140 INJ. TIME
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80 j
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File:T980164 #1-563 Acq:7-JAN-98 01:07:26 EI+ Voltage SIR 70T
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Sample Text:TLI#44376 137-140 INJ. TIME =
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Sample Text:TLI#44376 137-140 INJ. TIME = 01:09
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File Text:TLI#44376 137»
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Time
-------
TLI Project: 44376
Client Sample: 137-140
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P9801f j
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
yUtgtb*ag.
Gulp Aluminum Alloys
M23TRAIN Date Received:
194-59-9A-9D Date Extracted:
Date Analyzed:
1.000 Dilution Factor:
n/a Blank File:
DB-225 Analyst:
v " ^''-JkttiL faaV ' "'* ^5fk_ %
l"ar -f ^ -, ,,,
12/17/97
12/29/97
01/10/98
n/a
X980083
WK
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V"»« -~ -
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
ix " <-CV ''".ftrffcj" "f^ '-f'-'i
5; V , >,
SPC2NF04
PF22206
P980164
n/a
n/a
n/a
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